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"B^ 


tiMos  l^o-\^^ 


Given  By 
U.  S.  SUPT.  OF  DOCUMENTS 


UNITED    STATES    TARIFF   COMMISSION 

SYNTHETIC 
ORGANIC  CHEMICALS 

United  States  Production 
and  Sales,  1941-43 

Report  No.  153  •  Se<H>nd  Series 


United  States 

Qovernment  Printing  Office 

Washington:  1946 

BOSTON  PUBLIC  LIBRARY 

3  9999  06317  196  9 


m-.  21  1946 


UNITED  STATES  TARIFF  COMMISSION 


Report  No.  153  •  Second  Series  •  1945 

SYNTHETIC  ORGANIC  CHEMICALS 

United  States  Production  and  Sales,  1941-43 

CONTENTS 

Page 

Introduction 1 

Summary,  1941-43 , 3 

PART  I.     PRODUCTION  AND   SALES,  BY  GROUPS,  1941-43 

Coal-tar  and  petroleum  crudes 9 

Intermediates 14 

Dyes 21 

Lakes  and  toners , 36 

Medicinals 36 

Flavor  and  perfume  materials . .  .  45 

Plastics  materials 50 

Rubber  chemicals 56 

Elastomers 58 

Miscellaneous  chemicals 58 

PART  II.     INDIVIDUAL  ITEMS  AND  MANUFACTURERS,  1941-43 

Coal-tar  crudes 67 

Intermediates 68 

Dyes 81 

Lakes  and  toners 97 

Medicinals 101 

Flavor  and  perfume  materials 108 

Plastics  materials 113 

Rubber  chemicals 116 

Elastomers 119 

Miscellaneous  chemicals Hg 

APPENDIX 

A.  Imports  of  coal-tar  intermediates  and  finished  products 133 

B.  Research  workers  and  expenditures 134 

C.  Directory  of  manufacturers 134 

TABLES 
Summary 

1.  Tars  and  tar  crudes:  Summary  of  production  and  sales  of  specified  products, 

average,  1936-40,  annual,  1941-43 3 

2.  Synthetic  organic  chemicals:  Summary  of  United  States  production  and 

sales,  average,  1936-40,  annual,  1941-43 4 


II  CONTENTS 

Part  I 

Page 
3.     Tar:  United  States  production  and  consumption,  19-41-43 9 

4A.  Organic  chemicals :  United  States  production  and  sales  of  tars  and  tar 

crudes,  1941-43 12 

5A.  Synthetic  organic  chemicals:  United  States  production  and  sales  of  cyclic 

intermediates,  1941-43 15 

6.  Synthetic  organic  chemicals:  United  States  production  of  coal-tar  dyes, 

"  by  class  of  apphcation,  average,  1936-40,  annual,  1941-43 22 

7.  Synthetic  organic  chemicals :  United  States  sales  of  coal-tar  dyes,  by  class 

*  of  application,  average,  1936-40,  annual,  1941-43 23 

8.  Synthetic  organic  chemicals :  United  States  production  and  sales  of  coal-tar 

dyes,  by  chemical  class,  1941-43 25 

9.  Synthetic  organic  chemicals:  United  States  production  and  sales  of  azoic 

'  dyes  and  their  components,  1941-43 26 

lOA.  Synthetic  organic  chemicals:  United  States  production  and  sales  of  coal-tar 

dyes,  1941-43 27 

11  A.  Synthetic  organic  chemicals:  United  States  production  and  sales  of  lakes 

and  toners,  1941-43 37 

12A.  Synthetic  organic  chemicals:  United  States  production  and  sales  of  medici- 

nals,  1941-43 41 

13A.  Synthetic  organic  chemicals:  United  States  production  and  sales  of  flavor 

and  perfume  materials,  1941-43 46 

14A.  Synthetic  organic  chemicals:  United  States  production  and  sales  of  plastics 

'  materials,  1941-43 52" 

15A.  Synthetic  organic  chemicals:  United  States  production  and  sales  of  rubber 

chemicals,  1941-43 57 

16A.  Synflietic  organic  chemicals:  United  States  production  and  sales  of  elas- 
tomers (synthetic  rubbers),  1941-43.  .  . .- 59 

17A.  Synthetic  organic  chemicals:  United  States  production  and  sales  of  mis- 
cellaneous chemicals,  1941-43 61 

Part  II 

4B.  Organic  chemicals :  Tar  crudes  for  which  United  States  production  or  sales 

were  reported,  identified  by  manufacturer,  1941-43 67 

5B.  Synthetic  organic  chemicals:  Cyclic  intermediates  for  which  United  States 

'  production  or  sales  were  reported,  identified  by  manufacturer,  1941-43 .  .     68 
lOB.  Synthetic  organic  chemicals:  Coal-tar  dyes  for  which  United  States  pro- 
duction or  sales  were  reported,  identified  by  manufacturer,  1941-43.  .     81 
IIB.  Synthetic  organic  chemicals:  Lakes  and  toners  for  which  United  States  pro- 
duction or  sales  were  reported,  identified  by  manufacturer,  1941-43.  .  .     97 
12B.  Synthetic  organic  chemicals:  Medicinals  for  which  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  1941-43 101 

13B.  Synthetic  organic  chemicals:  Flavor  and  perfume  materials  for  which 
United  States  production  or  sales  were  reported,  identified  by  manu- 
facturer, 1941-43 108 

14B.  Synthetic  organic  chemicals :  Plastics  materials  for  which  United  States 

production  or  sales  were  reported,  identified  by  manufacturer,  1941-43.  .   113 
15B.  Synthetic  organic  chemicals:  Rubber  chemicals  for  which  United  States 

"production  or  sales  were  reported,  identified  by  manufacturer,  1941-43.  .   116 
16B.  Sjiithetic  organic  chemicals:  Elastomers  (synthetic  rubbers)  for  which 
United  States  production  or  sales  were  reported,  identified  by  manu- 
facturer, 1941-43 119 

17B.  Synthetic  organic  chemicals:  Miscellaneous  chemicals  for  which  United 
'States  production  or  sales  were  reported,  identified  by  manufacturer, 
1941-43 119 

Appendix 

18.  Coal-tar  intermediates  and  finished  coal-tar  products:  United  States  im- 

ports for  consumption,  classified  by  uses,  1941-43 133 

19.  SjTithetic  organic  chemicals:  Directory  of  manufacturers 135 


INTRODUCTION 

The  last  complete  report  made  by  the  United  States  Tariff  Commis- 
sion on  production  and  sales  of  synthetic  organic  chemicals  in  the 
United  States  was  the  twenty-fourth  annual  report  on  this  subject, 
issued  for  1940.  Although  preliminary  reports  have  been  released  each 
succeeding  year,  statistics  on  some  of  the  most  important  chemicals 
were  omitted  because  of  the  possible  value  of  such  information  to  the 
enemy.  This  report  includes  all  data  on  production  and  sales  of  syn- 
thetic organic  chemicals  for  the  period  1941-43,  except  production  and 
sales  of  chemicals  manufactured  at  Ordnance  plants.  Data  for  1944 
are  not  yet  available. 

Many  synthetic  organic  chemicals  are  of  military  importance  and 
are  also  essential  to  civilian  life  and  public  health.  Phenol  and  toluene 
are  used  in  making  explosives;  acrylic  ester,  coal-tar  acid,  and  urea 
plastics  materials,  in  making  airplanes,  tanks,  and  naval  vessels;  and 
acrylonitrile,  butadiene,  chloroprene,  and  styrene,  in  making  synthetic 
rubber.  There  are  also  chemotherapeutic  agents  of  military  and  civilian 
importance,  such  as  sulfathiazole  and  sulfapyridine,  and  the  synthetic 
vitamins — ascorbic  acid,  nicotinic  acid  amide,  and  riboflavin.  Finally 
there  are  synthetic  insecticides  and  various  solvents  useful  in  ])oth 
civilian  and  military  life. 

The  chemicals  in  this  report  are  grouped,  as  heretofore,  according 
to  use,  into  crudes,  intermediates,  dyes,  lakes  and  toners,  medicinals, 
flavor  and  perfume  materials,  plastics  materials,  rubber  chemicals, 
elastomers,  and  miscellaneous  chemicals.  In  accordance  with  industrial 
practice  and  the  chemical  literature,  chemicals  in  each  group  are  classi- 
fied as  cyclic  or  acyclic  according  to  their  known  chemical  structure. 
This  classification  is  of  value  since  the  two  types  are  frequently  pro- 
duced by  different  segments  of  the  organic  chemical  industry,  their 
properties  are  dissimilar,  they  move  in  different  channels  of  trade,  and 
they  are  usually  produced  from  different  raw  materials.  It  is  more 
accurate  than  a  classification  into  coal-tar  and  non-coal-tar  chemicals 
because  a  growing  number  of  identical  products  are  now  derived  from 
both  coal-tar  and  non-coal-tar  sources.  Almost  all  chemicals  of  coal-tar 
origi-n  are  cyclic  compounds.  Not  all  the  cyclic  organic  chemicals  are 
derived  from  coal  tar.  Some  are  obtained  from  raw  materials  such  as 
petroleum,  wood  distillation  products,  and  natural-occurring  sub- 
stances. Many  of  the  acyclic  chemicals  also  are  made  from  petroleum 
and  wood  or  produced  by  fermentation  from  grain  and  other  agricul- 
tural products.  Some  cyclic  organic  chemicals  have  been  further 
classified,  as  into  benzenoid,  alicyclic,  and  heterocyclic  compounds; 
this  additional  classification  provides  more  significant  subtotals  and 
also  a  greater  flexibility  in  grouping  the  data. 

Since  the  report  for  1940  was  published,  a  number  of  chemicals  have 
been  reclassified  from  one  group  to  another  because  of  a  pronounced 
change  in  use.  As  a  result  of  this  change,  some  of  the  totals  given  in 
the  tables  for  these  several  groups  in  this  report  do  not  agree  with  the 


2  UNITED  STATES  TARIFF  COMMISSION 

totals  published  in  the  preliminary  reports  for  the  same  years.  The 
classification  of  items  within  each  group  follows  as  closely  as  feasible 
the  system  of  classification  of  chemicals  used  in  Group  19  of  the 
Standard  Commodity  Classification;  ^  the  American  Chemical  Society's 
system  of  nomenclature  has  been  used  as  a  standard.  This  has  resulted 
in  the  elimination  of  much  duplication  of  the  same  item  under  different 
names,  which  occurred  in  .earlier  years  when  a  designation  commonly 
used  by  the  producing  company  was  inaccurate  or  insufficiently  de- 
scriptive, and  consequently  a  source  of  error  in  tabulating  the  data.  In 
this  report,  most  chemicals  are  listed  by  the  standard  name,  and,  where 
other  former  designations  are  dissimilar,  these  follow  the  standard 
name  in  parentheses.  Statistics  which  might  disclose  operations  of 
individual  companies  are  not  shown  separately  in  the  tables  for  in- 
dividual commodities  but  are  included  in  the  group  totals. 

The  data  given  in  this  report  were  compiled  from  schedules  re- 
ceived by  the  Commission  from  527  companies — nearly  twice  as  many 
as  reported  before  the  war.  A  list  of  these  companies  is  included  in 
the  appendix. 

The  report  includes  also  an  analysis  of  coal-tar  intermediates  and 
finished  products  for  1941-43  imported  into  the  United  States  under 
paragraphs  27  and  28  of  the  Tariff  Act  of  1930,  and  a.  tabulation  of 
expenditures  for  chemical  research  by  the  synthetic  organic  chemical 
industry  obtained  from  data  supplied  the  United  States  Tariff  Com- 
mission by  producing  companies. 


1  Executive  Office  of  the  President,  Bureau  of  the    Budget,  Standard   Commodity    Classification, 
vol.  1,  Tech.  Paper  26,  1943. 


i/v;'i!<fr«.f' 


j-*ldi*:i  ^;'i-' 


SUMMARY,  1941-43 


Production  and  sales  of  crudes,  intermediates,  and  finished  jDroducts 
in  the  period  1941-43  continued,  at  an  accelerated  rate,  the  upward 
trend  of  the  past  10  years.  The  total  quantity  of  tar  available  in  1942 
and  1943  for  the  production  of  these  commodities  was  about  100 
million  gallons  over  the  1941  level,  an  increase  of  about  13  percent. 
This  expansion  was  due  to  a  9-percent  increase  in  production  and  a 
4-percent  decrease  in  consumption  of  tar  as  fuel.  No  greater  increase 
was  possible,  despite  the  heavy  demand,  without  the  installation  of 
additional  byproduct  coke  ovens.  The  Nation's  coke  production  was 
maintained  at  well  over  90  percent  of  potential  capacity,  but  decreased 
yields  of  tar  resulted  from  the  shorter  coking  cycle  at  higher  tempera- 
tures, which  was  the  common  practice. 

Production  of  water-gas  tar,  oil-gas  tar,  and  coal  tar  combined,  and 
the  production  and  sales  of  the  principal  tar  crudes,  for  1941-43,  are 
shown  in  table  1 .  The  large  increase  shown  in  the  production  of  ben- 
zene was  made  possible  chiefly  by  the  preferential  production  of  ben- 
zene at  the  expense  of  motor  benzene,  an  automotive  fuel.  More 
toluene  and  naphthalene  Were  produced  in  response  to  demands  for 
war  purposes. 


Table  l.—  Tars 

%7id  tar  crudes:  .Summary  .of  production  and  sales  o 
average,  1936-iO,  annual,  19Ifl-JtS 

/  specified  products. 

CJ        Chemical  i 

Unit 

of 

quantity 

Average 
1936-40 

1941 

1942 

Increase  (+) 

or 
decrease  ( — ), 

1942 
over  1941 

1943 

Increase  (+) 

-or 
decrease  ( — ), 
1943 
over  1942 

Tar  produced  - 

Benzene: 

1,000  gal.. 
..do 

668,100 

26,196 

23,693 

3,169 

86,098 

83,350 

7.559 

22,318 

21,933 

5,305 

104,564 

93,578 

1,883 

105,408 
99,723 
11,800 

856,100 

44,812 

41,569 

4,912 

112,508 

104,402 

7,975 

35,587 

35,049 

8,691 

197,779 

163,501 

3,423 

143,503 
155,360 
18,998 

931,100 

85,257 
80,779 
10,487 

68,662 

66,698 

5,808 

43,292 
43,004 
11,630 

250,925 

220,291 

5,407 

175,297 

174,733 

23,779 

Percent 
+8.8 

+90.3 

+94.3 

+  113.5 

—39.0 
—36.1 
—27,2 

+21.7 
+22.7 
+.33.8 

+26.9 
+34.7 
+58.0 

+22.2 
+  12.5 
+25.2 

928,100 

142,047 

135,960 

17,864 

24,390 

24,530 

2,310 

96,342 
90,388 
28,635 

305,269 

235,305 

5,785 

175,186 

156,669 

21,714 

Percent 
—0.3 

+66  6 

Sales 

. . .do 

+68.3 

Sales  value 

1  Motor  benzene: 

Production 

Sales 

1,000  dol.. 

1,000  gal.. 
.    do ...  . 

+70.3 

—64.5 
— 63.2 

Sales  value 

'  Toluene: 

Production 

1,000  dol.. 

1,000  gal., 
do   . 

—60.2 

+122.5 
+110  2 

Sales  value 

Naphthalene: 

Production 

1           Sales 

1,000  dol.. 

1,000  1b... 
. ..do 

+146.2 

+21.7 
+6.8 

Sales  value 

Creosote  oil : 

1          Production 

Sales 

1,000  dol.. 

1,000  gal. 
.  .  .do 

+7.0 

—0.1 
—10.3 

Sales  value . 

1 

1,000  dol.. 

—8.7 

1  For  detailed  explanation  of  data  included  in  statistics  shown  in  this  table,  see  table  4A. 

^  Includes  estimated  production  of  water-gas  and  oil-gas  tar. 

Source:  Compiled  from  data  reported  to  the  U.  S.  Tariff  Commission  and  Bureau  of  Mines. 

A  preliminary  survey  of  some  of  the  chemical  raw  materials  derived 
from  petroleum  is  included  in  the  report  because  of  their  increasing 
importance.  At  present  the  bulk  of  these  materials  are  used  in  the 
manufacture  of  synthetic  rubber.    Organic  chemicals  produced  under 

3 


UNITED  STATES  TARIFF  COMMISSION 


wartime  conditions  from  petroleum  for  use  as  aviation  fuels  are  con- 
sidered to  be  beyond  the  scope  of  this  report  and  therefore  are  omitted. 
Table  2  summarizes  production  and  sales  of  synthetic  organic 
chemicals  for  1941-43,  by  groups,  and  compares  these  statistics  with 
the  corresponding  averages  for  1936-40. 

Table   2. — Synthetic  organic  chemicals:   Summary  of   United   States    production  and 

sales,  average,  1936-^0,  annual,  1941-^3 

[Productien  and  sales  in  thousands  of  pounds;  sales  value  in  thousands  of  dollars] 


Chemical 

Average 
1936-40 

1941 

1942 

Increase  (+) 

or 

decrease  ( — ) , 

1942  over 

1941 

1943 

Increase  (+) 

or 

decrease  ( — ), 

1943  over 

1942 

ORGANIC  CHEMI- 
CALS, CYCLIC  1 

Intermediates 

580,105 

244,376 

35,690 

1,007,426 

432,162 

63,833 

78 

806,954 
673,966 
314,667 

168,657 
176,801 
113,324 
45 

136,935 

143,580 

75,080 

14,935 
15,582 
19,635 

16,787 
17,639 
18,609 

26,272 

24,304 

18,773 

44 

31,303 

26,619 

.54,082 

56 

11,507 

10,854 

13,280 

29 

344,965 

261,680 

68,310 

75 

42,928 

32,823 

15,425 

11 

1,272,834 

698,991 

93,973 

96 

794.102 
676,198 
333,428 

151,878 

144.847 

99,431 

48 

117,204 

113,028 

62,791 

16,529 
15,464 
18,836 

18,145 
16,355 
17,804 

17,178 

15,243 

10,702 

44 

38,298 

34,944 

75,790 

84 

11,536 

10,041 

13,883 

35 

294,883 

248,751 

76,289 

77 

36,536 

31,309 

13,411 

11 

Percent 

+26  3 
+61.7 

+47.2 

1,637,275 

1,032,439 

134,988 

101 

1,398,342 

1,272,568 

484,881 

144,013 

145.499 

105,350 

46 

107,147 

108,724 

60,267 

20,098 
19,605 
25,041 

16,768 
17,170 
20,042 

16,317 

14,970 

10,358 

45 

51,633 

47,262 

120,869 

97 

9,559 

9.516 

11.920 

35 

380,523 

337.654 

76.761 

112 

61,710 

58,300 

23,628 

10 

Percent 

+28  6 

Sales       

+47.7 

+43.6 

Finished  Products 

389,303 
320,857 
134,342 

114,310 
112,119 
65,610 

—16 
+0  3 
+6.0 

—10  0 
—18.1 
—12.3 

+76.1 

+88.2 

Sales  value,  total 

Dyes 

+45.4 
—5.2 

+0.5 

+6.0 

Number  of  manufacturers  - 
Colour  Index  Group 

96,131 
94,846 
45,498 

(') 
(') 

18,179 
17,273 
20,112 

17,032 
14,770 
1 1 ,  137 

—14.4 
—21.3 
—16.4 

+10.7 
—0.8 
—4.1 

+8.1 
^7.3 
—4.3 

—34.6 
—37.3 
—43.0 

—8  6 

—3.8 

—4.0 

Prototype  Group 

+21.6 

+26.8 

+32.9 

Ungrouped 

—7  6 

Sales         

+5.0 

+  12.6 

Lakes  and  Toners 

—5.0 

Sales       

—1.8 

—3.2 

Number  of  manufacturers  2 

Medicinals 

14,267 
11,779 
12,451 

+22.3 
+31   3 
+40.1 

+34.8 

Sales 

+35.2 

+59.5 

Number  of  manufacturers  ^ 

Flavor  and 
Perfume  Materials 

4,502 
4,202 
3,954 

+0.3 
—7.5 
+4.5 

—14  5 
—4.9 
+  11.7 

—17.1 

—5.2 

—14.1 

Plastics  Materials 

153,706 
112,424 
21,971 

+29.0 

Sales 

+35.7 

+0.6 

Rubber  Chemicals 

29,167 

21,225 

9,204 

—14.9 

—4  6 

—13.1 

+68.9 

Sales 

+86.2 

+76.2    : 

.... 

See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43  5 

Table  2. — Synthetic   organic   chemicals:    Summary   of   United   States   production   and 
sales,  average,  1936-^0,  annual,  19Jil-i3- — Contimied 


Chemical 


ORGANIC  CHEMICALS, 

CYCLIC  '—Continued 
Finished  Products— Con. 

Elastomers 
(Synthetic  Rubbers) 

Production 

Sales 

Sales  value 

Number  of  manufacturers  - 

Miscellaneous  • 

Production 

Sales 

Sales  value 

Number  of  manufacturers  - 


ORGANIC  CHEMI- 
CALS, ACYCLIC  aN- 
TERMEDIATES  AND 
FINISHED  PRODUCTS) « 

Production,  total 

Sales,  total 

Sales  value,  total 


M  edicinals 

Production 

Sales 

Sales  value 

Number  of  manufacturers  ^ 

Flavor  and 
Perfume  Materials 

Production 

Sales 

Sales  value 

Number  of  manufacturers  ^ 

Plastics  Materials 

Production 

:   Sales 

■  Sales  value 

:   Number  of  manufacturers  - 

Ruhber'J^hemicals 
I  Production 

■  Sales 

•  Sales  value 

;  Number  of  manufacturers  - 

I  Elastomers 

(Synthetic  Rubbers) 

Production 

Sales 

■  Sales  value 

Number  of  manufacturers  - 

Miscellaneous 

Production 

Sales 

Sales  value 

Number  of  manufacturers  - 


Average 
1936-40 


56,319 
44,338 
10,015 


2,789,660 

1,369,265 

161,254 


1,665 
1,399 
4,054 


1,823 
1,676 
1,238 


29,523 
26,636 
11,661 


'15,019 

'13,625 

'3,417 


2,756,649 

1,339,554 

144,301 


181,322 

140,885 

31,473 

55 


4,997,906 

2,693,717 

353 , 579 


2,896 
2,405 
4,685 

44 


3,117 

3,083 

2,982 

31 


107,206 

94,541 

51,170 

32 


16,762 

15,703 

4,495 

10 


27,745 

21,577 

12,126 

7 


4,840,180 

2,556,408 

278,121 

111 


1942 


(*) 


243 . 793 

191,063 

43,922 

65 


7,131,681 

3,639,396 

508,815 


2,883 

1,795 

7,658 

60 


3,861 

3,769 

4,122 

34 


145,116 

132,771 

75.262 

42 


15,188 

14.669 

3,591 

11 


59,101 

45,618 

27,450 

7 


6,905,532 

3,440,774 

390,732 

135 


Increase  (+) 

or 

decrease  ( — ) , 

1942  over 

1941 


Percent 


(*) 
(*) 
(*) 


+34  5 
+35.6 
+39.6 


+42.7 
+35.1 
+43.9 


—0  5 
—25  4 
+63  5 


+23.9 
+22  3 
+.38  2 


+35  4 
+40.4 
+47.1 


—9  4 

—6.6 

—20.1 


+  113.0 
+  111.4 
+  126.4 


+42.7 
+34  6 
+40.5 


1943 


413,908 

401,056 

74,3.55 

14 


320,679 

2.'i8,311 

61,640 

92 


9,033,935 

5,029,043 

812,025 


4,062 

4,  ail 

18,770 

67 


3.687 

3,. 573 

3,933 

34 


273,415 

2.30,179 

101,430 

65 


19,213 

18,975 

7,509 

14 


158,801 

151,. 560 

82,022 

12 


8,, 574, 757 

4,620,215 

598,361 

I  165 


Increa.sc  ( +) 

or 

decrease  ( — ) , 

1943  over 

1942 


+31 . 5 
+35  2 
+40.3 


+26.7 
+38.2 
+59.6 


+40.9 
+153.0 

+  145.1 


—4.5 
—5.2 
—4.6 


+88.4 
+73.4 
+.34  8 


+26.5 

+29.4 

+109.1 


+  168.7 
+232.2 
+  198.8 


+24  2. 
+34  3 
+53.1 


1  Before  1941  this  group  included  only  cyclic  organic  chemicals  derived  from  coal  tar.  The  statistics 
shown  for  1941-43  include  alicyclic,  heterocyclic,  and  terpenoid  compounds,  as  well  as  benzenoid  (coal-tar) 
chemicals.  r        j     • 

-  Number  of  companies  engaged  in  the  manufacture  of  these  products,  not  the  number  of  producing 
establishments  or  plants  operated  by  a  single  company,  except  that  separated  divisions  of  large  corpora- 
tions are  considered  as  separate  companies  if  their  operations  are  practically  independent  of  the  parent 
organization. 

'  Included  with  ungrouped  dyes. 

*  Combined  with  acyclic  elastomers  to  avoid  revealing  confidential  information, 
s  Includes  biological  stains  and  chemical  indicators,  poisonous  and  tear  gases,  synthetic  insecticides, 
surface-active  agents,  solvents,  photographic  chemicals,  plasticizers,  synthetic  tanning  materials,  textile 
I  chemicals,  and  other  miscellaneous  chemicals. 

j         « Before  1941  this  group  included  all  synthetic  organic  chemicals  not  derived  frorn  coal  tar  and  thero- 
I  fore  contained  certain  alicyclic  and  terpenoid  compounds  as  well  as  acychc  organic  chemicals.    In  the 
statistics  shown  for  1941-43  only  acyclic  chemicals  are  included  in  this  group. 

'2-year  average,  1939-40.  These  data  are  included  with  miscellaneous  chemicals  for  the  5-year 
I  average  1936-40  and  therefore  are  not  considered  again  in  arriving  at  the  5-year  average  totals  for 
1  acyclic  intermediates  and  finished  products. 


6  UNITED  STATES  TARIFF  COMMISSION 

The  total  value  of  sales  of  all  intermediates  and  finished  products; 
cyclic  and  acyclic,  increased  from  732  million  dollars  in  1941  to  936 
million  in  1942  and  to  1,432  million  in  1943.  The  last  amount  repre- 
sents an  increase  of  333  percent  over  the  average  of  the  5  years  1936-40, 
Avhich  was  331  million  dollars.  These  totals,  however,  involve  a  con- 
siderable duplication  of  values. 

In  terms  of  quantity,  sales  of  all  synthetic  organic  chemicals 
amounted  to  55  percent  of  the  production  in  1941  and  1942  and  to  60 
percent  in  1943;  most  of  the  rest  was  consvmied  in  further  processing 
in  the  producing  establishments.  In  1941  and  1942,  the  value  of  sales 
Avas  fairly  equally  divided  between  cyclic  and  acyclic  chemicals,  but 
in  1943  sales  of  acyclic  chemicals  were  valued  at  812  million  dollars,'- 
compared  with  620  million  for  the  cyclic  products. 

Production  and  sales  of  intermediates,  cyclic  medicinals,  cyclic  and 
acyclic  elastomers,  acyclic  plastics  materials,  and  miscellaneous  chemi- 
cals increased  in  both  1942  and  1943.  There  .was  a  decrease  in  both 
years  for  dj^es,  and  for  lakes  and  toners.  Other  groups  were  irregular 
in  movement:  production  and  sales  of  flavor  and  perfume  materials 
increased  in  1942  and  decreased  in  1943,  whereas  those  of  cyclic  resins, 
cyclic  rubber  chemicals,  and  acyclic  medicinals  decreased  in  1942,  but 
were  larger  in  1943  than  in  1941. 

Increased  output  in  1942  and  1943  over  1941  occurred  chiefly  in. 
those  chemicals  wdiose  manufacture  was  pei^mitted  because  of  their 
use  for  essential  military  or  civilian  purposes.  Examples  of  these 
chemicals  are  monochlorobenzene,  phthalic  anhydride,  nitrobenzene, 
styrene,  and  phenol  among  the  intermediates;  and  urea-formaldehyde 
resins,  synthetic  rubber  and  polyvinyl  elastomers,  sulfa  drugs,  and; 
vitamins  among  the  finished  products. 

In  1941,  only  a  few  chemicals,  principally  formaldehyde,  phenol,  and 
toluene,  were  under  general  preference  orders  of  the  War  Production 
Board.  In  1942,  forty  chemicals  and  chemical  products,  such  as; 
l)henolic  and  vinyl  resins,  chlorinated  paraffins,  aniline,  and  benzene, 
were  allocated;  and  by  1943  most  of  the  more  important  organic 
chemicals  had  been  placed  under  allocation  control.  The  output  of 
dyes  and  of  lakes  and  toners  decreased  in  1942  and  1943  and  that  of- 
flavor  and  perfume  materials  decreased  in  1943,  principally  because' 
of  the  allocation  of  basic  chemicals  used  in  their  production  for  more 
essential  products  and  because  of  the  limitation  of  dye  j^roduction  for 
use  in  civilian  textiles.  The  shortage  in  phenol  and  formaldehyde' 
reduced  the  output  of  phenolic  resms  in  1942;  in  1943,  however,  sup-j 
]ilies  of  these  materials  became  more  plentiful  and  the  output  ex-' 
paneled.  Organic  chemicals  used  in  compounding  rubber  arc  known  as. 
rubl)cr  chemicals.  These  chemicals  were  in  less  demand  in  1942_ 
because  of  the  shortage  of  rubber,  but  the  demand  for  them  increased' 
sharply  in  1943  as  the  production  of  synthetic  rubber  gained  momentum. 

Other  factors  influencing  the  relative  output  of  the  several  kinds  of, 
synthetic  organic  chemicals  in  the  3-year  period  were  the  variation  in 
military  demands  for  them,  and  the  unusually,  heavy  inventories  of 
some  commodities  accumulated  in  1941  in  anticipation  of  future 
shortages.  Although  this  report  does  not  include  the  production  of 
chemicals  at  Government-owned  Ordnance  plants,  it  does  include 
production  of  some  of  the  basic  organic  chemicals  used  by  these  plants 
in  manufacturing  other  products.  Consumption  of  chemicals  in- 
directly for  military  purposes  is  generally  much  larger  than  direct 
consumption  at  Ordnance  plants. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43  7 

The  average  unit  sales  value  of  all  finished  cyclic  organic  chemicals 
increased  from  47  cents  per  pound  in  1941  to  49  cents  in  1942,  but  in 
1943  it  decreased  to  38  cents,  or  by  22  percent.  This  decrease  reflects 
the  increased  importance  of  sales  of  synthetic  elastomers  at  the  low 
unit  value  of  19  cents  per  pound,  and  the  declining  unit  value  of  tar- 
acid  resins.  On  the  other  hand,  the  unit  sales  value  of  acyclic  inter- 
mediates and  finished  products  increased  from  13  cents  per  pound  in 
1941  to  14  cents  in  1942,  and  to  16  cents  in  1943,  an  increase  of  33  per- 
cent over  the  average  for  1936-40.  This  increase  was  due  principally 
to  the  rising  unit  value  of  medicinals  in  1942  and  to  the  increased  im- 
portance of  rubber  chemicals  and  miscellaneous  chemicals  in  1943. 
There  was  a  decline  in  the  unit  value  of  acyclic  elastomers,  plastics 
materials,  and  medicinals  in  1943  compared  with  1942.  It  should  be 
noted  that  changes  in  average  unit  values  of  a  given  group  may  reflect 
not  only  changes  in  prices  of  particular  products,  but  also  changes  in 
the  relative  importance  of  different  products  in  the  group  total. 

The  foreign  values  of  imports  of  intermediates  and  finished  products 
in  1941-43  entering  the  United  States  under  paragraphs  27  and  28  o^ 
the  Tariff  Act  of  1930  are  given  in  the  appendix.^  These  imports  were 
valued  at  5.6  million  dollars  in  1941  and  dropped  to  3.6  million  in  1942 
and  to  3  million  in  1943,  a  considerable  decrease  from  the  10-year  high 
of  10.1  million  dollars  in  1939,  when  Germany  was  still  a  major  source 
of  imports. 


1  See  table  18. 


PART  I.    PRODUCTION  AND  SALES,  BY  GROUPS,  1941-43 

COAL-TAR  AND  PETROLEUM  CRUDES 

Crudes  obtained  from  coal  and  so-called  crudes  obtained  from  petro- 
leum are  the  raw  materials  fon  a  vast  number  of  chemicals.  Although 
there  is  considerable  overlapping  of  products  in  the  several  groups, 
coal  crudes  consist  chiefly  of  light  oil,  containing  mixtures  of  benzene, 
toluene,  xylene,  solvent  naphtha,  and  coumarone;  middle  oil,  con- 
taining the  tar  acids  (cresols,  phenols,  and  xylenols),  pyridine  bases, 
and  naphthalene;  and  heavy  oil  and  anthracene  oil,  containing  an- 
thracene, fluorene,  and  naphthalene  derivatives.  These  materials  are 
recovered  chiefly  from  the  gases  produced  when  coal  is  converted  to 
coke  in  byproduct  coke  ovens.  Crude  coal  tar  usually  consists  of  a 
mixture  containing  about  5  percent  light  oil,  17  percent  middle  oil, 
7  percent  heavy  oils,  9  percent  anthracene  oil,  and  62  percent  pitch. 
Light  oil  products  distill  below  200°  C. ;  middle  oil,  between  200°  and 
250°  C;  heavy  oil,  between  250°  and  300°  C;  and  anthracene  oil, 
between  300°  and.  350°  C.  The  distillates  contain  different  proportions 
of  the  crudes  depending  in  part  on  the  type  of  coal  and  the  coking 
temperatures  used. 

Water  gas  is  produced  by  the  combustion  of  coal  or  coke  in  an  at- 
mosphere of  steam.  Water-gas  tar  is  made  by  carbureting  water  gas 
with  oil  and  subsequently  cracking  the  mixture;  oil-gas  tar  is  made  by 
cracking  petroleum  with  or  without  the  use  of  coal  or  coke.  Both  are 
byproducts  in  the  manufacture  of  fuel  gas.  They  contain  many  of  the 
same  products  as  coal  tar  but  less  naphthalene  and  phenol,  and  their 
properties  are  intermediate  between  coal  tar  and  petroleum  asphalt. 

Chemical  raw  materials  derived  from  crude  petroleum  are  obtained 
by  distillation,  cracking,  reforming,  hydrogenation,  or  other  chemical 
processes  and  are  used  to  produce  a  wide  variety  of  synthetic  organic 
chemicals.  Many  of  these  products  arc  identical  with  those  obtained 
from  coal  tar  or  other  sources. 

Since  coal  tar  is  one  of  the  byproducts  recovered  in  the  process  of 
making  coke  and  in  making  fuel  gas  for  industrial  and  household  con- 
sumption, the  quantity  produced  depends  on  the  demand  for  coke  for 
the  manufacture  of  steel  and,  to  a  lesser  extent,  on  the  consumption 
of  fuel  gas.  No  coal  tar  is  recovered  from  beehive  coke  ovens.  Pro- 
duction and  consumption  of  tar  during  1941-43  are  given  in  table  3. 

Table  3. —  Tar:  United  States  production  and  consumption,  19ffl-JiS 
[In  millions  of  gallons] 


Source  and  use 

1941 

1942 

194.3 

Produclion 
Tar,  total 

856 

9.31 

928 

Coal  tar.i  total 

726 

761 

758 

Coal  tar  from  coke-oven  byproduct  plants,  total 

704 

740 

738 

658 
46 
22 

130 

692 
48 
21 

170 

689 

Plants  owned  by  city  gas  companies  (public  utilities) 

49 
20 

Water-gas  and  oil-gas  tar  - 

170 

See  footnotes  at  end  of  table. 


10  UNITED  STATES  TARIFF  COMMISSION 

Table  3. — Tar:  United  States  production  and  consumption,  19^1-^3 — Continued 


Source  and  use 

1941 

1942 

1943 

Consumption 
Tar,  total 

858 

920 

929 

571 

651 

682 

Coal  tar  distilled  or  topped  by  byproduct  coke-oven  operators  i . 
Coal  tar  distilled  by  tar  distillers  ' 

184 
341 

46 
239 

154 

195 
388 

68 
210 

205 

408 

Water-gas  and  oil-gas  tar  distilled  by  producers  and  tar  dis- 
tillers * • 

69 

Tar  consumed  chiefly  as  fuel  tar,  total 

204 

Coal  tar  sold  or  consumed  as  fuel  by  byproduct^operators  ' 

98 

102 

3 
136 

1 
14 

85 
48 

1 

94 

\ 

112    . 
59 

o 

As  fuel  in  open-hearth  and  affiliate  plants 

85 

Sold  as  fuel  by  byproduct  operators  to  affiliates  ' 

1 

Sold  as  fuel  bv  byproduct  operators  to  others 

14 

Water-gas  and  oil-gas  tar  consumed  principally  as  fuel  and  in 
road  tars  * •. 

102 

Tar  consumed  otherwise  than  by  distillation  or  as'fiiel,  total  .... 

43 

Coal  tar  consumed  in  coal-tar  solution  < 

6 

20 

20 

7 
20 

2 

30 

9 
20 

Coal  tar  consumed  in  byproduct  plants  '  (roads,  upkeep,  etc.) .  . 
Coal  tar,  water-gas  tar,  and  oil-gas  tar  processed  at  tar  refinery 

4 
10 

1  Reported  to  the  U.  S.  Bureau  of  Mines. 

2  Estimated.  Production  reported  to  the  U.  S.  Tariff  Commission  currently  represents  about  65 
percent  of  the  total  production.  This  estimate  is  based  on  quantity  of  oil-gas  and  water-gas  tar  distilled 
(35  to  40  percent  of  production)  and  burned  as  fuel  or  otherwise  consumed  as  reported  to  the  Commission 
(60  to  65  percent). 

5  Represents  coal  tar  purchased  from  byproduct  coke-oven  and  retort  i)lants  and  distilled  by  chemical 
companies  operating  tar-distillation  plants  as  reported  to  the  U.  S.  Tariff  Commission.  Tar  purchased 
and  distilled  by  corporations  affiliated  with  the  byproduct  coke-oven  operators  is  included  in  the  quantity 
of  tar  distilled  and  topped  by  these  operators. 

*  Reported  to  the  U.  S.  Tariff  Commission. 

^  Estimated  as -65  to  70  percent  of  production  of  water-gas  and  oil-gas  tar. 

6  Estimated  by  the  Bureau  of  Mines  for  1941.  Consumption  of  some  of  this  coal  tar  may  be  in- 
eluded  also  in  the  data  shown  for  tar  distilled  at  tar  refineries. 

'Partly  estimated;  includes  crude  tar  used  for  refining,  blending,  and  as  such  at  refinery  plants. 

In  1941-43,  recovery  of  coal  tar  at  byproduct  coke  plants  not  owned 
by  city  gas  companies  averaged  680  million  gallons  a  year;  at  those 
owned  by  city  gas  companies,  47  million  gallons;  and  at  coal-tar  retort 
plants,  21  million  gallons,  or  a  total  of  748  million  gallons.  This 
average  output  was  33  percent  higher  than  that  of  1936-40,  an  in- 
crease owing  principally  to  greater  production  to  satisfy  a  marked 
rise  in  the  demand  for  refined  coal-tar  products,  a  rise  which  began  in 
1941  and  continued  through  1943.  Production  of  coal  tar  increased 
only  slightly  in  1942  and  hardly  changed  in  1943.  Plants  were  already 
operating  at  about  capacity  in  1941,  and,  a,lth6ugh  installed  coking 
capacity  expanded  3  percent  in  1942  and  11  percent  in  1943,  the  effect 
of  these  increases  on  the  output  of  tar  was  offset  to  a  certain  extent 
by  a  decrease  in  tar  yields  from  8.4  to  8.1  gallons  per  ton  of  coke  pro- 
duced, as  a  result  of  higher  operating  temperatures  and  shorter 
coking  time. 

Complete  data  are  not  available  on  water-  and  oil-gas  tar  production 
in  the  years  1941-43,  but  an  estimate  can  be  made  from  the  quantity 
of  tar  distilled,  consumed  as  fuel,  and  used  for  other  purposes.  Pro- 
duction of  water-gas  and  oil-gas  tar  increased  from  an  estimated  130 
million  gallons  in  1941  to  170  million  in  1942  and  1943.  It  accounted 
for  from  15  to  18  percent  of  the  total  output  of  tar. 

The  quantity  of  crude  tar  burned  in  1942  and  1943  was  about  35 
miUion  gallons  less  than  that  burned  in  1941;  consequently  more  was 
available  for  conversion  into  coal-tar  crudes  or  to  be  consumed  for 
other  purposes.     The  total   quantity  of   tar  distilled,  including  tar 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43  11 

topped  (partiallv  distilled),  increased  from  571  million  gallons  in  1941 
to  651  million  in  1942  and  to  682  million  gallons  in  1943.  Of  these 
amounts,  the  coal  tar  distilled  at  byproduct  coke-oven  plants  ac- 
counted for  about  30  percent  of  the  total,  or  184  and  195  million 
gallons,  respectively,  in  1941  and  1942,  and  205  million  gallons  in 
1943,  of  Avhich  104  million  gallons  in  1941  and  1942,  and  113  million 
gallons  in  1943,  were  topped.  The  remaining  coal  tar,  amounting  to 
60  percent  of  the  total  quantit}'  of  tar  processed,  was  distilled  by  the 
tar  distillers;  water-  and  oil-gas  tar,  amounting  to  about  10  percent 
of  the  total,  was  distilled  by  both  tar  distillers  and  water-  and  oil-gas 
tar  producers. 

The  total  calculated  value  of  production  of  crudes  obtained  from  tar 
was  about  80  million  dollars  in  1941,  and  138  million  dollars  in  1943. 
In  addition,  tar  valued  at  about  10  million  dollars  was  burned  annually 
as  fuel.  Production  and  sales  of  these  products  in  1941-43  are  given 
in  table  4A,  and  the  manufacturers  are  identified  in  table  4B  (see 
part  II). 

The  most  marked  increase  was  in  the  output  of  toluene.  Statistics 
of  production  of  toluene  from  all  sources,  including  petroleum,  are 
combined  in  1941  and  1942  to  avoid  disclosure  of  individual  company 
operations,  and  in  1943  to  preserve  the  continuity  of  the  data.  In 
normal  times  production  ranges  between  20  million  and  25  million 
gallons  annually.  As  toluene  is  the  raw  material  for  the  manufacture 
of  one  of  the  most  important  explosives,  trinitrotoluene,  its  production 
from  all  sources  was  pushed  to  the  limit  of  the  Nation's  capacity. 
Production  from  coal  tar,  water-gas  tar,  and  oil-gas  tar  was  inade- 
quate to  satisfy  military  demands  for  toluene;  consequently  its  manu- 
facture from  petroleum  by  a  number  of  different  processes  was  under- 
taken during  1941-43,  chiefly  with  newly  constructed  facilities.  Out 
of  a  total  of  96  million  gallons  produced  in  1943  at  plants  other  than 
Ordnance  plants, 'about  58  million  gallons  was  from  petroleum.  If 
Ordnance-operated  plants  were  included,  the  total  output  would  be 
vastly  larger. 

A  striking  decrease  is  shown  in  the  production  of  motor  benzene 
during  the  period  covered  by  this  report;  output  dropped  from  113 
million  gallons  in  1941  to  69  million  in  1942,  and  to  24  million  in  1943. 
Motor  benzene  is  a  mixture  of  crude  benzene  and  toluene,  and  in  1942 
and  1943  both  of  these  products  were  in  demand  for  indirect  war  uses. 
Although  benzene  is  one  of  the  basic  materials  needed  in  the  production 
of  cyclic  intermediates  for  a  large  number  of  chemicals,  the  sharp  in- 
crease in  demand  for  high-grade  benzene  was  due  largely  to  its  con- 
version to  cumene  and  styrene.  (The  GR-S  type  synthetic  rubber  is 
made  up  of  about  25  percent  styrene,  and  cumene  is  used  in  aviation 
fuel.)  Other  major  uses  of  benzene  are  in  the  manufacture  of  phenol, 
anihne,  monochlorobenzene,  acetanilide,  and  other  benzenoid  inter- 
mediates consumed  in  the  plastics  materials,  explosives,  dye,  phar- 
maceutical, and  other  industries.  At  present  it  is  practicable  to  obtain 
benzene  from  petroleum  sources  only  in  small  quantities. 

Naphthalene,  another  coal-tar  crude,  finds  important  use  in  the 
manufacture  of  synthetic  resins,  dyes,  and  moth  repellents.  About 
one-third  of  the  naphthalene  is  recovered  at  byproduct  coke-oven 
plants,  and  the  remainder,  at  tar-distilling  plants;  very  little  is  re- 
covered at  water-  or  oil-gas  tar  plants.  The  upturn  in  consumption  of 
naphthalene,  which  became  apparent  in  1939  and  has  continued  ever 
since,  is  due  chiefly  to  the  large  increase  in  consumption  of  phthalic 


12 


UNITED  STATES  TARIFF  COMMISSION 


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SYNTHETIC  ORGANIC  CHEMICALS,  1941-43  13 

anhydride,  which  is  made  from  naphthalene.  Phthalic  anhydride,  in 
turn,  is  used  in  making  plasticizers  and  certain  types  of  alkyd  resins 
for  protective  coatings.  In  1941,  production  of  crude  naphthalene 
was  198  million  pounds,  nearly  twee  as  much  as  the  average  for 
1936-40.  It  rose  to  251  million  pounds  in  1942  and  to  305  million  in 
1943.  During  this  period  facilities  for  producing  naphthalene  were 
expanded,  and  more  efficient  recovery  methods  were  adopted.  Never- 
theless, the  demand  for  naphthalene  continued  to  exceed  productive 
capacity,  especially  in  the  latter  part  of  1943  after  new  capacity  for 
the  production  of  phthalic  anhydride  came  into  operation.  Naphthalene 
and  phthalic  anhydride  were  placed  under  allocation  control  in  1942. 

Crude  naphthalene  is  produced  in  several  grades  based  on  the 
solidifying  temperatures,  the  better  grades  solidifying  at  the  higher 
temperatures.  In  the  statistics  reported  for  naphthalene,  some 
pyramiding  of  data  results  from  the  conversion  of  one  grade  to  another 
by  fractional  distillation  and  blending. 

Crude  creosote  oil  is  a  name  somewhat  loosely  applied  to  a  mixture 
of  certain  middle-  and  heavy-oil  distillates.  This  mixture  may  contain 
some  cresol,  xylenol,  and  their  homologues;  naphthalene;  and  anthra- 
cene in  various  proportions.  Frequently,  creosote  oil  is  made  by 
blending  middle  and  heavy  oils  after  most  of  the  tar  acids  and  naphtha- 
lene have  been  removed;  it  is  also  blended  from  several  distillate  frac- 
tions to  meet  certain  specifications  or  to  satisfy  customer  preferences. 
The  principal  end  use  of  creosote  oil  is  as  a  preservative  of  wood. 
About  70  million  gallons  of  domestic  distillate  creosote  and  70  million 
gallons  of  creosote  in  coal-tar  solution  are  used  annually  for  this 
purpose;  smaller  quantities  are  used  for  insecticides  and  germicides. 
The  output  of  creosote  oil  increased  from  144  million  gallons  in  1941 
to  175  miUion  in  1942  and  in  1943,  partly  in  response  to  the  increased 
demand  for  treatment  of  railroad  ties,  wood  piling,  balks,  and  tele- 
phone poles. 

Production  of  pyridine  at  byproduct  plants  in  1943  was  586,000 
gallons,  which  was  more  than  twice  the  1941  production  of  277,000 
gallons.  This  quantity  is  small  compared  with  that  of  many  other 
crudes;  nevertheless  pyridine  is  important  as  one  of  the  raw  materials 
for  some  sulfa  drugs  and  the  important  vitamin  niacin. 

Statistics  on  tar  crudes  combine  the  data  furnished  the  United  States 
Tariff  Commission  by  distillers  of  coal  tar  and  distillers  and  producers 
of  water-  and  oil-gas  tar  with  the  data  furnished  the  Coal  Economics 
Division  of  the  U.  S.  Bureau  of  Mines  by  coke-oven  operators. 

Statistics  of  production  and  sales  of  chemical  raw  materials  derived 
from  petroleum  were  obtained  for  the  first  time  in  a  general  survey  in 
1943.  More  than  1.5  billion  pounds  of  these  chemicals  were  produced 
in  1943,  exclusive  of  fuel  for  aviation  and  other  uses.  Among  them  are 
toluene,  to  which  reference  has  already  been  made,  butadiene  for 
synthetic  rubber,  and  naphthenic  and  cresylic  acids.  A  tabulation  of 
the  production  of  these  crudes  from  petroleum,  as  reported  to  the 
Commission,  follows: 

Production 
Product  (1,000  pounds) 

Cresylic  acid 13,916 

Naphthenic  acid 17,341 

Butadiene 98,580 

Ethylene 166,id24 

Propanes 394,620 

Butanes 673,006 

All  other 201,225 


14  UNITED  STATES  TARIFF  COMMISSION 

Important  chemical  raw  materials  included  above  in  the  "all  other" 
class  (to  prevent  disclosure  of  the  operations  of  individual  companies) 
were  X3'lene,  benzene,  and  tri-isobutylene.  The  total  value  of  sales  of 
the  products  listed  above  was  reported  as  34:  million  dollars,  with  an 
average  unit  value  of  3.2  cents  per  pound.  Crudes  from  petroleum 
will  probably  increase  in  importance,  but  the  number  of  producing 
companies  in  1943  was  too  small  to  permit  disclosure  of  the  results  in 
iliuch  detail. 

Huge  quantities  of  pure  chemicals  are  used  as  automotive  and  avia- 
tion fuels  and  are  not  included  with  those  reported  for  further  chemical 
conversion.  Until  the  function  of  these  chemicals  as  a  part  of  the 
synthetic  organic  chemicals  industry  is  more  completely  delineated, 
data  for  fuel  products  will  be  omitted  from  these  reports. 

INTERMEDIATES 

The  intermediates  make  up  a  large  group  of  organic  chemicals  which 
are  in  general  derived  from  crudes  and  which  are  in  turn  used  to  pro- 
duce finished  products  such  as  dyes,  medicinals,  explosives,  synthetic 
resins,  flavor  and  perfume  materials,  and  elastomers.  Originally  the 
term  was  applied  principally  to  chemicals  of  coal-tar  origin  used  in  the 
manufacture  of  dyes.  Chemicals  now  considered  as  intermediates  may 
be  obtained  from  petroleum,  wood,  or  grain,  as  well  as  from  coal. 

In  this  report  all  cyclic  organic  chemicals  which  are  chemically 
converted  to  finished  products  are  included  among  the  cyclic  inter- 
mediates. Intermediates,  however,  are  not  confined  to  cyclic  organic 
chemicals.  Many  acyclic  chemicals  are  also  used  as  intermediates  in 
the  manufacture  of  acyclic  finished  products.  In  this  report  these  are 
included  with  acyclic  miscellaneous  organic  chemicals  as  in  previous 
reports.  In  later  reports  acyclic  intermediates  will  probably  be 
established  as  a  separate  class  in  accordance  with  the  revised  Standard 
Commodity  Classification  now  in  preparation. 

Nearly  1,000  intermediates  are  produced  annually  in  the  United 
States.  Table  5A  gives  production  and  sales  of  intermediates  for 
1941-43,  and  an  alphabetical  list  of  them  with  numbers  which  identify 
the  manufacturers  of  each  appears  in  table  5B  (see  part  II). 

The  prewar  trend  toward  increased  production  of  intermediates 
was  accentuated  after  1941.  In  1943,  production  reached  1.6  billion 
pounds,  or  more  than  twice  the  average  for  1936-40.  Sales  in  1943 
were  1  billion  pounds,  valued  at  135  million  dollars,  compared  with 
sales  of  432  million  pounds,  valued  at  64  million  dollars  in  1941.  The 
decline  in  unit  value  of  sales  from  15  cents  per  pound  in  1941  to  13 
cents  per  pound  in  1943  was  due  to  relatively  greater  increases  in  the 
sales  of  low-priced  bulk  intermediates,  such  as  aniline,  phenol,  naphtha- 
lene, phthalic  anhydride,  and  styrene.  The  ratio  of  sales  to  production 
for  intermediates  as  a  group  is  lower  than  the  similar  ratio  of  any  othef 
group;  in  other  words,  a  larger  proportion  of  intermediates  than  of 
any  other  group  is  consumed  within  the  plant  where  they  are  produced 
in  the  manufacture  of  other  products. 

The  greatest  gain  in  volume  of  production  in  1941-43  was  recorded 
for  intermediates  which  are  used  in  the  manufacture  of  products 
essential  for  military  uses  such  as  medicinals,  plastics  materials,  and 
explosives.  Large  increases  in  the  production  of  intermediates  for  the 
manufacture  of  high  explosives  and  smokeless  powder  are  not  fully 
reflected  in  this  report,  since  the  considerable  production  of  aniline, 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


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SYNTHETIC  ORGANIC  CHEMICALS,  1941-43  21 

dimethyl  aniline,  and  nitrobenzene  at  Government-owned  and  Ord- 
nance plants  is  not  included.  The  most  marked  increases  were  in  the 
production  of  acetanilide,  aniline  and  dimethylaniline,  chlorobenzene, 
0-  and  p-dichlorobenzenes,  nitrobenzene,  synthetic  phenol,  styrene, 
and  phthalic  anhydride.  Production  of  the  cresols,  refined  cresylic 
acid,  and  other  tar  acids  and  tar-acid  derivatives  did  not  increase 
greatly  during  1941-43;  the  output  of  these  intermediates  was  neces- 
sarily limited  by  the  output  of  coal  tar,  which,  as  already  shown,  did 
not  expand  much  beyond  the  1941  level. 

Production  remained  stationar}'^,  or  declined  for  most  of  the  inter- 
mediates that  are  normally  used  in  the  manufacture  of  dyes,  with  the 
exception  of  o-benzoylbenzoic  acid,  the  intermediate  used  in  the 
manufacture  of  vat  dyes.  Production  of  8.9  million  pounds  of  o-ben- 
zoylbenzoic acid  in  1943  represented  an  89-percent  increase  over  the 
4.7  million  pounds  produced  in  1941. 

The  output  of  181  million  pounds  of  synthetic  phenol  in  1943  was 
a  100-percent  increase  over  the  1941  output  of  92  million  pounds; 
sales  were  163  million  pounds  in  1943  and  61  million  in  1941.  The 
output  of  natural  phenol  became  of  less  importance,  and  decreased 
from  22  million  pounds  in  1941  to  14  million  in  1943.  The  large  in- 
crease in  the  output  of  synthetic  phenol  went  chiefly  into  the  manu- 
facture of  phenolic  resins.  The  increased  production  of  chlorobenzene, 
from  129  million  pounds  in  1941  to  221  million  in  1943,  went  chiefly 
into  the  manufacture  of  synthetic  phenol  and  aniline,  and  into 
chlorodinitrobenzene,  used  chiefly  -in  the  manufacture  of  the  high 
explosives — tetryl  and  picric  acid.  The  output  of  p-chloronitroben- 
zene  for  rubber  chemicals,  dyes,  and  gasoline  inhibitors,  and  that  of 
o-chloronitrobenzene  for  saccharin  also  increased.  Production  of  both 
o-  and  p-dichlorobenzenes  increased  chiefly  because  these  intermediates 
are  byproducts  of  the  manufacture  of  monochlorobenzene.  p-Dichloro- 
benzene  was  used  chiefly  for  large  military  requirements  for  moth- 
repellent  agents  and  as  a  substitute  for  naphthalene.  Styrene,  one  of 
the  two  principal  ingredients  of  the  GR-S  type  of  synthetic  rubber, 
was  produced  on  only  a  limited  scale  in  1941  and  1942.  In  1943, 
almost  the  entire  output,  which  rose  to  97  million  pounds,  went  to 
plants  of  the  Rubber  Reserve  Company. 

DYES 

The  United  States  production  of  dyes  amounted  to  144  million 
pounds  in  1943,  a  substantial  decrease  from  the  169  million  pounds 
in  1941.  The  record  output  in  1941  resulted  from  the  increased  demand 
for  dyes  to  meet  vital  textile  needs  of  _our  rapidly  expanding  military 
forces;  from  unusually  large  exports  as  German  supplies  were  shut 
off  by  the  British  blockade;  from  a  heavy  stock  piling  in  the  face  of 
the  impending  state  of  war;  and  from  a  lively  civilian  market  then 
unrestricted  by  Government  controls.  Lowered  production  in  1942 
and  1943  followed  War  Production  Board  Conservation  Order  M-103, 
which  restricted  deliveries  of  all  dyes  for  nonmilitary  purposes  to  70 
percent  of  those  in  1941.  Also  contributing  to  this  decreased  production 
was  the  restriction  of  the  supplies  of  many  basic  raw  materials  (ben- 
zene, phenol,  toluene,  phthalic  anhydride,  aniline)  needed  for  use  in 
civilian  dye  production. 

In  1943,  sales  of  dyes  totaled  145  million  pounds,  valued  at  105 
million  dollars;  and  in  1941,  176  million  pounds,  valued  at  113  million 


22 


UNITED  STATES  TARIFF  COMMISSION 


dollars.  Sales  were  larger  than  production  in  two  of  these  years  chiefly 
because  of  changes  in  producers'  inventories;  few  dyes  are  consumed 
at  producing  plants.  Production  and  sales  of  dyes  in  the  United  States 
in  1941-43  by  class  of  application  (vat,  direct,  sulfur,  acid,  etc.)  are 
s  jmmarized  in  tables  6  and  7. 

After  imports  from  Germany  were  cut  off  and  those  from  Switzerland 
were  substantially  reduced,  the  domestic  dye  industry  began  producing 
a  more  comprehensive  line  of  dyes.  Intensive  research  was  successfully 
directed  toward  the  domestic  production  of  superior-quality  dyes  of 
maximum  all-around  fastness,  chiefly  anthraquinone  vat  colors,  which 
can  be  applied  by  simple  and  rapid  continuous  processes.  War  re- 
quirements accelerated  the  normal  prewar  trend  toward  the  expansion 
of  production  of  vat  dyes  other  than  synthetic  indigo. 

In  1943,  production  of  vat  dyes  other  than  synthetic  indigo  totaled 
36  million  pounds,  compared  with  an  average  output  of  16  million 
pounds  in  1936-40  and  an  output  of  27  million  pounds  in  1941.  The 
ratio  of  these  dyes  to  all  dyes  produced  rose  from  15.8  percent  in  1941 
to  25.3  percent  in  1943.  This  large  gain  was  achieved  by  a  substantial 
expansion  of  the  facilities  necessary  for  their  manufacture. 

The  next  most  important  classes  of  dyes  were  direct  dyes,  sulfur 
dyes,  and  acid  dyes.  Direct  dyes  accounted  for  24  percent  of  the  total 
output  of  dyes  in  1941  and  19  percent  in  1943;  sulfur  dyes,  for  16 
percent  of  the  total  in  1941  and  14  percent  in  1943;  acid  dyes,  for  11 

Table  6. — Synthetic  organic  chemicals:  United  States  prodvction  of  coal-tar  dyes,  by  class 
of  application,  average,  1936-^0,  annual,  19^1-^3 


Class  of  application 


Average 
1936-40 


1941 


1942 


1943 


Total 

Acetate  rayon 

Acid 

Azoic 

Basic 

Direct 

Lake  and  spirit  soluble 
Mordant  and  chrome . . 
Sulfur 

Vat,  total 

Indigo 

Other 

All  other 

Total 

Acetate  rayon 

Acid 

Azoic 

Basic 

Direct 

Lake  and  spirit  soluble 
Mordant  and  chrome. . 
Sulfur 

Vat,  total 

Indigo 

other 

All  other 


Quantity  (1,000  lb.) 


114,928        168,657        151,878        144,013 


2,. 357 
15,579 
1  3,084 

5,863 
29,173 

3,071 

5,617 
18,584 

30,282 


14.213 

16,069 

1,318 


3,287 

19,324 

6,140 

8,449 

39,742 

5,220 

9,476 

27,059 

47,002 


20,. 386 

26,616 

2,958 


3,523 
16,753 

4,070 

6,811 
34,563 

4,410 
12,001 
20,629 

46,. 365 


18,9.33 

27,432 

2.753 


2,512 

14,512 

3,282 

5,502 

26,903 

7,123 

9,693 

19,561 

54,104 


17,770 

36,334 

821 


Percent  of  total  quantity 


100  0 


2  0 

13  6 

2.7 

5.1 

25  4 

2  7 

4.9 

16.2 

26.3 


12  3 

14.0 

1.1 


100.0 


1.9 

11.4 

3.6 

5.0 

23.6 

3.1 

5  6 

16  1 

27.9 


12.1 

15.8 

1.8 


lOO.O 


2  3 
11.0 
2.7 
4.5 
22  8 
2  9 
7.9 
13.6 

30.5 


12.5 

18.0 

18 


100  0 


1.7 
10  1 
2  3 
3.8 
18.7 
4.9 
6.7 
13.6 

37  6 


12.3 

25.3 

.6 


'  4-year  average. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


23 


Table  7. 


-Synthetic  organic  chemicals:  United  States  sales  of  coal-tar  dyes,  by  class  of 
application,  average,  1936-^0,  annual,  1941—43 


Class  of  application 

Average 
1936-40 

1941 

1942 

1943 

Quantity  (1,000  1b.) 

Total 

112,701 

176,801 

144,847 

145,499 

Acetate  rayon 

Acid 

2,191 
15,171 
12,915 

5,506 
28,332 

2,946 

5,450 
18,490 

30,434 

3,536 
21,986 

5,904 

8,650 
43,805 

5,500 
10,385 
27,398 

46,598 

2,916 
15,746 

4,110 

6,301 
33,513 

4,095 
10,786 
20,927 

43,833 

2,990 

15,456 

3  161 

5  365 

Direct 

28,822 
6  736 

Mordant  and  chrome 

Sulfur 

9,869 
19  542 

Vat,  total 

52  684 

Indigo 

14,267 

16,167 

1,266 

19,368 

27,230 

3,039 

17,542 

26,291 

2,620 

18  284 

Other 

34  400 

All  other 

874 

Percent  of  total  quantity 

Total 

100  0 

100  0 

100.0 

100.0 

Acetate  rayon 

2.0 

13  5 

2  6 

4.9 

25  1 

2  6 

4.8 

16.4 

27.0 

2.0 

12.4 

3.3 

4  9 

24  8 

3  1 

5.9 

15.5 

26  4 

2  0 

10.9 

2  8 

4.4 

23.1 

2.8 

7.4 

14.5 

30.3 

2  1 

10.6 

Azoic 

2.2 

3.7 

19.8 

4.6 

Mordant  and  chrome 

6  8 

13.4 

Vat,  total 

36  2 

12  7 

14  3 

1.1 

11.0 

15  4 

1.7 

12  1 

18  2 

1.8 

12  6 

Other 

23  6 

All  other 

.6 

Value  (1,000  dollars) 

Total 

66,520 

113,324 

99,431 

105,350 

Acetate  rayon 

2,259 
11,921 
14,548 
5,084 
15,690 
2,062 
2,735 
4,493 

16,573 

3,586 
18,272 
7,797 
8,115 
25,784 
4,366 
5,672 
7,115 

29,704 

2,795 
13,583 
5,648 
6,547 
20,803 
3,273 
6,305 
5,731 

32,506 

2,915 
13,579 
4,661 
5,449 
17,561 
5,478 
5,777 
4,956 

Sulfur 

Vat,  total 

43,924 

Indigo 

2,285 

14,288 

1,155 

3,011 

26,693 

2,913 

2,894 

29,612 

2,240 

2,819 
41,105 

Other 

All  other 

1,050 

Percent  of  total  value 

100.0 

100  0 

100.0 

100  0 

Acid ' '..'.'.'.'.'.'.'.'.'..'.'.'.'.'..'.'.'.'..'.'.'.'.' 

3  4 

17.9 

6  8 

7.7 

23  6 
3   1 
4.1 
6.8 

24  9 

3.2 
16.1 
6.9 
7.2 
22.7 
3.8 
5.0 
6.3 

26.2 

2  8 
13  7 

5.7 

6  6 

20.9 

3  3 
6  3 
5.7 

32  7 

2.8 
12  9 

Azoic 

4  4 

Basic 

5  2 

16  6 

Lake  and  spirit  soluble .        

5  2 

Sulfur 

5  5 

4  7 

Vat,  total 

41  7 

Indigo 

3.4 

21.5 

1.7 

2.7 

23  5 

2  6 

2.9 

29  8 

2  3 

2  7 

Other 

39  0 

All  other 

1   0 

1 4-year  average. 


24  UNITED  STATES  TARIFF  COMMISSION 

percent  of  the  total  in  1941  and  10  percent  in  1943.  Sales  of  vat, 
sulfur,  and  acid  dyes  did  not  differ  greatly  from  production.  Produc- 
tion of  direct  dyes  in  1941,  however,  totaled  40  million  pounds  and 
sales  totaled  44  million  pounds. 

Table  8  shows  dyes  classified  by  chemical  classes.  The  production 
of  azo  dyes  was  49  million  pounds  in  1943,  a  sharp  drop  from  1941, 
when  it  was  69  million  pounds.  The  output  of  most  of  the  other  groups 
also  declined,  except  anthraquinone  vat  dyes  and  xanthene  dyes. 
The  output  of  anthraquinone  vat  dyes  expanded  because  they  were 
used  in  the  dyeing  of  uniforms,  canvas,  and  other  textiles  used  by  the 
military  forces. 

Statistics  of  production  and  sales  of  azoic  dyes  are  shown  in  table  9. 
Production  amounted  to  3.2  million  pounds  in  1943,  a  drop  of  47 
percent  from  the  output  of  6.1  million  pounds  in  1941.  Sales  of  azoic 
dyes  were  3  million  pounds,  valued  at  4.7  million  dollars,  in  1943  com- 
pared with  6  million  pounds,  valued  at  7.8  million  dollars,  in  1941.  The 
War  Production  Board  limitation  order,  as  well  as  shortages  of  raw 
materials,  affected  the  production  of  these  dyes,  since  they  are  of  im- 
portance principally  for  civilian  use.  In  general,  producers  of  dyes 
chose  to  use  their  share  of  critical  intermediates  as  well  as  their  equip- 
ment, for  the  manufacture  of  the  more  widely  used  staple  colors  having 
more  complete  ranges  of  shade.  Manpower  considerations  also  favored 
the  manufacture  of  staples,  which  are  made  in  larger  batches  than  the 
azoics.  The  same  combination  of  factors  also  accounts  for  the  war- 
time drop  in  production  of  those  dyes  for  which  statistics  are  not 
separately  shown.  Most  of  these  dyes  are  normally  made  in  small 
quantities  for  specialized  uses. 

Statistics  for  individual  dyes  which  are  combined  in  summary  tables 
6  to  9,  are  given  separately  in  table  lOA,  and  an  alphabetical  list  with 
identity  of  manufacturers  is  shown  in  table  lOB  (see  part  II).  They 
are  grouped  according  to  Colour  Index  number  or  Foreign  Prototype 
number,  or  are  listed  as  ungrouped  dyes.  In  former  reports  the  dyes 
classified  by  Foreign  Prototype  number  and  the  ungrouped  dyes  were 
combined  as  unclassified  dyes. 

In  1943,  the  output  of  dyes  classified  by  Co.lour  Index  number  was 
107  million  pounds;  sales  were  109  million  pounds,  valued  at  60  million 
dollars.  In  1941,  production  of  these  dyes  was  137  million  pounds; 
sales  were  144  million  pounds,  valued  at  75  million  dollars.  Production 
of  dj^es  which  have  a  recognized  foreign  equivalent  (protot^'pe) 
amounted  to  20.1  million  pounds  in  1943,  compared  with  14.9  million 
pounds  in  1941.  The  increase  of  35  percent  for  the  group  may  be  some 
indication  that  an  increasing  number  of  dyes,  of  kinds  imported  before 
the  war,  are  now  being  made  by  domestic  producers. 

The  output  of  dyes  listed  as  ungrouped  increased  in  1942  but 
declined  in  1943.  Production  was  16.8  million  pounds  in  1943,  18.1 
million  in  1942,  and  16.8  million  in  1941.  Sales  were  17  million  pounds, 
valued  at  20  million  dollars,  in  1943;  and  17.6  million  pounds,  valued  at 
18.6  million  dollars  in  1941.  Acetate  rayon  dyes  were  the  most  impor- 
tant ungrouped  dyes,  followed  by  Developed  black  and  Zambesi  black. 

In  1941  the  average  unit  sales  value  of  all  dyes  was  64  cents  per 
pound;  in  1943  it  was  72  cents.  Appreciable  increases  occurred  in  the 
unit  value  of  pyrazolone,  triphenylmethane,  and  azoic  dyes  and  their 
components. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


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36  UNITED  STATES  TARIFF  COMMISSION 

LAKES  AND  TONERS 

Lakes  and  toners  are  used  to  color  paints  and  varnishes,  wallpapers, 
printing  inks,  plastics,  and  other  ^industrial  products.  Lakes  are 
organic  pigments  prepared  by  precipitating  a  soluble  dye  on  the 
surface  of  an  inorganic  compound,  known  as  the  substrate.  Toners, 
or  full-strength  colors,  are  insoluble  organic  pigments.  Reduced  or 
extended  toners  are  toners  to  which  a  solid  diluent  has  been  added. 
Table  11 A  gives  production  and  sales  of  lakes  and  toners,  1941-43. 
Statistics  not  publishable  as  individual  items  have  been  classified  as 
far  as  possible  in  color  groups.  Phosphomolybdic  acid  and  phospho- 
tungstic  acid  compounds,  formerly  classified  as  lakes,  have  been  re- 
classified as  reduced  toners.  An  alphabetical  list  of  lakes  and  toners, 
identifying  the  manufacturer  of  each,  appears  in  table  IIB,  which  is 
in  part  XL 

The  production  and  sales  of  lakes  and  toners  since  1941  has  followed 
the  same  trend  as  those  of  dyes.  Production  in  1941  reached  a  record 
of  26  million  pounds.  In  1942,  output  decreased  sharply  to  17  million 
pounds;  in  1943,  it  was  16  million  pounds.  Sales  in  1941  were  24  mil- 
lion pounds,  valued  at  19  million  dollars;  in  1943  they  were  15  million 
pounds,  valued  at  10.3  million  dollars.  The  average  unit  sales  value 
of  lakes  and  toners  was  77  cents  in  1941  and  69  cents  in  1943. 

The  considerable  increase  in  output  of  lakes  and  toners  in  1941  was 
due  in  part  to  heavy  stock  piling  by  consuming  industries,  to  greater 
civilian  consumption  caused  by  generally  accelerated  business  activity, 
and  to  an  increased  consumption  of  pigments  for  military  purposes. 
In  1942-43,  the  large  military  demand  for  munitions,  dyes,  and  plastics 
made  from  such  crudes  and  intermediates  as  benzene,  toluene,  naphtha- 
lene, anthracene,  and  phthalic  anhydride  tightened  the  supply  of  these 
chemicals  normally  available  for  use  in  the  manufacture  of  lakes  and 
toners.  In  order  to  insure  equitable  distribution  of  existing  supplies, 
WPB  Conservation  Order  M-53,  issued  in  1942,  limited  the  use  of 
organic  pigments  in  printing  inks  to  70  percent  of  that  in  1941,  and 
Conservation  Order  M-103  limited  the  use  of  dyes  and  organic  pig- 
ments in  nonmilitary  uses  to  70  percent  of  that  consumed  in  1941.  The 
growing  shortage  of  paper  contributed  further  to  the  decreased  con- 
sumption of  organic  pigments  in  printing  inks  and  wallpapers.  The 
most  marked  decreases  in  production  were  shown  by  helio  fast  rubine, 
eosine  and  phloxine  lakes,  pigment  scarlet,  fast  light  j'ellow,  maroon 
toners,  and  purple  toners. 

MEDICINALS 

Production  and  sales  of  all  synthetic  organic  medicinals  are  shown 
in  table  12A,  and  an  alphabetical  list,  with  the  identity  of  manufac- 
turers, is  shown  in  table  12B  (see  part  II).  To  avoid  duplication  in 
the  figures,  all  data  are  given  in  terms  of  medicinals  in  bulk.  The 
sales  value  of  medicinals  in  the  form  of  tablets,  ampoules,  perles,  or 
other  finished  forms  is  much  larger  than  the  value  of  sales  of  the  same 
medicinals  in  bulk  form. 

In  this  report  the  statistics  are  divided  into  several  subgroups: 
Cyclic  benzenoid  compounds  (usually  derived  from  coal  tar) ;  alicyclic 
and  heterocyclic  compounds  (which  may  be  derived  from  coal  tar  or 
from  other  sources,  as  terpenes  from  wood,  hormones  from  cholesterol) ; 
and  acyclic  compounds  (derived  from  natural  gas,  petroleum,  coal,  or 
grain  by  fermentation).    The  products  of  each  group  differ  chemically 


i 


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40  UNITED  STATES  TARIFF  COMMISSION 

and  pharmacologically,  and  these  statistical  subdivisions  provide  more 
information  concerning  different  classes  of  compounds  than  those  pre- 
sented in  former  reports  on  these  chemicals. 

Synthetic  organic  medicinals  are  essential  to  the  militar^^  forces. 
The  total  output  of  all  synthetic  medicinals  reached  a  record  high  of 
56  million  pounds  in  1943,  compared  with  34  million  in  1941.  Sales  in 
1943  totaled  52  million  pounds,  valued  at  140  million  dollars;  and  in 
1941,  29  million  pounds,  valued  at  59  million  dollars.  The  average 
unit  sales  value  of  synthetic  medicinals  was  34  percent  greater  in  1943 
than  in  1941,  owing  principally  to  increased  sales  of  higher  priced 
items. 

The  record  output  of  these  war  years  resulted  from  a  combination 
of  factors — a  large  civilian  demand  for  vitamin  products,  the  flour- 
enrichment  program,  and  purchases  by  the  Army  and  Lend-Lease. 
Restrictions  on  the  use  of  several  of  the  raw  materials  (benzene, 
phenol,  toluene)  did  not  depress  the  total  output  of  synthetic  medici- 
nals, partly  because  most  medicinals  were  rated  high  in  the  allocation 
program  and  sufficient  crudes  and  intermediates  for  their  manufacture 
were  allotted.  The  output  of  medicinals  was  also  raised  by  increased 
productive  efficiency  and  the  installation  of  new  facilities.  To  supply 
the  requirements  of  Latin  American  countries,  production  of  several 
medicinal  chemicals,  formerly  imported  by  them  from  Germany,  was 
initiated  in  the  United  States,  and  substantial  quantities  were  ex- 
ported to  those  countries. 

Cyclic  medicinals  accounted  for  approximately  93  percent  of  total 
production  of  all  organic  medicinals  in  1941-43.  Based  on  raw-material 
classification,  benzene,  its  homologues,  and  phenol-derived  compounds 
furnished  between  60  and  68  percent  of  the  total  material  for  cyclic 
medicinals. 

The  output  of  sulfa  drugs  in  1943  was  five  times  that  in  1941  and  for 
the  first  time  topped  that  of  acetylsalicylic  acid  (aspirin).  In  that 
year,  production  of  the  sulfa  drugs  totaled  10  million  pounds;  sales 
totaled  8.8  million  pounds,  valued  at  36.7  million  dollars.  The  average 
unit  sales  value  gradually  decreased  from  .^4.83  ])er  pound  in  1941  to 
$4.17  per  pound  in  1943. 

The  total  value  of  all  bulk  vitamins  sold  in  1943  was  61  million 
dollars,  or  more  than  twice  the  value  in  1941.  Consumption  of  nia- 
cinamide (nicotinic  acid  amide),  which  is  the  antipellagra  vitamin  and 
one  of  the  three  vitamins  required  in  the  national  flour-and-l)read- 
enrichment  program,  showed  tremendous  growth.  Sales  increased 
from  21,000  pounds  in  1941  to  214,000  pounds  in  1943.  With  in- 
creased production,  the  unit  sales  value  has  gradually  decreased  from 
$19.35  per  pound  in  1941  to  $6.41  in  1943.  Vitamin  B2  (riboflavin) 
for  human  consumption  is  another  vitamin  produced  on  a  large  scale, 
in  spite  of  a  complex  synthesis  Avhich  involves  from  10  to  15  distinct 
steps.  Output  jumped  from  3,000  pounds  in  1941  to  72,000  pounds 
in  1943.  In  1943,  production  of  all  acyclic  vitamins  reached  777,000 
pounds,  and  sales  782,000  ])ounds,  valued  at  15  million  dollars.  The 
vitamins  included  in  this  classification  are  principally  ascorbic  acid, 
pantothenic  acid,  and  their  salts. 

Acetylsalicylic  acid  (aspirin)  was  the  single  synthetic  medicinal  pro- 
duced in  the  largest  quantity  during  1941-43.  Output  totaled  8.1 
million  pounds  in  1941  and  8.7  million  in  1943.  The  unit  sales  value 
dropped  from  44  cents  per  pound  in  1941  to  39  cents  in  1943.  Salicylic 
acid,  the  second  most  important  single  medicinal,  slightly  decreased 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


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in  production  from  5.3  million  pounds  in  1941  to  5.1  million  in  1943, 

Alicyclic  and  heterocyclic  medicinals,  which  increased  in  output 
from  8.3  million  pounds  in  1941  to  18.5  million  in  1943,  represent  a 
classification  used  for  the  first  time  in  the  Commission's  series  of  reports 
on  synthetic  organic  chemicals.  It  includes  compounds  obtained  by 
synthesis  from  heterocyclic  raw  materials  such  as  pyridine,  quinoline, 
and  other  products  made  from  starting  materials  such  as  ox  bile, 
cholesterol,  and  other  natural-occurring  substances. 

Quinacrine  hydrochloride,  commonly  referred  to  by  its  trade-marked 
name  "Atebrin,"  is  the  principal  synthetic  antimalarial  used  by  our 
armed  forces.  Without  this  substitute  for  quinine,  military  losses  from 
malaria  would  probably  have  been  extremely  serious.  Data  on  pro- 
duction, which  totaled  466,000  pounds  in  1943,  are  shown  for  the  first 
time  in  this  report.  Sales  in  that  year  were  504,000  pounds,  valued 
at  6  million  dollars. 

Barbituric  acid  derivatives  represent  an  important  subgroup  of  the 
heterocyclic  chemicals.  Production  totaled  531,000  pounds  in  1941, 
rose  to  607,000  pounds  in  1942,  but  dropped  to  583,000  pounds  in  1943. 
The  most  important  of  these  derivatives  were  5-ethyl-5-phenylbar- 
bituric  acid  and  its  sodium  salt. 

Production  of  all  acyclic  medicinals  totaled  2.9  million  pounds  in 
1941  and  4.1  million  pounds  in  1943.  Ethyl  nitrite,  iodoform,  and 
amino  acids  were  the  principal  acyclic  medicinals,  other  than  the 
acyclic  vitamins  already  mentioned. 

FLAVOR  AND  PERFUME  MATERIALS 

The  flavor  and  perfume  materials  included  here  are  organic  chemi- 
cals synthesized  from  natural  crude  materials  or  from  cyclic  or  acyclic 
chemical  intermediates;  floral  extracts  or  flavors  obtained  by  extrac- 
tion or  distillation  from  natural  substances  are  not  included.  Statistics 
of  production  and  sales  of  these  artificial  flavor  and  perfume  materials 
are  shown  in  table  13A.  An  alphabetical  list  of  them,  identifying  the 
manufacturer  of  each,  appears  in  table  l^B  in  part  II. 

In  general,  the  products  in  this  section  do  not  reach  the  ultimate 
consumer  as  chemicals  but  are  blended  with  solvents  and  fixatives,  or 
are  compounded  according  to  various  formulas  by  producers  or  dis- 
tributors. This  group  of  synthetic  chemicals  comprises  a  larger  pro- 
portion of  chemicals  derived  from  terpenes — wood-distillation  prod- 
ucts— than  any  other  group.  For  the  first  time  in  this  series  of  reports, 
flavor  and  perfume  materials  are  divided  into  three  principal  classes, 
benzenoid  (generally  of  coal-tar  origin),  terpenoid  (generally  not  of 
coal-tar  origin),  and  acyclic  (non-coal-tar)  compounds.  This  classifi- 
cation allows  the  publication  of  statistics  not  heretofore  available, 
showing  totals  of  important  classes  of  flavor  and  perfume  materials. 
Since  their  major  use  is  no  longer  as  perfume  materials,  products  such 
as  dipentene,  diphenyl  oxide,  and  secondary  capryl  alcohol,  which 
former  reports  included  in  the  totals  for  flavor  and  perfume  materials, 
have  been  reclassified  and  added  to  the  total  for  other  groups.  Dipen- 
tene is  now  listed  among  the  intermediates;  and  diphenyl  oxide  and 
secondary  capryl  alcohol  are  listed  among  the  miscellaneous  finished 
products. 

During  1941-43,  production  of  flavor  and  perfume  materials  was 
hampered  by  lack  of  raw  materials  derived  from  coal  tar,  which  were 
diverted  to  more  essential  uses.    It  was  hampered  also  by  lack  of  cer- 


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°  S       -3 


50  UNITED  STATES  TARIFF  COMMISSION 

tain  imported  raw  materials.  On  the  other  hand,  demand  increased 
because  of  higher  national  income,  a  greater  substitution  of  synthetic 
flavor  and  perfume  materials  for  natural  products,  imports  of  which 
were  limited  by  war  conditions,  and  use  of  certain  flavoring  materials 
in  military  rations. 

Production  of  artificial  flavor  and  perfume  materials  reached  a 
maximum  in  1942  of  15.4  million  pounds;  sales  were  13.8  million 
pounds,  valued  at  18  million  dollars.  In  1943,  production  and  sales 
both  fell  to  13.2  million  pounds  produced  and  sold,  with  sales  valued 
at  15.8  million  dollars.  In  both  years,  production  and  sales  were 
double  the  average  for  1936-40.  Benzenoid,  terpenoid,  and  hetero- 
cj'clic  flavor  and  perfume  materials  made  up  over  70  percent  of  the 
total  of  this  group,  benzenoid  compounds  alone  accounting  for  about 
50  percent. 

The  most  important  of  the  benzenoid  compounds  was  methyl 
salicylate,  an  artificial  wintergreen  flavor,  used  in  confectioner^^  and 
pharmaceutical  products.  Production  in  1941-43  averaged  about  2.5 
million  pounds  and  sales,  2.6  million,  with  a  value  of  $798,000.  Cinna- 
maldehyde,  used  to  make  artificial  cinnamon,  made  important  gains 
owing  to  the  scarcity  of  imported  cinnamon;  sales  of  cinnamaldehj'de 
totaled  339,000  pounds  in  1943,  an  increase  of  122  percent  over  the 
1941  sales  of  153,000  pounds. 

Production  of  the  terpenoids,  the  next  most  important  class  of  flavor 
and  perfume  materials,  declined  in  1943  to  50  percent  of  that  in  1941; 
sales  declined  to  60  percent,  or  by  1.3  million  pounds.  Most  of  the 
decline  occurred  in  1943.  These  decreases  were  accompanied  by  an 
increase  in  average  unit  value  from  $1.59  per  pound  in  1941  to  $1.98 
in  1943.  These  changes  were  undoubtedly  due  largely  to  the  scarcity 
of  imported  citronella  and  lemon-grass  oils.  These  are  raw  materials 
for  producing  items  such  as  menthol,  geraniol  and  its  derivatives, 
citronellol,  and  numerous  other  aldehydes  and  ketones  used  as  perfume 
materials.  Production  in  1942  was  maintained  to  a  certain  extent  by 
withdrawal  of  stocks  imported  in  anticipation  of  shipping  difficulties 
in  the  Pacific. 

Among  the  heterocyclic  flavoring  and  perfume  compounds  of  im- 
portance, synthetic  coumarin  had  declined  about  one-third  in  output 
in  1943  as  compared  with  1941.  Saccharin,  a  substitute  sweetening 
agent,  increased  in  output. 

The  acyclic  flavor  and  perfume  materials  consist  chiefly  of  synthetic 
alcohols,  aldehydes,  ketones,  and  esters.  Statistics  concerning  the 
principal  item,  monosodium  glutamate,  cannot  be  shown.  It  is  used 
to  accentuate  the  flavor  of  meat  and  certain  vegetables  and  at  present 
is  manufactured  to  a  considerable  extent  for  use  in  army  rations. 

PLASTICS  MATERIALS 

Plastics  materials  consist  of  synthetic  resins  and  cellulose  com- 
pounds, used  to  manufacture  plastic  products.  During  most  of  the 
period  1941-43,  the  output  of  plastics  materials  was  principally  for 
direct  and  indirect  military  purposes.  The  phenolic,  urea,  and  mela- 
mine  types  are  used  in  the  construction  of  airplanes,  tanks,  trucks, 
and  submarines,  and  their  parts;  acyclic  resins  go  into  airplane  turrets, 
and  instruments,  windows,  gages,  and  surgical  appliances;  vinyl 
polymers,  into  electrical  equipment,  cables,  glass  substitutes,  and 
chemical-resistant  tubing;  and  phthalic  and  other  alkyd  resins,  into 
protective  coatings  to  be  used  under  extreme  conditions. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43  51 

Most  of  the  synthetic  resins,  such  as  urea,  melamine,  phenols, 
acryhc,  phthalic,  polystyrene,  polyvinyl  resins,  and  ethyl  cellulose, 
were  subject  to  allocation  by  the  War  Production  Board  in  1943,  and 
most  of  the  raw  materials  used  in  their  manufacture  were  also  allo- 
cated in  1942  and  1943.  The  quantities  of  these  materials  produced 
were  therefore  determined  by  the  essentiality  of  the  products  made 
from  them  and  the  availability  of  the  raw  materials  from  which  they 
were  made. 

Statistics  of  production  and  sales  of  plastics  materials  in  this  section 
are  in  terms  of  the  net  resin  content  and  do  not  include  materials  used 
as  additives  or  fillers.  In  plastics  materials  such  as  alkyd  resins  (poly- 
basic  acid-polyhydric  alcohol-oil  combinations)  the  portion  of  the  oil 
which  is  combined  chemically  with  the  rest  of  the  product  is  considered 
part  of  the  resin.  Plastics  materials  converted  to  elastomers  ^  by  the 
addition  of  plasticizers,  or  possessing  properties  of  an  elastomer,  are 
discussed  in  a  subsequent  section.  Since  statistics  for  some  of  the 
polj'vinyl  elastomers  were  not  collected  separately  in  1941  and  1942, 
they  are  combined  with  the  totals  for  plastics  materials  in  these  years. 

Production  and  sales  of  plastics  materials  are  shown  in  table  14A. 
The  table  groups  these  materials  in  two  ways — by  chemical  composi- 
tion and  by  use.  Table  14B  (part  II)  lists  plastics  materials  alpha- 
betically and  identifies  the  manufacturers. 

The  volume  of  production  and  sales  of  all  plastics  materials  in  1943 
was  the  largest  on  record;  production  was  654  million  pounds  and  sales 
were  568  million  pounds,  valued  at  178  million  dollars.  Of  the  total 
produced,  381  million  pounds  represented  cyclic  (benzenoid)  materials. 
In  1942,  production  of  cyclic  resins  was  14.5  percent  below  the  345 
million  pounds  produced  in  1941,  owing  principally  to  the  shortage  of 
phenol.  Output  of  acyclic  ^  plastics  materials  totaled  273  million 
pounds  in  1943,  or  almost  three  times  that  in  1941. 

Sales  of  cyclic  plastics  materials  for  the  3-year  period  represented 
about  85  percent  of  production;  those  of  acyclic  plastics  represented 
about  90  percent  of  production.  Although  the  quantity  of  acyclic 
materials  sold  was  much  less  than  that  of  cyclic  materials,  their  total 
value  was  nearly  equal  to  that  of  the  cyclic  materials,  owing  to  their 
higher  unit  value.  The  average  unit  value  for  the  3-year  period  was 
50  cents  per  pound  for  acyclic  materials,  compared  with  26  cents  for 
the  cyclic  materials. 

The  phthalic  alkyd  resins  are  the  most  important  of  the  cyclic  group 
in  terms  of  quantity,  and  the  phenol-formaldehyde  resins  in  terms  of 
value.  In  1943,  the  output  of  phthalic  alkyd  resins  was  155  million 
pounds,  compared  with  101  million  pounds  in  1942  and  138  million  in 
1941.  The  lower  output  in  1942  was  due  to  a  shortage  of  naphthalene 
in  that  year.  The  wartime  demand  for  alkyd  resins  of  all  types,  in- 
cluding the  acyclic  maleic  anhydride  type,  has  exceeded  available 
supplies  and  productive  capacity  because  of  the  extreme  conditions 
of  weather  and  temperature  which  surface  coatings  must  meet  in  mili- 
tary uses.  Sales  of  phthalic  alkyd  resins  in  1943  were  125  million 
pounds,  valued  at  24  milHon  dollars;  in  1941,  they  were  68  million 
pounds,  valued  at  14  milHon  dollars.  The  apparent  increase  in  sales 
from  about  50  percent  of  reported  production  in  1941  to  about  81  per- 
cent in  1943  reflects  not  only  more  actual  sales  by  producers  but  also 

1  An  elastomer  is  defined  as  a  material  that  will  stretch  repeatedly  to  at  least  150  percent  of  its  original 
dimension  and  will  return  rapidly  and  with  force  to  its  approximate  original  shape. 

5  Data  for  small  amounts  of  heterocyclic  and  alicyclic  plastics  materials  are  included  with  those  given 
for  acyclic  materials. 


52 


UNITED  STATES  TARIFF  COMMISSION 


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SYNTHETIC  ORGANIC  CHEMICALS,  1941-43  55 

more  accurate  reporting  of  intracompany  transfers  with  sales,  and 
the  more  complete  reporting,  under  sales  of  alkyd  resins,  of  the  alkyd 
resin  content  of  surface  coatings  sold  by  producers  of  alkyd  resins. 

Phenolic  resins,  principally  of  the  cresols-formaldehyde  and  phenol- 
formaldehyde  types,  and  mixed  phenolic  resins,  such  as  the  cresols- 
and  xylenols-alclehyde  type  and  the  phenol-  and  cresols-aldehyde  type 
are  capable  of  withstanding  heat  and  shock.  When  used  for  molding 
and  laminating,  they  usually  contain  considerable  quantities  of  fillers 
or  additives  so  that  the  weight  of  the  resin  also  used  would  be  con- 
siderably greater  than  the  net  resin  content  reported  in  table  14A. 

Tar  acid  (mixed  phenolic)  resins  are  less  important,  in  terms  of 
quantity  produced  and  value  of  sales,  than  phenolic  resins  containing 
one  phenolic  constituent.  In  1943,  about  20  million  pounds  were  pro- 
duced, compared  with  148  million  pounds  of  phenolic  resins.  The  ap- 
parent decrease  in  output  of  mixed  phenolic  resins  from  about  49  mil- 
lion pounds  in  1941  and  1942,  as  well  as  the  decrease  in  unit  value  per 
pound  from  56  to  21  cents,  is  due  in  part  to  the  reclassification  by 
producers  of  part  of  the  material  formerly  reported  as  tar-acid  resins 
(mixed  phenolics)  to  phenolic  condensation  resins. 

Phenolic  resins  containing  a  single  phenolic  constituent  consist 
principally  of  the  phenol-formaldehyde  type,  which,  in  1943,  accounted 
for  125  million  pounds  out  of  the  total  of  148  million  for  all  phenolic 
resins.  This  quantity  represents  a  gain  of  38  million  pounds  over  1942 
and  of  26  million  pounds  over  1941.  The  decrease  in  1942  may  be  ex- 
plained by  the  shortage  of  phenol  for  plastics  materials,  whereas  addi- 
tional supplies  of  synthetic  phenol  in  1943  made  possible  the  1943 
recovery  in  production.  Sales  of  phenolic  resins  each  year  averaged 
about  10  million  pounds  less  than  production.  Sales  were  valued  at 
43  million  dollars  in  1943,  compared  with  about  31  million  in  1942 
and  in  1941. 

Of  the  cyclic  polymerization  resins,  polystyrene  and  coumarone- 
indene  resins  are  among  the  most  important,  in  terms  of  value  of  trade. 
Polystyrene  resins  have  unusually  good  optical  and  electrical  properties 
and  are  used  chiefly  as  special-purpose  resins.  The  raw  material  for 
polystyrene  resins  is  styrene,  also  used  in  the  most  important  type  of 
synthetic  rubber.  Production  of  polystyrene  resins  in  1941-43  was, 
therefore,  limited  by  plant  equipment  and  raw  materials.  Coumarone- 
indene  resins  are  produced  in  large  volume  and  are  used  to  a  consider- 
able extent  for  chemical-resistant  coatings. 

Output  and  sales  of  all  acyclic  resins  were  in  1943  roughly  three  times 
those  in  1941.  The  value,  hoAvever,  was  only  about  twice  that  in  1941, 
owing  to  a  drop  in  the  average  unit  value.  Production  of  52  million 
pounds  of  acvclic  alkyd  resins  in  1943  was  240  percent  above  that 
of  1941. 

The  largest  single  use  of  plastics  materials  is  in  protective  coatings; 
the  next  largest  is  for  molding  and  casting.  In  1943,  about  50  percent 
of  the  production  of  the  benzenoid  type  of  resins  was  for  protective 
coatings  (largely  alkyd  resins);  20  percent  for  molding  and  casting; 
13  percent  for  laminating;  and  the  remainder  for  adhesives,  textiles, 
and  miscellaneous  uses.  Of  the  acyclic  type  of  plastics  materials,  21 
percent  was  produced  for  protective  coatings;  20  percent  for  molding 
and  casting;  17  percent  for  adhesives;  7  percent  for  textiles;  5  percent 
for  laminating;  and  the  remaining  30  percent  for  miscellaneous  uses. 
The  large  increase  in  the  use  of  acyclic  resins  for  adhesives  in  1943  to 
nearly  eightfold  the  1942  figure,  was  probably  due  to  its  expanded  use 


56  UNITED  STATES  TARIFF  COMMISSION 

as  a  plywood  adhesive.  Since  some  resins  sold  for  adhesive  purposes 
may  be  used  by  purchasers  for  laminating,  the  distinction  in  use  is  not 
entirely  clear. 

RUBBER  CHEMICALS 

Synthetic  organic  chemicals  are  incorporated  into  rubber  to  control 
vulcanization  (accelerators),  to  improve  the  aging  properties  (anti- 
oxidants), and  to  impart  certain  characteristics  to  synthetic  rubber  in 
order  to  make  it  more  comparable  to  the  natural  product  (tackifiers). 
All  these  are  known  as  rubber  chemicals.  They  do  not  include  the 
basic  materials  for  the  manufacture  of  synthetic  rubber.  These  ma- 
terials are  dealt  with  in  the  section  of  this  report  on  intermediates  and 
on  miscellaneous  chemicals.  Synthetic  rubber  is  discussed  in  the 
section  on  elastomers. 

The  quantity  and  kind  of  organic  chemicals  used  in  compounding 
vary  with  the  type  of  rubber  products  made,  the  quantity  and  kind 
of  rubber  compounded,  and  advances  in  the  techniques  of  compound- 
ing. Table  15A  gives  production  and  sales  of  rubber  chemicals  for 
1941-43,  and  table  15B  (see  part  II)  Hsts  these  chemicals  alphabeti- 
cally, identifying  the  manufacturer  of  each. 

Production  totaled  a  record  81  million  pounds  in  1943,  an  increase 
of  21  million  pounds  over  the  60  million  pounds  of  1941 — the  previous 
high.  Sales  also  reached  a  record  high  of  77  million  pounds,  valued  at 
31  million  dollars,  in  1943.  The  large  gain  in  the  manufacture  of  rubber 
products  for  direct  military  use,  together  with  the  larger  use  of  syn- 
thetic rubber,  accounts  for  the  larger  production  and  sales  of  these 
chemicals  in  1943.  The  smaller  production  and  sales  of  rubber  chemi- 
cals in  1942  compared  with  1941  reflected  reduced  production  of  rubber 
products  in  the  United  States  during  that  year.  Severe  limitations 
had  been  placed  on  use  of  natural  rubber,  and  the  output  of  synthetic 
rubber  was  still  low. 

Rubber  chemicals  derived  from  benzene  and  its  homologues  con- 
stituted 71  to  76  percent  of  the  total  production.  Output  of  these 
chemicals,  which  include  both  cyclic  accelerators  and  antioxidants, 
reached  62  million  pounds  in  1943,  after  a  decrease  in  1942  from  the 
previous  high  of  43  million  pounds  produced  in  1941. 

The  cyclic  accelerators  are  listed  here  according  to  subgroup  head- 
ings for  the  first  time  in  this  series  of  reports.  Data  are  shown  for  all 
the  important  subgroupings  except  for  mercaptobenzothiazole  and 
derivatives,  which  have  been  included  under  the  designation  "All  other 
accelerators"  to  avoid  disclosure  of  company  operations.  The  output 
of  cyclic  accelerators  was  24  millions  pounds  in  1943,  compared  with 
17  million  in  1941.  Sales  were  22  million  pounds,  valued  at  8.8  million 
dollars,  in  1943  and  12  million  pounds,  valued  at  5.5  million  dollars, 
in  1941. 

Cyclic  antioxidants  did  not  follow  the  general  slump  in  1942.  Output 
was  maintained  at  approximately  25  million  pounds  during  1941  and 
1942;  in  1943  it  increased  to  38  million  pounds. 

Only  accelerators  are  included  among  the  acyclic  rubber  chemicals. 
Production  of  these  chemicals  did  not  vary  so  widely  from  year  to  year 
as  that  of  the  cycHc  compounds.  Production  totaled  17  million  pounds 
in  1941,  decreased  slightly  in  1942,  and  then  rose  to  19  million  pounds 
in  1943.  Sales,  which  closely  paralleled  production,  were  valued  at  4.5 
million  dollars  in  1941  and  7.5  million  dollars  in  1943.  Tetramethyl- 
thiuram  sulfide  and  disulfide,  the  only  acyclic  accelerators  for  which 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


57 


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58  UNITED  STATES  TARIFF  COMMISSION 

statistics  are  given  for  all  3  years,  dropped  in  unit  value  from  $1.76 
per  pound  in  1941  to  SI. 52  in  1943. 

ELASTOMERS 

An  elastomer  is  defined  as  a  material  that  will  stretch  repeatedly  to 
at  least  150  percent  of  its  original  dimension  and  will  return  rapidly  and 
with  force  to  its  approximate  original  shape.  The  term  synthetic 
elastomer  is  not  limited  to  the  true  synthetic  rubbers,  but  also  in- 
cludes plastics  such  as  the  vinyl  polymers,  which  are  converted  to 
elastomers  by  the  addition  of  plasticizers  and  other  compounding 
chemicals.  Since  the  war  began,  elastomers  have  become  one  of  the 
most  important  groups  of  synthetic  organic  chemicals. 

Production  and  sales  of  synthetic  elastomers  are  shown  in  table  16A, 
and  an  alphabetical  list  of  these  chemicals,  identifying  the  manu- 
facturer, appears  in  table  16B  (see  part  II).  Data  for  elastomers,  other 
than  sj'nthetic  rubber,  were  not  separately  reported  to  the  Commission 
before  1943.  Production  and  sales  of  synthetic  rubber  shown  in  the 
group  totals  for  1941  and  1942  are  not  shown  in  detail  according  to 
types  in  these  years  to  avoid  disclosure  of  the  operations  of  individual 
companies.  , 

The  statistics  reflect  the  progress  of  the  Government  synthetic- 
rubber  program.  The  production  of  573  million  pounds  of  all  types  of 
elastomers  (chiefly  synthetic  rubber)  in  1943  was  nearly  tenfold  the 
production  of  59  million  pounds  in  1942,  which,  in  turn,  was  more 
than  twice  that  of  28  million  pounds  in  1941.  In  1943  the  output  of 
the  butadiene-stj'rene  (GR-S)  general-purpose  style  of  synthetic 
rubber — which  is  also  a  cyclic  elastomer — amounted  to  414  million 
pounds,  or  to  72  percent  of  the  total  production  of  elastomers.  In  1941 
and  1942,  production  was  exclusively  in  privately  owned  plants  and 
consisted  chiefly  of  acyclic  elastomers  of  the  types  that  are  superior 
to  natural  rubber  for  numerous  specialized  applications.  These  were 
neoprene  (polj^chloroprene),  butyl  rubbers  (poljdsobutylene  and 
polyisobutylene-isoprene  mixtures),  and  thiokol  types  (polj^alkalene- 
sulfides).  By  1943,  considerable  quantities  of  the  special-purpose 
GR-A  (polybutadiene-acrylonitrile)  were  also  being  produced. 

In  1943,  the  production  of  6.4  million  pounds  of  vinyl  elastomers 
(polyvinyl  alcohol-butyraldehyde  types)  also  contributed  to  meeting 
the  pressing  demands  for  rubber  substitutes. 

The  average  unit  sales  value  per  pound  of  all  types  of  elastomers  in 
1943,  though  less  than  in  1941  and  1942,  was  considerably  above  the 
price  at  which  natural  rubber  was  available  before  the  attack  on  Pearl 
Harbor. 

Production  of  the  GR-S  type  of  synthetic  rubber  in  1943  repre- 
sented new  production  which  took  place  almost  entirely  in  Govern- 
ment-owned plants,  erected  as  a  part  of  the  Government  synthetic- 
rubber  program.  The  average  unit  sales  value  of  19  cents  per  pound 
given  for  the  GR-S  type  of  rubber  is  the  average  book  value  per  pound 
for  1943,  as  supplied  by  the  Rubber  Reserve  Company. 


MISCELLANEOUS  CHEMICALS 

Miscellaneous  synthetic  organic  chemicals  include  those  not  classi- 
fied under  anj'^of  the  previous  specific  groups.  Among  these  chemicals 
are  solvents,  plasticizers,  photographic  chemicals,  insecticides,  and 
textile  chemicals.    Table  17A  gives  production  and  sales  for  1941-43, 


1 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


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and  table  17B  (see  part  II)  gives  an  alphabetical  list  of  these  chemicals 
identifying  the  manufacturer  of  each. 

Production  of  these  miscellaneous  items  was  8.9  billion  pounds  in 
1943,  or  77  percent  above  the  production  of  5  billion  pounds  in  1941. 
Sales  of  miscellaneous  organic  chemicals  were  4.9  billion  pounds, 
valued  at  660  million  dollars  in  1943,  as  against  2.7  billion  pounds, 
valued  at  310  million  dollars  in  1941.  The  average  unit  sales  value  was 
14  cents  per  pound  in  1943  and  11  cents  in  1941.  Sales  ranged  between 
50  and  55  percent  of  production  during  1941-43,  the  remaining  output 
being  consumed  in  the  producing  plants  in  the  manufacture  of  other 
products. 

The  cyclic  organic  chemicals  included  accounted  for  only  3  to  4 
percent  of  the  total  production  of  this  miscellaneous  group  during 
1941-43.  The  output  of  miscellaneous  cyclic  chemicals  was  321 
million  pounds  in  1943,  as  against  181  million  pounds  in  1941.  The 
most  important  group  was  plasticizers,  principally  phthalates.  The 
production  of  plasticizers  in  1943  was  112  million  pounds;  in  1941, 
53  million  pounds.  The  average  unit  sales  value  of  plasticizers 
dropped  from  25  cents  per  pound  in  1941  to  23  cents  per  pound  in 
1942  and  1943.  About  40  to  45  percent  of  these  cyclic  chemicals  were 
items  for  which  the  production  statistics  could  not  be  disclosed. 

Acyclic  chemicals  accounted  for  96  to  97  percent  of  the  total  produc- 
tion of  miscellaneous  organic  chemicals.  As  yet  no  major  group  of 
acyclic  intermediates  corresponding  to  the  group  of  cyclic  intermediates 
has  been  established;  therefore  more  of  the  acyclic  chemicals  fall  into 
the  miscellaneous  group.  Production  of  miscellaneous  acyclic  or- 
ganic chemicals  totaled  8.6  billion  pounds  in  1943,  an  increase  of 
about  80  percent  over  the  4.8  billion  pounds  produced  in  1941.  Ap- 
proximately half  of  the  output  of  miscellaneous  acyclic  organics  was 
produced  for  sale.  Sales  of  these  products  were  4.6  billion  pounds, 
valued  at  598  million  dollars  in  1943,  compared  with  2.6  billion 
pounds,  valued  at  278  million  dollars,  in  1941.  The  average  unit  sales 
value  in  1943  was  13  cents  a  pound,  an  increase  of  2  cents  above  the 
value  in  1941  and  1942. 

Production  statistics  are  publishable  for  slightly  more  than  half 
of  the  acyclic  miscellaneous  organic  chemicals.  Among  these,  the 
most  important  are  acetic  acid,  acetic  anhydride,  acetone,  carbon 
disulfide,  carbon  tetrachloride,  formaldehyde,  isopropyl  alcohol,  sjni- 
thetic  methanol,  butadiene,  and  cellulose  acetate.  Production  of  for- 
maldehyde (37  percent  by  weight),  an  important  raw  material  for 
resin  manufacture,  was  523  million  pounds  in  1943,  compared  with 
310  million  in  1941.  Production  of  acetic  anhydride,  a  basic  chemical 
for  cellulose  acetate  manufacture,  averaged  445  million  pounds  over 
the  2-year  period  1942-43;  data  for  1941  are  confidential.  The  output 
of  isopropyl  alcohol  was  376  million  pounds  in  1943,  352  million 
pounds  in  1942,  and  260  million  pounds  in  1941.  Production  of 
acetone  was  348  million  pounds  during  1943,  as  against  259  million 
pounds  in  1941.  Isopropyl  alcohol  and  acetone  are  important  sol- 
vents. Only  that  part  of  the  butadiene  produced  from  ethyl  alcohol, 
is  included  among  the  miscellaneous  acyclic  chemicals.  Statistics  for 
butadiene  from  petroleum  are  included  with  those  given  for  chemical 
raw  materials  clerived  from  petroleum  (see  p.  13).  Production  of 
butadiene  from  alcohol  increased  from  6  million  pounds  in  1941  to 
260  million  in  1943,  which  is  not  surprising  since  it  was  used  as  a  raw 
material  for  the  most  important  type  of  synthetic  rubber. 


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66  UNITED  STATES  TARIFF  COMMISSION 

One  of  the  subgroups  of  miscellaneous  organic  chemicals  which  is 
increasing  in  importance  is  the  surface-active  agents — wetting,  emul- 
sifying, and  flotation  agents.  Production  of  these  chemicals  in  1943 
was  as  follows:*  27  million  pounds  of  cyclic  compounds,  and  60  million 
pounds  of  acyclic  compounds.  Part  of  the  increase  in  1943  shown  for 
the  latter  compounds  is  apparent  only;  the  coverage  of  producers 
increased,  and  there  were  more  accurate  reporting  and  classification 
of  the  data. 

Important  acyclic  miscellaneous  organic  chemicals  for  which  pro- 
duction statistics  are  not  publishable  are  synthetic  ethyl  alcohol, 
tetrachloroethane,  tetraethyl  lead,  and  trichloroethylene. 


PART   II.    INDIVIDUAL  ITEMS  AND  MANUFACTURERS,  1941-43 

COAL-TAR  CRUDES 

Table  4B. — Organic  chemicals:   Tar  crudes  for  ivhich   United  States  production  or  sales 
were  reported,  identified  by  manufacturer,  19Jfl-43 

Coal-tar  crudes  for  which  separate  statistics  are  given  in  table  4A  are  marked  below  with  an  asterisk  (*) 
products  not  so  marked  do  not  appear  in  table  4A  because  the  reported  data  are  confidential   and  may 
not  be  published.   Manufacturers  are  identified  by  numbers  in  the  alphabetical  list  appearing  on  p.  135. 
An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of   his  identification   number 
with  the  designated  product.] 


Product 


Tari. 


Light  oil  and  derivatives: 
*Crude  light  oil , . 

•Benzene  (except  motor  benzene) 

*Motor  benzene 

*Toluene,  crude  and  refined 

•Solvent  naphtha 

"Xylene 

•All  other 

•Naphthalene,  crude  (solidifying  at  less  than  79°  C.) ; 

Anthracene,  crude  (less  than  30  percent) 

•Cresylic  acid,  crude  (less  than  75  percent) 

Cumene 

'Pyridine,  crude  and  refined - 

•Creosote  oil 

'Crude  tar  acids 

•Coal  tar  sold  or  consumed  in  coal-tar  solution 

'Tars,  crude  (used  or  sold  for  paints,  pipe  coatings,  saturatings,  etc.) 
*Tars,  refined  (used  or  sold  for  paints,  pipe  coatings,  saturatings,  etc.) 

•Tars,  road 

•Other  distillates .  .  ■ 

'Pitch  of  tar 

'Pitch  of  tar  coke .".... 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  13.3) 


58,  88,  109,  110,  141,  265,  273. 
305,  312,  322,  3.53,  358,  369, 
381,  393,  406,  408,  431,  X,  X, 
X,  X,  X,  X,  X,  X,  X,  X,  X,  X, 
X,  X,  X,  X. 

71,  109,  110,  116,  209,  2.36,  245, 

258,  358,  369,  384,  397,  X,  X, 

X,  X. 
45,  72,  127,  328,  369,  40S,  X,  X. 
45,  369,  408,  X. 
45,  72,   112,   127,  328,  342,  359, 

369.   408,   417.   421.   440.  441. 

468.  478.  X.  X,  X.  X.  X. 
45,  72,  245,  328,  352,  369,  384. 

.387.  408. 
45.  72,  210,  328,  369,  408. 
45,   71.   72,    109,    116,    209,   328, 

352.  358,  369,  387,  408. 
45,   116,   1.35,  2.36,  245,  2.58,  328. 

352,  369,  384,  387,  397,  408. 
245,  384. 
45,  86,  135,  384. 
45. 

45,  245,  384. 
19,  45,  71,  72,  86,  115,  116,  135, 

209,   219,    224,    2.36,    245,    253, 

258,  328,  369,  384,  .387,  397,  X. 
19,  45,  72,  86,  115,  135,  209,  219. 

224,   236,   245,   253,   258,   384, 

387,  397,  431,  X. 
19,  45, 135,  224,  236,  245,  258.  358, 

.384,  387,  397. 
116,  236,  245,  2.58,  384,    387,   X. 
19,  45,  116,  209,  236,  245,  2.58,  .369, 

384,  387,  397. 
19,  45,  135,  209,  224,  245.  258,  .369, 

384,  387,  397,  X. 
19,  45.  71,  115,  116,  209,  236,  245. 

258,  328,  384,  387,  397. 
19,  45,  71,  115,  116,  135,  209,  219, 

224,  236,  245,  258,  369,  384,  .387. 

397 
19,  4.5,  135,  224,  245,  384,  387. 


'  Only  those  manufacturers  are  identified  by  number  who  report  production  of  oil-gas  and  water-gas 
tar  to  the  U.  S.  Tariff  Commission. 


67 


68 


UNITED  STATES  TARIFF  COMMISSION 


INTERMEDIATES 

Table   5B. — Synthetic  organic  chemicals:  Cyclic  intermediates  for  which   United   States 
production  or  sales  were  reported,  identified  by  manufacturer,  19Itl—.!t3 

[Cyclic  intermediates  for  which  separate  statistics  are  given  in  table  5A  are  marked  below  with  an  asterisk 
(*);  cyclic  intermediates  not  so  marked  do  not  appear  in  table  5A  because  the  reported  data  are  con- 
fidential and  may  not  be  published.  Manufacturers  are  identified  by  numbers  in  the  alphabetical  list 
appearing  on  p.  135.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his 
identification  number  with  the  designated  product.] 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


Aeenaphthylene  (Acenaphthene) 

Acetamidoaminoanthraquinone 

5-Acetamido-2-aminobenzenesulfonic  acid 

5-Acetamido-8-amino-2  and  3-naphthalenesulfonic  acid  (Acetyla- 
mino  Cleve's  acid). 

2-Acetamido-4-aminophenol  hydrochloride 

4-Acetamido-2-aminophenol  hydrochloride 

l-Acetamido-4-bromoanthraquinone 

3-Acetamido-N-butyl-4-methoxybenz6nesulfonamide 

2-Acetamido-3-chloroanthraquinone 

2-Acetamido-3-chloro-9,10-anthradiol-9,10-d isulfonic   acid, 
diethyl  ester. 

l-Acetamido-7-naphthol 

8-Acetamido-l-naphthol-3,5-disulfonic  acid 

2-Acetamido-4-nitrophenol ^ 

5-Acetamidosalicylic  acid 

*Acetanilide,  tech 

o-Acetaniside  (Acetyl-o-anisidine) 

p-Acetaniside  (Acetyl-p-anisidine) .' 

Acetate  leuco  violet 

Acetoacetanilide 

o-Acetoacetaniside 

p-Acetoacetaniside 

o-Acetoacetochloroanilide 

p-Acetoacetochloroanilide 

Acetoaceto-4-chloro-l-naphthylamide 

p-Acetoacetophenetide 

7-(o-Acetoacetophenyl)acetoacetanilide 

o-Acetoacetotoluide 

2,4-Acetoacetoxylide 

o-Acetotoluide 

*p-Acetotoluide 

l-Acetyl-3-(4-amino-p-anisyl)urea 

Acetylsalicylic  acid,  methyl  ester 

N-Acetylsulfanilic  acid 

*N-Acetylsulfanilyl  chloride 

Acridine  yellow 

Alloxan 

m-Aminoacetanilide 

*p-Aminoacetanilide 

p-Aminoacetanilide  sulfate 

3-Amino-p-acetotoluide .••■■. 

5-Amino-S-(p-aminophenylazo)-2-naphthalenesulfonic acid  (Black 
base  V) . 

2-Amino-5-(p-aminophenyl)benzenesulfonic  acid 

5-Amino-2-(4-amino-m-toluino)benzenesulfonic  acid 

*.5-Amino-2-anilinobenzencsulfonic  acid 

*6-(p-Aminoanilino)metanilic  acid  (Phenylene  nerol  acid) 

*2-(p-Aininoanilino)-5-nitrobenzenesulfonic  acid 

6-(p-Aiiiiniianilino)-3-nitro-o-toluenesulfonic  acid 

2-Amin():uitlirai|uinone 

*l-Aminuanthraquinone  and  salt 

*2-Aminoanthraquinone  and  salt 

l-Aminoanthraquinone-2-sulfonic  acid 

4-Aminoantipyrine  (Aminopyrazolone) 

*6-Amino-3,4'-azobis(benzenesulfonic  acid) 

8-Amino-l,2-benzacridin-7(12)-one 

p-Aminobenzaldehyde 

l-Amino-5-benzamidoanthraquinonp 

S-[3-(m-Aminobenzamido)-4-methylbenzamido]-l ,3,5-ii  a  p  h  t  li  a- 

lenetrisulfonic  acid. 
*6-(m-Aminobenzamido)-l-naphthol-3-s  ulfonic    acid   (m- 

Aminobenzoyl  J  acid). 
*6-(p-Aminobenzamido)-l-naphthol-3-s  ulfonic    acid    (p- 

Aminobenzoyl  J  acid). 
*2-Amino-p-benzenedisulfonic  acid 

4-Amino-m-benzenedisulfonic  acid 

o-Aminobenzencsulfonic  acid 

o-Aminobenzenesulfon-p-toluide 

p-Aminobenzoic  acid 

p-Aminobenzoic  acid,  ethyl  ester 

7-(p-Aminobenzoyl)acetoacetic  acid,  ethyl  ester 

m-Aminobenzoyl-m-phenylenediarnine 

p-Aminobenzoyl-m-phenylcnediamine 

m-A!ninobenzoyl-i)-tolylenediamine .■••■: 

'o-Aminobenzylsulfonic  acid  (o-Toluidine  omega  sulfonic  acid)  .  .  . 

2-Amino-4-biphenylsulfonic  acid 


245,  384. 
13. 
176. 
313. 

X. 
X. 

176. 
176. 

176. 
176. 

176,  313. 

176. 

X. 

1. 

95,  127,  129,  176,  204,  290,  .307,  X. 

13. 

13,  204,  313,  X. 

282. 

77,  470. 

176,  470. 

470. 

77,  470. 

470. 

357. 

470. 

470. 

77,  176,  470. 

176,  470. 

72,  313. 

129,  204,  X,  X. 

176. 

295. 

176. 

1,  72,  95,  294,  307,  X,  X,  X. 

129,  176,  313. 

139. 

13. 

95,  129,  176,  313. 

176. 

176,  204. 

95. 

13,  95. 

176. 

95,  176,  313. 

13,  55,  95,  129,  176,  313. 

13,  55,  95,  176,  313. 

176. 

129,  176,  313. 

13,  72,  129,  176,  313,  X. 

72,  129,  176,  313. 

176,  313. 

357,  X. 

1.3,  89,  95,  176,  313. 

129. 

176. 

13.  176. 

176. 

13,  129,  176,  313,  357. 

13,  95,  129,  176,  313,  357,  X. 

95,  129,  313,  357. 

313. 

176,357. 

176. 

129,  136. 

176,  X. 

176. 

129. 

129. 

129. 

13,72,      9     :3,  357. 

357. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


69 


Table  5B. — Synthetic  organic  chemicals:  Cyclic  intermediates  for  which   United    States 
production  or  sales  were  reported,  identified  by  manufacturer,  19Ifl~Jf3 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


*l-Amino-4-bromoanthraquinone-2-sulfonic      acid      (Bromamine 
acid) . 

]-Amino-2-bromo-4-(p-toluino)anthraquinone 

p-Amino-N-(n-butyl)  phenol 

3-Amino-N-butyl-p-toluenesulfonamide 

3-Amino-2-chloroanthraquinone 

.5-Amino-l-chloroanthraquinone 

8-Amino-l-chloroanthraquinone 

•2-Amino-5-chlorobenzenesuIfonic  acid 

2-Amino-6-chlorobenzenesulfonic  acid 

*3-Amino-6-chlorobenzoic  acid 

o-(3-Aniino-4-chlorobenzoyl)benzoic  acid 

2-Amino-4-chloro-6-nitrophenol 

2-Amino-4-chlorophenol 

2-Amino-4-chlorophenolsulfonie  acid 

6-Amino-4-chloro-l-phenol-2-sulfonic  acid 

*2-Amino-5-chloro-p-toluenesulfonic  acid  (Lake  red  C  amine) .  .  .  . 

6-Amino-4-chloro-m-toluenesulfonic  acid 

6-Amino-3-chloro-2,5-xylenesulfonic  acid 

2-Amino-p-cresol  (m-Amino-p-cresol) 

l-Amino-2,4-dibromoanthraquinone 

4-Amino-2,5-dichloro-m-benzenedisulfonic  acid 

*Aminodichlorobenzenesulfonic     acid      (2,.5-Dichloroanilincsulfonic 
acid). 

3-Amino-N,N-diethyl-p-toluenesulfonamide 

3-Amino-6-dimethylamino-2-methylacridinium  chloride 

4-Amino-5-ethoxy-o-butyrophenetide 

5-Amino-6-ethoxy-2-naphthalenesulfonic  acid 

9-Amino-2-ethoxy-6-nitroacridine 

2-(p-Amino-N-ethyIanilino)ethanol 

Aminodihydroxyanthraquinone 

3-AminoformaniIide .• 

3-Amino-2-hydroxyanthraquinone 

4-Amino-l-hydroxyanthraquinone 

3-Amino-4-hydroxybenzenearsonic  acid 

3-Aniino-6-hydroxy-2-methylphcnazin('  (Tolazine  base) 

n-Amino-N-isobutylphenol 

5-Aminoisophthalic  acid 

4-Amino-4-methylacetanilide 

4'-Amino-5'-methyl-p-to!uenesulfon-o-aniside 

1-Aminonaphthalenedisulfonic  acid 

2-Amino-l,5-naphthalenedisulfonic  acid 

*3-Amino-I,5-naphthaIenedisulfonic  acid 

*3-Amino-2,7-naphthalenedisulfonic  acid 

*4-Amino-l,5-naphthalenedisuIfonic  acid 

4-Amino-1.6-naphthalened!sulfonic  acid 

4-Amino-l,7-naphthalpnedisulfonic  acid 

*6-Amino-l,3-naphthaIenedisulfonic  acid 

*7-Amino-l,3-naphthaleneclisulfonic  acid  (Amino  G  acid) 

*8-Amino-l,6-naphthalenedisulfonic  acid 

5-Amino-2,7-naphthalenpdisulfonic  acid,  sodium  salt 

8-Amino-l,6-naphthalenedisulfonie  acid,  monosodium  salt 

l-Amino-2-naphthalenpsulfonic  acid  (o-Naphthionic  acid) 

*2-Amino-l-naphthaIpnpsulfonic  acid  (Tobias  acid) 

4-Amino-2-nai)hthalpnesulfonic  acid 

*-)-Amino-l-naphthalenesulfonic  acid  (Laurent's  acid) 

*o-Amino-2-naphthalenesulfonic  acid 

*5-  and  8-Amino-2-naphthalencsulfonic  acids  (Cleve's  acid) 

6-Amino-l-naphthalenesu!fonic  acid 

*l3-Amino-2-naphthalenesulfonic  acid  (Broenner's  acid) 

7-Amino-l-naphthalenesulfonic  acid,  sodium  salt 

*8-Amino-l-naphtha!enesulfonic  acid 

*8-Amino-2-naphthalenpsulfonic  acid 

7-Amino-l,3,6-naphthalenetnsulfonic  acid 

*8-Aftiino-l,3,6-naphthalpnetiisulfonic  acid 

4-Amino-l,3,.5-naphthalpnetrisulfonic  acid-4,5-sultam 

8-Amino-l,3,5-naphthalenetrisulfonic  acid-l,8-sultam  (1-Naph- 
tham-4,6,8-trisulfonic  acid). 

8-Amino-l-naphthoic  acid 

8-Amino-2-naphthol 

8-Amino-l-naphthol-3,.5-disulfonic  acid 

*8-Amino-l-naphthol-5,7-disulfonic  acid,  monosodium  salt  (Chicago 
acid). 

7-Amino-l-naphthol-3,6-disulfonic    acid,    monosodium   salt    (2R 

acid). 
*8-Amino-l-naphthol-3,6-disulfonic    acid,     monosodium    salt    (H 

acid). 
*l-Amino-2-naphthol-4-sulfonic  acid 

6-Amino-2-naphthol-4-sulfonic  acid 

*S-Amino-l-naphthol-.'J-sulfonic  acid,  sodium  salt  (S  acid) 

*6-Amino-l-naphthol-3-sulfonic  acid,  sodium  salt  (J  acid) 

*7-Amino-l-naphthol-3-sulfonic  acid,  sodium  salt  (Gamma  acid).  . 
*2-Amino-.5-nitrobenzcnesulfonic  acid 

2-Amino-4-nitrophenol 


129,  176,  313. 

129,  313. 

129. 

176. 

176. 

129,  313. 

129. 

13,  9.3,  129,  176. 

176,  357. 

95,  129,  176,  313. 

176. 

95,  176. 

95,  313. 

95,  129,  176. 

313. 

.55,  72,  206,  X,X. 

129. 

13. 

95. 

129,  176,  313. 

129,  357. 

13,  129,  282,  313,  .3.57. 

176. 

357. 

357. 

176. 

176. 

176. 

176. 

176. 

176. 

176,  313. 

1. 

95,  313. 

129. 

176. 

176. 

176. 

129. 

X. 

95,  129,  176,  282,313. 

95,  176,313. 

95,  129,  176,  313. 

129,  313. 

129. 

13,  9.5,  129.  176,  313. 

13,  95,  129,  176,  313,  X. 

95,  129,  313. 

176. 

129,  313. 

129,  X. 

22,  72,  95,  129,  204,  X,  X. 

176. 

72,  95,  129,  176,  313. 

95,  129,  176,  282,  313. 

72,  95,  129,  176,  282. 

176. 

22,  95,  129,  313,  X. 

313. 

72,89,  95,  129,  176,  313. 

95,  129,  176,  282,  313. 

313. 

95,  129,  176,  313. 

176. 

176. 

176.  ' 

129,  176. 

176. 

95,  129,  176,  313. 

129,  313. 

129,  176,  .307,  313. 


9.5,  129,  136,  1.39,  170,  313. 

95. 

95,  129,  313. 

13,  .5.5,  72,  89,9,5,  129,  176,  3i:' 

13,  95,  129,  176,  313. 

72,  95,  129,  176,  313. 

72,  89,  129,  176,  X. 


70 


UNITED  STATES  TARIFF  COMMISSION 


Table  5B. — Synthetic   orgunir  chemical.'!:  Cyclic  intermediates  for  vhich   United  States 
production  or  sales  were  reported,  identified    by  manufacturer,    19Jfl-Jf3 — Continued 


Chemical 


2-Amino-5-nitioplienol 

•4-Aniino-2-nitrophenoI 

2-Amino-4-nitro-l-phenol-6-sulfonic  acid 

2-Amino-6-nitro-l-phenol-4-.sulfonic  acid 

3-Amino-5-nitro-p-toluenesulfonic  acid  potassium  salt 

*o-AminophenoI 

•p-Aminophenol  and  salts 

p-Aminophenol  oxalate 

2-Amino-l-phenol-4-sulfonamide 

•2-Amino-l-phenol-4-suIfonic  acid 

p-Aminophenylammonium  hydroxide 

*p-AminophenyIazobenzenesuifonic  acid 

*m-(p-AminophenyIazo)benzenesulfonic  acid 

•p-(p-AminophenyIazo)benzenesuIfonic  acid 

p-(p-Aminophenylazo) phenol  (Azohydroxyaniline) 

4-Amino-a-phenyl-m-cresol  hydrochloride 

2-(p-Aminophenyl)-6-methylbenzothiazole 

l-(m-Aminophenyl)-5-pyrazolone-4-carboxylic  acid 

2-Aminopyridine 

2-Aminopyrimidine " 

5- Aminosalicylic  acid 

Amino  Schaeffer  ether  (5-Amino-6-ethoxy-2-naphthalenesulfonic 
acid). 

3-Amino-5-stearoylamido-p-toluenesulfonic  acid 

2-Amino-p-sulfobenzoic  acid 

*2-(4-Amino-3-sulfophenyI)-6-methylbenzothiazole 

l-(3-Aminc)-5-sulfo-o-tolyl)-3-methyl-5-pyrazolone 

*2-Aminothiazole 

]-Amino-4-toluenesulfonamidoanthraquinone-2-sulfonic  acid.  .  .  . 

Aminotoluenesulfonic  acid 

•4-Amino-m-toluenesulfonic  acid 

4-Amino-o-toluenesuIfonic  acid 

,5-Amino-o-toluenesulfonic  acid 

5-Amino-o-toluenesulfonic  acid,  isopropyl  ester 

*4-(4-Amino-m-toIylazo)-m-toluenesulfonie  acid  and  salt 
(o-Aminoazotoluenesulfonic  acid  and  salt). 

16-Aminoviolan  throne 

*2-Amino-3,.5-xylenesulfonic  acid 

Amylbenzylcyclohexylamine 

Amylnaphthalenes 

o-Amylphenol 

p-tert-Amylphenol 

•Aniline  (Aniline  oil) 


Aniline  disulfide 

Aniline  hydrochloride  and  sulfate 

Aniline  sulfate 

l-.\nilino-2-anthraquinonecarboxylic  acid 

2-.'\nilinoethanol  (Phenylethanolamine) 

•Anilinomethanesulfonic  acid  (Aniline  omega  sulfonic  acid)  and  salt. 

6-Anilino-2-methoxymetanilic  acid 

*8-.\nilino-l-naphthalenesulfonic  acid  (Phenyl  peri  acid) 

•6-Anjlino-l-naphthol-3-sulfonic  acid  (Phenyl  J  acid) 

*7-.\nilino-l-naphthol-3-sulfonic  acid  (Phenyl  gamma  acid) 

2-.\nilino-5-nitrobenzenesulfonic  acid  (4-Nitrodiphenylamine-2- 
sulfonic  acid). 

Anisic  acid 

o-.\nisidine 

'p-.Anisidine 

*o-.\nisidinomethanesulfonic  acid,  sodium  salt  (o-Anisidine  omega 
sulfonic  acid  salt). 

2-(p-Anisidino)-5-nitrobenzenesulfonic  acid 

-Anisoin 

2-(p-Anisyl)-4-chloroanthranilic  acid 

2-(m-Anisyl)-4-chloroanthranilic  acid,  potassium  salt 

2-(p-Anisyl)-4-chloroanthranilic  acid,  potassium  salt 

n-(p-Anisyl)-p-methoxyacetophenone 

N-(p-.A.nisyl)-p-phenylenediamine 

Anthracene,  refined 

Anthraflavic  acid  (2,6-Dihydroxyantliraquinone) 

-Anthranilic  acid 

.Anthra  (l,9]pyrazol-6(2)-one  (Pyrazolanthrone) 

.'\nthraquinone,  100% 

N,  N'-(l,.")-Anthraquinone)dianthranilic  acid 

.Antliraquinone-l,5-disulfonic  acid 

.\nthraquinone-l  ,iH-disulfonic  acid 

*.\nthraquinone-2,6-disulfonic  acid 

Anthraquinone-l,8-disulfonic  acid,  potassium  salt 

Anthraquinone-2,6-(lisuIfonic  acid,  salt 

a-.Anthraquinonchydrazinedisulfonate 

l-.\nthraquinoncsulfonic  acid 

2-Anthraquinonpsulfonic  acid 

2-AnthraquinoneRulfonic  acid  and  salt 

•1-Anthraquinonesulfonic  acid,  sodium  salt 


Manufacturers'  identification 
numbers  (according  to  list  on  j).  13.5) 

176. 

72,  95,  313,  X. 

95,  176. 

176. 

176. 

129,  136,  150.  282,  480,  506,  X. 

72,  129,  136,  ,307,  313,  480,  506,  X. 

139. 

95. 

55,  9.5,  129,  313,  357,  X. 

X. 

13,  55,  72,  95.  129.  176.  313,  3.57 

13,  55,  95,  129,  313. 

72,  89.  176,  357. 

357. 

136. 

129,  313. 

129. 

1,  294,  379. 

1. 

13,  95.  X. 

176,  282. 

176. 

176. 

95,  129,  176,  313. 

176. 

72,  95,  282,  294,  307,  X. 

176. 

136. 

72,  95,  129,  313,  357. 

176. 

95.  129,  176,  313,  X. 

129 

13,  176,  313. 

176. 

13,  129,  176,  313. 

307. 

413. 

413. 

413. 

72,   127,   129,  176,  290,  .307,  313, 

X,  X. 
307. 
72,  282. 
294. 
129. 
77. 

.55,  72,  129.  176,  282,  313,  3,57. 
95,  176. 

72,  95,  129,  176,  313. 
13,  89,  95,  129,  176,  313,  357,  X. 
13,  89,  95,  129,  176,  313,  .357. 
176. 

X. 

129,  307. 

129,  307,  313,  X. 

89,  129,  313,  357. 


176. 

248,  200.  X. 

.3.57. 

X. 

313. 

260.  X. 

176. 

384. 

176. 

22.  127.  129. 

129.  176.  313. 

72.  176,  313. 

129,  176. 

72,  129,  176,  313. 

129,  176,  313. 

129,  176,  313. 

129,  176. 

72,  176. 

176. 

95,  176,  X. 

176. 

1.37.  176. 

72.  129.  313. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


71 


Table  5B. — Synthetic  organic  chemicals:  Cyclic  intermediates  for  which  United  States 
production  or  sales  vere  reported,  identified  by  manufacturer,  191^1-^3 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


*2-Anthraquinonesulfonic  acid,  sodium  salt  (Silver  salt) 

3-(l-Anthraquinonylaniino)-7-benz[de]anthracen- 

7-one   ("Benzamide"). 
*Anthranifin  (1,5-Dihydroxyanthraquinonc) 

Anthra[l,9]isothiazoIe-2-carbonyl  chloride 

Arsanilic  acid 

Azobenzene 

•l.l'-Azobis(2-naphthol-4-sulfonic*acid) 

1 , 1  '-Azobis(8-nitro-2-naphthol-4-sulfonic  acid) 

*.5,5'-Azobis(6alicylic  acid) 

m,m'-Azoxydianiline 

Benzaldehyde,  tech 

Benzaldehyde  semicarbazone 

*l-(4-Ben2amido-l-anthraquinonylimino)  -5-benzamidoanthraqui- 
none. 

l-Benzamido-4-cliJoroanthraquinone 

*l-Benzaniido-5-chloroanthraquinone 

2-[l-(4-Benzamido-2,5-diethoxyphenyl)-3-methyl-3-t  ri  a  zene] 
ethancRuIfonic  acid. 

2-[l-(4-Benzamido-2,  5-dimethoxyphenyl)-3-methyl-3-triazene] 
cthanesulfonic  acid. 

l-(4-Benzainido-6-methoxy-m-tolyI)-3-mcthyl-3-triazoBeacetic 
acid. 

6-Benzamido-4-methoxy-3-(p-toIuenesulfonamido)  toluene 

*6-Benzamido-l-naphthol-3-sulfonic  acid  (Benzoyl  J  acid) 

*7-Benz(de]anthracen-7-one  (Benzanthrone) 

Benzanthronedianthraquinonyldi-imide 

m-Benzenedisulfonic  acid,  sodium  salt 

Bcnzenesulfinic  acid,  sodium  salt 

Benzenesulfonamidc 

Benzenesulfonic  acid 

Bcnzpnesulfonic  acid,  sodium  salt 

Benzenesulfonyl  chloride 

Benzidine,  base 

'Benzidine  hydrochloride  and  sulfate 

Benzil 

ll-Benzo[a]carbazole-2-sulfonic  acid 

2-Benzofuryl  cyanomethj'l  ketone 

'Benzoic  acid,  tech 


13,  129,  313. 
176. 


Benzoic  acid,  2-naphthyl  ester  (Benzonaphthol) 

Benzoic  anhydride : 

Benzoin 

a-Benzoylacetanilide 

*o-Benzoylbenzoic  acid 

Benzoyl  chloride 

2-BenzoyI-4-chloro-3-nitrobenzoic  acid 

*Benzyl  alcohol,  tech 

Benzyl  disulfide 

Benzyl  ether 

*4-(N-Benzyl-N-ethylaniino)-o-toluenesulfonic  acid 

*X-Benzy!-N-ethylaniline 

N-Benzyl-N-ethyl-p-nitrosoaniline 

X-Benzyl-N-ethyl-m-toluidine 

o-Benzylhydroxybenzoate,  calcium  salt 

Benzylidineaminopyrazolone 

p,p'-Benzylidinebis(N,N-diethylani]ine)  (Tetraethyldiaminotri- 
phenylmethane) . 

p.p'-Benzylidinebis(N,N-dimethylaniline)(Tetramethyldiamino- 
triphenylmethane) . 

Benzyl  polysulfide 

(3,3'-Bi-7-benz[de]ant.hracene)-7,7'-dione  (13,13-D  i  b  e  n  z  a  n  - 
thronyl) . 

(4,4'-Bi-7-benz[de]anthracene)-7,7'-dione  (2,2-Dibenzanthronyl) 

Bibenzyl 

(l,l'-Binaphthalene)-8,8'-dicarboxylic  acid. 

Biphenyl 

o-Biphenylamine 

p-Biphenylamine 

\,N'-Bis(acetoacetyl)benzidine 

5,S-Bis(p-aminobenzamido)-2-naphthalencsulfonic  acid 

l,3-Bis(4-p-aminobenzamido-3-sulfophenyl)urea 

l,.3-Bisf4-amino-.3-su!fophenyl)urea 

l,4-Bis(l-anthraquinonylamino)anthraquinone 

l,3-Bis''4-biphenylyl)-2-thiourea  (s-Dixenylthiourea) 

p,p'-Bis('diethylamino)benzohydrol 

p,p'-Bisfdiethylamino)benzophrnone  (Ethyl  ketone  base) 

2,7-Bis(dimethylamino)acridinehydrochloridc 

•p,p'-Bisfdimethylamino)benzohydrol  (Michler's  hydrol) 

*p,p'-Bis(dimpthylamino)benzophenone  (Michler's  ketone) 

Bis(p-dimcthylaminophonyl)methancsulfonic  acid  and  salt 

N,N-Bis''2-hydroxyethyl)aniIine 

*N,N-Bis(2-hydroxyethyl)-m-toluidine 


95,  129,  176,  313. 

129. 

1,  248,  294,  297. 

313,  357,  X. 

89,  95,  139,  176,  313. 

176,  313. 

129,  176,  313. 

176,  .3.57. 

51,  197,  X,  X,  X,  X. 

139. 

72,  129,  176.  313. 

129,  176. 

13,  72,  129,  176,  313. 

176. 

176. 

176. 

176. 

55,  89,  95,  176. 

13,  72,  129,  176,  313,  349. 

176. 

129. 

176. 

307,  320. 

45,  136,  307. 

176. 

136. 

95,  129.  1.36,  313. 

72,  84,  95,   129,   136.   159.   176. 

313,  X. 
1.36,  294.  X. 
176. 
X. 
127,    129,    176,    197,    203,    207, 

294,  307,  476. 
304. 
13,  207. 

51,  136,  150,  294,  X. 
X. 

72,  129,  176,  313. 
127,  203,  207,  460. 
176. 

51,  204,  207. 
159,  207. 
51. 

129.  176.  313. 
129.  204.  313. 
176. 

129.  313. 
1. 
X. 
132,282. 

132.  282. 

207. 
129.  176. 

129.  176. 

197.  476,  X. 

176. 

127.  159.  .307. 

307. 

307. 

357. 

176. 

357. 

357. 

176. 

307. 

176.  282. 

129.  132.  176,  204,  313. 

3.57. 

129,  176,  282,  313. 

129,  1.32,  176,  204,  313. 

313. 

176,  282. 

176,  282. 


72 


UNITED  STATES  TARIFF  COMMISSION 


Table  5B. — Synthetic  organic  chemicals:  Cyclic  intermediates  for  which    United   States 
production  or  sales  were  reported,  identified  by  manufacturer,  19Ifl-!io — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


4,4'-Bis(p-hydroxyphenylazo)-2,2'-s tilbenedisulfonic  acid, 
disodium  salt  (Distilbenediphenol). 

2,4-Bis(p-hydroxyphenyI)-3-ethylhexane 

4,4'-Bis  [2-(l-o-anisyl-3-methyl-3-triazene)ethanesulfonic  acid] . 
*X,N'-Bis-6-(l-naphthol-3-sulfonic  acid)urea  (J  acid  urea) 

5,8-Bis(p-nitrobenzamido)-2-naphthalenesulfonicacid 

Bis(o-nitrophenyl)disulfide 

*3-Bromo-7-benz[de]anthracen-7-one 

Bromobenzene 

l-Bronio-4-(X-methylacetamido)anthraquinone 

*p-Bronio-methylaminoanf  hraquinone 

6-Bromo-3-methyl-7-dibenz[f,ij]isoquinoline-2,7(3)-J  i  o  n  e  (4- 
Bromo-N-methyl-1 ,9-anthrapyridone) . 

1-Bromonaphthalene 

p-Bromophenol 

2-Bromo-4-phenylphenol 

3-Bromophthalic  acid 

N-Butylbenzenesulfonamide 

N-ButyI-4-chloro-3~nitrobenzenesulfonamide 

6-tert-Butyl-2,4-dimethylacetophenone 

2-tert-Butyl-5-methylanisole 

1-(N-Butyl)naphthylamine .*. 

p-tert-ButylphenoI ' 

o-tert-Butyl-m-xylene 

Camphene 

Carbazole,  refined 

Carbazole-ethoxypyrazolone 

Carbazoletetrasulfonic  acid 

o,o'-Carbonyldioxydibenzoic  acid,  diethyl  ester 

3-Carboxy-i-(3'-nitrophenyl)-5-pyrazolone 

7-(p-CarboxyphenyIainino)-l-naphthol-3-sulfonic  acid 

Chloranil  (Tetrachloroquinone) 

o-Chloroacetoacetanilide 

Chloroacetoamidonaphthalene 

m-Chloroaniline 

o-Chloroaniline 

p-Chloroaniline 

o-Chloroaniline  sulfate 

4-ChIoro-o-anisidine 

l-(4-Chloro-o-anisyl)-3-methyl-3-triazeneacetic  acid 

3-Chloro-2-anthracenecarboxylic  acid 

5-ChIoroanthranilic  acid 

*  1-Chloroanthraquinone 

•2-Chloroanthraquinone 

•l-ChIoro-2-anthraquinonecarboxylic  acid 

3-Chloro-2-anthraquinonecarboxylic  acid 

*o-Chlorobenzaldchyde 

"Chlorobenzene,  mono 


ni-Chlorobenzenesulfonic  acid 

p-Chlorobenzenesulfonic  acid 

Chloro-7-benz(delanthracen-7-one 

*o-Chlorobenzoic  acid 

in-Ch!orobenzoic  acid 

]v-Chlorobenzoic  acid 

'Chlorobenzoylbenzoic  acid 

6-ChIoro-m-cresoi 

4-Chloro-X,N-diethyl-3-nitrobenzpnesulfonamide 

a-Chloro-3,4-dihydroxyacetophenone 

5-Chloro-2,4-dimethoxyaniline 

b-Chloro-],3-dimethoxy-4-nitrobenzene 

*l-Chloro-2,4-dinitrobenzene 

4-Chloro-3,.5-dinitrobenzencsulf()nic  acid 

4-Chloro-3,5-dinitrobenzoic  acid 

4-Chloro-2,6-dinitrophenol 

0-Chloro-2,4-dinitrophenol 

!)-Chloro-2-ethoxy-6-nitroacridinc ^ 

fi-(2-Chloroethoxy)-2,4,6-trichloropiicnctoIc  (Triclilorophenoxy- 
ethoxyethyl  chloride). 

2-Chloro-X-ethyl-o-nitrobenzpnenulfonaiiilitlc 

•")-Chloro-2-formylbenzenesulfonic  acid 

Chloro-4-hydrazinobenzencsulfonic  acid 

.")-Chloro-8-hydroxyquinoline 

'5-Chloromctanilic  acid 

•I-Chloro-2-methylanthraqiiinonc 

Chloronaphthalcnes 

.S-Chloro-l-naphthol-3,6-disulfonic  ucid  (Chloro  II  acid) 

*2-Chloro- 4-nitroaniline 

'4-Chloro-2-nitroani]ine 

]-Chloro-o-nitroanthraquinone 

l-ChIoro-8-nitroanthraciuinone 

Chloro-2-nitrobenzene 

Chloro-3-nitrobenzene 

Chloro-4-nitrobenzene 


313. 

402. 

176. 

13,  5.5,  72,  95,  89,  129,  176,  313. 

176. 

176. 

13,  129,  176. 

127,  1.36,  159. 

176. 

176. 

176. 

136,  159 

127,  X. 

127. 

149. 

307. 

176. 

X. 

X. 

307. 

127. 

X. 

129 

129,  ,384. 

176. 

176. 

127. 

176. 

176. 

X. 

77. 

357. 

129,  307. 

307,  480. 

307. 

357. 

207,  313,  480. 

176. 

176. 

357. 

72,  129,  176,  313,  X. 

72,  129,  176,313. 

129,  176,  313. 

176. 

129,  203,  204,  313. 

127,  129,  130,  1.59,  142,  207,  .307 

425,  426,  X,  X. 
176. 
176. 
313. 

95,  129,  203,  313. 
176. 

176,  203. 

72,  129,  176,  313. 
45. 
176. 
248. 
176. 
176. 

13,  72,  129,  176,  282,  .307,  313. 
176. 
176. 
95. 
176. 
176. 
127. 

176. 
176. 
176. 
95,  X. 

,55,  95,  129,  313. 

13,  72,  129,  17G,  313. 

207,  X.  X,  X. 

176,  313. 

13,  22,  72,  127,  129. 

127,  129,  313,  480. 

129,  313. 

129 

13,'l29,  .307. 

129,  307. 

13.  129,  307,  313,  X. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


73 


Table  Uli. — Synfketic  organic  chemicals:  Cyclic  intermediates  for  which   United  State-' 
production  or  sales  were  reported,  identified  by  manufacturer,  lO^l—^S — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


*2-Chloro-4-nitrobenzenesulfonic  acid 

4-Ch!oro-2-nitrobenzenesulfonic  acid 

2-Chloro-4-nitrobenzoic  acid 

2-Chloro-5-nitrobcnzoic  acid 

5-Chloro-2-nitrobcnzoic  acid 

Chloronitrodiphenyl  ether 

4-Chloro-2-nitrophenol 

4-ChIoro-2-nitro-l-phenol-6-sulfonic  acid 

2-Chloro-4-nitrotoluenc 

*4-ChIoro-2-nitrotoIuene 

6-ChIoro-2-nitrotoluene 

*Q-Chlorophcnol 

p-Chlorophenol 

4-Chloro-o-phcnylenediamine 

o-Chlorophenylhydrazine 

t-(o-Chlorophcnyl)-3-niethyl-5-pyrazolone 

2-Chloro-6-phcnylijhenol 

2-Chloro-6-phenylphenoI,  sodium  salt 

2-Chioro-6-phenylphenol  and  sodium  salt 

2-(l-ni-Chlorophenyl-3-triazene)-4-sulfobenzoic  acid. 

2-ChloroQuinizarin 

2-Chloro-5-sulfobenzoic  acid 

l-(2-Chloro-4-sulfophenyl)-3-methyl-5-pyrazolone.  . 

2-C'hlorotcrephthaloyl-o-benzoic  acid 

Chlorotoluene 

*a-Chlorotoluene  (Benzyl  chloride) 

o-Chlorotoluene 

5-Chloro-o-toIuenesuIfonic  acid 

3-Chloro-p-toluenesulfonic  acid,  sodium  salt 

3-Chioro-o-toluidine 

3-Chloro-p-toluidine 

4-ChIoro-o-toluidine 

*.T-Chloro-o-toluidine  (Red  KB  base) 

6-Chloro-o-toluidinc 

4-Chloro-o-toluidine  iiydrochloride 

*Chlorotoluidincsulfonic  acid 

o-(3-Chloro-p-tolyl) benzoic  acid 

(4-Chloro-o-tolylniercapto)acetic  acid 

l-(5-ChIoro-o-tolyl)-3-methyl-3-triazeneacetic  acid . 

4-Chloro-a-trifluoro-3-nitrotoluene 

4-Chloro-a-trifluorotoluene 

6-Chloro-a-trifluoro-m-toluidine 

4-Chloro-m-xylenc  (Xylyl  chloride) 

Chloro-3,.3-xylenol 

Chrysazin  (l.S-Dihydroxyanthraquinonc) 

m-Cresol 

*o-Cresol 

11-Cresol 

*Crcsol  (meta,  para) 

*Cresol  (ortho,  meta,  para) 

Cresols,  chlorinated 

2,3-Cresotic  acid 

*Cresylic  acid,  refined 


Cumcne 

Cuniinyl  chloride 

S-Cyano-1-naphthalenesulfonic  acid 

Cyclohexane 

Cyclohcxylamine 

2-Cyclohexyl-4,6-dinitrophenol 

N-Cyclohexyl-N-ethylbenzamide 

p-Cymene 

Decylbenzene 

*Diaminoanthraquinone 

1,4-Diaminoanthraquinone 

*l,5-Diaminoanthraquinone 

2,6-r)iaminoanthraquinone 

4,8-Diaminoanthrarufin 

4,8-Dianiino-2,6-anthrarufindisulfonic  acid 

3,3'-Diaminobenzanilide 

*2,4-Diaminobenzenesulfonic  acid  (m-Phenylenediaminesulfonic 
acid). 

2,5-Diaminobcnzenesulfonic  acid 

Diamino-3,3'-bibenz[dc]anthracen-7-one 

*4,4'-Diamino-3,3'-biphenyldisulfonic  acid 

*2,2'-Diamino-5,5'-bi-m-toluenesulfonic  acid 

*4,4'-Dianiino-l,l'-dianthraquinonylamine 

1,4— Diamino-2,3-dihydroanthraquinone 

l,8-Diamino-4,5-dinitroanthraquinone 

1,4— Diamino-o-nitroanthraquinone 

2,4-Dianiinophenol 

N,N  '-Di (m-aminophenyl ) oxamide  (Oxalyl-m-phenylenediamine) 
*N,N'-Di(p-aminophenyl)oxamide   (Oxalyl-p-phenylenediamine) . 

l,3-Di(m-aminophenyl)urea 


13,  55,  89,  95,  129,  176,  313. 

95,  313. 

176. 

129,  176,  313. 

13,  95,  176,  .357. 

357. 

95. 

95. 

313. 

13,  129,  176,  313. 

129,  313. 

127,307,  351. 

127,  129,  307. 

150. 

176. 

176. 

127. 

127. 

127. 

176. 

95,  313. 

176,  357. 

129,  176. 

176. 

129,  207,  313,  X. 

51,204,207,307,  X. 

129,  313. 

176. 

129,  .307.  X. 

129,  313. 

129,  313. 

176. 

13,  129,  176,  289,  313. 

176. 

129 

72,  95,  129,  X. 

176. 

129,  313. 

176. 

176. 

176. 

176. 

176. 

45. 

129,  176. 

45,  384,  X. 

45,  72,  245,  .363,  384,  387,  X. 

45,  384,  X. 

45,  72,  245,  363,  384,  387,  X,  X. 

45,  72,  245,  384,  387,  X,  X. 

45. 

127. 

45,   72,  86,  245,  384,  .387,  416, 

440,  X. 
127. 
69,  X. 
176. 

45,  127,  129. 
307. 
127. 
307. 

201,  319. 
307. 

13,  95,  129,  176. 
95,  176. 

13,  127,  129,  176. 
72,  176,  313. 
129.    • 
89. 
176. 
89,95,  129,  176,  313. 

95,  176. 

129 

13,  72,  89,  95,  1.36,  176,  .357,  X. 

13,  89,  95,  176,  313,  357,  X. 

72,  129,  176,  313,  X. 

176. 

129. 

176. 

176. 

129,  313,  3.57. 

129,  176,  282,  313. 

176. 


74 


UNITED  STATES  TARIFF  COMMISSION 


Table  .5B. — Synthetic  organic  chemicals:  Cyclic  intermediates  for  which  United    State 
production  or  sales  were  reported,  identified  by  manufacturer,  i94i-4-?— Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


2,6-Diaminopyridine 

*4,4'-Diamino-2,2'-stilbenedisulfonic  acid 

3,5-Diamino-p-toluenesulfonic  acid 

2,4-Di-tert-amylphenol 

l,2-Di-p-anisyl-l,2-butanediol 

l,2-DianisyI-l,2-ethanediol 

2,4-Di(p-anisyl)-3-ethyIhexane 

2,4-Di(p-anisyI)-3-ethylhexene 

l,3-Di(p-anisyl)-2-ethyl-l-pentanone 

3,4-Di(p-anisyl)hexane 

3,4-Dianisyl-3-liexanol . 

»l,l'-DianthraquinonyIamine 

]  ,5-Dibenzoylnaphthalene 

Dibenzylidenehydrazine 

Dibenzylsulfanilic  acid,  sodium  salt 

l,3-Di-(o-biphenyI)thiourea 

3,9-Dibromo-7-benz[de]anthracen-7-one 

p-Dibromobenzene 

4,5-Dibromo-l,8-dihydroxynaphthalene 

2',7'-Dibroniofluorescein 

7,16-Dibromoindanthrene 

Dibromo-8,16-pyranthrenedione 

4,6-Di-tert-butyl-m-cresol 

Di-tert-butyl-p-cresol. . 

2,5-Dichloroacetoacetanilide 

*2,5-Dichloroaniline 

2,5-Dicldoroaniline  hydrochloride 

1 ,5-Dichloroanthraquinone 

1,8-Dichloroanthraquinone 

4,5-Dichloro-l,8-anthraquinonedisulfonic  acid . 

4,8-Diciiloro-l,5-anthraquinonedisulfonic  acid . 

2.6-DichIorobenzaldehyde 

*o-Dichlorobenzene 


*p-Dichlorobenzene . 


*3,3'-Dichlorobenzidine 

2,2'-Dichorobenzidine  hydrochloride 

3,3'-DichIoroben2idine  sulfate 

*2,4-Dichlorobrnzoic  acid 

Dichlorobenzyl  disulfides 

l,8-Dichloro-4,5-dinitroanthraquinone 

*6,9-Dichloro-2-methoxyacridine 

Dichloronaphthalene 

2,6-Dichloro-4-nitroaniline 

•l,4-Dichloro-2-nitrobenzene 

2,4-Dichlorophenol 

2-[l-(2,5-Dichlorophenyl)-3-ethyl-3-triazene]-5-sulfobenzoic  acid 

2,5-Dichlorophenylhydrazine 

•l-(2,5-Dichlorophenyl)-3-methyl-5-pyrazolone 

o-(3,5-Dichlorosalicyloyl)benzoic  acid   (Dichlorohydroxybenzoyl- 

benzoic  acid). 
*l-(2,5-Dichloro-4-sulfophenyl)-3-metliyl-.'5-pyrazolone 

l-(2,5-Dichloro-4-sulfophenyI)-5-pyra2o!one-3-carboxylic  acid. .  . 

o,a-Dichloroto!uene 

*2,4-Dichlorotoluene 

2,6-DichIorotoIuene 

Dicresyl  disulfide 

Dicyclohexylamine 

Dicyclopentadiene 

2,.5-Diethoxyaniline 

1,4-Diethoxybenzene.  . 

l,4-Diethoxy-2-nitrobenzene 

X-(2,.'')-Diethoxy-4-nitrophenyl)benzaniide 

K-(2,4-Diethoxyphenyl)benzamide 

Diethylaminobenzaldehyde 

3-Diethylamimo-6-nitrosophenol 

m-Dietliylaminophenol 

*N,N'-Diethylaniline 

•N,N'-Diethylcarbanilide 

N,N-Diethylnietanilic  acid 

N,N-Diethyl-3-nitro-p-anisolesulfonaiTiide 

N,N-Diethyl-p-nitrosoaniline 

N',N-DiethyI-4-nitroso-m-toluidin(! 

•N,N-Diethyl-p-phonylenedianiine 

N6,N'-Diethyl-2,r)-to!ylenediamine  hydrochloride 

Diethyl-m-toluidine 

N,N'-Diformyl-2,.5-tolylenediamine 

3,4-Dihydroxy-o-dimethylaminoacetophenone . 

*4,5-Dihydroxy-2,7-naphthalenediSulfonic  acid  (Chromf>tropic  acid) 
*4,.5-Dihydroxy-l-naphthalcnesulfonic  acid  (Dioxy  S  acid) 

6,7-Dihydroxy-2-naphthalenesulfonic  acid 

3,.5-Dihydroxy-2-naphthoic  acid 

3,5-Di-iodo-4-oxo-l(4)-pyridineacetic  acid  (I'clviren  acid) 


379 

129^  176,313. 

176. 

413,  X. 

248. 

X. 

402. 

402. 

402. 

295. 

248. 

129,  176,  313,  X. 

176. 

1.39. 

357. 

307. 

176. 

127. 

1.36. 

22,  149,  204,  X. 

129. 

129. 

245. 

X. 

77. 

95,  129,  207,  ,307,  313,  480. 

207. 

129,  176,  313. 

72,  129,  176. 

176. 

176. 

313. 

127,  129,  130,  142,  207,  307,  425. 

426,  4.38,  X. 
127,  129,  130,  142,  207,  307,  425, 

426,  438,  X. 
84,  95,  129,  196,  204. 
313. 
X. 

203,  204,  207,  294,  313,  X. 
X. 

129. 

204,  313,  .357,  .500. 
207. 

176. 

95,  313,  480. 

307. 

176. 

357. 

357. 

313. 


95,  129,  357. 

89,  357. 

203,  207. 

203,  294,313,  X. 

176,313. 

X. 

307. 

X. 

129,  176. 

176. 

176. 

176. 

176. 

176,  313. 

176. 

129,  282. 

127,  129,  204,  313. 

95,  129,  204,413. 

1 29,  282. 

176. 

176,  313. 

176. 

1,36,  176,  313. 

136. 

129,313. 

95. 

248. 

13,  95,  129,  313. 

13,  95,  176,  129,  313. 

176. 

176. 

X. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


75 


Table  5B. — Synthetic  organic  chemicals:  Cyclic  intermediates  for  which    United   States 
production  or  sales  were  reported,  identified  by  manvfacturer,  1941-4^3 — Continued 


Chemical 


16,17-Dihyflioxyviolanthroiie , 

2,5-Dimpf  lioxyanilinp 

1,4-Diinrthoxybcnzeno 

3,3'-Dinicthoxybenzidine 

2,5-Dimethoxy-4-nitroanilinc 

l,4-Dimethoxy-2-niti-obenzenp 

N-(2,5-Dimcthoxy-4-nitrophcnyi)bonzainide 

N-(2,5-Diniethoxyphonyl)benzaiiiidc 

p-Dimethylaniinobenzaldchyde 

N,N-Diraethyl-3-aminophcnol 

*X,N-nimcthylanilinc 

*2,2'-Dimcthyl-l,l'-bianthiaquinonc 

2,2'-Dimpthyl-l,l'-dianthraqiiinonylamine 

Dimethyldiphonylurea 

2',7'-DimothyIfluoran 

2,8-Dimcthyl-13b-hydroxy-9(13b)-ccroxcnonc 

N'.N-DiniPthyl-a-naphthylaminc 

*N,X-Dimpthyl-p-nitrosoanilinc 

N,N-Dimethyl-p-phpnylenediaminc 

N,N-Dimethyl-p-phpnylenpdiamine  hydrochloride 

N,N-DimPthyl-p-phpnylpnpdianiine  sulfate 

p-a-DiniPthylptyrcne 

N.N-Diinpthylsulfanilic  acid 

2,4-Dinitroanilinp 

*p-(2.4-Dinitroanilino)phpnol  (Dinifrohydroxydiphenylamine) . .  .  . 

'2.4-DinitroanisoIp 

*Dinitroanthraqiiinone  (1,5-  and  1,8-) 

4,8-Dinitroanthrarufin  (l,.5-Dihydroxy-4,8-dinitroanthraciuinonc) 

4,8-Dinitroanthrarufindisiilfonic  acid,  sodium  salt 

*Dinitrobpnzpne 

m-Dinitrobcnzpne 

p-Dinitrobenzenp 

2,4-DinitrobpnzcnesuIfonic  acid 

3,.5-Dinitrobpnzoic  acid 

3,.5-Dinitrobpnzoyl  chloride 

Dinitro-3,3'-bi(7-benz(de]anthraccn-7-one) 

4,4'-Dinitro-l  ,l'-dianthraquinonylaminc 

2,4-Dinitro-X-rnethylanilinp 

Dinitronaphthalenp  (1,5-  and  1,8-mixturc) 

2,4-Dinitro-a-naphthol 

*2,4-Dinitrophpnol,  tech 

N,N'-Di(p-nitroplipnyl)oxaniide  (Oxalyl-p-nitro-aniiinp) 

'4,4'-ninitro-2,2'-stilbenedisulfonic  acid 

2,4-Dinitrotolupnp 

3,5-Dinitro-n-tolupnesulfonic  acid 

1,.5-Dioxamidoanthraquinonc 

Dippntenp  (dl-Limonpnc) 

1,.5-Diphpnoxyanthraquinone 

Diphenylaniinp 

2,4-Diphpnylaminp-l-hydroxyanthraquinone 

*S-DiDhpnylamino-l,6-naphthalpnpdisulf()nic  acid 

1,5-Diphpnylcarbohydrazidc 

1,3-Dinhpnyltriazpnp  (Diazoaminobpnzcne) 

l,3-Di(p-toluino)anthraquinonp 

l,4-Di(p-toluino)anthraquinonp 

Dodecylbenzenc 

6-Ethoxy-3-hydroxythianaphtheno 

2-Ethoxynaphthalcne 

6-Ethoxy-2-naphthaIenesulfonic  acid 

2-Ethoxy-l-naphthyIamine 

2-Ethoxy-l-nitronaphthalene 

6-Ethoxy-m-phpnylpnediamine  (Dianiinophcnctolc) 

3-Ethylamino-p-crcsol 

3-EthyIaniino-{>-toluenesulfonic     acid     (N-Ethyl-o-toIuidinc-p- 

sulfonic  acid). 
*N-Ethylaniline,  mono  and  di 

2-(X-Ethylanilino)ethanol  (Hydroxycthylcthylaniline) 

'a-(X-Ethylanilino)-p-tolupnpsulfonic  acid 

Ethylbpnzcnc 

X'-Ethylbenzenpsulfonamidp 

a-Ethyl-4,4'-dimpthoxychalconp 

2-[3-Ethyl-l-(,")-nitro-o-anisyl).3-triazpnp]-5-sulfobenzoic  acid.  .  . 

2-(X-Ethyl-4-nitrosoanilino)ethanol  ( N -Ethan ol-N-e thy  1-4- 

nitrosoanilinc). 
*Ethylphpnylmalonic  acid,  diethyl  ester 

X-Ethyl-5-sulfoanthranilic  acid 

N'-Ethyl-p-toluenediamine 

X-Ethyl-m-toluidino 

X-Ethyl-o-toluidinc 

Fluorene 

a-Fluorenone 

4-Formyl-m-benzcnpdisulfonio  acid 

o-Formylbenzcnesulfonic  acid  (o-Sulfobcnzaldehyde) 

Furoic  acid 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


129,  176. 

129,  176. 

13,  176,  X. 

95,  129. 

176. 

13,  176. 

176. 

176. 

1.36,  159,  313. 

9g2 

72,  127,  129,  132,  204,  313 

72,  129,  176,  313. 

176. 

129. 

176,  498. 

176. 

1.36. 

13,  1.32,  176,  313. 

1.32,  136,  150. 

136. 

1.50. 

319. 

176. 

72,  204,  307. 

95,  176.  313. 

282,  480,  X. 

13,  89,  129. 

129. 

13,  129,  176. 

72,  129,  313. 

72,  313. 

129. 

95,  176. 

1.36,  137,  150. 

136. 

129. 

129.  X. 

72. 

176. 

1.59. 

129,  176,313. 

129,  282,  313. 

89,95,  129,  176,  313. 

129,  176,  313. 

95,  176. 

176. 

129,  319,  409. 

13   129 

127,  129,  136,  1.59. 

95. 

95,  129.  313. 

1.36,  1.59. 

129,  313. 

129. 

129. 

307. 

129. 

176. 

282,  357. 

176. 

176. 

72. 

129,  282 

129,  282. 

72,  95, 127,  129,  176,  204,  313,  413. 

176,  282. 

72,  95,  129,  176,  204,  282,  313. 

127,  ,307. 

.307. 

402. 

176. 

176. 

1,  51,  294,  X. 

176. 

176. 

129,  313. 

129,313. 

245,  384. 

1.39. 

176. 

129,  176.  .357. 

380. 


76 


UNITED  STATES  TARIFF  COMMISSION 


Table  5B. — Synthetic  organic  chemicals:  Cyclic  intermediates  for  ichich    United    States 
production  or  sales  were  reported,  identified  by  manufacturer,  19^1-43 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


Furoyl  chloride 

8-(3-Guanylguanidino)-2-naphthol  hydrochloride 

Glycerolmonoethylaniline 

Heptachlorodiphenyl  oxide 

Hexachlorobenzene 

Hexachlorodiphenyl  oxide 

Hydrazinobenzenesulfonic  acid 

m-Hydrazinobenzenesulfonic  acid 

o-Hydrazinobenzenesulfonic  acid 

*p-Hydrazinobenzcnesulfonic  acid 

3-Hydrazino-5-nitro-p-toIuenesulfonic  acid 

4-Hydrazino-m-toIuenesulfonic  acid 

Hydrof  uramide 

*Hydroquinone,  tech 

3-Hydroxy-2-anthracenecarboxylic  acid 

l-Hydroxyanthraquinone 

N-(3-Hydroxy-2-anthraquinonyIj-l-nitro-2-anthraquinonecar- 
boxamide. 

2-Hydroxy-ll-benzo[a]carbazole-3-carboxylic  acid 

p-Hydroxybenzoic  acid 

2-Hydroxycarbazole 

2-Hydroxy-3,6,8-carbazoletrisulfonic  acid 

3-Hydroxydiphenylamine 

l-(2-Hydroxyethyl)-3-phenyl-2-thiourea . 

4-Hydroxy-l-methylcarbostyril 

2-Hydroxy-l-naphthoic  acid 

*3-Hydroxy-2-naphthoic  acid 

l-Hydroxy-2-naphthoic  acid,  ethyl  carbonate 

l-Hydroxy-2-naphthoyl  chloride,  ethyl  carbonate 

(2-Hydroxynaphthyl)-3-thianaphthenol  (/3-N aphtholthioin- 
doxyl). 

l-Hydroxy-4-nitroanthraquinone 

4-Hydroxy-3-nitro-l-phenylarsonic  acid 

2-Hydroxyphenetolo 

p-Hydroxyphenylarsonic  acid 

N-(p-Hydroxyphenyl)-2-naphthylamine 

3-Hydroxy-5-sulfo-2-naphthoic  acid 

5-Hydroxy-m-toluenesulfonic  acid 

l,l'-Iminobis(4-benzamidoanthraquinone) 

*6,6'-Iminobis(l-naphthol-3-sulfonic  acid)  (I  or  J  acid  imide) 
(Rhoduline  acid). 

Indene T 

*Indophenol  (blue  and  green) 

Isatin 

Isobutylquinolinc 

Isophorone 

Isophthalic  acid  (1,3-Benzenedicarboxylic  acid) 

p-Isopropylideneaminobenzenesulfonic  acid,  sodium  salt  (Dimeth- 
anil-4-sodium  sulfonate). 

p,p'-Isopropylidenediphenol  (p,p'-Dihydroxydiphenyldimethyl- 
methane). 

Isoviolanthrone  (Isodibenzanthrone) 

Leuco  l,4-di(methylamino)anthraquinone 

Leuco  indophenol  BCFN 

*Leuco  quinizarin 

Leuco  tctrahydroxyanthraquinone 

2,6-Lutidine 

Melamine 

*Metanilic  acid 

p-jVJethoxy-a-(p-anisyl)butyrophenone 

1-Methoxyanthraquinone 

p-Methoxybutyrophenone 

3-Methoxydiphenylamine 

*5-Methoxy-m-phenylenediamine  (m-Diaminoanisole) 

6-Methoxyquinoline 

3-Methoxysulfanilic  acid 

6-Methoxy-m-toluidine  (2-Amino-p-cresol  methyl  ether) 

N-Methyl-p-acetaniside 

•1-Methylaminoanthraquinone 

Methylaniline,  mono 

2-(N-M('thylanilino)ethanol  (Hydroxyethylmethylaniline) 

o-Methyl-o-anisidine  (Cresidine) 

m-Methylanisole  (m-Cresol  methyl  ether) 

N-Methylanthranilic  acid 

2-Methylanthraquinone 

2-Methyl-7-benz[de]anthracene-7-one  (2-Methylbenzanthrone) . . 

2-Methylbenzoxazole 

N-Methylcyclohexylamine 

3,3'-Methylenebis(l-o-anisyl-3-triazeneacetic  acid) 

3,3'-Methylenebis(l-o-anisyl-3-triazenepropionic  acid) . 

N,N'-Methylenebis[N-p-(5-chloro-o-anisylazo)  phenylglycine] , 
disodium  salt. 

3,3'-Methylenebis[l-(5-chloro-o-anisyl)-3-triazeneacetic  acid].  .  . 

2,2'-Methylenebis(4-chlorophenol) 


207. 

176. 

95. 

207. 

127,  142,  207. 

127,  207. 

357. 

176,  357. 

176,  357. 

176,  357,  446. 

176. 

176. 

380. 

83,  129,  480,  X. 

176. 

13,  129,  313. 

176. 

176. 

203. 

176. 

176. 

176. 

307. 

176. 

129 

176;  313,  X. 

176. 

176. 

95. 

129. 

1,  294. 

307. 

1,  294. 

176. 

176. 

260. 

72,  129,  176,  313,  X. 

95,  129,  176,  313,  357. 

X. 

41,  129,  313. 

313. 

150. 

77,  207,  416. 

176,  313. 

176. 

127,  176. 


13, 

129 

129 

13, 

176 

245 

72, 

72, 

260 

13, 

402 

176 

72, 

176 

176 

95, 

X. 

72, 

129, 

176 

129 

286 

176 

72, 

313 

136 

307 

357. 

357. 

357. 

357. 
176. 


129,  176. 

72,  129,  282,  313. 

X. 

89,  95,  129,  176,  282,  313. 

,  X. 

176. 

282,  480. 

313. 
129,  176. 

,  X. 

129,  313. 

;  176. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


77 


Table  5B. — Synthetic  organic  chemicals:  Cyclic  intermediates  for  which  United    States 
production  or  sales  were  reported,  identified  by  manufacturer,  IdJ^l-JfS — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


3,3'-Methylenebis[l-(5-chloro-o-toIyl)-3-triazeneacetic  acid] 

3,3'-Methylenebis[I-(5-chioro-o-tolyl)-3-tria2enepropionic  acid] .  . 
p,p'-Methylenebis(N,N-diethylaniline)  (Te  tract  hyldiaminodi- 

ph  cn>-I  ni  ot  h  ane ) . 
*p,p'-M<'thylc'npbis(N,N-dimethylaniline)    (Tetramethyldiamino- 

diplicnylincthane). 
p,p'-Methylenebis(N,N-dimethyI-2-nitroaniIine)      (Dinitrotetra- 

methyldiaminodiphenylmethane). 
p,p'-Methylenebis(N-ethylaniline)    [Di(ethylamino)    diphenylme- 

thane]. 

N,N'-MethyIenebi8(4-methylaminoantipyrine) 

5-Methylenebis-2,4-toluenediamine  (Tetraaminoditolylmethane) .  . 
4,4'-Metliylonebis(m-toIuidine)      (4,4'-Diamino-2,2'-diniethyldi- 

phenylmethane) . 

p,p'-Methylenedianiline 

2-[3-Methyl-l-(4-methyl-5-nitro-o-anisyl)-3-triazenel-5-sulfo- 

benzoic  acid. 

2-MethyInaphthalene 

N-Methylnaphtho[2,3-h]quinoline  (N-Methyl-l,2-anthrapyridine) 

N-Methyl-p-nitroaniline 

5-MethyI-4-nitro-o-anisidine 

4-Methyl-o-nitroanisole 

N-(5-Methyl-4-nitro-o-anisyl)-p-toluenesulfonamide 

2-Methyl-l-nitroanthraquinone 

2-Methyl-6-nitrobenzoxazole 

2-Methyl-3-nitrodiphenylamine  (4-Nitrotoluene  anilide) 

3-Methyl-l-(3-nitro-5-sulfo-o-tolyl)-5-pyrazolone 

3-Methyl-l-p-phenetyl-3-triazeneacetic  acid 

*3-Methyl-l-phenyl-5-pyrazolone  (Phenylmethylpyrazolone) 

Q-Methylstyrene 

N-Methyl-5-sulfoanthranilic  acid 

3-Methyl-l-(m-sulfopheny!)-5-pyrazolone 

'3-Methyl-l-(p-sulfophenyl)-5-pyrazolone 

5'-Methyl-p-toluenesulfon-o-aniside  [3'-Aniino(p-toIuenesul- 
f  one)  methoxy  toluene] . 

3-Methyl-l-p-tolyl-3-triazene  acetic  acid 

4-MethylumbelIiferone 

•Naphthalene,  solidifying  at  79°  C.  or  above  (refined,  flake): 

From  American  crude  naphthalene 

From  imported  crude  naphthalene 

2-NaphthaIeneacetic  acid 

1,5-NaphthaIenediol  (1,5-IMhydroxynaphthalene) 

2,3-Naphthalenediol  (2,3-Dihydroxynaphthalene) 

•1,5-Naphthalenedisulfonic  acid 

'2,7-Naphthalenedisulfonic  acid 

1-NaphthaIenesulfonic  acid 

*2-Naphthalenesulfoiiic  acid 

•Naphthalenesulfonic  acids,  sodium  salt 

1-Naphthalenesulfonic  acid,  sodium  salt 

Naphthalenesulfonyl  chloride 

2-Naphthalenethiol 

1,3,6-NaphthalenetrisuIfonic  acid 

Naphthalic  anhydride 

•Naphthionic  acid  (4-Amino-l-naphthalenesulfonic  acid) 

Naphthionic  acid,  sodium  salt 

•1-Naphthol 

•2-Naphthol,  tech 

l-Naphthol-2-carboxylic  acid 

l-Naphthol-3,6-disulfonic  acid 

l-NaphthoI-4,8-disulfonic  acid 

*2-Naphthol-3,6-disuIfonic  acid 

*2-Naphthol-6,8-disuIfonic  acid 

*2-Naphthol-3,6-disulfonic  acid,  disodium  salt 

*2-Naphthol-6,8-disu!fonic  acid,  disodium  salt 

l-Naphthol-3,6-disulfonic  acid,  monosodium  salt 

2-Naphthol,  phenyl  ammonium  salt 

l-Naphthol-8-suIfamide 

l-Naphthol-3-suIfonic  acid 

*l-Naphthol-4-sulfonic  acid  (Nevile  &  Winther's  acid) 

*l-Naphthol-5-suIfonic  acid 

l-Naphthol-8-sulfonic  acid 

•2-Naphthol-6-suIfonic  acid  (SchaefTer's  acid) 

*2-NaphthoI-7-sulfonic  acid 

2-Naphthol-8-suIfonic  acid 

l-Naphthol-3,6,8-trisulfonic  acid  1,8-sultone 

1-8-Naphthosultoue 

•1-NaphthyIamine 

2-NaphthyIamine 

1-Naphthylamine  hydrochloride 

l-(l-NaphthyIamino)-2-anthraquinonecarboxylic  acid 

N-(1-Naphthyl)ethylenediamine  hydrochloride 

1-Naphthyl  isocyanate , 


127,  129,  176,  313,  357, 


357. 
357. 
176,  282. 

72,  129,  176,  282,  313. 

176. 

307. 

X. 

313. 
129,  313. 

176. 
176. 

245,  384. 

176. 

176. 

176. 

129. 

176. 

176. 

176. 

176. 

176. 

176. 

13,  72,  8 

X. 
127,  X. 
176. 
95,  176. 

55,  72,  95,  129,  176,  357. 
176.  . 

176. 
176,  351. 

45,  72,  116,  129,  245,  369,  384,  387 

416,  439,  X. 
45,  72,  245,  439. 
X,  X. 

129,  176,  313. 
176. 

95,  129,  176,  313. 
95,  129,  282,  313,  X. 
176. 

95,  307,  313,  X. 
72,  95,  176,  313,  X. 
95. 
176. 
176. 
89,  176. 
136. 

13,  72,  95,  129,  313. 
129 

9.5,  129,  159,  176,  313. 
72,  95,  313,  X. 
176. 

95,  313. 
95,  176. 

95,  129,  176,  313,  X. 
95,  129,  176,  313. 
95,  129,  176,  313,  X. 
95,  129,  176,  313. 
313. 
72. 
95. 
176. 

13,  95,  129,  313. 
95,  129,  176,  313. 
176. 

22,  72,  95,  129,  176,  282,  313. 
95,  129,  282,  X. 
95. 
95. 

95,  176. 

129,  159,  176,  313. 
129,  282,  313. 
136,  159. 
129,  313. 
136. 
136. 


78 


UNITED  STATES  TARIFF  COMMISSION 


Table  oB. — Synthetic  organic  chemicals:    Cyclic  intermediates  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  IQItl-JfS — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  13.3) 


2-Xaphthyl  isocyanate 

*2-NaphthyImercaptoaoetio  acid 

5-Xitroacenaphthene 

p-Nitroacetanilide 

*m-Nitroaniline 

o-Nitroaniline 

p-Xitroaniline 

*2-Xitro-p-anisidine 

*4-Nitro-o-anisidine 

*5-Xitro-o-anisidine 

5-Nitro-2-anisidinesulf onic  acid  urea 

o_(4-Nitro-o-anisidino)benzenesulfonic  acid 

o-NitroanisoIe 

p-Nitroanisole 

9-Xitroanthral[l,9-de,  4,10-d'e']bis(l,2,3-oxathiazine)-2,7-bis- 
dioxide. 

1-Xitroanthraquinone 

l-Xitro-2-anthraquinonecarborv'lic  acid 

5-Xitro-l-anthraquinonesulfonic  acid 

2-(l-Xitro-2-anthraquinonyl)anthr[2,3]oxazole-5,10-dione 

6-(m-Xitrobenzamido)-l-naphthol-3-sulfonic  acid  (m-Nitroben- 
zoyl  J  acid). 

6-(p-Xitrobenzamido)-l-naphthol-3-sulfonic   acid    (p-Xitroben 

zoyl  J  acid). 
•Xitrobenzene 

2-Xitro-p-benzenedi8ulfonic  acid 

•Xitrobenzenesulfonic  acid. 

m-Xitrobenzenesulfonic  acid  (m-Xitrobenzoylsulfonic  acid) 

o-Xitrobenzene,sulfonic  acid 

p-Nitrobenzenesulfonic  acid,  potassium  salt 

m-Xitrobenzenesulfonyl  chloride 

m-X'itrobenzoic  acid 

p-Xitrobenzoic  acid 

5-[a-(p-Xitrobenzoyl)acetamido]isophthaIic  acid 

p-Xitrobenzoylacetic  acid . .  t 

.y_(p_Xitrobenzoyl)acetoacetic  acid,  ethyl  ester 

m-Xitrobenzoyl  chloride 

p-Xitrobenzoyl  chloride : 

Xitrobenzoyltoluenediaminesulfonic  acid 

o-Xitrobiphenyl 

p-Xitrobiphenyl 

Nitrobutyrylaminodiethylhydroquinone 

2-Xitro-p-cresol 

2-XitrodiphenyIsulfonc 

5-Xitroisophthalic  acid 

•Xitronaphthalene 

7-Xitro-l,o-naphthalenedisulfonic  acid 

S-Xitro-l-naphthalenesuIfonic  acid 

S-Xitronaphthalenetrisulfpnic  acid 

4-Xitronaphthalic  anhydride 

7-Xitronaphth[l,2]oxadiazole-5-sulfonic  acid, 

4-Xitro-oxanihde 

o-Xitrophenetole 

*o-Xitrophenol 

p-XitrophenoI 

2-Xitro-l-phenol-4-suIfonamide 

Xitrophenylenediamine 

m-Xitrophenylhydrazine 

p-(p-Xitropheny]mercapto)aniHne  (Nitroaminodiphenyl  sulfide) . 

Xitrophfnyl  phenyl  ether 

X'itropyrazolone 

Xitropyrazoloneearboxylic  acid 

.')-Xitrosalicylic  acid 

l-Xitroso-2-naphthol 

•p-Xitrosophenol .■■■•. 

3-Xitro-.5-stearoylamido-p-toluenesulfonic  acid 

m-Xitrotoluene 

o-X'itrotoluene 

p-Xitrotoluene 

X^itrotoluene  mixtures 

*3-Xitro-p-toIuenesulfonic  acid 

*.3-Xitro-o-toluenesulfonic  acid 

4'-Xitro-p-toluenesulfono-o-toluide 

3-X'itro-p-toluic  acid 

Xitrotoluidine 

*2-Xitro-p-toluidine 

4-Xitro-o-toluidine ■ 

5-Xitro-o-toluidine 

3-Xitro-p-tolunitrile 

3-Xitro-p-tolyl  chloride 

2-[3-Methyl-l-(4-nitro-o-tolyI)-3-triazone]-5-sulfobenzoic  acid. 

4-Xitro-X-p-tolylnaphthalimide 

X-(4-Xitro-o-tolyl)-p-toluenesulfonamide 

16-Xitro\'iolanthrone 


136. 

"2,  129,  176,  313. 


176 
95, 
13, 
89, 
13, 
129 
129 
129 
176 
176, 
129 
129 
176 


129,  176. 

72,  9.5,  129,  282,  307,  313,  480. 

307. 

129,  204,  307,  313,  486. 

,  176,  204,  282,  289,  313. 

,  176,  289. 

,  176,  282,  289,  313. 


,  307,  313. 
,  159,  313,  X. 


176. 
176. 
129. 
176. 
129,  176. 

129,  176,  357. 

72,  129,  176,  307,  313,  X. 

95. 

95!  129,  176,  282,  313. 

13,  89,  95,  129,  176,  282. 

176,  313. 

72. 

137. 

129,  207. 

129,  207,  313,  357. 

176. 

176. 

176. 

129,  207. 

129,  136,  207,  X. 

176. 

307. 

307. 

357. 

1,  95,  129. 

176.  * 

176. 

129,  176,  313. 

95,  176. 

176. 

176. 

176. 

176. 

176. 

129 

51,  129,  282,  307,  480. 

72,  129,  307,  480. 

95. 

176. 

1.36,  176. 

313. 

357. 

357. 

357. 

176. 

72,  1.39,  159. 

41,72,95,  129,  176,313. 

176. 

129,  176,  313. 

129,  176,  313. 

129,  176,  313. 

72,  129,  176,  313. 

13,  89,  95,  176. 

72,  95,  129,  176,  313. 

357. 

176. 

1. 

72,  129,  176,  204,  351,  X. 

129,  176,  3.57. 

129,  176,  X. 

176. 

176. 

176. 

176. 

176. 

72,  176. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


79 


Table  5B. — Synthetic  organic  chemicals:  Cyclic  intermediates  for  which    United   States 
production  or  sales  were  reported,  identified  by  manufacturer,  1941--'t3 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


*Nitroxylene 

2-Nitro-p-xyIene 

4-Nitro-m-xylene 

4-Nitro-o-xylene 

Pentachlorobenzene 

Pentachlorophenol,  sodium  salt 

Pentachlorophenol  and  sodium  salt 

Phenazine 

o-Phenetidine 

p-Phenetidine 

Phenol: 
•Natural: 

From  coal  tar: 

U.S.P 

37°  C.  m.p 

39°  C.  m.p 

82-84  percent 

All  other 

•Synthetic: 

Bv  caustic  fusion: 

"82-84  percent 

39°  C.  m.p 

U.S.P 

All  other 

From  chlorobenzene  bv  liquid  phase  hydrolysis: 

U.S.P 

39°  C.  m.p 

From  chlorobenzene  by  vapor  phase  hydrolysis: 

U.S.P 

From  benzol  by  oxidation: 

U.S.P 

From  petroleum: 

U.S.P 

Other 

Phenol,  sodium  salt 

Phenolsulfonic  acid 

Phenoxathiin  (Phenothioxin) 

o-Phenoxyaniline 

2-Phenoxyethanol 

2-Phenylanthr[2,3]oxazoIe-5,lO-dione 

*p-Phenylazoaniline    and    hydrochloride    (Aminoazobenzene    and 
hydrochloride). 

N-Phenyldibenzylamine  (Dibenzylaniline) 

'm-Phenylenediamine 

*o-PhenyIenediamine 

*p-Phenylonediamine 

•Phenylglycine,  sodium  salt 

Phenylhydrazine 

Phenylhydrazine  and  hydrochloride 

a,a'-Phenyliminobis(p-toluenesulfonic  acid)    (N-Phenyldibenzyl- 
aminedisulfonic  acid). 

2,2'-Phenyliminodiethanol  (Phenyldiethanolamine) 

Phenylisocyanate 

Phenylmalonic  acid,  diethyl  ester .' 

N-Phenyl-2-naphthylamine ■  ■  • 

o-Phenyl  phenol 

p-Phenylphenol 

o-Phenylphenol,  sodium  salt 

N-Phenyi-p-phenylenediamine 

l-Phenyl-5-pyrazolone-3-carboxylic  acid 

Phenylthiourea 

Phthalamide 

Phthalic  acid 

•Phthalic  anhydride 

Phthalonitrile 

Phthaloyl  chloride 

*2-Picoline  (alpha) 

•3-Picoline  (beta) 

4-Picoline  (gamma) 

*3-and  4-Picoline  (beta,  gamma  mixture) 

•Picramic  acid  and  salt 

Picric  acid  (Trinitrophenol) 

2-PipecoIine 

3-(l-Piperidyl)-l,2-propanedioI 

•Piperidine 

1-Piperidinepropanol 

Polychlorobiphenyl 

Polychloronaphthalenes 

Primuline,  base 

Primuline  sulfonic  acid 

Proflavine,  base  (3,6-Diaminoacridine) 

Propiophenone 

Pseudocumidine 

Pyrazole  anthrone  yellow 


95,  129,  176,  313. 

176. 

95,  176. 

294. 

207. 

127,  307. 

127,  307. 

176. 

129,  307. 

129,  307,  X,  X. 


384,  387. 

72. 

45,  72,  245,  384. 

45,  245,  384. 

45,  72,  245,  384,  387,  X. 


45. 

45. 

45,  86,  307. 

45. 

127. 
179. 

130. 

425. 

384. 

384. 

159 

127,  294,  351. 

127. 

357. 

77,  479. 

176. 

13,  72,  95,  129,  176,  313. 

129. 

72,  89,  95,  129,  176,'313,  370,  480. 

136,  139,  150. 

13,  72,  480,  486,  X. 

127,  129,  313. 

127. 

127,  136.  159,  176. 

176. 

77,  127,  129. 

136. 

1,  294,  X. 

176,  307. 

127. 

127. 

127. 

129,  139. 

176. 

137. 

127,  129,  X. 

X. 

16,  45,  129,  307,  313,  .383. 

129. 

307. 

45,  245,  363,  X. 

45,  245,  384. 

45. 

45,  245,  384,  X,  X. 
72,  129,  313. 

129,  313. 

307. 

295. 

129,  207,  307. 

260. 

307. 

207. 

95,  176,  313. 

176,  349. 

1. 

351. 

46,  313. 
129,  176. 


80 


UNITED  STATES  TARIFF  COMMISSION 


Table  5B. — Synthetic  organic  chemicals:  Cyclic  intermediates  for  which    United   States 
production  or  sales  were  reported,  identified  by  manufacturer,  19Jfl-Jf3 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


•Pyridine,  refined 

Pyridine,  salts,  bases,  and  residues 

•Quinaldine  (2-Methylquinoline) 

Quinaldine  yellow,  base 

*Quinizarin  (1,4-Dihydroxyanthraquinone) 

Quinizarinsulfonic  acid 

Quinoline 

Quinoline,  2° 

Quinoline  yellow,  base 

Quinolinic  acid 

Resorcinol,  tech 

/9-Resorcylic  acid 

'Salicylic  acid,  tech 

Styphnic  acid  (2,4,6-Trinitroresorcin) 

Styphnic  acid,  lead  salt 

'Styrene  (Vinylbenzene)  : 

•Grade  for  rubber  (elastomers) 

•Other  grades 

p-Sulfamylbenzoic  acid  (p-Carboxybenzene-sulfonamide) 

•Sulfanilic  acid  and  salt 

p-Sulfoanthranilic  acid 

o-Sulfobenzoic  anhydride. 

p-Sulfo-o-benzoylbenzoic  acid  (Sulfo  BB  acid) 

p,p'-Sulfonyldiphenol  (4,4'-Dihydroxy-diphenylsulfone) 

l-(p-Sulfophenyl)-5-pyrazolone-3-carboxylic  acid  (Pyrazolone  T) 

2',4',5',7'-Tetrabromofluorescein 

•1,4,5,8-Tetrachloroanthraquinone 

Tetrachlorobenzene 

Tetrachlorophenol,  sodium  salt 

a,a,2,6-Tetrachlorotoluene 

Tetrahydrof urf uryl  alcohol 

•l,4.5.8-Tetrakis(l-anthraquinonylamino)anthraquinone 

•p,p'-Thiodianiline 

6-Thiodimetanilic  acid  (Thioaniline  disulfonic  acid) 

3(2)-Thiophanthrenone  (Naphthoxythiophene) 

*o-Tolidine  and  salts 

2-(o-Toloxy)ethanol  (Cresylglycol) 

o-Toluenesulfonamide 

p-Toluenesulf  onamide 

Toluenesulfonic  acid,  tech 

p-Toluenesulfonic  acid 

p-Toluenesulfonic  acid,  ethyl  ester 

o-Toluenesulfonyl  chloride 

l)-Toluenesulfonyl  chloride 

•  a-Toluic  acid  and  ethyl  ester  (Phenylacetio  acid  and  ester) 

m-Toluidine 

o-Toluidine 

*p-Toluidine 

Toluidine,  mixed 

2-(m-Toluino)ethanoI  ( Hydroxy ethyl-3-toluidine) .  • 

6-(p-Toluino)metanilic   acid   (4'-Methyl-4-aminodiphenylamine- 

2-sulfonic  acid. 
•g_(p_'roluino)-l-naphthalenesulfonic  acid  (Tolyl  pe»  acid) 

a-Tolunitrile  (Beitzyl  cyanide) 

p-Tolunitrile 

•4_(Q_T'olylazo)-o-toluidine  (o-Aminoazotoluene) 

4_(o_ToIylazo)-o-toluidine  sulfate  (o-Amino-azotoluene  sulfate)  . 

*o-(p-Tolyl)benzoic  acid 

*m-Tolylenediamine 

p-TolvIenediamine 

•m-Tolylenediamine  sulfate 

p-Tolylenediamine  sulfate 

Tribromophenol 

•Trichlorobenzene 

1 ,2,4-Trichloro-5-nitrobenzene 

2,4,.'J-Trichlorophenol,  sodium  salt 

•a-Trichlorotoluene  (Bcnzotrichloride) 

1,2,4-Trihydroxyanthraquinone 

p,o,a-Trimethylbenzyl  alcohol  (Diniothyltnlylcarbinol) 

o-Vanillin  (2-Hydroxy-3-methoxybinzal<l(liyde) 

o-Veratraldehyde  (2,3-Dimethoxyb('iizal(li'liyde) 

9-Vinylcarbazole 

Violanthrene •  •  • 

♦Violanthrone  (Dibenzanthrone) 

m-Xylene 

Xylene,  ortho  and  para ,■  j  \' 

2,4-Xylenesulfonanilide  (2,4-Dimethylbenzenesulfonanilide) . . 

Xylenol,  crystals 

Xylenola 

•Low  b.p 

Medium  b.p 

High  b.p 


45,  245,  384. 

X. 

45,  282,  313. 

313. 

13,  33,  72,  95,  129,  176,  282,  313, 

511. 
13,  282. 
45,  245,  384. 
45. 
313. 
95. 

129,  320,  351. 
149. 

127,  129,  203,  307,  313. 
X. 
X. 

127,  307,  512,  520. 

45,  72,  319,  X. 

307. 

13,  72,  95,  129,  159,  176,  204,  313, 

480. 
176. 

136,  348. 
129. 

176,  351. 
13.  176. 
22. 

129,  176,  313. 
127,  207. 
127. 
129. 

207i  380. 
129,  176,  313. 
72,  95,  129,  282,  313,  357. 
313. 
313 

95.  129,  176,  313,  348,  X. 
176. 
307. 
307,  X. 
307. 

129,  136,  307,  X. 
1.36.  480. 
307. 
307. 

51.233,  294,  X,  X. 
129,  176,  313. 
72,  129,  159,  176,  313. 
129,  203,  313. 
72. 
176. 
95.  313. 

72.  129,  176,  313. 

51,  233,  286,  X. 

176. 

13,  72,  95,  129,  176,  313,  X. 

176. 

72.  129.  176.313. 

72.  95,  129,  176,  313. 

72,  X. 

95,  129,  313. 

72,  176. 

127. 

127,  129,  207,  307. 

176. 

127. 

203,  207,  307. 

176. 

319. 

307. 

307. 

176. 

176. 

72,  129,  176,  349. 

129,  X. 

45,  129,  176. 

176. 

45. 

45. 

72.  384,  387,  X. 

72,  384. 

72.  384. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


81 


Table  5B. — Synthetic  organic  chemicals:  Cyclic  intermediates  for  which   United   States 
production  or  sales  were  reported,  identified  by  manufacturer,  191fl-lf3 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


Xylidines: 

*XvIidine,  ortho  and  para. 

*2,4-Xylidine  (m-4-Xylidine) 

2,5-Xylidine  (p-Xylidine) 

•Mixed  Xylidines 

2,4-Xylidine  acetate 

4-(2,4-Xylylazo)-o-tokudine  (Aminoazoxylene-toluidine) 

4-(2,4-XylylaEo)-2,.5-xylidine  (Aminoazoxylene) 

Xylyl  disulfide 

Other  intermediates 


13,  72,  129. 

13,  129,  176,  313. 

176. 

13,  72,  95,  129,  176,  294,  313. 

282,  313. 

72,  313. 

13,  176,  313. 

207. 

129,  X. 


DYES 

Table  lOB. — Synthetic  organic  chemicals:  Coal-tar  dyes  for  which  United  States  produc- 
tion or  sales  ivere  reported,  identified  by  manufacturer,  19^1— It3 

[Dyes  for  which  separate  statistics  are  given  in  table  lOA  are  marked  below  with  an  asterisk  (*) ;  dyes  not 
so  marked  do  not  appear  in  table  lOA  because  the  reported  data  are  confidential  and  may  not  be  pub- 
lished. Manufacturers  are  identified  by  numbers  in  the  alphabetical  list  appearing  on  p.  135.  An  X 
signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number  with  the 
designated  product.] 


Colour 
Index 


Prototype 
No. 


Dye 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


10 
11 


15 
16 
17 
19 
20 
21 
24 
26 
27 
29 
30 
31 
32 
36 
40 
44 
52 
53 
54 
56 
57 
68 
69 
73 
79 
84 
88 
90 
98 
99 
101 
105 
110 
113 
114- 
117 
118 
119 
122 
126 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBERS 

Nilroso  Dyes 


Fast  printing  green. 
Naphthol  green  B. . 


Naphthol  yellow  S. 
Amido  yellow  E . .  . 


Nitro  Dyes 


Azo  Dyes 
Monoazo  Dyes 

Spirit  yellow  G 

'Acid  yellow  G 

'Spirit  yellow  R 

'Oil  yellow 

'Chrysoidine  Y 

'Chrysoidine  R 

'Sudan  I 

Croceine  orange  G 

■Orange  G 

Chromotrope  2R 

Fast  acid  f uchsine  B 

'Amido  naphthol  red  G 

Brilliant  sulphon  red 

'Chrome  yellow  2G 

'Chrome  yellow  R 

Paranitraniline  red 

*Azo  alizarin  yellow  GP 

'Victoria  violet  4BS 

Lanaf  uchsine 

Chromotrope  6B , 

'Amido  naphthol  red  6B 

Fast  scarlet  G  base 

Toluidine  red  RL 

Sudan  II 

'Ponceau  R 

Double  ponceau 

•Fast  red  B 

Chromotrope  lOB 

•Chrome  brown  R 

Chrome  green  2G 

Chromate  brown  B 

Acid  chrome  brown  R . 

Chrome  flavine  G 

Sudan  R 

Azo  eosine  G 

'Fast  red  B  base 

Azo  orange  NA 

Eosamine  G 

Chrome  yellow  5G 

Direct  pink  2GN 


176. 
72. 


72,  95,  313. 
176. 


176. 

13,  72,  176. 

13,  72,  107,  163,  176,  313. 

13,  72,  107,  129,  163,  176,  313. 

72,  129,  176,  313,  320. 

72,  176,  313,  320. 

13,  72,  107,  129,  163,  176,  313,  X. 

95,  313. 

72,  95,  129,  176,  313. 

313 

13,  313,  510. 

13,  72,  95,  107,  129,  176,  313. 

510. 

13,  55,  72,  89,  95,  176,  282. 

13,  55,  72,  95,  176,  507,  X. 

176,  X. 

13,  95,  176,  313. 

72,  95,  129,  176,  313. 

95,  X. 

95,  313. 

13,  72,  89,  95,  129,  176,  313. 

13,  176. 

422 

13,  72,  163,  176,  313. 

13,  72,  95,  129,  176,  313,  320. 

129,  176. 

72,  95,  176,  313. 

129. 

72,  95,  176,  313. 

176. 

72,  89,  370. 

129,  282. 

89,  176,  370. 

163. 

129,  176. 

13,  176,  282,  X. 

13.  176,  282,  X. 

129. 

95. 

129. 


646064—46—6 


82 


UNITED  STATES  TARIFF  COMMISSION 


Table  lOB. — Synthetic  organic  chemicals:  Coal-tar  dyes  for  which  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  19^1~Jf3 — Continued 


Protot\Tie 
No. 


DYES  GROUPED  BY  COLOUR 

INDEX  NUMBERS— Continued 

Azo  Dyes — Continued 

Monoazo  Dyes — Continued 

Direct  pink 

Direct  fast  pink  EBN 

Janus  black  B 

♦Metanil  yellow 

Methyl  orange 

* Azoflavine  RS 

*Azo  yellow 

Resorcin  yellow 

*Orange  II 

Hansa  rubine 

•Orange  R '■ •  • 

•Pigment  rubine  B 

Lake  red  C 

Acid  chrome  brown  B 

•Acid  chrome  garnet  R 

Acid  chrome  violet  N 

Chrome  black  PV 

Acid  chrome  black  R 

Naphthylamine  brown 

•Fast  red  A 

•Azo  rubine 

•Fast  red  VR 

Croceine  scarlet  3BX 

Amaranth 

Cochineal  red  A 

Lake  red  R 

'Mordant  yellow  O 

Chrome  yellow  RN 

•Chrome  blue  black  B 

•Chrome  blue  black  R 

•Chrome  black  T 

•Chrome  black  A 

•Fast  acid  blue  R 

•Fast  acid  blue  B 

Lake  red  D 

•Acid  chrome  red  B 

•Chrome  flavine  A 

Direct  pink  2B 


DisazolDyes 

•Resorcin  brown 

•Resorcin  dark  brown 

Chrome  brown  G 

Acid  black  lOB 

Azo  dark  green  A 

Cloth  red  G 

Brilliant  croceine  M 

Ponceau  SS  ex 

Erj'thrine  P 

Cloth  red  3G  ex 

Sudan  IV 

•Cloth  red  B 

Neutral  gray  G 

•Milling  orange 

•Cloth  scarlet  G 

Direct  fast  red  8BL 


•Scarlet  EC 

•Fast  acid  cyanine  G 

•Fast  acid  cyanine  oR  ex 

Naphthalene  acid  black  4B 

Acid  chrome  verdone  A 

Acid  black  B 

•Acid  chrome  black  F 

•Acid  chrome  green  SS 

•Fast  acid  black  2BN 

Fast  acid  black  F 

•Fast  acid  cyanine  black  B 

Naphthylamine  black  D 

Brilliant  black  B 

•Developed  blue  NA 

•Developed  blue  B 

Naphthylamine  black  V 

•Direct  fast  heliotrope 

Developed  brilliant  orange  GR  ex. 

Direct  brilliant  violet 

•Direct  fast  scarlet 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


176,  313. 

129. 

176. 

95,  129,  176,  313. 

129. 

13,  95,  176. 

13,  176,  313. 

72,  176,  313. 

72,  95, 107,  176,  204,  313,  320,' 510. 

176. 

72,  129,  313. 

95,  129,  313. 

72. 

313. 

95,  176,  313. 

95,  129,  313,  370. 

176,  313. 

176. 

176. 

72,  95,  129,  176,  313. 

13,  95,  129,  176,  313. 

72,  95,  176,  313. 

95. 

13,  95,  313. 

72,  95,  176,  313. 

422 

89,  95,  176,  313. 

13,  95,  176,  313. 

95,  176,  313. 

95,  129,  176,  313. 

95,  176,  313. 

95,  176,  313,  370. 

72,  129,  176,  313. 

129,  176,  313. 

422 

72,  95,  129,  176,  313,511. 

13,  95,  129,  176,  313,  357,  370. 

129,  349. 

13,  72,  95,  107,  129,  176,  313,  510. 

13,  72,  95,  176,  313,  510. 

129  313. 

13,  72,  9'o,  129,  176,  313,  510. 

95,  129. 

95. 

72,  95,  129,  176,  313. 

313. 

176. 

72  129. 

95',  107',  129,  163,  176,  313. 

13,  95,  176,  313. 

89,  129. 

13,  72,  95,  176. 

13,  72,  95,  129,  510,  X. 

13,  55,  72,  89,  95,  129,  176,  313, 

357,  510,  X. 
13,  176,313. 
72,  89,  95,  176,  313. 
72,  89,  129,  176,  313. 
176. 
72. 

176,  313. 

72,  95.  129,  176,  313. 
72,  129,  176. 
95,  129,  176. 
176. 

72,  89,  129,  176,  313. 
176. 
176. 

72,  95,  129,  176,  313. 
95,  129,  176,  313. 
129. 

89,  '95,  129.  176. 
89,  129,  176,  357. 
13,  176. 
13,  72,  89,  95,  129,  176,  313,  X. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


83 


Table  lOB. — Synthetic  organic  chemicals:  Coal-tar  dyes  for  u-hich  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  19^1-4.3 — Continued 


Colour 

Index 

or 

Prototype 

No. 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


DYES  GROUPED  BY  COLOUR 

INDEX  NUMBERS— Continued 

Azo  Dyes — Continued 

Disazo  Dyes — Continued 

Direct  fast  scarlet  4BA 

'Bismarck  brown  G 

Bismarck  brown  R 

Acid  chrome  black  SE 

'Chrome  fast  yellow  C 

Direct  fast  yellow  5GL 

Direct  fast  yellow  4GL  ex 

Para  fast  brown  GR 

Direct  fast  pink  2BL 

Brilliant  yellow 

Chrysophenine  G 

Congo  red 

Congo  corinth  G 

Congo  rubine 

Direct  orange  G 

Direct  scarlet  B 

Direct  violet 

Direct  violet  B 

Benzo  violet  O 

Direct  violet  N 

Direct  black  RO 

Direct  brilliant  Bordeaux  R 

Developed  black  BH 

Direct  cyanine  R 

Direct  blue  2B 

Brilliant  orange  G 

Chrysamine  G 

Cresotine  yellow  G 

Direct  orange  R 

Direct  fast  red  F 

Direct  brown  M 

•Direct  brown  B 

Polar  red 

Acid  chrome  red 

Direct  brilliant  red  SB 

■•Chrome  fast  yellow  RD 

Milling  red  G 

Direct  orange  R 

Benzopurpurine  4B 

Direct  blue  3R 

Direct  blue  4R 

Direct  blue  BX 

Direct  blue  3B 

Direct  orange  G 

Acid  anthracene  red  3B 

Benzopurpurine  lOB 

Fast  blue  B  base  and  salt 

Direct  azurine  G 

Direct  brilliant  blue  G 

Direct  blue  RW 

Direct  blue  B 

Chicago  blue  B 

Direct  sky  blue  FF 

*Direct  pure  blue 

Trisazo  Dyes 

Direct  fast  blue  FR 

Naphthogene  blue  4R 

Direct  fast  black  FF 

Pluto  black  5BS 

Plutoform  black 

Diazo  blue  black  RS 

Direct  bronze  G 

Direct  brown  BT 

Direct  fast  blue  R 

Direct  fast  blue  B 

Chlorazol  brown  2G 

Direct  black  EW 

Direct  black  RX 

•Direct  green  ET 

Chloramine  green  B 

Direct  steel  blue  G 

•Direct  green  B 

•Direct  green  G ;;;;:::;;; 


13,  95,  176. 

72,  129,  176,  313. 

72,  95,  129,  176,  313. 

176. 

72,  89,  95,  282,  313,  357. 

72,  129,  176,  313. 

89. 

176. 

72,  129,  176,  313. 

72,  129,  176,  313. 

129,  176,  313. 

72,  129,  313. 

13,  55,  72,  95,  129,  176,  313,  510. 

95.x. 

176,  313. 

13,  55,  72,  95,  176,  313,  510,  X. 

95. 

95;  129,  176,  510. 

176. 

13,  72,  95,  129,  176,  313. 

13. 

313. 

72,  95,  129.  176.  3l3,  510. 

313. 

13.  72,  95,  107,  129,  176,  313,  510. 

95,  129,  176. 

129. 

95,  313.  510. 

95,  129,  176,  313. 

13,  55,  72,  89,  95.  129,  176,  313, 

510. 
13,  55,  72.  95,  129,  176,  313.  510. 
72.  95.  510. 

72,  89,  95,  129,  176.  313.  510,  X. 
129. 
95. 

176,  313.  357. 
13,  72,  89,  95. 
13,313. 
95.  129.  313. 
129. 

95.  313. 

95,  129,  176,  313. 
13.  95.  107,  129,  313. 
13,  95,  313. 

13,'  72!  89,  95,  176.  313.  357. 
95.  129,  313,  510. 
172,  176,  313,  X. 
13.  95,  129,  176,  313,  510. 
129 

13,  55,  95,  129,  176.  313. 
313. 
176. 

13.  55.  95.  129,  176.  313. 
55,  95,  129,  176,  313. 


13,  72,  95,  129. 

176. 

72,  95.  129.  176.  313. 

176. 

72,  89,  95. 

129,  313. 

176. 

13,  55,  95,  129,  176,  313.  .357,  510, 

X. 
95. 

95,  129.  313. 
72. 

72.  95.  129,  176,  313,  510. 
72,  95,  129,  176,  313,  510. 
13,  72,  95,  129,  176,  313.  510. 
72,  95,  129,  176,  313.  510. 
55   129 
13',  72,  89.  95.  129,  176,  313.  370, 

510. 
95.  129.  113.  510. 


84 


UNITED  STATES  TARIFF  COMMISSION 


Table  lOB. — Synthetic  organic  chemicals:  Coal-tar  dyes  for  ichich   United  States  produc- 
tion or  sales  icere  reported,  identified  by  manufacturer,  19^1-^3 — Continued 


Dye 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


DYES  GROUPED  BY  COLOUR 

INDEX  NUMBERS— Continued 

Azo  Dyes — Continued 

Trisazo  Dyes — Continued 

Direct  olive  G 

♦Direct  brown  3G0 

*Congo  brown  G 

Congo  brown  R 

Tetrakisazo  Dyes 

'Direct  brown  G 

Naphthamine  fast  black  RS 

Stilbene  Dyes 

'Direct  yellow  R 

'Chloramine  orange  G 

'Stilbene  yellow 

Diphenyl  catechine  G 

Diphenyl  chrysoine  G 


Pyrazolone  Dyes 


'Fast  light  yellow  G . 
'Xylene  light  yellow. 


'Tartrazine 

Polar  yellow 

Dianil  yellow  3G 

Pigment  fast  yellow  G .  .  . 

'Chrome  red  B 

'Pyrazol  orange 

Developed  fast  yellow  2G  . 


Ketonimine  Dyes 

*Auramine 

Triphenylmethane  and  Diphenylnaphthylmethane  Dyes 

"Malachite  green 

*Rhoduline  blue  6G 

"Brilliant  green 

Setocyanine 

*Acid  green  B 

"Fast  acid  green  B 

Acid  light  green 

*Aeid  glaucine  blue 

*Para  f  uchsine 

"Magenta 

"Methyl  violet  B  and  base 

"Crystal  violet 

"Ethyl  violet 

Benzyl  violet ? 

Spirit  blue  2B 

Victoria  blue  4R 

Fast  green  bluish 

Acid  magenta 

Fast  acid  violet  lOB 

"Acid  violet 

Acid  fast  violet  BG 

Alkali  blue  6B 

Methyl  blue 

Methyl  cotton  blue 

"Soluble  blue 

Brilliant  sky  blue  5G 

•Patent  blue  V 

"Patent  blue  A 

"Acid  chrome  azurol  B 

"Acid  chrome  cyanine  R 

Aurine 

Victoria  blue  R 

"Victoria  blue  B 

"Naphthalene  green  V 

"Wool  green  S 

Xanlhene  Dyes 

Rhodamine  B,  20% 

Rhodamine  B  cone.  100% 

Rhodamine  6G  cone.  100% 

Fast  acid  violet  A2R 

"Fluorescein  and  salt 

"Tetrabromofluorescein  (Eosine) 

Ery throsine  bluish 

Phloxine 

1  Rose  bengale  B 


176. 

13,  72,  95,  129,  176,  313,  .510. 

13,  55,  95,  129,  176,  313. 

129. 


72,  176,  510. 
176. 


72,  95,  129,  176,  313. 

72,  95,  129,  176,  313. 

72,  129,  176. 

313. 

95. 


13,  129,  176,  313,  357. 

13.  55,  72,  89,  95,  129,  176,  313, 

357. 
13,  72,  176,  204,  313,  357. 
95,  176,  .357. 
176. 
176. 

72,  89,  95,  129,  176,  313. 
13,  55,  95,  313,  357. 
129. 


72,  129,  282,  313. 


72,  132,  282,  313. 

129,  132,  176,  204,  282,  313. 

72,  132,  282,  313. 

129,  176. 

72,  95,  129,  176,  204,  282,  313. 

72,  129,  176,  282,  313. 

129,  176. 

72,  129,  176,  204,  282,  313. 

72,  320,  X. 

72,  95,  176,  320,  X. 

72,  129,  132,  176.  313,  X,  X. 

129,  132,  176.  204,  313. 

129,  132,  176. 

132. 

176. 

176. 

13. 

176. 

129,  282. 

72,  89.  95.  129,  176,  204,  282,  313. 

313. 

176,  320. 

176,  320. 

72,  320. 

72,  176,  X. 

176. 

176,  204,  313. 

72,  176,  204,  313. 

95,  129,  176,  313. 

95,  129,  176,  313. 

129 

129,'  176,  204. 

129,  176,  204,  313. 

129,  176,  282,  313. 

72,  129,  176. 


129,  282. 

129,  282. 

129.  282. 

X. 

22,  72,  204,  313.  320. 

13,  22,  72,  204,  227.  313,  320.  X. 

72,  320. 

320. 

72,  320. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


85 


Table  lOB. — Synthetic  organic  chemicals:  Coal-tar  dyes  for  which  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  19^1~43 — Continued 


Prototype 
No. 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


DYES  GROUPED  BY  COLOUR 

INDEX  NUMBERS— Continued 

Acridine  Dyes 

Acridine  orange  NO 

•Phosphine 

Phosphine  2G 

Euclirysine  2G 

Quinoline  Dyes 

Quinoline  yellow,  spirit  soluble 

•Quinoline  yellow 

Quinoline  yellow  KT 

Thiazole  Dyes 
'Primuline 

Direct  pure  yellow  M 

'Direct  fast  yellow 

ThioflavineT 

Direct  brilliant  flavine  S 

Azine  Dyes 

•Wool  fast  blue 

*Safranine 

Methylene  violet 

Safranine  MN 

Acid  cyanine 

'Induline  (spirit-soluble) 

'Induline  (water-soluble) 

'Nigrosine  (spirit-soluble) 

'Nigrosine  (water-soluble) .  .* 

Aniline  Black  and  Allied  Dyes 

Diphenyl  black  base 

New  fast  gray 

Fur  black .  ." 

Oxazine  Dyes 

Gallocyanine 

'New  blue  R 

Nile  blue  A ■ . 

Thiazine  Dyes 

'Methylene  blue 

Methylene  green  B 

New  methylene  blue  N 

Brilliant  chrome  blue 

Sulfur  or  Sulfide  Dyes 
Derivatives  of  Carbazole 

Carbazole  vat  blue  R 

Carbazole  vat  blue  G 

Other  Sulfur  or  Sulfide  Dyes 

'Sulfur  black 

'Sulfur  blue 

'Sulfur  brown 

'Sulfur  green 

'Sulfur  maroon 

'Sulfur  olive 

'Sulfur  orange 

'Sulfur  tan 

'Sulfur  yellow 

Anthraquinone  Dyes 

Alizarin  VI 

'Alizarin  red  S 

Alizarin  brown 

Alizarin  SX 

Pseudopurpurine 

'Acid  alizarin  blue  SE 

'Acid  alizarin  blue  B 

Anthracene  blue  SWGG 

Anthracene  blue  WR ■. 

Anthracene  blue  SWX 

'Alizarin  irisol  R 

Alizarin  astrol  B 

Cyananthrol  R 


129,  176,  357. 

72,  95,  129,  176,  313,  357. 

357. 

176,  357. 


282. 

129,  282,  313. 

282. 


95,  129,  313. 

129. 

95,  129,  176,  313,  349. 

129. 

349. 


95,  129.  176,  313. 
72,  129,  176,  313. 
176. 
313. 

129,  176. 
72,  176,  313. 
72,  176,  313. 
72,  176,  313. 
72,  176,  313. 


176. 
72,  357. 


72,  313,511. 
13,  72,  313. 
176. 


72,  129,  132,  176,  313. 

72. 

72. 

176. 


129,  176. 
129,  176. 


41,  72,  129,  176,  313,  X. 

41,  72,  95,  129,  176,  215,  313,  X. 

41,  72,  95,  114,  129,  176,  215,  313, 

X. 
41,  72,  129,  176,  215,  313. 
41,  72,  129,  176,313. 
41,  72,  95,  114,  129,  176,  215,  313, 

X. 
95,  129,  176,  313. 
41,  72,95,  129,  176,215. 
41,  72,  95,  114,  129,  176,  215,  313, 

X. 

13,  72,  176,  313. 

13,  72,  176,  313. 

313,511. 

313. 

176. 

33,  72,  95,  129,  176,  313. 

33,  72,  89,  95,  129,  176,  313,  511. 

33 

89^  176,  313. 

33. 

33,  129,  511. 

129,  176. 

129. 


86 


UNITED  STATES  TARIFF  COMMISSION 


Table  lOB. — Synthetic  organic  chemicals:  Coal-tar  dyes  for  which  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  iP^i-^^— Continued 


Prototype 

No. 


Dye 


DYES  GROUPED  BY  COLOUR 
INDEX  NUMBERS— Continued 
.4  nihraquinone  Dyes — Continued 
'Alizarin  cyanine  green 


Acid  anthraquinone  violet .  .  . 
'Anthraquinone  blue  black  B  . 


*Acid  anthraquinone  sky  blue  B. 

Anthraquinone  blue  SR 

Acid  alizarin  rubine 


Anthraquinone  Val  Dyes 

vat  yellow  GC,  12i-^% 

vat  golden  orange  G,  12% 

vat  golden  orange  R,  12% 

vat  scarlet  G,  16%% 

vat  dark  blue  BO,  25% 

vat  navy  blue  G 

vat  jade  green,  6% 

vat  green  B  and  black  B,  123^%. 

vat  violet  R,  25% 

vat  violet  2R,  12}^% 

vat  violet  B,  25% 

vat  blue  RS,  10% 

vat  blue  3G,  10% 

vatblueGCD,  8}^% 

vat  blue  BCS,  20% 

vat  yellow  G,  12H% 

vat  brown  B,  22% 

vat  pink  R,  121^% 

vat  yellow  GK,  12!-^% 

vat  red  FF,  extra,  12"^% 

vat  brilliant  violet  2B,  12i^%  . . . 
vat  brilliant  violet  RK,  12J^%.  . 

vat  olive  R,  12J^% 

vat  brown  R,  12}^% 

vat  brown  G,  12J^% 

vat  red  violet  RRN,  12H% 

vat  red  BN,  extra,  12>^% 

vat  violet  BN,  25% 

vat  vellow  R,  12>^% 

vat  blueSG 


'Anthraquinone 
'Anthraquinone 
'Anthraquinone 

Anthraquinone 
'Anthraquinone 

Anthraquinone 

Anthraquinone 
'Anthraquinone 

Anthraquinone 
'Anthraquinone 

Anthraquinone 
•Anthraquinone 

Anthraquinone 
'Anthraquinone 
'Anthraquinone 
'Anthraquinone 

Anthraquinone 

Anthraquinone 

Anthraquinone 

Anthraquinone 

Anthraquinone 

Anthraquinone 
'Anthraquinone 
'Anthraquinone 

Anthraquinone 

Anthraquinone 

Anthraquinone 

Anthraquinone 

Anthraquinone 

Anthraquinone 

Indigoid  and  7^hioindigoid  Dyes 
'Indigo,  svnthetic,  20% 

Indigo  white,  20% 

Indigotin  lA 

Tribromindigo  RB,  20% 

'Broniindigo  blue  2BD,  16% 

Vat  blue  5B,  20% 

Brilliant  indigo  B 

Ciba  pink  B,  20% 

Vat  red  B,  12^% 

'Vat  red  3B,  20% 

'Vat  orange  R,  10% 


Food,  Drug,  and  Cosmetic  Dyes 

■Blue*l 

■Blue*  2 

'Green  *  1 

'Green  *2 

Green  «3 

'Orange  *  1 

Orange  *  2 

'Red  *  1 

'Red  #2 

•Red  #3 

Red  *4,  *32 

Yellow  «  1 

Yellow  «  3,  *  4 

'Yellow  *  5 

'Yellow  *6 

Yellow  *22,  *61 


Drug  and  Cosmetic  Dyes 

Black  *  1 : 

Blue  «1,  *4,  *6,  *9 

Brown  *  1 

Green  *1,  «5,  #6,  *7 

Orange  *1,  «3,  «4,  *o,  « 10,  *11,  *14,  *15,  *17. 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


13,  33,  72,  89,  129,  176,  313,  511, 

X. 
33,  129. 
13,  33,  72,  89,  95,  176,  282,  313, 

37p,  511. 
129,  176,  313. 
33. 
176. 


72,  129,  176. 

72,  129,  176,  313. 

72,  129,  176,  313. 

72,  313. 

13,  72,  129,  176,  313,  349. 

72. 

129,  176. 

72,  129,  176,  313,  349. 

176. 

13,  129,  176,  313. 

176. 

72,  129,  176,  313. 

129. 

72,  129,  176,313. 

72,  129,  176,  313. 

129,  176,  313. 

129,  313. 

176. 

129. 

129. 

129. 

129. 

13,  72,  129,  176,  313,  X. 

72,  129,  176,  313. 

72,  129,  176,  313. 

129,  176,  313. 

129,  313. 

129,313. 

129,  349. 

176. 


127,  129,  176,  313. 

313. 

129,  313. 

127,  313. 

127,  176,  313. 

127. 

313. 

127. 

313. 

72,  127,  129,  176,  313. 

72,  129,  176,  313. 


46,  313, 
46,  244, 
46,  313, 
46,  313, 
487. 
46,  244, 
313. 
46,  244, 
46,  244, 
46,  244, 
313,487 
244. 
1.33,313 
46,  244, 
46,  244, 
313. 


487. 

313,446,  487. 
487. 
487. 

313,  446,  487. 

313,446. 
313,  446,  487. 
313,  446. 


313,  446,  487. 
313,  446,  487. 


313. 

244,313. 

244,  313. 

244,  313. 

22,  244,  313,  X. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


87 


Table  lOB. — Synthetic  organic  chemicals:  Coal-tar  dyes  for  which  United  States  produc- 
tion or  sales  ivere  reported,  identified  by  manufacturer,  19^1—^3 — Continued 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


DYES  GROUPED  BY  COLOUR 

INDEX  NUMBERS— Continued 

Drug  and  Cosmetic  Dyes — Continued 

Red  «1,  «2,  «3,  *5,  *7,  «8,  #9,  *10,  «11,  *  12,  *16, 

*17,  *1S,  *19,  #21,  *22,  «24,  *28,  *29,  *30,  *31, 

*33,  *34,  *35,  «36,  «37,  *3S,  *39. 

Violet  *  1 

Yellow  *1,*5,  *6,  #7,  ijSS,  iJflO,  *11 

Drug  and  Cosmetic  Dyes,  External 

Blue  *  1 

Green  #1 

Orange  *  1 

Red*l,  «3,  *8,  *10,  *11,  «13 

Violet  *2 

Yellow  *1,  *5 

DYES  GROUPED  BY  FOREIGN  PROTOTYPE 
NUMBERS 

Acid  alizarin  flavine  R 

Acid  anthracene  brown  B .' 

Acid  anthracene  brown  3B 

*Acid  anthracene  brown  PG 

Acid  chrome  blue  2R 

Alizarin  direct  blue  A2G 

Alizarin  direct  blue  AR 

Alizarin  supra  blue  A 

Alkali  fast  green  lOG 

'Anthracene  chromate  brown  EB 

•Artificial  silk  black  G 

*Benzo  Bordeaux  6B 

*Benzo  chrome  black  blue  B 

Benzo  chrome  brown  BS 

Benzo  copper  blue  B 

Benzo  dark  brown  ex 

*Benzo  fast  black  L 

♦Benzo  fast  blue  4GL 

Benzo  fast  blue  8GL 

Benzo  fast  brown  3GL 

Brilliant  acid  blue  3B 

Brilliant  benzo  violet  B 

Brilliant  milling  blue  B 

Brilliant  wool  blue  FFR 

Cellitazol  B 

*Celliton  orange  GR 

Chlorantine  fast  blue  2GL '. 

*Chlorantine  fast  brown  BRL 

Direct  fast  red  5BL 

Chlorantine  fast  yellow  4GL 

Chlorantine  fast  yellow  RL 

Chrome  yellow  DS 

Chrome  yellow  G 

Cibacete  diazo  black  B 

Cibacete  sapphire  blue  G 

Cotton  black  3G 

Diamine  azo  Bordeaux  B 

Diamine  Bordeaux  B 

Diamine  catechine  G 

Diamine  catechine  3G 

♦Diamine  fast  blue  FFB 

♦Diamine  fast  orange  EG 

♦Diamine  fast  orange  ER 

Diaminogen  blue  N2B 

♦Diazo  Bordeaux  7B 

♦Diazo  brilliant  green  3G 

♦Diazo  brilliant  scarlet  2BL  ex 

Diazo  brilliant  scarlet  ROA 

Diazo  brown  NR 

Diazo  brown  3RB 

Diazo  fast  red  5BL 

Diazo  fast  red  7BL. 

Diazo  indigo  blue  4GL 

♦Diazo  rubine  B 

Diazo  sky  blue  B 

Diazo  sky  blue  3GL 

Fast  mordant  blue'B 

♦Fast  scarlet  2G  base,  salt 

Fastusol  brown  L3R 

Fastusol  gray  R 

Fastusol  orange  L5G 


22,  176,  227,  244,  313,  X,  X. 


244,  313. 
22,  244,  313. 


313. 
313. 
244. 

244,  313. 
244. 
244,  313. 


313. 

72. 

95 

IS,  89,  95,  176,  357,  510. 

95,  176. 

176. 

176. 

129,  176. 

129,  176,  313. 

13,  72,  89,  95,  129,  176,  313,  510. 

95,  176,  313,  510. 

13,  95,  176,  313. 

95,  129,  176,  313. 

72,  176. 

176. 

176. 

13,  95,  129,  176,  313. 

89,  176,  357. 

357. 

176,  313. 

13. 

13,  95. 

129,  176. 

176,  313. 

72. 

72,  129,  176,  360. 

95. 

95,  176,  313,  357. 

95. 

95,  357. 

95,  357. 

95. 

72. 

95. 

95. 

176. 

313. 

13,  313. 

13,313. 

13,  72,  313. 

13,  95,  176,  313. 

72,  89,  95,  176.      " 

72,  89,  176,  215. 

13  313 

13!  89,  129,  176,  357. 

176,  313,  357. 

89,  129,  176,  313. 

176,  357. 

176. 

176,  313. 

89. 

89,  129,  3.57. 

129,  176. 

89,  176,  357. 

176. 

176. 

511. 

13,  176,  282,  313,  .357,  X. 

176. 

176. 

176. 


88 


UNITED  STATES  TARIFF  COMMISSION 


Table  lOB. — Synthitic  organic  chemicals:  Coal-tar  dyes  for  which  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  1941—43 — Continued 


Colour 

Index 

or 

Prototype 

No. 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  13.5) 


99 
101 
102 
103 
104 
105 
108 
109 
112 
116 
118 
121 
122 
123 
124 
128 
134 
135 
137 
138 
139 
140 
141 
142 
143 
144 
145 
146 
147 
148 
151 
152 
155 
163 
164 
165 
166 
168 
169 
170 
171 
172 
173 
174 
176 
178 
180 
181 
182 
186 
187 
188 
189 
190 
191 
192 
193 
194 
195 
197 
198 
199 
201 
202 
203 
204 
205 
207 
208 
209 
210 
211 
212 
213 
214 
215 
216 
217 
218 


DYES  GROUPED  BY  FOREIGN  PROTOTYPE 

NUMBERS— Continued 

Fastusol  yellow  L5G 

'Guinea  fast  red  BL 

Guinea  fast  red  4BL 

Hansa  yellow  G 

Hansa  yellow  5G 

Hansa  yellow  lOG 

Helindone  pink  B  ex 

Helindone  pink  R  ex 

Helio  red  RMT 

Indanthrene  brilliant  orange  RK 

Indanthrene  brown  BR 

*  Indanthrene  brown  RRD 

•Indanthrene  khaki  2G 

Indanthrene  pink  B 

Indanthrene  rubine  R  dbl 

Indocyanine  B 

Metachrome  Bordeaux  R 

Metachrome  red  G 

Milling  orange  G 

Mining  yellow  H5G 

Milling  yellow  O . 

Monochrome  blue  black  B 

Naphthol  blue  black  S 

Naphtogene  blue  B 

Neolan  black  WA 

Neolan  blue  GG 

Neolan  Bordeaux  R 

Neolan  orange  R 

Oxydiaminogen  OB 

Paper  red  A  ex 

Polar  orange  GS 

Polar  orange  R 

Polypheny]  dark  blue  SR 

Rapidogen  blue  BN 

'Rapidogen  blue  D 

Rapidogen  Bordeaux  R 

Rapidogen  brown  GN 

Rapidogen  red  GS 

Rapidogen  red  RS 

Rapidogen  .scarlet  RS 

Rapidogen  yellow  G 

'Rosanthrene  fast  Bordeaux  2BL 

Rosanthrene  orange  R 

Setacvl  direct  orange  2R 

Silk  black  4BF 

Sudan  brown  5B 

Sudan  orange  2R 

Sudan  orange  RT 

Sudan  red  BB 

Sulphon  orange  G 

'Sulphon  yellow  R 

Supra  light  rubine  BL 

Supramine  black  BR 

Supramine  blue  R 

Supramine  Bordeaux  B 

Supramine  brown  R 

Supramine  red  3B 

Supramine  red  2G 

Supramine  yellow  R    

Victoria  fast  violet  2R  ex 

Victoria  pure  blue  B 

Victoria  violet  RL 

'Zambesi  black  D 

'Zambesi  black  V 

Acid  anthracene  brown  KE 

Acid  anthracene  brown  LE-CF 

Acid  anthracene  brown  WSG 

Alizarin  supra  sky  R 

Alphanol  brown  B 

Amido  naphthol  brown  3G 

Anthralan  red  B-CF 

Azosol  fast  orange  G 

Azosol  fast  orange  RR 

Azosol  fast  red  3B 

Azosol  fast  scarlet  CR 

Azosol  fast  scarlet  CGG 

Azosol  fast  yellow  GR 

Benzo  fast  Bordeaux  6BL 

Benzo  fast  brown  RL 


176. 

72,89,  129,  176,  313. 

89. 

72. 

129. 

129. 

72. 

72,  129,  313. 

176. 

176. 

176. 

72,  95,  129,  176,  .'{.J?. 

72,  129,  176,  313. 

129. 

129,  176. 

176. 

89. 

511. 

13. 

13.  176. 

313. 

95. 

13,  313. 

95. 

95. 

95,  176. 

95. 

95. 

13,  176,313. 

176. 

95 

95,  176,  313. 

95. 

176. 

129,  176,  3.37. 

176,  357. 

176. 

176,  357. 

129,  176,  357. 

176,  357. 

176,  ,357. 

13,  89,  95,  129,  176,  .357. 

95,  176,  357. 

72. 

95.. 

176. 

72   . 

176. 

176. 

13,  176. 

13,  72,  95,  176,  .357. 

176,313. 

13,  176. 

176. 

176. 

13. 

13,  176. 

176. 

176. 

72,  313. 

176. 

95 

95,'  176,  313. 

95,  176,  313. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


89 


Pable  lOB. — Synthetic  organic  chemicals:  Coal-tar  dyes  for  ichich  United  States  produc- 
tion or  sales  were  reported,  identified  by  mannfacturer,  191(1-43 — Continued 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


DYES  GROUPED  BY  FOREIGN  PROTOTYPE 
NUMBERS— Continued 

Benzoform  blue  BBL 

Benzo  new  blue  5B 

Brilliant  indocyanine  6B-CF 

Brilliant  indocyanine  G 

Brilliant  sulpho  tiavine  FFA 

Celliton  blue  G 

Celliton  fast  blue  B 

Celliton  fast  blue  FR 

Celliton  fast  blue  FFR    .  .* 

Celliton  fast  blue  green  B 

Celliton  fast  brown  3R 

Celliton  fast  brown  5R 

Celliton  fast  navy  blue  B 

Celliton  fast  navy  blue  BR 

Celliton  fast  pink  B 

Celliton  fast  pink  FF3B 

Celliton  fast  red  GG 

Celliton  fast  red  violet  RN 

Celliton  fast  rubine  B 

Celliton  fast  rubine  3B 

Celliton  fast  violet  B 

Celliton  fast  violet  6B 

Celliton  fast  yellow  G 

Celliton  fast  yellow  RR ; 

Celliton  scarlet  B 

Celliton  yellow  5G 

Chrome  fast  orange  3RL 

Diazo  brown  3R 

Diazo  fast  yellow  2G 

Diazo  fast  yellow  3G 

Fast  black  B  salt 

Fast  black  K  salt 

Fast  black  LB  base 

Fast  blue  BB  base,  salt 

Fast  Bordeaux  BD  salt -. 

*Fast  Bordeaux  GP  base,  salt 

Fast  Corinth  X  salt 

♦Fast  garnet  GBC  base,  salt 

Fast  garnet  GC  salt 

Fast  orange  GC  base,  salt 

Fast  orange  GR  base,  salt 

Fast  orange  RD  salt 

Fast  red  AL  salt 

Fast  red  GL  base,  salt 

Fast  red  3GL  base,  salt 

♦Fast  red  KB  base,  salt 

Fast  red  RC  base,  salt 

Fast  red  RL  base,  salt 

♦Fast  red  TR  base,  salt 

Fast  violet  B  base,  salt 

Fast  yellow  GC  base,  salt 

Fastusol  orange  LGGL 

Fastusol  red  violet  LRL ...........': 

Fastusol  turquoise  blue  LGL 

Hansa  yellow  GA 

Hiinsa  yellow  3R 

Heliogen  blue  B 

Heliogen  green  G 

Indanthrene  brilliant  orange  GR 

Indanthrene  direct  black  RB 

Indanthrene  golden  orange  3G 

Indanthrene  golden  yellow  GK 

Indanthrene  golden  j'ellow  RK 

♦Indanthrene  olive  green  B 

Indanthrene  red  FBB 

Monochrome  black  blue  G 

Monochrome  red  FG 

Monochrome  violet  FB 

•Naphthol  AS 

•Naphthol  .4.S-BO 

♦Naphthol  AS-BR 

'Naphthol  AS-BS 

•Naphthol  AS-D 

Naphthol  AS-DB 

Naphthol  AS-E 

Naphthol  AS-G 

Naphthol  AS-ITR 

♦Naphthol  AS-OL 

Naphthol  AS-RL 


176. 

510. 

176. 

176. 

176. 

176. 

176. 

176. 

72,  176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176,  313. 

176. 

176,  313. 

176. 

176,  X. 

176. 

176. 

13,  176,  313,  357,  X. 

176. 

13,  176,  282,  313,  X. 

176. 

13,  176,313. 

176,  X. 

176. 

176,313. 

13,  176,  282,  357,  X. 

13,  176,  357,  X. 

13,  72.  176. 

13,  176,  313. 

176. 

13,  176,  313,  X. 

176. 

176,  282,  313. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176,  313. 

176. 

176. 

176. 

13,  72,  176,  313. 

176. 

176. 

176. 

176. 

13,  72,  176,  313. 

13,  176,  313,  X. 

13,  129,  176,  313. 

13,  72,  176,  313. 

13,  72,  176,  313,  357 

176. 

17G. 

13,  176. 

176. 

176,  313,  357. 

13,  176,  313. 


90 


UNITED  STATES  TARIFF  COMMISSION 


Table  lOB. — Synthetic  organic  chemicals:  Coal-tar  dyes  for  which  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  19Jtl-Jf3 — Continued 


Colour 
Index 


Prototype 
No. 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


313 

314 
315 
316 

318 
320 
321 
322 
323 
324 
325 
326 
327 
328 
329 
330 
331 
334 
335 
336 
337 
338 
339 
340 
341 
342 
343 
344 
345 
346 
347 
348 
349 
350 
351 
352 
353 
356 
357 
358 


DYES  GROUPED  BY  FOREIGN  PROTOTYPE 
NUMBERS— Continued 

Naphthol  AS-SW 

Naphthol  AS-TR 

Neolan  orange  G 

Neolan  j'ellow  GR  cone 

Palatine  fast  blue  BN 

Palatine  fast  claret  RN 

Palatine  fast  green  BLN 

Palatine  fast  marine  blue  REN 

Palatine  fast  orange  GEN 

Palatine  fast  orange  GN 

Palatine  fast  orange  RN 

Palatine  fast  pink  BN 

Palatine  fast  red  RN 

Palatine  fast  violet  3RN 

Palatine  fast  violet  5RN 

Palatine  fast  yellow  ELN 

Palatine  fast  yellow  GRN 

Rapid  fast  orange  RH 

Rapid  fast  red  FGH 

Rapid  fast  red  RH 

Rapid  fast  scarlet  ILH 

Rapid  fast  yellow  GGH 

Rapidogen  black  MG 

Rapidogen  black  brown  IT 

Rapidogen  blue  N 

Rapidogen  blue  R 

Rapidogen  brown  IB 

Rapidogen  brown  IPT 

Rapidogen  golden  yellow  R 

Rapidogen  golden  yellow  3R 

Rapidogen  green  B 

Rapidogen  orange  G 

Rapidogen  orange  R 

Rapidogen  red  violet  RR 

Rapidogen  violet  B -  .  .  . 

Rapidogen  yellow  G 

Rapidogen  yellow  2G 

Solamine  blue  FFG 

Variamine  blue  BD  salt 

Variamine  blue  RT  salt 


UNGROUPED  DYES 
Acetate  rayon  dyes:  ' 
*Black  III,  IV,  IV  ex.,  AS,  AZO,  AZZ.  B,  BG,  BN, 
END,  BNF,  BNS,  BZA,  BZS,  2G,  3G,  3GNF,  GS, 
J,  NAZ,  NBZ,  NS,  NSJ,  NZD,  ONS,  ONSW,  RB, 
SD,  SN. 
♦Blue  III,  IV,  2B,  2BA,  BBN,  BNN,  FFR,  2G,  3G, 
GBC,  GGN,  GR,  R,  3R.  RTG. 

Blue  black 

Bordeaux,  FJA 

•Brilliant  blue,  B,  R 

Brilliant  Bordeaux  3B 

Brilliant  orange  G 

Brilliant  red 

Brilliant  vellow  FF 

Brown  BR,  R,  Y 

•Developed  black  AD,  AS,  B,  3B,  BBN,  BDN,  BGD, 
CB,  FL,  GA,  GFS,  MBD,  NS,  SOL. 

Developed  na\^  SD 

Developed  yellow  GN 

Developer  I 

Direct  black,  GN 

Direct  blue  S : 

Direct  orange  R 

Direct  red  BP,  YC 

Direct  scarlet  GP 

Direct  yellow  GN 

Discharge  blue  R 

Fast  black  B,  BTN 

Fast  blue  3BFV 

Fast  blue  green  BG 

Fast  Bordeaux  B 

Fast  red 

Fast  violet  RL 

Fast  yellow  GL,  GR,  4RL 

Fluorescent  yellow  HEB 

Golden  yellow  VIII,  IX,  XI,  XII,  XIII,  F,  FSI.  .  .  . 

Gray  NBN 


13.  72,  176,  313,  X. 

13,  176,  X. 

95. 

95. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

176. 

129,  176. 

129,  176. 

176. 

176. 

176. 

176. 

129,  176. 

176. 

176. 

176. 

176. 

176. 

129,  176,  357. 

176. 

176. 

176. 

129,  176. 

176. 

176. 

176. 

176. 


13,  129,  176,  313,  510,  X. 


13,  89,  95,  129,  176,  313,  X. 

313. 

72. 

13,  72,  129,  360,  511. 

72. 

89. 

129. 

176. 

89,  129. 

72,89,  129,  163,  176,360. 

13. 

95. 

13. 

95. 

72. 

89. 

72,  95. 

95. 

95. 

13. 

176. 

176. 

176. 

89. 

511. 

511. 

129,  176. 

72. 

13,  72. 

13. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


91 


Table  lOB. — S_i/nthetic  organic  chemicals:  Coal-tar  dyes  for  which  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  19^1—^3 — Continued 


Colour 

Index 

or 

Prototype 

No. 


UNGROUPED  DYES— Continued 
Acetate  rayon  dyes  ' — Continued 

Green  blue  I,  II,  II  ex 

Heliotrope  I 

liight  orange  FSI 

Monocel  orange  II 

Monooel  rubine  G 

Monocel  scarlet  B,  G 

Navy  blue  B,  BP,  BX,  BXN,  R 

•Orange,  I,  II,  III,  BL,  GF.  GFN,  GR,  GRN,  JER, 
R,  2R,  2RN,  3R,  4R,  TF. 

Pink  II,  B,  BR 

Printing  blue 

Pure  blue  B,  BR,  BR  ex 

Pure  yellow  I,  II,  III 

Purple 

♦Red  I,  III,  V,  VI-X,  VII,  VIII,  B,  2B,  .3B,  6B.  BF, 
BM.  BR,  FSI,  GG,  NB,  R,  RN,  RP,  Y,  2Y. 

Red  violet  R 

♦Rubine  IX,  B,  C,  G,  R 

Saphirole  blue  FFG , 

•Scarlet,  III,  B,  BG,  BN,  BR,  BS,  CSB,  GY 

Skv  blue  B 

Turquoise  G,  MG 

♦Violet  II,  B,  4B,  BA,  CB,  2R,  3R,  4R 

Violet  blue  FSI 

♦Yellow  *8,  #38,  C,  G,  5G,  6G,  3GA.  3GM,  6GN, 
6GN  ex.,  GR,  GS,  GX,  JT,  N,  R,  3R,  RN  cone. 

Acid  anthracene  yellow  GR  ex 

♦Acid  black  AR,  3G,  GRF,  GRF  cone,  R,  RB,  RCW, 
RYC. 

Acid  black  jet 

Acid  blue,  D,  R,  RS 

Acid  blue  black  RC 

Acid  brilliant  blue  RR 

Acid  brilliant  red  4BL,  G 

♦Acid  brown,  B,  G,  FN,  MF,  N,  R,  R  cone,  RB,  RGO, 

ROO. 

Acid  chromal  brown  AEB 

Acid  chrome  blue  .3G,  .3GN,  2RL 

Acid  chrome  brown  DKL,  RLL 

Acid  chrome  olive  BL 

Acid  chrome  yellow  ME 

Acid  dark  green  B 

♦Acid  fast  blue  BN,  G,  2GA,  IB 

Acid  fast  brown  CGS 

Acid  fast  orange  LW 

Acid  fast  red  CA,  CY 

Acid  fast  yellow  JY,  N 

Acid  fuchsine 

Acid  garnet  BG 

Acid  golden  yellow  R 

Acid  green  A,  BL,  GR,  S 

Acid  lake  red 

Acid  leather  brown  EBR 

.4cid  light  red  4BL 

Acid  light  rubine  BL 

Acid  milling  orange  R,  4R 

Acid  milling  yellow  GN,  2GX 

Acid  naphthol  blue  black 

Acid  navy  FN 

Acid  navy  blue,  B  cone 

Acid  neutral  red  3G  ex 

Acid  olive  G 

Acid  orange  2R,  4R,  4RN,  YF 

Acid  pink  BA,  N 

♦Acid  red.  A,  B,  3B,  3B  ex.,  3BX,  GL,  OA 

Acid  sapphire  G 

Acid  scarlet  G,  Y 

Acid  spirit  black 

Acid  spirit  orange  R 

Acid  spirit  yellow  G,  2R 

♦Acid  violet  A,  B,  2R,  RNL 

♦Acid  yellow,  BE,  G,  2G,  3G,  GOO,  GR,  R 

Alizarin,  oil  soluble 

Alizarin  blue  GS 

Alizarin  fast  blue  RB 

Alizarin  fast  gray 

Alizarin  gray  DG 

Alizarin  orange  RA 

Does  not  include  acetate  rayon  dyes  grouped  under  Colour  Index 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


13. 

13. 

13. 

510. 

510. 

510. 

13.  72,  129,  X. 

13,  72,  129,  176,  313,  360,  510,  X. 

13,  313,  X. 

13. 

13,  129. 

13. 

129. 

13,  72,  129,  163,  176,  313,  360,  X. 

129. 

13,  129,  163,  510,  X. 

89. 

13,  72,  129,  163,  313,  510,  X. 

129. 

13,  176. 

13,  129,  176,  313,  X. 

13. 

13,  72,  89,  129,  163,  313,  360,  X. 

89. 

55,  129,  313,  510. 

176. 

357,  370. 

129. 

129. 

129,  313. 

55,  72,  357,  370. 

95. 

95,  176. 
95. 
95. 
95. 
95. 

72,'  89,  129,  313. 
129. 
13. 

72,  129. 
72. 
89 
37Cf. 
357. 

129]  357,  370. 
72. 
176. 
129. 
176. 
72,  129. 
129,  357. 
95. 
510. 
72,  510. 
13. 
72. 

72,  357. 
72,  95. 

55,  95,  129,  357. 
X. 
357. 
72. 
72. 
72. 

129,  357,  370,  510. 
55,  72,  95,  357. 
X. 
313. 
313. 
176. 
313. 
13. 
ind  Foreign  Prototype  numl  era. 


92 


UNITED  STATES  TARIFF  COMMISSION 


Table  lOB. — Synthetic  organic  chemicals:  Coal-tar  dyes  for  which  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  19Jtl-.k3 — Continued 


Colour 
Index 


Prototype 
No. 


Dye 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


UNGROUPED  DYES— Continued 

Alizarin  supra  blue  C 

Amido  brilliant  red  BB 

Anthracene  blue  SWN 

Anthracene  chrome  brown  RL 

Anthracene  indigo  blue 

Anthraquinone  blue  EGA,  3G,  5R,  SWB,  WSA 

Anthraquinone  vat  black  2G,  J,  R 

Anthraquinone  vat  black  brown  V 

♦Anthraquinone  vat  blue  CLX-RCX,  GR 

Anthraquinone  vat  blue  green  B,  FFB,  Y 

Anthraquinone  vat  Bordeaux  GRR 

Anthraquinone  vat  brilliant  green  4B 

Anthraquinone  vat  brilliant  red  B 

Anthraquinone  vat  brilliant  violet  3B 

Anthraquinone  vat  brilliant  yellow  4G 

Anthraquinone  vat  brown  XR,  RRD,  VR 

Anthraquinone  vat  dark  blue  BOR 

Anthraquinone  vat  dark  brown  R 

Anthraquinone  vat  dark  olive  B 

Anthraquinone  vat  direct  black,  3G 

Anthraquinone  vat  flavine  GC 

Anthraquinone  vat  golden  orange  YL 

Anthraquinone  vat  golden  yellow  GO 

'Anthraquinone  vat  gray  GD,  R,  RL,  M 

Anthraquinone  vat  green  2BL,  Y 

Anthraquinone  vat  khaki  OG,  V 

♦Anthraquinone  vat  navy  blue,  BN,  BR,  G,  3G,  NRD. 

Anthraquinone  vat  olive,  G,  GGL,  T 

Anthraquinone  vat  olive  green  3B 

Anthraquinone  vat  orange  A 

Anthraquinone  vat  printing  black  B,  R,  TL 

Anthraquinone  vat  printing  green  B,  BG 

Anthraquinone  vat  red  brown,  DBL,  R 

Anthraquinone  vat  red  violet  RRN,  6RN 

Anthraquinone  vat  scarlet  BBN 

Anthraquinone  vat  violet  FFBX 

Anthraquinone  vat  yellow  8G,  3RD 

Azoanthrene  dyes; 

Black  N,  NV 

Blue  G,  RL,  RS 

Brown  DW,  R 

Claret  S 

Golden  orange  R  ex 

Green  G 

Navy  BR,  CW,  LN 

Red  3BW 

Rubine  B  ex.,  S 

Scarlet  O,  Y  ex 

Turquoise  B 

Violet  O,  OC 

Yellow  G,  GSB,  S  ex 

Azo  Bordeaux  BL,  4BL 

Azo  brilliant  green,  B 

Azo  brown  BY,  DB,  RN 

Azo  ceresine 

Azo  cosine  2B 

Azo  fast  blue  B  cone,  2R 

Azo  fast  brilliant  red  B 

Azo  fast  orange  GRN '. 

Azo  fast  red  B 

xA.zo  fast  violet 

Azo  fast  yellow  G 

Azo  green  OL 

Azo  oil  black 

Azo  oil  blue  black  B. .,, 

Azo  olive  green  BL 

Azo  orange  GCW,  GN,  GR,  RG,  2RG,  RNC,  3RP,  RS 

.4zo  red  DP,  R,  RP 

Azo  scarlet,  2BLL,  G,  RB,  RBN 

Azo  seal  brown 

Azo  violet  B,  R 

Azo  yellow  GG,  N 

*Azoic  dyes  and  their  components:  - 
Dyes : 

Rapid  fast: 

Blue  B 

Brown  IRII 

Orange,  G 

RedGL 

Scarlet  RII 


176. 

176. 

313. 

511. 

176. 

33,  129. 

72,  313. 

176. 

129,  176,  313. 

129,  176,  313. 

176. 

176. 

129. 

129. 

129 

13,  129,  313. 

13. 

129. 

13. 

129,  313. 

313. 

129. 

176. 

72,  129,  313. 

129. 

X. 

13,  72,  129,  176. 

13,  129,  176. 

176. 

129. 

13,  176. 

176. 

13,  313. 

13. 

176. 

176. 

129,  176. 

X. 

X. 

X. 

X. 

X. 

X. 

X. 

X. 

X. 

X. 

X. 

X. 

X. 

3.57. 

176. 

357. 

72. 

129. 

313. 

176. 

176. 

176. 

313. 

176. 

357. 

313. 

313. 

357. 

357. 

176. 

3.57. 

357. 

357. 

176. 


176. 
176. 

72,  357. 
176. 
176. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


93 


Table  lOB. — Synthetic  organic  chemicals:  Coal-tar  dyes  for  which  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  1941~If3 — Continued 


Colour 

Index 

or 

Prototype 

No. 

Dye 

Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 

UNGROUPED  DYES— Continued 
*A2oic  dyes  and  their  components  ^ — Continue 
Dyes — Continued 
Rapidogen: 

Black  DM 

d 

129. 

Blue,  MGC,  MSG 

Bordeaux,  MR 

129,  357. 
129,  357 

Brown,  FFIB,  GRNN 
Corinth  DR 

IRF.  .  . 

176,  357 

129. 

Dark  brown  AR,  R 

129,  176. 

G,  double           

176. 

Golden  yellow  MRS,  N,  RNW. 
Navy  blue  FFR 

129,  176,  357 

176. 

Orange  FFR 

176. 

Pink  FITRW 

176. 

*Red,  BB,  FFBB,  FFG 
•Scarlet  FFG,  FFR,  R, 
Yellow,  FFGG,  GP   .  . 

FFR,  G 
RBY .  .  . 

IP,  M2B 

72,  129,  176,  357. 
72,  129,  176,  357. 

176,  357 

Components: 

Fast  color  bases: 

172. 

Garnet  GC    

13,  176. 

13. 

Red  GGN,  PDC 

176. 

Scarlet  R 

13,  176,  X. 

Fast  color  salts: 

Black  G 

176. 

*Blue  B,  K 

13,  172,  176,  357 

"• 

'Orange 

13,  176,  282,  313,  357. 
13. 

•Red  B,  FG,  FR,  G,  3G 
Rubine  FG 

,  2GS,  KBN,  RC. . 

13,  176,  282,  313,  357,  X. 
172. 

•Scarlet  R 

13,  176,  282,  313  357   X 

Yellow  G,  3GL 

13. 

Naphthols: 

AS-BG 

13,  176. 

AS-GR 

176. 

AS-KR 

176. 

AS-L4G 

13. 

AS-MX 

176. 

AS-OP 

357. 

AS-PH    

176,  313. 

AS-PN 

72. 

AS-SR 

176. 

Benzoform  dyes: 

Black  RR 

176. 

'Blue  BNL,  GG,  GS 

176. 

Blue  green  B 

176. 

Bordeaux  7B,  7BAN0 

176. 

Brown  LG,  L3R 

176. 

Gray  N 

176. 

Orange  FGL 

176. 

Red  7B,  G 

176.                                 • 

Rubine  B 

176. 

Violet  BB,  R 

176. 

Yellow  3G,  GR 

176. 

Black  BDN,  NAP 

72,  176. 

Brilhant  acid  blue  3B,  6BN 

313. 

Brilliant  benzo  green  B 

176. 

Brilliant  benzo  violet  B,  4B     

129,  176. 

Brilliant  blue  5B 

313. 

Brilliant  milling  blue  FFR 

176. 

Brilliant  wool  blue  G  ex  ,  N           

313. 

Carbolan  blue  B 

129. 

Chroniate  brilliant  brown  RL 

89. 

511. 

•Chrome  black  EA  ex.,  3G,  P2B,  SW, 

Chrome  blue  ATX 

Chrome  brilliant  orange  2R     

T  cone. 

WSE... 

89,  129,  313. 

129. 

13. 

•Chrome  brown  2AB,  B,  B  ex.,  EBL,  HN  cone. 
RB,  4RC,  VR. 

O,  PG, 

72,  89,  95,  129,  176,  313,  357. 
511. 

Chrome  fast  red  2RL 

129. 

129. 

129. 

Chrome  green  B,  CB,  G 

95,  313. 

Chrome  leather  fast  black  SG 

176. 

2  Does  not  include  azoic  dyes  and  their  components  grouped  under  Colour  Index  and  Foreign  Proto- 
type numbers. 


94 


UNITED  STATES  TARIFF  COMMISSION 


Table  lOB. — Synthetic  organic  chemicals:  Coal-tar  dyes  for  which  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  191fl-Jt3 — -Continued 


Manufacturers'  identification 
numbers  (according  to  liet  on  p.  135) 


UXGROUPED  DYES— Continued 

Chrome  orange  3R,  RL 

Chrome  red  G 

Chrome  violet  B 

'Chrome  yellow  A,  AS,  B,  FTL,  2G,  2GN,  ME,  SW. . .  . 

Chromolan  blue  3R 

Ciba  blue  BR 

Ciba  red  R 

Ciba  scarlet 

Ciba  violet 

Cloth  red  Y 

Cotton  black  3G 

Cotton  red  D 

Croceine  scarlet  FP  cone 

•Developed  black  G,  NS,  OT,  ZV  cone 

Developed  blue  B,  6G,  5GL,  GR,  4RL 

•Developed  Bordeaux  2BL,  7BL,  RB 

Developed  brilliant  blue  BBL 

Developed  brilliant  orange  GR,  GR  ex.,  GRS,  ex.,  RAS 

Developed  brilliant  scarlet  .5BL,  GL 

Developed  brown  CBS,  6G,  R 

Developed  dark  brown  B 

Developed  fast  black  PG  ex 

Developed  fast  blue  B 

Developed  fast  Bordeaux  BGL,  BTL 

Developed  fast  brown  RK 

Developed  fa.st  green  GFL , 

Developed  fast  orange  6R 

Developed  fast  turquoise  8GL 

Developed  fast  violet  BL 

Developed  fast  yellow  2G 

Developed  garnet  RD 

Developed  green  BL,  2GL,  GW 

Developed  indigo  blue  BRR,  3GL 

Developed  orange,  DD,  GR,  R,  2R,  3R,  RFW,  WD.  . 

•Developed  red  2B,  7BL,  lOBL,  BFW 

•Developed  scarlet  A,  AE,  FW,  GFW,  2BLN  ex.,  N.  R. 

Developed  violet  BRD,  RR 

Developed  yellow  4G 

Diazophen  red  BTB 

Diazophen  yellow  BTB 

•Direct  black  CW,  3G,  5G,  NCW 

•Direct  blue  A,  2B,  5B,  BR,  FF,  2G,  .3G,  oG,  GL,  GR, 
NR,  NRS,  RL,  RDW,  VRS. 

Direct  blue  green  GW 

Direct  Bordeaux  6BP 

Direct  brilliant  blue  BFL 

Direct  brilliant  cerise 

Direct  brilliant  green  VB 

Direct  brilliant  orange  RS 

Direct  brilliant  red  12B  cone 

•Direct  brilliant  violet  B,  4B,  R 

JDirect  brilliant  yellow  8G 

•direct  brown  BRLL,  CSW,  CWR,  FW,  GB,  G2R,  3GS, 
K,  KRS,  N.  R,  RB,  RRF,  RY,  S,  VG. 

Direct  catechine 

Direct  chrome  black  blue  BNL 

Direct  chrome  blue  black  B 

Direct  chrome  navy  blue  B 

Direct  copper  blue  GL,  RRX 

•Direct  fast  black  AM,  FAM,  FOR,  FTC,  G,  PG  ex.... 
•Direct  fast  blue,  FFE,  6GKS,  GL,  8GL,  R,  RL,  3RL, 
SFGL,  SRL. 

Direct  fast  Bordeaux  2B,  5B,  BLL,  6BLN 

•Direct  fast  brown  BRL,   BRLN,   4GL,   LBR,   R,   4R, 
2RL,  3YL. 

Direct  fast  catechine  G\ 

•Direct  fast  gray  BL,  GL,  2GL,  LVGL,  LVL,  RLN.  .  . 

Direct  fast  olive  brown  RL 

Direct  fast  olive  drab  LH 

•Direct  fast  orange  EG,  E3G,  ER,  ERS,  G,  2G  cone, 

4G  cone,  5GC,  GL,  2GL,  R.  6R,  SRL,  2RN,  RT,  S 
♦Direct  fast  red  3BL,  8BLN,  8BLSW.  FA.  R 

Direct  fast  rubine  B  cone,  2B,  LB 

Direct  fast  scarlet  4BA,  8BD,  G 

Direct  fast  turquoise  8GL 

Direct  fast  violet  5BL,  2RL 

•Direct  fa.st  yellow,  G,  4GL,  5GL,  4GLP,  LR,  RL 

Direct  golden  vellow  R,  R  spec 

Direct  grav  BBC.  LVL,  Z 

•Direct  green  B,  G,  3G,  GB,  5GSC,  2Y 


129,  313. 

313. 

89. 

72,  89,  95,  129,  313,  X. 

313. 

127. 

127. 

127. 

127. 

95. 

72,  510. 

95. 

313. 

55,  72,  95,  129,  176. 

13,  95,  129,  360. 

13,  129,  313. 

313. 

89.  176. 

89,  129. 

129,  176,  313. 

89. 

129. 

95. 

176. 

129. 

89. 

129. 

129. 

129. 

89,  313. 

13. 

129. 

176. 

13,  129,  313. 

13,  95,  129,  313. 

13,  129,  313. 

13,  129. 

129. 

72. 

72. 

95,  176,  313,  510,  X. 

13,  72,  89,  129,  313,  360,  X. 

313. 

176. 

313. 

72. 

313. 

95. 

313. 

13,  72,  313. 

313. 

13,  M,  72,  89,  95,'_107,  176,  313, 

510,  X. 
129,  313. 
176. 
313. 
13. 

129   313. 

13,  89,  129,  176,  313,  510. 
95,  129,  313,  X. 

176,  313. 

89,  129,  176,  313. 

89. 

129,313,  X. 

13. 

13. 

72,  89,  95,  129,  313,  X. 

13,  89,  313,  X. 

13,  313. 

13,  89,  176,  313. 

129. 

13,  313. 

89,  95,  129,  176,  313. 

357. 

X. 

13,  72,  129,  176,  313. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


95 


Table  lOB. — Synthetic  organic  chemicals:  Coal-tar  dyes  for  which  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  19^1-^3 — Continued 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


UNGROUPED  DYES— Continued 

Direct  green  black 

Direct  indigo  blue 

Direct  light  yellow  RL 

Direct  navy  G,  R,  4R 

♦Direct  navy  blue  B,  BFN,  BW,  DB,  R,  RY. 

Direct  neutral  blue  G 

Direct  new  blue  5B 

♦Direct  orange  B,  R;  RT 

Direct  red  3BL,  MC,  MU 

Direct  reseda  green 

Direct  rhoduline  red  B 

Direct  royal  blue 

Direct  rubine  G 

Direct  sapphire  B 

Direct  scarlet  G 

Direct  silk  blue  NR 

Direct  sky  blue  B 

Direct  speck  dye  red  SW 

♦Direct  violet  B,  2B,  BOW,  BRL,  2R 

Direct  violet  black 

Direct  viscose  blue  GG,  GS,  RS 

Direct  yellow  B,  FR,  S3G,  S5GP  cone 

Ergan  yellow  RNC 

Fast  acid  blue  WF 

Fast  acid  brown  RG 

Fast  acid  light  red  B 

Fast  acid  orange  RW 

Fast  acid  red  BBL 

Fast  acid  violet  ERR  ex 

Fast  acid  yellow  GS 

Fast  black  G 

Fast  blue  BN,  5RN 

Fast  brown  FN,  MF 

Fast  catechine  G A 

Fast  chrome  brown  RB 

Fast  crimson  R 

Fast  light  red  4B,  BL 

Fast  light  violet  B 

Fast  olive  brown  G 

Fast  orange  4RN,  YF 

Fast  pigment  violet  RP 

Fast  pink  N 

Fast  printing  yellow  G 

Fast  spirit  black  R 

Fast  spirit  brown  G 

Fast  spirit  orange  R 

Fast  spirit  yellow  2R 

Fast  yellow  2G,  N 

Fat  orange  4A 

Fluorol  5G,  5GR 

Fluoroleum  supra 

Fluorescent  purple  2G 

Formaldehyde  black  B,  GR,  ex 

Formaldehyde  fast  black  GR  ex 

Formaldehyde  red  B 

Formaldehyde  scarlet  Y 

Formalide  brown  RD 

Formalide  deep  blue  R 

Formanol  black  RW 

Formyl  black  G 

Formyl  blue  B 

Formyl  brown 

Fur  colors  (other  than  Colour  Index  No.  875) 

Gasoline  blue 

Gasoline  yellow,  2G 

Hansa  yellow  G 

Heliogen  blue  G 

Heliogen  green  B 

Hydroform  navy  blue 

Igenal  brown  CRT,  IIG,  PGM 

Indigo  vat  black 

Indigo  vat  brown,  G,  2R 

Indigo  vat  scarlet  2GN . 

Indophenol  black 

Indophenol  blue 

Induline  base,  black . 

Ink  fast  black  G 

Jet  black  APX 

Lake  brown  BC 

Lake  fast  blue  BL  cone 


95. 

13. 

95. 

13,  72. 

72,  95,  129,  313,  510. 

357. 

95. 

13]  95,  176,  X. 

176,  X. 

13. 

129. 

13. 

13. 

X. 

13. 

176. 

95. 

313. 

13,  72,  176,  313,  360. 

95. 

176. 

176,  313. 

176. 

313. 

313. 

95. 

95. 

176. 

129. 

313. 

72. 

72,  176. 

72. 

89. 

357. 

313. 

176,  313. 

313. 

72. 

72. 

313. 

72. 

313. 

72. 

72. 

72. 

72. 

72. 

95. 

176. 

129. 

133. 

55,  95. 

55,  95. 

95. 

95. 

510. 

510. 

X. 

72. 

72. 

72. 

89. 

72. 

72. 

129,  176. 

176. 

176. 

349. 

176. 

127. 

72,  313. 

313. 

X. 

X. 

X. 

176. 

129. 

129. 

129. 


96 


UNITED  STATES  TARIFF  COMMISSION 


Table  lOB. — Synthetic  organic  chemicals:  Coal-tar  dyes  for  which  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  1941-43 — Continued 


Dye 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


UNGROUPED  DYES— Continued 

Lake  fast  orange  G,  R 

Lake  fast  yellow  G 

Lake  orange  OTP 

Lake  pink  RL 

Lake  red  2B,  BP,  CPS,  DP,  RP 

Lake  scarlet  2YL 

Lake  yellow  G,  GNP,  PL 

Leather  brown  2R,  5RT 

Levelling  brown  B 

Lithol  yellow  G,  2G,  GTR 

Metalized  azo  gray  G 

Methyl  red 

Methyl  violet  crystals 

Mining  black  B 

Milling  fast  garnet  R 

Milling  fast  red  FF,  GD 

Milling  fast  yellow  DOM,  5GL 

Milling  navy  blue  4B 

Milling  orange  G 

Milling  red  B,  2G 

Milling  yellow  2G  ex.,  3G,  2GCW,  2GX  cone,  NGS. 

RG,  XN. 

Monaetral  fast  blue  B,  G,  2RP 

Monastral  fast  green  G 

Mordant  green  SN 

Mordant  yellow 

Naphthalene  green  B 

Naphthanil  scarlet  for  printing 

Naphthol  navy  blue  M 

Neutral  blue  G 

•Neutral  brown  R,  RD,  2RS,  RX 

Neutral  silk  brown  RHS,  RWA 

Neutral  silk  yellow  CGA 

Neutral  yellow  SX 

New  f  uchsine 

Nirodole  JPG 

Oil  bronze 

Oil  brown  *69,  *79,  #102,  D,  M,  R,  Y 

Oil  fast  blue  R 

Oil  fast  yellow  EG 

Oil  orange,  «  30,  *  67,  MT 

Oil  pink  B 

■Oil  red,  *322,  EG,  EGN,  N-1700,  O,  OB,  RO.  XO, 

Y-292. 

Oil  scarlet 

Oil  soluble  azoic  yellow 

Oil  yellow,  PHW 

Orange  TR 

Palatine  fast  blue  5RN 

Paper  white  GDC,  GDX 

Patent  blue  B  cone,  RRG 

Permanent  red  FBL,  GG 

Phenoform  orange  G 

Phosphine  HB,  R,  PB 

Pigment  blue  GNL,  WNL 

Pigment  khaki  CW 

Pigment  rubine  3G 

Poly  form  dyes: 

Blue  BRF,  2RF 

Bordeaux  RF 

Dark  brown  3BF 

Dark  maroon  GF 

Orange  RF 

Scarlet  2GF,  RF 

Yellow  GF 

Printsol  orange  GNR 

Pyrazol  fast  orange  GL 

Pyrazoline  dyes: 

Black, 

Blue  R 

Gray  GL    

RedBLW 

Yellow  4GLP 

Rayon  dyes: 

Bordeaux  B 

Brown  B,  2BL,  G,  M 

Navy  blue  N 

Orange  RB 

Red  BX 

Violet  3B 


129. 

129. 

129. 

313. 

129,  176. 

129. 

129,  176,  313. 

129,  176. 

13. 

176. 

72. 

X. 

313. 

313. 

89. 

89. 

89. 

313. 

357. 

313,  357. 

313,  357. 

129. 

129. 

72. 

176. 

176. 

129. 

95. 

357. 

95,  129,  313,  X. 

89. 

89. 

X. 

72. 

176. 

129 

107i  163,'313. 

13. 

129. 

72,  163. 

313. 

13,  72,  163,  313. 

72. 
X. 

72,  176,  511. 

149. 

176. 

176. 

176,  313. 

176. 

176. 

72,  176. 

176. 

176. 

176. 

l29. 
129. 
129. 
129. 
129. 
129. 
129. 
313. 
95. 

357. 
357. 
357. 
357. 
357. 

129,  X. 
129,  X. 
129,  X. 
129,  X. 
129,  X. 
129,  X. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


97 


Table  lOB. — Synthetic  organic  chemicals:  Coal-tar  dyes  for  which  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  19^1-^3 — Continued 


Colour 

Index 

or 

Prototype 

No. 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


UNGROUPED  DYES— Continued 

Resin  brilliant  orange  2R 

Resin  brilliant  red  R 

Resin  brown  Z 

Resin  violet  B 

Resorcine  brown  3R 

Rosanthrene  A,  R 

Rosanthrene  Bordeaux  2BL 

Rosanthrene  orange 

Rubber  colors 

Silk  brown  G,  R 

Silk  fast  blue  3G 

Silk  red  2B,  4B,  lOB 

Solventol  yellow 

_Spirit  brown  G 

"Spirit  soluble  blue 

Spirit  soluble  fast  black 

Spirit  soluble  fast  blue  B 

Spirit  soluble  fast  orange  A  cone 

Spirit  soluble  fast  red  M,  Y 

Spirit  soluble  fast  yellow  3G 

Spirit  soluble  green 

Spirit  soluble  violet 

Spirit  yellow 

Stilbene  brown  3GXL 

StUbene  orange  EG,  E3G 

Sudan  corinth  B 

Sudan  orange  FL 

Sudan  red  IT 

Sulfonal  orange  R 

Toluvlene  fast  brown  3G 

Vat  khaki  OG 

Vat  printing  black  G 

Victoria  blue  BGO 

Visco  blue  RS ' 

Vulcan  fast  orange  G,  GR,  GRN 

Vulcan  fast  red  B,  BA 

Vulcan  fast  yellow  G,  GR 

Vulcan  vellow  GN 

Wool  blue  CGG 

Wool  navy  B 

Wool  red,  special 

Yellow,  medium 

'Zambesi  black 

Miscellaneous  mixtures,  etc 


313 

313 

313 

313 

107, 

129 

95. 

129 

129 

X. 

129 

95, 

313 

72. 

511, 

313 

313 

313 

313 

313 

511 

511 

176 

72. 

72. 

176 

176 

176 

176, 

176, 

349 

313 

204, 

95. 

176. 

176, 

176. 

176 

313. 

313 

357. 

X. 

95, 

129 


176,  313. 
,  X. 


LAKES  AND  TONERS 


Table  llB. — Synthetic  organic  chemicals:   Lakes  and  toners  for   which    United    States 
production  or  sales  were  reported,  identified  by  manufacturer,  19Jfl—JfS 

[Lakes  and  toners  for  which  separate  statistics  are  given  in  table  ll.\  are  marked  below  with  an  asterisk 
(*) ;  those  not  so  marked  do  not  appear  in  table  1  l.A.  because  the  reported  data  are  confidential  and  may 
not  be  published.  Manufacturers  are  identified  by  numbers  in  thealjjhabetical  list  appearing  on  p.  i:<."i. 
An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number 
with  the  designated  product.] 


Product 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  13.^) 


FULL-STRENGTH  LAKE  COLORS 
'Alizarin  lakes 

•Black  lakes 

*Bhie  lakes: 

Heliogen  blue 

Indanthrene  blue 

'Peacock  blue 

.MI  other 


646064— 4G— 7 


22,  129,  134,  239,  244,  293,  X,  X, 

X,  X. 
93,   103,   129,   193,  244,  285,  466, 

469,  511,  X,  X. 

229,  X,  X. 

129,  236. 

6,  22,  62,  74,  93,  103,  129,  134,  153, 
168,  196,  204,  206,  227,  229,  244, 
256,  285,  383,  .395,  422,  451,  466, 
469,  493,  511,  X,  X,  X,  X,  X,  X. 

22,  62,  93,  103,  129,  1.34,  153,  158, 
193,  196,  236,  2.39,  244,  285,  .383, 
422,  451.  466,  469,  493,  497,  511, 
X,  X,  X.  X,  X,  X,  X,  X. 


98 


UNITED  STATES  TARIFF  COMMISSION 


Table  IIB. — Synthetic  organic  chemicals:   Lakes  and   toners  for  which    United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  19^1— ]f3 — Continued 


Product 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


FULL-STREx\GTH  LAIiE  COLORS— Continued 
•Brown  lakes 


*Green  lakes: 

Naphthol  green . 
All  other 


•Maroon  lakes: 

*Azo  Bordeaux. 


*Helio  fast  rubine. 
•All  other 


•Orange  lakes: 

•Persian  orange 


•AH  other. 


Phosphomolybdic  acid  lakes.   See  Reduced  Toners 
Phosphotungstic  acid  lakes.  See  Reduced  Toners. 

•Red  lakes: 

•Eosine  and  phloxine 

Lithol  rubine.   See  Reduced  Toners. 

Permanent  red  2B 

•Pigment  scarlet 

Red  lakes  C  and  D.   See  Reduced  Toners. 

Rose  and  pink  lakes 

•Scarlet  2R 

All  other 


•Violet  lakes: 

•Methyl  violet 

•All  other 

•YellowTakes: 

•Fast  light  yellow 

•Naphthol  yellow 

•Quinoline  yellow 

•Tartrazine 

•All  other 

TONERS  OR  FULL-STRENGTH  COLORS 
Black  toners: 

Phosphomolybdic  acid  black 

Phosphotungstic  acid  black 

All  other 

•Blue  toners: 

•Alkali  blue 

Permanent  blue 

•Phosphomolybdic  acid  blue 

•Phosphotungstic  acid  blue 

•Phthalocyanine  blue  B 

Phthalocyanine  blue  G 

All  other 


22,  93,  103,  129, 168.  244,  285,  466, 
511,  X. 

493,  X. 

22,  62,  93,  103,  129,  153,  158,  193, 
206,  236,  239,  244,  285,  383,  451, 
466,  469,  497,  X,  X,  X,  X,  X,  X, 
X. 

22,  62,  129,  134,  206,  364,  383,  466. 

469,  493,  X,  X. 
22,  62, 103,  129,  134,  206,  236,  244, 

285,  383,  466,  493,  X,  X,  X. 
22,  74,  93,  103,  129,  134,  193,  229, 

236,  244,  285,  293,  297,  493,  497, 

X,  X,  X. 

22,  74,  129,  153,  158,  204,  227,  229, 
244,  256,  285,  383,  395,  422,  451, 
466,  469,  493,  X,  X,  X,  X,  X,  X. 

62,  74,  93,  103,  129,  153,  158,  193, 
239,  244,  285,  422,  466,  469,  497, 
X,  X,  X,  X,  X,  X. 


22,  62,  74,  93,  129, 134,  153,  158, 
193,  227,  285,  383,  422,  451,  469, 
X,  X,  X,  X,  X. 

129 

22,  62,  103, 129, 158,  206,  244,  285, 

383, 422,  466,  469,  493,  497,  511, 

X,  X,  X,  X,  X. 

103,  2.36,  244,  493,  X,  X. 

22,  62,  74,  93,  129,  134,  158,  193, 
236,  244,  364,  383,  422,  451,  466, 
469,  493,  497,  X,  X,  X,  X,  X. 

22,  62,  74,  93,  103,  129,  1.34,  153, 
168,  193,  236,  239,  244,  285,  383, 
422,  451,  466,  469,  493,  497,  511, 
X,  X.  X,  X,  X.  X,  X,  X,  X. 

22,  62,  93,  103,  129,  134,  158,  193, 
206,  244,  285,  383,  422,  451,  466, 
469,  511,  X,  X,  X,  X,  X. 

93,  103,  129,  193,  206,  239,  244, 
285,  493,  497,  X. 

22,  129,  158,  204,  206,  244,  256, 

285,  451,  469,  X,  X. 
22,   153,  158,  244,  451,  469,  511, 

X,  X. 
129,  204,  227,  229,  244,  256,  422, 

451,  X,  X. 
22,  74,  103,  134,  158,  169,  204,  206, 

227,  229,  244,  256,  285,  422,  451, 

469,  X,  X,  X,  X. 
22,  74,  93,  103,  129,  158,  239,  285, 

451,  469,  511,  X,  X,  X,  X. 


103. 
22,  103. 
422. 


72,  244,  256,  451,  X,  X. 

204. 

22,  62,  74,  103,  129,  134,  153,  158, 

204,  206,  236,  244,  256,  466,  X, 

X,  X. 
6,  22,  62,  103,  129,  153,  158,  196, 

204,  206,  244,  285,  383,  422,  451, 

466,  469,  493,  511,  X,  X,  X,  X, 

X   X 
103, 'l96,  204,  493,  X,  X,  X. 
493 
22,  153,  204,  206. 


I 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


99 


Table  llB. — Synthetic  organic  chemicals:  Lakes  and  toners  for  which   Uyiited  States 
'production  or  sales  were  reported,  identified  by  manufacturer,  1941-^3 — Continued 


Product 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  133) 


TONERS  OR  FULL-STRENGTH  COLORS— Continued 
Brown  toners 

'Green  toners:  . 

*Phosphomolybdic  acid  green 

*Phosphotungstic  acid  green 

Phthalocyanine  green 

AH  other 

•Maroon  toners 

'Orange  toners: 

'Permanent  orange: 

*2,  4rDinitroaniline  orange 

*o-Nitroaniline  orange 

'Permanent  orange,  unspecified 

All  other 

'Purple  toners: 

'Phosphomolybdic  acid  purple 

'Phosphotungstic  acid  purple 

'Red  toners: 

'Chlorinated  nitroaniline  red 

•Eosine  and  phloxine 

Flame  red 

'Lithol  (red  and  maroon) 

'Lithol  rubine 

Lithosol  red  2B 

'Para  red 

Permanent  red 

Phosphomolybdic  acid  red 

'Phosphotungstic  acid  red 

'Red  lake  C 

•Red  lake  D 

Scarlet 

'Toluidine  red 

All  other 

'Violet  toners: 

'Methyl  violet 

'Phosphomolybdic  acid  violet 

'Phosphotungstic  acid  violet 

'Yellow  toners: 

Benzidine  yellow 

'Hansa  yellow , 

All  other 

Other  toners 


22,  103,  107,  469. 


22,  62,  74,  103,  129,  134,  153,  204, 
206,  236,  244,  256,  466,  X. 

6,  22,  62,  93,  103,  129,  134,  153, 
158,  204,  206,  244,  285,  383,  422, 
451,  466,  469,  493,  511,  X,  X, 
XXX 

103, '196,493,  X. 

22,  129,  196,  244,  493,  X. 

22,  129,  196,  204,  236,  244,  364, 
383,  422,  466,  493,  497,  511, 
X,  X. 


22,  511,  X.  X. 

153,  236,  466,  493,  X. 

22,  72, 129, 153, 158,  204,  236,  244, 

511,  X,  X. 
22,  129.  153,  158,  204,  229.  383, 

451,  497.  X.  X.  X,  X. 

22,  62,  103.  129.  132,  134,  158.  204, 

206,  244,  256,  285,  383.  422,  451, 

466,  X,  X,  X. 
22,  62,  103,  129,  204,  206,  244,  285, 

383,  422,  451,  466,  469,  493,  X, 

X,  X,  X. 

22,  134,244,493,511,  X,  X. 

22,  103,  129,  153,  158.  204,  229, 

244,  256.  422,  451,  469,  511.  X, 

X.  X. 
204. 
22.  74. 103.  129.  153. 158,  204,  206, 

244,  256,  383,  395,  422,  466,  469, 

493,497,511,  X,  X,  X. 
22,  62,   103,   129,   153,   158,    204, 

206,  236,  244,  383,  395,  422,  451. 

446,  469.   493,  497,   X,  X,  X, 

X,  X.  X. 
422. 
22,  62,  74,  129,  134,  1.53,  196,  204, 

206,  236,  244,  256,  364,  383,  395, 

422,  466,  469,  493,  497,  X,  X,  X. 

X,  X. 
72,  204,  X. 
22,  103,  451. 
22,  62, 103,  129,  153,  158,  204,  206. 

244,  285,  383,  422,  451,  469,  511, 

X,  X.  X,  X. 
6,  22,  72,  74,  103,  129,  153,  158, 

204,  206,  227,  244,  256,  383,  419, 

422,  451.  466.  469,  511,  X.  X, 

X.  X.  X. 
74,  129,  158,  244,  256,  422,  511,  X. 
22,  103,  204,  236,  422,  466,  X. 
22,  74,  103,  129,  134,  l.J3,  1.38,  196, 

204,  206,  236,  244,  256,  364.  383. 

395,  422,  466,  469,  493,  497,  X, 

X,  X,  X,  X. 
22,  62,  72,  103,  129,  134.  153,  158, 

204,  206,  244,  285,  383,  451,  469, 

493,  497,  511.  X.  X,  X.  X,  X.  X. 

6,  22,  62,  72,  103,  129,  132.  153. 
158.  193,  204,  206,  227,  244,  256, 
.383.451,466,  469,  X,  X. 

6.  22,  74,  129,  132,  206,  244,  285, 
466,  X,  X. 

153,  244,  X. 


74,  196,  422.  451,  511,  X,  X. 

22,  74,  103.  129.  153.  196,  204.  206. 

227,  229,  244,  383,  422,  493,  511. 

X   X   X  X 
22,   i29',  153.  206.  244.  451.  469, 

511,  X,  X. 
62,  129,  153,  206,  256,  X. 


100 


UNITED  STATES  TARIFF  COMMISSION 


Table  llB. — Synthetic  organic  chemicals:  Lakes  and  toners  for   which   United  States 
production  or  sales  loere  reported,  identified  by  manufacturer ,,  19Jtl-Jt3 — Continued 


Product 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


TONERS,  EXTENDED  OR  REDUCED 

'Reduced  blue  toners: 

Alkali  blue 

•Phosphomolybdic  acid  blue 


*Phosphotungstic  acid  blue. 


*Phthalocyanine  blue  B . 


Phthalocyanine  blue  G 

Phthalocyanine  blue,  not  specified. 
All  other 


Phthalocyanine  green. 

Pigment  green 

All  other 


*Reduced  maroon  toners. 


'Reduced  orange  toners 

'Reduced  purple  toners: 

*Phosphomolybdic  acid  purple. 

'Phosphotungstic  acid  purple. . 
All  other 


•Reduced  red  toners: 

*Lithol  (red  and  maroon) . 

*Lithol  rubine 


*Para  red. 


Permanent  red 

Phosphomolybdic  acid  red. 
*Phosphotungstic  acid  red.  . 


Pigment  rubine  C. 

Red  2B 

♦RedlakeC 


*Red  lake  D.  . 
Red  lake  P.. . 
*Toluidine  red. 


All  other. 


Reduced  violet  toners: 

Pho.sphomolybdic  acid  violet . 
Phosphotungstic  acid  violet. . 

'Reduced  yellow  toners: 

'Hansa  yellow 


Phosphotungstic  acid  yellow. 
All  other 


Other  reduced  toners. 


206. 

22,  62,  72,  103,  153,  158,  193,  206, 

239,  383,  451,  469,  X,  X. 
22,  62,  72,  93,  103,  129,  153,  158, 

193,  204,  206,  229,  244,  285,  422, 

451,466,  469,  511,  X,X,X. 
22,   103,   129,   134,   196,  236,  239, 

244,  466,  493,  497,  X,  X,  X. 
493. 

22,  129,  206,  244,  X,  X. 
206. 


Reduced  brown  toners: 

Phosphomolybdic  acid  brown 239. 

•Reduced  green  toners: 

'Phosphomolybdic  acid  green 22,  93,  103,  129,  193,  206,  236,  285 

466,  X,  X,  X 
'Phosphotungstic  acid  green 


22,  62,  72,  93,  103,  129,  193,  204, 
206,  229,  244,  285,  466,  469,  493, 
511,  X,  X,  X,  X,  X. 

134,  X. 

129,  X. 

129,  134,  239,  244. 

22,  129,  193,  196,  244,  493,  X. 
103,  196,  239,  285,  466,  493,  X. 


22,  74,  103,  129,  158,  193,  206,  244, 

255,  285,  466,  X.  " 
22,  62,  74,  93,  103,  129,  193,  204, 

206,  285,  422,  451,  466,  469,  493, 

511,  X,  X. 
206. 


22,  62,  103,  129,  153,  158,  206,  244, 

383,  395,  422,  469,  493,  511,  X. 
22,  62,  103,  129,  153,  158,  206, 

244,  383,  395,  422,  451,  466,  X, 

X,  X,  X,  X. 
22,  62,  74,  129,  134,  153,  206,  236, 

244,  364,  383,  395,  466,  469,  493, 

497,  X,  X. 
193,  X. 

62,  103,  129,  206,  256. 
22,  62,  72,  74,  93,  103,  129,  153, 

158,  193,  204,  206,  229,  239,  244, 

285,  422,  451,  493,  511,  X,  X, 

X,  X,  X. 
129. 
206. 
22,   129,   153,   158,   193,  206,  229, 

244,  285,  395,  422,  451,  466,  469, 

493,  511,  X,  X,  X,  X. 
22,  129,  244,  383,  422,  511,  X,  X. 
2S. 
62,   129,   134,  193,  206,  229,  236, 

244,  383,  451,  466,  469,  493,  497, 

X,  X,  X,  X,  X. 
153,  193,  196,  239,  255,  493,  X,  X. 

X,  X. 

193. 
X. 


56,    103,    129,   134,   206,   239,   X, 

X,  X. 
1.53,  285. 
22,  196.  X. 

62,  74,  103,  129,  236,  255,  285,  466, 
X,  X,  X. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


101 


MEDICINALS 
Table  12B. — Synthetic  orgaiiic  chemicals:  Medicinals  for  which  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  1941— -'4^3 
[iMedicinals  for  which  separate  statistics  are  given  in  table  12A  are  marked  below  with  an  asterisk  (*); 
medicinals  not  so  marked  do  not  appear  in  table  12A  because  the  reported  data  are  confidential  and 
may  not  be  published.    Manufacturers  are  identified  by  numbers  in  the  alphabetical  list  appearing  on 
p.  135.    An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification 
number  with  the  designated  product.] 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


MEDICINALS,  CYCLIC 

Benzenoid 

*Acetanilide 

Acetol  salicylate  (l-Hydroxy-2-propanone  salicylate) 

*.\cetophenetidin  (Phenacctin) 

•Acetyl-p-aminophenyl  salicylate  (Phenetsal) 

Acetylarsan 

.Acet.ylglycol  salicylate 

*N-Acetyl-4-hydroxy-m-arsanilic  acid  (Acetarsone)  (Stovarsol)  .  . 

*Acetylsalicylic  acid  (Aspirin) 

*Acetyltannic  acid  (Tannigen)  (Tannyl  acetate) 

3-Amino-4-acctoxyphenyl  arsonic  acid 

Amino  acids: 

Di-iodotyrosine 

dl-Phenylalanine 

1-Tyrosine 

*p-Aminobenzoic  acid  derivatives: 

N-Amylaminoethyl  p-aminobenzoate  hydrochloride 
(Amylcaine)  ' 

N-Butyl  p-aminobenzoate  (Bute.sin) 

Di(n-butyl  p-aminobenzoate) trinitrophenol  (Butesin  picrate) 
3-Di~n-butvlaminopropyl    p-aminobenzoate    (Butacaine) 

fButyn).  ■ 
3-Di-n-butylaminoprop.vl  p-aminobenzoate  hydrochloride. .  . 

S-Di-n-butylaminopropyl  p-aminobenz(jate  sulfate 

2-Diethylaminoethyl  p-aminobenzoate  (Procaine)  (Novocaine) 
*2-Diethylaniinoethyl    p-aminobenzoate    borate     (Ethocaine 
borate)  (Borocaine). 

*2-Diethylaminoethyl  p-aminobenzoate  hydrochloride 

3-Dimethylamino-l  ,2-dimethy  Ipropyl     p-aminobenzoate 

hydrochloride  (Tutocaine  hydrochloride). 
2-Dimethylaminoethyl    p-butylaminobenzoate     (Tetracaine) 
(Pontocaine). 

*Ethyl  p-aminobenzoate  (Benzocaine)  (Anaesthesine) 

Isobutyl  p-aminobenzoate 

Isobutylaminoethyl  p-aminobenzoate  (Monocaine) 

Propyl  p-aminobenzoate 

3-Amino-4-hydroxyphenylarsine  oxide  hydrochloride  (Mapharsen) 

4-Amino-2-methylTl-naphthol  hydrochloride  (Synkaminj 

*  Arsphenamine 

Arsphenamine  base ■ 

Barbituric  acid  derivatives.   See  Alicyclic  and  Heterocyclic  medic- 
inals. 

•Benzaldehyde 

Benzochrome 

Benzoic  acid 

Benzoyltetramethyldiaminoethylisopropanol  hydrochloride 

*Benzyl  benzoate 

Benzyl  succinate 

Bismethyl  benzylidine .  . .  . ' 

Bismuth  arsphenaniinesulfonate 

Bismuth  betanaphthol 

Bismuth  iodosubgallate 

Bismuth  phenylarsenate  salt 

Bismuth  subbenzoate 

*Bismuth  subgallate 

'Bismuth  subsalicylate 

Bismuth  tetrabromopyrocatechol 

Bismuth  tribromophenate 

Bromocamphor,  mono 

m-Bromoacetophenyl  benzoate  (Neoxyn) 

tert-Butyl  cresol  (Cresophan) 

Calcium  benzylphthalate 

Calcium  cresolsulfonate 

Calcium  iodoxybenzoate 

p-Carbamidobenzenearsonic  acid  (Carbasone) 

Chloromercuri-4-nitro-o-cresol 

Chloiothymol 

Colchicine  salicylate 

m-Cresyl  acetate  (Cresatin) 

Diacetylaminoazotoluene 

2,5-Diaminotoluene  sulfate 

Dichlorophenarsine  hydrochloride 

Y-Diethylaminopropyl  cinnamate  hydrochloride  (Apothcsine)  .... 

•Diethylstilbfstrol 

m-Dihydroxy-di-(sec)hcxylbenzene  (Dihexylin) 

1,3-Dihydroxynaphthalene  (Naphthoresorcinol) 

3,4-Dihydroxyphenylethylmethylamine  (Epinine) 


97,  127,  290,  307. 

92. 

97,  127,  307,  X. 

90,  159,  238,  304,  X,  X. 

92. 

X. 

1,  294,  X. 

3,  127,  144,  1.59,  307,  X,  X,  X. 

92,  159,  238,  249,  297,  X. 

X. 

150. 
294. 
294. 

331. 

1,  X. 

1. 
1. 

1. 

1. 

1,  51,  72,  173,  316,  331,  377,  X,  X. 

1,  412,  X. 

1,  51,  72,  173,  316,  331,  377,  X,  X. 
X. 

500. 

1,  51,  173,  294,  .331,  411,  X,  X. 

237,  X. 

51,  331. 

X. 

346,  432. 

X. 

1,  124,  278,  294,  346,  432,  500. 

1 


197,  460,  476,  X.  X. 

401,  488. 

127,  129,  207,  294,  307,  476. 

X. 

233,  420,  X.  X. 

294,411. 

X. 

1. 

294,  321. 

92. 

297. 

294 

278!  294,  321,  356,  432. 

278,  294,  321,  432. 

297. 

294,  X. 

127,  278. 

127. 

X. 

159. 

X. 

X. 

68,  260. 

1. 

294,  339. 

216,  294. 

412. 

1.39. 

1.36. 

X. 

X. 

1,68,260 

X. 

405. 

68. 


294,  295,  432,  483,  X. 


102 


UNITED  STATES  TARIFF  COMMISSION 


Table  liB. — Synthetic  organic  chemical.'!:  Medicinah  for  uhich   United  States  produc- 
tion or  sales  were  reported,  identified  by  manufaetiirer,  19il-JiJ — Continued 


Chemical 

Manufacturers'  identification 
numbers  (according  to  list  on  p.  13.5) 

MEDICINALS,  CYCLIC— Continued 
Benzenoid — Continued 

0-(3,5-Di-iodo-4-hydroxyphenyl)-a-phenylpropioriic  acid 

l-Dimethylaniino-2-(diniethylaniinomethyl)-2-butanol  benzoate 

hydrochloride  (Alypin). 
dl-Dimethvlaniinoethanolcatechol  (Methadren) 

400. 
X. 

248. 

Dimethylether  of  diethvlstilbestrol 

248,  260. 

] 

Diphenvlacetyldiethylaniinoethanol  hydrochloride 

X. 

Diphenyleneglycolviurea  sodium 

295. 

Disodium  acetarsonate 

X. 

Disodium  hydroxymercurisalieyloxy  acetate  (Mercurosal) 

Disodium-4-sulfaminophenyl-2-azo-7-acetylan)ine-l-hydroxy- 

naphthalene-3,6-disulfonate. 
*Dyes,  medicinal: 

Acriviolet 

346. 
X. 

313. 

Brilliant  green .' 

313. 

3,6-Diaminoacridine  dihvdrochloride 

X. 

3,6-Diaminoacridine  sulfate  (Proflavine) 

1,  313. 

1,313. 

Dibromohydroxymercurifiuorescein,    sodium    salt     (Mercuro- 

chrome). 
2,2-Dihydroxy-5,5-dichlorodiphenylmethane 

92,  213. 
X. 

2,2'-Dihydroxy-3,5,6,-3',o',6'-hexaclxIorodiphenylmethane 

Gentian  violet 

X. 

313. 

Hexalet 

294. 

Methylene  blue 

72,  313. 

313 

313. 

51,  136,  213,  348. 

379. 

313. 

Sulfosalicvlic  acid .    .    . 

159,  294. 

Tetraiodophenolphthalein  and  sodium  salt 

51,  68,  136,  159,  278,  294,  313,  34S. 

159. 

1-Ephedrine  and  salts,  synthetic 

294. 

68. 

294. 

Ephedrinc  derivatives: 

Ephedrine  benzoate 

260. 

260. 

260. 

Xethamine  hydrochloride  (n-Ethylephedrine  hydrochloride)  . .  . 

295. 
X. 

(Diasone). 

294. 
136,  278. 

500. 

Guaiacol  (liquid) 

Hexamethyleneamine  acetaminosalicylic  acid  (Salihexin) 

203,  307. 
1. 

Hexesterol  (3,4-Di-p-hydroxyphenyl-n-hexane) 

295. 

412. 

412. 

p-Hydroxybenzoic  acid  esters: 

203,  294. 

203. 

.  203,  X. 

203,  X. 

92. 

Hydroxymercuri-4-nitro-o-cresol  anhydride 

1. 

X. 

1,  139. 

136,  X. 

X. 

92,  X. 

X. 

92,411. 

1,  278,  294. 

1,  260,  278,294,379,432. 
294,  X,  X. 

1,  278,  294. 

278,  294. 

286,  500. 

286. 

Mcthyl-m-amino-p-hydroxybenzoate  (Orthoform) 

500. 
295. 

X. 

346. 

295. 

2-Methyl-I,4-naphthoquinone 

•p-Methylphenylcinchoninic  ethyl  ester  (Xeocinchophen) 

2-Naphthol,  U.S.P 

2-Naphthoxyacetic  acid 

1 .  294. 
1,  51,  72. 
159. 
294. 

SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


103 


Table  12B. — Syjithetic  organic  chemicals:  M edicinab  for  which  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  19^1-^3 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


MEDICINALS,  CYCLIC— Continued 
Benzenoid — Continued 

5-Xaiihthyl  benzoate 

2-XapJith.vl  salicylate 

'Xcoarsphenamine 

Xeo-silver  arsphenamine 

Xeo-synephrin  hydrochloride 

Phenacaine  hydrochloride  (Di-(p-ethoxyphenyl)-acetamidine)  .... 

Phenarsine  hydrochloride 

*Phenolphthalein 

*Phenolsulfonates  (calcium,  sodium,  zinc,  etc.) 

2-Phenylisopropylamine  and  sulfate  (Benzedrine) 

Phenylmercuric  acetate 

Phenylmercuric  benzoate 

Phenylmercuric  borate 

Phenylmercuric  chloride 

Phenylmercuric  nitrate 

Phenylmercuric  salicylate 

Phenylpropanolamine  hydrochloride  (Propadrin  hydrochloride) .... 

Phenylsalicylate  (Salol) 

Phenylsemicarbazide  and  salts 

Potassium  hydroxyquinoline  sulfate 

Propenylmethylguaethol 

Resorcinol 

*Resorcinol  monoacetate 

•Salicylic  acid  U.S.P 

•Salicylic  acid  salts: 

Ammonium  salicylate 

'Calcium  salicylate 

Lithium  salicylate 

•Magnesium  salicylate 

•Sodium  salicylate 

Strontium  salicylate 

Salicylsalicylic  acid 

Silver  arsphenamine 

Sodium  p-aminophenylarsonate 

Sodium  antimony  III  bis-catechol-2,4-disuIfonate  (Fuadin) 

Sodium  arsanilate  (Atoxyl) 

Sodium  ethylmercurithio-benzene  sulfonate 

Sodium  ethylmercurithiosalicylate 

Sodium  o-iodohippurate 

Sodium  methylenesulfonaminohydroxy phenyl  arsenate  (Aldarsone) . 

Sodium  p-toluenesulfonchloramine  (Chloramine  T) 

Stilbamine  glucoside  (X'eostara) 

•Sulfa  drugs: 

Acetylsulfathiazole 

p-Benzylaminobenzenesulfonamide 

4'-Dimethylsulfamylsulfanilanilide  (Diseptal  A) 

Phthalylsulfathiazole 

Succinylsulfathiazole 

Sulfa-acetimide  (N-acetylsulfanilamide) 

Sulfadiazine .• 

Sulfaguanidine 

Sulfamerazine  (2-Sulfanilamido-4-methylpyrimidinc) 

•Sulfanilamide  (p-Aminobenzenesulfonamide) 

Sulfapyrazine  (2-Sulfanilamidopyrazine) 

Sulfapyridine  (2-Sulfanilamidopyridine)  and  salt 

•Sulfathiazole  (2-Sulfanilamidothiazole)  and  salt 

Sulfanilate,  zinc .■ 

•Sulfoarsphenamine 

4-Sulfonamido-2,4-diaminoazobenzene 

p-Sulfondichloramidobenzoic  acid 

Tannin  albuminate  (Tannalbin) 

Tannin-formaldehyde  (Tannoform) 

Tetrachlorophenol    

X.X.X'.X'-Tetraethylphthalamide  (Neospiran) 

p-Thiobenzenesulfonic  acid 

Thiosalicylic  acid 

•Thymol 

•Thymol  iodide 

Thymolphthalein 

p-Toluenesulfondichloramine  (Dichloroamine  T) 

a-Toluic  acid  (Phenylacetic  acid) 

Trichlorophenol 

Trisodium  sulfoarsphenamine. . . .  r 

Tryparsamide 

Vinethene  (Divinyl  ether) 

Vitamins: 

*K  (Menadione)  (2-Methyl-l,4-naphthoquinonc) 

K  (2-Methyl-l,4-naphthoquinone)-diphosphoric  ester,  tctra 

sodium  salt. 
Ki  (2-Methyl-3-phytyl-l,4-naphthoquinone) 


90 

159 

1,  1 

1. 

X 

173 

X. 

307, 

127, 

139 

52 

192 

52, 


159,294. 

,  297. 

24,  278,  294,  432,  500. 


,491. 


52, 

52, 

52. 

412 

127, 

139 

51. 

X. 

129 

136 

127 


,  356,  X. 
,  278,  294. 
,  X. 
139,  192, 


192. 
192. 
139,  192. 


351. 

159,  294,411. 
,  203,  295,  307. 


X. 

203,  278. 

203,  278. 

203,  249,  294,  295,  307. 

203,  278. 


127, 

127, 

X. 

127, 

127, 

127, 

294. 

500. 

68. 

500. 

68. 

260. 

260. 

278. 

1. 

307. 

68. 


307,  X. 
294. 
X. 
307. 

307,  348. 
72. 
1,  72. 
72. 
72. 

68.  72,  97,  294,  307,  500,  X. 
294 

1,  72,  294,  X.  X. 
1,  72,  95,  196,  260,  294,  307,  432 
500.  509,  X.  X. 

1,  124,  294,  432,  500. 

X. 

1. 

92.  159,  249,  297. 

92.  159. 

127. 

297. 

260. 

260. 

339.  X,  X. 

278.  294,  .321. 

1.36,  159. 

307. 

232,  294. 

127. 

1. 

294,  4.32. 

294. 

1,  16.  146.  175,  294,  295,  4.32,  483, 

.500.  X. 
205. 


104 


UNITED  STATES  TARIFF  COMMISSION 


Table  12B. — Synthetic  organic  chemicals:  Medicinals  for  which  United  States  produc- 
tion or  sales  were  reported,  identified  by  manufacturer,  191fl~!fS — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


MEDICINALS,  CYCLIC— Continued 

Alicyclic  and  Heterocyclic 

Adenine  sulfate 

Allantoin  (5-Ureidohydantoin) 

AUylcamphoramic  acid  and  mercurial  salts 

Amino  acids,  alicyclic  and  heterocyclic: 

Histidine  monohydrochloride 

l(-)-Hydroxyproline 

l(-)-Proline 

1-Tryptophane 

dl-Tryptophane 

2-Aminothiazole 

Antipyrine 

•Antipyrine  s  ^icylate 

Atropine,  synthetic,  and  salts 

Atropine  amineoxide  hydrochloride 

•Barbituric   acid   derivatives    (Salts   included   with    corresponding 
acids)  : 

5-Allyl-5-cyclopentenylbarbituric  acid  (Cyclopal) 

5-Allyl-5-isopropylbarbituric  acid  (Allonal)  (Alurate) 

.5-Allyl-5-(l-methyl-n-butyl)barbituric  acid  (Seconal) 

5-Allyl-5-phenylbarbituric  acid  (Alphenal) 

Aminopyrine  diethylbarbiturate  (Veramon)  (Peralga) 

Barbituric  acid 

5-n-Butyl-5-ethylbarbituric  acid  (Neonal) 

.5-sec-butyl-5-ethylbarbituric  acid 

5-(l-Cyclohexenyl)-l,5-dimethylbarbituric  acid  (Evipan) .  .  . 

.5-(l-Cyclohexenyl)-5-ethylbarbituric  acid  (Phanodorn) 

.5,.'3-Diallylbarbituric  acid  (Dial) 

Dibromobarbituric  acid 

/J.S-Diethylbarbituric  acid  (Barbital)  (Veronal) 

.5-Ethyl-5-n-hexylbarbituric  acid  (Ortal) 

o-Ethyl-o-isoamylbarbituric  acid  (Amytal) 

5-Ethyl-5-isopropylbarbituric  acid  (Ipral) 

5-Ethyl-5-(l-methyl-l-butenyl)barbituric  acid  (Delvinal) .  .  , 
•5-Ethyl-5-(l-methyl-n-butyljbarbituric  acid  (Pentobarbital) 
(Nembutal). 

5-Ethyl-5-(l-methyl-n-butyl)-2-thiobarbituric    acid    (Pen- 
tothal). 

5-Ethyl-l-methyl-5-phenylbarbituric  acid  (Mebaral) 

*5-Ethyl-5-phenylbarbituric  acid  (Plienobarbital)  (Luminal)  .  . 

5-(l-methyl-n-butyl)barbituric  acid 

•Bile  acids  and  salts: 

Cholic  acid 

Cholic  and  desoxycholic  acids,  mixed 

•Dehydrocholic  acid 

Dehydrocholic  acid  sodium  salt 

Dehydrocholic  and  dehydrodesoxycholic  acids,  mixed. 

Desoxycholic  acid 

Desoxycholic  acid,  sodium  salt 

Other  bile  acids  and  salts 

Bismuth  camphocarboxylate 

2-Butyloxycinehoninic   acid   diethylethylenodiamide   and    hydro- 
chloride. 

2-Butyloxy-2,6-diamino-5,5-azopyric'iine  (Niazo) 

•Caffeine  (from  Theobromine) 

Caffeine  derivatives: 

Citrate 

Hydrobromide 

•Sodium  benzoate 

Sodium  salicylate 

Tri-iodide 

Camphor,  synthetic,  U.S.P 

Camphoric  acid 

Camphoric  anhydride 

•Camphosulfonic  acid  and  salts 

ChaulmooKric  acid,  ethyl  ester 

Cholesterol .  .  .  : 

Cinchophen  hydroiodide 

Desox.vcorticosterone  acetate  (Cortate) 

3,4'-Di(acetylamino)-4-hydroxy-2'-phonoxyacetic    acid     arseno- 

benzene,  sodium  salt  (Salusalvarsan). 
N-Diethylaminoisopentyl-8-amino-6-iiu'tliuxyiiiiin(iliiic    (  I'l  a  s- 
mochin). 

Dihydroeodcionono  bitartrate 

3,o-Di-iodo-N-methyl-4-pyridoxyl-2,()-ilicarboxylic    acid,    (iiso- 
dium  salt  (Neo-iopax). 

3,.5-Di-iodo-4-pyridon-N-acetic  acid  diethanolaminc 

4-Dimcthylaminoantipyrine  (Aminopyrine) 

Diphenylhydantoin,  sodium  salt 

Emetine  h.vdrochloride,  synthetic 

Eserine  amineoxide  salicylate 


136. 

1,  139,  X. 

159. 

205,  348,  355,  474. 

294. 

294. 

294,  355. 

294. 

X. 

127,  159,  294. 

92,  127,  1.59,  294,  297 

216,  294. 

118. 


173. 

205. 

260. 

173. 

92. 

1. 

1. 

X. 

X. 

X. 

173,  X. 

X. 

1,  173,  205,  X. 

346. 

260. 

X. 

294 

1,  173,  260,  ,331,  372,  X. 

1. 


1,  51,  173,  174,  2.33,  260,  278,  294, 

X. 
260. 

146,  248,  288,  474,  499,  X. 

146. 

146,  238,  248,  474,  499,  X. 

474. 

146. 

248,  474,  499. 

238,  474. 

146,  X. 

1. 

X. 

400. 

14,  159,  180,  290,  307. 

294,  307. 

294 

92,  278,  294,  321. 

278,  294,  ,321. 

297. 

129,  319. 

159. 

159,  278. 

92,  1.36,  159,  249,  297. 

159,  X. 

15,  27. 
260. 
400. 
X. 


X. 

146. 
400. 

X. 

3i:!, 

X. 

294. 

ns. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


105 


Table  12B. — Si/nthetic  organic  chemicals:  Medicinals  for  which  United  States  produc- 
tion or  sales  were  reported,  ident'fied  by  manufacturer,  1941— JfS — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


MEDICINALS,  CYCLIC— Continued 

AHcyclic  and  Heterocyclic — Continued 

Eserine  salicylate 

Estradiol 

a-Estradiol-3-benzoate 

o-'Estradiol-3,17-dipropionatc 

Estrone  (Ketohydroxyestrin) 

2-Ethoxy-6,9-diaminoacridine  and  salts 

Ethynyltestosterone 

Eucatropine  hydrochloride 

Hexamethylenetetramine 

•Hcxamethylenctetramineanhydromethylene  citrate  (Helmitol) . . . . 
•Hcxamethylenetctramincmethylenc  citrate 

Hexamethylenetetramine  tetraiodide 

Histamine  base 

Histamine  phosphate 

Homatropine  and  salts    

Homatropine  methylbromide  (Novatropine) 

Homomenthyl  sahcylate 

S-Hydroxyquinoline  (Oxyquinoline) 

8-Hydroxyquinoline  benzoate 

8-Hydroxyquinoline  citrate 

8-Hydroxyquinoline  hydrochloride 

8-Hydroxyquino)ine  sulfate 

8-Hydroxyquinoiine  tannate 

8-Hydroxyquinoline-5-8ulfonic  acid 

Iodochloro-8-hydroxyquinoline 

*7-Iodo-8-hydroxyquinoline-o-sulfonic  acid  (Yatren  acid)  and  salt 

lodopyrine 

Lysidine  bitartrate 

Menthyl  ethoxyacetate  (Coryfin) 

Menthyl  sahcylate 

Menthyl  valerate  (Validol) 

b-Mercurial  allylcamphoramic  acid 

o-Mercurial  allylcamphoramic  acid,  sodium  salt  (Mercurin) 

*2-Methoxy-6-chloro-9-diethylaminopentylaminoacridine  hydro- 
chloride (Atebrin)  (Quinacrine  hydrochloride). 

Methylcholanthrene 

7-(2~Methylpiperidino)-propyI  benzoate  hydrochloride 

^lethyltestosterone  (Oreton  M) 

'Nikethamide  (Niacin  diethylamide)  (Coramino) 

Nucleic  acid  (from  yeast) 

Nucleic  acid  salts 

Papaverine,  synthetic 

l-PhenyI-2,3-dimethyl-4-mcthylamino-5-pyrazolone     formalde- 
hyde bisulfite  (Novaldin). 
2-Phenyl-4-cjuinolinecarboxylic    acid    (Cinchophen)    (Phenylcin- 
choninic  acid). 

Piperazine,  anhydrous 

Piperazine  derivatives: 

Piperazine  hcxahydrate  (Piperazine  hydrate) 

Piperazine  salicylate 

Piperazine  tartrate 

Piperidinopropanedioldiphenylurethane  (Diothane) 

Piperidinopropanedioldiphcnylurc thane  hydrochloride  (Diothane 
hydrochloride). 

Progesterone 

Pyramidon  and  trichloroethyl  alcohol  urethane  compounds 

Quinine  bismuth  iodide 

Scopolamine  amineoxide  hydrobroniide 

Sodium  diphenylhydantoinate  (Dilantin) 

Sodium  succinate 

*Terpin  hydrate 

Testosterone 

Testosterone  propionate 

Theobromine  derivatives: 

Theobromine  calcium  gluconate 

Theobromine  calcium  salicylate 

'Theobromine  sodium  acetate 

'Theobromine  sodium  salicylate 

'Theoph.vlline  (1,  3-Dimethylxanthine)  and  derivatives: 

Theophylhne  base 

'Theophylline  ethylencdiamine  (Aminophylline) 

Theophylline  methylglucamine  (Glucophylline) 

Theophylline  monoethanolamine  (Theamin) 

Theophylhne  sodium  acetate 

Theophylline  sodium  salicylate 

'Vitamins: 

A  acetate,  concentrate 

A  acetate,  crystalline 

A  palmitate,  crystalline 


216,  294. 

400. 

400. 

400. 

81. 

X. 

400. 

491,  X. 

129,  203. 

139,  159,  238,  297,  X. 

159,  297,  X. 

92,  X. 

474. 

474. 

216,  294. 

X. 

X. 

51.  294. 

51,  294. 

294. 

51. 

51,  294. 

51. 

51,294. 

X. 

1,  51,  57,  68.  297,  X. 

92,  278. 

X. 

X. 

X. 

X. 

1.59. 

159. 

1,  196,  294,  313,  500,  X,  X. 

137. 

260. 

400,  X. 

1,  146,  150,  173,  2.38,  249,  288,  294, 

297,  X,  X,  X,  X. 
405. 
405. 
294. 
X. 

51,  72. 

288,  367. 

139,  159,  288. 

367. 

60,  288,  367. 

295. 

295. 

146,  184,  248,  400,  X,  X. 

159,  X. 

139,  238,  297. 

118. 

51,  294,346. 

278,  294. 

129,  201,  294,  411,  X. 

400. 

400,  X. 

X. 

92,  372. 

278,  294,  321,  X. 

92,  278,  294,  321. 

51,  173,  278. 

18,  51,  57,  128,  173,  248,  277.  294 

372,  X,  X. 
1. 

260. 

173,  278,  X. 
278. 

125. 
125. 
125. 


106 


UNITED  STATES  TARIFF  COMMISSION 


Table  12B. — Synthetic  organic  chemicals:  Medicinals  for  which  United  States  produc- 
tion or  sales  ivere  reported,  identified  by  manufacturer,  19Jtl~i3 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


MEDICINALS,  CYCLIC— Continued 
Alicyclic  and  Heterocyclic — Continued  ^ 

•Vitamins — Continued 

Bi  (Thiamin  chloride  and  hydrochloride) 

*B2  (Riboflavin,  for  human  consumption) 

*B2  (Riboflavin,  for  animal  and  poultry  consumption)  (100%) 

Bo  (Pyridoxine) 

*D8  (Irradiated  ergosterol)  (Viosterol) 

D3  (Irradiated  or  activated  animal  sterol)  (Delsterol) 

E  (a-Tocopherol) 

E  (a-Tocopherol  acetate) 

E  (a-Tocopherol  calcium  succinate) 

Inositol 

Inositol  hexaphosphate,  calcium  magnesium 

*Nicotinic  acid  (Niacin) 

'Nicotinic  acid  amide  (Niacinamide) 

MEDICINALS.  ACYCLIC 

Acetylcholine  bromide 

Acetylcholine  chloride 

Acetyl- ^-methylcholine  bromide 

Acetyl-|3-methyIcholine  chloride 

AUylisopropyl  acetylurea 

Allylurea  (Thiosinamine) 

•Amino  acids,  acyclic: 

i8- Alanine 

dl-a-Alanine 

Aminoacetic  acid  (Glycocoll)  (Glycin) 

Arginine  and  hydrochloride 

dl-Aspartic  acid 

•Cysteine  hydrochloride 

1-Cystine 

Cystine  monohydrochloride 

1(  +)-Glutamic  acid 

dl-Glutamic  acid 

Glutathione 

dl-Isoleucine 

1-Leucine 

dl-Leucine 

d- Lysine  monohydrochloride 

1-Lysine  monohydrochloride 

dl-Methionine 

dl-Norleucine 

dl-Serine 

dl-Threonine 

dl- Valine ; 

*Amyl  nitrite  (Isoamyl  nitrite) 

Auro-thioglucose  (Solgenal-B  oleosum) 

Azochloramide . 

Barium  hexose  diphosphate 

Bismuth  albuminate 

Bismuth  octyl  oxyacetate  (Lipo  bismol) 

Bismuth  tri-a-ethyl  caproate  (Lipobin) 

Bromodiethylacetylcarbamide 

Bromoisovalerylurea  (Brornural) 

•Caeodylic  acid  and  derivatives: 

Bismuth  cacodylate 

Caeodylic  acid  chloride 

Calcium  cacodylate 

•Iron  cacodylate 

•Guaiacol  cacodylate 

Magnesium  cacodylate 

Manganese  cacodylate 

•Sodium  cacodylate 

Strychnine  cacodylate 

Calcium  hexose  diphosphate 

Calcium  iodobehenate 

Calcium  lactobionate 

Calcium  lactophosphate 

•Calcium  levulinate 

Calcium  saccharate 

Chloral  hydrate 

Choline  chloride 

•Disodium  methylarsonate  (Arrhenal) 

Erythrol  tetranitrate  (Erythrityl  tetranitrate) 

Ethyl  carbamate  (Urethan) 

Ethyl  di-iodobrassidate 

Ethylenediamine  dihydrochloride 

Ethyldiamine  di-iodide 

Ethylenediamine  mandelate 


205,  294,  X. 

106,  205,  94,  356. 

106,  356,  374,  470,  X. 

205,  294. 

1,  129,  175,  180,  181,  291,  333,  432, 

436,  483,  X,  X. 
129. 

205,  294. 
294. 
294. 
355. 
92,  X. 
1,  45,  72,  83,  177,  205,  294,  321. 

379,  X. 
1,  72,  173,  175,  177,  205,  248,  28S, 

294,  297,  321,  379,  X. 


136. 

238,  294. 

294. 

294. 

205. 

139,  248,  X. 

1.294,  X,  X. 

294. 

51,  127,  355. 

292,  294,  474. 

294. 

1.59i  348,  474,  355. 

1.59,  3.55. 

474. 

294. 

294. 

405. 

294. 

294,  355. 

294. 

294. 

294,  474. 

294. 

294,  355. 

294. 

294. 

294. 

136,  278,  294,  X. 
400. 

X. 

405. 

297. 

X. 

248. 

90,  .304,  X. 

90. 

137. 
297 
137',  249,  297. 

137,  2.38,  249,  297,  418,  X. 
1.37,  294,  297. 

1.37,  249. 

249. 

137,  2.38,  249,  297,  375,  418,  X. 

249,  297. 

405. 

1.59,  X. 

1.59. 

92,  238,  278. 

68,  92,  159,  348,  355,  X,  X. 

60,  356,  X. 

294,  307. 

106,  1.36,  294. 

238,  249,  297. 

294. 

470. 

X. 

X. 

X. 

X. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


107 


Table  12B. — Synthetic  organic  chemicals:  Mcdicinals  for  which   United  States  produc- 
tion or  sales  ivere  reported,  identified  by  manufacturer,  1941-43 — Continued 


Chemical 


MEDICINALS,  ACYCLIC— Continued 

♦Ethyl  iodide. 

Ethyl  mercui'ic  chloride 

Ethyl  monhuatc 

♦Ethyl  nitrite 

Gluconic  acid  salts: 

Calcium  gluconate 

Copper  gluconate 

Potassium  gluconate 

Glycerophosphorjc  acid 

Glycerophosphoric  acid  salts: 

Calcium  glycerophosphate 

Iron  glycerophosphate 

Magnesium  glycerophosphate 

Manganese  glycerophosphate 

Potassium  glycerophosphate 

Sodium  glycerophosphate 

Other  glycerophosphates 

Hcxamethyldiaminoisopropanol  di-iodide 

Hcxamethylenemethjl  iodide 

Humic  acid  and  salts 

Iodized  castor  oil  (Riodine) 

Iodized  fatty  acids 

♦Iodoform 

lodomethanesulfonic  acid,  sodium  salt 

Isobutanolaminc  hydrochloride 

Lactic  acid  salts: 

Calcium  lactate 

Copper  lactate 

Ferrous  lactate 

Magnesium  lactate 

Strontium  lactate 

Lithium  lactate 

Mecholyl  bromide 

Mecholyl  chloride • 

Magnesium  hexosediphosphate 

Met hoxyoximercuripropylsuccinyl urea  (Mercuhydrin,  Urolake) 

Methylocholine  chloride  urethane 

Methylenccitric  acid  and  salts 

Methylene  iodide 

♦Methyl  iodide 

Potassium  bisaccharatc 

dl-Ribosc 

Saccharic  acid (.  . 

Silver  preparations,  colloidal: 

Silver  protein,  mild 

Silver  protein,  strong 

Silver  preparations,  colloidal,  n.e.s 

Sodium  aurotliionialato  (Myochrysine) 

Sodium  bismuth  thioglycolate  (Thiobismol) 

Sodium  ricinoleate 

Sodium  succinate 

Sulfonethylmcthane  (Trional) 

Sulfonmethane  (Sulfonal) 

Tartaric  acid  salts: 

Antimony  and  potassium  tartrate 

Bismuth  potassium  tartrate 

Bismuth  sodium  tartrate 

Potassium  bitartrate 

.  Potassium  sodium  bismuth  tartrate  (Bismosol) 

Potassium  sodium  tartrate 

tert-Tribromobutvl  alcohol  (Brometone) 

2,2,2-Tribromoethanol 

Tribroniomethane  (Bromoform) 

Trichloroacetic  acid 

♦tert-Trichlorobutyl  alcohol  (Chloretonc)  (Chlorobutanol) 

L'rea  nitrate 

Urethane 

n-Valerie  acid  salts: 

Ammonium  valerate 

Zinc  valerate 

♦Vitamins: 

Bi  (Panthothenic  acid) 

Calcium  panthothenate,  racemic 

Calcium  d-panthothenate 

Other  B4  derivatives 

C  (Ascorbic  acid) 

♦C  (Ascorbic  acid,  sodium  salt) 

Iso-ascorbic  acid 

Bismuth  ascorbate 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  1.35) 


136,  139,  27S,  294. 

260. 

159. 

278,  294,  350. 

278,  356,  X. 
356. 
3.56. 
307. 

203,  307. 

203,  307. 

203,  307. 

203,  307. 

203,  307. 

203,  307. 

203,  307. 

X. 

297. 

159. 

X. 

260. 

278,  294,  321. 

X. 

295. 

17,  24,  415,  X. 

415. 

278,  415. 

415. 

278,  294. 

223. 

294. 

294. 

405. 

248. 

294. 

159,  X. 

1.36,  137,  294,  X. 

1.36,  139,  249,  278,  294,  297. 

60. 

405. 

60. 

203,  412,  4.32,  X. 

203. 

297. 

294. 

.346. 

295,  X. 

294,  X. 

27S. 

278. 

356. 

1. 

60,  248. 

356. 

294. 

356. 

346. 

X. 

127,  298,  X. 

127,  1.36. 

51,  294,  X,  X,  X,  X. 

1.59. 

470. 

92 

92,"  150. 

175. 

1. 

1,294,  X. 

294,  X,  X. 

205,  294,  356. 

205,  294,  297. 

205. 

X. 


108 


UNITED  STATES  TARIFF  COMMISSION 


FLAVOR  AND  PERFUME  MATERIALS 

Table  13B. — Synthetic  organic  chemicals:  Flavor  and  perfume  materials  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,    19^1- JfS 

[Flavor  and  perfume  materials  for  which  separate  statistics  are  given  in  table  13A  are  marked  below  with 
an  asterisk  (*) ;  those  not  so  marked  do  not  appear  in  table  13A  because  the  reported  data  are  confi- 
dential and  may  not  be  published.  Manufacturers  are  identified  by  numbers  in  the  alphabetical  list 
appearing  on  p.  135.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his 
identification  number  with  the  designated  product.] 


Material 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  13.)\ 


FLAVOR  AND  PERFUME  MATERIALS,  CYCLIC 
Benzenoid 

*Acet(>phenone • 

*AmyI  benzoate 

*a-Amylcinnamaldehyde 

a-Amylcinnamyl  acetate 

a-Amylcinnamyl  alcohol.- 

Amyl-p-cresol 

•  Amyl  salicylate 

Amyl  a-toluate  (Amyl  phenylacetate) 

Anethole 

*Anisaldehyde  (Aubepine) 

Anisole  (Methyl  phenyl  ether) 

Anisyl  acetate 

*Anisyl  alcohol 

Anisyl  formate 

Anisylideneacetone 

Anisyl  propionate 

•Benzophenone 

Benzylacetal 

*Benzyl  acetate 

•Benzyl  alcohol 

•Benzyl  benzoate 

Benzyl  butyl  phthalate 

•Benzyl  butyrate 

Benzyl  cinnamate 

Benzyl  ether 

•Benzyl  formate 

•Benzylideneacetone 

Benzylideneglycerol 

Benz.yl  isoamyl  ether 

Benzyl  isobutyrato 

•Benzyl  isoeugenyl  ether  (Benzyl  isoeugenol) 

Benzyl  ketone 

•Benzyl  propionate i 

•Benzyl  salicylate 

Benzyl  a-toluate  (Benzyl  phenylacetate) 

Benzyl  valerate 

•Bromostyrene 

Butyl  anthranilate 

Butyl  a-toluate  (Butyl  phenylacetate) 

•Cinnamaldehyde 

•Cinnamic  acid 

•Cinnamyl  acetate 

•Cinnamyl  alcohol 

Cinnamyl  anthranilate 

Cinnamyl  butyrate 

♦Cinnamyl  cinnamate 

Cinnamyl  formate 

•Cinnamyl  isobutyrate 

Cinnamyl  isovalerate 

Cinnamyl  propionate 

Cinnamyl  valerate 

♦p-Cresyl  acetate 

p-Cresyl  benzyl  ether 

p-Cresyl  caprylate 

p-Cresyl  ethyl  ether 

p-Cresyl  isobutyrate 

•p-Cresyl  methyl  ether 

p-Cresyl  phenyl  ether 

m-Cresyl  a-toluate  (m-Cresyl  phenylacetate) 

p-Cresyl  a-toluate  (p-Cresyl  phenylacetate) 

p-Cresyl  valerate 

Cumaldehyde  (p-Isopropylbenzaldehyde) 

3,4-Diethoxybenzaldehyde 

2,4-Dimethylacetophenone 

(3,/3-Dimethylphenethyl  acetate 

S,/3-Dimethylphenethyl  alcohol 

Dimethylphenylpropyl  alcohol 

2,6-Dinitro-3-tert-butylcymene 


169,  X,  X,  X. 

156,  473,  X,  X. 

156,  233,  286,  409,  473,  479, 

480,  X,  X,  X. 
479. 
479. 
479. 

286,  290,  420,  475,  X,  X. 
156,  286,  X. 
319,  X,  X. 

129,  340,  479,  X,  X,  X,  X. 
159. 

129,  X,  X. 
129,  X,  X. 
156,  X. 
479. 
409,  X. 

169,  233,  286,  X. 
X. 
233,  286,  340,  420,  476,  479, 

X,  X,  X. 
207,  233,  286,  420,  473.  475,  X,  X. 
233,  286,  420,  475,  X,  X. 
475. 

156,  286,  473,  475,  X,  X,  X. 
51,  473,  475,479,  X,  X. 
420. 

156,  286,  290,  473,  475,  X,  X,  X. 
286,  290,  340,  473,  X. 
X. 

129,  X. 

150,  156,  X,  X. 
479,  X,  X. 
479,  X,  X. 
129,  156,  286,  290,  340,  409, 

473,  X,  X,  X. 
169,  286,  475,  X,  X. 
473,  X. 
156,  X,  X. 
51,473,475,  X. 
156. 

479,  480. 
207,  233,  286,  409,  420,  476,  X,  X, 

X. 
51,  169,  X. 
156,  286,  .340,  473,  479,  X,  X,  X, 

X. 
169,  286,  290,  473,  475,  X,  X,  X. 
156. 
156. 

475,  479,  X,  X. 
156,  473,  X,  X. 
156,  409,  X. 
156,  409,  X. 
156,  409,  X,  X. 
409,  X. 

156,  473,  475,  X,  X. 
X. 

156,  473. 
480. 

156,  473,  X. 
129,  480,  X. 
X. 

X,  X. 

156,  473,  479,  X,  X. 
156. 

129,  156,  X,  X. 
X. 
X. 

473,  479. 
473. 
X. 
X. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


109 


Table  13B. — Synthetic  organic  chemicals:  Flavor  and  perfume  materials  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1941— 4S — Continued 


Material 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


FLAVOR  AND  PERFUME  MATERIALS, 
CYCLIC— Continued 
Benzenoid — Continued 

Diphenylmethane 

p-Ethoxybenzaldehyde 

Ethyl  anisate 

'Ethyl  anthranilate 

*Ethyl  benzoate 

Ethyl  cinnamate 

•Ethylmethylphenyl  glycidate 

Ethylphenyl  glycidate 

•Ethyl  salicylate 

Ethyl  a-toluate  (Ethyl  phenylacetate) 

Ethyl-p-tolyl  glycidate 

Ethylvanillin 

Eugenol 

Eugenyl  acetate 

Eugenyl  formate 

Eugenyl  a-toluate  (Eugenyl  phenylacetate) 

Guaiacyl  acetate 

Hexylcinnamaldehyde 

Hydroquinonc  dimethyl  ether  (Dimethyl  hydroquinone) 

Hydroquinone  monomethyl  ether 

Isoamyl  cinnamate 

*Isobutyl  benzoate 

Isobutyl  cinnamate 

Isobutyl  salicylate 

•Isobutyl  a-toluate  (Isobutyl  phenylacetate) 

•Isoeugenol 

•Isoeugenyl  acetate 

Isoeugenyl  a-toluate  (Isoeugenyl  phenylacetate) 

Isopropyl-o-cresol  (Carvacrol) 

Isothymol,  hydrogenated 

Menthyl  anthranilate 

p-Methoxyacetophenone 

*p-Methylacetophenone  (Methyl  p-tolyl  ketone) 

•Methyl  anthranilate 

*N-Methylanthranilic  acid  methyl  ester  (Dimethyl  anthranilate)  . 

p-Methylbenzaldehyde  (p-Tolualdehyde) 

•Methyl  benzoate 

*a-Methylbenzyl  acetate  (Styralyl  acetate) 

*a-Methylbenzyl  alcohol  (Methylphenyl  carbinol)  (Styralyl  alcohol) 
•Methyl  cinnamate 

Methyl  p-cresol 

•Methyl  eugenyl  ether 

p-Methylhydratropaldehyde  (p-Methyl-a-phenylpropionaldehyde) 
•Methyl  isoeugenyl  ether 

a-Methyl-p-isopropylhydrocinnamaldehyde 

p-Methylphenylaeetaldehyde 

Methyl  phenylpropionate 

•Methyl  salicylate  ( Wintergreen  oil) 

•Methyl  a-toluate  (Methyl  phenylacetate) 

Musk  ambrette 

Musk  ketone 

•Musk  xylene 

•Phenethyl  acetate 

•Phenethyl  alcohol 

Phenethyl  anthranilate 

Phenethyl  benzoate 

•Phenethyl  butyrate 

Phenethyl  cinnamate 

•Phenethyl  formate 

Phenethyl  isobutyrate 

Phenethyl  isovalerate 

Phenethyl  phenylisobutyrate 

•Phenethyl  propionate 

•Phenethyl  salicylate 

•Phenethyl  a-toluate  (Phenethyl  phenylacetate) 

•Phenethyl  valerate 

/3-Phenoxyethyl  isobutyrate 

Phenyl  benzoate 

l-Phenyl-2-propanone  (Benzyl  methyl  ketone)  (Phenylacetone) .  . 
•a-Phenylpropionaldehyde  (Hydratropaldehyde) 

3-Phenyl-l-propionaldehyde  (Hydrocinnamaldehyde) 

•3-Phenyl-l-propyl  acetate  (Hydrocinnamyl  acetate) 

•3-Phenyl-l-propyl  alcohol  (Hydrocinnamic  alcohol) 

3-Phenyl-l -propyl  cinnamate  (Hydrocinnamyl  cinnamate) 

3-Phenyl-l-propyl  formate 

3-Phenyl-l-propyl  propionate 

Propyl  cinnamate 

Salicylaldehyde 

a-Tolualdehyde  (Phenylacetaldehyde) 

a-Tolualdehyde  dimethylacetal 


X. 

479. 

X. 

150,  156,  286. 

330,  470,  473,  X,  X,  X,  X. 

473,  X,  X. 

156,  409,  473,  480,  X,  X,  X. 

480,  X. 

127,  X,  X,  X. 

1.  51,  233,  286,  473,  X. 

409. 

290,  307,  X. 

X,  X. 

479,  X. 

479. 

X. 

156,  479,  X. 

129,  X. 

129.  X. 

X. 

X. 

156,  290,  473,  X. 

156,  X. 

479,  X,  X. 

156,  286,  290,  473,  X,  X. 

156,  X,  X,  X,  X. 

340,  479,  X,  X. 

X. 

339,  X. 

207. 

X. 

X. 

169,  319,  X,  X,  X,  X. 

127,  129,  290,  X,  X. 

129,  156,  286,  475,  X. 

X  X 

203,  207,  286,  330,  473,  476,  X,  X. 

169,  473,  X. 

169,  207,  473,  X.  X. 

51,  X,  X,  X,  X,  X. 

156,  X. 

156,  X,  X,  X. 

480,  X. 

156,  X,  X,  X. 

129,  X. 

X. 

X. 

127,  159,  203,  295,  307,  X,  X. 

51,  169,  233,  286,  473,  X,  X,  X. 

286,  X. 

286,  X. 

129,  286,  X. 

1,  51,  233,  290,  409,  473,  X,  X,  X. 

127,  233,  473,  480,  X. 

479,  X. 

479. 

156,  290,  X,  X. 

156,  479,  X. 

156,  340,  473,  479,  X,  X. 

150,  X,  X. 

X,  X,  X. 

473. 

156,  286,  290,  473,  479,  X,  X. 

129,  473,  479,  X,  X. 

156,  473,  X,  X. 

156,  409,  X. 

X. 

X. 

169,  479,  X,  X. 

156,  169,  473,  480,  X,  X. 

479,  X. 

156,  286,  473,  479,  X,  X. 

169,  207,  473,  X. 

X. 

X. 

156,  473. 

156. 

127,  129. 

169,  X,  X. 

156,  169,  340,  X. 


no 


UNITED  STATES  TARIFF  COMMISSION 


Table  13B. — Synthetic  organic  chemicals:  Flavor  and  perfume  materials  for  which  United 
States  production  or  sales  loere  reported,  identified  by  manufacturer,  lO^l-JfS — Continued 


Material 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  13o) 


FLAVOR  AND  PERFUME  MATERIALS, 
CYCLIC— Continued 
Benzenoid — Continued 

*a-Toluic  acid  (Phenyla'cetic  acid) 

Tol vl  acetate 

Tolylaldehyde 

Triciiloromethylphenylcarbinyl  acetate  (Rosetone) 

l,3,4-Trimethyl-5-tert-butyI-2,6-dinitrobenzene 

*  Vanillin 

Veratraldehyde  bisulfate 


Terpenoid 


Bornyl  acetate. . . . 

Bornyl  isovalerate. 

Carvomenthol 

*Cedryl  acetate. . . . , 

Cedryl  butyrate. .  . 

Cedryl  formate . . . . 

Cedryl  propionate. 
*Citral 


Citral  acetate. 
•Citronellal 


•Citronellol. 


*Citronellyl  acetate 

*Citronellyl  butyrate 

Citronellyl  formate 

Citronellyl  isobutyrate 

Citronellyl  propionate 

Cyclamene  alcohol 

Cyclogeraniol 

Cyclogeranyl  acetate 

Dihydrocitronellol  (3,7-DimethyI-l-octanol) . 

Dihydrocitronellyl  acetate 

Farnesol 

Geralin,  synthetic 

*Geraniol 


Geraniol,  hydrogenated. 

Geraniol  residue 

*Geranyl  acetate 


•Geranyl  benzoate 

*Geranyl  butyrate 

*Geranyl  formate 

Geranyl  i.sobutyrate 

Geranyl  isovalerate 

Geranyl   a-toluate ■ 

Geranyl  propionate 

Hexahydropseudoionone. . , 

'Hydroxycitronellal 

*Hydroxycitronellol  dimethylacetal 

Hydroxycitronellol 

Hydroxy citronellylidene-o-aminobenzoic  acid, methyl  ester(Aurania) 
*o-Ionone 


*i8-Ionone 

*Ionone  n.e.s 

Isobornyl  acetate 

Isobornyl  alcohol  (Isoborneol) . 

'Isopulegol 

*Isopulegyl  acetate , 

Isosafrol 

•Linalool 

*Linalyl  acetate 


Linalyl  anthranilate 

Linalyl  benzoate 

•Linalyl  butyrate. 

Linalyl  cinnamate 

•Linal.vl  formate 

Linalyl  isobutyrate 

•Linalyl  propionate 

Linalyl  salicylate 

Linalyl  valerate 

Menthocitronellol 

Menthol,  hydrogenated  .  .  . 
•Menthol,  synthetic,  tech. . . 

Menthol,  synthetic,  U.S.P. 

Menthone 


51,  169,  233,  286,  473,  X,  X. 

X. 

203,  X. 

X,  X. 

X. 

290,  307,  399,  X,  X. 

129. 


156,  X. 

X. 

207. 

473,  479,  X,  X. 

479. 

479. 

479. 

70,  129,  156,  269,  340,  473,  475, 

X,  X,  X,  X,  X. 
479. 
129,  156,  269,  286,  329,  340. 

409,  461.  473,  479,  X,  X,  X,  X. 
129,  156,  169,  269,  286,  340,  409, 

461,  473,  475,  479,  X,  X,  X. 
1.56,  286,  473,  479,  X,  X. 
156,  479,  X. 
156,  286,  479. 
150,  X. 
156.  473,  X. 
479. 
479. 
479. 

156,  409,  473,  X. 
479. 
479. 
X. 
129,  156,  169,  269.  286,  340, 

409,  461,  473,  475,  479,  480,  X, 

X,  X,  X,  X. 
207. 
409. 
129,  156.  169,  233,  286,  340, 

409,  473,  479,  X,  X,  X,  X,  X,  X. 
150,  479,  X. 
1.56,  473,  475,  479,  X. 
156,  286,  473,  475,  479,  X,  X.  X. 
150.  473. 
156.  X. 

156,  479,  X,  X. 
156.  286,  473,  479,  X. 
X. 

129,  340.  409,  461,  473,  480,  X,  X. 
129.  156,  340,  409,  X. 
409,  480,  X. 
156. 
129,  286.  290,  409,  473,  480.  X, 

X  X 
129, '290,  X,  X. 

129,  290,  340.  473,  480,  X,  X,  X. 
129,  156. 
129 

129',  169,  409.  473,  X,  X. 
129,  473,  X. 
X,  X. 

156,  286,  X,  X,  X,  X,  X,  X. 
156,  340,  473,  475,  479,  X,  X,  X, 

X,  X,  X,  X. 
475,  479. 
1.50,  479,  X. 
150,  156,  479.  X,  X,  X. 
479,  X. 

150,  156.  340.  473,  479,  X.  X.  X, 
150,  473,  X,  X. 
156,  473,  479,  X,  X. 
479. 
479. 
X. 
207. 

286,  329,  X.  X,  X,  X. 
286,  X. 
286,  329,  479,  X,  X. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


111 


Table  13B. — Synthetic  organic  chemicals:  Flavor  and  perfume  materials  for  which  United 
States  production  or  sales  ivere  reported,  identified  by  manufacturer,  1941-^3 — Continued 


Material 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


FLAVOR  AND  PERFUME  MATERIALS, 
CYCLIC— Continued 
Terpenoid — Continued 

Menthyl  acetate 

Menthyl  anthranilate 

Metahomomenthol 

Methylhomojasmone 

*Methylionone 


•Nerol,  pure 

Neryl  acetate 

Neryl  propionate 

•Rhodinol  (2,6-Dimethyl  octene(2)ol) , 


Rhodinol  rose 

•Rhodinyl  acetate.  .  .  . 
*Rhodinyl  formate. . . 

Sagyl  acetate 

Santalal 

Santalyl  acetate 

Santalyl  a-toluate. .  . 

•a-Terpineol 

•/3-Terpineol 

Terpineol,  n.e.s 

•Terpinolene 

•Terpinyl  acetate 

Terpinyl  formate.  .  . 

Terpinyl  a-toluate.  .  , 

Terpinyl  propionate. 

Vetivenol 

•  Vetivenyl  acetate . . . 


Heterocyclic 
*Coumarin,  synthetic 

Dihydrocoumarin  (Melilotin) 

Dihydromethylcoumarin  (Methyl  melilotin) 

6-Hydroxy-3-methyl-5(l'-metho-ethynyl)  coumarone. 

Indalone  (Pyrone) 

•Indole 

Isobutylquinoline 

Isopropylquinoline 

3-Methylcoumarin 

6-Methylcoumarin 

*Piperonal  (Heliotropin) 

Saccharin 

Saccharin,  sodium  salt 

Skatole 


Naphthalenoid 

Ethyl  /3-naphthyl  ether  (Nerolin) 

Methyl  /3-naphthyl  ether  (Yara  yara) . . . 

Methyl  ^-naphthyl  ketone 

/3-Naphthyl  anthranilate 


Ali  cyclic 


Cyclopentanone . 


FLAVOR  AND  PERFUME  MATERIALS,  ACYCLIC 
Acetal . 


'Allyl  caproate 

Ally!  caprylate 

Allyl  enanthate 

Allyl  heptoate 

Allyl  isothiocyanate  (Synthetic  mustard  oil) 

Allyl  myristate 

Allyl  propionate 

Allyl  urea 

Amyl  butyrate 

Amyl  caproate 

Amyl  ethyl  ketone 

Amyl  formate 

Amyl  laurate 

Amyl  propionate 

Amy!  valerate 

2,3-Butanedione  (Diacetyl) 

n-Butyl  butyrate 

n-Butyl  capryl  ether 

Butyl  isoValerate 

Butyl  sulfide 

Capryl  butyrate ^ 

1-Carbomethoxyheptme  (Methyl  heptine  carbonate) . 
Cetyl  alcohol 


286,  329,  479,  X. 

286,  X. 

X. 

479. 

129,  286,  290,  473,  479, 

X,  X. 
156,  473,  479,  X. 
479. 
479. 
129,  156,  269,  340,  473, 

479,  X,  X,  X,  X. 
479. 

156,  340,  473,  475,  X,  X, 
156,  340,  X,  X. 
479. 

156,  473,  X. 
156,  479,  X. 
X. 

201,  319. 
319. 

129!  319,  475,  X,  X. 
129,  201,  X. 

129,  156,  340,  X.  X,  X,  X. 
150. 
479. 

129,  479,  X,  X. 
479,  X,  X,  X. 
1.56.    340,    473,    475, 

X,  X,  X. 

127,  129,  290,  307,  479. 
X. 

X.     m 
351.    m 

470.      — 

127,  129,  X. 

150. 

150. 

290. 

X. 

X,  X,  X,  X. 

307. 

307. 

129,  150. 


169,  233,  479. 
169,  233,  X. 
169,  286,  X,  X. 
156.  X. 


475, 
,  X,  X. 


479,   X.   X, 


479. 


409, 

150 

150 

150 

150 

139 

409 

156 

248 

156 

409 

479 

156 

409 

156 

156 

51, 

156, 

150, 

156, 

479, 

150, 

286 

329 


X. 

156,  409,  X,  X,  X,  X. 
409. 
.  X. 
409. 
X. 


X. 
,  X. 
,  X. 
■  X. 

,x. 


150.  479,  X. 
,  330,  X. 


,  X. 

,  479,  X. 


112 


UNITED  STATES  TARIFF  COMMISSION 


Table  13B. — Synthetic  organic  chemicals:  Flavor  and  perfume  materials  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  19^1-43 — Continued 


Material 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  13.j) 


FLAVOR  AND  PERFUME  MATERIALS, 
AC  YCLIC— Continued 

Decyl  acetate  (Cio) T . 

n-Decvl  alcohol  (Cio) 

*Decyl  aldehyde  (Cio) 

Diamyl  ketone 

Dibutylcarbinol 

Diethyl  succinate 

Dipropyl  ketone 

Dodecyl  acetate  (C12) 

*Dodecyl  aldehyde  (Cij) 

Dodecyl  formate  (Cij) 

'Ethyl  butyrate 

•Ethyl  caproate " 

*Ethyl  enanthate 

Ethyl  isovalerate 

Ethyl  laurate 

Ethyl  myristate 

•Ethyl  pelargonate 

Ethyl  sebacate 

Glutamic  acid,  sodium  salt 

Glyceryl  tributyrin 

Glyceryl  tricaprin 

Heptaldehyde  (C7) 

Heptaldehyde  diglyceryl  acetal 

2,3-n-Heptanedione  (Acetylvaleryl) 

n-Heptanol  (Enanthylol) 

n-Heptanyl  acetate  (Enanthyl  acetate) 

Heptyl  methyl  ketone 

Hexyl  methyl  ketone 

Hexadecyl  aldehyde  (Cu) 

2,3-n-HexanediQne  (Acetylbutyryl) 

Hexyl  methyl  ketone 

•Isoamyl  butyrate 

•Isoamyl  caproate 

•Isoamyl  formate 

•Isoamyl  isovalerate 

Isoamyl  propionate 

•Isobutyl  acetate 

Isobutyl  butyrate 

Isobutyl  caproate 

Isopropyl  caproate 

Isopropyl  pelargonate 

Lauryl  formate 

Methylheptenone 

Methylheptyl  acetaldehyde 

Methyl  noneoate 

•Methyl  nonylacetaldehyde 

Methyl  nonyl  ketone 

4-Methyl-2,3-pentanedione  (Acetyl  isobutyryl) 

Methyl  imdecylenate 

Myristyl  alcohol 

•Nonalactone 

Nonyl  acetate  (Cs) 

Nonyl  aldehyde  (C») 

1-OctadecanaI  (Cis) 

1-Octanol  (n-Capryl  alcohol) i 

Octvl  acetate 

•Octyl  aldehyde  (C«) 

Octyl  butyrate 

•Pelargonic  acid 

2,3-n-Pentanedione  (Acetylpropionyl) 

n-Propylacetal 

Propyl  propionate 

Tetradecyl  aldehyde  (Cm) 

n-Tridecyl  aldehyde  (C13) 

•Undecalactonc 

Undecyl  alcohol  (Cii) 

Undecylenic  alcohol 

Undecvlenic  aldehyde  (Cii) 

Other 

CHEMICALLY  MOD.IFIED  ESSENTIAL  OILS 

Citral  citron,  synthetic 

Citronella,  acetylated 

Citronella,  hydrogenated 

Citropene 

•Ethyl  oxy hydrate 

Isobergamone 

Lemon-grass  oil,  hydrogenated 

Peppermint  oil,  synthetic 

Shiu  oil  acetate 


156,  409,  479. 

409,  X. 

156,  473,  479. 

479. 

409. 

150,  409,  X. 

409. 

129,  156,  X,  X. 

156,  473,  479,  X,  X,  X. 

156. 

156,  165,  330,  350,  X,  X. 

156,  330,  X,  X. 

156,  330,  475,  X,  X,  X. 

156,  330,  X,  X. 

156,  237,  X. 

237,  X. 

70,  1.56,  X. 

156,  X. 

21,  181,  211. 

479.  X. 

479. 

156,  X,  X. 

156. 

150. 

207,  479. 

479. 

479. 

388,  X,  X. 

156. 

150. 

388,  X,  X. 

156,  165,  330,  350,  X,  X. 

156,  330,  X,  X. 

156,  330,  X,  X. 

165,  330,  X,  X. 

156,  165,  X,  X. 

156,  330,  X,  X. 

330,  X. 

156,  X. 

156. 

156. 

X. 

409,  X. 

479. 

X,  X. 

156,  409,  473,  479,  X,  X. 

156,  473,  479,  X,  X. 

X. 

473,  X,  X,  X. 

156,  X. 

156,  473,  X,  X. 

409,  479,  X. 

159.  409. 

409,  479.  X. 

156,  409,  473, 

479,  X. 

143,  156,  X. 

150. 

X. 

156. 

156,  X. 

479. 

473,  479,  X,  X,  X,  X,  X. 

77,  X. 

X. 

156,  473,  479,  X,  X. 

156. 


479. 

X. 

207. 

409. 

156,  269,  473.  X. 

366. 

207. 

330. 

X. 


479,  X,  X. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


113 


PLASTICS  MATERIALS 

Table  l-lM.—  Sj/ittlidic  organic  chemicals:  Plastics  materials  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1941-Jf.3 

[Plastics  materials  for  which  separate  statistics  are  given  in  table  14A  are  marked  below  with  an  asterisk 
(*) :  products  not  so  marked  do  not  appear  in  table  14A  because  the  reported  data  are  confidential  and 
may  not  be  published.  Manufacturers  are  identified  by  numbers  in  the  alphabetical  list  appearing  on 
p.  13o.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification 
number  with  the  designated  product.] 


Material 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


Plastics  Materials,  Cyclic 
Condensation  Resins,  Benzenoid 
*Alkyd  resins,  phthalic  anhydride: 

•For  molding  and  casting 

For  laminating 

*For  protective  coatings 


*For  adhesives 

♦For  textiles 

All  other,  unspecified 

•phenolic  resins: 

•Cresols  (cresylic  acid) -formaldehyde: 

For  molding  and  casting 

•For  laminating 


•For  protective  coatings. 


For  adhesives 

All  other,  unspecified . 

•Phenol-formaldehyde : 

•For  molding 


'For  casting. ... 
•For  laminating. 


•For  protective  coatings. 


•For  adhesives. 


All  other,  unspecified. 


Phenol-f ormaldehyde-abietic  acid : 

•For  protective  coatings 

*Xylenol-f  ormaldehyde : 

For  molding  and  casting 

For  laminating 

For  protective  coatings 

p-tert-Amylphenol : 

For  protective  coatings 

p-tert-Butylphenol : 

For  unspecified  use 

Diamylphenol-hexamethyleneamine: 

For  molding  and  casting 

Diphenylol-propane: 

For  protective  coatings 

Phenol-aniline-formaldehyde : 

For  molding  and  casting 

Phenol-furfural: 

For  molding  and  casting 

For  laminating 

p-Phenylphenol : 

For  protective  coatings 

Phenol-terpene  (rosin) : 

For  protective  coatings 

•Tar  acid  (mixed  phenolic)  resins: 
•Cresols-  and  xylenols-aldehyde: 

For  molding  and  casting 

For  laminating .    ■  • 

For  protective  coatings 

All  other,  unspecified 

•Phenol-  and  cresols-aldehyde : 

For  molding  and  casting 

•For  laminating 


•For  protective  coatings. 

For  adhesives 

All  other,  unspecified . . . 


12,  100,  179,  X,  X,  X,  X. 

179,  X,  X. 

4,  8,  16,  26,  65,  74,  76,  129,  151, 
157,  164,  179,  183,  184,  201,  218, 
221,  228,  230,  232,  266,  267,  311, 
327,  332,  341.  344,  364,  383.  388, 
445.  449.  450,  472,  504,  X,  X, 
X,  X,  X,  X,  X,  X,  X,  X,  X,  X, 
X,  X,  X,  X,  X,  X,  X,  X,  X,  X, 
X,  X,  X,  X,  X,  X,  X. 

16.  179.  201. 

12,  140.  179.  X,  X. 

X,  X,  X. 


86,  130,  179.  384,  X.  X,  X. 
86.  131,  152.  179,  251.  317,  343. 
X,  X,  X,  X.  X,  X,  X. 

130,  131,  383.  384,  427,  458,  X, 
X,  X.  X.  X.  X,  X. 

179.  251.  X,  X. 

86,  130,  X.  X.  X.  X. 

86,  100,  104.  130,  131.  179.  202. 

221.  276.  307.  384.  X,  X,  X,  X, 

X,  X.  X.  X. 
86,  130,  179,  226,  243,  280,  307, 

384.  X. 
16,86.  111,117.152.179.220,221, 

251,  307,  343.  383,  X,  X,  X,  X, 

X,  X. 
16,  130,  164,  184.  201.  202.  246, 

307,  332,  383,  388,  427,  450,  458, 

X,  X,  X,  X,  X,  X,  X,  X,  X.  X. 
86,  220,  251.  252.  307,  X,  X,  X, 

X,  X,  X. 
85,  86,  130.  131,  201.  202,  220,  252, 

307,  X.  X.  X.  X. 

164,  246,  X. 

Ill,  179,  X. 

111. 

179,  383,  X,  X. 

X. 

202,  383,  221. 
X. 

8,  129. 
179. 

131,  179,  221. 
221. 

383. 


X,  X. 


179,  X. 
131,  179,  X. 
131,  179,  X,  X. 
X. 

5,  86,  179,  X,  X,  X,  X. 

86.  111.  179.  271.  307.  384,  458. 

X.  X. 
179.  384.  X.  X.  X,  X.  X: 
307.  X. 
5.  152,  307.  388.  X. 


646064—46—8 


114 


UNITED  STATES  TARIFF  COMMISSION 


Table  14B. — Synthetic  organic  chemicals:  Plastics  materials  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  lO^l-JfS — Continued 


Material 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


Plastics  Materials,  Cyclic — Continued 
Condensation  Resins,  Benzenoid — Continued 
•Tar  acid  (mixed  phenolic)  resins — Continued 
Phenol-,  cresols-,  and  xylenols-aldehyde: 

For  laminating 

Cashew-nut  oil  resins: 

For  molding  and  casting 

For  laminating 

For  protective  coatings 

All  other,  unspecified 

Coumarone-indene-cresols : 

For  protective  coatings 

Petroleum  hydrocarbon  resins: 

For  molding  and  casting 

All  other,  unspecified 

Resorcinol : 

For  molding  and  casting 

For  adhesives 

All  other  tar  acid  (mixed  phenolic)  resins,  unspecified 

Aniline-formaldehyde : 

For  molding  and  casting 

p-Toluenesulf  onamide : 

For  unspecified  use 

Polymerization  Resins 
Coumarone-indene : 

For  molding  and  casting 

For  protective  coatings 

All  other,  unspecified , 

•Polystyrene: 

♦For  molding  and  casting 

For  protective  coatings , 

For  adhesives 

All  other,  unspecified 

Polystyrene-carbazole : 

For  molding  and  casting 

Polystyrene,  diolefin: 

For  molding  and  casting 

Polystyrene  indene: 

For  protective  coatings 

Polymerized  petroleum  polymer: 

For  protective  coatings 

All  other,  unspecified 

Vinyl-carbazole 

Plastics  Materials,  Acyclic^ 
Condensation  Resins,  Benzenoid 
•Alkyd:  _ 

•Abietic  acid  and  abietic  acid-maleic  acid: 

For  laminating 

For  protective  coatings 

All  other,  unspecified 

Adipic  acid: 

For  molding  and  casting 

For  protective  coatings 

Adipic  acid-maleic  acid: 

For  adhesives 

Azelaic  acid: 

For  molding  and  casting 

For  protective  coatings 

Citric  acid: 

For  molding  and  casting 

•Fumario  acid: 

For  molding  and  casting 

For  protective  coatings 

For  adhesives 

For  textiles 

•Maleic  anhydride: 

For  laminating 

For  molding  and  casting 

For  protective  coatings 

For  adhesives 

For  textiles 

All  other 

•Sebacic  acid: 

For  protective  coatings 

For  textiles 

'Includes  small  amounts  of  aUcyclic  and  heterocyclic  resins, 


X,  X. 

131,  221. 
221. 
221. 
221. 

317,  X. 

384. 
X. 

131. 

85. 

5.  95,  388. 

95. 

307. 


317.  X. 
45,  317,  X. 
45,  317,  X. 

86,  127,  307,  317,  X. 

408. 

86,  467. 

X. 


442. 

408. 

478. 
478. 
X. 


164. 

4,  8,  16,  76,  164,  184,  201,  230, 
246,  267,  332,  449.  450,  X,  X, 
X,  X,  X,  X,  X,  X. 

201. 

X. 

383,  X. 

179. 

X. 
X,  X. 

X. 

X. 

16,  179,  450,  X,  X. 

179. 

X. 

129. 

X. 

8,  16,  74,  76,  151,  188,  201,  228, 
230,  246,  266,  267,  332,  383.  388, 
449,  450,  X,  X,  X,  X,  X.  X,  X, 
X,  X.  X,  X,  X,  X,  X,  X,  X,  X,  X. 

179,  201. 

X. 

201. 

16,  230,  383.  449,  470,  X,  X. 

5,  230,  X. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


115 


Table  14B. — Synthetic  organic  chemicals:  Plastics  materials  for  which   United  States 
production  or  sales  iccre  reported,  identified  by  manufacturer,  1941— JfS — Continued 


Material 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


Plastics  Materials  A  cyclic ' — Continued 
Condensation  Resins,  Benzenoid — Continued 
Succinic  acid: 

For  protective  coatings 

Miscellaneous,  unspecified: 

,  For  protective  coatings 

For  laminating 

Organic  nitrogen  resins: 
*Urea-f  ormaldehyde : 

*For  molding  and  casting 

*For  laminating 

♦For  protective  coatings 

*For  adhesives 

For  textiles 

*A11  other,  unspecified 

Guanidine-f  ormaldehyde : 

For  adhesives 

Melamine-f  ormaldehyde : 

For  molding  and  casting 

For  laminating 

For  protective  coatings 

For  adhesives 

All  other,  unspecified , 

Melamine-^urea-f  ormaldehyde : 

For  laminating 

For  adhesives 

Miscellaneous: 

For  adhesives 

All  other,  unspecified 

Polymerization  Resins 

•Alcohol  (allyl  or  furfuryl),  aldehyde,  and  ether  resins: 
Allyl  alcohol  resins: 

For  molding  and  casting 

For  laminating 

Furfural  resins: 

For  molding  and  casting 

For  laminating 

For  protective  coatings 

For  adhesives 

Miscellaneous,  unspecified 

Ethyl  cellulose: 

For  unspecified  use 

Methyl  cellulose: 

For  unspecified  use 

Polyvinyl  resins: 
'Polyvinyl  alcohol— aldehyde  resins: 
Polyvinyl  acetal: 

For  adhesives 

Polyvinyl  acetal  and  polyvinyl  butyral: 

For  molding  and  casting 

•For  laminating 

For  protective  coatings 

All  other,  unspecified 

Polyvinyl  butyral : 

For  laminating 

For  protective  coatings 

For  adhesives 

For  textiles 

All  other 

Polyvinyl  formal: 

For  molding  and  casting 

For  protective  coatings 

For  adhesives 

•Polyvinyl  alcohol,  ester,  and  halide  resins: 
Polyvinyl  alcohol: 

For  molding  and  casting 

For  adhesives 

For  textiles 

All  other 

Polyvinyl  acetate: 

For  laminating 

For  protective  coatings 

For  adhesives 

All  other,  unspecified 

Polyvinyl  acetate-chloride: 

For  molding  and  casting 

For  laminating. 

For  protective  coatings 

For  textiles 

All  other,  unspecified 


16,  383,  X. 


5,  X. 

281. 


16,  179,  221,  X,  X. 

16,  179,  252,  388,  X,  X,  X. 

16,  129,  383,  388,  X.  X. 

16,  85,  252,  X,  X,  X,  X,  X. 

276,  388,  394. 

16, 85, 252,  276, 388,  394,  X,  X,  X. 

X. 

16,  307,  X. 
86.  X. 
388,  X. 
X. 
X. 

86. 
X. 

467. 
X. 


X. 

281,  X. 

5,  221. 
221. 
127. 
X. 
5,  221. 

127,  221. 

127 


77,  X. 

77,  X. 
77,  129,  X. 
77,  X. 
77,  129,  X. 

77,  129,  X. 
X. 

129,  X. 
77,  129. 
129. 

X. 
X. 
X. 


129. 
129. 
129. 
129.x. 

77. 

76,  77,  X,  X. 
129.  X. 

129.  221.  X.  X. 

77. 

77.  127. 
77,  221. 
77. 

77,  186,  221. 


116 


UNITED  STATES  TARIFF  COMMISSION 


Table  14B. — Synthetic  organic  chemicals:  Plastics   materials  for  which   United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  19il-43 — Continued 


Material 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  1.3") 


Plastics  Materials,  Acyclic  i — Continued 
Polymerization  Resins — Continued 
Polyvinyl  resins — Continued 
•Polyvinyl  alcohol,  ester,  and  halide  resins — Continued 
Polyvinyl  chloride: 

For  molding  and  casting 

For  laminating 

For  textiles 

All  other 

Polyvinyl  chloride-poly vinylidene  chloride: 

For  molding  and  casting 

For  laminating 

All  other 

Polyvinyl  ethers: 

For  adhesives 

Polyacrylate  and  methacrylate  resins : 

For  molding  and  casting 

For  laminating 

For  protective  coatings 

For  textiles 

All  other 

Polyamide  (adipamide) 

Polyolefin  (polyethylene) : 

For  molding  and  casting 

All  other,  unspecified 

Polymerized  petroleum  resins: 

For  molding  and  casting 

For  laminating 

For  protective  coatings 

All  other 

Polyterpene  resins: 

For  molding  and  casting 

For  laminating .  •  •  ■ 

For  protective  coatings 

All  other,  unspecified 

Miscellaneous  polymerization  resins: 

For  protective  coatings 

For  textiles 

All  other,  unspecified 

1  Includes  small  amounts  of  alicyclic  and  heterocyclic  resins 


77. 
127. 
77. 
186. 

127. 
127. 
X. 

X. 

129,  394. 
394. 

388,'  394. 
129,  394. 
129,  394. 
129. 

77. 
129. 

440. 
376. 
376,  X. 
376,  X. 

X. 

317. 

X. 

207,221,  X,  X. 

77,  246,  383,  442. 

129. 

129,  179. 


RUBBER  CHEMICALS 

Table    15B. — Synthetic  organic  chemicals:  Rubber  chemicals  for   which   United  States 
production  or  sales  icere  reported,  identified  by  manufacturer,  19Jf.l—]tS 

[Rubber  chemicals  for  which  separate  statistics  are  given  in  table  1.5A  are  marked  below  with  an  asterisk 
(*) ;  chemicals  not  so  marked  do  not  appear  in  table  15A  because  the  reported  data  are  confidential  and 
may  not  be  published.  Manufacturers  are  identified  by  numbers  in  the  alphabetical  list  appearing  on 
p.  135.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification 
number  with  the  designated  product.] 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


RUBBER  CHEMICALS,  CYCLIC 
•Accelerators: 

•Aldehyde-amines; 

*  Acetaldohyde-aniline 

*n-Butyraldehyde-aniline 

Crotonylidine-aniline 

a-Ethyl-|3-propylacrolein-aniline 

Heptaidehyde-aniline 

Methylene-aniline  (Anhydroformaldehyde-aniline) 

Methylene-p-toluidine 

Urea-butyraldehyde-aniline 

•Dithiocarbamates: 

Carbon  disulfide-methylenedimethylcyclohexylamine 

Carbon  disulfide-methylenedipiperidine 

Bcnzal  dimethyldithiocarbamate 

Dibenzyldithiocarbamic  acid,  dibenzylaniine  salt 

Dimethylcthylene  fiiphenyl  dithiocarbamic  acid,  lead  salt. .  .  . 

Dimethylethylene  diphenyl  dithiocarbamic  acid,  zinc  salt.  .  .  . 

2,  4-Dinitrophenyl  (liiiictliyl  (lithiocarhaiiiate 

Diphenylcarbamyl  dimethyl  dithiocarbamate 

l-Methylene-0-naphthyl  dimethyl  dithiocarbamate 

Piperidine  pentamethylene  dithiocarbamate 

Piperidine  pentamethylene  dithiocarbamic  acid,  potassium  salt 

Trie  (diphenylcarbamylmethyl)  amine 


129,  .307,  X. 

129,  186,  307,  X. 

X. 

91. 

X. 

129,  307. 

129. 

X. 

307. 

307. 

X. 

X. 

91. 

91. 

X. 

X. 

X. 

X. 

129,  X. 

186. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


117 


Table  loB. — Synthetic  organic  chemicals:   Rubber   chemicals  for  which   United  States 
production  or  sales  icere  reported,  identified  by  manufacturer,  19^1-43 — Continued 


Chemical 


RUBBER  CHEMICALS,  CYCLIC— Continued 

'Arpelerators^— Continued 
*Guanidine  derivatives: 

*Diphenylguanidine 

Diphenylguanidine  oxalate 

Diphenylguanidine  phtiialate 

Di-o-tolylguanidine '. 

Di-o-tolylguanidine  zinc  chloride 

Triphenylguanidine 

'Guanidine  mixtures: 

Diphenylguanidine  acetate  and  2-(2,4-dinitrophenyhnercapto) 
benzotliiazole. 

Diphenylguanidine     acetate,     diphenylguanidine     phthalate, 
and  2,2'dithiobenzothiazole. 

Diphenylguanidine       and       2-(2,4-dinitrodiphenylniercapto) 
benzothiazole. 

Diphenylguanidine,  diphenylguanidine  phthalate,  and  2-(2,4- 
dinitrophenylmercapto)thiazole. 

Diphenylguanidine  and  di-o-tolylguanidine 

Diphenylguanidine    phthalate,    dibenzothiazyldimethylthiol- 
urea,  and  anhydroformaldehyde  aniline. 

Diphenylguanidine,     zinc     chloride,    and    2-mercaptobenzo- 
thiazole. 
Thiazole  derivatives: 

Alkylated     2,2'-dithiobisthiazole     (Alkylated     2-thiazyI     di- 
sulfide). 

.\lkyl  2-mercaptothiazole 

Aminobenzothiazole 

2- (2-Aminoethylmercapto) benzothiazole  (Benzothiazyl-2-sul- 
phenethylamide) . 

Benzothiazole 

Benzothiazyl  ethyl  chlorbcarbonate 

Bis-N,N'-(2-benzothiazylthiomethyl)urea 

2-(2,4-Dinitrophenylmercapto)  benzothiazole 

2,2'-Dithiobisbenzothiazole  (Benzothiazyl  disulfide) 

2-Mercaptobenzothiazole 

2-Mercaptobenzothiazole   benzoate    (Benzothiazole   thioben- 
zoate). 

2-Mercaptobenzothiazole,  benzylhexamethylenetetramine  salt. 

2-Mercaptobenzothiazole,   cyclohexylamine  salt 

2-Mercaptobenzothiazole,  lead  salt 

2-Mercaptobenzothiazole,  sodium  salt 

2-Mercaptobenzothiazole,  zinc  salt 

2-Mercaptobenzothiazolemethylene  aniline 

2-MercaptobenzothiazoIemethylene-o-toluidine 

2-Mercaptothiazoline 

Methylenemercaptobenzothiazole 

Phenylmercaptobenzothiazole 

Reaction    product,    mercaptobenzothiazoleforriialdehyde-cre- 
sylic  acid-hexaniethylenetetramine. 
Miscellaneous: 

Chloronaphthaxanthate 

p,  p'-Diaminodiphenylmethane 

Dibenzylamine 

Di-N-pentamethy!enethiuramtetrasulfide 

Di-o-tolylthiourea  (Thiocarbtoluide) 

p-Quinonedioxime 

*Thiocarbanilide  (Diphenylthiourea) 

'-Antioxidants: 

Aldehyde  and  acetone  amines: 

Aniline-acetone 

Aniline-acetone,  acid  derivatives 

p^Aminodiphenyl-acetone 

Butyraldehyde-aniline 

Crotonylidine-a-naphthylaniine 

Diphenylamine-acetone 

Diphenylamine-acetone  formaldehyde 

Diphenyl-p-phenylenediamine  and  p-aminodiphenyl  acetone. 

Diphenyl-p-phenylenediamine  and  aniline  acetone,  acid  de- 
rivatives. 

Phenyl-/3-naphthylamine-acetone . .  -. 

'Phenols  or  primary  amines: 

2,4-Diaminodiphenylamine 

p, p'-Diaminodiphenylmethane 

^-Di-p-hydroxyphenylpropane 

Hydroquinone,  monobenzyl  ether 

p-Hydroxydiphenylamine 

Hydroxyphenylmqrpholine 

Methylene  di-^-naphthol 

(3-Xaphthol,  aniline  salt 

/3-Naphthol,  p-phenylenediamine  salt 

/3-Xaphthol,  polyethylenepolyamine  salt 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


16,  127,  129,  307. 

X. 

307,  X. 

129,  X. 

X. 

313. 

307. 

307. 

307.      • 

307. 

X. 

307. 


186. 

186. 
186. 
X. 

307. 

X. 

307.- 

307. 

307,  X,  X,  X. 

307,  X,  X,  X. 

307. 

129. 

307. 

129. 

307,  X. 

129,  X,  X,  X. 

X. 

X. 

129. 

307. 

307. 

X. 


307. 

X. 

X. 

129. 

129,  313. 
X. 

16,  129,  307,  313. 


307. 

307. 

307. 

129. 

186. 

X. 

X. 

129,  307. 

307. 

X. 

307. 

X. 

127,  X. 

186. 

129,  186. 

129. 

X. 

129. 

186. 

X. 


118 


UNITED  STATES  TARIFF  COMMISSION 


Tablk  loB. — Synthetic  organic  chemicals:   Rubber   chemicals  for   vkich    United  States 
production  or  sales  %cere  reported,  identified  by  manufacturer,  IGlfl-^S — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


RUBBER  CHEMICALS,  CYCLIC— Continued 
•Antioxidants — Continued 
Secondary  amines: 

Alicylated  diphenylamine 

Dimethoxydiphenylamine 

Diphenyletliylenediamine 

*Diphenyl-p-phenylenediamine 

Ditolylamines 

Di-o-tolylethylenedianiine 

Isopropoxydiphenylamine 

p-Methyl-p-tolylsulf  onamidodiphenylamine 

Phenyl-a-naphthylamine 

Phenyl-/3-naphthylamine 

ThiopIienyl-/3-naphtliylamine 

p-(p-Toluenesulfonamido)diphcnylaniine . 

Miscellaneous: 

Dicatechol  borate,  di-o-tolylguanidine  salt 

Cashew  oil  polymers 

Phenol-cyclohexanone 

Phenyl-/3-naphthylnitrosamine 

Tetrahydroglyoxaline  sodium  acetate  mixture 

2',2',4-TrimethyldihydroquinoHne  polymers 


RUBBER  CHEMICALS,  ACYCLIC 
Accelerators: 
*Aldehyde-amines : 

Aldehyde-ammonia 

Butyraldehyde-butylamine 

Butyraldoxime •  •  •  ■ 

Triethyltrimethylenetriamine  (Formaldehyde  aniUnc) 

*Dithiocarbamates : 

Dibutyldithiocarbamic  acid,  zinc  salt 

Diethyldithiocarbamic  acjd,  diethylamine  salt 

Diethyldithiocarbamic  acid,  sodium  salt 

•Diethyldithiocarbamic  acid,  zinc  salt 

Dimethyldithiocarbamic  acid,  amylamine  zinc  salt 

Dimethyldithiocarbamic  acid,  dimethylamine  zinc  salt 

Dimethyldithiocarbamic  acid,  lead  salt 

Dimethyldithiocarlsamic  acid,  zinc  salt 

Dithiocarbamic  acid,  hexamethylenetetramine  salt 

Tetrabis(diethyldithiocarbamyl)selenium    (Selenium    diethyl- 
dithiocarbamate) . 

Tetrabis(diethyldithiocarbamyl)tellurium 

Thiuram  derivatives: 

Tetra-amylthiuram  monosulfide 

Tetrabutylthiuram  monosulfide 

Tetraethylthiuram  disulfide 

'    *Tetramothylthiuram  sulfide  and  disulfide 

Xanthates: 

Di-n-butyl  xanthodisulfide 

Di-isopropyl  xanthodisulfide 

Potassium  amy]  xanthate 

Potassium  butyl  xanthate 

Potassium  ethyl  xanthate 

Potassium  isopropyl  xanthate 

Potassium  pentasol  xanthate 

Sodium  butyl  xanthate 

Sodium  ethyl  xanthate .". 

Sodium  isopropyl  xanthate 

Zinc  butyl  xanthate 

Miscellaneous: 

Dioctyl  disulfide 

Dodecyl  mercaptan 

Fatty  acid  amides,  mixed 

Keryl  mercaptan 

Organic  mercaptans 


186. 

129. 

91. 

129,  186,  X. 

186. 

91. 

186. 

X. 

129,  313. 

129,  176,  1S6,  X. 

X. 

X. 

129. 
X. 
307. 
X. 

91. 

186. 


129,  307. 
129. 
313. 
X. 


506,  X. 

X. 

506. 

413,  506,  X,  X. 

X. 

307. 

506. 

307,  413,  X,  X. 

129. 

413,  506. 

506. 

X. 
X. 

129,  307,  413,  .506. 
129,  307,  413,  X,  X. 

X. 

186. 

127,  307. 
16,  127,  307. 
127,  307. 
127,  X. 
127. 
X,  X. 
127,  X. 
X. 

x,x. 

X. 

207,  307.  X. 

195. 

313. 

207. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


119 


ELASTOMERS 

Table  16B. — Synthetic  organic  chemicals:  Elastomers  (synthetic  rubbers)  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1941-43 

[Elastomers  (synthetic  rubbers)  for  which  separate  statistics  are  given  in  table  16A  are  marke d  below  with 
an  asterisk  (*);  products  not  so  marked  do  not  appear  in  table  16A  because  the  reported  data  are 
confidential  and  may  not  be  published.  Manufacturers  are  identified  by  numbers  in  the  alphabetical 
list  appearing  on  p.  135.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his 
identification  number  with  the  designated  product.] 


Product 

Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 

ELASTOMERS,  CYCLIC 
•Polybutadiene-styrene  (GR-S) 

122,  127,  202,  212,  443,  513,  515, 

ELASTOxMERS,  ACYCLIC 
Polyalkylene-sulfide  (Thiokol  type) 

516.   517,    518,  522,    526,  527, 
X,  X. 

514. 

•Polyalkvlene-sulfide  (Thiokol  FA) 

127. 

'Polybutadiene— acrylonitrile  (GR-A  type) 

127,  160,  202,  212,  443,  X. 

127. 

•Polychloroprene  (Neoprene) 

129,  514. 
77. 

524,  X. 

•Polyisobutylene-isoprene  (Butyl  type) 

Polymerized  rubber  chloride 

524. 
201. 
X. 

129. 

•Polyvinyl  alcohol-butyraldehyde  elastomers 

77,  129,  307. 
129. 

Polyvinyl  chloride-acetate  elastomers 

77,  X. 

MISCELLANEOUS  CHEMICALS 

Table  17B. — Synthetic   organic   chemicals:    Miscellaneous   chemicals  for  ivhich   United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  19^1— 43 

[Miscellaneous  chemicals  for  which  separate  statistics  are  given  in  table  17A  are  marked  below  with  an 
asterisk  (*) ;  chemicals  not  so  marked  do  not  appear  in  table  17A  because  the  reported  data  are  confi- 
dential and  may  not  be  published.  Manufacturers  are  identified  by  numbers  in  the  alphabetical  list 
appearing  on  p.  135.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  iden- 
tification number  with  the  designated  product.] 


Chemical 


MISCELLANEOUS  CHEMICALS,  CYCLIC 

Abietic  acid  esters 

p-Acetamidophenol 

2-Aminobenzothiazole 

tert-Amylphenol  sulfide 

Benzoic  acid  salts: 

Ammonium  benzoate 

*Sodium  benzoate 

a-Benzoin  oxime 

Benzoyl  peroxide 

Benzylated  phenol  (Santophen) 

'Biological  stains 

Bis-tert-amylphenol  sulfide 

Bis-tert-amylphenol  sulfide,  calcium  salt 

Bis-iso-octylphenol  sulfide,  barium  salt 

Bis-tetramethylbutylhydroxyphenyl  sulfide 

n-Butylcatechol 

p-tert-Butylcatechol 

3-(tert)-Butyl-p-cymene 

Camphocarboxylic  acid 

Camphor-lO-sulfonic  acid 

Caprolactam 

p-Carboxybenzenesulfondichloramide  (Halozone) 

Chemical  indicators: 

o-Cresolphthalein ; 

o-Cresolsulfonphthalein  (Cresol  red) 

m-Cresolsulfonphthalein  (m-Cresol  purple) 

*Dibromo-o-cresolsulfonphthalein  (Bromocresol  purple) 

♦Dibromothymolsulfonphthalein  (Bromothymol  blue) 

Dichlorophenolsulfonphthalein  (Chlorophenol  red) 

•Phenolsulfonphthalein  (Phenol  red) 

Tetrabromo-m-cresolsulfonphthalein    (Bromocresol   green) . 

Tetrabromophenolsulfonphthalein   (Bromophenol   blue) .... 

Thymolphthalein 

Thymolsulfonphthalein  (Thymol  blue) 

All  other,  unspecified 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


307,  460. 


1.36,  199,  250,  313,  348,  X,  X. 


201. 
139. 
139. 
413. 

207,  307. 

83,91,  127,  129,203,207 

136,  150,  159. 

268. 

307. 

101, 

443. 

443. 

X. 

443. 

307. 

127. 

X. 

1. 

1. 

129. 

307. 

4.53. 

136,  250,  453. 

136,  250,  453. 

136,  250,  348,  453. 

136,  250,  348,  453. 

453. 

136!  213,  250,  348,  453. 

136,  250,  453. 

136,  348,  4.53. 

136,  159,250,453. 

136,  250,  453. 

250,  X. 


120 


UNITED  STATES  TARIFF  COMMISSION 


Table  17B. —  Synthetic  organic  cheviicah:    Miscellajieous   chemicals  for  which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1941-43 — Continued 


Chemical 


MISCELLANEOUS  CHEMICALS,  CYCLIC— Continued 

Clieiiiical  reagents: 

p-Aniinodiphenylaniine  diazosulfate 

Aurintricarboxylic  acid 

l-Diazo-2-naphthol-4-sulfonic  acid 

2,6-Dibromoquinone  chloroiniidc 

Diphenylthiocarbazone  (Dithizone) 

a,a'-Dipyridyl  (2,2'-Bipyndine) 

N-(l-Naphthyl)-ethylenedianiine  ilihydrochioridc 

Nitranilic  acid 

Nitrosophenylhydroxylamine  (Cupferron) 

Potassium  biphthalate  reagent 

Quinhydrone 

Sodium-2,6-dichIorobenzenoneindophonol 

Sulfosalicylic  acid ^ 

*Cyclohexanol ' 

Cyclohexanone 

Cyclohexyl  phosphite 

Cyclonol 

♦Cyclopropane 

Decahydronaphthalene  (Decalin) 

Diamylhydroquinone 

Dibenzyl  disulfide 

Dichlorobenzyl  disulfide 

Diethylaminohydroquinone 

Diethylene  oxide  (Dioxan) 

2,2'-Dihydroxy-5,.5'-dichlorodiphenylmethano 

2,2'-Dihydroxy-3,5,6,3'5'6'-hexachlorodiphcnylmethane 

2,4-Di-(p-hydroxyphenyl)-3-ethylhexane 

Di-isopropylbenzenesulfonic  acid 

6,12-Dimethylceroxenyl  acetate 

Diphenylethane  polymer 

Diphenylthiocarbazone  (Dithizone) 

Ergosterol,  crystalline 

Ethyl  benzoylacetate 

Ethyleneglycol  monosalicylate 

Furan  derivatives: 

Furfural 

Furf uryl  acetate 

Furfuryl  alcohol 

Furf  uryl  mercaptan 

Nitrofurfuryl  propionate 

•Gallic  acid,  tech 

Gases  (poisonous,  tear,  etc.) : 

Bromobenzyl  cyanide  (Bromo-o-tolunitrilc) 

Chloroacetophenone ; .  . 

Diphenylchlorarsine 

Diphenylaminechlorarsine 

Diphenylcyanarsine 

Phenyldichlorarsine 

•Gasoline  antioxidants  and  inhibitors 

Glycol  terpenyl  ether 

Guanine 

•Insecticides,  synthetic: 

Benzyl  thiocyanate 

4,4'-Dichlorodiphenyl-l,l,l-trichlorocthane   (DDT) 

2,4-Dinitroanisole 

4,6-Dinitro-o-cresol 

4,6-Dinitro-o-cresol,  sodium  salt 

Laurie  acid  ester  of  colaminoformylmethylpyridinium  chloride 

Phenothiazine 

Xanthone 

All  others,  unspecified 

Luric  acid 

p-Menthane 

Menthyl  carbinol 

Methylcyclohexane 

•Methylcyclohexanol  (Methyl  hexalin) 

Methylcyclohexanone 

4-Methyl-5-(b-hydroxycthyl)-thiazole 

Morpholine 

Naphthalene  and  chlorinated  paraffin  condensation  product 

Phenyl  ether  (Diphenyl  oxide) 

Octylphenol 

Phenyl  mercuric  derivatives: 

Phenyl  mercuric  acetate 

Phenyl  mercuric  borate 

Phenyl  mercuric  chloride 

Phenyl  mercuric  hydroxide 

Phenyl  mercuric  nitrate 

Phenyl  mercuric  phosphate 

All  others,  unspecified 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


139. 

453. 

10,  1.39. 

136,  139. 

1.36,  159. 

136,  150. 

1.36. 

1.39. 

136. 

294. 

83,  136,  294. 

136. 

1.36,  159,  294. 

45,  129,  207. 

45,  129. 

45. 

129. 

278!  335,  432,  X. 

129. 

307. 

207. 

207. 

207. 

77. 

77. 

X. 

X. 

37. 

498. 

X. 

1.36,  159. 

.308,  436. 

470. 

X. 

.380. 

X. 

207,  .380. 

139. 

136. 

136,278,  511. 

51,  247. 

1.39.  154,247,  351. 

247,  X. 

154,  204,  247,  351. 

247. 

247. 

129,  210,  X. 

201. 

292. 

207. 

95,  129. 

480,  X. 

313,  434. 

434. 

145. 

127,  129. 

127,  178. 

254,  394,  X. 

137. 

319. 

319. 

45,  X. 

45,  129,  207. 

45,  129. 

294. 

77. 

441,  X. 

127,  245,  X. 

388,  X. 

52,  192. 
52. 

52,  192. 
52,  192. 
52,  139. 
52. 
52. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


121 


Table  17B. — Hynthetic  organic  chemicals:    Miscellaneous  chemicals  for  which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  19Jtl-J^3 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


MISCELLANEOUS  CHEMICALS,  CYCLIC— Continued 

Phenylsemicarbazide  and  salts 

Phenylphosplioric  acid,  disodiuni  salt 

Phloroglucinol 

•Photographic  chemicals: 

p-Aniinophenol  hydrochloride 

p-Aniinophenol  oxalate 

p-Aminophenol  sulfate 

•Benzotriazole 

Catechol  (Pyrocatechin) 

Chlorobenzotriazole 

Chlorohydroquinone ■.  .  .  . 

p-Chloro-o-phenylenediamine 

2,4-Dianiinophenol  dihydrochloride  (Amidol) 

*Hydroquinone  (Hydroquinol) 

'p-IIydroxyphenylglycine 

*p-Methylaniinophenol  sulfate 

Methylbenzoxazole 

Phthalide 

Plant  hormones: 

Indole-3-acetic  acid,  crystals 

a-Indole-3-n-butyric  acid 

N'aphthaleneacetic  acid  (Parmone) 

•Plasticizers: 

Camphor,  synthetic 

Castor  oil  phthalate 

^-Chloro-^'-(2-xenoxy)-diethyl  ether 

Coumarone-indene  plasticizer 

o-Cresyl-p-toluenesulfonate 

Cyclohexyl-p-toluenesulfonaniide 

Diallyl  phthalate 

Diallyl  succinate 

*Di-n-amyl  phthalate 

Di-(butylcellosolve)  phthalate  [Di-(butoxyethyl)  phthalate] 
*Dibutyl  phthalate 


Di-(p-teit-butylphenyl)  mono-(.5-tei  t-butyl-2-xcnyl)  phos- 
phate. 

Di-(p-tert-butylphenyl)  monophenyl  phosphate 

Dicapryl  phthalate 

Dicarbitol  phthalate  [Bis-(diethylene  glycol  monoethyl  ether) 
phthalate]. 

Dicellosolve  phthalate  (Diethoxyethyl  ]>hthaIato) 

Dicresyl  dithiophosphate,  sodium  salt ■ 

Dicyclohf.xyl  i.lithalate 

Diethylbutoxycthyl  phthalate 

Diet  liyleni'gly col  dibenzoate 

I)i-2-ethylhexyl  phthalate 

*  1  )i('t  hy  1  phthalate '. 


Dimethylcarbitol    phthalate    [Bis-(diethylene    glycol    mono 

methyl  ether)  phthalate]. 
Dimetlnlcollosolve  phthalate  [Di-(methoxyethyl)  ijhthalate] 

Di-(methvlcv(lnlipxyl)  phthalate 

♦Dimethyl  phthalate 


Di-n-octyl  phthalate 

Diphenyl  mono-o-xenyl  phosphate 

Diphenyl  phthalate 

Di-o-xenyl  monophenyl  phosphate 

Ethyl  o-benzoylbenzoate 

N-Ethyltoluenesulfonamide,  o,  p  mixture. 

CJlyceryl  tris  (monobutyl  phthalate) 

Glycolic  acid  phthalate  alkyl  esters 

Ilydrogi-nated  castor  oil  phthalates 

MorplidhiK'  stearate 

PhciKjlir  coumarone-indene  plasticizer. . . . 

Sodium  butyl  phthalate 

Sodium  ethyl  butyl  phthalate 

Tetrahydiof urf uryl  oleate 

Tetra-wax  phenyl  phthalate 

Toluenesulfonamide,  o,  p  mixture 

Tri-(p-tert-amylphcnyl)  phosphate 

Tri-(i>-tert-butylphenyl)  phosphate 

•Tricresyl  phosphate 

Triphenyl  phosphate 

All  others,  unspecified 

Polyglycerol-abietic  acid  compound 

Potassium  acid  urate 

Propenylpyrocatechol  butoxymethyl  ether.  .  .  . 


139. 
348. 
139. 

136. 

139. 

139. 

136, 

136, 

150, 

139, 

150 

36. 

83, 

129, 

129 

150 

129 


139,  1.30. 
139,  307,  351. 


511. 


136,  480. 

129,  136,480,  511,  X. 

,  136,  139,  X. 

,  136,  480,  511,  X. 


294. 
294. 
127i  178,  X. 

129,  319,  X. 

129. 

127. 

317. 

307. 

307. 

X. 

139 

45,  129,  470,  X. 

129   3.34. 

16, '45,   106,   129,  204,  2.33,  237, 

307,  317,  .334,  470,  475,  X,  X, 

X,  X. 
127. 


127. 

45,  388,  X,  X. 

X. 

334. 
X. 

45,  129. 

334. 

X. 

77,  334. 

16,  106,  129,  233,  307,  470,  X,  X, 

X. 
.334. 

129,  334. 

129. 

16,  129,  168,  233,  307,  329,  475, 

498,  X,  X,  X,  X. 
207. 
127. 
307. 
127. 
X. 
307. 
X. 
307. 

129,  207. 
195. 
317. 
129. 
129. 
207. 
307. 
307. 
307. 
127. 

.307,  .308,  .3.34,  X,  X. 
127,  307,  X. 
3.34. 
307. 

1.39,  355,' X. 
X. 


122 


UNITED  STATES  TAMFF  COMMISSION 


Table  17B.— Synthetic  organic  chemicals:  Miscellaneous  chemicals  for  which   United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1941—^3 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


MISCELLANEOUS  CHEMICALS,  CYCLIC— Continued 


Propylcyclohexanol 

*PyrogalIol  (Pyrogallic  acid) 

Quinhydrone 

Quinoidine,  sulf urized 

Quinone • 

Research  chemicals 

Salicylanilide  (Shirlan) 

Sulfonated  tliiocarbaniUde  acetaldehyde  ammonia  compounds. 
Surface-active  agents: 

'Quaternary  ammonium  compounds: 

Benzyl  phenyl  ammonium  chloride 

Cetyl  dimethyl  benzyl  ammonium  chloride 

Cetyl  pyridinium  chloride 

Lauryl  dimethyl  benzyl  ammonium  chloride 

Lauryl  pyridinium  chloride 

Stearoxymethyl  pyridinium  chloride 

Trimethyl  benzyl  ammonium  chloride 

All  other 

•Sulfonated  alkyl  aryl  compounds: 

Sulfonated  alkyl  benzene  and  salts 

Sulfonated  alkyl  diphenyl  and  salts 

•Sulfonated  alkyl  naphthalene  and  salts: 

Amylnaphthalencsulfonic  acid,  sodium  salt 

Butylnaphthalenesulfonic  acid,  sodium  salt 

Dilaurylnaphthalenesulfonic  acid,  sodium  salt. .  . 
Isopropylnaphthalenesulfonic  acid,  sodium  salt. . 

All  others,  unspecified 

Sulfonated  alkyl  naphthyl  ethers,  and  salts 

Sulfonated  alkyl  phenyl  ethers,  and  salts 

All  others,  unspecified 

Sulfonated  naphthenic  compounds  and  salts: 

Sulfonated  naphthenic  acid,  aluminum  salt 

Sulfonated  naphthenic  acid,  calcium  salt 

Sulfonated  naphthenic  acid,  sodium  salt 

•Tanning  materials,  synthetic 


Tetrahydroglyoxaline 

Tetrahydronaphthalene  (Tetralin) 

•Textile  chemicals,  other  than  surface-active  agents: 

Derived  from  anthracene 

Derived  from  biphenyl 

Derived  from  benzene 

•Derived  from  naphthalene .  . 

Derived  from  pyridine '.  .  . 

Derived  from  tar  acids 

All  others,  unspecified 

Thiophene  (Thiofuran) 

Tin  sulfurized  tri  wax  phenolate 

o-Tolylbiguanide 

Triamyl phenyl  phosphite 

Tricresyl  phosphite 

Triphenyl  phosphite 

Uric  acid 

Veratyl  aldehyde  bisulfite  compound 

Waxes,  synthetic 

o-Xenylbiguanide 

All  others,  unspecified 


MISCELLANEOUS  CHEMICALS,  ACYCLIC 


•Acetaldehyde 

Acetamide 

•Acetic  acid: 

•Synthetic  (100%) 

•Recovered  (100%) 

Acetic  acid  salts: 

•Aluminum  acetate 

Copper  acetate 

Manganese  acetate 

P«tassium  acetate 

•Sodium  acetate 

•Acetic  anhydride: 

From  acetylene  (100%) 

From  ethylene  (100%) 

From  ketene  (100%) 

From  recovered  acetic  acid  by  the  vapor  phase  process  (100%) . 
From  acetic  acid  (other  than  recovered)  by  the  vapor  phase 
process  (100%). 
•Acetone 


207. 

136,  278,  511. 

136,  294. 

129. 

136,  511. 

68,  136,  139,  159,  292,  396. 

129,  X. 

307. 


507. 

254,  394. 
139,  295. 
389. 
207. 
489. 
106. 
159. 

37,  307,  313. 
307. 

309,  314,  389,  507. 

176. 

314. 

16,  28,  176,  313,  507. 

309,  437.  X. 

89. 

254,  394. 

37,  313. 

441. 

468. 

441,  468. 

16,  28,  45,  95,  119,  129,  176,  254, 

307,  313,  394,  507,  X. 
91. 
129. 

437. 

307. 

28,  307,  313,  507. 

28,  129,  176,  309,  313,  437,  507. 

28,  129. 

28,  313. 

89,  176,  X- 

1.36. 

307. 

307. 

307. 

X,  X. 

307. 

139. 

X. 

307. 

307. 

176,  306,  X,  X. 


96,  129,  323,  374,  X,  X,  X. 
323. 

77,  106,  129,  323,  374,  470,  X,  X. 
129,  268,  294,  307,  460,  X,  X,  X, 

X,  X,  X,  X,  X. 
129,  294,  323. 
323. 
323. 
323 
91,  'l27,  129,  204,  278,  294,  307, 

323,  X. 
129. 
77. 
77. 
X,  X. 

X,  X. 

35,   77,   106,  374,  416,  435,   470, 
X,  X. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


123 


Table  17B. — Synthetic  organic  chemicals:   Miscellaneous    chemicals  for   ivhich    United 
States  production  or  sales  icere  reported,  identified  by  manufacturer,  191^1— It3 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

Acetonitrile 

Acetonylacetone 

Aeetylacetone  (2,4-Pentanedione) 

•Acetyl  chloride 

Aconitic  acid 

•Acrylonitrile 

Adipic  acid 

Adiponitrile 

Aldol  (3-Hydroxybutyraldehyde) 

Allyl  alcohol 

•Allyl  bromide 

Allyl  chloride 

Allyl  mercaptan  (2-Propene-l-thiol) 

]-AllyI-3-succinylurea 

Allyl  sulfide 

Aluminum  alkoxides: 

Aluminum  tert-butylate 

Aluminum  isopropylate 

•Amines: 

Allylamine t 

2-Aminoheptane 

Amylamines 

Butylamines: 

Mono 

Di 

Tri 

Iso 

Diethylenetriamine 

Dioctylamine 

Dipropylenetriamine 

Ethylamines; 

Mono 

Di 

Tri 

Monoethylamine  hydrochloride 

•Ethylenediamine,  tech 

Fatty  acid  amines 

Hexamcthylenediamine 

•Hexamethylenetetramine,  tech 

Laurylamine  and  hydrochloride 

Methylamine: 

•Mono ■ 

•Di 

Tri 

1-Methylhexylamine  (2-Aminoheptane) 

Polyethylene  amines 

Propylenediamine 

Tetraethylenepentamine 

Triethylenetetraniine 

Aminoacetic,  tech.  (Glycine) 

2-Amino-l-butanol 

Aminocapronitrile 

2-Aniinoethanol  sulfite  (Monocthanolamine  sulfite) 

2-Amino-2-ethyI-l,3-propanediol ^ 

Aminoguanidine  sulfate 

Aminoisobutanol  (2-Amino-2-methyl-l-propanol) 

2-Amino-2-methj'l-l,3-propanediol 

*Amyl  acetates: 
Primary: 

•Normal  (90%) 

Active  (90%) 

•Isoamyl  (90%) .• 

Secondary  (90%) 

Not  specified 

*Amvl  alcohols: 

•Crude  (Fusel  oil)  (100%,) 

•Refined: 

Primary: 

xXormal  (n-Butylcarbinol)  (lOOS't) 

Active  (2-Methyl-l-butanol)  (100%) 

Isoamyl  (3-Methyl-l-butanol;  (100%) 

Secondary: 

2-Pentanol    (Methylpropylcarbinol)    (10  0%)    (  1 
Methylbutanol). 

3-Pentanol  (Diethylcarbinol)  (100%) 

Tertiary: 

Amyl  (2-Methyl-2-butanol)  (100%) 

n-Amyl  chloride 

Amylenes,  mixed 

Amyl  ether 


45,  294,  323. 

77. 

136,  139. 

178,  207,  X. 

176. 

16,  127,  129,  394. 

129. 

129. 

323. 

139,  416. 

127,  139,  298. 

416. 

139. 

248. 

139. 

136. 
136,  139. 

139. 
307. 
413. 

77,  413,  X. 

77,  413. 

413. 

129. 

54,  77,  119. 

77. 

54,  119. 

413. 

413. 

413. 

413. 

54,  77,  119. 

29,  176,  437. 

129 

129',  130,  203,  276,  X,  X,  X. 

129. 

106,  129,  254,  394. 

106,  129,  254,  394. 

106,  129,  254,  394. 

307. 

77. 

54,  77,  119. 

77. 

77. 

51. 

106. 

129. 

278. 

106. 

176. 

106,  295. 

106. 


106,  129,  374,  413,  470. 

129  413 

129!  165',  237,  330,  350,  413,  470, 

X,  X. 
413. 
129,  413,  X. 

106,  129,  300,  470. 

165,  374,  413,  470. 

129,  413. 

165,  350,  413,  470,  X,'.X. 

77,  207,  413,  435. 

413. 

± 

413. 
413. 
413. 


124 


UNITED  STATES  TARIFF  COMMISSION 


Table  17B. — Synthetic  organic  chemicals:   Miscellaneous   chemicals  for  tvhich   United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1941~43 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


,     MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

Amyl  mercaptan  (Pentanethiol) 

Amyl  methyl  ketone  (2-Heptanone) 

Amyl  propionate 

Amyl  sulfide 

Anhydromethylenecitric    acid    [^-(Hydroxymethyl)    tricarballylic 
acid  lactone]. 

Azelaic  acid 

1-Bromobutane 

2-Bromobutane 

l-Bromo-3-chloropropane 

o-Bromoisovaleryl  urea,  mono 

2-Bromo-octane  (sec-Octyl  bromide) 

2-Bromopentane 

'Butadiene 

•Butyl  acetates: 

♦Normal  (90%) 


Iso    90%) 

Secondary  (90%) 

*Butyl  alcohols: 

Primary: 

♦Normal  (n-Propylcarbinol)  (100%) 

Iso  (Isopropvlcarbinol)  (100%) 

Secondary  (Ethylmethylcarbinol)    (100%) 

Tertiary  (Trimethylcarbinol)  (100%) 

n-Butyl  ether 

tert-Butyl  hydroperoxide 

Butyl  lactate 

Butyl  methyl  ketone  (2-Hexanone) 

Butyl  propionate  (100%) 

n-Butyraldehyde 

n-Butyric  acid 

Butyric  anhydride 

Butyryl  chloride 

*n-Caproic  acid 

*Carbon  disulfide 

♦Carbon  tetrachloride '..... 

Cellulose  esters: 

♦Cellulose  acetate 

Cellulose  acetate  butyrate 

Cellulose  acetate  propionate 

Cellulose  nitrate 

Cellulose  ethers: 

Ethyl  cellulose 

Methyl  cellulose 

Cetyl  bromide 

Cetyl  chloride 

Chemical  reagents: 

Girard's  reagent  PI 

Chlorinated  solvents 

Chloroacetic  acid: 

Mono 

Di 

Tri :... 

Chloroacetamide 

Chloroacetyl  chloride 

1-Chlorobutane 

2-Chlorobutane 

/3-Chloro-o-diethylaminoethane  hydrochloride  (Novolid  salt). 

2-Chloroethanol  (Ethylene  chlorohydrin) 

♦Chloroform 

♦Technical 


"U.  S.  P. 


Chlorokerosene,  sulfurized 

Cliloromaleic  anhydride 

2-Chloro-2-methyIpropane  (tcrt-Butyl  chloride) 

♦Chloroparaffin 

3-Chloro-l,2-propanediol  (Glyceryl  o-chlorohydrin) . .  . 

l-Chloro-2-propanol  (Propylene  chlorohydrin) 

3-Chloro-l-propanol  (Trimethylene  chlorohydrin) 

Chromium  acetylacetonate 

Citric  acid: 

Crude,  fermentation 

♦Refined,  fermentation 

Refined,  natural 

Cobalt  acetylacetonate 

Coconut  oil  fatty  acid  chloride 

Crotonaldehyde 

Cyanoacetamide 

Cyanoacetic  acid 

♦Diacetone  alcohol  (4-Hydroxy-4-methyl-2-pcntanone) . 


413. 
77,  X. 
156,  470. 
413. 
139. 

143. 

1,  136,  139,  298. 

136,  X. 

127,  X. 

304. 

1.39. 

260. 

127,  359,  416,  512,  .520,  X,  X. 

77,  106,  129,  159,   165,  350,  374, 

470. 
129. 
416,  435. 


35,  77,  106,  374,  470. 

77,  129. 

416,  435. 

416. 

77,  106. 

467. 

106. 

435. 

165,  470. 

77,  X. 

77,  .3.30,  X. 

77,  X. 

207. 

77,  286,  330. 

127,  338,  447,  457,  495,  X. 

127,  325,  409,  457,  495,  X. 

201,  X,  X,  X,  X,  X.' 

X. 

X. 

201. 

127,  201. 
127. 

1.39,  295. 
295. 

248. 
50,  328. 

127. 

127. 

127. 

294 

127!  145,  169. 

77,  413. 

136. 

413,  X. 

77.- 

50. 

64,  127,  129. 

64,  127,  129. 

X. 

313. 

136,  X. 

11,  201,  204,207,  440. 

413,416. 

77. 

1.36,  260. 

139. 


356. 

97,  294,  356,  447. 

447. 

1.39. 

176. 

323,  X. 

51,233. 

51,  127. 

77,  106,  307,  416. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


125 


Table  17B. — Synthetic  organic  chemicals:    Miscellaneous   chemicals  for  which   United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  19^1-^3 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

Diaminobimalonic  acid,  sodium  salt  (Ethylenediamine  tetrasodium 
carboxylate). 

Diaminodiacetic  acid 

Dibromochlorobutane 

1 ,2-Dibromoetliane  (Ethylene  dibroniide) 

Dibromomethane  (Methylene  dibromide) 

1 ,3-Dibromopropane  (Trimethylene  bromide) 

Dibutylaminoethanol 

Dibutyl  oxalate 

Dichlorodiethyl  ether  [Bis(2-chloroethyl)etherJ 

*1,2-Diohloroethane  (Ethylene  dichloride) 

Dichloroethyl  acetate 

Dichloroethyl  formal 

Dichloroisopropyl  ether 

Dichloromethane  (Methylene  dichloride),  crude 

*Dichloroniethane  (Methylene  dichloride),  grade  not  specified 

Dichloropentane  (Aniylene  dichloride) 

1,2-Dichloropropane  (Propylene  dichloride) 

*l,3-Dichloro-2-propanol  (Glycerol  dichlorohydrin) 

Dichlorostearic  acid 

Dicyandiamide 

*l-Diethylamino-4-aminopentane  (Novoldiamine) 

l-Diethylamino-4-aminopentanone  (Novol  ketone) 

Diethvlaminoethanol 

Diethyl     butylethylmalonate    (n-  and    sec-)    (Butylethylmalonic 
ester). 

Diethyl  carbonate  (Diatol) 

Diethyl  chloromaleate 

'Diethyl  diethylmalonate  (Diethylinalonic  ester) 

Diethylone  glycol  (2,2'-Oxydiethanol) 

Diethylene  glycol  diethyl  ether  (Diethyl  carbitol) 

Diethylone  glycol  monobutyl  ether  (Butyl  carbitol) 

Diethylene  glycol  monobutyl  ether  acetate  (Butyl  carbitol  acetate) . 

Diethylene  glycol  monoethyl  ether  (Carbitol) 

Diethylene  glycol  monoethyl  ether  acetate  (Carbitol  acetate) 

Diethylene  glycol  monolinoleate 

Diethylene  glycol  monomethyl  ether  (Methyl  carbitol) 

Diethyl  ethylisoamylmalonate 

Diethyl  ethylisopropylmalonate  (Ethylisopropylmalonic  ester) 

Diethyl  ethyl-1-methylbutylmalonate    (Ethyl-1-methylbutylma- 
lonic  ester). 
♦Diethyl  malonate  (Malonic  ester) 

Diethyl  monoethylmalonate  (Monoethylmalonic  ester) 

Diethyl  sec-octylmalonate  (sec-Octylmalonic  ester) 

•Diethyl  o.xalate 

Diethyl  sulfate  (Ethyl  sulfate) 

Di-isobutylene 

Di-isobutylene,  S,  CI,  derivative  (Sulfalene) 

Di-isobutyl  ketone  (2-4-Dimethyl-4-heptaiione) 

Di-isopropanolamine 

Dimethyl  chloromaleate 

Dimethyformamide 

Dimethylglyoxime 

Dimethyl  maleate 

Dimethylolurea 

Dimethyl  sulfate 

Dimethylurea 

Dioleyl  malate 

Dipropylene  glycol  [Bis(2-hydroxy-l-propyI)ether] 

1-Dodecanol  (Lauryl  alcohol) 

Dulcitol 

Epichlorohydrin  (l-Chloro-2,3-epoxypropane) 

Ergosterol  (unirradiated) 

Erueie  acid 

Ethanethiol  (Ethyl  mercaptan) 

Ethanolamine: 

Mono 

Di 


Tri 

Mixed 

Ethanolamine  sulfite,  mono. 
•Ethyl  acetate  (85%) 


Ethyl  acetoacetate 

Ethyl  alcohol,  synthetic 

•Ethyl  bromide 

Ethyl  bromoacetate 

2-Ethylbutyl  acetate 

2-Ethvlbutvl  alcohol 

2-EthyIbutyraldehyde 

a-Ethylbutyric  acid  (Diethylacetic  acid) . 


119. 

357. 

148. 

127,  148,  298,  495. 

127,  136. 

1,  127,  335. 

77,  413. 

106,  470. 

77,  95,  127. 

77,  127,  394,  470,  X. 

95. 

77. 

77. 

50,  127. 

50,  127,  129,  482. 
413. 

77,  127. 

413,  416,  X. 

207. 

X. 

204,  413,  X. 

413,  X. 

77,  413. 

X. 

470. 

313 

1,  51,  139,  173,  205,  X. 

77,  127,  470. 

77. 

77. 

77. 

77. 

77. 

.505,  X. 

77. 

260. 

X. 

1,  260. 

1,  51,  127,  173,  260. 

1,  260. 

139 

51,  165,  350,  470. 
77. 

443. 

207. 

77. 

77. 

313. 

129. 

136. 

313. 

129. 

129. 

51,  173,  .389. 

.307. 

77,  127. 

X. 

39. 

127,  207,  410. 

X. 

139,  X. 

278,  423,  440. 

77,  127,  413. 

77,  127,  413. 

77,  127. 

413. 

X. 

77,  106,  129,  162,  165,  307,  350, 

374,  470,  X,  X,  X. 
77,  294,  470. 
72,  77,  129,  X,  X. 
1,  127,  148,  173,  298. 
127,  1.36. 
77,  129. 
77. 
77. 
77. 


126 


UNITED  STATES  TARIFF  COMMISSION 


Table  17B. — Synthetic  organic   chemicals:  Miscellaneous   chemicals  for  which   United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  19^1-^3 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

Ethyl  chloride: 

Technical 

U.S.P 

•Ethyl  chloroacetate 

Ethyl  chloroformate  (Ethyl  chlorocarbonate) 

Ethyl  cyanoacetate 

•Ethylene  (from  ethyl  alcohol) 

Ethylenebis(imino  acetic  acid) 

•Ethylene  glycol 

Ethylene  glycol  bori-borate 

Ethylene  glycol  diacetate 

Ethylene  glycol  diethyl  ether  (Diethyl  cellosolve) 

Ethylene  glycol  diformate 

Ethylene  glycol  dinitrate 

Ethylene  glycol  monobutyl  ether  (Butyl  cellosolve) 

Ethylene  glycol  monoethyl  ether  (Cellosolve) 

Ethylene  glycol  monoethyl  ether  acetate  (Cellosolve  acetate) 

Ethylene  glycol  monomethyl  ether  (Methyl  cellosolve) 

Ethylene    glycol    monomethyl    ether  acetate   (Methyl    cellosolve 
acetate). 

Ethylene  oxide I  77,  127, 


127,  129,  147,  298. 

127,  174. 

127,  156,  294,  X,  X. 

470. 

51    127  233. 

127,  148,  263,  335,  394,  470. 

357. 

77,  127,  129,  470. 

X. 

77. 

77. 

77. 

201. 

77. 

77. 

77. 

77. 

77. 


•Ethyl  ether . 

Technical 

U.S.P 

Absolute 

•Ethyl  formate 

Ethyl  glyceryl  ether 

2-Ethylhexanal 

2-Ethyl-l,3-hexanediol 

2-Ethylhexanol 

2-Ethylhexoic  acid 

2-Ethylhexyl  acetate 

Ethylidene  diacetate 

Ethyl  iodide 

Ethyl  lactate 

Ethyl  methyl  ketone  (methyl  acetone)  (2-Butanone) . 

Ethyl  N-nitroso-N-methylcarbamate 

Ethyl  propionate 

Ethyl  sodium  acetone  oxalate. 

•Fatty  acid  esters,  except  plasticizers: 

Amyl  esters  of  linseed  oil 

Amyl  esters  of  soybean  oil 

Butyl  linoleate 

Butyl  palmitate 

Butyl  tallow 

Diglycol  monolinoleate 

Ethyl  palmitate 

Glyceryl  ester  of  linseed  oil 

Glyceryl  tri  tallow 

Propylene  glycol  monolinoleate 

Tall  oil  esters 

All  others,  unspecified 


Fatty  alcohols  (containing  more  than  8  carbon  atoms) . 

Fenchone 

•Formaldehyde  (37%  HCHO  by  weight) 


Formamide 

Formic  acid  (90%) 

•Formic  acid  salts: 

Aluminum 

Chromium 

Nickel 

•Sodium 

Fumaric  acid 

•Gases  (poisonous,  tear,  etc.): 

Bis-(2-chloroethyl)  sulfide  (Mustard  gas) . 

Carbonyl  chloride  (Phosgene) 

*Chloropicrin 

Chlorovinyl  dichloroarsine  (Lewisite) 

Gluconic  acid,  crude 

Glyceric  acid 

Glyceryl  monoisoline 

Glyceryl  tributyrate 

Guanidine  carbonate 

Guanidine  nitrate 

Guanylnitrosaminoguanyltetrazene 

Heptadecanol 

Heptane 

•Hexachloroethane 

Hexadecanol,  crude 

Hexaldehyde 


77,  278,  294,  470,  X,  X. 

77,  201,  X,  X. 

278,  432,  470. 

470. 

106,  165,  278,  330,  350,  470, 

X. 

77. 

77. 

77,  207. 

77. 

77. 

X. 

139. 

106',  470,  X. 

77,  409,  416,  435,  X. 

136. 

129,  156,  165,  470,  X,  X. 

470. 

505. 

505. 

X. 

237,  314. 

237. 

237. 

237. 

505. 

237. 

237. 

314,  505. 

48,  195,  237,  314,  389,  437 

X,  X. 
129,  156. 
319,  X. 
96,  106,  129,  203,  233,  234, 

X,  X. 
129 
129^203,  481. 

129,481. 

176. 

198,  481. 

129,  203,  278,  294,  481,  X. 

313,  356. 

247. 

207,  324. 

23,  127,  217,  X. 

247. 

356. 

159. 

237. 

479. 

317,  X. 

X. 

X. 

77. 

77. 

127,  129,  207,  X. 

195. 

77. 


507, 
394, 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


127 


Table  17B. — Synthetic  organic  chemicals:  Miscellaneous   chemicals  for  which   United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  19Jfl~i3 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

Hexamethyldiaminoisopropyldi-iodide 

Hexamethylenediammonium  adipate 

Hexamethylenetetramine  nitrate 

n-Hexyl  alcohol 

n-Hexyl  ether 

Higher  alcohols  (containing  more  than  5  carbon  atoms)  

Higher  ketones 

Higher  methacrylates  (above  methyl) 

Hydracrylonitrile  (Ethylene  cyanohydrin) 

Hydroxyacetic  acid  (Glycolic  acid) 

Hydroxyalkylene  glucosides 

Hydroxyethyl  ethylenediamine 

Insecticides: 

Indalone 

Isobutylundecylenamide 

Organic  thiocyanates 

*Iodomethane  (Methyliodide) 

Iron  (ferrous)  oxalate 

Isoamyl  chloride  (l-Chloro-3-methylbutane) 

Isobutylene 

Isobutyl  methyl  ketone  (4-methyl-2-pentanone) 

Isobutyl  propionate 

Isobuty  raldehyde 

Isobutyric  acid 

Iso-octane  cutting  oil 

Iso-octane,  hydrogenated 

Iso-octyl  sulfide 

Isoprene 

Isoprene-piperylene,  crude 

Isopropyl  acetate 

*Isopropyl  ale  ohol  (Isopropanol)  100% 

Isopropyl  bromide 

Isopropyl  chloride 

*Isopropyl  ether 

Isovaleric  acid 

Kerosene  disulfide 

Lactic  acid: 

♦Edible  (100%) 

Medicinal  (100%) 

♦Technical  (100%) 

Lauroyl  peroxide 

Lauroyl  chloride 

Lauryl  chloride 

Levulinic  acid  (/3-Acetylpropionic  acid) 

Maleic  acid. . 

♦Maleic  anhydride 

Malic  acid 

Malonic  acid 

Mannitol 

Mannitol  hexanitrate .-•••. 

Mercaptoacetic  acid  and  salts  (Thioglycolic  acid  and  salts) 

3-Mercapto-l,2-propanediol  (l-Mercapto-2,3-dihydroxypropane) 
(a-Thioglycerol). 

Mercury  disinfectants: 

Seed 

Other 

•Mesityl  oxide  (Isopropylidene  acetate) 

Metaldehyde 

Methacrylates,  above  methyl 

Methacrvlic  acid 

Methallyl  alcohol  (2-Methyl-2-propen-l-ol) 

Methallyl  chloride ._ 

♦Methanol  (synthetic) ' 

Methoxymethoxyethanol 

♦Methyl  acetate 

Methyl  acetoacetate 

Methyl  acetone-acetol 

Methylaminoacetic  acid  (Sarcosine)  (N-methylglycine) 

Methylaminodiethanol 

Methyl  borate 

♦Methyl  bromide 

1-Methylbutyl  bromide 

Methyl  chloride,  crude 

Methyl  chloride,  crude  and  refined 

Methylenebis  (iminoacetic  acid) 

Methylenebis  (iminopropionic  acid) 

Methyl  ether 

Methyl  formate 

Methyl  glutarate 

Methyl  glycolate  (Methyl  hydroxyacetate) 

Methyl  isobutyl  carbinol  (4-Methvl-2-pentanol) 


159. 
129. 
X. 

77. 

77. 

129. 

129. 

129. 

129. 

129. 

39. 

77. 

470. 

129. 

129,  394. 

10,  139,  294. 

60. 

260. 

443. 

77,  416. 

129. 

129. 

129. 

207. 

207. 

207. 

319,  X,  X. 

X. 

77,  106,  129,  416,  435,  470. 

77,  416,  435,  X. 

127,  X. 

207,  X. 

77,  416,  435,  X. 

330,  X,  X. 

207. 

17,  24,  98,  129,  X. 

24   129 

17!  24,  98,  129,  X. 

268. 

295. 

129. 

433. 

16,  313,  355. 

16,  77,  307,  313. 

313. 

127,  X. 

39. 

39 

136,  137,  139.  150,  159,  284,  357, 

X,  X. 
X. 


129,  X. 

129 

77,  106,  416. 

106. 

129. 

129. 

416. 

416. 

72,  77,  96,  106,  129. 

129. 

77,  129,  162,  323. 

77. 

96. 

176. 

77,  176. 

129. 

127,  129,  298,  362. 

1. 

50,  129. 

127,  362,  482,  X, 

357. 

357. 

129. 

106,  129,  233. 

129. 

129. 

77,  416. 


128 


UNITED  STATES  TARIFF  COMMISSION 


Table  17B. — Synthetic  organic  chemicals:    Miscellaneous   chemicals  for  which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1941-43 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  13.5 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

Methyl  isobutyl  carbinyl  acetate 

Met  hyl  lactate 

Methyl  methacrylate 

2-Methyl-2,4-pentanediol 

Methyl  propyl  ketone  (2-Pentanone) 

Methyl  succinate 

N-Methyltaurine 

Methyl  terpinyl  ether 

Mucochloric  acid  (Dichloroformylacrylic  acid) 

Nitrohydroxy  compounds: 

2-Nitro-l-butanol 

2-Nitro-2-ethyl-l,3-propanediol 

2-Nitro-2-methyl-l,3-propanediol 

2-Nitro-2-methyl-l-propanol 

Tris-(hydroxymethyl)-nitromethane 

Nitroparaffins: 

Nitroethane 

Nitromethane 

1-Nitropropane 

2-Nitropropane •  •  •  • 

Nonenoic  acid 

Nonyl  alcohol 

Nylon  polymers 

l,i2-Octadecanediol  CDiolin) 

1-Octanol  (N-Capryl  alcohol) 

2-Octanol  (sec-Capryl  alcohol) 

Octanoyl  chloride  (Capryloyl  chloride) 

Olefinepersulfides  (Thialkenes) 

Oleoyl  chloride 

Oleyl  polyether  alcohol 

Oxalacetic  acid,  sodium  salt 

•Oxalic  acid,  crude  and  refined 

Oxalic  acid  salts: 

'Ammonium  oxalate ' 

Calcium  oxalate 

Copper  oxalate 

Ferric  ammonium  oxalate 

Ferric  sodium  oxalate 

Ferrous  oxalate 

Potassium  binoxalate 

Potassium  oxalate 

Sodium  oxalate 

Palmitic  acid 

Palmitoyl  chloride 

Paracetaldehyde 

Paraformaldehyde 

Pelargonyl  chloride 

Pcntachloroethane ." , 

•Pentaerythritol 

Pentaerythritol  tetranitrate 

2,3-Pentanedione 

Phorone   (Di-isobutylene  ketone)    (2,6-Dimetliyl-2,5-heptadien- 
4-one). 

Phosgene  (10%)  in  carbon  tetrachloride  solution 

Phosphorus  derivatives  of  high  molecular  weight  hydrocarbons.  . 

Pine  oil,  synthetic 

Piperylene  (1,3-Pentadiene) 

•Plasticizers: 

Acetyltri-n-butyl  citrate 

Acetyltriethyl  citrate 

Amyl  stearate 

n-Butyl  acetylricinoleate 

Butyl  acetylricinoleate,  polymerized 

Butyl  cellosolve  oleate  (Butoxyethyl  oleate) 

Butyl   cellosolve  stearate    (Ethylene  glycol  monobutyl  ether 
stearate)   (Butoxyethyl  stearate). 

Butyl  laurate 

Butyl  oleate 

Butyl  palmitate 

Butyl  ricinoleate 

'Butyl  stearate 

Cellosolve  stearate  (Ethylene  glycol  nionoethyl  ether  stearate) 
(Ethoxyethyl  stearate). 

Di(butyl  cellosolve)  sebacate 

I)i  (butyl  cellosolve)  tartrate 

•  Dibutyl  sebacate 

'Dibutyl  tartrate 

Diethylene  glycol  dipelargonatc 

Diethylene  glycol  diproijionatc 

Diethylene  glycol  distcarate 

Diethylene  glycil  iiionoChydroxystearate) 

Diethylene  glycol  nionolaurate  (mono  and  di) 


77. 

98,  106. 

129,  .394,  479. 

106. 

435. 

X. 

176. 

201. 

X. 

106. 
106. 
106. 
106. 
106. 

106. 

106. 

106. 

106. 

X. 

X. 

X. 

129. 

129,  314. 

195,  388. 

207. 

112. 

176. 

176. 

470. 

60,  178,  337,  .356,  481. 

60,  178,  198,  278,  294,  356. 

60. 

60. 

60,  356. 

60,  356. 

60,  356,  X. 

60. 

60.  178,  3.56. 

60,  178,  278,  294,  481. 

1.59. 

176. 

.323. 

129,  203,  X. 

207. 

129. 

201,  323,  388,  462,  X,  X,  X. 

201,462. 

1.39. 

77. 

247. 
X. 
201. 
X. 


356. 

3.56. 

237. 

44,  106 

44. 

334. 

195,  334. 


237. 

106,  237,'314,  334. 
314,  X. 
44,  X. 

106,  129,  237,'314,  X. 
129. 

129. 

129 

lOel  129,' 195,  388,  X,  X. 

106,  129,  237. 

143. 

334. 

237. 

314. 

237,  314,  X,  X. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


129 


Table  17B. — Synthetic  organic  chemicals:    Miscellaneous   chemicals  for   tvhich    United 
States  production  or  sales  were  reported,  identified  by  manvfacturer,  19Jtl-.'t3 — Continued 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 
*Plasticizers — Continued 

*Diethylene  glycol  mono-oleate  (mono  and  di) 

Diethylene  glycol  monopalmitate 

Diethylene  glycol  monoricinoleate 

Diethylene  glycol  monostearate  (mono  and  di) 

*Diethylene  glycol  stearate,  not  specified 

Diethyl  sebacate 

Di-isobutyl  adipate 

Dimethoxytetraglycol 

Dimethylcellosolve  adipate  [Di-(methoxyethyl)adipate) 

Dimethyl  sebacate 

Ethyl  acetylricinoleate 

Ethylene  glycol  mono-oleate 

Ethylene  glycol  stearate 

Ethyl  oleate 

Ethyl  ricinoleate 

Ethyl  stearate 

Fatty  acid  nitriles 

Glyceryl  diacetate  (Diacetin) 

Glyceryl  diacetyltartrate  mono-oleate 

Glyceryl  monoacetate  (Acetin) 

Glyceryl  mono(hydroxystearate) 

Glyceryl  monolaurate 

Glyceryl  mono-oleate - 

Glyceryl  monoricinoleate 

*Glyceryl  monostearate 

♦Glyceryl  triacetate  (Triacetin) 

Glyceryl  triacetylricinoleate  (Castor  oil,  acetylated) 

Glyceryl  tri(hydroxystearate) 

Glyceryl  trioleate 

Glyceryl  tripropionate 

Glyceryl  tristearate 

Methyl  acetylricinoleate 

Methyl  cellosolve  acetylricinoleate  (Methoxyethyl  acetylricin- 
oleate). 

Methyl  cellosolve  oleate  (Methoxyethyl  oleate) 

Methyl  cellosolve  ricinoleate 

Methyl  cellosolve  stearate 

Methyl  dichlorostearate 

Methyl  oleate 

Methyl  pentachlorostearate 

Methyl  ricinoleate 

Methyl  stearate 

Pentaerythritol  tetra-acetate 

Polyethylene  glycol 

Polyglycerol 

Polyglyceryl  oleate 

Polyglyceryl  stearate 

Polyglycol  monostearate 

Polyglycol  oleate 

Polypropylene  glycol 

1,2-Propylene  glycol  monolaurate 

1,2-Propylene  glycol  mono-oleate 

*  1,2-Propylene  glycol  monostearate. . ; 

Sucrose  oeta-acetate 

Tetraethylene  glycol 

Tributylcellosoive  phosphate  [Tii-(ethylene  glycol  monobutyl 
ether)  phosphate]. 

Tributyl  citrate 

Tributyl  phosphate 

Triethyl  citrate 

Triethylene  glycol  di-2-ethylhexoate 

Triethylene  glycol  di-n-hexoate ,  .  ,  . , 

Triethylene  glycol  monomethyl  ether  acetate 

*Triethyl  phosphate 

Trioctyl  phosphate 

Other  acyclic  plasticizers 

Polyglycol  akyl  amine  sulfate 

Propenyl  methyl  anaethol 

Propionaldehyde 

Propionic  acid 

Propionic  acid  salts: 

Calcium  propionate 

Sodium  propionate 

Propionic  anhydride 

Propionyl  chloride 

n-Propyl  acetate 

n-Propyl  alcohol  (Propanol) 

Propylene 

Propylene  glycol 

Propylene  oxide 

Propyl  mercaptan  (l-Propanethiol) 


14.-,, 

237. 

314. 

237, 

145, 

106, 

129. 

77. 

129, 

129. 

44. 

195 

237, 

237 

295 

X. 

29. 

237 

145 

176 

314 

X. 

48, 

314 

145 

204 

44. 

129 

195 

X. 

X. 

44. 

44, 


195,  237,  314,  X. 


314. 

237,  314,  389,  X,  X. 


,237. 


195,  237. 

,  X,  X. 

,  195,  237,  314,  437,  X,  X. 

,  237,  268,  314,  X,  X,  X. 


,  237. 


334. 


334. 

44. 

334. 

207. 

314. 

207. 

44. 

195,  207,  X. 

X. 

77. 

307,  X. 

145. 

145. 

39. 

176. 

77. 

39,  237. 

39,  237. 

39,  145,  237. 

.323. 

77. 

334. 


106, 

106, 

356, 

77. 

77. 

77. 

106, 

334, 

.39, 

176. 

X. 

129. 

106, 


356. 
307. 
X,  X. 


307,  X,  X. 
207,  221,  237,  334,  475',  507 


129,  X. 


129. 
129. 
77,  X. 

207. 

129,  156,  159. 

129. 

129. 

77,  127,  129,  237. 

77,  127. 

423. 


646064—46—9 


130 


UNITED  STATES  TARIFF  COMMISSION 


Table  17B. — Synthetic  organic  chemicals:  Miscellaneous  chemicals  for   which   United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  19^1-43 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

Protalbinic  acid 

Pyruvic  acid 

Refrigerants: 

Chlorodifiuoromethane 

Dichilorodifluoromethane 

Dichloromonofluoromethane 

Dichlorotetrafluoroethane 

♦Methyl  chloride 

Methylene  chloride  (Dichloromethane) •. 

Trichioromonofluoromothane 

Trichlorotrifluoroethane 

Research  chemicals 

Ricinoleic  acid 

Sebacic  acid 

Semicarbazide  hydrochloride 

Sodium  glycerophosphate 

Sodium  hydroxyethane  sulfonate 

*Sodium  lactate 

Sodium  methylate 

Sodium  oleate 

Sodium  oxalacetate 

Sorbitol 

♦Stearic  acid  salts: 

♦Aluminum  stearate 

Ammonium  stearate 

Barium  stearate 

•Calcium  stearate 

Cupric  stearate 

*  Magnesium  stearate 

*Zinc  stearate 

Stearoyl  chloride 

♦Succinic  acid  and  anhydride 

Succinic  acid  salts: 

Ammonium  succinate i 

Sodium  succinate 

Succinimide 

Sulfoacetic  acid 

Sulfonated  thiocarbanilide  acetaldehyde  ammonia  compound 

♦Surface-active  agents: 
♦Amides: 

Diethanol  lauramide  fN,N-Di(2-hydroxyethyl)lauramide] 

Ethanol  hydroxystearamide 

Ethanol  lauramide 

Ethanol  oleamide 

Ethanol  ricinoleamide 

Ethanol  stearamide 

Oleic,  linoleic,  and  rosin  acids,  mixed 

Stearamide  and  palmitamide,  mixed 

All  other 

Amines: 

Amidazoline 

Dioctadecyl 

Hexadecyl,  tech 

Isopropanolamines 

Mixed  fatty  alcohols  and  fatty  acid  alkylamine 

Octadecyl 

Hexose  derivatives: 

Anhydrohexitol  ester  polyglycol  ethers 

Anhydrohexitol  esters 

Hydroxyalkyleneglucoside,  cotton  seed  fatty  acid  ester. .  . 

Hydroxyalkyleneglucoside  stearate 

Substituted  ammonium  compounds: 

Butylamine  oleate 

Ethanolamine  hydrochloride  (2-AminoethanoI  hydrochlo- 
ride) fatty  acid  esters. 

Cetyl  trimothyl  ammonium  bromide 

Ethanolamine  soaps,  not  specified 

Diethyleneglycol  laurate  sulfate,  ethanolamine  salt 

Diethylene  glycol  oleate  sulfate,  ethanolamine  salt 

Fatty  acid  amine  acetates 

Quarternary  ammonium,  not  specified 

Salts  of  fatty  acids: 

Potassium  laurate 

Sodium  laurate 

♦Sulfated  and  sulfonated  fatty  and  alkyl  acids  and  salts: 

Hydroxyethane  oleate  sulfonic  acid,  sodium  salt 

Monostearine  sulf oacetate,  sodium  salt 

♦Sulfonated  oleic  acid  (Sulfonated  red  oil) 

Sulfonated  ricinoleic  acid,  sodium  salt 

Trihexylsulfotriearballylic  acid,  sodium  salt 

Sulfated  and  sulfonated  fatty  and  alkyl  acids  and  salts 
not  specified. 


89. 
72. 

241. 

241. 

241. 

241. 

2,3,  127,  129,  307,  362,  482. 

50,  127,  129. 

241. 

241. 

68,  136.  348,  X. 

44. 

195,  314,  388. 

139,  150,  159. 

145. 

176. 

24,  98,  204,  278,  294,  X,  X. 

129,  287. 

91. 

470. 

39,  355,  356. 

48,  166,  278,  314,  455,  489,  503. 

198,  204,  314,  X. 

166. 

48,  166,  198,  278,  314,  455,  489. 

489. 

48,  166,  278,  314,  455,  489. 

48,  166,  278,  314,  455,  489,  503. 

176. 

16,  136,  307,  313,  348. 

X. 

278,  294. 
313. 
129. 
307. 


314. 

314. 

314,  505. 

314,  505. 

314. 

314. 

195. 

29 

200,  507. 

389. 

29. 

29. 

77. 

389. 

29. 

.39. 
39. 
39.  . 
39. 

413. 

145. 

137,  295. 
437,  507. 
145. 
145, 
29. 
254,  394. 

309. 
91. 

176. 

145. 

176,  403,  489,  507. 

403,  437. 

314. 

95,  176,  437. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


131 


Table   17B. — Synthetic  organic  chemicals:    Miscellaneous  chemicals  for  which   United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1941-43 — Continued 


Chemical 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

'Surface-active  agents — Continued 

•Sulfated  and  sulfonated  alcohols  and  salts: 

Cetyl  sulfate,  sodium  salt 

3,9-Diethyl-6-tndecyIsulfate,  sodium  salt 

7-Ethyl-2-methyl-4-undecylsulfatc,  sodium  salt 

2-Ethylhexylsulfate,  sodium  salt 

Isopropylsulfonic  acid 

Lauryl  sulfate,  sodium  salt 

Octyl  sulfate,  sodium  salt 

Oleyl  sulfate 

Sulfated  and  sulfonated  alcohols  and  salts,  not  specified.  . 

•Sulfated  and  sulfonated  amides  and  salts: 

Ethanololeamide  sulfate,  sodium  salt  [N-(2-Hydroxyethyl) 
oleamide,  sodium  salt]. 

Monoethanol-lauramidesulfonic  acid,  potassium  salt 

Oleylamidehydroxyethane  sulfonate,  sodium  salt 

Sulfoacetoethanolamide  laurate,  potassium  salt 

Sulfated  and  sulfonated  amides  and  salts,  not  specified.  .  . 
•Sulfated  and  sulfonated  esters  and  salts: 

Diamyl  sodium  sulfosuccinate 

Dibutyl  sodium  sulfosuccinate 

Dihexyl  sodium  sulfosuccinate 

Dioctyl  sodium  sulfosuccinate 

Distearoyl  sodium  sulfosuccinate 

Lauryl  sulfoacetate 

Monostearine  sodium  sulfoacetate 

n-Octadecyl  disodium  sulfosuccinate 

n-Octadecyl  nickel  2-dicarboxethyl-sulfosuccinate 

Sulfated  butyl  ricinoleate,  sodium  salt 

Sulfated  butyl  oleate 

All  other 

•Sulfated  and  sulfonated  oils,  fats,  waxes,  and  their  salts : 

*Castor  oil,  sulfonated 

Corn  oil ,  sulfonated 

Peanut  oil,  sulfonated 

Sperm  oil,  sulfonated 

Tallow,  sulfonated 

All  other,  unspecified 

•Sulfonated  paraffinic  petroleum  compounds  and  salts: 

Petroleum  sulfonate,  ammonium  salt 

Petroleum  sulfonate,  sodium  salt 

All  other,  unspecified 

Xanthogen  derivatives: 

Butylxanthogen  ethyl  formate 

Ethylxanthogen  ethyl  formate 

Other  acyclic  surface-active  agents,  unspecified 

Tanning    chemicals,    synthetic: 

Calcium  sulfide  dicyandiamide 

All  other,  unspecified 

Tartaric  acid 

Tartaric  acid  salts: 

Calcium  tartrate 

Potassium  bitartrate 

Potassium  sodium  tartrate 

Tetrabromoethane  (Acetylene  tetrabromide) 

sym.-Tetrachloroethane  (Acetylene  tetrachloride) 

•Tetrachloroethylene  (Perchloroethylene) 

1-Tetradecanol  (Myristyl  alcohol) 

Tetraethyl  lead 

Tetraethyl  orthosilioate 

•Textile  chemicals,  other  than  surface-active  agents 

Thioglycerol 

•Thiourea 

Tribromoacetaldehyde  (Bromal) 

Tributyl  borate 

Tributyl  phosphite 

1,1,2-Trichloroethane  (Methyl  chloroform) 

Trichloroethylene •. 

Triethanolamine  phosphate 

Triethykne  glycol 

Triethylene  glycol  dichloride  (Triglycol  dichloride) 

Triethyl  orthoformate  (Ethyl  orthoformate) 

Triethyltin  bromide 

Tri-isobutylene 

Tri-isopropanolamine 

Tris(hydroxymethylamino)  methane 

Turpentine  sulfide 

Undecylenic  acid 

Urea  (solid) 

Urea  in  solid  fertilizer 

Urea  in  urea-ammonia  solution 


507. 
77. 
77. 
77. 
X. 
129. 
145. 
389. 

77,  95,  129,  176,  195,  309,  389, 
437,  489,  X,  X,  X. 

314. 

489. 

176,  437,  505. 

145. 

200,  309,  507,  X. 

X. 
X. 
X. 

X. 
X. 

313. 
313. 
X. 
X. 

507. 
389. 
176,  309,  313. 

176,  200,  489,  507,  X. 

489. 

489. 

200. 

489,  507. 

200,  309,  389,  437,  489,  507,  X. 

210. 

129,  210,  417. 

440,  X- 

306. 
306. 
29,  176,  309,  437,  454,  537. 

X. 
X. 

60. 


60. 

60. 

60. 

127, 

127, 

127, 

77. 

147, 

77. 

39, 

X. 

72, 

X. 

106, 

129 

77, 

127 

77. 

77, 

77. 

233 

247 

443 

77, 

106 

207, 

44, 

129, 

129, 

129, 


159. 

129,  495. 
129,  X. 


129,  309,  437,  489,  X. 
136,  282,  294,.307,  355. 


127. 

,  129,  495. 

127. 


.  X. 

156,  X,  X. 


132 


UNITED  STATES  TARIFF  COMMISSION 


Table   17B. — Synthetic  organic  chemicals:   Miscellaneous  chemicals  for    which   United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1941--i-3 — Continued 


Chemical 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

Vinyl  acetate: 

Monomer 

Vinyl  chloride: 

Monomer 

Vinyl  ether: 

Monomer 

Vinylidene  chloride: 

Monomer 

Waxes  (synthetic) 

Other  miscellaneous  acyclic  chemicals 


Manufacturers'  identification 
numbers  (according  to  list  on  p.  135) 


129,  323. 

77,  127,  129,  186. 

176. 

127. 
X. 

39,  96,  129,  139,  159,  207,  350. 


APPENDIX 

A.   IMPORTS  OF  COAL-TAR  INTERMEDIATES  AND  FINISHED  PRODUCTS 

Before  1942,  the  United  States  Tariff  Commission  cooperated  with 
the  U.  S.  Department  of  Commerce  in  compiling  data  from  original  cus- 
toms documents  on  coal-tar  intermediates  and  finished  coal-tar  prod- 
ucts entering  the  United  States  under  paragraphs  27  and  28  of  the 
Tariff  Act  of  1930.  These  statistics  were  formerly  released  semi- 
annually by  the  Department  of  Commerce  in  Import  Statement  No. 
2865.  This  statement  shows  imports  of  dutiable  coal-tar  products  in 
greater  detail  than  in  the  annual  publication,  Foreign  Commerce  and 
Navigation  of  the  United  States.  Since  1941,  the  United  States  Tariff 
Commission  has  compiled  these  statistics  principally  for  use  of  the 
war  agencies.    A  summary  of  these  data  is  shown  in  table  18. 

Table   18. — Coal-tar  intermediafcs,  and  finished  coal-tar  products:  United  States  imports 
for  consumption,  classified  by  uses,  lOil-^S 


1941 

1942 

1943 

Product 

Quantity 

Foreign 
invoice 
value 

Quantity 

Foreign 
invoice 
value 

Quantity 

Foreign 

invoice 

vahie 

Intermediates,  total 

1,000 
pounds 

3,149 

1,000 

dollars 

1,176 

/  ,  000 
pounds 

3,243 

1,000 
dollars 

.564 

1,000 
pounds 

4,424 

1,000 
dollars 

651 

Finished  coal-tar  products*  total 

6,601 

4.446 

6,109 

3,051 

1,283 

2.334 

Dyes,  total 

2,230 

3,. 596 

1,127 

1,905 

607 

1,318 

Acid 

Vat '.    

.535 

380 

252 

663 

142 

191 

17 

37 

13 

25 

11 

4,335 

1,069 

622 

379 

1,060 

218 

152 

10 

84 

2 

67 

112 
671 

219 
297 

147 

291 

78 

*? 

27 

17 

3 

1 

4,978 

447 

413 

260 

473 

120 

76 

5 

108 

3 

21 

33 

1,092 

169 
36 

100 

170 

96 

22 

449 
115 

Mordant  and  chrome 

Direct  '              

210 
318 

156 

40 

Sulfur 

Color-lake  and  spirit-soluble 

Other       

9 

206 
467 

28 
2 

IS 

Medicinals  and  pharmaceuticals    .  . 

862 
136 

1  Includes  rapid  fast  dyes. 

Source:  Compiled  from  records  of  the  L'.  8.  Bureau  of  Customs. 


Large  imports  of  dinitrotoluene  from  Canada  for  further  processing 
in  the  United  States  and  of  trinitrotoluene  from  Canada  and  Mexico 
made  up  the  bulk  of  the  imports,  accounting  for  6.2  million  pounds  out 
of  a  total  of  9.7  million  pounds  in  1941 ;  and  6.5  million  pounds  out  of 
9.4  million  in  1942.  There  were  no  imports  of  dinitrotoluene  in  1943, 
and  imports  of  trinitrotoluene  dropped  to  397,000  pounds.  Styrene, 
a  raw  material  for  synthetic  rubber,  was  imported  for  the  first  time 
in  1943;  imports,  entirely  from  Canada,  amounted  to  3.7  milllion 
pounds.  Other  important  chemicals  imported  in  1943  were  tetryl, 
an  explosive,  and  sulfapyridine,  a  medicinal. 

133 


134 


UNITED  STATES  TARIFF  COMMISSION 


In  terms  of  value,  dyes  were  the  principal  imports  of  dutiable 
coal-tar  chemicals  in  the  period  1941-43.  From  85.  to  90  percent  of 
the  dye  imports  were  high-priced  dyes  classified  as  noncompetitive. 
These  imports  originated  chiefly  in  Switzerland  and  were  largely 
withdrawals  from  warehouse  of  goods  which  had  previously  entered 
the  country.  The  ratio  of  the  value  (foreign  invoice  value)  of  imports 
to  the  value  of  domestic  production  of  coal-tar  intermediates  and 
finished  products  (such  as  dyes,  flavor  and  perfume  materials,  and 
medicinals)  was  less  than  1  percent  in  1943  and  1942  and  less  than  2 
percent  in  1941. 

B.  RESEARCH  WORKERS  AND  EXPENDITURES 

The  Tariff  Commission  has  from  time  to  time  collected  some  general 
information  concerning  research  expenditures  in  the  synthetic  organic 
chemical  industry.  Because  of  the  difficulty  in  segregating  research 
work  on  synthetic  organic  chemicals  in  a  plant  from  research  work  on 
other  chemicals,  the  figures  reported  by  the  industry  are  only  approxi- 
mate. They  are,  nevertheless,  of  value  in  indicating  trends  and  pro- 
viding information  not  available  elsewhere. 

A  summary  of  the  data  reported  is  shown  below: 


Year 

Companies 
reporting 

Technically 
trained 
research 
workers  ' 

Salaries 
paid 

Cost  of  research 

Gross 

Xet  - 

1941 

Number 

153 
183 
236 

Number 

2,957 
3,839 
5,086 

1,000 

dollars 

8,966 
11,541 
20,816 

1,000 

dollars 

18,425 
23,440 
28,723 

1,000 
dollars 

17,137 

1942 

1943                    

20,768 

28,470 

1  For  the  years  1941-43,  a  technically  trained  research  worker  was  defined  as  a  person  with  technical 
training  engaged  in  research  work  and  earning  not  less  than  $2,000  per  year. 

2 The  net  cost  figure  is  obtained  by  deducting  from  gross  cost,  the  credits  for  salable  products 
obtained  in  the  course  of  research. 


The  average  annual  salary  paid  to  research  workers  was  approxi- 
mately $3,000  per  year  for  1941  and  1942  and  $4,100  in  1943.  The 
higher  figure  in  1943  probably  indicates  in  part  an  increase  in  the  num- 
ber of  older  and  more  experienced  men  employed.  The  increase  in  the 
total  number  of  workers  and  the  net  cost  of  research  in  1942  and  1943, 
compared  with  the  other  years,  is  a  result  of  an  expansion  of  research 
activity  directly  or  indirectly  connected  with  the  war.  In  1943,  ex- 
penditures for  research  were  38  percent  greater  than  in  1942,  which, 
in  turn,  was  substantially  (21  percent)  greater  than  those  in  1941. 
In  1941  and  1942  the  net  cost  of  research  amounted  to  2.3  percent  of 
the  value  of  sales  of  all  synthetic  organic  chemicals,  but  the  ratio  de- 
clined to  2.0  percent  in  1943.  This  ratio,  however,  was  appreciably 
lower  than  in  the  years  immediately  preceding  the  war:  correspond- 
ing ratios  in  1938,  1939,  and  1940  were  4.3,  3.5,  and  3.3  percent,  re- 
spectively. 

C.  DIRECTORY  OF  MANUFACTURERS 

The  directory  of  manufacturers  of  synthetic  organic  chemicals 
included  in  this  report  consists  of  companies  on  the  list  of  producers  re- 
porting to  the  United  States  Tariff  Commission  and  companies  listed 
in  other  directories  and  pubhcations  available  to  the  public.     The 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43 


135 


name  of  each  manufacturer  listed  in  the  directory  is  preceded  by  an 
identifying  number.  Companies  which  manufacture  each  chemical 
Hsted  on  the  series  B  tables  of  part  II  of  this  report  are  identified  by 
these  numbers,  except  those  which  have  requested  the  Tariff  Com- 
mission to  withhold  this  information  concerning  specific  items;  the 
latter  manufacturers  are  indicated  by  the  letter  X.  Firms  designated 
as  producers  of  a  given  item  did  not  necessarily  produce  that  item 
during  all  3  years  covered  by  this  report. 

More  than  500  producing  companies  reported  to  the  Commission 
in  1943  compared  with  380  in  1942  and  335  in  1941.  Part  of  this 
increase  is  due  to  more  complete  coverage  of  existing  manufacturers. 

Not  all  the  firms  listed  in  the  directory  produce  organic  chemicals 
for  sale;  many  consume  their  entire  production  in  further  processing. 

This  directory  is  given  in  table  19. 

Table  19. — Synthetic  organic  chemicals:  Directory  of  manufacturers 

[Names  of  synthetic  organic  chemical  manufacturers  who  reported  production  and  sales  to  the  United 
States  Tariff  Commission,  1941-43,  or  who  are  listed  as  manufacturers  of  synthetic  organic  chemicals 
in  other  directories  or  publications  available  to  the  public.  These  companies  do  not  necessarily  produce 
synthetic  organic  chemicals  for  sale;  some  consume  their  entire  production  in  further  processing.] 


Number 


Name  of  company 


6 

7 

8 

9 
10 
11 
12 
13 
14 
15 
16 
17 
18 
19 

20 

21 

22 

23 

24 
25 
26 
27 
28 
29 
30 
31 
32 
33 
34 
35 
36 
37 
38 
39 
40 
41 
42 
43 
44 
45 

46 
47 
48 


Abbott  Laboratories 

Academy  Laboratories,  Inc 

Acme  Chemical  Co.,  Inc 

Acme  White  Lead  &  Color  Works 

A.  C.  Spark  Plug  Division  General  Motors 
Corp. 

Ad-Co  Color  Corp 

Advance  Paint  Co 

Alkydol  Laboratories,  Inc 

Althouse  Chemical  Co 

Altis  Chemical  Co 

Amecco  Chemicals,  Inc 

American  Alkyd  Industries,  Inc 

American  Aniline  Products,  Inc 

American  Chlorophyll  Co.,  Inc 

American  Cholesterol  Products,  Inc 

American  Cyanamid  Co , 

American  Alaize-Products  Co 

American  Pharmaceutical  Co.,  Inc 

American  Tar  &  Chemical  Co 


American  Viscose  Corp 

Amino  Products  Division,  International  Min- 
erals &  Chemical  Corp. 
Ansbacher-Siegle  Corp 


Ansul  Chemical  Co 

Apex  Chemical  Co.,  Inc 

Appleton  Coated  Paper  Co 

Arco  Co 

Arista  Oil  Products  Co 

Arkansas  Co.,  Inc 

Armour  Chemical  Division,  Armour  &  Co. . . . 

Armstrong  Cork  Co 

Armstrong,  C.  M.,  Inc 

Armstrong  Paint  &  Varnish  Works 

Arnold,  Hoffman  &  Co.,  Inc 

Ashland  Oil  &  Refining  Co 

Asociacion  Azucarera  Cooperative  Lafayette 

Associated  Chemists,  Inc 

Atlantic  Refining  Co 

Atlas  Oil  and  Refining  Corp 

Atlas  Powder  Co 

Atlas  Wall  Paper  Mills,  Inc . 

Augusta  Chemical  Co 

Ault  and  Wiborg  Corp 

Bakelite  Corp 

Baker  Castor  Oil  Co 

Barrett  Division,    Allied    Chemical    &    Dye 
Corp. 

Bates  Chemical  Co 

Bayer  Co.  Division,  Sterling  Drug  Co 

Beacon  Co 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office). 


14th  St.  and  Sheridan  Rd.,  North  Chicago,  111. 
5049  49th  St.,  Woodside,  Long  Island,  N.  Y. 
410  East  32d  St.,  New  York  16,  N.  Y. 
8250  St.  Aubin  St.,  Detroit  11,  Mich. 
1300  North  Dort  Highway,  Flint  2,  Mich. 

66  Lister  Ave.,  Newark  5,  N.  J. 

545  West  Abbott  St.,  Indianapolis  7,  Ind. 

3242  South  50th  Ave.,  Cicero  50,  111. 

540  Pear  St.,  Reading  Pa. 

136  Liberty  St.,  New  York  6,  N.  Y. 

75  Rockwood  St.,  Rochester  10,  N.  Y. 

Broad  and  14th  St.,  Carlstadt,  N.  J. 

50  Union  Square,  New  York  3,  N.  Y. 

P.  O.  Box  431,  Alexandria,  Va. 

Milltown,  N.  J. 

30  Rockefeller  Plaza,  New  York  20,  N.  Y. 

100  East  42d  St.,  New  York,  N.  Y. 

525  West  43d  St.,  New  York  18,  N.  Y. 

423  Canada  Cement  Bldg.,  Montreal,  Canada. 

(5910  Freemont  St.,  Duluth,  Minn.) 
Delaware  Trust  Bldg.,  Wilmington  99,  Del. 
20  North  Wacker  Drive,  Chicago,  111. 

92  Chestnut  Ave.,  Rosebank,  Staten  Island  5, 

N.  Y. 
Box  231,  Marinette,  Wis. 
225  West  34th  St.,  New  York,  N.  Y. 
1200  North  Meade  St.,  Appleton,  Wis. 
7301  Bessemer  Ave.,  Cleveland  4,  Ohio. 
135  Front  St.,  New  York,  N.  Y. 
185  Foundry  St.,  Newark  5,  N.  J. 
1355  West  31st  St.,  Chicago  9,  111. 
Lancaster,  Pa. 

9  East  46th  St.,  New  York,  N.  Y. 
1330  South  Kilbourne  Ave.,  Chicago  23,  111. 
55  Canal  St.,  Providence  1,  R.  I. 
1409  Winchester  Ave.,  Ashland,  Ky. 
342  Madison  Ave.,  New  York  17,  N.  Y. 
North  Collins,  N.  Y. 

260  South  Broad  St.,  Philadelphia  1,  Pa. 
619  Market  St.,  Shreveport  94,  La. 
9th  and  Market  Sts.,  Wilmington  99,  Del. 
Coal  City,  III. 

P.  O.  Box  660,  Augusta,  Ga. 
1754  Dana  Ave.,  Cincinnati  7,  Ohio. 
30  East  42d  St.,  New  York  17,  N.  Y. 
120  Broadway,  New  York  5,  N.  Y. 
40  Rector  St.,  New  York  6,  N.  Y. 

Scottdale  Road,  I,ansdowne,  Pa. 
170  Varick  St.,  New  York  13,  N.  Y. 
97  Bickford  St.,  Boston  30,  Mass. 


136  UNITED  STATES  TARIFF  COMMISSION 

Table  19. — Synthetic  organic  chemicals:  Directory  of  maniifacturers — Continued 


Name  of  company 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office). 


Beaudry  Wall  Paper  Corp 

Belle  Alkali  Co 

Benzol  Products  Co 

Berk,  F.  W.,  &  Co.,  Inc 

Berry  Brothers,  Inc 

Bersworth,  F.  C.,  Laboratories. 

Bick  &  Co.,  Inc 

Birge  Co.,  Inc 

Bischoff,  Ernst,  Co.,  Inc 

Boston  Consolidated  Gas  Co. .  . 

Bridgeport  Gaslight  Co 

Brocker  Chemical  Co , 

Brooklyn  Borough  Gas  Co 


Brooklyn  Color  Works.  . 
Brooklyn  Union  Gas  Co. 

Brown  Co 

Brown,  Andrew,  Co 


Bryant  Electric  Co 

Burkart-Schier  Chemical  Co 

Burroughs  Wellcome  &  Co.,  Inc 

Bush,  Burton  T.,  Inc.  (Givaudan-Delawanna) 

Bush,  W.  J.  &  Co.,  Inc 

Cabot,  Samuel,  Inc 

Calco  Chemical  Division,  American  Cyana- 
mid  Co. 

California  Flaxseed  Products  Co 

California  Ink  Co.,  Inc 


Cambridge  Gaslight  Co 

Capital  Paint  &  Varnish  Works,  Inc 

Carbide  &  Carbon  Chemicals  Corp 

Carlsen,  John  G.,  &  Co 

Carlson,  John  P.,  Inc 

Carnegie-Illinois  Steel  Corp 

Carnrick,  G.  W.,  Co. 

Carroll  Dunham  Smith  Pharmacal  Co 

Carus  Chemical  Co 

Carwin  Co 

Casein  Co.  of  America,  Division  of  Borden 
Co. 

Catalin  Corp.  of  America 

Celanese  Corp.  of  America 

Central  Hudson  Gas  &  Electric  Cori) 

Chemical  Manufacturing  Co.,  Inc 

Chemical  Specialties,  Inc 

Chemico,  Inc 

Chemo  Puro  Mfg.  Corp 


Childs  Pulp  Colors,  Inc 

Ciba  Pharmaceutical  Products,  Inc. 
Cincinnati  Chemical  Works 


Cities  Service  Oil  Co 

Citro  Chemical  Co 

Clinton  Co 

Coastwise  Petroleum  Co 

Colasta  Co.,  Inc 

Coleman  &  Bell  Co 

Colgate-Palmolive-Peet  Co 

Collway  Colors,  Inc 

Colt's  Patent  Fire  .^rms  Manufacturing  Co. . 

Columbus  Varnish  Co 

Commercial  Solvents  Corp 

Commonwealth  Color  &  Chemical  Co 

Connecticut  Power  Co 

Consolidated  Edison  Co.  of  New  York,  Inc. . 
Consolidated  CJas  Electric  Light  &  Power  Co. 

Continental-Diamond  Fibre  Co 

Continental  Oil  Co 

Cook  P<.int  &  Varnish  Co 

Cooks  Falls  Dye  Works,  Inc 

Coopers  Creek  Chemical  Corp 

Crown  Tar  Works 

Daystrom  Corp -.  .  .  . 

Debruille  Chemical  Corp 

Dennis,  Martin,  Co 

Delta  Chemical  Maimfacturing  Co 

Detroit  Ellison  Co 

Dewey  and  Alniy  Chemical  Co 

Diamond  Alkali  Co 

Diarsenol  Co.,  Inc., 

Distillation  Products,  Inc 


46  Elm  St.,  Cortland,  N.  Y. 

P.  O.  Box  615,  Belle,  W.  Va. 

237  South  St.,  Newark  .5,  N.  J. 

Railroad  Ave.,  Wood-Ridge,  N.  J. 

211  Leib  St.,  Detroit  7,  Mich. 

609  Waverly  St.,  Framingham,  Mass. 

1820  North  12th  St.,  Reading,  Pa. 

390  Niagara  St.,  Buffalo  1,  N.  Y. 

Ivoryton,  Conn. 

100  Arlington  St.,  Boston  16,  Mass. 

815  Main  St.,  Bridgeport  1,  Conn. 

Morgan ville,  N.  J. 

West  17th  St.  and  Mermaid  Ave.,  Brooklyn  24, 

N.  Y. 
Morgan  and  Norman  Aves.,  Brooklyn  22,  N.  Y. 
176  Remsen  St.,  Brooklvn  2,  N.  Y. 
650  Main  St.,  Berlin,  N.  H. 
5431   South  Riverside  Drive,   Los  Angeles  22, 

Calif. 
1421  State  St.,  Bridgeport,  Conn. 
1202  Chestnut  St.,  Chattanooga  2,  Tenn. 
9  East  41st  St..  New  York  17,  X.  Y. 
109-201  Delawanna  Ave.,  Delawanna,  N.  J. 
11  East  .38th  St.,  New  York  16,  N.  Y. 
141  Milk  St.,  Boston  9,  Mass.  (Chelsea,  Mass.) 
30  Rockefeller  Plaza,  New  York,  N.  Y. 


3135  East  26th  St.,  Los  Angeles  23,  Calif. 
545  Sansome  St.,  San  Francisco  1],  Calif 

(Berkelev,  Calif.) 
354  Third  St.,  Cambridge  42,  Mass. 
47-55  Rodney  St.,  Brooklvn  11,  N.  Y. 
30  East  42d  St.,  New  York  17,  N.  Y. 
1446  West  Kenzie  St.,  Chicago,  III. 
420  Carroll  St.,  Brooklyn  15,  N.  Y. 
Carnegie  Bldg.,  Pittsburgh  30,  Pa. 
20  Mt.  Pleasant  Ave.,  Newark  4,  X.  J. 
350  Scotland  Road,  Orange,  N.  J. 
1.335  8th  St.,  La  Salle,  III. 
1310  West  Elizabeth  Ave.,  Linden,  N.  J. 
350  Madison  Ave.,  New  Nork  17,  X.  Y. 


Meadow  Road,  Fords,  N.  J. 

180  Madison  Ave.,  New  York  10,  N.  Y. 

South  Road,  Poughkeepsie,  N.  Y. 

Ashhmd,  Mass. 

151   Xorth  Centennial  St.,  Zeeland,  Mich. 

1745  Front  St.,  Cuyahoga  Falls,  Ohio. 

48th  Ave.  and  5th  St.,   Long   Island   Citv    1, 

N.  Y. 
43  Summit  St.,  Brooklyn  31,  N.  Y. 
Lafayette  Park,  Summit,  N.  J. 
P.  O.  Box  20,  Evanston  Station,  Cincinnati  7, 

Ohio. 
Masonic-Empire  Bldg.,  Bartlesville,  Okla. 
Mavwood  Ave.,  Maywood,  N.  J. 
P.  6.  Box  340,  Clinton,  Iowa. 
1127  Munsey  Bldg.,  Baltimore  2,  Md. 
1  Mechanic  St.,  Hoosick  Falls,  N.  Y. 
4101  Main  St.,  Norwood,  Ohio. 
105  Hudson  St.,  Jersev  Citv  2,  N.  J. 
15  Market  St.,  Paterson  1,  N.  J. 
17  Van  Dyke  .^ve.,  Hartford,  Conn. 
95  West  Long  St.,  Columbus  15,  Ohio. 
17  East  42d  St.,  New  York  17,  X.  Y. 
■  223  Nevins  St.,  Brooklyn  17,  N.  Y. 
31  Union  St.,  New  London,  Conn. 
4  Irving  Place,  New  York  3,  N.  Y. 
T;exington  Bldg.,  Baltimore  3,  Md. 
70  S.iuth  Chapel  St.,  Newark,  Del. 
1000  South  Pine  St.,  Ponca  City,  Okla. 
P.  O.  Box  389,  Xorth  Kansas  City  10,  Mi'. 
Cooks  Falls,  X.  Y. 

River  Road,  West  Conshohocken,  Pa. 
900  1.5th  St.,  Denver  ^,  Colo. 
FrankUn  St.,  Olean,  N.  Y. 
1841. Broadway,  New  York  23,  N.  Y. 
8.59  Summer  Ave.,  Newark  4,  N.  J. 
2100  Wa.-ihington  Blvd.,  Baltimore,  Md. 
2000  Second  .\ve.,  Detroit  26,  Mich.   - 
62  Whittemore  Ave.,  Cambridge  40,  Mass. 
.535  Siiiilhtielil  St.,  Pittsburgh  22,  Pa. 
72  Kiiif-'slev  St.,  Buffalo  8,  X.  Y. 
755  Hidge  Road  West,  Rochester  13,  X.  Y. 


svnthb:ti('  organic  chemicals,  1941-43  137 

Table  19. — Synthetic  organic  chemicals:  Directory  of  manufacfnrers — Continued 


126 
127 
128 
129 
130 
131 
132 
133 
134 
135 
136 
137 
138 

139 
140 
141 
142 
143 
144 
145 
146 
147 
148 
149 

loO 
151 
152 
153 
154 
155 
156 
157 
158 
159 
160 
161 
162 
163 
164 

165 

166 
167 
168 
169 
170 
171 
172 
173 
174 
175 
176 

177 
178 
179 
180 
181 

182 
183 
184 
185 
186 
187 
188 

189 
190 
191 

192 
193 
194 
195 
196 
197 
198 
199 
200 
201 
202 


Name  of  company 


Dodge  &  Olcott  Co 

Dow  Chemical  Co 

Dubin.  H.  E.,  Laboratories,  Inc 

duPont  de  Nemours,  E.  I.,  &  Co 

Diirez  Plastics  &  Chemicals,  Inc 

Durite  Plastics,  Inc 

Dye  Specialties  Corp.,  Inc 

Dykem  Co 

Eakins,  J.  S.  &  W.  R.,  Inc 

Ea.stern  Tar  Products  Corp 

Eastman  Kodak  Co 

Edcan  Laboratories 

Edison,     Thomas    A.,     Inf.,     Medical    Gas 
Division. 

Edwal  Laboratories,  Inc 

Electro  Technical  Products,  Inc 

Elizabethtown  Consolidated  Gas  Co 

Elko  Chemical  Works,  Inc 

Emery  Industries,  Inc 

Empire  Chemical  Co.,  Inc 

Emulsol  Corp 

Endo  Products.  Inc 

Ethyl  Corp 

Ethyl-Dow  Chemical  Co 

Factor,  Max,  &  Co 


Fairmount  Chemical  Co.,  Inc 

Falk  &  Co 

Farley  &  Loetscher  Manufacturing  Co. 

Federal  Color  Laboratories,  Inc 

Federal  Laboratories,  Inc 

Federal  Varnish  Co 

Felton  Chemical  Co.,  Inc 

Ferbert-Schorndorfer  Co 

Fine  Colors  Co 

Fine  Organics,  Inc 

Firestone  Tire  &  Rubber  Co 

Forbes  Varnish  Co 

Ford  Motor  Co 

Foster-Heaton  Co 

France,  Campbell  &  Darling,  Inc 


Franco-American  Chemical  Works 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office). 


Franks  Chemical  Products  Co.,  Inc 

Fries  Bros.,  Inc 

Fries  &  Fries,  Inc 

Fries,  George  G.,  &  Co.,  Inc 

Fritzsche  Bros.,  Inc 

Fuller,  W.  P.,  &  Co 

Fulton  Aniline  Corp 

Ganc's  Chemical  Works,  Inc 

Gebauer  Chemical  Co 

Gelatin  Products  Co 

General    Aniline    Works    Division,    General 

.\niline  &  Film  Corp. 

General  Biochemicals,  Inc 

General  Chemical  Co 

General  Electric  Co 

General  Foods  Corp 

General    Mills,    Inc.,    Special    Conmiodities 

Division. 

George,  P.  D.,  Co 

Gilman  Paint  &  Varnish  Co 

Glidden  Co 

GIvco  Products  Co.,  Inc 

Goodrich,  B.  F.,  Co. 

Goodyear  Tire  &  Rubber  Corp 

Grand  Rapids  Varnish  Corp 


Gulf  Oil  Corp 

Guvan  Color  &  Chemical  Works 

Halowax  Products  Division,  Union  Carbide 
&  Carbon  Corp. 

Hamilton  Laboratories,  Inc 

Hampden  Color  &  Chemical  Co 

Harbor  Plvwood  Corp 

Hardesty,  W.  C.  Co.,  Inc 

Harmon  Color  Works,  Inc 

Harris  Chemical  Co.,  Inc 

Harshaw  Chemical  Co 

Hartman-Leddon  Co.,  Inc 

Hart  Products  Corp ". 

Hercules  Powder  Co 

Heresite  &  Chemical  Co 


180  Varick  St.,  New  York  14,  N.  Y. 
Midland,  Mich. 

250  East  43d  St.,  New  York  17,  N.  Y. 
Wilmington,  Del.  (10th  and  Market  Sts.) 
Walck  Road,  North  Tonawanda  4,  N.  Y. 
5000  Summerdale  Ave.,  Philadelphia  24,  Pa. 
924  Bergen  Ave.,  Jersey  City  6,  N.  .1. 
2307  North  11th  St.,  St.  Louis  6,  Mo. 
55  Berry  St.,  Brooklyn  11,  N.  Y. 
Lexington  Bldg.,  Baltimore  1,  Md. 
343  State  St.,  Rochester  4.  N.  Y. 
10  Pine  St.,  South  Norwalk,  Conn. 
P.  O.  Box  45,  Bloomfield,  N.  J. 

732  Federal  St.,  Chicago  5,  111. 

113  E.  Centre  St.,  Nutley  10,  N.  .1. 

16  West  Jersey  St.,  Elizabeth  4,  N.  J. 

60  East  42d  St.,  New  York  17,  N.  Y. 

4300  Carew  Tower,  Cincinnati  2,  Ohio. 

399  Cod  wise  .\ve..  New  Brunswick,  N.  J. 

59  East  Madison,  Chicago  3,  III. 

84-40  101  St.,  Richmond  Hill  18,  N.  Y,_ 

405  Lexington  Ave.,  New  York  17,  N.  Y. 

Midland,  Mich. 

1666   North  Highland  Ave.,   Los  Angeles  28, 

Calif. 
600  Ferry  St.,  Newark,  N.  J. 
P.  O.  Box  1075,  Pittsburgh  30.  Pa. 
7th  and  White  Sts.,  Dubuque,  Iowa. 
4633  Forest  Ave.,  Norwood  12,  Ohio. 
185  4Ist  St.,  Pittsburgh  1.  Pa. 
.333  South  Peoria  St.,  Chicago  7,  111. 
599  .lohnson  Ave.,  Brooklyn  6,  N.  Y. 
12815  Elmwood  Ave.,  Cleveland  11,  Ohio. 
21-29  McBride  Ave.,  Paterson,  N.  J. 
211  East  19th  St.,  New  York  3,.N.  Y. 
1200  Firestone  Parkway,  Akron  17,  Ohio. 
3800  West  14.3d  St.,  Cleveland  11,  Ohio. 
3000  Schaefer  Road,  Dearborn,  Mich. 
16  East  5th  St.,  Paterson  4,  N.  J. 
Michigan  Ave.  and   Monroe  St.,   Kenilworth, 

N.  J. 
(Amalgamated   with   Pennsylvania   Alcohol   & 

Chemical  Co.  in  1943.) 
55  .3.3d  St.,  Brooklyn  32,  N.  Y. 
92  Reade  St.,  New  York  13,  N.  Y. 

13  East  37th  St.,  New  York  16,  N.  Y. 
11-25  44th  Road,  Long  Island  City  1,  N.  Y. 
76  9th  Ave.,  New  York  11,  N.  Y. 

.301  Mission  St.,  San  Francisco  19,  Cahf. 
91  Oliver  St.,  Boston,  Mass. 
43  West  16th  St.,  New  York  11,  N.  Y. 
9410  St.  Catherine  Ave.,  Cleveland,  Ohio. 
9425  Grinnell  Ave.,  Detroit  13,  Mich. 
435  Hudson  St.,  New  York  14,  N.  Y. 

Laboratory  Park,  Chagrin  Falls,  Ohio. 

40  Rector  St.,  New  York  6,  N.  Y. 

1  River  Road,  Schenectady  5,  N.  Y. 
250  Park  Ave.,  New  York  17,  N.  Y. 
400  South  4th  St.,  Minneapolis  15,  Minn. 

5200  North  2d  St.,  St.  Louis  7,  Mo. 

West  8th  and  Pine  Sts.,  Chattanooga  1,  Tenn. 

11001  Madi,son  Ave.,  Cleveland  14,  Ohio. 

148  Lafavette  St.,  New  York,  N.  Y. 

500  South  Main  St.,  Akron  18,  Ohio. 

1144  East  Market  St.,  Akron  5,  Ohio. 

.565   Godfrey  Ave.,   SW.,   Grand   Rapids   2, 

Mich. 
Gulf  Bldg.,  Pittsburgh,  Pa. 
P.  O.  Box  1088,  Huntington,  W.  Va. 
.30  East  42d  St.,  New  York  17,  N.  Y. 

120  Patton  Ave.,  Asheville,  N.  C. 
161  Armory  St.,  Springfield,  Mass. 
Hoquiam,  Wash. 

41  East  42d  St.,  New  York,  N.  Y. 
P.  O.  Box  11.58,  Paterson,  N.  J. 

14  Mill  St.,  New  Haven,  Conn. 

1945  East  97th  St.,  Cleveland  6,  Ohio. 
6010  Haverford  Ave.,  Philadelphia  31,  Pa. 
1440  Broadway,  New  York  18,  N.  Y. 
900  Market  St.,  Wilmington  99,  Del. 
822  South  14th  St.,  Manitowoc,  Wis. 


138  UNITED  STATES  TARIFF  COMMISSION 

Table  19. — Synthetic  organic  chemicals:  Directory  of  manufacturers — Continued 


Name  of  company 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office). 


Heyden  Chemical  Corp 

Hilton-Davis  Chemical  Co 

Hoffmann-La  Roche,  Inc 

Holland  Color  &  Chemical  Co.  (formerly  Hol- 
land Aniline  Dye  Co.) 

Hooker  Electrochemical  Co 

Huber,  J.  M.,  Inc 

Huggins,  James,  &  Son 

Humble  Oil  &  Refining  Co 

Huron  Milling  Co 

Hycar  Chemical  Co 

Hynson,  Westcott  &  Dunning,  Inc 

Imperial  Paper  &  Color  Corp 

Industrial  Dyestuff  Co 

Inland  Alkaloid  Co ; 

Innis,  Speiden  &  Co 

Inter-Coastal  Paint  Corp 

Interlake  Chemical  Corp 

Ironsides  Co 

Irvington  Varnish  &  Insulator  Co 

Jamestown  Paint  &  Varnish  Co 

Jamieson,  C.  E.,  &  Co ^-  •  •  • 

Jennison-Wright  Corp \  .  .  . 

Jersey  Central  Power  &  Light  Co 

Joanite  Corp 

Johnson,  Charles  Eneu,  &  Co 

Johnson,  S.  C,  &  Son,  Inc 

Joliet  Wall  Paper  Mills 

Jones-Dabney  Co.  Division  of  Devoe  &  Rey- 
nolds Co.,  Inc. 

Jones  &  Laughlin  Steel  Corp 

Kay  &  Ess  Co 

Kay-Fries  Chemicals,  Inc 

Keery,  Thos.,  Chemicals  Co 

Kennecott  Copper  Corp.,  Chino  Mines  Divi- 
sion. 

Kentucky  Color  &  Chemical  Co 

Kessler  Chemical  Co.,  Inc 

Keto  Chemical  Co.,  Inc 

Keystone  Color  Works,  Inc 

Keystone  Varnish  Co 

Kinetic  Chemicals,  Inc 

Kings  County  Lighting  Co 

Knoedler,  A.,  Co 

Kohnstamm,  H.,  &  Co.,  Inc 

Koppers  Co 

Krumbhaar  Chemicals,  Inc 

Lake  Erie  Chemical  Co 

Lakeside  Laboratories,  Inc 

Lamon  Chemical  Corp 

LaMotte  Chemical  Products  Co 

Laucks,  I.  F.,  Inc 

Lauxite  Corp 

Lehigh  Briquetting  Co 

Lennig,  Charles,  &  Co 

Lever,  C,  Co.,  Inc 

Levey,  Fred'k  H.,  Co.,  Inc 

Lewis,  John  T.,  &  Bros.  Co 

Lewis  Tar  Products  Co 

Lewistown  Corp 

Eli  Lilly  &  Co 

Lilly  Varnish  Co 

Lion  Oil  &  Refining  Co 

Liquid  Carbonic  Corp.  (formerly  Cheney 
Chemical  Co.) 

Looto  Co 

Long  Island  Lighting  Co 

Long,  Chas.  R.,  Jr.,  Co.,  Inc 

Lucas,  John,  &  Co.,  Inc 

Lucidol  Corp 

Lueders,  George,  &  Co 

Maas  &  Waldstein  Co 

M  &  M  Wood  Working  Co 

Macher,  Wm.,  &  Son 

Madison  Gas  and  Electric  Co 

Magnolia  Petroleum  Co 

Magruder  Color  Co.,  Inc 

Makalot  Corp 

Mallard,  A.  E.,  Laboratories 

Mallinckrodt  Chemical  Works 


50  Union  Square,  New  York  3,  N.  Y. 
2235  Langdon  Farm  Rd.,  Cincinnati  12,  Ohio. 
324-424  Kingsland  Rd.,  Nutley  10,  X.  J. 
R.  F.  D.  «4,  Holland,  Mich. 

Buffalo  Ave.  and  47th  St.,  Niagara  Falls,  X.  Y. 

460  West  .34th  St.,  New  York,  N.  Y. 

239  Medford  St.,  Maiden  48,  Mass. 

Humble  Bldg.,  Houston,  Tex. 

9  Park  Place,  New  York,  N.  Y. 

335  South  Main  St.,  Akron  8,  Ohio. 

1030  North  Charles  St.,  Baltimore  1,  Md. 

Glens  Falls,  N.  Y. 

Massasoit'Ave.,  East  Providence  14,  R.  I. 

Tipton,  Ind. 

117  Liberty  St.,  New  York  6,  N.  Y. 

1248  Walnut  Ave.,  East  St.  Louis,  III. 

1900   L^nion   Commerce   Bldg.,   Cleveland    14, 

Ohio. 
Box  1999,  Columbus  15,  Ohio. 
6  Argyle  Terrace,  Irvington  11,  JN'.  J. 
Jamestown,  Pa. 

1962-1980  Trombly  Ave.,  Detroit  11,  Mich. 
2463  Broadway,  Toledo  1,  Ohio. 
501  Grand  Ave.,  A.sbury  Park,  N.  J. 
10-02  44th  Drive,  Long  Island  City,  N.  Y. 
10th  and  Lombard  Sts.,  Philadelphia  47,  Pa. 
1525  Howe  St.,  Racine,  Wis. 
225  Logan  Ave.,  Joliet,  111. 
1481  South  11th  St.,  Louisville  8,  Ky. 

3d  Ave.  and  Ross  St.,  Pittsburgh,  Pa. 

825  Kiser  St.,  Dayton  1,  Ohio. 

180  Madison  Ave.,  New  York  16,  N.  Y. 

Cadosia,  N.  Y. 

Hurley,  N.  M. 

600  North  34th  St.,  Louisville  12,  Ky. 

State  Road  and  Cottman  Ave.,  Philadelphia 

35,  Pa. 
40-33  23d  St.,  Long  Island  City,  N.  Y. 
151  West  Gay  Ave.,  York,  Pa. 
71  Otsego  St.,  Brooklyn  31,  N.  Y. 
duPont  Bldg.,  Wilmington  98,  Del. 
6740  4th  Ave.,  Brooklyn  20,  N.  Y. 
717  North  Prince  St.,  Lancaster,  Pa. 
87  Park  Place,  New  York  7,  N.  Y. 
430  Seventh  Ave.,  Pittsburgh  19,  Pa. 
24  Jacobus  Ave.,  South  Kearny,  N.  J. 
.3650  East  93d  St.,  Cleveland  13,  Ohio. 
1707  East  North  Ave.,  Milwaukee  1,  Wi.*. 
551  Fifth  Ave.,  New  York  17,  N.  Y. 
McCormick  Bldg.,  Baltimore,  Md. 
911  Western  Ave.,  Seattle  4,  Wash. 
116  South  Niagara  St.,  Lockport,  N.  Y. 
First  National  Bank  Bldg.,  Dickinson,  N.  Dak. 
222  West  Washington  Square,  Philadelphia  .'>, 

Pa. 
Howard  and  Huntington  Sts.,  Philadelpliia  3.'>, 

Pa 
41  East  42d  St.,  New  York  17,  N.  Y. 
910  Widener  Bldg.,  Philadelphia  7,  Pa. 
P.  O.  Box  A,  Lyons,  III. 
221  West  57th  St.,  New  York,  N.  Y. 
740  South  Alabama  St.,  Indianapolis  6.  lad. 
666  South  California  St.,  Indianapolis  7,  liid. 
Exchange  Bldg.,  El  Dorado,  Ark. 
2929  East  67th  St.,  Cleveland  4,  Ohio. 

791  Hampden  Ave.,  St.  Paul  4,  Minn. 

250  Old  Country  Road,  Mineola,  N.  Y. 

1630-44  West  Hill  St.,  Louisville  10,  Ky. 

Haddon  Ave.,  Gibbsboro,  N.  J. 

1740  Military  Rd.,  Buffalo  5,  N.  Y. 

427  Washington  St.,  New  York  13,  N.  Y. 

438  Riverside  Ave.,  Newark  4,  N.  J. 

2301  North  Columbia  Blvd.,  Portland,  (^reg. 

1533  West  Clearfield  St.,  Philadelphia,  Pu. 

100  North  Fairchild  St.,  Madison,  Wis. 

P.  O.  Box  900,  Dallas  1,  Tex. 

2385    Richmond    Terrace,    Staten    Island    2, 

N.  Y. 
262  Washington  St.,  Boston  9,  Mass. 
.3021  Wabash  Ave.,  Detroit  16,  Mich. 
3600  North  2d  St.,  St.  Louis  7,  Mo. 


SYNTHETIC  ORGANIC  CHEMICALS,  1941-43  139 

Table  19. —  Syyithctic  organic  chemicals:  Directory  of  maniifacfvrers — Continued 


Name  of  company 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office). 


Maltbie  Chemical  Co 

Marblctte  Corp 

Marco  Chemicals,  Inc 

Marietta  Dyestuffs  Co 

Marietta  Paint  &  Color  Co 

Martin  Laboratories 

Marx,  Max,  Color  &  Chemical  Co. 

Maschmeijer,  A.,  Jr.,  Inc 

Mathieson  Alkali  Works,  Inc 

IMaxim  Chemical  Co.,  Inc 

May,  Otto  B.,  Inc 

Maywood  Chemical  Works 

Mead,  Johnson  &  Co 


Mearl  Corporation 

Mepham,  Geo.  S.,  Corp 

Merck  &  Co.,  Inc 

Merrell,  Wm.  S.,  Co 

Metropolitan  Edison  Co 

Mever,  Herman,  Drug  Co.,  Inc.  (Hema  Drug 
Co.) 

Michigan  Chemical  Corp 

Midland  Industrial  Finishes  Co 

Midwest  Solvents  Co 

Mid-West  Tar  Products  Corp 

Miles  Laboratories,  Inc 

Millergum  Products  Co 

Millmaster  Chemical  Co 

Milwaukee  Gas  Light  Co 

Minerec  Corp 

Monsanto  Chemical  Co 

Montrose  Chemical  Co 

Morton  Chemical  Co _ 

Murphy  Varnish  Co " 

Nason,  R.  N.,  &  Co 

Nassau  &  Suffolk  Lighting  Co 

National  .\nilinc  Division,  Allied  Chemical  & 
Dye  Corp. 

National  Oil  Products  Co 

Naugatuck  Chemical  Division  of  V .  S.  Rub- 
ber Co. 

Neo-Quest  Chemical  Co.,  Inc 

Neville  Co 

New  Bedford  Gas  &  Edison  Light  Co 

Newport  Industries,  Inc 

New  York  Color  &  Chemical  Co.,  Inc.  (Divi- 
sion of  American  Dyewood  Co.) 

New  York  Quinine  and  Chemical  Works,  Inc. 

New  York  &  Richmond  Gas  Co 

Niacet  Chemicals  Corp 

Niagara  Chlorine  Products  Co 

Niagara  Smelting  Corp 

Niagara  Wall  Paper  Co 

Nonweiler,  A.  P.,  Co 

Nord  &  Co.,  Inc 

Norda  Essential  Oil  &  Chemical  Co.,  Inc 

Northwestern  Chemical  Co 

Novocol  Chemical  Mfg.  Co.,  Inc 

Nubian  Paint  &  Varnish  Co 

Nutrition  Research  Laboratories 

Ohio-Apex,  Inc 

Ohio  Chemical  &  Mfg.  Co 

Ohio  Oil  Co 

Oldbury  Electro  Chemical  Co 

Old  Hickory  Chemical  Co 

Orbis  Products  Corp 

Organic  Products,  Inc 

Osborn,  C.  J.,  Co. 

Pan-American  Refining  Corp 

Panelyte  Corp 

Paraffine  Companies,  Inc 

Paramet  Chemical  Corp 

Parke,  Davis  &  Co 

Patent  Chemicals,  Inc 

Paul-Lewis  Laboratories,  Inc 

Peerless  Color  Co 

Pennsylvania  Alcohol  &  Chemical  Corp 

Pennsylvania  Coal  Products  Co 

Pennsylvania  Industrial  Chemical  Corp 

Pennsylvania  Power  &  Light  Co 

Peoples  Gas  Light  &  Coke  Co 

Pfanstiehl  Chemical  Co 

Pfizer,  Chas.,  &  Co.,  Inc 

Pharma  Chemical  Corp 

Philadelphia  Gas  Work?  Co 


240  High  St.,  Newark  2,  N.  J. 

37  30th  St.,  Long  Island  City  1,  N.  Y. 

Sewaren,  N.  J. 

401  Peoples  Bank  Bldg.,  Marietta,  Ohio. 

Greene  and  Acme  Sts.,  Marietta,  Ohio. 

2.51  East  1.39th  St.,  New  York  51,  N.  Y. 

192  Coit  St.,  Irvington  11,  N.  J. 

43  West  16th  St.,  New  York  11,  N.  Y. 
60  East  42d  St.,  New  York  17,  N.  Y. 

44  CHff  St.,  New  York  7,  N.  Y. 
196-214  Niagara  St.,  Newark  5,  N.  J. 
100  West  Hunter  Ave.,  Maywood,  N.  J. 

St.  Joseph  .Ave.  and  Pennsylvania  St.,  Evana- 

ville  21,  Ind. 
153  Waverly  Place,  New  York  14,  N.  Y. 
2001  Lynch  Ave.,  East  St.  Louis,  111. 
Lincoln  Ave.,  Rahway,  N.  J. 
Amity  Rd.,  Cincinnati  15,  Ohio. 
412  Washington  St.,  Reading,  Pa. 
66-38  Clinton  Ave.,  Maspeth,  N.  Y. 

500  North  Bankson  St.,  St.  Louis,  Mich. 

East  Water  St.,  Waukegan,  111. 

1300  Main  St.,  .\tchison,  Kans. 

332  South  Michigan  Ave.,  Chicago  4,  111. 

1127  Myrtle  St.,  Elkhart,  Ind. 

6450  North  66th  Place,  Chicago,  111. 

.551  Fifth  Ave.,  New  York  17,  N.  Y. 

626  East  Wisconsin  Ave.,  Milwaukee,  Wis. 

120  Broadway,  New  York  5,  N.  Y. 

1700  South  2d  St.,  St.  Louis  4,  Mo. 

120  Lister  Ave.,  Newark  5,  N.  J. 

2110  High  Point  Road,  Greensboro,  N.  C. 

224  McWhorter  St.,  Newark  1,  N.  J. 

151  Potrero,  San  Francisco  3,  Calif. 

250  Old  Country  Road,  Mineola,  N.  Y. 

40  Rector  St.,  New  York  6,  N.  Y. 

First  and  Essex  Sts.,  Harrison,  N.  J. 
12.30  6th  Ave.,  New  York  20,  N.  Y. 

2  Albany  St.,  New  York,  N.  Y. 
Neville  Island,  Pittsburgh  25,  Pa. 
693  Purchase  St.,  New  Bedford,  Mass. 
P.  O.  Box  911,  Pensacola,  Fla. 
374  Main  St.,  BelleviUe  9,  N.  J. 

99  North  11th  St.,  Brooklyn  11,  N.  Y. 

691  Bay  St.,  Staten  Island,  N.  V. 

4700  Pine  Ave.,  Niagara  Falls,  N.  Y. 

North  Transit  Road,  Lockport,  N.  Y. 

420  Lexington  Ave.,  New  York  17,  N.  Y. 

Walnut  Ave.  and  2d  St.,  Niagara  Falls,  N.  Y. 

P.  O.  Box  1007.  Oshkosh,  Wis. 

Broadway  and  Clark  St.,  Keyport,  N.  J. 

601  West  26th  St.,  New  York  1,  N.  Y. 

1263  North  70th  St.,  Wauwatosa  13,  Wis. 

2923  Atlantic  Ave.,  Brooklyn  7,  N.  Y. 

1856  North  LeClaire  Ave.,  Chicago,  111. 

4210  Peterson  Ave.,  Chicago  30,  111. 

P.  O.  Box  98,  Nitro,  W.  Va. 

1177  Marquette  St.,  Cleveland  14,  Ohio. 

539  South  Main  St.,  Findlav,  Ohio. 

P.  O.  Box  346,  Niagara  Falls,  N.  Y. 

P.  O.  Box  1480,  Richmond  12,  Va. 

215  Pearl  St.,  New  York  7,  N.  Y. 

Springdale,  Conn. 

1.32  Nassau  St.,  New  York  7,  N.  Y. 

P.  O.  Box  401,  Texas  City,  Tex. 

Enterprise  Ave.,  Trenton  4,  N.  J. 

47.5  Brannan  St.,  San  Francisco,  Calif. 

10-17  44th  Ave.,  Long  Island  City  1,  N.  Y. 

Foot  of  McDougall  Ave.,  Detroit  32,  Mich. 

.57  Wilkinson  Ave.,  Jersey  City  5,  N.  J. 

918  North  4th  St.,  Milwaukee  3,  Wis. 

521-535  North  Ave.,  Plainfield,  N.  J. 

Berry  Ave.,  Carlstadt,  N.  J. 

P.  O.  Box  C,  Petrolia,  Pa. 

120  State  St.,  Clairton,  Pa. 

9th  &  Hamilton  Sts.,  AUentown,  Pa. 

122  South  Michigan  Ave.,  Chicago  3,  111. 

104  Lakeview  Ave.,  Waukegan,  111. 

81  Maiden  Lane.  New  York  7,  N.  Y. 

175  .5th  Ave.,  New  York  10,  N.  Y. 

1800  North  9th  St.,  Philadelphia  22,  Pa. 


140  UNITED  STATES  TARIFF  COMMISSION 

Table  19. — Synthetic  organic  chemicals:  Directory  of  vianufacturers — Continued 


Name  of  company 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office). 


Phillips  Petroleum  Co 

Phoenix  Color  &  Chemical  Co.,  Inc 

Pitman-Moore  Co.,  Division  of  Allied  Labora- 
tories, Inc.  , 

Pittsberg  Chemical  Co 

Pittsburgh  Coke  &  Iron  Co 

Pittsburgh  Plate  Glass  Co 

Plaskon  Division,  Libbey-Owen-Ford  Glass 
Co. 

Polak  &  Schwarz,  Inc 

Polychemical  Co 

Pontiac  Varnish  Co 

Portland  Gas  &  Coke  Co 

Poughkeepsie  Dyestuff  Corp 

Pratt  &  Lambert  Inc 

Premo  Pharmaceutical  Labs.,  Inc 

Pruett-Schaffer  Chemical  Co 

Publicker,  Inc 

Pure  Chemicals  Mfg.  Corp 

Pure  Oil  Co 

Purocaine  Chemical  Co.,  Inc 

Pylam  Products  Co.,  Inc 

Pyridium  Corporation 

Quaker  Oats  Co 

Queens  Borough  Gas  &  Electric  Co 

Raybestos-Manhattan,  Inc 

Reichhold  Chemicals,  Inc 

Reilly  Tar  &  Chemical  Corp 

Reliance  Varnish  Co.,  Inc 

Remington  Arms  Co.,  Inc 

Republic  Creosoting  Co 

Resinous  Products  &  Chemical  Co 

Richards  Chemical  Works,  Inc 

Richardson  Co 

Richfield  Oil  Corp 

Richmond  Department  of  Public  Utilities.  . 

Rochester  Gas  &  Electric  Corp 

Rohm  &  Haas  Co 

Roosen,  H.  D.,  Co 

R.  S.  A.  Corp 

Ruberoid  Co 

Saint  Louis  County  Gas  Co 

Salvo  Chemical  Corp 

Schering  Corp 

Schering  &  Glatz,  Inc 

Schieffelin  &  Co 

Scholler  Bros.,  Inc 

Schuylkill  Chemical  Co 

Schwarz  Laboratories,  Inc 

Scranton-Spring  Brook  Water  Service  Co. .  . 

Searle,  G.  D.,  &  Co 

Seattle  Gas  Co 

Seeley  &  Co. ,  Inc 

Sepin  Laboratories 

Seydel  Chemical  Co 

Sharp  &  Dohme,  Inc 

Sharpies  Chemicals,  Inc 

Shawinigan  Resins  Corp 

Sheffield  Farms  Co.,  Inc 

Shell  Chemical  Co.  (Shell  Union  Oil  Corp.) . 

Shell  Oil  Co.,  Inc 

Sherman  Laboratories 

Sherwin-Williams  Co 

Simons,  Harold  L.,  Inc 

Sinclair  Refining  Co : 

Sinclair  &  Valentine  Co 

Skelly^Oil  Co 

Smith,  Kline  &  French  Laboratories 

Solvay  Process  Co 

Solvent  Chemical  Co.,  Inc : 

Sonoco  Products  Co 

Southern  California  Gas  Co 

Southern  Dyestuff  Corp 

Spaulding  Fibre  Co.,  Inc 

Springfield  Gas  Light  Co 

Squibb,  E.  R.,  &  Sons 

Staley,  A.  E.,  Manufacturing  Co 

Standard  Agricultural  Chemicals,  Inc 


Bartlesville,  Okla. 

24  1/2  Van  Houten  St.,  Paterson,  N.  .1. 

120()  Madison  Ave.,  Indianapolis  6,  Ind. 

3100  East  26th  St.,  Los  Angeles  23,  Calif. 
Grant  Bldg.,  Pittsburgh  19,  Pa. 
2000  Grant  Bldg.,  Pittsburgh  19,  Pa. 
2112  Sylvan  \ve.,  Toledo  6,  Ohio. 

667  Washington  St.,  New  York  14,  N.  Y. 
1938  Park  Ave.,  New  York  35,  N.  Y. 
30  Brush  St.,  Pontiac  12,  Mich. 
Public  Service  Bldg.,  Portland  4,  Oreg. 

77  North  Water  St.,  Poughkeepsie,  N.  Y. 
75  Tonawanda  St.,  Buffalo  7,  N.  Y. 

443  Broadway,  New  York  13,  N.  Y. 

Head  of  Tabor  St.,  Pittsburgh  4,  Pa. 

1429  Walnut  St.,  Philadelphia  2,  Pa. 

26-02  4th  St.,  Long  Island  City,  N.  Y. 

35  East  Wacker  Drive,  Chicago  1,  111. 

9-20  38th  Ave.,  Long  Island  City  1,  N.  Y. 

799  Greenwich  St.,  New  York  14,  N.  Y.    , 

21  Gray  Oaks  Ave.,  Yonkers  2,  N.  Y. 

141  West  Jackson  Blvd.,  Chicago  4,  111. 

250  Old  Country  Road,  Mineola,  N.  Y. 

61  Willett  St.,  Passaic,  N.  J. 

601    Woodward    Heights    Blvd.,    Detroit    20, 

Mich.. 
500  .5th  Ave.,  New  York  18,  N.  Y. 
915  East  Kentucky  St.,  Louisville  4,  Ky. 
939  Barnum  Ave.,  Bridgeport  2,  Conn. 
1615   Merchants   Bank  Bldg.,   Indianapolis  4, 

Ind. 
222  West  Washington  Square,  Philadelphia  5, 

Pa. 
Warren  and  Morris  Sts.,  Jersey  Citv  2,  N.  J. 
27th  and  Lake  Sts.,  Melrose  Park,  III. 
555  South  Flower  St.,  Los  Angeles  13,  Calif. 
Room  317,  City  Hall,  Richmond  19,  Va. 
89  East  Ave.,  Rochester  4,  N.  Y. 
222  West  Washington  Square,  Philadelphia  .", 

Pa 

78  2dth  St.,  Brooklyn  32,  N.  Y. 
Ardsley,  N.  Y. 

.500  .5th  Ave.,  New  York  18,  N.  Y. 

231  West  Lockwood  Ave.,  Webster  Grove,  Mo. 

Rothschild,  Wis. 

2  Broad  St.,  Bloomfield,  N.  J. 

113  West  18th  St.,  New  York  11,  N.  Y. 

16-30  Cooper  Square,  New  York  3,  N.  Y. 

Collins  and  Westmoreland    Sts.,    Philadelphia 

34,  Pa. 
2346  Sedgley  Ave.,  Philadelphia,  Pa. 
202  East  44th  St.,  New  York  17,  N.  Y. 
30  North  Franklin  St.,  Wilkes-Barre,  Pa. 
P.  O.  Box  5110,  Chicago  80,  111. 
1511  4th  Ave.,  Seattle  11,  Wa.sh. 
136  Liberty  St.,  New  York  6,  N.  Y. 
Box  185,  Station  A,  San  Diego,  Calif. 
225  Mercer  St.,  Jersev  Citv  2,  N.  J. 
640  North  Broad  St.,  Phila(leli)hia  1,  Pa. 
123  South  Broad  St.,  Philadelphia  9,  Pa. 
644  Monsanto  Ave.,  Springfield  2,  Mass. 
,524  West  57th  St.,  New  York  19,  N.  Y. 

100  Bush  St.,  San  Francisco  4,  Calif. 
50  West  50th  St.,  New  York  20,  N.  V. 
14600  P^ast  Jefferson  Ave.,  Detroit,  Mich. 

101  Prospect  Ave.,  N.  W.,  Cleveland  1,  Ohio. 
11-25  44th  Road,  Long  Island  City  1,  N.  Y. 
630  5th  Ave.,  New  York  20,  N.  Y. 

611  West  129th  St.,  New  York  27,  N.  Y. 

P.  O.  Box  1650,  Tulsa  2,  Okla. 

105  North  5th  St.,  Philadelphia  5,  Pa. 

P.  O.  Box  271,  Syracuse  1,  N.  Y. 

341  Commercial  St.,  Maiden,  Mass. 

Hartsville,  S.  C. 

Box  3249,  Los  Angeles  54,  Calif. 

P.  O.  Box  1045,  Charlotte  1,  N.  C. 

310  Wheeler  St.,  Tonawanda,  N.  Y. 

35  State  St.,  Springfield  2,  Mass. 

745  5th  Ave.,  New  York  22,  N.  Y. 

Decatur,  111. 

1301  Jefferson  St.,  Hoboken,  N.  J. 


SYNTHETIC  ORGANIC  CHEMICLAS,  1941-43  141 

Ta9LE  19. — Sytithetic  orgaixic  chemicals:  Directory  of  vianufacturers — -Continued 


Name  of  company 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  oflBce). 


Standard  Alcohol  Co 

Standard  Brands,  Inc 

Standard  Chemical  Products,  Inc 

Standard  Chlorine  Chemical  Co 

Standard  Naphthalene  Products  Co 

Standard  Oil  Co.  of  California 

Standard  Oil  Co.  of  Indiana 

Standard  Oil  Co.  of  Louisiana 

Standard  Oil  Co.  of  New  Jersey  (Stanco  Dis- 
tributors, Inc.) 

Standard  Ultramarine  Co 

Standard  Varnish  Works 

Stange,  Wm.  J.,  Co 

Stauffer  Chemical  Co.,  Inc 

Frederick  Stearns  &  Co 

Stresen-Reuter,  F.  A.,  Inc 

Stroock  &  Wittenberg  Corp 

Sun  Chemical  &  Color  Co.,  Division  General 
Printing  Ink  Corp. 

Sun  Oil  Co 

Synthetical  Laboratories 

Synthetic  Chemicals,  Inc 

Synthetic  Products  Co 

Swann  Chemical  Corp 

Taylor  Chemical  Corp 

Taylor  Fibre  Co 

Tennessee  Eastman  Corp 

Tennessee  Products  Corp 


Todd,  A.  M.,  Co 

Trojan  Powder  Co 

Trubek  Laboratories 

Tubize  Rayon  Corp 

Ugite  Sales  Corp 

Uhlich,  Paul,  &  Co.,  Inc 

LTnion  Bay  State  Co.,  Inc 

Union  Oil  Co.  of  California 

United    Color    &    Pigment    Co.    (American 
Cyanamid  Co.) 

U.  S.  Industrial  Chemicals,  Inc 

Utah  Copper  Co 

Valentine  &  Co.,  Inc 

Van  Ameringen-Haebler,  Inc 

Van  Camp  Laboratories 

Van  Dyk  &  Co.,  Inc 

Van  Schaack  Chemical  Works,  Inc 

Varcum  Chemical  Corp 


Velsicol  Corp 

Verley  Chemical  Co.,  Inc 

Verona  Chemical  Co 

Victor  Chemical  Works 

Virginia  Smelting  Co 

Vitamins,  Inc 

Vita-Var  Corp 

Wallace  &  Tiernan  Products,  Inc 

Wannamaker  Chemical  Co.,  Inc 

Warner- Jenkinson  Manufacturing  Co 

Warner,  William  R.,  &  Co.,  Inc 

Warwick  Chemical  Co 

Watertown  Manufacturing  Co 

Werner  Drug  &  Chemical  Co 

Western  Condensing  Co 

Western  Dry  Color  Co 

Westinghouse  Electric  &  Manufacturing  Co. 

Westvaco  Chlorine  Products  Corp 

Wetherill,  Geo.  D.,  Varnish  Co.,  Inc 


Wilhelm,  A.,  Co.,  Division  of  the  Glidden  Co. 

Wilmot  &  Cassidy,  Inc 

Wilson  Laboratories 

Winthrop  Chemical  Co.,  Inc 

Wisconsin  Power  &  Light  Co 

Wisconsin  Public  Service  Corp 

Wishnick-Tumpeer,  Inc 

Witte,  John  H.,  &  Sons 

Woburn  Chemical  Corp 

Wolff-Alport  Chemical  Corp 

Wolf,  Jacques  &  Co 

Worchester  Gas  Light  Co 

Wyeth,  John,  &  Bros.,  Inc 

Young  Aniline  Works,  Inc 

Zinser  &  Co.,  Inc 


26  Broadway,  New  York  4,  N.  Y. 
595  Madison  Ave.,  New  York  22,  N.  Y. 
1301  Jefferson  St.,  Hoboken,  N.  J. 
Jacobus  Ave.,  South  Kearny,  N.  J. 
Jacobus  Ave.,  South  Kearny,  N.  J. 
225  Bush  St.,  San  Francisco  20,  CaUf. 
910  South  Michigan  Ave.,  Chicago  80,  III. 
P.  O.  Box  551,  Baton  Rouge  1,  La. 
26  Broadway,  New  York  4,  N.  Y. 

24th  St.  and  5th  Ave.,  Huntington  18,  W.  Va. 
2600  Richmond  Terrace,  Staten  Island  3,  N.Y. 
2536  West  Monroe  St.,  Chicago  12,  111. 
420  Lexington  Ave.,  New  York  17,  N.  V. 
6533  East  Jefferson  Ave.,  Detroit  31,  Mich. 
2113  Medill  Ave.,  Chicago  47,  111. 
60  East  42d  St.,  New  York  17,  N.  Y. 
309  Sussex  St.,  Harrison,  N.  J. 

1608  Walnut  St.,  Philadelphia  3,  Pa. 

5558  Ardmore  Ave.,  Chicago  30,  111. 

57  Wilkinson  Ave.,  Jersey  City  5,  N.  J. 

1798  London  Road,  Cleveland  12,  Ohio. 

205  South  32d  St.,  Birmingham,  .\la. 

600  North  Broad  St.,  Phillipsburg,  N.  J. 

P.  O.  Box  470,  Norristown,  Pa. 

Kingsport,  Tenn. 

American  National  Bank  Bldg.,   Nashville  3, 

Tenn. 
1717  Douglas  Ave.,  Kalamazoo  99,  Mich. 
17  North  7th  St.,  Allentown,  Pa. 
State  Highway  17,  East  Rutherford,  N.  J. 
2  Park  Ave.,  New  York  16,  N.  Y. 
1401  Arch  St.,  Philadelphia  5,  Pa. 
90  West  St.,  New  York  6,  N.  Y. 
50  Harvard  St.,  Cambridge  42,  Mass. 
617  West  7th  St.,  Los  Angeles  14,  Calif. 
158-178  Mt.   Olivet  .Ave.,   Newark  5,   X.   J. 

60  East  42d  St.,  New  York  17,  N.  Y. 

Kearns  Bldg.,  Salt  Lake  City  12,  Utah. 

11  East  36th  St.,  New  York  16,  N.  Y. 

315  Fourth  Ave.,  New  York  10,  N.  Y. 

Terminal  Island,  Calif. 

57  Wilkinson  Ave.,  Jersey  City  5,  N.  J. 

3430  Henderson  St.,  Chicago  18,  111. 

East   Falls  and   Portage   Rd.,    Niagara   Falls, 

N.  Y. 
120  East  Pearson  St.,  Chicago  11,  111. 
100  Maine  St.,  Belleville  9,  N.  J. 
26  Verona  Ave.,  Newark  4,  N.  J. 
141  Jackson  Blvd.,  Chicago  4,  111. 
Jefferson  and  Third  Sts.,  West  Norfolk,  Va. 
809  West  58th  St.,  Chicago  21,  111. 
46  Albert  Ave.,  Newark  5,  N.  J. 
1  Mill  St.,  Belleville,  N.  J. 
79  East  Russell  St.,  Orangeburg,  S.  C. 
2526  Baldwin  St.,  St.  Louis  6,  ^lo. 
113  West  18th  St.,  New  York,  X.  Y. 
100  Pulaski  St.,  West  Warwick,  R.  I. 
Echo  Lake  Road,  Watertown,  Conn. 
914  Race  St.,  Cincinnati  2,  Ohio. 
935  East  John  St.,  Appleton,  Wis. 
600  West  52d  St.,  Chicago  9,  III. 
306  Fourth  Ave.,  Pittsburgh  30,  Pa. 
405  Lexington  Ave.,  New  York  17,  N.  Y. 
Haddon  Ave.  and  White  Horse  Pike,  Camden, 

N.  J. 
3d  and  Bern  Sts.,  Reading,  Pa. 
292  Freeman  St.,  Brooklyn  22,  X.  Y. 
4221  South  Western  Ave.,  Chicago  9,  111. 
170  Varick  St.,  New  York  13,  X.  Y. 
122  West  Washington  Ave.,  Madison  1,  Wis. 
1029  Xorth  Marshall  St.,  Milwaukee  1,  Wis. 
295  Madison  Ave.,  New  York  17,  N.  Y. 
Burlington,  Iowa. 

1200  Harrison  Ave.,  Harrison,  N.  J. 
1127  Irving  Ave.,  Brooklyn  27,  N.  Y. 
356  Lexington  Ave.,  Passaic,  N.  J. 
240  Main  St.,  Worchester  8,  Mass. 
1600  Arch  St.,  Philadelphia  3,  Pa. 
2731  Boston  St.,  Baltimore  24,  Md. 
Hastings  on  Hudson,  N.  Y. 


142  UNITED  STATES  TARIFF  COMMISSION 

Table  19. — Synthetic  organic  chemicals:  Directory  of  ■manufacturers — Continued 


Number 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office). 


512 
513 
514 
515 

516 
517 
518 

519 
520 
521 
522 
523 
524 
525 
526 

527 


United  Slates  Government  plants 
operated  by  Rubber  Reserve  Company 

Carbide  &  Carbon  Chemical  Corp 

Copolymer  Corp 

E.  I.  duPont  de  Nemours  &  Co 

Firestone  Tire  &  Rubber  Co 

General  Tire  &  Rubber  Co 

B.  F.  Goodrich  Co 

Goodyear  Synthetic  Rubber  Corp 

Humble  Oil  &  Refining  Co 

Koppers  Co.,  Inc 

Lion  Oil  Refining  Co 

National  Synthetic  Rubber  Corp 

Shell  Chemical  Co 

Standard  Oil  Co.  of  New  Jersey 

Sun  Oil  Co 

U.  S.  Rubber  Co 

Polymer  Corp 


Institute,  W.  Va.;  Louisville,  Ky. 

Baton  Rouge,  La. 

Louisville,  Ky. 

Akron,  Ohio;  Lake  Charles,  La.;  Port  Xeches, 

Tex. 
Baytown,  Tex. 

Borger, Tex. ; Louisville,  Ky.;  Port  Neches,  Tex. 
Akron,    Ohio;    Houston,    Tex.;    Los    Angeles, 

Calif. 
Baytown,  Tex. ;  Ingleside,  Tex. 
Kobuta,  Pa. 
El  Dorado,  Ark. 
Louisville,  Ky. 
Torrance,  Calif. 
Baton  Rouge,  La. 
Toledo,  Ohio. 
Institute,     W.     Va.;     Los     Angeles,     Calif., 

Naugatuck,  Conn. 
Sarnia,  Ontario,  Canada. 


•if  U.S.  GOVERNMENT  PRINTING   OFFICE:  1945—646064