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Full text of "Synthetic organic chemicals : United States production and sales"

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UNITED STATES TARIFF COMMISSION 

/ ^ ^ - . 



SYNTHETIC 
ORGANIC CHEMICALS 

United States Production 
and Sales, 1954 



[GPO CI. No. 
TC 1.9; 196] 



Report No. 196 
Second Series 




BOSTON PUBLIC LIBRARY 



3 9999 06317 303 1 




PUBLIC 



RECENT REPORTS OF THE UNITED STATES TARIFF COMMISSION 
ON SYNTHETIC ORGANIC CHEMICALS 



Synthetic Organic Chemicals, United States Production and Sales, 1950 (Rept. 
No. 173, 2d ser., 1951), 45< 

Synthetic Organic Chemicals, United States Production and Sales, 1951 (Rept. 
No. 175, 2d ser., 1952), 45^ 

* Synthetic Organic Chemicals, United States Production and Sales, 1952 (Rept. 
No. 190, 2d ser., 1953) 

Synthetic Organic Chemicals, United States Production and Sales, 1953 (Rept. 
No. 194, 2d ser., 1954), 55^ 



MISCELLANEOUS SERIES 

United States Import Duties (1952), $3.25 (subscription price) 

Thirty-eighth Annual Report of the United States Tariff Commission (1954), 
300 



INOTE.— The report preceded by an asterisk (*) is out of print. The other reports listed may 
be purchased from the Superintendent of Documents, U. S. Government Printing OfRce, Washing- 
ton 25, D. C. See inside back cover for other available reports. All V. S. Tariff Commission 
reports reproduced by the U. S. Government Printing Office may also be consulted in the official 
depositary libraries throughout the United States. 



UNITED STATES TARIFF COMMISSION 

SYNTHETIC 
ORGANIC CHEMICALS 



United States Production 
and Sales, 1954 



UNDER THE GENERAL PROVISIONS 
OF TITLE III, PART II, SECTIONS 332 
AND 333 OF THE TARIFF ACT OF 1930 



UNITED STATES 

GOVERNMENT PRINTING OFFICE 

WASHINGTON : 1955 



Report No. 196 • Second Series 



UNITED STATES TARIFF COMMISSION 

Edgar B. Brossard, Chairman 
Joseph E. Talbot, Vice Chairman 
Walter R. Schreiber 
Glenn W. Sutton 
J. Weldon Jones 
William E. Dowling 



DONN N. Bent, Secretary . ^ «_ >» 

Bosto:. Public Li::ary r Of 3 S (,. R klB A '^^ 

Superintendent or uocuments kA ^^ \^ k % ^6 



Address all communications 

UNITED STATES TARIFF COMMISSION 

Washington 25, D. C. 



[Er 



ACKNOWLEDGMENT 

In the preparation of this report, the Commission had the services of 

James H. Hibben, Henry O. Parsons, Deborah K. Emory, 

Frank Gonet, Pauline T. Eno, and others of its staff 



For sale by the Superintendent of Documents, U. S. Government Printing Office 
Washington 25, D. C. - Price 60 cents 
II 



CONTENTS 



Page 



Introduction v 

Summary vii 

PART I. PRODUCTION AND SALES OF TARS, TAR 
CRUDES, AND CRUDES DERIVED FROM PETRO- 
LEUM AND NATURAL GAS 

Tars 1 

Tar crudes 2 

Crude products from petroleum and natural gas for chemical 

conversion 5 

PART II. PRODUCTION AND SALES OF IN- 
TERMEDIATES AND FINISHED SYNTHETIC 
ORGANIC CHEMICALS, BY GROUPS 

General 9 

Cyclic intermediates 13 

Dyes 17 

Toners and lakes 30 

Medicinals 34 

Flavor and perfume materials i8 

Plastics and resin materials 41 

Rubber-processing chemicals 45 

Elastomers (synthetic rubbers) 47 

Plastic izers 48 

Surface -active agents 48 

Pesticides and other organic agricultural chemicals 52 

Miscellaneous synthetic organic chennicals 53 

PART III. ALPHABETICAL LIST OF INDIVIDUAL PROD- 
UCTS, BY GROUPS, AND NAMES OF MANUFACTURERS 

Tar crudes 59 

Crude products from petroleum and natural gas for chemical 

conversion 60 

Cyclic intermediates 62 

Dyes 79 

Toners and lakes 96 

Medicinals 102 

Flavor and perfume materials 116 

Plastics and resin materials 121 

Rubber-processing chemicals 124 

Elastomers (synthetic rubbers) 126 

Plasticizers 126 

Surface -active agents 129 

Pesticides and other organic agricultural chemicals 135 

Miscellaneous synthetic organic chemicals 138 

Directory of manufacturers 154 



CONTENTS 

APPENDIX 

Page 
United States imports of coal-tar intermediates and 

finished coal-tar products ^"" 

Research workers and research expenditures in the 

synthetic organic chemical industry 

Glossary of synonymous names of cyclic interme- 
diates - 

Production and sales of cellulose plastics ^°^ 



k 



INTRODUCTION 

This is the thirty-eighth annual report of the United States Tar- 
iff Commission on production and sales in the United States of syn- 
thetic organic chemicals and the raw materials from which they 
are made. The report gives statistics, for 1954, on the production 
and sales of crude organic chemicals derived from coal, natural 
gas, and petroleum, of intermediates, and of finished synthetic 
organic chemical products. The finished products are grouped ac- 
cording to their principal use--dyes, toners and lakes, medicinals, 
flavor and perfume materials, plastics and resin materials, rub- 
ber-processing chemicals, elastomers, plasticizers, surface- 
active agents, pesticides and other organic agricultural chemicals, 
and miscellaneous chemicals. With a few exceptions, the report 
does not cover organic chennicals (such as wood-distillation prod- 
ucts, essential oils, and naval stores) that are derived from nat- 
ural (vegetable) sources by simple extraction or distillation. The 
Connmission has compiled the statistics presented in this report 
from information supplied by the 605 primary manufacturers listed 
in part III. 

The raw materials covered in this report are obtained from 
coal, crude petroleum, natural gas, and certain other natural ma- 
terials such as vegetable oils, fats, rosin, and grains. Thermal 
decomposition of coal yields coal-tar crudes and other raw mate- 
rials. Crude organic chemicals are derived also from petroleum 
and natural gas by catalytic cracking, followed by distillation or 
absorption, and from other natural sources by fermentation. Pro- 
duction of these crude organic chemicals is the first step in the 
manufacture of synthetic organic chemicals. From these crudes, 
intermediates are obtained by synthesis or refining; most of the 
intermediates then are converted into finished chemical products, 
such as medicinals, plastics and resin materials, and dyes. In- 
termediates usually are not sold directly to the ultimate consumer, 
but are used by the producing companies themselves --or by other 
industrial concerns --in their manufacturing processes. 

In this report, the statistics on production include the total out- 
put of the reporting companies' plants --the materials produced for 
consumption within the plants, as well as those produced for sale. 
The quantities reported as produced, therefore, generally exceed 
the quantities reported as sold, although changes in inventory may 
account for some differences. No chemical is reported as produced, 
however, unless it has been withdrawn from the reaction system. 
Sales are actual sales of commodities --by original manufacturers 
only--accompanied by passage of title. The value of sales is the 
net sales value, f.o.b. plant or warehouse. 

Data on the chemicals covered in the report usually are given 
in terms of undiluted materials. The principal exceptions are the 
statistics on dyes and a few solvents --which are reported in terms 
of comnnercial concentrations --and those on certain plastics and 
resins--which are reported on a dry basis. The report specifically 



Vi INTRODUCTION 

notes those products for which the statistics are reported in 
terms of commercial concentrations. 

The average unit values of sales for groups of products shown 
in the tables accompanying this report are weighted averages for 
products which vary widely in unit values and in the quantities sold. 

Statistics on tars and tar crudes include data furnished directly 
to the Tariff Commission by distillers of coal tar, water-gas tar, 
and oil-gas tar; data furnished to the Coal Economics Division of 
the United States Bureau of Mines by coke-oven operators; and 
data furnished to the American Gas Association by producers of 
water-gas and oil-gas tar. 

Statistics on United States imports in 1954 of coal-tar inter- 
mediates and finished coal-tar products which entered under para- 
graphs 27 and 28 of the Tariff Act of 1930 are given in appendix A. 
Appendix B includes a table that shows the number of technical re- 
search workers in the synthetic organic chemical industry and the 
cost of research in the industry. Appendix C is a glossary of the 
common (or trivial) names of coal-tar intermediates usually en- 
countered in the trade, together with their equivalent standard (or 
Chemical Abstracts) names. Appendix D summarizes the data on 
production and sales of cellulose plastics that were reported to the 
Commission monthly during 1954. 



SUMMARY 

Combined production of all synthetic organic chemicals (includ- 
ing their raw nnaterials) in 1954 was 61,507 nnillion pounds--1.2 
percent more than in 1953 (see table l). Sales in 1954 totaled 
34,707 million pounds, valued at 4,537 million dollars--a decline 
of 0.9 percent in quantity and 1. 1 percent in value, compared with 
1953. As these data include several successive steps in the manu- 
facturing process, they necessarily include much duplication. 

The output of tars from all sources in 1954 was 7,659 million 
pounds (766 million gallons)-- 15. percent less than in 1953. Pro- 
duction of tar crudes by coke-oven operators and tar distillers in 
1954 totaled 11,957 million pounds, or 4.2 percent more than the 
output in 1953. Sales of tar crudes in 1954 totaled 7,593 million 
pounds, valued at 236 million dollars--an increase of 6.9 percent 
in quantity and 15.6 percent in value, compared with sales in 1953. 
The output in 1954 of crude products from petroleum and natural 
gas for chemical conversion totaled 13,446 million pounds --an 

TABLE 1. --Synthetic organic chemicals and their raw mater iala; United States production and sales, 

1953 and 1954 















Sales 








p.— j.—^-f ». 
























Qoantit; 


Value 








In- 






In- 






In- 


Chenloal 






ereaae, 
or de- 






crease, 
or de- 






orsaae, 
or de- 




1953 


1954 


crease 

(-), 
1954 
over 
1953 1 


1953 


1954 


crease 

(-), 
1954 
over 
1953^ 


1953 


1954 


crease 
{-), 
1954 
over 
1953^ 




Million 


Million 




Million 


Million 




Million 


Million 






pounds 


pounds 


Percent 


pounds 


pounds 


Percent 


do I lors 


dollars 


Percent 


Grand total^ 


60,759 


61,507 


1.2 


35,037 


34,707 


-0.9 


4,587 


4,537 


-1.1 


Tar 


9,007 


7,659 


-15.0 


4,994 


3,831 


-23.3 


50 


40 


-20.0 


Tar erudea' 


11,';76 


11,957 


4.2 


7,105 


7,593 


6.9 


204 


236 


15.6 


Crude products frCTi 




















petroleum and natural 






















11,147 


13,446 


20.6 


7,301 


7,551 


3.4 


303 


284 


-6.4 


Synthetic organic 


chemicals, total 


29,129 


28,445 


-2.3 


15,637 


15,732 


.6 


4,030 


3,977 


-1.3 


Intermediates 


4,699 


4,614 


-1.8 


1,874 


1,793 


-4.3 


341 


320 


-6.3 


Dyes 


166 


143 


-13.8 


152 


137 


-9.4 


168 


160 


-A.3 


Toners and lakes 


44 


40 


-9.2 


37 


35 


-5.0 


56 


54 


-3.9 


Medic Inals 


67 


66 


-1.1 


54 


53 


-1.8 


409 


426 


4.1 


Flavor and perfujae 




















materials 


34 


35 


4.2 


31 


31 


-.9 


47 


47 


1.6 


Plastics and resin 




















materials 


2,777 


2,828 


1.8 


2,372 


2,497 


5.3 


838 


856 


2.3 


Rubber-processing chem- 




















Icoj^Q , , „ , . 


145 


130 


-10.3 


103 


101 


-1.7 


60 


62 


3.8 


Elastomers (synthetic 


rubbers ) 


1,958 


1,435 


-26.7 


1,909 


1,497 


-21.6 


529 


436 


-17.6 


Plasticizers 


293 


301 


2.7 


235 


247 


5.3 


83 


82 


-1.6 


Surface-active agents — 


921 


1,026 


11.3 


732 


913 


24.7 


145 


196 


35.5 


Pesticides and other 




















organic agricultural 




















chemicals 


356 


419 


17.8 


334 


336 


.6 


118 


125 


5.0 


Miscellaneous chemicals 


17,669 


17,408 


-1.5 


7,804 


8,092 


3.7 


1,236 


1,213 


-1.9 



^ Percentages calculated on figures rounded to thousands. 
This total involves much duplication. 
Excludes products derived from petroleum, but Includes products derived from tar and from coke-oven gas. 



vu 



Viii SUMMARY 

increase of 20.6 percent from the 11,147 nnillion pounds reported 
for 1953. Sales of these products in 1954 totaled 7,551 million 
pounds, valued at 284 million dollars, compared with sales of 
7,301 million pounds, valued at 303 million dollars, in 1953. 

Production of all synthetic organic chemicals in 1954 (exclud- 
ing the raw materials mentioned above) totaled 28,445 million 
pounds --a total that also involves much duplication. This produc- 
tion represents a decline of 2. 3 percent from the output of 29,129 
million pounds in 1953. Of the 11 individual groups of finished syn- 
thetic organic chemicals, 6 declined in value of output in 1954 com- 
pared with 1953, and 5 increased. The output of intermediates in 
1954 was 4,614 million pounds, compared with 4,699 million pounds 
in 1953--a decrease of 1.8 percent. Those groups of finished syn- 
thetic organic chemicals which increased in volume of output in 
1954, compared with 1953, are pesticides and other organic agri- 
cultural chennicals, 419 million pounds, compared with 356 million 
pounds (or by 17.8 percent);-"- surface -active agents, 1,026 million 
pounds, compared with 921 nnillion pounds (or by 11.3 percent); 
flavor and perfume materials, 35 million pounds, compared with 
34 million pounds (or by 4.2 percent); plasticizers, 301 million 
pounds, compared with 293 million pounds (or by 2.7 percent); 
and plastics and resin materials, 2,828 million pounds, compared 
with 2,777 million pounds (or by 1.8 percent). 

Those groups of finished products which declined in output in 
1954 compared with 1953 are elastomers, 1,435 million pounds, 
compared with 1,958 million pounds (or by 26.7 percent); dyes, 
143 million pounds, compared with 166 million pounds (or by 13.8 
percent); rubber-processing chemicals, 130 million pounds, com- 
pared with 145 million pounds (or by 10. 3 percent); toners and 
lakes, 40 million pounds, compared with 44 million pounds (or by 
9.2 percent); miscellaneous chemicals, 17,408 million pounds, 
compared with 17,669 million pounds (or by 1. 5 percent); and me- 
dicinals, 66 million pounds, compared with 67 million pounds (or 
by 1 . 1 percent). 

' Based on figures rounded to thousands. 



PART I. PRODUCTION AND SALES OF TARS, TAR CRUDES, 
AND CRUDES DERIVED FROM PETROLEUM AND 
NATURAL GAS 

Tars 

Coal tar is produced chiefly by the steel industry as a byprod- 
uct of the manufacture of coke. Water-gas tar and oil-gas tar are 
produced by the fuel-gas industry. Production of coal tar, there- 
fore, depends on the demand for steel; production of water-gas 
tar and oil-gas tar reflects the consumption of manufactured gas 
for industrial and household use. Water-gas and oil-gas tars have 
properties intermediate between those of petroleum asphalts and 
coal tars. Petroleum asphalts are not usually considered to be raw 
materials for chemicals. 



-Tar: United States production and consumption , 1953 and 1954 
[in tbouBands of gallons] 



PRODDCTION 



Mater-gas and oil-gas tar^- 



Coal tar, total - 



Coal tar from coke-oven byproduct plants, total 

Plants not owned by city gas companies 

Plants ovmed by city gas companies (public utilities)- 

Coal tar from coal-gas retort plants' 



COHSIMPTION 



Tar consumed by distillation, total- 



Water-gas and oil-gas tar distilled by producers and tar dlstillers*- 

Coal tar distilled or topped by coke-oven operators' 

Coal tar distilled by tar distillers' 



Tar ooDsumed chiefly as fuel, total- 



Water-gas and oil-gas tar consumed as fuel" 

Coal tar sold or consumed as fuel by coke-oven operators' — 
As fuel under boilers 



In open-hearth or affiliated plants 

Sold as fuel by coke-oven operators to affiliates- 
Sold as fuel by coke-oven operators to others 



Tar consumed otherwise than by distillation or as fuel, total- 
Coal tar consumed at coke-oven plants for roads and upkeep' 



Coal tar, water-gas tar, and oil -gas tar processed at tar refineries, 
crude tar consumed for upkeep at such refineries, and tar consuzned in 
making gas and in special -purpose tar blends' 



900,806 



67,290 
633,516 



828,729 

802,044 

26,685 

4,787 



877,751 



641,720 



41,957 
254,448 
345,315 

153,991 



9,667 
144,324 

3,152 
124,181 
12,536 

4,455 

82,040 



2,373 



79,667 



765,932 



45,040 
720,892 



715,840 

703,333 

12,507 

5,052 



764,833 



556,181 



43,202 
218,169 
294,810 



3,060 
146,783 

146,783 



58,809 



2,416 
56,393 



Heported to the American Gas Association. 
' Reported to the U. S. Bureau of Mines. 
' Includes low-temperature carbonization tar. 
* Heported to the 0. S. Tariff Commission. 

' Represents tar purchased from companies operating coke ovens and gas-retort plants and distilled by 
companies operating tar-<listillatlon plants. 

' Reported to the American Qss Association and to the V. S. Tariff Commission. 



2 UNITED STATES TARIFF COMMISSION 

The quantity of tar produced in the United States from all 
sources in 1954 was 766 million gallons, or 15.0 percent less than 
the output of 901 million gallons in 19 53. Of the total quantity pro- 
duced in 1954, about 7Z1 million gallons was coal tar and 45 million 
gallons was water-gas and oil-gas tars (see table 2). In 1953 the 
output of coal tar was 834 million gallons and that of water-gas and 
oil-gas tars, 67 million gallons. The decline in the output of water- 
gas and oil-gas tars in 1954 was the result of further displacement 
of manufactured gas by natural gas. 

The total consumption of tar in 1954 amounted to 765 million 
gallons, of which 556 million gallons was consumed by distillation, 
150 million gallons as fuel, and 59 million gallons in miscellaneous 
uses such as refinery upkeep and in special road-tar blends. 

The quantity of tar distilled in 1954 was 86 million gallons less 
than in 1953; the quantity consumed chiefly as fuel was 4 million 
gallons less than in 1953. In 1954 the quantity of coal tar distilled 
or topped by coke-oven operators was Z18 million gallons, com- 
pared with 254 million gallons in 1953; the quantity of coal tar dis- 
tilled by tar distillers in 1954 was 295 million gallons, compared 
with 345 nnillion gallons in 1953; and the quantity of water-gas and 
oil-gas tar distilled by producers and tar distillers was 43 million 
gallons, compared with 42 nnillion gallons in 1953. 

Tar Crudes 

Tar crudes, the most important of which are benzene, toluene, 
xylene, and naphthalene, are derived from coke-oven gas and by 
distilling coal tar, water-gas tar, and oil-gas tar. Some products 
identical with those derived from coal tar are also derived from 
petroleum and natural gas; these latter materials are, for the most 
part, included in the statistics on tar crudes that are given in 
tables 3 and 4A. ^ 

The total production of specification and industrial grades of 
benzene in 1954 amounted to 257 million gallons, compared with 
273 million gallons in 1953--a decline of 5.8 percent. These totals 
include benzene produced from tar, from domestic and imported 
crude light oil, from petroleum, and from imported motor -grade 
benzene. Sales of benzene in 1954 amounted to 202 million gallons, 
valued at 83 million dollars --about 13 percent less in quantity than 
the sales of 233 million gallons, valued at 96 million dollars, in 
1953. Coke-oven operators accounted for the largest part of the 
benzene production in 1954 (139 million gallons); production of 
motor-grade benzene by these operators was 3. 3 million gallons. 
The output of toluene in 1954 from all sources amounted to 159 
nnillion gallons, a slight increase over the output in 1953. Sales 
of toluene in 1954 totaled 126 million gallons, valued at 37 million 
dollars. Petroleum sources accounted for 123 million gallons of 
the total output of toluene in 1954. 

Production of xylene in 1954 amounted to 110 million gallons, 
compared with 113 million gallons in 1953. Sales of xylene in 1954 
totaled 66 million gallons, valued at 18 million dollars, slightly 
larger than sales in 1953. In 1954 nnore than 90 percent of the xy- 
lene produced was fronn petroleum sources. Production of crude 
naphthalene in 1954 was 316 nnillion pounds, or 15.6 percent nnore 



^ See also table 4B, part III, which lists these products and identifies the manufacturers. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



TABLE 3. "Tar and tar crudest Su 



mary of production and sales of specified products, average 1949-53, 
aimual 1953 and 1954 



Chemical^ 



quantity 



Average 
1949-53 



decrease (-), 

195-; 
over 19<49-53 



decrease (-), 

195i 

over 1953 



Tar: Produotion'- 

Benzene : 

Production 

Sales 



Value of sales- 
Motor benzene:' 
Production- 
Sales — 



Value of sales- 
Toluene : 

Production 

Sales 



Value of sales- 
Xylene : 

Production 

Sales 



Value of sales- 
Naphthalene : 

Production 

Sales 



Value of sales- 
Creosote oil: 

Production 

Sales 



Value of sales- 



1,000 gal- 

1,000 gal- 
1,000 gal- 
1,000 dol- 



,000 gal- 

,000 gal- 

,000 dol- 

,000 gal- 

,000 gal- 

,000 dol- 

,000 gal- 

,000 gal- 

,000 dol- 



,000 gal- 
,000 gal- 
,000 dol- 



905,935 

221,910 
196,875 
66,53A 

8,765 
7,917 
1,328 

105,716 
88,616 
2-1,276 

78,062 
55,645 
13,663 

303,700 
201,611 
,10,874 

141,873 

133,093 

23,975 



900,671 

272,744 

232,701 

95,765 

1,160 

1,150 

184 

156,248 
130,222 
39,244 

113,474 
65,588 
16,968 

315,799 

200,086 

11,100 

145,300 
125,285 
25,020 



Percent 

-15.4 

15.7 
2.6 
24.8 

-62.0 
-58.9 
-56.9 



41.2 
19.4 
33.6 

-2.8 
11.2 
-6.0 



765,932 

256,810 
201,915 
83,002 

3,327 

3,255 

572 

159,185 
126,195 
37,098 

110,192 
66,467 
18,259 

295,149 

224,225 

10,220 

117,646 
113,517 
22,918 



186.8 
183.0 
210.9 



-3.1 
-5.5 



-6.5 
12.1 
-7.9 

-19.0 
-9.4 
-8.4 



^ for details concerning statistics shown In this table, see table 4A. 

^ Includes data for oil-gas and water-gas tar reported to the American Gas Association and for coal tar 
reported to the Coal Economics Division, U. S. Bureau of Mines. 

' Data for 1951 and 1952 do not include a small amount of motor benzene produced by other than coke-oven 
operators . 



than the output of 276 million pounds in 1953. Sales in 1954 amounted 
to 224 million pounds, valued at 10 million dollars, compared with 
sales of 200 million pounds, valued at 1 1 million dollars, in 1953. 

The output in 1954 of creosote oil (a mixture of xylenols, 
cresols, and their homologues and derivatives, and of anthracene 
oil, naphthalene, and some phenols), which is used chiefly in wood 
preserving, -amounted to 118 million gallons--a decline of 19.0 
percent from the 145 million gallons produced in 1953. The output 
of road tar in 1954 was 81 million gallons, compared with 110 mil- 
lion gallons in 1953. Production of pitch of tar (all grades) in 1954 
was 1. 6 million tons, compared with 1. 9 million tons in 1953. 

Some of the products included in the statistics given in table 
4A are derived from other products, data for which are also in- 
cluded. The statistics, therefore, involve considerable duplica- 
tion, and for this reason group totals and grand totals are not given. 
After as much duplication as possible has been eliminated, it is 
estimated that in 1954 the net value of production of these products 
and of tar burned as fuel was 345 million dollars, compared with 
344 million dollars in 1953 and 282 million dollars in 1952. 



UNITED STATES TARIFF COMMISSION 



TABLE 4A. --Organic chemicals: United States production and sales of tar crudes, 1954 

[Listed b.-lou are all tar crudes for which any reported data on production or sales may be published. Table 
^B in part III lists separately all products for which data on production or sales were reported ana iden- 
tifies the manufacturers reporting to the U. S. Tariff Commission] 



Crude light oil 

Intermediate light oil: Coke-oven operatcrs- 
Light-oil distillates: 

Benzene, specification and industrial 

grades, total 

Tar distillPrs^ 



Coke-oven operators - 
Petrolexim operators- 



Benzene, motor grade, coke-oven ope 

Toluene, all grades, total 

Tar distillers 

Coke-oven operators 

Petroleum operators 

Xylene, all grades, total 

Tar distillers 

Coke-oven operators 

Petroleum operators 

Solvent naphtha, total 

Tar distillers 

Coke-oven operators 

Other light-oil distillates, total- 
Tar distillers • — 

Coke-oven operators- 



Pyridine crude bases (dry basis): Coke-oven 
operators 



Naphthalene, crude (solidifying at less than 

79° C.),^ total 

Tar distillers 



quantity 



Coke-oven operators- 
Crude tar-acid oils: 

Coke-oven operators 

Cresylic acid, crude (less than 75^ distilling 
over 215° C): Tar distillers 

Creosote oil (Dead oil),* total 

Tar distillers: 

Sold or constimed as such 



Sold or consumed in coal-tar solution 

Coke-oven operators: 

Distillate as such 



In coal-tar solution- 



Coal tar sold or consumed in ooal-tar solution: 
Tar distillers 



All other distillate products' 

Tar (crude and refined) for other uses' 

Pitch of tar: 

Soft and medium (Water softening point less 
than 110° F., and 110° F. to 160° F. ASTM 

Hard (Water softening point above 160° F.) 

Pitch of tar coke and pitch emulsion 



1,000 gal 

1,000 gal 



1,000 gal — 
1,000 gal — 
1,000 gal — 
1,000 gal — 
1,000 gal — 
1,000 gal— 
1,000 gal~ 
1,000 gal— 
1,000 gal— 
1,000 gal— 
1,000 gal— 
1,000 gal— 
1,000 gal— 
1,000 gal— 
1,000 gal— 
1,000 gal— 
1,000 gal— 
1,000 gal— 
1,000 gal— 

1,000 gal— 



1,000 lb— 
1,000 lb~ 
1,000 lb— 

1,000 gal- 
1,000 gal- 

1,000 lb— 

1,000 gal- 

1,000 gal- 
1,000 gal- 

1,000 gal- 
1,000 gal- 



1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 



Produc- 
tion 



1,000 tons 

1,000 tons 

1,000 tons 



2^,539 
2,907 



256,810 

25,460 

139,438 

91,912 

3,327 

159,185 

2,917 

33,383 

122,885 

110,192 

505 

9,956 

99,731 

22,731 

18,148 

4,583 

7,684 

3,611 

4,073 

232 



295, 149 



195,090 
100,059 



3,440 
23,087 



3,838 
117,646 



74,072 

17,104 



19,588 
6,882 



7,253 
22,820 
80,540 
33,002 



1,095 
543 



15,288 
2,984 



201,915 

18,344 

131,857 

51,714 

3,255 

126,195 

2,075 

30,548 

93,572 

66, 467 

635 

9,527 

56,305 

22,684 

18,124 

4,560 

6,048 

3,343 

2,705 

281 



224,225 



1,000 
dollars 
3,575 
497 



83,002 

7,413 

50,958 

24,631 

572 

37,098 

684 

9,664 

26,750 

18,259 

242 

3,121 

14,896 

5,029 

3,832 

1,197 

1,273 

917 

356 



393 



126,923 
97,302 



692 
23, 522 



113,517 



71,107 
16,762 



18,959 

6,689 



7,060 
16, 524 
77,474 
25,194 



554 
364 



5,851 
4,369 



288 
4,936 



22,918 



14, 709 

3,317 



3,610 

1,282 



1,015 
2,673 
12,036 
4,746 



20,007 
11,949 

781 



Unit 
value^ 



$0.23 



.38 
.33 



.05 

~:u3 



36.11 
32.83 
33.96 



^ Unit value per gallon, pound, or ton, according to the unit specified, calculated on rounded figures. 

^ Includes data for benzene distilled from imported crude light oil, 

' Statistics represent the combined production and sales of the three commercial grades of crude naphthalene 
to avoid disclosure of individual company operations. As there is some conversion between grades of crude 
naphthalene, the published totals necessarily include some duplication. 

* The statistics include data only for material sold for or consumed in wood preserving. The figures do not 
represent the total distillate which could be used as creosote oil, from which other products are extracted. 

' Includes data for neutral and high-boiling oils, shingle-stain oil, crude and semirefined pyridine, crude 
light oil and other products produced by tar distillers, and for crude sodium phenolate produced by coke-oven 
operators . 

' Includes data for tar used or sold for paints, pipe covering, saturating, etc. 

Uote Statistics for materials produced in coke and gas-retort ovens are compiled by the Coal Economics 

Division of the U. S. Bureau of Mines, and those for materials produced in tar and petroleum refineries are 
compiled by the U. S. Tariff Commission. 



SYNTHETIC ORGANIC CHEMICALS, \95U 5 

Crude Products From Petroleum and Natural Gas 
for Chemical Conversion 

The crude products that are derived from petroleum and natu- 
ral gas are related to the intermediate and finished products nnade 
from such crudes in much the same way thatcrude products derived 
from the distillation of coal tar are related to their intermediates 
and finished products. Many of the crude products derived from 
petroleum are identical with those derived from coal tar (e. g. , 
benzene, toluene, and xylene). Considerable duplication exists in 
the statistics on the production and sales of petroleunn crudes, be- 
cause some of these crude chemicals are converted to other crude 
products derived from petroleum, and because data on production 
and sales may be reported at successive stages in the conversion 
processes (see table 5A^), Notwithstanding these duplications, 
however, the statistics are sufficiently accurate to indicate trends 
in the industry, and to serve as a basis for general comparison. 
Many of the crude products for which data are included in the sta- 
tistics may be used as fuel or as basic materials from which to 
derive other chemicals, depending upon prevailing economic con- 
ditions. In this report, however, every effort has been made to 
exclude data on nnaterials that are used as fuels. 

Production in 1954 of crude products derived from petroleum 
and natural gas as a group amounted to 13,446 million pounds--an 
increase of 20.6 percent from the 11,147 million pounds reported 
for 1953. The larger production in 1954 is accounted for in part 
by the inclusion of data on n-butane which were received from 
companies reporting for the first time. Sales of crude chemicals 
from petroleum in 1954 were 7, 551 million pounds, valued at 284 
million dollars, compared with 7,301 million pounds, valued at 
303 million dollars, in 1953. 

Production in 19 54 of all aromatic and naphthenic products 
amounted to 2,874 million pounds, compared with 2,506 million 
pounds in 1953. Sales in 1954 were 2,026 million pounds, valued 
at 79 million dollars, an increase of 231 million pounds in quan- 
tity and 6 million dollars in value, compared with 1953. In 1954 
benzene, toluene, and cresylic acid were produced from petrole- 
um sources in substantially larger quantities than in 1953; pro- 
duction of naphthenic acid increased slightly. Production of spec- 
ification and industrial-grade benzene from petroleum was 674 
million pounds in 1954, compared with 462 million pounds in 1953 
(an increase of 45. 8 percent); the output of toluene was 890 million 
pounds in 1954, compared with 836 million pounds in 1953 (an in- 
crease of 6.4 percent). The output of naphthenic acids amounted 
to 24 million pounds in 1954, compared with 23 million pounds in 
1953; production of cresylic acid was 22 million pounds in 1954, 
compared with 16 million pounds in 1953; and production of xylene 
was 726 million pounds in 1954, compared with 749 million pounds 
in 1953 (a decrease of 3. 1 percent). 

The output of all aliphatic hydrocarbons and derivatives from 
petroleum and natural gas in 1954 was 10,572 million pounds, 
compared with 8,641 million pounds in 1953. Sales of these prod- 
ucts in 1954 were 5,524 million pounds, valued at 204 million dol- 
lars, compared with 5,506 million pounds, valued at 230 million 
dollars, in 1953. Production of methane, shown separately for the 
first time, amounted to 44 million pounds. Production of ethylene 
in 1954 was 2,345 million pounds, an increase of 9.8 percent over 

^ See also table 5B, part III, which lists these products alphabetically and identifies 
the manufacturers. 



UNITED STATES TARIFF COMMISSION 



TABLE 5A. --Synthetic organic chemicals: United States production and sales of crude products from 
petroleum and natural gas for chemical conversion , 1954 

[Listed below are the crude products from petroleum and natural gas for chemical conversion for which any 
reported data on production or sales may be published. (Leaders are used where the reported data are 
accepted in confidence and may not be published or where no data were reported.) Table 5B in part III lists 
separately all products from petroleum and natural gas for chemical conversion for which data on production 
or sales were reported and identifies the manufacturer of each] 



Sales 



Unit 
value^ 



Grand total 

AROMATICS AND NAPHTHENES^ 
Total 

Alkyl aromatios, distillates, and solvents 



Benzene (except motor grade), total- 
Benzene, 1° 

Benzene, 2° ' 



1,000 

pounds 

13,'U5,62<; 



1,000 
pounds 

7,550,762 



1,000 
dollars 

283,503 



2,874,C 



520,286 
673,715 



Cresylic acid, crude- 



Naphthenic acids, total- 
Acid number 220-22<i 

Acid number 225-249 

All other 



232,867 
440, 8i8 



21,576 
23,666 



513,306 
379,049 



10,559 
24,631 



206,098 

172,951 



9,677 
17,438 



13,277 
11,354 



1,194 
12,578 
9,894 



901 
13,644 
2,893 



1,424 

182 



Toluene, all grades, total- 
Nitration grade, 1° 

Pure commercial grade, 2° 
All other 



Xylenes, mixed- 
All other* 



366,822 
405,845 
117,020 

726,041 
19,037 



ALIPHATIC HYDROCARBONS 



Total 

Ci hydrocarbon, methane- 



292,612 

309,821 

75,028 

409,901 
19, 104 



5,524,326 



11,940 
12,350 
2,460 

14,896 
419 



C2 hydrocarbons, total- 
Ethane 

Ethylene^ 



44,036 
2,700,464 



355,820 
2,344,644 



43,125 
440, 983 



579 
15,875 



121,186 
319,797 



C3 hydrocarbons, total 

Propane 

Propylene and propane-propylene mixture 



762 
15,113 



25,350 



C4 hydrocarbons, total — — 

1,3-Butadiene, grade for rubber (elastomers), total — 

Produced for Government account 

Produced for private account 



1,6"5,124 
1,203,501 



4,067,2''0 



1-Butene, 2-butene, and mixtures 

Isobutane 

All other^ 



C5 hydrocarbons 

All other aliphatic hydrocarbons and derivatives, total 

Dodecene (Tetrapropylene ) 

Nonene ( Tr ipropylene ) — 

Hydrocarbon derivatives, total — — 

All other hydrocarbon derivatives^" 



38,731 
690,744 
117,987 
941,088 
1,214,756 
250,055 
852,640 

179,395 

701, 826 



1,651,235 
613,639 



2,263,238 



789, 174 

291,062 
830,023 

208,592 
144,387 

161,673 

350,428 



16,659 
8,n9: 

145,34' 



21,997 

316,337 

98,557 

5,331 

1,930 

3,401 

259,604 



l''4,546 
12,197 
4,991 

4,991 
158,694 



6110,292 

2,527 
25,177 
2,762 
4,539 

2,897 

14,164 



6,635 

444 

1,035 

1,035 
6,049 



.021 
.065 



.064 
.066 



.036 
.097 



.091 
.104 
.063 



.039 
.040 
.033 

.036 
.022 



.013 
.036 



.010 
.014 



.009 
.030 
.013 
.032 

.013 

.040 



.038 
.036 
.207 

.207 
.038 



^ Calculated on rounded figures. 

^ The chemical raw materials designated as aromatios are in some cases identical with those obtained from 
the distillation of coal tar. However, the statistics given in the above table relate only to such materials 
as are derived from petroleum and natural gas^. 

^ Includes a small amount of 90? benzene. 

* Includes data for motor-grade benzene, cyclopentane, petroleum phenols, sodium carbolate and phenate, and 
hydrocarbon polymers. 

' Includes a small amount of ethylene from coke-oven gas. 

' Partly estimated. 

' The statistics represent principally the butene content of crude refinery gases from which butadiene is 
manufactured. 

' Includes data for isobutene, 1-butene, 2-butene, butane-butylene, and butadiene-butene mixtures and con- 
centrates. 

' Includes data for pentanes, pentenes, isoprene, and mixtures. 
^° Includes data for di-tert-butyldlsulfide, miscellaneous mercaptans, and mixed alkanesulfonic and 
aliphatic acids. 

^^ Includes data for acetylene, hexanes, heptanes and heptenes, octanes and octenes, polybutene, eicosane, 
and hydrocarbon mixtures. 



SYNTHETIC ORGANIC CHEMICALS, 1954 7 

the 2,136 million pounds produced in 1953. The output of propane, 
propylene, and propane -propylene mixture in 1954 was 2,879 mil- 
lion pounds, compared with 2,589 million pounds in 1953. Produc- 
tion of 1, 3-butadiene in 1954 was 809 million pounds, compared 
with 1,152 million pounds in 1953. The decrease in the production 
of 1, 3-butadiene, one of the principal ingredients of the GR-S type 
synthetic rubber, is accounted for chiefly by the 34-percent de- 
crease in production for Government account. 



PART II. PRODUCTION AND SALES OF INTERMEDIATES AND 
FINISHED SYNTHETIC ORGANIC CHEMICALS, BY GROUPS 

General 

On the basis of their principal uses, the synthetic organic 
chemicals covered in this report are classified as intermediates 
and as finished products. Finished products, in turn, are grouped 
as follows: Dyes, toners and lakes, medicinals, flavor and per- 
fume materials, plastics and resin materials, rubber-processing 
chemicals, elastomers (synthetic rubbers), plasticizers, surface- 
active agents, pesticides and other organic agricultural chemicals, 
and miscellaneous synthetic organic chemicals. Most of these 
groups are further subdivided, according to chemical classes, 
into cyclic and acyclic compounds. 

As many of the intermediates are used in the manufacture of 
finished products, aggregate figures which cover both intermedi- 
ates and finished products necessarily include nnuch duplication. 

Total production of all synthetic organic chemicals (interme- 
diates and finished products combined) was 28,445 million pounds 
in 1954, or 684 million pounds less than the output in 1953 (see 
table 6). Sales in 1954 totaled 15,732 nnillion pounds, valued at 
3,977 million dollars, connpared with sales of 15,637 million pounds, 
valued at 4,030 million dollars, in 1953. Production of all cyclic 
products (intermediates and finished products) in 1954 totaled 9,174 
million pounds, or 4.8 percent less than the 9,637 million pounds 
produced in 1953. Sales of all cyclic products in 1954 were 5,764 
million pounds, compared with 6,072 million pounds in 1953. Pro- 
duction of all finished cyclic products in 1954 was 4,560 million 
pounds, or 7. 7 percent less than in 1953. Sales of these products 
in 1954 totaled 3,972 million pounds, compared with sales of 4,198 
million pounds in l953--a decline of 5.4 percent. Production of 
cyclic intermediates in 1954 was 4,6l4 million pounds, or 1.8 per- 
cent less than the output in 1953. In 1954 production of finished 
acyclic products and acyclic intermediates (included with miscel- 
laneous acyclic chemicals) totaled 19,271 million pounds, or 1. 1 
percent less than the 19,491 million pounds reported for 1953. 

Of the individual groups of finished synthetic organic chemicals 
having both cyclic and acyclic components, three increased in out- 
put in 1954, compared with 1953, in both cyclic and acyclic cate- 
gories. These three groups (and their percentage increases) are 
as follows: Pesticides and other organic agricultural chemicals 
(cyclic, 20.4 percent, and acyclic, 4.8 percent); surface -active 
agents (cyclic, 7.8 percent, and acyclic, 17.7 percent); and plas- 
ticizers (cyclic, 1.7 percent, and acyclic, 5.7 percent). Two 
groups declined in output in both categories in 1954 compared with 
1953. These groups (and their percentage decreases) are elasto- 
mers (cyclic, 31.2 percent, and acyclic, 15.0 percent) and rubber- 
processing chemicals (cyclic, 9.6 percent, and acyclic, 13.7 per- 
cent). Four groups declined in output in one category and increased 

9 



10 



UNITED STATES TARIFF COMMISSION 



TABLE 6. --Synthetic organic chemicals: Summary of United States production and sales of in 
and finished products, average 1949-53, annual 1953 and 1954 

[Production and sales In thousands of pounds; sales value in thousands of dollars] 



Production, grand total 

Sales, grand total 

Sales value, grand total 

I. ORGAMIC CHEMICALS, CYCLIC 

Production, total 

Sales, total 

Sales value, total 

A. INTERMEDIATES 

Production 

Sales 

Sales value 

n. FINISHEn PRODUCTS 

Production , total 

Sales , total 

Sales value, total 

1. Dyts 

Production , total 

Sales , total 

Sales value, total 

a. Colour Index Group 

Production 

Sales 

Sales value 

b. Prototype Group 

Production 

Sales 

Sales value 

c . Ungrouped 

Production 

Sales 

Sales value 

2. Toners and Lakes 

Production 

Sales 

Sales value 

3. Uedicinals 

Production 

Sales 

Sales value 

4. Flavor and Perfume Materia 

Production 

Sales 

Sales value 

5. Plastics and Resin Material 

Produc tion 

Sales 

Sales value 

6. Rubber-Processing Chemical 

Production 

Sales 

Sales value 



Average 
1949-53 



2-4,526,923 
13,164,689 
3,319,895 



7,886,310 
5,006,176 
1,731,522 



3,859,140 

1,5U,595 

271,400 



,027,170 
,491,581 
,460,122 



166,640 
156,979 
169,641 



118,198 
112,094 
89,006 



27,607 
25,522 
45,050 



20,835 
19,363 
35,585 



42,907 
37,803 
49,695 



49,376 
40,243 
368,365 



17,403 
14,823 
20,975 



,312,203 
,071,629 
285,437 



29,128,545 

15,636,993 

030,357 



9,637,093 
6,072,460 
2,011,311 



4,698,585 

1,874,175 

341,421 



4,938,508 
4,198,285 
1,669,890 



165,806 
151,675 
167,526 



117,206 
107,986 
89,546 



32,612 
29,516 
49,586 



15,988 
14,173 
28,394 



44,056 
36,661 
56,031 



51,003 
41,080 
380,914 



18,458 
16,512 
21,419 



1,605,447 

1,317,069 

362,958 



102,506 121,532 
75,618 85,495 
38,163 47,592 



28,444,747 
15,732,303 
3,977,444 



9,173,954 
5,764,463 
1,970,452 



4,613,869 

1,792,831 

319,875 



4,560,085 
3,971,632 
1,650,577 



142,982 
137,463 
160,302 



100,860 
94,839 
83,701 



29,232 
29,678 
50,035 



12,890 
12,946 
26,566 



39,981 
34,844 
53,869 



49,262 
39,900 
400,139 



21,870 
18,241 
26,823 



1,588,180 

1,330,509 

360,406 



109,868 
85,134 
50,555 



Increase, or 
decrease (-) 



1954 
over 
1949-53 



15.1 
13.8 



19.6 
18.4 
17.9 



13.7 
13.0 



-14.2 
-12.4 



-15.4 
-6.0 



16.3 
11.1 



-6.9 
-7.8 
8.4 



-.2 
-.9 



25.7 
23.1 
27.9 



SYNTHETIC ORGANIC CHEMICALS, 1954 



11 



TABLE 6. --Synthetic organic chemicals: Summary of United States production and sales of intermediates 
and finished products, ^average 1949-53. annual 1953 and 1954- -Continued 

[Production and sales In thousands of pounds; sales value In thousands of dollars] 



Average 
19-49-53 



Increase, or 
decrease (-) 



1954 
over 
1949-53 



1954 
over 
1953 



I. ORGANIC CHEMICALS, CYCLIC— Continued 

B. FINISHED PRODUCTS — Continued 

7. fUsto.irrs (Synthetic Rubbers) 

Production 

Sales 

Sales value 

Production 

Sales 

Sales value 

9. Surface-Active Agents 

Production 

Sales value 

10. Pesticides and Other Organic 
Agricultural Chemicals^ 

Production 

Sales 

Sales value ~ 

11. Miscellaneous'' 

Production 

Sales 

Sales value 

II. ORGANIC CHBMICALS, ACYCLIC 
(INTERMEDIATBS AND FINISHED 
PRODUCTS) 

Production, total 

Sales , total 

Sales value, total 

1. Medicinals 

Production 

Sales 

Sales value 

2. Flavor and Perfume 

Materials 

Production 

Sales 

Sales value 

3. Plastics and Resin 

Uaterials 

Production 

Sales 

Sales value 

4. Rubber-Processing 

Chemicals 

Production 

Sales 

Sales value 

See footnotes at end of table. 



1,166,570 

1,175,027 

265,929 



184,993 
140,975 
49,728 



427,574 

337,821 

59,418 



293,886 

244,654 

90,949 



263,112 
196,009 
61,822 



16,640,613 
8,158,513 
1,588,373 



10,178 
8,424 
25,087 



11,292 
10,850 
17,747 



926,373 
843,979 
360,879 



18,491 
15,347 
11,112 



1,414,944 

1,387,198 

319,056 



223,810 

180,137 

59,955 



594,089 

438,491 

73,301 



297,054 

281,652 

98,572 



402,309 
262,315 
82,566 



19,491,452 
9,564,533 
2,019,046 



15,582 
13,147 
28,154 



15,413 
14,568 
25,109 



1,171,180 

1,054,911 

474,578 



23,252 
17,726 
12,463 



973,249 

1,028,525 

242,419 



227,618 

185,781 

56,993 



640,222 
577,022 
120,338 



357,533 
279,103 
102,145 



409,320 
255,110 
76,588 



19,270,793 
9,967,840 

2,006,992 



16,622 
13,332 
25,696 



13,437 
12,553 
20,457 



1,239,623 

1,166,088 

496,087 



20,057 
16,332 
11,806 



-16.6 
-12.5 



23.0 
31.8 
14.6 



49.7 
70.8 
102.5 



21.7 
14.1 



55.6 
30.2 



15.8 
22.2 
26.4 



63.3 
58.3 



33.8 
38.2 
37.5 



6.4 
6.2 



-31.2 
-25.9 
-24.0 



1.7 
3.1 
-4.9 



7.8 
31.6 
64.2 



1.7 
-2.7 
-7.2 



-1.1 
4.2 



6.7 

1.4 

-8.7 



-12.8 
-13.8 
-18.5 



5.8 
10.5 
4.5 



-13.7 
-7.9 
-5.3 



12 



UNITED STATES TARIFF COMMISSION 



TABLE 6. --Synthetic organic chemicaia: Sumary of United States production and sales of intermediates 
and finished products, average 1949-53, annual 1953 and i954- -Continued 

I Production and sales In thousands of pounds; sales value in thousands of dollars] 



Average 
19*9-53 



Increase , or 
decrease (-) 



195* 
over 
19*9-53 



195* 
over 
1953 



II. ORGANIC CHHUCALS, ACYCLIC (INTERMEDIATES 
AND FINISHED PRODUCTS)— Continued 



(Synthetic Rabbtrt) 



Production- 
Sales 



Production- 
Sales 



Sales value- 



7. Surface-Active Aftntt 



Production- 
Sales 



Sales value- 



and Othe 
al Chemic 



Production 

Sales 

Sales value 



Production- 
Sales 



Sales value- 



*27,07* 
*15,389 
157,952 



65,128 
50,850 
20, %7 



26*,806 

227,877 

60,673 



*2,68* 
37,102 
1*,665 



1*, 87*, 586 

6,5*8,695 

919,291 



5*3,*06 
521,595 
210,308 



69,088 
5*, 929 

23,380 



327,505 
293,613 
71,671 



58,899 
52,*9* 
19,9*5 



17,267,127 
7,5*1,550 
l,153,*3e 



*61,713 
*68,002 
193,539 



73,056 
61,66* 
25,00* 



385,61* 
336,252 

76,095 



61,7*1 
56,896 
22,356 



16,998,930 
7,836,721 
1,135,952 



8.1 
12.7 



*5.6 
*7.6 
25.* 



**.6 
53.* 
52.* 



1*.3 
19.7 
23.6 



5.7 

37.2 

6.9 



17.7 
1*.5 
6.2 



*.8 
8.* 
12.1 



-1.6 
3.9 

-1.5 



^ Data on pesticides and other organic agricultural chemicals were shown in 1951 for the first time in a 
separate section of this report; the data for 19*9-50 have been adjusted to mke them coii?>aratJle with those 
for 1951-5*. 

^ Data on miscellaneous chemicals given in this table exclude pesticides and other organic agricultural 
chemicals for the years 19*9-50. Data on pesticides and other organic agricultural chemicals were Included 
with those on miscellaneous chemicals in reports for years before 1951, Statistics on miscellaneous chemicals 
for 19*9-50 have been adjusted to make these data comparable with those for 1951-5*. 

in output in the other in 1954 compared with 1953. These groups 
are as follows: Medicinals (cyclic, -3.4 percent, and acyclic, 
+6.7 percent); plastics and resin materials (cyclic, -1. 1 percent, 
and acyclic, +5.8 percent); perfume and flavor materials (cyclic, 
+ 18.5 percent, and acyclic, -12.8 percent); and miscellaneous 
chemicals (cyclic, +1.7 percent, and acyclic, -1.6 percent). The 
output of dyes and of toners and lakes (all cyclic compounds) de- 
clined in 1954 compared with 1953. 

The tabulation below shows, by chemical group, the number of 
companies that reported production in 1954 of one or more of the 
chemicals included in the groups listed in table 6. 



Grc 



Number of companies 



Intermed ia tes 1 42 

Dyes 52 

Toners and lakes 40 

Medicinals 121 

Flavor and perfume materials 52 

Plastics and resin materials 150 

Rubber-processing chemicals 24 



Group Number of companies 

Elastomers (synthetic rubbers) 21 

Plasticizers 52 

Surface-active agents 146 

Pesticides and other organic 

agricultural chemicals 78 

Miscellaneous chemicals 231 



SYNTHETIC ORGANIC CHEMICALS, 1954 13 

Cyclic Intermediates 

Cyclic intermediates are synthetic organic chennicals derived 
principally from coal-tar crudes produced by destructive distil- 
lation (pyrolysis) of coal and from petroleum and natural gas. 
Most cyclic intermediates are used in the manufacture of more ad- 
vanced synthetic organic chemicals and finished products, such as 
dyes, medicinals, explosives, elastomers (synthetic rubbers), 
pesticides, and plastics and resin materials. Some intermediates, 
however, are sold as end products without further processing. For 
example, refined naphthalene may be used as a raw material in the 
manufacture of 2-naphthol, or of other more advanced intermedi- 
ates, or it nnay be packaged and sold as a moth repellent or as a 
deodorant. In generad, the way in which the greater part of the out- 
put of a given chemical is consumed determines its use classifica- 
tion in this report. 

Table 7A^ shows statistics on production and sales of cyclic in- 
termediates in 1954. Intermediates for which individual statistics 
are given in the table represent 83 percent of the total quantity 
produced. Since many of the intermediates included in the statis- 
tics represent successive steps in production, the totals neces- 
sarily include considerable duplication. In 1954, about one-third 
of the total output of cyclic intermediates was sold; the rest was 
consumed chiefly by the producing plants in the manufacture of 
more advanced intermediates and finished products. 

The total output of all cyclic intermediates in 1954 was 4,614 
million pounds, or 1.8 percent less than the record output of 4,699 
million pounds reported for 1953, and 10. 6 percent more than the 
4,171 million pounds reported for 1952. Sales in 1954 amounted to 
1,793 rriillion pounds, valued at 320 million dollars, compared with 
1,874 million pounds, valued at 341 million dollars, in 1953, and 
1,544 million pounds, valued at 290 million dollars, in 1952, The 
average unit value of sales was 18 cents a pound both in 1954 and 
1953, and 19 cents a pound in 1952. 

The output of many individual intermediates was greater in 1954 
than in 1953. In 1954 the output of dodecylbenzene, used chiefly in 
the manufacture of surface-active agents, was 358 million pounds, 
or 20.3 percent more than the 297 million pounds produced in 1953. 
In 1954, production of phthalic anhydride, used chiefly in the nnan- 
ufacture of alkyd resins and phthalate esters, was 254 million 
pounds, or 12. percent more than the 227 nnillion pounds pro- 
duced in 1953; and the output of phenol, used chiefly in the manu- 
facture of phenolic resins, was 418 million pounds, or 9. 2 per- 
cent more than the 382 million pounds produced in 1953. On the 
other hand, the production of a sizable number of important inter- 
mediates was smaller in 1954 than in 1953; that of cyclohexane de- 
creased 27.4 percent; nitrobenzene, 17.2 percent; refined naphtha- 
lene, 14.6 percent; aniline, 14.2 percent; p-dichlorobenzene, 12.5 
percent; and styrene, 11.9 percent. In this report statistics for a 
number of important intermediates are given for the first time; the 
output in 1954 of ethylbenzene was 825 nnillion pounds; of p -xylene, 
59 nnillion pounds; and of cumene, 33 million pounds. 



^ See also table 7B, part III, which lists these products alphabetically and identifies 
the manufacturers; part A of the appendix, which shows imports of intermediates and related 
products during 1952-54; and part C of the appendix, which is a glossary of synonymous 
names of cyclic intermediates. 



14 



UNITED STATES TARIFF COMMISSION 



TABIX 7\. --Synthetic organic chemicals: United States production and sales of cyclic intermediates, 1954 

[Listed below are all cyclic intermediates for which any reported data on production or sales may be pub- 
lished. (Leaders are used where the reported data are accepted in confidence and may not be published or 
where no data were reported.) Table 7B in part III lists alphabetically all cyclic intermediates for which 
data on production or sales were reported and identifies the manufacturer of each. Part C in the appendix 
lists alphabetically all the important common names of cyclic intermediates usually met with in the trade 
and gives the corresponding standard (Chemical Abstracts) name under which data are presented in tables 7A 
and 7B] 



Sales 



(Juantity 



Unit 
value ^ 



1,000 

pounds 

'1,613,869 



1,000 

pounds 

1,792,831 



1,000 
dollars 
319,875 



$0.18 



Chemicals for which separate statistics may not be shown- 
Cheraicals for which separate statistics are shown below — 



782, -439 
3,831,';30 



403,780 
1,389,051 



10-4,592 
215,283 



Aoetanilide, tech 

N-Acetylsulfanilyl chloride 

p-Aminoacetanilide (Acetyl-p-phenylenediamine) 

5-Ajnino-2-anilinobenzenesulfonic acid 

2-(p-Aminoanilino)-5-nitrobenzenesulfonic acid 

1-Aminoanthraquinone and salt 

2-Aminoanthraquinone and salt 

6-Amino-3,"4' -azobis [benzenesulfonio acid] 

l-Amino-4-benzamidcanthraquinone 

l-Amino-5-ben2amidoanthraquinone 

6- (m-Aminobenzamido)-l-naphthol-3 -sulfonic acid 

6-(p-Aminobenzamido)-l-naphthol-3-sulfonic acid 

2-Anu.no-p-benzenedisulf onic acid [S03H=l] 

l-Amino-A-bromo-2-anthraquinonesulfonic acid 

l-Amino-5-chloroanthraqulnone 

2-Amino-A-chlorophenol 

2-Amino-4-chloro-l-phenol-6-sulfonic acid 

2-Amino-5-chloro-p-toluenesulfonic acid [ S03H=l] 

l-Ainino-2,4-dibromoanthraquinone 

3-Amino-l,5-naphthalenedisulfonic acid (Cassella acid) 

6-Amino-l,3-naphthalenedisulfonic acid (Amino I acid) ~ — 

7-Amlno-l,3-naphthalenediEulfonic acid (Amino G acid) 

2-Araino-l-naphthalenesulfonic acid (Tobias acid) 

5-Amino-l-naphthalenesulfonic acid (Laurent's acid) 

5-Amino-2-naphthalenesulfonic acid (l,6-Cleve's acid) 

5(and 8)-Amino-2-naphthalenesulfonic acid (Cleve's acid, mixed) 

6-Amlno-2-naphthalenesulfonic acid (Broenner's acid) 

8-Amlno-l-naphthalenesulfonic acid (Perl acid) 

8-Aiiilno-2-naphthalenesulfonic acid (1,7-Cleve's acid) 

8-Anilno-l-naphthol-3,6-disulfonic acid (H acid), monosodium salt 

8-Amino-l-naphthol-5,7-disulfonio acid (Chicago acid) (2S acid), 

monosodium salt 

l-Amino-2-naphthol-'i-sulfonic acid (l,2,i-Acid) 

6-Amino-l-naphthol-3-sulfonlc acid (I acid), sodium salt 

7-Amino-l-naphthol-3-3ulfonio acid (Gamma acid), sodium salt 

8-Amino-l-naphthol-5-sulfonlc acid (S acid), sodium salt 

2-Aiiiino-4-nitrophenol 

2-Aaiino-<i-Ritro-l-phenol-6-sulfonio acid 

p-Aminophenol and salts 

2-Amino-l-phenol-4 -sulfonamide 

2-Amlno-l-phenol-4-sulfonic acid 

p-(p-Aminophenylazo)benzenesulfonic acid 

i-Amino-m-toluenesulfonio acid [S03H=l] 

2-Amino-3,5-xylenesulfonic acid [ S03H=l] 

Aniline (Aniline oil) 

Anillnomethanesulfonic acid and salt 

8-Anilino-l-naphthalenesulfonic acid (Phenyl peri acid) 

6-Anilino-l-naphthol-3-sulfonic acid (Phenyl J acid) 

7-Anllino-l-naphthol-3-sulfonio acid (Phenyl gamma acid) 

Anthranilic acid (o-Aminobenzoic acid) 

Anthra[l,9]pyTazol-6(2H)-one (Pyrazoleanthrone) 

1,5-Anthraquinonedisulfonic acid 

1,8-Anthraquinonedisulfonic acid and potassium salt 

2,6-Anthraquinonedisulfonic acid and salt 

1-Anthraquinonesulfonic acid and salt 

3-( 1-Anthraquinonylamino) -7H-benz [de] anthracen-7-one 

Anthrarufin (1,5-Dihydroxyanthraquinone) 

See footnotes at end of table. 



3,1'MD 

2,868 

198 



29 



1,085 

66 

72 

1,262 

301 

3,825 

113 

217 

171 

77 

459 

234 

2,227 



1,120 
858 
674 



24 
235 

16 
105 
113 
234 

12 

97,349 

164 

261 



253 
11 
495 
142 
379 
1,636 
207 
167 



3,191 
82 



.26 
.15 

.28 

1.49 



1,754 



1,310 



54 



1.69 
1.14 
1.26 



37,382 
60 



SYNTHETIC ORGANIC CHEMICALS, 1954 

TABLE 7A. --Synthetic organic chemicals: United States production and sales of cyclic intermediates, 

1954 --Continued 



15 



Production 



Quantity Value 



Unit 
value ' 



Benzaldehyde , tech — — — - — 

l-Benzainido-5-chloroanthraquinone — — — — 

7H-Benz [de ] anthracen-7-one ( Benzanthrone ) 

Benzenesulfonaniide " 

Benzenesulfonyl chloride — 

Benzidine hydrochloride and sulfate — 

Benzoic acid, tech ~ 

Benzotriazole, tech 

o-Benzoylbenzoio acid — 

Benzylamlne ._.— • 

Benzyl ether (Dlbenzyl ether) — 

(i,,i'.Bl-7H-benz[de]anthracen)-7,7'-dlone 

l,i-Bis[l-anthraquinonylamino] anthraquinone 

3, 9-Bis[ 1-anthraquinonylamlno] -7H-benz [de ]anthracen-7-one 

A,'i'-Bis[dimethylamino]benzhydrol (Michler's hydrol) 

"Iji'-Bisidimethylaminojbenzophenone (Michler's ketone) 

3-Bromo-7H-benz[ de] anthracen-7-one ( Bromobenzanthrone ) — 

2-Chloroanthraquinone 

Chlorobenzene, mono 

o-(p-Chlorobenzcyl)benzoic acid 

l-Chloro-2,^-dinitrobenzene (Dinitrochlorobenzene) 

6-Chlorometanilio acid 

l-Chloro-2-methylanthraquinone 

2-Chloro-^-nitroaniline (o-Chloro-p-nitroaniline) 

'4-Chloro-2-nitroaniline (p-Chloro-o-nitroaniline) 

l-Chloro-5-nitroanthraquinone 

4-Chloro -3 -nitrobenzenesulf onaini de 

2-Chloro-5-nitrobenzenesulfonio acid 

«i-Chloro-2-nitrophenol 

(p-Chlorophenyl)aoetonitrile 

2-Chloroquinizarin 

-i-Chlorotoluene ( Benzyl chloride ) 

-V-Chloro-o-toluidine [>JH2=l] (Fast red XR base) 

5-Chloro-o-toluidine hydrochloride [MHj^l] 

■i-Chloro-o-tolylmercaptoacetic acid 



Cresols, total^ 

Cresols, (c-), (m-), and (p-) 

Cresols, (m,p-) and (o,m,p-)' 



Cresylic acid, refined, total^- 

From coal tar 

From petroleum 



Cumene 

Cyolohexane 

1,4-Diaminoanthraquinone 

1,5-Diaminoanthraquinone 

2,6-Diaminoanthraquinone 

2,'i-Diaminobenzenesulfonic acid [SOjHsl] 

'i,'i'-Diamno-3,3'-blphenyldisulfonic acid 

2,2'-Diamino-5,5' -bi-m-toluenesulfonio acid 

i,<»'-Diaminodiphenylamine-2 -sulfonic acid 

4,'4'-Diamino-2,2' -stilbsnedisulfonic acid 

l,5-Dianilino-2,5-anthraquinonedicarbo]!ylic acid 

4,5'-Dibenzamido-l,l'-iiiiinodianthraquinone 

1,5-Dibenzoylnaphthalene 

3,9-Dibromo-7H-benz[de] anthracen-7-one 

2,5-Dichloroaniline and hydrochloride [NH2=1] 

1,5-Dichloroanthraquinone 

1,8-Diohloroanthraquinone 

o-Dichlorobenzene 

p-Diohlorobenzene 

3,3'-Dichlorobenzidine base and salts 

l,4-Dichloro-2 -nitrobenzene (Nitro-p-dichlorobenzene)- 

2,'4-Dlchlorophenol 

l-(2,5-Dichloro-4-sulfophenyl)-3-methyl-5-pyrazolone — 

N,N-Diethylaniline 

4,5-Dihydroxy-l-naphthalenesulfonic acid 

6,7-Dihydroxy-2-naphthalenesulfonic acid . 

16,17-Dihydroxyvlolanthrone (Dihydroxydibenzanthrone)- 

m-Dimethoxybenzene 

3,3'-Dimethoxybenzidine 

N,N-Diinethylaniline 

2,2' -Dimethyl-1, 1 ' -bianthraquinone 

p-(2,4-Dinitroanilino)phenol 

•4,<i'-Dinitro-2,2'-stilbenedi3ulfonic acid 

6, S-Diphenylamino-l-naphthalenesulf onic acid — — 

l,4-Di(p-toluidino) anthraquinone 



1,879 

79 

1,450 

80 

247 

1,277 

241 

5,180 

41 

47 

564 
91 



200 

86 

488 

367,947 

964 

4,150 

50 

133 

494 

335 



11,545 



22.036 



5,895 
16, 141 



21,259 
26,635 



33,118 
217,619 



42 

65 

23,890 

51,871 

923 

492 

17,215 

71 

329 

4 

252 

540 

56 

620 

7,017 

75 



1,546 



1,773 
274 



1.000 
dollars 

662 



38,661 



5,149 



21,657 



5, 
15,809 



41,091 



4,379 



2,454 
1,925 



21,148 
19,943 



2,145 
1,730 



17,816 
42,153 



1,826 
6,355 



See footnotes at end of table. 



16 UNITED STATES TARIFF COMMISSION 

TAf^IE 7A. --Synthet ic omanic chemicals: Vni ted States production and sales of cyclic intermediates, 

1954- -Con tinuerf 



Quantity Value 



Unit 
value ^ 



Dodecylbenzenes* 

2-(N-Ethylanilino)ethanol 

1 -( N-Ethylanllino ) -p-toluenesulf onio acid 

Ethylbenzene 

N-Ethyl-N-phenylbenzylamlne (N,N-Ethylbenzylaniline)- 

o-Formylbenzenesulfonio acid (o-Sulfobenzaldehyde) 

p-Hydrazinobenzenesulfonlc acid 

3-Hydroxy-2-naphthoio acid (B.O.N.) 

l,l'-Iminobis[<;-aniinoanthraquinone] 

l,l'-Iminobis[5-benzamidoanthraquinone] 

6,6'-Iminobls [l-naphthol-3-sulfonic acid] 

l,l'-Imlnobis [i-nltroanthraquinone] 

l,l'-Iminodianthraquinone (Dianthriraide) 

Isoviolanthrone ( Isodibenzanthrone ) 

Leuco-l.i-diaminoanthraquinone 

Leuoo quinizarin (Ij-ijgjlO-Anthratetrol) 

Metanilic acid (m-Aminobenzenesulfonic acid) 

o-Methoxyanilinomethanesulfonic acid and sodiujti salt- 

2-Methyl-l-nitroanthraquinone 

3-Methyl-l-phenyl-5-pyrazolone (Developer Z) 

3-Methyl-l-(p-sulfophenyl)-5-pyrazolone 



Naphthalene, solidifying at 79 C, or above 

From American crude naphthalene 

From imported crude naphthalene 



(refined flake), total- 



1,5-Naphthalenedisulfonio acid 

Naphthionic acid, sodium salt 

1-Naphthol (a-Naphthol) 

2-Naphthol-3,6-disulfonic acid and disodium salt 

2-Naphthol-6,8-disulfonie acid (G acid) 

1-Naphthol -<i-sulfonic acid (Nevile & Winther's acid) 

l-Naphthol-5-3ulfonic acid 

l-Naphthol-8-sulfonic acid 

2-Naphthol-6-sulfonic acid (Schaeffer's acid) 

1, 8-Naphthosultone ' 

Naphth [l,2]oxadiazole-5-sulfonic acid 

2-Naphthylainine (p-Naphthylamine) 

2-Naphthylmercaptoacetio acid (P-Naphthylthioglycolic acid) 

m-Nitroanlllne 

2-Nitro-p-anisidlne [NH2=1] 

4-Nitro-o-anisidine [ NHj=ll 

5-Nitro-o-anisidlne [NHj=l] 

l-Nitro-2-anthraquinonecarboxylio acid 

5-Nitro-l-anthraquinonesulfonic acid 

6-(p-Nitrobenzamido)-l-naphthol-3-sulfonic acid (p-Nitrobenzoyl J 



acid)- 



Nitrobenzene 

m-Nltrobenzenesulfonic acid and sodium salt 

7(and g)-Nitronaphth[l,2]oxadiazole-5-sulfonio acid 

l-(m-Nitrophenyl)-5-oxo-2-pyrazoline-3-carboxylio acid 

o-Nitrotoluene 

3-Nitro-p-toluenesulfonic acid [S03H=1] 

5-Nitro-o-toluenesulfonic acid [S03H=lJ 

2-Nitro-p-toluidine [NHj^l] 

4-Nitro-o-toluidine [ NH2=1 ] 

16-Nltrovlolanthrone 

Nitroxylenes, mixed 

Nonylphenol 

5-Oxo-l-(p-sulfophenyl)-2-pyrazoline-3-carboxylic acid (Pyrazolone T) 

Phenol, total^ 

Natural, from coal tar and petroleum 

Synthetic 



Phenylacetio acid (a-Toluio acid), all grades 

Phenjrlacetio acid, ethyl ester, all grades 

Phenylacetic acid, potassium salt 

Phenylacetonitrile (T-Tolunitrile) 

p-Phenylazoaniline (p-Aminoazobenzene) and hydrochloride- 

m-Phenylene diamine 

o-Phenylenediamine 

Phenylglyoine, potassium and sodium salts, total 

2,2'-(Phenyllmino)diethanol 

Phthalic anhydride 

Phthalimide 

Plcolines' 

Primuline base 



357,781 

96 

297 

825,010 

631 

135 

127 

3,428 

89 

66 



183 
13'i 

780 
27 
137 
261 
81 



51,433 
19,718 

211 

1,133 

523 

1,119 

1,508 

76 

64 



598 
1,086 



122 
255 



122,548 

1,038 

498 



333 
1,582 
2,170 



849 
9,196 



417,503 



20,830 
396,673 

601 

524 

2,041 

1,513 

149 

650 

773 

3,625 

428 

253,847 

93 

963 

129 



1,000 
pounds 

313,067 



i.ono 

dollars 
35,525 



$0.11 



39,071 



27,360 
11,711 



335 
171 



3,480 



2,399 
1,081 



334 
151 



5,928 
538 



656 
192 



4,511 



218,581 



18,455 
200,126 



2,355 



31,504 



2,403 
29,101 



210,197 
841 



39,737 

401 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



17 



TABLE ^^. --Synthetic organic chemiatls: United States production and aalea of cyclic intermediatea , 

7954- -Continued 



Oiantlty Value ^i^gi 



Pyridine ' 

Qulnaldine — — 

(^linizarin ■ 

Salicylic acid, tech 

Styrene, all grades 

Sulfanilio acid (p-Amlnobenzoic acid) and salt 

<;-Sulfoanthranllic acid 

^j-V'-Sulfonyldiphenol (4, A '-Dihydroxydiphenylsulfone) 

1,^,5, 8-Ietrachloroanthraquinone 

1,2,^,5-Tetrachlorobenzene ■ ■ ■- ■ ■ ■ 

1, A, 5, 8-Tetrakis [l',l",l"',l"' '-anthraquinonylamino lanthraquinone 

(Pentaanthramide) • ■■ 

3 , 3 '-Thiobis [7H-benz [de ] anthraoen-7-one] 

Toluene-2,<»-diainlne ('i-m-Tolylenediamlne) — — 

6-p-Toluidicometanillc acid — . .. ,- ,----.,.— 

m- and o-Toluidinomethanesulfonio acids, total -— 

o-(p-Toluyl) benzoic acid 

'V-(o-Tolylazo)-o-toluidine (o-Aminoazo toluene) 

a»a/0-Trichloro toluene (Benzo trichloride) > — 

6,6'-Ureylenebis[l-naphthol-3-sulfonic acid) (J acid urea)— 

Veratraldehyde ( 3, 4-Dljnethoxybenzaldehy de ) 

Violanthrone (Dibenzanthrone) 

p-Xylene -■■ 

Xylenesulfonlc acid 

Xylenols, total 

2,-;-, 2,5-, 3,'i-Xylidines, total 

Xylidine (original mixture) — ■ ■- • 



t.OOO 

884 

17 

1,198 

15,053 

703,169 

2,085 

10 

265 

32 

5,12-; 



184 
1,627 



328 
477 
444 
354 

13 

485 

59,188 

38 

1,344 

71 



2,315 
328,782 



402 
20 



41,891 
1,491 



1.000 

dollar, 

820 



823 
53,073 



7,035 
114 



Per 
pound 
$0.90 



485 



' Calculated on rounded figures. 

' Includes data for coke ovens and gas-retort ovens, reported to the Coal Economics Division, U. S. Bureau 
of Mines, and for tar and petroleum refineries and other producers, reported to the U. S. Tariff ConnilBslon. 

^ Includes some mixed cresols. 

* Includes keryl-type benzenes. 

' Includes data for coke ovens and gas-retort ovens, reported to the Coal Economics Division, U. S. Bureau 
of Mines, and for tar refineries and other producers, reported to the U. S. Tariff Conmisslon. 



Dyes 



Table 8A shows United States production and sales of dyes in 
1954, total and by individual dyes, grouped by Colour Index num- 
ber and by prototype number.^ The total output of dyes in 1954 was 
143 million pounds, or 13.8 percent less than the 166 million 
pounds produced in 1953, ana 1 percent less than the 145 million 
pounds produced in 1952. Sales in 1954 amounted to 137 million 
pounds, valued at l60 million dollars, compared with 152 million 
pounds, valued at l68 million dollars, in 1953- -a decrease of 9.4 
percent in quantity and 4. 3 percent in value. The average unit 
value of all sales was $1. 17 a pound in 1954, compared with $1. 10 
a pound in 1953 and $1. 15 a pound in 1952. 

Dyes for which separate statistics are given in table 8A repre- 
sent 82 percent of the total quantity of all dyes produced in 1954. 
In 1954, as in previous years, dyes grouped by Colour Index num- 
ber accounted for the greater part of the output of all dyes (71 per- 
cent). The production of Colour Index dyes was 101 million pounds 
in 1954, compared with 117 million pounds in 1953--a decrease of 
13.9 percent. Sales of Colour Index dyes totaled 95 million pounds, 



^ See also table 8B, part III, which lists these products and identifies the manufac- 
turers, and part A (table 28) of the appendix, which shows imports of dyes during 1952-54. 



18 UNITED STATES TARIFF COMMISSION 

TABLE 8A. --Synf/ie fie organic chemicals: United States production and sales of coal-tar dyes, 1954 



[Listed below are all coal-tar dyes for which any reported data on production or sales may be published. 
(Leaders are used where the reported data are accepted in confidence and may not be published or where no 
data were reported.) Table 8B in part III lists all dyes for which data on production or sales were 
reported and identifies the manufacturer of each] 



Grand total 



Dyes for which separate statistics may not be shown- 
Dyes for which separate statistics are shown below — 



DYES GROUPED BY COLOUR INDEX ^mMBEfi 



Azo Dyes 
Monoazo E^es 



Spirit yellow R 

Oil yellow 

Chrysoidine Y 

Chrysoidlne R 

Sudan I 

Orange G — 

Amido naphthol red G 

Chrome yellow 2G 

Chrome yellow R 

Azo alizarin yellow GP- 

Viotoria violet ^BS 

Amido naphthol red 6B — 

Fast scarlet G salt 

Fast red GL salt 

Ponceau R 

Fast red B 

Chrome brown R 

Azo eosine G 

Fast red B base 

Fast red B salt 

Fast scarlet R base 

Fast scarlet R salt 

Metanil yellow 

Orange II 

Orange R 

Acid chrome garnet R 

Fast red A — 

Azo rubine 

Fast red VR 

Cochineal red A 

Chrome blue black R 

Chrome black T 

Acid chrome red B 

Chrome flavine A 



Sales 



1,000 
pounds 
142,982 



25,775 
117,207 



100, 860 



Disazo Etyes 



Resorcin brown 

Reso-tcin dark brown 

Acid black lOB 

Azo dark green A 

Brilliant croceine M 

Cloth scarlet G 

Direct fast red 8BL 

Scarlet EC 

Fast acid cyanine 5R ex 

Acid chrome black F 

Fast acid black 2BN 

Fast acid cyanine black B- 

Direct fast heliotrope 

Rosanthrene 

Direct fast scarlet 

Direct fast scarlet 4BA 

Bismarck brown G 

Bismarck brown R 

Direct fast yellow 5GL 



182 
231 



29<i 
330 
6^ 
322 
769 
384 

135 
78 



972 
1,423 



432 
339 
974 
38 
279 



328 

175 



738 
267 

143 
817 



Quantity 



1,000 
137,463 



24,160 
113,303 



81 


121 


142 


95 


112 


115 


421 


445 


323 


138 


130 


103 


869 


800 


770 


34^ 


353 


312 


375 


336 


253 



196 
232 



300 
321 
662 
297 
761 
339 



938 
1,414 



1.000 
dollars 

160,302 



37,762 
122,540 



83,701 



112 
190 
154 
59 
119 



326 
371 
606 
278 
410 
211 



640 
1,523 



424 


396 


330 


340 


983 


810 


25 


40 


313 


500 


17 


28 


230 


471 


9 


13 


301 


288 


148 


247 


281 


329 


164 


195 


26 


86 


11 


20 


755 


1,302 


247 


443 


133 


80 


821 


700 


20 


46 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



TABLE 8A. --Synthetic organic chemicals 



■ United Stntex procJiu 
J95-f- -Continued 



and sales of coal-tar dyes 



19 



Dye 



Quantity 



DYES GROUPED BY COLOUR INDEX NUMBER— Continued 



Aio Dycf-Contlnued 



Dlsazo Dyes — Continued 



Direct fast pink 2BL 

Brilliant yellow 

Chrysophenine G 

Congo red 

Congo corinth G 

Direct scarlet B 

Direct violet B 

Direct violet N 

Developed black BH 

Direct blue 2B 

Direct orange R — 

Direct fast red F 

Direct brown M 

Polar red — — 

Milling red G- 

Benzopurpurlne 4B 

Benzo new blue 5B 

Acid anthracene red 3B 

Fast blue B base 

Fast blue B salt 

Direct azurine G 

Direct blue RW 

Direct sky blue FF 

Direct pure blue 



Trisazo Dyes 



Direct fast blue FR— 
Direct fast black FF- 

Direct brown BT 

Direct black EW 

Direct black RX 

Direct green EI 

Direct green B 

Direct green G -- 

Direct brown 3G0 

Congo brown G 



Direct yellow R 

Chloramine orange G~ 
Stilbene yellow 



Pyrazolo 



Fast light yellow — 
Xylene light yellow — 

Tartrazine 

Polar yellow 

Chrome red B 

Pyrazol orange 



Kctonimme Dye 



Auramine- 



Tr ipheny Ime thane and 
Dtphenyinaphthylme thane Dyt 

Malachite green 

Rhoduline blue 6G 

Brilliant green — 

Acid green B — — — 

Fast acid green B 

Acid glaucine blue — 

Methyl violet B and base 

Crystal violet 

Ethyl violet 

Acid violet 

Acid chrome azurol B 



311 
328 
153 
122 
85 

19 

1,818 

611 

112 

153 

314 

216 

14 

568 

35 

58 

62 

100 

169 



58 
141 
142 
5,560 
410 
212 
638 

657 



50 
115 
352 



000 


1,000 


inds 


dollars 


22 


59 


261 


387 


280 


614 


138 


116 


122 


149 


125 


222 


7 


10 


17 


27 


1,953 


1,333 


621 


238 


100 


82 


153 


167 


322 


316 


194 


282 


10 


18 


505 


595 


29 


60 


37 


49 


67 


110 


116 


129 


140 


156 


31 


52 


264 


438 


68 


60 



45 
144 
137 
5,387 
375 
179 
584 

51 
653 



41 
162 
326 
50 
63 
48 



96 

140 
295 
3,063 
257 
143 
418 
39 
455 



291 
439 
103 
102 
90 



1,681 



91 


78 


197 


137 


119 


121 


14 


24 


88 


709 


512 


530 


1,283 


1,038 


1,127 


518 


503 


1,359 


74 


24 


64 


101 


98 


161 


76 


73 


183 



See footnotes at end of table. 



20 



' UNITED STATES TARIFF COMMISSION 



TABLE 8\, ^-Syntbet ic organic chemicals: United States production and sales of coal-tar dye 

1954- -Continued 



Dye 



DYES OROUPED BY COLOUR INDEX NUMBER— Continued 

Triphtnylme thane and 
DiphenylnaphthylMt thane Dyes --Continued 

Acid chrome cyanine R 

Victoria blue B 

Naphthalene green V 

Xanthene DyeJ 



Rhodamine B cone, lOOit 

Fluorescein 

Uranlne (Fluorescein, alkali salt)- 

Quinolme Dye! 



Quinoline yellow- 



Primuline — — 

Direct fast yellow- 



Thiaiole Dye 



Wool fast blue 

Safranine 

Induline, spirit-soluble 



Thiaime Dye 



Methylene blue- 



Sulfur or Sulfide Dye 



Total^ 

Sulfur black 

Sulfur maroon 

Sulfur olive 

Sulfur yellow 

All other 



Alizarin VI 

Alizarin red S 

Acid alizarin blue SE 

Acid alizarin blue B— 

Alizarin irisol R 

Alizarin cyanine green 

Anthraquinone blue black B 

Acid anthraquinone sky blue B — 



/tnt/iraiiui 



Vat Dye 



Anthraquinone vat golden orange G, 12% 

Anthraquinone vat scarlet G, 16-2/35t 

Anthraquinone vat dark blue BO, 25% 

Vat navy blue NTP 

Anthraquinone vat jade green, 6% 

Anthraquinone vat green B and black B, l2~l/2%- 

Anthraquinone vat violet 2R, 12-1/2% 

Anthraquinone vat blue RS, 10% 

Anthraquinone vat blue GOD, 8-1/3% 

Anthraquinone vat olive R, 12-1/2% 

Anthraquinone vat brown R, 12-1/2% 

Anthraquinone vat brown G, 12-1/2% 

Anthraquinone vat violet BN, 25% 



Indigoid and Thiomdigoid Dyes 

Indigo, synthetic, 20% 

Bromindlgo blue 2BD, 16% 

Vat red 3B, 20% 

Vat orange R, 10% 



125 
263 



75 
222 



1,000 
pounds 



116 
287 



1,521 


11,546 


U9 


180 


132 


176 


429 


457 


3,615 


8,735 



124 
453 



196 

471 



2,314 
164 



149 
3,234 



509 


1,332 


3 


18 


458 


1,345 


106 


228 


25 


132 



515 


205 


362 


364 


271 


724 


373 


374 


773 


697 


520 


944 


6,098 


5,653 


5,036 


1,743 


1,700 


1,213 


522 


718 


1,365 


1,638 


96 


136 


2,623 


2,489 


2,896 


513 


561 


648 


627 


611 


989 


734 


730 


945 


117 


125 


692 


11,129 


10,620 


3,067 


649 


587 


442 


122 


125 


201 


446 


371 


435 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1954 

TABLE 8\. --Synthetic organic chemicals: United States production and sale: 

19 J4- -Continued 



21 



Qxiantlty 



DYES GROUPED BY COLOUR INDEX mjMBER— Continued 
Food, Drug, and Cosmetic Dyes 



Food, Drug, and Cosmetic Colors 



Orange # 1 

Red #1 

Red # 2 

Red #4 

Yellow #4 

Yellow #6 



Drug and Cosmetic Colors 



Total^- 

Red #7 

Red #9 



Red § 12 

Red # 13 

Red # 19 

All other 



All Other Dyes Grouped by Colour Index Numbe 

Total 

DYES CKOUPED BY PROTOTYPE NUMBER 



Total- 



Acid alizarin flavine R 

Acid anthracene brown PG 

Algol yellow GC 

Alizarin supra blue A 

Anthracene chromate brown EB 

Artificial silk black G 

Benzo Bordeaux 6B 

Benzo chrome black blue B 

Benzo copper blue B 

Benzo fast black L 

Benzo fast blue 4GL 

Benzo red 12B 



Benzo rhoduline red 3B — 

Brilliant benzo violet B 

Brilliant milling blue B 

Brilliant wool blue FFR 

Celliton orange GR 

Chlorantine fast brown BRL — 

Chlorantine fast yellow AGL 

Diamine Bordeaux B 

Diamine catechine 3G 

Diamine fast blue FFB 

Diamine fast orange EG 

Diamine fast orange ER — 

Diamlnogen blue N2B 

Diazo Bordeaux 7B 

Diazo brilliant green 3G ~ 

Diazo brilliant scarlet 2BL ex 

Diazo fast red 5BL 

Diazo fast red 7BL 

Fast scarlet 2G salt 

Guinea carmine B 

Guinea fast red BL 

Hellndone pink R ex 

Indanthrene brilliant orange RK 

Indanthrene brown BR 

Indanthrene brown RRD - 

Indanthrene khaki 2G 

Indanthrene rubine R 

Milling yellow H5G 

Neolan blue GG 



1,524 



28 
201 
115 
419 



48 
302 
232 
109 



13,310 
29,232 

1,944 
53 
125 
170 
18 



Oxydiaminogen OB 



30 
208 



17 
935 
202 
881 
519 
637 
85 
18 
375 
434 



1,000 

pounds 

1,529 



1.000 
dollars 
5,844 



58 
291 
205 



10,478 



29,678 



2,981 
53 
130 



360 
166 
81 
44 
154 
106 



836 
258 
300 
605 
796 



277 
500 



5,235 



374 
412 
556 
1,183 
403 
174 
87 
130 
897 
622 
397 



10,749 



50,035 
13 



2,982 
223 



246 
202 



262 
266 
116 
53 
319 
193 



53 
298 
24 



1,291 
491 

1,521 
954 

1,352 

41 
449 
6^ 



pound 

J3.82 



22 



UNITED STATES TARIFF COMMISSION 



TABLE 8\.--Synthetic organic chemicals: United States production and sales of coal-tar dye 

1954- -Continued 



Quantity Value 



DYES GROUPED BY PROTOTYPE NUMBER— Continued 



Paper red A ex — — 

Polar orange R -— 

Rapldogen Bordeaux R — 

Rapldogen red RS 

Rapldogen scarlet RS 

Rapldogen yellow G 

Rosanthrene fast Bordeaux 2BL 

Rosanthrene orange R 

Victoria fast violet 2R ex 

Victoria pure blue B 

Alizarin fast gray BBLW 

Brilliant indocyanine G 

Celliton fast blue FTR 

Celliton fast brown 3R ~ 

Celliton fast pink FF3B 

Celliton fast red GG 

Celliton fast red violet RN 

Celliton fast rubine B 

Celliton fast rubine 3B 

Celliton fast yellow G 

Celliton scarlet B— 

Celliton yellow 5G- 

Chlorantine fast red 5BRL 

Diazo fast yellow 2G 

Erlo chrome brown DKL — 

Fast blue BB base 

Fast Bordeaux GP base — 

Fast Bordeaux GP salt- — — — — ~ 

Fast orange GR salt-- — — — — 

Fast red AL salt — 



Fast red 3GL salt 

Fast red KB base 

Fast red KB salt 

Fast red RC base 

Fast red RC salt 

Fast red TR salt 

Fast violet B base — 

Sirius supra red violet RL 

Sirius supra turquoise blue GL 

Indanthrene brilliant violet 3B — ~ — 

Indanthrene direct black RB 

Indanthrene golden orange 3G 

Indanthrene golden yellow GK 

Indanthrene olive green B 

Monochrome black blue G — 

Naphthol AS-BR 

Naphthol AS-BS 

Naphthol AS-E 

Naphthol AS-ITR 

Naphthol AS-OL 

Naphthol AS-SW 

Naphthol AS-TR 

Neolan orange G 

Palatine fast pink BN 

Palatine fast yellow ELN 

Rapldogen blue N 

Rapldogen brown IPT 

Rapldogen violet B 

Cotonerol — 

Fast red ITR base 

Sirius supra gray VGL 

Naphthol AS-BG 

Chlorantine fast red 6BLL 

Chlorantine fast violet 5BL 

Chlorazol blue 5GKS 

Sirius light blue FBGL 



See footnotes at end of table. 






1,000 


ds 


dollars 


120 


277 


6 


11 


117 


289 


20 


62 


300 


54.8 


139 


253 


169 


397 


96 


196 


20 


58 


65 


225 


20 


35 


65 


76 


112 


351 


23 


36 


25 


130 


8 


66 


8-15 


1,194 


40 


67 



107 


99 


95 


241 


262 


385 


136 


156 


195 




18 


53 


161 


140 


354 




5 


11 




5 


10 


11 


15 


80 



127 
445 
116 
29 



314 


279 


653 


105 






337 






547 


526 


827 


985 


648 


1,436 


1,300 


1,268 


2,169 


58 


44 


152 


947 


726 


931 


23 


24 


75 


22 


28 


91 


273 


133 


315 


347 


183 


389 




4 


13 


41 


31 


118 


108 


39 


175 


59 


47 


133 


570 


513 


1,209 




32 


143 


63 


66 


105 


57 


36 


78 


51 


61 


107 


137 


127 


197 


54 


54 


327 


133 


162 


154 


22 


26 


97 


505 


472 


353 




7 


27 



SYNTHETIC ORGANIC CHEMICALS, 1954 

TABLE SA. --Synthetic organic chemicals: United States production and sales of coal-tar dyes, 

2954--Continued 



23 



Dye 



Quantity 



Unit 

value^ 



DYES GROUPED BY PROTOTYPE NUMBER— Continued 



Chlorantine fast violet 2KL 

Fast red PDC base 

Fast red PDC salt 

Indanthrene red violet RRN — — 

Cellltazol AZN 

Direc t chlnollne 

Eastman fast yellow GLF 

Indanthrene olive T 

Naphthol AS-MX 

Naphthol AS-PH 

Neutral bro'*n RX — 

Pontamine navy blue DB 

Solantine orange ^G 

Sirius supra yellow R ex 

All other dyes grouped by prototype nujnber- 



UNGROUPED DYES 



Total- 



Acetate rayon dyes, total (see table 3 for total of 

all acetate rayon dyes)' 

Black, IV ex., B, DB, EC, 3G, GGN, GOO, GS, GY, 

J, LNB, NC, PL, R, RB, RK, SS^ 

Blue, #15, A8-45, AGF, B, 2B, BG, BGLF, BN, BP, 
CH, EC, G, 2G, 5G, 6G, GBN, GFD, GLF, GLT, GP, 
GR, GSF, GSS, LB, LWGF, MJ, NBN, NVY, RB, RBN, 
RDA, RG, 2R, 3R, -iR, WNBN* 

Red III, VI-X, AB, B, 2B, 3B, 2B-GLF, iBLL, C, FFB, 
G, GLF, GSF, MBS, NB, R, RP, WLF-iO, Y, YP'' 

Yellow, CW, FSI, G, 3G, 5G, 8GLF, GL, GR, I, III, 
IX, M, N, PGA, R, 2RGLF, -VRL, <iRLA, 4RLF, 4RL-SN, 
RN, YL^ 

All other acetate rayon dyes 

Acid violet NR, R, RNL, 2R, 3RL 

Acid yellow 3G, 6G, N, NR, NW, 3RD 

Anthraquinone vat gray BR, 2G, GFL, GNF, R 

Azoic dyes and their components, total (see table 3 
and table 6 for data on all azoic dyes and their 

components )' 

Direct black, CW, DB, 3G, 5G, 3GR, GN, HH, MB, RCW, 

RW 

Direct blue, 2BCF, BFL, lOBLL, 12BLL, 16BLL, lOBLU, 
BR, BVW, 2GFL, GL, 3GLL, 4GLL, 8GLN, SGttF, LBLL, LDU, 
LULR, NPC, NR, R, RDW, 2RCF, 3R, RL, RLU, 2RFL, 2RLU, 

7RLL, UGLL, VRS 

Direct brown, GB, 3GS, KRS, NZ, 2R, 3RLL, RSC, RY 

Direct fast blue, BLL, 2BRN, CPL, 3GL, 8GLL, GLFV, 

L5GA, L6GA, LRRU, RL, 3KL, 2RLL, SFGL, SFRL 

Direct fast orange, G, GL, 2GL, 4GLL, L8GL, 3LWF, R 

Direct fast red, 3BL, 8BLN, 8BLSW, SBNL, GBL, L<iBL, 

WL 

Direct fast yellow, EFC, 5G, 3GL, 8GLL, AGLP, L2RX, 3R 
Direct white, ACC, ACL, B, AB, 5B, 4BN, BP, GG, K, LD, 

MR, t^R, P3R, 2R, RN, RW, SC, WT 

Oil orange, #30, MT 

Oil red, #322, #-^30, DB, ED, EGN, N-1700, 0, RO 

All other ungrouped dyes ™ 



J, 000 
pound. 



779 
153 



199 
6,9<;2 



12,690 
2,293 



<;i5 



1,122 
300 



231 
225 



1,530 
107 



l,-i28 



5<U 
5,523 



37 

57 

250 



1,002 



194 
7,35-4 



12,946 
2,.i08 



1,000 
dollars 

86 
191 
434 

623 

475 

114 

1,273 

42 
296 

37 

121 

189 

466 

14,156 



26,566 
4,634 



425 



1,107 
322 



309 
245 



1,176 
135 



57 

1,559 

39 

519 

6,328 



440 



2,639 
526 



2,091 
136 



4,576 



692 
12,857 



pound 
$2.32 
3.35 
1.74 

.71 
3.25 
1.43 
1.27 
1.91 
2.96 
2.31 
1.05 
2.45 
2.40 
1.92 



2.38 
1.63 



1.70 
2.06 



1.78 
1.00 



2.38 
1.60 



1.33 
2.03 



^ Calculated on rounded figures. 

^ Does not include derivatives of oarbazole (Colour Index Nos. 943, 969). 

^ Includes drug and cosmetic colors, external, data on which cannot be published separately without dis- 
closing information received in confidence. 

' Excludes acetate rayon dyes that appear under "Dyes grouped by prototype number." 

' Includes developed black and diazo black. 

' Includes brilliant blue, fast blue, navy blue, and pure blue. 

"^ Includes pink, rubine, and scarlet. 

Includes fast yellow, golden yellow, and printing yellow. 

' Does not include azoic dyes and their components that appear under "Dyes grouped by Colour Index number" 
and "Dyes grouped by prototype number." 



24 UNITED STATES TARIFF COMMISSION 

valued at 84 million dollars, in 1954, compared with 108 million 
pounds, valued at 90 million dollars, in 1953--a decrease of 12.2 
percent in quantity and 6. 5 percent in value. Production of proto- 
type dyes in 1954 was 29 million pounds, or 10.4 percent less than 
the 33 million pounds produced in 1953. The sales of these dyes 
totaled 30 nnillion pounds, valued at 50 million dollars, in both 
1953 and 1954. Production of ungrouped dyes in 1954 was 13 mil- 
lion pounds, compared with 16 million pounds in 1953--a decline 
of 19.4 percent. Sales of such dyes in 1954 amounted to 13 million 
pounds, valued at 27 million dollars, compared with 14 million 
pounds, valued at 28 million dollars, in 1953--a decline of 8.7 
percent in quantity and 6. 5 percent in value. 

Among the individual dyes for which statistics are given intable 
8A, increases in production in 1954 compared with 1953 were re- 
ported for only a snnall number- -principally low- and medium- 
priced dyes. Production of sulfur black in 1954 was 11.5 million 
pounds, or 23. 8 percent more than the 9. 3 million pounds produced 
in 1953. The output of anthraquinone vat blue GCD (C.I. 1113) was 
2. 6 million pounds, compared with 2. 5 million pounds in 1953, and 
1.8 million pounds in 1952. On the other hand, the output of a large 
number of low- and medium-priced dyes was smaller in 1954 than 
in 1953. For example, production of synthetic indigo (C.I. 1177) 
was 11.1 million pounds in 1954, or 37. 6 percent less than the 
17.8 million pounds produced in 1953, and the output of direct 
black EW (C. I. 581) was 5. 6 million pounds or 10. 1 percent less 
than the 6. 2 million pounds produced in 1953. Decreased output in 
1954, compared with 1953, was reported also for indanthrene 
olive T (Pr. 547) (a decrease of 42.8 percent); bromindigo blue 
2BD(C.I. 1184) (37.7 percent); indanthrene olive green B (Pr. 
293) (36. 2 percent); acid black lOB (C.I. 246) (32. 5 percent); 
a ur amine (C.I. 655) (31.8 percent); and developed black BH (C.I. 
401) (23.8 percent). 

Table 9 shows production and sales of dyes in 1954, by chenni- 
cal class. Four chemical classes of dyes accounted for about 84 
percent of the total quantity of all dyes produced in 1954: Azo dyes, 
for 36.6 percent; anthraquinone vat dyes, for 21.8 percent; sulfur 
dyes, for 15.8 percent; and indigoid and thioindigoid dyes, for 9.8 
percent. Except for sulfur dyes, the production of which increased 
0. 5 percent in 1954 compared with 1953, the output of the remain- 
ing three classes declined in 1954 compared with 1953. Production 
of indigoid and thioindigoid dyes declined 3 5. 1 percent; anthraqui- 
none vat dyes, 18.9 percent; and azo dyes, 8.3 percent. 

Table 10 shows the average annual production of dyes in the 
5-year period 1948-52, together with annual data for 1953 and 1954 
by class of application. Table 11 gives corresponding data for 
sales. Two classes of dyes accounted for 50 percent of the total 
output of all dyes in 1954; these classes are vat dyes, which ac- 
counted for 31.6 percent, and direct dyes, which accounted for 
18. 3 percent. Production of 3 classes of dyes increased in 1954 
over the 1948-52 average: Azoic dyes, 30.8 percent; lake and 
spirit-soluble dyes, 11.5 percent; and sulfur dyes, 10.8 percent. 
On the other hand, the output of direct dyes declined 3 0. 1 percent 
in 1954, compared with 1948-52; that of mordant and chrome dyes 
declined 28. 2 percent; that of acid dyes declined 26. 8 percent; 
and that of vat dyes declined 24. 1 percent. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



25 



TABLE 9. --Synthetic organi 



chemicals: United States production and 
chemical class, 1954 



ales of coal-tar dyes, by 



Chemical class 



Quantity 



Unit 
value^ 



Anthraqulnone vat^ 

Indlgold and thioindlgoid 

Sulfur or sulfide 



Triphenylme thane and diphenylnaphthylmethane- 

Anthraquinone 

Stilbene- 

Ketonlmine 

Pyrazolone 

Xanthene 

Thiazole 

Thiazine 

Quinol ine 

Acrldine 

All other' 



1,000 



l'i2,982 



1,000 
pounds 
137,^3 



1,000 
dollars 
160,302 



52,388 

31,128 

1^,0^1 

22,608 

5,599 

5,IM0 

2,935 

98-4 

1,190 

869 

A3A. 

298 

258 

130 

5,080 



50,3^2 

30,058 

13,253 

22,801 

3,938 

i,961 

3,057 

973 

1,155 

678 

A5A 

315 

248 

90 

5,i';o 



67,27-i 

40,387 

6,451 

6,573 

7,925 

11,069 

6,276 

1,681 

2,550 

2,387 

804 

508 

762 

140 

5,515 



$1.17 



1.34 

1.34 

.49 

.29 

2.01 
2.23 
2.05 
1.73 
2.21 
3.52 
1.77 
1.61 
3.07 
1.56 
1.07 



'■ Calculated on rounded figures. 

^ Includes carbazole vat dyes. 

■' Includes naphthalimlde, nitro, nitroso, azine, oxazine, phthalooyanine, and aniline black and allied dyes; 
also includes rubber colors and miscellaneous mixtures. Statistics for these groups cannot be published sep- 
arately without disclosing information accepted in confidence. 



TABLE 10. --Synthetic organi 



chemicals: United States production of coal-tar dye 
average 1948-52, annual 1953 and 1954 



by class of applicat i 



Class of application 



Acetate rayon- 
Ac id 

Azoic 



Direct 

Lake and spirit-soluble- 

Mordant and chrome 

Sulfur 



Vat, total- 
Indigo 

All other- 



All other coal-tar dyes- 



Total- 



Aoetate rayon 

Acid 

Bas ic 

Direct 

Lake and spirit-soluble- 

Mordant and chrome 

Sulfur 



Vat, total ~ 

Indigo 

All other- 



All other coal-tar dyes- 



ftuantity (1,000 pounds) 



173,754 



7,284 

18,837 

7,901 

7,838 

37,382 

5,462 

5,776 

20,404 

59,558 



19,886 
39,672 



3,312 



165,806 



6,263 
15,510 
8,713 
7,981 
31,495 
6,270 
3,844 
22,489 

60,957 



17,839 
43,118 



2,284 



142,982 



5,326 
13,783 
10,336 

6,995 
26,142 

6,091 

4,150 
22,608 

45,200 



11,129 
34,071 



2,351 



Percent of total quantity 



100.0 



4.2 
10.9 

4.6 

4.5 
21.5 

3.1 



11.5 
22.8 



3.8 
9.4 
5.2 
4.8 



10.8 
26.0 



3.7 
9.6 
7.2 
4.9 
18.3 
4.3 



31.6 
7.8 
23.8 



Note. — The leuco vat esters are included uith vat dyes in 1949-54, and with direct dyes in 1948. 



26 



UNITED STATES TARIFF COMMISSION 



TABLE 11. --Synthetic orga 



chemicals: United State 
average 1948-52, an 



sales of coal-tar dye 
al 1953 and 1954 



,f appli 



Class of application 



Total 

Acetate rayon 

Ac id 

Basic 

Direct 

Lake and spirit-soluble 

Mordant and chrome 

Sulfur 



Vat, total- 
Indigo 

All other- 



All other coal-tar dyes- 



Total 

Acetate rayon 

Ac id 

Azoic 

Basic 

Direct 



Lake and spirit-soluble- 

Mordant and chrome 

Sulfur 



Vat, total 

Indigo 

All other 



All other coal-tar dyes- 



Total 

Acetate rayon 

Ac id 

Azoic 

Direct 

Lake and spirit-soluble- 

Mordant and chrome 

Sulfur 



Vat, total- 
Indigo 

All other- 



All other coal-tar dyes- 



Total 

Acetate rayon- 
Acid 

Azoic 

Basic 



Direct 

Lake and spirit-soluble- 

Mordant and chrome 

Sulfur 



Vat, total 

Indigo 

All other — 



All other coal-tar dyes- 



Quantity (1,000 pounds) 



16<;,001 



6,750 

17,20^ 

6,803 

7,175 

36,130 

5,11A 

5,662 

21,055 

5^,997 



19,303 
35,69^ 



3.111 



151,675 



5,927 
13,231 
6,7^1 
6,928 
29,174 
5,935 
3,8';5 
21,910 

55,853 



19,289 
36, 56-; 



2.131 



137,4.63 



5,6U 

12,622 

8,629 

6,067 

26,082 

5,885 

4,23<V 

22,801 

43,324 



10,620 
32 ,704 



Percent of total quantity 



4.1 
4.4 

.^.0 



21.7 
2.0 



8.7 
4.4 
4.6 

19.3 
3.9 
2.6 

14.4 

36.8 



12.7 
24.1 



100.0 



4.1 
9.2 
6.3 
4.4 

19.0 
4.3 
3.1 

16.6 



7.7 
23.8 



Value (1,000 dollars) 



168,902 



9,741 
19,726 
13,912 
10,398 
37,668 
4,823 
5,686 
6,593 

52.918 



4,482 
48,436 



167,526 



9,577 
17,076 
12,254 
10,645 
37,462 
6,435 
4,829 
7,073 

55,705 



5,090 
50,615 



160,302 



9,653 

17,395 

15,430 

10,813 

34,674 

6,718 

5,294 

6,573 

46.854 



3,067 
43,787 

6,898 



Percent of total value 



100.0 



5.8 
11.7 
8.2 
6.2 
22.3 
2.8 
3.4 
3.9 



2.7 
28.6 



100.0 



5.7 
10.2 
7.3 
6.4 
22.4 
3.8 
2.9 
4.2 



100.0 



6.0 
10.9 
9.6 
6.8 
21.6 
4.2 
3.3 
4.1 

29.2 



1.9 
27.3 



;.— The leuco vat esters are included with vat dyes in 1949-54, and with direct dyes in 1948. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



27 



Production and sales of ungrouped dyes (those having neither a 
Colour Index nor a prototype number) are shown by chemical class in 
table 12 andbyclass of application in table 13. Two chemical classes 
of ungrouped dyes accounted for two-thirds of the total output of 
these dyes in 1954; these were azo dyes, which accounted for 49. 3 
percent, and anthraquinone vat dyes, which accounted for 17.4 per- 
cent. The output of azo dyes was slightly smaller in 1954 than it 
was in 1953, but that of anthraquinone vat dyes was 54.4 percent 
smaller. For ungrouped dyes arranged by class of application, three 
classes of dyes accounted for two-thirds of the total output of these 
dyes: Direct dyes accounted for 28.9 percent; vat dyes, for 19.6 
percent; and acetate rayon dyes, for 17.8 percent. The output of all 
three classes of these dyes was smaller in 1954 than it was in 1953. 
The output of ungrouped vat dyes declined 50. 7 percent; that of ace- 
tate rayon dyes, 25. 6 percent; and that of direct dyes, 22. percent. 



TAELE 12. -'Synthetic organic chemicals: United States production and sale 
by chemical class, 1954 



of tjngrouped dye 



Chemical class 



Sales 



Quantity 



Value Unit value^ 



12,890 



1,000 
pounds 
12,9A6 



1,000 
>Uar5 
26,566 



Anthraquinone vat 

Indlgoid and thloindigoid- 

Anthraquinone 

Stilbene 

All other^ 



6,3'i9 
2,2';2 

281 
1,636 
1,556 

826 



6,005 
2,5*9 

202 
1,668 
1,668 

85A 



10,7*6 
5,305 
321 
3,606 
^,807 
1,781 



»2.05 



1.79 
2.08 
1.59 



^ Calculated on rounded figures. 

' Includes triphenylmethane and dlphenylnaphthylmethaiie, pyrazolone, xanthene, quinoline, acridine, 
phthalocyanine, and miscellaneous dyes. 



T/ffiLE 13. --Synthetic organic chemicals: United States production and sales of 
by class of application, 1954 



ngrouped dyes. 



Class of application 



(luantity 



Value Unit value^ 



1,000 
pound. 

12,890 



1,000 
pounds 

12,946 



1.000 
dollar, 
26,566 



Acetate rayon- 
Acid 



Lake and splrit-soluble- 
Vat- 



All other^- 



2,293 
496 
1,530 
3,719 
1,520 
2,523 
809 



2,408 
567 
1,176 
3,866 
1,443 
2,751 
735- 



4,634 
1,223 
2,091 
8,800 
2,635 
5,626 
1,557 



$2.05 



1.92 

2.16 
1.78 
2.28 
1.83 
2.04 
2.12 



^ Calculated on rounded figures. 

' Includes basic, sulfur, mordant and chrome, and miscellaneous dyes. 



28 UNITED STATES TARIFF COMMISSION 

Table 14 shows production and sales of azoic dyes and their 
components in 1954. The output of these products totaled 10. 3 mil- 
lion pounds in 1954, or 18.6 percent more than the 8.7 million 
pounds produced in 1953. In 1954 sales of these products were 8.6 
million pounds, valued at 15.4 million dollars, compared with 6.7 
million pounds, valued at 12. 3 million dollars, in l953--an in- 
crease of 28. percent in quantity and 25.9 percent in value. The 
output of rapidogens was 1.8 million pounds in 1954, or 32.9 per- 
cent more than the 1.4 million pounds produced in 1953. Production 
in 1954 of fast color salts increased 6, 3 percent compared with 
1953; that of Naphthol AS and its derivatives increased l6.9 per- 
cent. On the other hand, the output of fast color bases declined 
17.4 percent in 1954 compared with 1953. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



29 



TABLE lA. -Synthetic organic chemicals: United States productic 
and their components, 1954 



and sales of 



Dye 



Grand total' - 



Dyes and coii5>onents for which separate statistics 
may not be shown-' 

Dyes and components for which separate statistics 
are shown below 



DYES 



Rapidogen, total- 
Black 

Blue D 

Blue N 

Blue, other* 

Bordeaux 

Bordeaux R 

Brown IPT 

Orange R 

Red GS 

Red RS 

Red, other' 

Scarlet RS 

Violet B 

Yellow G 

All other 



Fast color bases, total- 
Blue B 

Blue BB 

Bordeaux GP 

Red B 



Red ITR 

Red KB 

Red PDC 

Red RC 

Scarlet R 

Violet B 

All other 



Fast color salts, total- 
Blue B 

Bordeaux GP 

Orange GC 

Orange GR 

Red AL 

Red B 

Red GL 

Red 3GL 

Red KB 

Red PDC ^— 

Red RC 

Red TR 

Scarlet G 

Scarlet 2G 

Scarlet R 

All other 

Naphthols , total 

Naphthol AS 



Naphthol AS-BG 

■Naphthol AS-BO 

Naphthol AS-BR 

Naphthol AS-BS 

Naphthol AS-D 

Naphthol AS-E 

Naphthol AS-G 

Naphthol AS-ITR 

Naphthol AS-MX 

Naphthol AS-OL 

Naphthol AS-PH 

Naphthol AS-SW 

Naphthol AS-TR 

All other 



Produc- 
tion 



1,000 
pounds 

10,336 



933 

9,403 

1,825 



216 
121 
137 
77 
23 
23 

5-; 

133 
318 
121 
103 
190 
22 
108 
179 



1,563 

— sr 



330 

1,025 
2,930 



100 
74 



121 
294 
132 
381 



345 
644 
228 



22 
273 
347 



108 
28 



145 
570 



Quantity 



1,000 

pounds 

8,629 



511 
8,118 



312 
117 
127 



162 
300 
139 



1,083 



116 
81 



127 
300 
196 
445 



332 
662 
235 



1,000 
dollars 

15,430 



576 
14,854 



764 
289 
197 
160 



327 
154 
548 
258 
203 
397 
97 
196 
529 



285 
191 

18 
371 

16 
601 



129 
106 
82 
31 
189 
326 
190 
293 



111 
112 
298 
606 
612 



133 


315 


183 


389 


4 


13 


31 


118 


39 


175 


22 


42 


47 


133 


100 


296 


513 


1,209 


32 


143 


262 


1,262 



Unit value' 



' Calculated on rounded figures. 

Totals shown represent all azoic dyes and their components. Totals shown in tables 8A and 13 represent 
ngrouped dyes and their components only. 

Includes rapid fast and fur dyes. 
' Includes navy blue. 
' Includes corinth. 
^ Colour Index number. 



30 



UNITED STATES TARIFF COMMISSION 

Toners and Lakes 



As the terms are used in this report, toners and lakes (or laked 
colors) are synthetic organic pigments. Statistics on production and 
sales of all toners and lakes are given in table 15A.^ Statistics on 
the commercial forms of a few selected pigments (dry, flushed, or 
pulp) are given in table l6. Wherever possible, individual toners 
and lakes are identified either by Colour Index number or prototype 
number of the dye from which they may be made, or by abbrevia- 
tions indicating the intermediates used in their manufacture. 

Synthetic organic pigments are used in paints and related prod- 
ucts, in printing inks, and in plastics and resin materials. Toners 
are full-strength pigments; lakes and reduced toners are extended 
or diluted colors. 

The total output in 1954 of toners, lakes, and extended (or re- 
duced) toners was 40. million pounds, a decrease of 9. 2 percent 
from the 44. 1 million pounds reported for 1953. Sales in 1954 
amounted to 34. 8 million pounds, valued at 53. 9 million dollars, 
compared with 36.7 million pounds, valued at 56.0 nnillion dollars, 
in 1953- -a decrease of 5. percent in quantity and 3. 9 percent in 
value. 

TABIX ISA. --Synthetic organic chemicals: Vpited States production and sales of toners and lakes, 1954 

[Listed below are all toners and lakes for which any reported data an production or sales may be published. 
Table 15B in part III lists all toners and lakes for which data on production or sales were reported and 
identifies the manufacturer of each ] 



Quantity 



Unit 
value^ 



TONERS OH FULL-STRENGTH COLQRS 



Products for which separate statistics may not be shown^- 
Produots for which separate statistics are shown below- 



Black toners- 



Blue toners, total- 
AliHll blue, C.I. 



7(X- 



Phthalocyanine blue B, Pr. A81 

Setoglaucine (Peacock blue a) (C.I. 658), PMA- 
Setoglaucine (Peacock blue 0) (C.I. 658), PTA- 

Viotoria pure blue B (Pr. 198), PMA 

Victoria pure blue B (Pr. 198), PTA 

All other 



Oreen toners, total 

Brilliant green (C.I. 662), PMA- 
Brilllant green (C.I. 662), PTA- 
Plgment green B, Pr. 1<«9 
All other 



Maroon toners, total- 



B.O.N. maroon (Llthol maroon)- 

Naphthol AS-D (Pr. 306) 

Toluldine maroon 
All other 



Orange toners, total- 



Benzidine orange 
Dianisidlne orange 
2,'4-^lnltroanlline orange- 
o-<<itroanlline orange 
All other 



See footnotes at end of table. 



1.000 
pounds 
39,981 



26,901 



78 
26,823 



3,826 



1,235 
1,9-13 



87 
28 

511 

2,432 



563 
1,841 



1.000 
pounds 
34,844 



1,000 
dollars 
53,869 



22,927 



86 

22,841 



28 
3,320 



1,194 

1,510 

7 

U 

86 

24 

485 

2,165 



447 
1,696 



43,022 



163 
42,859 



9.422 



2,511 
4,796 
41 
84 
243 
121 
1,626 

7.154 



36 

68 

574 

6,476 

1.981 



139 

1,518 



154 
164 
202 
65 
30 



$1,55 



1.90 
1.88 



1.57 



2.83 
2.10 
3.18 
5.86 
6.00 
2.83 
5.04 
3.35 



3.30 
3.60 
5.67 
1.28 
3.82 

3.49 

1.71 



3.4^ 
4.40 



1.80 
2.96 
2.45 
1.30 
1.18 
2.50 



SYNTHETIC ORGANIC CHEMICALS, 1954 



31 



TABLE 15\. --Synthetic orga 



ic chemicals: United States product i 
and lakes, 7954 --Continued 



Quantity 



TONERS OR Frai-^STRENGTH COLORS— Continued 



Red toners, total- 



1,000 
pounds 
15,487 



pounds 



o-Chloro-p-nltroanillne red (Chlorinated para red)- 

Eoslne (Bromo acid toner) (C.I. 768) 

Llthol red 2C (C.I. 166) 

Llthol red R, C.I. 189, total 

Barium toner — — __^_^-___^___-___ 



Calcium toner 

Sodium and other toners 

Llthol rubine B (C.I. 163) 

Naphthol AS (Pr. 302) and dca 

Naphthol AS (Pr. 302) and pnot 

Naphthol AS-BS (Pr. 305) and pnoa— 

Naphthol AS-D (Pr. 306) and pnot 

Naphthol reds, other 

Para red, light, C.I. AA 

Para red, dark- 



Permanent red 2B (Pr. 563)- 

Pigment rubine X 

Pyrazolone red 

Red lake C, C.I. 165- 



Rhodamine B (C.I. 7'i9), PMA 

Rhodamine B (C.I. 7'i9) , PIA 

Rhodamine 60 (Rhodamine 6GDN) (Rhodamine Y) (C.I. 752), PMA 

Rhodamine 60 (Rhodamine 6GDN) (Rhodamine Y) (C.I. 752), PTA 

Toluldina red, C.I. 69 

All other 



Violet toners: 

Methyl violet B (C.I. 680), PMA- 
Methyl violet B (C.I. 680), PTA- 



Metf^l violet B (C.I. 680), fugitive- 
Yellow toners: 

Benzidine yellow (deb and aaa)- 



Benzidlne yellow (dob and aaot)- 
Benzidine yellow, other——— 

Hansa yellow G, Pr. 103 

Hansa yellow lOG, Pr. 105 

Hansa yellow, other 



661 

721 

72 

5,118 

2,880 

1,651 

587 

69-4 

46 

117 

106 



1,046 
390 

1,739 
15 
150 

1,154 



2,565 
601 



1,238 
653 
13 
813 
142 
319 



460 

146 

71 

4,963 

2,710 

1,627 

626 

650 

37 

116 

109 



893 

397 

1,264 



55 

2,171 

565 



857 

603 

7 

631 



1,000 
dollar, 

17,412 



529- 

224 

107 

4,073 

2,191 

1,352 

530 

888 

110 

318 

372 

251 

854 
364 

2,352 

53 

574 

1,138 

63 

212 

217 

322 

3,264 

1,107 



526 
292 
448 

1,646 
1,330 
23 
960 
174 
832 



pound 



Production 



Toner 
content 



Q\iantity 



REDUCED OR EXTENDED TONERS 



Products for which separate statistics may not be 
shown^ .— — — — ^_— ^^.^__^-____.-__ 

Products for which separate statistics are shown 
below 



1.000 
pounds 
1,760 



7,389 



1,000 
dollars 

7,108 



72 
7,723 



1,750 



7,321 



7,033 



Blue toners, reduced, total- 
Methylene blue (C.I. 922)- 
Phthalocyanine blue B, Pr. 



Setoglauclne (Peacock blue G) (Rhodullne 
blue 6G) (C.I. 658), PMA and PTA- 



2,011 

11 

1,572 



1,729 

9 

1,283 



2,298 

10 

1,399 



Victoria pure blue B (Pr, 198), PMA and PTA- 
All other 



119 
295 



Green toners, reduced, total- 



Brilliant green (C.I. 662), PMA and PTA 

Brilliant green (C.I. 662) and thloflavine 
(C.I. 815), PMA and PTA- 



12 

106 
319 

1,530 



30 
114 
745 



Malachite green (C.I. 657), PMA and PTA- 

Pigment green B, Pr. 149 

All other 



Orange toners, reduced: o-^itroanlllne orange- 
Red toners, reduced, total 
Llthol red R, C.I. 189- 



73 

5 

674 

720 



2,365 



28 
537 



700 
702 



2,327 



366 
737 



Llthol rubine B (C.I. 163) 
Naphthol reds, total 



Naphthol AS-BS (Pr. 305) and pnoa- 
Other naphthol reds 



129 
140 
1,032 
559 
473 



212 
149 



105 
144 
1,034 
556 
478 



104 
733 
354 
379 



See footnotes at end of table. 



32 



UNITED STATES TARIFF COMMISSION 



TABL£ ISA. --Synthetic organic chemicala: United States production and aaiea of 
tonera and lakea , 19 54- -Continued 



Tcnar 
oontan't 



Quantity 



REDUCED OR EiTEMDBD TOMERS— ContlnUBd 

Had tanors, reduced — Continued 
Para red, dark 

Permanent red 2B (Pr. 563) 

Red lake C, C.I. 165, barluB toner 

Hhodamlne B (C.I. 7'i9), PMA and PTA 

Rhodflmlne B (C.I. 749). fugitiv e 

Rhodamlne 60 (C.I. 752), PMA and PTA 

Toluldlne red, C.I. 6 9 
AH other 

Violet toners, reduced, total 

Ethyl violet (C.I. 682), PMA 

Methyl violet B (C.I. 680), PMA 

Methyl violet B (C.I. 680), fugitive 

Yellow toners, reduced: 

Benzidine yellows 



52 
6 

146 
137 
317 



156 
6 

9 
34 
29 



1,000 
pound* 
45 
368 

7 
57 

6 
124 
137 
300 



1.000 

dollar, 

12 

455 

5 

58 

5 

122 

73 

377 



320 
228 



313 
657 



113 
72 



309 
202 
79 
138 

292 
674 



356 

176 

81 

213 

257 
381 



Quantity 



LAKES OR UED COLORS 



ProductB for which Bopapate statlBtles may not be ahown*- 
Prodiirts for which separate statistic* are shram belcjw — 



1,000 
pounds 
5,285 



16 
5,269 



17 
4,511 



20 
3,719 



Blask lolcaa- 



Blus lakes, total - 



Brilliant wool blue FFR (Pr. 40) 

Peacock blue, fugitive (Patent blue) (C.I. 671)- 
All other 



205 
2,158 



Maroon lakss- 



27 

1,966 

165 

193 
1,038 



1,541 



~2F 

1,355 
161 

91 

1,050 



"~1J 
1,223 



107 
429 



Orange lakes, total- 



Persian orange (Acid orange T) (Orange II) (C.I. 151)- 
All other 



Red lakes, total- 



Allzarln red B (C.I. 1027) 

Hello fast rublne 4BL (Pr. 406)- 
Plgment scarlet 3B (C.I. 216) — 

Scarlet 2R (C.I. 79) 

All other 



1,171 



IM 
100 
191 
353 
339 



135 
120 



1,117 



112 
105 
201 
372 
327 



1.319 



270 
263 
280 
198 
308 



Violet lakes, total 

Acid violet (C.I. 698)- 
Methyl violet- 
All other 

Yellow lakes: 

Fast light yellow (C.I. 636)- 
Qulnoline yellow (C.I. 801) — 
Tartrazine (C.I. 640) 



15 
13 
192 



^ Calculated on rounded figures. 

^ Includes all brown toners and tmspecifled violet and yellow toners. 

' Includes all black, brown, and maroon reduced toners and unspecified orange and yellow reduced toners. 

* Includes all brown lakes and unspecified yellow lakes. 

Note. — The C. I. and Pr. numbers stand for Colour Index and prototype numbers of the dyes from which the 
lakes or toners may be produced. When the number is not enclosed in parentheses, it signifies that the toner 
Is the same as the dye described In the Colour Index or prototype listing. 

The abbreviations PMA and PTA stand for phosphomolybdlc and phoaphotungstlc acids, respectively. Pigments 
formerly listed as PTMA (phoBphotungstomolyMio acid) are now included with PTA colors. 

Intemediates used In the manufacture of certain colors are abbreviated as follows: 



aaa aoetoecetanillde 

aaot acetoacet-ortho-toluidlde 

dca dichlaroenlllne 

deb dichlorobenzldine 

pnoa para-nitro-ortho-enlsldlne 

pnot para-nitro-ortho-toluldine 



SYNTHETIC ORGANIC CHEMICALS, 1954 



33 



TABLE 16. --Synthetic organic chemicals: United States production and sales o/ selectea ary, 
flushed, and pulp colors, 1954^ 

{Listed below are selected dry, flushed, aad pulp colors for which data on production may be published] 



Dry, fluahed, and pulp fonis 



Produc- 
tion 



Quantity Value 



Unit 
value' 



Alkali blue, C.I. 
Dry form- 



Flushed form- 
Pulp form- 



Benzidlne yellow: 
Dry f onfr- 



Flushed fomt- 
Pulp fontt- 



Eosine (C.I. 76S):* 
Dry f onn— 



Fluahed form- 



Llthol red R, C.I. 189, barium toner: 
Dry f pm^ 



Flushed form- 
Pulp foroi- 



Uthol red R, C.I, 
Dry f omw 



189, calcium toner: 



Flushed fom- 
Pulp form- 



Llthol red R, C.I, 
Dry f orm- 



189, sodium toner: 



Fluahed fona- 



Methyl Tlolet B (C.I. 
Dry form— 



), fugitive:'* 



Flushed form- 
Pulp form- 



Methyl violet B (C.I. 680), permanent: 
Dry for m 



Flushed form- 
Pulp form- 



Peacock blue (C.I. 671), fugitive:' 
Dry form- 



Flushed form- 



Phthalocyanlne blue B, Pr. 
Dry f orm— 



Flushed form- 
Pulp form- 



Red lake C, C.I. 165, barium toner:' 

Dry form 

Fluahed for m 
Toluldine red, C.I. 69: 

Dry form- 



Fluahed form- 
Pulp form 



1,000 

pound$ 

102 

2,536 

994 

1,561 
2,607 
1,224 

301 
1,721 

2,318 

1,788 

339 

1,422 
669 

227 

483 

173 

345 
569 
38 

290 

211 

68 

720 

2,145 

2,943 

888 

2,241 

788 
621 

2,114 
592 
308 



i.OOO 

pounds 

99 

2,562 

963 

1,214 

2,513 

839 

83 
1,054 

2,134 

1,707 

164 

1,385 
611 



492 
268 



236 

523 



250 

214 

55 

2A5 
1,842 

2,600 

865 

2,179 

6A6 
588 

1,746 
304 
329 



1.000 

dollars 

200 

2,895 

325 

2,297 

1,462 

429 

123 
775 

1,648 
749 
76 

1,084 
321 



399 
136 



285 
358 



627 
218 
102 

219 
1,060 

5,351 
1,026 

1,411 

709 
358 

2,544 
253 

112 



Per 
pound 
$2.02 
1.13 
.34 

1.09 
.58 

.51 

1.48 
.74 



.78 
.53 



.81 
.51 



1.21 
.68 



2.51 
1.02 
1.85 

.89 

.58 

2.06 

1.19 
.65 

1.09 
.61 

1.46 
.83 
.34 



^ Statistics on production and sales of the organic pigments (color lakes and toners) listed in this table 
are given In terms of the commercial (physical) forms in \Alch they enter commercial channels. Data on the 
flushed and pulp forma therefore are In terms of total weight. Including pigment and vehicle (water or oil). 

* Calculated on rounded figures. 

' Data on the pulp form were accepted in confidence and may not be published. 

* Data on the pulp form of sales were accepted in confidence and may not be published. 



Production of toners in 1954 totaled 26. 9 million pounds, or 
1.2 percent less than the 27.2 million pounds reported for 1953. 
Sales, however, increased; they totaled 22. 9 million pounds, 
valued at 43. million dollars, in 1954, compared with sales of 
22. 1 million pounds, valued at 41. 1 million dollars, in 1953--an 
increase of 3. 9 percent in quantity and 4. 6 percent in value. Near- 
ly 60 percent of the output of toners consisted of red toners (15. 5 
million pounds). Individual toners produced in the largest quanti- 
ties were lithol red R, 5. 1 million pounds; toluidine red, 2. 6 mil- 
lion pounds; phthalocyanine blue B and benzidine yellow, 1.9 mil- 
lion pounds each; permanent red 2B, 1.7 nnillion pounds; alkali 
blue and red lake G, 1.2 nnillion pounds each; and para red, light, 
1. million pounds. 



34 UNITED STATES TARIFF COMMISSION 

Total production in 1954 of lakes and extended (or reduced) 
toners amounted to 13. 1 million pounds, of which lakes accounted 
for 5. 3 million pounds and extended toners for 7. 8 million pounds; 
total production of lakes and extended toners in 1953 amounted to 
16.8 million pounds. Total production of lakes and extended toners 
in 1954, therefore, was 22. 3 percent smaller than in 1953. Total 
sales of lakes and extended toners in 1954 were 11,9 million pounds, 
valued at 10.8 nnillion dollars, of which 4. 5 million pounds, valued 
at 3.7 million dollars, were lakes, and 7.4 million pounds, valued 
at 7. 1 million dollars, were extended toners; total sales of lakes 
and extended toners in 1953 amounted to 14. 6 million pounds, valued 
at 14. 9 million dollars. Total sales of lakes and extended toners in 
1954, therefore, were 18.4 percent smaller in quantity and 27.3 
percent smaller in value than in 1953. Of the extended pigments, 
blues constituted the leading group. Production of fugitive peacock 
blue lake (C.I. 671) in 1954 was 2.0 million pounds; of reduced 
phthalocyanine blue B toner, Pr. 481, 1.6 million pounds; and of 
reduced naphthol red toners, 1. million pounds. 

Statistics on the dry, flushed, and pulp form of 12 selected 
colors are given in table l6. The data show that in 1954 the quan- 
tity of production and sales of alkali blue, benzidine yellow, eosine, 
fugitive methyl violet B, and fugitive peacock blue in the flushed 
form exceeded the quantity of production and sales in the dry form. 
Conversely, the quantity of production and sales of lithol reds, 
permanent methyl violet B, phthalocyanine blue B, red lake C, and 
toluidine red in the dry form exceeded the quantity of production 
and sales in the flushed form. For most of the specified pigments-- 
except alkali blue and phthalocyanine blue B--the quantity of pro- 
duction and sales in the pulp form was smaller than that in either 
the dry form or the flushed form. 

Medicinals 

In this report, medicinal chemicals are divided into three ma- 
jor groups: (l) Benzenoid compounds, derived principally fronn 
coal tar; (2) alicyclic and heterocyclic compounds, usually derived 
from vegetable products and animal tissues, but sometimes also 
from coal tar; and (3) acyclic compounds, usually derived from 
petroleum and from natural gas, or from grain by fermentation. 

Statistics on the production of medicinals are in terms of 100- 
percent content of the medicinal itself, exclusive of all diluents or 
other materials used in mixing or compounding tablets, solutions, 
and suspensions for consumer use. Except for antibiotics, the 
statistics on sales include only that part of the original (primary) 
production which was sold in undiluted or uncompounded form, in- 
cluding that sold in bulk and that sold in packages (tablets, am- 
poules, etc.). Sales of antibiotics include all forms --diluted or 
undiluted, in bulk or in packages. 

In 1954 the production of all the medicinal chemicals covered 
in this report amounted to 66 million pounds (see table 17A'*)-- 
slightly less than the output reported for 1953. Sales in l954totaled 
53 million pounds, valued at 426 million dollars, compared with 54 
million pounds, valued at 409 million dollars, in 1953. 



* See also table 17B, part III, which lists these products alphabetically and identifies 
the manufacturers. 



SYNTHETIC ORGANIC CHEMICALS, I95A 35 

The output in 1954 of all cyclic medicinals was 49 million 
pounds, of which 35 million pounds consisted of benzenoid medici- 
nals and 14 million pounds, of alicyclic and heterocyclic nnedici- 
nals. Production of acyclic medicinals in 1954 was 16. 6 nnillion 
pounds, compared with 15.6 nnillion pounds in 1953. In terms of 
quantity, acetylsalicylic acid (aspirin) was the most important 
medicinal produced in 1954. The output in that year was 13.9 mil- 
lion pounds, compared with 13. 7 nnillion pounds in 1953; sales in 
1954 amounted to 11.9 million pounds, valued at 6.3 million dol- 
lars, compared with sales of 11.7 million pounds, valued at 6. 1 
million dollars, in 1953. Production of sulfa drugs in 1954 totaled 
4. 2 million pounds, compared with an output of 4. 7 million pounds 
in 1953. Production of barbituric acid derivatives in 1954 totaled 
798, 000 pounds, compared with 634, 000 pounds in 1953--an in- 
crease of 25.9 percent. Sales in 1954 totaled 524,000 pounds, 
valued at 3. 2 million dollars, compared with sales of 427, 000 
pounds, valued at'2.8 million dollars in 1953. 

In terms of value, the antibiotics --as a group- -were the most 
important medicinals produced in 1954. Total production of anti- 
biotics for human and veterinary use in 1954 was 1,837,000 
pounds--207,000 pounds more than the output of 1,630,000 reported 
for 1953. Sales in 1954 totaled 1,263,000 pounds, valued at 240 
million dollars, compared with 1,467,000 pounds, valued at 231 
million dollars, in 1953. Production of penicillin salts in 1954 to- 
taled 477 trillion international units, compared with 372 trillion 
international units in 1953. Sales in 1954 of penicillin salts totaled 
323 trillion international units, valued at 53 million dollars, com- 
pared with 354 trillion international units, valued at 58 million dol- 
lars, in 1953. The output of dihydrostreptomycin increased to 
446,000 pounds in 1954 from the 305,000 pounds reported in 1953. 
Sales in 1954 totaled 286,000 pounds, valued at 19. 5 nnillion dol- 
lars, compared with sales of 297,000 pounds, valued at 24. 5 mil- 
lion dollars, in 1953. The output of streptomycin increased to 
141,000 pounds in 1954 from the 125,000 pounds produced in 1953. 
Production of neonnycin and derivatives was reported for the first 
time in 1954. The total output of these antibiotics in that year 
amounted to 15,000 pounds; sales were 9,000 pounds, valued at 4.6 
million dollars. 

The connbined output of other medicinal antibiotics, such as 
chlorotetracycline, chloramphenicol, and oxytetracycline, totaled 
597,000 pounds in 1954; sales of these products in 1954 amounted 
to 461,000 pounds, valued at 156 million dollars. The total output 
of antibiotics for animal feed supplennent in 1954 was 479,000 
pounds, compared with the 434,000 pounds reported for 1953; sales 
of these products in 1954 amounted to 562,000 pounds, valued at 
25.9 million dollars. 

Among the other important groups of medicinal products in 1954 
were the vitamins. The combined output of vitamins, as a group, 
in 1954 was 5.4 million pounds, compared with 4. 7 million pounds 
in 1953; sales in 1954 totaled 4. 1 million pounds, valued at 76.4 
nnillion dollars, compared with 4.2 million pounds, valued at 77.8 
million dollars, in 1953. In terms of quantity, the output in 1954 
of some of the more important vitamins was as follows: Niacin and 
niacinamide, 2.2 million pounds; ascorbic acid and derivatives, 
1.8 million pounds; pantothenic acid and derivatives, 458,000 
pounds; thiamin derivatives, 259,000 pounds; and vitamin A alcohol 



36 



UNITED STATES TARIFF COMMISSION 



TABLE 17A. --Synt/ieti 



ic chemicals: United States production 



ales of medicinals, 1954 



[Listed below are all synthetic organic medicinals for which any reported data on production or sales may be 
published. (Leaders are used where the reported data are accepted in confidence and may not be published 
or lAere no data were reported.) Table 17B in part III lists alphabetically all medicinals for which data 
on production or sales were reported and identifies the manufacturer of each] 



Sales* 



Quantity 



Value Unit value^ 



Grand total- 



1.000 
pounds 

65,88A 



MEDICINALS, CYCLIC 



Chemicals for which separate statistics may not be shown- 
Chemioals for which separate statistics are shown below — 

Benzenoid 

Acetylsalicylic acid (Aspirin) 

p-Aminobenzoic acid 

p-Aminobenzoic acid derivatives, total 
Benzocaine (Ethyl p-aminobenzoate) — 

Procaine base and salts 

All other 



p-Aminobenzoic acid salts, total- 
Sodium p-aminobenzoate 

All other 



^-Aminosalicylic acid- 
Bismuth subgallate- 



Bismuth subsalicylate 

d-N .a-Dimethylphenethylamine hydrochloride 

Dyes , medicinal 

p-Hydroxybenzoio acid esters: Methyl p-hydroxybenzoate- 
3-(o-Methoxyphenoxy)-l,2-propanediol 

(Glyceryl guaiacyl ether) 

a-Methylphenethylamine (Amphetamine) (Benzedrine) base- 

a-Methylphenethylamine salts 

d-a-Methylphenethylamine salts 

Salicylamide-- — — 

Salicylic acid 



Salicylic acid salts, total - 

Sodium salicylate 

All other 



Sulfa drugs 

3-o-Toloxy-l,2-propanediol (o-Cresyl a-glyceryl ether)- 

Vitamin K and derivatives 

All other benzenoid medicinals 



Alicyclic and Hete 



Antibiotics for human or veterinary use, total- 
Bacitracin 



Dihydrostreptomycin 

Neomycin and salts 

Penicillin salts, total * 

Penicillin potassium 

Penicillin procaine 

All other penicillin salts- 
Streptomycin 

All other antibiotics 



Antibiotics for animal feed supplements- 
Antihistamines 



49,262 



9,838 
39,^24 



35,011 



13,913 



560 



66 
36 

116 
37 

1<V6 
A 
18 

116 



18 

147 

6,195 



4,157 
230 



8,063 



14,251 



631 
186 
378 
67 
141 
597 

479 
163 



1,000 
pounds 
53,232 



1,000 
dollars 

425,835 



39,900 



400,139 



10,349 
29,551 



35,790 
364,349 



27,590 



35,513 



11,6 



""77" 
506 



6,254 
165 



1,851 



"25r 
1,531 
78 



114 



14 
118 



180 
4,851 



166 

87 



84 
133 



258 
213 



215 
1,817 



135 

3 

8,518 



12,310 



5 
286 

9 
427 
113 
258 



542 
114 



242 

109 
23,179 



364,626 



240,128 

— rrfsT 

19,476 
4,563 
53,030 
20,047 
26,213 
6,770 
5,497 
156,278 

25,871 
1,639 



pound 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



TABLE \7h. --Synthetic organic chemicals: United States production and sales of medic 



87 

Bis, 1954- -Continued 



Production^ 



Sales 



Quantity 



Value Unit value^ 



MEDICINAIS, CYCLIC— Continued 



AUcycli 



nd Heterocy<:Iic--Contlnued 



Barbituric acid derivatives, total- 



1,000 
pounds 

798 



5-Allyl-5-Cl-methyltiutyl)barbituric acid (Secobarbital) 
and salt — — — 



5-sec-Butyl-5-ethylbarbiturio acid ^— _ 

5-sec-Butyl-5-ethylbarbituric acid, sodixjm Balt- 
ic 5-Diethylbarbit\iric acid (Barbital) and salt — 
5-Ethyl-5-(l-methyl-n-butyl)barbituric acid 
(Pentobarbital) 



5-Ethyl-5-(l-methyl-n-butyl)barbiturio acid, sodium salt— 
5-Ethyl-5-phenylbarbiturlc acid (Phenobarbital) (Luminal) - 
5-Ethyl-5-phenylbarbituric acid, sodium salt- 
All other — 



Bile acids and salts, total - 

Dehydrooholio acid 

Desoxycholic acid 

All other 



Caffeine, natural and synthetic 

Caffeine citrate 



5-Chloro-7-iodo-8-quinolinol ( lodochlorohydroxyquinoline ) - 
5,7-Diiodo-8-quinolinol- 



5,5-Diphenylhydantoin and sodium salt 

Hormones (steroid), total- 



Hydrocortisone alcohol and aoetate- 

All other . 



Isoniootinic acid hydrazide- 

Phenothiazine 

Piperazine 

Theobromine and derivatives- 



Theophylline base and derivatives, total — 
Theophylline base (1,3-Dimethylxanthine) 



Theophylline ethylenediamine (Aminophylline)- 



Vitamins, total- 



A (Alcohol and esters),' ' from all sources 

Bi (Thiamine derivatives) 

Bj (Riboflavin for human consumption) (lOOjt) 

B2 (Riboflavin for animal and poultry consumption) (lOOjt)- 

Bg (Pyridoxine) — 

all grades- 



D2 (Irradiated ergosterol)' — 

D3 (Irradiated animal sterol )^*'- 
Niacin (Nicotinic acid) , niacina 

hydrochloride 

All other 



ide, and niacinamid 



All other alioyolic and heterocyclic medicinals- 
MEDICINALS, ACYCLIC 
Total 



Chemicals for which separate statistics may not be shown- 
Chemicals for which separate statistics are shown below — 



Amino acids, total-- 
p-Alanine- 



1(+) -Glutamic acid- 
Methionine, all grades- 
All other 



Betaine base and hydrochloride- 
Calcium succinate 



Carbromal (Bronodiethylacetylcarbamide) 

Chloretone (tert-Trichlorobutyl alcohol) 

See footnotes at end of table. 



316 
20 
170 



38 
38 
78 

1,910 



55 
3,437 



150 
105 
12 



116 
259 



181 
24 



(«) 



2,206 

198 



1,775 



16,622 



8,590 
8,032 



1,768 



201 

175 

1,085 

307 

59 



1,000 
dollars 
3,204 



32 

313 
17 
85 



1,696 



3,749 



118 
18 



1,632 
122 



1,831 



13,332 



6,790 
6,542 



1,463 



146 
116 
748 
455 



247 
1,118 



1,216 
1,652 



456 
1,196 



4,752 



12,018 



1,802 
168 



249 
364 



60,006 



11,765 
8,764 
2,726 
3,376 
4,157 

18,894 
437 



5,812 
3,190 



12,611 



25,696 



3,903 
21,793 



3,547 



351 

255 

2,173 

768 

92 



.11 



7.63 
9.00 
9.58 
3.90 

5.86 
7.72 
3.57 



10.60 
15.74 



4.62 
5.75 



4,006.00 



.48 
2.47 



3.11 
3.83 



26.97 



120.05 
52.80 
39.51 
28.61 

230.94 
67,720.43 

415.95 

728.70 

3.56 
26.15 



3.33 



2.42 
2.40 

2.20 
2.91 
1.69 



2.30 



38 



UNITED STATES TARIFF COMMISSION 



TAa,E nK. --Synthetic organic cheaicats: United States production and sales of medic inals, I9J4- -Continued 



Production^ 



Quantity Value Unit value' 



MEDICINALS, ACYCLIC— Continued 



Choline salts, total - 
Choline bltartrate- 



1.000 
pounds 

3,791 



Choline chloride, for animal and poultry feed and for use 
as an Intermediate— ___— ^^-^-^____^_^ 



Choline chloride, medicinal grade only- 
Chollne dlhydrogen citrat e 
All other 



Hexamethylenebis [trlmethylanmonium chloride] 

(Haxamethonium chloride) 
Methyl iodide 
Sodium succinate 

Vitamins, total- 



13!r 



198 
U9 



2,292 



ind 

»0.58 



Ascorbic acid and derivatives, total - 
Ascorbic acid 
All other 



Pantothenic acid and derivatives, total- 

Pantothenic acid, dl-calcium salt 

All other— ————— ——^——— —— 



1,33^ 

1,725 

109 

221 
237 



2,690 
70 
193 
136 



1,8^2 



17626 

1,561 

85 

196 

128 



1,283 



16,285 



1.15 

1.29 

1.20 

.96 



8.84 



13,326 
12,614 
712 
2,959 
1,058 
1,901 



8.10 
8.08 
8.38 

15.10 
8.27 

27.96 



^ Production of mediclnals is in bulk only. The statistics do not inclxide the production of finished prep- 
arations, such as tablets, capsules, and an^ules, ^rtilch are manufactured from bxili mediclnals. 

* Except for antibiotics, sales Include only that part of the original production which is sold in undi- 
luted or uncompounded form including that sold in bulk and that sold in packages (tablets, ajnpoules, etc.). 
Sales of antibiotics include all forms (both undiluted or unconyounded and diluted or compounded) Including 
that sold In bulk and that sold in packages. 

3 Calculated on rounded figures. 

* Penicillin salts in terms of international units based on 1,667 units per milligram of the penicillin 
Q standard of the Food and Drug Administration were reported as follows; 





Production 


Sales 


Chemical 


(luantity 


Value 


Unit value 




BiUion inter- 
national units 

476,658 


BUiion inter- 
national units 

323,030 


1.000 
dollars 

53,030 


Per billion 

international 

units 

$164.16 






140,632 

285,609 

50,417 


35,262 
195,271 
42,477 


20,047 
26,213 
6,770 


235.07 
134.24 
159.38 


_ ...-,. z. ■ 







' Commercial sales are based on international units. 

' ftuantitles reported in units have been converted to pounds using as a factor the average units per pound 
of the medicinal grade as determined by the Food and Drug Administration, 

'' Production of vitamin A alcohol and esters from all sources totaled 103,845 billion U.S. P. units; sales 
totaled 94,423 billion U.S. P. units. 

° Production of vitamin B12, all grades, totaled 422 pounds; sales totaled 292 pounds. 

' Production of vitamin D2 totaled 24,023 billion U.S. P., units; salts totaled 19,049 billion U.S. P. units. 
Calculated at the rate of 18.14 billion >mlts per pound, production totaled 1,324 pounds and sales totaled 
1,050 pounds. 

^° Production of vitamin D3 totaled 24,731 billion U.S. P. units; sales totaled 22,026 billion U.S. P. units. 
Calculated at the rate of 18.14 billion units per pound, production totaled 1,363 pounds and sales totaled 
1,214 pounds. 

and esters, 116,000 pounds (103,845 billion U. S. P. units). In 
terms of value of sales, vitamin B^ was the most innportant. 
Sales of this medicinal in 1954 totaled 292 pounds, valued at 18.9 
million dollars. Sales of ascorbic acid and derivatives were 1.6 
million pounds, valued at 13. 3 million dollars, and of vitamin A, 
98,000 pounds, valued at 11.8 million dollars. 

In 1954 the combined production of all hormones was 28,000 
pounds; sales totaled 3,000 pounds, valued at 12 million dollars. 

Flavor and Perfiune Materials 



Flavor and perfume materials, which are chemicals with de- 
sirable flavors or odors, are used in the manufacture of food, bev- 
erages, cosmetics, and soaps, and to disguise unpleasant odors in 



SYNTHETIC ORGANIC CHEMICALS, 1954 



39 



industrial products. This report covers flavor and perfume mate- 
rials derived from natural products by actual chemiical processes, 
and from coal tar. It does not cover purely natural products, such 
as floral essences, essential oils, and other perfume nnaterials ob- 
tained by simple extraction or by distillation from natural vegetable 
and animal sources. 

On the basis of their chemical structure, the flavors and per- 
fumes covered in this report are grouped as either cyclic or acy- 
clic materials. Cyclic materials are further classified as (l) ben- 
zenoid and naphthalenoid, and (2) terpenoid, heterocyclic, and 
alicyclic. Statistics on the production and sales of flavor and per- 
fume materials in 1954 are given in table 18A.^ 



TABLE tSk.'-Syntbetic orfa 



ic chemicals: United States production and sales of flavor and 
per fx2me materials, 1954 



[Listed below are all synthetic organic flavor and perfume materials for which any reported data on produc- 
tion or sales may be published. (Leaders are used where the reported data are accepted in confidence and 
may not be published, or where no data were reported.) Table 18B in part III lists alphabetically all 
flavor and perfume materials for which data on production or sales were reported and Identifies the 
manxifacturer of each] 



Produc- 
tion 



(Juantity Value 



Unit 
Talue^ 



FLAVOR AHD PEBFUME MATERIALS, CYCLIC 



Materials for which separate statistics may not be shown- 
Materlals for which separate statistics are shown below — 



id and NaphthaU 



a-Amyloinnamaldehyde- 

Ane thole 

Anisaldehyde 



Benzyl acetate 

Benzyl alcohol^ 

Benzyl benzoate^ — 
Benzyl cinnamate — 
Benzyl propionate- 
Benzyl salicylate- 
Eugenol- 



Isobutyl benzoate 

Isobutyl phenylacetate — 
Isoeugenol- 



Methyl benzylacetate- 
Methyl clnnamate- 



Methyl salicylate (Synthetic wlntergreen oil)- 
Phenethyl acetate- 
Phenethyl alcohol- 



All other benzenoid and naphthalenoid materials- 



Ttr 



id. Heterocyclic, and Alicycli 



Cedryl acetate- 



Cineole (Euoalyptol)- 

Citral (Geranlal) 

Citronellol 



Citronellyl acetate 

Citronellyl propionate- 

Coumarin 

Geraniol 



Geranyl acetate- 
Geranyl formate- 



Hydroxycitronellal- 



lonones , total- 
tt-Ionone- 



lonone (p- anda+p-)-- — — — 
See footnotes at end of table. 



1,000 
pounds 

35,307 



1.000 
dollar, 

';7,280 



21,870 



8,705 
13,165 



261 
934 
189 
202 
624 
466 
445 



54 
886 
,392 



418 
417 



18,241 



26,823 



5,985 
12,256 



11,008 



12,712 
14,111 



240 
1,024 
163 
181 
564 
502 
279 



40 
120 
10 



24 
51 

,807 
36 
844 

,022 



394 
792 
321 
207 
309 
246 
148 



241 

38 

65 

1,327 

46 

954 

8,544 



426 
429 



152 
47 
157 
445 



1,100 
736 



20 
716 



13 
112 



pound 
$1.54 



2.12 

1.15 



1.28 



1.64 

.77 

1.97 

l.U 

.55 

.49 

.53 

3.23 

1.24 

1.34 

2.68 

.73 

1.25 

3.50 

1.57 

1.29 

.47 

1.27 

1.13 

2.12 



1.76 



2.32 
1.20 
3.42 
2.34 
3.34 
5.91 
2.58 
1.74 
2.46 
5.17 
4.84 



4.02 
6.62 
3.73 



^ See also table 18B, part III, which lists these products alphabetically and identifies 
the manufacturers. 



40 



UNITED STATES TARIFF COMMISSION 



TAELE ISA.'-Synthetic organic chemicals: United States production and sales of flavor and 
perfume materials, 7954- -Continued 



froduo- 
Uon 



CJiumtlty Value 



Italt 
Talue^ 



FIAVOR AMD FEHFTJME MiTERIAI^, CICLIC— Continued 



7-trp. 



id, HettrocycH 



and Alicycll 



leobomyl aoetate- 
Llnalool 



Llsalyl acetate- 



Menthol, synthetic, tech. and U.S.P- 

Methyllonones (a-, P -, and a+P-) 

Plperonal (Hellotrppln) 

Hhodlnol 
Safrole- 



Terplneols (a-, p -, anda+P-)- 

Terplnyl acetate 

Vetlvenyl acetate- 



All other terpenoid, heterocyclic, and allcyellc materlala'- 
FLAVQR AND PERFTJME MATERIALS, ACTCLIC 
Total 



Materials for which separate statistics may not be shown- 
Materlala for which separate statistics are shown below— 



Ally! caproate- 
Ethyl butyrate- 



Glutamlc acid, monosodlum salt (Monosodlum glutajnate)- 
Isoamyl butyrato (Amyl butyrate) 



1.000 
pounds 

219 
142 
127 
364 
134 
261 
8 
256 

2,481 

237 

4 

3,313 



13,437 



499 
12,938 



Wl 

12,771 

22 



1,000 
pounds 
254 
46 

265 

130 

281 

9 

1A2 

2,381 

254 

4 

1,963 



I2,ii3 



1.000 
dollars 

122 
272 

i,602 
712 
821 
223 
156 
498 
115 
101 

4,168 



20,457 



325 
12,228 



524 
19,933 



4 

156 

12,043 

25 



9 

117 

19,788 

19 



pound 
$0.48 
5.85 

6.05 

5.49 

2.92 

24.53 

1.10 

.21 

.45 

27.69 

2.11 



1.61 
1.63 



2.02 
.75 

1.64 
.76 



^ Calculated on the exact (I.e., unrounded) figures. 

Includes same technical and medlelxal grades. 
* Includes chemically modified essential oils. 



Production of flavor and perfunne materials as a group totaled 
35 million pounds in 1954, compared with 34 million pounds re- 
ported for 1953. Sales in 1954 were 31 million pounds, valued at 
47 million dollars --about the same as in 1953. 

The output of benzenoid and naphthalenoid flavor and perfunne 
nnaterials in 1954 was 13 million pounds, an increase of 14.3 per- 
cent fronn the 11 million pounds reported for 1953. Methyl salicyl- 
ate (synthetic wintergreen oil) is the chemical in this group pro- 
duced in greatest volume; in 1954 production of this chemical 
totaled 2.9 million pounds--a decrease of 8.7 percent from the 
output in 1953. Sales in 1954 of benzenoid and naphthalenoid flavor 
and perfume materials as a group totaled 11 million pounds, valued 
at 14 million dollars, compared with 10 million pounds, valued at 
13 million dollars in 1953. 

In 1954 the output of terpenoid, heterocyclic, and alicyclic 
flavor and perfume materials was 9.1 nnillion pounds, compared 
with 7.3 million pounds, in 1953--an increase of 24.9 percent. In 
volume of production, the most important chemicals in this group 
were the alpha and beta terpineols; production of these materials 
in 1954 totaled 2.5 nnillion pounds--an increase of 23. 2 percent 
from the output reported in 1953. Sales of terpenoid, heterocyclic, 
and alicyclic materials as a group totaled 7.2 nnillion pounds, 
valued at 12.8 million dollars, in 1954, compared with 6.1 million 
pounds, valued at 8.7 million dollars in 1953. 

Production of acyclic flavor and perfume materials in 1954 
totaled 13.4 nnillion pounds--a decrease of 12.8 percent from the 
15.4 nnillion pounds produced in 1953. By far the most innportant 
nnaterial in this group in 1954 was monosodium glutamate, production 



SYNTHETIC ORGANIC CHEMICALS, 1954 41 

of which amounted to 12,8 million pounds, or about 95 percent 
(by weight) of the total output of acyclic perfume and flavoring ma- 
terials. Sales of acyclic perfume and flavoring materials in 1954 
totaled 12.6 million pounds, valued at 20. 5 million dollars, com- 
pared with 14.6 million pounds, valued at 25. 1 nnillion dollars, in 
1953. 

Plastics and Resin Materials 

The products covered in this section of the report are synthetic 
plastics and resin materials. These materials result from the con- 
densation or polymerization of organic chemicals together with 
other necessary additives. At sonne stage of their manufacture they 
pass through a plastic condition which renders them capable of be- 
ing formed and shaped by the application of heat and pressure. 
Some types of plastics may be molded, cast, or extruded into semi- 
finished or finished forms. Other types are used for adhesives, for 
the treatment of textiles and paper, and for protective coatings. 
Still other types are rolled or extruded into continuous sheets and 
film of varying thicknesses, which in turn are made into rainwear, 
shower curtains, wrapping materials, and other products. Except 
for the data on vinyl resins, which are shown on the basis of resin 
content, the statistics in the following tables are given on the basis 
of the total weight of the materials, excluding liquids. Cellulose 
products, which are derived primarily from natural raw materials, 
are not covered in this section (see appendix D). 

Statistics on the production and sales of plastics and resins are 
given in table 19A6 according to chemical composition, and in table 
20 according to broad end uses. In 1954, the total output of all syn- 
thetic plastics and resin materials (except cellulosics), amounted 
to 2,828 million pounds, or slightly more than the 2,777 million 
pounds reported for 1953. Sales in 1954 amounted to 2,497 million 
pounds, valued at 856 million dollars, compared with 2,372 million 
pounds, valued at 838 million dollars, in 1953. Production of cel- 
lulose plastics in 1954 (see table 30) was 123 million pounds. 

Total production in 1954 of benzenoid plastics and resins was 
1,588 million pounds, compared with 1,605 million pounds in 1953. 
Sales in 1954 were 1,331 million pounds, valued at 360 million dol- 
lars, compared with 1,317 million pounds, valued at 363 million 
dollars, in 1953. Of the benzenoid group, styrene resins were 
produced in the largest volume in 1954. Production of styrene 
resins in 1954 was 481 million pounds; sales were 458 million 
pounds, valued at 151 million dollars. These statistics are not 
strictly comparable with those for previous years. Some resins 
that formerly were classified as styrene resins are now included 
in the group of polyester resins; separate figures are given for 
these resins for the first time. Production of polyester resins, 
which are used principally in the production of reinforced plastics, 
was 49 million pounds in 1954. 

Phenolic and other tar-acid resins ranked second in volume of 
production in the benzenoid group in 1954, production amounting 
to 434 million pounds, a decrease of 5 1 million pounds from the 
485 million pounds reported for 1953. Sales of phenolic resins in 



^ See also table 19B, part III, which lists these products according to chemical com- 
position, and identifies the manufacturers. 



42 



TABLE 19A. --Synt/ieti 



UNITED STATES TARIFF COMMISSION 

ganic chemicals; United States production and sales of plastics and 
grouped according to chemical composition , 1954 



[Quantities and values are given In terms of the total weight of the materials (dry basis). Listed below 
are all synthetic plastics and resin materials for which any reported data on production or sales may be 
published. (Leaders are used where the reported data are accepted In confidence and may not be published 
or where no data were reported.) Table 19B in part III lists all plastics and resin materials for which 
data on production or sales were reported and identifies the manufacturer of each] 



Grand total- 



PLASTICS AND RESIN MATERIALS, BENZENOID 



Total 



Materials for which separate statistics may not be shown' - 
Materials for which separate statistics are shown below — 



Coumarone-indene and petroleum poller resins- 
Epoxy resins 



Phenolic and other tar-acid resins, total- 
Unmodified, total 

Bisphenol-formaldehyde 

p-tert-Butylphenol-bisphenol-formaldehyde- 

p-tert-Butylphenol-formaldehyde 

Cresols-formaldehyde 



Cresylic ac id-f ormaldehyde- 

Phenol-ionnaldehyde 

Phenol-furfural 

Resorc inol-f ormaldehyde 

All other 

Modified, total- 



B isphenol-f ormaldehyde-ros in 

p-tert-Butylphenol-formaldehyde-rosin 

Phenol-formaldehyde-aniline 

Phenol-formaldehyde-rosin 

Phenol-formaldehyde , sulfonated 

All other 



Phthalic alkyd resins, total 

Unmodified , total 

Phthalic anhydride-glycerol- 



Phthalic anhydride-glycerol-glycol 

Phthalic anhydride-glycerol-pentaerythritol 

Phthalic anhydride-glycerol-sorbitol 

Phthalic anhydride-glycol-pentaerythritol 

Phthalic anhydride-pentaerythritol 

All other 

Phthalic anhydride-adlpic acid -glycol 

Phthalic anhydride-benzole acid-glycerol 

Phthalic anhydride -fumaric acid-glycerol 

Phthalic anhydrlde-fumaric acld-glycerol-rosin 

Phthalic anhydride-glycerol-phenol-f ormaldehyde 

Phthalic anhydride-glycerol-phenol-f ormaldehyde-rosin 

Phthalic anhydride-glyoerol-pentaerythritol-phenol- 

f ormaldehyde-rosin 

Phthalic anhydride-glycerol-pentaerythrltol-rosin 

Phthalic anhydride-glycerol-rosin 

Phthalic anhydride-maleic anhydride-glycerol 

Phthalic anhydride-maleic anhydride-glycerol- 

Phthallc anhydride-maleic anhydride-glycerol- 

pentaerythritol-rosln 

Phthalic anhydride-maleic anhydride-glycerol-rosin 

Phthalic anhydride-maleic anhydride-pentaerythritol 

Phthalic anhydride-maleic anhydride-pentaerythritol-rosin 

or tall oil 

Phthalic anhydride-pentaerythrltol-rosin or tall oil 



dry basis' 
2,827,803 



Polyester resins 



1,588,180 



4,330 
1,583,850 



219,359 
18,390 



't33,678 



389,669 

157 

429 

7,361 

6,081 

9,100 

329,252 

1,271 

3,812 

32,206 

44,009 

7,545 

6,776 

4,868 

18,268 

297 

6,255 

382,367 



pounds , 
2,496,597 



1,330,509 



1,692 
1,328,817 



287,736 

126,446 

4,989 

36,925 

2,844 

44,910 

67,904 

3,718 

94,631 

198 

2,206 

2,610 

695 

5,135 

5,358 

3,058 

5,696 

24,331 

8,308 

6,976 

758 
1,362 
3,355 

3,691 
8,053 
12,791 

49,019 



216,462 

12,800 



392,089 



350,495 

121 

383 

6,686 

4,554 

2,214 

309,452 

488 

2,918 

23,679 

41,594 

7,720 

6,493 

3,346 

18,056 

78 

5,901 

205,986 



1.000 
dollars 
856,493 



837 
359,569 



20,042 

7,217 



100,751 



145,126 
52,961 
3,178 
12,615 

39,392 

31,550 

5,430 

60,860 

338 
425 

1,684 
4,889 

271 

2,968 

20,641 

5,124 

6,074 



632 
3,028 

2,339 
4,0^8 
8,399 



90,050 

63 

155 

2,328 

1,387 

681 

74,692 

156 

2,189 

8,399 

10,701 

1,633 

1,523 

1,054 

4,181 

54 

2,256 

61.828 



43,748 
16,995 
1,011 
4,516 

10,030 
9,417 
1,779 

18,080 

*"l54 
182 

599 
1,826 



606 
5,254 
1,648 



270 
856 

707 
1,305 
2,525 

18,542 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



43 



TABLE l9tL. --Synthetic organic chemicals: 
grouped according to 



United States production and sales of pla 
chemical composition, I9J4- -Continued 



Quantity 



Unit 
value ^ 



PLASTICS AND RESIN MATERIALS, BENZENO ID— Continued 



Styrene resins, totii 

Polystyrene 

Styrene-alkyd polyester resins, total 

Maleic anhydride-styrene 

Phthalic anhydride-glycerol-pentaerythritol-styrene- 

Phthalic anhydride-glycerol-styrene 

All other 

Styrene-butadiene copolymer 

Styrene-divinyl benzene copolymer 

All other styrene resins 



PLASTICS AND RESIN MATERIALS, NONBENZENOID 



Materials for which separate statistics may not be shovm' 
Materials for which separate statistics are shown below — 



Allcyd resins, except phthalic, total 

Unmodified, total 

Maleic anhydride-pentaerythritol 

All other 

Modified , total 

Fumaric acid-glyoerol-rosin or tall oil 

Fumaric acid-pentaerythritol-rosin 

Maleic anhydride-glyoerol-pentaerythritol-rosin 

Maleic anhydride-glycerol-rosin 

Maleic anhydride-pentaerythritol-rosin 

Maleic anhydride-pentaerythritol-tall oil 

All other 



Rosin and terpene adduct resins- 



Rosin and tall oil esters, unmodified total- 

Rosin-glycerol 

Rosin-pentaerythritol 

All other 



Silicone resins 

Urea and melamine resins, total 

Urea-formaldehyde type, total 

Butyl xirea-formaldehyde 

Urea-formaldehyde 

Melamine-formaldehyde type 

Vinyl and vinyl copolymer resins (resin content) , total — 

Polyvinyl chloride and copolymer resins (containing 50 

percent or more polyvinyl chloride) 

All other vinyl resins' 



1,000 
pounds, 

Iry basis' 
^81,037 



328,204 

9,297 

377 

1,098 

7,001 

821 

100,155 

22,795 

20,586 



1,239,623 



458,037 

317, 2-^ 

7,280 

"78 
6,351 
851 
93,114 
22,395 
18,004 



1,166,088 



1,000 
dollars 

151,189 



3,335 
3,401 

22 

3,075 

304 

32,596 

10,275 

6,582 



313,926 
925,697 



71,234 



18,185 
635 
17,550 
53,049 
2,676 
7,428 
1,210 
16,325 
18,419 
4,080 
2,911 

6,945 

56,869 



289,412 
876,676 



53,411 



16,550 

542 

16,008 

36,861 

1,867 

2,448 

984 

14,831 

14,104 

199 

2,428 

6,940 

55,705 



179,056 
317,031 



16 ,423 



8,095 

111 

7,984 

8,328 

419 

780 

204 

3,258 

2,893 

30 

744 



21,694 
16,353 
18,822 

1,851 

265 . 193 



20,811 
15,695 
19,199 

1,705 

244.633 



3,699 
2,432 
2,965 

5,548 

73,669 



197,549 
13,810 

183,103 

636 

67,644 

523,605 



180,782 

9,180 

170,941 

661 

63,851 

514,282 



396,919 
78,534 



45,569 



397,194 
71,519 



43,076 

3,756 

38.996 

324 

30,593 

210,666 



16,392 



149,238 
45,036 



.28 
.48 
.36 



.16 
.18 



.63 



^ Calculated on rounded figures. 

^ Dry basis, for the purpose of this report, is defined as the total weight of the material, including 
resin, plasticizers, fillers, extenders, colors, and stabilizers, and excluding water, solvents, and other 
liquid diluents, 

^ Includes data for aniline-formaldehyde, toluenesulfonamlde, and other benzenoid plastics and resin 
materials. 

' Polyester resins, for the purposes of this report, include unsaturated aliyds. copolymerized with 
monomers such as styrene, and polyallyl resin such as diallyl phthalate or allyl diglycol carbonate. Data 
for styrene-alkyd polyesters for protective coatings are not included in this group. 

' Includes data for acrylic, polyamide, polyethylene, and other nonbenzenoid plastics and resin materials. 

' Includes some data for copolymers of polyvinyl oh-\oride and polyvinyl acetate which are included in 
table 20 in the statistics for polyvinyl chloride and copolymers. 

' Includes data for polyvinyl alcohol, butyral and formal, and for copolymers containing less than 50 
percent polyvinyl chloride. 



44 



UNITED STATES TARIFF COMMISSION 



TABLE 20. --Synthetic organic cheaicala: United States production and sales of plastics and resin materials, 
grouped according to classes and uses, 1954 

[ In thousands of pounds, dry basls^] 



Phenolic and other tar acid resins: 

Molding materials 

Bonding and adhesive resins for — 

Laminating (except plywood) 

Coated and bonded abrasives 

Friction materials (brake linings, clutch facings, etc.) 

Thermal insulation (rock wool, fiber glass) 

All other bonding and adhesive uses 

Protective-coating resins, unmodified and modified, except by rosin 
Resins for all other uses 

Urea and melamlne resins: 

Textile-treating and textile-coating resins 

Paper-treating and paper-coating resins 

Bonding and adhesive resins for — 

Plywood 

All other bonding and adhesive uses, including laminating 

Protective-coating resins, straight and modified 

Resins for all other uses, including molding 

Styrene resins: 

Mold ing materials 

Protective-coating resins, straight and modified^ 

Resins for all other uses 



Vinyl and vinyl copolymer resins (resin content), total — - 



Polyvinyl chloride and copolymer resins (50 percent or more polyvinyl 
chloride) for — 

Film (under 0.010 gage) 

Sheeting (0.010 gage and over) — 

Molding and extrusion 

Textile- and paper-treating and coating 

Protective coatings 

All other vinyl resins for — 

Adhesives 



All other uses 

Alkyd resins: 

For protective coatings: 
Phthallc anhydride types: 

Unmodified 

Modified 

Polybasic acid types: 

Unmodified 

Modified 

For all other uses 

Rosin modifications: 

Rosin esters for protective 

Unmodified (ester gums) 

Modified (hard resins) 

All other modifications for protective coatings and other uses- 

Coumarone-indene and petroleum polymer resins 

Polyester resins: 

For reinforced plastics 

For all other uses- 



atlngs: 



Miscellaneous synthetic plastics and resins:' 
Molding materlals- 



Protective-eoating resins- 
Resins for all other uses- 



182,135 

63,8«1 
10, 161 
15,692 
35,6^3 
35,125 
13,000 
22,970 
29, U5 

U,352 
20,567 

79,835 
25,290 
27,839 
67,311 

325,910 
83,215 
71,910 



286,751 
9-i,292 

15,6^ 
13,322 
5,448 



37,591 

54,959 

33,021 

219,358 

35,680 
13,695 

200,065 
21,008 
129, 160 



171,833 

43,447 
11,032 
U,876 
36,873 
28,335 
12,955 
21,644 
26,631 

38,640 
19,672 

74,855 
23,842 
21,603 
66,041 

309,204 
80,420 
68,416 

514,282 



68,818 
54,708 
146,605 
48,395 
34,497 
23,372 
33,998 

28,456 
75,433 



144,731 
61,618 

14,476 
3,017 
2,472 



35,902 

51,805 

32,616 

216,461 

31,441 
12,228 

167, 132 
13,331 
134, 113 



^ Dry basis, for the purpose of this report, is defined as the total weight of the material. Including 
resin, plasticizers, fillers, extenders, colors, and stabilizers, and excluding the weight of water, 
solvents, and other liquid diluents. 

' Includes data for styrene-alkyd polyester resins. 

' Includes data for acrylic, epichlorohydrin, polyamlde (nylon), polyethylene, silicone, and other syn- 
thetic plastics and resin materials. 

Note. — The figures In the above table are based on the Commission's monthly reports on the production 
and sales of synthetic plastics and resin materials. They are partially estimated, and may not be correlated 
exactly with those given in table 19A. The data given in the above table are In substantial agreement with 
those given in the Commission's release for January 1955 which gave a summation of the data reported by 
months for 1954. Changes in classification and a minor Increase in coverage on some products result in some 
differences in the detail figures given in this table from those given In the January 1955 report. 



1954 were 392 million pounds, valued at 101 million dollars. The 
phthalic alkyd resins, used principally in the manufacture of pro- 
tective coatings, were third in volume of production in the benze- 
noid group in 1954; the total output was 382 million pounds. Sales 
of these resins in 1954 amountedto 206 million pounds, valued at 62 
million dollars. 



SYNTHETIC ORGANIC CHEMICALS, 1954 45 

Production of nonbenzenoid plastics and resin materials in 1954 
amounted to 1,240 million pounds, compared with 1,171 million 
pounds in 1953. Sales in 1954 were 1,166 million pounds, valued at 
496 million dollars, compared with 1,055 million pounds, valued at 
475 million dollars, in 1953. Of the nonbenzenoid group, the vinyl 
resins were produced in the largest volume in 1954, as they have 
been in the last several years. Production of these resins in 1954 
was 524 nnillion pounds --slightly more than the 516 million pounds 
reported for 1953. Sales of vinyl resins in 1954 were 514 million 
pounds, valued at 2 1 1 million dollars, compared with 464 million 
pounds, valued at 199 million dollars, in 1953. Production in 1954 
of urea and nnelamine resins, which ranked second in volume of 
production in the nonbenzenoid group, amounted to 265 million 
pounds, compared with the 257 million pounds reported for 1953. 
Sales of these resins in 1954 totaled 245 million pounds, valued at 
74 million dollars. Other important nonbenzenoid plastics and res- 
ins, data for which are included in this report, are polyethylene, 
acrylic, and polyamide. 

Statistics on the production and sales of plastics and resins by 
uses, given in table 20, are compiled for the most part fronn the 
Tariff Commission's nnonthly surveys on the production and sales 
of synthetic plastics and resin materials. The largest single use 
for plastics and resin materials in 1954, as in 1953, was for mold- 
ing and extruding into finished and semifinished forms. Other im- 
portant uses were for the manufacture of sheeting and film, for the 
treatment of textiles and paper, for adhesives, and for protective 
coatings. 

Rubber-Processing Chemicals 

Rubber -processing chemicals are organic compounds added to 
natural and synthetic rubbers to give them qualities necessary for 
their conversion into finished rubber goods. In this report, statis- 
tics are given for cyclic and acyclic compounds by use- -such as 
accelerators, antioxidants, and peptizers. Statistics on the produc- 
tion and sales of rubber -processing chemicals in 1954 are given in 
table 21 A.''' 

Production of rubber-processing chemicals as a group in 1954 
amounted to 130 million pounds--a decrease of 10.3 percent from 
the 145 million pounds reported for 1953. The decrease in the 
production of rubber -processing chemicals resulted from the de- 
creased consumption of rubber in 1954. Sales in 1954 of rubber- 
processing chemicals were 101 million pounds, valued at 62 mil- 
lion dollars, connpared with 103 nnillion pounds, valued at 60 
million dollars, in 1953. 

The output of cyclic rubber-processing chemicals in 1954 
amounted to 110 million pounds, or 9. 6 percent less than the 122 
million pounds reported for 1953. Sales in 1954 were 85 million 
pounds, valued at 51 million dollars, compared with 85 million 
pounds, valued at 48 million dollars, in 1953. Included in this re- 
port also are statistics for the dithiocarbamic acid and benzothia- 
zole derivatives that are used as accelerators. Of the total produc- 
tion of cyclic rubber-processing chemicals in 1954, accelerators 



^ See also table 21B, part III, which lists these products alphabetically and identifies 
the manufacturers. 



46 



UNITED STATES TARIFF COMMISSION 



TABL£ 21k. •"Synthetic organic chemicaia: United Statea prothiction and aalea of 
rubber •pToceaaing chetaicala , 1954 



I 



[Listed belov are all rubber-processing chemicals for which any reported data on production or sales may be 
published. Table 21B in part III lists separately all rubber-processing chemicals for which data on produc- 
tion or sales were reported and identifies the manufacturer of each] 



Produo- 
tlon 



^lantlty 



Unit 
value ^ 



Qrand total- 



RUBBER-PROCESSINQ CHIMICALS, CYCLIC 



Accelerators, total 

n-Butyraldehyde-aniline- 
Dithlocarbamlc acid derivatives- 
Thlazole derivatives, total 



2,2'-Dithlobls[benzothlazole] (2,2'-Benzothiazyl disulfide) 

2-Mercaptobenzothlazole 

All other 

All other accelerators 



Antlojiidants, total- 

Amino or hydroxy compounds - 
All other 



Peptizers, taeklf lers. Inhibitors, and blowing agents- 
RUBBER-PROCESSDIO CHIMICAI^, ACYCLIC 



Accelerators, total- 



Dlthlooarbamlo acid derivatives, total^- 
Dlbutyldithlocarbamic acid, zinc salt- 



Diethyldithiocarbamic acid, zinc salt 

Dljnethyldithlocarbamlc acid, potassium salt — 

Dimethyldithlocarbamic acid, sodium salt, and sodium polysulf ide- 
All other- 



Tetramethylthluram sulfides, total''- 

Tetramethylthluram disulfide 

Tetramethylthluram monosulfide 

All other* 



Peptizers, lubricating, conditioning, and blowing agents, total 

Dodecyl mereaptana 

All other 



t.ooo 

pound. 
129,925 



109,868 



53,316 



255- 

203 
47,006 
U,725 
11,873 
20,«)8 
5,852 

51, -122 



24,628 
26,794 



5,130 



20,057 



654 
1,522 

2,583 
1,395 
4,770 
3,915 
855 
3,324 

5,809 



3,843 
1,%6 



1,000 
pounds 
101,466 



62,361 



85,134 



50,555 



31,520 

ili 

193 
24,817 
10,617 

3,872 
10,328 

6,264 

48,315 



23,092 
25,223 



5,299 



16,332 



17,237 

IZT 

368 
12,022 
5,017 
1,491 
5,514 
4,701 

28,249 



u;iM 

14,141 



5,069 



U,806 



10,907 



9,006 



37804 
746 

1,436 
119 

1,503 
4,170 
3,346 
824 
2,933 

5,425 



3,638 

1,787 



3,145 

691 

1,238 

57 

1,159 
4,291 
3,363 
928 
1,570 

2,800 



1,934 
866 



pound 

♦0.61 



.59 



.55 

1.91 
.48 
.47 
.39 
.53 
.75 

.58 



.83 

.93 
.86 
.48 

!77 
1.03 
1.01 
1.13 

.54 

.52 



- Calculated on rounded f'j'ires. 

2 Data on dithlocarbamates lr,cluded in this table are for material used exoluflively In the processing of 
natural and synthetic rubbers . Data on dithiocarbainates which are used as fungicides are reported In the sec- 
tion "Pesticides and Other Organic Agricultural Chemicals." 

^ Includes data for small amounts of tetramethylthluram sulfides for uses other than In the processing of 
natural and synthetic rubbers. 

* Includes a small amount of tetraethylthlxiram disulfide. 

accounted for about 49 percent, antioxidants, for 47 percent, 
and other uses, for about 4 percent. 

Production of acyclic rubber -processing chemicals in 1954 
announted to 20. 1 million pounds, compared with the 23. 3 million 
pounds reported for 1953. Sales in 1954 were 16.3 million pounds, 
valued at 11.8 million dollars, compared with 17.7 million pounds, 
valued at 12. 5 million dollars, in 1953. Accelerators, principally 
dithiocarbamic acid derivatives and tetramethylthiuram sulfides, 
accounted for approximately 71 percent of the production of acyclic 
rubber-processing chemicals in 1954. Peptizers and modifiers-- 
chiefly dodecyl mercaptans, together with lubricating, condition- 
ing, and blowing agents --accounted for approximately 29 percent 
of the output in the acyclic group. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



47 



Elastomers (Synthetic Rubbers) 

The total output of elastomers (synthetic rubbers) in 1954 
amounted to 1,435 million pounds--a decrease of 26.7 percent 
from the 1,958 million pounds reported for 1953. Sales in 1954 
were 1,497 million pounds, valued at 436 million dollars, com- 
pared with 1,909 million pounds, valued at 529 million dollars, 
in 1953. Statistics on the production and sales of elastomers are 
given in table 22A.^ 



TAELE 22A.- -Synthetic organic chemicals: United States product! 
(synthetic rubbers),^ 1954 



and sales of elastomers 



[Listed below are all synthetic elastomers for which reported data on production or sales may be published. 
Table 22B In part III lists alphabetically all elastomers for which data on production or sales were re- 
ported and Identifies the manufacturer of each] 



Produc- 
tion 



Sales 



Quantity 



Value Unit value' 



Qrand total- 



1,000 

pounds 

l,'i>4,%2 



1,496,527 



1.000 
dollars 
-135,958 



per 
pound 
J0.29 



ELASTOMERS, C^nH-IC 



Polybutadiene-atyrene type (Buns S, CH-S), total- 
S-type rubber, produced at GoTemment planta- 



973, 2A9 



S-type and modifications produced at private plants- 
ELASTOMERS, ACTTCLIC 



Products for which separate statistics may not be shown*- 
Products for which separate statistics are shown below — 



Polybutadiene-acrylonitrlle type (N-type) 
Polychloroprene type (Neoprene, CR-M)- 



966,813 
6,<;36 



461,713 



1,022,276 
6,249 



468,002 



242,419 



238,504 
3,915 



193,539 



23,792 
437,921 



22,557 
445,445 



15,871 
177,668 



Polylsobutylene-lsoprene type (Butyl, CE-I)- 
Polyvlnyl type* 



47,933 
154,899 

130,116 
104,973 



46,508 
155,154 
139,485 
104,298 



23,262 
65,165 

31,195 
58,046 



^ An elastomer is defined as a material which can be stretched repeatedly to 150 percent or more of normal 
length and will return rapidly and with force to Its approximate original state. 

' Calculated on rounded figures. 

' Includes data for chlorinated and cyclo rubbers, polyurethane foams, and thlokol, silicone, and poly- 
Isobutylene elastconera. 

* Includes data for polyvinyl alcohol, butyral, and chloride elastomers. 

Note. — Statistics on production and sales of Cffi-S and CE-I rubbers for Government account are as reported 
to the Federal Facilities Corporation. Sales for N-type and neoprene rubbers were calculated from data on 
consumption, inventories, and published prices. All other data are as reported to the n. S. Tariff Com- 
mission. 



Production in 1954 of cyclic elastomers, consisting entirely of 
the polybutadiene-styrene type (Buna S, GR-S), amounted to 973 
million pounds, or 31.2 percent less than the 1,415 million pounds 
reported for 1953. Sales of GR-S in 1954 totaled 1,029 million 
pounds, valued at 242 million dollars, compared with 1,387 mil- 
lion pounds, valued at 319 million dollars, in 1953. The major 
portion of the output of the GR-S type synthetic rubber in 1954 was 
produced in Government-owned plants for the account of the Fed- 
eral Facilities Corporation. GR-S rubber is used principally in 
the manufacture of pneumatic -tire casings. 



* See also table 22B, part III, which lists these products alphabetically and identifies 
the manufacturers. 



48 UNITED STATES TARIFF COMMISSION 

The output of acyclic elastomers in 1954 amounted to 462 nnil- 
lion pounds, compared with 543 million pounds in 1953. Sales in 
1954 were 468 nnillion pounds, valued at 194 million dollars, com- 
pared with 522 million pounds, valued at 210 million dollars, in 
1953. The acyclic group of elastomers includes oil-resistant types 
such as neoprene, and other special-purpose types such as butyl, 
or GR-I, rubber (used in the manufacture of inner tubes for tires), 
and vinyl and silicone elastonners. 

Plasticizers 

Plasticizers are organic chemicals that are used in the manu- 
facture of plastics and resin materials to impart essential proper- 
ties to the materials so that they may be adapted to various appli- 
cations. Statistics on the production and sales of plasticizers in 
1954 are given in table 23A.^ 

The output of all plasticizers in 1954 totaled 301 million 
pounds --a slight increase over the 293 million pounds reported 
for 1953. Sales in 1954 totaled 247 million pounds, valued at 82 
million dollars, compared with 235 million pounds, valued at 83 
million dollars, in 1953. 

Production of cyclic plasticizers in 1954 amounted to 228 mil- 
lion pounds, compared with 224 million pounds in 1953. The cyclic 
plasticizers group consists chiefly of the esters of phosphoric acid 
and phthalic anhydride. Sales of cyclic plasticizers in 1954 were 
186 million pounds, valued at 57 million dollars, compared with 
180 million pounds, valued at 60 million dollars, in 1953. In 1954, 
as in 1953, production of the phthalic anhydride esters, which are 
essential in the processing of vinyl resins, was the largest in the 
cyclic group. Production of phthalic anhydride esters in 1954 was 
171 million pounds; sales were 134 million pounds, valued at 41 
million dollars. 

Production of acyclic plasticizers in 1954 totaled 73 million 
pounds, compared with 69 million pounds in 1953. This group con- 
sists of the esters of adipic, lauric, oleic, phosphoric, sebacic, 
stearic, and other acids. Sales of acyclic plasticizers in 1954 were 
62 million pounds, valued at 25 million dollars, connpared with 55 
million pounds, valued at 23 million dollars, in 1953. Of the 
acyclic plasticizers, the oleic acid esters were produced in the 
largest volume. 

Surface -Active Agents 

The surface -active agents covered in this report include syn- 
thetic organic detergents, wetting agents, and emulsifying agents; 
soaps are not included. As the data are given in terms of 100-per- 
cent active nnaterial, they exclude all inorganic salts, water, and 
other diluents. 

Although they were originally developed as soap substitutes, 
surface -active agents have proved valuable in many other applica- 
tions because of their varied and specific properties. Because they 
do not form insoluble precipitates, as some soaps do, they are 
especially valuable as detergents in hard water. For certain 



^ See also table 23B, part III, which lists these products alphabetically and identifies 
the manufacturers. 



I 



SYNTHETIC ORGANIC CHEMICALS, 1954 



49 



TABLE 23A. --Synthetic organic chemicals: United States production and sales of plasticizers,1953 

[Listed below are all plasticlzers for which reported data on production or sales may be published. (Leaders 
are used where the reported data are accepted in confidence and may not be published or where no data 
were reported.) Table 23B in part III lists all plasticlzers for which data on production or sales were 
reported and identifies the manufacturer of each] 



Produc- 
tion 



IJuantlty 



Unit 
valuB^ 



Grand total— 



PLASTICIZERS, CYCLIC 



Chemicals for which separate statistics may not be shown' 
Chemicals for which separate statistics ere shown below— 



Riosphorlo acid esters: 
Trlcresyl phosphate'— 
Triphenyl phosphate— 



Phthallc anhydride esters, total- 
Dibutyl phthfllate- 



Dlcapryl phthalat o 

Diethyl phthalat o 

Di(2-^n9thoxyethyl)pht.hHl ate (Di(methylcellosolve) phthalate)- 

Dimethyl phthalate- 



Dioctyl phthalates, total- 



Dl(2-ethylhexyl) phthalate- 



Dl-n-ootyl, dilso-ootyl, and mixed octyl phthalates- 
Octyl decyl phthalat o 
Ai 1 other 



PLASTICIZERS, ACYCLIC 



Chemicals for which separate statistics may not be shown*- 
Chemlcals for which separate statistics are shown below— 



Mlplc acid esters, totals 
Dl(2-ethylheKyl) adlpats- 
Dllso-octyl adipat o 
All other 



Laurie acid esters- 



Olelo aold esters, total- 



Cilyceryl trioleate (Trloleln)'- 
All other 



Phosphoric acid estera- 



Sebaoic acid esters, total — 
Dlbutyl sebacat o 
Dl(2-ethylhexyl) sebacate- 
All other 



Stearic aold esters. 
Butyl stearate— 
All other 



1.000 



300,674 



227,618 



26,735 
200,883 



23,847 
6,426 



170,610 



19,876 
5,832 
15,999 
2,098 
2,557 
88,224 
54,067 
34,157 
10,060 
25,964 



36,722 
36,334 



2,710 

884 

3,443 



4,054 
6,031 



6,122 
6,566 



1,950 

4,076 

540 



3,647 
2,822 



1.000 
pounds 

247,445 



i.OOO 
dollars 
81,997 



185,781 



56,993 



23,747 
162,034 



7,326 
49,667 



24,553 
3,454 

134,027 

13,897 

5,831 

10,141 

2,328 
68,423 
41,471 
26,952 

9,907 
23,500 



61,664 



7,740 
1,255 



40,672 



3,685 
1,713 
2,492 

598 
20,550 
12,494 
8,056 
3,213 
8,421 



23,004 



31,279 
30,385 



12,332 
12,672 



1,536 
1,221 
2,420 



2,390 



4,237 
3,770 



5,571 
5,446 



666 

552 
1,172 

26 

2,675 



967 

3,812 

667 



1,123 
1,552 



2,439 
3,685 



676 

2,428 

581 



"3;55f 
2,562 



730 
727 



$0.33 



.28 



^ Calculated on rounded figures. 

Includes data for synthetic camphor, certain phosphoric acid esters, toluenesulf onamldes , tetrahydrofur- 
furyl oleate, and other cyclic plasticlzers. 

' Includes data for material reported for use as motor-fuel additivs. 

Includes data for citric and acetylcltrio, palmitic, azelalc, tartaric, and riclnolelc acid esters, and 
for butyl myrlstate, glyceryl and glycol esters of certain fatty acids, glyceryl triproplonate, and conplex 
polymeric plasticlzers . 

Includes data for material reported for ubq as a surface-active agent. 



industrial purposes, surface -active agents are used as emulsifying 
and wetting agents for agricultural, leather, and textile chemicals. 
They are also used in dentifrices and shampoos. 

Statistics on production and sales of surface -active agents in 
1954 are given in table 24A. ■'■^ In 1954 production of surface -active 



See also table 24B, part III, which lists these products alphabetically and identifies 
the manufacturers. 



50 



UNITED STATES TARIFF COMMISSION 



TAHI.E 24A. --Synf/iefic organic chemicals: United States production and sale 



ijr face-active agents,^ 195A 



[Listed below are all surface-active agents for vfhloh reported data on production or sales may be published. 
(Leaders are used where the reported data are accepted In confidence and may not be published or where no 
data were reported. ) Table 2'iB In part III lists all surface-active agents for which data on production or 
sales were reported and identifies the manufacturer of each] 



Production 



Quantity 



Grand total — 



SURFACE-ACTIVE AGENTS, CYCLIC 



Esters and ethers, nonsulf onated , total^ 

Nonylphenoxy polyethoxyethanol 

All other 

Nitrogen-containing surface-active agents, nonsulf onated, 

total* ' — 

Benzyllauryldimethylanrmonium chloride 

All other 

Sulfated and sulfonated cyclic surface-active agents, total — 

Alkyl benzenold compounds, sulfated and sulfonated, total — 

Dodecylbenzenesulfonlc acid type 

Lignln derivatives, sulfonated, total — 



Naphthalene derivatives, sulfonated, total 

Butylnaphthalenesulfonic acid, mono and di 

Diamylnaphthalenesulfonlc acid 

Isopropylnaphthalenesulfonic acid, mono and di 

All other 

Petroleum aromatic compounds , sulfonated , total 

Acid-layer-type petroleum sulfonate, sodium salt 

Oil-layer-type petroleum sulfonate, sodium salt 

All other 

All other sulfated and sulfonated cyclic surface-active 
agents' 

SURFACE-ACTIVE AGENTS, ACYCLIC 



Total- 



Esters and ethers, nonsulf onated , total' - 

Dlethylene glycol monolaurate 

Diethylene glycol mono-oleate 

Dlethylene glycol monostearate 

Glyceryl mono-oleate — 

Glyceryl monostearate 

Polyethoxyethyl dilaurate 

Polyethoxyethyl dioleate- 



Polyethoxyethyl dlstearate 

Polyethoxyethyl monolaurate 

Polyethoxyethyl mono-oleate 

Polyethoxyethyl monostearate 

1,2-Propylene glycol monostearate- 
All other 



Nitrogen-containing surface-active agents, nonsulf onated, 

N-CAmlnoethyl)-N-(hydroxyethyl)stearamide (Stearamide of 

aminoethylethanolamlne ) 

Coconut oil amide of mono(dlethanolamlne) (Dlethanol 

lauramide ) 

Coconut oil amide of bis(dlethanolamine) 

Coconut oil amide of dlethanolamlne. neither mono nor bis- 

Coconut oil amide of diethylenetriamlne 

N,N-Di(2-hydroxyethyl5oleamide (Dlethanol oleamide) 

(Dlethanolamlne oleate ) 

N,N-Dl(2-hydroxyethyl)stearamide (Dlethanol stearamide) 

Stearamide of diethylenetriamlne 

All other' 



Phosphorus-containing surface -active agents, nonsulf onated— 

Salts of fatty acids, nonsulf onated, total 

Coconut oil, potassium salt 

Potassium laurate 

Potassium oleate 

Potassium stearate 

Potassium tallate 



1,025,836 



5,350 
36,739 



7,215 



1,176 
6,039 



590.918 



388,959 

386,243 

2,716 

39,352 

7,332 

842 

61 

2,254 

4,175 

142,782 

2,182 

84,723 

55,877 

12,493 



88,478 



1,250 

5,573 

1,974 

1,890 

154 

962 

706 

408 

43,860 

586 

21,129 



115 

626 

36 

764 



1,000 
pounds 
913,274 



196,433 



577,022 



35,001 
6,205 
28,796 



11,998 



1,036 
3,827 

537,158 



1,665 
10,333 



4,099 
326" 



628 


505 


176 


515 


462 


156 


883 


598 


164 


2,070 


2,001 


682 


11,971 


10,949 


3,022 


278 


271 


110 


161 


156 


56 


84 


74 


30 


426 


287 


107 


1,102 


787 


294 


2,836 


2,616 


1,021 


566 


532 


152 


66,958 


61,967 


14,256 



382,291 

379,558 

2,733 

38,732 

4,607 

1,024 

60 

2,177 

1,346 

97,150 

63,755 
33,395 

14,378 



336,252 



81,205 



55,404 



1,223 

5,245 

1,515 
1,812 



940 

578 

387 

43,704 

899 

21,659 



36 

115 
423 



104.241 

82,268 

780 

2,176 

1,659 

625 

32 

817 

185 

13,934 

8,655 
5,279 



76,095 



20,226 



17,788 



1,270 

2,067 
600 
732 



376 

260 

246 

12,237 

570 

2,166 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



51 



TABU 2*k.- 'Synthetic orfanic chemical*: United Slate* protection and aalea of aur face-act iva a4enta,' 1934- 

Continued 



SURFACE-ACTIVE AQENTS, ACYCLIC— Continued 

Salts of fatty acids, nonsulfonated— Continued 

Sodium stearate — -— 

All other 

Sulfated and sulfonated acyclic surface-active agents, total — 

Acids, sulfated and sulfonated, total 

Oleic acid, sulfonated (Sulfonated red oil) 

All other 

Alcohols and esters , sulfated and sulfonated , total 

Lauryl sulfate, sodium salt 

Lauryl sulfate, trlethanolamlne salt — — 

Isopropyl sulfo-oleate '■ ■ ■'- ■ 

n-Propyl sulfo-oleate 

All other 

Nitrogen-containing surface-active agents, sulfated and 

Coconut oil amide of monoethanolamlne, sulfated, potassium 

Coconut oil amide of monoethanolamlne, sulfated, sodium 

All other , 

Oils, fats, and wajces. sulfated and sulfonated, total 

Animal fats and oils, sulfated and sulfonated: 

Qrease other than wool grease, sulfonated 

Neat's-foot oil, sulfonated 

Tallow, sulfonated 

Fish and marlne-anlmal oils, sulfated and sulfonated: 

Cod oil, sulfonated 

Sperm oil, sulfonated 

Vegetable oils, sulfated and sulfonated, total 

Castor oil, sulfonated 

Coconut oil, sulfonated 

Com oil, sulfonated — — 

Peanut oil, sulfonated -— 

Rice-bran oil, sulfonated 

Soybean oil, sulfonated 

All other oils, fats, and waxes, sulfated and sulfonated' — 



Production 



1,000 
poundt 

702 
18,850 

218, 6U 



3,665 

2,358 

1,307 

129,503 

16,207 

2,674 

809 

1,655 

108,158 

8,566 



298 
8,159 
76,910 

3,207 
1,389 
11,750 

16,781 

5,-133 

493 

U,205 

9,613 

294 

205 

1,806 

986 

406 

895 

23,652 



Quantity 



1.000 
pound* 
712 
19,627 



177.085 
3,574 
2,016 
1,558 

127,854 

16,015 

2,317 

790 

1,523 

107,209 

4,863 



288 
4,468 
40,794 



1,271 
10,070 

3,006 
2,221 

497 
10,839 
7,939 

198 

1,590 

264 

374 

474 

12,890 



1,000 
toiler. 



222 
1,693 



35,345 



1,168 

673 

495 

25,438 

5,807 

774 

398 

336 

18,123 

1,952 



245 
1,610 
6,787 



268 
1,269 

411 

439 

98 

2,156 

1,360 

49 



U2 

103 

2,146 



Unit 
value^ 



Ptr 
pound 

t0.31 
.09 



1 Data are given In terms of bulk surface-active agents, that is. In terms of 100 percent content of 
surface-active agents, exclusive of all Inorganic salts, water, or other ingredients. 

^ Calculated on rounded figures. 

' Includes polyhydrlc alcohol ethers and esters. 

^ Includes quaternary ammonium compounds. 

' Includes sulfated and sulfonated phenyl ethers and substituted blphenyls. 

' Includes certain laurlc, oleic, and stearic acid esters reported as plastlclzers prior to 1953. 

' Includes amine salts of fatty acids, esters of hydroxyamlnes , fatty acid amines, quaternary ammonium 
compounds, salts of nitrilo acids, and fatty acid derivatives of guanidlne, glycine, polypeptides, and others. 

' Includes sodium salt of petroleum sulfonate, sulfonated synthetic Japan wax, sulfonated recovered grease, 
sulfonated lard oil, sulfonated wool grease, and other animal and fish oils. 



agents as a group totaled 1,026 million pounds, or 11.3 percent 
more than the 922 million pounds reported for 1953. Sales in 1954 
were 913 million pounds, valued at 196 million dollars, compared 
with 732 million pounds, valued at 145 million dollars, in 1953. 

In 1954 the production of anionic surface -active agents (sulfated 
and sulfonated cyclic and acyclic compounds and acyclic salts of 
fatty acids) amounted to 831 million pounds, or approximately 80 
percent of the total amount of surface -active agents produced. 
This quantity was 79 million pounds more than the output in 1953. 
Sales in 1954 totaled 736 million pounds, valued at 141 million 
dollars, compared with 580 million pounds, valued at 93 million 
dollars in 1953. In volume of production, the principal items 
produced in the anionic group in 1954 were the following: Thedodecyl- 
benzenes ulfonic acidtype of surface-active agent (386 million pounds); 



52 



UNITED STATES TARIFF COMMISSION 



sulfonated petroleum aromatic compounds (143 million pounds); and 
sulfated and sulfonated alcohols and esters (130 million pounds). 

Pesticides and Other Organic Agricultural Chemicals 

Pesticides (insecticides, herbicides, rodenticides, and fungi- 
cides) and other organic agricultural chemicals such as seed dis- 
infectants, plant hormones, fumigants, and soil conditioners are 
covered in this section. As in other sections of this report, the 
data (except where otherwise indicated) are given in terms of 100- 
percent active material, thus excluding such materials as wetting 
agents, emulsifiers, and diluents. Statistics on production and 
sales of pesticides and other organic agricultural chemicals in 
1954 are given in table ZBA.-'^-'- 



TABLE 25A. -Syntheti 



orjaiic chemicals: United States production and sale 
agricultural chemicals, 1954 



of pesticides and other organic 



[Listed below are all pesticides and other organic agricultural chemicals for which any reported data on 
production or sales may be published. (Leaders are used where the reported data are accepted in confidence 
and may not be published or where no data were reported.) Table 25B in part III lists all pesticides and 
other organic agricultural chemicals for which data on production or sales were reported and Identifies 
the manufacturer of each] 



(iiairtlty 



Unit 
value ^ 



1,000 
pounds 
A19,27A 



335,999 



12A,501 



PiSTICIDES AND OTHER ORGANIC AQRICULTURAL CHEMICALS, CTCLIC 

Total 

Fungicides and seed disinfectants, total _— 

Naphthenic acid, copper salt- 

Phenyl mercuric oleate 

8-Qiinolinol (8-Hydroxyquinoline), copper salt— — 

2,<4,5-Trichlorophenol 

2,4,5-Triohlorophenol, sodium salt 

All other 



357,533 



279,103 



102,145 



57,993 



Herbicides and plant hormones, total 

Naphthalene and naphthoxyacetic acid derivatives 

Phenoxyacetio acid, salts, and derivatives: 

(2,4-Dichlorophenoxy)acetic acid (2,4-0) 

(2,4-Dichlorophenoxy)acetic acid esters, total 

n-Buty 1 2 , 4-dlchlorophenoxyacetate 

sec-Butyl 2,4-dichlorophenoxyaoetate 

Isopropy 1 2 , 4-dichlorophenoxyacetate 

All other 

(2,4— r>lchlorophenoxy)acetic acid salts 

(2,4,5-Trichlorophenoxy)acetic acid (2,4,5-T) 

(2,4,5-Trichlorophenoxy)acetic acid esters 

Phenyl mercuric acetate 

Inseotic ides, total— 

Hexachlorocyclohexane (Benzene hexachloride)^ 

Parathion (0,0-Diethyl O-(p-nltrophenyl) phosphorothionate ) 

l,l,l-Trichloro-2,2-bis(p-chloropheryl)ethane (DDT) 

All other* 

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHIMICALS, ACTCLIC 
Fumigants , total 



3,557 
142 

2,785 
2,018 
49,491 

64,013 



43,393 
32,084 



30,184 
16,994 
2,394 

6,005 
8,595 
5,642 
2,697 
3,883 
598 
4,015 

235,527 



"TT 

10,665 
8,647 
2,321 
1,111 
2,212 
3,003 
6,534 
1,409 
1,356 
525 
2,936 

200,312 



19,454 
22,778 



76,934 

3,889 

97,198 

57,506 



61,741 



53,339 
4,905 
91,548 
50,520 



56,896 



"5T 

5,189 
4,570 
1,036 
452 
1,304 
1,778 
2,568 
1,610 
1,757 
2,878 
4,147 

58,926 
5,891 
6,494 
21,603 
24,938 



22,356 



.71 



.59 
.39 

1.14 
1.30 
5.48 

1.41 



.29 

.11 

1.32 

.24 

.49 



Fungicides, seed disinfectants, herbicides, and insecticides. 

Fungicides and seed disinfectants: 

Dimethyldithiocarbamic acid, sodium salt 

Dlmethyldithiocarbamic acid, zinc salt (Ziram) 

Insecticides: Ethyl pyrophosphate (Tetraethylpyrophosphate) 
( TEPP ) ' 



34,648 
27,093 



30,677 
26,219 



5,867 
16,489 



471 
1,117 



361 
25,144 



379 
1,062 



386 
24,392 



152 
559 



344 

15,434 



.89 
.63 



^ Calculated on rounded figures. 

' Includes such materials as dinitro compounds, isopropyl oarbanilate (IPC), maleic hydrazide, and a small 
amount of phenoxyacetic acid derivatives. 

' Production of the gamma isomer content in benzene hexaohloride totaled 11.5 million pounds; sales 
amounted to 8.1 million pounds. 

* Combined production in this group of aldrin, chlordane, dieldrin, endrin, heptaohlor, isodrin, and toxa- 
phene amounted to 45,169 thousand pounds. Sales totaled 39,982 thousand pounds, valued at 16,278 thousand 
dollars. Also included in this group are allethrln, aramite, arathane, DDD, DNOC, EPN, lindane, methoxychlor. 



SYNTHETIC ORGANIC CHEMICALS, 195^ 53 

In 1954 production of all pesticides and other organic agricul- 
tural chemicals amounted to 419 million pounds, an increase of 
17.8 percent over the 356 million pounds reported for 1953, Sales 
in 1954 amounted to 336 nnillion pounds, valued at 125 million dol- 
lars, compared with 334 million pounds, valued at 119 million dol- 
lars, in 1953. 

In 1954 the output of cyclic pesticides and other cyclic chemi- 
cals in this group totaled 358 million pounds, or 20. 4 percent more 
than the 297 million pounds produced in 1953. Sales in 1954 were 
279 million pounds, valued at 102 nnillion dollars, compared with 
282 million pounds, valued at 99 million dollars, in 1953. 

Production of cyclic insecticides in 1954 was 236 million 
pounds, or 56. 2 percent of the total output of all organic pesti- 
cides and 65.9 percent of the total output of cyclic pesticides. 
Sales in 1954 totaled 200 million pounds, valued at 59 million dol- 
lars. The chemical in this subgroup that was produced in the 
greatest quantity in 1954 was the insecticide DDT, production of 
which amounted to 97 million pounds. 

Production of acyclic pesticides and other acyclic organic agri- 
cultural chemicals in 1954 amounted to 62 million pounds, com- 
pared with the 59 million pounds reported for 1953. Sales in 1954 
were 57 million pounds, valued at 22 million dollars, compared 
with 52 million pounds, valued at 20 million dollars, in 1953. 

Miscellaneous Synthetic Organic Chemicals 

As used in this report, the term "miscellaneous synthetic or- 
ganic chemicals" includes products such as halogenated hydrocar- 
bons, paint driers, photographic chemicals, solvents, and tanning 
materials that are not included in the use groups covered in the 
other sections of this report. In 1954 the production of these mis- 
cellaneous chemicals as a group was 17,408 million pounds, a de- 
crease of 1.5 percent from the 17,669 million pounds reported for 
1953. Sales in 1954 totaled 8,092 million pounds, valued at 1,213 
million dollars, compared with 7,804 million pounds, valued at 
1,236 nnillion dollars, in 1953. Statistics on production and sales 
of miscellaneous chemicals in 1954 are given in table 26A, 12 

In 1954 the output of cyclic miscellaneous chemicals as a group 
totaled 409 million pounds, an increase of 1.7 percent from the 
402 million pounds reported for 1953. Sales in 1954 totaled 255 
million pounds, valued at 77 million dollars, compared with 262 
million pounds, valued at 83 million dollars, in 1953. In volume 
of production, the most important chemicals in this group in 1954 
were hexamethylenetetrannine (26 million pounds) and the formal- 
dehyde condensate of 2-naphthalenesulfonic acid (21 million 
pounds). 



^^ See also table 26B, part III, which lists these products alphabetically and identifies 
the manufacturers. 



54 



UNITED STATES TARIFF COMMISSION 



TABLE 26k* ••Synthetic organic chemicals; United States production and sales of miscellaneous chemicals, 1954 



[Listed below are all miscellaneous chemicals for which any reported data on production or sales may be pub- 
lished. (Leaders are used where the reported data are accepted in confidence and may not be published or 
where no data were reported.) Table 26B in part III lists alphabetically all miscellaneous chemicals for 
which data cm production or sales were reported and identifies the manufacturer of each] 



Grand total- 



MISCELLANEOUS CHEMCCALS, CYCLIC 



Chemicals for which separate statistics may not be shown- 
Chemicals for which separate statistics are shown below — 



Benzoic acid salts: Sodium benzoate, tech. and U.S.P- 
Benzoyl peroxide- 



Chlorophyll and chlorophyllins 

Cyclopropane 

2,6-Di-tert-butyl-p-cresol, all grades- 
Flotation reagents, total- 



Thlocarbanilide (Diphenylthiourea)- 
All other 



Hexamethylenetetramlne, tech 

Lubricatinr oil additives 

^-Hethylumbelliferone 

Naphthenic acid salts, total^ ■' 

Calcium naphthenate — — — 

Cobalt naphthenate 

Iron naphthenate 

Lead naphthenate 



Manganese naphthenate- 

Zino naphthenate 

All other- ■ 



Organic mercury compounds* 

Photographic chemicals, total- 
Benzotriazole- 



p-Diazo-N,N-diethylaniline, zinc chloride salt— 
p-Diazo-N,N-dimethylanillne, zinc chloride salt- 
All other ' ■ — ______ 



n-Propyl gallate 

Rosin acid salts, totals- 
Calcium resinate 
Lead resinate 



Manganese reslnate- 
All other 



Tall oil salts, totals- 
Cobalt tallate 

Iron tallate 

Lead tallate 



Manganese tallate- 
All other———— 



Tanning materials, total- 



2-Naphthalenosulf onio acid, formaldehyde condensate and 
salts — — — — — _— — -^ — 



MISCELLANEOUS CHEMICALS, ACYCLIC 



Chemicals for which separate statistics may not be shown- 
Chemlcals for which separate statistics are shown below — 



Acetaldehyde — 
Acetic acid, synthetic, 100^' 



17,408,250 



1.000 
pounds 

8,091,831 



409,320 



138,236 
271,084 



4,156 
1,768 



4, 
4,350 



376 
3,974 



26,148 



19,358 



t:;5(36 

3,008 
166 
11,413 
2,223 
1,072 
270 

28 

4,344 



25 
4,244 



4,759 



1,510 
113 

1,748 
964 
424 

32,386 



20,780 
11,606 



16,998,930 



Quantity 



255,110 



97,410 
157,700 



4,320 
1,130 



2,659 



18,588 
71,220 



18,885 



1,133 

3,163 

146 

10,967 

2,271 

969 

236 

31 



3,994 
5" 



3,903 



139 
175 
491 



4,7U 

1,495 

94 

1,827 

844 

453 

31,164 



1.000 

dollars 

1,212,540 



76,588 



32,009 
44,579 



1,593 
820 
714 

1,506 



3,317 
16,596 



6,358 



413 
2,074 
39 
2,733 
706 
282 
111 

166 

5,481 



154 

79 

5,187 

76 



35 
47 

127 



19,774 
11,390 



7,836,721 



4,977,210 
12,021,720 



442,007 



2,035,418 
5,801,303 



31,518 
93,502 



1,476 

24 

511 
204 
85 

5,278 



3,219 
2,059 



1,135,952 



540,639 
595,313 



2,672 
7,663 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1954 

TABLE 26h. -Synthetic organic chemicals: United States production and sales of 
miscellaneous chemicals, 1954- -Cont inued 



55 



Production 



Quantity Value 



MISCELLANEOUS CHIMICALS, ACYCLIC— Continued 



Acetic acid salts, total- 
Aluminum acetate 



Ammonium acetate — 

Barium acetate 

Cobalt acetate 

Lead subacetate 

Potassium acetate- 
All other 



Acetic anhydride, lOOJt, from all sources- 
Acetone, total 



By fermentation 

From isopropyl alcohol 

All other' 



Acrylonitrlle- 
Amines, total- 



n-Butylamine, mono- 
All other 



Bls(2-chloroethyl) ether (Dichloroethyl ether), all grades- 
Butyl acetates, 90^1 



Butyl alcohols, lOO^t, total- 
Primary, normal 
All other 



Caprylic acid salts- 
Carbon disulfide— 



Cellulose esters and ethers, total- 
Cellulose acetate- 



Sodium carboxymethylcellulose, 100^- 
All other 



Chloroacetic acid, mono 

2-Chloro-N,N-dlmethylethylamine (Dimethylaminoethyl chloride) 
hydrochloride 



Citric acid salts, total- 
Potassium citrate 

All other 



Diethyl diethylmalonate (Diethyl malonlc ester) - 

Diethylene glycol 

Diethyl malonate (Malonlc ester) 

2-Dlmethylaminoethanol 

Dipropylene glycol 



Ethanolamines , total - 

Monoethanolamine 

Dlethanolamine 



Triethanolamine- 



Ethyl acetate, 85lt 

Ethyl alcohol, synthetic*- 



a-Ethylcaproic (2-Ethyl-l-hexoio) acid salts, total- 
Calcium a-ethylcaproate —____——— 

Cobalt a-ethylcaproate 

Manganese a-ethylcaproate 

Zinc a-ethylcaproate 

All other ' ■ , , 



Ethylene glycol — 
Ethylene oxide 



Ethyl ether, total- 



Absolute and U.S.P- 
Tech 



Ethyl formate 

Fatty acid esters not Included with plasticlzers or surface- 
active agents _^__^___^.^.^_ 



1,000 
pounds 

15,000 



29T 
306 
196 
107 

472 
13,556 

690,643 



1,000 
pounds 

13,546 



1,000 
dollar, 
2,615 



20,866 

403,681 

52,998 

63,107 

141,966 



116 
108 



402 
12,579 



245,846 



119 
185 



113 
2,040 



17,829 



363 
141,603 



10,293 
78,255 



180,135 
65,711 



64,733 
32,112 



194,407 
213,654 



138 
476,503 



224 
31,888 



78,250 
155,182 



13,496 
4,333 

19,946 

14,575 



118,831 
36,351 



129 
463,368 



111 
14,464 



9,180 
18,236 



364,407 
22,177 
158,823 

40,112 



14,574 
3,662 



83 

23,473 



68,584 



21,280 
152,029 



15,637 
38 



9,455 
59,129 



3,051 



79 



180 
4,966 

34 

36,242 

806 

290 

6,372 

62,885 



23,511 
22,755 
16,619 

72,451 
1,151,590 

1,529 



1,118 
637,901 



4,200 
51,800 



2,529 



41,163 
215 



6,465 
54,435 



5,360 
161 



894 
12,631 



22,661 
31,774 



68,327 
510,303 



1,440 



5,469 
7,212 



6,645 
23,282 



337 
304 



283,262 
97,878 



44,464 



3,762 
40,702 



103 
2,351 



126 
187 



31 
325 



28,975 
13,128 



2,337 
2,136 



See footnotes at end of table. 



56 UNITED STATES TARIFF COMMISSION 

TABLE 2fiK. --Synthetic organic chemicals: United States production and sales of 
miscellaneous chemicals, I954--Continued 



MISCELLANEOUS CHIMICALS, ACYCLIC — Continued 

Fatty and synthetic higher alcohols (Cio and higher), total- 

1-Hexadecanol (Cetyl alcohol) 

All other — ^ ■ — — ■ 



Flotation reagents, total - 
Ootadeoyl amine acetate- 
All other 



Formaldehyde (37^6 HCHO by welght)- 
Formlc acid, 90f> 

Fonnlo acid salts, total 
Sodium formate, total' 
Crude 



Refined- 
All other- 



Halogenated hydrocarbons, total- 
Carbon tetrachloride 
Chlorinated paraffins, total— 
Less than 35^ chlorine 
35'fi or more ohlorlne- 



Chloroethane (Ethyl chloride) , tech. and U.3.P- 

Chloroform, total — • • — - 

Tech — ■ — 



Chloromethane (Methyl chloride) , all grades 

1,2-Dlchloroethfliie (Ethylene dlchlorlde) 

Dichloromethane (Methylene chloride), all grade 
Lauryl chlorlde- 



Tetrachloroethylene (Perchloroethylene) — 

Trlchloroethylene 

Vinyl chloride (Chloroethylene), monomer- 
All other 



Isoprqpyl alcohol' 

Isopropyl ether 

Lactic acid, IOO56, total- 
Edible and medicinal 

Tech 



Lactic acid salts: Sodium lactate- 

Llnolelc acid salts, total' 

Calcium llnoleate 
Cobalt llnoleate 
Lead llnoleate 



Manganese linoleate- 
All other 



Lubricating oil addltlves- 

Malele anhydride 

Methanol, synthetic' 

Methyl acetate- 



1- and 2-Octanol 

Oleic acid salts, total'- 
Aluminum oleat o 
All other 



Oxalic acid salts 

Pentaerythritol 

Pentaerythritol tetranitrate 

Polyacrylic acid, sodium and potassium salts- 

Propionic acid 

Propylene glycol (1,2-Propanedlol) 

Riclnoleic acid salts 

Sarcosine 



Sequestering agents: (Ethylenedinltrllo)tetraacetlc acid, 
tetrasodlum salt 



Sodium formaldehydesulfoxylate- 

Stearic acid salts, total^" 

Altminum stearatea, total 
Aluminum monostearate 
Aluminum dlstearate 
Aluminum trlstearate— — — 
Calcium stearate 



48,769 



447 
48,322 

20,335 



20,335 

1,032,026 
14,431 

22,868 



22,868 
3.088,500 



234,895 

30,004 

5,352 

24,652 

547,072 

32,087 

29,234 

2,853 

33,147 

452,161 

69,833 

1,248 

157,974 

296,783 

393,246 

840,050 

858,682 
3,267 

5.071 



Quantity Value 



460 
28,786 



107 
19,803 

578,311 
12,639 

16,626 



11,536 

11,531 

5 

5.090 

1.327.140 



3,929 
1,142 

62 

1,347 



706 
304 
US 
139 
60 

78,908 

1,118,477 
2,686 
6,000 



107 
209 

17,488 

3,204 

53,662 

1,402 

980 

12,844 

50,728 

238 

533 

3,740 
5,624 

20,238 



7,141 
1,951 
4,7U 
476 
3,429 



226,349 

30,790 

5,304 

25,486 

121,835 
23,262 
20,877 
2,385 
26,262 
72,391 
62,934 

140,558 
252,434 

370,325 

387,654 
2,082 

4,827 



3,710 
1,117 



552 
274 
53 
100 
178 

26,560 
33,548 
710,558 

*3,017 
344 



1,000 
dollar, 

10,345 



180 
10.165 

5,826 



46 
5,780 

17.550 
1,970 

1,068 



523 
518 



165,943 



15,477 
3,852 

899 
2,953 
8,524 
3,421 
2,834 

587 
3,119 
4,622 
6,988 

13,727 
24,502 

81,711 
20,176 



1,516 
292 



104 
240 

17,608 
2,978 

44,353 

1,220 

870 

57^637 
262 



3,421 
5,054 

20,356 



7,189 
1,936 
4,813 
440 
3,486 



99 
199 

18 



7,176 

7,995 

26,384 

'872 
115 



39 
76 

2,913 

798 

14,370 

949 



7,335 
208 



2,115 
1,089 

6,980 



2,351 
639 

1,562 
150 

1,215 



Se» footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



57 



TABLE 26K.- -Synthetic organic chemicals: United States production and sales of 
miscellaneous chemicals , 7954- -Continued 



Quantity 



Unit 
valus^ 



MISCELLANEOUS CMMIGALS, ACTCLIC— Contlnuad 



Stearic acid salts— Continued 
Lead stearate 



Lithium stearate— 
Magnesium stearate- 

Zinc stearate 

All other 



Thloglycollc acid derivatives: Ammonium thioglycolate- 

Triethylene glycol 

Vinyl acetate, monome r 

Zinc formaldehydesulfoxylate 



893 
75 

635 
6,017 
2,048 

1,536 

17,413 

106,129 

1,363 



907 

114 

597 

5,879 

2,184 

1,523 
13,486 

1,279 



1,000 

dollars 

290 

64 

232 

2,109 

719 

2,009 
2,334 



Per 
pound 
$0.32 
.56 
.39 
.36 
.33 

1.32 
.17 



^ Unit values calculated on rounded figures. 

^ Quantities are given on the basis of solid naphthenate, reslnate, tallate, or linoleate content. 

' Statistics exclude production and sales of copper naphthenate. Statistics on copper naphthenate are 
given in the section "Pesticides and Other Organic Agricultural Chemicals." 

* Does not include medicinal mercury compounds or phenyl mercuric acetate used as a pesticide. Statistics 
on phenyl mercuric acetate are given in the section "Pesticides and Other Organic Agricultural Chemicals." 

' In addition, production of natural acetic acid totaled 19,022,000 pounds. 

' Statistics on production of ethyl alcohol from natural sources by fermentation are issued by the Alcohol 
Tax Unit, U. S. Internal Revenue Service. 

' Data which were reported on the basis of 91 percent isopropyl alcohol have been converted to a 100- 
percent basis. 

' In addition, production of methanol from natural sources totaled 13,293,280 pounds. 

' Statistics exclude production and sales of potassium oleate. Statistics on potassium oleate are given in 
the section "Surface-Active Agents." 

^^ Statistics exclude production and sales of potassium and sodium stearate. Statistics on these stearates 
are given in the section "Surface-Active Agents." 



Production of acyclic miscellaneous chemicals as a group in 
1954 totaled 16,999 million pounds, a decrease of 1.6 percent fronn 
the 17,267 million pounds reported for 1953. This group consists 
chiefly of solvents, refrigerants, and acyclic intermediates. Sales 
in 1954 totaled 7,837 million pounds, valued at 1,136 million dol- 
lars, compared with 7,542 million pounds, valued at 1,153 million 
dollars, in 1953. ^^ 



*^ The large difference between production and sales indicates that a substantial part 
of the output of acyclic miscellaneous chemicals is consumed at the producing plants in the 
manufacture of other more advanced products. Acyclic miscellaneous chemicals so used are, 
therefore, acyclic intermediates. They correspond in function to cyclic intermediates, al- 
though no group of acyclic miscellaneous chemicals is commonly recognized by the chemical 
industry as intermediates. 



58 UNITED STATES TARIFF COMMISSION 

Production of halogenated hydrocarbons (a group consisting of 
chlorine, bromine, fluorine, and iodine derivatives of hydrocar- 
bons) totaled 3,088 million pounds in 1954, compared with 3,l67 
million pounds in 1953. This subgroup includes such chemicals as 
ethyl chloride, ethylene dichloride, and monomeric vinyl chloride. 

The volume of the output in 1954 of most of the acyclic miscel- 
laneous chemicals that are produced in large quantities differed 
only slightly from the volume of the output in 1953. Production of 
the following of these chemicals increased in 1954, compared with 
1953: Ethyl alcohol^'^ (1,152 million pounds, compared with 1,060 
million pounds); synthetic methanol (1,118 million pounds, com- 
pared with 1,116 million pounds); and ethylene glycol (638 million 
pounds, compared with 624 million pounds). Production of the fol- 
lowing acyclic miscellaneous chemicals decreased in 1954, com- 
pared with 1953: Formaldehyde (1,032 million pounds, connpared 
with 1,119 million pounds); isopropyl alcohol (859 million pounds, 
compared with 901 million pounds); and acetic anhydride (691 mil- 
lion pounds, connpared with 804 million pounds). 



'■* This report does not include statistics on the production of ethyl alcohol from natural 
sources by fermentation. The Alcohol Tax Unit, U. S. Internal Revenue Service, issues such 
statistics monthly and annually. 



PART m, ALPHABETICAL LIST OF INDIVIDUAL PRODUCTS, BY 
GROUPS, AND NAMES OF MANUFACTURERS 

Part III of this report consists of (l) a series of tables that 
supplement the statistical information given in parts I and II, and 
(2) a Directory of Manufacturers. The tables with numbers that in- 
clude the letter "B" supplement the tables in part I or part II with 
numbers that include the letter "A"; for example, table 8B in part 
III supplements table 8A in part II. 

Each table in part III lists alphabetically the individual items in 
each group for which data on production or sales were reported for 
1954. Where an asterisk (*) precedes the nanne of an item in the 
tables in part III, separate statistics for the item are given in the 
tables in part I or part II. The manufacturers of each product are 
indicated by identification numbers, which are listed in the Direc- 
tory of Manufacturers (table 27). A few connpanies, however, have 
specifically requested the Tariff Commission to withhold such in- 
formation on certain itenns. These manufacturers are indicated by 
the letter "X" in the tables. 

Tar Crudes 



TABLE AB. '-Organic chemicals 



Tar crudes for which United States production or sales were reported, 
identified by manufacturer , 1954 



[Tar crudes for which separate statistics are given in table AA are marked below with an asterisk (»); 
products not so marked do not appear in table AA because the reported data are accepted in confidence and 
may not be published. Manufacturers' identification numbers shown below are taken from table 27. Table 27 
identifies all United States producers of tar crudes (except producers who report to the Coal Economics 
Division, U. S. Bureau of Mines) ] 



Product 



Manufacturers' identification numbers 
(according to list in table 27) 



•Crude light oil 

Light-oil distillates: 
•Benzene, specification and industrial grades: 



•Toluene : 

Nitration grade, 1 

Pure commercial grade, 2 

•Xylene: 

3° 

Commerc 5 al 

•Solvent naphtha 

All other lightroil distillates 

Pyridine: 

Crude bases 

Semireflned or denaturing grade 

•Naphthalene, crude, solidifying at — 

Less than 7i° C 

7'4° C. to less than 76° C 

76° C. to less than 79° C 

•Crude tar-acid oils, having a tar-acid content of- 

5% to less than 2i% 

2^% to 50« 

•Cresylic acid, crude 

•Creosote oil (Dead oil): 

•Sold or consumed as such 



•Sold or consumed in coal-tar solution 

•Coal tar sold or consumed in coal-tar solution 

•All other distillate products 

•Tar , road 



51, 98, 161, 322. 



320, 460, <466, 584. 
429, 584. 
161, 584. 
276. 

320, 460, 466, 584. 
161, 276, 429, 584. 

161, 460, 466. 

276, 320, 429, 466, 584. 

44, 161, 176, 276, 460, 466, 509, 584. 

44, 176, 429, 460, 584. 

460, 584. 
460, 584. 

16, 25, 198, 276, 508. 

44, 176, 198, 460, 466, 508. 

322, 460, 507, 508, 584. 

98, 176, 198, 466, 508, 584. 
322, 460, 508, 583. 
460, 507, 509, 584. 

16, 25, 51, 98, 198, 207, 322, 460, 466, 508, 

509, 584. 
110, 198, 322, 437, 460, 508, 584. 
198, 322, 460, 508, 584. 

44, 98, 176, 207, 276, 460, 508, 509, 584. 
98, 198, 207, 276, 378, 437, 460, 508, 509, 

584. 



60 



UNITED STATES TARIFF COMMISSION 



T JHJ m.-'Orgmtie chemicals: Tar crudes far which United States production or sates were reported, 
identified by manufacturer , 19S4- -Cent imted 



»Tar for other uses: 

Crt;de 

Refined 

Pitch of tar: 

»Soft (Uttter Boftenlng point lees than 110° F.) 

"Medium (Water softening point 110° F. to 160° F.)- 

»Hard: Water softening point of — 

161° F. to 230° F 

23f F. to 291° F., and over 

»Pltoh of tar coke and pitch emulsion 



HanufaiEturers' Identif loatlan n\abera 
(aooording to list in table 27) 



54, 161, 198, 460, 508, 509, 584. 

25, 98, 198, 207, 322, 460, 508, 509, 584. 

16, 276, 508, 584. 

25, 51, 98, UO, 198, 207, 322, 437, 460, 508, 
509, 584. 

460, 508, 509, 584. 

207, 276, 460, 508, 509, 584. 

198, 437, 460, 508, 509. 



Crude Products From Petroleum and Natural Gas 
for Chemical Conversion 



TABLE SB. --Synthetic organic chemicals: Crude products from petroleum artd natural gas for chemical conversion 
for which United States production or sales were reported, identified by manufacturer, 1954 

[Orude products from petroleum and natural gas for chemical conversion for which separate statistics are 

given in table 5A are marked below with an asterisk (•); products not so marked do not appear in table 5A 

because the reported data are accepted in confidence and ma; not be published. Manufacturers' identifica- 
tion numbers shown below are taken from table 27] 



Manufacturers' Identlfloation numbers 
(aooording to list In table 27) 



ARCMATICS AND NAFHTHENES 

•Alkyl aromatics, distillates, and solvents- 

•Benzene (except motor grade): 

•Benzene, 1° ' 

•Benzene, 2° 



Benzene, motor grade- 

•Cresylio acid, orude- 

Cyelopentane- 



'•Naphthenic acids: 

Acid number less than 150- 

Acid number 150-199 

•Acid number 200-224 

•Acid number 225-249 

Acid number 250 and over — 

Petroleum phenols 

Sodium carbolate and phenate, crude- 
•Toluene : 

•Nitration grade, 1° 

•Pure coBmemial grade, 2° 

Solvent grade 

All other 

•Xylene : 



Aviation grade 

Nitration grade, 3° — 
All other 



All other aromatics and naphthsnes- 



ALIFHATIC HSmOCARBONS 



•Ci hydrocarbon, methane- 
•C2 hydrocarbons: 

Acetylene 

•Ethane 



•Ethylene- 



•C3 hydrocarbons: 
•Propane 



•Propylene- 



•Propane -propylene mixture 

•C4 hydrocarbons: 

•1,3-Butadiene, grade for rubber (elastomers)- 



234, 261, 335, 363, 423, 457, 4%, 537, 574. 

88, 135, 210, 241, 479. 

144, 186, 189, 204, 335, 423, 452, 518, 544, 

562, 564, 567. 
186. 

184, 329, 439, 507, 518, 544, 605. 
458. 

231, 479. 

209, 457, 479, 564. 

209, 286, 457, 564. 

209, 297, 457, 518, 564. 

209, 457. 

344. 

286. 

135, 210, 241, 479, 518. 

189, 204, 208, 261, 329, 335, 518. 

241, 544, 562. 

144, 186, 204, 479, 564. 

189, 241, 329, 564. 

479, 518. 

135, 144, 186, 204, 261, 518, 544, 564. 

234, 457, 458. 



281, 458, 531, 544. 

208. 

222, 231, 281, 423, 4%, 531, 544. 
204, 208, 222, 231, 234, 286, 335, 339, 423, 
460, 4%, 531, 537, 544, 562, 567. 

144, 189, 222, 281, 329, 363, 423, 439, 450, 

457, 458, 518, 531, 544, 556. 
184, 204, 335, 423, 450, 458, 496, 504, 518, 

531, 537, 544, 562. 
231, 286. 

52, 193, 261, 335, 423, 450, 458, 562, 567, 
602. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



61 



TABLE SB. --Synf/iefic organic chemicals: Crude products from petroleum arxl natural gas for chemical conversi 
for which United States production or sales were reported, identified by manufacturer,t954--ContLnued 



Manufacturers' identification numbers 
(according to list in table 27) 



ALIPHATIC HYDROCAHBONS— Continued 



•C* hydrocarbons — Continued 

Butadiene and butylene fractions- 
Butane -buty lene 

*1-Butene, 2-butene, and mixtures- 



Butylene concentrate- 



•Isobutane 

Isobutylene 

All other 

•Cj hydrocarbons: 

Isopentane 

Isoprene 

n-Pentane 

1-Pentene, 2-pentene, and mixtures — 
Cs hydrocarbons: 

Diisopropyl (2,3-Dlinethylbutane) 

Isohexane 

Neohexane 

C7 hydrocarbons: 

Heptenes 

Isoheptane and isoheptene 

All other 

C$ hydrocarbons: 
»Diisobutylene 

2,2,'i-Trimethylpentane (Iso-octane)- 

Hydrocarbons, C9 and above; 
*Dodeoene (Tetrapropylene) 

Eicosane 

*Nonene (Trlpropylene) 

Polybutene 

Triisobutylene 

All other 



•Hydrocarbon derivatives: 

tert-Butyl mercaptan 

Di-tert-butyl disulfide— 

*Ethyl mercaptan 

Methyl mercaptan 

tert-Octyl disulfide 

All other 



135, 20A, 23A, 335, 50-i, 564. 

189. 

118, 189, 222, 281, 329, 363, 458, 564. 

52, 193, 231, 261, 286, 329, 423, 439, 450, 

458, 518, 531, 602. 
458. 

118, 189, 222, 281, 363, 458, 518, 531. 
261, 297, 423, 531. 
222, 450. 



189, 


458, 


531, 


556. 








423. 














458. 














222, 


363, 


458, 


517. 








458. 














261, 


458, 


556. 










458. 














458. 














261, 


458, 


556. 










286. 














458. 














423, 


458. 












297, 


439, 


567. 










261, 


458. 












261, 


458. 












458. 














189, 


261, 


303, 


423, 


450, 


458. 


479, 518, 564 


439, 


479. 












144, 


189, 


204, 


231, 


423, 


439, 


479. 


241, 


544, 


564. 










439. 














329, 


427, 


458. 










458. 














458. 














184, 


241, 


564. 










184, 


241. 












458. 














130, 


439, 


458, 


564. 









62 



UNITED STATES TARIFF COMMISSION 
Cyclic Intermediates 



TABL£ 7B. '•Synthetic organic chemicalg: Cyclic intermediates for which United States production or salem 
were reported, identified by manufacturer, 1954 

[Cyelle Intermediates for which separate statistics are given in table 7A are marlced below with an asterisk 
(»); cyclic intermediates not so loarked do not appear in table 7A because the reported data are accepted 
in confidence and may not be published. Manufacturers' identification nufflbers shown below are taken from 
table 27. An X signifies that the manufacturer did not consent to the publication of his identification 
number with the designated product. (Part C in the appendix lists alphabetically all the important common 
names of cyclic intermediates usually encountered In the trade and gives the corresponding standard 
(Chemical Abstracts) name under which the manufacturers' identification numbers are given in this table)] 



Manufacturers' identification numbers 
(according to list in table 27) 



Acenaphthene— — ■ 

6 ( and 7 ) - (2-Acetamido-4-aminophenylazo ) - 
1-naphthalenesulfonic acid. 

2-Acetamldo-3-chloroanthraquinone __— — 

2-Acetamldo-p-cresol — — — — __— __ 

l-Acetamldo-2-methoxynaphthalene — 

l-Acetamii^o-2-naphthol— — ___— 

l-Acetamldo-7-naphthol— 



p-Acetamldophenol -— — - 

»Aoetanlllde, tech — — 

o-Acetanisidide-— — — 
Acetoacetanillde- 
Acetoaceto-1-naphthylamide- 
o-Acetoaoetotoluidlde- 

p-Acetotoluidide — — — 

21-Aceto)ty-4-bro!ic-17-hydroxy-3,H,20-triketo- 

pregnane. 
N-Acetylanthranillc acid, potassium (and sodium) 
salt. 

3-Acetyl-<»-hydroxyooumarin— ■'--■■-- 

Acetylphenyl benzoate ■• ■■- — 

Acetylsulfadlazine — — 

Acetylsulfamerazlne — — 

»N-Acetylsulfanllyl chloride- 
Acetylsulfathiazole- 

Acrldine 

Acridine yellow 

Aliyl benzene (high molecular weight) 

2-Amlno-5-acetamido-'i-methyldiphenylsultone ~ 

m-Aminoacetanilide 

»p-Amlnoaoetanilide (Acetyl-p-phenylenedlamine) 

m-Amlnoacetophenone — — — — ■ — ^— - 

3-Amino-p-aoetotoluidlde- 



l-Amino-*('i'-amino-3'-sulfoanilino)-2-anthraqulnone- 
sulfonlo acid. 
«5-Amlno-2-anilinobenzenesulfonlc acid — 



»2-(p-Aminoanillno)-5-nltrobenzenesulfonic acid — 

»l-Amlnoanthraquinone and salt— 

»2-Amlnoanthraqulnone and salt — 

l-Aminoanthraquinone-2-sulfonlc acid ^__ 

N-f^-Amino-l-anthraqulnonyl )aiithranllic acid— 

N-[5(and 8)-Amlno-l-anthraqulnonyl]anthr,anlllc 
acid. 

N-(8-Amlno-l-anthraqulnonyl)anthranilic acid — — 

'V-Amlnoantlpyrine — ■■■ 

»6-Amino-3, i'-azoblE,[benzenesulfonic acid] ■ 

8-Aminobenz[a]acridln-7(12H)-one 

«l-Amlno-^-benzamidoanthraquinone ______ 

»l-Amino-5-benzamidoanthraquinone _— — 

5-Amlno-2-benzamldQ-l,^-diethoxybeDzen o — 
»6-(m-Aminobenzamldo)-l-naphthol-3-sulfonic acid— - 

»6-(p-Aminobenzamido)-l-naphthol-3-sulfonic acid 

•2-Amlno-p-benzenedisulfonic acid [SOsH'l] 

2 -Amino benzene thiol— ■_^____— _._ 



5-Amino-2 C3H)-benzimidazolone— — -^— — — — — 
p-Amlnobenzoic acid, tech — — — ^-^— — -^— 
p-Aminobenzoic acid, ethyl ester (Benzocalne, non- 
medicinal grade). 
p-Aminobenzoyl-m-phenylenedlamiDe 
l-Amino-4-bromoanthraquinone-2, 5-dlsulf onic acid 

»l-Amino-^-bromo-2-anthraqulnonesulfonio acid— — — 

l-Amlno-^bromo-2 -methylanthr aqulnone 

l-Amlno-2-bromo-^(p-toluidlno)anthraquinone 

A-Aml no-3-c ar bo xy benzene sulf onan thranllide——— 

»l-Amlno-5-chloroanthraquinone- 



l-Amino-5 ( and 8)-ohloroanthraqulnone~ 
l-Amlno-8-chloroanthraquinone- 
2 -Amlno-1-chloroanthraqulnone- 
2-Amino-3-chloro an thr aqulnone — 
3-Amlno-6-chlorobenzoic acid — — — — 



508. 
559. 

384. 

559. 

559. 

559. 

384, 403, 559. 

208. 

335, 494, 495, 559. 

403. 

415, 562. 

415. 

415, 562. 

403. 

466, 494. 

X. 



537. 

466. 
223. 
466. 
466. 
208, 
208. 
508, 
403. 
439. 
559. 
559. 
384, 
223, 
384. 
559. 



466, 540. 
537. 



403, 495, 537, 559, 565. 
335, 501. 



384, 403, 537, 559. 

443, 455, 510, 559. 

106, 237, 369, 384, 401, 403, 466, 510, 537. 

106, 384, 403, 466, 537. 

384. 

384. 

537. 

537. 

247. 

384, 403, 443, 451, 455, 510. 

403. 

384, 

106, 

443. 

403, 

384, 

403, 

466. 

537. 

384, 

247. 



401, 403, 466, 537. 

384, 403, 537. 

443, 451, 510, 537. 

403, 443, 455, 537, 559. 

443, 537, 559. 



559. 
559. 
384, 
537. 
369, 
559. 
106, 
466. 
403, 
537. 
384. 
443. 
5W» 



403, 537. 

384. 

401, 403, 466, 537. 

537. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



63 



-Synthetic organic chemicals: Cyclic intermediates for which United States production or sales 
were reported, identified by manufacturer, J954- -Continued 



Manufacturers' identification numbers 
(according to list in table 27) 



2-Aiiilno-6-chloro-A-nltrophenol 

2-Aiiiino-^-ohloro-5-nltrcphenol-— • -— 

»2-Amino-4-ohlorophenol — 

»2-Amino-<4-chIoro-l-phenol-6-sulfonlo acid 

»2-Amino-5-chloro-p-toluenesulfonlo acid f S03H=l] 

6-Amino-4-ohloro-m-toluenesulfonlo acid [ SOsH^l] 

5-Amlno-2 (2 (3H)-dehydro-2-oxo-5-benzliiildazolyl )- 
benzenesulfonio acid. 

'i-Amino-S-ohloro-p-toluenesulfono-o-toluidide — 

»l-Amlno-2,4-dlbromoanthraqulnone 

4' -Amino-2' ,5' -dlethoxybenzanillde — 

2-Aiiiino-4, 6-diniethylpyrlmldlne 

2-Amlno-3,5-dlnltrobenzenesulfonethylamlde 

5-Aniino-6-ethoxy-2-naphthalenesulfonic acid 

5-(4-Amlno-5-ethoxy-o-tolylazo)-2-chlorobenzene- 
sulfonlo acid [S03H=l]. 

2-Amlno-N-ethylbenzenesulfonanillde 

p-Amlno-N-ethyl-N-l-naphthylbenzamlde 

2-Amino-N-ethyl-5-nitrobenzenesulfonanilide 

SCand 8)-Aiiiino-8(and 5)-(p-hydroxyanlllno)-2- 
naphthalenesulfonlc acid. 

l-Amino-^-hydroxyanthraquinone — 

3-Amlno-2-hydroxyanthraqulnone 

2-Amlno-4-hydroxybenzenearsonic acid 

3-Ainino-6-hydroxy-2-niethylphenazine (Tolazine base)- 

l-Ainino-4-methoxyanthraquinone 

5-Aiiiino-6-methoxy-2-naphthalenesulfonic acid 

ni-(4-Aininoiiiethoxyphenylazo)benzenesulfonio acid 

8-Ainino-6-methoxyquinoline (Amichin ) 

l-Amino-2-methoxy-'i-(p-tolylsulfonaiiiido)anthra- 

qulnone . 
7-(4-Amino-5-methoxy-o-tolylazo)-l,3-naphthalenedl- 

sulfonic acid. 
4-(4'-Amino-5'-methoxy-o-tolyla2o)-2,7-naphthalene- 
disulfonic acid,5-phenylsulfone ester. 

4-Amino-N-methylacetanillde-— — 

l-Ainlno-2-methylanthraqulnone — 

2-Amino-4-methyldiazine 

8-Ainino-7-methyl-2-phenazlnol — 

4-Ainino-4'-(3-methyl-5-pyTazolone)-2,2'-stilbenedl- 

sulfonic acid. 
2-Aiiilno-5-methyl-l, 3,4-thiadlazole— — — — — — — - — 

l-Amlno-2-methyl-4-(p-toluidino)anthraquinone 

l-Amlnonaphth[2,3-cjacridlne-5,8,14(13H)-trlone 

2-Aiiiino-l,5-naphthalenedisulfonlo acid 

l-Amino-3,6-naphthalenedisulfonlo acid, 8-phenyl- 
sulfone ester. 

2-Amlno-l,5(and l,8)-naphthalenedisulfonlo acid 

»3-Amlnci-l,5-naphthalenedlsulfonlo acid (Cassella 
acid). 

3-Amlno-2, 7-naphthalenedlsulfonlc acid 

4-Amlno-l, 5-naphthalenedlsulf onlc acid 

4-Ainino-l,6-naphthalenedisulfonlo acid — .—— . 

4-Ainlno-l, 7-naphthalenedlsulfonlc acid -— 

5-Aiiiino-2,7-naphthaleQedlsulfonio acid (F acid) 

•6-Amino-l,3-naphthalenedlsulfonlo acid (Amino I 

acid). 
»7-Amino-l,3-naphthalenedlsulfonlc acid (Amino G 
acid). 

8-Ajiilno-l, 5-naphthalenedi6ulfonlo acid-— — ■ 

l-Ajiilno-2-naphthaleDesulfonio acid (o-Naphthlonic 
acid). 

«2 -Amlno-1-naphthalenesulf onlo acid (Tobias acid) 

4(and 5 )-Amlno-l-naphthalenesulfonic acid 

•5-Amino-l-naphthalenesulfonlo acid (Laurent's acld)- 
»5 -Amino-2 -naphthalenesulfonio acid (1,6-Cleve's 

acid). 
•5(and 8 )-Ainino-2 -naphthalenesulfonio acid (Cleve's 
acid, mixed). 
6-Amino-l-naphthaleneBulfonlc acid ■■ ■■■ ■ 
»6-Amino-2 -naphthalenesulfonio acid (Broenner's add) 

6(and 7)-Amlno-l-naphthalenesulfonio acid 

»8-Amlno-l-naphthalenesulfonlc aold (Perl acid) 

»8-Amino-2-naphthalenesulfonio acid (1,7-Cleve's 
aold). 

7-Amino-l,3,6-naphthalenetrisulfonlo acid 

■ 8-Amlno-l,3,5-naphthalenetrlsulfonlo acid 

8-Amino-l,3,6-naphthalenetrisulfonlc aold (Koch's 

acid). 
4-Amino-l,3,5-naphthalenetrlsulfonlc acld-4,5- 
sultam, trlsodium salt. 

8-Amino-l-naphtholc acid 

5-Amlno-l-naphthol ■ — — — — . ~ 



443. 

384. 

366, 403, 443, 537, 559. 

384, 403, 443, 455, 599. 

223, 444, 466, 494, 538. 

384, 494, 537. 

537. 



443. 




369, 


384, 403, 537. 


384. 




466. 




495. 




384, 


443. 


559. 




559. 




384. 




384. 




537. 




384, 


537. 


384, 


403. 


247. 




403. 




537. 




403, 


559. 


537, 


559. 


40. 




537. 





384, 


403. 










369, 


537. 










466. 












384, 


537. 










559. 












466. 












369. 












537. 












223, 


466. 










559. 












559. 












384, 


403, 


494, 


537. 






403, 


559. 










403, 


537. 










403, 


537. 










559. 












384, 


451. 










237, 


384, 


403, 


443, 


466, 537, 559 


384, 


403, 


466, 


537, 


559. 




384, 


559. 










466, 


537. 










444, 


466, 


494, 


559, 


X. 




466, 


559. 










403, 


537, 


559. 








384, 


403, 


443, 


537, 


559. 




384, 


403, 


537, 


559. 






443. 












403, 


472, 


537, 


559. 






559. 












384, 


403, 


537, 


559. 






384, 


403, 


443, 


537, 


559. 




537. 












384. 












403, 


537. 










537. 












384. 












403. 













64 



UNITED STATES TARIFF COMMISSION 



TAHIJ: TR. --Synthetic orga 



che 



als: Cyclic intermediates for which United States producti 



were reported, identified by i 



ufacturer, J954- -Continued 



Manufactvirers' identification numbers 
(according to list in table 27) 



8-Aiiiino-2-naphthol 

7-Aiiiino-l-naphthol-3,6-disulfonic acid (2R acid), 
monosod ium salt. 

8-Ajnino-l-naphthol-3,5-disulfonic acid (K acid) 

•8-Amino-l-naphthol-3,6-disulfonic acid (H acid), 

monosodium salt. 
«8-Amlno-l-naphthol-5,7-disulfonic acid (Chicago 
acid) (2S acid), monosodium salt. 
8-Amino-l-naphthol-3,6-disulfonic acid, p-toluene- 
sulfonate. 

»l-Amino-2-naphthol-4-sulfonic acid (l,2,i-Acid) 

»6-Amlno-l-naphthol-3-sulfonlc acid (I acid), sodium 

salt. 
»7-Mino-l-naphthol-3-sulfonic acid (Gamma acid), 

sodium salt. 
»8-Amino-l-naphthol-5-sulfonic acid (S acid), sodium 
salt. 

5-Amino-2-(p-nitroanilino) benzene sulfonic acid 

2-Amino-5-nitrobenzenesulfonic acid [sOsH^l] 

»2-Amino-4— nitrophenol -— 

2-Amino-5-nitrophenol 

-Amino-2-nitrophenol- 



•2-Amlno-^nitro-l-phenol-6-sulfonic acid 

8-Amino-4- ( iii-ni trophenylazo ) -2 -naphthol 

"i-Amino-4 '-nitro-2,2 '-stilbenedlsulfonic acid 

3-Amino-5-nitro-p-toluenesulfonic acid, potassium 

salt. 
3-Amino-A-octadecylaminobenzenesulfonic acid, sodium 
salt. 

m-Aminooxanilic acid-— --- 

p-Aminooxanllio acid ___-_ 

(6-Amlnophenethylmercapto)acetlc acid, sodium salt~ 

m-Aminophenol ^ 

o-Amlnophenol ■ " ■ 

»p-Aminophenol and salts -_— ■ 

2-Amino-l-phenol-4,6-disulfonic acid— 

»2-Amino-l-phenol-'i-sulfonamide 

3-Aminophenylsulfonanilide 



»2-Amlno-l-phenol-^-sulfonic acid 

m-(p-Amlnophenylazo)benzenesulfonic acid 

#p_(p_Aminophenylazo)benzenesulfonlc acid 

5(and 8 ) -Amlno-8 ( and 5 )-phenylazo-2-naphthalene- 

sulfonic acid. 
5-(p-Aminophenylazo)salicylic acid- 



4-Aiiiino-a-phenyl-m-cresol hydrochloride 

2-(p-Aminophenyl)-6-methylbenzothiazole 

2-(p-Aminophenyl)-6-methyl-7-benzothiazoleBulfonic 

acid and salt. 

l-(m-Amlnophenyl)-3-mfithyl-5-pyrazolone 

l-(m-Amlnophenyl)-5-oxo-2-pyrazoline-3-carboxyllc 

acid, 

3-Amino-5-phenyl-l,2,'Utriazole 

2-Amlno-3-picoline — 

2-Amlno-^plooline- 
6-Amino-2-picoline- 
6-Amino-3-picoline- 

2-Aminopyridine 

2-Amlnopyrlmidine- 
5-Aminosalicyllc 



lid 



2-Amino-5-(p-3ulfophenylazo)benzenesulfonlc acld»— 
2-(A-Amlno-3-sulfophenyl)-6-methylbenzothiazole- 

sulfonic acid. 

2-Aminothiazole — 

l-Amlno-2-(p-toluenesulfonamido)-2-anthraquinone- 

sulfonlc acid. 



♦A-Amlno-m-toluenesulfonic acid 



A-Amlno-o-toluenesulfonio acid ,S03H=1 



SOsH^ll 






_ -Amino-o-tolueneaulfonic 
6-Amino-ro-toluenesulfonic acid [S03H=l] 
7-('i-Amino-o-tolylazo)-l, 5-naphthalenedisulfonic 
acid. 

<V-(^Amlno-m-tolylazo)-m-toluenesulfonie acid 

N-('UAmino-m-tolyl)-p-quinone imine 

2-Amino-3,4, 6-trichlorophenol 

16- Ami noviolan throne 

"i-Amlnoxanthopurpurln 

«2-Amino-3,5-3<ylenesulfonic acid [sOsH^l] 

Amylnaphthalenes 

o-Amylphenol ■ ~ 

•Aniline (Aniline oil) 

Aniline salt 



38-4, 537. 
403, 537. 



384. 

208, 403, 537. 



403, 537, 559. 



384, 403, 443, 451, 466, 537, 559. 

237, 351, 384, 403, 443, 451, 455, 466, 510, 537, 559. 

384, 403, 537, 559. 

403, 537, 559. 

451. 

403, 537, 559. 

384, 403, 455, 537. 

443. 

559. 

384, 443, 455, 559. 

537. 

384, 559. 

384. 

384. 



559. 
537, 
537. 
237, 
461. 
311, 
559. 
403, 
559. 
351, 
237, 
384, 
559. 



559. 
384. 

461, 466, 537. 

537, 559. 

394, 403, 451, 510, 537, 559. 

510, 537, 559. 

403, 443, 451, 455, 466, 537, 559. 



559. 












513. 












403, 


537. 










537. 












537. 












443, 


559. 










384. 












508. 












508. 












508. 












508. 












284, 


508. 










466. 












403, 


510, 


559. 








537. 












559. 












466, 


540. 










537. 












223, 


384, 


403, 


466, 


494, 


537, 559 


443. 












384, 


472. 










537. 












559. 












403, 


443. 










537. 












559. 












106, 


384, 


466. 








384. 












223, 


246, 


403. 








517. 












517. 












517. 












517. 












208, 


335, 


403, 


466, 


477, 


537. 


466, 


524. 











SYNTHETIC ORGANIC CHEMICALS, 1954 



65 



TABLE 7B. --Syntheti 



organic chemicals: Cyclic intermediates for which United States production or sales 
were reported, identified by manufacturer , 1954- -Continued 



Manufacturers' Identification numbers 
(according to list in table 27) 



l-Anlllno-2-anthraqulnoneoarboxylio acid 

2-Anilinoethanol (Phenylethanolamlne) 

l-Anllino-4-hydroxyanthraquinone 

A-Anlllno-4' -hydro xydiphenylamlne 

2-Anillno-4-(8'-hydroxy-3',6'-disulfo-l'-naphthyl- 
amino)-6-('i-p-anlllnosalicylazo)-s-trlazlne. 

•Anllinomethanesulfonlc acid and salt — 

6-Anllino-2-methoxymetaiilllo acid 

»8-Anillno-l-naphthalenesulfonio acid (Phenyl peri 
acid). 

»6-Anilino-l-naphthol-3-sulfonic acid (Phenyl J acid) 

»7-Anilino-l-naphthol-3-sulfonic acid (Phenyl gamma 
acid). 

2-Anilino-5-nitroben2enesulfonic acid 

N-(p-Anillnophenyl)-p-quinone imlne 

Anisic acid 

o-Anisldine 

p-Anisidine 

o-Anisidine nitrate — — • 



o-Anisidinomethanesulfonic acid 

Anlsoin (Aj^'-Dimethoxybenzoin), tech 

Anisole, tech 

Anthracene, refined 

Anthraflavio acid (2,6-Dlhydroxyanthraquinone) 

»Anthranilic acid (o-Aminobenzoic acid) 

»Anthra[l,9]pyrazol-6(2H)-one (Pyrazoleanthrone) 

2-Anthraquinonecarboxylic acid 

N , N '- ( 1 , 5-Anthraquinone ) dioxamic acid 

»1, 5-Anthraquinonedisulf onic acid 

1,5 (and l,8)-Anthraquinonedisulfonic acid and salt — 

»1, 8-Anthraquinonedisulfonic acid 

»l,8-Anthraqulnonedlsulfonic acid, potassium salt 

»2,6-Anthraquinonedisulfonlc acid and salt 

"l-Anthraquinonesulfonic acid and salt 

2-Anthraquinonesulfonio acid and salt (Silver salt)- 
•3-(l-Anthraquinonylamino)-7H-benz[de] anthraoen-7-one 

N, N '-(1, 5-Anthraquinonylene)dianthranilic acid 

1, 1 '-[ 1, 5 (and 1, 8 )-Anthraquinonylenediimino] bis- 

[naphth[2,3-cJacridine-5,8,l'i(13H)-trione]. 
l-( l-Anthraquinonyl )-l, 2-hydrazinedisulf onic ac id, 
disodium salt. 

»Anthrarufln (1,5-Dihydroxyanthraquinone) 

Arsanilic acid and salt, tech — 

<i',<i"'-Azobis[4-biphenylcarboxylic acid], disodium 
salt. 

p,p'-Azodibenzoic acid 

Azoxybenzene 

3,3'-A2oxydianillne 

•Benzaldehyde, tech 

Benzamide- 



A_( ^Benzamido-1-anthraqulnonylamino ) naphth [2 , 3-c] - 
acridine-5 , 8, 1<;( 13H ) -trlone . 

1-Benzamido-i-chloroanthraquinone 

»l-Benzamldo-5-ohloroaiithraquinone 



l-Benzamido-5-chloro-^-methoxyanthraquinone 

5-Benzamldo-4-chloro-o-toluidine [ NHj^l] 

2-Benzamido-p-ore3ol [OH=l] 

2-[3_(4_Benzamido-2,5-diethoxyphenyl)-l-methyl- 

dlazoamlnojethanesulfonlo acid. ' 
2-[3-(i-Benzamido-2,5-dlmethoxyphenyl)-l-methyl- 

diazoamino]ethanesulfonio acid. 
[ 3-(A-Benzamldo-6-methoxy-m-tolyl )-l-methyldiazo- 
amino] acetic acid. 

<i-Benzamldo-5-methyl-o-anlsidlne [ NH2=l] 

8-Benzamldo-l-naphthol-3, 5-disulfonic acid 

6-Benzamldo-l-naphthol-3-sulfonic acid (Benzoyl J 
acid). 

»7H-Benz [de ] anthracen-7-one (Benzanthrone) 

♦Benzene sulfonamide -^- 

Benzenesulfonio acid 

Benzenesulfonlc acid, isopropyl ester- 
Benzenesulfonlc acid, sodium salt _____ 

»Benzenesulfonyl chloride -_— 

Benzhydrol (Dlphenylmethanol) 

Benzidine base- 

»Benzidlne hydrochloride and sulfate- 

Benzll (Blbenzoyl) 

Benzilic acid — 



2-Benzofuryl cyanomethyl ketone- 

♦Benzoic acid, tech 

Benzoin 

Benzonitrile 



A03, 537. 

562. 

537. 

559. 

559. 

<M33, 443, 451, 455, 466, 537, 559. 

559. 

384, 403, 455, 537, 559. 

237, 351, 384, 403, 443, 451, 455, 510, 537, 559. 
384, 403, 443, 455, 466, 537, 559. 



559. 

466, 569. 
537. 

403, 537. 
443. 



508, 584. 

537, 559. 

349, 384, 394, 403, 537. 

384, 401. 

466, 537. 

559. 

369, 384, 403, 466, 537. 

537. 

384. 

369, 384, 403, 466, 537. 

369, 384, 401, 403, 466, 510, 537, 559. 

403, 510, 537. 

384, 401, 466. 



384, 
537. 
141, 
208, 
208, 
334, 
443. 
374. 
537. 
460, 
384, 
335, 
106, 
384, 
466. 
384, 
106, 
537. 
369, 
106, 
106, 
106, 
106, 
106, 
537. 
537. 

384. 



384, 403, 455, 466, 537, 559. 

420. 

537. 

537. 

394. 

443. 

199, 240, 569. 

369, 513. 

537. 

106. 

106, 384, 401, 403, 466, 537. 

384. 

443. 

559. 

384. 

384. 

223, 384. 

443. 
384. 
455, 559. 



92, 
325, 

185. 
537. 
185, 
384, 
374. 
403, 
384, 
305, 
240, 
513. 
199, 
240, 
391, 



106, 369, 384, 401, 403, 455, 466, 510, 537. 
349, 527, 574. 



574. 

527, 559, 574. 

537. 

394, 403, 451, 501, 537, 559. 

569. 

305, 569. 

208, 240, 549, 569. 

569. 

417. 



66 



TABLE 7B.--Synf/iefi 



UNITED STATES TARIFF COMMISSION 

oriianic chemicals: Cyclic intermediates for which United States production or 
were reported, identi tied by manufacturer , i954- -Continued 



Manufacturers' identification numbers 
(according to list in table 27) 



»Benzotrlazole, tech — 

Benzoylacrylic acid 

*o-Benzoylbenzolc ac id — — 

Benzoyl chloride — — — — 

*Benzylajiilne — ~ 

o-Benzyl-p-chlorophenol — — — 

«Benzyl ether (Dibenzyl ether) 

4-(N-Benzyl-N-ethylainino)-o-toluenesulfonic acid 

N-Benzyl-N-ethyl-m-toluidine 

<V-Benzylidlneaminoantipyrine 

■i,<i'-Benzylidinebls[N,N-dlethylanillne] 

<i,4'-Benzylidlnebis[N,N-dimethylanillne] 

2-BenzylpyTidine- 



-i-Benzylpyridine — — 

A, A -Biacetoacetanillde — • — 

N>N-Biacetoacet-o-tolidine — — 

(3,3'-Bianthra[l,9]pyrazole)-6,6'(2H, 2'H)-dione 

(I^azole anthrone yellow). 
(3, 3' -Bianthra[ 1,9] pyrazolone )-6, 6' -dione, potas- 
sium salt. 

(3,3' -Bi-7H-benz [ de ] anthracen )-7, 7' -dione 

«(4,4'_Bi-7H-benz[de]anthracen)-7,7'-dlone 

endo-ciE-Bicyclo[2,2,l]-5-heptene-2,3-dicarboxylio 
anhydride, 

(l,l'-Binaphthalene)-8,8'-dicarboxylio acid 

l,l'-Bl-2-naphthol 

Biphenyl 

2-Biphenylamine (2-Aminoblphenyl) 

p-Biphenyl isocyanate 

•1,4-Bis [l-anthraquinonylamino] anthraquinone 

»3,9-Bis [l-anthraquinonylamino] -7H-benz [de] anthra- 
oen-7-one. 

Bis [l-anthraquinonylamino ]violanthrone 

N,N'-Bis [dehydroabietyl] ethylenediamine dihydro- 
chloride. 

l,l-Bis[2,4-diamino-m-tolyl]ethane 

A^/i'-BisIdiethylamlnoJbenzophenone (Ethyl ketone 
base) . 

2,7-BiE [dlmethylamlno] aoridlne hydrochloride 

»4,ii'-Bis[dlmethylamino]benzhydrol (Michler's hydrol) 
*A, "i '-Bi s [ d tmethylamino ] benzophenone ( Mlohler ' s 
ketone) . 
l,5-Bis[2,A-dinitrophenoxy]-4, 8-dinitroanthraqulnone 

m-Bis[ 2, 3-epoxypropoxy] benzene 

1,2-Bis [l-nitro -2 -anthraquinonylcarbonyl] hydrazine — 
2 , 5-Bis [l-nitro-2-anthraquinonyl ] -1, 3 , li-oxadiazole — 
Bls[4'-(N,3"-sulfobenzyl-N-ethylamino)-2'-tolyl]- 
p-sulfophenyl methane. 

Bit9lylene dilsooyanate 

3,3 -Bitolylene-^,A -dilsooyanate 

m-Bromoacetylphenyl benzoate 

p-Bromoanisole — — — 

»3-Bromo-7H-benz[ de ]anthracen-7-one (Bromobenz- 
anthrone) . 

Bromobenzene, mono — 

A-Bromobenzophenone — 

(2-Bromoethyl)benzene -___- 

l-Bromo-A-methylamlnoanthraquinone — 

"i-Bromo-l-methylaminoanthraquinone 

2-Bromo-3-methylanthraquinone — 

6-Bromo-3-methyl-7H-dibenz (f , 1 J )lsoquinoline-2, 7- 
(3H)-dione. 

1-Bromonaphthalene — — 

a-Bromo-p-nitroacetophenone 

2-Bromo— 4-phenylphenol — — -— — — 

2-Bromopyridine- 



o-(3-BroiQ0-p-tolyl )benzoic acid 

l-BroinD-2 , A, 6-triethylbenzene 

2-tert-Butylanthraquinone _____ 

Butyl -m-cre sol 

3-tert-Butyl-p-cymene — — — 

6-tert-Butyl-2,i-dimethylacetophenone 

N^-Butyl-^-methoJtymetanilamide — ■ 

2-tert-Butyl-5-methylanisole 



223, 3^9, 38-4, 480. 

'M)3. 

384, 403, 466, 537. 

199, 549. 

141, 145, 477. 

208. 

188, 501. 

240, 355, 374. 

403. 

403, 537. 

247. 

399. 

399. 

549. 

508. 

508. 

443. 

394. 

106, 38A. 

537. 

401, 537. 

106, 369, 384, 401, 403, 537. 

403. 

208. 

384, 403, 537. 

417. 

208, 335. 

208. 

208. 

106, 384, 401, 403, 466, 537. 

106, 369, 384, 401, 403, 466. 

384. 
420. 

443. 

223, 399, 537. 

4A3. 

384, 399, 537. 

223, 384, 399, 403, 537. 

537. 
495. 
537. 
537. 
559. 

394. 
403. 
223. 
141. 
106, 369, 384, 401, 403, 510, 537. 

263, 310, 335. 

141. 

537. 

384. 

537. 

369, 384. 

537. 

369. 

513. 

335, 384. 

335, 513. 

335. 

508. 

537. 

537. 

537. 

384, 537. 

458. 

458. 

458. 

460. 

395. 

395. 

384. 

395. 



SYNTHETIC ORGANIC CHEMICALS, \95U 

-Synthetic organic chemicals: Cyclic intermediates for which United States producti 
were reported, identified by manufacturer , 1954- -Continued 



67 



p-tert-Butylphenol 

5-tert-BQtyl-m-xylene 

Carbazole, refined — -— — 

p-(3-CarbaBolylamino)phenol 

2,4 '-Carbonyldlbenzoio acid-— 

0,0 '-Carbonyldloxydibenzolc acid, diethyl ester 

2(aiid 6)-Carbo)cybenzene-4(and 2)-dlazo-l-oxlde 

'3-Carboxy-2(and A)-hydroxybenzenedlazonluni sulfate — 
3-Carboxyinethyl-l-(5-chloro-o-iiiethoxyphenyl)-3- 

methyltrlazene . 
3-Carboxymethyl-l-(5-chloro-o-tolyl)-3-methyl- 

trlazene. 

Chelldamic acid 

Chlorendic acid 

Chlorendic anhydride 

o-Chloroaoetoaoetanillde — — — — 

<i'-(Chloroaoetyl)acetanilide 

Chloroacetyloatechol — ~- — — 

m-Chloroaniline _— — — — 

o-Chloroanlline ■ 

2-(Chloroanilino)ethanol 

-;-Chloro-o-anisidine [ NH2=1] 

5-Chloro-o-anisldine [NH2=1] ('i-Chloro-c-anlsidine ) 
[0CH3 = l]. 

i-Chloroanthranllio acid 

»l-Chloroanthraqul-none — — • — — 

•2-Chloroanthraqulnone 

l-Chloro-2-anthraquinonecarboxylic acid 

o-Chlorobenzaldehyde 

p-Chlorobenzaldehyde 

Chloro-7H-benz [del anthraoen-7-one (Chlorobenzan- 
throne ) . 
•Chlorobenzene, mono—- 



Manufacturers' identification numbers 
(according to list in table 27) 



335, 5i6. 

5-^6. 

567. 

395. 

508, 537. 

537. 

466. 

335. 

537. 

384, 403. 

537. 

537. 



p-Chlorobenzenesulfonlc acid —— 

4-Chlorobenzhydrol 

p-Chlorobenzhydryl chloride • 

o-Chlorobenzoic ac id- 

p-Chlorobenzoic acid— 

Chlorobenzophenone — 

2-Chlorobenzothiazole 

5-Chloro-2 (3H )-benzoxazolone ^ 

o-(m-Chlorobenzoyl)benzoie acid 

»o-(p-Chlorobenzoyl )benzoio acid 

p-Chlorobenzoyl chloride ^ 

p-Chloro-o-cresol 

N-(3-Chloro-9, lO-dihydroxy-2-anthranyl jacetamide- 
biE[acid sulfate]. 

5 -Chloro-2 , 4-d imethoxyaniline 

6-Chloro-l,2-dliiiethoxy-4-nitrobenzene 

5-Chloro-4,7-dimethyl-3(2H)-thianaphthenone 

»l-Chloro-2, 4-dinltrobenzene (Dinitrochloro benzene ) — 

2-Chloro-3,5-dinitrobenzenesulfohethylamide 

2-Chloro-3, 5-dinitrobenzenesulfonyl chloride 

4-Chloro-3,5-dinltrobenzolc acid 

6-Chloro-2,4-dinitrophenol 

2-Chloro-N-ethyl-5-nitrobenzenesulfonanilide 

2-Chloroethyl-p-toluenesulfonate 

p-Chloroethyl-p-toluenesulfonic acid, sodium salt — 

5-Chloro-2-fonnylbenzenesulfonio acid 

4-Chloro-3-hydrazinobenzenesulfonic acid 

4-Chlorometanllic acid 

5-Chlorometanilio acid 

•6-Chlorometanilic acid 

[3-(5.Chloro-2-methoxyphenyl)-.l-methyldiazoaminol- 
acetio acid. 

*l-Chloro-2-methylanthraquinone— — — — 

6-Chloro-4.-methylbenzo-l, 3-thiaza-2-thionium chlo- 
ride. 

Chloronaphthalenes 

8-Chloro-l-naphthalene3ulfonlc acid, sodium salt 

8-Chloro-l-naphthalenesulfonyl chloride 

8-Chloro-l-naphthol-3,D-disulfonic acid (Chloro H 
acid). 

9-Chloronaphtho [l, 2-b] thiophen-3 (2H )-one 

8-Chloro-l-naphthylmercaptoacetic acid — 

»2-Chloro-4-nitroaniline (o-Chloro-p-nitroaniline) 

«4-Chloro-2-nitroaniline (p-Chloro-o-nltroaniline) 

4-Chloro-2-nitroanisole 

»l-Chloro-5-nitroanthraquinone 



247. 












549. 












549. 












415, 562. 












537. 












247. 












208, 384, 


403, 


537. 








208, 461, 


537. 










208, 537. 












495. 












384. 












384, 461. 












487, 537. 












369, 384, 


403, 


466, 


510, 


537. 




384, 403, 


466. 










537. 












403, 569. 












403, 569. 












466. 












123, 208, 


312, 


335, 


363, 


475, 506, 


537 


384, 451. 












420. 












561. 












569. 












569. 












561. 












513. 












384. 












466. 












384, 403, 


537. 










569. 












549. 












537. 












384. 












384, 575. 












384. 












487, 537. 












208, 384, 


403, 


466, 


510, 


537. 




495. 












495. 












X. 












443. 












384. 












384. 












403. 












384. 












384. 












384, 537 












403. 












384, 403, 


494 


537, 


559 






384. 












106, 384, 


403, 


455, 


466, 


537. 




537. 












546. 












384. 












384. 












403. 












384. 












384. 












335, 444 


466 


472, 


510, 


537. 




335, 461 


537 










384. 












106, 401 


403 


537 









549, 574. 



68 



TABLE 7B. --Syntheti 



UNITED STATES TARIFF COMMISSION 

rganic chemicals: Cyclic intermediates for which United State 
were reported, identified by manufacturer, J954- -Continued 



production or sale 



l-Chloro-8-nitroanthraquinone 

l-Chloro-2 -nitrobenzene (Chloro-o-nitrobenzene) 

l-Chloro-2(and 'i)-nitrobenzene (Chloronitrobenzenes, 
o- and P-). 

l-Chloro-3-nitrobenzene (Chloro-m-nitrobenzene) 

l-Chloro-<i-nitrobenzene (Chloro-p-nitrobenzene) 

»'i-Chloro-3-nitrobenzeneEulfonaiiiide 

»2-Chloro-5-nitrobenzenesulfonio acid 

2-Chloro-5-nitrobenzeneEulfonlc acid, magnesium salt 

2-Chloro-5-nitrobenzenesulfonio acid, sodium salt 

'i-Chloro-2-nltrobenzenesulfonio acid 

"i-Chloro-S-nitrobenzenesulfonic acid 

2-Chloro-5-nitrobenzenesulfonyl chloride 

4-Chloro-3-nitrobenzenesulfonyl chloride 

2-Chloro-5-nitrobenzoic acid 

5 -Chloro-6-ni tro-2 ( 3H ) -benzoxazolone 

o- ( ^-Chloro-3 -nitrobenzoyl )benzoic ao id 

»A-Chloro-2-nitrophenol 

<i-Chloro-2-nitro-l-phenol-6-sulfonic acid 

A-Chloro-2-nitrophenyl ether 

2-Chloro-5-nitrophenyliiiethylsulfone 

2-Chloro-^nitro toluene — 

'i-Chloro-2-nitro toluene 

'4-Chloro-3-nitro toluene — 

6-Chloro-2-nltro toluene 

o-Chlorophenol' 



Manufacturers' identification numbers 
(according to list in table 27) 



5-Chloro-2-phenoxyaniline 

» (p-Chlorophenyl )aoetonitrile 

l-(m-Chlorophenyl)-3-methyl-5-pyrazolone 

4-Chlorophthalic ac id 

Chlorophthalic anhydride 

2-Chloropyrldine 

6-Chloroquinaldine — 

»2-Chloroquinizarln — — 

5-Chloro-8-quinollnol — 

6-Chloroquinophthalone 

2-Chloro-5-sulfobenzoic acid 

1- (6-Chloro-3-sulfophenyl )-3-methyl-5-pyrazolone 

8-Chlorotheophylline 

m-Chloro toluene 

o-Chloro toluene 

p-Chloro toluene 

»o-Chlorotoluene (Benzyl chloride) 

3-Chloro-o-toluidine [ NHjrl] 

3-Chloro-p-toluidine [ NH2=1] 

«A-Cbloro-o-toluidine [NH2=1J (Fast red TR base) 

5-Chloro-o-toluidine [NH2=1] (Red KB base) 

4-Chloro-o-toluidlne hydrochloride [NH2=1] 

•5-Chloro-o-toluidine hydrochloride [NH2=1] 

5-Chloro-o-toluidine sulfate [NH2=1] 

i-Chloro-o-tolyl ethyl xanthate 

*^-Chloro-o-tolylmercaptoacetic ac id 

[ 3- (5-Chloro-o-tolyl )-l-methyldiazoamino ] acetic acid 
2-[3-('i-Chloro-o-tolyl)-l-methyldiazoamino]ethane- 

sulfonic acid. 
l-(5-Chloro-o-tolyl)-3-methyl-3-triazenoacetic acid- 

i-Chloro-a , a, a-trifluoro-3-nitro toluene 

i-Chloro-c.aia-trifluorotoluene 

Chlorotriphenylsilane 

<l-Chloro-2,5-xylenesulfonyl chloride 

4-Chloro-2,5-xylylniercaptoacetic acid 

Chrysazin (1, 8-Dihydroxyanthraquinone ) 

s-Collidlne (2,4,6-TrlmethylpyTidine) 

»Cresols:^ 

p-Cresol — 

»Cresols, mixed :^ 

Cresol (ortho, meta, para) 

2,3-Cresotic acid 

»Cresylic acid, refined 

»Cumene 

p-((2-Cyanoethyl)niethylamino]benzaldehyde 

8-Cyano-l-naphthalenesulf onlc ac id 

8-Cyano-l-naphthalenesulfonic acid, sodium salt 

Cyanuric chloride 

Cyclohexane-l,2-dicarboxyllc anhydride (Hexahydro- 

phthalic anhydride). 
Cyolohexanol 



AOl, 4.03, 537. 
208, 537. 
311, 537. 



208. 
208, 
495, 
384, 
537. 
495, 
559. 
384, 
495. 
495, 
403. 
384. 
384, 
366, 
559. 
443. 
495. 
384, 
384, 
510. 
537. 
208, 
208, 
443. 
141, 
443. 
537. 
208. 
313, 
537. 
366, 
559. 
537. 
334, 
384, 
327. 
549. 
403, 
403, 
199, 
384, 
384, 
160, 
223, 
384, 
223, 
403, 
384. 
384, 
384. 
384. 



510, 537. 
510, 537. 
403, 451, 455, 510, 559. 

537. 

403, U3, 451. 

537. 



403. 
384, 559. 



537. 
403, 537. 



355, 396, 484. 



484. 

369, 403, 559. 



443. 
537. 



569. 

569. 

208, 240, 549, 569. 

403, 537. 

537. 

403, 466, 510, 575. 

384, 403, 537. 

537. 

401, 466, 537, 576. 

575. 

403, 466, 487, 537. 



384. 

384. 

549. 

134. 

384. 

384, 487. 

384, 487, 537. 

384, 537. 

460, 508, 584. 

460. 

466, 507, 508. 

494. 

466, 507, 508, 509, 584. 

460, 466, 507, 584. 

335, 403. 

142, 344, 391, 460, 466, 507, 508, 509, 518, 564, 584. 

335, 564, 584. 

537. 

384. 

537. 

1, 466. 

261, 459, 518, 537, 584. 

403. 

335, 403, 537, 549. 



See footnote at end of table. 



TABLE 7B. --Syntheti 



SYNTHETIC ORGANIC CHEMICALS, 1954 

rganic chemicals: Cyclic intermediates for which United States production 
were reported, identified by manufacturer , 1954- -Continued 



69 



Manufacturers' Identification numbers 
(according to list in table 27) 



Cyolohexanone 

Cyclohexanone oxime 

Cyclohexene 

Cyclohexene-l,2-dicarboximide 

Cyclohexene-l,2-dicarboxyllc anhydride (Tetra- 
hydrophthalic anhydride). 

Cyolohexyl-2-prcpanone — 

Cyclopentadiene 

Cyclopentadiene and methylcyclopentadiene, mixed 

Decylbenzene — 

*1,4-Diaminoanthraquinone _— — — 

*1, 5-Di ami noanthraqui none — 

1, 5 (and 1, 8) -Diaminoanthraquinone — 

»2,6-Diaminoanthraquinone ~ 

1, <*-Diamino-2,3-anthraquinonedicarbonitrile — 

1, 'i-Diamino-2,3-anthraquinonedicarboximide 

l,'+-Diamino-2, 3 -an thraquinonedi sulfonic acid 

4, S-Diaminoanthraruf in 

4,^'-Dianilnoben2aiiiidodiphenylurea-3,3'-diaulfonic 

acid. 
3 , 4-Diaminobenzanilide 

•2,4-Diaminobenzenesulfonic acid [S03H=1] 

2,5-Diaminobenzenesulfonic acid [S03H=1] — • 

4, <l '-Dlamino-2 , 2 '-biphenyld isulf onic ao id 

•'i,4'-Diamino-3, 3 '-biphenyldisulfonic acid 

X,X'-Diamino(3,3'-bis-7H-benz [de] anthraoen-7, 7' - 
dione. 

»2,2'-Diamino-5,5'-bi-m-toluenesulfonic acid 

l,4-Diamino-2,3-dichloroanthraquinone 

4, 4' -Diamino-2, 2 ' -dimethylbiphenyl — 

i, 4'-Diamino-5, 5 ' -dimethyl-2 , 2 ' -biphenyldisulfonic 
acid. 

"i, 4' -Diamino-3, 3 ' -dimethyl triphenylmethane 

A, W -Diaminodiphenylamine sulfate 

»4, 4' -Diaminodiphenylamine-2 -sulfonic acid — 

4 , A ' -Diaminodipheny 1 sul f one 

5, 6-Diamino-l-naphthalenesulf onic acid 

1, 4-Diamino-5-nitroanthraquinone -- 

N, N' -Di (m-aminophenyl )oxajnide 

N, N'-Di (p-aminophenyl )oxamide 

2,6-Diaminopyridine 

»4,'i'-Diamino-2,2'-stilbenedisulfonic acid 

4-, 6-Diamino-m-toluenesulfonic acid [S03H=1] 

2 , 4-Di-sec-amylphenol 

2,4-Dl-tert-aa(ylphenol 

•1, 5-Dianilino-2,6-anthraquinonedlcarboxylic acid 

2,'i-Dianillno-l-hydroxyanthraquinone 

Dianisldlne diisooyanate — — 

4-Diazo-2,5-dichlorobenzenesulfonlc acid [sOsH^l] 

1, 5-Dibenzamidoanthraquinone 

»4,5'-Dibenzamido-l, I'-iminodianthraquinone 

U, 5 '-Dibenzamido-4 '-methoxy-1, 1 '-Iminodianthra- 
quinone . 

*1, 5-Dibenzoylnaphthalene 

N, N'-Dibenzylethylenediamine diacetate •* 

»3, 9-Dibromo-7H-benz [de] anthraoen-7-one 

p-Dibromobenzene 

1, 3-Dibromo-5,5-dimethylhydantoin 

5,5 '-Dibromoind igot in 

2, 6-Dibromo-l, 5-naphthalenediol — 

Dibromo-8,16-pyTanthrenedione ~ 

Dibromoviolanthrone 

*2,5-Dichloroaniline and hydrochloride [NH2=1] 

3, A-Dichloro aniline 

»l,5-Dlchloroanthraqulnone 

1, 5 ( and 1, 8 )-Dichloroanthraquinone 

*l,8-Dichloroanthraquinone — 

2,6-Dichlorobenzaldehyde 

*o-Dichlorobenzene — 



403, 537. 

403. 

261 

403 

403 



( and p ) -Dichlorobenzene 

*p-Dichlorobenzene 

»3,3'-Dichlorobenzidine base and salts 

2, 4-Dichlorobenzoic ac id 

2, 5-Dlchlorobenzoic acid 

2,4-Dichlorobenzoyl chloride 

N,N'-(2,5-Diohloro-3,6-dioxo-p-phenylene)bis[6- 
(2(3H)-oxo-5-benzlmidazolylamino)metanilic acid]. 

Dichlorodiphenylsilane 

2,5-Dichloro-4-hydrazinobenzenesulfonie acid 

4, 5-Dlchlorometanilic acid 



X. 



384, 401, 403, 537, 565. 

384, 537. 

537. 

369, 384, 403, 466, 510, 537. 



403, 537, 
559. 
394. 
510, 559. 



510, 559. 



443, 446, 451, 455, 510, 559. 
443. 



451. 
508. 
403, 443, 466, 537, 559, 595. 



384, 403. 
384, 559. 



537. 

384, 401, 403, 466, 537. 



117, 369, 384. 

240. 

369, 384, 403, 466, 537. 



384, 403, 461, 537, 559. 

537. 

369, 384, 403, 537. 

369, 384, 537. 
403. 

208, 331, 335, 358, 475, 537, 549. 

358, 506, 574. 

208, 331, 335, 358, 475, 537, 549. 

384, 394, 494, 537, 559, X. 

569. 



70 



TABLE 7B. --Syntheti 



UNITED STATES TARIFF COMMISSION 

rganic chemicals: Cyclic intermediates for which United States production or sale 
were reported, identified by manufacturer, 1954- -Continued 



Manufacturers' Identification numbers 
(according to list in table 27) 



Diohloromethylphenylsilane» ~ 

2 , 6-Dichlorc-'i-nitro aniline » 

4,5-Dichloro-l-nitroanthraqulnone — 

l,2-Dlchloro-4-nitrobenzene — 

«1, 4-Dichloro-2 -nitrobenzene (Nitro-p-dichloro- 
benzene) . 

«2,'l-Dichlorophenol • ~T"~ 

2-[3-(2,5-Dichlorophenyl)-l-ethyldlazoamino]-5-sul- 

fobenzoic acid. 

2,5-Dlchlorophenylhydrazine — 

^,7-Dichloroqulnoline 

o-(3,5-Dichlorosalicyloyl)benzoic acid 

2,5-Dichlorosulfanilio acid [S03H=l] 

»l-(2,5-Dichloro-4.-sulfophenyl)-3-iiiethyl-5-pyrazolone 

p,a-Dichloro toluene ~ " 

a,a-Diohlorotoluene (Benzal chloride) 

2, 4-Dichloro toluene 

2,6-Diohlorotoluene * 

3 , i-Dichloro toluene ' 

Dicyclohexylamine — — ■•-- "" 

Dicyclopentadiene ' — ■- ~ 

2, 5-Diethoxy aniline — ' 

3,<t-Diethoxybenzaldehyde ■^- — 

2 ' , 5 ' -Diethoxybenzanilide 

2 ' , 5 ' -Diethoxy-A '-nitrobenzanilide-r 

Diethoxynitrobenzene 

p-Diethylaminobenzaldehyde — • ~~ 

N,N-Diethyl-3-aiiiinophenol 

•N,N-Dlethylaniline 

N, N-Diethyl-m-anisldine 

Diethylbenzene ~ 

N, N-Diethylcyolohexylamine 

N,N-Diethylmetanilic acid, and salt 

Ni,lP--Diethyl-i-methoxymetanilamlde 

N, N-Diethyl-1-naphthylamine ' 

N,N-Diethyl-p-nltrosoaniline 

N,N-Diethyl-p-phenylenediamine ■- 

5-Diethylsulfajjyl-o-acetanisidlde 

2-(3- [5-(N,N-Diethylsulfonyl)-o-inethoxyphenyl]-l- 
ethyldlazoamlno)-5-sulfobenzoic acid. 

Diethylterephthaloyl diacetate 

N, N-Diethyltetrahydrophthalamic acid 

N, N-Diethyl-m-toluidine 

N- (2, 2-Dif luoroethyl )aniline 

2-(N-2,2-Dlfluoroethylanilino)ethanol 

2 , 3-Dihydro-l, A-bis (methylamino )anthraquinone 

2,3-Dihydropyran 

1, 5 ( and 1, 8 )-Dihydroxyanthraquinone 

i'-l Di-P-hydroxyethylamino ) -2 ' -tolylanillno-3- 

sulfonic acid. 
i,5-Dihydroxy-2,7-naphthalenedisulfonlo acid (Chro- 

motropic acid). 
»i;,5-Dihydroxy-l-naphthalenesulfonic acid (Dioxy S 

acid). 

»6,7-Dihydroxy-2-naphthalenesulfonic acid 

3, 5-Dlhydroxy-2 -naphthoic acid 

»16, 17-Dlhydroxyviolanthrone (Dihydroxydibenzan- 
throne ) . 

Diisobutyl-o-cresol 

2,4-Diniethoxyacetophenone — 

2,5-Dimethoxyacetophenone 

2,5-Dimethoxyaniline 

»m-Dlinethoxy benzene 

p-Dimethoxy benzene 

«3,3' -Dtmethoxybenzidine 



134. 

38<l, 495. 

384. 

537. 

208, 384, 403, 461, 510, 537, 559. 

208, 335, 389, 410. 
384. 



443. 
440. 
403. 
403, 
443, 
569. 
549, 
569. 
403, 
569. 
208. 
423. 
384. 
141. 
384. 
384. 
495. 
384, 
384, 
223, 
537. 
335, 
537. 
537. 
384. 
537. 
384. 
403. 
384. 
384. 



443. 

455, 537, 559. 



403, 537. 
466, 537. 
399, 403, 466, 537. 



2,4-Dimethoxybenzolc acid 

2 , 5 -Dlmethoxybenzolc ac id ■ ■ 

2,2'-[3,3'-(3,3'-Dimethoxy-4,4'-biphenylene)) bis U- 

methyldiazoaiiiino]di(ethanesulfonic acid). 
1, 1' - (3 , 3 ' -Dijiiethoxy-4, 4' -biphenylene )bls [3-methyl- 
3- (2-sulf oethy 1 )triazene ] . 

l,4-Dl]iiethoxy-2 -nitrobenzene 

3,4-Dimethoxyphenethylamlne (Homoveratrylamlne) 

16,17-Dlmethoxyvlolanthrone 

p-Dlmethylamlnobenzaldehyde 

o-(Dimethylaminomethyl)-p-butylphenol 

o-(Dljiiethylamlnomethyl)-p-octylphenol 

o- ( Dime thy laminome thy 1 )phenol 

m-Dimethylaminophenol 

N-(p-Dimethylaminophenyl)-l,4-naphthoquinone imine- 

»N,N-Dimethylaniline 

N, N-Dimethylbenzylamlne 

»2 , 2 ' -Dimethyl-1, 1 ' -bianthraquinone 



384. 

403. 

403, 537. 

495. 

495. 

537. 

537. 

537. 

495. 

366, 403, 559. 

510, 537, 559. 

280, 313, 384, 403, 480. 

160, 223, 384, 537. 

106, 369, 384, 401, 403, 455, 537. 



417, 


501. 






537. 








141. 








384. 








384, 


466, 


537. 




141, 


537. 






394, 


537, 


559. 




466, 


537. 






141. 








384. 








537. 








495. 








141, 


208, 


274. 




401. 








403. 








417. 








417. 








417. 








453. 








403. 








223, 


399, 


403, 


466, 537 


141, 


349, 


417. 




106, 


403, 


466, 


537. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



71 



TAW F 73. -'Synthetic organic chemicals: Cyclic intermediates for which United States production 
were reported, identified by manufacturer , i954--Continued 



Manufacturers' identification numbers 
(according to list in table 27) 



2',7'-Diinethylfluoran 

5,5-Diinethyliiydantoin 

2,8-Dlmethyl-13P-hydroxy-9(13P)-ceroxenone 

2, 3-Diiiiethyl indole 

N, N-Dimethyl-l-naphthylamine 

N, N-Dimethyl-p-nltrosoaniline 

N, N-Dimethyl-p-phenylenediamine and salts 

2,6-Diinethylpicoline 

2-[3-(5-Dimethylsulfaiiiyl-o-tolyl)-l-iiiethyldlazo- 

amino]-5-sulfobenzoic acid. 
N,N-Dimethylsulfanilic acid- 



2,7-Dlmethyltetrahydroquinollne 

N, N-Dlmethyl-p-toluidine 

2,<V-Dinitroaniline- 



•p-(2,'4-Dinitroanilino)phenol (Dinitrohydroxyphenyl- 
amine). 
2,'4-Dinitroaiiisole- 



sidi — 



1, 5 ( and 1,8) -Dinitroanthr aquinone 

N, N'-(2,'4-Dinitroanthraquinone)-l,5-dioxainic 
3,^'-Dlnitroben2anilide 

2,^-Dlnitrobenzenesulfonic acid 

3,5-Dinitrobenzolc acid 

Dinitro (3,3' -bi-7H-benz(de] anthraoen) -7, 7 '-dione 

4,5-Dinitroohrysazin 

4,5-Dinitrochrysazin-2,7-disulfonio acid, dlsodium 
salt. 

2 , "i-Dinitrod iphenylamine 

1, 5 ( and 1, 8 )-Dinitronaphthalene 

2,'i-Dinitro-l-naphthol — 

2,4-Dinitrophenol, tech- 



N, N' -Dl (p-nitrophenyl )oxaDiide 

p-Dinitrosobenzene 

»i,A '-Dinitro-2,2 '-stilbenedisulfonic acid 

2, "i-Dinitro toluene 

Dinitro toluenes, mixed 

Dipentene (Limonene ) — ___ 

1,5-Diphenoxyaiithraquinone 

1, S-Diphenoxyanthraquinone 

Dlphenylacetic acid- 



Diphenylacetonitrile 

Diphenylamine 

»6,8-Diphenylaiiiino-l-naphthalenesulfonic acid 

l,'i-Diphenyl-2-butaiie-l, "i-dione 

sym-N, N '-Diphenylethylenediamine 

Diphenylolpropane 

1,3-Diphenyltriazine 

Dithiodibenzoic acid 

*1, "i-Di ( p-toluid ino ) an thraquinone 

l,5-Di(p-toluidino)aiithraquinone 

Divinylbenzene 

•Dodeoylbenzene (includes keryl-type benzenes) 

6-Ethoxy-2-iDercaptobenzothiazole 

3(and •4)-Ethoxy-i(and 3 )-methoxybenzaldehyde 

a-(<l-Ethoxy-3-methoxyphenyl)acetamlde 

6-Ethoxy-2-naphthalenesulfonio acid 

3-Ethylami no-p-cresol 

3-Ethylaiiiino-p-toluenesulfonic acid [S03H=l] 

N-Ethy lanl 1 ine , refined 

»2-(N-Ethylanilino)ethanol 

a-(N-Ethylanilino )-iD-toluenesulfonic acid 

*a-(N-Ethylanilino)-p-toluenesulfonic acid 

2-Ethylaiithraqulnone 

N-Ethyldibenzylamine diacetate 

EthylenediaMne dibenzyl diacetate 

2-[l-Ethyl-3-(2-methoxy-5-nitrophenyl)diazo amino ]-5- 
sulfobenzoic acid. 

N-Ethyl-1-naphthylamine 

N-Ethyl-N-1-naphthyl-o-nitrobenz amide 

1-Ethyl -2 -nitrobenzene 

N-Ethy 1-2 -nitrobenzenesulfonanilide 

p-Ethylphenol 

•N-Ethy 1-N-phenylbenzylamine (N, N-Ethylbenzylauiline )- 

Ethylphenylmalonic acid, diethyl ester 

5-Ethyl-2-picoline (2-Methyl-5-ethylpyridine) (MEP)— 

l-Ethylplperidine 

2-Ethylpyridine 

N-Ethyl-5-sulfoanthranilic acid 

N-Ethyl-m-toluidine 



537. 

11. 

537. 

513. 

313, 384, 403, 466. 

403. 

508. 

384. 

384. 

495. 

513. 

208, 466. 

384, 403, 537. 

461. 

537. 

559. 

537. 

384, 403, 537. 

384, 559. 

513, 537. 

401, 537. 

384, 495, 537. 

537. 



495. 

384. 

501. 

403, 

451. 

501. 

223, 

403, 

403. 

31. 

537. 

495. 

240. 



384, 403, 455, 537, 559. 
537. 



335, 403, 537. 
403, 559. 



537. 

384, 403, 487, 537, 559. 

460. 

208, 403, 439, 544, 564. 



466, 537. 

384, 495, 537, 559, 562. 



403, 443, 466, 559. 

208, 261, 335, 460, 562, 584. 



40. 

208, 

384, 

403. 

537, 

417. 

403, 

349. 

369, 

369. 

335, 

208. 

189, 

537. 

208. 

208. 

443. 

537. 

537. 

208. 

403, 

223, 

537. 

246, 

495. 

403. 

204, 

561. 

561. 

384. 



399, 537. 

384.' 

208. 

559. 

494. 

223, 403, 537. 

240, 247, 327. 

562. 

540. 

508. 

384. 

403, 538. 



72 



TABLE 7B. --Synf/ietj 



UNITED STATES TARIFF COMMISSION 

rganic chemicals: Cyclic intermediates for which United States product i 
were reported, identified by manufacturer, J954- -Continued 



N-Ethyl-o-toluldine 

a-(N-Ethyl-m-toluidlno)-m-toluenesulfonic acid 

5-Ethyl-2-vlnylpyTidlne 

Ethynylcyclohexanol 

Fluorene 

Formanilide ■* 



o-Formotoluidlde 

-l-Forinyl-ni-benzenedlsulfonio acid 

m-Fonnylbenzenesulfonic acid 

»o-Fonnylbenzenesulfonlc acid (o-Sulfobenzaldehyde) 

Furfuryl alcohol 

3-Glycyl-3-methyl-l-(6-methoicy-m-tolyl)-trlazene 

Hexachlorobenzene ' 

Hexachlorocyclopentadiene 

Hexaohlorodiphenyl oxide' 



ojaja<o'<a'>a'-Haxachloro-p-xylene 

1,6-Hexane dlisooyanate 

Homoveratric acid 

Homoveratronitrile 



Homoveratryl amine homoveratrate 

»p-Hydrazinobenzenesuironic acid 

3-Hydrazino-5-nitro-p-toluenesulfonic acid [SOsH^l] — 

4-Ifydrazino-m-toluenesulfonio acid 

Hydroabietyl alcohol 

Hydroquinone, tech 

m-Hydroxyacetophenone 

o-Hydroxyacetophenone — ~ 

p-Hydroxyacetophenone 

Hydro xyanilinoethanol 



Manufacturers' identification numbers 
(according to list in table 27) 



1-Hydroxyanthraquinone 

N- ( 3 -Hydroxy-2 -anthraquinony 1 )-l-nitro-2-anthra- 
quinonecarboxamide , 

p-Hydroxybenzenearsonic acid 

2-Hydroxy-ll-benzo-a-carbazole-3-carboxylic acid 

p-Hydroxybenzoic acid 

p-Hydroxybenzoic acid, benzyl ester 

p-Hydroxybenzoic acid, butyl ester 

p-Hydroxybenzoic acid, ethyl eater — — — 

p-Hydroxybenzoic acid, methyl ester 

p-Hydroxybenzoic acid, propyl ester — ' 

2-Hydroxycarbazole 

2-Hydrcx^-3-oarba'^^leca^boxylic acid 

2-Hydroxy-3,6,?-ojibazoletrisulfonic acid 

'V-Hydroxycoumarln — 

2-Hydroxy-3-dibenzofurancaTboxylic acid, potassium 
salt. 

l-Hydroxyisobutylphenoxypropylene oxide 

3-Hydroxy-2-methylcinchonlnlc acid 

3-Hydroxy-2'-methylnaphthanilide 

2-Hydroxy-l-naphthaldehyde 

3-Hydroxy-2-naphthanilide 

l-Hydroxy-2 -naphthoic acid 

»3-Hydroxy-2-naphthoic acid (B.O.N.) 

2-Hydroxy-l,*-naphthoquinone 

N-(7-Hydroxy-l-naphthyl)acetamide 

2-(2-Hydroxynaphthyl)-3-thianaphthenol 

1-Hydroxy-^nitroanthraqulnone 

"4-Hydroxy-3-nitro-l-benzenearsonlc acid 

3-Hydroxy-3'-nitro-2-naphthanilide— 

Hydro xynltroviolan throne 

2-Hydroxyphenetole 

N-(p-Hydroxyphenyl)-2-naphthylamlne 

p-Hydroxypropiophenone — 

l-Hydroxy-4- (p-toluidino ) anthraquinone 

1, 1' -Iminobls 4-amlnoanthraquinone 1 — — 

'/»-benzamidoanthraquinone 1 

5-benzamidoanthraquinone J 

l-naphthol-3 -sulfonic ac id J 

^A-nitroanthraquinone] 

•l.l'-Iminodianthraquinone (Dianthrlmide) 

2,2 ' -Iminod ipyrid Ine 

2,2'-(l,3-Indandione)quinoline (Quinophthalone) 

Indolineacetaldehyde (Fisher's aldehyde) 

Isatin — — — ~ 

Isocytosine (2-Amino-4(3H)-pyriiEidone) 

Isonicotinic acid ~ 



l,l'-Imlnobls 
»1, I'-Imlnobis 
»6,6'-Iml nobis 
•l,l'-Imi nobis 



Isonitrosopropiophenone 

Isophorone — 

<i,4'-Isopropylidenediphenol (Bisphenol A)- 

Isopropylphenol — — 

4-Isopropylpyridine — — — 

Isoquinol ine — _ 

» I sovio Ian throne (Isodibenzanthrone) — 



223, 'M)3, 537. 

537. 

508. 

226. 

508. 

537. 

537. 

38A. 

38A. 

200, 223, 3SA, U3, 537, 

537. 

289. 

537. 

410. 

5<V9. 

335. 

549. 

537. 

208, 274. 

274. 

141. 

267, 384, 403, 443, 466, 537. 

246. 

384. 

214. 

295, 495. 

223, 335, 501. 

396. 

335, 396, 501. 

495. 

403, 559. 

384. 

420. 

160, 384, 537. 

394, 569. 

569. 

569. 

569. 

141, 569. 

569. 

384. 

384. 

384. 

420, 466. 

384. 

495. 

537. 

494. 

396. 

160, 223, 384, 494, 576. 

160. 

160, 384, 403, 444, 487, 494, 537, 569, 576. 

403. 

537. 

559. 

559. 

420. 

494. 

466. 

208. 

384. 

191. 

369. 

106, 369, 384, 401, 466, 537, 559. 

401, 466. 

106, 384, 401, 537. 

384, 403, 443, 451, 455, 537, 559. 

106, 369, 401, 537, 559. 

106, 369, 384, 401, 403, 466, 537. 

508. 

537. 

584. 

537. 

403. 

466. 

508. 

141. 

562. 

335, 567. 

460. 

508. 

508. 

106, 369, 384, 401, 537. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



73 



TABLE 7B. -Synthetic 



rganic chemical 
were reported, 



: Cyclic intermediates for which United States product i 
identified by manufacturer, i954--Continued 



•Leuco-l^-i-cliaminoanthraquinone 

»Leuco qulnlzarin (1,4,9, 10-Anthratetrol) 

Leuco tetrahydroxyanthraquinone 

2,3-Lutidlne 

2, 6-Lutid ine — 

Melamine 

o-Mercaptobenzoic ac id 

*Metanilic acid (m-Ajninobenzenesulfonic acid) 

«o-Methoxyanilinomethanesulfonic acid 

•o-Methoxyanilinomethanesulfonic acid, sodium salt 

2-(o-Methoxyanilino)-5-nltrobenzenesulfonic acid 

2-(p-Methoxyanilino)-5-nitrobenzenesulfonic acid 

1-Methoxyanthraquinone 

p-Methoxy-a-(p_methoxyphenyl)acetophenone (Desoxy- 

anisoin). 
6-Methoxy-8-(l-niethyl-4-diethylamlnobutylamino)- 
quinoline. 

2-Methoxynaphthalene — 

1-Methoxy— i-nltroaiithraqulnone 

p-Methoxyphenylaoetic acid 

5-Methoxy-m-phenylenedlamine 

N- (p-Methoxyphenyl )-p-phenylenediamine sulfate 

[3-(6-Methoxy-i!i-tolyl)-l-iiiethyldiazoaiiiino] acetic acid 

1-Methylaminoanthraqulnone 

l-Methylamino-^-(p-toluidlno)anthraquinone 

N-Methylaniline 

2-(N-Methylanilino)ethanol 

5-Methyl-o-anisidine (Cresidine) 

2-Methyl-p-anisidine 

2-Methylanthraquinone 

l-(3-Methyl-2-anthraqulnonylainino)-5-(7-oxo-7H-benz- 

[de]anthracen-3-ylamino)anthraquinone. 

3-Methylbenzo[f ]quinoline 

2-Methylbenzoxazole 

Methylcyclohexane 

N-Methylcyclohexylamine 

N-Methyleneaniline 

Me thylenebi s [l-aminopheny 1-2 -phenyl ether ] -3 - 

triazenemethylacetic acid. 
4,4'-Methylenebis[N,N-dlethylaniline] (Methane base)- 

■4,'i'-MethylenebiE[N,N-dimethylaniHne] 

ijA'-MethylenebisfN, N-dlmethyl-2-nitroanillne] 

5,5'-Methylenebis[toluene-2,i-diamlne] 

Methylenedl-p-phenylene isocyanate (^jA'-Methylene- 
dlphenyl isocyanate). 

Methylenedisalicylic acid 

2-Methyleneindollne 

2-Methylfuran 

Methylisonicotinic acid 

3-Methyl-l-(2-methyl-'4-sulfophenyl)-5-pyrazolone 

1-Methylnaphthalene 

l(and 2 )-Methylnaphthalene -■ 

2-Methylnaphthalene 

Methylnaphthalene, crud 



Manufacturers' identification numbers 
(according to list in table 27) 



N-Methyl-p-nitroacetanilide ~ 

N-Methyl-p-nltroaniline — 

5-Methyl-i-nitro-o-anisidine 

<V-Methyl-o-nltroanlsole 

»2-Methyl-l-nitroanthraqulnone 

3 -Methyl-1 ( m-ni trophenyl )-5 -pyrazolone 

2-[l-Methyl-3-('4-nltro-o-tolyl)diazoamino]-5-sulfo- 
benzolc acid. 

5-Methyl-o-phenetidine [NH2=1] 

4-Methyl-m-phenylene diisocyanate (Toluene-2,i- 
dlisocyanate). 

»3-Methyl-l-phenyl-5-pyrazolone (Developer Z) 

l-Methylpyrrole 

l-Methyl-2-pyrrolidone 

a-Methylstyrene 

3-Methyl-l-(m-sulfamldophenyl)-5-pyTazolone 

N-Methyl-5-sulfoanthranilic acid 

o-Methysulfonyl-p-nitro aniline 

3-Methyl-l-(m-sulfophenyl)-5-pyTazolone 

»3-Methyl-l-(p-sulfophenyl)-5-pyrazolone 

Methylsulfophenylpyrazolones, mixed 

2-Methyltetrahydrofuran 

Methyl 2-thienyl ketone- 



3-Methyl-6-(p-toluidino)-7-dibenz[f,ij]isoquinollne- 

2,7(3H)-dione. 
( l-Methyl-3 -p-toly Id i azoamlno ) acetic ac id 



200, 369, 38A, iWl, i66, 537 
403, 495, 510, 537, 559. 



584. 

508. 

403, 466, 537, 559. 

455, 537, 559. 

537. 



106, 
366, 
384, 
508. 
460, 
508. 
508. 
466, 
349. 
384, 
451. 
403, 
559. 
384. 
384, 
191. 

247. 

537. 

537. 

71. 

396. 

461, 466. 

384. 

384. 

369, 384, 537. 

384. 

537. 

384. 

537, 559. 

384. 

466. 

537. 

384. 

313, 513. 
335, 458. 
537. 
537. 
443. 

223, 466. 
223, 537. 
384. 
403. 
208, 537. 



569. 
537. 
537. 
508. 
443. 
508. 
508. 
508. 
186, 
384. 
384. 
443. 
537. 
106, 
443, 
384. 



369, 384, 403, 537. 
537. 



559. 

403, 537. 

247, 335, 403, 430, 443, 455, 510, 537, 559. 

X. 

384. 

335, 584. 

559. 

384. 

495. 

443, 537. 

351, 384, 443, 451, 455, 466, 510, 537, 559. 

559. 

537. 

40. 

384. 

384. 



74 



UNITED STATES TARIFF COMMISSION 



TABLE 7B. --Synthetic organic chemicals: Cyclic intermediates for which United States production or sales 
were reported, identified by manufacturer, 1954- -Continued 



Manufacturers' identification numbers 
(according to list in table 27) 



1-Naphthaldehyde 

•Naphthalene, solidifying at 79° C, or above (re- 
fined flake): 

*From American crude naphthalene 

•From imported crude naphthalene 

1-Naphthaleneacetonitrile 

1, 5-Naphthalenediol (1, 5-Dihydroxynaphthalene ) 

2,3-Naphthalenediol 

•1,5-Naphthalenedisulfonic acid 

1,5-Naphthalenedisulfonic acid, sodium salt 

1,6-Naphthalenedisulfonic acid, sodium salt 

2, 7- Naphthalenedi sulfonic acid 

1-Naphthalenesulfonic acid, sodium salt 

2-Naphthalenesulfonic acid 

2-Naphthalenesulfonic acid, sodium salt 

2-Naphthalenesulfonyl chloride 

1, 3, 6-Naphthalenetrisulf onic acid — • 

Naphthalic anhydride 

Naphthionic ac id 

•Naphthionic acid, sodium salt 

*l-Naphthol (a-Naphthol ) 

2-Naphthol, tech. (p-Naphthol) 

l-Naphthol-3,8-disulfonic acid 

»2-Naphthol-3,6-disulfonio acid (R acid) 

•2-Naphthol-3,6-disulfonic acid, disodium salt 

*2-Naphthol-6,8-disulfonic acid (G acid) 

2-Naphthol-6,8-disulfonic acid, disodium salt 

2-Naphthol-6-sulfonamide 

2-Naphthol-6-sulfonamide, p-toluenesulfonate 

•l-Naphthol—i-sulfonic acid (Nevile & Winther's acid) 

»l-Naphthol-5-sulfonic acid 

»l-Naphthol-8-sulfonle acid 

»2-Naphthol-6-sulfonic acid (Schaeffer's acid) 

2-Naphthol-6-sulfonlo acid, sodium salt 

2-Naphthol-6-sulfonic acid, p-toluenesulfonate, 
sodium salt. 

2-Naphthol-7-sulfonic acid 

2-Naphthol-8-sulfonic acid 

l,A-Naphthoquinone 

Naphthostyril 

•1, 8-Naphthosultone 

•Naphth [1,2] oxadiazole-5-sulf onic acid 

1-Naphthylamine (a-Naphthylamine ) 

»2-Naphthylamine (p -Naphthylamlne } 

l-(2-Naphthylamino)-2-anthraquinonecarboxylic acid — 

1-Naphthyl isocyanate 

»2-Naphthylmercaptoacetic ac id 

Nicotinic acid, n-butyl ester 

Nicotinic acid, methyl ester 

Nicotlnonitrile (3-Cyanopyridine ) 

m-Nitroacetanilide 

p-Nltroacetanillde 

2-Nitro-p-acetanlsldlde -. 

^-Nitro-o-acetanisidide 

^(and 5)-Nltro-o-acetanisidide 

m-Nitroacetophenone 

p-Nltroacetophenone — — — 

»m-Nitroaniline ■ 

o-Nitroanillne 

p-Nltro aniline 

•2-Nitro-p-anisidine [NH2=1] 

3-Nitro-o-anisldlne [NH2=1] 

•-l-Nltro-o-anlsldlne [NH2=1] 

»5-Nltro-o-anisldine pjH2=l] 

o-Nitroanisole 

A-Nltroanthranilic acid — 

l-Nitro-2-anthraqulnonecarbonyl chloride 

*l-Nitro-2-anthraquinonecarboxylic acid 

l-Nltro-2-anthraqulnonecarboxylic acid, hydrazide 

•5-Nltro-l-anthraqulnonesulfonic acid 

5 (and 8)-Nitro-l-anthraqulnonesulfonic acid 

8-Nitro-l-anthraquinonesulfonic acid 

2 - ( 1 ' -Nl tro-2 ' -an thraqulnonyl ) anthr [2,3] oxazole- 
5,10-dlone. 

m-Nltrobenzaldehyde — — 

5- (m-Nltrobenzamido )-l-naphthol-3-sulf onic acid 

•6-(p-Nitrobenzamido)-l-naphthol-3-sulfonlo acid 

•Nitrobenzene — - 

m-Nltrobenzenesulfonamide 

•m-Nltrobenzenesulf onic ac id 

•m-Nltrobenzenesulfonic acid, sodium salt 

m-Nltrobenzenesulfonic acid, trihydrate, sodium salt 



460, 
353, 
563. 
38-;, 
384. 
384, 
495, 
384. 
223, 
559. 
403, 
466, 
384, 
384. 
403. 
466, 
403, 
384, 
403, 
384, 
403, 
246, 
384, 
466. 
384, 
537. 
403, 
384, 
384, 
384, 
246, 
537. 

494, 
559. 
403. 
537. 
455, 
384, 
384, 
403, 
106, 
208, 
384, 
284, 
587. 
284. 
559. 
384, 
384, 
223. 
384, 
223, 
208. 
403, 
208. 
208, 
223, 
384, 
223, 
223, 
208, 
537. 
537. 
537. 
106, 
537. 
106, 
403, 
106, 
384. 



466, 494, 508, 537, 584. 
460, 466, 494, 584. 



403, 537, 559. 
537. 

403, 537, 559. 

501. 
559. 
537. 



537, X. 
537, 559. 
403, 537, 559. 
466, 494. 
537. 
559. 

384, 466. 
403, 537, 559. 

537. 

537, 559, X. 

403, 537, 559. 

403, 443, 451, 510. 

393, 403, 466, 559. 
537. 



466, 537, 559. 

403, 455, 510, 537, 559. 

403, 537. 

537, 575. 

403. 

394. 

403, 443, 537, 559. 

508. 



495, 559. 
401, 537. 

401. 
384. 

461, 466, 537, 559. 

403, 510. 

401, 537. 

403. 

384, 401, 403, 443, 466. 

401, 443, 510, 537, 575. 

537. 



384, 403, 537. 

384, 401, 403, 537. 

537. 

401, 537. 



223. 

443. 

384, H3, 451, 537. 

208, 384, 403, 466, 477, 537. 

559. 

208, 384, 401, 403, 443, 510, 537, 559. 

384. 

495. 



SYNTHETIC ORGANIC CHEMICALS, 195^ 



75 



TABLE 7B. --Synf/iefjc orga 



c chemical 
reported^ 



: Cyclic intermediates for which United States producti 
identified by manufacturer ^ 7954--Continued 



Manufacturers' Identification numbers 
(according to list in table 27) 



p-Nitrobenzenesulfonic acid — — — 

4-'-Nitro-o-benzenesulfonotoluidide 

m-Nitrobenzenesulfonyl chloride — _™ — — 

p-Nitrobenzenesulfonyl chloride — — 

5-Nltro-2 (3H )-benziinldazolone 

m-Nitrobenzoic acid 

p-Nltrobenzoic acid, n-butyl ester 

p-Nitrobenzoic acid, ethyl ester 

p-Nitrobenzoic acid, isobutyl ester 

p-Nitrobenzoic acid, n-propyl ester ~ — 

m-Nitrobenzoyl chloride 

p-Nitrobenzoyl chloride 

. 2-Nitrobiphenyl 

i-Nitrobiphenyl-A '-carboxylic acid — 

Nitrodiphenylamine 

1-Nitronaphthalene 

3-Nitro-l,5-naphthalenedisulfonic acid 

8-Nitro-l-naphthalenesulfonic acid 

8 (and 5)-Nitro-l(and 2)-naphthalenesulfonio acid 

»7(and 8)-Nitronaphth[l,2]oxadiazole-5-sulfonic acid — 

p-Nitrooxanilic acid 

Nitrophenethyl acetate 

Nitrophenethyl alcohol — — — 

p-Nitrophenetole 

o-Nitrophenol 

p-Nitrophenol — -____ 

p-(p-Nitrophenyl)acetophenone 

N, N'-("i-Nitro-m-phenylene)bls{acetamide] 

<>-Nitro-m-phenylenediamine 

4-Nitro-o-phenylenedlamine 

2-Nitrophenyl ether 

p-Nitrophenylhydrazine 

p-Nitrophenyl isocyanate 

*l-(m-Nitrophenyl)-5-oxo-2-pyTazoline-3-carboxylic 
acid. 

3'-Nitrophenylsulfonanllide — - — — ~ 

<4-Nltrophthalamide 

3(and 5)-NitroEalicylic acid — 

'V-Nitrosodiphenylamine 

l-Nitroso-2-naphthol 

p-NitroEophenol 

2-[4-(<i-Nitro-2-sulfotolyl)-3-sulfophenyl]naphtho- 

il,2]triazole-5-sulfonio acid. 
m-Nitro toluene ~ 

*o-Nitro toluene 

p-Nltro toluene 

Nitrotoluene mixtures 

»3-Nltro-p-toluenesulfonic acid [S03H=l] 

»5-Nitro-o-toluenesulfonic acid [ S03H=1] 

4'-Nitro-p-toluenesulfono-o-toluidide 

»2-Nltro-p-toluidine [ NHj^l] 

•■i-Nltro-o-toluidine [ NHs^ll ■ 

5-Nltro-o-toluidlne [ NH2=l] 

2-Nltro-3,4, 6-trlchlorophenol 

»16-Nitroviolan throne 

-i-Nitro-m- xylene 

»Nitro xylenes, mixed 

Nonyl- and dodecylbenzenes, mixed 

*Nonylphenol 

2-(Nonylphenoxy)ethanol 

6-0xo-6H-anthr [ 9 , l] isothiazole-3-carbonyl chloride 

6-0xo-6H-anthr[9,l] isothiazole-3-carboxylic acid 

l-(7-0xo-7H-benz[de] anthracen-3-ylamino)anthra- 

quinone . 
1, l'-(7-0xo-7H-benz[de ]anthraoen-3,9-ylenediimino )- 

dianthraquinone . 

5-0xo-l-phenyl-2-pyrazollne-3-carboxylic acid 

5-Oxo-l-phenyl-2-pyrazoline-3-carboxylic acid, ethyl 

ester. 
*5-0xo-l-(p-sulfophenyl)-2-pyTazollne-3-carboxylic 

acid (Pyrazolone T). 

Pentabromoindigo — — 

m-(n-Pentadecyl) phenol 

3, A, 9, lO-Perylenetetraoarboxylic acid 

3,'4,9, lO-Perylenetetracarboxylic diimlde 

Phenethylaraine — — 

0-Phenetidine — ~ ~ — 



537. 

466. 

403. 

537. 

549, 595. 

384, 403, 537. 

141. 

141, 247. 

141. 

141. 

549. 

384, 537, 549. 

208. 

208. 

384, 537. 

537, 559. 

466. 

384, 403, 537. 

537. 

384. 

334. 

384, 403, 559. 

537, 559. 

495. 

495. 

141, 537. 

310, 461, 537. 

208, 403, 461, 537. 

537. 



313, 537. 

443. 

513. 

208. 

443, 537, 559. 

559. 

537. 

384. 

384. 

501, 513. 

384, 403, 466, 537, 559. 

559. 



403, 
384, 
384, 
384, 
384, 
384, 
384. 
223, 
223, 
223, 
559. 
106, 
537. 
403, 
439. 
234, 
384. 
234, 
537. 
537. 
401, 

401. 

443. 
384. 



384, 443, 451, 510. 

384. 

426. 

384. 

384. 

240, 355, 374, 549, 561. 

208, 537. 

208, 510, 537. 



537. 

403, 537. 

403, 537. 

403, 466, 537. 

443, 455, 466, 510, 559. 

403, 537, 559. 

466, 494, 537. 

384, 537. 

443, 537. 

401, 466. 

466, 537. 

384, 417, 477. 

417, 501. 

537. 



76 



UNITED STATES TARIFF COMMISSION 



TABLE 7B. --Synthetic organic chemicals: Cyclic intermediates for which United States producti 
were reported, identified by manufacturer , 1954- -Continued 



Manufacturers' identification numbers 
(according to list in table 27) 



»Phenol: 
^Natural: 

From coal tar:^ 
U.S.P 



39° C, m.p- 



82ie-84i6~ 

All other 

From petroleum: 

U.S.P 

Other 

♦Synthetic: 

By caustic fusion: 

U.S.P 

82%-8l% 

From chlorobenzene by liquid-phase hydrolysis: 

U.S.P. 
From chlorobenzene by vapor-phase hydrolysis: 
U.S.P. 
l-Phenol-4-sulfonic acid 

Phenoxypropylene oxiiie 

*Phenylacetic acid (a-Toluic acid), all grades 

*Phenylacetic acid, ethyl ester, all grades 

Phenylaoetic acid, methyl ester, tech 

*Phenylacetic acid, potassium salt 

Phenylacetic acid, sodium salt 

»Phenylacetonitrile (a-Tolunitrile) 

2-Phenylanthr[2,3]oxazole-5,10-dione 

*p-Phenylazoaniline (p-Aminoazobenzene) and hydro- 
chloride. 

a-Phenyl-p-cresol carbamate 

Phenylcyclohexane 

N, N' -p-Phenylenebis [acetamidel 

2,2'-p-Phenylenebis[5-(l-nitro-2-anthraquinonyl)- 
1,3,^-oxadiazole] . 

*m-Phenylenediamine 

*o-Phenylenediamine 

p-Phenylenediamine 

1, l'-(p-Phenylenedicarbonyl)bis[2-(l-Ditro-2- 
anth^aquinonylca^bonyl)hydrazine J. 

Phenyl ether (Diphenyl oxide) 

*Phenylglycine salts: 

Potassium salt 

Sodium salt-— — — 

Phenylhydrazine 

Phenylhydrazine hydrochloride 

»2,2' -(Phenylimino)diethanol (Phenyldiethanolamine)- 

Phenyl isocyanate 

Phenyl ma Ionic acid, diethyl ester 

o-Phenylphenol, chlorinated 

o-Phenylphenol, sodium salt 

N-Phenyl-p-phenylenediamine — -— 

Phenyl-2-propanone — — — 

a-Phenyl-2i'i-xylenol -■ ■-■■ ~ 

Phloroglucinol — — ■-■- .— 

Phthalic acid 



»Phthal ic anhydride — ~ 

»Phthalimide 

Phthaloyl chloride (Phthalyl chloride) 

»Pioolines:' 

2-Picoline (a-Picoline) 

3-Picoline (P -Picoline ) 

■i-Picol ine (Y -Picol ine ) 

Picoline (3,<»-mixture) 

Picramic acid and salt 

Picric acid (Trinitrophenol) 

2-Pipecoline (a-Pipecoline) 

Poly-sec-amylphenol — — 

Polychlorobiphenyl 

Polydodecylbenzene 

*Primuline base 

Priraulinesulfonic acid 

n-Propylbenzenesulfonate 

Pseudocumidine (Cumidine) 



508. 












-166, 


584. 










508, 


584. 










466, 


507, 


508, 


509, 


584. 




508. 












507, 


508. 










208, 


489. 










A60. 












460. 












460, 


564, 


584. 








335. 












312, 


546. 










185, 


208. 










335. 












443. 












495. 












240, 


247, 


374, 


395, 


396. 




240, 


247, 


327, 


355, 


374, 


396, 420 


240, 


355, 


396. 








208, 


240, 


355, 


374, 


396, 


561. 


374. 












208, 


240, 


396. 








384. 












141. 












141. 












208, 


513. 










466. 












537. 













501. 

495, 537, 559, 562. 

549. 



537. 
240, 374. 



119, 384, 403, 466, 537, 559. 
223, 313, 384, 480, 537, 540, 559. 
466, 487, 494. 
537. 

335. 



335. 
403, 
335. 
384, 
384, 
208, 
247. 
208, 
335. 
335. 
335. 
384, 
236, 
527. 
480. 
384, 
208, 
335, 
208. 

460, 
508. 
508, 
460, 
508, 
403, 
311, 
274. 
208, 
517. 
208. 
189. 
403, 
92, 
141, 
508. 
527. 
-^9, 



396, 537. 

389, 403, 460, 466, 489, 494, 564, 584. 

349, 384, 394, 537. 



466, 508, 562, 584. 



562. 
508, 584. 



537. 
403, 537. 



508, 537, 549. 



537, 559. 
384. 
374, 460. 



See footnote at the end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



77 



TABLE 7B. "Synthetic organic chemicals: Cyclic intermediates for which United States producti 
were reported, identified by manufacturer, i954--Continued 



Manufacturers' Identification numbers 
(according to list in table 27) 



•Pyridine, all grades 

2-Pyridine ethanol — — 

2-Pyridine propanol 

3-Pyridol 

Pyrrolidone 

»CJuinaldlne — 



Quinaldlne yellow, base 

»Quinizarin 

2-Qulnizarinsulfonic acid 

Quinoline: 

Quinoline, 1° and 2° 

Other grades 

2,A-Quinolinediol 



Quinoline yellow, base- 
Resorclnol, tech- 

Resorc inol monobenzoate 

p-Resorcylic acid 

"Salicylic acid, tech- 



Salicylideneaminoguanidine oleate- 
Sodium phenolate- 
Styphnic acid, lead salt— 



•Styrene (Vlnylbenzene), all grades 

i'-Sulfamoylacetanilide — 

•Sulfanilic acid (p-Amlnobenzoio acid) and salt 

•<;-Sulfoanthranilic acid 

o-Sulfobenzoic anhydride 

i-Sulfo-o-benzoylbenzoic acid (Sulfo BB acid) 

♦'i, 'i'-Sulfonyldlphenol (4,4'-Dlhydroxydiphenylsulfone) 

"i-Sulfophthalio acid 

Terephthallo acid 

Terephthalic acid, dimethyl ester 

Terphenyl (Phenylbiphenyl ) 

Tetrabromo-S, 16-pyr anthrened lone 

•1,'1,5,8-Tetrachloroanthraqulnone 

»1, 2, A, 5-Tetraohlorobenzene 

Tetrachloronltrobenzene — 

1,<1, 5,6-Tetrachlorophthalic anhydride 

a, a,2,6-Tetrachlorotoluene — 

Tetrahydrofuran 

Tetrahydrophthal imld e- 



Tetrakisaminophthalocyanine, copper salt 

•Ij'V,?, 8-TetraklB [l' , 1" , 1" ' , l" " -anthraqx;iiiOt.yl- 
amino] anthraquinone (Pentaanthramide) . 

TetraJsisnitrophthalocyanine, copper salt 

Thianaphthene 

3 (2H)-Thianaphthenone- 
*3,3'-Thiobls[7H-benz [de] anthracen-7-one]— 

6, 6' -Thiodimetanilic ac id 

•o-Tolidine and salts 

»Toluene-2,'i-diamine (•i-m-Tolylenediamine)- 

Toluene-2,'i-disulfonic acid 

o-Toluenesulfonamide 

p-Toluenesulfonamide — 



o(and p )-Toluenesulfonic acid 

p-Toluenesulfonie acid, ethyl ester 

p-Toluenesulfonic acid, isopropyl ester- 

p-Toluenesulfonic acid, methyl ester 

p-Toluenesulfonic acid monohydrate 

Toluenesulfonic acid, sodium salt 

p-Toluenesulfono-o-toluidide 

o-Toluenesulfonyl chloride- 
p-Toluenesulfonyl chloride- 

Toluhydroquinone-— • 

m-Toluidine 

o-Toluidine 

p-Toluidine 

•6-p-Toluid inomet anl lie ac id 

•m-Toluidinomethanesulfonic acid 

•o-Toluidinomethanesulfonic acid 

8-(p-Toluidino )-l-naphthalenesulfonie acid 

2-(p-Toluidino)-5-nitrobenzenesulfonic acid 

*o-(p-Toluyl )benzoic acid 

»4_(o-Tolylazo )-o-toluidine (o-Amlnoazo toluene ) 

o-(p-Tolyl )benzoic acid 

2,2'-(m-Tolyliiiiino)dlethanol 
3-(p-Tolyl)-l-methyldiazoaminoacetic acid 

2,i, 6-Tribrcimophenol 

1, 2, 3 ( and 1, 2, 4 )-Trichlorobenzene 



i60, 508, 


584. 




508. 






508. 






28A. 






38-4, 537. 






-403, 460, 


466, 537, 584. 




-466. 






106, 200, 


366, 369, 384, 394, 403, 466, 487, 495 


510, 537, 559, 575. 




39-4, 487. 






460, 584. 






313, 508, 


513. 




537. 






403. 






460. 






495. 






460. 






208, 223, 


335, 403, 569. 




537. 






501, 537. 






X. 






204, 208, 


335, 460, 562. 




466. 






540. 






223, 403, 


466, 559. 




384, 443, 


455, 559. 




513. 






537. 






185, 208, 


384. 




394. 






537. 






214, 537. 






208. 






106, 384. 






369, 403, 


537. 




208, 335, 


363, 549. 




223. 






63. 






537. 






537. 






503. 






537. 






369, 384, 


537. 




537. 






234. 






384. 






106, 369, 


384, 401, 537. 




403. 






234. 






394, 403, 


501, 537, 559. 




311, 384, 


403, 466, 537, 559. 




384. 






208. 






208. 






185, 208, 


494, 574. 




461. 






417, 537. 






208, 369, 


461. 




185, 384. 






185. 






384, 537. 






208. 






208. 






495. 






384, 403, 


460, 537. 




384, 403, 


510, 537. 




403, 503. 






446. 






403, 537, 


559. 




443, 451. 






403, 510. 






384, 403. 






559. 






384, 466, 


537. 




384, 403, 


451, 466, 537. 




403. 






495, 559. 






384. 






335. 






335, 410. 







78 



UNITED STATES TARIFF COMMISSION 



TAELE TB. --Synthetic organic chemicals: Cyclic intermediates for which United States production or sale 
were reported, identified by manufacturer , J954--Continued 



1,2,4-rrichlorobenzene— ~ 

l,2,^-Triohloro-5-nltrobenzene 

Trlchlorophenylsllane 

*a, a, a-Trichloro toluene (BenzotrichlorlJe) 

a,2,A-Trichlorotoluene 

a,3,A-Trlohlorotoluene 

2,'i,6-Trlnltrobenzolc acid 

Triphenylmethyl Isooyanate (Trltyl isooyanate)- 
2,'l,6-Tris(dl]iietlwlaminomethyl)phenol 

«6,6'-Ureylenebia [l-naphthol-3-Buironlo acid] — 



Vanillic acid 

o-Vanillln (2-[^droxy-3-methoxybenzaldehyde ) 

»Veratraldehyde Oj'l-Dimethoxybenzaldehyde) 

o-Veratraldehyde (2,3-Diiiiethoxybenzaldehyde) 

Veratryl alcohol- — 

Vinylbenzenesulfcnio acid, potassium salt 

5-Vinyl-2-picoline (MVP) 

l-Vinyl-2-pyrrolidone — — — 

»Violanthrone (Dibenzanthrone ) — ~ 

Xanthene-9-carbo)tyllc ao id — 

Xenylamlne (A-Biphenylamine)- 

m-Xylene 

o ( and p )-Xylene 

•Xylenesulf onlc ac id 

Xylenesulfonic acid, sodium salt 

Xylenol crystals 

»}^lenols: 

Low b , p- — — — —- . 

Not classified as to b.p ~ 

•Xylidines: 

2,4-Xylidine (m-A-Xylidine) 

2,5-Xylidine (p-Xylidine) 

Xylidinee, mixed: 

•Original mixture 

Xylldine (ortho, para) -— — 

2,'i-Xylldine acetate 

2,5-Xylidine hydrochloride 

4-(2,4-Xylylazo)-o-toluidine 

<4-C2,5-Xylylazo)-o-toluidine 

4-f2,A-Xylylazo)-2,5-xylidine 

A- (3, 5-Xylylazo )-3 , 5-xylidine 

All other intermediates 



Manufacturers' Identification numbers 
(according to list in table 27) 



208, 363, 549. 

384. 

134. 

199, 549, 569. 

569. 

569. 

480. 

208. 

417. 

237, 384, 403, 443, 451, 455, 466, 510, 537, 559, 

585. 
310. 
208. 

141, 208, 244, 274, 395. 
208. 
208. 

274, 395. 
537. 
458. 
508. 
508. 
384. 

92, 106, 369, 384, 401, 466, 510, 537. 
327, 453. 
208. 

395, 537. 
261, 564. 
537. 

241, 261, 395, 458, 564. 
185, 501, 527, 574. 
574. 
584. 

507. 

389, 507, 508. 

466, 508. 

384, 403, 537. 
384, 403. 
540. 

403, 466, 537. 

466, 537. 

466, 585. 

403, 585. 

403. 

466. 

403, 510. 

384. 

200. 



^ Does not Include manufacturers' identification numbers for producers who report to the Coal Economics 
Division, U. S. Bureau of ;«!lnes. 



SYNTHETIC ORGANIC CHEMICALS, 1954 

Dyes 



79 



TABU fSB. '-Synthetic organic chemical*: Coal-tar dye* tor which United State* production or aalet were 
reported, identified by manufacturer, 1954 

[Dyes for which separate statistics are given In table SA are marked below with an asterisk (»); dyes not 
so marked do not appear In table 6k because the reported data are accepted In confidence and may not be 
published. Manufacturers' Identification numbers shown below are taken from table 27. An X signifies that 
the manufacturer did not consent to the publication of his Identification number with the designated 
product] 



Manufacturers' Identification numbers 
(according to list In table 27) 



DIES (SiODFED BY COLOUR INDBC NDMBHl 
NitroBo Dy 
Naphthol green B 



Nitro Dy 



Naphthol yellow S- 
Amldo yellow E 



Alt Dyit 
Monoazo Dyes 



Spirit yellow Q- 
Acld yellow 

•Spirit yellow R- 

»011 yellow- 



•Chrysoldlne Y- 
•Chrysoldlne R- 
»Sudan 

Crocelne orange Q 

•Orange G — 



Chronotrope 2R 

Fast acid fuchslne B 

•Amldo naphthol red G 

Brilliant sulphon red 

•Chrome yellow 2G- 
•Chrome yellow R 

Fast red GO salt 

•Azo alizarin yellow QP- 
•Vlotorla violet *BS 

Chromotrope 6B- 



•Amldo naphthol red 6B- 

Flbre black V 

Fast scarlet Q base 

•Fast scarlet G salt 

Fast red QL base 

•Fast red QL salt 

Sudan II 

•Ponceau R 

Double ponceau 

•Fast red B 



Chromotrope lOB 

•Chrome brown R 



Chrome green 2G 

Chromate brown B 

Acid chrome brown R 

Chrome garnet R 

Chrome flavlne G 

•Azo eoslne G 

•Fast red B base 

•Fast red B salt 

•Fast scarlet R base 

•Fast scarlet R salt 

Eosamlne Q 

Direct pink 2Cm 

Direct pink 



•Metanll yellow- 
Methyl orange — 
Azoflavlne RS — 
Azo yellow- 



Resorcln yellow 

•Orange II 

•Orange R 

Acid chrome brown B 

•Acid chrome garnet R 

Acid chrome violet N — 

Chrome black FV 

Naphthylamine brown — 

•Fast red A 

•Azo rublne — 
•Fast red VH- 



403, 466. 
384. 



384 


466. 














466 
















250 


384, 


403, 


443, 


466, 


510, 


537. 




250 


265, 


384, 


403, 


466, 


510, 


537. 




384 


403, 


466. 












384 


403, 


466. 












250 


384, 


403, 


466, 


510, 


537, 


559. 




403 
















223 


384, 


403, 


46o, 


537, 


559. 






403 
















403 


446, 


510. 












223 


384, 


403, 


443, 


466, 


510, 


511, 


537, 559 


403 


446. 














384 


466, 


510, 


559. 










223 


384, 


403, 


466, 


510, 


559. 






384 


510. 














403 


510, 


559. 












384 


403, 


537, 


559. 










403 
















223 


384, 


403, 


455, 


466, 


510, 


511, 


537, 559 


559 
















223 


510, 


537. 












223 


384, 


443, 


510, 


576. 








223 


510, 


537. 












223 


384, 


401, 


403, 


443, 


510, 


576, 


583. 


250 


384, 


403, 


466. 










384 


403, 


466, 


537, 


559, 


585. 






384 
















384 


403, 


466, 


559, 


585. 








537 
















119 


384, 


403, 


537, 


559. 








384 
















U9 
















119 


537. 














559 
















119 
















384 


446, 


455, 


537, 


559, 


585. 






117 


223, 


384, 


403, 


510, 


537. 






223 


384, 


401, 


403, 


443, 


510, 


576. 




223 


384, 


403, 


466, 


510, 


537, 


576, 


583. 


223 


384, 


401, 


403, 


443, 


451, 


510, 


576, 583 


537 
















537 
















384 


403. 














223 


384, 


403, 


537, 


559. 








223 


384. 














384 


U3, 


559. 












403 


510. 














403 
















384 


403, 


446, 


466, 


559, 


585. 






384 


403, 


466, 


537, 


559. 








403 
















384 


403, 


559. 












119 


403. 














403 
















384 
















384 


403, 


466, 


537, 


559, 


585. 






223 


384, 


403, 


537, 


559, 


585. 






384 


403, 


537, 


559. 











80 



UNITED STATES TARIFF COMMISSION 



TABLE SB. -Synthetic organic chemicais: Coal-tar dyes for which United States producti 
reported, identified by manufacturer, 1954--Continued 



Colour 
Index or 

Proto- 
type No. 



Mamifaoturers' identification numbers 
(according to list in table 27) 



183 
184 
185 
195 
197 
201 
202 
203 
204 
208 
209 
216 
219 
225 



234 

235 
238 
246 
247 
252 
253 
258 
262 
267 
271 
274 
275 
278 

280 

288 

289 

291 

292 

294 

299 

302 

304 

305 

306 

307 

308 

316 

317 

319 

324a 

325 

326 

327 
331 
332 
343 
346 
349 
353 
364 
365 
370 
375 
376 
377 
382 
387 
393 
394 
395 
400 
401 
403 
405 
406 



DYES GROUPED BY COLODR INDEX NUMBER— Continued 

Aio Dy«t--Contlnued 

Monoazo Dyes — Continued 



Croceine scarlet 3BX 

Amaranth 

•Cochineal red A 

Mordant yellow 

Chrome yellow RN 

Chrome blue black B 

•Chrome blue black R 

•Chrome black T 

Chrome black A 

Fast acid blue R 

Fast acid blue B — 

*Acid chrome red B- 

•Chrome flavine A — 
Direct pink 2B 



Disazo Dyes 



•Resorcin brown 

"Resorcin dark brown 

Chrome brown G 

•Acid black lOB 

»Azo dark green A 

•Brilliant croceine M- 

Ponceau SS ex 

Sudan IV 



Cloth red B 

Neutral gray G 

Fast acid black R 

Milling orange 

•Cloth scarlet G 

•Direct fast red 8BL — 



•Scarlet EC 

Fast acid cyanlne G 

•Fast acid cyanlne 5H ex 

Silk red 4B 

Acid chrome verdone A 

Acid black B 

•Acid chrome black F 

Acid chrome green SS 

•Fast acid black 2BN 

Fast acid black R 

Fast acid black F 

•Fast acid cyanine black B- 

Naphthylamine black D 

Developed blue NA 

Developed blue B 

•Direct fast heliotrope 

•Rosanthrene 

Direct brilliant violet 

•Direct fast scarlet 



•Direct fast scarlet 4BA 

•Bismarck brown G 

•Bismarck brown R 



Chrome fast yellow C 

•Direct fast yellow 5GL 

Direct fast yellow 4CiL ex 

•Direct fast pink 2BL 

•Brilliant yellow 

•Chrysophenine G 

•Congo red 

•Congo corinth G 

Congo rubine 

Direct orange G 

•Direct scarlet B 

•Direct violet B 

Benzo violet 

•Direct violet N 

Direct black RO 



Direct brilliant Bordeaux R- 

•Developed black BH 

Diphenyl fast gray B 

Direct cyanine R 

•Direct blue 2B 



403, 


559. 












223, 


384, 


403, 


466, 


559. 






384, 


403, 


559. 










384, 


403, 


559. 










403, 


559. 












384. 


403, 


466, 


537, 


559. 






384, 


403, 


559. 










384, 


403, 


559. 










384, 


403, 


559. 










384, 


403. 












384, 


403, 


466, 


537, 


559. 






384, 


403, 


537, 


559. 








537. 














384, 


403, 


446, 


466, 


537, 


559. 




223, 


384, 


403, 


446, 


466, 


537, 


559. 


403, 


537. 












223, 


384, 


403, 


446, 


466, 


510, 


537, 559, 585 


403. 


537, 


559. 










223, 


384, 


403, 


466, 


537, 


559, 


585. 


403. 














29, 


250, 


265. 


403, 


451, 


537, 


559, 


384, 


403, 


559. 










537. 














384. 














384. 


466, 


559. 










446, 


466, 


510. 


511, 


559. 






351, 


384, 


403, 


443. 


446, 


451, 


455, 466, 510 


511, 537, 559. 








384, 


403, 


510. 










384, 


403. 












384, 


403, 


451, 


537, 


559. 






559. 














403. 














403. 














384, 


403, 


537, 


559. 








466. 














403, 


537, 


559. 










559. 














384. 














384, 


403. 


537. 










384. 














443. 














384, 


559. 












403, 


443, 


537, 


559. 








403, 


443, 


537. 










510. 














351, 


384, 


403, 


443, 


451, 


455, 


466, 510, 537 


559, 585. 










384, 


451 


466, 


537. 


559. 


585. 




384. 


403 


466, 


537, 


559. 






384 


403 


466, 


537, 


559. 






466, 


537. 












351 


384 


403 


451 


466, 


511, 


537. 


455 


511. 












384 


403 


443 


455 


466, 


537. 




384 


403 


537 


559. 








384 


403 


537 


559. 








403 


537 


559. 










384 


403 


446 


466 


510, 


559, 


585. 


351 


559 












403 














384 


403 


446 


466 


510 


559. 




384 


403 


537 


559 








384 














384 


403 


510 


537 


559. 






510 














403 














384 


403 


446 


451 


466 


537 


559, 585. 


559 














403 














384 


403 


446 


466 


510 


537 


559, 585. 



SYNTHETIC ORGANIC CHEMICALS, \95U 

TABLE 8B. --Synthetic organic chemicals: Coal-tar dyes for which United States products 
reported, identified by manufacturer , i954--ContinucH 



81 



or sales were 



Colour 
Index or 

Proto- 
type No. 



Dye 



411 
415 
419 



423 
430 

431 
436 
441 
443 
446 
446 
464 
466 
471 
472 
477 
478 
487 
495 
499 
499 
502 
508 
512 
515 
516 
518 

520 



533 
538 
539 
540 
552 
561 
576 
581 
582 
583 
589 
593 
594 
595 
596 
598 
601 



620 
621 
622 
628 
631 



636 

639 
640 
642 
652 
653 



rriES GHOUPED BY COLODR INDEX NUMBER—Contlnued 

Aio /)y*s--Contlnued 

Dlsazo Dyes — Continued 



Cresotine yellow G- 

«Direot orange R 

•Direct fast red F — 



•Direct brown M 

Direct brown B 

•Polar red 

Acid chrome red 

Direct brilliant red 8B- 
Chrome fast yellow RD 

•Milling red G 

Direct orange R 

•Benzopurpurine 4B 

Direct blue 3R 

•Benzo new blue 5B 

Direct blue 4R 

Direct blue BX 

Direct blue 3B 

Direct orange G 

•Acid anthracene red 3B — 
Benzopurpurine lOB 

•Fast blue B base 

•Fast blue B salt 

•Direct azurine G 

Direct brilliant blue G- 

•Direot blue RW 

Direct blue B- 



Manufacturers' identification numbers 
(according to list in table 27) 



Chicago blue B 

•Direct sky blue FF- 



•Direct pure blue- 



Trisazo Dyes 



•Direct fast blue FR 

Oxydiamlne black N 

•Direct fast black FF 

Isodiphenyl black HO 

Diazo blue black BS 

•Direct brown BT 

Direct fast blue B 

•Direct black EW 

•Direct black RX 

•Direct green ET 

Chloramine green B — 

•Direct green B 

•Direct green G 

Direct olive Q 

•Direct brown 3G0 

•Congo brown G 

Congo brown R 



Tetrakisazo Dyes 



Direct brown G- 



•Direct yellow R 

•Chloramine orange G 

•Stilbene yellow 

Dlphenyl catechine G — 
Diphenyl chrysoine G — 



Pyrazolone Dye 



•Fast light yellow G- 
•Xylene light yellow- 

•Tartrazine 

•Polar yellow 

•Chrome red B 

•Pyrazol orange 



403, 559. 

384, 403, 537, 559. 

200, 384, 403, 446, 455, 510, 511, 537, 559, 

585. 
351, 384, 403, 446, 451, 466, 510, 511, 537, 

559, 585. 
446, 466, 559. 
351, 384. 403, 443, 446, 451, 455, 466, 511, 

537, 559. 
537. 
559. 
443. 

384, 443, 466, 510, 559. 
403, 510. 
403, 537, 559. 
537. 

384, 403, 443, 446, 537, 559. 
403, 559. 

384, 403, 559, 585. 
403, 537, 559. 
403, 510. 

384, 403, 443, 466, 510, 559. 
403, 537, 559. 
223, 401, 510, 537. 

200, 223, 384, 403, 443, 510, 576, 583. 
384, 403, 446, 451, 510, 537, 559, 585. 
537. 

384, 403, 455, 510, 537, 559. 
537, 559. 
384. 
380, 384, 403, 446, 451, 455, 466, 510, 537, 

559, 585. 
384, 403, 443, 451, 537, 559, 585. 



510, 537, 559, 585. 

451. 

384, 403, 451, 537, 559. 

451. 

403. 

351, 384, 403, 446, 510, 537, 559 

559. 

384, 403, 446, 451, 

384, 403, 446, 451, 

384, 403, 446, 451, 

403, 446, 537, 559. 

384, 403, 446, 466, 

403. 446, 537, 559. 

384, 510. 

384, 403, 446, 466, 

384, 403, 537, 559, 

537. 



466, 537, 559. 
466, 537, 559. 
466, 510, 537, 559. 

510, 537, 559. 



537, 559. 
585. 



384, 446. 



384, 403. 466, 537, 559. 
384, 403, 466, 537. 
384, 403, 466, 537, 559. 
403. 
559. 



384, 403, 443, 537. 

223, 384, 403, 443, 455, 466, 537, 559. 

223, 384, 403, 443, 451, 466, 510, 511, 559. 

384, 403, 443, 455, 559. 

384, 403, 443, 455, 466, 537, 559. 

351, 384, 403, 443, 451, 510, 511, 559. 



82 UNITED STATES TARIFF COMMISSION 

TABL£ 8B. '•Synthetic organic chemicals: Coal-tar dyes for which United States production or sales were 
reported, identified hy manufacturer , i954- -Continued 



Colour 
Index or 

Proto- 
type No. 



Dye 



Manufacturers' identification numbers 
(according to list In table 27) 



657 
658 
662 
663 
666 
667 
670 
671 
672 
673 
676 
677 
680 
681 
682 
683 
689 
692 
695 
696 
697 
698 
699 
70i 
705 
706 
707 
7U 
720 
722 
728 
729 
735 
737 



7iS 
749 
749 
752 
758 
766 
766 
768 
768 
771 
773 
778 
779 



788 
789 
793 
797 



800 
801 
802 



812 
813 
8U 
815 
816 



DIES GROUPED BY COLOUR INDEX NUMBER—Contlnued 
Ketonimint Dyes 

Tr iphenylme thane and 
Diphenylnaphthylme thane Dyes 

•Malachite green 

•Rhoduline blue 60 

♦Brilliant green- 
Setocyanlne- 

»Acid green B 

»Fast acid green B 

Acid light green 

«Acid glaucine blue 

Xylene blue VS 

Xylene blue AS 

Para fuchsine 

Magenta 

♦Methyl violet B and base- 

»Crystal violet 

»Ethyl violet- 
Benzyl violet — 
Spirit blue 2B- 
Acid magenta- 
Acid violet 4BN- 

Fast acid violet lOB 

Wool violet 



»Acid violet • 

Acid fast violet BG 

Alkali blue 

Methyl blue 

Methyl cotton blue — — 

Soluble blue 

Patent blue A 



*Acid chrome azurol B 

«Acid chrome cyanine R 

Victoria Blue R 

•Victoria blue B 

•Naphthalene green V 

•Wool green S 



Xanthene Dye 

Xylene red B — 

Rhodamine B 20i6 

•Rhodamine B cone, 100;6 

Rhodamine 60 cone, 100% 

Fast acid violet A2R 

•Uranlne (Fluorescein, aliali salt) 

Eosine G (Tetrabromofluoresceln, alkali salt)- 

Tetrabromofluorescein . 

Dinltrodibromofluorescein 

firythrosine bluish 

Phloxine B 



Acridme Dye 

Acridine orange NO- 
Brilliant phosphine 

Euchrysine 2G 

QumoUne Dyes 

Qulnoline yellow, aplrit-soluble- 

•Qulnoline yellow 

Quinollne yellow KT 



)1« Dye 



•Prlmuline 

Direct pure yellow M 

•Direct fast yellow 

Thioflavlne T 

Direct brilliant f lavine S 



403, 


466, 


537. 






223, 


399, 


403, 


466. 




223, 


384, 


399, 


403, 


537. 


223, 


399, 


403, 


466, 


537. 


384, 


403, 


537. 






223, 


384, 


403, 


443, 


4t>6, 537, 559 


223, 


384, 


403, 


443, 


466, 537. 


384. 










223, 


384, 


403, 


443, 


466. 


384, 


403. 








384, 


403. 








356, 


AAA, 


466. 






356, 


466, 


494. 






384, 


399, 


403, 


466, 


537. 


223, 


384, 


399, 


403, 


537. 


384, 


399, 


403, 


537. 




399. 










356. 










384. 










403. 










537, 


559. 








223, 


403. 








384, 


466, 


537, 


559. 




537. 










356, 


444. 








444. 










384, 


444. 








356, 


466. 








466. 










384, 


403, 


510, 


537, 


559. 


384, 


403, 


443, 


537, 


559. 


223, 


399, 


537. 






223, 


384, 


399, 


403, 


537. 


223, 


384. 


403, 


537, 


559. 


223, 


384, 


443, 


466, 


537. 


384. 










403. 










384, 


466, 


537. 






384, 


537. 








403, 


483. 








223, 


356, 


466, 


472, 


483. 


223, 


356, 


403, 


466. 




356, 


466. 








223, 


356, 


466. 






223. 










356. 










223, 


356. 








356. 










384, 


403, 


443. 






443, 


537. 








403, 


466, 


559. 






443. 










403, 


466. 








384, 


403, 


466 


537. 




537. 










403, 


537, 


559. 






537. 










92, 


384, 


403, 


451, 


537, 559. 


537. 










92. 











SYNTHETIC ORGANIC CHEMICALS, 1954 



83 



TAS£ SR, •-Synthetic organic chemicala: Coal'tar tfyea for which United Statea production or aalea were 
reported, identified by manufacturer, 7 954- -Continued 



Dye 



Mamifaoturers' Identification numbers 
(according to list In table 27) 



DYES QROUPED BY COLOUR INDEX NUMBER— Continued 
Aztne Dyes 



•Wool fast blue 

•Safranlne 



Methylene violet -____ 

Acid cyanlne 

"Induline, spirit-soluble 

Indullne , water-soluble 

Nlgrosine, spirit-soluble -— - 

Nigrosine, water-soluble 



Aniline Black and Allied Dye 



Diphenyl black base 

New fast gray 

Fur black 

Old 



Dye 



New blue R 

Nile blue A 

Th\aiine Dye 

•Methylene blue 

Methylene green B 



Salfar or Sulfide Dyet 

Derivatives of Carbazcle 



Immedial yellow D 

Carbazole vat blue R 



Other Sulfur or Sulfide Dyes 



•Sulfur black 

Sulfur blue 

•Sulfur maroon 



•Sulfur olive 

•Sulfur yellow 

Anthraqainont 

•Alizarin VI 

•Alizarin red S 

Alizarin brown — - 

Alizarin SX 



•Acid alizarin blue SE 

•Acid alizarin blue B 

Anthracene blue SWGG 

Anthracene blue WR 

•Alizarin Irisol R 

Alizarin astrol B 

Cyananthrol R 

•Alizarin cyanlne green 



Acid anthraquinone violet 

•Anthraqulnone blue black B 

•Acid anthraquinone sky blue B- 

Anthraqulnone blue SR 

Acid alizarin rubine 



Anthraqu 



Vat Dyes 



•Anthraqulnone vat golden orange G, 12%-- 

•Anthraqulnone vat scarlet G, 16-2/3% 

•Anthraquinone vat dark blue BO, 25% 

•Vat navy blue NTP 

•Anthraquinone vat Jade green, 6% 

•Anthraquinone vat green B and black B, 
12-1/2%. 

•Anthraquinone vat violet 2R, 12-1/2% 

•Anthraqulnone vat blue RS, 10% 

Anthraquinone vat blue 3G, 10% 

Anthraquinone vat blue GCS, 8-1/3% 

•Anthraquinone vat blue GCD, 8-1/3% 



384, 


403, 


559. 




223, 


384, 


403, 


537. 


403. 








384. 








384, 


403, 


466. 




384, 


403, 


466. 




384, 


403, 


466. 




384, 


403, 


466. 




466. 








466. 








466. 








403, 


466. 






384. 








223, 


384, 


399, 


403, 466 


466. 









384. 
311, 537. 



311, 384, 403, 466, 537. 

280, 311, 334, 403, 466, 537, 559, 576. 

384, 403, 466, 537. 

280, 311, 384, 403, 466, 537. 

280, 311, 384, 403, 466, 537, 576. 

280, 311, 384, 403, 466, 537, 559, 576. 



403, 466, 510. 

369, 384, 403, 466, 510. 

366, 403. 

403. 

384, 403, 466, 559. 

384, 403, 455, 466, 510, 537, 559. 

369. 

455. 

366, 369, 537. 

369, 384, 537. 

369, 537. 

265, 366, 369, 384, 403, 455, 466, 510, 537, 

559. 
369, 403. 

366, 369, 384, 403, 466, 510, 559. 
369, 384, 403, 537. 
369. 
369, 384. 



106, 384, 403, 455, 466, 537. 

106, 384, 403, 466, 510, 537. 

92, 106, 369, 389, 401, 403, 466, 510, 537. 

106, 369, 389, 401, 466, 510, 537. 

106, 117, 369, 384, 401, 403, 455, 510, 511, 

537. 
92, 106, 311, 384, 403, 466, 537. 

106, 369, 384, 401, 403, 537. 

106, 384, 466, 537. 

537. 

384, 403, 537. 

106, 384, 403, 466, 537. 



84 



UNITED STATES TARIFF COMMISSION 



TABLE SR.-Syntheti 



ic chemicals: Coal-tar dyes for which United States product ion 
reported, identified by manufacturer, J954- -Continued 



ColOXLT 

Index or 
Proto- 
type No. 



Dye 



Manufacturers' Identification numbers 
(according to list in table 27) 



1118 
1120 
1132 
1135 
1150 

1151 
1152 
1161 
1162 
1163 
1167 
1170 
1173 



1177 
1180 
1183 
118^ 
1185 
1207 
1212 
1217 



DICES GROUPED BY COLOUR INDEX NUMBER—Continued 

Anthraqumone Vat Djies-'Contlnued 

Anthraquinone vat yellow G, 12-1/2%- 

Anthraqulnone vat brown B. 22^ 

Anthraquinone vat yellow GK, 12-1/2% 

Anthraquinone vat brilliant violet RK, 12-1/2% 
♦Anthraquinone vat olive R, 12-1/2% 

♦Anthraquinone vat brown R, 12-1/2% 

•Anthraqxrtnone vat brown G, 12-1/2% 

Anthraquinone vat red violet RRN, 12-1/2% 

Anthraquinone vat red BN, ex., 12-1/2% 

♦Anthraquinone vat violet BN, 25% 

Anthraquinone vat olive G 

Anthraquinone vat yellow R, 12-1/2%- 

Anthraquinone vat blue 3G, 12-1/2% 

Indigoid and Thioindtgoid Dyes 

♦Indigo, synthetic, 20% 

Tribromindigo RB, 20% 

♦Bromindlgo blue 2BD, 16% 

Indigo blue 6B 

Clba pink B, 20% 

♦Vat red 3B, 20% 

♦Vat orange R, 10% 

Food, Drug, and Cosmttlc Dyes 
Food, Drug, and Cosmetic Colors 



♦Blue #1 

Blue #1, aluminum lake 

Blue #2 

Green #1, #2 

Green #3 

♦Orange #1 

Orange #2 

♦Red #1 

♦Red # 2 

♦Red #3 

Red #3, aluminum lake 

Red #32 

Violet #1 

Yellow #1 

♦Yellow #3, #4- 

♦Yellow #5, #6 

Yellow #5, alumimrai lake- 



Drug and Cosmetic Colors 



Black #1 

Blue ft 

Blue #4 

Blue #6 

Blue #9 

Brown # 1 

Green # 1 

Green # 5 

Green #6, #7- 



Orange # 3 

Orange f-i 

Orange #5 

Orange #11, #12 

Orange # 17 

Red #2 

Red #3 

Red #5 

♦Red # 7 

Red #8 

•Red #9, #12. #13, #34 

Red # 10 

Red #11, #31, #35, #36 

Red #17, #18, #28, #33, #37, #39— 



311, 403, 537. 

237. 

403, 510, 537. 

384, 403, 537. 

106, 369, 384, 389, 401, 403, 455, 466, 510, 

537. 
106. 384, 389, 403, 466, 537. 
106, 389, 401, 403, 466, 537. 
403, 537. 
384, 403. 

369, 384, 403, 537. 
311. 

92, 537. 
384, 403, 510. 



335, 384, 403, 537. 

403, 537. 

117, 335, 403. 

117, 335, 384, 403, 537. 

384, 403. 

335, 384. 

117, 384, 403, 466, 537. 

117, 384, 403, 466, 510, 537. 



29, 49, 223, 


246. 


403. 


29. 






29, 49, 267. 


403. 




246, 403. 






246. 






29, 49, 223, 


246, 


267, 403 


403, 466. 






29, 49, 223, 


403. 




29, 49, 223, 


246, 


267, 403 


29, 49, 223, 


267, 


403. 


29. 






29, 223, 246 


267 


403. 


403, 466. 






403. 






20. 






29, 403, 422 


466 




29, 49, 223, 


246, 


267, 403 


29. 






403. 466. 






29. 






403. 






29, 403. 






403. 






403. 






29. 






29, 403. 






403. 






29. 






29, 403. 






29, 403, 472 






29, 223, 356 


393 


472. 


403. 






29, 472. 






29. 






29, 472. 






29, 393. 






29, 223, 403 






29, 393, 472 






29, 472. 






29, 393, 472 






29. 






29, 393, 472 






403. 






29, 393, 403 


466 


472. 



SYNTHETIC ORGANIC CHEMICALS, 1954 

-Synthetic organic chemicals: Coal-tar dyes for which United States production 
reported, identified by manufacturer , 1954- -Continued 



85 



Colour 
Index or 
Proto- 
type No. 



Manufacturers' identification numbers 
(according to list in table 27) 



DYES GROUPED BY COLOUE INDEX NUMBER— Continued 



Food, Crug, and Cos 



Dyt 



Drug and Cosmetic Colors — Continued 



»Red #21 

Red #22 

Red #27 

Red #30, #38 

Violet #1 

Yellow #1, #10 

Yellow #5 

Yellow #6 

Yellow #7 

Yellow #8 

Yellow # 11 



Drug and Cosmetic Dyes, External 



Blue #1 

Green #1 

Red #1, #8, #10, #11- 

Red #13 

Violet #2 

Yellow #1, #3, #5 



DYES GROUPED BY PROTOTYPE NUMBER 



»Acid alizarin flavlne R- 
Acld anthracene brown B- 
Acld anthracene brown 3B- 

»Acid anthracene brown PG 

Acid chrome blue 2R 

•Algol yellow GC 

Alizarin direct blue A2G 

Alizarin direct blue AR 

•Alizarin supra blue A 

Alkali fast green lOG 

•Anthracene chromate brown EB — 

•Artificial slli black G 

•Benzo Bordeaux 6B 

•Benzo chrome black blue B 

•Benzo copper blue B- 

Benzo dark brown ex — 

•Benzo fast black L 

•Benzo fast blue 4GL- 

Benzo fast blue 8GL 

Benzo fast brown 3GL 

•Benzo red 13 

Benzo rhodullne red B 

•Benzo rhodullne red 3B 

Brilliant acid blue 3B- 



•Brllliant benzo violet B 

•Brilliant milling blue B 

Brilliant wool blue FFB 

•Brilliant wool blue FFR 

Cellitazol AZ 

•Celliton orange GR 

Chlorantlne fast blue 2GL 

•Chlorantine fast brown BRL 



•Chlorantlne fast yellow 4GL- 
Chlorantine fast yellow RL— 
Chrome yellow G — 



Clbacete dlazo black B 

Cibacete dlazo black GN 

Cibacete sapphire blue G 

Cibacete scarlet 

Cotton black 3G 

Cross dye green B 

•Diamine Bordeaux B 

Diamine catechlne B 

Diamine catechlne G 

•Diamine catechlne 3G- 

•Dlamlne fast blue FFB 

•Diamine fast orange EG 

•Diamine fast orange ER 

•Dlaminogen blue N2B 

•Dlazo Bordeaux 7B 

•Dlazo brilliant green 3G- 
•Diazo brilliant scarlet 2BL ex- 



29, 356, 393, -Vee, 


472 


223, 356, 403. 




393. 




29. 




29. 




29, A03. 




29, 472. 




29. 




29, 223, 393, 403, 


466 


393, 403. 




403. 




403. 




403. 




403. 




29, 403, 




403. 




29. 





384, 4C3, 443, 466, 

384, 403, 559. 

559. 

119, 384, 403, 443, 

384, 403, 559. 

106, 117, 369, 384, 

537. 
384, 403. 
384, 403. 

384, 403, 455, 537. 
384, 403. 

384, 403, 446, 455, 
384, 403, 559. 
384, 403, 510, 559, 
384, 403, 537, 559, 
384, 403. 585. 
384. 

384, 403, 510, 537, 
384, 403, 443, 455, 
443, 537. 
384, 403. 

403, 451, 537, 585. 
384, 537. 559. 
384, 403, 585. 
4C3, 510. 

334. 403, 451, 510, 
384, 403, 537. 
403. 

384, 403, 537. 
384. 
200, 384, 510, 537, 

559. 

351, 380, 384, 403, 
511, 537, 559. 

351, 384, 403, 443, 

351, 559. 

403. 466. 

537, 559. 

559. 

384, 537, 559. 

200. 

446. 

384, 403, 466. 

384, 403, 446, 451, 

403, 537. 

403, 510, 537. 

384, 403, 510, 537. 

380, 384, 403, 443, 

280, 384, 403, 451, 

280, 384, 455, 466, 

380, 384, 451, 537, 

384, 403, 443, 455, 

334, 403, 443, 537 

384, 403, 443, 455 



446, 455, 510, 537. 
389, 403, 443, 466, 510, 



466, 537, 559. 



559. 
537, 585. 



537, 559. 



443, 446, 451, 455, 510, 
451, 537, 559. 



510, 537, 585. 



451, 


455, 


537, 


559, 585 


455, 


466, 


537, 


559. 


537. 








559. 








510, 


537, 


559. 




559. 








510, 


537, 


559. 





86 



UNITED STATES TARIFF COMMISSION 



TABLE SB. --Synf/iefic organic chemicals: Coal-tar dyes for which United States production or sales were 
reported, identified by manufacturer , i954- -Continued 



Colour 
Index or 

Proto- 
type No. 



Manufacturers' Identification numtiers 
(according to list in table 27) 



100 
101 
102 
106 
107 
108 
109 
116 
118 
119 
121 
122 
124 
125 
126 
129 
135 
137 
138 
139 
Ul 
W3 
144 

145 
146 
147 

148 
151 
152 
157 
158 
162 
163 
164 
165 
166 
168 
169 
170 
171 
172 
173 
178 
181 
182 
186 
187 
188 
189 
191 
192 
193 
194 
195 
197 
198 
201 
2C2 
203 
206 



D'ffiS GHOUPED BY PROTOTYPE NTMBER — Continued 

Diazo brilliant scarlet PDA 

Diazo brown 6G 

Diazo brown MR 

Diazo brown 3RB 

»Diazo fast red 5BL 

»Diazo fast red 7BL 

Diazo indigo blue 4RL 

Diazo rubine B 

Diazo sky blue B 

Diazo sky blue 3GL 

Fast mordant blue B 

Fast scarlet 2G base 

»Fast scarlet 2G salt 

Slrius supra brown 3R 

Sirius supra gray R 

Sirius supra orange 5G 

Sirius supra yellow 50 

*Gulnea oannine B 

•Guinea fast red BL 

Guinea fast red 4BL 

Helindone fast scarlet B 

Helindone fast scarlet G 

Helindone pink B ex 

*Helindone pink R ex 

♦Indanthrene brilliant orange RK 

»Indanthrene brown BR 

Indanthrene bro\m GG 

»Indanthrene brown RRD 

»Indanthrene khaki 2G 

♦Indanthrene rubine R 

Indanthrene yellow brown 3G 

Indo carbon CL 

Katigen chrome blue 5G 

Metachrome red G 

Milling orange G 

♦Milling yellow H5G 

Milling yellow 

Naphthol blue black S 

Neolan black WA 

»Neolan blue GG 



Neolan Bordeaux R- 

Neolan orange R 

«Oxydiaminogen OB — 



♦Paper red A ex 

Polar orange GS 

♦Polar orange R 

Pyrogene orange G-CF 

Pyrogene violet brown X 

Pyrogene yellow brown 2RS-CF 

Rapidogen blue BN 

♦Rapidogen blue D 

♦Rapidogen Bordeaux R 

Rapidogen brown GN 

♦Rapidogen red GS 

♦Rapidogen red RS 

♦Rapidogen scarlet RS 

♦Rapidogen yellow G 

♦Rosanthrene fast Bordeaux 2BL 

♦Rosanthrene orange R 

Sudan brown 5B 

Sudan orange RT 

Sudan red BB 

Sulphon orange G 

♦Sulphon yellow R 

Supra light rubine BL 

Supramine black BR 

Supramine Bordeaux B 

Supramine brown R 

Supramine red 3B 

Supramine red 2G 

Supramine yellow R 

♦Victoria fast violet 2R ex 

♦Victoria pure blue B 

♦Zambesi black D 

Zambesi black V 

Acid anthracene brown KE 

♦Alizarin fast gray BBLW 



384, 


443. 






384, 


403. 






384. 








384, 


403. 






403, 


455, 


537. 




403, 


443, 


451, 


455, 


384. 








384, 


443, 


455. 




384. 








384. 








366, 


403. 






223, 


384, 


510, 


537. 


200, 


223, 


384, 


401, 


384. 








384. 








384. 








384, 


403. 






384, 


537, 


559. 




384, 


403, 


455. 


537, 


403, 


537. 






537. 








510, 


537. 






466. 








117, 


384, 


403, 


466, 


384, 


401, 


403, 


455, 


106, 


384, 


401, 


403, 


389. 








384, 


403, 


443, 


466, 


369, 


384, 


403, 


537. 


106, 


384, 


401, 


403, 


4C1, 


403. 






311, 


384. 






384. 








366. 








510. 








384, 


403, 


443, 


510, 


384, 


403. 






403. 








384, 


403, 


559. 




200, 


384, 


403. 


443, 


559. 






443, 


455, 


559. 




403, 


537, 


559. 




380, 


384, 


403, 


443, 


585. 






384. 


403, 


537, 


559. 


559. 








384, 


403, 


537, 


559. 


559. 








559. 








559. 








384, 


443, 


585. 




117, 


200, 


384, 


443, 


117, 


200, 


384, 


443, 


384, 


443. 






117, 


200, 


384, 


403, 


117, 


200, 


384, 


443 


117, 


200, 


384, 


403 


117, 


200, 


384, 


443 


384, 


403 


443, 


455 


384 


403 


443, 


537 


384. 








384. 








384. 








384 


510. 






384 


443 


455 


466 


384 


403 






384 


510 






384 








510 








384 


510 






334 








384 








384 


403 


466 


537 


223 


384 


399 


537 


384 


403 


559 




384 


403 


537 


559 


384 


443 






369 


384 


403 


455 



510, 537. 



403, 443, 510, 576, 583. 



510, 537. 
510, 537. 
466, 510, 



537. 
559. 



511, 559. 



451, 455, 466, 510, 537, 



446, 451, 510, 511, 559, 



537. 576, 
585. 



443, 466, 
466, 537, 
443, 466, 
466, 537, 
510. 537, 
559. 



537, 576, 585. 

576, 585. 

537, 576, 585. 

576, 585. 
559. 



466, 537. 



SYNTHETIC ORGANIC CHEMICALS, 195^ 



87 



TABLE m. -Synthetic organic chemicals: Coal-tar dyes for which United States productionor sale 
reported, identified by manufacturer, i954- -Continued 



DYES GROUPED BY PROTOTYPE NUMBER—Continued 



Alizarin supra sky R 

Alphanol brovm B 

Amido naphthol brown X 

Anthralan red B-CF 

Azosol fast orange G 

Azosol fast red 3B 

Azosol fast scarlet CGG 

Azosol fast yellow GR 

Benzo fast Bordeaux 6BL 

Benzo fast brown KL 

Brilliant indocyanine 6B-CF 

•Brilliant indocyanine G 

Brilliant sulpho flavine FFA 

Celliton fast blue FR 

»Celliton fast blue FFR 

Celliton fast blue green B 

■»Celliton fast brown 3R 

Celliton fast brown 5R 

Celliton fast navy blue B 

Celliton fast pink B 

*Celliton fast pink FF3B 

•Celliton fast red GG 

•Celliton fast red violet RN 

•Celliton fast rubine B 

•Celliton fast rubine 3B 

Celliton fast violet B 

Celliton fast violet 6B 

•Celliton fast yellow G 

•Celliton scarlet B 

•Celliton yellow 5G 

•Chlorantine fast red 5BRL 

Chrome fast orange 3RL 

Dianil yellow 5G 

Diazo brown 3R 

•Diazo fast yellow 2G 

Diazo fast yellow 3G 

•Erio chrome brown DKL 

Erio chrome olive BL 

Fast black B salt 

Fast black K salt 

Fast black LB base 

•Fast blue BB base 

Fast blue BB salt 

Fast Bordeaux BD salt 

•Fast Bordeaux QP base 

•Fast Bordeaux GP salt 

Fast corinth V salt 

Fast orange GC base 

•Fast orange GC salt 

•Fast orange W. salt 

Fast orange RD salt 

•Fast red AL salt 

Fast red 3GL base 

•Fast red 3GL salt 

•Fast red KB base 

•Fast red KB salt 

•Fast red RC base 

•Fast red RC salt 

Fast red RL base 



Manufacturers' identification numbers 
(according to list in table 27) 



Fast red RL salt 

Fast red TR base 

•Fast red TR salt 

•Fast violet B base 

Fast violet B salt 

Fast yellow GC base 

Fast yellow GC salt 

Sirius supra orange GG 

•Sirius supra red violet RL 

•Sirius supra turquoise blue GL — 

Inimedial new blue FBL ex 

•Indanthrene brilliant violet 3B- 

•Indanthrene direct black RB 

•Indanthrene golden orange 3G 

•Indanthrene golden yellow GK 

Indanthrene golden yellow RK 

•Indanthrene olive green B 



Indanthrene printing black BL- 
Indanthrene red FBB 



384, 


403. 












384. 














384. 














384. 














384. 














384. 














384. 














384. 














384. 














384, 


403. 












384, 


403. 












384, 


403, 


559. 










384, 


403. 












200, 


384. 












200, 


366, 


384. 


403, 


495, 


510, 


559. 


200, 


384, 


403, 


510, 


537. 






384, 


495, 


510. 










384. 














510. 














200, 


403, 


559. 










200, 


384, 


510, 


537. 








2C0, 


384. 


510, 


537. 








200, 


384, 


510, 


537, 


559. 






200, 


384, 


537. 










200, 


384, 


403. 


495, 


510, 


537, 


559. 


510. 














200, 


384, 


403, 


537. 








200, 


384, 


495, 


510, 


511, 


537, 


559. 


200, 


384, 


403, 


495, 


510, 


537, 


559. 


200, 


384. 


495, 


510. 








380, 


384, 


403, 


443, 


451, 


511, 


537. 


384, 


443. 












384, 


403. 












384. 














384, 


403, 


443. 










384, 














384, 


403, 


559. 










559. 














384, 


403, 


443. 










384, 


403. 












403. 














200, 


223, 


384, 


583. 








200, 


223, 


384, 


403, 


583. 






384. 














223, 


384, 


401, 


443, 


510, 


537. 




223, 


384, 


401, 


403, 


4^3, 


510, 


576. 


384. 














223, 


384, 


401, 


403. 








223, 


384, 


401, 


403, 


510. 






223, 


384, 


401, 


403, 


510. 






223, 


384, 


403, 


510. 








223, 


384, 


403, 


443, 


510. 






223, 


510, 


537. 










223, 


384, 


401, 


403, 


443, 


510, 


576, 583. 


223, 


384, 


401, 


403. 


466, 


510, 


576, 583. 


200, 


510, 


537. 










223, 


384, 


401, 


510. 








200 


223, 


384, 


401, 


403, 


510. 




223 


384. 












200 


223, 


384. 










401 


403, 


443. 










384 


401, 


510 


583. 








200 


223, 


384 


443. 








223 


384 


583. 










401. 














237 


384. 












384 


537. 












384 


537 


585. 










200 


237 


384 


403 


455, 


511, 


537. 


384 














106 


384 


537 










106 


384 


403 










106 


384 


389 


401 


403 


537. 




106 


117 


369 


384 


403 


443 


455, 510, 537 


117 


369 


384 


403 


455. 






106 


237 


369 


384 


389 


401 


403, 466, 510 


537. 












384 


403 












384 


403 













88 



UNITED STATES TARIFF COMMISSION 



TABLE 8B. --Synthetic organic chemicals: Coal-tar dyes for which United States productiory or sales were 
reported, identified by manufacturer , 1954- -Continued 



Colour 
Index or 

Proto- 
type No. 



Msnufacturers' Identification numbers 
(according to list in table 27) 



298 
299 
300 
301 
302 

303 
304 
305 

306 

307 

308 

309 

310 

311 

312 

313 

31-; 

315 

316 

317 

318 

319 

321 

322 

32<; 

325 

326 

327 

328 

329 

330 

332 

333 

33?~ 

336 

339 

340 

341 

342 

343 

344 

345 

347 

348 

349 

350 

351 

352 

353 

357 

358 

360 

361 

364 

365 

366 

367 

368 

369 

370 

371 

372 

375 
376 
377 
378 
378 
379 
381 
383 
385 
386 
387 
388 
389 



DffiS GROUPED BY PROTOTYPE hEmBER — Continued 

Metomega chrome brown KLL 

"Monochrome black blue G 

Monochrome red FG 

Monochrome violet FB 

»Naphthol AS 

•Naphthol AS-BO 

»Naphthol AS-BR 

•Naphthol AS-BS 

«Naphthol AS-D 



Naphthol AS-DB 

"Naphthol AS-E 

"Naphthol AS-G 

"Naphthol AS-ITR 

"Naphthol AS-OL 

Naphthol AS-RL 

"Naphthol AS-SW 

"Naphthol AS-TR 

"Neolan orange G 

Neolan yellow OR 

Omega chrome yellow ME- 

Palatlne fast blue BN 

Palatine fast blue RRN- 



Palatine fast green BLN 

Palatine fast marine blue REN- 

Palatine fast orange GN 

Palatine fast orange RN 

"Palatine fast pink BN 

Palatine fast red RH 



Palatine fast violet 3RN 

Palatine fast violet 5RN 

"Palatine fast yellow ELN 

Pluto black G 

Pyrazol fast orange GL 

Rapid fast orange RH 

Rapid fast red RH 

Rapidogen black HG 

Rapidogen black brown IT 

"Rapidogen blue N 

Rapidogen blue R 

Rapidogen brown IB 

"Rapidogen brown IPT 

Rapidogen golden yellow R 

Rapidogen green B 

Rapidogen orange G 

"Rapidogen orange R 

Rapidogen red violet RR 

•Rapidogen violet B 

Rapidogen yellow G 

Rapidogen yellow 2G 

Variamine blue BD salt 

Variamine blue RT salt 

Acid chrome red B 

Alizarin rubinol 3G 

Benzochrome brown B 

Benzoehrome brown G 

Benzo fast heliotrope KRL 

Brilliant benzo fast violet BL — 

Brilliant benzo green B 

Celliton brilliant yellow FF 

Celliton fast pink RF- 

Chrome leather fast black S 

"Cotonerol 

Diamond black P3 

Diazo brilliant orange CK 

Diazo brilliant scarlet 5BLN — 

"Fast red ITR base 

Fast red ITR salt 

"Sirius supra gray VOL 

Indanthrene orange 4R 

Janus black G 

"Naphthol AS-BG 

Naphthol AS-CK 

Naphthol AS-LB 

Naphthol AS-SO 

Neolan pink B 



559. 

384, 403, 455, 

119, 384. 

384. 

160, 223, 284, 

576, 585. 
160, 223, 384, 
160, 223, 384, 
160, 223, 384, 

576, X. 
160, 223, 384, 
576, 585, X. 
223, 384, 
160, 223, 384, 
160, 223, 310, 
160, 200, 223, 
160, 223, 384, 
223, 384, 537. 
160, 223, 384, 
160, 384, 510. 
384, 443, 455, 
384, 403, 443, 
559. 

384, 443. 
455. 

384, 403, 443, 
200, 403, 443, 
466. 
384. 

200, 384, 4^3, 
384, 443. 
384. 

384, 466. 
384, 443, 455, 
446. 
559. 
466. 
334. 
384. 
384, 585. 

200, 384, 443, 

384, 585. 

384, 585. 

384, 443, 585. 

384, 466, 585. 

384. 

384. 

200, 384, 403, 

384, 443. 

U7, 200, 384, 

384, 576. 

200, 384, 537, 

384, 583. 

384. 

384. 

384. 

384. 

384. 

384, 403. 

384, 403, 537. 

384, 403. 

384, 403. 

384, 537. 

384. 

200, 380, 384, 
585. 

384. 

384. 

384, 403, 443, 

200, 223, 384, 

223, 384, 583. 

384, 403, 455, 

384, 403, 537. 

384. 

160, 223, 384, 

384. 

384. 

160, 223, 384, 

384, 403, 559. 



537, 559. 



403, 443, 466, 487, 510, 537, 

403, 466, 510, 537, 576. 

403, 510, 576. 

403, 443, 466, 487, 510, 537, 

403, 443, 466, 487, 510, 537, 



403. 

384, 403, 443, 510, 537. 

384, 510, 576, 583. 

403, 466, 510, 537, 576, 585. 

403, 443, 466, 510, 537, 576. 

559. 

455, 537, 559. 



559. 
455. 



455, 466, 537, 559. 



466, 537. 



443, 585. 
443, 585. 
585. 



403, 443, 455, 510, 537, 559, 

537. 
583. 

585. 

403, 510. 
537. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



89 



TABLE SP- --Synthetic organic chemicals: Coal-tar dyes for which United States production or sales were 
reported, identified by manufacturer , 1954--Continued 



Colour 
Index or 

Proto- 
type No. 



391 
393 
394 
397 

402 

403 

404 

408 

409 

412 

413 

416 

417 

418 

420 

421 

422 

423 

424 

425 

426 

427 

428 

429 

430 

432 

433 

435 

436 

438 

439 

442 

443 

446 

447 

448 

449 

450 

451 

452 

453 

456 

457 

460 

461 

462 

463 

467 

468 

469 

470 

471 

472 

474 

484 

485 

487 

488 

489 

490 

491 

492 

493 

494 

495 

496 

497 

498 

498 

499 

501 

501 

503 

504 

505 

506 

507 

508 

509 



DtES GROUPIE BY PROTOTWE NUMBER— Continued 
Neolan red ORE — 



Oxamine brilliant red B 

Palatine fast claret BN 

Para brown V 

Rapidogen red ITR 

Rapldogen scarlet IL 

Rosanthrene Bordeaux B 

Acid chrome blue 3G 

Algol scarlet B — 

Azo rubinol 3GP 

Azosol fast blue HL 

Benzo fast gray BL 

Brilliant congo blue BFL 

Brilliant wool blue G 

Celliton fast yellow 7G 

Chlorantine fast Bordeaux 2B 

Chlorantine fast Bordeaux BLL 

Chlorantine fast brown 8RLL 

Chlorantine fast gray RLN 

Chlorantine fast green BLL 

Chlorantine fast orange T4RLL 

Chlorantine fast orange T5RLL 

♦Chlorantine fast red 6BLL 

»Chlorantine fast violet 5BL 

Chlorantine fast violet RLL 

*Chlorazol blue 5GKS 

Derma brown G 

Diazanil orange RR 

Diazo brilliant blue 2BL 

Diazo fast Bordeaux FBL 

Diphenyl fast yellow RL 

Fast scarlet TR base 

»Sirius light blue FBGL 

Indanthrene orange F3R 

Indanthrene red brown R 

Indanthrene red brown 5RF 

Indanthrene scarlet R- 



Manufacturera' identification numbers 
(according to list in table 27) 



Indanthrene yellow FFRK 

Indanthrene yellow GF 

Indanthrene yellow 3R 

Kiton fast red 4BLN 

Metomega chrome brown 3GL 

Metomega chrome orange ML 

Naphthol AS-LC 

Naphthochrome violet R 

Neolan blue 2R 

Neolan orange GRE 

Rapidogen golden yellow IK3 

Rapidogen red IGG 

Rapidogen yellow 14G 

Diphenyl fast blue green BL 

Sudan red GG 

Sudan yellow GRN 

Supramine yellow 3GL 

Chromoxane brilliant violet SB — 

Alizarin light blue 4GL 

Azosol fast blue M 

Azosol fast red BE 

Brilliant indo blue 5GL— 



Chloramine fast orange 2RN 

♦Chlorantine fast violet 2RL 

Cloth fast yellow 5G 

Diazo brilliant scarlet BA 

Diazo brilliant scarlet ROL 

Diazo fast yellow 3GLL 

Diphenyl fast blue red R- 

Erganil gray BC 

Fast blue RR base 

Fast blue RR salt- 



Fast corlnth LB salt 

♦Fast red FDC base 

»Fast red PDC salt 

♦Indanthrene red violet RRN- 

Leather brown ET 

Naphthol AS-LG 

Naphthol AS-LT 

Neolan Bordeaux BE 

Neolan Bordeaux RM 

Neolan red BRE 



403, 

403. 

384. 

384. 

384, 

384. 

384, 

384. 

384. 

559. 

384. 

403, 

403. 

403. 

384. 

403, 

403. 

403, 

403. 

384, 

403, 

403. 

200, 

403, 

403. 

380, 

559. 

384, 

384, 

384. 

403. 

384. 

380, 

403. 

510. 

384, 

384, 

403. 

403. 

537. 

443, 

559. 

403, 

384. 

403. 

403, 

559. 

384, 

585. 

384, 

403, 

384. 

384, 

384. 

384. 

403, 

384. 

384. 

384. 

559. 

380, 

559. 

537. 

384. 

559. 

403. 

384. 

537. 

384. 

223, 

223, 

223, 

117, 

384. 

160, 

384. 

559. 

559. 

559. 



559. 



585. 
537, 559. 



451. 



451, 511, 559. 

537. 

403, 537, 559. 
559. 



380, 403, 443, 451, 455, 537, 559. 
537, 559. 

384, 403, 433, 466, 537, 559. 



537. 
403. 



384, 451, 466, 559. 



403, 537. 
403. 



559. 
559. 

559. 

585. 

585. 
559. 

403. 
537, 559. 



384, 403, 443, 511, 537, 559, 585. 



384. 

384, 443, 510, 583. 

384, 443,- 510, 583. 

384, 537. 

384. 



90 



UNITED STATES TARIFF COMMISSION 



TABLE m. -Synthetic orga 



ic chemicals: Coal-tar dyes for which United States production or sales were 
reported, identified by manufacturer, 7954--Continued 



Colour 
Index or 

Proto- 
type No. 



Dye 



Manufacturers' Identtfleation numbers 
(according to list In table 27) 



511 
513 
5W 
515 
516 
517 
519 
520 
522 
523 
52A 
525 
526 
527 
529 
530 
531 
532 
533 
53A 
535 
536 
537 
538 
539 
540 
542 
543 
545 
547 

551 
552 

553 
554 
555 
556 
557 
558 
559 
560 
561 
562 
565 
566 
567 
568 
569 
571 
572 
575 
576 
577 
578 
579 
580 
582 



DYES GROUPED BY PROTOTYPE NUMBER — Continued 



Rapldogen corlnth IB 

Xylene fast orange PO 

Acid alizarin black KGW 

Acid leather brown EQB 

Alizarin saphirol WSA 

Azosol fast yellow R 

Buffalo black 30 

Calcofast spirit orange RN 

Caledon dark blue G 

»Cellitazol AZN 

Chloramine copper blue 3G 

Chloramine copper blue 4G 

Chlorantlne fast yellow 2GLL- 

Chrome fast green G 

Diaminogen tlue NA 

Diazo fast green GF 

Dlazo fast violet BL 

Dipyrazo scarlet RP 

•Direct chinoline 



Dispersol fast yellow 2G 

Durazol fast blue 3RS 

Durazol fast orange R 

♦Eastman fast yellow GLF 

Eastone blue BGF 

Erie fast rubine B 

Fast brown salt VA 

Fluorol 5G 



Guinea brown RD 

Immedial black brown A 

»Indanthrene olive T 

Interchem acetate orange 4R — 

Leather brown 5RTX 

Luxol brilliant green BL 

Luxol fast blue ^ES 

Naphthol AS-L3G 

»Naphthol AS-MX 

»Naphthol AS-PH 

Naphthol AS^R 

Naphthol AS-RC 

Neolan dark green B 

Neolan navy blue RLG 

•Neutral brown RX 



Pontamlne black AWG 

Pontamine diazo brown R 

Pontamine dlazo orange 

Pontamine diazo orange 3G 

"Pontamine navy blue DB 

Rapidogen black 3G 

Rapldogen blue PEN 

Sirlus supra brown 2RL 

Sirius supra orange RRL 

Sirlus supra scarlet GG 

•Solantlne orange 4G 

Supranol brown 3GL 

Varlamine blue FG salt 

»Sirius supra yellow R ex 

UNCaiOUPED DYES 



•Acetate rayon dyes: '■ 

•Black, IV ex., B, DB, EC, 30, GGN, GOO, GS, 

GY, J, LNB, NC, PL, R, RB, RK, SS.^ 
•Blue, #15, A8^5, AGF, B, 2B, BG, BGLF, BN, 
BP, OR, EC, G, 2G, 5G, 6G, GBN, GFD, GLF, 
GLT, GP, GR, GSF, GSS, LB, LWGF, MJ. NBN. 
N7Y, RB, RBN, RDA, RG, 2R, 3R, 4R, WNBN.^ 

Brown #8, JO, R 

Orange, FSI, GR, GRN, R, 2R, 3R, 2RP, 
RD-GLF.* 

Pink, 3BGLF, FFB, ^BS 

•Red III, VI-X, AB, B, 2B, 3B, 2B-GLF, 4BLL, 
C, FFB, G, GLF, GSF, MBS, NB, R, RP, 
WLF-40, Y, YP.' 
Violet B, 7BC, BGF, BN, DAC, FSI, MB, 2R, 
3RGFL, 5RLF. 
•Yellow, CW, FSI, G, X, 5G, 8GLF, GL, CR, I, 
III, DC, M, N, PGA, R, 2RGLF, 4RL, 4RLA, 
4HLF, 4RL-SN, RJJ, YL.* 



See footnotes at end of table. 



384, 585. 

403. 

559. 

384. 

384, 537. 

384. 

403. 

384, 466. 

537. 

384, 495, 537, 559. 

384, 559. 

384. 

559. 

403, 559. 

403, 537. 

384. 

403, 443. 

403, 443. 

384, 403, 443, 466. 

537. 

537. 

537. 

200, 403, 495, 510. 

495. 

403, 537. 

384. 

384. 

384. 

384. 

106, 237, 369, 384, 389, 401, 403, 455, 466, 

510, 537. 
200, 537. 
384, 403. 
384, 537. 
403, 537. 
384. 

160, 223, 384, 510, 576, 585. 
160, 223, 384, 537, 576, 585. 
384. 

160, 384. 
559. 

403, 443. 

403, 455, 537, 559. 
403, 537. 
384, 537. 
403, 537, 559. 
537. 

403, 446, 451, 466, 5U, 537, 559. 
384. 

384, 585. 
384, 403. 
384. 
403. 

200, 380, 403, 443, 466, 5U, 559. 
384. 
384. 
380, 384, 403. 443, 451, 455, 511, 537, 559. 



200, 403, 446, 451, 495, 510, 537, 559. 
200, 384, 403, 495, 510, 537. 



200, 495. 

200, 403, 446, 495, 510, 537. 



403, 495. 

200, 403, 446, 451, 495, 510, 537, 559. 



200, 384, 403, 495, 510, 537. 

200, 384, 401, 403, 495, 510, 537, 565. 



SYNTHETIC ORGANIC CHEMICALS, i95/i 

TABLE m. -Synthetic organic chemicals: Coal-tar dyes for which United States production or sale 
reported, identified by manufacturer , 1954- -Continued 



91 



Dye 



Manuf aoturera ' identification numbers 
(according to list in table 27) 



UNCfflDUPED DICES — Continued 

Acid alizarin Bordeau:c BLT 

Acid alizarin brovm RLL 

Acid anthracene brovm TBL 

Acid black AR, GHF. N. RB 

Acid blue G. NB 

Acid Bordeaux NB- 



Acid brilliant pink 3B 

Acid brilliant red 3B 

Acid brown CRTA, ITGA, m30, NY, PGMA, R, RD— 

Acid chrome blue GW 

Acid dark brown B 

Acid dark green B 

Acid fast brown GGS 



5G- 



Acld fast red GL 

Acid leather brown 

Acid milling orange RN 

Acid milling yellow GN 

Acid navy blue 

Acid orange 2G, MR, R 

Acid red B, 2B, 3B, G, RB, 3RB 

Acid scarlet GN 

»Aold violet NR, R, 2R, 3RL, RNL 

Acid woodstaln black GRF, N 

»Acld yellow 3G, 6G, N, NR, NW, 3RD 

Alizarin blue GS 

Alizarin sapphire EMM 

Alizarin violet NBR 

Alphazurlne B 

Anthracene chrome brown RL 

Anthraqulnone blue BGA, 3G, 2GA, 3GW, RA 

Anthraquinone milling blue BL 

Anthraqulnone vat black 2G, J, R 

Anthraqulnone vat black brown VA 

Anthraquinone vat blue BCL, GR 

Anthraqulnone vat blue green 3B, Y 

Anthraquinone vat brilliant red B 

Anthraquinone vat brilliant violet 3R 

Anthraqulnone vat brilliant yellow 3G, 4G 

Anthraqulnone vat brown BB, BN, NR, VR 

Anthraqulnone vat copper brown 

Anthraqulnone vat direct black 3G, 3GA 

Anthraqulnone vat fast yellow 

Anthraquinone vat golden orange AC 

•Anthraquinone vat gray BR, 20, GFL, GNF, R — 

Anthraquinone vat maroon 3N 

Anthraquinone vat olive G, 2GL 

Anthraquinone vat printing black BBD, PG, R- 

Anthraquinone vat red FG, RL, RRB 

Anthraqulnone vat red brown N, RB 

Anthraqulnone vat scarlet 3GA, GL 

Anthraqulnone vat yellow EK, 5GLL, K, LN, Pa 
Anthraquinone violet A — 

Azo black NV 

Azo blue G, RS 

Azo brown BY, DW, RRK 

Azo cardinal WF 

Azo ceresine B — 

Azo eosine 2B — -— 

Azo green FB, FFW, G 

Azo navy BR, CV, LN 

Azo oil black B — — —- 

Azo olive green BLN 

Azo orange BRS, GRN, RXA 

Azo red Z 

Azo rubine B, S 

Azo scarlet 

Azo turquoise B — ■ 

Azo violet 0, R- 



Azo wine WF 

Azo yellow DW, G, 3 

»Azolc dyes and their components:' 
Dyes, rapidogen: 

Black, A, 2B, BR, DM, ITA, J, MR- 
Blue AS, B, 2B 



537. 
537. 



38A. 

38<;. 

38^. 

-403, 

384, 

38A. 

537. 

443. 

384, 

384. 

537. 

537. 

537. 

451. 

403. 

466. 

537. 

537. 

466. 

384, 

403, 

537. 

351. 

443. 

119, 

537. 

384, 

403. 

403. 

403. 

403. 

366. 

537. 

537. 

403, 

384, 

384, 

384, 

537. 

537. 

384, 

403, 

466. 

384, 537. 

466. 

537. 

384, 403, 466, 510, 537 

384. 

403, 

403, 

537. 

537. 

384, 

403, 

537. 

466. 

351. 

351. 

351. 

351, 

351. 

466. 

537. 

351, 

351. 

403. 

443. 

443. 

351. 

351, 

351. 

351. 

443. 

351. 

351. 



384, 443, 537, 583, 585. 
200, 223. 



537. 
443, 537. 



366, 384, 403, 446, 537. 
403, 443, 537. 



466. 
455. 
403. 
537. 



537. 
537. 



537. 
510. 



537. 
537. 



See footnotes at end of table 



92 



UNITED STATES TARIFF COMMISSION 



TABLE SB. --Synthetic organic chemicals: Coal-tar dyes for which United States product i 
reported, identified by manufacturer , i 954- -Continued 



I or sales were 



. Colour 
Index or 
Proto- ! 
type No. I 



Dye 



Manufacturers' Identification numbers 
(according to list in table 27) 



UNGROUPED DYES—Contlnued 

'Azoic dyes and their components' — Continued 
Dyes, rapldogen — Continued 

Bordeaux AF, ^E 

Dark brovm AR 



Golden yellow MRS, N- 
Gray R 



Navy blue F, FFBR, FFR, GA 

Orange FFR, M3 

Red AFR, AS, BB, 3B, 2BN, FB, FFBB, 
KB, KBS, RC. 

Scarlet FFG, 2G, 2R 

Yellow AGL, GR 

Components: 

Fast color bases: 

Blue BE, B-P 

Claret KB-P 

Garnet GBCP, GC 

Orange R-P 

Red FB 

Fast color salts: 
Blue B-P, RBN- 



Orange RD-P 

Red FDC 

Fur dyes: Fur #2, #<i, BCA. NZA, NZF~ 
Naphthols: 

Naphthol AS-BB 

Naphthol AS-BC 

Naphthol AS-BGN 

Naphthol AS-BG-P 

Naphthol AS-BN 

Naphthol AS-BO-P 

Naphthol AS-BS-P 

Naphthol AS-CW 

Naphthol AS-EL 

Naphthol AS-HB 

Naphthol AS-KB 

Naphthol AS-hC 

Naphthol AS-PN 

Naphthol AS-RL-P 

Naphthol AS-5RN 

Naphthol AS-RO 

Naphthol AS-RR 

Naphthol AS-RT 

Naphthol AS-SG-P 

Naphthol AS-ST 

All other components 

Azosol brilliant blue B 

Azosol fast brilliant red BN 

Basic blue B, OB 

Basic blue black BA 

Basic green 

Basic orange L : 

Basic red AG, L 

Basic yellow OL, OR 

Benzo fast copper brown BRL 

Benzoform red G 

Brilliant cyanine green 5G 

Brilliant blue B, R 

Brilliant fast red LBL 

Brilliant oil blue BMA 

Brilliant sky blue 8GA, RRMA 

Brilliant violet AB, R 

Canary lake yellow PL 

Celliton yellow 6D 

Chlorantlne fast green 5GLL 

Chroma te brown R, RL 

Chrome black 3G 

Chrome Bordeaux B 

Chrome brown B 

Chrome cyanine BLL 

Chrome fast green G 

Chrome garnet GR 

Chrome gray BL 

Chrome green B, G 

Chrome orange LC, 3R 

Chrome soga yellow A 



200, 
3SA, 
537, 
537, 
384, 
384, 
384, 
200, 

223, 
537. 



443, 537, 576. 
443. 

585. 

443. 

443, 585. 

537. 

223, 384, 443, 537, 585. 

384, 443. 



223, 537, 583. 

223. 

223, 250, 384, 401, 583. 

223. 

511, 583. 

223, 443. 
223. 

576. 
455. 

384. 

384. 

223. 

223. 

384. 

223. 

223. 

160. 

223. 

223. 

160, 223, 384, 510. 

384. 

466. 

223. 

384. 

403. 

384. 

160. 

223. 

384. 

537. 

384. 

384. 

537. 

384. 

537. 

537. 

537. 

537. 

384. 

384. 

369. 

510, 537. 

585. 

403. 

384. 

510. 

403. 

384. 

559. 

366, 455. 

403. 

200. 

403. 

403, 559. 

559. 

119. 

366. 

119, 403. 

403, 466. 

384. 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



93 



TABLE SB- --Synthetic organic chemicals: Coal-tar dyes for which United States product! 
reported, identified by manufacturer, 19 54 --Continued 



or sales were 



Dys 



Manufacturers' Identification numbers 
(according to list In table 27) 



UNQROUPED DYES— Continued 

Chrome yellow 2CN, GR, RL, SW 

Cupranine brovm B 

Cupramlne orange RB 

Developed brown CBS 

Developed orange A, RFW, WD 

Developed scarlet GFW 

Diamine catechine ER 

Diazo blue MP 

Diazo brilliant scarlet 2QA 

Diazo fast orange GL 

Diazo orange LGA ~ 

Diazophen red BTB 

Diazophen yellow BTP 



»Direct black, CW, DB, 3G, 5G, GN, 3GR, HH, MB, 

RCW, RW. 
•Direct blue, 2BCF, BFL, lOBLL, 12BLL, 16BLL, 
lOBLU, BR, BUW, 2GFL, GL, 3GLL, 4GLL, 8GLN, 
8GUF, LBLL, LDU, LULR, NPC, NH, R, RDW, 
2RCF, 3R, RL, RLU, 2RFL, 2RHJ, 7RLL, UGLL, 
VRS. 

Direct blue green CW ___ 

Direct Bordeaux B, RLFW 

Direct brilliant blue J 



Direct brilliant brown S 

•Direct brown, GB, 3GS, KRS, NZ, 2R, 3RLL, RSC, 

RY. 

Direct catechine 2BAC 

Direct copper blue BF 

Direct diazo blue 3G, 6G, 5GL 

Direct diazo brown 6G 

Direct diazo green BL, 2GL 

Direct diazo orange G, GR, N, WD 

Direct diazo scarlet R, RN 

Direct diazo violet BL, RR 

Direct diazo yellow 2GL 

Direct fast black GRNX 

•Direct fast blue, BLL, 2BRN, CPL, 30L, 8GLL, 

GLFV, L5GA, L6GA, LRRU, RL, 3RL, 2RLL, 

SFGL, SFRL. 

Direct fast brilliant blue LSGU 

Direct fast brown 4GL, R, AR, 2RL, 4fiL, 2RLL, 

SKRL, 3YL. 

Direct fast copper Bordeaux BGL 

Direct fast gray BL, 3BL, 2GL, 3GL, LGL 

Direct fast heliotrope FFB 

•Direct fast orange, G, GL, 2GL, 4GLL, L8GL, 

3LWF, R. 
•Direct fast red, 3BL, 8BLN, 8BLSW, 8BNL, GBL, 

L^BL, WL. 

Direct fast rubine BBLL, WL 

Direct fast violet BL, R 

•Direct fast yellow, EFC, 5G, 3GL, 8GLL, 4GLP, 

L2R)C, 3R. 

Direct garnet RB 

Direct gray BBC, 2G, 2GFL, GL, 3LUF, LVBL, 

LVL, LVLU, UFLL. 

Direct green B, 5GSC, 2Y 

Direct lumisol blue GL, GLS, RL 

Direct lumisol gray G 

Direct maroon LFS, LFVS 

Direct orange C, 2GLL, LR, 3LWF, RT, UF2G 

Direct red 7B, 9B, 8BLN, 5BLU, RL 

Direct rubine BB, WLKS 

Direct scarlet B, BCW, G 

Direct silk blue NR 

Direct violet BCW, 2R 

•Direct white, ACC, ACL, B, AB, 5B, ABU, BP, 

GG, K, LD, MR, M2R, P3R, 2R, RN, RW, SC, WT. 

Direct yellow EFC, G, S5GP 

Euchryslne 2GA 

Fast acid orange RW 

Fast acid yellow GS 

Fast black FTC, G 

Fast Bordeaux BN, RB 

Fast brilliant crimson RB 

Fast brown FN, MF 

Fast crimson R 



403, 537. 

351. 

351. 

'W3. 

-^03, AA3. 

403. 

384. 

585. 

384. 

559. 

384. 

466. 

466. 

351, 401, 446, 510, 559. 

200, 351, 380, 403, 443, 451, 466. 



403. 

351, 403. 

351. 

403. 

351, 403, 451, 466, 510. 

403. 

451. 

451, 537. 

537. 

537. 

537. 

537. 

537. 

537. 

451. 

384, 403, 451, 455, 537. 



384. 
403, 

403. 
384, 
200. 
384, 



451, 537. 

455, 537. 

403, 451, 455, 537, 559. 

446, 451, 455, 510, 537. 



403. 










403, 


443, 


451, 


537, 559. 




403. 










200, 


351, 


380, 


401, 403, 


466. 


403, 


466, 


537. 






559. 










559. 










351. 










351, 


380, 


443. 






200, 


351, 


443. 






351. 










351, 


510. 








384. 










200, 


403. 








223, 


384, 


403, 


443, 466, 


505, 537, 595 


351, 


403. 








384. 










559. 










403. 










466, 


510. 








455. 










466. 










403. 










466. 










403. 










466. 











94 UNITED STATES TARIFF COMMISSION 

TAHLE SB. --Synthetic organic chemicals: Coal-tar dyes for which United States production or sale 
reported, identified by manufacturer, J954- -Continued 



Colour 
Index or 

Proto- 
type No. 



Dye 



UNGROUPED DYES — Continued 



Fast orange LW, YF 

Fast red B 

Fast spirit black RB 

Fast spirit brown GN 

Fast spirit yellow G, 2RN— 

Fast violet 5RN 

Fast wool orange FF 

Fast wool yellow GL 

Fast yellow G, 2G, N 

Fluorescent green HW 

Fluorescent yellow HEB 

Fluorol VGA, OBR 

Formaldehyde blue 2B 

Formalide deep blue R 

Gasoline yellow 

R.F. Green 2B 

Indian brown 3G 

Indigo blue 

Ink blue PP 

losol black 

losol blue, 60 " 

losol green 

losol orange 

losol red 

losol violet 

losol yellow — 



Manufacturers' identification numbers 
(according to list in table 27) 



Levelling blue 2R 

Methyl orange 

Milling red brown 

Milling yellow XN 

Navy blue G 

Neutral black BSS 

Neutral brown R — 

Neutral dark brown H 

Neutral red 30 

Neutral silk brown 0, R, RG 

Neutral silk yellow CGA, SX 

Nydye blue GB 

Nydye orange 2R 

Nydye red 3B 

Nydye scarlet G 

Nydye violet BX 

Nylanthrene blue 3BLF 

Nylanthrene navy LFWG 

Nylanthrene orange RRLF 

Nylanthrene red 2RWF-^ 

Nylanthrene rubine 5BLF 

Nylanthrene scarlet YLFW 

Nylanthrene yellow FLW 

Oil black BT 

Oil blue A, AP, NE 

Oil brown #79, #102, M, Y 

Oil fast blue R 

•Oil orange, #30, MT 

Oil pink B- 



«Oil red, #322, #430, DB, ED, EON, N-1700, 0, RO 
Oil yellow PHW 

Oxydiaminogen BBA 

Palatine fast blue 5RNA 

Palatine fast yellow 5GN 

Pluto orange C2U 

Qulnoline yellow P 

Resin brilliant red R 

Resin brown Z 

Resin dark red Z 

Resin fast blue 7GL, 4GLR, LBGL, LBL, LLGG, 
LDL, 2RLL, UGLL. 

Rhodamine B stearate 

Spirit-soluble blue 

Spirit-soluble brown 2RS 

Spirit-soluble fast black 

Spirit-soluble fast blue B 

Spirit-soluble fast green B 

Spirit-soluble fast orange A 

Spirit-soluble fast red M, Y 

Spirit-soluble fast yellow 30 

Spirit-soluble green- 
Spirit-soluble orange M, RS 



^6, 510. 

466. 

466. 

466. 

466. 

451. 

403. 

403. 

451. 

11. 

466. 

384. 

559. 

446. 

466. 

585. 

384. 

510. 

403. 

403. 

403. 

403. 

403. 

403, 

403. 

403. 

510. 

537. 
403. 
403. 

510. 
403. 

403. 
446. 

510. 

351. 

351, 455. 

351. 

351. 

351. 

351. 

351. 

351. 

351. 

351. 

351. 

351. 

351. 

351. 

403. 

466, 510, 537. 

250, 403. 

510. 

250, 265, 466. 

403. 

250, 403, 466, 510. 

466. 

510. 

384. 

384. 

384. 

384. 

537. 

403. 

403. 

403. 

585. 

403. 
466. 
366. 
403. 
403. 
403. 
403. 
403. 
403. 
403. 
366. 
403. 



SYNTHETIC ORGANIC CHEMICALS, I95A 



95 



TABLE HK. --Synthetic organic chemicals: Coal-tar dyes for which United States producti 
reported, identified by manufacturer, 1954- -Continued 



Colour 
Index or 

Proto- 
type No. 



Dye 



Manufacturers' Identification numbers 
(according to list in table 27) 



TOCKOUFED DIES— Continued 



Spirit-soluble red MS 

Spirit-soluble red brown MR 

Spirit-soluble scarlet MD 

Spirit-soluble violet hE 

Spirit-soluble yellow OR, MDS 

Stllbene orange E3G 

Sudan corinth 3B 

Sudan dark brown BG 

Sudan yellow GRA 

Sulfur direct blue N 

Sulfur direct brown CWR 

Supra blue FELL 

Supramine pure blue BL-CF 

Synlan black J 

Toluylene fast brown 3GA —- 

Vat black, DM 

Vat printing black GR . - 

Vat yellow PGA 

Water black SR 

Yellow new MF4 



403. 

403. 

403. 

403. 

403. 

466. 

384. 

384. 

384. 

403. 

403. 

510. 

384. 

559. 

384. 

106, 335. 

311. 

106. 

403. 

335. 

106. 

466. 

384. 

119, 265, 537. 



^ Excludes acetate rayon dyes that appear under "Dyes Grouped by Prototype Number." 
^ Includes developed black and diazo black. 
^ Includes brilliant blue and navy blue, 
* Includes golden orange and monocel orange. 
' Includes monocel red, rubine, and scarlet. 
' Includes fast yellow, golden yellow, and printing yellow. 
Does not include azoic dyes and their components that appear under "Dyes Grouped by Colour Index 
Number" and "Dyes Grouped by Prototype Number." 



UNITED STATES TARIFF COMMISSION 

Toners and Lakes 



TABLE ISB.- -Synthetic organic chemicals: Toners and lakes for which United States production or sales were 
reported, identified by manufacturer, 1954 

[Toners and lajces for which separate statistics are given in table 15A are marked below with an asterisk 
(•); those not so marked do not appear in table 15A because the reported data are accepted in confidence 
and may not be published. Manufacturers' identification numbers shown below are taken from table 27. An X 
signifies that the manufacturer did not consent to the publication of his identification number with the 
designated product] 



Product 



Manufacturers' identification numbers 
(according to list In table 27) 



TCNZBS CR rOLL-STRDJQlH COLORS 



»Black toners: 

Aniline black- 

PMA black 

PIA black 

•Blue toners: 

•Alkali blue, C.I. 704 



Dlanlsidine blue (Naphthol AS^ and dianisidlne) — 
Dianisldine blue (Naphthol AS-OL and dianisidinfi ) - 
Indanthrene blue CKD (C.I. 1113)-- 

Methylene blue (C.I. 922) 

Peacock blue GG, PTA 

Peacock blue R (C.I. 664), PMA 

Peacock blue R (C.I. 664), PTA 

»Phthalocyanlne blue B, Pr. 481 



Phthalocyanine blue B (Pr. 481), resinated 

Pigment blue WKL 

»Setoglauolne (Peacock blue G) (Rhoduline blue 6G) 
(C.I. 658), FMA. 

•Setoglaucine (Peacock blue G) (Rhoduline blue 5G) 
(C.I. 658), PIA. 

Victoria blue B (C.I. 729), PMA 

Victoria blue B (C.I. 729), PTA 

Victoria blue B (C.I. 729), fugitive 

Victoria blue BGO, ItlA- 
Victoria blue R (C.I. 728), mA- 



•Vlctoria pure blue B (Pr. 198), PMA- 
•Vlctorla pure blue B (Pr. 198), PTA 



Brown toners: 

Bismarck brown 

B.O.N, brown 

fMA brown—— 



Gun metal brown- 
Havana brown 

Para brown 

All other 



•Green toners: 

•Brilliant green (C.I. 662), PMA- 
•Brllliant green (C.I. 662), PTA- 



Brilliant green (C.I. 662) and malachite green 

(C.I. 657). 
Brilliant green (C.I. 662) and thloflavlne 

(C.I. 815), FMA. 
Brilliant green (C.I. 662) and thloflavlne 

(C.I. 815), PTA. 

Malachite green (C.I. 657), PMA 

Malachite green (C.I. 657), PTA 



Malachite green (C.I. 657) and thloflavlne 

(C.I. 815), PTA. 
Peacock blue GG and thloflavlne (C.I. 815), PMA- 

Permanent green 

Phthalocyanine green, Pr. 483- 



Phthalooyanlne green (Pr. 483), resinated 

•Pigment green B, Pr. 149 

All other 

•Maroon toners: 

•B.O.N. Maroon (Llthol maroon) (Tobias acid and bon) 
Hello Bordeaux (C.I. 84): 

Made from pigments of own manufacture 

Made from purchased pigments 

Indanthrene maroons 



Llthol red 3G, manganese toner- 
•Naphthol AS-D (Pr. 306) 

a-Naphthylamlne maroon, C.I. 82- 
•Toluldine maroon (Naphthol AS-BS and mnpt) 

All other 



•Orange toners: 

•Benzidine orange (deb and pii5>)- 



•Wanisidine orange (Naphthol AS-OL and dianisi- 
dlne). 

•2,4-Dlnltroanlllne orange (dna and bn) 

Hansa orange- 



•o-Nitroanlline orange (ona and bn)- 

Sulfanll orange 

Vulcan fast orange C2U>I 

All other 



472. 

138, 382, 433. 

138, 382, 433, 464. 

356, AAA, Abb, 494. 

223. 

487, 537, 539. 

28, 537. 
466. 

138, 466, 539. 

464. 

340, 46A, 560. 

346, 384, 393, 444, 466, 472, 487, 494, 537, 539. 

29, 237, 393, 472, 487, 537. 
384. 

55, 223, 340, 356, 382, 433, 464. 

55, 223, 340, 343, 382, 464, 539, 560. 

138, 271, 346, 382, 494, 537. 

29, 138, 164, 346, 382, 464, 466, 494. 

382. 

223. 

223. 

55, 83, 340, 356, 382, 433, 436, 464, 466, 472, 538, 

539, 594. 
29, 55, 340, 343, 366, 382, 433, 464, 472, 487, 538, 

539, 560, 594. 

29, 382. 
366. 

82, 382. 
366. 
271. 

223, 366, 487. 
494. 

83, 271, 382, 433, 464, 539. 

29, 55, 223, 340, 343, 382, 464, 472, 494, 539, 560. 
466. 

29, 138, 223, 343, 382, 433, 464, 494, 539, 594. 

29, 55, 223, 340, 343, 346, 382, 433, 436, 464, 466, 

472, 538, 539, 560, 594. 
29, 83, 382, 594. 
29, 55, 223, 343, 382, 433, 464, 472, 538, 539, 560, 

594. 
433. 

539. 

366. 

384, 393, 472, 537. 

29, 537. 

29, 384, 436, 472, 494, 537, 539. 

433. 

28, 29, 343, 444, 472, 487, 494, 537, 539. 

340, 366, 539. 

55. 

487. 

537. 

29, 436, 487, 494, 539. 
539. 

28, 487, 494, 537, 539. 
537. 

29, 55, 223, 346, 466, 487, 494, 537, 539, 560. 
487, 494, 537, 539. 

366, 444, 466, 472, 494, 539. 
29, 487. 

28, 164, 223, 343, 444, 494, 539. 
466. 

384. 

29, 82. 



TABLE ISB.- -Syntheti 



SYNTHETIC ORGANIC CHEMICALS, 195^^ 

rganic chemicals: Toners and lakes for which United States production 
reported, identified by manufacturer , 1954- -Continued 



97 



TONERS OR FULL-STRENGTH COLORS — Continued 

»Red toners: 

Bona arylamine 

Brilliant red N (Red lake R) 

«o-Chloro-p-nltroanillne red (Chlorinated para 
red) (ocpna and bn) . 

p-Chloronltroanillne red 

•Eoslne (Bromo aoid toner) (C.I. 768) 

Fuchslne (C.I. 677), PMA 

Hello fast pink RLA 

Hello red RMTA (Pr. 112) (mtps and bn) 

»Llthol red 2G (C.I. 166) 

»Hthol red R, C.I. 189: 

•Barium toner 



•Calcium toner- 



•Sodium toner 

•All other lithol red R toners 

•Lithol rubine B (C.I. 163) 



Lithosol red CSP 

Naphthoic red C 

Naphthol reds: 

•Naphthol AS (Pr. 302) and pnot 

•Naphthol AS (Pr. 302) and dca 

Naphthol AS (Pr. 302) and oca 

•Naphthol AS-BS (Pr. 305) and pnoa— 

•Naphthol AS-D (Pr. 306) and pnot — 
Naphthol AS-E (Pr. 308) and pnot — 

Naphthol AS-ITR (Pr. 310) 

Naphthol AS-a (Pr. 311) 

Other naphthol reds 

•Papa red, light, C.I. iA 



•Para red, dark 



Permanent carmine FL 

Permanent carmine FR (Pr. 398) 

•Permanent red 2B (Pr. 563) (ooptms and bon)- 



Permanent red FKB 

Permanent red FKR ex 

Permanent red F4RH 

Permanent red TP 

•Pigment rubine 3G (pcams and bon)- 

•Pyrazolone red 

•Red lake C (C-red), C.I. 165: 

Barium toner 



Ilanuf aoturers ' identification numbers 
(aooordlng to list in table 27) 



Sodium toner 

Red lake D (C.I. 214) 

•Rhodamine B (C.I. 749), Ph\- 
•Rhodamlne B (C.I. 749), PTi-.- 



•Rhodamine 6r (Rhodamine Y) (Rhodamine 6GDN) 

(C.I. 752), PMA. 
•Rhodamine 6G (Rhodamine Y) ( Ihodamlne 6GDN) 

(C.I. 752), PTA. 

Sulf anil red 

•Toluldine red, C.I. ^^ -~ — 

Vulcan fast red B (Pr. 47," 

Vulcan fast red BBE 

Violet toners: 

Crystal violet (C.I. 681), PTA 

Ethyl violet (C.I. 682), PMA 

Indanthrene brilliant violet RR (C.I. 1104)- 
•Methyl violet B (C.I. 680), PMA 



•Methyl violet B (C.I. 680), PTA 

•Methyl violet B (C.I. 680), fugitive 

All other 

Yellow toners: 

Auramine (C.I. 655), PTA 

•Benzidine yellow (deb and aaa) 



444. 
366, 487. 

28, 29, 55, 164, 223, 343, 346, 366, 436, 444, 466, 
472, 494, 538, 539, 560. 

494, 537. 

83, 343, 346, 356, 466, 525, 560. 

382. 

384. 

384. 

55, 494, 538, 539. 

29, 55, 83, 223, 271, 343, 346, 436, 444, 466, 472, 
494, 538, 539, 560. 

29, 83, 223, 271, 343, 346, 436, 444, 466, 472, 475, 

494, 538, 539, 560. 
29, 223, 343, 444, 494, 538, 560. 
466, 538. 
28, 55, 83, 223, 343, 346, 382, 464, 472, 487, 494, 

537, 538, 539, 560. 
537. 

466, 487. 

28, 29, 55, 223, 340, 343, 466, 487, 494, 537, 538. 

29, 55, 433, 436, 487, 539. 
433. 

28, 29, 55, 343, 346, 436, 466, 472, 487, 494, 537, 

538, 539. 

55, 343, 346, 382, 466, 487, 494, 539. 

29. 

55, 346, 494. 

28, 55, 487, 537. 

55, 537, 539. 

28, 29, 83, 164, 223, 271, 343, 436, 444, 466, 472, 

475, 487, 494, 538, 539. 
28, 29, 73, 83, 223, 271, 343, 382, 436, 444, 466, 

472, 475, 487, 494, 538, 539, 560. 
384. 
384. 

28, 29, 223, 343, 382, 466, 472, 475, 487, 494, 537, 
538, 539, 560. 

384. 
384. 
384. 
384. 
382, 384, 494, 539. 

29, 472, 487, 494, 537. 

29, 55, 83, 223, 271, 343, 346, 382, 444, 466, 472, 

487, 494, 525, 538, 539, 560. 
343, 466, 560. 
366. 

29, 55, 83, 340, 356, 382, 433, 464, 472, 539. 
29, 55, 223, 271, 340, 343, 346, 382, 433, 436, 464, 

466, 472, 494, 537, 539, 560. 
29, 55, 223, 340, 356, 382, 433, 464, 472, 538, 539. 

29, 55, 340, 343, 346, 382, 433, 436, 464, 472, 494, 

537, 538, 539, 560. 
466. 

28, 29, 55, 73, 164, 223, 271, 343, 436, 444, 466, 
472, 475, 487, 494, 537, 538, 539, 560. 

384. 
384. 
494, X. 

340. 

356, 466. 
537. 

29, 55, 83, 138, 164, 223, 340, 346, 356, 382, 433, 
436, 444, 464, 466, 472, 475, 494, 538, 539, 560, 
594. 

29, 55, 271, 340, 346, 382, 433, 466, 487, 494, 537, 

538, 539, 560. 

29, 55, 83, 223, 356, 382, 433, 444, 466, 472, 538, 

539, 560. 
138. 

433. 

29, 55, 83, 223, 340, 343, 346, 356, 366, 444, 466, 
472, 487, 494, 537, 538, 539, 560. 



98 

TABLE ISB. --Synthetic organi 



UNITED STATES TARIFF COMMISSION 

chemicals: Toners and lakes for which United States producti 
reported, identified by manufacturer , J954- -Continued 



Manufacturers' Identification numbers 
(according to list In table 27) 



TCKERS CH FOLL-STRENGTH COLORS — Continued 

Yellow toners — Continued 
•Benzidine yellow (deb and aaot) 

•Benzidine yellow, other 

Hansa yellows: 
»Hansa yellow G, Pr. 103 (mnpt and aaa) 

Hansa yellow 3G 

Hansa yellow 5G, Pr. 104 (ona and aaa) 

♦Hansa yellow lOG, Pr. 105 (pcona and ocaaa) 

Hansa yellow 13fr ~ 

Hansa yellow 3R, Pr. 280 

Hansa yellow AR —— ■ 

Llthol fast yellow 3GD (Llthosol fast yellow 
3GD). 

Llthol yellow G (Llthosol yellow G) 

Vulcan fast yellow G (Pr. 478) 

Other hansa yellows — 

REDICED OR EXTENDED TONERS 

Black toners, reduced: Basic black 

•Blue toners, reduced: 

Alkali blue, C.I. 704 

Indanthrene blue GCD (C.I. 1113) 

Indanthrene blue RS (C.I. 1106) 

•Methylene blue (C.I. 922) 

Peacock blue R (C.I. 664), PMA 

Peacock blue R (C.I. 664), PTA 

•Phthalocyanine blue B, Pr. 481 

Phthalocyanine blue B (Pr. 481), resinated 

Phthalocyanine blue H 

•Setoglauclne (Rhodullne blue 6G) (Peacock blue G) 
(C.I. 658), PMA. 

•Setoglauclne (Rhodullne blue 6G) (Peacock blue G) 
(C.I. 658), PTA. 
Setoglauclne (Rhodullne blue 6G) (Peacock blue G) 
(C.I. 658), fugitive. 

Victoria blue B (C.I. 729), PMA 

Victoria blue B (C.I. 729), PTA 

Victoria blue B (C.I. 729), fugitive 

Victoria blue R (C.I. 728), PMA 

Victoria blue R (C.I. 728), PTA 

•Victoria pure blue B (Pr. 198), PMA 

•Victoria pure blue B (Pr. 198), PTA 

Victoria pure blue B (Pr. 198), fugitive 

Brown toners, reduced: 

Bismarck brown G (C.I. 331), PMA 

Bismarck brown G (C.I. 331), fugitive 

Bismarck brown R (C.I. 332), PMA 

Bismarck brown R (C.I. 332), fugitive 

Para brown 

•Green toners, reduced: 

Benzidine yellow and iron blue 

•Brilliant green (C.I. 662), PMA 

•Brilliant green (C.I. 662), PTA 

Brilliaiit green (C.I. 662) and aur amine 
(C.I. 655), PMA. 

Brilliant green (C.I. 662) and benzidine yellow 

•Brilliant green (C.I. 662) and thioflavlne 

(C.I. 815), FMA. 
•Brilliant green (C.I. 662) and thioflavlne 
(C.I. 815), PTA. 
Brilliant green (C.I. 662) and thioflavlne 

(C.I. 815), fugitive. 
Brilliant green (C.I. 662) and rhodanine B 
(C.I. 749). 

•Malachite green (C.I. 657), FMA 

•Malachite green (C.I. 657), PTA 

Malachite green (C.I. 657), fugitive 

Malachite green (C.I. 657) and auramine 

(C.I. 655). 
Malachite green (C.I. 657) and setoglauclne 

(C.I. 658). 
Malachite green (C.I. 657) and thioflavlne 

(C.I. 815), FMA. 
Phthalocyanine blue B, Pr. 482, and benzidine 
yellow . 



29, 55, 223, 346, 366, 384, 444, 466, 472, 487, 494, 

537, 538, 539, 560. 
472, 494, 539. 

29, 55, 164, 223, 343, 346, 366, 436, 444, 466, 472, 

475, 487, 494, 537, 538, 539, 560. 
271, 436, 538. 
55, 366, 436, 538, 539. 

29, 55, 271, 366, 436, 487, 494, 538, 539. 
436, 444, 487. 
494. 
538. 
366. 
537. 

384. 
384. 
472, 494. 



340, 382. 



382, 538. 




539. 




28, 537. 




340, 382, 560. 




340, <i33. 




433, 538, 539, 560. 




29, 138, 340, 382, 393, 436, 472, 487, 494, 


537, 538 


539. 




164. 




164. 




340, 356, 382, 433, 464, 539. 




382, 433, 539. 




382, 433. 




340, 382, 433, 464. 




382, 464, 472. 




340, 382. 




539. 




539. 




340, 356, 382, 433, 537, 538, 539. 




29, 382, 538. 




340. 




340. 




433. 




433. 




382. 




29, 382. 




340. 




539. 




55, 340, 382, 433, 537, 539. 




164, 356, 433. 




138, 433. 




340, 346, 382, 537, 539. 




138, 340, 382, 433, 472, 537. 




29, 340, 382, 433, 436, 472. 




382. 




433. 




382, 538. 




29, 433, 464. 




382. 




382, 433. 




433. 




433, 539. 




340, 539. 





SYNTHETIC ORGANIC CHEMICALS, \95U 



99 



TABLE \SB.- -Synthetic organic chemicals: Toners and lakes for which I'nited States product! 
reported, identified hy manufacturer, 1954- -Continued 



Manufacturers' identification numbers 
(according to list in table 27) 



REDUCED OR EXTENDED TONERS— Continued 

•Green toners, reduced — Continued 

Phthalocyanine blue B, Pr. '•82, and zinc yellow 

Phthalooyanine green, Pr. -483 

Phthalocyanine green (Pr. ^^83), resinated 

•Pigment green B, Pr. U9 

Shamroolt green 

All other 

Maroon toners, reduced: 

B.O.N. Maroon (Tobias acid and bon) 

Naphthol AS-OL maroon (Pr. 311) 

a_Naphthylamine maroon, C.I. 82 

All other 

Orange toners, reduced: 

Dlanisidlne orange (Naphthol AS-OL and dlanlsi- 
dine). 

2,'4-Dinitroanillne orange (dna and bn) 

*o-Nitroanlline orange (ona and bn) 

All other 

•Red toners, reduced: 

o-Chloro-p-nitroanillne red (Chlorinated para red) 
(oopna and bn) . 

Eosine (Bromo acid toner) (C.I. 768) 

Fuohsine (Magenta) (C.I. 677), PMA 

Fuchsine (Magenta) (C.I. 677), fugitive 

Llthol red 2G (C.I. 166) 

•Lithol red R, C.I. 189: 

•Lithol rubine B (C.I. 163) 

•Naphthol reds: 

Naphthol AS (Pr. 302) and pnot 

Naphthol AS (Pr. 302) and dca 

•Naphthol AS-BS (Pr. 305) and pnoa 

Naphthol AS-BS and mnpt 

Naphthol AS-D and ona plus mnpt 

Naphthol AS-D and ona 

Naphthol AS-D and mnpt 

Naphthol AS-OL (Pr. 311) and poena 

Other naphthol reds 

Para red, light, C.I. AA 

•Permanent red 2B (Pr. 563) (ocptms and bon) 

Phloxine (C.I. 774) 

Pigment rubine 3G (pcams and bon) 

Pyrazolone red 

•Red lake C (C-red), C.I. 165, barium toner 

•Rhodamine B (C.I. 749), mA 

•Rhodamine B (C.I. 749), PTA 

•Rhodamine B (C.I. 749), fugitive 

Rhodamine B (C.I. 749) and auramlne 

(C.I. 655), PMA. 
Rhodamine B (C.I. 749) and rhodamine 60 

(C.I. 752), PMA. 
Rhodamine B (C.I. 749) and rhodamine 6G 
(C.I. 752), PTA. 

•Rhodamine 6G (Rhodamine Y) (C.I. 752), PMA 

•Rhodamine 6G (Rhodamine Y) (C.I. 752), PTA 

•Toluldine red, C.I. 69 

Vat pink (C.I. 1211) 

All other 

•Violet toners, reduced: 

•Ethyl violet (C.l. 682), PMA 

Ethyl violet (C.I. 682), PTA 

Indanthrene brilliant violet RR (C.I. 1104) 

Indanthrene red violet RH (C.I. 1212) 

•Methyl violet B (C.I. 680), PMA 

Methyl violet B (C.I. 680), PTA 

•Methyl violet B (C.I. 680), fugitive 

Victoria pure blue B (Pr. 198) and ethyl violet 
(C.I. 682). 

Yellow toners, reduced: 

Auramlne (C.I. 655), PMA 

Auramlne (C.I. 655), fugitive 

Benzidine yellow (deb and aaa) 

Benzidine yellow (deb and aaot) — 

Hansa yellows: 

Hansa yellow G, Pr. 103 (imipt and aaa) 

Hansa yellow 5G, Pr. 104 (ona and aaa) 

Hansa yellow lOG, Pr. 105 (poona and ocaaa) 



29. 

82, 340, 382, 436, 472, 537. 

29, 138, 164, 538. 

82, 384, 436, 537. 

436. 

433, 539. 

382, 537. 
82. 
472. 
433. 

537. 

29, 340, 356. 

164, 382, 494, 539. 

82. 

29. 

55, 382, 436, 539. 

464. 

382. 

538. 

29, 138, 164, 343, 356, 382, 436, 472. 

29. 

343. 

29, 55, 382, 433, 472, 537, 539. 



472, 537, 539. 
436. 
472, 494, 537, 538. 



164, 539. 

138, 271, 382, 430, 436, 472, 539. 

55, 138, 164, 343, 382, 436, 472, 494, 537, 538. 

537. 



55, 343, 466, 494. 
356, 382, 433. 
433, 464, 472, 537, 538. 
433, 436. 



29, 346, 382. 



346. 



340, 346, 356, 382, 433, 537, 560. 

82, 366, 382, 436, 472, 537, 539. 

29, 82, 138, 164, 300, 382, 436, 494, 537, 539. 

29, 55, 340, 382, 433. 

138, 343, 382, 433, 538. 



433, 537, 539, 
537. 



346, 356, 382, 433, 436, 537, 538, 539. 

366, 382, 433. 

138, 340, 346, 366, 382, 433. 



433. 

340, 433. 

366, 494, 537. 

466, 487, 494, 537, 539. 

356, 472, 494, 537, 539. 

436. 

346, 537. 



100 

TABLE 15B. -Synthetic 



UNITED STATES TARIFF COMMISSION 



c chemicals: Toners and lakes for which United States production or sales were 
reported, identified by manufacturer, J 954- -Continued 



REDUCED OR EXTENDED TONERS— Continued 

Yellow toners, reduced — Continued 
Hansa yellows — Continued 

Lithol fast yellow 3W 

Other hansa yellows 

Safranlne (C.I. 8^1) and auramlne (C.I. 655) 

LAKES OR LAKED COLORS 

»Blaok lakes: 

Logwood hlaek (C.I. 1253) 

»Blue lakes: 

Brilliant blue FCF 

•Brilliant wool blue FFR (Pr. 40) 

Methylene blue (C.I. 922) 

"Peacock blue, fugitive (Patent blue) (C.I. 671) — 



Permanent blue- 



Phthalooyanine blue, sulfonated 

Victoria blue B (C.I. 729) 

Victoria pure blue B (Pr. 198) 

All other 

Brown lakes 

»Green lakes: 

Acid green B (C.I. 669) 

Brilliant green (C.I. 662) 

Malachite green (C.I. 657) and fast light yellow 

(C.I. 636). 
Naphthol yellow S (C.I. 10) and brilliant green 

(C.I. 662). 
Naphthol yellow S (C.I. 10) and peacock blue 

(C.I. 671). 
Pigment green B, Pr. 149 

All other 

"Maroon lakes: 

Alizarin maroon (C.I. 1041) 

Amaranth (C.I. 184) 

Azo Bordeaux (C.I. 



Manufacturers' identification numbers 
(according to list in table 27) 



406)- 



Helio fast rubine 4BL (Pr. 

Hypernio (C.I. 1243) 

•Orange lakes: 

Acid orange R (C.I. 161) 

Lithosol orange OTP 

Naphthol AS-OL (Pr. 311) 

"Persian orange (Acid orange Y) (Orange II) 
(C.I. 151). 

"Red lakes: 

•Alizarin red B (C.I. 1027) 

Carmine (C.I. 1239) 

Crooein scarlet 3BX (Cochineal lake) (C.I. 183)- 

"Helio fast nibine 4BL (Pr. 406) 

Lithol rubine B (C.I. 163) 

Permanent red 

Pigment soarlet- 



"Pigment scarlet 3B (C.I. 216)- 

Polar red (C.I. 430) 

Rhodamlne B (C.I. 749) 

Rhodamine 6G (C.I. 752) 

Rubine FF 

•Scarlet 2R (C.I. 79) 



537. 

82. 

433. 



29, 82. 

29, 300, 352, 356. 

366. 

29. 

82, 300, 352. 

436. 

29, 55, 83, 223, 271, 300, 340, 346, 382, 433, 436, 

464, 466, 472, 525, 539, 560, 594. 
464. 

55, 352, 366, 393. 
433, 464. 
436. 

82, 366, 382. 
82, 300, 352. 

55, 352, 382, 464. 

464. 

73, 436, 539. 

73. 

300, 436. 

29. 



Turkey red, medium 

"Violet lakes: 

•Acid violet (C.I. 698) 

Alizarin purple 

"Methyl violet 

Purple lake R 

All other 



494. 








343. 








487. 








29, 382, 494. 








164, 382, 436, 466, 


475, 


537, 


539 


494. 








539. 








82, 300, 352, 436. 









271, 433, 464, 539. 

537. 

271. 

29, 55, 83, 300, 340, 346, 352, 464, 466, 472, 525, 

539, 560. 
73. 

29, 55, 138, 340, 366, 472, 475, 494, 537, 539. 

382. 

29, 155. 

29. 

28, 164, 265, 346, 382, 537, 538, 539. 
494. 

464. 
73, 164. 

29, 55, 164, 340, 366, 382, 472, 537, 538. 
433. 

346. 
539. 
265. 

28, 29, 55, 138, 300, 352, 382, 436, 466, 472, 475, 
494, 537, 539. 

73. 

29, 73, 164, 271, 352, 464. 

300, 382, 433, 538. 

366. 

300, 352, 464, 466, 539. 

366, 436. 

73, 538. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



101 



TABLE ISB. --Symthetic organic chemicals: Toners and lakes for which United States production or sales were 
reported, identified by manufacturer, J954--Continued 



Manufacturers' identification numbers 
(according to list in table 27) 



LAKES OR LAKED COLORS— Continued 

Yellow lakes: 

•Fast light yellow (C.I. 636) 

Naphthol yellow S (C.I. 10) 

CJiercitron (Flavine) (C.I. 1251) 

•Quinoline yellow (C.I. 801) 

»Tartrazlne (C.I. 640) 

Thioflavlne 

All other 



29, J-iO, 3A6, A6A, V12, 538. 

539. 

29, 83, 346, 464, 525, 539. 

29, 55, 83, 271, 340, 346, 436, 464, 466, 487, 539, 

560. 
539. 
539. 



Note. — Intermediates used in the manufacture of certain colors are abbreviated as follows: 



aaot 

bn 

bon 

dca 

deb 

dna 

□mpt 

mtps 

ocaaa 

oca 

ocpna 

ocptms 

ona 

pcams 

pcona 

pnoa 

pnot 



acetoaoetanilide 

acetoaoet-ortho-toluidide 

beta-naphthol 

beta-oxynaphthoic acid 

dichloroanlline 

dichlorobenzidlne 

dinitroanillce 

meta-nltro-para-toluidlne 

meta-toluidine-para-sulfonic acid 

ortho-ohloroacetoacetanllide 

ortho-ohloroanlline 

ortho-chloro-para-nitro aniline 

ortho-ohloro-para-toluidine-meta-sulfonic acid 

ortho-nitroaniline 

para-ohloroaniline-meta-sulfonio acid 

para-chloro -ortho-nitroaniline 

para-nitro -ortho -anisidine 

para-nitro-ortho-toluidine 

phenylmethylpyrazolone 



102 



UNITED STATES TARIFF COMMISSION 

Medicinals 



TABLE ITB.-Syntheti 



rganic chemicali 
reported. 



: Medicinals for which United States producti 
identified by manufacturer , 1954 



or sales were 



[Modlcinals for which aaparate statistics are given In table 17A are marked below with an asterisk («); 
medicinals not so marked do not appear In table 17A because the reported data are accepted in confidence 
and may not be published. Manufacturers' Identification numbers shown below are taken from table 27. An X 
signifies that the manufacturer did not consent to the publication of hla Identification number with the 
designated product] 



Mamif aeturers ' identification numbers 
(according to list in table 27) 



MEDiciNAi^, craic 

Btnztnoid 

3-Aeetanldo-2,4,6-trllodobenzolc acid and sodium 

salt. 
p-Acetamlnophenol 
Acetanl llde 
Acetarsone (N-Acetyl-4-hydroxy-m-arsanlllc acid) 

(Stovaraol) . 
4-Acetary-m-arsanillc acid (Nemural) 
Acetylglycol sallcylate- 



Acetylsallcylchollne hydrochloride 
»Aoetylsallcyllc acid (Aspirin) 
Acetyl-o-aallcyllc acid, dlalumlnum salt- 
Adrenaline (Epinephrine) 

Amino acids: 

3,5-Dliodotyrosine 

d-Phenylalanlne- 



dl-Phenylalanine- 
1-Phenylalanlne— 

d-Tyros Ine 

dl-Tyrosine 

1-Tyroslne- 



2-Amlno-4-arsenosophenol (Mapharsen) hydrochlorlde- 
m-Amlnobenzolc acid derivatives: 2-Isobutylamlno- 

ethyl m-amlnobenzoate (tJnacalne) . 
o-Amlnobenzolc (Anthranlllc) acid, cadmium salt 
*p-Amlnobenzoic acid 
•pWlmlnobenzoic acid derivatives; 
»Benzocaine (Ethyl p-amlnobenzoate)- 



Butacalne ( 3-Dl-n-butylamlnopropyl p-«mlno- 

benzoate) base. 
Butacalne sulfate- 



Butesln (n-Butyl p— amlnobenzoate) 

Butesln plorate (Di(n-butyl p-«mlnobenzoate)- 

trlnltrophenol) . 
2^1ethylamlnoethyl '»-amlno-2-propaxybonzoate 

(novocain) hydrochloride. 
Isobutyl p-emlnobenzoate (Cycloform)- 



2-l8obutylamlnoethyl p-aminobenzoate (Monooalne)- 
Monocaine formate- 



•Prooalne base ( 2-Dlethylamlnoethyl p-omino- 

benzoate) (Novacalne base) . 
•Procaine hydrochloride and butyrate— — — 
Propyl p-aminobenzoate- 



Tetracalne (2-Dlmethylamlnoethyl p-butylamlno- 

benzoate) base. 
Tetracaine bydrochlorld o 
»p-Aminobenzolc acid salts: 
Calcium p -amlnobenzoat e 
Potassium p-aminobenzoate 
•Sodium p -amlnobenzoate 
pTAminohippttrlc acid 

<i-^Amlno-2-methyl-l-naphthol hydrochloride 
(Synlmmln) . 

»<4-AmlnoBallcylio acid 

"i-Amlnoaallcyllc acid salts: 
Calcium *<— aminosalicylate 
Potassium A-amlnosallcylat o 
Sodium ^-aminosalicylate 
sec-Amyltricresol 
Anlsoln (4,4^-Dimethoxybenzoln) 

1,8,9-Anthratrlol (Anthralin) 

Antihistamines : 

2-(Benzhydryloxy)-*J,N-dimethylethylamine hydro- 
chloride. 
N , N-Dimethyl-2-(a-phenyl-o-toloxy) ethylamlne 
dlhydrogen citrate, 
Atrolact nmi de 
Benzaldehyde- 



Benzestrol (2 .^-Di(p-hydroxyphenyl)-3-ethyIhexane)- 
Benzolo acid 

Benzoic acid salts: Llthlxim benzoate 
N-Benzyl-p-chloropropionamlde (Hiblcon) 
p-Benzylphenyl carbamate (Dlphanan) 



501. 
208. 
247, 

2-17. 

Ul, 

501. 

^-^^ 

420, 

168, 

313, 
247, 
335. 
397. 

158. 
335. 
158, 
180. 
150. 

327. 
40, 

141, 
420. 

219, 

141, 
420. 



305, 
126, 
126, 
403. 
180. 



327. 
569. 
183. 
208. 
293. 
466. 

24a, 



420. 

208. 

163, 177, 208, 335. 

180, 232. 247, 355. 

413. 
397. 



126, 279, 305, 306, 355, 403, 447. 
150, 240, 279, 420, 447. 



420. 
420. 



305, 306, 420. 

150, 247, 305, 306, 309, 420. 

247. 

413. 

447. 

305, 306, 447. 

279, 305, 306, 403, 447, 550. 

180, 447, 466. 

447, 466. 

180, 447, 466. 
274. 



SYNTHETIC ORGANIC CHEMICALS, \95h 



103 



TABLE \7B. --Synthetic organic chemicais: Medicinals for which United States production 
reported, identified by manufacturer, i9J4- -Continued 



Manuf aoturers ' identification numbers 
(according to list in table 27) 



MEUICINAIS, CrCLIC— Continued 



id- -Continued 



Benzyl succinate 

Bls(m-ajninob©nzoyl-Hn-amino-p-Knethylbenzoyl-l- 
naphthylaiiilno-4,5,8-tri8ulfcinio acid) carbamide 
(Naphuride) . 

•Bismuth subgallate 

•Bismuth subsalicylate 

Bismuth tetrabromopyrocateehol 

a-Bromolsovaleryl-p-phenetidine 

Calcium benzy Iphthalat 9 

Calcium oreosotate- 



Carbarsone Cp-CarbamldobenzeneaTsonlc acid) - 
Carbobenzoxy ohloride- 



Chloramine T (Sodium p-toluenesulfonchloramlde) 

Chloromercuri-^nitro-o-eresol 

Chlorothymol 

Chlorotris(p-methcocyphenyl) ethylene (Tri-p- 

anlsylohloroethylene) . 
m-Cresyl acetate (Cresatin) 

p-(Cyolohexylaxy) benzoic acid 

Desoxyanisoln 
3,5^iac6tamido-2,4,6-triiodobenzolc acid, sodium 

salt (Hypaque) . 
p,p'-Diaminodiphenylsulfone-N,N'-dl( dextrose 

sodium sulfonate) . 
2,5-Diaminotolu9ne sulfat e 
Dibenzyl sulfoxide- 



a-Diethylamlno-2 , 6-ac etoxylidine 

3-Diethylamlno 2,2-dimethylpropyl hydratropate , 

phosphate salt. 
p-Diethylaminoethyl diphenylthloacetate hydro- 
chloride. 
2-Diethylamlnoethyl p-ethoxybenzoate (Intracaine) 

hydrochloride . 
N-Diethylamlnoethyl isoamyl phenyl glycinate 

dlhydrochloride . 

p,p'-(l,2-Dlethylethylene)diph9nol (Hexestrol) 

p,p'-(l,2-Diethylethylene)diphenol (Hexestrol) 

diproplonate. 
a ,a ' -Diethy 1-4,4' -atilbenediol (Diethyl- 

stilbestrol) . 

a,a'-Diethyl-4,4'-stilbenedlol diproplonate 

3,4-Dlhydroxy-2-methylaininoacetophenone hydro- 
chloride. 
3,'4-Dihydroxynorephedrine (3,4-Dihydroxyphenyl- 

prppanolamine) hydrochloride. 
p-(3,5-Diiodo-^-hydroxyphenyl) -a-hydratropic acid — 
6^imethylamino-4, 4-diphenyl-3-heptanone 

hydrochloride (Dolophine) (Methadone) . 

Y-Dim6thylamino-a,ci -diphenylvaleramide 

P-Dlmethylaminoethyl(l-hydroxycyclopentyl)phenyl 

acetate (Cyclopentolate) hydrochloride. 
Dlmethyl-3-hydroxyphenylammonium chloride. 
N,a-Dimethylphenethylamine (Desoxyephedrine) base — 
P-Dimethylphenethylamine (f-Phenyl propyl 

methylamine) . 

»d-N,a-Dimethylphenethylamine hydrochloride 

N,a-Dimethylphenethylamine hydrochloride 
N,N'-Di(3-nltrobenzene3ulfonyl)ethylenediamin o 
Dlphenylaeetic acid 

Diphenylacetyldiethylami noethanol hydrochloride 

p-(Di-N-^)ropylsulfamyl) benzoic acid (Benemld) 

Dithiosalicyllc acid 
»Dyes, medicinal: 

Acrif lavine ( 3, 6-Diamino-lO-methylacridine 
chloride) . 

2,4-Diamlno— i' -ethoxyazobenzene hydrochloride 
(Serenium) . 

Gentian violet- 



Merbromin (Dibromohydroxymereurifluorescein, 

sodium salt) . 
Methylene blu o 
Methyl violet- 



Proflavine (3,6-Diaminoacridine sulfate)- 

Scarlet red (Phenol red) 

Tetraiodqphenolphthalein 
Trypan blue- 



305. 








2A1. 








201, 


327, 


528, 


540, 550 


177, 


327, 


540, 


550. 


413. 








4^7. 








501. 








327. 








126, 


274, 


413. 




413. 








208. 








420. 








540, 


561. 






194. 








447, 


540. 






274. 








197. 








247. 








180. 








513. 








501. 








78. 








463. 








563. 








438. 








484. 








520. 








520. 








197, 


274, 


447. 




197, 


520. 






247. 








247. 








266, 


414. 






274, 


327, 


540. 




512. 








183. 








463. 








145, 


484. 






194. 








145, 


420, 


447, 


484. 


145, 


447, 


484. 




X. 








305. 








141, 


421. 






208, 


413, 


540. 




274. 









l-Ephedrine (a -(1-Methylamlnoethyl) benzyl aloohol)- 
Ephedrine, racemic 



403, 420. 



403. 
18. 

403, 466. 

403. 

403. 

403, 501. 

403. 

403. 

540. 

540. 



104 



UNITED STATES TARIFF COMMISSION 



TABLE \71i. -Synthetic organic chemicals: Medicinals for which United States produ 
reported, identified hy manufacturer , 19 54- -Continued 



MEDICIKALS, CYCLIC — Continued 
Benzene id- -Continued 



p-Ethoxybenzolo acid 
4-Ethoxy-3-methoxyphenylacetlo acld- 
N-Ethyl-3, 3' -dlphenyldlpropylamlne- 



N-Ethyl-3,3'-diphenyldlprapylamlne citrate 

N-Ethyl-3 , 3 ' -dlphenyldlpropylamlne hydrochlaride- 
Ethylene glycol sallcylate- 



N-Ethylephedrlna hydrochloride 

Ethyl (lodoph6nyl)hendecanoate (Pajitopaque)- 

a-Ethyl-i-phenyl-glutanlmlde (Dorlden) 

Ethyl vanlllate 

Gallic acld- 



Gontlsic acid ( 2 , 5-Dlhydxoxyhenzolc acid) and 
derivatives: 
Gentlslo acid- 



Gentlslc acid, sodium salt- 



N-2-Hydroryethylgentlsamlde (Centisic acid 
amide of ethanolamlne) . 

Guaiacol, liquid and crystalline 

Hexylresorcinol- 



sec-Hexylresorclnol (Dlhexylin) — 
Hydroqulnone n-amyl ether (Amol)- 
p-Hydroxyacetanlllde- 



m-Hydroxybenzaldehyde 

p-Hydroxybenzolc acid esters: 
Benzyl p-hydroxybenzoate 



n-Butyl p-hydroxybenzoate (Butoben)- 
Ethyl p-hydroxybenzoate- 



■nMethyl p-hydroxybenzoate 

Propyl p-hydroxybenzoate 

p-Hydroxy-p-(2,5-dlmethoxyphenyl)i3ciprqpylamine 

hydrochloride (Methoxamlne) . 
o-[3-(Hydroxymerourio)-2-(2-niethoxyethoxy)propyl 

carbamoyl] -phenoxyaoetic acid (Merethoxyllne) . 
Hydroxymerouri-4-nitro-o-creaol anhydride 

(Metaphen) . 
4-Hydroxy-3-nitrobenzenear3onlc acid 
P_(4_Hydroxyphenyl)-a-phenylproplonlc acid (P-(A- 

Hydroxyphenyllhydratroplc acid). 
p-Hydroxyproplophenone (Hydrophen) 
o-Iodobenzoic acid — 



a-Clsopropylaininomethyl)protocatechuyl alcohol 

(Aleudrine) . 

Mandelic acid (Phenylglycollc acid) 

Mandellc acid derivatives: 

Calcium mandfllate- 



N-2-Hydroxyethylmandelamlde- 



o-Methoxy-N ,a -dlmethylphenethylamine ( l-( o- 
Methoxyphenyl)-2-Hiiethylamlnc!prqpane) hydro- 
chloride. 
»3-( o-Methoxyphenoxy) -1, 2-propanedlol ( Glyceryl 
guaiacyl ether) . 

Methylenebls[ octyloresol] — — 

a -Methyl homoveratrylamine 
N-(a -+!ethyIhomoveratryl) -3-methoxy-4— ethoxy- 
phenylacetamide (Amide 678) . 
«x-Methylphenethylamine (Amphetamine) (Benzedrine) 
base, 
o^ethylphenethylamlne salts: 

«a-MethylphenethylaminB hydrochloride 

<<a-Methylphenetl^lamine phosphate 

«a-Methylphenethylamine sulfate- 



»d-(x-Methylphenethylamlne hydrochloride and 
phosphate. 

»d-a-Methylphenathylamlne sulfate 

2-Naphthol (P-Naphthol) 

2-Naphthyl benzoate 
Neostigmine bromide- 



Neostigmine methyl sulfat e 

Neosynephrlne (Phenylephrine) hydrochlorlde- 

p-Nitrobenzenearsonic acld- 



'i-(2-Nltropropenyl)veratrole (l-(3,<i-Dl 

methoxyphenyl)-2-nltropropene-l) . 
Norephedrine base 



Norephedrine (Propadrine) hydrochloride — 

Octyleresol 

Octylresorclnol' 



Orthoform (Methyl m-amlno-p-hydrorybenzoate) - 



Manufacturers' identification numbers 
(according to list in table 27) 



27-^. 






141, 


197. 




Ul, 


197. 




197. 






Ul. 






197. 






513. 






421. 






438. 






327. 






141. 






141, 


447. 




141. 






208, 


569. 




40, 


484, 


540. 


180. 






540. 






145, 


447. 




403. 






141, 


569. 




141, 


569. 




141, 


569. 




126, 


141, 


447, 569 


141, 


447, 


569. 


24S. 






274. 






168, 


420. 




447, 


X. 




141. 






145. 






413, 


447. 




197, 


274, 


279. 


327. 






327. 






274. 






145. 







141, 413, 420, 447. 

501. 
274, 
274. 

145, 178, 236, 240, 484. 



145, 


484. 






145, 


484. 






145, 
145. 


236, 


447, 


484. 


145, 


236, 


447, 


484. 


501. 








310, 


447, 


540. 




413, 


453, 


463, 


4S4. 


413, 


453, 


463, 


4^4. 


168, 


247, 


279, 


447, 501 


274. 








141. 








141, 


413. 






501. 








501. 








247. 









TABLE 17B. - -Syn the ti 



SYNTHETIC ORGANIC CHEMICALS, 1954 

organic chemicals: Medicinals for which United States producti 
reported, identi fied by manufacturer , J954- -Continued 



105 



1 or sales were 



MEDICINALS, OfCLIC— Continued 
Benzeno id- -Continued 

Paredrlne (p-Hydroxy-a-methylphenethylamlne) 
hydrobr omlde . 

Phenaoalne [(Dl-p-ethoxyphenyl)acetamldlne] hydro- 
chloride. 

Phenaoetln (Aeetophenetldln) 

Phenolphthaleln- 



Phenolsulfonlc acid salts: 
Aluminum phenolsulfonate- 
Ammonlum phenolsulfonate- 
Calclum phenolsulfonate — 

Copper phenolsulfonate 

Sodium phenolsulfonate 

Zinc phenolsulfonate- 



2-Phenyl-l,3-lndandlone (Danllone) 

Phenyl mercuric derivatives: 

o-Chloromercurlphenol ( o-Hydroxyphenylmercurlc 
chloride) . 

Phenylmercurlc acetate- 



Phenylmercurlc benzoate — 

Phenylmercurlc borate 

Phenylmercurlc chloride— 
Phenylmercurlc hydroxlde- 
Phenylmercurlo nltrate- 



4-Phenylsemloarbazlde hydrochlorlde- 
P-Phenyl-P-sulfanllyl-proplophenone- 
Phthalazone 



Procaine amide hydrochlorlde- 

Propsnyl methyl guaethol 

Resorclnol monoacetate 

»Salioylamide ^— — 

♦Salicylic acid- 



»Salicyllo acid salts: 
Ammonium salicylate — 
Bismuth salicylate— 

Calcium salicylate 

Lithium salicylate 

Magnesium aalicylate- 
Manganeae sallcylate- 
Mercurlc salicylate — 
Potassium sallcylate- 

*Sodium salicylate 

Strontium salicylate- 



Salicyl salicylate (Salysal)- 

Salol (Phenyl salicylate) 

Silver plcrate- 



Sodium antimony III bi3catechol-2,4-dlsulfonate 

(Fouadln). 
Sodium benzyl phthalate 
Sodium benzyl succinate 



Sodium ethylmercurithiosalicylate 

Sodium o-iodohippurate dlhydrate (Hlppuran)- 
Stilbamlne glucoslde (Neostam) 
•Sulfa drugs: 

N^-Aoetylbj-V-dlmethyl-S-lBoxazolyl) ^ '- 

sulfanilamide. 
Benzoylsulfanllamide- 



p-Benzylamlnobenzenesulfonamide 

N^-(3,'i-Dimethyl-5-isoxazolyl)sulfanilamlde- 

2-Methyl-l,3,4,5-sulfanilamidothiadiazcle 

Neoprontosll "5" 

Nisulfazole— — 



p-(p-Nitrophenylsulfcmamido)aoetanlllde 

(N*-Acetyl-N '-(4-nitrophenyl) sulfanilamide) . 

N*-Phthalylsulfaacetamide 

Phthalylsulfathiazole- 



Prontosil soluble (Disodium 'i-sulfaminophenyl— 2- 
azo-7-acetylamlno-l-hydroxynaphthalene-3,6- 
disulf onate) . 

Sulfadiazine^ — — — — — — — — ^— _____ 

Sulfadiazine, sodium salt 

Sulfaguanidin o 

Sulfallantoin 



Sulfamerazine (2-Sulfanilamlde— i-methyl- 

pyrimldine) . 
Sulfamerazine, sodium aalt- 



Sulfamethazine (Sulfadlmethyldlazlne)- 
Sulfamethazine, sodium salt 



Sulfanilamide (p-Aminobenzenesulfonamlde)- 



Manuf acturers ' identification numbers 
(according to list in table 27) 



219, 


247, 


279. 




Ul 


208 


335. 




208. 








327. 








587, 


X. 






327. 








327. 








327, 


587, 


X. 




327. 








183, 


197, 


279. 




232, 


248, 


309, 


480. 


233. 








233. 


309. 






233, 


309. 






233, 


309. 






233. 








233, 


309. 






126. 








463. 








403. 








438. 








141. 








178, 


447, 


460, 


501, 513. 


208, 


447, 


550, 


557, 569, 587 


208, 


223, 


335, 


569. 


126, 


327, 


447, 


550. 


327. 








327, 


335, 


447, 


569. 


293. 








327. 








569. 








327. 








327, 


447, 


550. 




208, 


327, 


335, 


569. 


335, 


569. 






447. 








335. 








126, 


413, 


471. 




247. 








501. 








305. 








168, 


274, 


453, 


484, 520. 


327. 








248. 








463. 








466. 








247. 








463. 








466. 








247. 








247. 








X. 








126, 


305, 


414, 


466. 


208, 


266. 






247. 








466. 








466. 








466. 








364. 








466. 








466. 








466, 


559. 






466. 








540. 









106 



UNITED STATES TARIFF COMMISSION 



TABLE 17B. --Synthetic organic chemicals: Medicinals for which United States product! 
reported, identified by manufacturer , 7954--Continued 



or sales were 



MEDICINALS, CYCLIC — Continued 



»Sulfa drugs — Continued 

N-Sulfanllylacetamlde (Sulfaacetamlde)- 

N-Sulfanilylaoetamlde, sodium salt 

Sulfapyrldlre- 



Sulfapyridine, sodium salt ■ 

Sulfaquinoxaline __^_— — — ^— 

Sulfasuxidine (Suocinylsulfathiazole) 

Sulf athalldine ( 4' -( 2-Thiazolylsulf amyl) - 

phthalanlllo acid). 
Sulfathiazole- 



Sulfathlazole, sodium salt- 



[Sulfonyll)ls(p-phenylenelmlno)] dimethanesiilflnate, 
dlsodium salt (Dlasone). 

Tannin albuminate (Tannalbln) 

Tannin yeast (Eldoform)-— 

TMophenol — — 

Thiosallcylic acid- — 

Thymol- 



Thymol lodJ'^i 

»3-o-Toloxy-l,2-^)rqpanedlol (o-Cresyl a-glyceryl 
ether) . 
3-o-Toloxy-l,2-propanediol, l-carbamate 
hemlhydrate. 
»Vltamlns : 

K (Menadione) (2-Methyl-l,4-naphthoqulnone) 

K (Menadione) , sodium bisulfite 

K ( 2-Methyl-l , 4-naphthoquinone-diphosphorio 
ester, tetrasodlum salt) . 

Ki (2-Methyl-3-jphytyl-l,'i-napiithoqulnone) 

Zinc aulfanllate (Nlzin) 



Manufacturers' identification numbers 
(according to list in table 27) 



5-Aoetamido-l, 3, '*-thlodiazole-2 -sulfonamide- 
Adenine base- 



Adenine hydrochloride- 
Adenine sulfate 
Adenoslne- 



Adenoslnediphosphoric acid 

Adenosinedlphosphoric acid, barium salt- 

Adeno6ine-5-phosphoric acid ■ — 

Adenosinetriphosphoric acid 

Adenosinetriphosphorlo acid, salt 

Adenylic aold- 



Adenyllc acid, isomers A and B 

Alkaloids and related products: 

Areooline (Methyl 1,2,5,6-tetrahydromethyl- 
nicotinate) hydrobroralde. 

Atropine- 



Atropine amlneoxlda hydrochloride- 
Atropine methyl nitrate 

Berberine hydrochloride 

Brucine ■ — 

Clnchonidine 

Colchiclne- 



Digitalis gluoosides: 

Digifolln 

Dlgitalin 

Digitoxin 

Digoxin— — — — — — — — 

Ergotamine tartrate - 

Eserine (Physostigmlne) 

Eserlne salicylate 

Ethylmorphine hydrochlorlde- 

Eucatropine hydrochloride — 

Homatropine- 



Homatropine hydrobromlde — 
Homatropine methyl bromide- 
Hydrastine- 



Hydrastine hydrochlorlde- 
Hyoscine (Scopolamine) - 



Hyosclne (Soopolamlnej amlneoxlde hydrobroralde- 

Hyosoine methyl bromide 

Hyosoyamlne- 



Hyoscynmlne sulfate 

3-^ethoxy-N-methylmorphlnan hydrobromide- 
Nicotine salicylate 

Pilocarpine salts 

Quinine 



126, 208, 305, 414. 

126, 305, 414. 

466, 540. 

466, 540. 

540. 

208, 266, 540. 

540. 

274, 466, 540. 
247, 466, 540. 
420. 

126, 447, 501. 

247. 

453. 

274, 453. 

395, 561. 

540. 

141, 145, 310, 438, 4^7, 484. 

^.38. 



178, 279, 


420, 447, 484. 


420, 520. 




463. 




540. 




248. 




466. 




397. 




397. 




397, 513. 




397. 




X. 




397. 




397, X. 




397. 




397, X. 




397. 




397. 




388. 




206, 247, 


557. 


206, 447, 


526. 


557. 




206, 355, 


420, 557, 


206, 540. 




540. 




206, 420, 


557. 


421. 




206. 




492. 




248. 




355, 447. 




206. 




206, 557. 




327. 




219, 447. 




197, 206, 


540, 


197, 206. 




197, 442, 


447, 484, 540 


206, 557. 




557. 




206. 




206, 447, 


526. 


197. 




206, 355. 




206, 355. 




463. 




501. 




206. 




540. 





TAJI,E 17B. --Synthetic 



SYNTHETIC ORGANIC CHEMICALS, 1954 

rganic chemicals: Medicinals for which United States product! 
reported, identified hy manufacturer , I954--Cofitinued 



107 



or sales were 



Manufacturers' Identification numbers 
(according to list In table 27) 



MEDICINALS, CYCLIC — Continued 

Alicyclic and He ttrocyc 1 ii;--Contlnued 

Alkaloids and related products— Continued 
Reserpine- 



Spai-tein lodomethylate- 

Strychnine 

Totaqulne 

Tubocurarln o 



TubocurarlnG dimethyl ether chlorlde- 

Veratrine— ■ 

Yohlmbine- 



Allantoln (5-Ureldohydantoin) 

6-Allyl-6,7-dlhydro-5H-dlbenz[o,e]-azeplne, 

phosphate salt. 
*Amino acids: 

dl-Acetyltryptophane 

Histamine, base- 



Histamlne dihydrochloride- 
Histamlns phosphate 
dl-Tryptophane- 



9-Amlnoacridine base and hydrochloride — 

2Wimino-5-nltrothiazole (Enheptin) 

Aminopyrine bicBji^)horat o 
"Antibiotics for human or veterinary use: 

Actidlone 

•Bacitracin- 



Chloroamphenlcol (Chloromycetin) 
Chlortetraoyollne (Aureomyoin) hydroohloride- 
»Dlhydro3treptomycin 
Erythromyci n ' ' 
Fumagillin- 



»Neomycin and salts 

Ctitytetraoycllne (Terramycln)- 
«Penielllin salts: 

Chloroprooalne penicillin "0"- 



Dipenloillin G dlbenzylethylenediamine- 
Penicillin Bl uTi-t mim 

Penicillin calcium 

Penicillin l-ephenam1n o 



♦Penicillin potassium- 
Penicillin "0" potassium (Allylmercaptomethyl 
derivative) . 
"Penicillin proc ain e 



Penicillin sodium 

P olymixin 

•Streptomycin 

Tetracycline (Achromycin) - 
Vlol^ycin- 



»Antibiotlcs for animal feed supplements: 
Bacltracin- 



Chlartetracycline (Aureomyoin) hydrochloride 

Oxytetracycllne (Terramycin) 

Penicillin salts: 



Dlpeniclllin G dibenzylethylenediamine- 

Penicillln procaine—^ 

•Antihistamines : 

3-(2Wlminoethyl)pyTazole dlhydrochloride 
(Hlstalogue) . 

l-Amino-l^henyl-3-piperidlnapropane- 



2-(Benzhydryloxy) -N,N-dlmethylethylaiidne 
8-chlorctheophyllinate. 

2- [Benzyl( 2-dimethylamlnoethyl) amino] pyridine 
(N,N-Dlmethyl-N'-benzyl-N'-pyridylethylene- 
diamine) . 

l-(<V-Chlorobenzhydryl)-4-m6thylpiperazine hydro- 
chloride. 

2-[p-Chlarobenzyl(2-dimethylaminoethoiy) ] - 
pyridine maleate. 

2-[ l-(p-Chlorophenyl) -3-dim6thylaminppropyl] - 
pyridine maleate ( Chlorophenylpyrldamine 



l-(p-Chlorophenyl) -2-phenyl-4-^yTTolidyl-2- 

butanol. 
l-(p-Chlorophenyl) -2-phenyl-4-pyrrolldyl-l- 

butene diphosphate and hydrochloride. 
l-(p-Chlorophenyl)-2-phenyl— i-pyrrolidyl-l- 

butene hydrobrcardde. 



180, 421. 










355. 










540, 550, 


557. 








540, 557. 










438. 










438. 










206, 438, 


557. 








206, 557. 










364, 501, 










463. 










247. 










532. 










463. 










532. 










247, 335, 










141. 










466. 










501, 










232, 










290, 528, 


557, 








180. 










466, 










274, 420, 


438, 


466, 


512, 528, 


540. 


232, 274, 


420, 








420, 










232, 466, 


528, 


540, 


557, 




528, 










232, 










471, 512, 


528. 








528, 










232. 










290, 










140, 232, 


274, 


290, 


420, 438, 


466, 471, 512, 528 


540, 










232, 











140, 232, 274, 290, 420, 438, 466, 471, 512, 528, 

540. 
232, 290, 438, 466, 512, 523, 540, 
528, 

274, 420, 438, 466, 512, 528, 540, 
466, 512, 528. 
528. 

290, 485, 557, 

466. 

528. 

528, 557. 

140, 208, 274, 420, 512, 528, 540. 

274. 

274, 
46, 

421. 

420, 
414, 
41A, 

274. 
274, 
274, 



108 



UNITED STATES TARIFF COMMISSION 



TABLE 17H. -Synthetic organic chemicals: Medicinals for which United States producti 
reported, identified by manufacturer, 1954- -Continued 



Manufacturers' identification numbers 
(according to list in table 27) 



MEDICINALS, CYaiC— Continued 



All 



nd He 



eye lic--Contlnued 



•Antihistamines — Continued 

2-[ ( 5-Chloro-2-thenyl) ( 2-dimethylajiilnoethyl ) - 
ajnlno]pyridlne citrate (N,N-Dimethyl-N'2- 
pyrldyl-}4'2-(5-chlorothenyl)ethylenediainine 
citrate). 

2-[a-(2^1methylamlnoethoxy)-a-methylbenzyl] - 
pyridine succinate (2-(Methyl-2'-<iimethyl- 
amlnoethcxybenzyl)pyrldlne succinate) . 

2- [ ( 2-Dimethylflmf noethyl) (p-methoxybenzyl)- 
amlnojpyridine maleate. 

2-[ (2-Dlmethylaiiilnoethyl) (p-methoxybenzyl) - 
amino]pyrlmldine (N,N-Dlniethyl-N'-p- 
methoxybenzyl-W-2-pyrliiildylethylenedlainlne) , 

2-[(2-Dlmethylajninoethyl)thenylamlno]pyrldine 
fumarate (N,N-Dim6thyl-N'2-pyrldyl-N'2- 
thenylethylenediamine fumarate). 

2-[ (2-Dlmethylamlnoethyl) thenylamlnojpyridlne 
hydrochloride (N,N-Dliiiethyl-N'2-pyrldyl- 
N'2-thenylethylenediamlne hydrochloride) . 

2- [3-( Dimethylamino) -l^henylpropyl] pyridine 
( l-Phenyl-l-( 2-pyridyl) -3-dimethylamlno- 
propane) . 

2- [ 3-( Dlmethylamino) -l-^henylpropyl] pyridine 
maleate (Prophenpyrldamlne maleate) . 

2-Methyl-9-phenyl-2 , 3 , -i, 9-tetrahy4ro-l- 
pyrldindene hydrogen tartrate. 

N-(l^yrrolldyl)ethylph6nothiazine hydro- 
chloride. 
Antlpyrlne ( l,5-Dimethyl-2-ph6nyl-3-pyrazolone) — 
Barbituric acid 



•Barbituric acid derivatives: 

5-Allyl-seo-butyl barbituric acid (Lotusate)";— 
5-Allyl-5-(2-cyclqpenten-l-yl) barbituric acid 

and salt (Cyclopal). 
5-Allyl-5-lsobutylbarblturic acid and salt 
5-JVllyl-5-isopropylbarblturlc acid (Alurate) — 
»5-Allyl-5-( l-methylbutyl) barbituric acid 

(Secobarbital) and salt. 
5-Allyl-5-phenylbarbiturlc acid and salt 

(Alphenal) . 
n-Amyl ethylbarblturlc acid, sodium salt- 



5-n-Butyl-5-ethylbarblturic acid (Neonal) 

»5-sec-Butyl-5-ethylbarbituric acid 

*5-sec-Butyl-5-ethylbarblturlc acid, sodium salt- 
5-( 1-Cyclohexen-l-yl) -1, 5-dimethylbarbltur Ic 

acid (Evipa].) . 
5-(l-Cyclohexen-l-yl)-l,5-dlmetliylbarblturlo 

acid, sodium salt. 
5-(l-Cyclohexen-l-yl)-5-ethylbarbituric acid 

and salt. 
5,5-Dlallylbarbituric acid (Dlal)- 



»5,5-Dl6thylbarblturlc acid (Barbital) 

»5, 5-Dlethylbarbituric acid, sodium salt 
5-Ethyl-5— isoamylbarblturic acid and salt 

(Amytal) , 
5-Ethyl-5-laqpropylbarblturic acid and salt 
5-Ethyl-5-(l-methyl-l-*utenyl)barbiturlo acid 
(Delvinal) . 
«5-Ethyl-5-(l-methyl-n-butyl) barbituric acid 
(Pentobarbital) . 
5-Ethyl-5-(l-m6thyl-o-butyl) barbituric acid, 
calcium salt. 
»5-Ethyl-5-( 1-methyl-n-butyl) barbituric acid, 
sodium salt. 
5-Ethyl-5-( 1-mothyl-n-butyl) -2-thlobarblturic 

acid and salt (Pentothal) . 
5-Ethyl-l-methyl-5-phenylbarblturlc acid 

(Mephobarbital) . 
5-Ethyl-N-methyl-5-5henylbarbituric acid 
(Mebaral) . 
»5-Ethyl-5-fh6nylbarblturlc acid (Phenobarbital) 
(Luminal) . 
5-Ethyl-5-phenylbarblturlc acid, calcium salt — 

*5-Ethyl-5-phenylbarbiturlc acid, sodium salt 

Barium Inoslnate 



19<;, 201. 

540. 
284. 

208, 420. 

208, 247, 420. 



l^enzamido-l-phenyl-3.^)iperldlnqpropane 
hydrochloride. 



414. 










463. 










232. 










335, 


420, 


447, 






396, 










247. 










279. 










145, 


279. 








126, 


463, 








168, 


240, 


274, 


279, 


310 


279. 










240. 










420. 










145, 


168, 


240, 


279, 


420 


168, 


240, 


279, 


420. 




247. 










247. 










247. 










279, 


421. 








274, 


279, 


420, 






279, 


420, 








168, 


240, 


274, 


279. 




420. 










145, 


X, 








145, 


168, 


240, 


279, 


420, 


279. 










145, 


168, 


240, 


279, 


420, 


420. 










447, 










2A7. 










240, 


247, 


279, 


327, 


420. 


240, 


279. 








240, 


247, 


279, 


327, 


420. 


397. 










274. 











SYNTHETIC ORGANIC CHEMICALS, 1954 



109 



TAHLE 17B. --Synthetic organic chemicals: Medicinals for which United States production 
reported, identified by manufacturer, J954- -Continued 



Mamif aeturars ' identification numbers 
(according to list in table 27) 



MEDICINALS, CICLIC— Continued 



All 



nd Hete 



; lie- -Continued 



N-Benzoyl ethyl-plperldlne axlme and hydro- 
chloride. 
«Blle acids and salts: 

BlliTMbln 

Bilron 

Cholio acid 
•Dehydrochollc acid 

Dehydrocholie acid, sodium salt 
•Desoxychollc acid 

Ketocholanic acids 

Lithochollc acid 



Mixed bile acids, extracted 
Mixed oxidized bile acids 
Bromocamphor, mono 

4-(n-Butoxy)phenyl "t-niorphollnepropyl ether 
a-Butyloxycinchoninic acid dlethylethylenediamlde 
and hydrochloride (Ni^iercalne) , 

•Caffeine, natural 

•Caffeine, synthetic 

Caffeine derivatives, natural and synthetic: 
•Caffeine citrate 



Caffeine sodium benzoat o 

Camphor, synthetic, U.S.P— — — — 

Caiqjharic acid 

Camphoric anhydrld o 
Camphosulf onlc acid 
Caj^jhosulfonlc acid salts: 

Calcium camphosulf onate 

Sodium camphosulf onate 
Carboxymethylcellulose, sodium salt- 
Cellulose, oxidized 
Chelidonlc acid- 



7-Chloro— li— (i-dlethylamlno-lKnethylbutylamlno) - 

quinoline (Aralen) . 
»5-Chloro-7-lodo-8-qulnollnol (lodochlorohydroxy- 

quinollne) . 
7-ChlorokynurBnic add ( 7-CM.oro— 4-hydroxy- 

qulnollne-2-carboxyllc acid) . 

6-Chloropurlne 

P -Cholesterol 

Clnchophen (2^henylqulnoline-4-oarboxyllc acid) 

hydrolodide. 
Clnchophen, sodium salt 
Cocarboxylase 
Coenzyme A- 



Coramine (NikethHinide)- 
Cozymase- 



l-Cyclohexylamino-2^ropyl benzoate (Cyolaine) 

hydrochloride . 
l-Cyclohexyl-2-niethylpropylamlne — 



a-Cyclohexyl-a-phenyl-l-plperidinepropanol 
a-Oyclohexyl-a-phenyl-l-pyrrolidinepropanol— — — — 
a-Cyclohexyl-a-^henyl-l-pyrrolidineprapanol methyl 

sulfate and methyl chloride. 
Cyclcipentamine o, 4— hydroxybenzoyl benzoat o 
Cyclopentanol — 
Cyclopentyl bromide 
l-Cyclopentyl-2-methylpropylamlne (Cyclopentamine) 

hydrochloride . 
a-Cyelopentyl-a-phenyl-l-piperidineprqpanol 

Cytldlne and cytidine sulfate ___ _ ^_ 

Cytldyllc acid 
Cytoslne- 



Desoxyribonuclelc acid 

Dextran (Glucopyranose anhydride) 

2,'i-Diamlno-5-(p-chlorophenyl)-6-ethylpyrimidlne 

(Daraprlm). 
A, 7-Dichloroquinollne- 



Dlethylamlnocarbethoxybicycloheryl (Dicyclomine) 
hydrochloride (Bentyl hydrochloride). 

6-(2-Diethylamlnoethcacy) -2-dlmethylamino- 
benzothiazole hydrochloride. 

l-Diethylcarbamyl-4-methylpiperazlne dihydrogen 
citrate (Hetrazan) . 

3,3-Dlethyl-2,A-dioxoplperidine- 



3,3-Dlethyl-5-niethyl-2,4-piperidinedione 

N,N-Dlethylpicolinamide (Pyridine-g-carboxylic 
acid, diethylamide). 



513. 




27^. 




206, 247, 


278, 367. 


206, 218, 


278, 367. 


278. 




206, 218, 


247, 278, 355, 367 


Ae, 218, 


247, 442. 


355. 




2-17, AA2. 




278, 367. 




327, 335. 




420. 




421, «7, 


557. 


208, 293, 


354. 


208, 528. 




208, 327, 


540, 550. 


279, 327, 


540. 


31, 537. 




126, 447, 


501, 


158, 501. 




126, 501. 




501. 




501. 




421. 




495. 




274. 




247. 





126, 305, 309, 421. 

223. 

543. 
367. 
274, 

466. 
397. 
X. 

126, 421. 
397, X. 
540. 

208. 
466. 
274. 
274. 

274. 
274. 

263, 274. 
274. 

274. 

397. 

397. 

397. 

397. 

201, 290. 

248. 

180. 
201. 



463, 
463. 
178. 



110 



UNITED STATES TARIFF COMMISSION 



TABLE ITH.-Syntheti 



rganic chemicals: Kedicinals for which United States production or sales were 
reported, identified by manufacturer, 7954- -Continued 



Manufacturers' Identification numbers 
(according to list in table 27) 



MEDICINALS, CYCLIC— Continued 
Alicyclic and He lerocyc I ic--Continued 

Dihydrocodeinone bitartrate 
Dihydrohydroxycodeinone hydrochloride 
Dllodochelidamio acid 



3,5-Dlicdo-N-niethyl-4— pyridone— 2,6-dicarboxyllc 

acid. 
3,5-Diiodo--l-pyrldone-N-acetic acid, diethanol- 

amlne. 

»5,7-Diiodo-8-qulnolinol 

6,7-Dimethoxy-l-('i-ethory-3-methoxybenzyl)-3- 

methylqulnoline phosphate (Dlcacyline phosphate) . 
•l-DimethylaQlnoantlpyrine (Amlnqpyrlne) 
P,a-Dimethylben2yl camphorate, diethanolamlne salt- 
p,a— Dimethylbenzyl camphorate, N-ethyl-3,3'- 

dlphenyldlpropylamihe salt. 
N,a— Dlmethylcyclohexane-ethylamine (l-^yclo- 

hexyl-2-methylaminopropane) . 
l,3-Dimethyl—i-^)hanyl-'i-^ropionoxypiperldin9 

hydrochloride (dl a form) . 
N,N-Dim6thyl--;-piperidylldene-l,l-diphenylmethaiio 

methyl sulfate (Diphenmethanil methyl sulfate) , 
Diothane (Piperldinepropanedlol dlphenylurethane) 

base. 
Diothane hydrochloride 
»5, 5-Diphenylhydantoin- 



•5,5-Diphenylhydantoin, sodium salt 
l-(Dlphenylmethyl) -4-methylpiperazinium base 

(Cyolizine) and hydrochloride. 
a,a-Dlphenylpiperldinemethanol- 



Dlpyrrobutamine-l, 5-naphthalene disulf onate- 
Epoxytropine-tropate methylbromide- 



5-Ethyl-3,5-dimethyl-2,'V-oxazolidlnedicine 

Ethyl l-methylwV^henyliaonipecotate (Demerol)- 
Ethynyl oyclohexyl carbamate (Valaid) 
Fructose (Levulose)- 



Fructose-6-phosphate, barium salt- 
Galaetose 



Glucose-6-^hosphate, barium salt— — 

GluooBe-1-phosphate, potassium aalt- 
GlucuroDolaeton o 
Guanin e 



Guanine hydrochloride- 
Guanine sulfat e 
Guanosln o 
Guanylio acid- 



Guanyllo acid, sodium salt- 
Hexamethylenetetramlne- 



Hexamethylenatetramlne acetajuinosallcylic acid 

(Sallheiin). 
Hexamethylanetetramine anhydrooiethylene citrate 

(Heljnitol). 
Hexamethylenetetramlne cajqjhorat o 
Hexamethylenetetramlne mandelat o 
Hexokinase 
Hexosediphosphorlc acid salts: 

Barium hexoaedlphosphate 

Calcium hexosediphoephat o 

Magnesium hexes ediphosp hat e 
•Hormones (steroid): 



Adrenocorticotroplo barmone (ACTH)- 
Deaoxyoorticosterone acetat e 
Estradiol 



Estradiol 3-benzoata- 



Estradlol cyclopentylpropionats- 

Estrogenlc substanc e 

Estron e 



Estrone sulfate, sodium salt— 
Ethlnylestradlol- 



Ethlnyltostost er one- 
»Hydrooortisone alcohol and aoetate- 



17^iydroxy-ll-dehydrocorticosterone (Cortisone) 

and acetate. 
Methylandrostenedial 
Methyltestosterone- 



Plperazine estrone sulfate- 
Pregnenolone- 



Pregnenolone acetate- 
Progesterone 



Reichflteins substance S acetate- 



327, 4^2, 550. 
327, ^2. 
5A0. 

247. 

46, 126, 305, 309, 413, 4-47. 
274. 

447. 
197. 
197. 



194. 

194. 

126, 168, 279, 310. 

126, 168, 279, 310, 4S4, 501, 540. 

248. 

194. 

274. 

232, 447. 

420. 

247. 

274. 

4L2. 

397. 

412. 

397. 

397. 

146. 

397. 

397, 513, 

397. 

397. 

397. 

397. 

569. 

420. 

247. 

501. 
284. 
485. 

397. 
397. 
397. 

180, 232, 367, 438. 

414, 581. 

4W. 

414, 421. 

232. 

1A3, 

U3, 180. 

471. 

414, 421. 

414. 

232, 414, 528, 540. 

232, 414, 540. 

414, 421. 

414, 421. 

420. 

414. 

414. 

180, 414, 421, X. 

581. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



111 



TABLE 17B. --Synf/iefic organic chemicals: tedicinals for which United States producti 
reported, identified by manufacturer , 1954- -Continued 



Manuf acturors ' Identlfloatlan numbers 
(aoeordlng to llat In table 27) 



MEDICINALS, CTCL I C— Continued 

Alicyclic and flef erocyc 1 ic--Continued 

•HarmoneB (starold)— Continued 
Reichfltelns substance S alcohol 
Teatoateron o 



Testosterone benzoat o 
Testosterone cyclopentylproplonate- 
Testosterone phenylaoetate— — — 
Testosterone proplonate- 



l-Hydrazlnonaphthalazine hydrochloride— —— 

A-Hydroxycoumar In 

8-Hydroxy-7-iodo-5-quinollnesulfonic acid 

(Yatren acid) and salt. 
l-( 3-Hydroxy-5-methyl-4-phenylhexyl) -1-methyl- 

piperldinium bromide (Darstlne) . 
8-Hydraxy-5-qulnolinesulfonio acid 
Hypoxanthi.n o 
lodoantipyrin o 

»Isonicotinic acid hydxazlde 

Lysidine bitartrat o 
Malt OS 



Menthyl salicylat e 
homo-Menthyl salicylat e 
6-Mereaptc^urin o 
P^ethoxy-Y-hydroxymercuric propylamide of 

eaji5>horic acid (Mercurial acid) . 
P-«ethoxy-Y-hydroxymercuric propylamide of 

caagjhorio acid, sodium salt with theophylline 

(Merci5)uriii) . 
8-(2'-WethQiy-3-hydroxymerouri)propylcoumarln- 

3-carboxylio acid (Mercumallyllc acid) . 
Methylcholanthrene- 



3,3'-Methyl6nebis[4-hydroxycouiiiarin] (Dicumarol)- 
Methyl nicotinate- 



3-(2-Methyl-l-piperidyl) propyl alcohol 

3-(2-Methyl-l-piperidyl)prcipyl benzoate 

(Metyealne) . 
3-(2-Methyl-l-piperidyl)propyl p-cyolohexyl- 

oxybenzoate. 

5(and 6) -Methylthiouracll 

l-Methyl-2-und6cylimldazole 

5(and 6)-M9thyluracil- 



Myristyl-Y-picolinium chloride (Quatresin) 

2-( 1-Naphthylmethyl) -2-imidazollne (Privine) 

hydrochloride . 
Neocinchophen (Ethyl 6-methyl-2-phenylclnchoni- 

nate) . 
Novalgin ( l-Phenyl-2,3-dimethyl-<»-methylamlno- 

5-pyrazolone formaldehyde bisulfite) . 
Nucleic acid 
Nucleic acid salts- 



Pamaqulne (Plaamochln) (N-Dlethylamlnoisopentyl- 

8-amino-6-methoxyquinollne) . 
Papaverine hydrochloride, synthetic 
Perparln base 
Perparin hydrochloride 
•Phenothlaz ine 

Phytic acid 

Phytic acid salts: Calcium phytate 

»Piperazine 

Piperazine derivatives: 

Plperazine adipate 

Piperazine citrate- 



Piperazine dliodide- 
Piperazine tartrate- 



sym-N-Tetramethylpiperazine dllodlde— — 

6-Propyl-2-thlouracil 

Pyridlum (2,6-diamino-3-^henylazapyTidlne)- 

p-Pyridyl-carbinol 

P-Pyrldyl-carbinol tartrate 

Pyrimet hamin e 

Y-Pyrone- 



P-Pyrrolldinqproplophenone hydrochloride 
(Juinaorlne (Atebrin) ( 2-Methoxy-6-<hlo^o-9- 
diethylaminopentylamlnoaoridlne) . 
8-Qulnollnol (8-Hydroxyqulnoline) salts and esters: 
8-(iulnolinol base 



8-^3uinolinol benzoate 
8-Quinolinol citrate 
8-(Juinolinol sulfate (ftuinosol)- 



581. 

U3, 4U, 421. 

U3. 

232. 

';21. 

-lU, «1. 

421. 

501. 

126, 247, 305, 309. 

540. 

309. 

397. 

327. 

284, 438, 463, 473. 

141. 

412. 

141. 

141. 

248. 

168, 501. 

168, 501. 



513, 


543. 




420, 


466, 


501. 


141, 


178, 


447. 


274. 






274. 






274. 






397. 






274. 






397. 






232. 






421. 






466. 






247, 


413, 


447. 


397. 






397. 






247. 






274, 


327, 


540. 


141, 


447. 




141, 


145, 


447. 


4, 176, 335, 537 


162. 






146, 


413. 




126, 


413, 


447. 


447. 






126, 


413, 


447. 


413. 






126, 


447. 




126. 






466. 






284, 


447. 




463. 






463. 






248. 






274. 






274. 






247. 






40, 


309. 




40, 


309. 




40. 






40, 


126, 


309. 



112 



TABLE nB.--Syntheti 



UNITED STATES TARIFF COMMISSION 

organic chemicals: Hedicinals for which United States producti 
reported, identified by manufacturer, 1954- -Continued 



Manufacturers' IdeEtlflcatlon numbers 
(according to list In table 27) 



HEDICINALS, CYCLIC— Continued 



Alt 



and Hcterocyclic--r.ontin 



8-Quinolinol (8-Hydroxyqulnoline) salts and 
esters— Continued 
8-Quinollnol sulfate, potassium salt 
8-Quinolinol tannate 



Rutin- 

Terpinol hydrate- 



Thenylpyramlne o,^hydroxybenzoylbenzoate- 

»Theobromlne , natural 

•Theobromine derivatives: 

Theobromine calcium gluconate 

Theobromine calcium salicylate 

Theobromine salicylate 



Theobromine sodium acetate 

Theobromine sodium salicylate- 



»Th6ophylline (1,3-DimethylJcanthine) base and 
derivatives: 

7-( P-Hydroxypropyl) theophylline 

Magnesium theophylline 

Theophylline acetic acid 

Theophylline aminoisobutanol 

•Theophylline base- 



•Theopl^lline ethylenediamine (Aminophylline) — 
Theophylline ethylenediamine sodium biphosphate- 

Theopl^lline methoxymercuripropylsuccinylurea 

Theophylline monoethanolamine 

Theophylline sodium acetate- 



Theophylline sodium salicylate 

2-Thiouracil 

Thymidine — ^— — -— — ^— — — 

3,5,5-Trimethyl-2,'i-oxazolidinedione (Tridione)- 
Triphosphopyridine nucleotide 

Tropine benzoliydryl ether methanesulf onate 

Uraci 1 

Uric acid 

Uridine ■■■ 



Uridine 5 '-phosphate 

Uridine triphosphate __— 

Uridylic acid 

l-Vinyl-2-pyrrolidone polymerlzed- 
•Vitamins: 

»A, from all sources: 
A, acetate- 



A, acetate (feed grade)- 

A, alcohol 

A, esters 

A, palmltate- 



A, palmitate (feed supplement) 
»Bi (Thiamine hydrochloride)-^-— 
«Bi (Thiamine nitrate) 



•Riboflavin for human consumption, 100^- 



•Riboflavin for animal and poultry consumption, 
lOO^t. 

Rlboflavin-5' -phosphate, monosodium salt 

•Bj (Pyridoxine) 

»Bi2, 100«t: 
Feed grade- 



Pharmaceutical quality- 
U.S.P. Crystalline- 



»D2 (Irradiated ergosterol) (Calciferol) — 
»D3 (Irradiated animal sterol) (Delsterol)- 
E (a -Tocopherol) - 



E (a-Tocopherol acetate) 

Folic acid 

Inositol 



Inositol hexaphosphate , calcium, magnesium — 

•Niacin (Nicotinic acid) 

•Niacinamide (Nicotinamide) 

•Niacinamide hydrochloride 

Xanthine 

Xanthine, sodium salt——— 



MEDICINALS, ACYCLIC 

Acetylcarbromal (l-Acetyl-l-(2-bromo-2- 
ethylbutyryl) urea) . 

Acetylcholine bromide 

Acetylcholine chloride 



309. 




40. 




180, 305, 


557. 


305, 447, 


557. 


274. 




208, 293. 




218. 




168, 447. 




540, 550. 




327, 438, 


540. 


293, 327, 


447, 540. 


279. 




327. 




279. 




X. 




240, 279, 


327. 


46, 93, 240, 279, 305, 355, 528, 540 


550. 




174. 




274. 




279, 327, 


355. 


528. 




466. 




397. 




420. 




485. 




540. 




397, 513. 




304, 412. 




397. 
X. 




X. 

397. 




384. 




383, 463, 


513, 528, 540. 


528. 




383, 534, 


540. 


513. 




463, 513, 


528, 540. 


463. 




463, 466, 


528, 540. 


463, 466, 


540. 



205, 463, 528, 540. 

205, 272, 290, 466, 485, 528, 540. 



463. 
















463, 


466, 


540. 












205, 


272, 


290, 


466, 


485, 


528, 


540, 


601 


528, 


540. 














540. 
















180, 


211, 


247, 


249, 


272, 


385, 


388, 


534 


247, 


249, 


272, 


388, 


534, 


537. 






463. 
















463. 
















232, 


466. 














146, 


162. 














162, 


421, 


447. 












284. 


388, 


540, 


584. 










211, 


284, 


473, 


508. 










284. 
















397. 
















397. 
















145, 


310, 


447. 












126, 


513. 














126, 


413, 


540. 













SYNTHETIC ORGANIC CHEMICALS, 1954 



113 



TABLE 17B. --Synthetic organic chemicals: Medicinals for which United States production 
reported, identified by manufacturer, J954- -Continued 



Manufacturers' Idanttflcatlon numbers 

(according to Hat in table 27) 



MED1CINA15, ACyCLIC — Continued 



S-Aeetylglutathicme 

Acetylmethionlne 

Acetyl-p -niethylchollne bromide — 
Acetyl-^-methyloholine chloride- 
Acetyl phosphate, lithium salt — 
•Amino acids: 
d-Alanine- 



dl -Alanine (dl-a Alanine) - 
1-Alanine 

•P -Alanine 

dl-Aspartic acid 
l-Citrulline- 



l(+) -Cysteine hydroohloride- 
Ethionine- 



«l(+) -Glutamic acid 

l(+) -Glutamic acid, calcium salt- 
l{+) -Glutamic acid hydrochloride- 



l(+) -Glutamic acid, monoammonium salt — 
l(+) -Glutamic acid, monopotassium salt- 
1-Glutamin 



Glycine (Aminoacetic acld)- 
1-Isoleucine 

d-Leuoine 

dl-Leuc ine 
1-Leucine 



dl-Lyaine hydrochloride 

l(+) -Lysine hydrochloride- 

»d -Methionine 

»dl-Methlonine 

»l-Methionine 



•Methionine, feed grade- 
dl-Norleuo ine— — — — 



1-Omithine hydrochloride- 

dl^erine 

dl-Threonlne— 

d-Valine 

dl -Valine 

1-Valine 



Amino acid mixtures- 
2-Amino-4-methylhexane- 



Amyl nitrite (Isoamyl nitrite) 

Auro-thiogluoose 

a,a'-Azobis(chloroformamldine) (Azochlora 

•Betalne base 
Betaine hydrate 

»Betaine hydrochloride 

Bromocholine bromide- 



lide)- 



Bromoform (Tribromomethane) 

Bromural (a-Bromoisovalerylurea)- 
Cacodylic acid derivatives: 
Iron cacodylate 



Sodium caoodylate- 



Calcium bromolactobionate- 

Calcium glycerate 

Calcium iodobehenate 

Calcium lactophosphate 

Calcium levullnate 

•Calcium succinate 



Carbaminol choline chloride 
Carbamyl-2-hydroxyprqpyltrimethylaimionium chloride- 

•Carbromal (Bromodiethylacetylcarbamlde) 

Cetyl-<limethyl-ethyl-ammonium bromide 
Chloral hydrate- 



•Chloretone (tert-Trichlorobutyl alcohol) - 

Chloriodized oil 

•Choline salts: 



Choline bicarbonate- 
•Choline bitartrate — 



•Choline chloride, for animal and poultry feed and 
for use as an intermediate. 

•Choline chloride, medicinal grade only 

•Choline dihydrogen citrate 
Choline tricitrate 

Diallylacetlc acid 

Diallylacetic acid, bismuth salt 

2,2-Diethyl-l,3-propanediol 

l,3-Dliodo-2-propanol 

2 , 2-Dii3opropyl-5-hydr oxymethyl-1 , 3-dioxolane 



397. 








il5. 








540. 








413, 


540. 






397. 








397. 








335. 








397. 








388, 


420, 


487. 




403. 








397. 








266. 








415. 








158, 


385, 


416. 




305. 








158, 


385. 






158, 


385. 






158. 








158. 








240, 


335, 


447. 




335, 


397. 






397. 








247, 


335. 






162, 


540. 






335, 


447. 






537. 








397. 








335, 


415, 


447, 


537. 


397. 








415, 


537. 






540. 








397. 








413, 


540. 






247, 


413. 






397. 








335, 


540. 






397. 








162. 








274. 








327, 


513. 






414. 








419. 








158, 


447. 






158. 








158, 


305, 


44.7, 


587. 


413. 








335. 








145, 


447. 






126, 


180. 






126, 


180. 






447. 








501. 








501. 








327. 








447. 








305, 


403, 


557. 




413, 


540. 






540. 








145, 


180, 


247, 


310, 447 


150. 








540. 








141, 


180, 


240, 


395. 



290, 447, 587. 

126, 466, 515, 587. 

272, 290, 388, 417, 515, 540. 

126, 447, 466, 515, 540, 587. 

126, 447, 466, 515, 587. 

447, 466, 515, 587. 

197. 

197. 

438. 

501. 

145. 



114 



UNITED STATES TARIFF COMMISSION 



TABLE 17H. --Synthetic organic chemiculs: Medicinals for which United States prodtcti 
reported, ident i fied by manufacturer , i954- -Continued 



Manufacturers' identification numbers 
(according to list in table 27) 



MEDICINAI-S, ACYCLIC— Continued 



1,2-Dim6roaptopropaiiol— — — — 
Dlvinyl ether 

Ethyl carbamate (Urethane) 

Ethyl cha\ i1m oograte 
Ethylenediamlne dlhydroohloride- 

Ethylenedlamlne dilodide 

Ethyl iodide 

Ethylmercuric chloride 

Ethyl morrhuate 

Ethyl nitrlte- 



Gluconic acid salts: 
Ammonium gluconate- 



Caloium glucoheptonate—- 
Calcium gluconate 
Cobalt gluconate— 
Copper gluconate 
Iron (ferrous) gluoonete- 
Magnesium gluconate 
Manganese gluconate 
Potassium gluconate 
Sodium gluconate- 



Glucono-delta-laotone- 
Glutathlone- 



Glutathione, monosodium salt 

Glutathione (oxidized) 

Glycerophosphoric acid 

Glycerophosphoric acid derivatives: 
Calcium glycerophosphate 
Iron glycerophosphate 

Manganese glycerophosphate 

Potassium glycerophosphate——— 
Sodium glycerophosphate———— 

Gold sodium thiomaleate- 



Hendecenoic acid (Undecylenlc acid) sedts: 
Copper hendecenoate — ■ 

Zinc hendecenoate 



Hexamethyldlaminoisopropanol dilodide 

Hexamethylenebls[ trimethylammonium bitartrate] 

(Hexamethonlum bitartrate) . 
Hexamethylenebisf trlmethylammonium bromide] 

(Hexamethonlum bromide). 
»Hexamethylenebis[trimethylammonlum chloride 1 

(Hexamethonlum chloride). 
Iodized castor oil 
Iodized oils, other 
Iodoform 



lodomethanesulfonic acid, sodi 
Iron (ferrous) oxalate 
Isovaleric acid salts: 

Ammonium isovalerate 

Sodium Isovalerate 

Zinc laovalerate- 



Lactlc acid salts (medicinal grades only): Aluminum 

lactate. 
Lithium pyruvate — — ^— .— — — ^-^— — — ^ 
Magnesium citrate 
Malononitrile 

Methylenecltrlo acid and salts 

Methylene iodide 
l-Methylhexylamine 

«Methyl iodide 

Morrhulc acid salts: Sodium morrhuate 
Phosphoglyceric acid, barium salt 
2-Propylvalerlc acid, bismuth salt 
d-Rlbo36 



Rlbose-5-phosphate, barium salt- 
Silver protein, strong 
Sodium bismuth trlglycolamate — 
Sodium lodopropanol sulfonate — 

Sodium pyruvate 

*Sodium succinate 
1-^orbose 



Succlnylcholine dlohlorlde- 
Succinyl peroxide 
Tartaric acid 



Tartaric acid salts, medicinal grades only: 
Antimony potassium tartrate (Tartar emetic) — 
Bismuth potassium tartrate 
Calcium tartrate 



Potassium bitartrate- 



501. 






5A0. 






-115. 






501. 






201, 447. 






459. 






327, 413, 


540. 




274. 






501. 






327. 






528. 






4L2, 






327, 412, 


528. 




447. 






447, 528. 






447, 528. 






528. 






447, 528. 






528. 






528. 






528. 






397. 






397. 






397. 






208, 569. 






201, 208, 


569. 




208, 569. 






569. 






208. 






208, 569. 






540. 






447. 






447. 






247, 413. 






454. 






434. 






413, 438, 


484. 




141. 






274. 






327, 550. 






247. 






447. 






310, 413. 






310. 






310. 






447. 






397. 






327, 540. 






40. 






247. 






247, 413, 


447, 513, 


540, 543 


274. 






327, 413, 


513. 




501. 






397. 






197. 






397. 






397. 






247. 






240. 






141. 






397. 






305, 540, 


557. 




388, 528. 






24a. 






141. 






528. 






528. 






413. 






447. 






392, 528. 







SYNTHETIC ORGANIC CHEMICALS, 1954 115 

TABLE \Tfl.- -Synthetic orgeric chemicals: Hedicinals for which United States production or sales were 
reported, iderti fied by manufacturer , 7 9 54 --Continued 



Manufacturers' identification numbers 
(according to list in table 27) 



MEDICINALS, ACYCLIC— Continued 

Tartaric acid salts, medicinal grades only- 
Continued 
Potassium sodium tartrate (Blsmosal)— — — 
Sodium bitartrate 
Sodium tartrate 



Tetraethylammonium chloride— 
Tetramethylammonlum chloride- 
Ttdosemlcarbazide 



2,2, 2-Tribromoethanol 

Triiodoethlonic acid 

Urea calcium iodide 
•Vitamins : 

"Ascorbic acid and derivatives: 
•Ascorbic acid 



Ascorbic acid, calcium salt- 
Ascorbic acid, sodium salt — 
Ascorbyl palmltate- 



•Pantothenic acid and derivatives: 
Pantothenic acid 



Pantothenic add, d-oalclum salt 
•Pantothenic acid, dl-calclum salt 

Pantothenic acid, sodium salt 

d-Pantothenyl alcohol (a , Y-Dlhydr oxy-N- 
(3-hydroxypropyl)-P,P-dimethylbutyTamlde) . 



392, 


528. 












327. 
201, 


327. 












413. 














413. 














126, 


313. 












247. 














414. 














327. 














463, 


528, 


540. 










528. 














463, 


523, 


540. 










528. 














272. 














180, 


274, 


388, 


420, 


466, 


540. 




211, 


274, 


388, 


420, 


466, 


515, 


540 


180. 














463. 















116 



UNITED STATES TARIFF COMMISSION 

Flavor and Perfume Materials 



TABLE 18B. --Synf/iefic 
product! 



rganic chemicals: Flavor and perfume materials for which United States 
or sales were reported, identified by manufacturer, 1954 



^ZZ,T,lfT "^^"^^^^ ^°l ^hf ^ separate statistics are given in table ISA are narked below with an 
asterisk (»); those not so marked do not appear in table ISA because the reported data are accepted in 
taS^e 27]" "^'^ " published. Manufacturers' identification numbers shown below arl ?^en ?rom 



Material 



FLAVOR AND PERFUME MATERIALS, CYCLIC 



Btnz 



nd Naphthaltnoid 



2-Aoetonaphthone (Methyl g-naphthyl ketone) 

Acetophenone 

•a -Amylc innamaldehyde 

a-Amylcinnamaldehyde, dimethyl acetal 

(X-Amylcinnamyl alcohol 

*Ane thole , 

•Anisaldehyde 

Anisole (Methyl phenyl ether) 

Anisyl acetate 

Anisyl alcohol 

Anisyl formate 

Anisyl propionate 

»Ben2ophenone 

»Benzyl acetate 

•Benzyl alcohol, all grades 

•Benzyl benzoate, all grades 

Benzyl butyrate 

•Benzyl c innamate 

Benzyl ether 

Benzyl formate 

Benzyl isoamyi ether 

Benzyl isobutyrate 

Benzyl isoeugenyl ether 

Benzyl isovalerate 

Benzyl phenylacetate (Benzyl a-toluate) 

•Benzyl propionate- 



•Benzyl salicylate 

Benzyl valerate 

a-Bromostyrene 

Butyl anthranilate 

'4-tert-Butyl-2,6-dimethyl-3,5-dlnitroacetophenone 

(Musk ketone). 

3-tert-Butyl-2,6-dinitro-p-cyii!ene 

5-tert-Butyl-4,6-dinitrohemimellitene 

6-tert-Butyl-3-methyl-2,4-dlnitroanisole (Musk 

ambrette). 

Butyl phenylacetate 

5-tert-Butyl-2,4,6-trinitro-m-xylene (Musk xylol)- 

Carvacrol (Isopropyl-o-cresol) ^_ 

C Innamaldehyde 

C innamic ac id — ' 

C innamyl ace tate~— — 

Cinnanyl alcohol 

C Innanyl anthr ani late 

Clnnamyl butyrate — 

Cinnamyl c innamate 

Clnnamyl formate- 

Clnnamyl isobutyrate 

Clnnamyl isovalerate 

Cinnamyl propionate 

Clnnamyl valerate- 



Cumaldehyde (p-Isopropylbenzaldehyde) 

p, a-Dimethylbenzyl alcohol (p-Methylphenylmethyl- 

carbinol). 

o ,a-Dimethylphenethyl acetate 

a,o-Diiiiethylphenethyl alcohol 

a,a-Dlmethyl-3-phenylpropanol 

Dlphenylme thane 

l,3-Diphenyl-2-propanone (Dibenzyl ketone) 

Dulein (p-Phenetylurea) 

2-Zthoxynaphthalene (Ethyl g-naphthyl ether) 

Ethyl anlsate 

Ethyl anthranilate 

Ethyl benzoate 

Ethyl cinnamate 

Ethyl a,P-epoiy-P-methylhydroclnnamate (Ethyl 

methylphenylglyc idate ) . 

2-EthyIheiyl salicylate 

Ethyl p-methoxyc innflmate 

Ethyl methyltolylglycidate 

p-Ethylphenol . 

Ethyl P-phenylglycidate 

Ethyl salicylate 

Ethyl vanillin 



Manufacturers' identification numbers 
(according to list in table 27) 



374, 395. 

395, 562. 

132, 302, 338, 355, 374, 395, 449, 598. 

302. 

338, 374. 

31, 124, 214, 374, 395. 

141, 374, 395. 

141, 395. 

154, 302, 374, 395. 

302, 374, 395. 

154, 302, 374. 

154, 302, 374. 

374, 395, 396. 

9, 338, 355, 374, 395, 396, 449. 

9, 199, 239, 240, 338, 355, 374, 395. 
9, 199, 208, 239, 355, 395, 580. 

125, 154, 302, 374, 395, 449. 

9, 141, 302, 338, 374, 395. 

395. 

293, 302, 374, 395. 

374, 395. 

154, 302, 374, 395. 

302, 374, 395. 

302, 374. 

293, 302, 374, 395, 449. 

125, 154, 302, 338, 374, 395, 449. 

9, 132, 338, 355, 374, 395. 

154, 302. 

374. 

125. 

355, 395. 



395 








395 








355 


395 






395 








355 


395 






395 








374 


395 






141 


240 






302 


374 


395 




132 


355 


374 


,^95. 


302 


449. 






125, 


302 


374 


395. 


374, 


395. 






302, 


374, 


449, 




154, 


302, 


374. 




9, 154, 302, 374, 395. 


125, 


302, 


374, 


395. 


302, 


449. 






395, 


461, 


537. 




395. 








338. 








338. 








338. 








335, 


374. 






395. 








413. 








374, 


395. 






Ul, 


302, 


395. 




302, 


313, 


355. 




302, 


374, 


395, 


415. 


302, 


374, 


395. 




141, 


302, 


374, 


395, 449 


449. 








395. 








Ul, 


302. 






395. 








141, 


302, 


374, 


449. 


335, 


374. 






208. 









SYNTHETIC ORGANIC CHEMICALS, I95A 



117 



T/ULE 18B. --Synthetic organic chemicals: Flavor and perfime materials tor which United States 
production or sales were reported, identified by manufacturer, I95¥- -Continued 



FLAVOR AND PERFUME MATERIALS, CYCLIC — Continued 

Bemtnoid and Naphthalenoid--Contlnued 

»'E\igenol ■■ ■ ' 

Eugenyl methyl ether 

Hexylclnnajoaldehyde 

Hydra tropaldehyde (a-Phenylproplonaldehyde ) 

Hydra tropaldehyde , dimethyl acetal 

Hydroclnnamaldehyde (p-Phenylproplonaldehyde) 

A- (A-Hydroxy-S-methoxyphenyl ) -3-'buten-2-one 
(Vanlllidlne acetone). 

Isoanyl tenzoate (Ajnyl henzoate) 

Isoamyl olnnamate (Amyl oinnainate) ■ ' 

laoamyl phenylaoetate (Amyl a-toluate) 

Isoamyl salicylate (Amyl salicylate) 

»Isobutyl benzoate 

Isobutyl clnnamate — — 

»Isobutyl phenylaoetate ( Isobutyl a -toluate ) 

Isobutyl salicylate 

• I soeugenol 

Isoeugenyl acetate 

Isoeugenyl methyl ether 

p-Isopropyl-a-methylhydroclnnamaldehyde (Cyclamen 
aldehyde ) . 

p-Me thoxyace tophenone 

o-Methoxybenzaldehyde 

2-Methoxybiphenyl 

2-Methoxynaphthalene (Methyl P-naphthyl ether) 

p-Methylacetophenone (Methyl p-tolyl ketone) 

Methyl anisate 

p-Me thy lanisole (p-Cresyl methyl ether) 

Methyl anthranilate 

Methyl benzoate 

•a-Methylbenzyl acetate 

p-Me thy Ibenzyl acetate 

a-Methylbenzyl alcohol (Methylphenyl carblnol) 

»Methyl clnnamate 

Methyl N-methylanthranllate (Dimethyl anthranilate )- 
p-Methylphenethyl alcohol (2-Phenyl-l-propyl 
alcohol). 

Methyl phenylaoetate (Methyl a-toluate) 

•Methyl salicylate (Synthetic vrlntergreen oil) 

»Phenethyl acetate 

*Phenethyl alcohol ■ 

Phenethyl anthranilate 

Phenetf^l butyrate 

Phenethyl clnnamate — — 

Phenethyl formate 

Phenethyl isobutyrate 

Phenethyl isovalerate 

Phenethyl phenylaoetate (Phenethyl a-toluate) 

Phenethyl propionate 

Phenethyl salicylate 

Phenethyl valerate 

2-Phenoxyethyl isobutyrate 

Phenylaoetald'ehyde (a-Tolualdehyde) 

Phenylacetaldehyde, dimethyl acetal 

4-Phenyl-3-buten-2-one (Benzylidene acetone) 

Phenyl-l,2-ethanediol diacetate 

3-Phenyl-l-propyl acetate 

3-Phenyl-l-propyl alcohol (Hydrocinnamic alcohol) — 

Sallcylaldehyde 

p-Tolualdehyde (p-Me thy Ibenzaldehyde ) 

p-Tolyl acetate (p-Cresyl acetate) 

p-Tolyl isobutyrate (p-Cresyl Isobutyrate) 

p-Tolyl phenylaoetate (p-Cresyl a-toluate) 

a-(Trlohloramethyl)benzyl acetate (Rosetone) 

p-o,a-Trlmethylphenethyl alcohol 

2,3, 5-Trlmethyl-l , 2 , 3 ,6-tetrahydrobenzaldehyde 

Vanillin 



Manufacturers' Identtfloatlon numbers 
(according to list in table 27) 



Terpenoid, Hettrocycli 



nd Alicycli 



Allyl cyclohexanepropionate- 

Allyl ionone 

Bomyl acetate 

Carvone (Carvol) 

Caryophyllene 

Cedrenal 



132, Ul, 239, 292, 302, 374, 395, 


557, 598 


Ul, 302, 374, 395. 




374, 537. 




338, 374, 395. 




338, 374. 




395. 




302. 




154, 302, 374, 395. 




154, 302, 374, 449. 




125, 302, 374, 395. 




374, 386, 395. 




154, 293, 302, 374, 395, 




154, 302, 374, 395, 449. 




125, 302, 374, 395, 598. 




302, 374, 395. 




132, 239, 302, 374, 395. 




302, 374, 395. 




Ul, 302, 374, 395. 




395, 461. 




141, 374, 395. 




125. 




338, 395. 




302, 374, 395. 




132, Ul, 374, 395. 




141, 302. 




374, 395. 




335, 355, 395. 




Ul, 154, 302, 569. 




302, 374, 395, 598. 




Ul, 302. 




374. 




Ul, 338, 374, 395. 




302, 355, 395, 449, 537. 




338. 




208, 374, 395. 




208, 335, 569. 




132, 302, 338, 395. 




132, 335, 338, 395, 557. 




302, 313, 449. 




302, 313, 374, 395. 




302, 338, 374, 395, 449. 




302, 338, 374, 395. 




395. 




125, 302, 374, 395. 




293, 302, 338, 374, 395. 




293, 302, 395. 




302, 338, 374, 395. 




302, 449. 




395. 




374, 395. 




302, 374, 395. 




374. 




338. 




374, 395. 




374, 395. 




302, 449. 




335. 




Ul, 302, 395, 569. 




125, 302, 374, 395. 




302. 




374, 395. 




141, 338. 




338. 




338. 




208, 244, 293, 395. 




302. 




395. 




125, 302, 449. 




124, 125, 302, 5U. 557. 




395. 




374, 598. 





118 



UNITED STATES TARIFF COMMISSION 



TABLE ISB. --Synthetic organic cheaicala: Flavor and perfume materiala for which United State 
production or sales were reported, identified by manufacturer, 1954- -Continued 



Manufacturers' identification numbers 
(according to list in table 27) 



FLAVOR AND PERFUME MATERIALS, CYCLIC—Conttnued 



Terpenoid, Heterocycli 



nd Alicycli 



Cedrol 

•Cedryl acetate 

»Clneole (Eucalyptol)- 
•Citral (Geranlal) 

Cltronellal 

«Cltronellol 



l-Citronellol 

•Citronellyl acetate- 



Cltronellyl butyrate 

Citronellyl formate 

•Citronellyl propionate 

•Couniarin 



Cyclohexanesulfamlc acid, calcium salt- 
Cyclohexanesulfamlc acid, sodium salt- 

Cyclopentanol 

Cyc lopentanone — 
Dlhydrocltronellol- 



3,7-Dimethyl-3-octanol (Tetrahydrollnalool) 

•Geraniol 

»Geranyl acetate ■ 

Geranyl benzoate —— 

Geranyl butyrate 

"Geranyl formate- 



Geranyl isovalerate 

Geranyl phenylacetate (Geranyl a-toluate)- 

Geranyl propionate 

a-Heptyl-8i-butyrolaotone ■ 

2-Hexyl-2-cyclopenten-l-one 

Hydrocoumarin (3,4— Dibydroooumarin)- 
» Hydro xyci tronellal- 



Hydrojiycitronellal, dimethyl acetal- 

Hydroxycitronellol 

Indole *• 

»Ionones: 



»a-Ionone- 
»P-Ionone- 
•lonone («- and P-)- 



Isobomeol (Isobomyl alcohol)- 

»l3oborryl acetate 

Isobomyl propionate 

Isobutylqulnollne 

Isopropylqulnoline 

Isopulegol 

Isosafrole 



d-Li^ionene 

*Linalool — 

•Llnalyl acetate 

Linalyl anthranilate- 

Linalyl benzoate 

Linalyl butyrate 

Linalyl cinnaniate- 



Llnalyl formate 

Linalyl isobutyrate 

Linalyl isovalerate — - 

Linalyl propionate 

•Menthol, synthetic, tech 

•Menthol, synthetic, U.S.P 

Menthone — — 

Menthyl acetate 

Menthyl anthranilate 

Menthyl Isovalerate- 

Metahomcnenthol (Cyolonol) 

Metahamomenthyl acetate 

3-Methylcoumarin 

6-Methylcoumarln 

•Methylionones : 

Methyl-a-lonone 

Methyl-p-ionone 

Methylionone Jx- and P-)- 

Nerol 

Neryl acetate — 



•Plperonal (Heliotropin)- 

•Rhodlnol 

Rhodlnol rose- 

Rhodinyl acetate 

Rhodlnyl formate 

Saccharin 



374, 598. 

374, 395, 598. 
461, 514. 

292, 293, 302, 338, 374, 395, 449, 598. 
302, 338, 355, 374, 395, 598. 

338, 355, 374, 395, 598. 

338, 355, 374, 395, 598. 

374, 395, 449, 

338, 374, 395. 

338, 374, 395, 449. 

293, 335, 374, 537. 



395. 

302, 338, 355, 374, 395, 598. 

154, 302, 338, 355, 374, 395, 449, 598. 

395, 598. 

302, 338, 374, 395, 449. 

154, 302, 338, 374, 395, 449, 598. 

302, 374. 

374, 395. 

154, 302, 338, 374, 395. 



395. 

374, 395, 598. 

374, 395. 



293, 338, 374, 395, 537. 

293, 374, 395. 

292, 293, 302, 338, 395, 598. 

395, 537, X. 
537. 



395, 598. 

374, 595, 557. 

125, 132, 302, 338, 374, 395, 449, 598. 
125, 132, 292, 302, 374, 395, 598. 
313. 

313, 395, 598. 

302, 374. 

313, 374. 

302, 338, 374, 395, 598. 

374, 395. 
374. 

374, 395. 

Ul, 302, 355, 395. 

355, 395. 

154, 355, 395, 598, X. 

355, 395. 
395. 

313, 355. 



293, 338, 395. 

293, 338, 374, 395, 537, 598. 

302, 338, 374. 

302, 374. 

374, 395. 
125, 239, 292, 302, 338, 374, 395, 449, 537. 

598. 
302, 338, 374, 395, 598. 

333, 395, 449, 598. 

349. 



SYNTHETIC ORGANIC CHEMICALS, \95U 



119 



TAELE 18B. '-Synthetic organic chemicals: Flavor and perfume materials for which United Stataa 
production or sales were reported, identified by manufacturer, J9J4- -Continued 



Manufaoturere' Identification numliers 
(according to list In table 27) 



FLAVOR AND PKRFOME MATERIALS, CTCLIC — Continued 
Terpenoid, He lerocycl ic, and ytlicycl ic--Contlnued 



Saccharin, calcium ealt- 
Saccharln, sodium salt — 
•Safrole 

Santalol 



Santalyl acetate 

Skatole 

•Terplneols: 

a-Terplneol 

P -Terplneol 

Terplneol (a- and P-) 

Terplnol hjdrate (Terpin hydrate), tech 

♦Terplnyl acetate 

Terpinyl proplonate- 



Tetrahjdropseudolonone 

Trljiiethyl-4-cyolohexene-l-carboiyaldehyde- 
Vetlvenol 



»Vetlvenyl acetate 

FLAVOR AND FERFOME MATERIALS, ACYCLIC 

»Allyl caproate 

Allyl enanthate (Allyl heptanoate) 

Allyl Isothlocyanate (Synthetic mustard oll)- 
Allyl proplonate- 



Allyl sulfide (Dlallyl sulfide)- 

2,3-Butanedione (Blacetyl) 

n-Butyl butyrate 

Butyl butyryllactate 

Butyl levullnate- 



Butyrone (Di-n-propyl ketone) 

Capraldehyde (Deoyl aldehyde) (Cio) 

Caprylaldehyde (Octyl aldehyde) (Cg) 

Deoyl acetate- 



n-Decyl alcohol 

Diethyl sebaoate (Ethyl sebaoate) 

Diethyl succinate 

Dime thy loctanol 

Dodecyl acetate (Lauryl acetate) 

Bnanthaldehyde (n-Heptaldehyde) (C7)- 

•Ethyl butyrate 

Ethyl caprate (Ethyl decylate) 

Ethyl caproate (Ethyl hexoatc) 

Ethyl caprylate (EUiyl oetoate) 

Ethyl enanthate (Ethyl heptylate) 

Ethyl isobutyrate- 
Ethyl isovalerate- 

Ethyl laurate 

Ethyl levulinate- 
Ethyl myristate- 
Ethyl oleate- 



Ethyl pelargonate 

•Glutamic acid, monosodimn salt (Monosodlum 
glutamate ) . 
Hendeoanaldehyde (Undecyl aldehyde) (Cu) 



2-Hendecanone (Methyl nonyl ketone) 

Hendecenaldehyde (Undeoylenlc aldehyde) 

Hendecenoic acid (Undecylenic acid) 

Hendeoenol (Undecylenyl alcohol) 

2,3-Heptanedione (Aoetylvaleryl) 

Heptyl alcohol (Heptanol) 

2,3-Hexanedione (Acetylbutyral) 

3-Hydroxy-2-butanone (Acetoin) 

y-Hydroxycaprylic acid, lactone (Y-Octalactone) 

"V-Hydroxyhendecanoic acid, Y-lactone (Y-Undeca- 

lactone). 
Y-Hydroxypelargonlc acid, lactone (Y-Nonalaotone)- 

"Isoamyl butyrate (Amyl butyrate) 

Isoamyl caproate (Anyl caproate) 

Isoamyl caprylate (Amyl caprylate) 

Isoamyl formate (Amyl formate) 

Isoamyl Isovalerate (Amyl iaovalerate) 

Isoamyl propionate (Amyl propionate) 

Isobutyl butyrate 

Isobutyl caproate 

Isobutyl iaovalerate 

Isopropyl palmltate 



3<19. 






208, 3<19. 






12A, 125, 


374, 


395, 557, 561. 


302, 338, 


395, 


449. 


313. 






31, X. 






31. 






2W, 395, 


598. 




ZlA. 






31, 338, 


374, 


395, 449, 537, 598. 


302, 37<l, 


395. 




395. 






537. 






125, 374, 


395. 




9, 338, 374, 395, 598. 


125, 154, 


302, 


338, 374, 395, 449 


141, 302, 


374. 




141, 480. 






449. 






302, 480. 






141, 240, 


302. 




154, 374, 


449. 




141. 






395. 






374. 






302, 374, 


395. 




302, 374, 


395. 




302, 374. 






374, 395. 






313, 374, 


449. 




313, 374. 






226. 






302, 374, 


395. 




103, 374, 


419. 




3, 125, 302, 374, 449. 


125, 302, 


374, 


449. 


125, 302, 


374, 


449. 


125, 302, 


374. 




302, 374, 


449. 




302, 374. 






125, 302, 


374. 




125, 302, 


374, 


386, 395. 


302, 313, 


338, 


449. 


302, 386, 


395. 




386. 






141, 302, 


374, 


395, 449. 


158, 162, 


385, 


416, 577. 


374. 






374, 395. 






374, 395. 






103, 355, 


419. 




374, 395. 






374. 






103. 






313. 






313, 449. 






302, 395. 






302, 395. 






302, 395. 






125, 141, 


302, 


374, 395, 449. 


125, 302 


374 


449. 


125, 302 


374. 




125, 302, 


374 


395, 449. 


125, 302 


374. 




154, 302 


374 


395, 449. 


125, 154 






154, 302 


374 




154, 302 


338 


374, 395. 


302, 374 






395. 







120 



UNITED STATES TARIFF COMMISSION 



TABLE ISB. '-Synthetic organic chemicals: Flavor and perfume materials for which United State 
production or sales were reported, identified by manufacturer , 1954- -Continued 



Manufacturers' Identification numbers 
(according to list in table 27) 



FLAVOR AND PERFUME MATERIAI^, ACTCLIC— Continued 



Isopropyl pelargonate 

Lauraldehyde (Dodecyl aldehyde) (C12) 

2-Methylhendecanaldehyde ( 2-Me thy Inony lace t- 
aldehyde). 

Methyl hendecanoate (Methyl undecylenate) 

6-Methyl-5-hepten-2-one 

Methyl P-methylthiolpropionate 

Methyl nonenoate (Methyl nonylenate) — ~ — 

Methyl ootynoate (Methyl heptine oarbonate)- 

Myristylaldehyde 

Nonyl alcohol (C9) 

Octenoic acid 

n-Octyl aoetate- 
n-Octyl formate 



n-Ootyl Isobutyrate 

Pelargonaldehyde (Nonyl aldehyde) (C9)- 

2 , 3-Pentaned lone 

2-Propene-l-thiol (Allyl mercaptan) 

Propyl propionate 

Valerolaotone 

CHEMICALLY MODIFIED ESSENTIAL OII^ 



Ethyl oxyhydrate 

Lavandln, aoetylated 

Petltgrain oil, acetylated 

Sassafras oil, hydrogenated — 
Spike lavender, acetylated- 
Vetivert, acetylated 



4^9. 

302, 37A, 395. 

302, 37-;, 395. 

302, 395. 

37-;, 395. 

302. 

302, 355, 395, U9. 

355, 395. 

395. 

374, 395. 

302. 

302, 374. 

Ul, 302, 374. 

302, 374. 

374, 395. 

313. 

302, 4«). 

302, 374. 

395. 



Ul, 154, 292, 302, 449. 

302, 395, 449. 

125, 302. 

395. 

132. 

132. 



SYNTHETIC ORGANIC CHEMICALS, 1954 

Plastics and Resin Materials 



121 



•Synthetic organic cht 
aaiea i 



micals: Plaatics and resin materials for which United States production or 
ere reported, identified by manufacturer , 1954 



[plastics and resin materials for which separate statistics ere given In table 19A are marked below with an 
asterisk (•); chemicals not so marked do not appear In table 19A because the reported data are accepted in 
confidence and may not be published. I*muf ac turers ' identification numbers shown below are taken from table 
27. An X signifies that the manufacturer did not consent to the publication of his identification number 
with the designated product] 



Manufacturers' identification numbers 
(according to list In table 27) 



PLASTICS AND BJESIN MATERIAI^, BENZENOID 



Aniline -formaldehyde reslns- 
"Coumarone-indene resina- 
•Epoxy resins: 

Epichlorohydrln-bisphenol- 



Eplchlorohydrln-phenol 

All other 



•Petroleum polymer and condensation resins 

•Phenolic and other tar-acid resins: 
•Unnodif led : 

•Bisphenol-formaldehyde 

•p-tert-Butylphenol-bisphenol-formaldehyde- 
«p-tert-Butylphenol-formaldehyde 



Cashew nut shell oil type — 

•Cresols-formaldehyde 

"Cresylio acid-formaldehyde- 



Phenol-p-tert-butylphenol-formaldehyde- 

Phenol-cresols-formaldehyde 

Phenol-cresylic acid-formaldehyde 

•Phenol-formaldehyde 



•Phenol -furfural - 



•Resorclnol -formaldehyde 

Xylenols-formaldehyde 

All other 

•Modified: 

•Bisphenol-formaldehyde-roaln- 



•p-tert-Butylphenol-formaldehyde-rosln 

Phenol -formaldehyde, aimoniated 

•Phenol -formaldehyde-aniline 

•Phenol-formaldehyde-rosln- 



•Phenol-formaldehyde, sulfonated- 
All other 

•Phthallc alkyd resins: 
•Unmodified: 

•Phthallc anhydride -glycerol 



•Phthallc anhydride-glycerol -glycol 

•Phthallc anhydride-glycerol -pentaerythritol 



•Phthallc anhydride-glycerol -sorbitol 

•Phthallc anhydrlde-glyool -pentaerythritol 

•Phthallc anhydride-pentaerythritol 

•Modified: 

•Phthallc anhydride-adipio aoid-glycol 

Phthallc anhydride-benzole acid-alcohol, with 
modifiers. 
•Phthallc anhydride-benzole acid-glycerol 

Phthallc anhydride-fumaric acid-alcohol, with 
modifiers. 

•Phthalle anhydride-fumarie acid-glycerol 

•Phthallc anhydride-fumarie acid-glycerol-rosin — 



559. 

44, 176, 584. 

105, 215, 270, 273, 468, 474, 494, 529, 537, 546, 

581. 
245, 273, 314, 567. 
165, 357, 375, 426. 
44, 144, 186, 329, 423. 



269, 283, 468. 

96, 415, 529, 530, 546. 

148, 165, 269, 316, 362, 415, 489, 494, 530, 546, 
581. 

22, 426. 

36, 151, 165, 175, 269, 316, 408, 468, 489, 546. 

22, 57, 66, 68, 97, 165, 217, 269, 316, 432, 546, 
584. 

208, 546. 

208, 468, 589. 

66, 217, 546. 

8, 17, 22, 33, 42, 48, 57, 68, 87, 97, 114, 116, 127, 
151, 165, 175, 203, 208, 217, 224, 255, 264, 269, 
312, 316, 324, 362, 372, 375, 408, 415, 417, 432, 
468, 488, 489, 508, 530, 546, 581, 584, 589, 596, 
600, X. 

66, 165, 224, 408, 426, 489, 546. 

48, 151, 208, 316, 408, 417, 432, 460, 489, 546. 

68, 546. 

175, 208, 269, 489, 546, 584, 589. 

Ill, 148, 157, 196, 214, 296, 415, 489, 494, 530, 

581, 584, 589. 
283, 2%, 316, 406, 415, 417, 489, 494, 530, 581, 

584. 
417, 489. 

151, 165, 208, 432, 546, 534, 589. 
214, 415, 417, 432, 489, 530, 546, 581, 584. 
208, 357, 375, 489. 
165, 291, 375, 417, 489, 546, 589. 



10, 19, 34, 43, 62, 65, 96, 105, 111, 129, 157, 165, 
179, 182, 192, 196, 215, 235, 245, 260, 264, 270, 
271, 273, 283, 296, 314, 365, 377, 381, 400, 405, 
406, 411, 415, 417, 454, 466, 469, 470, 474, 475, 
488, 489, 494, 529, 530, 537, 546, 551, 581, 584, 
589, 597. 

41, 129, 196, 245, 273, 365, 415, 454, 468, 494, 529, 
551, 581, 589. 

10, 19, 34, 62, 65, 96, 105, 129, 165, 192, 245, 260, 
264, 270, 316, 365, 381, 404, 406, 411, 415, 417, 
454, 468, 470, 475, 488, 489, 494, 537, 551, 581, 
584, 589, 597. 

65, 129, 260, 489, 537, 584, 589. 

129, 192, 195, 214, 245, 264, 270, 381, 404, 406, 
411, 415, 466, 468, 474, 475, 488, 489, 494, 529, 
537, 551, 573, 581, 584, 586, 589. 

19, 34, 43, 65, 111, 129, 157, 165, 192, 195, 196, 
245, 264, 270, 271, 273, 314, 381, 405, 406, 411, 
415, 417, 466, 468, 470, 474, 475, 488, 489, 494, 
529, 530, 537, 551, 581, 584, 589, 592. 

214, 260, 417, 466, 474, 488, 489, 494, 537, 581, 
589, 599. 

415, 466, 537, 589. 
195, 270, 468, 474, 537. 

10, 196, 245, 270, 381, 466, 468, 474, 475, 489, 537, 

581, 589. 
%, 192, 270, 415, 494, 592. 

215, 270, 283, 415, 474, 475, 494, 529, 537. 
215, 469, 470, 475, 488, 494. 



122 



UNITED STATES TARIFF COMMISSION 



TABLE i9E. -'Synthetic organic chemicals: Plastics and res 
sales were reported, identified by 



jtateriais for which United States production or 
jfacturer , i954- -Continued 



Mamif ac turers ' Identlfloatlon numbers 
(according to list in table 27) 



PLASTICS AND KESIN MMIRIALS, BENZZNOID— Continued 

»Phthallc alkyd resins — Continued 
•Modified—Continued 

Phthallo anhydride-glycerol, with modifiers 

»Phthalie anhydride-glyoerol-phenol-formaldehyde 
•Phthallo anhydride-glycerol-phenol- 

formaldehyde-rosin. 
•Phthallo anhydride-glyoerol-pentaerythrltol- 

phenol-formaldehyde-rosin. 
•Phthallo anhydride-glycerol-pentaerythrltol- 

rosin. 
•Phthallo anhydrlde-glycerol-rosin 



Phthallo anhydrlde-glyool-pentaerythrltol, with 

modifiers. 
Phthallo anhydride-malelo anhydride-alcohol, 

with modifiers. 
•Phthallo anhydride-^alelc anhydride-glycerol 

•Phthallo anhydride-malelo anhydride-glyeerol- 

pentaerythr 1 tol . 
•Phthallo anhydride-malelo anhydride-glyeerol- 

pentaerythrltol-rosin. 
•Phthallo anhydride-malelo anhydride-glyoerol- 

rosin. 
•Phthallo anhydride-malelo anhydrlde- 

pentaerythritol. 
•Phthallo anhydride-malelo anhydrlde- 

pentaerythritol-rosln or tall oil. 
Phthallo anhydride-pentaerythritol-phenol- 

f ormaldehyde . 
•Phthallo anhydride-pentaerythrltol-rosln or 

tall oil. 

Phthallo anhydride-sebacio acid-pentaerythrltol, 
with modifiers. 

All other 

•Polyester resins: 

Allyl diglyool carbonate and diallyl phthalate 

Phthallo anhydride-malelo anhydride-glyool- 

styrene. 
All other 

•Styrene resins: 
•Polystyrene- 



Styrene-acrylonitrile copolymer- 
's tyrene-alkyd polyester resins: 
•Maleie anhydrlde-styrene- 



*PhthaHo anhydride-glyoerol-pentaerythrltol- 
styrene. 

•Phthallo anhydrlde-glycerol-styrene 

All other 

•Styrene-butadiene copolymer 

•Styrene-divinylbenzene copolymer 

All other 

Toluenesulfonamide resins 



All other benzenoid plastics and resin materials- 

PLASTICS AND HESIN MATERIALS, NONBENZENDID 

Acetone-formaldehyde resins 

Acrylic resins: 

Polybutyl methaorylate — — 



Polymethyl methaorylate- 
All other 



•Aliyd resins (except phthallo): 
•Unmodified: 

Adipio acid esters- 



Fumaric acid esters: 

Fumaric aold-pentaerythritol 

All other 

Malelc anhydride-glycerol 

•Malelc anhydride-pentaerythrltol 

Sebaoic acid -glycerol 

All other 

•Modified: 

Fumaric acid esters: 
•Fumaric acid-glyoerol-rosin or tall oll- 

•Fumarlo aoid-pentaerythritol-rostn 

All other 



468, -475, 494, 537. 

245, 264, 381, 454, 466, 489, 494, 537, 546, 581, 589. 

19, 62, 129, 215, 245, 260, 264, 270, 271, 365, 415, 

466, 469, 475, 489, 494, 551, 581, 584, 589. 
215, 264, 270, 415, 454, 489, 494, 529, 581. 

10, 19, 43, 129, 192, 260, 273, 381, 411, 454, 475, 

494, 573, 581. 
10, 19, 34, 65, 105, 129, 192, 1%, 245, 260, 264, 

273, 381, 406, 411, 415, 417, 466, 469, 475, 489, 

494, 530, 537, 551, 581, 584, 589. 
270, 466, 468, 489, 551. 

260, 342, 365, 415, 474, 489, 494, 529, 530, 581, 

589, 592. 
192, 1%, 245, 264, 270, 342, 365, 381, 415, 469, 

470, 475, 489, 494, 529, 530, 537, 581, 589, 592. 
245, 260, 264, 270, 342, 365, 415, 454, 469, 488, 

489, 494, 519, 530, 537, 573, 581, 589, 592. 
165, 264, 451, 470, 475, 489, 494. 

192, 215, 245, 252, 264, 270, 365, 466, 469, 475, 

488, 489, 494, 581, 589. 
96, 245, 264, 342, 381, 451, 470, 474, 489, 494, 

529, 530, 537, 581, 589, 592. 
96, 195, 215, 245, 264, 342, 451, 475, 488, 494, 

529, 581, 584, 589. 
196, 489, 537. 

10, 62, 96, 105, 111, 129, 157, 214, 245, 270, 271, 
381, 405, 406, 411, 451, 466, 470, 474, 475, 494, 
551, 581. 

365, 468, 475, 537. 

196, 264, 270, 488, 494, 596, 599. 

255, 475. 

245, 375, 417, 468, 477, 546. 

156, 165, 169, 192, 316, 415, 417, 466, 475, 489, 

530, 546, 549, 581, 584, 589. 

161, 208, 335, 432, 460, 489, 497, 546. 
335, 477, 546, 581. 

165, 208, 432, X. 

165, 196, 264, 273, 381, 468, 475, 494, 581. 

196, 273, 417, 466, 468, 489, 537, 581. 

165, 466, 537, 581, 599. 

60, 259, 335, 408, 423, 424, 460, 477, 478, 487. 

335, 357, 375, 415, 417, 530, 581. 

U, 156, 208, 245, 335, 357, 466, 537, 546. 

208, 466. 

312, 384, 468. 



466, 489, 546. 

408, 417, 537. 

147, 417, 468, 475, 537. 

235, 417, 466, 497, 537. 



245, 415, 417, 530, 589. 

192, 260, 474. 

165, 257, 466. 

494, 581, 589. 

192, 260, 264, 494, 581, 584. 

129, 417, 489, 581. 

203, 214, 260, 271, 415, 417, 475, 599. 



215, 283, 406, 415, 417, 466, 470, 475, 489, 494, 

530, 581. 
415, 417, 474, 475, 494, 530, 581, 592. 
466, 470, 474. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



123 



TAELE 19B.- -Synthetic organic chanicets: Plastics and resin materials for which United States production or 
sales were reported, identified by manufacturer, 1954- -Continued 



Manuf acturera ' Identification numbers 
(according to list in table 27) 



PLASTICS AND RESIN MAIERIALS, NONBKNZENOID— Continued 

»Alkyd reslna (except phthallc) — Continued 
•Modified — Continued 

Maleio anhydride esters: 
»Maleio anhydrlde-glycerol-pentaerythrltol- 

rosln. 
•Malelc nnhydrlde-glycerol-rosin 



Maleic anhydride-glycol-rosln 

»Malelc anhydrlde-pentaerythrltol-rosln- 



«Maleic anhydrlde-pentaerythritol-tall oil- 
All other 



All other modified aliyd realna 

Dlcyandlamlde-formaldehyde resins 

Furfuryl resins 

Polyamide (nylon) resins 

Polychloro- and polyfluoroethylene resins 

Polyethylene resins 

Polyterpene type reslns- 



*Roaln and terpene adduct resins: 
Fumarlc acld-rosln 



Maleic anhydride-rosin- 
All other 



*Hosln and tall oil esters, unmodified: 
•Rosin-glycerol 



Rosin-glycerol-pentaerythrltol- 

Rosln-glycol 

»Rosln-pentaerythritol 



Tall oil-pentaeryxhritol- 
All other 



•Silicone resins 

•Urea and melamlne resins: 
•Urea-formaldehyde type: 
•Butylurea-formaldehyde- 
•Urea-formaldehyde 



All other 

•Melamine-formaldehyde type; 
Buty Ime lamine-f ormaldehyde- 

Melamine-formaldehyde 

All other ____^— - 



•Vinyl and vinyl copolymer resins: 
•Polyvinyl acetate—-—— 



Polyvinyl alcohol 

Polyvinyl butyral 

•Polyvinyl chloride and eopolymers; 
Polyvinyl chloride- 



Polyvinyl ehloride-aeetata copolymer- 
All other 



Polyvinyl ohlorlde-vlnylldene chloride copolymar- 

All other 

All other nonbenzenold plastics and resin matarlals' 



129, 316, 406, 415, 475, 489, 494, 530. 

65, 108, 129, 148, 157, 192, 196, 2U, 215, 270, 273, 

2%, 406, 411, 415, 417, 466, 488, 489, 494, 530, 

581, 584. 
179, 195, 214, 494, 529. 
10, 43, 108, 111, US, 196, 2U, 215, 245, 260, 365, 

405, 411, 415, 417, 474, 475, 489, 494, 529, 530, 

551, 581. 
6, 96, 105, 260, 475, 489, 494, 581, 597. 
129, 196, 215, 260, 415, 530, 546. 
96, 165, 466, 494, 581. 
170, 384, 445, 466, 595. 
426, 432. 
385, 537. 

259, 415, 530, 537. 
4%, 504, 537, 562. 
44, 584. 

U8, 214, 215, 415, 417, 466, 470, 489, 494, 529, 530. 
157, 245, 466, 468, 494. 
21A, 271, 312. 

96, 108, 111, 157, 192, 2U, 215, 271, 283, 406, 
415, 468, 474, 475, 489, 530, 581, 584. 

214, 245, 406, 415, 489. 

214, 245, 415. 

6, 105, 108, 21A, 264, 406, 415, 474, 489, 494, 530, 
581, 584, 592. 

192, 245, 385, 406, 470, 489, 494, 581, 584. 

129, 192, 214, 546. 

134, 494, 546, 547, 584, 589. 



175, 196, 208, 417, 466, 537, 581, 584. 

13, 48, 116, 127, 149, 170, 173, 182, 196, 203, 208, 
2U, 224, 235, 254, 273, 408, 417, 418, 432, 465, 
466, 468, 475, 477, 489, 537, 541, 546, 581, 584, 
X, X. 

417, 4«6, 595. 

208, 417, 466, 537, 584. 
208, 432, 466, 475, 489, 584. 
36, 208, 417, 466. 

175, 182, 235, 245, 323, 341, 406, 408, 417, 478, 

489, 537, 541, 562. 
323, 537, 541. 
323, 537, 562. 

208, 259, 335, 398, 424, 477, 487. 

208, 259, 408, 487, 552. 

259, 335, 487. 

259, 335, 487. 

323, 384, 537. 

259, 357, 417, 465, 466, 487, 489, 537. 



124 



UNITED STATES TARIFF COMMISSION 

Rubber-Processing Chemicals 



TABLE 2in. --Synthetic 



rganic chemicals: Rubber-processing chemicals for which United State 
sales were reported, identified by manufacturer, 1954 



[Rubber-processing chemicals for Mhlch separate statistics are given in table 2LA are marked below with an 
asterisk (»); chemicals not so marked do not appear In table 2LA because the reported data are accepted 
in confidence and may not be published. Manufacturers' identification numbers shown below are taken fron 
table 27] 



Chemical 



Manufacturers' identification numbers 
(according to list in table 27) 



RUBBER-PROCESSING CHEMICALS, CYCLIC 

•Accelerators: 

Aldehyde-amines : 

Acetaldehyde-anlllne 

»n-Butyraldehyde-anillne 

a-Ethyl-§-propylacrylanlllde 

Formaldehyde-p-toluldine (Methylene-p-toluldine) 

Heptaldehyde-anillne 

Triethyltrimethylenetriamine 

»Dlthiocarbamic acid derivatives: 

Benzenebls [dimethyldlthiocarbamate] 

Carbon disulf lde-l,l'-methylenedlpiperldlne 

Dibenzyldithiocarbamic acid, zinc salt 

Dibutyldlthiocarbamlc acid, dlphenylguanldine 

salt. 
Dlmethylethylene dlphenyldlthiocarbamlc acid, 
lead salt. 

2,'i-Dlnitrophenyl dimethyldlthiocarbamate 

Plperldlnlum pentamethylenedithiocarbamate 

Piper Idlnium pen tame thylenedithlocarbamlo 
acid, potassium salt. 
Quanidlnes: 

Dioatechol borate, di-o-tolylguanldine salt 

Dlphenylguanldine 

Dlphenylguanldine phthalate 

Di-o-tolylguanidine 

Triphenylguanldine 

•Thlazole derivatives: 

2-Benzothlazyl-N,N-diethylthiocarbafflyl sulfide — 

Bis[N,N '-2(2-benzothlazylthlamethyl)urea] 

N-Cyclohexyl-2-benzothlEizolesulfenamide 

»2,2'-Dithiobis[benzothlazole] (2,2'-Ben20- 
thlazyl disiOfide). 

•2-Mercaptobenzothiazole — 

2-Mercaptoben2othiazole, sodium salt 

2-Mercaptobenzothlazole, zinc salt 

2-Mercaptobenzothiazoline 

N-0xydiethylene-2-beni:othlazolesulfenamide 

Miscellaneous compounds: 

Dlbenzylamlne 

Dl-N-pentamethylenethiuram tetrasulflde 

2-Imidazollne-2- thiol 

Poly-p-dlnltrosobenzene 

p-Quinoned ioxime 

p-Qulnoned loxljne d ibenzoate 

•Antioxidants: 

Aldehyde- and acetone-amines: 

Aeetaldehytle-anlllne hydrochloride 

p-Amlnod Iphenyl-ace tone — — — 

Aniline-acetone, acid derivatives 

Diphenylamlne-aoetone 

Dlphenylamine -acetone -aldehyde 

p-Phenetldlne -acetone 

Phenyl-2-naphthylamlne-aeetcine — — 

All other 

•Amino or hydroxy compounds: 

p,p'-Dlamlnophenylme thane 

2 , 5-Dl-tert-amylhydroqulnone 

2,5-Dl-tert-butylhydroquinone 

p,p'-Dlmethoxydiphenylamlne 

N,N'-Di-2-naphthol-p-phenylenedlamlne 

N ,N' -Dlphenylethylenedlamlne 

N,N'-Diphenyl-p-phenylenedlamine 

N,N'-Diphenylpropylenedlamlne 

Dl-o-tolylethylenediamlne 

Hydroqulnone monobenzyl ether 

p-Hydroxyd Iphenylamlne 

p-Isopropoxydiphenylamine ______ 

p,p'-Isopropylldenedlphenol (p_Di-p-hydroxy- 
phenylpropane ) . 

Oetyldlphenylamlne 

Octyldlphenylamlne , alkylated 

N-Phenyl-1-naphthylamine 

N-Pheiiyl-2-naphthylamlne 

Tetramethyl dlphenylethylenediamine 

Tliiobls[di-Bec-amylphenol) 

i.-i'-Thloblaf^-tert-butyl-n-oresol]) 



-;77, AS7. 

208, 477, 537. 

229. 

537. 

'i77. 

477. 

477. 
208. 
477. 
229. 

229. 

477. 
208. 
537. 



537. 

208, 466. 
208. 

466, 537. 
403. 

517. 
208. 
208. 
208, 424, 466, 477. 

208, 424, 466, 477. 

208, 424, 466, 477. 

424, 466. 

466. 

466. 

477. 
537. 
537. 
537. 
537. 
472. 



477. 
208. 
208. 
477. 
477. 
208. 
477. 
537. 

477. 

208. 

208. 

537. 

487. 

229, 445. 

208, 477, 4«7, 537. 

229. 

229. 

487. 

487, 537. 

487. 

424. 

477. 

487. 

537. 

487, 537. 

445. 

208. 

208. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



125 



TABLE 2m. --Synthetic organic chemicals: Kubber -processing chemicals for which United States producti 
sales were reported, identified by manufacturer, 1954- -Continued 



Manufacturers' Identification numbers 
(according to list In table 27) 



RUBBER-PROCESSING CHEMICALS, CYCLIC—Contlnued 
»Antlo:cldants — Continued 

•Amino or hydroxy compounds — Continued 

p-(p-Toluenesulfonamido) diphenylamlne 

N-o-Tolyl-2-naphthylaiDine 

Miscellaneous compounds: 

Aldol-a-naphthylamine condensation 

Dlcresyl disulfide 

2,2'-Methylenebls[^-ethyl-6-tert-butylphenoJ — 
2 , 2' -Methylenebis l^-me thyl-6-tert-butylphenol] - 

Nonylphenyl phosphites, mixed 

Phenol, alkylated 

Phenol, aliylated-styrenated 

Phenol, styrenated 

2,2,'i-TrliDethyldlhydroqulnoline 

Blowing agents and processing aids: 

Dinitrosopentamethylenetetramine 

p,p'-Oxybls [benzene sulfonhydrazide) 

Tall oil, trllsopropanolamlne salt 

Inhibitors: N-Nltrosodlphenylamlne 

Peptizers: 

o,o '-Dlbenzamldophenyl disulfide 

Dixylyl disulfides, mixed 

2-Na'phthalenethlol (2-Naphthylmercaptan) 

Pentachlorobenzene thiol 

Xylene thiol, zinc salt 

Tacklflers: 

p-tert-Amylphenol sulfide 

Bis [Jso-octylhydroxyphenylmethylene] 

RUBBER-PROCESSING CHEMICAl^, ACYCLIC 

•Accelerators: 

»Dlthiooarbamlc acid derivatives: 

Dibutyldlthlocarbamic acid, dimethyl- 

cyclohexylamlne salt. 
Dibutyldithiooarbamio acid, sodium salt- 



•Dlbutyldlthiocarbamlc acid, zinc salt 

Dlethyldithlocarbamlc acid, selenium salt 

Diethyldlthlocarbamic acid, sodium salt 

Dlethyldithlocarbamlc acid, tellxirlum salt 

•Dlethyldithlocarbamlc acid, zinc salt 

Dlmethyldlthlocarbamlc acid, blsmate salt 

Dimethyldithiooarbamlc acid, copper salt 

Dlmethyldithiocarbamic acid, dlmethylammonlum 

salt. 
Dlmethyldithiocarbamic acid, lead salt 

•Dlmethyldithiocarbamic acid, potassium salt 

Dlmethyldlthlooarbamio acid, selenium salt 

•Dlmethyldithiocarbamic acid, sodium salt and 
sodium polysulfide. 

Dlmethyldithiocarbamic acid, zinc salt 

All other — -- . , . ■- 

Thlurams: 



Tetrabutylthluram monosulf ide — 



Tetraethylthiuram disulfide 

•Tetramethylthiuram disulfide 

•Tetramethylthiuram monosulflde 

Xanthates: 

Di-n-butylxantho dlsulflde- 



Dlisopropylxantho disulfide 

Potassium butyl xanthate 

Sodium butyl xanthate 

Zinc dlbutyl xanthate 

All other 



Miscellaneous compounds: 

n-Butyraldehyde-butylamlne 

Dl-n-butylanmonlum oleate 

•Peptizers, lubricating, conditioning, and blowing 
agents : 

Aliyl meroaptans, mixed- 



Cadmium lauryl mercaptlde- 
•Dodeoyl mercaptans- 



tert-Hexadecyl mercaptan 

Trldecyl mercaptan 

Zinc laurate 

Bloving agents: 

a >a'-Azoblsformamlde ~ 

Urea-biuret mixture 



477. 

487. 

477. 

466. 

466. 

477. 

229. 

487. 

424, 487. 

487. 

537, X. 
477. 
X. 
487. 

466. 
537. 
537. 
537. 
537. 
537. 

517. 
425, 



Lubricating and conditioning agents- 



208 


477, 


537, 


568. 






122, 


424, 


477, 


517, 


537, 


568. 


122, 


517. 










477, 


513. 










122. 












122, 


208, 


424, 


477, 


517, 


568. 


122. 












122. 












477. 












L22. 












156, 


424, 


477, 


517. 






122. 












424, 


477, 


537. 








122, 


477. 










487, 


517. 










477. 












424, 


477, 


517. 








122, 


156, 


208, 


424, 


477, 


487, 517, 537 


208, 


424, 


477, 


537. 






477. 












487. 












477, 












477. 












424, 


477. 










477. 












537. 












156, 


537. 










458. 












259. 












458, 


476, 


517, 


549. 






458. 












476. 












477. 












477. 












494. 












537. 













126 



UNITED STATES TARIFF COMMISSION 

Elastomers (Synthetic Rubbers) 



TABLE 22B. --Synthetic organic chemicals: Elastomers (synthetic rubbers) for which United States production 
or sales were reported, identified by manufacturer, 1954 

[Elastomers (synthetic rubbers) for which separate statistics are given In table 22A are marked below with 
an asterisk (•); products not so marked do not appear In table 22A because the reported data are accepted 
In confidence and may not be published. Manufacturers' Identification numbers shown below are taken frcn 
table 27. An X signifies that the manufacturer did not consent to the publication of Vj Identification 
number with the designated product] 



Product 



Mamifaeturers ' Identification nuijbers 
Caccordlng to list In table 27) 



ELASTOMERS, CYCLIC 
•Polybutadlene-styrene type (Buna 3, (S.S)- 

ELASTOMERS, ACYCLIC 



Polyacrylate ester type — 
Polyalkalene sulfide type (Thiokol)- 



«Polybutadiene-acrylonltrile type (N-type)- 
Polybutadlene type — 



•Polychloroprene type (Neoprene, QR-M) 

•Polylsobutylene-isoprene type (Butyl, CR-1) 

Polyurethane 

•Polyvinyl type 



Reaction products of natural rubbers: 

Cyc lorubber E 

Polymerized chlorinated rubber 

Silicone type 

All other 



52, 80, 113, 156, 259, A2A, *34, 458, 476, 477, 487, 
603, 604. 



487. 

522. 

259, 362, 424, 477, 487. 

424. 

537. 

285, 423. 

388, 424, 477. 

208, 487, 562. 

424. 

214. 

134 X. 

259^ 423, 537, X. 



Plasticizers 



TABI^ 23B. --Synthetic organic chemicals: Plasticizers for which United States production or sales were 
reported, identified by manufacturer, 1954 

[Plasticizers for which separate statistics are given in table 23A are marked below with an asterisk (•); 
products not so marked do not appear in table 23A because the reported data are accepted in confidence and 
may not be published. Manufacturers' identification numbers shown below are taken from table 27. An X 
signifies that the manufacturer did not consent to the publication of his identification number with the 
designated product] 



Manufacturers' identification numbers 
(according to list in table 27) 



PLASTICIZZRS, CYCLIC 



Camphor, synthetlc- 
Coumarone-lndene plaatielzer- 
N-Cyclohexyl-p-sulfonamide — 
Dibenzyl sebacate 



Diethylene glycol dlbenzoate 

Dl-tert-ootyldiphenyl oxide 

Diphenyl cyclohexyl, o-, m-, p- — 

Dlpropylene glycol dlbenzoate 

N-Ethyl-p-toluenesulfonamlde 

Isoprop 'lidenedlphenojtypropanol 

Naphthalene, alkylated 

Phenoxyath;.'! oompounds 

Phosphoric acid esters: 
Cresyl diphenyl phosphate- 



Diphenyl mono-o-xenyl phosphate — 
Diphenyl octyl phosphate- 



Trl(p-tert-butylphenyl) phosphate — 

»Trioresyl phosphate 

•Trlphenyl phosphate — ..-- .. — 

Polyoxyalialene phenol — ■ 

Phthalic anhydride esters: 

Butyl benzyl phthalate- 



Butyl cyclohexyl phthalate 

Butyl decyl phthalate 

Butyl octyl phthalate 

Butyl phthalyl butyl glycolate 

Castor oil phthalate, hydrogenated 

Dlallyl phthalate 

Diamyl phthalate 

Dl(2-butoxyethyl) phthalate (Dl(2-butyl 
cellosolve) phthalate). 
«Dibutyl phthalate 



537. 
176. 
208. 
139. 
199. 
335. 
208. 
199. 
208. 
335. 
144. 
257. 

208. 

335. 

208. 

335. 

169, 172, 208, 580. 

169, 208, 335, 513. 

257. 

208. 

584. 

128, 389, 584. 

562. 

208. 

537. 

172, 567. 

415. 

172, 386, 537. 

128, 133, 139, 172, 208, 213, 245, 290, 389, 415, 
478, 494, 495, 537, 580, 534. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



127 



TABLE 23B. --Synthetic orianic chemicals: Plasticizera for which United Statea production or aalea mere 
reported, identi tied by manufacturer , 1 954-. Continued 



Manufacturers' Identification numbers 
(according to list in table 27) 



PLASTIC IZERS, CYCLIC — Continued 



Phthallc anhydride eaters — Continued 
«Dlcapryl phtbalate- 



Dicyclohexyl pbthalate 

Dldeoyl phtbalate 

Dl(2-(2-ethoxyBtlioxy)etliyl) phthalate (Dicarbltol 
pbthalate ) . 

Dl(2-ethylbutyl) pbthalate 

•Diethyl pbthalate 

Dlhexyl pbthalate- 



Dlisobutyl pbthalate 

Diisodecyl pbthalate 

•Di(2-metboxyethyl) pbthalate (Di(metbyl cello- 
solve) pbthalate). 

"Dimethyl pbthalate 

Dinonyl pbthalate 

»Dioctyl phthalates: 

•Di(2-ethylhexyl) pbthalate 



«Dliso-octyl pbthalate- 



»Dl-n-octyl pbthalate and mirtures- 

Dlphenyl pbthalate 

Ethyl phtbalyl ethyl glyeolate 

Isobutyl castor oil pbthalate 

Iso-ootyl capryl pbthalate 

Methyl phtbalyl ethyl glyeolate 

«Octyl decyl pbthalate 

All other phthallc anhydride estera- 

Tetrahydrofurfuryl oleate 

Toluenesulf onBTTiide , o-, p- mixture 

All other cyclic plasticizera 



PLASTICIZERS, ACYCLIC 

Adipic acid esters: 

Di(2-(2-butoxyetboxy)ethyl) adipate (DiCbutyl 

carbitol) adipate). 
Di(2-butoxyetbyl) adipate (Di(butyl cellosolve) 

adipate). 
Didecyl adipate- 

•Di(2-ethylhejgrl) adipate 

Diisoamyl adipate 

Diisobutyl adipate 

»Dilso-octyl adipate 

Dinonyl adipate 



Dipropyl adipate- 
n-Octyl decyl adlpate- 
All other 



Azelaic acid esters: 

Di(2-ethylbutyl) azelate- 
Di(2-ethylhex7l) azelate- 
Diiaobutyl azelate 



Dliao-octyl azelate- 
All other 



2-Butoxyethyl diglycol carbonate — • 

Butyl myristate 

Castor oil maleate 

Citric and acetylcltric acid esters — — 

Di(butoxyetboxyethyl) methane 

Dibutyl tartrate 

Dieapryl diglyeolate- 



Diethylene glycol dlpelargonate 

Dietbylene glycol ester of coconut oil fatty acid- 
Glyceryl dlacetyl tartrate monoesters- 
Glyceryl tributyrate (Tributyrln)- 

Glyceryl trlproplonate 

Isobutyl maleate 

Isopropyl myristate _________ 

•Laurie acid esters: 

2-Butoxyethyl laurate (Butyl cellosolve laurate) 

Butyl laurate ' 

Methyl laurate 

•Oleic acid esters: 

2-Butoxyethyl oleate (Butyl eellosolTe oleate) — 

Butyl oleate 

Dimetbylamine oleate- 



Glyceryl trioleate (Trioleln)- 

Methyl oleate 

n-Propyl oleate 



139, 172, 389, A17, 58*. 

172, 537, 584. 

213, 441, 535. 
172. 

495. 

208, 2W, 396, 415, 495, 584. 

139, 256. 

495. 

172, 208, 584. 

172, 386, 495, 537. 

208, 3%, 495, 537, 584. 
389, 441, 535. 

128, 133, 139, 172, 213, 389, 441, 478, 494, 495, 

535, 537, 562, 580, 584. 
128, 133, 139, 172, 208, 213, 214, 245, 389, 441, 

478, 4*^, 495, 535, 584. 
208, 213, 487, 584. 
208. 
208. 
537. 

213, 245. 
208. 

133, 172, 208, 213, 2U, 389, 441, 535, 562. 
172, 213, 386, 441, 495, 535, 537. 
389, 467. 
208. 
172, 517. 



522. 






172, 537. 






172, 441, 


535. 




172, 389, 


495, 


562. 


417. 






139, 495, 


535. 




133, 139, 


172, 


208, 213, 389, 417, 441, 535 


389. 






386. 






172, 213, 


2i>;. 




172, 213, 


487, 


562. 


467. 






213, 441, 


467, 


495. 


371, 386, 


495. 




245, 441, 


535. 




386, X. 






475. 






369. 






417. 






415, 495. 






522. 






386. 






172. 






467. 






188, 456. 






456. 






495. 






495. 






495. 






9, 369. 






371, 386. 






386. 






258, 386. 







371, 386. 

128, 172, 235, 369, 386, 388. 

417. 

188, 345, 386, 467, 482. 

369, 386, 388, 467. 

345, 467. 



128 



UNITED STATES TARIFF COMMISSION 



TABLE 23B.--Syntheti 



rganic chemicals: Plasticizers for which United States producti 
reported, identi fied by manufacturer , i954- -Continued 



Manufacturers' identification numbers 
(according to list In table 27) 



PUSTICIZERS, ACYCLIC— Continued 

•Oleic acid esters — Continued 

Trlethanolamlne oleate- 

All other 

Palmltlo acid esters: 

Isobutyl palmltate 

Isopropyl palmltate 

Methoxyethyl palmltate- 

Methyl palmltate 

Octyl palmitate- 
Phosphorlc acid esters: 

Trl(2-butoxyethyl) phosphate (Trl{butyl 
cellosolve ) phosphate ) . 

Trlbutyl phosphate 

Triethyl phosphate — 



Trlisobutyl phosphate — 

Trloctyl phosphate 

Polyethylene glycol-dl-2-ethylhexoate 

Polyethylene glycol ester of soybean oil fatty 

acid. 
Riclnolelc and acetylrlcinolelc acid esters: 

n-Butyl acetylrioinoleate 

Butyl rloinoleate- 



Glyoeryl monorloinoleate- 

Glyceryl trlacetylricinoleate 



2-Methoxyethyl acetylrlclnoleate (Methyl 
cellosolve acetylrlclnoleate). 

Methyl acetylrlclnoleate 

Methyl riclnoleate 

All other ■ 

Sebaclc acid esters: 

Dlamyl sebacate 

Dl(2-butoxyethyl) sebacate (Dl{butyl cellosolve) 
sebacate). 

»Dlbutyl sebacate 

»Dl(2-ethylhe3cyl) sebacate 

Diiso-octyl sebacate- 



Dtmethyl sebacate 

Polyethylene glycol 2-ethyLhexyl sebacate- 
All other ■ ' ' ■ 



Stearic acid esters: 

2-Butoxyethyl stearate (Butyl cellosolve 

stearate). 
Butyl Etearate- 



Dlethylene glycol dlstearate 

Dimethylammonluni stearate 

2-Ethylhexyl stearate 

Glyceryl monohydroxystearate 

Glyceryl trlstearate (Trlstearln)- 

Methyl dichlorostearlc acid 

Methyl pentachlorostearate 

An other- 



Triethylene glycol dl(caprylate-caprate) 

Trlethylene glycol di-S-ethylbutyrate 

Trlethylene glycol di-2-ethylhexoate 

All other acyclic plasticizers — — 



345, 


417, 






172, 


386, 


417. 




-495. 








369. 








-495. 








258. 








133. 








172. 








172, 


290. 






-495. 








495. 








562. 








562. 








4i41, 


482. 






103. 








103, 


441. 






81, 


103, 


188, 


371, 386, 388. 


103. 








103, 


441. 






103. 








103, 


388. 






103, 


371, 


386 


441, 


417. 








4^1. 









139, 213, 371, 389, 417, 495. 

139, 2L3, 389, 417, 441, 478, 495. 

133, 139, 389, 417. 

139, 310. 

213. 

139, 213, 371, X. 

172, 369, 386. 



139, 172, 290, 345, 369, 386, 388, 441. 
386. 



L28, 
235, 
417. 
172. 
388. 
482. 
549. 
549. 
369, 
133, 
562. 
562. 
214, 258, 336, 417, 562, X. 



386, 441, 456, X. 
258, 482. 



SYNTHETIC ORGANIC CHEMICALS, 1954 

Surface-Active Agents 



129 



TABLE 24B. --Synf/iefic organic chemicals: Surface-active agents for which United States production or sale 
were reported, identified by manufacturer, 1954 

[Surface-active agents for which separate statistics are given in table 2<iA are marked below with an aster- 
isk («); products not so marked do not appear In table 7Ak because the reported data are accepted in con- 
fidence and may not be published. Manufacturers' identification numbers shown below are token from table 
27. An X signifies that the manufacturer did not consent to the publication of his Identification number 
with the designated product] 



Manufacturers' identification numbers 
(according to list In table 27) 



SDRFACE-ACIIVE AGENTS, CYCLIC 

•Esters and ethers, nonsulf onated : 

Amylphenoxy polyethoxyethanol 

Anhydrohexitol castor oil polyoxyalkylene ether 

Anhydrohexitol dilaurate polyoxyalkylene ether 

Anhydrohexitol dioleate 

Anhydrohexitol glycerol monola'jrate 

Anhydrohexitol monolaurate 

Anhydrohexitol monolaurate polyoxyalkylene ether 

Anhydrohexitol mono-oleate 

Anhydrohexitol mono-oleate polyoxyalkylene ether 

Anhydrohexitol monopalmitate 

Anhydrohexitol monopalmitate polyoxyalkylene ether- 

Anhydrohexitol monostearate 

Anhydrohexitol monostearate polyoxyalkylene ether — 

Anhydrohexitol sesqul-oleate 

Anhydrohexitol tall oil polyoxyalkylene ether 

Anhydrohexitol tetrastearate 

Anhydrohexitol trioleate 

Anhydrohexitol trioleate polyoxyalkylene ether 

Anhydrohexitol triricinoleate 

Anhydrohexitol triricinoleate polyoxyalkylene ether 

Anhydrohexitol tristearate 

Anhydrohexitol tristearate polyoxyalkylene ether 

Diisobutylphenoxy polyethoxyethanol 

Dlpropylene glycol salicylate 

Glucose polyoxyalkylene distearate 

Glucose polyoxyalkylene ether polyoxyalkylene 

oleate. 

Glucose polyoxyalkylene oleate 

Iso-octylphenoxy polyethoxyethanol 

•Nonylphenoxy polyethoxyethanol 

n-Octylphenoxy polyethoxyethanol 

Tetradecylphenoxy polyethoxyethanol 

•Nitrogen-containing surface-active agents, 

nonsulf onated : 

N-Alkylethylmorpholinium ethosulfate 

Benzyloetyldimethylammonium chloride 

Benzyldimethyloctylammonlum chloride 

Benzyldimethylphenylammonium chloride 

l-(l-Benzyl-l-hydroxyethyl)-2-tridecylimldazoliniujn 

chloride. 

•Benzyllauryldimethylammonium chloride 

Benzylpolyethoxy coconut oil ammonium chloride 

Benayltrimethylammonlum chloride 

Benzyltrimethylammonium hydroxide 

Caprylethyl-5-hydroxycyclolmidine-sodium ethylate , 

sodium ethionate. 

Cetylpyridinium chloride 

3,>i-Dichlorobenzyllauryldimethylanmonium chloride — 
l,l-Dihydroxyethyl-2-heptadecenylimidazoJ-lnium 

chloride. 

Dodecylmet'hylbenzyltrimethylammonium chloride 

Ethanol diphenylethylenediamine 

Ethoxybenzyldimethyloctylphenoxyanimonlua chloride — 

2-Heptadecyl-l-hydroxyethyl-2-imIdazollne 

2-Lauroyloxyethylcarbamylmethylpyridinlum chloride 

(Lauryl ester of colaminoformylmethylpyridinium 

chloride) . 

Lauryldimethylbenzyldimethylammonlum chloride 

Laurylethyl-5-hydroxycyclolmidine, sodium ethylate, 

sodium ethionate. 

Laurylpyridinium chloride 

Mixed fatty acid imidazolines 

Oleyl imidazoline 

Oxazoline, substituted 

Rosin amlnopolyethoxyethanol 

Rosin soap of polyamidoimidazoline 

Stearoylethyl-5-hydroxycyc lolmidine , sodium 

ethylate, sodium ethionate. 
Stearyl imidazoline 



456. 

257. 

257. 

257, 593. 

257. 

257. 

257. 

257, 4B6. 

257. 

257. 

257. 

257. 

257. 

257. 

257, 4S6. 

257. 

257. 

257. 

257. 

257. 

257. 

257. 

384. 

X. 

257. 

384. 



257. 










384, 


388, 


417. 






234, 


257, 


321, 


384, 


486, X. 


486, 


562. 








431. 










257. 










235, 


247, 


417, 


501. 




235. 










384. 










595. 










107, 


223, 


2ii, 


473, 


486, 501 


384, 


417. 








290, 


431. 








501. 










90. 










141, 


501. 








235, 


247, 


473, 


501. 




595. 










417, 


501. 








77. 










417. 










595. 










456. 










473, 


501. 








90. 










501, 


549. 








137. 










465, 


593. 








290. 










384, 


486. 








478. 











130 



UNITED STATES TARIFF COMMISSION 



TABL£ 2Ali. --Synthetic organic chemicals: Surface -active agents for which United States production or sales 
fere reported, identified by manufacturer, 1954- -Continued 



SURFACE-ACTIVE AGENTS, CYCLIC— Continued 

»Nitrogen-oontalnlng surface-active agents, 
nonsulfonated — Continued 

Stearyloxyethylcarbamyljiiethylpjrrldlnluni chloride 

2-Undecyl-l-hydroxyethyl-2-lmida2ollne 

N-Xylol stearamlde 

•Sulfated and sulfonated cyclic surface-active agents: 
» tlVy l benzenoid compounds, sulfated and sulfonated: 

Decylbenzenesulfonlc acid type 

Didodecylbenzenesulfonlc acid type 

•Dodeeylbenzenesulfonlc acid type 



Dodecylbenzenesulfonlc acid, butylammonium salt — 

Dodeoylbenzenesulfonlo acid, calcium gait 

Dodecylbenzenesulfonlc acid, Isopropylammonium 

salt. 
Dodecylbenzenesulfonlc acid, triethanolamine salt 

Dodecyltolueneeulfonic acid type 

All other 

»Llgnln derivatives, sulfonated: 

Calcium llgnosulfonate 

Magnesium lignosulfonate 

Sodium lignosulfonate 

•Naphthalene derivatives, sulfonated: 

Benzylnaphthalenesulfonic acid, mono— — 

Butylisopropylnaphthalenesulfonlc acid, sodium 

salt. 
•Butylnaphthalenesulfonic acid, mono— 



•Dlanylnaphthalenesulfonlc acid 

•Dlbutylnaphthalenesulfonic acld- 

•Dlisopropylnaphthalenesulfonlc acid — — — 

•Isopropylnaphthalenesulfonic acid, mono 

1 , 1' -Methylenebis ( 2-naphthalenesulf onlc ac id ) 

Mixed alkylated naphthalenesulfonlc acid 

Octylnaphthalenesulfonic acid — 

OleylnaphthalenesxU-fonlc acid ~ 

Tetrahydronaphthalenesulfonic acid 

•Petroleum aromatic compounds, sulfonated: 

•Ac Id-layer- type petroleum sulfonate, sodium salt- 

Oil-layer-type petroleum sulfonate 

Oil-layer- type petroleum sulfonate, ammonium salt 
Oll-layer-type petroleum sulfonate, barium salt — 
Oil-layer-type petroleum sulfonate, calcium salt- 
Oil-layer-type petroleum sulfonate, lead salt 

•Oll-layer-type petroleum sulfonate, sodium salt — 

•All other sulfated and sulfonated cyclic surface- 
active agents: 
Butylbiphenylsulfonlc acid 

Butylhydroxyhiphenylsulfonlc acid 

N-Cyclohexylpalmltoyl taurine 

Dlbutylhydroxyblphenyldlsulfonic acid 

N,N-Dlethylcyclohexylamlne salt of lauryl sulfate 

Nonylphenoxypolyethoxyethyl sulfate 

Octylphenoxypolyethoxyethyl sulfate 

Octylphenoxypolyethoxyethyl sulfonate 

Toluene sulfonate, sodium salt 

Trlchlorophenol ethanolamlne sulfate 

Xylene sulfonate, sodium salt 



SURFACE-ACTIVE AGENTS, ACYCLIC 

•Esters and ethers, nonsulfonated: 

Diethylene glycol ester of tall oil fatty acld- 

•Diethylene glycol monolaurate 

•Diethylene glycol mono-oleate ~ 

•Diethylene glycol monostearate- 



Manufacturers' Identification numbers 
(according to list in table 27) 



Dilsobutylene maleate, sodium salt — — 

Dipolyethoxyethyl ether of polyoxypropylene glycol- 
Ethylene glycol mono-oleate 

Ethylene glycol monostearate 

Glyceryl maleate mono-oleate 

Glyceryl mono and di esters of mixed fatty acids 

Glyceryl monococate 

Glyceryl monoester of lard 

Glyceryl monolaurate 

•Glyceryl mono-oleate 



456. 
595. 
A81. 



35, 208, A81. 

213. 

A7, 56, 59, 69, 112, 182, 189, 208, 257, 291, 30<;, 

321, 326, 328, 403, 439, 445, 465, 481, 490, 564, 

571, 574, 593, X, X. 
208, X. 
469. 
465, 469, X. 



330, 369. 






559, 593. 






101, 428, 


579. 




428. 






428. 






384. 






268. 






345, 455, 


559. 




182, 465, 


595. 




321, 384, 


465, 


595. 


213, 235, 


384, 


388, 478, 481, 537. 


360, 403, 


466, 


537. 


445, 537. 






137, 482, 


491. 




77. 






328. 






537. 






20, 391, 


450, 


479, 544. 


20, 544. 






450. 






439, 450, 


466. 




450, 518. 






564. 






20, 30, 231, 297, 391, 417, 439, 450, 479, 518, 555 


564, 588. 




208. 






208. 






384. 






208. 






537. 






384, 571. 






69, 417. 






417. 






481. 






384. 






469, 481. 







182, 456. 

81, 371, 386, 388, 588. 
81, 386, 388, 456, 467. 

9, 47, 81, Ul, 182, 188, 371, 386, 388, 456, 553, X. 
417. 
574. 

371, 593. 

9, 188, 371, 386, 469, X. 
456. 

59, 171, 257, 456, 545, X. 
371, X. 
482. 

81, 371, 386. 

81, 188, 257, 371, 386, 388, 467, 469, 482, 533, 
588, 593, X. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



131 



TABLE 24B. -Synthetic organic chemicals: Surface-active agents for which United States production or aalea 
were reported, identified by manufacturer , 19J<--Continued 



MnruTacturera' Identlf lotion numbers 
(according to list in tatle 27) 



SOTTACl-ACTIVB AOENTS, ACTCLIC — Continued 



•Esters and ethers, nonsulfonated — Continued 
•Glyceryl monoetearate- 



Hexltol polyoxyaliylene 'beeswai ester- 
Hexltol polyoxyalkylene dloleate- 



Hexltol polyoxyalkylene fatty acid ester 

Hexltol polyoxyalkylene heialaurate 

Hexitol polyoxyalkylene hexaoleate 

Hexltol polyoxyalkylene hexastearate 

Hexitol polyoxyalkylene liexa(tall oil) eater — 

Hexltol polyoxyalkylene lanolin ester 

Hexitol polyoxyalkylene oleate _________ 

Hexitol polyoxyalkylene pentalaurate 

Hexitol polyoxyalkylene penta(tall oil) ester — 
Hexitol polyoxyalkylene tetra(oleate, laurate) 

ester. 
Hexitol polyoxyalkylene tetra(tall oil) ester — 

Methoxypolyethoxyethyl coconut oil ester 

Polyethoxyetliyl castor oil ester 

Polyethoxyethyl coconut oil ester 
Polyethoxyethyl decyl ether 

•Polyethoxyethyl dllaurate 

•Polyethoxyethyl dloleate- 



•Polyethoxyethyl distearate 

Polyethoxyethyl tert-dodeoyl thioether- 
Polyethoxyethyl lauryl ether- 



Polyethoxyethyl mixed fatty acid ester_ 

•Polyethoxyethyl monolaurate 

•Polyethoxyethyl mono-oleate 



Polyethoxyethyl monopalmltate 

Polyethoxyethyl monorioinoleate- 
•Polyethoxyethyl monostearate 



Polyethoxyethyl oleyl ether 

Polyethoxyethyl rosin ester 

Polyethoxyethyl soybean fatty acid ester- 

Polyethoxyethyl tall oil ester 

Polyethoxyethyl tallow ester 

Polyethoxyethyl tridecyl ether 

Polyglyceryl oleate 

Polyoxyalkylene castor oil ether 

Polyoxyalkylene fatty acid ester 

Polyoxyalkylene glycollate 

Polyoxyalkylene lanolin ether 

Polyoxyalkylene resin ester 

1,2-Propylene glycol monococate 

1,2-Propylene glycol monolaurate 

1,2-Propylene glycol mono-oleate 

•1,2-Propylene glycol monostearate- 



Propylene glycol polyoxyalkylene stearate 

Propylpolyethoxyethyl ether of polyoxypropylene 

glycol. 
•Nitrogen-containing surface-active agents, non_ 

sulfonated: 

Aliylamlno polyethoxyethanol 

Aliylsulfoamidoacetlc acid, sodium salt 

N- ( Amlnoethyl ) -N- ( hydroxye thyl ) oleajnide (Oleamide 

of amlnoethylethanolamine). 
•N- (Amlnoethyl) -N- (hydro xye thyl) stearamlde 

(Stearamlde of amlnoethylethanolamine). 
Cetylbetalne- 



Cetylethyldlmethylammonium bromlde- 
Cetyl, lauryl trlmethylammonium bromide — 
Cetyltrlmethylanmonium acetate- 
Cetyltrimethylammonlum bromide- 



Cetyltrimethylammonium stearate 

Coconut oil amide of aminoethylethanolamlne- 

•Cooonut oil amide of mono(dlethanolajnlne) 
(Dlethanol lauramlde). 

•Coconut oil amide of bls(diethanolamine) 



•Coconut oil amide of diethanolamlne (neither bis 
nor mono). 

•Coconut oil amide of diethylenetriamine 

Coconut oil amide of dllsopropanolamlne 

Coconut oil amide of isopropanolamine — 



Coconut oil amide of monoethanolamlne (Sthanol 
lauramlde ) . 

Coconut oil trimethylaramonlum chloride 

Decylbetaine 

Dlooconut oil dlmethylammonlum chloride 

Diethanolamlne, coconut oil ester 



3, 9, 81, Wl, 188, 328, 371, 386, 388, 482, X. 

257. 

257. 

257. 

257. 

257. 

47, 257. 

257. 

257. 

257. 

257. 

257. 

257. 

257. 

47, 386. 

384, 456, 595. 

112, 328, 593. 

257. 

81, 235, 301, 371, 386, 595. 

348, 371, 386, 388, 445, 553, 593, 595. 

81, 371, 386, 553, X. 

208, 517, 593. 

182, 257, 537, 571. 

182, 268, 553. 

81, 334, 348, 371, 384, 386, 388, 470, 482, 553, 595. 

81, 235, 256, 257, 348, 371, 384, 386, 388, 445, 482, 

553, 593, 595. 
24, 257. 
386, 388. 
47, 81, 107, 235, 257, 301, 348, 371, 384, 386, 388, 

417, 482, 545, 553, 595, X. 
257, 321, 384, 537, 571. 
X. 
235. 

15, 47, 77, 182, 208, 234, 257, 384, 388, 456, 593. 
373, 445, 593. 
257, 593. 
456. 
486. 

9, 257, 486. 
486. 

234, 257. 
257, X. 
X. 

257, 371, 386, 482, X. 
371, 386, 495. 
188, 328, 371, 386, 456, X. 
257. 
574. 



486. 
384. 
2, 388, 481. 

2, 47, 59, 170, 171, 182, 235, 254, 326, 345, 369, 

388, 445, 481. 
501, 537. 
501. 
537. 
501. 
501. 
501. 

47, 69, 171, 388, 469. 
2, 9, 112, 171, 212, 221, 235, 301, 326, 328, 388, 

445, 456, 469, 481, 490, 593, 595, X. 
47, 95, 170, 182, 334, 388, 465, 481, 516. 
35, 59, 69, 482, 571, X. 

77, 388, 469. 

X. 

170, 469, 481, 571. 

47, 77, 170, 235, 321, 326, 328, X. 

333. 
537. 
333. 
321. 



132 



UNITED STATES TARIFF COMMISSION 



TABLE 24Ti. -Synthetic organic chemicals: Surface-active agents for which United States production or sales 
were reported, identified by manufacturer, 1954- -Continued 



Manufacturers' identification numbers 
(according to list in table 27) 



SUHFACE-ACTIVK AGENTS, ACYCLIC— Continued 

•Nitrogen-containing surface-active agents, non- 
sulfonated — Continued 
Diiydrogenated tallow dlmethylaramonluni chlorlde- 

N,N-Di(2-hydro}£yethyl)biaoleamlde 

N,N-Di(2-hydroxyetliyl)capramide 

N,N-Dl(2-hydroxyethyl)laurainide (Diethanolamlne 
laurate ) . 
•N,N-Dl(2-hydro)!yethyl)oleamlde (Diethanol 

oleamide). 
•N,N-Dl(2-hydroxyethyl)stearandde (Diethanol 
stearamlde) . 

DilaurylannnonluDi bromide 

N-Dodecyl-P-alanlne, sodium salt 

Dodecyltrlmethylammonlum bromide 



Dodecyltrlmethylajmnonlum chloride- 
Dodecyltrlmethylammonium tosylate- 

N,N-Ethylene bisoleamlde 

NjN-Ethylene bis-stearamide 

N-(2-Hydro)cyethyl)aiyrlstamide (Ethanol 

myristamide). 
N-(2-Hydroxyetliyl)oleamlde (Ethanol oleamlde)- 
N-(2-Hydroxyethyl) stearamlde — 



N-(Hydroxyme thyl ) stearamlde (Me thylolstearamide ) — 
N-(2-Hydroxypropyl)oleamlde (Isopropanol oleamide) 

Laurie, myristic diethanolamlne 

N-Lauroyl Isopropanolamide 

N-Lauroylpolypeptide 

N-Lauroylsarcosin 

Octadecylethyldimethylammonlum bromide 

Octadeoylguanidine carbonate and octyldecylamlne- 

ethylene oxide addition product. 

Oc tadeeyl tr ime thylnrmnonium bromide 

Octadecyltrlmethylaramonium chloride 

Oleamide of diethylenetetramine 

Oleylamlno polyethoxyethanol 

Oleylbiguanlde hydrochloride 

Oleylpolypeptlde 

N-Oleylsarcosin (N-Methyloleoylglycine), sodium 

salt. 

Palm oil amide of amlnoethylethanolamine 

Polyethoxyethanol mixed fatty amides and amines 

Polyethoxyethyl casein 

Soybean oil acyl chloride salt of sodium 

lysalbinate. 
Soybean oil diethyltriamine-ethylene oxide 

addition product, ammonium salt. 

Soybean oil trimethylammonium chloride 

•Stearamlde of dlethylenetrlamine 

Stearamlde of tetraethylenepentamlne 

1-Stearamido-l' -adipoamldo diethyleneamlne 

1-Stearamido-l' -sebaoamido dlethylenedlamine 

Stearic acid ester of N-(2-hydroxyethyl) 

stearamlde. 
N-Stearoylsarcosln, sodium salt — 

Stearylamido polyethoxyethanol 

Stearylamlno polyethoxyethanol 

Stearylblguanide hydrochloride 

Tallow amide of diethanolamlne 

Tallow trimethylammonium chloride- 



Tetraiis (hydroxyethyl polyoxyethylene- 
polyoxypropylene ) e thylenedlamlne . 

Triethanolamine, coconut oil ester 

Triethanolamine llnoleate 

Triethanolamine oleate — 

Triethanolamine atearate 

Trihexylammonium sulfotricarballylate 

Trimethylstearylammonium bromide — 



•Phosphorous-containing surface-active agents, 
nonsulf onated : 

Allcyl polyphosphates, mixed, sodium salt 

Capryl, octyl phosphate 

Decyl phosphate, triethanolamine salt 

Ethylhexyl phosphate, sodium salt 

Mixed mono- and dialkyl acid phosphates 

Mixed mono- and dialkyl acid phosphates, 
diethanolamlne salt. 

Octyl polyphosphate, sodium salt 

Stearyl phosphate, triethanolamine salt 



333. 

595. 

3^8, AA5, 537, 553. 

188, 345, 348, 456, 469, 505, 595. 

47, 77, 321, 388, 465, 469, 481, 595. 

235. 

487. 

537. 

333. 

501. 

188. 

188, 595. 

456. 

170, 388. 

469. 

537. 

456. 

X. 

595. 

293. 

384, 465, 595, X. 

501. 

466. 

537. 

333. 

2. 

384. 

384. 

293. 

384. 

345. 

137, 234, 384. 

384. 

293. 

58, 384. 

384. 



2, 77, 170, 182, 235, 360, 369, 445, 542. 

171, 235, 369. 

77. 

77. 

456. 

384. 
257. 
257. 
384. 
328. 
333. 
574. 

469. 

470. 

348, 445, 470, 536. 

24, 371, 542. 

384. 

537. 



307. 

171, 307. 

69. 

562. 

537. 

537. 

307. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



133 



TABLE 2'4B. --Synthetic organic chemicals: Surface-active agents for which United States production or sales 
were reported, identified by manufacturer, J9J4- -Continued 



Manufacturers' identification numberB 
(aooordlng to list in table 27) 



SOHFACK-ACTIVE ACZNTS, ACYCLIC— Continued 



»Salts of fatty acids, nonsulfonatedi 
Castor oil, potassium salt 



•Coconut oil, potassium salt- 
Corn oil, potassium salt 

Com oil, sodium salt- 



Mixed fatty acids, calcium salt 

Mixed vegetable oils, potassium salt- 
Olive oil, sodium salt 

•Potassium laurate 

•Potassium oleate 



Potassium restnate- 
•Potassium atearate- 
•Potassium tallate — 

Sodium oleate 

•Sodium stearate 

Sodium tallate 



Soybean oil, potassium salt- 
Tallow, potassium salt 

Tallow, sodium salt- 



•Sulfated and sulfonated acyclic surface-active 
agents : 
•Acids, sulfated and sulfonated: 
Acetylolelc acid, sulfonated- 



Coconut oil fatty acids, sulfonated- 
Fish oil fatty acids, sulfonated- 



•Oleic acid, sulfonated (Sulfonated red oil)- 



Ricinolelc acid, sulfonated- 



Soybean oil fatty acids, sulfonated 

•Alcohols, sulfated and sulfonated: 

Capryl, octyl sulfate 

Cetyl, oleyl sulfate 

Decyl sulfate- 



n-Decyloxyethyl sulfate 

3,9-Dietliyl-6-tridecyl sulfate 

2-EtliyIhexyl sulfate 

7-Ethyl-2-methyl-4-undecyl sulfate- 
Hexadeoyl sulfate- 



Lauryl, oleyl sulfate, sodium salt 

Lauryl sulfate, ammonium salt 

Lauryl sulfate, diethanolamlne salt 

Lauryl sulfate, monoethanolamlne salt- 
Lauryl sulfate, potassium salt — 



•Lauryl sulfate, sodium salt (Sodium dodeoyl 
sulfate ) . 

•Lauryl sulfate, triethanolamine salt 

Oetadecyl sulfate (Stearyl sulfate) 

Polyethoxyethyl octadecyl sulfate- 



Polyethoxyethyl octadecyl sulfate, 

diethanolamine salt. 
•Esters, sulfated and sulfonated: 

Bls-sulfosuoolnate ester of tallow mono- 

glyceride. 
Bis (p-tert-butylphenoxyethyl ) sulf osuccinate , 

sodiim salt. 

Bla(tridecyl) sulfosuccinate, sodium salt 

Butyl ethylene glycol sulfo-oleate 

n-Butyl sulfo-oleate 

n-Butyl sulforiolnoleate, sodium salt 

Diarayl sulfosuccinate, sodium salt 

Dicapryl sulfosuccinate, sodium salt 

Di(2-ethylhexyl)sulf osuccinate, sodium salt 

Dihexyl sulfosuccinate, sodium salt — 



Ethyl, butyl sulfoaconitate, sodium salt — 

Ethyl sulfo-oleate 

Glycerol di(sulfo-oleate)- 



Glycerol mono(coconut oil) ester, sulfated, 

ammonium salt. 
Glycerol mono(ooconut oil) ester, sulfated, 

sodium salt. 
Glycerol monostearate sulfoaoetate, sodium salt- 

Glycerol tri(sulfo-oleate) 

•laopropyl sulfo-oleate — 

Lauryl sulfoacetate 

Methyl sulfo-oleate 



Methyl, ethyl, propyl sulfo-oleate 

Mixed alkyl ethers, sulfated 

*n-Propyl sulfo-oleate 

Tallow fatty acid, ethyl eater, sulfonated- 



182, X. 

32, ^7, 89, 170, 254. 

32, 516, 593. 

2A. 

499. 

32. 

465. 

213, 334, 388, 4S2, 553. 

32, 37, 47, 89, 159, 182, 254, 308, 345, 388, 470, 

'i90, 553, 568, 593. 
593. 

182, 308, 327, 481. 

24, 32, 171, 182, 221, 334, 516, 553, 593. 
37, 47, 128, 170, 171, 182, 388, -^l, 482, 553. 
67, 1:28, 308, 327, 388, 445, 481, 540. 
132, 334, 388. 
32, 432. 
182. 
171, 182, 482. 



537 














37, 


321. 












35, 


388, 


533. 










20, 


35, 37, 56, 59 


, 102, 131, 171, 182, 212, 221, 


235, 308, 321, 345, 359, 360, 


369, 


384, 387, 388, 


402, 445, 466, 482, 498, 533, 


593. 




388 


482 












388 














171 


318 












235 


318 


455 










235 


537 












X. 














562. 














562. 














562. 














318 


537 


595 










318 


537 












69, 


318, 


328, 


571. 








537. 














268. 














318 


328 












•^7, 


69, 182, 235, 


257, 318, 328 


417 


445, 465, 537 


571. 












69, 


235, 


318, 


328, 


537, 571. 






112 


171 


182 


328 


537. 






537. 














318. 














318, 


466 












466. 














466. 














254, 


445. 












47, 


235, 


369, 


445, 


465, 553. 






441. 














466. 














417. 














47, 


69, 112, 171, 182, 321, 388, 


466 


595. 


466. 














47. 














221, 


384. 












465. 














X. 














223, 


384, 


482 


X. 








456. 














182, 


345. 


466. 










171, 


182, 


213 


326 


360. 






403. 














369. 














388. 














328. 














334, 


345, 


373 


466 


467, 593. 






384. 















134 



UNITED STATES TARIFF COMMISSION 



TABLE 24B. "Synthetic organic chemicals: Surface-active agents for which United States production or sales 
were reported, identified by manufacturer , 7954--Continued 



Manufaoturera' identification numbers 
{according to list In table 27) 



SURFACE-ACTIVE AGENTS, ACTCLIC— Continued 

•Sulfated and sulfonated acyclic surface-active 
agents — Continued 
»Nltrogen-oontalnlng surface-active agents, 

sulfated and sulfonated: 
Castor oil amide of monoethanolamine, sulfated, 

sodium salt. 
Coconut oil amide of Isopropanolamine , 

sulfated, sodium salt. 
•Coconut oil amide of monoethanolamine, sulfated, 

potassium salt. 
•Coconut oil amide of monoethanolamine, sulfated, 

sodium salt. 
N-(2-Hydrox7ethyl)oleamide, sulfated (Oleic 

acid ethanolamlde sulfate), sodium salt. 
N-(2-Hydroxyethyl)stearamide, sulfated (Stearic 

acid ethanolamlde sulfate), sodium salt. 
Laurie acid ester of potassium sulfoaceto- 

ethanol amide. 

Lauroylamidoethyl sulfate, sodium salt 

N-Me thy loleoyl taurine, sodium salt 

N-Me thy Ipalmitoyl taurine, sodium salt 

N-(Myristoylethyl)sulfosuccinamide, sodium salt- 
Neat's-foot oil amide of ethanolamine, sulfated, 

ajnEDonium salt. 

N-Octadecylsulfosuccinamlde, disodium salt 

N-Octadecylsulfosucclnate, disodium salt 

Oleoyl isopropanolamlde sulfate, ethanolamine 

salt. 
N-(01eoylisopropyl)sulf03uccinamlde, sodium salt 
Tallow amide of ethanolamine sulfosucclnate, 

sodium salt. 

Tallow fatty acid, N-methyl taurine salt 

•Oils, fats, and vaxes, sulfated and sulfonated: 
Animal fats and oils, sulfated and sulfonated: 
•Grease other than wool grease, sulfonated 

Lard oil, sulfonated 

•Neat's-foot oil, sulfonated 



Oleostearine, sulfonated- 
•Tallow, sulfonated 



Wool grease, sulfonated- 



Flsh and marine-animal oils, sulfated and 

sulfonated : 
•Cod oil, sulfonated 



Herring oil, sulfonated 

Menhaden oil, sulfonated 

Mixed fish oils, sulfonated 

•Sperm oil, sulfonated 



•Tall oil, sulfonated 

•Vegetable oils, sulfated and sulfonated: 



•Castor oil, sulfonated- 



•Coconut oil, sulfonated 

•Com oil, sulfonated 

Cottonseed oil, sulfonated 

Linseed oil, sulfonated- 
Mustard-seed oil, sulfonated- 
Ollve oil, sulfonated 



Palm-kernel oil, sulfonated- 

•Peanut oil. sulfonated 

Rapeseed oil, sulfonated- 

•Rice-bran oil, sulfonated 

Rice-bran-oil foots, sulfonated 

•Soybean oil, sulfonated 

•All other oils, fats, and waxes, sulfated and 
sulfonated : 

Japan wax, synthetic, sulfonated 

Recovered grease, sulfonated 

Petroleum aliphatic compounds, sulfated and 
sulfonated: Petroleum sulfonate, sodium salt. 



182. 

171, 326, 465. 
77, 170, 171, 182, 235, 321, iSl, 595. 
388. 



109, 170, 321, 326, 38<;, 445, 482. 
445. 



481. 

170, 

112, 

•iV, 

345, 

445. 

456. 

90. 
^T, 
384. 
456. 
77, 

466. 
466. 
456. 

456. 
345. 



102, 227, 388, 591. 

27, 77, 227, 481, 591, 593. 

23, 37, 59, 77, 89, 102, 221, 227, 387, 388, 445, 
482, 498, 505, 533. 

498. 

20, 26, 47, 56, 59, 94, 102, 109, 182, 227, 235, 
321, 326, 330, 345, 360, 369, 370, 373, 387, 388, 
445, 465, 466, 482, 498, 533, 553, 593. 

102, 227. 



27, 37, 61, 89, 102, 254, 387, 388, 445, 4«2, 498, 

505, 533, 591, 593. 
102, 388, 482, 498, 591. 
102, 388, 482, 591. 
227, 591. 
37, 61, 89, 102, 112, 182, 212, 221, 227, 235, 254, 

326, 387, 388, 402, 445, 466, 482, 498, 505, 591, 

593. 
77, 182, 221, 321, 359, 369, 466, 498, 533. 

20, 21, 35, 37, 38, 47, 56, 59, 67, 77, 89, 102, 
131, 171, 212, 221, 227, 235, 254, 321, 326, 330, 
334, 345, 359, 360, 369, 370, 384, 387, 388, 402, 
441, 445, 465, 466, 481, 482, 498, 505, 533, 537, 
553, 571, 591, 593. 

26, 59, 61, 167, 388, 402, 466, 490. 

388, 465, 466, 571, 593. 

388. 

387. 

387, 388, 571. 

359, 445. 

61. 

20, 56, 67, 330, 345, 373, 387, 388, 402, 466. 

182. 

182, 321, 326, 330, 388, 445, 482, 593. 

59, 388. 

102, 212, 221, 235, 326, 387, 482. 



47. 

37, 102, 498. 

348, 537. 



SYNTHETIC ORGANIC CHEMICALS, 1954 135 

Pesticides and Other Organic Agricultural Chemicals 



TABL£ 2Sli. --Synthetic organic chemicals: Pesticides and other organic agricultural chemicals for which 
United States production or sales were reported, identified by manufacturer, 1954 

[Pesticides and other organic agricultural chemicals for which separate statistics are given In table 25A 
ar« marked below with an asterisk (») ; products not so marked do not appear in table 25A because the re- 
ported data are accepted In confidence and may not be published. Manufacturers' Identification numbers 
shown below are taken from table 27. An X signifies that the manufacturer did not consent to the publica- 
tion of his Identlfloatlcm number with the designated product] 



Manuf actxirers ' identification numbers 
(according to list In table 27) 



PBSnCIDES AMD OTHER QRQANIC AGHICULTDEAL 
CHEMICAI^S, CTCLIC 

■•Fungicides and seed disinfectants: 

Acrolein 8-qulnolinol (Acrolein 8-hydroxy- 

quinollne) . 
Captan(N-(Trlchloromethylthlo')-'4-oyclohexene-l,2- 

dicarboxlmlde) . 
Chloranll (Tetrachloro-p-quinone) 
2-Chloro-4-( hydroxymercuri) phenol- 



Dlchlone (2,3-Dlohlaro-l,'i-naphthoqulnone) 

3,5-Dlm6thyltetrahydro-3,5-thladlazin6-2-thlone 

N-(Ethylmercurl) -p-toluenesulfananilide 
Glyodln (2-Heptadecyl-2-lmldazollne acetate) 
-^(Hydroxymercuri) -2-nltrophenol 
»Naphthenic acid, copper salt 
Pentachlorophenol- 



Pentachlorophenol, sodium salt 

Phenylamlno cadmium dilactate 

a-Phenyl-p-cresol (p-Benzylphenol)- 
Phenyl mercuric fnT 1llB^l^ l^a 

Phenyl mercuric hydroxide 

Phenyl mercuric lactate- 



Phenyl mercuric monoethanolammonlum aoetate- 

Phenyl mercuric naphthenate 

"Phenyl mercuric oleate 
Phenyl ijercuric 8-oxyqulnollne 
Phenyl mercuric propionate- 



Phenyl mercuric trlethanolammonlum lactate 

Phenyl mercuric urea 
•8-Qulnollnol (8-Bydroxyqulnollne), copper salt- 

2,3,^,6-Tetrachlorophenol 

»2, A, 5-Trlchlorophenol 

2,i,5-'rrlchlorophenol, ethanolamlne salt 
«2,4,5-Trichlorophenol, sodium salt 

2 , 4, 6-Trlchlorophenol- 



2,'•,6-TTichlorophenol, potassium salt- 
»Herbicldes and plant hormones: 
2-aec-Amyl-^, 6-dlnitrophenol- 



2-eec-Butyl-<i, 6-dlnitrophenol 

2-aec-Butyl-4, 6-dlnitrophenol, trlethanolamine 

salt. 
l-(p-Chloraphenyl) -3,3-dlmethylurea 
2,4-J31chlarophenoxy ethyl sulfate, sodium salt- 



3-(3,4-Dlchlorophenyl)-l,l-dlmethylurea 

l,2-Dihydro-3,6-pyrldazlnedione (Maleic hydrazide) 

l,2-Dthydro-3,6-pyridazlnedlcine, sodium salt 

3,6— Endoxyhexahydrophthalic acid, dlsodlum salt 

Isqpropyl earbanllate (Isopropyl N-phenylcarba- 

mate) (IPC). 
Isopropyl-3-chlorocarbanilate (Isopropyl 

N-(3-chlorophenyl)carbamate) . 
•Naphthalene and naphthoxyacetle acid derivatives: 

l-Haphthaleneacetamide- 



1-Naphthaleneacetic acid 

l^aphthaleneacetic acid, methyl ester- 

1-Naphthaleneaeetlc acid, sodium salt — 
2-Naphthoxyaoetie acld- 



2-i)aphthoxyHcetlc acid, sodium seilt— — 

N-1-Naphthylphthalamic acid 

Octachlorocyolohezenone^ 

Phenoiyncetic acid derivatives: 

(2-Chlaro—i-methoxyphenaxy) acetic acid, 

dimethylamine salt. 
("i-Chloro-i-methylphBnoxy) acetic acid— — 
(p-Chlarophenoxy) acetic acid 
»(2,4-J)lchlarophenary) acetic acid (2,4-D)- 
»(2,4-Dlchlorophenoxy)acetic acid esters: 
Amyl 2,4— dlchlorophenoxyaoetate- 



309. 
104, 503. 



477. 

537. 

477. 

107. 

537. 

562. 

537. 

85, 

208 

208 

473 

141 

473 

233 

309 

473 

99, 

99, 

409 

309 

473 

233 

40, 

335. 

335, 

384. 

208, 

335. 

410. 



99, 128, 136, 256, 275, 336, 457, 470, 519, 564. 
335, 489. 
335. 



309. 
473. 



233, 309. 
233, 409, 537. 



99, 208. 
363, 410, 549. 
335, 389. 



86. 
335. 



537. 
562. 
537. 
477. 
477. 
517. 
475. 



Butoxyethanol 2,4-dlchlorciphenaxya.cetate- 



208, 475, 545. 



12. 

12, 501, 563. 

12, 335, 563. 

12, 310. 

310, 501. 

310. 

477. 

487. 

545. 

208. 
335. 
208, 335, 389, 410, 417, 475. 

502. 
X. 



136 



UNITED STATES TARIFF COMMISSION 



TABLE 2SB. --Synthetic ortanic cheaicala: Pesticides and other organic agricultural chemicals lor which 
United States production or salea were reported, identified by manufacturer, W5<- -Continued 



PESTICIDES AMD OTSSR OHGiNIC ACaUCULTUHAL 
(SOKlCilS, CICLIC— Con-tlinied 

«B*rblclde> Bnd plajrt hnnnones— Contlmied 
Phmoxjrscrtlo acid dorlvatlvos— Contlnusd 
»(2,';-Dlchlaroph«ioa[y)ac»tlo acid esters— Con. 
ButcotyethoDcypropanol 2,'r-dlchlarDphenooty— 

acetate. 
Butaxyetliaiyprqpyl 2,4— dlchlorophenaxyacwtate 
Butoxypoljrprtipylsne glycol 2,^-dlchloro- 
pbanaxTBcetate. 
•n-Butyl 2,4-dlchlorophgnaiyaoetat o 
»see-Butyl 2,4-dichlarophapoocyaeetat o 
Ethyl 2,A-<llolilartjpheiiaiyacetate- 



2-Ethylheiyl 2,'4-dlchlarcphenoa:yacetate- 
laolnityl 2,<4-dlclilaropliajioixyacetate— — — 
lao-octyl 2,'4-dlotiiciroplienoiyacetate— 



•laorpropyl 2,<V-<llohlar<^li8noacyac9tate- 
Polyathyleneglycol Sj'i-diclilarophenaxymcetate 
Tetraiyirofurfuryl 2,'l-diclilarqpbenaiyacetate 
»(2,4-W.cU.aropheiicaty)acetlo acid salts: 

(2,4-J)lchlaroph9naxy)acetic add, dlrthsnol- 

anlzie salt. 
(2,<i-Dichlorophenoxy)aoetie add, dlaetliyl- 

anlne salt. 
( 2, 4-Dlchlaropliencay) acetic acid, Isopro- 

panolaxDlne salt. 
( 2, 'WJiclilcirophBncixy) acetic add, sodiun salt 
( 2, <i-Dlchlarophencacy) acetic acid, trlethsnol- 

amlse salt. 
»(2,4,5-TrlclilarciphsncDcy)aoetie acid (2,4,5-T) — 
»(2,'V,5-Trlchlarqplienoxy)acetlc acid esters: 

Butaxyethaaol 2,'i,5-triclLlaroplienaiyacetate— 
ButoxyBthnrypropanol 2,'4, S-trlchlortiphaiiary- 

acetats. 
Butoxyethorypropyl 2,<4,5-trlehlarqpliBnoixy- 

acetate. 
Bvrtaxypolyprapylene glycol 2,4,5-trlohlaro- 

phenoxyacetate. 
nJutyl 2,'»,5-trlchlorciplisnaiyacetat8- 



seo^utyl 2,A,5-trlchlaroph9naiyaeetate— 
2-EthyLheiyl 2,'i,5-trielilaroplienaiyaoetat« 
Iso-octyl 2,<l,5-xrlchlarophenaxyacetate— 



Hamif acturers ' idestifieatlon mmbers 
(according to list in table 27) 



Isopropyl 2,^,5-triehlaroplienaxyacetate— 
TetrahydPofurfvnTl 2,'1,5-trlchlorophenoxy- 
acetate. 
•Phenyl mercuric acetate- 



(2,4,5-Trichlarciphena}cy)propianlo acid 
•Insecticides : 

Aldrin (HeiachlaroheialiydrodimethBTiminphthalene) - 
Allethrln (Allyl hauolog of Cinerln !)-■ 
Benzyl thiocyanate 

l,l-Bis(p-chlarophenyl)-2^iltrobutaiie 
1, 1-Bls (p-chlarophenyl) -2-oltropTcpane- 



2-(p-tert-Buty]^henoccy) lsoprcpyl-2-chleroetliyl 

sulfite. 
Chlordan (1,2, 4,5,6, 7,8-0ctaohlaro-3a,i;, 7,7a- 

tetrahydro-4, 7-oiethanolndan) . 
Chlorinated mixed terpens* (Strobane) 
p-Chlorophenyl p-chlarobenaenesulf onate— — — 
2-Cyolohexyl-4, 6-dinitrophenol- 



1,2-Dibromoethylbeiizeiie (Styrene dlbromide)— — 
l,l-J)ichlaro-S,2-bi«(p-chlon7i^hexiyl)ethane (DDD) 

(TDE). 
1, l^ichlaro-2,2-bis(p-ethylphanyl) etha n e 
2,<l-Dlchlcirciphenyl benzenesulfonate- 



Dieldrln (Hexachlaroepoxyoctahydrodliiierthano- 

naphthaleoe) . 
-i,6-Dinitro-o-cresol (DNOC) 
4,6-Dinltro-o-cr9sol, sodium salt— 



Endrin (Heiaehlaroepoxyoctahydroondo,«ndo, 

dlmethanonaphthalene) . 
Ethyl p-nitrophenyl thlonobenzenephosphonmte 

(EPN). 
Heptachlcr (1,4,5, 6, 7,8,8-H^tachlaro-3a,4, 7,7a- 

tetraliydro-4, 7^»thaiioiiidene) . 
1,2,3,A,5,7,7-Hoptachlarobi(jyclo-2,2,1- 

heptadlene-2 , 5 . 
l,2,3,4,5,7,7-Heptachlarobleyclo-2,2,l-*;^tei»-2- 
•Hexachlorocyclohaiane (Benzene harachloride). 



208. 
335. 

12, 208, 410, 417, 502, 545, 580. 

335, 389, 417. 

I. 

410. 

389. 

389, 545. 

12, 104, 208, 335, 389, 410, 417, 545. 

410. 

104, 417. 

12, 590. 

104, 389, 410, 417, 502, 545. 

290, 410. 

208, 290. 
410. 

208, 310, 335, 339, 389, 410, 501, 502. 

X. 

410. 

208. 

335, 339. 

335, 389, 410, 545, 590. 

417. 

410. 

389, 545. 

208, 389, 410. 

104, 417. 

107, 233, 309, 409, 473, 537. 
208, 310, 462. 

566. 

240, 415, 557. 

549. 

290. 

290. 

477. 

186. 

487. 

335, 410. 

335. 

335. 

45, 417, 524. 

417. 
524. 
566. 

86, 501. 

86. 

186, 566. 

537. 

186. 

566. 



199, 290, 299, 339, 363, 368, 410, 435, 475, 524, 
537, 549, 595. 



SYNTHETIC ORGANIC CHEMICALS, \95U 



137 



TABLE 25B. --Synthetic organic chenicala: pesticides and other organic agricultural chemicals for which 
United States production or sales were reported, identified by manufacturer, J954- -Continued 



Nanufacturers ' Identification numbers 
(according to list In table 27) 



PESTICIDES AND OTHER QRGUnC AGRICULTURAL 
CHH1ICALS, CYCLIC — Continued 

»Inaect ic ides— Cont inued 

Isodrln (l,2,3,A,10,10-Hexachloro-l,i,4a,8,8a- 
haxahydro-i ,■4, 5,8-endo, endo, dimethHnonfiptha- 
lene) . 
Llndane- 



2-( 1-Methylheptyl) -4, 5-dlnltrophenyl crotonate 
(Arathane) . 
•Parathlon (0,0-Dl6thyl O-(p-nitrophenyl) phos- 
phorothionato) . 
Thfljilte (Isobomyl thiocyanoacetate) — — — — 
Toxaphene (Chlarinatad CEUi;>hsne)- 



»1 , 1 , l-Trlcbloro-2 , 2-b l3 ( p-chlorophenyl) ethane 
(DDT), 
l,l,l-Trlchlaro-2,2^1e(p-methoxyphenyl) ethane 
(Methorychlor) (Methoxy DOT) . 
Rodentlcldes: 

2-Pivalyl-l,3-indandiane- 



Warfarln (3-(Acetonylbenzyl)-^^iydroxyooumarln)- 



PE3TICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICALS, ACrCLIC 



♦Fumigants: 

Bromomethane (Methyl bromide) - 
Chlo^ppic^in- 



l,2^ichlaropropane- 



Diohloropropene dlchloropropane (DD mlxture)- 
•Fxmglcides and seed disinfectants: 

Bis (dlmethylthlocarbamyl) disulfide (Thlrajii)^ 
Cadmium succinate- 



Copper ethylhexenoate (Copper ethylcaproate) - 
Copper hendecenoate (Copper undecylenate)- 



Dimethyldlthiocarbamio acid, ferric salt (Ferbam) 
»Dlmethyldlthlocarbamio acid, sodium salt 
«Dlm6thyldlthiocarbamic acid, zinc salt (Ziram) 

Dithlocarbamate formaldehyde resin, zinc salt 

Ethyl mercuric acetate 

Ethyl mercuric chloride- 



Ethyl mercuric phosphate 

Ethylene bls(dithiocarbamlc acid), manganese 

salt (Manzate) (Haneb) . 
Ethylene bis(dithiocarbamlc acid), sodium salt 

(Nabam) . 
Ethylene bis(dlthlooarbamic acid) , zinc salt 

(Zineb). 
Methoxyethyl mercuric acetate- 



Sodium hendecenoate (Sodium undecyleaate) - 
Tetralpdoethylene- 



Zlnc hendecenoate (Zinc undecylenate)- 
•Herbicldes: 

Diethyl dithlobis(thlonoformate) 

Trichloroacetic acid, sodium stilt—— 
•Insecticides: 

Aliphatic thlocyanates- 



»Ethyl pyrophosphate (Tetraethyl pyrophosphate) 

(TEPP). 
Ethyl thlopyrophosphate (Tetraethyl dlthionopyro- 

phosphate) . 
Malathion (S-(l,2-Dlcarbethoxyethyl) 0,0-dimethyl 

dithiophcsphate) . 
Metaldehyde- 



Octamethyl pyrophosphoramide (CMPA) 
Rodentlcldes: Sodium f luoroacetate 
Soil conditioners: 

Methylvlnylether-malelc anhydride half -amide 
copolymer. 

Polyaerylonltrile, hydrolyzed, sodium salt 

Vinyl aoetate-maleic acid, modified 



339, 410, 524, 549, 
417. 














208, 389, 448, 466. 














201, 214. 
214. 

45, 208, 263, 363, 368, 
559, 595. 

537. 


410, 


417, 


506, 


521, 


524, 


537, 


480. 
420, 557. 















263, 


335, 


347. 




158. 








574. 








567. 








327. 








470. 








310. 








233, 


537. 






156, 


424, 


517, 


568. 


208, 


233, 


424, 


517, 537, 568 


201. 








309, 


537. 






309, 


537. 






537. 








417, 


537. 






417, 


537. 






417, 


537. 






233. 








310. 








419, 








310, 


419. 






208. 








208, 


335, 


549. 





417. 

104, 208, 307, 347, 435. 



290. 
208. 
208. 



208, 237, 466. 
208. 



^ Manufacturers' Identification numbers for thiram are given in table 21B. 



138 UNITED STATES TARIFF COMMISSION 

Miscellaneous Synthetic Organic Chemicals 

TABLE 2€B. --Synthetic organic chemicals: Miscellaneous chemicals for which United States production or 
sales were reported, identified by manufacturer , 1954 

[Miscellfineoufl chemicals for which separate statlstios are given in table 2eA are marked below with an 
asterisk (») ; chemicals not so marked do not appear in table 26A. because the reported data are accepted 
in confidence and may not be published. Manufacturers' identification numbers shown below are taken from 
table 27. An X signifies that the manufacturer did not consent to the publication of his identification 
number with the designated product] 



MISCELLANECfDS CHDGCAI^, CTCLIC 



2-Aminobenzothlazole- 



'4-Amlno-5-(ethoxymethyl) -2-methylpyrlmidine- 
Benzoic acid salts: 

Ammonium benzoate 

Calcium benzoat o — — 

Copper benzoat o 



Ferric benzoate 

*Sodium benzoate, tech 

•Sodium benzoate, U, S. P- 

Benzoin oxlme 

Benzothlazole- 



•Benzoyl peroxide 
BenzoyLresorclnol 
3-Benzyl-4-methylumbelliferone 
Biological stains 



^,';'-Bls[phenylureido]-2,2'-stilbenedisulfonic acid- 
Boron fluoride-phenol coii^)lex — — 
Buto:cysafrole 
Butyl berzoate- 



tert-Butylbenzolc acid 

tert-Butyl dimethyl ether of hydroqulnone- 

2(and 3)-tert-Butyl-<»-methoxyphenol 

tert-Butyl peroxybenzoate 
4— tert-Butylpyrocatechol 
Butyrolactone 



Caroten 

Centrallte (N,N '-Diethyl-N,N '-diphenylurea) - 
Chemical indicators: 
Acid ammonium purpurate- 



Dibromo-o-creaolsulfonphthalein (Bromocresol 

purple) . 
Dlbromcthymolsulfonphthalein (Bromothymol blue)- 
Phenolsulfonphthalein (Phenol red)- 



Tetrabrcmo-m-cresolsulf onphthaleln (Branocresol 

green) . 
Tetrabromcrphenolsulfonphthaleln (Bromqphenol blue) 

All other —^^ 



Chemical reagents: 
Aurintricarboxyllc acid- 



Barium diphenylamine sulfonate- 
Dlphenyl carbazide- 
Diphenyl carbazone- 



Diphenylthlooarbazone (Dithlazone)- 
a, g-Dlpyrldyl 
Clrard P reagent- 



N-( 1-Naphthyl) ethylenedlamlne dihydrochloride- 
Nltrosophenylhydroxylamlne (Cupferron) 
Phlorogluclnol- 



Potasaium biphthalate- 
Quinhydrone- 



Sodixim biphthalate — — ^_.— — — -^ 
Sodium-2,6-dichlorob6nzenonelndophenol- 

Sulfosallcyllc acid, reagent 

All other 



5-Chloro-a,a-bls [3, 5-dichloro-2-hydraiyphenyl^- 
toluenesulfonic acid. 
•Chlorophyll and chlorophylllna: 
Chlorophyll: 

Copper fixed 

Not fixed 



Chlorophyllins : 
Sodium -copper- 
Sodium-iron 



Sodium-magnesium 

Sodlum-^jotasslum-oopper- 
Sodium-potaesium-iron- 



Sodium-potasslum-magnesium- 

Copper pheophytin 

Cumene hydroperoxide 



Manufacturers' identification numbers 
(according to list in table 27) 



313. 
540, 

208. 

569. 

319. 

312. 

569. 

199, 208, 549, 569. 

313, 513. 

466. 

5, 223, 317, 350. 

384. 

188. 

7, 152, 403. 

384. 

524. 

395. 

562. 

567. 

495. 

495. 

317. 

335. 

384. 

537, 581. 

72. 

223, 517. 

364. 

403, 513. 

403, 513. 
403, 513. 
403, 513. 



403, 513. 






501, 513. 






7, 262, 403, 513. 






513. 






513. 






513. 






319. 






513. 






513. 






152, 453. 






513. 






513. 






480. 






327, 513, 524. 






513, 540. 






524. 






262, 513. 






501, 540. 






7, 403, 419, 438, 453, 
384. 


501, 


513 



72, 253. 

253, 383. 

253. 

253. 

72, 337. 

72. 

72. 

253. 

214. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



139 



'Synthetic organic cbeaicala: Miscellaneous chemicals for which United States production or 
sales were reported, identified by manufacturer , 1 954- -Cont ijiued 



Manuf acturera ' Identification numbers 
(aooordlnfi to list In table 27) 



MISCELLANEOUS CHJJIICALS, CTCLIC— Continued 

Cycloliexen6-l,2-dlcarboiyllo aold (Tetrahydro- 

phthalio acid) , dlsubstltuted, polyester salts: 
Barium salt 



Barium cadmium salt- 
Cadmium salt 



Cyclohexenyl-2'^ropanone- 
•Cyclopropane- 



Decahydronaphthalene (Decalln)- 
Dlazodlnitrophenol- 



2,5-Dl-n-butcacyanlllne (Amlnohydroquinone, dlbutyl 
ether) . 

p-Dlbuto3£ybenzene (Hydroq\d.none, dlbutyl ether) 

»2,6-Dl-tert-butyl-^-cresol, all grades 
2, 5^1-tert-butylhydroqulnon o 
l,3-Dlchloro-5, 5-dlmethylliydantoln- 



p-(Dlohloro8ulfamyl) benzole acid (Halazone)- 

2,5-DlethoxyBnllln6 

p-DlethcQcybenzene- 



7-Dlethylamlno-4-methylco\imarln- 
Dlhydroxydlmethoxybenzcrphenone— 
5,7-i)ihydroxy-4-methylcaumarin — 

3,5-Dliodosalicyllo acid 

Dllsopropylphenyl hydrqperoxlde- 
2, S^lmethoxyanlllne- 



p^^methoxybenzene (Dimethyl ether of hydroqulnone) - 
<t,'l ^lnltrocarbanlllde-2-hydroxy— 4,6-dlmethyl- 
pyrlmldlne. ,. 

Dloiane (ij-i-^lethylene oxide) 

Dipentene, hydrogenated 
Ethyl benzoylacetate 
Ethylene carbonate- 



Ethylene glycol monophenyl ether- 

Ethylene glycol terplnyl ether 

Ethylenethlotirea 
Ethyl hydrocaffeate- 
Ethyl oxanllate- 



Ethyl 2-phenylbutyrate- 
Fenchone 



•Flotation reagents: 

Dlcresyldlthlophosphorlc acld- 



Dlcresyldlthlophosphoric acid, ammonium salt- 

Dlcresyldlthlophosphoric acid, sodium salt 

Dl-o-tolylthlourea 
Rosin amine 



Rosin amine D ethylene oxide condensate — 

"Thiocarbanllide (Diphenylthlourea) 

Furan derivatives: 

Furfural (2-Furaldehyde) 

Furolc acid 



Hydrofuramlde- 



Tetrahydrofurfuryl alcohol- 
Gallic acid, tech 



Gallic acid, sodium salt 
Gasoline antioxidants and inhibitors : 
p-Butylamlnqphenol- 



N,N -Dl-sec-butyl-p-phenylenediamine- 
N,N'-Disalicylidene-l,2-firopanediamln 
All other 



Glyceryl p-amlnobenzoate- 
Glyceryl carbonate 
Glycidyl phenyl ether 



♦Hexamethylenetetramine, tech 

2-Hydroxy-^,'4 '-dimethoxybenzophenone— — 
d , l-o-Hydroxy-P ,P -dimethylbutyrolaotone- 
P^ydroxyethyl ester of tall oil 

•Lubricating oil additives: 



Allcyollo compounds, sulfurlzed 

AUsyl phenyl thiophosphates and salts 

2,2 '^ihydToxy-5,5 '-di-tert-octylphenol, mono- 

sulflde, barium salt. 
Heterocyclic conjjounds, gulfurlzed 
Petroleum sulfonate, barium salt- 



Petroleum sulfonate, calcium salt- 

Phosphorufl sulfurlzed terpene 

Tall oil ester, sulfurlzed 

All other 
p-Menthane 



p-Menthyl hydroperoxlde- 
p-Methoxyphenol 
Methylcyclohexanol 



iAl. 

Ul. 

441, 470. 

395. 

79, 288, 327, 438. 

537. 

214. 

495. 

495. 

460, 495, 567. 

495. 

81. 

420. 

495. 

495. 

188, 223. 

384. 

480. 

480. 

214. 

495. 

495. 

X. 

562. 

549. 

415. 

234. 

335, 562. 

214. 

517. 

141. 

524. 

327. 

31. 

466. 

466. 

570. 

208, 466, 537. 

214. 

214. 

208, 403, 466. 

289. 
289. 
289. 

289, 549. 
327, 36b. 
327. 



537. 
537. 



3J2, 408, 537, 540, 546, 569. 



537. 

495, 

495, 

495. 

9. 

234. 

567. 

120, 

466. 

466. 

208. 



450, 470, 544. 

431. 

466. 

431. 

548. 

431, 548. 

548. 

548. 

208, 549. 

31. 

2U. 

141, 495. 

549. 



140 



UNITED STATES TARIFF COMMISSION 



TABLE 2BB. -•Synthetic organic chemicals: Miscellaneous chemicals for which United States producti 
sales were reported, identified by manufacturer , 19 54 --Continued 



HflDuf acturers ' Identification nujnbera 
(according to Hat in table 27) 



MISCELLAKEOUS CHBKICALS, CYCLIC — Continued 

2,2'-Methylen6bls [i-chlorophenol] (Diohlorophene) 

2,2'-Methylenebi8 [3,i,6-tricM.orophenol] (Hexachloro- 
phene) . 

2,2' -Methylenedi-p-oresol 

Methylgluooside- 



Methyloldimethylhydantoin 

Mett^l terpinyl ether 

4-Methyl-5-thiazole-ethanol 

»4_M6thylumbellifercine— — — 
Morphollne 

Morpboline p-toluenesulfonate- 
»Naphthenic acid salts: 
Aluminum naphthenate 
Cadmium naphthenate 
•Calcium naphthenate 



Cobalt-lead-manganese naphthenate- 
«Cobalt naphthenate 
»Iron naphthenate 

Lead manganese naphthenate 
"Lead naphthenate 

Lithium naphthenate 
•Manganese naphthenate 

Mercury naphthenate 

Nickel naphthenate 

Strontium naphthenate 

Rare earth naphthenates 
»Zinc naphthenate- 



•Organic mercury compounds: 

o-Chloromercurlphenol (o,p^ydroxyphfinyl mercuric 
chloride) . 

Phenyl mercuric benzosulf imide 

Phenyl mercuric borate- 



Phenyl mercuric carbonate 

Phenyl mercuric hexoate— — — — 

Phenyl mercuric linoleate 

Phenyl mercuric octat o 
Phenyl mercuric salicylate 
Phenyl mercuric stearate 
Phenyl mercuric trichlorophenate- 
Pyridyl mercuric acetate 
Pyridyl mercuric chloride- 



Pyridyl mercuric stearats- 
Phenolthlosulfonic acid 

Phenyl magnesium bromide 

•Photographic chemicals: 



5-Amino-l, 3, •i-triazole- 
•Benzotriazole- 



Catechol (Pyrocatechln)- 
Chlorobenzotriazole— ^— 



2,4-Diaminophenol hydrochloride 

p-Diazo-N-banzyl-N-ethylanillne, zinc chloride 

salt. 
p-Diazochloro-N,N-diethylanilin6, zinc chloride 

salt. 

«p-Diazo-4l,N-<iiethylaniline, zinc chloride salt 

p-Diazo-N,N-diethyl-m-phenetidine, zinc chloride 

salt. 

«p-Diazo-N,N-dimethylaniline, zinc chloride salt 

Diazodiphenylamine aulfat 



p-Diazo-N-ethyl-N-hydroxyethylaniline, zinc 

chloride salt. 
p-Diazo-N-hydroxyethyl-N-methylaniline, zinc 

chloride salt. 
P'JJiazo-N-methyl-o-toluldine, zinc chloride salt — 
NjN-Diethyl-p-^henylenediamine hydrochloride 
N,N-Oiethyltoluene-2,5-diamine, monohydrochloride- 
2,5-Dihydroxybenzenesulfonio acid (Hydroquinone- 

sulfonic acid), sodium salt. 
N-Ethyl-N-hjdroJtyethyl-p^henylenediamine sulfate- 
N-Ethyl-N-(p -methanesulf onamldoethyl) toluene-2, 5- 

diamine sulfate, 

Hydroquinone (Hydroquinol) 

7-Hydroxy-l,2-naphthlmidazole 

N-(Hydroiyphenyl) glycine 

4-Methoxy-l-naphthol 
p-Methylamlnophenol sulfate (Metol) 
5-Methylbenzotriazole 

2-Methylthiazoline 

6-)Jitrob6nz imidazole 
A-Phenylpyrocatechol- 



395. 
395. 

395. 
1^. 
537. 
2U. 
540. 
188, 
234, 
191. 



460, 505. 
562. 



99, 128, 136, 190, 256, 275, 336, 470, 564. 
233, 309. 



99, 136, 327. 

256. 

85, 99, 128, 136, 190, 256, 275, 336, 470, 564. 

136, 564. 

85, 99, 128, 136, 190, 256, 275, 336, 470, 564. 

99, 136, 256, 275, 336, 470, 564. 

136. 

85, 99, 128, 136, 190, 256, 275, 336, 470, 564. 

256. 

85, 

99, 

256. 

256. 

256. 

85, 99, 128, 136, 190, 256, 336, 470, 564. 



309. 
233. 
473. 
107. 
473. 
107. 
233, 
309. 
473. 
327. 
327. 
327. 
384. 
152. 

313. 
313, 
460. 
313. 
461. 
313, 



280, 
X. 

280, 
313. 
280, 



480, 513. 



313, 384, 403, 407, 480. 



313, 407, 480. 
313, 480. 



Fhthalic acid, lead salt, dibaslc- 



495. 
495. 
513. 

280. 
495. 

295, 495. 

313. 

280. 

495. 

366, 461, 513. 

513. 

313. 

513. 

313, 495. 

404. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



141 



TABL£ 26B.- -Synthetic organic chemicals: liacellaneoua cheaiicala for which United States producti 
sales were reported, identified by manufacturer, 1954- -Continued 



Cbsmloal 



Mflruf actuTBTB ' Idantlfleation numbers 
(aooardlng to list In table 27) 



MISCELLAKEOnS CHEMICALS, CTCLIC — Continued 



Phytol 

Flnaoole and plnacolone- 
P Inene 



Plnena msrcoptan— 
PIperonyl butoDcldo- 



Polyethylene terephtlmlate- 
P ■J'rciplolactone 
Propylene carbopat o 
»n-Propyl gallate- 



Pyrogailol (Pyrogalllc acld)- 
8-Qulnollnol, zlno salt 
p-Qulnone- 



Rssearoh chemicals: 
Aralkyl chlorldes- 

AraUsyl sllanos 

Araliyl aulfldos- 



Pyrldlne derlvatlvea- 
All other 



•Rosin aeld salts i 
Aluminum reslnate— 
•Calcium reslaate— 
Cobalt reslnate— 



Copper reslnate- 

Iron reslnate— 

•Lead reslnate- 



•Manganese reslnate— 

Zinc reslnate 

All other 

Sallcylanlllde- 



Sallcyllc acid, lead salt- 
Sulfosalloylic acid- 



Tall oil fatty acid ohlorlde- 



•Tall oil salts (Llnolelc-rosln acid salts): 

Barium zinc tallate 

Calcium tallat e 
•Cobalt tallate 

Copper tallat o 
•Iron tallate 



•Lead tallate 

Lead manganese tallate- 
•Manganese tallate 

Zinc glyceryl tallate — 

Zinc tallate 



•Tanning materials, synthetic: 

Bisphenol-farmaldehyde, bisulfite type- 



Cresol-formaldehyde sulfonate, sodium salt- 

Cresyllc acid, polysulfone condensate 

Llgnoeulfonlc acid, sodium salt- 



1-Naphthalenesulfonie acid, formaldehyde eondsn- 
sate and salt. 
•2-Naphthalonasulfonic acid, formaldehyde conden- 
sate and salts. 

2-NaphtholBUlfonio acid, formaldehyde condensate, 
sodium salt, 

Phenol-fomaldehyde, sulfonate 

Styrene-maleic anhydride tnterpolymer, pai^lal 
sodium salt. 

Sulfonyldiphenolsulfonic acid, formaldehyde con- 
densate. 
Terpene hydrocarbons- 



1,2,3,A-Tetrahydranaphthalen6 (Tetralin)- 

Tetrahydrothiqphen o 

Tetraphenyl tin- 



Textile chemicals, other than surface-active agents 
Diphenyl-l,2-propanediamine- 



Methyl stearate picolinium ohlorlde- 

l-Phenyl-S-pyrazolidone 

Protalbinio acid 
Saccharide bisulfite 



Stearamldemethylpyridinium chloride- 
Sulfonated phenol — 



2,2 '-Thiobis[4,6-diehloroph6nolJ- 

Thiophenol 

o-Tolylblguanide- 



Trl-tert-amylphenyl phosphlte- 
N-Trichloromelamlne 
Tricresyl phosphite 
Trioxane 



Trlphenyl phosphite- 



72, 253. 










480. 










581. 










537. 










415. 










537. 










487. 










234. 










366, 495, 501, 569. 










327, 366. 










582. 










366, 495. 










172. 










134, 547. 










172. 










508. 










50j 53, 152, 234, 302, 313, 


319, 


394, 


397, 466, 480 


508, 513, 547. 










84, 327. 










84, 136, 215, 273, 470. 










85, 275, 470. 










84. 










84, 










84, 136, 275, 470. 










84, 136, 275, 470. 










84, 136, 470, 581. 










84. 










537. 










404. 










501, 540. 










384. 










136. 










99, 256. 










85, 99, 128, 136, 190, 256, 


275, 


336, 


470. 




85, 136. 










85, U28, 136, 470. 










85, 99, 128, 136, 190, 256, 


275, 


336, 


470. 




136, 336. 










85, 99, 128, 136, 190, 256, 


275, 


336, 


470. 




256. 










136. 










445. 










384. 










595. 










428. 










445. 










356, 403, 417, 445, 478. 










445. 










417, 445. 










537. 










384. 










537. 










537. 










431. 










549. 










465. 










X. 










595. 










455. 










X. 










537. 










384. 










208. 










513. 










208. 










208. 










419. 










187. 










169. 










208. 











142 



UNITED STATES TARIFF COMMISSION 



TABUE 2SB. --Synthetic organic chemicals: Miscellaneous chemicals for which United States producti 
sales were reported, identified by manufacturer , i954- -Continued 



Masuf acrturers ' Identification numbers 
(according to list In table 27) 



MISCZLLANEODS CHEJGCAI^, CTCLIC— Continued 



Xanthophyll 

Xenylblguanlde- 



mSCELLUfEOUS CHaGCAI^, ACTCLIC 



»Ac9taldehjde- 
Acetamlde- 



»Acetlo acid, synthetic, lOOjt- 
»Aoetlc acid salts; 
•Aluminum acetate 



Aluminum subacetate- 

•Amnonium acetate 

»BarlxM acetate 
Cadmlima acetate 
Calcium acetate 
Chrcoiium acetate 

•Cobalt acetate 
Copper acetat e 
Lead acetate 

•Lead subacetate— — 



Lithium acetate- 
Magnesium acetate- 



Manganese acetate- 
Mercuric acetate — 
Nickel acetat e 
•Potassium acetate- 
Silver acetate—— 
Sodium acetat e 
Zinc acetate- 



•Acetic anhydride, 100^: 
From acetaldebyde 
From ethylene 
From recovered acetic acid by the vapor-phase 

process. 
From acetic acid (other than recovered) by the 
vapor-phase process. 
Acetin i 

Mono — .^ — ^— ^— - 



Dl— 
Tri- 



•Acetone: 

•By fermentatlon- 



•From isopropyl alcohol- 
•All other 



Acetone semlcerbazone- 

Acetonitrile- 



Acetonylacetone (2,5.flexanedica5e)- 

Acetonylacetone carbon disulfide— 

Acetylacetone 

Acetyl broBiide 

Acetyl chloride 

Aconitic acid 

Acrylamlde 

Acrylates, above ethyl 

Acrylic acid 

Acrylic acid, calcium salt 
•Acrylonltrile 

Adipic acid 

Adiporitrile- 



Aldol (Acetaldol) 

Alkyl acid phosphates 

Aliyl ammonium phxjsphates- 
Allyl alcohol- 



Allyl glyceryl ether 

Allyl glycldyl ether 

N-Allylglycine 

Allyl Isothiooyanate, comm 
Allylthloirrea 

Aluminum isopropoxide (Aluminum isopropylate)- 
•Amlnea: 

Ally l amino 



»n jutylandne, njono- 
tert-jutylamine- 



Coconut oil amlno- 

Diallylamlne 

Dl-n-butylajnine 

Dlethylamlne- 



Diethylamlne hydrochlorlde- 
Dlethylenetrlamine 



72, 253. 
208. 



169, 181, 2U, 290, 493, 495, 496, 537, 556, 562. 
524. 

181, 214, 290, 495, 562. 



445, 


466, 


524, 


540, 


562. 


327, 


540. 








201, 


327, 


524. 






201, 


327, 


524. 






201, 


327, 


524. 






201, 


327, 


524, 


540. 




136, 


327, 


445, 


466. 




85, 


136, 


201, 


275. 




201, 


275, 


524, 


562. 




201, 


470, 


494, 


524. 




201, 


327, 


524, 


540. 




319. 










201, 


327, 


524. 






136. 










327, 


524. 








136, 


275, 


327. 






201, 


327, 


524, 


540, 


562. 


327. 










169, 


201, 


524, 


540, 


562. 


136, 


201, 


327, 


524, 


540, 562 


214. 










562. 










169, 


214. 









214, 495. 



386. 
495, 580. 



181, 290, 415. 
495, 562, 567. 
564, 584. 



466, 562. 
X. 



567. 
517, 562. 



567. 
562. 
562. 



SYNTHETIC ORGANIC CHEMICALS, 195^ 



143 



TABU 2€B. ^'Synthetic organic cheaicala: Kiacellaneoua cheaicaia for which United Stataa production or 
aalea were reported, identified by manufacturer , 1954^ •Continued 



Hanuf seturora ' Idantlfloatlon nunbcra 
(accanUng to ll»t in tabl» 27) 



mSCELLAKEODS CBHGCAI£, ACTCLIC— Contlmied 

«Aiilne8— Cont Inuod 

N^jN^-Dlethyl-lj't-pentanedlainlna (NovoldlamlnB)- 

N,M^)lethyl-l,3-prcipaji9dlamln o 

M ieobuty lamlns- 



DUsopropylamlne- 
Dlnethylamljie- 



Dlmethylamlno hydrochloride 

Dimdthylainine sulfat e 

DlmBthyloctadaeylamlne (Stearyldlmsthylajiiliie)- 

N,M-Pliiiflthyl-l,3-prcfpaii9dlaiiilii o 

Dl-n-propylajnln o 

Dodaoylamine- 



EthylajDlno, mono- 
KthylensdlamlDS- 



N-Ethyl-l,3-propaii8dlaiiilne- 
Haxadecylamlne- 



Hsxamsthylansdlanln*— — 
3,3 '-ImlnohlspropylaMina- 
iBohutylamine- 



Isoprqpylamliie- 



MethyLamlne, mono- 
Octadecylamlna— — 



Octylamlne- 



Oleyl-llnolayl amine- 
Polyethyleneamlnes— 
PropylanedlamLne- 



Soyhoan oil amina 

Staaryl-palmltyl amlne- 
Tallow amije 



Tallow amliie, hydrogenated- 

Trlhutylamlno- 

Trlathylamlne- 



Trlmethylamlne- 



TrimethylBjnliie hydrochloride— 
All othar 



Aadnoguanldlna blcarbonat o 
Ajnlnoguflnldina gulf at o 
2-Jimlno-2-(hydra3cyiiiethyl)-l,3-propanedlol 

( Trig (hydroxymathyl) smi nnrmthapa) . 
2-Aiiilno-2-iiiathyl-l,3-yrqpaaadlol 
2-Amliio-2-<nethy'l-l-prppaiiol 
3-Amiiio-l-propanol- 



Anyl aoetatea, 90^, prlnary: 



Normal- 



iBoamyl 

Mlzad Iscmers- 



Anyl aold phosphates———— 
Amyl alcohols, lOOjt: 
Unmixed: 
Primary! 

Namal (n-Butylcarblnol)- 



Isoainyl (3-Methylbutanol-l) 

Secondary: 

Pentanol-2 f Methylpropylcarbtnol) - 
Peirtanol-3 (Dlethylearblnol) 

Tertiary: Amyl (2-MathylbutaDol-2) — 
Mixed: 

Fusel oil, crude- 



Fusel oil, refined 

Other than fusel oil: 
Primary mlxad- 



Seoondary niixad- 
Prlmary-secondary mixad- 



Primary-aeoondary-tertlary mixed- 
All other 
Amyl athsr- 



Amyl ethyl ketone 

Ai^l mercaptan (l-Pentanethiol)- 

Amyl nltrate- 



Aiqyl potassium sodlxim phosphate- 
Azelaic acid 



, (U a '-Azodllsobutyronltrlle- 
Behanlc acld- 



»Bis(2-chloroethyl) other (Dlchloroethyl ether), all 
grades. 
Bls(chlaroisapropyl) ether (Dlchlorolsopropyl ether) 
Boron fluoride ethyl ether cocylex 



Bromal- 



N-Bromoacetamlde- 
a^roBiolaurlc aeld- 



417, 537. 



549. 



385. 
562. 
562. 



562. 

417, 537. 
385. 
417, 562. 



562. 

417, 537. 
537. 
466, 517. 



223. 
466. 
517. 
517. 
290, 
447. 
417. 
417. 
466, 
517. 
333, 
517, 
363, 
567. 
333. 
537. 
466. 
517. 
517, 
290, 
333, 
333, 
385. 
562. 
562. 
333. 
385. 
333. 
333. 
517. 
517, 
290, 
447, 
417, 
225. 
384. 
290. 

290. 
290. 
466. 



181, 290. 
3, 125, 415. 
517. 
307. 



517. 
125, 415. 

517. 
562. 
247, 517. 

290. 

181, 290, 415. 



517. 
517. 
517. 
517. 
281, 
517. 
567. 
500, 
339. 
208. 
467. 
462. 
530. 
234, 



517. 
517. 



335, 363, 562, 574. 



a-Broiiio(laurlc-atearlc) acld- 



335, 562, 574. 

136, 524. 

247. 

152. 

537. 

537. 



144 



UNITED STATES TARIFF COMMISSION 



TABLE 26B. -Synthetic organic chemicals: Miscellaneous chemicals for which United States production or 
sales were reported, identified by manufacturer , i9J4--Continued 



Mssuf acturers ' Identification numbers 
(according to list in table 27) 



KtSCELUNEOnS CEOaCALS, ACTCUC— Continued 



N>^romosuooinljside (Succinlbromlmide)- 
•Butyl acetates, 90^: 



Seoondary- 



H-tert-Butylaorylamide 
•Butyl alcoliols, lOOjt: 
PrliLBry: 
•Manual (n-Propylcarblnol)- 
Iso (isopropylcarbinol)- 



Secondary (Methylethylcarblnol)- 

Tertlary (Trlmethylcarblnol) 

Milt vera 8- 



Butylene glycol (1,2- and 1,3- mixture) - 

Butyl ether (Dl-n-bvrtyl ether) 

tert-Butyl hydroperoxide ■ 
Butyl lactate- 



tert-Butyl peroxide (Dl-tert-butyl peroxide) - 

tert-Bxityl peroxyaeetate 

Butyraldehyde- 



Butyraldehyde oxim o 

Butyric acid 

Butyric acid, sodium salt-^— 

Butyric anhydride 

Butyryl chlorid e 

Capric acid (n-Decyllo aeld)- 

Caproic acid- 



Caprolaetam (2-Oxohexamethyleiiimine)- 
Capryl chloride (Decanoyl chloride) — 
Caprylic acid (Octanolc acid) 
»Caprylic acid salts: 

Aluminum eaprylate 

Sodium eaprylate 

Zinc eaprylate 



Caprylyl chloride- 
»Carbon disulfide— 



•Cellulose eaters: 
•Cellulose acetate 
Cellulose acetate butyrate 
Cellulose acetate propionat e 
Cellulose nltrat o 
•Cellulose ethers: 

Ethyl cellulose 

Ethyl hydroxyethyleellulose 
Methyl celluloa o 
•Sodium carboxymethylcellulose, 100 ^ 
Sodium carboxymethylhydroxyethylcelluloBe- 
Chemical reagents- 



Chloral (Trichloroacetaldehyde)— — 
Chloroacetaldehyde dimethyl acetal- 
•Chloroacetic acid, mono- 



Chloroacetlc acid, mono, derivatives: 
Butyl mcnoohloroacetate 



Ethyl monochloroacetate— — 
Isopropyl monochloroacetate- 
Methyl monochloroacetate—— 
Sodium monochloroacetate- 



Chloroacetone ( l-Chloro-2-propanane) - 
Chloroacetyl chlorlde- 



•2-Chloro-N . N-dimethylethylamine ( Dimethylaminoethyl 
chloride) hydrochloride. 
2-Chlaro-N,N-dimethylprci)ylamlne hydrochloride—— 
P -Chloroethyl acetate- 



2-Chloroethyl methyl ether (2-Chlaroethcixyiiiethan9)- 
Chloromalelc anhydride 
Chloromethyl methyl ether 
P-Chlorpproplanyl chloride 
Chloropropyl thlophosphate- 



N-Chlorosuccinimide (Succiniehlorimide) 
2-Chlorotrlethylamine (Diethylaminoethyl chloride) 

hydrochloride . 
Chlarotrimethylsilan o 
Choline 

Citric acid, by fermentation, refined 

•Citric acid salts: 
Ammonium citrat e 



Ammonium citrate, dibasic- 
Barium citrat o 
Calcium citrate 



152, 403. 



169, 181, 290, -H5, 495, 562. 
169, 495. 



!fa9, 181, 290, 415, 495, 496, 562. 
169, 496, 537, 562. 



496. 
567. 

:-67. 

49b. 

Zei, 495, 562. 

562. 

374, 562. 



Ferric ammonium citrate- 
Ferric citrate 



76, 

125, 

567. 

567. 

169, 

169. 

562. 

317, 

290. 

317, 

317. 

495, 

403. 

169, 

396, 

495, 

549, 

482. 

302, 

537. 

549. 

482. 



388, 465. 

447. 

201, 447. 

580. 

U, 64, 166, 202, 392, 435. 

70, 169, 214, 495, 537. 

495. 

495. 

2U, 537. 

214, 

214, 

335. 

214, 228, 537, 574, 

214. 

152. 

41C, 435, 506, 537. 

384. 

208, 214, 228, 240, 335, 549, 554. 

208. 

208, 335, 395. 

396. 

335, 396. 

335. 

513. 

335. 

263, 310, 484, 527. 

263. 

141, 

522. 

403, 

417, 549. 

513. 

339. 

152, 403. 

263, 310, 484, 

134, 
417. 
528, 

327, 528, 540, 

540, 

494. 

528. 

327, 528. 

327, 



SYNTHETIC ORGANIC CHEMICALS, 1954 



145 



TABLE 2SB. --Synthetic organic chemicals: Miacel leneoua chemicals for which United States production or 
sales »ere reported, identified by manufacturer , i 85<- -Continued 



Mamif acturars ' Identification numbsrs 
(aocordlng to list In table 27) 



MISCELLAKEOtJS CHUIICAIS, ACTCLIC— Continue^ 



•Citric aold salts— Continued 
Manganese citrate 



"Potasalum cltrate- 
SodluB citrate— 
Crotonaldehjd o 
a-CyanoacetajBlde— - 
Cyanoacetlc acid — 
P -Cyancrpropylainlne- 



Cyanurio aold- 

Dlacetone alcohol ('»-^Iydroiy-4-Biethyl-2-p9ntanone)T- 

2-Dlbutylamlnoethanol 

W-butyl maleato' 



1, 3-Dlbutyl-2-tlilovirea 

Dlbutyl tin methorlde 

Dlchloroacetaldehyde 

Dlchloroaoetio acid 
Dlchloroaoatlc acid, methyl ester- 
Dlohloroacetyl chlorlde- 



Dlchlorodlethylsllane (Diethyl silicon dlchlorlde) — 
Dlchlorodlmethylsllane- 



Dlchloroethyl fonnal (Bls(2-chlaroethoiy)methsne) 

l,3^1chlaro-2-propanol (Glycerol dlchlorohydrln) 

Dl ( 1,2-epcaypropyl) ajnine- 



Dlethyl allyl-l-mothylbutylmalonate- 
2-I)lethylaj!ilnoethanol- 



Dlethylamlnoethyl oethacrylate- 



l^lethylaiiilno-4-pentaiiol (Nopol alcohol) - 

Dlethylaminoproplonitrlle 

Diethyl sec-butylethylmalonate 

Diethyl carbonate- 



•Dlethyl dlethylmalonate (Diethyl malonlc ester) - 
«Dlethylene glycol- 



Dlethylene glycol chlorofarmate- 



Dlethylene glycol diethyl ether (Bls(2-ethoiyethyl) 

ether) . 
Diethylene glycol monobutyl ether (2-(2-Butoxy- 

ethoxy) ethanol) . 
Diethylene glycol monobutyl ether acetate- 



Dlethylene glycol monoethyl ether (Carbltol)(2-(2- 

Ethaxyethoiy) ethanol) . 
Diethylene glycol monoethyl ether acetate- 



Dlethylene glycol monomethyl ether (2-(2-Methcacy- 
ethoxy) ethanol) . 

Diethyl (ethoiymethylene)malanate 

Diethyl ethylisoajuylmalonate- 



Dlethyl ethylmalanate (Ethyl malonlc aster)- 

Dlethyl ethyl-1-methylbutylmalonate 

Dl-2-ethylhexyl maleate 
Dlethylhydroiylamine oxalate 
Diethyl maleate- 



»Diethyl malonate (Malcmlc aster) - 
Diethyl l-methylbutylmalonate— — 
Diethyl oxalate (Ethyl oxalate) — 
Dlethylthiocarbamyl chloride 

l,3-Dlethyl-2-thlourea 

Dlglyoollo acld- 



a,a-Dlhydroxy-P,P-dlmethylbutyrlo aold, sodium salt- 
Dllsobutyl ketone (isovalerone)- 



Diisopropyl peroxydlcarbonate (Isqprqpyl percarbon- 

ate). 
1,3-Dllaopropyl -2 -thiourea 
»2-DlmethylamlnoethaDol 
Dlmethylajnlnqproplonltrlle 

Dimethylcarbamoyl chloride 

N,N-Dlmethylformamlde 
Dlmethylglyoilme- 



2 , 6-Dimethyl-4-heptanol ( Dllsobutyloarbinol) - 

Dlmethylhexynedlol 

Dlmethylhexynol- 



Dlmethyl hydrogen phosphite- 
Dimethyl malonate 

Dlmethyloctynedlol 

Dlmethylolurea 

1 , 3-Dimethylurea 

Dloleyl maleat o 
»Dlpropylene glycol- 



Dlpropylene glycol methyl ether- 
Dithlo-oxamide (Rubeanlc acid) — 
Dodecenylsuoelnlo anhydride—— 

Zplchlorohydrln 

Eruclo acid 



327. 

327, 

327, 

495, 

395. 

2-M), 

495. 

513. 

562, 

517. 

562. 

517. 

X. 

435. 

396. 

396. 

396. 

134. 

134. 

562. 

513. 

537. 

168. 

234, 

537. 

247. 

466. 

168, 

415. 

274, 

234, 

475. 

562. 



528, 540. 
528, 540. 
562. 

279, 335, 390. 
567. 



517, 362. 



279, 420. 

335, 363, 562, 574. 



234, 562. 



562. 
363, 562. 



562. 

234, 335, 363, 562, 



396. 
168, 
168, 
168. 
562. 
513. 
466, 
274, 
168, 
290. 
517. 
517. 
537. 
274. 
562. 
475. 

517. 
417, 
466, 
453. 
417, 
513. 
562. 
226. 
226. 
187. 
396. 
226. 
537. 
240, 
208. 
169, 
335. 
327. 
403. 
562, 
530. 



274, 420, 
208, 274, 420, 



562. 

279, 335, 396, 420. 

274, 279. 



517, 562. 
549. 



517. 

234, 335, 562, 574. 



146 



TABLE 2f!B.--Syntheti 



UNITED STATES TARIFF COMMISSION 

organic chemicals: Miscellaneous chemicals for which United States production or 
sales were reported, identified by manufacturer, I954--Continued 



HISCELLANEODS CHEMICAI^, ACTCLIC— Continued 



•Ethanolajnlnaa : 

•Mono ( 2-Amipoethanol) - 
»D1 (2,2^-AmlDcidiethanol) 

»Trl (2,2',2"-Nltrllotriethflnol) 

Ethanolanlne (mono) salt with formaldehyde 

Ethflnolamlne residue 

P-Ethoiypropianltrlle — 

•Ethyl acetate, SSf — ■ 

Etl^rl aoetoacetate-^ ■ 

Ethyl acid phosphates ■ — ■ 

Ethyl acrylate— — — 

»Ethyl alcohol, synthetic 

Ethylamlnoethanola , mixed 

Ethyl ajnmonlum phosphate 

Etl^l bromoaeetate — 

2-Ethyl-l-butanol (sec-Hexyl alcohol) 

a-Ethylbutyraldehyde — 

a-Ethylbutyrlc acid (Dlethylacetlc acid) 

a-Ethyloaproaldehyde (2-EthyLhexaldehyd9) 

a-Ethylcaprolc acid (2-Ethyl-l-hexolc acid) — 
»a-Ethylcaprolc (2-Ethyl-l-hexclc) acid salts: 
Aluminum a -«thylcaproate 

»Calclum a -«thyloaproate ■'■ 

•Cobalt a -ethyloaproate 

Iron a-ethylcaproate— 

Lead a-ethylcaproate — 

•Manganese a-ethylcaproate 

Strontium a-«thylcaproat6-^ 

•Zlne a-ethylcaproate — ■ 

Zirconium a-ethylcaproate 

a-Ethylcapryl acetate 

N-2-Ethylcarblmlde^ — 

Ethyl chloroformate 

Ethyl cyanoacetate 



Ethylene, from ethyl alcohol 

Ethylene chlorohydrln (2-Chlaroethanol)- 
Ethylene cyanhydrln (Hydracrylonltrile) - 
•Etl^lene glycol 



Ethylene glycol dlformate - 

Ethylene glycol dimethyl ether (1,2-Dlmethoxyethane) 

Ethylene glycol monobutyl ether (2-Butaxy«thanol) 

Ethylene glycol monoethyl ether (Cellosolve) 

( 2-Ethoicyethanol ) . 
Ethylene glycol monoethyl ether acetate (2-Ethoiy- 

ethyl acetate) . 
Ethylene glycol monomethyl ether ( 2-Methaicyethanol) - 
Ethylene glycol manoaethyl ether acetate (2-Methaxy- 
ethyl acetate) . 

•Ethylene oilde — — __— ^— — — — 

•Ethyl ether: 

•Tech ' ■■ — — • ~"~~ 

•U.S.P^ — 

•Absolute — _— — — ^— ^— ^-^— — ^— — ^— 



•Ethyl formate 

N-Ethylglyolne 

2-Ethyl-l,3-hexanedlol 
2-Ethyl-l-hBxanol 



Ethyl a-hydroiylBobutyrate 

Ethyl a-hydroxylsovalerat o 
2-Ethyl-2-(hydroxymethyl)-l,3-prcipanedlol 

(Trlmothylolpropane) . 
Ethyl lactate- 



Ethyl magnesium bromide 

2-(Ethylmercapto) othanol 

2-Ethyl-2-nltro-l , 3-pr opanedlol 

Ethyl potassium sodium phosphate- 
Ethyl propionate^ 

Ethyl propyl nitrate 

Ethyl silicate (Tetraethoiysllane)- 
Ethyl stearoylacetate- 



Ethyl sulfate (Diethyl sulfate) 

2-Ethynyl-2-butanol 

Fats and oils, chemically modified: 

Castor oil, acetylated ■ 

Castor oil, phosphated- 



Manuf acturers ' identification numbers 
(according to list in table 27) 



Vegetable oils, brominated- 
All other- 



ratty acids, chemically modified: 
Castor oil fatty acids, dehydrated- 
Stearlo acid, dehydrated 



335, 562. 
335, 562. 
335, 562. 



290, 323, 415, 495, 562. 
562. 



562. 

222, i23, 496, 537, 562, 567, 



562. 
562. 



136, 256, 470. 
136, 256, 336, 470. 



136, 256, 404, 470. 
256, 470. 



234, 
234, 
234, 

417. 
234. 
466. 
181, 
415, 
307. 
417, 
214, 
517. 
208. 
335. 
495, 
562. 
562. 
496, 
495, 

128. 
128, 
128, 
136. 
128, 
136, 
256. 
136, 
256, 
562. 
562. 
415. 
279, 
288, 
522, 
417, 
234, 
562. 
152. 
234, 
335, 

562. 



234, 335, 363, 562. 
562. 

234, 332, 335, 363, 562. 

214, 222, 423, 496, 562. 

327, 415, 438. 

327, 415. 

125, 290, 302, 374, 562. 

466. 

562. 

495, 496, 562. 

417, 

417. 

225. 

466. 

152. 

517. 

290. 

208. 

125, 302, 374. 

339. 

440, 562, 580. 

I, 

562. 

508. 

103. 
307. 

302, 536. 
188, 273, 302. 

103. 
417. 



256, 470. 



335, 396. 

415. 

562. 

466. 

332, 335, 363, 537, 562, 574. 



562. 
363, 562. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



147 



'Synthetic organic cheaicaim; Miacellaneoua chemicals for which United Statea production or 
sales were reported, identified by manufacturer , 1954' -Continued 



Kunif aoturers ' Idmtlflaatlon Dunbars 
(according to list In table 27) 



mSCHiAMKODS CHIMICALS, ACTCLIC — Continued 

•Fatty acid esters not Included with plastlclzera or 
surface-active agents: 
Butyl palmltate- 



Ethylene glycol mono-oleat o 
Isopropyl myrlatat o 
Isoprppyl oleate 
Isopropyl palmltate 
Isopropyl stearate 
Metbyl eaproate 

Methyl ester of coconut oil 

Methyl nyrlstate 

Polyethoxyethyl castor oil ether 

Polyothoxyethyi castor oil ether, hydrogenated- 
l,2-Propylen6 glycol dloleate 
All other- 



»Fatty and synthetic higher alcohols (Cio and 
higher) : 
Decyl aleohol- 



3 , 9-Dlethyl-6-trldeoanol 

Dodecyl alcohol (Lauryl alcohol) - 

7-Etl^l-2-methyl-4-hendeeanol 

5-Etl^l-2-nonanol- 



»l-4iexadecanol (Cetyl alcohol) 
l-Ootadecanol (Stearyl alcohol) 
cls-9-Octadecen-l-ol (Oloyl alcohol)- 
1-Trideeanol 
All other 



♦Flotation reagents: 
Dlthlophosphfltes : 
Anmonluiii dl-aec-butyl dithlophosphate- 
Ammonlum dlisopropyl dithlophosphate — 

Potassium dihexyl dithlophosphate 

Potassium dlisopropyl dlthlophoaphate- 



Sodium dl-aec-butyl diethyl dithlophosphate 
Sodium dl-sec-butyl dithlophosphate——— 
Sodium diethyl dithlophosphate- 
Sodium dihexyl dithlqphosphate- 



Sodium dlisopropyl dithlophosphate- 
Fatty amine salts: 
Butylammonium oleate- 



Cooonut oil amine acetate 
Cottonseed oil dlethylenetriamlne acetate- 
»Octadecyl amine acetate 
Oleyl-linoleyl amine acetate 
Stearyl-palmityl amine acetate 
Tallow amine acetate 



Tallow amine acetate, hydrogenated- 
Xanthates: 

Potassium amylxanthate 



Potassium sec-butylxanthate — 
Potassium ethylxanthate 
Potassium isopropylxanthate— 

Sodium n-butylxanthate 

Sodium sec-butylxanthate 

Sodium ethylxanthate 

Sodium Isopropylxanthate 

•Formaldehyde,' 37^ HCHO by welght- 



Formamlde 

•Formic acid, 90l> 

•Formic acid salts: 
Aluminum formate— 
Ammonium formate- 
Calcium formate— 

Chromic formate 

Lead formate 

Nickel formate 

Potassium formate- 
•Sodlum formate: 
•Crude 



•Refined 
All other 

Fumaric acid 

Fumaryl chloride—— 
Gluconic acid, tech- 
Glutamlc aeid- 



Glycerol, synthetic 

Glycerol a -chlorohydrln (3-Chloro-l,2-propanediol) — 

Glycine (Aminoacetlc acid) , tech 

Glycine ethyl ester hydrochloride 

Glycolic acid (Hydroxyacetic aold) 



386, 388. 






ICK. 






386, 395. 






386. 
386, 395. 




•t 


386. 






258. 






258. 






258. 






257. 






257. 






482. 






258. 






423, 537, 


578. 




562. 






328, 537, 


578, 




562. 






562. 






139, 530, 


537, 578. 




530, 537, 


578. 




537. 






«3. 






417, 537, 


578. 




466. 






466. 






466. 






466. 






466. 






466. 






466. 






466. 






466. 






517. 






333. 






466. 






333, 385, 


466, 




385. 






385. 






333. 






333. 






335. 






335. 






335. 






335. 






216. 






466. 






335, 466. 






335, 466. 






120, 169, 


208, 225, 290, 312, 332, 363, 


396, 408, 417 


489, 493, 537, 540, 546, 569, 




537. 






307, 537, 


569. 




307, U5, 


562, 595. 




274, 447, 


524. 




225. 






384. 






404. 






136, 275. 






247, 447. 






214, 307, 


540, 569, 




201, 524, 


540, 




319. 






208, 403. 






403. 






528. 






158. 






477, 567. 






141, 447, 


495, 513, 




240, 447. 






240. 






537. 







148 



UNITED STATES TARIFF COMMISSION 



TAHLE 2f>li.- -Synthetic organic chemicals: Hiscellaneous chemicals for which United States producti 
sales were reported, identified by manufacturer, 1954- -Continued 



MISCELLANEOUS CHailCALS, ACYCLIC — Continued 



Glycolonltrlle 

Olyoxal- — 

Guanidine carbonate 

Guanldine hydrochloride 

4-Guanyl-l-isonltro8oguanyl-l-tetraz6ne- 

Guanylurea (Amldinouraa) phosphate 

Guanylurea sulfate 

»Halogenated hydrocarbons: 

l-Bromobutane (n-Butyl bromide) - 



2-Bromobutane (sec-Butyl bromide) 
Bromochloromethan o — — — — 

l-Bromo-3-chloropropane (Trimethylenechloro- 
bromlde) , 

Bromoethane (Ethyl bromide)- 

1-Bromohexadecane (Cetyl bromide) - 



l-Bromo-2-methylpropane (isobutyl bromide) - 
l-B^omo-octadecane- 



1-Bromopentane (n-Ainyl bromide) 

2-Bromopentane (1-Methylbutyl bromide) - 

l-Bromopropane (n-Propyl bromide) 

2-Bromopropane (laopropyl bromide) 

3-Bromcipropene (Allyl bromide) 

Bromotrifluoromethane 

»Carbon tetrachloride 

•Chlorinated paraffins: 

"Less than 35lt chlorine 

•35$-6<i^ ohlorlne- 



•65^ or more chlorine 
1-Chlorobutane (n-Butyl chloride) - 

l-Chloro-l,l-difluoroethane 

Chlorodlfluoromethane 

•Chloroethane (Ethyl chloride): 
Tech 



•Chloroform: 
•Tech 



•Chloromethane (Methyl chloride) : 
Crude- 



Refined, refrigerant grade 

l-Chloro-3-methylbutane (Isoamyl chlorido) 

2-Chloro-2-methylprctpane (tert-Butyl chloride)- 

l-Chloropentane (n^Amyl chloride) 

Chloropentanes, mixed isomers 
2-Chloropropane (Isopropyl chloride) 

3-Chlorciprcipene (Allyl chloride) 

Chlorotrifluoroethylene 

Chlorotrifluoromethan o 
Dlbromodifluoromethans- 



1,2-Dibromoethane (Ethylene dibromlde)- 
Dlbromomethane (Methylene bromide) - 



1,3-Dibromcipropajie (Trlmethylene dlbromide)- 
1 , 'V-Dichlorobutane- 



Dlchlorodifluoromethane 

»1,2-Diohloroethan8 (Ethylene dichloride)- 
•Dlchloromethane (Methylene chloride) ; 
Crude ■ 



Refined, refrigerant grade- 
Dichloropentanea, mixed iaomera- 



1,2-Dlchloropropaiie (Propylene dlchlorlde)- 

Dichlorotetrafluoroethan o 

I,l-Difluoroethaj6- ■■ 

Dilodomethane 

Hexachloroethane- 



lodoethane (Ethyl iodide), teoh- 
lodoform- 



lodomethane (Methyl Iodide), teeh- 
•Lauryl chloride i 
Crude 



Pentaehloroethap o 

1,1,2,2-Tetrabromoethaiie (Acetylene tatrabromlde)- 
1,1,2,2-Tetrachloroethane (Acetylene tetra- 
chloride) . 
•Tetraohloroethylene (Perchlaroothyl»ne)- 



1,1,1-Triehloroethaiie (Methyl ohloroform)- 
1,1,2-Trlchlcroethane (Vinyl trlchlorlde)- 
•Tri chloroethylene- 



Manuf acturers ' identification numbers 
(according to list in table 27) 



Trichlorofluoromethane- 



417, 466. 








562. 








466. 








356. 








X. 








466. 








466. 








335, 420, 


500. 






168, 274, 


335, 


500, 


X. 


263, 347. 








79, 263, 


335. 






263, 279, 


335. 






335, 500. 








335, 500. 








384, 500, 


537. 






335, 500, 


513. 






168, 274, 


420, 


500. 




335, 500, 


513. 






335, 500. 








335, 500. 








537. 








234, 335, 


392, 


398, 


435, 466. 


546, 549, 


X. 






214, 398, 


549. 






398. 








562, 580. 








524. 








524, 537. 








214, 222, 


234, 


335, 


339, 537 


335, 567. 








153, 220, 


335, 


537. 




123, 153, 


220, 


335, 


438. 


71. 








71, 123, 


220, 


335, 


537. 


274, 500. 








500, 513. 








500, 517. 








517. 








335. 








567. 








524, 537. 








537. 








537. 








335, 347, 


435, 


558, 




335, 513. 








335. 








537. 








524, 537. 








208, 234, 


335, 


339, 


363, 398 


123, 220, 


335. 






220, 335, 


537. 






517. 








335, 562, 


574. 






524, 537. 








524. 








376. 








501. 








500, 513. 








376, 








U7, 480, 


500. 






325, 384, 


456 


537 


549. 


325, 384, 


537 


549 




537. 








335. 








537. 








335, 398 


475 


537 


552. 


335. 








562. 








63, 335, 


537, 


552. 




524, 537 









SYNTHETIC ORGANIC CHEMICALS, 1954 



149 



TAEU 2f!B. --Synthetic organic chanicala: tiacellaneoua chemicals for which United Statea production or 
aales were reported, identified by manufacturer , 7954- -Continued 



KtSCZLLAMECfDS CHEMICA13, ACICLIC — Continued 



•Halogenated hydrocarbons— Ccntlnuod 
1 , 2 , 3-Trl ohlaropropane- 



Trlohlorotrlfluaroethan*— — ^— — ^— 
TrlTluoroniethaiie— — ■ 

Trifluorovliiyl chloride, polymerized—— 
"Vinyl ohlarlde (Chloroethylene), monomer- 
Vinyl fluoride— • 

Vlnylldene chloride, monomer- 



All other halogenated hydroearbonft-- 
3-Het)tanol 

2-Heptanone (Methyl anyl ketone) 

3^6ptanone (Ethyl butyl ketone) 

n-Heiadecarie 
l-Hexadecene- 



Hexamethylenedlaimnonlum adipate- 

Hexyl alcohol 

Hexyl alcohol mixture 

n^eiyl ether 

Hydrazine and salts- 



Hydrogenated tallow amld o 
N-(2^1ydroxyethyl)-N-(2-etearoylainlnoethyl) glycine, 

aodlujn salt. 
N-2-Hydroxyethylthloglycolainlde- 



ii-Rydroxylsobutyrlo acid esters, mixed 

ouHydroxylsobutyronltrlle (Acetone cyanhydrln) — 
2-(Hydroxymethyl) -2 -methyl -1, 3-propanedlol 

(Trlmethylolethane) . 
2-(Hydroxynethyl) -2 -nltro-1, 3-propanedlol 

(Trls(hydroxymethyl)nltromethfine) . 
N-Hydroxymethylstearamlde (N-Methylolstearamlde) - 

P,P '-Inlnodlprqplonltrlle 

Inositol hexanltrate- 



laethlonlo acid (2-Hydroxyothaxie3uironlc acid)- 
laobutyraldehyde 

Isobutyric acid 

Isobutyrlc anhydrlde- 



Iso-octyl alcohol ( 6-Methyl-l-hBptanol) - 
Isopropanolamlnes : 

Monoisopropanol Hnii ne 

Dllsopropanolamine- 



Manuf acturera ' Identification numbers 
(according to list In table 27) 



Trllaqpropanolamlne- 
Mixed 



Isopropoxypropylamlne— — — — 
Isopropyl acetate 
•Isoprqpyl alcohol (Isopropanol) : 
91^- 



1005t- 



Isoprqpyl chloroformate- 
»Isoprapyl ether 

Isovaleric acid, 90^ 

»Laotlc acid, lOC^: 

•Edible 



"Medicinal 

"Technical 

Lactic acid salta: 

Calcium lactate 

Potassium lactate- 

"Sodlum lactate 

Strontium lactate- 
All other 
Lactide 



Laetonltrlle 

Lauroyl acid phosphate and derlvativos- 
Lauroyloxyaoetio acid 
Lauroyl peroxide 

Lead soaps of oxidized hydrocarbons—^— 
"Llnoleic acid salts; 
Aluminum linoleate 



Ammonium linoleate- 
"Calcium linoleate— 
"Cobalt linoleate— 

Copper linoleate— 

Iron linoleate 
"Lead linoleate 



Lead manganese linoleate- 
•Manganese linoleate- 



"Lubricatlng oil additives: 

Barium aliyl dlthlophoaphate- 
Chloronaphtha xanthate- 



Hlgh molecular weight hydrocarbons and their 
phosphorus derivatives. 



567. 
52*, 

537. 
549. 
208, 
537. 
335. 
234, 
562. 
562. 
562. 
537, 
578. 
537. 
562. 
169. 
562. 
313, 
333. 
X. 



537. 

335, 398, ASA, i77, 487, 562. 

500, 574, 578. 

578, 
363, 540. 



298. 

417. 

417, 466, 537. 

225. 

290. 

537, 
466. 
257. 
384, 
496. 
495, 
495. 
286, 423. 



335, 


562, 






562. 








562. 








562. 








466. 








423, 


495, 


562. 




562. 








423, 


567 


X. 




475. 








423, 


562 


567. 




125. 








282, 


287 


390 


537. 


537. 








282, 


287, 


390, 


537. 


282, 


327 


390 




390, 








223, 


390 


465 


540. 


327. 








319, 


390. 






287. 








466. 








307. 








450. 








5, 317. 






294. 








327. 








85. 








85, 


159, 


273, 


470. 


85, 


136, 


223, 


275, 470 


136. 








136. 








85, 


136, 


223, 


273, 470 


136, 


223 


470 




85, 


136, 


273, 


470. 


466 


548 






208. 








54A. 









150 



UNITED STATES TARIFF COMMISSION 



TABLE 2f^. -Synthetic organic 
sales were 



chemicals: Miscellaneous chemicals for which United States producti 
reported, identified by manufacturer , I954--Continued 



MISCELLANEOUS CHiMICALS, ACYCLIC — Continued 

•Lubricating oil additlvea^ontinued 
Octyl formal- 



Oxidized hydrooarbona — — ■ — 

Phosphoaulfurized mineral oil — 

Polymethacrylates, diethylamlnoethyl and lauryl, 
mixed. 

Sulfocblorlnated oila^ ~- — 

Sulfurized lard oil— ■ ~ 

Sulfurized sperm oil- 



Zinc alkyl dithlophosphate 

All other- ■ — - 

Maleic acld^ — 

Malelc acid, trlbaalc lead salt- 

f»Malele anhydride 

Malic acid^ 

Malonic acid ■ ■ 

Mannltol- 



Mannitol hexaacetate- 
Mannitol hexanitrate- 
Mesltyl oxide- 



Methacrylamide— 

Methaorylatea, above methyl 

Methacrylle acid 

Methacrylic acid, sodium salt- 

•Methanol, synthetic 

Methoxypolyethylene glycol 

3-Methaxyproplonitrlle 

3-Methoxypropylamine 

Methoxytriglycol acetate 

•Methyl acetate 
Methyl acetone acetal 
Methyl acid phosphates 
Methyl aery late, monomer 
Methylal (Dlmethoxymethane) — 
Methylbutanol- 



Methyl cyanoacetate^ 

N,N'-Methylenebls[2-imlnopropianic acid]- 

N,N'-Methyl9nebi3-stearamide 

Methylenecltrlc acid- 



Methyl ether (Dimethyl ether) 

Methyl ethyl ketone (2-Butanone)— 

Methyl ethyl ketone mixture ■ 

Methyl ethyl ketone peroxide ■ ■ 

Methyl ethyl ketoxime- ■ 

Metl^l formate — — 

N-«ethylglucamlne — — 

N-Methylglycine— — ■ 

Methyl glycolate (Methyl hydroxyacetate) 

4-Methyl-2-hexaiicin6^ ^ 

l-Methyllsobutylcarbinol (4-Methyl-2-p9ntanol) 

l-Methylisobutylcarbinyl acetate (4-Methyl-2-amyl 

acetate) . 
Methyl lactato- 



Methyl magnesium bromide 

Methyl methaorylate, monomer- 



2-Methyl-2-nltro-l,3-propapedlol 
2-Methyl-2-nltro-l-propanol 
2-Methyl-2,'i-pontanedlol (Hoxylene glycol) — 
<methyl-2-l)entanone (Methyl isobutyl ketone) - 
M9thylpentynol- 



Methylp olyethajiolamine ■ 

Methyl sulfate (Dimethyl sulfate) — 

N-Methyltaurlne 

Methyl vinyl ether 
Mucochlorio acid 

Nltroothane— — ■ 

mtromethane 
l-Mltropropane — ■ 

2-Nltropropane— — 

Nylon (Polyhexanethylene adlp«iiilde)- 
l-Octadecene- 



Ootadeeyl laocyanate 

•1-Octanol — 

•2-Clotanol — 

2-Octanone (Hexyl methyl ketone) - 

Ooteno-2— 

Octyl acid phosphates 

n-Cctyl mercaptan ■ 

Octyl oleyl maleate- 



Octylsulfuryl chloride 

Oleamide (Octadecone amide)- 



Manufacturers' identification numbers 
(according to list In table 27) 



567. 
29A. 
A50. 
537. 

188, 450. 

188. 

188, iSO. 

466, 548. 

208, 466, 549. 

403, 584. 

404. 

208, 403, 4S9, 562. 

403, 412. 

191. 

257. 

257. 

257. 

562, 567. 
417. 

417, 537. 
417, 537. 

417. 

120, 169, 290, 327, 332, 363, 493, 537, 562. 

562. 

466. 

466. 

562. 

541, 562, X. 

493. 

307. 

417. 

169. 

226. 

335, 396. 

443. 

333. 

247. 

177, 537. 

495, 562, 567, X. 

169. 

5, 317. 

403. 

537. 

537. 

466. 
537. 

274. 

562, 567. 
562. 

287. 

152. 

147, 417, 537, 

290. 

290. 

562, 567. 

562, 567. 

226. 

384. 

537. 

384. 

364. 

513. 

290. 

290. 

290. 

290. 

537. 

578. 

208. 

395, 537, 578. 

139, 417. 

417, 584. 

417. 

307. 

578. 

208. 

549. 

333. 



SYNTHETIC ORGANIC CHEMICALS, 1954 151 

TABL£ 26B. -'Syrithetic organic chemicals: Miacellaneoua cheaticaia for which United Statea production or 
aalea were reported, identified by manufacturer, / 9 54 --Continued 



Masuf aoturara ' Identlfloatlon mimbars 
(according to list In tatle 27) 



MISCZLLiJffiCUB CESGCAI^, ACTCIJC— ContlnuBd 



»01»lc acid salts: 
<tAJ.uinlnum olsat»- 



Barlun zinc oleats- 



Calolxim soap of liTdrozTolslc aold- 
Chronlum ol»ate 
Cc5ip«r oleat» 

Lsad olsate 

All other ■ ■ 



Oleoyl ohlorlde- 
•Qxallc acid 



»Oiallc acid salts: 
AjmaonluiD Gocalato— 
Calcium oxalate— 



Ferric ammonium oxalate— 
Ferric oxalate 
Ferric potassium oialate- 
Ferrlc sodium oxalate 
Ferrous oxalat o 



Potassium blnoxalate- 

Potasslum oxalate 

Sodium oxalate 



Oxidized hydrocarbons, cither than lubricating oil 
additives. 

Oxobutyraldehjde (Farmylacetone), dimethyl acotal- 

Palmltlc acid salts: 

Aluminum palmltate ■ 

Zinc palmltate ' ' 

Palmitoyl chloride 

Paraformaldehyde 

Paraldehyde (Paracetaldehyde) 

Pelargonic acid (Nonanoic acid) 
»Pentaerythritol 
•Pentaerythritol tetranltrate 

1,5-^antanedlol 

Perchloromethyl mercaptan 

Phosgene (Carbonyl chloride) 

Pine oil, synthetio- 



«Polyacrylic acid, potassium salt- 
•Polyacrylic acid, sodium salt 

Poljrecrylonitrll o 

Polyethoxyethylsorbltol 

Polyethylene glycol 

Polyglyeerol 

Polypropylene glycol 

Propionaldehyd o 
»Prpplonio acid 

Propionic acid salts: 

Calcium prqpionate 

Sodium propionate 
Zinc propionate 

Propionic anhydrid e 

Prppionyl chloride 

n-Propyl acetate— 



n-Propyl alcohol (Prqpanol) ' 

a -Propylene chlorohydrln ( l-Chlaro-2-propanol) - 

•Propylene glycol (l,2-Prcipan9dlol) 

Propylene glycol ethers, mixed 
Propylene glycol glycolate 
Propylene glycol methyl ether 
Propylene oilde- 



Prppyl isocaproate (Propyl Isobutylacetate) - 
n^^opyl nitrat e 
Pyruvic acid 



Heaearch chemicals: 

AlVenyl succinic anhydrldes- 
Creatlnin o 



EthOTB and tblosthers- 
Halogen confound s 
Nltriles 



Phosphites and phosphates- 
Rare sugars 
Silanes 



•Riclnolelc acid salts: 
Aluminum rlclnoleate- 
Barium ricinoleate— 
Cadmium ricinoleate— 
Calcium ricinoleate — 
Sodium ricinoleate— 



85, 128, 


327, 388, 


470. 




136. 








388. 








136. 








85, 470. 








85, 128, 


136, 470. 






327. 








139, 170, 


384. 






100, 307, 


524, 528. 






201, 327, 


524, 528. 






307. 








528. 








528. 








528. 








528. 








480, 








201, 524, 


540. 






201, 524, 


528. 






201, 307, 


327, 524, 


540. 




524. 








294. 








396. 








128, 159, 


388. 






128, 159, 


388, 466. 






325, 374, 


384. 






169, 537, 


569. 






562. 








395, 467. 








2U, 225, 


238, 290, 


489, 556 


590 


2U, 225, 


257, 537. 






537. 








503. 








475. 








108, 214. 








487. 








301, 417, 


466, 487, 


568. 




257. 








257. 








234, 335, 


363, 562. 






208, 424, 


X. 






335, 562. 








281. 








169, 290, 


495, 537. 






169, 390, 


U7, 537. 






169, 537. 








201, 447. 








495, 562. 








lAl, 374. 








169, 374, 


415. 






125, 169, 


537. 






562. 








169, 335, 


537, 562, 


574. 




335. 








256. 








335. 








169, 335, 


562. 






290. 








339. 








466. 








578. 








412. 








578. 








500. 








466, 500 








187. 








412. 








134, 547. 








53, 152, 


226, 242, 


319, 335, 


384, 


159. 








103. 








103, 136. 








103, 256. 








103. 









152 



UNITED STATES TARIFF COMMISSION 



TABLZ 2f!B.--Synthetic organic chemicals: tiacellaneoua chemscala for which United Statea production or 
sales were reported, identified by manufacturer , i954--Continued 



Hanuf actursrs ' Idantlflcatlon numbers 
(accanling to Hot In tatlo 27) 



MISCELUUSODS CBUCLCALS, ACtCLXC— Castlnaed 



•Sarooaln* (H-Jtothylaminoacetlo aold)- 
Sebaclo acid 
Sebacle anhjdrld o 
Ssndcarbazlde baa o 



Semlcsrbazlda hydrochlarld o 
Sequarterlug agents: 

fDlethylenetrlnltrllo)p«ntaaoetlo aold- 



N,N.J)l(hydroiyethyl) glycine, sodium salt 
(Ethyl8nedinitrilo)tetraacetlo acid (Ethylane- 

diamlnetetraacetic acid) . 
(Khylenedinitrllo)tetraac9tle acid, ealoium ealt- 
(Ethylenedinitrilo)tetraaoetio acid, copper salt — 
(Ethylonedinltrilo)totraacetio acid, diammonlum 

salt. 
(EthylenedinitriloHetraaoatic acid, diaodium salt 
(Ethylenodinitrilo)t6traacetic acid, dlsodium Iron 

salt. 
(Ethylenedinitrilo)tetraacetic acid, magnesium 

salt. 
(Ethylonedinltrilo)t»traacetic acid, manganese 

salt. 
(Kthylonedinltrilo)tetraaoetle acid, moMSodlum 

Iron salt. 
»(Ethylenedinitrilo)tetraacetic acid, tetrasodiuB 

salt. 
(Ethylenedinitrllo)tetraacetic acid, trisodium 

salt. 
(Ethylonedinltrilo) tetraacetic acid, zlno salt— 
N-(Hydroiy«thyl)stbylenedinitrilatriacetic acid, 

trisodium salt. 
Silicones, fluids and greases 
Sodium ethoxid o 



Sodium ethyl oialacetat o 
Sodium fornaldehyde bisulfite— 
•Sodium formaldehyde sulf oiylate- 
Sodium isopropoxide- 



Sodlum methoxlde (Sodium methylate)- 
Sodium sorbitol borate 

Sorbitol 

Soya nitril o 

Stearamide (Octadecane amide) 
Stearamide-palmitamide 
Stearamldo«Bethylcarbamide polymers— 
•Stearic acid salts: 
•Aluminum stearates: 

•Aluminum monostearat o 

•Aluminum dlstearate 



•Aluminum trlstearate— 
Ammonium stearate 

Barium stearate 

Cadmium stearat e 

•Calcium stearate 
Cobalt stearat e 
Ferric atearat o 

•Lead stearate 
Lead stearate, dibasic- 
Lithium hydraxystearate- 

•Lithium stearat e 

•Magnesium stearat e 

•Zinc stearat e 
All other 

Stearoyl chloride 

Succinic acid 



Succinic acid, sodium salt- 
Sucoinlc anhydrid e 

Suceinonitrll o 



Sucrose octaacetate- 



Tallow fatty acyl chloride 
Tartaric acid salts, nonmedislnal- 
Tetraethylane glycol- 



Tetraethylene glycol dimethyl ethar (Bis{2-(2- 

mothoxyethory) ethyl] ether) . 
Tetraethyl lead- 



Tetraglyclne hydroperiodid o 

TetrahydroxyBuocinie acid (Dioxytartaric aeid)- 
Tetralds(2-hydroocypropyl) ethylenediamine 
Tetraootyl orthosilicat e 



223, 38A, U3, 537. 

139, *17. 

355. 

313. 

313, A80. 

595. 

572. 

81, 38-;, 572, 595. 

595. 
595. 
595. 

595. 

572. 

595. 

595. 

3a;, 595. 

38-;, 388, 572, 595. 

572, 595. 

595. 
572, 595. 

13-1. 

208, 279, -;i5, 527. 

*15. 

396, 513. 

330, -117, U5, 537. 

527. 

279, 363, 527, X. 

257. 

257, 528. 

333. 

333, 537. 

385. 



91, 121, 128, 159, 327, 388, A65, 466. 

91, 121, 128, 159, 327, 388, ^5, *66. 

91, 121, 128, 159, 273, 327, 388, 465, -«6. 

26, 128, 159, 388. 

91, 121, 128, 159, 388, <;65. 

128, 388. 

91, 121, 128, 159, 327, 388, 465, 466, 

465. 

128, 465. 

121, 128, 136, 159, 388, 404, 465. 

128, 404. 

128. 

91, 128, 159, 293, 388. 

91, 121, 128, 159, 327, 388, 465, 466. 

91, 121, 128, 159, 327, 388, 465, 466. 

257. 

325, 384, 456. 

152, 403. 

327. 

208, 403. 

152, 403, 513. 

466. 

562. 

384. 

319, 327, 540. 

335. 

ru 

339, 537. 

152, 420. 
466. 
574. 
208. 



SYNTHETIC ORGANIC CHEMICALS, 1954 153 

TABL£ 2SB.- -Synthetic organic chemicala: Miscellaneous chemicala for which United States production or 
aales were reported, identified by "amfacturer , J9i<- -Continued 



Manufacturers' Idontlflcatlan mimbara 
(according to llBt In table 27) 



mSCZLLAKEOnS CHHCCAL5, ACTCLIC — Cantljwod 



Thiamine hydrobromlde- 
Thloaeetamlde- 



Thloaoetic aold (Sulfoacotlo aeld)- 
TMoglycerol- 



TMogljcollc aold (Mercaptoaoetio aold)- 
TMoglyoolle acid derivatives: 
vAsnonlum thioglycolat o 

Calcium thioglycolate 

Iso-octyl thiogljoolate 

Sodium thloglyeolat o 
Thioaortitol 
Thiourea 



Trlaliyl stearyl ammonium ethyl phosphit e 

Trlallyl eyanurat o 

Trichlaroethylsilane (Ethyl silicon trichloride) - 

Triehlorohaiadacylsllane 

Trlehlaronethylsllan o 

Triehlooro-octadecy l s l l f m » 

Trlchlorovinylsilane- 



Trlethanolaalne phoaphat o 
Trlethyl citrat e 
•Trlethylene glycol 
Triothylene glycol dichlorldo (2-(2-Chlaroethcay)- 

ethyl 2-chlaroothyl other). 
Trlethyl orthoacetat o 
Trlethyl arthxaformate 
Triiso-octyl phosphit e 
Trimethyl orthoformate 
Triprppylene glyeol- 



Tripropylene glycol, methyl ether- 
Tris(2-ethylheiyl) phosphite- 



Cndocylenle acid (Hendeoenoic acid)- 
Urea, aolid- 



Urea in feed ccii5>ounda 

Drea In solid fertilizer 

Urea In urea^umnonia solution 

Urea arthophosphat o 

Urea, other 
•Vinyl acetate, monomer 

Vinyl stearate 

Xanthlc aold, ethyl, sodium salt— 
•Zinc formaldohydesulfaxylate— — 



5^. 
513. 
513, 
298. 
115, 298. 

115, 298, 379, 480. 

298. 

298. 

298, 453. 

537. 

208. 

257. 

466. 

134. 

134. 

134. 

134. 

134. 

536. 

528. 

234, 335, 363, 562. 

562. 

513. 

396. 

187. 

396. 

335. 

335. 

187. 

103. 

26, 332, 537. 

332, 537. 

332, 361, 537. 

332, 537. 

208. 

332. 

169, 537, 562. 

226. 

537. 

330, 417, 445, 537. 



154 UNITED STATES TARIFF COMMISSION 

Directory of Manufacturers 

The Directory of Manufacturers lists the companies that report 
their production of synthetic organic chemicals to the Tariff Com- 
nnission. The name of each manufacturer is preceded by an identi- 
fication number. 

For 1954, the Directory of Manufacturers lists 605 companies 
(see table 27). This is 3 less than the number that reported for 
1953. Some of the companies that report production of synthetic 
organic chemicals consume their entire output in further manufac- 
turing. 

The Directory of Manufacturers lists the companies in two ways, 
Section 1 lists them in numerical order, the identification number 
for each company having been assigned in the order in which the 
Commission received the company's reporting schedule. This sys- 
tem makes it unnecessary to wait until all the schedules are re- 
turned before assigning the identification nunnbers, and greatly 
speeds the preparation of the tables in part 111. Section 2 lists the 
companies in alphabetical order. 



SYNTHETIC ORGANIC CHEMICALS, 1954 155 

TAELE 27 . --Synthetic organic chemicals: Directory of manufacturers, 1954 

SECTION 1. NUMEEICAL DIRECTORY 

[ Names of synthetic organic chemical manufacturers who reported production or sales to the United States 

Tariff Commission for 19^ are listed helow in the order of their identification numbers as used in 

tables in part III. Section 2 of this table lists these manufacturers alphabetically and gives their 
offices and plant addresses] 



No. 


Name of company 


No. 


Name of company 


1 


Nilok Chemicals, Inc. 


74 


Miles Laboratories, Inc. 


2 


Alframlne Corp. 


75 


Remington Arms Co., Inc. 


3 


Northwestern Chemical Co. 


76 


Western Condensing Co. 


<; 


Atomic Basic Chemicals Corp. 


77 


Apex Chfflnlcal Co., Inc. 


5 


Cadet Chemical Corp. 


78 


Astra Pharmaceutical Products, Inc. 


6 


Bird & Son, Inc. 


79 


Edison, Thomas A., Inc. (Medical Gas Dlv.). 


7 


Hartman-Leddon Co. 


80 


General Tire & Rubber Co. (F. F. C.)^ 


8 


Knoedler Chemical Co. 


81 


Glyco Products Co., Inc. 


9 


Van Dyk & Co., Inc. 


82 


Keystone Color Works, Inc. 


10 


Vita-Var Corp. 


83 


Levey, Fred'k, H., Co., Inc. 


11 


Wilmot & Cassidy, Inc. 


84 


Meyer, J. , & Sons. 


12 


American Chemical Paint Co. 


85 


Shepherd Chemical Co. 


13 


American Viscose Corp. (Sylvania Div.). 


86 


Standard Agricultural Chemicals, Inc. 


U 


Barium Reduction Corp. 


87 


Armstrong Cork Co. 


15 


Blockson Chemical Co. 


88 


Atlas Processing Co. 


16 


Coopers Creek Chemical Corp. 


89 


Ottol Oil Co. 


17 


Farley & Loetscher Manufacturing Co. 


90 


Mlranol Chemical Co., Inc. 


18 


Hynson, Wescott & Dunning, Inc. 


91 


Parsons, M. W., Plymouth, Inc. 


19 


Sipe, James B., & Co. 


92 


Peerless Color Co., Inc. 


20 


Sonnebom, L., Sons, Inc. 


93 


Premo Pharmaceutical Laboratories, Inc. 


21 


Standard Chemical Co. 


94 


Siddall, George F., Co., Inc. 


22 


Raybestos Dlv. of Raybeatos-Manhattan, Inc. 


95 


Southern Textile Chemical Corp. 


23 


Chaffardon, J. 


96 


Wetherill, George D., Varnish Co. 


2A 


Canmonwealth Color & Chemical Co. 


97 


Harbor Plywood Corp. 


25 


Crown Tar i Chemical Works, Inc. 


98 


Huggins, James, S: Son, Inc. 


26 


Farrington, W. U., Estate of. 


99 


Nuodex Products Co., Inc. 


27 


Kehew-Bradley Co. 


100 


Oldbury Electro-Chemical Co. 


28 


Kentucky Color & Chemical Co. 


101 


Puget Sound Pulp & Timber Co. 


29 


Kohnstamm, H., & Co., Inc. 


102 


White & Hodges, Inc. 


30 


Mineral Oil Refining Co. 


103 


Baker Castor Oil Co. 


31 


Newport Industries, Inc. 


104 


California-Spray Chemical Corp. 


32 


Peerless Chemical Co. 


105 


Carpenter-Morton Co. 


33 


Plastics Engineering Co. 


106 


Clba States, Ltd. (Toms River Div.). 


3^ 


Pratt & Lambert, Inc. 


107 


Cleary, W. A., Corp. 


35 


Scholler Bros. , Inc. 


108 


Crosby Chemicals, Inc. 


36 


Taylor Fibre Co. 


109 


Crown Chemical Corp. 


37 


White & Bagley Co. 


110 


Dakota Briquets & Tar Products, Inc. 


38 


All-Tex Specialties Co. 


111 


Davis, H. B., Co. 


39 


Drug Processors, Inc. 


1L2 


Emkay Chemical Co. 


AO 


Gamma Chemical Corp. 


113 


Firestone Tire & Rubber Co. (F. F. C.)^ 


Al 


Hanna Paint Manufacturing Co. (Industrial 


114 


General Motors Corp. (AC Spark Plug Div.). 




Div.). 


115 


Halby Products Co. 


42 


Inland Steel Container Co. 


116 


M Sc M Wood Working Co. 


43 


Kyanize Paints, Inc. 


117 


Metro Dyestuff Corp. 


44 


Pennsylvania Industrial Chemical Corp. 


118 


El Paso Natural Gas Co. 


45 


Pine Bluff Chemical Co., subsidiary of Food 


119 


Poughkeepsie Dyestuff Corp. 




Machinery & Chemical Corp. 


120 


Spencer Chemical Co. 


46 


Searle, G. D., & Co. 


121 


Synthetic Products Co. 


47 


Amalgamated Chemical Corp. 


122 


Vanderbilt Chemical Corp. 


48 


American Marietta Co. 


123 


Allied Chemical i Dye Corp. (Solvay Process 


49 


Bates Chemical Co. 




Dlv.). 


50 


Bios Laboratories, Inc. 


124 


Bush, W. J., & Co., Inc. 


51 


Cabot, Samuel, Inc. 


125 


Frltzsche Brothers, Inc. 


52 


Copolymer Corp. (F. F. C.")^ 


126 


Polychemical Co. 


53 


Delta Chemical Works, Inc. 


127 


Snyder Chemical Corp. 


54 


Ellzabethtown Consolidated Gas Co. 


128 


Wltco Chemical Co. 


55 


Fine Colors Co. 


129 


Grand Rapids Varnish Corp. 


56 


Industrial Products, Inc. 


130 


Indoil Chemical Corp. 


57 


Ironsides Co. 


131 


Marlowe-Van Loan Corp. 


58 


Kalide Corp. 


132 


Norda Essential Oil & Chemical Co., Inc. 


59 


Laurel Soap Manufacturing Co., Inc. 


133 


Rubber Corp. of America. 


60 


Borg-Wamer Corp. (Marbon Chemical Div.). 


134 


Dow Coming Corp. 


61 


Marden-Wlld Corp. 


135 


Great Southern Chemical Corp. 


62 


Minnesota Paints, Inc. 


136 


Harshaw Chemical Co. 


63 


Niagara Alkali Co. 


137 


Petrolite Corp. (Tretolite Co. Dlv.). 


64 


Old Hickory Chemical Co., Inc. 


138 


Uhllch, Paul, & Co., Inc. 


65 


Red Spot Paint & Varnish Co., Inc. 


139 


Wallace & Tleman, Inc. (Harchem Div.). 


66 


Richardson Co. 


140 


Cutter Laboratories. 


67 


Soluol Chemical Co., Inc. 


Ul 


Fries Bros., Inc. 


68 


Spaulding Fibre Co., Inc. 


142 


Magnolia Petroleum Co. 


69 


Treplorw Products, Inc. 


143 


Organios, Inc. 


70 


American Viscose Corp. 


144 


Pan American Refining Corp. 


71 


Ansul Chemical Co. 


145 


Sumner Chemical Co., Inc. 


72 


Strong, Cobb & Co., Inc. (American 


146 


Com Products Refining Co. 




Chlorophyll Div.). 


U7 


U. S. Plastic Products Corp. 


73 


Appleton Coated Paper Co. 


148 


Krumbhaar Chemical Co., Inc. 



See footnote at end of table. 



156 



UNITED STATES TARIFF COMMISSION 





TABLE 27. --Synthetic organic chemicals: Directory 


of manufacturers , 1954- -Continued 


No. 


Name of ccmpany 


No. 


Name of company 


U9 


U. S. Oil Co. 


229 


Chemico, Inc. 


150 


United States Procaine Co., Inc. 


230 


Peck's Products Co. 


151 


Watertoun Manufacturing Co. 


231 


Texas Co. 


152 


Arapahoe Chemicals, Inc., & Arapahoe Special 


232 


Upjohn Co. 




Products, Inc. 


233 


Berk, F. W., & Co., Inc. 


153 


Brown Co. 


234 


Jefferson Chemical Co., Inc. 


154 


Florasynth Laboratories, Inc. 


235 


Onyx Oil & Chemical Co. 


155 


General Color Co., Inc. 


236 


Smith, Kline & French Laboratories. 


156 


General Tire 4 Rubber Co. (Chemical Div.). 


237 


Wilson Organic Chemicals, Inc. 


157 


Oilman Paint & Varnish Co. 


238 


Delaware Chemicals, Inc. 


158 


International Minerals & Chemical Corp. 


239 


Shulton, Inc. (Fine Chemicals Div.). 


159 


Leffingwell Chemical Co. 


240 


Benzol Products Co. 


160 


Pfister Chemical Works, Inc. 


241 


Cosden Petroleum Corp. 


161 


Seattle Gas Co. 


242 


Halogen Chemicals, Inc. 


162 


Staley, A. E., Manufacturing Co. 


243 


National Polychemicals, Inc. 


163 


Sterling Drug, Inc. (Bayer Co. Div.). 


244 


Salvo Chemical Corp. 


164 


Western Dry Color Co. 


245 


Specialty Resins Co. 


165 


Westinghouse Electric Corp. 


246 


Wamer-Jenkinson Manufacturing Co. 


166 


Wheeler, Reynolds &. Stauffer. 


247 


Wlnthrop-Steams, Inc. 


167 


American Aniline & Extract Co., Inc. 


248 


Burroughs-Wellcome 4 Co. (U.S.A.), Inc. 


168 


Blackman Brands, Inc. 


249 


Douglas Chemical Corp. 


169 


Celanese Corp. of America. 


250 


Foster-Heaton Co. 


170 


DePaia Chemical Co., Inc. 


251 


Kem Products Co., Inc. 


171 


Dexter Chemical Corp. 


252 


Maas 4 Waldstein Co. 


172 


Food Machinery & Chemical Corp. (Ohio-Apex 


253 


National Chlorophyll 4 Chemical Co. 




Div.). 


254 


Sandoz Chemical Works, Inc. 


173 


Gordon Chemicals, Inc. 


255 


Acme Resin Corp. 


174 


Lakeside Laboratories, Inc. 


256 


Advance Solvents 4 Chemical Corp. 


175 


Lebec Chemical Corp. 


257 


Atlas Powder Co. 


176 


Neville Chemical Co. 


258 


El Dorado Oil Works. 


177 


Norwich Pharmacal Co. 


259 


Firestone Plastics Co. Div. of Firestone 


178 


Ortho Chemical Corp. 




Tire & Rubber Co. 


179 


Oxford Corp. 


260 


Fuller, W. P., 4 Co. 


180 


Parke, Davis & Co. 


261 


Humble Oil 4 Refining Co. 


181 


Publicker Industries, Inc. 


262 


LaMotte Chemical Products Co. 


182 


Quaker Chemical Products Corp. 


263 


Michigan Chemical Corp. 


183 


Sohieffelin & Co. 


264 


Pacific Paint 4 Vamiah Co. 


184 


Union Oil Co. of California. 


265 


Patent Chemicals, Inc. 


185 


United States Pipe & Foundry Co. 


266 


Paul -Lewis Laboratories, Inc. 


186 


Velsicol Corp. (Div. of Arvey Corp.). 


267 


Stange, Wm. J., Co. 


187 


Virginia-Carolina Chemical Corp. 


268 


Synthetic Chemicals, Inc. 


188 


Carlisle Chemical Works, Inc. 


269 


Varcum Chemical Corp. 


189 


Continental Oil Co. 


270 


American Marietta Co. (Ferbert-Schomdorfer 


190 


Chase Chemical Corp. 




Co. Div.). 


191 


American Bio-Synthetics Corp. 


271 


California Ink Co., Inc. 


192 


Cargill, Inc. 


272 


Dawe's Laboratories, Inc. 


193 


Cities Service Refining Corp. (F. F. C.)^ 


273 


Jones-Dabney Co. 


194 


Merrell, Wm. S., Co. 


274 


Lilly, Eli, 4 Co. 


195 


Morwear Paint Co. 


275 


McGean Chemical Co. 


1% 


Reliance Varnish Co., Inc. 


276 


Portland Gas 4 Coke' Co. 


197 


Specific Pharmaceuticals, Inc. 


277 


Colgate-Palmolive Co. 


198 


Tar Distilling Co., Inc. 


278 


Wilson Laboratories. 


199 


Tennessee Products & Chemical Corp. 


279 


Oane's Chemical Works, Inc. 


200 


Interchemical Corp. (Textile Colors Div.). 


280 


Industrial Dyestuff Co. 


201 


Baker, J. T., Chemical Co. 


281 


Stanolind Oil 4 Oas Co. 


202 


Baker, J. T., Chemical Co. (Taylor Chemical 


282 


American Maize Products Co. 




Div.). 


283 


France, Campbell 4 Darling, Inc. 


203 


Booty Reslneers, Inc. 


284 


Nepera Chemical Co., Inc. 


204 


Dow Chemical Co. (Styrene Div.). (F. F. C.)^ 


285 


Humble Oil 4 Refining Co. (F. F. C.)^ 


205 


Grain Processing Corp. 


286 


Oulf Oil Corp. 


206 


Inland Alkaloid Co. 


287 


Clinton Foods, Inc. 


207 


Lewis Tar Products Co. 


288 


Ohio Chemical 4 Surgical Equipment Co. 


208 


Monsanto Chemical Co. 


289 


(Juaker Oats Co. 


209 


Richfield Oil Corp. 


290 


Commercial Solvents Corp. 


210 


Roosevelt Oil & Refining Corp. 


291 


Lever Brothers Co. 


211 


Soherer, R. P., Corp. 


292 


Lueders, George, 4 Co. 


212 


Swift & Co. 


293 


Maywood Chemical Works. 


213 


Morton-Withers Chemical Co. 


294 


Alox Corp. 


2W 


Hercules Powder Co. 


295 


Carus Chemical Co., Inc. 


215 


Osbom, C. J., Co. 


296 


Cook Paint 4 Vamiah Co. 


216 


Kemiecott Copper Corp. (Chlno Mines Div.). 


297 


Esso Standard Oil Co. 


217 


Continental-Diamond Fiber Co. 


298 


Evans Chemetics, Inc. 


218 


Maltbie Laboratories, Inc. 


299 


Frontier Chemical Co. 


219 


Werner Drug 4 Chemical Co. 


300 


Hampden Color 4 Chemical Co. 


220 


Belle Alkali Co. 


301 


Jordan, Jr., W. H., 4 F., Manufacturing Co. 


221 


Kali Manufacturing Co. 


302 


Ritter, F., 4 Co. 


222 


National Petro-Chemicals Corp. 


303 


Suntide Refining Co. 


223 


Sterling Drag, Inc. (Hilton-Davis Chemical 


304 


Purex Corp., Ltd. 




Co. Div.). 


305 


Lemke, B. L., 4 Co., Inc. 


224 


Synvar Corp. 


306 


Purocaine, Inc. 


225 


Trojan Powder Co. 


307 


Victor Chemical Works. 


226 


Air Reduction Chemical Co. 


308 


Carolina Aniline 4 Extract Co. 


227 


Atlas Refinery, Inc. 


309 


Metalsalts Corp. 


228 


Buckeye Cotton Oil Co. 


310 


Berkeley Chemical Corp. 



See footnote at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



157 





TABLE 21 .--Synthetic organic cheaicala: Directory 


of manufacturers. i95<- -Continued 


No. 


Name of company 


No. 


Name of company 


3U 


Southern Dyeatuff Corp. 


392 


Stauffer Chemical Co. 


312 


Durez Plastics & Chemicals, Inc. 


393 


Thcmasset Colors, Ins. 


313 


Falrmount Chemical Co., Inc. 


394 


Carwin Co. 


3U 


Modene Paint Co., Inc. 


395 


Glvaudan Corp. 


315 


Dr. Salahury's Latoratories. 


396 


Kay-Fries Chemicals, Inc. 


316 


Schenectady Varnish Co., Inc. 


397 


Schwarz Laboratories, Inc. 


317 


Wallace & Tleman, Inc. (Lucidol Dlv.). 


398 


Diamond Alkali Co. 


31B 


American Alcolac Corp. 


399 


Dye Specialties Corp., Inc. 


319 


City Chemical Corp. 


400 


Ford Motor Co. 


320 


Coastwise Petroleum Co. 


401 


May, Otto B., Inc. 


321 


Metro-Atlantic, Inc. 


402 


Rltter Chemical Co., Inc. 


322 


Ruberoid Co. 


403 


Allied ChfflBical t Dye Corp. (National Aniline 


323 


Shawinigan Resins Corp. 




Div. ) . 


324 


Sonoco Products Co. 


404 


National Lead Co. 


325 


Genesee Research Corp. 


405 


Keystone Paint & Varnish Corp. 


326 


Hart Products Corp. 


406 


Alkydol Laboratories, Inc. 


327 


MaUinolcrodt Chemical Works. 


407 


Azoplate Corp. 


328 


Procter t Gamble Co. 


408 


Borden Co. (Chemical Div.). 


329 


Pure Oil Co. 


409 


Buckman Laboratories, Inc. 


330 


Royce Cheanlcal Co. 


410 


Diamond Alkali Organic Chemicals Dlv., Inc. 


331 


Solvent Chemical Co., Inc. 


411 


Long, Chas. R., Jr., Co. 


332 


Allied Chemical & Dye Corp. (Nitrogen Div.). 


412 


Pfanstlehl Laboratories, Inc. 


333 


Armour & Co. (Chemical Div.). 


413 


R. S. A. Corp. 


2^ 


Burkart-Schler Chemical Co. 


4U 


Schering Corp. 


335 


Dow Chemical Co. 


415 


U. S. Industrial Chemicals Co. 


336 


Ferro Chemical Corp. 


416 


Huron Milling Co. 


337 


Keystone Chemurgic Corp. 


417 


Rohm & Haas Co. 


338 


van Amerlngen-Haebler, Inc. 


418 


United Piece Dye Works. 


339 


Ethyl Corp. 


419 


Wallace & Tleman, Inc. 


340 


Marx, Max, Color & Chemical Co. 


420 


Abbott Laboratories. 


341 


National Starch Products, Inc. 


421 


Ciba Pharmaceutical Products, Inc. 


342 


Bruder, M. A., & Sons, Inc. 


422 


Dykem Co. 


343 


Federal Color Laboratories, Inc. 


423 


Esso Standard Oil Co. (Louisiana Dlv.). 


344 


Merichan Co. 


424 


Goodyear Tire & Rubber Co. 


345 


Standard Chemical Products, Inc. 


425 


Harsyd Chemicals, Inc. 


346 


Sun Chemical Corp. (Pigment Div.). 


426 


Inrlngton Varnish & Insulator Dlv. of 


347 


American Potash & Chemical Corp. (Eston 




Minnesota Mining and Manufacturing Co. 




Chemicals Dlv.). 


427 


Kendall Refining Co. 


348 


Griffin Chemical Co. 


428 


Marathon Corp. 


349 


Maumee Chemical Co. 


429 


Oil & Chemical Products, Inc. 


350 


Peters Chemical Co. 


430 


Organic Chemical Corp. 


351 


Althouse Chemical Co . , Inc . 


431 


Oronlte Chemical Co. 


352 


Childs Pulp Colors, Inc. 


432 


Catalin Corp. of America. 


353 


Standard Naphthalene Products Co., Inc. 


433 


Collway Colors, Inc. 


354 


General Foods Corp. (Maxwell House Div.). 


434 


Goodrich, B. F., Chemical Co. (Div. of B. F. 


355 


Maschmeijer, A., Jr., Inc. 




Goodrich Co.). (F. F. C.)^ 


356 


New York Color & Chemical Co. Div. of American 


435 


Food Machinery & Chemical Corp. (Westvaoo 




Dyewood Co, 




Chlor-Alkall Dlv. & Uestvaco Mineral 


357 


Permutlt Co. 




Products Dlv.). 


358 


Standard Chlorine Chemical Co., Inc. 


436 


Eaklns, J. S., i; W. R., Inc. 


359 


Zxim, 0. F., Co. 


437 


Jenniaon-Wright Corp. 


360 


Bryant Chemical Corp. 


438 


Squibb, E. R., & Sons, Div. of Olln- 


361 


Deere & Co. (Grand River Chemical Div.). 




Mathleaon Chemical Corp. 


362 


Heresite & Chemical Co. 


439 


Atlantic Refining Co. 


363 


Olln Mathieson Chemical Corp. 


440 


Anderson Laboratories, Inc. 


364 


Schuylkill Chemical Co. 


441 


Deecy Products Co. 


365 


Standard-Toch-Chemlcals , Inc . 


442 


Endo Products, Inc. 


366 


Zinsser & Co., Inc. 


443 


Pharma Chemical Corp. 


367 


Armour Laboratories Div. of Armour S Co. 


444 


Standard Ultramarine & Color Co. 


368 


Pennsylvania Salt Manufacturing Co. 


445 


Wolf, Jacques, & Co. 


369 


Arnold, Hoffman & Co., Inc. 


446 


Young Aniline Works, Inc. 


370 


Greenwood Textile Supply Co. 


447 


Chemo-Puro Manufacturing Corp. 


371 


Hall, C. P., Co. of Illinois. 


448 


Chemagro Corp. 


372 


Marble tte Corp. 


U9 


Felton Chemical Co., Inc. 


373 


Southern Sizing Co. 


450 


Sinclair Refining Co. 


374 


Trubek Laboratories. 


451 


Blck & Co., Inc. 


375 


Chemical Process Co. 


452 


Eastern States Chemical Corp. 


376 


National Biochemical Co. 


453 


Medical Chemicals Corp. 


377 


Nonweiler, A. P., Co. 


454 


Rlnshed-Mason Co. 


378 


Old Colony Tar Co., Inc. 


455 


Chemical Manufacturing Co., Inc. 


379 


Summit Chemical Products Corp. 


456 


Emulsol Corp. 


380 


Berkshire Color & Chemical Mfg. Corp. 


457 


General Petroleum Corp. 


381 


Arco Co. 


458 


Phillips Petroleum Co. (F. F. C.)^ 


382 


Brooklyn Color Works, Inc. 


459 


Pitman-Moore Co., Div. of Allied 


383 


Collett-Week Corp. 




Laboratories, Inc. 


384 


General Aniline & Film Corp. (Dyestuff and 


460 


Koppers Co., Inc. 




Chemical Div.). 


461 


Verona Chemical Co. 


385 


General Mills, Inc. 


462 


Westvllle Laboratories. 


386 


Kessler Chemical Co., Inc. 


463 


Hof fmann-LaRoche , Inc. 


387 


Leatei Chemical Co. 


464 


Magruder Color Co., Inc. 


388 


Nopco Chemical Co., Inc. 


465 


Sun Chemical Corp. (Warwick Chemical Co. Dlv.) 


389 


Pittsburgh Coke & Chemical Co. 


466 


American Cyanamid Co. (Lederle and Fine 


390 


Sheffield Chemical Co., Inc. 




Chemical Dlv., Organic Chemicals Dlv., and 


391 


Socony-Vacuum Oil Co., Inc. 




Industrial and Plastics and Resins Dlv.). 



See footnote at end of table. 



158 



UNITED STATES TARIFF COMMISSION 



TABLE 27.--SyT»f/ief jc oceanic chemicals; Directory of ^ 



jfacturers, 1954- -Continued 



Name of company 



Name of company 



Emery Industries, Inc. 544 

Interohemlcal Corp. (Finishes Dlv.). 545 

Nlnol Laboratories, Inc. 546 

Stresen-Reuter , Fred'k. A., Inc. 547 
Wyeth Laboratories, Inc. 

Ansbacher-Slegle Corp. 548 

Gallovhur Chemical Corp. 549 

McCloskey Varnish Co. 550 

Pittsburgh Plate Glass Co. 551 

United States Rubber Co. (F. F. C.)^ 552 

United States Rubber Co. (Nau^tuck Chemical 553 

Dlv.). 554 

Dewey & Almy Chemical Co. (Dlv. of W. R. 555 

Grace & Co.). 556 

Sun Oil Co. 557 

Rlngwood Chemical Corp. 558 

Ultra Chemical Works, Inc. 559 

Drew, E. F., i Co., Inc. 560 

Guyan Color & Chemical Works. 561 

Hexagon Laboratories, Inc. 562 
Pabst Brewing Co. 

Aquaneas Corp. 563 

Goodrich, B. F., Chemical Co. (Dlv. of B. F. 564 

Goodrich Co.). 565 

Midland Industrial Finishes Co. 566 

Relchhold Chemicals, Inc. 567 

Wlca Co., Inc. 568 

Universal Detergents, Inc. 569 

Callison, I. P., 4 Sons, Inc. 570 

Cities Service Oil Co. 571 

Sherwin-Williams Co. 572 

Tennessee Eastman Co., Div. of Eastman Kodak 573 

Co. 574 

Texas Eastman Co. , Dlv. of Eastman Kodak Co. 575 

Union Bay State Chemical Co., Inc. 576 

tfhlttemore-Wright Co., Inc. 577 

Allied Asphalt & Mineral Corp. 578 

Columbia Organic Chemicals, Inc. 579 

Fine Organics, Inc. 580 

Thompson Chemicals Corp. 581 

CalMo Chemicals, Inc. 582 
Allied Chemical & Dye Corp.(Semet-Solvay Div.). 583 

Fiber Chemical Corp. 584 

Montrose Chemical Corp. of California. 585 

Productol Co. 586 

Reilly Tar & Chemical Corp. 587 

Republic Creosotlng Co. 588 

American Aniline Products, Inc. 589 
Belle Chemical Co., Inc. 

Bristol Laboratories, Inc. 590 

Eastman Kodak Co. 591 

Farmers' Chemical Co, 592 

Hoffman-Taff, Inc. 593 

Phoenix Oil Co. 594 

Sharpies Chemicals, Inc. 595 

Shell Oil Co. 596 

Federal Paint Co., Inc. 597 

LaSalle Chemical Corp. 598 

Lebanon Chemical Corp. 599 

Thiokol Chemical Corp. 600 

Lever, C, Co., Inc. 601 
Allied Chemical & Dye Corp. (General Chemical 602 

Dlv.). 603 

Johnson, Chas. Eneu, Co., Inc. 604 

Loblca-Debniille. Inc. 605 
Padlow-Nease Chemical Co., Inc. 
Pfizer, Chas., & Co., Inc. 
Washburn, T. F., Co. 
Aroher-Daniels-Mldland Co. 
Crown Central Petroleum Corp. 
Van Camp Laboratories. 
Trask, Arthur C, Co. 
Vitamins, Inc. 
Cabot, Godfrey L., Inc. 
Dominion Products, Inc. 
duPont de Nemours, E. I., & Co., Inc. 
Holland Color & Chemical Co. 
Imperial Paper & Color Corp., Pigment Color 

Dlv. 
Merck & Co., Inc. 
Col ton Chemical Co., Div. of Air Reduction 

Co., Inc. 
Gary Chemicals, Inc. 
Edcan Laboratories. 

•■■ F. F. C. In parentheses following the name of a company indicates U. S. GoTemment plant operated for 
the Federal Facilities Corporation. 



Standard Oil Co. of Indiana. 

Riverdale Chemical Co. 

Union Carbide t Carbon Corp. (Bakellte Co.). 

Union Carbide & Carbon Corp. (Llnde Air 

Products Co.). 
Lubrizol Corp. 
Hooker Electrochemical Co. 
New York Quinine & Chemical Works, Inc. 
Baltimore Paint & Color Works. 
Hooker-Detrex, Inc. 
Moretex Chemical Products, Inc. 
New York Ohio Chemical Corp. 
Sherwood Refining Co., Inc. 
Warren Petroleum Corp. 
Penlck, S. B., & Co. 
Ethyl^ow Chemical Co. 
Cincinnati Chemical Works, Inc. 
Sinclair & Valentine Co. 
Orbls Products Corp. 
Union Carbide & Carbon Corp. (Carbide & 

Carbon Chemicals Co. ) . 
Coekerllle, F. 0. 
Standard Oil Co. of California. 
Crown Chemical Co., Inc. 
I^man, Julius & Co. 
Shell Chemical Corp. 
Aloo Oil & Chemical Corp. 
Heyden Chemical Corp. 

Kennecott Copper Corp. (Utah Copper Dlv.). 
Stepan Chranlcal Co. 
Versenes , Inc . 
Wltte, John H., & Sons. 
Wyandotte Chaaicals Corp. 
Kilsdonk Chemical Corp. 
Augusta Chemical Co. 
Great Western Sugar Co. 
Humphrey-Wilkinson, Inc. 
Lake States Yeast Corp. 
Montrose Chemical Co. 
Glidden Co. 

New Jersey Zinc Co. (of Pa.). 
Alliance Color & Chemical Co. 
Allied Chemical & Dye Corp. (Barrett Dlv.). 
Atlantic Chemical Corp. 
American Alkyd Industries. 
Meta Chemical Corp. 
Pennsylvania Refining Co. 
General Electric Co. (Chemical Materials 

Dept.). 
Imperial Chemical Co. 
Salem Oil & Grease Co. 
Crownoll Chemical Co., Inc. 
Houghton, E. F., & Co. 
Ad -Co Color Corp. 
Gelgy Chemical Corp. 
George, P. D., Co. 
Pabco Products, Inc. 
Verley Chemical Co., Inc. 
Freeman Chemical Corp. 
Loven Chemical Co. of California. 
Pacific Yeast Products, Inc. 
Neches Butane Products Co. (F. F. C.)^ 
Kentucky Synthetic Rubber Co. (F. F. C.)^ 



Midland Synthetic Rubber Co. (F. F. 
Deep Rock Oil Co. 



C.)' 



SYNTHETIC ORGANIC CHEMICALS, 1954 

TAHLE 2'7-- -Synthetic orgenic chemicals: Directory of manufacturers, 79J<--Coot inued 
SECTION 2. ALPHABETICAL DIRECTORY 



159 



[Naines of synthetic organic chemical manufacturers who reported production or sales to the United States 
Tariff ConniilEsion for 1954 are listed below alphahetically, together with their identification numbers 
as used in tables In part III. Section 1 of this table lists these manufacturers in the order of their 
identification numbers] 



Name of company 



Office address (location of plant given In 
parentheses If not in saae city as office) 



Abbott Laboratories 

Acme Resin Corp 

Ad-Co Color Corp 

Advance Solvents & Chemical Corp- 

Alr Reduction Chemical Co 

Alco Oil & Chemical Corp 

Alframlne Corp 

Alkydol Laboratories, Inc 

Alliance Color k Chemical Co 

Allied Asphalt & Mineral Corp 

Allied Chemical & Dye Corp.: 
Barrett Div- 



General Chemical Dlv 

National Aniline Div 

Nitrogen Div 

Semet-Solvay Div 

Solvay Process Div 

All-Tex Specialties Co- 

Alox Corp 

Althouse Chemical Co., Inc 

Amalgamated Chemical Corp 

American Aloolac Corp 

American Aliyd Industries 

American Aniline & Extract Co., Inc — 

American Aniline Products, Inc 

American Bio-Synthetios Corp 

American Chemical Paint Co 

American Cyanamid Co.: 

Industrial and Plastics and Resins 
Div. 



Lederle and Fine Chemical Div — 



Organic Chemicals Div 

American Maize Products Co 

American Marietta Co 

Ferbert-Schomdorfer Co. Div 

American Potash and Chemical Corp., 

Eston Chemicals Div. 
American Viscose Corp 

Sylvania Div 

Anderson Laboratories, Inc 

Ansbacher-Slegle Corp 

Ansul Chemical Co 

Apex Chemical Co., Inc 

Appleton Coated Paper Co 

Aquaness Corp 

Arapahoe Chemicals, Inc., & Arapahoe 

Special Products, Inc. 
Archer -Daniels-Midland Co 

Arco Co — 

Armour & Co.: 

Chemical Div 

Armour Laboratories Div 

Armstrong Cork Co 

Arnold, Hoffman & Co., Inc 



Astra Pharmaceutical Products, 

Atlantic Chemical Corp 

Atlantic Refining Co 

Atlas Powder Co 



Inc 



Atlas Processing Co 

Atlas Refinery, Inc 

Atcmic Basic Chemicals Corp 

Augusta Chemical Co 

Azoplate Corp 

Baker Castor Oil Co 

Baker, J. T., Chemical Co 

Taylor Chemical Div 

Baltimore Paint & Color Works 



Uth St. and Sheridan Rd., North Chicago, 111. 

1401 Circle Ave., Forest Park, 111. 

56 Lister Ave., Newark 5, N. J. 

245 5th Ave., New York 16, N. Y. (Jersey City, N. J.). 

60 E. 42d St., New York 17, N. Y. (Bound Brook, N. J.). 

Trenton Ave. and William St., Philadelphia 34, Pa. 

72-76 Putnam St., Paterson 4, N, J. 

3242 S. 50th Ave., Cicero 50, 111. 

33 Avenue P, Newark 5, N. J. 

217 Broadway, New York 7, N. Y. (Dunellen, N. J.). 

40 Rector St., New York 6, N. Y. (Fairfield, Ala.; Calumet 

City and Chicago, 111.; Detroit, Mich.; Edgewater, N. J.; 

Greensboro, N. C; Ironton, Toledo, and Youngstown, Ohio; 

and Bethlehem, Frankford, and Philadelphia, Pa.). 
40 Rector St., New York 6, N. Y. (Nichols, Calif.; Baton 

Rouge, La.; Buffalo, N. Y.; and Marcus Hook, Pa.). 
40 Rector St., New York 6, N. Y. (Buffalo, N. Y.; Hopewell, 

Va.; and Moundsville, W. Va.). 
Hopewell, Va. (Omaha, Nebr.; South Point, Ohio; and Orange, 

Tex.). 
40 Rector St., New York 6 (Tonawanda), N. Y. 
P. 0. Box 271, Syracuse 1 (Solvay Village), N. Y. 
65 Meadow St., Warwick, R. I. 
3943 Buffalo Ave., Niagara Falls, N. Y. 
540 Pear St., Reading, Pa. 
Ontario and Rorer Sts., Philadelphia 34, Pa. 
3440 Fairfield Rd., Baltimore 26, Md. 
Broad and 14th Sts., Carlstadt, N. J. 
Venango and F Sts., Philadelphia 34, Pa. 
50 Union Sq. , New York 3, N. Y. (Lock Haven, Pa.). 
710 W. National Ave,, Milwaukee 4, Wis. 
Ambler, Pa. 

30 Rockefeller Plaza, New York 20, N. Y. (Azusa, Calif.; 
Stamford and Wallingford, Conn.; Bound Brook, Linden, and 
Woodbridge, N. J.; Charlotte, N. C; and Brldgeville, Pa.). 

30 Rockefeller Plaza, New York 20, N. Y. (Princeton, N. J., 
and Pearl River, N. Y.). 

30 Rockefeller Plaza, New York 20, N. Y. (Bound Brook, N. J.). 

250 Park Ave., New York 17, N. Y. 

3400 Uth Ave., SW., Seattle 4, Wash. 

12815 Elrawood Ave., Cleveland 11, Ohio. 

3100 E. 26th St., Los Angeles 23, Calif. 

1617 Pennsylvania Blvd., Philadelphia 3 (Meadvllle), Pa. 

Frederioksb\rrg, Va. 

3940 Summit St., Weston, Mich. 

92 Chestnut Ave., Staten Island 5, N. Y. 

1 Stanton St., Marinette, Wis. 

225 W. 34th St., New York 1, N. Y. (Elizabetl5)ort, N. J.). 

1200 N. Meade St., Appleton, Wis. 

2005 Quitman St., Houston 26, Tex. 

2800 Pearl St., Boulder, Colo. 

2191 W. 110th St., Cleveland, Ohio (Minneapolis, Minn., and 

Wyandotte , Mich. ) . 
7301 Bessemer Ave., Cleveland 27, Ohio. 

1355 W. 31st St., Chicago 9 (MoCook), 111. 

Box 511, Kankakee, 111. 

W. Liberty St., Lancaster (Pittsburgh), Pa. 

55 Canal St., Providence 1, R. I. (Dighton, Mass.; Charlotte, 

N. C; and Cincinnati, Ohio). 
7-1/2 Neponset St., Worcester 6, Mass. 
153 Prospect St., Passaic (Clifton), N. J. 
260 S. Broad St., Philadelphia 1, Pa. (Port Arthur, Tex.). 
9th and Market Sts., Wilmington 99, Del. (Atlas Point, Del., 

and Tamaqua, Pa.) . 
P.O. Box 1786, Shreveport, La. 
142 Lockwood St., Newark 5, N. J. 
350 Delwar Rd., Pittsburgh 36, Pa. 
Box 660, Augusta, Ga. 

Morris Ave. and Weaver St., Summit, N. J. 
120 Broadway, New York 5, N. Y. (Bayonne, N. J.). 
600 N. Broad St., Phillipsburg, N. J. 

600 N. Broad St., Phillipsburg, N. J. (Penn Yan, N. Y.). 
2325 Annapolis Ave., Baltimore 30, Md. 



160 UNITED STATES TARIFF COMMISSION 

TABLE 27 .- -Synthetic organic chemicals; Directory of manufacturers , /954--Continued 



Name of company 



Office address (location of plant given In 
parentheses If not In sane city as office) 



Barium Reduction Corp 

Bates Chemical Co 

Belle Alkali Co 

Belle Chemical Co., Inc 

Benzol Products Co 

Berk, F. W., &. Co., Inc 

Berkeley Chemical Corp 

Berkshire Color & Chemical Mfg. Corp- 

Blck S: Co., Inc 

Bios Laboratories, Inc 

Bird & Son, Inc 

Blackman Brands, Inc 

Blockson Chemical Co- 

Booty Reslneers, Inc 

Borden Co. , Chemical Dlv 



Borg-Wamer Corp., MEirbon Chemical 
Dlv. 

Bristol Laboratories, Inc 

Brooklyn Color Works, Inc 

Bruder, M. A., & Sons, Inc 

Bryant Chemical Corp 

Buckeye Cotton Oil Co- 



Buckman Laboratories, Inc 

Burkart-Schler Chemical Co 

Burroughs-Wellcome Sc Co. (U.S.A.), 
Inc. 

Bush, W. J., & Co., Inc 

Cabot, Godfrey L., Inc 

Cabot, Samuel, Inc 

Cadet Chemical Corp — 

Calhio Chemicals, Inc 

California Ink Co., Inc 

California-Spray Chemical Corp 

Callison, I. P., & Sons, Inc 

Cargill, Inc 

Carlisle Chemical Works, Inc 

Carolina Aniline ^ Extract Co 

Carpenter-Morton Co 

Cams Chemical Co., Inc 

Cary Chemicals, Inc 

Catalln Corp. of America 

Celanese Corp. of America 



Marco Products Dlv 

Chaffardon, J 

Chase Chemical Corp 

Chemagro Corp 

Chemical Manufacturing Co., Inc 

Chemical Process Co 

Chemo-Puro Manufacturing Corp 

Childs Pulp Colors, Inc 

Ciba Pharmaceutical Products, Inc- 
Clba States, Ltd., Toms River Dlv- 
Clnolnnati Chemical Works, Inc 



Cities Service Oil Co 

Cities Service Refining Corp. 
(F.F.C.)^ 

City Chemical Corp 

Cleary, W. A., Corp 

Clinton Foods, Inc 

Coastvise Petroleum Co 

Cockerille, F. 

Col^jte-Palmollve Co 



Collett-Week Corp 

Collway Colors, Inc 

Colton Chemical Co., Div. of Air 

Reduction Co., Inc. 
Columbia Organic Chemicals, Inc — 
Commercial Solvents Corp 



Commonwealth Color St Chemical Co- 

Contlnental-Dlamond Fibre Co 

Continental Oil Co 

See footnote at end of table. 



P.O. Box 8097, S. Charleston 3, W. Va. 
Scottdale Rd., Lansdoune, Pa. 

300 Union Commerce Bldg., Cleveland lA, Ohio. 
53^ Pearl St., Reading, Pa. 

237 South St., Newark 5 (Nixon), N. J. 

Park PI., E., Wood-Ridge, N. J. 

Summit Ave., Berkeley Heights, N. J. 

250 Delawanna Ave., Delawanna, N. J. 

Bern & 12th Sts., Reading, Pa. 

17 W. 60th St., New York 23, N. Y. 

East Walpole (Norwood), Mass. 

Wesley St., S. Hackensack, N. J. 

Jollet, 111. 

112 Jefferson St., Newark, Ohio. 

350 Madison Ave., New York 17, N. Y. (Demopolis, Ala.; Los 
Angeles, Calif.; Illiopolls and Union, 111.; Peabody, 
Mass.; Balnbrldge, N. Y.; Kemersville, N. C; Spring- 
field, Oreg.; Philadelphia, Pa.; and Seattle, Wash.). 

1926 W. 10th Ave., Gary, Ind. 

P. 0. Box 657, Syracuse 1, N. Y. 

681 Morgan Ave., Brooklyn 22, N. Y. 

650 Main St., Berlin, N. H. 

52d and Grays Ave., Philadelphia 43, Pa. 

6 North St., N. Qulncy 71, Maaa. 

P.O. Box 539, Cincinnati 1, Ohio (Memphis, Tenn.). 

1256 N. McLean, Memphis 8, Tenn. 

1228 Chestnut St., Chattanooga 2, Tenn. 

Soarsdale Rd., Tuckahoe 7, N. Y. 

19 W. 44th St., New York 36, N. Y. (Linden, N. J.). 

77 Franklin St., Boston 10, Mass. 

141 Milk St., Boston 9 (Chelsea), Mass. 

717 Elk St., Buffalo 5, N. Y. 

380 Madison Ave., New York 17, N. Y. (Perry, Ohio). 

545 Sansome St., San Francisco 11 (Berkeley), Calif. 

Lucas and Ortho Way, Richmond 4, Calif. 

801 Lloyd Bldg., Seattle 1 (Chehalis), Wash. 

P.O. Box 1075, Pittsburgh (Carnegie), Pa. 

West St., Reading 15, Ohio. 

301 S. Cedar St., Charlotte 1, N. C. 
376 3d St., Everett 49, Mass. 

1377 8th St., LaSalle, 111. 

Stiles Lane, North Haven, Conn. 

64 Hamilton St., Paterson 3 (Milltown), N. J. 

1 Park Ave., New York 16, N.Y. (Calumet City, 111.; Fords, 

N. J.; and Thcmasville, N. C). 
180 Madison Ave., New York 16, N. Y. (Amcelle, Md.; Newark, 

N. J.; Cclrlver, S. C; Bishop and Pampa, Tex.; and Celco, 

Va.). 
290 Ferry St., Newark 5 (Linden), N. J. 
209 Market St., Lynn, Mass. 
3527 Smallman St., Pittsburgh 1, Pa. 
101 Park Ave., New York 17, N. Y. (Pittsburgh, Pa.). 
Megonko Rd., Ashland, Mass. 
901 Spring St., Redwood City, Calif. 
2508 E. Bailey Rd., Cuyahoga Falls, Ohio. 
32-25 Queens Blvd., Long Island City 1, N. Y. 
43 Summit St., Brooklyn 31, N. Y. 
556 Morris Ave., Summit, N. J. 
P.O. Box 71, Toms River, N. J. 
P.O. Box 20, Evanston Sta., Cincinnati 7 (Norwood and St. 

Bernard), Ohio. 
Cities Service Bldg., Bartlesvllle (Tallant), Okla. 
716 Hodges St., Lake Charles, La. 

132 W. 22d St., New York 11, N. Y. (Jersey City, N. J.). 

P.O. Box 749, New Brunswick (Franklin Township), N. J. 

Clinton, Iowa. 

1127 Munsey Bldg., Baltimore 2, Md. (Goodhope, La.). 

Greenwood, Va. 

105 Hudson St., Jersey City 5, N. J. (Berkeley, Calif.; 

Jeffersonville, Ind.; Kansas City, Kans.; and Jersey 

City, N. J.). 
Quimby St., Ossining, N. Y. 
15 Market St., Paterson 1, N. J. 
1545 E. 18th St., Cleveland 14, Ohio. 

600 Capitol PI., Columbia 5 (Cedar Terrace), S. C. 

260 Madison Ave., New York 16, N. Y. (Agnew, Calif.; Peoria, 

111.; Terre Haute, Ind.; Harvey and Sterlington, La.; and 

Carlstadt, N. J.). 
3240 Grace Ave., New York 69, N. Y. 
70 S. Chapel St., Newark, Del. (Bridgeport, Pa.). 
lOOO S. Pine St., Ponca City, Okla. 



SYNTHETIC ORGANIC CHEMICALS, mu 



161 



TABLE 27. --Synthetic organic chemicals: Directory of manufacturers, l954--Continued 



Name of company 



Office address (location of plant given In 
parentheses If not In same city as office) 



Cook Paint & Varnish Co 

Coopers Creek Chemical Corp 

Copolymer Corp. (F.F.C.)^ 

Corn Products Refining Co 

Cosden Petroleum Corp 

Crosby Chemicals, Inc 

Crcvm Central Petroleum Corp 

Crown Chemical Co. , Inc 

Crown Chemical Corp 

Crownoll Chemical Co., Inc 

Crown Tar & Chemical Works, Inc 

Cutter Laboratories 

Dakota Briquets & Tar Products, Inc — 

Davis, H. B., Co 

Dave's Laboratories, Inc 

Deecy Products Co 

Deep Rock Oil Co 

Deere & Co. , Grand River Chemical 

Div. 

Delaware Chemicals, Inc 

Delta Chemical Works, Inc 

DePaul Chemical Co., Inc 

Dewey 4 Almy Chemical Co., Dlv. of 

W. R. Grace & Co. 

Dexter Chemical Corp 

Diamond Alkali Co 

Diamond Alkali Organic Chemicals Div. 
Inc. 

Dominion Products, Inc- - ■ 

Douglas Chemical Corp 

Dow Chemical Co 



Styrene Dlv. 



Dow Chemical Co., 
(F.F.C.)^ 

Dow Coming Corp 

Drew, E. F.. & Co., Inc 

Drug Processors, Inc — — 

duPont de Nemours, E. I., & Co. 



Durez Plastics & Chemicals, Inc 

Dye Specialties Corp., Inc 

Eaklns, J. S., & W. R., Inc 

Eastern States Chemical Corp 

Eastman Kodak Co 

Tennessee Eastman Co. Div 

Texas Eastman Co. Div 

Edcan Laboratories 

Edison, Thomas A., Inc., Medical Gas 

Div. 

El Dorado Oil Works 

Elizabethtown Consolidated Gas Co 

El PSso Natural Gas Co 

Emery Industries, Inc — 

Emkay Chemical Co 

Eraulsol Corp 

Endo Products, Inc 

Esso Standard Oil Co 

Louisiana Dlv 

Ethyl Corp 



Ethyl-Dow Chemical Co 

Evans Chemetlcs, Inc 

Falrmount Chemical Co., Inc 

Farley & Loetscher Manufacturing Co — 

Farmers' Chemical Co 

Farrlngton, W. U., Estate of 

Federal Color Laboratories, Inc 

Federal Paint Co., Inc 

Felton Chemical Co. , Inc 

Ferro Chemical Corp 

Fiber Chemical Corp 

Fine Colors Co 

Fine Organlcs, Inc 

Firestone Tire & Rubber Co. (F.F.C.)^ 
Firestone Tire & Rubber Co., 
Firestone Plastics Co. Div. 

See footnote at end of table. 



P.O. Box 389, Kansas City Al, Mo. 

River Rd., W. Conehohocken, Pa. 

P.O. Box 1029, Baton Rouge 1, La. 

17 Battery PI., New York A, N. Y. (Argo, 111.). 

P.O. Box 1311, Big Spring, Tex. 

Box 111, Picayune, Miss. (De Ridder, La.). 

American Bldg., Baltimore 3, Mi. (Houston, Tex.). 

Pleasantvlew Terrace, Ridgefleld, N. J. 

240 India St., Providence 3, R. I. 

2-U 'i9th Ave., Long Island City 1, N. Y. 

900 Wewatta St., Denver 4, Colo. 

"ith and Parker Sts., Berkeley 10, Calif. 

Box 446, Dickinson, N. Dak. 

Bush & Severn Sts., Baltimore 30, Md. 

4800 S. Richmond St., Chicago 32, 111. (Newaygo, Mich.). 

120 Potter St., Cambridge 42, Mass. 

Atlas Life Bldg., Tulsa 2 (Gushing), Okla. 

2010 S. Utica, Tulsa (Pryor), Okla. 

50 Murray St., Staten Island 9, N. Y. 

23 U. 60th St., New York 23, N. Y. 

44-27 Purvis St., Long Island City 1, N. Y. 

62 Whlttemore Ave., Cambridge 40 (Acton), Mass. 

819 Edgewater Rd., New York 59, N. Y. 

300 Union Commeroe Bldg., Cleveland 14, Ohio (Painesvllle, 

Ohio, and Houston, Tex.}. 
80 Lister Ave., Newark 5, N. J. 

10_40 44th Dr., Long Island City 1, N. Y. 

1624 Darrow Ave., Evanston, 111. 

Midland, Mich. (Pittsburg and Torrance, Calif.; Gales 

Ferry, Conn.; and Freeport, Tex.). 
P.O. Box 500, Gardena (Los Angeles), Calif. 

Box 592, Midland, Mich. 

15 E. 26th St., New York 10, N. Y. (Boonton, N. J.). 
1219 E. Church St., Adrian, Mich. 

10th and Market Sts., Wilmington 98, Del. (S. San 
Francisco, Calif.; Newport and Wilmington, Del.; Chicago, 
111.; E. Chicago, Ind.; Ft. Madison, Iowa; Louisville, 
Ky.; Everett, Mass.; Flint, Mich.; Carney's Point, 
Grasselli, Linden, Newark, New Brunswick, Parlin, and 
Perth Amboy, N. J.; Niagara Falls, N. Y.; Cleveland, Ohio; 
Philadelphia, Pa.; Chattanooga, Tenn.; La Porte and 
Orange, Tex.; Martinsville, Va.; and Belle, W. Va.). 

Walck Rd., N. Tonawanda, N. Y. 

26 Journal Sq., Jersey City 6, N. J. 

2307 N. nth St., St. Louis 6, Mo. 

55 Berry St., Brooklyn 11, N. Y. 

P.O. Box 5008, Harrisburg Sta., Houston 12, Tex. 

343 State St. , Rochester 4, N. Y. 

Eastman Rd., Kingsport, Tenn. 

P.O. Box 2068, Longview, Tex. 

10 Pine St., South Norwalk, Conn. 

P.O. Box 15, Stuyvesant Falls, N. Y. 

P.O. Box 599, Oakland 4, Calif. 

16 W. Jersey St. , Elizabeth 4, N. J. 
P.O. Box 1492, El Paso, Tex. 

4300 Carew Tower, Cincinnati 2 (St. Bernard), Ohio. 

319 2d St., Elizabeth 1, N. J. 

59 E. Madison St., Chicago 3, 111. 

84-40 101st St., Richmond Hill 18, N. Y. 

P.O. Box 23, Linden, N. J. 

P.O. Box 551, Baton Rouge 1, La. 

100 Park Ave., New York 17, N. Y. (Baton Rouge, La.; 

Orangeburg, S. C; and Pasadena, Tex.). 
Midland, Mich. (Freeport, Tex.). 
250 E. 43d St., New York 17 (Waterloo), N. Y. 
600 Ferry St., Newark 5, N. J. 
7th and White Sts., Dubuque, Iowa. 
3713 W. Main St., Kalamazoo, Mich. 
Box 389, E. Greenwich (Warwick), R. I. 
4633 Forest Ave., Norwood 12, Ohio. 
33 Rector St., New York 6, N. Y, (Newark, N. J., and 

Brooklyn, N. Y. 
599 Johnson Ave., Brooklyn 37, N. Y. 
Box 349, Bedford, Ohio. 
P.O. Box 218, Matawan (Cliffwood), N. J. 
21-29 McBrlde Ave., Paterson 1, N. J. 
211 E. 19th St., New York 3, N. Y. (Lodi, N. J.). 
381 W. Wllbeth Rd., Akron 1, Ohio. 
P.O. Box 690, Pottstown, Pa. 



162 



UNITED STATES TARIFF COMMISSION 



TAELE 27. --Synthetic organic chemicals: Directory ol manufacturers, 1954- -Continued 



Name of ccnipany 



Office address (location of plant given in 
parentheses If not in same city as office) 



Floraaynth Laboratories, Inc 

Food Machinery & Chemical Corp. 
Ohio-Apex Dlv- 



Plne Bluff Chemical Co- 



Westvaco Chlor-Aliali Div. & 
Uestvaco Mineral Products Div. 

Ford Motor Co 

Foster-Heaton Co 

France, Campbell & Darling, Inc 

Freeman Chemical Corp 

Fries Bros., Inc 



Fritzsohe Brothers, Inc- 
Frontler Chemical Co- 
Fuller, W. P., 4 Co- 
Gallovhur Chemical Corp- 

Oamma Chemical Corp 

Cane's Chemical Works, Inc — 

Gelgy Chemical Corp 

General Aniline & Film Corp. 

& Chemical Div. 

General Color Co., Inc 

General Electric Co., Chemical 

Materials Dept. 



Dyestuff 



General Foods Corp., Maxwell House Div 

General Mills. Inc 

General Motors Corp., AC Spark Plug 

Div. 

General Petroleum Corp 

General Tire & Rubber Co. (F.F.C.)^ 

General Tire & Rubber Co., Chemical 

Div. 

Genesee Research Corp 

George, P. D., Co 

Oilman Paint tc Varnish Co 

Givaudan Corp 

Glldden Co 



Glyoo Products Co., Inc 

Goodrich, B. F., Co.: 

Goodrich, B. F., Chemical Co. Div. 
(F.F.C.)^ 

Goodrich, B. F., Chemical Co. Div— 



Goodyear Tire & Rubber Co — 

Pathfinder Chemical Corp- 

Gordon Chemicals, Inc — 

Grain Processing Corp — 



Grand Rapids Varnish Corp 

Great Southern Chemical Corp — 

Great Western Sugar Co 

Greenwood Textile Supply Co 

Griffin Chemical Co 

Gulf Oil Corp 

Guyan Color & Chemical Works — 

Halby Products Co— 

Hall, C. P., Co. of Illinois- 
Halogen Chemicals, Inc 

Hampden Color & Chemical Co 

Hanna Paint Manufacturing Co., 

trial Div. 
Harbor Plywood Corp- 



Harshaw Chemical Co— — 

Harsyd Chemicals, Inc 

Hart Products Corp 

Hartman-Leddcm Co- 

Hercules Powder Co 



Heresite & Chemical Co 

Hexagon Laboratories, Inc- 
Heyden Chemical Corp 



Hoffmann-LaHoche, Inc — 
Hoffman-Taff , Inc 



Holland Color & Chemical Co- 
Hooker-Detrex, Inc 

Hooker Electrochemical Co 

Houghton, E. F., & Co 

Huggins, James, 4 Son, Inc — 
Humble Oil & Refining Co 



See footnote at end of table. 



900 Van Nest Ave., New York 62, N. Y. 



(Arsenal, Ark.). 
(Newark, Calif., and 



Nitro, W. Va. 

100 Niagara St., Middleport, N. T 

161 E. <l2d St., New York 17, N. Y 

S. Charleston, W. Va.). 
3000 Schaefer Rd., Dearborn (Highland Park), Mich. 
16 E. 5th St., Peterson -i, N. J. 
Michigan Ave., Kenilworth, N. J. 
Saukville, Wis. 

271 Church St., New York 13, N. Y. (Bloomfleld, N, J.). 
76 9th Ave., New York 11, N. Y. (Clifton, N. J.). 
321 W. Douglas, Wichita, Kans. 
301 Mission St., San Francisco 19, Calif. 
N. Water St., Osslnlng, N. Y. 

220 E. 42d St., New York 17, N. Y. (Great Meadows, N. J.). 
677 5th Ave., New York 22, N. Y. (Carlstadt, N. J.). 
89 Barclay St., New York 8, N. Y. (Cranston, R. I.). 
P.O. Box 12, Linden, N. J. (Rensselaer, N. Y.). 

2A Ave. B, Newark 5, N. J. 

1 Plastics Ave., Plttsfield, Mass. (Anaheim, Calif.; 

Pittafleld, Mass.; Schenectady, N. Y.; and Coshocton, 

Ohio). 
1125 Hudson St., Hoboken, N. J. 
AOO 2d Ave., S., Minneapolis 1, Minn. 
1300 N. Dort Highway, Flint 2, Mich. 

P.O. Box 2122, Terminal Annex, Los Angeles 5^, Calif. 

Baytown, Tex. 

1708 Knglewood Ave. at Holmes, Akron (Mogadore), Ohio. 

961 Lyell Ave., Rochester 6, N. Y. 

5200 N. 2d St., St. Louis 7, Mo. 

216 W. 8th St., C.'iflttanooga 1, Tenn. 

109-201 Delawanna Ave., Delawanna, N. J. 

11001 Madison Ave., Cleveland 2, Ohio (San Francisco, 

Calif.; Jacksonville, Fla.; Chicago, 111.; Minneapolis, 

Minn.; Cleveland, Ohio; and Reading, Pa.). 

26 Court St., Brooklyn 1, N. Y. (Williamsport, Pa.). 

32/1 Rose Bldg., Cleveland 15, Ohio (Port Neches, Tex., and 
Institute, W. Va.). 

324 Rose Bldg., Cleveland 15, Ohio (Calvert City and 

Louisville, Ky.; Haledon and Kearny, N. J.; Niagara Falls, 
N. Y.; and Akron and Avon Lake Village, Ohio). 

1144 E. Market St., Akron 16, Ohio. 

5408 Baker Ave., Niagara Falls, N. Y. 

A & Lombard Sts., Wilmington 99, Del. 

1600 Oregon St., Muscatine, Iowa. 

1350 Steele Ave., SW., Grand Rapids 2, Mich. 

P.O. Box 4166, Corpus Christi, Tex. 

P.O. Box 5308, Terminal Annex, Denver (Johnstown), Colo. 

27 Meadow St., Warwick, R. I. 

1000 16th St., San Francisco 7 (Richmond), Calif. 

Gulf Bldg. , Pittsburgh 30, Pa. 

Box 1088, Huntington, W. Va. 

P.O. Box 366, Wilmington 99, Del. 

5145 W, 67th St., Chicago 38, 111. 

1505 Charlton Dr., Columbia 3, S. C. 

5 Albany St., Springfield 1, Mass. 

1313 Windsor Ave., Columbus 16, Ohio. 

Box 940, Aberdeen, Wash. 

1945 E. 97th St., Cleveland 6, Ohio (Gloucester City, N. J.). 

397 W. 21st St., Holland, Mich. 

L440 Broadway, New York 18, N. Y. (Jersey City, N. J.). 

5821 Market St., Philadelphia 39, Pa. 

900 Market St., Wilmln^on 99, Del. (Brunswick, Ga.; 

Mansfield, Mass.; Hattlesburg, Miss.; Burlington, 

Kenvll, and Parlln, N. J.; and Hopewell, Va.). 
822 S. 14th St., Manitowoc, Wis. 
3536 Peartree Ave., New York 69, N. Y. 
342 Madison Ave., New York 17, N. Y. (Fords and Garfield, 

N. J.). 
324-424 Klngsland Rd., Nutley 10, N. J. 
W. Bennett Street Rd., Springfield, Mo. 
492 Douglas Ave., Holland, Mich. 
Buffalo Ave. & •47th St., Niagara FaUa, N. Y. (Ashtabula, 

Ohio, and Tacoma, Wash.). 
Buffalo Ave. &. 47th St., Niagara Falls, N. Y. 
303 W. Lehigh Ave., Philadelphia 33, Pa. 
239 Medford St., Maiden 48, Mass. 
P.O. Box 2180, Houston 1 (Baytown), Tex. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



163 



TABLE 27 .--Synthetic organic cheaiicata: Directory of manufacturers, J9J4- -Continued 



Name of company 



Office address (location of plant given In 
parentheses If not In same city as office) 



Humble Oil & Refining Co. (F.F.C.)^— 

Humphrey-Wilkinson, Ino 

Huron Milling Co 

Hyman, Julius, & Co 

Hynson, Weateott & Dunning, Inc 

Imperial Chemical Co 

Imperial Paper & Color Corp., Pigment 

Color Dlv. 

Indoll Chemical Corp 

Industrial Dyestuff Co 

Industrial Products, Inc 

Inland Alkaloid Co 

Inland Steel Container Co 

Interchemloal Corp.: 

Flnlshea Dlv 



Textile Colors Dlv 

International Minerals & Chemical 

Corp. 

Ironsides Co 

Irvlngton Vamlsh & Insulator Dlv. of 

Minnesota Mining and Manufacturing 

Co. 
Jefferson Chemical Co., Ino 

Jennison-Uright Corp 

Johnson, Charles Eneu, Co., Inc 

Jones-Dabney Co 

Jordan, Jr., W. H., i F., 

Manufacturing Co. 

Kail Manufacturing Co 

Kalide Corp 

Kay-Friea Chemicals, Inc 

Kehew-Bradley Co — 

Kem Products Co., Inc ~ — — — 

Kendal Refining Co 

Kennecott Copper Corp.: 

Chlno Mines Dlv ■ 

Utah Copper Dlv- 



Kentucky Color & Chemical Co 

Kentucky Synthetic Rubber Corp. 

(F.F.C.)^ 

Kessler Chemical Co., Inc 

Keystone Chemurglc Corp 

Keystone Color Works, Inc 

Keystone Paint & Vamlsh Corp 

Kilsdonk Chemical Corp 

Knoedler Chemical Co 

Kohnstamm, H., & Co., Inc 

Koppers Co., Inc.: 

Chemical Dlv- 



Tar Products Dlv 



Krumbhaar Chemical Co., Inc 

Kyanize Paints, Inc 

Lakeside Laboratories, Inc 

Lake States Yeast Corp 



LaMotte Chemical Products Co 

LaSalle Chemical Corp 

Laurel Soap Manufacturing Co., Inc — 

Leatex Chemical Co 

Lebanon Chemical Corp 

Lebec Chemical Corp 

Lefflngwell Chemical Co 

Lemke, B. L., & Co., Inc 

Lever Brothers Co 

Lever, C, Co., Inc 

Levey, Fred'k. H., Co., Inc 

Levis Tar Products Co 

Lilly, Eli, i Co 

Lobica-Debrullle, Inc 

Long, Chas. R., Jr., Co 

Loven Chemical Co. of California 

Lubrizol Corp- 



Luedera, George, & Co 

See footnote at end of table. 



P.O. Box -iSZl, Baytovm, Tex. 

DeVlne St., North Haven, Conn. 

9 Park PI., New York 7, N. Y. (Harbor Beach, Mich.). 

P.O. Box 2171, Denver 1, Colo. 

Charles & Chase Sts., Baltimore 1, Md. 

West 6th & Grass Sts., Shenandoah, Iowa. 

P.O. Box 231, Glens Falls, N. Y. 

910 S. Michigan Ave., Chicago 80, 111. (Whiting, Ind.). 

Massasolt Ave., E. Providence 14, R. I. 

215 S. Laurens St., Greenville, S. C. 

Tipton, Ind. 

6532 S. Menard Ave., Chicago 38, 111. 

224. McWhorter St., Newark 1, N. J. (Los Angeles, Calif.; 

Chicago, 111.; Elizabeth and Newark, N. J.; and 

Cincinnati, Ohio). 
150 Wagaraw Rd., Hawthorne, N. J. 
20 N. Wacker Dr., Chicago 6, 111. (San Jose, Calif.; 

Skokle, 111.; Niagara Falls, N. Y.; and Rossford, Ohio). 
270 W.. Mound St. (P.O. Box 1999), Columbus 16, Ohio. 
6 Argyle Ter., Irvlngton 11 (Newark), N. J. 



260 Madison Ave., New York 16, N. Y. (Austin and Port 

Neches, Tex.). 
2463 Broadway, Toledo 9, Ohio. 
10th & Lombard Sts., Philadelphia 47, Pa. 
14B1 S. 11th St., Louisville 8, Ky. 
2126 E. Somerset St., Philadelphia 34, Pa. 

427 E. Moyer St., Philadelphia 25, Pa. 

S. Canal St., Lawrence, Mass. 

180 Madison Ave., New York 16 (West Haverstraw), N. Y. 

40 Oliver St., Boston 10 (Everett), Maaa. 

229 High St., Newark 2, N. J. 

77 N. Kendall Ave., Bradford, Pa. 

Hurley, N. Mex. 

721 Keams Bldg., Salt Lake City 10 (Garfield), Utah. 

600 N. 34th St., Louisville 12, Ky. 

Louisville Ky. 

State Rd. and Cottman Ave., Philadelphia 35, Pa. 

R. D. #1, Bethlehem, Pa. 

151 W. Gay Ave., York, Pa. 

71 Otsego St., Brooklyn 31, N. Y. 

101 Canal St., Lock Haven, Pa. 

651 High St., Lancaster 1, Pa. 

83-93 Park PI., New York 7 (Brooklyn), N. Y. 

Koppers Bldg., 430 7th Ave., Pittsburgh 19, Pa. (Kobuta, 
Monaca, Oil City, and Petrolla, Pa.; and Port Arthur, 
Tex.). 

Koppers Bldg., 430 7th Ave., Pittsburgh 19, Pa. (Woodward, 
Ala.; Fontana, Calif.; New Haven, Conn.; Chicago, 111.; 
Chalmette, La.; Portland, Maine; Everett and Westfield, 
Mass.; St. Paul, Minn.; St. Louis, Mo.; Kearny and 
Westfield, N. J.; Buffalo, Rochester, and Utlca, N. Y.; 
Hamilton, Warren, and Youngstown, Ohio; Swedeland and 
Swissvale, Pa.; E. Providence, R. I.; Memphis, Tenn.; 
Houston, Tex.; Follansbee, W. Va.; and Carroll vllle. 
Wis.). 

24-30 Jacobus Ave., S. Kearny, N. J. 

2d & Boston Sts., Everett 49, Mass. 

1707 E. North Ave., Milwaukee 1, Wis. 

603 W. Davenport St., Rhinelander, Wis. 

Towson 4, V&. 

Fox Island Rd., Port Chester, N. Y. 

Tioga & Thompson Sts., Philadelphia 34, Pa. 

2722 N. Hancock St., Philadelphia 33, Pa. 

P.O. Box 532, Lebanon, Pa. 

14066 S. Garfield Ave., Paramount, Calif. 

10523 S. Santa Gertrudes, Whittler, Calif. 

199 Main St., Lodl, N. J. 

390 Park Ave., New York 22, N. Y. 

Howard and Huntington Sts., Philadelphia 33, Pa, 

380 Madison Ave., New York 17 (Brooklyn), N. Y. 

P.O. Box A, Lyons (MoCook), 111. 

740 S. Alabama St., Indianapolis 6, Ind. 

1841 Broadway, New York 23, N. Y. 

1630 W. Hill St., Louisville 10, Ky. 

244 Pine St., Newhall, Calif. 

Cleveland 17, Ohio. 

427 Washington St., New York 13 (Brooklyn), N. Y. 



164 



UNITED STATES TARIFF COMMISSION 



TABLE 27. "Synthetic organic chemicals: Directory of martufacturers, 19S4- -Continued 



Name of company 



Office addreas (location of plant given in 
parentheses if not in same city as office J 



M & M Wood Working Co- 
Maas Sc Waldsteln 

Magnolia Petroleum Co— 

Magruder Color Co., Ino 

Mallinckrodt Chemical Works — 

Maltbie Laboratories, Inc 

Marathon Corp 

Marblette Corp 



Marden-Wild Corp 

Marlowe-Van Loan Corp 

Marx, Max, Color & Chemical Co 

Maschmeijer, A,, Jr., Inc 

Maumee Chemical Co 

May, Otto B., Inc- 

Mayvood Chemical Works 

McCloskey Varnish Co 

McGean Chemical Co 

Medical Chemicals Corp 

Merck & Co., Inc 



Merichem Co- 
Merrell, Win. S., Co- 
Meta Chemical Corp — 

Metalsalts Corp 

Metro-Atlantic , Inc- 
Metro Dyestuf f Corp- 
Meyer , J . , & Sons- 
Michigan Chemical Corp 

Midland Industrial Finishes Co- 
Midland Synthetic Rubber Co. 
(F.F.C.)i 

Miles Laboratories, Inc 

Mineral Oil Refining Co 

Minnesota Paints, Inc 

Miranol Chemical Co., Inc 

Modene Paint Co., Inc 

Monsanto Chemical Co 



Montrose Chemical Co 

Montrose Chemical Corp. of California 

Moretex Chemical Products, Inc 

Morton-Withers Chemical Co 

Morvear Paint Co 



National Biochemical Co 

National Chlorophyll & Chemical Co — 
National Lead Co 



National Petro-Chemlcals Corp- 

National Polychemlcals, Inc 

National Starch Products, Inc- 



Dlv. 



Heches Butane Products Co. (F.F.C.)^- 

Nepera Chemical Co., Inc 

Neville Chemical Co- 
New Jersey Zinc Co. (of Pa.)- 

Newport Industries, Ine 

New York Color & Chemical Co. 

of American Dyewood Co. 

New York Ohio Chemical Corp 

New York Quinine & Chemical Works, 

Inc. 

Niagara Alkali Co 

Nllok Chemicals, Ino 

Ninol Laboratories, Ino 

Nonweiler, A. P., Co 

Nopco Chemical Co., Ino 

Norda Essential Oil & Chemical Co., 
Inc. 

Northwestern Chemical Co 

Norwich Pharmacal Co 

Nuodex Products Co., Ino 

Ohio Chemical 4 Surgical Equipment Co 

Oil Sc Chemical Products, Inc 

Oldbury Electro-Chemical Co 

Old Colony Tar Co., Inc 



Old Hickory Chemical Co., Inc 

Olin Mathleson Chemical Corp 



Squibb, E. R., & Sons 



Onyx Oil and Chemical Co — 
See footnote at end of table. 



2301 N. Columbia Blvd., Portland 17, Oreg. 

2121 McCarter Hwy., Newark A, N. J. 

P.O. Box 900, Dallas 21 (Beaumont), Tex. 

2385 Richmond Ter., Staten Island 2, N. Y. 

3600 N. 2d St., St. Louis 7, Mo. (Jersey City, N. J.). 

240-250 High St., Newark 1, N. J. 

Rothschild, Wis. 

37-21 30th St., Long Island City 1, N. Y. 

500 Columbia St., Somerville A3, Mass. 

1511 Byrum St., High Point, N. C. 

188-194 Colt St., Irvlngton 11, N. J. 

43 W. 16th St., New York 11, N, Y. (Newark, N. J.). 

2 Oak St., Toledo 5, Ohio. 

52 Amsterdam St., Newark 5, N. J. 

100 W. Hunter Ave., Maywood, N. J. 

7600 State Rd., Philadelphia 36, Pa. 

1040 Midland Bldg., Cleveland 15, Ohio. 

4122 W. Grand Ave., Chicago 51, 111. 

Lincoln Ave., Hahway, N. J. (Albany, Qa.; Rahway, N. J.; 

Danville and West Point, Pa.; and Eliton, Va.). 
3101 Fannin St., Houston 4 (Green's Bayou), Tex. 
Galbralth Rd. and Pennsylvania R. R., Cincinnati 15, Ohio. 
214-1/2 Washington Ave., Carlstadt, N. J. 
200 Wagaraw Rd., Hawthorne, N. J. 
2072 Smith St., Centerdale 11, R. I. 
129 W. Quidnick St., West Warwick, R. I. 
4321 N. 4th St., Philadelphia 40, Pa. 
500 N. Bankson St., St. Louis, Mich. 
E. Water St., Waukegan, 111. 
Los Angeles, Calif. 

Elihart, Ind. 

P.O. Box 625, Dickinson, Tex. 

1101 S. 3d St., Minneapolis 15, Minn, 

277 Colt St., Irvlngton 11, N. J. 

305 Eastern Ave., Chelsea 50, Mass. 

800 N. 12th Blvd., St. Louis 1, Mo. (Annieton, Ala.; Long 

Beach and Santa Clara, Calif.; Monsanto, 111.; Camden, 

N. J.; Everett and Springfield, Mass.; Trenton, Mich.; 

Texas City, Tex.; Seattle, Wash.; and Nltro, W. Va.). 
120 Lister Ave., Newark 5, N. J. 

824 Wilshire Blvd., Los Angeles 17 (Torrance), Calif. 
314 W. Henry St., Spartanburg, S. C. 
2110 High Point Rd., Greensboro, N. C. 
568 14th St., Oakland 12, Calif. 
3106 W. Lake St., Chicago 12, 111. 
Lamar, Colo. 
Ill Broadway, New York 6, N. Y. (Perth Amboy, N. J., and 

Philadelphia, Pa.) 
Box 109, Tuscola, 111. 
Eames St., Wilmington, Mass. 

270 Madison Ave., New York 16, N. Y. (Plalnfield, N. J.). 
P.O. Box 1535, Port Neches, Tex. 
21 Gray Oaks Ave., Yonkers 2 (Harrlman), N. Y. 
Neville Island, Pittsburgh 25, Pa. (Anaheim, Calif,). 
160 Front St., New York 38, N. Y. (Palmerton, Pa.) 
P.O. Box 911, Pensacola, Fla. 
Main & Joralemon Sts., Belleville 9, N. J. 

P.O. Box 616, Niagara Falls, N. Y. 

50 Church St., New York 7, N. Y. (Newark, N. J.). 

60 E. 42d St., New York 17 (Niagara Falls), N. Y. 

2000 College Ave., Niagara Falls (Lockport), N. Y. 

1719 S. Clinton St., Chicago 16, 111. 

Box 1007, Oshkosh, Wis. 

1st and Essex Sts., Harrison, N. J. (Richmond, Calif.; 

Cedartown, Ga.; and Harrison, N. J.). 
601 W. 26th St., New York 1, M. Y. (Boonton, N. J.). 

120 N, Aurora St., West Chicago, lU. 

17 Eaton Ave., Norwich, N. Y. 

830 Magnolia Ave., Elizabeth, N. J. 

1400 E. Washington Ave., Madison 10, Wis. (Cleveland, Ohio). 

295 Madison Ave., New York 17, N. Y. (Houston, Tex.). 

5001 Buffalo Ave., Niagara Falls, N. Y. 

500 5th Ave., New York 36, N. Y. (Cambridge, Framingham, 

New Bedford, and Worcester,. Mass.). 
P.O. Box 1480, Richmond 12, Va. (Old Hickory, Tenn.). 
10 Light St., Baltimore 3, Md. (Huntsvllle and Mcintosh, 

Ala.; Doe Run, Ky.; Lake Charles, La.; Niagara Falls, 

N. Y.; and Morgantown, W. Va.). 
745 - 5th Ave., New York 22, N. Y. (New Brunswick, N. J., 

and Brooklyn, N. Y. ). 
Warren & Morris Sts., Jersey City 2, N. J. 



SYNTHETIC ORGANIC CHEMICALS, 1954 

TABLE ^.'-Synthetic organic chemicaia: Directory of aanufacturera, 1954- -Contimjtd 



165 



Name of company 



Offle« address (location of plant ^ven In 
parentheses if not in same city as office) 



Orbls Products Corp 

Organic Chemical Corp- 

Organlcs, Ino 

Oronlte Chemical Co- 
Ortho Chemical Corp- 

Oabom, C. J., Co 

Ottol Oil Co 

Oxford Corp- 



Pabco Products, Inc- 
Pabst Brewing Co- 



Paclflc Paint & Varnish Co 

Pacific Yeast Products, Ine 

Pan American Refining Corp 

Parke, Davis & Co 

Parsons, M. W., Plymouth, Inc- 

Patent Chemicals, Inc 

Paul -Lewis Laboratories, Inc — 

Peck's Products Co- 

Pedlow-Nease Chemical Co., Ino 

Peerless Chemical Co 

Peerless Color Co., Inc 

Penick, S. B., & Co 



Pennsylvania Industrial Chemical Corp 
Pennsylvania Refining Co- 



Pennsylvania Salt Manufacturing Co- 



Permutlt Co 

Peters Chemical Co 

Petrollte Corp. (Tretollte Co. Dlv.)- 

Pfanstlehl Laboratories, Inc 

Pflster Chemical Works, Ino 

Pfizer, Chas., & Co., Inc 



Pharma Chemical Corp 

Phillips Petroleum Co. (F.F.C. 
Phoenix Oil Co~— 



Pitman-Moore Co., Dlv. of Allied 

Laboratories, Inc. 
Pittsburgh Coke & Chemical Co 

Fine Chemicals Dlv 

Pittsburgh Plate Glass Co 



Plastics Engineering Co- 
Polychemlcal Co- 



Portland Gas & Coke Co 

Poughkeepsie Dyestuff Corp- 
Pratt 4 Lambert, Inc- 



Premo Pharmaceutical Laboratories, 

Inc. 
Procter t Gamble Co 



Productol Co- 



Publicker Industries, Inc 

Puget Sound Pulp & Timber Co- 
Pure' Oil Co 



Purei Corp., Ltd- 
Purocalne, Inc- 



Quaker Chemical Products Corp — 
Quaker Oats Co 



R. S. A. Corp 

Raybestos Dlv. of Raybestos- 

Manhattan, Inc. 
Red Spot Paint & Varnish Co., Inc- 
Relchhold Chemicals, Inc 



Reilly Tar & Chemical Corp- 



Rellance Varnish Co., Inc- 

Remlngton Arms Co., Inc 

Republic Creosotlng Co 



601 W. 26th St., New York 1, N. Y. (Newark, N. J.). 

7<_a4 Valley St., E. Providence, R. I. 

1724 Greenleaf Ave., Chicago 26, 111. 

200 Bush St., San Francisco <l, Calif, (Oak Point, La.). 

44-26 Purvis St., Long Island City 1, N. Y. 

132 Nassau St., New York 38, N. Y. (Linden, N. J.). 

455 Cortlandt St., BelleviUe 9, N. J. 

350 Morris St. , Toledo 4, Ohio. 

475 Brannan St., San Francisco 19 (Emeryville), Calif. 

917 W. Juneau, Milwaukee IS, Wis. (Peoria, 111.). 

4th and Cedar Sts., Berkeley 10, Calif. 

703 5th St., Wasco, Calif. 

P.O. Box 401, Texas City, Tex. 

Foot of Joseph Campau, Detroit 32, Mich. 

59 Beekman St., New York 38 (Brooklyn), N. Y. 

335 McLean Blvd., Paterson 4, N. J. 

4253 N. Port Washington Rd., Milwaukee 12, Wis. 

610 E. Clarence Ave., St. Louis 15, Mo. 

P.O. Box 548, Lock Haven, Pa. 

3850 Oakman Blvd., Detroit 4, Mich. 

521-535 North Ave., Plalnfleld, N. J. 

50 Church St., New York 8, N. Y. (Jersey City, Lyndhurst, 

and Montvllle, N. J.). 
120 State St., Clalrton (Chester), Pa. 
Butler (Kama City), Pa. 
1000 Wldener Bldg., Philadelphia 7, Pa. (Calvert City, Ky.; 

Natrona, Pa.; and Portland, Oreg.). 
330 W. 42d St., New York 36, N. Y. (Birmingham, N. J.). 
2575 Ewen Ave., New York 63, N. Y. 
369 Marshall Ave., Webster Groves 19, Mo. 
104 Lakevlew Ave., Waukegan, 111. 
Foot of Linden Ave., Rldgefleld, N. J. 
630 Flushing Ave., Brooklyn 6, N. Y. (Groton, Conn., and 

Vigo, Ind.). 
175 5th Ave., New York 10, N. Y. (Bayonne, N. J.), 
BartlesvlUe, Okla. (Phillips, Tex.). 
9505 CassluB Ave., Cleveland 5, Ohio. 
1200 Madison Ave., Indianapolis 2, Ind. 

Pittsburgh 25, Pa. 

Grant Bldg., Pittsburgh 19, Pa. 

1 Gateway Center, Pittsburgh 22, Pa. (Torrance, Calif.; 
Atlanta, Ga.; Detroit, Mich.; Newark, N. J.; Barberton, 
Cleveland, and Dayton, Ohio; Sprlngdale, Pa.; Houston, 
Tex.; Natrium, W. Va.; and Milwaukee, Wis.). 

1607 Geele Ave., Sheboygan, Wis. 

494 Hunts Point Ave., New York 59, N. Y. 

Public Service Bldg., Portland 4, Oreg. 

77 N. Water St., Poughkeepsie, N. Y. 

75 Tonawanda St., Buffalo 7, N. Y. 

Ill Leunlng St., S. Hackensack, N. J. 

Gwynne Bldg., 6th & Main Sts.^ Cincinnati 2, Ohio (Long 
Beach and Sacramento, Calif.; Chicago, 111.; Kansas City, 
Kans.; Baltimore, Md.; Qulnoy, Mass.; St. Louis, Mo.; 
Staten Island, N. Y.; St. Bernard, Ohio; and Dallas, 
Tex.). 

417 S. Hill St., Los Angeles 13 (Santa Fe Springs), Calif. 

1429 Walnut St., Philadelphia 2, Pa. 

300 Laurel St., Bellingham, Wash. 

35 E. Wacker Dr., Chicago 1, 111. (Toledo, Ohio; Dollar- 
hide, Snyder, Nederland, and Van, Tex. J Cabin Creek, W. 
Va.; and Worland, Wyo.). 

9300 Rayo Ave., South Gate, Calif. (St. Louis, Mo.). 

Valley Rd., Hookessln, Del. 

Lime & Elm Sts., Conshohocken, Pa. 

Merchandise Mart Plaza, Chicago 54, 111. (Cedar Rapids, 
Io%ra; Omaha, Nebr.; and Memphis, Tenn.). 

690 Saw MIU River Rd., Ardsley, N. Y. 

75 E. Main St., Stratford, Coim. 

110-112 Main St., Evansvllle 8, Ind. 

525 N. Broadway, White Plains, N. Y. (Tuscaloosa, Ala.; 

Azusa and San Francisco, Calif.; Argo, 111.; Ballardvale, 

Mass.; Femdale, Mich.; Elizabeth, N. J.; Brooklyn, N. Y.; 

Charlotte, N. C; and Seattle, Wash.). 
1615 Merchants Bank Bldg., Indianapolis 4, Ind. (Chicago 

and Granite City, 111.; Indianapolis, Ind .;' Newark , N. J.; 

Cleveland and Dover, Ohio; Chattanooga, Tenn.; Lone Star, 

Tex.; and Fairmont, W. Va.). 
4730 Crittenden Dr., Louisville 9, Ky. 
939 Bamum Ave., Bridgeport 2, Conn. 
1615 Merchants Bank Bldg., Indianapolis 4, Ind. (Mobile and 

Florence, Ala.; Indianapolis, Ind.; St. Louis Park, Minn.; 

Lima, Ohio; Ironton, Utah; Norfolk, Va.; and Seattle, 

Wash.). 



See footnote at end of table. 



166 



UNITED STATES TARIFF COMMISSION 



TAELE 27. --Synthetic organic chaoicals: Directory of 



jfacturera, 1954- -Continued 



Name of ccmpany 



Office address (location of plant given In 
parentheses If not In same city aa office) 



Richardson Co 

Richfield Oil Corp 

Rlngwood Chemical Corp 

Rlnshed-Mason Co 

Ritter, ?., Sc Co 

Hitter Chemical Co., Ino 

Rlverdale Chemical Co 

Rohm & Haas Co 



Roosevelt Oil & Refining Co 

Royce Chemical Co 

Rubter Corp. of America 

Ruheroid Co 



Salem Oil & Orease Co 

Dr. Salabury'a Laboratories — 

Salvo Chemical Corp 

Sandoz Chemical Worlcs, Inc 

Schenectady Varnish Co., Inc- 



Scherer, R. P., Corp- 

Schering Corp — — 

Schieffelln & Co 



Scholler Bros . , Inc- 

Schuyliill Chemical Co 

Schwarz Laboratories, Inc- 

Searle, 0. D., & Co 

Seattle Gas Co 



Sharpies Chemicals, Inc- 
Shawiningan Resins Corp- 
Shef field Chemical Co., 
Shell Chemical Corp- 



Shell Oil Co- 



Shepherd Chemical Co- 
Shervln-Wllliams Co — 



Sherwood Refining Co., Inc 

Shulton, Inc., Fine Chemicals Div- 

Slddall, George F., Co., Inc 

Sinclair Refining Co 



Sinclair t Valentine Co- 
Slpe, James B., & Co 



Smith, Kline & French Laboratories- 

Snyder Chemical Corp 

Socony-Vaomm Oil Co., Inc 



Soluol Chemical Co., Inc — 
Solvent Chemical Co., Ino- 
Sonnebom, L., Sons, Inc — 



Sonoco Products Co 

SoutherE Dyestuff Corp 

Southern Sizing Co 

Southern Textile Chemical Corp- 

Spaulding Fibre Co., Inc 

Specialty Resins Co 

Specific Pharmaceuticals, Inc — 
Spencer Chemical Co——— 



Squibb, E. R., & Sons 

Staley, A. E., Manufacturing Co 

Standard Agricultural Chemicals, Inc- 
Standard Chemical Co 



Standecrd Chemical Products, Inc 

Stsmdard Chlorine Chemical Co., Inc- 
Standard Naphthalene Products Co., 

Inc. 
Standard Oil Co. of California 



Standard Oil Co. of Indiana- 



Standard-Toch-Chemicals , Inc 

Standard Ultramarine tc Color Co- 

Stange, Wm. J., Co 

Stanollnd Oil & Gas Co 

Stauffer Chemical Co——— — 



27th Ave. and Lake St., Melrose Park, 111. 

555 S. Flower St., Los Angeles 17 (Watson), Calif. 

120 S. La Salle St., Chicago 3 (Rlngwood), 111. 

5935 Milford Ave., Detroit, Mich. (Anaheim, Calif,). 

-VOOl Goodwin Ave., Los Angeles 39, Calif. 

"W3 W. Main St., Amsterdam, N. r. 

32A E. 147th St., Harvey (Dolton), 111. 

222 W. Waahlngton Sq., Philadelphia 5, Pa. (Bristol and 

Philadelphia, Pa.; Knoxville, Tenn.; and Deer Park, Tex.). 
Box 271, Mt. Pleasant, Mich. 
Carlton Ave., Carlton Hill, N. J. 
New South Rd., Hloksville, N. Y. 
500 5th Ave., New York 36, N. Y. (Joliet, 111.; Baltimore, 

Md.; and Erie, Pa.). 
60 Grove St., Salem, Mass. 
500 Gilbert St., Charles City, Iowa. 
Rothflohild, Wis. 

61-63 Van Dam St., New York 13, N. Y. (Fair Lawn, N. J.). 
Congress and 10th Ave., Schenectady 1 (Rotterdam Jet.), 

N. Y. 
9425 GrlnneU Ave., Detroit 13, Mich. 
60 Orange St., Bloomfield (Union), N. J. 
16-26 Cooper Sq., New York 3, N. Y. 
Collins and Westmoreland St., Philadelphia 34, Pa. 
2346 Sedgley Ave., Philadelphia 32, Pa. 
230 Washington St., Mt. Vernon, N. Y. 
P.O. Box 5110, Chicago 80 (Skokie), lU. 
1507 4th Ave., Seattle 11, Wash. 

1100 Wldener Bldg., Philadelphia 7, Pa. (Wyandotte, Mich.). 
644 Monsanto Ave., Springfield 2, Mass. 
P.O. Box 630, Norwich, N. Y. 
50 W. 50th St., New York 20, N. Y. (Martinez, Los Angeles, 

and Pittsburg, Calif.; and Deer Park, Tex.). 
50 W. 50th St., New York 20, N. Y. (Martinez and Wilmington, 

Calif.; Roxana, 111.; Norco, La.; and Deer Park, Tex.). 
2803 Highland Ave., Cincinnati 12, Ohio. 
101 Prospect Ave., N. W., Cleveland 1, Ohio (Chicago, 111.; 

Detroit, Mich.; Dayton and Cleveland, Ohio; and 

Philadelphia and Pittsburgh, Pa.). 
1 W. Forest Ave., Englewood, N. J. (Gretna, La.). 
Route 46, Clifton, N. J. 

P.O. Box 925, Spartanburg, S. C. (Providence, R. I.). 
600 5th Ave., New York 20, N. Y. (Sand Springs, Okla.; 

Marcus Hook, Pa.; and Houston, Tex.). 
611 W. 129th St., New York 27, N. Y. (Rldgway, Pa.). 
P.O. Box 8010, S. Hills Branch, Pittsburgh 16 (Bridgeville), 

Pa. 
1530 Spring Garden St., Philadelphia 1, Pa. 
Henry St., Bethel, Conn. 
26 Broadway, New York 4, N. Y. (PaulBboro, N. J., and 

Beaumont, Tex.). 
Green Hill and Market Sts., Natiok, R. I. 

341 Commercial St., Maiden 48, Mass. 

300 4th Ave., New York 10, N. Y. (Petrolla, Pa., and Hutley, 

N. J.). 
Hartsville, S. C. 

P.O. Box 1045, Charlotte 1 (Sodyeco), V. C. 
P.O. Box 391, 601 Campbell St., East Point, Ga. 
1A07 Broadway, New York 18, N. Y. (Clearwater, S. C). 
310 Wheeler St., Tonawanda, N. Y. 
2801 Lynwood Rd., Lynwood, Calif. 
331 4th Ave., New York 10, N. Y. (Bayonne, N. J.). 
610 Dwlght Bldg., Kansas City 5, Mo. (Calumet City, 111., 

and Pittsburg, Kans.). 
See Olin Mathleson Chemical Corp. 
Decatur, 111. 

1301 Jefferson St., Hoboken, N. J. 
217-219 New St., Philadelphia 6, Pa. 
1301 Jefferson St., Hoboken, N. J. (Charlotte, K. C). 
115 Jacobus Ave., S. Kearny, N. J. 
115 Jacobus Ave., S. Keamy, N. J. 

225 Buflh St., San Francisco 20 (Bakersfield, El Segundo, 

and Richmond), Calif. 
910 S. Michigan Ave., Chicago 80, 111. (Wood River, 111.; 

Whiting, Ind.; and Sugar Creek, ito.). 
2600 Richmond Ter., Staten Island 3, N. Y. 
5th Ave. and 24th St., Huntington, W. Va. 

342 N. Western Ave., Chicago 12, 111. 

P.O. Box 591, Tulsa, Okla. (Brownsville, Alvin, Andrews, 

Katy, Pettus, Sundown, and Sweeney, Tex.). 
380 Madison Ave., New York 17, N. Y. (LaMoyne, Ala.; 

Henderson, Nev.; Brooklyn and Niagara Falls, N. Y. ; 

Perry, Ohio; Chester and Moncmgahela, Pa.; Lowland, 

Tenn.; and Bentonvllle, Va.). 



See footnote at end of table. 



SYNTHETIC ORGANIC CHEMICALS, \95U 

TABLE 27. --Synthetic organic cheaicala: Directory of aanufacturera, 19 34- -Continued 



167 



Name of company 



Office addresa (location of plant fflvan in 
parentheses If not In same city as office) 



Stepan Chemical Co- 
Sterling Drug, Inc. 
Bayer Co. Dlv ■ 



Hlltou-Davls Chemical Co, Dlv 

Stresen-Reuter , Fred'k. A., Inc 

Strong, Cobh & Co., Inc., American 

Chlorophyll DlT. 

Summit Chemical Products Corp 

Sunmer Chemical Co., Inc 

Sun Chemical Corp.: 

Pigment Dlv- 



Warvlck Chemical Co. Dlv- 



Suntlde Refining Co- 
Svift & Co 



Synthetic Chemicals, Inc- 
Synthetlc Products Co— — 

Synvar Corp 

Tar Distilling Co., Inc— 
Taylor Fibre Co 



Tennessee Eastman Co., Div. of 

Eastman Kodak Co. 
Tennessee Products & Chemical Corp- 



Texas Co — 



Texas Eastman Co., Dlv. of Eastman 

Kodak Co. 

Thiokol Chemical Corp 

Thomasset Colors, Inc 

ThampBoa Chemicals Corp 

Trask, Arthur C, Co 

Treplow Products, Inc 

Trojan Powder Co 

Trubek Laboratories 

Uhlich, Paul, i Co., Inc 

Ultra Chemical Works, Inc 

Union Bay State Chemical Co., Inc — 
Union Carbide S: Carbon Corp.: 

Bakellte Co 



Carbide & Carbon Chemicals Co- 



Linde Air Products Co- 



Union Oil Co. of California- 



United Piece Dye Works 

U. S. Industrial Chemicals Co., Dlv. 

of National Distillers Products 

Corp. 
U. S. Oil Co 



United States Pipe 8: Foundry Co 

U. S. Plastic Products Corp 

United States Procaine Co., Inc 

U. S. Rubber Co., Naugatuck Chemical 

Div. 
U. S. Rubber Co. (F.F.C.)^ 



Universal Detergents, Inc — 

Upjohn Co- 

van Ameringen-Haebler, Inc- 



Van Camp Laboratories 

Vanderbilt Chemical Corp- 
Van Dyk & Co., Inc 



Varcum Chemical Corp 

Velslcol Corp., Dlv. of Arvey Corp 



Verley Chemical Co. 
Verona Chemical Co- 
Versenes, Ino- 



Vlctor Chemical Works 

Virginia-Carolina Chemical Cor 
Vitamins, Inc- 



Vlta-Var Corp 

Wallace & Tleman, Inc- 

Harchem Div 

Luc Idol Dlv 



Warner- Jenkinson Manufacturing Co 

Warren Petroleum Corp 

Washburn, T. F., Co 

Watertown Manufacturing Co 



20 N. Wacker Dr., Chicago 6, 111. 

U50 Broadway, New York 18, N. Y. (Trenton, N. J.). 
2235 Langdon Farm Rd., Cincinnati 13, Ohio. 
2113 Medin Ave., Chicago 47 (Bensenvllle ) , 111. 
P.O. Box 231, Lake Worth, Fla. 

11 WlUiam St., Belleville 9, N. J. 
215 N. Centennial St., Zeeland, Mich. 

309 Sussex St., Harrison, N. J. 

10-10 AAth Ave., Long Island City, N. Y. (Wood River 

Junction, R. I., and Rock Hill, S. C). 
1608 Walnut St., Philadelphia 3 (Marcus Hook), Pa. 
P.O. Box 658, Carpus Chrlstl, Tex. 
4115 Packers Ave., Chicago 9, 111. 
335 McLean Blvd., Paterson A, N. J. 
1636 Wayside Rd., Cleveland 12, Ohio. 
419 E. Front St., Wilmington 99, Del. 
500 5th Ave., New York 36, N. Y. (Cleveland, Ohio). 
Norrlstown (Betzwood), Pa. 
See Eastman Kodak Co. 

First American National Bank Bldg., Nashville 3 (Chatta- 
nooga), Tenn. 
P.O. Box 2332, Houston 1, Tex. 
See Easlnian Kodak Co. 

780 N. Clinton Ave., Trenton 7, N. J. 

338 Wilson Ave., Newark 5, N. J. 

3028 Locust St., St. Louis 3, Mo. 

4103 S. LaSalle St., Chicago 9, HI. 

59 Carapen St., Paterson, N. J. 

17 N. 7th St., Allentown (Selple), Pa. 

Box F, E. Rutherford, N. J. 

90 West St., New York 6 (Brooklyn), N. Y. 

2 Wood St., Paterson 4, N. J. 

491 Main St. , Cambridge 42, Mass. 

30 E. 42d St., New York 17, N. Y. (Ottawa, 111.; Wyandotte, 

Mich.; Bound Brook, N. J.; and Marietta, Ohio). 
30 E. 42d St., New York 17, N. Y. (Whiting, Ind.; Niagara 

Falls, N. Y.; Port Lavaca and Texas City, Tex.;^ and S. 

Charleston, W. Va.). 
30 E. 42d St., New York 17 (Tonawanda), N. Y. 
617 W. 7th St., Los Angeles 17, Calif, (Bakersf leld , Rodeo, 

Santa Maria, and Wilmington, Calif.; Cut Bank, Mont.; and 

Edmonds, Wash. ) . 
Nicholson St., Lodl, N. J. 
120 Broadway, New York 20, N. Y. (New Orleans, La., and 

Baltimore, ha.). 

Box 1345, Providence (Phlllipsdale), R. I. 

P.O. Box 2651, Birmingham, Ala. 

Lake & Whitman Aves., Hetuchen, N. J. 

2911 Atlantic Ave., Brooklyn 7 (College Point), N. Y. 

1230 Ave. of the Americas, New York 20, N. Y. (Naugatuck, 

Conn.). 
1230 Ave. of the Americas, New York 20, N. Y. (Naugatuck, 

Conn., and Port Neches, Tex.). 
1825 E. Spring St., Long Beach 6, Calif. 
301 Henrietta St., Kalamazoo 99, Mich. 
521 W. 57th St., New York 19, N. Y. (Elizabeth and Union 

Beach, N. J.). 
772 Tuna St., Terminal Island, Calif. 
230 Park Ave., New York 17, N. Y. (Bethel, Conn.). 
11 William St., Belleville 9, N. J. 
P.O. Box 476, Niagara FaUs, N. Y. 
330 E. Qrand Ave., Chicago 11, 111. (Marshall, 111., and 

Meinphls, Tenn.). 
200 Pulaski St., Newark 5, N. J. 
26 Verona Ave., Newark 4, N. J. 
875 Waver ly St., Framingham, Mass. 
155 N. Wacker Dr., Chicago 6, 111. 

401 E. Main St., Richmond 5, Va. (Charleston, S. C). 
809 W. 58th St., Chicago 21, 111. 
10 Commerce Ct., Newark 2, N. J. 
25 Main St., Belleville 9, N. J. 
25 Main St., Belleville, N. J. (Dover, Ohio). 
1740 Military Rd., Buffalo 5, N. Y. 
2526 Baldwin St., St. Louis 6, Mo. 
P.O. Box 1589, Tulsa, Okla. 
2244 Elston Ave., Chicago 14, 111. 
127 Echo Lake Rd., Watertown, Conn. 



See footnote at end of table. 



168 UNITED STATES TARIFF COMMISSION 

TAaX 27. --Synthetic organic cheaicaia: Directory cf manufacturers, I95¥- -Continued 



Name of ccaipany 



Office address (location of plant given In 
parenthesea If not In same city as office) 



164 
165 

462 

96 

166 

37 

102 

498 

490 

11 

278 

237 

247 

128 

573 
445 
574 

471 

446 
366 
359 



Werner Drug & Chemical Co- 
Western Condensing Co — 
Western Dry Color Co— 
Westlnghoufle Electric Corp- 



Westvllle Laboratories 

Wetherlll, George D., Vamlsh Co 

Wheeler, Reynolds & Stauffer 

White & Bagley Co 

White & Hodges, Inc- 
Whittemore-Wrlght Co. 
Wica Co., Inc 



Wllmot & Cassldy, Inc- 
Wllson Lahoratorles- 



Wilson Organic Chemicals, Inc- 

Wlnthrop-Steams, Inc 

Wltco Chemical Co— 



Wltte, John H., & Sons 

Wolf, Jacques, 4 Co 

Wyandotte ChemioalB Corp- 
Wyeth Laboratories, Inc — 

Young Aniline Works, Ine- 
Zlnsser & Co. , Inc — 
Zum, 0. F., Co— — 



759 Beechwood Ave., Cincinnati 32, Ohio. 

P.O. Box 739, Appleton (Adell), Wis. 

600 W. 52d St., Chicago 9, 111. 

401 Liberty Ave., P.O. Box 2278, Pittsburgh 30 (East 

Pittsburgh), Pa. 
Stepney (Monroe), Conn. 

Haddon Ave. & White Horse Pllce, Canden 3, N. J. 
636 California St., San Francisco 8 (Richmond), Calif. 
100 Foster St., Worcester 8, Mass. 
2 Wellington Ave., Everett 49, Mass. 
62 Alford St., Charlestown 29, Mass. 
P.O. Box 506, Charlotte 1, N. C. 
108-112 Provost St., Brooklyn 22, N. Y. 
4221 S. Western Ave., Chicago 9, lU. 
P.O. Box 452, SayreviUe, N. J. 
1450 Broadway, New York 18 (Rensselaer), N. Y. 
260 Madison Ave., Hew York 16, N. Y. (Lynwood, Calif.; 

Chicago, 111.; and Brooklyn, N. Y.). 
206 Jefferson St., Burlington, Iowa. 
356 Lexington Ave., Passaic, N. J. 
1609 Blddle Ave., Wyandotte, Mich. 
1401 Walnut St., Philadelphia 2, Pa. (Chicago, 111.; and 

Marietta, Philadelphia, and West Chester, Pa.). 
2731 Boston St., Baltimore 24, Md. 
HastingB-on-Hudson 6, N. Y. 
2736 N. Broad St., Philadelphia 32, Pa. 



^ F.F.C. in parentheses following the name of a ccnpany Indicates U. 
Federal Facilities Corporation. 



S. GoTemment plant operated for the 



APPENDIX 

A. United States Imports of Coal- Tar Intermediates and 
Finished Coal- Tar Products 

Table 28 summarizes, for the period 1952-54, United States 
imports of coal-tar products dutiable under paragraphs 27 and 28 
of the Tariff Act of 1930. The data, which were obtained by ana- 
lyzing invoices covering imports through all United States customs 
districts, are given in detail in a separate report of the Tariff 
Commission. ^ 

Imports in 1954 of coal-tar chemicals entered under paragraph 
27, virtually all of which are intermediates, totaled 8.6 million 
pounds, with a foreign invoice value of 4. 5 million dollars. In 1953, 
imports were 22. 3 million pounds, valued at 5.4 million dollars, 
and in 1952 they were 3. million pounds, valued at 1. 7 million 
dollars. The very large decrease in the quantity of imports in 
1954, compared with 1953, was due primarily to greatly reduced 
imports of phthalic anhydride (681,000 pounds in 1954, compared 
with l6. 7 million pounds in 1953). About three-fourths of all inn- 
ports of intermediates in 1954 came fronn Germany and the United 
Kingdom. Imports from Germany totaled 4. 9 million pounds in 
1954, compared with 7.7 million pounds in 1953; imports from 
the United Kingdom were 1.9 million pounds in 1954, compared 
with 4.9 million pounds in 1953. In 1954 sizable quantities of in- 
termediates were also imported from the Netherlands and Switzer- 
land. 

In terms of quantity, the three most important intermediates 
imported were adipic acid, caprolactam, and naphthalene. Im- 
ports of naphthalene totaled 1. 3 million pounds in 1954, and im- 
ports of adipic acid and caprolactam each totaled 1. 1 million 
pounds. Imports of adipic acid came entirely from Germany; 
caprolactam, chiefly from Germany; and naphthalene, principally 
from Germany and the Netherlands. In 1954 there also were siza- 
ble imports of phthalic anhydride (681,000 pounds), principally 
from Germany and Italy, and m-chloroaniline (403, 000 pounds), 
all from Gernnany. 

In 1954, innports of all finished coal-tar products that are duti- 
able under paragraph 28 totaled 4. 1 million pounds (actual weight), 
with a foreign invoice value of 8. 7 million dollars, compared with 
3.4 million pounds, valued aX 6.9 million dollars in 1953, and 4. 5 
nnillion pounds, valued at 6.9 million dollars, in 1952. It should 
be noted that the data for 1953 and 1954 are based on general im- 
ports, whereas the data for 1952 are based on imports for con- 
sumption. The differences between general imports and imports 
for consumption are small, however, so that the data for the 3 
years are comparable. 



' U. S. Tariff Commission , Imports of CoaL-Tar Products, 1954 [processed]. 

169 



170 



UNITED STATES TARIFF COMMISSION 



-Coal-tar intermediates and finished coal' tar products 
by use, 1952-54 



United States imports, classified 



Foreign 
Invoice 
value 



Quantity 



Foreign 
invoice 
value 



Quantity 



Foreign 
invoice 

value 



Intermediates^ 



Finished coal-tar products, total- 



3,028 



1.000 
iolUrs 

\,7A9 



1,000 

dollars 

5,<tl9 



8,579 



1,000 
dollar, 
4,510 



6,93i 



3,39-4 



4,064 



8,672 



Dyes, total- 
Add 

Vat 



2,175 



Mordant and chrome — 

Sulfur 

Direct 



Acetate rayon 

Color-laie and spirit-soluble 

All other—— 



Medlclnals and pharmaceuticals 

Flavor and perfume materials 

All other — — 



247 
896 
247 
30 
509 
48 
95 



2,138 



4,404 



705 
1,192 

593 

29 

1,245 

123 

240 
15 
52 

210 

1,928 

18 

584 



2,555 



43 
398 

132 

379 
105 
355 



4,594 



1,043 
1,240 
313 
38 
958 
147 
99 
88 
299 
369 

1,925. 
194 
192 



^ 3,005 



4<59 

1,045 

170 



435 
396 

497 
176 
386 



5,832 



1,094 
1,228 
291 
24 
913 
131 



361 
1,673 

2,150 
326 
364 



Includes small quantities of organic pesticides, rubber-processing chemicals, and surface-active agents. 
^ Actual weight; the computed weight (corrected to the standard of strength established by the Secretary of 
the Treasury) was 2,703 thousand pounds In 1952, 3,255 thousand pounds In 1953, and 4,042 thousand pounds in 
1954. 

Source: Compiled from the records of the U. S. Bureau of Customs. 

Note. — The statistics for 1953 and 1954 are based on general imports; the statistics for 1952 are based on 
imports for consumption. The statistics for 1953 and 1954, therefore, are not strictly comparable with those 
for 1952. The differences, however, are small, so that comparisons are significant. 



As in previous years, dyes were by far the most important 
group of finished coal-tar products imported in 1954, accounting 
for 5.8 inillion dollars, or 67 percent of the total foreign invoice 
value of all imports under paragraph 28. In 1953, imports of dyes 
were valued at 4.6 million dollars. In 1954, Germany was the 
principal supplier, accounting for 55 percent of total imports of 
dyes (based on computed weight). Medicinals and pharmaceuticals 
were the next most important group of products imported under 
paragraph 28 in 1954. In that year, imports of these products were 
valued at 2.2 million dollars, or 25 percent of the total foreign in- 
voice value of all imports under paragraph 28. In each of the years 

1952 and 1953, imports of medicinals and pharmaceuticals were 
valued at 1.9 million dollars. Imports of flavor and perfume ma- 
terials increased in value to $326, 000 in 1954 from $ 194, 000 in 

1953 and $18,000 in 1952. Imports of other coal-tar products en- 
tered under paragraph 28 were valued at $364, 000 in 1954, com- 
pared with $192, 000 in 1953 and $584, 000 in 1952. 

B.. Research Workers and Research Expenditures in 
the S3nithetic Organic Chemical Industry 



Because of the interest of the synthetic organic chemical indus- 
try in statistics on chemical research, the Tariff Commission each 
year collects and publishes statistics on the number of technically 
trained research workers in the industry, their salaries, and the 
cost of research (see table 29). This informiation is not available 
elsewhere. As many of the companies that produce synthetic or- 
ganic chemicals also manufacture other products, the data are only 
approximate; for some companies the allocation of the cost of re- 



SYNTHETIC ORGANIC CHEMICALS, 1954 



171 



search on synthetic organic chemicals is somewhat arbitrary. Not- 
withstanding this limitation, the statistics do indicate trends in the 
amount of research done in the synthetic organic chemical indus- 
try. The data here reported probably cover about 85 percent of the 
industry's total expenditure for research activities. 

In 1954 a total of 388 companies reported on research activities. 
The number of technically trained research workers (earning not 
less than $3, 600 per year) reported for 1954 was 13, 474, a some- 
what larger number than the 12, 208 reported for 1953. The aver- 
age salary paid in 1954 was $7, 009, compared with $6, 856 in 1953. 
Total salary payments made to research workers in 1954 were 
94.4 million dollars, compared with 83.7 million dollars in 1953. 
In 1954 the gross cost of research was 236. 5 million dollars, an 
increase of 26. 5 million dollars over that in 1953. The cost to the 
industry in 1954 for research conducted for it outside of the facil- 
ities of the reporting companies --a cost not included in the figures 
given above--was 9.2 million dollars, or 1.3 million dollars more 
than in 1953. This figure, however, does not represent all research 
projects in universities and private laboratories, or all consulting 
services. 



TAHLE 29. -'Synthetic organic chemical industry: Number of research workers, 
workers, and cost of research, 1946-54 



Biaries paid research 



Companies 
reporting 



Technically 
trained 
research 
workers ^ 



Salaries 

paid 
research 
workers 



Total reported cost of research 



Within the plant 



QrosB 



Nef^ 



Outside 

the 
plant 



1,000 
dollars 



1946 

1947 

1948 

1949 

1950 

1951 

1952 

1953 

1954 



313 
301 
303 
338 
335 
353 
381 
363 
388 



7,527 
8,707 
9,114 
8,916 
10,529 
9,984 
12,203 
12,203 
13,474 



35,791 
41,571 
46,346 
51,521 
56,619 
67,376 
76,701 
83,694 
94,432 



73,376 
90,640 
98,729 
105,333 
115,191 
149,607 
194,993 
210,035 
236,524 



1.000 
dollars 
69,412 
87,825 
95,417 
100,580 
111,374 
144,784 
186,503 
199,829 
221,842 



4,249 
4,600 
4,594 
4,996 
6,648 
6,724 
9,603 
7,951 
9,238 



^ For the years 1946-50, a technically trained research worker was defined as a person with technical 
training engaged in research work and earning not less than t2,500 per year; for 1951-54, the minimum amount 
of earnings was fixed at $3,600. 

^ The net cost figure is obtained by deducting from gross cost the credits for salable products obtained 
in the course of research. 

C. Glossary of Synonymous Names of Cyclic Intermediates 



Many cyclic intermediates are known in the chemical trade by 
a variety of names. Individuals in the trade frequently are not ac- 
quainted with all the synonymous names for a given product. To 
bring together the synonymous nannes for each product, the tables 
on intermediates in this report (table 7A in part II, and table 7B in 
part III) show the standard name, in accordance with the system 
used by Chemical Abstracts; this standard name is frequently fol- 
lowed by the most common synonymous name in parentheses. 



172 UNITED STATES TARIFF COMMISSION 

In this report, as in previous reports in this series, the Tariff 
Commission has included a glossary of synonymous names of cy- 
clic intermediates. This glossary, which originally was compiled 
at the suggestion of the Industry Advisory Committee on Govern- 
ment Reports, is intended to serve principally as an index to the 
standard names used in the tables on intermediates. The first 
column of the glossary lists alphabetically the common, or trivial, 
names usually encountered in the trade. The second column gives 
the corresponding standard (Chemical Abstracts) names, under 
which the data are presented in tables 7A and 7B. 



SYNTHETIC ORGANIC CHEMICALS, \95U 

Cyclic intermediates: Gloaaary of synonymous names 



173 



Common name 



Acedian throne 

p-Acetamldobenzenesulfonyl chloride 

5-Aoetamido-2-hydroxybenzolc acid 

5-Acetamido-orthanllic acid 

Aoetanilide-p-eulfonlc acid 

Aeetanllld sulfon chloride 

p-Acetoacetchloranlllde — — 

Acetoaoet-o-chloroanlllde 

o-Acetoacetochloroanillde 

B-Acetoacetoxylldlde 

Acetoacet-o-toluldlde 

Aoetoacet-o-toluldlne 



Acetoacetyl-o-anlsldlne 

AcetOBcetyl benzidine 

Acetylacet-o-phenylacetoacetanillde 

Acetyl -p-amlno-o-amlnophenol hydrochloride 

Acetylamlno Cleve's acid 

Acetyl -o-anlsldlne 

Acetyl -p-anlsldlne 

Acetyldiamlnoanthraqulnone 

Acetyl-2,4-dlamlnophenol hydrochloride 

Acetyl H acid 

Acetyl-lj-i-naphthalenedlamine-eCand 7)-suLfonlc aclda 

Acetyl -p-nitro-o-amlnophenol 

Acetyl -m-phenylenediamlne 

Acetyl -p-phenylenedlamine 

Acetyl-p-phenylenedlamlne sulfate 

N^-Acetylsulfanllamide 

N*-Acetylsulfanllamlde 

2-(N*-Acetylsulfanllamldo)thlazole 

K'-Acetyl-2-sulfo-p-phenylenedlamine 

N-Acetyl-o-toluldlne ~ 

p-Aminoazobenzene ■• — 

Aminoazobenzene dlsulfo acid 

Aminoazobenzene-3,'i-disulfonlc acid — 

p-Amlnoazobenzene hydrochloride 

Amlnoazobenzene-m-eulfonlc acid 

Aminoazobenzene -p-sulfonic acid 

o-Amlnoazo toluene 

o-Amlnoazotoluene sulfate 

o-Amlnoazotoluenesulfonic acid and salt 



Aminoazoxylene 

Aminoazoxylenetoluidine 

8-Amino-l,2-benzacrldin-7(12)-one — 

8-Amino-l,2-benzacridone 

p-Amlnobenzenearsonlc acid 

m-Amlnobenzenesulfonlc acid 

p-Amlnobenzenesulfonic acid 

o-Aminobenzoic aold- 



Standard (Chemical Abetracte) name 



m-Aminobenzoyl I(or J) acid 

p-Aminobenzoyl I(or J) acid 

o-Aminobenzylsulfonlc acid 

o-Aminobiphenyl 

2-Aminobiphenyl — *- — 

"i-Aminobiphenyl 

l-Amino-2-bromo— i-(p-toluidine)anthraqulnone — 

5-Amlno-2-chlorobenzenesulfonic acid 

5-Amino-3-chlorobenzenesulfonlc acid 

5-Amlno-^-ohlorobenzenesulfonlo acid 

5 -Amino -2 -chlorobenzo Ic ac id 

2-Amlno -4 -chloro toluene 

2-Amlno-5-chloro toluene — 

2-Amino -6 -chloro toluene 



2-Amlno-5-chlorotoluene hydrochloride 

m-Amlno-p-cresol 

3-Amino-p-cresol methyl ether 

3-Amino-p-cresyl methyl ether 

Amlnod ichlorobenzeneaulf onlc ac id 

2-Aminodlcyclohexyl 

2-Amlno-l,4-diethoxybenzene 

2-Amlno-5-dlethylaminotoluene hydrochloride 

p-Aminodiethylanillne 

4-Amlno-l,3-dihydroicyanthraquinone 

2-Amino-l,4-dimethoxybenzene 

P-Aminodimethylanlline .__ 

p-Amlnodimethylaniline hydrochloride — 

p-Amlnodlmethylanillne sulfate 

2-Amino-4,6-dinltrophenol and salt 

p-Aminodlphenyl f- 



Aceanthra [2, 1-a) aceanthrylene-5 , 13-dlone, 

N-Acetylsulfanllyl chloride. 

5-Acetamldosalicyllc acid, 

5-Acetamido-2-amlnobenzene8ulfonio acid. 

N-Acetylsulfanlllc acid. 

N-Acetylsulfanilyl chloride. 

p-Chloroacetoacetanillde . 

o-Chloroacetoacetanlllde. 

o-Chloroacetoacetanillde. 

2,4-Acetoaceto5tylidlde. 

o-Acetoacetotoluidide. 

o-Acetoaoetotoluldlde, 

o-Acetoacetanisidide, 

p,p '-Blacetoacetanllide, 

Y-(o-Acetoacetophenyl)acetoacetanlllde. 

'i-Acetamldo-2-aminophenol hydrochloride. 

8-Aoetamido-5-amlno-2(and 3)-naphthaleneBulfonic acid. 

o-Acetanlsldide. 

p-Acetanisidlde. 

1 , 5 ( or 1,8) -Diacetamidoanthraqulnone . 

'i-Acetamido-2-amlnophenol hydrochloride. 

8-Acetamido-l-naphthol-3,6-dlsulfonlc acid. 

8-Acetamido-5-amlno-2{and 3 ) -naphthalenesuLf onie 

acid. 
2-Acetamldo-4-nitrophenol, 
m-Aminoacetanllide. 
p-Amlnoacetanlllde. 
p-Aminoaoetanilide sulfate. 
N-Sulfanilylacetamide. 
p-Sulfamylacetanilide. 
p-2-Thlazolylsulfamylacetanilide. 
5-Aoetamido-2-amlnobenzenesuLfonlc acid. 
o-Aoetotoluldlde. - 
l-Amlno-2^iaphthol-i-sulfonic acid. 
8-Amino-6-methoxyquinollne. 
p-Phenylazoanlllne. 

6-Amino-3,'i'-azobis[benzenefiulfonlc acid] . 
6-Amlno-3,4'-azobls[benzenesulfonlc acid] . 
p^henylazoanlline hydrochloride. 
m-(p-Aminophenylazo )benzenesulf onlc acid. 
p-(p-Amlnophenylazo)benzenesulfonlc acid. 
4-(o-Tolylazo)-o-toluldine. 
"i-{o-Tolylazo)-o-toluidine sulfate. 
4-(A-Amino-m-tolylazo)-iii-toluenesulfonic acid and 

salt. 
4-(2,'i-Xylylazo)-2,5-xylidlne. 
— I ';-(2,'i-Xylylazo)-o-toluldine. 
8-Amlnobenz[a] acrldin-7(12)-one. 
8-Aminobenz[ a] aerldln-7( 12 ) -one. 
Arsanilic acid. 
Metanllic acid. 
Sulfanilic acid. 
Anthranllic acid. 

6-(m-Aminobenzamldo)-l-naphthol-3-3Ulfonlc acid. 
6-Cp-Aminobenzamido)-l-naphthol-3-sulfonic acid. 
o-Toluidinomethanesulfonic acid. 
2-Blphenylamine. 
2 -Bipheny lamine . 
Xenylamine. 

l-Amino-2-bromo-4-(p-toluidlno)anthraquinone. 
6-Chlorometanilic acid. 
5-Chlorometanilic acid. 
4-Chlorometanilic acid. 
3-Amino-6-chlorobenzoic acid. 
5-Chloro-o-toluldine. 
4 -Chloro -o-toluldlne. 
6-Chloro-o-toluldlne. 
4-Chloro-o-toluidine hydrochloride. 
2-Amino -^-cresol. 
5-Methyl-o-anisidlne. 
5-Methyl-o-anisldlne. 
2,5-Dichloro3ulfanillc acid. 
2-Aminobicyolohexyl. 
2 , 5-Diethoxyaniline. 

N',N' -Diethyl to luene-2,5-diamine hydrochloride. 
N, N-Dlethyl-p-phenylenedlamlne. 
4-Ajninoxanthopurpurin. 
2 , 5-Dimethoxyanl line . 
N,N-Dlmethyl-p-phenylenediamine. 
N,N-Dimethyl-p-phenylenedlamlne hydrochloride. 
N,N-DijEethyl-p-phenylenedlamine sulfate. 
Picramic acid and salt. 
-] 2-Blphenylamlne. 
- Xenylamine. 



174 



UNITED STATES TARIFF COMMISSION 



Cyclic intermediatem: Gloaaary of ayntMiymoua namea — Continued 



ComiDOn name 



Standard (Chemical Abstracts) name 



p-Amlnodlphenylamlne 

'♦-Amlnodlphenylamine-2 -sulfonic acid 

Amlnodlphenyl ether 

"i-Amlnoethoxyethylanlllne 

Amino G acid 

Amino I(or J) acid 

p-Amlno-N-lsobutylphenol 

5-Amino-2-methoxybenzyl alcohol 

"♦-Amlno-i-methoxydlphenylamlne-S -sulfonic acid 

"l-Amlno-l-naphthalenesulfonic acid 

2-Amlnonaphthalene-3,6,8-trlsulfonlc acid 

l-Amlno-7-naphthol 

l-Amlno-8-naphthol-4,6-dlsulfonic acid 

i-Amlno-5-naphthol-l,7-disulfonlc acid 

l-Amlno-8-naphthol-2,4-dlsulfonio acid, monosodium 

salt, 
l-Amino-fl-naphthol-3,6-disulfonlc acid, monosodium 

salt. 
2-Amlno-8-naphthol-3,6-dlaulfonlc acid, monosodium 

salt. 
'4-Amino-5-naphthol-l,3-disulfonlc acid, monosodium 

salt, 
5-Amino-4-naphthol-2,7-disulfonio acid, monosodium 

salt. 
6-Amino-4-naphthol-2,7-dlsulfonic acid, monosodium 

salt. 

2-Amlno-6-naphthol-8-sulfonic acid 

^-Amlno -3 -naphthol -1 -sulf onl c acid 

7-Amlno-3-naphthol-l-Eulfonlc acid 

l-Amlno-8-naphthol-<4-sulfonlc acid, sodium salt 

2-Amino-5-naphthol-7-sulfonlc acid, sodium salt 

2-Amino-8-naphthol-6-sulfonlc acid, sodium salt 

"i-Amino-S-naphthol-l-sulfonlc acid, sodium salt 

6-Amino— 4-naphthol-2-8ulfonlc acid, sodium salt 

7-Amino-i-naphthol-2-sulfonlc acid, sodium salt 

2-Amino-^-nitroanl8ole 

2-Amino-5-nltroanlsole 

2-Amino-6-nltroanisole 

'i-Amlno-3-nitroanlsole 

'4-Amlno-4-nltrodiphenylamine-2 -sulfonic acid 

2-Amlnophenetole 

Amlnophenol sulf amide 

o-Aminophenol-p -sulfonamide 

o-Aminophenol-p-sulfonio acid 

Amlnophenylphenyl ether 

m-Aminophenylpyrazoloneoarboxylie acid 

l-(m-Aminophenyl )-5-pyrazolone-3-oarboxyllc acid 

p-Aminophenyl-p-tolylamInes,ilf onic aci d 

Amino R acid 

6-AmIno-3-(p-toluene sulfone^B.'-iiuo-fc-methoxytoluene — 

i' -Amlno-(p-toluenesulfone )ethoxytoluene 

2-Aminotoluene-5-aulfonic acid 

Aminovlolanthrene 

Anillne-2,';-disulfonlc acid 

Anillne-2,5-dl8ulfonic acid 

Aniline hydrochloride 

Aniline oil 

Anlllne-m-sulfonlc acid 

Anlllne-p-sulfonic acid- 
Anlline-omega-Bulfonic acid, sodium salt- 

6-AnillnoBstanlllc acid — — 

o-Aiilside-4-acetylurea- 
2-Anl8 Ide-^-acetylurea- 



2-AiilBldlne-4-aulfobutylamids 

o-Anlsldine-onega-eulfonlc acid ■ 

1,4,9, lO-Anthratetrol 

l,9-Anthrathiazole-2-carbonyl, chloride 

l,l'-Azobis(2-naphthol-<l-6Ulfonic acid) 

l,l'-A2obls(8-nitro-2 -naphthol -4-sulfonic acld)- 

5, 5,' -Aaobl8( salicylic acid ) 

Azohydroiyanlline 

Azoxyanillne 

m,m'-Azoxybisaniline 



Benzal chloride 

Benzaldehydedisulfonlc acid — 

Benzaldehydemonosulfonlc acid 

l-(4^enzamldo-l-anthraquinonyllmino)-5-benzamido- 
anthraqulnone. 

Benzanthrone 

Beuzanthronedianthraquinonyldi-imide 



N-Phenyl-p-phenylenedlamlne. 
5-Amlno-2-anllinobenzenesulfonic acid, 
p-Phenoxyanl line, 

2-(p-Amino-N-ethylanllino)ethanol, 
7-Amino-l,3-naphthalenedlsulfonlc acid, 
6-Amino-l,3-naphthalenedi8ulfonic acid, 
p-Isobutylaminophenol, 
5-Aminosallgenln-2-methyl ether, 
6-Anllino-2-methoitymetanillc acid, 
Naphthionlc acid, 

7-Amino-l,3,6-naphthalenetrisulfonlc acid. 
8-AmIno -2 -naphthol, 

8-Amino-l-naphthol-3,5-disulfonic acid, 
8-Amino-l-naphthol-3,5-disulfonlc acid, 
8-Amino-l-naphthol-5,7-disulfonlc acid, monosodium 

salt, 
8-Amino-l-naphthol-3,6-disulfonlc acid, monosodium 

salt. 
7-Amlno-l-naphthol-3,6-dlsulfonic acid, monosodium 

salt, 
8-Amlno-l-naphthol-5,7-dlsulfonic acid, monosodium 

salt, 
8-Amlno-l-naphthol-3,6-dlsulfonio acid, monosodium 

salt, 
7-Amino-l-naphthol-3,6-disulfonlc acid, monosodium 

salt, 
6-Amlno-2-naphthol-4-sulfonlo acid, 
l-Amlno-2-naphthol-4-sulfonlc acid. 
6-Amino-2-naphthol-4-sulfonlc acid. 
8-Amino-l-naphthol-5-sulfonlc acid, sodium salt. 
6-Amino-l-naphthol-3-sulfonlc acid, sodium salt. 
7-Amlno-l-naphthol-3-Bulfonic acid, sodium salt. 
8-AmIno-l-naphthol-5-sulfonic acid, sodium salt, 
7-Amlno-l-naphthol-3-8ulfonlc acid, sodium salt, 
6-Amino-l-naphthol-3-sulfonic acid, sodium salt, 
5-Nitro-o-anlsldlne, 
4-Nltro-o-anlsidine, 
6-Nltro-o-anlsldine, 
2-Nltro-p-anlsldine^ 

2-(p-Aminoanlllno )-5-nitrobenzenesulfonic acid, 
o-Phenetldlne. 

2-Amino-l-phenol-4-sulfonamide. 
2 -Ami no -1 -phenol -4 -sulfonamide. 
2-Amino-l-phenol— i-sulfonic acid. 
Phenoxyanlllne. 
l-{m-Aminophenyl)-5-oxo-2-pyrazoline-3-carboxylle 

acid. 
l-(m-Aminophenyl ) -5-oxo-2-pyTazoline-3-oarboxylio 

acid, 
6-p-Toluidinometanillc acid, 
3-Ainlno-2,7-naphthalenedisulfonlc acid. 
4, -Amino-5' -iiiethyl-p-t&luenesulfon-o-aniei'lide, 
3-Methyl-N-(p-toluenesulfonyl)-t>-phenetidine, 
4-Amlno-m-toluenesulfonlc acid, 
16-Aminovlolanthrone, 
4-Amino-m-benzenedisulfonic acid. 
2-Amlno-p-benzenedisulfonlc acid. 
Aniline salt. 
Aniline. 
Metanilic add. 
Sulfanilic acid. 

Anlllnomethanesulfonic acid, sodium salt. 
5-Amlno-2-anllinobenzeneaulfonio acid. 
o-Anisidlnomenthanesulfonic acid. 
l-Acetyl-3-( 4-aiiiino-p-anlBy 1 ) urea . 
3-Amiiio-N-butyl-p-anisolesulf onamlde . 
o-Anisidinomethanssulfonic acid. 
Leuco quinlzarln. 

Anthr[l,9]lsothlazole-2-carbonyl chloride. 
Naphth[l,2]oxadlazole-5-3ulfonic acid, 
7Cand 8)-rNitronaphth[l,2]oxadiazole-5-sulfonlc acid. 
3-Carboxy-2(and 4)-hydroxybenzenediazonium sulfate. 
p-(p-Aminophenylazo )phenol, 
m,m' -Azoxydlanillne, 
m,m' -Azoxydlanillne, 

a,a-Dlchlorotoluene, 
4-Formyl-ffl-benzenedlsulfonic acid, 
o-Formylbenzenesulfonic acid, 
4,5' -Dlbenzamido -1 , 1' -iminod ianthraqulnone, 

7-Benz[ de] anthracen-7-one, 

3 , 9-Bl s [ 1 -anthraquinony lamino ] -7 -benz [ de ] anthracen- 
7 -one. 



SYNTHETIC ORGANIC CHEMICALS, 1954 



175 



Cyclic intermcdiatcM: CioMaary of aynonymoua names — Continued 



Common name 



Standard (Chemical Abstracts) name 



Benzeneazobenzene 

8enzene-l,3-dicarboxyllc acid 

p-Benzenedlcarboxyllc acid 

1,3, 5 -Benzene triol 

2,2 'benzidine disulfonlc acid 

Benzidine sulfonic acid 

Benzooaine _______ 

Benzotrlohlorlde 

Benzoy lacetanl 11 de 

l-Benzoylamlno-4-amlnoanthraquinone 

2 -Benzoy lamlno -1 , <! -d le thoxybenzene — 

2 -Benzoy lamlno-1 , 4-d ime thoxybenzene 

5-Benzoylamino-2-nltrodl]nethoxybenzene 

5-Benzoylamlno-2-nltrohydroquinone diethyl ester — 
6-Benzoylamlno-3-(p-tolueneBulfonamldo)-i-methoxy- 
toluene. 

2-Benzoyl-4-chloro-3-nltrobenzolo acid 

Benzoyl J acid ' — 



2-Benzoylthiophene 

a-Benzylacetamlde 

m-Benzyl-p-amlnophenol hydrochloride 

Benzyl chloride 

Beniyl cyanide 

N-6enzy 1 -N-ethy lanl 1 Ine - 



N-Benzyl-N-ethyl-p-nltrosoanlllne 

3-Benzyl-7 -hydroxy -4 -me thy looumarln- 

Benzylldlneacetophenone 

Blbenzoyl 

o-Biphenylamlne- 
'i-Blphenylamlne- 



p . p '-Bis ( acetoacetanlllde ) 

N,N'-Bls(aoetoacetyl)benzldlne __— 

N,N-Bis(2-hydroxyethyl)anlllne 

N,N-Bls(2-hydroxyethyl-m-toluldlne) 

>«,'»'^ls[2-(N-methyl-o-anlsyldlazoamlno)ethanesul- 
fonlc acid], 

N,N'-Bls-6-Cl-naphthol-3-sulfonlc acld)urea 

B.O.N. 

Broenner ' s acid 

Bromamlne acid ___ 

p-Bromoacetamldoanthraquinone 

Bromobenzanthrone 

p^romomethylamlnoanthraqulnone 

"i-Bromo-N-Biethyl-ljg-anthrapyrldone 



n-Butyl-p-nltrobenzoate- 



p-Carboxybenzenesulfonamlde 

3-Carboxy-4-hydroxyacetanillde 

Cassella acid 

Centrallte 

Chicago acid 

Chlorinated cresols 

2-Chloro-3-acetamino-9,10-anthrahydroqulnone disul- 
fonlc acid ester, 

2-Chloro-3-acetamlnoanthraqulnone 

2 -Chloro -3 -ac etajnino-9 . 10-d ihydroxyanthracene -9 , 10- 
dlsulfonic acid ester. 

Chloroacetylarsanlllc acid 

5-Chloro-2-amlnoanisole 

'i-Chloro-2-amlno-6-benzenesulfonlc acid 

6-Chloro-3-amlnobenzotrifluorlde 

Chloroamlnophenol 

2-Chloro-i-aminotoluene 

5 -Chloro-2 -amino toluene 

m-Chloroanlllne-o-sulfonlc acid 

p-Chloroanillne-m-sulfonlo acid 

p-Chloroanlllne-o-sulfonic acid 

5-Chloroanlsidlne 

2-Chloro-3-anthracenecarboxylic acid 

2 -Chloroanthr aquinone -3-carboxyllc ac id 

2 -Chlorobenzaldehyde -5 -sulfonic acid 

'l-Chlorobenzaldehyde-2 -sulfonic acid — 

1 -Chloro -5 -benzamldeanthraquinone 

Chlorobenzanthrone 

4-Chlorobenzotrlfluoride 

Chlorobenzyl cyanide — — 

l-Chloro-2-carboxyanthraquinone 

p -Chloro -m-cresol 

2-Chloro-l,4-dlhydroxyanthraqulnone 

Chloro H acid 

5-Chloro-8-hydroxyquinoline 

3-Chloro-3 -methoxy-6-diphenylaminecarboxyllc acid, 
potassium salt. 



Azobenzene. 

Isophthalic acid. 

Terephthallc acid. 

Phloroglucinol. 

4,4' -Dlamlno-2,2 '-blphenyldisulfonic acid. 

2-Amino-5-(p-amlnophenyl)benzene3ulfonlc acid, 

p-Aminobenzoic acid, ethyl estsr. 

OiO. M -Trlchloro toluene. 

01 -Benzoy lace tanillde. 

l-Amino-4-benzamidoanthraqulnone, 

2 ',5 '-Diethoxybenzanillde, 

2 ', 5 '-Dimethoxybenzanillde, 

2',5'-Dimetho)cy^'-nitrobenzanillde, 

2 ', 5 '-Dlethoxy-4 '-nltrobenzanillde, 

6-Benzamido-4-methoxy-3-(p-toluenesulfonamido) tolu- 
ene. 

o-(4_Chloro-3-nitrobenzoyl)benzolo acid. 

6^enzamido-l-naphthol-3-sulfonic acid. 

Phenyl 2-thienyl ketone. 

Hydroc innamami de . 

4-ABino— o-phenyl-a-cresol hydrochloride. 

A -Chloro toluene . 

Phenylacetonltrlle. 

N-Ethyl-N-phenylbenzylamine. 

N-Ethyl-N-(p-nitrosophenyl)benzylamine. 

3-Benzyl-4-methylumbelliferone. 

Chaloone. 

Benzil. 

2-Blphenylamine. 

Xenylamine. 

4,4'-Biacetoacetanillde. 

4,4'-Biacetoacetanilide. 

2,2'-(Phenylimlno)diethanol. 

2,2'-(ra-Tolyllmlno)diethanol. 

3,3' -Dime thoxy -4,4' -biphenylbisl3-methyl-3-triazene- 
ethanesulfonlc acidjp,^ 

6,6'-Ureylenebls(l-naphthol-3-sulfonlc acid] . 

3 -Hydroxy -2 -naphthoic acid. 

6-Amlno-2-naphthalenesulfonlc acid. 

l-Amino-4-bromo-2-anthraquinonesulfonlc acid. 

1 -Acetamido -4-bromoanthraqulnone . 

3-Bromo-7-benz [de] anthracen-7-one. 

4-Bromo-l-methylBminoanthraquinone. 

6-Bromo-3-methyl-7-dibenz If ,1 j] l8oqulnollne-2,7(3)- 
dione, 

p-Nltrobenzoie acid, n-butyl ester. 

p-Sulfamylbenzoic acid. 

5-Acetamidosalicylic acid. 

3-Amlno-l,5-naphthalenedisulfonic acid. 

N,N '-Diethyloarbanillde. 

8-Amlno-l-naphthol-5,7-dlsulfonic acid, 

Cresols, chlorinated. 

2-Aoetamido-3-chloro-9, lO-dihydro-9, lO-anthradlol- 

9,10-dlsulfonic acid, diethyl ester. 
2-Acetamldo-3-chloroanthraqulnone. 
2-Acetamido-3-chloro-9,10-dihydro-9,10-anthradlol- 

9,10-dlsulfonlc acid, diethyl ester. 
Chloroarsacetin. 
4-Chloro-o-anisidlne. 
5-Chlorometanllic acid. 
6-Chloro-a-trifluoro-m-toluidine. 
2-Amino-4_chlorophenol. 
3-Chloro-p-toluldlne. 
4-Chloro-o-toluidlne. 
2-Amino-6-chlorobenzenesulfonlc acid, 
6-Chlorometanllic acid. 
2-Amino-5-chlorobenzenesulfonlo acid, 
4-Chloro-o-anlsidine, 
3-Chloro-2-anthracenecarboxylic acid. 
3-Chloro-2-anthraqulnonecarboxylic acid. 
4-Chloro-3-formylbenzenesulfonlc acid. 
5-Chloro-2-formylbenzene3ulfonic acid. 
l-Benzamido-5-chloroanthraqulnone. 
Chloro-7-benz[ de]anthracen-7-one, 
4-Chloro-a,a,a-trlfluoro toluene. 
(p-Chlorophenyljacetonitrllc. 
l-Chloro-2-anthraqulnoneo -rboxylic acid. 
6-Chloro-m-ore3ol. 
2-Chloroqulnlzarln. 

8-Chloro-l-naphthol-3,6-dlsulfonlc acid. 
5-Chloro-8-qulnolinol. 
N-(m-Anisyl)-4-chloroanthranlllc acid, potassium 

salt. 



176 



UNITED STATES TARIFF COMMISSION 



Cyclic intermediates: Glossary of ftynooymous natpes — Continued 



Common name 



Standard (Chemical Atetracts) name 



3-Chloro-4'-iiiethoxy-6-diphenylamlneoarboxylic acid, 

potassium salt. 
(4-Chloro-2-methoxy-N-Biethylphenyldlazoamino)acetio 

acid. 

Chlorome thylanthraquinone 

f5-Chloro-N-methyl-o-tolyldlazoamino)acetlc acid 

o-Chloro-p-nitroanlllne 

p-Cliloro-o-nitroanlline 

4-Chloro-3-nltroben20trifluoride 

2-Chlorophenol — 

"4-Chlorcphenol 



N-(p-Anlsyl)-4-chloroanthranlllc acid, potassium 

salt. 
l-(4-Chloro-o-anlsyl)-3-methyl-3-triazeneacetic acid. 

l-Chloro-2-methylanthraquinone. 

l-(5-Chloro-o-tolyl)-3-methyl-3-triazeneaeetlc acid. 
2 -Chloro-4-nltroanl 1 Ine , 
'i-Chloro-2-nitroanlllne. 
<t-Chloro-a,a,a-trlfluoro-3-nltro toluene, 
o -Chlor-iphenol. 
:h,' -.r-p'-.'inol. 



2-(m-Chloroprienyldlazoamino)^-sulfobenzoic acid J 2-Li.-!ji-<;hioropiienyl)triazenoJ-4-sulfobenzoic acid, 



Clilorophenylhydrazine-p-sulfoni 

a-Chloro-o-phenyl phenol 

l-(2-Chloro-4-sulfophenyl)-3-methyl-5-pyrazolone 

o-Chloro-p-tolaene sodium sulfonate 

4.-Chlorotoluene-2 -sulfonic acid 

m-Chlorotoluenethioglycolic acid 

5-Chloro-2-toluidine 

o-Chloro-m-toluidine-p-sulfonic acid 

2-Chloro-p-toluldine-5-sulfonic acid 

2-Chloro-5-toluidine^-sulfonlc acid 

Chlorotolylthioglycollc acid 

Chloro-sym-xylenol 

Chloroxylldenesulfonlc acid 

Chromo tropic acid 

1 , 6-Cleve ' s acid 

1, 7-Cleve ' s acid 

Cleve's acid, mixed 

Cresidine 

m-Cresol methyl ether- 

Cresols, mixed 

m-Cresolsulfonic acid — 

o-Cresotic acid 

o-Cresotinic acid 

m-Cresyl methyl ether — 

psl-Cumidine 

Cumlnaldehyde 

2 -Cyanopyr id ine 

3-Cyanopyridine 

^-Cyanopyridine 



Dahl ' s acid 

Dehydrothio-p-toluldine 

Developer Z 

3,6-Diaminoacridine 

m-Diaminoanisole 

3^3'-Diamlnoazoxybenzene 

•4,4' -Diamino-1 , 1 ' -dianthraquinony lamine 

'V,4'-Diamino-l,l'-dianthriiiiide 

Diamino -4 , 4 ' -dltenzoy 1 -1 , 1 ' -d lanthraquinoneimine — 
Diejiiino-4,5-dibenzoyl-l,l '-dianthraquinony lamine — 

l,4-Dlamino-2,3-dihydroanthraquinone 

3,6-Dlamino-2,7-dlmethylacridine hydrochloride 

4,4 '-Diamino-3, 3 '-dlmethyl-5, 5 '-bisbenzenesulf onic 
acid. 

4,4'-Diamino-2,2'-dimethyldiphenylmethane 

p,p"'-Diaminodiphenyljnethane 

p,p'-Diaminodiphenylsulfide 

3 , 3 '-Diamlnod iphenyl urea 

Di(p-aminophenyl) sulfide 

1 , 3 -Dl (m-aminopheny 1 ) urea - 



2,6-Diaminotoluene-4-sulfonic acid 

Dlamylphenol 

l,5-0ianilinoanthraquinone-o,o'-dicarboxylic acid — 

o-Dianisldine 

Dl ( o-anlsyldiazo )methy lenebls ( iminoacetic acid ) 

Di(o-anl8yldiazo)methylenebis(imlnopropionic acid)- 



a.^Dianisylglycol 

1,1' -Dianthraquinoneimine • 

1,1' -Dianthraquinonylamlne 

Dlazoaminobenzene 

l-Diazo-2-naphthol-4-sulfonic acid 

Dibenzanthrone— 

2,2 -Dibenzanthrony 1 

13 , 13 -Dlbenzanthronyl 

Dibenzoyl 

4,5 -Dibenzoylamidodianthraquinony lamine - 
4,4'-Dibenzoyldiamino-l,l'-dianthrimlde- 
Dlbenzyl 



4-'3liloro--3-liydrazincbenzenesulfonic acid. 

2-Chloro-6-phenylphenol. 

l-(6-Ch"Jcro--'-sv.iroplienyl)-3-methyl-5-pyrazolone. 

3-CMoro~p-toluenesuU'onic acid, sodium salt. 

S-Chloro-o-tolutnesulfonic acid. 

4-Chloro-o-tGljlmerceptcacetic acid. 

5-ChlorD-o-toluidlne. 

2-Amino-5-chloro-p-toluenesulfORlc acid. 

6-Amino-4-ch:i-.ro-oi-toluenesulfonlc acid. 

2-Amino-5-chloro-p-toiaene3ulfonio acid. 

4-Ctl .-o-T'-tolylDjercaptoscetic acid. 

4-Chloro-3, 5-xylenol. 

6-tailno-3-chloro-2,5-xylenesulfonlc acid. 

4,5-Dihydrox;'-2,7-naphthalenedisulfonic acid. 

5-Amlno-2-naphthalenesulfonic acid. 

8-Amino-2-naphthalenesull"onic acid. 

5{and 8)-Amino-2-naphtiialenesulfonic acid. 

5-Hethyl-o-anisidine, 

m-Methylanisole. 

Cresylic acid. 

S-l^droxy-m-toluenesulfonlc acid. 

2,3-Cresotic acid. 

2,3-Cresotic acid. 

m-Methylanisole. 

Pseudociimidine. 

Cumaidehyde. 

Plcolinonitrile. 

Niootinonitrile. 

Isonicotinonltrlle. 



6-Amino-l-naphthalenesulfonic acid. 

2-(p-Aminophenyl ) -6-methy Ibenzothiazole. 

a-(p-Anisyl)-p-methoxyacetophenone. 

3-Methyl-l-phenyl-5 -pyrazolone . 

Proflavine base. 

5-Methoxy-(ii-phenylenedlamlne. 

m,m'-Azoxydianlline, 

1,1 '-lminodi-4-aminoanthraqulnone. 

l,l''-Iminodi-4-aminoanthraquinone. 

l,l'-Imlnobi3[4-benzajnldoanthraquinone]. 

4,5''-Dibenzamido-l,l'-aminodianthraquinone. 

Acetate leuco violet. 

Acridine yellow. 

2.2 '-Dlamino-5,5'-bi-m-toluenesulfonic acid. 

4,4''-MethC)'lenebis(m-toluldlne]. 

p,p '-Methylenedianillne. 

p,p '-Thlodianiline. 

3,3 '-DIaminooarbanilide. 

p,p '-Thlodianiline. 

3,3'-Diamlnocarbanillde. 

3,5-Diamlno-p-toluenesulfonlc acid. 

2,4-Di-tert-amylphenol. 

l,5-Dlanilino-2,6-anthraquinonedicarboxylic acid. 

3,3 '-Dime thoxybenzidine. 

3,3'-Methylenebis[l-o-anlsyl-3-trlazeneacetic acid] . 

3.3 '-Methylenebi3[l-o-anisyl-3-trlazenemethylacetlc 
acid] . 

1 , 2-Dl -p-anlsyl-1 , 2-ethanediol. 

l,l' -Iminodianthraquinone. 

1, l' -Imlnodianthraquinone. 

1, 1 ' -Imlnodianthraquinone. 

1,3-Dlphenyltriazine. 

5-Naphth[l,2]oxadiazosulfonic acid. 

Violanthrone, 

( 4, 4' -Bi -7-benz[de] anthracen) -7, 7 '-dlone. 

(3,3'-Bi-7-benz[de]anthracen)-7,7'-<Jione. 

Benzil. 

.^,5 '-Dibenzamido-1,1 '-amlnodianthraquinone. 

l,l'-Iminobis[4-benzamldoanthraqulnone] . 

Bibenzyl. 



SYNTHETIC ORGANIC CHEMICALS, 1954 

Cyclic interm^iates: Giosasry of synonymous nrtmes— Ovnt inued 



177 



Common name 



Standard (Chemical Abstracts) name 



Dlbenzylanlline 

Dibenzyl disulfide 

Dlbenzyl ether 

Dibenzyl sodium sulfanilate 

Dibromoaminoanthraqulnone 

7,16-Dlbromo-6,15-<Jlhydro-5,9,14,18-anthrazlnetetrone 

p-Dibromodihydroxynaphthalene 

2,6-Dlbromo-l,5-dlhydroxynaphthalenc 

4,5-Dlbromo-l,8-dlhydro](ynaphthalene 

1,4-Dlchloroanillne _________ 

2 , 5 -Di ohloroani 1 ine -4 -sulfonic acid 

Diohloroanisyldiazodl-lmlnodiacetic acid 



Dl(5-chloro-o-anisyldlazo)methylenebls(imlnoacetic 
acid). 

l,5-Dlchloro-4,8-anthraqulnonedlsulfonlc acid 

l,8-Dichloro-4,5-anthraqulnonedisulfonic acid 

2 , 6-Dlchlorobenzalchloride 

0,0' -Dichlorobenz id ine — 

m,m -Dichlorobenzidlne hydrochloride — 

2,4-Dichlorobenzyl chloride 

2,'i-Dichlorobenzylidene chloride 

2,6-Dichlorobenzylidene chloride 



Dl(4-chloro-2-diazotoluol)methylenebis(ljninoacetio 

acid). 
2-(2,5-Dlchloro-N-ethylphenyldiazoamino)-5-sulfoben- 

zoic acid. 

Dichlorohydroxybenzoylbenzoic acid 

2,5-Dichlorophenylhydrazinesulfonlc acid 

l-(2,5-Dichlorophenyl)-5-pyrazolone-3-oarboitylic 



id- 



Di ( 5-chloro-o-tolyldiazo )methylenebis( iminoacetlo 

acid). 
Di( 5-chloro-o-tolyldiazo )me thy lenebls{imlnoproplonic 

acid). 

Dicresyldisulfide 

Dicyc lohexyl 

Diethanolaniline 

Diethanol-m-toluidine 

l,i-Diethoxybenzene 

N-(2,5-Diethoxy-4-nitrophenyl)benzamide 

N-(2,5-Diethoxyphenyl)benzamide 

p-Dlethylaminobenzalaniline-o-sulfonic acid 

Diethylanlline-m-sulfonic acid 

Diformyl-m-tolylenediaiDlne 

1,2-Dihydroacenaphthylene 

1 ,i-Dlhydro-4-oxo-2,6-pyridinedicarboxylic acid 

1,3-Dihydroxyanthraquinone 

l,i-Dihydroxyanthraquinone 

1,5-Dihydroxyanthraquinone 

1,8-Dlhydroxyanthraquinone 

2,6-Dihydroxyanthraquinone 

2,4-Dihydroxybenzoio acid 

2 , 3-Dihydroxy-l , -4 -d i aminoanthraquinone 

Dlhydroxyd ibenzanthrone 

3,'i-Dihydroicy-«^-dimethylamlnoaeetophenone 

5,5'-Dihydroxyd'i-2-naphthylamine-7,T'-disulfonic acid- 

l,5-Dihydroxy-4,8-dinltroanthraquinone 

p,p -Dlhydroxydiphenyldlmethy line thane 

<l,4''-Dihydroxydlphenylsulfone 

5,5'-Dlhydroxy-7,T'-disulfonio-2,2'-dlnaphthylamine — 

Dlhydroxyethylaniline 

Dlhydroxyethyl-3-toluidine 

1,5-Dihydroxynaphthalene 

. 2,3-Dihydroxynaphthalene 

l,8-Dihydroxynaphthalene-3,6-disulfonic acid 

l,8-Dlhydroxynaphthalene-4-sulfonic acid 

2,3-Dihydrojtynaphthalene-6-sulfonic acid 

Dlmethanil-4-sodium sulfonate 

2,3-Dimethoxybenzaldehyde 

3,'4-Dimethoxybenzaldehyde 

o-Dlmetho!cybenzene 

1,2 -Dime thoxybenzene 

4,4 '-Dime thoxybenzoin 

3,4-Dlmethoxybenzyl alcohol 

Dl(methoxy-2-diazo-4-chlorobenzoyl)methylenebis(imino- 

acetic acid). 
Dimethoxydiazodiphenylmethylenebis(imlnoacetic acid)— 
Dime thoxyd lazed ipheny Imethy leneb i s ( Iminopropionlc 

acid). 
2, 2 '-( 3, 3 '-Dimethoxy-N, N '-dimethyl-4,4 '-biphenylbls- 

dlazoamino)diethanesulfonlc acid. 

Di-p-methoxyethylchalcone 

N-(2,5-Dlmethoxy_4-nitrophenyl)benzamlde 



N-Phenyldibenzylamine. 

Benzyl disulfide. 

Benzyl ether. 

N,N-DibenzylsulfanHic acid, sodium salt. 

1 -Amino -2 , 4-d ibromoanthraquinone . 

7, 16-Dibromolndanthrene. 

4,5-Dlbromo-l,8-naphthalenediol. 

2 , 6-Dlbromo-l , 5-naphthalened iol . 

4,5-Dibromo-l,8-naphthalenediol. 

2,5-Dichloroanillne. 

2,5-Diohloro8ulfanllio acid. 

3, 3^-Methylenebis (l-( 5-chloro-o-anlsyl )-3-trlazene- 

acetic acid] , 
3,3 '-Methy lenebia [l-( 5-ohloro-o_anlsyl ) -3-triazene- 

acetio acid]. 
4,8-Dlchloro-l,5-anthraquinonedlsulfonlc acid. 
4,5-Dlchloro-l,8-anthraqulnonedisulfonlc acid, 
ij,?, 2, 6-Tetrachloro toluene. 
3, 3 '-Dichlorobenzidlne. 

2.2 -Dichlorobenzidlne hydrochloride. 
a,2,4-Trichlorotoluene. 

?,?, 2, 4-Tetrachloro toluene, 
f , ({, 2, 6-Tetrachloro toluene. 
3,3'' -Methy lenebis[ l-{4-chloro-o-tolyl )-3-triazene- 

acetic acid]. 
2-ri-(2,5-Diohlorophenyl)-3-ethyl-3-triazene]-5-aul- 

fobenzoic acid. 
o-(3,5-Diohlorosalicyloyl)benzolc acid. 
2,5-Dichlorohydrazinobenzenesulfonlc acid. 
l-(2,5-Diohlorophenyl)-5-oxo-2-pyrazollne-3-carbox- 

ylic acid. 
3 , 3' '-Wethylenebis (l-( 5-chloro-o-tolyl ) -3-triazene- 

acetic acid] . 

3.3 '-Methylenebls[l-(5-chloro-o-tolyl)-3-triazene- 
methylaoetic acid] . 

Cresyl disulfide. 

Bicyclohexyl. 

2, 2^-(Pheny limine )diethanol. 

2,2 '-(m-Tolyllmino)diethanol. 

p-Dlethoxybenzene. 

2 ', 5 -Diethoxy-4'-nitrobenzanilide. 

2 ', 5' -Dlethoxybenzanllide. 

N-(p-Diethylaminobenzylidene)aniline-o-sulfonio acid. 

N,N-Diethylmetanllic acid. 

N, N'-Dlf oniiyltoluene-2, 5-<Jiamine. 

Acenaphthene. 

Chelidamic acid. 

Xanthopurpurin. 

Quinizarln. 

Anthrarufin. 

Chrysazin. 

Anthraflavic acid. 

p-Resorcylic acid. 

1 , 4-Dlaminohystazarin. 

16, 17 -Dihydroxyviolan throne. 

Adrenalone. 

6,6' -Iminobis[l-naphthol-3-sulfonic acid]. 

4, 8-Dinitroanthraruf in, 

p,p -Isopropylidenediphenol. 

p,p -Sulfonyldiphenol, 

6,6 -Iminobis[l-naphthol-3-sulfonic acid], 

2,2^-(Phenylimino)dlethanol. 

2.2 -(m-Tolylimino)diethanol. 
1,5-Naphthalenedlol, 
2,3-Naphthalenediol. 

4,5-Dlhydroxy-2,7-naphthalenedisulfonie acid. 
4,5-Dihydroxy-l-naphthalenesulfonic acid, 
6,7-Dihydroxy-2-naphthalenesulfonlc acid. 
Isopropylideneaminobenzenesulfonic acid, sodium salt, 
o-Veratraldehyde. 

Veratraldehyde . 

Veratrole, 

Veratrole. 

Anisoin. 

Veratryl alcohol. 

3.3'-Methylenebis[l-(5-chloro-o-anisyl)-3-triazene- 

acetic acid] . 
3,3 '-Methylenebis(l-o-anlsyl-3-triazeneacetic acid] . 
3,3'-Methylenebls[l-o-aiilsyl-3-triazenemethylacetic 

acid] . 

3.3 '-Dlmethoxy-4,4 '-blphenylbiE[3-iiiethyl-3-triazene- 
ethanesulfonic acid] . 

oc-Ethyl-4,4'' -dimethoxychalcone. 

2 ,5 -DiJiiethoxy-4 -nltrobenzanlllde . 



178 



UNITED STATES TARIFF COMMISSION 

Cyclic intermediates: Glossary of synonymous names — Cont 



Oommon name 



( 3 , 4-Dlmethoxypheny 1 )aoetlc acid 

N-(2,5-Dlinethoiyphenyl)benzaBilde 

2,4^Dl(p-methoxyphenyl)-3-ethylhexane 

2,4^i(p-inethoxyphenyl)-3-ethylhexene 

3,4-Dl(p-inetho][yphenyl)hexane 

Dlmethylacetanlllde 

Dlmethylamlnoacetylcateohol 

N,N-Dlmethyl-3-«mlnophenol 

Dlmethylanlllne 

Dlmethylbenzene 

2,-1 -Dime thy Ibenzenesu If onanlllde 

2,4— Dimethyl-6-tert-butylacetophenone 

l,3-Dlmethyl-5-tert-butylbenzene 

2,7-Diiiiethyloeroxanol 

Dlmethyldlanthraquinonyl 

2,2'-Dimethyl-l,l-dianthraqulfionylamine 

2,7-Dlmethylfluorane 

Dlmethylhydroreeorclnol 

Dimethyl -a-naphthylamlne 

2,7-Dlmethylquinoline 

Dinaphtho[ 1,2, 3-od, 3' ,2' , 1' -lnj perylene 

Dlnaphtho[l,2,3-cd,3' ,2',l'-lm]perylene-5,10- 
dione, 

l.'i-Dinitrobenzene 

2,4-Dinitrobenzene 

Dinltrochlorobenzene ~ 

Dlnitrochlorobenzenesulfonio acid 

3,5-Dlnitro-4-ohlorobenzoic acid - 

2,5-Dlnltro-i-ohlorophenol 

Dlnltro-o-oyclohexylphenol 

^,^' ^initro-1,1' -dlanthraqulnonylamine 

Dinitrodlbenzanthronyl -— 

Dinltrohydro]cydlphenylamine 

Dinltrotetramethy Id laminod iphenylme thane 

2,4-Dinltrotoluenesulfonlc acid 

1,5-Dloxamldoanthraqulnone 

Dioxy S acid 

Dlphenyl 

2,4-Dlphenylamlne-l-hydroxyanthraqulnone 

2,'i-Diphenylamlne-l-oxyanthraquinone 

Dlphenylcarbazide 

Dlphenylene oxide 

Diphenyl epallon acid 

Dlphenyl ether 

Dlphenyl ketone 

Diphenylmethanol 

Dlphenyl oxide 

Dlphenyl silicon dichloride 

Dipyrazoledianthrone 

1 , 3-Di -p-to luid Ineanthraqulnone 

1,4-Dl-p-toluidineanthTaqulnone — 

1 , 3-Di (p-to lylamino ) anthraquinone 

1,4-Dl-p-tolylamlnoanthraqulnone 



Standard (Chemical Abatracte) name 



N-Ethanol-N-€thyl-4-nitrosoanlline 

2-Ethanolpyridine 

2-Ethoxy aniline 

'l-Ethoxy aniline 

2-Ethoxy-6-sulfonaphthalene 

Ethyl -p-aminobenzoate 

Ethyl-o-amino-p-cresol 

Ethylaniline (mono ) 

N,N-Ethylbenzylanlllne 

EthylbenzylanlllneBulfonio acid 

Ethylbenzyl-m-toluldlne 

Ethylbenzyl-m-toluldlne^-sulfonlc acid 

Ethylenerlycol monophenylether 

Ethyl hydrol 

Ethyl ketone base 

2-(N-Ethyl-2Hiiethoxy-5-nltrophenyldlazoamlno)-5-sul- 

fon. 

5-Ethyl-2-iiiethylpyTidine 

2-(N-Ethyl)-5-nitro-o-ani8yldlazoamlno-5-sulfo- 

benzoic acid, 

p-Ethylnltrobenzene 

Ethyl p -ni trobenzoa te 

Ethyl -p-nltrobenzoylacetate 

Ethyl phenyl ether 

Ethyl sallcyl carbonate 

Ethyl sulfobenzylani line 

N-Ethyl-o-toluIdlne-p-Bulfonlc acid 



Fast red TR base 

p-Formylaniline 



Homoveratrlc acid, 

2',5'-Dlmethoxybenzanllide, 

2 , 'i-Di (p-anisyl ) -3-ethylhexane. 

2,4-Dl(p-anl8yl)-3-ethylhexene. 

3,'4-Di(p-aniByl )heiane, 

Acetoxylidide, 

Adrenalone, 

m-Dlmethylamlnophenol, 

Xylidine. 

}^lene, 

p-Toluenesulfono-o-toluidide, 

6-tert-Butyl-2,',-dimethylacetophenone, 

5-tert -Butyl -m-xylene, 

2 , 8-Dimethyl-13p -hydroxy-9( 13? )-ceroxenone . 

2,2 -Dlaiethyl-l,l'-bianthraquinone. 

1,1' -Iminobls[2-methylanthraqulnone], 

2' ,7' -Dijnethylf luoran, 

Dimethyl-l,3-cyclohexanedione, 

N,N-Dimethyl-l-naphthylamine, 

m -To luquina Id ine , 

Vlolanthrene, 

Violanthrone, 

p-Dinitrobenzene. 

m-Dinitrobenzene, 

l-Chloro-2,4-dlnltrobenzene. 

4 -Chloro-3 , 5 -dlni trobenzenesulf oni c acid, 

4-Chloro-3,5-dlnltrobenzolc acid. 

4-Chloro-2,6-dlnltrophenol. 

2-Cyclohexyl-4,6-dlnltrophenol, 

1,1' -Iminodi-4-nitroanthraquinone, 

Dlnitro(3,3' -bl-7-benz[ del anthracen)-7,7'-dlone. 

p-(2,4-Dinitroanllino)phenol, 

p,p'-Methylenebla[N,N-dimethyl-2-nitroanilin«!l . 

3,5-Dinltro-o-toluenesulfonic acid, 

N,N'-(l,5-Anthraqulnone)dloxamic acid, 

4, 5-Dihydroxy-l-naphthalenesulf onic acid, 

Blphenyl, 

2, 4-Dlanilino-l-hydroxy anthraquinone, 

2,4-Dlanlllno-l-hydroxyanthraquinone, 

1,5-Dlphenyloarbohydrazlde, 

Dibenzofuran, 

8-Dlphenylamino-l,6-naphthalenedlsulfonic acid. 

Phenyl ether, 

Benzophenone, 

Benzhydrol, 

Phenyl ether. 

Dlchlorophenylsilane, 

Pyrazole anthrone yellow. 

l,3-Dl-p-(toluidino) anthraquinone. 

l,4-Di-p-(toluldino)anthraquinone. 

1 ■ 3-Dl-p-( toluidino )anthraqulnone. 

l,4-Di-p-(toluidino)anthraquinone. 

2-(N-Ethyl-4-nltrosoanllino)ethanol. 

2-Pyridlneethanol. 

o-Phenetidine, 

p-Phenetldine. 

6-Ethoxy-2-naphthalenesulfonlo acid. 

p-Aminobenzoic acid, ethyl ester. 

3-Ethylamlno-p-Gregol. 

N-Ethylanlllne, 

N-Ethyl-N-phenylbenzylamine, 

» -(N-Ethylanlllno)-p-toluenesulfonie acid, 

N-Benzyl-N-ethyl-m-toluldine, 

4-(N-Benzyl-N-ethylamino)-o-toluenesull'onic acid. 

2 -Phenoxy e thano 1 , 

4,4' -Bls(diethylamino)ben2hydrol, 

4,4' -Bis(diethylamlno)benzophenone, 

2-[3-Ethyl-l-(5-nltro-o-ani3yl)-3-triazene] -5-sulfo- 

benzoic acid. 
5-Ethyl-2-picoline. 
2-[3-Ethyl-l-(5-nitro-o-anisyl)-3-trlazene] -5-sulfo- 

benzoic acid. 
1-Ethyl -4 -nitrobenzene. 
p-Nitrobenzoic acid, ethyl ester. 
p-Nltrobenzoylacetlc acid, ethyl ester. 
Phenetole. 

o,o'-Carbonyldloxydibenzoic acid, diethyl ester. 
a-(N-Ethylanl lino) -p-to luenesulfonlc acid. 
3-Ethylamino-p-toluenesuironlc acid. 

5-Chloro-o-toluidine. 
p-Aminobenzaldehyde, 



SYNTHETIC ORGANIC CHEMICALS, 1954 

Cyclic intermediates: Gloaaary of aynonyaoua naaea — Continued 



179 



Common najne 



Standard (Chemical Abstracts) name 



p-Fonnyl-N.N-diethylanlllne- 



G acid 

Gamma dlsulfo acid ~ -— — - — 

Glycerolmonoethylanillne 



H acid 

Halocrin 

Hexahydrobenzolo acid — ~ 

Hexahydropyrldlne — — — _. — __ 

Homoveratrylamlne — 

1,2-1,2-Hydrazlnedlbromoanthraqulnone 

Hydrol 

Hydroqulnone dimethyl ether 

o-Hydroxybenzyl benzoate, calcium salt 

7-I^droxycoumarln —- 

4-Hydro][ydiphenyl 

P-t^droxyethyl-o-chloroanlline 

Hydroxyethylethylanlllne 

Hydroxyethylmethylanlllne 

Hydro xyethyl-3-toluldine 

2-I^droxy-3-methoxyben2aldehyde 

2-Hydroxy-3-methylbenzolc acid 

2-}^droxy-4-methylbenzoic acid 

7-ffydroxy— 4-methylcoumarln 

2-I6'dro)(y-5-nltroacetanilide 

p-Hydroxyphenylarsonlc acid 

p-Hydroxyphenyl-n-butylamlne 

8-Hydroxyqulnollne 



I add 

I acid tmlde 

Isobutyl p-nltrobenzoate 

I sod Ibenzanthrone 

p-Isopropylanlllne 

p -Isopropy Ibenzald ehyde 

Isopropylbenzene 

Isopropyl p-toluenesulfonate- 



acld 

acid Imlde 
acid urea- 



Koch's acid- 



Lake red C amine 

Laurent ' s acid 

Lead atyphnate 

Lead trinitroresorclnate 

Leuco-1 , 4-dl (methylamino )anthraquinone- 

Leucolndophenol BCFN 

Llmonene 



Methane base 

Methane salt 

o-Methoxyacetanlllde — — 

p-Methoxyacetanilide ~ 

4-Methoxy-4'-amlnodlphenylamine _— 

2-Methoxy-4-aminodiphenylamlne-2 -sulfonic acid — •- 

Methoxy aniline 

Methoxybenzene 

p-Methoxybenzoic acid 

4-Methoxy-3'-chloro-6 '-carboxydiphenylamlne, potas- 
sium salt. 

2-Methoxy-6,9-dichloroacrldlne 

4' -Me thoxy-4-nltrodlphenylamlne-2' -sulfonic acid 

Me thoxy-cmega -sulfonic acid 

6-Methoxy-m-toluidlne 

'4-Methyl—4-amlnodlphenylamlne-2 -sulfonic acid 

Methylamlnosulfobenzolc acid 

o-Methylanlllne 

Methylaniline(mono) 

2-Me thy Ibenzanthrone 

2'-Wethyl-3-benzldlnesulfonic acid 

Methylenebls [n-p-( 5-chloro-o-anl3ylazophenyl )lmino- 
acetic acid], dlsodlum salt. 

Methylenebis(methylamlnoantipyrlne) 

Methylenebls (toluenedlamine) 

2-Methyl-5-ethylpyridine 

■4-Methyl-7-hydroxycoumarln — — 

Methyl-p-hydroxy-m-nitrobenzoate 

MethylphenylpyTazolone-3-3ulfonlo acid 



p-Dlethylamlnobenzaldehyde. 

2-Naphthol-6,8-<iisulfonlc acid. 
7-Amlno-l-naphthol-3-sulfonlc aald. 
7-Amlno-l-naphthol-3,6-dlsulfonlo acid. 
3-(N-Ethylanilino)-l,2-propanediol. 

8-Amlno-l-naphthol-3,6-disulfonlo acid. 

6,9-Dlchloro-2-methoxyacrldlne. 

Cyclohexanecarboxylio acid. 

Plperldine. 

3,4-Dlinethoxyphenethylamlne. 

7,16-Dlbromolndanthrene. 

p,p' -Bls{dlmethylamlno)benzhydrol. 

p-Dlmethoxybenzene. 

Sallgenin iaenzoate, calcium salt. 

Unbelllferone, 

p-Phenylphenol. 

2-(Chloroanlllno)ethanol. 

2-(N-Ethylanlllno)ethanol. 

2-(N-Methylanlllno)ethanol. 

2-(m-Toluidlno )ethanol. 

o-Vanlllin. 

2,3-Cresotlc acid. 

2,'i-Cresotlo acid. 

4-Methylumbelliferone. 

2-Aoetamldo-4-nitrophenol. 

p-}fydroxybenzenearsonlc acid. 

p-Amlno-N-Cn-butyl) -phenol. 

8-Quinollnol. 

6-Amlno-l-naphthol-3-sulfonlc acid, 

6,6'-Imlnobis[l-naphthol-3-sulfonlc acid] . 

p-Nltrobenzolc acid, Isobutyl ester. 

Isovlolan throne. 

Cumldlne. 

Cumaldehyde. 

Cumene. 

p-Toluenesulfonic acid, isopropyl ester. 

6-Amlno-l-naphthol-3-aulfonic acid. 
6,6'-Iminobls[l-naphthol-3-sulfonic acid]. 
6,6'-Ureylenebis[l-naphthol-3-sulfonlc acid], 

8-Amino-l-naphthol-3,5-disTilfonic acid. 
8-Amlno-l,3,6-naphthalenetrisulfonlo acid. 

2-Amlno-5-chloro-p-toluenesulfonlc acid. 

5-Amlno-l-naphthalenesulfonic acid. 

Styphnic acid, lead salt. 

Styphnlc acid, lead salt. 

l.-i-Dlmethylamino-g.lO-anthradlol. 

<i-(p-Dlmethylamlnoanillno)-l-naphthol. 

Dlpentene. 

p,p'-Methylenebls(N,N-dlethylanlllne], 

'i,4'-Methylenebls[3-hydroxy-2-naphthoic acid]. 

o-Aoetanisldlde. 

p-Acetanisidlde. 

N-(p-Anisyl)-p-phenylenedlamine. 

o-(4-Amlno-2-anlsldlno)benzenesulfonic acid. 

Anlsidine. 

Anlsole. 

Anisic acid, 

N-(p-Anlsyl)-4-chloroanthranllic acid, potassium 

salt. 
6,9-Dlchloro-2-methoxyacrldine. 
2-p-Anlsidino-5-nitrobenzenesuLfonlc acid. 
o-Anlsldinomethanesulfonio acid. 
5-Methyl-o-anisidine[NH2=l] . 
6-p-Toluidlnometanlllc acid. 
N-Methyl-5-sulfoanthranllle acid. 
o-Toluidlne. 
N-Methylaniline. 

2-Methyl-7-benz[de]aiithracen-7-one. 
5-Amino-2-(4-amlno-m-toluidino)benzeneaulfonlc acid, 
N,N'-Methylenebis[N-p-(5-chloro-o-anisylazo)phenyl- 

glycine], dlsodlum salt. 
N,N '-Methylenebls [<4 -me thylamlnoantipyrine]. 
5,5'-Methylenebls[toluene-2,'4-dlamine] . 
5-Ethyl-2-plooline. 
4-Methylumbelllferone. 

p-Hydroxy-m-nitrobenzoic acid, methyl ester, 
3-Methyl-l-(m-sulfophenyl)-5-pyrazolone. 



180 



UNITED STATES TARIFF COMMISSION 



Cycli 



intermediates : Giosaary of synonymous 



Common nane 



Standard (Chemical Abstracts) name 



Methylphenylpyrazolone-i-sulfonlc acid 

2-Methylpiperldine 

Methylpyrldlne 

2-Methylquinol Ine 

Methyl-p-toluenesulfonate ~ 

P-Methylumbelllferone 

Mlohler ' s hydrol 

Mlohler ' s ketone 

Mixed oresols, refined -_— 

Monobromobenzene 

Monochlorobenzene 



Naphthalene sodium sulfonates 

Naphthalene-p-thloglycollc acid — 

o-Naphthionic acid 

a-Naphthol 

l-Naphthol-8-chloro-3,6-disuironic acid 

2-Naphthol ethyl ether 

2-Naphtholthloindoxyl 

Naphthosulfochloride 

Naphthylacetonltrile 

a-Naphthylamine 

P-Naphthylamlne 

1 -Naphthy lamlne -3 , 6-d I sulfonic ac id 

1 -Naphthy lamine -3 , 8-di sulfonic ac Id 

l-Naphthylamine-^,7-di3ulfonic acid 

l-Naphthylamine-4,8-disulfonic acid 

2 -Naphthy lamine -1 , 5 -d isulf onio ac id 

2 -Naphthy lamine -3 , 6 -disulf onic ac id 

2-Naphthylamine-4,8-disulfonic acid 

2-Naphthylamine-5,7-disulfonic acid 

2 -Naphthy lamine-6,8-dlsulf onic acid — 

l-Naphthylamlne-2 -sulfonic acid 

l-Naphthylamine-3-sulfonic acid 

1-Naphthy lamine -4-sulf onic acid — 

l-N»phthylamlne-5-6ulfonlc acid 

1 -Naphthy lamine -6-sulf onic acid 

l-Naphthylamine-6(and 7)-sulfonic acid 

l-Naphthylaiiilne-7 -sulfonic acid 

l-Naphthylamine-8-sulfonic acid 

2 -Naphthy lamine -1 -sulfonic acid 

2-Naphthylamine-5-sulfonic acid — 

2-Naphthylamine-6-sulfonic acid 

2-Naphthylamine-8-8ulfonlc acid 

1 -Naphthy lamine-3, 6. S-trisulf onic acid 

2-Naphthylamine-3, 6 , 8-trisulf onic ac id 

l-Naphthylamino-2-carboxylic acid anthraquinone 

a -Naphthy 1 1 socyanate 

Naphthy Imethane sulfonic acid 

p -Naphthylthioglyoolio acid 

Nevile and Winther's acid —- — — 

3-Nitro-4-aminoanisole 

'l-Nitro-2-amlnoanisole — • — 

5-Nitro-2-amlnoanisole 

6-Nltro-2-«mlnoanl8ole — 

o-Nitro-p-aminophenol _____ 

p-Nltro-o-«minophenol 

5-Nitro-o-aminophenol 

'i-Nitro-2-aminophenol-6-aulfonic acid 

6-Nitro-2-aminophenol-^-8ulfonio acid 

"i-Nltro-^' -amino -2 -su If odipheny lamine-—-- 

5-Nitro-2 -amino toluene — 

p-Nltroaniline-o-8ulfonic acid 

m-Nitro -p-ani sid ine — — 

3-Nitro-p-ani3ldine — 

'i-Nltro-2-ani8idlne 

5-Nitro-2-anisidine 

2-Nitroanl80le-4-sulfodiethylamide 

9-Nitroanthra{l, 9,-4, 10 )bis( 1,2,3 )oxathlazlne-2,7-bi8- 
dioxide. 

mitroanthraquinone-2-carboxylic acid 

Nitrobenzene-2,5-disulfonlc acid 

l-Nltrobenzene-4-sulfonic acid -_— — 

2-Nitrobenzenesulfonic acid — 

3-NitrobenzeneBulfonic acid — 

3-Nitrobenzenesulfonyl chloride _____ 

m-Nitrobenzoyl J acid 

p-Nltrobenzoyl J acid ■ — 



m-Ni trochlorobenzene 

o-Nitrochlorobenzene 

p-Ni trochlorobenzene 

2-Nitro-l-ohlorobenzene-4-sulfobutylamide 



3-Me thy l-l-(i.-suKophenyl)-5-pyrazo lone. 

2-Pipecoline, 

Picoline. 

(Jiinaldlne. 

p-Toluenesulfonic acid, methyl ester. 

•i-Methylumbelliferone. 

^,A' -BisTdimethylamino] benzhydrol. 

A,i' -Bls[dimethylaii;ino]benzophenone. 

Cresyllc acid, refined. 

Bromobenzene . 

Chlorobenzene ( mono ) . 

Naphthalenesulfonic acids, sodium salt (mixed). 

2-Naphthylmercaptoacetlc acid. 

l-Amlno-2-naphthalenesulfonic acid. 

1-Naphthol. 

2-Naphthol. 

8-Chloro-l-naphthol-3,6-disulfonic acid. 

2-Ethoxynaphthalene, 

g-( 2-Hydroxynaphthyl ) _3-thianaphthenDl. 

1-Naphthalenesulfonyl chloride. 

Naphthaleneacetonitrile. 

1 -Naphthy 1 amine . 

2-Naphthy lamine. 

5-Amino-2,7-naphthalenedl3ulfonic acid. 

8-Anino-l,6-naphthalenedisulfonlc acid. 

4— Amlno-l,6-naphthalenedisulfonic acid. 

'i-Amino-l,5-naphthalenedisulfonic acid. 

2-Amino-l,5-naphthalenedisulfonic acid. 

3-Amino-2,7-naphthalenedisulfonio acid. 

3-Amino-l,5-naphthalenedisulfonic acid, 

6-Aiiino-l,3-naphthalenedisulfonic acid. 

7-Amino-l,3-naphthalenedisulfonic acid. 

l-Amino-2-naphthalenesulfonic acid. 

4-Amino-2-naphthalenesulfonic aeid. 

Naphthionic acid. 

5-Amino-l-naphthalenesulfonic acid. 

5-Amino-2 -naphthalenesulfonic acid. 

5(and 8 )-Amino-2 -naphthalenesulfonic acid. 

8-Amino-2 -naphthalenesulfonic acid. 

8-Amino-l -naphthalenesulfonic acid. 

2-Amino-l -naphthalenesulfonic acid. 

6-Amino-l -naphthalenesulfonic acid. 

6-Amino-2 -naphthalenesulfonic acid. 

7-Amino-l -naphthalenesulfonic acid, 

8-Amino-l, 3, 6-naphthalenetrisulfonic acid. 

7-Amino-l, 3, 6-naphthalenetrlsulf onic acid. 

l-( 1-Naphthylamino ) -2-anthraquinonecarboxylic acid. 

1-Naphthyl isocyanate. 

Naphthalenemethanesulfonic acid. 

2-Naphthyliiiercaptoacetio acid. 

1-Naphthol-^-sulfonic acid, 

2-Nitro-p-anisidine. 

5-Nitro-o-anIaldine, 

4-Nitro-o-anlsidine. 

3-Nitro-o-anl8idine. 

'i-Amino-2-nitrophenol. 

2 -Amino -i -ni trophenol . 

2-Amino-5-nitrophenol. 

2-Amino-i-nitro-l-phenol-6-eulfonic acid. 

2-Amino-6-nitro-l-phenol-4-8ulfonlc acid. 

2-(p-Amlnoanilino)-5-nitrobenzenesulfonio acid. 

<i-Nitro-o-toluidine. 

2-Amino-5-nitrobenzenesulfonlc acid. 

2-Nitro-p-anisidine. 

2-Nitro-p-ani8idlne. 

5-Nitro-o-anisidine. 

<;-Nitro-o-anisidine. 

N,N-Dlethyl-3-nitro-p-anlBoleBulfomailde. 

9-Nitroanthra[l,9-de,'4,10-d^e'l bis[l,2,3]oxathiazine- 

2,7-bi3dioxlde. 
l-Nltro-2-anthraqulnonecarboxyllc acid. 
2-Nitro-p-benzenedisulfonic acid. 
p-Nitrobenzenesulfonic acid. 
o-Nitrobenzenesulfonic acid, 
m-Nitrobenzenesulfonic acid. 
m-Nitrobenzenesulfonyl chloride. 
6-(m-Nitrobenzamido)-l-naphthol-3-aulfonic acid. 
6-(p-Nitrobenzamido)-l-naphthol-3-sulfonlc acid, 
1 -Chloro -3 -ni trobenzene. 
1 -Chloro -2 -nl trobenzene . 
1 -Chloro -4-nl trobenzene . 
N-Butyl-4-chloro-3-nitrobenzenesulfonamide, 



SYNTHETIC ORGANIC CHEMICALS, 1954 

Cyclic intermediates: Glossary of synonymous names — Continued 



181 



Common name 



Standard (Chemical Abstracts) name 



2-Nltro-fl.-chlorobenzene-*-^ulfodlethylamlde 

o-Nltrochlorobenzene-p-sulfonlc acid 

p-Nltrochlorobenzene-o-sulfonlc acid 

3-Nltro-4-chlorobenzoylben201c acid 

'i-Nltro-6-chloro-l,3-dlmethoxybenzene 

2-Nltro-4-chlorophenol 

2-Nltro— 4-chlorophenol-6-suLfonlc acid 

m-Nltro-p-chloro toluene 

o-Nltro-p-chlorotoluene 

p-Nltro-o-chloro toluene 

2-Nitro-4-chlorotoluene 

m-Nltro-p-cresol 

Nltrocresyl methyl ether 

Nltro-p-dlchlorobenzene 

o -Nl trod Ipheny 1 - 
p-Nltrodlphenyl- 



4-Nltro-2-dlphenylamine-sulfonic acid 

4-Nltrodlphenylamlno-2-eulfonic acid 

2-Nltrohydroqulnone, diethyl ether 

2-NltrohydroqulnQne, dimethyl ether 

3-Nitro-4-hydroxy-l-phenylarsonic acid 

6-Nitro-4-methoxy-3-amlnotoluene- 



2-Nitro-4-methoxy-5-(p-toluenesulfonamldo)toluene- 
4-Nltro-l-niethylanlllne 

l-Nitro-2-niethylanthraqulnone 

2-Nitronaphthalene-4,8-dlsulfonIc acid 

7-Nitro-l,5-naphthalenedisulfonic acid 

4-Nltronaphthallc acid tolylimide 

3-Nltrophenylhydrazine 

l-(m-Nltrophenyl )-5-pyrazolone-3-carboxyllc acid — 

Nltropyrazolonecarboxylic acid 



p-NltroEOdiethylanillne 

p-Nltrosodlmethylanlllne 

Nitroao-^naphthol 

3-Nltro-5-stearoylaiiilno-p-toluenesulfonic acid 

<l-Nitrotolueneanlllde 

6-Nltro-3-{p-toluenesulfone)amino-4-niethoxytoluene- 

A^-Nltro-p-toluenesulfone-o-toluide 

o-NltrotoluenesuLfonlc acid 

p-Nltrotoluene-o-sulfonic acid 

m-Nltro-o-toluidlne 

m-Nltro-p-toluldine 

p-Nitro-o-toluld ine — — 



3-Nltro-4-toluldine 

';-Nitro-2-toluldine 

5 -Nltro-2-toluld ine ■ 

Nitrotoluidlne sulfone 

6-Nitro-o-toluldlne-4-sulfonlc acid 

5-Nltro-l,2,4-trlchlorobenzene 

Nltroviolanthrene — - — - — — 

p-Nltro-o-xylene 

i-Nltro-l , 3-xylene — 

2-Nitro-l,'i-xylol 

-i-Nltro-l . 3-xylol 



Orthanillc acid 

Oxalyl-p-nitro aniline 

Oxalyl-m-phenylenedlamine 

Oxalyl-p-phenylenedlamine 

0xo-l,4-pyran-2,6-dicarboxyllc acld- 

2'Oxycarbazole 

a-Oxynaphtholc acid 

P -Oxynaphtholc acid 



Pentaanthr amide- 



Peri acid 

Phenethylmalonlc acid, diethyl ether 

1-Phenylacetylcarbinol 

P-Phenylacrylophenone 

2-Phenylamine-5-naphthol-7 -sulfonic add . 

2-Phenylamine-8-naphthol-6-sulfonic acid 

N-Phenylaniline 

Phenylarsonic acid 

Pheny lb ipheny 1 

Phenyl bromide 

l-Phenyl-3-carboxy-5-pyrazolone-4-sulfonlc acld- 



Phenyldlethanolamlne 

m-Phenylenediamlnedisulfonic acld- 

m-PhenylenediajninesuIfonlc acid 

p-Phenylenediaminesulfonlc acid 



4-Chloro-N,N-dlethyl-3-nltrobenzene3ulfonamlde. 

4-Chloro-3-nitrobenzenesulfonic acid, 

2-Chloro-5-nltrobenzenesulfonlc acid. 

o-('l-Chloro-3-nitrobenzoyl)benzolc acid. 

6-Chloro-l,3-dimethoiy--*-nltrobenzene. 

"i-Chloro -2 -nl trophenol , 

'4-Chloro-2-nltro-l-phenol-6-auironlc acid> 

'i-Chloro-3-nitro toluene, 

"i-Chloro -2 -nitro toluene, 

2-Chloro -4 -nitro toluene, 

'i-Chloro-2-nltro toluene, 

2-Nltro-p-cresol, 

4-Methyl-o-nltroanlsole, 

1,4-Dlchloro -2 -nitrobenzene. 

2-Nitrobiphenyl. 

■t-Nltrobiphenyl. 

2-Anllino-5-nitrobenzeneBulfonle acid. 

2-Anilino-5-nltrobenzenesulfonlc acid, 

l,<i-Dlethoxy-2^iltrobenzene, 

1,4-Dlmethoxy -2 -nitrobenzene. 

'4-Hydroxy-3-nitro-l-benzenear8onic acid. 

4-Methyl-5-nitro-o-anlaidlne, 

N-( 5-Methyl— 4-nltro-o-anisyl ) -p-toluenesulfonamlde, 

5-Nitro-o-ioluidlne. 

2-Methyl-l-nitroanthraquinone. 

3-Nltro-l,5-naphthalenedisulfonlc acid. 

3-Nitro-l,5-naphthalenedisulfonic acid. 

■i-Nltro-N-tolylnaphthalimlde. 

m-Nltrophenylhydrazine, 

l-(m-Nltrophenyl)-5-oxo-2-pyrazoline-3-carboxylic 

acid. 
l-(m-Nltrophenyl)-5-oxo-2-pyTazollne-3-carboxyllc 

acid. 
N,N-Dlethyl-p-nitrosoaniline. 
N,N-Dlmethyl-p-nitrosoanlllne. 
l-Nitroso-2-naphthol. 

3-Nitro-5-stearoylamldo-p-toiuenesulfonic acid, 
2-Methy 1 -5 -ni trod ipheny lamlne , 

N-(5-Methyl-4-nitro-o-anisyl)-p-toluenesulfonamide, 
N-(<i-Nitro-o-tolyl)-p-toluenesulfonamide, 
3-Nitro-p-toluenesulfonic acid. 
5-Nltro-o-toluenesulfonlc acid. 
i-Nltro-o-toluidine, 
2-Nltro-p-toluldine, 
5-Nltro-o-toluidine, 
2-Nitro-p-toluldine, 
5-Nltro-o-toluldine. 
'V-Nltro-o-toluidlne. 
4';;-Nltro-p-toluenesulfono-o-tolulde, 
3-ABino-5-nitro-p-toluenesulfonio acid. 
1 , 2 , <i-Trlchloro-5-nltrobenzene, 
16-Nitroviolanthrone, 
"i-Nltro-o-xylene, 
"i-Nitro-m-xylene, 
2-Nitro-p-xylene, 
"i-Nltro-m-xylene, 

o-Amlnobenzenesulfonic acid. 
N,N'-Dl(p-nltrophenyl)oxamide. 
N, N '-Di (m-amlnophenyl joxamide, 
N,N'-Di(p-amlnophenyl)oxamide, 
Chelldonlc acid. 
2-Hydroxycarbazole, 
l-Hydroxy-2-naphtholc acid, 
3-Itrdroxy-2-naphtholc acid, 

l,';,5,8-Tetrakis[l',l",l'",l""-anthraqulnonyl- 

amino] anthraquinone . 
S-Ajnino-l-naphthalenesulfonlc acid, 
Ethylphenylmalonic acid, diethyl ester, 
1 -ICrdr oxy -1 -phenyl -2 -propanone , 
Chalcone, 

6-Anlllno-l-naphthol-3-sull'onio acid. 
7-Anllino-l-naphthol-3-sulfonlc acid. 
Dlphenylamine, 
Benzenearsonic acid, 
Terphenyl, 
Bromobenzene. 
5-Oxo-l-(p-sulfophenyl)-2-pyTazollne-3-oarboxyllc 

acid, 
2,2'-(Phenylimino)diethanol, 
'i,6-Diamino-iii-benzenedisulfonic acid, 
2,4-Diaininobenzenesulfonic acid, 
2.5-Diaminobenzenesulfonic acid. 



182 



UNITED STATES TARIFF COMMISSION 

Cyclic intermediates: Glossary of synonymous names- -Cont ini 



Phenylene nerol acid 

Phenylethanolamlne 

Phenylethylmalonlc ester 

Phenyl ganma acid 

Phenylhydrazine-p-sulfonic acid 

Phenylhydrazine-2 -sulfonic acid 

Phenylhydrazlne-3-sulfonio acid 

N-Phenyl-N'-Cp -hydroxyethyl) thiourea 

Phenyl isocyanate 

Phenyl J acid 

Phenylmalonic ester 

Phenylmethanesulfonic acid 

N-Phenyl-l-naphthylamine-8-sulfonlc acid 

a -Phenyl -ji-{A -oxopheny 1 )proplonic acid 

Phenyl peri acid 

N-Pheny 1 -p-pheny lened iaminesulf onio ac id 

l-Phenyl-5-pyrazolone-3-carboxylic acid, ethyl ester 



Standard (Chemical Abstracts) name 



Phenyl silicon chloride 

l-Phenyl-4-sulfo-5-pyrazolone-3-carl)Oxylic acid 



Phthalyl chloride 

Plperidinopropyl alcohol 

Polychlorodiphenyl 

Potassium-3-chloro-6-carboxy-3-niethoxydiphenyli 



n-Propyl p-nitrobenzoate- 

Pyrazolanthrone 

Pyrazolone C 

Pyrazolone T 



6-(p-Amlnoanilino)metanilio acid. 

-j 2-Anilinoethanol, 

Ethylphenylmalonic acid, diethyl ester. 
7-Anillno-l-naphthol-3-sulfonic acid. 
p-Hydrazinobenzenesulfonic acid. 
o-Hydrazinobenzenesulfonic acid. 
m-Hydrazinobenzenesulfonic acid, 
l-( 2-Hydro)tyethyl ) -3-phenyl-2-thiourea. 
Isocyanic acid, phenyl ester, 
6-Anilino-l-naphthol-3-sulfonic acid. 
Phenylmalonic acid, diethyl ester. 
a-Toluenesulfonic acid. 
8-Anillno-l-naphthalenesulfonic acid. 
P-(p-Hydroxyphenyl)-a-phenylproplonic acid. 
8-Anillno-l-naphthalenesulfonic acid. 
5-Amino-2-anilinobenzenesulfonic acid, 
5-Oxo-l-phenyl-2-pyTazoline-3-carboxyllc acid, ethyl 

ester. 
Trichlorophenylsilane. 
5-0xo-l-(p-sulfophenyl)-2-pyrazollne-3-carboxylic 

acid. 
Phthaloyl chloride. 
l-Piperidinepropanol, 
Polychlorobiphenyl. 
2-(m-Anisyl)-4-chloroanthranilic acid, potassium 

salt. 
p-Nitrobenzoic acid, n-propyl ester. 
AnthraLl,9]pyrazol-6(2)-one. 
3-Methyl-l-(p-sulfophenyl) -5 -pyrazolone. 
5-0xo-l-(p-sulf ophenyl ) -2-pyrazolliie-3-carboxylic 

acid. 



Quinophthalone- 



fi acid 

2R acid 

Red KB base 

Rhoduline acid- 



S acid 

2S(SS) acid 

Schaeffer' s acid 

Silver salt 

Sodium carbolate 

Sodium naphthionate 

Sodium phenate 

Sodium -o-phenylphenolate 

Sodium tetrachlorophenolate 

Sodium trlchlorophenolate 

Sulfo BB acid 

o-Sulfobenzaldehyde 

1 -Sulf 0-5 -nl troanthraquinone 

Sulf opheny Ime thy Ipyrazo lone 

1 -( p-Sulf ophenyl ) -5 -pyTazolone-3-carboxylic acid - 



Tetraaminodi to ly Ime thane 

Tetrachloroquinone 

Tetraethyldiaminobenzhydrol 

Tetraethyldiaminobenzophenone 

Tetraethyldlaminodlphenylmethane 

Tetraethyldiaminotriphenylmethane 

Tetramethyldiaminoacridlne hydrochloride 

Tetramethyldiamlnobenzophenone 

Tetramethyldiamlnobenzoylhydrol 

Tetrame thy Id iamlnodipheny Ime thane 

Tetramethyldiaminoaiphenylmethanesulfonic acid and 
salt. 

Tetrame thyldiamlnotriphenylmethane 

Thioaniline 

Thioanllinedlsulfonio acid 

P,p'-Thiobis(<i-amino-o-benzenesulfonic acid) 

Thlosalicylic acid ,. 

Tobias ac id 

Tolazine base 

o-Tolidinedisulfonic acid 

a-Toluamide 

p-Toluenesulfochlorlde 

4-Toluenesulfonamido-l-amlnoanthraquinone sulfonic 
acid. 

'♦-Toluic acid 

a-Toluic acid 

4-Toluidine-2-sulfanilide 

ra-Toluidine-o-sulfonio acid — 



2,2' -(l,3-Indandione)quinollne. 

2-Naphthol-3,6-disulfonic acid. 

7-Amino-l-naphthol-3,6-diaulfonic acid. 

^-Chloro-o-toluidine, 

6,6" -Iminobisf l-naphthol-3-sulfonic acid) . 

8-Amino-l-naphthol-5-sulfonic acid. 
8-Amino-l-naphthol-5,7-disuironic acid. 
2-Naphthol-6-sulfonic acid. 
2-Anthraquinonesulfonic acid, sodium salt. 
Phenol, sodium salt, 
Naphthionlc acid, sodium salt. 
Phenol, sodium salt. 
o-Phenylphenol, sodium salt. 
2,3,'4,6-Tetrachlorophenol, sodium salt. 
2,'i,5-Trichlorophenol, sodium salt. 
4-Sulfo-o-benzoylbenzoic acid. 
o-Fonnylbenzenesulfonic acid. 
5-Nltro-l-anthraqulnonesulfonic acid. 
3-Methyl-l-p-sulfophenyl-5-pyrazolone. 
5-0xo-l-(p-sulf ophenyl ) -2 -pyrazoline-3-carboxyllc 
acid. 

5,5' -Methylenebis[toluene-2,'i-dlamine] . 

Chloranil. 

^,4' -Bisfdiethylaminolbenzhydrol. 

"ij-i'-BisfdiethylamlnoJbenzophenone. 

p,p'-Methylenebis[N,N-<iiethylanillne]. 

p,p'-Benzylidenebis[N,N-diethylaniline]. 

2,7-Bis[dimethylaminoJacrldine hydrochloride. 

^ , ^' ^is[ dimethylamino] benzophenone. 

^,^' -Bis[dlmethylamino]benzhydrol. 

p,p' -Methylenebis[N,N-dimethylaniline] . 

Bis^p-dlmethylaminophenyl]methanesulfonio acid and 

salt. 
p,p' -Benzylldinebi3[ N,N-dlmethylaniline] . 
p,p' -Thlodianiline. 
6,6'-Thiodlmetanilic acid. 
6,6'-Thiodimetanilic acid. 
o-Mercaptobenzoic acid. 
2-Amino-l-naphthalenesulfonic acid. 
3-ABino-6-hydroxy-2-methylphenazine. 
2,2' -Dlamlno-5,5'-bi-m-toluenesulfonlc acid. 
a-Phenylacetamlde. 
p-Toluenesulfonyl chloride. 
l-Amino-4-(p-toluenesulfonamido)-2-anthraquinone- 

sulfonlc acid. 
p-Toluic acid. 
Phenylacetlo acid, 
o-Aminobenzenesulfon-p-toluide, 
4-Amino-o-toluenesulfonlc acid. 



SYNTHETIC ORGANIC CHEMICALS, 1954 

Cyclic intermediates: Glossary of synonymous names- -Continued 



183 



standard (Chemical Abstracts) name 



m-Toluldlne-p-sulfonlc acid ~ — 

o-Toluldlne-m-sulfonlc acid — — — 

o-Toluidlne-omega-suLfonlo acid 

p-Toluldlne-m-sulfonlc acid — 

p-Toluldine-o-sulfonic acid 

p-Toluldlne-o-sulfonlc acid, Isopropyl ester- 

3-Toluldine-6-sulfonlo acid 

a-Tolunltrlle 

-i-Tolunitrlle 

p-Tolyl-o-benzolo acid 

o-Tolylcarblnol ~ — 

p-m-Tolylenedlamlne 

A-m-Tolylenedlamlne -— ~ — 

5-m-Tolylenedl amine — - 

m-Tolylenedlaminesulfonlc acid — - 

Toiyl peri aold- 



2,'i,6-Trlamlnobenzene trlhydrochloride- 
2,i,6-Triamlnotoluene trihydrochlorlde- 

Trlanthraqulnonyldl-imlde 

1,^-Trlanthrlmlde 

1 , 2 , 'i-Trlhydroxyanthraqulnone — — 

1,2,6 -Trlhydroxyanthraquinone 

1,3,5-Trlmethylbenzene ~ — - 

2,'4,6-Trlmethylpyridlne 

Trlnitrophenol — - — - — 

2,A,6-Trlnitrore8orcln 

l,2,'»-Trloxyanthraqulnone — 

Trlphenyl silicon chloride 



3 , 3 '-Ureyleneaniline- 



Vinylbenzene- 



2,i-Xylenesulfonanillde 

m-Xylidlne acetate 

m-Xyiidinesulfonio acid 

Xyiyl chloride 



2-Amino-p-toluenesulfonic acid. 

■i-Amlno-m-toluenesulfonlo acid, 

o-ToluidinomethaneEulTonio acid. 

6-Amlno-m-toluenesulfonic acid. 

5-Amlno-o-toluenesuLfonlc acid. 

5-Amlno-o-toluenesulfonic acid, isopropyl es 

A-Amlno-o-toluenesulfonlc acid. 

Phenylacetonitrile. 

p-Tolunitrile. 

o-(p-Tolyl)benzoic acid. 

2-Methylbenzyl alcohol. 

Toluene -2 , 5 -d iamine . 

Toluene-2, ^-diamine. 

Toluene-3,5-dlamine. 

2,^-Diamlno-m-toluenesull"onic acid. 

8-(p-Toluldino)-l-naphthalenesulfonic acid. 

1,3,5-Benzenetriamine trlhydrochloride. 

2,^,6-Toluenetriamine trlhydrochloride. 

l,'i-Bis[l-anthraquinonylaminoJanthraquinone. 

l,4-Bls[l-anthraquinonylamlno]anthraquinone. 

Purpurin. 

Flavopurpurin. 

Mesitylene. 

s-Collidlne. 

Picric acid. 

Styphnic acid. 

1 , 2 , ^-Trlhydroxyanthraquinone. 

Chlorotriphenylsllane. 

1 , 3-Di (m-aminophenyl)urea. 

Styrene. 

p-Toluenesulfono-o-toluldide. 
2,4-Xylldlne acetate. 
2-Amlno-3,5-xylenesulfonlc acid. 
■i-Chloro-m-jcylene. 



184 UNITED STATES TARIFF COMMISSION 

D. Production and Sales of Cellulose Plastics 

Cellulose plastics are derived from cellulose acetate, cellulose 
propionate, cellulose butyrate, and mixtures of cellulose esters, 
and from cellulose nitrate and ethyl cellulose. The most important 
uses of cellulose plastics are in the manufacture of molded and ex- 
truded articles and accessories such as umbrella handles, toys, 
buckles, and fittings for household and automotive equipment, and 
in packaging. The statistics given in table 30 were compiled from 
the Tariff Commission's monthly reports on the production and 
sales of synthetic plastics and resin materials. 

Production of cellulose plastics as a group in 1954 announted to 
123 nnillion pounds --a slight decrease from the 129 million pounds 
reported for 1953. Sales in 1954 were 121 million pounds, com- 
pared with 125 million pounds in 1953. In volume of production, 
cellulose acetate and mixed ester plastics continued to be the most 
important of the cellulose group. Production of these plastics in 
1954 amounted to 112 million pounds, compared with 115 million 
pounds in 1953. The output of cellulose nitrate plastics in 1954 was 
5. 3 million pounds, compared with 7. 6 million pounds in 1953. 



TABLE 30. --Cellule 



plastics: United States production and sales, 1954 

[ In thousands of pounds] 



Produc- 
tlon 



Cellulose plastics, ^ total 

Cellulose acetate and mixed esters, total 

Sheets, under 0.003 gage 

Sheets, 0.003 gage and over— — 

All other sheets, rods, and tubes -— 

Molding and extrusion materials 

Nitrocellulose sheets, rods, and tubes 

Other cellulose plastics^ . 



123,224 



120,729 



112,396 
17,785 
12,239 
5,809 
76,563 
5,266 
5,562 



110,815 
17,526 
12,399 
5,343 
75,547 
4,909 
5,005 



^ Includes weight of fillers, plasticisers, and extenders. 

^ Includes data for sheets, rods, and tubes, and molding and extrusion materials derived from ethyl cellu- 
lose and other cellulosio materials. 



•i^ U. S. GOVERNMENT PRINTING OFFICE: 1955 O — 35840S 



REPORTS OF THE UNITED STATES TARIFF COMMISSION 
ON THE OPERATION OF THE TRADE AGREEMENTS PROGRAM 

% 

Operation of the Trade Agreements Program, June 1934 to April 1948, Rept. 
No. 160, 2d ser., 1949: 

Part I. Summary, 20^ 

Part II. History of the Trade Agreements Program, 25^ 
Part III. Trade-Agreement Concessions Granted by the United States, 35^ 
Part IV. Trade-Agreement Concessions Obtained by the United States, 25^* 
Part V. Eflfects of the Trade Agreements Program on United States 
Trade, 15< 
Operation of the Trade Agreements Program: Second Report, April 1948- 

March 1949, Rept. No. 163, 2d ser., 1950, 25< 
Operation of the Trade Agreements Program: Third Report, April 1949- 

June 1950, Rept. No. 172, 2d ser., 1951, 45^ 
Operation of the Trade Agreements Program: Fourth Report, July 1950- 

June 1951, Rept. No. 174, 2d ser., 1952, 40?^ 
Operation of the Trade Agreements Program: Fifth Report, July 1951-June 

1952, Rept. No. 191, 2d ser., 1954, 55^ 

Operation of the Trade Agreements Program: Sixth Report, July 1952-June 

1953, Rept. No. 193, 2d ser., 1954, 50< 

tOperation of the Trade Agreements Program: Seventh Report, July 1953- 
June 1954, Rept. No. 195, 2d ser., 1955 



NOTE. The report preceded bv a dagfier <t) is in press and will be available shortly. The 

reports followed by a price may be purchased from the Superintendent of Documents, V. S. Gov- 
ernment Printing Office. Washington 25, D. C. See inside front cover for other available reports. 
All U. S. Tariff Commission reports reproduced by the U. S. Government Printing Office may also 
be consulted in the official depository libraries throughout the United States. 



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