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Given  By 

U.S.SUFT.  OFOornv. 


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UNITED   STATES   TARIFF   COMMISSION 

SYNTHETIC 
ORGANIC  CHEMICALS 

United  States  Production 
and  Sales,  1944 

Report;  No.  155  •  Seeond  Scries 


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BOSTON  PUBLIC  LIBRARY 


3  9999  06317  197  7 


RECENT  REPORTS  OF  THE  UNITED  STATES  TARIFF  COMMISSION 


Synthetic  Organic  Chemicals,  United   States  Production  and   Sales, 

1941-43,  Report  No.  153,  Second  Series,  1946 $0.30 

Post-War  Imports  and  Domestic  Production  of  Major  Commodities, 
Report  No.  154,  Second  Series,  1945  (in  response  to  S-  Res.  341,  78lh 
Cong.),  a  volume  of  1,321  pages,  is  availahle  in  separates,  as  follows: 

Price 

Section  1.  General  Introduction  and  Summary 10 

Section  2.  Chemicals,  Oils,  and  Paints 30 

Section  3.  Earths,  Earthenware,  and  Glassware 20 

Section  4.  Metals  and  Manufactures 30 

Section  5.  Wood  and  Wood  Manufactures 15 

Section  6.  Agricultural  and  Fishery  Products,  and  Beverages 40 

Section  7.  Textile  Fibers  and  Manufactures 30 

Section  8.  Papers  and  Books 15 

Section  9.  Sundries 25 

War  Changes  in  Industry  (reports  in  response  to  requests  from  House 
Ways  and  Means  Committee  and  Senate  Finance  Committee)  (proc- 
essed) ; 

No.    6.  Rubber 20 

No.  11.  Cigarette  Paper 10 

No.  12.  Refractory  Magnesia  (Magnesite) 15 

No.  13.  Hides  and  Skins  and  Leather 25 

No.  14.  Aluminum 25 

No.  15.  Iron  and  Steel 30 

No.  16.  Potatoes 15 

No.  17.  Petroleum 30 

For  sale  by  the  Superintendent  of  Documents,  U.   S.  Government  Printing  OfiBce 
'Washington  25,  D.  C,  at  the  prices  indicated 


UNITED   STATES   TARIFF   COMMISSION 


SYNTHETIC 
ORGANIC  CHEMICALS 

United  States  Production 
and  Sales,  1944 


UNDER    THE    GENERAL    PROVISIONS    OF    TITLE    III 
PART  II,  SECTION  332  OF  THE  TARIFF  ACT  OF  1930 


UNITED  STATES 

GOVERNMENT  PRINTING  OFFICE 

WASHINGTON  :  1946 


Report     No.     155  •  Second     Series 


(     PUSLIC      ) 


M.  S.  SUPERINTENDENT  Of  OOCUMyiT| 


§§t  m  \m 


J    r//V^ 


UNITED  STATES  TARIFF  COMMISSION 

Oscar  B.  Ryder,  Chairman 

Lynn  R.  Edminster»  Vice  Chairman 

Edgar  B.  Brossard 

E.  Dana  Durand 

George  McGill 

Sidney  Morgan,  Secretary- 


Address  all  communications 

UNITED  STATES  TARIFF  COMMISSION 

WASHINGTON  25,  D.  C. 


ACKNOWLEDGMENT 

In  the  preparation  of  this  report  the  Commission  had  the 

Bervices  of  James  H.  Hibben,  Martin  L.  Peller,  H.  Deborah  Keister, 

Bertha  M.  Robertson,  and  others  of  its  staff 


For  sale  by  the  Superintendent  of  Documents,  U.  S.  Government  Printing  Office,  Washington  25,  D.  C. 

Price  25  cents 


CONTENTS 

Page 

Introduction 1 

Summary 3 

PART  I.  PRODUCTION  AND  SALES  OF  TARS,  TAR  CRUDES, 
AND  CRUDES  DERIVED  FROM  PETROLEUM  AND  NATURAL 
GAS 

Tars 7 

Tar  crudes 8 

Crude  products  from  petroleum  and  natural  gas 12 

PART  11.  PRODUCTION  AND  SALES  OF  INTERMEDIATES  AND 
FINISHED  SYNTHETIC  ORGANIC  CHEMICALS,  BY  GROUPS 

General 13 

Intermediates 16 

Dyes 20 

Lakes  and  toners 30 

Medicinals 34 

Flavor  and  perfume  materials 38 

Plastics  materials 41 

Rubber-processing  chemicals 45 

Elastomers  (synthetic  rubbers) 47 

Surface-active  agents 48 

Plasticizers 50 

Miscellaneous  synthetic  organic  chemicals 52 

PART  III.  ALPHABETICAL  LIST  OF  INDIVIDUAL  PRODUCTS, 
BY  GROUPS,  AND  MANUFACTURERS 

Tar  crudes 57 

Crude  products  from  petroleum  and  natural  gas 58 

Intermediates 59 

Dyes 71 

Lakes  and  toners 87 

Medicinals 90 

Flavor  and  perfume  materials 98 

Plastics  materials 102 

Rubber-processing  chemicals ._  106 

Elastomers  (synthetic  rubbers) 108 

Surface-active  agents 109 

Plasticizers ^---  112 

Miscellaneous  synthetic  organic  chemicals ^^-  114 

Directory  of  manufacturers 126 

APPENDIX 

A.  Imports  of  coal-tar  intermediates  and  finished  products __  137 

B.  Research  workers  and  expenditures , 1.38 

^ -      - ^  ■      -  -  ^  - -•     ■-  ;.-•-.     ".-'hi 


IV  CONTENTS 

TABLES 

Summary  Page 

1.  Synthetic  organic  chemicals  and  their  raw  materials:  United  States 

production  and  sales,  1943  and  1944 3 

Part  I 

2.  Tar  and  tar  crudes:  Summary  of  production  and  sales  of  specified 

products,  average,  1937-41,  annual,  1942-44 9 

3 A.  Organic    chemicals:  United    States    production    and    sales    of    tar 

crudes,  1944 11 

4 A.  Organic   chemicals:  United    States   production   and   sales   of   crude 

products  from  petroleum  and  natural  gas  for  chemical  conversion, 

1944 12 

Part  II 

5.  Synthetic  organic  chemicals:  Summary  of  United  States  production 
and  sales  of  intermediates  and  finished  products,  average,  1938-42, 
annual,  1943-44 13 

6 A.  Synthetic  organic  chemicals:  United  States  production  and  sales  of 

cyclic  intermediates,  1944 17 

7A.  Synthetic  organic  chemicals:  United  States  production  and  sales  of 

coal-tar  dyes,  1944 21 

8.  Synthetic  organic  chemicals:  United  States  production  and  sales  of 

coal-tar  dyes,  by  chemical  class,  1944 27 

9.  Synthetic   organic   chemicals:  United  States  production  of  coal-tar 

dyes,  by  class  of  application,  average,  1938-42,  annual,  1943-44._         28 

10.  Synthetic  organic  chemicals:  United  States  sales  of  coal-tar  dyes,  by 

class  of  application,  average,  1938-42,  annual,  1943-44 28 

11.  Synthetic  organic  chemicals:  United  States  production  and  sales  of 

azoic  dyes  and  their  components,  1944 30 

12 A.  Synthetic  organic  chemicals:  United  States  production  and  sales  of 

lakes  and  toners,  1944 ^--         31 

13 A.  Synthetic  organic  chemicals:  United  States  production  and  sales  of 

medicinals,  1944 34 

14A.  Synthetic  organic  chemicals:  United  States  production  and  sales  of 

flavor  and  perfume  materials,  1944 39 

15 A.  Synthetic  organic  chemicals:  United  States  production  and  sales  of 

plastics   materials,    grouped   according   to   chemical   composition, 

1944 --         42 

16.      Synthetic  organic  chemicals:  United  States  production  and  sales  of 

plastics  materials,  grouped  according  to  use,  1944 44 

17A.  Synthetic  organic  chemicals:  United  States  production  and  sales  of 

rubber-processing  chemicals,  1944 46 

18 A.  Synthetic  organic  chemicals:   United    States   production  and  sales 

of  elastomers  (synthetic  rubbers),   1944 48 

19A.  Synthetic   organic    chemicals:    United  States  production  and  sales 

of  surface-active  agents,    1944 49 

20A.  Synthetic  organic  chemicals:  United  States  production  and  sales  of 

plasticizers,  1944 51 

21  A.  Synthetic  organic  chemicals:  United  States  production  and  sales  of 

miscellaneous  chemicals,  1944 52 


CONTENTS  V 

Part  III  Page 

3B.     Organic  chemicals:  Tar  crudes  for  which  United  States  production  or 

sales  were  reported,  identified  by  manufacturer,  1944 57 

4B.  Organic  chemicals:  Crude  products  from  petroleum  and  natural  gas 
for  chemical  conversion  for  which  United  States  production  or  sales 

were  reported,  identified  by  manufacturer,  1944 58 

6B.  Synthetic  organic  chemicals:  Cyclic  intermediates  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufac- 
turer, 1944 59 

7B.  Synthetic  organic  chemicals:  Coal-tar  dyes  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer, 
1944 J 71 

12B.  Synthetic  organic  chemicals:  Lakes  and  toners  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufac- 
turer, 1944 87 

13B.  Synthetic  organic  chemicals:  Medicinals  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer, 
1944 90 

14B.  Synthetic  organic  chemicals:  Flavor  and  perfume  materials  for 
which  United  States  production  or  sales  were  reported,  identified 
by  manufacturer,  1944 98 

15B.  Synthetic  organic  chemicals:  Plastics  materials  for  which  United 
States  production  or  sales  were  reported,  identified  by  manu- 
facturer, 1944 102 

17B.  Synthetic  organic  chemicals:  Rubber-processing  chemicals  for 
which  United  States  production  or  sales  were  reported,  identified 
by  manufacturer,  1944 106 

18B.  Synthetic  organic  chemicals:  Elastomers  (synthetic  rubbers)  for 
which  United  States  production  or  sales  were  reported,  identified 
by  manufacturer,  1944 108 

19B.  Synthetic  organic  chemicals:  Surface-active  agents  for  which 
United  States  production  or  sales  were  reported,  identified  by 
manufacturer,  1944 109 

20B.  Synthetic  organic  chemicals:  Plasticizers  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer, 
1944 --        112 

2 IB.  Synthetic  organic  chemicals:  Miscellaneous  chemicals  for  which 
United  States  production  or  sales  were  reported,  identified  by 
manufacturer,  1944 114 

22.  Synthetic  organic  chemicals:  Directory  of  manufacturers,  1944 126 

Appendix  •• 

23.  Coal-tar  intermediates  and  finished  coal-tar  products:  United  States 

imports  for  consumption,  classified  by  uses,  1942-44 137 


INTRODUCTION 

For  28  years  the  United  States  Tariff  Commission  has  issued 
reports  on  the  annual  production  and  sales  of  synthetic  organic 
chemicals  and  the  raw  materials  from  which  they  are  made.  The 
last  complete  report  covered  a  period  of  3  years,  1941-43.  The  report 
for  1944  mcludes  statistics  on  United  States  production  and  sales  of 
all  synthetic  organic  chemicals  and  their  raw  materials,  except  ex- 
plosives and  other  chemicals  manufactured  at  Government-owned 
Ordnance  plants.  These  statistics  were  compiled  from  information 
supplied  by  531  producing  companies,  a  list  of  which  is  given  in 
part  III. 

The  raw  materials  covered  by  this  report  are  obtained  by  various 
processes  from  coal,  crude  petroleum,  natural  gas,  and  other  natural 
sources.  Those  derived  from  coal  are  obtained  from  coke-oven  gas 
and  by  distillation  from  various  tars;  those  derived  from  crudfi 
petroleum  and  natural  gas  are  principally  the  result  of  cracking  and 
distillation  piocesses;  and  those  derived  from  other  natural  sources 
are  obtained  by  fermentation.  These  raw  materials  (principally  coal- 
tar  crudes  and  crude  petroleum  products)  represent  the  first  stage  in 
the  manufacture  of  synthetic  organic  chemicals.  Intermediates  are 
chemicals  derived  from  these  crudes  by  refining  or  by  synthesis  and 
represent  the  second  stage.  They,  in  turn,  are  used  chiefly  to  make 
finished  chemical  products.  Finished  products,  including  dyes,  rub- 
ber-processing chemicals,  and  plastics  materials,  are  not  usually  sold 
to  the  ultimate  consumer  but  to  mdustrial  concerns  for  use  in  their 
manufacturing  processes.  In  general,  organic  chemicals  extracted  or 
distilled  from  natural  (vegetable)  sources  such  as  wood  or  plants 
(except  grains)  are  beyond  the  scope  of  this  report. 

Unless  otherwise  noted,  the  data  on  chemicals  are  given  in  terms  of 
undiluted  materials.  Dyes,  however,  are  reported  in  terms  of  estab- 
lished commercial  concentrations.  The  items  included  are  grouped 
into  the  following  categories:  Crudes,  mtermediates,  dyes,  lakes  and 
toners,  medicinals,  flavor  and  perfume  materials,  plastics  materials, 
rubber-processing  chemicals,  elastomers,  plasticizers,  surface-active 
agents,  and  miscellaneous  chemicals.  Because  of  the  increasing 
importance  of  plasticizers  and  surface-active  agents,  statistics  for 
these  products  are  shown  m  separate  tables  for  the  first  time.  For- 
merly they  were  included  with  miscellaneous  synthetic  organic 
chemicals.  Organic  chemicals  made  from  grain  by  fermentation 
processes  are  included  with  miscellaneous  chemicals. 

Within  each  group  the  classification  of  items  follows  as  closely  as 
feasible  the  system  used  in  Group  19  of  the  Standard  Commodity 
Classification.^  In  accordance  with  the  practice  in  the  more  recent 
of  these  reports,  the  synthetic  organic  chemicals  in  each  group  are 
divided  according  to|their^known  chemical  structure  into  cyclic  and 

1  Executive  Office  of  the  President,  Bureau  of  ttie  Budget,  Standard  Commodity  Classification,  vol.  1, 
Tech.  Paper  26,  1943. 


2  UNITED    STATES    TARIFF    COMMISSION 

acyclic  compounds.  This  classification  roughly  parallels  the  dis- 
tinction between  chemicals  of  coal-tar  and  non-coal-tar  origin  followed 
in  earlier  reports.  The  cyclic  and  acyclic  classification  is  more 
accurate  as  important  products  which  formerly  were  exclusively  of 
coal-tar  origin,  are  now  made  from  non-coal-tar  sources. 

The  system  of  nomenclature  for  organic  chemicals  used  by  Chemical 
Abstracts,  a  publication  of  the  American  Chemical  Society,  is  em- 
ployed as  standard,  whenever  possible,  to  avoid  confusion  in  ter- 
minology and  errors  in  tabulation. 

Statistics  on  tar  and  tar  crudes  include  the  data  furnished  the 
United  States  Tariff  Commission  by  distillers  of  coal  tar  and  distillers 
and  producers  of  water-gas  and  oil-gas  tars  and  also  the  data  furnished 
the  Coal  Economics  Division  of  the  United  States  Bureau  of  Mines 
by  coke-oven  operators. 

Imports  of  coal-tar  intermediates  and  finished  coal-tar  products 
entering  the  United  States  under  paragraphs  27  and  28  of  the  Tariff 
Act  of  1930  are  given  in  the  appendix  of  the  repoit.  In  the  appendix 
there  is  also  given  a  tabulation  of  the  number  of  technical  research 
workers  and  the  cost  of  research  in  the  synthetic  organic  chemicals 
industry. 


SUMMARY 

Synthetic,  organic  chemicals  are  used  in  the  manufacture  of  many 
products  indispensable  to  the  Nation's  health,  comfort,  and  security. 
Production  of  these  chemicals  was  larger  in  1944  than  in  1943,  but 
the  percentage  increase  over  the  preceding  year  was  less.  The  out- 
put of  tars,  tar  crudes,  and  crudes  from  petroleum  and  natural  gas — 
the  raw  materials  from  which  most  of  the  synthetic  organic  chemicals 
are  made — was  also  larger  in  1944  than  in  1943. 

As  shown  in  table  1,  the  combined  production  of  synthetic  organic 
chemicals  and  their  raw  materials  (a  total  involving  much  duplica- 
tion) was  37  billion  pounds  in  1944  compared  with  32  billion  in  1943. 
In  1944,  sales  amounted  to  about  25  billion  pounds,  valued  at  2.4 
billion  dollars,  an  increase  of  20  percent  in  quantity  and  47  percent  in 
value  over  the  sales  in  1943.  The  quantities  sold  in  both  1944  and 
1943  represented  about  65  percent  of  the  production,  the  remainder 
being  consumed  chiefly  at  the  producing  plants  in  further  manu- 
facturing. 

Table  1.- — Synthetic   organic   chemicals   and   their   raw   materials:   United   States 
production  and  sales,  1943  and  1944 


Production 

Sales 

1943 

1944 

In- 
crease 
or  de- 
crease 
(-), 
1944 
over 
1943 

Quantity 

Value 

Chemical 

1943 

1944 

In- 
crease 
or  de- 
crease 
(-), 
1944 
over 
1943 

1943 

1944 

In- 
crease 
or  de- 
crease 
(-), 
1944 
over 
1943 

Grand  total ' 

Millien 
pounds 
32, 121 

Million 
pounds 
37,  318 

Percent 
16 

Million 
pounds 
20, 475 

Million 
pounds 
24,  589 

Percent 
20 

Million 

dollars 

1,609 

Million 

dollars 

2,358 

Percent 
47 

Tar2 

Tar  crudes  _  _.        _. 

9,280 
9,207 

1,565 

12,  069 

9,680 
9,905 

2,804 

14,  929 

4 
8 

79 

24 

5,679 
■   5,845 

1,617 

7,334 

5,131 
6,850 

2,547 

10,  061 

-10 

17 

58 
37 

30 

114 

34 
1,431 

27 
132 

194 

2,005 

-10 

16 

Crude  products  from  petro- 
leum and  natural  gas 

Synthetic    organic    chemi- 
cals, total 

471 
40 

Intermediates 

Dyes      

1,637 

144 

16 

56 

13 
654 

81 

573 
8,895 

2,143 

152 

19 

39 

16 

782 

93 

1,758 
9,927 

31 

6 

19 
-30 

23 
20 

15 

207 
12 

1,032 

145 
15 
52 

13 
568 

77 

553 
4,879 

1,556 
150 
18 
36 

16 
697 

85 

1,628 
5,875 

51 
3 

20 
-31 

23 
23 

10 

194 
20 

135 

105 

10 

140 

16 

178 

31 

156 
660 

185 

111 

14 

112 

19 
211 

42 

354 
957 

37 
6 

Lakes  and  toners  

40 

Medicinals 

Flavor  and  perfume  ma- 
terials  

Plastics  materials  ..    

-20 

19 
19 

Rubber-processing  chemi- 
cals    ..    _  

35 

Elastomers        (synthetic 
rubbers).  

127 

Miscellaneous  chemicals  _. 

45 

•  This  total  involves  much  duplication;  see  text. 
2  Partly  estimated. 


4  UNITED    STATES    TARIFF    COMMISSION 

Since  these  j&giires  include  the  production  of  tars,  crudes,  and  inter- 
mediates, as  well  as  the  production  of  finished  synthetic  organic 
chemicals,  the  totals  necessarily  include  considerable  duphcation. 

The  output  of  all  tare  in  1944  was  968  million  gallons  (9,680  million 
pounds),  or  about  4  percent  larger  than  in  1943.  Production  of  coal 
tar  was  about  30  milhon  gallons  larger  than  in  the  preceding  year, 
and  that  of  oil-gas  and  water-gas  tar  about  10  million  gallons  larger. 
The  quantity  of  tar  distilled,  however,  declined  from  682  million  gal- 
lons in  1943  to  633  milhon  in  1944.  This  decline  was  due  principally 
to  the  rise  in  consumption  of  tar  for  fuel  and  other  purposes. 

In  spite  of  the  decrease  in  the  quantity  of  tar  distilled,  the  output 
of  tar  crudes  was  8  percent  greater  in  1944  than  in  1943.  This  output 
was  possible  because  of  increased  production  of  tar  crudes  at  byproduct 
coke  ovens,  production  of  benzene  from  imported  ci'ude  materials, 
and  increased  production  of  toluene  from  petroleum.  Production  of 
toluene  from  petroleum  is  included  with  that  from  coal  tar,  since  in 
eaiher  years  the  data  could  not  be  shown  separately.  Alost  of  the 
toluene  went  into  the  manufacture  of  explosives,  and  most  of  the 
benzene  into  the  manufacture  of  synthetic  rubber  and  of  cumene, 
an  additive  for  aviation  gasoUne. 

The  most  striking  increase  in  production  of  all  organic  chemicals 
in  1944  was  in  the  group  of  organic  raw  materials  derived  from  petro- 
leum and  natural  gas.  The  computed  value  of  the  output  of  these 
materials  was  about  five  times  that  in  1943,  principally  because  of 
the  large  quantities  needed  in  the  manufacture  of  synthetic  rubber. 
Production,  from  petroleum,  of  butadiene,  one  of  the  principal  con- 
stituents of  synthetic  rubber,  was  valued  at  20  miUion  dollars  ui 
1943  and  143  million  in  1944. 

In  1944,  production  of  all  synthetic  organic  chemicals  (interme- 
diates and  finished  products)  totaled  14.9  billion  pounds,  an  increase 
of  24  percent  over  that  of  1943.  The  production  of  many  of  the 
important  synthetic  organic  chemicals  would  probably  have  been 
still  larger  in  1944  except  for  the  fact  that  the  output  was  limited  by 
Government  controls  and  that  the  quantities  produced  were  under 
Government  allocation.  Approximately  one-third  of  the  total  pro- 
duction was  consumed  at  the  producing  plants  in  the  manufacture 
of  other  finished  products. 

Because  of  the  continued  increase  in  the  demand  for  intermediates 
used  in  the  manufacture  of  explosives,  signal  smokes,  dyes,  synthetic 
rubber,  and  plastics,  the  output  of  intermediates  was  31  percent 
higher  in  1944  than  in  1943. 

Over-aU  production  of  dyes  and  of  lakes  and  toners  increased  only 
moderately  in  1944,  principally  because  the  TVar  Production  Board 
restricted  deliveries  for  nonmilitary  purposes.  Aledicinals  in  bulk 
were  the  only  group  of  finished  synthetic  organic  chemicals  which 
showed  a  decrease  m  1944  compared  with  1943;  production  in  1944 
was  39  million  pounds,  valued  at  120  million  dollar's,  a  substantial 
decline  from  the  56  milhon  pounds,  valued  at  150  million  dollars, 
produced  in  1943.  A  smaller  output  of  sulfa  drugs  and  lower  prices 
of  vitamins  were  important  factors  in  this  decline.  Statistics  on 
production  of  penicillm  are  not  included  with  the  total  for  medicinals 
in  1944;  the  limited  output  m  that  year  went  exclusively  to  the 
mihtary  forces. 


SYNTHETIC    ORGANIC    CHEMICALS,    19  44  5 

Production  of  flavor  and  perfume  materials  in  1944  was  23  percent 
greater  than  in  1943.  More  abundant  supplies  of  raw  materials 
during  the  year  allowed  increased  production  for  civilian  uses.  Large 
quantities  of  synthetic  flavoring  materials  were  also  used  in  Army 
rations. 

The  mounting  requirements  for  plastics  in  important  civilian  and 
military  uses  were  reflected  in  a  larger  output  of  plastics  materials 
in  1944,  chiefly  among  the  acyclic  (including  nonbenzenoid)  group. 
Production  of  all  plastics  materials,  except  cellulose  esters,  was  782 
million  pounds  compared  with  654  million  pounds  in  1943.  Plastics 
materials  made  from  cellulose  esters  are  not  covered  in  this  report. 

Production  of  rubber-processing  chemicals  in  1944  rose  about  15 
percent  over  the  level  of  1943,  because  of  the  increased  production 
of  synthetic  rubber. 

Elastomers  kiclude  synthetic  rubbers,  of  which  the  GE,-S  type  is 
the  most  important.  As  might  be  expected,  production  of  elasto- 
mers increased  more  than  that  of  any  other  group  of  finished  products. 
It  totaled  1.8  billion  pounds  in  1944,  more  than  a  200-percent  increase 
over  1943. 

Miscellaneous  synthetic  organic  chemicals  consist  of  products 
such  as  solvents,  insecticides,  and  other  chemicals  not  included  in 
any  other  group.  In  1944,  production  of  these  items  was  9.9  billion 
pounds,  an  increase  of  12  percent  over  that  of  1943. 


PART  I.    PRODUCTION  AND  SALES  OF  TARS,  TAR  CRUDES,  AND 
CRUDES  DERIVED  FROM  PETROLEUM  AND  NATURAL  GAS 

TARS 

The  quantity  of  crude  tars  produced  depends  on  the  demand  for 
coke  for  the  manufacture  of  steel  and  on  industrial  and  household 
consumption  of  manufactured  gas.  Coal  tar  is  recovered  principally 
as  a  byproduct  in  the  manufacture  of  coke.  Water-gas  tar  and  oil- 
gas  tar  are  byproducts  of  the  fuel-gas  industry.  Water  gas  is  pro- 
duced when  coal  or  coke  is  burned  in  an  atmosphere  of  steam;  water- 
gas  tar  is  made  by  carbureting  water  gas  with  oil  and  cracking  the 
mixture ;  oil-gas  tar  is  manufactured  in  the  process  of  cracking  certain 
types  of  oil  to  produce  fuel  for  household  and  industrial  purposes. 
Oil-gas  and  water-gas  tars  have  properties  intermediate  between  those 
of  petroleum  asphalt  and  coal  tar;  and,  although  they  contain  many 
crudes  that  are  recovered  from  coal  tar,  they  contain  these  crudes  in 
smaller  amounts  and  in  different  proportions.  Petroleum  asphalts 
are  not  considered  as  raw  materials  for  chemicals. 

In  1944,  the  amount  of  tars  recovered  from  all  sources  totaled  968 
million  gallons  compared  with  about  930  million  in  both  1942  and 
1943,  and  856  million  in  1941.  Of  the  output  in  1944,  788  million 
gallons  was  coal  tar — 768  million  gallons  of  which  was  produced  at 
byproduct  coke-oven  plants  and  20  million  gallons  at  coal-gas  retort 
plants.  The  output  of  water-gas  and  oil-gas  tar  in  1944  was  estimated 
at  180  million  gallons.  Statistics  on  production  and  consumption  of 
tars  in  1944  are  given  below: 

Source  and  use,  19U  ^000  gallons 

Production  of  tar,  total 967,  526 

Water-gas  and  oil-gas  tari 180,  000 

Coal  tar,2  total 787,  526 

Coal  tar  from  byproduct  coke-oven  plants,  total 767,  807 

Plants  not  owned  by  city  gas  companies 719,  145 

Plants  owned  by  city  gas  companies  (public  utilities) 48,  662 

Coal  tar  from  coal-tar  retort  plants 19,  719 

Consumption  of  tar,  total 974,  057 

Tar  consumed  by  distillation,  total 633,  428 

Water-gas  and  oil-gas  tar  distilled  by  producers  and  tar  distillers  ^--  35,  709 

Coal  tar  distilled  or  topped  by  byproduct  coke-oven  operators  ^ 200,  570 

Coal  tar  distilled  by  tar  distillers^ 397,  149 

Tar  consumed  chiefly  as  fuel  tar,  total 248,  365 

Water-gas  and  oil-gas  tar  consumed  as  fuel  ^ 74,  915 

Coal  tar  sold  or  consumed  as  fuel  by  byproduct  operators  ^ 173,  450 

As  fuel  under  boilers 863 

In  open-hearth  or  affihated  plants 156,  736 

Sold  as  fuel  by  byproduct  operators  to  affiliates 688 

Sold  as  fuel  by  byproduct  operators  to  others 15,  163 

See  footnotes  at  end  of  table. 

7 


UNITED    STATES   TARIFF    COMMISSION 

SouTce'and'use'JQU  1,000  gaUona 

Consumption  of  tar — Continued 

Tar  consumed  otherwise  than  by  distillation  or  as  a  fuel,  total 92,  264 

Coal  tar  from  retort  plants  sold  for  consumption  2« 19,  067 

Coal  tar  consumed  in  byproduct  plants  for  roads  and  upkeep 5,  166 

Coal  tar,  water-gas  and  oil-gas  tar  processed  at  tar  refineries  and 

consumed  in  roads  and  upkeep  at  such  refineries  ^ 68,  031 

1  Estimated.  Production  reported  to  the  U.  S.  Tariff  Commission  (150  million  gallons)  estimated  to 
represent  between  80  and  S5  percent  of  the  total  production. 

2  Reported  to  the  U.  S.  Bureau  of  Mines. 

3  Reported  to  the  U.  S.  Tariff  Commission. 

<  Represents  coal  tar  purchased  from  byproduct  coke-oven  and  retort  plants  and  distilled  by  chemical 
companies  operating  tar-distillation  plants  as  reported  to  the  U.  S.  Tariff  Commission.  Tar  purchased  and 
distilled  by  corporations  affiliated  with  the  byproduct  coke-oven  operators  is  included  in  the  quantity  of 
tar  distilled  and  topped  by  these  operators. 

'  Represents  data  reported  to  the  Federal  Power  Commission  by  gas-manufacturing  plants.  Consump- 
tion of  water-gas  and  oil-gas  tars  as  a  fuel  reported  to  the  U.  S.  Tariff  Commission  (63  million  gallons)  esti- 
mated to  represent  between  80  and  85  percent  of  total  consumption. 

9  Consumption  of  some  of  this  coal  tar  from  coal-tar  retort  plants  may  also  be  included  in  the  data  shown 
for  tar  distilled  at  tar  refineries. 

'  Partly  estimated;  includes  crude  tar  used  for  refining  and  blending  at  refinery  plants,  and  crude  tar 
consumed  in  plant  upkeep,  roads,  and  for  other  purposes  at  tar  refineries. 

Apparent  consumption  of  all  tars  in  1944  slightly  exceeded  produc- 
tion and  totaled  about  974  million  gallons.  Of  this  quantity,  633 
milhon  gallons  was  consumed  by  distillation. 

Byproduct  coke-oven  operators  distilled  or  partially  distilled 
(topped)  201  million  gallons  of  coal  tar  m  1944  compared  with  205 
million  in  1943;  tar-distilUng  companies  distilled  397  million  gallons 
in  1944  compared  with  408  million  gallons  m  1943.  The  total  quantity 
of  water-gas  and  oil-gas  tar  distilled  was  36  million  gallons  in  1944 
compared  with  69  million  in  1943.  Tar  consumed  as  fuel  m  1944 
amounted  to  248  million  gallons,  an  increase  of  about  44  million  gallons 
over  1943;  tar  thus  consumed  consists  chiefly  of  coal  tar  burned  in 
open-hearth  steel  plants  (or  other  plants  affiliated  with  those  owned 
by  byproduct  operators)  and  oil-gas  and  water-gas  tar  burned  as  fuel 
by  gas  companies.  In  1944  about  92  million  gallons  of  tar  was  con- 
sumed for  road  and  plant  maintenance,  in  blending,  and  for  other 
purposes  in  refineries  and  byproduct  plants.  Tars  consumed  for 
these  purjDoses  amounted  to  43  million  gallons  in  1943.  The  apparent 
increase  of  49  million  gallons  in  1944  was  due,  in  part,  to  more  complete 
reporting  by  producers  in  that  year. 

In  1944  sales  of  all  tars  amounted  to  513  million  gallons,  valued  at 
27  million  dollars;  of  this  quantity  it  is  estimated  that  84  million 
gallons,  valued  at  4.2  million  dollars,  represented  the  sales  of  oil-gas 
tar  and  water-gas  tar  combined. 

TAR  CRUDES 

Before  the  war,  United  States  production  of  coal-distillation  prod- 
ucts such  as  coke-oven  gas  and  coal  tar  was  large  enough  to  supply 
the  domestic  synthetic  organic  chemical  industry  with  most  of  its 
raw  materials  (coal-tar  crudes).  Dming  the  war,  however,  as  the 
demand  for  synthetic  organic  chemicals  increased,  the  supply  of 
crudes  from  coke-oven  gas  and  coal  tar  became  inadequate,  and 
efforts  were  made  to  obtain  more  of  these  crudes  from  other  sources, 
chiefly  from  petroleum  crude  hydrocarbons,^  from  natmal  gas,  and 
from  oil-gas  and  water-gas  tar. 

I  These  crudes  should  not  be  confused  with  crude  petroleum. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


9 


In  1944,  increased  quantities  of  benzene,  toluene,  and  various  crude 
tar  acids  were  derived  from  coal  tar,  oil-gas  tar,  and  water-gas  tar. 
In  addition,  large  quantities  of  crudes  such  as  cresylic  and  naphthenic 
acids,  toluene,  butadiene,  butanes,  and  ethylene  were  produced  from 
petroleum.  Ethylene,  butane,  butylene,  and  some  of  their  derivatives 
were  obtained  also  from  natural  gas  or  grain. 

Production  and  sales  of  the  principal  tar  crudes  (benzene,  toluene, 
naphthalene,  and  creosote  oil)  in  1942,  1943,  and  1944  and  the  average 
of  1937-41  are  shown  in  table  2. 


Table  2. — Tar  and  tar  crudes:     Summary  of  production  and  sales  of  specified 
products,  average,  1937-41,  annual,  194^-44 


Chemical  • 

Unit  of 
quantity 

Average, 
1937-41 

1942 

1943 

Increase 
or  de- 
crease 
(-),  1943 
over  1942 

1944 

Increase 
or  de- 
crease 
(-),  1944 
over  1943 

Tar:  Production  2 

1,000  gal_.-__ 

1,000  gal 

1,000  gal 

1,000  dol 

1,000  gal 

1,000  gal 

1,000  dol 

1,000  gal 

1,000  gal 

1,000  dol 

1,0001b 

1,0001b 

1,000  dol 

1,000  gal 

1,000  gal 

1,000  dol 

697,  600 

31,276 

28, 178 

3,616 

91,  465 

87,  278 
7,628 

25, 148 

24,  689 

5,884 

126,  213 

111,  468 

2,275 

113,  757 

112, 152 

13,  541 

931, 100 

85,2.57 
80,  779 
10, 487 

68,  662 

66,  698 

5,808 

43, 292 
43, 004 
11,  630 

250, 926 

220,  291 

5,407 

175, 297 
174,  733 
23,  779 

928, 100 

142, 047 
135, 960 

17, 864 

24, 390 

24,  530 

2,310 

96, 342 
90,  388 
28, 635 

305,  269 

235. 305 

5,785 

175, 186 
150,  669 
21,  714 

Percent 
-0.3 

66.6 
68.3 
70.3 

-64.5 
-63.2 
-60.2 

122.5 
110.2 
146.2 

21.7 
6.8 
7.0 

-.1 
-10.3 

-8.7 

967,  526 

178,  392 
172,  503 
23, 230 

(3) 
(3) 

134, 178 
127,  066 
39. 873 

301, 1.38 

240,  512 

5,898 

161,152 
163, 293 
22, 175 

Percent 
4.2 

Benzene: 

Production 

Sales 

Sales  value 

Motor  benzene: 
Production—    --     

25.6 
26.9 
30.0 

Sales 

Toluene: 
Production 

39.3 

Sales 

Sales  value    

40.6 
3Q.2 

Naphthalene: 
Production 

Sales 

-1.4 
2.2 

Sales  value    

1.9 

Creosote  oil: 
Production 

Sales          -  . 

-8.0 
4.2 

Sales  value       -  -- 

2.1 

'  For  detailed  explanation  of  data  included  in  statistics  shown  m  this  table,  see  table  3A. 

2  Includes  estimated  production  of  water-gas  and  oil-gas  tar. 

'  Data  reported  to  the  U.  S.  TarilT  Commission  by  tar  distillers  cannot  be  published  because  they  would 
disclose  the  operations  of  individual  companies.  Data  reported  to  the  U.  S.  Bureau  of  Mines  by  byproduct 
operators  were  as  follows:  Production,  18,557,000  gal.;  sales,  17,289,000  gal.;  and  sales  value,  $1,547,000. 

Large  quantities  of  benzene  were  used  to  make  styrene  in  1944. 
Styrene  constitutes  about  25  percent  by  weight  of  all  the  synthetic 
rubber  of  the  GK.-S  type,  which  is  used  chiefly  for  automobile,  bus,  and 
airplane  tires.  Additional  quantities  of  benzene  were  used  also  to  pro- 
duce synthetic  cumene  (isopropyl  benzene),  which  was  employed  as 
an  additive  to  aviation  fuel;  to  produce  monochlorobenzene  for 
making  phenol  and  other  products  used  in  plastics  materials ;  and  to 
produce  explosives,  dyes,  and  pharmaceuticals.  In  1944  production 
of  benzene  amounted  to  178  million  gallons,  or  36  million  gallons 
more  than  the  quantity  reported  in  1943,  the  largest  up  to  that  time. 
Part  of  the  extra  supply  was  obtained  by  distilling  imported  crude 
materials  to  produce  a  high-grade  benzene,  and  part  by  recovering 
more  benzene  from  motor  benzene,  a  mixture  containing  3  parts  of 
benzene  to  1  part  of  toluene.  Before  the  war,  motor  benzene  was 
made  in  large  quantities  as  a  motor  fuel,  but  during  the  war  production 
of  this  product  decreased  sharply. 


10  UNITED    STATES    TARIFF    COMMISSION 

In  1944  approximately  three  times  as  much  toluene  was  produced 
from  petroleum,  by  distillation,  cracking,  reforming,  hydrogenation, 
and  other  chemical  processes,  as  was  produced  from  tar.  The  output 
of  toluene,  excluding  Ordnance  plants,  in  1944  totaled  134  million 
gallons,  or  39  percent  more  than  in  1943.  Most  of  the  toluene  was 
used  in  the  production  of  explosives. 

Naphthalene  has  important  uses  as  a  raw  material  in  synthetic 
resins,  dyes,  moth  repellents,  and  other  products.  Large  amounts 
are  consumed  in  the  production  of  phthalic  anhydride  to  make  alkyd 
resins,  phthalate  plasticizers,  and  mosquito  repellents  such  as  dimethyl 
phthalate.  Production  in  1944  remained  at  about  the  1943  level  of 
slightly  more  than  300  million  pounds,  which  is  about  the  limit  for 
economical  production  of  naphthalene  with  the  available  facilities. 

Creosote  oil  is  a  name  loosely  applied  to  certain  middle  and  heavy 
oil  distillates  consisting  usually  of  mixtures  of  cresols  and  xylenols 
and  their  derivatives,  anthracene  oil,  naphthalene,  and  some  phenols. 
After  the  removal  of  the  more  important  tar  acids,  creosote  oil  is  made 
by  blending  the  residue  with  several  other  distillate  fractions.  The 
composition  of  the  mixture  is  varied  according  to  consumer  preference. 
Creosote  oil  is  used  chiefly  as  a  wood  preservative  in  railroad  ties, 
telephone  poles,  and  pilings.  In  1944  the  output  of  creosote  oil 
amounted  to  161  million  gallons,  a  decrease  from  the  level  of  about 
175  million  gallons  in  1943  and  in  1942,  but  still  well  above  the  1937-41 
average  of  114  million.  The  recent  decrease  was  due,  in  part,  to  the 
diversion  of  the  tar-acid  content  of  creosote  oil  to  the  manufacture  of 
plastics  materials  as  a  result  of  War  Production  Board  General  Prefer- 
ence Order  M-27.  The  increased  consumption  of  coal  tar  as  fuel 
possibly  had  some  effect  on  the  supplies  of  creosote  oil. 

Detailed  statistics  of  production  and  sales  of  tar  crudes  and  such 
residual  tar  crude  products  as  pitch  and  tar  coke  are  shown  in  table 
3 A  (see  also  table  3B,  part  III,  for  an  alphabetical  list  of  these  prod- 
ucts in  which  the  manufacturers  are  identified). 

Owing  to  increased  road  construction,  production  of  road  tars  was 
161  million  gallons  in  1944  compared  with  151  million  in  1943. 
Pitch  has  important  applications  in  the  manufacture  of  roofing  ma- 
terials and  special  electrodes.  The  output  of  1.3  million  tons  in  1944 
was,  however,  only  slightly  larger  than  that  of  1943  because  of  the 
heavy  demand  for  the  lighter  distillate  fractions. 

Recovery  of  crude  tar  acids,  which  represent  a  mixture  of  crude 
xylenols  and  phenols,  was  pushed  to  the  limit  in  1944;  so  was  pro- 
duction of  road  tars,  roofing  and  coating  tars,  and  pitch. 

An  accurate  total  value  of  production  of  the  products  listed  in 
table  3 A  cannot  be  computed  as  it  is  no,t  practicable  to  eliminate  all 
duplication  contained  in  the  figures  shown.  Nevertheless,  an  idea  of 
the  magnitude  of  this  value  can  be  gained  by  multiplying  the  quan- 
tities of  each  produced  by  the  unit  value  of  sales  of  the  several  items. 
In  1944  the  value  of  production  of  tar  crudes,  tar  pitches,  and  tar 
coke  thus  calculated  was  about  147  million  dollars  compared  with  138 
million  in  1943. 


SYNTHETIC   ORGANIC    CHEMICALS,    1944 


11 


Table  3A. — Organic  chemicals:^   United  States  production  and  sales  of  tar  crudes, 

1944 

[Listed  below  are  all  tar  crudes  for  which  any  reported  data  on  production  or  sales  may  be  published. 
Table  3B  in  part  III  lists  alphabetically  all  those  products  for  which  data  on  production  or  sales  were 
reported  and  identifies  the  manufacturer  of  each] 


Product 


Unit  of 
quantity 


Produc- 
tion 


Sales 


Quan- 
tity 


Value 


Unit 
value  2 


Crude  light  oil 

Light  oil  distillates: 

Benzene,  except  motor  benzene  3 ___ 

Motor  benzene  * 

Toluene,  except  aviation  grade: 
Produced  at  byproduct  plants  and  tar  re- 
fineries   

Produced  at  petroleum  refineries  5 

Toluene,  aviation  grade  ^ ' 

Xylene  * 

Solvent  naphtha 

Other  light  oil  distillates  * 

Pyridine:  * 

Crude 

Refined 

Naphthalene,  crude  (solidifying  under  79°  C.)'- 
Creosote  oil  (distillate  as  such  and  in  coal-tar 

solution) 

Crude  tar  acids: 

From  5%  to  24% 

Other  crude  tar  acids 

Carbolic  oil,  light  and  heavy  * 

Sodium  phenolate  * 

Coal  tar  sold  or  consumed  in  coal-tar  solution  K 

All  other  distillate  products  i" 

Blended   tars  (crude  and  refined)  for  coatings, 

satura tings,  etc 

Road  tars 

Pitch  of  tar,  soft  *  " 

Pitch  of  tar,  medium  12 

Pitch  of  tar,  hard  '3 

Pitch  of  tar  coke  '* 


1,000  gaL. 

1,000  gal_- 
1,000  gal.- 

1,000  gal.. 
1,000  gal- 
1,000  gal.. 
1,000  gal__ 
1,000  gal.. 
1,000  gal_. 

1,000  gal.. 
1,000  gal__ 
1,000  1b... 

1,000  gal_. 

1,000  gaL. 
1,000  gal.. 
1,000  gal- 
1,000  gaL. 
1,000  gal.. 
1,000  gal.. 

1,000  gaL. 
1,000  gaL. 
1,000  tons. 
1,000  tons. 
1,000  tons. 
1,000  tons. 


284, 849 


178, 392 
18,  557 


37,  771 
62,  693 
33,  714 
8,669 
7,139 
36, 170 

485 

135 

301, 138 

161, 152 

13,  548 
6,261 
1,477 
3, 318 
10,  7o2 
11, 226 

49,  561 
160, 976 
380 
214 
707 
104 


38, 330 

172,  503 
17, 289 


36, 946 
60, 155 
29, 965 
8,903 
6,669 
32, 463 

434 

135 

240, 512 

163,  293 

13,  467 
1,748 
1,480 
3,  213 

11,  439 
9,776 

44,  572 

160, 825 

53 

183 

358 

99 


1,000 
dollars 
3,407 

23,  230 
1,547 


10, 070 
19,  295 
10,  508 
2,284 
1,196 
4,950 

305 

472 

5,898 

22, 175 

1,625 
265 
155 
187 
928 

2.046 

2,795 
12, 983 
572 
3,418 
3,898 
1,236 


.135 


.273 
.321 
.351 
.257 
.179 
.152 

.701 

3.490 

.025 

.136 

.121 
.151 
.105 
.058 
.081 
.209 

.062 
.081 
10. 859 
18.  637 
10. 888 
12. 483 


'  Data  for  coke  ovens  and  gas-retort  ovens  reported  to  the  Coal  Economics  Division,  U.  S.  Bureau  of 
Mines,  and  for  tar  refineries  and  others  to  the  U.  S.  Tariff  Commission  unless  otherwise  noted. 

2  Unit  value  per  gallon,  pound,  or  ton  according  to  the  unit  of  quantity  shown. 

3  Does  not  include  benzene  produced  from  petroleum. 

*  Product  of  coke-oven  operators  only;  reported  to  the  U.  S.  Bureau  of  Mines. 

5  Does  not  include  toluene  produced  under  Ordnance  control  in  petroleum  refineries,  but  does  include 
toluene  produced  from  petroleum  in  plants  not  under  such  control. 

s  All  aviation  grade  was  produced  in  petroleum  refineries. 

'  Reported  to  the  U.  S.  Tarifl'  Commission  only. 

8  Includes  data  of  production  and  sales  of  motor  benzene  and  xylene  reported  to  the  U.  S.  Tarifl  Com- 
mission by  tar  distillers  only.  The  statistics  have  been  combined  in  order  to  prevent  the  disclosure  of  the 
operation  of  individual  producers. 

'  Included  in  the  statistics  are  data  for  three  grades  of  crude  naphthalene  combined  to  prevent  the  dis- 
closure of  the  operations  of  individual  companies.  These  are  the  grade  solidifying  at  less  than  74°  C.  as 
produced  for  sale  only,  and  the  grades  solidifying  at  74°  C.  to  less  than  76°  C.  and  at  76°  C.  to  less  than  79° 
C.  produced  both  for  consumption  within  the  producing  plants  and  for  sale.  As  ttiere  is  some  conversion 
between  grades,  the  data  include  some  duplication. 

1"  Includes  anthracene;  cumene;  cresylic  acid,  crude;  and  pyridine,  crude  and  scmirefined,  all  reported 
to  the  U.  S.  Tarifl:  Commission,  and  other  tar  distillate  products  reported  to  the  Coal  Economics  Division 
of  the  U.  S.  Bureau  of  Mines  and  the  U.  S.  Tarift'  Commission. 

»  Water  softening  pomt  less  than  110°  F.  ASTM  D61-2L 

12  Water  softening  point  110°  to  160°  F.  Includes  data  of  production  and  sales  of  soft  pitch  of  tarxeported 
to  the  U.  S.  Tariff  Commission.  These  data  have  been  combined  in  order  to  prevent  the  disclosure  of  the 
operations  of  individual  producers. 

"  Softening  point  above  160°  F. 

1*  Includes  some  pitch  emulsion. 


697646 — 4C 


12 


UNITED   STATES   TARIFF    COMMISSION 


CRUDE  PRODUCTS  FROM  PETROLEUM  AND  NATURAL  GAS 

Statistics  on  the  production  and  sales  of  chemical  raw  materials 
derived  from  petroleum  and  natural  gas  were  first  reported  to  the 
Tariff  Commission  in  1943.  In  that  year  more  than  1.5  billion 
pounds  of  these  materials,  excluding  toluene,  were  produced  for  pur- 
poses other  than  for  fuel.  In  1944  the  output  of  these  products 
totaled  2.8  billion  pounds;  sales  were  2.5  billion  pounds,  valued  at 
194  million  dollars.  Production  and  sales  of  chemical  raw  materials 
from  petroleum  and  natural  gas  are  shown  in  table  4 A  (see  also  table 
4B,  part  III,  for  an  alphabetical  list  of  these  products  in  which  the 
manufacturers  are  identified). 

Naphthenic  acid,  cresylic  acid,  xylene,  and  the  C2  to  C4  hydro- 
carbons are  some  of  the  raw  materials  derived  from  petroleum. 
Cresylic  acid  is  used  chiefly  to  make  plastics  materials  and  plasticizers. 
Salts  of  naphthenic  acids  are  employed  mainly  as  paint  driers  and 
antimildew  agents.  The  C2  and  C4  hydrocarbons  are  used  in  the 
manufacture  of  synthetic  rubber,  solvents,  and  other  hydrocarbon 
derivatives,  all  of  which  will  probably  have  large  peacetime  uses. 
Production  of  most  items  in  this  group,  particularly  the  hydro- 
carbons used  in  synthetic  rubber,  increased  in  1944  compared  with 
1943.  The  output  of  butadiene  alone  (not  counting  that  made  from 
alcohol)  rose  from  about  100  million  pounds  in  1943  to  nearly  half  a 
billion  pounds  in  1944. 


Table    4A. — Organic    chemicals:   United    States    production    and    sales    of   crude 
products  from  petroleum  and  natural  gas  for  chemical  conversion,  1944 

[Listed  below  are  the  crude  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which 
any  reported  data  on  production  or  sales  may  be  published.  Table  4B  in  part  III  lists  alphabetically 
all  those  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  data  on  production 
or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Product 


Total 

Chemicals  for  which  separate  statistics  may  not  be 
shown  ' : 

Chemicals  for  which  separate  statistics  are  shown 
below 

Crude  products  from  petroleum:  2 

Cresylic  acid,  crude 

Naphthenic  acid 

Xylene,  all  grades  < 

Hydrocarbons: 

Ci  hydrocarbons:  Ethylene  ^ 

C3  hydrocarbons:  Propane  and  propylene 

C4  hydrocarbons: 

1,3-Butadiene,  grade  for  rubber '-, 

1-Butene  and  2-butene  mixture...' 

All  other - 


Produc- 
tion 


1,000  pounds 
2, 804, 625 


674,  362 
2, 130, 263 


0) 

28, 462 
354, 639 

272, 188 
214,  559 

488, 945 
202, 380 
569,  090 


Sales 


Quantity         Value        Unit  value 


IfiOOpounds 
2,  547, 196 


646,  788 
1,  900, 408 


15,  524 
245,  048 

216,  733 
187, 100 

482, 744 
200,  774 
551. 885 


1,000  dollars 
193, 665 


8,015 
185,  650 


1,346 

4,875 

9,801 
1,438 

143, 450 

4,001 

20, 739 


Per  pound 
$0. 076 


.012 
.097 


(3) 


.087 
.020 


.045 
.008 


.020 
.038 


'  Represents  statistics  on  production  and  sales  of  benzene  and  other  crude  products  from  petroleum, 
other  petroleum-derived  hydrocarbons,  and  some  material  derived  from  natural  gas.  Data  for  toluene 
produced  at  petroleum  refineries  not  under  Ordnance  control  are  shown  in  table  3A. 

'  The  chemical  raw  materials  designated  as  crude  products  from  petroleum  may  include  some  compounds 
identical  with  those  obtained  by  the  carbonization  of  coal  or  the  processing  of  coal  tar;  those  derived  from 
coal  tar,  however,  are  excluded  from  this  table. 

3  Statistics  on  production  and  sales  of  crude  cresylic  acid  from  petroleum  have  been  included  with  data 
for  the  chemicals  for  which  separate  statistics  may  not  be  shown  in  order  to  prevent  the  disclosure  of  opera- 
tions of  individual  producers.  In  1944  the  production  of  cresylic  acid,  crude,  from  petroleum  and  coal  tar 
combined  amounted  to  29,052,000  pounds;  total  sales  were  26,175,000  pounds,  valued  at  $1,302,000. 

*  Includes  all  grades  of  xylene;  nitration  grade  1°,  aviation  grade,  and  all  other  grades. 

*  Statistics  on  production  and  sales  of  ethylene  and  butadiene  produced  from  alcohol  are  given  in  table  21A. 


PART  II.    PRODUCTION  AND  SALES  OF  INTERMEDIATES  AND 
FINISHED  SYNTHETIC  ORGANIC  CHEMICALS,  BY  GROUPS 

GENERAL 

In  this  report,  synthetic  organic  chemicals  are  grouped  according  to 
their  principal  uses.  These  groups,  in  turn,  are  subdivided  according 
to  chemical  classes  into  cyclic  and  acyclic  compounds. 

In  1944,  production  of  all  cyclic  and  acyclic  synthetic  organic  chem- 
icals combined  (intermediates  and  finished  products)  totaled  14.9 
billion  pounds  compared  with  12.1  billion  in  1943;  sales  in  1944  were. 
10.1  billion  pounds,  valued  at  2.0  billion  dollars,  a  gain  of  37  percent 
in  quantity  and  40  percent  in  value  over  the  corresponding  figures 
for  1943. 

Production  and  sales  statistics  of  intermediates  and  finished  syn- 
thetic organic  chemicals  by  major  groups  in  1943  and  1944  are  shown 
in  table  5  for  general  comparative  purposes. 


Table  5. — Synthetic  organic  chemicals:  Summary  of  United  States  production  and 
sales  of  intermediates  and  finished  products,  average,  1938-42,  annual,  1943-44 

[Production  and  sales  in  thousands  of  pounds;  sales  value  in  thousands  of  dollars] 


Chemical 


Average, 
1938-42 


Increase  or 

decrease  (— ), 

1943  over 

1938-42 


Increase  or 

decrease  (—), 

1944  over 

1943 


Production,  grand  total- 
Sales,  grand  total 

Sales  value,  grand  total.. 


I.  ORGANIC  CHEMICALS, 
CYCLIC  1 


Production,  total- 
Sales,  total 

Sales  value,  total. 


A.  Intermediates 


Production 

Sales 

Sales  value 

Number  of  manufacturers  *. 


B.  Finished  Products 


Production,  total- 
Sales,  total 

Sales  value,  total. 


1.  Dyes 


Production,  total 

Sales,  total 

Sales  value,  total 

Number  of  manufactm-ers  2. 


a.  Colour  Index  Group 


Production- 
Sales 

Sales  value. 


See  footnotes  at  end  of  table. 


5,  688, 025 

3, 043, 104 

556,  507 


1,  386,  669 
847, 831 
267, 824 


819, 037 

377,  544 

53,  763 


567, 632 
470, 287 
214, 061 


130, 064 
129, 324 
82,  501 


105,  246 
105, 229 
54, 682 


12, 069,  552 
7, 334, 050 
1,  431, 894 


3, 035, 617 

2, 305, 007 

619,  869 


1,637,275 

1, 032,  439 

134, 988 

101 


1, 398, 342 
1, 272,  568 

484, 881 


144, 013 

145,  499 

105, 350 

46 


107, 147 
108,  724 
60,  267 


Percent 
112.2 
141.0 
157.3 


118.9 
17L9 
131.4 


100.0 
173.5 
151.1 


146.3 
170.6 
126.5 


10.7 
12.5 
27.7 


1.8 
3.3 
10.2 


14,  929,  550 
10, 061, 193 
2, 004,  621 


4, 805, 870 

3, 938,  432 

881, 299 


2, 143, 305 

1, 555,  749 

184, 660 

101 


2,  662,  565 

2, 382,  683 

696, 639 


151, 653 

160, 049 

110,  748 

45 


109, 870 
108, 320 
59, 861 


Percent 

23.7 
37.2 
40.0 


58.3 
70.9 
42.2 


30.9 

50.7 
36.8 


90.4 

87.2 
43.7 


5.3 
3.1 
5.1- 


2.5 
-.4 
-.7 


13 


14 


UNITED   STATES   TARIFF    COMMISSION 


Table  5. — Synthetic  organic  chemicals:  Summary  of  United  States  production 
and  sales  of  intermediates  and  finished  products,  average,  1938—43,  annual, 
1943-44 — Continued 

[Production  and  sales  in  thousands  of  pounds;  sales  value  in  thousands  of  dollars] 


Chemical 

Average, 
1938-42 

1943 

Increase  or 

decrease  (— ), 

1943  over 

1938-42 

1944 

Increase  or 

decrease  (— ), 

1944  over 

1943 

I.  ORGANIC  CHEMICALS, 
CYCLIC— Continued 

B.  Finished  Products— Continued 

1.  Dj/es— Continued 

b.  Prototype  Group 

(3) 
(') 

24,818 
24,  095 
27,  819 

19,045 
16,  914 
12,  635 

20,  098 

19,  605 
25,  041 

16,768 
17,  170 

20,  042 

16,317 

14,970 

10,  358 

45 

51,633 

47,  262 

120,869 

97 

9,  559 

9,  516 

11,920 

35 

380,  523 

337, 654 

76,  761 

112 

61,710 

58,  300 

23,  628 

10 

413,  90S 

401,056 

74, 355 

14 

320, 679 

258,311 

61,640 

92 

Percent 

26,314 

26,  062 
32, 027 

1.5,469 
15,  667 
18, 860 

19,197 

18,  401 

13,  793 

45 

35,  353 

33, 103 

94, 039 

98 

11,726 

11,050 

14,565 

38 

404,113 
380,  822 

83,  264 
111 

73,  774 
66,  260 

27,  446 

10 

1,  500,  993 

1,395,136 

268,315 

16 

465,  756 
327, 862 

84,  469 
110 

Percent 

30.9 

Sales 

32.9 

Sales  value                     

27.9 

c.  Ungrouped 
Production                     '            -  .  _  - 

-32.4 

-28.7 
-28.0 

-14.3 
-11.5 
-18.0 

-7.7 

Sales                                

-8.8 

Sales  value  .-. --- 

-5.9 

?.  Lakes  and  Toners 
Production                    .  

17.7 

Sales 

22.9 

Sales  value .- 

33.2 

Number  of  manufacturers  2 

S.  Medicinals 
Production,  ._ 

22,  820 
19,  678 
34, 173 

126.3 
140.2 
253.7 

-31.5 

Sales                                     ... 

-30.0 

Sales  value ...  .. 

-22.2 

Number  of  manufacturers  2 _ 

4.  Flavor  and  Perfume  Materials 

Production 

Sales .._ 

7,543 
6,912 
7,946 

26.7 
37.7 
50.0 

22.7 
16.1 

Sales  value                             ... 

22.2 

Number  of  manufacturers  2.  _ .. 

5.  Plastics  Materials 

Production 

Sales 

229,810 
175,427 
43,  364 

65.  6 
92.5 
77.0 

6.2 
12.8 

Sales  value 

8.5 

Number  of  manufacturers  2 , 

e.  Rtibber-Processing  Chemicals 
Production 

33, 068 
25,  557 
11,654 

86.6 
128.1 
102.7 

19.5 

Sales 

13.7 

Sales  value 

16.2 

Number  of  manufacturers  2 

7.  Elastomers  {Synthetic  Rubbers) 
Production 

0) 

262.6 

Sales 

247.9 

Sales  value    ... 

260.9 

Number  of  martufacturers  2.. 

8.  Miscellaneous  ' 
Production 

125,  282 
96, 475 
21,  788 

156.0 
167.7 
182.9 

45.2 

Sales.. 

26.9 

Sales  value 

37.0 

Number  of  manufacturers  2. _ 

See  footnotes  at  end  of  table. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


15 


Table  5. — Synthetic  organic  chemicals:  Summary  of  United  States  production 
and  sales  of  intermediates  and  finished  products,  average,  1938-42,  annual, 
1943-4.4 — Continued 

[Production  and  sales  in  thousands  of  pounds;  sales  value  in  thousands  of  dollars] 


Chemical 


Average, 
1938-42 


1943 


Increase  or 

decrease  (— ), 

1943  over 

1938-42 


1944 


Increase  or 

decrease  (— ), 

1944  over 

1943 


II.  ORGANIC  CHEMICALS, 
ACYCLIC  (INTERMEDIATES 
AND   FINISHED   PRODUCTS) « 


Production,  total - 

Sales,  total 

Sales  value,  total. 


1.  Medicinals 


Production 

Sales 

Sales  value 

Number  of  manufacturers  2. 


2.  Flavor  and  Perfume  Materials 


Production 

Sales 

Sales  value 

Number  of  manufacturers  - 


?.  Plastics  Materials 


Production 

Sales 

Sales  value 

Number  of  manufacturers  2. 


i.  Rubber-Processing  Chemicals 


Production 

Sales 

Sales  value 

Number  of  manufacturers  2. 


6.  Elastomers  (Synthetic  Rubbers) 


Production 

Sales 

Sales  value 

Number  of  manufacturers  2. 


6.  Miscellaneous  ' 


Production '... 

Sales 

Sales  value 

Number  of  manufacturers  2. 


4, 301,  356 

2, 195,  273 

288,  683 


2,214 
1,709 
5,666 


2,620 
2,502 
2,282 


72,  664 
65,  367 
35,  093 


14,  203 
13,  239 
3,  355 


■  42,  423 
'  33,  598 
7  19,  788 


I  4,  209, 655 

12,112,456 

8  242,  287 


9, 033, 935 

5, 029, 043 

812, 025 


4,062 

4,541 

18, 770 

67 


3,687 

3,573 

3,933 

26 


273,  415 

230, 179 

101,430 

65 


19,213 

18,  975 

7,509 

14 


1.58,  801 

151,  560 

82. 022 

12 


8,  574,  757 

4,  620,  215 

598,  361 

165 


110.0 
129.1 
181.3 


83.5 
165.7 
231.3 


40.7 
42.8 
72.3 


276.3 
252.1 
189.0 


3.5.3 
43.3 
123.8 


274.3 
351.1 
314.5 


103.7 
118.7 
147.0 


10, 123, 680 
6,122.701 
1,123,322 


3,398 
3,109 

17,  756 
67 


4,553 

4,514 

4,546 

25 


378,  239 

316,  506 

128,  078 

59 


18, 865 

18, 465 

14,  629 

13 


256,  917 

233,  301 

85, 435 

14 


9, 461,  708 

5,  546, 866 

872, 878 

168 


12.1 
21.7 
38.3 


-16.3 
-31.5 
-5.4 


23.5 
26.3 
15.6 


38.3 
37.5 
26.3 


-1.8 
-2.7 
94.8 


61.8 
53.9 
4.2 


10.3 
20.1 
45.9 


'  Before  1941  this  group  included  only  cyclic  organic  chemicals  derived  from  coal  tar.  The  statistics 
shown  for  1941-44  include  alicyclic,  heterocyclic,  and  terpenoid  compounds,  as  well  as  benzenoid  (coal-tar) 
chemicals. 

2  Number  of  companies  engaged  in  the  manufacture  of  these  products,  not  the  number  of  producing 
establishments  or  plants,  except  that  separate  divisions  of  large  corporations  are  considered  as  separate 
companies  if  their  operations  are  virtually  independent  of  the  parent  organization. 

3  Included  with  ungrouped  dyes. 

*  Cyclic  elastomers  are  included  with  acyclic  elastomers  to  avoid  disclosure  of  confidential  information. 

6  Includes  totals  of  plasticizers  and  surface-active  agents. 

6  Before  1941  this  group  included  all  synthetic  organic  chemicals  not  derived  from  coal  tar  and  therefore 
contained  certain  alicyclic  and  terpenoid  compounds  as  well  as  acyclic  organic  chemicals.  In  the  statistics 
shown  for  1941-44  only  acyclic  chemicals  are  included  in  this  group. 

'  2-year  average,  1941^2.  Elastomers  are  included  with  miscellaneous  chemicals  for  5-year  average 
1938-42  and  therefore  are  not  considered  again  in  arriving  at  the  5-year  average  totals  for  acyclic  interme- 
diates and  finished  products. 

8  Includes  elastomers. 


16  UNITED    STATES   TARIFF    COMMISSIOlSr 

The  output  of  all  cyclic  intermediates  and  cyclic  finished  products 
(such  as  dyes,  color  lakes  and  toners,  flavor  and  perfume  materials, 
plastics  materials,  rubber-processing  chemicals,  elastomers,  and 
miscellaneous  chemicals)  m  1944  totaled  4.8  billion  pounds,  of  which 
cyclic  finished  products  represented  2.7  million  pounds,  an  increase  of 
90  percent  over  1943.  Cyclic  elastomers  accounted  for  most  of  this 
increase. 

Total  production  of  acyclic  intermediates  and  acyclic  finished  chem- 
ical products  (the  intermediates  are  not  shown  separately  from  the 
finished  products)  amounted  to  10.1  billion  pounds  in  1944,  or  68  per- 
cent of  all  synthetic  organic  chemicals.  This  production  represented 
an  increase  of  12  percent  over  the  output  of  9.0  billion  pounds  in  1943. 
The  principal  acyclic  groups  showmg  large  gains  in  output  in  1944  were 
elastomers  (the  increases  amounting  to  62  percent) ,  plastics  materials 
(38  percent),  and  flavor  and  perfume  materials  (24  percent).  Produc- 
tion of  acyclic  medicinals  decreased  16  percent  and  that  of  rubber- 
processing  chemicals,  2  percent. 

INTERMEDIATES 

Cyclic  intermediates  are  semifinished  materials  of  commerce  from 
which  finished  synthetic  products,  such  as  dyes,  medicinals,  explosives, 
plastics  materials,  flavor  and  perfume  materials,  and  elastomers,  are 
made.  There  is  no  rigid  distinction  between  intermediates  and 
finished  products:  some  intermediates  are  chemically  converted  to 
finished  products  or  may  be  sold  without  further  processing  as 
finished  products.  p-Dichlorobenzene,  for  example,  may  be  employed 
as  a  coupling  agent  in  the  production  of  various  dyes,  or  it  may  be 
recrystallized  and  packaged  for  use  as  a  moth  repellent  or  a  deodorant. 
In  general,  the  classic v,ci.cw„  .  f  materials  m  this  report  is  determined 
by  the  manner  in  which  most  of  a  given  product  is  consumed.  Cyclic 
intermediates  are  generally  of  coal-tar  origin,  but  more  recently 
increasing  quantities  of  them  are  being  manufactured  from  petroleum 
raw  materials. 

Production  and  sales  of  cyclic  intermediates  in  1944  are  shown  in 
table  6A  (see  also  table  6B,  part  III,  for  an  alphabetical  list  of  these 
products  in  which  the  manufacturers  are  identified).  Production  of 
cyclic  intermediates  in  1944  totaled  2.1  billion  pounds.  This  quantity 
exceeds  that  reported  in  1943  by  30.9  percent,  thus  continuing  the 
sharp  upward  trend  of  the  five  previous  years.  Sales  of  1.6  billion 
pounds  of  intermediates  in  1944  accounted  for  72  percent  of  the  total 
quantity  produced;  the  rest  was  consumed  by  the  original  producers 
in  the  manufacture  of  finished  products. 

A  much  greater  proportional  increase  occurred  in  production  of 
intermediates  used  in  the  manufacture  of  synthetic  elastomers  (such 
as  GR-S,  GR-A,  and  GR-M)  than  in  the  production  of  all  mter- 
mediates.  The  output  of  styrene,  an  important  constituent  of  GR-S, 
in  1944  rose  260  percent.  The  production  of  intermediates  used 
chiefly  m  synthetic  resins  remained  at  the  high  levels  of  the  previous 
year  or  slightly  exceeded  them;  production  of  phenol  and  phthalic 
anhydride,  for  example,  increased  4  and  8  percent,  respectively. 
Phenol  is  used  chiefly  in  phenolic  resins.  Phthalic  anhydride  is  used 
in  alkyd  resins,  plasticizers,  and  insect  repellents.     Production  of  the 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


17 


Table  6A. — Synthetic  organic  chemicals:   United  States  production  and  sales  of 

cyclic  intermediates,  1944 

[Listed  below  are  all  cyclic  intermediate  synthetic  organic  chemicals  for  which  any  reported  data  on  produc- 
tion or  sales  may  be  published.  (Leaders  are  used  where  the  reported  data  are  confidential  and  may  not 
be  pubhshed  or  where  no  data  were  reported.)  Table  6B  in  part  III  lists  alphabetically  all  cyclic  inter- 
mediate synthetic  organic  chemicals  for  which  data  on  production  or  sales  were  reported  and  identifies 
the  manufacturer  of  each] 


Product 

Production 

Sales 

Quantity 

Value 

Unit  value 

Total 

1,000  pounds 
2, 143, 305 

1,000  pounds 
1,  555, 749 

1,000  dollars 
184, 660 

PeT  pound 
$0.12 

Chemicals  for  which  separate  statistics  may  not 
be  shown..      

764,  561 
1, 378, 744 

6 

5,302 

507 

5,914 

224 

75 

2,190 

804 

54 

25 

66 

35 
35 

337 
176 

1,168 

752, 978 
802, 771 

91,975 
92, 685 

Chemicals  for  which  separate  statistics  are  shown 

5-Acetamido-8-ammo-2-  and  3-naphthalene  sulfonic 
acid  (Acetylamino  Cleve's  acid) 

Acetanilide,  tech 

p-Acetotoluide .  _.  .. 

N-Acetylsulfanilyl    chloride    (p-Acetamidoben- 
zenesulfonyl  chloride) 

692 

305 

44 

p-Amtnoacetanilide 

5-Amino-2-anilinobenzenesulfonic  acid 

1-Aminoanthraquinone  and  salt .  ... 

2-Aminoanthraciuinone  and  salt 

6-Amino-3,4'-azobis(benzenesulfonic  acid) 

6-(m-Aminobenzamido)-l-naphthol-3-sulfonicacid 
(m-Ammobenzoyl  J  acid) 

6-(p-Aminobenzamido)-l-naphthol-3-suIfonicacid 
(p-AminobenzoylJ  acid) 

2-Amino-p-benzenedisulfonic  acid  (Aniluio-2,5-di- 
sulfonic  acid) 

3-Amino-6-chlorobenzoic  acid 

2-Amuio-5-chloro-p-toIuenesulfonic    acid    (Lake 
red  C  amine)... 

70 

53 

76 

3-Amino-l,5-iiaphthalenedisulfonieacid 

6- Amino-1 ,3-naphthalenedisulfonic  acid ... 

7-Amino-l,3-naphthalenedisulfonic  acid  (Amino 
Gacid) 

2 

1 

.47 

8-Amino-l,6-naphthalenedisulfonic  acid  and  salt... 

88 
1,850 

218 
120 

282 

80 

411 

107 

2,795 

3,549 
1,583 

730 

889 

49 
44 
16 

211 
38 

650 
46 

110 
49 

818 

218 
89, 130 

93 

23 

225 

2-Amino-l-naphthalenesulfonic  acid  (Tobias  acid). 

5-AmLno-l-naphthalenesulfonic  acid    (Laurent's 

acid) .  ... 

832 

430 

.52 

5-Amino-2-naphthalenesulfonic  acid_ 

5-     and     8-Ammo-2-naphthalenesuUonic     acids 
(Cleve's  acid) .. ..  

23 

13 

54 

6-Amino-2-naphthalenesulfonic  acid  (Broenner's 
acid) __  _  

8- Amino-1-naphthalenesulfonic  acid 

8-Amino-2-naphthalenesulfonic  acid 

8-Amino-l,3,6-naphthalenetrisulfonic  acid     

8-Amino-l-naphthol-3,6-disulfonic    acid,    mono- 
sodium  salt  (H  acid) _      -      _ 

1- Amino-2-naphthol-4-sulf onic  acid . 

6-Amino-l-naphthol-3-sulfonic  acid,  sodium  salt 
(J  acid)  -  - 

77 

153 

1  98 

7-Amino-l-naphthol-3-sulfonic  acid,  sodium  salt 
(Gamma  acid) 

S-Amino-l-naphthol-5-sulfonic  acid,  sodium  salt 
(vSacid) 

2-Amino-5-nitrobenzenesulfonic  acid-  __  __ 

4'-Amino-4-nitrodiplienylamine-2-sulfonic  acid 

2-Amino-4-nitrophenol- ...  

o-.\minophenol 

p-Aminophenol  and  salts.-. 

40 
552 

59 
325 

1.47 
.59 

2- Amino-l-phenol-4-sulfonic  acid . 

m-  (p- Aminophenylazo)  benzenesulfonic  acid. . .   _ . 

p- (p-Aminophenylazo) benzenesulfonic  acid 

2-Aminothiazole .          _  _.  ... 

4-Amino-m-toluenesulfonic  acid . 

Aniline  (Aniline  oil) ...  .           _        . 

42,  606 

4,338 

.10 

6-Anilino-l-naphthol-3-sulfonic   acid    (Phenyl   J 
acid) -  _      .               .     . 

7-Anilino-l-naphthol-3-sulfomc  acid  (Phenyl 
gamma  acid).  ...  _. 

N-(p-Anisyl)-4-chIoroanthranilic  acid,  potassium 
salt  (3-Chloro-4'-methoxy-6-diphenylamine-car- 
boxylicacid,  potassium  salt) 

18 


UNITED    STATES   TARIFF    COMMISSION 


Table  6A. — Synthetic  organic  chemicals:   United  States  production  and  sales  of 
cyclic  intermediates,  1944 — Continued 

[Listed  below  are  all  cyclic  intermediate  synthetic  organic  chemicals  for  ■which  any  reported  data  on  produc- 
tion or  sales  may  be  published.  (Leaders  are  used  where  the  reported  data  are  confidential  and  may  not 
be  published  or  where  no  data  were  reported.)  Table  6B  in  part  III  lists  alphabetically  all  cyclic  inter- 
mediate synthetic  organic  chemicals  for  which  data  on  production  or  sales  were  reported  and  identifies 
the  manufacturer  of  each] 


Product 


Production 


Sales 


Quantity 


Value 


Unit  value 


Anthraquinone-2,6-disulfonic  acid  and  salt 

l-Anthraquinonesulfonic  acid  and  salt 

Anthrarufin  (l,5-Dihydro.\yanthraquinone) 

Benzaldehy de,  tech 

3-(4-Benzamido-l-anthraquinonylimino)-5-benza- 

midoanthraquinone 

l-Benzamido-5-chloroanthraquinone 

6-Benzamido-l-naphthol-3-sulfonic  acid  (Benzoyl  J 

acid) 

7-Benz[de]anthracen-7-one  (Benzanthrone) 

Benzenesulfonie  acid  and  salt.   

Benzidine  hydrochloride  and  sulfate 

p,p'-Bis(dimethylamino)bcnzophenone(Michler's 

ketone)  

N,N'-Bis-6-(l-naphthol-3-sulfonie  acid)urea(J  acid 

urea) ._ 

3-Bromo-7-benz[de]anthi  acen-7-one 

4-Chloro-o-anisidine  _-_ _._ 

1-Chloroanthraquinone _-_ 

2-Chloroanthrftquinone 

o-Chlorobenzal(iehyde 

Chlorobenzene ,  mono 

Chlorobenzoylbenzoie  acid 

1-C  hloro-2,4-dinitrobenzenc 

Chloromcthylanthraquinone -. 

2-Chloro-4-nitroaniline 

4-Chloro-2-nitroaniline 

2-Chloro-5-nitrobenzenesulfonic  acid 

2-Chloro-5-nitrobenzoic  acid -- 

o-Chlorophenol _ 

a-Chlorotoluene  (Benzyl  chloride) 

(4-Chloro-o-tolylmercapto)acetic  acid 

Cresols,  total  i 


1 ,000  pounds 

140 

4,629 

157 

2,230 

106 
,"12 

6 
1,361 

n 

2,108 

110 

247 

214 

91 

289 

577 

167 

212,455 

1,641 

18,  556 

270 

172 

168 

283 

33 


1 ,000  pounds 


1,000  dollars 


Per  pound 


Cresol  (meta,  para)  ' 

Cresol  (ortho,  meta,  para) 

o-Cresol ) 

Another 


Cresylic  acid,  refined  i  ^ 

2,6-Diaminoanthraquinone 

4,4'-Diamino-3,3'-biphenyldisulfonie  acid 

2,2'-Diamino-5,5'-bi-m-toluenesulfonic  acid 

4,4'-Diamino-l,l'-dianthraquinonylamine 

4,4'-Diaminodiphenylamine-2-sulfonic  acid 

N,N'-Di(m-amuiophenyl)oxamide       (O.xalyl-m- 

phenylenediamine) 

4,4'-Diamino-2,2'-stUbenedisulfonic  acid 

l,l'-DianthraquLnonylamine 

2',7'-Dibromofluoresceiii 

2,5-Dichloroaniline 

o-Dichlorobenzene 

p-Dichlorobenzene 

3,3'-Dichlorobenzidine  and  sulfate. 

2,4-Dichlorobenzoic  acid _. 

6,9-Dichloro-2-methoxyacridine 

l,4-Dichloro-2-nitrobenzene 

l-(2,5-Dichloro-4-sulfophenyl)-3-methyl-5-pyrazo- 

lone.- 

2,4-Dichlorotoluene 

N,N-Diethylaniline 

4,5-Dihydroxy-l-naphthalenesulfonie  acid  (Dioxy 

Sacid) 

N,N-Dimethylaniline 

2,2'-Dimethyl-l,r-bianthraquinone 

N,N'-Dimethyl-p-phenylenediamine  and  hydro- 
chloride  

2,4-Dinitrophenol,  tech 

4,4'-Dinitro-2,2'-stilbenedisulfonic  acid 

8-Diphenylamino-l,6-naphthalenedisulfonie  acid  . 

«-(N-E thylanilino)  -p-toluenesulfonic  acid 

See  footnotes  at  end  ot  table. 


3,730 
62 


6,  141 
7,337 
3,625 


29, 859 

65 

5 

17 

324 

17 

9 

226 

274 

7 

176 

12,333 

24,  649 

398 

531 

342 

346 

109 
337 

472 

11 

7,274 
181 


482 
82 
457 


2,204 


363 

2,845 


13,  101 


m 

2,484 
10,617 

28,  628 


127 

9,  856 

23, 900 

323 

463 


883 


100 


517 
1,336 


318 
1,018 

2,225 


20 
62 
566 
2.  152 
376 
454 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


19 


Table  6A. — Synthetic  organic  chemicals:   United  States  production  and  sales  of 
cyclic  intermediates,  1944- — Continued 

[Listed  below  are  all  cyclic  intermediate  synthetic  organic  chemicals  for  which  any  reported  data  on  produc- 
tion or  sales  may  be  published.  (Leaders  are  used  where  the  reported  data  are  confidential  and  may  not 
be  published  or  where  no  data  were  reported.)  Table  6B  in  part  III  lists  alphabetically  all  cyclic  inter- 
mediate synthetic  organic  chemicals  for  which  data  on  production  or  sales  were  reported  and  identifies 
the  manufacturer  of  each] 


Production 

Sales 

Product 

Quantity 

Value 

Unit  value 

1,000  pounds 

48 

285 

96 

3,  651 

312 

14 
215 

39 
537 

983 
119 

27 

81,588 
181 

1,574 
731 
562 

1,167 
119 
237 

3,803 

1,000  pounds 

1,000  dollars 

Per  pound 

3,449 

1,932 

$0.56 

l,l'-Iminobis(4-benzamidoanthraquinone) 

6,6'-Iminqbis(l-naphthol-3-sulfonic  acid)  (I  or  J 

p,p'-Methylenebis(N,N-dimethylaniline)  (Tetra- 

3-Methyl-l-phenyl-5-pyrazolone  (Developer  Z)  — 

Methylphenylpyrazolone-4-sulfon ic  acid 

Naphthalene,  solidifying  at  79''  C.  or  above,  re- 
fined, flake                                             -  

40,  528 

3,044 

.08 

Naphthionic  acid  (4-Amino-l-naphthalenesulfon- 

a-Naphthol                                         - 

368 

189 

.52 

2-Naphthol-6,8-disulfonic  acid  and  salt              

70 

37 

.53 

2-Naphthol-6-sulfonic  acid  (Schaeffer's  acid) 

75 
559 
228 

34 
160 
106 

.45 
.29 

2-Naphthylamine    - 

.47 

217 
73 

24 

69 

118,928 

675 

289 

213 

168 

1,069 

1,007 

201,  993 

6-(m-Nitrobenzamido)-l-naphthol-3-sulfonic  acid 

6-(p-Nitrobenzamido)-l-naphthol-3-sulfonic   acid 

3,876 

287 

.09 

2-Nitro-p-toluidine                             -  

658 
176,110 

651 
16,  527 

.99 

Phenol,  total  i 

.09 

28,  852 

2,233 

26,  619 

173, 141 

352 
61 

152 
1,050 

163 

9 

5,567 

158 
150 

278 
122,723 

1,614 

27,  305 

3,230 

24, 075 

148,  805 

367 

57 

2,352 

309 

2,043 

14, 175 

50 

58 

.09 

39°  Cm.  p. 1                           

.10 

.08 

Synthetic ...  

.10 

.14 

1.03 

p-Phenylazoaniline  (Aminoazobenzene)  and  hy- 

2,2'-Phenyliminodiethanol      (Phenyldiethanola- 
mine)  (N  ,N'-B  is  (2-hydroxyethyl)  aniline) .  - 

N-Phenyl-l-naphthylamiiie-8-sulfonic  acid  (Phen- 

Phthalic  anhydride                 - 

87, 117 
1,366 

10, 934 
317 

.13 

.23 

1,  l.?0 
484 

149 

1,029 

349, 367 

518 

1,005 
361 

119 

443 

348,  747 

180 
137 

87 

649 

41,343 

.18 

All  other                                    .    .        

.38 

.72 

Quinizarin  (1,4-Dihydroxyanthraquinone) 

1.47 
.12 

1 ,4,5,8-Tetrachloroanthraquinone 

See  footnotes  at  end  ofltable. 


20 


UNITED   STATES   TARIFF    COMMISSION 


Table  6A. — Synthetic  organic  chemicals:   United  States  production  and  sales  of 
cyclic  intermediates,  1944 — Continued 

[Listed  below  are  all  cyclic  intermediate  synthetic  organic  chemicals  for  which  any  reported  data  on  produc- 
tion or  sales  may  be  published.  (Leaders  are  used  where  the  reported  data  are  confidential  and  may  not 
be  published  or  where  no  data  were  reported.)  Table  6B  in  part  III  lists  alphabetically  all  cyclic  inter- 
mediate synthetic  organic  chemicals  for  which  data  on  production  or  sales  were  reported  and  identifies 
the  manufacturer  of  each] 


Product 

Production 

Sales 

Quantity 

Value 

Unit  value 

1,4,5,8  -  TetrakisCl  -  anthraquinonylamino)anthra- 
quinone  (Penta-anthramide)        ,     _      . 

1,000  pounds 

1, 665 

172 

1,000  pounds 

1,000  dollars 

Per  pound 

a-Toluicacid,  ethyl  ester  (Phenylacetic  acid,  ethyl 
ester)  (Ethyl  phenylacetate)- 

p-Toluidine             -      .. 

1,019 

457 

$0.45 

8-(p-Toluino)-l-naphthalenesulfonic  acid   (Tolyl 
peri  acid) .._ 

50 

480 

603 

1,115 

2,379 

4-(o-Tolylazo)-o-toluidine  (o-Aminoazotoluene)... 

o-(p-Tolyl) benzoic  acid 

m-Tolylenediamine 

272 

2.196 

115 

185 
155 
17 

.68 

Trichlorobenzenes 

a-Trichlorotoluene  (Benzotrichloride) . 

.07 
.15 

m-Xylene__  .. 

90 
62 

65 
416 

Xylene,  ortho  and  para 

Xylidines: 
2,4-Xylidine  (m-4-Xylidine) 

Xylidine  mi.xtures  * 

1  Includes  data  reported  by  coke-oven  manufacturers  to  U.  S.  Bureau  of  Mines. 

2  Included  in  "All  other"  cresols. 

3  Includes  cresylic  acid,  refined  from  petroleum. 

*  Obtained  by  the  chemical  reduction  of  the  reaction  product  of  nitric  acid  and  xylene. 

purified  cresols  and  refined  cresylic  acids  decreased  slightly  from  the 
levels  of  recent  years. 

The  output  of  monochlorobenzene,  amounting  to  212  million 
poimds  in  1944,  was  9  million  pounds  less  than  in  1943  but  consider- 
ably more  than  in  the  earlier  war  years.  Most  of  this  material  goes 
into  phenol  and  a  smaller  amount  mto  aniline,  certain  dyes,  and 
insecticides.  Production  of  benzoic  acid  and  benzaldehyde  also 
increased  appreciably. 

Statistics  on  the  production  and  sales  of  synthetic  cumene  (iso- 
propylbenzene)  are  not  mcluded  in  the  totals  for  1944  for  all  mter- 
mediates  because  in  that  year  this  material  was  consumed  almost 
entirely  in  aviation  fuel.  Production  totaled  217  million  pounds; 
sales  of  213  million  pounds  were  valued  at  6.4  million  dollars. 

DYES 

In  1944,  production  of  dyes  of  all  types  amomited  to  152  million 
pounds  compared  with  144  million  m  the  previous  year.  Peak 
militaiy  requirements  for  dyes  accounted  for  most  of  this  increase. 
The  production  of  coal-tar  dyes  for  civilian  use  continued  under 
War  Production  Board  Order  M-103,  which  restricted  deliveries 
to  70  percent  of  those  for  1941.  Restrictions  were  placed  also  on 
the  supplies  of  many  basic  raw  materials  (benzene,  phenol,  toluene, 
aniline,  and  naphthalene)  available  for  production  of  civilian  dyes. 

Sales  of  all  dyes  in  1944  totaled  150  million  pounds,  valued  at  111 
million  dollars,  compared  with  145  million  pounds,  valued  at  105 
million  dollars,  in  1943.  Inventories  of  dyes  for  civilian  consumption 
were  abnormally  low  m  1944,  and  the  dyes  being  produced  for  military 


SYNTHETIC   ORGANIC    CHEMICALS,    1944 


21 


purposes  were  disposed  of  rapidly.     Few  dyes  are  consumed  in  the 
dye-producing  plants  themselves. 

Statistics  on  production  and  sales  of  dyes  are  shown  in  table  7A 
(see  also  table  7B,  part  III,  for  an  alphabetical  list  of  these  products 
in  which  the  manufacturers  are  identified). 

Table  7A. — Synthetic  organic  chemicals:    United  States  production  and  sales  of 

coal-tar  dyes,  1944 

[Listed  below  are  all  coal-tar  dyes  of  which  any  reported  data  on  production  or  sales  may  be  published. 
(Leaders  are  used  where  the  reported  data  are  confidential  and  may  not  be  published  or  where  no  data 
were  reported.)  Table  7B  in  part  III  lists  alphabetically  all  dyes  for  which  data  on  production  or  sales 
were  reported  and  identifies  the  manufacturer  of  each] 


Colour 
Index 

Dye 

Production 

Sales 

or  Pro- 
totype 
No. 

Quantity 

Value 

Unit  value 

Grand  total        

1,000  pounds 
151, 653 

/  ,000  pounds 
150, 049 

1,000  dollars 
110,  748 

Per  pound 
$0.74 

Dyes  for  which  separate  statistics  may 
not  be  shown.  -    -_    

32, 491 
119, 162 

109, 870 

31,185 
118, 864 

108, 320 

35, 584 
75, 164 

59,  861 

1.14 

Dyes  for  which  separate  statistics  are 
shown  below 

.63 

DYES  GROUPED  BY  COLOUR 
INDEX  NUMBER 

Total.. 

.55 

Azo  Dyes 

Monoazo  Dyes 

Spirit  yellow  R 

17 

85 
404 

67 
427 
130 
272 
376 

11 
502 
226 
112 
164 

48 
261 

95 
535 

52 

163 

49 

143 

172 

5 

163 

112 

65 

69 

32 

137 

82 

167 

.77 

20 

ChrysoidineY 

.38 

21 

Chrysoidine  R 

.38 

24 

Sudan  I 

260 
385 

.52 

27 

Orange  G 

.46 

30 

Fast  acid  fuchsine  B.  . 

.44 

31 

Amido  naphthol  red  G      _    .. 

496 

202 

95 

98 

37 

266 

.32 

36 

Chrome  yellow  2G     .     ...     ... 

.49 

40 

Chrome  yellow  R 

.58 

52 

Azo  alizarin  yellow  GP 

.42 

53 

Victoria  violet  4BS 

.67 

57 

Amido  naphthol  red  6B 

.53 

73 

Sudan  II 

.86 

79 

Ponceau  R 

575 

84 

266 

291 

12 

25 

1,292 

.31 

88 

Fast  red  B 

98 

Chrome  brown  R 

263 

302 

16 

43 

1,195 

63 

10 

178 

123 

79 

177 

161 

18 

27 

322 

44 

7 

92 
67 
41 

.67 

138 

Metanil  yellow  . 

.53 

145 

Azofiavine  RS..    

1.14 

146 

Azo  yellow 

.62 

151 

Orange  II..     .      ..  ... 

.27 

168 

Acid  chrome  garnet  R 

.69 

169 

Acid  chrome  violet  N     . 

11 

206 
128 
67 
46 
122 
184 
2,438 
1,102 
162 
107 

.75 

176 

Fast  red  A  ....  _..                ...... 

.51 

179 

Azorubine 

.54 

180 

Fast  red  VR 

.52 

184 

185 

Cochineal  red  A                                .  ... 

112 

200 

2,296 

1,000 

130 

92 

16 

59 

214 

470 

140 

1,551 

28 

256 

50 

89 

685 

338 

57 

45 

10 

33 

215 

255 
98 

571 
16 

223 

.45 

201 

Chrome  blue  black  B..         .... 

.45 

202 

Chrome  blue  black  R 

.30 

203 

Chrome  black  T 

.34 

204 

Chrome  black  A 

.44 

208 

Fast  acid  blue  R                    

.49 

209 

Fast  acid  blue  B 

.66 

216 

Acid  chrome  red  B..  

73 
144 

465 

118 

1,389 

.55 

219 

Chrome  flavine  A ..- 

1.01 

234 

Disazo  Dyes 
Resorcin  brown.       ..                     

.54 

235 

Resorcin  dark  brown 

.70 

246 

Acid  black  lOB 

.37 

247 

.57 

252 

Brilliant  croceine  M    

259 
45 

.87 

262 

Cloth  red  B 

22 


UNITED    STATES   TARIFF    COMMISSION 


Table   7A. — Synthetic  organic  chemicals:    United  States  production  and  sales   of 
coal-tar  dyes,  1944 — Continued 


Colour 
Index 

Dye 

Production 

Sales 

or  Pro- 
totype 
No. 

Quantity 

Value 

Unit  value 

274 

DYES  GROUPED  BY  COLOUR 
INDEX  NUMBER— Continued 

Azo  Dyes — Continued 

Disazo  Dyes— Continued 

Milling  orange. .^ 

1,000  pounds 

/  ,000  pounds 

39 

3 

205 

14 

452 

193 

13 

60 

246 

109 

32 

19 

968 

108 

826 

84 

21 

36 

187 

420 

145 

34 

68 

2,877 

959 

15 

113 

397 

639 

257 

9 

140 

70 

17 

184 

128 

480 

187 

393 

278 
8,290 

eo9 

195 
31 

600 

76 

804 

149 

418 
194 
313 

115 
189 
719 
203 
57 

1.5.59 

1 ,000  dollars 

18 

3 

391 

14 

247 

103 

10 

28 

165 

90 

34 

43 

999 

43 

355 

53 

36 

69 

141 

281 

136 

28 

66 

947 

208 

6 

44 

236 

310 

216 

6 

35 

61 

15 

123 

96 

415 

89 

187 

343 

2,120 

179 

65 

12 
228 

33 
283 

66 

214 
142 

182 

119 
182 
481 
174 

75 

1.299 

Per  pound 
$0.46 

275 

Cloth  scarlet  G 

.98 

278 

Direct  fast  red  8BL-                          .     - 

228 

25 

446 

169 

1.90 

280 

Scarlet  EC.          .                 

1.00 

289 

Fast  acid  cyanine  5R  ex 

.55 

299 

Acid  chrome  black  F .. 

.53 

302 

Acid  chrome  green  SS 

.75 

304 

Fast  acid  black  2BN__ 

54 

264 

96 

55 

24 

972 

114 

920 

57 

13 

39 

202 

424 

158 

.46 

307 

Fast  acid  cyanine  black  B.. 

.67 

316 

Developed  blue  NA.  --  

.82 

324a 
325 
326 

Rosanthrene 

Direct  billiant  violet 

Direct  fast  scarlet 

1.07 
2.27 
1.03 

331 

Bismarck  brovs^n  G          .  _     _ -  .. 

.39 

332 

Bismarck  brown  R 

.43 

343 

Chrome  fast  yellow  C_  _     

.62 

346 

Direct  fast  yellow  5GL                        -  . 

1.75 

353 

Direct  fast  pink  2BL                    .... 

1.91 

364 

Brilliant  yellow       .           ..... 

.76 

375 

Congo  corinth  G.   ._                 ...  

.67 

382 

Direct  scarlet  B 

.93 

387 

Direct  violet  B ...  

.83 

394 

Direct  violet  N-_ . 

.97 

401 

Developed  black  BH 

3,078 
1,046 

.33 

406 

Direct  blue  2B 

.22 

411 

Cresotine  yellow  G 

.37 

415 
419 

Direct  orange  R 

Direct  fast  red  F 

106 
406 
629 
249 
6 
113 
76 

.39 
.59 

420 
430 

Direct  brown  M 

Polar  red...      .                      ..... 

.49 
.84 

472 

Direct  blue  BX 

.71 

477 

Direct  blue  3B ..     

.25 

487 

Acid  anthracene  red  3B.-     ...  

.87 

495 

Benzopurpurine  lOB   . 

.88 

502 
512 

Direct  azurine  G_ 

Direct  blue  R\V_. 

191 
157 
506 
185 

398 
255 
8,211 
619 
241 
54 
682 
126 
898 
174 

418 
217 
392 

149 
227 
715 
215 

56 

1,461 

.67 
.75 

518 

Direct  sky  blue  FF 

.86 

520 
539 

Direct  pure  blue 

Trisazo  Dyes 
Direct  fast  black  FF 

.48 
.48 

561 

Direct  brown  BT 

1.24 

,581 

Direct  black  EW 

.26 

582 

Direct  black  RX. 

.29 

583 

Direct  green  ET 

.34 

.589 

Chloramine  green  B     

.40 

593 

Direct  green  B__  

.38 

594 

Direct  green  O  . 

.44 

596 

Direct  brown  3Q0 

.35 

598 

Congo  brown  G 

.45 

620 

Stilbene  Dyes 
Direct  yellow  R 

.51 

621 

Chloramine  orange  G..    ...  _ 

.73 

622 

Stilbene  yellow 

.58 

636 

Pyrazolone  Dyes 
Fast  light  yellow  O 

1.04 

639 

Xylene  light  yellow 

.96 

640 

Tartrazine. .  .  . 

.67 

652 

Chrome  red  B 

.86 

653 

Pvrazol  orange ._  .        ... 

1.32 

655 

Ketonimine  Dyes 
Anramine 

.83 

SYNTHETIC    ORGANIC    CHEMICALS,    1944 


23 


Table   7A. — Synthetic  organic  chemicals:    United  States  production  and  sales  of 
.  coal-tar  dyes,  1944 — Continued 


Dye 


DYES  GROUPED  BY  COLOUR 
INDEX  NUMBER— Continued 

Triphenylmethane  and  Diphenylnaph- 
thylmethane  Dyes 


Malachite  green 

Rhoduline  blue  60 

Acid  green  B 

Fast  acid  green  B 

Acid  glaucine  blue 

Para  fuchsine 

Magenta 

Methyl  violet  B  and  base. 

Crystal  violet 

Acid  violet 

Soluble  blue 

Patent  blue  A 

Acid  chrome  azurol  B 

Victoria  blue  R 

Naphthalene  green  V 

Wool  green  S_ 


Xanthene  Dyes 


Fluorescein 

Tetrabromofluorescein. 


Acridine  Dyes 
Phosphine 

Quinoline  Dyes 
Quinoline  yellow 

Thiazole  Dyes 

Direct  fast  yellow 

Azine  Dyes 


Wool  fast  blue 

Safranine--. 

Nigrosine,  spirit-soluble . 
Nigrosine,  water-soluble. 


Thiazine  Dyes 

Methylene  blue 

Sulfur  or  Sulfide  Dyes 
Total 


Sulfur  black.  _. 

Sulfur  blue 

Sulfur  brown.. 
Sulfur  green.. - 
Sulfur  maroon. 

Sulfur  olive 

Sulfur  tan 

Sulfur  yellow. 
Another 


Anthraquinone  Dyes 


Alizarin  red  S 

Acid  alizarin  blue  SE 

Acid  alizarin  blue  B 

Alizarin  cyanine  green 

Anthraquinone  blue  black  B. 


Production 


1,000  pounds 
240 

109 
28 

612 
11 


1,016 

1,003 

200 

77 

120 

105 


158 
270 


2.012 
1.363 


17,  896 


Sales 


Quantity 


t, 000  pounds 
248 
12 
83 
24 
529 


11,  738 

2,137 

1,767 

346 

476 

1,088 

67 

253 

24 


48 
428 
457 
340 


58 
864 
946 
201 


Value 


1,000  dollars 

278 

39 

59 

,56 

379 


273 

76 


219 

192 

2,  055 

1,188 


747 


11, 629 

2,043 

1,791 

300 

429 

1,2.38 

85 

208 

24 


92 

45 
421 
465 
435 


105 
523 
1.635 
193 
192 
164 
127 
3 
85 
81 


Unit  value 


Per  pound 

$1.12 

.3.22 

.72 

2.33 

.72 


320 
72 

103 


311 
244 
650 
443 


239 


500 

231 

195 

365 

24 

67 

6 


158 
108 


924 

628 


1.81 

.61 

1.73 

.96 

2.00 

1.68 

1.45 

2.56 

1.86 

.52 


1.18 
.95 

1.96 


1.42 
1.28 
.32 
.37 


.17 
.47 
.28 
.77 
.45 
.29 
.28 
.32 
.25 


1.72 
2.40 
1.64 
1.99 
1.44 


24 


UNITED   STATES   TAKIFF    COMMISSION 


Table  7A. — Synthetic  organic  chemicals:   United  States  production  and  sales  of 
coal-tar  dyes,  1944^ — Continued  . 


Colour 
Index 
or  Pro- 
totype 
No. 


Dye 


Production 


Sales 


Quantity 


Value 


Unit  value 


1095 
1096 


1099 
1102 

1104 
1106 
1113 
1114 
1150 
1151 
1152 


1177 
1184 
1212 


DYES  GROUPED  BY  COLOUR 
INDEX  NUMBER— Continued, 

Anthraquinone  Vat  Dyes 

Anthraquinone  vat  yellow  GC,  12i^%-- 
Anthraquinone  vat  golden  orange  G, 

12% ---- 

Anthraquinone  vat  golden  orange  R, 

12% 

Anthraquinone  vat  dark  blue  BO,  25%. 
Anthraquinone  vat  green  B  and  black 

B,  12H% 

Anthraquinone  vat  violet  2R,  12).^% — 

Anthraquinone  vat  blue  RS,  10% 

Anthraquinone  vat  blue  GCD,  SH%-.- 

Anthraquinone  vat  blue  BCS,  20%, 

Anthraquinone  vat  olive  R,  12^% 

Anthraquinone  vat  brown  R,  12^2% 

Anthraquinone  vat  brown  G,  12)^4% 

Indigoid  and  Thioindigoid  Dyes 


Indigo,  synthetic,  20% 

Bromindigo  blue  2BD,  16%,. 
Vat  red  3B,  20%, 


1,000  pounds 
977 


565 


Food,  Drug,  and  Cosmetic  Dyes 
Total.... 


Food,  drug,  and  cosmetic  colors,  total.. 


Blue#l.... 
Blue  #2.... 
Green  #1... 
Orange  #1. 

Red#l 

Red  #2...-. 
Red#3  .... 
Yellow  #5. 
Yellow  #6^ 
All  other.. 


Drug  and  cosmetic  colors,  total  i. 


Orange  #4. 

Red  #7 

Red  #19... 
Red  #21... 
Red  #35.... 
All  other  L 


AU  other  Colour  Index  Dyes 


Total. 


DYES  GROUPED  BY  FOREIGN 
PROTOTYPE  NUMBER 


Total. 


Acid  alizarin  flavine  R 

Acid  anthracene  brown  PG 

Anthracene  chromate  brown  EB. 

Benzo  chrome  black  blue  B 

Benzo  fast  black  L 

Benzo  fast  blue4GL 

Brilliant  benzo  violet  B_ 

Brilliant  wool  blue  FFR 

Celliton  orange  GR 

Chlorantine  fast  brown  BRL 

Chlorantine  fast  yellow  4GL 

Chlorantine  fast  yellow  RL. 


1,000  pounds     1,000  dollars 
1, 005  963 


362 


322 

768 

1,132 

3,392 

773 

1,024 


17, 287 
934 
170 


678 


93 
47 

187 
8 

164 
87 
89 

173 


9 
10 
23 
11 

4 
116 


14,  479 


26, 314 


56 
323 


50 
45 
168 
170 


530 
733 

566 
129 
299 
633 
966 

3,693 
897 

1,033 


17,  435 

1,005 

194 


681 


12 

3 

1 

86 

43 

204 

7 

169 

92 

64 

166 


9 

23 

10 

4 

111 


12, 755 


26, 062 


21 
82 
340 
54 
220 
107 
96 
49 
36 
202 
140 
32 


696 
936 

224 

239 

231 

397 

1,140 

4,002 

1,107 

1,212 


2,856 
670 
205 


2,303 


1,930 


127 
31 
8 
187 
186 
493 
99 
415 
217 
167 

373 


Per  pound 
$0.96 


11,252 


32, 027 


19 
138 
248 

50 
181 
154 
101 

81 

48 
258 
196 

55 


'  Includes  drug  and  cosmetic  dyes,  external,  data  on  which  are  confidential. 


SYNTHETIC   ORGANIC    CHEMICALS,    1944 


25 


Table  7 A.- — Synthetic  organic  chemicals:    United  States  'production  and  sales  of 
coal-tar  dyes,  i 94-4— Continued 


Dye 


DYES  GROUPED  BY  FOREIGN 
PROTOTYPE  NUMBER— Con. 


Diamine  Bordeaux  B 

Diamine  catechine  30 

Diamine  fast  blue  FEB 

Diamine  fast  orange  EG 

Diamine  fast  oranfre  ER 

Diazo  Bordeaux  7B 

Diazo  brilliant  scarlet  2BL  ex 

Diazo  brilliant  scarlet  ROA 

Fast  scarlet  2G  base,  salt 

Guinea  fast  red  BL 

Indanthrene  brown  RRD 

Indanthrene  khaki  2G 

Oxydiaminogen  OB 

Polar  orange  R 

Rapidogen  blue  D 

Rapidogen  red  RS 

Rosanthrene  fast  Bordeaux  2BL 

Sulphon  yellow  R 

Supra  light  rubine  BL 

Victoria  fast  violet  2R  ex 

Zambesi  black  D 

Zambesi  black  V 

Celliton  scarlet  B 

Fast  Bordeaux  GP  base,  salt 

Fast  orange  GC  base,  salt 

Fast  red  3GL  salt 

Fast  red  KB  base 

Fast  red  TR  base,  salt 

Fast  yellow  GC  base,  salt 

Indanthrene  olive  green  B 

Naphthol  AS 

Naphthol  AS-BS 

Naphthol  AS-D 

Naphthol  AS-RL » 

Naphthol  AS-TR 

All  other    dyes    grouped   by   Foreign 
Prototype  number 


UNGROUPED  DYES 


Total. 


Acetate  rayon  dyes,  total  (see  tables  9  and 
10  for  total  of  all  acetate  rayon  dyes)  ^. 

Black,  IV,  IV  ex.,  B,  BND,  BNF,  2G, 

3G,  3GNF,  GS,  J,  NS,  RB,  SN,  SS,_ 
Blue,  IV,  XII,  BB,  BGF,  BNN,  G,  2G, 

GR,  R,  3R3 

Orange,  BL,  GR,  GRN  cone,  JER,  E, 

2R,  3R,  4R,  RB,  TF  * 

Red,  III,  VI  ex.,  VII.  VIII,  B,  2B,  BX, 

FSI,  NB,  R,  RP,  VOL,  Y 

Rubine  IX,  B,  C,  G,  R    __..     

Scarlet  III,  BG,  BS,  CSB,  G,  GY._.. 
Violet  II,  3B,  4B,  BA,  BGF,  FSI,  2R, 

4R,  3RA,  5RLF 

Yellow  #8,  #38,  G,  5G,  6G,  3GM,  GN, 

6GN,  GS,  GX,  JT,  4RL,  RN 

All  other 

Acid  black,  640,  773,  AR,  3G,  GRF  cone, 

J,  RB,  RCW 

Acid  red  A-lOO,  3B,  3BX,  G,  GL,  OA, 

RB 

Anthraquinone  vat  blue  CLX,  GR,  IBC. 

Anthraquinone    vat    navy    blue,    BN, 

BRA,  NRD,  NTP 


Production 


1,000  pounds 

99 

119 

338 

141 

67 

26 

28 

166 

110 

54 

761 

12, 660 

117 


187 
120 


270 
70 
81 
27 

115 


27 


1,304 

620 

114 

63 


21 

7,397 


15, 469 


2,584 


1,107 

541 

189 

174 
21 
37 


118 
397 


16 
135 


308 


Sales 


Quantity 


1,000  pounds 

98 

115 

333 

137 

47 

38 

32 

179 

134 

71 

776 

12, 119 

146 

16 


123 
56 
35 
14 
39 
22 

294 
68 
92 
32 

122 
26 


6 

1,090 

672 

85 

17 

5 

19 

7,625 


15, 667 


957 

451 

142 

145 
56 
24 


104 
396 


19 
109 


302 


Value 


1,000  dollars 
82 
69 

401 

137 
58 
46 
72 

280 
74 
59 

740 
14, 598 

119 
17 


197 
93 
33 
27 
24 
20 

174 
70 
92 
31 
76 
59 


6 

1,449 

645 

144 

33 

12 

57 

10,  504 


18, 860 


1,973 


516 
139 


116 

48 


19 


115 
395 


16 
222 


283 


Unit  value 


Per  pound 


'  Does  not  include  acetate  rayon  dyes  which  appear  in  the  Colour  Index  and  Foreign  Prototype  groups. 
8  Includes  brilliant  blue  B,  NR. 
*  Includes  golden  orange  I,  III. 


26 


UNITED   STATES   TARIFF    COMMISSION 


Table   7A. — Synthetic  organic  chemicals:    United  States  production  and  sales  of 
coal-tar  dyes,  1944 — Continued 


Colour 
Index 
or  Pro- 
totype 
No. 


Dye 


UNOROUPED  DYES— Continued 

Azoic  dyes  and  their  components,  total 

(see  table  U  for  data  on  all  azoic  dyes 

and  tiieir  components) ' 

Ciirome  yellow  FTL,  2G,  2GN,  SSN, 

SW 

Developed  Bordeaux  7B,  2BL 

Developed  red  2B,  BFW,  7BL 

Direct  black  CAM,  CW,  3G,  5G,  NCW 
Direct  blue  2B,  BR,  FFGL,  5G,  KHB, 

NR,  RDW,  VRS 

Direct  brilliant  violet  B,  4B,  R 

Direct  brown  BGA/CF,  CWR/GB,  OKA, 

02R,  3GS,  KRS,  N,  R,  RB,  RBA 
Direct  fast  blue  60KS,   GL,  8GL,  R, 

RL,  SRL 

Direct    fast    brown    BRL,    FW,    4GL, 

LBRSA,  R,  4R,  2RL,  3YL 

Direct  fast  gray  BL,  GL,  2GL,  LVGLA, 

LVL,  RLN .... 

Direct  fast  orange  G,  2G,  4G,  GL,  2GL, 

R,  4RL,  SRL,  2RN,  RT 

Direct  fast  red,  3BL,  8BLN,  8BLSW... 

Direct  navy  blue  B,  DB,  RY 

Oil  orange,  #30,  MT,  2R 

Oil  red,  #322,  EGN,  G,  1-1471,  N-1700, 

OB,  XO,  Y-292 

All  other  ungrouped  dyes 


Production 


1 ,000  poundu 


104 
11 


77 

50 

32 

79 
40 
63 
33 

241 
10,  015 


Sales 


Quantity 


t, 000  pounds 


116 
13 
40 

133 

21 
15 


89 
35 
61 
35 

245 
10, 805 


Value 


1,000  dollars 


1,474 

39 
20 
62 
59 

17 
17 

61 

157 

72 

55 

135 
54 
35 
30 

238 
13, 828 


Unit  value 


Per  pound 

$1.40 

.34 
1.54 
1.54 

.45 

.78 
'      LIO 

.72 

1.58 

1.45 

1.57 

1.52 
1.55 
.56 
.85 

.97 
1.28 


»  Does  not  include  azoic  dyes  and  their  components  which  appear  in  the  Colour  Index  and  Foreign  Proto- 
type groups. 

The  dyes  are  grouped  according  to  Colour  Index  number,  or  accord- 
ing to  Foreign  Prototype  number,  or  are  listed  as  ungrouped  dyes. 
Of  a  total  production  of  152  million  pounds  of  dyes  reported,  sepa- 
rate statistics  on  individual  items  are  shown  for  119  million  pounds. 
Dyes  grouped  by  Colour  Index  number  accounted  for  110  million 
pounds  in  1944,  compared  with  107  million  pounds  in  1943.  Sales  of 
such  dyes  in  1944  were  108  million  pounds,  valued  at  60  million  dol- 
lars. Production  of  dyes  having  a  recognized  foreign  equivalent 
(prototype)  amounted  to  26  million  pounds  in  1944,  compared  with 
20  million  pounds  thus  grouped  in  1943.  This  increase  indicates  that 
an  increasing  number  of  dyes,  of  types  which  were  imported  before 
the  war,  are  now  being  made  by  domestic  producers.  The  output  of 
ungrouped  dyes  in  1944  was  15  million  pounds,  compared  with  17 
million  in  the  previous  year.  As  in  previous  years,  acetate  rayo 
dyes  were  the  most  important  type  of  ungrouped  dyes. 

Production  and  sales  of  dyes  by  chemical  classes  in  1944  are  shown 
in  table  8.  Of  the  dyes  produced  in  large  quantities,  antlii'aquinone 
vat  dyes  made  a  greater  proportional  gain  in  output  over  the  pre- 
vious year  than  any  other  chemical  class;  about  38  million  pounds  of 


SYNTHETIC   ORGANIC    CHEMICALS,    1944 


27 


these  dyes  was  produced  in  1944  compared  with  33  million  in  1943. 
Anthi'aquinone  vat  dyes  were  used  chiefly  for  dyeing  uniforms,  can- 
vas, and  other  textiles  of  the  armed  forces.  Production  of  azo  dyes 
also  increased  significantly,  totaling  55  million  pounds  in  1944  com- 
pared with  49  million  in  1943.  Sulfide  dyes  and  indigoid  and  thio- 
indigoid  dyes  were  among  the  important  chemical  classes  which  were 
produced  in  smaller  quantities  in  1944  than  in  1943. 

Table  8. — Synthetic  organic  chemicals:   United  States  'production  and  sales  of 
coal-tar  dyes,  by  chemical  class,  1944 


Chemical  class 


Production 


Sales 


Quantity 


Value 


Unit  value 


Grand  total 

Azo 

Anthraquinone  vat ' 

Indigoid  and  thioindigoid  vat 

Sulfide 

Triphenylmethane  and  diphenylnaphthylmeth 

ane 

Azine 

Anthraquinone 

Pyrazolone 

Ketonimine 

Xanthene 

Stilbene 

Nitro 

Oxazine 

All  other  2 


1 ,000  pounds 
151,653 


IftOOpounds 
150,  049 


1,000  dollars 
110,748 


Per  pound 
$0.74 


54,  921 
37,  739 
20, 435 
17, 990 

4,806 
3,908 
3,590 
1,572 
1,460 
1,396 
1,116 
82 
38 
2,600 


54,  444 
37,  348 
20,  742 
17,874 

4,277 
3,755 
3,422 
1,503 
1,559 
1,480 
1,028 
84 
41 
2,492 


35,  384 

44,  785 
5,408 
4,488 

5,592 

1,745 

4,888 

1,519 

1,299 

2,096 

669 

83 

53 

2,739 


.65 
1.20 
.26 
.25 

1.31 

.46 

1.43 

1.01 

.83 

1.42 

.65 

.98 

1.29 

1.10 


1  Includes  carbazole  vat  dyes. 

2  Includes  nitroso,  acridine,  quinoline,  thiazole,  aniline  black  and  allied  dyes,  thiazine,  rubber  colors,  and 
miscellaneous  mixtures;  these  groups  cannot  be  published  separately  without  disclosing  confidential 
information. 

Production  of  dyes  by  class  of  application  (such  as  acid,  direct, 
sulfur,  and  vat)  in  1943  and  1944  and  in  the  period  1938-42  is 
shown  in  table  9,  and  corresponding  data  on  sales  are  given  in  table 
10.  The  output  of  vat  dyes  (other  than  synthetic  indigo)  in  1944 
continued  the  sharp  upward  trend  which  had  prevailed  in  recent 
years.  It  amounted  to  41  million  pounds,  or  27  percent  of  all  dyes 
produced,  compared  with  25  percent  in  the  previous  year.  Produc- 
tion of  indigo  vat  dyes  was  17  million  pounds  in  1944,  a  drop  of 
half  a  million  from  1943.  Direct  dyes,  the  next  most  important 
class,  accounted  for  20  percent  of  total  production,  compared  with 
19  percent  in  the  previous  year.  Sulfur  dyes  and  acid  dyes  ac- 
c J^.nted  for  12  percent  and  11  percent  of  the  total,  respectively,  in 
1944.  Sales  of  vat  dyes  in  1944,  amounting  to  58  million  pounds 
valued  at  50  million  dollars,  accounted  for  39  percent  of  the  total 
quantity  of  all  dyes  sold  in  that  year.  Sales  of  direct  dyes  accounted 
for  20  percent  of  the  total  sales  in  1944. 


697646- 


28  UNITED    STATES   TARIFF    COMMISSION 

Table  9. — Synthetic  organic  chemicals:  United  States  production  of  coal-tar  dyes, 
by  class  of  application,  average,  1938-42,  annual,  1943-44 


Class  of  application 

Average, 
,   1938-42 

1943 

1944 

Quantity  (1,000  pounds) 

Total                                     -  -      -  - 

130, 051 

144, 013 

151, 653 

2,803 
16,  519 
3,969 
6,615 
31, 933 
3,820 
7,346 
19, 872 

35, 165 

2,512 
14,  512 
3,282 
5,502 
26, 903 
7,123 
9,693 
19,  561 

54, 104 

3,473 

17, 236 

3,d05 

6,758 

29,880 

4,352 

8,438 

17,990 

V^at,  total           

58,174 

14,  785 
20,  380 

2,009 

17,  770 
36, 334 

821 

17,  287 

other 

4.11  other          -  

40, 887 
1,547 

Percent  of  total  quantity 

Total  -        .  .  - 

100.0 

100.0 

100.0 

2.2 
12.7 
3.1 
5.1 
24.6 
2.9 
5.6 
15.3 

27.0 

1.7 
10.1 
2.3 
3.8 
18.7 
4.9 
6.7 
13.6 

37.6 

2.3 

11.4 

2.5 

4.4 

19.7 

2.9 

5.6 

Sulfur                                -  

11.9 

38.3 

11.4 
15.6 

1.5 

12.3 
26. 3 

.6 

11.4 

Other                      -         - 

26.9 

Ml  other                    

1.0 

Table  10. — Synthetic  organic  chemicals:   United  States  sales  of  coal-tar  dyes,  by  class 
of  application,  average,  1938-4^,  annual,  1943-44 


Class  of  application 


1944 


Quantity  (1,000  pounds) 


Total 

Acetate  rayon 

Acid 

Azoic 

Basic 

Direct 

Lake  and  spirit  soluble 
Mordant  and  chrome.. 
Sulfur  

Vat,  total. 

Indigo.. 

Other 

All  other. 


129, 322 

145, 499 

150, 049 

2,673 

2,990 

3,150 

16,  627 

15,456 

17,029 

3,856 

3,161 

3,930 

6,316 

5,365 

6,378 

32, 066 

28, 822 

29,  356 

3,750 

6,736 

4,309 

7,236 

9,869 

8,425 

19, 902 

19, 542 

17,874 

34, 927 

52, 684 

58, 090 

14, 521 

18,284 

17, 434 

20,406 

34, 400 

40, 656 

1,969 

874 

1,508 

SYNTHETIC    ORGANIC    CHEMICALS,    1944 


29 


Table  10. — Synthetic  organic  chemicals:   United  States  sales  of  coal-tar  dyes,  by  class 
of  application,  average,  1938-42,  annual,  194S-44 — Continued 


Class  of  application 


Average, 
1938^2 


1943 


1944 


Percent  of  total  quantity- 


Total 

Acetate  rayon 

Acid 

Azoic 

Basic--- 

Direct 

Lake  and  spirit  soluble 
Mordant  and  chrome  _- 
Sulfur 

Vat,  total 

Indigo 

Other 

All  other 


Total 

Acetate  rayon 

Acid 

Azoic 

Basic 

Direct 

Lake  and  spirit  soluble 
Mordant  and  chrome-. 
Sulfur 

Vat,  total --- 

Indigo 

Other -— 

Another 


Total.- 

Acetate  rayon 

Acid 

Azoic 

Basic 

Direct 

Lake  and  spirit  soluble 
Mordant  and  chrome  _. 
Sulfur 

Vat,  total 

Indigo --- 

Other 

All  other.- 


100.0 

100.0 

100.0 

2.1 

2.1 

2.1 

12.9 

10.6 

11.3 

3.0 

2.2 

2.6 

4.9 

3.7 

4.3 

24.8 

19.8 

19.6 

2.9 

4.6 

2.9 

5.5 

6.8 

5.6 

15.4 

13.4 

11.9 

27.0 

36.2 

38.7 

11.2 

12.6 

11.6 

15.8 

23.6 

27.1 

1.5 

.6 

1.0 

Value  (1,000  dollars) 

82, 498 

105,  350 

110,  748 

2,577 

2,915 

3,164 

13,610 

13,579 

13,293 

5,494 

4,661 

5,577 

6,023 

5,449 

6,449 

18, 481 

17, 561 

17, 109 

2,876 

5,478 

2,944 

3,931 

5, 777 

4,621 

5,213 

4,956 

4,488 

22, 477 

43, 924 

50, 193 

2,296 

2,819 

2,856 

20, 181 

41, 105 

47,  337 

1,816 

1,050 

2,910 

Percent  of  total  value 

100.0 

100.0 

100.0 

3.1 

2.8 

2.9 

16.5 

12.9 

12.0 

6.7 

4.4 

5.0 

7.3 

5.2 

5.8 

22.4 

16.6 

15.5 

3.5 

5.2 

2.7 

4.8 

5.5 

4.2 

6.3 

4.7 

4.0 

27.2 

41.7 

45.3 

2.8 
24.4 


2.2 


2.7 
39.0 


1.0 


2.6 
42.7 


2.6 


Production  and  sales  of  azoic  dyes  and  their  components  are  shown 
in  table  11.  Output  of  this  group  totaled  3.8  million  pounds,  com- 
pared with  3.2  million  in  the  previous  year.  Sales  amounted  to  3.9 
million  pounds,  valued  at  5.6  million  dollars. 


30 


UNITED    STATES    TARIFF    COMMISSION 


Table    11. — Synthetic  organic  chemicals:    United  States   ■production   and  sales   of 
azoic  dyes  and  their  components,  1944 


For- 
eign 

Dye  or  component 

Production 

Sales 

Proto- 
type 

No. 

Quantity 

Value 

Unit  value 

Grand  total  i.      . 

/ ,000  pounds 
3,805 

1,000  pounds 
3,930 

1,000  dollars 

5,577 

Per  pound 
$1  42 

Dyes  and  components  for  which  sep- 
arate statistics  may  not  be  shown 

Dyes  and  components  for  which  sep- 
arate statistics  are  shown  below 

DYES 
Rapid  fast 

371 
3,434 

623 
3,307 

41 
1,251 

1,243 
4,334 

74 
2,294 

1.99 
1.31 

1  79 

Rapidogen,  total .. 

1,172 

1  83 

Blue  D 

164 

187 
71 
86 
36 
120 
273 
117 
121 
161 

27 

(*) 

<29 

110 

155 

2  282 
82 
41 
123 
269 
140 
113 
201 

32 
26 
15 
134 

154 
6 

71 
92 
122 

5  286 
279 

2  495 

179 

lis 

197 
402 
247 
213 
443 

31 
59 
35 
74 
238 
6 

49 
92 
76 

S251 
164 

0) 
1.75 

Blue 

Bordeaux. -- 

2  20 

Brown.-    .    .  .               

2  84 

169 

RedRS 

1  61 

Red -- 

1  49 

Scarlet- 

1  76 

Yellow.. 

1  88 

Other .-                 ... 

2  20 

264 

COMPONENTS 

Fast  color  bases: 
Orange  ^ .  ... 

97 

270 

Red 

2  25 

94 

Red 

Scarlet  s...    ...                .. 

2.39 
.55 

Scarlet ...  ... 

1.55 

275 

Yellow  3 

1.07 

260 

Fast  color  salts: 
Blue 

Bordeaux' ._. 

78 
81 
115 
27 
212 
285 

1,143 

.70 
1.00 

269 

Red ...    .  . 

.63 

273 

Red  3.              

.88 
.59 

Red 

Scarlet 

Naphthols,  total 

Naphthol  AS . 

302 

620 
114 
63 

672 

85 

17 

5 

19 

645 

144 

33 

12 

57 

.96 

305 
306 

Naphthol  AS-BS 

Naphthol  AS-D 

1.68 
2.00 

312 

Naphthol  AS-RL..    ... 

2.43 

314 

Naphthol  AS-TR. 

21 
325 

2.98 

All  other .. 

'  Totals  shown  represent  all  azoic  dyes  and  their  components.    Totals  shown  in  table  7A  represent  un- 
grouped  azoic  dyes  and  their  components  only. 
2  Blue  and  blue  Foreign  Prototype  No.  164  combined. 
'  Base  and  salt. 

*  Red  base  and  red  Foreign  Prototype  No.  270  combined. 
«  Red  salt  and  red  Foreign  Prototype  No.  273  combined. 

LAKES  AND  TONERS 

Lakes  and  toners  are  synthetic  organic  pigments  used  to  color 
paints  and  varnishes,  wallpapers,  printing  inks,  plastics,  and  other 
industrial  products.  Lakes  are  organic  pigments  prepared  by  pre- 
cipitating a  soluble  dye  on  the  surface  of  an  inorganic  compound, 
known  as  the  substrate.  Toners,  or  full-strength  colors,  are  insoluble 
organic  pigments.  Reduced  or  extended  toners  are  toners  to  which 
a  solid  diluent  has  been  added. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


31 


Data  on  production  and  sales  of  lakes  and  toners  in  1944  are  given 
in  table  12A  (see  also  table  12B,  part  III,  for  an  alphabetical  list  of 
these  products  in  which  the  manufacturers  are  identified).  Sta- 
tistics not  publishable  as  individual  items  have  been  classified  as  far 
as  possible  in  color  groups. 


Table  12A.- 


-Synthetic  organic  chemicals:    United  States  production  and  sales 
of  lakes  and  toners,  1944 


[Listed  below  are  all  lakes  and  toners  for  which  any  reported  data  on  production  or  sales  may  be  published. 
(Leaders  are  used  where  the  reported  data  are  confidential  and  may  not  be  published  or  where  no  data 
were  reported.)  Table  12B  in  part  III  lists  alphabetically  all  lakes  and  toners  for  which  data  on  pro- 
duction or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Product 

Production 

Sales 

Quantity 

Value 

Unit  value 

Grand  total                                     .    .  -- 

1,000  pounds 
19, 197 

1,000  pounds 
18, 401 

1,000  dollars 
13, 793 

Per  pound 

$0.  75 

LAKES  OR  LAKE  COLORS 
Total - 

5,741 

5,098 

2,317 

.45 

Products  for  which  separate  statistics  may  not  be 
shown -.-  ...  

1,626 

4,115 

82 

1,776 

1,594 

3,504 

75 

1,259 

505 

1,812 

43 

766 

.32 

Products  for  which  separate  statistics  are  shown 
below..  ...  ...  ...  ._ 

.52 

Black  lakes 

.57 

.61 

Indanthrene  blue  ...       .         ..  .      

15 

4 

1.574 

39 

144 

26 

189 

20 

5 

1.100 

33 

101 

43 

3 

649 

18 

53 

2.18 

Methylene  blue  

.55 

Peacock  blue  (Patent  blue) 

.59 

Victoria  blue .                .                      .  . 

.54 

Another 

.53 

Green  lakes,  total 

173 

87 

.50 

Acid  green 

20 
47 
37 
85 

48 

234 

58 

316 

20 

12 

.62 

Naphthol  green ..                        ... 

Pigment  green     .  

38 
115 

44 

240 

61 

275 

13 

62 

38 
73 
50 

104 

.34 

All  other 

.53 

Maroon  lakes: 
Alizarin  maroon 

.87 

Azo  Bordeaux 

.30 

Helio  fast  rubine           .           .... .    .. 

.82 

Orange  lakes,  total 

.38 

Persian  orange 

223 
93 

88 

22 

3 

9 

941 

104 

188 
87 

91 

24 

4 

8 

946 

105 

84 
20 

125 
22 
6 
8 

293 

67 

.45 

All  other .  .  . 

.23 

Red  lakes: 
Alizarin  red 

1.37 

Eosine  and  phloxine ..     .. 

.89 

Rhodamine ...  

1.37 

Rose  and  pink  lakes    - 

1.05 

Scarlet  2R ..    . 

.31 

Violet  lakes,  total              ..        ..           .    . 

.64 

Methyl  violet ... 

91 
13 

219 

94 
11 

199 

63 
130 

.67 

All  other 

.37 

Yellow  lakes,  total 

.65 

Fast  light  yellow.              .                            

24 
14 
34 
102 
45 

26 
13 

27 
115 
18 

22 
9 
23 
65 
11 

.86 

Naphthol  yellow    

.69 

Quinoline  yellow 

.84 

Tartrazine       ..  ...     _             ... 

.57 

Another 

.60 

32 


UNITED    STATES   TARIFF    COMMISSION 


Table  12A. — Synthetic  organic  chemicals:    United  States  production  and  sales 
of  lakes  and  toners,  1944 — Continued 


Product 

Production 

Sales 

Quantity 

Value 

Unit  value 

TONERS  OR  FULL-STRENGTH  COLORS 

Total     ...                       .      . 

1,000  pounds 
9,867 

1,000  pounds 
9,610 

1,000  dollars 
9,571 

Per  pound 
$1  00 

Products  for  which  separate  statistics  may  not  be 
shown 

30 

9,837 

667 

28 

9,582 

668 

54 
9,517 
1,572 

1  93 

Products  for  which  separate  statistics  are  shown 
below .. 

99 

Blue  toners,  total .                           ..  . 

2  35 

PMA  Victoria  blue_ 

37 
20 
55 
14 
541 

1 

320 

27 
17 
56 
15 
553 

1 

289 

86 
65 
173 
32 
1,216 

1 

814 

3  19 

PTA  Peacock  blue.    .- 

3  87 

PTA  Victoria  blue 

3  09 

PTA  Blue,  other    

2  22 

Another 

2  20 

Brown  toners .  ..      ...      .  -. 

1  81 

Green  toners,  total .  ... 

2  82 

PMA  Brilliant  green 

37 
30 

7 
23 

8 

19 

196 

69 
6 
58 

171 

24 

28 
6 

19 
7 

18 
187 

74 
6 
59 

182 

71 
92 
21 
58 
21 
46 
505 

76 

5 

163 

174 

2  96 

PTA  Brilliant  green. 

3  26 

Brilliant  green,  other.    .. 

3  43 

PMA  Malachite  green ... 

2  98 

PTA  Malachite  green 

3  11 

PTA  Green,  other 

2  56 

All  other 

2  70 

Maroon  toners: 
Lithol  maroon 

1  03 

a-Naphthylamine  maroon 

.86 

Toluidine  maroon.. 

2  75 

Orange  toners,  total 

.96 

2,4-Dinitroaniline  orange 

72 
64 
35 

7,247 

84 
65 
33 

7,056 

81 
47 
46 

5,261 

97 

o-Nitroaniline  orange.    .. 

72 

All  other 

1  40 

Red  toners,  total .  . 

75 

o-Chloronitroaniline  red 

296 

352 

3,404 

193 

799 

403 

44 

10 

22 

42 

2 

496 

8 

1,045 

131 

278 
32 
36 
33 

7 

912 

316 

211 

3,232 

198 

838 

456 

45 

5 

18 

40 

2 

388 

16 

1,119 

172 

222 
31 
31 
36 

8 

919 

251 

229 

1,745 

193 

522 

315 

71 

19 

69 

150 

3 

329 

11 

1,144 

210 

148 
39 
36 
73 
17 

1,138 

79 

Eosine  and  phloxine 

1  08 

Lithol  red 

.54 

Lithol  rubine  .. 

98 

Para  red,  hght 

62 

Parared.dark 

69 

Permanent  red  2B 

1.57 

PMA  Red 

4.09 

PTA  Rhodamine  B.. 

3  83 

PTA  Rhodamine  Y .. 

3.73 

PTA  Red,  other... 

1.99 

Red  lake  C 

84 

RedlakeD . 

69 

Toluidinered .. 

1.02 

Another 

1  22 

Violet  toners: 
Methyl  violet,  other  than  PMA  or  PTA 

PMA  Methyl  violet 

.67 
1.25 

PMA  Violet,  other 

1.16 

PTA  Methyl  violet . 

2.00 

PTA  Violet,  other 

2.21 

Yellow  toners,  total 

1.24 

Benzidine  yellow 

581 

279 

52 

3,589 

578 

295 

46 

3,693 

750 

334 

54 

1,905 

1.30 

Hansa  yenow 

1.13 

Another 

1.17 

EXTENDED  OR  REDUCED  TONERS 
Total. 

.52 

Products  for  which  separate  statistics  may  not  be 
shown 

759 
2,830 

807 
2,886 

334 
1.571 

.41 

Products  for  which  separate  statistics  are  shown 
below 

.54 

SYNTHETIC   ORGANIC    CHEMICALS,    1944 


33 


Table  12 A. — Synthetic  organic  chemicals:    United  States  production  and  sales 
of  lakes  and  toners,  1944 — Continued 


Product 

Production 

Sales 

Quantity 

Value 

Unit  value 

EXTENDED  OR  REDUCED  TONERS— 
Continued 

Blue  toners,  reduced,  total 

1,000  pounds 
988 

1,000  pounds 
985 

1,000  dollars 
791 

Per  pound 
$0.80 

PMA  Victoria  blue.  . 

29 
104 

24 
342 

26 
137 

23 

340 

2 

457 

47 
9 

59 

19 
93 
37 

299 
2 

341 

28 
6 

32 

.73 

PMA  Blue,  other                            .    

.68 

PTA  Peacock  blue.  .  .  

1.62 

Phthalocyanine  blue  B .__ . 

.88 

Phthalocyanine  blue  G ..  . 

1.24 

All  other             ...        .      .    

489 

55 
7 

37 
8 
5 

20 

1,113 

.75 

Green  toners,  reduced: 
PMA  Brilliant  green  .  . 

.58 

.70 

PTA  Brilliant  green 

(1) 

PTA  Green,  other                        -      _  .  . 

.54 

14 
1,188 

6 
483 

.45 

.41 

Litholred                  ..    .  .    

142 

90 

131 

153 

15 

15 

27 

158 

382 

23 

27 

547 

158 

93 

161 

192 

15 

11 

25 

142 

391 

34 
26 

524 

52 
44 
21 
26 
14 
18 
11 
44 
253 

18 
23 

184 

.33 

.47 

Para  red,  light. .  - 

.13 

Para  red,  dark                                               .  _ 

.14 

PTA  Rhodamine  B. 

.97 

PTA  Rhodamine  Y 

1.69 

Red  lake  C 

.45 

Toluidine  red                          ...             _      . 

.31 

All  other ... 

.64 

Violet  toners,  reduced: 
PMA  Violet                             

.53 

PTA  Violet,  methyl  and  other 

.88 

Yellow  toners,  reduced,  total    .      .... 

.35 

Hansa  yellow                          .  - 

489 

58 

465 
59 

144 
40 

.31 

Another...    . 

,    .68 

'  Included  in  "PTA  Green,  other." 

Note.— The  abbreviations  PMA  and  PTA  stand  for  phosphomolybdic  acid  and  phosphotungstic  acid, 
respectively. 

Data  were  obtained  in  1944  in  more  detail  than  in  previous  years, 
and  phosphomolybdic  acid  (PMA)  and  phosphotungstic  acid  (PTA) 
toners  are  now  further  identified  by  the  dye  component  of  the  pigment 

Production  of  organic  pigments  totaled  19.2  million  pounds  in  1944, 
an  increase  of  3  million  pounds  over  that  of  1943,  but  considerably 
less  than  the  record  of  26  million  pounds  in  1941,  when  consuming 
industries  were  building  up  stocks.  Sales  were  23  percent  higher  in 
quantity  than  in  1943  and  33  percent  higher  in  value.  The  output  of 
lake  colors  in  1944  was  almost  the  same  as  in  1943,  but  that  of 
toners  increased  substantially.  The  most  important  products  among 
the  lakes  were  peacock  blue  (patent  blue)  and  scarlet  2R;  among 
the  toners,  lithol  reds,  para  reds,  and  toluidine  red;  and  among 
the  reduced  toners,  phthalocyanine  blues  and  hansa  yellows. 

Production  of  lakes  and  toners  in  1944  was  restricted  somewhat 
by  shortages  of  the  organic  intermediates  and  other  raw  materials 
as  a  result  of  diversions  of  these  materials  to  products  considered 
more  essential  to  the  war.  In  order  to  insure  equitable  distribution 
of  existing  supplies,  consumption  of  organic  pigments  in  printing 
inks,  controlled  by  War  Production  Board  Conservation  Order  M-53, 


34 


UNITED    STATES   TARIFF    COMMISSION 


and  of  dyes  and  organic  pigments  in  nonmilitary  uses,  controlled  by 
Conservation  Order  M-103,  was  maintained  at  approximately  70 
percent  of  the  quantity  consumed  in  1941.  The  growing  shortage 
of  paper  also  contributed  to  the  decreased  consumption  of  organic 
pigments  in  printing  inks  and  wallpapers. 

MEDICINALS 

Statistics  on  production  and  sales  of  medicinals  are  divided  into 
three  subgroups — benzenoid  compounds  (usually  derived  from  coal 
tar) ;  alicyclic  and  heterocyclic  compounds,  which  may  be  derived 
from  sources  such  as  terpenes  from  wood  and  cholesterol  from 
animal  tissue;  and  acyclic  compounds,  which  are  usually  derived 
from  grain,  natural  gas,  and  petroleum  hydrocarbons.  The  products 
of  each  group  differ  pharmacologically  and  chemically.  Production 
and  sales  of  medicinals  in  1944  are  shown  in  table  13A  (see  also  table 
1.3B,  part  III,  for  an  alphabetical  list  of  these  products  in  which  the 
manufacturers  are  identified). 


Table   13A.- — Synthetic  organic  chemicals:    United  States  production  and  sales  of 

medicinals,^  1.944 

[Listed  below  are  all  synthetic  orp;anic  medicinals  for  which  any  reported  data  on  production  or  sales  may 
be  published.  (Leaders  are  used  where  the  reported  data  are  confidential  and  may  not  be  published  or 
where  no  data  were  reported.)  Table  13B  in  part  in  lists  alphabetically  all  those  medicinals  for  which 
data  on  production  or  salas  were  reported  and  identifies  the  manufacturer  of  each] 


Product 


.Grand  total _ 

MEDICINALS,  CYCLIC 
Total 

Chemicals  for  which  separate  statistics  may  not 
be  shown..- 

Chemicals  for  which  separate  statistics  are  shown 
below 

Benzenoid 
Total... 

Acetanilide 

Acetyl-p-aminophenyl  salicylate  (Phenetsal) 

N-Acetyl-4-hydroxy-m-arsanilic  acid  (Acctarsone) 

(Stovarsol) 

Acetylsalicylic  acid  (Aspirin) 

Acetyltannic  acid  (Tannigen)  (Tannyl  acetate) .  _ 

p-Aminobenzoic  acid  derivatives,  total - . . 

i8-Diethylaminoethyl  p-aminobenzoate  hydro- 
chloride (Procaine  hydrochloride) 

Ethyl  p-aminobenzoate  (Benzocaine)  (Anaes- 
thesine). 

All  other 

3-Amino-4-hydroxyphenyldichloroarsine  hydro- 
chloride (Dichlorophenarsine  hydrochloride)... 

Benzaldehyde 

Benzoic  acid  salts  ^ 

Benzyl  benzoate  ♦ 

Bismuth  compounds: 

Bismuth  subgallate 

Bismuth  subsalicylate 

See  footnotes  at  end  of  table. 


Sales' 


Production 

Quantity 

Value 

Unit  value 

1,000  pounds 
38,751.1 

],000  pounds 
36,212.4 

1,000  dollars 
111,794.4 

Per  pound 
$3.09 

35, 353.  3 

33, 103. 3 

94,038.8 

2.84 

7,  234.  5 

7,371.7 

18,229.2 

2.47 

28,118.8 

25,  731.  6 

75,  809.  6 

2.95 

28, 489. 0 

26,  445.  6 

.34,  935.  3 

1.32 

620.9 

9.8 

597.  9 
9.3 

175.4 
41.4 

.29 
4.44 

11.6 

9,  423.  4 

5.6 

11.4 

9, 325.  3 

4.1 

326.  0 

3,  676. 0 

14.4 

28.59 

.39 

3.51 

141.8 

96.0 

612.3 

6.38 

44.7 

20.2 

127.7 

6.30 

71.3 
25.8 

55.9 
19.9 

171.6 
313.0 

3.07 
15.73 

1.4 
269.2 

8.7 
432. 6 

.5 

122.5 

250.  54 

7.0 
437.1 

10.7 
438.7 

1.52 
1.00 

32.5 
66.5 

40.6 
79.2 

58.3 
197.0 

1.44 
2.48 

SYNTHETIC   ORGANIC    CHEMICALS,    1944 


35 


Table   13 A.- — Synthetic  organic  chemicals:   United  States  'production  and  sales  of 
medicinals,^  1944 — Continued 


Product 


Production 


Sales  2 


Quantity 


Value         Unit  value 


MEDICINALS,  CYCLIC— Continued 

Bemenoid — Continued 

dl-Desoxyephedrine,  and  d-desoxyepliedrine  and 
dl-desoxyephedrine  hydrochloride  (all  isomers) . 

Diethylstilbestrol 

Dyes,  medicinal- - 

(3-Naphthyl  benzoate 

Neoarsphenamine 

Phenolsulfonic  acid  salts 

Salicylic  acid 

Salicylic  acid  salts,  total 


Sodium  salicylate. 

Another 

Sulfa  drugs,  total 


Sulfanilamide  (p-Aminobenzenesulfonamide) . 

Sulfathiazole 

Sulfathiazole,  sodium 

All  other 


Sulfoarsphenamine 

Tannin  albuminate  (Tannalbin). 

Vitamin  K,  all  forms 

All  other 


Total - 


Alicydic  and  Heterocyclic 


Amino  acids  derived  from  proteins. 
Antipyrine  salicylate 


Barbituric  acid  derivatives,  total 

5-Ethyl-5-phenylbarbituric  acid  (Phenobar- 
bital)  (Luminal) 

5-Ethyl-5-phenylbarbituric  acid,  sodium  salt 
(Phenobarbital  sodium) 

All  other 

Bile  acids  and  salts,  total 


Cholic  acid 

Dehydrocholic  acid  and  sodium  salt- 
All  other 

Cafleine 

C  afleine  derivatives,  total : . 


C  afieine  citrate 

CafTeine  sodium  benzoate  and  cafleine  sodium 
salicylate 


C  amphosulfonic  acid  and  salts 

Hexamethylenetetramineanhydromethylene  ci- 
trate (Helmitol) 

7-Iodo-8-hydroxyquinoline-5-sulfonic  acid  ( Yatren 
acid)  and  salt 

2-Methoxy-6-chloro-9-diethylaminopentylamino- 
acridine  (Quinacrine  hydrochloride)  (Atebrin). 

p-Methylphenylcinchoninic  ethyl  ester  (Neocin- 
chophen) 

Nikethamide  (Niacin  diethylamide) 

Progesterone 

Theobromine  derivatives,  total 


1.000  pounds 

.1 

.4 

86.1 

8.2 

16.9 

1,360.7 

5, 469. 4 

1,431.5 


Theobromine  and  sodium  salicylate 

All  other 

Theophylline  (1,3-Dimethylxanthine)  and  deriv- 
atives, total 


Theophylline  base 

See  footnotes  at  end  of  table. 


1,000  pounds 

.1 

.5 

38.5 

11.6 

13.6 

1, 077.  5 

3,  661. 4 


1,386.9 

44.6 

4,514.5 


748.0 

1, 498. 8 

55.0 

2,  212.  7 

2.4 

3.4 

.4 

4,571.0 


6, 864.  3 


1.1 

2.2 


205.4 

28.3 
325.5 
108.3 


39.4 
23.7 
45.2 
646.6 
62.8 


46.2 
16.6 
4.3 
15.0 
43.4 
853.7 


(») 


25.9 


92.0 
28.9 


118.9 


1,000  dollars 

5.1 
158.9 
625.5 
19.7 
436.  e 
286.9 
964.6 


1,352.8 
5,  012.  7 


1,193.2 

1,913.0 

34.9 

1,871.6 


2.9 

.2 

4,  665.  4 


6,  657.  ■; 


1.1 
3.1 


221.6 

54.2 
282.6 
96.7 


23.5 

73.2 

657.3 

63.0 


46.5 

16.5 

3.9 

11.2 

44.5 

853.3 

7.8 
27.2 


C) 


Per  pound 

$47.  24 

344.  64 

16.25 

1.70 

32.18 

.27 

.26 


17,  ( 


1, 106. 1 

4, 877.  7 

121.0 

10,  983.  3 


9.6 

23.5 

9,  045.  5 


59, 103.  5 


112.4 
4.4 


3,119.8 


795.2 

193.7 

2, 130.  9 

380.4 


246.1 

134.3 

1,732.3 

146.3 


92.5 

53.8 

15.9 

27.9 

320.4 

8, 901.  4 

55.6 
437.5 
555.5 
252.8 


88.0 
32.2 


178.0 
74.8 


1,711.6 


99.2 


690.0 


.44 
3.41 


.93 
2.55 
3.46 

5.87 


3.35 

117.50 

1.94 


102. 18 
1.42 


3.59 

3.57 
7.54 
3.93 


10.46 
1.83 
2.64 
2.32 


1.99 

3.26 

4.08 

2.48 

7.21 

10.43 

7.15 

16.08 

21, 366.  50 

2.10 


2.02 
2.32 


36 


UNITED    STATES   TARIFF    COMMISSION 


Table  13A. — Synthetic  organic  chemicals:  United  States  production  and  sales  of 
medicinals,^  194-4 — Continued 


Product 


MEDICINALS,  CYCLIC— Continued 

Alicyclic  and  Heterocyclic— Cont'inned 

Theophylline  (1,  3-Dimethylxanthme)  and  deriva- 
tives— Continued 
Theophylline    ethylenediamine    (Aminophyl- 

line) 

All  other --- - 

Vitamins,  total. --. 


Bi  (Thiamin) 

Bj  (Riboflavin)  for  human  use 

B(j  (Pyridoxine) 

Dj  (Irradiated  ergosterol)  (Viosterol)  «- 

Niacin  and  niacinamide 

All  other 


All  other. 


MEDICINALS,  ACYCLIC 


Total. 


Chemicals  for  which  separate  statistics  may  not 
be  shown 

Chemicals  for  which  separate  statistics  are  shown 
below... 


Cacodylic  acid 

Cacodylic  acid  salts 

Calcium  lactophosphate.- 

Calcium  levulinate 

Ethyl  iodide.- 

Iodoform 

Methyl  iodide 

Silver  preparations,  colloidal.. 

Tartaric  acid  salts 

Thiosinamine  ( Allylurea) 

tert-Trichlorobutyl  alcohol  (Chloretone)  (Chloro- 

butanol) 

Vitamins,  total 


Production 


1,000  pounds 


93.9 

14.3 

1,530.3 


152.9 

84.6 

4.2 

307.9 

939.7 

41.0 

2, 663.  5 


3,  397. 8 


2, 082. 4 
1,  315.  4 


2.3 


6.3 
10.0 


A  (all  esters) 

C  (Ascorbic  acid  and  sodium  salt,  and  Iso- 

ascorbic  acid) 

Pantothenic  acid  salts. 


7.2 

46.1 

.5 

.2 

23.9 
1,  218.  9 


Sales  2 


Quantity 


1,000  pounds 


93.7 

12.2 

1,  298.  6 


122.6 

60.1 

3.0 

304.2 

774.5 

34.2 

2,  706.  3 


3, 109. 1 


1, 833. 1 
1,  276.  0 

.5 
2.4 
7.2 
6.9 
10.2 


7.7 
5.7 
46.8 
.2 
.1 

29.2 
1, 159. 1 


9.0 

1, 177.  2 
32.7 


7.6 


1,123.6 
27.9 


Value         Unit  value 


1,000  dollars 


903.5 

118.1 

32, 145.  6 


9,  740. 9 
6,  293.  7 
1,337.3 
1, 926.  4 
3,  007.  8 
9,  839.  5 
9, 183.  7 


17, 755.  6 


2, 962.  2 
14,  793.  4 

7.5 
26.1 

5.3 
11.0 
25.7 

32.0 

21.1 

144.7 

1.2 

.6 

59.9 
14,  458.  3 


Per  pound 


$9.64 
9.67 
24.75 


79.43 

104.  65 

454.  56 

6.33 

3.88 

288.05 

3.39 


5.71 


397.9 

13, 192.  7 
867.7 


1.62 
11.59 

14.75 

10.82 

.73 

1.60 

2.53 

4.18 
3.68 
3.09 
6.00 
4.56 

2.06 
12.47 


52.36 


11.74 
32.22 


•  Represents  statistics  of  production  and  sales  of  bulk  medicinals  only.  These  statistics  do  not  include 
the  production  of  finished  preparations,  such  as  tablets,  capsules,  or  ampoules,  which  are  manufactured 
from  bulk  medicinals.  The  quantity  and  value  of  sales  are  for  bulk  medicinals  or  the  bulk  equivalent  of 
medicinals  whicti  are  compounded  into  finished  preparations. 

'  Sales  represent  the  combined  quantity  of  sales  to  another  company  and  the  quantity  of  interplant 
transfers  for  consumption,  i.  e.,  the  transfer  within  a  company  from  the  division  which  manufactures  the 
bulk  medicinal  to  another  division  which  makes  it  into  a  finished  consumer  product.  The  value  of  sales 
represents  the  combined  sales  value  and  the  value  (at  the  prevailing  market  price)  of  interplant  transfers 
for  consumption. 

'  Does  not  include  sodium  benzoate. 

« Includes  non-U.  S.  P.  grade. 

*  Less  than  50  pounds. 

» In  million  U.  S.  P.  units,  these  data  would  be  as  follows;  Production,  33,905,981;  sales,  32,165,411,  valued 
at  $1,926,378.    The  unit  value  per  million  U.  S.  P.  units  is  6  cents. 

To  avoid  duplication  in  these  figures,  all  data  are  given  in  terms 
of  bulk  medicinals.  This  practice  has  been  followed  in  the  Com- 
mission's reports  beginning  with  that  for  1942.  Before  that  year, 
the  figures  given  in  these  reports  represented  production  and  sales 
which  were  partly  in  bulk  form  and  partly  in  the  form  of  finished 
products  such  as  tablets,  ampoules,  and  perles.  Reports  from  dif- 
ferent manufacturers  were,  therefore,  not  entirely  comparable. 


SYNTHETIC   ORGANIC    CHEMICALS,    1944  37 

Medicinals  were  the  only  group  of  synthetic  organic  chemicals 
produced  in  smaller  volume  in  1944  than  in  1943.  Production 
amounted  to  39  million  pounds  in  1944  compared  with  56  million 
pounds  in  1943;  sales  in  1944  were  36  million  pounds,  valued  at  112 
million  dollars,  a  considerable  decrease  from  the  52  million  pounds, 
valued  at  140  million  dollars,  sold  in  1943. 

Cyclic  medicinals  represented  in  1944  approximately  91  percent 
of  the  output  of  all  synthetic  organic  medicinals.  Benzenoid  deriva- 
tives accounted  for  81  percent  of  the  cyclic  compounds,  and  alicyclic 
and  heterocyclic  compounds  for  19  percent. 

Among  the  more  important  benzenoid  medicinal  compounds  were 
acetylsalicylic  acid  (aspirin);  salicylic  acid;  sulfa  drugs;  salicylic 
acid  salts,  principally  sodium  salicylate ;  and  phenolsulfonic  acid  salts. 

The  production  of  acetylsalicylic  acid  (aspirin)  in  1944  set  a  new 
record  of  9.4  million  pounds ;  this  was  an  increase  of  more  than  700,000 
pounds  over  that  of  the  previous  year.  Sales  totaled  9.3  million 
pounds,  valued  at  3.7  million  dollars. 

Production  of  salicylic  acid,  which  decreased  slightly  during 
1941-43,  rose  to  a  new  high  of  5.5  milhon  pounds  in  1944.  The  aver- 
age unit  value  of  sales  dropped  to  26  cents  per  pound  in  1944  after 
having  reached  29  cents  in  1942. 

Phenolsulfonic  acid  salts  (principally  the  sodium  and  zinc  salts), 
which  are  used  as  anti-infective  agents,  have  steadily  increased  in 
production  from  566,000  pounds  in  1941  to  more  than  twice  as  much 
(1.4  million  pounds)  in  1944.  Sales  also  rose,  from  566,000  pounds, 
valued  at  $145,000,  in  1941  to  1.1  million  pounds,  valued  at  $287,000, 
in  1944. 

Production  of  sulfa  drugs,  which  totaled  10  million  pounds  in  1943, 
fell  sharply  to  4.5  million  in  1944.  Current  demand  was  able  to 
draw  upon  the  fairly  large  stock  piles  accumulated  during  1942  and 
1943.  Competition  with  the  newer  antibiotics  such  as  penicillin, 
which  were  preferred  in  some  clinical  applications,  also  may  have 
contributed  to  the  decline  in  production.  Sulfathiazole  continued 
as  the  principal  sulfa  drug. 

Production  of  acetanilide  in  1944  decreased  to  621,000  pounds 
from  the  level  of  840,000  pounds  in  1942  and  in  1943. 

The  output  of  p-aminobenzoic  acid  derivatives,  which  include 
compounds  such  as  jS-diethylomino ethyl  p-aminobenzoate  hydro- 
chloride (procaine  hydrochloride),  ethyl  p-aminobenzoate  (benzo- 
caine  or  anaesthesine),  and  isobutylaminoethyl  p-aminobenzoate 
(monocaine),  was  142  million  pounds  in  1944;  this  quantity  repre- 
sented a  decline  of  about  5  percent  from  the  1943  level.  The  average 
unit  value  of  sales  of  these  compounds  dropped  from  $10.10  per  pound 
in  1943  to  $6.38  in  1944. 

Although  penicillin  was  the  most  important  heterocyclic  medicinal 
produced  in  1944,  statistics  on  production  and  sales  of  this  product 
are  not  included  with  those  on  medicinals  for  that  year  because  pro- 
duction was  still  largely  on  an  experimental  basis.  Sales,  completely 
under  Government  control,  were  almost  entirely  to  the  armed  forces, 
and  at  a  price  many  times  that  which  prevailed  early  in  1945.  Pro- 
ductipn  in  1944  is  estimated  at  1.6  trillion  Oxford  units,  valued  at 
35  million  dollars. 

The  demand   for  2-methoxy-6-chloro-9-diethylaminopentylamino- 


38  UNITED    STATES   TARIFF    COMMISSION 

acridine  (quinacrine  hydrochloride  or  atebrin),  the  most  important 
antimalarial,  continued  to  increase  in  1944.  Production  reached 
854,000  pounds;  sales  were  853,000  pounds,  valued  at  8.9  million 
dollars.  In  1943,  sales  amounted  to  504,000  poimds,  valued  at  6.2 
million  dollars. 

Sales  of  synthetic  caffeine  in  1944  slightly  exceeded  production  of 
that  product;  they  amounted  to  657,000  pounds,  valued  at  1.7  million 
dollars,  compared  with  468,000  pounds,  valued  at  $821,000,  in  1943. 

Production  of  barbituric  acid  derivatives,  used  by  the  military 
forces  and  in  medicine  for  treatment  of  shock  and  as  a  soporific, 
amomited  to  559,000  pounds  m  1944,  compared  with  583,000  iii  1943 
and  607,000  in  1942. 

The  sales  value  of  all  bulk  vitamins  amounted  to  47  million  dollars 
in  1944,  a  considerable  drop  from  the  value  of  61  million  dollars  in 
1943,  owmg  chiefly  to  a  marked  decrease  in  prices  in  1944.  An  ap- 
parent decrease  m  the  quantity  of  some  of  the  vitamins  produced  is 
the  result  of  converting  to  a  100-percent  basis,  data  which  had  pre- 
viously been  incorrectly  reported  on  a  more  dilute  basis.  Several  of 
the  vitamins  were  produced,  however,  m  larger  quantity  in  1944  in 
accordance  with  increased  demand  and  the  flour-enrichment  program. 
The  combmed  output  of  niacm  and  niacinamide,  the  pellagra- 
preventive  vitamins,  was  940,000  pounds  in  1944.  Statistics  on 
production  and  sales  of  vitamins  Bi  (thiamin)  and  Bg  (pyridoxine) 
are  reported  separately  for  the  first  time.  In  1944  the  output  of  Bi 
was  153,000  pounds;  sales  were  123,000  pounds,  valued  at  9.7  million 
dollars.  Production  of  pyridoxine  was  4,200  pounds,  and  sales  were 
3,000  pounds,  valued  at  1.3  million  dollars. 

The  most  important  item  m  the  acyclic  subgroup  of  medicinals  was 
ascorbic  acid,  the  output  of  which  totaled  about  1.2  million  pounds,  a 
gam  of  about  400,000  pounds  over  1943.  Sales  of  this  vitamin  were 
valued  at  13  million  dollars  out  of  a  total  of  18  million  for  the  entire 
group  of  acyclic  medicinals. 

FLAVOR  AND  PERFUME  MATERIALS 

The  flavor  and  perfume  materials  included  in  this  report  are  organic 
chemicals  synthesized  from  natural  crude  materials  or  from  cyclic  or 
acyclic  chemical  intermediates;  floral  extracts  or  flavors  obtained  by 
extraction  or  distillation  from  natural  substances  are  not  included. 
Statistics  on  production  and  sales  of  these  synthetic  flavor  and  perfume 
materials  are  shown  in  table  14A.  An  alphabetical  list  of  them, 
identifying  the  manufacturers  of  each,  appears  m  table  14B,  part  III. 

Few  of  the  products  in  this  group  reach  the  ultimate  consumer  in 
the  form  of  the  pure  chemicals  listed  in  the  tables;  instead  they  are 
blended  with  essential  and  floral  oils,  fixatives,  and  solvents  according 
to  special  formulas.  These  blends  or  mixtm-es  are  then  used  to 
flavor  foods,  drinks,  and  medicines;  to  perfume  toiletries,  cosmetics, 
and  soaps;  and  to  conceal  objectionable  odors. 

The  individual  flavor  and  perfume  materials  are  arranged  in  groups 
according  to  chemical  classification  as  cyclic  (including  benzenoid,  as 
well  as  terpenoid  and  heterocyclic),  acyclic,  and  chemically  modified 
essential  oils.     In  1944,  refined  benzyl  benzoate  was  shifted  to  the 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


39 


Table  14 A. — Synthetic  organic  chemicals:   United  States  production  and  sales  of 
flavor  and  perfume  materials,  1944 

[Listed  below  are  all  synthetic  organic  flavor  and  perfume  materials  for  which  any  reported  data  on  pro- 
duction or  sales  may  be  published.  (Leaders  are  used  where  the  reported  data  are  confidential  and  may 
not  be  published,  or  where  no  data  were  reported.)  Table  14B  in  part  III  lists  alphabetically  all  those 
flavor  and  perfume  materials  for  which  data  on  production  or  sales  were  reported  and  identifies  the 
manufacturer  of  each] 


Production 

Sales 

Quantity 

Value 

Unit  value 

Grand  total 

1,000  pounds 
16,279.0 

1,000  pounds 
15,  564. 0 

1,000  dollars 
19,111.2 

Per  pound 
$1.23 

FLAVOR  AND  PERFUME  MATERIALS, 
CYCLIC 
Total     -..      

11, 726.  3 

11,049.8 

14,  564.  7 

1.32 

Materials  for  which  separate  statistics  may  not 
be  shown  ,                            _        _. 

3.066.3 
8, 660. 0 

7, 425.  2 

3,137.7 
7, 912. 1 

6, 879. 4 

4, 733. 8 
9, 830.  9 

7,161.3 

1.51 

Materials  for  which  separate  statistics  are  shown 
below 

1.37 

Benzenoid 
Total 

1.04 

a-Amylcinnamaldehyde ..-  -.- 

80.3 
221.9 
385.2 

62.6 

74.7 

198.6 

407.7 

54.5 

.3 

.4 

1.7 

328.7 

194.3 

1.1 

2.7 

.7 

2.9 

21.2 

121.6 

120.5 

408.2 

144.9 

1.1 

3.1 

8.8 

177.9 

131.6 

2.8 

15.2 

1.8 

5.4 

34.4 

1.61 

Amyl  salicylate -  -     

.61 

Anethole 

1.00 

Anisaldehyde  .         -._.-. .. 

2.  66 

Anisole  (Methyl  phenyl  ether) .- 

3.38 

Anisyl  acetate 

7.00 

Anisyl  alcohol                   .      -                  ^ 

2.5 

331.9 

204.3 

1.0 

2.8 

.5 

3.4 

23.7 

347.5 

7.7 

.7 

34.4 

5.20 

Benzyl  acetate.-  _  _-_ 

.54 

Benzyl  alcohol _  .  _            

.68 

Benzyl  butyrate                     .            _..___ 

2.57 

Benzyl  cinnamate-.    .-  --.     . 

5.55 

Benzyl  formate .-.          _  - 

2.49 

1.89 

Benzyl  salicylate      .-.  . -.  -  -. 

1.63 

Cinnamic  acid 

Cinnamvl  acetate 

.5 

34.5 

.1 

1.4 
.1 

1.7 
.7 

1.7 

.3 

,58.7 

2.9 

98.3 

1.0 

6.1 

.8 

1.4 

1.8 

12.2 

.2 

138.  7 

6.08 

Cinnamyl  alcohol- --  - 

2.85 

Cinnamyl  propionate     ..  

9.31 

p-Cresyl  o-toluate  (p-Cresyl  phenylacejate)     .  . . 

4.46 

Ethyl  anthranilate - 

5.74 

Ethyl  benzoate .- 

.83 

Ethyl  cinnamate                                    .  .  - 

.4 

2.78 

Ethyl  methylphenylglycidate 

7.19 

Ethyl  salicylate  - 

.93 

Eugenol ..     ._                            __  -.. 

55.0 
.2 

2.37 

Isoeusenol- _ 

29.0 

97.4 

3.36 

Methyl  benzoate 

53.0 

.7 
1.1  , 

a-Methylbenzyl  alcohol  (Methylphenyl  carbinol) 
(Styralyl  alcohol) 

Methyl  cinnamate  .  _             - 

.7 
2.8 
1.9 

2.8 
5.3 
8.2 

4.01 
1.91 

Methvl  eugenyl  ether  (Methyl  eugenol)      .    -. 

4.28 

Methyl  isoeugenyl  ether 

4.1 

3.412.0 

•      139. 0 

284.5 

Methyl  salicylate  (Artificial  wintergreen  oil) 

Musk  xylene _      ..        --  „ 

3, 127. 1 
128.1 

268.4 
.4 

.2 

681.2 

1,  250. 4 

4, 170.  4 

964.3 

173.2 

509.5 

1.7 

1.4 

1,  528. 1 

2,  428.  7 

7,  403. 4 

.31 
1.35 

Phenethyl  alcohol  (Phenylethyl  alcohol) 

Phenethyl  propionate    -         

1.90 
4.56 

3-Phenyl-l-propyl  acetate  (Hydrocinnamyl  ace- 
tate)-.. 

.2 

653. 0 
1,111.7 

4,301.1 

6.12 

Vanillin  -  .         . 

2.24 

All  other  1 _-    ---- 

2.11 

Terpenoid  and  Heterocyclic 
Total -.     

1.78 

Cedryl  acetate     .    ..           ..        ..  ■ 

11.9 

48.1 

3.3,1 

.4 

259.8 

11.5 

42.0 

36.5 

.7 

244.0 

33.3 

160. 1 

198.9 

5.1 

601.4 

2.90 

Citral 

Citronellol     . ._        .                ...        - 

3.81 
5.44 

Citronellyl  acetate      .           

7.31 

Coumarin,  synthetic 

2.47 

1  Includes  data  of  production  and  sales  for  naphthalenoid  compounds,  which  amounted  to  less  than  1 
percent  of  the  total.  The  data  have  been  included  with  "All  other"  benzenoid  compounds  in  order  to 
prevent  the  disclosure  of  the  operations  of  individual  companies. 


40 


UNITED    STATES   TARIFF    COMMISSION 


Table  14A. — Synthetic  organic  chemicals:   United  States  production  and  sales  of 
flavor  and  perfume  materials,  1944 — Continued 


Material 


Production 


Sales 


Quantity 


Value 


Unit  value 


FLAVOR  AND  PERFUME  MATERIALS, 
CYCLIC— Continued 

Terpenoid  and  HeteTocydic — Continued 


Geraniol 

Geranyl  acetate.- 

Geranyl  butyrate 

Geranyl  formate 

Indole- -.- 

a-Ionone..- - 

^-lonone 

lonone,  mixed 

Linalool,  natural 

Linalyl  acetate 

Linalyl  butyrate , 

Linalyl  formate 

Linalyl  isobutyrate 

Linalyl  propionate 

Menthol,  synthetic,  tech.  and  U.  S.  P- 

Methylionone 

Nerol 

Piperonal  (Heliotropin) 

Rhodinol  (2,6-Dimethylocten(2)ol) 

Rhodinyl  acetate 

Santalol 

Terpineol  (a  and  /3) 

Terpinyl  acetate 

Vetivenyl  acetate 

All  other 


1,000  pounds 

62.0 

20.0 

.1 

.6 


FLAVOR  AND  PERFUME  MATERIALS, 
ACYCLIC 
Total 


Materials  for  which  separate  statistics  may  not 
be  shown 

Materials  for  which  separate  statistics  are  shown 
below 


Allyl  caproate. 

Decyl  aldehyde  (Cio) 

Ethyl  butyrate 

Ethyl  caproate 

Ethyl  enanthate 

Ethyl  pelargonate 

Ethyl  sebacate. 

Isoamyl  butyrate. 

Isoamyl  formate 

Methylnonylacetaldehyde. 
Undecalactone 


CHEMICALLY  MODIFIED  ESSENTIAL 
OILS 
Total- 


25.1 


18.2 

38.3 

101.2 

.4 

.4 


.2 

217.1 

123.7 

1.8 

47.8 

21.6 

.2 

1.1 

1, 140.  3 

171.7 

1.4 

1, 954. 6 


4, 040.  2 


1 ,000  pounds 

59.2 

15.3 

.2 

.2 

3.7 

29.8 

.9 

28.4 

34.1 

89.9 

.2 

.4 

.4 

.1 

201.7 

125.3 

1.8 

44.4 

21.9 

.2 

.8 

1, 124.  0 

164.2 

1.3 

1,887.3 


4, 003. 6 


3, 992.  3 
47.9 

2.5 
2.9 


1.3 

9.5 

.3 

.8 

25.2 

1.3 

1.1 

3.0 


512.5 


1,000  dollars 

257.  4 

75.0 

LI 

1.5 

68.4 

121.4 

8.2 

100.4 

255.6 

441.0 

2.1 

3.2 

4.3 

1.3 

1, 400.  3 

519.4 

15.8 

141.8 

183.4 

3.0 

11.8 

299.7 

106.2 

77.2 

2,  305. 1 


4, 431. 9 


3, 890.  5 
113.1 

2.2 

2.5 

7L4 


10.4 
.1 


21.4 
LO 
LI 
3.0 


510.6 


Per  pound 

$4. 35 

4.90 

6.45 

8.59 

18.  67 

4.08 

9.32 

3.53 

7.48 

4.90 

8.49 

7.84 

9.75 

10.64 

6.94 

4.14 

8.89 

3.19 

8.36 

18.35 

14.90 

.27 

.65 

59.01 

L22 


1.11 


4,  244. 8 
187.1 

10.1 
44.8 
53.1 


1L6 
.4 


17.7 

1.0 

26.0 

22.4 


L09 


4.51 

17.57 

.74 


1.  U 
7.51 


.83 

.97 

24.05 

7.42 


medicinal  group  because  of  its  increased  use  in  the  treatment  of 
scabies;  another  use  of  this  product  is  in  insect  repellents. 

Production  of  all  flavor  and  perfume  materials  in  1944  totaled  16.3 
million  pounds,  an  mcrease  of  23  percent  over  1943  and  almost  6 
percent  over  1942,  the  highest  previous  year.  This  increase,  made 
possible  by  larger  supplies  of  some  raw  materials,  was  partly  in  re- 
sponse to  a  greater  demand  resulting  from  a  higher  national  income. 
It  also  reflected  a  greater  substitution  of  synthetic  flavor  and  perfume 
materials  for  natural  products,  imports  of  which  were  limited  by  war 
conditions.  Certain  flavoring  materials  were  requhed  in  greater 
quantity  for  use  in  military  rations.  Sales  in  1944,  totaling  15.6 
million  pounds,  were  valued  at  19.1  million  dollars. 


SYNTHETIC   ORGANIC    CHEMICALS,    1944  41 

Production  of  benzenoid  flavor  and  perfume  materials  in  1944 
amounted  to  7.4  million  pounds,  18  percent  greater  than  in  1943. 
This  mcrease  was  due  in  part  to  larger  supplies  of  coal-tar  intermedi- 
ates. Production  of  methyl  salicylate  (artificial  wintergreen  oil)  in 
1944  totaled  3.4  million  poimds;  sales  were  3.1  million  pounds,  valued 
at  $964,000.  Production  of  vanillin  totaled  653,000  pounds;  sales 
were  681,000  pounds,  valued  at  1.5  million  dollars. 

The  output  of  terpenoid  and  heterocyclic  chemicals  combined  was 
4.3  million  pounds;  sales  were  4.2  million  pounds,  valued  at  7.4  million 
dollars.  Shortages  of  natural  menthol  stimulated  the  production  of 
synthetic  menthol,  which  reached  217,000  pounds;  production  would 
probably  have  been  much  higher  if  raw  materials  for  the  synthetic 
product  had  been  more  abundant.  Another  important  item  in  this 
group  was  coumarin;  260,000  pounds  was  produced  and  244,000 
pounds,  valued  at  $601,000,  was  sold.  Production  of  citronellol, 
geraniol,  and  their  derivatives  was  low  because  of  the  shortage  of 
imported  raw  materials.  Among  the  items  for  which  the  statistics 
are  not  publishable,  saccharin,  a  substitute  sweetening  agent,  was 
produced  in  large  quantities  owing  to  the  shortage  of  sugar. 

The  acyclic  flavor  and  perfume  materials  consist  chiefly  of  sjni- 
thetic  alcohols,  aldehydes,  ketones,  and  .esters.  Statistics  reported 
to  the  Commission  on  the  principal  item  in  this  group,  monosodium 
glutamate,  cannot  be  shown  as  they  are  confidential;  but  production 
in  1944  is  estimated  in  trade  publications  at  about  3.5  million  pounds. 
This  material  enriches  the  flavors  of  other  foods  and  is  used  in  dehy- 
drated soups.  Army  rations,  and  other  products. 

PLASTICS  MATERIALS 

Plastics  materials  are  produced  in  semimanufactured  forms  such  as 
granular  molding  compounds,  solutions,  and  sheets.  They  may  be 
further  processed  by  the  manufactiuers,  or  sold  to  fabricators.  In 
either  case,  the  plastics  materials  go  into  molded  objects  such  as 
radio  cabinets;  laminated  products  such  as  table  tops;  preparations 
for  treatment  of  paper,  textiles,  and  leather;  protective  coatings  for 
wood  and  metal;  adhesives;  safety  glass;  and  a  multitude  of  other 
finished  products  for  civilian  or  military  uses. 

Plastics  materials  may  be  made  from  a  wide  variety  of  raw  materials 
and  each  has  its  special  properties  which  make  it  preferable  in  certain 
uses.  Phenolic  condensation  resins,  for  example,  have  a  high  tensile 
strength  and  are  thermo-setting;  that  is,  they  are  not  changed  greatly 
in  form  by  heat.  Polystyrene  polymerization  resins  have  excellent 
electrical  properties.  Organic  nitrogen  resins  may  be  easily  molded 
or  cast  into  clear  or  slightly  colored  products;  vinyl  polymers  make 
flexible  special-purpose  resins;  and  acrylate  resins  are  transparent 
and  especially  useful  where  special  optical  properties  are  desired. 
Alkyd  resins  of  the  phthalic  anhydride,  abietic  acid,  and  maleic  acid  or 
anhydride  types  are  used  widely  in  protective  coatings,  which  consti- 
tute one  of  the  major  uses  of  all  plastics  materials  as  a  group. 

Plastics  materials  made  from  cellulose  esters  are  not  considered 
within  the  scope  of  this  report.  Data  on  cellulose  plastics  are  pub- 
lished by  the  United  States  Bm^eau  of  the  Census.  Statistics  on 
production  and  sales  of  cellulose  esters  as  a  chemical  raw  material  for 


42 


UNITED    STATES   TARIFF    COMMISSION 


all  purposes  are  included  with  the  group  of  miscellaneous  chemicals. 
United  States  production  and  sales  of  plastics  materials  are  shown 
in  table  ISA  (see  also  table  15B,  part  III,  for  an  alphabetical  list  of 
these  products  in  which  the  manufacturers  are  identified). 

Table  15A. — Synthetic  organic  chemicals:   United  States  production  and  sales  of 
plastics  materials,  grouped  according  to  chemical  composition,  1944 

[Quantities  and  values  are  based  on  net  resin  content'only.i  Listed  below  are  all  synthetic  plastics  materials 
for  which  any  reported  data  on  production  or  sales  may  be  published.  (Leaders  are  used  where  the  re- 
ported data  are  confidential  and  may  not  be  published  or  where  no  data  were  reported.)  Table  15B  in 
part  III  lists  alphabetically  all  those  products  for  which  data  on  production  or  sales  were  reported  and 
identifies  the  manufacturer  of  each] 


Material 


Grand  total 

PLASTICS  MATERIALS,  CYCLIC 
Total ."- 

Materials  for  which  separate  statistics  may  not  be 
shown - 

Materials  for  which  separate  statistics  are  shown 
below - 

Condensation  Resins,  Benzenoid 

Total- -- 

Alkyd  resins,  total ' ..- 

Saturated  polyesters  type,  total 

Phthalic  anhydride-glycerol,  total 

For  molding  and  casting 

For  protective  coatings..- 

For  other  uses 

All  other 

Unsaturated  polyesters  type 

Coal-tar  acid  resins,  total.— 

Phenolic  resins,  total.. 

p-tert-Allcylphenol-aldehyde  (p-tert-Amyl- 
phenol  and  p-tert-Butylphenol) 

Cresols-formaldehyde,  total 

For  laminating 

For  other  uses 

Phenol-formaldehyde,  total. 

For  molding 

For  laminating 

For  protective  coatings 

For  adhesives 

For  textile,  paper,  and  leather  treatment... 
For  other  uses 

Phenol-formaldehyde,  modified  by  abietic 
acid 

Phenol-formaldehyde,  modified  by  abietic 
acid  ester. 

All  other  phenolic  resins 

Mi.xed  phenolic  (tar  acid)  resins,  total. 

Cresylic  acid-formaldehyde 

Cresols-  and  xylenols-aldehyde 

All  other  mixed  phenolic  resins 

All  other  cyclic  condensation  resins 

Polymerization  Resins,  Benzenoid 

Total 

Polyaromatic  resins,  total 

Polystyrene  resins 

All  other  polyaromatic  resins 

All  other  cyclic  polymerization  resins 

See  footnotes  at  end  of  table. 


Production 


1,000 
pounds 
782, 352 


16,535 
387,  578 


334,  396 


132,  402 


130, 123 

127,  854 

162 

127,083 

609 

2,269 

2,279 

197,  315 


158,  946 

2,575 
14, 825 
12,  481 

2,344 
116,204 
42, 094 
27, 173 
10,  296 
21, 080 
318 
15,  243 

2, 020. 

20, 889 
2,433 

38, 369 
6,720 
1,740 

29,  909 
4,679 


,717 


57,  861 


10,  571 
47,  290 
11, 856 


Sales  2 


Quantity 


1,000 
pounds 
697, 328 


380,  822 


16,  356 
364,  466 


311,  345 


118,348 


116,079 

114,  205 

118 

113,534 

553 

1,874 

2,269 

188, 366 


153, 370 

2,513 
15, 134 
12,  795 

2,339 
111,340 
41,  868 
23,169 
10, 115 
20,  787 

15, 401 

1,625 

20,  627 
2,131 

34, 996 
4,148 
1,340 

29,  508 
4,631 


69,  477 


57,  752 


10,  702 
47,  050 

11,  725 


Value 


1,000 
dollars 
211,342 


1,397 
81,867 


76, 081 


22,278 


21,  813 

21,  392 
35 

21,  244 
113 
421 
465 

52, 662 


42, 461 

807 

3,546 

2,889 

657 

33,  576 

15, 726 

5,527 

3,793 

3,841 

(*) 

4,689 

237 

.3, 492 

803 

10,  201 

1,089 
385 

8,727 

1,141 


7,183 


6,927 


3,001 

3,926 

256 


Unit  value 


Per 
pound 
$0.30 


.19 
.19 
.30 
.19 
.20 
.22 
.20 
.28 


(*) 


.32 
.23 
.23 
.28 
.30 
.38 
.24 
.37 
.18 


.17 
.38 
.29 
.26 
.29 
.30 
.25 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


43 


Table  15A.' — Synthetic  organic  chemicals:   United  States  production  and  sales  of 
plastics  materials,  grouped  according  to  chemical  composition,  jfS^^^Continued 


Material 

Production 

Sales  2 

Quantity 

Value 

Unit  value 

PLASTICS  MATERIALS,  ACYCLIC  « 
Total  .                                 .    .                 .- 

1,000 
pounds 
378,  239 

1,000 
pounds 
316,  506 

1,000 
dollars 
128,  078 

Per 
pound 
$0.40 

Materials  for  which  separate  statistics  may  not 
be  shown. _                        

79,  429 
298,  810 

171,  545 

50,  770 
265,  736 

162, 312 

39,  567 
88,511 

37,  885 

.78 

Materials  for  which  separate  statistics  are  shown 
below -. 

.33 

Condensation  Resins 
Total 

.23 

Alkyd  resins,  total 

105,  481 

101, 337 

17, 484 

.17 

Abietic  acid,  and  abietic  acid  and  maleic  acid._ 
Kiimarin  acid 

70,  686 
.3,  411 

13,  572 
17, 812 
66, 064 

68, 126 
3,306 

12, 955 
16,  950 
60, 975 

8,088 
665 

3,164 

5,567 
20,  401 

.12 

.20 

Maleic  acid  or  anhydride  and  maleic  anhydride- 
terpene ...    

.24 

All  other __ 

.33 

Organic  nitrogen  resins,  total 

.33 

Urea-formaldehyde,  total 

48,  066 
18,  647 
22,411 
3,  580 
3,  428 
17, 998 

206,  694 

43, 110 
13,  958 
20, 876 
5,359 
2,  917 
17, 865 

154, 194 

13,  218 

7,108 

4,  575 

916 

619 

7,183 

90, 193 

.31 

.51 

For  adhesives-      

.22 

For  textile,  paper,  and  leather  treatment 

.17 
.21 

All  other  organic  nitrogen  resins  ' 

.40 

Polymerization  Resins 
Total..... 

.59 

Alcohol  polymerization  resins  (allyl  and  furfuryl 
alcohols) 

Polyvinyl  alcohol,  ester,  ether,  and  halide  resins.. 
Polyvinyl  alcohol-aldehyde  resins 

373 

111,900 

14, 992 

79,  429 

444 
91, 369 
11,611 
50,  770 

394 
39,  743 
10,  489 
39,  567 

.89 
.43 
.90 

.78 

1  Net  resin  content  excludes  all  fillers,  drying  agents,  dyes,  and  plasticizers.  Chemical  modifiers  such  as 
abietic  acid  and  special  oils  are  considered  part  of  the  net  resin  content  when  they  are  chemically  combined 
with  the  principal  resin. 

2  Sales  of  protective  coatings  materials  include  certain  intraplant  transfers  as  well  as  the  usual  interplant 
transfers,  i.  e.,  transfers  from  the  producing  department  of  a  plant  to  the  department  of  the  same  plant 
which  mixes  or  compounds  these  materials  for  sale. 

3  Data  for  alkyd  resins  include  anhydride-alcohol-oil  chemically  combined. 
<  Included  in  statistics  of  phenol-forrnaldehyde  resins  for  other  uses. 

'  Includes  small  amounts  of  alicychc'and  heterocyclic  resins. 

6  Includes  statistics  for  polymethacrylic  acid  ester  resins,  polyamide  resins,  and  several  other  miscella- 
Qeous  resias. 

The  data  in  table  15A  are  given  in  terms  of  the  net-resin  content  of 
the  type  of  resin  reported,  that  is,  solvents,  dyes,  fillers  (such  as  saw- 
dust), and  other  unreacted  chemicals  are  not  included  in  the  weight 
reported.  Oil  and  abietic  acid  when  chemically  combined,  however, 
are  included.  Statistics  of  plastics  materials  on  this  basis  are  less 
influenced  by  various  methods  of  formulation,  which  may  change 
from  year  to  year,  than  statistics  on  the  basis  of  gross  weight.  They 
are  also  more  suitable  for  combination  with  the  statistics  of  the 
other  synthetic  organic  chemicals  included  in  this  report.  In  order 
to  obtain  over-all  totals  for  the  entire  synthetic  organic  chemical 
industry,  statistics  for  all  synthetic  organic  chemicals,  except  dyes, 
are  given  in  terms  of  undiluted  materials. 

According  to  value  of  sales,  plastics  materials  was  the  third  largest 
group  in  the  synthetic  organic  chemical  industry  in  1944,  being 
exceeded  only  by  miscellaneous  chemicals  and  synthetic  elastomers 

697646—46 4 


44 


UNITED   STATES   TARIFF    COMMISSION 


(synthetic  rubbers).  Sales  amounted  to  211  million  dollars.  The 
quantity  produced  was  782  million  pounds,  and  the  quantity  sold, 
697  million  pounds.  In  1943,  about  654  million  pounds  was  produced 
and  568  million  pounds,  valued  at  178  million  dollars,  was  sold. 

Most  of  the  increase  in  the  output  of  plastics  materials  in  1944  over 
previous  years  was  in  the  acyclic  subgroup.  Included  in  this  subgroup 
in  1944  are  small  amounts  of  nonbenzenoid  resins,  that  is,  non-coal-tar 
resins,  which  are  nevertheless  cyclic  compounds.  Production  of 
materials  in  this  subgroup  totaled  378  million  pounds  compared  with 
273  million  in  1943,  the  previous  high.  Alkyd  resins  (chiefly  types  such 
as  abietic  acid,  maleic  acid  and  anhydride,  and  fumaric  acid),  poly- 
vinyl resins,  acrylate  resins,  and  polyamide  condensation  resins 
accounted  for  most  of  the  increase.  Production  of  urea-formaldehyde 
resins  decreased. 

The  output  of  cyclic  plastics  materials,  chiefly  benzenoid  con- 
densation products  such  as  alkyd  resins  derived  from  phthalic  anhy- 
dride and  coal-tar  acid  resins,  amounted  to  404  million  pounds  in  1944. 
This  represents  an  increase  of  24  million  pounds  over  the  output  in 
1943.  Production  of  resins  derived  from  phenols,  cresols,  xylenols, 
or  mixtures  of  these  materials  (tar-acid  resins)  totaled  197  million 
pounds,  an  increase  of  49  million  over  the  output  in  1943.  Production 
of  alkyd  resins  in  this  subgroup  amounted  to  132  million  pounds  in 
1944  compared  with  155  million  in  1943.    Tliis  decline  in  output  oc- 

Table   16. — Synthetic  organic  chemicals:    United  States  production  and  sales  of 
plastics  materials,  grouped  according  to  use,  1944 

[Quantities  and  values  are  based  on  net  resin  content  only] 


Production 

Sales 

Use 

Quantity 

Percent 
of  total 

Quantity 

Value 

Percent 
of  total 

Unit  value 

Grand  total 

1,000 
pounds 
782.  352 

t 

1,000 
pounds 
697,  328 

1,000 
dollars 
211,342 

Per  pound 
$0.30 

PLASTICS  MATERIALS, 
CYCLIC 
Total _., 

404, 113 

100.0 

380, 822 

83,  264 

100.0 

.22 

For  molding  and  casting 

72,270 
50,  883 
188,  685 
26,  241 

793 
65,  241 

378,  239 

17.9 
12.6 

46.7 
6.5 

.2 
16.1 

100.0 

72, 124 

44,  531 

173,434 

2.5,  843 

720 
64. 170 

316,  506 

26,  293 
9,963 

33,  276 
5,365 

203 
8,164 

128, 078 

31.6 
12.0 
40.0 
6.4 

.2 
9.8 

100.0 

.36 

For  laminating 

.22 

For  protective  coatings          

.19 

For  adhesives _      _  .. 

.21 

For    textile,  paper,  and  leather 
treatment- .. 

.28 

For  miscellaneous  uses  i 

.13 

PLASTICS  MATERIALS, 
ACYCLIC  2 

Total 

.40 

For  moldin?  and  casting 

For  laminating. "  ._    . 

47,  645 

6,059 

102, 138 

55,  544 

25, 628 
141,  225 

12.6 

1.6 

27.0 

14.7 

6.8 
37.3 

38,  586 

5,908 

97,  461 

46,  982 

26.  303 
101, 266 

29,  279 
3,490 
18,912 
14,  508 

10,753 
51,  136 

22.9 

2.7 

14.8 

11.3 

S.4 
39.9 

.76 
.59 

For  protective  coatings 

For  adhesives  .   ..    

.19 
.31 

For  textile,   paper,   and  leather 
treatment.. 

.41 

For  miscellaneous  uses  "  . 

.50 

•  Includes  small  amount  of  resin  reported  for  ion  exchange. 
'  Includes  small  amounts  of  alicyclic  and  heterocyclic  resins. 
'  Includes  resins  reported  for  glazing,  sheeting,  and  films, 


SYNTHETIC   ORGANIC   CHEMICALS,    1944  45 

curred  partly  because  of  a  shortage  in  supplies  of  phthalic  anhydride 
owing  to  an  increase  in  the  demand  for  this  material  for  plasticizers 
and  insect  repellents. 

Production  and  sales  of  plastics  materials  classified  by  use  are  shown 
in  table  16. 

Materials  for  protective  coatings  were  the  largest  item  in  the  total 
quantity  produced,  followed,  in  the  order  named,  by  materials  for 
molding  and  casting;  for  adhesives;  for  laminating;  and  for  treatment 
of  textiles,  paper,  and  leather.  About  200  million  pounds  was  pro- 
duced for  unspecified  uses. 

RUBBER-PROCESSING  CHEMICALS 

Rubber-processing  chemicals  (formerly  reported  under  the  name  of 
rubber  chemicals)  include  those  organic  compounds  which  are  added 
to  rubber  in  order  to  control  its  vulcanization  and  aging  properties. 
This  classification  does  not  include  chemicals  (such  as  styrene  and 
butadiene)  used  as  raw  materials  for  the  manufacture  of  synthetic 
elastomers  (synthetic  rubbers). 

The  three  principal  groups  of  rubber-processing  chemicals  are  the 
accelerators,  the  antioxidants,  and  the  peptizers.  The  addition  of  an 
accelerator  to  an  unprocessed  rubber  mixture  materially  shortens  the 
time  required  for  vulcanization  and  yields  a  finished  product  with 
higher  tensile  strength  and  better  resistance  to  aging.  The  use  of 
antioxidants  lengthens  the  hfe  of  the  rubber.  Peptizers  are  used  by 
the  rubber-goods  manufacturing  industry  to  soften  rubber  more 
quickly  during  its  processing. 

Statistics  on  production  and  sales  of  these  rubber-processing  chemi- 
cals for  1944  are  shown  in  table  17A  (see  also  table  17B,  part  III,  for 
an  alphabetical  list  of  these  products  in  which  the  manufacturers  are 
identified.) 

Production  of  rubber-processing  chemicals  continued  to  increase  in 
1944,  reaching  a  new  high  of  93  million  pounds,  an  increase  of  12 
million  pomids  over  the  previous  peak  production  of  1943.  Sales  in 
1944  also  reached  a  record  high  of  85  million  pounds,  valued  at  42 
million  dollars,  compared  with  77  million  pounds,  valued  at  31  mil- 
lion dollars,  in  1943.  The  increase  was  due  to  a  greater  production 
of  both  synthetic  rubber  and  rubber  manufactures  and  to  the  larger 
amount  of  rubber-processing  chemicals  required  to  process  synthetic 
rubber  compared  with  natural  rubber. 

The  output  of  cyclic  rubber-processing  chemicals,  chiefly  acceler- 
ators and  antioxidants,  rose  from  62  million  pounds  in  1943  to  74 
million  in  1944,  an  increase  of  almost  20  percent.  Sales  of  these 
cyclic  compounds  totaled  66  million  pounds,  valued  at  27  million 
dollars,  representing  an  increase  over  1943  of  14  percent  in  the  quan- 
tity sold. 

Statistics  for  cyclic  accelerators  are  shown  in  four  chemical  sub- 
groups, of  which  the  most  important  was  the  thiazole  derivatives. 
In  1944,  production  of  this  group  amounted  to  29  million  pounds; 
production  of  2-mercaptobenzothiazole  accounted  for  11  million 
pounds  of  this  amount.  The  output  of  guanidine  accelerators  was 
about  3  million  pounds,  which  was  above  the  level  of  the  last  2  years, 
but  less  than  the  high  of  4  million  pounds  reached  in  1941.     Di- 


46 


UNITED   STATES   TARIFF    COMMISSION 


Table  17A.^ — Synthetic  organic  chemicals:    United  States  production  and  sales  of 
rubber-processing  chemicals,  1944 

[Listed  below  are  all  rubber-processing  chemicals  for  which  any  reported  data  on  production  or  sales  may 
be  published.    (Leaders  are  used  where  the  reported  data  are  confidential  and  may  not  be  published  or 

•  where  no  data  were  reported.)  Table  17B  in  part  III  lists  alphabetically  all  those  for  which  data  on  pro- 
duction or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Product 

Production 

Sales 

Quantity 

Value 

Unit  value 

Grand  total            -                 .    

1,000 
pounds 
92,  639 

1,000 
pounds 
84,  725 

1,000 
dollars 
42, 075 

Per 
pound 
$0.50 

RUBBER-PROCESSING  CHEMICALS, 
CYCLIC 
Total  -              

73, 774 

66,  260 

27,446 

.41 

Products  for  which  separate  statistics  may  not 

38,222 
35,  552 
33,  528 

37, 058 
29,202 
27,  769 

14, 464 
12,982 
11,944 

.39 

Products  for  which  separate  statistics  are  shown 
below                      . .  -    - 

.44 

Accelerators,  total                                           -- 

.43 

Aldehyde-amines,  total       .                       _  -. 

833 

510 

323 

538 

2, 967 

2,459 

508 

28,  782 

11,207 

17,  575 

408 

40,  246 

792 

476 

316 

522 

2,942 

2,331 

611 

23, 134 

461 

287 
174 
487 

1,067 
809 
258 

9,675 

.58 

n-Butyraldehyde-aniline 

.60 

All  other             

.55 

Dithiocarbamates 

.93 

Guanidines  and  guanidine  mixtures,  total 

.36 
.35 

All  other 

.42 

Thiazole  derivatives,  total 

.42 

All  other 

All  other  I                                           -     

379 
38, 491 

254 

15,  502 

.67 

Antioxidants,  total              - 

.40 

315 

2,117 
37, 814 

18,  805 

Secondary  amines:  N,N'-Diphenyl-p-phenyl- 
enediamine. ._    -    .. -    

1,812 
36, 679 

18, 465 

1,292 
14,  210 

14, 629 

.71 

All  other                                                  

.39 

RUBBER-PROCESSING    CHEMICALS 
ACYCLIC 
Total-   

.79 

Products  for  which  separate  statistics  may  not 
be  shown 

204 
18,  661 
6,536 

188 
18,  277 
6,178 

160 
14, 469 
5,623 

.85 

Products  for  which  separate  statistics  are  shown 
below 

.79 

Accelerators,  total 

.91 

Dithiocarbamates^  _  . 

612 

5,720 

773 

4,947 

204 

12,  329 

511 
5,479 

664 
4,  815 

188 
12,  287 

709 
4,754 

786 
3,968 

160 
9,006 

1.39 

Thiuram  derivatives,  total        .  .           _.  .     _ 

.87 

Tetramethylthiuram  disulfide 

1.18 

Another 

.82 

Another _. .  .      

.85 

Peptizers:  Dodecyl  mercaptan  ...  . 

.73 

'  Includes  statistics  of  production  and  sales  of  rubber  tackifiers. 

phenylguanidine  continued  to  be  the  leading  individual  guanidine 
compound. 

The  output  of  cyclic  antioxidants  continued  its  slow  rise.  In  1944, 
production  totaled  40  million  pomids,  or  2  million  pounds  more  than 
in  1943. 

Acyclic  rubber-processing  chemicals  include  both  accelerators  and 
peptizers.  No  data  have  been  reported  for  acyclic  antioxidants.  An 
apparent  slight  decrease  in  the  output  of  acyclic  compounds  is  due 
to  the  reclassification  of  several  of  them,  particularly  xanthates; 
these  compounds  are  now  included  with  miscellaneous  chemicals  (see 
table  2lA)  as  flotation  reagents,  which  is  now  their  major  use. 


SYNTHETIC   ORGANIC    CHEMICALS,    1944  47 

The  production  of  dithiocarbamates  has  been  irregular  in  recent 
years.  It  was  470,000  pounds  in  1941,  150,000  pounds  in  1942,  and 
612,000  pounds  in  1944. 

Dodecyl  mercaptan  was  the  rubber-processing  chemical  produced 
in  the  largest  quantity  in  1944.  It  is  used  both  as  a  peptizer  and  as 
an  agent  to  control  the  polymerization  processes  in  manufacturing 
synthetic  rubber.  Production  of  dodecyl  mercaptan,  which  was  12 
million  pounds  in  1944,  was  very  much  larger  than  in  1943.  The 
large  output  of  this  material  (with  an  average  sales  value  of  73  cents 
per  pound)  raised  the  average  sales  value  for  all  acyclic  rubber- 
processing  chemicals  from  40  cents  per  pound  in  1943  to  79  cents  in 
1944.  Sales  of  dodecyl  mercaptan  accounted  for  67  percent  of  the 
total  sales  of  acyclic  rubber-processing  chemicals  in  1944. 

ELASTOMERS  (SYNTHETIC  RUBBERS) 

Synthetic  elastomers  ^  made  the  greatest  gain  in  production  of  any 
group  of  synthetic  organic  chemicals  in  1944.  The  relative  impor- 
tance of  this  group  has  increased  with  the  mounting  production  of 
synthetic  rubber.  This  group  includes  synthetic  rubber  of  the  poly- 
butadiene-styrene  (GR-S),  polybutadiene-acrylonitrile  (GR-A),  and 
polycliloroprene  (GR-M)  types  for  special  purposes  and  for  tire 
manufacture,  and  also  products  such  as  polyvinyl  alcohol  and  poly- 
vinyl alcohol-aldehyde  copolymers  which  have  been  converted  into 
elastomers  by  the  addition  of  a  plasticizer.  Statistics  on  production 
and  sales  of  synthetic  elastomers  are  shown  in  table  18A  (see  also 
table  18B,  part  III,  for  an  alphabetical  list  of  these  products  in  which 
the  manufacturers  are  identified). 

In  1944,  the  production  of  synthetic  elastomers  was  three  times  that 
of  1943  (1.8  billion  pounds  compared  with  573  million).  Sales  totaled 
1.6  billion  pounds,  valued  at  354  million  dollars,  in  1944,  compared 
with  553  million  pounds,  valued  at  156  million  dollars,  in  the  previous 
year. 

Production  of  the  cychc  elastomers,  chiefly  the  polybutadiene- 
styrene  (GR-S)  type  of  synthetic  rubber,  reached  a  total  of  1.5  billion 
pounds,  or  more  than  three  and  one-half  times  the  output  in  1943, 
which  was  414  million  pounds.  This  elastomer  accoimted  for  the 
greater  part  of  the  production  of  all  synthetic  rubbers  in  1944.  It  is 
preferred  because  of  its  comparatively  low  cost  and  general  suitability 
for  use  in  tires.  Raw  materials  for  the  polybutadiene-styrene  elas- 
tomers may  be  obtained  from  either  petroleum  or  grain  and  from  either 
coke-oven  gas  or  tar.  This  type  of  synthetic  rubber  is  produced  by 
emulsifying  high-purity  butadiene  and  styrene,  adding  a  catalyst 
to  promote  polymerization,  and  coagulating  to  recover  the  final  prod- 
uct, which  is  dried  and  pressed  into  blocks. 

Production  of  acyclic  elastomers,  principally  polychloroprene 
(GR-M  or  Neoprene),  polyisobutylene-diolefin  (GR-I),  and  poly- 
butadiene-acrylonitrile (GR-A)  types,  increased  from  159  million 
pounds  in  1943  to  257  million  in  1944.  The  average  unit  value  of  37 
cents  per  pound  in  1944  represented  a  considerable  decrease  from 
that  of  54  cents  in  1943.  The  unit  value  of  nearly  all  of  the  elastomers 
decreased  in  1944. 

1  An  elastomer  is  defined  as  a  material  that  will  stretch  repeatedly  to  at  least  150  percent  of  its  original 
dimension  and  will  return  rapidly  and  with  force  to  its  approximate  original  shape. 


48 


UNITED    STATES   TARIFF    COMMISSION 


Table  18A. — Synthetic  organic  chemicals:  United  States  production  and  sales  of 
elastomers  {synthetic  rubbers),^  1944 

[Listed  below  are  all  synthetic  elastomers  for  which  any  reported  data  on  production  or  sales  may  be  pub- 
lished. Table  18B  in  part  III  lists  alphabetically  all  those  elastomers  for  which  data  on  production  or 
sales  were  reported  and  identifies  the  manufacturer  of  each] 


Chemical 


Production 


Sales  » 


Quantity 


Value         Unit  value 


Grand  total 

ELASTOMERS,  CYCLIC 

Total - --.. 

Polybutadiene-styrene  (GR-S  type): 

Produced  at  Government  plants  ^. , 

Produced  at  private  plants  *. 

ELASTOMERS,  ACYCLIC 

Total 

Elastomers  for  which  separate  statistics  may  not 
be  shown 

Elastomers  for  which  separate  statistics  are 
shown  below -.- 

Polybutadiene-acrylonitrile  (GR-A  type)  (Bima 
N),  total 

Produced  at  Government  plant 

Produced  at  private  plants. 

Polychloroprene  (GR-M  type)  (Neoprene) ' 

Polyisobutylene-diolefin  (QR-I  type)  ' 

Polyisoprene  » 


1 ,000  pounds 
1,757,910 


1 ,000  pounds 
1,  628,  437 


1,000  dollars 
3.^3,  750 


Per  pound 
$0.22 


1,  600, 993 


1, 395, 136 


268,  315 


1, 497,  758 
3,235 


256,  917 


1, 391,  697 
3,439 


233, 301 


266, 961 
1,354 


85, 435 


.37 


70,  544 
186,  373 

37,  731 


68,434 

164, 867 

31,  704 


34, 486 
60, 949 

14, 954 


4,617 
33, 114 

105, 957 

42, 315 

370 


46 
31, 658 

98,  435 

34, 362 

366 


23 
14, 931 

27, 070 

8,857 

68 


'  An  elastomer  is  defined  as  a  material  which  will  stretch  repeatedly  to  150  percent  or  more  and  will  return 
rapidly  and  with  force  to  its  approximate  original  shape.    Synthetic  elastomers  include  synthetic  rubbers. 

2  Value  of  sales  for  some  plants  operated  for  the  Rubber  Reserve  Company  represent  the  value  calculated 
from  the  quantity  of  sales  and  the  average  book  value  per  pound  for  1944  as  supplied  by  the  Rubber  Reserve 
Company. 

3  In  addition,  plants  operated  for  Polymer  Corporation,  a  Canadian  Government  corporation,  produced 
71,814,400  pounds  and  sold  71,814,400  pounds,  valued  at  $13,285,664. 

*  Includes  statistics  for  polystyrene  and  polyisoprene-styrene  elastomers. 

•  Data  for  Government  plant  only. 

'  In  addition,  plants  operated  for  Polymer  Corporation,  a  Canadian  Government  corporation,  produced 
6,198,080  pounds  and  sold  6,198,080  pounds,  valued  at  $960,702. 

Polychloroprene  elastomers,  which  have  been  manufactured  in  the 
United  States  since  1932,  have  increased  in  use  to  such  an  extent  that 
they  have  become  one  of  the  most  important  of  the  acyclic  subgroup. 
Production  in  1944  was  106  million  pounds,  or  31  million  greater 
than  in  1943.  The  stability  of  Neoprene  under  continued  exposure  to 
oils,  chemicals,  heat,  freezing,  and  sunlight  accounts  for  its  widespread 
use  even  though  it  is  higher  in  price  than  most  of  the  other  synthetic 
elastomers. 

Important  elastomers  for  which  statistics  are  not  separately  shown 
are  the  poljrvinyl  alcohol-aldehyde  copolymers  and  the  polyalkylene- 
sulfide  types.  Polyvinyl  polymers  have  proved  to  be  especially 
adapted  for  certain  uses.  Their  electrical  properties  and  chemical 
resistance  have  promoted  their  use  for  tubing,  wire,  and  cable  insula- 
tion. 

SURFACE-ACTIVE  AGENTS 

Table  19A  shows  production  and  sales  of  surface-active  agents  for 
1944  (see  also  table  19B,  part  III,  for  an  alphabetical  list  of  these 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


49 


Table  19 A. — Synthetic  organic  chemicals:  United  States  production  and  sales  of 
surface-active  agents,  1944 

[Listed  below  are  all  surface-active  agents  for  which  any  reported  data  on  production  or  sales  may  be  pub- 
lished. (Leaders  are  used  where  the  repoFted  data  are  confidential  and  may  not  be  published  or  where 
no  data  are  reported.)  Table  19B  in  part  III  lists  alphabetically  all  those  chemicals  for  which  data  on 
production  or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Chemical 

Production 

Sales 

Quantity 

Value 

Unit  value 

Grand  total  

1,000  pounds 
152,  636 

1,000  pounds 
134,  706 

1,000  dollars 
29, 938 

Per  pound 
$0.22 

SURFACE-ACTIVE  AGENTS,  CYCLIC 
Total        

74,  264 

70, 880 

11, 905 

.17 

Chemicals  for  which  separate  statistics  may  not 
be  shown               -         ..    .  ._ 

31, 454 
42, 810 

1,890 
11, 401 

31,  550 
39, 330 

1,828 
11, 143 

5,778 
6,127 

1,864 
1,978 

.18 
16 

Chemicals  for  which  separate  statistics  are  shown 

Nonsulfated  and  nonsulfonated:  Quaternary  am- 

L02 

.18 

Sulfated  and  sulfonated: 
Naphthalene  derivatives,  sulfonated,  total 

Isopropylnaphthalenesulfonic    acid    (mono) 
and  sodium  salt      

433 
10,  968 
29,  519 

78, 372 

412 
10,  731 
26, 359 

63, 826 

140 

1,838 
2,285 

18, 033 

34 

All  other 

17 

Petroleum  sulfonates . 

09 

SURFACE-ACTIVE  AGENTS,  ACYCLIC 
Total 

28 

Chemicals  for  which  separate  statistics  may  not 
be  shown _        -_.  _  -        _ 

27, 636 
50,  736 

1,133 
548 

2,727 

11,595 
52,  231 

519 
547 

2,998 
15,035 

267 
76 

,26 

Chemicals  for  which  separate  statistics  are  shown 
below                - -    -  - 

29 

Nonsulfated  and  nonsulfonated: 
Amides 

51 

Salts  of  fatty  acids          -  .    .      ..  .- 

14 

Sulfated  and  sulfonated: 
Acids,  sulfated  and  sulfonated,  total 

Oleic  acid,  sulfonated  

2,031 

696 

8,613 

1,963 

385 

20 

All  other 

Amides,  sulfated  and  sulfonated,  total-. 

8,717 

2,462 

28 

Lauroyltaurine  (Ethanol  lauramide  sulfonic 
acid)  salts 

315 
8,298 

333 

8,384 
14, 049 
7,536 

18,  900 

169 
2,293 
3,706 
5,553 

2,586 

.51 

Another--     _     

.27 

Alcohols,  sulfated  and  sulfonated.. 

.26 

Esters,  sulfated  and  sulfonated  

8,945 
28,  770 

.74 

Oils,  fats,  and  waxes,  sulfated  and  sulfonated, 
total 

14 

Castor  oil,  sulfonated 

Cod  oil,  sulfonated    -.                        .         . 

6,770 
1,639 

723 
2,616 
1,928 

661 
1,232 
3,769 
9,432 

4,568 

1,638 

270 

2,542 

571 

657 

575 

2,599 

5,480 

719 
215 

44 
340 

90 
102 

87 
248 
741 

.16 
13 

Corn  oil,  sulfonated 

Neat's-foot  oil,  sulfonated 

Peanut  oil,  sulfonated 

.16 
.13 
.16 

Soybean  oil,  sulfonated  . 

.16 

Sperm  oil,  sulfonated 

Tallow,  sulfonated 

.       .15 
.09 

Another 

.14 

products  in  which  the  manufacturers  are  identified).  In  previous 
years,  these  chemicals  have  been  included  with  miscellaneous  chem- 
icals; their  totals  are  still  included  with  that  group  in  order  to  tempo- 
rarily preserve  comparability  of  the  statistics  of  miscellaneous  chem- 
icals. Data  are  reported  in  terms  of  bulk  surface-active  agents,  that 
is,  in  terms  of  100-percent  content  of  the  surface-active  agent,  exclusive 
of  all  ingredients  such  as  inorganic  salts  and  water. 


50  UNITED    STATES    TARIFF    COMMISSION 

Surface-active  agents  include  detergents  (other  than  soap),  wetting 
agents,  and  dispersing  agents  (other  than  waxes).  In  general,  these 
chemicals  contain  a  hydrophobic — or  water-insoluble — radical  and  a 
hydrophyllic- — or  water-soluble — radical  which  enable  them  to  be 
partly  soluble  in  both  aqueous  and  nonaqueous  mediums.  This 
property  alters  the  interfacial  tension  between  these  two  mediums, 
thereby  improving  their  miscibility.  The  selection  of  the  proper 
radicals  or  chemical  groups  results  in  products  that  are  active  in  a 
variety  of  mixtures  where  soaps  would  be  quite  ineffective.  Subse- 
quently these  chemicals  may  be  converted  into  finished  preparations 
such  as  cleaning  compounds,  shampoos,  prepared  textile  specialties, 
and  dentifrices. 

Production  of  surface-active  agents  totaled  153  million  pounds  in 
1944.  This  was  a  large  increase  over  1943,  but  part  of  it  was  only 
apparent,  being  due  to  more  complete  reporting,  especially  of  the 
cyclic  products.  Sales  in  1944  were  135  million  pounds,  valued  at 
30  million  dollars,  with  an  average  unit  value  of  22  cents  per  pound. 

The  1944  output  of  cyclic  surface-active  agents,  which  accounted 
for  slightly  less  than  half  of  the  total  for  all  such  agents,  was  74  million 
pounds;  sales  of  71  million  pounds  amounted  to  12  million  dollars. 
Production  of  aromatic  sulfonates  from  petroleum  was  30  milUon 
pounds;  sales  were  26  miUion  poimds,.  valued  at  2  million  dollars. 
Quaternary  ammonium  compounds,  wliich  are  effective  cationic  ger- 
micides, had  the  highest  average  unit  value  of  any  surface-active 
agent — $1.02  per  pound. 

Production  of  acyclic  surface-active  agents  totaled  78  million  pounds, 
a  31-percent  increase  over  1943.  Sales  were  64  million  pounds,  valued 
at  18  million  dollars,  in  1944,  compared  with  57  million  pounds,  valued 
at  15  million  dollars,  in  1943.  Fats  and  oils — the  raw  materials  for 
soaps — are  also  the  most  important  raw  materials  for  acyclic  surface- 
active  agents.  The  fatty  acids  obtained  from  these  fats  and  oils  may 
be  hydrogenated,  re-esterified,  sulfonated,  or  converted  to  amides  or 
other  products.  Production  of  sulfonated  fats  and  oils — one  of  the 
oldest  types  of  surface-active  agents — totaled  29  million  pounds,  an 
increase  of  at  least  150  percent  over  1943.  This  increase,  however, 
largely  reflects  more  complete  reporting  of  the  statistics.  Sales  of 
sulfonated  fats  and  oils  were  19  million  pounds,  valued  at  3  million 
dollars,  in  1944  compared  with  11  million  pounds,  valued  at  4  million 
dollars,  in  1943. 

PLASTICIZERS 

Plasticizers  are  relatively  inert  high-boiling  liquids  or  low-melting 
solids  which  are  added  to  plastics  materials  in  order  to  make  them 
more  workable,  more  flexible,  or  more  elastic.  Table  20A  shows  pro- 
duction and  sales  of  these  products  in  1944  (see  also  table  20B,  part 
III,  for  an  alphabetical  list  of  these  products  in  which  the  manufac- 
turers are  identified).  In  previous  years,  these  chemicals  have  been 
included  with  miscellaneous  chemicals;  their  totals  are  still  included 
with  that  group  in  order  to  temporarily  preserve  comparability  of  the 
statistics  on  miscellaneous  chemicals. 

Production  of  plasticizers  amounted  to  187  million  pounds  in  1944, 
a  37-percent  increase  over  1943.    Sales  of  plasticizers  were  172  million 


SYNTHETIC    ORGANIC    CHEMICALS,    194  4 


51 


pounds,  valued  at  39  million  dollars,  compared  mth  129  million 
pounds,  valued  at  32  million  dollars,  in  1943. 

About  six  times  as  much  cyclic  plasticizers — 160  million  pounds— 
as  acyclic  plasticizers  was  produced  in  1944.  Sales  of  153  million 
pounds  were  valued  at  32  million  dollars.  The  most  important  group 
of  cyclic  plasticizers  were  the  phthalates,  and  the  most  important 
individual  items  were  dibutyl  phthalate,  with  a  production  of  48  mil- 
lion pounds,  and  dimethyl  phthalate  (which  is  also  used  as  an  insect 
repellent),  with  a  production  of  43  million  pounds.  Tricresyl  phos- 
phate, the  output  of  which  amounted  to  21  million  pounds,  ranked 
third  in  importance  in  the  cyclic  group. 

Production  of  acyclic  plasticizers  totaled  27  million  pounds  in  1944. 
Sales  of  19  million  poimds  were  valued  at  7  million  dollars.  The 
production  of  dibutyl  sebacate,  the  most  important  acyclic  plasticizer, 
was  5  million  pounds;  sales  were  slightly  less  than  5  million  pounds, 
valued  at  2  million  dollars. 

Table  20A. — Synthetic  organic  chemicals:   United  States  -production  and  sales  of 

plasticizers,  1944 

[Listed  below  are  all  plasticizers  for  which  any  reported  data  on  production  or  sales  may  be  published. 
Table  20B  in  part  III  lists  alphabetically  all  those  plasticizers  for  which  data  on  production  or  sales  were 
reported  and  identifies  the  manufacturer  of  each] 


Production 

Sales 

Quantity 

Value 

Unit  value 

1,000  pounds 
186,  745 

1,000  pounds 
171,  741 

1,000  dollars 
39, 065 

Per  pound 
$0. 23 

PLASTICIZERS,  CYCLIC 

Total                                              -        

160,  235 

153, 120 

32,  257 

.21 

Chemicals  for  which  separate  statistics  may  not 

22,  253 
137,982 

21, 172 
116,  810 

17, 996 
135, 124 

20,  409 
114,715 

5,187 
27, 070 

4,979 
22, 091 

.29 

Chemicals  for  which  separate  statistics  are  shown 

.20 

Phosphoric  acid  esters:  Tricresyl  phosphate 

Phthalic  acid  or  anhydride  esters,  total         . 

.24 
.19 

Dibutyl  phthalate  .  .-           

47, 810 

3,478 

42, 837 

22,  685 

26,  510 

47,  232 

3,714 

42, 163 

21,606 

18, 621 

9,533 

710 

6,609 

5,239 

6,808 

.20 

.19 

Dimethyl  phthalate  '  --    

.16 

All  other-.     .  .._ -     - 

.24 

PLASTICIZERS,  ACYCLIC 
Total                                 

.37 

Chemicals  for  which  separate  statistics  may  not  be 
shown                                 .    -      

12,  495 
14,015 

946 
3,544 
1,104 
5,455 
2,966 

7,416 
11,205 

927 
2,049 
1,085 
4,522 
2,622 

2,530 
4,278 

354 
431 

452 

2,216 

825 

.34 

Chemicals  for  which  separate  statistics  are  shown 

.38 

.38 

.21 

.42 

.49 

.32 

602 
1,260 
1,104 

691 

958 

1,073 

175 
322 
328 

.30 

.34 

.31 

>  Includes  dimethyl  phthalate  for  use  as  an  insect  repellent. 


52 


UNITED   STATES   TARIFF    COMMISSION 


MISCELLANEOUS  SYNTHETICIORGANICICHEMICALS 

Miscellaneous  synthetic  organic  chemicals  consist  of  acyclic  inter- 
mediates and  finished  acyclic  and  cyclic  products  not  included  in 
any  of  the  previous  groups.  Among  these  are  chemicals  such  as 
solvents,  photographic  chemicals,  insecticides,  plasticizers,  and 
surface-active  agents.  For  the  first  time,  in  these  reports,  however, 
statistics  on  surface-active  agents  and  on  plasticizers  are  shown  in 
separate  groups  (see  tables  19A  and  20A).  In  order  to  temporarily 
preserve  comparability  of  the  statistics,  data  for  the  totals  of  these 
two  groups  are  also  included  among  those  of  the  miscellaneous  chemical 
group  in  1944.  Production  and  sales  of  miscellaneous  chemicals  in 
1944  are  shown  in  table  21 A  (see  also  table  2 IB,  part  III,  for  an 
alphabetical  list  of  these  products  in  which  the  manufacturers  are 
identified). 


Table  21A. — Synthetic  organic  chemicals:   United  States  production  and  sales  of 
miscellaneous  chemicals,  1944 

[Listed  below  are  all  miscellaneous  chemicals  for  which  any  reported  data  on  production  or  sales  may  be 
published.  (Leaders  are  used  where  the  reported  data  are  confidential  and  may  not  be  published  or 
where  no  data  were  reported.)  Table  21B  in  part  III  lists  alphabetically  all  those  chemicals  for  which 
data  on  production  or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Production 

Sales 

Product 

Quantity 

Value 

Unit 
value 

Grand  total. 

1,000  pounds 
9, 927, 464 

1,000  pounds 
5, 874, 728 

1,000  dollars 
957,347 

Per  pound 
$0  16 

MISCELLANEOUS  CHEMICALS,  CYCLIC 
Total 

465, 756 

327,862 

84, 469 

26 

Chemicals  for  which  separate  statistics  may  not 
be  shown 

183, 142 
282, 614 

160,  235 
74,  264 

48, 115 

61,818 
266, 044 

153, 120 
70,  880 

42, 044 

20,  713 
63,  756 

32,  257 
11,905 

19,  594 

34 

Chemicals  for  which  separate  statistics  are  shown 
below 

24 

Plasticizers,  cyclic  ' 

21 

Surface-active  agents,  cyclic'. 

17 

All  other  cyclic  miscellaneous  chemicals  shown 
below,  total 

47 

Benzoic  acid  salts:  Sodium  benzoate     ... 

2,881 

18 

1 

12 

36 

1,301 

4,839 

2,762 

18 

1 

10 

32 

1,400 

864 
201 
■52 
55 
457 
1,013 

31 

Biological  stains . 

11  06 

Chemical  indicators . 

73  00 

Chemical  reagents 

5  45 

Cyclopropane. 

14  25 

N.N'-Diethyldiphenylurea 

.72 

Flotation  reagents 

Gallic  acid,  tech 

145 
16,  205 

158 
11,195 

1.09 

Insecticides,  synthetic,  total     

19, 107 

.69 

4,4'-  Dichlorodiphenyl-l,l,l-trichloroethane 
(DDT) 

9,626 
9,481 
2,536 

9,039 
7,166 
4,422 

7,560 
3,635 
4,009 

84 

All  other 

51 

Photographic  chemicals,  total.  . 

.91 

Benzotriazole 

1 

3,682 

4 

735 

8 

2,425 

10 

1,566 

7  23 

H y droquinone  (Hy droquinol) 

1,899 

4 

633 

19 

68 
17,  297 

66 

p-Hy  droxyphenylglycine 

2.77 

Another 

2  17 

Plant  hormones 

Pyrogallol  (Pyrogallic  acid) 

62 
16, 987 

127 

9   flR 

Tanning  materials 

1,463                    .09 

See  footnotes  at  end  of  table. 


SYNTHETIC   ORGANIC   CHEMICALS,    1944 


53 


Table  21  A. — Synthetic  organic  chemicals:   United  States  production  and  sales  of 
miscellaneous  chemicals,  1944 — Continued 


Product 


Production 


Sales 


Quantity 


Value 


Unit 
value 


MISCELLANEOUS  CHEMICALS, 

ACYCLIC 
Total.- 


1,000  pounds 
9,  461,  708 


Chemicals  for  which  separate  statistics  may  not 
be  shown 

Chemicals  for  which  separate  statistics  are  shown 
below..- --- 


Plasticizers,  acyclic  ' - 

Surface-active  agents,  acyclic  ' - 

All  other  acyclic  miscellaneous  chemicals  shown 
below,  total - - 


Acetaldehyde 

Acetic  acid:  Synthetic  (100%) 

Acetic  acid  salts 

Acetic  anhydride,  from  all  soiuces. 

Acetin:  Tri 

Acetone: 

By  fermentation -.. 

From  isopropyl  alcohol 

Amines,  total 


Hexamethylenetetramine . 
All  other 


Amyl  acetates,  primary,  total. 


Normal  (90%) 

Another  (90%).-.. 
Amyl  alcohols,  total. 


Crude  (Fusel  oU)  (100%) 

All  other 

Butadiene:  Grade  for  rubber  3. 
Butyl  acetates:  Normal  (90%). 
Butyl  alcohols,  total 


Primary:  Normal  (n-Propylcarbinol)  (100%). 

All  other 

Carbon  disulfide 

Cellulose  derivatives 

C  hloral  (Triehloroacetaldehyde) 

l-Diethylamino-4-aminopentane       (Novoldia- 

mine). 

Diethyl  malonate  (Malonic  ester) 

Ethyl  acetate  (85%) 

Ethylene  (from  ethyl  alcohol  and  ether) 

Ethylene  glycol 

Ethyl  ethers,  technical,  absolute,  and  U.  S.  P 

Ethyl  formate 

Ethyl  monochloroacetate 

Ethyl  oxalate  (Diethyl  oxalate) 

Fatty  acid  esters,  not  included  with  plasticizers 

Flotation  reagents 

Formaldehyde  (37%  HCHO  by  weight) 

Formic  acid  salts,  total. 


Sodium  formate,  tech. 
All  other.. 


Gases  (pwsonous,  tear,  etc.).- 
See  footnotes  at  end  of  table. 


1 ,000  pounds 
5,  546, 866 


2,  599,  560 
6, 862, 148 

26,  510 
78, 372 

6,  757,  266 


292,  611 

11,  706 

495, 522 

7,530 

56, 386 

328,  428 

44, 340 


18, 309 
26, 031 
15,  088 


11,  734 
3,354 
18,  527 


2,193 
16, 334 

723, 814 
69,  987 

246,  444 


150,  320 

96, 124 

291, 807 

353,  258 

2,608 

223 

480 

108, 196 


202, 451 

76, 192 

449 

18 

592 

3,000 

20, 487 

522, 440 

2,520 


3,409 


1,000  dollars 
872, 878 


1, 847,  837 
3,  699, 029 

18,  621 
63,  826 

3,  616,  582 


20,  917 

108,  743 

11, 301 


7,129 
57,  278 
22, 946 


11,  539 


16,  282 


2,149 
14, 133 

725,  502 
67, 965 

161, 044 


284,  425 
223, 513 


90, 203 
202 


70, 415 
420 


2,304 

19, 206 

344, 902 

2,912 


1,466 
1,446 


3,478 


Per  pound 
$0.16 


288, 727 
584, 151 

6,808 
18, 033 

559, 310 


2,028 

7,801 

981 


2,050 
4,103 
8,103 


1,857 


2,309 


272 

2,037 

273, 917 

10, 608 

23,564 


10, 124 
68,  233 


9,586 
154 


6,933 
108 


633 
3,604 
12, 889 

408 


320 
963 


.28 


54 


UNITED    STATES   TARIFF    COMMISSION 


Table  21  A.— Synthetic  organic  chemicals:   United  States  production  and  sales  of 
miscellaneous  chemicals,  1944 — Continued 


Product 


Production 


Sales 


Quantity 


Value 


Unit 
value 


MISCELLANEOUS  CHEMICALS, 
ACYCLIC— Continued 

All  other  acyclic  miscellaneous  chemicals— Con. 
Halogenated  hydrocarbons,  total 


1,000  pounds 
1, 842, 082 


Chlorides,  total 

Carbon  tetrachloride 

Chlorinated  paraffin -. 

Chloroform: 

Technical 

U.  S.  P 

Hexachloroethane 

Methyl  chloride  (Chloromethane),  crude 

and  refined 

Methylene    chloride    (Dichloromethane), 

crude  and  refined 

Tetrachloroethylene  (Perchloroethylene) . . . 

All  other 

Bromides,  fluorides,  iodides,  and  mixtures, 

total -. 

Ethyl  bromide 

Methyl  bromide 

All  other 


Isopropyl  alcohol  (100%)... - 

Isopropy  1  ether 

Lactic  acid: 

Edible  (100%) 

Technical  (100%) 

Lactic  acid  salts:  Sodium  lactate 

Maleic  acid  and  anhydride 

Methanol  (synthetic) 

Oxalic  acid 

Oxahc  acid  salts:  Ammonium  oxalate. 
Pentaerythritol 


Stearic  acid  salts,  total. .. 

Aluminum  stearate,  di. 
Aluminum  stearate,  tri. 

Calcium  stearate 

Magnesium  stearate 

Zinc  stearate 

All  other 


Thioglycolic  acid  and  salts.. 
Thiourea 

Trimethylene  chlorohydrin. 


/  ,000  pounds 
939, 044 


1,000  dcllars 
82,  274 


1, 688, 813 
209, 802 
43,  560 

7,762 

1,985 

76,  526 

24,  299 

8,329 

75, 128 

1,241,422 

153, 269 

377 

3,678 

149, 214 

480, 772 


788, 087 
201, 074 
41,911 

7,453 

1,918 

77,  833 

22, 000 

.  7, 9^8 


427,  900 
150, 957 


3,511 
147, 446 


4,161 

4,458 

324 

7,823 

472,  686 

18, 027 


12, 440 
13,  719 


5,995 

4,208 

4,215 

350 

6,988 

360,  741 

17,  754 

95 

10, 856 

13, 628 


3,453 
716 

2,354 
663 

4,384 

2,149 

104 

2,156 

1 


3,299 
726 

2,358 
658 

4,430 

2,157 

82 


P  r pound 
$0.09 


54, 096 
8,302 
4,179 

1,180 

445 

6,987 


930 


28, 185 
28, 178 


1,907 
26,  271 


200 


589 
66 
1,768 
12,  853 
1,812 
23 
3,807 

3,512 


743 
170 
609 
204 
1,319 
467 

463 


.07 
.04 
.10 

16 

.2 

.09 

.18 

.12 

.07 

.19 


.03 

.23 
.14 
.19 
.25 
.04 
.10 
.24 
.35 


.23 
.23 
.26 
.31 
.30 
.22 

5.64 


1  See.table  20A. 
>  See  table  19A. 

»  Data  shown  refer  to  butadiene  produced  from  alcohol.    Data  for  butadiene  produced  from  petroleum 
are  given  in  table  4A. 


Production  of  all  these  miscellaneous  items  reached  9.9  billion 
pounds  in  1944,  an  increase  of  12  percent  over  1943,  and  almost 
double  the  production  in  1941.  Sales  of  miscellaneous  organic 
chemicals  were  5.9  billion  pounds,  valued  at  957  million  dollars,  in 
1944  as  against  4.9  billion  pounds,  valued  at  660  million  dollars,  in 
1943.  Sales  accounted  for  about  60  percent  of  production,  the  re- 
maining output  being  consumed  in  the  producmg  plants  in  the 
manufacture  of  other  products. 

Cyclic  organic  chemicals  included  constituted  less  than  5  percent 
of  the  total  production  of  miscellaneous  synthetic  organic  chemicals 
in  1944.  The  outstanding  cyclic  chemical  was  the  new  insecticide 
DDT,  which  was  credited  with  preventing  the  spread  of  typhus 


SYNTHETIC   ORGANIC    CHEMICALS,    1944  55 

during  the  war.  Production  of  DDT,  publishable  for  tHe  first  time, 
totaled  9.6  million  pounds  in  1944;  sales  totaled  9.0  million  pounds, 
valued  at  7.6  million  dollars. 

Acyclic  chemicals  represented  about  95  percent  of  the  total  produc- 
tion of  miscellaneous  organic  chemicals,  in  part  owing  to  the  inclusion 
of  all  acyclic  intermediates  with  that  group,  whereas  cyclic  inter- 
mediates are  shown  in  a  separate  group.  Acyclic  miscellaneous 
chemicals  also  include  solvents  and  other  finished  products  produced 
in  large  volume.  Production  of  miscellaneous  acyclic  organic  chem- 
icals totaled  9.5  billion  pounds  in  1944,  a  10-percent  increase  over  1943 
and  almost  double  the  production  in  1941.  More  than  half  of  the 
output  of  these  chemicals  was  produced  for  sale.  Sales  were  5.5 
billion  pounds,  valued  at  873  million  dollars  in  1944,  compared  with 
4.6  billion  pounds,  valued  at  598  million  dollars,  in  1943.  The 
average  unit  sales  value  in  1944  was  16  cents  a  pound,  an  increase  of 
3  cents  over  the  average  of  1943. 

Production  statistics  are  shown  separately  for  about  two-thirds  of 
the  acyclic  miscellaneous  organic  chemicals.  In  1944  a  new  sub- 
group was  set  up  for  halogenated  hydrocarbons  (bromides,  chlorides, 
fluorides,  and  iodides).  Production  of  this  subgroup  of  chemicals, 
which  includes  various  solvents,  acyclic  intermediates,  and  refrig- 
erants, totaled  1.8  billion  pounds;  sales  of  939  million  pounds  were 
valued  at  82  million  dollars.  The  most  important  chemicals  in  this 
group  are  carbon  tetrachloride,  ethyl  chloride,  sym.-tetrachloroethane 
(acetylene  tetrachloride),  and  trichloroethylene. 

The  most  important  miscellaneous  acyclic  organic  chemical  was 
butadiene  derived  from  ethyl  alcohol  and  used  in  production  of 
synthetic  rubber.  In  1944,  about  724  million  pounds  of  butadiene 
was  produced  from  alcohol  and  726  million  pounds,  valued  at  274 
million  dollars,  was  sold.  (Production  of  butadiene  from  petroleum, 
shown  in  table  4A,  totaled  489  million  pounds.) 

Other  important  chemicals  in  this  subgroup  are  synthetic  acetic 
acid  (with  a  production  of  293  million  pounds),  acetone  (385  million 
pounds),  formaldehyde  (522  million  pounds),  and  isopropyl  alcohol 
(481  million  pounds).  Acetic  acid  is  used  to  make  acetic  anhydride 
and  cellulose  acetate;  acetone  is  used  as  a  solvent  in  the  manufacture 
of  cellulose  acetate  rayon  and  smokeless  powder;  formaldehyde, 
chiefly  in  the  manufacture  of  tar-acid  resins;  and  isopropyl  alcohol, 
chiefly  as  a  solvent. 

Important  chemicals  for  which  production  statistics  are  not 
publishable  are  synthetic  ethyl  alcohol  ^  and  tetraethyl  lead.  Before 
1944,  statistics  on  production  and  sales  of  recovered  acetic  acid  were 
included  with  the  totals  for  the  miscellaneous  chemicals  group. 
Beginning  with  1944,  however,  these  data  are  not  included  in  the 
group  totals  since  the  recovery  of  used  acetic  acid  does  not  represent 
true  production.  Most  of  this  acetic  acid  is  recovered  as  a  byproduct 
in  the  manufacture  of  cellulose  acetate.  In  1944,  production  of 
recovered  acetic  acid  amounted  to  about  1  billion  pounds.  The 
total  recovered  is  larger  than  the  amounts  reported  in  former  years 
because  of  errors  in  reporting  in  those  years.  Sales  of  the  recovered 
acid  were  53  million  pounds,  valued  at  1.6  million  dollars. 

'  Statistics  on  the  production  of  ethyl  alcohol  from  natural  sources  by  fermentation  are  not  included  in 
this  report.  They  are,  however,  issued  monthly  and  annually  by  the  Alcohol  Tax  Unit,  Bureau  of  Internal 
Revenue,  IT.  S.  Treasury  Department. 


PARI 


ALri;ABETICAL  LIST  OF  INDIVIDUAL  PRODUCTS,  BY 


GROUPS,  AND^MANUFACTURERS" 

Part  III  of  this  report  consists  of  a  series  of  tables  (3B  to  2 IB) 
which  hst  alphabetically  all  the  synthetic  organic  chemicals  reported 
as  produced  in  1944,  and  a  Directory  of  Manufacturers  (table  22). 
Each  table  lists  the  individual  items  which  are  included  in  the  totals 
shown  in  the  tables  for  the  different  groups  in  parts  I  and  II.  Products 
for  which  separate  statistics  are  given  in  part  I  and  part  II  are  indi- 
cated by  an  asterisk  (*).  Tables  in  part  III  have  the  same  number 
(followed  by  the  letter  B)  as  the  corresponding  tables  in  part  I  or  part 
II  which  are  followed  by  the  letter  A. 

The  Directory  of  Manufacturers  consists  chiefly  of  companies  which 
report  production  of  synthetic  organic  chemicals  to  the  United  States 
Tariff  Commission.  The  name  of  each  manufacturer  listed  in  the 
directory  is  preceded  by  an  identifying  number.  Companies  which 
manufacture  the  chemicals  listed  in  the  B  series  of  tables  in  part  III 
of  this  report  are  identified  by  these  numbers  except  for  a  few  com- 
panies which  have  specifically  requested  the  Tariff  Commission  to 
withhold  such  information  on  certain  items.  The  latter  manufac- 
turers are  indicated  only  by  the  letter  X. 

TAR  CRUDES 


Table  3B. — Organic  chemicals:  Tar  crudes  for  which  United  States  production  or 
sales  were  reported,  identified  by  manufacturer,  1944 

[Tar  crudes  for  which  separate  statistics  are  given  in  table  3A  are  marked  below  with  an  asterisk^*) ;  products 
not  so  marked  do  not  appear  in  table  3A  because  the  reported  data  are  confidential  and  may  not  be  pub- 
lished. Manufacturers  are  identified  by  numbers  in  the  alphabetical  list  appearing  in  table  22.  An  X 
signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number  with  the 
designated  product] 


Product 


Manufacturers'  identification  numbers  (according  to  list  in 
table  22) 


Tari. 

Light  oil  and  distillates: 
•Crude  light  oil 

♦Benzene  (except  motor  benzene) 

*Motor  benzene 

♦Toluene: 

"All  grades,  except  aviation  grade 

♦Aviation  grade 

♦Solvent  naphtha 

♦Xylene 

♦Another. 

♦Naphthalene,   crude  (solidifying  at  76°  to 
less  than  79°). 

Anthracene,  crude  (less  than  30%)- 

Cresylic  acid,  crude  (less  than  75%) 

Cumene 

♦Pyridine,  crude  and  refined 

♦Creosote  oil... 


31,  38,  51,  55,  56,  58,  59,  61,  72,  83,  106,  107,  108,  109,  139,  151, 
238, 249, 259,  260, 264, 288, 289, 295, 303, 309, 310, 314, 323, 346, 
353,  361,  362,  368, 369, 375, 387, 392, 401, 403, 422, 425, 453, 481, 
491, 503, 504, 505, 510,  X,  X,  X. 

31, 55, 61, 68, 83, 108, 109, 115, 139, 207, 232, 309, 353, 369, 386, 391, 

425   X   X. 
43, 69^96,' 308, 458. 
43, 361, 403, 458. 

43, 96, 298, 335,  361, 403, 415, 433, 434, 458, 466,  515,  X,  X,  X. 

HI,  265,  335, 354, 370, 434, 458, 466, 515. 

43, 241, 321, 345,  361, 381, 403. 

43,361. 

43, 69, 96, 254, 321, 346, 403, 458. 

43, 115, 217, 241, 293, 308, 345, 361, 377, 391, 403, 457. 

241, 377. 
43,377,381. 
43. 

43, 277. 

15, 43, 68, 114, 115, 133,  207,  217,  223,  232, 241,  249,  254,  293,  361, 
377, 381, 391, 453,  X. 

57 


58 


UNITED    STATES   TARIFF    COMMISSION 


Table  3B. — Organic  chemicals:  Tar  crudes  for  which  UniUd  States  production  or 
sales    were   reported,    identified   by    manufacturer,    1944- — Continued 


Product 


Manufacturers'  identification  numbers  (according  to  list  in 
table  22) 


•Crude  tar  acids 

*Coal  tar  sold  or  consumed  in  coal-tar  so 
lution. 

*Tars,  crude 

*Tars,  refined 

*Tars,  road 

*  Other  distillates 

'Pitch  of  tar 

♦Pitch  of  tar  coke - 


15, 43, 114, 133, 207, 217, 223, 232, 241, 254, 293, 377, 391, 425, 452. 
43,  223,  232,  241, 377, 293, 452. 

15,43,115,151,241,254,369. 

43, 115,  207,  241,  254, 361, 369,  377, 381, 391, 452. 

15,  31,  43,  133,  159,  207,  217,  223,  241,  254, 293, 361, 369, 377, 381 , 

391  425  452 
43,  68',  108',  207',  241,  254, 377,  381. 
15,  43,  68, 114, 115, 133,  207,  217,  223,  232,  241,  254,  361,  369,  377, 

381,391,  X. 
15, 43, 133,  223, 241, 293, 377,  381, 452. 


■  Only  those  manufacturers  are  identified  by  number  who  report  production  of  oil-gas  and  water-gas  tar 
to  the  U.  S.  Tariff  Commission.    For  P'-oduction  and  consumption,  see  tabulation,  p.  7. 

CRUDE  PRODUCTS  FROM  PETROLEUM  ANb  "  'ATURAL  GAS 

Table  4B.- — Organic  chemicals:  Crude  products  from  petroi  j,nd  natural  gas 

for  chemical  conversion  for  which  United  Sta  tes  production  or  sales  were  reported, 
identified  by  manufacturer,  1944- 

[Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  separate  statistics  are 
given  in  table  4A  are  marked  below  with  an  asterisk  (*);  products  not  so  marked  do  not  appear  in  table 
4A  because  the  reportea  data  are  confidential  and  may  not  be  published.  Manufacture.  "^  are  identified 
by  numbers  in  the  alphabetical  list  appearing  in  table  22.  An  X  signifies  that  the  manulacturer  did  not 
consent  to  the  publication  of  his  identification  number  with  the  designated  product] 


Product 


Manufacturers'  identification  numbers  (according  to  list 
in  table  22) 


Crude  products  from  petroleum: 

Cresylic  acid,  crude 

*Naph thenie  acid 

Benzene,  all  grades 

•Xvlene,  all  grades 

Another 

Hydrocarbons: 
Cj  hydrocarbons: 

Ethane 

•Ethylene 

*C3  hydrocarbons: 

Propane 

Propylene 

Ci  and  Cs  hydrocarbon  mixture.. - 
C4  hydrocarbons: 

n-Butane 

Butanes,  mixed 

*1,3-Butadiene,  grade  for  rubber. 

1,  3-Butadiene,  other  grades 

•1-Butene  and  2-butene,  mixture 

Isobutane 

Isobutylene 

Di-isobutylene 

Isoheptene 

Iso  pen  tane - 

Isoprene 

Isoprene-piperylene 

Methane 

Methyl-acetone-aeetal 

n-Pentane 

Piperylene 

Polybutene 

Tri-isobutylene 

Another 


265,  411,  412,  433,  434. 

385,  412,  433,  437,  447,  458,  466,  X. 

354 

111^  208,  335,  433,  434,  436. 

527. 


74, 329. 

74, 124,  298, 436. 

74,  329,  354,  447. 
74, 124,  329, 435, 436. 
434. 

74,  329,  354,  411,  447,  530. 

435 

74,  92,  124,  208,  307,  354,  410,  437,  525,  526,  528,  529. 

256,  329,  527,  528,  530,  X. 

208,  436,  458,  530. 

74,  329,  447. 

208,  435,  436,  530. 

435. 

354. 

447. 

X. 

X. 

74,  329. 

92. 

354. 

X. 

433,  435. 

435. 

435. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


59 


INTERMEDIATES 

Table  6B. — Synthetic  organic  che'micals:   Cyclic  intermediates  for  which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 

[Cyclic  intermediates  for  which  separate  statistics  are  given  in  table  6A  are  marked  below  with  an  asterisk 
(*);  cyclic  intermediates  not  so  marked  do  not  appear  in  table  6A  because  the  reported  data  are  con- 
fidential and  may  not  be  published.  Manufacturers  are  identified  by  numbers  in  the  alphabetical  list 
appearing  in  table  22.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his 
identification  number  with  the  designated  product] 


Chemical 


Acenaphthylene  ( Aeenaphthene) 

5-Acetamido-2-aminobenzenesulfonic  acid 

*5-Acetamido-8-amino-2-  and  3-naphthalene  sulfonic  acid   (Acetyl- 
amino  Cleve's  acid). 

2-Acetamido-4-aminophenol  hydrochloride 

2-Acetamido-3-chloroanthraquiiione 

2-Acetamido-3-chloro-9,10-dihydro-9,10-anthradiol-9,10-disuIfonicacid, 
diethyl  ester. 

5-Acetamido-2-naphthalenesulfonic  acid. 

5- Acetamido-8-nitro-2-naphthaleDer''i  f  .uie  acid 

2-Acetamido-4-nitrophenol ^^.  (^•-^ 

5-Acetamidosalicylic  f">i'^  '      :- 

*Acetanilide,  tech..  ^ 

o-Acetaniside  (Acetj.  S'\'^:-Maine) 

p- Acetaniside  (Acetyl-p-a>iisidine)  - 

Acetate  leueo  vio'"t  (1,4-Dihydroanthraquinone) 

Acetoacetanilide  

Acetoaceto-1-naphc-^ylamide 

o-Acetoacetotoluide -' 

o-AcetotoluidO-- 

*p-Acetotoluide.;2 

*N-Acetylsulfaiiilyl  chloride  (p-Acetamidobenzenesulfonyl  chloride) - 
Acridine  yellow 

*p-Aminoacetanilide 

4-Amino-o-acetaniside 

3-Amino-p-acetotoluide 

5- Amino-2- (4-amino-m-toluiiio)  benzenesulfonic  acid 

*5-Amino-2-anilinobenzenesulfonic  acid 

*l-Aminoanthraquinone  and  salt. 

*2-Aminoanthraquinone  and  salt 

1- Aminoanthraquinone-2-sulfonic  acid 

*6-Amino-3,4'-azobis(benzenesulfonicacid)- 

8-Amino-l,2-benzacridui-7(12)-one 

p-Aminobenzaldehyde 

l-Amino-5-benzamidoanthraquinoiie 

*6-(m-Amuiobenzamido)-l-naphthol-3-sulfonic    acid    (m-Aminoben- 
zoyl  J  acid). 

*6-(p-Aminobenzamido)-l-naphthol-3-sulfonie  acid  (p-Aminobenzoyl 

J  acid). 
4-Amino-m-benzenedisulfonic  acid 

*2-Amino-p-benzenedisulfonic  acid  (Anilino-2,5-disulfonic  acid) 

o-Aminobenzenesulfonic  acid _ 

p-Aminobenzoic  acid 

p-Aminobenzoic  acid,  ethyl  ester  (Ethyl  p-aminobenzoate) 

o-Aminobenzylsulfonic  acid  (o-Toluidine  omega  sulfonic  acid) 

l-Amiiio-4-bromo-2-anthraquinonesulfonic  acid  (Bromamine  acid)__ 

l-Amino-2-bromo-4-(p-toluino)  anthraqutnone 

p-Amino-N-(n-butyl)phenoL 

Amtnobutyramidodiethylhydroquiaone 

2-Amino-3-chloroanthraquinone 

l-Amino-5-chloroanthraquinone  and  l-amino-8-chloroanthraquinone. 

l-Amino-5-chloroanthraquinone 

2-Amuio-5-chlorobenzenesulfonic  acid 

•'^- Amino-2-chlorobenzenesulfonic  acid 

nino-6-chlorobenzoic  acid 

.    ^Amino-4-chlorobenzoyl)  benzoic  acid 

Atiinochloronitrophenol 

2-A  ilno-4-chlorophenol - 

Aminochlorophenolsulfonie  acid 

6-Amino-4-chloro-m-toluenesulfonic  acid 

•2-Amino-5-chloro-p-toluenesulfonic  acid  (Lake  red  C  amine) 

2-Amino-p-cresol  (m-Amino-p-cresol) 

2-Amino-l,3-dibromoanthraquiiione 

l-Amino-2,4-dibromoanthraquuione 

4-Amino-2,5-dichloro-m-benzenesulfonic  acid 

4- Amino-5-ethoxy-o-butyrophenetide 

5-Amino-6-ethoxy-2-naphthalenesulfonic  acid 

p- Amino-N-ethyl-N-l-naphthylbenzamide 

697646—46 5 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


241,  377. 

171. 

127,  171,  304. 

X. 

171. 
171. 


171, 

171, 

X. 

1. 

91, 

11. 

202 

28, 

74. 

;,351 

,74, 
,'304 
69, 
f69, 
'127 
91, 
171, 
202, 
171, 
91, 
11, 
69, 
171 
11, 
127, 
171 
171 
11, 


124,  127,  171,  282,  298,  413. 
171,  193. 


193. 

,467. 

202,  413. 

79,  91,  286,  298,  413,  501. 

,304, 

127,  171,  304. 


127,  171,  304. 

28,  69,  127,  171,  281,  304. 

127,  171,  304. 


85,  171,  304. 


127,  171,  304,  351. 


11,  85,  127,  171,  304,  351,  X. 

304. 

91,  127,  351. 

171. 

127,  134,  405. 

501. 

304. 

127,  171. 

127. 

127. 

351. 

171. 

304. 

304. 

11, 127,  304. 

91. 

91,  127,  171,  351. 

171. 

91, 171. 

91,  171. 

91. 

127. 

53,  69,  204,  413,  439. 

91. 

127. 

127, 171,  304; 

127. 

351. 

171. 

171. 


60 


UNITED    STATES   TARIFF    COMMISSION 


Table  6B. — Synthetic  organic  chemicals:   Cyclic  intermediates  for  which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


3-Aminoformanilide 

3-Amino-2-hydroxyanthraquinone ._. 

3-Amino-4-hydroxybenzenearsonic  acid _ 

3-Amino-6-hydroxy-2-methylphenazine  (Tolazine  base) 

8-Amino-6-methoxyquinoliue  ( Amichin) 

4'-Amino-5'-methyl-p-toluenesulfon-o-aniside 

1-Aminonaphthalenedisulfonic  acid 

2-Amino-l,5-naplithalenedisulfonic  acid _. 

*3-Amino-l,5-naphthalenedisulfonic  acid 

3-Amino-2,7-naplithalenedisulfonic  acid 

4-Amino-l ,5-naphthaIeued isulfonic  acid 

4-Amino-l,6-naphthialenedisulfonic  acid 

*6-Amino-l ,3-naph tlialenedisulfonic  acid 

*7-Amino-l,3-naphithalenedisulfonic  acid  (Amino  G  acid) 

*8-Amino-l,6-naplithalenedisulfonic  acid  and  salt 

l-Amino-2-napiathalenesulfonic  acid  (o-Napbthionic  acid) 

•2-Amino-l-naphthalenesulfonic  acid  (Tobias  acid).__ 

*5-Amino-l-naphthalenesu]fonic  acid  (Laurent's  acid). 

*5-Amino-2-naphthalenesulfonic  acid 

•5-  and  8-Amino-2-naphthalenesulfonic  acids  (Cleve's  acid) 

*6-Amino-2-naphthalenesulfonic  acid  (Broenner's  acid).. 

7-Amino-2-naphthalenesulfonic  acid,  sodium  salt 

*8-Amino-l-naphthalenesulfonic  acid 

*8-Amino-2-naphthalenesulfonic  acid 

7-Amino-l .3,6-naphthaleni'trisulfonic  acid 

8-Amino-l,3,5-naphthalenetrisulfonic  acid 

*8-Amino-l,3,6-naphthalenetrisulfonic  acid 

8-Amino-l-naphthol-5,7-disulfonie  acid,  monosodium  salt  (Chicago 

acid). 
7-Amino-l -naphthol-3,6-disulfonic  acid,  monosodium  salt  (2R  acid).. 
*8-Amino-l-naphthol-3,6-disulfonic  acid,  monosodium  salt  (H  acid)... 

5-Amino-l-naphthol 

*l-Amino-2-naphthol-4-sulfonic  acid __,. 

*6-Amino-l-naphthol-3-sulfonic  acid,  sodium  salt  (J  acid) 

•7-Amino-l-naphthol-3-sulfonic  acid,  sodium  salt  (Gamma  acid) 

8-Amino-l -naphthoic  acid 

8-Amino-2-naphthol [_ 

8-Amino-l-naphthol-3,5-disulfonic  acid' .'.    ". 

•8-Amino-l-naphthol-5-sulfonic  acid,  sodium  salt  (Sacid) 

*2-Amino-5-nitrobenzenesulfonic  acid 

Aminonitrodiphenylsulfide l.l.l[[[[[[[]l\l[ 

*4'-Amino-4-nitrodiphenylamine-2-suifonic  acid 

•2-Amiiio-4-nitrophenol 

2-Amino-S-nitrophenol l.l""[[[l 

4-Amino-2-nitrophenol l"["l[V. 

2-Amino-4-nitro-l-phenol-6-sulfonic  acid' ""' 

•o-Aminophenol ".I.I. 

•p-Aminophenol  and  salts. 1. 1 1 II  "III 

p-Aminophenol  oxalate I 

•2-Amino-l-phenol-4-sulfonicacid IIIIIIIIII. 

*m-(p-Aminophenylazo)benzenesulfonic  acid I. II 

*p-(p-Aminophenylazo)benzenesulfonic  acid 

5(and  8)-Ammo-8(and  5)-phenylazo-2-naphthalenesulfonic  acid 

6-Amino-5-phenylazo-l-naphthol-3-sulfonicacid 

4-Amino-3-phenyl-m-cresol  hydrochloride 

2-(m-Aminophenyl)-6-hydroxy-3-naphth[l,2]imidazoie-8-sulfonic 
acid. 

2-(p-Aminophenyl)-6-methylbenzothiazoIe 

l-(m-Aminopbenyl)-5-oxo-3-pyrazoline-4-carboxylic  acid  (m-Amino- 
phenylpyrazolonecarboxylic  acid) . 

Aminopyrazolone  (4-Aminoantipyrine) 

2-Aminopyridine IIIIIIIIIIIII 

2-Aminopyrimidine IIIII  "I 

5-Aminosalicylic  acid III  ' 

2-(4-Amino-3-sulfophonyl)-6-methylbenzothiazo"le 

2-(4-Amino-3-sulfophenyl)-6-methylbenzothiazolesulfonic  acid..    .  I" 
•2-Aminothiazole_  _  _ 

l-Amino-4-toluenesulf onamidoanthraquinone-2-sulfonic  acid I . 

•4-Amino-m-toluenesulfonic  acid 

4-Amino-o-toluenesulfonic  acid IIIIIIIIIIIII 

5-Amino-o-toluenesulfonic  acid I.IIIII 

4-(4-Amino-m-toIylazo)-m-toluenesulfonic  acid  and  salt  (o-Aminoazo- 
toluenesulfonie  acid  and  salt). 

16-Aminoviolanthrene 

2-Amino-3,5-xylenesulfonic  acid I  I 

Amylnaphthalenes __ ""l"[ 

o-AmylphenoL IIIIIII""!  I 

p-tert-Amylphenol .".'"".'.".".""  

*  Aniline  (Anihne  oil) 


171. 
171. 

I,  501. 
91,  304. 
501. 
171. 
127. 
413. 

91,  127,  171,  304. 

85,  91. 

127,  304. 

304. 

91,  127,  171,  304. 

85,  91,  127,  171,  304,  413. 

91,  127,  304. 

X. 

18,  69,  91,  202,  413,  439. 

69,  85,  91,  127,  171,  304. 

91,  127,  171,  304. 

69,  91,  127,  171,  304. 

18,  91.  304,  413. 

413. 

85,  127,  171,  304. 

91,  127,  171,  304. 

304. 

171. 

127,  171,  304. 

91,  127,  304. 

127,  304. 

127,  171,  298,  304. 

304. 

91,127,134,171,304. 

II,  85,  91,  127,  171,  304. 
11,  91,  127,  171,  304. 
171. 

127,  171. 

171. 

91,127,171,304. 

91,  127,  304. 

304. 

11,  91,  304. 

69,  85,  127,  171,  304,  X. 

171. 

91. 

91,  171. 

48,  134,  274,  479. 

69,  127,  134,  479,  509. 

134. 

53,  91,  304,  X. 

11,  91,  127,  304. 

53,  69,  85,  171,  351. 

171. 

171. 

134. 

171. 

127,  304. 
127,  304,  351. 

501. 

372,  377. 

286,  X. 

11,91,304. 

171. 

127,171. 

69,  91,  274,  298,  X. 

171. 

69,91,127,351,413. 

91,  171. 

127. 

304. 

171. 

171,485. 
407. 
407. 
407. 
69,  124,  127,  282, : 


i,  304,  306,  X. 


SYNTHETIC   ORGANIC    CHEMICALS,    1944 


61 


Table  6B. — Synthetic  organic  chemicals:   Cyclic  intermediates  for  which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944- — Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


Aniline  hydrochloride 

Aniline  hydrochloride  and  sulfate 

Aniline  methane  sulfonic  acid,  sodium  salt 

Aniline  omega  sulfonic  acid 

Aniline  sulfate 

2-Anilinoethanol  (Phenylethanolamine) -.. 

6-Anilino-2-methoxymetani]ic  acid 

*6-Anilino-l-naphthol-3-sulfonic  acid  (Phenyl  J  acid) 

•7-Anilino-l-naphthol-3-sulfonic  acid  (Phenyl  gamma  acid) 

2- Anilino-5-nitrobenzenesulfonic  acid 

Anisic  acid 

o-Anisidine 

p-Anisidine 

o-Anisidinomethanesulfonic  acid  (o-Anisidine  omega  methanesul- 

fonic  acid) . 

o-Anisidine  nitrate 

Anisoin 

*N-(p-Anisyl)-4-chloroanthranilic  acid,  potassium  salt  (3-Chloro-4'- 

methoxy-6-diphenylamine-carboxylic  acid,  potassium  salt). 

a-(p-Anisyl)-p-methoxyacetophenone 

Anthracene,  refined 

Anthra[l  ,9]isothiazole-2-carbonyl  chloride 

Anthranilic  acid 

Anthra[l,9]pyrazol-6(2)-one  (Pyrazolanthrone) 

Anthraquinone 

Anthraquinone-l,5-disulfonic  acid 

Anthraquinone-l,8-disulfonic  acid... 

Anthraquinone-1 ,8-disulfonic  acid,  potassium  salt 

Anthraquinone-1,5-  and  1,8-disulfonic  acid 

*Anthraquinone-2,6-disuIfonie  acid  and  salt 

a-Anthraquinonehydrazinedisulfonate 

*l-Anthraquinonesulfonic  acid  and  salt 

2-Anthraquinonesulfonic  acid,  sodium  salt  (Silver  salt) 

3-(l-Anthraquinonylamino)-7-benz(de)anthracen-7-one  (Benzamide) 

♦Anthrarufin  (1,5-Dihydroxyanthraquinone) 

Arsanilic  acid 

Arsanilic  acid,  sodium  salt 

Arsphenamine 

Azobenzene 

p,p'-Azobis  (N,N-dimethylaniline  hydrochloride) 

4,4'-Azobisdiphenylamine  (4'-Diazodiphenylamine) 

l,l'-Azobis(l-amino-2-naphthol-4-sulfonic  acid) 

l,l'-Azobis(8-nitro-2-naphthol-4-sulfonic  acid) 

5,5'-Azobis  (salicylic  acid) 

Azoxydianiline  (Azoxybisaniline) 

Benzal  chloride 

♦Benzaldehyde,  tech 

Benzaldehydedisulfonic  acid 

Benzaldehydemonosulfonic  acid 

Benzaldehyde  semicarbazone 

'l-(4  -  Benzamido-1-  anthraquinonylimino)  -5-benzamidoanthra- 

quinone. 

l-Benzamido-4-chloroanthraquinone 

•l-Benzamido-5-chloroanthraquinone 

2-(4-Benzamido-2,5-diethoxy-N-methylphenyldiazoamino)ethane- 

sulfonicacid. 
2-(4-Benzamido-2,5-dimethoxy-N-methylphenyldiazoamino)ethane- 

sulfonic  acid. 

4-Benzamido-6-methoxy-N-methyl-m-tolyldiazoaminoacetic  acid 

6-Benzamid  o-4-methoxy-3-(p-toluenesulfonamido)  toluene 

8-Benzamido-l-naphthol-3,5-disulfonic  acid 

*6-Benzamido-l-naphthol-3-sulfonicacid  (Benzoyl  J  acid) 

•7-Benz[de]anthracen-7-one  (Benzanihronc) 

Benzanthronedianthraquinonyldi-imide 

Benzenedisulfonic  acid,  sodium  salt 

Benzenesulfonamide 

*Benzenesulfonic  acid  and  salt 

Benzenesulfonyl  chloride 

Benzidine,  base 

•Benzidine  hydrochloride  and  sulfate 

Benzil 

2-Benzofur_yl  cyanomethyl  ketone 

Benzoic  acid,  tech 

Benzoic  anhydride... 

Benzoin 

Benzonaphthol 

a-Benzoylacetanilide 

o-Benzoylbenzoie  acid 

Benzoyl  chloride - .-. 


171,  351. 

69,  85,  127,  304. 

286. 

74. 

91. 

11,  85,  91,  127,  171,  304,  351,  X. 

11,  85,  127,  351. 

53. 

165. 

127,  298. 

127,  298,  304. 

85,  127,  304,  351. 

171. 
137. 
304,  351,  501. 

255. 

241,  377. 

127. 

124, 127. 

127, 171. 

69,  171. 

69,  127,  171,  304. 

171. 

127, 171. 

304. 

69,  "127,171,304. 

171. 

11,  69,  91,  127,  171,  281,  304. 

11,  127,  304. 

171. 

85,  91,  127,  171,  304. 

1,  243,  286. 

88. 

1,501. 

134,  304. 

149. 

149. 

85,  91,  304. 

127,  304. 

127,  304. 

351. 

201,205. 

48,165,201,457,  X. 

171. 

171. 

137. 

69,  127,  171,  304. 

171. 

69,127,171,304. 

171. 

171. 


85,  91. 

69,  127,  171,  304,  341. 


286. 
X. 

48, 
157 
134 
50, 
X. 
69, 
205 


,  511. 

134,  171,  298. 

,  298,  511. 

,304. 

79,  91,  127,  134,  157,  171,  304^ 


201,  286,  298,  475. 

,205. 

,  149,  157,  286. 

X. 

127,  171,  304. 
,457. 


62 


UNITED   STATES   TARIFF    COMMISSION 


Table  6B. — Synthetic  organic  chemicals:    Cyclic  intermediates  for  which   United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


Benzyl  alcohol,  tech.. 

Benzyl  disulfide. - 

Benzyl  ether 

N-Bcnzyl-N-ethylaniline 

N-Benzyl-N-ethyl-p-nitrosoaniline 

o-Benzylhydroxybenzoate,  calcium  salt 

Benzylidineaminopyrazolone  (Benzylidine-4-amino  antipyrinc) 

p,p'-Benzylidinebis(N,N-dimethylaniline)     (Tetramethyldiamino- 
triphenylmethane) . 

Benzyl  morcaptan 

p,p'-Biacetoacetanilide 

(3,3'-Bi-7-benz(de]anthracen)-7,7'-dione  (13,13-Dibenzanthronyl) 

(4,4'-Bi-7-benz[de]anthracen)-7,7'-dione  (2,2-Dlbenzanthronyl) 

Bibenzyl 

Binaphthalenedicarboxylic  acid 

Biphenyl 

o-Biphenylamine 

p-Biphenylamine 

5,8-BisCp-aminobenzamido)-2-naphthalenesulfonic  acid 

p,p'-Bis(diethylamino)benzophenone  (Ethyl  ketone  base) 

2,7-Bis  (dimothy  lamino)  acridinehydrochloride 

p,p'-Bis(dimethylamino) benzohydrol  (Michler's  hydro!) 

•p,p'-Bis(dimethylamino) benzophenone  (Michler's  ketone) 

Bis(p-dimethylaminophenyl)methanesulfonic  acid  and  salt 

N,N-Bis(2-hydroxyethyl)-m-toluidine 

l,4-Bis(methylamino)anthraquinone 

*N,N'-Bis-6-(l-naphthol-3-sulfonic  acid)urea  (J  acid  urea) 

5,8-Bis(p-nitrobenzamido)  -2-naphthalenesulfonic  acid 

Bis(o-nitrophenyl)disulfide 

Black  base  V 

•3-Bromo-7-benz[de]anthracen-7-one 

Bromobenzene 

Bromobenzyl  chloride 

2-Bromodibenzofuran . 

p-Bromomethylaminoanthraquinone 

6-Bromo-3-methyl-7-dibenz[f,i,Jlisoquinoline-2,7(3)-dione    (4-Bromo- 
N  -meth  yl-1 ,9-anthrapyridone) . 

1-Bromonaphthalene 

p-Bromophenol 

3-tert-Butyl-p-cymene 

6-tert-Butyl-2,4-dimethylacetophenone 

2-tert-Butyl-5-methylanisole 

5-tert-Butyl-m -xylene  (l,3-Dimethyl-5-tert-butylbenzene) 

Butylnaphthylamine 

Carbazole,  refined 

Carbazoletetrasulfonic  acid 

3-Carboxy-2-  and  4-hydroxybenzenediazonium  sulfate 

o-(Carboxymethylmercapto) benzoic  acid 

3-Carboxy-l-(3'-nitrophenyI)-5-pyTazolone 

Chloranil  (Tetrachloroquinone) 

o-Chloroacetoacetanilide  (o-Acetoacetochloroanilide) 

p-Chloroacetoacetanilide  (p-Acetoacetochloroanilide) 

Chloroacetylcatechol. 

m-Chloroaniline 

o-Chloroan;Iine 

p-Chloroaniline.-  

*4-Chloro-o-anisidine 

l-(4-Chloro-o-anisyl)  -3-methyl-3-triazeneacetic  acid 

3-ChIoro-2-anthracenecarboxylic  acid __ 

•1-Chloroanthraquinone 

*2-Chloroanthraquuionc-. 

l-Chloro-2-anthraquinonecarboxyIicacid 

3-Chloro-2-anthraquinonecarboxylicacid 

*o-Chlorobenzaldehyde 

p-Chlorobenzaldehyde 

Chlorobenzanthrone 

*Chlorobenzene,  mono 

p-Chlorobenzenesu Ifonic  acid 

o-Chlorobenzoic  acid.. 

*Chlorobenzoylbenzoic  acid. 

5-Chloro-2(3)-benzoxazolone. 

6-Chloro-m-cresol _. 

5-Chloro-2,4-dimethoxyaniline 

5-Chloro-l,4-dimethoxy-2-nitrobenzene 

*l-Chloro-2,4-dinitro  benzene ^ 

4-Chloro-3-hydrazinobenzenesulfonic  acid 

6-Chloro-2-hydroxyacetanilide 

5-Chloro-2-hydroxy-3-nitroacetanilide.. 

Chlorohydroxyquinoline... 


48,  205,  414. 

157. 

414,  X. 

127,  304. 

171. 

1. 

501. 

274. 

205. 

351. 

127,  171. 

127. 

475,  X. 

171. 

124,  298. 

298. 

298. 

171. 

127,  130,  202. 

351. 

127,171. 

127,  130,  171,  202,  274. 

304. 

171. 

171. 

11,  69,  85,  91,  127,  171,  304. 

171. 

171. 

91. 

11,  127,171. 

124. 

157. 

171. 

171. 

171. 

134. 
124. 
X. 

X. 
X. 

X. 

298. 

127,  377. 

171. 

171. 

171. 

304. 

124,  306. 

193,  467. 

467. 

243,  501. 

127.  298. 

298. 

298. 

127^  205,  479. 

171. 

171. 

69,127,171,281,304. 

69,  171,  304. 

127,  304. 

171. 

127,  201,  304. 

171. 

304. 

124,  127,  128,  140,  205,  298,  419. 

171. 

127,  201. 

69.127,171,304. 

171. 

43. 

171. 

171. 

11,69,127,171,274,298,304. 

171. 

171. 

171. 

91. 


SYNTHETIC   ORGANIC    CHEMICALS,    1944 


63 


Table  6B. — Synthetic  organic  chemicals:   Cyclic  intermediates  for  which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22)  J 


4-Chlorometanilic  acid 

5-Chlorometanilic  acid 

•Chloromethylanthraquinone 

o-Chloro-l-methylnaphthalene 

Chloronaphthalenes 

8-Chloro-l-naphthol-3,6-disulfonie  acid  (Cnloro  H  acid)_._ 

*2-Chloro-4-nitroaniline 

*4-Chloro-2-nitroaniline 

l-Chloro-5-nitroantliraquinone 

l-Chloro-8-nitroanthraquinone 

l-Chloro-5-  and  8-nitroanthraquinone 

Chloionitrobenzene,  mixed  (o  and  p) 

Chloro-m-nitrobenzene 

Chloro-o-nitrobenzene 

Chloro-p-nitrobenzene 

4-Chloro-3-nitrobenzenesulfonic  acid 

*2-ChIoro-5-nitrobenzenesulfonic  acid 

2-Chloro-4-nitrobenzoic  acid 

*2-Chloro-5-nitrobenzoic  acid 

o-(4-Chloro-3-nitrobenzoyl) benzoic  acid 

4-Chloro-2-nitrophenol 

4-Chloro-2-nitro  toluene 

6-Chloro-2-nitro  toluene 

*o-Chloroplienol 

p-Chlorophenol 

4-Chloro-o-phenylenediamine 

o-Chlorophenylhydrazine 

l-(o-Chloro  phenyl)  -3-methyl-5-pyrazolone 

2-Chloro-6-phenylphenol 

2-Chloro-6-phenylphenol,  sodium  salt 

2-[l-(m-Chlorophenyl)triazenol-4-sulfobenzoic  acid 

p-Chloropropionanilide 

2-Chloroquinizarin : 

2-Chloro-5-sulfobenzoic  acid 

l-(6-Chloro-3-sulfo  phenyl)  -3-methyl-5-pyrazolone 

2-Chloroterephthaloylbis-o-benzoic  acid 

•a-Chlorotoluene  (Benzyl  chloride) 

m-Chlorotoluene 

o-Chloro  toluene 

p-Chloro  toluene 

3-Chloro-p-toluenesulfonic  acid,  sodium  salt _ 

3-Chloro-o-toluidine 

3-Chloro-p-toluidine  (4-Amino-2-chloro toluene)  _  _  _ - . 

4-Chloro-o-toluidLne  (Red  KB  base)..- 

4-Chloro-o-toluidine  hydrochloride 

5-Chloro-o-toluidine  (2-Amino-4-chlorotoluene) 

Chlorotolylbenzoic  acid 

* (4-Chloro-o-tolylmercapto)acetic  acid 

l-(5-Chloro-o-tolyl)-3-methyl-3-triazenoacetic  acid 

2-Chloro-p-xylene 

Chloro-3,5-xylenol 

(4- C hlo ro-2, 5-xylylmercapto)acetic  acid 

Chrysazin  (1,8-Dihydroxyanthraquinone) 

*Cresol  (meta,  para) 

"Cresol  (ortho,  meta,  para) 

m-Cresol 

*o-Cresol 

p-Cresol 

Cresols,  chlorinated 

2,3-Cresotic  acid 

*Cresylic  acid,  refined 

m-Cresyl  valerate -- 

8-C  yano-1-naph thalenesulfonic  acid 

Cyclohexylacetic  acid 

Cyclohexylamine 

2-Cyclohexyl-4,6-dinitrophenol 

4,4'-Cyclohexylidene-o-toluidine-.  _ 

Cymene 

Decylbenzene 

1,5-  and  1,8-Diacetamidoanthraquinone 

1,4-Diaminoanthraquinone 

1,5-Diaminoanthraquinone 

*2,6-Diaminoanthraquinone-- 

Diaminoanthraquinone  (1,5- and  1,8-) 

*4,4'-Diamino-3,3'-biphenyldisulfonic  acid 

*2,2'-Diamino-5,5'-bi-m-toluenesulfonic  acid 

m,m'-Diaminocarbanilide  (l,3-(Di-m-aminophenyl)urea) 

*4,4'-Diamino-l,l'-dianthraquinonylamine --- 

4,4'-Diaminodiphenyl  sulfone - 


304. 

127. 

69, 127, 171,  304. 

494. 

39, 188.  205. 

171,  304. 

11. 18,  69, 124, 127. 

124, 127, 479. 

127,  304. 

127. 

304. 

127. 

298. 

127,  298. 

11,127,298. 

85, 91,  304. 

11,85,91,127,171,304. 

171. 

91,  304, 351. 

171. 

91, 171. 

127, 171, 304. 

127. 

124, 298,  X. 

124,  298. 

149. 

171. 

568. 

124. 

124. 

171. 

171. 

304. 

171,  351. 

127, 171. 

171. 

48,  201,  205,  298. 

171. 

127,  304. 

201.  205. 

127,  298, 413. 

127, 171. 

127. 

127, 304. 

127. 

127, 171,  281, 304. 

171. 

127, 171,  304. 

171. 

171. 

43. 

171. 

127, 171. 

43,  69,  241,  377, 381. 

43,  69,  377. 

43,  377. 

43, 69,  241,  377, 381. 

43,  201, 377, 413. 

43. 

124. 

43,  241, 377,  433. 

501. 

171. 

205. 

298. 

124. 

171. 

X. 

298. 

11. 

127, 171. 

127, 171,  304. 

69, 171,  304. 

11. 

11,69,85,351. 

11,85,91,351. 

85. 

69, 127, 171,  281,  304. 

304. 


64 


UNITED    STATES   TARIFF    COMMISSION 


Table  6B. — Synthetic    or  garlic^  chemicals:   Cyclic  intermediates  for  which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


Manufacturers'  identification  num- 
l.bers  (according  to  list  in  table  22) 


*4,4'-D iaminodiphenylamine-2-sulfonic  acid. _ 

5,8-Diamino-2-naphthalenesulfonic  acid 

7,8-Diamino-2-naphthalenesulfonic  acid... 

l,4-Diamino-5-nitroanthraquinone 

Diaminophenetole 

*N,N '-Di(m-aminophenyl)oxamide  (Oxalyl-m-phenylenediamine)... . 
N,N'-Di(p-aminophenyl)oxamide  (Oxalyl-p-phenylenediamine) 

*4,4'-Diamino-2,2'-stilbenedisulfonic  acid 

3,5-Diamino-p-toluenesulfonic  acid 

Diamylphenol 

l,5-Dianilinoanthraquinone-o-o'-dicarboxylic  acid 

3,4-Di(p-anisyl)hexane 

l,2-Di(p-anisyl)l,2-hexanediol 

3,4-Dianisyl-3-hexanol 

*l,l'-Dianthraquinonylamine 

1,5-Dibenzamidoanthraquinone 

Dibenzofurenol 

1,6-DibenzoylnaphthaIene 

Dibenzylidenehydrazine 

Dibenzylsulfanilic  acid,  sodium  salt 

3,9-Dibromo-7-benz[de]anthracen-7-one 

p-Dibromobenzene 

2,6-Dibromo-l,5-dihydroxynaphthaiene 

*2',7'-Dibromofluorescein 

7,16-Dibromoindanthrene  (1,2,1,2-Hydrazinedibromoaathraquinone) 
Dibromo-8,16-pyranthrenedione 

*2,5-r)ichloroaniline 

1,5-Dichloroanthraquinone 

1,8-Dichloroanthraquinone 

1,5-  and  1,8-Dichloroanthraquinone 

2,6-DichIorobenzaldehyde 

'o-Dichlorobenzene ". 

*p-Dichlorobenzene ....'. 

3,4-Dichlorobenzenesulfonic  acid 

•3,3'-Diehlorobenzidine  and  sulfate 

•2,4-Dichlorobenzoic  acid 

2,6-Dichlorobenzylidine  chloride ll.""'l"llll[l[[ 

l,S-Diehloro-4,5-dinitroanthraquinone 

Dichlorohydrazine. 

Dichlorohj  droxybenzoylbenzoic  acid 

*6.9-Dichloro-2-methoxyacridine 

2,6-Dichloro-4-nitroaniline 

*l,4-Dichloro-2-nitrobenzene 

2,4-Diehloropheuol  _ __. 

2-[l-(2,5-Dichlorophenyl)-3-ethyl-3-triazene]-5-sulfobenzoicacid 

l-f2,5-Dichlorophenyl)-3-methyl-5-pyrazolone 

l-(2,5-Dicho]orophenyl)-5-pyrazolonc-3-carboxyIic    acid    (Diehloro- 

phenylpyrazolonecarboxylic  acid) . 
2,5-Dichlorosulfanilicacid(ArainodichIorobenzenesulfonicacid) 

'l-(2,5-Dichloro-4-sulfophenyl)-3-methyl-S-pyrazolone 

*9  J-T^inlil/^rrvf nliifiTirt 


*2,4-Dichlorotoluene 

Dicresyl  disulfide 

Dicyclohexylamine I..""^_"]I"III" 

Dicyclopentadiene ".. 

2,5-Diethoxyaniline I..  _!..".].'." 

2,5'-Diethoxybenzanilide 

1,4-Diethoiy  benzene " 

l,4-Diethoxy-2-nitrobenzene '..'.'.'..'.." 

N-(2,5-Diethoxy-4-nitrophenyl)benzamide ..  .' 

Diethylaminobenzaldehyde 

N-Diethylaminoisopentyl-8-amino-6-methoxyquinoline'base'(Pias- 
mochin  base). 

m-Diethylaminophenol 

Diethylamino  rosindone 

*N,N-Diethylaniline "'"I. "I 

JS1,N-Diethylmetanihc  acid  and  salt 

N,N-Diethyl-p-nitrosoaniline 

N,N-Diethyl-4-nitroso-m-toluidine 

N,N-Diethyl-p-phenylenediamine 

N,N-Diethyl-p-phenylenediamine  hydrochloride  (p-Aminodiethyl- 

aniline  hydrochloride). 
2  -  (1  -  (5  -  Diethylsulfamyl  -  o  -  anisyl)  -  3  -  ethyl  -  3  -  triazene)  -  5  -  sul- 
fobenzoic  acid. 

Diethyl-m-toluidine 

N8,N«-Diethyl-2,5-toluenediamine  hydrochloride 

N,N'-Diformyl-2,5-toluenediamine 

Dihydroxydibenzanthrone 

4,5-Dihydroxy-2,7-naphthalenedisulfonie  acid  (Chromotropic  acid).. 

•4,5-Dihydroxy-l-naphthalenesulfonic  acid  (Dioxy  S  acid) 


11. 85, 91, 171,  304,  512. 

171. 

171. 

171. 

69. 

85, 127,  304, 351, 

127. 

127,171,304. 

304. 

407. 

127. 

287. 

243. 

243. 

127, 171, 281, 304. 

171. 

171. 

171. 

137. 

171,351. 

171. 

124. 

X. 

18, 202, 290. 

127. 

127. 

127, 205,  298,  304, 479. 

127, 171,  304. 

69, 127, 171. 

304. 

304. 

124, 127, 128, 140, 205, 298, 419, 431. 

124, 127, 128, 140, 205, 298, 419, 431. 

243. 

79, 127, 193,  202, 413. 

201, 205, 286, 304,  501. 

127. 

127. 

351. 

304. 

202, 351,  304,  501. 

171. 

91,298,304,479. 

124, 298. 

171. 

53. 

351. 

304,  351. 

85,  91, 127. 361. 

201, 286, 304,  501. 

306. 

298. 

X. 

171. 

171. 

171. 

171. 

171. 

304. 

501. 

127, 304. 

304. 

124, 127,  202, 304, 407. 

127, 304. 

171, 304. 

171. 

171. 

X. 

171. 

127. 
X. 

91. 

127. 

11,127,304. 

11,127,171. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


65 


Table   6B. — Synthetic  organic  chemicals:   Cyclic  intermediates  for  which   United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


4,6-Dihydroxy-2-naphthalenesulfonic  acid 

6,7-Dihydroxy-2-naphthalenesulfonic  acid 

3,5-Dihydroxy-2-naphthoic  acid 

16,17-Dihydroxyviolantlirone 

Di-isopropylbenzene 

2,5-Dimethoxyaniline 

1,4-Dimethoxybenzene 

3,3'-Dimethoxybenzidine 

l,4-Dimethoxy-2-nitrobenzene 

N-(2,5-Dimethoxy-4-nitrophenyl)benzamide 

N-(2,5-Dimethoxy  phenyl)  benzamide 

3,3'-Dimethoxy-4,4'-diphenylbis(3-methyl-3-triazene-ethanesulfonic 
acid). 

Dimethylaminoacetylcatechol 

p-Dimethylaminobenzaldehyde 

•N,N-Dimethylaniline 

*2,2'-Dimethyl-l,l'-bianthraquinone 

N,N-Dimethylcyclohexylamine 

Dimethyldiphenylurea 

2',7'-Dimethylfluoran 

Dimethyl-a-naphthylamine 

N,N-Dimethyl-p-nitrosoaniline 

N,N-DimethyIphenylazoaniline 

•N,N'-Dimethyl-p-phenylenediamine  and  hydrochloride 

Dimethylstyrene-_ 

N,N-Dimethylsulfanilic  acid 

2,4-Dinitroaniline 

p-(2,  4-Dinitroanilino)phenol  (Dinitrohydroxydiphenylamine) 

2,4-Dinitroanisole 

Dinitroanthraquinone  (1,5- and  1,8-) 

4,8-Dinitroanthrarufln  (l,5-Dihy(iroxy-4,8-dinitroanthraquinone) 

m-Dinitrobenzene 

2,4-Dinitrobenzenesulfonic  acid 

3,5-Dinitrobenzoic  acid 

3,5-Dinitrobenzoyl  chloride 

Dinitro(3,3'-bi-7-benz[de.]anthracen)-7,7'-dione       (Dinitrodibenzan- 
thronyl). 

4,4'-Dinitro-l,r-dianthraquinonylamine 

Dinitromonomethylaniline 

Dinitronaphthalene 

2,4-Dinitro-a-naphthol 

•2,4-Dinitrophenol,  tech 

N,N'-Di(p-nitrophenyl)oxamide  (Oxalyl-p-nitroaniline)  _ 

♦4,4'-Dinitro-2,2'-stilbenedisulfonic  acid 

2,4-Dinitrotoluene --- 

Di-o-tolylthiourea 

1,5-Dioxamidoanthraquinone 

Dipentene  (dl-Limonene) - 

1,5-Diphenoxyanthraquinone 

Diphenylamine 

*8-Diphenylamino-l,6-naphthalenedisulfonic  acid 

1,5-Diphenylcarbohydrazide 

1,3-Diphenyltriazene  (Diazoaminobenzene) 

Dipyrazoledianthrone 

Di-tert-butyl-m-cresol 

Di-tert-butyl-p-cresol 

l,4-Di(p-toluino)anthraquinone 

Dodecylbenzene 

6-Ethoxy-3-hydroxythianaphthene 

2-Ethoxynaphthalene 

2-Ethoxy-l-naphthylamine 

2-Ethoxy-l-nitronaphthalene 

N-(p-Ethoxyphenyl)-4-nitroanthranilic  acid-.-, 

3-Ethylamino-p-cresol 

3-Ethylamino-p-toluenesulfonicacid  (N-Ethyl-o-toluidine-p-sulfonic 
acid) . 

Ethylaniline,  mono,  crude  and  refined 

2-(N-E thylanilino)ethanol  (Hydroxyethylethylaniline) 

*a-(N-Ethylanilino)-p-toluenesulfonic  acid 

Ethylbenzene 

Ethylbenzyl-m-toluidine 

•Ethylbenzyl-m-toluidinesulfonic  acid 

3,3'-Ethylenebis[l-(5-chloro-l-anlsyl) -3-triazenp-acetic  acid] 

2-[3-Ethyl-l-(5-nitro-o-anisyl)-3-triazene]-5-sulfobenzoic   acid    (2-(N- 
E  thyl-5-nitro-o-anisyl-diazoamino)  -5-sulfobenzoie  acid) . 

•Ethylphenylmalonic  acid,  diethyl  ester 

Ethylsalicyl  carbonate 

N-Ethyl-5-sulfoanthranilic  acid.. 

N-2-Ethyl-2,5-toluenediamine 


171. 

171. 

171. 

171. 

32. 

127, 171. 

171. 

91, 127 

171. 

171. 

171. 

171. 

243. 

134,  157,  304. 

69,  127,  202,  304. 

69,  127,  171,  304. 

298. 

127. 

499. 

134. 

304. 

304. 

149,  304,  X. 

311. 

171. 

69,  298. 

91,  171,  304. 

274,  479. 

11,  85. 

127. 

127,  304. 

91,  171. 

134. 

134. 

127. 

127,  281. 

69. 

171. 

157. 

127,  171,  304. 

127. 

85,  91,  127,  171,  304. 

127,  304. 

127. 

171. 

127,  311. 

127. 

124,  127,  134. 

91,  127,  171,304. 

134. 

127,  304. 

127,  171. 

241. 

165. 

127. 

298. 

127. 

171. 

171. 

171. 

171. 

127. 

127. 

69,  127,  202,  304. 

171. 

69,  91,  127.  171,  304,  485. 

124,  298,  515. 

127,  304. 

127,  171,304. 

351. 

171. 

1,  48,  286,  501. 

124. 

171. 

171. 


66 


UNITED    STATES   TARIFF    COMMISSION 


Table  6B. — Synthetic  organic  chemicals:   Cyclic  intermediates  for  which    United- 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


N-Ethyl-m-toluidine  - 

N-Ethyl-o-toluidine , 

Fluorene 

a-Fluorenone 

o-Formylbenzenesulfonic  acid  (o-Sulfobenzaldehyde) 

Formanilide 

8-(3-Ouanylguanidino) -2-naphthol  hydrochloride 

Hexachlorobenzene -- 

Hexachlorodiphenyl  oxide 

m-Hydrazinobenzenesulfonic  acid 

*p-Hydrazinobenzenesulfonic  acid 

4-Hydrazino-m-toluenesulfonic  acid 

*Hydroquinone,  tech 

l-Hydroxy-4-aminoanthraquinone 

3-Hydroxy-2-anthracenecarboxylic  acid 

1-Hydroxyanthraquinone 

p-Hydroxybenzoic  acid..- 

2-Hydroxy-ll-benzo[a]carbazole-3-carboxylic  acid 

2-Hydroxy-3-carbazolecarboxylic  acid 

8-Hydroxy-3-naphth[l,2]  imidazole  hydrochloride 

2-Hydroxy-l-naphthoic  acid 

l-Hydroxy-2-naphthoic  acid,  ethyl  carbonate 

l-Hydroxy-2-naphthoic  acid,  methyl  ester 

3-Hydroxy-2-naphthoic  acid 

N-(7-Hydroxy-l-naphthyl)benzamide . 

/S-(2-Hydroxynaphthyl)-3-thianaphthenol  O-Naphtholthioindoxyl) . 

4-Hydroxy-3-nitro-l-phenylarsonic  acid 

l-Hydroxy-N-octadecyI-2-naphthamide 

2-Hydroxyphenetole 

p-Hydroxyphenylarsonic  acid 

0-  (p-Hydroxy  phenyl)-a-pheny  Ipropionic  acid 

8-Hydroxyquinoline,  crude 

p-(8-Hydroxy-6-sulfo-2-naphthylamino) benzoic  acid 

3-Hydroxy-,')-sulfo-2-naphthoic  acid 

5-Hydroxy-m-toluenesu!fonic  acid 

*  1,  l'-Iminobis(4-benzamidoanthraquinone) 

•6,6'-Iminobis(l-naphthol-3-sulfonic  acid)  (I  or  J  acid  imide)  (Rhodu- 

lineacid). 
Indene. 


*Indophenol,  blue  and  green 

7-Iodo-8-hydroxyquinoline-5-sulfonic  acid. 
Isatin 


p-Isobutylaminophenol  (p- Amino- N-isobutylphenol) 

Isophorone 

Isopropyl  ester  p-toluenesulfonate 

p,p'-IsopropylidenediphenoI        (p,p'-Dihydroxydiphenyldimethyl- 
methane). 

Isophthalic  acid  (1,3-Benzencdicarboxylic  acid) 

Isoviolanthrone  (Isodibenzanthrone) 

Leuco  l,4-di(methylamiDo)anthraquinone 

Leuco  indophenol  BCFN 

*Leuco  quinizarin 

Leuco  tetrahydroxyanthraquinone 

2,6-Lutidine 

2,4-Lutidine 

*Metanilic  acid 

2-Methoxy-4-aminodiphenylamine-2-sulfonic  acid 

p-Methoxy-a-  (p-anisyl)  butyrophenone 

1-Methoxyanthraquinone 

p-Methoxybutyrophenone 

2-(6-Methoxy-N-methyl-4-nitro-m-tolyldiazoamino)-5-sulfobenzoir 
acid. 

2-Me thoxy-4-nitrodiphenylamine-2'-sulfonic  acid 

4-Methoxy-4-nitrodiphenylamine-2'-sulfonic  acid 

5-Methoxy-m-phenylenediamine  (m-Diaminoanisole) 

6-Methoxy-m-toluiaine  (2-Amino-p-cresol  methyl  ether) 

Methyl  acetylsalicylate 

1-Methy  laminoanthraquinone. 

Methy laminosulfobenzoic  acid 

Methylaniline,  mono _. 

2-(N-Methylanilino)ethanol  (Hydroxyethylmethylaniline) 

5-Methyl-o-anisidine  (Cresidine) 

m-Methylanisole  (m-Cresol  methyl  ether) ._ 

N-Methylanthranilic  acid 

2-Methylanthraquinone 

2-Methy l-7-benz[de]anthracen-7-one  (2-Methylbenzanthrone) 

Methylbenzoxazole .._ 

Methylbenzyl  alcohol 

3,3'-Methylenebis(l-o-anisyI-3-triazeneacetic  acid) 


127,  304. 

127,  304. 

241.377. 

137. 

127. 

127. 

171. 

124,205. 

124. 

171. 

171,351,  441. 

171. 

78,  127,  134,  45(i,  479,  513. 

171.  304. 

171. 

304. 

201. 

171. 

171. 

171. 

127. 

171. 

171. 

171,  304,  413. 

171. 

91. 

1.  28<;. 

171. 

298. 

1,  134,  286. 

105. 

48. 

171. 

171. 

255. 

09,  127,  171,  281. 

f)9,  85.  127,  304.  351. 

155,  X. 

37,  127,  304. 

501. 

304. 

127. 

74,  410. 

127. 

124,  171. 


,171. 

69,  127,  274,  304,  X. 

^377. 

09,  85,  9i,  127.  171,  304. 

171. 


171. 

171. 

69,  274,  479. 

91. 

287 

28,69,91,  .27,  171.  193. 

171. 

91,  127. 

171. 

172. 

278. 

171,  278. 

69,  127,  304. 

304. 

134,  149. 

311. 

351. 


SYNTHETIC   ORGANIC    CHEMICALS,    1944 


67 


Table  6B. — Synthetic  organic  chemicals:   Cyclic  intermediates  for  which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  19^4 — Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


3,3'-Methylenebis(l-o-anisyl-3-triazenepropionic  acid) 

2,2'-Methylenebis(4-chlorophenol) 

3,3'-Methylenebis[l-(5-chloro-o-anisyl)-3-triazeneacetic  acid] 

3,3'-Methylenebis[l-(4-chloro-o  tolyl)-3-triazeneacetic  acid] 

3,3'-Methylenebis(  1  -(5-chloro-o-tolyI) -S-triazeneacetic  acid] 

3,3'-Methy lenebis[l- (fi-chloro-o-tolyl) -3-triazenepropionic  acid] 

p,p'  -  Methylenebis(N,N  -  diethylaniline)       (Tetraethyldiaminodi- 
phenylmethane). 

*p,p'-Methylenebis(N,N-dimethylanOine)    (Tetramethyldiaminodi- 

phenylmethane). 
p,p'-Methylenebis(N,N  -  dimethyl-  2-  nitroaniline)      (Dinitrotetra- 

methyldiaminodiphenylmethane) . 
p,p'-Methylenebis(N-ethylaniline)    [Di (ethylamino) diphenylmeth- 

ane]. 
4,4'-Methylenebisf3-hydroxy-2-naphthoic  acid)  sodium  salt  (Meth- 
ane salt). 

N,N'-Mf'thylenebis(4-methyIaminoantipyrine) 

Methylenebis(toluonediamine)  (Tetra-aminoditolylmethane) 

4,4'-Methylenebis(m-toluidine)    (4,4'-Diamino-2,2'-dimethyldiphen- 
ylmethane). 

Methyl  p-hydroxy-m-nitrobenzoate 

N-Methyl-N-(3-methyl-o-anisyldiazo)glycine 

2-Methylnaphthalene 

N-Methyl-p-nitroacetanilide 

4-Methyl-o-nitroanisole 

2-(N-Methyl-p-nitrosoanilino)ethanol 

N-(5-Methyl-4-nitro-o-anisyl)-p-toluenesulfonamide 

2-Methyl-l-nitroanthraquinone 

2-(N-Methyl-4-nitro-o-to!yldiazoamino)-5-sulfobenzoicacid 

(N-Methyl-p-phenpthyldiazoamino) acetic  acid 

'S-Methyl-l-phenyl-S-pyrazolone  (Developer  Z) -. 

Methylphenylpyrazolone - 

MethylphenylpyrazoIone-3-sulfonic  acid 

*Methyiphenylpyrazolone-4-sulfonicacid 

6-Methylquinoline. 

3-Methvl-l-(m-sulfophenyl)-5-pyrazolone 

3-Methyl-l-(p-sulfophenyl)-5-pyrazolone  (Methylsulfophenylpyraz- 
olone) . 

3-Methyl-l-(4-sulfo-o-tolyl)-5-pyrazolone 

Methylstyrene 

Methyl-p-toluenesulfonate 

5'-Methyl-p-toluenesulfon-o-aniside 

4-Methylumbelliferone 

♦Naphthalene,  solidifying  at  79°  C.  or  above,  refined,  flake 

Naphthaleneacetic  acid 

1 ,5-Naphthalenediol  (1 ,5-D  ihydroxynaphthalene) 

*l,5-Naphthalenedisulfonicacid--_ 

2,7-Naphthalenedisulfonic  acid 

1-Naphthalenesulfonic  acid 

1-Naphthalenesulfonic  acid,  aniline  salt 

2-Naphthalenesulfonic  acid 

2-Naphthalenesulfonic  acid,  sodium  salt 

Naphthalenesulfonic  acids,  sodium  salt,  mixture 

1,3,6-Naphthalenetrisulfonicacid 

Naphthalic  anhydride 

Naphthenic  acid 

3-Naphth[l,2]imidazole-8-sulfonicacid 

♦Naphthionic  acid  (4-Amino-l-naphthalenesuIfonic  acid)  and  salt 

•a-Naphthol . 

^-Naphthol,  tech 

l-Naphthol-3,6-disulfonic  acid  and  salt 

*2-Naphthol-3,6-disuUonic  acid  and  salt 

*2-Naphthol-6,8-disulfonic  acid  and  salt 

l-Naphthol-8-sulfamide 

l-Naphthol-4-sulfonic  acid  (Nevile  and  Winther's  acid) 

*l-Naphthol-5-sulfonic  acid 

l-Naphthol-8-sultonic  acid 

'2-Naphthol-6-sulfonic  acid  (Schaeffer's  acid) 

2-Naphthol-7-su!fonic  acid 

2-Naphthol-8-sulfonic  acid 

1-8-Naphthosultone 

l,8-Naphthosultone-3,6-disulfonicacid 

Naphth(1.2)oxadiazole-5-sulfonic  acid 

*1-Naphthylamine 

*2-Naphtbylamine 

1-Naphthylamine  hydrochloride 

l-(l-Naphthylamino)-2-anthraquinonecarboxylicacid 

ISI-(l-Naphthyl)ethylenediamme  hydrochloride --- 

1  Naphthyl  isoeyanate 


351. 
171. 
351. 
351. 
351. 
351. 
69,  274. 

127,  171,  274,  304, 

171,  304. 

298. 

501. 

501. 
304. 
127. 

501. 

171. 

377. 

171. 

127. 

171. 

171. 

171. 

171. 

171. 

11,69,85,127,171,304,351,601. 

124, 127. 

171. 

69,  91, 171. 

171. 

53. 

127, 351. 

171. 

124,  X. 

171. 

171. 

134,  X. 

43,  69, 115, 127,  241,  361,  377, 413,  432. 

413. 

171,304. 

91,127,171,304. 

127, 274, 304,  413. 

171. 

171. 

91, 157, 298, 304. 

69. 

91. 

171. 

134. 

134. 

171. 

69,91,127,171,304. 

91,127,171,304. 

69,  304, 413. 

85, 91,  304. 

91, 171, 304, 413, 485. 

91,127,171,304. 

91. 

91, 127, 304. 

91, 171, 127, 304. 

171. 

18. 69, 91, 127, 171, 304, 485. 

91, 127, 413, 

91. 

85, 91. 

274. 

171. 

127, 171, 304. 

127,157,274,304. 

157, 171. 

127. 

134. 

134. 


68 


UNITED    STATES   TARIFF    COMMISSION 


Table  6B. — Synthetic  organic  chemicals:   Cyclic  intermediates  for  which   United 
States  -production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


2-Naphthylmercaptoacetic      acid      (2-Naphthalenemercaptoacetic 
acid). 

p-NitroacetanUide 

4-Nitro-o-acetaniside 

4-Nitroaminobeuzene-2-sulfoethylanilide 

*m-NitroanilLne 

o-Nitroaniline 

p-Nitroaniltne 

*2-Nitro-p-anisidine 

4-Nitro-o-anisidine 

S-Nitro-o-auisidine 

o-Nitroanisole 

p-Nitroanisole 

9-Nitroanthra[l,9-de,  4,10-d'e']bis(l,2,3-oxathiazine)-2,7-bisdioxide 

l-Nitro-2-anthraquinonecarboxylic  acid 

5-Nitro-l-anthraqutnonesuIfonic  acid 

5-  and  8-Nitroanthraquinonesulfonic  acid 

2(l'-Nitro-2'-anthraquinonyl)anthra[2,3]oxazole-5,10-dione 

m-Nitrobenzaldehyde 

*6-(m-Nitrobenzamido)-l-naphthol-3-sulfonic  acid  (m-Nitrobenzoyl  J 
acid). 

•6-(p-Nitrobenzamido)-l-naphthol-3-sulfonic  acid  (p-Nitrobenzoyl  J 
acid) . 

•Nitrobenzene 

2-Nitro-p-benzenedisulfonic  acid 

Nitrobenzenesulfonic  acid 

•m-Nitrobenzenesulfonic  acid 

o-Nitrobenzenesulfonic  acid ._ 

p-N  itrobenzenesulf onic  acid ,  potassium  salt 

ra-Nitrobenzenesulfonyl  chloride 

m-Nitrobenzoic  acid 

p-Nitrobenzoic  acid 

p-Nitrobenzoic  acid,  ethyl  ester  (Ethyl  p-nitrobenzoate) 

m-Nitrobenzoyl  chloride. 

p-Nitrobenzoyl  chloride 

m-Nitrobenzoylsulfonic  acid 

Nitrobenzoyltoluenediaminesulfonic  acid 

o-Nitrobiphenyl 

p-Nitrobiphenyl 

Nitrocresol  (isomer  not  specified) 

m-Nitrocresol 

2-Nitro-p-cresol 

4-Nitro-2-diphenylaminesulfonicacid 

4-Nitro-5-ethoxy-o-butyrophenetide 

Nitronaphthalene 

7-Nitro-l,5-naphthalenedisulfonic  acid 

8-Nitronaphthalenetrisulfonic  acid 

7,8-Nitronaphth(l,2)oxadiazole-5-sulfonicacid 

o-Nitrophenetole 

*o-Nitrophenol _ 

p-Nitrophenol I. ".'.".]".!!..  . 

o-Nitrophenoxybenzene 

p-Nitrophenylhydrazine '... 

l-(m-Nitrophenyl)-5-pyrazolone-3-carboxyiicacid 

Nitropyrazolonecarboxylic  acid 

5-Nitrosalicylic  acid 

l-Nitroso-2-naphthol l.[Vi"l"".- 

l-Nitroso-2-naphthol-7-sulfonicacid ll..l.[[[l[ll"l[[ 

Nitrosophenol 

*p-Nitrosophenol l^^\\\[^^        '.'."/. 

m-Nitrotoluene '-""""!!-"'' 

o-Nitrotoluene l.[[[l[\lV^l\[l"\. 

p-Nitrotoluene l"l[\\\[]W     '_'  """ 

Nitrotoluene  mixtures V^l"l[[\][\m\\[^\\l\] 

1-Nitro-p-toluenesulfonic  acid -_"I.I-Iim"I". 

*3-Nitro-p-toluenesulfonie  acid 1. 1 -!.'_' 

*5-Nitro-o-toluenesulfonie  acid 

3-Nitro-p-toluic  acid 

*2-Nitro-p-toluidine !.__  I 

4-Nitro-o-toluidine ...11  

fi-Nitro-o-toluidine ' 

3-Nitro-p-tolunitrile 

3-Nitro-p-tolyl  chloride. 

4-Nitro-N-tolylnaphthahmide .... 

N-(4-Nitro-o-tolyl)-p-toluenesulfonamide 

Nitroviolanthrene 

4-Xitro-m-xylene... I]I]II!].IIII 

Nitroxylene "-...^^mil^mil^I"" 

Pentachlorophenol  and  sodium  salt".V"rrrr"'"rrr"I''"  """ 


69, 127, 171. 

91, 171. 

171. 

304. 

69, 85, 91, 127, 304. 

298. 

11, 127,  298,  304. 

127, 171, 202,  304. 

127, 171,  281, 304. 

127, 171, 281, 304. 

127, 298. 

127, 157. 

171. 

171. 

127. 

304. 

171. 

171. 

127,171,351. 

127,171,351. 

69, 127, 171,  298, 304, 306. 

91. 

85, 304. 

91, 127, 171, 304,  X. 

171. 

69. 

304. 

127, 205. 

127. 

501. 

127, 205. 

127, 134, 205. 

11. 

171,304. 

2«8. 

298. 

127. 

1. 

91. 

171. 

351. 

127,  171,  304. 

91,  171. 

171. 

171. 

127. 

48,  127,  479. 

127,  298. 

351. 

134. 

171. 

351. 

171. 

69,  157,  304. 

171. 

304. 

37,  69,  91,  127,  171. 

127,  171,  304. 

127,  171,  304. 

127,  171,  304. 

127,  171,  304. 

85. 

11,69,91,  171. 

91.  127,  171,  304. 

171. 

69,  127,  202,  304,  413. 

171. 

127,  351,  413.. 

171. 

171. 

171. 

171. 

69,  171. 

91. 

127,  171,  304. 

124,  298. 


SYNTHETIC   ORGANIC    CHEMICALS,    1944 


69 


Table  6B.- — Synthetic  organic  chemicals:   Cyclic  intermediates  for  which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


9.10-Plienanthrenequinone 

Phenazlne 

o-Phenetidine 

p-Phenetidine 

p-Phenetidine  citrate 

•Phenol: 
Natural: 
♦From  coal  tar: 

U.  S.  P... 

37°  C.  m.  p 

*39°  C.  m.  p 

82  to  84  percent 

Another.. 

♦Synthetic: 

By  caustic  fusion: 

U.  S.  P 

82  to  84  percent . 

All  other 

From  benzol  by  oxidation:  U.  S.  P 

From  chlorobenzene  by  liquid-phase  hydrolysis:  U.  S.  P 

From  chlorobenzene  by  vapor-phase  hydrolysis:  XJ.  S.  P 

Phenol,  sodium  salt 

*Phenolsulfonic  acid 

Phenothioxin 

o-Phenoxyaniliae 

*Phenylacetic  acid,  tech 

Phenylacetic  acid  and  ester 

2-Phenylanthra[2,3]oxazole-5,10-dione 

•p-Phenylazoaniluie  (Aminoazobenzene)  and  hydrochloride 

N-Phenyldibenzylamtae  (Dibenzylaniline) 

*m-Phenylenediamine 

o-Phenylenediamine 

p-Phenylenediamine 

*m-Phenjienediaminesulfonic  acid 

*p-Phenylenediaminesulfonic  acid 

Phenylene  nerol  acid  (6-(p-AminoanUiao)metanilic  acid) 

Phenyl  ether  (Diphenyl  oxide).. 

♦Phenylglycine  and  salt 

Phenylhydrazine 

Phenylhydrazuie  and  hydrochloride. 

•2,2'-Phenyliminodiethanol    (Phenyldiethanolamine)     (N,N'-Bis(2- 
hydroxyethyl)  anUtne) . 

Phenylisocyanate 

♦Phenylmalonio  acid,  diethyl  ester 

N-Phenyl-1-naphthylamiae , 

N-Phenyl-2-naphthylamine 

*N-Phenyl-l-naphthylamine-8-sulfonic  acid  (Phenyl  peri  acid) 

o-Phenylphenol 

p-Phenylphenol 

o-Phenylphenol,  sodium  salt 

N-Phenyl-p-phenylenediamine 

l-Phenyl-5-pyrazolone-3-carboxy]ic  acid,  ethyl  ester 

Phthalamide 

Phthalic  acid 

*Phthalic  anhydride 

Phthalonitrile 

Phthaloyl  chloride . 

*2-Picoline  (alpha)...  

3-Picoline  (beta) 

4-Picoline  (gamma) 

3-  and  4-Picollae  (beta-gamma  mixture) 

*Picramic  acid  and  salt 

Picric  acid  (Trinitrophenol) 

Piperidine . 

Piperidinopropanediol 

Piperidino propyl  alcohol 

Polychlorobiphenyl. 

Primuline,  base 

Primuline  sulfonic  acid 

Proflavine,  base  (3,6-Diaminoacridine) 

Propiophenone 

Pseudocumidine 

Pyrazolone 

Pyridine,  refined 

Pyridine,  salts,  bases,  and  residues 

Quinaldine  (2-MethylquinoIine) 

Quinaldine  yellow,  base 

*Quinizarin  (1,4-Dihydroxyanthraquinone) 


304. 
171. 

127,  298. 
127,  165,  298. 


377. 

69. 

43,  69,  241,  377. 

43,  241. 

43,  69,  241,  377,  381. 


43,  298. 

43. 

43,  376. 

419. 

124. 

128. 

157. 

124,  157,  298,  X. 

124. 

351. 

48,  186,  229,  X,  X. 

501. 

171. 

11,  69,  127,  171,  304. 

127. 

69,  85,  91,  127,  171,  304,  363. 

137,  149. 

69,  413. 

91,  127,  171,  304. 

85,  91,  171. 

53. 

124. 

124,  127,  304. 

124. 

134,  157. 

74,  124,  127,  171,  304. 

134. 

I,  286,  501. 
127. 

127,  171. 

69,  127,  171,  304. 

124. 

124. 

124. 

127,  171. 

171. 

124,  127. 

171. 

13,  43,  127,  298,  304,  376: 

127. 

298. 

43,  241,  377. 

43,  241,  377. 

43,  241,  377. 

43,  241,  377. 
69,  127,  304. 
127,  304. 
127,  205,  298. 
287. 

255. 

298. 

304. 

341. 

1. 

X. 

44,  304. 
11. 

43,  241,  377. 

241. 

43,  241,  274,  304. 

304,  377. 

II,  28,  69,  85,  91,  127,  171,  193,  274, 
304,  513,  X. 


70 


UNITED    STATES   TARIFF    COMMISSION 


Table  6B. — Synthetic  organic  chemicals:   Cyclic  intermediates  for  which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


Quinoline .. 

Quinoline,  2° 

Quinolinic  acid .- 

Eesorcinol,  tech.. 

^-Resorcylic  acid 

Salicylic  acid,  tech.. 

Styphnic  acid  (2,4,6-Trinitroresoroin) 

Styphnic  acid,  lead  salt.. 

•Styrene  ( Vinylbenzene) .-- 

p-Sulfamylbenzoic  acid  (p-Carboxybenzenesulfonamide) 

Sulfanilic  acid  and  salt-.. ^ 

p-Sulfoanthranilic  acid 

o-Sulfo benzoic  anhydride 

p-Sulfo-o-benzoylbcnzoic  acid  (Sulfo  BB  acid) 

p,p'-Sulfonyldiphenol  (4,4'-Dihydroxydiphenylsulfone) 

Sulfophenyl-m-pyrazolone 

l-(o-Sulfophenyl) -5-pyrazolone-3-carboxylic  acid 

l-(p-Sulfophenyl)-5-p>Tazolone-3-carboxylic  acid  (Pyrazolone  T) 

Tetrabromo-8, 16-pyranthrenedione 

•1,4,5,8-Tetrachloroanthraquinone 

Tetrachlorobenzene 

Tetrachlorophenol,  sodium  salt 

*l,4,5,8-Tetrakis(l-anthraquinonylamino)anthraquinone    (Penta-an- 
thramide). 

3-(2)  -Thianaphthenone 

3,3'-Thiobis(7-ben?.[de]anthracen  7-one) 

p,p'-Thiobis(4-amino-o-benzenesulfonic   acid)    (Thioaniline    disul- 
fonic  acid). 

p,p'-Thiodianiline 

Thiophenylsulfonic  acid 

Tolidine  and  salts 

o-Tolidine  and  salts 

2-(o-Toloxy)pthanol  (Cresylglycol) _.. 

o-Toluenesulfonamide 

p-Toluenesulfonaraide 

p-Toluenesulfonic  acid 

Toluenesulfonic  acid,  tech 

p-Toluenesulfonic  acid,  crude 

p-Toluenesulfonic  acid,  ethyl  ester 

o-Toluenesulfonyl  chloride 

p-Toluenesulfonyl  chloride 

•a-Toluic  acid,  ethyl  ester  (Phenylacetic  acid,  ethyl  ester)  (Ethyl 
phenylacetate). 

m-Toluidine 

o-Toluidine 

•p-Toluidine __. 

Toluidine,  mixed. 

*8-(p-Toluino)-l-naphthalenesulfonic  acid  (Tolyl  peri  acid) 

m-(p-Toluino)  phenol. 

a-Tolunitrilp  (Benzyl  cyanide) 

p-Tolunitrile 

*4-(o-Toly lazo) -o-toluid ine  (o-Aminoazo toluene) _.. 

*o-(p-Tolyl)benzoic  acid 

*m-Tolylenediamine _ 

m-Tolylenediamine  sulfate _ 

m-Tolylenediaminesulfonic  acid 

Trianthraquinonyl  di-imide_. 

Tribromophenol 

•Trichlorobenzenes 

Trichlorocumcne 

Trichlorophenol,  sodium  salt 

Trichlorophenoxyethoxychloroethane       (Trichlorophenoxyethoxy- 
ethyl  chloride). 

*a-Trichlorotoluene  (Benzotrichloride) 

]  ,2,4-Trihydroxyanthraquinone 

6- Valeryl-m-cresol 

o-Vanillin  (2-Hydroxy-3-methoxybenzaldehyde) 

o-Veratraldehyde  (3,4-DimethoxybeiizaIdehyde) . 

Vinylcarbazole 

Violanthrene. . . 

Violanthrone  (Dibenzanthrone) ....; .:. 

*m-Xylene 

*Xylene,  ortho  and  para.... . ............:. 

Xylenols: 

Low  b.  p .............:....... 

High  b.  p ...:...-...-............ 

Not  classified  as  to  b.  p.. .........: 


134,  241,  377. 

43. 

91. 

127,  312,  X. 

X. 

124,  127,  201,  298. 

X. 

X. 

74,  124,  298,  515,  522,  X. 

298 

11,'69,  91,  304. 

171. 

134,  340. 

127. 

171,  X. 

85. 

351. 

11,  171. 

171. 

127,  171,  304. 

124. 

124. 

28,  127,  171,  304. 

171. 
171. 
304. 

127,  304. 

255. 

304. 

91,  127,  157. 

i;i. 

298. 

298. 

134,  157,  413. 

298. 

413. 

134,  479. 

298. 


48,  286,  501, 

127.  171,  304. 

127,  171.  304. 

127,  201,  304. 

69,  241. 

127,  171,  304. 

171. 

48,  229. 

171. 

11,91,  127,171,304. 

69,  127,  304. 

69,91,  127,  171,304. 

69,  127. 

304. 

171. 

124. 

124,  205,  298. 

205. 

124. 

124. 

201,  205,  298. 

85,  171. 

501. 

298. 

298,  398. 

171. 

171. 

69,  127,  341. 

127,  135,  278,  X. 

43,  127,  278. 

377,  381. 

377. 

43,  69,  377. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


71 


Table  6B. — Synthetic  organic  chemicals:   Cyclic  intermediates  for  which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 

Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 

Xylidincs: 

2,3-Xylidine              

304. 

*2,4-Xylidine  (m-4-Xylidrae)                                             . 

11, 127, 286,  304. 

11, 127,  304. 

'Xylidine  mixture,  original 1 

*Xylidine  mixtures,  other  (ortho  and  para) . 

91,  127,  171,  274,  304. 
69. 

304. 

304. 

2,4-Xylidinesulfonic  acid                      -     .        -_ 

304. 

127. 

304. 

4-(2,4-Xylylazo)-2,5-sylidine  (Aminoazoxylcne) 

11.  304. 
127. 

DYES 


Table  7B. — Synthetic  organic   chemicals:    Coal-tar  dyes  for  which    United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 

[Dyes  for  which  separate  stati'Jtics  are  given  in  table  7A  are  marked  below  with  an  asterisk  (*) ;  dyes  not  so 
marked  do  not  appear  in  table  7A  because  the  reported  data  are  confidential  and  may  not  be  published. 
Manufacturers  are  identified  by  numbers  in  the  alphabetical  list  appearing  in  table  22.  An  X  signifies  that 
the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number  with  the  designated 
product] 


Colour 
Index  or 
Proto- 
type 
No. 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBERS 

NitToso  Dyes 

Fast  pruiting  green -.. 

Naphthol  green  B 

NitTo  Dyes 

Naphthol  yellow  S 

Amide  yellow  E 

Azo  Dyes 

Monoazo  Dyes 

Spirit  yellow  Q 

Acid  yellow  G 

♦Spirit  yellow  R -- 

Oil  yellow -. 

*Chrysoidine  Y 

♦Chrysoidine  R 

Sudan  G 

*Sudan  I 

Croceine  orange  G -- 

*Orange  G 

Chromotrope  2R ^ 

*Fast  acid  fuchsine  B -- 

*Amido  naphthol  red  G 

Brilliant  sulphon  red 

*Chrome  yellow  2G 

*Chrome  yellow  R 

*Azo  alizarin  yellow  GP 

'Victoria  violet  4BS 

Lanafuchsine 

Chromotrope  6B 

*Amido  naphthol  red  6B 

Fast  scarlet  Q  base 

*SudanII 

*  Ponceau  R 

Double  ponceau 

*Fast  red  B 

Chromotrope  lOB 

*Chrome  brown  R 

Chrome  green  2G 

Chromate  brown  B 


171. 
69,  171. 


69,  91,  304. 

171. 


171. 

69. 

11,  69,  104,  162,  171,  304. 

11,  69,  104,  127,  162,  171,  304. 

69,  104,  127,  171,  304. 

69,  171,  304. 

104. 

11,  69,  91,  104,  127,  162,  171,  304. 

91,  304. 

69,  91,  127,  171,  304. 

304. 

11,  304,  512. 

11,  69,91,  104,  127,171,  304. 

512. 

11,69,85,91,171,274. 

11,69,91,  171. 

11,91,  171,  304. 

91,127,  171,304. 

91. 

91,  304. 

11,  69,  85,  91,  127,  171,  304. 

171. 

11,  69,  104,  162,  171,  304. 

69,  91,  127,  171,  304. 

171. 

69,  91,  171,  304. 

127. 

91,  171,  304. 

171. 

69,  85, 363. 


72 


UNITED    STATES   TARIFF    COMMISSION 


Table  7B. — Synthetic  organic  chemicals:  Coal-tar   dyes  for  which   United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Dye 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


DYES  GROUPED  BY  COLOUR  INDEX 

NUMBERS— Continued 

Azo  Dyes— Continued 
Monoazo  Dyes— Continued 

Metachrome  olive  brown  G : 

Acid  chrome  brown  R _.. 

Chrome  flavine  G 

Azoeosine  G _._ _ 

Fast  red  B  base.. 

Eosamine  G .._ 

Chrome  yellow  5G 

Direct  pink  2GN 

Direct  pink 

Direct  fast  pink  EBN 

Janus  black  B _ 

*Metanil  yellow.. 

Methyl  orange 

*Azoflavtne  RS 

*Azo  yellow 

Resorcin  yellow 

*Orange  II _" 

Hansa  rubine 

Orange  R .' '"_ I.I.I 

Pigment  rubine  B .1.1 

Lake  red  C I 

Acid  chrome  brown  B V... 

*Acid  chrome  gaj-net  R 

•Acid  chrome  violet  N 

Chrome  black  PV_ 

Acid  chrome  black  R 

Metachrome  violet  B .1 '..'.".'.../.. 

Naphthylamine  brown _ , 

•Fast  red  A 

•Azo  rubine 

•Fast  red  VR ^^^^^^^^^^^^^[^[^^[^^^^[^^^^^^[^^^^^^^^^ 

Croceine  scarlet  3BX 

•Amaranth I__ __ 

•Cochineal  red  A " 

Mordant  yellow  O... 

Chrome  yellow  RN. ...I 

•Chrome  blue  black  B .  . 

•Chrome  blue  black  R 

•Chrome  black  T 

•Chrome  black  A I 

•Fast  acid  blue  R 

•Fast  acid  blue  B IIIIIIIIIIIIIIIIIIIIIIII! 

•Acid  chrome  red  B ...I...IIII.IIIIIII.III.I! 

•Chrome  flavine  A II.  _I 

Direct  pink  2B 


Disazo  Dyes 


•Resorcin  brown.. 

•Resorcin  dark  brown 

Chrome  brown  G 

•Acid  black  lOB 

•Azo  dark  green  A 

Cloth  red  G I. 

•Brilliant  croceine  M 

Ponceau  SS  ex.. 

Cloth  red  3G  ex... 

Sudan  IV. 
•Cloth  red  B .1. 

Neutral  gray  Q 

•Milling  orange 

•Cloth  scarlet  Q 

•Direct  fast  red  8BL 
•Scarlet  EC 

Fast  acid  cyanine  d_ 

•Fast  acid  cyanine  5R  ex 

Naphthalene  acid  black  4B. 

Acid  black  B 

•Acid  chrome  black  F 


274. 

127. 

171,363. 

127, 171. 

171,  274. 

127. 

91. 

127. 

171,304  . 

127. 

171. 

127, 171, 304. 

127. 

11,91,171. 

11,171,304. 

304. 

69, 91, 104, 171, 304,  512. 

171. 

69, 127, 304. 

91, 127, 304. 

69. 

69, 304. 

91,171,304. 

91, 304, 363. 

69, 85, 171, 304. 

171. 

85. 

171. 

69, 91, 127, 171, 304. 

11,91,127,171,304. 

69, 91, 171, 304. 

91. 

91,240,304. 

69, 91, 171, 304. 

85, 171, 304. 

91,171,304. 

91,171,304. 

91, 127, 171, 304, 363. 

91, 127, 171, 304. 

91,171,304,363. 

69, 127, 171, 304. 

127, 171, 304. 

69,91,127,171,304,513. 

85, 91, 127, 171, 304, 351. 

127. 


11, 69, 91, 104, 127, 171, 304, 512. 

11, 69, 91, 104, 171, 304,  512. 

127, 304. 

11,69,91,127,171,304,512. 

91, 127, 512. 

91. 

69, 127, 171, 304. 

304. 

69. 

91, 104, 127, 162, 171. 

91,171,304. 

127. 

11,69,91,171. 

11,69,91,512. 

11,  53, 69, 85, 127, 171, 304, 351, 512,  X. 

11,171,304. 

171,  304. 

69, 127, 171, 304. 

171. 

304. 

69, 91, 127, 171, 304. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


73 


Table  7B. — Synthetic  organic  chemicals:    Coal-tar   dyes  for   which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Colour 
Index  or 
Proto- 
type 
No. 


Dye 


IManufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


302 

304 

306 

307 

308 

315 

316 

317 

319 

324 

324a 

325 

326 

327 

331 

332 

336 

343 

346 

349 

349a 

353 

364 

365 

370 

375 

376 

377 

382 

385 

387 

393 

394 

395 

400 

401 

405 

406 

409 

410 

411 

415 

419 

420 

423 

430 

431 

441 

443 

446 

448 

464 

471 

472 

477 

478 

487 

495 

499 

502 

508 

512 

515 

516 

518 

520 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBERS— 

Continued 

Azo  Dyes— Continued 

Diazo  Dyes— Continued 

*Acid  chrome  green  SS 

♦Fast  acid  black  2BN 

Fast  acid  black  F 

*Fast  acid  cyanine  black  B 

Naphthylamiue  black  D 

Brilliant  black  B 

♦Developed  blue  NA 

Developed  blue  B 

Direct  fast  heliotrope 

Developed  brilliant  orange  GR  ex 

*Rosanthrene 

*Direct  brilliant  violet 

*Direct  fast  scarlet 

Direct  fast  scarlet  4BA 

*Bismarck  brown  G 

*Bismarck  brown  R 

Acid  chrome  black  SE 

*Chrome  fast  yellow  C 

*Direct  fast  yellow  5GL 

Direct  fast  yellow  4GL  ex 

Direct  fast  yellow  RL 

*Direct  fast  pink  2BL 

♦Brilliant  yellow 

Chrysophenine  G 

Congo  red 

*Congo  corinth  G 

Congo  rubine 

Direct  orange  G 

♦Direct  scarlet  B 

Direct  violet 

♦Direct  violet  B 

Benzo  violet  O 

♦Direct  violet  N 

Direct  black  RO 

Direct  brilliant  Bordeaux  R 

♦Developed  black  BH 

Direct  cyanine  R 

♦Direct  blue  2B 

Brilliant  orange  G 

Chrysamine  G 

♦Cresotine  yellow  G 

♦Direct  orange  R 

♦Direct  fast  red  F 

♦Direct  brown  M 

Direct  brown  B 

♦Polar  red 

Acid  chrome  red 

Chrome  fast  yellow  RD 

Milling  red  G 

Direct  orange  R 

Benzopurpurine  4B 

Direct  blue  3R 

Direct  blue  4R 

♦Direct  blue  BX 

♦Direct  blue  3B 

Direct  orange  G 

♦Acid  anthracene  red  3B 

♦Benzopurpurine  lOB 

Fast  blue  B  base  and  salt 

♦Direct  azurine  G 

Direct  brilliant  blue  G 

♦Direct  blue  RW 

Direct  blue  B 

Chicago  blue  B 

♦Direct  sky  blue  FF 

♦Direct  pure  blue 


69, 127, 171. 

91, 127, 171, 304. 

171. 

69, 85, 127, 171,  304. 

171. 

171. 

91, 127, 171,  304. 

91,  127,  171,  304. 

91,  127,  171. 

127,  351. 

127,  171,  304. 

11,  171,  304. 

11,  69,  85,  91,  127,  171,  304,  X. 

91,  171. 

69,  127,  171,  304. 

69,  91,  127,  171,  304. 

171. 

69,  85,  274,  304,  351. 

69,  127,  171,  304,  X. 

85. 

85,  304. 

69,  127,  171,  304. 

69,  127,  173,  304. 

127,  171,  304. 

127,  304. 

11,  53,  69,  91,  127,  171,  304,  512. 

91,  X. 

304. 

11,  53,  69,  91,  171,  304,  512. 

91. 

69.  91,  127,  171,  304. 

171. 

11,  69,  91,  127,  171,  304. 

11. 

304. 

53,  69,  91,  127,  171,  304,  512. 

304. 

11,  69,  91,  104,  127, 171,  304,  512. 

127. 

127. 

91,  304,  512. 

91,  127,  171,  304. 

11,  53,  69,  85,  91,  127,  171,  304,  512. 

11,  53,  69,  91,  127,  171,  304,  512,  X. 

69,  512. 

69,  85,  91,  127,  171,  .304,  512,  X. 

85,  127. 

171,  351. 

11,69,91,  171. 

11,  304. 

91,  127,  304. 

127. 

91,  304. 

91,  127,  171,  304. 

11,  91,  104,  127,  304. 

11,  304. 

11,69,85,91,  171,351. 

91,  127,  304,  512. 

171,  304. 

11,  91,  127,  171,  304,  512. 

127. 

II,  91,  127,  171,  304. 
304. 

171. 

III,  53,  91,  127,  171,  304. 
153,  91,  127,  171,  304. 


74 


UNITED    STATES    TARIFF    COMMISSION 


Table  7B. — Synthetic  organic  chemicals:    Coal-tar  dyes  for  which   United   States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Colour 
Index  or 
Proto- 
type 
No. 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBERS- 
Continued 

Azo  Dyes— Continued 

Trisazo  Dyes 

Direct  fast  blue  FR 

*Directfast  black  FF 

Plutoform  black 

Diazo  blue  black  RS 

Direct  bronze  G 

♦Direct  brown  BT 

Direct  fast  blue  B 

*Direct  black  EW 

•Direct  black  RX 

•Direct  green  ET 

*Chloramine  green  B .-. 

Direct  steel  blue  G 

•Direct  green  B 

•Direct  green  G 

Direct  olive  Q 

"Direct  brown  3G0 

•Congo  brown  O 

Congo  brown  R 

Tetrakisazo  Dyes 

Direct  brown  O 

Naphthamine  fast  black  RS 

Stilbene  Dyes 

•Direct  yellow  R 

•Chloraminc  orange  Q 

•Stilbene  yellow 

Dipheny]  catechine  G 

Diphenyl  chrysoine  G 

Pyrazolone  Dyes 

•Fast  light  yellow  Q 

•Xylene  light  yellow 

•Tartrazine 

Polar  yellow 

'Chrome  red  B 

•Pyrazol  orange 

Developed  fast  yellow  2G _, 

Ketonimine  Dyes 
•Auramine 

Triphenylmelhane  and  Diphenylnaphthylmethane  Dyes 

•Malachite  green 

•Rhoduline  blue  6G 

Brilliant  green 

Setocyanine 

•Acid  green  B 

•Fast  acid  green  B 

Acid  Hght  green 

♦Acid  glaucine  blue 

'Para  fuchsine 

•Magenta  ' 

New  fuchsine 

•Methyl  violet  B  and  base 

•Crystal  violet 

Ethyl  violet 

Benzyl  violet 

Victoria  blue  4R 

Acid  magenta 

Fast  acid  violet  lOB 

•Acid  violet 

Acid  fast  violet  BO 

Alkali  blue  6B - 


11,  69,  91,  127. 

91,  127,  171,  304. 

69,  85,  91. 

127,  304. 

171. 

11.  53,  91,  127,  171,  304,  512,  X. 

127,  304. 

69,91,  127,  171,304,512. 

69,  91,  127,  171,  304.  512. 

11,  69,  91,  127,  171,  304,  512. 

91,  127,  171,  304,  512. 

127. 

11,  69,  85,  91,  127,  171,  304,  512. 

69,91,  127,  171,304,  512. 

171. 

11,  69,  91,  127,  171,  304,  512. 

11,91, 127, 171, 304,  X. 

127. 


171, 512. 

171. 


69, 91, 127, 171,  304. 

69,91,127,171,304. 

69, 127, 171. 

304. 

91. 


11, 127, 171, 304, 351. 

53,  69,  85,  91,  127,  171,  304,  351. 

11,69,171,202,304,351. 

85,91,171,351. 

69,  85, 91. 127, 171,  304. 

11,  53, 91,  304, 351,  X. 

127. 


69, 127, 274, 304. 


69, 130, 274, 304. 

127, 130, 171,  202, 304. 

69, 130, 304. 

127, 171. 

69,  91, 127, 171, 304. 

69, 127, 171,  304. 

127, 171. 

69,127,171,202,304. 

09,  312, 439. 

69, 312,  413. 

69. 

69, 127, 130, 171, 304. 

69, 127, 130, 171, 202,  304. 

127, 130, 171. 

130. 

171. 

171. 

127,  274. 

69. 91, 127, 171, 202,  304. 

274, 304. 

312. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


75 


Table  7B. — Synthetic  organic  chemicals:   Coal-tar  dyes  for  which    United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Dye 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBERS- 
Continued 

Triphenylmethane  and  Diphenylnaphthylmethane  Dyes- 
Continued 


Metbyl  blue 

Methyl  cotton  blue 

♦Soluble  blue 

Brilliant  sky  blue  5G 

Patent  blue  V 

♦Patent  blue  A 

♦Acid  chrome  azurol  B__. 

Acid  chrome  cyanine  R. 

Aurine 

♦Victoria  blue  R 

Victoria  blue  B 

•Naphthalene  green  V-— . 
♦Wool  green  S 


Xanthene  Dyes 


Rhodamine  B,  20% 

Rhodamine  B  cone,  100% 

Rhodamine  60  cone,  100% 

Fast  acid  violet  A2R 

♦Fluorescein 

Uranine  (Fluorescein,  alkali  salt) 

♦Tetrabromofluorescein 

Eosin  Q  (Tetrabromofluorescein,  alkali  salt)  - 

Erythrosine  bluish 

Phloxine 

Rose  bengale  B 


Acridine  Dyes 


Acridine  orange  NO. 

♦Phosphine 

Phosphine  2G 

Euchrysine  2G 


Quinoline  Dyes 


Quinoline  yellow,  spirit-soluble  . 

'Quinoline  yellow _. 

Quinoline  yellow  KT 


Thiazole  Dyes 

Primuline 

Direct  pure  yellow  M. 

♦Direct  fast  yellow 

ThioflavineT 

Direct  brilliant  flavine  S 


Azine  Dyes 

♦Wool  fast  blue 

♦Safranine 

Safranine  MN 

Acid  cyanine 

Induline,  spirit-soluble 

Induline,  water-soluble 

♦Nigrosine,  spirit-soluble 

♦Nigrosine,  water-soluble 


Aniline  Black  and  Allied  Dyes 


New  fast  gray. 
Fur  black 


Gallocyanine. 
New  blue  R.- 
Nile blue  A... 


Oxazine  Dyes 


171, 312. 

171, 312. 

69, 171, 439. 

171. 

171, 304. 

69, 171, 202, 304. 

91, 127, 171, 304. 

127, 171, 304. 

127. 

127, 171, 202. 

127,171,202,304. 

127,  274,  304. 

69, 127, 171. 


127. 

127. 

127. 

186. 

18, 69, 186, 202, 304. 

69,  312. 

18, 69, 202,  225, 312. 

69, 312. 

69, 312. 

312. 

69, 312. 


127, 171, 351. 

69,91,127,304,351. 

351. 

171,351. 


274. 

127, 274, 304. 

274. 


127,  304. 

127. 

91,127,171,304,341. 

127. 

341. 


91, 127, 171,  304. 
127, 171, 304. 
304. 
171. 

69,171,304. 
69, 171, 304. 
69, 171, 304. 
69, 171, 304. 


513. 
69,  304. 
171. 


697646—46- 


76 


UNITED    STATES   TARIFF    COMMISSION 


Table  7B. — Synthetic  organic   chemicals P  Coal-tar  dyes  for  which   United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Colour 
Index  or 
Proto 

type 

No. 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


922 
924 
927 
931 


971 


1027 
1033 
1034 
1035 
1040 
1053 
1054 
1060 
1062 
1063 
1073 
1075 
1076 
1078 
1080 
1085 


1095 
1096 
1097 
1098 
1099 
1101 
1102 
1104 
1106 
1109 
1113 
1114 
1118 
1120 
1128 
1132 
1135 
1150 
1151 
1152 
1161 
1162 
1163 
1167 
1170 
1173 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBERS— 
Continued 

Thiazine  dyes 

•Methylene  blue 

Methylene  green  B 

New  methylene  blue  N 

Brilliant  chrome  blue 

Sulfur  or  Sulfide  Dyes 

Derivatives  of  Carbazole 

Carbazole  vat  blue  R 

Carbazole  vat  blue  G 

Other  Sulfur  or  Sulfide  Dyes 

*Sulfur  black 

•Sulfur  blue 

*Sulfur  brown 

*Sulfur  green 

*Sulfur  maroon 

*Sulfur  olive - 

*Sulfur  tan 

*Sulfur  yellow 

*A11  other 

Anthraquinone  Dyes 

Alizarin  VI 

Alizarin  orange  AD-- 

♦Alizarin  red  S 

Alizarin  brown.. 

Alizarin  SX 

*Acid  alizarin  blue  SE 

*Acid  alizarin  blue  B 

Anthracene  blue  SWQQ 

Anthracene  blue  WR 

Anthracene  blue  SWX 

Alizarin  irisol  R 

Alizarin  astrol  B 

Cyananthrol  R 

•Alizarin  cyanine  green 

Acid  anthraquinone  violet 

•Anthraquinone  blue  black  B 

Acid  anthraquinone  sky  blue  B 

Anthraquinone  blue  SR 

Acid  alizarin  rubine 

Anthraquinone  Vat  Dyes 

•Anthraquinone  vat  yellow  GC,  \2)4%- 

•Anthraquinone  vat  golden  orange  G,  12% 

•Anthraquinone  vat  golden  orange  R,  12% 

Anthraquinone  vat  scarlet  G,  16^% 

•Anthraquinone  vat  dark  blue  BO,  25% 

Anthraquinone  vat  jade  green,  6% 

•Anthraquinone  vat  green  B  and  black  B,  12}^% 

•Anthraquinone  vat  violet  2R,  \2\i% 

•Anthraquinone  vat  blue  RS,  10% 

Anthraquinone  vat  blue  3G,  10% 

•Anthraquinone  vat  blue  GCD,  8^% 

•Anthraquinone  vat  blue  BOS,  20% 

Anthraquinone  vat  yellow  G,  12)^% 

Anthraquinone  vat  brown  B,  22%... 

Anthraquinone  vat  pink  R,  123^% 

Anthraquinone  vat  yellow  GK,  12J^% 

Anthraquinone  vat  brilliant  violet  RK,  12)^% 

•Anthraquinone  vat  olive  R,  123^% 

•Anthraquinone  vat  brown  R,  12J^% 

•Anthraquinone  vat  brown  G,  12J^%. 

Anthraquinone  vat  red  violet  RRN,  \V/2% 

Anthraquinone  vat  red  BN  extra,  ViyiVo 

Anthraquinone  vat  violet  BN,  25% 

Anthraquinone  vat  olive  G 

Anthraquinone  vat  yellow  R,  \2]4% 

Anthraquinone  vat  blue  3G,  12}^% 


69, 130, 171, 304. 

69. 

69. 

171. 


127. 
171. 


37,69,127,171,304,423. 

37,  69, 91, 127, 171, 213, 304, 423. 

37, 69, 91, 113, 127, 171, 213, 304, 423. 

37,69,127,171,213,304. 

37,69,127,117,304. 

37, 69,  91, 127, 171,  213, 304, 423. 

37,69,91,127,171,213. 

37,69,127,171,213,304,423. 

91,127,171,304. 


11,  X. 

171. 

11, 69, 171, 304. 

304, 513. 

304. 

69,127,171,304. 

28, 69,85, 91, 127, 171,  304,  513. 

28. 

85,171. 

28. 

28, 127, 513. 

127,171. 

127. 

11,  28,  69, 85, 127, 171,  304, 339,  513. 

28, 127. 

11, 69, 85, 91, 171,  274,  304, 363,  513. 

127, 171, 304. 

28. 

171. 


127,  171. 

127,  171,  304. 

127,  171,  304. 

171. 

127,  171,  304,  341. 

,  171. 

127,  171,  304,  341. 

127,  171,  304. 

127,  171. 

',  171,  304. 
127,  171,  304. 
,  171,  304. 
,304. 

il71. 

69,  127,  171,  281,304. 

127,  171,  304. 

127,  304. 

,  171,  304. 

,304. 

,  171. 

i341. 


SYNTHETIC   ORGANIC    CHEMICALS,    1944 


77 


Table  7B. — Synthetic   organic  chemicals:    Coal-tar  dyes  for  which 
production  or  sales  were  reported,  identified  by  manufacturer,  1944~ 


United  States 
-Continued 


Colour 
Index  or 

Proto- 
type 
No. 

Dye 

Manufacturers'identiflcation  num- 
bers (according  to  list  in  table  22) 

1177 

DYES  GROU 

*Indigo,  syntl 
Indigo  white 
Indigotin  lA 
Tribromindi 

♦Bromindigo 
Ciba  pink  B 

*Vat  red  3B,  i 
Vat  orange  B 
Vat  fast  scar] 

*Blue#l 

FED 

Indig 

letie, 
,  20%. 

BY  COLOUR  INDEX  NUMBERS— 
Continued 

oid  and  Thioindigoid  Byes 

20% 

124,  127,  171,  304. 

1178 

304. 

1180 

127,  304. 

1183 

?oRB 

blue  2 

20%. 

0%- 

,  20% 

124,  304. 

1184 

BD,  16% 

124,  171,  304. 

1207 

124. 

1212 

69,  124,  127,  171,  304. 

1217 

^,  10% 
etc, 

Food, 

69,  127,  171,  304. 

1228 

20% 

124. 

Drug,  and  Cosmetic  Dyes 

44,  304,  485. 

*Blue#2 

44,  240,  304,  441. 

♦Green  #1  _          .     ..      . 

44,  304,  485. 

Green  #2.   .  _ 

44,  304,  485. 

Green  #3 

485. 

*Orange  #1. 

44,  240,  304,  441,  485. 

Orange  #2 . 

304. 

*Red#l 

44,  304,  485. 

*Red#2 

44,  240,  304,  441,  485. 

*Red#3 

44,  304,  485. 

Red#4 

304,  485. 

Red  #32 . 

304. 

Yellow  #1.... 

240. 

Yellow  #3 

131,  304. 

Yellow  H 

131,  304. 

♦Yellow  #5  ... 

44,  240,  304,  441,  485. 

♦Yellow  #6 - 

44,  240,  304,  441,  485. 

Black  #1 

Drug  and  Cosmetic  Dyes 

304. 

Blue  #4.. 

304. 

Blue  #6 . 

240,  304. 

Blue#9 

304. 

Brown  #1 

304. 

Green  #1 .                                                      

304. 

Green  #5 .                            .        

304. 

Green  #6 

304. 

Green  #7  ....                                                             .  .     .- 

304. 

Orange  #3.   ._.     .     .                              . 

304. 

♦Orange  #4     ..  . 

18, 193,  240,  304. 

Orange  #5 -.. 

18. 

Orange  #8- .- 

240. 

Orange  #11 .                 

304. 

Orange  #15 

18 

Orange  #17  .- 

18. 

Red#l- 

240. 

Red  #2 

240, 304. 

Red  #3.. 

240. 

Red  #5- 

18, 240. 

Red  #6 

18. 

♦Red  #7. 

18, 193,  240,  304. 

Red  #8          .                                                   .             

18. 

Red  #9     .                                   

18. 

Red  #10     .- - 

18, 240. 

Red  #11 

18, 193,  240. 

Red  #12 

18,  240. 

Red  #13-  ..                .  . - 

18. 

Red  #14-- 

18,  X. 

Red  #18 — 

304. 

♦Red  #19 

18, 193,  240, 304. 

♦Red  #21     - 

18, 193,  225,  240. 

Red  #22 

304. 

Red  #28                                                                   

304. 

Red  #29..  .                                                           - 

X. 

Red  #30 

240. 

Red  #31 

18,  240. 

Red  #33 

304. 

Red  #34 

18, 193, 240. 

♦Red  #35.. 

18, 193, 240. 

78 


UNITED    STATES   TARIFF    COMMISSION 


Table  7B. — Synthetic  organic  chemicals:    Coal-tar  dyes  for  which   United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Colour 
Index  or 
Proto- 
type 
No. 

Dye 

Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 

DYES  GROUPED  BY  COLOUR  INDEX  NUMBERS— 
Continued 

Drug  and  Cosmetic  D2/e«— Continued 

Red  #36 - 

18. 

Red  #37  -. 

304. 

Red  #39 

338. 

Violet  #1 

18,  304. 

Yellow  #1 

240,  304. 

Yellow  #5 - 

18,  240. 

Yellow  #6.     

240. 

Yellow  #7 

240, 304. 

Yellow  #8              .                                                    ... 

304. 

Yellow  #10  -          

304. 

Yellow  #11 

304. 

Drug  and  Cosmetic  Byes,  External 
Blue  #1 

304. 

Green  #5                    .      . 

304. 

Red  #1       

304. 

Red  #3 

304. 

Red  #8 

304. 

Red  #10 

304. 

Red  #11 

304. 

Red  #13 

304. 

Yellow  #3 

18. 

Yellow  #5 

18, 

1 

DYES    GROUPED    BY    FOREIGN    PROTOTYPE 
NUMBERS 

*Acid  alizarin  flavins  R.  

69, 127, 171,  304. 

2 

Acid  anthracene  brown  B 

69. 

4 

*Aeid  anthracene  brown  PG 

11,  69,  85,  91, 127, 171, 351,  512. 

7 

Acid  chrome  blue  2R ... .  .     . 

91, 171. 

10 

Alizarin  direct  blue  A2G.. 

171. 

11 

Alizarin  direct  blue  AR 

171. 

12 

Alizarin  supra  blue  A 

127, 171. 

13 

Alkali  fast  green  lOQ                             .                             .  . 

171. 

14 

69,  85,  91, 127, 171, 304,  512. 

16 

Artificial  silk  black  G  

91,171,304,512. 

19 

Benzo  Bordeaux  6B 

11,91,171,304. 

20 

*Benzo  chrome  black  blue  B._ 

91,  127, 171, 304. 

21 

Benzo  chrome  brown  BS                      ..                              

69, 171. 

22 

Benzo  copper  blue  B       .... 

171. 

23 

171. 

24 
26 

•Benzo  fast  black  L ^ 

*Benzo  fast  blue  4GL 

11,69,91,127,171,304. 
85, 171,  351. 

27 

Benzo  fast  blue  8GL       .          ...                       ..      

351. 

28 

Benzo  fast  brown  3GL.. 

69, 171, 304. 

30 

Benzo  red  12B 

127. 

31 

Benzo  rhoduline  red  B 

127. 

33 

Brilliant  acid  blue  3B_   

11. 

35 

11,127,171. 

37 

Brilliant  mOling  blue  B   _ .  .  

127, 171. 

40 

♦Brilliant  wool  blue  FFR _. 

127,171,304. 

42 

Cellitazol  B     . 

69. 

43 

*Celliton  orange  GR 

69, 127, 171. 

45 

Celliton  red  violet  R       __        _. 

127. 

47 

*Chlorantine  fast  brown  BRL 

53, 91, 127, 304, 351,  X. 

50 

Direct  fast  red  5BL 

91. 

53 

*Chlorantine  fast  yellow  4QL 

69,91,127,351. 

54 

*Chlorantine  fast  yellow  RL          ....                .     .. 

91, 127, 357,  X. 
91. 

55 

Chrome  yellow  DS-  _  

56 

Chrome  yellow  G               .          . 

69. 

58 

Cibacete  diazo  black  B.  ..  .  .  .  ... 

91, 127,  512. 

59 

Cibacete  diazo  black  GN.  

91. 

61 

Cibacete  red  3B-. ...                ... 

127. 

62 
63 

Cibacete  sapphire  blue  G 

Cibacete  scarlet  G . 

69,91. 
69. 

64 

Cotton  black  3G        

171. 

65 
66 

Cross  dye  green  B 

Diamine  azo  Bordeaux  B 

69. 
304. 

67 

•Diamine  Bordeaux  B 

11, 171, 304,  X. 

SYNTHETIC    ORGANIC    CHEMICALS,    1944 


79 


Table  7B. — Synthetic  organic   chemicals:    Coal-tar  dyes  for  which   United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


DYES  GROUPED  BY  FOREIGN  PROTOTYPE 
NU  MBERS— Continued 


Diamine  catechLne  B 

Diamine  catechuie  G 

♦Diamine  catechine  30 

♦Diamine  fast  blue  FFB 

♦Diamine  fast  orange  EG 

♦Diamine  fast  orange  ER 

Diaminogren  blue  N2B 

♦Diazo  Bordeaux  7B 

Diazo  brilliant  green  3G 

*Diazo  brilliant  scarlet  2BL,  ex 

*Diazo  brilliant  scarlet  ROA 

Diazo  brown  OG 

Diazo  brown  NR 

Diazo  brown  3RB 

Diazo  fast  red  5BL 

Diazo  fast  red  7BL  

Diazo  indigo  blue  4GTj 

Diazo  indigo  blue  4RL 

Diazo  olive  G 

Diazo  rubine  B 

Diazo  sky  blue  B 

Diazo  sky  blue  3GL 

♦Fast  scarlet  2G  base,  salt 

Fastusol  brown  L3R 

Fastusol  gray  R 

Fastusol  orange  L5G 

Fastusol  yellow  ly5G 

♦Guinea  fast  red  BL 

Guinea  fast  red  4BL 

Helindone  fast  scarlet  B 

Helindone  fast  scarlet  G 

Helindone  pink  B  ex 

Helindone  pink  R  ex 

HelioredRMT.   

Indanthrene  brilliant  orange  RK. 
Indanthrene  brown  BR 

♦Indanthrene  brown  RRD 

♦Indanthrene  khaki  2G 

Indanthrene  rubine  R  dbl 

Indo  carbon  CL 

Indo  carbon  CLG  cone 

Indocyanine  B 

Katigen  chrome  blue  5G 

Metachrome  Bordeaux  R 

Metachromc  red  G 

Milling  orange  G 

Milling  yellow  H5G 

Milling  yellow  O 

Monochrome  blue  black  B 

Naphthol  blue  black  S 

Naphthogene  blue  B 

Neolan  black  WA 

Neolan  blue  GO 

Neolan  Bordeaux  R 

Neolan  orange  R . 

*Oxydiaminogen  OB 

Paper  red  A  ex 

Polar  orange  GS 

'Polar  orange  R 

Rapidogen  blue  BN 

♦Rapidogen  blue  D 

Rapidogen  Bordeaux  R 

Rapidogen  brown  GN 

Rapidogen  red  GS 

♦Rapidogen  red  RS 

Rapidogen  scarlet  RS 

Rapidogen  yellow  G 

♦Rosanthrene  fast  Bordeaux  2BL.. 

Rosanthrene  orange  R 

Setacyl  direct  orange  2R 

Setacyl  direct  violet  B 

Sudan  blue  G ._ 

Sudan  brown  5B .,, 


127, 304. 

11, 127, 304. 

11,  69, 127,304. 

91, 127, 171,  304. 

69,85,91,127,171. 

69, 85, 127, 171, 213. 

304. 

127,171,351. 

171. 

127,171,304,351. 

127, 171,  351. 

171. 

171. 

171,304. 

85, 127. 

85,127,351. 

171. 

171. 

171. 

171,  351. 

171. 

171. 

11,171,274,281,304,351. 

171. 

171. 

171. 

171. 

69,  85. 127, 171,  304. 

127. 

127. 

127. 

69. 

69,127,171. 

171. 

171. 

171. 

69,91,127,171,351. 

11, 127, 171,  304. 

127,171. 

171. 

171. 

171. 

171. 

85. 

513. 

11. 

11,171. 

304. 

91. 

304. 

91. 

91. 

69,85,91,171. 

91. 

91. 

11,53,171,304. 

171. 

91. 

85, 91, 127, 171,  304. 

171,  351. 

127,  171,  351. 

171,  351. 

171,  351. 

69,  171. 

127,  171,  351. 

69,  171,  351. 

127,  171. 

11,91,127,171,351. 

127,  171,  351. 

127. 

127. 

171. 

171, 


80 


UNITED    STATES   TARIFF    COMMISSION 


Table  7B. — Synthetic  organic  chemicals:    Coal-tar   dyes  for  which   United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Colour 
Index  or 

Proto- 
type 
No. 


Manufacturers'  identification  num  ■ 
bers  (according  to  list  in  table  22) 


180 
181 
182 
186 
187 


190 
191 
192 
193 
194 
195 
197 
198 
199 
201 
202 
20.3 
204 
205 
206 
207 
208 
209 
210 
211 
212 
213 
214 
216 
217 
218 
219 
220 
221 
222 
223 
224 
225 
226 
227 
228 
229 
230 
231 
232 
233 
234 
235 
236 
237 
238 
239 
240 
241 
242 
243 
244 
245 
247 
248 
249 
250 
251 
252 
255 
256 
257 
258 
259 
260 
261 


DYES  GROUPED  BY  FOREIGN  PROTOTYPE 
NUMBERS— Continued 

Sudan  orange  2R 

Sudan  orange  RT 

Sudan  red  BB 

Sulphon  orange  G _. 

*Sulphon  yellow  R 

*Supra  light  rubine  BL 

Supramine  black  BR 

Supramine  blue  R 

Supramine  Bordeaux  B 

Supramine  brown  R 

Supramine  red  3B 

Supramine  red  2G 

Supramine  yellow  R 

*Victoria  fast  violet  2R  ex 

Victoria  pure  blue  B 

Victoria  violet  RL 

♦Zambesi  black  D 

*Zambesi  black  V 

Acid  anthracene  brown  KE 

Acid  anthracene  brown  LE-CF 

Acid  anthracene  brown  WSG 

Alizarin  fast  gray  BBLW 

Alizarin  supra  sky  R 

Alphanol  brown  B 

Amido  naphthol  brown  3G 

Anthralan  red  B-CF 

Azosol  fast  orange  G 

Azosol  fast  orange  RR 

Azosol  fast  red  3B 

Azosol  fast  scarlet  CR 

Azosol  fast  yellow  GR 

Benzo  fast  Bordeaux  6BL 

Benzo  fast  brown  RL 

Benzoform  blue  BBL 

Benzo  new  blue  5B 

Pyramine  yellow  R 

Brilliant  indocyanine  6B-CF 

Brilliant  indocyanine  G 

Brilliant  sulpho  flavine  FFA,.- 

Celliton  blue  Q 

Celliton  fast  blue  B_ 

Celliton  fast  blue  FR 

Celliton  fast  blue  FFR 

Celliton  fast  blue  green  B - 

Celliton  fast  brown  3R 

Celliton  fast  brown  5R 

CeUiton  fast  navy  blue  B 

Celliton  fast  navy  blue  BR.. 

Celliton  fast  pink  B 

Celliton  fast  pink  FF3B 

Celliton  fast  red  GG 

Celliton  fast  red  violet  RN 

Celliton  fast  rubine  B 

Celliton  fast  rubine  3B 

Celliton  fast  violet  B 

Celliton  fast  violet  6B._ 

Celliton  fast  yellow  G 

Celliton  fast  yellow  RR 

*Celliton  scarlet  B 

Celliton  yellow  5G 

Chrome  fast  orange  3RL 

Diamine  orange  F 

Dianil  yellow  5G _ - 

Diazo  brown  3R 

Diazo  fast  yellow  2G 

Diazo  fast  yellow  3G 

Fast  black  B  salt 

Fast  black  K  salt 

Fast  black  LB  base 

Fast  blue  BB  base,  salt 

Fast  Bordeaux  BD  salt -- 

*Fast  Bordeaux  GP  base,  salt 

Fast  corinth  V  salt ..,,„,,,,.,. 


69. 

17L 

171. 

11,  171. 

11,  69,  91,  171,  351. 

69,  171,  304. 

11,  171. 

171. 

171. 

11. 

11,  171. 

171. 

171. 

69,  171,  304. 

171. 

91,  127. 

91,  171,  304. 

91,  127,  171,  304. 

171. 

171. 

171. 

171. 

171. 

171. 

171. 

171. 

171. 

171. 

171. 

171. 

171. 

171. 

171.. 

171. 

171. 

171. 

171. 

171. 

171. 

127, 171. 

171. 

171. 

69,  171. 

171- 

171. 

171. 

171. 

171. 

171. 

171. 

69,  171. 

171. 

171. 

171. 

171. 

171. 

127,  171. 

171. 

69,  127,  171,  512. 

171. 

171. 

171. 

171. 

171. 

171. 

171. 

171. 

171. 

171. 

171. 

171. 

11,69,  171,281,304,351. 

171. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


81 


Table  7B. — Synthetic   organic   chemicals:    Coal-tar  dyes  for  which   United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


DYES  GROUPED  BY  FOREIGN  PROTOTYPE 

NUMBERS— Continued 


Fast  garnet  GBC  base,  salt 

Fast  garnet  GC  salt 

*Fast  orange  GC  base,  salt 

Fast  orange  GR  salt 

Fast  orange  RD  salt 

Fast  red  AL  salt 

Fast  red  GL  base,  salt 

*Fast  red  SQL  salt 

*Fast  red  KB  base 

Fast  red  RC  base,  salt 

Fast  red  RL  salt 

*Fast  red  TR  base,  salt 

Fast  violet  B  base,  salt 

*Fast  yellow  GC  base,  salt 

Fastusol  orange  LGGL 

Fastusol  red  violet  LRL 

Fastusol  turquoise  blue  LGL 

Immedial  new  blue  FBLex 

Immedial  new  blue  3GL  ex 

Indanthrene  brilliant  orange  GR. 
Indanthrene  brilliant  violet  3B... 

Indanthrene  direct  black  RB 

Indanthrene  golden  orange  3G 

Indanthrene  golden  yellow  GK... 
Indanthrene  golden  yellow  RK... 

*Indanthrene  olive  green  B 

Indanthrene  red  FBB 

Monochrome  black  blue  G 

Monochrome  red  FG 

Monochrome  violet  FB 

*Naphthol  AS 

Naphthol  AS-BO 

Naphthol  AS-BR 

♦Naphthol  AS-BS 

♦Naphthol  AS-D 

Naphthol  AS-DB 

Naphthol  AS-E 

Naphthol  AS-G 

Naphthol  AS-ITR 

Naphthol  AS-OL 

♦Naphthol  AS-RL 

Naphthol  AS-SW 

♦Naphthol  AS-TR 

Neolan  orange  G 

Neolan  yellow  GR  cone 

Palatine  fast  blue  BN 

Palatine  fast  green  BLN 

Palatine  fast  marine  blue  REN... 

Palatine  fast  orange  GEN 

Palatine  fast  orange  GN 

Palatine  fast  orange  RN 

Palatine  fast  pink  BN 

Palatine  fast  red  RN 

Palatine  fast  violet  3RN 

Palatine  fast  violet  5RN 

Palatine  fast  yellow  E  LN 

Palatine  fast  yellow  GRN 

Pluto  black  G 

Rapid  fast  orange  RH 

Rapid  fast  red  FQH 

Rapid  fast  red  RH 

Rapid  fast  yellow  GGH 

Rapidogen  black  MG 

Rapidogen  blue  N 

Rapidogen  blue  R 

Rapidogen  brown  IPT 

Rapidogen  golden  yellow  R 

Rapidogen  green  B 

Rapidogen  orange  G 

Rapidogen  orange  R 

Rapidogen  red  violet  RR 

Rapidogen  violet  B 

Rapidogen  yellow  Q 


11, 171,  281. 

171. 

11,  171,  274,  281,  304. 

171,  281. 

171. 

171, 304. 

11,  69,  171. 

11,  171,  274,  281. 

11,  69,  171. 

171,  281,  304. 

171. 

11,  171,  281,  304. 

171. 

171,  274,  281. 

171. 

171. 

171. 

171. 

171. 

171. 

127,  171. 

171,  304. 

171. 

171. 

171. 

69,  127,  171,  304. 

171. 

127,  171. 

171. 

171. 

11,  69,  127,  171,  304. 

11,  171,  281,  304. 

11,  171. 

11,  69,  127,  171,  304. 

11,  69,  127,  171,  304,  351. 

171. 

171. 

11,  171. 

171. 

171,  304,  351. 

11,  171,  304. 

11,  69,  171,  304. 

11,  171,  X. 

91. 

91. 

69,  171. 

171. 

171. 

171. 

171,  304. 

171. 

171. 

171. 

171. 

171. 

171. 

171. 

171,  512. 

171. 

171. 

171. 

171. 

171. 

171. 

127,  171. 

171. 

171. 

171. 

127,  171. 

171, 

117 

171. 

171. 


82 


UNITED    STATES   TARIFF    COMMISSION 


Table  7B. — Synthetic   organic   chemicals:   Coal-tar  dyes  for  which   United  States 
production  or  sales  were  reported,  identified  by  manujacturer,  1944 — Continued 


DYES  GROUPED  BY  FOREIGN  PROTOTYPE 
NUMBERS— Continued 

Rapidogen  yellow  2G -- 

Rapidogen  yellow  GOP _ 

Solamine  blue  FFG 

Variamine  blue  BD  salt. 

Variamine  blue  RT  salt.. 

UNQROUPED  DYES 

Acetate  rayon  dyes: 
♦Black,  IV,  IV  ex.,  B,  BND,  BNF,  2G,  3G,  3GNF,  GS, 

J,  NS,  RB,  SN,SS. 
•Blue,  IV,  XII,  BB,  BGF,  BNN,  G,  2Q,  GR,  R,  3R-_. 

Bordeaux  BF,  FJA 

Brilliant  blue,  B,  B  ex.,  NR 

Brilliant  Bordeaux  3B 

Brilliant  red 

Brilliant  yellow  FFA 

Brown  B,  BR,  G,  JS,  Y... 

Developed  black  AD,  B,  BAM,  BBN,  BGD,  GFS, 
SOL. 

Developed  navy  SD 

Diazo  black,  BDN,  Q  cone,  NS... 

Direct  red  BP 

Direct  scarlet  GP 

Fast  pink  RFA 

Fast  yellow  GL,  GLF,  L3G 

Fluorescent  yellow  HEB 

Golden  orange  I,  III 

Golden  yellow  VIII,  IX,  XI,  XII,  XIII,  FSI 

OrayNBN 

Heliotrope  I --■ 

Light  orange  FSI 

Navy  blue  B,  BP,  BXN,  R 

•Orange,  BL,  GR,  GRN  cone,  JER,  R,  2R,  3R,  4R, 
RB.  TF. 

Pink  II,  B 

Pure  blue  B  ex 

Purple 

♦Red,  III,  VI  ex.,  VII,  VIII,  B,  2B,  BX,  FSI,  NB,  R, 
RP,VOL,Y. 

•Rubine  IX,  B,  C,  G,  R 

Saphirole  blue  FFG 

♦Scarlet  III,  BG,  BS,  CSB,  G,  GY 

•Violet  II,  3B,  4B,  BA,  BGF,  FSI,  2R,  4R,  3RA,  5RLF. 
♦Yellow  #8,  #38,  G,  5G,  6G,  3GM,  GN,  6GN,  GS,  GX, 
JT,  4RL,  RN. 

Acid  alizarin  Bordeaux  BLT 

Acid  anthracene  yellow  OR 

•Acid  black,  640,  773,  AR,  30,  GRF  cone,  J,  RB,  ROW 

Acid  blue  D.  R -- 

Acid  blue  black  RG 

Acid  brilliant  red  3B,  4BL 

Acid  brown  R,  R  cone,  ROO,  SF 

Acid  chrome  black  blue  G 

Acid  chrome  blue  3GNA 

Acid  chrome  brown  DKL,  RLL 

Acid  chrome  olive  BL 

Acid  chrome  yellow  ME 

Acid  dark  green  B 

Acid  fast  brown  COS 

Acid  fast  orange  LW 

Acid  fast  yellow  L 

Acid  garnet  BQ  cone 

Acid  golden  yellow  R  cone 

Acid  green  GR,  S 

Acid  leather  brown  EBR 

Acid  milling  orange  4R_ 

Acid  milling  yellow  GN 

Acid  navy  B,  FN 

Acid  navy  blue,  M4B.. 

Acid  neutral  brown  2RS 

Acid  neutral  red  3G  ex.  cone 

Acid  orange  2R 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


171. 
171. 
171. 
171. 
171. 


11,127,171,304,456,512. 

11,69,171,304,456. 

69. 

11,127,304,513. 

69. 

127. 

171. 

69, 127,  X. 

85, 127, 162. 

11. 

53, 69, 91. 

91. 

91. 

171. 

127,171,456. 

69. 

11. 

11.  • 

11. 

11. 

11. 

11, 127, 456. 

11, 69, 127, 304, 456, 512,  X. 

11, 304. 

11. 

127. 

11,127, 162, 171,  304, 456,  X. 

11,127,456,512. 

85. 

11,162,304,456,512. 

11,127,171,304,456. 

11, 69, 91, 162, 171, 304, 456. 

171. 

85. 

104, 127, 304. 

351. 

127. 

304, 351. 

53, 69, 351. 

91. 

171. 

91. 

91. 

91. 

91. 

127. 

11. 

69. 

363. 

351. 

351, 363. 

171. 

69. 

127. 

512. 

69, 127. 

127. 

11. 

351. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


83 


Table  7B. — Synthetic  organic   chemicals:    Coal-tar  dyes  for  which   United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — -Continued 


Manufacturers'  ideutification  num- 
bers (according  to  list  in  table  22) 


UNGROUPED  DYES— Continued 

Acid  pink  BA 

*Acid  red  A-lOO,  3B,  3BX,  G,  GL,  OA,  RB 

Acid  scarlet  G,  Y 

Acid  violet  RNL,  2R 

Acid  yellow  BE,  CW,  G,  3G,  GR 

Alizarin  blue  GS _ 

Alizarin  fast  blue  RB.. 

Alphazurine  B  cone 

Amido  brilliant  red  BBA 

Anthracene  blue  SWN 

Anthracene  chrome  brown  RL 

Anthraquinone  blue  BGA,  3G,  SWB,  WSA 

Anthraquibone  vat  black  2G,  J,  R 

Anthraquinone  vat  black  brown  VA 

*  Anthraquinone  vat  blue  CLX,  GR,  IBC 

Anthraquinone  vat  blue  green  B,  Y 

Anthraquinone  vat  brilliant  red  B 

Anthraquinone  vat  brilliant  yellow  4G 

Anthraquinone  vat  brown  NR,  RRD,  VR 

Anthraquinone  vat  dark  olive  B 

Anthraquinone  vat  direct  black  3G 

Anthraquinone  vat  flavine  GO. 

Anthraquinone  vat  golden  orange  YL 

Anthraquinone  vat  gray  4G,  R,  M 

•Anthraquinone  vat  navy  blue,  BN,  BRA,  NRD,  NTP 

Anthraquinone  vat  olive,  G,  GGL,  TA 

Anthraquinone  vat  olive  green  B 

Anthraquinone  vat  orange  A-lOO,  A-200 

Anthraquinone  vat  printing  violet  4R 

Anthraquinone  vat  red  brown  DBL 

Anthraquinone  vat  violet  A-lOO,  A-200 

Anthraquinone  vat  yellow  8Q,  3R 

Azoanthrene  dyes: 

Black  NV 

Golden  orange  R 

Green  G 

Navy  BR,  CW,  LN 

Royal  blue  L,  S 

Rubine  S 

Turquoise  B 

Scarlet  Y 

Yellow  Q,  GSB.  S 

Azo  Bordeaux  BL 

Azo  brilliant  orange  GRN 

Azo  brown  BY 

Azo  ceresine  B._ 

Azo  eosine  2B 

Azo  fast  blue  B 

Azo  fast  brilliant  red  BA 

Azo  fast  yellow  RCA 

Azo  oil  black 

Azo  oil  blue  black  B 

Azo  olive  green  BL 

Azo  orange  GCW,  ON,  GR  new,  RNC  #90,  3RP,  RS_ . 

Azo  scarlet  RBN 

Azoic  dyes  and  their  components: 
Dyes: 
Rapid  fast: 

BlueB 

Brown  IRH , 

Orange  O 

Orange  GNR : 

Scarlet  RH 

Rapid  ogen: 

Black  DM 

Blue  C,  G,  GDNN,  QNN,  MSG 

Bordeaux  MR . 

Brown 

Dark  brown  AR,  R 

Golden  yellow  MRS,  N 

Navy  blue  FFR 

Orange  FFR 

Red  FFBB,  FFG,  FFR,  G,  GNN,  IP,  ITR 

Scarlet,  FFG,  FFR,  R,  RBY 

Yellow,  FFG G... 


91. 

53, 91, 127, 351. 

351. 

363, 512. 

91,304,351. 

304. 

304. 

304. 

171. 

304. 

513. 

127. 

69,  304. 

171. 

127, 171, 304. 

127, 304. 

127. 

127. 

11,127,304. 

11. 

127. 

304. 

127. 

69,304. 

11,09,127,171. 

127, 171. 

11. 

127. 

11. 

11. 

127. 

127. 

X. 
X. 
X. 

X. 

X. 

X. 

X. 

X. 

X. 

351. 

351. 

351. 

69. 

127. 

304. 

171. 

171. 

304. 

304. 

351. 

351. 

351. 


171. 

171. 

351. 

69. 

171. 

127. 

127,351. 

127. 

351. 

127, 171. 

127,351. 

171. 

171. 

127, 171, 351. 

127,171,^51. 

171,351. 


84 


UNITED    STATES   TARIFF    COMMISSION 


Table  7B. — Synthetic   organic  chemicals:    Coal-tar   dyes  for  which   United  States 
production  or  sales  were  reported,  identified  by  mamifacturer ,  1944 — Continued 


Colour 
Index  or 
Proto- 
type 
No. 


Dye 


Manufacturers*  identification  num- 
bers (according  to  list  in  table  22) 


UNQROUPED  DYES— Continued 

Azoic  dyes  and  their  components— Continued 
Components: 
Fast  color  bases: 

Ponceau  L 

Red,  B,  PDC 

Scarlet  GG,  RC --. 

Fast  color  salts: 

BlueB - --- 

Ponceau  L 

Red  B,  G,  2G,  3G 

Scarlet  R 

Fur  dyes: 

Nyanzol  NZA.  NZDA,  NZDP,  NZF 

Nyanzol  berry  blue --- 

Nyanzol  fusion  #W387 

Nyanzol  gray  #G02A,  BCA 

Naphthols: 

AS-BG 

AS-GR 

AS-OP 

AS-PN 

Benzoform  dyes: 

Blue  GGAex.,  GS 

Blue  green  BA 

Brown  L3RA-- -  - 

Gray  M.  _ 

Red7B,  G 

Rubine  BA. 

Violet  BB 

Benzol  brown  R. 

Brilliant  acid  blue  3B 

Brilliant  benzo  green  BA,  BACF 

Brilliant  blue  5B 

Brilliant  wool  blue  G  ex.,  N 

Chromate  brilliant  brown  RL 

Chromate  brown 

Chrome  black  FA  ex.,  3G 

Chrome  blue  ATX 

Chrome  brilliant  orange  2R 

Chrome  brown  2AB,  B,  DK,  HN,  O,  PD,  PG 

Chrome  fast  black  SG 

Chrome  fast  green  SP 

Chrome  fast  red  2RL 

Chrome  fast  yellow  R. 

Chrome  green  B,  CB,  G 

Chrome  orange,  RL,  3R 

Chrome  red  G 

*Chrome  yellow  FTL,  2G,  2GN,  SSN,  SW 

CibablueBR 

Cloth  red  Y._ 

Cotton  black  3G 

Croceine  scarlet  FP-- 

Developed  black  G 

Developed  blue  B,  3G,  6G,  5GL 

'Developed  Bordeaux  7B,  2BL 

Developed  brilliant  orange  GRS 

Developed  brilliant  scarlet  2BL,  GL 

Developed  brown  R 

Developed  fast  Bordeaux  2BL 

Developed  fast  brown  RK 

Developed  fast  violet  BL 

Developed  fast  yellow  2Q 

Developed  green  BL,  2GL,  GW 

Developed  indigo  blue  BRRA. 

Developed  orange  DD,  GRN,  2R,  3R,  RFW,  WD 

♦Developed  red  2B,  BFW,  7BL 

Developed  rubine  B - 

Developed  scarlet  A,  2BLN,  FW,  GFW,  N 

Developed  violet  BRD,  RR 

Diaminogen  NAA 

Diazophen  red  BTB 

Diazophen  yellow  BTB 

♦Direct  black  CAM,  CW,  3G,  5G,  NCW^ 

♦Direct  blue  2B,  BR,  FFGL,  5G,  KHB,  NR,  RDW,  VRS 
Direct  blue  green  B,  CW 


11. 

11,171,281. 

11,171,274,281. 

11,171,281,351. 
11. 

171,274.281,304,351. 
11,171,274,281,304. 

85. 
85. 
85. 
85. 

11,171. 
171. 
351. 
60. 

171. 

171. 

171. 

171. 

171. 

171. 

171. 

104. 

304. 

171. 

304. 

304. 

85. 

513. 

304. 

127. 

11. 

91,  127,  304. 

171. 

513. 

127. 

127. 

91,  304. 

127,  304. 

304. 

85,127,171,304. 

124. 

91. 

512. 

304. 

91 

91,  127. 

11,  85,  304. 

85. 

85. 

127. 

85. 

127. 

127. 

304. 

127. 

171. 

11,  127,  171.  304. 

11,91,127,304. 

85. 

11,  127. 

11,  127. 

171. 

69. 

69. 

91,  171,  304,  512,  X. 

11,  53,  69,  85,  304. 

11.  304. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


85 


Table  7B. — Synthetic   organic  chemicals:    Coal-tar   dyes  Jor  which   United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Colour 
Index  or 

Proto- 
type 
No. 


Manufacturers'  identiflcationnum- 
bers  (accordinglto  list  in  table  22) 


UNGROUPED  DYES— Continued 

Direct  Bordeaux  B 

Direct  brilliant  blue  BFL 

Direct  brilliant  cerise 

Direct  brilliant  orange  RS 

Dii'ect  brilliant  red  12B 

♦Direct  brilliant  violet  B,  4B,  R 

Direct  brilliant  yellow  8G 

^Direct  brown  BGA/CF,  C  WR/GB,  GKA,  G2R,3GS,  KRS 
N,  R,  RB,  RBA. 

Direct  copper  blue  RRX 

Direct  fast  black  AM,  FOR,  FTC,  G,  PG 

♦Direct  fast  blue  6GKS,  GL,  8GL,  R,  RL,  SRL 

Direct  fast  Bordeaux  2B 

♦Direct  fast  brown  BRL,  FW,  4GL,  LBRSA,  R,  4R,  2RL, 

3YL. 
Direct  fast  catechine  GA 

♦Direct  fast  gray  BL,  GL,  2GL,  LVGLA,  LVL,  RLN 

Direct  fast  olive  brown  RL 

♦Direct  fast  orange  G,  2G,  4G,  GL,  2GL,  R,  4RL,  5RL,  2RN, 

RT. 
Direct  fast  pink  2B 

♦Direct  fast  red,  3BL,  8BLN,  8BLSW 

Direct  fast  rubine  B,  LB 

Direct  fast  scarlet  G 

Direct  fast  violet  5BL,  BRL 

Direct  fast  yellow  4GL,  5GL,  LRA 

Direct  golden  yellow  R 

Direct  gray  BBC 

Direct  green  B,  GB,  5GSC,  2Y 

Direct  light  yellow  RL 

Direct  navy  G,  R 

♦Direct  navy  blue  B,  DB,  RY 

Direct  neutral  blue  G 

Direct  new  blue  5B 

Direct  orange  BA 

Direct  red  G,  R 

Direct  rhoduline  BA/CF 

Direct  rubine  G 

Direct  scarlet  G 

Direct  silk  blue  NR 

Direct  speck  dye  red  SW 

Direct  violet  2R 

Direct  violet  black 

Direct  viscose  blue  GGS,  GS,  RS . 

Direct  yellow  S3G,  S5GP-. 

Fast  acid  brown  RG 

Fast  acid  light  red  B 

Fast  acid  orange  RW 

Fast  acid  red  BBLA 

Fast  acid  yellow  GS 

Fast  black  G 

Fast  Bordeaux  BN 

Fast  brown  FN,  MF 

Fast  crimson  R 

Fast  light  red  BL,  4BA 

Fast  olive  brown  G 

Fast  orange  4RN,  YF 

Fast  pink  N 

Fast  spirit  black  R 

Fast  spirit  brown  G 

Fast  spirit  orange  R 

Fast  spirit  yellow  2R 

Fast  yellow  2G,  N 

Fluorescent  green 

Fluorescent  purple  2G 

FluorolSG - 

Formaldehyde  black  B 

Formaldehyde  fast  black  GR 

Formaldehyde  scarlet  Y 

Formalide  brown  RD 

Formalide  deep  blue  R 

Formanol  black  RW 

Gasoline  blue - . 

Gasoline  yellow  2G 

Helio  fast  rubine  4BLA 

Igenal  brown  CRTA,  ITGA,  PGMA 


304. 

304. 

69. 

91. 

304. 

11,  91,  304. 

304. 

11,69,85,91,171,304,512. 

127. 

11,  127,171.304. 

127,  304,  X. 

304. 

11,  85,  127,  171,  304,  X. 

85. 

127,  171,  304,  X. 

11. 

85,  91,  127,  304,  X. 

11. 

11,  85,  171,  X. 

127,  304. 

304. 

11.  304. 

171,  304. 

351. 

X. 

11,  69,  127,  304. 

91. 

11,  69. 

91,  127,  512. 

351. 

91. 

171. 

11. 

171. 

11. 

11. 

171. 

304. 

11. 

91. 

171. 

304. 

304. 

91. 

91. 

171. 

304. 

69. 

69. 

69. 

304. 

171,  304. 

69. 

69. 


69. 

69. 

499. 

304. 

171. 

91. 

53. 

91. 

512. 

512. 

X. 

69,  85. 

69. 

171. 

171. 


86 


UNITED    STATES   TARIFF    COMMISSION 


Table  7B. — Synthetic  organic  chemicals:   Coal-tar   dyes  for    which    United   States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Colour 
Index  or 
Proto- 
type 
No. 


Dye 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


UNQROUPED  DYES— Continued 

Indigo  vat  black : 

Indigo  vat  brown  G 

Tndigo  vat  printing  black  G 

Indigo  vat  scarlet  2QN 

Jet  black  APX 

Lake  pink  RL 

Lake  yellow  PL 

Leather  brown  5RTA 

Methyl  violet  3RA 

Milling  fast  garnet  R. 

Milling  fast  red  FF,  GD 

Milling  navy  blue  4B 

Milling  orange  Q 

Milling  red  B 

Milling  yellow  3Q.  2QCW,  NGS,  XN 

Mordant  green  SN... --- 

Naphthol  navy  blue  M 

Neutral  brown  GH 

Neutral  silk  brown  RHS,  RWA 

Neutral  silk  yellow  GGA._  

Oil  brown  #79,  #102,  D,  M,  Y 

Oil  fast  blue  R 

Oil  fast  yellow  EG 

Oil  mahogany  #51 

■Oil  orange,  #30,  MT,  2R 

Oil  pink  B 

■Oil  red,  #322,  EGN,  G,  1-1471,  N-1700,  OB,  XO,  Y-292. 

Oil  scarlet  X-9995 

Oil  soluble  azoic  yellow 

Oil  yellow,  PHW 

Palatine  fast  blue  5RNA/CF 

Paper  white  GDC 

Phosphine  PB 

Pigment  rubine  3G 

Polyform  dyes: 

Blue  BRF.  2RF 

Bordeaux  RF 

Dark  brown  3BF 

Dark  maroon  OF 

Orange  RF 

Scarlet  RF 

Yellow  GF 

Pyrazol  fast  orange  GL 

Pyrazoline  dyes: 

Black 

BlueCF 

BlueR 

Blue2RCF 

RedBLW 

Resin  brilliant  red  R 

Resin  brown  Z 

Resin  royal  blue  #51591 

Resin  sky  blue  #51590 

Resorcin  brown  RP,  2YDS 

Rosanthrene  orange 

Rubber  colors 

Silk  black  4BF . 

Spirit  soluble  blue 

Spirit  soluble  fast  black... 

Spirit  soluble  fast  blue  B 

Spirit  soluble  fast  orange  A 

Spirit  soluble  fast  red  M,  Y 

Spirit  soluble  fast  yellow  3G 

Spirit  soluble  green 

Spirit  soluble  violet 

Stilbene  orange  E36 

Sudan  corinth  B 

Sudan  dark  brown  BG 

Supranol  yellow  RA 

Toluylene  fast  brown  3GA 

Victoria  blue  BGO 

Visco  blue  RS_ 

Wool  navy  B 

Zambesi  black  BG 


124. 

304,  471. 

304. 

304. 

127. 

304. 

304. 

171. 

171. 

85. 

85. 

304. 

351. 

304,  351. 

304. 

69. 

91. 

304. 

85. 

85. 

162,  304. 

11. 

127. 

69. 

69,  104,  162,  339. 

304. 

11,  69,  104,  162,  304,  339. 

69. 

X. 

69,  339. 

171. 

171. 

69. 

171. 

127.  ■ 

127. 

127. 

127. 

127. 

127. 

127. 

91. 

351. 

351. 

351. 

351. 

351. 

304. 

304. 

304. 

304. 

69,  171. 

127. 

127. 

91. 

513. 

304. 

304. 

304. 

304. 

304. 

513. 

513. 

69. 

171. 

171. 

171. 

171. 

202. 

91. 

304. 

91. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


87 


LAKES  AND  TONERS 


Table  12B. — Synthetic  organic  chemicals:  Lakes  and  toners  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 

[Lakes  and  toners  for  which  separate  statistics  are  given  in  table  12A  are  marked  below  with  an  asterisk  (*); 
those  not  so  marked  do  not  appear  in  table  12A  because  the  reported  data  are  confidential  and  may  not 
be  published.  Manufacturers  are  identified  by  numbers  in  the  alphabetical  list  appearing  in  table  22. 
An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number  with 
the  designated  product] 


Product 


Manufacturers'  identification  numbers  (according  to 
list  in  table  22) 


LAKES  OR  LAKE  COLORS 

*Black  lakes: 

Nigrosine 

AH  other 

*Blue  lakes: 

Brilliant  wool  blue 

*Indanthrene  blue 

*Methylene  blue 

*Peacock  blue  (Patent  blue) 

Turquoise  blue 

"  Victoria  blue 

All  other . 

*Brown  lakes: 

Bismarck  brown,  tannic 

All  other 

*  Green  lakes: 

*Acid  green 

Malachite  green 

*Naphthol  green 

*  Pigment  green 

All  other 

Maroon  lakes: 

♦Alizarin  maroon 

Amaranth 

*Azo  Bordeaux 

*E[elio  fast  rubine . 

Hypernic 

Quinizarine  maroon 

All  other 

*  Orange  lakes: 

Acid  orange 

*Persian  orange 

All  other 

Red  lakes: 
*Alizarin  red 

Cochineal  lake 

*Eosine  and  phloxine 

Pigment  scarlet 

Naphthol  red 

*Rhodamine 

*Rose  and  pink  lakes 

♦Scarlet  2R 

All  other 

♦Violet  lakes: 

Acid  violet 

♦Methyl  violet 

All  other 

♦Yellow  lakes: 

Auramine 

♦Fast  light  yellow 

♦Naphthol  yellow 

Quercitron 

♦Quinoline  yellow 

♦Tartrazine 

All  other 


190. 

36,  89,  193,  240,  277,  513. 

235. 

127,  193,  212,  232. 

127,  266,  416,  446. 

3,  18,  60,  69,  71,  132,  190,  202,  204,  212,  225,  240,  252,  266, 

277,  376,  389,  413,  416,  446,  490,  513. 
46,  413. 

69,  190,  266,  277,  498. 
21,  36,  60,  89,  101,  132,  212,  277. 

240. 

36,  101,  513. 

18,  190,  212,  240,  266. 

212. 

54,  132,  193,  490. 

54,  235,  413,  498. 

36,  60,  89,  101,  127,  132,  153,  277,  463. 

46,  193,  235,  285,  513. 

71,  240,  413. 

18,  60,  127,  132,  204,  212,  232,  285,  357,  376,  413,  463,  490. 

18,  60,  101,  127,  132,  204,  212,  232,  357,  413,  463,  490. 

212. 

513. 

89,  132,  190,  498. 

190,  498. 

18,  69,  71,  76,  101,  202,  212,  225,  240,  252,  266,  277,  376,  389, 

416,  446,  490. 
21,  60,  89,  212,  235,  277,  416. 

18,  69,  127,  193,  212,  240,  277,  357,  413,  416. 

174. 

60, 69,  89,  132,  212,  277,  416,  446. 

18,  36,  60,  127,  204,  240,  277,  357,  376,  490,  513. 

69,  235. 

127,  190,  212,  277. 

21,  36,  71,  232,  277,  413,  490,  X. 

18,  21,  60,  69,  76,  89,  127,  132,  190,  212,  232.  240,  277,  413, 

463,  490,  498. 
60,  69,  127,  132,  235,  277,  413,  416. 

101,  266. 

18,  60,  69, 101, 132,  190,  240,  266,  277,  376, 413,  446. 463,  490. 

513. 
21,89,204. 

101,  277. 

18,  69,  204,  240,  266,  277,  446. 

18,  153,  204,  212,  266,  416,  446. 

127,  212. 

212,  225,  252,  266,  376,  416,  446. 

18,  69,  71, 101, 132,  202,  204,  212,  225,  240,  252,  266,  277,  376, 

416,  446. 
36,  89,  204. 


88  UNITED    STATES   TARIFF    COMMISSION 

Table  12B. — Synthetic  organic  chemicals:  Lakes  and  toners  jor  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Product 


Manufacturers'  identification  numbers  (according  to 
list  in  table  22) 


TONERS  OR  FULL-STRENGTH  COLORS 

Black  toners:  PMA  black 

•Blue  toners: 

Alkali  blue 

Dianisidine  blue 

Phthalocyanine  blue  B 

Phthalocyanine  blue  Q 

Phthalocyanine  blue  SBL 

Pigment  blue,  AVNL  and  GNL 

PMA  Peacock  blue 

*PMA  Victoria  blue 

PMA  Blue,  other... 

•PTA  Peacock  blue 

*PTA  Victoria  blue. 

•PTA  Blue,  other 

All  other 

•Brown  toners: 

Havana  brown 

PMA  Brown 

All  other 

•Green  toners: 

•PMA  Brilliant  green 

•PTA  Brilliant  green 

•Brilliant  green,  other 

•PMA  Malachite  green 

•PTA  Malachite  green 

PTMA  Malachite  green 

PMA  Green,  other 

•PTA  Green,  other 

Phthalocyanine  green 

Pigment  green 

All  other 

Maroon  toners: 

Indo  maroon 

•Lithol  maroon 

Lithosol  Bordeaux 

•orNaphthylamine  maroon 

•Toluidine  maroon 

All  other 

Orange  toners: 

Benzidine  orange 

Dianisidine  orange 

*2,4-Dinitroaniline  orange 

*o-Nitroaniline  orange. 

Vulcan  fast  orange  O 

All  other 

•Red  toners: 

*o-Chloronitroaniline  red 

p-Chloronitroaniline  red 

•Eosineand  phloxine 

Oentex  red 

Lithol  scarlet  2YLN 

•Lithol  red 

•Lithol  rubine 

Naphthanil  red 

•Para  red,  light 

•Para  red,  dark 

•Permanent  red  2B 

•PMA  Red 

•PTA  Rhodamine  B 

•PTA  Rhodamine  Y ... 

•PTA  Red,  other 

•Red  lake  C 

•Red  lakoD 

Red  lake  P 

Rubine  3G 

•Toluidine  red 

Vulcan  fast  red  B 

All  other 


463. 

69,  204,  252.  439. 

193. 

17l',  193,  204,  212,  416,  463,  490. 

490. 

171,  490. 

171. 

212  240. 

18,  71,  127,  204,  212,  240,  252,  266,  446,  463. 

60,  132,  202. 

69,  101,  153,  202,  277,  416. 

3,  69,  101,  127,  153,  193,  204,  212,  266,  277,  413,  416.  463. 

490,  513. 
60,  101,  127,  202,  266. 
21,  202. 

71. 

235. 

101. 


202,  240,  252,  416,  463. 

i9,  101,  127,  212,  277,  413,  490,  513. 

101,  266,446,490. 

,  202,  252,  416,  446. 

101.  127,  153,  204,  212. 

132,  212. 
132,  212,  413. 
,  204,  490. 
,  212,  413,  490. 


71, 
3,  ( 
21, 
153 
69, 
18. 
60, 
60, 
171 
127 
266 

193. 

18,  127,  193,  202,  212,  240,  357,  413,  463. 

498. 

212,  232,  357. 

127,  193,  212,  232,  413,  463. 

127. 

212. 

439. 

18,  127,  204,  212,  376,  413,  513. 

153,  204,  212,  232,  357,  376,  413,  446,  463,  490. 

171. 

202,  204. 

18, 132,  204,  212, 240, 376, 413, 439,  490, 498, 513. 

127,  204,  212,  490. 

69,  76, 153,  202, 225,  252, 416, 446. 

171. 

127. 

18,  69,  71, 101, 127, 153, 193,  202,  204,  212,  240,  252, 376,  389, 

413, 416, 439, 446, 463, 490, 498,  513. 
18,  60,  101,  127,  153,  193,  202,  204,  212,  232,  240,  266,  376, 

413,  416,  439, 446, 463, 490. 
127. 
18,  60,  69,  71,  127, 132,  193,  202,  204,  212,  232,  240,  252,  357, 

376,  439, 463, 490,  498,  X. 
18,  21,  60,  69,  71,  127,  132,  153,  193,  202,  204,  212,  232,  240, 

252, 357, 376, 389, 416, 439, 463,  490, 498,  X. 
127,153,171,212,416. 
101, 212, 252, 446. 

69,  71, 101, 127, 153, 204,  212,  240,  277, 413,  416, 463. 
18,  69,  71, 101, 127, 153, 193, 204, 212,  240, 277,  413,  416, 513. 
60,  69,  202, 416. 
3,  18,  69,  71,  76,  101,  127,  153,  193,  202,  204,  212,  225,  240, 

252, 376, 389, 413, 416, 439, 446.  463. 
71, 193, 212, 240,  2,^2, 376, 416,  513. 
513. 
212. 
18,  21,  69,  71, 127,  132, 153, 193,  204,  212,  232,  240,  357,  376, 

389, 413,  416,  439,  463, 490, 498,  X. 
171. 
60, 69, 101, 127, 132, 193, 212, 232, 439. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


89 


Table  12B. — Synthetic  organic  chemicals:  Lakes  and  toners  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Product 


Manufacturers'  identification  numbers  (according  to 
list  in  table  22) 


TONERS  OR  FULL-STRENGTH 
COLORS— Continued 

Violet  toners: 

•Methyl  violet,  other  than  PMA  or  PTA 

•PMA  Methyl  violet 

•PMA  Violet,  other, 

'PTA  Methyl  violet 

•PTA  Violet,  other 

All  other 

♦Yellow  toners: 

•Benzidine  yellow 

p-Chloro-o-nitroanUine  yellow 

Gentex  yellow 

•Hansa  yellow 

Lithol  yellow 

Vulcan  fast  yellow  G 

All  other 

EXTENDED  OR  REDUCED  TONERS 

Black  toners,  reduced; 

PTA  Black 

•Blue  toners,  reduced: 

Alkali  blue 

PMA  Peacock  blue - 

•PMA  Victoria  blue 

•PMA  Blue,  other 

*PTA  Peacock  blue 

PTA  Blue,  other 

•Phthalocyanine  blue  B 

•Phthalocyanine  blue  G 

Phthalocyanine  blue,  other 

All  other 

Brown  toners,  reduced: 

Pigment  khaki 

Green  toners,  reduced: 

Nitroso  green 

•PMA  Brilliant  green 

PMA  Malachite  green 

PMA  Green,  other 

•PTA  Brilliant  gi-een 

PTA  Malachite  green 

PTA  Green,  other 

Phthalocyanine  green 

Pigment  green  B 

Shamrock  green 

All  other 

•Maroon  toners,  reduced: 

a-Naphthylamine  maroon 

p-Phenetidine  maroon 

•Orange  toners,  reduced: 

o-Nitroaniline  orange 

All  other 

•Red  toners,  reduced: 

p-Chloronitroaniline  red 

Eosine  and  phloxine 

*Lithol  red 

•Lithol  rubuie 

p-Nitro-o-anisidine-naphthanil 

p-Nitro-o-toluidine-naphthanil 

•Para  red,  light 

•Para  red,  dark 

Permaton  red 

Permanent  red  2B 

Phenylmethylpyrazolone  dianisidine 

Red  lake  2B 

•Red  lake  C 

Red  lake  D 

PMA  Red 

•PTA  Rhodamine  B 

*PTA  Rhodamine  Y 

PTA  Rubine  3G 

PTA  Red,  other 

Scarlet  2YL 

•Toluidine  red 

All  other 


3, 18, 60, 101, 130, 204, 212, 252, 266, 439,  464. 
3, 71, 101, 127,  204. 212,  277, 416,  446, 490. 
60, 130, 132, 202,  240,  252,  266, 357, 376, 463. 
69, 101, 127, 193,  204, 212,  277, 416,  446, 490. 
60, 127, 153, 240,  266, 376, 413, 463. 
277, 446. 

69, 127, 193, 204, 212, 376, 413, 416. 446, 513. 

376. 

171. 

18,  71,  127,  171,  193,  202,  204,  212,  225,  240,  252,  376,  413, 

416, 446,  513. 
171. 
171. 
101, 204. 


101. 

69. 

18,  212. 

18, 101, 190,  204. 

60, 69, 101,  204. 

101,  204,  212, 416. 

60, 101, 127,  212. 

54, 101, 127, 132, 193,  204,  232,  235,  240,  318,  490, 498. 

171, 190, 490. 

235, 498. 

127, 463. 

171, 

235 

18,89,101,127,277. 

190,  204,  266. 

212. 

101,'  127,  212. 

190. 

60,  101,  127. 

127,  132,  490. 

127. 

413. 

190,  204,  232. 

54. 
490. 

54,  413,  490. 
101,  153. 

127. 

416. 

18,  60,  101,  127,  153,  190,  204,  240,  389,  416,  490. 

18,  60,  101,  127,  204,  212,  389,  416. 

127. 

127. 

18,  60,  71,  132,  204,  212,  240,  357,  490,  X. 

60,  71, 127, 132,  204, 212,  232, 240, 357, 389, 490, 498. 

69. 

127. 

127. 

127, 490. 

18,  153,  204,  240,  490. 

416. 

60,  101. 

101,  127,  416. 

54,  101,  204,  277,  416,  446. 

127. 

60,  101,  127. 

127. 

18,  54,  60, 101,  127, 132,  190,  204,  212,  240,  357,  413,  490,  X. 

69,  101,  153,  190,  204,  266,  463. 


90 


UNITED    STATES    TARIFF    COMMISSION 


Table  12B.- — Synthetic  organic  chemicals:  Lakes  and  toners  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Product 


EXTENDED  OR  REDUCED  TONERS 
Continued 

Violet  toners,  reduced: 

PMA  Methyl  violet 

*PMA  Violet,  other 

•PTA  Methyl  violet 

•PTA  Violet,  other 

Methyl  violet,  other  than  PMA  or  PTA_. 
♦Yellow  toners,  reduced: 

Benzidine  yellovi^ 

*Hansa  yellow 

All  other 

All  other 


Manufacturers'  identification  numbers  (according  to 
list  in  table  22) 


71,  153,  190,  202,  204. 
IH,  101,  446. 
127,  212. 
60,  101. 


212,  413. 

18,  54,  127,  132,  212,  235,  413. 

101. 

204,  251. 


Note.— The  abbreviations  PMA,  PTA,  and  PTMA  stand  for  phosphomolybdic  acid,  phosphotungstie 
acid,  and  phosphotungstomolybdic  acid,  respectively. 

MEDICINALS 

Table  13B. — Synthetic  organic  chemicals:    Medicinals  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 

[Medicinals  for  which  separate  statistics  are  given  in  table  13 A  are  marked  below  with  an  asteri.sk  (*);  me- 
dicinals not  so  marked  do  not  appear  in  table  13A  because  the  reported  data  are  confidential  and  may  not 
be  published.  Manufacturers  are  identified  by  numbers  in  the  alphabetical  list  appearing  in  table  22. 
An  X  signifies  "that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number 
with  thedesignatcd  product] 


Chemical 


MEDICINALS,  CYCLIC 

Benzenoid 
•Acetanilide 

Acetol  salicylate  (l-Hydroxy-2-propanone  salicylate) 

Acetophenetidm  (Phenacetin) 

2-Acetoxymercuri-4-di-isobuty  Iphenol 

*Acetyl-p-aminopheny  1  salicylate  (Phenetsal) 

Acetylarsan 

Acetylgly col  salicylate 

•N-Acetyl-4-hydroxy-m-arsanilicacid  (Acetarsone)  (Stovarsol) 

*Acetylsalicy lie  acid  (Aspirin) 

* Acetyltannic  acid  (Tannigen)  (Tannyl  acetate) 

3-Amino-4-acetoxyphenylarsonicacid 

Amino  acids,  derived  from  proteins: 

3,5-Di-iodotyrosine-.- 

dl-Phenylalanine 

1-Tyrosine 

•p-Aminobenzoic  acid  derivatives: 

n-Amylaminoethyl  p-aminobenzoate   hydrochloride    (Amylsine 
hydrochloride). 

n-Butyl  p-aminobenzoate  (Butesin) 

Di(n-butyl-p-aminobenzoate)trinitrophenol  (Butesin  picrate) 

3-Di-n-butylamiuopropyl  p-aminobenzoate  (Butacaine  baso) 

3-Di-n-butylaminopropyl  p-amiuobenzoate  hydrochloride  (Buta- 
caine hydrochloride). 
3-Di-n-butylaminopropyl   p-aminobenzoate   sulfate   (Butacame 
sulfate) . 

^-Diethylaminoethyl  p-aminobenzoate  (Procaine  base) 

0-Diethylaminoethyl  p-aminobenzoate  derivatives: 

Procaine  borate . 

♦Procaine  hydrochloride 

a-Dimethylamino-a,^-dimethylpropyl   p-aminobenzoate   hydro- 
chloride (Tutocaine  hydrochloride). 
2-Dimethylammoethyl      p-butylaminobenzoate     hydrochloride 
(Tetracaine  hydrochloride). 

•Ethyl  p-aminobenzoate  (Benzocaine)  (Anaesthesine) 

Isobutyl  p-aminobenzoate- -- 

Isobutylaminoeth  y  1  p-aminobenzoate  (Monocaine) 

Propyl  p-aminobcnzoate.  - 

p-Aminohippuric  acid 

3-Amino-4-hydroxyphenylarsine  oxide  hydrochloride  (Mapharsen). 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


94,  124,  282,  298. 

88 

124,  165,  298. 

397. 

50,  86,  157, 165,  501. 

198. 

165. 

1,  286,  501. 

45,  124,  142,  222,  298,  X. 

88, 157,  234,  244,  501. 

501. 

149. 
286. 
286. 

325. 

1. 
1. 
1. 
1. 

1. 

1,  169,  501. 

1,  406,  501. 

1,48,69,  165,  169,501,  X. 

501. 

501. 

1,  48,  165,  169,  286,  325,  405,  501. 

165. 

48. 325. 

165. 

304. 

338. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


91 


Table  13B. — Synthetic  organic  chemicals:    Medicinals  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


MEDICINALS,  CYCLIC— Continued 

Ben  zenoid — C  ontinued 

•3-Amiuo-4-hydroxyphenyldichloroarsine   hydrochloride    (Dichloro- 
phenarsine  hydrochloride) . 

4-Amino-2-methyl-l-naphthol  hydrochloride  (Synkamin) 

Arsphenamine -- 

•Benzaldehyde 

Benzochrome 

Benzoic  acid 

•Benzoic  acid  salts: 

Lithium  benzoate 

Magnesium  benzoate _- 

Benzoylethyldimethylaminoisopropanol  (Stovaine) 

Benzopyrene r. 

•Benzyl  benzoate 

Benzyl  methyl  ketone 

Benzyl  succinate 

Bismuth  araphenaminesulfonate . 

Bismuth  iodosubgallate - 

Bismuth-^-naphthol 

Bismuth  subbenzoate 

•Bismuth  subgallate ^ 

•Bisnuith  subsalicylate 

Bismuth  tetrabromopyrocatcchol 

Bismuth  tribromophenate 

m-Bromoacetophenyl  benzoate  (Keoxyn) 

tert-Butylcresol  (Cresophan).^ 

Calcium  benzyl  phthalate 

Calcium  eresolsulfonate 

Calcium  iodoxy benzoate 

p-Carbamidobenzenearsonic  acid  (Carbasone) 

Catechol  (Pyrocatechin),  resublimed ._ 

Chloromercuri-4-nitro-o-cresol 

o-Chloromercuriphenol 

Chloro  thymol 

m-Cresyl  acetate  (Cresatin) 

*dl-Desoxyephedrine,    d-desoxyephedriue    hydrochloride    (Methed- 
rine),  and  dl-desoxyephedrine  hydrochloride. 

Diacetylaminoazotoluene 

3,4'-Di(acetylamino)-4-hydroxy-2'-phenoxyacetic    acid     arsenoben- 

zene,  sodium  salt  (Solusalvarsan). 
p.p'-Diaminodiphenylsulfone-N.N'-diCdextrose  sodium  sulfonate)  - -. 

2,5-Diaminotoluene  sulfate 

1,2,5,6-Dibenzanthracene 

7-Diethylaminopropyl  cinnamate  hydrochloride  (Apothesine  hy- 
drochloride) . 

•Diethylstilbestrol. 

Diethylstilbestrol  dimethyl  ether 

Diethylstilbestrol  dipropionate 

m-Dihydroxy-di-(soc)hexylhenzene  ( Dihexylin) 

3,4-Dihydroxy-a-methylaminoacetopheiione  hydrochloride    (Keph- 
rine  hydrochloride). 

1,3-Dihydroxynaphthalene  (Naphthoresorcinol) 

2,4-Di(p-hydroxyphenyl)-3-ethylhexane  (Octafollin) 

3,4-Dihydroxy phenylethylmethylamine  CE pinine) 

0-(3,5-Di-iodo-4-hydroxyphenyl) -a-phenylpropionic  acid 

l-Dimethylamino-2-(dimethylaminomethyl)-2-butanol        benzoate 
hydrochloride  (Alypin  hydrochloride). 

dl-Dimethylaminoethanolcatechol  (Me thadren) 

Dioxyanthranol  ( Anthralin) 

Diphenylacetyldiethylaminoethanol  hydrochloride 

Diphenyleneglycolylurea  sodium 

Disodium  acetarsonate 

Disodium  hydroxymercurisalicyloxy  acetate  (Mercurosal) 

Disodium -4-sulfaminophenyl-2-azo-7-acetylamino-l-hydroxynaph- 

thalene-3,6-disulfonate. 
•Dyes,  medicinal: 

Acriviolet 

Brilliant  green 

3,6-Diaminoacridine  dihydrochloride 

3,6-Diaminoacridinp  sulfate  (Proflavine) 

3,6-Diamino-lO-methylacridine  chloride  (Acriflavine) 

Dibromohydroxymercurifluorescein,  sodium  salt  (Mercurochrome) 

Gentian  violet 

Methylene  blue 

Methyl  violet _ - 

697646—46 7 


1,338,420,501. 

338. 

121, 280,  501. 

165,  201, 457, 475. 

396. 

127,  205,  298. 

88, 198,  X. 

405. 

280. 

135. 

157, 165, 229, 278, 414,  474,  X. 

165,418. 

157, 286, 405. 

1. 

88, 198. 

286. 

286. 

269,  286,  313,  350,  426. 

269, 286,  313. 

198. 

88, 157,  286, 396,  X. 

121. 

165. 

157. 

501. 

418. 

65, 198,  255, 280. 

X. 

1. 

137. 

286. 

406. 

57,  65, 144, 234. 

137. 
501. 

338. 
134. 
135. 
338. 

1,57,65,255,426,483,  X. 

57,  243, 255. 

57,  X. 

338. 

501. 

400. 
397.  X. 
65. 
X. 
501. 

243. 
1. 

90. 

287. 
501. 
338. 
501. 


304, 
304. 
1, 269. 
1, 269, 304. 
1.304. 
88.  211. 
304. 
69, 304. 
304. 


92 


UNITED    STATES    TARIFF    COMMISSION 


Table  13B. — Synthetic  organic  chemicals:    Medicinals  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


MEDICINALS,  CYCLIC— Continued 

Ben  zenoid— Continued 

*Dyes,  medicinal— Continued 

Parafuchsine 

Scarlet  red  (Phenol  red)... 

Tetraiodophenolphthalein  and  sodium  salt 

Trypan  blue 

1-Ephedrtne,  synthetic,  and  salts 

Ephedrine,  racemic,  and  salts 

Ephedrine  derivatives: 

Ephedrine  benzoate 

Ephedrine  cinnamate 

Ephedrine  ethylmercurithiosalicylate 

pseudo-Ephedrine  hydrochloride 

Ethyl-p-diethoxydiphenylamidine  hydrochloride 

n-Ethylephedrine  hydrochloride 

Ethyliodophenylundecylate  (Pantopaque) 

Gallic  acid 

Qermanin .-. 

Ouaiacol 

Guaiacol,  liquid 

Hexamethyleneamine  acetaminosalicylic  acid  (Salihexin) 

Hexestrol  (3',4-Di-p-hydroxyphenyl-n-hexane) 

Hexylresorcinol 

Homoveratrylamine 

Hydroquinone  n-amyl  ether  (Amol) 

p-Hydroxybenzoic  acid  esters: 

n-Butyl  p-hydroxy benzoate  (Butoben) 

Ethyl  p-hydroxybenzoate 

Methyl  p-hydroxybenzoate 

Propyl  p-hydroxybenzoate 

Hydroxymercuri-4-nitro-o-cresol  anhydride 

p-Hydroxyphenylisopropylamine  hydrobromide 

o-Hydroxyphenylmercuric  chloride 

o-Iodobenzoic  acid _ 

o-Iodosobenzoic  acid 

Lithium  hippurate 

Mandelicacid 

Mandelic  acid  salts: 

Ammonium  mandelate 

Calcium  mandelate 

Sodium  mandelate 

1-Methylaminoethanol  catechol  (Epinephrine).— 

Methyl  m-amino-p-hydroxybenzoate  (Orthoform) 

3-3'-Methylenebis(4-hydroxycoumarin)  (Dicumarol) 

Monoethanolamine  mandelate 

a-Naphthol 

^-Naphthoxyacetic  acid _ 

*^-Naphthyl  benzoate 

0-Naphthyl  salicylate.- 

*Neoarsphenamine 

Neo-synephrin  hydrochloride.. 

Phenacaine  hydrochloride  (Di-(p-ethoxyphenyl)acetamidine) 

Phenolphthalein 

*Phenolsulfonic  acid  salts: 

Ammonium  phenolsulfonate 

Bismuth  phenolsulfonate 

Calcium  phenolsulfonate 

Copper  phenolsulfonate 

Sodium  phenolsulfonate 

Zinc  phenolsulfonate 

r^-Phenylisopropylamine  and  sulfate  (Amphetamine  and  sulfate)... 

Phenylmercuric  acetate 

Phenylraercuric  benzoate 

Phenylmercuric  borate 

Phenylmercuric  chloride 

Phenylmercuric  nitrate 

Phenylmercuric  salicylate 

Phenylpropanolamine  hydrochloride  (Propadrine  hydrochloride).. 

Phenyl  salicylate  (Salol) 

Propenylmethylguaethol 

Resorcinol 

Resorcinol  monoaeetate 

•Salicylic  acid 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


304. 

304. 

48,65,269,286,304. 

304. 

286. 

286. 

255. 

255. 

255. 

65. 

501. 

287. 

134. 

269. 

501. 

298. 

201. 

1. 

287,  483,  X. 

406. 

165. 

406. 

165,  201,  286. 

201. 

165,  201. 

165,  201. 

1. 

418. 

65,  137. 

134,  418. 

418. 

338. 

269, 286. 

286,  426. 

1,  269,  286. 

269,  286. 

278,  501. 

501. 

287. 

255. 

157. 

134. 

86,  157,  286. 

157,  198. 

1,  121,286,426,501. 

444. 

169,  488. 

298. 

124. 

286. 

124,  269,  286. 

269,  286. 

124,269,286. 

124,269,286. 

234,  418,  X. 

189. 

189. 

189. 

189. 

189. 

189. 

406. 

124. 

165. 

127,  X. 

134,  157,  405. 

124,  201,  286,  298. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


93 


Table  13B.— Synthetic  organic  chemicals:    Medicinals  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944~~Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


MEDICINALS,  CYCLIC- Continued 

Benzenoid— Continued 

♦Salicylic  acid  salts: 

Arnmonium  salicylate 

Calcium  salicylate 

Lithium  salicylate 

Magnesium  salicylate 

♦Sodium  salicylate 

Strontium  salicylate. 

Salicylsalicylic  acid 

Silver  arsphenamine 

Sodium  p-aminophenylarsonate 

Sodium  antimony  III  bis-catechol-2,4-disuironate  (Fuadin) 

Sodium  ethylmercurithiobenzene  sulfonate 

Sodium  ethylmercurithiosalicylate 

Sodium  o-io'dohippurate 

Sodium  methylenesulfonaminohydroxyphenyl  arsenate  (Aldarsone). 

Sodium  p-toluenesulfoachloramine  (Chloramine  T) 

Stilbamine  glucoside  (Neostam) 

♦Sulfa  drugs: 

Acetylsulfathiazole 

p-BenzylaminobenzenesuIfonamide 

Phthalylsulfathiazole 

Succinylsulfathiazole 

Su'.fa-acetamide  (N-acetylsulfanilamide) 

Sulfadiazine 

Sulfadiazine,  sodium 

Sulfaguanidine 

Sulfamerazine,  sodium 

Sulfamerazine  (2-Sulfanilamido-4-methylpyrimidine) 

♦Sulfanilamide  (p-Aminobenzenesulfonamide) 

Sulfanilamide  ascorbate 

Sulfapyridine  (2-Sulfanilamidopyridine) 

Sulfapyridine,  sodium 

♦Sulfathiazole 

Sulfathiazole  ascorbate 

♦Sulfathiazole,  sodium 

♦Sulfoarsphenamine 

4-Sulfonamido-2,4-diaminoazobenzene---- 

•Tannin  albuminate  (Tannalbin) 

Tannin-formaldehyde  (Tannoform) 

Tetrachlorophenol 

N,N,N',N'-Tetraethylphthalamide  (Neospiran) 

Thiosalicylic  acid 

Thymol 

Thymol  iodide ---- 

p-Toluenesulfondichloramine  (Dichloroamine  T) 

a-Toluic  acid  (Phenylacetic  acid) 

Trichlorophenol 

Tryparsamide 

Tyramine  ethanesulfonate.-. 

•Vitamin  K,  all  forms: 

K  (Menadione)  (2-MethyI-l,4-naphthoqninone) 

K  f(2-MethyI-l,4-naphthoquinone)diphosphoric ester,  tetra  sodium 
salt)]  (Thyloquinone). 

Ki  (2-Methyl-3-phytyl-l,4-naphthoquinone)- 

Zinc  sulfanilate 

Alicyclic  and  Heterocyclic 

Adenine  hydrochloride - -- 

Adenine  sulfate 

Adenylic  acid 

Allantoin  (S-Ureidohydantoin) 

Allylcamphoramic  acid 

•Amino  acids  derived  from  proteins: 

Histamine,  free  base 

Histamine  phosphate 

1-Histidine 

Histidine  monohydrochloride -- 

1-Hydroxyproline 

1-Proline 

dl-Tryptophane 

1-Tryptophane 

Antipyrine 

•Antipyrine  salicylate 

Atropine  amineoxide  hydrochloride 

Barbituric  acid 


88,  124,  269. 

88,  124,  269. 

88,  X. 

88,  124,  269. 

124,201,298. 

124,  269. 

286. 

501. 

65. 

501. 

255. 

255. 

269. 

1. 

298. 

65. 

298. 

286. 

298. 

298. 

69. 

69,  X. 

69,  X. 

69. 

69. 

69. 

65,  69,  94,  286,  298,  413,  501. 

157. 

69,  286. 

286. 

69,  91,  255,  286,  298,  426,  501,  X. 

157. 

69,  255,  286,  501,  X. 

1,  121,286,426,501. 

501. 

88,  157,  198,  244. 

88,  157. 

124. 

198. 

255. 

333,  X,  X. 

269,  286,  313. 

298. 

X. 

124. 

243,  286,  426. 

65. 

1,  69,  144,  170,  483. 
203,  426. 

286. 
65. 


400. 

134,  400. 
400. 

137,  399. 
157. 

338,  473. 

473. 

243,  473. 

203. 

268,  349. 

286. 

286. 

124,  286,  349,  473. 

124. 

88,  124,  157,  198,  286. 

116. 

1. 


94 


UNITED    STATES   TARIFF    COMMISSION 


Table  13B.^ — Synthetic' organic^chemicals:    Medicinals  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


MEDICINALS,  CYCLIC— Continued 

Alicyclic  and  Heterocyclic— Continued 

•Barbituric  acid  derivatives: 

5-Allyl-5-cyclopentenylharbituric  acid  and  salt  (Cyclopal)  

5-Allyl-5-isopropylbarbituric  acid  (Allurate) 

5-Allyl-5-phenylbarbituric  acid  and  salt  (Alphenal)  

Aminopyrine  diethylbarbiturate  (Veramon)  (Peralga) 

5-n-Butyl-5-ethylbarbituric  acid  (Neonal) 

5-(l-Cyclohexenyl)-5-ethylbarbituric  acid  and  salt  (Phanodorn) . .  - 

5,5-Diallylbarbituric  acid  (Dial) 

5,5-Diethylbarbituric  acid  (Barbital) 

5,5-Diethylbarbituric  acid,  sodium  salt 

5-Ethyl-5-(sec)butylbarbituric  acid  and  salt 

5-Ethyl-5-n-hexylbarbituric  acid  and  salt  (Ortal) 

6-Ethyl-5-isoamylbarbituric  acid  and  salt  (Amytal) 

5-Ethyl-5-isopropylbarbituric  acid  and  salts  (Ipral) 

5-Ethyl-5-(l-methyl-n-butyl)barbituric  acid  (Pentobarbital) 

5-Ethyl-5-(l-methyl-n-butyl)barbituric  acid,  sodium  salt 

5-Ethyl-5-(l-methyl-n-butyl)-2-thiobarbituric      acid      and      salt 
(Pentothal). 

*5-Ethyl-5-phenylbarbituric  acid  (Phenobarbital)  (Luminal) 

5-Ethyl-5-phenylbarbituric    acid,    calcium   salt    (Phenobarbital 

calcium). 
♦5-Ethyl-5-phenylbarbituric   acid,    sodium    salt    (Phenobarbital 
sodium). 

N-Methyl-5-cyclohexenyl-5-methylbarbituric  acid  and  salt 

l-Methyl-5-ethyl-5-phenylbarbituric  acid 

5-Methyl-5-phenethylbarbituric  acid  and  salt 

Methylpropylcarbinyl  allylbarbituric  acid,  sodium  salt 

Methylpropylcarbinylbarbituricacid 

*Bile  acids  and  salts: 

Bilron  (Iron  bile  salts) 

*Cholic  acid 

*Dehydrocholic  acid 

*Dehydrocholic  acid,  sodium  salt 

Desoxycholic  acid 

Desoxycholic  acid,  sodium  salt 

Mixed  bile  acids 

Another 

Bismuth  camphocarboxylate 

Bromocamphor  (mono) 

2-Butyloxycinchoninic   acid   diethylethylenediamide   and   hydro- 
chloride. 

*Cafleine  (from  theobromine) 

'Caffeine  derivatives,  natural  and  synthetic: 

•Caffeine  citrate 

Caffeine  hydrobromide 

•Caffeine  sodium  benzoate 

•Caffeine  sodium  salicylate 

Camphor,  synthetic,  U.  S.  P 

Camphoric  acid 

Camphoric  anhydride 

•Camphosulfonic  acid  and  salts 

Cinchophen  hydroiodide_ 

Desoxycorticosterone  acetate  (Cortate) 

N-Diethylaminoisopentyl-8-amuio-6-methoxyquinoline       (Plasmo- 
chin) . 

Dihydrocodeinone  bitartrate 

3,5-Di-iodo-N-methyl-4-pyridoxyl-2,6-dicarboxylic    acid,    disodium 
salt  (Neo-iopax). 

3,5-Di-iodo-4-pyridon-N-acetic  acid  diethanolamine 

4-Dimethylaminoantipyrine  (Aminopyrine) 

Emetine  hydrochloride,  synthetic 

Eserine  salicylate 

Estradiol 

Estradiol  esters: 

a-Estradiol-3-benzoate 

a-Estradiol-17-benzoate 

a-Estradio]-3,17-dipropionate 

Estrone   (Ketohydroxyestrin) 

2-Ethoxy-6,9-diaminoacridine  and  salts 

E  thyl-l-methyl-4-phenylpiperidine 

Ethyl-l-methyl-4-phenylpiperidine-4-carboxylate  (Demerol) 

Ethynyltestosterone 

Eucatropine  hydrochloride 

Hexamethylenemethyl  iodide 

Hexamethylenetetramine ,. 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


169. 

203. 

169. 

88,  234. 

1. 

501. 

90,  169. 

1,  169,  203. 

1,  203. 

X. 

338. 

255. 

255,  X. 

1,  169,  325. 

1,  48,  255,  325,  365. 

1. 

1,  48,  169,  229,  269,  286,  501. 
48. 

1,  48,  169,  255,  269,  286,  501 . 

501. 
501. 
501. 
255. 
255. 


144,  243,  278,  473,  500,  X. 

243,  270,  278,  473,  500. 

144,  473,  500. 

500. 

473. 

^444. 

,  269,  X. 


176,  282,  298,  X. 

88,  198,  269,  286,  298,  313. 

286. 

88,  198,  269,  286,  313. 

198,  269,  286. 

127,311. 

157,  390. 

157,  269. 

88,  134,  157,  198,  244. 

255. 

90,  X. 

501. 

144. 
X. 

501. 

304,501. 
286,  X. 
116,214. 
198,  X. 

X. 

198. 
X. 

77. 
501. 
278. 
501. 
X. 

396,  488. 
243. 
127,  201. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


95 


Table  13B. — Synthetic  organic  cheviicals:    Medicinals  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


MEDICINALS,  CYCLIC— Continued 

Alicyclic  and  Heterocpclic—  Continued 

•Hexamethylenetetramineanhydromethylene  citrate  (Helmitol) 

Hexamethylenetetramine  camphorate 

Hexamethylenetetramine  mandelate 

Hexamethylenetetraminemetl)  ylene  citrate 

Hexamethylenetetramine  monobromide 

Hexamethylenetetramine  mono  iodide 

Hexamethylenetetramine  tetraiodide 

Homatropine  and  salts 

Homatropine  methyl  bromide  (Novatropine) 

8-Hydroxyquinoline  derivatives: 

8-Hydroxyquinoline  (Oxyquinoline  base) 

8-Hydroxyquinoline  benzoate 

8-Hydroxyquinoline  citrate 

8-Hydroxyquinoline  hydrochloride 

8-Hydroxyquuioline  sulfate 

8-Hydroxyquinoline  sulfate,  potassium  salt 

8-Hydroxyquinoline  tannate 

8-Hydroxyquinoline-5-sulfonic  acid 

Iodochloro-8-hydroxyquinoline 

*7-Iodo-8-hydroxyquinoline-5-sulfonic  acid  (Yatren  acid)  and  salt 

lodopyrine 

Menthol  ethoxyacetate  (Coryfln) 

homo-Menthyl  salicylate 

•2-Methoxy-6-chloro-9-diethylaminopentylaminoacridine  (Quinacrine 

hydrochloride)  fAtebrin). 
/3-Methoxy-8-hydroxymercuri-propyIamide  of  camphoric  acid  and 
salts. 

Methylcholanthrene 

*p-Methylphenyloinchoninic  ethyl  ester  (Neocinchophen) 

7-(2-Methylpipcridino)  propyl  benzoate  hydrochloride 

Methyltestosterone 

♦Nikethamide  (Niacin  diethylamide) 

Nucleic  acid  (from  yeast) u 

Nucleic  acid  salts 

Papaverine  hydrochloride 

Papaverine,  synthetic 

Phenylazo-diaminopyridine  hydrochloride  (Pyridium) 

l-Phenyl-2,3-dimethyl-4-methylamino-5-pyrazolone    formaldehyde 

bisulphite  (Novaldin). 
2-Phenyl-4-quinoluiecarboxylic    acid     (Cinchophen)     (Phenylcin- 
choninic  acid). 

2-Phenylquino]ine-4-carboxylic  acid,  sodium  salt 

Piperazine  derivatives: 

Piperazine  hexahydrate  (Piperazine  hydrate) 

Piperazine  salicylate 

Piperazine  tartrate 

3-(l-Piperidy])propanediol-l,2-diphenylurethane  base   and   hydro- 
chloride (Diothane) . 

*  Progesterone 

Scopolamine  amineoxide  hydrobromide 

Sodium  d  iphenylhydantoinate  (Dilantin) 

Sulfallantoin 

Terpin  hydrate 

Testosterone 

Testosterone  esters:  Testosterone  propionate 

sym-N-Tetramethylpiperazine  di-iodide 

*Theobromine  derivatives: 

Theobromine  calcium  gluconate 

Theobromine  calcium  salicylate _._ 

Theobromine  salicylate 

Theobromine  sodium  acetate 

♦Theobromine  and  sodium  salicylate 

♦Theophylline  (1,3-Dimethylxanthine)  and  derivatives: 

Theophylline  aminoiso bu tanol 

♦Theophylline  base 

♦Theophylline  ethylenediamine  ( Amino phylline) 

Theophylline  methyl  glucamine  (Glucophylline) 

Theophylline  monoethanolamine  (Theamine) - 

Theophylline  sodium  acetate 

Theophylline  sodium  salicylate 

Tliic  acid 

♦Vitamins: 

♦Bi  (Thiamin  chloride  and  hydrochloride) 

♦B2  (Riboflavin,  for  human  consumption)  (100%) 

B2  (Riboflavin,  for  animal  and  poultry  consumption)  (100%) 


137,  157,  198,  234,  244,  501. 

234. 

372. 

157. 

198. 

198. 

355 

214',  278,  286. 

144,  390,  X. 

48,  286. 
48,  286. 
286. 
48. 
48,  286. 


48,  286. 

90. 

48,  65,  286,  501,  X. 

269. 

501. 

165. 

1,  193,  202,  255,  286,  304,  501. 

157. 

134, 135. 

1 ,  48,  69. 

255. 

90,  X. 

90,  169,  198,  234,  243,  244,  280. 

400. 

400. 

255. 

286,  313. 

372. 

501. 


48. 

280,  359. 
280,  359. 
280,  359. 
287. 

144,  180,  243,  338,  X. 

116. 

286,  501. 

399. 

127,  405. 

X. 

90,  X. 

390. 

270. 

88. 

286. 

269,  286,  313. 

88,  269,  286,  313. 

287. 

48,  169,  269. 

48,  126,  169,  243,  268,  286,  365,  X,  X. 

1. 

255. 

269,  501. 

269. 

137,  399. 

203,  286. 

13,  103,  203,  286,  350. 

13,  103,  350,  489. 


96 


UNITED    STATES    TARIFF    COMMISSION 


Table  13B. — Synthetic  organic  chemicals:    Medicinals  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


MEDICINALS,  CYCLIC— Continued 

Alkyclic  and  Heterocyclic— Continued 

•Vitamins — Continued 
*  Be  (Pyridoxine) 

*D2  (Irradiated  ergosteiol)  (Viosterol) 

Da  (Irradiated  or  activated  animal  sterol)  (Delsterol) 

E  (a-Tocoptierol) 

E  (a-Tocopherol  acetate) 

Inositol 

Inositol  hexaphosphate,  calcium  magnesium 

'Niacin  (Nicotinic  acid) 

"Niacinamide  (Nicotinic  acid  amide) 

MEDICINALS,  ACYCLIC 

Acetylcholine  bromide 

Acetylcholine  chloride 

Acetyl-/S-methylcholine  bromide. 

Acetyl-;8-methylcholine  chloride 

Amino  acids  derived  from  proteins: 

^-Alanine 

dl-a- Alanine  __    

Aminoaeetic  acid  (Glycocoll)  (Glycin) ... 

Arginine  monohydrochloride 

l(+)-Arginine  monohydrochloride 

dl- Aspartic  acid 

1-Cystine 

Cystine  hydrochloride 

l(4-)-Glutamic  acid... 

dl-Glutamic  acid 

Glutathione 

dl-Isoleucine _. 

l-Leucine 

dl-Leucine. 

d-Lysine  monohydrochloride 

dl-Lysine  monohydrochloride 

1-Ly sine  monohydrochloride 

dl-Methionine 

dl-Norleucine 

dl-Serine 

dl-Threonine 

dl- Valine 

A  myl  nitrite  (Isoamyl  nitrite) 

Auro-thioglucose  (Solgenal-^  oleoum) 

A  zochloramide 

Barium  hexose  diphosphate 

Bismuth  octyloxyacetate  (Lipo  bismol). 

Bismuth  tri-a-ethyl  caproate  (I>ipobin) 

Bromodiethylacetylcarbamide 

Bromoisovalerylurea  (Bromural) 

Cacodylic  acid  and  derivatives: 

*Cacodylic  acid 

Guaiacol  cacodylate 

Strychnine  cacodylate 

*Caeodylic  acid  salts: 

Barium  cacodylate 

Bismuth  cacodylate 

Calcium  cacodylate 

Iron  cacodylate 

Magnesium  cacodylate 

Sodium  cacodylate 

Calcium  hexose  diphosphate 

Calcium  iodobehenate '. 

*Calcium  lactophosphate 

"Calcium  levulinate 

Chloral  hydrate 

Choline  chloride 

Diallylmalonic  acid 

Disodium  methylarsonate  (Arrhenal) 

Erythrityl  tetranitrate. 

Ethyl  chaulmoograte 

Ethyl  di-iodobrassidate 

Ethylenediamine  derivatives: 

Ethylenediamine  dihydrochloride 

Ethylenediamine  di-iodide 

*Ethyl  iodide '.'. 


203. 

1,  127,  170,  177,  283,  327,  338,  426, 

429,  483,  501. 
127. 
286. 

203,  286. 
X. 

88,  90. 

43,  172,  286,  372. 
1,  169,  170,  172,  198,  243,  372. 


134,  390. 
234,  286,  390. 
286. 
286,  390. 

69,  170,  286,  338. 

286,  349. 

48,  124. 

284,  473. 

286. 

286,  304. 

349,  472. 

340,  349,  473. 

286. 

286. 

400. 

286. 

286,  349. 

286. 

473. 

286. 

286. 

286. 

286. 

286. 

286. 

286. 

134,  269,  286,  338. 
X. 

X. 
400. 
338. 
243. 
86,  501. 
50,  86. 

135,  234,  244. 
135,  234. 
198,  234.  244. 


135 
244, 
135 
135 
135 
1135 
400, 
157 


,  244. 

,  198,  234,  244,  338. 

,  234,  244. 

,  198,  234,  244,  338. 

,501. 
234,  269. 
8,  157,  165,  244,  340,  349. 

298. 
,286. 


,  234. 
',  501. 


355. 
355 
134*,  137,  269,  286. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


97 


Table  13B.^ — Synthetic  organic  chemicals:    Medicinals  for  which  United  States 
production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


MEDICINALS,  ACYCLIC— Continued 

Ethyl  mercuric  chloride 

Ethyl  morrhuate - 

Ethyl  nitrite 

Formaldehyde  sodium  sulfoxylate 

Gluconic  acid  salts: 

Calcium  gluconate 

Copper  gluconate -. 

Iron  (ferrous')  gluconate '-.. 

Manganese  gluconate 

Potassium  gluconate 

Glycerophosphoric  acid 

Glycerophosphoric  acid  salts: 

Calcium  glycerophosphate 

Iron  glycerophosphate. 

Magnesium  glycerophosphate 

Manganese  glycerophosphate 

Potassium  glycerophosphate 

Sodium  glycerophosphate 

Hexamethyldiaminoisopropanol  di-iodide 

Humic  acid  and  salts 

Iodized  fatty  acids: 

Calcium  salts  of  iodized  fatty  acids 

Iodized  castor  oO  (Riodine) 

'Iodoform 

lodomethanesulfonic  acid,  sodium  salt -.. 

n-Isovaleric  acid  salts: 

Ammonium  isovalerate.. 

Zinc  isovalerate . 

Lithium  lactate - 

Lysidine  bitartrate 

Methoxyoximercuripropylsuccmyl  urea  (Mercuhydrin) . . 

Methylenecitric  acid  and  salts— 

Methylene  iodide .-- 

*Methyl  iodide 

Morrhuic  acid,  sodium  salt 

Potassium  bismuth  saccharate 

d-Ribose 

*Silver  preparations,  colloidal: 

Silver  protein,  mild... — 

Silver  protein,  strong 

Sodium  aurothiomalate  (Myochrysine) 

Sodium  bismuth  thioglycolate  (Thiobismol) 

Sodium  ricinoleate 

Sodium  succinate 

1-Sorbose 

Sulfonethylmethane  (Trional) 

Sulfonmethane  (Snlfonal) --- 

*  Tartaric  acid  salts: 

Antimony  sodium  tartrate 

Bismuth  potassium  tartrate - 

Bismuth  sodium  tartrate 

Potassium  sodium  bismuth  tartrate  (Bismosol) 

Potassium  tartrate 

*Thiosinamine  (Allylurea) 

2,2,2-Tribromoethanol 

Tribromomethane  (Bromoform) 

*tert-Trichlorobutyl  alcohol  (Chloretone)  (Chlorobutanol) 

Urethane 

Vinethene  (Diviuyl  ether) 

'Vitamins: 

*A  acetate,  concentrate 

*A  acetate,  crystalline 

*A  alcohol  concentrate 

*C  (Ascorbic  acid) 

*C  (Ascorbic  acid,  sodium  salt)-- 

*d-Calcium  pantothenate 

*dl-Calcium  pantothenate 

*Isoaseorbic  acid 

*d-Sodium  pantothenate 


255. 

157. 

269,  286,  343. 

286. 

255,  269,  350. 

350. 

269,  350,  444. 

350. 

350. 

201,  298. 

201,298. 
201,  298. 
201,  298. 
201,  298. 
201,  298. 
201,  298. 
157,  501. 
157. 

255. 

165. 

269, 286,  313. 

501. 


149. 

222. 

165. 

243. 

157,  501. 

134,135. 

134,  137,  198,  269,  286. 

65,  157. 

57. 

400. 

201,  338,  406,  426. 

201,  501. 

286. 

338. 

222. 

269. 

400. 

269. 

269. 

65. 

1. 

198,  243. 

286. 

88 

137,  165,  269. 

501. 

124,  290. 

48,  165,  286,  338,  X, 

349,  467. 

286. 

122. 

122. 

473,  483. 
203,  350. 
157,  286. 
13,  286. 
1,  170. 
203. 
338. 


98 


UNITED    STATES   TARIFF    COMMISSION 


FLAVOR  AND  PERFUME  MATERIALS 

Table   14B. — Synthetic  organic  chemicals:  Flavor  and  perfume  materials  for  which 
United  States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 

[Flavor  and  perfume  materials  for  which  separate  statistics  are  given  in  table  14A  are  marked  below  with 
an  asterisk  (*);  those  not  so  marked  do  not  appear  in  table  14A  because  the  reported  data  are  confidential 
and  may  not  be  published.  Manufacturers  are  identified  by  numbers  in  the  alphabetical  list  appearing 
in  table  22.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification 
number  with  the  designated  product] 


Material 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


FLAVOR  AND  PERFUME  MATERIALS,  CYCLIC 

Benzenoid 

Acetophenone 

Amyl  benzoate 

*or-Amylcinnamaldehyde- 

Amyl  cinnamate 

a-Amylcinnamyl  acetate 

a-Amylcinnamyl  alcohol 

*Amyl  salicylate 

Amyl-a-toluate  (Amyl  phenylacetate) 

*Anethole 

*Anisaldehyde -' 

♦Anisole  (Methyl  phenyl  ether) 

*Anisyl  acetate 

* Anisyl  alcohol 

Anisyl  formate 

Anisylideneacetone 

Anisyl  propionate 

Benzophenone.. 

•Benzyl  acetate 

*Benzyl  alcohol 

Benzyl  butyl  phthalate 

*Benzyl  butyrate 

*Benzyl  cinnamate 

Benzyl  p-cresyl  ether 

Benzyl  ether  (Dibenzyl  ether) 

•Benzyl  formate 

Benzylideneacetone 

Benzylideneglycerol 

Benzyl  isoamyl  ether -- 

Benzyl  isobutyrate 

Benzyl  isoeugenyl  ether  (Benzyl  isoeugenol) 

Benzyl  methyl  ketone 

•Benzyl  propionate 

•Benzyl  salicylate 

Benzyl  a-toluate  (Benzyl  phenylacetate) 

Benzyl  valerate 

^-Bromostyrene 

Butyl  a-toluate  (Butyl  phenylacetate) -- 

•Ciimamaldehyde 

•  Cinnamic  acid 

•Cinnamyl  acetate 

•Cinnamy  1  alcohol 

Cinnamyl  anthranilate 

Cinnamyl  butyrate 

Cinnamyl  cinnamate 

Cinnamyl  formate 

Cinnamyl  isobutyrate _-- 

C  iimamy  1  iso  valerate 

•Cinnamyl  propionate 

Cinnamyl  valerate 

p-Cresyl  acetate 

p-Cresyl  caprylate - 

p-Cresyl  isobutyrate 

p-Cresyl  methyl  ether 

p-Cresyl  phenyl  ether 

m-Cresyl  o-toluate  (m-Cresyl  phenylacetate) 

*p-Cresyl  a-toluate  (p-Cresyl  phenylacetate) 

p-Cresyl  valerate 

Cumaldehy de  (p-Isopropylbenzaldehyde) 

Di-isopropylthymol,  hydrogenated 

3,4-Dimethoxybenzaldehyde  ( Veratraldehyde) 

2,4-Dimethylacetophenone 

Dimethy l-/3-phenethyl  acetate 

Dimethyl-/S-phenethyl  alcohol  (Dimethylbenzyl  carbinol) 

2,6-Dinitro-3-tert-butylcymene 

Diphenylmethane 

p-Ethoxybenzaldehyde 

Ethyl  anisate ■ 

•Ethyl  anthranilate,.- 


229,  X. 
X. 

229,  278,  472,  478,  X. 


282,  414,  474,  X,  X. 
X. 

311,  474,  X,  X,  X. 
165,  478,  X,  X,  X. 
165,  390,  X. 
155,  X,  X. 
165,  X,  X. 
X,  X. 


229,  278,  X. 
278,  414,  475,  X. 
278,  414,  474,  X. 

168,  278,  474,  X,  X. 
168,  278,  472,  474,  X. 

414. 

278,  472,  474,  X,  X. 

472,  475,  X. 

X. 

X,  X. 
X,  X. 

155, 168, 278,  282,  404, 472,  X,  X . 
278,  474,  X,  X. 


229,  404,  414,  475,  X. 
165,  278,  474,  X. 
278,  478,  X,  X. 
168,  278,  478,  X,  X. 

X. 


404,  X. 

X. 

168,  404,  X,  X. 

478,  X,  X. 
472. 

168,  X. 


478,  X,  X. 

474. 

X. 


278,  474. 


SYNTHETIC    ORGANIC    CHEMICALS,    19  44 


99 


Table  14B. — Synthetic  organic  chemicals:  Flavor  arid  perfume  materials  for  which 
United  States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — 
Continued 


Material 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


FLAVOR  AND  PERFUME  MATERIALS,  CYCLIC— Con. 

Bemenoid— Continued 

♦Ethyl  benzoate 

*Ethyl  cinnamate 

*Ethyl  methylphenylglycidate 

Ethyl  phenylglycidate 

•Ethyl  salicylate 

Ethyl  a-toluate  (Ethyl  phenylacetate) 

Ethylvauillin 

♦Eugenol 

Eugenyl  acetate 

Eugenyl  formate 

Eugenyl  a-toluate  (Eugenyl  phenylacetate) 

*Guaiacyl  acetate 

Hexylcinnamaldehyde 

Hydroquinone  dimethyl  ether  (Dimethyl  hydroquinone) 

Hydroquinone  monomethyl  ether 

Isobutyl  benzoate 

Isobutyl  cinnamate 

Isobutyl  salicylate 

Isobutyl  a-toluate  (Isobutyl  phenylacetate) 

*Isoeugenol 

Isoeugenyl  acetate 

Isopropyl-o-cresol  (Carvacrol) 

Isothymol,  hydrogenated 

p-Methoxyacetophenone  (Novatone) 

p-Methylacetophenone  (Methyl-p-tolyl  ketone) 

Methyl  anthranilate. 

N-Methylanthrauilic  acid  methyl  ester  (Dimethyl  anthranilate) 

p-Methyli»enzaldehyde  (p-Tolualdehyde) 

♦Methyl  benzoate 

a-Methylbeuzyl  acetate  (Styralyl  acetate) 

*a-Methylbenzyl  alcohol  (Methylphenyl  carbinol)  (Styralyl  alcohol). 

a-Methylbenzyl  propionate  (Styralyl  propionate) 

Methylcinnamaldehyde 

*Methyl  cinnamate 

p-Methyl  cresyl  ether 

*Methyl  eugenyl  ether  (Methyl  eugenol) 

*Methyl  isoeugenyl  ether 

a-Methyl-p-isopropylhydrocinnamaldehyde 

.  *  Methyl  salicylate  (Artificial  wintergreen  oil) 

Methyl-a-toluate  (Methyl  phenylacetate) 

Musk  ambrette 

Musk  ketone 

•Musk  xylene 

Phenethyl  acetate 

♦Phenethyl  alcohol  (Phenylethyl  alcohol) 

Phenethyl  anthranilate 

Phenethyl  butyrate 

Phenethyl  cinnamate 

Phenethyl  formate 

Phenethyl  isobutyrate 

Phenethyl  iso valerate 

•Phenethyl  propionate 

Phenethyl  salicylate 

Phenethyl  a-toluate  (Phenethyl  phenylacetate) 

p-Phenethylurea 

Phenethyl  valerate 

Phenylacetone 

Phenyl  benzoate 

Pheny Ipropionaldehyde  (Hydratropaldehyde) 

*3-Phenyl-l-propyl  acetate  (Hydrocinnamyl  acetate)  _ 

3-Phenyl-l-propyl  alcohol  (Hydrocinnamic  alcohol) 

Propyl  cinnamate 

Salicylaldehyde 

a-Tolualdehyde  (Phenylacetaldehyde) 

a-Tolualdehyde  dimethylacetal  (Phenylacetaldehyde  diniethylace- 
tal). 

a-Toluic  acid  (Phenylacetic  acid) 

Thymol,  hydrogenated 

T  r ichloromethy Iphenylcarbiny  1  acetate  (Rosetone) 

1 ,3,4-Trimethyl-5-tert-butyl-2,6-dinitrobenzene 

•Vanillin _. 


165,  324,  467,  X,  X. 

155,  165,  168,  278,  474,  X. 

165,  X,  X. 

165. 

124,  168,  X,  X. 

48,  168,  229,  278,  478. 

298. 

155,  262,  X,  X,  X. 

168. 

478. 

472. 

155,  478,  X. 

X. 

127,  165. 

165. 

155,  282,  X. 

155. 

X,  X. 

282,  X,  X. 

155,  X,  X,  X. 

X. 

333,  X. 

205,  X. 

165. 

165,  311,  X. 

124,  127,  278,  X. 

127,  478,  X. 

165. 

165,  205,  278,  324,  475,  X. 

167,  472,  X. 

167,  472,  X,  X. 

478. 

165. 

48,  165,  168,  278,  478. 

478. 

155,  165,  168,  X. 

155,  165,  474,  X. 

X. 

124,  201,  298. 

48,  168,  278,  474,  X. 

278,  X. 

278,  X. 

127,  278,  X. 

1,  155,  404,  472,  X,  X. 

124,  229,  472,  479,  X. 

168. 

155,  282,  X. 

155,  X. 

X,  X. 

X,  X. 

X,  X. 

155,  282,  472,  X,  X. 

X,  X. 

155,  X,  X. 

165. 

155,  404. 

167. 

X,  X. 

155,  167,  X. 

478,  X,  X. 

167,  205,  X. 

155. 

124,  127. 

167,  X. 

155,  167,  X. 

278,  X. 

205,  X. 

165. 

X. 

282,  298,  393,  X,  X. 


100 


UNITED    STATES   TARIFF    COMMISSION 


Table  14B. — Synthetic  organic  chemicals:  Flavor  and  perfume  materials  for  which 
United  States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — 
Continued 


Material 


FLAVOR  AND  PERFUME  MATERIALS,  CYCLIC— Con. 

Naphthalenoid 

Ethyl  ^-naphthyl  ether  (Nerolin) 

Methyl  0-naphthyl  ether  (Yara  yara) 

Methyl  /3-nai>hthyl  ketone 

Methyl  napht h y  1  ketone,  mixed 

/3-Naphthyl  anthranilate 


Bornyl  acetate 

Carvomenthol,  hydrogenated. 

Cedrol 

*Cedryl  acetate 

Cedrvl  formate 

♦CitraL- 


Terpenoid 


Citrapene 

Citronellal 

*Citronellol 

*Citronellyl  acetate 

Citronellyl  butyrate 

Citronellyl  formate 

Citronellyl  propionate 

Cyclogeranyl  acetate 

Dihydrocitronellol  (3,7-DimethyI-l-octanol)  _ 
Farnesol 

•Geraniol 


Geraniol,  hydrogenated 

*Geranyl  acetate 

Gcranyl  benzoate 

•Geranyl  butyrate 

*Gerauyl  formate 

Geranyl  isobutyrate 

Geranyl  isovalerate 

Geranyl  propionate 

Geranyl  a-toluate  (Geranyl  phenylacetate). 

Hexahydropseudoiouone. 

Hydroxycitronellal 

Hydroxycitronellol 

H  y droxy citronellol  dimethylacetal 

*a-Ionone 

*/3-Ionone 

*Ionone,  mixed 

Isobornyl  acetate 

Isobornyl  alcohol  (Isoborneol) 

Isopulegol 

Isopulegyl  acetate 

Isosafrol 

*Linalool,  natural 

Linalool,  synthetic 

*Linalyl  acetate 

Linalyl  anthranilate 

Linalyl  benzoate 

*Linalyl  butyrate 

Linalyl  cinnamate.- 

•Linalyl  formate 

•Linalyl  isobutyrate 

•Linalyl  propionate 

•Menthol,  synthetic,  tech 

Menthol,  synthetic,  racemie 

♦Menthol,  sj-nthetic,  U.  S.  P 

Menthone 

Menthyl  acetate 

Menthyl  anthranilate 

Metahomomenthol 

•Methylionone 

•Nerol 

Neryl  acetate 

•Rhodinol  (2,6-Dimethylocten(2)  ol) 


•Rhodinyl  acetate 

Rhodinyl  formate 

Rhodinyl  a-toluate  (Rhodinyl  phenylacetate). 
Safrol 

•Santalol 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


167,  229. 
167,  X. 
167,  X. 
167. 
155. 


155,  X. 

205. 

127,  155,  472,  478,  X. 

155,  472,  478,  X,  X. 

478. 

67,   127,  155,  168,  262,  306,  472,  X, 
X,  X. 

404. 

168,  322,  472,  474,  478. 

127,  1.55,  168,  278,  404,  472,  474,  X. 

155,  278,  472,  478,  X,  X. 

X. 

155. 

472,  X. 

478. 

404. 

478. 

127,  155,  167,  168,  278,  404,  472,  474, 
478,  X,  X. 

167. 

127,  155,  278,  404,  472,  474,  X,  X. 

149,  X,  X. 

155,  472,  478,  X. 

155,  278,  472,  478,  X. 

472. 

X. 

155,  X. 

X. 

X. 

127,  404,  472,  479,  X. 

278,  X. 

127,  168,  X. 

127,  306,  472,  X,  X. 

127,  472,  X,  X. 

127,  282,  479. 

127. 

127. 

127,  322,  X. 

127,  X. 

X  X 

155, 168,  262,  300,  472, 474,  478.  X,  X. 

278 

149^  155,  322,  472,  474,  478,  X,  X,  X. 

149,  478. 

149,  478. 

155,  168,  478,  X,  X. 

478,  X. 

155,  168,  472,  478,  X,  X. 

149,  472,  X,  X. 

155,  168,  472,  478,  X,  X. 

165,  278,  322,  X. 

X. 

278,  X. 

165,  278,  322,  478,  X, 

165,  322,  X. 

X. 

165. 

127,  282,  306,  472,  479,  X,  X. 

155,  168,  472,  474,  478,  X. 

X. 

127,  155,  165,  168,  262,  278,  472,  474, 

X,X. 
155,  167,  472,  X,  X. 
155,  X. 
478. 
333,  X. 
155,  472,  478,  X. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


101 


Table  14B. — Synthetic  organic  chemicals:  Flavor  and  perfume  materials  for  which 
United  States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — 
Continued 


Material 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


FLAVOR  AND  PERFUME  MATERIALS,  CYCLIC— Con. 


Santalyl  acetate. 

*a-Terpineol 

*^-Terpineol 

Terpin  hydrate,  tech. 

Terpinolene 

*Terpinyl  acetate 

Terpinyl  butyrate 

Terpinyl  propionate.. 

Vetivenol 

*Vetivenyl  acetate 


Terpenoid — Continued 


Heterocyclic 


♦Coumarin,  synthetic 

Hydrocoumarin 

♦Indole 

Isobutyl  quinoline 

Isopropylquinoline 

3-Methylcoumarin 

Methylhydrocoumarin.. 
*Piperonal  (Heliotropin) . 

Saccharin 

Saccharin,  sodium  salt.. 
Skatole 


FLAVOR  AND  PERFUME  MATERIALS,  ACYCLIC 

Acetal - 

*Allyl  caproate 

Allyl  enanthate  (Allyl  heptanoate) , 

Allyl  isothiocyanate  (Mustard  oil)... 

Amyl  butyrate , 

Amyl  caproate 

Amyl  caprylate - 

Amyl  formate 

Amyl  propionate , 

Amyl  valerate 

2,3-Butanedione  (Diacetyl)  (Biacetyl) 

n-Butyl  butyrate.. 

Capryl  butyrate 

1-Carbomethoxyheptine  (Methyl  heptine  carbonate) 

Cetyl  alcohol 

Decyl  acetate  (Cio) 

n-Decyl  alcohol 

*Decyl  aldehyde  (Cio). 

Di-n-butylcarbinol 

Dibutyl  sulfide 

Diethyl  succinate 

Di-n-propyl  ketone. 

Dodecyl  acetate  (C12) - 

Dodecyl  aldehyde  (C12) 

*Ethyl  butyrate 

*Ethy]  caproate 

•Ethyl  enanthate 

Ethyl  isobutyrate 

Ethyl  isovalerate 

Ethyl  laurate.. 

Ethyl  myristate 

*Ethyl  pelargonate 

*Ethyl  sebacate 

Glutamic  acid,  monosodium  salt  (Ajinomoto). 

Heptaldehyde  (C?) 

2,3-n-Heptanedione  (Acetylvaleryl) 

n-Heptanyl  acetate... 

Hexaldehyde  (Ce)... 

2,3-n-Hexanedione  (Acetyl butyryl) 

3-Hydroxy-2-butanone  (Acetoin). 

•Isoamyl  butyrate 

Isoamyl  caproate 

•Isoamyl  formate.. 

Isoamyl  isovalerate 

Isoamyl  propionate 

Isobutyl  acetate 

Isobutyl  butyrate 

Isobutyl  caproate 


168. 

311,  X,X. 


X. 


155, 

127,; 

311. 
X. 

127,: 

127,  155,  404,  474,  X,  X,  X. 

478. 

127,: 

306,' 

155, 


X. 

478,  X. 

168,  472,  478,  X,  X. 


124,  127,  282,  298. 

165. 

124,  127,  X. 

149. 

149. 

282,  X. 

165. 

X,X,  X. 

298. 

298. 

127,  149. 


168. 


155,  165,  404,  478,  X,  X,  X 

149,  165,  404. 

137,  165. 

155. 

233,  404. 

478. 

155. 

X. 

155 

48,  149,  165. 

X. 

149. 

278,  472,  X. 

322,  478,  X. 

404. 

X  X. 

404,  472,  478,  X,  X. 

404. 

478. 

404. 

404. 

168,  478. 

X,  X. 

155,  168,  324,  343,  X. 

155,  168,  324,  X. 

168,  324,  X. 

X. 

324,  X. 

X. 

404. 

155,  165,  X. 

149,  155,  X. 

17,  177,  209. 

306. 

149. 

478. 

478. 

149. 

149. 

168,  324,  343,  X. 

324,  X. 

168,  324,  X. 

168,  X. 

168,  X. 

324,  X. 

324,  X. 

X, 


102 


UNITED    STATES   TARIFF    COMMISSION 


Table  14B. — Synthetic  organic  chemicals:  Flavor  and  'perfume  materials  for  which 
United  States  production  or  sales  were  reported,  tdentified  by  manufacturer,  19JfA — 
Continued 


Material 


FLAVOR  AND  PERFUME  MATERIALS,  ACYCLIC— Con 

Isobutyl  isovalerate... - 

Isopropyl  caproate 

Isopropyl  pelargonate .- 

Methylheptenone..- 

Methyl  homo  jasmone 

Methyl  nonenoate 

*Methylnonylacetaldehyde 

Methyl  nonylinate 

Methyl  nonyl  ketone 

4-Methyl-2,3-pentanedione  (Acetylisobutyryl) 

Methyl  undecylenate 

Myristyl  alcohol 

Nonalactone 

Nonyl  acetate  (C() 

Nonyl  aldehyde  (Cb) 

Octanol-1 

n-Octyl  acetate 

n-Octyl  aldehyde  (Cg) 

n-Octyl  butyrate 

n-Octyl  isobutyrate 

2,3-n-Pentanedione  (Acetylpropionyl) 

Propylacetal 

Propyl  propionate 

•Undecalactone 

Undecyl  aldehyde  (Cn) 

Undecylenic  alcohol 

Undecylenic  aldehyde 

Undecylic  acid,  hydrogenated 

♦CHEMICALLY  MODIFIED  ESSENTIAL  OILS 

Citronella,  acetylated 

Citronella,  hydrogenated 

Citronella  oil  fraction,  acidulated 

Ethyl  oxyhydrate. 

Lemon-grass  oil,  hydrogenated 

Peppermint  oil,  synthetic 

Sassafras  oil,  hydrogenated ^ 

Ylangol 


Manufacturers'  identification  num- 
bers (accordina  to  list  in  table  22) 


X. 

155. 

155. 

168,  X. 

478. 

X. 

478,  X,  X. 

165. 

478,  X,  X. 

149. 

472,  X. 

X. 

165,478,X,X. 

478,  X. 

478,  X,  X. 

X. 

X. 

478,  X. 

404. 

X. 

149. 

X. 

155. 

155, 165, 168, 306, 477,  X,X. 

472, 478. 

478,  X. 

155,478,  X.X. 

205. 


X. 

205. 

278. 

155, 262, 474,  X. 

205. 

324. 

205. 

478. 


PLASTICS  MATERIALS 

Table    15B. — Synthetic   organic   chemicals:   Plastics   materials  for   which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  19Jf.Ii. 

[Plastics  materials  for  which  separate  statistics  are  given  in  table  15A  are  marked  below  with  an  asterisk  (*); 
products  not  so  marked  do  not  appear  in  table  15A  because  the  reported  data  are  confidential  and  may  not 
be  published.  Manufacturers  are  identified  by  numbers  in  the  -alphabetical  list  appearing  in  table  22. 
An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number  with 
the  designated  product] 


Material 


PLASTICS  MATERIALS,  CYCLIC 
Condensation  Resins,  Bemenoid 


*Alkyd  resins: 
•Saturated  polyesters  type: 
*Phthalic  anhydride-glycerol: ' 

*  For  molding  and  casting 

*For  protective  coatings 


Foradhesives 

For  textile,  paper,  and  leather  treatment 
For  miscellaneous  uses 

See  footnotes  at  end  of  table. 


Manufacturers'  identification  num- 
bers (according;  to  list  in  table  22) 


10,  39,  98,  175. 

4,  6, 13.  22,  63,  70,  71,  73, 112, 127, 138, 
150, 161, 163, 175. 178,  179,  180, 184, 
216,  221,  226,  258,  263,  291,  301,  302, 
320,  327,  337,  357,  360,  376,  379,  382, 
394,  413,  440,  445,  467,  470,  496,  507, 
X,  X,  X,  X,  X,  X,  X,  X,  J?,  X. 

175. 

10,  13,  373. 

X,  X,  X. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


103 


Table    1518.— Synthetic   organic   chemicals:   Plastics   materials  for   which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Material 


PLASTICS  MATERIALS,  CYCLIC— Continued 

Condensation  Resins,  Benzenoid— Continued 

•Alkyd  resins — Continued 
♦Saturated  polyesters  type— Continued 
Phthalic  anhydride-glycol: 

For  protective  coatings 

For  textile,  paper,  and  leather  treatment 

Phthalic  anhydride-pen taerythritol:  For  protective  coatings 

All  other,  unspecified: 

For  protective  coatings 

For  miscellaneous  uses 

♦Unsaturated  polyesters  type: 

Phthalic  anhydride-allyl  alcohol:  For  protective  coatings 

Cyclopentadiene-maleic  anhydride-alcohol: 

For  protective  coatings 

For  adhesives 

*Coal-tar  acid  resins: 
♦Phenolic  resins: 
*p-tert-Amylphenol-aldehyde: 

For  protective  coatings 

For  miscellaneous  uses 

Bis-phenol:  For  protective  coatings 

*p-tert-Butylphenol-aldehyde: 

For  protective  coatings 

For  miscellaneous  uses 

•Cresols-formaldehyde: 

For  molding  and  casting 

*For  laminating 

For  protective  coatings 

Diamylphenol  and  hexamethylene :  For  miscellaneous  uses 

Diphenylpropanol-formaldehyde:  For  protective  coatings 

♦Phenol-formaldehyde : 
♦For  molding 

For  casting 

♦For  laminating. ^ 

♦For  protective  coatings 

♦For  adhesives 

♦For  textile,  paper,  and  leather  treatment 

For  miscellaneous  uses 

♦Phenol-formaldehyde,  modified  by  abietic  acid:  For  protective 
coatings. 

♦Phenol-formaldehyde,  modified  by  abietic  acid  ester: 

For  protective  coatings 

For  textile,  paper,  and  leather  treatment 

For  miscellaneous  uses,.- 

Phenol-furfural: 

For  molding  and  casting 

For  laminating 

Resorcinol-formaldehyde: 

For  adhesives 

For  miscellaneous  uses 

Xylenol-f  ormaldehyde : 

For  molding  and  casting 

For  protective  coatings 

•Mixed  phenolic  (tar  acid)  resins: 
Cashew  nut  shell  oil: 

For  molding  and  casting 

For  laminating 

For  protective  coatings 

For  miscellaneous  uses 

♦Cresylic  acid-formaldehyde: 

For  molding  and  casting 

For  laminating 

For  protective  coatings 

For  adhesives 

For  miscellaneous  uses 

♦Cresols-  and  xylenols-aldehyde: 

For  molding  and  casting 

For  laminating 

For  protective  coatings 

For  miscellaneous  uses 

See  footnotes  at  end  of  table. 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


13. 

376. 

227,  291,  413. 

413,  X. 
X. 

156,  175. 

;39,  150. 
175. 


70,  163,  180,  413,  467,  X. 

467,  X. 

413. 

70,  200,  320,  376,  413,  467. 
467. 

476. 

39,  81,  110,  152,  175,  336,  376,  455, 

492,  X. 
39,  301,  394,  476. 
435. 
6. 

39,  84,  98,  102,  110,  129,  200,  267,  298, 

476. 
42,  81,  84,  239,  271. 
39,  81,  84,  110,   152,  219,  247,  298, 

336,  376,  382,  492,  X. 
13,  39,  70,  180,  200,  242,  337,  421,  476, 

X,  X. 
39,  80,  81,  84,  219,  246,  298,  358,  376, 

382,  476,  X. 
81,  376,  421. 

39,  84,  129,  298,  382,  X,  X. 
163,  180,  221,  242,  376,  496. 


163,  199,  376,  382,  467. 

199. 

199. 

129,  220. 
220. 

80,  X. 
129. 

110,  476. 

175,  376,  413,  476. 


129,  220. 
220. 
220. 
220. 

128. 
81,  492. 

128,  178,  X. 
81. 

128. 

128. 
129. 

129,  175,  384. 
X. 


104 


UNITED    STATES   TARIFF    COMMISSION 


Table    15B. — Synthetic   organic   chemicals:    Plastics   materials  for   which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Material 


Manufacturprs'  identification  num- 
bers (according  to  list  in  table  22) 


PLASTICS  MATERIALS,  CYCLIC— Con. 

Condensation  Resins,  Ben  zenoid— Con. 

•Coal-tar  acid  resins— Con. 
*Mixed  phenolic  (tar  acid)  resins — Con. 
Phenols-  and  cresols-aldehyde: 

For  molding  and  casting 

For  laminating 

For  protective  coatings 

For  adhesives - -- 

For  miscellaneous  uses 

Phenols-,  cresols-,  and  xylenols-formaldehyde: 

For  laminating - 

For  protective  coatings - 

Furfural-acetone  resins:  For  ion  exchange 

Organic  nitrogen  resins:  Aniline-formaldehyde: 

For  molding  and  casting. - 

For  laminating... 

Organic    sulfur    resins:  p-Toluenesulfonamide:  For  miscellaneous 
uses. 

Petroleum  condensation  resins:  For  laminating 

Styrene  polyesters: 

For  laminating 

For  protective  coatings 


Polymerization  Resins,  Bemenoid 


Petroleum  polymer  resins: 

For  protective  coatings 

For  miscellaneous  uses 

•Polyaromatic  resins: 

Coumarone-indene  resins: 

For  molding  and  casting 

For  protective  coatings 

For  adhesives 

For  miscellaneous  uses 

Cyclopentadiene:  For  protective  coatings 

Polydichlorostyrene:  For  molding  and  casting. 
•Polystyrene  resins: 

For  molding  and  casting 

For  protective  coatings 

For  adhesives 

For  glazing,  sheeting,  and  films. 

For  miscellaneous  uses 

Polyvinyl  carbazole:  For  molding  and  casting.. 
All  other,  unspecified:  For  protective  coatings 


PLASTICS  MATERIALS,  ACYCLIC  ' 

Condensation  Resins 
*Alkyd  resins: 
•Abieticacid: 

For  protective  coatings 


For  adhesives 

For  textile,  paper,  and  leather  treatment. 

For  miscellaneous  uses 

'Abietic  acid  and  maleic  acid: 

For  protective  coatings 


For  textile,  paper,  and  leather  treatment. 

For  miscellaneous  uses 

Adipic  acid:  For  protective  coatings 

Azelaic  acid:  For  protective  coatings 

Citric  acid: 

For  protective  coatings 

For  miscellaneous  uses 

Congo  ester: 

For  protective  coatings 

For  miscellaneous  uses... 

Ester  gums:  For  protective  coatings 

•Fumaric  acid: 

For  protective  coatings 

For  miscellaneous  uses 

See  footnotes  at  end  of  table. 


2,  128,  487. 

384. 

112,  128,  301. 

297. 

2,  128. 

110,  394. 

301. 

13. 

91. 

336. 

298. 

163,  370. 

39. 

74,  178. 


370. 

370,  433,  X. 


308. 
43,  308. 
308. 
43,  345. 
357. 
298. 

39, 81, 124,  298. 

403. 

81,465. 

74. 

39, 345,  X. 

171. 

220. 


184,  199,  221,  302,  357,  376,  413,  467, 

496,  X. 
199. 
199. 
199, 467. 

6,  70,  73,  163,  184,  199,  227,  291,  302, 
357,  376,  413,  445,  467,  X,  X,  X,  X. 
199. 

199, 467. 
13,  70. 
70, 357. 

70. 
X. 

242,  467, 496. 

467. 

13. 

175,  227, 376, 413,  465, 467,  496,  X. 
467. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


105 


Table    15B. — Synthetic  organic   chemicals:   Plastics   materials  for   which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Material 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


PLASTICS  MATERIALS,  ACYCLIC— Con. 

Condensation  Resins — Con. 
*Alkyd  resins — Con. 
*Maleic  acid  or  anhydride: 

For  molding  and  casting 

For  laminating 

For  protective  coatings w. 

♦Maleic  anhydride-terpene: 

For  protective  coatings 

For  adhesives 

For  textile,  paper,  and  leather  treatment 

For  miscellaneous  uses 

Octohydric  polymer:  For  protective  coatings 

Rosin:  For  protective  coatings 

Sebacicacid: 

For  molding  and  casting 

For  protective  coatings 

For  textile,  paper,  and  leather  treatment.. 

Succinic  acid ;  For  protective  coatings 

Tall  oO:  For  adhesives 

All  other,  unspecified:  For  laminating.. , 

*Organic  nitrogen  resins: 
Melamine-formaldehyde: 

For  molding  and  casting 

For  laminating 

For  protective  coatings 

For  adhesives 

For  textile,  paper,  and  leather  treatment 

For  ion  exchange 

Melamine-urea-formaldehyde: 

For  laminating 

For  adhesives 

*Urea-formaldehy  de : 

*For  molding  and  easting 

For  laminating 

For  protective  coatings 

*For  adhesives 

*For  textile,  paper,  and  leather  treatment 

For  miscellaneous  uses , 

Urea-  and  thiourea-formaldehyde: 

For  adhesives 

For  textile,  paper,  and  leather  treatment 

Petroleum  condensation  resins — 

Polyamide  resins 

Silicone  resins.. 

Polymerization  Resins 

♦Alcohol  polymerization  resins: 
Ally]  alcohol: 

For  molding  and  casting 

For  laminating 

Furfural-furfuryl  alcohol: 

For  molding  and  casting 

For  protective  coatings 

For  miscellaneous  uses 

Polyacrylic  and  methacrylic  acid  resins: 

For  textile,  paper,  and  leather  treatment. 

For  miscellaneous  uses 

Polyacrylic  and  polymethacrylic  acid  ester  resins: 

For  molding  and  casting 

For  laminating 

For  textile,  paper,  and  leather  treatment... 

For  glazing,  sheeting,  and  films 

For  miscellaneous  uses. 

Polyolefin  resins:  Polyethylene,  unplasticized 

Polyterpene  resins _ 

♦Polyvinyl  alcohol,  ester,  ether,  and  halide  resins: 
Polyvinyl  alcohol: 

For  molding  and  casting... 

For  adhesives. 

For  textile,  paper,  and  leather  treatment 

See  footnotes  at  end  of  table. 


413. 

13,  298, 306,  358. 

4,  13,  70,  71,  112,  180,  184,  226,  227, 

242,  258,  275,  357,  376,  382,  394, 

445, 496,  X,  X,  X. 

199,  226. 

199. 

199. 

199. 

242. 

376, 467. 

382. 

2,  13,  227,  357,  376,  382,  445,  467.  X. 

227,  376. 

413. 

376. 

272. 


13,  298,  358. 

13,  39. 

13,  382. 

13. 

13. 

13. 

13,  81. 
13. 

13,  39,  358,  448. 

39. 

13,  127,  358,  376. 

13,  39,  246,  358. 

13,  358,  373,  376,  382, 

358. 

80,  X. 
267,  468. 
X. 
127. 
124. 


357. 
272. 

220. 
180. 
220. 


127. 
127,  388. 


127,  388. 
i  388,  X. 
,345. 


127. 
127. 
127. 


106 


UNITED    STATES   TARIFF    COMMISSION 


Table    15B. — Synthetic   organic  chemicals:   Plastics   materials  for   which    United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Material 


Manufacturers'  identification  num- 
bers faccordine;  to  list  in  table  22) 


PLASTICS  MATERIALS,  ACYCLIC— Con 
Polymerization  Resins— Con. 

•Polyvinyl  alcohol,  ester,  ether,  and  halide  resins— Con. 

Polyvinyl  alcohol— Con. 

For  glazing,  sheeting,  and  films 

For  miscellaneous  uses 

Polyvinyl  acetate: 

For  protective  coatings 

For  adhesives_.- -. 

For  textile,  paper,  and  leather  treatment 

For  miscellaneous  uses _ -. 

Polyvinyl  chloride: 

For  molding  and  casting --. 

For  protective  coatings-.. 

For  textile,  paper,  and  leather  treatment 

For  miscellaneous  uses... _. 

Polyvinyl  chloride-acetate  copolymer: 

For  molding  and  casting 

For  protective  coatings 

For  adheslves 

For  textile,  paper,  and  leather  treatment 

For  glazing,  sheeting,  and  films. 

For  miscellaneous  uses 

Polyvinyl  ether  resins:    For  adhesives 

Polyvinylidene  chloride-polyvinyl  chloride  copolymer: 

For  molding  and  casting 

For  glazing,  sheeting,  and  films. 

For  miscellaneous  uses. 

*Polyvinyl  alcohol-aldehyde  resins: 

Polyvinyl  acetal:    For  adhesives 

Polyvinyl  butyral: 

For  laminating 

For  protective  coatings 

For  adhesives 

For  textile,  paper,  and  leather  treatment 

For  glazing,  sheeting,  and  films 

For  miscellaneous  uses 

Polyvinyl  formal: 

For  molding  and  casting 

For  protective  coatings - 


127. 
127. 

7.3,  74,  X. 
74,  127,  X. 
X. 
127,  X. 

74. 
127. 
127. 
182. 

74. 
74.  220. 

74. 
74. 
74. 
74. 
171. 

124. 
124. 

74. 

408. 

74,  408. 

408. 

74,  127,  408. 

74,  127. 

127. 

74,  127. 

408. 


1  Includes  phthalic  anhydride-abietic  acid  glycerol  and  phythalic  anhydride  maleic  anhydride  glycerol 
resins. 

2  Includes  small  amounts  of  alicyclic  and  heterocyclic  resins. 


RUBBER-PROCESSING  CHEMICALS 


Table  17'B.— Synthetic  organic  chemicals:  Rubber-processing  chemicals  for  which 
United  States  production  or  sales  were  reported,  identified  by  7nanufacturer,  1944 

I  Rubber-processing  chemicals  for  which  separate  statistics  are  given  in  table  17A  are  marked  below  with 
an  asterisk  (*);  chemicals  not  so  marked  do  not  appear  in  table  17A  because  the  reported  data  are  con- 
fidential and  may  not  be  published.  Manufacturers  are  identified  by  numbers  in  the  alphabetical  list 
apnearing  in  tabie  22.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his 
identification  number  with  the  designated  product] 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


RUBBER-PROCESSING  CHEMICALS,  CYCLIC 

'Accelerators: 
*  Aldehyde-amines: 

Acetaldehyde-aniline 

*n-Butyraldehyde-aniline 

a-Ethyl-/3-propylacrolein-aniline 

Formaldehyde-aniline  (Methylene  aniline) 

Formaldehyde-monoethylamine         (Triethyltrimethylenetria 
mine). 


127,  298,  306. 

127, 182,  298, 306. 

87. 

127, 198. 

306. 


SYNTHETIC   ORGANIC    CHEMICALS,    19  44 


107 


Table  17B. — Synthetic  organic  chemicals:  Rubber-processing  chemicals  for  which 
United  States  'production  or  sales  were  reported,  identified  by  manufacturer, 
1944 — Continued 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


RUBBER-PROCESSING  CHEMICALS,  CYCLIC— Con. 

*  Accelerators — Con. 
*Aldehyde-amines — Con. 

Formaldehyde-p-toluidine  (Methylene-p-toluidine) 

Heptaldehyde-aniline 

Hexamethylenetetramine  (Aldehyde-ammonia) 

Urea-butyraldehyde-aniline 

•Dithiocarbamates: 

Carbon  disulflde-methylenedipiperidine 

Dimethyl  ethylenediphenyl  dithiocarbamic  acid,  lead  salt 

Dimethyl  ethylenediphenyl  dithiocarbamic  acid,  zinc  salt 

2,  4-Dinitrophenyl  dimethyl  dithiocarbamate 

Piperidinium  pentamethylene  dithiocarbamate 

Piperidinium  pentamethylene  dithiocarbamic  acid,  potassium 
salt. 
♦Guanidines: 

*Diphenylguanidine 

Diphenylguanidine  and  mercaptobenzothiazole  dinitrophenyl 
ester. 

Diphenylguanidine  phthalate 

Di-o-tolylguanidine 

Triphenylguanidine 

*Thiazole  derivatives: 

Alkyl  2-mercaptothiazole 

2-(Benzoylthio)benzothiazole  (Benzothiazole  thiobenzoate) 

Bis-N,N'-(2-benzothiazylthiomethyl)urea 

N-Cyclohexyl-2-benzothiazole  sulfenamide 

Diphenylguanidine  phthalate,  diphenylguanidine,  and  mercap- 
tobenzothiazole dinitrophenyl  ester. 

Disulfide  alkylated-2-mercaptothiazole 

2,2'-Dithiobisbenzothiazole  (2,2'-Benzothiazyl  disulfide) 

*2-Mercaptobenzothiazole 

2-Mercaptobenzothiazole,  copper  salt 

Mercaptobenzothiazole  hexamethylenetetramine  ester 

2-Mercaptobenzothiazole,  lead  salt 

Mercaptobenzothiazolemethylene  aniline 

Mercaptohenzothiazoleraethylene-o-toluidine 

2-Mercaptobenzothiazole,  sodium  salt 

2-Mercaptobenzothiazole,  zinc  salt 

2-Mercaptothiazoline 

Thiuram  derivatives:  Di-N-pentamethylenethiuramtetrasulflde--. 

Miscellaneous: 

Dibenzylamine 

p-Quinone  dioxime 

p-Quinone  dioxime  dibenzoate 

•Antioxidants: 

Aldehyde-  and  acetone-amines: 

Acetaldehy de-aniline  hydrochloride 

p-Amtnodiphenyl-acetone 

Aniline-acetone,  acid  derivatives 

Butyraldehyde-aniline 

Crotonilidine-a-naphthylamine 

Diphenylamine-acetone 

Pheny  1-fl-naphthylamine-acetone 

•Amino  or  hydroxy  compounds: 

2,4-Diaminodiphenylamine 

p,p'-Diaminodiphenylmethane 

2,4-Di-tert-butylhydroquinone 

Di-o-tolylethylenediamine 

Hydroquinone  monobenzyl  ether 

p-Hydroxydiphenj'lamine 

Guanidine:  Dicatechol  borate,  di-o-tolylguanidine salt 

Secondary  amines: 

Alkylated  diphenylamine 

p,p'-Dimethoxydiphenylamuie 

Di-0-naphthol-p-phenylenediamine --. 

N,N'-Diphenylethylenediamine 

*N,N'-Diphenyl-p-phenylenediamine 

p-Isopropoxydiphenylamine 

p-Methyl-p-(p-tolylsulfonylamino)  diphenylamine 

Phenyl-or-naphthylamine 

Phenyl-;8-naphthylamine 

p-(p-Toluenesulfonamino)diphenylamine 

Thiophenyl-/3-naphthylamine 

697646 — 46 8 


127. 
306. 
127. 
306. 

298. 

87. 

87. 

306. 

298, 306. 

127. 


13, 127,  298. 
298. 

298,  306. 
13, 127. 
304. 

182. 
298. 
298. 
298. 
298. 

182. 

69, 183,  298. 

69. 183,  298,  306. 

183. 

127. 

127. 
'306. 
1306. 

183. 

69,  306. 

69, 127. 

127.  ^ 

306. 
306. 
306. 


306. 
298. 
298. 
127. 
182. 
306. 
306. 

298. 

306. 

298. 

87. 

182. 

127, 182. 

127. 

182. 
127. 
182. 

87. 

127, 182,  298,  306. 

182. 

306. 

127. 

127, 182, 183. 

306. 

183. 


108 


UNITED   STATES   TARIFF    COMMISSION 


Table  17B. — Synthetic  organic  chemicals:  Rubber-processing  chemicals  for  which 
United  States  production  or  sales  were  reported,  identified  by  manufacturer, 
1944 — Continued 


Chemical 


RUBBER  PROCESSING  CHEMICALS,  CYCLIC— Con 

♦Antioxidants— Continued 
Miscellaneous: 

p-terf-Butyl-m-cresol  monosulfide 

^-Di-p-hydroxypheny  Ipropane 

Diphenyl-p-phenylenediamine-p-aminodiphenyl-acetone 

p-Hydroxy-N-plienylmorpholine 

Phenol-cydohexanoiic 

2,2,4-Trimethyldihydroquinoline  polymers 

Tackiiiers:  Amylplienyl  sulfide 

RUBBER-PROCESSING  CHEMICALS,  ACYCLIC 

Accelerators: 

Aldehyde-amines:  Butyraldehyde-monobutylamine 

*Dithiocarbamates: 

Amyl-ammonium  dimethyldithiocarbamic  acid,  zinc  salt 

Dibutyl  dithiocarbamic  acid,  sodium  salt 

fDibutyl  dithiocarbamic  acid,  zinc  salt 

Diethyl  dithiocarbamic  acid,  selenium  salt 

Diethyl  dithiocarbamic  acid,  zinc  salt--. 

Diethyl  dithiocarbamic  acid,  sodium  salt 

Dimethyl  dithiocarbamic  acid,  zinc  salt 

*Thiuram  derivatives: 

Tetra-amylthiuram  monosulfide 

Tetrabutylthiuram  monosulfide 

Tetraethylthiuram  disulfide 

*Tetramethylthiurani  disulfide 

Tetrametliylthiuram  monosulfide 

Tetramethylthiuram  tetrasulfide 

Xanthates: 

Di-n-butyl  xanthodisulfide , 

Di-isopropyl  xanthodisulfide 

Zinc  butyl  xanthate 

Miscellaneous: 

tert-Butylhydro  peroxide 

Keryl  mercaptan 

*Peptizers:  Dodecyl  mercaptan 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


298. 
183. 
298. 
127. 
298. 
182. 
407. 


127. 


183. 

407. 

306. 

407.  509. 

183,  306, 407. 

.'i09. 

306,  407. 


306. 

127,183,407,509. 

127,298,306,407. 

127.306. 

127. 

306. 

182,  298. 

183,  306. 

465. 
304. 
127, 205,  298.  306,  531. 


*  ELASTOMERS  (SYNTHETIC  RUBBERS) 

Table  18B. — Synthetic  organic  chemicals:   Elastoyners  {synthetic  rubbers)  for  which 
United  States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 

[Elastomers  (synthetic  rubbers)  for  which  separate  statistics  are  .i?iven  in  table  18A  are  marked  below  with 
an  asterisk  (*);  products  not  so  marked  do  not  appear  in  table  ISA  because  the  reported  data  are  confi- 
dential and  may  not  be  published.  Manufat  turors  are  identified  by  numbers  in  the  alphabetical  list 
appearing  in  tabli!  22.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his 
identification  number  with  the  designated  product] 


Product 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


ELASTOMERS,  CYCLIC 

Polybutadiene-styrene  (GR-S  type): 

*Produced  at  Government  plants 

♦Produced  at  private  plants 

ELASTOMERS,  ACYCLIC 

Polyalkylene-sulfide  (Thiokol  type) 

*Polybutadiene-acrylonitrile  (GR-A  type)  (Buna  N) 

*  Produced  at  Government  plant 

♦Produced  at  private  plants. ._- 

Polychloroprene  (GR-M  type)  (Neoprene): 

♦Produced  at  Government  plant 

Produced  at  private  plant 

Polyisobutylene 

♦Polyisobutylene-diolefln  (GR-I  type) 

♦Polyisoprene..- 


514,  517,  518,  519,  520,  523,  524,  531. 
124,  183,  210,  437,  465,  517,  X,  X. 


519 

124*  158,  183,  210,  437. 

516. 

127. 

436. 

436,  521,  524. 

520. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


109 


Table  18B. — Synthetic  organic  chemicals:  Elastomers  {synthetic  rubbers)  for  which 
United  States  production  or  sales  were  reported,  identified  by  manufacturer, 
1944 — Continued 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


ELASTOMERS,  ACYCLIC— Continued 

Polyisoprene-acrylonitrUe 

Polyvinyl  alcohol 

Polyvinyl  alcohol-aldehyde:  Polyvinyl  butyral  (Butvar)  (Butacite) 

Polyvinyl  chloride-acetate  copolymer 

Reaction  products  of  natural  rubber: 

Polymerized  chlorinated  rubber  (Parlon) 

Polymerized  rubber  hydrochloride  (Plioform) 


X. 

127. 

74,  127,  298. 

74,  357. 

199. 
183. 


SURFACE-ACTIVE  AGENTS 

Table  19B. — Synthetic  organic  chemicals:  Surface-active  agents  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 

[Surface-active  agents  for  which  separate  statistics  are  given  in  table  19A  are  marked  below  with  an  asterisk 
(*);  products  not  so  marked  do  not  appear  in  table  19 A  because  the  reported  data  are  confidential  and 
may  not  be  published.  Manufacturers  are  identified  by  numbers  in  tlie  alphabetical  list  appearing  in 
table  22.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification 
number  with  the  designated  product] 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


SURFACE-ACTIVE  AGENTS,  CYCLIC 

Nonsulfated  and  nonsulfonated: 

Polyhydric  alcohol  esters  and  ethers: 

Diamylphenyl  polyether  alcohol. 

Iso-octylphenyl  polyether  alcohol. 

Iso-octyltolyl  polyether  alcohol 

'Quaternary  ammonium  compounds: 

Cetyldimethylbenzylammonium  chloride 

Cetylpyridinium  bromide 

Cetylpyridinium  chloride 

Cetylpyridinium  iodide 

2-Lauroyloxyethylcarbamylmethylpyridinium  chloride  (Lauryl 
ester  of  colaminoformylmethylpyridinium  chloride). 

Lauryldimethylbenzylammonium  chloride 

Laurylpyridinium  chloride 

Stearoxymethylpyridinium  chloride,  mixture.. 

Trimethylbenzylammonium  chloride 

Trimethylbenzylammonium  hydroxide 

All  other 

Sulfated  and  sulfonated: 

Benzene  derivatives,  sulfonated: 

Alkyl  phenyl  ethers,  sulfonated 

Decylbenzenesulfonic  acid,  sodium  salt 

Di-isopropylbenzenesulfonic  acid 

Dodecylbenzenesulfonic  acid,  sodium  salt 

Polyalkylbenzenesulfonic  acid,  sodium  salt 

Diphenyl  derivatives,  sulfonated: 
5-Chlorobis  (3,5-dichloro-2-hydroxyphenyl) -o-toluenesulfonic 
acid,  sodium  salt. 

Dibutylphenylphenoldisulfonic  acid,  sodium  salt 

Monobutylbiphenylmonosulfonic  acid,  sodium  salt 

Monobutylphenylphenolmonosulfonic  acid,  sodium  salt 

*Naphthalene  derivatives,  sulfonated: 

Amylnaphthalenesulfonic  acid,  sodium  salt 

Benzylnaphthalene  sulfonic  acid  (di  and  mono) 

Butyl  ester  of  l-naohthalenesulfonic  acid,  sodium  salt 

Butylnaphthalenesulfonic  acid,  sodium  salt... 

Dibutylnaphthalenesulfonic  acid,  sodium  salt 

Di-isopropylnaphthalenesulfonic  acid,  sodium  salt 

Dilaurylnaphthalenesulfonic  acid,  sodium  salt 

Dimethylhexylnaphthalenesulfonic  acid... 

Hexylnaphthalenesulfonic  acid 

*Isopropylnaphthalenesulfonic  acid  (mono)  and  sodium  salt. 

2-Naphthalenesulfonic  acid  formaldehyde  condensate 

Oleylnaphthalene  sulfonic  acid 

Another 


171. 
171. 
171. 

250,  388. 
137. 

137,  287. 
137. 
143. 

383,  501. 

205. 

486. 

103. 

103. 

157. 


250,  388. 

298. 

32 

298,  304. 

32. 

171. 

298. 
298. 


5,  8,  305. 

171. 

23. 

430. 

171. 

171. 

305. 

5. 

5. 

13, 197,  304,  383,  450,  464,  X. 

X. 

366. 

X. 


110 


UNITED    STATES    TARIFF    COMMISSION 


Table   19B. — Synthetic  organic  chemicals:  Surface-active  agents  fur  which   Uniied 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


SURFACE-ACTIVE  AGENTS,  CYCLIC— Continued 

Sulfated  and  sulfonated— Continued 
'Petroleum  derivatives,  sulfonated: 

Naphthenic  acid,  sulfonated 

Naphthenic  acid,  sulfonated,  aluminum  salt 

Naphthenic  acid,  sulfonated,  sodium  salt - 

Petroleum  sulfonate,  ammonium  salt. 

Petroleum  sulfonate,  barium  salt 

Petroleum  sulfonate,  calcium  salt 

Petroleum  sulfonate,  sodium  salt 

Petroleum  sulfonates,  other 

SURFACE-ACTIVE  AGENTS,  ACYCLIC 

Nonsulfatcd  and  nonsulfonated: 
•Amides: 

N-(Aminoethyl)-N-(hydroxyethyl)oleamide     (Aminoethyl- 

ethanol  mono-oleylamide). 
N-(Aminoethyl)-N-(hydroxyethyl)stearamide        (Aminoethyl- 

ethanol  monostearylamide). 

N-(  Aminoethyl)  lauramide 

N-(Aminoethyl)oleamide -_- 

N-(Aminoethyl)stearamide 

Coconut  oil  fatty  acid  amide  and  ester  mixture 

N,N-D!(2-hydroxyethyl)lauramide  (Diethanol  laiu-amide) 

N,N-Di(2-hydroxyethyl)oleamide  (Diethanol  oleamide,  amide 

and  ester  mixtures). 

N-(2-Hydroxyethyl)  lauramide  (Ethanol  lauramide) 

N-(2-Hydroxyethyl)oleamide  (Ethanol  oleamide) 

N-(2-Hydroxyethyl)ricinoleamide  (Ethanol  ricinoleamide) 

N-(2-Hydroxyethyl)stearamide  (Ethanol  stearamide) 

12-Hydroxy-N-(2-hydroxyethyl)stearamide  (Ethanol  hydroxy- 

stearamide). 

Tall  oil  amide 

Nitrogen-containing  surface-active  agents  other  than  amides: 

Betaine  hydrochloride 

Castor  oil  amine,  polyether  alcohol 

Diethanolamine  laurate .-- 

Ethylenedinitrilotetra-acetic  acid,  tetrasodium  salt 

Hexadecyl,  octadecenyl  amineacetate  mixture 

Hexadecyl,  octadecadienyl,  octadecenyl  amineacetate  mixture.. 

Monobutylamine  oleate 

Nitrilotriacetic  acid,  trisodium  salt..  _-_ 

Oleoylsarcosine  (n-Methyloleoylglycine),  sodium  salt 

Oleylamine  polyether  alcohol 

Oleyl  glyoxilidine 

Stearoylsarcosine  (n-Methylstearoylglycine),  sodium  salt 

Stearylbiguanide  hydrochloride 

Stearyl  glyoxilidine  (2-(2-Heptadecyl-2-imidazoline-l)ethanol).. 

Triethanolamine,  coconut  oil  fatty  acid  ester 

Triethanolamine  palmitate 

Trihexylammonium  tricarballylate 

Polyhydric  alcohol  esters  and  ethers: 

Glucose  polyglycol  ether  di-(cottonseed  fatty  acid)ester 

Glucose  polyglycol  ether  distearate 

Glucose  polyglycol  ether  oleate 

Mannitan  monolaurate 

Mannitan  monolaurate  polyglycol  ether 

Mannitan  mono-oleate 

Mannitan  monopalmitate 

Olein  polyether  alcohol 

Oleyl  polyether  alcohol 

Peanut  oil  polyethylene  glycol 

Polyglycol  laurate.- -. 

Polyglycol  monostearate 

Polyglycol  lauryl  ether -- 

Polyglycol  mono-oleate -. 

Propyleneglycol,  glycerol  mono-(cottonseed  fatty  acid)ester 

Propyleneglycol  monostearate 

Propyleneglycol  monostearate  polyglycol  ether 

Sorbitau  dioleate. _ 

Sorbitan,  glycerol,  propyleneglycol  ricinoleate  polyglycol  ether. 

Sorbitan  monolaurate 

Sorbitan  monolaurate  polyglycol  ether 

Sorbitan  mono-oleate 

Sorbitan  mono-oleate  polyglycol  ether 

Sorbitan  monopalmitate 

Sorbitan  monopalmitate  polyglycol  ether 

Sorbitan  monostearate 


Manufacturers'  Identification  num- 
bers (according  to  list  in  table  22) 


447. 

434. 

433,  434,  466. 

208,  415. 

32. 

32.415. 

32,  415,  420,  433,  437,  458,  521. 

411,  521. 


197. 

305. 

305. 

305. 

X. 

305. 

X. 

450. 
305. 
40,  305. 
305. 
305. 

192. 

157. 

171. 

8. 

171. 

24. 

24. 

407. 

171. 

171. 

171. 

464. 

171. 

171. 

464. 

X. 

8. 

171. 

34. 

34. 

34. 

34. 

34. 

34. 

34. 

171. 

171. 

171. 

8, 171. 

34, 233,  305. 

34. 

34,  305. 

34. 

34. 

34. 

34. 

34. 

34. 

34. 

34. 

34. 

34. 

34. 

34. 


SYNTHETIC   ORGANIC    CHEMICALS,    194  4 


111 


Table  19B. — Synthetic  organic  chemicals:  Surface-active  agents  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


SURFACE-ACTIVE  AGENTS,  ACYCLIC— Continued 

Nonsulfated  and  nonsulfonated— Continued 

Polyhydric  alcohol  esters  and  ethers — Continued 

Sorbitan  monostearate  polyglycol  ether 

Sorbitan  tetrapropionate 

Sorbitan  trioleate 

Sorbitan  triricinoleate 

Sorbitol  monolaurate  polyglycol  ether 

•Salts  of  fatty  acids: 

Ammonium  Itnoleate 

Ammonium  oleate 

Potassium  laurate 

Sodium  oleate. 

•Sulfated  and  sulfonated: 
*Acids,  sulfated  and  sulfonated: 

Fish  oil  fatty  acids,  sulfonated 

•Oleic  acid,  sulfonated  (Sulfonated  red  oil) 

Ricinoleic  acid,  sulfonated,  sodium  salt 

Rictnoleic  acid,  sulfonated,  potassium  salt 

•Alcohols,  sulfated  and  sulfonated: 

Cetyl,  lauryl,  and  oleyl  alcohol,  sulfated 

Coconut  fatty  acid  ester  ethyleneglycolsulfate  ethanolamine  salt 

3,  9-Diethyl-6-tridecylsulfate,  sodium  salt 

2-E thylhexylsulfate,  sodium  salt • 

7-E  thyl-2-methyl-4-undecy IsuUate,  sodium  salt 

Lauryl  sulfate,  sodium  salt 

Lauryl  sulfate,  triethanolammonium  salt 

N-Methyloleylaminopolyethoxyethylsulfuric  acid,  sodium  salt 

(Methyl  polyethanolamine) . 

Oleyl  sulfate 

•Amides,  sulfated  and  sulfonated: 

Laurie  acid  ester  of  potassium  sulfoacetoethanolamide 

•Lauroyltaurine  (Ethanol  lauramide  sulfonic  acid)  salts 

Methylene-diethanolamide  of  stearic  and  coconut  oil  fatty  acids. 

N-Methyloleoyltaurine 

N-Methylpalmitoyltaurine 

N-Octadecyldisodium  sulfosuccinamate 

N-Octadecyltetrasodium  N'-l,  2-dicarboxysulfosuccinamate 

Oleoyltaurine  (Ethanol  oleamide  sulfonic  acid)  and  salts 

Eicinoleyltaurine,  sodium  salt  (Ricinoleylamidehydroxyethane- 

sulfonate,  sodium  salt) . 

Spermacite  amide,  sulfonated 

Stearoyltaurine,     sodium     salt     (Stearicamidehydroxyethane 

sulfonate,  sodium  salt). 

Another 

•Esters,  sulfated  and  sulfonated: 

Butyl  acetylricinoleate,  sulfated,  sodium  salt 

Butyl  oleate,  sulfated 

Diamyl  sodium  sulfosuccuiate 

Dibutyl  sodium  sulfosuccinate 

Diethyleneglycol  oleate  sulfate 

Dihexyl  sodium  sulfosuccinate 

Dioctyl  sodium  sulfosuccinate 

Lauryl  sulfoacetate 

Methyl,  ethyl,  and  propyl  oleate,  sulfated 

Sulfated  monoglycerides  from  coconut  fatty  acids,  ammonium 

salt. 
Sulfated  monoglycerides  from  coconut  fatty  acids,  sodium  salt__ 

Monostearine  sodium  sulfoacetate 

Sulfoethyl  oleate 

All  other 

Glyceryl  phosphate  ester  of  cottonseed  oil  fatty  acids,  sodium  salt. 
•Oils,  fats,  and  waxes,  sulfated  and  sulfonated: 
•Castor  oil,  sulfonated 

Coconut  oil,  sulfonated- - 

•Cod  oil,  sulfonated 

•Com  oil,  sulfonated .- 

Cottonseed  oil,  sulfonated-.. 

Fish  oils,  mixed,  sulfonated.. 

Herring  oil,  sulfonated 

Lard  oil,  sulfonated 

Menhaden  oil,  sulfonated 

Mustardseed  oil,  sulfonated 

*  Neat 's-foot  oil ,  sulfonated 


34. 
34. 
34. 
34. 
34. 

181. 
181. 

300, 305. 
464. 


273. 


8, 171, 192, 195, 197, 300,  305,  373,  398, 

420, 486, 497. 
91. 
305. 

383. 
X. 

74. 

74. 

74. 

127, 366. 

366. 

171. 

383. 

143. 

8, 197, 464, 486. 

5. 

171. 

171. 

13. 

13. 

305, 430, 464. 

464. 

383. 
464. 

5, 300. 

197. 

305, 383. 

13. 

13. 

X. 

13. 

13. 

304. 

206. 

X. 

5,X. 

143. 

171. 

300. 

143. 

8,  13,  35,  64,  171,  195,  197,  206,  248, 
300,  305,  373,  378,  383,  420,  464, 
486, 497. 

195, 464. 

35. 

8,  13,  206,  248,  305,  373,  464,  486. 

35,  305. 

195,  273,  497. 

35,  195,  273,  305,  497. 

300,  464. 

273. 

305  383 

35,  'l95,  206,  248,  305,  373,  378,  383. 


112 


UNITED   STATES   TARIFF    COMMISSION 


Table  19B. — Synthetic  organic  chemicals:  Surface-active  agents  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 

Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 

SURFACE-ACTIVE  AGENTS,  ACYCLIC-Con. 

♦Sulfated  and  sulfonated— Con. 
*Oils,  fats,  and  waxes,  sulfated  and  sulfonated— Con. 
*Peanut  oil,  sulfonated  _            , 

197,  206,  248,  305,  373,  383,  420,  430, 

Recovered  grease,  sulfonated                .              --    - 

486. 
273. 

Rice  bran  oil,  sulfonated  .     ._      .  

305. 

Seal  oil,  sulfonated  

273. 

8,  195, 197,  206,  248,  273,  373,  383,  497. 

*Sperm  oil,  sulfonated     .                              ... .- 

13,  35, 195,  197,  248,  273,  305,  378,  383, 

'Tallow,  sulfonated 

464,  486,  497. 
13,  35, 195, 197,  206,  248,  305,  373,  378, 

Whale  oil,  sulfonated 

383,  420,  464,  486,  497. 
273. 

All  other ■ 

273,  430,  497. 

Petroleum,  alkyl,  sulfonated:  Petroleum  sulfonate,  sodium  salt  .. 
All  other 

127. 
300. 

PLASTICIZERS 

Table  20B. — Synthetic  organic  chemicals:  Plasticizers  for  which  United  States  pro- 
duction or  sales  were  reported,  identified  by  manufacturer,  1944 

(Plasticizers  for  which  separate  statistics  are  a;iven  in  table  20A  are  marked  below  with  an  asterisk  (*); 
products  not  so  marked  do  not  appear  in  table  20A  because  the  reported  data  are  confidential  and  may  not 
be  published.  Manufacturers  are  identified  by  numbers  in  the  alphabetical  list  appearing  in  table  22. 
An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number 
with  the  designated  product] 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


PLASTICIZERS,  CYCLIC 

Camphor,  synthetic 

/S-Chloro-/3'-(2-xenoxy) diethyl  ether 

Coumarone-indene  plasticizer 

Cyclohexyl  levulinate 

Di-tcrt-amylphenoxyethanol 

Dibenzyl sebacate  -. 

Diethylene  glycol  dibenzoate. 

Ethyl  o-benzoylbcnzoate , 

N-Ethyltoluenesulfonamide,  o,  p  mixture 

Methyl  abietate 

Methyl  abietate,  hydrogenatcd_- 

Naphthalene  derivatives: 

Amylnaphthalene,  mono 

Diamylnaphthalene 

Polyamylnaphthalene 

Phenolic  coumarone-indene  plasticizer.. 

Phosphoric  acid  esters: 

Diphenyl  mono-o-xenyl  phosphate 

Di-o-xenyl  monophenyl  phosphate 

Tri-(p-tert-amylphenyl)  phosphate.. 

•Tricresyl  phosphate... 

Triphenyl  phosphate 

*Phthalic  acid  or  anhydride  esters: 

Butyl  phthalyl  butyl  glycolate 

Castor  oil  phlhalate,  hydrogenated 

Diallyl  phthalate 

Di-n-amyl  phthalate 

Dl-(butylcellosolve) phthalate  (Di-(butoxyethyl)phthalate) 

*Dibutyl  phthalate 

Dicapryl  phthalate 

Dicarbitol  phthalate   (Bis-(diethylene  glycol  monoethyl  ether) 
phthalate). 

Dicellosolve  phthalate  (Diethoxyethyl  phthalate) 

Dicyclohexyl  phthalate 

Di-2-ethylhexyl  phlhalate 

•Diethyl  phthalate 

Di-(fusel  oil)  phthalate... 

Dihexylcellosolve  phthalate  (Di-(ethyleneglycolmonohexyl  ether) 
phthalate). 


127. 

124. 

308,  346. 

298. 

407. 

382. 

X. 

13. 

298. 

199. 

199. 

407. 
407. 
407. 
308. 

124. 

124. 

124. 

298,  299,  328,  X. 

124,  298. 

298. 

127. 

328. 

467. 

127,  328. 

13,  43,  103,  127,  229,  298,  308,  413, 

467,  474,  X. 
43,  382. 
328. 

328. 

43,  127. 

74,  328. 

13,  103,  127,  229,  298,  467,  X. 

127. 

328. 


SYNTHETIC    ORGANIC    CHEMICALS,    194  4 


113 


Table  20B. — Synthetic  organic  chemicals:  Plasticizers  for  which  United  States  pro- 
duction or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Chemical 


Manufacturers'  identiflcation  num- 
bers (according  to  list  in  table  22) 


PLASTICIZERS,  CYCLIC— Con. 
-Con. 


'Phthalic  acid  or  anhydride  esters- 

Di-isobutyl  phthalate 

Dimethylcenosolve  phthalate  (Di-(ethylene  glycol  monomethyl 
ether)  phthalate)  (Di-(methoxyethyl)  phthalate). 

Di-(methylcyclohexyl)  phthalate -. - 

*Dimethyl  phthalate -.- 


Di-n-octyl  phthalate 

Diphenyl  phthalate .-. 

Ethyl  phthalyl  ethyl  glycolate 

Glyceryl  tributyl  triphthalate 

Methyl  phthalyl  ethyl  glycolate 

Polyoxypropylene  phenyl  propionate. 

Styrene,  polymerized  plasticizer 

Tetrahy  drof  urfury  1  oleate 

ToluenesulTonamide,  o,  p  mixture 


PLASTICIZERS,  ACYCLIC 

Azelaic  acid  esters: 

Di-isobutyl  azelate -. - 

Monomethyl  azelate. 

Citric  acid  esters: 

Acetyltri-n-butyl  citrate. 

Acetyltriethyl  citrate 

Tributyl  citrate 

Triethyl  citrate 

Diethylene  glycol  ester  of  mixed  fatty  acids 

Diethylene  glycol  dipropionate 

Fraternity  oil,  hydrogenated 

Glyceryl  tributyrate 

Glyceryl  triprorionate 

*  Laurie  acid  esters: 

Butylcellosolve  laurate  (Ethylene  glycol  monobutyl  ether  laurate) 
(Butoxyethyl  laurate). 

Butyl  laurate 

Diethylene  glycol  dilaurate 

Diethylene  glycol  monolaurate 

Glyceryl  monolaurate 

1, 2-Propylene  glycol  monolaurate 

Triethylene  glycol  laurate 

All  other 

Mannitol  hexa-acetate 

Octadecadiene,  octadecene  nitrile  mixture ., 

*01eic  acid  esters: 

Amyl  oleate.— 

Butyl  oleate 

Diethylene  glycol  mono-oleate 

Ethyl  oleate 

Glyceryl  diacetyltartrate  mono-oleate 

Glyceryl  mono-oleate 

Methylcellosolve  oleate  (Ethylene  glycol  monomethyl  ether  ole- 
ate) (Methoxyethyl  oleate). 

Methyl  oleate 

Polyglyceryl  oleate 

1, 2-Propyleneglycol  mono-oleate 

All  other 

Pelargonic  acid  esters: 
Butylcellosolve  pelargonate  (Ethylene  glycol  monobutyl  ether 
pelargonate)  (Butoxyethyl  pelargonate). 

Diethylene  glycol  dipelargonate 

•Phosphoric  acid  esters: 

Tributylcellosolve  phosphate    (Tri-(ethylene  glycol   monobutyl 
ether)  phosphate). 

Tributyl  phosphate 

Triethyl  phosphate 

Polyethylene  glycol 

Ricinoleic  acid  esters: 

n-Butyl  acetylricinoleate 

n-Butyl  acetylricinoleate,  polymerized 

Butyl  ricinoleate 

Cellosol  ve  ricinoleate  (Ethylene  glycol  monoethyl  ether  ricinoleate) 
(Ethoxyethyl  ricinoleate). 

Diethylene  glycol  monoricinoleate 

Ethyl  acetylricinoleate 

Glyceryl  monoricinoleate 

Glyceryl  triacetylricinoleate  (Castor  oil,  acetylated) 


127. 
127,  328. 

127. 

13,  16,  127,  166,  199,  229, 

376,  499,  X. 
328. 
298. 
298. 
13. 
298. 
34. 
124. 
205. 
298. 


187,  328. 
141. 

350. 

350. 

103,  127,350. 

127,  350,  X,  X. 

141. 

328. 

205. 

478. 

X. 

187,  233. 

233. 

305. 

143, 165, 181,  233. 

181,233. 

233. 

450. 

181. 

34. 

24. 

407. 

233,  305, 328. 

181,  233,  X. 

233. 

143. 

233,  X. 

328. 

305. 
143. 
233. 
181. 

187, 

141. 

328. 

103,  298. 
298,  X. 
74. 

40. 
40. 
40. 
181. 

305. 

40. 

181,  233, 305. 

40. 


8,  322, 


114 


UNITED   STATES   TARIFF    COMMISSION 


Table  20B. — Synthetic  organic  chemicals :'Plasticizers  for  which  United  States  pro- 
duction or  sales  werejreported,  identified Jby  manufacturer,  1944 — Continued 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


PLASTICIZERS,  ACYCLIC— Continued 

Ricinoleic  acid  esters — Continued 

Methyl  acetylricinoleate 

Methylcellosolve  acetylricinoleate  (Ethylene  glycol  monomethyl 

ether  acetylricmoleate)  (Methoxyethyl  acetylricinoleate). 
Methylcellosolve  ricinoleate  (Ethylene  glycol  monomethyl  ether 
ricinoleate)  (Methoxyethyl  ricinoleate). 

Methyl  ricinoleate 

Sebacic  acid  esters: 
Dibutylcellosolvc  sebacate  (Di-(ethylene  glycol  monobutyl  ether) 
sebacate)    (Di-(butoxyethyl)  sebacate). 

*Dibutyl  sebacate 

Diethyl  sebacate 

Dimethyl  sebacate 

Sorbitan  tetrapropionate - 

'Stearic  acid  esters: 

Amyl  stearate 

Butylcellosolve  stearate  (Ethylene  glycol  monobutyl  ether  stea- 
rate) (Butoxyethyl  stearate). 

*Butyl  stearate 

Cellosolve  stearate  (Ethylene  glycol  monoethyl  ether  stearate) 
(Ethoxyethyl  stearate). 

Diethylene  glycol  distearate 

Diethylene  glycol  monostearate 

Diethylene  glycol  monohydroxystearate 

Glyceryl  distearate... 

Glyceryl  monohydroxystearate 

•Glyceryl  monostearate _. 

Isopropyl  stearate 

Methylcellosolve    stearate    (Ethylene    glycol    monoethyl    ether 
stearate)  (Methoxyethyl  stearate). 

Methyl  dichlorostearate 

Methyl  pentachlorostearate 

Methyl  stearate 

Polyethylene  glycol  monostearate 

Polyglyceryl  stearate 

1, 2-Propylene  glycol  monostearate 

All  other 

Sucrose  octa-acetate... 

Tartaric  acid  esters: 
Dibutylcellosolvc  tartrate  (Di-(ethylene  glycol  monobutyl  ether) 
tartrate)  (Di-(butoxyethyl)  tartrate). 

Dibutyl  tartrate 

Triethylene  glycol  di-2-ethylbutyTate 

Triethylene  glycol  di-2-ethylhexoate 

All  other 


40. 
40,  328. 

40. 

40, 233. 

127. 

103, 127, 192,  382,  X. 

233. 

103, 127, 192. 

34. 

407. 
328. 

103, 233,  305,  X. 

127. 

181  383 

143^  165,"  233,  305, 474. 

305. 

181. 

305. 

143, 165, 181,  233, 305,  430, 474. 

233. 

181,  X. 

205. 

205. 

165,  205, 305. 

181. 

143. 

143,  233. 

181. 

315. 

127. 

103, 233. 
74. 
74. 
220,  328. 


MISCELLANEOUS  SYNTHETIC  ORGANIC  CHEMICALS 


Table  21B. — Synthetic  organic  chemicals:  Miscellaneous  chemicals  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 

[Miscellaneous  chemicals  for  which  separate  statistics  are  given  in  table  21A  are  marked  below  with  an 
asterisk  (*) ;  chemicals  not  so  marked  do  not  appear  in  table  21 A  because  the  reported  data  are  confidential 
and  may  not  be  published.  Manufacturers  are  identified  by  numbers  in  the  alphabetical  list  appearing 
in  table  22.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification 
number  with  the  designated  product] 


Chemical 

Manufacturers'  identification  num 
bers  (according  to  list  in  table  22) 

MISCELLANEOUS  CHEMICALS,  CYCLIC 

Acetyl-p-aminophenol .., 

2-Aminobenzothiazole 

Aniline-acetone 

137, 157. 

137. 

298. 

Barium  iso-octylphenol  sulfide  and  stearol 

Benzoic  acid  salts: 
Ammonium  benzoate  . 

437. 
205,  298. 

*Sodium  benzoate .          ... 

127,  201,  205,  298,  457. 

a-Beuzoin  oxime 

134, 149. 

Benzothiazole 

298. 

Benzoyl  peroxide 

261. 

SYNTHETIC    ORGANIC    CHEMICALS,    1944 


115 


Table  21  B. — Synthetic  organic  chemicals:  Miscellaneous  chemicals  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  i 944— Continued 


Chemical 


MISCELLANEOUS  CHEMICALS,  CYCLIC— Continued 

0- and  p-Benzylphenol 

•Biological  stains ' 

Bis-tert-amylphenol  sulfide,  calcium  salt.""!'"" 

n-Butylcatechol _  ------- 

p-tert-Butylcatechol .  """ 

tert-Butyl  perbenzoate 

p-tert-Butylphenol 

Camphene , I."  " 

Camphocarboxylic  acid l-l.ll]\^lll]l"      I 

p-Carboxybenzenesulfondichloramide  (Halozone)- 
*Chemical  indicators: 

o-Cresolphthalein 

o-Cresolsulfonphthalein  (Cresolred) """"^ "]"]"'. 

m-CresolsuIfonphthalein  (m-Gresol  purple") W 

Dibromo-o-cresolsulfonphthalein  (Bromocresol  purple)  "  ' 

Dibromothymolsulfonphthalein  (Bromothymol  blue) 
Dichlorophenolsulfonphthalein  (Chlorophenol  red) 

Methyl  red 

Phenolsulfonphthalein  (Phenol red) """II" 

Tetrabromo-m-cresolsulfonphthalein  (Bromocresol  green) 
Tetrabromophenolsulfonphthalein  (Bromophenol  blue) 

Thymolphthalein 

Thymolsulfonphthalein  (Thymol  blue) 

Another 

*Chemical  reagents: 

p-Aminodiphenylamine  diazosulfate 

Aurintricarboxylic  acid 

Barium  diphenylamine  sulfonate I.IIIIIIIIIIII 

p-Diazodiphenylamine  magnesium  sulfate  mixture III 

p-Diazodiphenylamine  zinc  chloride  double  salt 

l-Diazo-2-naphthol-4-sulfonic  acid._  

2,6-Dibroraoquinone  chloroimide _ 

Diphenylbenzidine 

Diphenylcarbazone IIII 

Diphenylthiocarbazone  (Dithizone)  ...  __      I 

a.a'-Dipyridyl  (2,2'-Bipyridine) 

p-Nitrobenzeneazoresorcinol 

Nitrosophenylhydroxylamine  (Cupferron) 

Potassium  biphthalate 

Quinhydrone IIIIIIIIIIII.IIIII.IIII 

Sodium-2,6-dichlorobenzenonein"dophenol-._ 

Sulfosalicylic  acid I 

All  other III II I         I 

Cyclohexane "  _'_  ----- 

Cyclohexanol IIIIIIIIIIIIII..IIII 

Cyclohexanone II  I    "III" 

Cyclohexyl  phosphite ".[.I  I 

'Cyclopropane '"_ 

Decahydronaphthalene  (Decalin) I 

Diazodinitrophenol '  I~~ 

Dibenzyl  disulfide 

Dichlorobenzyl  disulfide IIIIIII 

*N,N'-Diethyldiphenylurea 

Diethylene  oxide  (Dioxan) 

2,2'-Dihydroxy-5,5'-dichlorodiphenyImethane 

2,2^-Dihydroxy-3,5,6,3',5',6'-hexachlorodiphenyimethane 

2,2  7Dihydroxy-3,3',5,5'-tetra-amyldiphenylmonosulflde,  barium  salt 
Di-isobutylene-phenolsulfur  monochloride. - 

6,12-Dimethylceroxenyl  acetate _  "" 

Diphenylearbazide ~~~" 

Ergosterol,  crystalline I  

Ethyl  benzoylacetate I 

Ethyleneglycol  monophenyl  ether I..  I 

'Flotation  reagents: 

Dicresyl  dithiophosphoric  acid 

Dieresyl  dithiophosphoric  acid,  ammonium  salt 
Dicresyl  dithiophosphoric  acid,  sodium  salt 

Di-o-tolylthiourea 

Thiocarbanilide III 

Fluorobenzene I  I 

Furan  derivatives: 

Furfural 

Furfuryl  alcohol 

Furfuryl  mercaptan IIIIIIIII  I  "I 

Hydrofuramide III" 

Tetrahydrofurfuryl  alcohol--. mill 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


196,  304,  X. 

407. 

298. 

124. 

465. 

124. 

127. 

1. 

1. 

157. 

134, 157,  304,  449. 

134,  304,  340, 449. 

134,  304,  340, 449. 

134,  304,  340,  449. 

134,  304,  449. 

157,  304. 

48,134,211,304,340,449. 

134,304,449. 

134,  304, 449. 

134, 157. 

134,  304,  449. 

99,  245, 304. 

137. 

134,449. 

134. 

137. 

137. 

137. 

134,  304. 

134. 

157. 

134, 157. 

134, 149. 

134. 

134. 

173,286. 

134,  286. 

134. 

157,  286. 

304. 

43, 124, 127. 

127,  205, 298. 

43, 127. 

43. 

136,  269,  329, 426. 

127. 

199. 

157,205. 

205. 

91, 127, 202, 407. 

74. 

X. 

X. 

13. 

13. 

499. 

157. 

299, 429. 

467. 

74. 

X. 
X. 
X. 
X. 

13, 127,  298, 304. 
134. 

374. 

205,  374. 
137. 
374. 
205,  374, 


116 


UNITED    STATES   TARIFF    COMMISSION 


Table  21B. — Synthetic  organic  chemicals:  Miscellaneous  chemicals  jor  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  194-4 — Continued 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,  CYCLIC— Con. 

♦Gallic  acid,  tech.-. 

Gases  (poisonous,  tear,  etc.):  Chloroacetophenone 

Gasoline  antioxidants. - 

Gasoline  inhibitors -- 

Guanine --- -- 

1-Hydrocyclohexylhydroperoxide-l--- 

♦Insecticides,  synthetic: 

N.N-Benzoylethylcyclohexylamine... --. 

Benzyl  thiocyanate 

•4,4'-Dichlorodiphenyl-l,l,l-trichloroethane  (DDT) 

2,4-Dinitroanisole-.. - - 

4,6-Dinitro-o-cresol --- 

4,6-Dinitro-o-cresol,  sodium  salt 

Fenchyl  thiocyanoacetate 

Phenothiazine • 

Xanthone • 

Mesoxalylurea  (Alloxan) --- 

Methylcyclohexane • 

Methylcyclohexanol  (Methyl  hexalin) 

4-Methyl-5-(/3-hydroxyethyl)thiazole --- 

Methylphloroglucinol 

Morpholine - ■ 

Naphthenic  acid  salts: 

Chromium  naphthenate. — - -- 

Cobalt  naphthenate 

Copper  naphthenate -- — 

Iron  naphthenate 

Lead  naphthenate... 

Manganese  naphthenate -■ 

Mercury  naphthenate - 

Nickel  naphthenate. -.. 

Naphthenic,  oleic,  and  coconut  fatty  acid  mixture,  aluminum  soap 

Octylphenol 

Octylresorcinol... - 

Phenol,  hydrogenated - - 

2-Phenylbutyric  acid 

Phenyl  mercuric  derivatives: ' 

Phenyl  mercuric  acetate 

Phenyl  mercuric  chloride 

Phenyl  mercuric  cyanamide 

Phenyl  mercuric  hydroxide - 

Phenyl  mercuric  nitrate 

Phenyl  mercuric  salicylate..- -. 

All  other - --- 

Phenylphosphoric  acid,  disodium  salt 

Phenylsemicarbazide — 

Phloroglucinol 

♦Photographic  chemicals: 

p-Aminophenol  hydrochloride. 

p-Aminophenol  sulfate 

♦Benzotriazole. 

Catechol  (Pyrocatechin)... 

Chlorobenzotriazole 

Chlorohydroquinone. 

2,4-Diaminophenol  dihydrochloride  (Amidol). 

♦Hydroquinone  (Hydroquinol) 

♦p-Hydroxyphenylglycine 

p-Methylaminophenol  sulfate  (Metol)  (Rhodol) 

Phthalic  acid,  sodium  salt. 

♦plant  hormones: 

2,4-Dichlorophenoxyaceticacid. 

a-Indole-3-n-butyric  acid 

Naphthaleneacetamide  (N-Acetylnaphthylamine) 

Naphthaleneacetic  acid 

2,4,5-Trichlorophenoxyacetic  acid 

♦Plasticizers.    See  table  20B. 

Propylcyclohexanol 

♦Pyrogallol  (Pyrogallic  acid) 

Quinoidine,  sulfurized 

Quinone 

Research  chemicals 

Rosin  acid  salts: 

Calcium  resinate .- 

Manganese  resinate 

Zinc  resinate 

'  See  table  13B  for  medicinal  grades. 


134, 269, 513. 

154,  X. 

127, 208. 

456. 

284. 

465. 

298. 
205. 
41,  91,  127,  140,  173,  274,  286,  290, 

298,  306, 351, 413,  X. 
165, 479. 
X. 
X. 
X. 

124, 127,  241, 308. 
124, 173. 
137. 
43, 306. 
127,205. 
286. 
137. 
74. 

326. 

194, 326. 

194. 

326. 

326. 

194, 326. 

326. 

194. 

193. 

X. 

157. 

205. 

137. 

49. 

49, 189. 

X. 

49. 

49. 

49. 

49. 

340. 

137, 157. 

137. 

134. 

137. 

134, 137, 149. 

X. 

149. 

137. 

30, 479. 

78, 127, 134, 456, 479,  513. 

.30,127,130.x. 

127, 134,479,513,  X. 

171. 

12. 

286. 

12,494. 

12, 13, 124, 173, 494. 

12. 

205. 

134,  269,  513. 

127. 

513. 

65, 134, 157, 284,  390. 

13. 
13. 
13. 


SYNTHETIC   ORGANIC    CHEMICALS,    1944 


117 


Table  21B. — Synthetic  organic  chemicals:  Miscellaneous  chemicals  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Chemical 

Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 

MISCELLANEOUS  CHEMICALS,  CYCLIC— Con. 
Salicylanilide  (Shii'lan)  ...           .        _  

127. 

134, 157. 

*Surface-active  agents.    See  table  19B. 
*Tanning  materials,  synthetic: 

Isopropylidinediphenolsulfonic  acid,  formaldehyde  condensate 

171. 

117, 250, 298, 304, 388. 

2-Naphthalenesulfonic  acid,  formaldehyde  condensate,  ammonium 

salt. 
1-Naphthalenesulfonic  acid,  formaldehyde  condensate,  sodium  salt. 
2-Naphthalenesulfonic  acid,  formaldehyde  condensate,  sodium  salt. 

X. 

23. 
X. 
91. 

171. 

St  yrenemaleic  anhydride  interpolymer,  partial  sodium  salt 

Terpenyl  glycol  ether.  .             ...      

127. 
X. 

X. 

Tetrahydronaphthalene  (Tetralin)                      .    . 

127. 

Tetraphenylarsonium  chloride .       .  .    

137. 

205. 

Derived  from  naphthalene.  .  .. 

127. 

127. 

Thionalid                                                                   

137. 

134. 

o-Tolylbiguanide 

298. 

Tri-tert-amylphenyl  phosphite                      .         .         .  

298. 

Trimethyl  cyclohexanol.                   ...        

205. 

Triphenyl  phosphite 

298. 

Veratyl  aldehyde  bisulfite  compound ..... 

127,  X. 

o-Xenylbiguanide                                         .           

298. 

MISCELLANEOUS  CHEMICALS,  ACYCLIC 
Acetaldehyde 

92, 315, 367, 457,  X,X. 

*Acetamide  .                                                                        

315. 

*Aceticacid:  Synthetic  (100%)                                            

74,  103,  127,  315,  367,  456,  467. 

*  Acetic  acid  salts: 

Aluminum  acetate                                                           .    

13,  127,  173,  286,  315. 

13,  173. 

Cadmium  acetate.. .    .....  ..  

173. 

Calcium  acetate                                                                      . 

173. 

13,  194. 

Cobalt  acetate  

173,  194. 

Copper  acetate                                                                            

173,  194,  315. 

173. 

Magnesium  acetate 

173. 

Mansanese  acetate                                                              

194,  315. 

173. 

Nickel  acetate.  . 

194. 

173,  315. 

Sodium  acetate  ...     .                      ...  

124,  127,  173,  269,  286,  298,  315. 

Zinc  acetate                                                                                   

173,  194. 

'Acetic  anhydride: 

127. 

From  ethylene  (100%)                                                            

74. 

From  ketene  (100%)    ^               ..     .  .               

74. 

From  recovered  acetic  acid  by  the  vapor-phase  process  (100%) 

From  acetic  acid  (other  than  recovered)  by  the  vapor-phase  process 
(100%). 

Mono ... .-        . 

456,  X. 
456. 

171,  233. 

Di 

233. 

*Tri .                                   .                      

166,  199,  202,  233,  261,  305,  456,  X. 

149. 

Acetone: 

29,  103,  129,  367,  467. 

*From  isopropyl  alcohol             .                                                     

74,  367,  410,  435,  456. 

28G,  315. 

Acetonvlacetone                                                                                   

74. 

137. 

Acetylacetone  (2,4-Pentanedione) 

134. 

134. 

a-AcetylbutjTolactone  ...  ..     ....      ...  .  .  .  

467. 

Acetyl  chloride                                                                                     

165,  171,  205. 

Acetyl  iodide .  .. 

137. 

467. 

Aconitic  acid.      .                .                                               . . 

171. 

Acrylonitrile . 

13,  127,  388. 

118 


UNITED    STATES    TARIFF    COMMISSION 


Table  21B. — Synthetic  organic  chemicals:  Miscellaneous  chemicals  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

Adipic  acid 

Adiponitrile 

^-Alanine 

Aldol  (Acetaldol) 

Alk vl  mercaptans,  mixed 

Allyl  alcohol 

Allyl  mercaptan  (2-Propene-l-thiol) 

a- Allyl-^-succtnylurea 

Allylurea 

Aluminum  isopropylate.-. 

•Amines: 

Allylamine 

2-Aminoheptane 

Amylamines: 

Mono 

Di 

Tri 

Butylamines: 

Mono 

Di 

Tri 

Iso 

Decylamine,  dodecylamine,  octadecenylamine,  octylamine,  tetra- 
decylamine  mixture. 

Diethylenetriaraine 

Dioctylamine- 

Dipropylenetriamine- 

Dodecylamine 

Ethylamines: 

Mono - 

Di 

Tri 

Ethylenediamine,  tech 

Hexadecylamine,  tech _ 

Hexadecylamine,  octadecenylamine,  octadecylamine  mixture 

Hcxamethylenediamine .__ 

*Hexamethylenetetramine,  tech 

Methylamine: 

Mono 

Di 

Tri 

Octadecylamine 

Polyethyleneamines 

Propylenediamine 

Stearylamine . 

Tetraethylenepentamine ' 

Triethylenetetramine 

Aminoacetic  acid,  tech.  (Glycine) 

Amino  acid  mixture 

2-Amino-l-butanol 

2-(AminoethyI)aminoethanol  (Hydroxyethyl  ethylenediamine) 

2-Amino-2-ethyl-l,3-propanediol 

Aminoguanidine  sulfate 

2-Amino-2-methy  1-1-propanol  (Aminoisobutanol) 

2-Amino-2-methyl-l,3-propanediol 

*Amyl  acetates,  primary: 

•Normal  (90%) -, 

Active  (90%) 

Isoamyl  (90%) 

•Amyl  alcohols: 

•Crude  (Fusel  oil)  (100%) 

Refined  fusel  oil - -  - 

Refined: 
Primary: 

Active  (2-Methvlbutanol-l)  (100%) 

Isoamyl  (3-MethyIbutanoI-l)  (100%) 

Normal  (n-Butylcarbinol)  (100%) 

Secondary: 

Pentanol-2  (Methylpropylcarbinol)  (100%). 

Pentanol-3  (Dieth vlcarbinol) 

Tertiary:  Amyl  (2-Methylbutanol-2)  (100%) 

Amylenes,  mixed 

Amyl  ether -- 

Amyl  formate 

Amyl  mercaptan  (Pentanethiol) 

n-Amyl  nitrate 


127. 

127. 

1. 

316 

417. 

70,  410. 

137. 

243. 

243. 

134. 

i37. 


407. 
407. 
407. 

407,  X. 

407. 

407. 

127. 

24. 

52,  74. 

74. 
52. 
24. 

407. 

407. 

407. 

52,  74. 

24. 

24. 

127. 

39,  127,  128,  201,  487. 

103,  127,  250,  388. 

103,  127. 

103,  127. 

24. 

74. 

52,  74. 

430. 

74. 

74. 

48. 

X. 

103. 

74. 

103. 

171. 

103. 

103. 

103, 127,  407. 

127. 

168,  324,  343,  467. 

103,  127,  292,  467. 
467. 


127. 

168,  343,  X. 

367; 

407,  438. 

407. 

501. 

407. 

407. 

155. 

407. 

286. 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


119 


Table  21B. — Synthetic  organic  chemicals:  Miscellaneous  chemicals  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

Anhydromethylenecitric  acid  03-(Hydroxy methyl)  tricarballylic  acid 
lactone) . 

Azelaic  acid 

Barium  dihexyl  dithiophosphate 

Barium  dilauryl  dithiophosphate 

l-Bromo-2,3-epoxypropane 

♦Butadiene,  from  alcohol:  Grade  for  rubber  (elastomers) 

Butyl  acetates: 

•Normal  (90%) 

ISO  (90%) 

Secondary  (90%) 

*Butyl  alcohols: 
Primary: 

•Normal  (n-Propylcarbinol)  (100%) 

Iso  (Isopropylcarbinol)  (100%) 

Secondary  (Ethylmethylcarbinol)  (100%) 

Tertiary  (Trimethylcarbinol)  (100%) 

Butyl  chloroacetate 

Butyl  formate 

Butyl  lactate 

Butyl  methacrylate 

Butyl  vinyl  ether . 

n-Butyraldehyde 

n-Butyraldoxime 

n-Butyric  acid 

Butyric  anhydride 

Butyryl  chloride 

n-Caproic  acid 

Caprylic  acid 

Caprylyl  chloride 

•Carbon  disulfide 

•Cellulose  derivatives: 
Cellulose  esters: 

Cellulose  acetate 

Cellulose  acetate  butyrate 

Cellulose  acetate  propionate 

Cellulose  nitrate 

Cellulose  ethers: 

Ethyl  cellulose 

Methyl  cellulose 

Sodium  carboxymethylcellulose 

Chemical  reagents:  Girard's  reagent  P  1 

•Chloral  (Trichloroacetaldehyde) 

Chloroacetamide 

Chloroacetic  acid,  primary: 

Mono 

Di 


Tri 

Chloroacetyl  chloride 

/3-Chloro-a-diethylaminoethane  hydrochloride  (Novolid  salt). 

l-Chloro-3-hydroxypropane 

2-Chloroisopropyl-2-chloroethyl  ether 

Chlorokerosene,  sulfurized 

Chloromaleic  anhydride,  mono 

Chromium  acetylacetonate 

Citric  acid: 

Crude,  fermentation 

Refined,  fermentation 

Cobalt  acetylacetonate -. 

Crotonaldehyde 

Cyanoacetamide .._ 

Cyanoacetic  acid 

Diacetone  alcohol  (4-Hydroxy-4-methyl-2-pentanone) 

Diallyl  succinate 

Diallyl  sulfide. 

Diamyl  sulfide - 

l,3-Dibromo-2-hydroxypropane 

Dibutyl  ether  (n-Butyl  ether) 

Dibutyl  oxalate 

Dichlorodiethyl  ether  (Bis-(2-chloroethyl)  ether) 

Dichloroethyl  acetate 

Dichloroethyl  formal 

Dichloroisopropyl  ether 

1 ,3-Dichloro-2-propanol  (Glycerol  dichlorohydrin) 

Dichlorostearic  acid 

Dicyandiamide 

Piethylaminoethanol ,-.,. . ,...,,..,.,.-,..,, 


137. 

141. 

X. 

X. 

329. 

74,  522,  X. 

74,  103,  127,  157,  343,  367,  467,  X. 

127. 

438. 


29,  74,  103,  367,  467. 

74,  127. 

410,  438. 

410,  524. 

298. 

155. 

103. 

388. 

171. 

74,  X. 

304. 

74,  324,  X. 

74,  X. 

205. 

74,  278,  824. 

X. 

205. 

124,  382,  443,  454,  493,  X. 


14,  16,  127,  199,  456,  X,  X. 

456. 

456. 

199. 

124,  199. 

124. 

199. 

243. 

127,  173,  298,  493. 

286. 

124. 

124. 

124. 

124. 

407,  501. 

329. 

329. 

437. 

304. 

137. 


350. 

94,  350. 

137. 

315,  X,  X 

48,  229. 

48,  124,  278. 

74,  103,  298,  410. 

137. 

137. 

407. 

329. 

74,  103. 

467. 

74,  124. 

91. 

74. 

74,  124. 

329,  410. 

205. 

13. 

74,  407. 


120 


UNITED    STATES   TARIFF    COMMISSION 


Table  21B. — Synthetic  organic  chemicals:  Miscellaneous  chemicals  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Con. 

*l-Diethylamino-4-aminopentane  (Novoldiamine) 

l-Diethylamino-4-pentanol  (Novol  alcohol) -- 

l-Diethylamino-4-pentanone  (Novol  ketone) 

Diethyl  carbonate  (Diatol) 

Diethylene  glycol 

Diethylene  glycol  diethyl  ether  (Diethyl  carbitol). .-. 

Diethylene  glycol  monobutyl  ether  (Butyl  carbitol) 

Diethylene  glycol  monobutyl  ether  acetate  (Butyl  carbitol  acetate) . 

Diethylene  glycol  monoethyl  ether  (Carbitol) 

Diethylene  glycol  monoethyl  ether  acetate  (Carbitol  acetate) 

Diethylene  glycol  monomethyl  ether 

Diethyl  maleate 

♦Diethyl  malonate  (Malonic  ester). _. 

Diethylmalonic  ester  (Diethyl  diethylmalonate) 

Diethyl  sulfate  (Ethyl  sulfate). 

Diglycolic  acid - 

Di-isobutyl  adipate - 

Di-isopropanolamine 

Dimethyl  ether - .- 

Dimethylformamide 

Dimethyl  glutarate 

Dimethylglyoxime --- 

Dimethyl  maleate 

Dimethylolurea.. 

Dimethyl  sulfate 

Dimethylurea 

Dioctanyl  disulfide -. 

Dioleyl  maleate 

Dipropylene  glycol  (Bis-(2-hydroxy-l-propyl)  ether) 

Drying  oil. -. - 

Dulcitol - 

Epichlorohydrin  (l-Chloro-2,3-epoxypropane) 

Erucic  acid 

Ethane  sulfonic  acid. 

Ethanolamine: 

Mono - 

Di.. - - 

Tri... 

♦Ethyl  acetate  (85%).... 

Ethyl  acetoacetate - - 

Ethyl  acrylate 

Ethyl  alcohol,  synthetic 

Ethyl  bromoacetate 

a-Ethylbutyl  acetate 

a-Ethylbutyl  alcohol 

a-Ethylbutyraldehyde-.. 

a-Ethylbutyric  acid  (Diethylacetie  acid) 

Ethyl  chloroacetate -- 

Ethyl  chloroformate  (Ethyl  chlorocarbonate) 

Ethyl  cyanoacetate - 

•Ethylene  (from  ethyl  alcohol  and  ether) 

Ethylene  chlorohydrin 

Ethylene  cyanohydrin. 

N,N'-Ethylenediglycine 

•Ethylene  glycol 

Ethylene  glycol  diethyl  ether  (Diethyl  cellosolve) 

Ethylene  glycol  diacetate.. 

Ethylene  glycol  dinitrate 

Ethylene  glycol  monoacetate. 

Ethylene  glycol  monobutyl  ether  (Butyl  cellosolve) 

Ethylene  glycol  monoethyl  ether  (Cellosolve)... 

Ethylene  glycol  monoethyl  ether  acetate  (Cellosolve  acetate) 

Ethylene  glycol  monomethyl  ether  (Methyl  cellosolve) 

Ethylene   glycol   monomethyl   ether   acetate    (Methyl   cellosolve 

acetate). 
Ethylene  oxide 

*Ethyl  ether. 

Technical. 

U.S.  P 

Absolute --- 

•Ethyl  formate - - 

2-Ethylhexanal- 

2-Ethyl-l,3-hexanedioL._. 

2-Ethylhexanol  (Octyl  alcohol) 

2-Ethylhexoic  acid 

2-Ethylhexyl  acetate 

Ethyl  hydroxy butyrate 


202,  407,  501' 

501. 

407,  467,  501. 

467. 

74,  124. 

74. 

74. 

74. 

74. 

74. 

74. 

304. 

1,  48,  124,  255. 

1. 

74. 

127. 

127. 

74. 

127. 

127. 

127. 

134. 

304. 

127,  486. 

127. 

48,  169,  383. 

437. 

298. 

74,  124. 

127,  389. 

34. 

127,  329,  410. 

157,  501. 

65. 

74,  124. 
74,  124. 
74,  124. 
74,  103,  127,  161,  298,  324,  343,  367, 

408,  450,  467. 
74,  467. 
13,  388. 

69,  74,  127,  438,  X. 
124,  134. 
74,  127. 
74. 
74. 
74. 
298. 
467. 
48,  229. 

124,  146,  257,  329,  388,  467,  515,  522. 
74. 
13. 
351. 

74,  124,  127. 
74. 
74. 
199. 
134. 
74. 
74. 
74. 
74. 
74. 

74, 124. 

74, 199,  438,  467,  522,  X. 

269,  426. 

467. 

103, 168,  269, 324, 343,  467,  X. 

74. 

74. 

74, 157. 

74. 

74. 

13. 


SYNTHETIC   ORGANIC    CHEMICALS,    1944 


121 


Table  21B. — Synthetic  organic  chemicals:  Miscellaneous  chemicals  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944- — Continued 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Con, 

Ethylidene  diacetate - 

Ethyl  lactate 

Ethyl  levulinate 

Ethylmalonic  ester  (Ethyl  ethylmalonate) - 

Ethyl  mercaptan 

Ethyl-1-methylbutylmalonic  ester 

Ethyl  monobromoacetate 

*Ethyl  monochloroacetate 

*Ethyl  oxalate  (Diethyl  oxalate) 

Ethyl  propionate-- 

Ethyl  silicate --- - 

Ethyl  sodium  acetone  oxalate 

Fats  and  oils,  modified: 

Castor  oil,  dehydrated - 

Castor  oil,  hydrogenated 

Linseed  oil,  accelerated 

Linseed  oil,  conjugated. 

Tall  oil,  modified 

Fatty  acids,  chemically  modified: 

Castor  oil  fatty  acids,  dehydrated 

Coconut  oil  fatty  acid  chloride 

Linseed  oil  fatty  acids,  conjugated 

Soybean  oil  fatty  acids,  conjugated 

*ratty  acid  esters,  not  included  with  plasticizers: 

Butyl  palmitate - 

Diethylene  glycol  mono-soybean 

Ethylene  glycol  mono-oleate 

Ethylene  glycol  monostearate 

Ethylene  glycol  and  glycerol  esters  of  tall  oil 

Ethyl  esters  of  linseed  oil  fatty  acids 

Ethyl  laurate.- 

Glucose  polyslycol  ether  pentastearate 

Glyceryl  tall  oil  esters. , 

Glyceryl  tritallow - - 

Isopropyl  laurate..- -.. 

Isopropyl  laurate  and  myristate , 

Isopropyl  oleate.. 

Isopropyl  palmitate 

Methyl  tallow 

Pentaerythritol  esters  linseed  fatty  acid 

Pentaerythritol  soybean  fatty  acid,  esters 

Polyglycol  stearate 

Sorbitan  linseed  fatty  acid  ester 

Sorbitol  polyglycol  ether  hexastearate 

Fatty  alcohols: 

Heptadecanol 

Hexadecanol 

Lauryl  alcohol 

Octadecanediol-. 

Tetradecanol-- 

2-Undecanol 

Another , 

Fenchone 

*Flotation  reagents: 
Thiophosphates: 

Ammonium  di-sec-butyl  dithiophosphate 

Sodium  di-sec-butyl  dithiophosphate.. 

Sodium  diethyl  dithiophosphate 

Sodium  di-isopropyl  dithiophosphate... 

Xanthates: 

Butylxanthogen  ethyl  formate 

Chloronaphtha  xanthate 

Ethylxanthogen  ethyl  formate 

Potassium  amyl  xanthate 

Potassium  butyl  xanthate 

Potassium  ethyl  xanthate 

Potassium  isopropyl  xanthate 

Potassium  pentasol  xanthate 

Sodium  butyl  xanthate... 

Sodium  sec-butyl  xanthate. 

Sodium  ethyl  xanthate 

Sodium  isopropyl  xanthate 

♦Formaldehyde  (37%  HCHO  by  weight).. 

Formamide 

Formic  acid  (90%) 


127. 

13. 

149. 

169,  X. 

269, 417. 

1. 

124. 

124, 165, 286,  X. 

48,  343,  467. 

127, 168,  X. 

74. 

467. 

508. 

127,  205. 
508. 
508. 
300. 

508. 
171. 
508. 
508. 

233, 305. 

233. 

192. 

233. 

508. 

233. 

233. 

34. 

305,  508. 

233. 

143. 

X. 

192. 

143. 

305. 

508. 

508. 

383. 

34. 

34. 

74. 

192, 

X. 

127. 

74. 

74. 

127. 

311. 


X. 
X. 
X. 
X. 

296. 

298. 

296. 

124, 298. 

124,  306. 

124, 298. 

124, 306. 

124. 

X. 

X. 

13, 124. 

X. 

39, 92, 103, 127,  201, 229,  388,  X. 

127. 

127,201,480. 


122 


UNITED    STATES   TARIFF    COMMISSION 


Table  21B. — Synthetic  organic  chemicals:  Miscellaneous  chemicals  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Chemical 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

•Formic  acid  salts; 

Aluminum  formate 

C  iiromic  formate 

Nickel  formate 

*Sodium  formate,  crude 

Sodium  formate,  refined 

Fumaric  acid 

•Oases  (poisonous,  tear,  etc.): 

Carbonyl  chloride  (Phosgene) 

C  hloropicriu 

O  luconic  acid ,  tech ..  _ 

Glucose  polyglycol  ether 

Glyceric  acid  and  calcium  salt 

Glycerol  chlorohydrin,  mono 

Glycerol  epichlorohydrin 

Glycol  bori-borate 

Glycol  diformate -- 

Glycolic  acid  (Hydroxyacetic  acid) 

Glyoxal 

Guanidine  carbonate 

Guanidine  hydrochloride 

Guanidine  nitrate 

Guany  Initrosam  Lneguanyltetrazene 

•Halogenated  hydrocarbons; 
•Chlorides: 

Allyl  chloride 

Amyl  chlorides,  mixed -. 

Butyl  chloride: 

Normal 

Secondary 

Tertiary 

*Carbon  tetrachloride 

Cetyl  chloride 

Chlorinated  methane  and  homologs. 

•Chlorinated  paraffin 

Chlorinated  propane,  liquid _. 

Chlorinated  propane,  wax... — 

Chloroform: 

•Technical 

•U.  S.  P 

l,2-Dich!oroethane  (Ethylene  dichloride) 

Dichloropentane  ( Amylene  dichloride) 

1,2-Dichloropropane  (Propylene  dichloride) 

Ethyl  chloride: 

Technical 

U.  S.  P 

Hexachlorobutadiene 

•Hexachloroethane 

Hexachloropropy  lene 

Isoamyl  chloride  (l-Chloro-3-methylbutane) 

Isopropyl  chloride 

Methallyl  chloride 

•Methyl  chloride  (Chloromethane): 

Crude 

.  Refined,  refrigerant  grade 

•Methylene  chloride  (Dichloromethane): 

Crude 

Refined,  refrigerant  grade 

Pentachloroethane 

sym . -Tetrachloroethane  (Acetylene  tetrachloride) 

•Tetrachloroet hylene  ( Perchloroethylene) 

1,1,2-Trichloroethane  (Methyl  chloroform) 

Trichloroet  hylene 

Vinyl  chloride,  monomer 

Vinylidene  chloride,  monomer 

Another 

•Bromides,  fluorides,  iodides,  and  mixtures: 

Allyl  bromide 

Allyl  iodide 

n- Amyl  bromide 

2-Bromo-l-chloropropane 

2-Bromopentane 

Butyl  bromide: 

Normal 

Iso 

Secondary 

Tertiary 


Manufacturers'  identification  num- 
bers ( according  to  list  in  table  22) 


127,  480. 

171. 

194. 

127,  201,  480. 

173,  269,  286,  501. 

298,  304,  350. 

205,  316. 

19,  124,215. 

350. 

34. 

157. 

410,  X. 

165. 

181. 

74. 

127. 

171. 

13,  157. 

157. 

308. 

X. 


329,  410. 
407. 

74,  407. 

134. 

134,  X. 

120,  124,  317,  454,  493,  X. 

137,  287. 

47. 

9,  120,  199,  202,  205,  433,  437. 

205. 

205. 

62,  124,  127. 

62,  124,  127. 

74,  124,  388,  467. 

407. 

74,  124,  410. 

124,  145. 

124. 

205. 

124,  127,  205,  X. 

205. 

255. 

205. 

410. 

47. 

19,  47,  124,  127,  298,  329,  356,  482. 

47,  124. 

47,  124,  127. 

127. 

124,  127,  493. 

124,  127,  493. 

74,  124. 

127,  493. 

74,  124,  127,  182. 

124,  182. 

205. 

124,  290. 
134,  137. 
124. 
329. 
255. 

124,  134,  157,  290. 

124. 

134,  X. 

134. 


SYNTHETIC   ORGANIC   CHEMICALS,    1944 


123 


Table  21B. — Synthetic  organic  chemicals:  Miscellaneous  chemicals  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

•Halogenated  hydrocarbons— Continued 
♦Bromides,  fluorides,  iodides,  and  mixtures — Continued 

Cetj'l  bromide 

Cetyl  iodide 

l-Chloro-2,3-dibromopropane 

Chlorodifluoromethane,  mono 

l,3-r)ibromopropane  (Trimethylene  bromide) 

Dichlorodifluoromethane 

Dichloromonofluoromethane 

Dichlorotetrafluoroethane 

•Ethj'l  bromide 

Ethylene  dibromide  (1,2-Dibromoethane) ^. 

Isopropyl  bromide 

•Methyl  bromide 

1-Methylbutyl  bromide „ 

Methylene  bromide  (Dibromomethane) 

Methylene  iodide,  tech... 

Methyl  iodide,  tech. 

sec-Octyl  bromide 

n-Propyl  bromide 

Tetrabromoethane  (Acetylene  tetrabromide) 

1,2,3-Tribromopropane 

Trichloromonofluoromethane. 

Trichlorotrifluoroethane 

Trimethylene  bromide 

Trimethylene  chlorobromide 

Heptane 

Hexadecaneamide 

Hexamethylenediammonium  adipate 

n-Hexyl  alcohol 

n-Hexyl  ether 

Hydrocarbon  mixture,  high  molecular  weight.. 

2-Hydroxyethanesulfonic  acid 

a-Hydroxyisobutyronitrile  (Acetone  cyanhydrin) 

12-Hydroxystearic  acid  salts: 

Aluminum  (di)  12-hydroxystearate 

Zinc  (di)  12-hydroxystearate. 

Insecticides: 

Aliphatic  thiocyanates 

Cyclohexyl  caprate 

Indalone 

Isobutylundeeylenamide 

Lorol  rhodanate 

Isoamylethylmalonic  ester 

Isobutyl  propionate - 

Isobutyraldenyde 

Isobutyric  acid 

Iso-octane  cutting  oil 

Isoprene 

Isopropyl  acetate 

*Isopropyl  alcohol  (Isopropanol)  (100%) 

•Isopropyl  ether ._ 

Isopropylethylmalonic  ester _ 

Isopropyl  vinyl  ether 

Isovaleric  acid . 

Lactic  acid: 

•Edible  (100%) 

Medicinal  (100%) 

•Technical  (100%) 

Lactic  acid  salts: 

Calcium  lactate 

Ferrous  lactate. 

•Sodium  lactate 

Strontium  lactate 

Lauroyl  peroxide 

Levulinic  acid  (/3-Acetylpropionic  acid) 

Linoleic  acid  salts: 

Cobalt  linoleate 

Lead  manganese  linoleate 

Manganese  linoleate 

Lorol  chloride- - 

•Maleic  acid  and  anhydride 

Malic  acid 

Malonicacid 

Mannitol 

Mannitol  hexanitrate 


134,  137. 

137. 

329. 

237. 

329. 

237. 

237. 

237 

1,  124,  146,  169,  290. 

124,  145,  146,  493. 

124,  329,  X. 

124,  290,  356,  493. 

1. 

124,  134. 

286,  501. 

390. 

137. 

124,  134,  329. 

124,  157,  329. 

329. 

237. 

237. 

1,  124,  329. 

124, 136,  329. 

74. 

24. 

127. 

74. 

74. 

X. 

171. 

127. 

218. 
218. 


233. 

467. 

127. 

127. 

255. 

127. 

127. 

127, 

205. 

311,  436. 

74,  438. 

74,  410,  438. 

74,  410,  438. 

X. 

171. 

60,  324,  X. 

20,  25,  95, 127,  409. 

20.  127. 

20, 25, 95, 127, 409. 

25,  409. 

269. 

20,25,202,269,286,409, 

269,  286. 

261. 

427. 

13. 

13. 

13. 

127. 

13,  298,  304. 

304. 

124, 157, 165,fX. 

34. 

34. 


697646 — i6- 


-9 


124 


UNITED   STATES   TARIFF    COMMISSION 


Table  21B. — Synthetic  organic  chemicals:  Miscellaneous  chemicals  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Chemical 


Manufacturers'  identification  num. 
bers  (according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Con. 

Melamine 

Mercury  disinfectants: 
Seed. 


All  other.. 

Mesityl  oxide  (Isopropylideneacetone) - 

Metaldehyde 

Methacrylates,  above  methyl 

Methacrylic  acid 

Methallyl  alcohol  (2-Methyl-2-propen-l-ol) 

•Methanol  (synthetic) 

Methoxymethoxyethanol -.- 

Methoxytriglycol  acetate 

Methyl  acetate --- 

Methyl  acrylate,  monomer 

Methyl  amyl  ketone .' 

Methyl  borate 

Methyl  diethanolamine.-- - 

N.N'-Methylenedialanine. 

N,N'-Methylenediglycine 

Methyl  ethyl  ketone  (2-Butanone)  (Methyl  acetone) 

Methyl  formate -- 

Methyl  hydroxyacetate 

Methyl  isobutyl  carbinol 

Methyl  isobutyl  carbinol  acetate 

Methyl  isobutyl  ketone 

Methyl  isobutyl  ketone  and  methyl  isobutyl  carbinol  and  ketone 
blend. 

Methyl  lactate 

Methyl  methacrylate 

2-Methyl-2,4-pentanediol 

Methyl  propyl  ketone  (2-Pentanone) 

Methyl  succinate 

N-Methyltaurine 

Methyl  vinyl  ether 

Monoethanolamine  sulfite 

Monoethyl-ethylmalonic  acid 

Myrcene  (7-Mcthyl-3-methylene-l,6-octadiene) 

Nitrohydroxy  compounds: 

2-Nitro-l-butanol , 

2-Nitro-2-ethyl-l,3-propanediol-- 

2-Nitro-2-methyl-l,3-propanediol 

2-Nitro-2-methyl-l-propanol 

Tris-(hydroxymethyl)nitromethane 

Nitroparaffins: 

Nitroethane 

Nitromethane 

1-Nitropropane 

2-Nitropropane 

Nonenoicacid 

Nonyl  alcohol. 

Octadecane  amide  (mixtures) 

Octadecanenitrile 

Octanol-1  (N-Capryl  alcohol). 

Octyl  oleyl  maleate 

Oleic  acid  salts: 

Aluminum  oleate 

Lead  oleate 

Oleic  chloride 

•Oxalic  acid 

Oxalic  acid  salts: 

•Ammonium  oxalate 

Ferric  ammonium  oxalate 

Ferric  sodium  oxalate 

Ferrous  oxalate 

Potassium  binoxalate 

Potassium  oxalate 

Sodium  oxalate 

Palmitic  acid  salts: 

Aluminum  palmitate 

Zinc  palmitate. 

Palmitoyl  chloride 

Paracetaldehyde 

Paraformaldehyde 

Pelargronic  acid 

Pelargonyl  chloride 

Pelviren  acid. 

•Pentaerythrito) 


69. 

127. 

127. 

74,  410. 

103. 

127. 

127. 

410. 

09,  74,  92, 103. 

127. 

74. 

74,  127,  315. 

388, 

74. 

127. 

74. 

351. 

351. 

74,  410,  X. 

127. 

127. 

74. 

74. 

74, 410. 

410. 

95. 

127,  388. 

103. 

438. 

168. 

171. 

171. 

269. 

1. 

465. 

103. 
103. 
103. 
103. 
103. 

103. 

103. 

103. 

103. 

X. 

478,  X. 

24. 

24. 

192. 

298, 

13. 

13. 

143,171. 

173,331,350,480. 

173, 269, 286, 350. 

350. 

350. 

269,  350. 

173. 

173, 350. 

173, 269, 286, 480. 

13. 

13, 495. 

171. 

315. 

39, 127, 201. 

141. 

205. 

501. 

199, 201, 459,  X. 


SYNTHETIC   ORGANIC    CHEMICALS,    1944 


125 


Table  21  B. — Synthetic  organic  chemicals:  Miscellaneous  chemicals  for  which  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Continued 


Chemical 


Manufacturers'  Identification  num- 
bers (according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Con. 

Pentaerythritol  tetranitrate 

Phorone  (Di-isobutylene  ketone) 

Phosphorus  derivatives  of  high  molecular  weight  hydrocarbons. 

o,|S-Pinene,  polymerized 

Pine  oil,  synthetic. - - 

♦Plasticizcrs.    See  table  20B. 

Polyethylene 

Polypropylene  glycol - 

Propionaldehyde 

Propionic  acid '. -.- 

Propionic  acid  salts: 

Calcium  propionate 

Sodium  propionate --- 

Propionic  anhydride -. 

Propionyl  chloride.. 

n-Propyl  acetate 

n-Propyl  alcohol  (Propanol) 

Propylene 

Propylene  chlorohydrin 

Propylene  glycol - 

Propylene  glycol  glucoside -.. 

Propylene  oxide 

Propyl  mercaptan  (1-Propanethiol) 

Pyruvic  acid 

Research  chemicals 

Saccharic  acid 

Saccharic  acid,  calcium  salt 

Sarcosine 

Sebacic  acid 

Semicarbqzide  hydrochloride - 

Sodium  ethoxide 

Sodium  methylate 

Sodium  oxalacetate 

Sorbitol 

Starch  solution,  hydrogenated.. 

•Stearic  acid  salts: 

Aluminum  stearate: 

Mono .- 

*Di.... 

*Tri 

Ammonium  stearate 

Barium  stearate 

*Calcium  stearate 

Copper  stearate - 

Cupric  stearate 

Iron  stearate 

Lead  stearate. 

*Maguesium  stearate - 

*Zine  stearate 

Stearoyl  chloride 

Stcaryl  peroxide 

Succinic  acid - 

Succinichlorimide 

Succinic  anhydride 

Succinimide 

Sulfoacetic  acid 

Sulfonated  thiocarbanilide 

Sulfurized  thialkene  vrax  olefins.. 

♦Surface-active  asents.    See  table  19B. 
Tartaric  acid  salts: 

Antimony  potassium  tartrate 

Potassium  sodium  tartrate. 

Tetraethvlene!?lycol  dimethyl  ether 

Tetraethyl  lead 

Tetramethyl  ammonium  formate 

Tetramethylethyleneclycol ..- 

Textile  chemicals,  other  than  surface-active  agents: 

Ethylaminoethylethanol-fatty-amide . 

Methylaminoethylethanol-fatty -amide 

Thioplycerol 

*Thioglycohc  acid  and  salts 

Thioglycolic  acid  anhydride 

♦Thiourea 

Triamyl  borate. 

Tribromoacetaldehyde  (Bromal) 

Tributyl  phosphite 

Triethylene  glycol.,. -- 


199, 459,  X. 

74. 

X. 

205. 
199. 

127. 
74. 
127. 
127,  X. 

127. 

127. 

74,  X. 

205. 

127, 155, 157, 168,  X. 

127. 

127. 

X. 

74, 124, 127. 

34. 

74, 124. 

417. 

69. 

65, 105, 134. 

157. 

157,  269,  350. 

171. 

192, 305. 

149, 157. 

467. 

127,  279. 

467. 

34, 350. 

205. 


164,  194,  269,  305,  486. 

13, 164, 194,  218,  209,  305, 451, 486, 495. 

13,  104,  194,  269,  305,  486,  495. 

181,  194,  305. 

164,  495. 

13,  164,  194,  269,  305,  451,  486,  495. 

194, 

486. 

194,  486. 

194,  486. 

13,  164,  194,  269,  305,  451,  486,  495. 

13,  164,  194,  269,  305,  451,  486,  495. 

171. 

X. 

304. 

304. 

134,  298,  304,  340. 

304. 

127. 

298. 

111. 


350. 

350. 

74. 

145. 

390. 

X. 

5. 

5. 

147, 

134 

137 

69, 

407, 

501. 

127. 

74,  124. 


,  147,  149,  276,  442,  501,  X. 
274,  298. 


126 


UNITED    STATES   TARIFF    COMMISSION 


Table  2 IB. — Synthetic  organic  chemicals:  Miscellaneous  chemicals  for  lohich  United 
States  production  or  sales  were  reported,  identified  by  manufacturer,  1944 — Con. 


Chemical 


Manufacturers'  identification  num- 
bers (according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

Tricthyl  orthoaoetate - 

Triethyl  orthoformate- 

TriPlhyl  ortbopropionate - - 

Triglycol  dichloride... 

Tri-isobutylene - -. - - - -- 

Tri-isopropanolfimine - -- 

•Trimethyiene  chlorohydrin 

Trimetbylene  slycol -- 

Tris-(hydroxymethyl)aminomethane.- -- 

Turpentine  sulfide 

Undecyclenic  acid... - 

Urea  (solid)  ._ 

Urea  in  solid  fertilizer 

Urea  in  urea-ammonia  solution 

Urea  in  feed  compound 

Valerolactone,  gamma. _ 

Vinyl  acetate,  monomer 

Another — - - 


134. 

229. 

131 

74. 

165. 

74. 

134,  255,  329. 

329. 

103. 

205. 

40.  X. 

127. 

127. 

127. 

127. 

298. 

127,  315. 

205,  343. 


DIRECTORY^OF  MANUFACTURERS 

In  1944  the  directory  of  manufacturers  was  compiled  from  more 
than  530  companies  producing  synthetic  organic  chemicals  which 
reported  to  the  Tariff  Commission,  compared  with  500  companies  in 
1943  and  about  300  in  the  immediate  prewar  years.  Not  all  the 
companies  wliich  report  production  to  the  Tariff  Commission  manu- 
facture synthetic  organic  chemicals  for  sale;  some  consume  their 
entire  output. 

The  directory  of  manufacturers  is  given  in  table  22. 

Table  22.— Synthetic  organic  chemicals:  Directory  of  manufacturers,  1944 

[Names  of  synthetic  organic  chemical  manufacturers  who  reported  production  and  sales  to  the  United 
States  Tariff  Commission,  1944,  or  who  are  listed  as  manufacturers  of  synthetic  organic  chemicals  in  other 
directories  or  publications  available  to  the  public.  These  companies  do  not  necessarily  produce  sjmthetie 
organic  chemicals  for  sale;  some  consume  their  entire  production  in  further  processing] 


Num- 
ber 


Name  of  company 


Office  address  (location  of  plant  given  in  parentheses  if 
not  in  same  city  as  office) 


Abbott  Laboratories... 

A.   C.   Spark   Plug  Division,   General 
Motors  Corp. 

Ad-Co  Color  Corp... 

Advance  Paint  Co 

Alframine  Corp 

Alkydol  Laboratories,  Inc.. 

Althouse  Chemical  Co 

Amalgamated  Chemical  Corp 

Amecco  Chemicals,  Inc  .._ 

American  Alkyd  Industries,  Inc 

American  Aniline  Products,  Inc 

American  Chemical  Paint  Co 

American  Cyanamid  Co 


American  Molding  Powder  &  Chemical 

Corp. 
American  Tar  &  Chemical  Co... 


American  Viscose  Corp. 


14th  St.  and  Sheridan  Rd.,  North  Chicago,  lU. 
1300  N.  Dort  Highway,  Flint  2,  Mich. 

66  Lister  Ave.,  Newark  5,  N.  J. 

545  W.  Abbott  St.,  Indianapolis  7,  Ind. 

155  E.  44th  St.,  New  York  17,  N.  Y.    (Paterson  4, 

N.  J.). 
3242  S.  50th  Ave.,  Cicero  50,  111. 
540  Pear  St.,  Reading,  Pa. 
Ontario  and  Rorer  Sts.,  Philadelphia  34,  Pa. 
75  Rockwood  St.,  Rochester  10,  N.  Y. 
Broad  and  14th  St.,  Carlstadt,  N.  J. 
50  Union  Square,  New  York  3,  N.  Y.    (Lock  Haven 

Pa.). 
Brookside  Ave.,  Ambler,  Pa. 
30  Rockefeller  Plaza,  New  York  20,  N.  Y.  (Azusa, 

Calif.;  Bound  Brook,    Warners    and    Woodbridge, 

N.  J.;  Bridgeville,  Pa.;  Charlotte,  N.  C;  Wallingford, 

Conn.;  and  Pearl  River,  N.  Y.). 
44  Hewes  St.,  Brooklyn  11,  N.  Y 

2240  Sun  Life  Bldg.,  Montreal  2,   Canada    (Duluth, 

Minn.). 
Delaware  Trust  Bldg.,  Wilmington  99,  Del.    (Mead- 

ville,  Pa.)  I 


SYNTHETIC   ORGANIC    CHEMICALS,    1944 


127 


Table  22. — Synthetic  organic  chemicals:  Directory  of  manufacturers,  1944 — 

Continued 


Name  of  company 


Oflico  address  Gocaf.ion  of  plant  given  in  parentheses  If 
not  in  same  city  as  office) 


Amino  Products  Division,  International 
Minerals  &  Chemical  Corp. 

Ansbacher-Siegle  Corp 

Ansul  Chemical  Co 

Apex  Chemical  Co.,  Inc 


Appleton  Coated  Paper  Co 

Arco  Co 

Arkansas  Co.,  Inc 

Armour  Chemical  Division,  Armour  & 
Co. 

Armstrong,  C.  M.,  Inc 

Armstrong  Cork  Co... 

Armstrong  Paint  &  Varnish  Works 

Arnold,  HoSman  &  Co.,  Inc 

Asociacion  Azucarera  Cooperative  La- 
fayette. 

Associated  Chemists,  Inc 

Atlantic  City  Gas  Co. 

Atlantic  RefinLng  Co 


Atlas  Oil  &  Refining  Corp. 
Atlas  Powder  Co - 


Atlas  Refinery,  Inc 

Atlas  Wall  Paper  Mills,  Inc 

Augusta  Chemical  Co 

Ault  &  Wiborg  Division,  Interchemical 

Corp. 
Bakelite  Corp 


Baker  Castor  Oil  Co 

Baker,  J.  T.,  Chemical  Co 

Baker  Oil  Tools,  Inc 

Barrett   Division,   Allied    Chemical   & 
Dye  Corp. 


Bates  Chemical  Co.,  Inc 

Bayer  Co.  Division,  Sterling  Drug  Co... 

Beaudry  Wall  Paper  Corp 

Belle  Alkali  Co 

Bonzol  Products  Co 

Berk,  F.  W.,  &  Co.,  Inc 

Berkeley  Chemical  Corp 

Berry  Brothers,  Inc 

Bcrsworth,  F.  C.,  Laboratories 

Bick  &  Co.,  Inc 

Birge  Co.,  Inc 

Blackstone  Valley  Gas  &  Electric  Co 

Boston  Consolidated  Qas  Co 

Breon,  Geo.  A.,  &  Co 

Bridgeport  Gas  Light  Co 

Brooklyn  Borough  Gas  Co 

Brooklyn  Color  Works,  Inc 

Brooklyn  Union  Gas  Co 

Brown  Co 

Brown,  Andrew,  Co 

Bnrkart-Schier  Chemical  Co 

Burroughs  Wellcome  &  Co.,  Inc 

Bush,  Burton  T.,  Inc 

Bush,  W.  J.,  &  Co.,  Inc 

Cahot,  Samuel,  Inc 

Calco    Chemical    Division,    American 
Cyanamid  Co. 

California  Flaxseed  Products  Co 

California  Ink  Co.,  Inc 

Cambridge  Gas  Light  Co 

Capitol  Paint  &  Varnish  Works,  Inc 

Carbide  &  Carbon  Chemical  Corp 

Carlsen,  John  G.,  &  Co , 

Carlson,  John  P.,  Inc 1 

Camrick,  O.  W.,  Co 

Carus  Chemical  Co.,  Inc 


20  N.  Wacker  Drive,  Chicago,  111. 

92  Chestnut  Ave.,  Rosebank,  Staten  Island,  N.  Y. 

P.  O.  Box  231,  Marinette.  Wis. 

225  W.  34th  St.,  New  York  1,  N.  Y.    (Elizabethport, 

N.  J.). 
1200  N.  Meade  St.,  Appleton,  Wis. 
7301  Bessemer  Ave.,  Cleveland  4,  Ohio. 
185  Foundry  St.,  Newark  5,  N.  J. 
1355  W.  31st  St.,  Chicago  9,  111. 

9  E.  46th  St.,  New  York,  N.  Y. 

Lancaster,  Pa.    (Pittsburgh,  Pa.). 

1330  S.  Kilbourne  St.,  Chicago  23,  HI. 

55  Canal  St.,  Providence  1,  R.  I.    (Dighton,  Mass.). 

342  Madison  Ave.,  New  York  17,  N.  Y.     (Arroyo, 

P    R  ) 
North  Collins.  N.  Y. 

80  Park  PI.,  Newark  1,  N.  J.  (Atlantic  City,  N.  J.). 
260  S.  Broad  St.,  Philadelphia  1,  Pa.  (Port  Arthur, 

Tex.). 
P.  O.  Box  1007,  Shreveport,  La. 
9th  and  Market  Sts.,  Wilmmgton  99,  Del.  (Reynolds, 

Pa.,  and  Atlas  Point,  Del.). 
142  Lockwood  St.,  Newark  5,  N.  J. 
Coal  City,  111. 

P.  O.  Box  660,  Augusta,  Oa. 
1754  Dana  Ave.,  Cincinnati  7,  Ohio. 

30  E.  42d  St.,  New  York  17,  N.  Y.  (Bound  Brook  and 
Bloomfield,  N.  J.). 

120  Broadway,  New  York  5,  N.  Y.  (Bayonno,  N.  J.), 

PhilhDSburg,  N.  J. 

6000  Boyle  Ave.,  Los  Angeles  11,  Calif. 

40  Rector  St.,  New  York  6,  N.  Y.  (Bethlehem,  Frank- 
ford,  and  Philadelphia,  Pa.;  Bufl'alo,  Rochester, 
Syracuse,  and  Troy,  N.  Y.;  Chicago,  111.;  Cincinnati, 
Cleveland,  Toledo,  and  Youngstown,  Ohio;  Detroit, 
Mich.;  Edgewater,  N.  J.;  FairQeld,  Ma.;  Maiden, 
Mass.;  Minneapolis,  Minn.;  St.  Louis,  Mo.;  and 
Savannah,  Ga.). 

Scottdale  Rd.,  Lansdowne,  Pa. 

170  Varick  St.,  New  York  13,  N.  Y.  (Rensselaer,  N.  Y.), 

46  Elm  St.,  Cortland,  N.  Y. 

P.  O.  Box  615,  Belle,  W.  Va. 

237  South  St.,  Newark  5,  N  J.  (Piscataway,  N.  J.). 

Railroad  Ave.,  Wood-Ridge,  N.  J. 

942  Summit  Ave.,  Berkeley  Heights,  N.  J. 

211  Leib  St.,  Detroit  7.  Mich. 

609  Waverly  St.,  Framingham,  Mass. 

1820  N.  12th  St.,  Readmg,  Pa. 

390  Niagara  St.,  Bufialo  1,  N.  Y. 

55  High  St.,  Pawtucket,  R.  I. 

100  Arlington  St.,  Boston  16,  Mass.   (Everett,  Mass.). 

2000  Baltimore  Ave.,  Kansas  City,  Mo. 

815  Main  St.,  Bridgeport  1,  Conn. 

17th  St.  and  Mermaid  Ave.,  Brooklyn  24,  N.  Y. 

Morgan  and  Norman  Aves.,  Brooklyn  22,  N.  Y. 

176  Remsen  St.,  Brooklyn  2,  N.  Y. 

650  Main  St.,  Berlin,  N.  H. 

5431  South  Riverside  Dr.,  Los  Angeles,  Calif. 

1202  Chestnut  St.,  Chattanooga  2,  Tenn. 

9  E.  41st  St.,  New  York  17,  N.  Y.  (Tuckahoc,  N.  Y.). 

201  Delawanna  Ave.,  Delawanna,  N.  J. 

11  E.  38th  St.,  New  York  10,  N.  Y.  (Linden,  N.  J.). 

141  Milk  St.,  Boston  9,  Mass.  (Chelsea,  Mass.). 

Bound  Brook,  N.  J.  (Newark,  N.  J.,  and  Damascus, 
Va.). 

3135  E.  26th  St.,  Los  Angeles  23,  Calif. 

545  Sansome  St.,  San  Francisco  11,  Calif.  {Berkeley, 
Calif.). 

354  3d  St.,  Cambridge  42,  Mass. 

47-55  Rodney  St.,  Brooklyn  11,  N.  Y. 

30  E.  42d  St.,  New  York  17,  N.  Y.  (South  Charleston, 
W.  Va.;  Niagara  Falls,  N.  Y.;  Whiiing,  Ind.;  Texas 
City,  Tex.;  Institute,  W.  Va.;  and  Louisville,  Ky.). 

1446  W.  Kenzic  St.,  Chicago  22,  111. 

420  Carroll  St.,  BrookljTi  15,  N.  Y. 

20  Mt.  Pleasant  Ave.,  Newark  4,  N-  J. 

1335  8th  St.,  La  SaUe,  III 


128 


UNITED   STATES   TARIFF    COMMISSION 


Table  22. — Synthetic  organic  chemicals:  Directory  of  manufacturers,  1944 — 

Continued 


Num- 
ber 


Name  of  company 


Office  address  (location  of  plant  given  in  parentheses  If 

not  in  same  city  as  office) 


79 
80 

81 

82 

83 

84 

85 
86 
87 
88 
89 
90 
91 

92 

93 

94 
95 
96 
97 
98 
99 
100 
101 
102 

103 

104 
105 
106 

107 
108 

109 

110 
111 
112 

113 

114 
115 

116 
117 
118 
119 
120 

121 
122 
123 
124 
125 
126 
127 


128 
129 
130 
131 
132 
133 
134 
135 
136 
137 
138 


Carwin  Co 

Casein  Co.  of  America  Division,  Borden 
Co. 

Cotalin  Corp.  of  America 

Celaneso  Corp.  of  America 

Central  Hudson  Gas  &  Electric  Corp — 

Central  Process  Corp 

Chemical  Manufacturing  Co.,  Inc 

Chemical  Specialties,  Inc 

Chemico,  Inc-.. 

Chemo  Puro  Manufacturing  Corp 

Childs  Pulp  Colors,  Inc 

Ciba  Pharmaceutical  Products,  Inc 

Cincinnati  Chemical  WorKs,  Inc 

Cities  Service  OU  Co 

Cities  Service  Refining  Co 

Citro  Chemical  Co 

Clinton  Co. 

Coastwise  Petroleum  Co 

Coca-Cola  Co 

Colasta  Co.,  Inc 

Coleman  &  Bell  Co.,  Inc.. 

Colgate-Palmolive-Peet  Co 

Collway  Colors,  Inc 

Colt's  Patent  Fire  Arms  Manufacturing 

Co. 
Commercial  Solvents  Corp 

Commonwealth  Color  &  Chemical  Co-.. 

Connecticut  Hard  Rubber  Co 

Connecticut  Light  &  Power  Co 

Connecticut  Power  Co 

Consolidated  Edison  Co.  of  New  York, 

Inc. 
Consolidated    Gas    Electric    Light    & 

Power  Co.  of  Baltimore. 

Continental-Diamond  Fibre  Co 

Continental  Oil  Co 

Cook  Paint  &  Varnish  Co.- -.. 

Cooks  Falls  Dye  Works 

Coopers  Creek  Chemical  Corp 

Crown  Tar  Works,  Division  of  Colorado 
Public  Service. 

Debruille  Chemical  Corp.. .- 

Dennis,  Martin,  Co 

Detroit  Edison  Co 

Dewey  &  Almy  Chemical  Co 

Diamond  Alkali  Co 

Diar.senol  Co.,  Inc.. 

Distillation  Products,  Inc 

Dodge  &  Olcott  Co 

Dow  Chemical  Co 

Dow  Corning  Corp 

Dubin,  H.  E.,  Laboratories,  Inc 

DuPont  de  Nemours,  E.  I.,  &  Co.,  Inc. 


Durez  Plastics  &  Chemicals,  Inc 

Durite  Plastics,  Inc 

Dye  Specialties  Corp 

Dykem  Co 

Eakins,  J.  S.  &  W.  R.,  Inc 

Eastern  Tar  Products  Corp 

Eastman  Kodak  Co 

Edcan  Laboratories 

Edison,  Thomas  A.,  Inc.. 

Edwal  Laboratories,  Inc 

Electro  Technical  Products,  Inc- 


1310  W.  Elizabeth  Ave.,  Linden,  N.  J. 

350  Madison  Ave.,  New  York  17,  N.  Y.  (Bainbridge, 

N.  Y.,  and  Seattle,  Wash.). 
Meadow  Road,  Fords,  N.  J. 

150  Madison  Ave.,  New  York  16,  N.  Y.  (Amcelle, 
Md.;  Celco,  Va.;  and  Newark,  N.  J.). 

South   Road,  Poughkeepsie,  N.  Y.  (Newburgh  and 

Kingston,  N.  Y.). 
1900    Lnion    Commerce    Bldg.,    Cleveland   14,    Ohio 

(Forest  Park,  111.). 
Ashland,  Mass. 

151  N.  Centennial  St.,  Zeeland,  Mich, 
1745  Front  St.,  Cuyaho;^a  Falls,  Ohio. 

48th  A\e.  and  5th  St.,  Long  Island  City  1,  N.  Y. 

43  Summit  St.,  Brooklyn  31,  N.  Y. 

Lafayette  Park,  Summit,  N.  J 

P.  O.  Bo.x  20,  Evanston  Station,  Cinciimati  7,  Ohio 

(Norwood  and  St.  Bernard.  Ohio). 
Masonic-Empire  Bldg.,  Bartlesville,  Okla.   (Tallant, 

(Okla.) 
Lake  Charles,  La. 
Maywood  Ave.,  Mavwood,  N.  J. 
P.  O.  Box  340,  Clinton,  Iowa. 

1127  Munsey  Bide,  Baltim.ore2,  Md.  (Goodhope,  La.) 
310  North  .A.ve.,  Atlanta  1,  Ga. 
1  Mechanic  St.,  Hoosick  Falls,  N.  Y. 
4101  Main  St..  Norwood,  Ohio. 
105  Hudson  St.,  Jersev  City  2,  N.  J. 
15  Market  St.,  Paterson.  N.  J. 
17  Van  Dyke  Ave.,  Hartford  15,  Conn. 

17  E.  42d  St.,  New  York  17,  N.  Y.  (Peoria,  111.;  Terre 
Haute,  Ind.;  Harvev,  La.;  and  Agnew,  Calif.). 

223  Nevins^t.,  Brooklyn  17,  N.  Y. 

407  East  St..  New  Haven  9,  Conn. 

36  Pearl  St.,  Hartford  1,  Conn.  (Norwalk,  Putnam, 
Waterbury,  Willimantie,  and  Winsted,  Conn.). 

31  Union  St.,  New  London,  Conn.  (Stamford,  Conn.). 

4  Irving  PI.,  New  York  3,  N.  Y. 

Lexington  Bldg.,  Baltimore,  Md. 

70  S.  Chapel  St.,  Newark,  Del.  (Bridgeport,  Pa.). 

1000  S.  Pine  St.,  Ponca  City,  Okla. 

P.  O.  Box  389,  Kansas  City  10,  Mo.  (Detroit,  Mich., 

and  Houston,  Tex.).  • 
Cooks  Falls,  N.Y. 

River  Road,  West  Conshohocken,  Pa. 
900  15th  St.,  Denver  2,  Colo. 

1841  Broadway,  New  York  23,  N.  Y. 

859  Summer  Ave.,  Newark  4,  N.  J. 

2000  2d  Ave.,  Detroit  26,  Mich.  (Marysville,  Mich.). 

62  Whittemore  Ave.,  Cambridge  40,  Mass. 

535  Smithfield  St.,  Pittsburgh  22,  Pa.  (Painesville, 
Ohio). 

72  Kinesley  St.,  Buffalo  8,  N.  Y. 

755  Ridge  Rd.  W.,  Rochester  13,  N.  Y. 

180  Varick  St.,  New  York  14,  N.  Y.  (Bayonne,  N.  J.). 

Midland,  Mich.  (Pittsburg,  Calif.,  and  Freeport,  Tex.). 

Midland,  Mich. 

250  E.  43d  St.,  New  York  17,  N.  Y. 

10th  and  Market  Sts.,  Wilmington  98,  Del.  (Carneys 
Point,  New  Brunswick;  Perth  Amboy,  Arlington, 
and  Newark,  N.  J.;  Waynesboro  and  Martinsville, 
Va.;  Scaford,  Del.;  Leominster,  Mass.;  Belle  and 
Moundsville,  W.  Va.:  Niagara  Falls,  N.  Y.;  El  Monte, 
Calif.;  and  Wyandotte,  Mich.). 

Walck  Road,  North  Tonawanda  4,  N.  Y. 

5000  Summerdale  Ave.,  Philadelphia  24,  Pa. 

924  Bergen  Ave.,  Jersey  City  0,  N.  J. 

2307  North  11th  St.,  St.  Louis  6,  Mo. 

55  Berry  St.,  Brooklyn  11,  N.  Y. 

605  Lexington  Bldg.,  Baltimore  1,  Md. 

343  State  St..  Rochester  4.  N.  Y. 

10  Pine  St.,  South  Norwalk,  Conn. 

P.  O.  Box  45,  Bloomfield,  N.  J. 

732  Federal  St.,  Chicago  5,  111.  (Ringwood,  111.). 

113  E.  Centre  St.,  Nutley  10,  N.  J. 


SYNTHETIC   ORGANIC    CHEMICALS,    1944 


129 


Table  22. — Synthetic  organic  chemicals:  Directory  of  manufacturers ,  1944 — 

Continued 


Name  of  company 


Office  address  (location  of  plant  given  in  parentheses  if 
not  in  same  city  as  office; 


Elizabethtown  Consolidated  Gas  Co. 

Elko  Chemical  Works,  Inc 

Emery  Industries,  Inc 


Empire  Chemical  Co.,  Inc- 

Emulsol  Corp 

Endo  Products,  Inc 

Ethyl  Corp 


Ethyl-Dow  Chemical  Co 

Evans  Chemetics,  Inc.. 

Factor,  Max,  &  Co 

Fairmount  Chemical  Co.,  Inc 

Falk  &  Co 

Fall  River  Gas  Works  Co 

Farley  &  Loetscher  Manufacturing  Co. 

Federal  Color  Laboratories,  Inc 

Federal  Laboratories,  Inc 

Felton  Chemical  Co.,  Inc 

Ferbert-Schorndorfer  Co 

Fine  Organics,  Inc 

Firestone  Tire  &  Rubber  Co 

Fitehburg  Gas  &  Electric  Light  Co 

Forbes  Varnish  Co.. 

Ford  Motor  Co 


Foster-Heaton  Co 

France,  Campbell  &  Darling,  Inc 

Franks  Chemical  Products  Co.,  Inc. 

Fries  Bros.,  Inc. 

Fries  &  Fries,  Inc... 


Fries,  George  G.,  &  Co.,  Inc 

Fritzsche  Bros.,  Inc 

Gane's  Chemical  Works,  Inc 

Gelatin  Products  Corp 

General  Aniline  Works  Division,  Gen- 
eral Aniline  &  Film  Corp. 

General  Biochemicals,  Inc 

General  Chemical  Co 


General  Color  Co 

General  Electric  Co 

General  Foods  Corp 

General  Mills,  Inc 

George,  P.  D.,  Co 

Gilman  Paint  &  Varnish  Co. 

GliddenCo 

Glyco  Products  Co.,  Inc 

Goodrich,  B.  F.,  Co 


Goodyear  Tire  &  Rubber  Co 

Grand  Rapids  Varnish  Corp 

Gulf  Oil  Corp 

Guyan  Color  &  Chemical  Works 

Hall,  C.  P.,  Co 

Halowax  Products  Division,  Union  Car- 
bide &  Carbon  Corp. 

Hamilton  Laboratories,  Inc 

Hampden  Color  &  Chemical  Co 

Harbor  Plvwood  Corp 

Hardesty,  W.  C,  Co.,  Inc 

Harmon  Color  Works,  Inc 

Harshaw  Chemical  Co 


Hart  &  Harrington,  Inc 

Hartman-Leddon  Co.,  Inc. 
Hart  Products  Corp 


Hema    Drug    Co.,    Inc.. 
Hercules  Powder  Co.,  Ine. 


Heresite  and  Chemical  Co. 
Heyden  Chemical  Corp 


Hilton-Davis  Chemical  Co 

Hoffman- LaRoche,  Inc 

Holland  Color  &  Chemical  Co. 
Hooker  Electrochemical  Co 


16  W.  Jersey  St.,  Elizabeth  4,  N.  J. 
60  E.  42d  St.,  New  York  17,  N.  Y.  (Pittstown,  N.  J.). 
4300  Carew  Tower,  Cincinnati  2,  Ohio  (St.  Bernard. 
Ohio). 

399  Codwise  Ave.,  New  Brunswick,  N.  J, 
59  E.  Madison  St.,  Chicago  3,  111. 

84-40  101st  St.,  Richmond  Hill  18,  N.  Y. 

405  Lexington  Ave.,  New  York  17,  N.  Y.  (Deepwater, 

N.  J.,  and  Baton  Rouge,  La.). 
Midland,  Mich.  (Vv^ilmington,  N.  C;  Freeport,  Tex.). 
250  E.  43d  St.,  New  York  17,  N.  Y.  (Waterloo,  N.  Y.)- 
1666  N.  Highland  Ave.,  Los  Angeles  28,  Calif. 
600  Ferry  St.,  Newark  5,  N.  J. 
P.  O.  Box  1075,  Pittsburgh  30,  Pa.  (Carnegie,  Pa.)i 
155  N.  Main  St.,  Fall  River,  Mass. 
7th  and  White  Sts.,  Dubuque,  Iowa. 
4633  Forest  Ave.,  Cincinnati  12,  Ohio. 
185  41st  St.,  Pittsburgh  1,  Pa. 
599  Johnson  Ave.,  Brooklyn  6,  N.  Y. 
12815  Elmwood  Ave.,  Cleveland  11,  Ohio. 
211  E.  19th  St.,  New  York  3,  N.  Y.  (Lodi,  N.  J.). 
1200  Firestone  Parkway,  Akron  17,  Ohio, 
89  Broad  St.,  Boston  10,  Mass. 
3800  W.  143d  St.,  Cleveland  11,  Ohio, 
3000  Schaefer  Rd.,  Dearborn,  Mich.  (Iron  Mountain 

and  Kingsford,  Mich.). 
16  E.  5th  St.,  Paterson  4,  N.  J. 
Michigan  Ave.  and  Monroe  St.,  Kenilworth,  N.  J. 
55  33d  St.,  Brooklyn  32,  N.  Y. 

92  Reade  St.,  New  York  13,  N.  Y.  (Bloomfield,  N.  J.), 
13  E.  37th  St.,  New  York  16,  N.  Y.  (Cincinnati  16, 

Ohio). 
11-25  44th  Rd.,  Long  Island  City  1,  N.  Y. 
76  9th  Ave.,  New  York  11,  N.  Y.  (Clifton.  N.  J.). 
43  W.  16th  St.,  New  York  11,  N.  Y.  (Carlstadt,  N,  J,). 
9425  Grinnell  Ave.,  Detroit  13,  Mich. 
435  Hudson  St.,  New  York  14,  N.  Y.  (Grasselli,  N,  J. 

and  Rensselaer.  N.  Y.). 
Laboratory  Park,  Chagrin  Falls,  Ohio. 

40  Rector  St.,  New  York  6,  N.  Y.  (Buffalo,  N.  Y.; 
Marcus  Hook,  Pa.;  and  Edgewater,  N.  J.). 

24  Avenue  B,  Newark  5,  N.  J. 

1  River  Road,  Schenectady  5,  N.  Y.  (Pittsfield.Mass.), 

250  Park  Ave.,  New  York  17,  N.  Y.  (Hoboken,  N.  J.). 

400  S.  4th  St.,  Minneapolis  15,  Minn.  (Keokuk,  Iowa). 
500  N.  2d  St.,  St.  Louis  7,  Mo. 

W.  8th  and  Pine  Sts.,  Chattanooga  1,  Tenn. 

11001  Madison  Ave.,  Cleveland  2,  Ohio  (Chicago,  111.). 

26  Court  St.,  Brooklyn,  N.  Y. 

500  S.  Main  St.,  Akron  18,  Ohio  (Niagara  Falls,  N.  Y., 

and  Louisville,  Ky.). 
1144  E.  Market  St.,  Akron  16,  Ohio. 
565  Godfrey  Ave.,  SW.,  Grand  Rapids  2,  Mich. 
Gulf  Bldg.,  Pittsburgh,  Pa. 
Box  1088,  Huntington,  W.  Va. 
2510  First-Central  Tower,  Akron  8,  Ohio. 
30  E.  42d  St.,  New  York  17,  N.  Y.  (Wyandotte,  Mich.) 

120  Patton  Ave.,  Asheville,  N.  C. 
161  Armory  St.,  Springfield,  Mass. 
Hoquiam,  Wash.  (Aberdeen,  Wash.). 

41  E.  42d  St.,  New  York,  N.  Y.  (Dover,  Ohio). 
P.  O.  Box  1158,  Paterson,  N.  J.  (Haledon,  N.  J.). 
1945  E.  97th  St.,  Cleveland  6,  Ohio  (Elyria,  Ohio, 

and  Philadelphia,  Pa.). 
925-929  W.  Weed  St.,  Chicago  22,  111. 
6010  Haverford  Ave.,  Philadelphia  31,  Pa. 
1440  Broadway,  New  York  18,  N,  Y.  (Woodbridge, 

N.J.). 
66-38    Clinton    Ave.,    Maspeth,    N.    Y. 
900  Market  St.,  Wilmington  99,  Del.  (Parlin,  N.  J., 

and  Hopewell,  Va.). 
822  S.  14th  St.,  Manitowoc,  Wis. 
393  7th  Ave.,  New  York  1,  N.  Y.  (Fords  and  Garfield, 

N.J.). 
2235  Langdon  Farm  Rd.,  Cincinnati  12,  Ohio. 
324-424  Kingsland  Rd.,  Nutley  10,  N.  J. 
P.  O.  Box  1001,  Holland,  Mich. 
Bufialo  Ave.  and  47th  St.,  Niagara  Falls,  N.  Y. 


130 


UNITED   STATES   TARIFF    COMMISSION 


Table  22. — Synthetic  organic  chemicals:  Directory  of  manufacturers,  1944- 

Continued 


Name  of  company 


Office  address  (location  of  plant  Riven  in  parentlieses  if 
not  in  same  city  as  office) 


Houghton,  E.  F.,  &  Co 

Huggins,  James,  &  Son 

Humble  Oil  &  Refining  Co 

Huron  Milling  Co 

Hyear  Chemical  Co... 

HynsoD,  Westcott  &  Dunning,  Inc 

Imperial  Paper  &  Color  Corp 

Industrial  DyestufE  Co 

Inland  Alkaloid  Co - 

Innis,  Speiden  &  Co. 

Inter-Coastal  Paint  Corp 

Interlake  Chemical  Corp 

International  Lubricant  Corp 

Ironsides  Co 

Irvington  Varnish  &  Insulator  Co 

Jamestown  Paint  &  Varnish  Co. 

Jamicson,  C.  E.,  &  Co 

Jennison-Wright  Corp 

Jersey  Central  Power  &  Light  Co 

Johnson,  Charles  Eneu,  &  Co - 

Johnson,  S.  C,  &  Son,  Inc_.. 

Jones-Dabncy  Co.  Division  of  Devoe  & 
Reynolds  Co.,  Inc. 

Kay  &  Ess  Co 

Kay-Fries  Chemicals,  Inc 

Keery,  Thomas,  Co.,  Inc 

Kennecott  Copper  Corp.,  Chine  Mines 
Division. 

Kentucky  Color  &  Chemical  Co.. 

Kessler  Chemical  Co.,  Inc 

Keto  Chemical  Co.,  Inc. .- - 

Keystone  Color  Works,  Inc 

Keystone  Varnish  Co..- 

Kinetic  Chemicals,  Inc_ 

Kings  County  Lighting  Co. 

Knoedler,  A.,  Co 

Kohnstamm,  H.,  &  Co.,  Inc 

Koppers  Co 


Krumbhaar  Chemicals,  Inc 

Lakeside  Laboratories,  Inc 

Lamex  Chemical  Corp 

LaMotte  Chemical  Products  Co 

Laucks,  Inc 

Laucks,  I.  F.,  Inc 

Leatex  Chemical  Co 

Lehigh  Briquetttng  Co 

Lennig,  Charles,  &  Co 

Lever,  C,  Co.,  Inc 

Levey,  Frederick  H.,  Co.,  Inc... 

Lewis,  John  T.,  &  Bros.  Co 

Lewis  Tar  Products  Co 

Lilly,  Eli,  &  Co 

Lion  Oil  Refining  Co... 

Liquid  Carbonic  Corp 

Long,  Charles  R.,  Jr.,  Co.,  Inc.. 
Long  Island  Lighting  Co 

Lowell  Gas  Light  Co 

Lucidol  Corp 

Lueders,  George,  &  Co... 

Maas  &  Waldstein  Co 

Madison  Gas  &  Electric  Co 

Magnolia  Petroleum  Co 


303  W.  Lehigh  Ave.,  Philadelphia  33,  Pa. 

239  Medford  St.,  Maiden  48,  Mass. 

Humble  Bldg.,  Houston  1,  Tex.  (Baytown  and  Ingle- 
side,  Tex.). 

9  Park  Pi.,  New  York,  N.  Y. 

335  S.  Main  St.,  Akron,  Ohio. 

1030  N.  Charles  St.,  Baltimore  1,  Md. 

Glens  Falls,  N.  Y. 

Massasoit  Ave.,  East  Providence,  R,  I. 

Tiptou,  Ind. 

117  Liberty  St.,  New  York  6,  N.  Y.  (Niagara  Falls, 
N.  Y.  ). 

1248  Walnut  Ave.,  East  St.  Louis,  El. 

1900  Union  Commerce  Bldg.,  Cleveland  14,  Ohio  (Chi- 
cago, 111.). 

P.  O.  Box  390,  New  Orleans  1,  La. 

270  W.  Mound  St.,  Columbus  16,  Ohio. 

6  Argyle  Ter.,  Irvington  11,  N.  J. 

Jamestown,  Pa. 

1952-1980  Trombly  Ave.,  Detroit  11,  Mich. 

2463  Broadway,  Toledo  1,  Ohio. 

501  Grand  Ave.,  Asbury  Park,  N.  J.  (Long  Branch, 
Dover,  Belmar,  Toms  River,  Ocean  City,  and  Wild- 
wood,  N.  J). 

lOth  and  Lombard  Sts.,  Philadelphia  47,  Pa. 

1535  Howe  St.,  Racine,  Wis. 

1481  S.  nth  St.,  Louisville  8,  Ky. 

825  Kisor  St.,  Dayton  1,  Ohio. 

180  Madison  Ave.,  New  York  16,  N.  Y.  (West  Haver- 
straw,  N.  Y.). 
Cado.sia,  N.  Y. 
Hurley,  N.  Mex. 

600  N.  34th  St.,  Louisville  12,  Ky. 

State  Rd.  and  Cottman  Ave.,  Philadelphia  35,  Pa. 

40-33  23d  St.,  Long  Island  City  1,  N.  Y. 

151  W.  Gay  Ave.,  York.  Pa. 

71  Otsego  St.,  Brooklyn  31,  N.  Y. 

duPont  Bldg.,  Wilmington 98,  Del.  (East  Chicago,  111., 
and  Penn's  Neck,  N.  J.). 

6740  4th  Ave.,  Brooklyn  20,  N.  Y. 

651  High  St.,  Lancaster,  Pa. 

83-93  Park  PI.,  New  York  7,  N.  Y.  (Brooklyn,  N.  Y.). 

430  7th  Ave..  Pittsburgh  19,  Pa.  (Buffalo  and  Utica, 
N.  Y.;  Hamilton  and  Youngstown,  Ohio;  Chicago, 
111.;  Everett,  Mass.;  Kearny,  N.  J.;  New  Haven, 
Conn.;  St.  Louis,  Mo.;  St.  Paul,  Minn.;  Woodward, 
Ala.;  Swedcland,  Pa.;  Houston,  Tex.;  Carrollville, 
Wis.;  FoUansbee,  W.  Va.;  and  East  Providence, 
R.  I.). 

24-30  Jacobus  Ave.,  South  Kearny,  N.  J. 

1707  E.  North  Ave.,  Milwaukee  1,  Wis. 

19  W.  44th  St.,  New  York  18,  N.  Y. 

McCormick  Bldg.,  Baltimore,  Md.  (Towson,  Md.). 

Lockport,  N.  Y. 

911  Western  Ave.,  Seattle  4,  Wash. 

2722  N.  Hancock  St.,  Philadelphia  33,  Pa. 

First  National  Bank  Bldg.,  Dickinson,  N.  Dak.  (Le- 
high, N.  Dak.). 

222  W.  Washington  Sq.,  Philadelphia  5,  Pa.  (Brides- 
burg,  Pa.). 

Howard  and  Huntingdon  Sts.,  Philadelphia  33,  Pa. 

41  E.  42d  St.,  New  York  17,  N.  Y.  (Brooklyn,  N.  Y.) 

910  Wideuer  Bldg.,  Philadelphia  7,  Pa. 

P.  O.  Box  A,  Lyons,  111.  (McCook,  111.). 

740  S.  Alabama  St.,  Indianapolis  6,  Ind. 

Exchange  Bldg.,  El  Dorado,  Ark. 

2929  E.  C7th  St.,  Cleveland  4,  Ohio. 

1630  W.  Hill  St.,  Louisville  10,  Ky. 

250  Old  Country  Rd.,  Mineola,  N.  Y.  (Bay  Shore, 
N.  Y.). 

22  Shattuck  St.,  Lowell,  Mass. 

1740  Military  Rd.,  Buffalo  5,  N.  Y. 

427  Washington  St.,  New  York  13,  N.  Y.  (Brooklyn, 
N.  Y.). 

438  Riverside  Ave.,  Newark  4,  N.  J. 

100  N.  Fairchild  St.,  Madison  1,  Wis. 

P.  O.  Box  900,  Dallas  1,  Tex.  (Beaumont,  Tex.). 


SYNTHETIC    ORGANIC    CHEMICALS,    1944 


131 


Table  22. — Synthetic  organic  chemicals:  Directory  of  manufacturers,  1944 — 

Continued 


Name  of  company 


Office  address  (location  of  plant  given  in  parentheses  it 
not  in  same  city  as  office) 


Magruder  Color  Co.,  Inc 

Makalot  Corp 

Mallard,  A.  E.,  Laboratories,  Inc.. 

Mallinckrodt  Chemical  Works 

Maltbie  Chemical  Co 

Marblette  Corp 

Marco  Chemicals,  Inc 

Mardon  Wild  Corp 

Marietta  Dyestuffs  Co - 

Marietta  Paint  &  Color  Co. 

Martin  Laboratories 

Marx,  Max,  Color  &  Chemical  Co- 

Maschmeijer,  A.,  Jr.,  Inc 

Mathieson  Alkali  Works,  Inc 

Maxim  Chemical  Co.,  Inc 

May,  Otto  B.,  Inc 

Maywood  Chemical  Works 

Mead,  Johnson  &  Co -. 


MearlCorp- 


Mepham,  George  S.,  Corp. 
Merck  &  Co.,  Inc 


Merrell,  Wm.  S.,  Co 

Metropolitan  Edison  Co 

Metropolitan  Utilities  Co 

Michigan  Chemical  Corp 

Midland  Industrial  Finishes  Co- 

Midwest  Solvents  Co. 

Mid-West  Tar  Products  Corp... 


Miles  Laboratories,  Inc. 

Milwaukee  Gas  Light  Co 

Minerec  Corp 

M  &  M  Wood  Working  Co_ 
Monsanto  Chemical  Co 


Montrose  Chemical  Co- 

Morton  Chemical  Co , 

Murphy  Finishes  Corp .., 

Nason,  R.  N.,  &  Co 

Nassau  &  Suffolk  Lighting  Co. 


National  Aniline  Division,  Allied  Chem- 
ical &  Dye  Corp. 

National  Oil  Products  Co.. 

Naugatuck  Chemicals  Division,  U.  S. 
Rubber  Co. 

Neches  Butane  Products  Co, 

Neville  Co 

New  Bedford  Gas  &  Edison  Light  Co_. 

New  England  Power  Association 


Newport  Industries,  Inc 

New  York  Color  &  Chemical  Co.,  Inc. 

(Division  of  American  Dyewood  Co.). 
New    York    Quinine    and    Chemical 

Works,  Inc. 

New  York  &  Richmond  Gas  Co 

Niacet     Chemicals     Division,    U.     S. 

Vanadium  Corp. 

Niagara  Chlorine  Products  Co 

Niagara  Smeltmg  Corp 


Niagara  Wall  Paper  Co 

Ninol  Laboratories- 

Nonweiler,  A.  P.,  Co 

Nord  &  Co.,  Inc 

Norda  Essential  Oil  &  Chemical  Co.,  Inc 
Northern  Indiana  Public  Service  Co 


Northwestern  Chemical  Co 

Novocol  Chemical  Manufacturing  Co., 
Inc. 


2385  Richmond  Ter.,  Staten  Island  2,  N.  Y. 

262  Washington  St.,  Boston  9,  Mass.  (Waltham,  Mass.) 

3021  Wabash  Ave.,  Detroit  16,  Mich. 

3600  N.  2d  St.,  St.  Louis  7,  Mo. 

240  High  St.,  Newark  2,  N.  J.  (Morristown,  N.  J.). 

37-21  30th  St..  Long  Island  City  1,  N.  Y. 

Sewaren,  N.  J. 

500  Columbia  St.,  Somerville  43,  Mass. 

401  People's  Bank  Bldg.,  Marietta,  Ohio. 

Greene  and  Acme  Sts.,  Marietta,  Ohio. 

251  E.  139th  St.,  New  York  51,  N.  Y.  (Newark,  N.  J.). 

192-194  Colt  St.,  Irvington  11,  N.  J. 

43  W.  16th  St.,  New  York  11,  N.  Y.  (Newark,  N.  J.). 
60  E.  42d  St.,  New  York  17,  N.  Y. 

44  Cliff  St.,  New  York  7,  N.  Y. 
198-214  Niagara  St.,  Newark  5,  N.  J. 
100  W.  Hunter  Ave.,  Maywood,  N.  J. 

St.  Joseph  Ave.  and  Pennsylvania  St.,  Evansville  21, 

Ind. 
153  Waverly  PL,  New  York  14,   N.   Y.   (Eastport, 

Maine). 
2001  Lynch  Ave.,  East  St.  Louis,  111. 
Lincoln  Ave.,  Rahway,  N.  J.  (Elkton,  Va.;  Rahway, 

N.  J.;  and  Philadelphia,  Pa.). 
Amity  Rd.,  Cincinnati  15,  Ohio. 
412  Washington  St.,  Reading,  Pa.  (Easton,  Pa.). 
18th  and  Harney  Sts.,  Omaha  2,  Nebr. 
500  N.  Bankson  St.,  St.  Louis,  Mich. 
E.  Water  St.,  Waukegan,  111. 
1300  Main  St.,  Atchison,  Kans. 
332  S.  Michigan  Ave.,  Chicago  4,  111.  (East  Chicago, 

Ind.). 
1127  Myrtle  St.,  Elkhart,  Ind. 
626  E.  Wisconsin  Ave.,  Milwaukee  1,  Wis. 
120  Broadwav,  New  York  5,  N.  Y.  (Baltimore  25,  Md.). 
2301  Columbia  Blvd.,  Portland  3,  Oreg. 
1700  S.  2d  St.,  St.  Louis,  Mo.  (Everett  and  Springfield, 

Mass.;  Texas  City,  Tex.;  Nitro,  W.  Va.;  Anniston, 

Ala.;  and  Monsanto,  111.). 
120  Lister  Ave.,  Newark  5,  N.  J. 
2110  High  Point  Rd.,  Greensboro,  N.  C. 
224  McWhorter  St.,  Newark  1,  N.  J. 
151  Potrero  St.,  San  Francisco  3,  Calif. 
250  Old  Country  Rd.,  Mineola,  N.  Y.  (Hempstead, 

N.  Y.). 
40  Rector  St.,  New  York  6.  N.  Y.  (Buffalo,  N.  Y.). 

1st  and  Essex  Sts.,  Harrison,  N.  J. 

1230   6th  Ave.,  New  York  20,  N.  Y.  (Naugatuck, 

Conn.). 
Box  1535,  Port  Neches,  Tex. 
Neville  Island,  Pittsburgh  25,  Pa. 
693  Purchase  St.,  New  Bedford,  Mass. 
441   Stuart   St.,   Boston,   Mass.    (Athol,   Gloucester, 

Lawrence,     Leominster,     Maiden,     Northampton, 

North  Adams,  Salem,  Spencer,  and  Webster,  Mass.; 

Burlineton,  Vt.;  and  We.<!terly,  R.  I.). 
P.  O.  Box  911,  Pensacola,  Fla. 
374  Main  St.,  Belleville  9,  N.  J. 

99-117  N.  nth  St.,  Brooklyn  20,  N.  Y. 

691  Bay  St.,  Staten  Island,  N.  Y. 

30  E.  42d  St.,  New  York  17,  N.  Y.  (Niagara  Falls, 

N.  Y.). 
N.  Transit  Road,  Lockport,  N.  Y. 
420  Lexington  Ave.,  New  York  17,  N.  Y.  (Niagara 

Falls,  N.Y.). 
Walnut  Ave.  and  2d  St.,  Niagara  Falls,  N.  Y. 
1719  S.  Clinton  St.,  Chicago  16,  111. 
P.  0.  Box  1007,  Oshkosh,  Wis. 
Broadway  and  Clark  St.,  Keyport,  N.  J. 
601  W.  26th  St.,  New  York  1,  N.  Y.  (Boonton,  N.  J.). 
5265  Hohman  Ave.,  Hammond,  Ind.  (South  Bend  and 

La  Porte,  Ind.). 
1263  N.  70th  St.,  Wauwatosa  13,  Wis. 
2923  Atlantic  Ave.,  Brooklyn  7,  N.  Y. 


132 


UNITED    STATES   TARIFF    COMMISSION 


Table  22. — Synthetic  organic  chemicals:  Directory  of  manufacturers,  1944 — 

Continued 


Name  of  company 


Nuodex  Products  Co.,  Inc 

Nutrition  Research  Laboratories 

Ohio-Apex,  Inc 

Ohio  Chemical  &  Manufacturing  Co 

Ohio  Oil  Co 

Oldbury  Electro  Chemical  Co 

Old  Hickory  Chemical  Co 

Orbis  Products  Corp 

Osborn,  C.  J.,  Co. .__ 

Pan  American  Refining  Corp 

Panelyte  Division,  St.  Regis  Paper  Co.. 

Paraniet  Corp 

Parke,  Davis  &  Co 

Patent  Chemicals,  Inc 

Paul-Lewis  Laboratories,  Inc 

Peerless  Color  Co 

Penick,  S.  B.,  &  Co 

Pennsylvania  Alcohol  &  Chemical  Corp 

Pennsylvania  Coal  Products  Co 

Pennsylvania  Industrial  Chem.  Corp.... 

Pennsylvania  Power  <fe  Light  Co 

Pennsylvania  Salt  Manufacturing  Co... 

Peoples  Gas  Light  &  Coke  Co , 

Pfanstiehl  Chemical  Co 

Pfizer,  Chas.,  &  Co.,  Inc. , 

Pharma  Chemical  Corp 

Pharmedic  Corp 

Philadelphia  Gas  Works  Co 

Phillips  Petroleum  Co 

Pitman-Moore  Co.,  Division  of  Allied 
Laboratories,  Inc. 

Pittsberg  Chemical  Co 

Pittsburgh  Plate  Glass  Co 

Plaskon   Division,    Libbey-Owen-Ford 

Glass  Co. 

Polychem.ical  Co__ 

Pontiac  Varnish  Co 

Portland  Gas  &  Coke  Co 

Portland  Gas  Light  Co 

Poughkeepsie  Dyestufl  Corp 

Pratt  &  Lambert,  Inc 

Premo     Pharmaceutical    Laboratories, 

Inc. 

Procter  &  Gamble  Co... 

Publicker  Industries,  Inc 

Public  Service  Co.  of  N.  C,  Inc 

Public  Service  Electric  &  Gas  Co 

Pure  Oil  Co 

Purocaine,  Inc.. 

Pyridium  Corp 

Quaker  Chemical  Products  Corp 

Quaker  Oats  Co 

Queens  Borough  Gas  &  Electric  Co 

Eeichhold  Chemicals,  Inc 

ReillyTar<t  Chemical  Corp 

A 

Reilly-Whiteman  Walton  Co _ 

Reliance  Varnish  Co.,  Inc 

Remington  Arms  Co.,  Inc 

Republic  Creosoting  Co 

Resinous  Products  &  Chemical  Co 

Richards  Chemical  Works,  Inc. 

Richardson  Co 


Office  address  (location  of  plant  given  in  parentheses  if 
not  in  same  city  as  office) 


Elizabeth,  N.  J. 

4210  Peterson  Ave.,  Chicago  30,  111. 

P.  O.  Box  98,  Nitro,  W.  Va. 

1177  Marquette  St.,  Cleveland,  Ohio. 

539  S.  Main  St.,  Findlay,  Ohio  (Robinson,  111.). 

Buffalo  Ave.,  Niagara  Falls,  N.  Y. 

P.   O.  Box  1480,   Richmond  12,  Va.   (Old  Hickory, 

Tenn.). 
215  Pearl  St.,  New  York  7,  N.  Y.  (Newark,  N.  J.). 
132  Nassau  St.,  New  York  7,  N.  Y.  (Linden,  N.  J.). 
P.  O.  Box  401,  Texas  City,  Tex. 
230  Park  Ave.,  New  York  17,  N.  Y.  (Trenton,  N.  J.). 
10-17  44th  Ave.,  Long  Island  City  1,  N.  Y. 
McDougall  Ave.,  Detroit  32,  Mich. 
335  McLean  Blvd.,  Paterson  4,  N.  J. 
918  N.  4th  St.,  Milwaukee  3,  Wis. 
521-535  North  Ave.,  Plainfleld,  N.  J. 
50  Church  St.,  New  York  7,  N.  Y.  (Lyndhurst,  N.  J.). 
Berry  Ave.,  Carlstadt,  N.  J. 
P.  O.  Box  C,  Petrolia,  Pa. 

20  State  St.,  Clairton,  Pa. 

9th  and  Hamilton  Sts.,  Allentown,  Pa. 

1000  Widener  Bldg.,  Philadelphia,  Pa.  (Wyandotte, 

Mich.). 
122  S.  Michigan  Ave.,  Chicago  3,  111. 
104  Lakeview  Ave.,  Waukegan,  111., 
81  Maiden  Lane,  New  York  7,  N.    Y.  (Brooklyn  6, 

N.  Y.). 
175  5th  Ave.,  New  York  10,  N.  Y.  (Bayonne,  N.  J.). 
239  W.  Broadway,  New  York  13,  N.  Y. 
1800  N.  9th  St.,  Philadelphia  22,  Pa. 
Phillips  Bldg.,  Bartlesville,  Okla.  (Borger,  Tex.). 
1200  Madison  Ave.,  Indianapolis  6,  Ind. 

3100  E.  2Gth  St.,  Los  Angeles  23,  Calif. 

2000   Grant   Bldg.,    Pittsburgh    19,    Pa,    (Barberton 

Ohio). 
2112  Sylvan  Ave.,  Toledo  6,  Ohio. 

1938  Park  Ave.,  New  York  35,  N.  Y, 
30  Brush  St.,  Pontiac  12,  Mich. 
Public  Service  Bldg.,  Portland  4,  Oreg. 
5  Temple  St.,  Portland  6,  Maine. 
77  Water  St.,  Poughkeepsie,  N.  Y. 
75  Tonawanda  St.,  Buffalo  7,  N.  Y. 
443  Broadway,  New  York  13,  N.  Y. 

Gwynne  Bldg.,  Cincinnati  2,  Ohio  (Ivorydalc,  Ohio). 

1429  Wataut  St.,  Philadelphia  2,  Pa. 

119  S.  Salisbury  St.,  Raleigh,  N.  C. 

80  Park  PI.,  Newark  2,  N.  J.  (Harrison,  Jersey  City, 

Paterson,  Piscataway,  Trenton,  and  Camden,  N.  J.). 
35  East  Wacker  Dr.,  Chicago  1,  111.  (Cabincreek,  W. 

Va.). 
Packard  Bldg.,  Philadelphia,  Pa. 

21  Gray  Oaks  Ave.,    Yonkers  2,  N.  Y.  (Harriman, 
N.  Y.). 

Lime,  Elm,  and  Sandy  Sts.,  Conshohocken,  Pa. 

141  W.  Jackson  Blvd.,  Chicago  4,  111.  (Cedar  Rapids, 

Iowa) . 
250  Old  Country  Rd.,  Mineola,  N.  Y.  (Rockaway  Park, 

N.  Y.). 
601    Woodward   Heights    Blvd.,    Detroit    20,    Mich. 

(Elizabeth,  N.  J.;  San  Francisco,  Calif.;  Brooklyn, 

N.  Y.;  and  Tuscaloosa,  Ala.). 
500  5th  Ave.,  New  York  18,  N.  Y.  (Newark,  N.  J.; 

Chicago  and  Granite  City,  111.;  Indianapolis,  Ind.; 

Belle  and  Fairmont,  W.  Va.;  Cleveland  and  Dover, 

Ohio;  and  Chattanooea,  Tenn.). 
P.  O.  Box  188,  Conshoh(,Lken,  Pa. 
915  E.  Kentucky  St.,  Louisville  4,  Ky. 
939  Barnum  Ave.,  Bridgeport,  Conn. 
1615    Merchants   Bank    Bldg.,    Indianapolis   4,   Ind. 

(St.  Louis  Park,  Minn.;  Mobile,  Ala.;  Norfolk,  Va.; 

fronton,  Utah;  Lima,  Ohio;  and  Seattle,  Wash.). 
222  W.  Washington  Sq.,  Philadelphia  5,  Pa.  (Brides- 

burg.  Pa.). 
Warren  and  Morris  Sts.,  Jersey  City  2,  N.  J. 
27th  and  Lake  Sts.,  Melrose  Park,  111. 


SYNTHETIC   ORGANIC    CHEMICALS,    1944 


133 


Table  22. — Synthetic  organic  chemicals:  Directory  of  manufacturers,  1944- 

Continued 


Name  of  company 


Office  address  (location  of  plant  given  in  parentheses  if 
not  in  same  city  as  office) 


Richfield  Oil  Corp.. 

Richmond,    City    of    (Department    of 
Public  Utilities). 

Rochester  Gas  &  Electric  Co 

Rohm  &  Haas  Co 

Roosen,  H.  D.,  Co 

R.  S.  A.  Corp 

Ruberoid  Co 

St.  Louis  County  Gas  Co-- 

Salvo  Chemical  Corp 1 

Schenectady  Varnish  Co.,  Inc 

Schering  Corp 

Schering  &  Glatz,  Inc 

SchiefEelin  &  Co  -._ 

Scholler  Bros.,  Inc 

Schuylkill  Chemical  Co 

Schwarz  Laboratories,  Inc 

Scranton-Spring  Brook  Water  Service 
Co. 

Searle,  G.  D.,  &  Co.— 

Seattle  Gas  Co _.. 

Seeley  &  Co.,  Inc 

Seydel  Chemical  Co 

Sharp  &  Dohme,  Inc- 

Sharpies  Chemicals,  Inc. 

Shavrinigan  Resins  Corp 

Sheffield  Farms  Co., Inc 

Shell  Chemical  Division  of  Shell  Union 

Oil  Corp. 
Shell  Oil  Co.,  Inc - 

Shell  Oil  Co.,  Inc.. 

Sherwin-Williams  Co. 

Simons,  Harold  L.,  Inc.. 

Sinclair  Refining  Co 

Sinclair  &  Valentine  Co 

Skelly  Oil  Co 

Smith,  Kline  &  French  Laboratories 

Solvay  Process  Co.. 

Sonneborn,  L.,  Sons,  Inc. 

Sonoco  Products  Co 

South  Carolina  Electric  &  Gas  Co 

Southern  Dyestufl  Corp. 

Spaulding  Fibre  Co.,  Inc 

Springfield  Gas  Light  Co 

Squibb,  E.  R.,  &  Sons 

Staley,  A.  E.,  Manufacturing  Co 

Standard  Agricultural  Chemicals, Inc... 
Standard  Brands,  Inc.. 

Standard  Chemical  Products,  Inc 

Standard  Chlorine  Chemical  Co 

Standard  Naphthalene  Products  Corp  . 
Standard  Oil  Co.  of  California 

Standard  Oil  Co.  of  Indiana. 

Standard  Oil  Co.  of  New  Jersey 

Standard  Oil  Co.  of  New  Jersey  (Louis- 
iana Div.). 
Standard  Oil  Co.  of  New  Jersey  (Stanco 

Distributors  Inc.). 
Standard  Oil  Co.  of  New  Jersey  (Stand- 
ard Alcohol  Co.). 

Standard  Ultramarine  Co 

Standard  Varnish  Works. 

Stange,  Wm.  J.,  Co 

Stanton  Laboratories 


555  S.  Flower  St.,  Los  Angeles  13,  Calif.  (Watson, 

Calif.). 
City  Hall,  Richmond  19,  Va. 

89  East  Ave.,  Rochester  4,  N.  Y. 

222  W.  Washington  Sq.,  Philadelphia  5,  Pa.  (Bristol, 

Pa.). 
78  20th  St.,  Broooklyn  32,  N.  Y. 
690  Sawmill  River  Rd.,  Ardsley,  N.  Y. 
500  5th  Ave.,  New  York  18,  N.  Y.  (Joliet,  111.,  and 

Erie,  Pa.). 
231  W.  Lockwood  Ave.,  Webster  Grove  19,  Mo. 
Rothschild,  Wis. 

P.  O.  Box  1046,  Schenectady  1,  N.  Y. 
2  Broad  St.,  Bloomfleld,  N.  J.  (Union,  N.  J.). 
113  W.  18th  St.,  New  York  11,  N.  Y. 
16-28  Cooper  Sq.,  New  York  3,  N.  Y. 
Collins  and  Westmoreland  Sts.,  Philadelphia  34,  Pa. 
2346  Sedgley  Ave.,  Philadelphia  32,  Pa. 
202  E.  44th  St.,  New  York  17,  N.  Y.  (Brooklyn,  N.  Y.). 
30  N.  Franklin  St.,  Wilkes-Barre,  Pa.  (Scranton,  Pa.). 

P.  O.  Box  5110,  Chicago  80,  111. 
1511  4th  Ave.,  Seattle  11,  Wash. 
136   Liberty  St.,  New  York  6,  N  Y.  (Farmingdale, 

N.  Y.). 
225  Mercer  St.,  Jersey  City,  N.  J. 
640  N.  Broad  St.,  Philadelphia  1,  Pa. 
123  S.  Broad  St.,  Philadelphia  9,  Pa.  (Wyandotte, 

Mich.). 
644  Monsanto  Ave.,  Springfield  2,  Mass. 
524  W.  ,57th  St.,  New  York  19,  N.  Y.  (Woods  Corners, 

N.  Y.). 
100  Bush  St.,  San  Francisco  6,  Calif.  (Houston,  Tex.; 

Pittsburg,  Martinez,  and  Dominguez,  Calif.). 
50  W.  50th  St.,  New  York  20,  N.  Y.  (Houston,  Tex., 

and  Roxana,  111.). 

100  Bush  St.,  San  Francisco  6,  Calif.  (Wilmington, 
Calif.). 

101  Prospect  Ave.,  NW.,  Cleveland  1,  Ohio  (Chicago, 
111.;  Newark  and  Oibbsboro,  N.  J.;  Oakland,  Calif.; 
Detroit,  Mich.;  Dallas,  Tex.;  and  Dayton,  Ohio). 

11-25  44th  Rd.,  Long  Island  City  1,  N.  Y. 

630  5th  Ave.,  New  York  20,  N.  Y.  (Marcus  Hook,  Pa., 

and  Sand  Springs,  Okla.). 
611  W.  129th  St.,  New  York  27,  N.  Y. 
P.  0.  Box  1650,  Tulsa  2,  Okla.  (Eunice,  N.  Mex.). 
5th  and  Arch  Sts.,  Philadelphia  5,  Pa. 
P.  O.  Box  271,  Syracuse  1,  N.  Y.  (Geddes,  N.  Y.). 
88  Lexington  Ave.,  New  York  16,  N.  Y.  (Petrolia,  Pa., 

and  Nutley,  N.  J.). 
Hartsville,  S.  C. 
328  Main  St.,  Columbia,  S.  C. 

P.  O.  Box  1045,  Charlotte  1,  N.  C.  (Sodyeco,  N.  C). 
310  Wheeler  St.,  Tonawanda,  N.  Y. 
35  State  St.,  Springfield  2,  Mass. 

25  Columbia  Heights,  Brooklyn  2,  N.  Y. 
Decatur  50,  111. 

1301  JeSerson  St.,  Hoboken,  N.  J. 

595  Madison  Ave.,  New  York  22,  N.  Y.  (Peekskill, 

N.  Y.). 
1301  Jefierson  St.,  Hoboken,  N.  J. 
115  Jacobus  Ave.,  South  Kearny,  N.  J. 
115  Jacobus  Ave.,  South  Kearny,  N.  J. 
225  Bush  St.,  San  Francisco  20,  Calif.  (Richmond  and 

El  Segundo,  Calif.). 
910  S.  Michigan  Ave.,  Chicago  80,  HI.  (Wood  River, 

111.,  and  Whiting,  Ind.). 

26  Broadway,  New  York  4,  N.  Y.  (Linden,  N.  J.). 
P.  O.  Box  551,  Baton  Rouge  1,  La. 

216  W.  14th  St.,  New  York  11,  N.  Y. 

26  Broadway,  New  York  4,  N.  Y. 

5th  Ave.  and  24th  St.,  Huntington  18,  W.  Va. 
2600  Richmond  Ter.,  Staten  Island  3,  N.  Y. 
2536  W.  Monroe  St.,  Chicago  12,  lU. 
Wyncote,  Pa. 


134 


UNITED   STATES   TARIFF    COMMISSION 


Table  22. — Synthetic  organic  chemicals:  Directory  of  manufacturers,  1944 — 

Continued 


Num- 
ber 

Name  of  company 

Office  address  (location  of  plant  piven  in  parentheses  If 
not  in  same  city  as  office) 

443 

Stauffer  Chemical  Co.,  Inc 

420  Lexington  Ave.,  New  York  17,  N.  Y.  (Chauncey, 
N.  Y.;  Monongahela  and  Chester,  Pa.;  Roanoke, 
Va.;  and  Perry,  Ohio). 

6533  E.  Jefferson  Ave  ,  Detroit  31   Mich 

444 

Steams,  Frederick,  &Co 

445 

Stresen-Reuter,  F.  A.,  Inc.. 

2113  Medill  Ave.,  Chicago  47,  111.  (Bensenville,  HI.). 

309  Sussex  St.,  Harrison,  N.  J. 

446 

Sun  Chemical  &  Color  Co... 

447 

Sun  Oil  Co 

1608  Walnut  St.,  Philadelphia  3,  Pa.  (Marcus  Hook, 

Pa.). 
Fredericksburg,  Va. 

448 

Sylvania  Industrial  Corp 

449 

Synthetical  Laboratories 

5558  Ardmore  Ave.,  Chicago  30,  HI 

450 

Sjmthetic  Chemicals,  Inc. 

335  McLean  Blvd.,  Paterson  4,  N.  J. 

451 

Synthetic  Products  Co 

1798  London  Rd.,  Cleveland  12,  Ohio. 

452 

Tar  Distilling  Co 

500  5th  Ave.,  New  York  18  N  Y 

453 

Taunton  Gas  Li?ht  Co 

41  Taunton  Green,  Taunton,  Mass. 

454 

Taylor  Chemical  Corp 

600  N.   Broad  St.,  Phillipsburg,  N.  J.  (Penn  Yan, 

N.  Y.). 
Norristown,  Pa.  (Betzwood,  Pa.). 

455 

Taylor  Fibre  Co... 

456 

Tennessee  Eastman  Corp 

457 

Tennessee  Products  Corp 

404  American  National  Bank  Bldg.,  Nashville  3,  Tenn' 

458 

Texas  Co 

(Chattanooga  10,  Tenn.). 
Box  2332  Houston  1    Tex 

459 

Trojan  Powder  Co 

17  N.  7th  St ,  Allentown,  Pa  (Seiple,  Pa). 

460 

Trubek  Laboratories 

State  Highway  #17,  East  Rutherford,  N.  J. 

461 

Tubize  Rayon  Corp.. 

2  Park  Ave.,  New  York  16,  N.  Y.  (Rome,  Oa.). 

462 

Ugite  Sales  Corp 

1401  Arch  St.,  Philadelphia  5,  Pa.  (Chester,  Pa.). 

463 

Uhlich,  Paul,  &  Co.,  Inc 

90  West  St.,  New  York  6,  N.  Y.  (Brooklyn  15,  N.  Y.). 
2  Wood  St.,  Paterson  4,  N.  J. 

464 

Ultra  Chemical  Works 

465 

Union  Bay  State  Co 

50  Harvard  St.,  Cambridge  42,  Mass. 

466 

Union  Oil  Co.  of  California 

617  W.  7th  St.,  Los  Angeles  14,  Calif. 

467 

U.  S.  Industrial  Chemicals,  Inc 

60  E.  42d  St.,  New  York  17,  N.  Y.  (New  Orleans.  La.). 

468 

U.  S.  Oil  Co 

P.  0.  Box  1345,  Providence,  R.  I. 

469 

Utah  Copper  Co 

Keams  Bldg.,   Salt   Lake  City  12,  Utah   (Garfield, 

Utah). 
11  E.  36th  St.,  New  York  16,  N.  Y.  (Brooklyn,  N.  Y.). 

470 

Valentine  &  Co.,  Inc... 

471 

Valley  Chemical  Co.,  Inc  ... 

80  Wheeler  Point  Rd  ,  Newark  5,  N  J. 

472 

Van  Ameringen-Haebler,  Inc 

315  4th  Ave.,  New  York  10,  N.  Y.  (Elizabeth  2,  N.  J.). 

473 

Van  Camp  Laboratories 

Terminal  Island,  Calif. 

474 

Van  Dyk  &  Co.,  Inc 

57  Wilkinson  Ave.,  Jersey  City  6,  N.  J.  (Belleville  9, 

475 
476 

Van  Schaack  Chemical  Works,  Inc 

Varcum  Chemical  Co. 

N.  J.). 
3430  Henderson  St.,  Chicago  18,  111. 
P.  O.  Box  433,  Niagara  Falls,  N.  Y. 

477 

Velsicol  Corp 

120  E.  Pearson  St..  Chicago  11,  111.  (Marshall,  El.). 
Main  and  William  Sts.,  Belleville  9,  N.  J. 

478 

Verley  Chemical  Co.,  Inc 

479 

Verona  Chemical  Co 

26  Verona  Ave.,  Newark  4,  N.  J. 

480 

Victor  Chemical  Works... 

141  W.  Jackson  Blvd.,  Chicago  4,  111. 

481 

482 

Virginia  Electric  &  Power  Co 

Virginia  Smelting  Co. 

Norfolk,  Va. 

Jeflerson  St.  and  3d  Ave.,  West  Norfolk,  Va. 

483 

Vitamins,  Inc 

809  W.  58th  St.,  Chicago  21,  111. 

484 
485 
486 

Wallace  &  Tiernan  Products,  Inc 

Warner-Jenkinson  Mfg.  Co 

Warwick  Chemical  Co 

Belleville  9,  N.  J. 

2526  Baldwin  St.,  St.  Louis  6,  Mo. 

100  Pulaski  St.,  West  Warwick,  R.  I. 

487 

Watertown  Mfg.  Co..  ...     .  . 

127  Echo  Lake  Rd.,  WatertoNvn,  Conn. 

488 

Werner  Drug  &  Chemical  Co 

914  Race  St.,  Cincinnati  2,  Ohio. 

489 

Western  Condensing  Co.. 

935  E.  John  St.,  Appleton,  Wis.  (Adell,  Wis.). 

490 

Western  Dry  Color  Co 

600  W.  52d  St..  Chicago  9,  111. 

491 
492 

493 

494 

Western  United  Gas  &  Electric  Co 

Westinghouse  Electric  &  Manufacturing 

Co. 
Westvaco  Chlorine  Products  Corp 

Westville  Laboratories 

50  Fox  St.,  Aurora,  111.  (Lockport  and  DuQuoin,  III.). 
306  4th  Ave.,  Pittsburgh  30,  Pa.  (Trafford,  Pa.). 

405  Lexingt.on  Ave.,  New  York  17,  N.  Y. 

(South  Charleston,  W.  Va.,  and  Newark,  Calif.). 
Stepney,  Conn.  (Derby,  Conn.). 

495 

Westwell  Chemical  Co 

P.  0.  Box  191,  Whittier,  Calif. 

496 
497 

Wetherill,  George  D.,  Varnish  Co.,  Inc.. 
White  &  Hodges 

Haddon  Ave.  and  White  House  Pike,  Camden,  N,  J. 
2  Wellington  Ave.,  Everett  49,  Mass. 

498 

Wilhelm,  A.,  Co 

3d  and  Bern  Sts  ,  Reading,  Pa. 

499 

Wilmot  &  Cassidy,  Inc 

292  Freeman  St  ,  Brooklyn  22,  N.  Y. 

600 

Wilson  Laboratories 

4221  S.  Western  Ave  ,  Chicago  9,  111. 

501 

Winthrop  Chemical  Co.,  Inc 

170  Varick  St.,  New  York  13,  N.  Y.  (Rensselaer,  N.  Y.). 

502 

Wisconsin  Fuel  &  Light  Co.. 

106  N.  8th  St.,  Manitowoc,  Wis. 

603 

Wisconsin-Michigan  Power  Co 

137  W.  Mill  St.,  Appleton,  Wis. 

604 

Wisconsin  Power  &  Light  Co 

122  W.  Washington  Ave.,  Madison  1,  Wis. 

605 

Wisconsin  Public  Service  Corp 

1029  N.  Marshall  St.,  Milwaukee,  Wis. 

606 

Witco  Chemical  Co 

295  Madison  Ave.,  New  York  17,  N.  Y. 

607 

Witte,  John  H.,  &  Sons 

508 

Wobum  Chemical  Corp 

1200  Harrison  Ave.,  Harrison,  N.  J.  (Kearny,  N.  J.). 

609 

WollT-Alport  Chemical  Corp... 

1127  Irving  Ave.,  Brooklyn  27,  N.  Y. 

610 

Worcester  Gas  Light  Co 

240  Main  St.,  Worcester  8,  Mass.  (Framingham,  Mass.). 

611 

Wyandotte  Chemicals  Corp 

1609  Biddle  Ave.,  Wyandotte,  Mich. 

612 
613 

Young  Aniline  Works,  Inc :... 

Zinsser  &  Co.,  Inc 

2731  Boston  St.,  Baltimore  24,  Md. 
Hasthigs  on  Hudson,  N.  Y. 

SYNTHETIC    ORGANIC    CHEMICALS,    1944 


135 


Table  22. — Synthetic  organic  chemicals:  Directory  of  manufacturers,  1944 — 

Continued 


Num- 
ber 


Name  of  company 


Office  address  (location  of  plant  given  in  parentheses  if 
not  in  same  city  as  office) 


514 

615 

516 
517 

618 
619 

520 

521 
522 
523 
524 
625 

526 
527 
528 

529 
630 
631 


United  States  Government  plants 

operated  by  Rubber  Reserve 

Company 

Copolymer  Corp... 

Dow  Ctiemical  Co.,  Styrene  Div 

DuPont  de  Nemours,  E.  I.,  &  Co.,  Inc. 
Firestone  Tire  &  Rubber  Co 

General  Tire  &  Rubber  Co 

Goodrich,  B.  F.,  Co 

Goodyear  Sjmthetie  Rubber  Co 

Humble  Oil  &  Refining  Co.. 

Koppers  Co.,  Inc 

National  Synthetic  Rubber  Corp 

Poljmier  Corporation,  Ltd 

Shefi  Chem.  Div.  of  SheU  Union  OU 
Corp. 

Sinclair  Rubber,  Inc 

Southern  California  Gas  Co 

Standard  Oil  Co.  of  California 

Sun  Oil  Co 

Taylor  Refining  Co 

United  States  Rubber  Co 


P.  O.  Box  1029,  Baton  Rouge  2,  La. 

P.  O.  Box  500,  Gardena,  Calif.  (Freeport  and  Velasco, 

Tex.). 
P.  O.  Box  1378,  Louisville  1,  Ky. 
1200  Firestone  Parkway,  Akron  17,  Ohio  (Port  Neches, 

Tex.). 
Baytown,  Tex. 
324  Rose  Bldg.,  Cleveland  15,  Ohio  (Louisville,  Ky.; 

Borger  and  Port  Neches,  Tex.). 
1144  Market  St.,  Akron  16,  Ohio  (Houston,  Tex.,  and 

Torrance,  Calif.).; 
P.  O.  Box  1321,  Baytowxt,  Tex. 
P.  O.  Box  92,  Monaca,  Pa.  (Kobuta,  Pa.). 
P.  O.  Box  2068,  Louisville  1,  Ky. 
Sarnia,  Ontario,  Canada. 
P.  O.  Box  211,  Torrance,  Calif. 

P.  0.  Box  2584,  Houston  1,  Tex. 

P.  O.  Box  3249  Terminal  Annex,  Los  Angeles  54,  Calif. 

225  Bush  St.,  San  Francisco  20,  Calif.  (El  Segundo, 

Calif.). 
Woodville  &  Bay  Terminal  Railroad,  Toledo  1,  Ohio. 
Taylor,  Tex.  (Corpus  Christi,  Tex.). 
1230  6th  Ave.,  New  York  20,  N .  Y.  (Naugatuck,  Conn.; 

Institute,  W.  Va.;  and  Torrance,  Calif.). 


APPENDIX 

A.  IMPORTS  OF  COAL-TAR  INTERMEDIATES  AND  FINISHED  PRODUCTS 

Statistics  on  United  States  imports  of  coal-tar  products  entered  in 
1944  under  paragraphs  27  and  28  of  the  Tariff  Act  of  1930  were  ob- 
tained by  analyzing  invoices  covering  imports  through  all  customs 
districts.  These  imports,  summarized  in  table  23,  are  given  in  detail 
in  a  separate  report.^ 

Table  23. — Coal-tar  intermediates    and  finished  coal-tar  products:  United  States 
imports  for  consumption,  classified  by  uses,  1942-44 


1942 

1943 

1944 

Product 

Quantity 

Foreign 
invoice 
value 

Quantity 

Foreign 
invoice 
value 

Quantity 

Foreign 
invoice 
value 

Intermediates,  total 

1,000 
pounds 
3,243 

1,000 
dollars 
564 

1,000 
pounds 
4,424 

1,000 
dollars 
651 

1,000 
pounds 
9,034 

1,000 
dollars 
1,395 

Finished  coal-tar  products,  total 

6,109 

3,051 

1,283 

2,334 

5,455 

2,593 

Dyes,  total-. 

1,127 

1,905 

607 

1,318 

651 

1,514 

Acid    .- 

219 

297 

147 

291 

78 

48 

3 

27 

17 

3 

1 

4,978 

447 

413 

260 

473 

120 

76 

5 

108 

3 

21 

33 

1,092 

169 
36 
100 
170 
96 
22 

449 
115 
210 
318 
156 
40 

247 
36 
69 

196 
70 
27 

662 

Vat 

132 

Mordant  and  chrome 

130 

Direct ' 

410 

Acetate  rayon. 

112 

Basic 

« 

Sulfur-- - 

Color-lake  and  spirit-soluble 

9 
5 
3 

206 
467 

28 
2 

18 
862 
136 

9 
7 
5 
21 
4,778 

28 

All  other .- 

31 

Aromatic  chemicals 

Medicinals  and  pharmaceuticals - 

All  other 

69 
979 

1  Includes  rapid  fast  dyes. 

2  Publication  would  reveal  operations  of  individual  importers. 
Source:  Compiled  from  records  of  the  U.  S.  Bureau  of  Customs. 

Dyes  continued  in  1944  to  be  the  most  important  group,  in  terms 
of  value,  among  imports  of  dutiable  coal-tar  chemicals.  In  that  year 
imports  of  dyes  amounted  to  1.5  million  dollars,  or  58  percent  of  the 
total  value  of  all  imported  finished  coal-tar  products,  which  was  2.6 
million  dollars.  Switzerland  supplied  89  percent  of  the  total  quan- 
tity of  dyes  imported  for  consumption  in  1944.  These  imports,  how- 
ever, were  chiefly  withdrawals  from  warehouse  of  goods  which  had 
been  shipped  to  this  country  in  earlier  years.  Imports  of  other 
finished  coal-tar  products  consisted  chiefly  of  medicinals,  almost  en- 
tirely sulfapyridine  and  salts,  and  perfume  and  flavor  materials, 
largely  musk  ambrette. 

Imports  of  coal-tar  intermediates  in  1944  totaled  9  million  pounds, 
valued  at  1.4  million  doUars.  They  consisted  chiefly  of  ethylbenzene 
(from  which  styrene  is  made)  and  styrene,  both  of  which  were  im- 


»  See  U.  S.  Tariff  Commission,  Imports  of  Coal  Tar  Productt,  19U,  1945  [processed]. 


137 


138 


UNITED    STATES   TARIFF    COMMISSION 


ported  from  Canada  for  the  account  of  the  Rubber  Eeserve  Com- 
pany. Dibutyl  phthalate,  also  from  Canada,  was  another  large  im- 
port item  grouped  among  the  intermediates. 

Among  the  chemicals  listed  as  "All  other,"  the  most  important 
were  the  military  explosives,  trinitrotoluene  and  tetryl,  both  of  which 
came  chiefly  from  Canada.  Another  major  item  in  this  group  was 
phenylaminomethyl-2-benzothiazyl  sulfide,  an  accelerator  for  rubber 
vulcanization;  107,000  pounds  of  this  chemical  was  imported,  all 
from  Canada. 

The  ratio  of  the  value  (foreign  invoice  value)  of  imports  to  the 
value  of  the  domestic  output  of  all  coal-tar  products  was  less  than  1 
percent  in  1944. 

B.  RESEARCH  WORKERS  AND  EXPENDITURES 

From  time  to  time  the  Commission  has  collected  some  general  in- 
formation on  research  expenditures  of  the  synthetic  organic  chemical 
industry.  The  data  are  approximate  because  some  of  the  reporting 
companies  which  produce  chemicals  other  than  synthetic  organic 
chemicals  find  it  difficult  to  determine  how  much  of  the  total  cost  of 
research  should  be  allocated  to  synthetic  organic  chemicals.  Fur- 
thermore, since  some  companies  do  not  report  all  the  data  requested, 
it  has  been  necessary  to  estimate  part  of  the  data.  Notwithstanding 
these  limitations,  the  following  statistics,  which  are  not  available 
elsewhere,  are  of  value  in  indicating  trends: 


Year 

Companies 
reporting 

Technically 
trained 
research 
workers  > 

Salaries 
paid 

Cost  of  research 

Extra-plant 

Gross 

Net» 

research 

1941                 

Number 
153 
183 
236 
272 

Number 
2,957 
3,839 
6,086 
5,118 

1,000 

dollars 
8,966 
11,541 
20, 816 
22, 428 

1,000 
dollars 
18, 425 
23,440 
28,723 
43, 820 

1,000 

dollars 
17, 137 
20,768 
28, 470 
40,946 

1,000 
dollars 

(3) 

1942    

1943 

C) 

1944 

2,646 

«  For  the  years  1941-43,  a  technically  trained  research  worker  was  defined  as  a  person  with  technical  train- 
ing engaged  in  research  work  and  earning  not  less  than  $2,000  per  year;  in  1944  the  minimum  amount  of 
earnings  was  fixed  at  $2,500. 

2  The  net  cost  figure  is  obtained  by  deducting  from  gross  cost  the  credits  for  salable  products  obtained  in 
the  course  of  research. 

8  Data  for  extra-plant  research  were  not  collected  before  1944. 

The  apparent  increase  in  the  number  of  companies  reporting  research 
work  in  1944  reflects  the  greater  eflort  of  the  Commission  to  enlist  the 
cooperation  of  all  companies  having  research  organizations. 

In  1944,  information  was  reported  for  the  first  time  on  the  amount 
expended  by  companies  on  extra-plant  research,  that  is,  for  consult- 
ants, research  projects  in  universities,  and  privately  endowed  labora- 
tories. The  reported  amount  (which  is  probably  incomplete)  was 
about  2.5  million  dollars. 

The  average  salary  of  technically  tramed  research  workers  was 
$4,400  in  1944  compared  with  $4,100  in  1943  and  $3,000  in  1942  and 
1941,  The  gross  cost  of  research  increased  from  28.7  million  to  43.8 
million  dollars,  or  roughly  50  percent,  from  1943  to  1944,  while  salaries 
paid  increased  only  from  20.8  million  to  22.4  million  dollars,  or  roughly 
8  percent. 

U.  S.  GOVERNMENT  PRINTING   OFFICEl  1946