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SYNTHETIC 
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United  States  Production 
and  Sales,  1953 


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UNITED  STATES  TARIFF  COMMISSION 

SYNTHETIC 
ORGANIC  CHEMICALS 


United  States  Production 
and  Sales,  1953 


UNDER  THE  GENERAL  PROVISIONS 
OF  TITLE  III,  PART  II,  SECTIONS  332 
AND  333  OF  THE  TARIFF  ACT  OF  1930 


UNITED  STATES 

GOVERNMENT  PRINTING  OFFICE 

WASHINGTON    :    1954 


Report   No.    194  •  Second   Series 


Boston  Public  Library 
Guperintcndent  of  Documents 

SEP  28 1954 

UNITED    STATES    TARIFF    COMMISSION 

EdgAK  B.  BkoSSARD,  Chairman 

Joseph  E.  Talbot,  Vice  Chairman 
Oscar  B.  Kydek 
Lynn  K.  Edminstek 
Walter  K.  Schreiber 

DONN  N.  Bent,  Secretary 


Address  all  communications 

UNITED  STATES  TARIFF  COMMISSION 

Washington  25,  D.  C. 


ACKNOWLEDGMENT 

In  the  preparation  of  this  report,  the  Commission  had  the  services  of 

James  H.  Hibben,  Henry  O.  Parsons,  Deborah  K.  Emory, 

Frank  Gonet,  Pauline  T.  Eno,  and  others  of  its  staff 


For  8ale  by  the  Superintendent  of  Documents   U.  S.  Government  Printing  Office 
Washington  25  D.  C.     -     Price  55  cents 


CONTENTS 

Page 

Introduction v 

Summary vii 

PART  I.   PRODUCTION  AND  SALES  OF  TARS,    TAR  CRUDES, 
AND  CRUDES  DERIVED  FROM  PETROLEUM  AND  NATURAL  GAS 

Tars 1 

Tar    crudes 2 

Crude   products  from  petroleum  and  natural  gas  for  chemical 

conversion '■ ^ 


PART  II.    PRODUCTION  AND  SALES  OF  INTERMEDIATES  AND 
FINISHED  SYNTHETIC  ORGANIC  CHEMICALS,    BY  GROUPS 

General 9 

Cyclic  intermediates 13 

Dyes 1^ 

Toners  and  lakes 29 

Medicinals 3Z 

Flavor  and  perfume  materials 37 

Plastics  and  resin  materials 39 

Rubber-processing  chemicals 44 

Elastomers  (synthetic  rubbers) 45 

Plasticizers 46 

Surface -active  agents 48 

Pesticides  and  other  organic  agricultural  chemicals 51 

Miscellaneous  synthetic  organic  chemicals 52 

PART  III.    ALPHABETICAL  LIST  OF  INDIVIDUAL  PRODUCTS, 
BY  GROUPS,    AND  NAMES  OF  MANUFACTURERS 

Tar  crudes 57 

Crude  products  from  petroleum  and  natural  gas  for  chemical 

conversion 58 

Cyclic  intermediates 60 

Dyes 77 

Toners  and  lakes 94 

Medicinals 99 

Flavor  and  perfume  materials 112 

Plastics  and  resin  materials 117 

Rubber-processing  chemicals 121 

Elastomers  (synthetic  rubbers) 123 

Plasticizers 123 

Surface -active  agents 126 

Pesticides  and  other  organic  agricultural  chemicals 133 

Miscellaneous  synthetic  organic  chemicals 136 

Directory  of  manufacturers 152 

APPENDIX 

A.  United  States  imports    of  coal-tar  intermediates  and 

finished  coal-tar  products lo7 

B.  Research  workers  and  research  expenditures  in  the 

synthetic  organic  chemical   industry loo 

C.  Glossary  of  synonymous  names  of  cyclic  intermediates lo9 

D.  Production  and  sales  of  cellulose  plastics 181 

iii 


INTRODUCTION 

This  is  the  thirty- seventh  annual  report  of  the  United  States 
Tariff  Commission  on  production  and  sales  in  the  United  States  of 
synthetic  organic  chemicals  and  the  raw  materials  from  which  they 
are  made.    The  report  gives  statistics,    for  1953,    on  the  production 
and  sales  of  crude  brganic  chemicals  derived  from  coal,    natural 
gas,    and  petroleum;  intermediates;  and  finished  synthetic  organic 
chemical  products.    The  finished  products  are  grouped  according  to 
their  principal  use--dyes,   toners  and  lakes,    medicinals,    flavor 
and  perfume  materials,    plastics  and  resin  materials,    rubber-proc- 
essing   chemicals,    elastomers,    plasticizers,    surface -active  agents, 
pesticides  and  other  organic  agricultural  chemicals,    and  miscel- 
laneous chemicals.    With  a  few  exceptions,    the  report  does  not 
cover  organic  chemicals  (such  as  wood-distillation  products, 
essential  oils,    and  naval  stores)  that  are  derived  from  natural 
(vegetable)  sources  by  simple  extraction  or  distillation.    The 
Commission  has  compiled  the  statistics  presented  in  this  report 
from  information  supplied  by  more  than  600  primary  manufacturers 
listed  in  part  III. 

The  raw  materials  covered  in  this  report  are  obtained  from  coal, 
crude  petroleum,    natural  gas,    and  certain  other  natural  materials 
such  as  vegetable  oils,    fats,    rosin,    and  grains.    Thermal  decom- 
position of  coal  yields  coal-tar  crudes  and  other  raw  materials. 
Crude  organic  chemicals  are  derived  also  from  petroleum  and 
natural  gas  by  catalytic  cracking,    followed  by   distillation  or  ab- 
sorption,   and  from  other  natural  sources  by  fermentation.    Pro- 
duction of  these  crude  organic  chemicals  is  the  first  step  in  the 
manufacture  of  synthetic  organic  chemicals.    From  these  crudes, 
intermediates  are  obtained  by  synthesis  or  refining;  most  of  the 
intermediates  then  are    converted  into  finished  chemical  products, 
such  as  medicinals,    plastics  and  resin  materials,    and  dyes. 
Intermediates  usually  are  not  sold  directly  to  the  ultimate  consumer, 
but  are  used  by  the  producing  companies  themselves,    or  by  other 
industrial  concerns,    in  their  nnanufacturing  processes. 

In  this  report,    the  statistics  on  production  include  the  total 
output  of  the  reporting  companies'  plants --the  materials  produced 
for  consumption  within  the  plants,    as  well  as  those  produced  for 
sale.    The  quantities  reported  as  produced,    therefore,    generally 
exceed  the  quantities  reported  as  sold,    although  changes  in  in- 
ventory may  account  for  some  differences.    No   chemical  is  reported 
as  produced,    however,    unless  it  has  been  withdrawn  from  the 
reaction  system.    Sales  are  actual  sales  of  commodities- -by 
original   manufacturers  only- -accompanied  by  passage  of  title. 
The  value  of  sales  is  the  net  selling  value,    f.o.b.   plant  or  warehouse. 

Data  on  the  chemicals  covered  in  the  report  usually  are  given 
in  terms  of  undiluted  materials.    Principal  exceptions  are  the 
statistics  on  dyes  and  a  few  solvents,    which  are  reported  in  terms 
of  commercial  concentrations,     and  those  on  certain  plastics  and 
resins,    which  are  reported  on   a  dry  basis.    The  report  specifically 


Vi  INTRODUCTION 

notes  those  products  for  which  the  statistics  are  reported   in  terms 
of  commercial  concentrations. 

The  average  unit  values  of  sales  for  groups  of  products  shown 
in  the  tables  accompanying  this  report  are  weighted  averages  for 
products  which  vary  w^idely  in  unit  values  and  in  the  quantities 
sold. 

Statistics  on  tars  and  tar  crudes    include  data  furnished  directly 
to  the  Tariff  Commission  by  distillers  of  coal  tar,    water-gas  tar, 
and  oil-gas  tar;  data  furnished  to  the  Coal   Economics  Division  of 
the  United  States  Bureau  of  Mines  by  coke-oven  operators;  and 
data  furnished  to  the  American  Gas  Association  by  producers  of 
water-gas  and  oil-gas  tar. 

Statistics  on  United  States  imports  in  1953  of  coal-tar   inter- 
mediates and  finished  coal-tar  products  which  entered  under 
paragraphs  27  and  28  of  the  Tariff  Act  of  1930  are  given  in  ap- 
pendix  A.    Appendix  B  includes  a  table  showing  the  number  of 
technical  research  workers  in  the  synthetic  organic  chemical 
industry  and  the  cost  of  research  in  the  industry.    Appendix  C  is 
a  glossary  of  the  common  (or  trivial)  names  of  coal-tar   inter- 
mediates usually   encountered  in  the  trade,    together  with  their 
equivalent  standard  (or  Chemical  Abstracts)  names.     Appendix  D 
summarizes  the  data  on  production  and  sales  of   cellulose  plastics 
that  were  reported  to  the  Commission  monthly   during  1953. 


SUMMARY 

Combined  production  of  all  synthetic  organic  chennicals  (in- 
cluding their  raw  materials)  in  1953  was  60,759  million  pounds -- 
15.5  percent  more  than  that  in  1952  (see  table  1).   Sales  in  1953 
totaled  35,  037  million  pounds,    valued  at  4,587  million  dollars--an 
increase  of  14.9  percent  in  quantity  and  7.1  percent  in  value,    com- 
pared with  1952.    As  these  totals  include  the  data  for  several  suc- 
cessive steps  in  the  manufacturing  process,    they  necessarily 
include  much  duplication. 

The  output  of  tars  from  all  sources  in  1953  was  9,007  million 
pounds    (901  million  gallons)-- 13.6  percent  more  than  in  1952. 
Production  of  tar  crudes  in  1953  totaled  11,476  million  pounds, 
compared  with  10,701  million  pounds  in  l952--an  increase  of  7.2 
percent.   Sales  of  tar  crudes  in  1953  totaled  7,105   million  pounds, 
valued  at  204  nnillion  dollars.    The  output  in  1953  of  crude  products 
from  petroleum  and  natural  gas  for  chemical  conversion  totaled 
11,147  million  pounds--an  increase  of  41.7  percent  from  the  7,867 

TABLE  1, --Synthetic  organic  chemicals  and  their  raw  materials:    United  States  production  and  sales, 

1952  and  1953 


In- 
crease, 
or  de- 
crease 

(-), 
1953 
over 
1952^ 


Quantity 


In- 
crease, 
or  de- 
crease 

(-), 
1953 
over 


In- 
crease, 

or  de- 
crease 

(-), 

1953 

over 

19521 


Grand  total^- 


pounds 

52,618 


60,759 


30,502 


Uillion 
pounds 

35,037 


dollars 
4,282 


lollars 
4,587 


Xar 

Tar  crudes-' 

Crude  products  from 
petroleum  and  natural 
gas 

Synthetic  organic  chemi- 
cals, total 


7,931 
10,701 


7,867 
26,119 


9,007 
11,476 


11, 147 


29,129 


13.6 
7.2 


4,327 
7,059 


4,732 


14,384 


4,994 
7,105 


7,301 


15,637 


15.4 
.7 


8.7 


50 
204 


19.0 
6.3 


6.5 


Intermediates 

Dyes 

Toners  and  lakes 

Mediclnals ~— 

Flavor  and  perfume 

materials 

Plastics  and  resin 

materials 

Ruhber-processing  chem- 
icals  

Elastomers  (synthetic 

rubbers ) 

Plasticizers 

Surface-active  agents- 
Pesticides  and  other 
organic  agricultural 

chemicals 

Miscellaneous  chemicals 


4,171 
145 
39 
67 

28 

2,333 

127 

1,889 
268 
741 

418 
15,893 


4,699 
166 
44 
67 

34 

2,777 

145 

1,958 
293 
921 


356 
17, 669 


12.6 
14.2 
13.6 


19.0 

13.7 

3.7 

9.4 

24.3 


-14.8 
11.2 


1,544 
149 
36 
51 

27 

2,045 

94 

2,003 
202 
612 

331 
7,290 


1,874 
152 
37 
54 

31 

2,372 

103 

1,909 
235 
732 

334 
7,804 


21.4 
2.1 
2.8 
6.8 

17.3 

16.0 

9.5 

-4.7 
16.2 
19.6 


290 
171 


727 

54 

549 

75 

120 

133 
1,145 


341 
168 


47 
838 
60 

529 

83 
145 

118 
1,236 


17.6 
-1.9 
14.9 
-4.8 

17.1 

15.2 

11.7 

-3.5 

10.8 
21.1 

-11.1 
7.9 


1  Percentages  calculated  on  figures  rounded  to  thousands. 

^  This  total  involves  much  duplication. 

'  Excludes  products  derived  from  petroleum. 


Vll 


viii  SUMMARY 

million  pounds  reported  for  1952,    Sales  of  these  products  in  1953 
were  7,301  million  pounds,    valued  at  303  million  dollars. 

Production  of  all  synthetic  organic  chemicals  in  1953  (excluding 
the  raw  materials  mentioned  above)  totaled  29,129  million  pounds -- 
a  total  that  also  involves  considerable  duplication.    This  output 
represents  an  increase  of  11.5  percent  from  the  26,119  million 
pounds  produced  in  1952.    Compared  with  that  in  1952,    the  volume 
of  output  of  9  of  the   11  individual  groups  of  finished  synthetic 
organic    chemicals  and  that  of  the  group  of  intermediates  increased 
in  1953;  the  output  of  2  groups  declined.    Production  of  surface - 
active  agents  in  1953  increased  to  921  million  pounds  from  the    741 
million  pounds  reported  for  1952- -an  increase  of  24.  3  percent. 
Production  of  flavor  and  perfume  materials  increased  to  34  million 
pounds  (or  by  22.  1  percent);  plastics  and  resin  materials,    to  2,777 
million  pounds  (or  b^  19.0  percent);    dyes,    to  166  million  pounds 
(or  by  14.2  percent);  rubber-processing  chemicals,   to  145  million 
pounds  (or  by  13.7  percent);  toners    and  lakes,    to  44  million  pounds 
(or  by  13.6  percent);  intermediates,    to  4,699  million  pounds  (or  by 
12,6  percent);  miscellaneous  chemicals,    to  17,669  million  pounds 
(or  by  11.2  percent);  plasticizers,    to  293  million  pounds  (or  by  9.4 
percent);  and  elastomers,    to  1,958  million   pounds  (or  by  3.7  per- 
cent). 

Production  of  pesticides  and  other  organic  agricultural  chemi- 
cals   declined  to  356   million  pounds  in  1953  (or  by  14.8  percent 
compared  with  that  in  1952).    The  output  of  medicinals  in  1953- -67 
million  pounds- -represents  a  decline  of  0.3  percent  from  that  in 
1952. 


PART  I.  PRODUCTION  AND  SALES  OF  TARS,  TAR  CRUDES,  AND 
CRUDES  DERIVED  FROM  PETROLEUM  AND  NATURAL  GAS 

Tars 

Coal  tar  is  produced   chiefly  by  the  steel  industry  as  a  byprod- 
uct of  the  manufacture  of  coke.    Water-gas  tar  and  oil-gas  tar  are 
produced  by  the  fuel-gas  industry.    Production  of  coal  tar,    there- 
fore,   depends  on  the  demand  for  steel;  production  of  water-gas  tar 
and  oil-gas  tar  reflects  the    consumption  of  manufactured  gas  for 
industrial  and  household  use.     Water-gas  and  oil-gas  tars  have 
properties  intermediate  betv/een  those    of  petroleum   asphalts  and 
coal  tars.    Petroleum  asphalts  are  not  usually   considered  to  be 
raw  materials  for  chemicals. 

The  quantity  of  tar  produced  in  the  United  States  from  all 
sources  in  1953  was  901  million  gallons,    or  13.6   percent  more 
than  the  output  in  1952.    Of  the  total  quantity  produced  in  1953, 


-Tar:   United  States  production  and  consumption,    1952  and  1953 

[In  thousands  of  gallons] 


Total 

Water-gas  and  oil-gas  tar-"- 

Coal  tar, ^  total 

Coal  tar  from  coke-oven  byproduct  plants,  total- 

Plants  not  owned  by  city  gas  companies 

Plants  owned  by  city  gas  companies  (public  utilities) - 
Coal  tar  from  coal-gas  retort  plants 


CONSUMPTION 


Total- 


Tar  consumed  by  distillation,  total — 

Water-gas  and  oil-gas  tar  distilled  by  producers  and  tar  distillers* — 
Coal  tar  distilled  or  topped  by  coke-oven  operators^—-- — -——.—— 
Coal  tar  distilled  by  tar  distillers' 


Tar  consumed  chiefly  as  fuel,  total-- ______ 

Water-gas  and  oil-gas  tar  consumed  as  fuel'- 


Coal  tar  sold  or  consumed  as  fuel  by  coke-oven  operators^- 

As  fuel  under  boilers 

In  open-hearth  or  affiliated  plants 

Sold  as  fuel  by  coke-oven  operators  to  affiliates 

Sold  as  fuel  by  coke-oven  operators  to  others 


Tar  consumed  otherwise  than  by  distillation  or  as  fuel,  total- 
Coal  tar  from  retort  plants  sold  for  consumption^ 

Coal  tar  consumed  at  coke-oven  plants  for  roads  and  upkeep^_ 


Coal  tar,  water-gas  tar,  and  oil-gas  tar  processed  at  tar  refineries, 
crude  tar  consumed  for  upkeep  at  such  refineries,  and  tar  consumed  in 
making  gas  and  in  special-purpose  tar  blends' 


793,087 


88,282 
704,805 


703,890 

672,126 

31,76A 

915 


25; 274 
219,892 
226,520 

134,930 

id, hi 

114,592 
1,666 

107,734 

5,022 

170 

64,324 


9g3" 
,758 


67,290 
833,381 


828; 725 

802,044 

26,685 

3  4,652 


641,720 
41,557 
254,448 
345,315 

153,991 
9,667 

144,324 
3,152 

124,181 
12,536 
4,455 

82.040 
?7329 


^  Reported  to  the  American  Gas  Association. 

^  Reported  to  the  U.  S.  Bureau  of  Mines,  Department  of  the  Interior. 

^  Includes  low-temperature  carbonization  tar  not  included  in  1952. 

*  Reported  to  U.  S.  Tariff  Commission. 

'  Represents  tar  purchased  from  companies  operating  coke  ovens  and  gas-retort  plants  and  distilled  by 
companies  operating  tar-distillation  plants. 

*  Reported  to  the  American  Gas  Association  and  to  the  U.  S.  Tariff  Commission. 


2  UNITED  STATES  TARIFF  COMMISSION 

about  833  million  gallons  was  coal  tar  and  67  million  gallons  was 
water-gas  and  oil-gas  tars    (see  table  2).     The  corresponding 
figures  for  1952  were  705  million  gallons  of  coal  tar  and  88  million 
gallons  of  water-gas  and  oil-gas  tars.    The  decline  in  output  of 
water-gas  tar  and  oil-gas  tar  in  1953  was  the  result  of  further 
displacement  of  manufactured  gas  by  natural  gas- -particularly  in 
the  eastern  part  of  the  United  States. 

Of  the  total  consumption  of  tar  in  1953  (878   million  gallons), 
642  million  gallons  was  consumed  by  distillation,    154  million 
gallons  was  consumed  as  fuel,    and  82  million  gallons  was  con- 
sumed  in  miscellaneous  uses  such  as  refinery  upkeep  and  the 
making  of  special  road-tar  blends. 

The  total  quantity  of  tar  distilled  in  1953  was  170  million 
gallons  greater  than  in  1952;  the  quantity  consumed  as  fuel  was 
19  million  gallons  greater.    In  1953  the  quantity  of  tar  distilled  or 
topped  by  coke-oven  operators  was  254  million  gallons,    compared 
with  345  million  gallons  distilled  by  tar  distillers. 

Tar  Crudes 

Tar  crudes,    the  most  important  of  \vhich  are  benzene,    toluene, 
xylene,    and  naphthalene,    are  derived  from  coke-oven  gas  and  by 
distilling  coal  tar,    water-gas  tar,    and  oil-gas  tar.    Some  products 
identical  with  those  derived  from  coal  tar  are  also  derived  from 
petroleum  and  natural    gas;  these  latter  materials  are,    for  the 
most  part,    included  in  the  statistics  on  tar  crudes  which  are 
given  in  tables  3  and  4A. 

The  total  production  of  specification  and  industrial  grades  of 
benzene  in  1953  amounted  to  273  million  gallons,    compared  with 
252  million  gallons  in  1952.    These  totals  include  benzene  pro- 
duced from  tar,    from  domestic  and  imported  crude  light  oil,    from 
petroleum,    and  from  imported  motor-grade    benzene.    Sales  of 
benzene  in  1953  amounted  to  233  million  gallons,    valued  at  96 
million  dollars,    compared  with  217  million  gallons,    valued  at 
83  million  dollars,    in  1952.    Coke-oven  operators  accounted  for  the 
largest  part  of  the  benzene  production  in  1953  (178  million  gallons); 
production  of  nnotor-grade  benzene  by  these  operators  amounted 
to  slightly  more  than  1  million  gallons.    The  output  of  toluene  from 
all  sources  in  1953  amounted  to  156  million  gallons,    an  increase 
of  48.  4  percent  from  the  105  million  gallons  produced  in  1952. 
Sales  of  toluene  in  1953  totaled  130  million  gallons,    valued  at  39 
million  dollars,    compared  with  88  million  gallons,    valued  at  25 
million  dollars,    in  1952.    Petroleum  sources  accounted  for  about 
74  percent  of  the  total  output  of  toluene  in  1953. 

Production  of  xylene  in  1953  amounted  to   113  million  gallons, 
compared  with  72  million  gallons  in  1952.    Sales  of  xylene  in  1953 
were  66  million  gallons,    valued  at  17  million  dollars,    compared 
with  58  million  gallons,     valued  at  14  million  dollars,    in  1952.    In 
1953,    more  than  90  percent  of  the    xylene  produced  was  from 
peti-oleum  sources.    Production  of  naphthalene  in  1953  was  276 
million  pounds,    or   14.5  percent  less  than  the  output  of  322  million 
pounds  reported  for   1952.    Sales  in  1953  amounted  to  200  million 
pounds,    valued  at  11  million  dollars. 


^  See  also  table  4B,  part  III,  which  lists  these  products  and  identifies  the  manufacturers. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


TABLE  3. --Tar  and  tar  crudes:    Summary  of  production  and  sales  of  sped  fied  products ,    average  1948-52,    annual 

1952  and  1953 


Chemical^ 


Unit 

of 

quantity 


Average 
1948-52 


Increase,  or  decrease 
(-) 


1953 
over 
1948-52 


1953 
over 
1952 


Tar:  Productions- 
Benzene  : 

Production 

Sales 

Value  of  sales- 
Motor  benzene: 

Produc  tion 

Sales 

Value  of  sales- 
Toluene  : 

Production 

Sales 

Value  of  sales- 
Xylene : 

Production 

Sales 

Value  of  sales- 
Naphthalene  : 

Production 

Sales 

Value  of  sales- 
Creosote  oil: 

Produc  tion 

Sales 

Value  of  sales- 


1,000  gal— 

1,000  gal~ 
1,000  gal— 
1,000  dol— 

1,000  gal— 
1,000  gal— 
1,000  dol— 

1,000  gal— 
1,000  gal— 
1,000  dol— 

1,000  gal— 
1,000  gal — 
1,000  dol— 

1,000  lb 

1,000  lb 

1,000  dol — 

1,000  gal — 
1,000  gal — 
1,000  dol — 


930,218 

202,134 
181,565 
53,451 

'  13,295 
^  12,122 
^  1, 960 

91,159 
77,681 
19,869 

67,581 
51,227 
12,003 

306,051 
211,195 
11,342 

141,800 
133,873 
23,814 


793,087 

251,667 
216,998 
83,210 

(*) 
(*) 

105,297 
87,507 
24,890 

71,727 
57,810 
14,060 

322,485 
209, 765 
12,219 

138,722 
139,681 
25,476 


900,671 

272,74^ 
232,701 
95,765 

5  1,160 
=  1,150 
5   184 

156,248 
130,222 
39,244 

113,474 
65,588 
16,968 

275, 799 
200,086 

11,100 

145,300 
125,285 
25,020 


34.9 
28.2 
79.2 


71.4 
67.6 
97.5 

67.9 
28.0 

41.4 

-8.9 
-5.3 

-2.1 


8.4 
7.2 
15.1 


48.4 
48.8 
57.7 

58.2 
13.5 
20.7 

-14.5 
-4.6 
-9.2 

4.7 
-10.3 


^  For  details  concerning  statistics  shown  in  this  table,  see  table  4A. 

Includes  data  for  oil-gas  and  water-gas  tar  reported  to  the  American  Gas  Association  and  for  coal  tar 
reported  to  the  Coal  Economics  Division,  U.  S.  Bureau  of  Mines. 
4-year  average. 
*  Production  and  sales  of  motor  benzene  in  1952  were  negligible. 
Includes  data  for  coke-oven  operators  only. 

In  1953  the  output  of  creosote  oil  (  a  mixture  of  xylenols  and 
cresols  and  their  homologues  and  derivatives,    and   of   anthracene 
oil,    naphthalene,    and  some  phenols),    which   is  used  chiefly  in 
wood  preserving,    amounted  to  145  million  gallons- -somewhat 
more  than  the  139  million  gallons  produced  in  1952.    The  output 
of  road  tar  in  1953  was  110  million  gallons,    compared  with  112 
million  gallons  in  1952. 

Some  of  the  products  included  in  the  statistics  given  in  table 
4A  are  derived  from   other  products,    data  for  which  are  also 
included.    The  statistics,    therefore,    involve  some  duplication,    and 
for  this  reason  group  totals  and  grand  totals  are  not  given.    After 
as  much  duplication  as  possible  has  been  eliminated,    it  is  esti- 
mated that  in  1953  the  net  value  of  production  of  these  products 
and  of  tar  burned  as  fuel  was  344  million  dollars,    compared  with 
282  million  dollars  in  1952,    and  314  million  dollars  in  1951. 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  4A. --organic  chemicals:   United  States  production  and  sales  of  tar   crudes,    1953 

[Listed  below  are  all  tar  crudes  for  which  any  reported  data  on  production  or  sales  may  be  published.  Table 
<iB  in  part  III  lists  separately  all  products  for  which  data  on  production  or  sales  were  reported  and  iden- 
tifies the  manufacturers  reporting  to  the  U.  S.  Tariff  Commission  ] 


Crude  light  oil 

Intermediate  light  oil:  Coke-oven  operators 

Light-oil  distillates: 

Benzene,  specification  and  industrial 

grades,  total 

Tar  distillers^ 


Coke-oven  operators- 
Petroleimi  operators- 


Benzene,  motor  grade,  coke-oven  operators- 
Toluene,  all  grades,  total 

Tar  distillers 

Coke-oven  operators 

Petroleum  operators 

Xylene,  all  grades,  total 

Tar  distillers 


Coke-oven  operators 

Petroleum  operators 

Solvent  naphtha,  total 

Tar  distillers 


Coke-oven  operators ~ 

Other  light-oil  distillates,  total — 
Tar  distillers 


Coke-oven  operators- 


Pyridine  crude  bases  (dry  basis) :  Coke-oven 
operators-— 


Naphthalene,  crude  (solidifying  at  less  than 

79°  C.),^  total 

Tar  distillers 


Coke-oven  operators- 


Crude  tar-acid  oils: 
Tar  distillers 


Coke-oven  operators 

Cresylic  acid,  crude  (less  than  755t  distilling 
over  215°  C):  Tar  distillers 


Creosote  oil  (Dead  oil),*  total- 
Tar  distillers: 

Sold  or  consimied  as  such- 


Unit 
of 

quantity 


Sold  or  consumed  in  coal-tar  solution — 
Coke-oven  operators: 
Distillate  as  suoh- 
In  coal-tar  solution- 


Coal  tar  sold  or  consumed  in  coal-tar  solution: 
Tar  distillers 


All  other  distillate  products' 

Tar,  road — 

Tar  (crude  and  refined)  for  other  uses* 

Pitch  of  tar:  ' 

Soft  and  medium,  total ■-■  ■    - 

Soft  (Water  softening  point  less  than 
110°  F.  ASTM  D61-2i)- 


Medium  (Water  softening  point 
110°  F.  to  160°  F.)- 


1,000 
1,000 


1,000 
1,000 
1,000 
1,000 
1,000 
1,000 
1,000 
1,000 
1,000 
1,000 
1,000 
1,000 
1,000 
1,000 
1,000 
1,000 
1,000 
1,000 
1,000 


gal- 
gal- 
gal- 
gal- 


gal- 
gal- 
gal- 
gal- 
gal- 
gal- 
gal- 
gal- 
gal- 


1,000  gal- 


1,000  Ib- 
1,000  lb- 
1,000  Ib- 

1,000  gal- 
1,000  gaL 


Hard  (Water  softening  point  above  160     F.) — 
Pitch  of  tar  coke  and  pitch  emulsion 


1,000  lb 

1,000  gal~ 

1,000  gal~ 
1,000  gal~ 

1,000  gal~ 
1,000  gal~ 

1,000  gal~ 
1,000  gal— 
1,000  gal— 
1,000  gal— 

1,000  tons- 

1,000  tons- 

1,000  tons- 
1,000  tons- 
1,000  tons- 


Produc- 
tion 


304,091 
1,062 


272,  VW 

32, 108 

177,593 

63,043 

1,160 

156,248 

4,677 

36,036 

115,535 

113,474 

660 

9,928 

102,886 

15,661 

9,376 

6,285 

14,657 

8,560 

6,097 

551 


162,862 
112,937 


2,945 
24,812 


4,537 
145,300 


Quantity   Value 


83,368 
19,605 

31,343 
5,984 

8,370 
18,469 
109,832 
36,415 

1,174 

641 

533 
710 
38 


23,898 
1,065 


232,701 

19,224 

172,406 

41,071 

1,150 

130,222 

3,866 

35,445 

90,911 

65,588 

580 

9,759 

55,249 

15,389 

9,321 

6,068 

11,410 

8,153 

3,257 

456 


108,544 
91,542 


23,691 


125,285 


5,610 
204 


95,765 

8,496 

66,479 

20,790 

184 

39,244 

1,307 

11,075 

26, 862 

16,968 

213 

3,118 

13,637 

5,804 

4,281 

1,523 

3,512 

3,064 

448 

963 


11,100 


68,329 
20,012 

31,303 
5,641 

8,523 
16,537 
95,677 
36,095 

602 


6,713 
4,387 


298 
6,147 


25,020 


14,092 
3,945 

6,031 
952 

1,186 
3,217 
14,278 
7,585 

21,061 


12,812 
1,242 


Unit 
value^ 


$0.24 
.19 


.39 
.51 
.16 
.30 
.34 
.31 
.30 
.26 
.37 
.32 
.25 
.38 


.31 
.38 
.14 


.05 
.06 
.05 


.43 
.26 


31.25 
34.50 


^  Unit  value  per  gallon,  pound,  or  ton,  according  to  the  unit  specified;  calculated  on  rounded  figures. 

^  Includes  data  for  benzene  distilled  from  imported  crude  light  oil. 

^  Statistics  represent  the  combined  production  and  sales  of  the  three  commercial  grades  of  crude  naphthalene 
to  avoid  disclosiire  of  individual  company  operations.  As  there  is  some  conversion  between  grades  of  crude 
naphthalene,  the  published  totals  necessarily  include  some  duplication. 

*  The  statistics  include  data  only  for  material  sold  for  or  consumed  in  wood  preserving.  The  figures  do  not 
represent  the  total  distillate  that  could  be  used  as  creosote  oil,  from  which  other  products  are  extracted. 

'  Includes  data  for  neutral  and  high-boiling  oils,  shingle-stain  oil,  crude  and  semirefined  pyridine,  and 
other  products  produced  by  tar  distillers,  and  for  crude  sodium  phenolate  and  oarbolate,  produced  by  coke-oven 
operators . 

*  Includes  data  for  tar  used  or  sold  for  paints,  pipe  covering,  saturating,  etc. 

NOTE. — Statistics  for  materials  produced  in  coke  and  gas-retort  ovens  are  compiled  by  the  Coal  Economics 
Division  of  the  U.  S.  Bureau  of  Mines,  and  those  for  materials  produced  in  tar  and  petroleum  refineries  are 
compiled  by  the  U.  S.  Tariff  Commission. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953  5 

Crude  Products  From  Petroleum  and  Natural  Gas 
for  Chemical  Conversion 

The  crude  products  that  are  derived  from  petroleum  and  natural 
gas  are  related  to  the  products  made  from   them  in  much   the  same 
way  that  crude  products  derived  from  the  distillation  of  coal  tar 
are  related  to  their  intermediates  and  finished  products.    Many  of 
the  crude  products  derived  from  petroleum  are  identical  with  those 
derived  from  coal  tar  (e.  g.  ,    benzene,    toluene,    and  xylene).    Con- 
siderable duplication  exists  in  the  statistics  on  the  production  and 
sales  of  petroleum  crudes,    because  some  of  these  crude    chemicals 
are  converted  to  other  crude  products  derived  from  petroleum, 
and  because  data  on  production  and  sales  may  be  reported  at  suc- 
cessive stages  in  the  conversion  processes.    Notwithstanding  these 
duplications,    the  statistics  (see  table  5A^  )   are  sufficiently  accurate 
to  indicate  trends  in  the  industry,    and  to  serve  as  a  basis  for 
general  comparison.    Many  of  the  crude    products  for  which  data 
are  included  in  the  statistics  may  be  used  as  fuel  or  as  basic 
materials  from  which  to  derive  other  chemicals,     depending  upon 
prevailing  economic  conditions.    In  this  report,    however,    every 
effort  has  been  made  to  exclude  data  on  materials  that  are  used  as 
fuels. 

As  shown  in  table  5A,    production  in  1953  of  crude  products 
derived  from  petroleum  and  natural  gas  as  a  group  amounted  to 
11,147  million  pounds--an  increase  of  41.7  percent  from  the  7,867 
million  pounds  reported  for  1952.    The  larger  production  in  1953 
is  accounted  for  in  part  by  several  plants  which  began  operations 
in  that  year.    Sales  of  crude  chemicals  from  petroleum  in  1953 
were  7,301  million  pounds,    valued  at  303  million  dollars,     com- 
pared with  4,732  million  pounds,    valued  at  265  million  dollars,    in 
1952. 

Production  in  1953  of  all  aromatic  and  naphthenic  products 
amounted  to  2,506  million  pounds,    compared  with  1,605  million 
pounds  in  1952--an  increase  of  56  percent.    Sales  in  1953  were 
1,795  million  pounds,    valued  at  73  million  dollars,    an  increase 
of  515  million  pounds  in  quantity  and  26  million  dollars  in  value, 
compared  with  1952.    In    1953  production  of  specification-    and 
industrial-grade  benzene  from  petroleum  was  462  million  pounds, 
compared  with  256  million  pounds  in  1952  (an  increase    of  81  per- 
cent); the  output  of  toluene  from  petroleum  was  836  million  pounds 
in  1953,    compared  with  464  million  pounds  in  1952  (an  increase 
of  80  percent);  and  the  output  of  xylene  in  1953  was  749  million 
pounds,    compared  with  444  million  pounds  in  1952  (an  increase 
of  69  percent).    The  output  of  naphthenic  acids  amounted  to  23 
million  pounds  in  1953,    compared  with  19  million  pounds  in  1952, 
and  that  of   cresylic  acid  was  16  million  pounds  in  1953,    compared 
with    14  million  pounds  in  1952.    While  these  increases    can  be 
accounted  for  in  part  by  the  production  reported  by  new  companies, 
the  increased  output  probably  also  reflects  a  greater    use  of   cata- 
lytic re-forming  processes  by  the  refiners. 

The  output  of  all  aliphatic  hydrocarbons  and  derivatives  from 
petroleum  and  natural  gas  in  1953  was  8,641  million  pounds,    com- 
pared with  6,262  million  pounds  in  1952.    Sales  of  these  products 
in  1953  were  5,506  million  pounds,    valued  at  230  million  dollars. 


2  See  also  table  5B,  part  III,  which  lists  these  products  alphabetically  and  identifies 
the  manufacturers. 


6  UNITED  STATES  TARIFF  COMMISSION 

TABLE  5 A. --Synthetic  organic   chemicals:   United  States  production  and  sales  of   crude  products   from 
petroleum  and  natural  gas   for  chemical  conversion ,   1953 

[Listed  below  are  the  crude  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  any 
reported  data  on  production  or  sales  may  be  published.  (Leaders  are  used  where  the  reported  data  are 
confidential  and  may  not  be  published  or  where  no  data  were  reported.)  Table  5B  in  part  III  lists 
separately  all  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  data  on  produc- 
tion or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Quantity 


Unit 

value-"- 


Grand  total — 


AROMAIICS  AND  NAPHTHENES^ 


Total- 


Alkyl  aromatics,  distillates,  and  solvents- 
Benzene  (except  motor  grade),  total 

Benzene ,  1° 

Benzene ,  2° 

Cresylic  acid,  crude 

Naphthenic  acids,  total 

Acid  number  225-2^f9 

All  Q-ther 

Toluene,  all  grades,  total 

Nitration  grade,  1° 

Pure  commercial  grade,  2° 

All  other 


Xylenes,  mixed 

All  other* 


ALIPHAIIC  HmROCARBONS 


C2  hydrocarbons,   total- 
Ethane 

Ethylene ' 


C3  hydrocarbons,  total 

Propane- 


Propylene  and  propane-propylene  mixture- 


Ci,   hydrocarbons,  total 

1,3-Butadiene,  grade  for  rubber  (elastomers),  total- 
Produced  for  Government  account 

Produced  for  private  account 

n-Butane 

1-Butene,  2-butene,  and  mixtures'- 

Isobutane — 

All  other* 

C5  hydrocarbons' 


All  other  aliphatic  hydrocarbons  and  derivatives,  total - 

Dodecene  (Tetrapropylene) '■ 

Nonene  (Tripropylene)- 


Hydrocarbon  derivatives^°- 
All  other^^ 


i,000 
pounds 

11,147,060 


2,505,691 


75,975 
386,130 


16,080 
23,123 


10,999 
12,124 


836,473 


192,113 
282,338 
362,022 

749,010 
14,355 


8,641,369 


2,280,363 


144,623 
2,135,740 


1,366,175 
1,222,622 


3.167.169 


1,152,197 
1,051,468 
100,729 
418,144 
906,732 
155,589 
534, 507 

122,048 

482,992 


23,157 
176,926 

60,986 

2,681 

219,242 


7,301,453 


302,939 


1,795,099 


73,007 


399,420 
301,051 


9,123 
20,790 


6,246 


10,557 
3,737 


658,195 


320 
1,541 


166,440 


402,213 
13,680 


5,506,354 


26,862 


7,4^1 


13,637 
734 


229,932 


362,350 


12,761 


108,450 
253,900 


1,186,415 
671,833 


2.868.633 


720 
12,041 


20,221 


1,135,292 

267, 136 
882,803 
151,318 
432,084 

108,908 

308,215 


12,521 
7,700 


183,492 


136,235 

3,199 
26,714 

2,317 
15,027 

2,958 

10,500 


125,100 
4,828 
2,496 

175,791 


4,685 
217 
462 

5,136 


pound 

$0.04 


.03 


^  Calculated  on  rounded  figures. 

The  chemical  raw  materials  designated  as  aromatics  are  in  some  cases  identical  with  -those  obtained  from 
the  distillation  of  coal  tar.  However,  the  statistics  given  in  the  above  table  relate  only  to  such  materials 
as  are  derived  from  petroleum  and  natural  gas. 
^  Includes  a  small  amount  of  90-peroent  benzene. 

Includes  data  for  motor-grade  benzene,  cyclopentane,  dicyclopentadiene,  petroleum  phenols,  sodium 
carbolate  and  phenolate,  and  hydrocarbon  polymers. 

Includes  a  small  amount  of  ethylene  from  coke-oven  gas. 
*  Partly  estimated. 

''  The  statistics  represent  the  butene  content  of  crude  refinery  gases  from  which  butadiene  is  manufactured. 
Includes  data  for  isobutene,  1-butene,  2-butene,  butane-butylene,  and  butadiene-butene  mixtures  and 
concentrates . 

'  Includes  data  for  isoprene,  pentanes,  pentenes,  and  mixtures. 
^°   Includes  data  for  di-tert-butyldisulfide,  miscellaneous  mercaptans,  and  mixed  alkanesulfonic  and 
aliphatic  acids. 

^^  Includes  data  for  acetylene,  hexanes,  heptanes  and  heptenes,  methane,  octanes  and  ootenes,  polybuteno, 
eicosane,  and  hydrocarbon  mixtures. 


SYNTHETIC  ORGANIC  CHEMICALS,  i953  7 

compared  with  3,451  million  pounds,    valued  at  219  million  dollars, 
in  1952.   Production  of  ethylene  in  1953  was  2,136  million  pounds, 
compared  with  1,809   million  pounds  in  1952.    The  output  of  propane, 
propylene,    and  propane-propylene  nnixture  in  1953  was  2,589 
million  pounds,    compared  with  1,576  million  pounds  in  1952.    The 
production  of  1,  3 -butadiene  in  1953  was  1,152  million  pounds, 
compared  with  1,106  million  pounds  in  1952;  this  product  is  one  of 
the  principal  ingredients  of  GR-S   or  Buna-S  type  synthetic  rubber. 


I 


PART  II.  PRODUCTION  AND  SALES  OF  INTERMEDIATES  AND 
FINISHED  SYNTHETIC  ORGANIC  CHEMICALS,  BY  GROUPS 

General 

On  the  basis  of  their  principal  uses,    the  synthetic  organic 
chennicals  covered  in  this  report  are  classified  as  intermediates 
and  as  finished  products.    Finished  products,    in  turn,    are  grouped 
as  follows:  Dyes,    toners  and  lakes,    medicinals,    flavor  and  per- 
fume materials,    plastics  and  resin  materials,    rubber-processing 
chemicals,    elastomers  (synthetic  rubbers),    plasticizers,    surface- 
active  agents,    pesticides  and  other  organic  agricultural   chemicals, 
and  miscellaneous  synthetic  organic  chemicals.    Most  of  these 
groups  are  further  subdivided,    according  to  chemical   classes, 
into   cyclic  and  acyclic  compounds. 

As  many  of  the  intermediates  are  used  in  the  manufacture  of 
finished  products,    aggregate  figures  which  cover   both  inter- 
mediates and  finished  products  necessarily  include  much  dupli- 
cation. 

The  total  production  of  all  synthetic  organic  chemicals  (in- 
termediates and  finished  products  combined)  was  29,129  million 
pounds  in  1953,    or  3,010   million  pounds  more  than  the  output 
in  1952  (see  table  6),    and  1,630  million  pounds  more  than  the 
previous  record  output  of  27,499  million  pounds  in  1951.    Sales  in 
1953  totaled  15,637  million  pounds,    valued  at  4,030  million  dollars, 
compared  with  sales  of  14,384  million  pounds,    valued   at  3,783 
million  dollars,    in  1952.    Production  of  all  cyclic  products  in  1953 
totaled  9,637  million  pounds,    or  10.9   percent  more  than  in  1952. 
The  output   of  cyclic  intermediates  in  1953  was  4,699  million 
pounds,    connpared  with  4,171    million  pounds  in  1952--an  increase 
of  12.6  percent.    Production  of  all  finished  cyclic  products  in  1953 
was  4,939  million  pounds,    or  9.4  percent  more  than  in  1952.    Pro- 
duction in  1953  of  finished  acyclic  products  and  acyclic  inter- 
mediates (included  with  acyclic  miscellaneous  chemicals)  totaled 
19,491  million  pounds,    or  11.8  percent  more  than  the  17,433 
million  pounds  produced  in  1952. 

Of  the  individual  groups  of  finished  synthetic  organic  chemicals, 
six  increased  in  volunne  of  production  in  1953,    compared  with  1952, 
in  both  cyclic  and  acyclic  categories.    These  six  groups  (and  their 
percentage  increases)  are  as  follows:  Surface-active  agents  (cyclic, 
24.4  percent,    and  acyclic,    24.3  percent);  flavor  and  perfume  ma- 
terials (cyclic,    18.6  percent,    and  acyclic,    26.6   percent);  plas- 
tics and  resin  materials  (cyclic,    18.8  percent,    and  acyclic,    19.3 
percent);  rubber-processing  chemicals  (cyclic,    12.6   percent,    and 
acyclic,    19.9  percent);  elastomers  (cyclic,    1.5  percent,    and  acyclic, 
9.7   percent);  and  miscellaneous    chemicals    (cyclic,     10.9   percent, 
and  acyclic,    11.2  percent).    T'he  cyclic  component  of  the  medicinal 
group  declined  8.6  percent  in  1953,     compared  with  1952,  whereas 
the  acyclic  component  increased  41.5  percent.    For  pesticides  and 
other  organic  agricultural   chemicals,    the  output  of  the    cyclic 

313486   O  -  54  -  2  9 


10 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  6'--Syntbetxc  organic  chemicals:   Summary   of  United  States  production  end  sales  of  intermediates 
and  finished  products,   average  1948-52,    xinual  1952  and  1953 

[Production  and  sales  in  thousands  of  pounds;  sales  value  in  thousands  of  dollars] 


Average 
19i8-52 


Increase,  or 
decrease  (-) 


1953 
over 

ig-vs-sa 


Production,  grand  total 

Sales,  grand  total 

Sales  value,  grand  total 

I.  ORGANIC  CHEMICALS,  CYCLIC 

Production,  total 

Sales ,  total 

Sales  value,  total 

A.  INTERMEDIATES 

Production 

Sales 

Sales  value 

B.  FINISHED  PRODUCTS 

Production,  total 

Sales ,  total 

Sales  value,  total 

i.  Dyes 

Production,  total 

Sales  value,  total 

a.  Colour  Index  Group 

Production 

Sales 

Sales  value 


b.  Prototype  Group 


Production 

Sales 

Sales  value 


0.  Ungrouped 


Production- 
Sales 


Sales  value 

2.  Tontrs    and  Lake 


Production- 
Sales 


Sales  value- 


3.    Medicinals 


Production — 
Sales 


Sales  value 


i.    Flavor   and  Perfume  UateriaU 


Production 

Sales 

Sales  value-—- 


5.    Plastics    and  Resin  Materials 


Production — 









6.   fl 

ibber 

-Proces 

ing 

Chest 

ieal< 

Sales-     

Sales  value — 



, 

_^_ 

22,390,675 
11,930,716 
2,9<i3,868 


7,070,171 
4,462,820 
1,552,971 


3,494,976 

1,367,014 

239, 586 


3,575,195 
3,095,806 
1,313,385 


173,754 
164,001 
168,902 


125,151 
119,065 
90,212 


26, 587 
24,406 
42,794 


22,016 
20, 530 
35,896 


42,271 
37, 330 
46, 325 


46,44^ 
38,594 
338,632 


16,801 
14,028 
20,034 


1,175,713 
958,004 
249,998 


94, 569 
70,586 
34,044 


26,119,201 
14,384,021 
3,783,031 


8,686,038 
5,548,476 
1,953,286 


4,171,124 

1,544,388 

290,278 


4,514,914 
4,004,088 
1,663,008 


145, 209 
148,603 
170,699 


101,131 
101,640 
83,975 


24,101 
25,457 
46, 532 


19,977 
21,506 
40,192 


38,779 
35,666 
48,748 


55,803 
42,828 
407,207 


15,565 
14,311 
19,278 


1,351,329 

1,112,786 

310,239 


107,905 
77,718 
42,054 


29,128,545 
15,636,993 
4,030,357 


9,637,093 
6,072,460 
2,011,311 


4,698,585 

1,874,175 

341,421 


4,938,508 
4,198,285 
1,669,890 


165,806 
151,675 
167,526 


117,206 

107,986 

89,546 


32,612 
29,516 
49,586 


15,988 
14,173 
28,394 


44,056 
36,661 
56,031 


51,003 
41,080 
380,914 


18,458 
16, 512 
21,419 


1,605,447 

1,317,069 

362,958 


121, 532 
85,495 
47, 592 


36.3 
36.1 


34.4 
37.1 
42.5 


38.1 
35.6 
27.1 


-4.6 
-7.5 


-6.3 
-9.3 


22.7 
20.9 
15.9 


-27.4 
-31.0 
-21.9 


9.8 

6.4 

12.5 


9.9 
17.7 
6.9 


36.6 
37.5 
45.2 


28.5 
21.1 
39.8 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


11 


TABLE  6. -Synthetic  organic  chemicals:    Summary  of  United  States  production  and  sales  of  intermediates 
and  finished  products,    average  1948-52,    annual   1952  and   /953- -Continued 

[Production  and  sales  in  thousands  of  pounds;  sales  value  in  thousands  of  dollars] 


I.  ORGANIC  CIEMICAIS,  CYCLIC—Continued 

B.  FINISHED  PRODUCTS— Continued 

7.  Elastomers    (Synthetic  Bubbtrs) 

Production 

Sales 

Sales  value 

8.  Plasticizers 

9.    Surface-Active   Agents 
Sales  value 


10.    Pesticides    and  Other 
Organic  Agricultural    Chemicals^ 


Production 

Sales 

Sales  value- 


11.    Miscellane 


Production 

Sales- 
Sales  value- 


II.  ORGANIC  CHEMICAI3,  ACYCLIC  (INTERMEDIATES 
AND  FINISHED  PRODUCTS) 


Production,  total 

Sales,  total 

Sales  value,  total — 


Production 

Sales 

Sales  value — — - 


2.  Flavor    and  Perfume  Materials 
Production 


Sales  value- 


3.    Plastics    and  Besin  Materials 


Production- 
Sales 


i.   Rubber-Processing  Chemicals 


Production 

Sales 


Average 
19';8-52 


Sales  value- 


5.    Elastomers    (Synthetic  Rubbers) 


Production 

Sales 

Sales  value 


1,060,050 

l,0'i7,575 

229,865 


162,100 
122,428 
44,496 


344,002 

276,296 

52,061 


256,679 
206,441 
78,008 


202, 812 

160, 523 

51,020 


15,320,504 
7,467,896 
1,390,897 


8,520 

6,876 

22,540 


9,560 
9,232 

14,724 


804,664 
731,974 
303,274 


16,673 
14,074 
10,498 


376, 520 
369,906 
135,421 


1,393,559 

1,513,986 

361,112 


194,362 

144, 539 

51,126 


477,643 

380,968 

64, 371 


371,890 
289,4^1 
110,659 


362,870 

243,242 

77,515 


17,433,163 
8,835,545 
1,829,745 


11,012 

7,955 

22,595 


12,177 
12, 176 
20,467 


981,863 
932,218 
417,010 


19,395 
16,589 
11,701 


495,324 
489,406 
187,620 


1,414,944 

1,387,198 

319,056 


223,810 

180,137 

59,955 


594,089 
438,491 
73,301 


297,054 

281,652 

98,572 


402,309 
262,315 
82,566 


19,491,452 
9,564,533 
2,019,046 


15,582 
13, 147 
28,154 


15,413 
14, 568 
25,109 


1,171,180 

1,054,911 

474, 578 


23,252 
17,726 
12,463 


543,406 
521,595 
210,308 


Increase,  or 
decrease  (-) 


1953 

over 

1948-52 


33.5 
32.4 
38.8 


72.7 
58.7 
40.8 


15.7 
36.4 
26.4 


63.4 
61.8 


28.1 
45.2 


82.9 
91.2 
24.9 


61.2 
57.8 
70.5 


45.5 
44.1 
56.5 


39.5 
25.9 
18.7 


44.3 
41.0 
55.3 


1953 
over 
1952 


-8.4 
-11.6 


24.4 
15.1 
13.9 


-20.1 
-2.7 
-10.9 


11.8 

8.3 

-IQ.^' 


41.5 
65,3 
24.6 


26.6 
19.6 
22.7 


19.3 
13.2 
13.8 


19.9 
6.9 
6.5 


9.7 
6.6 

12.1 


See  footnotes  at  end  of  table. 


12 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  6.--Synthetic  organic  chemicals:   Swimary  of  United  States  production  and  sales  of  intermediates 
and  finished  products,    average  1943-52,    annual  1952  and  l953--Continued 

[Production  and  sales  in  thousands  of  pounds;   sales  value  in  thousands  of  dollars] 


Average 
19A8-52 


Increase,   or 
decrease   (-) 


1953 
over 
19^8-52 


1953 
over 
1952 


II.  ORGANIC  CHEMICALS,  ACYCLIC  (INTERMEDIATES 
AND  FINISHED  PRODUCTS)— Continued 


Production — — — 

Sales  value — — 


7.  Surfa 


Production 

Sales 











«. 
Organ 

Pest 

c  Agr 

cidts 
culti 

and  Othe 
ral   Chtmi 

cal 

Sales 



Production- 
Sales 


Sales  value- 


58,955 
«,836 
18,911 


239,002 

198,006 

57,017 


33,085 
28,311 
11,586 


13,773,525 

6,063,681 

816,926 


73,362 
57,75-; 
24,114 


263, 504 

231,328 

55,345 


45,734 
41,874 
22,700 


15,530,792 
7,046,245 
1,068,193 


69,088 
54,929 
23,380 


327,505 
293,613 
71,671 


58,899 
52,494 
19,945 


17,267,127 
7,541,550 
1,153,438 


17.2 
19.8 
23.6 


37.0 
48.3 
25.7 


78.0 
85.4 
72.1 


25.4 
24.4 
41.2 


-5.8 
-4.9 
-3.0 


24.3 
26.9 
29.5 


28.8 
25.4 
-12.1 


11.2 
7.0 
8.0 


Data  on  pesticides  and  other  organic  agricultural  chemicals  were  shovm  in  1951  for  the  first  time  in  a 
separate  section  of  this  report;  the  data  for  1948-50  have  been  adjusted  to  make  them  ooii?)arable  with  those 
for  1951-53. 

^  Data  on  miscellaneous  chemicals  given  in  this  table  exclude  pesticides  and  other  organic  agricultural 
chemicals  for  the  years  1948-50.  Data  on  pesticides  and  other  organic  agricultural  chemicals  were  included 
with  those  on  miscellaneous  chemicals  in  reports  for  years  before  1951.  Statistics  on  miscellaneous  chemi- 
cals for  1948-50  have  been  adjusted  to  make  these  data  coii5)arable  with  those  for  1951-53. 

^  Statistics  for  acyclic  plasticizers  and  surface-active  agents  in  1953  are  not  strictly  coii?)arable  with 
statistics  for  earlier  years;  some  items  previously  reported  as  plasticizers  were  reclassified  as  surface- 
active  agents  in  1953.  The  items  transferred  amounted  to  about  25  percent  of  the  total  production  of  acyclic 
plasticizers  and  to  less  than  2  percent  of  the  total  production  of  acyclic  surface-active  agents  in  1953. 


group   declined  ZO.l  percent  and  that  of  the  acyclic  group   increased 
28.8   percent.    In  the  plasticizer  group  the  cyclic  component   in- 
creased   15.2  percent;  the  acyclic  component  declined    5.8  percent 
(partly  as  a  result  of  the  transfer  of  certain  compounds  in  this 
group  to  the  group  of    surface-active  agents).    The  output  of  all  dyes 
in  1953  increased  14.2  percent,    and  that  of  toners  and  lakes,    13.6 
percent,    compared  with  1952. 

The  tabulation  below  shows,  by  chemical  group,  the  number  of 
companies  that  reported  production  in  1953  of  one  or  more  of  the 
chemicals  included  in  the  groups  listed  in  table  6. 


Group  Number  of  companies 

Intermediates 144 

Dyes 52 

Toners  and  lakes 42 

Medicinals 126 

Flavor  and  perfume  materials 52 

Plastics  and  resin  materials 148 


Group  Number  of  companies 

Rubber-processing  chemicals  18 

Elastomers  (synthetic  rubbers) 19 

Plasticizers 57 

Surface-active  agents 152 

Pesticides  and  other  organic 

agricultural  chemicals 82 

Miscellaneous  chemicals • 218 


SYNTHETIC  ORGANIC  CHEMICALS,  1953  13 

Cyclic  Intermediates 

Cyclic  intermediates  are  synthetic  organic  chemicals  derived 
principally  from  coal-tar  crudes  produced  by  destructive  distil- 
lation (pyrolysis)  of  coal.    In  recent  years,    however,    increasing 
quantities  of  cyclic  intermediates  have   been   obtained  from  petro- 
leum and  natural  gas.  Most  cyclic  intermediates  are  used  in  the  manu- 
facture of  more  advanced  synthetic  organic  chemicals  and  finished 
products,    such  as  dyes,   medicinals,    explosives,    elastomers 
(synthetic  rubbers),    pesticides,    and  plastics  and  resin  materials. 
Some  intermediates,    however,    are  sold  as  end  products  without 
further  processing.    For  example,    refined  naphthalene  may  be  used 
as  a  raw  material  in  the  manufacture  of  phthalic  anhydride,     2- 
naphthol,    or   other  more  advanced  intermediates,    or  it  may  be 
packaged  and  sold  as  a  moth  repellent  or  as  a  deodorant.  In  general, 
the  way  in  which  the  greater  part   of  the  output  of  a  given   chemical 
is    consumed  determines  its  use  classification  in  this  report. 

Table    TA-"-     shows  statistics  on  production  and  sales  of  cyclic 
intermediates  in  1953.    Intermediates  for  which  individual  statistics 
are  given  in  the  table  represent  64   percent  of  the  total   quantity 
produced.    Since  many  of  the  intermediates    included  in  the  statis- 
tics represent  successive  steps  in  production,    the  totals  neces- 
sarily include  considerable  duplication.    In  1953,    40  percent  of  the 
total  output  of  cyclic  intermediates  was  sold;  the  rest  was  con- 
sumed chiefly  by  the  producing  plants  in  the  manufacture  of  more 
advanced  intermediates  and  finished  products. 

The  total  output  of  all  cyclic  intermediates  in  1953  was  4,699 
million  pounds,    or  3.8  percent  more  than  the  previous  record  out- 
put of  4,528  million  pounds  reported  for  1951,    and  12.6  percent 
more  than  the  4,171  million  pounds  reported  for  1952.    Sales  in 
1953  amounted  to  1,874  million  pounds,    valued  at  341  million 
dollars,    compared  with  1,544   million  pounds,    valued  at  290  million 
dollars,    in  1952,    and  1,802  million  pounds,    valued  at  338  nnillion 
dollars,    in  1951.    The  unit  value  of  sales  was  18   cents  per  pound 
in  1953,    compared  with  19  cents  per  pound  in  both  1951  and  1952. 

In  1953,    the  output  of  many  individual  intermediates    was  sub- 
stantially  greater  than  it  was  in  1952.    The  output  of  styrene,  which 
is  used  in  the  manufacture  of  plastics  materials  and  GR-S    syn- 
thetic rubber,    reached  a    record  total  of  798  million  pounds  in  1953, 
compared  with  700  million  pounds  in  1952.    In  1953,    the  production 
of  phenol,    which  is  used  chiefly  in  the  manufacture  of  phenolic 
resins,    was  382  million  pounds,    or  13.2  percent  more  than  the  338 
million  pounds  produced  in  1952;  the  output  of  dodecylbenzenes, 
used  chiefly  in  the  manufacture  of  surface -active  agents,    was  297 
million  pounds,    or  43.9   percent  more  than  the  207  million  pounds 
produced  in  1952.    Other  large-volume  intermediates  the  production 
of  which  in  1953  increased  by  substantial  percentages  over  that  in 
1952,    were  p-dichlorobenzene    (21 .8  percent) ,     cyclohexane    (18.7 
percent),    aniline  (18.4   percent),    cresylic  acid  (12.1    percent),    and 
nitrobenzene  (7.3  percent).     On  the  other  hand,  important  inter- 
mediates for  which  production  showed  decreases  from  1952  to  1953 
were  refined  naphthalene  (18.6  percent);  cresols    (11.8  percent); 
and  monochlorobenzene  (1.6  percent). 

^  See  also  table  7B,  part  III,  which  lists  these  products  alphabetically  and  identifies  the 
manufacturers;  part  A  of  the  appendix,  which  shows  imports  of  intermediates  and  related 
products  during  1951-53;  and  part  C  of  the  appendix,  which  is  a  glossary  of  synonymous 
names  of  cyclic  intermediates. 


14 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  7A. --Synthetic  organic  chemicals:    United  States  production  and  sales  of  cyclic   intermediates,   1953 

[Listed  below  are  all  cyclic  intermediates  for  which  any  reported  data  on  production  or  sales  may  be  pub- 
lished. (Leaders  are  used  where  the  reported  data  are  confidential  and  may  not  be  published  or  where  no 
data  were  reported.)  Table  7B  in  part  III  lists  alphabetically  all  cyclic  intermediates  for  which  data  on 
production  or  sales  were  reported  and  identifies  the  manufacturer  of  each.  Part  C  in  the  appendix  lists 
alphabetically  all  the  important  common  names  of  cyclic  intermediates  usually  net  with  in  the  trade  and 
gives  the  corresponding  standard  (Chemical  Abstracts)  name  under  which  data  are  presented  In  tables  7A 
and  7B]  


Total 


Chemicals  for  which  separate  statistics  may  not  be  shown 

Chemicals  for  which  separate  statistics  are  shown  below 

Acetanilide,  teoh- 


N-Acetylsulfanilyl  chloride 

p-Amlnoacetanilide  (Acetyl-p-phenylenediamine ) 

2-(p-Aminoanilino )-5-nitrobenzenesulf onic  acid 

1-Amlnoanthraquinone  and  salt- 
2-Aminoanthraquinone  and  salt- 


6-Amino-3,4-'-azobis[benzenesulfonio  acid]  - 
1-Amino-^benzamidoanthraquinone- 


6-  (m-Aminobenzamido )  -l-naphthol-3-sulf onic  acid 

6- (p-Aminobenzamido )-l-naphthol-3-sulf onic  acid 

2-Amlno-p-benzenedisulfonic  acid  [s03H=l] 

l-Amino-'4-bromo-2-anthraquinonesulfonic  acid  and  salt 

l-Amino-5-chloroanthraquinone 

2-Amino-<i-chlorophenol 


2-Amino-5-chloro-p-toluenesulf onic  acid  [S03H=l] 

l-Amino-A-hydroxyanthraquinone  (l-Hydroxy-<i-aminoanthraquinone ) 

3-Amino-l,5-naphthalenedisulfonic  acid  (Cassella  acid)  and  sodium 

salt 

6-Amino-l,3-naphthalenedisulfonic  acid  (Amino  I  acid) 

2-Amino-l-naphthalenesulfonic  acid  (Tobias  acid) 

5-Amino-l-naphthaleneeulfonic  acid  (Laurent's  acid) 

5-Amino-2-naphthalenesulfonic  acid  (1,6-Cleve's  acid) 

5 (and  8)-Amino-2-naphthalenesulfonic  acid  (Cleve's  acid,  mixed) 

6-Amino-2-naphthalenesulfonio  acid  (Broenner's  acid)- 


S-Amino-l-naphthalenesulfonio  acid  (Peri  acid) 

8-Amino-2-naphthalenesulfonic  acid  (l,7-Cleve's  acid) 

8-Amino-2-naphthol- 


3-Aj!iino-l-naphthol-3,6-disulfonio  acid   (H  acid),   monosodium  salt- 
8-Amlno-l-naphthol-5,7-disulfonio  acid  (Chicago  acid)    (2S  acid), 

monosodium  salt — 

l-Amino-2-naphthol-4-3ulfonic  acid  (1, 2,^Acld) 

6-Amlno-l-naphthol-3-sulfonic  acid  (I  acid),  sodium  salt 

7-Amino-l-naphthol-3-sulfonic  acid  (Gamma  acid),  sodium  salt- 

8-Amino-l-naphthol-5-sulfonie  acid  (S  acid),  sodium  salt 

2-Amino-5-nitrobenzenesulfonlc  acid  [S03H=l] 

2-Amino-'4-nitrophenol _____ 

m-Aminophenol ,..---■— 

2-Amino-l-phenol-4-sulfonamide -— 

2-Amino-l-phenol-'i-sulfonlc  acid 


4,698,585 


1,681,985 
3,016,600 


p_(p-Aminophenylazo )benzenesulf onic  acid — - 

4_Amino-m-toluenesulfonic  acid  [SOsH'lJ- 


and  5-Amino-o-toluenesulfonic  acids  [S03H=1],  total- 

2-Ajiiino-3,5-xylenesulfonic  acid  [S03H=l] 

Aniline  (Aniline  oil) — __ 


Anilinomethanesulfonio  acid  and  salt-—— _— — -_ — 

8_Anilino-l-naphthalenesulfonio  acid  (Phenyl  perl  acid) 

6-Anilino-l-naphthol-3-sulfonic  acid  (Phenyl  J  acid) 

7-Anilino-l-naphthol-3-sulfonic  acid  (Phenyl  gamma  acid) 

Anthranllic  acid  (o-Aminobenzoic  acid) 

1,5-Anthraquinonedisulfonic  acid  and  salt ~ 

1,8-Anthraquinonedisulfonic  acid  and  potassium  salt 

2,6-Anthraquinonedisulfonio  acid  and  salt 

1-Anthraquinonesulfonic  acid  and  salt 

Anthr aruf in  ( 1 , 5-Dihydroxyanthraquinone ) 

1-Benzamido- 5-ohloroanthr aquinone- 


7-Benz [de J  anthracen-7-one  (Benzanthrone ) 

Benzenesulfonic  acid,  sodium  salt 

Benzidine  base-™ — — 

Benzidine  hydrochloride  and  sulfate 

Benzoin 


o-Benzoylbenzoic  acid- 

Benzyl  ether  (Dibenzyl  ether) 

('i,4'-Bi-7-benz[de]  anthracen)-7,7'-dione 

l,4-Bis[l-anthraquinonylamino]anthrBquinone- 


4,';68 
3,775 
183 
21 
1,17-; 
1,095 


906 
18 

223 

1,152 

3,286 

129 

140 

194 

74 

333 

139 

19 

2,437 

110 

712 

845 

762 

32 

64 

82 

364 


149 
337 


113,487 

214 

357 

66 

16 

303 

431 

69 

345 

3,011 

119 

119 

1,900 

17 
1,413 

50 
6,970 

65 
512 

85 


Quantity    Value  y^^^^i 


1,874,175 


325,588 
1, 548, 587 


3,438 


1,000 
dollars 

341,421 


104, 815 
236,606 


32 
1,110 


$0.18 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 

TABLE  7 A^  -Synthetic    organic  chemicals:    United  States  production  and  sales  of  cyclic   intermediates, 

i95J- -Continued 


15 


Quantity 


Unit 
value^ 


3 , 9-Bis  p.-anthraquinonylaiiiino]  -7-benz  [de  ]  anthracen-7-one 

^,'4'-Bis[dimethylaiiiino]benzhydrol   (Miohler's  hydrol) 

4,<l'-Bis[dimethylamino]benzophenone   (Miohler's  ketone) 

3-Broino-7-benz  [de  ]anthraoen-7-one  (Bromobenzanthrone ) 

•i-Bromobenzophenone — — 

m-Chloroaniline — 

l-Chloroanthraqainone— — 

Chlorobenzene ,  mono — — 

o- (p-Chlorobenzoyl )benzoio  acid 

l-Chloro-2, ^dinitrobenzene   (Dlnitroohlorobenzene ) 

l-Chloro-2-methylanthraqviinone — 

2-Chloro-4-5itroaniline    (o-Chloro-p-nitroanillne ) 

'4-Chloro-2-nitroaniline   (p-Chloro-o-nitroanillne ) 

4-C]hloro-3-nitrobenzenesulfonainide 


2-Chloro-5-nitrobenzenesulfonio  acid ~ ~ 

(p-Chlorophenyl)acetonitrile 

a-Chlorotoluene   (Benzyl  chloride ) • 

4-Chloro-o-toluidine    [CH3=1]    (Red  KB  base) 

4-Chloro-o-toluidine  hydrochloride 

"i-Chloro-o-tolylmeroaptoacetio  acid 

'l-Chloro-2,  S-xylylmercaptoacetio  acid 

Cresols,  total^- 


Cresols,  (o-),  (m-),  and  (p-) 

Cresols  (meta,  para,  an.''  ortho,  meta,  para)^ 

Cresylic  acid,  refined,  total^ 

From  coal  tar — — 


Cyclohexane 

1 , 4-Diaiiiinoanthraquinone — 

2 , 6-Diaiiiinoanthraqulnone 

2,'4-Diaminobenzenesulfonic  acid    [SOsH'l] 

'l,^'-Diaiiiino-3,3'-biphenyldisulfonic  acid 

2 , 2 '-Diamino-5, S'-bi-m-toluenesulf onic  acid 

A,  A  '-Diaminodiphenylanilne-2-sulf onio  acid— — 

N,  N  '-Di  (m-aminophenyl  )oxamide -~ 

A ,  A  '-Diainino-2 , 2  '-stilbenedisulf onic  acid 

l,5-Dlanilino-2,6-anthraquinonedicarboxylio  acid 

2 ,  ^Dianilino-1-hydroxyanthraquinone 

A , 5 ^-Dlbenznmi  do-1 , l' -iminodianthr aqulnone 

3,9-Dibromo-7-benz  [de]  anthraeen-7-one 

2, 5-Dichloroaniline  and  hydrochloride  [NH2=l] 

1, 5(and  1 , 8  )-Dichloroanthraquinone ~ 

1,8-Dichloroanthraquinone 

3,3'-Dichlorobenzldine  base  and  salts 

1, 4-Dichloro-2-nitrobenzene  (Nitro-p-dichlorobenzene ) -— 

2,  "i-Diohlorophenol- 


1- (2, S-Diehloro-A-sulf ophenyl )-3-methyl-5-pyrazolone 

2 , 6-Dichlorotoluene — — 

N,N-Diethyl-3-aiiilnophenol 

N, N-Diethylaniline- 


6,7-Dlhydroxy-2-naphthalenesulfonio  acid 

16,17-Dihydroxyviolanthrone  (Dihydroxydibenzanthrone) 

3, 3 '-Dimethoxybenzidine 

2,2' -Dimethyl-l , 1 ' -b  ianthraquinone- 


4, 4 '-Dinitro-2, 2 '-stilbenedisulf onic  acid  and  sodium  salt 

1 , 4-Di  (p-toluidino  )anthraquinone-— — _______ 

Dodecylbenzenes* : 

2-(N-Ethylanilino)ethanol 

a_ (N-Ethylanilino )-p_toluenesulf onic  acid 

o_Fonnylbenzenesulfonio  acid  (o_Sulf obenzaldehyde ) 

~  p-Hydrazinobenzenesulf onic  acid 

3-Hydroxy-2-naphthoic  acid  (B.O.N.) 

1,  l'_Iminobis  [4-amiiioanthraquinone] 

6,6'-Iminobis  [l-naphthol-3-sulfonic  acid]    (I    (or  J)  acid  imide) 

l,l'_Imlnodianthraqulnone  (Dianthrimlde)__ -_ — — 

Leuoo-l,<l-diaminoanthraquinone 

Leuco  quinizarin  (l,'l,9,10_Anthratetrol) 

Metanllic  acid  (m_Aminobenzenesulfonlc  acid)  and  salt 

o-Methoxyanilinomethanesulfonic  acid,  sodium  salt 

2-Methyl-l_nitroanthraquinone- 


3-Methyl_l_phenyl-5-pyrazolone  (Developer  Z) 

3-Methyl_l- (p_sulf ophenyl )-5_pyrazolone 

See  footnotes  at  end  of  table. 


1,000 
pounds 

259 

11 

141 

235 

10 

1,065 

170 

629 

377,184 

852 

4,695 

192 

415 

155 

128 

5 

39 

10,491 

81 

31 

142 

27 

18,757 


4,216 
14, 541 


50,647 


20,626 
30,021 

299, 578 

59 

251 

74 

19 

24 

16 

35 

941 

9 

31 

175 

191 

172 

47 

38 

59 

26,230 

59,289 

1,086 

814 

15,436 

65 

26 

152 

768 

276 

470 

505 

128 

1,147 

79 

297,286 

150 

299 

125 

165 

3,571 

139 

44 

152 

170 

169 

1,114 

24 

210 

228 

99 


1,000 
pounds 


10 
622 


50,184 


1,000 
dollars 


32 

447 


4,235 


Ptr 
pound 


$3,20 
.72 


1,048 


4,351 
13,415 


47,325 


21,364 
25,961 

114,624 


1,584 
1,650 


4,117 


2,217 
1,900 


6,500 


20,424 
42,655 


2,013 
5,787 


276,284 


32,419 


2.40 
.20 


.10 
.14 


16  UNITED  STATES  TARIFF  COMMISSION 

TABLE  TA. --Synthetic  orgaiic  chemicals:    United  States  production  and  sales   of  cyclic   intermediates, 

1953- -Continued 


Production 


C,  or  above  (refined  flake),  total- 


Naphthalenf   solidifying  at  79 

From  American  crude  naphthalene 

From  imported  crude  naphthalene 

1 . 5-Naphthalenediol  (1, 5-Dihydroxynaphthalene ) 

1, 5-Naphthalenedisulf onic  acid 

Naphthionio  acid,  sodium  salt 

1-Naphthol  (a-Naphthol ) 

2-Naphthol-3,6-diaulfonic  acid  and  disodium  salt 

2-Naphthol-6,8-disulfonio  acid  (G  acid) 

l-Naphthol'-i-sulfonio  acid  (Nevile  &  Winther's  acid) 

l-Naphthol-5-sulfonie  acid  and  sodium  salt 

2-Naphthol-6-sulfonic  acid  (Schaeffer's  acid) 

Naphth[l, 2] oxadiazole-5-sulfonio  acid 

2-Naphthylmercaptoaoetic  acid  (;3-Naphthylthioglycolio  acid) 

2-Nitro-p-anis Idine  [ NHj  =1 ] 

4-Nitro-o-anisidine  f NHa  =1 1 

5-Nitro-o-ani3idine  [ NHj  =1] 

l-Nitro-2-anthraquinonecarboxylic  acid 

5(and  8)-Nitro-l-anthraquinonesulfonli  acid- 


6-(m-Nitrobenzaiiiido)-l-naphthol-3-sulfonic  acid   (m-Nitrobenzoyl  J 


aoid)- 
6-(p-Nitrobenzamldo)-l-naphthol-3-sulfonic  acid  (p-Nitrobenzoyl  J 

Nitrobenzene- 


m-Nitrobenzenesulfonio  acid  and  sodium  salt- 

m-  and  p-Nitrobenzoic  acids,  total --- 

p-Nitrosophenol ~ 

5-Nitro-o-toluenesulfonic  acid 

2-Nitro-p-toluidine  [ NHa  =1 ] 

Nitroxylenes ,  mixed 

Nonylphenol — ~ 


Phenol,  total^ 

Natural,  from  coal  tar  and  petroleum- 
Synthetic 


Phenylacetio  acid  (a-Toluic  acid) 

Phenylacetio  acid,  ethyl  ester,  all  grades- 
Phenylaeetio  acid,  potassium  aalt- 


Phenylacetonitrile  (a-Tolunitrile ) 

p-Phenylazoanlline  (p-Aminoazobenzene )  and  hydrochloride 

o-  and  p-Phenylenedlamines,  total 

Phenylglyclne,  potassium  and  sodium  salts,  total-— — — 

2,2'-(Phenylimlno)dlethanol 

Phthalic  anhydride 

Pioolines' 

Priffluline ,  base 

Propiophenone— — — — — —__ — - — — ■ 

Pseudocumidine  (Cumldine )— — - — — ___- — — 

Quinaldine -. 

Quinizarln 

Salicylic  acid,  tech 


Styrene 

1,4, 5, 8-Tetraohloroanthraquinone 

1,2,'4,5-Tetraohlorobenzene 

1, 4, 5, 8-Tetrakia  [l' , l"  ,  l" ' ,  1 ' "  '-anthraquinonylamlno]  anthraqulnone 
(Pentaanthramide )- 


o-Tolidine  and  salts 

Toluene-2 , 4-diamine  (4-m-Tolylenediamlne ) 

6-p-Toluldinometanlllo  acid 

m^  arid  o-Toluidinomethanesulfonic  acids,  total 

4-(o-Tolylazo)-o-toluidine  (o-Aminoazotoluene) 

6,6'-Ureylenebis[l-naphthol-3-3ulfonlc  acid]  (J  acid  urea) 

Vlolanthrone  (Dlbenzanthrone ) 

Xylidlne  (original  mixture ) 

2,3-,  2,A-,    2,5-,  and  3,4-Xylldlnes,  total 


1,000 
potinds 
83,313 


68, 140 
15,173 

62 

296 

1,222 

287 

1,198 

1,075 

157 

62 

255 

406 

111 

197 

56 

132 

266 


45 

148,048 

932 

1,178 

288 

2,025 

1,963 

983 

4,448 

382,433 


25,596 
356,837 

420 

284 

2,306 

1,030 

170 

740 

1,058 

5,545 

380 

226,646 

1,264 

246 

27 

27 

1,408 

798,433 

129 

8,948 

344 
315 
1,217 
44 
3 
529 
368 
530 
682 
107 


Quantity    Value 


1,000 
pounds 
40,169 


33,552 
6,617 


109 
33 


6,505 
392 


629 

2,532 

199,543 


1,000 
dollars 
4,941 


4,216 
725 


Unit 
value-"- 


pound 
$0.12 


112    1.03 
70    2.12 


648 
159 


20,210 
179,333 


407 
2,451 


191,604 
1,208 


1,583 
470,066 


935 
1,127 
33,531 


3,143 
30,388 


297 
i,*684 


40,688 
750 


555 
77,509 


^  Unit  values  calculated  on  rounded  figures. 

'  Includes  data  for  coke  ovens  and  gas-retort  ovens,  reported  to  the  Coal  Economics  Division,  U.  S.  Bureau 
of  Mines,  and  for  tar  and  petroleum  refineries  and  other  producers,  reported  to  the  U.  S.  Tariff  Commission. 

^  Includes  some  mixed  cresols. 

*  Includes  keryl-type  benzenes. 

'  Includes  data  for  coke  ovens  and  gas-retort  ovens,  reported  to  the  Coal  Economics  Division,  U.  S.  Bureau 
of  Mines,  and  for  tar  refineries  and  other  producers,  reported  to  the  U.  S.  Tariff  Commission. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953  17 

Dyes 

Table  8A  shows  United  States  production  and  sales  of  dyes  in 
1953,    total  and  by  individual  dyes,    grouped  by  Colour  Index   number 
and  by   prototype  number.^     The  total  output  of  dyes  in  1953  was 
166  million  pounds,    or  14.2  percent  more  than  the  145  million 
pounds  produced  in  1952.    Sales  in  1953  amounted  to  152  million 
pounds,    valued  at  168  million  dollars,    compared  with  149  million 
pounds,    valued  at  171  million  dollars,  in  1952- -an  increase  of  2.1 
percent  in  quantity  and  a  decrease  of  1.9  percent  in  value.    The 
average  unit  value  of  all  sales  was  $1.10  per  pound  in    1953,    com- 
pared with  $1.  15  per  pound  in  1952. 

Dyes  for  which  separate  statistics  are  given  in  table  8A 
represent  80  percent  of  the  total  quantity  of  all  dyes  produced  in 
1953..  In  1953,    as  in  previous  years,    dyes  grouped  by  Colour  Index 
number  accounted  for  the  greater  part  of  the  output  of  all  dyes  (71 
percent).     The  production  of  Colour  Index  dyes  was  117  million 
pounds  in  1953,    compared  with  101  million  pounds  in  1952--an 
increase  of  15.9    percent.    Sales  of  Colour  Index  dyes  totaled  108 
million  pounds,    valued  at  90  million  dollars,    in  1953,    compared 
with  102   million  pounds,    valued  at  84  million  dollars,    in  1952- -an 
increase  of  6.2  percent  in  quantity  and  6.6  percent  in  value.    The 
production  of  prototype  dyes  in  1953  was  33  million  pounds,    or 
35.3  percent  more  than  the  24  million  pounds  produced  in  1952. 
Sales  of  these  dyes  increased  to  30  million  pounds,    valued  at  50 
million  dollars,    in  1953,     compared  with  25  million  pounds,    valued 
at  47  million  dollars,    in  1952.    Production  of  ungrouped  dyes  in 
1953  was  16  million  pounds,    compared  with    20  million  pounds  in 
1952;    sales    of  these  dyes  in  1953  totaled  14  million  pounds,    valued 
at  28  million  dollars,    compared  with  22  million  pounds,    valued  at 
40  million  dollars,    in  1952.    The  increase    in  production  and  sales 
of  prototype  dyes  and  the  decrease  in  the  ungrouped  category  are 
due  in  part  to  the  reclassification  in  1953  of  a  large  number  of 
ungrouped  dyes  as  prototype  dyes. 

Among  the  individual  dyes  for  which  statistics  are  given  in 
table  8A,    increases  in  production  in  1953  as  compared  with  that 
in  1952  were  reported  for  many  low-  and  medium-priced  dyes. 
Production  of  synthetic  indigo  in  1953  was  17.8  million  pounds, 
compared  with  17.2  million  in  1952.    Output  of  sulfur  black  was  9.3 
million  pounds  in  1953,    compared  with  8.9  million  in  1952,    and 
that  of  direct  blackEW  (C.I.  581)  was  6.2  million  pounds  in  1953, 
compared  with  5.3  million  in  1952.    The  output  in  1953,    as  com- 
pared with  that  in  1952,    increased  also  for  sulfur  brown  (by  52 
percent);  anthraquinone  vat  blue  GCD  (C.I.  1113)  (by  41  percent); 
methyl   violet  B  and  base  (C.I.  680)  (by  22  percent);    auramine 
(C.I.  655)    (by  21    percent);  and  algol  yellow  GC    (Pr.  9)  (by  16 
percent).    On  the  other  hand,    the  output  of  chrome  blue  black  R 
(C.I.  202)  was  43  percent  lower  in  1953  than  in  1952,     and  that  of 
indanthrene  khaki  2G  (Pr.   122)  was   19  percent  lower. 


^  See  also  table  8B,  part  III,  which  lists  these  products  and  identifies  the  manufacturers, 
and  part  A  (table  28)  of  the  appendix,  which  shows  imports  of  dyes  during  1951-53. 


18  UNITED  STATES  TARIFF  COMMISSION 

TABLE  81^. -Synthetic  organic  chemicals:   United  States  production   and  sales  of  coal-tar  dyes,    1953 

[Listed  below  are  all  coal-tar  dyes  for  which  any  reported  data  on  production  or  sales  may  be  published. 
(Leaders  are  used  where  the  reported  data  are  confidential  and  may  not  be  published  or  where  no  data  were 
reported.)  Table  8B  in  part  III  lists  all  dyes  for  which  data  on  production  or  sales  were  reported  and 
identifies  the  manufacturer  of  each] 


Colour 
Index 

or 
Proto- 
type 

No. 


Dye 


Production 


Quantity 


98 
lU 
117 
118 
138 
U5 
151 
161 
176 
179 
180 
185 
202 
203 
20-; 
216 
219 


234 

235 

246 

247 

252 

274 

275 

278 

280 

288 

289 

299 

307 

319 

324a 

326 

327 

331 

332 

343 


Grand  total- 


1.000 
pounds 

165,806 


151,675 


1,000 
dollars 
167,526 


Dyes  for  which  separate  statistics  may  not  be  shown- 
Dyes  for  which  separate  statistics  are  shown  below — 


DYES  CaiOUPED  BY  COLOUR  INDEX  NIJMBER 


32,962 
132,844 


117,206 


26,160 
125,515 


107,986 


Monoazo  Dyes 


Spirit  yellow  R- 

Oil  yellow 

Chrysoidine  Y 

Chrysoidine  R 

Sudan  I 


Orange  G 

Amide  naphthol  red  G — 

Chrome  yellow  2G 

Chrome  yellow  R 

Victoria  violet  4BS 

Amido  naphthol  red  SB- 
Fast  scarlet  G  base 

Fast  red  QL  salt 

Ponceau  R 

Fast  red  B 

Chrome  brovm  R 

Azo  eosine  G 

Fast  red  B  base 

Fast  scarlet  R  base—— 

Metanil  yellow 

Azoflavine  RS 

Orange  II 

Orange  R ■ 

Fast  red  A 

Azo  rubine— — — 

Fast  red  VR 

Cochineal  red  A 

Chrome  blue  black  R — 

Chrome  black  T 

Chrome  black  A 

Acid  chrome  red  B 

Chrome  flavine  A 


Disazo  Dyes 


Resorcin  brown 

Resoroln  daxk  brown- 
Acid  black  lOB 


Azo  dark  green  A 

Brilliant  orooeine  M- 
Milling  orange-— — 
Cloth  scarlet  G 
Direct  fast  red  SBL — 
Scarlet  EC 


Fast  acid  cyanine  G 

F^.st  acid  cyanine  5R  ex- 
Acid  chrome  black  F 


Fast  acid  cyanine  black  B- 
Direct  fast  heliotrope—— 
Rosanthrene 


Direct  fast  scarlet 

Direct  fast  scarlet  4BA — 

Bismarck  brown  G— 

Bismarck  brown  R— — — — 
Chrome  fast  yellow  C 


135 

150 

148 

138 

480 

439 

161 

153 

948 

793 

372 

322 

446 

372 

61 

74 

55 

64 

105 

110 

112 

76 

320 

306 

246 

241 

87 

70 

138 

115 

45 

46 

232 

217 

462 

360 

356 

330 

7 

933 

868 

371 

308 

219 

180 

134 

121 

34 

112 

100 

628 

715 

1,072 

1,017 

515 

449 

369 

338 

319 

308 

1,442 

1,227 

953 

32 

36 

379 

344 

539 

14 

11 

9 

9 

17 

315 

271 

545 

10 

16 

96 

109 

328 

264 

248 

162 

137 

134 

149 

136 

158 

41 

39 

111 

33 

23 

37 

835 

768 

1,286 

256 

268 

411 

145 

128 

73 

954 

849 

677 

, 

30 

33 

39,539 
127,987 


89, 546 


171 
140 
283 
103 
737 
267 
260 


116 
287 
180 


252 

449 

295 

17 

426 

177 

171 

125 

31 

79 

450 

945 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 

TABLE  8K. -Synthetic  organic  chemicals:   United  States  production  and  sales  of 
coal-tar  dyes,    J953- -Continued 


19 


Dye 


Quantity 


Unit 
value ^ 


DYES  CmOUPED  BY  COLOUR  INDEX  NUMBER— Continued 

Azo  Dyes — Continued 

Disazo  Dyes — Continued 


Direct  fast  yellow  5GL- 

Direot  fast  pink  2BL 

Brilliant  yellow 

Chrysophenine  G 

Congo  red- 


Congo  oorinth  0 

Direct  scarlet  B 

Direct  violet  B 

Direct  violet  N 

DevtlMped  black  BH- 

Direot  blue  2B 

Direct  orange  R 

Direct  fast  red  F — 

Direct  brown  M 

Polar  red 


Milling  red  G 

Benzopurpurine  4B — 
Benzo  new  blue  5B — 
Direct  blue  3B 


Acid  anthracene  red  3B- 

Benzqpurpurijie  lOB 

Fast  blue  B  salt 

Direct  azurine  G 

Direct  blue  RW 

Direct  sky  blue  FF 

Direct  pure  blue 


Irisazo  Dyes 


Direct  fast  black  FF- 

Plutoform  black 

Direct  brown  BT 

Direct  black  EW 

Direct  black  RX 

Direct  green  ET 

Chloramine  green  B 

Direct  green  B 

Direct  green  G 

Direct  brown  3G0 

Congo  brown  G 


Stilbene  Dye 


Direct  yellow  R 

Chloramine  orange  G- 
Stilbene  yellow 


Pyrazolone  Dye 


Fast  light  yellow  G- 
Xylene  light  yellow- 

Tartrazine 

Polar  yellow 

Chrome  red  B 

Pyrazol  orange 


Ketonimine  Dye 


Tr iphenylme thane 
Diphenylnaphthylnetha 


Dye 


Malachite  green 

Rhoduline  blue  6G 

Brilliant  green 

Acid  green  B 

Fast  acid  green  B 

Acid  glauoine  blue 

Para  fuohsine 


Methyl  violet  B  and  base- 
Crystal  violet 


000 

1.000 

1,000 

unds 

pounds 

dollars 

2A 

25 

54 

56 

58 

150 

328 

297 

382 

938 

635 

623 

178 

147 

176 

154 

188 

207 

150 

259 

11 

15 

26 

41 

2,387 

2,305 

1,515 

671 

701 

262 

115 

102 

68 

235 

172 

184 

390 

366 

329 

262 

219 

308 

18 

12 

21 

638 

612 

701 

31 

30 

61 

218 

144 

67 

66 

77 

118 

6 

9 

109 

103 

118 

102 

108 

114 

36 

50 

66 

361 

305 

469 

100 

64 

47 

208 

186 

152 

155 

194 

118 

179 

157 

330 

6,183 

6,180 

3,034 

247 

288 

168 

317 

225 

167 

55 

30 

702 

637 

415 

101 

77 

53 

795 

679 

441 

85 

66 

54 

910 

736 

625 

134 

114 

110 

658 

661 

717 

78 

70 

110 

133 

144 

231 

420 

364 

427 

61 

73 

150 

86 

90 

135 

1,442 


1,362 


1,876 


378 

369 

689 

19 

54 

116 

97 

235 

155 

156 

135 

30 

20 

73 

664 

462 

527 

10 

6 

19 

1,453 

1,112 

1,127 

825 

791 

1,525 

See  footnotes  at  end  of  table. 


20 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  SA---Synthetic  organic  chemicals:   United  States  production  and  sales   of 
coal-tar  dyes,   i953- -Continued 


Dye 


Quantity 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBER— Continued 


Triphenylme thane    and 
Diphenylnaphthylnethane   Dyes — Continued 


Ethyl  violet- 
Acid  violet — 
Soluble  blue- 


Acid  chrome  azurol  B 

Acid  chrome  cyanine  R 

Victoria  blue  B 

Naphthalene  green  V 

Wool  green  S 


Xanthene  Dye 


Fluorescein 

Uranine  (Fluorescein,  alkali  salt)- 
Tetrabromofluorescein 


Quinoline  Dye 


Quinoline  yellow- 


Thiazole    Dye 


Direct  fast  yellow- 


Azine  Dye 


Wool  fast  blue 

Safranine 

Induline,  spirit-soluble 

Induline,  water-soluble 


139 
11^ 
102 

1« 

133 


38 
607 


277 

417 


60 
296 


Methylene  blue- 


Sulfur    or  Sulfide   Dye 


Total^- 


20,838 


Sulfur  black — 

Sulfur  blue 

Sulfur  brown — 
Sulfur  green — 
Sulfur  maroon- 
Sulfur  olive — 
Sulfur  yellow- 
All  other 


Anthraquinone  Dye 


Alizarin  VI 

Alizarin  red  S- 


Aoid  alizarin  blue  SE 

Acid  alizarin  blue  B 

Alizarin  irisol  R 

Alizarin  oyanine  green 

Anthraquinone  blue  black  B 

Acid  anthraquinone  sky  blue  B- 


Anthraquinone   Vat  Dye 


Anthraquinone  vat  golden  orange  G,  12^- 

Anthraquinone  vat  scarlet  G,  16-2/3^ 

Anthraquinone  vat  dark  blue  BO,  25^ 

Vat  navy  blue  NTP- 


Anthraquinone  vat  jade  green,  &f>-  

Anthraquinone  vat  green  B  and  black  B,  12-l/2> 

Anthraquinone  vat  violet  2R,  12-l/2it 

Anthraquinone  vat  blue  GCD,  8-l/35t 

Anthraquinone  vat  yellow  G,  12-l/25t 

Anthraquinone  vat  olive  R,  12-l/25t 

Anthraquinone  vat  brown  R,  12-l/25t 

Anthraquinone  vat  brown  G,  12-l/25t 

Anthraquinone  vat  violet  BN,  255t 


9,303 

4,027 

4,282 

1,972 

399 

179 

472 

204 


34 
504 

12 
381 
142 

61 


674 

530 

441 

965 

6,506 

2,344 

376 

2,475 

93 

782 

852 

823 

162 


0 

1.000 

ds 

dollars 

17 

46 

116 

182 

88 

257 

118 

252 

22 

62 

139 

315 

63 

151 

106 

108 

247 
400 


70 
273 


20,594 


9,251 

4,036 

4,145 

1,932 

406 

177 

441 

206 


186 
20 
32 

473 
7 

389 

107 
38 


221 

405 

417 

855 

5,636 

2,225 

275 

2,074 

123 

770 

686 

789 

123 


242 

572 


175 
549 
23 


6,349 


1,979 
1,471 
1,146 
1,146 

306 
86 

163 


345 
47 
115 
1,266 
30 
929 
240 
196 


385 

950 

702 

1,073 

6,294 

1,412 

620 

3,251 

170 

879 

1,055 

1,076 

699 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 

TABLE  8A. --Synt/ietic  organic  chemicals:   United  States  production  and  saies   of 
coal-tar  dyes,    J953--Continued 


21 


Dye 


Quantity     Value 


Unit 
value ^ 


DYES  GROUPED  BY  COLOUR  INDEX  NU^EER— Continued 
Indigoid   and  Thioindigoid  Dyes 


Indigo,  synthetic,  20^ 

Bromindigo  blue  2BD,  l&f>- 

Vat  red  3B,  2O56- 

Vat  orange  R,  10^ 


Food,    Drag,    and  Cosxetic  Dye 


Food,  Drug,  and  Cosmetic  Colors 


Total- 
Blue  #  1~ 
Blue  #  2— 
Orange  #1- 
Red  #1- 
Red  #2- 
Red  #3- 
Red  #4- 


Yellow  #'!,— 
Yellow  #5— 
Yellow  #6— 
All  other 


Drug  and  Cosmetic  Colors 


Totals- 
Red  #11 — 
Red  #19 — 

Red  #21 

All  other — 


All  Other  Dyes  Grouped  by  Colour   Index  Nunber 

Total . 


DYES  GROUPED  BY  PROTOTYPE  NUMBER 


Acid  alizarin  flavine  R — 
Acid  anthracene  brown  PG- 
Algol  yellow  GC- 


Alizarin  supra  blue  A 

Anthracene  chromate  brown  EB- 
Benzo  Bordeaux  6B 


Benzo  chrome  black  blue  B- 

Benzo  fast  black  L 

Benzo  fast  blue  ^GL 

Benzo  rhodullne  red  3B 

Brilliant  benzo  violet  B— 
Celliton  orange  GR- 


Chlorantine  fast  brown  BRL — 
Chlorantine  fast  yellow  AGL- 

Diamine  Bordeaux  B 

Diamine  catechine  3G 

Diamine  fast  blue  FEB 

Diamine  fast  orange  EG 

Diamine  fast  orange  ER 

Diamlnogen  blue  N2B 

Diazo  Bordeaux  7B- 


Diazo  brilliant  green  3G 

Diazo  brilliant  scarlet  2BL  ex- 

Diazo  brilliant  scarlet  ROA 

Diazo  fast  red  5BL 

Diazo  fast  red  7BL 

Diazo  rubine  B 


Fast  scarlet  2G  salt — 
Guinea  carmine  B-— — 

Guinea  fast  red  BL 

Helindon  pink  R  ex 

Indanthrene  brown  BR — 
Indanthrene  brown  RRD- 
Indanthrene  khaki  2G — 


1,000 
pounds 

17,839 

i,o-;i 

190 
529 


1,559 


1,401 


169 
117 
414 
21 
39 
71 
274 
181 


30 

16 

101 


15,981 


32,612 


1.000 
>ounds 

19,289 
744 
169 
518 


1,447 


1,000 
dollars 

5,090 
518 
250 
663 


11,627 


29.516 


4,989 


26 

355 

5 

79 

216 

615 

108 

556 

339 

1,081 

20 

399 

32 

144 

55 

124 

252 

804 

159 

478 

92 

354 

103 

43 

349 


12,950 


99 

54 

66 

21 

28 

58 

2,269 

2,030 

3,033 

83 

64 

211 

125 

106 

140 

31 

24 

32 

85 

111 

155 

155 

235 

95 

90 

223 

7 

9 

78 

70 

104 

63 

41 

50 

373 

353 

311 

203 

188 

299 

109 

103 

126 

52 

54 

52 

172 

178 

368 

124 

94 

170 

65 

56 

99 

279 

251 

489 

101 

98 

193 

47 

38 

107 

124 

90 

290 

88 

99 

242 

18 

35 

54 

45 

95 

11 

8 

19 

193 

180 

151 

11 

12 

50 

42 

65 

1,019 

1,005 

1,487 

524 

403 

827 

759 

692 

1,109 

2,591 

2,626 

3,585 

See  footnotes  at  end  of  table. 


22 


UNITED  STATES  TARIFF  COMMISSION 

■  Synthetic  organic  chemicals:    United  States  production  and  sales  of 
coal-tar  dyes,   l953--Continued 


Colour 
Index 
or 
Proto- 
type 
No. 


138 

I'M- 

U7 

148 

152 

164 

168 

169 

170 

171 

172 

173 

187 

197 

198 

201 

202 

206 

223 

228 

230 

234 

235 

236 

237 

238 

239 

242 

244 

245 

246 

253 

258 

260 

260 

264 

267 

269 

270 

270 

271 

271 

273 

278 

291 

293 

299 

302 

303 

304 

305 

306 

309 

310 

311 

312 

313 

314 

316 

326 

341 

351 

353 

372 

377 

378 

379 

421 

428 

432 

491 

501 

533 

547 

556 


Dye 


DYES  GROUPED  BY  PROTOTYPE  NUMBER — Continued 


Milling  yellow  H5G 

Neolan  "blue  GG 

Oxydiamlnogen  OB 

Paper  red  A  ex 

Polar  orange  R— — — — 

Rapidogen  blue  D 

Rapidogen  red  GS ___^— — 

Rapidogen  red  RS 

Rapidogen  scarlet  RS 

Rapidogen  yellow  G 

Rosanthrene  fast  Bordeaux . 2BL- 

Rosanthrene  orange  R ■■ 

Sulphon  yellow  R 

Victoria  fast  violet  2R  ex 

Victoria  pure  blue  B -— 

Zambesi  black  D 

Zambesi  black  V 


Alizarin  fast  gray  BBLW- 
Brilliant  indooyanine  G- 
Celliton  fast  blue  FFR— 
Celliton  fast  brown  3R — 

Celliton  fast  pink  B 

Celliton  fast  pink  FF3B- 
Celliton  fast  red  GG- 


Celliton  fast  red  violet  RN- 

Celliton  fast  rubine  B- 

Celliton  fast  rubine  3B 

Celliton  fast  yellow  G 

Celliton  scarlet  B 

Celliton  yellow  5G 

Chlorantine  fast  red  5BRL 

Erlo  chrome  brown  DKL— — — 

Fast  blue  BB  base 

Fast  Bordeaiix  GP  base 

Fast  Bordeaux  GP  salt 

Fast  orange  GC  salt 

Fast  red  AL  salt 

Fast  red  3GL  salt 

Fast  red  KB  base 

Fast  red  KB  salt 

Fast  red  RC  base 

Fast  red  RC  salt 


Fast  red  TR  salt 

SlriuB  supra  turquoise  blue  GL- 
Indanthrene  golden  yellow  GK— 

Indanthrene  olive  green  B 

Monochrome  black  blue  G 

Naphthol  AS 

Naphthol  AS-BO 

Naphthol  AS-ffil 

Naphthol  AS-BS 

Naphthol  AS-D 

Naphthol  AS-G 

Naphthol  AS-ITR 

Naphthol  AS-OL 

Naphthol  AS-RL 


Naphthol  AS-SW 

Naphthol  AS-TR 

Neolan  yellow  GR 
Palatine  fast  pink  BN- 

Rapidogen  tlue  N 

Rapidogen  violet  B 

Rapidogen  yellow  2G — 
Cotonerol-  ■■ 


Diazo  brilliant  scarlet  5BLN- 

Fast  red  ITR  base 

Sirlus  supra  gray  VGL 

Chlorantine  fast  Bordeaux  2B- 

Chlorantine  fast  red  6BLL 

Chlorazol  blue  5GKS 


Chlorantine  fast  violet  2RL- 

Fast  red  PDC  salt 

Direct  chlnollne 

Indanthrene  olive  T 

Naphthol  AS-MX 


Quantity 


4 
197 
474 
134 

142 
206 

80 
123 

85 


13 
93 
167 


700 
40 

122 
16 

117 
39 
36 

150 

264 

165 
25 

238 


142 

886 

121 

21 

19 

10 

30 

214 

833 

2,038 

19 

945 

31 

40 

255 

237 

26 

23 

111 


113 
86 
55 
57 
97 
1,354 
45 


1,000 
pounds 


1,000 
dollars 


208 
436 
108 
23 
140 
207 


40 
122 

20 

76 
129 

17 
256 

78 

7 

1,040 

45 
117 


26 

129 

240 

152 

18 

228 

5 

14 

19 

148 

18 

134 

824 

100 

22 

11 

14 

22 

188 

513 

1,665 

27 

577 

24 

32 

62 

69 

10 

20 


492 
4 

20 
38 
17 

'"'  36 

3 

11 
12 
5 
99 
72 
57 

95 

1,368 

30 


28 

338 

604 

241 

40 

372 

483 

197 

i99 

189 

90 

257 

30 

87 

423 

26 

294 

332 

37 

1,474 

79 

246 

45 

92 

59 

27 

124 

372 

189 

52 

419 

8 

79 

47 

184 

21 

200 

674 

281 

49 

23 

34 

45 

416 

1,198 

2,636 

103 

761 

95 

106 

148 

142 

48 

87 

43 

22 

1,179 

17 

""  45 

103 
93 


10 
42 
23 
16 
324 
131 
135 

344 

1,868 

62 


3.62 

1.37 
2.07 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


23 


TtBLE  8A. --Synthetic  organic  chemicals:  United  States  production  and  sales  of 
coal-tar  dyes,   1953- -Continued 


Dye 


Quantity 


Unit 
value ^ 


DYES  CKOUPED  BY  PROTOntPE  KUMBER—Continued 


Naphthol  AS-PH 

Neutral  brawn  RX— — — — 
Pontamine  navy  blue  DB- 
Solantlne  orange  4G- 


Slrius  supra  yellow  R  ex 

All  other  dyes  grouped  by  prototype  number- 


DNCSROUPED  DYES 


Acetate  rayon  dyes,  total  (see  tables  10  and  11  for 
total  of  all  acetate  rayon  dyes)* 

Black,  IV  ex.,  B,  BNF,  DB,  EC,  G,  3G,  GGN,  GS,  GY, 
J,  LNB,  NC,  RB,  RK,  SDP,  SS* 

Blue,  #15,  #40,  AB-7,  A8-45,  AGF,  B,  2B,  BGLF,  BN, 
BUN,  BP,  CR,  EC,  G,  2G,  GBN,  GE,  GFD,  GLF,  GLT, 
GLT-KS,  2GN,  GP,  CR,   IB,   ID,  M,  MJ,  NBN,  NVC, 
NVY,  RB,  RDA,  RG,  R,  2R,  3R,  WNBN* 


Red  III,  VI-X,  B,  2B,  4BLL,  2B-GLF,  C,  FSI,  G,  GLF, 

LRB,  NB,  R,  HP,  WLF--M),  Y,  YP'' 

Violet  5B,  7BC,  BGF,  BN,  MB,  2R,  AR,   3RGFL,  5RLF 

Yellow  <»LF 


Yellow  B,  CW.  ESI,  G,  5G,  8GLF,  GL,  GN,  GR,  IX,  M, 
N,  RN,  4HL* 


3RL,  RNL- 


All  other  acetate  rayon  dyes- 
Acid  orange  NR,  R,  2R- 
Acid  violet  NR,  R,  2R, 

Anthraquinone  vat  gray  BR,  2G,  GFL,  GNF,  MBM,  R 

Anthraqulnone  vat  olive  G,  20L,  2GLD,  T,  TO,  TR 

Aaoic  dyes  and  their  components,  total  (see  tables 

10,  11,  and  K  for  data  on  all  azoic  dyes  and  their 

components) '- 


Chrome  yellow  2GN,  LL,  SW 

Direct  black  CW,  3G,  5G,  GN,  3GR,  HH,  RCW,  RW 

Direct  blue  B,  BBL,  BFL,  BLU,  10  BLU,  BVW,  CF,  CF2B, 
FBLT,,  2GFL,  GL,  3GLL,  4GLL,  8GLN,  4GU,  8GUF,  LBLL, 
LDU,  LGLL,  NPC,  NR,  RDW,  2RCF,  3RCF,  RFL,  2RFL,  RL, 

RLU,  2RLU,  2RLCF,  TRLL,  VHS 

Direct  brown  CR,  CWR,  CB,  3GS,  KRS,  RB,  3RLL,  RY 

Direct  fast  blue  BLL,  2BRN,  CPL,  GLFV,  VGIi,  8GLL, 

GSS,  L5GA,  L5R,  RL,  3RL,  SFGL,  SFRL 

Direct  faet  brovm  4GL,  5GLL,  R,  AR,  2RL,  3RL,  AKL, 

SRL,  SKRL,  3YL 

Direct  fast  orange  G,  2G,  5GC,  GL,  2GL,  4GLL, 

L8GL,  R 


Direct  fast  red  3BL,  gBLN,  7BNL,  L4BL,  RL,  WL 

Direct  fast  yellow  5G,  3GL,  3GU,  L2RX,  L3RX,  RL,  S5GP- 
Dixect  orange  C,  DB,  F3R,  GFL,  5GFL,  2GLL,  2GU, 

6G0F,  LR,  3LWF,  2R,  RT 

Direct  white,  ACC,  AW,  B,  4B,  5B,  5BM,  2G,  MR,  M2R, 

2R,  3R,  RN,  RW,  SC,  WT 

Oil  orange,  #  30,  MT 

Oil  red,  #322,  DB,  EGN,  N-1700,  0,  OB,  RO 

All  other  ungrouped  dyes — 


1,000 
pounds 


121 

130 

180 

9,793 


15,9 


3,080 
739 


1,4^ 

313 
106 
185 

179 
118 


1,250 

738 
132 


690 
60 


40 
120 
68 

151 

1,739 

47 

610 

7,188 


1,000 
pounds 

11 
13 

103 
92 

144 
8,598 


14,173 


1,000 
dollars 

31 

30 

97 

254 

357 

15,076 


28,394 


2,569 
769 


284 
93 
211 

141 
123 


594 
1,130 


586 

10 
140 


638 
57 


38 

109 


127 

1,521 

564 
5,935 


4,356 
671 


2,240 

44^ 
231 
321 

259 
190 


1,008 
1,909 


1,408 

8 

103 


1,121 
81 

130 

114 

94 
229 
122 

321 

5,174 

703 
11,513 


Per 
pound 

!p2.82 
2.31 
.94 
2.76 
2.48 
1.75 


1.70 
.87 


1.56 
2.48 
1.52 

1.84 
1.54 


1.70 
1.69 


2.40 
.80 
.74 


1.76 
1.42 

3.33 

2.4fi 

2.47 
2.10 
1.74 

2.53 

3.40 

1.25 
1.96 


^  Unit  values  calculated  on  rounded  figures. 

*  Does  not  include  derivatives  of  oarbazole  (Colour  Index  No.  969). 

'  Includes  di-ug  and  cosmetic  colors,  external,  data  on  which  cannot  be  published  separately  without  dis- 
closing Information  received  in  confidence. 

*  Excludes  acetate  rayon  dyes  that  appear  under  "Dyes  grouped  by  prototype  number." 
'  Includes  developed  black  and  diazo  black. 

'  Includes  brilliant  blue  and  navy  blue. 
'  Includes  monocel  red,  rubine,  and  scarlet. 
'  Includes  fast  yellc .,  golden  yellow,  and  printing  yellow. 

'  Does  not  Include  azoic  dyes  and  their  components  that  appear  under  "Dyes  grouped  by  Colour  Index  number," 
and  "Dyes  grouped  by  prototype  number . " 


24 


UNITED  STATES  TARIFF  COMMISSION 


Table  9  shows  production  and  sales  of  dyes  in  1953,    by  chemical 
class.    Four  chemical  classes  of  dyes  accounted  for  84.2  percent 
of  the  total  quantity  of  all  dyes  produced  in  1953:  Azo  dyes,    for 
34.5  percent;  anthraquinone  vat  dyes,    for  23.1  percent;    sulfur  dyes, 
for  13.6  percent;  and  indigoid  and  thioindigoid  dyes,    for   13.0 
percent.    The  output  of  each  of  the  four  classes  was  greater  in 
1953  than  in  1952.    The  production  of  sulfur  dyes  increased  19.2 
percent;  of  azo  dyes,  15.9  percent;  of  anthraquinone  vat  dyes,    6.8 
percent;  and  of  indigoid  and  thioindigoid  dyes,    7.0    percent. 


TABLE  9 . - -Syn the t ic 


rganic  chemicals:    United  States  product  ion  and  sales   of  coal-tar  dyes,   by 
chemical  class,    1953 


Chemical  class 


Quantity 


Unit  value^ 


1,000 

pounds 

165.,  £ 


1,000 
pounds 

151,675 


1,000 
dollars 

167,526 


$1.10 


Anthraquinone  vat^ 

Indigoid  and  thioindigoid- 
Sulfur  or  sulfide 


Triphenylme thane  and  diphenylnaphthylmethane- 

Stilbene ___ 

Pyrazolone 

Xanthene 

Thiazole 

Thiazine — — 

Acridine _— 


Phthalocyanine- 
All  other* 


57,158 

38,370 

21,623 

22,<;89 

6,089 

4,619 

-3,540 

1,442 

1,227 

1,243 

793 

390 

243 

254 
6,326 


51,821 

32,524 

22,729 

21,910 

4,408 

4,262 

3,118 

1,362 

1,153 

899 

739 

366 

220 

119 

221 

5,824 


65,262 

45,418 

9,138 

7,073 

7,949 

9,979 

6,798 

1,876 

2,321 

2,623 

1,047 

527 

679 

208 

582 

6,046 


1.26 
1.40 
.40 
.32 
1.80 
2.34 
2.18 
1.38 
2.01 
2.92 
1.42 
1.44 
3.09 
1.75 
2.63 
1.04 


Unit  value  calculated  on  rounded  figures. 
Includes  carbazole  vat  dyes. 
^  Included  in  "All  other." 

*  Includes  naphthalimide,  nitro,  nitroso,  aniline  black  and  allied  dyes,  and  oleate  dyes;  also  includes 
rubber  colors  and  miscellaneous  mixtures.  Statistics  for  these  groups  cannot  be  published  separately  vd.thout 
disclosing  information  received  in  confidence. 


Table   10  shows  the  average  annual  production  of  dyes  in  the  5- 
year  period  1947-51,    together  with  annual  data  for  1952  and  1953, 
by  class  of  application.    Table   11   gives  corresponding  data  for 
sales.    Two    classes  of  dyes  accounted  for  55.8  percent  of  the  total 
output  of  all  dyes  in  1953.    They  are  vat  dyes,    which  accounted  for 
36.8  percent,    and  direct  dyes,    which  accounted  for   19.0    percent. 
Three    classes  of  dyes  showed  increases  in  production  in  1953  over 
the   1947-51   average  as  follows:  Vat  dyes  other  than  indigo,    11.5 
percent;  azoic    dyes,     7.  8   percent;    and  lake  and  spirit-soluble  dyes, 
7.6  percent.    On  the  other  hand,    the  output  of  mordant  and  chrome 
dyes  declined  43.3  percent;  that  of  acid  dyes,    26.5  percent;  and 
that  of  direct  dyes,    22.6  percent. 

Production  and  sales  of  ungrouped  dyes  (those  having  neither 
a  Colour    Index  nor  a  prototype  number)    are  shown  by  chemical 
class  in  table   12  and  by  class  of  application  in  table   13.    Two 
chemical  classes  of  ungrouped  dyes  accounted  for  70.9  percent 
of  the  total  output  of  these  dyes  in  1953:    azo  dyes    accounted  for 
40.2  percent,    and  anthraquinone  vat  dyes  accounted  for  30.7  percent. 
Of  the  total  output  of  ungrouped  dyes,    arranged  by  class  of  appli- 
cation,    vat  dyes  accounted  for  32.0  percent  in  1953;  direct  dyes, 
for  29.8  percent;  and  acetate  rayon  dyes,    for   19.3  percent. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


25 


TABLE  10   -Synthetic  organic  chemicals:    United  States  production  of  coal-tar  dyes,   by  class  of  application, 
average  1947-51,    mnual   1952  and  1953 


Class  of  application 


Acetate  rayon- 

Ao  id ■  "  - 

Azoic— 

Basic 


Lake  and  spirit-soluble 

Mordant  and  chrome 

Sulfur 


Vat,  total- 
Indigo 


All  other  coal-tar  dyes- 


Acetnte  rayon- 

Ao  id——— 

Azoic 

Basic-———— 


Lake  and  spirit-soluble- 

Mordant  and  chrome 

Sulfur 


Vat,  total- 
Indigo 


All  other  coal-tar  dyes- 


Quantity  (-1,000  pounds) 


187, 173 


7,^35 

21,103 

8,083 

8,654 

40,717 

5,825 

6,776 

24,999 

60,280 


21,614 
38, 666 


3,301 


145,209 


5,449 
12,037 
7,177 
6,245 
26,805 
4,490 
4,564 
18,847 

57,189 


17, 165 
40,024 


2,406 


165,806 


6,263 
15,510 
8,713 
7,981 
31,495 
6,270 
3,844 
22,489 

60,957 


17,839 
43,118 

2,284 


Percent  of  total  quantity 


3.9 
11.3 
4.3 


3.6 
13.4 


100.0 


3.8 
8.3 
4.9 
4.3 

18.5 
3.1 
3.1 

13.0 


11.8 
27.6 


100.0 


3.8 
9.4 
5.2 
4.8 

19.0 
3.8 
2.3 

13.6 

36.8 


10.8 
26.0 


NOTE. — Ihe  leuoo  vat  esters  are  included  with  vat  dyes  in  1949-53,  and  with  direct  dyes  in  1947  and  1948. 


-Synthetic  organic  chemicals:    United  States  sales  of  coal-tar  dyes,    by  class  of  applicatic 
average  1947-51,    annual  1952  and  1953 


Class  of  application 


Average 
1947-51 


Acetate  rayon- 
Acid ' 

Azoic 

Basic 


Lake  and  spirit-soluble- 
Mordant  and  chrome——— 
Sulfur 


Vat,  total- 
Indlgo — 


All  other  coal-tar  dyes- 


Acetate  rayon- 
Acid 

Azoic 

Basic 


Lake  and  spirit-soluble- 
Mordant  and  chrome 
Sulfur 


Vat,  total- 
Indlgo 


All  other  coal-tar  dyes- 


Quantity  (1,000  pounds) 


175,322 


6,628 

19,246 

7,018 

7,790 

38,933 

5,353 

6,599 

25,057 

55,608 


21,173 
34,435 


3,090 


14S,603 


6,244 
12,479 
6,859 
6,389 
29,636 
4,689 
4,870 
19,475 

55,593 


16,565 
39,028 


2,369 


151,675 


5,927 

13,231 

6,741 

6,928 

29,174 

5,935 

3,845 

21,910 

55,853 


19,289 
36,564 


2,131 


Percent  of  total  quantity 


100.0 


3.8 
11.0 
4.0 
4.4 
22.2 
3.1 
3.8 
14.3 

31.7 


12.1 
19.6 


100.0 


4.2 
8.4 
4.6 
4.3 

19.9 
3.2 
3.3 

13.1 

37.4 


11.1 
26.3 


100.0 


3.9 
8.7 
4.4 
4.6 

19.3 
3.9 
2.6 

U.4 


36.8 
12.7 
24.1 


See  note  at  end  of  table. 
313486   O  -  54  -  3 


26 


UNITED  STATES  TARIFF  COMMISSION 


TA3LE  11. --Synthetic  organic  chemicals:   United  States   saies  of  coal'tar  dyes,    by  class   of  application, 
average  1947-51,    annual  1952  and  1953- -Continued 


Class  of  application 


Average 
19<;7-51 


Acetate  rayor- 
Acid 


Lake  and  spirit-soluble- 

Mordant  and  ehrcme 

Sulfur 


Vat,  total- 
Indigo 


All  other  coal-tar  dyes- 


Acetate  rayon- 

Acid 

Azoic-———— 
Basic 


Lake  and  spirit-soluble- 

Mordant  and  chrome- 

Sulfur 


Vat,  total- 
Indigo 


All  other  coal-tar  dyes- 


Value  (1,000  dollars) 


164,393 


9,118 

20,493 

13,968 

10,644 

36,128 

4,586 

5,922 

7,743 

48,554 


4,645 
43,909 

7,237 


170,699 


9,610 

16,106 

13,372 

9,376 

38,912 

5,216 

5,489 

6,337 

60,454 


4,383 
56,071 


5,827 


167,526 


9,577 
17,076 
12,254 
10,645 
37,462 
6,435 
4,829 
7,073 

55.705 


5,090 
50,615 


6,470 


Percent  of  total  value 


12.5 
8.5 
6.5 

22.0 
2.8 
3.6 
4.7 


2.8 
26.7 


100.0 


5.6 
9.4 
7.8 
5.5 
22.8 
3.1 
3.2 
3.7 

35.4 


2.6 
32.8 


100.0 


5.7 
10.2 
7.3 
6.4 
22.4 
3.8 
2.9 
4.2 


33.2 
"~3T0" 
30.2 


NOTE. — The  leuoo  vat  esters  are  included  with  vat  dyes  in  1949-53,  and  with  direct  dyes  in  1947  and  1948. 

The  statistics  on  sales  of  dyes  in  1948-53  do  not  include  the  quantity  and  value  of  interplant  transfers, 
as  the  statistics  for  1947  and  earlier  years  did.  The  sales  statistics,  therefore,  are  not  strictly  conpa- 
rahle  with  the  sales  statistics  for  earlier  years.  Before  1948,  interplant  transfers  probably  did  not  ac- 
count for  more  than  10  percent  of  the  total  of  sales  plus  transfers. 


--Synthetic  organic  chemicals:   United  States  production  and  sales  of 
by  chemical  class,    1953 


ngrouped  dyes. 


Chemical  class 


Quantity 


Unit  valua^ 


Total 

Azo 

Anthraquinone  vat 

Stilbene 

Indigoid  and  thioindigoid 

Triphenylmethane  and  diphenylnaphthylmethane 
All  other^ 


1,000 
pounds 

15, 9£ 


1,000 
Dounds 

14,173 


1,000 
dollar, 
28,394 


6,430 
4,916 
1,801 
1,572 
206 
(^) 
1,063 


5,937 
4,340 
1,579 
1,063 
207 
6 
1,041 


10,299 
7,630 
5,288 
2,749 
381 
18 
2,029 


Per 
pound 

»2.00 


1.73 
1.76 
3.35 
2.59 
1.84 
3.00 
1.95 


^  Unit  value  calculated  on  rounded  figures. 

*  Included  in  "All  other." 

'  Includes  pyrazolone,  xanthene,  sulfur,  aoridine,  quinoline,  azine,  oxazlne,  and  miscellaneous  dyes. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


27 


TABLF  13.--Syntheti 


organic  chemicais:   United  States  production  and  sales  of 
by  class  of  application,   1953 


ngrouped  dyes. 


Class  of  application 


Production 


Quantity 


Unit  value ^ 


Total- 


is,9 


l-i.lVS 


1,000 
dollars 
28,394 


Acetate  rayon- 

Aoid 

Azoic 

Direct 


Lake  and  spirit-soluble- 

Vat 

All  other^ 


3,080 

377 

738 

4,771 

1,178 

5,122 

722 


2,569 
393 
586 
4,313 
1,077 
4,547 


4,356 
929 

1,408 
10,362 

2,458 

8,011 
870 


pound 

$2.00 


1.70 
2.36 
2.40 
2.40 
2.28 
1.76 
1.26 


^  Unit  value  calculated  on  rounded  figures. 

^  Includes  basic,  sulfur,  mordant  and  chrome,  and  miscellaneous  dyes. 


Table  14  shows  production  and  sales  of  azoic  dyes  and  their 
components  in  1953.    The  output  of  these  products  totaled  8,7 
million  pounds  in  1953,    or  21.4  percent  more  than  the  7.2  million 
pounds  produced  in  1952.   Sales  of  these  products  in  1953  totaled 
6.7  million  pounds,    valued   at  12.3  million  dollars,  compared  with 
6.9  million  pounds,    valued  at  13.4  million  dollars,    in  1952- -a 
decrease  of  2.7   percent  in  quantity  and  8.4  percent  in  value  of 
sales.    The  output  of  rapidogens  was  1.4  million  pounds  in  1953-- 
slightly  more  than  the  1.3  million  pounds  produced  in  1952;  sales 
of  rapidogens  totaled  1.3  million  pounds,    valued  at  3.5  million 
dollars,    in  1953,    compared  with  1.4  million  pounds,    valued  at 
4.6  million  dollars,    in  1952.    Among  the  azoic  components,    pro- 
duction of  fast  color  bases  was  about  the  same    in  1953  as  in 
1952;  that  of  fast  color  salts  increased  18.5  percent  in  1953, 
compared  with  1952;  and  that  of  Naphthol  AS  and  derivatives 
increased  65.6  percent. 


28  UNITED  STATES  TARIFF  COMMISSION 

TABLE  U. -Synthetic  organic  chemicals:    United  States  production  and  sales   of  azoic  dye 
and  their   components,    1953 


Proto- 
type No, 


168 
169 


351 
171 
353 


258 
260 
117 
378 
270 
271 


499 
260 
26A 
267 
7  69 
269 
270 
501 
271 
273 
94 


302 
303 
304 
305 
306 
309 
310 

556 
311 
557 
312 
313 
314 


Dye  or  component 


Grand  total^- 


Dyes  and  components  for  which  separate  statistics  may 
not  be  shown^ 


Dyes  and  components  for  which  separate  statistics  are 
shown  below 


Pro- 
duction 


Rapidogen,  total- 
Black 

Blue  D 

Blue  N 

Bordeaux 

Brown 

Orange 

Red  GB 

Red  RS- 


Red,  other* 

Scarlet  RS 

Scarlet,  other- 
Violet  B 

Yellow  G 

Yellow  2G- 


Yellow,  other* 

All  other 


Fast  color  bases,  total- 
Blue  BB 

Bordeaux  GP 

Red  B 

Red  ITR 

Red  KB 

Red  RC 

Scarlet  G 

Scarlet  R — 

All  other 


Fast  color  salts,  total - 

Blue  B 

Bordeaux  GP 

Orange  GC 

Red  AL 

Red  GL 

Red  3GL 

Red  KB 

Red  PDC 

Red  RC 

Red  TR 

Scarlet  2G 

All  other 


Naphthols,  total 

Naphthol  AS 

Naphthol  AS-BO 

Naphthol  AS-BR 

Naphthol  AS-BS 

Naphthol  AS-D 

Naphthol  AS-G 

Naphthol  AS-ITR 

Naphthol  AS-KB 

Naphthol  AS-MX 

Naphthol  AS-OL 

Naphthol  AS-PH 

Naphthol  AS-RL 

Naphthol  AS-SW 

Naphthol  AS-TR 

All  other 


8,713 


51 
8,662 


112 
142 


118 
123 
28 
21 
85 
25 


1.893 


(') 

232 

121 
19 
112 
462 
947 

2,151 


109 
160 
7 
142 
320 


10 
30 
193 
822 


2,639 


945 
31 
40 

255 

237 
26 
23 
29 
45 

111 
(') 
11 

562 
(') 

22i. 


Quantity   Value 


1,000 
pounds 

6,741 


6,691 


114 
140 


73 
112 


1,000 
dollars 
12,254 


107 
12,147 


3,492 


(') 

170 


1.337 


19 
217 

11 
100 

11 

76 
360 
529 

2,601 


103 
148 

18 
134 
306 
824 

22 

14 

22 

180 

830 

1,500 


355 
372 
103 
122 
395 
176 
483 
197 
219 
199 
58 
93 
189 

(') 

(') 
531 


252 
42 
281 
23 
116 
449 
913 


577 
24 
32 
62 


(') 


_14t 


2.980 

"nF 

184 

21 

200 

287 

674 

49 

C) 

34 

45 

151 

1,217 

3,473 


761 
95 
106 
148 
142 


(') 


1,179 


Unit  values  calculated  on  rounded  figures. 

Totals  shown  represent  all  azoic  dyes  and  their  components.  Totals  shown  in  tables  8A 
represent  ungrouped  dyes  and  their  components  only. 
^  Includes  rapid  fast  and  fur  dyes. 

Includes  oorinth  and  garnet. 
'   Included  in  "All  other." 
*  Includes  golden  yellcw. 

Colour  Index  number. 


Unit 
value  ■"■ 


pound 

$1.82 


2.14 

1.82 


2.79 


3.11 
2.66 
2.71 
3.05 
4.65 
2.41 
2.33 
2.74 
3.00 
1.78 
2.42 
5.47 
2.15 


5.64 
2.47 
1.16 
3.82 
2.81 
2.09 
1.53 
1.25 
1.73 

1.15 


(') 


1.15 
1.24 
1.17 
1.49 
.94 
.82 
2.23 
) 

2.43 

2.05 

.84 

1.47 

2.32 


(') 


1.32 
3.96 
3.31 
2.39 
2.06 
4.80 
4.35 
) 

2.07 
2.69 
2.82 
3.14 
2.40 
4.25 
5.01 


SYNTHETIC  ORGANIC  CHEMICALS,  I953 
Toners  and  Lakes 


29 


As  the  terms  are  used  in  this  report,    toners  and  lakes    are 
synthetic  organic  pigments.    Statistics  on  production  and  sales  of 
all  toners  and   lakes  are  given  in  table   15A.      Statistics  on  the 
commercial  forms  of  a  few  selected  pigments  (dry,    flushed,    or 
pulp)  are  given  in  table   16. 

Synthetic  organic  pigments  are  used  in  paints  and  related 
products,    printing  inks,    and  plastics  and  resin  materials.    Toners 
are  full-strength  pigments;  lakes  and  reduced  toners  are  extended 
or  diluted  colors.    Whenever  possible,    individual  lakes  and  toners 
are  identified  by  the  Colour  Index  number  or  prototype  number  of 
the  dyes  from  which  they  may  be  made. 

The  total  output  of  organic  pigments  in  1953  was  44.1  million 
pounds,    an  increase  of  13.6  percent  over  the  38.8  million  pounds 
reported  for  1952.    Sales  in  1953  were  36.7  million  pounds,  valued 
at  56.  0  million  dollars,    compared  with  35.  7  million  pounds,    valued 
at  48.  7  million  dollars,    in  1952. 

TABLE  ISA. -Synthetic  organic  chemicals:    United  States  production   and  sales  of  toners   and  lakes,    1953 

[Listed  below  are  all  toners  and  lakes  for  which  any  reported  data  on  production  or  sales  may  be  published. 
Table  15B  in  part  III  lists  all  toners  and  laies  for  which  data  on  production  or  sales  were  reported  and 
identifies  the  manufacturer  of  each] 


Quantity 


Unit 
value-"- 


Grand  total 


44,056 


1,000 
pounds 

36,661 


1,000 
dollars 
56,031 


TO^ERS  OR  FULL-STRENGTH  COLORS 


Products  for  which  separate  statistics  may  not  be  shown^- 
Products  for  which  separate  statistics  are  shown  below — 


27,232 


22,060 


41,114 


38 
27,194 


41 
22,019 


175 
40,939 


Black  toners- 


Blue  toners,  total 

Alkali  blue  (C.I.  704) 

Peacock  blue  R  (C.I.  664),  PMA  and  PTA 

Phthalooyanine  blue  B  (Pr.  481) 

Setoglauoine  (Peacock  blue  G)  (C.I.  658),  PMA- 
Setoglaucine  (Peacock  blue  G)  (C.I.  658),  PTA- 

Victoria  blue  B  (C.I.  729),  PMA 

Victoria  blue  B  (C.I.  729),  PTA 

Victoria  pure  blue  B  (Pr.  198),  PMA 

Victoria  pure  blue  B  (Pr.  198),  PTA 

All  other 


9,766 


Green  toners,  total 

Brilliant  green  (C.I.  662),  PMA 

Brilliant  green  (C.I.  662),  PTA 

Malachite  green  (C.I.  657),  PMA 

Malachite  green  (C.I.  657),  PTA 

Pigment  green  B  (Pr.  149) 

All  other 


1,297 

9 

2,447 


2,249 


1,132 

7 

1,732 


20 
75 
52 
38 
236 

1,827 


15 

906 

1,262 


Maroon  toners,  total- 


^ -Hydroxynaphthoic  maroon  (B.O.N,  maroon)  (Lithol  maroon)- 

Toluidine  maroon — 

All  other 


TT" 

38 

8 

15 

647 

1,108 

616 
133" 


2,269 

43 

5,898 

35 

131 

48 

280 

212 

181 

669 


5,901 


200 
34 
66 

822 
4,735 


337 

320 

1,422 


Orange  toners,  total- 
Benzidine  orange- 


_^9_ 


2,4-Dinitroaniline  orange- 

o-Nitroaniline  orange 

Ail  other 


172 
56 


49 

154 

53 

60 


152 

211 

62 

140 


Ptr 
pound 

$1.53 


4.27 
1.86 


1.82 


2.94 
2.00 
6.14 
3.41 
4.38 
6.55 
2.40 
3.69 
4.08 
4.76 
2.83 


3.23 

5.26 
4.25 
4.40 
1.27 
4.27 


3.37 

3.48 
4.17 


1.79 
3.10 
1.37 
1.17 
2.33 


See  footnotes  at  end  of  table. 


See  also  table  15B,  part  III,  which  lists  these  products  alphabetically  and  identifies 
the  manufacturers. 


30  UNITED  STATES  TARIFF  COMMISSION 

TABLE  ISA. --Synthetic  organic  chemicals:   United  States  production   . 
toners  and  lakes,    i953- -Continued 


Quantity 


TONERS  OR  FULL-STRENGTH  COLORS — Continued 


Red  toners,  total- 


o-Chloronitroaniline  red  (Chlorinated  para  red)- 
Eoslne  (Bromo  acid  toner)  (C.I.  758) — 
Lithol  red  R  (C.I.  189),  total 


Barium  toner 

Calcium  toner 

Sodium  toner — 


Lithol  rubine  B  (C.I.  163)- 

Naphthol  AS  (Pr.  302) 

Naphthol  AS-BS  (Pr.  305) 

Naphthol  AS-D  (Pr,  306) 

C.I.  44,  Para  red,  light 

Para  red,  dark- 


Permanent  red  2B ■ 

Pigment  rubine  3G 

Red  lake  C  (C.I.  165) 

Rhodamine  B  (C.I.  749),  PMA 

Rhodamine  B  (C.I.  749),  PTA 

Rhodamine  6G  (C.I.  752),  PMA 


Rhodamine  60  (C.I.  752),  PTA- 

C.I.  69,  Toluidine  red 

Vulcan  fast  red  B  (Pr.  476) — 

All  other 

Violet  toners: 


Methyl  violet  B  (C.I.  680),  PMA 

Methyl  violet  B  (C.I.  680),  PTA 

Methyl  violet  B  (C.I.  680),  fugitive- 


Yellow  toners,  total 

Benzidine  yellow 

Pr.  103.  Hansa  yellow  G 

Pr.  105,  Hansa  yellow  lOG 

All  other 


LAKES  OR  LAKED  COLORS 


Products  for  which  separate  statistics  may  not  be  shown-'- 
Products  for  which  separate  statistics  are  shown  below 

Black  lakes-—-—— . — -    __-__ 

Blue  lakes,  total- 


Methylene  blue  (C.I.  922) 

Peacock  blue,  fugitive  (Patent  blue)  (C.I.  671) 

Victoria  blue  B  (C.I.  729) 

Victoria  pure  blue  B  (Pr.  198) 


Brown  lakes,  total 

Bismarck  brown  R  (C.I.  332)- 
All  other 


Green  lakes,  total 

Acid  green  B  (C.I.  669) 

Malachite  green  (C.I.  657) 

All  other 

Maroon  lakes: 

Azo  Bordeaux  (C.I.  88) 

Helio  fast  rubine  4BL  (Pr.  A06) 

Orange  lakes:  Persian  orange  (Acid  orange  Y)  (Orange  II) 
(CI.  151) 


Red  lakes,  total—— — — — 

Alizarin  red  B  (C,I,  1027) 

Eosine  (Bromo  acid  lake)  (C.I,  768) 

Permanent  red  2B 


Pigment  scarlet  3B  (CI. 
Rhodamine  B  (CI.  749)- 


216)- 


Rhodamir.e  60   (Rhodamine  Y)  (CI,  752)- 
Soarlet  2R  (CI.  79) 

All  other — —————— — 


1,000 
ounds 
15,548 


667 

761 

5,193 

2,749 

1,757 

687 

692 

201 

79 

66 

1,295 

515 

1,392 

6 

1,092 

17 

28 

32 

72 

2,577 

185 

678 

282 


3,191 


1,896 
878 
149 
268 


6,627 


463 
6,164 


2,660 


2,165 


20 
387 


10 
721 


217 
186 


256 
1,562 


77 

250 

6 

32 
441 
496 


13,049 


i3i 

236 

4,857 

2,485 

1,705 

667 

679 

90 

59 

50 

1,037 

471 

1,279 

7 

•  961 


267 
78 
354 

2,175 


1,439 
494 
79 
163 


5,277 


440 
4,837 


1,774 


1,379 


19 
305 


199 
178 


219 
1,389 


74 
249 


403 

471 


1.000 
dollars 
16,541 


^i95 
363 

3,905 

1,944 

1,407 
554 
913 
240 
215 
147 
962 
421 

2,436 
13 

1,128 

47 

135 

158 

421 

2,911 
343 

1,288 

552 
283 
441 

4,780 


2,944 
964 

152 
720 


5,923 


329 

5,594 


2,126 


54 

1,312 

36 

22 

702 


10 
329 


107 
404 


117 
1,675 


379 

7 

60 

341 

9 

34 

188 

657 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


31 


TABLE  l3A.- -Synthetic  organic  chemicals:    United  States  production  and  sates   of 
toners  and  lakes,    I95J- -Continued 


LAKES  OR  LAKED  COLORS — Continued 


Violet  lakes,  total 


Methyl  violet  B  (C.I. 

All  other 

Yellow  lakes: 

Fast  light  yellow  (C.I.  636) 


Quinollne  yellow  (C.I.  801) 

Tartrazine  (C.I.  640) 


REDUCED  OR  EXTENDED  TONERS 


Products  for  which  separate  statistics  may  not  be  shown 

Products  for  which  separate  statistics  are  shown  below 


Blue  toners,  reduced: 

Peacock  blue  R  (C.I.  664),  PMA  and  PTA 

Phthalocyanine  blue  B  (Pr.  481) 

Setoglaucine  (Peacock  blue  G)  (C.I.  658),  PMA 

Setoglaucine  (Peacock  blue  G)  (C.I.  658),  PTA 

Green  toners,  reduced: 

Brilliant  green  (C.I.  662),  PMA  and  PTA 

Malachite  green  (C.I.  657),  PMA  and  PTA 

Orange  toners,  reduced:  o-Nitroaniline  orange 


pounds 


10,197 


6,383 
3,8U 


Red  toners,  reduced,  total- 
Lithol  red  R  (C.I.  189)— 
Naphthol  AS-BS  (Pr.  305)- 
Para  reds — 


Rhodamine  B  (C.I.  749),  PMA  and  PTA 

Rhodamine  6G  (C.I.  752),  PMA  and  PTA 

C.I.  69,  Toluidine  red 

All  other 

Violet  toners,  reduced: 

Ethyl  violet  (C.I.  682),  PMA 

Methyl  violet  B  (C.I.  680),  PMA  and  PTA- 

Yellow  toners,  reduced:  Benzidine  yellow — 


1,324 
16 


Quantity    Value 


9,324 


5,747 
3,577 


18 
1,148 


J, 000 
dollars 


8,994 


5,035 
3,959 


26 

1,647 

18 

22 

125 


367 

1,404 

186 

l86 

232 

232 

85 

94 

72 

74 

112 

110 

134 

134 

546 

574 

300 

259 

153 

140 

405 

374 

Unit 
value^ 


J3ai 


.99 
5.09 

1.53 

1.50 

.97 


1.43 
1.29 
2.20 

.77 


319 

.94 

97 

.52 

340 

1.47 

25 

.27 

64 

.86 

86 

.78 

67 

.50 

640 

1.11 

308 

1.19 

108 

.77 

358 

.96 

^  Calculated  on  rounded  figures. 

^  Includes  all  brown  toners  and  unspecified  violet  toners. 
'  Includes  unspecified  maroon,  orange,  and  yellow  lakes. 

*  Includes  all  brown  and  maroon  reduced  toners  and  unspecified  blue,  green,  orange,  violet,  and  yellow 
reduced  toners. 

NOTE. — The  C.I.  and  Pr.  numbers  stand  for  Colour  Index  and  prototype  numbers  of  the  dyes  from  which  the 
lakes  or  toners  may  be  produced.  When  the  number  precedes  the  name  of  the  toner,  it  signifies  that  the  toner 
is  the  same  as  the  dye  described  in  the  Colour  Index  or  prototype  listing. 

The  abbreviations  PMA  and  PTA  stand  for  phosphomolybdio  and  phosphotungstio  acids,  respectively.  Pigments 
formerly  listed  as  PTMA  (phosphotungstomolybdio  acid)  are  now  included  with  PTA  colors. 

Production  in  1953  of  toners  (full-strength  colors)    was  27.2 
million  pounds- -5.4  million  pounds  more  than  the  output  in  1952. 
Sales  of  these  colors  in  1953  totaled  22.0  million  pounds,    valued 
at  41.1  million  dollars,    compared  with  19.6  million  pounds,    valued 
at  34.2  million  dollars,    in  1952.    About  57  percent  of  the  output  of 
full-strength  toners  in  1953  consisted  of  red  toners  (15.5  million 
pounds).    Of  the  individual  toners  for  which  separate  statistics 
may  be  shown,    those  produced  in  the  largest  quantities  were 
lithol  red  R  toners  (C.I.    189),    5.2  million  pounds;  toluidine  red 
(C.I.    69),    2.6  million  pounds;  phthalocyanine  blue  B  (Pr.    481), 
2.4  million  pounds;  benzidine  yellow,    1.9  million  pounds;  and 
permanent  red  2B ,    1.4  million  pounds. 

The  combined  production  of  lakes  and  reduced  toners  in  1953 
was   16.8  naillion  pounds,    compared  with  16.9  million  pounds  in 
1952.    Combined  sales  of  lakes  and  reduced  toners  in  1953  were 
14.6  million  pounds,    valued  at  14.9  million  dollars,    compared 
with  16.0  million  pounds,    valued  at  14.6  million  dollars,    in  1952. 
Of  the  extended  pigments  for  which. separate  statistics   naay  be 
shown,    blues  constituted  the  leading  group.    Production  of  fugitive 
peacock   blue    lake    (C.I.    671)  in  1953  was  2.2  million  pounds,    and 
of  phthalocyanine  blue  B  reduced  toner  (Pr.   481),    1.  3  million 
pounds. 


32 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  16. --Synthetic  organic  chemicals:    United  States  production   and  sales  of  selected  dry, 
flushed,    and  pulp  colors,    1953' 

[Listed  below  are  selected  dry,  flushed,  and  pulp  colors  for  which  data  on  production  may  be  published) 


Dry,  flushed,  and  pulp  forms 


Alkali  blue  toner  (C.I. 
Dry  form- 


704): 


Flushed  form 

Pulp  form 

Benzidine  yellow  toner: 

Dry  form 

Flushed  form 

Pulp  form 

Eosine  (C.I.  768)  and  phloxine  (C.I.  774)  toners: 

Dry  form 

Fliished  form 

Lithol  red  R  (C.I.  189),  barium  toner: 

Dry  form 

Flushed  form 

Pulp  form 

Lithol  red  R  (C.I.  189),  calcium  toner: 

Dry  form 

Flushed  form 

Pulp  form 

Lithol  red  R  (C.I.  189),  sodium  toner:^ 

Dry  form 


Flushed  form 

Methyl  violet  B  (C.I.  680),  fugitive: 

Dry  form 

Flushed  form 

Pulp  form- 


Methyl  violet  B  (C.I. 

Dry  form 

Fliished  form- 


680) ,  permanent  (PMA  and  PTA) : 


Peacock  blue  (C.I.  671),  fugitive: 
Dry  form- 


Flushed  form- 


Toluidine  red  toner  (C.I. 

Dry  form 

Flushed  form 

Pulp  form 


69): 


Produc- 
tion 


1,000 
ounds 

99 

2,685 

581 

1,460 

2,337 

608 

250 
1,735 

2,167 

1,695 

350 

1,498 
650 
226 

519 
402 

250 
553 


312 
226 

905 
2,668 

2,182 
632 
445 


Quantity 


2,698 
519 

1,236 

2,309 

229 


1,981 

1,538 

176 

1,424 
700 
110 

536 
297 

225 
478 


291 
222 

519 
2,048 

1,660 
415 
351 


1,000 
dollars 
191 
2,929 

654 

2,237 

1,321 

243 

218 
772 

1,509 
650 


1,116 
357 


424 
151 


290 
312 


599 
233 

519 
1,185 

2,408 
324 
156 


Unit 
value^ 


$1.95 
1.09 
1.26 

1.81 

.57 

1.06 


2.06 
1.05 

1.00 
.58 

1.45 
.78 
.44 


^  Statistics  on  production  and  sales  of  the  organic  pigments  (color  lakes  and  toners)  listed  in  this  table 
are  given  in  terms  of  the  commeroial  (physical)  forms  in  which  they  enter  commercial  channels.  Data  on  the 
flushed  and  pulp  forms  therefore  are  in  terms  of  total  weight,  including  pigment  and  vehicle  (water  or  oil). 

^  Calculated  on  rounded  figures. 

'  Data  on  the  pulp  form  were  received  in  confidence  and  may  not  be  published. 

Statistics  on  the  selected  dry,    flushed,    and  pulp    colors  in 
table   16  show  that  in  1953  the  quantity  of  production  and  sales  of 
the  toners  alkali  blue,    benzidine  yellow,    fugitive  methyl   violet  B, 
fugitive  peacock  blue,    and  eosine  and  phloxine  toners  in  the  flushed 
form  exceeded  the  quantity  of  production  and  sales  in  the  dry  form. 
Production  and  sales,    in  the  dry  form,     of  permanent  methyl 
violet  B  (PMA  and  PTA),    toluidine  red,    and  the  barium,    calcium, 
and  sodium  toners  of  lithol  red  R  exceeded  production  and  sales 
in  the  flushed  fornn..    In  1953,  for  most  pigments,     production  and 
sales    in  the  pulp  form  were  smaller  than  those  in  either  the 
flushed  or  the  dry  form. 

Medicinals 


In  this  report  medicinal  chemicals  are  divided  into  three  major 
groups:  (l)    Benzenoid  compounds,    derived  principally  from  coal 
tar;  (2)  alicyclic  and  heterocyclic  compounds,     usually  derived  from 
vegetable  products  and  animal  tissues  but  sometimes  also  from  coal 
tar;  and  (3)  acyclic  compounds,    usually  derived  from  petroleum  and 
from  natural  gas,    or  from  grain  by  fermentation. 


SYNTHETIC  ORGANIC  CHEMICALS,  i953  33 

Statistics  on  production  of  medicinals  are  in  terms  of  100-per- 
cent content  of  the  medicinal  itself,    exclusive  of  all  diluents  or 
other  materials  used  in  mixing  or  compounding  tablets,    solutions, 
and  suspensions  for  consumer  use.     Except  for  antibiotics,    the 
statistics  on  sales  include  only  that  part  of  the  original  (primary) 
production  which  was  sold  in  undiluted  or  uncompounded  form, 
including  that  sold  in  bulk  and  that  sold  in  packages  (tablets, 
ampoules,    etc.).    Sales  of  antibiotics  include  all  forms- -diluted  or 
undiluted,    in  bulk  or  in  packages. 

In  1953  the  production  of  all  medicinal  chemicals  covered  in 
this  report  amounted  to  67  million  pounds  (see  table   ITA*^)-- 
slightly  less  than  the  output  reported  for   1952.  Sales  in  1953  totaled 
54  million  pounds,    valued  at  409  million  dollars,    compared  with 
51  million  pounds,    valued  at  430    million  dollars,    in  1952. 

The  output  in  1953  of  all  cyclic  medicinals  was  51  million 
pounds,    of  which  3"'  million  pounds  consisted  of  benzenoid   chemi- 
cals.   Production  of  acyclic  medicinals  in  1953  was  16  million 
pounds,    compared  with  11  million  pounds  in  1952.    In  terms  of 
quantity,    acetylsalicylic  acid  (aspirin)  was  the  most  important 
medicinal  produced  in  1953.    The  output  in  that  year  was  14 million 
pounds,    compared  with  13  million  pounds  in  1952;  sales  in  1953 
were  12  million  pounds,    valued  at  6  million  dollars.    In    1953  the 
output  of  sulfa  drugs  totaled  4.7  million  pounds,    compared  with 
5.8  million  pounds  in  1952;  sales  in  1953  were  3.1  million  pounds, 
valued  at  16.8  million  dollars,    compared  with  3.1  million  pounds, 
valued  at  15.9    million  dollars,    in  1952.    Production  of  barbituric 
acid  derivatives  in  1953  totaled   634,000  pounds--an  increase  of 
18.1    percent  from  the  537,000  pounds  reported  for  1952.  Sales  in 
1953  totaled  427,000  pounds,    valued  at  2.8  million  dollars. 

As  a  group,    the  antibiotics  were  the  most  important  medicinals 
produced  in  1953,    in  terms  of  value.    In  1953  the  combined  output  of 
all  antibiotics  for  human  and  veterinary  use  was   1,630,000  pounds-- 
an  increase  of  143,000  pounds  over  the  1,487,000  pounds  produced 
in  1952.    Sales  in  1953  totaled  1,467,000  pounds,    valued  at  231 
million  dollars,  compared  with  1,321,000  pounds,    valued  at  267 
million  dollars,    in  1952,    reflecting  a  decline  in  prices.    Produc- 
tion of  penicillin  salts  in  1953  totaled  about  372  trillion  inter- 
national units,    compared  with  342  trillion  international  units  in 

1952.  Sales  in  1953  were  about  354  trillion  international  units, 
valued  at  58  million  dollars,    compared  with  sales  of  287   trillion 
international  units,    valued  at  83  million  dollars,    in  1952.    Peni- 
cillin procaine  was  the  most  important  penicillin  salt  produced  in 

1953.  The  output  of  dihydrostreptomycin  in  1953  declined  to 
305,000  pounds  from  the  337,000  pounds  reported  for  1952.    The 
output  of  streptomycin  in  1953,    however,    was  125,000  pounds, 
compared  with  50,000  pounds  in  1952.    The  combined  output  of 
most  of  the  broad-spectrum  antibiotics  in  1953  was  441,000  pounds, 
compared  with  414,000  pounds  in  1952.    The  output  of  antibiotics 
for  animal  feed  supplements  in  1953  was  434,000  pounds,  compared 
with  the  258,000  pounds  reported  for  1952. 

Among  the  other  important  medicinals  produced  in  1953  were 
the  vitamins.    The  combined  output  of  vitamins  as  a  group  in  1953 
was  4.7  million  pounds,    compared  with  an  output  of  4.9  million 


^  See  also  table  17B,  part  HI,  which  lists  these  products  alphabetically  and  identifies 
the  manufacturers. 


34  UNITED  STATES  TARIFF  COMMISSION 

TABLE  17 A.  --Synthetic  organic  chemicals:    United  States  production  and  sales   of  medicinals,    1953 

[Listed  below  are  all  synthetic  organic  medicinals  for  which  any  reported  data  on  production  or  sales  may 
be  published.  (Leaders  are  used  where  the  reported  data  are  confidential  and  may  not  be  published  or 
where  no  data  were  reported.)  Table  17B  in  part  III  lists  alphabetically  all  medicinals  for  which  data 
on  production  or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Production^ 


Sales^ 


Value    Unit  value' 


Grand  total- 


MEDICINALS,  CYCLIC 


Chemicals  for  which  separate  statistics  may  not  be  shown- 
Chemicals  for  which  separate  statistics  are  shown  below — 


Aoetylsalicylic  acid  (Aspirin)- 

Adrenaline  (Epinephrine) 

Amino  acids 


p-Aminobenzoic  aeid- 


p-Aminobenzoic  acid  derivatives,  total - 

Benzocalne  (Ethyl  p-amnobenzoate ) 

Procaine  base  and  hydrochloride 

All  other 


p-Aminobenzoio  acid  salts 

4-Aminosalicylic  acid  and  salts — 

Bismuth  subgallate 

Bismuth  subsalicylate 

0.,  a'-Diethyl-4,<i'-stilben6diol  (Diethylstilbestrol) 

N-a-Dimethylphenethylamine  base  and  hydrochloride 

Dyes ,  medicinal 

p-Hydroxybenzoic  acid  esters; 

Methyl  p-hydroxybenzoate 

Propyl  p-hydroxybenzoate 

a-Methylphenethylamine  (Amphetamine)  (Benzedrine)  base- 

a-Methylphenethylamine  salts 

Phenylmerourio  derivatives 

Prostigmine  (Neostigmine)  methyl  sulfate 

Resorcinol  monoacetate 

Salioylamide 

Salicylic  acid — 


Salicylic  acid  salts,  total- 

Calciuni  salicylate 

Sodium  salicylate 

All  other 


Silver  picrate ~ 

Sodium  ethylmercurithiosallcylate 

Sulfa  drugs 

Thymol  iodide — '■ 

3-o-Toloxy-l,2-propanediol  (o-Cresyl  a-glyceryl  ether) - 

Vitamin  K  and  derivatives 

All  other  benzenold  medicinals ~ 


Mi 


and  Htt€ 


Total- 


Alkaloids,  total 

Berberine  and  salts 

Homatroplne  and  salts- 
All  other — 


Amino  acids- 


Antibiotics  for  human  or  veterinary  use,  total 

Dihydrostreptorayoln 

Penicillin  salts,  total^o  ^^ 

Dlpenicillin  G  dlbenzylethylenedlamine 

Penicillin  potassium 

Penicillin  procaine 

Penicillin  sodium 

Streptomycin 

All  other .. 

See  footnotes  at  end  of  table . 


1.000 
pounds 
66,585 


51,003 


10,505 
^0,A98 


37,232 


13,713 
(*) 

3 


431 
17 


<i78 
30 
134 


(*) 


136 
8,020 


13,771 


(') 


305 
753 

37 
132 
556 

28 
125 


54,227 


1,000 
dollars 
409,068 


41,080 


380,914 


8,496 
32,584 


22,036 
358,878 


28,942 


37,92.6 


11,664 

(*) 

(') 

43 

503 


6,060 


192 

1,299 

197 


(*) 


117 
5,637 


155 
2,154 


726 
36 

(«) 

3,061 

21 

277 

1 

6,523 


12,138 


3 
423 


15 


20 

16,760 

155 

482 

21 

8,539 


342, S 


231,484 


4 

1,520 

297 

24,547 

708 

57,752 

32 

4,183 

144 

24,170 

509 

26,851 

23 

2,548 

104 

10,7!:5 

354 

136,880 

SYNTHETIC  ORGANIC  CHEMICALS,  1953 


TABLE   ITA.  -Synthetic   organic  chemicals:    United  States  production   and  sales   of  medic 


35 

3is,  J95J- -Continued 


Production-^ 


Sales^ 


Quantity- 


Value    Unit  value' 


MEDICINALS,  CYCLIC— Continued 
Alicyclic   and  He  terocyclic— Continued 


Antitiotios  for  animal  feed  supplements- 
Antihistajnines 


Bartiturio  acid  derivatives,  total 

5-Allyl-5-(l-methylbutyl)l)ai'bituric  acid  (Secobarbital) 

and  salt 

5,5-Diethylbarbiturio  acid  (Barbital)  and  salt 

5-Ethyl-5-(l-methylbutyl)barbiturio  acid  (Pentobarbital) 

and  salts 

5-Ethyl-5-phenylbarbituric   acid  (Phenobarbital)    (Luminal)- 

5-Ethyl-5-phenylbarbituric  acid  salts 

All  other 


Bile  acids  and  salts,  total- 
Cholic  acid 


Dehydrooholic  acid- 
Desoxycholic  acid — 
All  other 


Bromooamphor ,  mono 

Caffeine,  na-tural  and  synthetic 

Caffeine  citrate 

Caffeine  sodium  benzoate 

Camphoric  acid 

5-Chloro-7-iodo-8-quinolinol  ( lodoohlorohydroxyquinoline ) - 

Dihydrooodeinone  bitartrate *- 

5,7-Diiodo-8-quinolinol 

5,5-Diphenylhydantoin  and  sodium  salt 


Hormones ,  total 

Estrone 

17-Hydroxy-ll-dehydrocorticosterone  (Cortisone) - 

Progesterone 

All  other 


8-Hydroxy-7-iodo-5-quinolinesulfonio  acid  (Yatren  acid) 

and  salt 

Phenothiazine 

Piperazine — 

Rutin ! 


Terpinol  hydrate 

Theobromine  and  derivatives 

Theophylline  base  and  derivatives,  total 

Theqphylline  base  (1,3-Dimethylaanthine) 

Theophylline  ethylenediamine  (Aminophylline) 

All  other 

Vitamins,  total — 


A  (Alcohol  and  esters),^*  from  all  sources : 

B],  (Thiamin  derivatives) 

Bj  (Riboflavin)  for  human  and  for  animal  and  poultry  con- 
sumption, lOOJt 

Bs  ( Pyr idoxine ) 

Bi2)  all  grades 

D2  (Irradiated  ergosterol)^' 

D3  (Irradiated  animal  sterol) *°- 


Niacin  (Nicotinic  acid),  niacinamide,  and  niacinamide 

hydrochloride 

All  other — — 


All  other  alicyclic  and  heterocyclic  mediclnals- 
MEDICINAI£,  ACYCLIC 
Total 


Chemicals  for  which  separate  statistics  may  not  be  shown — 
Chemicals  for  which  separate  statistics  are  shown  below 


Acetylcholine  chloride 

Acetyl-^-methylohollne  ohloride- 


1,000 
pounds 

63^ 


l.OCO 
pounds 
"  391 
43 

<127 


128 
303 


37 

57 

102 


1,554 
10 


1,580 


(14) 


3,700 

21 

9 

74 

164 

167 


3,370 


131 
118 


96 

10 

2,700 


74 
2,309 


113 
277 


266 
18 


1,893 
131 


2,165 


15,582 


8,486 
7,096 


(") 


85 
194 


192 
18 


(18) 


1,660 
158 


1,973 


13,147 


7,239 
5,908 


(21) 
(22) 


1,000 
dollars 
19,423 
1,195 

2,757 


316 

1,160 

77 

1,054 


2,516 


4.644 


4,644 


12 

1,637 

59 

29 
369 

499 


336 
59,171 


10,808 
10,988 

7,673 
4,267 
14,270 
540 
1,364 

6,037 
3,224 

13,497 


28,154 


4,353 
23,801 


ound 
$49.68 
27.69 


10.12 
4.05 


333 

9.70 

462 

17.65 

615 

14.68 

1,106 

16.99 

32 

2.44 

4,913 

3.11 

32 

2.61 

5 

4.38 

22 

3.58 

36 

5.11 

254 

253.76 

57 

5.05 

115 

3.50 

1.154.92 


1,154.92 


5.60 

.49 

2.77 


.58 

2.81 


4.54 
25.63 


(17) 

56.69 

39.89 
232.64 
74,709.47 
(17) 
(17) 

3.64 
20.54 


.60 
4.03 


17.36 
69.62 


See  footnotes  at  end  of  table. 


36 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  17A. --Synthetic  organic  chemicals:   United  States  production  and   sales   of  medicinals,    795J- -Continued 


Production^ 


Sales^ 


Quantity 


Value    Unit  value'' 


MEDICINALS,  ACYCLIC— Continued 


Amino  acids,  total - 
/W-Alanine 


1(+) -Glutamic  aoid- 
iU.1  other 


Betaine  hydrochloride 

Calcium  succinate 

Choline  bitartrate 

Choline  chloride,  for  poultry  feed  and  for  use  as  a  chemical 

intermediate 

Choline  chloride,  medicinal  grade 

Methylene  iodide 

Methyl  iodide 

Sodium  succinate 


Tartaric  acid,  calcium  salt- 


Vitamins  ,  total 

Ascorhic  acid  and  derivatives 

Pantothenic  acid  and  derivatives,  total- 
Pantothenic  acid,  d-calcium  salt 


Pantothenic  acid,  dl-calcium  salt 

All  other 


poinds 


1,759 


197 
92 
1,470 


3,108 
53 


1,958 
1,672 


286 

161 

105 

20 


1,000 
pounds 
1,466 


150 

134 

1,182 


50 
108 


2,301 
40 


1,896 


1,770 
126 


1,000 

dollar: 

3,636 


305 
2,883 


37 
158 

1,138 
62 
81 


18,579 


15,865 
2,714 


2,714 


pound 
$2.48 


2.99 
2.28 
2.44 


.49 
1.55- 
7.67 
3.79 

.95 
1.48 


9.80 


21.54 


^  Production  of  medicinals  in  bulk  only.  The  statistics  do  not  include  the  production  of  finished  prepara- 
tions, such  as  tablets,  capsules,  and  ampoules,  which  are  manufactured  from  bulk  medicinals. 

^  Except  for  antibiotics,  sales  include  only  that  part  of  the  original  production  which  is  sold  in  undi- 
luted or  uncoiiipounded  form  including  that  sold  in  bulk  and  that  sold  in  packages  (tablets,  ampoules,  etc.). 
Sales  of  antibiotics  include  all  forms  (both  imdiluted  or  uncoiiipounded  and  diluted  or  compounded)  including 
that  sold  in  bulk  and  that  sold  in  packages. 

^  Calculated  on  the  exact  (i.e.,  unrounded)  figures. 

*  Production  of  adrenaline  totaled  136  pounds;  sales  totaled  27  pounds. 
'  Sales  of  benzenoid  amino  acids  totaled  571  pounds. 

*  Production  and  sales  of  prostigmine  methyl  sulfate  each  totaled  27  pounds. 
'  Production  and  sales  of  silver  piorate  each  totaled  116  pounds. 

*  Sales  of  sodium  ethylmercurithiosalicylate  totaled  279  pounds. 

'  Production  of  alicyolic  and  heterocyclic  amino  acids  totaled  281  pounds. 

^°  Penicillin  salts,  in  terms  of  international  units,  were  reported  as  follows: 


Production 


Quantity 


Total 

Dipenicillin  G  dibenzylethylenediamine 

Penicillin  potassium 

Penicillin  procaine 

Penicillin  sodium 


Billion    inter, 
national    units 

371,589 


lai  units 

354,024 


1.000 
dollars 

57,752 


$163.13 


19,099 

92,518 

239,764 

20,208 


16,787 
100,979 
219,495 

16,763 


4,183 
24,170 
26,851 

2,548 


249.18 
239.36 
122.33 
152.00 


■"■^  Excludes  minor  quantities  of  miscellaneous  penicillin  salts  for  which  data  cannot  be  shovm  separately. 
These  data  are  included  with  "All  other"  antibiotics. 

^^   Commercial  sales  are  based  on  international  units. 

Quantities  reported  in  units  have  been  converted  to  pounds,  using  as  a  factor  the  average  units  per 
pound  of  the  medicinal  grade  as  determined  by  the  U.  S.  Food  and  Drug  Administration. 

^*  Production  of  estrone  totaled  25  pounds. 

•"■'  Production  of  progesterone  totaled  100  pounds. 

^*  Production  of  vitamin  A  alcohol  and  esters  made  from  lemon-grass  oil  and  fish  oil  totaled  106,946  bil- 
lion U.S.P.  units;  sales  totaled  82,368  billion  U.S. P.  units.  Quantities  in  pounds  shown  in  the  table  have 
been  calculated  from  the  U.S.P.  units  reported  for  each  vitamin  A  compound,  using  the  theoretical  weight  per 
unit. 

^'  Commercial  sales  are  based  on  U.S.P.  units. 

^*  Production  of  vitamin  B12,  all  grades,  totaled  387  pounds;  sales  totaled  191  pounds. 

"•'  Production  of  vitamin  D2  totaled  25,824  billion  U.S.P.  units;  sales  totaled  23,147  billion.  Calculated 
at  the  rate  of  18.14  billion  units  per  pound,  production  totaled  1,424  pounds  and  sales  totaled  1,276  pounds. 

*°  Production  of  vitamin  D3  totaled  24,244  billion  U.S.P.  units;  sales  totaled  21,713  billion.  Calculated 
at  the  rate  of  18.14  billion  units  per  pound,  production  totaled  1,337  pounds  and  sales  totaled  1,197  pounds. 

^^  Production  of  acetylcholine  chloride  totaled  440  pounds.  Sales  totaled  447  pounds. 

^^  Production  of  aoetyl-^-methylchollne  chloride  totaled  379  pounds.  Sales  totaled  369  pounds. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953  37 

pounds  in  1952.    Sales  in  1953  were  4.2  million  pounds,    valued 
at  78  million  dollars.    In  terms  of  quantity,    the  output  in  1953  of 
some  of  the  more  important  vitamins  was  as  follows:  Niacin, 
niacinamide,    and  niacinamide  hydrochloride,    1.9  million  pounds; 
ascorbic  acid  and  derivatives,    1.7  nnillion  pounds;  thiamin  deriva- 
tives,   277,000  pounds;  riboflavin,    266,000  pounds;  and  vitamin   A 
alcohol   and   esters,     107   trillion   U.S.  P.  units,    or  113,000  pounds 
(as  calculated  from  the  data  reported  in  U.S. P.    units,    using  the 
theoretical  weight  per  unit  as  a  basis). 

Flavor  and  Perfume  Materials 

Flavor  and  perfume  materials,    which  are  chemicals  with 
desirable  flavors  or  odors,    are  used  in  the  manufacture  of  food, 
beverages,    cosmetics,    and  soaps,    and  to  disguise  unpleasant 
odors  in  industrial  products.    This  report  covers  flavor  and  per- 
fume materials  derived  from  nat-iral  products  by  actual    chemical 
processes,    and  from   coal  tar.    It  does  not  cover  purely  natural 
products,    such  as  floral  essences,    essential  oils,    and  other   per- 
fume materials  obtained  by  simple  extraction  or  by  distillation 
from  natural  vegetable  and  aninnal  sources. 

On  the  basis  of  their  chemical  structure,    the  flavors    and   per- 
fumes covered  in  this  report  are  grouped  as  either  cyclic  or 
acyclic  materials.    Cyclic  materials  are  further  classified  as  (1) 
benzenoid  and  naphthalenoid,    and  (2)  terpenoid,    heterocyclic,     and 
alicyclic.    Statistics  on  the  production  and  sales  of  flavor  and 
perfume  materials  in  1953  are  given  in  table  18A.^ 

Production  of  flavor  and  perfume  materials  as  a  group  totaled 
34  million  pounds  in  1953,    compared  with  the  28  million  pounds 
reported  for  1952.    Sales  in  1953  were  31  million  pounds,    valued 
at  47  million  dollars,    compared  with   26  million  pounds,    valued 
at  40  million  dollars,    in  1952. 

The  output  of  benzenoid  and  naphthalenoid  flavor  and  perfume 
materials  in    1953  was  11  million  pounds,    an  increase  of  14.2  per- 
cent from  the  10  million  pounds  reported  for  1952.    Sales  in  1953 
were  10  million  pounds,    valued  at  13  million  dollars,    compared 
with  9  million  pounds,    valued  at  1 1  million  dollars,    in  1952. 
Methyl    salicylate  (synthetic  wintergreen  oil)    is  the    chemical  in 
this  group   produced  in  greatest  volume;  in  1953  production  totaled 
3.2  million  pounds--an  increase  of  28.5  percent  from  the  output 
in  1952.    Two  important  chemicals  in  this  group  for  which  statistics 
may  not  be  shown  are  benzyl  benzoate  and  vanillin. 

In  1953  the  output  of  terpenoid,    heterocyclic,    and  alicyclic 
flavor  and  perfume  materials  was  7.3  million  pounds,    compared 
with  5.8  million  pounds  in  1952- -an  increase  of  26.0   percent. 
Sales  in  1953  were  6.1  million  pounds,    valued  at  8.7  million  dollars, 
compared  with  5.1  million  pounds,    valued  at  8.1  million  dollars, 
in  1952.    In  volume  of  production,    the  most  important  chemicals  in 
this  group  in  1953  were  the  alpha  and  beta  terpineols  (2,013,000 
pounds)  and  geraniol   (551,000   pounds). 


See  also  table  18B,  part  III,  which  lists  these  products  alphabetically  and  identifies 
the  manufacturers.  . 


38 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  18k. -Synthetic  organ! 


chemicals:    United  States  production  and  sales  of  flavor   and 
perfime  materials,    1953 


[Listed  below  are  all  synthetic  organic  flavor  and  perfvune  materials  for  which  any  reported  data  on  produc- 
tion or  sales  may  be  published.  (Leaders  are  used  where  the  reported  data  are  confidential  and  may  not  be 
published,  or  where  no  data  were  reported. )  Table  18B  in  part  III  lists  alphabetically  all  flavor  and 
perfume  materials  for  which  data  on  production  or  sales  were  reported  and  identifies  the  manufacturer  of 
each! 


Grand  total- 


FLAVOR  AND  PERIJME  MATERIALS,  CYCLIC 


Total 


Materials  for  which  separate  statistics  may  not  be  shown- 
Materials  for  which  separate  statistics  are  shown  below — 

Benzenoid   and  Naphthalenoid 


a-Amyloinnamaldehyde 

Amyl  salicylate  (Isoamyl  salicylate )- 
Anethole 


Anisaldehyde 

Benzophenone 

Benzyl  acetate 

Benzyl  alcohol^ 

Benzyl  butyrate- 


Benzyl  einnamate-     — 

Benzyl  formate 

Benzyl  isoeugenyl  ether — 

Benzyl  propionate 


Benzyl  salicylate — — — ~ — ___ 

Cinnamyl  acetate-  - —- _—- 

Ethyl  anthranilate 

Ethyl  a,   #-epoxy-^-methylhydrocinnamate  (Ethyl  methylphenyl- 

glycidate) 

Eugenol _— — 

Eugenyl  methyl  ether 

laobutyl  benzoate 

laoeugenol 

2-Methoxynaphthalene  (Methyl  A -naphthyl  ether) 

Methyl  salicylate  (Synthetic  wintergreen  oil)- 
Phenethyl  aoetate- 
Phenethyl  alcohol- 


Pro- 
duction 


p-Tolyl  acetate  (p-Cresyl  acetate) 

p-Tolyl  phenylacetate  (p-Cresyl  a -toluate ) 

All  other  benzenoid  and  naphthalenoid  materials — 


Terpenoid,    Heterocyclic,    andAlicycli 


Cedryl  acetate—— 
Citral  (Geranial)- 

Citronellal 

Citronellol 


Citronellyl  acetate 

Citronellyl  propionate — 
Coumarin      i      " - 


Geranyl  acetate 

Geranyl  formate 

Hydroxycitronellal- 

o-Ionohe 

^lonone- 


lonone  (a-  and  ;9-)- 
Linalool 


Linalyl  acetate 

Llnalyl  bensoate- 
Linalyl  formate — 
Llnalyl  proplonate- 


Menthol,  synthetic,  tech. 

Methyl- a-ionone 

Hethylionone  (a-  and  fi-)- 
Nerol— 


Pipercmal  (Heliotropln)- 


1,000 
pounds 
33, 871 


18,458 


6,828 
11,630 


11,153 


n 


Sales 


Quantity   Value 


31,080 


16, 512 


102 
6 


3,174 


4,218 


7,305 


3 
359 
551 

30 

2 

148 

10 
111 

38 
251 
120 

(') 

"'77 

52 

2 

240 


5,742 
10,770 


10,402 


203 

201 

297 

282 

... 

... 

531 

787 

462 

193 

186 

347 

150 

157 

179 

557 

567 

309 

775 

684 

328 

2 

e) 


45 
5 

2,802 

54 

733 


4,049 


6,110 


1,000 
dollars 
46,528 


21,419 


9,886 
11, 533 


12,690 


A6 

48 

1 

165 

3 

3 

397 

521 

27 

2 

118 

9 

69 

34 

48 

89 

(') 
255 

66 
59 
2 

243 


34 
185 

3 

152 

10 

1,290 

74 

948 

2 

4 

7,996 


8,729 


102 
139 


1,053 

436 

35 

8 

472 

47 

290 

101 

238 

449 

1 

3 

2 

1,137 

321 

264 

19 

615 


pound 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  I953 


39 


TABLE  ISA- --Synthetic  orianic  chemicals:   United  States  production  and  sales  of  flavor  and 
per  time  materials ,   /95J- -Continued 


Pro- 
duction 


Quantity       Value 


Unit 
valiie^ 


FLAVOR  Am  PERFUME  MATERIALS,  CYCLIC—Contlnued 
Terpenoid,    Hettrocyclic,    and  Alicyclic — Continued 


Rhodinyl  acetate- 

Safrole 

Santalol 


Terplneols  (a-,  g-,   and  a-  +  ^-)- 

Terpinyl  acetate ,  ■ .  .,.------■ 

Vetivenyl  acetate- 


All  other  terpenoid,  heterocyclic,  and  allcycllc  materials 

FLAVOR  AND  PERFUME  MATERIALS,  ACYCLIC 


1,000 
pounds 

8 

(') 

138 

1 

2,013 

2-;5 

7 

2,610 


15, -413 


6 

115 

1,833 

255 

3 

1,693 


U,  568 


1,000 
dollar, 

159 


368 
118 


1,890 


25,109 


Materials  for  which  separate  statistics  may  not  be  shovm — 
Materials  for  which  separate  statistics  are  shown  below 

Allyl  caproate- 
n-Butyl  butyrate- 


418 
U,995 


295 
U,273 


510 
24,599 


Ethyl  butyrate 

Ethyl  caprate  (Ethyl  deeylate) 

Etl^l  oaproate   (Ethyl  hexoate) 

Ethyl  caprylate  (Ethyl  oetoate) 

Glutamic  acid,  monoaodlum  salt  (Monosodlum  glutamate)- 

Isoamyl  butyrate  (Amyl  butyrate) 

Isoanyl  formate  {Aayl   formate) 

Isoamyl  propionate  (Amyl  propionate) 

Isobutyl  acetate-  -  — 


14,738 
30 


14,029 
30 


138 
2 
2 
1 
2 
24,419 
21 


Per 
pound 

$25.73 

26.36 

.75 

.20 

.46 

29.03 

1.12 


1.72 
1.72 


2.30 
1.31 

.69 
1.09 
1.87 
1.03 
2.70 
1.74 

.69 
1.02 
1.01 

.55 


Calculated  on  the  exact  (i.e.,  unrounded)  figures. 
^  Includes  some  technical  and  medicinal  benzyl  alcohol. 
'  Less  than  500  pounds. 
*  Includes  chemically  modified  essential  oils. 

Production   of  acyclic  flavor  and  perfunne  materials  in  1953 
totaled  15.4  million  pounds--an  increase  of  26.6  percent   over  the 
12.2  million  pounds  produced  in  1952.    By  far  the  most  important 
material  in  this  group  in  1953  was  monosodium  glutamate,    pro- 
duction of  which  amounted  to  14.7  million  pounds- -or  more  than 
95  percent  of  the  total  output  of  acyclic   perfume  and  flavoring 
materials. 

Plastics  and  Resin  Materials 


The  products  covered  in  this  section  of  the  report   are  synthetic 
plastics  and  resin  materials  which  are  formed  by  the  condensation 
or   polymerization  of  organic  chennicals  together  with  certain  addi- 
tives which  are  necessary  to  impart  certain  qualities  to  the  resins 
or  to  improve   their   physical  properties.    Sorne  types  of  these 
materials  may  be  molded,    cast,    or  extruded  into  semifinished   or 
finished  forms.    Others  are  used  for  adhesive s,    for  the  treatment 
of  textiles  and  paper,    and  for  protective  coatings.    Some  plastics 
are  made  into  sheets  of  filnm  of  varying  thicknesses,    which  are 
used  in  the  production  of   rainwear,    shower    curtains,    draperies, 
and  wrapping  materials.    Cellulose  plastics,    being  derived  from 
natural  raw  materials,    are  not   included  in  this  section.    (See 
appendix  D.)  Except  for  the  data  on  vinyl  resins,    which  are  shown 
on  the  basis  of  resin  content,    the  statistics  on  plastics  and  resin 
materials  in  this  report  are  given  on  the  basis  of  the  total  weight 
of  the  materials,    excluding  liquids. 


40 


UNITED  STATES  TARIFF  COMMISSION 


Statistics  on  the  production   and  sales  of  plastics  and  resins  in 
1953  are  given  in  table   19A^    according  to  the  chemical  composi- 
tion of  the  materials  and  in  table  20    according  to  their  uses.    In 
1953  the  total  output  of  all  synthetic  plastics  and  resin  materials 
(except  cellulosics)  announted  to  2,777  million  pounds,    or  19.0 
percent  more  than  the  2,333  million  pounds  reported  for  1952. 
Sales  in  1953  amounted  to  2,372  million  pounds,    valued  at  838 
million  dollars,    connpared  with  2,045  million  pounds,    valued  at 
727  million  dollars,    in  1952.    Production  of  cellulose  plastics  in 
1953  (table  30)  was  129  million  pounds. 

TABLE  19A- -'Synthetic  organic  chemicals:   United  States  production  and  sales  of  plastics  and  resin  materials, 
grouped  according   to  chemical  composition,    1953 

[Quantities  and  values  are  given  in  terms  of  the  total  weight  of  the  materials  (dry  basis).  Listed  below  are 
all  synthetic  plastics  and  resin  materials  for  which  any  reported  data  on  production  or  sales  may  be  pub- 
lished. (Leaders  are  used  where  the  reported  data  are  confidential  and  may  not  be  published  or  where  no 
data  were  reported.)  Table  19B  in  part  III  lists  all  plastics  and  resin  materials  for  which  data  on  pro- 
duction or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Sales 


Quantity 


Unit 
value^ 


Grand  total- 


PLASTICS  AND  RESIN  MATERIALS,  BENZENOID 


Materials  for  which  separate  statistics  may  not  be  shown^— 
Materials  for  which  separate  statistics  are  shown  below 


Coumarone-indene.  and  petroleum  polymer  resins- 


Phenolic  and  other  tar-acid  resins,  total- 
Unmodified,  total- 


p-tert-Butylphenol-bisphenol-formaldehyde- 

p-tert-Butylphenol-formaldehyde 

Cresols-formaldehyde ____ 

Cresylic  aoid-fonnaldehyde- 


Phenol-cresols-formaldehyde 

Phenol-oresols-xylenols-formaldehyde- 

Phenol-cresylio  acid-formaldehyde 

Phenol-formaldehyde 

Phenol-furfural 


Phenol-resoroinol-formaldehyde 

Phenylphenol-formaldehyde 

Resorcinol-formaldehyde 

Xylenols-formaldehyde 

All  other 


Modified,  total 


Except  rosin  and  rosin  ester  modified,  total 

Phenol-formaldehyde-aniline- 


Phenol-formaldehyde,  oil  modified- 
Rosin  and  rosin  ester  modified,  total- 


Bisphenol-formaldehyde-rosin  and  rosin  ester 

p-tert-Butylphenol-formaldehyde-rosin  and  rosin  ester- 

Phenol-formaldehyde-rosin  and  rosin  ester 

All  other 


Phthalic  alkyd  resins,  total- 
Unmodified,  total- 


Phthalio  anliydride-glycerol 

Phthalic  anhydride-glycerol-glycol 

Phthalic  anhydride-glycerol-pentaerythritol 

Phthalic  anhydride-glycerol-sorbitol 

Phthalic  anhydride-glycol-pentaerythritol 

Phthalic  anhydride-pent aerythritol 

All  other 


Modified,  total 

Except  rosin  and  rosin  ester  and  styrene  modified,  total — 

Phthalic  anhydrlde-adipic  acld-glycol 

Phthalic  anhydride-benzoic  acid-glyoerol 

See  footnotes  at  end  of  table. 


1,000 

pounds , 

dry   basis' 

2,776,627 


dry  basis' 
2,371,980 


1,000 
dollars 
837, 536 


1,605,4A7 


1,317,069 


362,958 


15,371 
1,590,076 


12,840 
1,304,229 


6,270 
356,688 


206,645 
484,942 


201,978 
426,349 


19,544 
114,326 


433,757 

2,604 

5,276 

6,724 

4,234 

13,203 

7,885 

2,545 

373,136 

1,254 

2,023 

3,271 

628 

259 

10,715 

51,185 

15,379 

5,581 

1,813 

7,985 

35,806 

7,322 

4,517 

10,689 

13,278 

390,527 


287,606 

142,374 

6,104 

37,500 

1,973 

25,132 

71,822 

2,701 

102,921 

38,703 

309 

703 


380,939 
2,245 
5,130 
6,280 


1,363 

1,143 

338,281 

1,493 

3,287 

601 

236 

20,880 

45,410 

10,266 

3,915 

1,626 

4,725 

35,144 

7,249 

4,571 

10,489 

12,835 

207,663 


138,425 
64,369 

3,801 
13,215 

1,718 
19,476 
33,851 

1,995 
69,238 
25,288 

346 


100,995 

870 

2,019 

2,265 


447 

380 

85,265 

994 
1,852 

560 
89 
6,254 
13,331 
4,368 
1,262 

726 
2,380 
8,963 
1,622 
1,120 
2,879 
3,342 

63,664 


43, 332 

20,857 

1,283 

3,813 

470 

5,981 

9,949 

979 

20,332 

8,491 

195 


^  See  also  table  19B,  part  III,  which  lists  these  products  according  to  chemical  com- 
position, and  identifies  the  manufacturers. 


TABLE  19A.--Syntheti 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 

organic  chemicals:   United  States   production  and  sales  of  plasti 
grouped  according   to  chenical   composition,    195J- -Continued 


41 


and  resin  materials , 


Quantity    Value 


PLASTICS  AND  RESIN  MATERIALS,  BENZENOID—Oontlnued 

Phthallo  alkyd  resins — Continued 
Modified — Continued 

Except  rosin  and  rosin  ester  and  styrene  modified— Con. 
Phthalic  anhydride-fumario  acid-glyoerol- 


Phthalic  anhydride-glyoerol-phenol-formaldehyde 

Phthalic  anhydride-maleio  anhydride-glycerol 

Phthalic  anhydride-maleic  anhydride-glycerol- 
pentaerythritol- 


Phthalic  anhydride-maleio  anhydride-pentaerythritol— 
All  other 


Rosin  and  rosin  ester  modified,  total- 


Phthalio  anhydride-fumario  acid-glyoerol-rosin  and  rosin 
ester 

Phthalic  anhydride-glycerol-pentaerythritol-phenol- 
formaldehyde-rosin  ester- 


Phthalic  anhydride-glycerol-pentaerythritol-rosin  and 

Phthalic  anhydride-glycerol-phenol-formaldehyde-rosin  and 

rosin  ester 

Phthalic  anhydride-glycerol-rosin  and  rosin  ester 

Phthalic  anhydride-maleic  anhydride-glycerol- 
pentaerythritol-rosin  ester- 


Phthalic  anhydride-maleio  anhydride-glycerol-rosin  and 

rosin  ester _— _.__ _ 

Phthalic  anhydride-maleio  anhydride-pentaerythritol-rosin 

ester 

Phthalic  anhydride-maleio  anhydride-pentaerythritol-tall 

oil 

Phthalic  anhydride-pentaerythritol-rosin  and  rosin  ester — 

Phthalic  anhydride-pentaerythritol-tall  oil 

All  other 

Styrene  and  styrene  derivative  polymer  and  copolymer  resins, 

total 


Polystyrene- 


Styrene-alkyd  polyesters,  total 


Phthalic  anhydride-glyOerol-pentaerythritol-styrene- 

Phthalic  anhydrlde-glycerol-styrene— — — — 

Phthalic  anhydride-maleic  anhydride-glyool-styrene — 
All  other 


Styrene-butadiene  copolymer— 
Styrene-divinyl  benzene  copolymer- 
All  other  styrene  resins 


PLASTICS  AND  RESIN  MATERIALS,  NONBENZENOID 


Materials  for  which  separate  statistics  may  not  be  shown* 

Materials  for  which  separate  statistics  are  shown  below 


Allsyd  resins,  except  phthalic,  total- 
Unmodified,  total- 


Maleic  anhydride-glyoerol- 
All  other 


Modified,  total- 


Fiimaric  acid-glyoerol-rosin  and  rosin  eeter- 

Fumaric  acld-pentaerythrltol-roain  and  rosin  ester 

Maleic  anhydride-glycerol-pentaerythritol-rosin  and  rosin 

eater _ 

Maleic  anhydride-glycerol-rosin  and  rosin  ester 

Maleic  anhydride-glycol-rosin  and  rosin  ester ...  -- — 

Maleic  anhydride-pentaerythritol-roain  and  rosin  ester 

Maleic  anhydride-pentaerythritol-tall  oil 

All  other 

Rosin  and  terpene  adduot  resins,  total w 

Fumarlo  acid-roeln 


Maleic  anhydride-ros In- 
All  other 


Rosin  esters,  unmodified,  total- 
Rosln-glycerol- 


Rosin-glycerol-pentaerythrltol- 

Ros  in-pent  aerythritol 

All  other 


Silicone  resins- 


See  footnotes  at  end  of  table. 
313486  0-54-4 


1,000 

pounds, 

dry  basis' 

1,730 

3,447 

14,260 

9,409 

1,166 

7,679 

64,218 

502 

476 

6,187 

7,289 
29,247 


1,432 

1,661 

1,755 
4,747 
2,213 
8,612 


320,694 

39,421 

130 

8,788 

22,154 

8,349 

101,041 

21,180 

25,626 


1,171,180 


1,000 

pounds, 

dry   basis' 

489 

1,006 

8,732 

8,715 

938 

5,062 

43,950 


3,360 

24,067 

48 

605 

1,341 


1,742 

499 

12,288 

468,239 


1,000 
dollars 

223 

339 

2,822 

2,949 

226 

1,737 

11,841 


738 

5,919 

10 

249 

344 


491 

145 

3,945 


298,626 
32,479 


17,940 
14, 539 
94,697 
19,587 
22,850 


1,054,911 


95,823 
14, 590 


7,860 
6,730 
32,947 
8,002 
7,792 


474,578 


252,765 
918,415 


227,397 
827, 514 


166,259 
308,319 


75,973 


15,931 
118 
15,813 
60,042 
1,337 
3,358 

2,765 
18,275 

1,755 
23,635 

5,868 

3,049 

10,430 
2,848 
1,006 
6,576 

56,271 


57,593 

14,376 


17,478 
7,632 


14,376 

43,217 

1,086 

2,544 

2,335 
15,386 

18,214 

113 

3,539 

10,121 


24,053 

1,459 

15,555 

15,204 

2,558 


2,582 
667 
6,872 

55,714 


7,632 

9,846 

222 

754 

521 
3,438 

3,751 

27 

1,133 

2,1 


150 
2,064 

9,241 


23,149 

1,631 

15,575 

15,359 

1,466 


4,169 

271 

2,319 

2,482 

4,484 


42 


UNITED  STATES  TARIFF  COMMISSION 


-Synthetic  organic  chemicals:    United  States  production   and  sales  of  plastics  and  resin  materials 
grouped  according   to  chemical  composition,    i95J- -Continued 


Quantity 


Unit 
value^ 


PLASTICS  AND  RESIN  MATERIALS,   NONBENZENOID— Continued 


Urea  and  melamine  resins,   total- 
Urea-formaldehjrde  type,   total- 

Butylurea-formaldehyde 

Urea-formaldehyde 

All  other 


1,000 


257,310 


Melamine-formaldehyde  type 


Vinyl  and  vinyl  eopolyner  resins   (resin  content),   total — 
Polyvinyl  acetate- 


13, 109 
171,685 
.    9,593 

62,923 

515, 873 


1,000 
pound§ , 
dry   ko.i.» 
238.467 


Polyvinyl  chloride  and  copolymers,  total- 

Polyvinyl  chloride 

All  other- 


All  other  vinyl  restns*- 


434,796 

203,879 

230,917 

38,895 


178,975 

8,178 

161,480 

9,317 

59,492 

464,153 


1.000 

dollar, 

74,854 


393,698 

180,153 

213, 545 

32,758 


-U,ff83 
3,610 

37,724 
3,549 

29,971 

199,364 


U,566 

152,679 
69,030 
83,649 
32,119 


pound 
$0.31 


Calculated  on  rounded  figures. 

^  Dry  basis,  for  the  purpose  of  this  report,  is  defined  as  the  total  weight  of  the  material,  including 
resin,  plastieizers,  fillers,  extenders,  colors,  and  stabilizers,  and  excluding  the  weight  of  water, 
solvents,  and  other  liquid  diluents. 

'  Includes  data  for  aniline-formaldehyde,  epichlorohyxirin-phenol,  and  toluenesulfonamlde  resins. 

*  Includes  data  for  acrylic,  polyamide  (nylon),  polyethylene,  and  other  nonbenzenold  plastics  and  resins. 

'  Includes  data  for  materials  containing  both  urea  and  melamine. 

'  Includes  data  for  polyvinyl  alcohol,  butyral,  and  formal,  and  for  some  latlces  and  unspecified  materials. 


The  total  production  of  benzenoid  plastics  and  resins  in  1953 
was  1,605  million  pounds,    an  increase  of  18.8  percent  over  the 
output  in  1952.    Sales  in  1953  were  1,317  million  pounds,    valued 
at  363  million  dollars,    compared  with  1,113  million  pounds,  valued 
at  310  million  dollars,    in  1952.    In  1953,    as  in  1952,    styrene 
resins  were  the  benzenoid  materials  produced  in  the  largest 
quantity.    Production  of  styrene  resins  in  1953  amounted  to  508 
million  pounds,    compared  with  425  million  pounds  in  1952  and 
394  million  pounds  in  1951.    Sales  in  1953  were  468  million  pounds, 
valued  at  159  million  dollars,    compared  with  392  million  pounds, 
valued  at  133  million  dollars,    in  1952.    Phenolic  and  other  tar-acid 
resins  ranked  second  in  the  benzenoid  group  in  volume  of  produc- 
tion in  1953,    production  totaling  485  million  pounds,    an  increase 
of  23.3  percent  over  the  393  million  pounds  reported  for  1952. 
Sales  of  phenolic  and  other  tar-acid  resins  in  1953  amounted  to 
426  million  pounds,    valued  at  114  million  dollars.    The  phthalic 
alkyd  resins,    used  principally  in  the  manufacture  of  protective 
coatings,    were  third  in  volume  of  production  in  the  benzenoid 
group;  in  1953  the  output  of  these  resins  was  391  million  pounds; 
sales  were  208  million  pounds,    valued  at  64  million  dollars. 

Production  of  nonbenzenoid  plastics  and  resin  materials  in 
1953  anaounted  to  1,171  million  pounds,    compared  with  982  million 
pounds  in  1952- -an  increase  of  19.3  percent.    Sales  of  nonbenzenoid 
plastics  and  resins  in    1953  were   1,055   million  pounds,    valued 
at  475  million  dollars,    compared  with  932  million  pounds,    valued 
at  417  million  dollars,    in  1952.    Of  the  nonbenzenoid  plastics  and 
resins,    vinyl  resins  were  produced  in  the    largest  volume  in  1953, 
as  they  were  also  in  1952  and  1951.    Production  of  these  resins  in 
1953  amounted  to  516  million  pounds,    an  increase  of  22.8  percent 
over  the  420  million  pounds  reported  for  1952.  Sales  of  vinyl  resins 
in  1953  were  464  million  pounds,    valued  at  199  million  dollars, 
compared  with  400  million  pounds,    valued  at  174  million  dollars, 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


43 


TABLE  20. --Synthetic  organic  chemicals:    United  States  production  and  sales  of  plastics   aid  resin  materials 
grouped  according   to  classes  and  uses,    1953 

[In  thousands  of  pounds,  dry  basis^] 


Phenolic  and  other  tar-acld  resins: 

Molding  materials 

Bonding  and  adhesive  resins  for — 

Laminating  (except  plywood) 

Coated  and  bonded  abrasives 

Friction  materials  (brake  linings,  clutch  facings,  etc.) 

Thermal  insulation  (rock  wool,  fiber  glass) 

Plywood 

All  other  bonding  and  adhesive  uses 

Protective-coating  resins,  unmodified  and  modified,  except  by  rosin- 
Resins  for  all  other  uses 

Urea  and  melamine  resins: 

Textile-treating  and  textile-codting  resins 

Paper-treating  and  paper-coating  resins 

Bonding  and  adhesive  resins  for — 

Plywood 

All  other  bonding  and  adhesive  uses,  including  laminating 

Protective-coating  resins,  straight  and  modified 

Resins  for  all  other  uses,  including  molding 

Styrene  resins: 

Molding  materials— 

Protective-coating  resins,  straight  and  modified^ 

Resins  for  all  other  uses 


Vinyl  and  vinyl  copolymer  resins  (resin  content) ,  total 

Polyvinyl  chloride  and  copolymer  resins  (50  percent  or  more  polyvinyl  chloride) 
for — 

Film  (under  0.010  gage) 

Sheeting  (0.010  gage  and  over) 

Molding  and  extrusion 

Textile  and  paper  treating  and  coating 

Flooring 

Protective  coatings 

All  other  uses 

All  other  vinyl  resins  for — 

Adhesives 

All  other  uses 


Alkyd  resins: 

For  protective  coatings: 
Phthalic  anhydride  types: 

Unmodified 

Modified 

Polybasic  acid  types: 

Unmodified 

Modified 

For  all  other  uses 

Rosin  modifications: 

Rosin  esters  for  protective  coatings: 

Unmodified  (ester  gums) 

Modified  (hard  resins) 

All  other  modifications  for  protective  coatings  and  other  uses- 

Coumarone-indene  and  petroleum  polymer  resins 

Miscellaneous  synthetic  plastics  and  resins:^ 

Molding  materials 

Protective-coating  resins 

Resins  for  all  other  uses •: 


224,364 

71,083 
13,255 
18,457 
20,801 
36,075 
17,981 
28,210 
34,484 

39,579 
22,121 

52,453 
43 ,739 
30,364 
69,060 

324,157 
84,247 
99,555 


286,578 
102,593 

11,360 
9,531 
8,883 


39,396 

63,996 

30,666 

206,645 

153,568 
17,515 
99,507 


203,986 

47,430 
12,124 
15,724 
20,556 
34,489 
17,617 
25,930 
27,823 

34,883 
21,652 

50,781 
43,386 
22,801 
64,969 

298,384 
81,904 
87,949 

464,067 


64,076 
59,417 
119,696 
46,247 
21,893 
22,315 
28,035 

24,227 
78,161 


138,241 
68,921 

10,055 
4,809 
4,509 


39,979 

56,005 

30,775 

201,978 

128,356 

12,488 

119,820 


Dry  basis,  for  the  purpose  of  this  report,  is  defined  as  the  total  weight  of  the  material,  including 
resin,  plastioizers,  fillers,  extenders,  colors,  and  stabilizers,  and  excluding  the  weight  of  water, 
solvents,  and  other  liquid  diluents. 

^  Includes  data  for  styrene-alkyd  polyester  resins. 

^  Includes  data  for  acrylic,  epichlorohydrin,  polyamide  (nylon),  polyethylene,  silicone,  and  other  syn- 
thetic plastics  and  resin  materials. 

NOTE. — The  figures  In  the  above  table  are  based  on  the  Commission's  monthly  reports  on  the  production  and 
sales  of  synthetic  plastics  and  resin  materials.  They  are  partially  estimated,  and  may  not  be  correlated  ex- 
actly with  those  given  in  table  1.  The  data  given  in  the  above  table  are  in  substantial  agreement  with  those 
given  in  the  Commission's  release  for  January  1954  which  gave  a  summation  of  the  data  reported  by  months  for 
1953.  Changes  in  classification  and  a  minor  increase  in  coverage  on  some  products  result  in  some  differences 
in  the  detail  figures  given  in  this  table  from  those  given  in  the  January  1954  report. 


in  1952.    Production  of  urea  and  melamine  resins  in  1953  was  257 
million  pounds,    compared  with  228  million  pounds  in  1952.    Sales 
in  1953  were  238  million  pounds,    valued  at  75  million  dollars. 
Other  important  nonbenzenoid  plastics  produced  in  1953  were 
acrylics,   polyamide,    and  polyethylene. 


44 


UNITED  STATES  TARIFF  COMMISSION 


Statistics  on  the  production  and  sales  of  plastics  and  resins  by- 
uses,    given  in  table  20,    are  compiled  for  the  most  part  from  the 
Tariff  Commission's  monthly    surveys  on  the  production  and  sales 
of  synthetic  plastics  and  resin  materials.    In  1953,    as  in  previous 
years,    the  largest  single  use  of  plastics  and  resins  was  for  molding 
and  extruding  into  finished  products;  the  second  largest  use  for 
these  materials  was  in  the  production  of  protective  coatings. 

Rubber-Processing  Chemicals 

Rubber-processing  chemicals  are  organic  compounds  added  to 
natural  and  synthetic  rubbers  to  give  them  qualities  necessary  for 
their  conversion   into  finished  rubber  goods.    In  this  report,    cyclic 
and  acyclic  compounds  are  listed  by  use --such  as  accelerators, 
antioxidants,    and  peptizers.    Statistics  on  the  production  and  sales 
of  rubber-processing  chemicals  in  1953  are  given  in  table  21A.''' 

TABLE  21P^. --Synthetic   organic  chemicals:   United  States  production   and  saies  of 
rubber -processing  chemicais,    1953 

[Listed  below  are  all  rubter-prooessing  ohemioals  for  which  any  reported  data  on  production  or  sales  may  be 
published.  Table  21B  in  part  III  lists  separately  all  rubber-processing  chemicals  for  which  data  on  pro- 
duction or  sales  were  reported  and  identifies  the  manufaotiirer  of  each! 


Produc- 
tion 


Quantity    Value 


Unit 
value^ 


Grand  total - 


1,000 
pounds 
144, 78A 


103,221 


1,000 
dollars 
60,055 


Per 
pound 
JO. 58 


RUBBER-PROCESSING  CHEMICALS,  CYCLIC 


Total- 


121,532 


85,495 


47,592 


Accelerators,  total 

Butyraldehyde-aniline 

Guanidines 

Thiazole  derivatives,  total — . 

2,2'-Dithiobis[benzothiazole]  (2,2'-Benzothiazyl  disulfide)- 

2 -Merc  aptobenzothiazole 

All  other 

All  other  accelerators 


61,013 


Antioxidants,  total 

Amino  or  hydroxy  compounds- 
All  other 


6,167 
52,769 
14,860 
15,915 
21,994 

1,703 

55,531 


30,894 


16,562 


.54 


Peptizers,  tackifiers,  and  inhibitors 

RUBBER-PROCESSING  CHiMICALS,  aCYCLIC 


23,893 
31,638 


4,988 


333 
5,206 
23,974 
10,053 
2,745 
11,176 
1,381 

50,266 


22,419 
27,847 


4,335 


187 
2,620 
11,603 
4,609 
1,069 
5,925 
2,152 

27,560 


.56 
.50 
.A8 
.46 
.39 
.53 
1.56 

.55 


Total- 


12,756 
14,804 


3,470 


12,463 


coelerators,  total 

Dlthiocarbamic  acid  derivatives,  total^ 

Dibutyldithiocarbamic  acid,  zinc  salt 

Diethyldithiocarbamie  acid,  zinc  salt 

Dimethyldithiocarbamic  acid,  potassium  salt — 

All  other — 

Tetramethylthluram  sulfides,  total^ 

Tetramethylthiuram  disulfide 

Tetrame  thylthiuram  monosulf ide 

All  other^ 


16,159 


10,544 


Peptizers,  lubricating  and  conditioning  agents,  total- 
Dodecyl  mercaptans — _ ■  .,.  .  ,.  ,-— - 

All  other -,— , 


6,273 

766 

1,278 

145 

4,084 

5,466 

4,719 

747 

4,420 

7,093 


8,874 


6,118 
975 


2,914 

637 

1,038 

125 

1,114 

3,780 

2,995 

785 

3,850 

7,182 


6,413 
769 


2,657 

600 

977 

63 

1,017 

4,100 

3,214 

886 

2,117 

3,589 


.91 
.94 
.94 
.50 
.91 
1.08 
1.07 


3,244 
345 


A5 


Calculated  on  rounded  figures. 

^  Data  for  dithiocarba mates  included  in  this  table  are  for  material  used  exclusively  in  the  processing  of 
natural  and  synthetic  rubbers.  Data  on  dlthlocarbamates  which  are  used  as  fungicides  are  reported  In  the 
section  "Pesticides  and  Other  Organic  Agricultural  Chemicals." 

^  Includes  data  for  small  amounts  of  tetramethylthiuram  sulfides  for  uses  other  than  in  the  processing  of 
natural  and  synthetic  rubbers. 

'  Includes  a  small  amount  of  tetramethylthiuram  tetrasulfide. 


See  also  table  21B,  part  III,  which  lists  these  products  alphabetically  and  identifies 
the  manufacturers. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953  45 

Production  of  rubber-processing  chemicals  as  a  group  in  1953 
amounted  to  145  million  pounds--an  increase  of  13.7    percent 
from  the   127  million  pounds  reported  for  1952.    The  increase  in 
the  production  of  rubber-processing  chemicals  reflects  the 
increased  consumption  of  rubber  in  1953.    Sales  of  rubber-proc- 
essing chemicals  in  1953  were  103  million  pounds,    valued  at  60 
million  dollars,    compared  with  94  million  pounds,    valued  at  54 
million  dollars,    in  1952. 

The  output  of  cyclic  rubber-processing  chemicals  in  1953 
amounted  to  122  million  pounds,    or   12.6  percent  more  than  the 
108  million  pounds  reported  for  1952.    Sales  in  1953  were  85 
million  pounds,    valued  at  48  million  dollars,    compared  with  78 
million  pounds,    valued  at  42  million  dollars,    in  1952.    Of  the  total 
production  of  cyclic  rubber-processing  chemicals  in  1953,    accel- 
erators accounted  for  about  50  percent,    antioxidants  for  46  percent, 
and  other  uses  for  about  4  percent.    Included  are  statistics  for  the 
guanidines  and  certain  benzothiazole  derivatives  used  as  accel- 
erators. 

Production  of  acyclic  rubber-processing  chemicals  in  1953 
amounted  to  23.3  million  pounds,  or  19.9  percent  more  than  the 
19.4  million  pounds  reported  for  1952.    Sales  in  1953  were   17.7 
million  pounds,    valued  at  12.5  million  dollars,    compared  with  16.6 
million  pounds,    valued  at  11.7  million  dollars,    in  1952.    Accel- 
erators,   principally  dithiocarbamic  acid  derivatives  and  tetra- 
methylthiuram  sulfides,    accounted  for  approximately  70  percent 
of  the  production  of  acyclic  rubber-processing  chemicals  in  1953. 
Peptizers,    and  modifiers,    chiefly  dodecyl  mercaptans,    together 
with  lubricating  and  conditioning  agents,    accounted  for  approxi- 
mately 30  percent  of  the  output  in  the  acyclic  group. 

Elastomers  (Synthetic  Rubbers) 

The  total  output  of  elastomers  (synthetic  rubbers)  in  1953 
amounted  to  1,958  million  pounds,    an  increase  of  69  million  pounds 
over  the  production  reported  for  1952.    Sales  in  1953  were  1,909 
million  pounds,    valued  at  529  million  dollars,    compared  with  2,003 
million  pounds,     valued  at  549  million   dollars,    in  1952.    Statistics 
on  the  production  and  sales  of  elastomers  are  given  in  table  22A. 

Production  in  1953  of  cyclic  elastomers,     consisting  entirely  of 
the  polybutadiene-styrene  type  (GR-S,  BunaS),  announted  to  1,415  nail- 
lion  pounds,  slightly  more  than  the  1,394  million  pounds  produced  in 
1952.    Sales  in  1953  were  1,387  million  pounds,    valued  at  319 
million  dollars,    compared  with  the  1,514  million  pounds,    valued 
at  361  million  dollars,    reported  for  1952.    The  major  part  of  the 
GR-S  type  of  synthetic  rubber  in  1953  was  produced  in   Govern- 
ment-owned plants  for  the  account  of  the  Reconstruction  Finance 
Corporation.    The  GR-S   material  is  used  principally  in  the  pro- 
duction of  tire  casings. 

The  output  of  acyclic  elastomers  in  1953  amounted  to  543 
million  pounds,    or  9.7  percent  more  than  the  495  million  pounds 
produced  in  1952.    Sales  in  1953  amounted  to  522  million  pounds, 
valued  at  210  million  dollars,    compared  with  489  million  pounds. 


See  also  table  22B,  part  III,  which  lists  these  products  alphabetically  and  identifies 
the  manufacturers. 


46 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  22A,- -Synthetic  organic  chemicals:   United  States  production  and  saies   of  elastomers 
(synthetic  rubbers),^  1953 

[Listed  below  are  all  synthetic  elastomers  for  which  reported  data  on  production  or  sales  may  be  published. 
(Leaders  are  used  where  the  reported  data  are  confidential  and  may  not  be  published  or  where  no  data  were 
reported.)  Table  22B  in  part  III  lists  alphabetically  all  elastomers  for  which  data  on  production  or  sales 
were  reported  and  identifies  the  manufacturer  of  each] 


Produc- 
tion^ 


Sales^ 


Quantity 


Grand  total 

ELASTOMEHS,  CYCLIC 

Polybutadiene-styrene  type  (GR-S,  Buna  S),  total 

Produced  at  Government  plants 

Produced  at  private  plants 

ELASTOMERS,  ACYCLIC 

Total 

Products  for  which  separate  statistics  may  not  be  shown' — 
Products  for  which  separate  statistics  are  shown  below 

Polybutadiene-acrylonitrile  type  (N-type) 

Polyohloroprene  type  (GR-M,    Neoprene) 

Polylsobutylene-isoprene  type  (GR-I,   Butyl) 

Polyvinyl  type* 


1,000 

pounds 

1,958,350 


1,000 
pounds 
1,908,793 


1,000 
dollars 
529,36A 


tO.28 


1,4U,94^ 


ij-iUjOgy 

1,847 


sOj/we 


1,387,198 


31?,056 


521,595 


210,308 


23,567 
519,839 


22,819 
A98,776 


16, 762 
193,546 


45,244 
180,308 
175,923 
118, 364 


42,758 
168,502 
174,576 
112,940 


21,586 
69,086 
37,500 
65,374 


.58 


^  An  elastomer  is  defined  as  a  material  which  can  be  stretched  repeatedly  to  150  percent  or  more  of  normal 
length  and  will  return  rapidly  and  with  force  to  its  approximate  original  state. 

^  Statistics  on  production,  except  for  polyvinyl  and  miscellaneous  elastomers,  are  as  reported  to  the  Re- 
construction Finance  Corporation  and  to  the  U.  S.  Department  of  Commerce. 

^   The  quantities  of  sales  of  polybutadiene-styrene,  polychloroprene,  and  polyisobutylene-isoprene  types  of 
elastomers,  shown  above,  are  calculated  from  data  on  consumption,  foreign  trade,  and  inventories  as  published 
by  the  Department  of  Commerce.  Values  of  sales  of  elastomers  produced  for  the  Reconstruction  Finance  Corpora- 
tion are  derived  from  the  base  prices  as  established  by  that  Office.  The  quantities  and  values  of  sales  of 
polyisobutylene,  polyvinyl,  and  miscellaneous  elastomers  were  reported  to  the  U.  S.  Tariff  Commission. 

*  Calculated  on  rounded  figures. 

'  Includes  data  for  chlorinated  rubber,  polyisobutylene,  silicone,  and  thiokol  elastomers. 

'  Includes  data  for  polyvinyl  butyral,  polyvinyl  alcohol,  and  polyvinyl  chloride  elastomers. 

valued  at  188  million  dollars,    in  1952.    The  acyclic  group  of 
elastomers  includes  oil-resistant  types  such  as  neoprene,    GR-I, 
or  butyl  rubber  (used  almost  entirely  in  the  manufacture  of  inner 
tubes  for  tires),    vinyl  elastomers,    and  silicones. 

Plasticizers 

Plasticizers  are  organic  chemicals  which  are  used  with  plastic 
materials  to  extend  or  modify  the  natural  properties  of  the  resins 
and  to  impart  improved  properties  that  are  not  inherent  in  the 
resins  themselves.    Statistics  on  the  production  and  sales  of 
plasticizers  in  1953  are  given  in  table  Z3A.^ 

The  output  of  all  plasticizers  in  1953  amounted  to  293  million 
pounds.  This  is  the  largest  output  on  record,    despite  the  fact  that 
certain  esters  of  lauric,    oleic,    and  stearic  acids  included  as  part 
of  the  plasticizers  group  in  previous  years  were  reclassified  and 
transferred  to  the  section  on  surface-active  agents  in  1953.    The 
production  of  these  transferred  items  in  1953  amounted  to  approxi- 
mately 17  million  pounds.    Sales  of  all  plasticizers  in  1953  were 
235  million  pounds,    valued  at  83  million  dollars. 


See  also  table  23B,  part  III,  which  lists  these  products  alphabetically  and  identifies 
the  manufacturers. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


47 


izers,    1953 


TABLE  23A.- -Synthetic   organic  chemicals:    United  States  production  and  sales  of  plasti 

[Listed  below  are  all  plastioizers  for  which  reported  data  on  production  or  sales  may  be  published.  (Leaders 
are  used  where  the  reported  data  are  confidential  and  may  not  be  published  or  where  no  data  were 
reported.)  Table  23B  in  part  III  lists  all  plastioizers  for  which  data  -    -^■-^'  —i""  ""- 

reported  and  identifies  the  manufacturer  of  each] 


production  or  sales  were 


Grand  total - 


PLASTICIZERS,  CYCLIC 


Chemicals  for  which  separate  statistics  may  not  be  shown^- 
Chemicals  for  which  separate  statistics  are  shown  below 


Phosphoric  acid  esters: 
Tricresyl  phosphate'— 
Triphenyl  phosphate — 


Phthalio  anhydride  esters, 
Dibutyl  phthalate- 


Dioapryl  phthalate 

Diethyl  phthalate ■ — 

Di(2-methoxyethyl)  phthalate  (Di(methyl  oellosolve)  phthalate)- 
Dimethyl  phthalate- 


Dioctyl  phthalates,  total 

Di ( 2-ethylhexyl)  phthalate 

Di-n-octyl  phthalate,  diiso-ootyl  ph-'halate,  and  mixtures- 

Octyl  decyl  phthalate ■ 

All  other 


Produc- 
tion 


PLASTICIZERS,  ACYCLIC 
Total 

Chemicals  for  which  separate  statistics  may  not  be  shown* 
Chemicals  for  which  separate  statistics  are  shown  below — 


Adipic  acid  esters,  total — 
Di(2-ethylhexyl)  adipate- 

Diiso-octyl  adipate 

All  other 


Laurie  acid  esters- 


Oleio  acid  esters,  total- 
Butyl  oleate- 


Glyceryl  trioleate' 
All  other 


Phosphoric  acid  esters— 

Riolnoleic  and  aoetylrioinoleic  acid  esters- 


Sebacic  acid  esters,  total — 

Dibutyl  sebaoate 

Di(2-«thylhexyl)  sebacate- 
All  other 


Stearic  acid  esters,  total- 
Butyl  stearate 

All  other — -— _— — 


1,000 
pounds 
292,898 


223,810 


29,046 
194,764 


22,109 
7,418 


165,237 


23,280 
7,762 
17,584 
2,240 
2,508 
84,813 
51,281 
33,532 
8,678 
18,372 


69,088 


Quantity 


235,066 


180,137 


22,893 
157,244 


21,043 
3,289 


132,912 


18,256 
9,398 
12,307 

2J734 
66,423 
38,640 
27,783 

8,130 
15,664 


54,929 


1,000 

dollars 

83,335 


59,955 


7,360 
52,595 


6,866 
1,206 


28,500 
40,588 


9,177 


3,497 
1,511 
4,169 


1,372 
3,214 
3,366 

8,534 

4,572 

5,701 


2,186 
2,498 
1,017 

4,539 


2,417 
2,122 


28,168 
26,761 


6,060 


2,045 
1,276 
2,739 


5,628 


3,323 
2,305 


6,398 


5,372 
3,091 
3,096 

696 
23,193 
13,704 
9,489 
2,938 
6,137 


23,380 


Unit 
value ^ 


11,328 
12,052 


2,722 


896 

589 

1,237 

42 

1,756 


2,432 

1,987 


4,150 


2,121 
2,029 


838 
918 


2,898 


1,736 
1,809 


1,089 


471 
618 


$0.35 


.40 
.45 


.45 
.44 
.46 
.45 

.40 

.31 

.25 


■  26 
.22 
.30 


^  Calculated  on  rounded  figures. 

*  Includes  data  for  phosphoric  acid  esters,  synthetic  caaiphor,  toluenesulfonamides,  tetrahydrofurfuryl 
oleate,  and  other  cyclic  plastioizers. 

'  Includes  data  for  material  reported  for  use  as  motor-fuel  additive. 

*  Includes  data  for  palmitic,  citric  and  acetylcitric,  azelaio,  pelargonlo,  and  tartaric  acid  esters,  and 
for  butyl  myristate,  glyceryl  and  glycol  esters  of  certain  fatty  acids,  glyceryl  tripropionate,  and  complex 
polymeric  plastioizers. 

'  Includes  data  for  material  reported  for  use  as  surface-active  agent. 

NOTE. — Because  of  changes  in  major  use  in  recent  years,  data  for  certain  esters  of  laurio,  oleic,  and 
stearic  acids  which  were  classified  as  plasticizers  in  1952  are  classified  as  surface-active  agents  in  1953 
and  data  on  their  production  and  sales  will  be  Incliided  in  the  section  of  the  report  covering  surface-active 
agents. 

Production  of  all  plasticizers  In  1953  would  have  been  17  million  pounds  larger — 5.8  percent  of  the  total 
output — If  the  data  had  included  production  of  the  same  lauric,  stearic,  and  oleic  acid  esters  as  were  in- 
eluded  in  1952. 


48  UNITED  STATES  TARIFF  COMMISSION 

Production  of  cyclic  plasticizers  in  1953  (consisting  principally 
of  esters  of  phosphoric  acid  and  phthalic  anhydride)  amounted  to 
224  million  pounds,    or  29.4  million  pounds  more  than  the   194 
million  pounds  reported  for  1952.    Sales  of  cyclic  plasticizers  in 
1953  were  180  million  pounds,    valued  at  60  million  dollars,    com- 
pared with  145  million  pounds,    valued  at  51  million  dollars,    in 
1952.    Because  of  their  versatility  and  relative  economy,    the 
phthalic  anhydride  esters  are  by  far  the  most  important  plasticizers 
in  the  cyclic  group.    In  1953  this  group  accounted  for  more  than 
half  the  total  domestic  production  of  plasticizers. 

Production  of  acyclic  plasticizers  in  1953,    consisting  mainly 
of  esters  of  adipic,    oleic,    phosphoric,    ricinoleic,     sebacic,    and 
stearic  acids,    amounted  to  69  million  pounds;    sales  were  55 
million  pounds,    valued  at  23  million  dollars.    In  previous  years 
some  esters  of  lauric,    oleic,    and  stearic  acids  that  are  now 
reported  as  surface-active  agents  were  included  in  the  plasticizers 
group.    The  statistics  for  1953  on  acyclic  plasticizers,    therefore, 
are  not  strictly  connparable  with  those  for  earlier  years.    Of  the 
acyclic  plasticizers,    the  adipic  acid  esters  were  produced  in  the 
largest  volume  in  1953;  production  of  them  amounted  to  9  million 
pounds. 

Surface-Active  Agents 

The  surface -active  agents  covered  in  this  report  include 
synthetic  organic  detergents,    wetting  agents,    and  emulsifying 
agents;   soaps  are  not  included.    As  the  data  are  given  in  terms  of 
100-percent  active  material,    they  exclude  all  inorganic  salts, 
water,    and  other  diluents. 

Although  they  were  originally  developed  as  soap  substitutes, 
surface -active  agents  have  proved  valuable  in  many  other  appli- 
cations because  of  their  varied  and  specific  properties.    They  are 
especially  valuable  as  detergents  in  hard  water,    since  they  do  not 
form  insoluble  precipitates,    as  some  soaps  do.    For  certain  in- 
dustrial purposes,     surface-active  agents  are  used  as  emulsifying 
and  wetting  agents  for  agricultural,    leather,    and  textile  chemicals. 
They  are  also  used  in  dentifrices  and  shampoos. 

Statistics  on  production  and  sales  of  surface -active  agents  in 
1953  are  given  in  table  24A.^     In  1953  production  of  surface-active 
agents  as  a  group  totaled  922  million  pounds,    or  24.3  percent 
more  than  the  741  million  pounds  reported  for  1952.    Sales  in  1953 
were  732  million  pounds,    valued  at  145  million  dollars,    compared 
with  612   million  pounds,    valued  at  120  million  dollars,    in  1952. 

In  1953  the  production  of  anionic  surface-active  agents 
(sulfated  and  sulfonated  cyclic  and  acyclic  compounds  and  acyclic 
salts  of  fatty  acids)  amounted  to  752  million  pounds,    or  116  mil- 
lion pounds  more  than  the  output  in  1952.    Sales  in  1953  totaled 
580  million  pounds,    valued  at  93  million  dollars,    compared  with 
532  million  pounds,    valued  at  88  million  dollars,    in  1952.    In 
volume  of  production,    in  1953,    the  principal  items  in  this  group 
were  the  following:     The  dodecylbenzenesulfonic  acid  type  of 
surface -active  agent  (364  million  pounds);  sulfonated  petroleum 
aromatic  compounds  (129  million  pounds);  and  sulfated  and  sul- 
fonated alcohols  (127  million  pounds). 


^^  See  also  table  24B,  part  III,  which  lists  these  products  alphabetically  and  identifies 
the  manufacturers. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


49 


TABLE  24A. --Synthetic   organic  chemicals:    United  States  production  and  sales  of  sur face- act ive  agents,'    1953 

[Listed  below  are  all  surface-active  agents  for  which  reported  data  on  production  or  sales  may  be  published. 
(Leaders  are  used  where  the  reported  data  are  confidential  and  may  -ot  be  published  or  where  no  data  were 
reported.)  Table  24B  in  part  III  lists  all  surface-active  agents  for  which  data  on  production  or  sales 
were  reported  and  identifies  the  manufacturer  of  each] 


ftuantity 


Unit 
value  ^ 


Grand  total 

SURFACE-ACTIVE  AGENTS,  CYCLIC 

Total 

Esters  and  ethers,  nonsulfonated^ 

Nitrogen-containing  surface-active  agents,  nonsulfonated, 

total* 

Benzyllauryldimethylammonium  chloride 

All  other 

Sulfated  and  sulfonated  cyclic  surface-active  agents,  total 

Alkyl  benzenoid  compounds,  sulfated  and  sulfonated:  Dodeoyl- 

benzenesulfonic  acid  type 

Naphthalene  derivatives,  sulfonated,  total 

Amylnaphthalenesulfonic  acid,  mono  and  di 

Butylnaphthalenesulfonic  acid,  mono  and  di ■ 

Isopropylnaphthalenesulfonic  acid,  mono 

Isopropylnaphthalenesulfonio  acid,  di ■ 

All  other 


Petroleum  aromatic  compounds,  sulfonated,  total- 


Acid-layer-type  petroleum  sulfonate,  sodium  salt 

Oil-layer-type  petroleum  sulfonate,  sodium  salt 

All  other 


All  other  sulfated  and  sulfonated  cyclic  surface-active 
agents ' 


SURFACE-ACTIVE  AGENTS,  ACYCLIC 


Esters  and  ethers,  nonsulfonated,*  total - 
Diethylene  glycol  monolaurate- 


Diethylene  glycol  mono-oleate 

Diethylene  glycol  monostearate 

Ethylene  glycol  monostearate 

Glyceryl  mono-oleate 

Glyceryl  monostearate- 


Polyethoxyethyl  castor  oil  ester 

Polyethoxyethyl  coconut  oil  ester 

Polyethoxyethyl  dioleate 

Polyethoxyethyl  laurate,  mono  and  di 

Polyethoxyethyl  mono-oleate- 


Polyethoxyethyl  stearate,  mono  and  di- 

1,2-Propylene  glycol  monostearate 

All  other 


Nitrogen-containing  surface-active  agents,  nonsulfonated,  total 
N-(Aminoethyl)-N-(hydroxyethyl)stearamide  (Stearamide  of 

aminoethylethanolamine ) 

Coconut  oil  amide  of  monoCdiethanolamine)  (Diethanol 

lauramide ) , 

Coconut  oil  amide  of  bis(diethanolamine) 

N,N-Di(2-hydroxyethyl)oleamide  (Diethanol  oleamide) 

(Diethanolamine  oleate ) — — - 

N,N-Di(2-hydroxyethyl)stearamide  (Diethanol  stearamide) 

Stearajnide  of  diethylenetriamine — 

Stearamide  of  tetraethylenepentajnine 

All  other' 

Phosphorus-containing  surface-active  agents,  nonsulfonated 

Salts  of  fatty  acids,  nonsulfonated,  total 

Coconut  oil,  potassium  salt 

Potassium  oleate — — — —    — — 

Pot  as  s  ium  r  e  s  inate ... __ 

Potassium  tallate— — — 

Sodium  oleate 

All  other __  

See  footnotes  at  end  of  table. 


1.000 
wands 

921,594 


594,089 


41,991 


1,383 
3,775 


546,940 


364,241 

5,970 

111 

1,194 

293 

2,527 

1,845 

129,070 

12,299 

59,580 

57,191 

47,659 


327,505 


69,885 


692^ 

482 

642 

326 

2,524 

11,876 

544 

247 

147 

764 

1,410 

5,479 

360 

44,390 

52,804 


1,043 

4,357 
4,767 

934 

290 

196 

34 

41,183 

773 

6,881 


131 
603 
319 
85 
704 
5,039 


1,000 
pounds 

732,104 


438,491 


30,923 


4,686 


1,329 
3,357 


402,882 


249,057 

4,819 

87 

1,270 

209 

2,132 

1,121 

101,799 

10,812 

50,304 

40,683 

47,207 


293,613 


65,649 


474 
333 
480 
323 
2,495 
10,808 

86 
137 
553 
834 
4,898 
348 
43,880 

50,372 


951 

4,124 
3,583 

928 
255 
188 
32 
40,311 

685 

6,939 


131 
529 
408 
78 
697 
5,096 


1,000 
hilars 

144,972 


73,301 


11,8 


2,827 
57,676 


36,034 

1,780 

48 

598 

81 

798 

255 

14,607 

642 

7,182 

6,783 

5,255 


71,671 


20,082 


178 
116 
131 
115 
687 
3,066 

34 

53 

194 

336 

1,776 

101 

13,295 

16,183 


938 

1,836 
1,654 

372 
124 
137 
32 
11,090 

382 

1,101 


34 
106 
183 

10 
150 
618 


Per 
pound 

$0.20 


T38 
.35 
.27 
.36 
.28 
.28 


.35 
.40 
.36 


.45 
.46 

.40 
.49 
.73 
1.00 
.28 

.56 


.16 
.26 
.20 
.45 
.13 
.22 
.12 


50 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  24A. --Synf/ietic  organic  chemicals:    United  States  product i 
surface-active   agents,^   1953- -Continued 


and  sales  of 


Quantity 


Unit 
valufi^ 


SURFACE-ACTIVE  AGENTS,  ACYCLIC— Continued 

Sulfated  and  sulfonated  acyclic  surface-active  agents,  total - 

Acids,  sulfated  and  sulfonated,  total 

Oleic  acid,  sulfonated  (Sulfonated  red  oil) 

Alcohols  and  esters,  sulfated  and  sulfonated,  total 

Glycerol  tri(sulfo-oleat9) 

Isopropyl  sulfo-oleate- 


1.000 
pounds 

197.162 


Lauryl  sulfate,  trlethanolamine  salt- 

n-Propyl  sulfo-oleate 

All  other 


Nitrogen-containing  surface-active  agents,  sulfated  and  sul- 
fonated ,  total 

Coconut  oil  ajnide  of  monoethanolajnine ,  sulfated,  sodium 

N-Methyloleoyltaurine ,  sodium  salt 

All  other 


Oils,  fats,  and  waxes,  sulfated  and  sulfonated,  total — 
Animal  fats  and  oils,  sulfated  and  sulfonated: 

Neat's-foot  oil,  sulfonated — 

Tallow,  sulfonated 

Fish  and  marine-animal  oils,  sulfated  and  sulfonated: 

Cod  oil,  sulfonated 

Herring  oil,  sulfonated — ~ 

Menhaden  oil,  sulfonated 

Sperm  oil,  sulfonated 

Tall  oil,  sulfonated- 


Vegetahle  oils,  sulfated  and  sxilfonated,  total - 
Castor  oil,  sulfonated- 


Coconut  oil,  sulfonated- 

Com  oil,  sulfonated 

Peanut  oil,  sulfonated- 
Rioe-bran  oil,  sulfonated- 

Soybean  oil,  sulfonated 

All  other- 


All  other  oils,  fats,  and  waxes,  sulfated  and  sulfonated* — 


5,461 

2,469 

2,992 

126,742 

390 

719 

2,522 

1,820 

121,291 

7,250 

528 

6,722 
57,709 

1,733 
12,382 

5,923 
3,734 

609 
5,852 

808 
13,765 
7,115 

586 

672 
1,536 
1,049 
1,250 
1,557 
12,903 


1,000 
pounds 
169,968 


33,923 


5,190 

2,050 

3,140 

117,135 

173 

699 

2,628 

1,643 

111,992 

4,961 

505 

2,817 

1,639 

42,682 

1,579 
10,711 

4,316 
722 
555 

2,747 
703 

8,798 

5,294 
456 

1,252 

283 

557 

956 

12,551 


1,322 

673 

649 

23,355 

50 

378 

822 

357 

21,748 

2,179 

351 
1,243 

585 
7,067 

280 
1,285 

589 

90 

66 

443 

104 

■2,195 

1,336 

122 

362 

89 

151 

135 

2,015 


Per 
pound 
$0.20 


.25 
.33 
.21 
.20 
.29 
.54 
.31 
.22 


^   Data  are  given  in  terms  of  bulk  surface-active  agents,  that  is,  in  terms  of  100-percent  content  of  sur- 
face-active agents,  exclusive  of  all  inorganic  salts,  water,  or  other  ingredients. 

*  Calculated  on  rounded  figures. 

3  Includes  polyhydric  alcohol  ethers  and  esters. 

*  Includes  quaternary  ammonium  compounds. 

'  Includes  sulfated  and  sulfonated  phenyl  ethers,  substituted  biphenyls,  sulfonated  lignin  derivatives,  ai 
a  small  amount  of  sulfated  and  sulfonated  aliyl  benzenoid  compounds. 

*  Includes  certain  lauric,  oleic,  and  stearic  acid  esters  reported  as  plasticizers  for  1952. 

'  Includes  amine  salts  of  fatty  acids;  esters  of  hydroxyamines ;  fatty  acid  amines;  quaternary  ammonium 
compounds;  salts  of  nltrilo  acids;  and  fatty  acid  derivatives  of  guanldine,  glycine,  polypeptides,  and 
others. 

*  Includes  sodium  salt  of  petroleum  sulfonate,  sulfonated  recovered  grease,  sulfonated  lanolin,  sul- 
fonated lard  oil,  sulfonated  wool  grease,  and  others. 


Production  in  1953  of  cationic  surface-active  agents  (all  cyclic 
and  certain  acyclic  nitrogen-containing  compounds,  nonsulfonated) 
was  8  million  pounds;  sales  totaled  8  million  pounds,  valued  at  6 
million  dollars.  Because  of  changes  in  classification  in  1953,  data 
on  production  and  sales  of  cationic  and  nonionic  surface -active 
agents  in  that  year  are  not  comparable  with  the  data  on  production 
and  sales  in  1952  or  earlier  years. 

In  1953  the  output  of  all  polyhydric  alcohol  esters  and  ethers 
and  those   acyclic  nonsulfonated  nitrogen-containing  compounds 
generally  considered  to  be  nonionic  materials  totaled  l6l  million 
pounds.    Sales  in  1953  totaled  144  million  pounds,    valued  at  46 
million  dollars. 


SYNTHETIC  ORGANIC  CHEMICALS,  I953 
Pesticides  and  Other  Organic  Agricultural  Chemicals 


51 


The  pesticides  and  other  organic  agricultural  chemicals 
covered  in  this  section  include  such  materials  as  fungicides,    seed 
disinfectants,    herbicides,    plant  hormones,    insecticides,    rodenti- 
cides,    fumigants,    and  soil   conditioners.    As  in  other  sections  of 
this  report,    the  data  (except  where  otherwise  indicated)  are  given 
in  terms  of  100 -percent  active  material,    thus  excluding  such  ma- 
terials as  wetting  agents,    emulsifiers,    and  diluents.    Statistics  on 
production  and  sales  of  pesticides  and  other  organic  agricultural 
chemicals  in  1953  are  given  in  table  25A. 

TABLE  2SA.  "Synthetic    organic  chemicals:    United  States  production  and  sales  of  pesticides  and  other   organic 

agricultural  chemicals,    1953 

[Listed  telow  are  all  pesticides  and  other  organic  agricultural  chemicals  for  which  any  reported  data  on 
production  or  sales  may  be  published.  (Leaders  are  used  where  the  reported  data  are  confidential  and  may 
not  be  published  or  where  no  data  were  reported.)  Table  25B  in  part  III  lists  all  pesticides  and  other 
organic  agricultural  chemicals  for  which  data  on  production  or  sales  were  reported  and  identifies  the 
manufacturer  of  each] 


Sales 


Quantity 


Unit 
value  ■"■ 


Grand  total 
PESTICIDES  AND  OTHER  ORGANIC  AGHICULTDHAL  CHEMICAI£ .  CYaiC 


1,000 
pounds 
355,953 


i.OOO 
tounds 

334,1-46 


1.000 
dollars 

118,517 


Per 
pound 
$0,35 


297, 05A 


281,652 


98,572 


.35 


Fungicides  and  seed  disinfectants,  total- 

Naphthenlc  acid,  copper  salt 

Phenyl  mercuric  oleate- 


44.832 


37,618 


8-Quinollnol  (8-Hydroxyquinoline),  copper  salt- 
All  other 


Herbicides  and  plant  hormones,  total 

Naphthalene-  and  naphthoxyacetlc  acid  derivatives- 
Phencocyacetic  acid,  salts  and  derivatives: 

2,4-Dichlorpphenoxyacetic  acid  (2,4-D) 

2,4-Dlchlorpphenaxyacetic  acid  esters 
2,4-I)ichlorcpheno3cyacetlc  acid  salts- 


41,517 
64,349 


2,4,5-Trichlorqph6noxyacetlc  acid  (2,4,5-T)- 


2,4,5-Trlchlorqphenoxyaoetlc  acid  derivatives- 

Phenyl  mercuric  acetate 

All  other^ 


Insecticides,  total 
Hoxachlorocyolohexane  (Benzene  hegachlorlde)'* 
Parathion  (0,0-Diethyl  O-(p-nitrciphenyl)  thiophosphate)— — 
l,l,i-Trichloro-2,2-bls(p-chlorophenyl)ethan9  (DDT) 
All  other* 

PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL  CHIWICALS,  ACYCLIC 

Total 

Fumigants,  fungicides,  seed  disinfectants,  and  herbicides,  total 

Fumigants:  Bromomethane  (Methyl  bromide; 

Fungicides  and  seed  disinfectants: 


50 

25,928 
18,826 
4,836 
5,281 
5,386 
154 
3,888 

187.873 


62 

166 

34,426 

49.235 


12,424 


57,363 

2,999 

84,366 

43,145 


37 


14,554 
4,968 

4^005 

139 

25,532 

194.799 


652 

245 

388 

11,139 

31.498 


60,934 


85,758 
48,107 


121 


7,603 
2,120 

5J800 

518 

15,336 

54.650 


.33 

■~T5r 

3.95 

2.34 

.32 

.64 
3.27 


.52 
.43 

i!45 

3,73 

.60 


55.054 


Dimethyldithiocarbamlo  acid,  sodium  salt- 


dmethyldithlocarbanlc  acid,  zinc  salt  (Zlram)- 
All  other 


6,167 

538 
1,152 

47,197 


49.183 


21,357 
26,405 


19,945 


Insecticides  and  soil  conditioners,  total- 
Tetraethyl  pyrophosphate  (TEPP)' — 
AU  other' 


229 
3,616 


5,750 

539 

1,176 

41,718 

3,311 


16,676 


2,771 

342 

694 

12,869 


.38 
.34 
"7^ 


.63 
.59 
.31 


716 
2,595 


611 
2,658 


^  Calculated  on  rounded  figures. 

^  Includes  such  materials  as  dlnltro  con^iounds,  isqprppylphenylcarbamate,  maleic  hydrazlde,  and  a  small 
amount  of  phenoxyacetic  acid  derivatives. 

^  Production  of  the  gamma  isomer  content  in  benzene  hexechloride  totaled  8.8  million  pounds;  sales 
amounted  to  8.9  million  pounds, 

*  Includes  aldrin,  allethrin,  chlordane,  dieldrln,  DDD,  EPN,  lindane,  toxaphene,  and  a  small  amount  of 
rodenticldes . 

9  TEPP  is  40jt  tetraethyl  pyrophosphate. 

'  Includes  a  small  amount  of  rodenticldes. 


^^  See  also  table  25B,  part  III,  which  lists  these  products  alphabetically  and  identifies 
the  manufacturers. 


52  UNITED  STATES  TARIFF  COMMISSION 

In  1953  production  of  all  pesticides  and  other  organic  agricul- 
tural chemicals  amounted  to  356  million  pounds,  a  decline  of  14.8 
percent  from  the  418  million  pounds  reported  for  1952.  The  decline 
was  due  in  part  to  the  existence  of  large  stocks  on  hand  at  the  end 
of  1952.  Sales  in  1953  amounted  to  334  million  pounds,  valued  at 
119  million  dollars,  compared  with  331  million  pounds,  valued  at 
133  million  dollars,    in  1952. 

Production  of  all  insecticides  (both  cyclic  and  acyclic)  in  1953 
was  about  192  million  pounds,    or  53.9  percent  of  the  total  output  of 
all  organic  pesticides.    Sales  in  1953  totaled  198  million  pounds, 
valued  at  58  million  dollars. 

In  1953  the  output  of  cyclic  pesticides  and  other  cyclic  chemi- 
cals in  this  group  totaled  297  million  pounds,    or  20.1  percent  less 
than  the  372  million  pounds  produced  in  1952.    Sales  in  1953  were 
282  million  pounds,    valued  at  99  million  dollars,    compared  with 
289  million  pounds,    valued  at  1 1 1  million  dollars,    in  1952. 

Production  of  cyclic  insecticides  in  1953  amounted  to  188 
million  pounds,     or  63.2  percent  of  the  total  output  of  cyclic  pesti- 
cides.   The  chemical  in  this  subgroup  that  was  produced  in  the 
greatest  quantity  in  1953  was  the  insecticide  DDT,    production  of 
which  amounted  to  84  million  pounds. 

Production  of  acyclic  pesticides  and  other  acyclic  organic 
agricultural  chemicals  in  1953  amounted  to  59  million  pounds, 
compared  with  the  46  million  pounds  reported  for  1952.    Sales  in 
1953  were  52  million  pounds,    valued  at  20  million  dollars,    com- 
pared with  42  million  pounds,    valued  at  23  million  dollars,    in  1952. 

Miscellaneous  Synthetic  Organic  Chemicals 

As  used  in  this  report,   the  term  "miscellaneous  synthetic 
organic  chemicals"  includes  products  such  as  halogenated  hydro- 
carbons,   paint  driers,    photographic  chemicals,    solvents,    and 
tanning  materials  that  are  not  included  in  the  use    groups    covered 
in  the  other  sections  of  this  report.    In  1953  the  production  of  these 
miscellaneous  chemicals  as  a  group  was  17,669  million  pounds,    an 
increase  of  11.2  percent  from  the   15,894  million  pounds  reported 
for  1952.     Sales  in  1953  totaled  7,804  million  pounds,    valued  at 
1,236  million  dollars,    compared  with  7,289  million  pounds,    valued 
at  1,146  million  dollars,     in  1952.    Statistics  on  production  and  sales 
of  miscellaneous  chemicals  in  1953  are  given  in  table  26A. 

In  1953  the  output  of  cyclic  miscellaneous  chemicals  as  a  group 
totaled  402  million  pounds,    an  increase  of  10.9  percent  from  the 
363  million  pounds  reported  for  1952.    Hexamethylenetetramine, 
used  in  phenolic  resins,    is  one  of  the  most  inaportant    chennicals 
in  this  group;  in  1953  the  output  of  this  product  totaled  56  million 
pounds.    Sales  of  cyclic  miscellaneous  chemicals  as  a  group  in 
1953  totaled  262  million  pounds,    valued  at  83  million  dollars, 
compared  with  243  million  pounds,    valued  at  78  million  dollars, 
in  1952. 

Production  of  acyclic  miscellaneous  chemicals  as  a  group  in 
1953  totaled  17,267  million  pounds,    an  increase  of  11.2  percent 
compared  with  the  output  of  15,531  million  pounds  reported  for  1952. 


See  also  table  26B,  part  III,  which  lists  these  products  alphabetically  and  identifies 
the  manufacturers. 


SYNTHETIC  ORGANIC  CHEMICALS,  I953 


53 


TABLE  26A.- -Synthetic  organic  chemicals:    United  States  production  and  sales  of  miscellaneous  chemicals.   1953 

[Listed  below  are  all  miscellaneous  chemicals  for  which  any  reported  data  on  production  or  sales  may  be  pub- 
^   lished  (i^eaders  are  used  where  the  reported  data  are  confidential  and  may  not  be  published  or  "here  no 
data  were  reported.)  Table  26B  in  part  III  lists  alphabetically  all  miscellaneous  chemicals  for  which 
data  on  production  or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Grand  total- 


MISCELLAMEOUS  CHEMICALS,  CYCLIC 


Total 


Chemicals  for  which  separate  statistics  may  not  be  shown 

Chemicals  for  which  separate  statistics  are  shown  below 

Benzoic  acid  salts:  Sodium  benzoate,  tech.  ana  U.S.P 

Benzoyl  peroxide 

Centralite  (N, N' -Diethyl-N, N'-diphenylurea ) 

Chemical  reagents 

Chlorophyll  and  ehlorophyllins 

Cyclopropane 


Flotation  reagents,  total 

Thlocarbanilide  (Diphenylthlourea)- 
All  other 


Production 


17,669,436 


Hexamethylenetetramine,  tech — 

Lubricating  oil  additives 

4-Methyluinbelliferone 

Naphthenic  acid  salts,  total^ 

Calcium  naphthenate 

Cobalt  naphthenate 

Iron  naphthenate 

Lead  naphthenate- 


Manganese  naphthenate- 
Zino  naphthenate—-—— 
All  other 


Organic  mercury  compounds* 
Photographic  chemicals,  total 


p-Dlazo-N,N-diethylanlline,  zinc  chloride "salt 

p-Diazo-N,N-dlmethylanillne,  zinc  chloride  salt 

p-Dlazo-N-ethyl-N-hydroxyethylaniline,  zinc  chloride  salt- 
All  other' 


n-Propyl  gallate 

Rosin  acid  salts,  totals- 
Calcium  resinate 


Manganese  reslnate- 
All  other 


Tall  oil  salts,  totals- 
Cobalt  tallate 

Iron  tallate 


Lead  tallate 

Manganese  tallate- 
All  other 


Tanning  materials,  total 


Naphthalene  condensates,  total 

2-Naphthalene3ulfonic  acid,  formaldehyde  condensate  and 

salt 

All  other- 


All  other  tanning  materials*- 


MISCELLANEOUS  CHEMICALS,  ACYCLIC 


402,309 


152,742 
249,567 


5,169 

1,792 

2,076 

15 

21 

106 

3,733 


3,347 

55,854 

115,194 

194 

19,540 


Sales 


Quantity    Value 


7,803,865 


262,315 


117,993 
144,322 


4,460 

1,084 

2,167 

14 

24 

90 


1,339 
4,287 

278 
9,864 
2,375 
1,136 

261 

86 

4,003 


45 

27 

17 

3,914 

66 

1,018 


224 
755 


4,907 


2,112 
51 

1,754 
557 
433 

35.793 


2,981 

47,315 

23,090 

177 

19,198 


1.000 
dollars 

1,236,004 


82,566 


33,914 
48,652 


1,641 
747 
1,900 
94 
1,360 
1,611 


1,275 
3,993 

9,72' 

2,4S4 

1,240 

484 

66 


1,151 

9,212 

9,357 

289 

6,919 


3,855 


32 
240 
833 

4.817 


Chemicals  for  which  separate  statistics  may  not  be  shown- 
Chemioals  for  which  separate  statistics  are  shown  below — 


Acetaldehyde 

Acetic  acid,  synthetic,  100?t' 


24,784 

22,187 
2,597 
11,009 


17,267,127 


4,490,084 
12,777,043 


477,728 


2,027 
70 

1,688 
641 
391 

33.810 


431 
2,518 

2,623 
783 
378 
186 

312 

5,598 


78 

76 

5,352 


7 
61 
198 

1.533 


23,011 

20,626 

2,385 

10,799 


7, 541, 550 


2,011,974 
5,529,576 


34,008 
149,397 


825 
14 
425 
176 
93 

6.662 


3,693 

3,342 

351 
2,969 


1,153,438 


566,188 
587,250 


Unit 
value^ 


2,881 
11,699 


.29 
.34 


.37 

.69 

.88 

6.71 

56.67 

17.90 


.19 

.41 

1.63 


.36 

.34 
.63 

.27 
.32 
.30 
.38 

4.73 


1.42 
3.68 
2.89 
4.47 
1.39 


.28 
.11 


See  footnotes  at  end  of  table. 


54  UNITED  STATES  TARIFF  COMMISSION 

TABLE  26k.  --Synthetic  organic  chemicals:   United  States  production  and  sales  of 
miscellaneous  chemicals,    2953- -Continued 


Quantity    Value 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 


Acetic  acid  salts,  total- 
Aluminum  acetate 

Cobalt  acetate 

All  other — 


Acetic  anhytiride,  lOC^,  from  all  sources 


Acetone,  total- 


From  isopropyl  alcohol 

By  fermentation  and  other  sources- 


Acrylonitrile — 


Amines ,  total- 


n-Butylamine ,  mono 

Methylamine ,  mono — — 

All  other 


Amyl  acetates,  90?t — 

Amyl  alcohols,  lOC^ 

Bis(2-chloroethyl)  ether  (Dichlorodiethyl  ether),  all  grades- 
Butyl  acetates,  9C?t 

Butyl  alcohols,  lOC^,  total 

Primary,  normal 

All  other 


Caprylio  acid  salts- 
Carbon  disulfide 


Cellulose  esters  and  ethers,  total 

Cellulose  acetate-— —      — 

Sodium  carboxymethylcelliilose,  1005^- 
All  other 


Chloral  (Trichloroacetaldehyde) — 

Chloroacetic  acid,  mono 

Citric  acid  salts — 

Diethylene  glycol 

Diethyl  malonate  (Malouie  ester  )- 

2-Dlmethylaminoethanol 

Dipropylene  glycol 


Ethanolamines ,  total 

Monoethanolamine 

Di-  and  triethanolamlnes- 


Ethyl  acetate,  85^ 

Ethyl  alcohol,  synthetic* 

o-Ethylcaproic  (2-Ethyl-l-hexoic )  acid  salts,  total- 
Calcium  a-ethylcaproate — — — 

Cobalt  a-ethylcaproate 

Lead  a.  -ethylcaproate— 

Zinc  a-ethylcaproate 

All  other 


Ethylene  glycol- 
Ethylene  oxide — 


Ethyl  ether,  total- 


Fatty  acid  esters,  not  included  with  plasticlzers 

Fatty  and  synthetic  higher  alcohols  (Cio  and  higher )- 
Flotation  reagents' 


Formaldehyde  {37f>  HCHO  by  weight  )- 
Formic  acid,  90f> 


Formic  acid  salts,  total- 


Sodium  formate,  crude  and  refined- 
All  other 


1,000 
tounds 

15,<420 


^32" 
122 


U,866 
803,540 


518,992 


468, -igi 

50,501 


56,980 
155,189 


274 
1,723 
153,192 

8,302 
20,777 

9,212 
61,545 

392,208 


155,272 
236,936 


95 
501,168 


435,417 
21,669 
169,407 

20,836 
37,504 
6,135 
47,436 
665 
225 
4,227 

53,363 


19,870 
33,493 

80,768 
1,060,283 


2(35" 
271 


67 
657 


624,324 
489,535 


47,326 


Fumaric  aeld- 


6,192 
41,134 

215 

3,057 

36,710 

19,254 

1,118,715 

16,213 

20.734 


18,770 
1,964 

3,829 


1,000 
pounds 

14, 345 


1.000 
dollars 

2,422 


3S5 


13,960 


24^,956 
198,296 


i5zn 

2,268 


19,112 
15,678 


51,245 
32,024 


3,434 
19,260 
10,035 


31,853 

8,178 

5,873 

4,624 

60,276 

118,029 


92,982 
25,047 


77 
480,017 


203,985 


97 

9,938 

1,256 

1,044 

288 

7,377 

14,358 


82,754 
20,005 
101,226 


33,778 
162 

'4,'453 

47,985 


11,816 
2,542 


23,536 
77,741 


27,772 

8,512 

41,457 


6,054 
122 


19,054 
28,931 


69,065 
324,323 


,109 
1§7 
275 
402 
62 
176 


5,307 
6,696 


7,126 
15,329 


224,522 
85,879 


140 
182 
19 
81 

32,207 
15,261 

4,648 


198 

2,213 

23,776 

19,489 

612,659 

13,820 

15.002 


13,096 
1,906 


68 

724 

9,566 

5,527 

20,623 

2,097 

1.040 


573 
467 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  I953 


55 


TABLE  26\.- -Synthetic   organic  chemicals:   United  States  production  and  sales  of 
miscellaneous  chemicals,   1953- -Continued 


Quantity 


Unit 
value^ 


MISCELLANEOUS  CHEMICAI£,  ACYCLIC— Continued 


Halogenated  hydrooarljons,  total- 
Carbon  tetrachloride 


Chlorinated  paraffins- 


Chloroethane  (Ethyl  chloride),  tech.  and  U.S.P- 

Chloroethylene  (Vinyl  chloride  moncmer) 

Chloroform,  tech.  and  U.S.P- 


Chloromethane  (Methyl  chloride),  all  grades- 
1,2-Dlchloroethane  (Ethylene  dichloride)- 


piohloromethane  (Methylene  chloride),  all  grades- 

Tetrachloroethylene  (Perchloroethylene) 

Trichloroethylene 

All  other 


Isopropyl  alcohol-"-"- 
laopropyl  ether 


Lactic  acid,  100^,  total- 
Edible  and  medicinal 

Tech 


Lactic  acid  salts:  Sodium  lactate- 

Linoleic  acid  salts,  total^ 

Calcium  linoleate 

Cobalt  linoleate 


Manganese  linoleate- 
All  other 


Lubricating  oil  additives- 

Methanol,  synthetic^^ 

1-  and  2-Octanol 


Oleic  acid  salts,  total^^- 

Lead  oleate 

All  other 

Oxalic  acid 


Oxalic  acid  salts 

Pal mi toy 1  chloride 

Pentaerythritol 

Pentaerythritol  tetranitrate-  ■■■ 

Propionic  acid—— _____________———— 

Propylene  glycol  (l,2-Propanediol) 

Sequestering  agents:  (Ethylenedinitrilo)tetraacetic  acid 

(Ethylenediaminetetraacetic  acid),  tetrasodium  salt 

Sodium  formaldehydesulfoxylate 

Stearic  acid  salts,  total^-' ■■  '■■' 

Aluminum  stearates,  total ___——————— 

Aluminum  distearate — ' 

All  other 


Barium  stearate — 
Cadmium  stearate- 


Calcium  stearate— 

Lead  stearates 

Lithium  stearate— 
Magnesium  atearate- 

Zinc  stearate 

All  other 


Succinic  anhydride 

Thioglycolio  acid  salts:  Ammonium  thloglyoolate- 
Zinc  foimaldehydesulfoxylato        ■■  ■ 


1.000 
pounds 

3,167,184 


259,705 

33,382 

520,078 

401,701 

25,537 

40,520 

528,646 

63,629 

152,917 

323,313 

817,756 

900,699 
4,977 

4,621 


1,000 
ounds 

1,326,542 

236,501 

32,122 


32, 184 

63,882 

58,782 

136,378 

287,665 

479,028 

397,724 
4,314 


3,143 
1,478 

40 

1,181 


3,067 
1,331 


45 
957 


1,000 
dollars 

159,867 

— I57SSO 

3,935 


3,871 
4,366 
6,601 
13,015 
27,850 
84,229 

21,336 
180 

1,624 


1,275 
349 


654 

349 

61 

117 

49,358 

1,115,770 

7,750 

159 


494 

264 

70 

129 

23,266 

688, 522 

5,912 


70 
153 
24 
45 

6,389 

27,943 

1,058 


92 

107 

18,636 

3,839 

110 

56,325 
1,329 
9,779 

59,646 

3,407 
4,814 

22,025 


7,361 

5,246 

2,115 

209 

17 

3,921 

1,698 

231 

534 

6,475 

1,579 

266 
1,414 
3,470 


73 
115 

18,766 
3,350 

47,820 
1,236 
1,065 

53,958 

3,443 
4,688 

21,656 


7,323 

5,223 

2,100 

197 

15 

3,875 

1,440 

223 

539 

6,355 

1,689 

120 
1,405 
3,514 


3,048 
836 

16,149 

931 

233 

9,182 

2,146 
1,216 

7,340 

2,403 

1,711 

692 

72 

17 

1,363 

593 

137 

205 

2,264 

286 

92 

1,896 

767 


ound 

$0.12 


.07 
.12 


.33 
.33 
.37 
1.13 
.35 
.41 
.61 
.38 
.36 


.77 

1.35 

.22 


^  Unit  values  calculated  on  rounded  figures. 

^  Quantities  are  given  on  the  basis  of  solid  naphthenate,  resinate,  tallate,  or  linoleate  content. 
'  Statistics  exclude  production  and  sales  of  copper  naphthenate.  Statistics  on  copper  naphthenate  are 
given  In  the  section  "Pesticides  and  Other  Organic  Agricultural  Chemioalsv" 

*  Does  not  include  medicinal  mercury  compounds  or  phenyl  mercuric  acetate  used  as  a  pesticide.  Statistics 
on  phenyl  mercuric  acetate  are  given  in  the  section  "Pesticides  and  Other  Organic  Agricultural  Chemicals." 

'  Includes  hydroqulnone,  p-mettaylamlnophenol  sulfate,  catechol,  and  others. 

*  Includes  lignosulfonic  acid  salts,  styrene-malelo  anhydride  Interpolymer,  and  others. 
'  In  addition,  production  of  natural  acetic  acid  totaled  20,387,000  pounds. 

*  Statistics  on  production  of  ethyl  alcohol  from  natural  sources  by  fermentation  are  issued  by  the  Alcohol 
Tax  Unit,  U.  S.  Bureau  of  Internal  Revenue. 

'  Includes  dithiophosphates,  fatty  amine  salts,  xanthates,  and  others. 

^°   Data  which  were  reported  on  the  basis  of  91  percent  isopropyl  alcohol  have  been  converted  to  a  100- 
peroent  basis. 

^^  In  addition,  production  of  methanol  from  natural  sources  totaled  13,173,760  pounds. 

^^  Statistics  exclude  production  and  sales  of  potassium  and  sodium  oleates.  Statistics  on  these  oleates  are 
given  in  the  section  "SurfaoeWiotlve  Agents." 

^^  Statistics  exclude  production  and  sales  of  sodium  stearate.  Statistics  on  sodium  stearate  are  given  in 
the  section  "Surface-Active  Agents." 


56  UNITED  STATES  TARIFF  COMMISSION 

Sales  in  1953  totaled  7,542  million  pounds,    valued  at  1,153  million 
dollars,    compared  with  7,046  million  pounds,    valued  at  1,068  mil- 
lion dollars,    in  1952.    This  group  consists  chiefly  of  solvents,  re- 
frigerants,   and  acyclic  intermediates.-'-^ 

In  1953  the  output  of  halogenated  hydrocarbons  (a  group  con- 
sisting of  chlorine,   bromine,    fluorine,    and  iodine  derivatives  of 
hydrocarbons)  totaled  3,167  million  pounds,    compared  with  2,610 
million  pounds  in  1952.    This  subgroup  includes  such  chemicals  as 
carbon  tetrachloride,    ethylene  dichloride,    perchloroethylene,    and 
vinyl  chloride  monomer. 

The  output  of  most  of  the  acyclic  miscellaneous  chemicals  that 
are  produced  in  large  volume  increased  in  1953  compared  with  1952. 
Production  of  formaldehyde  was  1,119  million  pounds  in  1953,    conn- 
pared  with  1,022  million  pounds  in  1952;  of  synthetic  methanol, 
1,116  million  pounds,    compared    with  1,099    million  pounds;  of 
synthetic  ethyl  alcohol,-'-'^  1,060  million  pounds,    compared  with  858 
million  pounds;  of  isopropyl  alcohol,    901  million  pounds,    compared 
with  846  million  pounds;  of  acetic  anhydride,    804  million  pounds, 
compared   with  686  million  pounds;    and   of  carbon  disulfide,    501 
million  pounds,    compared  with  476  million  pounds.    The  production 
of   ethylene  glycol  decreased  to  624  million  pounds  in  1953  from  the 
761  million  pounds  reported  for  1952.   Production  of  ethylene  oxide 
in  1953,    given  for  the  first  time,    totaled  490  million  pounds  (exclud- 
ing the  production  that  is  not  withdrawn  from  the  reaction  system). 


The  large  difference  between  production  and  sales  indicates  that  a  substantial  part  of 
the  output  of  acyclic  miscellaneous  chemicals  is  consumed  at  the  producing  plants  in  the 
manufacture  of  other  more  advanced  products.  Acyclic  miscellaneous  chemicals  so  used  are, 
therefore,  acyclic  intermediates.    They  correspond  in  function  to  cyclic  intermediates, 
although  no  group  of  acyclic   miscellaneous  chemicals   is  commonly  recognized  by  the 
chemical  industry  as  intermediates. 

This  report  does  not  include  statistics  on  the  production  of  ethyl  alcohol  from  natural 
sources  by  fermentation.  The  Alcohol  Tax  Unit,  U.  S.  Bureau  of  Internal  Revenue,  issues 
such  statistics  monthly  and  annually. 


mmmMm.iiim:T&i 


PART  III.  ALPHABETICAL  LIST  OF  INDIVIDUAL  PRODUCTS, 
BY  GROUPS,  AND  NAMES  OF  MANUFACTURERS 

Part  III  of  this  report  consists  of  (1)  a  series  of  tables  that 
supplement  the  statistical  information  given  in  parts  I  and  II,    and 
(2)  a  Directory  of  Manufacturers.    Those  tables  whose  numbers 
include  the  letter  "B"  supplement  the  tables  in  part  I  or  part  II 
whose  numbers  include  the  letter  "A";  for  example,    table  8B    in 
part  III  supplements  table  8A  in  part  II. 

Each  table  in  part  III  lists  alphabetically  the  individual  items  in 
each  group  for  which  data  on  production   or  sales  were  reported 
for  1953.    Where  an  asterisk  (*)    precedes  the  name  of  an  item  in 
the  tables  in  part  III,    separate  statistics  for  the  item  are  given  in 
the  tables  in  part  I  or  part  II.    The  manufacturers  of  each  product 
are  indicated  by  identification  numbers,    which  are  listed  in  the 
Directory  of  Manufacturers   (table  27).    A  few  companies,    however, 
have  specifically  requested  the  Tariff  Commission  to  withhold    such 
information  on   certain  items.    These  manufacturers  are  indicated 
by  the  letter  "X"  in  the  tables. 

Tar  Crudes 


TABLE  4B.- -Organic  chemicals:    Tar   crixles   for  which  United  States  production  or  sales  were  reported, 
identified  by  manufacturer ,    1953 

[Tar  crudes  for  which  separate  statistics  are  given  in  table  4A  are  marked  below  with  an  asterisk  («); 
products  not  so  marked  do  not  appear  in  table  AA  because  the  reported  data  are  confidential  and  may  not 
be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from  table  27.  Table  27  iden- 
tifies all  United  States  producers  of  tar  crudes  (except  producers  who  report  to  the  Coal  Economics 
Division,  U.  S.  Bureau  of  Mines)] 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


»Crude  light  oil 

Light-oil  distillates: 
»Benzene,  specification  and  industrial  grades: 


2° 

90i6 

All  other — __— 

•Toluene: 

Nitration  grade,   1° 

Pure  commercial  grade,  2° 

«:)^lene: 

3°- , 

Commercial 

•Solvent  naphtha 

»A11  other  light-oil  distillates 

Pyridine: 

Crude  bases — — — — - — — — 

Semirefined  or  denaturing  grade 

•Naphthalene,  crude,  solidifying  at — 

Less  than  7<l°  C 

7^°   C.  to  less  than  76°  C 

76°  C.  to  less  than  79°  C 

•Crude  tar-acid  oils,  having  a  tar-acid  content  of- 

5%   to  less  than  2i% 

2A%   to  50it 

•Cresylic  acid,  crude 

•Creosote  oil  (Dead  oil): 

•Sold  or  consumed  as  such——- — 


•Sold  or  consumed  in  coal-tar  solution 

•Coal  tar  sold  or  consumed  in  coal-tar  solution- 
•All  other  distillate  products 


45,  107,  155,  158,  375,  «0. 


323,  ^eA,   488,  536. 
215,  536. 
158,  536. 
157. 

323,  464,  536. 

157,  158,  215,  488,  536. 

158,  464. 
323. 

157,  215,  464,  488,  536. 

134,  157,  158,  323,  327,  372,  373,  464,  536. 

134,  215,  323,  488,  536. 

323,  536. 
323,  536. 

61,  107,  134,  157,  372. 

160,  327,  372. 

323,  372,  375,  536,  538. 

155,  160,  323,  372,  464,  536. 
155,  323,  327,  372,  375,  536. 
323,  372,  373,  536,  538. 

18,  45,  61,  107,  157,  160,  323,  372,  373,  375, 

464,  536,  585. 
160,  323,  372,  375,  528,  536. 
160,  323,  372,  375,  536. 
134,  155,  157,  323,  327,  372,  373,  536,  585. 


313486  O  -  54  -  5 


57 


58 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  4b. --Organic  chemicals 


Tar   crudes    for   which  United  States  production 
identified  by  manufacturer ,    i95J- -Continued 


sales  were  reported, 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


»Tar,  road 

»Tar  for  other  uses: 

Crude 

Refined 

Pitch  of  tar: 

*Sof t  (Water  softening  point  less  than  110°  F. ) 

♦Medium  (Water  softening  point  110°  F.  to  160°  F.)- 

»Hard:  Water  softening  point  of — 

.161°  F.  to  230°  F 

231°  F.  to  291°  F.  and  over 

*Pitch  of  tar  coke  and'  pitch  emulsion 


155,  156,  157,  160,  323,  372,  373,  528,  536, 
585. 

33,  158,  160,  323,  372,  373,  430,  536. 
107,  155,  323,  372,  373,  375,  536,  585. 

61,  157,  373,  536. 

18,  45,  107,  160,  323,  372,  373,  375,  528, 
536,  585. 

323,  372,  373,  536. 

157,  323,  372,  373,  536,  585. 

323,  372,  373,  528. 


Crude  Products  From  Petroleum  and  Natural  Gas 
for  Chemical  Conversion 

TAi3LE  52^  --Organic  chemicals:   Crude  products   from  petroleum  and  natural  gas   for  chemical   conversion  for 
which  United  States  production  or  sales  were  reported ,    identified  by  manufacturer ,  1953 

[Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  separate  statistics  are 
given  in  table  5A  are  marked  below  with  an  asterisk  (*);  products  not  so  marked  do  not  appear  in  table 
5A  because  the  reported  data  are  confidential  and  may  not  be  published.  Manufacturers'  identification 
numbers  shown  below  are  taken  from  table  27 1 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


ARQMATICS  AND  NAPHTHENES 


*Alkyl  aromatics,  distillates,  and  solvents- 
♦Benzene  (except  motor  grade): 


»2 


Benzene,  motor  grade 

*Cresylic  acid,  crude 

Dicyclopentadiene 

»Naphthenic  acids: 

Acid  number  less  than  150 

Acid  number  150-199 

Acid  number  200-224 

»Aoid  number  225-249 

Acid  number  250  and  over 

Petroleum  phenols — 

Sodium  carbolate  and  phenolate,  crude- 
»Toluene : 

♦Nitration  grade,  1° 

•Pure  commercial  grade,  2° 

Solvent  grade; 

All  other 

•Xylene : 

Aviation  grade 

Nitration  grade,  3° 

All  other 


All  other  aromatics  and  naphthenes- 


ALIPHATIC  fflfDROCARBONS 


Ci  hydrocarbons: 
»C2  hydrocarbons: 

Acetylene 

•Ethane 

•Ethylene 


i*C3  hydrocarbons: 
•Propane-— 


•Propylene- 


•Propane-propylene  mixture — 

*Ci   hydrocarbons: 
•1,3-Butadiene,  grade  for  rubber  (elaatomcrs)- 


321,  333,  430,  441,  443,  473,  481,  484,  549. 

31,  258,  278,  283,  404. 

62,  223,  234,  306,  311,  392,  473,  481,  497, 

555,  560. 
311,  592. 

210,  223,  232,  538,  555,  560. 
481. 

404,  405. 

221,  404,  555. 

209,  305,  555. 

221,  223,  305,  318,  555. 

305. 

232,  441. 

210. 

223,  278,  283,  306,  404. 
62,  223,  245,  247,  441,  448. 
392,  560. 
311,  441,  555,  560. 

247,  555. 

223. 

223,  234,  278,  283,  311,  441,  560. 

311,  321,  443. 


252,  413,  4-i3,  560. 


252,  405,  413,  481,  484,  560,  592. 
62,  209,  245,  258,  321,  323,  333,  392,  405, 
413,  426,  448,  481,  484,  560,  592. 

210,  223,  234,  247,  252,  413,  430,  443,  473, 

560,  592. 
62,  223,  323,  392,  413,  443,  448,  481,  484, 

560,  605. 
405. 

90,  105,  213,  258,  323,  392,  441,  443,  448, 
481,  518. 


SYNTHETIC  ORGANIC  CHEMICALS,  I953 

TABLE  5B.--0rgnnic  chemicals:   Crude  products   from  petroleum  and  natural  gas   for  chemical   c 
which  United  States  production  or  sales  were  reported,    identified  by  manufacturer,  1953- 


59 


ynversian    for 
-Continued 


ALIPHATIC  ffifDROCARBONS— Continued 


»C4  hydrocarbons — Continued 

Butadiene  and  butylene  fraotions- 

Butane-butylene 

»n-Butane — 

»1-Butene,  2-butene,  and  mixtures- 


Butylene  concentrate 

»Isobutane— 

Isobutylene 

»C5  hydrocarbons: 

Isopentane 

Isoprene- 

Methyl  butenes 

Neopentane 

n-Pentane 

1-Pentene,  2-pentene,  and  mixtures — 

Ce  hydrocarbons: 

Diisopropyl  ( 2 , 3-Diiiiethylbutane ) 

Hexane 

Hexene-2 

Isohexane 

Methylpentanes — 

Methylpentenes 

Neohexane 

C7  hydrocarbons: 

n-Heptane 

Heptanes 

Isoheptane  and  isoheptene 

All  other 

Cs  hydrocarbons: 

»Di  isobutylene 

n-Octane- 

2,2,4-Trimethylpentane  (Iso-ootane)- 
All  other 

Hydrocarbons,  C9  and  above: 

*Dodecene  (Tetrapropylene ) 

Eicosane 

»Nonene  (Tripropylene ) 

Polybutene 

Triisobutylene 

All  other 

^Hydrocarbon  derivatives: 

tert-Butyl  mercaptan 

Di-tert-butyl  disulfide 

Di-tert-butyl  polysulfide 

Ethyl  mere  aptan 

Methyl  mercaptan -— 

All  other 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


62,  278,  283,  321,  323,  4A8,  555,  605. 

473. 

223,  247,  252,  413,  430,  443,  473,  592. 

209,  210,  213,  223,  234,  247,  405,  413, 

441,  443,  473,  481. 
443. 

252,  413,  430,  443,  473,  592. 
318,  441,  481. 


443, 

473. 

481. 

443. 

443. 

443. 

430, 

443, 

580, 

592 

443. 

441, 

443. 

443. 

443. 

443. 

443. 

443. 

441, 

443. 

443. 

443. 

443, 

481. 

210, 

258, 

318. 

441, 

443. 

443. 

443. 

223, 

404, 

443, 

473 

481, 

518 

210. 

210, 

234, 

404, 

405 

473, 

481 

555, 

560. 

210. 

62, 

247, 

322, 

404, 

443. 

443. 

443. 

443. 

278, 

423. 

423. 

210, 

443, 

477, 

555 

60 


UNITED  STATES  TARIFF  COMMISSION 
Cyclic  Intermediates 


TA3LE  7B. --Synthetic  organic   chemicals:   Cyclic   intermediates   for   which  United  States  production  or  sales 
were   reported,    identified  by  manufacturer ,    1953 

[  Cyclic  intermediates  for  which  separate  statistics  are  given  in  table  7A  are  marked  below  with  an  asterisk 
(*);  cyclic  intermediates  not  so  marked  do  not  appear  in  table  7A  because  the  reported  data  are  confi- 
dential and  may  not  be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from  table 
27.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number 
with  the  designated  product.  (Part  C  in  the  appendix  lists  alphabetically  all  the  important  common  names 
of  cyclic  intermediates  usually  encountered  in  the  trade  and  gives  the  corresponding  standard  (Chemical 
Abstracts)  name  under  which  the  manufacturers'  identification  numbers  are  given  in  this  table)] 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


Acenaphthylene ~ — 

6  ( and  7)  -( 2-Aoetamido-'i-aminqphenylazo)  -1-naphthalene  . 
sulfonic  acid. 

3-Acetamldo-5-amino-p-toluenesulfonic  acid 

2-Acetamido-3-chloroanthraquinone 

2-Acetamldo-p-cresol 

l-Aoetamido-2-ethoxynaphthalene 

l-Aoetamido-2-methoxynaphthalene 

l-Acetamido-2-naphthol 

l-Acetamido-7-naphthol 

8-Acetamido-l-naphthol-3, 5-disulf onic  acid 

3-Acetamido-5-nitro-p-toluenesulfonio  acid 

5-Acetamidosalicylic  acid 

»Acetanilide ,  tech 

o-Acetanisidide 

Aoetoacetanilide 

Acetoaceto-1-naphthylamide 

e=rAaetaas»iiQt,oluidide 

p-AcetoacetotOiuidide 

o-Acetotoluididg: 

p-Acetotoluidide 


21-Acetoxy-'4-bromo-17-hydroxy-3, 11, 20-triketopregnane- 

N-Acetylanthranilic  acid 

"-Acetylhydrocinnamic  acid,  ethyl  ester 

3-Acetyl-'i-hydroxycoumarin . 

Aoetylphenyl  benzoate 

Acetylsulfadiazine 

Acetylsulfamerazine 

Acetylsulfamethazine 

«N-Acetylsulfanilyl  chloride 

Aoetylsulfathiazole 

Acridlne  yellow 

Alkyl  benzene  (high  molecular  weight ) 

*p-Aiiilnoacetanilide 

m-Aminoaoetqphenone 

5-Amino-2-(p-aminoanilino)benzenesulf onic  acid- — 

l-Amino-<4— (">'  -amino-3'  -sulf  oanillno)  -2-anthraquinone  - 

sulfonic  acid. 
5-Amino-2-anilinobenzenesulfonlc  acid 

*2- (p-Aminoanilino )-5-nitrobenzenesulf onic  acid 

6- (3-Aminoanisamido )-l-naphthol-3-sulfonic  acid, 
sodium  salt. 

*l-Aminoanthraquinone  and  salt 

*2-Aminoanthraquinone  and  salt 

l-Aminoanthraquinone-2-sulfonic  acid  and  salt 

l-Aminoanthraquinone-5(and  8)-sulfonic  acid 

N-(^Amino-l-anthraquinonyl  )anthranilic  acid 

N-(5-Amino-l-anthraquinonyl )anthranilic  acid 

N-[5(and  8)-Amino-l-anthraquinonyl]anthranilic  acid 

N-(8-Amino-l-anthraquinonyl)anthranilio  acid 

4— Aminoantipyrine 

»6-Amino-3, 4 '-azobis[ benzenesulf onic  acid ] 

^-Aminoazotoluene-'i  '-sulfonic  acid 

8-Aminobenz [ a ] acridin-7 (12 )-one 


*l-Amlno-4-benzamidoanthraquinone — 

l-Amino-5-benzamidoanthraquinone — 

5-Amino-2-benzamido-l,'4— diethoxybenzene- 

»6- (m-Amlnobenzamido )-l-naphthol-3-sulf onic  acid 

»6- (p-Amlnobenzamldo )-l-naphthol-3-sulf onic  acid 

*2-Amino-p-benzenedlsulfonic  acid  [S03H=ll 

p-Amlnobenzoio  acid,  tech 

p-Aminobenzoic  acid,  ethyl  ester  (Benzooaine,  non- 
medicinal  grade). 

m-Amlnobenzoyl-m-phenylenediamine — — 

p-Aminobenzoyl-m-phenylenediamine 

m-Aminobenzyl  alcohol — 


l-Amino-'4-bromoanthraquinone-2, 5-disulf  onic  acid 

'*l-Amino-i-bromo-2-anthraquinonesulfonic  acid  and  salt- 

l-Amino-2-bromo-<i-  (p-toluidino  )anthraquinone 

»l-Amino-5-chloroanthraquinone 

l-Amino-5(and  8 )-ohloroanthraquinone 

l-Amino-8-chloroanthraquinone 


372 

495 

550 

550 

495 

495 

495 

495 

495 

527. 

550 

550 

565 

245 

448, 

483, 

495, 

521. 

527 

392 

463. 

463 

559. 

392 

463. 

550 

333 

527. 

464 

521. 

X. 

333 

123 

464 

376 

464 

464 

464 

245 

376, 

464, 

515. 

245 

333 

372. 

527 

210 

245 

333, 

480, 

495, 

527, 

550. 

376 

333 

495 

333 

495, 

527, 

550. 

294 

495, 

527, 

559, 

576. 

333 

268 

333, 

365, 

366, 

464, 

527,  550,  552,  576 

333 

464, 

527, 

550. 

333 

550. 

495 

550 

333 

333 

333 

379 

294 

495, 

527, 

550, 

559, 

569,  576. 

569 

527 

333 

464, 

550. 

333 

527, 

550. 

559 

268 

333, 

495, 

527, 

559, 

576. 

294 

333, 

495, 

527, 

550, 

559,  576. 

333 

550, 

559. 

333 

527. 

379 

495 

495 

527. 

333 

495. 

333 

365, 

527, 

550. 

365, 

550. 

333, 

366, 

464, 

527. 

464 

527. 

333, 

366, 

527. 

TABLE  7B, -Synthetic  org 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 

mic   chemicals:   Cyclic   intermediates   for  which  United  States  production 
were  reported,    identified  by  manufacturer,    1953. -Continued 


61 


Chemical 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


2-Aiiilno-l-chloroanthraquinone 

2-Amino-3-chloroanthraquinone 

3-Ajiiino-6-chlorobenzoio  acid — 

l-Amino-5-chlorobenzothiazole  hydrochloride 

o-(3-Aiiiino-'4-chlorobenzoyl  )benzoic  acid 

2-Amino-5-chloro-^ethylbenzenesulfonic  acid — 

l-Amino-5-chloro-'i-hydroxyanthraquinone 

2-Amino-6-ohloro— 4-nitrophenol 

«2-Amino-'i-ohlorophenol r 

2-Ainino-'4-ohloro-l-phenol-6-sulfonic  acid 

2-Ainino-'i-ohlorophenyl  benzyl  ether 

»2-Amino-5-chloro-p-toluenesulfonic  acid  [S03H=l] 

3-Aiiiino-5-ohloro-p-toluenesulfonic  acid  [S03H=l] 

6-Ajiiino-4-chloro-m-toluenesulfonio  acid  [S03H=l] 

<i  -Amino-5' -chloro-p-toluenesulf ono-o-toluidide 

l-Ainino-2,4— dibromoanthraquinone 

l-Amino-ijS-dichloroanthraquinone 

i'  -Ajiiino-2 ' ,  5  '-diethoxybenzanilide 

5-Amino-2-( 2 ( 3) -dihydro-2-oxo-5-benzlmidazolyl) benzene- 
sulfonic  acid. 

l-Amino-2 ,  S-diinethoxybenzonitrile- 

2-Amlno-'4 , 6-dimethylpyr  imidine — 

2-Amino-3,5-dinitrobenzenesulfonethylajnide 

5-Aiiiino-5-ethoxy-2-naphthalenesulfonic  acid 

p-Amino-N-ethyl-N-1-naphthylbenzamide 

m-Aminoformanilide 

5-Amino-8-(p-hydroxyanilino) -2-naphthalenesulf onic  acid — 
5(and  8)-Amino-8(and  5)-(p-hydroxyanilino)-2-napthalene- 
sulfonic  acid. 

•l-Amino-4-hydroxyanthraquinone 

3-Amino-2-hydroxyanthraquinone 

2-Amino-<4-hydroxybenzenearsonio  acid 

3-Aiiiino-6-hydroxy-2-methylphenazine   (Tolazine  base ) 

6-Amino-2,'4-lutidine 

6-Amino-2-mercaptobenzothiazole 

l-Aiiiino-4— methoxyanthraquinone 

5-Ajiiino-6-methoxy-2-naphthalenesulfom.c  acid 

m-  ('4-Amino-3-methoxyphenylazo  )benzenesulf onic  acid 

S-Amino-S-methoxyquinoline  (Amichin) 

7_ (4_Amino-5-methoxy-o-tolylazo )-l , 3-naphthalenedi- 

sulfonic  acid. 
'i-('i'-Aiiilno-5'-!Hethoxy-o-tolylazo)-2,7-naphthalene- 
disulfonio  acid,  5-phenylsulfone  ester. 

l-Amino-2-methoxy-<i-  (p-tolylsulf  onamido  )anthraquinone 

4-Aiziino-N-methylac'etanilide 

l-Aniino-2-methylanthraquinone — — 

6-  ( 3-Amino-4-methylbenzainido  )-l-naphthol-3-sulf onic  aoid- 

4-'rAmino-6'-methylbenzanisidide 

2-A]iiino-5-(6-methyl-2-benzothiazolyl)benzene  sulfonic 
acid. 

2-Aiiiino-<4-methyldlazine __ 

8-Aniino-7-methyl-2-phenazinol 

A-Andno-A-  '-(3-methyl-5-pyrazolone  )-2, 2  '-stilbenedi- 
sulfonic  acid. 

2-Ai!iino-5-methyl-l ,  3,  -i-thiadiazole 

l-Aiiiino-2-methyl-4-  (p-toluidino  )anthraquinone 

1-Aminonaphth  [2 , 3-c]  acridine-5,  S,  14.(13  )-trione 

'i-Amlnonaphth[2,3-o]acridine-5,8,14(13)-trione 

2-Amino-l, 5-naphthalenedisulfonic  acid 

l-Amino-3,6-naphthalenedisulfonic  acid,  8-phenylsulfone 
ester. 

2-Amlno-l,5(and  l,8)-naphthalenedisulfonic  acid 

»3-Aiin.no-l, 5-naphthalenedisulfonic  acid  (Cassella  acid) 

3-Mino-2, 7-naphthalenedisulfonic  acid 

■i-Amino-l,  5-naphthalenedisulfonic  acid 

4-Aiiiino-l, 6-naphthalenedisulf onic  acid 

5-Ainino-2,7-naphthalenedisulfonic  acid   (F  acid) 

*6-Amino-l,3-naphthalenedisulfonic  acid  (Amino  I  acid) 

7-Amino-l,3-naphthalenedisulfonic  acid  (Amino  G  acid) 

8-Amino-l, 6-naphthalenedisulfonlc  acid 

l-Amino-2-naphthalenesulf onic  acid  (o-Naphthionic  acid ) — 

*2-Amino-l-naphthalenesulfonic  acid  (Tobias  acid) 

'♦(and  5)-Amino-l-naphthalenesulfonic  acid 

«5-Amino-l-naphthalenesulfonic  acid  (Laurent's  acid) 

»5-Amino-2-naphthalenesulfoniG  acid  (1,6-Cleve's  acid) 

»5(and  8)-Amino-2-naphthalenesulfonic  acid  (Cleve's 
acid,  mixed). 

»6-Amino-2-naphthalenesulfonic  acid  (Broenner's  acid)- 

»8-Amino-l-naphthalenesulfonic  acid  (Peri 'acid) 

»8-Amino-2-naphthalenesulfonic  acid  (l,7-Cleve's  acid) 

7-Ajiiino-l,3,6-naphthalenetrisulfonic  acid 


333,  550. 

550. 

550,  559. 

333. 

550. 

A6A. 

333,  550. 

550,  559. 

333,  424,  495, 

527 

550,  559. 

294,  495,  527, 

550 

559. 

376,  388,  464, 

521 

531,  569. 

376. 

333,  521,  550 

559. 

333,  527,  550 

333. 

550. 

333. 

550. 

464. 

483. 

333,  495,  559. 

550. 

333. 

333. 

333. 

333,  527,  550. 

527,  550. 

379. 

495,  527. 

372. 

498. 

333. 

495,  527. 

333,  495. 

132. 

495. 

495. 

333. 

527,  550. 

333,  365. 

333. 

550. 

550. 

464. 

333,  550. 

495. 

464. 

365. 

333. 

333. 

376,  464. 

495. 

495. 

333,  495,  521, 

527, 

550. 

495,  327. 

333,  527. 

333,  527. 

268,  569. 

268,  333,  464, 

495, 

527,  550,  559, 

576 

333,  464,  495, 

527, 

550. 

527,  550. 

333,  464. 

376,  464,  495, 

521, 

531,  X. 

464. 

294,  333,  495, 

527, 

559. 

333,  495,  527, 

550, 

559. 

333,  495,  527, 

550. 

495,  521,  527,  537,  X. 

333,  495,  527,  550. 

333,  495,  527,  550,  559. 
333. 


62 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  7B. -Syntheti 


rgnnic  chemicals:   Cyclic  intermediates   for  which  United  States  producti 
viere  reported,    identified  by  manufacturer ,   i95J- -Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


I 

* 


8-Amino-l, 3, 5-naphthalenetrisulf onic  acid 

8-Amino-l,3,6-naphthalenetrisulfonio  acid   (Koch's  acid) — 
"^Amino-l, 3,  5-naphthalenetrisulf onic  acid-4, 5-sultam, 

trisodium  salt. 
5-Amino-l-naphthol 

7-Aiiiino-l-naphthol-3,6-disulfonic  acid   (2R  acid), 
monosodium  salt. 

8-Amino-l-naphthol-3,5-disulfonic  acid   (K  acid) 

*8-Amino-l-naphthol-3,6-disulfonio  acid   (H  acid), 

monosodiuiTi  salt. 
*8-Amino-l-naphthol-5,7-disulfonic  acid   (Chicago  acid) 
(2S  acid),   monosodiiim  salt. 
8-Amino-l-naphthol-3,6-disulfonic  acid,   p-toluene- 
sulfonate. 

«l-Aiiiino-2-naphthol-4-sulfonic  acid   (1,2,'4-Acid) 

*6-Amino-l-naphthol-3-sulfonic  acid   (I  acid),   sodium  salt- 

»7-Aiiiino-l-naphthol-3-sulfonic  acid   (Gamma  acid),   sodium 
salt. 

»8-Amlno-l-naphthol-5-sulfonic  acid   (S  acid),   sodium  salt- 

m-(4-Amino-l-naphthylazo)benzenesulfonic  acid 

Aminonaphthylene  isocyanate 

5-Aniino-2-  (p-nitroanilino  )benzenesulf onic  acid 

3-Amino-5-(m-nitrobenzamido)-p-toluenesulfonic  acid 

3-Amino-'4'-nitrobenzanilide- 


*2-Amino-5-nitrobenzenesulfonic  acid  [SOjH^lJ 

*2-Amino-<i-nitrophenol 

2-Amino-5-nitrophenol 

2-Amino-'i— nitro-l-phenol-6-sulfonic  acid- 


8-Amino-'J-  (m-nitrophenylazo  )-2-naphthol 

'i-Amino-<i'-nitro-2,2'-stilbenedisulfonlc  acid 

2-Amino-5-nitrothiazole 

3-Amino-5-nitro-p-toluenesulfonic  acid  [S03H=l] 

3-Amino-'4-octadecylaminobenzenesulfonic  acid,  sodium 
salt. 

m-Aminooxanilio  acid 

p-Aminooxanilic  acid- 


(6-Aminophenethylmercapto )acetic  acid 

*m-Aminophenol 

p-Aminophenol  and  salts 

*2-Amino-l-phenol-4— sulfonamide 

2-Amino-l-phenol— 4-sulfonanthranilide 

*2-Amino-l-phenol-'i-sulfonic  acid 

m-(p-Aminophenylazo)benzenesulfonic  acid 

*p- (p-Aminophenylazo )benzenesulf onic  acid 

5(and  8)-Amino-8(and  5)-phenylazo-2-naphthalenesulfonic 
acid. 

5- (p-Aminophenylazo )salicylic  acid 

"i-Amino-a-phenyl-m-cresol  hydrochloride 

2- (p-Aminophenyl )-6-methylbenzothiazole 

2- (p-Aminophenyl )-6-methyl-7-benzothiazoleBulf onic 
acid  and  salt. 

1- (m-Aminophenyl )-5-oxo-2-pyrazoline-3-carboxylic  acid 

2-Amino-3-picoline 

6-Amino-3-picoline 

2-Aminopyridine 

"i-Aminosalicylic  acid 

5-Aminosalicylic  acid 

2-(i_Amino-3-sulfophenyl)-6-methylbenzothiazolesulfonic 

acid. 
2-Aminothiazole ~ — 

l-Amlno-4.-(p-toluenesulfonamido)-2-anthraqulnonesulfonic 
acid. 

5-Amlno-o-toluenesulfonanilide 

♦A-Amino-m-toluenesulfonic  acid  [S03H=l] 

»<4-Amino-o-toluenesulfonic  acid  [S03H=1] 

»5-Amino-o-toluenesulfonic  acid  [S03H=l] 

6-Amino-m-toluenesulfonic  acid  [S03H=l] 

7-(4-Amlno-o-tolylazo)-l, 5-naphthalenedisulfonic  acid 

4-('l-Amlno-m-tolylazo)-m-toluenesulfonic  acid —  --.. 

N-(4-Ainlno-m-tolyl )-p-quinone  imine 

^-Aminox  ant hopurpur  i  n- 


»2-Amino-3,5-xylenesulfonic  acid  [SOjHsl] 

p-seo-Araylphenol 

p-tert-Amylphenol 


333, 

527. 

333. 

527. 

333, 

495,    550. 

333, 

527. 

550. 

2-15, 

333,    527. 

333, 

495,    527. 

569. 

333, 

464,   495, 

527, 

550, 

559,    569. 

268, 

294,    333, 

464, 

495, 

523,    527,    550,    559 

576. 

333, 

.495,    527, 

550. 

333, 

495,    527. 

464. 

245. 

569. 

550. 

495. 

333, 

464,    495, 

527, 

550. 

294, 

333,    527, 

550. 

550, 

559. 

294, 

495, 

333. 

495. 

245, 

550. 

550. 

333. 

333, 

569. 

333. 

268, 

434,   464, 

498, 

550. 

460. 

333, 

460,    464, 

498. 

333, 

495,    527, 

550. 

495. 

333, 

434,   495, 

527, 

569, 

576. 

333, 

495,    576. 

294, 

464,    495, 

527, 

550, 

559,    569. 

495. 

495. 

498. 

333, 

527. 

333. 

333, 

495. 

372. 

372. 

372. 

205, 

372. 

464. 

569. 

495, 

527,    576. 

495. 

464, 

515. 

333. 

550. 

333, 

464,    521, 

527, 

559. 

376, 

495. 

333, 

537,    550. 

333. 

495. 

527, 

559. 

333. 

464, 

550. 

550. 

333, 

355,    376. 

580. 

580. 

580. 

580. 

TABLE  1B.--Syntheti 


SYNTHETIC  ORGANIC  CHEMICALS,  I953 

organic  chemicals:    Cyclic    intermediates    for   which  United  States  producti 
were  reported,    identified  by  manufacturer ,   l95J- -Continued 


63 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


2-n-Amylpyridine- 

"♦-n-Ajnylpyridine 

»Aniline  (Aniline  oil) 

Aniline  salt 

l-Anilino-2-anthraquinonecarboxylic  acid — ■ ~ 

2-Anilinoethanol  (Phenylethanolamine ) 

8-Anilino-5- (p-hydroxyanilino )-l-naphthalenesulf onio 

acid. 

l-Anilino-4-hydroxyanthraquinone 

"4-Anilino-4'-hydroxydipheoylamine 

2Wlnilino-4-(8  '-hydroxy-3',6'-disulfo-l'-naphthylamino)- 

6-(  "i-p-anilinosalicylazoj  -i-triazine . 

"Anilinomethanesulfonic  acid  and  salt 

6-Anilino-2-methoxynietanilic  acid- 


»8-Anilino-l-naphthalenesulfonic  acid  (Phenyl  peri  acid)- 
*6-Anilino-l-naphthol-3-sulfonio  acid  (Phenyl  J  acid) 


*7-Anilino-l-naphthol-3-sulfonic  acid  (Phenyl  gamma  aoid)- 

2-Anilino-5-nitrobenzenesulfonic  aoid~ — 

N-(p-Anilinophenyl  )-p-quinone  imine — 

o-Anisidine — 

p-Anisidine 

o-Anisidlne  nitrate 

Anisole ,  tech 

a-(p-Anisyl)-a-ethyl-p-methoxyacetophenone 

a- (p-Anisyl )-p-methoxyacetophenone 

N-  (p-Anisyl  )-'4-nitroanthranilic  acid 

N- (p-Anisyl )-p-phenylenediamine  sulfate-- 

Anthracene,  refined— 


Anthracene,  scintillation  grade 

Anthraflavic  acid  (2,6-Dihydroxyanthraquinone) 

*Anthranilic  acid  (o-Aminobenzoic  acid) 

Anthr a [1,9] pyrazol-6 (2 ) -one  (Pyrazolanthrone ) 

Anthr  aquinone ,  IOO56 

2-Anthraquinonecarboxylic  acid — ~ 

N ,  N '-  (1, 5-Anthraquinone  )dioxamic  acid 

•1, 5-Anthraquinonedlsulf onic  acid 

l,5(and  l,8)-Anthraquinonedisulfonic  acid  and  salt 

»1, 8-Anthraquinonedisulf onic  acid 

*l,8-Anthraquinonedisulfonic  acid,  potassium  salt 

*2 , 6-Anthraquinonedisulf onio  acid  and  salt ™ 

*l-Anthraquinonesulfonic  acid  and  salt- 


2-Anthraquinonesulf onic  acid  and  salt  (Silver  salt ) 

3- (1-Anthraquinonylamino )-7-benz[ de ] anthracen-7-one 

N,N'-(l,5-Anthraquinonylene)dianthranilic  acid— 

l,l'-[l,5(and  l,8)-Anthraquinonylenediimlno]bi3- 

[naphthf  2,3-0] acridine-5,8,l'i(13)-trione]. 
l-(l-Anthraquinonyl)-l,2-hydrazinedi3ulfonic  acid, 

disodium  salt. 

*Anthraruf in  ( 1 , 5-Dlhydroxyanthraqulnone ) 

Arsanllio  acid  and  salt,  tech 

Azobenzene 

"i',"*   -Azobis[4-biphenylcarboxylio  acid] 

l,l'-(Azobis [p-phenylenecarbonyl ] )-2-bls[ l-nitro-2- 

anthraquinonylcarbonyl] hydrazide . 

Azoxybenzene 

m,m-Azoxydi aniline 


Benzaldehyde,  tech- 

l-Benzamido-A-aminoanthraquinone 

^-(i-Benzamldo-l-anthraquinonylamino )naphth[  2, 3-0 ] - 

aoridine-5,8,U(l3)-trione. 

l-Benzamido-'4-ehloro anthr  aquinone- — — — _ 

•l-Benzamido-S-chloroanthraquinone 

l-Benzamido-5-ehloro-4-methoxyanthraquinone -— — 

4-Benzamido-5-ohloro-o-toluidine  [  NH2=l] 

5-Benzamido-i-ohloro-o-toluidine  [  NH2=l] 

2-Benzamido-p-oreaol  (0H= 1 ) 

2-[3-(4-Benzamldo-2,5-diethoxyphenyl)-l-methyldiazo- 

aminojethanesulfonic  acid. 
2-[3-(4-Benzamido-2 , 5-dimethoxyphenyl )-l-methyldiazo- 

aminojethanesulfonic  acid. 
[  3-(4-Benzamido-6-methoxy-m-tolyl)-l-methyldiazoamino] - 

acetic  acid. 
2-[3-(4-Benzamido-6-methoxy-m-tolyl)-l-methyldiazoaiaino]- 

ethanesulfonic  acid. 
8-Benzamldo-l-naphthol-3, 5-disulfonic  acid- 


6-Benzanddo-l-naphthol-3-8ulfonio  acid  (Benzoyl  J  aoid)- 
2-Benzanldo-5-nltro-l , 4-dlethoxybenzene- 


l-Benzamldo-5-(p-tolylaulfonaniido)anthraquinone 


372. 

372. 

245,    333, 

378, 

448, 

464, 

527. 

464,    504. 

464. 

527. 

392. 

333. 

333. 

495. 

495. 

294,    333, 

464, 

495, 

527, 

550,    559,    569. 

495. 

294,    333, 

495, 

527, 

550. 

268,   294, 

333, 

495, 

523, 

527,    550,    559,    569 

576. 

294,    333, 

464, 

495, 

527, 

559. 

495,    550. 

333. 

397,   431. 

245,    333. 

245,    333. 

550. 

333,    582. 

442. 

176,    4-i2. 

550. 

550. 

323,    372. 

372. 

495,    550. 

301,    333, 

434, 

448, 

527, 

550. 

333,    365, 

550. 

333,    464, 

550. 

464. 

495,    550. 

333,    365, 

366, 

464, 

527, 

550. 

333,    365, 

495. 

333,    365. 

366,    550. 

333,    365, 

456, 

464, 

527, 

550. 

333,    365, 

366, 

464, 

495, 

527,    550,    552,    576 

333,   527, 

576, 

456,   464, 

550, 

552. 

333. 

333. 

333,   X. 

294,    464, 

527, 

550. 

132,    565. 

527. 

333. 

333. 

434. 

495,    559. 

331,   343, 

397. 

365,   498. 

527. 

333. 

333,   550. 

333,    464, 

527, 

550. 

333,   550. 

559. 

559. 

495. 

550. 

550. 

376,   550. 

550. 

550. 

294,   495, 

559. 

333. 

64 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  7B. --Synthetic  organic  chemicals:   Cyclic   intermediatea   for  which  United  States  produ 
tiere  reported,    identified  by  manufacturer,    I95J- -Continued 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


»7-Benz[de]anthracen-7-one  (Benzanthrone)- 


Benzenesulfonamlde 

Benzenesulfonlc  acid- 


Benzenesulfonic  acid,  isopropyl  ester- 
Benzenesulfonic  acid,  n-propyl  ester — 

^Benzenesulfonlc  acid,  sodium  salt 

Benzenesulfonyl  chloride 

Benzhydrol  (Diphenylmethanol) 

"Benzidine  base— ■■- 


•Benzidine  hydrochloride  and  sulfate- 

Benzil  (Bibenzoyl) 

Benzillo  acid — — — — 


2-Benzofuryl  oyanomethyl  ketone- 
Benzoic  acid,  tech 

•Benzoin — 

Benzonitrile 

Benzotriazole- 


2  (3  )-Benzoxazolone— — 
•o-Benzoylbenzoic  acid — 

Benzoyl  chloride 

Benzylanine 


o-Benzyl-p-chlorophenol- 
Benzyl  disulfide- 


•Benzyl  ether  (Dibenzyl  ether) 

4r  (N-Benzyl-N-ethylaioino  )-o-toluenesulf onic  acid- 

N-Benzyl-N-ethyl-m-toluldine- 

'l-Benzylidlneaminoantlpyrlne- 


p,p'-Benzylidinebia[N,N-diethylanillne] 

p,p'-Benzylldinebis[N,N-dimethylaniline] 

Benzyl  polysulfide 

2-Benzylpyridine 
4-Benzylpyrldine- 


4, A' -Biacetoacetanilide- 
N,N-Biacetoaoet-o-tolidlne- 


(3, 3'-Bianthra[ 1,9] pyrazolone )-6, 6' -dlone,  potassium 

salt. 
(3,3'-Bl-7-benz[de]anthracen)-7,7'-dlone- 


* (A, A'-Bi-7-benz[  de] anthracen)-7,7'-dlone 

endo-cia-Blcyclq [2 ,2 , 1 ] -5-heptene-2 , 3-dlcarboxylic 

anhydride . 
Blcyclohoxyl 


(l,l'-Binaphthalene)-8,8'-dicarboxyHc  acid — 

1, l'-Bi-2-naphthol 

Biphenyl- 


p-Biphenyl,  Isocyanate— 


»1, A-Bia [l-anthraquinonylamino ]anthraquinone' 
1, 5-Bis [l-anthraqulnonylamino]anthrBqulnone. 


»3,9-Bis  [l-anthraquinonylamino]-7-benz  [de]anthracen-7-one- 
Bia [l-anthraqulnonylamlno] violanthrone- 


3,3^-Bisf7-benz[de^  anthracen-7-one]    sulfide 

N, N '-Bia [ l-ohloro-2-anthraqulnonyl] -4, A '-azobia [  A-ti- 

phenylcarbozimide] . 
A, A  '-Bis [ diethylamino] benzhydrol- 


4,4'-BlB[diethylamlno]benzophenone  (Ethyl  ketone  base)- 
2 , 7-Bis [dlmethylamino] acridine  hydroohloride- 


»A,4'-Blsfdiiiiethylamlno]benzhydrol  (Michler's  hydrol) 

*4,4'-Bis[dlmethylamino]benzophenone   (Michler's  ketone) 

Bis [p-dimethylamlnophenyl]methaneaulf onic  acid  and  salt — 
l-Bla[p-dlnethylamlnophcnyl]  inethyl-2, 7-naphthalenedi- 
sulfonic  acid. 

l,5-Biar2,-4-dlnltrophenoxy]-4,8-dinitroanthraquinone 

1, 8-Bi8  [2,4-dlnitropheno}cy]-4, 5-dinltroanthraqulnone 

m-Bls[2 , 3-epoxyprqpaxy ] benzene 

a-Bia  f(N-ethyl-N-3"-sulfobenzyl)-4'-amlno-2'-tolyl]-p- 
tolueneaulfonlc  acid. 

1, 2-Bia [l-nltro-2-anthraqulnonylcarbonyl] hydrazine 

m-BromoacBtylphenyl  benzoate : 

p-Bromoanlsole- 


•3-Broiiio-7-benz[de]anthracen-7-one  (Bromobenzanthrone  )- 
Bromobenzene,  nono- 


•4-Brainobenzophenone- 


12-Bromo-3,9-epoxy-ll-ketocholanlc  acid,  methyl  eater- 

S-Brostolaatin 

l-Braiao-4-(N-inethylaoetamido)anthraqulnone— — 

4-Bromo-l-methylaminoanthi'aquinone — ——————. 

2-Bromo-3-nethylanthraqulnone- 


6-Bramo-3-methyl-7-dibenz ( f , i J ) laoquinollne-2 , 7( 3) -diono- 

l-Brooionapbthalene 

o-BroBD-p-nltroacetophenone- 


1-  (9-BroBo-7-oxo-7-beisz[  de]  anthracen-3-ylaiiilno )  anthra- 
quinone. 


lU,   29-i,   333,    365, 

366, 

456, 

464,    527,    550 

552,    576. 

549. 

377. 

333. 

549. 

377,    536,    549. 

495,    549. 

582. 

333,    495,    527. 

333,   434,   495,    527, 

550, 

591. 

389,    397. 

343,    397. 

498. 

245,   331,   338,   343, 

397. 

343,   389,    397,    515. 

362. 

376,    599. 

550. 

333,   464,    527,    550. 

331,    338. 

431. 

245. 

123,    591. 

331,   343,   562,   582. 

527. 

527. 

379. 

76. 

76. 

338. 

372. 

372. 

559. 

434. 

333. 

333. 

294,   333,   365,   366, 

456, 

527, 

550,    552. 

527. 

245. 

333,    527,    550. 

176,   493. 

245,   448. 

245. 

333,   366,   464,   527, 

550, 

552. 

333. 

365,   366,   456,   464, 

527, 

550, 

552. 

550. 

366. 

550. 

495. 

76,   333. 

559. 

76,   333,   376,   550. 

76,   333,   376,   527, 

550. 

527. 

495. 

333. 

333. 

483. 

495. 

333. 

376. 

431. 

333,   365,   366,   456, 

464, 

527, 

550,   552,   576. 

181,   448,   494. 

229,   431,   494. 

122. 

550. 

550. 

365. 

333. 

365,   550. 

368,   498. 

245,   550. 

333. 

SYNTHETIC  ORGANIC  CHEMICALS,  1953 


65 


TABLE  TB.- -Synthetic  organic  chemicals:   Cyclic   intermediates   for  which  United  States  product i 
were  reported,    identified  by  manufacturer ,   J955- -Continued 


Manufacturers'   Identification  numbers 
(according  to  list  in  table  27) 


p-Bromophenol 

Z-Bromopyridine 

Bromoquinizarin 

o-(3-Bromo-p-tolyl)benzole  acid 

l-Broiiio-2, 4, 6-triethylbenzene 

p-n-Butylaniline 

Z-tert-Butylanthraquinone — ~ 

sec-Butylbenzene — -— 

tert-Butylbenzene 

Butyl-m-cresol — __ 

3-tert-Butyl-p-cymene 

6-tert-Butyl-2,4-diiiiethylacetophenone ______ 

N-"- -Butyl -'i-metlioxymetanilainide 

2-tert-Butyl-5-methylanisole 

p_tert-Butylphenol 

Carbazole,   refined — 

p_(3-Carbazolylainino)phenol ~ — — — 

o,o'-Carbonyldioxydibenzolc  acid,  diethyl  ester 

2(ajid  6)-Carboxybenzene-4(and  2 )-diazoa!nine 

5- (o-Carboxybenzoyl )-2-chlorooxanilio  acid 

3-Carboxy_2(and  'i)-hydroxybenzenediazonium  sulfate 

3-Carboxyiiiethyl-l-(5_chloro_o-anisyl)_3-methyltriazene 

3-Carboxyiiiethyl-l-(5-chloro-o-tolyl)-3-niethyltriazene 

Chelidamio  acid — ___________ 

o-Chloroaoetoaoetanilide ____ ________ 

Chloroaoetylcateohol 

«m-Chloroaniline — — 

o_Chloroaniline— —_ _■  ■  ■ _____ 

2- (Chloroanilino )ethanol 

5_Chloro-o-anisidine  [NH2=l]  ('4-Chloro-o_aniEidine ) 

[0CH3=l]. 
2-  [3-  ( 5-Chloro-2-anisyl  )-l-methyldiazoaiin"  no]  ethane- 
sulfonic  acid. 

3-Chloro-2-anthracenecarboxylic  acid 

i-Chloroanthranilic  acid _______ .. 

*1-Chloroanthraquinone ___ 

*2-Chloroanthraquinone ■■-  ■ — 

CW.oroanthraq\iinones ,  mixed 

l-Chloro-2_anthraquinonecarboxylie  acid ________ 

o-Chlorobenzaldehyde — — 

p-Chlorobenzaldehyde __________________________ 

Chloro-7-benz [de] anthracen-7-one  (Chlorobenzanthrone ) 

»Chloroben2ene,  mono 

N-Chlorobenzenesulfonamide,  sodium  sait 

p-Chlorobenzenesulfonic  acid 

m_Chlorobenzoic  acid— --■  - —  _ 

p-Chlorobenzoic  acid 

4-Chlorobenzophenone~ ___________________ — _____ 

5-Chloro_2(3)-benzoxazolone _____ 

o_  (m-Chlorobenzoyl)benzoic  acid— 

*o-(p-Chlorobenzoyl)benzoic  acid— 

p-Chiorobenzoyl  chloride 

7-Chlorocymene 

N_  f 3_Chloro-9, 10-dihydroxy_2_anthranyl )acetamidebis- 
[acid  sulfate]. 

5-Chloro-2 ,  't-dimethoxyaniline ___ 

5-Chloro-4, 7-dim&thyl-3 (2 ) -thianaphthenone 

*l-Chloro_2,  'i-dinltrobenzene  (Dinitrochlorobenzene ) 

2-Chloro-3 ;  5-dlnitrobenzenesulf  onethylamide ■ 

2-Chloro-3, 5-dinltrobenzenesulf onic  acid 

2-Chloro-3, S-dinltrobenzenesulf onyl  chloride 

6-Chloro-2, 4-dlnitrophenol 

2-Chloro-N-ethyl-5-nitrobenzenesulfonanilide 

5_Chloro-2-fornylbenzenesulfonlc  acid 

4-Chloro-3-hydrazinobenzene8ulfonic  acid i 

<l-Chloroiiietanillc  acid — 

S-Chlorometanllic  acid 

6-Chloroiiietanllic  acid 

[  3-  ( 5-Chloro-2-iiiethoxyphenyl )  -l-methyldiazoamino]  ao  et  ic 
acid. 

*l-Chloro-2_!iiethylanthraquinone 

5-Chloro-^-methylbenzo-l, 3-thlaza-2-thlonlum  chloride 

Chloronaphthalenes __________________ 

8-Chloro-l-naphthaleneeulfonlc  acid,  sodium  salt 

8_Chloro-l-naphthaleneBulfonyl  chloride 

8-Chloro_l_naphthol-3,6-dlsulfonio  acid  (Chloro  H  acid)- 


443. 
A43, 


AS'?. 
372. 


515,  597. 
463. 

333,  345,  527,  550. 

460. 

333. 


365,  366,  464,  527,  550,  552,  576. 
527,  550. 


245,  333,  338,  387,  390,  391,  448. 
569. 


527,  550. 


333,  464,  527,  550,  576. 


550. 
527,  550. 

366,  464,  527,  550. 


66 


UNITED  STATES  TARIFF  COMMISSION 


TAGLE  7B. --Synthetic  organic  chemicals:   Cyclic   intermediates   for  which  United  States  production 
were  reported ,    identified  by  manufacturer  ,    J95J- -Continued 


Manufacturers'  Identifioation  numbers 
(according  to  list  in  table  27) 


9-Chloronaphtho [ 1 , 2-b]  thlophen-3( 2 ) -one 

8-Chloro-l-naphthylmercaptoacetic  acid 

*2-Chloro-^nitroaniline  ( o-Chloro-p-nitroaniline ) 

*4-Chloro-2-nitroaniline  (p-Chloro-o-nitroanillne) 

4— Chloro-2-nitroanisole 

l-Chloro-5-nitroanthraquinone 

l-Chloro-5( and  8)-nltroanthraquinone 

l-Cliloro-8-nitroanthraquinone 

l-Chloro-2-nitrobenzene 

l-Chloro-2  ( and  >4)  -nitrobenzene ~ 

l-Chloro-3-nitrobenzene 

l-Chloro-4-nitrobenzene 

Chloronitrobenzenes ,  mixed 

»'i-Chloro-3-nitrobenzenesulfonamide 


*2-Chloro-5-nitrobenzenesulfonio  acid 

2-Chloro-5-nitrobenzenesulfonic  acid,  magnesium  salt 

2-Chloro-5-nitrobenzenesulfonic  acid,  sodium  salt 

4-Chloro-3-nitrobenzenesulfonic  acid ~ — — -_— 

2-Cliloro-5-nltrobenzenesulfonyl  chloride 

<i-Chloro-3-nitrobenzenesulfonyl  ch]  oride 

2-Chloro-<i-nitrobenzoic  acid 

2-Chloro-5-nitrobenzoic  acid 

5-Chloro-6-nitro-2  ( 3 )  -benzoxazolone — — — - 

o-C'i-Chloro-S-nitrobenzoyl) benzoic  acid-—— -— — 

4-Chloro-2-nitro-l-phenol-6-sulfonlc  acid 

6-Chloro-2-nitro-l-phenol-6-sulfonic  acid 

6-(2-Chloro-'4-nitrophenylazo)-<i— methyl -m-anisidine 

<i-Chloro-2-nitrophenyl  benzyl  ether 

4-Chloro-2-nitrophenyl  ether 

2-Chloro-A-nitrotoluene — 

4-Chloro-2-nitrotoluene — 

'4-Chloro-3-nitrotoluene 

6-Chloro-2-nitrotoluene — 

Chloronitrotoluenes,  mixed — 

A-Chloro-S-nitro-p-toluenesulfono-o-toluidide — — - 

p-Chlorophenol — — — — 

5-Chloro-2-phenoxyaniline 

»(p-Chlorophenyl)acetonitrile 

( o-Chlorophenyl )hydroquinone 

-i-Chlorophthalic  acid 


"i-Chlorophthalic  acid,  sodium  salt- 

Chlorophthalic  anhydride 

2-Chloropyridine 

6-Chloroquinaldlne _— 

*2-Chloroquinizarin- 


5-Chloro-8-quinolinol — — — 

2-Chloro-5-sulfobenzoic  acid — 

1- ( 6-Chloro-3-sulf ophenyl ) -3-methyl-5-pyrazolone- 

o-Chlorotoluene — — — 

p-Chlorotoluene -— — 

»a-Chlorotoluene  (Benzyl  chloride)- 


3-Chloro-p-tolaenesulfonic  acid  and  salt  [S03H=l] 

5-Chloro-o-toluenesulfonic  acid  and  salt  [sOsH^l] ~ 

5-Chloro-p-toluenesulfono-o-toluldide 

3-Chloro-o-toluidine 

3-Chloro-p-toluidine 

»'4-Chloro-o-toluidine  [CH3=l]  (Red  KB  base)- 


5-Chloro-o-toluidine  [CHj^l]  (Fast  red  TR  base) 

♦4-Chloro-o-toluidine  hydrochloride —- — — ~ 

5-Chloro-o-toluldine  hydrochloride 

5-Chloro-o-toluldine  sulfate 

*4-Chloro-o-tolylmercaptoacetio  acid — — 

2-[3-(5-Chloro-o-tolyl)-l-methyldiazoamino]ethanesul- 
fonlc  acid. 

l-(5-Chloro-o-tolyl)-3-methyl-3-triazenoaoetlc  acid 

4-Chloro-2 , 5-xylenesulf onyl  chloride 

*i-Chloro-2, 5-xylylmercaptoacetic  acid _— — — _ — 

s-Collldlne  (2,4,6-Trimethylpyridine) 

*Cresols:^ 

o-Cresol— — _ 

*Cresol3,  mixed:'- 

Cresol  (meta,  para) 

Cresol  (ortho,  meta,  para) — — -■  - — — 

2, 3-Cresotic  acid— — — _. — ______ 


448,  464,  531,  537,  576. 
448,  460,  527. 


366,  527. 


366,  527. 
333. 


333. 
333,  576. 


483,  495,  550,  576. 

464,  483,  495,  527,  550,  576. 


550,  559,  569,  576. 
483. 


424,  550. 
550. 


550. 
527,  550. 


448. 
448. 


431,  562. 


424,  495,  527. 

550. 
527. 
331,  338,  343,  397. 


550. 

527,  550,  576. 

464,  527. 

464,  550,  569. 


464,  527,  563. 


550,  563. 
550. 


372. 

372,  538. 

536,  562. 

372,  373,  536,  538. 

373,  536,  538. 


See  footnote  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 

•Synthetic  organic  chemicals:   Cyclic   intermediates   for  which  United  States  product! 
were  reported ,    identified  by  manufacturer ,    J953--Continued 


67 


"Cresyllc  acid,  reflned- 


Cumene- 


p_(2-Cyanoethyl)methylaminobenzaldehyde 

8-Cyano-l-naphthalenesulfonlo  acid,  sodium  salt- 

Cyanuric  chloride — — — ~ 

<<Cyclohexane 

Cyclohexanol 

Cyclohexanone — ~ 

Cyclohexanone  oxime 

Cyolohexene- 


4-Cyclohexene-l,  2-dicarl30xiiiilde — 

Cyolohexylamine 

Cyclohexyl-2-propanone- 
p-Cymene 


Decylbenzene — 

1 , 5  ( and  1,8)  -Diacetamidoantlrraquinone- 


4-Dlamlnoanthraquinone- 

S-Diamlnoanthraquinone 

5 (and  l,8)-Diajninoanthraquinone- 
6-Dlaminoanthraquinone-— 


4-Diainino-2 , 3-anthraquinonedicarbonitrile 

•i-Diamino-S ,  3-anthraqulnonedicarboxamide ___— _ 

4-Diajiiino-2, 3-anthraqulnonedisulf onic  acid 

8-Diaminoanthrarufin 

4-'  -Diaminobenzamidodiphenylurea-3,3'-disulfonio  aoid- 
i'-Diaminobenzanilide- 


4-Diaminobenzenesulfonio  acid  [SOjH^l] 

5-Diaminobenzeiiesulfonio  acid  [SOsH-l] 

a'  -Diaiiilno-2 , 2 ' -biphenyldisulf onic  acid 

4' -Diamino-3, 3 '-biphenyldisulf onic  acid 

2'-DiaiLino-5,5'-bi-m-toluenesulfonic  acid 

3 ' -Dlaminooarbanilide 

V-Diaminodlbenzothiophenedisulf onic  acid-5, 5-dioxide, 
disodium  salt. 

4-Diamino-2,3-dichloroanthraquinone— — ---.,-.  — 

4'-Diamino-5,5 '-dimethyl-2,2'-biphenyldisulf onic  acid- 

4'-Diamino-3, 3  '-dimethyl triphenylmethane 

/,'  -Diaminodiphenylamine  sulfate 

•4'  -Diaminodiphenylamine-2-sulf onic  acid 

4' -Diaminodlphenyl  sulf one- 


6-Diamino-l-naphthalenesulfonio  acid- 
4-Diamino-5-nitroanthraquinone- 

N'-Di(m-aminophenyl)oxamide-— 

N'-Dl(p-aminophenyl)oxamide 

4' -Dianiiio-2, 2'  -stilbenedisulf onic  acid 

6-Diamino-m-toluenesulfonic  acid   [S03H=l] 

4-Di-sec-aj!iylphenol 


4-Di-tert-amylphenol- 

5-Diaiilllno-2, 6-anthraqulnonedicarboxylic  aoid- 

4-Dianilino-l-hydroxyanthraquinone 

4-Diazo-2, 5-dichlorobenzenesulf onic  acid 

N-Dl-2-azodiphenol- 


Manuf acturers '  identification  numbers 
(according  to  list  in  table  27) 


464. 
305,  333,  4^1,  U3. 
338,  448. 


88,  223,  232,  323,  362,  372,  373,  464,  536, 

538,  555,  595.^ 
448. 
330. 
333 
10, 
223 
333 
333 
333 
448 
527 
245 
229 
285 
245 
576 
268 
333 
333 
333 
333 
333 
333 
333 
559 
550 
333 
294 
550 
434 
495 
550 
464 


l,5-Dibenz6imidoanthraquinone — ■■  ■  • 

4,4  '-Dibenzamido-1 ,1'  -iminodianthraquinone — ~ 

»4 , 5 '-Dibenzamido-1 , l' -iminodianthraquinone 

5 '-Dibenzamido-1, l' -iminodianthraquinone-- — 

5 '-Dibenzamido-8 '  -methoxy-1,  l' -iminodianthraquinone — 
Dibenzofuran — — ~ — .— — 


5-Dibenzoylnaphthalene- 
N'-Dibenzylethylenediamine  diacetate- 


N,N-Dlbenzylsulfanilic  acid  and  sodium  salt- 

»3,9-Dibromo-7-benz [de] anthraoen-7-one 

p-Dibromobenzene- 

7 

5 


16-Dibromoindanthrene- 
5 '-Dlbromoindigotin- 


2 , 6-Dibroiiio-l ,  5-naphthalenediol- 

Dlbromo-8, 16-pyranthTenedione 

Dibramoviolanthrone- 
Di-n-butylaniline- 


4,6-Di-tert-butyl-m-cresol 

»2,5-DichloroaniHne  and  hydrochloride  [NHjd.]- 
3 , 4-Dichloroaniline- 


»1, 5-Dichloroanthraquinone-  

•l,5(and  l,8)-Dlchloroanthraquinone- 
»1, 8-Diohloroanthraquinone- 


4,8(and  4,5)-Dlchloro-l,5(and  l,8)-anthraquinonedi- 

sulfonic  acid. 
2 , 6-Dichlorobenzaldehyde 
*o-Dichlorobenzene- 


o(and  p)-Dichlorobenzene- 


333,  366,  527,  550. 

366. 

495,  576. 

365,  366,  464,  527,  550,  576. 


495,  527,  550. 
495. 


464,  495,  559,  576. 
527,  559,  576. 


550. 

495,  527,  550,  559,  569,  576. 

495,  527,  559. 

372. 

342,  464,  495,  527,  550,  559. 


527,  550. 
495,  550. 


456,  464,  527,  550. 
550. 


550. 
431. 

333,  365,  366,  456,  464,  527,  550,  552. 


591. 

376,  460,  527,  550,  576. 

365,  527,  550. 

365,  527,  550. 

365,  366,  550. 


197,  236,  245,  333,  338,  391,  448. 

390. 


See  footnote  at  end  of  table. 


68 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  7B.  -Synthetic  organic  chemicals:   Cyclic  intermediates   for  which  United  States  production  or   sale 
were  reported,    identified  by  manufacturer ,    J953- -Continued 


Manufacturers'   identification  numbers 
(according  to  list  in  table  27) 


■*p-Dichloroben2ene — — 

*3,3'-Dichlorobenzidlne  base  and  salts 

Sj'i-Dichlorobenzolc  acid 

2, 5-Dichlorobenzoic  acid 

2,4.-Diohlorobenzoyl  chloride 

N,N'-(2,5-Dichloro-3,6-dioxo-p-pheiiylene)bis[6-(2(3) 
oxo-5-benzimida2Dlylamino]metanilic  acid. 

Dichlorcdiphenylsilane 

2, S-Dichloro-^hydrazinobenzenesulf onic  acid 

2,6-Diohloro-<i-nitroanlline 

<i,  S-Dicliloro-l-nitroanthraquinone — 

l,2-Dicliloro-'4— nitrobenzene — — 

»l,'i-Dichloro-2-nitrobenzene 

»2, 4-Dichlorophenol 


2-[3-(2,5-Diohlorophenyl)-l-ethyldiazoaniino]  -5-sulfo- 
benzoic  acid. 

2,5-Dichlorophenylhydrazlne _____ _ ___ 

Dichlorophenylphosphine  sulfide — • — 

<4,7-Diohloroquinoline 

o- ( 3 , 5-Dichlorosalicyloyl )benzoic  acid 

2,5_Dichlorosulfanilic  acid  [S03H=1] 

»l-( 2 , 5-Dichloro-4-sulf ophenyl ) -3-methyl-5-pyrazolone — 
p,  a-Dichlorotoluene — 
a,a-Dichlorotoluene  (Benzal  chloride)- 
2 , 4-Dichlor otoluene- 

*2,6-Dichlorotoluene- 
3,'4-Dichlorotoluene_ 
Dicyclohexylamine- 


p-Diethylaminobenzaldehyde- 

*N , N-Di  ethyl-3-aminophenol- 

*N,N-Dietliylaniline 

Diethylbenzene -__-- 

N, N_Diethylcyclohexylamine 

N.N-Diethylmetanilio  acid 

N^,N^_Dlethyl-4-jiiethoxyiDetanilamlde _______ _. 

NjN-Diethyl-l-naphthylamlne 

N,N-Diethyl-p-nitrosoaniline ____■________ — 

N,N-Diethyl-p-phenylenedi  amine _____ 

Diethylstilbestrol,   dimethyl  ether 

5-Diethylsulfaiicrl-p_acetanisidlde 

2-C3-[  5-(N.N-Dlethylsulfaiiiyl)-o-anisyl]  -l-ethyldi_ 
azoamlno)-5-sulfoben2oic  acid, 

Diethylterephthaloyl  diacetate 

N , N_Di  ethyl -m-toluidine- 


N-(2,2-Difluoroethyl)aniline 

2- ( N_2, 2-Dif luoroethylanilino ) ethanol 

2, 3-DihydropyTan 

1,5 (and  1,8)-Dihydroxyanthraquinone- 


'l,5-Ditjydroxy-2,7-naphthalenedlsulfonic  acid  (Chrcano- 

tropic  acid). 
■ijS-Dihydroxy-l-naphthalenesulfonic  acid  (Dioxy  S  acld)- 

4, 6-Dthydroxy-2-naphthalenesulf onic  acid ~ — ——- 

*6, 7-Dihydroxy-2-naphthalenesulf onic  acid — 
3,5_Dihydroxy-2-naphthoic  aold- 


»16, 17-Dihydroxyviolanthr one  ( Dihydr oxydibenzanthrone ) - 

Diisobutyl-o-cresol , .  ...  -_— 

2,5_Dijiiethoxyacetophenone —————— 

2, 5-Dimethoxyaniline-  -  — 

ro-Dimethoxybenzene— — — — - — — ■  ■  — _— — — 

p-Dlmethoxybenzene- 


*3, 3  '-Dinethoxybenzidine _____________ — _______ 

2,'i-Dlmethoxybenzoic  acid-_  — 

2, 5-Dimethoxybenzoic  acid —      ■■-  ■  ■-  — 

l,l'-(3,3'-Dimethoxy-4,'i'-biphenylene)bis[3-glycyl_3- 

methyltriazene] . 
2,2'-[3,3'-(3,3'-Dlmethoxy-4,'i'-blphenylene)]bl3_ 

[l-methyldiazoaminol  di(ethanesulf onic  acid) . 
1 , 1 '  -  ( 3 , 3' -Dimethoxy-<i, -i' -biphenylene  )bis[  3-methyl-3- 

( 2-sulf oethyl)triazene ] . 
4, <4'_Dijiiethoxy-6, 6 '-bis  [benzo-1, 3-thlaza_2-thlonlum 

chloride] . 

1 , 4-Diinethoxy-2-nitrobenzene— —  -■   ■        — 

16 , 17-Dlmethoxy violanthrone 

p-Dimethylaminobenzaldehyde--— — — 

o- ( Dimethylaminomethyl ) -p-butylphenol 

o- ( Dimethylaminomethyl ) -p-ootylphenol 

o-  ( Dine  thy  lajnlnomethyl  )phenol- 


N, N-Dtmethyl-7-amlno-l-naphthol-3-sulf oDlo  acid 

N_ (p_Dimethylajiilnophenyl ) -1 , '♦-naphthoquinone  Imlne- 

N,N_Dimethylanlline ■ 

N,  N_Dljnethylbenzylamlne' 


159,  197,  236,  245,  333,  338,  391,  448. 

333,  376,  434,  495,  550,  563,  X. 

397. 

559. 

397. 

333. 

315. 

550. 

483,  550. 

333,  550. 

333. 

245,  333,  460,  527,  550,  576. 

245,  448,  456. 

550. 


550. 
527. 

559,  569. 
464,  495,  550,  559,  569. 


338,  550. 


550. 

464,  550. 
333,  376,  464,  527. 
448. 


559. 

208. 

77, 

365 

527 

294 

397 

338 

397 

333 

397 

245 

527 

333 

76, 

323 

333. 

333. 

550. 

333. 

550. 

527. 

442. 

550. 

550. 


550. 
333. 
483. 
483. 
333. 
333. 
333,  424,  527. 


«2, 2 '-Dimethyl -1,1' -bianthraqulnone- 


495 
550 
133 
333 
294 
493 
431 
333 
333 

333 
464. 
431. 
333. 

550. 


527,  550,  576. 

461,  527,  540,  550,  599. 

376,  550. 

333,  365,  366,  456,  527,  550,  552. 


550. 
X. 
333,  431. 
434,  495. 


483. 
591. 


333,  376,  464,  527. 
366,  464,  527,  550. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


TARLE  7B.- -Synthetic  organic  chemicals:   Cyclic   intermediates   for   which  United  States  production  or  sales 
were  reported,    identified  by  manufacturer ,    J95J- -Continued 


Dime thyl-l,3-oyolohexanedl one 

2',7'-Dlmethylfluoran 

2 , 7-Dimethyl-N-glyoeryltetrahydroqulnoline 

5 , 5-Dimethylhydantoin 

2 , 8-Dimethyl-13^-hydroxy-9 ( 13  ^) -ceroxenone 

2 , 3-Dimethyllndole 

Dlmethylnaphthalene 

N ,  N-Dlmethyl-1-naphthylaiDine 

N,N-Dlmethyl-p-nitrosoanlllne 

N,N-Dimethyl-3-nitro-p-toluenesulfonanilde 

N,N-Dimethyl-p-phenylenediainlne  and  salts 

2_[3-(5-DiiDethylsulfainyl-o-tolyl)-l-methyldlazoainino]-5- 
sulfobenzolc  acid. 

N,N-Dimethylsulfaiillic  acid 

2,7-Dimethyltetrahydroquinollne ~ — 

N , N-Dtraethyl-p-toluidine 

2,4-Dinitroaoetanilide 

2 , 4-Dinitroaniline 

p_(2,4-Dinitroanilino)phenol 

2,'i-Dinitroanlsole 

1 , 5 ( and  1,8) -Dinitroanthraquinone 

N ,  N ' - ( 2 ,  i-Dinitroanthraqulnone ) -1 , 5-dioxainio  acid 

3,3'-Dlnitrot)enzanillde 

ij'i'-Dinitrobenzanllide 

m-Dlnitrobenzene- — - — —- 

2 ,  "i-Dinitrobenzenesulf onlo  acid 

3, 5-Dlnitrobenzoic  acid 

Dinitro(3,3'-bi-7-benz [d^  anthraoen)-7,7'-dione 

<i,5-Dinltrochrysazin 

4,5-Dlnitrochrysazln-2,7-disulfonic  acid,   disodium  salt — 

1, 5 ( and  1, 8 )-Dinitronaphthalene 

2,'4-Dinltrophenol,  tech 

N , N ' -Di ( p-nitrophenyl ) oxamide 

p-Dinitrosobenzene~— — -~~     

*A-, W -Dinitro-2, 2' -stllbenedisulf onic  acid 

2 , A-Dinitrotoluene 

Dinitrotoluenes ,  mixed 

3, 5-Dinitro-p-toluenesulf onic  acid 

Dipentene  (Limonene ) 

1 , 5-Diphenoxyanthr aquinone 

1 ,  S-Diphenoxyanthr  aquinone—— 

Diphenylaoetio  acid 

Diphenylaoetonitrile 

Diphenylamine 

8-Diphenylamino-l,6-naphthalenedisulfonio  acid  (Dlphenyl 
epsilon  acid) . 

6, 8-Diphenylainino-l-naphthalenesulf onic  acid 

Ij-i-Dlphenyl-lj-i-butanedione 

sym-N,N'-Diphenylethylenediainine 

Diphenylolpropane-- — ™ -— 

1 J  3-Diphenyltriazine 

Dithiodibenzoio  acid 

*1 , 4-Di ( p- 1 olui  dino ) anthraquinone 

1 , 5-Di ( p-t oluidino ) anthraquinone 

Divinylbenzene ■ 

•Dodecylbenzene  (includes  keryl-type  benzenes) 

6-Ethoxy-2-mercaptobenzothiazole — — -— .— — ■— ■  ■ 

3(and  A)-Ethoxy-4.(and  3)-methoxybenzaldehyde 

2-Ethoxynaphtlialene 

6-Ethoxy-2-naphthalenesulfonic  acid 

2-Ethoxy-l-naphthylamine 

2-Ethoxy-l-nltronaphthalene 

6-Ethoxy-5-nitro-2-naphthalenesulfonic  acid 

3-Ethylajiiino-p-cresol 

3-Ethylamino-p-toluenesulf onic  acid  [SO3H  =l] 

o-Ethylaniline 

N-Ethylaniline: 

Crude 

Refined 

»2-(N-Etliylanilino)ethanol 

■Ha-(N-Ethylanilino)-p-tolueneBulfonic  acid 

N-Ethyl-p-anisidine 

Ethylbenzene 

N-Ethyldibenzylamine 

N-Ethyldlbenzylamine  diacetate 

2-[l-Ethyl-3-(2-methoxy-5-nitrophenyl)diazoaiiilno}- 
S-sulfobenzoio  acid. 

N-Ethyl-l-naphthylamlne 

N-Ethyl-N-l-naphthyl-o-nitrobenzamide 

l-Ethyl-<i-nitrobenzene 

N-Ethyl-N-phenylbenzylamine  ( N , N-Ethylbenzylaniline ) 

Ethylphenylmalonio  acid,  diethyl  ester - 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


A83. 

168. 

<183. 

333. 

168. 

333. 

372. 

498. 

133,  464,  527, 

550. 

550. 

527. 

550. 

550. 

483. 

498. 

550. 

245,  464,  550. 

527,  550. 

460. 

333. 

495. 

495. 

550. 

333,  527. 

495,  550. 

333,  498. 

333. 

333,  550. 

333. 

550. 

333,  527. 

/ 

569. 

591. 

294,  333,  495, 

527, 

550. 

333,  527. 

527. 

550. 

285. 

333. 

333. 

266,  343. 

132. 

245,  333,  448, 

527. 

495. 

527,  550. 

527. 

333. 

493. 

333,  527. 

301. 

333,  365,  495, 

527, 

550. 

365. 

323,  448. 

210,  245,  473, 

527, 

555,  560. 

333. 

245. 

333. 

559. 

333,  550. 

333. 

559. 

333. 

333. 

245. 

464. 

333,  464,  527 

333,  392,  483, 

495, 

550. 

333,  355,  376, 

464, 

495,  527,  550,  559 

483. 

62,  323,  392, 

448. 

520. 

520. 

550. 

76,  333. 

550. 

245. 

333.  376,  527 

231,  266,  343 

379 

70 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  7B. --Synthetic  organic  chemicals;   Cyclic   intermediates   for  which  United  States  product i 
were   reported,    identified  by  manufacturer ,   i953- -Continued 


Manufacturers'  Identification  numbers 
(according  to  list  In  table  27) 


i 


3-Ethyl-4-picoline 

5-Ethyl-2-plooline   (2-Methyl-5-ethylpyTidine) 

l-Ethylpiperidine 

a-(N-Ethyl-3-sulfoanilino)-p-toluenesulfonic  acid- 

N-Ethyl-5-sulfoanthxanilic  acid 

N-Ethyl-m-toluidine 

N-Ethyl-o-toluidine 

Fonnanllide 

o-Formotoluldide 


"i-Formyl-m-benzenedisulfonic  acid 

m-Fonnylbenzenesulfonic  acid— 

*o-Foniiylbenzenesulfonic  acid 

5-Forrayl-6-hydroxy-2-naphthalenesulfonic  acid 

Fur  an ~ 

3-Glycyl-3-inethyl-l-  ( 6-methoxy-m-tolyl )  triazene 

Hexachlorobenzene ~ 

Hexachlorocyclopentadiene 

Hexachlorodiphenyl  oxide 

1, 6-Hexane  diisocyanate ___ _ 

Homoveratric  acid — 

Homoveratronltrile — . 

Homoveratroylhomoveratrylaniine  (HVA) 

Homoveratrylamine — -— — — ~ — - 

Homoveratrylamine  homoveratrate __— _ 

*p-Hydraainobenzenesulfonic  acid — — — - 

"i-Hydrazino-m-toluenesulfonio  acid — — 

Hydrazobenzene — - — — 

Hydroabietyl  alcohol 

Hydr oqulnone ,  tech 

m-Hydroxyacetophenone 

o-Hydroxyacetophenone 

p-Hydroxyacetophenone 

3-Hydroxy-2-anthraceneoarboxyllo  acid 

1-Hydroxyanthraquinone — — — _-_ ___ _ 

N- ( 3-Hydroxy-2-anthraquinonyl ) -l-nitro-2-anthraqulnone- 
carboxamlde. 

p-Hydroxybenzenearsonio  acid—-- — - — — — — 

2-Hydroxy-ll-benzo-a-carbazole-3-carboxylic  acid 

p-Hydroxybenzoic  acid — — 

p-Hydroxybenzoio  acid,  methyl  ester 

2-Hydroxy-3-carbazolecarboxylic  acid — 

2-Hydroxy-3-dibenzofuramarboxylic  acid,  potassium  salt — 

N-( 2-Hydroxyethyl )phenylacetamide 

1-Hy dr  oxy-i- ( a -hydroxy-m-t olui  dino ) anthraqulnone 

3a-Hydroxy-12-keto-9,ll-cholenic  acid 

3a-Hydroxy-12-methoxy-9,ll-cholenic  acid,  methyl  ester 

3-Hydroxy-2'-methylnaphthanilide 

2-Hydroxy-l-naphthaldehyde 

3-Hydroxy-2-naphthanilide 

l-Hydroxy-2-naphtholc  acid 

*3-Hydroxy-2-naphthoic  acid  (B.O.N.) 


2-Hydroxy-l , 4-naphthoquinone 

2- ( 2-Hydr oxynaphthyl ) -3-thianaphthenol 

l-Hydroxy-i-nltroanthraqulnone- 


4-Hydroxy-3-nitro-l-benzenearsonlc  acid- 

Hydroxynitrovlolanthrone 

2-Hydroxyphenetole - 


N- ( p-Hy dr oxyphenyl ) -2-naphthylamlne 

N-(^-Hydroxypropyl)-o-toluldine 

3-Hydroxy-5-sulfo-2-naphthoic  acid 

1-Hydr oxy-^- ( p-t oluldino ) anthraqulnone- 

*1,1  -Imlno['»-aminoanthraquinone] 

1,1' -Iminobls[^-benzamidoanthraquinone  ]- 
l,l'-Imlnobls[5-benzamldoanthraquinone] 

»6,6'-Iminobis  l-naphthol-3-sulfonic  acid] — 
1,1  -Imlnobis[4-nltroanthraquinone]  • 

*1, l' -Imlnodlanthraqulnone- 
2,2' -Iminodipyridlne- 


2,2  '-(l,3-Indandlone)qulnoline 


Indolineacetaldehyde  (Fisher's  aldehyde) 

Isatin 


Isocytosine  (2-Amlno-4(3)-pyrlmldone)- 

Isonlcotinlo  acid 

Isophorone -  ———.■■-■ 

Isophthalio  acid- 


4,'4'-Isopropylidenedlphenol 

I sopropyl phenol  (o,  m,  p  and  separated  Isomers)- 
Isoqulnoline 


7i, 

392. 

515. 

■^95. 

550. 

333, 

527. 

333, 

527. 

372. 

333. 

333. 

550. 

550. 

376, 

550,    559. 

550. 

333. 

338, 

475. 

333. 

594. 

338. 

m. 

333. 

245, 

442. 

4-i2. 

442. 

245, 

431,   4^2. 

431. 

330, 

355,  464, 

527, 

550, 

559. 

550. 

434. 

222. 

240, 

483. 

376. 

266, 

591. 

266, 

4^8. 

550. 

495, 

527. 

550. 

565. 

550. 

397, 

434. 

397, 

431. 

550. 

464. 

550. 

442. 

333. 

122. 

122. 

521. 

550. 

521, 

550. 

527, 

550. 

333, 

397,   434, 

483, 

486, 

521, 

527,    531,    550 

563,    578. 

527. 

495. 

495. 

565. 

464. 

245. 

550. 

483. 

333. 

365. 

294, 

333,    365, 

366, 

464, 

527, 

550,    552. 

464, 

552. 

333. 

294, 

333,   495, 

527, 

550, 

559, 

576. 

333, 

365,    552. 

333, 

365,    366, 

464, 

527, 

550, 

552. 

372. 

333. 

333. 

527. 

464. 

372, 

536,    550. 

392. 

550. 

77, 

448,   550. 

323. 

372. 

SYNTHETIC  ORGANIC  CHEMICALS,  1953 

-Synthet ic    organic   chemicals:   Cyclic    intermediates    for  whicti  United  States  producti 
were   reported,    identified  by  manufacturer ,    7953- -Continued 


71 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


Isoviolanthrone  (Isodibenzanthrone) 

Lepidine — — — — _ 

»Leuco-l ,  "i-diamlnoanthraquinone 

*Leuoo  quinizarin  (IjAjgjlO-Anthratetrol) 

Leuoo  tetrahydroxyanthraquinone — — — — -. 

2 , 3-Lutidine 

2,4-Lutidlne 

2,6-Lutidlne 

Melamine— -— ____ 

o-Mercaptobenzenesulfonic  acid-- — 

i<Metanilic  acid 

*o-Methoxyanilinomethanesulfonio  acid,  sodium  salt 

2-(o-Methoxyanlllno)-5-nitrobenzenesulfonic  acid— — - 

o-Methoxyanilino-p-sulfonlc  acid — — — — — — — 

6-Methoxy-8-  ( l-methyl-4-diethylaminobutylami»o )  qiiinoline- 

l-Methoxy-A-nitroanthraquinone 

4-Methoxy-6-nitrometanilic  acid 

p-Methoxyphenol 

5-Methoxy-m-phenylenediamine 

[3-(6-Methoxy-m-tolyl)-l.-methyldiazoamino]  acetic  acid 

5-Methyl-o-acetanisidine 

1-Methylaminoanthraquinone 

l-Methylamino-<4-(p-toluidino)anthraquinone — 

N-Methylaniline ~ — _ — . 

2- ( N-Methylanilino ) ethanol 

;8-(N-Methylanillno)propionltrile — ~ — — — 

4-Methyl-m-anlsidine — — 

5-Methyl-o-anisldine  ( Cresidine ) 

N-(5-Methyl-o-anisyl)benzenesulfonamide — — _- - 

N-Methylanthranilic  acid 

2-Methylanthraquinone 

l-( 3-Methyl-2-anthraquinonylamino )-5-( 7-oxo-7H-benz- 

[ de] anthracen-3-ylamino ) anthraquinone . 
3-Methylbenzo[f]qulnoline-— — — -_— — — — - 

N-Metiiylcyolohexylamine — — — 

N-Methyleneanlline — 


3, 3'-Methylenebis [l-aminophenyl-2-phenylether]  -3- 

trlazenemethylaoetlc  acid. 
p,p'-Methylenebis[N,N-diethylaniline]    (Methane  base) — 

p,p'-Methylenebis[  N,N-dimethylanillne] 

p,p  '-Methyl enebis[  N,N-dlmethyl-2-nitroaniline] 

4,^  -Methylenebis  E3-hydroxy-2-naphthoio  acid],   sodium 

salt. 

5,5  '-Methylenebis  [toluene-2,<i-diamlne] 

p,p '-Me thylenedi aniline 

Methylenedi-p-phenylene  isocyanate  (4-,4-'-Methylenedi- 

phenyl  isocyanate) . 
2-Methyleneindoline- 

1-Methylnaphthalene 

l(and  2)-Methylnaphthalene 

2-Methylnaphthalene 

Methylnaphthalene,  crude 

N-Methyl-p-nltroacetanilide — 

N-Methyl-p-nitroanlline 

5-Methyl-4-nitro-o-anisidine — 
i-MetJ^l-o-nitroanisole- 


*2-Methyl-l-nitroanthraquinone 

^Methyl-m-phenylene  diisoeyanate  (Toluene-2,^-dilso- 
oyanate,). 

*3-Methyl-l-phenyl-5-pyrazolone  (Developer  Z) 

Methylplperazine- 


Methylpropyloarblnylbarbituric  acid 

<4-(  3-Methyl-5-pyrazolone  )-m-toluenesulf onic  aoid- 
1-Methylpyrrole- 


l-Methyl-2-pyrrolidone- 
a-Methylstyrene- 


3-Methyl-l-(m-8Ulfamidophenyl)-5-pyrazolone- 

N-Methyl-5-sulfoanthranilio  acid 

o-Methylsulfonyl-p-nltroaniline- 


3-Methyl-l-(m-sulf ophenyl ) -5-pyrazolone- 
*3-Methyl-l-(p-sulfophenyl)-5-pyrazolone- 
Methyl-2-thlenyl  ketone- 


3-Methyl-6-(p-toluidino )-7-dibenz[ f , i j] isoqulnollne- 
2,7(3)-dione. 

(l-Methyl-3-p-tolyldlazoamlno)acetlc  acid 

1-Naphthaldehyde 


365,  366,  550. 

365,  366,  434,  464,  483,  550,  563. 

424,  495,  527,  576. 

550. 

372,  536. 

464. 

333,  464,  495,  527,  550. 

333,  527,  559. 

550. 


333, 

372. 

333, 

333, 

365, 

372. 

323, 

372. 

245, 

442. 

294, 

294, 

495, 

569. 

333, 

333. 

379. 

333. 

333. 

74. 

460, 

550. 

559. 

333, 

550. 

333. 

550. 

333. 

550. 

333, 

559. 

576. 

464, 

333. 


550. 

133,  498. 
443,  A48. 
333. 
333. 
559. 

464,  495. 

333,  376,  495,  527. 

550. 

379. 

527. 
550. 
245,  333. 


333. 
372. 
372. 
372. 
311, 
550. 
550. 
559. 
333. 
333, 
245, 


365,  366,  527,  550. 
333. 


294,  333',  379,  448,  495,  526,  559. 

565. 

442. 

495. 

X. 

550. 

448. 

495. 

550. 

483. 

559. 

294,  333,  464,  495,  550,  559,  569,  576. 

132. 

550. 

550. 
597. 


72  UNITED  STATES  TARIFF  COMMISSION 

TABLE  7B Synthetic  organic  chemicals:   Cyclic   intermediates    for  which  United  States  production   or  sales 

were  reported,    identified  by  manufacturer ,    J95J--GMitinued 


♦Naphthalene,  solidifying  at  79°  C,  or  above  (re- 
fined flake):. 
*From  Ajneridan  crude  naphthalene- 
*Froin  imported  crude  naphthalene- 


l-Naphthaleneacetonitrile 

1 ,  <4-Naphthalenediol 

*1 , 5-Naphthalenediol 

2, 3-Naphthalenediol 


*1, 5-Naphthalenedisulf onic  acid 

1,5-Naphthalenedisulfonic  acid,  sodium  salt 

2,6-Naphthalenedisulfonic  acid 

2, 7-Naphthalenedisulf onio  acid 

1-Naphthalenesulfonic  acid,  sodium  salt 

2-NaphthalenesulfoniG  acid 

2-Naphthalenesulfonic  acid,  sodium  salt 

2-Naphthalenesulfonyl  chloride 

1,3,6-Naphthalenetrisulfonio  acid 

Naphthalic  anhydride 

Naphthalimide — 

Naphthionic  acid 

*Naphthionic  acid,  sodium  salt — — — 

»l-Naphthol  C"^  -Naphthol ) 

2-Naphthol,  tech.  (^ -Naphthol )- 


l-Naphthol-3, 6-disulf onic  acid 

l-Naphthol-3, 8-disulf onic  acid 

»2-Naphthol-3,6-disulfonic  acid  (R  acid) 

*2-Naphthol-3, 6-disulf onio  acid,  disodium  salt 

»2-Naphthol-6, 8-disulf onic  acid  (G  acid) 

2-Naphthol-6, 8-disulf onic  acid,  disodium  salt 

2-Naphthol-6-sulfonamide 

2-Naphthol-6-sulfonaraide,  p-toluenesulfonate 

»l-Naphthol-4-sulfonic  acid  (Nevile  &  Winther's  acid) 

*l-Naphthol-5-sulfonic  acid  and  sodium  salt 

l-Naphthol-8-sulfonic  acid 

»2-Naphthol-6-sulfonic  acid  (Schaeffer's  acid) 

2-Naphthol-6-sulfonic  acid,  sodium  salt 

2-Naphthol-6-sulfonic  acid,  p-toluenesulfonate,  sodium 
salt. 

2-Naphthol-7-sulfonic  acid  and  sodium  salt 

2-Naphthol-8-sulfonic  acid 

l-Naphthol-3, 6, 8-trisulf onic  acid 

1 , 4-Naphthoquinone ~ 

Naphthostyril 

1 , 8-Naphthosultone — 

*Naphth[l,2]  oxadiazole-5-sulfonic  acid — ~ 

Naphth[l,2]  oxadlazole-6-sulfonic  acid 

1-Naphthylamine  (a  -Naphthylamine ) — 

2-Naphthylamine  (^-Naphthylamine) 

l-(2-Naphthylamino)-2-anthraquinonecarboxylio  acid 

1-Naphthyl  isocyanate 

2-Naphthyl  isocyanate 

*2-Naphthylmercaptoacetic  acid 

Nicotinic  acid,  n-butyl  ester — — -— 

Nicotinic  acid,  methyl  ester — 

Nicot inonitrile  ( 3-Cyanopyridine ) — 

p-Nitroacetanilide 

2-Nitro-p-aoetanisidide 

<+-Nitro-o-acetanisidide — 

<i(and  5)-Nitro-o-acetanisidide 

m-Nitroacetophenone — 

5-Nltro-o-acetotoluidide — — _ — 

*m-Nitroaniline 

o-Nitroaniline 

p-Nitroaniline 

6-(3-Nitroanisamidc)-l-naphthol-3-sulfonic  acid — — 

3-Nitroanisic  acid ~ 

*2-Nitr o-p-ani  sidine  [ NHa  =l] 

3-Nitro-o-anisidine  [  NH2=l] 

»4-Nitro-o-anisidine  [  NH2=l] 

»5-Nltro-o-anisidine  [  NHa^l] 

o-Nitroanisole 

p-Nltroanisole — ~ — 

3-Nitro-p-anisoyl  chloride  [CH3OI] 

4-Nitroanthranilic  acid - 

l-Nitro-2-anthraquinonecarbonyl  chloride—- 

*l-Nitro-2-anthraquinonecarboxylic  acid 

l-Nltro-2-anthraqulnonecarboxylio  acid,  hydrazide — 

5-Nltro-l-anthraquinonesulfonio  aoid- 


*5(and  8)-Nitro-l-anthraquinonesulfonic  acid 

8-Nitro-l-anthraquinonesulfonic  acid — — 

2-(l'-Nltro-2'-anthraqulnonyl)anthr[2,3joxazole-5,10- 
dione. 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


323 

333, 

372, 

464, 

521,  52 

6. 

179 

323, 

464, 

521, 

536. 

597 

527 

483 

527, 

550, 

578. 

550 

333 

495, 

527, 

550. 

333 

483. 

495 

333 

495, 

527. 

495 

527 

591. 

464 

495. 

333 

550. 

550 

550 

550 

333 

464. 

333 

376, 

495, 

527. 

333 

495, 

527, 

550. 

376 

464, 

521, 

572. 

527 

333 

333 

495, 

527. 

355 

464, 

550. 

333 

495, 

527, 

550. 

464 

333 

333 

333 

495, 

527. 

333 

495, 

527, 

550. 

550 

559, 

569. 

333 

464, 

495, 

527. 

355 

521. 

333 

333 

521. 

495 

333 

527 

333 

527. 

294 

464, 

495. 

294 

333, 

495, 

527, 

550,  576. 

550 

333 

527, 

550, 

591. 

333 

527. 

527 

245 

333, 

498. 

498 

333 

495, 

527, 

550, 

559. 

205 

562 

205 

495 

333 

550. 

376 

550 

376 

333 

333 

460, 

464, 

495, 

527. 

245 

333, 

576. 

245 

333, 

527, 

576. 

333 

333 

376 

527, 

550, 

552. 

527 

333 

376, 

■464, 

527, 

550,  552,  559 

333 

550', 

»2, 

559, 

576. 

245 

333. 

333 

333 

333 

333 

333 

527, 

550. 

333 

333 

527. 

366 

495, 

527. 

333 

550 

SYNTHETIC  ORGANIC  CHEMICALS,  1953 


73 


TABLE  7B.- -Synthetic   organic  chemicals:   Cyclic   intermediates    for  which  United  States  product i 
were  reported,    identified  by  manufacturer ,   1953--Continued 


Manufacturers'   Identification  numbers 
(according  to  list  In  table  27) 


m-Nitrobenzaldehyde 

*6-(m-Nitrobenzamido )-l-naphthol-3-sulf onic  acid— 

*6-(p-Nltrobenzaiiiido )-l-naphthol-3-sulf onic  acid 

»Nitrobenzene 

2-Nltro-p-benzenedisulfonio  acid 

*m-Nitrob  ?rizenesulf onic  acid 

p-Nltrobenzenesulfonic  acid 

A'-Nitro-o-benzenesulfonotoluidide- 

p-Nitrobenzenesulfonyl  chloride 

5-Nitro-2(3) -benzimidazolone- 


*m-Nitrobenzoic  acid 

»p-Nitrobenzoio  acid 

p-Nltrobenzoio  acid,  ethyl  ester 

p-Nltrobenzoic  acid,  isobutyl  ester 

p-Nitrobenzoic  acid,  n-propyl  ester- ~ 

6-Nitro-2(3)-benzoxazolone 

m-Nitrobenzoyl  chloride — — 

p-Nitrobenzoyl  chloride 

m-Nitrobenzyl  alcohol 

2-Nitrobiphenyl 

4-Nitrobiphenyl- 


4-Nitrobiphenyl-4-'-oarboxylic  acid  and  sodium  salt 

Nltrodiphenylamine 

m-Nitroformanillde— ~- 

1-Nitronaphthalene — — — --- — _— — — ■__ 

3-Nltro-l, 5-naphthalenedisulf onic  acid 

8-Nitro-l-naphthalenesulfonlc  acid--—- — — — - 

8(and  5)-Nitro-l(and  2)-naphthalenesulfonic  acid 

7(and  8)-Nitronaphth[l,:^  oxadiazole-5-sulfonic  acid — 

p-Nitrooxanilic  acid — 

p-Nltrophenetole 

p-Nitrophenol  and  sodium  salt 

2-Nitro-l-phenol-4, 6-disulf onic  acid 

2-Nltro-l-phenol-4-sulfonainide- 


p-(p-Nltrophenyl)acetophenone 

4-Nitro-o-phenylenediamine 

2-Nitrophenyl  ether 

p-Nitrophenylhydrazlne— — ~ — 

p-Nitrophenyl  isocyanate- 


p-(p-Nitrophenylmercapto)aniline- 


l-(m-Nitrophenyl  )-5-oxo-2-pyrazoline-3-oarbo]!ylic  acid 

4-Nitrophthalamlde 

3(and  5)-NitrosaHoylic  acid 

5-Nitrosalicylic  aoid- 


4-Nltrosodiphenylainlne 

l-Nitroso-2-naphthol 

*p-Nitrosophenol- 


5- ( 4-Nitr o-2-sulf oanilino )-2 ( 3 ) -benzimidazolone 

m-Nitrotoluene ~ — __ — .._____ _-__ 

o-Nitrotoluene 

p-Nltrotoluene— — — — — _— 

Nitrotoluene  mixtures- — — — — — _-- 

5-Nitro-o-toluenesulfonanilide- 


3-Nitro-p-toluenesulfonio  acid  [SOjHsl] 

*5-Nitro-o-toluenesulfonic  acid- 


■i'-Nltro-p-toluenesulfono-o-toluidlde- 

5-Nitro-o-toluenesulfonyl  chloride 

*2-Nitro-p-toluldine  [NH?=1] 

4-Nitro-o-toluidine  [NH2=1] 

5-Nitro-o-toluidine  [NH2=lj 

16-Nitroviolanthrone 

2-Nltro-p-xylene ~ 


4-Nitro-m-xylene 

ar-Nltro-o-xylene 

»Nitroxylenes,  mixed 

Nonyl-  and  dodecylbenzenes,  mixed 

*Nonylphenol- 


2- ( Nonylphenoxy ) ethanol- 
Octylphenol- 


6-0xo-6H-anthr[9,l]lsothiazole-3-carbonyl  chloride- 
6-0xo-6H-anthr[9,liisothiazole-3-carboxylio  aoid- 


l-(7-0xo-7H-benz  [de]  anthracen-3-ylamlno)anthraquinone 

1,1'  -(7-0xo-7H-benz[de]  anthraoen-3,9-ylenedilmino)- 

dianthraquinone . 

7-0xo-7H-benz[de] anthracen-3-ylsulfinylacetic  acid 

5-0xo-l-phenyl-2-pyrazoline-3-carboxylic  acid 

5-Oxo-l-phenyl-2-pyrazoline-3-oarboxylic  acid,  ethyl 

ester. 

313486  O  -  54  -  6 


464. 
333, 
333, 
245, 
495. 
245, 
464. 
333. 
527. 
333. 
333, 
333, 
379, 
431. 
431. 
550. 
333, 
333, 
333. 
245. 
245. 
333, 
333, 
550. 
464. 
333. 
333, 
333, 
550. 
530. 
*95, 
333. 
333. 
333, 
245, 
295. 
550. 
333. 
133, 
559. 
498. 
245. 
333. 
333, 
333. 
550. 
569. 
550. 
498, 
333, 
333. 
333, 
333, 
333, 
527, 
550. 
294, 
333, 
559. 
350. 
333, 
333, 
333, 
464. 
333. 
333. 
333. 
333, 
210. 
321, 
550. 
493. 
333. 
333. 
333. 
333. 

333, 
495. 
550, 


495,  559,    569. 

550,  559,    569. 

333,  378,   464,    527,    550. 

294,  333,   495,    527,    550,    559,    576. 


338,  342. 
527,  550. 
431. 


338. 
338,    550. 


550. 
495. 


527,    550. 
495. 


460,   494. 
333,    460,    527. 


591. 
464, 

464, 
527, 
527, 
550. 

464, 
495, 


495,   527,   578. 

527. 
550. 
550. 


495,    550,    559,   576. 
527,    550. 


376,   464,   521,   563. 

464. 

376,    550,    559. 


464,    527. 
323,   493,    550. 


550. 
563. 


74 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  7B.- -Synthetic  organic  chemicals:   Cyclic   intermediates   for  which  United  States  product i 
were  reported ,    identified  by  manufacturer ,   I95J- -Continued 


Manufacturers'   identification  numbers 
(according  to  list  in  table  27) 


5-0xo-l-(p-sulfophenyl)-2-pyrazoline-3-carboxylic  acid 
(Pyrazolone  T) . 

m-(n-Pentadecyl)phenol — _____ — _-_-_-. 

5-(n-Pentadeoyl)resorcinol — ~ — ■—- — — — — 

aj-ijgjlO-Perylenetetracarboxylic  acid 

3,  •i,  9 ,  10_Perylenetetracarboxylic  diimide 

Phenanthrene 

Phenethylamlne _ ~- 

o-Phenetidine — _-—___ _______ 

p-Phenetidine — ___________ — ___________ — _. 

*Phenol: 
♦Natural : 

From  coal  tar:^ 

U.S.P 

39°   C,  m.p 


All  other 

From  petroleum: 

U.S.P 

Other 


♦Synthetic: 

By  caustic  fusion: 

U.S.P 

39°  C,  m.p 


From  chlorobenzene  by  liquid-phase  hydrolysis:  U.S.P- 

From  chlorobenzene  by  vapor-phase  hydrolysis:  U.S.P — 

l_Phenol-2(and  4)-sulfonic  acid 

Phenolsulfonic  acid,  ammonium  salt — 

Phenolsulfonic  acid,  sodium  salt _~ — ~ 

Phenoxathin _____ — 

o_Phenoxyaniline 

»Phenylaoetic  acid  (a-Toluic  acid) 

*Phenylaoetic  acid,  ethyl  ester,  all  grades 

Phenylacetic  acid,  methyl  ester,  tech- — — _ 

*Phenylacetic  acid,  potassium  salt 

Phenylacetic  acid,  sodium  salt 

»Phenylacetonitrile  (a-Tolunitrile) 

p-Phenylacetophenone_ 


2-Phenylanthr[  2,3] oxazole_5 , 10-dione 

*p-Phenylazoaniline  (p-Amlnoazobenzene)  and  hydrochloride- 

Phenyloyclohexane 

N, N '-p-Phenylenebisf  acetamlde] 

2,2'_p_Phenylenebis[  5-(l-nit^o-2-anth^aquinonyl)_l,3,4_ 
oxadlazole  ] . 

*m-Phenylenedlamine 

*o-Phenylenedlamlne 

*p-Phenylenediamlne- 


Phenyl  ether  (Diphenyl  oxide) 

*Phenylglyoine  salts: 

Potassium  salt -_—__ — ____ 

Sodium  salt 

Phenylhydrazine- 


Phenyl-l,2_hydrazinedlsulfonio  acid,  disodium  salt 

Phenylhydrazine  hydrochloride 

*2 , 2 '_( Phenyl imino) dl ethanol 

Phenyl  isocyanate- 


Phenylmalonic  acid,  diethyl  ester_ 

o-Phenylphenol 

o-Phenylphenol,  chlorinated 

o-Phenylphenol,  sodium  salt 

p-Phenylphenol- 


N-Phenyl-p_phenylenediamlne- 

Phenyl-2-propanone_ __— 

Phlorogluoinol 

Phthalic  acid 

■'^hthalic  anhydride- 


Phthallo  anhydride  residue 

Phthalijiiide 

Phthallmide,  potassium  salt 

Phthaloyl  chloride  (Phthalyl  ohloride)- 
♦Picolines:^ 

2-Picoline  (a-Picoline) 

3-Plcollne  (/9-Plooline) 

<t-Plcollne  (r-Ploollne) 

Picoline  (3,4-mlxture) 

Plcramic  acid  and  salt- 


Picric  acid  (Trinitrophenol) 

2_Plpeooline  (a-Plpecoline) 

Piperidine  


559,  569,  576. 


339. 

339. 

550. 

550. 

372. 

338, 

343, 

520,    562,    582. 

2-^5, 

333. 

2-45, 

333, 

576. 

372. 

323, 

536. 

323, 

372, 

536. 

323, 

372, 

373,    536,    538. 

538. 

372, 

538. 

245, 

536, 

568. 

536. 

536. 

536. 

448. 

387, 

487. 

377. 

245, 

324. 

324. 

324. 

448. 

559 

229, 

245 

266,    343,   379, 

562,    582. 

266, 

343, 

379,    562,    565, 

582. 

343, 

562. 

245, 

266, 

343,    520,   562, 

582. 

266, 

582. 

245, 

266, 

343. 

550. 

550. 

333, 

464, 

495,    527,    550. 

245, 

498. 

464. 

333. 

11. 

333, 

4&4,   495,   527, 

550. 

133, 

515, 

550,   599. 

464, 

521. 

448. 

448. 

333, 

527. 

448, 

591. 

333. 

550, 

591. 

333, 

392, 

483,   495,    550. 

245, 

338. 

343, 

379. 

245, 

448. 

448. 

448. 

448. 

333, 

550. 

308, 

343. 

599. 

266, 

550. 

245, 

323, 

456,  464,   521, 

527,    536,    555,    568 

245, 

536. 

333, 

4X, 

448,   550. 

434. 

245. 

"!^, 

323, 

372,   464,   536. 

372. 

372, 

392. 

323, 

536. 

333, 

527. 

333, 

527. 

333. 

245, 

333, 

338. 

See  footnote  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


75 


TABLE  TB.  --Synthetic  organic  chemicals:   Cyclic   intermediates   for  which  United  States  product i 
were  reported,    identified  by  manufacturer ,   i953- -Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


3-(Plperidyl)-l,2-propanediol- 

a-Piperidylpropiophenone 

Poly-sec-amylphenol 

Polychlorobiphenyl- 
Polydodeoylbenzene- 


Polyethylbenzene  (80^  Diethylbenzene)- 

*Primuline  base 

Prlmulinesulfonic  acid — 

♦Propiophenone 

*Pseudooumidine  (Cmnldlne) 

Pyrazole  anthrone  yellow 

Pyridine  (refined ) 

2-Pyridlnepropanol 

3-Pyrldol— 


2-Pyrrolidone — — — -. __ 

«<Julnaldine- 


ftulnaldlne  yellow,  base- 
*Quinlzarin 


2-Quinizarlnsulfonio  acid 

Quinoline: 

Quinoline,  1°    and  2° 

Other  grades—— _____ 

2 , 4-Qulnolinediol 

Quinoline  yellow,  base — 

Quinolinic  acid__— — _ 

Resorclnol,  tech _— 

^Resorcyllc  acid 

Salicylanilide— 


»Salioylic  acid,  teoh- 

Salicylideneaminoguanldine  oleate 

Saligenin  benzoate,  calcium  salt- 
Sodium  phenolate- 


Styphnic  acid,  lead  3alt_ 

"Styrene  (Vinylbenzene) 

A' -Sulf amoylaoetanllide — 

p-Sulfamylbenzoic  acid 

Sulfanilamide 


Sulfanilic  acid  (p_Amlnobenzoic  acid)  and  salt 

7_(p-Sulfoanilino)-l-naphthol_3_sulfonic  acid,   disodium 
salt. 

4-Sulfoanthranillc  acid 

o-Sulfobenzoic  anhydride 


4-Sulfo_o-benzoylbenzolc  acid  (Sulfo  BB  acid) 

p,p'-Sulf onyldiphenol  ( 4-, 4' -Dthydroxydlphenylsulf one )- 

4_Sulfophthalic  acid 

Terephthalic  acid 

Terephthalic  acid,  dimethyl  ester 

Terphenyl  (Phenylbiphenyl) 


Tetrabromo_8, 16_pyranthrenedione- 
*l,4,  5, 8_Tetrachloroanthraqulnone- 
*l,2,4,5_Tetrachlorobenzene 

Tetrachloronitrobenzene- 


Tetrachlorophthalic  anhydride- 

a,  a,2,6_Tetrachlorotoluene 

Tetrahydrofuran- 


Tetraklsaminophthalooyanine,  copper  salt 

»l,4,5,8_Tetrakisri',l",l'",l""_aiithraquinonylamino]- 
anthraquinone  (Pentaanthramide) . 

Tetrakisnitrophthalocyanine,  copper  salt 

2-(2-Thienylmethyl)aminopyridine 

3,3'-ThiobiE[7-benz[de]anthracen-7-one] 

p,p' -Thlodianiline- 


p,p'-Thiodianiline  dihydrochloride- 

p,p'-Thlodianiline  dlsulfate 

6,6'-Thiodijiietanllic  acid 

Thiophene- 


Thiophene  aldehyde 
*o-Tolidlne  and  salts- 


»Toluene-2,4-diamlne   (4-m-Tolylenediamlne)- 

Toluene_2,5-diamine  sulfonate 

o-Toluenesulfonamlde— i 

p-Toluenesulfonamide_ 


o(and  p)-Toluenesulfonlc  acid - 

o(and  p)_Toluenesulfonic  acid,  sodium  salt- 

p-Toluenesulfonic  acid,  ethyl  ester 

p-Toluenesulfonio  acid,  isopropyl  ester 

PTloluenesulfonio  acid,  methyl  ester 

p-Toluenesulfonic  acid  monohydrate 

p-Tolueriesulfono-o-anlsidide. 


p-Toluenesulfono-o-toluidide -_ 

o-Toluenesulfonyl  chloride 

See  footnote  at  end  of  table. 


289. 

442. 

580. 

245. 

473. 

74,   323. 

333,    495,    527. 

114,    550. 

323,   431,    582. 

151,    376,    527. 

365,    550. 

74,   323,    372,    536. ^ 

372. 

205. 

550. 

323,    333,    372,   464,    527,    536. 

464. 

294,   320,   333,   365,   366,  424,   434, 

464,   483 

495.,    527,    550,    563,   576. 

434,    563. 

323,    536. 

372,   498,    536. 

333. 

527,    550. 

495. 

323,   397. 

323. 

333. 

245,   376,   397,  AAS. 

333. 

565. 

333. 

X. 

62,    245,    323,   392,   448. 

464. 

245. 

515. 

464,  495,   527. 

333. 

294,   495,   550. 

498. 

333. 

377,   550. 

434. 

333. 

153,    333. 

245. 

550. 

333,   365,   366,   527,   550. 

245,   338,   448. 

376. 

145. 

333. 

333. 

333. 

333,   365,   456,    527,    550. 

333. 

565. 

333,    365,    550. 

527. 

464. 

333. 

527. 

362. 

565. 

333,   495,    527. 

333,  464,   495,   527,   550. 

464. 

245. 

245. 

245,   377,   521. 

549. 

460,  493. 

333,   493. 

365,  460. 

377. 

559. 

333,    550,    559. 
245. 

76 


UNITED  STATES  TARIFF  COMMISSION 


-Synthetic  organic  chemicals 
were   reported , 


Cyclic    intermediates    for  which  United  States  production 
identified    by  manufacturer ,    i95J--Continued 


p-Toluenesulfonyl  chloride 

m-Toluidine 

o-Toluidine 

p-Toluidine 

Toluidines,  mixed 

*6-p-Toluidinometanilic  acid-- 

*m-Toluidinoiiiethanesulfonie  acid 

*o-Toluidinoiiiethanesulfonie  acid 

8-(p-Toluidino)-l-naphthalenesulfonic  acid 

2-(p-Toluidino)-5-nitrobenzeiiesulfonic  acid 

o-(p-Toluyl)benzoic  acid 

»i_ ( o-Tolylazo ) -o-toluidine   ( o-Aminoazotoluene )- 

N-(o-Tolyl)benzenesulfonaiiiide 

o-(p-Tolyl)benzoic  acid 

2 , 2 '- (m-Tolyltmino ) diethanol 

2,4,-6-Tribroinophenol 

l,2,3(and  1,2,4) -Trichlorobenzene 

1,2,  -i-Tri  chlorobenzene ^^ 

Trichlorophenylsilane 

a,  a, a_Trichlorotoluene  ( Benzotri chloride ) 

a,  3, 4— Trichlorotoluene 

a, 2, 4 (and  a- ,2,6) -Trichlorotoluene 

Triphenylmethyl  isocyanate 

2,4,6-Triiiitrobenzoic  acid- 


1,3, 5-Triphenylhexahydro- s-triazine 

2,4, 6-Tris  ( diinethylaminoiiiethyl)pheiiol 

*6, 6'-Ureylenebis [l-naphthol-3-sulf onio  acid] - 


Vanillic  acid 

o-Vanillin  ( 2-Hydroxy-3-metho3tybenzaldehyde ) 

Veratraldehyde  ( 3 , 4-Dimethoxybenzaldehyde ) 

o-Veratraldehyde   ( 2 , 3-Diraethoxybenzaldehyde ) 

Veratrole — _ — 


Veratryl  alcohol 

5-Vinyl-2-picoline  (MVP)- 

2-VinylpyTidine 

4-Vinylpyridine- 


l-Vinyl-2-pyrrolidone 

*Violanthrone  (Dibenzanthrone)- 
Xenylamine  (4-Biphenylainine)— 

m-Xylene 

o-Xylene 

o(and  p)-Xylene -  — 

p-Xylene- 


Xylenesulfonic  acid 

Xylenesulfonic  acid,  sodium  salt- 

Xylenol  crystals 

Xylenols: 

Low  b.p —_—.«—— 

Medium  b  .p — __________ 

Not  classified  as  to  b.p 

»Xylidines: 

2,3-Xylidine  (o-Xylidine) 

2,4-Xylidine  Cm-4-Xylidine) 

2,5-Xylldlne  (p-Xylidine) 

3,4-Xylidine- 

Xylidines,  mixed: 

"Original  mixture 

Xylidine  (ortho,  para) — . — 

2,4-Xylidine  acetate 

2,5_Xylidine  hydrochloride 

4_ ( 2 , 4-Xylylazo ) -o-toluidine 

4-(2,4-Xylylazo)-2,5-xylidine 

4-(3,5-Xylylazo)-3,5-xylidine 

All  other  intermediates 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


333,  550. 
527,  550,  576. 
527. 

495,  527. 
569. 
569. 
527. 

464. 

495,  527,  550. 


483,  495. 


448,  594. 
338. 


294,  333,  464,  495,  527,  550,  559,  569, 


442. 
431. 


333,  365,  366,  456,  464,  550,  576. 


441,  443,  555. 

549. 

549. 


527,  550. 
527,  576. 


464,  527. 
464. 


527. 
576. 


^Does  not  include  manufacturers'  identification  numbers  for  producers  who  report  to  the  Coal  Economics 
Division,  U.  S.  Bureau  of  Mines. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 
Dyes 


77 


TABLE  8B. -Synthetic 


rganic  chemicals:   Coal-tar  dyes   for   which  United  States  product! 
reported,    identified  by  manufacturer ,    1953 


yes  for  which  separate  statistics  are  given  in  table  8A  are  marked  below  with  an  asterisk  (») ;  dyes  not 
so  marked  do  not  appear  in  table  8A  because  the  reported  data  are  confidential  and  may  not  be  published. 
Manufacturers'  identification  numbers  shown  below  are  taken  from  table  27.  An  X  signifies  that  the  manu- 
facturer did  not  consent  to  the  publication  of  his  identification  number  with  the  designated  product] 


Dye 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBER 
Nitroso  Dyes 

Naphthol  green  B 

/Vitro  Dyes 

Naphthol  yellow  S 

Amido  yellow  E 

Azo  Dyes 

Monoazo  Dyes 


Spirit  yellow  G- 
Acid  yellow  G 

*Spirit  yellow  R- 

»Oil  yellow- 


»Chrysoidine  Y 

*Chrysoidine  R 

*Sudan  I 

Croceine  orange  G 

Orange  G 

Chromotrope  2R 

Fast  acid  fuchsine  B 

»Amido  naphthol  red  G 

Brilliant  sulphon  red — 

*Ghrome  yellow  2G 

»Chrome  yellow  R 

Fast  red  GG  salt 

Azo  alizarin  yellow  GP- 
»Victoria  violet  ^BS 

Chromotrope  6B 

»Amido  naphthol  red  6B — 
»Fast  scarlet  G  base 

Fast  scarlet  G  salt 

Fast  red  GL  base 

«Fast  red  GL  salt 

Sudan  II 

»Ponceau  R 

Double  ponceau 

»Fast  red  B 


Chromotrope  lOB 

»Chrome  brown  R 

Chrome  green  2G 

Chromate  brown  B 

Acid  chrome  brown  R — 

Chrome  flavine  G 

»Azo  eosine  G 

»Fast  red  B  base 

Fast  red  B  salt 

»Fast  scarlet  R  base — 
Fast  scarlet  R  salt — 

Eos amine  G 

Chrome  yellow  5G 

Direct  pink  2GN 

Direct  pink 

Direct  fast  pink  EBN- 

»Metanil  yellow 

Methyl  orange 

»Azoflavine  RS 

Azo  yellow 

Resorcin  yellow 

i<Orange  II 

*Orange  R 

Pigment  rubine  B 

Lake  red  C 


Acid  chrome  brown  B — 
Acid  chrome  garnet  R- 
Acid  chrome  violet  N- 

Chrome  black  PV 

Naphthylamine  brown — 

»Fast  red  A 

*Azo  rubine 


550. 


464 

A(A. 

12, 

12, 

464, 

464, 

12, 

495, 

333, 

527. 

411, 

333, 

411, 

464, 

464, 

550, 

527, 

333, 

527. 

294, 

333, 

576. 

333. 

376, 

12, 

333, 

550. 

464, 

333. 

11, 

550. 

11. 

11, 

11, 

294, 

333, 

376. 

333, 

576. 

333. 

495. 

333. 

527, 

333. 

333, 

333, 

495, 

527, 

527. 

411, 

333, 

333. 

464. 

527. 

495, 

11, 

527. 

550. 

333, 

333, 


550. 

333, 
333, 

527, 

527. 
333, 

527. 

376, 

527. 
376, 
527. 
495, 
495, 
576. 
576. 
464, 

333, 
376, 


464, 

464, 

550, 

550, 

464, 

464, 


527,  550,  576. 
527,  550,  576. 


495,  527,  550,  576. 
495,  527,  550. 


455,  464,  495,  527,  550,  559,  576. 


550, 
550, 


576. 
576. 


495,  550,  527. 


455,  464,  495,  527,  550,  576. 
464,  550,  559,  576. 


527,  550,  552,  559,  576,  583. 
464,  527,  550. 
464,  495,  527,  550. 

495,  527,  550. 

333,  495,  527,  550. 


333. 

550. 
333, 
527, 


495, 
550, 


550. 

552,  559,  576. 


376,  464,  527,  550,  559,  569,  576,  583. 


376, 
376. 
550, 
576. 

464, 
464, 


495, 
527. 


527, 
495, 


464, 
376, 


550. 
527. 


495, 
495, 


527,  550. 
576. 

527,  550. 


527,  550. 
527,  550. 


78 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  SB---Synthetic  organic  chemicals:    Coal-tar  dyes  for  which  United  States  product  ion  or  sales   were 
reported,    identified  by  manufacturer,    7953- -Continued 


Colour 
Index  or 

Proto- 
type No. 


Dye 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


DYES  GROUPED  BY  COLOUR  INDEX  NU>BER~Conti 


Azo   Dyes — Continued 

Monoazo  Dyes — Continued 


180 
183 
18A 
185 
195 
197 
201 
202 
203 
20A 
208 
209 
216 
219 
225 


234 
235 
238 
246 
247 
252 
253 
258 
262 
267 
274 
275 
278 


289 

292 

294 

299 

302 

304 

306 

307 

308 

316 

317 

318 

319 

324a 

325 

326 

327 

331 

332 

343 

346 

349 

353 

364 

365 

370 

375 

376 

377 

382 

385 

387 

393 

394 

395 

400 

401 

403 

405 

406 

411 


»Fast  red  VR 

Croceine  scarlet  3BX- 

Amaranth 

*Cochineal  red  A 

Mordant  yellow  0 

Chrome  yellow  RN 

Chrome  blue  black  B — 
«Chrome  blue  black  R — 

«Chrome  black  T 

•»Chrome  black  A 

Fast  acid  blue  R 

Fast  acid  blue  B 

*Acid  chrome  red  B 

^Chrome  flavine  A 

Direct  pink  2B 


*Resorcin  brown 

»Resorcin  dark  brown — 

Chrome  brown  G 

»Acid  black  lOB 

»Azo  dark  green  A 

*Brilliant  croceine  M- 

Ponceau  SS  ex 

Sudan  IV 

Cloth  red  B 

Neutral  gray  G 

^Milling  orange 

«Cloth  scarlet  G 

•Direct  fast  red  8BL — 


•Scarlet  EC 

•Fast  acid  cyanine  G 

•Fast  acid  cyanine  5R  ex- 
Acid  chrome  verdone  A 

Acid  black  B 

•Acid  chrome  black  F 

Acid  chrome  green  SS 

Fast  acid  black  2BN 

Fast  acid  black  F 


•Fast  acid  cyanine  black  B- 

Naphthylajnine  black  D 

Developed  blue  NA 

Developed  blue  B- 


Naphthylamine  black  V 

•Direct  fast  heliotrope 

•Rbsanthrene 

Direct  brilliant  violet 

•Direct  fast  scarlet 

•Direct  fast  scarlet  4BA 

•Bismarck  brown  G 

•Bismarck  brown  R 

•Chrome  fast  yellow  C 

•Direct  fast  yellow  5GL 

Direct  fast  yellow  4GL  ex 

•Direct  fast  pink  2BL 

•Brilliant  yellow 

•Chrysophenine  G — — 

•Congo  red 

•Congo  Corinth  0 _■_-_— 

Congo  rubine 

Direct  orange  G 

•Direct  scarlet  B 

Direct  violet 

•Direct  violet  B 

Benzo  violet  0 

•Direct  violet  N 

Direct  black  RO 

Direct  brilliant  Bordeaux  R- 
•Developed  black  BH 

Dlphenyl  fast  gray  B 

Direct  cyanine  R 

•Direct  blue  2B 

Cresotlne  yellow  G 


333, 

495, 

527, 

550. 

495. 

495, 

527. 

376, 

464, 

495, 

527,  550 

527, 

550. 

495, 

527, 

550. 

495, 

527, 

550. 

333, 

495, 

527, 

550. 

495, 

527, 

550. 

495, 

527, 

550. 

495, 

527, 

550. 

333, 

527, 

550. 

464, 

495, 

527, 

550. 

333, 

495, 

527, 

550. 

333. 

I 


333, 

411, 

464, 

495, 

527, 

550, 

559. 

333, 

376, 

411, 

464, 

495, 

527, 

550, 

576. 

333, 

527. 

333, 

376, 

411, 

464, 

495, 

527, 

550, 

576. 

333, 

495, 

527. 

333, 

376, 

464, 

495, 

527, 

550. 

527. 

12, 

333, 

527. 

495, 

527. 

333. 

464, 

495, 

550. 

411, 

464, 

495, 

576. 

268, 

294, 

333, 

411, 

455, 

464, 

495, 

523,  527, 

550,  559,  569,  576. 

495, 

527, 

550, 

576. 

495, 

527, 

550. 

333, 

527, 

550, 

569. 

527. 

527. 

333, 

495, 

527, 

550. 

464, 

550. 

333, 

495, 

527, 

550. 

550. 

333, 

527, 

550. 

550. 

550, 

559, 

569. 

495, 

527, 

550. 

333. 

333, 

495, 

527, 

559. 

333, 

527, 

559, 

569. 

576. 

294, 

333, 

464, 

495, 

523, 

527, 

550, 

559,  569,  576 

268, 

333, 

464, 

495, 

550. 

333, 

464, 

495, 

527, 

550. 

333, 

464, 

495, 

527, 

550. 

333, 

464, 

527. 

333, 

455, 

464, 

523, 

527, 

550, 

569. 

294, 

455. 

294, 

333, 

464, 

527, 

550, 

559. 

333, 

464, 

495, 

527, 

550. 

333, 

495, 

527, 

550. 

333, 

495, 

527. 

411, 

464, 

495, 

527, 

550, 

576. 

495, 

523. 

527. 

411, 

464, 

495, 

527, 

550, 

569, 

576. 

495. 

333, 

495 

527, 

550. 

550. 

333 

495, 

527, 

550, 

576. 

576. 

527. 

333 

411 

464, 

495, 

527, 

550, 

569. 

495. 

527 

333 

411 

464, 

495, 

527, 

550, 

569, 

576. 

495, 

527 

SYNTHETIC  ORGANIC  CHEMICALS,  1953 


79 


TAnLE  8B. --Synthetic  organic   chemicals:   Coal-tar  dyes   for  which  United  States  producti 
reported,    identified  by  manufacturer ,   295J--Continued 


Dye 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBER— Continued 
Azo   Dyes--Contlnued 


Disazo  Dyes — Continued 


»Direct  orange  R- 
*Direot  fast  red 


«Direct  brown  M 

Direct  brown  B 

*Polar  red 

Acid  chrome  red 

Direct  brilliant  red  81 
Chrome  fast  yellow  RD — 

«Milling  red  G 

Direct  orange  R 

»Benzopurpurine  AB 

Direct  blue  3R 

»Benzo  new  blue  5B 

Direct  blue  4R 

Direct  blue  BX 

»Direct  blue  3B 

Direct  orange  G 

»Acid  anthracene  red  3B- 

»Benzopurpurine  lOB 

Fast  blue  B  base 

»Fast  blue  B  salt 

»Direct  azurine  G 

Direct  brilliant  blue  G 

•»Direct  blue  RW 

Direct  blue  B 

Chicago  blue  B 

•Direct  sky  blue  FF 


•Direct  pure  blue- 


Trisazo  Dyes 


Direct  fast  blue  FR — 
•Direct  fast  black  FF- 
*Plutoform  black 

Diazo  blue  black  RS — 
•Direct  brown  BT 

Direct  fast  blue  R 

Direct  fast  blue  B 

•Direct  black  EW 

•Direct  black  RX 

•Direct  green  ET 

•Chloramine  green  B 

Direct  steel  blue  G — 

•Direct  green  B 

•Direct  green  G 

Direct  olive  G 

•Direct  brown  3G0 

•Congo  brown  G — ~ 


Tetrakisazo  Dyes 


Direct  brown  G- 


Stilbe 


Dye 


•Direct  yellow  R 

•Chloramine  orange  G— ~ • 

•Stilbene  yellow ~ 

Diphenyl  oatechine  G 

Diphenyl  chrysoine  G 

Pyrazolone  Dye 

•Fast  light  yellow  G 

•Xylene  light  yellow 

•Tartrazine 

•Polar  yellow 

•Chrome  red  B — 

•Pyrazol  orange- — — — - — -.— . 

Ketonimine  Dye 

•Aur  amine — . 


333,   -^95,   527, 
29A,    320,   333, 

569,    576. 
333,   411,   A55, 
-ill,  46A,   <195. 
29-i,   333,   411, 
333. 
495. 

550,    559. 
464,   495,    550, 
527,    576. 
333,  495,   527. 
333. 

333,  411,  495, 
495,  527. 
495,  527,  550. 
333,  495,  527. 
495,  527,  576. 
464,  495,  527, 
333,  411,  495, 
333,  464,  576. 
320,  527,  550, 
333,  411,  495, 
333. 

294,    333,   495, 
333. 
495. 
294,   333,   411, 

569,    576. 
333,   495,    527, 


550. 

411,   455,   464,   495,    527,    550, 

464,   495,    523,    527,    550,    576. 

464,   495,    523,    527,    550,    559. 

559,    576. 

527,    550. 


550,    559,    569,    576. 
527. 

552,   559,   576,   583. 
527,   550,   569,    576. 

527,    550,    569,   576. 

464,   478,   495,    527,    550,   559, 
550. 


333,  576. 
333,  495, 
294,  495, 
333,  527. 
333,  411, 
495. 
495. 

333,  411, 
333,  411, 
333,  411, 
333,  411, 
333. 

333,  411, 
333,  411, 
550,  576. 
333,  411, 
333,  495, 


411,    550. 


527,   550,   569. 
527,   559,   576. 


495,   523,    527,    550,    576. 


464,   495,    527,  550,   569. 

464,   495,    527,  550. 

464,  495,   527,  550,   569,   576. 
495,   527,   550. 

464,  495,    527,  550,    576. 
495,  527. 

464,  495,    527,  550. 

523,   527,    550,  569. 


333,   464,   495,    527,    550. 
333,  464,  495,   527,   550. 
333,  464,   527,   550. 
527. 
495. 


333,   527,    550,    559. 

294,   333,   376,   464,  495,   527,    550,    559,    569. 

376,  455,  464,  495,    527,   550,   559,    569,    576. 

294,   495,    527,   550,    559. 

11,   294,   333,  464,  495,   527,   550,    559. 

455,   495,   523,   527,    550,    559,    569,   576. 


333,  464,   527. 


80  UNITED  STATES  TARIFF  COMMISSION 

TABLE  SB. -Synthetic   organic  chemicals:   Coal-tar  dyes    for   which  United  States  producti 
reported,    identified  by  manufacturer ,   i95J- -Continued 


or  sales  were 


I 


Colour 
Index  or 

Proto- 
type -'o. 


Dye 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


657 
658 
662 
663 
666 
667 
670 
671 
672 
673 
676 
677 
680 
681 
682 
683 
689 
692 
695 
696 
697 
698 
699 
704 
706 
707 
710 
714 
720 
722 
724 
728 
729 
735 
737 


748 
749 
749 
752 
758 
766 
766 
768 
768 
77i 
773 
778 
779 


788 
789 
793 
794 


800 
801 
802 


812 
813 
814 
815 
816 


833 
841 


DYES  GROUPED  BY  COLOnR  INDEX  NUMBER— Continued 


TriphcnyUttha 


ndDipheny  Inaphthy  Ime  thane  Dye 


^Malachite  green 

»Rhoduline  blue  6G 

^Brilliant  green 

Setooyanine 

*Aoid  green  B 

»Fast  acid  green  B 

Acid  light  green- 


»Acid  glauoine  blue 

Xylene  blue  VS 

Xylene  blue  AS 

»Para  fuchsine 

Magenta 

»Methyl  viole  i  B  and  base 

<<Crystal  violet 

»Ethyl  violet 

Benzyl  violet 

Spirit  blue  2B 

Acid  magenta 

Acid  violet  4BN 


Fast  acid  violet  lOB — 
Wool  violet 

*Aoid  violet 

Acid  fast  violet  BG 

Alkali  blue 

Methyl  cotton  blue 

^Soluble  blue 


Brilliant  slcy  blue  5G 

Patent  bl\ie  A 


»Aeid  chrome  azurol  B — 
»Acid  chrome  oyanine  R- 

Aurine 

Victoria  blue  R 

"Victoria  blue  B 


"Naphthalene  green  V 

■"Wool  green  S 


Xanthe 


Dye 


Xylene  red  B 

Rhodamine  B  20^ 

Rhodamine  B  cone . ,  lOC^ 

Rhodamine  6G  cone . ,  100^ 

Fast  acid  violet  A2R 

■x-Fluoresoein- 


»Uranine  (Fluorescein,  alkali  salt) 

Eosine  G  (Tetrabromofluorescein,  alkali  salt)- 

*Tetrabromofluoresoein 

Dinitrodibromofluorescein— 

Erythrosine  bluish — • 

Phloxine  B 

Rose  bengals  B 


Acridine  orange  NO 

Brilliant  phosphine  G- 

Phosphine 

Phosphine  2G 


Qumcline  Dye 


Quinoline  yellow,   spirit-soluble 

<Quinoline  yellow- 


Quinoline  yellow  KT 

Thiazole  Dye 


»Pr  imuline — 

Direct  pure  yellow  M 

•Direct  fast  yellow 

Thioflavine  T 


Direct  brilliant  flavine  S- 


76, 

376, 

464,  527. 

76, 

333, 

376,  527,  550. 

76, 

333, 

376,  464,  527. 

333, 

527, 

550. 

333, 

376, 

464,  495,  527,  550,  559 

333, 

376, 

464,  527,  550,  559. 

550. 

376, 

464, 

527,  550,  559. 

527, 

550. 

527, 

550. 

464, 

519, 

531. 

464, 

519, 

521. 

76, 

333, 

464,  527,  531,  550. 

76, 

333, 

376,  527,  550. 

76, 

333, 

550. 

76. 

519. 

550. 

527. 

333, 

495. 

376, 

527. 

333, 

464, 

495,  550. 

333. 

519, 

531. 

550. 

464, 

519 

531,  550. 

550. 

464. 

333, 

495, 

527,  550,  576. 

333, 

495, 

527,  550,  559. 

333. 

76, 

276. 

76, 

333, 

376,  527,  550. 

333, 

376 

495,  527,  550. 

333, 

376, 

464,  550,  559. 

550. 

550. 

333, 

464 

527. 

333. 

2,  527. 

2,  376,  464,  519,  527,  537. 

376 

464 

519. 

464 

519 

369 

376 

464,  519. 

376. 

519 

376 

519 

464, 

51^^ 

333 

527 

550,  559. 

333 

559 

464 

495 

527. 

559 

464 

527 

550. 

333 

464 

527,  550. 

333 

333 

495 

527. 

333 

114 

333 

495,  527,  550. 

333 

114 

«Wool  fast  blue- 
♦Safranine 


495,  527,  550. 
333,  376,  527,  550. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953  81 

TABLE  SB. -Synthetic  organic  chemicals:   Coal-tar  dyes    (or  which  United  States  production  or  sales  were 
reported,    identified  by  manufacturer,    i  95  J- -Continued 


Dye 


DIES  GROUPED  BY  COLOUH  INDEX  mMBER— -Continvied 

Azine   Dyes — Continued 

Methylene  violet 

Acid  cyanine 

»Induline ,  spirit-soluble 

»Induline ,  water-soluble 

Nigrosine ,  spirit-solutle 

Nigrosine,  water-soluble 

Aniline   Black    and   Allied  Dyes 

Diphenyl  black  base 

New  fast  gray 

Fur  black 


Oxaz 


Dye 


Gallocyanine- 

New  blue  R 

Nile  blue  A — 


Thi 


Dye 


^Methylene  blue 

Methylene  green  B 

Sulfur   or  Sulfide  Dyes 

Derivatives  of  Carbazole 
Carbazole  vat  blue  R 


Other  Sulfur  or  Sulfide  Dyes 


»Sulfur  black— 

»Sulfur  blue 

•Sulfin-  brown — 
»Sulfur  green — 
*Sulfur  maroon- 
»Sulfur  olive— 
»Sulfur  yellow- 
All  other 


•Alizarin  VI 

•Alizarin  red  S- 


Alizarin  brown- 
Alizarin  SX 


»Acid  alizarin  blue  SE — 
*Aoid  alizarin  blue  B 

Anthracene  blue  SWGG 

Anthracene  blue  WR 

•Alizarin  irisol  R 

Alizarin  astrol  B 

Cyananthrol  R- 


•Alizarin  cyanine  green- 


Acid  anthraquinone  violet 

•Anthraquinone  blue  black  B 

•Acid  anthraquinone  sky  blufl  B- 

Anthraquinone  blue  SR 

Acid  alizarin  rubine 


Anthraquinone    Vat  Dyes 

•Anthraquinone  vat  golden  orange  G,  I256- 

•Anthraquinone  vat  scarlet  G,  16-2/35t 

•Anthraquinone  vat  dark  blue  BO,  25^ 

•Vat  navy  blue  NTP- 


•Anthraquinone  vat  jade  green,  &fi 

•Anthraquinone  vat  green  B  and  black  B,  12-l/2)t- 

•Anthraquinone  vat  violet  2R,  12-l/2it 

Anthraquinone  vat  violet  B,  25ffi 

Anthraquinone  vat  blue  RS,  lOjt — 

Anthraquinone  vat  blue  3G,  lOJt 

Anthraquinone  vat  blue  GCS,  S-l/yfi 

•Anthraquinone  vat  blue  GCD,  8-1/3^^ 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


527. 

550. 

^U 

527 

550. 

AM, 

527, 

550. 

A6A, 

527, 

550. 

A6A, 

527, 

550. 

A6A. 

K(A. 

464. 

424. 

464, 

527. 

550. 

76, 

464, 

527,   550 

464. 

250,  333. 


250,  333,  464,  527,  550. 

250,  333,  461,  464,  495,  527,  550. 

250,  333,  461,  464,  495,  527,  550,  587. 

250,  333,  461,  464,  527,  550. 

333,  464,  527,  550. 

250,  333,  461,  464,  527,  550,  578. 

250,  333,  461,  464,  495,  527,  550,  578. 

250,  333,  461,  527,  550,  578. 


464,  527,  576. 

365,  464,  527,  550,  576. 

424,  527. 

527. 

333,  464,  495,  527,  550. 

268,  294,  333,  464,  495,  527,  550. 

365. 

294,  527. 

333,  365,  424. 

333,  365,  550. 

333,  365. 

294,  333,  365,  424,  464,  467,  495,  527,  550, 

576. 
365,  527. 

365,  424,  464,  495,  527,  550,  576. 
333,  365,  527,  550. 
365. 
365,  550. 


333,  464,  527,  550. 

333,  464,  527,  550. 

114,  250,  268,  333,  365,  366,  464,  527,  576. 

333,  365,  366,  464,  550. 

68,  294,  333,  365,  366,  455,  456,  483,  527,  550, 

552,  576. 
114,  250,  268,  333,  366,  464,  527,  550. 
333,  365,  527,  550. 
333. 

333,  464,  527,  550. 
333. 

333,  527,  550. 
333,  464,  527,  550. 


82  UNITED  STATES  TARIFF  COMMISSION 

TABLE  S3. --Synthetic  organic  chemicals:   Coal-tar  dyes   for  which  United  States  production 
reported ,    identified  by  manufacturer ,    i95J- -Continued 


sales  were 


Coloiir 
Index  or 

Proto- 
type No. 


Dye 


Manufacturers'  Identification  numbers 
(according  to  list  in  table  27) 


1118 
1120 
1132 
1135 
1150 
1151 
1152 
1161 
1162 
1163 
1167 
1170 
1173 


1177 
1180 
1183 
1184 
1185 
1207 
1212 
1217 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBER—Continued 
Anthraquinone   Vat  Dyes — Continued 


*Anthraquinone 

Anthraquinone 

Anthraquinone 

Anthraquinone 

»Anthraqulnone 

^Anthraquinone 

*Anthraquinone 

Anthraquinone 

Anthraquinone 

»Anthraquinone 

Anthraquinone 

Anthraquinone 

Anthraquinone 


vat  yellow  G,   12-l/25t 

vat  brown  B,   225t 

vat  yellow  GK,   12-1/2$ 

vat  brilliant  violet  RK,  12-l/2$- 

vat  olive  R,  12-1/2$ 

vat  brown  R,  12-1/2^^ 

vat  brown  G,  12-1/2^- 


vat  red  violet  RHN,  12-l/25t- 

vat  red  BN,  ex.,  12-1/2$ 

vat  violet  BN,  25$ 

vat  olive  G 

vat  yellow  R,  12-1/2$ 

vat  blue  3G,  12-l/2$ 


Indigoid   and   Thioindigaid  Dye 


*Indigo,  synthetic,  20$ 

Indigotin  lA 

Tribromindlgo  RB,  20$ 

«Bromindigo  blue  2BD,  16$- 

Indigo  blue  6B 

Ciba  pink  B,  20$ 

»Vat  red  3B,  20$ 

*Vat  orange  R,  10$ 


food,  Drug,    and  Cosmetic  Dyes 

Food,  Drug,  and  Cosmetic  Colors 


»Blue  #1 

Blue  #1,  aluminum  lake- 
»Blue  #2 

Green  #1 

Green  #2 

Green  #3 

*Orange  # 1 

Orange  #2 

<<Red  #  1- 

»Red  #2- 

»Red  #3- 


Red  #3,  aluminum  lake- 

»Red  #A 

Red  #  32 

Violet  #1 

Yellow  # 1 

Yellow  #3 

»Yellow  #4- 


»Yellow#5,  #6 

Yellow  #'5,  aluminum  lake- 


Drug  and  Cosmetic  Colors 


Black  #  1 

Blue  #1 

Blue  #A 

Blue  #6,  #9- 
Brown  #1- 
Green  Si- 


Green  #5,  #6,  #7- 

Orange  #3 

Orange  #4- 
Orange  #5- 


Orange  #10,  #11,  #16 

Orange  #15,  #17 

Red  #1,  #2,  #3,  #30,  #38 

Red  #5 

Red  #  6 

Red  #7,  #8,  #10,  #31,  #35,  #36 

Red  #9,  #12,  #13,  #3A 

»Red  #11 

Red  #17,  #18,  #28,  #33,  #37,  #39 

»Red  #  21 

Red  #22 

Red  #27 


250, 
333, 
333, 
333, 
29<i, 
333, 
333, 
333, 
527, 
333, 
250. 
lU, 
527, 


333, 
«6. 
527, 
527, 
333, 
366, 
366, 
527. 
550. 
365, 

333. 
550. 


527. 

576. 
550. 
365, 
A56, 
456, 


366,  456,  464,  527,  550,  552. 
464,  527,  550. 
464,  537. 


527,  550. 


Violet  #1 

Yellow  #1,  #10- 


333,  448,  527,  550. 

333,  527. 

333,  448,  527. 

68,  448,  527,  550. 

68,  527,  550. 

448,  550. 

68,  333,  464,  527,  550. 

68,  333,  464,  550,  576. 


87,  151,  355,  376,  527. 

87. 

87,  151,  330,  527. 

151,  355,  527. 

151,  355,  527. 

355. 

87,  151,  330,  376,  527. 

376,  464,  527. 

87,  151,  376,  527. 

87,  151,  330,  355,  376,  527. 

87,  151,  330,  527. 

87. 

87,  330,  355,  376,  527. 

464,  527. 

527. 

87. 

87,  464,  472,  527. 

87,  464,  472,  527. 

87,  151,  330,  355,  376,  527. 

87. 


464, 

87. 

527. 

87, 

527. 

87. 

527. 

87, 

87, 

87, 

527. 

87, 

87. 

376. 

87, 

87, 

87, 

87, 

527. 

87, 

87, 

376, 

277. 

87, 

87, 


527. 
527. 


527. 

527,  537. 
277,  376. 


527,  537. 
537. 

277,  537. 

277,  537. 

277,  527,  537. 

277,  369,  376,  464,  519,  537. 
464,  527. 

527. 
527. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 

TABLE  8B. -Synthetic  organic  chemicals:   Coal-tar  dytfs    for   which  United  States  producti 
reported,    identified  by  manufacturer,    1953 --Continued 


83 


Colour 
Index  or 

Proto- 
type No. 


Dye 


DYES  GiROUPED  BY  COLOUR  INDEX  NUMBER—Continued 

Food,    Drug,    and  Cosmetic  Dyes— Continued 

Drug  and  Cosmetic  Colors — Continued 


Yellow  #5 

Yellow  #  6 

Yellow  #7,  #8 

Yellow  #11 


Drug  and  Cosmetic  Dyes,  External 


Blue  #1— 
Green  #1- 
Orange  #1- 


Red  #1,  #10,  #11- 

Red  #8,  #13 

Violet  #2 

Yellow  #1,  #3 

Yellow  #5 , — 


DYES  GROUPED  BY  PROTOTYPE  NUMBER 


«Acid  alizarin  flavine  R — 
Acid  anthracene  brown  B — 

*Acid  anthracene  brown  PG- 
Acid  chrome  blue  2R 

•Algol  yellow  GC— 


Alizarin  direct  blue  A2G- 
Alizarin  direct  blue  AR — 

•Alizarin  supra  blue  A 

Alkali  fast  green  lOG- 


*Anthracene  chromate  brown  EB- 

Artifioial  silk  black  G 

*Benzo  Bordeaux  6B 


*Benzo  chrome  black  blue  B- 

Benzo  copper  blue  B 

♦Benzo  fast  black  L 

*Benzo  fast  blue  4GL 

Benzo  fast  blue  8GL 

Benzo  fast  brown  3GL 

Benzo  red  12B -. 


Benzo  rhoduline  red  B 

•Benzo  rhoduline  red  3B 

Brilliant  acid  blue  3B 

•Brilliant  benzo  violet  B — 
Brilliant  benzo  violet  2R- 
Brilllant  milling  blue  B — 

Brilliant  wool  blue  FFB 

Brilliant  wool  blue  FFR 

•Celliton  orange  GR- 


Chlorantine  fast  blue  2GL 

•Chlorantine  fast  brown  BRL- 


Direct  fast  red  5BL 

•Chlorantine  fast  yellow  "WJL — 

Chlorantine  fast  yellow  RL 

Chrome  yellow  DS 

Chrome  yellow  G 

Cibacete  brilliant  blue  2B 

Cibaoete  diazo  black  B 

Cibacete  diazo  black  GN 

Cibacete  sapphire  blue  G 

Cibacete  scarlet  G 

Cotton  black  3G 


Cross  dye  green  B 

•Diajnine  Bordeaux  B 

Diamine  cateohine  B 

Diamine  oatechine  G 

•Diamine  catechine  3G 

•Diamine  fast  blue  FFB 

•Diamine  fast  orange  EG- 
•Diamine  fast  orange  ER- 

•Diamlnogen  blue  N2B 

•Diazo  Bordeaux  7B 


•Diazo  brilliant  green  3G 

•Diazo  brilliant  scarlet  2BL  ex- 

•Diazo  brilliant  scarlet  ROA 

Diazo  brown  5G 

Diazo  brown  MR 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


87,  537. 

87. 

87,  -464,  519,  527. 

527. 


527. 

527. 

87. 

527. 

87,  527. 

87,  527. 

87. 

87,  537. 


333,  464,  527,  550,  559. 

464,  495,  527,  550. 

11,  294,  333,  411,  495,  523,  527,  550,  559. 

495,  527,  550. 

268,  333,  365,  366,  456,  464,  527,  550,  576. 

527,  550. 

527,  550. 

294,  333,  527,  550. 

527,  550. 

294,  333,  411,  464,  495,  527,  550. 

495,  527,  550. 

495,  527,  550,  576. 

333,  495,  527,  550. 

527,  550. 

333,  495,  527,  550,  576. 

294,  333,  527,  550,  559. 

333,  559. 

527,  550,  569. 

333,  527. 

320,  550. 

320,  527,  550. 

527,  576. 

333,  495,  527,  550,  576. 

559. 

330,  527,  550. 

527. 

527,  550. 

320,  333,  495,  550. 
495. 

294,  333,  411,  455,  464,  478,  495,  509,  523, 

527,  550,  559,  569,  576. 
495. 

333,  495,  523,  527,  550,  559,  569. 

478,  495,  523,  559. 

495. 

464,  527. 

569. 

333,  495. 

495. 

333,  495,  550. 

320. 

550. 

333,  411,  464,  550. 

333,  411,  527,  550,  576. 

333,  527. 

333,  527,  576. 

333,  527,  550,  576. 

294,  333,  47P,  495,  527,  550,  559,  569. 

294,  333,  461,  464,  495,  550,  569. 

294,  333,  461,  464,  550. 

333,  478,  495,  550,  569. 

294,  333,  495,  527,  550,  559,  576. 

333,  495,  527,  550,  559. 

294,  333,  495,  527,  550,  559. 

333,  550,  559,  576. 

527,  550. 

550. 


84 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  8B. -Synthetic   organic  chemicals:   Coal-tar  dyes   for  which  United  States  production  or   sales  were 
reported,    identified  by  manufacturer ,   195  J --Continued 


Colour 
Index  or 

Proto- 
type No. 


Man\if acturers '  identification  numbers 
(according  to  list  in  table  27) 


DYES  GROUPED  BY  PROTOTYPE  NUMBER — Continued 


9A- 
95 
96 
97 
99 
100 
101 
102 
107 
108 
109 
116 
118 
121 
122 
124 
125 
126 
129 
135 
137 
138 
139 
UO 
Ul 
U3 
144 
145 
146 
147 
148 
149 
151 
152 
157 
158 
162 
163 
164 
165 
166 
168 
169 
170 
171 
172 
173 
178 
181 
182 
186 
187 
188 
189 
191 
193 
194 
195 
197 
198 
201 
202 
203 
205 
206 
207 
208 
209 
210 


Diazo  'brown  3RB 

♦Diazo  fast  red  5BL 

»Diazo  fast  red  7BL 

Diazo  indigo  blue  4GL — 
Diazo  indigo  blue  4R1 — 

»Diazo  rubine  B 

Diazo  sky  blue  B 

Diazo  slcy  blue  3GL 

•Fast  mordant  blue  B 

Fast  scarlet  2G  base 

*Fast  scarlet  2G  salt 

Sirius  supra  brown  3R — 

Sirius  supra  gray  R 

Sirius  supra  orange  5G- 
Sirius  supra  yellow  5G- 

*Guinea  carmine  B 

*Guinea  fast  red  BL 

Guinea  fast  red  4BL 


Helindon  fast  scarlet  G 

Helindon  pink  B  ex 

«Helindon  pink  R  ex 

Indanthrene  brilliant  orange  RK- 

»Indanthrene  brown  BR 

•Indanthrene  brown  RHD 

♦Indanthrene  khaki  2G 

Indanthrene  rubine  R 


Indanthrene  yellow  brown  3G- 
Indo  carbon  CL 


Katigen  chrome  blue  5G — 

Metachrome  red  G 

Milling  orange  G — 

"Milling  yellow  H5G 

Milling  yellow  0 

Monochrome  blue  black  B- 

Naphthol  blue  black  S 

Neolan  black  WA 

»Neolan  blue  GG 

Neolan  Bordeaux  R 

Neolan  orange  R- 


■"Oxydiaminogen  OB 

•Paper  red  A  ex — - 

Pigment  green  B 

Polar  orange  GS 

•Polar  orange  R 

Pyrogene  orange  G-CF 

Pyrogene  violet  brown  X 

Pyrogene  yellow  brown  2RS-CF 

Rapidogen  blue  BN 

•Rapidogen  blue  D 

Rapidogen  Bordeaux  R 

Rapidogen  brown  GN 

•Rapidogen  red  GS 

•Rapidogen  red  RS 

•Rapidogen  scarlet  RS 

•Rapidogen  yellow  G 

•Rosanthrene  fast  Bordeaux  2BL 


•Rosanthrene  orange  R 

Sudan  brown  5B 

Sudan  orange  RT 

Sudan  red  BB 


Sulphon  orange  G 

•Sulphon  yellow  R 

Supra  light  rubine  BL 

Supramins  black  BR 

Supramine  Bordeaux  B 

Supramine  red  3B 

Supramine  red  2G 

Supramine  yellow  R — - — 

•Victoria  fast  violet  2R  ex- 

•Victoria  pure  blue  B 

•Zambesi  black  D 

•Zambesi  black  V 


Acid  anthracene  brown  KE- 
Acid  anthracene  brown  WSG — 

•Alizarin  fast  gray  BBLW 

Alizarin  supra  sky  R 

Alphanol  brown  B 

Amldo  naphthol  brown  3G— • — 
Anthralan  red  B-CF 


527,  550. 

294,  333, 

527. 

294,  333, 

527,  559, 

569, 

576. 

550. 

550. 

294,  550, 

559. 

550. 

550. 

424,  527. 

333,  552, 

583. 

376,  527, 

550,  552, 

559, 

576. 

550. 

550. 

550. 

527,  550. 

333,  495, 

550. 

294,  333, 

495,  527, 

550. 

333,  527, 

550. 

576. 

464. 

68,  333, 

464,  550, 

576. 

294,  333, 

527,  550. 

333,  464, 

527,  550, 

552. 

333,  464, 

495,  527, 

550, 

559, 

576. 

333,  365, 

527,  550. 

333,  527, 

550. 

527. 

250,  550. 

550. 

424. 

576. 

455,  495, 

527,  550, 

559, 

576. 

527,  550. 

495. 

527,  550. 

495,  527, 

550. 

294,  320, 

333,  464, 

495, 

527, 

550,  559,  576 

294,  495, 

527,  559. 

333,  495, 

527. 

411,  455, 

478,  495, 

527 

550, 

559,  569,  576 

333,  495, 

527,  550. 

550. 

495. 

294,  333, 

495,  527, 

550, 

495. 

495. 

495. 

68,  320, 

550,  559. 

68,  333, 

550,  559. 

320,  550, 

559. 

550,  559. 

68,  320, 

333,  464, 

495, 

527, 

550,  559. 

68,  320, 

333,  464, 

550, 

559. 

68,  320, 

333,  464, 

527, 

550, 

559. 

320,  333, 

464,  527, 

550 

559 

268,  294, 

333,  495, 

527 

550 

559,  576. 

333,  495, 

527,  550, 

559 

550. 

550. 

550. 

550,  576. 

294,  464, 

495,  550, 

559 

576. 

527,  550 

550,  576 

550. 

550,  576 

550. 

550. 

333,  464, 

495,  527, 

550 

76,  333, 

376,  550. 

495,  527 

550. 

333,  495 

527,  550 

550,  559 

550. 

294,  333 

365,  464, 

527 

550 

527,  550 

550. 

550. 

550. 

SYNTHETIC  ORGANIC  CHEMICALS,  1953  85 

TABLE  8b. -Synthetic  organic  chemicals:   Coal-tar  dyes   for  which  United  States  production   or  sales  were 
reported,    identified  by  manufacturer,    i95J--Continued 


211 

213 

21^ 

215 

216 

217 

218 

222 

223 

224 

227 

228 

229 

230 

231 

232 

234 

235 

236 

237 

238 

239 

241 

242 

243 

244 

245 

246 

247 

249 

250 

251 

252 

253 

254 

255 

256 

257 

258 

258 

259 

260 

260 

261 

264 

264 

265 

265 

266 

267 

269 

269 

270 

270 

271 

271 

272 

272 

273 

273 

274 

274 

275 

275 

276 

277 

278 

285 

288 

289 

290 

291 

292 

293 

295 
296 
298 
299 


DYES  GROUPED  BY  PROTOTYPE  NUMBER— Continued 


Azosol  fast  orange  G 

Azosol  fast  red  3B 

Azosol  fast  scarlet  CR— 
Azosol  fast  scarlet  CGG- 

Azosol  fast  yellow  GR 

Benzo  fast  Bordeaux  6BL- 
Benzo  fast  brovm  Rl- 


Brilliant  indocyanine  6B-CF — 

♦Brilliant  indocyanine  G 

Brilliant  sulpho  flavine  FFA- 

Celliton  fast  blue  FR 

«Celliton  fast  blue  FFR 

Celliton  fast  blue  green  B 

•Celliton  fast  brown  3R 

Celliton  fast  brown  5R 

Celliton  fast  navy  blue  B 

»Celliton  fast  pink  B 

*Celliton  fast  pink  FF3B 

«Celliton  fast  red  GG- 


«Celliton  fast  red  violet  RN- 

«Celliton  fast  rubine  B 

•Celliton  fast  rubine  3B 

Celliton  fast  violet  6B 

«Celliton  fast  yellow  G 

Celliton  fast  yellow  RR 

*Celliton  scarlet  B 

•Celliton  yellow  5G- 


•Chlorantine  fast  red  5BRL 

Chrome  fast  orange  3RL 

Dianil  yellow  5G 

Diazo  brown  3R- 


Diazo  fast  yellow  2G — 

Diazo  fast  yellow  3G — 

*Erio  chrome  brown  DKL- 

Erio  chrome  olive  BL — 

Fast  black  B  salt 

Fast  black  K  salt 

Fast  black  LB  base 

•Fast  blue  BB  base 

Fast  blue  BB  salt 

Fast  Bordeaux  BD  salt- 
»Fast  Bordeaux  GP  base- 
»Fast  Bordeaux  GP  salt- 
Fast  Corinth  V  salt 

Fast  orange  GC  base 

•Fast  orange  GC  salt 

Fast  orange  GR  base 

Fast  orange  GR  salt 

Fast  orange  RD  salt 

•Fast  red  AL  salt 

Fast  red  3GL  base 

•Fast  red  3GL  salt 

•Fast  red  KB  base 

•Fast  red  KB  salt 

•Fast  red  RC  base 

•Fast  red  RC  salt 

Fast  red  RL  base 

Fast  red  RL  salt 

Fast  red  TR  base 

•Fast  red  TR  salt- 


Fast  violet  B  base 

Fast  violet  B  salt 

Fast  yellow  GC  base 

Fast  yellow  GC  salt 

Sirius  supra  orange  GG 

Sirius  supra  red  violet  RL 

•Sirius  supra  turquoise  blue  GL- 
Immadlal  new  bl\ie  FBL  ex- 


Indanthrene  brilliant  violet  3B- 
Indanthrene  direct  black  RB- 


Indanthrene  golden  orange  3G- 


•Indanthrene  golden  yellow  GK- 

Indanthrene  golden  yellow  RK- 

•Indanthrene  olive  green  B 


Indanthrene  printing  black  BL- 
Indanthrene  red  FBB- 


Manuf aoturers '  identification  numbers 
(according  to  list  in  table  27) 


Metomega  chrome  brown  HLL- 
•Monochrome  black  blue  G 


550. 
550. 
550. 
550. 
550. 
550. 
527. 

527,  550. 
495,  527, 
527. 

320,  550. 
320,  424, 
320,  333, 
483,  550, 
550. 
576. 

320,  495, 
320,  333, 
320,  333, 
320,  333, 
320,  333, 
320,  333, 
320,  333, 
320,  333, 
576. 

320,  333, 
320,  483, 
294,  455, 
550,  559. 
527,  550. 
550. 

527,  550, 
550. 

495,  527, 
495. 

527,  550, 
550. 
550. 

320,  376, 
320,  550, 
550. 

376,  527, 
333,  376, 
550. 

376,  527, 
376,  550, 
527. 

376,  550, 
376,  550. 
527,  550, 
552,  576. 
376,  527, 
376,  464, 
320,  333, 
376,  550, 
320,  376, 
376,  550. 
376,  550. 
552. 

527,  550, 
320,  550. 
527,  550, 
552. 

550,  552. 
550. 

333,  550. 
268,  294, 
550. 
550. 

527,  550 
333,  366 
68,  333, 
365,  527 
268,  333 

576. 
527,  550 
527,  550, 
495. 
294,  333 


483,  495,  527,  550,  576. 

550. 

576. 


527,  576. 

550,  576. 

550,  576. 

550,  576. 

550. 

483,  495,  527,  550,  576. 

550. 

480,  483,  495,  550,  569,  576. 

483,  495,  527,  550,  576. 

550,  576. 

527,  550,  559,  569. 


559. 
550. 
559. 


550,  583. 
583. 

550,  552. 

550,  552,  559,  576. 

550,  552. 
552,  576. 

552. 

559,  576. 

550,  552,  559,  576,  583. 
527,  550,  552,  576,  578,  583. 
576. 

552,  576. 
550,  552,  576. 


576. 
576,  583. 

320,  333,  527,  550. 


527,  550. 
365,  527,  550,  559. 
550. 
365,  366,  456,  464,  527,  550,  552, 


495,  527,  550. 


86 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  8B, -Synthetic  organic  chemicals:   Coal-tar  dyes   for  which  United  States  production  or   sales  were 
reported,    identified  by  mar^u facturer ,   1953--Continued 


Colour 
Index  or 

Proto- 
type Ko. 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


DYES  GROUPED  BY  PROTOTYPE  NUMBER — Continued 


300 
301 
302 

303 
304 
305 

306 

307 

308 

309 

310 

311 

312 

313 

3U 

315 

316 

317 

318 

319 

321 

322* 

324 

325 

326 

327 

328 

329 

330 

332 

333 

334 

335 

336 

337 

339 

340 

341 

342 

343 

344 

345 

347 

348 

349 

350 

351 

352 

353 

357 

358 

360 

361 

364 

365 

366 

367 

368 

369 

370 

371 

372 

375 

376 

377 

378 

379 

381 

383 

385 

386 

387 

388 

389 

391 

393 


Monochrome  red  FG 

Monochrome  violet  FB- 
»Naphthol  AS 


»Naphthol  AS-BO- 
»Naphthol  AS-BR- 
♦Naphthol  AS-BS- 


♦Naphthol  AS-D 

Naphthol  AS-DB 

Naphthol  AS-E 

»Naphthol  AS-G 

»Naphthol  AS-ITR 

♦Naphthol  AS-OL 

»Naphthol  AS-RL 

*Naphthol  AS^SW 

»Naphthol  AS-TR 

Neolan  orange  G 

»Neolan  yellow  W. 

Omega  chrome  yellow  ME 

Palatine  fast  blue  BN 

Palatine  fast  blue  RRN 

Palatine  fast  green  BLN 

Palatine  fast  marine  blue  REN 

Palatine  fast  orange  GN 

Palatine  fast  orange  RN 

♦Palatine  fast  pink  BN 

Palatine  fast  red  RN 

Palatine  fast  violet  3RN 

Palatine  fast  violet  5RN 

Palatine  fast  yellow  ELN 

Pluto  black  G 

Pyrazol  fast  orange  GL 

Rapid  fast  orange  RH 

Rapid  fast  red  FGH 

Rapid  fast  red  RH- 


Rapid  fast  scarlet  ILH 

Rapidogen  black  MG 

Rapidogen  black  brown  IT 

♦Rapidogen  blue  N 

Rapidogen  blue  R 

Rapidogen  brown  IB 

Rapidogen  brown  IPT 

Rapidogen  golden  yellow  R ~ — 

Rapidogen  green  B 

Rapidogen  orange  G 

Rapidogen  orange  R- 


Rapidogen  red  violet  RE 

•Rapidogen  violet  B 

Rapidogen  yellow  G 

♦Rapidogen  yellow  2G 

Variamine  blue  BD  salt ~ 

Variamine  blue  RT  salt 

Acid  chrome  red  B 

Alizarin  rubinol  3G ~ 

Benzochrome  brown  B 

Benzochrome  brown  G ~ 


Benzo  fast  heliotrope  RRL — 

Brilliant  benzo  fast  violet  BL 

Brilliant  benzo  green  B 

Celliton  brilliant  yellow  FF 

Celliton  fast  pink  RF 

Chrome  leather  fast  black  S 

♦Cotonerol 

Diamond  black  P2B 

Diazo  brilliant  orange  GR 

♦Diazo  brilliant  scarlet  5BLN 

♦Fast  red  ITR  base 

♦Sirius  supra  gray  VGL— ~ 

Indanthrene  orange  4R — 

Janus  black  G 

Naphthol  AS-BG 

Naphthol  AS-GR— 

Naphthol  AS-LB 

Naphthol  AS-SG 

Noolan  pink  B ~ ■ 

Neolan  red  GRE 

Oxamine  brilliant  red  B-— 


11,  550. 
550. 
333,  376, 

578. 
333,  376, 
376,  486, 
333,  376, 
578,  X. 
333,  376, 
578,  X. 
376,  550. 
376,  486, 
333,  376, 
376,  486, 
333,  376, 
333,  376, 
333,  376, 
486,  527, 
495,  550, 
294,  333, 
495. 

464,  550, 
294,  569. 
495,  527, 
294,  320, 
464. 

294,  550. 
294,  320, 
550. 
550. 

464,  550. 
294,  495, 
411. 
495. 

464,  550. 
550. 
550. 

550. 

550. 

550. 

320,  333, 

550. 

550. 

550,  559. 
464,  527, 

550,  559. 

550,  559. 

320,  527, 

550,  559. 

68,  320, 

68,  550. 

68,  320, 

550,  552, 

550. 

550. 

550. 

550. 

550. 

527,  550. 

527,  550. 

527,  550. 

527,  550. 

333,  550. 

550. 

320,  333, 

550. 

550. 

333,  550, 

320,  376, 

294,  527, 

333,  550. 

550. 

376,  550. 

550. 

550. 

376,  550, 

495,  527, 

294,  495. 

527,  550. 


464,  486,  527,  550,  559, 


464,  486, 
505,  527, 
464,  486, 


550,  576, 
576,  578. 
550,  559, 


464,  486,  527,  550,  559, 


494, 
583. 
527, 
550, 
527, 
576. 


527,  550. 

464,  486, 

550,  578, 

464,  486, 

486,  527, 

464,  486, 

550,  552, 
559. 

495,  527, 

559. 

550,  559. 
527,  559. 


333,  464,  550,  559. 


527,  550, 

550,  559, 
576. 

550,  559, 


563,  576, 
578. 

563,  576, 

563,  576, 

559,  576. 
563,  576,  X. 
576,  578. 


550,  559. 


464,  527,  550,  559. 


550. 
550,  559. 


333,  464, 
583. 


559. 
550. 
550. 


559. 
550. 


SYNTHETIC  ORGANIC  CHEMICALS,  I953 


87 


TABLE  SB. --Synthetic 


rganic  chemicals:   Coal-tar  dyes    foe  which  United  States  product  ion  or  sales   were 
reported,    identified  by  manufacturer,    1953- -Continued 


DYES  GROUPED  BY  PROTOTYPE  NUMBER— Continued 


Palatine  fast  claret  BN- 

Para  brovm  V 

Permanent  carmine  FB 

Rapid  fast  brown  lEH 

Rapid  fast  scarlet  RH 

Rapidogen  red  ITR 

Rapidogen  scarlet  IL 

Rosanthrene  Bordeaux  B — 

Acid  chrome  blue  3G 

Algol  scarlet  B 

Azo  rubinol  3GP 

Azosol  fast  blue  HL 

Azosol  fast  green  HL 

Benzo  fast  gray  BL- 


Brilliant  congo  blue  BFL 

Brilliant  wool  blue  Q 

Celliton  fast  yellow  70 

•Chlorantine  fast  Bordeaux  2B — 
Chlorantine  fast  Bordeaux  BLL- 

Chlorantine  fast  brown  8RLL 

Chlorantine  fast  gray  RLN 

Chlorantine  fast  green  BLL 

Chlorantine  fast  orange  TARIL- 
Chlorantine  fast  orange  T5HLL- 

»Chlorantine  fast  red  6BLL 

Chlorantine  fast  violet  5BL 

Chlorantine  fast  violet  Rll, 

•Chlorazol  blue  5GKS 

Derma  brown  G 

Diazanil  orange  RR 

Diazo  brilliant  blue  2BL 

Diazo  fast  Bordeaux  FBL 

Fast  scarlet  TR  base 

Sirius  light  blue  FBGL 

Indanthrene  orange  F3R 

Indanthrene  red  brown  R 


Indanthrene  red  brown  5RF 

Indanthrene  scarlet  R 

Indanthrene  yellow  FFRK 

Indanthrene  yellow  GF 

Indanthrene  yellow  3R 

Kiton  fast  red  4BLN 

Metomega  chrome  brown  3GL 

Metomega  chrome  orange  ML 

Metomega  chrome  red  GM 

Monochrome  olive  FBBL 

Naphthol  AS-LC- 


Naphthoohrome  violet  R- 
Neolan  blue  2R 


Neolan  orange  GRE 

Rapidogen  golden  yellow  IFG 

Rapidogen  red  IGG 

Rapidogen  yellow  UO 

Diphenyl  fast  blue  green  BL 

Sudan  red  GG 

Sudan  yellow  QRN 

Suprajnlne  yellow  3GL 

Chromoxane  brilliant  violet  SB- 
Alizarin  light  blue  4GL 

Azosol  fast  red  BE 

Brilliant  indo  blue  5GL 

Chloramlne  fast  orange  2RN — - — 

•Chlorantine  fast  violet  2RL 

Cloth  fast  yellow  5G 

Diazo  brilliant  scarlet  ROL 

Diazo  fast  yellow  3GLL 

Diphenyl  fast  blue  red  R 

Erganil  gray  BC 

Fast  blue  RR  base 

Fast  blue  RR  salt 

Fast  Corinth  LB  salt 

Fast  red  FR  salt 

Fast  red  PDC  base 

»Fast  red  PDC  salt 


Indanthrene  red  violet  RRN- 

Leather  brown  ET 

Naphthol  AS-LG 

Naphthol  AS-LT- 


Neolan  red  BRE 


Manuf act  j'"ers '  identification  numbers 
(according  to  list  in  table  27) 


^S,  550. 


495, 
569. 


495, 
527. 


320, 
527. 


550. 
569. 


527, 
550. 


550. 

333,  478,  495,  527,  559,  569. 

478,  495,  527,  550. 


550. 
527. 
495. 


478,  495,  523. 
527. 


550,  583. 
559,  583. 
550. 


88 


UNITED  STATES  TARIFF  COMMISSION 


tabu;  SB. -Synthetic  organic  chemicals:   Coal-tar  dyes    for  which  United  States  production  or  sales  were 
reported,    identified  by  manufacturer,    J953--Continued 


Colour 
Index  or 

Proto- 
type No. 


Dye 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


DYES  GROUPED  BY  PROTOTYPE  NIMBER — Continued 

Rapidogen  corinth  IB 

Sirius  supra  rubine  BB 

Xylene  fast  orange  PO 

Acid  alizarin  black  KGW 

Acid  leather  brovm  EGB 

Alizarin  saphirol  WSA 

Buffalo  black  X 

Caloofast  spirit  orange  RN 

Caledon  dark  blue  G 

Cellitazol  AZN 

Chloramine  copper  blue  3G 

Chlorantine  fast  yellow  2GIJ. 

Chrome  fast  green  G 

Diaminogen  blue  NA 

Diazo  fast  green  GF 

Diazo  fast  violet  BL 

^Direct  chinoline 

Dispersol  fast  yellow  2G 

Durazol  fast  blue  3RS 

Durazol  fast  orange  R — 

Eastman  fast  yellow  GLF 

Eastone  blue  BGF 

Erie  fast  rubine  B 

Fast  brown  salt  VA 

Guinea  brown  RD 

Iramedial  black  brown  A 

»Indanthrene  olive  T 

Indanthrene  yellow  3GF 

Interchem  acetate  orange  4R 

Leather  brown  5RTX 

Luxol  brilliant  green  BL 

Luxol  fast  blue  MBS 

Naphthol  AS-L3G 

»Naphthol  AS-MX 

»Naphthol  AS-PH 

Neolan  dark  green  B 

•Neutral  brown  RX 

Pontamine  black  AWG 

Pontamine  diazo  brown  R 

Pontamine  diazo  orange 

Pontamine  diazo  orange  3G 

♦Pontamine  navy  blue  DB 

Rapidogen  black  3G 

Rapidogen  blue  PBN 

Sirius  supra  brown  2RL 

Sirius  supra  orange  RRL 

Sirius  supra  scarlet  GO 

»Solantine  orange  Mi 

Supranol  brown  3GL 

Wool  black  GRF 

•Sirius  supra  yellow  R  ex 

Direct  brown  RG 

Direct  fast  yellow  3GP 

UNGROUPED  DYES 

•Acetate  rayon  dyes : ^ 

•Black,  IV  ex.,  B,  BNF,  DB,  EC,  G,  3G,  GGN, 

GS,  GY,  J,  LNB,  NC,  RB,  HK,  SDP,  SS.^ 
•Blue,  #15,  #40,  A8-7,  A8-45,  AGF,  B,  2B, 

BGLF,  BN,  BNN,  BP,  CR,  EC,  G,  2G,  GBN,  GE, 
GFD,  GLF,  GLT,  GLT-NS,  2GN,  GP,  CR,   LB, 
ID,  M,  MJ,  NBN,  NVC,  NVY,  HB,  RDA,  RG,  R, 
2R,  3R,  WNBN.^ 

Brown  #8,  JG,  R • 

Orange,  I,  III,  FSI,  GR,  GRN,  R,  2R,  3R, 
RD-GLF,  2RP.* 

Pink  MBS 

•Red  III,  VI-X,  B,  2B,  ABLL,   2B-GLF,  C,  FSI, 

G,  GLF,  LRB,  NB,  R,  RP,  WLF-40,  Y,  YP.' 
•Violet  3B,  7BC,  BGF,  BN,  MB,  2R,  4R,  3RGFL, 
5RLF. 

•Yellow  B,  CW,  FSI,  G.  50,  8GLF,  GL,  GN,  CR, 
IX,  M,  N,  RN,  4RL.* 

Acid  alizarin  Bordeaux  BLT 

Acid  alizarin  brown  RLL 

Acid  anthracene  brown  TBL 

Acid  black  AR,  SB,  CStF,  N,  RB 

See  footnotes  at  end  of  table. 


511 
512 
513 
5U 
515 
516 
519 
520 
522 
523 
52-4 
526 
527 
529 
530 
531 
533 
534 
535 
536 
537 
538 
539 
540 
543 
545 
547 
549 
551 
552 
553 
554 
555 
556 
557 
560 
562 
565 
566 
567 
568 
569 
571 
572 
575 
576 
577 
578 
579 
581 
582 
598 
622 


550. 
455, 
527. 
495. 
550. 
333, 
527. 
464, 
333. 
333, 
495, 
495. 
495, 
333, 
550. 
527, 
464, 
333. 
333. 
333. 
320, 
483. 
333, 
550. 
550. 
550. 
268, 
527. 
320. 
550. 
333, 
527, 
550. 
376, 
333, 
495. 
294, 
333, 
333, 
333, 
333. 
333, 
550. 
550. 
550. 
550. 
527. 
320, 
550. 
495. 
268, 
495. 
495. 


527,  550. 


550. 
550. 


483,  550. 
550. 


527. 
527. 


550,  559. 
527,  550. 


483. 
527,  569. 


294,  333,  365,  366,  456,  527,  550,  576. 


550. 
554. 

486,  550,  576,  578. 
376,  486,  550,  578. 

333,  495,  527. 

527. 

550. 

527. 

411,  464,  495,  527. 


455,  478,  495,  527. 

294,  320,  455,  495,  527,  550,  559,  569. 


320,  333,  411,  483,  495,  527,  550,  576. 
320,  333,  483,  527,  550,  576,  578. 


320,  483. 

320,  333,  411,  483,  527,  569,  576. 


320,  333,  411,  483,  495,  527,  569,  576. 

320,  333,  483,  495,  527. 

320,  483,  576. 

320,  333,  483,  495,  527,  550,  576. 

550. 
550. 
550. 
333,  527,  550. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


89 


TABl£  8B. --Synf/ietic  organic  chemicals:   Coal-tar  dyes   for  which  United  States  production  or   sales  were 
reported,    identified  l>y  manufacturer ,   i95J--Continued 


Dye 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


UNGROUPED  DYES— Continued 


Acid  blue  G 

Acid  blue  black  A- 
Aoid  Bordeaux  MB — 


Acid  brilliant  blue  RE 

Acid  brilliant  red  33 

Acid  brown  GRTA,  3G,  OR,  ITGA,  M130,  NY,  PGMA, 
2R,  RD. 

Acid  dark  brown  B 

Acid  dark  green  B — 

Acid  fast  brown  CGS 

Acid  green  G 

Acid  leather  brown 

Acid  metalized  blue  NB 

Acid  milling  orange  "iR 

Acid  navy  B,  FN 

Acid  navy  blue — 


»Aoid  orange  NR,  R,   2R 

Acid  red  B,   2B,   3B,  BR,   G,  RB,   3RB- 

Acid  sapphire  G 

Acid  scarlet  GN 


«Acid  violet  MR,  R,  2R,  3RL,  RNL- 
Acid  yellow  3G,  6G,  NR,  NW,  3RD- 

Alizarin  blue  GS 

Alizarin  sapphire  EMM 

Alizarin  violet  NRR 

Alphazurine  B 


Anthracene  chrome  brown  RL 

Anthraquinone  blue  BGA,  3G,  2GA,  4GL,  RA 

Anthraquinone  vat  black  BBN,  2G,  J,  R 

Anthraquinone  vat  black  brown  VA 

Anthraquinone  vat  blue  BCL,  GR 

Anthraquinone  vat  blue  green  3B,  FEB,  Y 

Anthraquinone  vat  brilliant  red  B 

Anthraquinone  vat  brilliant  violet  3R 

Anthraquinone  vat  brilliant  yellow  3G,  AG,   5G — 

Anthraquinone  vat  brown  BN,  NR,  VR- 

Anthraquinone  vat  copper  brown 

Anthraquinone  vat  direct  black  DB,  3G,  3GA,  HP- 

Anthraquinone  vat  fast  yellow 

Anthraquinone  vat  golden  orange  4G 

♦Anthraquinone  vat  gray  BR,  2G,  GEL,  GNF,  MEM, 
R. 
Anthraquinone  vat  navy  blue  BN 

•Anthraquinone  vat  olive  G,  2GL,  2GLD,  T,  TC, 
TR. 
Anthraquinone  vat  orange  RK- 


Anthraquinone  vat  printing  black  BBD,  PG,  R 

Anthraquinone  vat  red  EG,  RL,  RRB 

Anthraquinone  vat  red  brown  N,  RB 

Anthraquinone  vat  scarlet  3GA,  GL ^ 

Anthraquinone  vat  yellow  8G,  5GLL,  K,  LN,  PO 

Anthraquinone  vat,  other 

Anthraquinone  violet  A 

Aviation  blue 

Azo  black  NV 

Azo  blue  G ..-_ 


Azo  brilliant  blue  RS — 
Azo  brilliant  violet  0- 

Azo  brown  BY,  RRK 

Azo  cardinal  WE 

Azo  cerisine  B 

Azo  dark  brown  EW — 

Azo  eosine  2B — 

Azo  fast  yellow  G 

Azo  golden  orange  R 

Azo  green  FB,  EFV,  G 

Azo  navy  BR,  CW,  LN 

Azo  oil  black 


Azo  oil  blue  black  B 

Azo  olive  green  BLN 

Azo  orange  BRS,  GR,  RNC,  RXA- 

Azo  royal  blue  L,  S 

Azo  rubine  B,  S 

Azo  scarlet  0 

Azo  turquoise  B 

Azo  violet  R 

Azo  wine  WE 

Azo  yellow  DW,  S 


333. 
550. 
550. 
333. 
559. 
333,  550. 


333. 
333. 

333. 

11. 

550. 

464. 

411. 

464. 

333, 

333, 

523. 

559. 

llj 

333, 

527. 

527. 

527. 

527. 

424. 

333. 

464, 

550. 

527, 

333, 

333. 

333. 

333, 

333, 

464. 

333, 

464. 

333. 

333, 


550,  559. 
527,  559. 


333,  411,  424,  550. 
550,  559. 


527,  576. 


550. 
550,  576. 


550. 
527. 


550,  576. 

464,  527,  550,  576. 


576. 

333,  464,  552. 

576. 

527,  576. 

333. 

333. 

333,  550. 

333,  527. 

250. 

333. 

464. 

523. 

523. 

523. 

523. 

523,  559. 

523. 

464. 

523. 

333. 

523. 

523. 

523,  559. 

523. 

527. 

527. 

559. 

559. 

523. 

523. 

523. 

523. 

559. 

523. 

523. 


313486  O  -  54  -  7 


90 


UNITED  STATES  TARIFF  COMMISSION 


TA3LE  SB. --Synthetic   organic  chemicals:   Coal-tar  dyes    for  which  United  States  production  or 
reported ,    identified  by  manufacturer ,    i95J--Continued 


Colour 
Index  or 

Proto- 
type No. 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


UNGROUPED  DYES— Continued 

»Azoic  dyes  and  their  ooinponents: '' 
Dyes,  rapidogen: 

Black  BR,  DM,  ITA,  MR 

Blue  B,  2B,  PEN,  PBR,  R- 

Bordeaux  AF,  MR 

Brown  INR,  Y 

Dark  brown  AR 

Fast  red  B 

Garnet  0 


Golden  yellow  ms 

Gray  R 

Midnight  blue- 
Navy  blue  F,  FFR- 
Orange  FFR,  MG,  N- 


Red  3B,  2BN,  C,  FB,  FFBB,  FFG,  FFR,  KBS, 

RC,  SW. 
Scarlet  FFG,  FFR,  2G,  2H 

Violet  B,  SW 

Yellow  AGL 

Components: 

Fast  color  bases: 

Garnet  GBCP,  GC 

Ponceau  L 

Red  FB 


Fast  color  salts: 

Blue  RBN 

Ponceau  L 

Variamine  blue  FG 

Fur  dyes:  Fur  #2,  #<i,  BCA,  NZA,  NZF- 

Naphthols : 

Naphthol  AS-AAP 

Naphthol  AS-BGN 

Naphthol  AS-BN 

Naphthol  AS-EL 

Naphthol  AS-HB 

Naphthol  AS-KB 

Naphthol  AS-OP 

Naphthol  AS-PN 

Naphthol  AS-RO- 
Naphthol  AS-ST- 


Azosol  brilliant  blue  B 

Azosol  fast  brilliant  red  BN 

Basic  blue  OB 

Basic  red  AO 

Basic  yellow  OL 

Benzo  fast  copper  brown  BRL 

Benzo  fast  copper  yellow  2GL 

Benzo  fast  gray  BL 

Brilliant  cyanine  green  5G 

Brilliant  oil  blue  BMA 

Brilliant  rayon  blue  J 

Brilliant  violet  R 

Canary  lake  yellow  PL 

Celliton  yellow  6D 

Chloramine  brilliant  orange  RS — - 

Chlorantine  fast  green  5GLL 

Chromate  brown  R,  RL 

Chrome  black  3G — — — 

Chrome  blue  G — ~ 

Chrome  brilliant  pink  3B — 

Chrome  brown  B 

Chrome  cyanine  BLL — 

Chrome  garnet  GR ~ 

Chrome  gray  BL- 

Chrome  green  B,  CB,  SP 

Ciirome  orange  2G,  LC,  3R — 
tKIhrome  yellow  2GN,  LL,  SW- 

Chromolan  gray  G 

Chromolan  violet  2H ~ — 

Cupramine  brown  B ■ 

Cupramine  orange  RB-— -— 

Cupramine  red  BX — 

Dark  brown  B 

Developed  blue  BR- 


Deve loped  brown  CBS 

Developed  orar.ge  RIV,  WD — 
Developed  red  BFV- 


333, 
376, 
320, 
550, 
333. 
A6A. 
376. 
333. 
550, 
550. 
550, 
333, 
320, 


550,  559. 

550,  559. 

333,  559. 
559. 


559. 

550,  559. 

333,  376,  550,  559. 


Developed  scarlet  FW,  GFtf- 
See  footnotes  at  end  of  table. 


376,  550,  559. 
320,  376. 
333. 


333. 

12,  376,  552. 

576. 

455. 

559. 
576. 
550. 
294. 

333. 

376. 

550. 

376. 

376. 

376,  486,  550,  559. 

559. 

464. 

527. 

550. 

550. 

550. 

333. 

333. 

333. 

550. 

550. 

333. 

365. 

527. 

523. 

576. 

527. 

550. 

495. 

495. 

294,  424. 

527. 

11. 

333. 

527. 

527. 

11. 

424. 

424,  527. 

333,  464,  527. 

333,  523,  527. 

527. 

527. 

523. 

523. 

523. 

333. 

576. 

527. 

527. 

527. 

527. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


91 


TABLE  SB. -Synthetic  organic  chemicals:   Coal-tar  dyes   for  which  United  States  production  or  sales  wer 
reported,    identified  by  manufacturer ,    7953- -Continued 


Dye 


UNGROUPED  DYES — Continued 


Developed  violet  BED 

Diamine  oateohine  ER,  6CiA- 

Diazo  blue  3G,  6G,  5GL 

Diazo  Bordeaux  RLN- 


Diazo  brilliant  orange  GGA — 
Diazo  brilliant  scarlet  2GA- 
Diazo  brown  6G — 


Diazo  fast  violet  BL 

Diazo  green  BL,  2GL 

Diazo  orange  G,  CR,   LGA,  N,  RG,  RR,  WD- 

Diazo  scarlet  P 

Diazo  violet  RR 

Diazo  yellow  2GL — 
Diazophen  red  BTB- 


Diazophen  yellow  BTP 

(Direct  black  CW,  3G,  5G,  GN,  3GR,  HH,  RCW,  RW 

*Direct  blue  B,  BBL,  BFL,  BLU,  lOBLU,  BW,  CF, 
CF2B,  FBLL,  2GF1,  GL,  3GLL,  -iGLL,  8GLN,  ^U, 
SGUF,  LBLL,  LDU,  LGLL,  NPC,  MR,  RDW,  2RCF, 
3RCF,  RFL,  2RFL,  RL,  Rllf,  2RLU,  2RLCF,  TRLL, 
VES. 

Direct  blue  green  CW 

Direct  Bordeaux  B,  BH 

Direct  brilliant  blue  lOBLL,  12BLL,  16BLL 

Direct  brilliant  brown  S 

Direct  brilliant  cerise 

Direct  brilliant  violet  •4B,  R- 


(Direct  brown  OR,  CWE,  GB,  3GS,  MRS,  RB,  3RLL, 

Direct  oatechine  2EAC -— — — 

Direct  copper  black  brown — • — 

Direct  diazo  blue  NA — ■ — 


Direct  diazo  orange  RG 

Direct  fast  black  GRNX 

(Direct  fast  blue  BLL,  2BRN,  CPL,  GLFV,  7GLL, 
8GLL,  GSS,  L5GA,  L5R,  RL,  3RL,  SFGL,  SFRL. 
Direct  fast  brilliant  blue  L8GA. 

»Direot  fast  brown  4GL,  5GLL,  R,  AR,   2RL,  3RL, 
4RL,  8RL,  SKRL,  3YL. 

Direct  fast  copper  blue  EG,  R 

Direct  fast  gray  3BL,  2GL,  3GL " 

Direct  fast  heliotrope  B,  FFB 

•Direct  fast  orange  G,  2G,  5GC,  GL,  2GL,  4GLL, 
L8GL,  R. 

(Direct  fast  red  3BL,  8BLN,  7B^^:-,  lABL,   RL,  WL — 

Direct  fast  rubine  BBLL,  WL 

Direct  fast  violet  BL,  ABL,  R 

KDireot  fast  yellow  5G,  3GL,  3GU,  L2RX,  L3RX,  RL, 
S5GP. 

Direct  garnet  RB,  RD 

Direct  gray  BBC,  CSL,  2GLU,  3LUF,  LVL,  LVLU, 
UFLL. 

Direct  green  B,  GB,  5GSC,  2Y 

Direct  luniisol  blue  GL,  L,  RL 

Direct  lumisol  gray  G 

Direct  lumisol  violet  "iRL — — 

Direct  maroon  LFS,  LFVS- 


Manuf acturers '  identification  numbers 
(according  to  list  in  table  27) 


»Direct  orange  C,  DB,  F3R,  GFL,  5GFL,  2GLL,  2GU, 
6GUF,  LR,  3LWF,  2R,  RT. 

Direct  red  7B,  9B,  5BL,  8BLN,  5BLU,  3BW 

Direct  rubine  BB,  SB 

Direct  scarlet  B,  BCW,  G 

Direct  silk  blue  NR 

Direct  sky  blue  FF 

Direct  violet  BCW,  2R 

Direct  violet  blaok- 


*Direct  white,  ACC,  AW,  B,  4B,  5B,  5BM,  2G,  MR, 
M2R,  2R,  3R,  RN,  RW,  SC,  WT. 

Direct  yellow  EFC,  G,  3G 

Euohrysine  2GA 


Fast  acid  orange  RW — — — 

Fast  acid  red 


576. 
550. 
333. 
333. 
550. 
550. 
333. 
333. 
333. 
333, 
333. 
333. 
333. 
464. 
464. 
411, 
320, 


Fast  acid  yellow  GS,  RL- 

Fast  black  FTC,  G 

Fast  blue  2B 


Fast  Bordeaux  BN,  RB 

Fast  brilliant  crimson  RB- 

Faat  brown  FN,  MF 

Fast  crimson  R— — — — — - 


550,  569. 


495,  523. 

464,  478,  495,  509,  523,  527,  559,  576. 


527. 

320,  527. 

523. 

527. 

464. 

464,  576. 

333,  411,  464,  523,  527,  576. 

527. 
527. 
569. 
569. 
569. 
294,  333,  527,  550,  569. 

550. 

333,  527,  569. 


527. 
294, 
320, 
294, 


333. 
333. 
333,  527,  550,  569. 


294, 

333, 

411, 

455, 

523, 

550, 

576. 

411, 

569. 

333, 

527. 

333, 

509, 

527, 

559, 

569. 

527, 

576. 

320, 

523, 

527. 

333, 

464, 

527, 

576. 

495. 

495. 

495. 

523. 

333, 

464, 

478, 

509, 

523, 

559, 

569 

320, 

523, 

559. 

523, 

559. 

523, 

576. 

550. 

333. 

320, 

527, 

559, 

576. 

495. 

117, 

333, 

376, 

464, 

527, 

550, 

559 

523, 

559. 

550. 

495. 

569. 

333, 

527. 

464, 

576. 

294. 

464. 

527. 

464. 

527 

92  UNITED  STATES  TARIFF  COMMISSION 

TABLE  SB. --Synthetic  organic  chemicals:  Coal-tar  dyes   for  which  United  States  production  or  sales  were 
reported,    identified  by  manufacturer  ,    J95J- -Continued 


Colour 
Index  or 

Proto- 
type No. 


Dye 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


UNGROUPED  DYES — Continued 


Fast  olive  brown  G 

Fast  orange  LW,  YF 

Fast  spirit  black  RB 

Fast  spirit  brown  GN 

Fast  spirit  yellow  G,  2RN- 

Fast  wool  yellow  GL 

Fast  yellow  G,  2G,  N 

Fiber  black  V 

Fluorescent  green  Htf 

Fluorescent  yellow  HEB 

Fluorol  5G,  VGA,  OBR 

Formaldehyde  scarlet  Y 

Formalide  brown  RD 

Formalide  deep  blue  R 

Gasoline  yellow 

Indigo  blue 

Ink  blue  ASB,  PP 

losol  black 

losol  blue,  6G 

losol  green 

losol  orange 

losol  red 

losol  violet 

losol  yellow 

Jet  black  AFX 

Leather  brown  5RT 

Levelling  blue  2R 

Methyl  violet  base  oleate- 

Milling  blue  BL 

Milling  orange  RN 

Milling  red  brown 

Milling  yellow  GN,  XN 

Naphthol  navy  blue  M 

Navy  blue  G 


Neutral  black  BSS 

Neutral  brown  RD 

Neutral  dark  brown  H- 
Neutral  red  3G 


Neutral  silk  brown  G,  0,  R,  RG 

Neutral  silk  yellow  CGA,  SX 

Nydye  blue  GB 

Nydye  brilliant  red  3B 

Nydye  orange  2R 

Nydye  scarlet  G 

Nydye  violet  BX 

Oil  blue  A,  NE 

Oil  brown  #79,  #102,  D,  M,  Y 

Oil  fast  blue  R 

«Oil  orange,  #30,  MT 

Oil  pink  B 

•Oil  red,  #322,  DB,  EGN,  N-1700,  0,  OB,  HO 

Oil  yellow,  PHW 

Olive  brown  RL 

Palatine  fast  blue  5RNA 

Palatine  fast  yellow  5GN 

Permanent  brown  FR 

Pluto  orange  GRA 

Quinoline  yellow  P 

Resin  brilliant  red  R 

Resin  brown  Z — — 

Resin  dark  red  Z 

Resin  scarlet  2R -___ — 

Rhodamine  B  stearate ■ 

Rosanthrene  orange  R 

Silk  red  4B 

Soga  yellow  A 

Spirit-soluble  blue 


Spirit-soluble  brown  2RS 

Spirit-soluble  fast  black 

Spirit-soluble  fast  blue  B 

Spirit-soluble  fast  green  B 

Spirit-soluble  fast  orange  A — 
Spirit-soluble  fast  red  M,  Y — 
Spirit-soluble  fast  yellow  3G- 

Spirit-soluble  green 

Spirit-soluble  orange  M,  RS 

Spirit-soluble  red  MS 

Spirit-soluble  red  brown  NR 

Spirit-soluble  scarlet  MC 


464. 

464,  576. 

464. 

464. 

464. 

527. 

294,  464,  569 

495. 

168. 

464. 

550. 

495. 

411. 

411. 

464. 

576. 

527,  550. 

527. 

527. 

527. 

527. 

527. 

527. 

527. 

333. 

527. 

576. 

464. 

333. 

333. 

527. 

333,  527. 

495. 

576. 

527. 

527. 

411. 

576. 

523. 

294,  523. 

523. 

523. 

523. 

523. 

523. 

333 

12, 

576.  ■ 

12,  464,  467 

527. 

12, 

464, 

576. 

550. 

550. 

550. 

550. 

333. 

527. 

527. 

527. 

527. 

464. 

333. 

495. 

550. 

424. 

527. 

527. 

527. 

527. 

527. 

527. 

527. 

424. 

527. 

527. 

527. 

527. 


,  464. 
527. 


464,  467,  527,  576. 
467. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953  93 

TABLE  83.  -Synthetic  organic  chemicals:   Coal-tar  dyes   for  which  United  States  production  or  sales  were 
reported,    identified  by  manufacturer ,    1953- -Continued 


Colour 
Index  or 

Proto- 
type No. 


Dye 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


UNGROUPED  DYES— Continued 


Spirit-soluble  violet  MR 

Spirit-soluble  yellow  CS.,   MGS- 

Stilbene  orange  E3G 

Sudan  oorlnth  3B 

Sudan  dark  brown  BG 

Sudan  orange  FL 

Sudan  yellow  GRA 

Synlan  black 

Toluylene  fast  brown  3GA 

Vat  black 

Vat  maroon  3N 

Vat  pink  FG 

Vat  printing  black  GR 

Vat  red  2B 

Vat  scarlet  G,  GX,  GXS 

Water  black  SR 

All  other 


527. 
527. 
46^. 
550. 
550. 
550. 
550. 
495. 
550. 

550. 
333. 
527. 
448. 
333. 
464. 
333. 


^  Excludes  acetate  rayon  dyes  that  appear  under  "Dyes  Grouped  by  Prototype  Number." 
^  Includes  developed  black  and  diazo  black. 
^   Includes  brilliant  blue  and  navy  blue. 
*  Includes  golden  orange  and  monocel  orange. 
'  Includes  monocel  red  rubine  and  scarlet. 
'  Includes  fast  yellow,  golden  yellow,  and  printing  yellow. 

''  Does  not  include  azoic  dyes  and  their  components  that  appear  under  "Dyes  Grouped  by  Colour  Index 
Number,"  and  "Dyes  Grouped  by  Prototype  Number." 


94 


UNITED  STATES  TARIFF  COMMISSION 
Toners  and  Lakes 


TABLE  15b. --Synf/ietic  organic   chemicals:    Ton 
reported,    i 


and  lakes    for  which  United  States  production  or   sales   were 
titled  by  manufacturer ,    1953 


[Toners  and  lakes  for  which  separate  statistics  are  given  in  table  15A  are  marked  below  with  an  asterisk 
(») ;  those  not  so  marked  do  not  appear  in  table  15A  because  the  reported  data  are  confidential  and  may 
not  be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from  table  27.  An  X 
signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number  with 
the  designated  product] 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


TONERS  OR  FULL-STRENGTH  COLORS 


»Black  toners: 
Aniline  black- 

PMA  black 

PTA  black 


*Blue  toners: 

■K-Alkali  blue  (C.I.  704)- 

Dianisidine  blue 

Indanthrene  blue- 


Indanthrene  blue  GCD  (C.I.  1113) 

PTA  Peacock  blue  GG- 


«PMA  Peacock  blue  R  (C.I.  6i>A) 

»PTA  Peacock  blue  R  (C.I.  664) 

*Phthalocyanine  blue  B  (Pr.  481) 


Phthalocyanine  blue  B,  resinated  (Pr.  481)- 

Phthalocyanine  blue  G  (Pr.  482) 

Phthalocyanine  blue  R 

Pigment  blue  WNL- 


»PMA  Setoglaucine  (Peacock  blue  G)  (C.I.  658)- 
»PTA  Setoglaucine  (Peacock  blue  G)  (C.I.  658)- 
»PMA  Victoria  blue  B  (C.I.  729)- 


»PTA  Victoria  blue  B  (C.I.  729) 

PMA  Victoria  blue  R  (C.I.  728) 

PTA  Victoria  blue  R  (C.I.  728) 

»PMA  Victoria  pure  blue  B  (Pr.  198) 


«PTA  Victoria  pure  blue  B  (Pr.  198)- 


All  other 

Brown  toners : 
Bismarck  brown- 
PMA  Brown 


Gun  metal  brown- 
Havana  brown 

Para  brown 


Toner  browns 

»Green  toners: 

*PMA  Brilliant  green  (C.I.  662)- 
»PTA  Brilliant  green  (C.I.  662)- 


662)  and  thioflavine 
662)  and  thioflavine 


657)- 
657)- 


PMA  Brilliant  green  (C.I. 

(C.I.  815). 

PTA  Brilliant  green  (C.I. 
(C.I.  815). 

*PMA  Malachite  green  (C.I. 

■»PTA  Malachite  green  (C.I. 


PMA  Malachite  green  (C.I.  657)  and  thioflavine 

(C.I.  815). 
PTA  Malachite  green  (C.I.  657)  and  thioflavine 

(C.I.  815). 
PTA  Malachite  green  (C.I.  657)  and  auramine 

(C.I.  655). 
PMA  Peacock  blue  GO  and  thioflavine  (C.I.  815)- 

Pr.  483,  Phthalocyanine  green — 

»Pr;  149,  Pigment  green  B 

All  other 


»Maroon  toners: 

Helio  Bordeaux  (C.I. 


84)- 


Helio  Bordeaux  BL  <Pr.  110)- 
Helio  fast  rubine- 


*^-Hydroxynaphthoic  maroon  (B.O.N,  maroon) 
(Lithol  maroon) . 
Indanthrene  maroon ______ 


Lithol  red  3G,  manganese  toner- 
Naphthol  AS-D  (Pr.  306)- 


C . I .  82 ,  a -Naphthylamine  maroon- 

*Toluidlne  maroon 

All  other 


»0range  toners: 

^Benzidine  orange — — 
Dianisidlne  orange- 


»2,4-Dinitroanlline  orange- 
Hansa  orange- 


Lithosol  fast  orange  R- 

Lithosol  orange  OTP 

•o-Nitroanlline  orange-- 


537. 

406,  471,  500,  570. 

406,  471,  570. 

87,  172,  388,  464,  519,  521,  531. 

333,  376,  563. 

288. 

288,  333,  563. 

525. 

471,  500. 

119,  471,  525,  587,  X. 

63,  87,  268,  277,  333,  376,  388,  424,  458,  464, 

521,  525,  531,  537,  550,  563. 
410. 
87. 
388. 
550. 

119,  282,  471,  500,  525. 

119,  282,  376,  439,  464,  471,  500,  525,  570,  587. 
103,  471,  500,  521. 

87,  333,  406,  410,  464,  471,  521,  537. 
406. 
376. 
119,  172,  282,  291,  388,  458,  471,  500,  525,  567, 

570,  587. 
87,  119,  291,  376,  388,  439,  458,  471,  500,  525, 

531,  563,  570,  587. 
424,  464,  471. 

570. 

63. 

424. 

103. 

288,  376. 

424. 

103,  388,  471,  500,  525,  570. 

119,  237,  282,  376,  464,  471,  500,  521,  525,  570, 

587. 

172,  291,  406,  439,  458,  471,  500,  525,  537,  570. 

87,  119,  172,  282,  291,  376,  388,  439,  458,  471, 

500,  521,  525,  537,  567,  570,  587. 
172,  291,  388,  439,  471,  570. 
87,  119,  282,  291,  388,  471,  500,  525,  537,  570, 

587. 
471. 

376,  567,  587. 


333,  388,  525,  537,  550,  568. 
87,  333,  521,  525,  537,  550,  567. 


87,  424,  525. 
119,  282. 

87, '288,  333,  391,  521,  525,  531,  537,  563. 

563. 

333. 

521,  525. 

525. 

87,  288,  333,  521,  525,  563,  567,  568. 

333. 


333,  458,  464,  521,  525,  563,  587. 
,  521,  525,  563. 
424,  464,  521,  525,  531,  537,  567. 


376,  439,  458,  521,  525,  531,  587. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


95 


TABLE  ISB.- -Synthetic  organic  chemicals:    Toners  and  lakes  for   which  United  States  production  or  sales  were 
reported,    identified  by  manufacturer ,    1953- -Continued 


TONERS  OR  FULL-STRENGTH  COLORS — Continued 


•Orange  toners — Continued 
Vulcan  fast  orange  GRN- 

•Hed  toners: 

Bona  arylamine- 


Brilliant  red  N  (Red  lake  R) 

»o-Chloronitroanillne  red  (Chlorinated  para  red)- 


p-Chloronitroaniline  red 

»Eosine  (Bromo  acid  toner)  (C.I.  768)- 
Helio  fast  pink  RLA- 


Helio  fast  rubine  4BLA  (Pr.  «)6) — 

Helio  red  RMTA  (Pr.  112) 

»Lithol  red  R  (C.I.  189): 

•Barium  toner — ——————— 


•Calcium  toner- 


•Sodium  toner 

All  other 

Lithol  red  2G  (C.I.  166) — 
•Lithol  rubine  B  (C.I.  163)- 


Lithosol  red  CSP 

Naphthoic  red  C 

•Naphthol  AS  (Pr.  302) 

•Naphthol  AS-BS  (Pr.  305)  — 

•Naphthol  AS-D  (Pr.  306) — 

Naphthol  AS-G  (Pr.  309) — 

Naphthol  AS-ITR  (Pr.  310)- 

Naphthol  AS-OL  (Pr.  311)  — 

•C.I.  44,  Para  red,  light— 


•Para  red,  dark- 


•Permanent  red  2B- 


Permanent  red  FKB — 

Permanent  red  FKR  ex 

•Pigment  rubine  3G 

Pigment  scarlet  3B  (C.I.  216)- 
Pyrazolone  red — — . 

•Red  lake  C  (C.I.  165) 

Red  lake  D  (C.I.  214) 

•PMA  Rhodamine  B  (C.I.  749) 

•PTA  Rhodamine  B  (C.I.  749) 


•PMA  Rhodamine  6G  (Rhodamine  Y)  (C.I.  752)- 
•PTA  Rhodamine  6G  (Rhodamine  Y)  (c.I.  752)- 


PMA  Rhodamine  6GDN- 
Hubine  3G 


Sulfanil  red 

•C.I.  69,  Toluidine  red- 


p-Toluidine-m-Eulfonic  acid-azo-,8-naphthol- 

•Vulcan  fast  red  B  (Pr.  476) 

Vulcan  fast  red  BEE 

All  other 


Violet  toners: 

Indanthrene  brilliant  violet  RR- 
•PMA  Methyl  violet  B  (C.I.  680)  — 


•PTA  Methyl  violet  B  (C.I.  680) 

•Methyl  violet  B  (C.I.  680),  fugltive- 


•Yellcw  toners: 

PMA  Acetoacetanilid  yellow- 
•Benzidine  yellow 


Gentex  yellows 

Hansa  orange 

•Pr.  103,  Hansa  yellow  G- 


Pr.  104,  Hansa  yellow  5G — 

•Pr.  105,  Hansa  yellow  lOG- 

Hansa  yellow  130 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


550. 

333,  521. 

563. 

87,  282,  376,  388,  410,  424,  439,  458,  464,  521, 

525,  531,  537,  567,  568,  587. 
333,  410,  521. 

172,  369,  439,  458,  464,  519,  537,  587. 
550. 
471. 
550. 

87,  103,  172,  282,  333,  376,  388,  439,  458,  464, 

521,  525,  531,  537,  567,  568,  587. 
87,  103,  172,  282,  333,  376,  388,  391,  439,  4'^8, 

464,  521,  525,  531,  537,  567,  568,  587. 
87,  376,  388,  439,  464,  521,  531,  568,  587. 
383. 

388,  521,  525. 
87,  288,  333,  376,  388,  439,  458,  471,  500,  521, 

525,  537,  563,  570,  587. 
333. 
464. 

87,  282,  388,  439,  464,  521,  525,  567,  570. 
87,  388,  439,  458,  464,  521,  525,  537. 
87,  282,  439,  458,  464,  521,  525,  587. 
87. 
87,  458,  521. 

87,'l03,  288,  376,  388,  391,  439,  464,  471,  521, 

525,  531,  537,  563,  567. 
87,  103,  172,  237,  288,  333,  376,  388,  391,  410, 

439,  464,  471,  521,  525,  531,  537,  563,  567, 

587. 
87,  282,  288,  333,  376,  388,  391,  439,  471,  521, 

525,  537,  563,  568,  587. 
550. 
550. 

87,  282,  288,  471,  521,  550,  570. 
282,  388,  471. 
333,  563. 
87,  103,  172,  282,  369,  376,  388,  439,  458,  464, 

521,  525,  531,  537,  563,  568,  587. 
172. 

87,  119,  172,  471,  525,  570. 
87,  103,  119,  282,  333,  388,  439,  458,  464,  471, 

500,  521,  525,  570,  587. 
87,  119,  471,  525,  537,  570,  587. 
87,  119,  232,  333,  388,  439,  458,  471,  500,  521, 

525,  537,  567,  570,  587. 
464. 
525. 
464. 
87,  103,  172,  237,  282,  288,  333,  376,  388,  391, 

410,  439,  458,  464,  521,  525,  531,  537,  563, 

567,  568,  587. 
333. 

376,  550,  563. 
550. 
87,  282,  424,  439,  471,  521,  550. 

333. 

87,  103,  119,  172,  388,  391,  406,  410,  458,  464, 

471,  500,  521,  525,  531,  537,  567,  570,  587. 
87,  119,  282,  333,  376, -388,  458,  464,  471,  521, 

525,  537,  563,  570,  587. 
76,  87,  172,  282,  376,  388,  458,  464,  471,  519, 

525,  531,  570,  587. 
550. 

537. 

87,  119,  172,  282,  333,  376,  388,  424,  439,  458, 

464,  519,  521,  525,  531,  537,  563,  587. 
550. 
563. 
87,  103,  282,  333,  376,  388,  391,  424,  439,  458, 

464,  521,  525,  537,  563,  567,  568,  587. 
87,  388,  424,  525,  567. 

87,  282,  388,  424,  458,  521,  525,  563,  567. 
563,  567. 


96 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  15b. --Synthetic  organic  chemicals:    Toners  and  lakes   for  which  United  States  production  or  sales  were 
reported,    identified  by  manufacturer,    i953- -Continued 


Manuf actxirers '  Identification  numbers 
(according  to  list  in  table  27) 


TONERS  OR  FULL-STRENGTH  COLORS — Continued 


»Yellow  toners — Continued 
Pr.  280,  Hansa  -yellow  3R- 
Hansa  yellow  AR- 


Hanaa  yellow,  other—- 
Lithol  fast  yellow  30©- 
Lithol  yellow  G- 


Lithosol  fast  yellow  3GD- 

Vulcan  fast  yellows 

All  other 


LAKES  OR  LAKED  COLORS 


«Blaok  lakes: 

Logwood  black  (C.I.  1253)- 

Nigrosine  (C.I.  $eA) 

True  black — -— — — — — 
All  other 

*Blue  lakes: 


Alkali  blue- 
Brilliant  blue  FCF- 


Brilllant  wool  blue  FFR  (Pr.  40)- 

Indanthrene  blue  GCD  (C.I.  1113)- 

Indanthrene  blue  RS  (C.I.  1106)  — 

^Methylene  blue  (C.I.  922)- 


»Peacock  blue,  fugitive  (Patent  blue)  (C.I.  671)- 


Peacock  blue,  permanent 

Phthalocyanine  blue,  sulfonated 

Setoglaucine  (Peacock  blue  G)  (C.I.  658)- 

Turquoise  blue  (C.I.  661) 

•Victoria  blue  B  (C.I.  729)- 


*Victoria  pure  blue  B  (Pr.  198)- 

All  other 

»Brown  lakes: 


Bismarck  brown  G  (C.I.  331)- 
»BiBmarck  brown  R  (C.I.  332)- 

Indanthrene  brown  RY 

All  other 


*Green  lakes: 

■»Acid  green  B  (C.I.  669)- 
Acid  green  G  (C.I. 


Brilliant  green  (C.I.  662) 

Brilliant  green  (C.I.  662)  and  auramine 

(C.I.  655). 
Brilliant  green  (C.I.  662)  and  thioflavine 

(C.I.  815). 
Green  lake  C.P.S 


Light  green  SF  (C.I.  670) 

•Malachite  green  (C.I.  657) 

Malachite  green  (C.I.  657)  and  auramine 

(C.I.  655). 
Malachite  green  (C.I.  657)  and  fast  light  yellow 

(C.I.  636). 
Naphthol  yellow  (C.I.  10)  and  peacock  blue 
(C.I.  671)'. 

Phthalocyanine  green 

Pigment  green  B  (Pr.  149) 

Shamrock  green 
All  other 
Maroon  lakes: 

Alizarin  maroon  (C.I.  1041) 

Amaranth  (C.I.  184) 

»Azo  Bordeaux  (C.I.  88) 


»Helio  fast  rubine  4BL  (Pr.  406)- 

Hypemic  (C.I.  1243) 

Naphthol  AS-OL  (Pr.  311) 

Patent  fast  rubine  FF 
All  other 


Orange  lakes: 
Acid  orange  R  (C.I.  161)- 
^ -Naphthol- 


Naphthol  AS-OL  (Pr.  311)- 
Orange  lake- 


»Persian  orange  (Acid  orange  Y)  (Orange  II) 
(C.I.  151). 
*Red  lakes: 

•Alizarin  red  B  (C.I.  1027) 


388,  521,  550. 

424. 

521,  531. 

333. 

550. 

333. 

550. 

388. 


i 


87, 

420, 

519, 

567. 

83, 

420. 

424. 

119. 

570. 

87. 

63. 

525. 

333. 

119 

471 

567 

570 

587 

87, 

103, 

119, 

172, 

282, 

291, 

369 

,  376,  410,  458,  464 

471,  500,  525,  537,  567,  570, 

587. 

500. 

63, 

83,  282. 

471 

570 

83, 

420, 

500, 

567. 

87, 

119, 

464, 

471, 

500, 

567. 

119 

282 

420 

471 

567 

471 

282. 

87, 

471, 

537, 

570. 

570 

420, 

550 

87, 

282, 

471, 

500, 

567. 

567. 

119 

471 

500 

537 

119 

119, 

406 

570 

237 

420 

119 

471 

567 

570 

Carmine  (C.I.  1239)- 


63,  83,  521,  567,  570. 

521. 

439,  471,  525,  567. 

282,  424. 

87,  521. 

282,  333,  391,  406,  410,  464,  471,  521,  525,  537, 

567,  568. 
282,  288,  333,  388,  391,  410,  458,  467,  471,  521, 

525,  537,  563, 
525. 
63. 
467. 
63,  420,  587. 

103,  500,  525. 
63. 
103. 
237. 

87,  119,  172,  282,  369,  376,  420,  458,  464,  500, 
525,  537,  567,  570,  587. 

87,  119,  282,  333,  406,  424,  521,  525,  537,  563, 

587. 
87,  180. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


97 


TABLE  ISB.- -Synthetic  organic  chemicals:   Toners   and  lakes   for  which  United  States  production  or  sales  were 
reported ,    identified  by  manufacturer ,   l95J--Continued 


LAKES  OR  LAKED  COLORS— Continued 

»Hed  lakes — Continued 

Crocein  scarlet  3BX  (Cochineal  lake)    (C.I. 
»Eosine   (Bromo  acid  lake)    (C.I.   768) 

Fuchsine   (Magenta)    (C.I.   677) 

Lithol  rubine  B  (C.I.  163) — 

Naphthol  AS  (Pr.  302) 

Naphthol  AS-D  (Pr.  306) 

"Permanent  red  2B 


183)- 


Phloxine  (C.I.  774) 

"Pigment  scarlet  3B  (C.I. 

Polar  red  (C.I.  430) — 
"Rhodamine  B  (C.I.  749)- 


216)- 


"Rhodamine  6G  (Rhodamine  Y)  (C.I.  752)- 
Rose  lake 


"Scarlet  2R  (C.I.  79)- 


Searlet  lake 

Sodium  red  lake  C — — 

Toluidine  red 

Vat  pink  (C.I.  1211)- 
All  other 


"Violet  lakes: 

Acid  violet  (C.I. 


Crystal  violet  (C.I.  681) 

Indanthrene  red  violet  RH  (C.I. 
Methyl  violet- 


1212)- 


"Methyl  violet  B  (C.I. 


Purple  lake  R 

Violet  lake 

All  other 

i^llow  lakes: 
Auramine  (C.I.  655)- 
Benzldine  yellow- 


"Fast  light  yellow  (C.I. 
Hansa  yellow- 


Naphthol  yellow  S  (C.I.  10) 

Quereitron  (Flavlne)  (C.I.  1251)- 

"Qulnollne  yellow  (C.I.  801) 

"Tartrazlne  (C.I.  640) 


Thioflavine  (C.I.  815)- 
All  other 


REDUCED  OR  EXTENDED  TONERS 


Blue  toners,  reduced: 
Halqponts- 


Indanthrene  blue  RS  (C.I. 
Indanthrene  blue,  other- 


1106)- 


Indanthrene  brilliant  violet  RR- 

"PMA  Peacock  blue  R  (C.I.  664) 

»PTA  Peacock  blue  R  (C.I.  664) 

"Pr.  481,  Phthalocyanine  blue  B— 


Pr.  482,  Phthalocyanine  blue  G- 

Phthalocyanine  blue  R 

Phthalocyanine  blue,  other- 


"PMA  Setoglauclne  (Peacock  blue  G)  (C.I.  658)- 
*PTA  Setoglaucine  (Peacock  blue  G)  (C.I.  658)- 

PMA  Victoria  blue  B  (C.I.  729) 

PTA  Victoria  blue  B  (C.I.  729) 

Victoria  blue  B,  tannic- 


PMA  Victoria  blue  R  (C.I.  728) 

PTA  Victoria  blue  R  (C.I.  728) 

PMA  Victoria  pure  blue  B  (Pr.  198)- 
PTA  Victoria  pure  blue  B  (Pr.  198)- 
All  other 


Brown  toners,  reduced:.  Para  brown- 
Green  toners,  reduced: 
"PMA  Brilliant  green  (C.I.  662)  — 
"PTA  Brilliant  green  (C.I.  662)- 


PMA  Brilliant  green  (C.I.  662)  and  auramine 

(C.I.  655). 

PMA  Brilliant  green  (C.I.  662)  and  benzidine 

yellow. 

PMA  Brilliant  green  (C.I.  662)  and  thioflavine 

(C.I.  815). 

PTA  Brilliant  green  (C.I.  662)  and  thioflavine 

(C.I.  815). 

"PMA  Malachite  green  (C.I.  657) 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


87. 

103,  282,  464,  525,  567. 

471,  567. 

87,  521„. 

63,  282,  567,  570. 

63,  521. 

282,  406,  471,  500,  567. 

376. 

87,  119,  282,  333,  410,  424,  471,  537,  570. 

570. 

458,  471,  500,  521,  570. 

63,  471,  525,  537,  567,  570. 

103,  237. 

87,  103,  282,  288,  333,  406,  410,  420,  464,  471,  521, 

525,  537,  567. 
237. 
464. 
63. 

87,  282,  570. 
63,  471. 

388,  420,  471,  570. 

471. 

63,  563. 

525. 

87,  119,  282,  420,  439,  458,  464,  471,  500,  537  567* 

570. 
424. 

237,  458. 
388,  471. 

119,  570. 

500,  521. 

83,  87,  388,  458,  464,  500,  537. 

63. 

87,  500. 

525. 

87,  172,  369,  458,  500,  525,  587. 

87,  103,  119,  282,  369,  376,  458,  464,  500,  525,  567, 

587. 
525. 
525. 


333. 

333. 

563. 

333. 

119,  388,  471,  525,  570. 

471,  500,  525,  570,  587. 

87,  277,  333,  406,  410,  464,  521,  525,  537,  563,  567, 

570. 
567. 
333. 
87. 

119,  471,  519,  570. 
471,  525,  537,  570,  587. 
471,  570. 
87,  471,  537. 
406. 
525. 
525. 

119,  388,  458,  471,  519,  525,  570. 
87,  420,  471. 
388,  471. 
119,  521. 

119,  333,  471,  519,  525,  570. 

471,  519,  525. 

119. 

458. 

119,  537. 

119,  333,  410,  537,  567,  570. 

420,  471. 


98 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  15B.- -Synthetic  organic  chemicals:    Toners  and  lakes   for  which  United  States  production  or  sales  were 
reported,    identified  by  matufacturer ,   i 953 --Continued 


REDUCED  OR  EXTENDED  TONERS — Continued 

Green  toners,  reduced — Continued 
*PTA  Malachite  green  (C.I.  657) 


PMA  Malachite  green  (C.I.  657)  and  thioflavine 

(C.I.  815). 
PTA  Malachite  green  (C.I.  657)  and  thioflavine 

(C.I.  815). 

Pr.  483,  Phthalocyanine  green 

Pigment  green  B  (Pr.  14-9) 

Shamrock  green 

All  other 


Maroon  toners,  reduced: 

Bona  arylamine 

/3-Hydroxynaphthoio  maroon  (B.O.N,  maroon) 
(Lithol  maroon) . 

Lithol  red  3G,  manganese 

Paraphenetidin  maroon — — 

Orange  toners,  reduced: 

Dianisidine  orange • 

2,4-Dinitroaiiiline  orange 

»o-Nitroanillne  orange 

»Red  toners,  reduced: 

o-Chloronitroaniline  red  (Chlorinated  para  red) — 

Eosine  (Bromo  acid  toner)  (C.I.  768) 

Halqponts- 


Lithol  red  2G  (C.] 

»Lithol  red  R  (C.I, 

Barium  toner 


.  166)- 
189): 


Calcium  toner- 
Sodium  toner- 


Lithol  rubine  B  (C.I.  163)- 
*Naphthol  AS-BS  (Pr.  305) — 
»C.I.  AA,  Para  red,  light — 
»Para  red,  dark 

Permanent  red  2B— -  ■  ■---■ 

Red  lake  C  (C.I.  165)- 
*PMA  Rhodamine  B  (C.I. 
»PTA  Rhodamine  B  (C.I. 

PMA  Rhodamine  B  (C.I. 
(C.I.  655). 

PMA  Rhodamine  B  (C.I.  749)  and  6G  (C.I. 

Rhodamine  B,  tannic 

»PMA  Rhodamine  6G  (C.I.  752) 

«PTA  Rhodamine  6G  (C.I.  752) 

Rubine  3G • ' 

•»C.I.  69,  Toluldine  red 

All  other 


749) 

749) 

749)  and  auramin 


752)- 


682)- 


Violet  toners,  reduced: 
»PMA  Ethyl  violet  (C.I 
Haloponts  ■ 

»PMA  Methyl  violet  B  (C.I.  680) 

»PTA  Methyl  violet  B  (C.I.  680) 

Methyl  violet  B  (C.I.  680),  fugitive- 
Yellow  toners,  reduced: 
•Benzidine  yellow- 


Pr.  103,  Hansa  yellow  G 

Pr.  104,  Hansa  yellow  5G 

Pr.  105,  Hansa  yellow  lOG 

Indanthrene  yellow  GK  (C.I.  1132)- 
Lithol  fast  yellow  3GD 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


87,  471,  500,  570. 
525,  570. 

420,  570. 

87,  333,  406,  537,  563,  567,  570. 
333,  550. 
521,  567. 
525. 

333. 
333. 

333. 

410. 

333. 
570. 
410,  521,  525,  570. 

567. 
282. 
333. 
388. 

87,  282,  406,  439,  458,  537,  570,  537. 

87,  439,  458,  570. 

410,  439. 

333,  471,  500,  525,  537,  587. 

388,  464,  537,  567. 

87,  103,  391,  471,  525,  567,  570. 

87,  103,  172,  247,  391,  406,  410,  439,  471,  525. 

87,  333,  388,  410,  439,  471,  537. 

282,  410,  439. 

119,  471,  500,  519,  570. 

119,  333,  471,  537. 

458. 

458. 

406. 

119,  471,  519,  570,  587. 

87,  333,  420,  471,  525,  537,  567. 

537. 

87,  333,  406,  410,  420,  521,  525,  567,  570. 

439,  471. 

433,  519,  525,  570. 

333. 

87,  388,  458,  471,  519,  525,  567,  570. 

87,  119,  471,  587. 

406,  458,  471. 

87,  333,  458,  464,  519,  521,  525,  563,  570. 

333,  521,  525,  537,  570. 

525,  567,  570. 

333,  570. 

458. 

333,  388. 


I 


SYNTHETIC  ORGANIC  CHEMICALS,  I953 
Medicinals 


TABLE  17B. --Synthetic  organic  chemicals:   Medicinals   lor  which  United  States  production  or  sales 
were   reported,    identified  by  manufacturer ,    1953 

[Medicinals  for  which  separate  statistics  are  given  in  table  17A  are  marked  below  with  an  asterisk  (»); 
medicinals  not  so  marked  do  not  appear  in  table  17A  because  the  reported  data  are  confidential  and  may 
not  be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from  table  27.  An  X 
signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number  with 
the  designated  product] 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


MEDICINALS,    CYCLIC 

Benienoid 

Ij-i-Aeetamidophenyl  salicylate  (Phenetsal) 

Acetanilide 

Aeetarsone   (N-Aeetyl-4-hydroxy-m-arsanilic  acid) 
(Stovarsol ) . 

4- Acetoxy-m-arsanllio  acid   (Nemural) 

Acetylglycol  salicylate 

»Acetylsalicylic  acid  (Aspirin ) 

"Adrenaline  (Epinephrine ) 

»Amino  acids: 

3,5-Diiodotyrosine 

d-Phenylalanine 

dl-Phenylalanine 

1-Phenylalanine 

dl- Tyrosine 

1-Tyrosine — ~— — 

2-Amino-4-arsenosophenol  (Mapharsen)  hydrochloride-^ 

»p-Aminobenzoic  acid 

»p-Aminobenzoic  acid  derivatives: 

2-Amylaminoethyl  p-aminobenzoate  (Anorlsine) 

»Benzooaine  (Ethyl  p-aminobenzoate) 

Butaoaine  (3-Di-n-butylaiiiinopropyl  p-amino- 
benzoate) base. 

Butac  aine  sulfate 

Butesin  (n-Butyl  p-aminobenzoate ) __—_—— 

Butesln  piorate  (Di(n-butyl  p-aminobenzoate )tri- 
nitrophenol ) . 

Isobutyl  p-aminobenzoate  (Cycloform) 

2-Isobutylaminoethyl  p-aminobenzoate  (Unacalne) 

(Monocaine) . 
"Procaine  base  (2-Diethylaminoethyl  p-amino- 
benzoate) (Novooaine  base). 

"Procaine  hydrochloride 

Propyl  p-aminobenzoate 

Tetracaine  (2-0imethylaminoethyl  p-butylamino- 
benzoate)  base  and  hydrochloride. 
»p-Aminobenzolc  acid  salts: 

Calcium  p-aminobenzoate 

Magnesium  p-aminobenzoate 

Potassium  p-aminobenzoate 

Sodium  p-aminobenzoate 

p-Aminohippurie  acid 

A-Amino-2 -methyl- 1-naphthol  hydrochloride  (Synkamin) 

•4-Aminoaalicylio  acid 

»'»-Aminosalioylic  acid  salts: 

Calcium  i-aminosalicylate 

Sod  ium  ^-aminosalicylate 

sec-Anyl tricresol 

Anisoin  {A, U' -Dimethoxybenzoin ) 

1, 8, 9-Anthratriol  (Anthralin ) 

Antihistamines: 

2-(Benzhydryloxy)-N, N-dimethylethylamine 

(Benadryl)  hydrochloride - 
N,N-Dimethyl-2-(a^henyl-o-toloxy)ethylamine 
dihydrogen  citrate. 

Benzaldehyde — - — - — -__——— _ 

Benzestrol  [ 2, 4-Dl (p-hydroxyphenyl )-3-ethylhexane] — 

Benzoic  acid——-- — — — - — 

Benzoic  acid  salts: 

Calcium  benzoate 

Lithium  benzoate 

N-Benzyl-fl-chloropropionamide  (Hlbicon) 

p-Benzylphenyl  carbamate  (Diphenan) 

Benzyl  succ  Inate— ~ — — — _ — 

"Bismuth  subgallate 

"Bismuth  subsalicylate 

Bis (4-nitrophenyl )  disulfide 

p-Bromobenzyl  bromide 

o-Bromolsovaleryl-p-phenetidine 

N-Butylaoetanllide 

6-tert-Butyl-A-chloro-m-oresol  (2-tert-Butyl-/4.- 
chloro-5-methylphenol ) . 


198. 

132,  245. 
376,  379,  565. 

379. 

431. 

129,  173,  245,  376,  U8,  546. 

379,  381,  394,  400,  562,  X. 


133, 

468 

379, 

462 

448, 

558 

462. 

448. 

171, 

445, 

558. 

400. 

27, 

78,  132,  360,  389, 

527. 

22. 

343, 

394, 

431, 

565 

280, 

565. 

565. 

565. 

381, 

565. 

78, 

431. 

22. 

27, 

379, 

389, 

565. 

27, 

132, 

325, 

379, 

389 

565. 

431 

379, 

431, 

468 

389 

389 

78, 

360, 

389. 

27, 

78,  132,  360,  389, 

394,  527 

527. 

400, 

506 

198, 

360, 

400, 

464 

464 

198, 

360 

400, 

464 

X. 

187, 

442 

565 

400 

238. 

397. 

203. 

245. 

397. 

274, 

360 

464. 

78, 

163, 

468. 

586. 

231 

267 

281 

415 

515. 

129, 

231 

267 

515 

464 

468 

198, 

494 

431 

206 

100 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  17B^ --Synthetic  organic   chemicals:    Medicinals   for  which  United  States  production   or  sales 
were  reported,    identified  by  manufacturer ,   i95J- -Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


MEDICINALS,  CYCLIC— Continued 

Benzenoid — Continued 

tert-Butyloresol 

Calcium  cresolsulfonate 

Carbasone  (p-Carbamidobenzenearsonic  acid) 

Carbobenzoxy  chloride 

Chloramine  T  (Sodium  p-toluenesulfonohlor amide ) 

Chloromerouri-A-nitro-o-oresol 

Chlorosalicylanilide 

Chlorothymol 

Chlorotris (p-methoxyphenyl ) ethylene  (Tri-p-anisyl- 

ohloroethylene ) . 
"i-Chloro-SjS-xylenol  (3,5-Dimethyl-A-ohlorophenol)- 

Citryl-p-phenetidlne ~ 

m-Cresyl  acetate  (Cresatin) 

p-(Cyclohexyloxy)benzoio  acid 

p, p'-Diaminodiphenylsulfone-N, N'-di (dextrose  sodium 
sulfonate ) . 

2, 5-Diaminotoluene  sulfate — 

5,3'  -Dichlorosalioylanilide 

5,4'-Dichlorosalicylanilide — — 

a-Diethylamino-2,6-acetoxylidine 

2-Diethylaminoethyl  diphenylacetate  hydrochloride — 
^-Diethylamlnoethyl  diphenylthioacetate  hydro- 
chloride. 
N-Diethylaminoethyl  isoamyl  phenyl  glycinate 
dihydrochloride . 

P»P'-(lj2-Diethylethylene)diphenol  (Hexestrol) 

p,p'-(l,2-Dlethylethylene)diphenol  (Hexestrol) 
dipropionate. 
*a,a ' -Diethyl-i,  A' -stilbenediol  ( Diethylstilbestrol ) 

a,a.'-Diethyl-4,i' -stilbenediol  dipropionate 

3, 4-Dlhydroxynorephedrine  (3, A-Dihydroxyphenyl- 

propanolamine )  hydrochloride . 
^-(3,5-Diiodo-4~hydroxyphenyl)-a-hydratropic  acid — 
6-Dimethylamino-4, 4-diphenyl-3-heptanone  hydro- 
chloride (Dolophine)  (Methadone). 

■y-Dimethylamino-ajO-diphenylvaleramide 

^-Dlmethylaminoethyl(l-hydroxycyclopentyl)  phenyl 
acetate  (Cyclopentolate)  hydrochloride. 

Dimethylamlnopyrocatechol 

Dimethyl-3-hydroxyphenylnmmnnium  chloride 

»N,a-Dimethylphenethylamlne  (Desoxyephedrine)  base — 

*d-N, a-Dimethylphenethylamine  hydrochloride 

»N, a-Dimethylphenethylamine  hydrochloride 

Dimethyl-p-toluidine 

Diphenylacetic  acid 

Diphenylacetyldiethylamlnoethanol  hydrochloride 

p-(Di-N-propylsulfamyl)benzoio  acid  (Benemid) 

Dithiosalicylic  acid 

*Dyes,  medicinal: 

Acrlf lavine  (3, 6-Diamino-lO-methylaorldine 

chloride ) . 
2,  -i-Diamino-A'-  -ethoxyazobenzene  hydrochloride 
(Serenium). 

Gentian  violet— __• — 

Merbromin  ( Dibromohydroxymerourif luoresoein, 
sodium  salt). 

Methylene  blue 

Methyl  violet 

Proflavine  (3,6-Diaminoacridine  sulfate) 

Scarlet  red  (Phenol  red)- — 

Sulfobromophthalein,  sodium —«_____ 

Tetraiodophenolphthalein  and  sodium  salt 

Trypan  blue 

All  other 

1-Ephedrlne  (o-(l-Methylaminoethyl)benzyl  alcohol)- 

Ephedrine,  racemic — 

4-Ethoxy-3-methoxybenzaldehyde 

4-Ethoxy-3-methoxyphenylaoetic  acid— ~ 

N-Ethyl-3,3'-diphenyldipropylamine 

N-Ethyl-3, 3 ' -diphenyldipropylamine  citrate 

N-Ethyl-3,3'-diphenyldipropylamine  hydrochloride 

Ethylene  glycol  salicylate 

N-Ethylephedrlne  hydrochloride 

Ethyl  (lodophenyl)hendecanoate  (Pantopaque) 

Gallic  acid 

Oentisic  acid  (2,5-Dlhydroxybenzoio  acid)  and 
derivatives: 
Gentislc  acid 


431. 

360. 

78,  442,  468. 

468. 

245. 

565. 

591. 

515,  520. 

289. 

206. 
360. 
444. 
442. 
400. 

498. 

591. 

591. 

6. 

468. 

597. 


506. 
506. 

187,  360,  442,  506. 

187,  506. 

379. 

290,  457. 
442,  515. 

238. 
203. 

300. 

452. 

198,  324. 

542. 

198,  324,  542. 

468. 

389. 

336,  431. 

245,  4^4,  468,  542. 

442. 

527,  565. 


527. 

126, 

360 

464, 

527 

527. 

527, 

565 

527. 

599. 

527. 

527. 

527. 

515. 

515. 

442. 

442. 

187, 

431 

187, 

431 

187. 

431. 

289. 

498. 

231. 

431, 

542. 

SYNTHETIC  ORGANIC  CHEMICALS,  1953 


101 


TABLE  17B. --Synthetic  organic  chemicals:   Medicinais   for  which  United  States  producti 
were  reported,    identified  by  manufacturer ,   J95J- -Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


MEDICINALS,  CYCLIC— Continued 
Benzenoid — Continued 

Gentisio  acid  (2,5-Dihydroxybenzoic  acid)  and 
derivatives — Continued 

Oentisic  acid,  sodium  salt 

N-2-Hydroxyethylgentisamide  (Oentisic  acid  amide 
of  ethanolamine ) . 

Guaiaool,  liquid  and  ciystalline 

Hexyl-ra-cresol 

Hexylresoroinol 

Hydroquinone  n-amyl  ether  (Amol) 

p-Hydroxyaoetanilide 

p-Hydroxybenzoic  acid  esters: 

Benzyl  p-hydroxybenzoate 

n-Butyl  p-hydroxybenzoate  (Butoben) • 

Ethyl  p-hydroxybenzoate 

♦Methyl  p-hydroxybenzoate 

»Propyl  p-hydroxybenzoate 

^-Hydroxy -5-( 2, 5-dimethoxyphenyl) isopropylamine 

hydrochloride  ( Methoxamine ) . 
Hydroxyinercuri-4-nitro-o-oresol  anhydride  (Metaphen) 

4— Hydroxy -3-nitrobenzenearsonic  acid 

L-l-(m-Hydroxyphenyl ) -2-amino-l-propanol  hydrogen 

d -tartrate  ( Axamine ) . 
/5-(<i-Hydroxyphenyl)-a-phenylpropionic  acid  ($-H- 
Hydroxyphenyl)hydratropic  acid) . 

p-Hydroxypropiophenone  (Hydrophen) 

o-Iodobenzoic  acid 

a-(Isopropylaminomethyl)protocatechuyl  alcohol 
(Aleudrine ) . 

Mandelic  acid  (Phenylglycollc  acid) 

Mandelic  acid  derivatives: 

Calcium  mandelate 

N-2-Hydroxyethylmandelamide 

o-Methoxy-N,a-dimethylphenethylamine  ( l-(o-Methoxy- 

phenyl) -2-methylaminopropane)  hydrochloride . 
3-Methoxy-N-(a  -methylhomoveratryl ) -p-acetopheneti- 

dide, 
3-(o-Methoxyphenoxy) -1,2 -propanediol  (Glyceryl 
guaiaoyl  ether). 

N-Methylacetanilide  ( Exolgin ) 

Methylenebis  [octylcresol] 

5, 5' -Methylenedisalioylic  acid 

*a-Methylphenethylamine  (Amphetamine)  (Benzedrine) 

base. 
*a-Methylphenethylamine  salts: 

a-Methylphenethylamine  hydrochloride 

a-Methylphenethylamine  phosphate 

a-Methylphenethylamine  sulfate 

d -a-Methylphenethylamine  sulfate 

2,,7-Naphthalenediol  (2,7-Dihydroxynaphthalene) 

2-Naphthol  (yS-Naphthol ) 

2-Naphthyl  benzoate 

N-(1-Naphthyl)ethylenediamine  hydrochloride 

Neosynephrine  (Phenylephrine)  hydrochloride 

p-Nitrobenzenearsonic  acid 

'♦-(2-Nitrophenyl)veratrole  (l-(3,'4-Dimethoxyphenyl)- 
2-nitropropene-l) . 

Norephedrine  (Propadrine)  hydrochloride 

Octylcresol 

Ootylresorcinol 

Paredrine  (p-Itydroxy-a-methylphenethylamine)  hydro- 
bromide. 
Phenacaine  [(Di-p-ethoxyphenyl)acetamidine]  hydro- 
chloride. 

Phenacetin  ( Ace tophenetid  in ) ! 

[y-Phenenyltris ( oxyethylene ) ] -tris  [triethylammonlum 
iodide] . 

Phenolphthalein 

Phenolsulfonlc  acid  salts: 

Calcium  phenolsulf onate ■ "        --■    ■■  - 

Copper  phenolsulf onate 

Sodium  phenolsulf onate 

Zinc  phenolsulfonate         -  ■■-    .   i       - 

2  J'henyl-1 , 3-indandione 

•Phenylmarcurio  derivatives : 

o-Chloromercuriphenol  ( o-Hydroxyphenylmercuric 
chloride ) . 

Phenylmercuric  acetate 

Phenylmercur ic  benzoate 

Phenylmercuric  borate 

Phenylmercuric  chloride ~ 

Phenylmercuric  nitrate 

4-Phenylsemicarbazlde  hydrochloride 


360, 

431, 

542. 

«1. 

245, 

397. 

444. 

132, 

444, 

542. 

444. 

198. 

397, 

431. 

360, 

397, 

431. 

360, 

397, 

431. 

78, 

360, 

397,   431. 

360, 

397, 

431. 

163. 

381, 

442, 

565. 

198. 
468. 
187, 


231. 
442. 
198. 


394,  442. 


442. 

78,  360,  431,  468. 

78. 

591. 

397. 

47,  198,  308,  343,  442,  542. 


198,  542. 

198. 

198,  308,  542. 

308. 

468. 

591. 

360,  494,  515. 

468. 

360,  381,  394,  591. 

X. 

442. 

444. 
591. 
591. 
308. 

280,  379,  394. 

245,  389,  431,  448. 
464. 

245. 

231,  515. 
23i; 
231. 

231,  515. 
187,  203. 

163,  599,  X. 

211. 

211,  325. 

211,  325. 

211,  325. 

211,  325. 
468. 


102 


UNITED  STATES  TARIFF  COMMISSION 

■Synthetic   organic  chemicals:    Medlclnals  for  which  United  States  production  or  sale 
were   reported,    identified  by  manufacturer ,   J95J- -Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


MEDICINALS,  CYCLIC— Continued 
Benzeno id- -Continued 

Propenyl  methyl  guaethol 

Prostigmine  (Neostigmine)  bromide 

»Prostigmine  (Neostigmine)  methyl  sulfate 

♦Resorcinol  monoacetate 

*Salicylamide 

♦Salicylic  acid 

♦Salicylic  acid  salts: 

Ammonium  salicylate 

♦Calcium  salicylate 

Lithium  salicylate 

Magnesium  salicylate 

Manganese  salicylate 

♦Sodium  salicylate 

Strontium  salicylate 

Salicyl  salicylate  (Salysal) 

Salol  (Phenyl  salicylate) 

♦Silver  piorate 

Sodium  antimony  III  biscatechol-2,<i-disulfonate 
(Fouadin). 

Sodium  benzyl  succinate 

♦Sodium  ethylmercurithiosalicylate 

Sodium  o-iodohippurate  dihydrate  (Hippuran) 

Sodium  methylenesulfonaminohydroxyphenyl  arsenate 
(Aldarsone). 

Stilbamine  glucoside  (Neostam) 

♦Sulfa  drugs: 

Benzoylsulfanilamide 

Benzoylsulfanilamide,  sodium  salt 

p-Benzylaminobenzenesulfonamide 

N''--(3,'i-Dimethyl-5-isoxazolyl)sulfanilamide 

■i  -(3 , <i-Dime th^l -5-isoxazolylsulf amoyl )  - 
acetanllide. 

2-Methyl-l,3,'i,5-sulfanilamidothiadiazole 

Neo-Prontosil  "S" 

Nisulfazole 

P-(p-Nitiophenylsulfonajnido)acetanilide 

(N''-Acetyl-N'-('i-nitrophenyl)sulfanilamide). 

N''-Phthalylsulfaacetamide 

Phthalylsulfathiazole 

Prontosil  soluble  (Disodium  4-sulfaminophenyl-2- 
azo-7-acetylamino-l-hydroxynaphthalene-3,6- 
disulfonate). 

Sulfadiazine 

Sulfadiazine,  sodium  salt 

Sulfaguanidine 

Sulfallantoin 

Sulfamerazine  (2-Sulfanilajiiide-4-methylpyrimi- 
dine). 

Sulfamerazine,  sodium  salt 

Sulfamethazine  (Sulf adimethyldiazine ) 

Sulfanilamide  (p-Aminobenzenesulfonamide) 

Sulf anllanilide  { N^-Phenylsulf anilamide ) 

N-Sulf anilylacetamlde  (Sulf aacetamide ) 

N-Sulfanilylacetamide,  sodium  salt 

Sulfapyridine 

Sulfapyridine,  sodium  salt 

Sulfaquinoxaline 

Sulfasuxidine  (Succinylsulfathiazole) 

Sulfathiazole 

Sulfathiazole,  sodium  salt 

(Sulfonylbis(p-phenyleneimino))dimethanesulfinic 

acid^  disodium  salt  (Diasone). 
"ij-i'-Sulfonyldianiline  (4,4'  -Diaminodlphenyl- 
sulf one ) . 

Tannin  albuminate  (Tannalbln) 

Thiosalicylic  acid 

Thymol 

♦Thymol   iodide 

•3-o-Toloxy-l,2-propanediol   (o-Cresyl  a-glyceryl 
ether). 

Trithlo(p-niethoxyphenyl)propene 

♦Vitamins: 

K   (Menadione)   (2-Methyl-l,';-naphthoqulnone) 

K  (Menadione),   sodium  bisulfite 

K  (2-Methyl-l,4-naphthoqulnone-diphosphorlc 
ester  tetrasodlum  salt). 

Ki    (2-Methyl-3-phytyl-l,4-naphthoquinone) 

Zinc  sulfanilate   (Nizln) 


452,   468,    514,    542. 

468,    514,    542. 

47,   360,   498,    586,    591. 

245,    324,    360,    389,    504,    542,   600 

245,    376,   397,   448. 

231,   267,   360. 

231,   360,   397,   448. 

75,   274. 

231. 

397. 

245,   397,   448. 

231,   448. 

421. 

448. 

78,   468,    564. 

379. 

389,    586. 

381,    442,    506,    514. 

231. 

565. 

163. 

464. 

464. 

379. 

452. 

452. 

464. 

379. 

379. 

X. 

389,   457,   464. 

245,   290. 

379. 

464. 

464. 

464. 

174. 

464. 

464. 

464,   495. 

245,   464,    515. 

X. 

78,   245,   389,   457. 

389,   457. 

464,    515. 

464,    515. 

515. 

245,   290. 

442,   464,    515. 

464,    515,    522. 

565. 

X. 

360,    591. 

442,    514. 

229,    323,    520. 

231,   267,    515. 

198,    360,   431,   494,    542. 

591. 

^7,   394,    506,    542,    565. 

506. 

452. 

515. 

163. 

SYNTHETIC  ORGANIC  CHEMICALS,  1933 

TABLE  17B.--Synt/ietjc  organic   chemicals:    Hedicinals    for  which  United  States  production   or  sales 
were   reported,    identified  by  manufacturer ,    1953- -Continued 


103 


MEDICINAIS,  CYCLIC— Continued 


All 


id  Httt 


5-Aoetamido-l,3,4-thiodiazole-2-sulfonamicle 

Adenine,  base  and  hydrochloride 

Adenine  sulfate 

Adenosine 

Adenosinediphosphorio  acid 

Adenosinediphosphoric  acid,  barium  salt 

Adenosine-5-phosphoric  acid 

Adenosinetriphosphoric  acid  and  salt 

Adenylic  acid 

Adenylic  acid,  isomers  A  and  B 

♦Alkaloids  and  related  products: 

Arecoline  (Methyl  1,2,5,6-tetrahydromethyl- 
niootinate)  t^rdrobromide. 

Atropine 

Atropine  amineoxide  hydrochloride 

■^erberine  base  and  hydrochloride 

Brucine 

Cinchonidine 

Cinchonine 

Colchicine 

Digifolin 

Digitalin 

Digitonin 

Digitoxin 

Digoxin 

Emetine 

Ergonovine  maleate 

Eser ine  ( Physostlgmine ) 

Eserine  salicylate 

Eucatropine  hydrochloride 

*Homatropine  and  salts 

Horaatropine  methyl  bromide 

Hydrastine 

Hydrastine  hydrochloride 

dl-3-Hydroxy-N-methylmorphinan  hydrobromide 

1-3-Hydroxy-N-methylmorphinan  tartrate 

Hyosoine  (Scopolamine) 

i^oscine  (Scopolamine)  amineoxide  hydrobromide 

Hyoscyamine 

Ifyoscyamine  sulfate 

Nicotine 

Pilocarpine  hydrochloride 

Pilocarpine  nitrate 

ftainidine 

Quinine 

Reserpine 

Strychnine 

Totaquine 

Yohimbine 


Allantoin  ( 5-Ureidohydantoin) 

♦Amino  acids: 

Histamine ,  base 

Histamine  dihydrochloride 

Histamine  phosphate — 

Histidine  monohydroohloride 

dl -Tryptophane 

l-Tryptophane 

9-Aminoacridine  hydrochloride 

Z-Amino-S-nitrothiazole  ( Enheptin ) 

♦Antibiotics  for  human  or  veterinary  use: 

Actidione 

♦Bacitracin 

Carbomycin  (Magnamycin) 

Chloroamphenicol  ( Chloromycetin ) 

Chlortetracyoline  (Aureomycin)  hydrochloride 

♦Dihydrostreptomycln 

Erythromycin 

Fumagillln 

Neomycin 

Oxytetracyoline  ( Terramycin ) 

♦Penicillin  salts: 

Chloroprocaine  penicillin  "0" 

♦Dipeniclllin  G  dlbenzylethylenediamine 

Penicillin  calcium 

Penicillin  1-ephenamine 

♦Penicillin  potassium 

■Penicillin  "0"  potassium  (Allylmercaptomethyl 
derivative) . 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


464. 

462. 

462,  498. 

462. 

340. 

462. 

340,  462. 

340,  462. 

462. 

462. 


600. 
562,  565, 


565,  600. 


421. 

299, 
513. 
299, 
299. 
515. 
515. 
299, 
336. 
299, 
591, 
,606. 
163. 
600. 
163. 
299. 
600. 
280. 
187, 
187, 
299, 
600. 
452. 
452. 
299, 
513, 
299, 
562. 
600. 
299, 
562, 
600. 
515. 
336. 
515. 
515, 
299, 
174, 

42. 

452. 

42. 

468,  558. 

379,  448,  558. 

558. 

431. 

464. 


600. 
600. 


299,  515. 

299,  360,  419,  515. 

600. 


600. 
600. 
600. 


600. 
600. 


600. 
600. 
591. 


415,  600. 
400. 


367, 
415. 
245, 
464. 
116, 
442, 
565. 
397, 
415. 

X. 

238,  415,  442,  564. 

X. 

367. 

116,  152,238,  367,  397,  415,  442,515,  522,  564,  565,  X. 

X. 


238,  397,  415,  442,  515,  522,  565. 
565,  X. 


600,  X. 


104  UNITED  STATES  TARIFF  COMMISSION 

TABLE  17B. --Synthetic   organic  chemicals:   Kedicinals    for  which  United  States  proddctiat  or  sales 
were  reported,   identified  by  manufacturer ,   /953--Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


MEDICINAI£,  CYCLIC— Continued 

Alicyclic  and   fleterocyc J ic- -Continued 

^Antibiotics  for  human  or  veterinary  use — Continued 
♦Penicillin  salts — Continued 

♦Penicillin  procaine 

♦Penicillin  sodium 

Polymyxin 

♦Streptomycin— 

Tetracycline  (Achromycin) 

lyrothricin  (Gramicidin) 

Viomycin 

♦Antibiotics  for  animal  feed  supplements: 

Bacitracin 

Chlortetraoycline  (Aureomycin)  hydrochloride 

Oxytetracycline  ( Terramycin ) 

Penicillin  salts: 

Dipenicillin  G  dibenzylethylenediamine 

Penicillin  procaine 

♦Antihistamines : 

2-(Benzhydryloxy)-N,N-dimethylethylamine  8- 

chlorotheophyllinate . 
2-[Benzyl (2-dimethylaminoethyl ) amino] pyridine 

( N,N-Dlmethyl-N' -benzyl -N' -pyridylethylene- 

diamine). 
l-('i-Chlorobenzhydryl)-4Mnethylpiperazine  hydro- 
chloride . 
2- [l-(p-Chlorophenyl ) -3-dimethylaminopropyl ] - 

pyridine  maleate  (Chlorophenylpyridamine 

maleate). 
l-(p-Chlorophenyl) -2 -phenyl -4-pyrrolidyl-l-butene 

diphosphate  and  hydrochloride. 
l-(p-Chlorophenyl)-2-phenyl-4-pyrrolidyl- 

2 -butanol . 
2 - [ ( 5-Chloro -2 -thenyl } ( 2-dimethylaminoethyl )- 

amino] pyridine  citrate  (N,N-Dimethyl-N'2- 

pyridyl-N'2-( 5-chlorothenyl)  ethylenediamine 

citrate). 
2 - [ a- ( 2-Dimethylaminoethoxy )-a-»ethylbenzyl  ]- 

pyridine  succinate  (2-(Methyl-2'-dimethylamino- 

ethoxybenzyl)pyridine  succinate). 
2-[(2-Dimethylaminoethyl)  (p-methoxybenzyl)  amino] - 

pyridine  maleate. 
2 - [ ( 2 -Dimethylaminoethyl ) ( p-methoxybenzyl ) amino] - 

pyrimidine  (N, N-Dimethyl-N'-p-methoxybenzyim- 

2-pyrimidylethylenediamine ) . 
2-  [(2-Dimethylaminoethyl)thenylamino ]pyridine 

fumarate  (N,N-Dimethyl-N'2-pyridyl-N'2-thenyl- 

ethylened  i  amine  fumarate ) . 
2-  [( 2 -Dimethylaminoethyl ) thenylamino] pyridine 

hydrochloride  (N,N-Dimethyl-N'2-pyrldyl-N'2- 

thenylethylenediamine  hydrochloride ) . 
2- p-CDimethylamino) -1-phenylpropyl]  pyridine 

(1 -Phenyl -l-(2-pyridyl)-3-dimethylamino- 

propane ) . 
2-  [3-(Dlmethylamino )  -1-phenylpropyl]  pyridine 

maleate  (Prophenpyridamine  maleate). 
2-Methyl-9-phenyl-2,3,<i,9-tetrahydro-l-pyridin- 

dene  hydrogen  tartrate. 
N-(l-Pyrrolidyl)ethylphenothiazine  hydrochloride— 

Antipyrine  ( 1, 5-Dimethyl -2 -phenyl -3-pyrazolone ) 

Barbituric  acid 

♦Barbituric  acid  derivatives: 

5-Allyl-5-(2-cyclopenten-l-yl)barbituric  acid 

and  salt  (Cyolopal). 

5-Allyl-5-isobutylbarbiturlc  acid  (Sandoptal) 

5-Allyl-5-isopropylbarblturic  acid  (Alurate) 

♦5-Allyl-5-(l-methylbutyl)barbiturio  acid  and  salt- 

(Secobarbital). 
5-Allyl-5-phenylbarbiturio  acid  and  salt 

(Alphenal). 

5-n-Butyl-5-ethylbarblturio  acid  (Neonal) 

5-sec-Butyl-5-€thylbarblturic  acid  and  sodium 

salt. 
5-( 1-Cyolohexen-l-yl ) -1, 5-dlmethylbarbiturio 

acid  (Evipal). 
5-(  l-Cyclohexen-l-yl)-l,  5-<3imethylbarbituric 

acid,  sodium  salt. 
5-(l-Cyclohexen-l-yl)-5-ethylbarbiturlc  acid 

and  salt. 


116,  152,  238,  367,  397,  -VIS,  <W2,  515,  522,  564, 

565,  X. 
238,  367,  397,  415,  515,  X. 
415. 

116,  238,  397,  415,  442,  515,  522. 
397,  464. 
600. 
415. 

340,  367,  600. 

464. 

415. 

415. 

152,  238,  397,  415,  515,  565. 

547. 

336. 

565. 

457. 

442. 
442. 
245. 


281,  289. 

515. 
205. 

245,  565. 

245,  379,  565. 


457. 
452. 

X. 

448. 
266, 


198. 
452. 
343, 


565. 
198, 

379. 

379. 

379. 


381,  394,  442,  494. 


343,  360,  381,  394,  442,  565. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953  105 

TABLE  IIB. --Synthetic  organic  chemicaia:    Kedicinals    for  which  United  States  production   or   aalea 
were  reported,    identified  by  manufacturer ,    J953--Continued 


Manufacturers'  Identification  numbers 
(according  to  list  In  table  27) 


MEDICINALS,  CYCLIC— Continued 

Alicyclic    and  Heterocyc lic--Continued 

♦Barbituric  acid  derivatives — Continued 

5, 5-Diallylbarblturic  acid  (Dial) 

*5, 5-Diethylbarblturlo  acid  (Barbital)  and  salt: 

5, 5-Diethylbarbituric  acid 

5, 5-Diethylbarblturlc  acid,  sodium  salt 

5-Ethyl-5-isoamylbarbituric  acid  and  salt 
(Amytal). 

5-Ethyl-5-lsopropylbarblturio  acid  and  salt 

5-Ethyl-5-(l-methyl-l-butenyl)barbiturlo  acid 
(Delvinal). 
»5, 5-Ethyl-5-(l-methylbutyl)barbituric  acid 
(Pentobarbital)  and  salts: 

5-Ethyl-5-(l-methylbutyl)barbiturio  acid 

5-Ethyl-5-(l-metl^lbutyl)barbituric  acid, 

calcium  salt. 
5-Ethyl-5-(l-methylbutyl)barblturic  aold, 
sodium  salt. 
5-Ethyl-5-(lHnethylbutyl)-2-thiobarbiturio  acid 

and  salt  ( Pentothal ) . 
5-Ethyl-lHnethyl-5-phenylbarbiturlo  acid 
(Mephobarbital) . 
*5-Ethyl-5-phenylbarbiturio  acid  (Fhenobarbital) 

( Luminal ) . 
*5-Ethyl-5-phenylbarbituric  aold,  salts: 

5-Ethyl-5-phenylbarbiturlc  acid,  calcium  salt 

5-Ethyl-5-phenylbarbiturio  acid,  sodium  salt 

Barium  inosinate 

5, 6-Benzoqulnollne 

3-Benzyl-lHnethyl-s -undecylimidazollum  bromide 

«Bile  acids  and  salts: 

Bilirubin 

Bilron 

•Cholio  acid 

»Dehydrocholio  acid 

Dehydrooholio  acid,  sodium  salt 

*Desoxycholio  acid 

(  Ketooholanic  acids 

Methyl  hyodesoxycholate 

Mixed  bile  acids,  extracted 

Mixed  oxidized  bile  acids 

»Bromocamphor,  mono 

a-Butyloxyclnchoninio  acid  diethylethylenediamide 
and  hydrochloride  (Nupercaine). 

•Caffeine,  natural  and  synthetic 

Caffeine  derivatives: 

•Caffeine  citrate 

•Caffeine  sodium  benzoate 

Ethyl  caffeate 

Camphor,  synthetic,  U.S.P 

•Camphoric  acid 

Camphoric  anhydride 

Camphosulf onlo  acid 

Camphosulfonio  aold  salts: 

Calo  ium  camphosulf onate 

Sodium  camphosulf onate 

Carboxymethyloellulose,  sodium  salt 

Cellulose,  oxidized 

7-Chloro-i-('»-diethylamino-l-methylbutylamino)- 
qulnoline  (Aralen). 
•5-Chloro-7-iodo-8-quinolinol  ( lodoohlorohydroxy- 
quinoline). 
7-Chloroltynurenio  acid  (7-Chloro-<»-hydroxyquinoline- 
2-carboxylic  acid), 

^-Cholesterol 

Cinchophen  (2-Phenylqulnollne-^-oarboxyllc  acid) 

Cinchophen  (2-Phenylquinoline-i-carboxyllo  acid) 
hydroiodlde. 

Cinchophen,  sodium  salt 

Cocarboxylase 

Coenzyme  A 

Coramlne  ( Nikethamide ) 

Co zymase 

l,i-Cyolohexanedlone 

l-Cyclohexylamino-2-propyl  benzoate  (Cyclaine) 
l^drochloride . 

l-Cyclohexyl-2-methylpropylamine 

a-Cyolohexyl-a-phenyl-l-piperidinepropanol 

a-Cyclohexyl-o-phenyl-l-pyrrolidinepropanol 


39-;,   "W2, 

565. 

39<i,    565. 

360,   381, 

394,   442. 

X. 

198,   X. 

198,   3«, 

381,   394,    565. 

394. 

198,   3A3, 

381,   394,    565. 

565. 

360,   379. 

231,    3«, 

379,   394,    565. 

343,   394. 

231,    343, 

379,   394,    565. 

462. 

468. 

442, 

498, 

442, 

5,   122,   165,   379,  416, 

5,   122,   165,   379,  416, 

416. 

5,   122,    165,   379,   416,    562 

165,   379, 

419,    547. 

122. 

379,   416, 

419. 

122. 

231,   360, 

448,    600. 

336, 

104,   245, 

256,   274,   415. 

231,   245, 

267,    515. 

231,   394, 

515. 

599, 

285,  333. 

78,  360, 

468,    591. 

591. 

78,    591. 

591. 

78,    591. 

336. 

483. 

379. 

78,   325, 

336,   360,    389. 

376. 

122. 

464. 

442. 

464. 

462. 

340. 

47,  78,   336. 

340,   462 

527. 

444. 

462. 

464. 

442. 

313486  O  -  54  -  8 


106  UNITED  STATES  TARIFF  COMMISSION 

TABLE  i.7B.- -Synthetic  organic  chemicals:    Medicinals    for  which  United  States  production  or  sales 
were   reported,    identified  by  manufacturer ,   19 53 --Continued 


Ali 


MEDICIKALS,  CYCLIC — Continued 


nd  H'tt 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


a-Cyclohexyl-o-phenyl-l-pyrrolidinepropanol 

raethylsulfate, 
Cyclopentanol 

Cyclopentyl  bromide 

l-Cyclopentyl-2-methylpropylamine 

l-Cyclopentyl-2-methylpropylamine  (Cyclopentamine) 
hydrochloride . 

a-Cyclopentyl-o-phenyl-l-piperidinepropanol 

Cytidine  and  cytidine  sulfate 

Cytidylic  acid 

Cytosine 

Desoxyribonucleic  acid 

Dextran  (Glucopyranose  anhydride) 

2,4-Diamino-5-(p-chlorophenyl)-6-ethylpyrimidine 

(Daraprim). 
N-  [p-(2,'4-Diamino-6-pteridylmethylamino)benzoyl] 
glutamic  acid. 

-♦jV-Dichloroquinoline 

Diethylaminocarbethoxybicyclohexyl  (Dicyclomine) 

hydrochloride  (Bentyl  hydrochloride). 
6-(  2  -Diethylaminoethoxy ) -2 -dime thy laminobenzo- 
thiazole  hydrochloride. 

3,3-Diethyl-2,'i-dioxopiperidine 

N,N-Diethylpioolinamide  (Pyridine- ^carboxylic 
acid,  diethylamide). 

»Dihydrocodeinone  bitartrate 

Dihydrohydroxycodeinone  hydrochloride 

Diiodochelidamic  acid 

3,5-Diiodo-N-methyl-4-pyridone-2,6-diearboxylic 

acid. 
3,5-Diiodo-4-pyridone-N-aoetlc  acid,  diethanolamine- 

»5,7-Diiodo-8-quinolinol 

6,7-Dimethoxy-l-(4-ethoxy-3-methoxybenzyl)-3-methyl 
quinoline  phosphate  ( Dioxylline  phosphate ) . 

i-Dimethylaminoantipyrine  ( Aminopyrine ) 

Pji-Dimethylbenzyl  camphorate,  diethanolamine  salt— 
N,a-Dimethylcyclohexane-ethylamine  (1-Cyclohexyl- 

2-methylaminopropane ) . 
l,3-Dimethyl-4-phenyl-4-propionoxypiperidine 

hydrochloride  (dl  a  form). 
N,N-Dimethyl-4-piperidylidene-l,l-diph6nylmethane 
methyl  sulfate  ( Diphenmethanil  methyl  sulfate). 
Diothane  (Piperidinepropanediol  diphenylurethane) 
base. 

Diothane  hydrochloride 

»5, 5-Diphenylhydantoin  and  sodium  salt 

l-(Diphenylmethyl)-4-methylpiperazinium  (Marezine) 
(Cyclizine)  hydrochloride. 

Epoxytropine-tropate  methylbromide 

5-Ethyl-3,5-dimethyl-2,i-oxazolidlnedione 

Ethjl  l-methyl-4-phenylisonipecotate  (Demerol) 

Fructose-6-phosphate,  barium  §alt 

Glucose-1 -phosphate,  potassium  salt 

Glucose -6-phosphate,  barium  salt 

Glucuronolaotone 

Guanine 

Guanine  hydrochloride ~ 

Guanine  sulfate 

Guanosine 

Guanylic  acid  and  sodium  salt 

Hexamethylenetetramine 

Hexamethylenetetramine  acetaminosalioylic  acid 

(Salihexin). 
Hexamethylenetetramine  anhydromethylene  citrate 
(Helmitol). 

Hexamethylenetetramine  camphosulfonate 

Hexamethylenetetramine  mandelate 

Hexamethylenetetramine  methylene  citrate 

Hexamethylenetetramine  methyl  iodide 

Hexamethylenetetramine  salicylate 

Hexamethylenetetramine  sulfosallcylate 

Hexamethylenetetramine  tetraiodide 

Hexokinase 

Hexosediphosphoric  acid  salts: 

Barium  hexosediphosphate 

Calcium  hexosediphosphate ~ — — 

Magnesium  hexosediphosphate — — — — — 


442. 

442. 
442. 
245. 
AA2. 

442. 

462. 

462. 

462. 

462. 

281,  367. 

163. 

464. 

400. 
281. 

452. 

452. 
47. 

231,  267,  419. 
419. 

494,  515. 
457. 

379. 

78,  325,  360,  389,  468,  547. 

442. 

360,  527. 

187. 

308. 

452. 

457. 

289. 

129,  289. 

78,  381,  389,  394,  397,  494,  515,  542. 

163. 

X. 

565. 

379. 

462. 

462. 

462. 

287. 

462. 

462,  498. 

462. 

462. 

462. 

397. 

565. 

379,  591, 

591. 

205. 

591. 

468. 

591. 

591. 

246,  591. 

340. 

462. 
462. 
462. 


SYNTHETIC  ORGANIC  CHEMICALS,  I953 

TABLE  17B. -Synthetic  organic  chemicals:    Hedicinals    for  which  United  States  production  or  sales 
were  reported,    identified  by  manufacturer ,   J953- -Continued 


107 


MEDICINALS,  CYCLIC —Continued 
Alicyclic   and  He terocyc I ic--Continaed 

»Honnones  (steroid): 

21-Acetoxypregnenolone 

Adrenocorticotropic  hormone  (ACTH) 

Desoxycortioosterone  acetate 

Estradiol 

Estradiol  3-benzoate 

Estradiol  trimethylacetate 

Estrogenic  substance 

»Estrone 

Estrone  sulfate,  sodium  salt 

Ethinylestradiol 

Ethinyltestosterone 

Hydrocortisone  alcohol  and  acetate 

»17 -Hydroxy -11-dehydrocortioosterone  ( Cortisone ) 
and  acetate. 

Methylandrostenedial 

Methyltestosterone 

Piperazine  estrone  sulfate 

Pregnenolone 

Pregnenolone  acetate 

•Progesterone 

Reichsteins  substance  S  acetate 

Reichsteins  substance  S  alcohol 

Testosterone "^ 

Testosterone  cyclopentylpropionate 

Testosterone  propionate 

1-Hydrazinonaphthalazine  hydrochloride 

«8-Hydroxy-7-iodo-5-quinolinesulfonic  acid  (Yatren 
acid)  and  salt. 
l-(3-Hydroxy-5^ethyl^-phenylhexyl)-l-methyl- 
piperidinlum  bromide  (Darstine). 

8-Hydroxy-5-quinolinesulfonic  acid 

Hypoxanthine 

Isonicotinic  acid  hydrazide 

I^sidine  bltartrate 

Menthyl  salicylate 

homo -Menthyl  salicylate 

6-Mercaptopurine 

fl-Methoxy-7-hydroxymercuric  propylamide  of 

camphoric  acid  (Mercurial  acid). 
^-Methoxy-y-hydroxymercurlo  propylamide  of 

camphoric  acid,  sodium  salt  with  theophylline 
( Mercupur in ) . 
8-(2'-Methoxy-3-hydroxymercuri)  propyl  coumarin 
3-carboxylio  acid  (Mercumallylic  acid). 

Methylcholanthrene 

3, 3 '-Methylenebis[ 4-hydroxycoumarin]  (Dicumarol ) 

Methyl  2-furoate 

Methyl  nicotinate 

3-(2-Methyl-l-piperidyl)propyl  alcohol 

3-(2-Methyl-l-piperidyl)propyl  benzoate  (Metycaine)- 
3-(2-Methyl-l-piperidyl)pro'pyl  p-oyolohexyloxy- 
benzoate. 

Methylthiouraolls  (5-  and  6-) 

l-Methyl-2-undecylimidazole 

Methyluracils  (5-  and  6-) 

Nbrristyl-y-picolinium  chloride  (Quatresin) 

2 -( 1 -Naphthylmethyl ) -2 -imidazoline  hydrochloride 

(Privine). 
Neocinchophen  (Ethyl  6-methyl-2-phenyloinohoninate)- 

5-Nitro-2-furaldehyde  diacetate 

5-Nitro-2-furaldehyde  semlcarbazone  (Furacin) 

5-Nitro-2-furfurylidene  1-aminohydantoin 

(Furadantin). 
N-(5-Nitro-2-furfurylidene)-3-amino-2-oxazolidene — 

5-Nltro-2-furfuryl  methyl  ether 

Novalgin  (l-Phenyl-2,3-dimethyl-4-methylamino-5- 
pyrazolone  formaldehyde  bisulfite). 

Nucleic  acid  and  salts 

Pamaquine  (Plasmoohin)  (N-Diethylaminolsopentyl-8- 
amino-6-methoxyquinoline ) . 

Papaverine  hydrochloride,  synthetic 

Perparin  base  and  hydrochloride 

»Phenothiazine 

Phenothiazinecarbonic  ac  id 

Phytic  acid  salts: 

Calcium  phytate 

Iron  phytate 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


X. 

457, 

X. 

46, 

457. 

457. 

300. 

46. 

46, 

400, 

X. 

564. 

457. 

457. 

515, 

X. 

457, 

515, 

X,  X 

457. 

336, 

421, 

457. 

565. 

457, 

X. 

4?7, 

X. 

336, 

400, 

457, 

X. 

X. 

X. 

336, 

421, 

457. 

X. 

336, 

421, 

457. 

336. 

78, 

325, 

379, 

389,  468. 

444. 

325 

389. 

462. 

415 

452 

457, 

522,  562 

431 

468 

431 

431 

163 

381 

591 

381 

591 

419. 

368,  498. 

464,  565,  591. 

129. 

431. 

442. 

442. 

442. 

462. 

442. 

462. 

X. 

336. 

464. 
129. 

129. 

129. 

129. 
129. 
360,  379. 

462. 

379. 

231,  442,  515. 

431. 

59,  251,  327,  333,  448. 

468. 

468. 
468. 


108  UNITED  STATES  TARIFF  COMMISSION 

TABLE  17B. -Synthetic  organic  chemicals.-    Hedicinals   for  which  United  States  producti 
were   reported,    identified  by  manufacturer ,   795 J- -Continued 


MEDICINALS,  CYCLIC— Continued 
AlicycUc   and  He  terocyclic--Contlmiei. 


»Piperazine 

Plperazine  derivatives: 

Piperazine  citrate 

Piperazine  tartrate 

sym-N-Tetramethylpiperazine  diiodide 

6-Propyl-2-thiouraoil 

Pyridium  (2,6-Diamino-3-phenylazopyridine) 

3-Pyridyl-oarbinol  tartrate 

fl-Pyrrolidinopropiophenone  hydrochloride 

Quinacrine  (Atebrin)  (2-Metho}iy-6-chloro-9-diethyl- 

aminopentylaminoacridine ) . 
8-Quinolinol  (S-ffydroxyquinoline)  salts  and  esters: 

8-Quinolincl  base . 

8-Quinolinol  benzoate 

8-Quinolinol  citrate 

8-(iuinolinol  hydrochloride 

8-Quinolinol  phosphate 

8-Quinolinol  sulfate  (Quinosol) 

8-Quinolinol  sulfate,  potassium  salt 

8-Quinolinol  tannate 

d-Ribose 

Ribose-5-phosphate,  barium  salt 

-i«utin _ 

1-Sorbose 

*Terpinol  hydrate 

♦Theobromine  and  derivatives: 

Theobromine,  natural 

Theobromine  calcium  gluconate 

Theobromine  calcium  salicylate 

Theobromine  salicylate 

Theobromine  sodium  acetate 

Theobromine  sodium  salicylate 

•Theophylline  (1,3-Dimethylxanthlne)  base  and 
derivatives: 

Theophylline  acetic  acid 

Theophylline  amlnolsobutanol 

"Theophylline  base 

Theophylline  cholinate 

♦Theophylline  ethylenediamlne  (Aninophylllne) 

Theophylline  methoxymercuripropylsucolnylurea— 

Theophylllne  monoethanolamine 

Theophylline  sodium  acetate 

2-Thlouracil 

Thymidine 

3,5,  5-Trimethyl-2,'t-oxazolidinedione  (Trldlone) 

2-Undecyl -2 -imidazoline 

Uracil 

Uric  acid 

Uridine "IIIIIIIIZZIZZ! 

Uridine-  triphosphate 

Uridylic  acid ZZZZZ! 

l-Vinyl-2-pyTrolidone  polymerized 

♦Vitamins: 
*A,  from  all  sources: 

A,  acetate 

A,  alcohol 

A,  esters  (natural) 

A,  palmitate 

A,  palmitate  (feed  supplement) 

*Bi  (Thiamin  hydrochloride) 

«Bi  (Thiamin  nitrate) 


•Riboflavin  for  human  consumption,  100)6 

*''^''°ni*^^"  f°r  animal  and  poultry  consumption, 

Rlboflavin-5^-phosphate,  dlethanolamine 

Rlboflavin-5  -phosphate,  monosodium  salt 

•fie  ( Pyrldoxlne ) 

•Bij,  100*: 

Feed  grade 

Pharmaceutical  quality Z.ZZZZ 

U.S. P.  Crystalline ZZZZZZZZ 

•Dz  (Irradiated  ergosterol)  (Calciferol) 

•Dj  (Irradiated  animal  sterol)  (Delsterol) 

E  (a-Tooopherol ) 

E  esters:  a -Tocopherol  acetate 

Folic  acid  and  Dlopterln Z 

Inositol 

Inositol  hexaphosphate,  calcium  magnesium 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


78,  360,  368,  "i68. 

78. 
360. 

78,  468. 
464. 

205,  360. 
452. 
442. 
379. 


132,  325. 

132,  325. 

132. 

325. 

325. 

78,  132,  325. 

325. 

132. 

462. 

462. 

389,  400,  562,  600. 

415,  421. 

360,  389,  586,  600. 

245,  274,  562. 

165. 

360,  381. 

231. 

231,  267,  515. 

231,  267,  274,  360,  515. 


394. 

X. 

231,  274,  343,  394,  415. 

360. 

343,  389,  394,  401,  515,  547,  562. 

300. 

389,  442. 

231,  394. 

464. 

462. 

X. 

442. 

462,  498. 

174,  558. 

462. 

340. 

462. 

550. 


386,  415,  452,  498,  515. 

386,  469. 

498. 

415,  452,  498,  515. 

415. 

452,  464,  515. 

452,  515. 

415,  452,  515. 

340,  347,  367,  415,  464,  465. 

452. 
452. 
452,  464,  515. 

340,  347,  367,  397,  415,  464,  465,  515. 

42,  415,  515. 

515. 

99,  162,  228,  248,  379,  400,  421,  465,  469.  489. 

333,  379,  421,  465,  469,  489.  584. 

452. 

452. 

464,  X. 

287,  445. 

336,  360,  445,  468. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


109 


TABLE  17B. -Synthetic 


rganic  chemicals:   Kedicinais   for   which  United  States  production  or 
re  reported,    identified  by  manufacturer,    1953 --Contimjed 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


MEDICINALS,  CYCLIC— Continued 
Alicyclic   and  Htterocyc lie- -Continued 

»Vitamins — Continued 

»Nlaoin 

«Niacinamide  and  niacinamide  hydrochloride- 
Xanthine  and  monosodium  salt 


MEDICINALS,  ACYCLIC 


Acetone,  semlcarbazone 

Aoetylcarbromal 

Acetylcholine  bromide 

•Acetylcholine  chloride 

S -Acetylglutathione 

Acetylmethionine 

Acetyl -/Ssnethylcholine  bromide 

»Acetyl-a-methylcholine  chloride 

Acetyl  phosphate,  lithium  salt 

»Amino  acids: 

d -Alanine 

dl -Alanine 

dl-o-Alanine 

1-Alanine 

*,9-Alanine 

l(+)-Arginine  and  hydrochloride 

1(+ ) -Asparagine 

dl-Aspartic  acid 

l(+)-Aspartio  acid 

l-Citrulline 

l(+ ) -Cysteine  hydrochloride 

1-Cystine 

*1  (+ ) -Glutamic  ao  id 

d-Glutamic  acid,  crude 

1(+) -Glutamic  acid,  calcium  salt 

l(+)-Glutamic  acid  hydrochloride 

l(+)-Glutamlc  acid,  monoammonium  salt 

l(+)-Glutamic  acid,  monopotassium  salt 

1(+) -Glutamic  acid,  monosodium  salt 

Glycine  (Aminoacetic  acid) 

dl-Isoleuoine 

1-Isoleucine 

d-Leucine 

dl-Leucine 

1-Leucine 

1-Leuc  ine  ( Methionine  -free ) '■ 

lysine 

dl-Lysine  hydrochloride 

l(+ ) -lysine  monohydrochloride 

d-Methionine 

dl-Methionine 

1-Methionine 

Methionine,  feed  grade 

dl-Methionlne,  calcium  salt 

dl-Norleucine 

1 -Ornithine 

dl-Serine 

1-Serine ~ 

dl-Threonine 

d-Valine — 

dl-Valine 

1-Valine 

All  other  (mixtures) 

2-Amino-4-methylhexane 

Amyl  nitrite  (Isoamyl  nitrite) 

Antimony  sodium  thioglycolate — 

Auro-thioglucose 

a, a ' -Azobis ( chlorof ormamidine )  ( Azochloramide ) - 

Betaine  base 

Betaine  hydrate 

»Betaine  hydrochloride 

Bismuth  octyloxyacetate  (Lipo  bismol) — 

Broroocholine  bromide 

Bromof orm  ( Tribromomethane ) 

Bromural  (a  -Bromoisovalerylurea) 

Cacodylic  acid  derivatives: 

Iron  caoodylate 

Sodium  cacodylate 

Calc  ium  borohibate — 

Calc  ium  bromolaotobionate 

Calcium  glyoerate 

Calcium  iodobehenate 


205,   A6i, 

515, 

536. 

205,   2<t8, 

464. 

^62. 

129. 

198,   ^9^. 

78,    360. 

78,   360, 

468, 

515. 

462. 

360,   463. 

78. 

78,   468, 

515. 

462. 

462. 

448. 

558. 

462. 

248,  421, 

515, 

558,    563 

558. 

558. 

527,    558. 

558. 

462. 

290,    558. 

558. 

171,   228, 

384, 

558. 

462. 

171,    389. 

171,   228, 

558. 

171. 

171. 

558. 

187,   343, 

448, 

558. 

558. 

448. 

462. 

448,    558. 

445,    515, 

558. 

558. 

333. 

448. 

558. 

462. 

448,   463, 

558. 

462. 

463. 

515. 

515,    558. 

462. 

468,    515, 

558. 

462. 

468,    558. 

462. 

448,    515, 

558'. 

462. 

445,   463. 

442. 

231,   498. 

468. 

457. 

313. 

360. 

171. 

171,    360 

389. 

400. 

468. 

448. 

198. 

78,   400. 

78,  400. 

464. 

468. 

591. 

591. 

110  UNITED  STATES  TARIFF  COMMISSION 

TABLE  nB. --Synthetic  organic  chemicals:    Hedicinals    for  which  United  States  production  or  sales 
were  reported,    identified  by  manufacturer,    i95J- -Continued 


MEDICINALS,  ACYCLIC — Continued 

Calcium  lactophosphate 

Calcium  levulinate 

Calcium  methionate 

Calcium  salts  of  sugar  acids 

*Calcium  succinate 

Carbaminol  choline  chloride 

Carbaiiiyl-2-hydroxypropyltrlmethylammonium  chloride- 

Carbromal  (Bromodiethylacetylcarbamide) 

Chloral  hydrate 

Chloretone  (tert-Trichlorobutyl  alcohol) 

Chloriodized  oil 

l-Chlorobutane 

2-Chloro-N,N-dimethylethylamine  (Dimethylaminoethyl 
chloride)  hydrochloride. 

2-Chloro-N,N-dlmethylpropylamine  hydrochloride 

2-Chlorotriethylamine  (Diethylaminoethyl  chloride) 
hydrochloride. 

Choline  bicarbonate 

^Choline  bitartrate 

«€hollne  chloride,  for  animal  and  poultry  feed  and 
for  use  as  an  intermediate. 

^Choline  chloride,  medicinal  grade  only 

Choline  chloride,  nonmedicinal 

Choline  citrus  meal 

Choline  dihydrogen  citrate 

Choline  gluconate 

Choline  tricitrate 

Diallylacetic  acid  and  bismuth  salt 

2,2-Diisopropyl-5-hydroxymethyl-l,3-dioxolane 

1,2-Dimercaptopropanol 

Disodium  methanearsonate  (Arrhenal) 

Divinyl  ether 

Ethylenediamine  dlhydroohloride 

Ethylenediamine  diiodide 

Ethyl  iodide 

Ethylmercuric  chloride 

Ethyl  morrhuate 

Ethyl  nitrite 

Gluconic  acid  salts: 

Aluminum  gluconate 

Ammonium  gluconate 

Calcium  glucoheptonate 

Calcium  gluconate 

Copper  gluconate 

Iron  (ferrous)  gluconate 

Magnesium  gluconate 

Manganese  gluconate 

Potassium  gluconate 

Sodium  gluconate 

Glucono-delta -lactone 

Glutathione 

Glutathione,  monosodium  salt 

Glutathione,  oxidized 

Glycerophosphoric  ac  id 

Glycerophosphorio  acid  derivatives: 

Calcium  glycerophosphate 

Iron  glycerophosphate 

Magnesium  glycerophosphate 

Manganese  glycerophosphate 

Potassium  glycerophosphate 

Sodium  glycerophosphate 

Strychnine  glycerophosphate 

Zinc  glycerophosphate 

Hendecenoic  acid  (Undecylenic  acid)  salts: 

■  Copper  hendecenoate 

Zinc  hendecenoate 

Hexamethyldiaminolsopropanol  diiodide 

Hexamethylenebis[trimethylammonlum  base] 

(Hexamethonium  base). 
Hexamethylenebis[trimethylammonium  bitartrate] 

(Hexamethonium  bitartrate). 
Hexamethylenebis [trimethylammonium  bromide] 

(Hexamethonium  bromide). 
Hexamethylenebis [trimethylammonium  chloride] 

(Hexamethonium  chloride). 
Hexamethylenebis [trimethylammonium  iodld^ 
(Hexamethonium  iodide). 

Hexamethylenemethyl  iodide 

Iodized  castor  oil 

Iodized  oils,  other 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


231. 

360. 

A68. 

AA2. 

360, 

389,  527,  600. 

515. 

515. 

198, 

379,  494. 

360, 

515. 

229, 

343,  431. 

547. 

32A. 

181, 

542,  565. 

181. 

181, 

542. 

367. 

78,  32A,  360,  426, 

464, 

607. 

324, 

367,  421,  464 

465 

607. 

78, 

324,  360,  426, 

464, 

515,  607 

493, 

515. 

426. 

78, 

324,  360,  426, 

464, 

607. 

367. 

324, 

360,  426,  464 

607 

187. 

198. 

591. 

379. 

515. 

281. 

246. 

515, 

599. 

442. 

591. 

231. 

360. 

415. 

558. 

231, 

415,  558. 

415. 

360, 

415. 

360, 

415. 

415. 

75, 

415. 

415. 

415. 

462. 

462. 

462. 

245, 

397. 

245, 

281,  397. 

245 

397. 

245 

397. 

245 

281,  397. 

245 

397. 

245 

397. 

75. 

75. 

360. 

360. 

379 

468. 

468 

468 

542. 

542 

468 

542. 

468 

468 

431 

442 

SYNTHETIC  ORGANIC  CHEMICALS,  1953  111 

TABLE  17B.- -Synthetic   organic  chemicals;    Medicinals    for  which  United  States  production  or   sales 
were   reported,    identified  by  manufacturer,    1953- -Continued 


MEDICINALS,  ACYCLIC— Continued 


Iodoform 

lodomethanesulfonic  acid,  sodium  salt 

Iron  (ferrous)  oxalate 

Isovaleric  acid  salts: 

Ammonium  isovalerate 

Zinc  isovalerate 

Lactic  acid  salts  (medicinal  grades  only): 

Aluminum  lactate 

Iron  (ferrous)  lactate 

Lithium  pyruvate 

Magnesium  citrate  soluble 

Malononitrile 

Methylenecitric  acid  salts 

^Methylene  iodide 

»Methyl  iodide,  all  grades 

3-Methyl-l-pentyne-3-ol 

Morrhuio  acid,  copper  salt 

MDrrhuio  acid,  sodium  salt 

Phosphoglyceric  acid 

2-Propylvaleric  acid,  bismuth  salt 

Silver  protein,  mild 

Silver  protein,  strong 

Sodium  bismutn  triglycolamate 

Sodium  iodopropanol  sulfonate 

Sodium  pyruvate 

^Sodium  succinate 

Succinyloholine  dichloride 

Succinyl  peroxide — 

Sulf one thy Ime thane 

Tartaric  acid  salts,  medicinal  grades  only: 

Ammonium  tartrate 

Antimony  potassium  tartrate 

Bismuth  potassium  tartrate 

•Calcium  tartrate ■ 

Potassium  bitartrate 

Potassium  sodium  tartrate  (Bismosal) 

Sodium  tartrate 

Tetraethylammonium  chloride 

Tetrajnethylammonium  chloride 

Thiosemicarbazide 

Thiosinamine  (Allyl thiourea) 

2,2, 2-Tribromoethanol 

Triiodoethionio  acid 

»Vitamins : 

•Ascorbic  acid  and  derivatives: 

Ascorbic  acid 

Ascorbic  acid,  calcium  salt 

Ascorbic  acid,  sodium  salt 

Ascorbyl  palmitate 

•Pantothenic  acid  and  derivatives: 

Pantothenic  acid 

•Pantothenic  acid,  d-calcium  salt 

•Pantothenic  acid,  dl-oaloium  salt 

Pantothenic  acid,  sodium  salt 

d-Pantothenyl  alcohol  (a,>'-Dihydroxy-N-(3- 
hydroxypropyl )  -ff,  ;3-dimethylbutyramide ) . 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


75,  231,  267. 
360,  379. 
360. 

-168,  494. 
494. 

360. 

231. 

462. 

515. 

132,  462. 

379. 

233,  360,  368,  379,  468,  498,  515. 

231,  468,  498. 

457. 

591. 

400,  591. 

462. 

187. 

400. 

379,  397. 

X. 

431. 

462. 

231,  515,  600. 

163. 

431. 

231. 

360. 

415. 

468. 

78,  281,  360. 

217,  360,  415. 

217,  281,  415,  468. 

281,  360. 

468. 

468. 

78,  133. 

78,  431-. 

379. 

457. 


415,  452,  515. 

415. 

415,  452,  515. 

415. 

465. 

415,  421,  442,  464,  515. 

248,  421,  464,  565. 

400. 

452. 


112 


UNITED  STATES  TARIFF  COMMISSION 
Flavor  and  Perfume  Materials 


P 


TABLE  16B-  --Synthetic  organic  chemicals:    Flavor   and  perfume  materials    for  which  United  States 
production    or    sales  were  reported,    identified  by  manufacturer ,    1^53 

[Flavor  and  perfume  materials  for  which  separate  statistics  are  given  in  tahle  ISA  are  marked  below  with  an 
asterisk  (»);  those  not  so  marked  do  not  appear  in  table  18A  because  the  reported  data  are  confidential 
and  may  not  be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from  table  27] 


Manufacture! s '  identification  numbers 
(according  to  list  in  table  27) 


FLAVOR  AND  PEKFDME  MAIERIAIS,  CYCLIC 


Be 


id  and  Naphthalenoid 


2-Aoetonaphthone  (Methyl  ^ -naphthyl  ketone) 

Acetophenone 

Amyl  benzoate- 


^-Amylcinnamaldehyde ^ 

ii-Amylcinnamaldehyde,  dimethyl  acetal 

Amyl  cinnamate- 


a-Amylcinnamyl  alcohol 

Amyl  phenylacetate  (Isoamyl  a-toluate) 

»Amyl  salicylate  (Isoamyl  salicylate) 

*Ane thole 

»Anisaldehyde 

Anisole  (Methyl  phenyl  ether) 

Anisyl  acetate 

Anisyl  alcohol 

Anisyl  formate 

Anisyl  propionate 

*Benzophenone — 


*Benzyl  acetate 

»Benzyl  alcohol,  all  grades 

Benzyl  benzoate,  perfume  grade  only- 
»Ben2yl  butyrate 

Benzyl  ohloroacetate 

»Benzyl  cinnamate — 

Benzyl  ether,  perfume  grade  only 

*Benzyl  formate 

Benzyl  isoamyl  ether 

Benzyl  isobutyrate 

»Benzyl  isoeugenyl  ether 

Benzyl  isovalerate- 


Benzyl  phenylacetate  (Benzyl  a -toluate) 

•Benzyl  propionate ________ 

»Benzyl  salicylate 

Benzyl  valerate—- 

i-Bromostyrene- ________—— 

4-tert-Butyl-2, 6-dimethyl-3, 5-dinitroacetoph6none 
(Musk  ketone). 

3-tert-Butyl-2 , 6-dinitro-p-oymene 

6-tert-Butyl-3^iiethyl-2,  <i-dinitroanisole  (Musk 

ambrette) . 
5-tert-Butyl-2,4,6-trinitro-m-xylene  (Musk  xylol) - 
Carvacrol  (Isopropyl-o-cresol) 

C  innamaldehyde 

Cinnamio  acid — — — 

*Cinnamyl  acetate _____——_— 


Cinnamyl  alcohol 

Cinnamyl  anthranilate- 

Cinnamyl  butyrate 

Cinnamyl  cinnamate 

Cinnamyl  formate 

Cinnamyl  isobutyrate— 
Cinnamyl  isovalerate — 

Cinnamyl  propionate 

Cinnamyl  valerate 

Cumaldehyde  (p-Isopropylbenzaldehyde) - 


1- Dimethylbenzyl  alcohol  (p-Methylphenylmethyl- 
carbinol) . 
,a-Dimethylphenethyl  aoetate- 


a,a-Dimethylphenethyl  alcohol — 
a  ,a-Dimethyl-3-phenylpropanol — 
Diphenylmethane- 


1 , 3-Diphenyl-2-pr opanone  (Dlbenzyl  ketone) - 
Duloin  (p-Phenetylurea)- 


2-Ethoxynaphthalen6  (Ethyl  /9_naphthyl  ether) - 
Ethyl  anisate- 


»Ethyl  anthranilate 

Ethyl  benzoate ___—_———— 

Ethyl  cinnamate- ■ 

»Ethyl  a^^_epoxy-^-methylhydrocinnamate  (Ethyl 
methylphenylglyoldate) . 
2-Ethylhexyl  salicylate 
Ethyl  methyltolylglycidate  ■ 

Ethyl  ^-phenylglycidate 

Ethyl  salicylate 

Ethyl vanillin 


229, 

582. 

229, 

392, 

431. 

225, 

229, 

508, 

582. 

229, 

451, 

508, 

511, 

562, 

582, 

508, 

582. 

225, 

508, 

582. 

451, 

582. 

229, 

414, 

508, 

582, 

598. 

229, 

274, 

370, 

582, 

593. 

222, 

229, 

285, 

582. 

229, 

431, 

582, 

593. 

229, 

431. 

225, 

229, 

508, 

582. 

229, 

582. 

225, 

508, 

582. 

508, 

582. 

229, 

266, 

582. 

229, 

266, 

451, 

562, 

582. 

?29, 

255, 

331, 

343, 

402, 

451,  562,  582 

229, 

245, 

255, 

331, 

402, 

431,  562. 

225, 

229, 

414, 

508, 

562, 

582. 

274. 

229, 

255, 

508, 

582. 

229, 

562. 

229, 

274, 

508, 

582. 

229, 

582. 

225, 

229, 

508, 

582. 

229, 

508, 

511, 

582. 

229, 

508, 

582. 

229, 

274, 

508, 

582, 

598. 

225, 

229, 

414, 

451, 

508, 

562,  582,  598 

229, 

255, 

562, 

582. 

225, 

508, 

598. 

582. 

229, 

562. 

229. 

229, 

562. 

229, 

562. 

229. 

229, 

431, 

582. 

229, 

343, 

431. 

229, 

414, 

508, 

582. 

229, 

562, 

582. 

508, 

598. 

225, 

414, 

508, 

582. 

229, 

508, 

582. 

508, 

582, 

598. 

225, 

508, 

582. 

225, 

229, 

508, 

582. 

229, 

508, 

582. 

225, 

255, 

508, 

598. 

229, 

333, 

460. 

229. 

451. 

451. 

451. 

582. 

229. 

431, 

468. 

229, 

266. 

431, 

508. 

133, 

508, 

562, 

598. 

229 

397, 

463, 

508, 

582. 

229 

508, 

582. 

229, 

431, 

508, 

582, 

598. 

598 

229 

508 

431 

582 

598 

582 

245 

SYNTHETIC  ORGANIC  CHEMICALS,  1953 

TABLE  IHB^- -Synthetic  organic  chemicais:    Flavor   and  perfume  materials    for  which  United  States 
production   or   sales   were   reported,    identified  by  manufacturer ,    795J- -Continued 


113 


Mamif acturers '  identification  numbers 
(according  to  list  in  table  27) 


FLAVOR  AND  PERFUME  MAIERIALS,  CYCLIC— Continued 
Benzenoid   and  Naphthalenoid — Continued 


•Eugenol 

»Eugenyl  methyl  ether- 
Hexylc  innamaldehyde- 


Hydratropaldehyde  (<i-Phenylpropionaldehyde) 

Hydratropaldehyde,  dimethyl  acetal- 


Hydrooinnamaldehyde  (fi  -Phenylpropionaldehyde) 

"1— ('i-Hydroxy-3-methoxyphenyl)-3-buten-2-one 
(Vanillidine  acetone) . 

«Isobutyl  benzoate  

Isobutyl  oinnamate- 


Isobutyl  phenylacetate  (Isobutyl  a-toluate)- 

Isobutyl  salicylate 

*Isoeugenol- 


Isoeugenyl  acetate- 
Isoeugenyl  methyl  ether- 


p-Isopropyl-ii-methylhydrooinnamaldehyde  (Cyclamen 
aldehyde) . 

p-Methoxyacetophenone 

2-Methoxybiphenyl- 


»2-Methoxynaphthalene  (Methyl  ,8-naphthyl  ether)  — 

p-Methylaoetophenone  (Methyl  p-tolyl  ketone) 

Methyl  anisate- 


p-Methylanisole  (p-Cresyl  methyl  ether)- 

Methyl  anthranilate-—— — — — 

Methyl  benzoate- 


a-Methylbenzyl  acetate- 
p-Methylbenzyl  acetate- 


a-Methylbenzyl  alcohol  (Methylphenylcarbinol)- 

o-Methylbenzyl  propionate 

Methyl  oinnamate- 


Methyl  N-methylanthranilate  (Dimethyl  anthranilate) 
/9-Methylphenethyl  alcohol  (2-Phenyl-l-propyl 
alcohol) . 

Methyl  phenylacetate  (Methyl  a-_toluate) 

"Methyl  salicylate  (Synthetic  wintergreen  oil) 

*Phenethyl  acetate 


*Phenethyl  alcohol 

Phenethyl  anthranilate- 

Phenethyl  butyrate 

Phenethyl  oinnamate— — 

Phenethyl  formate 

Phenethyl  isovalerate- 


Phenethyl  phenylacetate  (Phenethyl  a-toluate) 

Phenethyl  propionate 

Phenethyl  salicylate 

Phenethyl  valerate- 


2-Phenoxyethyl  isobutyrate 

Phenylaoetaldehyde  (a -Tolualdehyde) 

Phenylacetaldehyde,  dimethyl  aoetal 

4— Phenyl-3-buten-2-one  (Benzylidene  acetone) - 
Phenyl-1, 2-ethanediol  diaoetate- 


l-Phenyl-2-propanone  (Benzyl  methyl  ketone) - 
3-Phenyl-l-propyl  acetate- 


3-Phenyl-l-propyl  alcohol  (Hydrocinnajnic  alcohol) - 

Propyl  oinnamate 

S  alicylaldehyde- 


p -Tolualdehyde  (p-Methylbenzaldehyde)- 
*p-Tolyl  acetate  (p-Cresyl  acetate) — 


p-Tolyl  isobutyrate  (p-Cresyl  isobutyrate )- 
»p-Tolyl  phenylacetate  (p-Cresyl  a-toluate)- 


-(Trichloromethyl)benzyl  acetate  (Rosetone)- 
-Trimethylphenethyl  alcohol — 


2,3, 5-Trimethyl-l, 2,3, 6-tetrahydrobenzaldehyde- 
Vanillin 

Terpenoid,    Heterocyclic,    and  Alicyclic 


Allyl  cyolohexanepropionate- 

Bomyl  acetate 

Carvone  (Carvol) 

C  aryophyllene 

C  edrenal 

C  edr ol 


*Cedryl  acetate 

Cineole  (Eucalyptol) - 
»Citral  (Geranial) 


229,  230, 

402 

431 

508,  511,  582 

593,  600 

229,  431, 

508 

582 

333,  508, 

582. 

229,  451, 

582. 

451,  582 

229. 

508. 

225,  229, 

274, 

508, 

582. 

225,  508, 

582, 

598. 

229,  508, 

582. 

229,  508, 

582. 

229,  352, 

402, 

508, 

582. 

229,  508. 

229,  431, 

508, 

582, 

229,  460. 

431. 

451. 

229,  451, 

508, 

582. 

229,  352, 

582. 

431,  508. 

229,  431, 

460, 

508, 

598. 

229,  333, 

448, 

508, 

562. 

225,  397, 

431. 

229,  508, 

511, 

582. 

431. 

582. 

508. 

229,  343, 

431, 

582. 

-" 

229,  333, 

508, 

598. 

451. 

229,  245, 

266, 

508, 

582,  600. 

245,  397, 

448. 

229,  352, 

451, 

508. 

229,  352, 

448, 

451, 

600. 

133,  229, 

508, 

598. 

133,  229, 

274, 

508. 

451,  508, 

598. 

229,  451, 

508. 

229,  274, 

414, 

508, 

582. 

229,  508, 

582. 

229. 

229. 

508,  598. 

229. 

229,  582. 

229,  508, 

582. 

274,  508, 

582. 

451. 

582. 

582. 

229,  508, 

582. 

508,  598. 

448,  572. 

229,  397, 

431. 

229,  414, 

508, 

582, 

598. 

451,  508. 

229,  508, 

511, 

582, 

598. 

431. 

451. 

451. 

98,  229, 

245, 

274. 

508. 

285,  508, 

598. 

414,  507, 

508, 

600. 

229. 

511,  582. 

451,  511, 

582. 

229,  352, 

451, 

511, 

582. 

507,  520. 

229,  230, 

274, 

414, 

451,  508,  511, 

582,  593, 

114  UNITED  STATES  TARIFF  COMMISSION 

TABLE  18B. --Synthetic  organic  chemicals:   Flavor  and  perfume  materials   for  which  United  States 
production  or  sales  were   reported,    identified  by  manufacturer,   1953- -Continued 


FLAVOR  AND  PEEiFUME  MATERIALS,  CYCLIC— Continued 


Ttrpenoid,    He 


and  Alicycli 


*Citronellal 

*C itronellol 

niitronellyl  acetate 

Citronellyl  butyrate 

Citronellyl  formate 

Citronellyl  isobutyrate 

♦Citronellyl  propionate 

*Coujnarin "      — ' 

Cyolohexanesxilfamio  acid,  calciinn  salt- 
Cyclohexanesulfamic  acid,  sodium  salt — 

Cyclop entanol 

Cyclopentanone- 


Dihydrocitronellol 

3,7-Dlmethyl-3-octanol   (Tetraliydrolinalool)- 
*Cleraiiiol —— 


«Geranyl  acetate 

Geranyl  benzoate 

Geranyl  butyrate 

♦Geranyl  formate 

Geranyl  isovalerate- 


Ger?inyl  phenylaoetate  (Geranyl  a_toluate)- 

Geranyl  propionate 

a -Heptyl-a-butyr olaotone- 


2-Hexyl-2-cyolopenten-l-one 

Hydrocoumarin  (SjA-Dihydrocoumarin)- 
♦Itydroxycitronellal- 


Manuf acturers '  identification  numbers 
(according  to  list  in  table  27) 


Hydroxyoitronellal,  dimethyl  acetal- 


*a/-Ionone- 


» ,8-Ionone — — 

»Ionone  (a-  and  ^-) 

Isobomeol  (Isobornyl  alcohol)- 

Isobornyl  acetate 

Isobornyl  propionate 

Isobutylquinoline 

Isopropylquinoline 

Isopulegol 

Isopulegyl  acetate 

Isosafrole 

d-Limonene 

»Linalool- 


»Linalyl  acetate 

Linalyl  anthranilate- 

♦Linalyl  benzoate 

Linalyl  butyrate 

Linalyl  cinnamate 

♦Linalyl  formate 

Linalyl  isobutyrate — 
Linalyl  isovalerate- 


Linalyl  phenylacetate 

♦Linalyl  propionate 

♦Menthol,  synthetic,  tech — 
♦Menthol,  synthetic,  U.S.P- 

Menthone- 


Menthyl  anthranilate 

Menthyl  isovalerate 

Metahomomenthol  (Cyclonol)- 

3-Methylooumarin- 

6-Methylooumarin 

♦Methyl-n -ionone 


Methyl-/3-ionone 

♦Methyllonone  (a-  and  g-)- 


6-Methylquinoline- 


♦Nerol- 
Neryl  acetate- 


♦Pipercnal  (Heliotropin)- 
♦Rhodinol 

Rhodinol  rose — — — — 
♦Rhodinyl  acetate 

Rhodlnyl  formate 

Saccharin- 


Saccharin,  calcium  salt- 
Saccharin,  sodium  salt — 

♦Safrole 

♦Santalol 

Skatole — 


229, 

229, 

229, 

133, 

229, 

229. 

229, 

245, 

565, 

565, 

101 

101 

229, 

582 

229 

225, 

133, 

225, 

225, 

133, 

229, 

225, 

451. 

451. 

431. 

229, 

229, 

229, 

229, 

229, 

229, 

333. 

229, 

333. 

133. 

133. 

229, 

229, 

229, 

508. 

229, 

229, 

133, 

133, 

225, 

511, 

229, 

229, 

508, 

133. 

225, 

229, 

229 

225, 

229 

133 

431 

274 

229 

229 

274 

229, 

451. 

414, 

582. 

229, 

229, 

511. 

229, 

229, 

245, 

301. 

245, 

229, 

229, 

133. 


414,  562,  582. 

255,  451,  508,  511,  562,  582. 

451,  508,  562,  582. 

229,  508,  582,  598. 

451,  508,  511,  582. 

451,  508,  582. 

274,  333,  448,  582. 


255,  352,  414,  451,  508,  511,  567,  582. 

229,  255,  414,  451,  508,  511,  562,  582,  598. 

229,  508. 

229,  508,-  511,  582,  598. 

229,  414,  451,  511,  582,  598. 

414,  508,  582. 

582. 

229,  451,  508,  582. 


255,  352,  511,  582,  593. 

582. 

448. 

230,  274,  451,  511,  582. 

274,  352,  582. 

230,  274,  352,  451,  511. 


333,  582. 


511,  562,  582. 

582. 

582. 

352,  414,  451,  508,  511,  582,  598,  600. 

230,  352,  414,  451,  508,  511,  582,  593,  598. 

508,  511. 

229,  508,  511. 

414,  508,  582. 

582. 

414,  508,  582. 

508,  582,  593. 

582. 

229,  451,  508,  582. 

352,  431,  562. 

352,  507,  562. 

229,  431,  511,  562. 
508. 
508. 


274,  352,  451,  582. 

230,  274,  333,  451,  511. 

451,  511,  582. 

230,  402,  582,  593. 

230,  255,  333,  402,  414,  451,  508,  582,  598. 

255,  414,  451,  508,  582. 

451,  508,  598. 

301. 

301. 

414,  520,  582,  600. 

451,  598. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


115 


TABLE  18b.  -Synthetic  organic  chemicals:   Flavor   and  per  time  materials   for   which  United  States 
production  or   sales  were   reported,    identified  by  manufacturer,   i95J--Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


FLAVOR  AND  PERFUME  MAIERIALS,  CYCLIC — Continued 
Terpenoid,   Heterocyclic,    and  Alicyclic — Continued 


»Terpineols: 
a-Terpineol- 
^-Terpineol- 


Terpineol  (a-  and  ^-)- 


Terpinol  hydrate  (Terpin  hydrate),  tech- 

»Terpinyl  acetate 

Terpinyl  propionate- 


l,2,3,4-Tetrahydro-6-methylquinoline 

Tririiethyl-A.-oyclohexene-1-carboxyaldehyde 

Vetivenol 


*Vetivenyl  aoetate- 


FLAVOR  AND  PERFUME  MATERIAI5,  ACYCLIC 


»Allyl  oaproate- 
Allyl  caprylate 


Allyl  enanthate  (Allyl  heptanoate) 

Allyl  isothiooyanate  (Synthetic  mustard  oil)- 
Allyl  propionate- 


Allyl  sulfide  (Diallyl  sulfide) 

2,3-Butanedione  (Biacetyl) 

«n-Butyl  butyrate 

Butyrone  (Di-n-propyl  ketone) 

Capraldehyde  (Deoyl  aldehyde)  (Cio)  — 
Caprylaldehyde  (Octyl  aldehyde)  (Cs)- 

Decyl  acetate 

n-Decyl  alcohol 

Diethyl  sebaoate  (Ethyl  sebaoate) 

Diethyl  succinate- 


Dodeoyl  acetate  (Lauryl  acetate) 

Enanthaldehyde  (n-Heptaldehyde)  (C7)- 
■Ethyl  butyrate- 


«Ethyl  caprate  (Ethyl  decylate) 

»Ethyl  oaproate  (Ethyl  hexoate) 

»Ethyl  caprylate  (Ethyl  ootoate) 

Ethyl  enanthate  (Ethyl  heptylate) 

Ethyl  isobutyrate— — — — 

Ethyl  isovalerate 

Ethyl  laurate 

Etliyl  levulinate 

Ethyl  myristate 

Etl^l  oleate 

•Ethyl  pelargonate 

•Glutamic  acid,  monosodium  salt  (Monosodium  gluta- 
mate) . 

Hondecanaldehyde  (Undecyl  aldehyde)  (Cn) 

2-Hendecanone  (Methyl  nonyl  ketone) 

Hendecenaldehyde  (Undecylenic  aldehyde) 

Hendecenoic  acid  (Undecylenio  acid) 

Hendecenol  (Undecylenyl  alcohol) 

Heptyl  alcohol  (Heptanol) 

2 , 3-Hexanedione  ( Acetylbutyral) 

3-Hj-droxy-2-butanone  (Acetoin) 

Y-Hydroxycaprylic  acid,  lactone  (Y-Octalaotone)  — 
i-lfydroxyhendeoanoic  acid,  Y -lactone  (Y-Undecalao 

tone) . 

Y-Hydroxypelargonic  acid,  lactone  (Y-JJonalactone) — - 
•Isoamyl  butyrate  (Amyl  butyrate) — 
Isoamyl  oaproate  (Amyl  caproate) — 
Isoamyl  caprylate  (Amyl  caprylate) - 

•Isoamyl  formate  (Amyl  formate) 

Isoamyl  isovalerate  (Amyl  isovalerate) - 
•Isoamyl  propionate  (Amyl  propionate) — 

•Isobutyl  acetate-' ■ 

Isobutyl  butyrate 

Isobutyl  caproate- 


222, 

285. 
229, 
222. 
229, 
229, 
451. 
333. 
229, 
229, 


Isobutyl  isovalerate 

Isopropyl  pelargonate 

Lauraldehyde  (Dodecyl  aldehyde)  (C12) 

2 -Methylhendeo analdehyde  ( 2-Methy Inonyl ac e taldehyd e ) 

Methyl  hendeoanoate  (Methyl  jndeoylenate) 

6-Methyl-5-hepten-2-one 


285,  352. 

333. 

285,  333,  451,  511,  582,  593,  598. 
508,  582. 


511,  582. 

255,  352,  451,  511,  552,  593. 


225, 
225, 
431, 
431, 
508, 
599. 
343, 
225, 
582. 
229, 
229, 
508, 
229, 
133, 
508, 
508, 

219; 

53, 
414j 
414, 
414, 
508. 
508, 
508, 
370 
133 
229 
370 
229 
171 


229,  414,  431,  451,  508,  582,  598. 

508. 

508. 

599. 

598. 

431. 

508,  582,  598. 

508,  582. 

508,  582. 

582,  598. 

582. 

598. 

582. 

582. 

313. 
414,  508,  582,  598. 

508,  582,  598. 

508,  582,  598. 

508,  582. 

598. 

582. 

582. 

414,  508. 
,  229,  451,  508,  598. 
,  370,  508. 

',   431,  508,  582,  598. 
,  228,  384,  445. 


582. 

229,  582. 

229,  508,  582. 

219,  313,  562. 

229,  582. 

219,  313,  551. 

133. 

133,  508,  598. 

508. 

229,  508. 


Methyl  e -methyl thiolpropionate 

Methyl  nonenoate  (Methyl  nonylenate) 

Methyl  ootynoate  (Methyl  heptine  carbonate) 

Nonyl  alcohol  (C9)— — — — ■  ■  -  — ~ — — 

Octenoic  acid — — — 

n-Octyl  acetate ' 


229, 

53, 

508, 

414, 

229, 

414, 

225, 

225, 

225, 

225, 

508. 

508, 

229, 

229, 

229, 

229, 

508. 

229, 

229, 

229, 

508. 

508, 


508. 
229, 
582, 
508, 
508, 
582. 
229, 
414, 
508, 
229, 


414,  431,  508,  582,  598. 
■  598. 

582. 

582,  598. 

414,  508,  582,  598. 

508,  582. 
582. 

508,  582. 


598. 

508,  582. 
582. 
508. 
582. 

508,  598. 
562. 
508,  582. 

582,  593,  598. 


116  UNITED  STATES  TARIFF  COMMISSION 

TABLE  iSB. -Synthetic   organic  chemicals:   Flavor   and  perfume  materials    for  which  United  States 
production   or  sales  were   reported,    identified  by  manufacturer,    i 953- -Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


FLAVOR  AND  PERTUME  MAIERIAI^,  ACYCLIC — Continued 


n-Ootyl  formate- 
n-Octyl  Isobutyrate- 


Pelargonaldehyde  (Nonyl  aldehyde)  (C9)- 
2 , 3-Pentanedione- 


1-Propanethiol  (n-Propyl  mercaptan)- 
2-Propene-l-thiol  (Allyl  mercaptan)- 
Propyl  propionate 


GHEMICAILY  MODIFIED  ESSENTIAL  OIIS 


Ethyl  oxyhydrate 

Lavandin,  acetylated 

Petitgrain  oil,  acetylated — 
Sassafras  oil,  hydrogenated- 


431, 

508, 

582 

508, 

582, 

593 

229, 

508, 

582 

133. 

508. 

508, 

599. 

508, 

582. 

225, 

230. 

508, 

598. 

508, 

511. 

229. 

SYNTHETIC  ORGANIC  CHEMICALS,  1953 
Plastics  and  Resin  Materials 


117 


TKWE.  l9Ji. -Synthetic  organic  chemicala;     Plaatics     and     reain    materiala   for  which    United  Statea  production 
or   aalea  were  reported,    identified  by  manufacturer ,   1953 

[Plastics  and  resin  materials  for  which  separate  statistics  are  given  In  table  19A  are  marked  below  with  an 
asterisk  (*);  chemicals  not  so  marked  do  not  appear  in  table  19A  because  the  reported  data  are  confiden- 
tial and  may  not  be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from  table  27. 
An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  Identification  number  with 
the  designated  product] 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


PLASTICS  AND  RESIN  MATERIALS,  BENZENOID 

Aniline-formaldehyde  resins 

«Coumarone-indene  resins 

Epichlorohydrin  resins: 

Epichlorohydrin-acetone-phenol 

Epiohlorohydrin-blsphenol 

I^ichlorohydrin-bisphenol-fatty  acid 

Epichlorohydrin-phenol-fatty  acid-rosin 

E^ichlorohydrin-polyamine 

All  other 

♦Petroleum  polymer  and  condensation  resins 

♦Phenolic  and  other  tar-acid  resins: 
♦Unmodified: 

p-tert-Aioylphenol -formaldehyde 

p-tert-Amylphenol-phenylphenol -formaldehyde 

Bisphenol-formaldehyde 

*p-tert-Butylphenol-bisphenol-formaldehyde — 

*p-tert-Butylphenol-formaldehyde 

Cashew  nut  shell  oil  type 

♦Cresols-formaldehyde 

Cresols-xylenols-formaldehyde 

♦Cresylic  acid-formaldehyde 

Phenol-p-tert-butylphenol-formaldehyde 

•Phenol-cresols-formaldehyde 

♦Phenol-cresols-xylenols-formaldehyde 

♦Phenol-cresylic  acid-formaldehyde 

♦Phenol-formaldehyde 


♦Phenol -furfural 

♦Phenol-resorcinol-formaldehyde 

Phenol-xylenols-formaldehyde 

♦Phenylphenol-formaldehyde 

♦Resorclnol-formaldehyde 

Xylenols-p-tert-amylphenol-formaldehyde 

♦Xylenols-formaldehyde 

All  other 

♦Modified: 

♦Except  rosin  and  rosin  ester  modified: 

Cresols-formaldehyde-dibutyl  phthalate 

Cresylic  acid-formaldehyde-dibutyl  phthalate 

Phenol-formaldehyde ,  ammonia ted 

♦Phenol-formaldehyde-aniline 

Phenol-formaldehyde-dipentene 

Phenol-formaldehyde-glycerol-fatty  acid 

♦Phenol-f ormaldelyrde ,  oil  modified 

Phenol-formaldehyde-styrene 

Phenol-formaldehyde ,  sulfonated 

Phenylphenol-formaldehyde-tung  oil 

All  other 

♦Rosin  and  rosin  ester  modified: 

♦Biephenol-formaldehyde-rosin  and  rosin  ester^ 
p-tert-Butylphenol-formaldehyde-glycerol- 
pentaerythri tol-ros  in . 
♦p-tert-Butylphenol -formaldehyde-rosin  and 
rosin  ester. 

p-tert-Butylphenol-glycerol-rosin 

Cresols-formaldehyde-tung  oil-rosin 

Cresols-phenol-p-tert-butylphenol- 
formaldehyde-tung  oil-rosin. 

Cresylic  acid-formaldehyde-rosln  ester 

Phenol-formaldehyde-glyoerol-rosin  and  rosin 
ester. 

Phenol-formaldehyde-pentaerythritol-rosln 

♦Phenol-fomialdehyde-rosln  and  rosin  ester 

Xylenols -formaldehyde -tung  oil-rosin 

All  other 


ASl,  A95. 
13A,  3Z7,   536. 

131,  258. 

AA,   170,  186,  192,  333,  361,  395,  -453,  521,  5-W. 

95,  131,  170,  361,  409,  422,  568. 

295,  577. 

44,  395,  453,  487. 

134,  234,  247,  311,  322,  327,  333. 


487,  536. 

487. 

408,  453,  579. 

167,  175,  408,  409,  463,  487. 

120,  204,  245,  350,  408,  463,  487,  568. 

69,  207,  339,  449. 

120,  167,  408,  432,  449,  453,  487,  536,  568. 

69,  346,  408,  432. 

71,  167,  408,  4S7,  524. 

245,  487,  521. 

29,  118,  167,  188,  245,  272,  346,  432,  453,  487, 
536,  568. 

13,  97,  118,  120,  408,  432,  536. 

35,  408,  487,  524. 

8,  26,  29,  30,  32,  67,  69,  70,  71,  85,  118, 
124,  141,  167,  196,  207,  226,  245,  295,  304, 
316,  317,  339,  346,  350,  372,  387,  395,  408, 
432,  449,  453,  454,  463,  487,  490,  493,  524, 
536,  568. 

97,  167,  339,  449. 

29,  207,  323,  449,  487,  524,  533. 

35,  521. 

323,  408,  487,  568. 

245,  MB,   487,  493,  524,  568. 

408. 

26,  71,  118,  487,  536,  568. 

487. 


4S7, 

524. 

493. 

29,  167,  245,  346,  408,  487. 

408. 

490. 

207,  408,  487,  521,  524. 

207. 

295,  577. 

487,  544. 

97,  167,  295,  346,  409,  464,  487,  568. 

91,  204,  222,  272,  292,  463,  536. 
568, 

91,  120,  272,  463,  493,  532,  536,  568. 


521, 
487, 
487. 

493, 
292, 

154, 
222, 
437. 
463, 


536. 

568. 


524,  568. 
493,  536,  568. 


395,  463,  568. 
395,  463,  487,  568. 


487,  568. 


118 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  19B. --Synthetic  organic  chemiatls:    Plastics  and    resin'  materials   for  which  United  States  production  or 
sales  were  reported,    identified  by  manufacturer ,    J95J- -Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


PLASTICS  AND  RESIN  MATERIALS,  BENZENOID— Continued 

»Phthalic  alkyd  resins: 
^Unmodified: 

»Phthalic  anhydride-glyoerol 


»Phthalic  anhydride-glyoerol-glycol- 


Phthalio  anhydride-glyoerol-glyool-penta- 
erythr itol . 
»Phthalio  anhydride-glycerol-pentaerythritol- 


Phthalic  anhydride-glycerol-pentaerythritol- 
sorbitol. 
»Phtlialic  anhydride-glyoerol -sorbitol 

Phthalio  anhydride-glyool 

»Phthalic  anl^dride-glycol-pentaerythritol 

»Phthalic  anhydride-pentaerythritol 

All  other 

«Modified: 

»Exoept  rosin  and  rosin  ester  and  styrene 
modified: 

*Phthalic  anhydride-adipic  acid-glycol 

»Phthalio  anhydride-benzoio  aoid-glycerol 

»Phthalio  anhydride -fumaric  acid-glycerol 

Phthalle  anhydride-fumaric  acid-glyool- 

pentaerythr itol . 
Phthalio  anhydride-glycerol-pentaerythritol- 
phenol-f ormaldehyde . 
«Phthalic  anhydride-glycerol-phenol- 
f ormaldehyde . 
Phthalio  anhydrlde-glycol-phenol-f ormaldehyde- 
*Phthalio  anhydride-male io  anhydride-glyoerol- 

»Phthalio  anhydride-maleic  anhydride-glyoerol- 
pentaerythritol . 

Phthalio  anhydride-maleio  anhydride-glyoerol- 
phenol-f ormaldehyde . 

Phthalio  anhydride-maleio  anhydride-glycol- 
pentaerythritol . 
»Phthalio  anhydride-maleio  anhydride- 
pentaerythritol. 

Phthalic  anhydride-pentaerythritol  with 
various  modifiers. 

Phthalio  anhydride-sebaoio  acid-alcohol 

All  other 


»Rosin  and  rosin  ester  modified: 

Phthalic  anhydride-benzoio  aoid-fumario  acid- 
pentaerythritol-tall  oil. 
»Phthalio  anhydride-fumaric  acid-glycerol- 
rosin  and  rosin  ester. 
Phthalio  anhydride-fumaric  aoid-glycol- 

pentaerythritol-tall  oil-rosin. 
Phthalio  anhydride-glyoerol -glycol -rosin  and 
rosin  ester. 
•Phthalio  anhydride-glyoerol -pentaerythritol- 

phenol-formaldehyde-rosin  ester. 
•Phthalio  anhydride-glyoerol-pentaerythritol- 

rosin  and  rosin  ester. 
•Phthalic  anhydride-glycerol-phenol- 

formaldehyde-rosln  and  rosin  ester. 
•Phthalic  anhydrlde-glycerol-rosln  and  rosin 
ester. 


Phthalio  anhydride-glyoerol-tall  oil 

Phthalic  anhydride-glycol-pentaerythrltol- 

abitol  alcohol  and  tall  oil. 
•Phthalio  anhydride-maleio  anhydride-glyoerol- 

pentaerythritol-rosin  ester. 
Phthalio  anhydride-maleio  anhydride-glyoerol- 

phenol-formaldehyde-rosln  and  rosin  ester. 


4,  20,  A3,   44,  49,  57,  66,  79,  84,  91,  92,  95, 

103,  127,  131,  138,  148,  154,  167,  170,  175, 

178,  186,  192,  194,  239,  257,  261,  263,  272, 

297,  304,  333,  346,  361,  374,  391,  393,  395, 

422,  453,  463,  464,  487,  493,  521,  532,  536, 

544,  564,  579,  581. 

4,  34,  79,  91,  131,  148,  170,  193,  263,  346, 

391,  395,  409,  422,  453,  463,  521. 

175,  422,  453,  464. 

4,  20,  43,  44,  66,  79,  91,  92,  95,  120,  138, 

148,  170,  186,  194,  239,  257,  263,  297,  304, 

333,  346,  361,  391,  393,  395,  422,  453,  463, 

464,  490,  521,  532,  536,  544,  568,  581. 

297. 

20,  170,  297,  536,  568. 

395,  453. 

4,  44,  66,  84,  91,  96,  170,  186,  222,  263,  304, 

333,  346,  361,  395,  409,  422,  453,  463,  464,  493, 

503,  521,  532,  544. 
20,  43,  64,  66,  84,  91,  95,  96,  103,  127,  131,  154, 

170,  186,  194,  239,  257,  263,  304,  333,  346,  361, 

391,  393,  395,  409,  422,  453,  463,  464,  493,  521, 

532,  536,  544,  568,  579,  581. 
91,  333,  453,  544,  568. 


333  ^3  464. 

91,'l86,'346,  391,  422,  464,  544,  568. 
44,  192,  214,  333,  361,  391,  463. 
463,  464. 

148,  297,  568.  ' 

170,  186,  304,  333,  346,  395,  422,  464,  568,  581. 

521. 

25,  44,  49,  79,  186,  192,  212,  304,  333,  391,  395, 

409,  422,  453,  463,  521,  568,  581. 
25,  44,  79,  212,  214,  304,  346,  361,  395,  463,  521, 

544,  568. 
395,  409,  463. 

422,  463,  464. 

175,  212,  304,  333,  395,  422,  463,  521,  581. 

333,  361,  395,  490,  493,  521. 

91,  333,  453. 

13,  44,  79,  96,  175,  178,  212,  333,  346,  391,  422, 
453,  463,  464,  487,  493. 

44. 

361,  453,  544,  581. 

391. 

84,  346. 

44,  192,  257,  395,  409,  463. 

4,  43,  44,  66,  92,  127,  131,  148,  167,  186,  192, 

297,  391,  395,  422,  568,  579. 
44,  79,  138,  170,  263,  346,  391,  395,  453,  463, 

464,  521,  536,  568. 
20,  66,  91,  92,  103,  131,  170,  186,  193,  194,  239, 

263,  297,  333,  346,  391,  395,  422,  453,  463,  464, 

493,  521,  532,  536,  568. 
304. 
391,  422,  463,  521. 

297,  304,  395,  464,  521. 

304,  453,  463,  521. 


SYNTHETIC  ORGANIC  CHEMICALS,  I953 


119 


TABLE  19B. -Synthetic  ornenic  chewicals:    Plastics    and    resin  materials     for  which  United  States  product  ion 
sales  were    reported,  identified  by  manufacturer ,  J95J- -Continued 


PLASTICS  AND  RESIN  MATERIALS,  BENZENOID— Continued 

»Phthalic  alkyd  resins — Continued 
<<Modified — Continued 

»Rosin  and  rosin  ester  modified — Continued 

»Phthalio  anhydride-maleic  anhydride-glyoerol- 
rosin  and  rosin  ester. 
Phthalio  anhydride-maleic  anhydride-penta- 
erythritol-phenol-f ormaldehyde-rosin  ester . 
»Phthalio  anhydride-maleic  anhydride-penta- 

erythritol -rosin  ester. 
»Phthalic  anhydride-maleic  anhydride-penta- 
erythritol-tall  oil. 
Phthalio  anhydride-pentaerythritol-phenol- 
formaldehyde -rosin  and  rosin  ester. 
»Phthalic  anhydride-pentaerythritol-rosin  and 
rosin  ester. 

»Phthalic  anhydride-pentaerythritol-tall  oil 

All  other 

«Styrene  and  styrene  derivative  polymer  and 
copolymer  resins: 

Polymethyl  styrene 

«Polystyrene 

Styrene-aorylonitrile  copolymer 

»Styrene-allqfd  polyesters: 

Adipic  acid-fumaric  aoid-glyool-styrene 

Adipic  acid-glycol -styrene 

Maleic  anhydride-adipic  acid-glycol-styrene 

Maleic  anhydride-glycerol-styrene 

Maleic  anhydride-glyool-styrene 

Maleic  anhydride-styrene 

Phthalic  anhydride-fumaric  acid-glycol-penta- 

erythritol-styrene . 
Phthalio  anhydride-fumaric  acid-glycol-styrene— 
»Phthalio  anhydride-glycerol-pentaerythrltol- 
styrene . 

wPhthalic  anhydride-glycerol-styrene 

Phthalic  anhydride-maleic  anhydride-adipio  acid- 
glycol-styrene  . 
»Phthalic  anhydride-maleic  anhydride-glyool- 
styrene. 
Phthalic  anhydride-maleic  anhydride-penta- 
erythritol-styrene . 

All  other 

■»StyTene-butadiene   copolymer- 


Manuf acturers '  identification  numbers 
(according  to  list  in  table  27) 


»Styrene-divinylbenzene  copolymer 

All  other 

Toluenesulfonamide  resins 

All  other  benzenoid  plastics  and  resin  materials 

PLASTICS  AND  RESIN  MATERIALS,  NONBENZENOID 

Acetone-formaldehyde  resins 

Acrylic  resins 

»Alkyd  resins  (except  phthalic): 
»Unmodif ied : 

Adipic  aoid-glyoerol 

Adipic  acid-glyoerol-glycol 

Adipic  aoid-glyool 

Cyolopentadiene-glycerol 

Fumaric  aoid-glyool — 

Fumaric  aoid-pentaerythritol 

»Male  ic  anhydride-glyoerol 

Maleic  anhydride-glycol 

Maleic  anhydride-pentaerythritol 

Sebaoic  acid -glycerol 

Sebacic  acid-glycol 

All  other 

itModified: 

Fumaric  aoid-glyoerol-pentaerythritol-tall  oil— 

»Fumaric  aoid-glyoerol-rosin  and  rosin  ester 

Fumaric  acid-glyool-rosin  and  rosin  ester 

»Fujiiario  aoid-pentaerythritol-rosin  and  rosin 

ester. 
■••Maleic  anhydride-glyoerol -pentaerythritol-rosin 
and  rosin  ester. 
Maleic  anhydride-glycerol-pentaerythritol- 

sorbitol-rosin. 
••Maleic  anhydride-glycerol-rosin  and  rosin  ester- 


Maleic  anhydride-glyool-pentaerythritol-rosin 


iA,   79,  \^,   192,  30-;,  391,  395,  399,  422,  <i53,  521, 

536,  544. 
212. 

25,  175,  212,  263,  346,  391,  422,  463,  521. 

96,  175,  186,  263,  391,  395,  409,  463,  536. 

395,  568. 

4,  66,  91,  103,  138,  170,  175,  186,  222,  239,  261, 

361,  391,  393,  395,  463,  521,  568. 
92,  154,  175,  391,  395,  463,  521,  532,  581. 
20,  44,  91,  192,  297,  333,  422,  493,  544. 


437, 
158, 
378, 

137, 
493. 
464, 
378. 
346, 
245, 
167, 

137, 
131, 


448. 

245,  323,  448,  487,  524. 

487. 

464. 

493. 

493. 

437,  524,  535. 

395. 

346,  464. 

186,  304,  391,  453. 


91,  131,  333,  391,  395,  453,  464,  521,  568. 
295. 

167,  391,  395,  418,  422,  453,  464,  487,  493,  536. 


395,  422,  464,  487,  493. 

Ill,  243,  323,  378,  396,  437,  44S,  431,  496,  563. 

295,  448,  463,  493,  577. 

134,  245,  333,  422,  453,  487,  493,  545,  568,  577,  X. 

245,  464. 

487,  536,  550. 


464,  487,  568. 

41,  333,  374,  437,  453,  464,  493,  545. 


148,  493. 

422,  463. 

148,  346,  422,  464,  493. 

391. 

417,  464. 

297,  361. 

96,  103,  346,  521,  566. 

346,  464. 

297,  304,  395,  521. 

44,  170,  186,  395,  493,  568. 

463,  464,  493. 

137,  167,  297,  346,  417,  464,  521. 

304,  521. 

192,  346,  391,  463,  464,  493,  521,  568,  581. 

532,  581. 

25,  91,  361,  463,  493,  521,  544. 

120,  170,  297,  393,  422,  463,  493,  532. 

170. 

20,  49,  66,  84,  91,  106,  131,  154,  170,  192,  193, 
204,  222,  272,  292,  391,  395,  453,  463,  464,  490, 
493,  521,  532,  536,  568. 

346. 


120 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  19B.  -Synthetic  organic  chemicals:    Plastics  and  resin  materials    for    which  United  States  product i 
sales  were  reported,    identified  by  manufacturer ,    J953- -Continued 


PLASTICS  AND  RESIN  MATERIALS,  NONBENZENOID—Contlnued 

»All£yd  resins  (except  phthalic) — Continued 
•Modified — Continued 

»Maleic  anhydride-glyool-rosin  and  rosin  ester 

Maleic  anhydride-pentaerythritol-phenol- 
formaldehyde-rosin  ester. 
«Maleio  anhydride-pentaerythritol-rosin  and  rosin 
ester. 

Maleic  anhydride-pentaerythritol-sorbitol-rostn- 
«Maleic  anhydride-pentaerythrltol-tall  oil 


All  other 

Butadlene-acrylonitrile  copolymer  resins- 

Furfuryl  resins 

Polyamide  (Nylon)  resins 

Polyohloro-  and  polyfluorethylene  resins- 
Polyethylene  resins 

Polyterpene  type  resins 

»Rosin  and  terpene  adduct  resins: 

»Fuinaric  acid-rosin 

«Maleic  anhydride-ros  in 

All  other 

»Rosin  esters,  unmodified: 

»Rosin-glycerol 


»Rosln-glyoerol-pentaerythritol- 

Rosin-glycol 

■wRosin-pentaerythritol 


Tall  oil-glyoerol 

Tall  oil-methanol 

Tall  oil-pentaerythritol 

All  other 

•Silicone  resins 

■•Hlrea  and  melamine  resins: 
»Urea-formaldehyde  type: 

»Butylurea-foriiialdehyde 

Isotutylurea-formaldehyde- 
»Urea-foniialdehyde 


All  other 

•Melamine-formaldehyde  type: 

Butylmelamine-formaldehyde 

Butylmelamine-urea-fornialdehyde- 

Melamine -formaldehyde 

Melamine-urea-formaldehyde 

All  other 

*Vinyl  and  vinyl  copolymer  resins: 
•Polyvinyl  acetate 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


Polyvinyl  alcohol 

Polyvinyl  butyral 

•Polyvinyl  chloride  and  copolymers: 

•Polyvinyl  chloride : 

Polyvinyl  ohloride-vinylidene  chloride 

All  other 

All  other  vinyl  and  vinyl  copolymer  resins 

All  other  nonbenzenoid  plastics  and  resin  materials- 


222,  "iOg,  -463,  521. 
257. 

&4,  66,  79,  92,  106,  127,  192,  2(X,  222,  239,  297, 
304,  391,  395,  409,  422,  463,  503,  521,  536,  568, 
579. 

91. 

91,  93,  95,  192,  212,  257,  263,  395,  422,  521,  544, 
568. 

79,  96,  175,  192,  297,  391,  395,  422,  463,  464,  487. 

350,  378,  437. 

339,  524. 

228,  333. 

243,  333. 

333,  392,  605. 

134. 

106,  192,  204,  463,  464,  493,  521,  568,  581. 
391,  422,  453,  464,  490,  521,  568. 
103,  222,  387. 

91,  103,  106,  154,  175,  192,  222,  292,  361,  391, 
395,  453,  463,  490,  532,  536,  568,  579, 

106,  222,  304,  463,  568. 

222,  422,  463. 

20,  25,  93,  95,  106,  170,  222,  239,  361,  395,  463, 
521,  532,  536,  568. 

91,  395,  536. 

96,  222,  422. 

84,  175,  395,  521,  532,  544,  568,  581. 

222,  487,  544,  568. 

315,  334,  346,  387,  487,  536. 


91,  245,  333,  391,  464,  493,  536. 

333,  464,  536. 

82,  91,  131,  178,  196,  207,  222,  245,  310,  333,  374, 

395,  407,  428,  449,  453,  464,  487,  493,  524,  533, 

535,  536,  566,  568,  575,  596. 
30,  333,  463,  464,  493,  535,  536,  566. 

245,  333,  464,  493,  536. 

188,  245,  493. 

245,  346,  464,  524,  536. 

464,  524. 

464,  493. 

178,  184,  249,  296,  333,  374,  392,  437,  449,  493, 

496,  532,  568. 
249,  296,  333. 
249,  333,  392. 

242,  243,  245,  354,  378,  448,  563. 

243,  448,  563. 
243,  392. 
249,  333,  563. 

243,  333,  391,  429, .464,  487,  536,  550,  563,  575, 
577. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 
Rubber- Processing  Chemicals 


121 


TABLE  21B. -Synthetic  organic  chemicals:   Rubber-processing  chemicals   for  which  United  States  production 
or   sales  were  reported,    identified  by  manufacturer ,    1953 

[Rubber-processing  chemicals  for  which  separate  statistics  are  given  in  table  21A  are  marked  below  with  an 
asterisk  (») ;  chemicals  not  so  marked  do  not  appear  in  tab].e  21A  because  the  reported  data  are  confiden- 
tial and  may  not  be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from  table  27[ 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


RUBBER-PROCESSING  CHEMECAIS,  CYCLIC 


»Accelerators : 

Aldehyde-amines: 

Acetaldehyde-aniline 

»Butyraldehyde-ani line- 


-Ethyl-yS-propylacrylanilide- 


Formaldehyde-aniline  (Methyleneaniline) - 
Formaldehyde-p-toluidine  (Methylene-p- 

toluidine) , 
Heptaldehyde-aniline- 


Triethyltrlraethylenetriamine- 
Dithiocarbamic  acid  derivatives: 

Carbon  disulf ide-methylenedipiperidine 

Dibenzyldithiocarbajnic  acid,  zinc  salt — 

Dibutyldithiocarbamic  acid,  diphenylguanidine 

salt. 
Dimethylethylene  diphenyldithlocarbamic  acid, 

lead  salt. 

2 ,4-Dinitrophenyl  dimethyldithiocarbamate 

Piperidinium  pentamethylenedithiooarbamate 

Piperidinium  pentamethylenedithiocarbamio  acid, 

potassium  salt. 
»Cuaiiidines : 

Dioatechol  borate,  di-o-tolylguanidine  salt 

Diphenylguanidine- 


Diphenylguanidlne  phthalate 

Di-o-tolylguanidine 

Triphenylguanidine 

»Thiazole  derivatives: 

2-Benzothiazyl-N,N-diethylthiocarbamyl  sulf ide- 

Bis[N,N'-2(2-benzothiazylthiomethyl)urea] 

N-Cyclohexyl-2-benzothlazolesulfenamide- 


2-(2  ',<V'-Dinitrophenylthlo)benzothiazole 

»2,2  '-Dithiobis [benzothiazole]    (2,2 '-Benzo- 

thiazyl  disulfide) , 
«2-Mercaptobenzothiazole- 


2-Meroaptobenzothiazole,   sodium  salt-— 

2-Meroaptobenzothiazole,   zinc  salt 

2-Mercaptobenzothiazole  phenylblguanide- 
2-Meroaptobenzothiazollne- 


N-0xydi9thylene-2-benzothiazolesulfenamide- 
Miscellaneous  compounds: 
Dibenzylamine- 


Di-N-pentamethylenethiurani  tetrasulfide- 

2-Imidazoline-2-thlol 

Poly-p-dinltrosobenzene         — — 

p-Quinonedioxime- 


p-Quinonedioxime  dibenzoate — — 

•Antioxidants: 

Aldehyde-  anl  acetone-amines: 

Acetaldehyde-aniline  hydrochloride- 
p-Aminodiphenyl-acetone- 


Aniline-acetone,  acid  derivatlves- 

Diphenylamine-aeetone 

p-Phenetidine-acetone- 


Phenyl-2-naphthylamlne-aoetone- 
»Amino  or  hydroxy  compounds: 
p,p '-Diamincphenylmethane- 


2,  5-Di-tert-amylhydroquinone 

2 , 5-Dl-tert-butylhydr oquinone ____ _ 

p,p'-Dimethoxydiphenylamlne 

N,N  -Di-2-naphthol-p-phenylenediamine 

N,N  -Diphenylethylenediamine— 

N,N  '-Diphenyl-p-phenylenediamine 

N,N  '-Diphenylpropylenediajnine 

Di-o-tolylethylenediamlne 

Hydroquinone  monobenzyl  ether- 

p-Hydroxydiphenylamine 

p-Iaopropoxydiphenylamine- 


p,p  '-iBqprqpylidenediphenol  (^ -Di-p-hydroxy- 

phenylpropane) . 
Ootyldlphenylamlne- 


Octyldiphenylamine,  alkylated- 

N-Phenyl-1-naphthylamine 

N-Phenyl-2-naphthylamlne- 


-Tetramethyl  diphenylethylenediamine- 


378,    563. 

245,    333, 

378. 

56. 

333. 

333. 

378. 

378. 

2«. 

378. 

56. 

56. 

378. 

245. 

333. 

333. 

245,   464. 

245. 

333,   464. 

527. 

580. 

245. 

245. 

245. 

245,  378, 

396,   464. 

245,   378, 

396,   464,    580 

245,   396, 

464. 

396,   464. 

464. 

464. 

396,   464. 

378. 

333. 

333. 

333. 

333. 

378. 

245,  378. 

245. 

245. 

378. 

245. 

378, 

378. 

245. 

245. 

333. 

563. 

56,   429. 

245,   333, 

378,    563. 

56. 

56. 

563. 

333,    563. 

563. 

396. 

37S. 

563. 

333,    527. 

333,    563. 

429. 

313486  O  -  54 


122 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  21R.- -Synthetic  organic  chemicals:   Rubber-processing  chemicals   for  irfiic/i  United  States  production 
or  sales  were  reported ,    identified  by  manufacturer ,    J95J--Continued 


Manufacturers'   identification  numbers 
(according  to  list  in  table  27) 


RUBBER-PROCESSING  CHEMICALS,   CYCLIC — Continued 

^Antioxidants — Continued 

*Aiiiino  or  hydroxy  compounds— Continued 
Thiobis [di-sec-amylphenol] - 


A,  A  -Thiobis  [6-tert-butyl-m-cresol] 

p-(p-Toluenesulfonamido)diphenylaii!lne- 

N-o-Tolyl-2-naphthylamine 

Miscellaneous  compounds: 

Aldo-o-naphthylamine  condensation 

Dicresyl  disulfide- 


2,2  '-Methylenebis['i-methyl-6-tert-butylphenol]  - 

Nonylphenyl  dioctylphenyl  phosphite— — — 

Phenol,   alkylated- 


Phenol,   styrenated- 

2,2, 4~Tr imethyldihydr oquinoline 

Inhibitors :   N-Nitrosodiphenylamine 

Peptizers: 

0,0 '-Dibenzamidophenyl  disulf ide- 


Phenylhydrazine  zinc  chloride  salt- 
2-Naphthyl  meroaptan- 


Xylyl  mercaptide,  zinc  salt- 
All  other 

Tackifiers: 


p-tert-Amylphenol  sulfide 

Bis[ iso-octylhydroxyphenylmethylene] 

RUBBER-PROCESSING  CHEMICALS,  ACYCLIC 

»Accelerators: 

*Dithiooarbamic  acid  derivatives: 

Dibutyldithiocarbamic  acid,  dimethylcyclohexyl- 

amine  salt. 

Dibutyldithiocarbamic  acid,  nickel  salt 

Dibutyldithiocarbamic  acid,  sodium  salt— — — 

^Dibutyldithiocarbamic  acid,  zinc  salt- 


Diethyldithiocarbamic  acid,  diethyls mmonium 
salt, 

Diethyldithiocarbamic  acid,  selenium  salt 

Diethyldithiocarbamio  acid,  sodium  salt 
Diethyldithiocarbamic  acid,  tellurium  salt 

»Diethyldithiocarbamlc  acid,  zinc  salt 

Dimethyldithiocarbamic  acid,  bismate  salt' 

Dimethyldithiocarbamlo  acid,  copper  salt 

Dimethyldithiocarbamic  acid,  dimethylammonium 

salt. 
Dimethyldithiocarbamic  acid,  lead  salt 

»Dimethyldithiocarbamlc  acid,  potassium  salt 

Dimethyldithiocarbamlo  acid,  selenium  salt 

All  other 

Thiurams : 

Methylethylthluram  disulfides,  mixed 

Tetrabutylthiuram  monosulf ide 

Tetraethylthiuram  disulfide 

»Tetramethylthi>iram  disulfide- 


•»Tetramethylthiuram  monosulf  ide— 
Tetramethylthiuram  tetrasulf ide- 
Xanthates : 

Di-n-butylxantho  disulfide 

Diisopropylxantho  disulfide 

Potassium  butyl  xanthate— — — — 
Zinc  dibutyl  xanthate- 


Miscellaneous  compounds: 

n-Butyraldehyde-butylamine- 
Di-n-butylammonium  oleate— ■ 
^Peptizers:. 

Alkyl  mercaptans,  mixed- 


Cadmium  lauryl  mercaptlde- 

»Dodecyl  mercaptans— 

tert-Hexadecyl  mercaptan— 

Zinc  laurate 

All  other 


245. 
245. 
378. 
396. 

563. 

378. 

464. 

378. 

56,  396. 

563. 

563. 

563. 

464. 
333. 
333. 
333. 
333. 

580. 
348. 


245. 


333. 

333,  364,  378. 

245,  254,  364,  378,  396,  580. 

580. 

254,  580. 

378,  498. 

254. 

245,  254,  364,  378,  396,  580. 

254. 

254,  447. 

378. 

254. 

137,  378,  396,  580. 

254. 

378,  396. 

580. 

378. 

378,  396,  580. 

245,  333,  378,  396,  563,  580, 

245,  333,  378,  396. 

333. 

378. 
563. 
378. 
378,  396. 

333. 
137,  333. 

443. 

243; 

146,  338,  443,  580. 

443. 

378. 

333. 


SYNTHETIC  ORGANIC  CHEMICALS,  I953 
Elastomers  (Synthetic  Rubbers) 


123 


TABLE  223. -Synthetic   organic  chemicals:    Elastomers  (synthetic  rubbers)    for  which  United  States  production 
or  sales  were  reported ,    identified  by  manufacturer ,    1953 

[Elastomers  (synthetic  rubbers)  for  which  separate  statistics  are  given  in  table  22A  are  marked  below  with 
an  asterisk  (»);  products  not  so  marked  do  not  appear  in  table  22A  because  the  reported  data  are  confi- 
dential and  may  not  be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from  table 
27.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number 
with  the  designated  product] 


Manufacturers'  Identification  numbers 
(according  to  list  i^  table  27) 


ELASTOMERS,  CYCLIC 

»Polybutadiene-styrene  type  (Buna  S,  GR-S)  — 

ELASTOMERS,  ACYCLIC 

Polyacrylate  ester  type 

Polyalkalene  sulfide  type  (Thiokol) 

»Polybutadiene-aorylonitrile  type  (N-type)~ 

Polybutadiene  type 

Polybutadiene-styrene-vinylpyridine  type 

Polybutadiene-vinylpyridine  type 

•Polychloroprene  type  (Neoprene,  GR-M) 

Polyisobutylene  type 

•Polyisobutylene-isoprene  type  (Butyl,  GR-I) 

•Polyvinyl  type 

Reaction  products  of  natural  rubber: 

Cyclorubbers ■ 

Polymerized  chlorinated  rubber  (Parlon) — 
Silicone  type 


105,  125,  W6,  243,  273,  396,  AA3,   459,  601,  602. 


350,  378,  396,  563. 


481. 
392,  563. 


396. 
222. 
315,  346. 


Plasticizers 


TABLE  23B. -Synthetic  organic  chemicals:    Plasticizers   for   which  United  States  production   or  sales 
were  reported,    identified  by  manufacturer,    1953 

.Plasticizers  for  which  separate  statistics  are  given  in  table  23A  are  marked  below  with  an  asterisk  (»); 
products  not  so  marked  do  not  appear  in  table  23A  because  the  reported  data  are  confidential  and  may  not 
be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from  table  27.  An  X  signifies 
that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number  with  the  designated 
product ] 


Chemical 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


PLASTICIZERS,  CYCLIC 


Camphor,  synthetic 

Coumarone-indene  plasticlzer 

N-Cyclohexyl-p-toluenesulfonamide 

Dibenzyl  sebaoate 

Di-tert-octyldiphenyl  oxide 

Diphenyl  cyclohexyl,  o-,  m-,  p-  

Dipropylene  glycol  dibenzoate 

Ethyl  oxanilate 

N-Ethyl-p-toluenesulfonamide 

Isopropylidenediphenoxypropanol 

Naphthalene ,  alkylated 

Phenoxyethyl  compounds 

Phosphoric  acid  esters: 

Cresyl  diphenyl  phosphate 

Dibutylphenyl  phosphate 

Diphenyl  mono-o-xenyl  phosphate 

Diphenyl  octyl  phosphate 

Tri(p-tert-butylphenyl)  phosphate 

•Tricresyl  phosphate ~ 

•Triphenyl  phosphate 

Polyoxyalkalene  phenol 

•Phthalic  anhydride  esters: 
Butyl  benzyl  phthalate- 


Butyl  cyclohexyl  phthalate 

Butyl  decyl  phthalate 

Butyl  phthalyl  butyl  glyoolate 

Castor  oil  phthalate,  hydrogenated 

Diallyl  phthalate 

Diamyl  phthalate 

Di(2-butoxyethyl)  phthalate  (Di(butyl  cellosolve) 
phthalate ) . 


333. 

327. 

245. 

86. 

4^8. 

245. 

331. 

504. 

245. 

448. 

234. 

417. 

245. 

245. 

448. 

245. 

448. 

128,  245,  418,  574. 

245,  418,  498,  536. 

417. 

245. 

536. 

456. 

245. 

333. 

128,  258. 

463. 

128,  333,  370. 


124 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  23b. --Synthetic   organic  chemicals:    Plasticizers   for  which  United  States  production   or  sales 
were   reported,    identified  hy  manufacturer,    1953- -Continued 


PLASTICIZERS,  CYCLIC— Continued 

»Phthalio  anhydride  esters — Continued 

•Dibutyl  phthalate 

♦Dicapryl  phthalate 

Dicyolohexyl  phthalate 

Dideoyl  phthalate 

Di(2-(2-ethoxyethoxy)ethyl)  phthalate  (Dioarbltol 

phthalate) . 
Di(2-ethoxyethyl)  phthalate  (Dioellosolve 
phthalate) . 

Di(2-ethylbutyl)  phthalate 

•Diethyl  phthalate- 

Dihexyl  phthalate 

Diisobutyl  phthalate 

Di  isodecyl  phthalate 

*Di(2-methoxyethyl)  phthalate  (Di{methyl  oello- 
solve )  phthalate ) . 

•Dimethyl  phthalate 

Dinonyl  phthalate 

Dioctyl  oapryl  phthalate 

•Diootyl  phthalates: 

*Di(2-ethylhexyl)  phthalate 

•Di-n-ootyl  phthalate,  diiso-ootyl  phthalate, 
and  mixtures. 

Diphenyl  phthalate 

Ethyl  phthalyl  ethyl  glyoolate 

Isobutyl  castor  oil  phthalate 

Iso-octyl  oapryl  phthalate 

Methyl  phthalyl  ethyl  glycolate 

•Octyl  decyl  phthalate 

Tetrahydrofurfuryl  oleate 

Toluenesulfonamide,  o-,  p-  mixture 

All  other 

PLASTICIZERS,  ACYCLIC 

*Adipio  acid  esters: 

Di(2-(2-butoxyethoxy)ethyl)  adipate  (Di(butyl 

carbltol)  adipate). 
Di(2-butoxyethyl)  adipate  (Di(butyl  cellosolve) 
adipate ) . 

Dioapryl  adipate 

Didecyl  adipate 

«Di(2-ethylhexyl)  adipate 

Di-n-hexyl  adipate 

Diisoamyl  adipate 

Diisobutyl  adipate 

•Diiso-octyl  adipate 

Dinonyl  adipate 

Dipropyl  adipate 

n-Ootyl  decyl  adipate 

All  other 

Azelaic  acid  esters; 

Di-n-butyl  azelate 

Di(2-ethylbutyl)  azelate 

Di(2-ethylhexyl)  azelate 

Diisobutyl  azelate 

All  other 

2-(2-Butoxyethoxy)ethyl  pelargonate 

2-Butoxyethyl  diglyool  carbonate 

Butyl  myristate 

Castor  oil  maleate 

Citric  and  acetylcitric  acid  esters: 

Tributyl  acetyloitrate 

Tri-n-butyl  citrate 

Triisobutyl  citrate 

Di(butoxyethoxy-ethoxy )  methane 

Dibutyl  tartrate 

Dicapryl  diglycolate 

Diethylene  glycol  dipelargonate 

Diethylene  glycol  ester  of  coconut  oil  fatty  acid 

Diethyl  maleate 

Glyceryl  dlacetyl  tartrate  monoesters 

Glyceryl  tributyrate  (Tributyrin) 

Glyceryl  tripropionate 

Isopropyl  myristate 

•Laurie  acid  esters: 

2-Butoxyethyl  laurate  (Butyl  cellosolve  laurate) — 
Butyl  laurate 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


-10,  36,  128,  2'i5,  JU,  333,  367,  ^22,  -456,  i.fi,   A&i, 

-Vgfe,  536,  57-1. 
86,  128,  -i56,  493,  516,  536. 
128,  333,  536. 
«0,  530. 
128. 


128. 


483. 

222,  245,  266,  463,  483,  536. 

86,  485. 

483. 

245. 

128,  333,  370,  483. 

245,  266,  333,  463,  483. 
450,  456. 
456,  530. 

40,  86,  128,  314,  333,  392,  450,  456,  483,  496,  530, 

536. 
40,  86,  128,  222,  245,  422,  450,  456,  496,  516,  530, 

536,  563. 
245,  516. 
245. 
333. 

422,  450,  456,  516. 
245. 

40,  128,  222,  245,  422,  450. 
499. 
245. 
128,  580. 


128,  333. 


450,  516,  530. 

128,  370,  392,  450,  456,  483,  530. 

86. 

493. 

128,  450,  483,  530. 

40,  86,  128,  370,  450,  456,  493,  516,  530. 

456. 

370. 

128,  222,  450. 

563. 

370,  483. 

499. 

499. 

262,  483,  X. 

530,  X. 

262. 

391. 

365,  370. 

493. 

415,  463. 
415,  463. 
483. 
412. 

314,  370. 
128. 
499. 
123,  X. 
483. 
541. 

483,  511. 
483. 
255,  365. 

262,  370. 
370. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 

TAHLE  23fi. -Synthetic   organic   chemicals:    Plasticizers    for    which   Un.tejl  States  production   or   sales 
were  reported,    identified  by  manufacturer,    1953-    rontimied 


12 


PLASTICIZERS,  ACYCLIC— Continued 

»Laurio  acid  esters — Continued 

Glyceryl  raonolaurate 

Methyl  laurate 

»01eic  acid  esters: 

2-Butoxyethyl  oleate  (Butyl  cellosolve  oleate) 

»Butyl  oleate 

Dimethylamine  oleate 

•Glyceryl  trioleate 

Methyl  oleate 

n-Propyl  oleate 

Triethanolamine  oleate 

All  other 

Palmitic  acid  esters: 

Isohutyl  palmitate 

Methoxyethyl  palmitate 

Octyl  palmitate 

•Phosphoric  acid  esters: 

Tri(2-butoxyethyl)  phosphate  (Tri(hutyl  cello- 
solve  )  phosphate ) . 

Tributyl  phosphate 

Triethyl  phosphate 

Triisobutyl  phosphate 

Trioctyl  phosphate 

Polyethylene  glycol  di-2-ethylhexoate - 

Polyethylene  glycol  ester  of  soybean  oil  fatty  acid- 
•Ricinoleio  and  acetylrioinoleic  acid  esters: 

n-Butyl  aoetylrioinoleate 

Butyl  ricinoleate 

Cyclohexyl  ricinoleate 

Diethylene  glycol  monoricinoleate 

Glyceryl  monoricinoleate 

Glyceryl  triaoetylricinoleaie 

2-Methoxyethyl  aoetylricinoleate  (Methyl  cello- 
solve  aoetylrioinoleate). 

Methyl  aoetylricinoleate 

Methyl  ricinoleate 

Propylene  glycol  monoricinoleate 

All  other 

»Sebacic  acid  esters: 

Diamyl  sebacate 

Di(2-butoxyethyl)  sebacate  (Di(butyl  cellosolve) 
sebacate) . 

•Dibutyl  sebacate 

Dicapryl  sebacate 

*Di( 2-ethylhexyl )  sebacate 

Diiso-octy  1  sebacate '- 

Dimethyl  sebacate ■■ 

Dlnonyl  sebacate 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


Polyethylene  glycol  2-ethylhexyl  sebacate 

All  other 

•Stearic  acid  esters: 

2-Butoxyethyl  stearate  (Butyl  cellosolve  stearate) 

Butyl  epoxystearate 

•Butyl  stearate 

Diethylene  glycol  distearate 

Dimethylammoniujn  stearate 

2-Ethylbutyl  stearate 

2-Ethylhexyl  stearate 

Ethyl  stearate 

Glyceryl  monohydroxy stearate 

2-Methoxyethyl  stearate  (Methyl  cellosolve 
stearate). 

Methyl  dichlorostearic  acid 

Methyl  pentachlorostearate 

Methyl  stearate 

Polyglyoeryl  stearate 

All  other 

Triethylene  glycol  di(caprylate-oaprate) 

Triethylene  glycol  di-2-ethylbutyrate 

Triethylene  glycol  di-2-ethylhexoate 

All  other 


183,   262,   370. 

108,   370. 

262,   370. 

128,    262,    3W, 

365, 

370, 

374,   421 

<V93. 

123,    «)3,   -438, 

499. 

183,    365,    370, 

421, 

499. 

"^03,   -199. 

493. 

128,   493. 

483. 

483. 

40. 

128. 

128,   367. 

483. 

483. 

392. 

392. 

374,   450. 

219. 

219,   450. 

450. 

183,    262,    370 

123,    183,    219, 

262 

370 

421. 

219. 

219,   450. 

219. 

219,   421. 

219,    370. 

370,   450. 

493. 

450. 

8S,    262,   450, 

456, 

483. 

493. 

86. 

86,   450,   456, 

493, 

516. 

40,   86,   493. 

86,   494. 

450. 

516. 

86. 

128,   370. 

128. 

86,   128,   314, 

365, 

367, 

370,   403, 

370,    374. 

493. 

450. 

128. 

370. 

421. 

262,    370. 

338. 

338. 

370. 

541. 

370. 

40,   108,    438. 

392. 

392. 

262,    392,    493 

,   X. 

126 


UNITED  STATES  TARIFF  COMMISSION 
Surface-Active  Agents 


TABLE  24B. -Synthetic   organic  chemicals:    Surface- active  agents   for  which  United  States  production  or   sales 
were  reported,    identified  by  manufacturer ,    1953 

[  Surface-active  agents  for  which  separate  statistics  are  given  in  table  24A  are  marked  below  with  an  aster- 
isk (*);  products  not  so  marked  do  not  appear  in  table  2^k  because  the  reported  data  are  confidential  and 
may  not  be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from  table  27.  An  X 
signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number  with  the 
designated  product] 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


SURFACE-ACTIVE  AGENTS,  CYCLIC 

*Esters  and  ethers,  nonsulfonated: 

Anhydrohexitol  castor  oil  polyoxyalkylene  ether 

Anhydrohexitol  dilaurate 

Anhydrohexitol  dilaurate  polyoxyalkylene  ether 

Anhydrohexitol  dioleate 


Anhydrohexitol  glycerol  monolaurate 

Anhydrohexitol  monolaurate 

Anhydrohexitol  monolaurate  polyoxyalkylene  ether 

Anhydrohexitol  mono-oleate 

Anhydrohexitol  mono-oleate  polyoxyalkylene  ether 

Anhydrohexitol  monopalmitate 

Anhydrohexitol  monopalmitate  polyoxyalkylene  ether- 

Anhydrohexitol  monostearate 

Anhydrohexitol  monostearate  polyoxyalkylene  ether — 

Anhydrohexitol  tall  oil  ester 

Anhydrohexitol  tall  oil  polyoxyalkylene  ether 

Anhydrohexitol  tetrastearate 

Anhydrohexitol  trioleate 

Anhydrohexitol  trioleate  polyoxyalkylene  ether 

Anhydrohexitol  tririoinoleate 

Anhydrohexitol  triricinoleate  polyoxyalkylene  ether 

Anhydrohexitol  tristearate . 

Anhydrohexitol  tristearate  polyoxyalkylene  ether 

Anhydrosorbitol  monostearate  polyoxyaUqrlene  ether- 

Diisobutylphenoxy  polyethoxy  ethanol 

Dlpropylene  glycol  salicylate 

Glucose  polyoxyalkylene  dlstearate- 


Glucose  polyoxyalkylene  ether  polyoxyalkylene 

oleate . 

Glucose  polyoxyalkylene  oleate 

Iso-ootylphenoxy  polyethoxyethanol 

Nonylphenoxy  polyethoxyethanol 

n-Octylphenoxy  polyethoxyethanol 

Tetradecylphenoxy  polyethoxyethanol 

*Nitrogen-oontaining  surface-active  agents, 

nonsulfonated: 

N-Alkylethylmorpholiniujn  ethosulfates— — 

Benzylcetyldimethylammonium  chloride 

Benzyldimethylootylaramonlum  chloride — — 

Benzyldlmethylphenylammonium  chloride 

l-(l-Benzyl-l-hydroxyethyl )-2-tridecyl  Imldazo- 

linium  chloride. 

»Benzyllauryldimethylammonlujn  chloride 

Benzylpolyethoxy  coconut  oil  ammonium  chloride 

Benzylpolyethoxy  tall  oil  ammonium  chloride 

Benzyltrimethylammonium  chloride 

Benzyltrimethylammonium  hydroxide 

Caprylethyl-5-hydroxycycloimldine-sodium  ethylate , 

sodium  ethionate. 

Cetylpyridlnium  chloride 

3, 4-Dichlorobenzyllauryldimethylammonium  chloride — 
1, l-Dihydroxyethyl-2-heptadecenyl  imidazollnlum 

chloride . 

Dodecylmethylbenzyltrimethylammonium  chloride 

Ethanol  diphenyl  ethylenediamine 

Ethoxybenzyldimethyloctylphenoxyammonium  chloride — 

2-Heptadecyl-l-hydroxyethyl-2-imidazoline 

2-LauroyloxyethylcarbamylmethylpyTidinium  chloride 

(Lauryl  ester  of  colamlnoforraylmethylpyridlnium 

chloride ) . 

Lauryldimethylbenzyldimethylammonium  chloride 

Laurylethyl-5-hydroxycycloimidine,  sodium  ethylate, 

sodium  ethionate. 

Laurylpyridinium  chloride 

Oleyl  Imidazoline — 

Oxazoline,  substituted- 


Rosln  aminopolyethoxyethanol 

Rosin  soap  of  polyamidoimidazoline 

Stearoyloxyethylcarbamylmethylpyrldlnlum  chloride- 
Stearoylethyl-5-hydroxycyoloimldine ,  sodium 
ethylate,  sodium  ethionate. 


a.1. 

All. 

<H7. 

AY!. 

417. 

417. 

417. 

342,  417. 

417. 

417. 

417. 

417. 

417. 

417. 

417, 

417. 

417. 

417. 

417. 

417. 

417. 

417. 

140. 

550. 

X. 

417. 

550. 

417. 

421,  493,  550, 

15,  222,  321,  417,  438,  550. 

392. 

303, 


417, 

374,  379,  493,  591, 

374. 

550. 

342, 

374,  376,  479,  557,  591. 

550. 

550. 

367,  493. 

591, 

351. 

431,  591. 

374,  379,  557,  591. 

342. 

493,  591. 

58. 

493, 

342, 

541, 


591, 
351, 

338,  591, 

566,  573, 

367. 

550. 

496. 

541. 

351. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953  127 

-Synthetic  organic  chemicals:   Surface-active  agents   for  which  United  States  product  ion   or   sales 
were  reported,    identified  ^y  manufacturer ,   195J- -Continued 


Maraif acturers '   identification  mimbers 
(according  to  list  in  table  27) 


SURFACE-ACTIVE  AGENTS,   CYCLIC—Continued 

*Nitrogen-containing  surface-active  agents, 
nonsulfonated — Continued 

N-Xylol  stearamide ~- 

All  other 

*Sulfated  and  sulfonated  cyclic  surface-active 
agents: 
Alkyl  benzenoid  compounds,  sulfated  and 
sulfonated: 
Benzyldimethylphenylammoniujn  chloride,  sulfated, 
calcium  salt. 

Decylbenzenesulfonic  acid  type 

*Dodecylbenzenesulfonic  acid  type 


Dodecylbenzenesulfonic  acid,  butylammonium  salt- 
Dodeoylbenzenesulfonio  acid,  isopropylaimnonium 
salt. 

Dodecyltoluenesulfonic  acid-- 

Xylenesulfonio  acid,  sodium  salt 

All  other 

Lignin  derivatives,  sulfonated: 

Calcium  lignosulfonate 

Sodium  lignosulfonate — 

♦Naphthalene  derivatives,  sulfonated: 
♦Amylnaphthalenesulfonio  acid,  mono- 


Benzylnaphthalenesulfonic  acid,  mono 

Butylisopropylnaphthalenesulfonic  acid,  sodium 
salt. 

Butylnaphthalenesulfonic  acid,  mono 

Diamylnaphthalenesulfonic  acid 

♦Dibutylnaphthalenesulfonio  acid 

Didodeoylnaphthalenesulfonic  acid — 

*Diisopropyliiaphthalenesulfonic  acid 

Dilaurylnaphthalenesulfonic  acid- 


*Isopropylnaphthalenesulfonic  acid 

l,l'-Methylenebis [2-naphthalenesulfonic  acid] 

Mixed  allcylated  naphthalenesulfonic  acid 

Octylnaphthalenesulfonic  acid 

Oleylnaphthalenesulfonio  acid 

Tetrahydronaphthalenesulfonic  acid — 

♦Petroleum  aromatic  oon^iounds,  sulfonated: 

»Acid-layer-type  petroleum  sulfonate,  sodium  salt 

Oil-layer-type  petroleum  sulfonate 

Oil-layer-type  petroleum  sulfonate,  ammonium 

salt. 
Oil-layer-type  petroleum  sulfonate,  barium  salt- 
Oil-layer-type  petroleiim  sulfonate,  calcium  salt 
Oil-layer-type  petroleum  sulfonate,  lead  salti — 

»Oil-layer-type  petroleum  sulfonate,  sodium  salt- 

*M'L  other  sulfated  and  sulfonated  cyclic  surface- 
active  agents: 

Butylbiphenylsulfonic  acid 

Butylhydroxybiphenylsulfonic  acid 

N-Cyclohexylpalmitoyltaurine 

Dibutylhydroxybiphenyldisulfonic  acid ~ 

Dicapryl  sulfosuccinate,  sodium  salt- — 

N,N-Diethylcyclohexylamine  salt  of  lauryl 
sulfate . 

Nonylphenoxypolyethoxyethyl  sulfate 

Octylphenoxypolyethoxyethyl  sulfate 

Ootylphenoxypolyethoxyethyl  sulfonate 

Toluene  sulfonate,  sodium  salt 

Trichlorophenolethanolamine  sulfate 

o-Xylenesulfonio  acid,  calcium  salt 

SURFACE-ACTIVE  AGENTS,   ACYCLIC 

*Esters  and  ethers,  nonsulfonated: 

Diethylene  glycol  ester  of  tall  oil  fatty  acid 

•Diethylene  glycol  monolaurate 

♦Diethylene  glycol  mono-oleate-- — — — — 

♦Diethylene  glycol  monostearate ™ 

Dlisobutylene  maleate,  sodium  salt-— 

Dipolyethoxyethyl  ether  of  polyoxypropylene  glycol 

Ethylene  glycol  mono-oleate 

♦Ethylene  glycol  monostearate 

Glyceryl  esters  of  normal  fatty  acids 


385. 
1. 


A29. 


AS,   245,  385,  561. 

15,  65,  140,  178,  191,  195,  210,  245,  276,  298,  332, 
349,  385,  417,  429,  446,  473,  505,  516,  527,  529, 
534,  549,  550,  555,  566,  571,  573,  596,  X,  X. 

245. 

566. 

365. 
446. 
573. 

19,  202. 
19. 

464,  566. 

550. 

470. 


294 

178 

15, 

516 

333, 

421. 

333, 

333. 

438, 

58. 

276. 

333. 


403,  495. 
342. 
342,  516,  550,  566. 

374,  385,  421,  496,  516,  550. 

382,  429,  464,  527. 

589. 


81,  362,  404,  518,  555,  560. 

81,  560. 

■^18. 

210,  464,  518. 
223,  303,  518. 
555. 

38,  81,  210,  223,  318,  362,  404,  405,  493,  502,  518, 
566. 


245. 
245. 
550. 
245. 
493. 
333. 

550,  571. 

493. 

493. 

385. 

550. 

75. 


140, 
183, 
183, 
123, 
X. 
493. 
549. 
573. 
123, 
417, 


X. 

262,  370,  421. 

262,  370,  421,  499,  X. 

140,  183,  255,  262,  284,  370,  421,  431,  446,  X, 


183,  255,  262,  370,  446. 


128 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  24B, --Synthetic  organic  chemicals:    Surface-active  agents   for  which  United  States  producti 
were  reported ,    identified  by  manufacturer ,    J95J- -Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


SURFACE-ACTIVE  AGENTS,  ACYCLIC— Continued 

»Esters  and  ethers,  nonsulfonated — Continued 

Glyceryl  maleate  mono-oleate 

Glyceryl  monococate 

Glyceryl  monoester  of  lard 

Glyceryl  monoester  of  soybean  oil 

^Glyceryl  mono-oleate 


^Glyceryl  monostearate- 


Hexitol  polyoxyalkylene  beeswax  ester 

Hexitol  polyoxyalkylene  dilaurate 

Hexitol  polyoxyallqrlene  dioleate 

Hexitol  polyoxyalkylene  fatty  acid  ester 

Hexitol  polyoxyalkylene  hexalaurate 

Hexitol  polyoxyalkylene  hexaoleate- 


Hexitol  polyoxyalkylene  hexastearate 

Hexitol  polyoxyalkylene  hexa(tall  oil)  ester 

Hexitol  polyoxyalkylene  lanolin  ester 

Hexitol  polyoxyalkylene  mono (tall  oil)  ester 

Hexitol  polyoxyalkylene  oleate 

Hexitol  polyoxyalkylene  pentalaurate 

Hexitol  polyoxyalkylene  penta(tall  oil)  ester 

Hexitol  polyoxyalkylene  tetra(oleate,  laurate) 
ester. 

Hexitol  polyoxyalkylene  tetra(tall  oil)  ester 

Methoxypolyethoxyethyl  coconut  oil  ester 

Polybasic  acid  esters 

*Polyethoxyethyl  castor  oil  ester 

*Polyethoxyethyl  coconut  oil  ester 

Polyethoxyethyl  decyl  ether 

*Polyethoxyethyl  dilaurate 

*Polyethoxyethyl  dioleb  ce 

*Polyethoxyethyl  distearate 

Polyethoxyethyl  tert-dodecyl  thioether 

Polyethoxyethyl  fatty  acid  esters 

Polyethoxyethyl  lauryl  ether 

^Polyethoxyethyl  monolaurate 

♦Polyethoxyethyl  mono-oleate 


Polyethoxyethyl  monopalmitate 

Polyethoxyethyl  monoricinoleate — 
♦Polyethoxyethyl  monostearate 


Polyethoxyethyl  oleyl  ether 

Polyethoxyethyl  palmitoylethanol- 

Polyethoxyethyl  rosin  ester 

Polyethoxyethyl  tall  oil  ester 

Polyethoxyethyl  tallow  ester 

Polyethoxyethyl  trideoyl  ether 

Polyethoxy  stearate 

Polyglyceryl  oleate 

Polyoxyalkylene  fatty  acid  ester- 

Polyoxyalkylene  lanolin  ether 

Polyoxyalkylene  resin  ester 


1 , 2-Propylene  glycol  monococate 

1,2-Propylene  glycol  monolaurate 

1,2-Propylene  glycol  mono-oleate 

«l,2-Propylene  glycol  monostearate 

Propylene  glycol  polyoxyalkylene  stearate 

Propylpolyethoxyethyl  ether  of  polyoxypropylene 

glycol. 
•Nitrogen-containing  surface-active  agents, 

nonsulfonated : 

Alkylaminopolyethoxy  ethanol 

Alkylsulfoamidoacetic  acid,  sodium  salt 

N- (Aminoethyl )-N- (hydroxyethyl )oleamide  (Oleamide 

of  aminoethylethanolamine ) . 
*N- (Aminoethyl )-N- (hydroxyethyl )stearamide  (Stear- 

amlde  of  aminoethylethanolamine). 

Cetylbetaine 

Cetylethyldimethylammonium  bromide 

Cetyl,  lauryl  trimethylammonium  bromide,  mixed 

Cetyltrimethylammonium  acetate 

Cetyltrimethylamraonium  bromide — 

Cocate  diethanolamine —— 

Coconut  oil  amide  of  aminoethylethanolamine 

♦Coconut  oil  amide  of  mono (diethanolamine) 

(Diethanol  lauramide). 


X. 

X. 

438,  541. 

541. 

123,  183,  259,  262,  370,  417,  421,  4^6,  499,  517, 

541,  X. 
53,  123,  183,  255,  262,  276,  370,  421,  431,  438, 

541,  X. 
417. 
417. 
417. 
417. 
417. 
417. 
417. 
417. 
417. 
417. 
417. 
417. 
417. 
417. 

417. 

140,  370,  438. 

466. 

342,  421,  550,  X. 

1,  178,  255,  276,  534,  573. 

417. 

183,  342,  370,  374. 

342,  370,  429,  573. 

284,  370,  517,  X. 

245,  464,  517,  573,  580. 

470. 

178,  333,  417. 

24,  109,  262,  265,  284,  342,  370,  421,  438,  446, 

517,  550. 
109,  178,  183,  262,  284,  342,  370,  374,  385,  417, 

421,  429,  438,  4S5,  517,  534,  550,  573,  581. 
417. 

370,  421. 
109,  140,  178,  183,  255,  262,  269,  284,  342,  370, 

374,  417,  421,  479,  517,  550,  X. 
333,  417,  550. 
550. 
222. 

58,  140,  245,  417,  421,  517,  550,  573,  X. 
140,  284,  429,  554, 
417. 
493. 
541. 
417. 
417. 
417. 
X. 

183,  262,  370,  417,  X. 
262,  370,  483. 
123,  262,  276,  370,  541,  X. 
417. 
549. 


417. 
550. 
358,  385,  421. 

15,  140,  284,  332,  349,  358,  365,  374,  385,  403, 

421,  428,  429,  566,  575. 
333,  591. 
591. 
333. 
591. 
591. 
X. 

140,  332. 
109,  115,  284,  332,  342,  349,  374,  385,  421,  429, 

438,  446,  529,  561,  571,  575,  X. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


129 


TABLK  24B, --Syntbet  ic   organic  chemicals:   Surface-act  ive  agents    for  which  United  States  product  ion 
were  reported ,    identified  by  manufacturer ,    J95J- -Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


SURT ACE-ACTIVE  AGENTS,   ACYCLIC— Continued 

»Nitrogen-containing  surface-active  agents, 

nonsulf onated — Cont  inued 

»Coconut  oil  amide  of  bis(diethanolamine) 

Coconut  oil  amide  of  diethanolamine  (neither  bis 

nor  mono). 

Coconut  oil  amide  of  diethylenetriamine 

Coconut  oil  amide  of  isopropanolamine 

Coconut  oil  amide  of  monoethanolamine  (Ethanol 

lauramide). 
Coconut  oil  ester  of  ethanolamine  hydrochloride-- 

Coconut  oil  trimethylammonium  chloride 

Deoylbetaine- 


Dicoconut  oil  dimethylammonium  chloride 

Dihydrogenated  tallow  dimethylammonium  chloride 

N,  N-Di  (2-hydroxyethyl  )bisoleamide 

N,N-Di (2-hydroxyethyl )lauramide  (Diethanolamine 
laurate ) . 
»N , N-Di ( 2-hydroxyethyl )oleamide  (Diethanol  oleamide ) 
*N , N-Di (2-hydroxyethyl )stearamide  (Diethanol 
stearamide). 

Dilaurylammonium  bromide 

Dodecyltrimethylammonium  bromide 

Dodecyltrimethylammonium  chloride 
Dodecyltrimethylammonium  tosylate 


Ethanollaurylamide-ethylene  oxide  condensate 

N,N-Ethylene  bisstearamide 

Fish  oil  amide  of  diethanolamine,  potassium  salt 

N-(2-Hydroxyethyl)myristamide  (Ethanol  myristamide) 

N-(2-Hydroxyethyl)oleamide  (Ethanol  oleamide) 

N-(2-Hydroxyethyl)stear amide 

N-(Hydroxymethyl)stearamide  (Methylolstearamide ) 

N-(Hydroxymethyl)stearamide,  methyl  ester 

N-(2-Hydroxypropyl)oleamide  (Isopropanol  oleamide  )- 
Laurie  myristic  diethanolamine- 


N-Lauroylisopropanolamide 

N-Lauroylpolypeptide-— — — 

Lauroylsarooside 


Nitrogen  base  stearates — 

Octadecylethyldimethylammonium  bromide 

Octadecyltrimethylammonium  chloride 

Octadecyltrimethylenediamine 

Oleamide  of  diethylenetriamine 

Oleylaminopolyethoxyethanol ~ 

Oleylbiguanide  hydrochloride 

Oleylpolypeptide — 


Oleylsarcosin  (N-Methyloleoylglyoine),  sodium  salt- 
Palm  oil  amide  of  ami  noethylethanolamine 

N-Polyethoxy  oocoamine — 

Polyethoxyethanol  mixed  fatty  amides  and  amines 

Polyethoxyethyl  casein 

Polypeptide 

Soybean  oil  aeyl  chloride  salt  of  sodium 

lysalbinate. 
Soybean  oil  diethyltriamino-ethylene  oxide  addition 

product,  ammonium  salt. 
Soybean  oil  trimethylammonium  chloride- — — — 

*Stearamide  of  diethylenetriamine 

»Stearamide  of  tetraethylenepentamine- 


l-Stearamido-l'-adipoamido  diethyleneamine 

l-Stearamido-l'-sebacamido  diethylenediamine—-- 

Stearic  acid  ester  of  N- (2-hydroxyethyl )stearamide- 

Stearylaminopolyethoxyethanol 

Stearylbiguanlde  hydrochloride 

Triethanolamine  coconut  oil  eater      — — — 

Triethanolamlne  oleate _.—-_-— 

Triethanolamine  stearate— — — — —- .-- 


Trihexylammonium  sulfotrlcarballylate 

Trimethylatearylammonium  bromide 

•Phosphorus-containing  surface-active  agents, 
nonsulf onated : 

Alkyl  phosphates  (mixed,  nonionic) 

Alkyl  polyphosphate,  sodium  salt- 


Diethanolamlne  salts  of  mixed  mono-  and  diallcyl 
acid  phosphates. 

Ethylhexyl  sodium  phosphate 

Lauryl  phosphate 

Octyl  polyphosphate,  potassium  salt 

Octyl  polyphosphate,  sodium  salt — 


17,  Ue,    lAO,  178,  265,  385,  <i21,  4A6,  566,  573,  X. 
535. 

58,  421. 

178,  385,  <W6. 

15,  58,  178,  276,  3i9,  37-1,  AAb,    566,  X. 

541. 

23. 

333. 

23. 

23. 

573. 

333. 

109,  123,  342,  403,  446,  X. 
58,  342,  385,  421,  446,  566. 

374. 

333. 

23. 

591. 

385. 

123,  342. 

535. 

X. 

421,  575. 

333. 

333.  -- 

333. 

X. 

X. 

342. 

244,  274. 

342,  550,  566. 

332. 

591. 

23. 

23. 

358. 

550. 

550. 

274. 

550. 

403. 

550. 

23,  550. 

550. 

274. 

244. 

550. 


358,  365,  374,  382,  429,  575. 
365,  374. 


X. 

550. 


Octyl  polyphosphonate  and  phosphate 

Phosphorus  derivatives  of  capryl  and  octyl  alcohol- 


23. 

58, 

332, 

58. 

58. 

446, 

417, 

550. 

446. 

302, 

24. 

550. 

333. 


208. 
208. 
333. 

392. 

333. 

535. 

208,  535. 

535. 

332. 


130 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  2'iB. -Synthetic  organic  chemicals:   Surface-active  agents   for  which  United  States  production  or   sale 
were  reported ,    identified  by  manufacturer ,    195J-- Con tinuei! 


Manufacturers '  identification  nujnbers 
(according  to  list  in  table  27) 


SURFACE-ACTIVE  AGENTS,  ACYCLIC— Continued 


•Salts  of  fatty  acids,  nonsulfonated: 
Castor  oil,  potassium  salt 

•Coconut  oil,  potassium  salt 

Coconut  oil,  sodium  salt 

Corn  oil,  potassium  salt 

Corn  oil,  sodium  salt 

Fish  oil,  potassium  salt 

Potassium  laurate 

•Potassium  oleate 


•Potassium  resinate 

Potassium  stearate — 

•Potassium  tallate — 

•Sodium  oleate 

Sodium  stearate 

Sodium  tallate 

Soybean  oil,  potassium  salt 

Tall  oil,  potassium  salt 

Tallow,  potassium  salt 

Tallow,  sodium  salt- 


•Sulfated  and  sulfonated  acyclic  surface-active 
agents : 
•Acids,  sulfated  and  sulfonated: 

Acetyloleic  acid,  sulfonated 

Coconut  oil  fatty  acids,  sulfonated 

Cottonseed  oil  fatty  acids,  sulfonated 

Fish  oil  fatty  acids,  sulfonated 

•Oleic  acid,  sulfonated  (Sulfonated  red  oil)- 


Ricinoleic  acid,  sulfonated 

Soybean  oil  fatty  acids,  sulfonated 

All  other 

•Alcohols,  sulfated  and  sulfonated: 

Capryl  and  octyl  alcohols,  sulfated 

Cetyl  and  oleyl  alcohols,  sulfated 

n-Deoyloxyethyl  sulfate 

Dieapryl  sulfate 

3, 9-Diethyl-6-tridecyl  sulfate 

2-Ethylhexyl  sulfate 

7-Ethyl-2-methyl-^undecyl  sulfate 

Hexadecyl  sulfate- 


Lauryl,  oleyl  sulfate,  mixed,  sodium  salt 

Lauryl  sulfate,  ammonium  salt 

Lauryl  sulfate,  diethanolamine  salt 

Lauryl  sulfate,  monoethanolamine  salt 

Lauryl  sulfate,  potassium  salt — 

Lauryl  sulfate,  sodium  salt  (Sodium  dodeoyl 

sulfate). 

•Lauryl  sulfate,  triethanolamine  salt 

Octadeoyl  sulfate  (Stearyl  sulfate) 

Polyethoxyethyloctadecyl  sulfate 

Polyethoxyethyloctadecyl  sulfate,  diethanolamine 

salt. 

Tridecyl  sulfate,  sodium  salt 

•Esters,  sulfated  and  sulfonated: 

Bis-sulfosuccinate  ester  of  tallow  monoglyceride 

Butylethyleneglycol  sulfo-oleate — — 

n-Butyl  sulfo-oleate 

n-Butyl  sulforicinoleate,  sodium  salt 

Di(2-ethylhexyl)  sulfosuocinate,  sodium  salt 

Dlhexyl  sulfosuocinate,  sodium  salt 

Ethyl  and  butyl  sulfoaoonitate,  sodium  salt 

Ethyleneglycol  sulfo-oleate 

Ethyl  sulfo-oleate 

Glycerol  mono(coconut  oil)  ester,  sulfated, 

ammonium  salt. 
Glycerol  mono(coconut  oil)  ester,  sulfated, 

sodium  salt. 
Glycerol  monostearate  sulfoaoetate,  sodium  salt- 

•Glycerol  tri (sulfo-oleate ) 

•Isopropyl  sulfo-oleate 


Lauroyl  ethylaulf onate ,  sodium  salt 

Lauryl  sulfoacetate 

Methyl  sulfo-oleate 

Methyl,  ethyl,  and  propyl  sulfo-oleate 

n-Octadecylsulfosuocinate,  disodium  salt- 
an-Propyl sulfo-oleate 

Synthetic  glyceride,  sulfonated 


534. 

113,  140,  284,  428,  438,  575. 
284. 

16,  113,  534. 
24. 
535. 

265,  421. 

16,  113,  140,  164,  293,  328,  356,  385,  403,  421, 
428,  561,  573,  581. 

15,  332,  566,  573. 

16,  164,  293. 

16,  24,  113,  140,  265,  534,  535. 

15,  16,  140,  356,  385,  421,  438,  464,  566,  575. 
231,  293,  314,  421,  429,  515,  566. 

140,  265,  421,  534. 
113,  438,  534. 
573. 
438. 

16,  332,  534. 


333. 

14,  356. 

136. 

48,  259,  421. 

14,  15,  48,  54,  65,  81,  112,  130,  136,  143,  178, 
259,  269,  293,  298,  332,  341,  356,  365,  382,  403, 
421,  429,  438,  491,  529,  550,  566,  571,  573,  596. 

421,  438. 

421. 

113,  495. 


332. 

294. 

333, 

X. 

535. 

392. 

392. 

392. 

333, 

333. 

100, 

333. 

470. 

100, 

100, 


342. 
276,  571. 


276,  516. 

178,  276,  333,  374,  429,  493,  566,  571. 


100,  276,  333,  374,  571. 

276,  332,  333. 

333. 

333. 

140. 

464, 

428. 

140,  365,  374,  566. 

450. 

178,  342,  464,  535. 

464. 

140,  464. 

428. 

550. 

X. 

376,  X. 


541. 
178, 
178, 
438. 
527. 
365, 
421. 
464. 
265, 
566. 


429,  438,  554. 
332,  349,  382,  516. 


403,  464,  499,  554,  573. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


131 


TABLE  24B... Synthetic  organic  chemicals:    Surface-active  agents   for  which  United  States  production  or   sales 
were   reported,    identified  by  manufacturer ,    795J- -Continued 


SURFACE-ACTIVE  AGENTS,   ACYCLIC— Continued 

»Sulfated  and  sulfonated  acyclic  surface-active 
agents — Continued 
»Esters,  sulfated  and  sulfonated — Continued 

Tallow  and  coconut  oil  fatty  acids,  ethyl  ester, 

sulfonated. 
»Nitrogen-containing  surface-active  agents,  sulfated 

and  sulfonated: 
Castor  oil  monoethanolamide,  sulfated,  sodium 

salt. 
Coconut  oil  amide  of  isopropanolamine,  sulfated, 

sodium  salt. 
Coconut  oil  amide  of  monoethanolamine ,  sulfated, 

potassium  salt. 
*Coconut  oil  amide  of  monoethanolamine,  sulfated, 

sodium  salt. 
Coconut  oil  fatty  acid  ethanolamide  sulfosuc- 

cinate,  sodium  salt. 
N-(2-Hydroxyethyl)oleamide,  sulfated  (Oleic  acid 

ethanolamide  sulfate),  sodium  salt. 
N-(2-Hydroxyethyl)stearamide,  sulfated  (Stearic 

acid  ethanolamide  sulfate),  sodium  salt. 
Laurie  acid  ester  of  potassium  sulfoaceto- 

ethanolamide . 

Lauroylamidoethyl  sulfate,  sodium  salt 

•N-Methyloleoyltaurine,  sodium  salt 

N-Methylpalmitoyltaurine,  sodium  salt 

N-(Myristoylethyl)sulfosuocinamide,  sodium  salt- 
Neat  's-foot  oil  amide  of  ethanolamine ,  sulfated, 

ammonium  salt. 
Octadecylamine-l-epiohlorohydrin  reaction 

product,  sulfonated. 

N-Octadecylsulfosuocinamide,  disodium  salt 

Oleoyl  isopropanolamide  sulfate,  ethanolamine 

salt. 
N-(01eoylisopropyl)sulfosucclnamide,  sodium  salt 
Tallow  amide  of  ethanolamine  sulfosuccinate, 

sodium  salt. 
*011s,  fats,  and  waxes,  sulfated  and  sulfonated: 
Animal  fats  and  oils,  sulfated  and  sulfonated: 

Grease  other  than  wool  grease,  sulfonated 

Lard  oil,  sulfonated 

»Neat' 8-foot  oil,  sulfonated 

Oleostearine,  sulfonated 

»Tallow,  sulfonated ■ 


Wool  grease,  sulfonated 

All  other 

*Flsh  and  marine-animal  oils,  sulfated  and 
sulfonated: 
«Cod  oil,  sulfonated 

*Herring  oil,  sulfonated 

»Menhaden  oil,  sulfonated 

Mixed  fish  oils,  sulfonated 

Red  fish  oil,  sulfonated 

Salmon  oil,  sulfonated 

»Sperm  oil,  sulfonated 

Whale  oil,  sulfonated 

»Tall  oil,  sulfonated 

•Vegetable  oils,  sulfated  and  sulfonated: 
"Castor  oil,  sulfonated — 


"Coconut  oil,  sulfonated' 

"Com  oil,  sulfonated 

Cottonseed  oil,  sulfonated- 
Linseed  oil,  sulfonated- 


Mustard-seed  oil,  sulfonated- 

Olive  oil,  sulfonated — 

Palm-kernel  oil,  sulfonated — 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


385. 

178,  575. 

332. 

15,  58,  140,  178,  332,  342,  349,  358,  374,  385,  516, 

566,  575. 
X. 

403,  421. 

429. 

X. 

351. 

15,  140,  349,  429,  505,  535,  550,  566,  575. 

550. 

X. 

58. 

464. 

464. 
X. 


X. 

403. 


136,  189,  421,  534. 

52,  58,  150,  385,  553,  573. 

54,  58,  60,  65,  117,  130,  143,  150,  259,  328,  356, 

421,  438,  491,  534. 
130. 
15,  65,  80,  81,  130,  136,  140,  143,  150,  178,  189, 

259,  279,  284,  298,  307,  319,  332,  349,  365,  374, 

382,  403,  421,  429,  438,  464,  491,  501,  534,  554, 

566,  573. 
136. 
150,  464. 


37,  52,  117,  130,  136,  150,  328,  356,  421,  428,  429, 

438,  491,  505,  534,  553,  573. 
37,  130,  136,  150,  421,  534,  553. 
136,  150,  534,  553, 
150. 
464. 
150. 
37,  52,  54,  117,  130,  136,  143,  150,  178,  328,  341, 

349,  356,  374,  421,  428,  429,  438,  464,  491,  505, 

534,  553,  573. 
150. 
15,  58,  130,  143,  178,  259,  269,  365,  421,  464,  505, 

534,  596. 

15,  48,  54,  58,  65,  81,  112,  117,  130,  136,  140, 
143,  149,  150,  189,  259,  265,  269,  279,  284,  298, 
304,  307,  328,  332,  333,  341,  349,  356,  365,  374, 
380,  382,  385,  421,  428,  429,  436,  438,  464,  491, 
495,  505,  529,  534,  550,  553,  556,  561,  566,  571, 
573. 

37,  65,  130,  150,  341,  421,  438,  464,  505,  553. 

14,  65,  113,  421,  464,  571. 

150,  341,  421. 

150,  491,  505. 

421,  491,  571. 

429,  436,  505. 

553. 


132 


UNITED  STATES  TARIFF  COMMISSION 


-Synthet  ic  organic   chemicals;   Sur face -active  agents   for   which  United  States  production   or   sales 
were  reported ,    identified  by  manufacturer ,    2955- -Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


SURFACE-ACTIVE  AGENTS,  ACYCLIC— Continued 

■"■Sulfated  and  sulfonated  acyclic  surface-active 
agents — Continued 
*Oils,  fats,  and  waxes,  sulfated  and  sulfonated — 
Continued 
*Vegetable  oils,  sulfated  and  sulfonated — 
Continued 

■»Peanut  oil,  sulfonated 

Rapeseed  oil,  sulfonated 

Hioe-bran  foots,  sulfonated 

^fRice-bran  oil,  sulfonated 

■^Soybean  oil,  sulfonated 

Soybean-oil  foots,  sulfonated 

Teaseed  oil,  sulfonated 

All  other 

All  other  oils,  fats,  and  waxes,  sulfated  and 
sulfonated: 

Japan  wax,  synthetic,  sulfonated 

Petroleum  aliphatic  compounds,  sulfated  and 
sulfonated:  Petroleum  sulfonate,  sodium  salt, 

Recovered  grease,  sulfonated 

All  other 


81,  298,  307,  3A1,  403,  421,  46-4,  491,  554. 

178. 

65,  421. 

15,  189,  307,  349,  421,  429,  438. 

15,  54,  136,  143,  150,  349,  374,  438,  491,  534,  553. 

113. 

505. 

140. 


140. 

109,  286,  333. 


130,  136,  356. 
333,  426,  429,  534. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


133 


Pesticides  and  Other  Organic  Agricultural  Chemicals 


TABLE  2SB.--Synthetic   organic  chemicals;    Pesticides  and  other  orHanic   agricultural   chemicals  for   which  United 
States  product  ion  or  sales   were   reported,    identified  by  manufacturer ,    1953 

[Pesticides  and  other  organic  agricultural  chemicals  for  which  separate  statistics  are  given  in  table  25A 
are  marked  below  with  an  asterisk  (») ;  products  not  so  marked  do  not  appear  in  table  25A  because  the  re- 
ported data  are  confidential  and  may  not  be  published.  Manufacturers'  identification  numbers  shown  below 
are  taken  from  table  27.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his 
identification  number  with  the  designated  product] 


Manuf aotxirers '  identification  nijmbers 
(according  to  list  in  table  27) 


PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL 
CHEMICALS,  CYCLIC 


•Fungicides  and  seed  disinfectants: 
p-Benzylphenol- 


Chloranil  (Tetrachloro-p-quinone)- 
2-Chloro-<i-  ( hydroxymerour  i )  phenol- 
2, 3-Diohloro-l ,  -i-naphthoquinone- 


3, 5-Dimethyltetrahydro-3, 5-thiadiazine-2-thione — 
N-(Ethylmercuri)-p-toluenesulfananilide— — — 
Hydroxymerourinitrophenol- 

*Naphthenic  acid,  copper  salt 

Pentachlorophenol 

Pentachlorqphenol,  sodium  salt- 

Phenyl  mercuric  hydroxide -  ■ 

Phenyl  mercuric  lactate- 
Phenyl  mercuric  monoethanolaramonium  acetate——- 
Phenyl  mercuric  naphthenate — 

•Phenyl  mercuric  oleate— — —  ■■ 

Phenyl  mercuric  triethanolammonium  lactate——-— 
Phenyl  mercuric  urea- 


»8-Quinolinol  ( 8-Hydroxyquinoline) ,  copper  salt- 
2,3,A,6-Tetraohlorqphenol- 


N-Trlchloromethylthiotetrahydrophthalimide- 
2,'4,5-Trlehlorciphenol- 


2,4,5-Trichlorophenol,  ethanolamine  salt- 

2,4,5-Trichlarophenol,  sodium  salt 

2 ,  <♦,  6-Trlohlorqphenol- 


2,4-,6-Triohlorophenol,  potassium  salt- 
•Herbicides  and  plant  hormones: 
2-seo-Amyl-<i,  6-dinltrophenol- 


2-seo-Butyl-4,6-dinltrophenol 

2-seo-Butyl-4, 6-dinitrqphenol,  triethanolamine 

salt. 

l-(p-Chlorophenyl)-3,3-dimethylurea 

3-(3,4-Oiohlarcrphenyl)-l,l-dimethylurea— — — - 
3-(3,4-Dichlorophenyl)-l-methylurea 
l,2-Dihydro-3,6-pyridazlnedione   (Malelo  hydrazide) 

l,l-Dimethyl-3-phenylurea 

3,6-Endoxyhexahydrcphthalio  acid,  dlsodium  salt— 
Isopropyl  N-( 3-chlorophenyl) carbamate— ————— 

Isqpropyl  N-phenylcarbamate  (Isopropyl 

oarbanilate)  (IPC). 
•Naphthalene-  and  naphthox^-acetic  acid 
derivatives : 

1-Naphthaleneacetamide- 


l-Naphthaleneaoetic  acid 

1-Naphthaleneaoetic  acid,  methyl  ester- 

1-Naphthaleneacetic  acid,  sodium  salt — 
2-Naphthoxyacetic  acid- 


2-Naphthoxyaoetic  acid,  sodium  salt- 

N-1-Naphthylphthalamic   acid ~ 

Phenoxyacetic  acid,   salts  and  derivatives: 
2-Chloro-4-mothoxyphenoxyacetic  acid, 

dlmethylamlne  salt. 
2-Chloro-4-methoxyphenoxyaoetic  acid,   iso-octyl 

ester, 
'»-Chloro-2-methylphenoxyacetio  acid 
p^hlorqphenoxyncetic  acld- 
*2,4^ichlorophenoxyBcetio  acid  (2,4-D)- 
•2,4-Dichlorqphenaxyacetlc  acid  esters: 
Amyl  2,4-dichlorqphenoxyaoetate- 
Butoxyethanol  2,4-dichlorophenoxyacetate- 
Butoxypolyprqpyleneglyool  2,'i-dichloro- 

phenoxyaoetate . 
n-Butyl  2,4-dlchlorciphenoxyao9tate— — 
sec-Butyl  2,4-dichlorophenoxyacetate— 
Ethyl  2,4-dichlorophenoxyacetate- 


Iso-octyl  2,4-dichlorqphenoxyacetate- 
Isopropyl  2,ii-diohlorcrphenoxyacetate- 


Tetrahydrofiirfuryl  2,'4-dichloraphenoxyacetate 
•2,'t^iohloraphenoxyacetlo  acid  salts: 

2,'i-Diohlorophenoxyacatic  acid,  diethanol- 

amlne  salt. 
2,4-Diohlorciphenaxyacetio  acid,  dimethylamine 
salt. 


431. 
378. 
333. 
378. 
479. 
333. 
333. 
110, 
245, 
245, 
211, 
211, 
557. 
211. 
211, 
557. 
211. 
132, 
448. 
177. 
338, 
550. 
245, 
448. 
479, 

3. 

448. 

3. 


333. 

333. 

333. 

378. 

333. 

580. 

245,  391,  463. 

391. 


135,  214,  221,  314,  353,  440,  466,  485,  555,  581. 

448. 

448. 

333. 

325. 


333,  353,  557. 

245,  342,  353. 

448,  594. 

448. 

594. 


271. 
448, 
271, 
271, 
494, 
494. 
378. 


245. 
448. 
245, 

55. 
X. 

448, 

55, 
448 
271 
456 
177 
493 


591,  597. 
597. 
494. 
591. 


391,  448,  456,  493,  517,  594. 


177,  245,  493,  517,  594. 
,  456,  493. 


517. 

271,  448,  456,  493,  517,  594. 


55, 


,  271,  504. 
177,  333,  456,  493,  517,  594. 


134 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  2SB. --Synthetic  organic  chemicals:   Pesticides  and  other  organic  agricultural  chemicals    for  which  United 
States  prodtiction  or  sales  were  reported,   identified  by  manufacturer,   J953- -Continued 


Manufacturers'  Identification  numbers 
(according  to  list  in  table  27) 


I 


PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL 
CHEMICALS,  CYCLIC — Continued 

*Herbioides  and  plant  hormones — Continued 

Phenoxyacetio  acid,  salts  and  derivatives — Con. 
»2,"i-Dichlorophenoxyacetic  acid  salts — Continued 
2,4-Diohlorophenoxyacetic  acid,  isopropanol- 
ajnine  salt . 

2,'4-Dichlorophenoxyacetic  acid,  sodium  salt 

2,4-Diohlorophenoxyacetic  acid,  triethanol- 
amine  salt. 

«2,'i,5-Triohlorophenoxyaoetic  acid  (2,A,5-T) 

»2,4,5-Trichlorophenoxyaoetio  acid  derivatives: 

Amyl  2,4-,5-trichlorophenoxyaoetate 

Butoxyethanol  2,i4,5-triohlorophenoxyaoetate 

Butoxypolypropyleneglycol  2,'4,5-trichloro- 
phenoxyacetate . 

n-Butyl  2 ,i , 5-trichlorophenoxyaoetate 

Iso-octyl  2,'4,5-trichlorophenoxyacetate 

Isopropyl  2,'*,5-trichlorophenoxyaoetate 

Tetrahydrofurfuryl  2,4,5-trichlorophenoxy- 
aoetate. 

♦Phenyl  mercuric  acetate 

2, A, 5-Trichlorophenoxypropionio  acid 

♦Insecticides: 

Aldrin  (Hexaohlorohexahydrodimethanonaphthalene) — 

Allethrin  (Allyl  homolog  of  Cinerin  I) 

Benzyl  thiooyanate— — ~ — ___— — 

l,l-Bis(p-chlorophenyl)-2-nitrobutane 

1, 1-Bis (p-chlorophenyl) -2-nitrqprapane 

2-(p-tert-Butylphenoxy)isopropyl-2-chloroethyl 

sulfite. 
Chlordane  (l,2,4,6,7,8,8-octaohloro-4,7-methano- 
3a,4.,7,7a-tetrahydroindane) . 

p-Chlorophenyl  p-chlorobenzenesulfonate 

2-Cyolohexyl-<t,6-dinitrophenol 

1,2-Dibromoethylbenzene  (Styrene  dibromide) 

l,l^ichloro-2,2-bis (p-chlorophenyl )ethane  (DDD)~ 

l,l-Diohloro-2,2-bis(p-ethylphenyl)ethane 

2,4-Dichlorophenyl  benzenesulfonate _______ 

Dieldrin  (Hexachloroepoxyoctahydrodimethano- 
naphthalene ) . 

Dlnitro-octylphenyl  crotonate  ■  

4,6-Dinitro-o-cresol  (DNOC) 

4,6-Dinltro-o-cresol,  sodium  salt 

Endrin  (Hexachloroepoxyoctahydroendoendodimethano- 

naphthalene ) . 
Ethyl  p-nitrciphenyl  thlonobenzenephosphonate  (EPN) 

Heptaohlor  (Heptachlorohydro-4, 7-methanoindene) 

»Hexaohlorooyolohexane  (Benzene  hexaohloride) 

Lindane  —  — — — 

Ootachlorooyclohexenone- 


Parathion  (0,0-Diethyl  O-(p-nitrqphenyl) 
thlophosphate) . 

Thanlte  (Isobomyl  thiocyanoaoetate) 

Toxaphene  (Chlorinated  cajnphene)- 


•1, 1, l-Triohloro-2, 2-bis (p-ohlorophenyl)ethane 
(DET). 
l,l,l-Trichloro-2,2-bls(p-methoxyphenyl)ethane 
(Methoxychlor)  (Methoxy  DDT) . 
Rodentioides: 

l-( 1-Naphthyl) -2-thiourea 

2-Pivalyl-l , 3-indandione 

Warfarin  ( 3- ( Aoetonylbenzyl ) -4-hydroxycoumar in) - 

PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL 
CHEMICALS,  ACICLIC 


•Fumigants : 
»Bramomethane  (Methyl  bromide) - 
Chlorqpiorin- 


1,2-Dichlorapropane- 


DlohloroprcpGne-dlohloropropane  (D-D  mixture) - 
♦Fungicides  and  seed  disinfectants: 

Cadmium  succinate 


Copper  ethyleaproate - - ■ 

Ccipper  hendecenoate  (Copper  undeoylenate) — — — — 
Dlmethyldithiocarbamlc  acid,  ferric  salt  (Ferbam)- 
•Dimethyldithiocarbamio  acid,  sodium  salt- 


245. 
177,  333. 

245,  363,   391,   426,  448,   456,  494,   594. 

55. 

X. 

426,  448. 

44S,   456,  493,   517,   594. 
456,   517. 

177,   245,   456,    517,    594. 
177,   493. 

211,   325,    557. 
271,   363,   494. 

474. 

343,   463,   600. 

338. 

367. 

367. 

378. 

311. 

448,   594. 

448. 

448. 

493,   504. 

493. 

504. 

474. 

493. 
3. 
3. 
474. 

333. 
311. 
161,   217,   275,   331,   333,   338,   345,   367,   391,  426,   430, 

456,   504,   574,   594. 
338,   504,   574,   594. 
563. 
245,   456,   464. 

222,   281. 

222. 

51,   139,   181,   245,   275,   333,   390,   492,   493,   495,   504, 

594. 
333. 


476. 
599. 
600,  X. 


♦Dlmetlflrldithiocarbamic  acid,   zinc  salt  (Zlram)- 


181, 

359, 

448. 

171. 

549. 

258. 

231, 

581. 

494, 

591. 

211, 

333, 

476. 

137, 

211, 

364, 

396,   580. 

211, 

245, 

333, 

364,   378,   396, 

580 

SYNTHETIC  ORGANIC  CHEMICALS,  1953 


135 


TABLE  2SB. -Synthetic  organic  chemicals:    Pesticides  and  other  organic  agricultural  chemicals   for   which  United 
States  production  or   sales  were  reported,    identified  by  manufacturer,    i95J- -Continued 


PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL 
CHEMICALS,  ACYCLIC — Continued 

•Fungicides  and  seed  disinfectants — Continued 
Ethyl  mercuric  acetate- 


Ethyl  mercuric  chloride 

Ethyl  mercuric  hydroxide 

Ethyl  mercuric  phosphate-—- 

Ethylenebis(dithlocarbamic  acid),  manganese  salt — 
Ethylenebis(dithiocarhaiiiic  acid),  sodium  salt 

(Nabam) . 
Ethylenebis(dithiooarbaralo  acid),  zinc  salt  (Zineb) 

Methoxyethylmercuric  acetate 

Methylmercuric  hyiiroxide 

Sodium  hendecenoate  (Sodium  undecylenate) 

Tetraiodoethylene 

Zinc  hendecenoate  (Zinc  undecylenate) 

All  other 

♦Herbicides: 

Diethyl  dithiobis(thionoformate) 

Trichloroacetic  acid- 


Trichloroacetic  acid,  sodium  salt 
•Insecticides: 

Aliphatic  thiooyanates 


S-(l,2-Dicarbethoxyethyl)  0,0-dimethyl  dithio- 

phosphate  (Malathion) . 
Metaldehyde 


Ootamethyl  pyrophosphoramide  (OMPA) 

Tetraethyl  dithionopyrqphosphate 

•Tetraethyl  pyrophosphate  (TEPP) 


Rodenticides:  Sodium  fluoroacetate 

•Soil  conditioners: 

Methylvinylether-maleio  anhydride  half -amide 
oqpolymer. 

Polyaorylonitrile,  hydrolyzed,  sodium  salt 

Vinyl  aoetate^naleio  acid,  modified 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


333. 
333. 
333. 
333. 
333. 
333,  493. 

333,  493. 

211. 

599. 

494. 

313. 

313,  494. 

563. 

245. 

448,  504. 
245,  338,  448. 

493. 
464. 

367. 

245. 

245,  476. 

177,  208,  245,  312,  345,  359,  476. 

245. 


268,  464. 
245. 


136  UNITED  STATES  TARIFF  COMMISSION 

Miscellaneous  Synthetic  Organic  Chemicals 


TABLE  26B. -Synthetic   organic 


chemicals:   Miscellaneous  chemicals   for  which  United  Sta 
were  reported,    identified  by  manufacturer ,   1953 


production  or  sales 


[  Miscellaneous  chemicals  for  which  separate  statistics  are  given  in  table  26A  are  marked  below  with  an 
asterisk  (»);  chemicals  not  so  marked  do  not  appear  in  table  26A  because  the  reported  data  are  confi- 
dential and  may  not  be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from  table 
27.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  num- 
ber with  the  designated  product] 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


MISCELLANEOUS  CHEMICALS,  CYCLIC 


2-Aminobenzothiazole 

<i-Amino-5-  ( e  thoxymethyl )  -2-methylpyrimidine 

Benzoic  acid  salts: 

Ammonium  benzoate 

Copper  benzoate 

»Sodium  benzoate,  tech 

*Sodium  benzoate,  U.S.P 

Benzoin  oxijne 

Benzothiazole 

»Benzoyl  peroxide 

Benzoyl  resorcinol 

3-Benzyl-<»-methylumbelliferone 

Biological  stains 

■4,'i'-Bis[phenylureido]-2,2'-stilbenedisulfonic 
acid. 

Boron  fluoride-phenol  complex 

Butoxysafrol ~ 

2 ( and  3 ) -tert-Butyl-^-methoxyphenol 

tert-Butyl  peroxybenzoate 

«i-tert-Butylpyrocatechol 

Butyrolactone 

Camphene 

«Centralite  ( N , N '-Diethyl-N , N '-diphenylurea ) 

Chemical  indicators: 

m-Cresolsulfonphthalein  (m-Cresol  purple) 

o-Cresolsulfonphthalein  (Cresol  red) 

Dibrorao-o-cresolsulfonphthalein  (Bromooresol 

purple). 
Dibromothymolsulfonphthalein  (Bromothymol  blue) — 
Dichlorophenolsulfonphthalein  (Chlorophenol  red)- 

N,N'-Diphenylbenzidine 

Phenolsulfonphthalein  (Phenol  red) 

Tetrabromo-ra-cresolsulfonphthalein  (Bromocresol 

green ) . 
Tetrabromophenolsulf onphthale  in  ( Bromophenol 
blue ) . 

Thymolphthalein 

Thymolsulfonphthalein  (Thymol  blue) 

All  other 

"Chemical  reagents: 

Aurin tricarboxylic  acid 

Barium  diphenylamine  sulfonate 

Diphenyl  carbazide 

Diphenyl  carba  zone 

Diphenyl  thiocarbazone  (Dithiazone) 

a,a-Dipyridyl 

Girard  P  reagent 

N-(1-Naphthyl)ethylenediamine  dihydroohloride 

NitroEophenylhydroxylamine  (Cupferron) 

Phlorogluc  inol  CP 

Potass  ium  biphthalate 

Quinhydrone 

Sodium  biphthalate 

Sodium-2 , 5-d  ichlorobenzenoneindophenol 

Sulfosalicylic  acid,  reagent 

o-Tolidine  dihydrochloride 

All  other 

5-Chloro-a,a_bis[3,5-dichloro-2-hydroxyphenyl]-o- 

toluenesulfonic  acid,  sodium  salt. 
10-Chloro-5,10-dihydrophenarsazine  (Dlphenylamine- 

chlorarsine). 
Chlorophyll  and  derivatives: 

Cp.ro  ten 

"Chlorophyll: 

Copper  fixed 

Not  fixed 

"Chlorophyllins: 

Sodium-copper 

Sodium-iron 

Sodium-magnesium 

Sodium-potassium-copper — 

Sodium-potassium-hydrogen 

Sodium-potassium-iron 

Sodium-potassium-magnesium 


133. 

515. 

2«. 

75. 

397. 

2«,   331,   338,   397,   586. 

133,   <;98. 

A6i. 

102,  357,   376,   i27. 

550. 

123. 

7,   527. 

550. 

50i. 

229. 

483. 

357. 

-448. 

550. 

333,   395. 

376,   495,   580. 

498,   527. 

498,    527. 

498,   527. 

498,   527. 

498,   527. 

498. 

498,   527,  591. 

498,   527. 

498,   527. 

498,    591. 

498,   527. 

7,    9,   498,   527,   591. 

498. 

498. 

498,    572. 

75,   498,   591. 

498,    572,   591. 

368,   498. 

101,   514. 

498. 

498. 

599. 

498,   504. 

498,    515,   572. 

504. 

498. 

515,   591. 

313. 

7,   101,   462,   498,   508,   527, 

591 

550. 

588. 
326,  588. 

326,  386. 

326. 

326. 

543,  588,  604. 

588. 

588. 

588. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


137 


TABLE  26B. -Synthetic  organic   chemicals:   Miscellaneous  chemicals   for  which  United  States  production  or  sales 
were  reported,    identified  by  manufacturer,    1953- -Continued 


MISCELLANEOUS  CHEMICALS,  CYCLIC—Continued 


Chlorophyll  and  derivatives — Continued 

Copper  ohlorin-e 

Copper  pheophytin 

Xanthophyll 

Cholesterol 

Cumene  hydroperoxide 

1,2-Cyclohexanedicart)oxylio  anhydride  (Hexahydro- 
phthalio  anhydride). 

Cyolohexanone  peroxide 

Cyolohexene-l,2-dicarboxylio  acid   (TetraJiydro- 

phthalio  acid),  disubstituted,  polyester  salts: 

Barium  salt 

Barium  cadmium  salt 

Cadmium  salt 


Cyolohexyl  phosphite 

«Cyolopropane 

Deoal^dronaphthalene  (Deoalin ) 

Diazodinitrophenol 

2,5-Di-n-butoxyaniline  ( Aminohydroquinone ,  dihutyl 
ether ) . 

p-Dibutoxybenzene  (Hydroquinone,  dibutyl  ether) 

2,5-Di-tert-butylhydroquinone 

p-(Diohlorosulfamyl)benzoic;  acid   (Halazone) 

2,5-Diethoxyaniline 

p-Diethoxybenzene 

7-Diethylamino-'i-methyloouinarin 

Dihydroxydimethoxybenzophenone 

3 , 5-Diiodosalioylic  acid 

Dilsopropylphenyl  hydroperoxide 

2,5-Dimethoxyaniline 

p-Dimethoxybenzene  (Dimethyl  ether  of  hydroquinone )  • 

o(and  p)-Dimethylaminophenol 

Dinitrosopentamethylenetetramine 

Dioxane  (1,4-Diethylene  oxide) 

Dipentene ,  hydrogenated • 

Diphenylaoetyl  chloride ■ 

Ergosterol 

Ethyl  benzoylacetate 

Ethylene  glycol  monophenyl  ether 

Ethylene  glycol  terpinyl  ether 

Ethylenethiourea- 


Manuf acturers '  Identification  numbers 
(according  to  list  in  table  27) 


Ethyl  hydrocaffeate  (Ethyl  3,4-dihydroxyhydro- 
oinnamate ) . 

Ethyl  oxanilate 

o-Ethylphenylguanidine 

Fenchone 

«Flotation  reagents: 


Dioresyldithiophosphorio  acid 

Dloresyldithiophosphoric  acid,  ammonium  salt — 

Dioresyldithiophosphorio  acid,  sodium  salt 

Di-o-tolyl thiourea 

Ros  in  amine 

Rosin  amine  D  ethylene  oxide  condensate 

«Thiocarbanilide  (Diphenyl thiourea) 

Furan.  derivatives: 

Furfural  (2-Furaldehyde) 

Furoio  acid 

Hydrofuramide 

Tetrahydrofurfuryl  alcohol 

Gallic  acid,  tsch 

Gasoline  antioxidants  and  inhibitors: 

p-Butylaminophenol 

N,N'-Dl-sec-butyl-p-phenylenediamine 

N,N'-Disalicylidene-l,2-propanedlamine 

All  other 

•■Hexamethylenetetramine,   tech 

Hydroquinone,  tert-butyl  dimethyl  ether 

8-Hydroxy-l,2-naphthimidazol  hydrochloride 

■»Lubrioatlng  oil  additives: 

Alicyclic  compounds,   sulfurized 

Alkylphenols ,  mixed 

2,6-Di-tert-butyl-p-cresol ■ 

2,2'-Dihydroxy-5,5, -di-tert-octylphenol  mono- 
sulfide,  barium  salt. 

High-molecular-«eight  hydrocarbons 

Petroleum  sulfonate,  barium  salt 

Tall  oil  ester,  sulfurized 

All  other 

p-Menthane 

p-Menthyl  hydroperoxide 

p-Methoxyphenol 


326. 

326. 

386,  588. 

558. 

222. 

527. 

357. 


A50. 

450. 

450. 

536. 

73,  231,  435,  522. 

333. 

222. 

483. 

483. 

483. 

565. 

483. 

483. 

123,  376. 

550. 

599. 

222. 

483. 

333,  483. 

75. 

333. 

392. 

338. 

281. 

99. 

463. 

392,  448. 

222. 

580. 

431. 

599. 
245. 
285. 

464. 

464. 

398. 

245,  333,  464. 

222. 

222. 

245,  464,  527. 

475. 
475. 
475. 

338,  475. 
424. 

333. 
333. 
333. 

483. 

72,  333,  387,  397,  487,  515. 

483. 

550. 

518,  560. 

323. 

258,  323,  483. 

464. 

560. 

608. 

608. 

608,  X. 

285. 

222. 

431,  483. 


313486  O  -  54  -  10 


138 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  26B. -Synthetic   organic  chemicals:    miscellaneous  chemicals    for  which  United  States  production  or  sales 
were  reported,    identified  by  manufacturer ,    i95J- -Continued 


MISCELLANEOUS  CHEMICALS,  CYCLIC— Continued 

Methyloyolohexanol 

2,2'-Methyleneti5 [-i-ehlorophenol]  (Diohlorophene ) — 
2,2'-Methylenebis[3,<i,6-triohlorophenol]  (Hexa- 
ohlorophene ) . 

2,2'-Methylenedi-p-cresol 

Methyl  glucoside 

Methyl  o-methoxybenzoate 

Methyl  terpinyl  ether 

4.-Methyl-5-thiazole-ethanol 

Methyl  toluenesulfonates 

^-i-Methylumhelliferone 

Morpholine 

»Naphthenic  acid  salts: 

Aluminum  naphthenate 

Cadmium  naphthenate 

*Caloium  naphthenate 

*Cobalt  naphthenate 

*Iron  naphthenate 

Lead-oobalt-manganese  blend 

*Lead  naphthenate 

Lithium  naphthenate 

■"Manganese  naphthenate 

Mercury  naphthenate 

Nickel  naphthenate 

Rare  earth  naphthenate 

Strontium  naphthenate 

«Zinc  naphthenate 

^Organic  mercury  compounds: 

o-Chloromercur Iphenol  ( o ,p-Hydroxyphenylmerourio 

chloride),  tech. 

Phenyl  mercuric  o-benzosulfimide 

Phenyl  mercuric  borate 

Phenyl  mercuric  chloride 

Phenyl  mercuj-ic  hydroxide 

Phenyl  mercuric  naphthenate 

Phenyl  mercuric  nitrate 

Phenyl  mercuric  salicylate 

Phenyl  mercuric  stearate 

Pyridyl  mercuric  acetate  (Acetoxymerouri- 

pyrldine ) . 

All  other 

p,p  '-Oxybis[benzenesulfonhydrazide] 

Phenol ,  sulfurated 

Phenolthiosulfonio  acid — 

Phenylmagnesiimi  bromide 

*Photographic  chemicals: 

S-Amino-ljSji-trlazole 

p-Aminophenol  oxalate,  acid  salt — 

Benzotriazole 

Catechol  (Pyrocateohin) 

Chlorobenzotriazole 

p-Diazo-N-benzyl-N-ethylaniline,  zinc  chloride 

salt. 

*p-Diaz6-N,N-diethylaniline,  zinc  chloride  salt 

p-Diazo-N,N-diethyl-m-phenetidine,  zinc  chloride 

salt. 
«p-Diazo-N,N-dimethylaniline,  zinc  chloride  salt — 

p-Diazodiphenylamine  sulfate 

»p-Diazo-N-ethyl-N-hydroxyethylaniline ,  zinc 

chloride  salt. 
p-Diazo-N-hydroxyethyl-N-methylaniline ,  zinc 

chloride  salt. 
p-Diazo-N-methyl-o-toluidine,  zinc  chloride  salt- 

N,N-Diethyl-p-phenylenedlamine  hydrochloride 

N,N-Diethyltoluene-3,4-diamine,  monohydrochloride 
2,5-Dihydroxybenzenesulfonic  acid  (Hydroquinone- 

sulfonio  acid),  sodium  salt. 
N-Ethyl-N-hydroxyethyl-p-phenylenediamine  sulfate 
N-Ethyl-N-(P-methanesulfonamidoethyl) toluene -2,5- 

diamine  sulfate. 

Hydroquinone  ( Hydroquinol ) — — — — 

N- ( Hydroxyphenyl ) glyc  ine 

"i-Methoxy-l-naphthol 

p-Methylaminophenol  sulfate  (Metol) 

5-Methylbenzotriazole 

2-Methylthiazoline 

6-Nitrobenzimidazole ™ 

"i-Phenylpyrocatechol ~ — 

Resorcinol 

All  other 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


338. 
229. 
229. 

229. 

287. 

229. 

222. 

515. 

2'i5. 

117,  123,  323. 

392,  448. 

353,  440. 

A85. 

110,  220,  314,  353,  440,  466,  485,  555,  581. 

110,  135,  220,  221,  314,  353,  440,  466,  485,  555,  581. 

314,  353,  440,  466,  485,  555,  581. 

555. 

103,  110,  135,  220,  221,  314,  353,  440,  466,  485,  555, 

581. 
485. 

110,  135,  220,  221,  314,  353,  440,  466,  485,  555,  581. 
353. 

353,  485. 
485. 
485. 
110,  135,  220,  221,  314,  353,  440,  466,  485,  555,  581. 

599. 

325. 
211. 
211. 
325. 
325. 
211. 
325. 
325. 
231. 

479. 
378. 
550. 
550. 
101. 

133. 

75. 

133,  498,  550,  599. 

323. 

133. 

133,  599. 

133,  461,  540,  550,  599. 
133,  X. 


133, 

461, 

540, 

599. 

133, 

599. 

133, 

461, 

540, 

599. 

540, 

X. 

X. 
133, 

483. 

433. 

498. 

133, 

461. 

483. 

240, 

483. 

461. 

483. 

424, 

460, 

498. 

498. 

133. 

498. 

483. 

323. 

599. 

SYNTHETIC  ORGANIC  CHEMICALS,  1953 


139 


TABLE  26B. -Synthetic  organic  chemicais:   Miscellaneous  chemicals   for  which  United  States  production  or  sales 
were   reported,    identified  by  manufacturer,    ;95J- -Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


MISCELLANEOUS  CHEMICALS,  CYCLIC— Continued 


Phthalic  acid,  lead  salt,  dibasic- 

Pinene 

Pinene  mercaptan 

Piperonyl  butoxide,  tech 

Polyethylene  terephthalate 

^-Fropiolactone 

»n-Propyl  gallate 

Pyrogallol  (Pyrogallic  acid) 

p-Quinone 

Research  chemicals: 

An  throne 

Aralljyl  chlorides  and  sulfides — 

Aryl  silanes 

Cyclopentane  derivatives- 

Guanidine  derivatives 

All  other 


*Rosin  acid  salts: 

Aluminum  resinate 

»Calclum  resinate 

Cobalt  resinate 

Copper  resinate 

Iron  resinate 

Lead  resinate 

■"Manganese  resinate 

Zinc  res  inate 

All  other 

Salicylanilide 

Salicylic  acid,  lead  salt 

Silicones: 

Methyl  silicone  fluids 

Pastes 

Sulfosalicylic  acid  and  salt 

«Tall  oil  (Linoleio-rosin  acid)  salts: 

Barium  zinc  tallate 

Calcium  tallate 

»Cobalt  tallate 

Copper  tallate 

»Iron  tallate 

»Lead  tallate 


Lead-manganese  tallate- 

«Manganese  tallate 

Zinc  glyceryl  tallate — 
Zinc  tallate 


"Tanning  materials,  synthetic: 

Bisphenol-formaldehyde,  bisulfite  type 

Cresol-formaldehyde  resin  sulfonate,  sodium  salt — 

Lignosulfonic  acid,  magnesium  salt 

Lignosulfonic  acid,  sodium  salt 

♦Naphthalene  condensates: 

1-Naphthalenesulfonic  acid,  formaldehyde 
condensate  and  salt. 
»2-Naphthalenesulfonic  acid,  formaldehyde 
condensate  and  salt. 
2-Naphtholsulfonic  acid,  formaldehyde 
condensate,  sodium  salt. 

Phenol -formaldehyde ,  sulfonated ■, 

Styrene-maleic  anhydride  interpolymer,  partial 

sodium  salt. 
Sulfonyldiphenolsulfonic  acid  formaldehyde 
condensate . 

Terpene  hydrocarbons 

1,2,3,^-Tetrahydronaphthalene   (Tetralin) 

Tetraphenyl  tin 

Textile  chemicals,  other  than  surface-active  agents: 

Diphenyl-l,2-propanediamine 

Protalbinio  acid  mixture 

Saccharide ,  bisulfite — 

Stearamide  methylpyridinium  chloride 

2,2' -Thiobis [A , 6-dichlorophenoll 

Thiophenol 

Thymol  iodide 

o-Tolylbiguanlde 

Tri-tert-aiiylphenyl  phosphite 

N-Trichloromelamine 

1,5, 5-Tr imethylhydantoin 

Trioxane 

Triphenyl  phosphite 

o-Xenylbiguanide 


371. 

395. 

333. 

'i63. 

333. 

563. 

397,  42^,  483,  591. 

231,  424. 

424,  483. 

144,  498. 
128. 

315,  334. 
101. 
464. 

101,  133,  144,  227,  334,  335,  482,  498,  514,  572, 
591,  599. 


89 

110 

89 


131,  292,  440,  581. 
,  135,  440,  581. 


110,  440,  581. 
110,  440,  581. 
395,  440,  581. 


333. 

371. 

346. 
346. 
515, 

440. 
353, 
110, 
135, 
135, 
110, 
110, 
110, 
485. 
110, 

429. 
550. 
19. 
19. 


485. 

135,  220,  314,  353,  440,  466,  485,  581. 

440. 

314,  440. 

135,  220,  314,  353,  440,  466,  485,  581. 

440,  466. 

135,  220,  314,  353,  440,  466,  485,  581. 

440. 


245,  429,  519. 

245,  429,  493,  496,  527. 


429. 


429,  493. 
245,  333. 


333. 
333. 
338. 

566. 

294. 

566. 

333. 

245. 

498,  514. 

599. 

245. 

245.- 

313. 

333. 

418. 

245,  378. 

245. 


140 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  26B. -Synthetic   organic  chemicals:    miscellaneous   chemicals    for   which  United  States  production  or   sale 
were  reported,    identified  by  manufacturer ,    JPJJ- -Continued 


Chemical 


MISCELLANEOUS  CHEMICALS,  ACYCLIC 


»Acetaldehyde 

Aoetamide 

»Acetic  acid,  synthetic,  100^- 

»Aoetic  acid  salts: 

♦Aluminum  acetate 

Aluminum  subacetate 

Ammonium  acetate 

Barium  acetate 

Cadmium  acetate 

Calcium  acetate 

Chromium  acetate 

♦Cobalt  acetate 

Copper  acetate 

Lead  acetate 

Lead  subacetate 

Lead  tetraacetate 

Magnesium  acetate 

Manganese  acetate 

Mercuric  acetate 

Nickel  acetate 

Potassitim  acetate 

Sodi\im  acetate 

Zinc  acetate 

All  other 

♦Acetic  anhydride,  100^: 

From  acetaldehyde 

From  ethylene 

From  tetene- 


From  recovered  acetic  acid  by  the  vapor-phase 

process. 
From  acetic  acid  (other  than  recovered)  by  the 
vapor-phase  process. 
Aoetin: 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


Mono- 


Di 

Tri 

♦Acetone: 

By  fermentation 

♦From  isopropyl  alcohol 

All  other 

Acetonitrile 

Acetonylacetone  (2 , 5-Hexanedione ) 

Aoetylacetone  (2,'i-Pentanedione) 

Acetyl  bromide 

Acetyl  chloride ■ 

l-Aoetyl-2-thiohydantoin 

Aconitic  acid 

Aorylamide 

Aorylate  esters,  above  ethyl 

Acrylic  acid 

Acrylic  acid,  calciiim  salt 

♦Acrylonitrile 

Acrylyl  chloride 

Adipio  ^cid 

Adiponitrile 

Aldol  ( Aoc  taldol ) 

Alkyl  hydrogen  phosphate  and  salts 

Allyl  alcohol 

Allyl  isothiooyanate ,  coram 

Aluminum  Isopropoxide  (Aluminum  isopropylate ) 
♦Amines : 

Allylamine 

♦n-Butylamine ,  mono 

tert-Butylamine 

Coconut  oil  amine — 

Diallylamine 

Di-n-butylamine 

Diethylamine- 


Diethylamine  hydrochloride 

Diethylene  glycol 

N^,N-'--Diethyl-l,'»-pentanediamine  (Novoldiamine) 

N , N-Diethyl-1 , 3-propaned  iamine 

Dilsobutylamine 

Diisopropylamine 

Dimethylamine 

Dlmethy Iamine  hydrochloride 

Dimethylamine  sulfate 

N,N-Dimethyl-l,3-propanediamine 

Dimethyloctadecylamlne  (Stearyldlmethylaraine ) 

Dlpropylamine 


216, 
50"^. 
216, 

392, 
515. 
281, 
281, 
281, 
281, 
«9, 
110, 
110, 
281, 
281, 
101. 
281, 
110, 
504. 
110, 
281, 
231, 
281, 
75. 

222. 
392. 
392. 
222, 

222, 


262, 
370, 

216, 
258, 
252, 
392. 
39;.. 
392. 
'i98. 
582. 
-198. 
ASe. 
A6A. 
-493. 
464, 
493. 
245, 
153. 
333. 
333. 
392. 
245. 
258. 
599. 
47, 

599. 

392, 
493. 


392, 
360. 
430. 
376. 
464. 
580 
580. 
245, 
360. 
493. 
464, 
493. 
580, 


222,  252,  333,  344,  367,  392,  418,  483. 

222,  252,  392,  418,  483. 

429,  464,  504,  515. 

504. 

429,  '504. 

504. 

504,  515. 

464. 

135,  281,  440. 

281,  392,  504. 

504,  521,  581. 

504,  515. 

504. 
281,  4^0. 

440. 

392,  504,  515. 
281,  392,  504,  515. 
392,  504,  515. 


418,  483. 
418,  483. 


370. 
483. 

218,  367,  463. 
392,  481,  483. 
418. 


493,  563. 
392,  464. 


483,  580. 


580. 
580. 


333,  367,  493. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


141 


TA3LE  26B.- -Synthetic  organic  chemicals:   Misceiianeous   chemicals   for   which  United  States  prockiction   or   sales 
were  reported,    identified  by  manufacturer ,    19 53 --Continued 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 


^Amines — Continued 

Dodecylamine 

Ethylamine,  mono 

Ethylenediamine 

Hexadeoylamine 

Hexamethylenediamine 

3,3  '-Iminobispropylamine 

Isobutylamlne 

Isopropylajnine 

*Methyla]iiine ,  mono 

Methylaralne ,  mono,  hydrochloride — 
1-Methylhexylamine  (2-Heptylamine)- 

Ootadeoylamine 

Octylaraine 

Polyethyleneamines — 

Propylamine ,  mono 

Propylened  iamine - 


Soybean  oil  amine- 
Tallow  amine 


Tallow  amine,  hydrogenated 

Tributy Iamine 

Trietl^flamine 

Trimethylamlne 

Trimethylamine  hydrochloride 

All  other 

2-Amino-l-butanol 

Aminoguanidine  sulfate 

2-Amino-2-(hydroxymethyl)-l,3-propanediol  (Tris- 
(hydroxyrae thyl)aminome thane) . 

2-Amino-2-methyl-l,3-propanediol 

2-Amino-2-methyl-l-propanol 

2-Amino-2-methyl-l-propyl  hydrogen  phosphate 

3-Aminopropanol 

»Aiiiyl  acetates,  90%,  primary: 

Normal : 

Isoamyl 

Mixed  isomers 

*Amyl  alcohols,  100%: 

Crude  fusel  oil 

Refined  fusel  oil 

Primary: 

Normal  (n-Butylcarbinol ) 

Active  ( 2-Methylbutanol-l ) 

Isoamyl  (3-Methylbutanol-l) 

Mixed 

Secondary: 

Pentanol-2  (Methylpropylcarbinol) 

Pentanol-3  (Diethylcarbinol) 

Mixed 

Tertiary: 

Amyl  (2-Methylbutanol-2) 

Mixed 

Amyl  ether 

Amyl  mercaptan  (1-Pentanethiol) 

Amyl  nitrate  mixt\ire 

Amyl  potassium  sodium  phosphate 

Azelaic  acid 

/3,  ff  '-Azodiisobutyronitr ile ___— 

/9,  /S'-Azobisformamide  (Azocarbonamide) 

Barium  and  zinc  salts  of  wool  grease  with  phospho- 
rus sesquisulfite. 

Behenlc  acid 

»Bis(2-chloroethyl)  ether  (Diohlorodiethyl  ether), 
all  grades. 
Bis(chloroisopropyl)  ether  (Dichloroisopropyl 
ether) . 

Bis(2-ethylhexyl)  hydrogen  phosphite 

Boron  fluoride  ethyl  ether  cong^lex 

Bromal 

N-Bromoacetamide 

o-Bromolaurio  acid 

N-Bromosuccinimide  (Succinlbromimide) 

»Butyl  acetates,  90%: 

Normal 

Iso 

Secondary- 


Manufacturers'  identification  numbers 
(according  to  list  in  tfible  27) 


Butyl  (mono)  acid  orthophosphate- 
»Butyl  alcohols,  100%: 
Primary: 

»Normal  (n-Propyloarbinol) 

Iso  (Isopropylcarbinol) 

Mixed 


23. 

392,  580. 

392. 

23. 

333. 

464. 

580. 

392,  580. 

333,  367,  493. 

360. 

442. 

23. 

23,  392,  493. 

392. 

580. 

392. 

23. 

23. 

23. 

580. 

392,  580. 

333,  367,  493. 

333. 

493. 

367. 

550. 

367. 

367. 
367. 
535. 


216,   367. 

53,  333,   414,   463. 

580. 

367. 

216,   333,  367,   463. 

580. 

333. 

367,  414,  463,   481. 

252,   580. 

580,  X. 

392. 

580. 

379,    580. 

580. 

580. 

512,   580. 

426. 

245. 

499. 

363. 

378. 

464. 

260. 

321,   392,  430,   448, 

549 

392,   448,    549,, 

312. 

440,   504. 

379. 

101. 

333. 

101,   527. 

216,  333,  367,  392,  418,  463,  483. 

418,  483. 

216,  X. 
208. 


216,  218,  252,  367,  392,  418,  463,  483. 
252,  333,  392,  414,  418,  483,  484. 
418. 


142 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  26B.- -Synthetic  organic  chemicals:   Miscellaneous  chemicals   for   which  United  States  production 
were  reported,    identified  by  manufacturer ,   i953-- Continued 


MISCELLANEOUS  CHEMICALS,  ACYCLIC—Continued 


»Butyl  alcohols,  1005^— Continued 

Secondary  (Methylethyloarbinol) 

Tertiary  (Trimethylcarbinol) 

Butylene  glycol  (1,2-  and  1,3-  mixture) 

Butyl  ether  (Di-n-butyl  ether) »■— 

2-Butyl-2-ethyl-l,3-propanediol 

tert-Butyl  hydroperoxide 

Butyl  lactate 

tert-Butyl  peroxide  (Di-tert-butyl  peroxide  )- 

tert-Butyl  peroxyacetate 

Butyraldehyde 

Butyraldehyde  oxime 

Butyric  acid- 


Butyric  acid,  sodiijiii  salt 

Butyric  anhydride 

Butyryl  chloride 

Capric  acid  (n-Decylie  acid) 

Caproio  acid 

Caprolaotam  (2-Oxohexamethyleniiiiine)- 
Capryl  chloride  (Decanoyl  chloride)— 

Caprylic  acid  (Octanoic  acid) 

«Caprylic  acid  salts: 

Aluminum  caprylate 

Sodium  caprylate- 


Triethanolamine  trioaprylate 

Zinc  caprylate 

«Carbon  disulfide 

^Cellulose  esters: 

^Cellulose  acetate 

Cellulose  acetate  butyrate 

Cellulose  acetate  propionate 

Cellulose  nitrate 

«Cellulose  ethers: 

Ethyl  cellulose 

Methyl  cellulose 

»Sodium  carboxymethylcellulose ,  100^ 

Sodium  carboxymethylhydroxyethylcellulose 

"Chloral  (Trichloroacetaldehyde ) 

Chloroacetaldehyde  dimethyl  acetal 

*Chloroacetic  acid,  mono 

Chloroacetic  acid,  mono,  derivatives: 

Butyl  monochloroaoetate 

Ethyl  monochloroacetate 

Methyl  monochloroaoetate 

Sodium  monochloroacetate 

Chloroacetone  (l-Chloro-2-propanone) 

Chloroacetyl  chloride 

Chlorodiethoxymethylsilane 

2-Chloroethyl  acetate 

2-Chloroethyl  methyl  ether  (2-Chloroethoxymethane)- 

Chloromaleic  anhydride,  mono 

Chloromethyl  methyl  ether 

Chloromethylsilanes 

^-Chloropropionyl  chloride 

N-Chlorosuccinimide  (Succinichlorimide) 

Chlorotrimethylsilane 

Citric  acid,  by  fermentation,  refined 

«Citric  acid  salts: 

Ammonium  citrate 

Ammonium  dihydrogen  citrate 

Barium  citrate 

Calcium  citrate 

Ferrous  calcium  citrate 

Iron  citrate 

Iron  ammonium  citrate 

Potassium  citrate 

Sodium  citrate 

Coconut  fatty  acid  amide 

Coconut  and  tallow  fatty  acyl  chloride 

Cottonseed  oil,  diethylenetriamine,  acetate 

Crotonaldehyde 

a-Cyanoaoetamide 

Cyanoacetic  acid 

Cyanuric  acid 

Decane 

Diacetone  alcohol  (A-Hydroxy-A-methyl-2-pentanone) 

2-Dibutylaminoethanol 

Dibutyl  hydrogen  phosphite 

l,3-Dibutyl-2-thlourea 

Dibutyl  tin  methoxide 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


258,  X. 
258. 

as. 

392. 

57^. 

258,  357. 

367. 

258,  357. 

357. 

392,  483,  484. 

527. 

252,  392,  483. 

266. 

392,  483. 

338. 

108. 

392,  582. 

333. 

338. 

108. 

360,  421,  566. 

360. 

550. 

281,  360,  566. 

166,  182,  190,  200,  217,  345,  448. 

50,  222,  333,  418,  483. 

483. 

483. 

222,  333. 

222,  448. 

448. 

222,  264,  333,  549. 

222. 

333,  345,  390. 

550. 

222,  245,  264,  338,  343,  448. 

245. 

245,  448. 

266,  448. 

448. 

498. 

448. 

315. 

431. 

412. 

527. 

338,  493. 

346. 

498. 

101,  527. 

315. 

415. 

231,  515. 

515. 

521. 

415. 

281. 

231,  415. 

231,  415. 

415,  515. 

415,  515. 

23. 

550. 

464. 

392,  483. 

266. 

266,  343,  394,  448. 

498. 

551. 

258,  392. 

580. 

312. 

580. 

X. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


143 


TABLE  26B. -Synthetic  organic  chemicals:    Miscellaneous  chemicals   for  which  United  States  production  or  sales 
were  reported,    identified  by  manufacturer ,    J95J- -Continued 


MISCELLANEOUS  CHEMICALS,  ACYCLIC—Continued 

Dichloroacetaldehyde 

Diohloroacetio  acid 

Diohloroacetic  acid,  methyl  ester 

Dichloroacetyl  chloride — 

Dichlorodiethylsllane :- 

Diohlorodimethylsilane  (Dimethyl  silicon 

dichloride) . 
Diohloroethyl  formal  (Bis(2-chloroethoxy)methane) — 

Did ,  2-epoxypropane )  amine 

Diethoxydimethylsilane 

2-Diethylaminoethanol 

Diethylaminopropionitrlle 

Diethyl  aniylethylmalonate  (n-Amyl  ethyl  malonic 

ester) . 

Diethyl  butylethylmalonates 

Diethyl  carbonate 

Diethyl  diethylmalonate  (Diethyl  malonio  ester) 

»Diethylene  glycol 

Diethylene  glycol  chloroformate 

Diethylene  glycol  diethyl  ether  (Bis(2-ethoKyethyl) 

ether). 
Diethylene  glycol  monobutyl  ether  (2-(2-Butoxyeth- 

oxy)ethanol). 
Diethylene  glycol  monobutyl  ether  acetate  (2-(2-Bu- 

toxyethoxy)ethyl  acetate). 
Diethylene  glycol  monoethyl  ether  (Carbitol) 

(2-(2-Ethoxyethoxy)ethanol) . 
Diethylene  glycol  monoethyl  ether  acetate  (2-(2-Eth- 

oxyethoxy) ethyl  acetate). 
Diethylene  glycol  monomethyl  ether  (2-(2-Methoxy- 

ethoxy)ethanol) . 

Diethyl  ethylisoamylmalonate 

Diethyl  ethylraalonate  (Ethyl  malonic  ester) 

Diethyl  hydrogen  phosphite 

Dietlyrlhydroxylamine  oxalate 

Diethyl  isopropylmalonate 

Diethyl  maleate- 


^Diethyl  malonate  (Malonic  ester) 

Diethyl  1-methylbutylmalonate 

Diethyl  oxalate  (Ethyl  oxalate) 

l,3-Diethyl-2-thiourea 

Diglyoolic  acid 

a,a-Dihydroxy-^,«-dimethylbutyrio  acid,  sodium  salt 
' (Sodium  3,3-dimethyl-2,4-dihydroxybutyrate) . 

Dihydroxytartaric  acid 

Diisobutyl  ketone  ( Isovalerone ) 

Diisopropyl  peroxydicarbonate  (Isopropyl  peroar- 
bonate ) . 

l,3-Diisopropyl-2-thiourea 

Dimethyl  acid  pyrophosphate 

»2 -Dime thy laminoethanol 

Dimethylaminopropionitrile 

NjN-Dlmethylformamide 

Dimethylglyoxime 

Dimethylglyoxtme ,  sodium  salt 

Dimethyl  hydrogen  phosphite 

1 , 1-Dimethylurea 

1,3-Dimethylurea 

Dioleyl  maleate- 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


»Dipropylene  glycol 

Dipropylene  glycol  methyl  ether 

Dithiooarbamates,  not  listed  under  specified  use 

classifications . 
Dithiophosphoric  acid  esters,  not  listed  under 
specified  use  classifications: 

Barium  di(hexyl,  lauryl)  dithiophosphate 

Zinc  dihexyl  dithiophosphate 

l-Dodeoene 

Dodecylsuccinlo  anhydride 

Epichlorohydrin 

Eruoic  acid 


Ethanesulfonic  acid 

»Ethanolamtnes : 

<<Mono  (2-Aminoethanol) 

»Di  (2,2  '-Aminodiethanol) 

«Trl  ( 2 , 2 ' , 2 '  '-Nitr ilotriethanol ) 

Ethanolamine  (mono)  hydrochloride 

Ethanolamine  (mono)  salt  with  formaldehyde- 

Ethanolamlne  residue 

Ethoxymethylene  malonio  ester 

fl-Ethoxypropionitrile 

"Ethyl  acetate,  S5% 


345. 
266. 
266. 
266. 
315. 
315. 

392. 

333. 

315. 

392,  580. 

464. 

442. 

565. 

463. 

442,  565. 

321,  392,  430,  448,  549. 

391. 

392. 

392. 


442. 
565. 


464. 

394,  442,  448,  565. 

442,  565. 

463. 


392. 

394, 

442, 

312. 

498. 

X.' 

392, 

266, 

394, 

367, 

580. 

333. 

442. 

464. 
392. 
391. 


580. 

208. 

392,  493,  580. 

338. 

333,  493. 

498. 

281. 

312. 

343. 

580. 

245. 

321,  392,  418,  448,  549. 

448. 

563. 


464. 
464. 
551. 
527. 
258. 
260. 
560. 

231,  321,  392,  448. 

321,  392,  448. 

321,  392,  448. 

566. 

493. 

321. 

266. 

464. 

216,  249,  252,  333,  367,  392,  463,  483. 


144 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  26B. -Synthetic  organic  chemicals:   Miscellaneous  chemicals   for  which  United  States  production   or  sales 
were  reported,    identified  by  manufacturer,    i953--Continued 


MISCELLANEOUS  CHiWICALS,  ACYCLIC— Continued 


Ethyl  aoetoaoetate 

Ethyl  acrylate 

»Ethyl  alcohol,  synthetic 

2-Ethylajiiinoethanol  (Ethylmonoethanolamine) 

Ethyl  ammonium  phosphate 

Ethyl  bromoaoetate  (Ethyl  monobromoacetate) — 

2-Ethyl-l-butanol  (sec-Hexyl  alcohol) 

a-Ethylbutyraldehyde • 

a-Ethylbutyric  acid  (Diethylacetic  acid) 

a-Ethylcaproaldehyde  (2-Ethylhexaldehyde) 

a-Ethylcaproic  acid  (2-Ethyl-l-hexoic  acid) — 
*a^Ethylcaproic  (2-Ethyl-l-hexoic)  acid  salts: 

Aluminum  a  -ethylcaproate 

*Calcium  ii -ethylcaproate 

■ifCobalt  a  -ethylcaproate 

Iron  a -ethylcaproate 

*Lead  a-ethylcaproate 

Manganese  a-ethyloaproate 

»Zinc  a-ethylcaproate 

Zirconium  a-ethylcaproate 

a-Ethylcapryl  acetate 

Ethyl  chloroformate 

Ethyl  cyanoacetate- 


Manuf acturers '  identification  numbers 
(according  to  list  in  table  27) 


Ethyldiethanolamine  (2,2'-(Ethylimino)diethanol) 

Ethylene,  from  ethyl  alcohol 

Ethylene  chlorohydrin  (2-Chloroethanol) 

Ethylene  cyanhydrin  (Hydracrylonitrile) 

^Ethylene  glycol 

Ethylene  glycol  diformate 

Ethylene  glycol  dimethyl  ether 

Ethylene  glycol  monobutyl  ether  (2-Butoxyethanol) — 
Ethylene  glycol  monoethyl  ether  (Cellosolve) 

(2-Ethoxyethanol) . 
Ethylene  glycol  monoethyl  ether  acetate  (2-Ethoxy- 

ethyl  acetate ) . 
Ethylene  glycol  monomethyl  ether  (2-Methoxyethanol) 
Ethylene  glycol  monomethyl  ether  acetate 
( 2-Methoxyethyl  acetate). 

^Ethylene  oxide — 

*Ethyl  ether: 

»Tech 

*U . S . P 

^Absolute 

Ethyl  ,3-ethoxypropionate ■ 

wEtlqrl  formate 

N-Ethylglycine 

2-Ethyl-l,3-hexanediol 

2-Ethyl-l-hexanol- 


Ethyl  a-hydroxyisobutyrate 

Ethyl  a-hydroxyisovalerate 

Ethyl  lactate 

Ethyl  magnesium  bromide 

2-(Ethylmercapto)ethanol 

Ethyl  (mono)  orthophosphate 

Ethyl  potassium  sodium  phosphate- 
Ethyl  propionate 

Ethyl  silicate 

Ethyl  stearoylacetate- 


Ethyl  sulfate  (Diethyl  sulfate) 

2-Ethynyl-2-butanol 

Fats  and  oils,  chemically  modified: 

Castor  oil,  acetylated 

Castor  oil,  dehydrated 

Castor  oil,  hydrogenated 

Fish  oil,  hydrogenated 

Soybean  oil,  hydiogenated 

Sperm  oil,  hydrogenated 

Tallow ,  hydrogenated 

Vegetable  oils,  bromlnated 

All  other 

Fatty  acids,  chemically  modified: 

Bromo  fatty  acids 

Castor  oil  fatty  acids,  dehydrated 

Stearic  acid,  dehydrated 

»Fatty  acid  esters,  not  Included  with  plasticizers: 

Butyl  palmitate 

Ethylene  glycol  mono-oleate 

^-Hydroxyetliyl  ester  of  tall  oil 

Isopropyl  myristate 

Isopropyl  oleate 


392,  A63. 

392,  <193. 

222,  252,  258, 

333, 

392,  481, 

580. 

245. 

448. 

392,  483. 

392. 

392. 

392,  484. 

392. 

314. 

314,  440,  485, 

581. 

314,  440,  485, 

581. 

440,  581. 

314,  371,  440, 

485, 

581. 

440,  485,  581. 

314,  440,  485, 

581. 

485. 

392. 

463. 

266,  394,  448. 

580. 

323,  435,  463. 

392,  412. 

338,  464,  493. 

321,  333,  392, 

430, 

448,  549 

392. 

101. 

321,  392. 

392. 

392. 

321,  392,  448. 

392. 

321,  392,  430, 

448. 

222,  323,  392, 

481 

484,  592 

231,  463,  522. 

463. 

493. 

367,  392,  414, 

508 

582. 

464. 

392. 

392,  483,  484 

493. 

493. 

464. 

101. 

580. 

208. 

245. 

53,  414,  582. 

315,  392. 

X. 

392. 

372. 

219. 

219. 

260. 

260. 

260. 

260. 

260. 

302. 

123,  131,  314 

333,  510. 

219. 

493. 

370,  421. 

177,  342. 

245. 

229,  370,  541 

370. 

SYNTHETIC  ORGANIC  CHEMICALS,  1953 


145 


TABLE  26B. --Syntheti 


organic  chemica 
were  reporte 


Miscellaneous  chemicals   for  which  United  States  producti 
ident i fied  by  manufacturer ,   295J-'Continued 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

■»Fatty  acid  esters,  not  included  with  plasticizers- 
Continued 

Isopropyl  palmitate 

Isopropyl  stearate 

Methyl  caproate 

Methyl  ester  of  coconut  oil 

Methyl  myristate 

Methyl  palmitate 

Methyl  tallow 

Pentaerythritol  tall  oil  ester 

Polyethoxyethyl  castor  oil  ether 

Polyethoxyethyl  castor  oil  ether,  hydrogenated— 

Polyethylene  glycol  stearate  (wax) 

Polyoxyalkylene  linseed  dimer  ester 

1,2-Propylene  glycol  dioleate 

Propylene  glycol  stearate 

All  other 

*Fatty  and  synthetic  higher  alcohols  (Cio  ^^^ 
higher) : 

Decyl  alcohol 

3,9-Diethyl-6-trldecanol ■ 

Dodecyl  alcohol  (Lauryl  alcohol) 

7-Ethyl-2-methyl-'i-hendecanol 

5-Ethyl-2-nonanol 

1-Hexadecanol  (Cetyl  alcohol) 

1-Ootadecanol  (Stearyl  alconol) 

ois-9-Octadecen-l-ol  (Oleyl  alcohol) 

1-Tetradecanol 

1-Trideoanol 

All  other 

»Flotation  reagents: 
Dithiophosphates : 

Ajumonium  di-sec-butyl  dithiophosphate 

Ammonium  diisopropyl  dithiophosphate 

Potassium  dihexyl  dithiophosphate 

Potassium  diisopropyl  dithiophosphate 

Sodium  di-sec-butyl  diethyl  dithiophosphate — 

Sodium  diethyl  dithiophosphate 

Sodium  dihexyl  dithiophosphate 

Sodium  diisopropyl  dithiophosphate 

Fatty  amine  salts: 

Butylammonium  oleate 

Coconut  oil  amine  acetate 

Octadecylamine  acetate 

Soybean  amine  acetate 

Tallow  amine  acetate 

Tallow  amine  acetate,  hydrogenated ■ 

Octyl  isocyanate 

Quaternary  ammonium  compounds 

Xanthates : 

Potassium  amylxanthate 

Potassium  sec-butylxanthate 

Potassium  ethylxanthate 

Potassium  isopropylxanthate 

Potassium  pentasolamylxanthate 

Sodium  n-butylxanthate 

Sodium  sec-butylxanthate 

Sodium  ethylxanthate 

Sodium  isopropylxanthate 

•Formaldehyde,  37%  HCHO  by  weight 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


Formamide 

•Formic  acid,  90% 

•Formic  acid  salts: 

Aluminum  formate 

Ammonium  formate 

Chromic  formate 

Lead  formate 

Magnesium  formate 

Nickel  formate 

Potassium  formate 

•Sodium  formate,  crude 

•Sodium  formate,  refined — 

All  other 

Formyl  acetone  dimethyl  acetal 

•Fumaric  acid 

Fumaryl  chloride 

Gases  (poisonous,  tear,  etc.):  Phosgene  (Carbonyl 
chloride) . 

Gluconic  acid,  tech 

Glycerol ,  synthetic 


229,  370. 

370. 

108. 

108. 

108. 

108. 

421. 

«1. 

417. 

417. 

421. 

417. 

438. 

417. 

108. 

333,   481,   551. 

392. 

276,   333,   551. 

392. 

392. 

86,   260,   333,    551. 

260,   333,    551. 

333. 

551. 

481. 

333,   493,   551. 

y 

464. 

464. 

464. 

464. 

464. 

464. 

464. 

464. 

580. 

23. 

23,  464. 

23. 

23. 

23. 

245. 

566. 

448,  464. 

448. 

448. 

448. 

448.     ■ 

36. 

464. 

44S,  464. 

448,   464. 

72,   245,   266,   286,   333,   344,   367,  387,   397,   418,   449 

493,   515,   596. 

333. 

208,   231,  333,   397. 

75,   208,   342,   392,   429. 

75,    504. 

550. 

371. 

360. 

110,   440. 

360,  379. 

208,   222,   397,    515. 

281,   504,    515. 

75. 

266. 

245,  464,   527. 

527. 

391. 

415. 

258. 

146 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  26B. --Synt/iefic  organic  chemicals:    Hiscellaneous  chemicals   for  which  United  States  production   or  sales 
were  reported,    identified  by  manufacturer ,    1955- -Continued 


Chemical 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

Glycerol  a-chlorohydrin  (3-Chloro-l,2-propanediol)- 
Glyoerol  dichlorohydrin  (l,3-Dichloro-2-propanol)  — 

Glycine  (Aminoaoetic  acid),  tech 

Glycine  ethyl  ester  hydrochloride 

Glycolic  acid  (Hydroxyacetic  acid) 

Glyoolonitrile 

Glyoxal 

Guanidine  hydrochloride 

Guanidine  stearate- 


i-Guanyl-l-isonitrosoguanyl-l-tetrazene 

*Halogenated  hydrocarbons : 

l-Bromobutane  (n-Butyl  bromide ) 

2-Bromobutane  (sec-Butyl  bromide) 

l-Bromo-2-chloroethane  (Ethylene  chlorobromide ) — 

Bromochlororae thane 

l-Bromo-3-chloropropane  (Trimethylene  chloro- 
bromide ) . 
1-Bromodecane- 
Bromoethane  (Ethyl  bromide )- 
l-Bromohexadecane  (Cetyl  bromide ) - 
l-Bromo-2-methylpropane  (isobutyl  bromide ) - 
Bromo-octadecane- 

1-Bromopentane  (n-Amyl  bromide) 

2-Bromopentane  ( 1-Methylbutyl  bromide )- 

l-Bromopropane  (n-Propyl  bromide) 

2-Bromopropane  (Isopropyl  bromide) 

3-Bromopropene  (Allyl  bromide) 

3-Bromo-l-propine 

Bromotr if luorome thane 

»Carbon  tetrachloride 

^Chlorinated  paraffins: 

Less  than  35%  chlorine 

35%-6A%   chlorine 

65%   or  more  chlorine- 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


1-Chlorobutane  (n-Butyl  chloride) 

l-Chloro-l,l-d  if  luoroe  thane 

Chlorod if luorome thane 

«Chloroethane  (Ethyl  chloride): 

Tech ■ 

U.S.P 

*Chloroethylene  (Vinyl  chloride  monomer) 

«Chloroform: 

Tech 

U.S.P 

*Chloromethane  (Methyl  chloride): 

Crude 

Refined,  refrigerant  grade 

l-Chloro-3-methylbutane  (Isoamyl  chloride) 

2-Chloro-2-iiiethylpropane  (tert-Butyl  chloride) 

1-Chloropentane  (n-Amyl  chloride) 

Chloropentanes  (Amyl  chlorides),  mixed 

1-Chloropropane  (n-Propyl  chloride) 

2-Chloropropane  (Isopropyl  chloride) 

3-Chloropropene  (Allyl  chloride) 

Chlorotrifluoroethylene 

Chlorotrlf luorome thane 

Dibromodif luorome thane 

1,2-Dibromoethane  (Ethylene  dibromide) 

Dibromomethape  (Methylene  bromide) 

1,'^-Dibromopentane 

1,3-Dibromopropane  (Trimethylene  dibromide) 

1,'^-Dlchlorobutane 

Dichlorodlf luorome thane 

*1,2-Dichloroethane  (Ethylene  diohloride) 

Dichlorofluoromethane 

»Dlchlororaethane  (Methylene  chloride): 

Crude 

Refined,  refrigerant  grade 

Dichloropentanes ,  mixed 

1,2-Dlchloropropane  (Propylene  dichloride) 

Dichlorotetrafluoroe thane 

1 , 1-Difluoroe thane 

1 , 1-Dlf luoroethylene 

Hexachlorobutadlene 

He  xachloroe  thane 

lodoethane  (Ethyl  Iodide),  tech 

Iodoform 

lodoroethane  (Methyl  iodide),  tech 

PentachloroS thane 

1,1,2,2-Tetrabromoethane  (Acetylene  tetrabromlde ) 


Ol, 

483,  498. 

498. 

343. 

343. 

333. 

464, 

493. 

392. 

426, 

519. 

426. 

X. 

448, 

512. 

442, 

448,  512,  X. 

345. 

181, 

359. 

73,  448. 

333. 

181, 

394,  448. 

448, 

512. 

448, 

512. 

333, 

512,  550. 

448, 

498,  512. 

442, 

498,  565. 

44S, 

512. 

448, 

X. 

448, 

512. 

550. 

333. 

217, 

242,  321,  345,  44S,  464. 

338, 

X. 

222, 

242,  338,  487. 

242. 

392, 

574. 

504. 

333, 

504. 

222, 

333,  426,  448. 

258, 

448. 

242, 

245,  354,  378,  392,  448,  563 

121, 

169,  333,  448. 

121, 

169,  448. 

v-^. 

346. 

vt. 

121,  333,  448. 

442, 

512. 

498, 

512. 

338, 

442,  512,  580. 

580. 

512. 

448. 

258. 

333. 

333. 

333 

345 

359,  448,  603. 

448 

498. 

431 

448 

512. 

333 

333 

504. 

242 

245,  321,  392,  426,  430,  448 

333 

121 

448. 

121 

333,  448. 

580 

392 

448,  549. 

333 

504 

504 

338 

591 

498 

,  512. 

233 

512 

,  599. 

333 
448 

SYNTHETIC  ORGANIC  CHEMICALS,  1953 


147 


TA3U.  26B.- -Synthetic  organic  chemicals:   Miscellaneous  chemicals  for  which  United  States  production  or   sales 
were  reported,    identified  by  manufacturer,    /953- -Continued 


MISCELLANEOUS  CHEMICALS,  ACYCLIC—Continued 

*Halogenated  hydrocarbons — Continued 

1,1,2,2-Tetrachloroethane  (Acetylene  tetra- 
chloride). 

«Tetrachloroethylene  (Perohloroethylene ) 

1,1,1-Triohloroethane  (Methyl  chloroform) 

1,1,2-Triohloroethane  (Vinyl  trichloride) 

»Trichloroethylene 

Triohlorofluorome thane 

1 , 2 ,3-Triohloropropane 

Trichlorotrifluoroe  thane 

Vinylldene  chloride,  monomer 

All  other  halogenated  hydrocarbons 

2-Heptanone  (Methyl  amyl  ketone) 

n-Hexadeoane. 

1-Hexadeoene 

Hexamethyldisiloxane 

Hexamethylenediammonium  adipate 

2,5-Hexanedione  (Acetonylaoetone )  carbon  disulfide 

Hexyl  alcohol 

n-Hexyl  ether r 

Hydrazine  and  salts — ■ 

Hydrogenated  tallow  amide 

a-HJrdroxyisobutyrates,  above  ethyl 

a-Hydroxyisobutyronitrile  (Acetone  cyanhydrin) 

2- (Hydroxymethyl ) -2-nitro-l ,3-propanediol  (Tris (hy- 

droxymethyl)nltromethane ) . 
N-Hydroxymethylstearamide  ( N-Methylolstearamide ) — 

.8,,9'-Iminodipropionitrile 

Inositol  hexanitrate 

Isethionlo  acid  (2-Hydroxyethanesulfonio  acid) 

. Isoamyl  octyl  orthophosphate 

Isoamyl  (mono)  orthophosphate 

Isobutyraldehyde ~ 

Isobutyraldehyde  lactone 

Isobutyric  acid 

Isobutyrio  anhydride 

Iso-ootyl  alcohol  (6-Methyl-l-heptanol) 

Iso-octyl  thioglyoolate 

Isopropanolamines : 

Monoisopropanolamine 

Diisopropanolamine 

Triisopropanolamine 

Mixed 

Isopropoxypropionitrlle 

Isopropyl  acetate 

»Isopropyl  alcohol  ( Isopropanol ) ,  100^ 

2-Isopropylaminoethanol 

Isopropyl  ohloroformate 

*Isopropyl  ether 

»Lactic  acid,  lOOiS: 

»Edible 

wMedioinal 

^Technical- 

Lactic -acid  salts: 

Calcium  lactate 

Ferrous  lactate 

*Sodium  lactate 

Strontium  lactate 

All  other 

Lactide 

Laotonitrile 

Laurie  acid 

Lauroyl  chloride: 

Crude 

Refined 

Lauroyloxyacetio  acid 

Lauroyl  peroxide 

N-Lauroylsaroosin,  sodium  salt 

Lead  soaps  from  oxidized  hydrocarbons 

Levulinic  acid 

»Linoleic  acid  salts: 

Ammonium  linoleate 

«Caloium  linoleate 

"Cobalt  linoleate 

Iron  linoleate ; 

Lead  linoleate 

Lead  manganese  linoleate 

•Manganese  linoleate 

•Lubricating  oil  additives: 

Allsyl  phosphate  esters 

Barium  alkyl  dithlophosphate 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


2« 

333 

337 

391,  448. 

445. 

392. 

145 

333 

337 

448. 

333 

504 

258. 

333. 

448. 

321, 

512 

549 

392. 

333 

551 

551. 

315. 

333. 

281. 

392. 

392. 

133. 

23. 

493. 

333, 

464 

493. 

367. 

333. 

464. 

417. 

550. 

208. 

208. 

4S4. 

464. 

483. 

483. 

209, 

481. 

147. 

392, 

448. 

392. 

392. 

392. 

464. 

333, 

367, 

392, 

483. 

252, 

258, 

392, 

481,  X. 

580. 

391, 

463. 

258, 

392, 

481. 

201, 

235, 

333, 

539. 

333. 

201, 

235, 

333, 

539. 

235, 

539. 

281. 

376, 

515, 

539, 

566. 

231. 

75. 

201. 

464. 

108. 

333, 

541, 

550. 

333, 

338, 

550, 

574. 

518. 

102, 

357. 

X. 

270. 

360. 

135, 

581. 

131, 

135, 

164, 

485,  581. 

110, 

131, 

135, 

376,  440,  581 

440. 

135, 

376, 

440, 

581. 

376, 

581. 

131, 

135, 

440, 

581. 

148 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  26B.- -Synthetic  organic  chemicals:    tliscellaneous  chemicals   for  which  United  States  production  or 
were  reported,    identified  by  manufacturer,    /95J- -Cent  imied 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

^Lubricating  oil  additives — Continued 

Chioronaphtha  xanthate 

Octyl  formaldehyde 

Oxidized  hydrocarbons 

Phosphorous  derivatives  of  high-molecular-ueight 

hydrocarbons. 
Polymethacrylates ,  diethylaminoethyl  and  lauryl, 
mixed. 

Zinc  alkyl  dithiophosphate 

All  other 

Haleic  acid 

Maleic  acid,  lead  salt,  tribasic 

Maleic  anhydride 

Malic  acid 

Malonic  acid 

Mannitol 

Mannitol  hexaacetate 

Mannitol  hexanitrate 

Mesityl  oxide 

Methacrylamide 

Methacrylates,  above  methyl 

Me  thacryl ic  ac  id 

•Methanol,  synthetic 

2-(Methoxyinethoxy)ethanol 

3-Methoxypropionitrile 

3-Methoxypropylamine 

Methoxytriglycol  acetate 

Methyl  acetate 

Methyl  acetone  acetal 

Methyl  acrylate,  monomer 

Methylal  (Dimethoxymethane) 

Methyl  cyanoacetate 

N,N'-Methylenebis[  iminopropionic  acid] 

N , N '-Methylenebis ( stearamide ) 

Methylene  citric  acid 

Methyl  ether  (Dimethyl  ether) 

Methyl  ethyl  ketone  (2-Butanone) 

Methyl  ethyl  ketone  peroxide 

Methyl  ethyl  ketoxime  (2-Butanone  oxime) 

Methyl  formate 

Methyl  glycolate  (Methyl  hydroxyacetate) 

■4-Methyl-2-hexanone 

1-Methylisobutylcarbinol  ( ■4-Methyl-2-pentanol ) 

1-Methylisobutylcarbinyl  acetate  (•4-Methyl-2-amyl 
acetate ) . 

Methyl  lactate 

Methyl  magnesivim  bromide 

Methyl  methacrylate,  monomer 

2-Methyl-2-nitro-l,3-propanediol 

2-Methyl-2-nitro-l-propanol 

Methylolurea,  mono  (Hydroxymethylurea) 

2-Methyl-2,'i-pentanediol  (Hexylene  glycol) 

4-Methyl-2-pentanone  (Methyl  isobutyl  ketone) 

Methyl  polyethanolamine 

Methyl  sulfate  (Dimethyl  sulfate) 

N-Methyl taurine 

Methyl trlethoxysilane 

Methyl  vinyl  ether 

Mucochloric  acid - — 

Myristic  acid 

Nitroe  thane -__ 

Nitrome thane 


l-Nitropropane 

2-Nitropropane 

Nylon  (Polyhexamethylene  adipamlde)- 

1-Octanol 

2-Octanol 


2-Octanone  (Hexyl  methyl  ketone) 

Ootene 

Octyl  (mono)  hydrogen  orthophosphate 

Octylamlde — 


Octyl  mercaptan 

Octyl  oleyl  maleate 

Oleamide  (Octadecene  amide )- 
•Oleic  acid  salts: 

Aluminum  oleate 

Barium  zinc  oleate 

Calcium  hydroxyoleate 

Chromium  oleate 

Copper  oleate 

•Lead  oleate 


2-^5. 
258. 

270. 
560. 

333. 


338,  X. 

442,  527 

536,  558 

371. 

245,  392 

527. 

464,  527 

558. 

176,  468 

417. 

417. 

417. 

258,  392 

493. 

333,  493 

333,  493 

72,  252, 

267,  286, 

333. 

464. 

464. 

392. 

296,  392, 

X. 

344. 

493. 

418. 

266,  448. 

559. 

23. 

379. 

333. 

252,  258, 

392,  X. 

102,  357. 

527. 

333. 

333. 

442. 

258,  392. 

333,  392. 

201. 

101. 

41,  333, 

493. 

367. 

367. 

333. 

258,  392. 

258,  392. 

550. 

333. 

550. 

315. 

550. 

498. 

108. 

367. 

367. 

367. 

367. 

333. 

333,  551, 

582. 

86,  493. 

493,  536. 

493. 

208. 

23. 

551. 

245. 

23. 

135,  314, 

421,  581. 

440. 

421. 

440. 

135,  440, 

581. 

135,  314, 

440,  581. 

TABLE  26B. --Synthetic  orga 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 

emicals:    Miscelimteous  chemicals    for   which  United  States  production  or 
were  reported,    identified  by   manufacturer ,    J95J- -Continued 


149 


MISCELLANEOUS  CHB1ICALS,  ACYCLIC— Continued 


Oleoyl  chloride 

»Oxalic  acid 

•Oxalic  acid  salts: 

Ammonium  oxalate 

Calcium  oxalate 

Ferric  ammonium  oxalate — 

Ferric  oxalate 

Ferric  potassiiun  oxalate- 

Ferric  sodium  oxalate 

Ferrous  oxalate 

Potassium  binoxalate 

Potassium  oxalate 

Sodium  oxalate 

All  other 

Oxamide — 


Oxidized  "nydrocarbons  other  than  lubricating  oil 

additives. 
Palmitic  acid  salts: 

Aluminum  palmitate 

Zinc  palmitate 

»Palmitoyl  chloride 

Paraformaldehyde 

Paraldehyde  ( Paracetaldehyde ) 

Pelargonic  acid  (Nonanoie  acid) 

*Pentaerythritol 

»Pentaerythritol  tetranitrate 

Pentanediol 

2-Pentanone  (Methyl  propyl  ketone) 

Phytic  acid,  calcium  salt 

Phj-tol 

Pine  oil,  synthetic 

Polyacrylic  acid,  potassium  salt 

Polyacrylic  acid,  sodium  salt 

Polyacrylonitrile 

Polyacrylonitrile,  hydrolyzed,  sodium  salt 
(non-soil-conditioner) . 

Polyethoxyethyl  sorbitol 

Polyethylene  glycol 

Polyglycerol 

Polyoxyalkylene  derivatives,  miscellaneous 

Polyoxyalkylene  glucose 

Polypropylene  glycol 

Propionaldehyde 

•"Propionic  acid 

Propionic  acid  salts: 

Cadmium  propionate 

Calcium  propionate 

Sodium  propio/'^te 

Zinc  propionate 

Propionic  anhydride 

Propionyl  chloride 

n-Propyl  acetate 

n-Propyl  alcohol  (Propanol) 

Propylene,  from  coke-oven  gas 

a-Propylene  chlorohydrin  (l-Chloro-2 -propanol) — 

•Propylene  glycol  (1,2-Propanediol) 

Propylene  glycol  dipropionate 

Propylene  glycol  glycolate 

Propylene  glycol  methyl  ether 

Propylene  glycols,  methyl  ethers,  mixtures 

Propylene  oxide 

Propyl  isobutylaoetate 

Propyl  mercaptan  (l-Propanethicl ) 

Pyruvic  acid 

Rare  sugars 

Research  chemicals: 

Bronentin 

Creatine  and  creatinine 

Halogen  compounds 

Hydrocarbons 

Phosphonaxes 

Silanes 


Manufacturers'  identification  numberc 
(according  to  list  in  table  27) 


Sulfur  eoT-  ..:r:ds 

All  other 

Ricinoleic  acid  salts: 
Aljminum  ricinoleate — 

Barium  ricinoleate 

Cadmium  ricinoleate 

Calcium  ricinoleate 

Sodium  ricinoleate 


86,  535,  550,  566,  575. 
185,  208,  -415,  504. 

231,  281,  415,  504. 

208. 

415. 

415. 

415. 

415. 

599. 

281,  504,  515. 

281,  504. 

208,  231,  281,  415,  504,  515. 

75. 

504. 

270. 


164,  421. 

164,  314,  421,  464. 

153,  550,  582. 

333,  344,  397,  418. 

392. 

229,  499. 

142,  222,  309,  367,  397. 

222,  309,  333. 

333. 

252. 


588. 

,.- 

222. 

563. 

529, 

563. 

333. 

364. 

417. 

321, 

392, 

448. 

245, 

396, 

X. 

44.8. 

417. 

392, 

448. 

252. 

252, 

333, 

418, 

483. 

504. 

333, 

360, 

418, 

539. 

333, 

360, 

418, 

539. 

281, 

360. 

392. 

431, 

582. 

418, 

463, 

582. 

252, 

333, 

414, 

418. 

333. 

392. 

333, 

392, 

418, 

448, 

549. 

370. 

485. 

448. 

446. 

392, 

418, 

448. 

367. 

498, 

512. 

464. 

558. 

101. 

558. 

512, 

591. 

551. 

312. 

315 

334 

V,? 

551 

"75, 

101, 

227, 

334, 

464,  482,  498,  508,  512,  514,  551 

558,  572,  591. 

164 

219 

219 

440 

219 

219 

UNITED  STATES  TARIFF  COMMISSION 


150 

TABLE  26B, --Synth-.cic  organic  chemicals:   Kiscellaneous  chemicals  for   which  United  States  production  or  sales 
were  reported,    identified  by  manufacturer ,   195 J- -Continued 


MISCELLANEOUS  CffiTIICALS,  ACYCLIC— Continued 

Rioinoleio  acid  salts — Continued 

Triethyltetramine  ricinoleate 

Zinc  ricinoleate 

Sarcosine  (N-Methylaminoacetio  acid) 

Sebaclo  acid 

Semicartazide  base 

Semicarbazide  hydrochloride 

Sequestering  agents: 

(Diethylenetrinitrilo )pentaaeetic  acid 

(.Ethylenedlnitrllo)tetraacetio  acid 

(Ethylenedinitrilo)tetraaoetic  acid,  disodium 

salt. 
(Ethylenedinitrilo)tetraacetic  acid,  disodium- 

copper  salt. 
(Ethylenedinitrilo)tetraacetio  acid,  monosodium- 
iron  salt. 
»(Ethylenedinitrilo)tetraacetic  acid,  tetrasodium 
salt. 
(Ethylenedinitrilo)tetraacetic  acid,  trisodium 
salt. 

Silicones,  fluids  and  greases 

Sodium  ethoxlde 

Sodium  ethyl  oxalaoetate 

Sodium  formaldehydebisulfite 

»Sodium  formaldehydesulfoxylate 

Sodium  methoxide  (Sodium  methylate) 

Sodium  sorbitol  borate 

Sorbitol 

Soya  nitrile 

Stearamide  (Ootadeoane  amide) 

»Stearic  acid  salts: 
^Aluminum  stearates: 

»Aluminum  distearate 

Aluminum  monostearate 

Aluminum  stearates,  mixed 

Aluminum  tristearate 

Ammonium  stearate 

*Barium  stearate 

«Cadmium  stearate 

^Calcium  stearate 

Cobalt  stearate 

Ferric  stearate > : 

Ferrous  stearate 

»Lead  stearate - 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


Lead  stearate,  dibasic — 

Lithium  hydroxystearate- 

»Lithium  stearate 

*Magnesium  stearate 

Manganese  stearate 

«Zlno  stearate 

All  other- 


Stearonitrile  ( Octadecanenitr ile ) 

Stearoyl  chloride 

Stearoyloxyethylcarbai^l  chloride 

Succinic  acid 

•Succinic  anhydride ~ 

Sucoinlmide 

Sucoinonitrile 

Sucrose  octaaoetate 

Tall  oil  fatty  aoyl  chloride 

Tallow  fatty  acyl  chloride 

Tartaric  acid 

Tartaric  acid  salts,  nonmedicinal 

Tetraethylene  glycol 

Tetraethylene  glycol  dimethyl  ether  {Bls[2-(2-meth- 
oxyethoxy)ethyl] ether ) . 

Tetraethyl  lead 

Tetraglycine  hydroperlodlde 

Thiamine  hydrobromlde 

Thioaoetamide 

Thioacetic  acid  (Sulfoaoetic  acid) 

Thioglycerol 

Thioglycolio  acid  (Mercaptoacetlo  acid) 

Thioglycollc  acid  salts: 

•Anmonium  thloglycolate 

Calcium  thloglycolate 

Sodium  thloglycolate 

Thiourea 

Triallyl  cyanurate 

Trlbutyl  phosphate 

Trlbutyl  phosphite 


550. 

219. 

333,  550,  559,  57A. 

86,  -493. 

133. 

133,  599. 

3<i2. 

342,  550. 
342. 


342. 

342,  464,  550,  590. 

342. 

315. 

394,  463. 

463. 

266,  498,  599. 

307,  333,  429,  493. 

394,  430,  551,  X. 

417. 

417. 

23. 

333. 


39,  164,  231,  288,  314,  421,  464,  566. 
164,  231,  421. 

39,  131,  164,  231,  314,  421,  464,  566. 

,  314,  319,  421,  566. 

39,  164,  314,  421,  566. 

314,  421. 

39,  164,  231,  314,  421,  464,  566. 


,  314,  371,  421,  440,  566. 
,  371. 

164,  274,  314,  421,  566. 

39,  164,  231,  314,  421,  464,  566. 

39,  164,  231,  314,  421,  464,  566. 
550. 


527,  551. 
498,  527. 


333,  426. 
313,  565. 

515. 
498. 
498. 
147. 
147,  383. 

147,  253,  383,  599. 

147. 

147,  514. 

245. 

464. 

312. 

312. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


151 


TABL£  26B* --Synthetic  organic  chemicals:    Miscellaneous  chemicals   for   which  United  States  production   or   sales 
were  reported,    identified  by  manufacturer ,    i9J3--Continued 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

2,2,2-Trlohloro-l-ethoxyethanol 

Trichloroethylsilane  (Ethyl  silicon  trichloride) 

Trichlorohexadecylsilane  (Hexadecyltrichlorosilane) 

Trichloromethylsilane  (Methyl trichlorosilane ) 

Trichloro-octadecylsilane  (Octadeoyl trichloro- 
silane). 

Triethanolamine  phosphate 

1 , 1 , l-Triethoxye thane 

Triethyl  citrate 

Triethylene  glycol 

Triethylene  glycol  dichloride  (2-(2-Chloroethoxy)- 
ethyl  2-chloroethyl  ether). 

Triethyl  orthoformate 

Triethyl  orthopropionate 

Triethyl  phosphite 

Trihexyl  phosphite 

Triiso-octyl  phosphite 

Tr'iisopropyl  phosphite 

Tripropylene  glycol 

Tripropylene  glycol,  methyl  ether 

Tris(2-ethylhexyl)  phosphite 

Undeoylenio  acid  (Hendeoenoio  acid) 

Urea ,  solid 

Urea  in  feed  compounds 

Urea  in  solid  fertilizer 

Urea  in  urea-ammonia  solution 

Vinyl  acetate,  monomer 

Xanthio  acid,  ethyl,  sodium  salt 

■»Zinc  formaldehydesulfoxylate 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


495. 
315. 
315. 
315. 
315. 

302. 

498. 

415. 

321,  392,  448. 

392. 


266. 
498. 
312. 
312. 
312. 
312. 
448. 
448. 
312. 
219. 
286, 
286, 
333. 
286, 
-333, 
333. 
307, 


333. 
333. 


333. 
392,  418. 


333,  429,  493,  596. 


152  UNITED  STATES  TARIFF  COMMISSION 

Directory  of  Manufacturers 

The  Directory  of  Manufacturers  lists  the  companies  that  report 
their  production  of  synthetic  organic  chemicals  to  the  United  States 
Tariff  Commission.    The  name  of  each  manufacturer  is  preceded 
by  an  identification  number. 

For  1953,    the  Directory  of  Manufacturers  lists  608    connpanies 
(see  table  2.1).     This  is   17  more  than  the  number  that  reported  for 
1952.    Some  of  the  companies  that  report  production  of  synthetic 
organic  chemicals  consume  their  entire  output  in  further    manu- 
facturing. 

The  Directory  of  Manufacturers  lists  the  companies  in  two 
ways.     Section  1  lists  them  in  numerical  order,    the  identification 
number  for  each  company  having  been  assigned  in  the  order  in 
which  the  Tariff  Commission  received  the  company's  reporting 
schedule.    This  system  makes  it  unnecessary  to  wait  until  all  the 
schedules  are  returned  before  assigning  the  identification  numbers, 
and  greatly  speeds  the  preparation  of  the  tables    in   part  III.  Section 
2  lists  the  companies  in  alphabetical  order. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


153 


TABLE  2T.--Synehetic   organic  chemicals:    Directory  of  m 

SECTION  1.   NUMERICAL  DIRECTORY 


ufacturem,    1953 


[Nanes  of  sjiithetio  organic  chemical  manufacturers  who  reported  production  or  sales  to  the  United  States 
Tai-iff  Coraraission  for  1953  are  listed  below  in  the  order  of  their  identification  numbers  as  used  in 
tables  in  part  III.  Section  2  of  this  table  lists  these  manufactui-ers  alphabetically  euid  gives  their 
offices  and  plant  addresses] 


No. 

Name  of  company 

No. 

Name  of  company 

1 

EmJcay  Chemical  Co. 

■/4 

Ansul  Chemical  Co. 

2 

Guyan  Color  &  Chemical  Works. 

75 

City  Chemical  Corp. 

3 

Standard  Agricultural  Chemicals,  Inc. 

76 

Dye  Specialties  Corp.,  Inc. 

A- 

Witte,  John  H.,  &  Sons. 

77 

Anderson  Laboratories,  Inc. 

5 

Drug  Processors,  Inc. 

■/8 

Polychemical  Co. 

0 

Astra  Pharmaceutical  Products,  Inc. 

79 

Stanuard-Tooh  Chemicals,  Inc. 

Hartman-Leddon  Co. 

SO 

Siddall,  George  F.,  Co.,  Inc. 

C 

Knoedler  Chemical  Co. 

81 

Sonneborn,  L.,  Sons,  Inc. 

9 

LaMotte  Chemical  Products  Co. 

82 

American  Viscose  Corp.  (Sylvania  D-"".). 

10 

Nilol:  Chemicals,  Inc. 

o3 

Atlas  Wall  Paper  Mills,  Inc. 

11 

PoughJ;eepsie  Dyestuff  Corp. 

Cargill,  Inc.  (Falk  Div.). 

12 

Foster-Heaton  Co. 

65 

General  Motors  Corp.  (AC  Spai-k  Plug  Div.). 

13 

George,  P.  D.,  Co. 

Hardesty,  W.  C,  Co.,  Inc. 

!■■, 

Marrov/ '  s ,  Inc . 

J', 

Kohnstamm,  H.,  ii  Co.,  Inc. 

\'j 

Metro-Atlantic,  Inc. 

66 

Magnolia  Petroleum  Co. 

16 

Standard  Soap  Co.  of  Camden. 

69 

Meyer,  J.,  .i  Sons. 

IV 

Southern  Textile  Chemical  Corp. 

90 

Neches  .Butane  Products  Co.  (R.  R.).^ 

lb 

Dal:ota  Briquets  &  Tai-  Products,  Inc. 

91 

Reliance  Varnish  Co.,  Inc. 

ly 

Marathon  Corp.  (Chemical  Div.). 

92 

Vita-Vai'  Corp. 

20 

Red  Spot  Paint  &  Varnish  Co. 

93 

Bird  £:  Son,  Inc. 

21 

Synthetic  Products  Co. 

94 

Humble  Oil  £:  Refining  Co.  (R.  R.).^ 

22 

United  States  Procaine  Co.,  Inc. 

95 

Modene  Paint  Co.,  Inc. 

23 

Annour  &  Co.  (Chemical  Div.). 

96 

Morv/ear  Paint  Co. 

2/ 

Commonwealth  Color  £:  Chemical  Co. 

97 

Richardson  Co. 

2i 

Crownoil  Chemical  Co.,  Inc. 

98 

Salvo  Chemical  Corp. 

26 

Ironsides  Co. 

99 

Standard  Brands,  Inc. 

2V 

Pur-ooaine,  Inc. 

100 

American  Alcolac  Corp. 

26 

Dr.  Salsbury's  Laboratories. 

101 

Arapalioe  Chemicals,  Inc.,  i  Ai-apahoe  Special 

29 

Watertown  Manufacturing  Co. 

Products,  Inc. 

30 

American  Marietta  Co. 

102 

Cadet  Chemical  Corp. 

31 

Atlas  Processing  Co. 

103 

California  Inlc  Co.,  Inc. 

32 

Armstrong  Corl:  Co. 

104 

Citro  Chemical  Co. 

33 

Elizabethtown  Consolidated  Gas  Co. 

105 

Copolymer  Corp.  (R.  R.).^ 

34 

Hanna  Paint  Manufacturing  Co.  (Industrial 

106 

Crosby  Chemicals,  Inc. 

Div.). 

107 

Crovm  Tar  &  Chemical  Works,  Inc. 

35 

Harbor  Plywood  Corp. 

108 

El  Doj'ado  Oil  Works. 

36 

Kennecott  Copper  Corp.  (Chino  Mines  Div.). 

109 

Griffin  Chemical  Co. 

37 

Marden-Wild  Corp. 

110 

McGean  Chemical  Co. 

36 

Mineral  Oil  Refining  Co. 

111 

MarbOii  Corp. 

39 

Parsons,  N.  W.,  Plymouth,  Inc. 

112 

Marlowe-Van  Loan  Corp. 

40 

Rubber  Corp.  of  America. 

113 

Peerless  Chemical  Co. 

41  ■ 

U.  S.  Plastic  Products  Corp. 

114 

Peerless  Color  Co.,  Inc. 

42 

Van  Camp  Laboratories,  Div.  of  Van  Camp  Sea 

115 

Phoenix  Oil  Co. 

Food  Co.,  Inc. 

116 

Schenley  Laboratories,  Inc. 

43 

Sipe,  James  B.,  fi:  Co. 

117 

Fiber  Chemical  Corp. 

44 

American  Marietta  Co.  (Ferbert-Schorndorfer 

118 

Continental-Diamond  Fibre  Co. 

Co.  Div.) . 

119 

Marx,  Max,  Color  &  Chemical  Co. 

■;5 

Cabot,  Samuel,  Inc. 

120 

Schenectady  Vai-nish  Co.,  .Inc. 

46 

Drganios,  Inc. 

121 

Belle  Alkali  Co. 

4V 

Ortho  Chemical  Corp. 

122 

Bio-Procoos  Co.,  Div.  of  Armour  ii  Co. 

46 

Scholler  Bros . ,  Inc. 

123 

Carlisle  Chemical  Works,  Inc. 

49 

Advance  Paint  Co. 

124 

Farley  &  Loetscher  Manuf aotui'ing  Co. 

50 

American  Viscose  Corp. 

125 

Firestone  Tire  &  Rubber  Co.  (R.  R.).^ 

51 

Calabar.ia  Chemical  Co. 

126 

Hjnson,  Westcott  S:  Dunning,  Inc. 

52 

Kehew-Bradley  Co. 

127 

Kyanize  Paints,  Inc. 

53 

Northwestern  Chemical  Co. 

128 

Food  Machinery  &  Chemical  Corp.  (Ohlo-Apex 

5/, 

Swift  S:  Co. 

Div.). 

55 

Thompson  Chemicals  Corp. 

129 

Noi-wich  Phai-macal  Co. 

56 

Cheraico,  Inc. 

130 

WlilLtemore-Wright  Co.,  Inc. 

57 

Nonweilor,  A.  P.,  Co. 

131 

Jones-Dabney  Co.,  Div.  of  Dovoe  &  Rayiiolds 

5S 

Apex  Chemical  Co.,  Inc. 

Co.,  Inc. 

59 

Atomic  Basic  Chemicals  Corp. 

132 

Gamma  Chemical  Coj-p. 

60 

Chaff ardon,  J. 

133 

Fairmont  Chemical  Co.,  Inc. 

61 

Coopers  Creek  Chemical  Corp. 

134 

Pennsylvania  Industrial  Chemical  Corp. 

62 

Dow  Chemical  Co.  (Styrene  Div.).  (R.  R.).^ 

135 

Shepherd  Chemical  Co. 

63 

Keystone  Color  Works,  Inc. 

136 

White  S:  Hodges,  Inc. 

6''r 

Keystone  Paint  &  Varnish  Corp. 

137 

General  Tire  i  Rubber  Co.  (Chemical  Div.). 

65 

Laurel  Soap  Manuf actm-ing  Co.,  Inc. 

138 

Minnesota  Paints,  Inc. 

66 

long,  Chas.  R.,  Jr.,  Co. 

139 

Pine  Bluff  Chemical  Co.,  subsidiai-y  of  Food 

6', 

Mai'blette  Corp. 

Machinery  &  Chemical  Corp. 

6i; 

Metro  Dyestuff  Corp. 

140 

Amalgamated  Chemical  Corp. 

6',' 

Raybestos  Div.  of  fiaybestos-Manhattan,  Inc. 

141 

Booty  Resineers,  Inc. 

70 

Sonoco  Products  Co. 

142 

Delaware  Chemicals,  Inc. 

71 

Spaulding  Fibre  Co.,  Inc. 

143 

Kali  Majiufactui-ing  Co. 

72 

Spencer  Chemical  Co. 

144 

Montclair  Research  Corp. 

73 

Edison,  Thomas  A.,  Inc.  (Medical  Gas  Div.). 

145 

Niagai-a  Alkali  Co. 

See  footnote  at  end  of  table. 
313486  O  -  54  -  11 


154 


UNITED  STATES  TARIFF  COMMISSION 


tabu;  27.--Syntheti 


rganic  chemicals:   Directory  of  manufacturers ,    i 955- -Continued 


No. 

Name  of  company 

No. 

Name  of  company 

146 

U.  S.  Eubter  Co.  (R.  R.).^ 

228 

General  Mills,  Inc. 

147 

Evans  Cheraetics,  Inc. 

229 

Givaudan  Corp. 

148 

Rinshed-Mason  Co. 

230 

Lueders,  George,  &  Co. 

149 

American  Aniline  t  Extract  Co.,  Inc. 

231 

Mallinolcrodt  Chemical  Works. 

150 

Atlas  Refinery,  Inc. 

232 

Merichem  Co. 

151 

Bates  Chemical  Co. 

233 

National  Biochemical  Co. 

152 

Cutter  Laboratories. 

234 

Pan  American  Refining  Corp. 

153 

Genesee  Research  Corp. 

235 

American  Maize  Products  Co. 

154 

Oilman  Paint  &  Varnish  Co. 

236 

Allied  Chemical  &  Dye  Corp.  (Solvay  Process 

155 

Huggins,  James,  &  Son,  Inc. 

Div.). 

156 

Old  Colony  Tar  Co.,  Inc. 

237 

J^pleton  Coated  Paper  Co. 

157 

Portland  Gas  &  Coke  Co. 

238 

Bristol  Laboratories,  Inc. 

158 

Seattle  Gas  Co. 

239 

Carpenter-Morton  Co. 

159 

Solvent  Chemical  Co.,  Inc. 

240 

Carus  Chemical  Co.,  Inc. 

160 

Tar  Distilling  Co.,  Inc. 

241 

Colgate-Palmolive  Co. 

161 

Tennessee-Frontier  Corp. 

242 

Diamond  Alkali  Co. 

162 

Whittier  Laboratories. 

243 

Firestone  Plastics  Co.  Div.  of  Firestone  Tire 

163 

Bin-roughs  Wellcome  &  Co.  (U.S.A.),  Inc. 

&  Rubber  Co. 

164 

Leffingwell  Chemical  Co. 

244 

Kalide  Corp. 

165 

Maltbie  Laboratories,  Inc. 

245 

Monsanto  Chemical  Co. 

166 

Old  Hickory  Chemical  Co.,  Inc. 

246 

Pitman-Moore  Co.,  Div.  of  Allied  Laboratories, 

16/ 

Westinghouse  Electric  Corp. 

Inc. 

16S 

Wilmot  Sc  Cassidy,  Inc. 

247 

Pure  Oil  Co. 

169 

Brovm  Co. 

248 

Scherer,  R.  P.,  Corp. 

170 

Grand  Rapids  Varnish  Corp. 

249 

Shawinigan  Resins  Corp. 

171 

International  Minerals  &  Chemical  Corp. 

250 

Southern  Dyes tuff  Corp. 

172 

Levey,  Fred'k.  H.,  Co.,  Inc. 

251 

Southside  Chemical  Co.,  Inc. 

173 

Miles  Laboratories,  Inc. 

252 

Stanolind  Oil  &  Gas  Co. 

174 

Schuylkill  Chemical  Co. 

253 

Summit  Chemical  Products. 

175 

Wetherill,  George  D.,  Varnish  Co. 

254 

Vanderbilt  Chemical  Corp. 

176 

American  Bio-Synthetics  Corp. 

255 

Van  Dyk  &  Co.,  Inc. 

l'/7 

California-Spray  Chemical  Corp. 

256 

General  Foods  Corp.  (Maxwell  House  Div.). 

178 

Qual;er  Chemical  Products  Corp. 

257 

Pabco  Products,  Inc. 

179 

Standard  Naphthalene  Products  Co. 

258 

Shell  Chemical  Corp. 

180 

General  Color  Co.,  Inc. 

259 

Trask,  Arthur  C,  Co. 

181 

Michigan  Chemical  Corp. 

260 

Archer-Daniels-Midland  Co. 

182 

Barium  Reduction  Corp. 

261 

Ford  Motor  Corp. 

183 

Glyoo  Products  Co.,  Inc. 

262 

Hall,  C.  P.,  Co.  of  Illinois, 

184 

National  Starch  Products,  Inc. 

263 

Baltimore  Paint  &  Color  Works. 

185 

Oldbuxy  Electro-Chemical  Co. 

264 

Buckeye  Cotton  Oil  Co. 

186 

Ai'co  Co. 

265 

Burkart-Schier  Chemical  Co. 

187 

Specific  Pharmaceuticals,  Inc. 

266 

Kay-Fries  Chemicals,  Inc. 

188 

Taylor  Fibre  Co. 

267 

New  York  Quinine  &  Chemical  Works,  Inc. 

189 

Crown  Chemical  Corp. 

268 

Wilson  Organic  Chemicals,  Inc. 

190 

Baker,  J.  T.,  Chemical  Co.  (Taylor  Chemical 

269 

Zurn,  0.  F.,  Co. 

Div,). 

270 

Alox  Corp. 

191 

Lever  Brothers  Co. 

271 

American  Chemical  Paint  Co. 

192 

Osborn,  C.  J.,  Co. 

272 

Cook  Paint  &  Varnish  Co. 

193 

Oxford  Corp. 

273 

General  Tire  &  Rubber  Co.  (R.  R.).^ 

194 

Pratt  &  Lambert,  Inc. 

274 

Maywood  Chemical  Works. 

195 

Pui-ex  Corp.,  Ltd. 

275 

Pennsylvania  Salt  Manufacturing  Co. 

196 

Snyder  Chemical  Corp. 

276 

Procter  &  Gamble  Co. 

197 

Standard  Chlorine  Chemical  Co. 

277 

Thomasset  Colors,  Inc. 

198 

Sumner  Chemical  Co.,  Inc. 

278 

Cosden  Petroleum  Corp. 

199 

Upjohn  Co. 

279 

Greenwood  Textile  Supply  Co. 

200 

Wheeler,  Reynolds  &  Stauffer. 

280 

Werner  Drug  &  Chamical  Co. 

201 

Clinton  Foods,  Inc. 

281 

Baker,  J.  T.,  Chemical  Co. 

202 

Puget  Sound  Pulp  &   Timber  Co. 

282 

Fine  Colors  Co. 

203 

Schieffelin  &   Co. 

283 

Great  Southern  Chemical  Corp. 

204 

Krumbhaar  Chemical  Co.,  Inc. 

284 

Moreland  Chemical  Co.,  Inc. 

205 

Nepera  Chemical  Co.,  Inc. 

285 

Newport  Industries,  Inc. 

206 

Ottawa  Chemical  Co.,  Inc. 

286 

Allied  Chemical  &  Dye  Corp.  (Nitrogen  Div.). 

207 

SjTivai-  Corp. 

287 

Corn  Products  Refining  Co. 

208 

Victor  Chemical  Works. 

288 

Kentuck-y  Color  &  Chemical  Co. 

209 

Gulf  Oil  Corp. 

289 

Merrell,  Wm.  S.,  Co. 

210 

Atlantic  Refining  Co. 

290 

Paul-Lewis  Laboratories,  Inc. 

211 

Berk,  F.  W.,  &  Co.,  Inc. 

291 

Ad -Co  Color  Corp. 

212 

Bruder,  M.  A.,  &  Sons,  Inc. 

292 

California  Flaxseed  Products  Co. 

213 

Cities  Service  Refining  Corp.  (R.  R.).^ 

293 

Carolina  Aniline  &  Extract  Co. 

214 

Federal  Paint  Co.,  Inc. 

294 

Chemical  Manufacturing  Co.,  Inc. 

215 

Oil  &  Chemical  Products,  Inc. 

295 

Chemical  Process  Co. 

216 

Publicker  Industries,  Inc. 

296 

Colton  Chemical  Co. 

217 

Stauffer  Chemical  Co. 

297 

Fuller,  W.  P.,  &  Co. 

218 

Western  Condensing  Co. 

298 

Industrial  Products,  Inc. 

219 

Balier  Castor  Oil  Co. 

299 

Inland  Alkaloid  Co. 

220 

Chase  Chemical  Corp. 

300 

Lakeside  Laboratories,  Inc. 

221 

General  Petroleum  Corp. 

301 

Maumee  Chemical  Co. 

222 

Hercules  Powder  Co. 

302 

Dominion  Products,  Inc. 

223 

Shell  Oil  Co. 

303 

Oronito  Chemical  Co. 

224 

Peck's  Products  Co. 

304 

Pacific  Paint  &  Varnish  Co. 

225 

Florasynth  Laboratories,  Inc. 

305 

Richfield  Oil  Corp. 

226 

Colt's  Manufacturing  Co. 

306 

Roosevelt  Oil  &  Refining  Corp. 

227 

Delta  Chemical  Works. 

307 

Royce  Chemical  Co. 

See  footnote  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


155 


TABLE  27. --Synthetic  organic  chemicals;   D 

irectory  of  manufacturers,    1 953- -Continued 

No. 

Name  of  company 

No. 

Name  of  company 

308 

Smith,  Klein  &  French  Laboratories. 

385 

Ultra  Chemical  Works,  Inc. 

309 

Trojan  Powder  Co. 

386 

Collett-Week-Nibeoker,  Inc. 

310 

United  Piece  Dye  Works. 

387 

Durez  Plastics  &  Chemicals,  Inc. 

311 

Velsiool  Corp.,  Div.  of  Arvey  Corp. 

388 

Holland  Color  &  Chemical  Co. 

312 

Virginia-Carolina  Chemical  Corp. 

389 

Lemlce,  B.  L.,  &  Co.,  Inc. 

313 

Wallace  &  Tiernan,  Inc. 

390 

Montrose  Chemical  Corp.  of  California. 

3U 

Witco  Chemical  Co. 

391 

Pittsburgh  Plate  Glass  Co. 

315 

Dow  Corning  Corp. 

392 

Union  Carbide  &   Carbon  Corp.  (Carbide  & 

Carbon 

316 

Inland  Steel  Container  Co. 

Chemicals  Co.). 

317 

Loven  Chemical  Co.  of  California. 

393 

Valspar  Corp.  (Valentine  &  Co.  Div.). 

31C 

Esso  Standard  Oil  Co. 

394 

Gane's  Chemical  Worlcs,  Inc. 

319 

Farrington,  W.  U.,  Estate  of. 

395 

Glidden  Co. 

320 

Interohemical  Corp.  (Textile  Colors  Div.). 

396 

Goodyear  Tire  &  Rubber  Co. 

321 

Jefferson  Chemical  Co.,  Inc. 

397 

Heyden  Chemical  Corp. 

322 

Kendall  Refining  Co. 

398 

Kennecott  Copper  Corp.  (Utah  Copper  Div 

). 

323 

Koppers  Co.,  Inc. 

399 

Maas  &  Waldstein  Co. 

324 

Meta  Chemical  Corp. 

400 

Parke,  Davis  &  Co. 

325 

Metalsalts  Corp. 

401 

Premo  Pharmaceutical  Laboratories,  Inc. 

326 

National  Chlorophyll  &   Chemical  Co. 

402 

Shulton,  Inc.  (Fine  Chemicals  Div.). 

327 

Neville  Chemical  Co. 

403 

Standard  Chemical  Products,  Inc. 

328 

Ottol  Oil  Co. 

404 

Sun  Oil  Co. 

329 

Remington  Arms  Co.,  Inc. 

405 

Texas  Co. 

330 

Stange,  Wm.  J.,  Co. 

406 

Uhlich,  Paul,  &  Co.,  Inc. 

331 

Tennessee  Products  &  Chemical  Corp. 

407 

U.  S.  Oil  Co. 

332 

Dexter  Chemical  Corp. 

408 

Varcum  Chemical  Corp, 

333 

duPont  de  Nemours,  E.  I.,  &  Co.,  Inc. 

409 

Washburn,  T.  F.,  Co. 

334 

Union  Carbide  Ce  Carbon  Corp.  (Linde  Air 

410 

Western  Dry  Color  Co. 

Products  Co.  Div.). 

411 

Young  Aniline  Works,  Inc. 

335 

Bios  Laboratories,  Inc. 

412 

Thiokol  Chemical  Corp. 

336 

Ciba  Pharmaceutical  Products,  Inc. 

413 

Crown  Central  Petroleum  Corp. 

337 

Hoolcer-Detrex,  Inc. 

414 

Fritzsche  Brothers,  Inc. 

33a 

Hooker  Electrochemical  Co. 

415 

Pfizer,  Chas.,  &  Co.,  Inc. 

339 

Irvington  Varnish  &  Insulator  Co.  Div.  of 

416 

Wilson  Laboratories . 

Minnesota  Mining  &  Manufacturing  Co. 

417 

Atlas  Powder  Co. 

340 

Pabst  Brewing  Co. 

418 

Celanese  Corp.  of  America. 

341 

Hitter  Chemical  Co.,  Inc. 

419 

Endo  Products,  Inc. 

342 

Alrose  Div.  of  Geigy  Chemical  Corp. 

420 

Hampden  Color  &  Chemical  Co. 

343 

Benzol  Products  Co. 

421 

Nopco  Chemical  Co.,  Inc. 

34^K 

Cities  Service  Oil  Co. 

422 

Specialty  Resins  Co. 

345 

Food  Machinery  &  Chemical  Corp.  (Westvaco 

423 

Union  Oil  Co.  of  California. 

Chemical  Div.). 

424 

Zinsser  &  Co.,  Inc. 

346 

General  Electric  Co.  (Chemical  Div.). 

425 

Childs  Pulp  Colors,  Inc. 

347 

Grain  Processing  Corp. 

426 

Ethyl  Corp. 

34£i 

Harsyd  Chemicals,  Inc. 

427 

Peters  Chemical  Co. 

349 

Hart  Products  Corp. 

428 

Sandoz  Chemical  Works,  Inc. 

350 

Heresite  &  Chemical  Co. 

429 

Wolf,  Jacques,  Sc   Co. 

351 

Miranol  Chemical  Co.,  Inc. 

430 

Mathieson  Chemical  Corp. 

352 

Norda  Essential  Oil  &  Chemical  Co.,  Inc. 

431 

Fries  Bros.,  Inc. 

353 

Nuodex  Products  Co.,  Inc. 

432 

Lebec  Chemical  Corp. 

354 

Pathfinder  Chemical  Corp.,  subsidiary  of 

433 

Lever,  C,  Co.,  Inc. 

Goodyear  Tire  &  Rubber  Co. 

434 

Car^^ri.n  Co. 

355 

Warner-Jenkinson  Manufacturing  Co. 

435 

Ohio  Chemical  &  Surgical  Equipment  Co. 

356 

White  &  Bagley  Co. 

436 

Soluol  Chemical  Co.,  Inc. 

357 

Wallace  &  Tiernan,  Inc.  (Lucidol  Div.). 

437 

American  Polymer  Co.  Div.  of  the  Borden 

Co. 

358 

Alframine  Corp. 

438 

Drew,  E.  F.,  &   Co.,  Inc. 

359 

American  Potash  Sc  Chemical  Corp.  (Eston 

439 

Federal  Color  Laboratories,  Inc. 

Chemicals  Div.). 

440 

Harshaw  Chemical  Co. 

360 

Chemo  Puro  Manufacturing  Corp. 

441 

Humble  Oil  &  Refining  Co. 

361 

McCloskey  Varnish  Co. 

442 

Lilly,  Eli,  &   Co. 

362 

Sooony-Vacuum  Oil  Co.,  Inc. 

443 

Phillips  Petroleum  Co.  (R.  R.).^ 

363 

Westville  Laboratories . 

444 

Sharp  &  Dohme  Div.  of  Merck  &  Co.,  Inc. 

364 

Alco  Oil  &  Chemical  Corp. 

445 

Staley,  A.  E.,  Manufacturing  Co. 

365 

Arnold,  Hoffman  Sc  Co.,  Inc. 

446 

Ninol  Laboratories,  Inc. 

366 

Ciba  States,  Ltd.  (Toms  River  Div.). 

4A7 

Wolff -Alport  Chemical  Corp. 

367 

Commercial  Solvents  Corp. 

448 

Dow  Chemical  Co. 

360 

Edcan  Laboratories. 

449 

Borden  Co.  (Chemical  Div.). 

369 

Johnson,  Chas.  Eneu,  Co.,  Inc. 

450 

Deecy  Products  Co. 

370 

Kessler  Chemical  Co.,  Inc. 

451 

van  Ameringen-Haebler,  Inc. 

371 

National  Lead  Co. 

452 

Hoffmann-LaRoche,  Inc. 

372 

Reilly  Tar  &  Chemical  Corp. 

453 

Interohemical  Corp.  (Finishes  Div.). 

373 

Republic  Creosoting  Co. 

454 

Plastics  Engineering  Co. 

374 

Richards  Chemical  Works,  Div.  of  Onyx  Oil  & 

455 

Belle  Chemical  Co.,  Inc. 

Chemical  Co. 

456 

Pittsburgh  Coke  &  Chemical  Co. 

375 

Ruberoid  Co. 

457 

Schering  Corp. 

376 

Sterling  Drug,  Inc.  (Hilton-Davis  Div.). 

458 

Sun  Chemical  Corp.  (Pigment  Div.). 

377 

United  States  Pipe  &  Foundry  Co. 

459 

Goodrich,  B.  F.,  Chemical  Co.  (Div.  of  B 

.  F. 

378 

U.  S.  Rubber  Co.  (Naugatuck  Chemical  Div.). 

Goodrich  Co.).  (R.  R.).^ 

379 

Winthrop-Stearns,  Inc. 

460 

Verona  Chemical  Co. 

380 

All-Tex  Specialties  Co. 

461 

Industrial  Dyestuff  Co. 

381 

Blackman  Brands,  Inc. 

462 

Schwarz  Laboratories,  Inc. 

382 

Bryant  Chemical  Corp. 

463 

U.  S.  Industrial  Chemical  Co. 

383 

Halby  Products  Co. 

464 

American  Cyanamid  Co.  (Lederle  Laboratories 

384 

Huron  Milling  Co. 

Div.  and  Organic  Chemicals  Div.). 

See  footnote  at  end  of  table. 


156  UNITED  STATES  TARIFF  COMMISSION 

TABLE  27 .--Synthetic   organic  chemicals:   Directory  of  manufacturers,    1953--Continued 


No. 

Name  of  company 

No. 

Name  of  company 

465 

Dawe's  Laboratories,  Inc. 

542 

Hexagon  Laboratories,  Ino. 

466 

Ferro  Chemical  Corp. 

543 

Keystone  Chemurgio  Corp. 

467 

Patent  Chemicals,  Inc. 

544 

Midland  Industrial  Finishes  Co. 

468 

R.  S.  A.  Corp. 

545 

Union  Bay  State  Chemical  Co.,  Inc. 

469 

Vitamins,  Inc. 

546 

Sterling  Drug,  Inc.  (Bayer  Co.  Div.). 

470 

Synthetic  Chemicals,  Inc. 

547 

Searle,  G.  D.,  S:  Co. 

471 

Brooklyn  Color  Works,  Inc. 

548 

Sigma  Chemical  Co. 

472 

Dykera  Co. 

549 

Wyandotte  Chemicals  Corp. 

473 

Continental  Oil  Co. 

550 

General  Aniline  &  Film  Corp.  (Dyestuff  & 

474 

Hyraan,  Julius,  &  Co. 

Chemical  Div.). 

475 

(Jialcer  Oats  Co. 

551 

Humplirey-Wilkinson,  Inc. 

476 

Remsen  Chemicals,  Inc. 

552 

May,  Otto  B.,  Inc. 

477 

Indoil  Chemical  Corp. 

553 

Salem  Oil  &   Grease  Co. 

47C 

Berkshire  Color  &   Chemical  Mfg.  Corp. 

554 

Southern  Sizing  Co. 

479 

Cleary,  W.  A.,  Corp. 

555 

Standai-d  Oil  Co.  of  California. 

4ao 

Crown  Chemical  Div.,  Joseph  Turner  &  Co. 

556 

Standard  Chemical  Co. 

481 

Esso  Standard  Oil  Co.  (Louisiana  Div.). 

557 

Gallowhur  Chemical  Corp. 

4C2 

Pedlow-Nease  Chemical  Co.,  Inc. 

558 

Pfanstiehl  Chemical  Co. 

4S3 

Tennessee  Eastman  Co.,  Div.  of  Eastman  Kodak 

559 

Phai-ma  Chemical  Corp. 

Co. 

560 

Standard  Oil  Co.  of  Indiana. 

484 

Texas  Eastman  Co.,  Div.  of  Eastman  Kodak  Co. 

561 

Wioa  Co.,  Ino. 

485 

Advance  Solvents  &  Chemical  Corp. 

562 

Maschmeijer,  A.,  Jr.,  Inc. 

486 

Pfister  Chemical  Works,  Inc. 

563 

Goodrich,  B.  F,,  Chemical  Co. 

487 

Union  Carbide  t  Carbon  Corp.  (Bakelite  Co.). 

564 

Wyeth  Laboratories,  Ino. 

488 

Coastwise  Petroleum  Co. 

565 

Abbott  Laboratories. 

439 

Douglas  Chemical  Corp. 

566 

Sun  Chemical  Corp.  (Warwick  Chemical  Co.  Div.). 

490 

France,  Campbell  S:  Darling,  Inc. 

567 

Ealcins,  J.  S.  &  W.  R.,  Inc. 

491 

Leatex  Chemical  Co. 

568 

Reichhold  Chemicals,  Ino. 

492 

Lebanon  Chemical  Corp. 

569 

Biok  &  Co.,  Inc. 

493 

Rohm  &  Haas  Co. 

570 

Collway  Colors,  Inc. 

494 

Berkeley  Chemical  Corp. 

571 

Stepan  Chemical  Co. 

495 

Cincinnati  Chemical  Works,  Inc. 

572 

Fisher  Scientific  Co. 

496 

Dewey  &  Almy  Chemical  Co. 

573 

Houghton,  E.  F.,  &   Co. 

497 

Eastern  States  Chemical  Corp. 

574 

Montrose  Chemical  Co. 

498 

Eastman  Kodak  Co. 

575 

DePaul  Chemical  Co.,  Inc. 

499 

Emery  Industries,  Inc. 

576 

American  Aniline  Products,  Inc. 

500 

Magruder  Color  Co.,  Inc. 

577 

Permutit  Co. 

501 

Arabol  Manufacturing  Co. 

578 

Augusta  Chemical  Co. 

502 

Pennsylvania  Refining  Co. 

579 

Davis,  H.  B.,  Co. 

503 

American  Alkyd  Industries. 

580 

Shai'ples  Chemicals,  Inc. 

504 

Allied  Chemical  S:  Dye  Corp.  (General  Chemical 

581 

Stresen-Reuter,  Fred'k.  A.,  Inc. 

Div.). 

532 

Trubek  Laboratories. 

505 

Finetex,  Inc. 

583 

Alliance  Color  &  Chemical  Co. 

506 

LaSalle  Chemical  Corp. 

534 

DePree  Co. 

507 

Farmers'  Chemical  Co. 

535 

Lewis  Tar  Products  Co. 

503 

Ritter,  F.,  S:  Co. 

586 

Seydel  Chemical  Co. 

509 

Rossville  Dyestuff  Corp. 

537 

Sinclair  &  Valentine  Co. 

510 

Sapon  Laboratories. 

588 

Strong,  Cobb  &  Co.,  Inc.  (American  Chlorophyll 

511 

Verley  Chemical  Co.,  Inc. 

Div.). 

512 

Columbia  Organic  Chemicals,  Inc. 

589 

Universal  Detergents,  Inc. 

513 

Lobica-Debruille,  Inc. 

590 

Bersworth  Chemical  Co. 

51-; 

Medical  Chemicals  Corp. 

591 

Fine  Organics,  Ino. 

515 

Merck  &  Co.,  Inc. 

592 

National  Petro-Chemicals  Corp. 

516 

Morton-Withers  Chemical  Co. 

593 

Dodge  &   Olcott,  Inc. 

517 

Riverdale  Chemical  Co. 

594 

Diamond  Alkali  Organic  Chemicals  Div.,  Inc. 

513 

Sinclair  Refining  Co. 

595 

Swope  Oil  &  Chemical  Co. 

519 

New  York  Color  &   Chemical  Co.,  Div.  of 

596 

Watson-Pai'k  Co. 

American  Dyewood  Co. 

597 

Cockerille,  F.  0. 

520 

Orbis  Products  Corp. 

598 

Felton  Chemical  Co.,  Inc. 

521 

Sherwin-Williams  Co. 

599 

Ringirood  Chemical  Corp. 

522 

Squibb,  E.  R.,  &  Sons,  Div.  of  Mathieson 

600 

Penick,  S.  B.,  &  Co. 

Chemical  Corp. 

601 

Kentuclcy  Synthetic  Rubber  Corp.  (R.  R.),.^ 
Midland  Synthetic  Rubber  Co.  (R.  R.).^ 

523 

Althouse  Chemical  Co.,  Inc. 

602 

524 

Catalin  Corp.  of  America. 

603 

Ethyl-Dow  Chemical  Co. 

525 

Imperial  Paper  &   Color  Corp.  (Pigment  Color 

604 

Archor-Daniels-Midland  Co.  (Chlorophyll  Div.). 

Div.). 

605 

Allied  Chemical  &   Dye  Coi-p.  (Semet-Solvay 

526 

Organic  Chemical  Corp. 

Div.). 

527 

Allied  Chemical  &  Dye  Corp.  (National  Aniline 

606 

Callison,  I.  P.y  &  Sons,  Inc. 

Div.). 

607 

Hoffman-Taff,  Iiic. 

528 

Jennison-Wright  Corp. 

608 

Lubrizol  Corp. 

529 

Jordan,  Jr.,  W.  H.,  &  F.,  Manufacturing  Co. 

530 

Cabot,  Godfrey  L.,  Inc. 

531 

Standard  Ultramai-ine  &  Color  Co. 

532 

Allcydol  Laboratories,  Inc. 

533 

Perkins  Glue  Co. 

534 

Reilly-Whitman-Walton  Co. 

535 

Synthron,  Ino . 

536 

Allied  Chemical  &  Dye  Corp.  (Barrett  Div.). 

537 

Ansbacher-Siegle  Corp. 

538 

Productol  Co. 

539 

Sheffield  Chemical  Co.,  Ino. 

5^f0 

Azoplate  Corp. 

541 

Emulsol  Corp. 

^  R.  R.  in  parentheses  following  the  name  of  a  company  indicates  U.  S.  Government  plant  operated  for  the 
Office  of  Rubber  Reserve. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953  157 

tabu;  27 .  -Synthetic  organic  chemicals:   Directory  of  manufacturers ,    7953- -Cnnt  iniieH 

SECTION  2,  AIPHABETICAL  DIRECTORY 

[ Names  of  synthetic  organic  chemical  manufacturers  who  reported  production  or  sales  to  the  United  States 
Tariff  Commission  for  1953  are  listed  below  alphabetically,  together  with  their  identification  numbers 
as  used  in  tables  in  part  III.  Section  1  of  this  table  lists  these  manufacturers  in  the  order  of  their 
identification  numbers! 


Name  of  company 


Abbott  Laboratories 

Ad-Co  Color  Corp 

Advance  Paint  Co — 

Advance  Solvents  &  Chemical  Corp' 

Alco  Oil  &  Chemical  Corp 

Alframine  Corp 

Alkydol  Laboratories,  Inc 

Alliance  Color  &   Chemical  Co 

Allied  Chemical  &  Dye  Corp.: 
Barrett  Div 


General  Chemical  Div- 


National  Aniline  Div 

Semet-Solvay  Div — 

Solvay  Process  Div 

All-Tex  Specialties  Co 

Alox  Corp 

Alrose  Div.,  Geigy  Chemical  Corp 

Althouse  Chemical  Co.,  Inc 

Amalgamated  Chemical  Corp 

American  Alcolac  Corp-- ~ — 

American  Alkyd  Industries 

American  Aniline  &  Extract  Co.,  Inc- 

American  Aniline  Products,  Inc 

American  Bio-Synthetics  Corp — 

American  Chemical  Paint  Co 

American  Cyanamid  Co 


Lederle  I aboratories  Div 


Organic  Chemicals  Div- 


Amerioan  Maize  Products  Co- 
American  Marietta  Co 


Ferbert-Schorndorfer  Co.  Div 

American  Polymer  Co.  Div.  of  the 

Borden  Co. 
American  Potash  and  Chemical  Corp. 

Eston  Chemicals  Div. 
American  Viscose  Corp——-—- 

Sylvania  Div- 


Anderson  Laboratories,  Inc 

Ansbacher-Siegle  Corp — 

Ansul  Chemical  Co — — 

Apex  Chemical  Co.,  Inc———— 

Appleton  Coated  Paper  Co 

Arabol  Manufacturing  Co 

Arapahoe  Chemicals,  Inc.,  &  Arapahoe 

Special  Products,  Inc. 
Aroher-Daniels-Midland  Co 

Chlorophyll  Div 


Arco  Co- 


Armour  &  Co.,  Chemical  Div 
Armstrong  Cork  Co- 
Arnold,  Hoffman  &  Co.,  Inc 

Astra  Pharmaceutical  Products,  Ino- 
Atlantic  Refining  Co 


Atlas  Powder  Co- 


Atlas  Processing  Co 

Atlas  Refinery,  Inc 

Atlas  Wall  Paper  Mills,  Inc 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office) 


and  Marcus 
(Buffalo,  N.  Y. 
(South  Point, 


14th  St.  and  Sheridan  Rd.,  North  Chicago,  111. 

66  Lister  Ave.,  Newark  5,  N.  J. 

601-35  Kentucky  Ave.,  Indianapolis  7,  Ind. 

245  5th  Ave.,  New  York  16,  N.  Y.  (Jersey  City,  N.  J.). 

Trenton  Ave.  and  William  St.,  Philadelphia  34,  Pa. 

72-76  Putnam  St.,   Paterson  4,    N.   J. 

3242  S.  50th  Ave.,  Cicero  50,  111. 

33  Avenue  P,  Newark  5,  N.  J. 

40  Rector  St.,  New  York  6,  N.  Y.  (Fairfield,  Ala.; 

Calumet  City  and  Chicago,  111.;  Detroit,  Mich.; 

Edgewater,  N.  J.;  Greensboro,  N.  C;  Ironton, 

Toledo,  and  Youngstown,  Ohio;  and  Bethlehem, 

Frankford,  and  Philadelphia,  Pa.). 
40  Rector  St.,  New  York  6,  N.  Y.  (Claymont,  Del.; 

Baton  Rouge,  La.;  Buffalo,  N 

Hook,  Pa.). 
40  Rector  St.,  New  York  6.  N.  ' 

and  Moundsville,  W.  Va.). 
40  Rector  St.,  New  York  6,  N.  ' 

Ohio,  and  Hopewell,  Va.). 
40  Rector  St.,  New  York  6  (Tonawanda),  N.  Y. 
Syracuse  1  (Geddes),  N.  Y. 
65  Meadow  St.,  Warwick,  R.  I. 
70  Pine  St.,  New  York  3  (Niagara  Falls),  N.  Y. 
P.O.  Box  1294,  Providence  1  (Cranston),  R.  I. 
540  Pear  St.,  Reading,  Pa. 
Ontario  and  Rorer  Sts.,  Philadelphia  34,  Pa. 
3440  Fairfield  Rd.,  Baltimore  26,  Md. 
Broad  and  14th  Sts.,  Carlstadt,  N.  J. 
Venango  and  F  Sts.,  Philadelphia  34,  Pa. 
50  Union  Sq.,  New  York  3,  N.  Y.  (Lock  Haven,  Pa.). 
710  W.  National  Ave.,  Milwaukee  4,  Wis. 
Ambler,  Pa. 
30  Rockefeller  Plaza,  New  York  20,  N.  Y.  (Azusa, 

Calif.;  Stamford  and  Wallingford,  Conn.;  Bound 

Brook,  Warners,  and  Woodbridge,  N.'J.;  Charlotte, 

N.  C;  and  Bridgeville,  Pa.). 
30  Rockefeller  Plaza,  New  York  20  (Pearl  River), 

N.  Y. 
30  Rockefeller  Plaza,  New  York  20,  N.  Y.  (Bound 

Brook,  N.  J.). 

100  E.  42d  St.,  New  York  17,  N.  Y. 
3400  13th  Ave.,  SW.,  Seattle  4,  Wash. 
12815  Elmwood  Ave.,  Cleveland  11,  Ohio. 

101  Foster  St.,  Peabody,  Mass. 

3100  E.  26th  St.,  Los  Angeles  23,  Calif. 

1617  Pennsylvania  Blvd.,  Philadelphia  3  (Meadville),  Pa. 

Fredericksburg,  Va, 

3940  Summit  St.,  Weston,  Mich. 

92  Chestnut  Ave.,  Hosebank,  Staten  Island  5,  N.  Y. 

1  Stanton  St.,  Marinette,  Wis. 

225  W.  34th  St.,  New  York  1,  N.  Y.  (Ellzabethport, 

N.  J.). 
1200  N.  Meade  St.,  Appleton,  Wis. 
110  E.  42d  St.,  New  York  17,  N.  Y. 
2800  Pearl  St.,  Boulder,  Colo. 

2191  W.  110th  St.,  Cleveland,  Ohio  (Wyandotte,  Mich.). 
P.O.  Box  839,  Minneapolis  2.  Minn.  (Neodesha, 

Kans . ,  and  Bethlehem,  Pa . ) . 
7301  Bessemer  Ave.,  Cleveland  27,  Ohio. 
1355  W,  31st  St.,  Chicago  9  (McCook) ,  111. 
W.  Liberty  St.,  Lancaster  (Pittsburgh),  Pa. 
55  Canal  St.,  Providence  1,  R.  I.  (Dighton,  Mass.; 

Charlotte,  N.  C;  and  Cincinnati,  Ohio). 
7j  Neponset  St.,  Worcester  6,  Mass. 
260  S.  Broad  St.,  Philadelphia  1,  Pa.  (Port  Arthur, 

Tex.). 
9th  and  Market  Sts.,  Wilmington,  Del.  (Atlas  Point, 

Del,,  and  Reynolds,  Pa.). 
P.O.  Box  1786,  Shreveport,  La, 
142  Lockwood  St.,  Newark  5,  N.  J. 
Coal  City,  111. 


158 


UNITED  STATES  TARIFF  COMMISSION 


TAHLE  27. --Synthetic  organic  chemicals:   Directory  of  manufacturers,    W53--Continue(1 


Name  of  company 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office) 


578 
540 
219 
281 
190 
263 
182 
151 
121 
455 
343 
211 
494 
478 
590 
569 
122 
335 
93 
381 
141 
449 


238 
471 
169 
212 
382 
264 
265 
163 


292 
103 
177 
606 
84 
123 
293 
239 
240 
434 
524 


60 
220 
294 
295 

56 
360 
425 
336 
366 
495 

34A 
213 
104 
75 
479 
201 
488 
597 
241 


386 
570 
296 
226 
512 


Atomic  Basic  Chemicals  Corp 

Augusta  Chemical  Co 

Azoplate  Corp 

Baker  Castor  Oil  Co 

Baker,  J.  T.,  Chemical  Co 

Taylor  Chemical  Div 

Baltimore  Paint  &  Color  Works- 
Barium  Reduction  Corp 

Bates  Chemical  Co-~ 

Belle  Alkali  Co 

Belle  Chemical  Co.,  Inc — 

Benzol  Products  Co 

Berk,  F.  W.,  &  Co.,  Inc 

Berkeley  Chemical  Corp 

Berkshire  Color  &  Chemical  Mfg.  Corp- 

Bersworth  Chemical  Co— — 

Bick  &  Co.,  Inc 

Bio-Process  Co.,  Div.  of  Armour  &  Co- 
Bios  Laboratories,  Ino 

Bird  Sc  Son,  Inc 


Blackman  Brands,  Ino- 
Booty  Resineers,  Inc- 
Borden  Co.,  Chemical  Div- 


Bristol  Laboratories,  Inc 

Brooklyn  Color  Works,  Ino 

Brovm  Co 

Bruder,  M.  A.,  &  Sons,  Ino 


Bryant  Chemical  Corp- 
Buckeye  Cotton  Oil  Co- 
B\irkart-Schier  Chemical  Co- 


Burroughs-Wellcome  &  Co.  (U.S.A.), 
Inc. 

Cabot,  Godfrey  L.,  Inc — 

Cabot,  Samuel,  Inc — — 

Cadet  Chemical  Corp 

Calabama  Chemical  Co~ 


California  Flaxseed  Products  Co 

California  Ink  Co.,  Inc 

California-Spray  Chemical  Corp 

Callison,  I.  P.,  &  Sons,  Ino 

Cargill,  Inc.,  Falk  Div- 
Carlisle  Chemical  Works,  Inc — 
Carolina  Aniline  &  Extract  Co- 
Carpenter-Morton  Co 

Carus  Chemical  Co.,  Inc- 
Carwin  Co — 


Catalin  Corp.  of  America- 
Celanese  Corp.  of  America- 


Marco  Products  Div  . 

Chaffardon,  J 

Chase  Chemical  Corp 

Chemical  Manufacturing  Co.,  Inc- 
Chemical  Process  Co — • 


Chemico,  Inc 

Chemo-Puro  Manufacturing  Corp 

Childs  Pulp  Colors,  Ino 

Ciba  Pharmaceutical  Products,  Inc- 
Ciba  States,  Ltd.,  Toms  River  Div- 
Cinoinnati  Chemical  Works,  Inc 


Cities  Service  Oil  Co- 


Cities  Service  Refining  Corp.  (R.  R.)^ 

Citro  Chemical  Co 

City  Chemical  Corp 

Cleary,  W.  A.,  Corp —————— 

Clinton  Foods,  Ino — — 

Coastwise  Petroleum  Co 

Cockerille,  F.  0 

Colgate-Palmolive  Co 


Collett-Week-Nlbecker, 

Collway  Colors,  Inc 

Colton  Chemical  Co 

Colt ' s  Manufacturing  Co- 


Columbia  Organic  Chemicals,  Ino- 
See  footnote  at  end  of  table. 


350  Delwar  Rd.,  Pittsburgh  36,  Pa. 

Box  660,  Augusta,  Ga. 

Morris  Ave.  and  Weaver  St.,  Summit,  N.  J. 

120  Broadway,  New  York  5,  N.  Y.  (Bayonne,  N.  J.). 

600  N.  Broad  St.,  Phillipsburg,  N.  J. 

600  N.  Broad  St.,  Phillipsburg,  N.  J.  (Penn  Yan,  N.  Y.). 

2325  Annapolis  Ave.,  Baltimore  30,  Md. 

P.O.  Box  8097,  S.  Charleston  3,  W.  Va. 

Scottdale  Rd.,  Lansdowne,  Pa. 

P.O.  Box  615,  Belle,  W.  Va. 

534  Pearl  St.,  Reading,  Pa. 

237  South  St.,  Newark  5  (Piscataway),  N.  J. 

Park  PI.,  E.,  Wood-Ridge,  N.  J. 

Summit  Ave.,  Berkeley  Heights,  N.  J, 

250  Delawanna  Ave.,  Delawanna,  N.  J. 

875  Waver ly  St.,  Framingham,  Mass. 

1820  N.  12th  St.,  Reading,  Pa. 

P.O.  Box  1411,  Joliet,  111. 

17  W.  60th  St.,  New  York  23,  N.  Y. 

East  Walpole  (Norwood),  Mass. 

Wesley  St.,  S.  Hackensack,  N.  J. 

112  Jefferson  St.,  Newark,  Ohio. 

350  Madison  Ave.,  New  York  17,  N.  Y.  (Demopolis,  Ala.; 

Dominguez,  Calif.;  Union,  111.;  Bainbridge,  N.  Y.; 

Kernersville,  N.  C;  Springfield,  Ore.;  Philadelphia, 

Pa.;  and  Seattle,  Wash.). 
P.O.  Box  657,  Syracuse  1,  N.  Y. 
681  Morgan  Ave.,  Brooklyn  22,  N.  Y. 
650  Main  St.,  Berlin,  N.  H. 
52d  and  Grays  Ave.,  Philadelphia  43,  Pa. 
6  North  St.,  N.  Quincy  71,  Mass. 
P.O.  Box  539,  Cincinnati  1,  Ohio. 
Chestnut  St.  at  13th,  Chattanooga  2,  Tenn. 
Main  St.,  Tuckahoe  7,  N.  Y. 

77  Franklin  St.,  Boston  10  (Cambridge),  Mass. 

141  Milk  St.,  Boston  9  (Chelsea),  Mass. 

717  Elk  St.,  Buffalo  5,  N.  Y. 

P.O.  Box  147,  Huntsville  1,  Ala. 

3135  E.  26th  St.,  Los  Angeles  23,  Calif. 

545  Sansome  St.,  San  Francisco  11  (Berkeley),  Calif. 

Lucas  and  Ortho  Way,  Richmond  4,  Calif. 

801  Lloyd  Bldg.,  Seattle  1,  Wash. 

Rosslyn  Sta.,  Carnegie,  Pa. 

West  St.,  Reading  15,  Ohio. 

301  S.  Cedar  St.,  Charlotte  1,  N.  C. 

376  3d  St.,  Everett  49,  Mass. 

Box  364,  LaSalle,  111. 

Stiles  Lane,  North  Haven,  Conn. 

1  Park  Ave.,  New  York  16,  N.  Y.  (Calumet  City,  111.; 

Fords,  N.  J.;  and  Thomasville,  N.  C). 
180  Madison  Ave.,  New  York  16,  N.  Y.  (Amcelle,  Md.; 

Newark,  N.  J.;  Celxiver,  S.  C;  Bishop  and  Painpa, 

Tex.;  and  Celco,  Va.). 
290  Ferry  St.,  Newark  (Linden),  N.  J. 
209  Market  St.,  Lynn,  Mass. 
3527  Smallman  St.,  Pittsburgh  1,  Pa. 
Ashland,  Mass. 

901  Spring  St.,  Redwood  City,  Calif. 
2508  E.  Bailey  Rd.,  Cuyahoga  Falls,  Ohio. 
32-25  Queens  Blvd.,  Long  Island  City  1,  N.  Y. 
43  Summit  St.,  Brooklyn  31,  N.  Y. 
556  Morris  Ave.,  Summit,  N.  J. 
P.O.  Box  71,  Toms  River,  N.  J. 
P.O.  Box  20,  Evanston  Sta.,  Cincinnati  7  (Norwood 

and  St,  Bernard),  Ohio. 
Masonic-Empire  Bldg.,  Bartlesville  (Tallant),  Okla. 
716  Hodges  St.,  Lake  Charles,  La. 
199  Maywood  Ave.,  Maywood,  N.  J. 

132  W.  22d  St.,  New  York  11,  N.  Y.  (Jersey  City,  N.  J.). 
New  Brunswick  (Franklin  Township),  N.  J. 
Clinton,  Iowa. 

1127  Munsey  Bldg.,  Baltimore  2,  Md.  (Goodhope,  La.). 
Greenwood,  Va. 
105  Hudson  St.,  Jersey  City  2,  N.  J.  (Berkeley, 

Calif.;  Jeffersonville,  Ind.;  Kansas  City,  Kane.; 

and  Jersey  City,  N.  J.). 
Quimby  St.,  Osslning,  N.  Y. 
15  Market  St.,  Pater son  1,  N.  J. 
1545  E.  I8th  St.,  Cleveland  14,  Ohio. 
17  Van  Dyke  Ave.,  Hartford  15,  Conn. 
600  Capitol  PI.,  Columbia  (Cedar  Terrace),  S.  C. 


1 


SYNTHETIC  ORGANIC  CHEMICALS,  I953 

TABLE  27. -Synthetic  organic  chemicals:   Directory  of  manufacturers ,    /953- -Continued 


159 


Name  of  company 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office) 


Commercial  Solvents  Corp 


Commonwealth  Color  &  Chemical  Co 

Continental-Diamond  Fibre  Co — 

Continental  Oil  Co-  - — 


Cook  Paint  &  Varnish  Co 

Coopers  Creek  Chemical  Corp 

Copolymer  Corp.  (R.  R.)''' 

Com  Products  Refining  Co 

Cosden  Petroleum  Corp— — — — 

Crosby  Chemicals,  Ino— 

Crown  Central  Petroleum  Corp 

Crown  Chemical  Corp 

Crown  Chemical  Div.  of  Joseph  Turner 
&   Co. 

Crownoil  Chemical  Co.,  Inc 

Crown  Tar  &  Chemical  Works,  Inc 

Cutter  Laboratories 


Dakota  Briquets  &  Tar  Products,  Ino- 

Davis,  H.  B.,  Co 

Dawe's  Laboratories,   Inc 

Deecy  Products  Co 

Delaware  Chemicals,  Inc 

Delta  Chemical  Works 


DePaul  Chemical  Co.,  Ino 

DePree  Co 


DeVoe  &  Raynolds  Co.,  Inc. 

Dabney  Co.  Div. 
Dewey  &  Alray  Chemical  Co — 

Dexter  Chemical  Corp 

Diamond  Alkali  Co 


Diamond  Alkali  Organic  Chemicals 
Div.,  Inc. 

Dodge  &  Olcott,  Ino 

Dominion  Products,  Inc 

Douglas  Chemical  Corp 
Dow  Chemical  Co 


Dow  Chemical  Co.,  Styrene  Div. 

(R.  R.).i 
Dow  Corning  Corp  — 

Drew,  E.  F.,  &  Co.,  Ino 

Drug  Processors,  Inc 

duFont  de  Nemours,  E.  I,,  &  Co, 


Durez  Plastics  &   Chemicals,  Inc- 

Dye  Specialties  Corp.,  Ino 

Dykem  Co —____ 

Eakins,  J.  S.  &  W.  R.,  Ino 

Eastern  States  Chemical  Corp 

Eastman  Kodak  Co 


Tennessee  Eastman  Co.  Dlv- 

Texas  Eastman  Co.  Div 

Edcan  Laboratories———— 


Edison,  Thomas  A.,  Inc.,  Medical  Gas 
Div. 

El  Dorado  Oil  Works 

Elizabethtown  Consolidated  Gas  Co 

Emery  Industries,  Inc 

Emkay  Chemical  Co—- 

Emulsol  Corp 

Endo  Products,  Inc 

Esso  Standard  Oil  Co- 
Louisiana  Div 

Ethyl  Corp 


Ethyl-Dow  Chemical  Co 
Evans  Chemetics,  Inc 

Fairmont  Chemical  Co.,  Ino 

Farley  &  Loetsoher  Manufacturing  Co- 
Farmers  '  Chemical  Co 
Farrington,  W,  U.,  Estate  of 
Federal  Color  Laboratories,  Inc 


See  footnote  at  end  of  table. 


260  Madison  Ave.,  New  York  16,  N.  Y.  (Agnew,  Calif.; 

Peoria,  111.;  Terre  Haute,  Ind.;  Harvey  and 

Sterlington,  La.;  and  Carlstadt,  N.  J.). 
3240  Grace  Ave.,  New  York  69,  N.  Y. 
70  S.  Chapel  St.,  Newark,  Del.  (Bridgeport,  Pa.). 
1000  S.  Pine  St.,  Ponca  City,  Okla. 
P.O.  Box  389,  Kansas  City  41,  Mo. 
River  Rd.,  W.  Conshohocken,  Pa, 
P.O.  Box  1029,  Baton  Rouge  1,  La. 
17  Battery  PI.,  New  York  4,  N.  Y.  (Argo,  111.). 
P.O.  Box  1311,  Big  Spring,  Tex. 
Box  32,  De  Rldder,  La.  (Picayune,  Miss.). 
American  Bldg.,  Baltimore  2,  Md.  (Pasadena,  Tex.). 
240  India  St.,  Providence  3,  R.  I. 
Pleasantvlew  Terrace,  Ridgefield,  N.  J. 

2-14  49th  Ave.,  Long  Island  City  1,  N.  Y. 

900  Wewatta  St.,  Denver  4,  Colo. 

4th  and  Parker  Sts.,  Berkeley  1,  Calif. 

Dickinson,  N.  Dak. 

Bayard  &  Severn  Sts.,  Baltimore  2,  Md. 

4S0O  S.  Richmond  St.,  Chicago  32,  111.  (Newaygo,  Mich.). 

120  Potter  St.,  Cambridge  42,  Mass. 

50  Murray  St.,  Staten  Island  9,  N.  Y. 

23  W.  60th  St.,  New  York  23,  N.  Y. 

44-27  Purvis  St.,  Long  Island  City  1,  N.  Y. 

130  Central  Ave.,  Holland,  Mich. 

1481  S.  11th  St.,  Louisville  8,  Ky. 

62  Whittemore  Ave.,  Cambridge  40  (Acton),  Mass. 

819  Edgewater  Rd.,  New  York  59,  N.  Y. 

300  Union  Commerce  Bldg.,  Cleveland  14,  Ohio  (Painesville, 

Ohio,  and  Houston,  Tex.). 
80  Lister  Ave.,  Newark  5,  N.  J. 

180  Variok  St.,  New  York  14,  N.  Y.  (Bayonne,  N.  J.). 

10-40  44th  Dr.,  Long  Island  City  1,  N.  Y. 

1624  Darrow  Ave.,  Evanston,  111. 

Midland,  Mich.  (Pittsburg,  Calif.;  Gales  Ferry, 

Conn.;  and  Freeport,  Tex.). 
P.O.  Box  500,  Gardena  (Los  Angeles),  Calif. 

Box  592,  Midland,  Mich. 

15  E.  26th  St.,  New  York  10,  N.  Y.  (Boonton,  N.  J.). 
1219  E.  Church  St.,  Adrian,  Mich. 

10th  and  Market  Sts.,  Wilmington  '"  ',,  Del.  (Newport 
and  Wilmington,  Del.;  E.  Chicago,  Ind.;  Louisville, 
Ky. ;  Wyandotte,  Mich.;  Arlington,  Carney's  Point, 
Deepwater,  Glbbstown,  Grasselli,  Newark,  New 
Brunswick,  Parlln,  and  Perth  Amboy,  N.  J.;  Dresden 
and  Niagara  Falls,  N.  Y.;  Toledo,  Ohio;  Philadelphia, 
Pa.;  Memphis,  Tenn.;  Houston,  Orange,  and  Victoria, 
Tex.;  and  Belle  and  Parkersburg,  W.  Va.). 

Walok  Rd.,  N.  Tonawanda,  N.  Y. 

26  Journal  Sq.,  Jersey  City  6,  N.  J. 

2307  N.  11th  St.,  St.  Louis  6,  Mo. 

55  Berry  St.,  Brooklyn  11,  N.  Y. 

8938  Manchester  Ave.,  Houston  12,  Tex. 

343  State  St.,  Rochester  4,  N.  Y. 

Eastman  Rd.,  Kingsport,  Tenn. 

P.O.  Box  2068,  Longview,  Tex. 

10  Pine  St.,  South  Norwalk,  Conn. 

P.O.  Box  15,  Stuyvesant  Falls,  N.  Y. 

311  California  St.,  San  Francisco  4  (Oakland),  Calif. 

16  W.  Jersey  St.,  Elizabeth  4,  N.  J. 
4300  Carew  Tower,  Cincinnati  2,  Ohio. 
319  2d  St.,  Elizabeth  1,  N.  J. 

59  E.  Madison  St.,  Chicago  3,  111. 

84-«)  101st  St.,  Richmond  Hill  18,  N.  Y. 

P.O.  Box  23,  Linden,  N.  J. 

P.O.   Box  551,  Baton  Rouge  1,  La. 

100  Park  Ave.,   New  York  17,  N.  Y.    (Baton  Rouge,  La.; 

Orangeburg,  S.  C;  and  Pasadena,  Tex.). 
Midland,  Mich.  (Freeport,  Tex.). 
250  E.  43d  St.,  New  York  17  (Waterloo),  N.  Y, 
600  Ferry  St.,  Newark  5,  N.  J. 
7th  and  White  Sts,,  Dubuque,  Iowa. 
P.O.  Box  591,  Kalamazoo,  Mich. 
Box  389,  E.  Greenwich  (Warwick),  R.  I. 
4633  Fcrest  Ave.,  Norwood  12,  Ohio. 


160  UNITED  STATES  TARIFF  COMMISSION 

TABLE  27. --Synthetic  organic  chemicals:    Directory  of  manufacturers,    J95J- -Continued 


2U 
598 
A66 
117 
282 
591 
505 
125 
2A2 

572 
225 

128 
139 


490 
431 
414 
297 
557 
132 
394 
550 

180 
346 


228 
85 

221 

273 
137 

153 
13 
154 
229 
395 


183 
459 
563 


396 
347 
170 
283 
279 
109 
209 
2 
383 
262 
-420 
34 


86 
440 


348 
349 


Name  of  company 


Federal  Paint  Co.,  Ino 

Felton  Chemical  Co.,  Inc 

Ferro  Chemical  Corp 

Fiber  Chemical  Corp 

Fine  Colors  Co — 

Fine  Organlcs,  Inc 

Finetex,  Inc 

Firestone  Tire  6  Rubber  Co.  (R. 
Firestone  Tire  &  Rubber  Co., 
Firestone  Plastics  Co.  Div. 
Fisher  Scientific  Co 


R.)i- 


Florasynth  Laboratories,   Inc 

Food  Machinery  &.  Chemical  Corp.: 
Ohio-Apex  Div- 


Pine  Bluff  Chemical  Co- 
Westvaco  Chemical  Div — 


Ford  Motor  Corp— 

Foster-Heaton  Co 

France,  Campbell  4:  Darling,  Inc 

Fritzsche  Brothers,  Inc 

Fuller,  W.  P.,  &  Co 

Gallowhur  Chemical  Corp — 

Gamma  Chemical  Corp — ~ 

Gane's  Chemical  Works,  Inc 

General  Aniline  Sc  Film  Corp.,  Dyestuff 
&  Chemical  Div. 

General  Color  Co.,  Ino 1— — 

General  Electric  Co.,  Chemical  Div 


General  Foods  Corp.,  Maxwell  House 

Div. 

General  Mills,  Inc 

General  Motors  Corp.,  AC  Spark  Plug 

Div. 

General  Petroleum  Corp 

General  Tire  &  Rubber  Co.  (R.  R.)-'- — 
General  Tire  &  Rubber  Co.,  Chemical 

Div. 

Genesee  Research  Corp 

George,  P.  D.,  Co 

Oilman  Paint  &  Varnish  Co 

Givaudan  Corp — -— 

Glidden  Co 


Glyco  Products  Co.,  Inc 
Goodrich,  B.  F.,  Co.: 

Goodrich,  B.  F,,  Chemical  Co.  Div. 
(R.  R.).' 

Goodrich,  B.  F.,  Chemical  Co.  Div- 


Goodyear  Tire  &  Rubber  Co- 
Grain  Processing  Corp 

Grand  Rapids  Varnish  Corp- 
Great  Southern  Chemical  Corp- 


Greenwood  Textile  Supply  Co- 
Griffin  Chemical  Co 

Gulf  Oil  Corp 

Guyan  Color  &  Chemical  Works — 

Halby  Products  Co — 

Hall,  C.  P.,  Co.  of  Illlnois— 

Harapden  Color  &  Chemical  Co 

Hanna  Paint  Manufacturing  Co., 

trial  Div. 
Harbor  Plywood  Corp- 
Hardesty,  W.  C,  Co.,  Inc- 
Harshaw  Chemical  Co 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office) 


Harsyd  Chemicals,  Inc- 

Hart  Products  Corp 

Hartman-Leddon  Co— — — 
Hercules  Powder  Co— — 


Heresite  &  Chemical  Co- 


Hexagon  Laboratories,  Ino- 
See  footnote  at  end  of  table. 


33  Rector  St.,  New  York  6,  N.  Y. 

599  Johnson  Ave.,  Brooklyn  37,  N.  Y. 

450  Krick  Rd.,  Bedford,  Ohio. 

P.O.  Box  218,  Matawan  (Cliffwood),  N.  J. 

21-29  McBride  Ave.,  Paterson  1,  N.  J. 

211  E.  19th  St.,  New  York  3,  N.  Y.  (Lodi,  N.  J.). 

Box  414,  Pompton  Plains,  N.  J. 

381  W.  Wilbeth  Rd. ,  Akron  1,  Ohio. 

P.O.  Box  690,  Pottstown,  Pa. 

635  Greenwich  St.,  New  York  14,  N.  Y. 
900  Van  Nest  Ave.,  New  York  62,  N.  Y. 

Nitro,  W.  Va. 

100  Niagara  St.,  Middleport,  N.  Y.  (Arsenal,  Ark.). 

161  E.  42d  St.,  New  York  17.  N.  Y.  (Newark,  Calif., 

and  S.  Charleston,  W.  Va.). 
3000  Schaefer  Rd.,  Dearborn  (Highland  Park),  Mich. 
16  E.  5th  St.,  Paterson  4,  N.  J. 
Michigan  Ave.,  Kenilworth,  N,  J. 

271  Church  St.,  New  York  13,  N.  Y.  (Bloomfield,  N.  J.). 
76  9th  Ave.,  New  York  11,  N.  Y.  (Clifton,  N.  J.). 
301  Mission  St.,  San  Francisco  19,  Calif. 
801  2d  Ave.,  New  York  25  (Ossining),  N.  Y. 
220  E.  42d  St.,  New  York  17,  N.  Y.  (Great  Meadows,  N.  J.). 
677  5th  Ave.,  New  York  22,  N.  Y.  (Carlstadt,  N.  J.). 
435  Hudson  St.,  New  York  14,  N.  Y.  (Linden,  N.  J., 

and  Rensselaer,  N.  Y.). 
24  Ave.  B,  Newark  5,  N.  J. 
1  Plastics  Ave.,  Pittsfield,  Mass.  (Anaheim,  Calif.; 

Pittsfield,  Mass.;  Schenectady  and  Waterford,  N.  Y.; 

and  Coshocton,  Ohio) . 
1125  Hudson  St.,  Hoboken,  N.  J. 

400  2d  Ave.,  S,,  Minneapolis  1,  Minn, 
1300  N.  Dort  Highway,  Flint  2,  Mich. 

P.O.  Box  2122,  Terminal  Annex,  Los  Angeles  54,  Calif. 

Baytown,  Tex. 

1708  Englewood  Ave.  at  Holmes,  Akron  (Mogadore) ,  Ohio. 

961  Lyell  Ave.,  Rochester  6,  N.  Y. 

5200  N.  2d  St.,  St.  Louis  7,  Mo. 

216  W.  8th  St.,  Chattanooga  1,  Tenn. 

109-201  Delawanna  Ave.,  Delawanna,  N.  J, 

11001  Madison  Ave.,  Cleveland  2,  Ohio  (San  Francisco, 

Calif.;  Jacksonville,  Fla.;  Chicago,  111.; 

Minneapolis,  Minn.;  Cleveland,  Ohio;  and  Heading, 

Pa.). 

26  Court  St.,  Brooklyn  1,  N.  Y.  (Williamsport,  Pa.). 

324  Rose  Bldg.,  Cleveland  15,  Ohio  (Port  Neches, 

Tex.,  and  Institute,  W.  Va.). 
Rose  Bldg.,  2060  E.  9th  St.,  Cleveland  15,  Ohio 

(Calvert  City  and  Louisville,  Ky. ;  Haledon  and 

Kearny,  N.  J.;  Niagara  Falls,  N.  Y.;  and  Akron 

and  Avon  Lake  Village,  Ohio). 
1144  E.  Market  St.,  Akron  16,  Ohio. 
1600  Oregon  St.,  Muscatine,  Iowa. 
1350  Steele  Ave.,  SW.,  Grand  Rapids  2,  Mich. 
P.O.  Box  4166,  Corpus  Christi,  Tex. 

27  Meadow  St.,  Apponaug,  R.  I. 

1000  16th  St.,  San  Francisco  7  (Richmond),  Calif. 

Gulf  Bldg.,  Pittsburgh  30,  Pa. 

Box  1088,  Huntington,  W.  Va. 

P.O.' Box  366,  Wilmington  99,  Del. 

5145  W.  67th  St.,  Chicago  38,  111. 

5  Albany  St.,  Springfield  1,  Mass. 

95  W.  Long  St.,  Columbus  15,  Ohio. 

Box  940,  Aberdeen,  Wash. 

P.O.  Box  148,  Newark,  N.  J.  (Dover,  Ohio). 

1945  E.  97th  St.,  Cleveland  6,  Ohio  (Gloucester 

City,  N.  J.). 
397  W.  21st  St.,  Holland,  Mich. 

1440  Broadway,  New  York  18,  N.  Y.  (Jersey  City,  N.  J.), 
5821  Market  St.,  Philadelphia  39,  Pa. 
900  Market  St.,  Wilmington  99,  Del.  (Savannah,  Ga. ; 

Mansfield,  Mass.;  Hattlesburg,  Miss.;  Burlington 

and  Parlin,  N.  J.;  and  Hopewell,  Va.). 
822  S.  14th  St.,  Manitowoc,  Wis. 
3536  Peartree  Ave.,  New  York  69,  N.  Y. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 

TABLE  27. -Synthetic  organic  chemicals:   Directory  of  manufacturers ,    7953 --Continued 


161 


Name  of  company 


Heyden  Chemical  Corp 

Hof f mann-LaRoohe ,  Ino 

Hoffman-Taff,  Inc 

Holland  Color  &  Chemical  Co 

Hooker-Detrex ,  Ino 

Hooker  Electrochemical  Co 

Houghton,  E.  F.,  &  Co 

Huggins,  James,  &  Son,  Inc 

Humble  Oil  &  Refining  Co 

Humble  Oil  &   Refining  Co.  (R.  R.)^ 

Huiiiphrey-Wllkinson,   Inc 

Huron  Milling  Co 

Hyman,  Julius,  &  Co 

Hynson,  Westcott  &  Dunning,  Inc 

Imperial  Paper  &   Color  Corp.,  Pigment 

Color  Div. 

Indoll  Chemical  Corp 

Industrial  Dyestuff  Co 

Industrial  Products,  Ino 

Inland  Alkaloid  Co 

Inland  Steel  Container  Cc  

Interohemical  Corp.: 

Finishes  Div 


506 
65 
«1 
<192 
432 
164 


Office  address  (location  of  plant  given  in 
parentheses  if  not  In  same  city  as  office) 


Textile  Colors  Div 

International  Minerals  &   Chemical 

Corp. 
Ironsides  Co- 


Irvington  Varnish  &  Insulator  Co.  Div. 
of  Minnesota  Mining  &  Manufacturing 
Co. 

Jefferson  Chemical  Co.,  Inc 

Jennieon-Wright  Corp 

Johnson,  Charles  Eneu,  Co.,  Inc 

Jordan,  Jr.,  W.  H.,  &  F.,  Manu- 
facturing Co. 

Kali  Manufacturing  Co 

Kalide  Corp 

Kay-Fries  Chemicals,  Ino— 

Kehew-Bradley  Co 

Kendall  Refining  Co 

Kenneoott  Copper  Corp.: 

Chino  Mines  Div 

Utah  Copper  Div 

Kentucky  Color  &  Chemical  Co 

Kentucky  Synthetic  Rubber  Corp. 
(R.  R.).i 

Kessler  Chemical  Co.,  Ino 

Keystone  Chemurgic  Corp 

Keystone  Color  Works,  Inc 


Keystone  Paint  &  Varnish  Corp 

Knoedler  Chemical  Co—— -— 

Kohnstamm,  H.,  &  Co.,  Ino — — — 

Koppers  Co.,  Inc.: 

Chemical  Div 


Tar  Products  Div- 


Krumbhaar  Chemical  Co.,  Inc.— 

Kyanize  Paints,  Ino 

Lakeside  Laboratories,  Ino 

LaMotte  Chemical  Products  Co— 
LaSalle  Chemical  Corp — — — 
Laurel  Soap  Manufacturing  Co., 

Leatex  Chemical  Co 

Lebanon  Chemical  Corp  — 
Lebec  Chemical  Corp  — 
Leff Inguell  Chemical  Co 


342  Madison  Ave.,  New  York  17,  N.  Y.  (Fords,  Garfield, 

and  Princeton,  N.  J.). 
324-424  Kingslamd  Rd.,  Nutley  10,  N.  J. 
W.  Bennett  Street  Rd.,  Springfield,  Mo. 
Holland,  Mioh. 
Buffalo  Ave.  &  47th  St.,  Niagara  Falls,  N.  Y. 

(Ashtabula,  Ohio,  and  Taooma,  Wash.). 
Buffalo  Ave.  &  47th  St.,  Niagara  Falls,  N.  Y. 

(Taooma,  Wash.). 
303  W.  Lehigh  Ave.,  Philadelphia  33,  Pa. 
239  Medford  St.,  Maiden  48,  Mass. 
P.O.  Box  2180,  Houston  1  (Baytown),  Tex. 
P.O.  Box  4321,  Baytown,  Tex. 
DeVine  St.,  North  Haven,  Conn. 

9  Park  PI.,  New  York  7,  N.  Y.  (Harbor  Beach,  Mich.). 
P.O.  Box  2171,  Denver  1,  Colo. 
1030  N.  Charles  St.,  Baltimore  1,  Md. 
P.O.  Box  231,  Glens  Falls,  N.  Y. 

910  S.  Michigan  Ave.,  Chicago  80,  111.  (Whiting,  Ind.). 

Massasoit  Ave.,  E.  Providence  14,  R.  I. 

215  S.  Laurens  St.,  Greenville,  S.  C. 

Tipton,  Ind. 

6532  S.  Menard  Ave.,'  Chicago  38,  111. 

224  MoWhorter  St.,  Newark  1,  N.  J.  (Los  Angeles, 
Calif.;  Elizabeth  and  Newark,  N.  J.;  and 
Cincinnati,  Ohio). 

150  Wagaraw  Rd.,  Hawthorne,  N.  J. 

20  N.  Waoker  Dr.,  Chicago  6,  111.  (San  Jose,  Calif.; 
Niagara  Falls,  N.  Y.;  and  Rossford,  Ohio). 

270  W.  Mound  St.  (P.O.  Box  1999),  Columbus  16,  Ohio. 

6  Argyle  Ter.,  Irvington  11  (Newark),  N.  J. 


260  Madison  Ave.,  New  York  16,  N.  Y.  (Port  Neohes,  Tex.). 

2463  Broadway,  Toledo  9,  Ohio. 

10th  Sc  Lombard  Sts.,  Philadelphia  47,  Pa. 

2126  E.  Somerset  St.,  Philadelphia  34,  Pa. 

427  E.  Moyer  St.,  Philadelphia  25,  Pa. 

S.  Canal  St.,  Lawrence,  Mass. 

180  Madison  Ave.,  New  York  16  (West  Haverstraw),  N.  Y. 

40  Oliver  St.,  Boston  10  (Everett),  Mass. 

77  N.  Kendall  Ave.,  Bradford,  Pa. 

Hurley,  N.  Mex. 

Keams  Bldg.,  Salt  Lake  City  1  (Garfield),  Utah. 
600  t\   34th  St.,  Louisville  12,  Ky. 
Louisville,  Ky. 

State  Rd.  and  Cottman  Ave.,  Philadelphia  35,  Pa. 

R.  D.  # 1,  Bethlehem,  Pa. 

151  W.  Gay  Ave.,  York,  Pa. 

71  Otsego  St.,  Brooklyn  31,  N.  Y. 

651  High  St.,  Lancaster  1,  Pa. 

83-93  Park  PI.,  New  York  7  (Brooklyn),  N.  Y. 

Koppers  Bldg.,  430  7th  Ave.,  Pittsburgh  19,  Pa. 

(Berkeley  Heights  and  Kearny,  N.  J.;  Kobuta,  Monaca, 
Oil  City,  and  Petrolia,  Pa.;  and  Port  Arthur,  Tex.). 

Koppers  Bldg.,  430  7th  Ave.,  Pittsburgh  19,  Pa. 
(Woodward,  Ala.;  Fontana,  Calif.;  New  Haven, 
Conn.;  Chicago  and  East  St.  Louis,  111.;  Chalmette, 
La.;  Portland,  Maine;  Everett  and  Westfield,  Mass.; 
St.  Paul,  Minn.;  St.  Louis,  Mo.;  Kearny  and 
Westfield,  N.  J.;  Buffalo,  Rochester,  and  Utica,  N.  Y. 
Hamilton,  Warren,  Eind  Youngstown,  Ohio;  Swedeland  and 
Swissvale,  Pa.;  E.  Providence,  R.  I.;  Memphis,  Tenn.; 
Houston,  Tex. ;  Follansbee,  W.  Va. ;  and  Carrollville, 
Wis.). 

24-30  Jacobus  Ave.,  S.  Kearny,  N.  J. 

2d  &  Boston  Sts.,  Everett  49,  Mass. 

1707  E.  North  Ave.,  Milwaukee  1,  Wis. 

Towson  4,  Md. 

Fox  Island  Rd.,  Port  Chester,  N.  Y. 

Tioga  &  Thompson  Sts.,  Philadelphia  34,  Pa. 

2722  N.  Hancock  St.,  Philadelphia  33,  Pa. 

P.O.  Box  532,  Lebanon,  Pa. 

14066  S.  Garfield  Ave.,  Paramount,  Calif. 

P.O.  Box  191,  Whittier,  Calif. 


See  footnote  at  end  of  table. 


162  UNITED  STATES  TARIFF  COMMISSION 

TABLE  27. --Synthetic  organic  chemicals:   Directory  of  manufacturers,    1953--Continued 


389 
191 
-133 
172 
585 
442 
513 


230 
399 

88 
500 
231 
165 

19 

67 
111 

37 
112 

U 
119 
562 
430 

522 
301 
552 
274 
361 
110 
514 
515 

232 

289 

324 

325 

15 

68 

89 

181 

544 

602 

173 

38 

138 

351 

95 

245 


144 
574 
390 

284 
516 
96 
233 
326 
463 
371 

592 
184 


90 
205 
327 
285 
519 


145 

10 

446 

57 


Name  of  company 


Lemte,  B.  L.,  &  Co.,  Inc 

Lever  Brothers  Co 

Lever,  C,  Co.,  Inc 

Levey,  Fred'k.  H.,  Co.,  Inc 

Lewis  Tar  Products  Co 

Lilly,  Eli,  &  Co 

Lobioa-Debruille,  Inc         — 

Long,  Chas.  R.,  Jr.,  Co 

Loven  Chemical  Co.  of  Califomia- 

Lubrizol  Corp 

Lueders,  George,  Sc   Co 

Maas  &  Waldstein  Co 

Magnolia  Petrolevim  Co 

Magruder  Color  Co.,  Inc 

Mallinckrodt  Chemical  Works 

Maltbie  Laboratories,  Inc 

Marathon  Corp.,  Chemical  Div 

Marblette  Corp ________ 

Marbon  Corp 

Marden-Wild  Corp — • 


Marlowe-Van  Loan  Corp 

Marrow ' s ,  Inc 

Marx,  Max,  Color  &  Chemical  Co 

Maschmeijer,  A.,  Jr.,  Inc 

Mathieson  Chemical  Corp 


Squibb,  E.  R.,  &  Sons  Div- 

Maumee  Chemical  Co ■  ■  ■■ 

May,  Otto  B.,  Inc- 
Maywood  Chemical  Works- 

McCloskey  Varnish  Co 

McGean  Chemical  Co- 
Medioal  Chemicals  Corp- 
Merck  &  Co.,  Inc 


Merichem  Co ___ 

Merrell,  Wm.  S.,  Co 

Meta  Chemical  Corp 

Metalsalts  Corp 

Metro-Atlantic,  Inc 

Metro  Dyestuff  Corp : 

Meyer,  J.,  &  Sons _-_— _ 

Michigan  Chemical  Corp 

Midland  Industrial  Finishes  Co 

Midland  Synthetic  Rubber  Co.  (R.  R.)^ 
Miles  Laboratories,  Inc 

Mineral  Oil  Refining  Co 

Minnesota  Paints,  Inc 

Miranol  Chemical  Co.,  Inc 

Modene  Paint  Co.,  Inc 

Monsanto  Chemical  Co 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office) 


Montclalr  Research  Corp- 
Montrose  Chemical  Co — 
Montrose  Chemical  Corp.  of 

California. 
Moreland  Chemical  Co.,  Inc- 
Morton-Withers  Chemical  Co- 
Morwear  Paint  Co 


National  Biochemical  Co 

National  Chlorophyll  &  Chemical  Co 
National  Distillers  Products  Corp- 
National  Lead  Co 


National  Petro-Chemioals  Corp 

National  Starch  Products,  Inc 


Neches  Butane  Products  Co.  (R.  R.)^- 

Nepera  Chemical  Co.,  Inc 

Neville  Chemical  Co 


Newport  Industries,  Inc 

New  York  Color  &  Chemical  Co.,  Div. 

of  American  Dyewood  Co. 
New  York  Quinine  4  Chemical  Works, 

Inc. 

Niagara  Alkali  Co 

Nilok  Chemicals,  Inc 

Ninol  Laboratories,  Inc 

Nonweller,  A.  P.,  Co 


199  Main  St.,  Lodi,  N.  J. 

390  Park  Ave.,  New  York  22,  N.  Y. 

Howard  and  Huntington  Sts.,  Philadelphia  33,  Pa. 

380  Madison  Ave.,  New  York  17  (Brooklyn),  N.  Y. 

P.O.  Box  A,  Lyons  (MoCook),  111. 

740  S.  Alabama  St.,  Indianapolis  6,  Ind. 

1841  Broadway,  New  York  23,  N.  Y. 

1630  W.  Hill  St.,  Louisville  10,  Ky. 

244  Pine  St.,  Newhall,  Calif. 

Cleveland  17,  Ohio. 

427  Washington  St.,  New  York  13  (Brooklyn),  N.Y. 

2121  McCarter  Hwy. ,  Newark  4,  N.  J. 

P.O.  Box  900,  Dallas  21  (Beaumont),  Tex. 

2385  Richmond  Ter.,  Staten  Island  2,  N.  Y. 

3600  N.  2d  St.,  St.  Louis  7,  Mo.  (Jersey  City,  N.  J.).  ' 

240-250  High  St.,  Newark  1,  N.  J. 

Rothschild,  Wis. 

37-21  30th  St.,  Long  Island  City  1,  N.  Y. 

1926  W.  10th  Ave.,  Gary,  Ind. 

500  Columbia  St.,  Somerville  43,  Mass. 

1511  Byrum  St.,  High  Point,  N.  C. 

657  W.  Chicago  Ave.,  Chicago  10,  111. 

192  Coit  St.,  Irvington  11,  N.  J. 

43  W.  16th  St.,  New  York  11,  N.  Y.  (Newark,  N.  J.). 

10  Light  St.,  Baltimore  3,  Md.  (Brandenburg,  Ky. ; 

Niagara  Falls,  N.  Y. ;  and  Morgantown,  W.  Va.). 
745  5th  Ave.,  New  York  22,  N.  Y.  (New  Brunswick,  N.  J.). 
2  Oak  St.,  Toledo  5,  Ohio. 
52  Amsterdam  St.,  Newark  5,  N.  J. 

100  W.  Hunter  Ave.,  Maywood,  N.  J. 
7600  State  Rd.,  Philadelphia  36,  Pa. 
104O  Midland  Bldg.,  Cleveland  15,  Ohio. 
4122  W.  Grand  Ave.,  Chicago  51,  111. 

Lincoln  Ave.,  Rahway,  N.  J.  (Albany,  Ga.;  Danville,  Pa.; 

and  Elkton,  Va. ) . 
3101  Fannin  St.,  Houston  4  (Green's  Bayou),  Tex. 
Galbraith  Rd.  and  Pennsylvania  R.  R.,  Cincinnati  15,  Ohio. 
Washington  Ave.,  Carlstadt,  N.  J. 

200  Wagaraw  Rd.,  Hawthorne,  N.  J. 
2072  Smith  St.,  Centerdale  11,  R.  I. 

101  W.  Quidnick  St.,  West  Warwick,  R.  I. 
4321  N.  4th  St.,  Philadelphia  40,  Pa. 
500  N.  Bankson  St.,  St.  Louis,  Mich. 

E.  Water  St.,  Waukegan,  111. 

Los  Angeles,  Calif. 

Elkhart,  Ind. 

P.O.  Box  625,  Dickinson,  Tex. 

1101  S.  3d  St.,  Minneapolis  15,  Minn. 

277  Coit  St.,  Irvington  11,  N.  J. 

305  Eastern  Ave.,  Chelsea  50,  Mass. 

800  N.  12th  Blvd.,  St.  Louis  1,  Mo.  (Anniston,  Ala.; 
Long  Beach  and  Santa  Clara,  Calif.;  Monsanto,  111.; 
Everett  and  Springfield,  Mass.;  Trenton,  Mich.;  Texas 
City,  Tex.;  Seattle,  Wash.;  and  Nitro,  W.  Va.). 

4  Cherry  St.,  Monte lair,  N.  J. 

120  Lister  Ave.,  Newark  5,  N.  J. 

824  Wilshlre  Blvd.,  Los  Angeles  17  (Torrance),  Calif. 

P.O.  Box  1743,  Spartanburg,  S.  C. 

2110  High  Point  Rd.,  Greensboro,  N.  C, 

568  14th  St.,  Oakland  12,   Calif. 

3106  W.  Lake  St.,  Chicago  12,  111. 

Lamar,  Colo. 

See  U.  S.  Industrial  Chemicals  Co. 

Ill  Broadway,  New  York  6,  N.  Y.  (Perth  Amboy,  N.  J.,  and 

Philadelphia,  Pa.). 
Box  109,  Tuscola,  111. 
270  Madison  Ave.,  New  York  16,  N.  Y.  (San  Francisco, 

Calif.;  Chicago,  111.;  Indianapolis,  Ind.;  and 

Plainfield,  N.  J.). 
P.O.  Box  1535,  Port  Neches,  Tex. 
21  Gray  Oaks  Ave.,  Yonkers  2  (Harriman),  N.  Y. 
Neville  Island,  Pittsburgh  25,  Pa.  (Anaheim,  Calif.). 
P.O.  Box  911,  Pensacola,  Fla. 
Main  &   Joralemon  Sts.,  Belleville  9,  N.  J. 

50  Church  St.,  New  York  7,  N.  Y.  (Newark,  N.  J.). 

60  E.  42d  St.,  New  York  17  (Niagara  Falls).  N.  Y. 
2000  College  Ave.,  Niagara  Falls  (Lockport),  N.  Y. 
1719  S.  Clinton  St.,  Chicago  16,  111. 
Box  1007,  Oshkosh,  Wis. 


See  footnote  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 

TABLE  27. -Synthetic  organic  chemicals:    Directory  of  manufacturers ,    195 J- -Continued 


163 


Name  of  oorapany 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office) 


Napoo  Chemical  Co.,  Inc 

Norda  Essential  Oil  &  Chemical  Co. 
Inc. 

Northwestern  Chemical  Co 

Norwich  Pharmaoal  Co 


Nuodex  Products  Co. ,  Inc 

Ohio  Chemical  a  Surgical  Equipment 

Co.,  Div.  of  Air  Reduction  Co., 

Inc. 

Oil  &  Chemical  Products,  Inc 

Oldbury  Electro-Chemical  Co 

Old  Colony  Tar  Co.,  Inc 


Inc- 


Old  Hickory  Chemical  Co. 

Orbis  Products  Corp 

Organic  Chemical  Corp 

Organics,  Inc        ■   .. .  — 

Oronite  Chemical  Co 

Ortho  Chemical  Corp 

Oshom,  C.  J.,  Co 

Ottawa  Chemical  Co.,  Inc 

Ottol  Oil  Co 

Oxford  Corp 

Pabco  Products,  Inc 

Pabst  Brewing  Co 

Pacific  Paint  &  Varnish  Co 

Pan  American  Refining  Corp— — 

Parke,  Davis  &  Co———— 

Parsons,  M.  W.,  Plymouth,  Ino- 
Patent  Chemicals,  Inc- 


Pathfinder  Chemical  Corp.,  subsidiary 
of  Cioodyear  Tire  &  Rubber  Co. 

Paul-Lewis  Laboratories,  Inc — - 

Peck's  Products  Co 


Pedlow-Nease  Chemical  Co. 

Peerless  Chemical  Co 

Peerless  Color  Co. ,  Inc — 
Penick,  S.  B.,  &  Co 


Inc- 


Pennsylvania  Industrial  Chemical 
Corp. 

Pennsylvania  Refining  Co 

Pennsylvajiia  Salt  Manufacturing  Co- 
Perkins  Glue  Co 

Permutit  Co 


Peters  Chemical  Co 

Pfanstiehl  Chemical  Co 

Pflster  Chemical  Works,  Inc- 
Pflzer,  Charles,  &   Co.,  Inc- 


Pharma  Chemical  Corp 

Phillips  Petroleum  Co.  (R.  R.)^- 
Phoenix  Oil  Co 


Pitman-Moore  Co.,  Dlv.  of  Allied 

Laboratories,  Inc. 
Pittsburgh  Coke  &  Chemical  Co 

Fine  Chemicals  Dlv 

Pittsburgh  Plate  Glass  Co— — — 


Plasties  Engineering  Co 

Polyohemlcal  Co 

Portland  Gas  &  Coke  Co 

Poughkeepsle  Dyestuff  Corp 

Pratt  &  Lambert,  Inc 

Premo  Pharmaceutical  Laboratories, 

Inc. 
Procter  and  Gamble  Co 
Productol  Co 


Publicker  Industries,  Inc 

Puget  Sound  Pulp  &  Timber  Co- 
Pure  Oil  Co 


Purex  Corp . ,  Ltd 

Purocaine,  Inc 

Quaker  Chemical  Products  Corp- 
Quaker  Oats  Co 


R.  S.  A.  Corp 

See  footnote  at  end  of  table. 


1st  and  Essex  Sts.,  Harrison,  N.  J.  (Richmond,  Calif.; 

Cedartown,  Ga.;  and  Harrison,  N.  J.). 
601  W.  26th  St.,  New  York  1,  N.  Y.  (Boonton,  N.  J.). 

120  N.  Aurora  St.,  West  Chicago,  111. 
17  Eaton  Ave.,  Norwich,  N.  Y. 
830  Magnolia  Ave.,  Elizabeth,  N.  J. 
1400  E.  Washington  Ave.,  Madison  10,  Wis.  (Cleveland, 
Ohio) . 

295  Madison  Ave.,  New  York  17,  N.  Y.  (Houston,  Tex.). 

5001  Buffalo  Ave.,  Niagara  Falls,  N.  Y. 

500  5th  Ave.,  New  York  36,  N.  Y.  (Cambridge, 

Framlngham,  New  Bedford,  and  Worcester,  Mass.). 
P.O.  Box  1480,  Richmond  12,  Va.  (Old  Hickory,  Tenn.). 
601  W.  26th  St.,  New  York  1,  N.  Y.  (Newark,  N.  J.). 
7^-84  Valley  St.,  E.  Providence,  R.  I. 
1724  Greenleaf  Ave.,  Chicago  26,  111. 

38  Sansome  St.,  San  Francisco  4,  Calif.  (Oak  Point,  La.). 
4^-26  Purvis  St.,  Long  Island  City  1,  N.  Y. 
132  Nassau  St.,  New  York  38,  N.  Y.  (Linden,  N.  J.). 
823  Hamilton  St.,  Toledo  7,  Ohio. 
455  Cortlandt  St.,  Belleville  9,  N.  J. 
350  Morris  St.,  Toledo  4,  Ohio. 

475  Brannan  St.,  San  Francisco  19  (Emeryville),  Calif. 
917  W.  Juneau,  Milwaukee  3,  Wis.  (Peoria,  111.). 
4th  and  Cedar  Sts.,  Berkeley  9,  Calif. 
P.O.  Box  401,  Texas  City,  Tex. 
Foot  of  Joseph  Campau,  Detroit  32,  Mich. 
59  Beekman  St.,  New  York  38  (Brooklyn),  N.  Y. 
335  McLean  Blvd.,  Paterson  4,  N.  J. 
5408  Baker  Ave.,  Niagara  Falls,  N.  Y. 

4253  N.  Port  Washington  Rd.,  Milwaukee  12,  Wis. 

610  E.  Clarence  Ave.,  St.  Louis  15,  Mo. 

Lock  Haven,  Pa. 

3850  Oakman  Blvd.,  Detroit  4,  Mich. 

521-535  North  Ave.,  Plainfield,  N.  J. 

50  Church  St.,  New  York  8,  N.  Y.  (Jersey  City,  Lyndhurst, 

and  Montville,  N.  J.). 
120  State  St.,  Clairton  (Chester),  Pa. 

Butler  (Kams  City),  Pa. 

1000  Widener  Bldg.,  Philadelphia  7,  Pa. 

632  Cannon  Ave.,  Lansdale,  Pa. 

330  W.  42d  St.,  New  York  36,  N.  Y.  (Birmingham,  N.  J.). 

2575  Ewen  Ave.,  New  York  63,  N.  Y. 

104  Lakevlew  Ave.,  Waukegan,  111. 

Ridgefleld,  N.  J. 

630  Flushing  Ave.,  Brooklyn  6,  N.  Y.  (Groton,  Conn.,  and 

Vigo,  Ind.). 
175  5th  Ave.,  New  York  10,  N.  Y.  (Bayonne,  N.  J.). 
Bartlesville,  Okla.  (Phillips,  Tex.), 
9505  CassiuB  Ave.,  Cleveland  5,  Ohio. 
1200  Madison  Ave.,  Indianapolis  2,  Ind. 

Grant  Bldg.,  Pittsburgh  19  (Neville  Island),  Pa. 

Grant  Bldg.,  Pittsburgh  19,  Pa. 

1  Gateway  Center,  Pittsburgh  22,  Pa.  (Torrance,  Calif.; 
Atlanta,  Ga.;  Detroit,  Mich.;  Newark,  N.  J.;  Barberton, 
Cleveland,  and  Dayton,  Ohio;  Springdale,  Pa.;  Houston, 
Tex.;  New  Martinsville,  W.  Va.;  and  Milwaukee,  Wis.). 

1603  Geele  Ave.,  Sheboygan,  Wis. 

494  Hunts  Point  Ave.,  New  York  59,  N.  Y. 

Public  Service  Bldg.,  Portland  4,  Oreg. 

77  N.  Water  St.,  Poughkeepsle,  N.  Y. 

75  Tonawanda  St.,  Buffalo  7,  N.  Y. 

Ill  Leuning  St.,  S.  Hackensaok,  N.  J. 

Gwynne  Bldg.,  Cincinnati  2,  Ohio. 

417  S.  Hill  St.,  Los  Angeles  13  (Santa  Fe  Springs),  Calif. 

1429  Walnut  St.,  Philadelphia  2,  Pa. 

300  Laurel  St.,  Bellingham,  Wash. 

35  E.  Waoker  Dr.,  Chicago  1,  111.  (Toledo,  Ohio; 

Nederland,  Tex.;  Cabin  Creek  and  Dawes,  W.  Va.;  and 

Worland,  Wyo.). 
9300  Rayo  Ave.,  South  Gate,  Calif.  (St.  Louis,  Mo.). 
Valley  Rd.,  Hockessin,  Del. 

Lime  &  Elm  Sts.,  Conshohooken,  Pa.  (Wilmington,  Del.). 
Merchandise  Mart  Plaza,  Chicago  54,  111.  (Cedar  Rapids, 

Iowa;  Omaha,  Nebr.;  and  Memphis,  Tenn.). 
690  Saw  Mill  River  Rd.,  Ardsley,  N.  Y. 


164 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  27.  -Synthetic  organic  chemicals 


ztory  of  manufacturers,    J953--Continued 


Name  of  company 


Office  address   (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office) 


329 
373 


305 
599 
14S 
508 
341 
517 
493 


306 
509 
307 
40 
375 

553 
28 
98 
428 
510 
120 

116 
248 
457 
203 
48 
174 
462 
547 
158 
586 
444 

580 
249 
539 
258 


135 
521 


402 
80 


548 
518 


308 
196 
362 


Raybestos  Div.  of  Raybestos- 

Manhattan,  Inc. 
Red  Spot  Paint  &  Varnish  Co- 
Reiohhold  Chemicals,  Inc 


Reilly  Tar  &  Chemical  Corp- 


Reilly-Whitman-Walton  Co — 
Reliance  Varnish  Co.,  Ine- 

Remington  Arms  Co.,  Inc 

Remsen  Chemicals,  Inc 

Republic  Creosoting  Co 


Richards  Chemical  Works,  Div.  of  Onyx 
Oil  &   Chemical  Co. 

Richardson  Co 

Richfield  Oil  Corp 


Ringwood  Chemical  Corp 

Rinshed-Mason  Co 

Ritter,  F.,  &  Co 

Ritter  Chemical  Co.,  Inc 

Riverdale  Chemical  Co 

Rohm  &  Haas  Co 


Roosevelt  Oil  &  Refining  Corp- 

Roasville  Dyestuff  Corp 

Royce  Chemical  Co 

Rubber  Corp.  of  America 

Ruberoid  Co- 


Salem  Oil  &  Grease  Co—— — 
Dr.  Salsbury's  Laboratories- 
Salvo  Chemical  Corp 

Sandoz  Chemical  Works,  Inc — 
Sapon  Laboratories- 


Schenectady  Varnish  Co.,  Ino 


Schenley  Laboratories,  Inc- 

Scherer,  R.  P.,  Corp 

Sobering  Corp- 


Schieffelin  &  Co 

Scholler  Bros.,  Inc 

Schuylkill  Chemical  Co 

Schwarz  Laboratories,  Inc- 

Searle,  G.  D.,  &  Co 

Seattle  Gas  Co~— 

Seydel  Chemical  Co 

Sharp  &  Dohme  Div.  of  Merck  &  Co. 

Inc, 
Sharpies  Chemicals,  Inc 

Shawlnigan  Resins  Corp — — 

Sheffield  Chemical  Co.,  Inc 

Shell  Chemical  Corp- 


Shell  Oil  Co- 


Shepherd  Chemical  Co- 
Sheruin-Williams  Co — 


Shulton,  Inc.,  Fine  Chemicals  Div- 
Slddall,  George  F.,  Co.,  Inc 


Sigma  Chemical  Co- 


Sinclair  Refining  Co- 


Sinclair  &  Valentine  Co- 
Sipe,  James  B.,  &  Co 


Smith,  Kline  4  French  Laboratories- 

Snyder  Chemical  Corp 

Sooony-Vaouum  Oil  Co.,  Inc 

Soluol  Chemical  Co.,  Ino 


75  E.  Main  St.,  Stratford,  Conn. 

110  Main  St.,  Evansville  8,  Ind. 

525  N.  Broadway,  White  Plains,  N.  Y.  (Tuscaloosa,  Ala.; 

Azusa  and  San  Francisco,  Calif.;  Argo,  111.;  Detroit, 

Mich.;  Elizabeth,  N.  J.;  Brooklyn,  N.  Y.;  Charlotte, 

N.  C;  and  Seattle,  Wash.). 
1615  Merchants  Bank  Bldg.,  Indianapolis  4,  Ind.  (Chicago 

and  Granite  City,  111.;  Indianapolis,  Ind.;  Newark,  N.  J.; 

Cleveland  and  Dover,  Ohio;  Chattanooga,  Tenn.;  Lone  Star, 

Tex.;  and  Fairmont,  W.  Va.). 
Washington  &  Righter  Sts.,  Conshohocken,  Pa. 
4730  Crittenden  Dr.,  Louisville  9,  Ky. 
939  BamumAve.,  Bridgeport  2,  Conn. 

1  Park  Ave.,  New  York  16  (Oceanside),  N.  Y. 

1615  Merchants  Bank  Bldg.,  Indianapolis  4,  Ind.  (Mobile  and 
Florence,  Ala.;  Indianapolis,  Ind.;  St.  Louis  Park,  Minn.; 
Lima,  Ohio;'Ironton,  Utah;  Norfolk,  Va.;  and  Seattle, 
Wash. ) . 

190  Warren  St.,  Jersey  City  2,  N.  J. 

27th  Ave.  and  Lake  St.,  Melrose  Park,  111. 

555  S.  Flower  St.,  Los  Angeles  17  (Watson),  Calif. 

Ringwood,  111. 

5935  Milford  St.,  Detroit,  Mich.  (Anaheim,  Calif.). 

4001  Goodwin  Ave.,  Los  Angeles  39,  Calif. 

403  W.  Main  St.,  Amsterdam,  N.  Y. 

324  E.  147th  St.,  Harvey  (Dolton),  111. 

222  W.  Washington  Sq.,  Philadelphia  5,  Pa.  (Bristol  and 

Philadelphia,  Pa.;  Knoxville,  Tenn.;  and  Deer  Park, 

Tex.). 
Box  271,  Mt.  Pleasant,  Mich. 
Arthur  Kill  Rd.,  Staten  Island  9,  N.  Y. 
Carlton  Ave.,  Carlton  Hill,  N.  J. 
274  Ten  Eyck  St.,  Brooklyn  6  (Hicksville) ,  N.  Y. 
500  5th  Ave.,  New  York  36,  N.  Y.  (Joliet,  111.;  Baltimore, 

Md.;  and  Erie,  Pa.). 
60  Grove  St.,  Salem,  Mass. 
500  Gilbert  St.,  Charles  City,  Iowa. 
Rothschild,  Wis. 

61-63  Van  Dam  St.,  New  York  13,  N.  Y.  (Fair  Lawn,  N.  J.). 
543  Union  St.,  Brooklyn  15,  N.  Y. 
Congress  and  10th  Ave.,  Schenectady  1  (Rotterdam  Jet.), 

N.  Y. 
350  5th  Ave.,  New  York  1,  N.  Y.  (Lawrenceburg,  Ind.). 
9425  Grinnell  Ave.,  Detroit  13,  Mich. 

2  Broad  St.,  Bloomfield  (Union),  N.  J. 
16-26  Cooper  Sq.,  New  York  3,  N.  Y. 

Collins  and  Westmoreland  Sts.,  Philadelphia  34,  Pa. 

2346  Sedgley  Ave.,  Philadelphia  32,  Pa. 

230  Washington  St.,  Mt.  Vernon,  N.  Y. 

P.O.  Box  5110,  Chicago  80  (Skokie),  111. 

1507  4th  Ave.,  Seattle  11,  Wash. 

225  Mercer  St.,  Jersey  City  2  (Clifton),  N.  J. 

640  N.  Broad  St.,  Philadelphia  1  (West  Point),  Pa. 

1100  Widener  Bldg.,  Philadelphia  7,  Pa.  (Wyandotte,  Mich.). 

644  Monsanto  Ave.,  Springfield  2,  Mass. 

P.O.  Box  630,  Norwich  (Oneonta),  N.  Y. 

50  W.  50th  St.,  New  York  20,  N.  Y.  (Martinez.  Los  Angeles, 

and  Pittsburg,  Calif.;  and  Deer  Park,  Tex.). 
50  W.  50th  St.,  New  York  20,  N.  Y.  (Martinez  and 

Wilmington.  Calif.;  Roxana,  111.;  Norco,  La.;  and  Deer 

Park,  Tex.). 
2803  Highland  Ave.,  Cincinnati  12,  Ohio. 
101  Prospect  Ave.,  N.  W.,  Cleveland  1,  Ohio  (Chicago,  111.; 

Detroit,  Mich.;  Dayton  and  Cleveland,  Ohio;  and 

Philadelphia  and  Pittsburgh,  Pa.). 
Route  46,  Clifton,  N.  J. 
P.O.  Box  975,  Providence  1,  R.  I.  (Spartanburg,  S.  C,  and 

Cranston,  R.  I.). 
4648  Easton  Ave.,  St.  Louis  15,  Mo. 
600  5th  Ave.,  New  York  20,  N.  Y.  (Sand  Springs,  Okla.; 

Marcus  Hook,  Pa.;  and  Houston,  Tex.). 
611  W.  129th  St.,  New  York  27,  N.  Y.  (Ridgway,  Pa.). 
P.O.  Box  8010,  S.  Hills  Branch,  Pittsburgh  16  (Brldgevllle), 

Pa. 
1530  Spring  Garden  St.,  Philadelphia  1,  Pa. 
Henry  St.,  Bethel,  Conn. 
26  Broadway,  New  York  4,  N.  Y.  (Paulaboro,  N.  J.,  and 

Beaumont,  Tex.). 
Green  Hill  and  Market  Sts.,  Natick,  R.  I. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 

TABLE  27. --Synthetic   organic  chemicals:   Directory  of  manufacturers ,    /95J--Cr>ntimieH 


165 


Name  of  company 


33i 
A23 


Solvent  Chemical  Co. ,  Ino 

Sonneborn,  L.,  Sons,  Inc 

Sonooo  Products  Co ~ 

Southern  Dyestuff  Corp 

Southern  Sizing  Co 

Southern  Textile  Chemical  Corp 

Southside  Chemical  Co. ,  Ino 

Spaulding  Fibre  Co. ,  Ino 

Specialty  Resins  Co 

Specific  Pharmaceuticals,  Inc 

Spencer  Chemical  Co 

Squibb,  E.  R.,  &  Sons 

Staley,  A.  E.,  Manufacturing  Co 

Standard  Agricultural  Chemicals,  Inc 

Standard  Brands,  Inc 

Standard  Chemical  Co 

Standard  Chemical  Products,  Ino 

Standard  Chlorine  Chemical  Co 

Standard  Naphthalene  Products  Co 

Standard  Oil  Co.  of  California 

Standard  Oil  Co.  of  Indiana 

Standard  Soap  Co.  of  Camden 

Standard-Tooh-Chemicals,  Ino 

Standard  Ultramarine  &  Color  Co 

Stange,  Wm.  J.,  Co 

Stanolind  Oil  &  Gas  Co 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office) 


Stauffer  Chemical  Co- 


Div- 


Stepan  Chemical  Co 

Sterling  Drug,  Inc.: 

Dayer  Co.  Div 

Hilt<in-Davi:;  Chemi(;:il  Co. 

.'.'tresen-Reuter,  Fred'k.  A.,  Inc 

Strong,  Cobb  &  Co.,  Inc.,  American 
Chlorophyll  Div. 

Summit  Chemical  Products 

Sumner  Chemical  Co.,  Inc 

Sun  Chemical  Corp.: 

Pigment  Div 

Warwick  Chemical  Co.  Div 

Sun  Oil  Co 


Swift  &  Co 

Swope  Oil  &  Chemical  Co 

Synthetic  Chemicals,  Inc 

Synthetic  Products  Co 

Synthron,  Inc 

Synvar  Corp 

Tar  Distilling  Co.,  Ino 

Taylor  Fibre  Co 

Tennessee  Eastman  Co.,  Div.  of 
Eastman  Kodak  Co. 

Tennessee-Frontier  Corp 

Tennessee  Products  &  Chemical  Corp 

Texas  Co 

Texas  Eastman  Co.,  Div.  of  Eastman 

Kodak  Co. 

Thiokol  Chemical  Corp 

Thomasset  Colors,  Ino 

Thompson  Chemicals  Corp 

Trask,  Arthur  C,  Co 

Trojan  Powder  Co 

Trubek  Laboratories 

Uhlloh,  Paul,  &  Co.,  Inc 

Ultra  Chemical  Works,  Inc 

Union  Bay  State  Chemical  Co.,  Ino 

Union  Carbide  &  Carbon  Corp.: 

Bakelite  Co 

Carbide  &  Carbon  Chemicals  Co 


Linde  Air  Products  Co- 


Union  Oil  Co.  of  California- 


34.1  Commercial  St.,  Maiden  48,  Mass. 

300  ith  Ave.,  New  York  10,  N.  Y.  (Petrolia,  Pa.). 

Hartsville,  S.  C. 

P.O.  Box  1045,  Charlotte  1  (Sodyeoo),  N.  C. 

P.O.  Box  391,  601  Campbell  St.,  East  Point,  Ga. 

Clearwater,  S.  C. 

2031  Woodland  Rd.,  Petersburg  23,  Va. 

310  Wheeler  St.,  Tonawanda,  N.  Y. 

2801  Lynwood  Rd.,  Lynwood,  Calif. 

331  ith  Ave.,  New  York  10,  N.  Y.  (Bayonne,  N.  J.). 

610  Dwight  Bldg.,  Kansas  City  5,  Mo.  (Calumet  City,  111., 

and  Pittsburg,  Kans.). 
See  Mathieson  Chemical  Corp. 
Decatur,  111. 

1301  Jefferson  St.,  Hoboken,  N.  J. 
595  Madison  Ave.,  New  York  22,  N.  Y. 
217-219  New  St.,  Philadelphia  6,  Pa. 
1301  Jefferson  St.,  Hoboken,  N.  J. 
115  Jacobus  Ave.,  S.  Kearny,  N.  J. 
115  Jacobus  Ave.,  S.  Kearny,  N.  J. 
225  Bush  St.,  San  Francisco  20  (Bakersfield,  El  Segundo, 

and  Richmond),  Calif. 
910  S.  Michigan  Ave.,  Chicago  80,  111.  (Wood  River,  111.; 

Whiting,  Ind.;  and  ;;ugar  Creek,  Mo.). 
205  S.  2d  St.,  Camden  3,  N.  J. 
2600  Richmond  Ter.,  Staten  Ir.iand  3,  N.  Y. 
5th  Ave.  ana  24th  St.,  Huntington,  W.  Va. 
342  N.  Western  Ave.,  Chicago  12,  111. 
P.O.  Box  591,  Tulsa,  Okla.  (Brownsville,  Alvin, 

Katy,  Pettus,  and  Sweeney,  Tex.). 
380  Madison  Ave.,  New  York  17,  N.  Y.  (Henderson, 

Nev.;  Brooklyn  and  Niagara  Falls,  N.  Y.;  Perry,  Ohio; 

Chester  and  Monongahela,  Pa.;  Lowland,  Tenn.;  and 

Bentonville  and  Roanoke,  Va.). 
20  N.  Wacker  Dr.,  Chicago  6,  111. 

1450  Broadway,  New  York  18,  N.  Y.  (Trenton,  N.  J.). 
:>215   Langdon  Farm  Rd.,  Cincinnati  13,  Ohio. 
2113  Medill  Ave.,  Chicago  47  (Bensenville) ,  111. 
P.O.  Box  231,  Lake  Worth,  Fla. 

11  William  St,,  Belleville  9,  N.  J. 
215  N.  Centennial  St.,  Zeeland,  Mich. 

309  Sussex  St.,  Harrison,  N.  J. 

Wood  River  Junction,  R.  I.  (Rock  Hill,  S.  C). 

1608  Walnut  St.,  Philadelphia  3,  Pa.  (Marcus  Hook, 

Pa.,  and  Toledo,  Ohio). 
4115  Packers  Ave.,  Chicago  9,  111. 
3335  Richmond  St.,  Philadelphia  34,  Pa. 
335  McLean  Blvd.,  Paterson  4,  N.  J. 
1636  Wayside  Rd.,  Cleveland  12,  Ohio. 
Ryan  Ave.,  Ashton,  R.  I. 
419  E.  Front  St.,  Wilmington  99,  Del. 
500  5th  Ave.,  New  York  36,  N.  Y.  (Cleveland,  Ohio). 
Norri'stown  (Betzwood),  Pa. 
See  Eastman  Kodak  Co. 

321  W.  Douglas,  Wichita  2,  Kans. 

First  American  National  Bank  Bldg.,  Nashville  3 

( Chattanooga) ,  Tenn . 
P.O.  Box  2332,  Houston  1,  Tex. 
See  Eastman  Kodak  Co. 

780  N.  Clinton  Ave.,  Trenton  7,  N.  J. 
338  Wilson  Ave.,  Newark  5,  N.  J. 
3028  Locust  St.,  St.  Louis  3,  Mo. 
4103  S.  LaSalle  St.,  Chican;o  9,  111. 
17  N.  7th  St.,  Allentown  (Seiple) ,  Pa. 
State  Highway  #17,  E.  Rutherford,  N.  J. 
90  West  St.,  New  York  6  (Brooklyn),  N.  Y. 
2  Wood  St.,  Paterson  4,  N.  J. 
491  Main  St.,  Cambridge  42,  Mass. 

30  E.  42d  St.,  New  York  17,  N.  Y.  (Wyandotte,  Mich.; 

Bloomfield  and  Bound  Brook,  N.  J.;  and  Marietta,  Ohio). 
30  E.  42d  St.,  New  York  17,  N.  Y.  (Whiting,  Ind.;  Niagara 

Falls,  N.  Y.;  Texas  City,  Tex.;  and  Institute  and  S. 

Charleston,  W.  Va.). 
30  E.  42d  St.,  New  York  17  (Tonawanda),  N.  Y. 
617  W.  7th  St.,  Los  Angeles  17,  Calif.  (Bakersfield,  Rodeo, 

and  Wilmington,  Calif.;  Cut  Bank,  Mont.;  and  Edmonds, 

Wash.). 


166  UNITED  STATES  TARIFF  COMMISSION 

TABLE  27. --Synthetic  organic  chemicals:   Directory  of  manufacturers ,    1953--Continued 


Name  of  company 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  sajne  city  as  office) 


310 
-163 


407 
377 


22 
378 


589 
199 
393 
451 


254 
255 
408 
311 

511 
460 
208 
312 
469 

92 
313 
357 
355 
409 

29 
596 
280 
218 
410 
167 

363 
175 
200 
356 
136 
130 
162 
561 
168 
416 
268 
379 
314 


429 
447 
549 
564 

411 
424 
269 


United  Piece  Dye  Works 

U.  S.  Industrial  Chemicals  Co.,  Div. 

of  National  Distillers  Products 

Corp. 

United  States  Pipe  &  Foundry  Co 

U.  S.  Plastic  Products  Corp 

United  States  Procaine  Co.,  Ino 

U.  S.  Rubber  Co.,  Naugatuck  Chemical 

Div. 
U.  S.  Rubber  Co.  (R.  R.)^ 

Universal  Detergents,  Inc 

Valspar  Corp.,  Valentine  &  Co.  Div 

van  Ameringen-Haebler,  Ino 


Van  Camp  Laboratories,  Div.  of  Van 
Camp  Sea  Food  Co.,  Inc. 

Vanderbilt  Chemical  Corp 

Van  Dyk  &  Co.,  Ino 

Varoum  Chemical  Corp- 


Velsicol  Corp.,  Div.  of  Arvey  Corp 


Verley  Chemical  Co.,  Inc 

Verona  Chemical  Co 

Victor  Chemical  Works 

Virginia-Carolina  Chemical  Corp 

Vita-Var  Corp 

Wallace  &  Tiernan,  Ino 

Warner-Jenkinson  Manufacturing  Co- 
Washbum,  T. 


Watertown  Manufacturing  Co- 
Watson-Park  Co 


Werner  Drug  &  Chemical  Co- 

Westem  Condensing  Co 

Western  Dry  Color  Co- 


Westinghouse  Electric  Corp- 


Westville  Laboratories 

Wetherill,  George  D.,  Varnish  Co- 
Wheeler,  Reynolds  &  Stauffer 

White  &  Bagley  Co- 


White  Sc  Hodges,  Inc 

Whittemore-Wright  Co.,  Inc — 

Whittier  Laboratories 

Wica  Co.,  Inc 


Wilmot  &  Cassidy,  Ino- 
Wilson  Laboratories 


Wilson  Organic  Chemicals,  Inc 

Winthrop-Stearns,  Inc 

Witco  Chemical  Co ~ 

Witte,  John  H.,  &  Sons 

Wolf,  Jacques,  &  Co 

Wolff -Alport  Chemical  Corp 

Wyandotte  Chemicals  Corp- ~ 

Wyeth  Laboratories,  Ino — 

Young  Aniline  Works,  Ino 

Zinsser  &  Co.,  Inc — - 
Zurn,  0.  F.,  Co 


Nicholson  St.,  Lodi,  N.  J. 

120  Broadway,  New  York  20,  N.  Y.  (Pensacola,  Fla.;  New 
Orleans,  La.;  Baltimore,  Md.;  and  Newark,  N.  J.). 

Box  1345,  Providence  (Phillipsdale),  R.  I. 

P.O.  Box  2651,  Birmingham,  Ala. 

Lake  Sc  Whitman  Aves.,  Metuchen,  N.  J. 

15-29  129th  St.,  College  Point,  N.  Y. 

1230  Ave.  of  the  Americas,  New  York  20,  N.  Y. 

( Naugatuck,  Conn . ) . 
1230  Ave.  of  the  Americas,  New  York  20,  N.  Y. 

(Naugatuck,  Conn.,  and  Port  Neches,  Tex.). 
1825  E.  Spring  St.,  Long  Beach  6,  Calif. 
301  Henrietta  St.,  Kalamazoo  99,  Mich. 
11  E.  36th  St.,  New  York  16  (Brooklyn),  N.  Y. 
521  W.  57th  St.,  New  York  19,  N.  Y.  (Elizabeth  and 

Union  Beach,  N.  J.). 
772  Tuna  St.,  Terminal  Island,  Calif. 

230  Park  Ave.,  New  York  17,  N.  Y.  (Bethel,  Conn.). 

11  William  St.,  Belleville  9,  N.  J. 

P.O.  Box  476,  Niagara  Falls,  N.  Y. 

330  E.  Grand  Ave.,  Chicago  11,  111.  (Marshall,  111.,  and 

Memphis,  Tenn.). 
200  Pulaski  St.,  Newark  5,  N.  J. 
26  Verona  Ave.,  Newark  4,  N.  J. 
141  W.  Jackson  Blvd.,  Chicago  4,  111. 
401  E.  Main  St.,  Richmond  5,  Va.  (Charleston,  S.  C). 
809  W.  58th  St.,  Chicago  21,  111. 
10  Commerce  Ct.,  Newark  2,  N.  J. 
25  Main  St.,  Belleville  9,  N.  J. 
1740  Military  Rd.,  Buffalo  5,  N.  Y. 
2526  Baldwin  St.,  St.  Louis  6,  Mo. 
2244  Elston  Ave. ,  Chicago  18,  111. 
127  Echo  Lake  Rd.,  Watertown,  Conn. 
Box  158,  Ballard  Vale,  Mass. 
759  Beechwood  Ave.,  Cincinnati  32,  Ohio. 
P.O.  Box  739,  Appleton  (Adell) ,  Wis. 
600  W.  52d  St.,  Chicago  9,  111. 
401  Liberty  Ave.,  P.O.  Box  2278,  Pittsburgh  30 

(East  Pittsburgh),  Pa. 
Stepney,  Conn. 

Haddon  Ave.  &  White  Horse  Pike,  Camden  3,  N.  J. 
636  California  St.,  San  Francisco  8  (Richmond),  Calif. 
100  Foster  St.,  Worcester  8,  Mass. 
2  Wellington  Ave.,  Everett  49,  Mass. 
62  Alford  St.,  Charlestown  29,  Mass. 
919  N.  Michigan  Ave.,  Chicago  11,  111. 
P.O.  Box  506,  Charlotte  1,  N.  C. 
108-112  Provost  St.,  Brooklyn  22,  N.  Y. 
4221  S.  Western  Ave.,  Chicago  9,  111. 
P.O.  Box  452,  Sayreville,  N.  J. 
1450  Broadway,  New  York  18  (Rensselaer),  N.  Y. 
260  Madison  Ave.,  New  York  16,  N.  Y.  (Chicago,  111.,  and 

Brooklyn,  N.  Y.). 
206  Jefferson  St.,  Burlington,  Iowa. 
350  Lexington  Ave.,  Clifton  (Carlstadt),  N.  J. 
1127  Irving  Ave.,  Brooklyn  27,  N.  Y. 
1609  Biddle  Ave.,  Wyandotte,  Mich. 
1401  Walnut  St.,  Philadelphia  2,  Pa.  (Chicago,  111.,  and 

Philadelphia  and  West  Chester,  Pa.). 
2731  Boston  St.,  Baltimore  24,  Md. 
Hastings-on-Hudson  6,  N.  Y. 
2736  N.  Broad  St.,  Philadelphia  32,  Pa. 


■"■  R.  R.  in  parentheses  following  the  name  of  a  company  indicates  U.  S.  Government  plant  operated  for 
the  Office  of  Rubber  Reserve. 


APPENDIX 

A.  United  States  Imports  of  Coal- Tar  Intermediates 
and  Finished  Coal-Tar  Products 

Table  28  summarizes,    for  the  period  1951-53,    United  States 
imports  of  coal-tar  products  dutiable  under  paragraphs  27  and  28 
of  the  Tariff  Act  of  1930.    The  data,    which  were  obtained  by  ana- 
lyzing  invoices  covering  imports  through  all  United  States  customs 
districts,    are  given  in  detail  in  a   separate  report  of  the  Tariff 
Commission. 

Imports  in  1953  of  coal-tar  chemicals    entered  under  paragraph 
27,    virtually  all  of  which  are  intermediates,    totaled  22.3  million 
pounds,    with  a  foreign  invoice  value  of  5.4  million  dollars.  Imports 
of  these  products  were  3.0  million  pounds,    valued  at  1.7  million 
dollars,    in  1952,    and  8.5  million  pounds,    valued  at  2.2  million 
dollars,    in  1951.    The  very  large  increase  in  the  quantity  of  im- 
ports in  1953,    compared  with  1951  and  1952,    was  due  primarily  to 
greatly  increased  imports  of  phthalic  anhydride,    and  to  substantial 
innports  of  many  other  low-priced  basic  intermediates.    More  than 
half   of  all  imports  of  intermediates  in  1953  came  from  Germany 
and  the  United  Kingdom.    Imports  from  Germany  totaled  7.7  million 
pounds  in  1953,    compared  with  1.4  million  pounds  in  1952;  imports 
from  the  United  Kingdom  were  4.9  million  pounds  in  1953,    com- 
pared with  629,000  pounds  in  1952.    In  1953  sizable  quantities  of 
intermediates  were  also  imported  from  Italy,    France,    Belgium, 
the  Netherlands,    Japan,    Switzerland,    and  Canada;  lesser  quantities 
came  from  Denmark,    Sweden,    Australia,    and  Mexico.    In  terms    of 
quantity,    the  three  most  important  intermediates  imported  in  1953 
were  phthalic  anhydride,    naphthalene,   and  anthraquinone.    Imports 
of  phthalic  anhydride  totaled  16.7  million  pounds  and  came  from 
Germany,    the  United  Kingdom,    Italy,    France,   Belgium,    the 
Netherlands,    Japan,    Switzerland,    and  Denmark.    Imports  of  refined 
naphthalene,    which  totaled  1.1  million  pounds,    came  from  the 
Netherlands,    Germany,    Belgium,    and  the  United  Kingdom;    im- 
ports of  anthraquinone,    which  totaled  732,000  pounds,    came  chiefly 
from  the  United  Kingdom,    France,    and  Germany. 

In  1953  the  innports  of  all  finished  coal-tar  products  that  are 
dutiable  under  paragraph  28  totaled  3.4  million  pounds  (actual 
weight),    with  a  foreign  invoice  value  of  6.9  million  dollars.    In  1952, 
imports  totaled  4,5  million  pounds,    with  a  foreign  invoice  value  of 
6,9  million  dollars,    and  in  1951,    4.4  million  pounds,    valued  at  7,3 
million  dollars.    It  should  be  noted  that  the  data  for  1953  are  based 
on  general  imports,    whereas  the  data  for  1951  and  1952  are  based 
on  imports  for  consumption.    The  differences  between  general  im- 
ports   and  imports  for  consumption  are  small,    so  that  the  figures 
for  the  3  years  are  quite  comparable. 


^  U.  S.  Tariff  Commission,  Imports  of  Coal-Tar  Products,  1953  [processed], 

167 


168 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  28.  --Coal- tar   intermediates   and  finished  coal-tar  products:    United  States    imports,    classified 

by  use,    1951-53 


Quantity 


Foreign 
invoice 
value 


Quantity 


Foreign 
invoice 
value 


Quantity 


Foreign 
invoice 

value 


Intermediates-^ 

Finished  coal-tar  products,  total- 
Dyes,  total 

Acid 

Vat 

Mordant  and  chrome 

Sulfur 

Direct 

Acetate  rayon 

Azoic 

Basic 

Color-lake  and  spirit-soluble 

All  other 

Medioinals  and  pharmaceuticals 

Flavor  and  perfume  materials 

All  other 


1,000 
dollars 
2, 2-^5 


3,028 


1,000 
dollars 

1,7^9 


22,273 


1,000 
dollars 

5,419 


4,»W8 


7,330 


4,526 


6,934 


6,905 


3,379 


515 
1,630 
326 
2 
616 
60 


6,264 


1,333 

2,317 

727 

4 

1,266 

162 

150 


2,175 


4,404 


247 
30 
509 


2,138 


705 
1,192 

593 

29 

1,245 

123 

240 
15 
52 

210 

1,928 

18 

584 


2,555 


4,594 


348 
957 
143 


398 
132 

379 
105 
355 


1,043 

1,240 

■  313 

38 

958 

147 


299 
369 

1,925 
194 
192 


Includes  small  quantities  of  organic  pesticides,  rubber-processing  chemicals,  and  surface-active  agents. 
^  Actual  weight;  the  computed  weight  (corrected  to  the  standards  of  strength  established  by  the  Secretary 
of  the  Treasury)  was  4,214  thousand  pounds  in  1951,  2,703  thousand  pounds  in  1952,  and  3,255  thousand  pounds 
in  1953. 

Source:  Compiled  from  the  records  of  the  U.  S.  Bureau  of  Customs. 

NOTE. — The  statistics  for  1953  are  based  on  general  imports;  the  statistics  for  1951  and  1952  are  based  on 
imports  for  consumption.  The  statistics  for  1953,  therefore,  are  not  strictly  comparable  with  those  for  1951 
and  1952.  The  differences,  however,  are  small,  so  that  comparisons  are  significant. 

As  in  previous  years,    dyes  were  by  far  the  most  important 
group  of  finished  coal-tar  products  imported.    Imports  of  dyes  in 
1953  amounted  to  4.6  million  dollars  (foreign  invoice  value),    or 
67  percent  of  the  total  value  of  all  imports  under  paragraph  28. 
In  1953  Switzerland  was  the  principal  supplier  of  dyes,    accounting 
for  51  percent  of  total  imports;  Germany's  share  of  the  total  was 
28  percent,    and  the  United  Kingdom's  share  was   20  percent.  Me - 
dicinals  andpharmaceuticals  were  the  next  most  important  group 
of  finished  coal-tar  products  imported  in  1953.    In  both    1953  and 

1952,  imports  of  these  products  were  valued  at  1.9  million  dollars, 
or  28  percent  of  the  total  value  of  all  imports  under  paragraph  28. 
Germany,    Switzerland,    and  Italy  were  the  principal  sources  of 
innports  of  coal-tar  medicinals  in  1953.    Imports  of  flavor  and  per- 
fume materials  increased  in  value  to  $194,000  in  1953  from  $18,000 
in  1952;  Canada  was  the  principal  source  of  these  materials  in 

1953.  Imports  of  other  coal-tar  products  dutiable  under  paragraph 
28  decreased  in  value   to  $192,000  in  1953  from  $584,000  in  1952. 
The  synthetic  resins --the  most  important   class  of  items  in  this 
group --came  chiefly  from  Canada  and  the  Netherlands. 

B.  Research  Workers  and  Research  Expenditures  in 
the  Synthetic  Organic  Chemical  Industry 


Because  of  the  interest  of  the  synthetic  organic  chemical 
industry  in  statistics  on  chemical  research,    the  Tariff  Commission 
each  year  collects  and  publishes  statistics    on  the  number  of  tech- 
nically trained  research  workers  in  the  industry,    their  salaries, 
and  the    cost  of  research  (see  table  29).    This  information  is  not 
available  elsewhere.    As  many  of  the  companies  that  produce  syn- 
thetic organic  chemicals  also  nnanufacture  other  products,    the  data 
are  only  approximate;  for  some  companies  the  allocation  of  the 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


169 


cost   of  research  on  synthetic  organic  chemicals  is  somewhat 
arbitrary.    Notwithstanding  this  limitation,    the  statistics  do  indi- 
cate trends  in  the  amount  of  research  done  in  the  synthetic  organic 
chemical  industry.    The  data  here  reported  probably  cover  about 
85  percent  of  the  industry's  total  expenditure  for  research   activi- 
ties. 

In  1953  a  total  of  363  companies  reported  on  research  activities. 
The  number  of  technically  trained  research  workers  (minimum 
salary  of  $3,600  per  year)  reported  for  1953  was   12,208,     or  about 
the  same  as  the  number  reported  for  1952.    The  average  salary 
paid  was  $6,856,    compared  with  $6,285  in  1952.    Salaries  paid  in 
1953    totaled  83.7  million   dollars,  compared  with  76.7  million 
dollars  in  the  preceding  year.    In  1953  the  gross  cost  of  research 
was  210    million  dollars,    or  an  increase  of  1  5  million  dollars  over 
that  in  1952,    The  cost  to  the  industry  in  1953  for  research  con- 
ducted for  it  outside  of  the  facilities  of  the  reporting  companies -- 
a  cost  not  included  in  the  figures  given  above --was  7.9  million 
dollars,    1.7  million   dollars  less  than  in  1952.    This  figure,    how- 
ever,   probably  does  not  represent  all  research  projects  in  uni- 
versities and  private  laboratories,    or  all  consulting  services. 


TABLE  23.--Syntheti 


r^anic  chemical    industry:   Number   of  research  worker 
and  cost  of  research,    1945-53 


alaries  paid     esearch   workers. 


Companies 
reporting 


Technically 
trained 
research 
workers^ 


Salaries 

paid 
research 
workers 


Total  reported 
2ost  of  research 


Within  the  plant 


Nef 


Outside 

the 
plant 


1945- 
1946- 
1947- 
1948- 
1949- 
1950- 
1951- 
1952- 
1953- 


274 
313 
301 
303 
338 
335 
353 
381 
363 


6,219 
7,527 
8,707 
9,114 
8,916 
10,529 
9,984 
12,203 
12,208 


1,000 
dollars 
26,944 
35,791 
41,571 
46,346 
51,521 
56,619 
67,376 
76,701 
83,694 


1,000 
dollars 

55,046 
73,376 
90,640 
98,729 
105,333 
115,191 
149,607 
1^4,993 
210,035 


1,000 

dollars 

52,184 

69,412 

87,825 

95,417 

100,580 

111,374 

144,784 

186,503 

199,829 


liars 

4,023 
4,249 
4,600 
4,594 
4,996 
6,648 
6,724 
9,603 
7,951 


■"■  For  the  years  1945-50,  a  technically  trained  research  worker  was  defined  as  a  person  with  technical 
training  engaged  in  research  work  and  earning  not  less  than  $2,500  per  year;  for  1951-55,  the  minimam  amount 
of  earnings  was  fixed  at  |3,600. 

The  net  cost  figure  is  obtained  by  deducting  from  gross  cost  the  credits  for  salable  products  obtained 
in  the  course  of  research. 

C .  Glossary  of  Synonymous  Names  of  Cyclic  Intermediates 

Many   cyclic  intermediates  are  known  in  the  chemical  trade  by 
a  variety  of  names.    Individuals  in  the  trade  frequently  are  not   ac- 
quainted  with  all  the  synonymous  names  for  a  given  product.    To 
bring  together  the  synonymous    names  for  each  product,    the  tables 
on  intermediates  in  this  report  (table  7A   in  part  II,    and  table  7B  in 
part  III)  show  the  standard  name,    in  accordance  with  the  system 
used  by  Chemical  Abstracts;  this  standard  name  is  frequently 
followed  by  the  most  common  synonymous  name  in  parenthesefs. 

In  this  report,    as  in  previous  reports  of  this  series,    the  Tariff 
Conamission  has  included  a  glossary  of  synonymous  names  of 
cyclic  intermediates.    This  glossary,    which  originally  was  com- 
piled at  the  suggestion  of  the  Industry  Advisory  Committee  on 
Government  Reports,    is  intended  to  serve  principally  as  an  index 
to  the  standard  names  used  in  the  tables  on  intermediates.    The 
first  column  of  the  glossary  lists  alphabetically  the  common,    or 
trivial,    names  usually  encountered  in  the  trade.    The  second 
columin  gives  the  corresponding  standard  (Chemical  Abstracts) 
names,    under  which  the  data  are  presented  in  tables   7A  and  7B. 


313486   O  -  54  -  12 


170 


UNITED  'STATES  TARIFF  COMMISSION 


Cyclic   intermediates:     Glossary  of 


synonymous  names 


Common  name 


Aoedlan throne 

p-Aeetamidobenzenesulfonyl  chloride 

5-Aoetamido-2 -hydroxy-benzoic  acid 

S-Aoetaniido-orthanilio  acid 

Acetanilide-p-sulfonic  acid 

Acetanilid  sulfon  chloride 

p-Acetoacetchloranilide 

Acetoacet-o-chloroanilide 

o-Acetoacetochloroanilide 

m-Acetoacetoxylidide 

Acetoacet-o-toluidide 

Acetoacet-o-toluidine 

Acetoacetyl-o-anisidine 

Acetoacetyl  benzidine 

Acetylacet-o-phenylacetoacetanilide 

Acetyl -p-amino-o-aminophenol  hydrochloride 

Acetylamino  Cleve's  acid 

Acetyl-o-anisidine 

Acetyl-p-anisidine 

Acetyldiaminoanthraquinone 

Acetyl-aj-i-diaminophenol  hydrochloride 

Acetyl  H  acid 

Aoetyl-l,4.-naphthalenediainine-6Cand  7)-sulfonic  acids 


Acetyl -p-nitro-o-aminophenol 

Acetyl -m-phenylenediamine 

Acetyl-p-phenylenediamine 

Acetyl -p-phenylenediamine  sulfate 

N-'--Acetylsulfanilamide 

N*-Acetylsulfanilamide 

2-(N*-Acetylsulfanilamido)thiazole 

N*-Acetyl-2-sulfo-p-phenylenediajiiine- 

N-Acetyl-o-toluidine 

1,2,4-Acid 

Amichin 

p-Aminoazobenzene : 


Standard  (Chemical  Abstracts)  name 


Aminoazobenzene  disulfo  acid 

Aminoazobenzene-3,4-disulfonic  acid 

p-Aminoazobenzene  hydrochloride 

Aminoazobenzene-m-sulfonio  acid 

Aminoazobenzene-p-sulfonic  acid 

o-Aminoazo toluene 

o-Aminoazotoluene  sulfate 

o-Aminoazotoluenesulfonio  acid  and  salt- 


Aminoazoxylene 

Aminoazoxylenetoluidine 

8-Amino-l,2-benzacridin-7(l2)-one 

8 -Amino -1 , 2 -benzaoridone 

p-Aminobenzenearsonic  acid 

m-Aminobenzenesulfonic  acid 

p-Aminobenzenesulfonic  acid 

o-Aminobenzoio  acid 

m-Aminobenzoyl  I(or  J)  acid — r 

p-Arainobenzoyl  I(or  J)  acid 

o-Aminobenzylsulfonic  acid 

o-Aminobiphenyl 

2-Aminobiphenyl 

■i-Aminobiphenyl 

l-Amino-2-bromo^-(p-toluidlne)anthraquinone- 

5-Amino-2-chlorobenzenesulfonic  acid 

5-Amino-3-chlorobenzenesulfonic  acid 

5-Amlno-i-chlorobenzenesulfonic  acid 

5-Amino-2-ohlorobenzoic  acid 

2-Amino -4 -chloro toluene 

2-Amino-5-chloro toluene 

2-Amino -6 -chloro toluene 

2-Amino-5-ohlorotoluene  hydrochloride 

m-Amino-p-cresol 

3-Amino-p-cresol  methyl  ether 

3-Amino-p-cresyl  methyl  ether 

Aminod  ichlorobenzenesulf onic  ac  id 

2-Aminodlcyclohexyl 

2-Araino-l,4-diethoxybenzene- 


2-Amino-5-diethylaminotoluene  hydrochloride 
p-Aminodiethylaniline 

'4-Amlno-l,3-dlhydroxyanthraqulnone 

2-Amlno-l,4-dimethoxybenzene — . 

P-Aminodimethylaniline 

p-Arainodlme thy lani line  hydrochloride 

p-Aminodimethylaniline  sulfate 

2-Araino-<4,6-dinitrophenol  and  salt 

o-Aminodiphenyl 

p-Arainodiphenyl 


Aceanthra[2,l-a]aceanthrylene-5,13-dione. 

N-Acetylsulfanilyl  chloride. 

5-Acetamidosalicylic  acid, 

5-Acetamido-2-aminobenzenesulfonic  acid. 

N-Acetylsulfanilic  acid. 

N-Acetylsulfanilyl  chloride. 

p-Chloroaoetoacetanilide . 

o-Chloroacetoacetanilide. 

o-Chloroacetoacetanilide, 

2,4-Acetoacetoxylidide. 

o-Acetoacetotoluidide, 

o-Acetoacetotoluidide, 

o-Acetoacetanisidide, 

p,p'-Biacetoacetanilide, 

y-(o-Acetoaoetophenyl)acetoaoetanilide. 

't-Aoetamido-2-aiiiinophenol  hydrochloride. 

8-Aoetamido-5-amino-2(and  3)-naphthalenesulfonio  acid. 

o-Aeetanisidide. 

p-Aoetanisidide. 

1,5 (or  l,8)-Diacetamidoanthraquinone. 

4-Acetajiiido-2-aminophenol  hydrochloride. 

8-Aoetamido-l-naphthol-3,6-disulfonic  acid. 

8-Acetamido-5-amino-2(and  3)-naphthalenesulfonio 
acid. 

2-Aoetamido-4-nitrophenol. 

m-Aminoacetani lide . 

p-Aminoacetanilide. 

p-Aminoacetanilide  sulfate, 

N-Sulfanilylacetamide. 

p-Sulfamylaoetanilide. 

p-2-Thiazolylsulfamylacetanilide, 

5-Acetamido-2-aminobenzenesulfonic  acid, 

o-Acetotoluidide. 

l-Amino-2-naphthol-4-sulfonic  acid. 

8-Amino-6-methoxyquinoline. 

p-Phenylazoaniline. 

6-Amino-3,'4'-azobis[benzenesulfonic  acid] . 

6-Amino-3,'4'-azobis[benzenesulfonic  acid] . 

p-Phenylazoaniline  hydrochloride. 
m-(p-Aminophenylazo )benzenesulf onic  acid. 
p-(p-Amlnophenylazo )benzencsulf onic  acid. 
<i-(o-Tolylazo)-o-toluidine. 
■i-Co-Tolylazoi-o-toluidine  sulfate. 
4-(4-Amino-m-tolylazo)-m-toluenesulfonio  acid  and 

salt. 
'l-(2,';-Xylylazo)-2,5-xylidine. 
i-(2,'4-Xylyla?o)-o-toluidine. 
8-Amlnobenz[ai  •icridin-7(12;-one. 
8-Aminobenz[ajacridin-7',  12)-one. 
Arsanilic  acid. 
Metanilic  acid. 
Sulfanilio  acid. 
Anthranilic  acid. 

6-(m-Aminobenzamido)-l-naphthol-3-sulfonio  acid. 
6-(p-Aminobenzamido)-l-naphthol-3-sulfonio  acid. 
o-Toluidinomethanesulfonio  acid. 
2-Biphenylamine. 
2 -B ipheny lamine . 
Xenylamine. 

l-Amino-2-bromo-4-(p-toluidino)anthraquinone, 
6-Chlororaetanilic  acid. 
5-Chlorometanllic  acid. 
4-Chlorometanllio  acid. 
3-Amlno-6-chlorobenzoio  acid, 
5-Chloro-o-toluidine. 
4-Chloro-o-toluidine. 
6-Chloro-o-toluidine. 
4-Chloro-o-toluidine  hydrochloride. 
2-Amino-p-cresol. 
5-Methyl-o-anisidine. 
5-Methyl-o-anisidine. 
2,5-Dichlorosulfanilic  acid. 
2-Aminoblcyclohexyl. 
2, 5-Diethoxyanillne. 

N',N'-Diethyltoluene-2,5-dlaiiilne  hydrochloride, 
N,N-Diethyl-p-phenylenediamine. 
4-Aminoxanthopurpurin. 
2,5-Dimethoxyaniline. 
N,N-Dimethyl-p-phenylenedlamine. 
N,N-Dimethyl -p-phenylenediamine  hydrochloride. 
N, N-Dime thy 1 -p-phenylenediamine  sulfate. 
Picramio  acid  and  salt, 
2-Biphenylamine. 
Xenylamine. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 

Cyclic   intermediates:      Glossary  of  synonymous  names — Continued 


171 


Coiranon  name 


Standard  (Chemical  Abstracts)  name 


p-Aminodiphenylamlne 

'i-Aminodlphenylajnlne-2 -sulfonic  acid 

Aminodiphenyl  ether 

4-Aminoetho5cyethylaniline 

Amino  G  acid 

Amino  I(or  J)  acid • 

p-Amino-N-isobutylphenol 

5-Amino-2-methoxybenzyl  alcohol 

4 -Amino -3 -methoxyd  ipheny lamine -2 -sulfonic  acid 

"i-Amino-l-naphthalenesulfonic  acid 

2-Aminonaphthalene-3,6,8-trisulfonic  acid 

l-Amino-7-naphthol 

l-Amino-8-naphthol-4,6-disulfonic  acid 

4-Amino-5-naphthol-l,7-disulfonic  acid 

l-Amino-8-naphthol-2,4-disulfonic  acid,  monosodium 

salt, 
l-Amino-8-naphthol-3,6-disulfonic  acid,  monosodium 

salt. 
2-Amino-8-naphthol-3,6-disulfonic  acid,  monosodium 

salt, 
4-Amino-5-naphthol-l,3-disulfonic  acid,  monosodium 

salt, 
5-Amino-<V-naphthol-2,7-disulfonio  acid,  monosodium 

salt. 
6-Amino-4-naphthol-2,7-disulfonlc  acid,  monosodium 

salt. 

2-Amino-6-naphthol-8-sulfonic  acid 

4-Amino-3-naphthol-l -sulfonic  acid 

7-Amino-3-naphthol-l-sulfonic  acid 

l-Amino-8-naphthol-4-sulfonic  acid,  sodium  salt 

2-Amino-5-naphthol-7-sulfonlc  acid,  sodium  salt 

2-Amino-8-naphthol-6-sulfonic  acid,  sodium  salt 

"i-Amino-S-naphthol-l -sulfonic  acid,  sodium  salt 

6-Amino-4-naphthol-2-sulfonio  acid,  sodium  salt 

7-Amino-4-naphthol-2-sulfonio  acid,  sodium  salt 

2-Amino-4-nitroanisole 

2-Amino-5-nitroanisole 

2-Amino-6-nitroanisole 

i-Amino-3-nitroanisole 

4-Amino-4-nitrodiphenylamine-2 -sulfonic  acid 

2-Aminophenetole 

Aminophenol  sulf amide 

o-Aminophenol-p -sulfonamide 

o-Aminophenol-p-sulfonic  acid 

Aminopheny Ipheny 1  ether 

m-Aminophenylpyrazolonecarboxylic  acid 

l-(m-Aminophenyl)-5-pyrazolone-3-carboxylic  acid 

p-Aminophenyl-p-tolylaminesulfonio  acid 

Amino  R  acid 

6-Amino-3-(p-toluene  sulf one )amino-4^aethoxytoluene- 

3,'  -Amino-(p-toluenesulfone  )ethoxytoluene 

2-Aminotoluene-5-sulfonic  acid 

Aminoviolanthrene 

Aniline-2,4-disulfonio  acid 

Aniline-2,5-disulfcnic  acid 

Aniline  hydrochloride 

Aniline  oil 

Aniline-m-sulfonic  acid 

Aniline-p-sulfonic  acid 

Aniline-omega-sulfonic  acid,  sodium  salt . 

6-Anilinoiiietanilic  acid 

o-Aiiiside-4-acetylurea- 
2-Aniside-i-aoetylurea- 


2-Anisidine-4-sulfobutylamide — 

o-Anisidine-omega-sulfonio  acid 

1, 4, 9, 10-Anthratetrol 

1, 9-Anthrathiazole -2 -oarbonyl  chloride 

l,l'-Azobis(2-naphthol-4-sulfonic  acid) 

1,1  -Azobis(8-nitro-2-naphthol-4-sulfonic  acid)- 

5,5,' -Azobis ( salicylic  acid ) 

Azohydroxyaniline 

Azoxy  aniline 

m,m'-Azoxybisanillne 


Benzal  chloride 

Benzaldehydedlsulfonie  acid 

Benzaldehydemonosulfonio  acid 

l-(4-Benzamido-l-anthraqulnonylimino)-5-benzamido- 
anthraquinone , 

Benzanthrone 

Benzanthronedianthraquinonyldi-imide 


N-Phenyl-p-phenylenediamine, 

5 -Amino -2 -ani linobenzenesulf oni c  acid. 

p -Phenoxyani line . 

2-(p-Amino-N-ethylanillno )ethanol. 

7-Amino-l,3-naphthalenedisulfonic  acid, 

6-Amino-l,3-naphthalenedisulfonio  acid, 

p-Isobutylaminophenol, 

5-Amlnosallgenin-2-methyl  ether, 

5-Anilino-2-methoxymetanilic  acid. 

Naphthionio  acid, 

7-Amino-l,3,6-naphthalenetrlsulfonic  acid, 

8 -Amino -2 -naphtho 1 , 

8-Amino-l-naphthol-3,5-disulfonic  acid, 

8-Amino-l-naphthol-3,5-disulfonic  acid, 

8-Amino-l-naphthol-5,7-disulfonio  acid,  monosodium 

salt, 
8-Amino-l-naphthol-3,6-disulfonic  acid,  monosodium 

salt, 
7-Amino-l-naphthol-3,5-disulfonic  acid,  monosodium 

salt. 
8-Amino-l-naphthol-5,7-disulfonie  acid,  monosodium 

salt. 
8-Amino-l-naphthol-3,6-disulfonic  acid,  monosodium 

salt. 
7-Amino-l-naphthol-3,6-disulfonic  acid,  monosodium 

salt. 
6-Amino-2-naphthol-4-sulfonic  acid. 
l-Amino-2-naphthol-<i-sulfonic  acid. 
6-Amino-2-naphthol-i-sulfonic  acid, 
8-Amlno-l-naphthol-5-sulfonic  acid,  sodium  salt, 
6-Amino-l-naphthol-3-sulfonic  acid,  sodium  salt, 
7-Amino-l-naphthol-3-sulfonio  acid,  sodium  salt, 
8-Amino-l-naphthol-5-sulfonio  acid,  sodium  salt, 
7-Amino-l-naphthol-3-sulfonic  acid,  sodium  salt. 
6-Amino-l-naphthol-3-sulfonic  acid,  sodium  salt, 
5-Nitro-o-anisidine, 
"i-Nitro-o-anisidlne, 
6-Nitro-o-anisidine. 
2-Nltro-p-anisidlne. 

2-(p-Aminoanilino)-5-nitrobenzenesulfonic  acid. 
o-Phenetidine. 

2-Amino-l-phenol-4— sulf onamide . 
2 -Amino -1 -phenol -4 -sulf onami de . 
2-Amino-l-phenol-4-sulfonic  acid. 
Phenoxyaniiine. 
l-(m-Aminophenyl) -5-0X0-2 -pyrazollne-3-carboxy lie 

acid. 
l-(m-Aminophenyl ) -5-oxo-2-pyTazoline-3-carboxyllo 

acid, 
6-p-Toluidinometanillc  acid, 
3-Amlno-2,7-naphthalenedisulfonic  acid. 
A.  -Amino-5' -methyl -p-toluenesulfon-o-anisidide. 
3 -Me thy 1 -N- ( p -to luene sulf ony 1 ) -p -phene t id ine . 
4-Amino-m-toluenesulfonlc  acid. 
16-Aminoviolanthrone. 
4-Amino-m-benzenedisulfonic  acid. 
2-Amlno-p-benzenedisulfonic  acid. 
Aniline  salt. 
Aniline, 
Metanllic  acid, 
Sulfanilic  acid, 

Anllinomethanesulfonic  acid,  sodium  salt, 
5-Amino-2-anilinoben2enesulfonie  acid. 
o-Anlsidlnomenthanesulfonlc  acid. 
l-Aeetyl-3- ( A-amino-p-anisyl ) urea . 
3-Amino-J<-butyl-p-aniaolesulf  onamide . 
o-Anisldlnomethanssulfonlc  acid. 
Leuco  qulnizarin, 

Anthr[l,9] lsothiazole-2-carbonyl  chloride, 
Naphth[l,2]oxadlazole-5-sulfonic  acid, 
7(and  8)-Nitronaphth[l,2]oxadiazole-5-sulfonic  acid, 
3-Carboxy-2(and  4)-hydroxybenzenediazonlum  sulfate. 
p-(p-Amlnophenylazo )phenol, 
m,m' -Azoxydianiline. 
m,m' -Azoxydianiline. 

a ,a -Dichlorotoluene . 
4-Formyl-m-benzenedisulfonio  acid. 
o-Formylbenzenesulfonic  acid. 
4,5'-Dlbenzamido-l,l'-lmlnodlanthraquinone. 

7-Benz[  de]  anthracen-7-one. 

3 ,  9^is  [  1-anthraquinonylamlno]  -7-benz  [  de  ]  anthraoen- 
7 -one. 


172 


UNITED  STATES  TARIFF  COMMISSION 

Cyclic   intermediates:      Glossary   of  synonymous   names— Continued 


Common  name 


Benzeneazobenzene 

Benzene-l,3-dicarboxylic  acid 

p-Benzenedicarboxylic  acid 

1, 3, 5-Benzenetriol 

2,2 '-Benzidine  dlsulfonic  acid 

Benzidine  sulfonic  acid 

Benzocaine 

Benzotrichloride 

Benzoylacetanilide 

l-Benzoylamino— 4-aminoanthraqiiinone 

2-Benzoylaraino-l,4-diethoxybenzene 

2-Benzoylamino-l,^-dinietnoxybenzene 

5-Benzoylamino-2-nitrodimethoxybenzene 

5-Benzoylaraino-2-nltrohydroquinone  diethyl  ester— 
6-Benzoylamino-3-(p-toluenesulfonamido)-i-methoxy- 
toluene. 

2-Benzoyl-4-chloro-3-nitrobenzoic  acid 

Benzoyl  J  acid 

2-Benzoylthiophene 

a-Benzylacetajnide 

ra-Benzyl-p-aniinophenol  hydrochloride 

Benzyl  chloride 

Benzyl  cyanide 

N-Benzyl-N-ethylaniline 

N-Benzyl-N-ethyl-p-nitrosoaniline 

3 -Benzy  1-7 -hydroxy-^ -methylcoumarin 

Benzylidlneacetophenone 

Bibenzoyl 

o-Biphenylamine 

"i-Biphenylamine 

p.p'-Bis(acetoacetanllide) 

N, N '-Bis ( acetoacetyl )benzidine 

N,N-Bis(2-hydroxyethyl)aniline 

N,N-Bis(2-hydroxyethyl-m-toluidine) 

'')'*'-Bis[2-(NHiiethyl-o-anisyldiazoamino)ethanesul- 
fonic  acid], 

N,N'-Bis-6-(l-naphthol-3-sulfonic  acid)urea 

B.O.N, 

Broenner ' s  ac  id 

Bromamine   acid 

p-Bromoacetamidoanthraquinone 

Bromobenzanthrone 

p-Broraomethylaminoanthraquinone 

■i-Bromo-N-methyl-l,9-anthrapyrldone 


n-Butyl-p-nitrobenzoate- 


Standard   (Chemical  Abstracts)  name 


p-Carboxybenzenesulfonamide 

3-Carboxy-/.-hydroxyacetanilide 

Cassella  acid 

Centralite 

Chicapo  acid 

Chlorinated  cresols 

2-Chloro-3-acetamino-9, lO-anthrahydroquinone  dlsul- 
fonic acid  ester. 

2-Chloro-3-acetaminoanthraquinone 

2-Chloro-3-acetamino-9,in-dihydroxyanthracene-9,in- 
disulfonic   acid   ester. 

Chloroacetylarsanilic   acid 

5-Ohloro-2-aminoanisole 

'i-Chloro-2-amino-6-benzenesulfonic  acid 

6-ChlQro-l-arainobenzotrifluoride 

Chloroaminophenol 

2-Chloro— 4-amlnotoluene 

5 -rhloro-2 -amino toluene 

m-Chloroaniline-o-sulfonie   acid 

p-Chloroaniline-ra-sulfonic   acid 

p-Chloroaniline-o-sulfonic  acid 

5-Chloroanisidine 

2-Chloro-3-anthracenecarboxylic   acid 

2-Chloroanthraquinone-3-carboxylic  acid 

2-Chlorobenzaldehyde-5-sulfonic   acid 

"i-Chlorobenzaldehyde-Z -sulfonic  acid 

l-Chloro-5-benzamideanthraquinone 

Chlorobenzanthrone 

"i-Chlorobenzotrifluoride 

Chlorobenzyl  cyanide 

l-Chloro-2-carboxyanthraquinone 

p-Chloro-m-cresol 

2-Chloro-l,^-dlhydroxyanthraquinone 

Chloro  H  acid 

5-Chloro-8-hydroxyquinoline 

3-Chloro-3  -methoxy-6-diphenylamineoarboxylic  aold, 


potassium  salt. 


Azobenzene. 

Isophthalic  acid. 

Terephthalic  acid. 

Phloroplucinol. 

"4,4'  -Diamino-2,2  '-biphenyldisulf  onic  acid. 

2-Amino-5-(p-aminophenyl)benzenesulfonic  acid. 

p-Arainobenzoic  acid,  ethyl  ester. 

o-tA  ,a  -Trichlorotoluene. 

a -Benzoylacetanilide. 

l-Amino-4-benzamidoanthraquinone. 

2 ', 5'-Diethoxybenzanilide. 

2',  5'-Dimethoxybenzanilide. 

2  ', 5  '-Dimethoxy-i ' -ni trobenzanilide. 

2',5'-Diethoxy-^'-nitrobenzanilide. 

5-Benzamido-4-methoxy-3-(p-toluenesulfonainido)tolu- 
ene. 

o-(<i-Chloro-3-nitrobenzoyl)benzoic  acid. 

6-Benzamido-l-naphthol-3-sulfonic  acid. 

Phenyl  2-thienyl  ketone. 

Hydroc innamamide . 

'i-Amino-a-phenyl-m-cresol  hydrochloride. 

a -Chloro to luene . 

Phenylacetonitrile. 

N-Ethyl-N-phenylbenzylamine. 

N-Ethyl-N-(p-nitrosophenyl)benzylamine. 

3-Benzyl-4^-methylumbelliferone. 

Chaloone. 

Benzil. 

2-Biphenylamine. 

Xenylamine. 

^,'l'-Biaoetoaoetanillde. 

^,'i'-Biacetoaoetanilide. 

2,2' -(Phenylimino )diethanol. 

2,2'-(n)-Tolylimino)diethanol. 

3, 3' -DiTiethoxy^,4' -biphenylbis  [3Hnethyl-3-triazene- 

ethmesulfonic  aeid],A 
6,6'-Ureylenebis[l-naphthol-3-sulfonic  acid] . 
? -Hydroxy -2 -naphthoic  acid. 
6-Amino-2-naphthalenesulfonic  acid. 
l-Amino-i-bromo-2-anthraquinonesulfonic  acid. 
1-Acetamido-^-bromoanthraquinone. 
3-Bromo-7-benz [de] anthracen-7-one. 
<i-Brorao-l-methylaminoanthraquinone. 
6-Bromo-3-methyl-7-dibenz  If ,ij] isoquinoline-2,7(3)- 

dione. 
p-Nitrobenzoic  acid,  n-butyl  ester. 

p-Sulfamylbenzoic  acid. 

5-Aoetamidosalicylic  acid. 

3-Araino-l,5-naphthalenedisulfonic  acid, 

N,N  '-Diethylcarbanilide. 

8-Amlno-l-naphthol-5,7-disulfonic  acid. 

Cresols,  chlorinated. 

2-Acetaraido-3-chloro-9, lO-dihydro-9, 10-anthradiol- 

9,in-disulfonio  acid,  diethyl  ester. 
2 -Ac  etamido -3 -chloroanthraquinone. 
2-Acetajnido-3-chloro-9,  lO-dihydro-9, 10-anthradiol- 

9,10-disulfonic  acid,  diethyl  ester. 
Chloroarsacetin. 
'+-Chloro-o-anisidine. 
''-Chlorometanilie  acid. 
6-Chloro-a-trifluoro-m-toluidine. 
2-Amino-'i-chlorophenol. 
3-Chloro-p-toluidine. 
'♦-Chloro-o-toluidine. 
2-Amino-6-chlorobenzenesulfonio  acid. 
6-Chlorometanllic  acid. 
2-Amino-5-chlorobenzenesulfonic  acid. 
•4-Chloro-o-anisidine. 
3-Chloro-2-anthraoenecarboxylic  acid. 
3 -Chloro -2 -anthraquinoneearboxy lie  acid. 
4-Chioro-3-formylbenzenesulfonic  acid. 
5-Chloro-2-formylbenzenesulfonic  acid. 
l-Benzamido-5 -chloroanthraquinone. 
Chloro-7-benz[  de]anthracen-7-one, 
■4 -Chloro-a,a,a-trifluoro  toluene. 
(p-Chlorophenyl)acetonltrile. 
l-Chloro-2 -anthraquinoneearboxy lie  acid. 
6-Chloro-m-cresol. 
2-Chloroquinizarin. 

8-Chloro-l-naphthol-3,6-disulfonic  acid. 
5-Chloro-8-qulnolinol. 

N-(m-Anlsyl)-4-ohloroanthranlllc  acid,  potassium 
salt. 


1 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


173 


Cyclic   intermediates:      Glossary  of  synonymous 


Common  name 


3-Chloro-4'-methoxy-6-diphenylajnlnecarl>oxylic  acid, 

potassium  salt, 
("i-Chloro-S-methoxy-N-methylphenyldlazoaminojaoetic 

acid, 

Chloromethylanthraquinone 

(5-Chloro-N-methyl-o-tolyldiazoamino)acetlc  aold 

o-Chloro-p-nitroanlline 

p-Chloro-o-nitroanHine 

i-Chloro-3-nitrobenzotrifluoride 

2-Chlorophenol 

^-Chlorophenol 

2-(m-Chlorophenyldlazoamino)-^-sulfobenzoic  acid 

Chlorophenylhydrazlne-p-sulfonio  aold 

2-Chloro-o-phenyl  phenol 

l-(2-Chloro^-sulfophenyl)-3-methyl-5-pyrazolone — 

o-Chloro-p-toluene  sodium  sulfonate 

4-Chlorotoluene-2-sulfonio  acid 

m-Chlorotoluenethloglycolio  acid 

5-Chloro-2-toluldine 

o-Chloro-m-toluidine-p-sulfonic  aold 

2-Chloro-p-toluidine-5-sulfonic  acid 

2-Chloro-5-toluldlne -^-sulfonic  aold 

Chlorotolylthioglyoolic  acid 

Chloro-sym-xylenol 

Chloroxylldenesulfonlo  acid 

Chromotropic  aold 

1,6-Cleve' s  acid 

1 , 7-Cleve ' s  ao Id ■ 

Cleve's  aold,  mixed- 

Cresidine 

m-Cresol  methyl  ether 

Cresols ,  mixed 

m-Cresolsulfonlo  acid 

o-Cresotlc  aold 

o-Cresotlnlc  aold 

m-Cresyl  methyl  ether 

psi-Cumidine 

Cuminaldehyde 

2-Cyanopyrldine 

3-CyanopyTidine 

"i-Cyanopyrldlne ■ 


Standard  (Chemical  Abstracts)  name 


Dahl's  aold 

Dehydrothlo-p-toluldlne 

Desoxyanlsoin 

Developer  Z ' 

3,6-Dlaininoaoridine 

m-Diamlnoanlsole 

3,3'-Dlamlnqazoxybenzene 

"ij^'-Dlamlno-ljl  -dlanthraqulnonylamlne 

•iji'-Diamino-ljl'-dlanthrimide 

Diamina-^ , ^ ' -dibenzoyl -1 , 1 ' -d  ianthraquinonelmlne — 
Diamlno-4,5-dibenzoyl-l,l  -dianthraquinonylamlne — 

l,4-Dlamino-2,3-dihydroanthraquinone 

3,6-Diamino-2,7-dimethylaoridine  hydrochloride 

4,i   -Diamlno--3,3'-dimethyl-5,5'-bisbenzenesulfonic 
acid, 

4,'4'-Diamino-2,2'-dlmethyldlphenylmethane 

p , p  -Diamlnod  ipheny Imethane 

p,p  -Diaminodiphenylsulfide 

3,3  '-Diamlnod  ipheny  1  urea 

Di(p-aminophenyl) sulfide 

l,3-Di(m-aminophenyl)urea 

2,6-Diaminotoluene-4-sulfonic  acid 

Diamylphenol 

l,5-Dianllinoanthraqulnone-o,o'-dlearboxylio  aold — 

o-Dianls Id  ine 

Dl (o-anisyldiazo )methylenebis ( iminoacetic  acid ) 

Di(o-anisyldiazo)methylenebis(iminopropionic  acid)- 


a ,  /3-Dlanisylglyool 

1, 1'  -Dianthraquinoneimlne 

1,1' -Dianthraquinonylamlne 

Dianthrlmide 

Diazoaminobenzene ■ ■ 

l-Diazo-2-naphthol-4-sulfonlo  aold 

Dibenzanthrone— 

2,2-Dibenzanthronyl-i 

13,13-Dibenzanthronyl 

Dibenzoyl 

4,5 -Dibenzoy lamidod lanthraqulnonylamlne - 
4,4'-Dibenzoyldiamlno-l,l'-^ianthrijnide- 
Dibenzyl 


N-(p-Anisyl)-4-ohloroanthranilio  acid,  potassium 

salt, 
l-('l-Chloro-o-anlsyl)-3-methyl-3-triazeneacetio  aold, 

l-Chloro-2-methylanthraquinone, 

l-(5-Chloro-o-tolyl)-3-inethyl-3-triazeneacetlc  acid, 

2-Chloro-4-nltroanlline, 

4 -Chloro -2 -nl troanl 1 ine , 

4-Chloro-a,a,a-trlfluoro-3-nitrotoluene. 

o-Ch] orophenol, 

p -Chloropheno 1 . 

2-{l-(m-Chlorophenyl)triazeno]-4-sulfobenzoic  acid, 

4-Chloro-3-hydrazlnobenzenesulfonic  acid. 

2 -Chloro -6 -pheny Iphenol , 

l-(6-Chloro-4-sulfophenyl)-3-methyl-5-pyrazolone, 

3-Chloro-p-toluenesulfonic  acid,  sodium  salt. 

5-Chloro-o-toluenesulfonlc  acid, 

4-Chloro-o-tolylmeroaptoacetic  acid, 

5 -Chloro -o -toluid  ine . 

2-Amlno-5-chloro-p-toluenesulfonlc  acid, 

6-Amino-4-chloro-m-toluenesulfonic  acid, 

2-Araino-5-chloro-p-toluenesulfonio  aold. 

4-Chloro-o-tolylmercaptoaoetlo  acid. 

4-Chloro-3,5-xylenol, 

6-Amlno-3-ohloro-2,5-xylenesulfonlo  aold, 

4,5-Dlhydroxy-2,7-naphthalenedisulfonic  acid, 

5-Amino-2-naphthalenesulfonio  aold, 

8-Amlno-2-naphthalenesulfonio  acid. 

5(and  8)-Amlno-2-naphthalenesulfonic  acid. 

5-Methyl-o-anlsldlne, 

m-Methylanisole, 

Cresylic  aold, 

5-Hydroxy-m-toluenesulfonlo  acid. 

2,3-Cresotic  aold, 

2,3-Cresotic  acid, 

ra-Methylanisole, 

Pseudocumidlne, 

Cumaldehyde, 

Picolinonitrile. 

Nlcotlnonltrile, 

Isonlootlnonitrile, 

6-Amino-l-naphthalenesulfonlc  aold, 

2-(p-Aminophenyl ) -6-methylbenzothlazole, 

a-(p-Anisyl)-p-methoxyaoetophenone, 

3 -Methyl -1 -phenyl -5 -pyrazolone , 

Proflavine  base. 

5-Methoxy-m-phenylenedlamine, 

m,m'-Azoxydianiline, 

1 , 1 ' -Iminod 1 -4-amlnoanthraquinone , 

1,1'  -Iminod 1 -4-aminoanthraquinone , 

1.1  -Imlnobls[4-benzamldoanthraquinone] , 
4,5  -Dlbenzamldo-1, 1  '-amlnodlanthraquinone. 
Acetate  leuco  violet, 

Acridlne  yellow, 

2.2  '-Diamino-5,5'-bi-m-toluenesulfonio  acid. 

4.4  '-Methylenebis[m-toluldine] , 
p,p '-Methylenedianiline, 

p,p '-Thlodlaniline, 

3,3'-Dlamlnooarbanilide. 

p,p'-Thiodlanlllne, 

3,3'-Diamlnocarbanlllde. 

3,5-Diamino-p-toluenesulfonio  aold, 

2, 4-Di-tert-amy Iphenol, 

1 , 5-Dianllino-2 , 6-anthraqulnonedloarboxylic  acid . 

3.3  -Dimetho3cybenzldlne, 

3.3'~Methylenebls[l-o-anisyl-3-triazeneaoetic  aci(}]  J 
3,3  '-Metl^lenebls[l-o-anisyl-3-triazenemethylaoetio  , 

acid] , 
l,2-Di-p-anlsyl-l,2-ethanediol,  ' 

1, l' -Iminodlanthraqulnone, 
l,l' -Iminodlanthraqulnone, 
1,1' -Iminodlanthraqulnone. 
1,3-Dlphenyltriazine, 
5-Naphth[l,2]oxadiazosulfonic  acid, 
Violan throne, 

;  4,4''-Bi-7-benz[de]  anthraeen) -7,  y'-dlone. 
(3,3'-Bl-7-benz[dejanthraoen)-7,7'-dlone, 
Benzil. 

4 . 5  '-Dlben^amido-1, 1 '-aminodianthraqulnonel 
1,1   -Imlnobls[4-benzajiiidoanthraquinone] . 
Bibenzyl. 


I' 


174 


UNITED  STATES  TARIFF  COMMISSION 


Cyclic    intermediate 


^ry  of  synonymous  names — Continued 


Common  n.ime 


-anthrazinetetrone' 


Standard  (Chemical  Abstracts)  name 


Dibenzyi aniline 

Dibenzyl  disulfide 

Dibenzyl  ether 

Dibenzyl  sodium  sulfanilate 

Dibromoaminoanthraquinone 

7,16-Dibromo-6,15-dihydro-5,9,l'i 

p-Dibromodihydroxynaphthalene 

2,6-Dibromo-l,5-dihydroxynaphthalene 

'i,5-Dlbromo-l,8-dihydroxynaphthalene 

1,4-Dichloroaniline 

2, 5-Dichloroaniline-<4-sulfonic  acid 

Dichloroanisyldiazodi-iminodiaeetic  acid 

Di(5-chloro-o-anisyldiazo)methylenebis(irainoacetio 

acid). 

1.5-Dichloro^,8-anthraquinonedisulfonlc  acid 

l,8-Dichloro-4,5-anthraquinonedisulfonic  acid 

2 , 6-Dichlorobenzalchloride 

o , o '-Dichlorobenzidine 

m,m'-Dichlorobenzidine  hydrochloride 

2,'i-Dichlorcbenzyl  chloride 

2,<i-Dichlorobenzylidene  chloride 

2,6-Dichlorobenzylidene  chloride 

Di('«-chToro-2-diazotoluol)methylenehis(iminoacetic 

acid) . 
2-' 2 , 5-Dichloro-N-ethylphenyldiazoamino )-5-sulfoben- 

zoic   acid, 

Dichlorohydroxybenzoylbenzoic  acid 

2,5-Dichlorophenylhydrazinesulfonic  acid 

l-(2,5-Dichlorophenyl)-5-pyrazolone-3-carboxylic  acid 

Di(5-ohloro-o-tolyldlazo)methylenebis(iminoacetic 

acid). 
Di(5-chloro-o-tolyldiazo)methylenebis(iminopropionic 

acid). 

Dicresyldisulfide 

Dlcyclohexyl 

Diethanolaniline 

Diethanol-m-toluidine 

1,^-Diethoxybenzene 

N-{2,5-Diethoxy-<4-nitrophenyl)benzamide 

N-(2,5-Diethoxyphenyl)benzamide 

p-Diethylaminobenzalaniline-o-sulfonic  acid 

Diethylaniline-ra-sulfonic  acid 

Diformyl-m-tolylenediamine 

1 . 2-Dihydroacenaphthylene 

1 .4-Dihydro-4-oxo-2,6-pyTidinedicarboxylic  acid 

1 , 3-Dihydroxyanthraquinone 

Ij/J-Dihydroxyanthraquinone 

1 , 5-Dihydroxyanthraquinone 

1,8-Dihydroxyanthraquinone 

2 , 6-Dihydroxyanthraquinone 

2,'4-Dihydroxybenzoic  acid 

2,3-Dihydroxy-l,'4-diaminoanthraquinone 

Dihydroxydibenzanthrone 

Sj'i-Dihydroxy-a-dimethylaminoacetophenone- 
5,5'-Dihydroxyd'i-2-naphthylamine-7,7^-disi 

IjS-Dihydroxy-'l.S-dinitroanthraquinone 

p,p'-Dihydroxydiphenyldimethylmethane 

''- ,  !•  '-Dihydroxyd  iphenylsulf  one 

f),5'-Dihydroxy-7.7'-disulfonio-2,2'-dinaphthylamine- 

Dihydroxyethylaniline 

Dihydroxyethyl-3-toluidine 

1 , 5-Dihydroxynnphthalene 

2 , 3-DlhydroxyTiaphthalene 

l,8-Dihydroxynaphthalene-3,6-disulfonic  acid 

1,8-Dihydroxynaphthalene— 4 -sulfonic  acid 

2,3-Dihydroxynaphthalene-6-sulfonic  acid 

Dimethanil-4-sodium  sulfonate 

2,3-Dimethoxybenzaldehyde 

3,i-Dimethoxybenzaldehyde 

o-Dimethoxybenzene 1  Veratrole 

1,2-Dimethoxybenzene Veratrole 

■4,<i'-Dimethoxybenzoin Anisoin, 

3,'i-Dimethoxybenzyl  alcohol Veratryl  alcohol. 

Di{methoxy-2-dlazo-4-chlorobenzoyl)methylenebis(imino-|  3.3 '-Methylenebis[l-(5-chloro-o-anisyl)-3-trlazene 

acetic  acid). 
Dlmethoxydiazodlphenylmethylenebis(iminoacetic  aoid)- 
DlmethoxydiazodiphenylJiiethylenebls(irairopropionic 

acid). 
2,2'-(3,3'-Dlraethoxy-N,N'-dimethyl-A,'4'-blphenylbis- 

diazoamino)dlethanesulfonic  acid. 

Di-p-raethoxyethylchalcone 

N-(2,5-Diraethoxy-4-nitrophenyl)benzamide 


isulfonic  acid 


N -Pheny Id  ibenzy lamine . 

Benzyl  disulfide. 

Benzyl  ether. 

N,N-Dibenzylsulfanilic  acid,  sodium  salt. 

1 -Amino -2,^-6 ibroraoanthraquinone . 

7, 16-Dibromoindanthrene. 

4,5-Dibromo-l,8-naphthalenediol. 

2,6-Dibromo-l,5-naphthalenediol. 

^,5-Dibromo-l,8-naphthalenediol. 

2,5-Dichloroaniline. 

2,5-Dichlorosulfanilic  acid. 

3,3'-Methylenebis[l-(5-chloro-o-anlsyl)-3-triazene- 

acetic  acid] . 
3, 3  '-Methylenebis [l-( 5-chloro-o-anisyl )-3-triazene- 

acetic  acid]. 
i,8-Dichloro-l,5-anthraquinonedisulfonic  acid. 
'i,5-Dichloro-l,8-anthraquinonedisulfonic  acid, 
a,  (X,  2 , 6-Tetrachlorotoluene . 
3,3'-Dichlorobenzidine. 
2, 2 '-Dichlorobenzidine  hydrochloride, 
a .  2 ,  -i-l^ichloro  toluene. 
?,?,2,'4-Tetrachlorotoluene. 
?, a, 2 , 6-Tetrachlorotoluene. 
3, 3'' -Methylenebis  [l-C-i-chloro-o-tolyl  )-3-triazene- 

acetic  acid]. 
2-[l-(2,5-Dichlorophenyl)-3-ethyl-3-triazene] -5-sul- 

fobenzoic  acid. 
o-(3,5-Dichlorcsalicyloyl)benzoic  acid. 
2,5-Dichlorohydrazinobenzenesulfonic  acid. 
l-( 2 , 5-Dichlorophenyl ) -5-oxo-2-pyrazoline-3-carbox- 

ylic  acid. 
3, 3' '-Methylenebis  [l-(5-chloro-o-tolyl)-3-triazene- 

acetic  acid] . 
3,3'-Methylenebis[l-(5-chloro-o-tolyl)-3-triazene- 

methylacetic  acid] . 
Cresyl  disulfide. 
Bicyclohexyl, 

2,2  '-(Pheny llraino)diethanol. 
2,2'-(m-Tolylimino)diethanol, 
p-Diethoxybenzene. 
2',5'-Diethoxy^''-nitrobenzanilide. 
2 ', 5' -Diethoxybenzanilide. 
N-(p-Diethylaminobenzylidene)aniline-o-sulfonic  acid. 

N,N-Diethyljnetanilic  acid. 

N,N'-Diformyltoluene-2,5-diamine. 

Acenaphthene. 

Chelidamic  acid. 

Xanthopurpurin. 

Quinizarin.  , 

Anthrarufin. 

Chrysazin. 

Anthraflavic  acid. 

P-Resorcylic  acid. 

1,^-Diaminohystazarin. 

16, 17-Dihydroxyviolanthrone. 

Adrenalone. 

6,6'-Iminobis[l-naphthol-3-sulfonic  acid], 

i,8-Dinitroanthraruf in. 

p,p  -Isopropylidenediphenol. 

p,p  -Sulfonyldiphenol. 

6,6'-Irainobis[l-naphthol-3-sulfonic  acid], 

2,2'-(Phenylimino)diethanol. 

2,2'-(m-Tolylimino)diethanol. 

1,5-Naphthalenediol. 

2 , 3-Naphthalenediol. 

';,5-Dihydroxy-2,7-naphthalenedisulfonic  acid. 

4,5-Dihydroxy-l-naphthalenesulfonic  acid. 

6,7-Dihydroxy-2-naphthalenesulfonic  acid. 

Isopropylideneaminobenzenesulfonic  acid,  sodium  salt, 

o-Veratraldehyde. 

Veratraldehyde. 


acetic  acid] . 
3,3'-Methylenebis[l-o-anisyl-3-trlazeneaoetlc  acid]. 
3,3'-Methylenebls[l-o-anlsyl-3-trlazenemethylacetic 

acid]. 
3,3'-Dimethoxy-4,4'-blphenylbls[3-methyl-3-trla2ene- 

ethanesulfonic  acid]. 
i-Ethyl-4,4'  -dimethoxychalcone. 
2' , 5' -Dlmethoxy-4'  -nitrobenzanilide . 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 

Cyclic    intermediates:      Oioss^ry  nf  xynonymnus   namp.-!— Cnnt  i  niied 


175 


Common  name 


(3,'i-Dimethoxyphen,vl)acetio  acid 

N-(2.5-Diraethox.vphenyl)benzamide 

2,<i-Di(p-raethoxyphenyl)-3-ethylhexane 

2,4-Di(p-niethoxyphenyl)-3-ethylhexene 

Sj'i-DiCp-methoxyphenyDhexane 

Dime thy lace tanilide 

Dlmethylaminoacetylcatechol 

N,N-Dimethyl-3-aminophenol 

Dimethylanillne 

Dime thy Ibenzene 

Sj-i-Dimethylbenzenesulfonanilide 

2,'i-Dimethyl-6-tert-butylacetophenone 

l,3-Dimethyl-5-tert-butylbenzene 

2,7-Dlmethylceroxanol 

Dimethyldianthraquinonyl 

2,2'  -Dimethyl-l.l-dianthraquinonylajnine 

2,7-Diraethylfluorane 

Dimethylhydroresorcinol 

Dimethyl-a-naphthylamine 

2,7-Dimethylquinoline 

0inaphtho[l,2,3-cd,3',2',l'-lid  perylene 

Dinaphtho[l,2,3-od,3',2',l'-lm]perylene-5,10- 
dione, 

1 ,  •i-Dinitrobenzene 

2,'i-Dinitrobenzene 

Dinitrochlorobenzene 

Dinitrochlorobenzenesulfonio  acid 

3 , 5  -Dini tro-<i-chlorobenzoic  acid 

2,6-Dinitro-4-chlorophenol 

Dinitro-o-oyolohexylphenol 

li.Y  -Dinitro-l,l'-dianthraquinonylamine 

Dinitrodibenzanthronyl 

Dinitrohydroxydiphenylamine 

Dinitrotetramethyldiaminodlphenylmethane 

2,'4-Dinitrotoluenesulfonic  acid 

1 , 5-Dioxaiiiidoanthraquinone 

Dioxy  S  acid 

Diphenyl 

2,4-Diphenylamine-l-hydroxyanthraquinone 

2,<V-Diphenylaraine-l-oxyanthraquinone 

Diphenyloarbazide 

Diphenylene  oxide 

Diphenyl  epsilon  acid 

Diphenyl  ether 

Diphenyl  ketone 

Diphenyljnethanol 

Diphenyl  oxide ' 

Diphenyl  silicon  diohloride 

Dipyrazoledianthrone 

1 , 3-Di -p-to luid  ineanthr aquinone 

l.A-Di-p-toluidineanthraquinone 

1. 3-Di  (p-to lylajnino)anthraquinone 

1,4-Di-p-tolylaminoaiithraquinone 


Standard  (Chemical  Abstracts)  name 


N-Ethanol-N-ethyl-4-nitrosoaniline 

2-Ethanolpyridine 

2-Ethoxyaniline 

■i-Ethoxy  aniline 

2-Ethoxy-6-sulfonaphthalene 

Ethyl-p-aminobenzoate 

Ethyl -o -amino -p-cresol 

Ethylaniline  (mono ) 

N,N-Ethylbenzylaniline 

Ethylbenzylanilinesulfonic  acid 

Ethylbenzyl-m-toluidine 

Ethylbenzyl-m-toluidine-o-sulfonic  acid 

Ethylene  lycol  raonophenylether 

Ethyl  hydrol 

Ethyl  ketone  base 

2-(N-Ethyl-2-methoxy-5-nitrophenyldia2oamino)-5-sul- 

fon, 

5-Ethyl-2-methylpyridine 

2-(N-Ethyl)-5-nitro-o-anisyldiazoamlno-5-sulfo- 

benzoic  acid, 

p-Ethylnitrobenzene 

Ethyl  p-nitrobenzoate 

Ethyl -p-nltrobenzoylacetate 

Ethyl  phenyl  ether 

Ethyl  salicyl  carbonate 

Ethylsulfobenzylaniline '■ 

N-Ethyl-o-toluidine-p-sulfonic  acid 


Fast  red  TR  base- 
p -Formy Inni 1 ine — 


Homoveratric  acid. 

2 ' , 5 ' -Dimethoxybenzanilide . 

2 ,  "i-Di  (p-anisyl )  -3-ethylhex'ine. 

2,'i-Di(p-anisyl)-3-ethylhexene. 

3,4-Di(p-anisyl)hexane, 

Acetoxylidide. 

Adrenalone. 

m-Dimethylaminophenol, 

Xylidine. 

Xylene. 

p-Toluenesulfono-o-toluidide. 

6-tert-Butyl-2,'i-dimf  thylaoetophenone. 

5-tert-Butyl-m-xylene. 

2,8-Dimethyl-13p-hydroxy-9(13P)-oeroxenone. 

2,2'-Dimethyl-l,l'-bianthraquinone. 

1,1'  -Iminobis [2-methylanthraquinone] . 

2' ,7' -Diraethylfluoran. 

Dimethyl-l,3-cyclohexanedione. 

N,N-Dimethyl-l-naphthylamine. 

m-Toluquinaldine. 

Violanthrene. 

Violanthrone . 

p -Dini  trobenzene . 

ra-Dinitrobenzene. 

l-Chloro-2,'i -dini  trobenzene. 

4-Chloro-3,5-dinitrobenzenesulfonic  acid. 

4-Chloro-3,5-dinitrobenzoic  acid. 

4-Chloro -2 , 6 -d  ini  trophenol . 

2-Cyclohexyl^,6-dinitrophenol. 

1 , 1'  -Iminodi-4-nitroanthraquinone. 

Dinitro(3,3'  -bi-7-benzL  de.'  anthracen)-7,7'-dione. 

p_(2,<4-Dinitroanilino)phenol. 

p,p'  -Methylenebis[N,N-dimethyl-2-nitroaniline]  . 

3,5-Dinitro-o-toluenesulfonic  acid, 

N,N'-(l,5-Anthraquinone)dioxamic  acid. 

•i , 5 -Dihydroxy-l -naphtha lene sulf oni c  acid. 

Biphenyl, 

2,4-Dianilino-l-hydroxyanthraquinone. 

2,'4-Dianilino-l-hydroxyanthraquinone. 

1,5-Diphenylcarbohydrazide. 

Dibenzofuran, 

8-Diphenylamino-l,6-naphthalenedi sulfonic  acid. 

Phenyl  ether. 

Benzophenone. 

Benzhydrol, 

Phenyl  ether. 

Dichlorophenylsilane. 

Pyrazole  anthrone  yellow. 

l,3-Di-p-(toluidino)anthraquinone. 

l,4-Di-p-(toluidino)anthraquinone. 

1 , 3-Dl-p-( toluidino )anthraquinone, 

l,'i-Di-p-(toluidino)anthraquinone, 

2-(N-Ethyl-4-nitrosoanilino)ethanol. 

2-PyTidineethanol. 

o-Phenetidine, 

p-Phenetidine. 

6-Ethoxy-2-naphthalenesulfonio  acid. 

p-Aminobenzoic  acid,  ethyl  ester. 

3-Ethylamino -p-cresol. 

N-Ethylaniline. 

N-Ethyl-N-phenylbenzylamine. 

a-(N-Ethylanilino)-p-toluenesulfonic   acid. 

N-Benzyl-N-ethyl-m-toluidine. 

'i-( N-Benzyl -N-ethy lamino ) -o-toluenesulf onic  ac id . 

2 -Phenoxye thano 1 . 

4,4' -Bis(diethylamino)benzhydrol, 

4,4' -Bis{diethylamino)benzophenone. 

2-[  3-Ethyl-l-(5-nitro-o-anisyl)-3-triazene] -5-sulfo- 

benzoic  acid. 
5-Ethyl-2-picoline. 
2-[3-Ethyl-l-(5-nitro-o-anisyl)-3-triazeneT  -5-siiIfo- 

benzoio  acid. 
1 -Ethyl -4-nitrobenzene. 
p-Nitrobenzoic  acid,  ethyl  ester, 
p-Nitrobenzoylncetic  acid,  ethyl  ester, 
Phenetole, 

o,o'-Carbonyldioxydibenzoic  acid,  diethyl  ester. 
a-(N-Ethylanilino)-p-toluenesulfonic  acid. 
3-Ethylamino-p-toluenesulfonic  acid. 

5-Chloro-o-toluidine. 
p-Aminobenzaldehyde. 


176 


UNITED  STATES  TARIFF  COMMISSION 

Cyclic    intermediates:      Glossary   of  synonymous  nc'mes — Continued 


Common  narrie 


p-Formyl-N,N-diethylaniline- 


C  acid 

Canrnia  acid 

Gajrana  diculfo  acid 

Clycerolmonoe thy lani line - 


H  acid 

Halocrin 

Hexahydrobenzoic   acid 

Hexahydropyridine 

Horaoveratrylaniine 

1,2-1,2-Hydrazinedibromoanthraquinone 

Hydrol 

Hydroquiiione  dimethyl  ether — 

o-Hydroxybenzyl  benzoate,  caleiijiii 

7-Hydroxycoumarin 

<i-Hydroxydiphenyl 

P-Hydroxyethyl-o-chloroaniline 

Hydroxyethylethylaniline 

Hyriroxyethylme thy lani line 

Hydro xyethyl-3-toluidine 

2-Hydroxy-3-raethoxybenzaldehyde — 

2-Hydroxy-3-methylbenzoie  acid 

2-Hydroxy-^-methylbenzoic  acid 

7-Hydroxy— 4-mothylcoumarin 

2 -Hydroxy -5-nitroaoetanilide 

p-Hydroxyphenylarsonic  acid 

p-Hydroxyphenyl -n-butylamine 

3-Hydroxyquinoline 


It- 


I  acid 

I  acjd  imide 

Isobuty]  p-nitrobenzoate 

Isod  ibenzanthrone 

p-Isoprcpy lani line 

p-Isopropylbenzaldehyde 

Isopropylbenzene 

Isjpropyl  p-to] uenesulfonate- 


'jcid 

acid    imide- 
acid   urea — 


K  acid 

Koch's  acid- 


Laki?  rcl  C  amine 

Lauren  I'  :■  acid 

Lend  atyphna lo 

I.i^ad  trini  troresorc  inate 

Leu<;o-L,-'.-(-li(m"thylamino)anthraquinon'^ 

Leiicoindophenol  BCFN 

Limoneni^ 


s-ilt- 


:id  — 


Me than 
Methari 

o-Mcthoxyacetani lide 

p-Methoxyacetani lide 

/, -M.-Hioxy—'. '-aminodiphenylamine 

2-Methoxy— 4-aminodiphenylamine-2-sulfonic 

Me  thoxyanll ine 

Me  Lhoxybenzene 

p-Methoxybenzoic  acid 

■  ^-Methoxy-3'-chloro-6  '-carboxydiphenylajnine,    potan- 
siiim  salt, 

2 -Me  thoxy-h ,9-dichloroacrid  i  no 

'. '-We  I. hoxy— 4 -ni  trod iphonylaraino-2' -sulfonic  acid 

Methoxy-ome.'a-;:ulfonic  acid 

6-Molhoxy-m-toliiidine 

"i-Mc'thyl-^. -aminodiphenylamine-2-K\ilfonlc  acid 

Mc thylajnino:;ulfobenzoic   acid 

o -Me  thy] aniline 

Moth,.  1  ani  line(mono ) 

2 -Me  thy Ibenzanthrone 

2'-Motliyl-3-benzidinof;nlloriic   acid 

Ml  thylenobisfN-p-iS-chloro-o-anisylazophenyl  )lmino- 
acntic   aoidl,    dl.':odiiim  salt. 

Methylcnebis(methylaminoantipyrine) 

Mi.'Lhyli-nebi;:(  toluenodi.'iminc) 

.'-Mfrthyi-'j -ethyl  pyridine 

.-Methyl -7-hydroxycoumarin 

Mt  ihyl-p-hydroxy-m-nilrobcnzoatn 

Mi'l.n,  lptinMylpyr'iZoioni>-3-:;iill'oni(;  .acid 


Standard  (Chemical  Abstracts)  name 


I 


p-Diethylaminobenzaldehyde. 

2-Naphthol-6,8-disulfonic   acid. 
7-Araino-l-naphthol-3-sulfonic   acid. 
7-Araino-l-naphtho 1 -3 , 6-d isulf onic   ac id . 
3-(N-Ethylanilino)-l,2-propanediol. 


8-Amiiio-l-naphthol-3,6-disulfonic  acid. 
6,9-Dichloro-2-methoxyacridine. 
Cyi'lohexanecarboxylic  acid. 

Piperidine. 

',  .-Dirapthoxyphenethylamine. 

7,16 -Dibromo  ind  anthrene , 

p,p' -Bis(diraethylaMino)benzhydrol. 

p-Dimethoxybenzene. 

Saligenin  benzoate,  calcium  salt. 

Umbelliferone. 

p -Pheny Ipheno 1 . 

2  - ( Chloroani lino ) ethanol . 

2-(N-Ethylanilino )ethanol. 

2-(N-Methylanilino)ethanol. 

2-(ra-loluidino)eth.anol. 

o-Vanillin. 

2,3-Cresotic  acid. 

2,4-Cresotic  acid, 

^-Methylumbelliferone. 

2-Acetamido^-nitrophenol. 

p-Hydroxybenzonearsonic  acid. 

p-Amino-N-(n-butyl) -phenol. 

8-Quinolinol. 

6-Araino-l-naphthol-3-sulfonic  acid. 

6,b'-lminobis[l-naphthol-3-sulfonic   acid], 

p-Nitrobcnzoic  acid,    isobutyl  ester. 

Isoviolnnthrone, 

Cumidine. 

Cumaldehyde. 

Cumene. 

p-Toluenesulfonic  acid,  isopropyl  ester. 

6 -Amino -1 -naphtho 1-3-sulfonic  acid. 
6,6'-Iminobis[l-naphthol-3-sulfonic  acid] . 
6,6'-Ureylenebis[l-naphthol-3-sulfonic  acid]. 

8-Amino-l-naphthol-3,5-disulfonic  acid. 
8-Amino-l, 3, 6-naphthalenetr isulf onic  acid. 

2-Amino-5-chloro-p-tolueneEulfonic  acid. 

5-Araino-l-naphthalenesulfonio  acid. 

Styphnic  acid,  lead  salt. 

Styphnie  acid,  lead  salt. 

l,.'.-Dimethylamino-9,in-anthradiol. 

•'.-(p-Dimethylaminoanilino)-l-naphthol. 

Dipentene, 


p,p'-Methylenebis;[N,N-diethylaniline] . 

^,i'-Meth,vlenebis[3-hydroxy -2 -naphthoic  acid]. 

o-Acetaninidide. 

p-Acetanisidide. 

N-(p-Ani:;yl  )-p-phenylenediamine. 

o-(i-Amino-2 -ani sidino)benzenesulf onic  acid. 


Ani 


idir 


Ani sole. 

Ani.Tic  acid. 

N-(p-Aiii.'iyl)-.-chloroanthranilic  acid,  pota^jsium 

salt. 
b,9-Dichloro-2-methoxyacridine. 
2-p-Anir:idino-5-nitrobenzenesulfonic  acid, 
o -An isidinome thane sulfonic  acid. 
5-Mcthyl-o-anisidino[NH2=l] . 
6-p-Toluidinomotanilic  acid. 
N-Methyl-5-.sulfoanthranilic  acid. 
o-Toluidine. 
N-Methylaniline. 

2-Methyl-7-benz[de]anthracen-7-one. 
S-Amino-2-('4-amino-m-toluidlno)benzenesulfonic  ac 
N,N'-Mcthylenebi;!tN-p-(5-chloro-o-anisylazo)phen.v 

jTlycinc],  disodium  i^alt. 
N,N'-Methylenebi.':[''.-methylaminoantipyTincl, 
'i, "i '-Me thy lenebis[toluene-2,'i -diamine] . 
:'-Ethyl-2-picoline. 

.-Methylumbelliferone, 
p-Hydroxy-m-nitrobenzoic  acid,  methyl  e;ter. 

t-Methyl-l-(m-.';'ilfophcnyl)-5-pyrazolone. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 


177 


Cyclic   intermediates:   Glossary  of  synonymous   names- -Cont  iniied 


Common  name 


Standard  (Chemical  Abstracts)  name 


MethylphenylpyTazolone-<i-sulfonio  acid- 

2-Methylpiperidine 

Methvlpyridine 

2-Methylquinoline 

Methyl-p-toluenesulfonate 

P-Methylumbelliferone 

Miohler ' s  hydrol 

Mlchler ' s  ketone 

Mixed  oresols,  refined 

Monobromobenzene 


Monoohlorobenzene Chlorobenzene  (mono 


Naphthalene  sodium  sulfonates 

Naphthalene-|3-thiorlycolio  aoid 

o-Naphthionio  acid 

a-Naphthol 

P-Naphthol 

l-Naphthol-8-chloro-3,6-disulfonic  aoid 

2-Naphthol  ethyl  ether 

2-Naphtholthioindoxyl 

Naphthosulfoehloride 

Naphthylacetonitrile 

a-Naphthylamine 

P-Naphthylamine 

l-Naphthylamine-3,6-disulfonic  acid 

l-Naphthylamine-3,8-disulfonic  aoid 

l-Naphthylamine-'4,7-di sulfonic  acid 

1 -Naphthy lamine -^ , 8-d i sulfonic  acid 

2-Naphthylamlne-l,5-disulfonic  aoid 

2-Naphth,v'lamine-3,6-disulfonio  acid 

2-Naphthyiamine-4,8-disulfonio  aoid 

2-Naphthylaraine-5,7-disulfonic  acid 

2-Naphthylamine-6,8-disulfonic  acid 

l-Naphthylaraine-2-sulfonic  acid 

l-Naphthylaraine-3-sulf onic  acid 

l-Naphthylainine-4-sulfonio  acid 

l-Naphthylaniine-5-sulfonic  aoid 

l-Naphthylajiiine-6-sulfonic  acid 

l-Naphthylainine-6(and  7)-sulfonio  acid 

l-Naphthylamine-7 -sulfonic  aoid 

l-Naphthylamine-8-sulfonic  acid 

2-Naphthylamine-l-sulfonic  aoid 

2 -Naphthy laraine -5 -sulfonic  aoid 

2-Naphthylamine-6-sulfonio  aoid : 

2-Naphthylamine-8-sulfonio  acid 

l-Naphthylamine-3,6.8-trisulfonic  acid 

2-Naphthylainine-3,6,8-trisulfonic  aoid 

l-Naphthylamino-2-carboxylic  aoid  anthraquinone 

a -Naphthyl  isocyanate 

Naph thy Imethane sulfonic  acid 

P -Naphthylthioglycolio  aoid 

Nevlle  and  Winther's  acid 

3-Nitro-^-aminoanisole 

'4-Nltro-2-aminoanisole 

5-Nitro-2-aminoanisole 

6-Nitro-2-ajninoanisole 

o-Nitro-p-aminophenol 

p-Nitro-o-aminophenol 

S-Nitro-o-aminophenol 

4-Nitro-2-aminophenol-6-sulfonio  aoid 

6-Nitro-2-aminophenol-4-sulfonic  aoid 

4-Nitro-4'  -amino-2-sulfodiphenylainine 

5 -Nitro -2 -amino toluene 

p-Nitroaniline-o-sulfonic  acid 

ra-Nitro-p-anisidine 

3-Nitro-p-anisidine 

'i-Nltro-2-anisidine 

5-Nitro-2-anisidine 

2-Nitroanisole-i-sulfodiethylamide 

9-Nitroanthra( 1,9, 4,10 )bis( 1,2,3 )oxathiazine-2.7-bis- 
dioxide. 

l-Nitroanthraquinone-2-oarboxylio  aoid 

Nitrobenzene-2,5-disulfonic  acid 

l-Nltrobenzene-4-sulfonic  acid 

2-Nitrobenzenesulfonic  acid 

3-Nitrobenzenesulfonic  aoid 

3-Nltrobenzenesulfonyl  chloride 

m-Nitrobenzoyl  J  acid 

p-Nitrobenzoyl  J  aoid 

m-Nitrochlorobenzene 

o-Nitrochlorobenzene 

p-Nitroohlorobenzene 

2-Nitro-l-ohlorobenzene-4-sulfobutylainide 


3-Methyl-l-(p-sulfophenyl) -5 -pyrazolone. 

2-Pipecoline. 

Picoline. 

Quinaldine, 

p-Toluenesulfonio  aoid,  methyl  ester. 

<i-Methylurabelliferone. 

4.4'  -BisTdiraethylamino]  benzhydrol, 

4 , 4' -Bis [dime thy laminol  benzophenone . 

Cresylio  acid, refined, 

Bromobenzene. 


Naphthalenesulfonio  acids,  sodium  salt  (mixed). 
2-Naphthylmeroaptoacetio  aoid. 
l-Amino-2 -naphthalenesulfonio  acid. 
1-Naphthol. 
2-Naphthol. 

8-Chloro-l-naphthol-3,6-disulfonic  acid. 
2-Ethoxynaphthalene. 

|i  -( 2  -[{yd  roxynaphthy  1 )  -3  -thi  anaphtheno  1 . 
1-Naphthalenesulfonyl  chloride. 
Naphthaleneacetonitrile, 
1-Naphthylamine. 
2-Naphthylamine. 

5-Amino-2,7-naphthalenedisulfonio  acid. 
8-Amino-l,6-naphthalenedisulfonio  acid. 
4-Amino-l , 6-naphthalenedisulf onic  ac id . 
4-Anino-l,5-naphthalenedisulfonio  acid. 
2-Amino-l, 5 -naphthalenedi sulfonic  aoid. 
3 -Amino -2, 7-naphthalenedi sulfonic  acid. 
3-Amino-l, 5 -naphthalened i sulfonic  ao id . 
6-Amino-l, 3-naphthalenedisulf onic  acid. 
7-Amino-l , 3-naphthalenedisulf onic  ao  id . 
l-Amino-2 -naphthalenesulfonio  acid. 
4-Amino-2 -naphthalenesulfonio  acid. 
Naphthionic  aoid. 

5 -Amino -1 -naphthalenesulfonio  aoid, 
5-Amino-2 -naphthalenesulfonio  acid. 
5(and  8)-Amino-2-naphthalenesulfonio  acid. 
8-Amino-2 -naphtha lenesulf onic  aoid. 
8-Amino-l -naphthalenesulfonio  aoid. 
2 -Amino -1 -naphthalenesulfonio  acid. 
6-Amino-l -naphtha lenesulf onic  aoid. 
6-Amino-2 -naphtha lenesulf onic  aoid. 
7-Amino-l -naphthalenesulfonio  acid. 
8-Amino-l, 3, 6-naphthalenetrisulfonio  acid. 
7-Amino-l, 3, 6-naphthalenetrisulf onic  aoid. 
l-(l-Naphthylamino)-2-anthraquinoneoarboxylio  acid. 
1-Naphthyl  isocyanate. 
Naphthalenemethanesulfonio  aoid, 
2-Naphthylmercaptoacetio  aoid, 
l-Naphthol-4-sulfonic  acid, 
2-Nitro-p-anisidine, 
5-Nitro-o-anisidine, 
4-Nitro-o-anisidine. 
3-Nitro-o-anisidine. 
4-Amino-2-nitrophenol, 
2-Amino-4-nitrophenol. 
2-Amino-5-nitrophenol. 

2-Amano-4-nitro-l-phenol-6-sulfonio  acid. 
2-Amino-6-nitro-l -phenol -4 -sulfonic  acid. 
2-(p-Aminoanilino)-5-nitrobenzenesulfonio  acid. 
4-Nitro-o-toluidine. 
2-Amino-5-nitrobenzenesulfonio  aoid. 
2-Nitro-p-anisidine. 
2-Nitro-p-anisidine. 
5-Nitro-o-anisidine. 
4-Nitro-o-anisidine. 

N,N-Diethyl-3-nitro-p-anlsolesulfonamide. 
9-Nitroanthra[l,9-de,4,10-d'e'l  bis [1,2, JJoxathiazine- 
2,7-blsdioxide. 
l-Nitro-2-anthraquinoneoarboxylio  acid, 
2 -Nitro-p-bonzeiiodi sulfonic  acid, 
p-Nitrobenzenesulfonio  aoid. 
o-Nitrobenzenesulfonic  acid. 
m-Nitrobenzenes\ilfonic  acid. 
m-Nitrobenzcnesulfonyl  chloride. 
6-(m-Nitrobenzamido)-l-naphthol-3-sulfonie  icid. 
6-(p-Nitrobonzamido)-l-naphthol-3-sulfonic  aoid. 
1-Chloro -3 -nitrobenzene. 
l-Chloro-2 -nitrobenzene. 
1 -Chloro  — 4-ni  trobenzene . 
N-Butyl— i-chloro-'-nitrobenzenc^-'ilfonamide. 


178 


UNITED  STATES  TARIFF  COMMISSION 

Cyclic   intermediates:     Glossary  of  synonymous   names— Continued 


2-Nitro-l-ohlorobenzene— 4-sulfodiethylaraide 

o-Nitrochlorobenzene-p-sulfonio  acid 

p-Nitrochlorobenzene-o -sulfonic  acid 

3-Nitro^-chloroben2oylbenzoic  acid 

4-Nitro-6-ehloro-l,3-di]iiethoxybenzene 

2-Nitro-4-chlorophenol 

2-Nitro-^-chlorophenol-6-sulfonic  acid 

m-Nitro-p-chloro toluene 

o-Nitro-p-chlorotoluene 

p-Nitro-o-chloro toluene 

2-Nitro-4-ohlorotoluene 

m-Nitro-p-cresol ■ 

Nitrocresyl  methyl  ether 

Ni  tro -p -d  i  chlorobenzene 

o-Nitrodiphenyl 

p-Nitrodiphenyl 

'4-Nltro-2-diphenylainine-sulfonio  acid 

•4-Nitrodiphenylamino-2-sulfonic  acid 

2-Nitrohydroquinone,  diethyl  ether 

2-Nitrohydroquinone,  dimethyl  ether 

3-Nitro-4-hydroxy-l-phenylarsonic  acid 

6-Nitro -4 -methoxy-3-amino toluene 

2-Nltro-^-methoxy-5-(p-toluenesulfonamido)toluene- 

"i-Nitro-l-methylaniline 

l-Nitro-2-methylanthraquinone 

2-Nitronaphthalene-4,8-disulfonic  acid 

7-Nitro-l,5-naphthalenedisulfonic  acid 

"i-Nltronaphthalic  acid  tolylimide 

3-Nitrophenylhydrazine ■ 

l-(m-Nitrophenyl )-5-pyTazolone-3-carboxylic  acid — 

Nitropyrazolonecarboxylic  acid 


Standard  (Chemical  Abstracts)  name 


p-Nitrosodiethylaniline 

p-Nitrosodimethylaniline 

Nitroso-p-naphthol 

3-Nitro-5-stearoylamino-p-toluenesulfonio  acid 

i-Nitrotolueneanilide 

6-Nitro-3-(p-toluenesulfone)amino-4-methoxytoluene 

4'-Nitro-p-toluenesulfone-o-toluide 

o-Nitrotoluenesulfonic  acid 

p -Ni trotoluene -o -sulfonic  acid 

m-Nltro-o-toluidine 

m-Nitro-p-toluidine 

p-Nitro-o-toluidine 

3-Nitro-4-toluidine , 

'i-Nitro-2-toluidine 

5-Nitro-2-toluidine 

Nitrotoluidine  sulfone 


5-Nitro-o-toluidine-4-sulfonic  acid- 

5-Nitro-l,2,'i-trichloroben2ene 

Nitroviolanthrene 

p-Nitro-o-xylene 

'i-Nitro-l,3-xylene 

2-Nitro-l,^-xylol 

'l-Nltro-l ,  3-xylol 


Qrthanilic  acid 

Oxalyl-p-nitroaniline 

Oxalyl-m-phenylenediamine- 
Oxalyl-p-phenylenediamine- 
Oxo-l,<i-pyran-2,6-dicarboxylio  acid- 
2-Oxycarbazole- 
a-Oxynaphthoic  acid- 
p-Oxynaphthoic  acid- 


Perl  acid- 

Pherie thy Ima Ionic  acid,  diethyl  ether- 

l-Phenylacetylcarbinol 

P-Phenylacrylophenone 

2-Phenylamlne-5-n.iphthol-7 -sulfonic  ncid 

2-Phenylamine-8-naphthol-6-sulfonic  acid  — 
N-Phenylaniline 

Phenylarsonic  acid 

Phenylbiphenyl 

Phenyl  bromide 

l-Phenyl-3-carboxy-5-pyrazolone-4-sulfonlc 


Phenyldiethanolamine 

m-Phenylenedlaminedisulfonlc  acld- 

m-Phenylenedlamlnesulfonic  acid 

P-Phenylenediaminesulfonic  acid 


<;-Chloro-N,N-diethyl-3-nitrobenzenesulfonamide. 
4-Chloro-3-nitrobenzenesulfonic  acid. 
2-Chloro-5-nitrobenzenesulfonic  acid. 
o-('i-Chloro-3-nitrobenzoyl)benzoic  acid. 
6-Chloro-l ,  3-d  ijnethoxy -4 -nitrobenzene. 
4— Chloro-2-nitrophenol. 

4-Chloro-2-nitro-l-phenol-6-sulfonic  acid, 
4-Chloro-3-nitro toluene. 
■4 -Chloro-2-ni  tro  toluene. 
2-Chloro-4-nitrotoluene. 
'i-Chloro-2-nitro  toluene. 
2-Nitro-p-cresol. 
■i-Methyl-o-nitroanisole. 
1,4-Diohloro -2 -nitrobenzene. 
2-Nitrobiphenyl. 
4-Nitrobiphenyl. 

2-Anilino-5-nitrobenzenesulfonic  acid. 
2-Anilino-5-nitrobenzenesulfonic  acid. 
1,4-Dlethoxy -2 -nitrobenzene. 
1,4-Dimethoxy -2 -nitrobenzene. 
4-Hydroxy-3-nitro-l-ben2enearsonic  acid. 
■4-Methyl-5-nitro-o-anisidine. 

N-(5-Methyl-4-nitro-o-anisyl)-p-toluenesulfonamide, 
5-Nitro-o-toluidine. 
2-Methyl-l-nitroanthraquinone. 
3 -Ni tro -1 , 5 -naphthalenedisulf onic  ac id . 
3-Nitro-l,5-naphthalenedisulfonic  acid. 
4-Ni  tro -N-toly Inaphthalimide . 
m-Nitrophenylhydrazine. 

l-(m-Nitrophenyl)-5-oxo-2-pyrazoline-3-carboxylic 
acid. 

l-(m-Nitrophenyl)-5-oxo-2-pyrazoline-3-carboxylic 

acid. 
N,N-Diethyl-p-nitrosoaniline. 
N,N-Dimethyl-p-nitrosoaniline. 
l-Nitroso-2-naphthol. 

3-Nitro-5-stearoylamido-p-toluenesulfonic  acid. 
2-Methyl-5-nitrodiphenylamine. 

N-(5-Methyl-4-nitro-o-anisyl)-p-toluenesulfonamide. 
N-(4-Nitro-o-tolyl)-p-toluenesulfonamide. 
3-Nitro-p-toluenesulfonic  acid. 
5-Nitro-o-toluenesulfonic  acid. 
4-Nitro-o-toluidine, 
2-Nitro-p-toluidine. 
5-Nitro-o-toluidine. 
2-Nitro-p-toluidine. 
5-Nitro-o-toluidine. 
4-Nitro-o-toluidine. 
4"-Nitro-p-toluenesulfono-o-toluide. 
3-Araino-5-nitro-p-toluenesulfonic  acid. 
1.2,4-Trichloro-5-nitrobenzene. 
16-Nitroviolanthrone . 
4-Ni tro -o -xylene. 
"i-Nitro-m-xylene. 
2-Nitro-p-xylene. 
4-Nitro-ra-xylene. 

o-Aminobenzenesulfonic  acid. 
N,N'-Di(p-nitrophenyl)oxamide. 
N,  N  '-Di  (m-aminopheny  1  )oxaiiiide . 
N, N  '-Di (p-aminophenyl )oxaraide. 
Chelidonic  acid. 
2 -Hy droxycarbazo le . 
l-Hydroxy-2-naphthoic  acid. 
3-Hydroxy-2-naphthoic  acid. 

l,4,5,8-Tetrakis[l',l",l"',]""-anthraquinonyl- 

aminol anthraqulnone . 
8-AmIno-l -naphtha lenesulf onic  acid. 
Ethylphenylmalonic  acid,  diethyl  ester. 
l-Hydroxy-l-phenyl-2-propanone. 
Chalcone. 

6-Anilino-l-naphthol-3-sulfonic  acid. 
7-Anilino-l-naphthol-3-sulfonic  acid. 
Dlphenylamine. 
Benzenenrsonic  acid. 
Terphenyl. 
Bromobenzene . 

5-Oxo-"l-(p-Gulfophenyl)-2-pyrazoline-3-cnrboxy]ic 

acid. 
2 . 2 '-(Phenyl imino )d  iethanol. 
4, 6 -Diamine -m-benzenedlsulf onic  acid. 
2,4-Diaminobenzenesulfonlc  acid. 
2.5-Diaminobenzenesulfonic  acid. 


^ 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 

Cyclic    intermediates:    Glossary   of   synonymous   names- -Cr>nt  irwu 


179 


Ccmmon  name 


Standard  (Chemical  Abstracts)  name 


Phenylene  nerol  acid 

Phenylethanolamine 

Phenylethylmalonic  ester 

Phenyl  f;amma  acid 

Phenylhydrazine-p-sulfonic  acid 

Phen,Ylhydrazine-2 -sulfonic  acid 

Phenylhydrazine-3-sulfonio  acid 

N-Phenyl-N'-({'  -hydroxyethyl)  thiourea 

Phenyl  isocyanate 

Phenyl  J  acid 

Phenylmalonic  ester 

Pheny Ime thane sulfoni c  acid 

N-Phenyl-1-naphthylaraine-S-sulfonic  acid 

a -Phenyl -p -( 4-oxophenyl )propionic  acid 

Phenyl  peri  acid 

N-Phenyl-p-phenylenediaminesulfonic  acid 

l-Phenyl-5-pyrazolone-3-carboxylio  acid,  ethyl  ester- 


Phenyl  silicon  chloride 

1-Phenyl— 4-sulfo-5-pyrazolone-3-oarboxylio  acid- 


Phthalyl  chloride 

Piperidinopropyl  alcohol 

Polychlorodiphenyl 

Potassium-3-chloro-6-oarboxy-3-methoxydiphenylamine- 


n-Propyl  p-nitrobenzoate- 

Pyrazo Ian throne 

Pyrazolone  C 

Pyrazolone  T 


Quinophthalone- 


R  acid 

2R  acid 

Red  KB  base 

Rhoduline  acid- 


S  acid 

2S(SS)  acid 

Schaeff er' s  acid 

Silver  salt 

Sodium  oarbolate 

Sodium  naphthionate 

Sodium  phenate 

Sodium -o-phenylphenolate 

Sodium  tetrachlorophenolate 

Sodium  trichlorophenolate 

Sulfo  BB  acid 

o-Sulfobenzaldehyde 

l-Sulfo-5-nitroanthraquinone 

Sulfopheny Ime thy Ipyrazo lone 

l-(p-Sulfophenyl)-5-pyTazolone-3-carboxylic  acid- 


Tetraaminoditoly Ime thane 

Tetrachloroquinone 

Tetraethyldiaminobenzhydrol 

Tetraethyldiaminobenzophenone 

Tetraethyldlaminodiphenylmethane 

Tetraethyldiaminotriphenylmethane 

Tetramethyldiaminoacrid  ine  hydrochloride 

Tetramethyldiaminobenzophenone — ' 

Tetramethyldiaminobenzoylhydrol 

Tetramethyldiaminodipheny Ime thane 

Tetramethyldiaminodiphenylmethanesulfonic  acid  and 

salt. 

Tetramethyldiaminotriphenylraethane 

Thioaniline 

Thioanilinedisulfonic  acid 

p I p' -Thiobis (<i-amino-o-benzenesulf onic  acid ) 

Thiosalioylic  acid -. 

Tobias  acid 

Tolazine  base 

o-Tolidinedisulfonio  acid 

a-Toluamide '. 

p-Toluenesulfochloride 

4-Toluenesulfonamido-l-aminoanthraquinonesulfonio 

acid, 

'i-Toluic  acid 

a-Tolulc  acid 

i-Toluidine-a-sulfanilide 

m-Toluidine-o-sulfonio  acid 


6-(p-Aminoanilino)metanilic  acid. 
2-Anilinoethanol. 

Ethylphenylmalonic  acid,  diethyl  ester. 
7-Anilino-l-naphthol-3-sulfonic  acid. 
p-Hydrazinobenzenesulfonio  acid, 
o-Hydrazinobenzenesulfonic  acid. 
m-Hydrazinobenzenesulfonic  acid. 
l-(2-Hydroxye thy l)-3-phenyl-2 -thiourea. 
Isocyanic  acid,  phenyl  ester. 
6-Anilino-l-naphthol-3-sulfonio  acid, 
Phenylmalonic  acid,  diethyl  ester, 
a-Toluenesulfonic  acid. 
8-Anilino-l-naphthalenesulfonic  acid. 
P-(p-Hydroxyphenyl)-a-phenylpropionio  acid. 
8-Anilino-l-naphthalenesulfonic  acid. 
5-Amino-2-anilinobenzenesulfonio  acid. 
5-0xo-l-phenyl-2-pyrazoline-3-carboxylic  acid,  ethyl 

ester. 
Triohlorophenylsilane. 
5-Oxo-l-(p-sulfophenyl)-2-pyrazoline-3-carboxylic 

acid. 
Phthaloyl  chloride. 
1 -Piper id inepropanol, 
Polychlorob  ipheny 1 , 
2-(m-Anisyl)-4-chloroanthranilio  acid,  potassium 

salt. 
p-Nitrobenzoic  acid,  n-propyl  ester. 
Anthra  L 1 , 9 J  pyrazol-6 ( 2 ) -one . 
3-Methyl-l-(p-sulfophenyl)-5-pyTazolone. 
5-0xo-l-(p-sulfophenyl)-2-pyrazoline-3-carboxylic 

acid, 

2,2'  -(l,3-Indandione)quinoline, 

2-Naphthol-3,6-disulfonic  acid. 

7-Amino-l-naphthol-3,6-disulfonic  acid. 

4-Chloro-o-toluidine, 

6,6^ -Iminobis[  l-naphthol-3-sulfonic  acid]  , 

8-Araino-l-naphthol-5-sulfonic  acid. 
8-Amino-l-naphthol-5,7-disulfonic  acid. 
2-Naphthol-6-sulfonic  acid. 
2-Anthraquinonesulfonic  acid,  sodium  salt. 
Phenol,  sodium  salt. 
Naphthionic  acid,  sodium  salt. 
Phenol,  sodium  salt. 
o-Phenylphenol,  sodium  salt. 
2,3,'4,6-Tetrachlorophenol,  sodium  salt. 
2,'4,5-Trichlorophenol,  sodium  salt. 
<i-Sulfo-o-benzoylbenzoic  acid, 
o-Formylbenzenesulfonic  acid. 
5-Nitro-l-anthraquinonesulfonic  acid, 
3-Methyl-l-p-sulfophenyl-5-pyrazolone. 
5-0xo-l-(p-sulfophenyl)-2-pyrazoline-3-carboxylic 
acid, 

5,5'  -Methylenebis[toluene-2,4-diamine]  . 

Chloranil. 

■4,4'  -Bisfdiethylaminojbenzhydrol, 

•iji'-Bisfdiethylaminojhenzophenone. 

p,p'-Methylenebis[N,N-diethylanilinel . 

p,p'  -Benzylidenebisf  N,N-diethylaniline] . 

2,7-Bis[dimethylaminol  acridine  hydrochloride. 

4,4' -Bis[dimethylamino]benzophenone. 

4,4' -Bis[dimethylamino]benzhydrol. 

p,p'-Methylenebis[N,N-dimethylaniline] . 

Bis[p-dimethylaminophenyl]methanesulfonic  acid  and 

salt, 
p,p'  -Benzylidinebis[N,N-dimethylaniline]  . 
p,p' -Thiodianiline, 
6,6'-Thiodimetanilic  acid, 
6,6'-Thiodimetanilio   acid, 
o-Mercaptohenzoic  acid, 
2-Amino-l-naphthalenesulfonic  acid, 
3-Amino-6-hydroxy-2-methylphenazine, 
2,2' -Diamino-5,5'-bi-m-toluenesulfonic  acid, 
a-Phenylacetamide, 
p-Toluenesulfonyl  chloride, 
l-Araino-4-(p-toluenesulfonamldo ) -2-anthraquinone- 

sulfonic  acid. 
p-Toluic  acid, 
Phenylaeetic  acid, 
o-Aminobenzenesulfon-p-toluide, 
4-Amino-o-toluenesulfonic  acid. 


180 


UNITED  STATES  TARIFF  COMMISSION 


jiossary  of  nynonymu'i: 


Common  name 


•n'-^r^  (Chemical  Abstracts)  name 


m-Toluidine-p-3uli'onic  acid 

c-Toluidine-m-sulf jnic  acid 

o-Tolu id ine-omef^a -sulfonic  acid 

p-Toluidine-m-sulfonic  acid 

p-Toluidine-o-sulfonic  acid 

p-Toluidine-o-sull'onic  acid,  isopropyl  ester- 

3-Toluidine-6-sulfonic  acid 

a-Tolunitrile 

<i-Tolunitrile 

p -To lyl-o -benzoic  acid 

o-Tolylcarbinol 

p-m-Tolylenediamine 

4-in-Tolylenediaraine 

5-m-Tolylenediamine 

m-To ly lened iaminesulf onic  ac id 

Tolyl  peri  acid 

2,'4,6-Triajninobenzene  trihydrochloride 

2,4,6-Triaiiiinotoluene  trihydrochloride 

Trianthraquinonyldi-imide 

1,4-rrianthriraide 

1,2,4-Trihydroxyanthraquinone 

1,2,6-Trihydroxyanthraquinone 

1,3,5-Trimethylbenzene 

2,'4,6-Trimethylpyridine 

Trinitrophenol 

2,4,6-Trinitroresorcin 

1,2 , 4-Trioxyanthraquinone 

Triphenyl  silicon  chloride 


3,3' -Ureyleneani 1 ine - 


Vinylb 


2 . 4 -Xylenesulf onani lide- 

m-Xylidine  acetate 

m-Xylidinesulfonic  acid- 
Xylyl  chloride 


2-Amino-p-toluenesulfcnic  acid. 

4-Airiir.o-m-toluenesulf&nic  acid, 

o-Ioluidinomethanesulfonic  ^cid, 

6-Araino-m-toluenesulfonic  acid. 

5-Aniino-o-toluenesulfcnic  acid. 

5-Ainino-o-toluenesulfonic  acid,  isopropyl  ester. 

4-Amino-o-toluenesuironic  acid. 

Fheaylacetonltrile. 

p-Tolunitrile. 

o-(p-Tolyl)benzoic  acid. 

2-Methylbenzyl  alcohol. 

Toluene-2,5-diamine. 

Toluene -2, 4 -diamine. 

Tolucne-3,5-diamine. 

2,4-Diaminc -m-toluenesulfonic  acid. 

8-(p-loluidino)-l-naphthaleneoulfonic  acid. 

1,3,5-Benzenetriainine  trih,ydrochloride. 

2,4,6-Toluenetriamine  trihydrochloride. 

l,4-Bis[l-anthraquinonylaminolanthraquinone. 

l,4-Bis[l-anthraqainonylamino]anthraquinone. 

Purpurin. 

Flavopurpurin. 

Mesitylene. 

s-Collidine. 

Picric  acid. 

Styphnic  acid. 

1 , 2, 4-Trihydroxyanthraqulnone. 

Chlorotriphenylsilane. 

l,3-Di(m-aminophenyl)urea. 

Styrene . 

p-Toluenesulfono-o-toluidide. 
2,4-Xylidlne  acetate. 
2-Amlno-3,5-xylenesulfonic  acid, 
4-ChloroHii-xylene. 


SYNTHETIC  ORGANIC  CHEMICALS,  1953 
D.  Production  and  Sales  of  Cellulose  Plastics 


181 


Cellulose  plastics  are  derived  from  cellulose  acetate,    cellulose 
propionate,    cellulose  butyrate,    and  mixtures  of  cellulose  esters, 
and  from  cellulose  nitrate  and  ethyl  cellulose.    The  most  important 
uses  of  cellulose  plastics  are  in  the  manufacture  of  molded  and  ex- 
truded articles  and  accessories  such  as  umbrella  handles,    toys, 
buckles,    and  fittings  for  household  and  automotive  equipment,    and 
in  packaging.    The  statistics  given  in  table  30  were  compiled  from 
the  Tariff  Commission's  monthly  reports  on  the  production  and 
sales  of  synthetic  plastics  and  resin  materials. 

Production  of  cellulose  plastics  as  a  group  in  1953  amotmted  to 
129  million  pounds --an  increase  of  31.4  percent  from  the  output 
of  98  million  pounds  reported  for    1952.    Sales    in    1953   were  125 
million  pounds,    compared  with  the  97  million  pounds  reported  for 
1952.   In  terms  of  volume  of  production,    cellulose  acetate  and 
mixed  ester  plastics  continued  in  1953  to  be  the  most  important 
group  of  cellulose  plastics.    Production  of  these  resins  in  1953  was 
115  million  pounds,    compared  with  85  million  pounds  in  1952.    The 
output  of  cellulose  nitrate  plastics  in  1953  was  7.  6  million  pounds, 
compared  with  6.  0  million  pounds  in  1952. 


TA3LE  30. --Cellulose  plastics:   United  States  production  and  sales,    1953 

[in  thouaands  of  pounds] 


Produo- 
tlon 


Cellulose  plastics, ■"■  total 

Cellulose  acetate  and  mixed  esters,  tot 

Sheets,  under  0.003  gage 

Sheets,  0.003  gage  and  over 

All  other  sheets,  rods,  and  tubes 

Molding  and  extrusion  materials 

Nitrocellulose  sheets,  rods,  and  tubes- 
All  other  cellulose  plasties^ 


128,963 


l/,472 
14,053 
5,869 
77,695 
7, 597 
6,272 


125,410 


112,434 
17,165 
13,143 
5,245 
76,881 
6,549 
6,427 


^  Includes  weight  of  fillers,  plasticizers,  and  extenders. 

Includes  data  for  sheets,  rods,  and  tubes,  and  molding  and  extrusion  materials  derived  from  ethyl 
cellulose  and  other  cellulosic  materials. 


I