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L&. 


^^ialkS^^^ 


Given  By 

rr.  3:.  SU?T.  OF  DOCUMENTS 


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UNITED     STATES     TARIFF     COMMISSION 

SYNTHETIC 
ORGANIC  CHEMICALS 

United  States  Production 
and  Sales,,  1956 


[GPO  CI.  No.  Report  No.  200 

TC  1.9:  200]  *  Seeond  Series 


BOSTON  PUBLIC  LIBRARY 


3  9999  06317  305  6 


RECENT  REPORTS  OF  THE  UNITED   STATES  TARIFF  COMMISSION 
ON  SYNTHETIC  ORGANIC  CHEMICALS 


Synthetic  Organic  Chemicals,  United   States  Production  and   Sales,  1951 
(Rept.  No.  175,  2d  ser.,  1952),  450 

*Synthetic  Organic  Chemicals,  United   States  Production  and   Sales,  1952 
(Rept.  No.  190,  2d  ser.  1953) 

Synthetic  Organic  Chemicals,  United   States  Production  and   Sales,  1953 
(Rept.  No.  194,  2d  ser.,  1954),  550 

Synthetic  Organic  Chemicals,  United   States  Production  and   Sales,  1954 
(Rept.  No.  196,  2d  ser.,  1955),  600 

♦Synthetic  Organic   Chemicals,   United    States   Production   and  Sales,  1955 
(Rept.  No.  198,  2d  ser.,  1956) 


MISCELLANEOUS  SERIES 

United  States  Import  Duties  (1952),  $4.25  (subscription  price) 

Fortieth  Annual  Report  of  the  United  States  Tariff  Commission  (1956),  250 


NOTE.— The  reports  preceded  by  an  asterisk  (*)  are  out  of  print.  The  other  reports  listed 
may  be  purchased  from  the  Superintendent  of  Documents,  U.  S.  Government  Printing  Office, 
Washington  25,  D.  C.  See  inside  back  cover  for  other  reports.  All  U.  S.  Tariff  Commission 
reports  reproduced  by  the  U.  S.  Government  Printing  Office  may  be  consulted  in  the  official 
depository  libraries  throughout  the  United  States. 


UNITED  STATES   TARIFF  COMMISSION 


SYNTHETIC 
ORGANIC  CHEMICALS 

United  States  Production 
and  Sales,  1956 


UNDER  THE  GENERAL  PROVISIONS 
OF  TITLE  III,  PART  II,  SECTIONS  332 
AND  333  OF  THE  TARIFF  ACT  OF  1930 


UNITED  STATES 

GOVERNMENT  PRINTING  OFFICE 

WASHINGTON   :  1957 


Report  No.  200       •       Second  Series 


«Va1®-7 


UNITED  STATES T'ARIFF  COMMISSION 

Edgak  B.  BroSSARD,  Chairman 
Joseph  E.  Talbot,  Vice  Chairman 
Walter  R.  Schreiber 
Glenn  W.  Sutton 
J.  Weldon  Jones 
William  E.  Dow  ling 

DONN  N.  Bent,  Secretary 


Address  all  communications 

UNITED  STATES  TAKIFF  COMMISSION 

Washington  25,  D.  C. 


ACKNOWLEDGMENT 

In  the  preparation  of  this  report,  the  Commission  had  the  services 

of  James  H.  Hibben,  Henry  O.  Parsons,  Deborah  K.   Emory, 

Frank  Gonet,  Pauline  T.  Eno,  and  other  members  of  its  staff 


For  sale  hy  the  Superintendent  of  Documents,  l".  S.  Government  Printing  Office 
Washington  25,  D.  C.  -  Price  tin  cents 


CONTENTS 


Page 


Introduction "^ 

Summary ^^ 

PART  I.    PRODUCTION  AND  SALES  OF  TARS,    TAR 
CRUDES,    AND  CRUDES  DERIVED  FROM  PETRO- 
LEUM AND  NATURAL  GAS 


Tars 


1 


Tar  crudes "^ 

Crude  products  from  petroleum  and  natural  gas  for  chemical 

conversion ^ 

PART  II.    PRODUCTION  AND  SALES  OF  INTER- 
MEDIATES AND  FINISHED  SYNTHETIC 
ORGANIC  CHEMICALS,    BY  GROUPS 


7 
10 
15 


General 

Cyclic  intermediates 

Dye  s 

Toners  and  lakes 28 

Medicinals 33 

Flavor  and  perfume  materials 37 

Plastics  and  resin  materials '^O 

Rubber-processing  chemicals 44 

Elastomers  (synthetic  rubbers) '4" 

Plasticizers '*' 

Surface -active  agents '*' 

Pesticides  and  other  organic  agricultural  chemicals 51 

Miscellaneous  synthetic   organic  chemicals ^3 

PART  III.    ALPHABETICAL  LIST  OF  INDIVIDUAL 

PRODUCTS,    BY  GROUPS,    AND  NAMES  OF 

MANUFAC  TUR  ERS 

Tar  crudes 5° 

Crude  products  fronn  petroleum  and  natural  gas  for  chemical 

conversion oO 

Cyclic  intermediates "2 

Dyes 81 

Toners  and  lakes 98 

Medicinals 105 

Flavor  and  perfume  materials    119 

Plastics  and  resin  nnaterials 124 

Rubber-processing  chemicals 127 

Elastomers  (synthetic  rubbers) 129 

Plasticizers    129 

Surface -active  agents 132 

Pesticides  and  other  organic  agricultural  chemicals 138 

Miscellaneous  synthetic   organic  chemicals 141 

ICQ 

Directory  of  manufacturers ■'-'° 


iii 


iV  CONTENTS 

APPENDIX 

Page 

A.  United  States  imports  of  coal-tar  intermediates  and 

finished  coal-tar  products 175 

B.  Research  workers  and  research  expenditures  in  the 

synthetic  organic  chemical  industry 176 

C.  Glossary  of  synonymous  names  of  cyclic  intermediates  -  177 

D.  Production  and  sales  of  cellulose  plastics 192 


i 


Introduction 

This  is  the  fortieth  annual  report  of  the  United  States   Tariff 
Commission  on  production  and  sales  in  the  United  States  of  synthetic 
organic  chemicals  and  the  raw  materials  from  which  they  are  made. 
The   report  gives  statistics  for   1956  on  production  and  sales  of  crude 
organic  chemicals  derived  from  coal,    natural  gas,    and  petroleum, 
of  intermediates,    and  of  finished  synthetic   organic  chemical  prod- 
ucts.   The  finished  products  are  grouped  according  to  their  princi- 
pal use--dyes,    toners  and  lakes,    medicinals,    flavor  and  perfume 
materials,    plastics  and  resin  materials,    rubber-processing  chemi- 
cals,   elastomers,    plasticizers,    surface -active  agents,    pesticides 
and  other  organic  agricultural  chemicals,    and  miscellaneous  chemi- 
cals.   With  a  few  exceptions,    the  report  does  not  cover  organic 
chemicals  (such  as  wood-distillation  products,    essential  oils,    and 
naval  stores)  that  are  derived  from  natural  (vegetable)   sources  by 
simple  extraction  or  distillation.    The  Commission  has  compiled  the 
statistics  presented  in  this   report  from  information  supplied  by  the 
620  primary  manufacturers  listed  in  part  III. 

The  raw  materials  referred  to  in  this  report  are  obtained  from 
coal,    crude  petroleum,    natural  gas,    and  certain  other  natural  nraate- 
rials,    such  as  vegetable  oils,    fats,    rosin,    and  grains.    Crude 
organic  chemicals  are  derived  from  coal  by  thermal  decomposition, 
from  petroleunn  and  natural  gas  by  catalytic  cracking  and  by  dis- 
tillation or  absorption,    and  from  other  natural  sources  by  fernnen- 
tation.    Production  of  these  crude  organic  chemicals  is  the  first 
step  in  the  manufacture  of  synthetic  organic  chemicals.    From  these 
crudes,    intermediates  are  obtained  by  synthesis  or  refining;  most 
of  the  intermediates  then  are  converted  into  finished  chemical  prod- 
ucts,   such  as  medicinals,    plastics  and  resin  materials,    and  dyes. 
Intermediates  usually  are  not  sold  directly  to  the  ultimate  consumer, 
but  are  used  by  the  producing  companies  themselves- -or  by  other 
industrial  concerns--in  their  manufacturing  processes. 

In  this  report  the  statistics  on  production  include  the  total  out- 
put of  the  reporting  companies'  plants,    i.e.,    the  materials  produced 
for  consumption  within  the  plants,    as  well  as  those  produced  for 
sale.    The  quantities  reported  as  produced,    therefore,    generally 
exceed  the  quantities  reported  as  sold.    Part  of  some  of  these  dif- 
ferences,   however,    are  due  to  changes  in  inventories.    As  specified 
in  the  reporting  instructions  that  the  Commission  sends  to  manu- 
facturers,   and  as  used  in  this  report,    production  and  sales  (unless 
otherwise  specifically  indicated)  are  defined  as  follows: 

Production  is  the  total  quantity  of  a  commodity  made  available  by 
original  manufacture  only.    It  is  the  sum,    expressed  in  terms  of  the 
basis  specified  in  the   reporting  instructions,    of  the  quantities  of  a 
commodity-- 

(1)  Produced,    separated,    and  consumed  in  the  same  plant  or 
establishment  (a  commodity  is  considered  to  be  separated 
when  it  is  withdrawn  from  the  process); 

(2)  Produced  and  transferred  to  other  plants  or  establishments 
of  the   same  firm; 


Vi  INTRODUCTION 

(3)  Produced  and  sold  to  other  firms  (including  production  for 

others  under  toll  agreements    ); 

(4)  Produced  and  held  in  stock. 

Production  excludes -- 

(1)  Commodities  that  have  already  been  reported  by  the  original 

producer  but  are  purified  in  the  process,    unless  inclusion 
of  such  purified  commodities  is  specifically  called  for  in 
the  reporting  instructions; 

(2)  Intermediate  products  that  are  formed  in  the  manufacturing 

process  but  are  not  withdrawn  from  the  reaction  system; 

(3)  Materials  that  are  used  in  the  process  and  are  recovered  for 

reuse  or  sale,    unless  inclusion  of  such  materials  is  spe- 
cifically called  for  in  the  reporting  instructions. 

Sales  are  defined  as  actual  sales  of  commodities  by  original 
manufacturers  only,  accompanied  by  passage  of  title.  Sales  in- 
c  lude  -  - 

(1)  Shipments  of  commodities  for  domestic  use  or  for  export, 

or  segregation  of  comnnodities  in  a  \varehouse  when  title  to 
them  has  passed  to  the  purchaser  in  a  bona  fide  sale; 

(2)  Shipments  of  commodities  produced  by  other  manufacturers 

under  toll  agreements. 

Sales  exclude -- 

(1)  All  intracompany  transfers,    unless  such  transfers  qualify 

as  transactions  under  the  definition  of  sales  given  above; 

(2)  All  sales  of  purchased  commodities; 

(3)  All  shipments  of  commodities  produced  for  others  under  toll 

agreements. 

The  value  of  a  sale  is  defined  as  the  net  selling  value  of  the  com- 
modities involved,    f .  o.  b.    plant  or  warehouse. 

Data  on  the  chemicals  covered  in  this  report  are  usually  given 
in  terms  of  undiluted  materials.    The  principal  exceptions  are  the 
statistics  on  dyes  and  a  few  solvents,    which  are  reported  in  terms 
of  commercial  concentrations;  the  statistics  on  certain  plastics 
and  resins,    which  are  reported  on  a  dry  basis;  and  the  data  on  sales 
of  antibiotics,    which  are  reported  on  the  basis  of  specific  condi- 
tions mentioned  in  the  section  on  medicinals.    The  report  specifi- 
cally notes  those  products  for  which  the  statistics  are  reported  in 
terms  of  commercial  concentrations. 

The  average  unit  values  of  sales  for  groups  of  products  shown 
in  the  tables  accompanying  this  report  are  weighted  averages  for 
products  which  vary  widely  in  unit  values  and  in  the  quantities  sold. 

Statistics  on  tars  and  tar  crudes  include  data  furnished  directly 
to  the  Tariff  Commission  by  distillers  of  coal  tar,    water-gas  tar, 
and  oil-gas  tar;  data  furnished  to  the  Division  of  Bitunninous  Coal 
of  the  United  States  Bureau  of  Mines  by  coke-oven  operators;  and 
data  furnished  to  the  American  Gas  Association  by  producers  of 
water-gas  and  oil-gas  tar. 


lA  toll  agreement  is  an  agreement  between  two  firms,  under  which  one  firm  furnishes  the  raw 
materials  and  pays  the  processing  costs  and  the  other  firm  prepares  the  finished  product  and  re- 
turns it  to  the  first  firm. 


INTRODUCTION  VU 

Statistics  on  United  States  imports  in  1956  of  coal-tar  interme- 
diates and  finished  coal-tar  products  that  entered  under  paragraphs 
27  and  28  of  the  Tariff  Act  of  1930  are  given  in  part  A  of  the  appen- 
dix.   Part  B  of  the  appendix  includes  a  table  that  shows  the  number 
of  technically  trained  research  workers  in  the   synthetic  organic 
chemical  industry  and  the  cost  of  research  in  the  industry.    Part  C 
of  the     appendix    is  a    glossary  of  the  common  (or  trivial)  names  of 
coal-tar  intermediates  usually  encountered  in  the  trade,    together 
with  their  equivalent  standard  (or  Chemical  Abstracts)  names.  Part 
D  of    the    appendix    summarizes    the  data  on  production  and  sales  of 
cellulose  plastics  that  were  reported  to  the  Commission  monthly 
during   1956. 


Summary 

Combined  production  of  all  synthetic  organic  chemicals  and  their 
raw  materials  in  1956  was  82,  121   million  pounds--9.  8  percent 
more  than  in  1955  (see  table   1).    Sales  totaled  45,  518  million  pounds, 
valued  at  5,  831  million  dollars,    in  1956--an  increase  over  1955  of 
5.  9  percent  in  quantity  and  5.  7  percent  in  value.    As  these  data  in- 
clude those  on  the  production  and  sales  of  chemicals  at  several  suc- 
cessive  steps  in  the  manufacturing  process,    they  necessarily  in- 
clude much  duplication. 

The  output  of  tars  from  all  sources  in  1956  was  8,911  million 
pounds  (891  million  gallons),    or  2.5  percent  less  than  in  1955.    Pro- 
duction of  tar  crudes  by  coke-oven  operators  and  tar  distillers  in 
1956  totaled  14,  560  million  pounds,    or  1.  9  percent  more  than  the 
output  of  14,  292  million  pounds  in  1955.    Sales  of  tar  crudes  totaled 
9,  274  million  pounds,    valued  at  283  million  dollars,    in  1956-- 
representing  an  increase  of  5.  3  percent  in  quantity  and  4.  0  percent 
in  value,    compared  with  1955. 


TAHUE   1, --Synthetic  organic  chemicals  and  their   raw  materials:      United  States  production   and  sales 

1955  and  1956 


Production 


In- 
crease 
or  de- 
crease 
(-), 
1956 
over 
1955^ 


Quantity 


In- 
crease 
or  de- 
crease 
(-), 
1956 


In- 
crease 
or  de- 
crease 
(-), 
1956 
over 
1955^ 


Grand  total^ 

Tar 

Tar  crudes^ 

Crude  products   from 
petroleum  and  natural 
gas 

Synthetic  organic 

chemicals,   total 

Intermediates 

Dyes 

Toners  and  lakes 

Medicinals 

Flavor  and  perfume 
materials 

Plastics  and  resin 
materials 

Rubber-processing 
chemicals 

Elastomers   (synthetic 
rubbers ) 

Plasticizers 

Surface-active  agents* 

Pesticides  and  other 
organic  agricultural 
chemicals 

Miscellaneous   chemicals* 


pounds 

74,821 


Milli 


82,121 


42,966 


45,518 


Million 
dollars 

5,518 


Million 

dollars 

5,831 


9,144 
14,292 


16,179 


35,206 


8,911 
14, 560 


17,898 


40,752 


-2.5 
1.9 


15.8 


4,258 


10,432 


19,469 


4,470 
9,274 


11,032 


20,742 


5.0 
5.3 


49 
272 


4,835 


53 
283 


5,116 


6,016 
168 


3,739 

177 

*   2,083 

396 

1,031 

506 
20,925 


6,600 
152 

41 


3,977 

167 

2,314 

417 

1,148 

570 
25,232 


9.7 
-9.8 

-7.8 
13.5 

6.4 

6.4 

-5.6 

11.1 

5.2 

U.4 


2,285 
156 
38 


3,219 

143 

2,069 
338 
961 


415 
9,740 


2,556 

155 
33 
73 

39 

3,465 

132 

2,156 

331 

1,047 


399 

10,356 


-13.1 
6.7 

9.3 

7.6 

-7.5 

4.2 
-2.0 
8.9 


408 

184 

'        64 

465 

52 

1,078 


573 
104 
229 


153 
1,439 


444 

185 

58 

506 

55 

1,142 

81 

588 
106 
208 


173 
1,570 


8.2 
4.0 


1.0 
-10.1 


4.0 

6.0 

-6.0 

2.6 
2.7 
-9.2 


13.2 
9.1 


^   Percentages  calculated  on  figures   rounded  to  thousands. 

^  This  total  involves  much  duplication. 

^  Excludes  products  derived  from  petroleum,   but  includes  products  derived  from  tar  and  from  coke-oven  gas . 

*  Adjusted. 


IX 


X  SUMMARY 

Production  in  1956  of  all  synthetic  organic  chemicals  (exclud- 
ing the  raw  materials  mentioned  above)  totaled  40,  752  million 
pounds --a  total  also  involving  much  duplication.    This  output  was 
15.  8  percent  greater  than  that  of  35,  206  nnillion  pounds  in  1955. 
Total  sales  of  synthetic  organic  chemicals  in  1956  also  increased 
in  volume  and  in  value,    compared  with   1955.    The  volume  of  output 
of  all  individual  groups  of  finished  synthetic  organic  chemicals  in- 
creased in  1956  compared  with   1956,    except  dyes,    toners  and 
lakes,    and  rubber-processing  chemicals. 

First   in   the    order  of  the  size  of  the  percentage  increase  in 
production  was  miscellaneous  chemicals,    the  output  of  which  in- 
creased to  25,  232  million  pounds  in  1956,    or  by  20.  6  percent.    Pro- 
duction of  medicinals  increased  to  89  million  pounds  in  1956  (or  by 
13.5  percent);  pesticides  and  other  organic  agricultural  chemicals, 
to  570  million  pounds  (12.6  percent);  surface-active  agents,    to 
1 ,  148  million  pounds  (11.4  percent);  elastomers,    to  2,  314  million 
pounds  (11.1  percent);  intermediates,    to  6,600  million  pounds  (9.7 
percent);  flavor  and  perfume  materials,    to  45  million  pounds  (6.4 
percent);  plastics  and  resin  materials,    to  3,  977  million  pounds 
(6.  4  percent);  and  plasticizers,    to  417  million  pounds  (5.  2  per- 
cent). 

Production  of  dyes  in  1956  declined  to  152  million  pounds  from 
168  million  pounds  in  1955,    or  by  9.  8  percent;  that  of  toners  and 
lakes  declined  to  41   million  pounds  in  1956  from  44  million  pounds 
in  1955,    or  by  7.  8  percent;  and  that  of  rubber-processing  chemi- 
cals,   to   167  million  pounds  from   177  million  pounds  in  1955,    or  by 
5.  6  percent. 


PART  I.  PRODUCTION  AND  SALES  OF  TARS,  TAR  CRUDES, 

AND  CRUDES  DERIVED  FROM  PETROLEUM  AND 

NATURAL  GAS 

Tars 

Coal  tar  is  produced  chiefly  by  the  steel  industry  as  a  byproduct 
of  the  manufacture  of  coke;  water-gas  tar  and  oil-gas  tar  are  pro- 
duced by  the  fuel-gas  industry.    Production  of  coal  tar,    therefore, 
depends  on  the  demand  for  steel;  production  of  water-gas  tar  and 
oil-gas  tar  reflects  the  consumption  of  manufactured  gas  for  in- 
dustrial and  household  use.    Water-gas  and  oil-gas  tars  have  prop- 
erties intermediate  between  those  of  petroleum  asphalts  and  coal 
tars.    Petroleum  asphalts  are  not  usually  considered  to  be  raw  ma- 
terials for  chemicals. 

The  quantity  of  tar  produced  in  the  United  States  from  all 
sources  in  1956  was  891  million  gallons,    or  2.5  percent  less  than 
the  output  of  914  million  gallons  in  1955.    Of  the  total  quantity  pro- 
duced in  1956,    833  million  gallons  was  coal  tar  and  58  million 
gallons  was  water-gas  and  oil-gas  tar  (see  table  2),    compared  with 
an  output  in  1955  of  853  million  gallons  of  coal  tar  and  6l  million 
gallons  of  water-gas  and  oil-gas  tar.    The  decline  in  production  of 
coal  tar  in  1956  reflects  decreased  steel  production,    which  was 
partly  attributable  to  a  strike  in  the  steel  mills  in  that  year. 


TABLE  2. --Tar:   United  States  production  and  consumption,    1955  and  1956 

[  In  thousBnds  of  gallons ] 


Water-gas  and  oil-gas  tar^ 

Coal  tar  from  coke-oven  byproduct  plants,^   total - 
Plants  not  owned  tiy  city  gas  oorapaniee- 


Plants  owned  by  city  gas  companies   (public  utilities) 


CONSUMPTION 


Total- 


Tar  consumed  by  distillation,  total — — 

Water-gas  and  oil-gas  tar  distilled  by  producers  and  tar  distillers^ - 

Coal  tar  distilled  or  topped  by  coke-oven  operators^ 

Coal  tar  distilled  by  tar  distillers* 


Tar  consumed  chiefly  as  fuel,  total 

Water-gas  and  oil-gas  tar  consumed  as  fuel'- 


Coal  tar  sold  or  consumed  as  fuel  by  coke-oven  operators' 


Tar  consumed  otherwise  than  by  distillation  or  as  fuel,  total 

Coal  tar  consumed  at  coke-oven  plants  for  roads  and  upkeep^ ---■■ 

Coal  tar,  water-gas  tar,  and  oil-gas  tar  processed  at  tar  refineries, 
crude  tar  consumed  for  upkeep  at  such  refineries,  and  tar  consumed  in 
making  gas  and  in  special-purpose  tar  blends' — 


9U,353 


61,430 
852.923 


BAJ.OOi, 
9,919 


Bib, 112 


52,615 
311,675 
3W,679 

1-^2,0^2 


4,930 
137,062 


1,544 


54,217 


891,157 


58,330 
832.627 


822,717 
10,110 


904,243 


734,019 


58,129 
285,805 
390,085 


3,490 
138,425 


28.309 


1,398 


26,911 


^   Reported  to  the  American  Gas  Association. 

*  Reported  to  the  U.  S.  Bureau  of  Mines. 

'  Reported  to  the  U.  S.  Tariff  Commission. 

*  Represents  tar  purchased  from  companies  operating  coke  ovens  and  gas-retort  plants  and  distilled  by 
companies  operating  tar-distillation  plants. 

'  Reported  to  the  American  Gas  Association  and  to  the  U.  S.  Tariff  Commission. 


2  UNITED  STATES  TARIFF  COMMISSION 

Total  consumption  of  tar  in  1956  amounted  to  904  million  gallons, 
of  which  734  million  gallons  was  consumed  by  distillation,    14Z  mil- 
lion gallons  as  fuel,    and  28  nnillion  gallons  in  miscellaneous  uses 
such  as  pipe  coatings,    upkeep  at  refineries,    and  in  special-purpose 
tar  blends. 

The  quantity  of  tar  distilled  in  1956  was   55  million  gallons  more 
than  that  in  1955.    The  quantity  of  coal  tar  distilled  or  topped  by 
coke-oven  operators  declined  to  286  million  gallons  in  1956  from 
312  million  gallons  in  1955,    but  the  quantity  distilled  by  tar  dis- 
tillers increased  to  390  million  gallons  in   1956  from  315  million 
gallons  in  1955.    The  amount  of  water-gas  tar  and  oil-gas  tar  dis- 
tilled increased  slightly  in  1956,    as  compared  with  1955  (by  5.  5 
million  gallons). 

Tar  Crudes 


Tar  crudes  are  obtained  from  coke-oven  gas  and  by  distilling 
coal  tar,    water-gas  tar,    and  oil-gas  tar.    The  most  important  tar 
crudes  are  benzene,    toluene,    xylene,    naphthalene,    and  creosote  oil. 
Some  of  the  products  derived  from  coal  tar  are  identical  with  those 
produced  from  petroleum  and  natural  gas.    Data  for  materials  de- 
rived from  these   latter  sources  are,    for  the  most  part,    included  in 
or  with  the  statistics  for  materials  derived  from  coal  tar,    which 
are  shown  in  tables  3  and  4A.1 

Total  domestic  production  of  industrial  and  specification  grades 
of  benzene  amounted  to  337  million  gallons  in  1956,    or  9.  5  percent 
more  than  the  307  miillion  gallons  reported  for  1955.    These  totals 
include  material  produced  from  domestic  tar,    from  imported  and 
domestic  crude  light  oil,    from  domestic  petroleum,    and  from  im- 
ported motor-grade  benzene.    Sales  of  benzene  amounted  to  284 
million  gallons,    valued  at  103  million  dollars,    in  1956,    compared 


TARLE   3. --Tar    and  tar   crudfts:      Sua 


ry  of  production   and  sales  of  sped  fied  products, 
annual    1955   and   1956 


erage   1951-55. 


Chemical'- 


Average 
1951-55 


decrease  (-;, 

1956 

over  1951-55 


decrease   (-), 

1956 

over  1955 


Tar:  Production^. 
Benzene: 

Production 

Sales-- -- 

Value  of  EELles- 
Toluene: 

Production 

Sales 

Value  of  sales- 
Xylene: 

Production 

Sales 

VsLlue  of  sales- 
Naphthalene: 

Production 

Sales 

Value  of  sales- 
Creosote  oil: 

Production 

Sales 

Value  of  sales- 


1,000  gal- 

1,000  gal- 
1,000  gal- 
1,000  dol- 

1,000  gal- 
1,000  gal- 
1,000  dol- 

1,000  gal- 
1,000  gal- 
1,000  dol- 


,000  lb— 
,000  lb— 
,000  dol- 

,000  gal- 
,000  gal- 
,000  dol- 


861,258 

270,886 

230,091 

88,<;92 

141,529 
112,921 
32,944 

95,799 
65,196 
17, 103 

345,269 

245,609 

13,597 

136,397 
128,750 
24,773 


914,353 

307,479 

264,808 

97,534 

185,502 
138,263 
39,115 

107,940 
77,603 
20,623 

477,170 

338,657 

19,6^2 

129,701 
118,994 
23,596 


24.3 
23.6 
16.1 

22.7 
19.7 


42.3 
30.8 
30.4 

42.3 
17.7 
37.2 

-2.9 
7.5 


891,157 

336,590 
284,457 

102,759 

173,594 
135,201 
35,166 

136,277 
85,295 
22,300 

491,430 

288,975 

18,657 

132,450 
138,358 
26,919 


9.5 
7.4 
5.4 

-6.4 
-2.2 
-10.1 

26.3 
9.9 
8.1 


2.1 
16.3 
14.1 


For  details  concerning  statistics  shown  In  this  table  see  table  4A. 
^  Includes  data  for  oil-gas,  water-gas,  and  gas-retort  tar  reported  to  the  American  Gas  Association,  and 
for  coal  tar  reported  to  the  Division  of  Bituminous  Coal,  U.  S.  Bureau  of  Mines. 
^   Includes  data  for  material  produced  for  use  in  blending  motor  fuels. 


iSee  also  table  -ffl,  part  III,  which  lists  these  products  and  identifies  the  manufacturers. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


T^BLE  4A. --Organic  che 


United  States  producti 


6{   tar  crudes,    1956 


[Listed  below  are  all  tar  crudes  for  which  any  reported  data  on  production  or  sales  may  be  published.  Table 
AB  in  part  III  lists  separately  all  products  for  which  data  on  production  or  sales  were  reported  and  iden- 
tifies the  manufacturers  reporting  to  the  U.  S.  Tariff  Commission] 


Pro- 
duction 


Quantity   Value 


Unit 
value ^ 


Crude  light  oil 

Intermediate  light  oil:  Coke-oven  operators 

Light -oil  distillates: 

Benzene,  specification  and  industrial  grades, 

total 

Tar  distillers^ 

Coke-oven  operators 

Petroleum  operators 

Toluene,  all  grades,  total 

Tar  distillers 

Coke-oven  operators 

Petroleum  operators 

Xylene,  all  grades,  total-' 

Tar  distillers 

Coke-oven  operators 

Petroleum  operators 

Solvent  naphtha,  total 

Tar  distillers 

Coke-oven  operators 

All  other  light-oil  distillates,  total 

Tar  distillers 

Coke-oven  operators 

Pyridine  crude  bases  (dry  basis) 

Naphthalene,  crude  (solidifying  at  less  than 

79°  C.),*  total 

Tar  distillers 

Coke-oven  operators 

Crude  tar-acid  oils: 

Tar  distillers 

Coke-oven  operators 

Cresylic  acid,  crude  (less  than  755t  distilling 
over  215°  C):  Tar  distillers 

Creosote  oil  (Dead  oil),'  total 

Tar  distillers: 

Distillate  as  such  (lOO^t  creosote  basis) 

Creosote  in  coal-tar  solution  {lOQ'f,   solution 

basis) 

Creosote  content  of  solution  (IOO5J  creosote 

basis) 

Coke-oven  operators: 

Distillate  as  such  (IOO56  creosote  basis) 

Creosote  in  coal-tar  solution  (100«t  solution 

basis) 

Creosote  content  of  solution  (lOOjt  creosote 

basis) 

All  other  distillate  products^ 

Tar,  road 

Tar  (crude  and  refined)  for  other  uses' 

Pitch  of  tar: 

Soft  and  medium  (water  softening  point  less 
than  110°  p.,  and  110°  F.  to  160°  F.  ASIM 

D61-24) 

Hard  (water  softening  point  above  160°  F.) 

Pitch  of  tar  coke  and  pitch  emulsion 


1,000  gal- 
1,000  gal- 

1,000  gal-- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gU.- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 

1,000  lb— 
1,000  lb— 
1,000  lb— 

1,000  gal- 
1,000  gal- 

1,000  lb— 
1,000  gal- 

1,000  gal- 

1,000  gal- 

1,000  gal- 

1,000  gal- 

1,000  gal- 

1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 

1,000  tons 
1,000  tons 
1,000  tons 


293,756 

3,008 


336,590 

50,551 

17<i,'i26 

111,613 

173,594 

5,584 

37,233 

130,772 

136,277 

1,362 

10,340 

124,075 

25,006 

19,181 

5,825 

9,195 

2,795 

6,400 

1,343 

491,430 


314,171 
177,259 


4,261 
26,311 


5,770 
132,450 


34,946 

19,075 

13,833 

23,984 

4,445 

3,711 
31,337 
92,376 
38,431 


1,194 

874 
31 


3,047 


284,457 

34,698 

173,420 

76,339 

135,201 

5,019 

35,584 

94,598 

85,295 

1,493 

10,237 

73,565 

24,367 

18,663 

5,704 

7,641 

2,769 

4,872 


288,975 


153,046 
135,929 


26,136 


138,358 


1,000 
dollars 


102,759 

10,377 

59,548 

32,834 

35,166 

1,414 

10,162 

23,590 

22,300 

445 

3,245 

18,610 

5,556 

4,118 

1,438 

1,429 

767 

662 


13,657 


10,335 
3,272 


279 
6,924 


26,919 


83,213 
20,631 
13,589 

25,117 

4,397 

3,637 
21,459 
83,949 
36,664 


17,485 
3,664 


4,976 


3,378 
13,759 
6,149 


22,763 
19,354 
1,198 


38.78 
35.51 
39.93 


^   Unit  value  per  gallon,  pound,  or  ton,  as  specified. 

^  Includes  data  for  benzene  produced  from  imported  crude  light  oil. 

^   Includes  data  for  material  produced  for  use  in  blending  motor  fuels. 

*  Statistics  represent  combined  data  for  the  3  commercial  grades  of  naphthalene  to  avoid  disclosure  of  in- 
dividual company  operations.  Owing  to  conversion  between  grades,  the  figures  may  include  some  duplication. 

^  Statistics  Include  data  only  for  creosote  oil  sold  for  or  used  in  wood  preserving. 

'  Includes  data  for  shlngle-staln  oil  and  neutral  oils  produced  by  tar  distillers,  and  for  crude  sodium 
phenolate  produced  by  coke-oven  operators. 

''  Includes  data  for  tar  used  for  paint,  pipe  covering,  saturating,  and  other  uses. 

Note. — Statistics  for  materials  produced  In  coke  and  gas-retort  ovens  are  compiled  by  the  Division  of  Bitu- 
minous Coal,  U.  S.  Bureau  of  I;Iines.  Statistics  for  materials  produced  in  tar  and  petroleum  refineries  are 
compiled  by  the  U.  S.  Tariff  Commission. 


4  UNITED  STATES  TARIFF  COMMISSION 

with  265  million  gallons,    valued  at  98  million  dollars,    in  1955.    The 
output  of  toluene  from  all  sources  (including  material  produced 
from  petroleum  for  use  in  blending  in  aviation  fuel)  amounted  to  174 
million  gallons  in  1956--slightly  less  than  the  186  million  gallons 
produced  in  1955.    Sales  of  toluene  in  1956  amounted  to  135  million 
gallons,    valued  at  35  million  dollars.    The  output  of  xylene  in  1956 
(including  that  produced  for  blending  in  motor  fuel)  was   136  million 
gallons;  sales  were  85  million  gallons,    valued  at  ZZ  million  dollars. 
More  than  90  percent  of  the  domestic  output  of  xylene  in  1956  was 
derived  from  petroleum  sources. 

Production  of  crude  naphthalene  in  1956  amounted  to  491   million 
pounds,    or  about  3  percent  more  than  the  477  million  pounds  re- 
ported for  1955.    Sales  of  naphthalene  were  Z89  million  pounds, 
valued  at  19  million  dollars,    in  1956,    compared  with  339  million 
pounds,    valued  at  ZO  million  dollars,    in  1955.    In  1956  the  total  out- 
put of  creosote  oil,    used  principally  in  wood  preserving,    was  13Z 
million  gallons;  sales  were   138  million  gallons,    valued  at  Z7  million 
dollars.    Production  of  road  tar  in  1956  was  9Z  million  gallons-- 
slightly  less  than  the  93  million  gallons  reported  for  1955. 

Some  of  the  products  included  in  the  statistics  given  in  table  4A 
are  derived  from  other  products,    data  for  which  are  also  included 
in  the  table.    The  statistics,    therefore,    involve  considerable  dupli- 
cation; for  this  reason,    no  group  totals  or  grand  totals  are  shown. 
After  as  much  duplication  as  possible  has  been  eliminated,    it  is 
estimated  that  the  net  value  of  production  of  these  products  and  of 
tar  burned  as  fuel  was  39Z  million  dollars  in  1956,    compared  with 
378  million  dollars  in  1955  and  345  million  dollars  in  1954. 

Crude  Products  From  Petroleum  and  Natural  Gas  for 
Chemical  Conversion 

Crude  products  that  are  derived  from  petroleum  and  natural  gas 
are  related  to  the  intermediates  and  finished  products  made  fronn 
such  crudes  in  much  the  same  way  that  crude  products  derived  from 
the  distillation  of  coal  tar  are  related  to  their  intermediates  and 
finished  products.    Many  of  the  crude  products  derived  from  petro- 
leum are  identical  with  those  derived  from  coal  tar  (e.g.  ,    benzene, 
toluene,    and  xylene).    Considerable  duplication  exists  in  the  statis- 
tics on  the  production  and  sales  of  petroleum  crudes  because  some 
of  these  crude  chemicals  are  converted  to  other  crude  products  de- 
rived from  petroleum  and  because  data  on  some  production  and  sales 
are  reported  at  successive  stages  in  the  conversion  processes  (see 
table  5A2).    Notwithstanding  these  duplications,    the  statistics  are 
sufficiently  accurate  to  indicate  trends  in  the  industry  and  to  serve 
as  a  basis  for  general  comparison.    Many  of  the  crude  products  for 
which  data  are  included  in  the  statistics  may  be  used  either  as  fuel 
or  as  basic  materials  from  which  to  derive  other  chemicals,    de- 
pending on  prevailing  economic  conditions.    In  this  report,    every 
effort  has  been  made  to  exclude  data  on  materials  that  are  used  as 
fuels.    However,    data  are  included  on  xylene  that  is  not  used  directly 
as  a  fuel  but  in  blending  aviation  and  motor -grade  gasolines. 

Production  of  crude  products  derived  from  petroleum  and  natural 
gas  as  a  group  amounted  to  17,  898  million  pounds  in  1956,    or   10.  6 


2  See  also  table  5B,  part  in,  which  lists  these  products  alphabetically  and  identifies  the  manu- 
facturers. 


SYNTHETIC  ORGANIC   CHEMICALS,  1956  5 

percent  more  than  the  I6,  179  million  pounds  reported  for  1955, 
The  larger  output  in   1956  is  accounted  for  chiefly  by  the  increase 
in  the  production  of  aliphatic  hydrocarbons,    principally  ethylene, 
butadiene,    1 -butene  and  2-butene  mixture,    isobutylene,    and 
propylene.    Sales  of  crude  chemicals  from  petroleum  were   11,  032 
million  pounds,    valued  at  379  million  dollars,    in  1956,    compared 
with  10,432  million  pounds,    valued  at  362  million  dollars,    in  1955. 

The  output  of  all  aromatic  and  naphthenic  products  amounted  to 
3,459  million  pounds  in  1956,    compared  with  3,  175  million  pounds 
in  1955.    Sales  were  2,  502  million  pounds,    valued  at  92  million 
dollars,    in  1956--representing  an  increase  of  125  million  pounds 
and  2  million  dollars  over  sales  in  1955.    Benzene  and  xylene  were 
produced  from  petroleum  sources  in  substantially  larger  quantities 
in  1956  than  in  1956;  production  of  cresylic  acid  increased  by  21.  7 
percent.    Production  of  specification-  and  industrial-grade  benzene 
from  petroleum  was  818  million  pounds  in  1956,    compared  with  723 
nnillion  pounds  in  1955- -representing  an  increase  of  13.  2  percent. 
The  output  of  xylene  was  895  million  pounds  in  1956.    These  figures, 
however,    are  not  comparable  with  those  for   1955  because  the   1956 
data  include  xylene  used  in  blends  in  aviation  and  motor-grade  gaso- 
line,   whereas  the  1955  data  did  not.    The  output  of  naphthenic  acids 
amounted  to  23  million  pounds  in  1956,    compared  with  17  million 
pounds  in  1955.    Production  of  cresylic  acid  was  30  million  pounds 
in  1956,    compared  with  24  million  pounds  in  1955;  .the  output  of 
toluene  was  947  million  pounds  in  1956,    compared  with  1,038  mil- 
lion pounds  in  1 955- -indicating  a  decline  of  8.8  percent. 

Production  of  all  aliphatic  hydrocarbons  and  derivatives  from 
petroleum  and  natural  gas  was   14,439  million  pounds  in  1956,    com- 
pared with  13,004  million  pounds  in  1955.    Sales  of  these  products 
were  8,  530  million  pounds,    valued  at  288  million  dollars,    in  1956, 
compared  with  8,  055  million  pounds,    valued  at  271  million  dollars, 
in  1955.    Statistics  on  acetylene  are  given  for  the  first  time  in  this 
report.    The  statistics  include  only  acetylene  that  was  produced 
from  calcium  carbide  and  from  natural  gas  and  was  used  as  a  raw 
material  in  the  production  of  other  chemicals.    The  statistics  ex- 
clude acetylene  used  for  welding  and  lighting.    Total  production  of 
acetylene  (principally  from  calcium  carbide),    as  reported  to  the 
Bureau  of  the  Census,    amounted  to  571  million  pounds  in  1956. 
Production  of  ethylene  was   3,  602  million  pounds  in   1956,    or   18.  2 
percent  more  than  the  3,  048  million  pounds  produced  in  1955.    The 
output  of  the  C3    hydrocarbons,    propane,    propylene,    and  propane- 
propylene  mixture,    was  3,824  million  pounds  in  1956,    compared 
with  3,339  million  pounds  in  1955- -representing  an  increase  of 
14.  5  percent.    Production  of  1,  3-butadiene,    including  that  produced 
from  alcohol,    was   1,  502  million  pounds  in  1956,    compared  with 
1,411  million  pounds  in  1955.    Production  of  1,  3 -butadiene --one  of 
the  principal  ingredients  of  the  GR -S  type  of  synthetic  rubber--was 
the  largest  on  record  in  1956,    the  first  full  calendar  year  of  opera- 
tion of  the  synthetic -rubber  industry  by  private  owners. 


6 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  5^. -'Synthetic  organic  chemicals:      United  States  production  and  sales  of  crude  products    from 
petroleum  and  natural   gas   for  chemical   conversion,    1956 

Clisted  below  are  the  crude  products  from  petroleum  and  natural  gas  for  chenilcal  conversion  for  which  any 
reported  data  on  production  or  sales  may  be  published.  (Leaders  are  used  where  the  reported  data  are 
accepted  in  confidence  and  may  not  be  published  or  where  no  data  were  reported.)  Table  5B  in  part  III  lists 
separately  all  products  from  petrcle'jm  and  natural  gas  for  chemical  conversion  for  which  data  on  production 
or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Grand  total 

AROMATICS  AND  NAPHTHENES^ 
Total 

Allsyl  aromatics,  distillates,  and  solvenxs 

Benzene  (except  motor  grade),  total 

Benzene,  1° 

Benzene,  2° 

Cresylic  acid,  crude-' 

Naphthenic  acids,  total 

Acid  number  150-199 - 

Acid  number  225-249- 

All  other 

Toluene,  all  grades,  total 

Nitration  grade,  1° 

Pure  commercial  grade,  2° 

All  other 

Xylenes,  mixed,  total 

Aviation  grade 

Nitration  grades,  3  and  5° 

All  other'^ - - - • 

All  other  aromatics  and  naphthenes' 

ALIPHATIC  HYDROCARBONS 

Total 

C2  hydrocarbons,  total 

Ethane 

Ethylene^ 

C3  hydrocarbons,  total 

Propane 

Propane-propylene  mixture 

Propylene 

C4  hydrocarbons,  total 

1,3-Butadiene,  grade  for  rubber  (elastomers)' 

Butadiene  and  butylene  fractions 

n- Butane* 

1-Butene  and  2-butene  mixture' 

Isobutane 

Isobutylene 

All  other^"-- 

C5  hydrocarbons''^ 

All  other  aliphatic  hydrocarbons  and  derivatives,  total- 

1-Dodecene  ( Tetrapropylene) 

Nonene  ( Tripropylene) 

Hydrocarbon  derivatives'-^ 

All  other'^ 


l.nnn 

pounds 

17,898,030 


3,459,175 


725,496 


279,016 
539,107 

29,772 

22,937 


2,665 

10,815 
9,457 

946,789 


382,105 
363,376 
201,308 

894,580 


226,502 
141,460 
526,618 

21,478 
14,438,855 


4,164,511 


562,153 
3,602,358 

3,823,861 


2,181,141 

227,954 

1,414,766 

5,039,028 


1,502,254 
412,399 
1,214,666 
1,006,659 
450,777 
327,352 
124,921 

310,709 

1,100,746 


394,491 

105,084 

5,996 

595,175 


Quantity 


1,01)0 
pounds 
11,031,740 


2,501,788 


689,323 
559,565 


239,185 

320,380 

12,738 
13,691 


2,469 

10,127 
1,095 

684,889 


273,650 

411,239 
530,404 


67,219 
102,476 
360,709 

11, 178 


8,529,952 


1,000 
dollars 
379,333 


91,639 


14,099 
32,834 


14,422 
18,412 

455 

1,548 


195 
1,246 

107 

23,590 


9,899 

13,691 
18,610 


793,305 


199,134 
594,171 

3,019,545 


2,216,919 
227,951 
574,675 

3,820,968 


952,133 
169,383 
930,772 
982,431 
434,834 
222,751 
128,664 

225,242 

670,892 


195,421 

52,956 

6,233 

416,282 


2,546 
4,805 
11,259 


287,694 


29,830 


1,441 
28,389 

35,619 


25,065 

2,374 

S,180 

196,904 


134,653 
5,641 
8,684 
30,226 
6,004 
7,525 
4,171 

4,715 

20,626 


6,470 

2,251 

771 

11,134 


$0.03 


^   Calculated  on  rounded  figures. 

^  The  chemical  raw  materials  designated  as  aromatics  are  in  some  cases  identical  with  those  obtained  from 
-the  distillation  of  coal  tar.  However,  the  statistics  given  in  -this  table  relate  only  to  such  materials  as  are 
derived  from  petroleum  and  natural  gas. 

^  Statistics  on  crude  cresylic  acid  from  coal  tar  are  shown  in  table  4A. 

*  Includes  xylene  blended  in  motor  gasoline. 

'  Includes  data  for  sodium  cresylate,  l,4-methano-2,5-cyclopentadiene,  mixed  pyridines,  sodium  carbolate  and 
phenate,  and  hydrocarbon  polymers. 

'  Includes  a  small  amount  of  ethylene  from  coke-oven  gas. 

'  Includes  butadiene  made  from  ethyl  alcohol.  In  1956  all  butadiene  was  produced  in  privately  owned  plants. 
For  some  earlier  years  separate  statistics  are  available  on  butadiene  production  for  private  account  and  for 
Government  account. 

*  Statistics  on  n-butane  are  not  strictly  comparable  with  those  for  1955  because  of  changes  by  some  companies 
in  reporting  production  and  sales  by  subsidiaries. 

'  The  statistics  represent  principally  the  butene  content  of  crude  refinery  gases  from  which  butadiene  is 
manufactured . 

^°  Includes  data  for  1-butene,  2-butene,  butane-butylene,  and  mixed  olefins. 

'-'■  Includes  data  for  pentanes,  pentenes,  isoprene,  and  mixtures. 

^^   Includes  data  for  di-tert-butyldisulfide,  miscellaneous  mercaptans,  and  aliphatic  acids. 

^^   Includes  data  for  methane,  acetylene,  di-isobutylene,  hexanes,  heptanes  and  heptenes,  octanes  and  octenes, 
polybutene,  eicosane,  and  hydrocarbon  mixtures.  The  above  data  do  not  include  any  acetylene  produced  from  cal- 
cium carbide.  The  to-tal  production  of  acetylene  for  chemical  processing  from  all  sources,  as  reported  by  -the 
Bureau  of  the  Census,  for  1956  amounted  to  570,972  thousand  pounds. 


PART  n.  PRODUCTION  AND  SALES  OF  INTERMEDIATES  AND 
FINISHED  SYNTHETIC  ORGANIC  CHEMICALS,  BY  GROUPS 

General 

On  the  basis  of  their  principal  uses,    the   synthetic  organic 
chemicals  covered  in  this   report  are  classified  as  either  inter- 
mediates or  as  finished  products.    Finished  products,    in  turn,    are 
grouped  as  follows:  Dyes,    toners  and  lakes,    medi'cinals,    flavor  and 
perfume  materials,    plastics  and  resin  materials,    rubber-process- 
ing chemicals,    elastomers  (synthetic   rubbers),    plasticizers,    sur- 
face-active agents,    pesticides  and  other  organic  agricultural  chem- 
icals,   and  miscellaneous  synthetic  organic  chemicals.    Most  of 
these  groups  are  further  subdivided,    acc:ording  to  chemical 
classes,    into  cyclic  and  acyclic  compounds. 

As  most  of  the  intermediates  are  used  in  the  manufacture  of 
finished  products,    aggregate  figures  that  cover  both  intermediates 
and  finished  products  necessarily  include  much  duplication. 

Total  production  of  all  synthetic  organic  chemicals  (interme- 
diates and  finished  products  combined)  was  40,  75Z  million  pounds 
in  1956,    or  5,  546  million  more  than  the  output  in  1955  (see  table 
6).    Sales  totaled  20,  742  million  pounds,    valued  at  5,  116  million 
dollars,    in  1956,    connpared  with  19,469  million  pounds,    valued  at 
4,  835  million  dollars,    in  1955.    Production  of  all  cyclic  products 
(intermediates  and  finished  cyclic  products  combined)  in  1956 
totaled  13,  069  million  pounds,    or  7.  8  percent  more  than  the   12,  123 
million  pounds  produced  in  1955.    Sales  of  all  such  cyclic  products 
were  7,  954  million  pounds  in  1956,    compared  with  7,  582  million 
pounds  in  1955--an  increase  of  4.9  percent.    Production  of  finished 
cyclic  products  totaled  6,469  million  pounds  in  1956  and  that  of 
cyclic  intermediates,    6,600  million  pounds,    compared  with  out- 
puts of  6,  106  million  pounds  and  6,016  million  pounds,    respectively, 
in  1955. 

In  1956,    production  of  acyclic  organic  chemicals  (finished 
acyclic  products  and  acyclic  intermediates  combined)  was  27,684 
million  pounds,    or  19.9  percent  more  than  the  output  in  1955. 

Of  the  individual  groups  of  finished  synthetic  organic  chemicals 
that  have  both  cyclic  and  acyclic  components,    the  change  in  pro- 
duction between  1955  and  1956  was  as  follows  (all  are  increases 
except  those  preceded  by  a  minus  sign):  Medicinals  (cyclic,    6.  2 
percent,    and  acyclic,    40,6  percent);  flavor  and  perfume  materials 
(cyclic,    5.3  percent,    and  acyclic,    7.9  percent);  plastics  and  resin 
materials  (cyclic,    -0.  I  percent,    and  acyclic,    14.  1  percent); 
rubber-processing  chemicals  (cyclic,    -4.  7  percent,    and  acyclic, 
-10.  6  percent);  elastomers  (cyclic,    10.  0  percent,    and  acyclic,    15.1 
percent);  plasticizers  (cyclic,    6.4  percent,    and  acyclic,    1.7  per- 
cent); surface-active  agents  (cyclic,    17.  2  percent,    and  acyclic, 
1.8  percent);  pesticides  and  other  organic  agricultural  chemicals 
(cyclic,    10.4  percent,    and  acyclic,    24.6  percent);  and  miscella- 
neous chemicals  (cyclic,    7.7  percent,    and  acyclic,    21.0  percent). 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  6.--Syntheti 


organic   chemicals:    Summary  of  United  States  [production  and  sale 
and  finished  products,    average   1951-55,    annual   1955  and  1956 


[  Production  and  sales  in  thousands  of  pounds;  sales  value  In  thousands  of  dollars 


Average 
1951-55 


Increase  or 
decrease  (-) 


1956 

over 

1951-55 


Organic  chemicals,  cyclic  and  acyclic, 
grand  total: 

Production 

Sales - 

Sales  value 

Cyclic,  total: 

Production 

Sales 

Sales  value 

Acyclic,  total: 

Production 

Sales -— 

Sales  value 

i.     Internediatcs,    Cyclic 

Production 

Sales 

Sales  value 

2.  Dyes,  Cyclic 

Production 

Sales - 

Sales  value 

a.  Colour  Index  Group 

Production 

Sales 

Sales  value : 

b.  Prototype  Group 

Production 

Sales 

Sales  value 

c .  Ungrouped 

Production 

Sales- 

Sales  value 

3.    Toners    and   Lakes,    Cyclic 

Production 

Sales 

Sales  value 

i.    Medicinals 

Cyclic: 

Production 

Sales 

Sales  value 

Acyclic: 

Production 

Sales 

Sales  value 

5.    Flavor    and   Perfume    Material 

Cyclic: 

Production 

Sales 

Sales  value 

Acyclic: 

Production 

Sales 

Sales  veilue 


29,279,W1 
15,957,625 
<1,099,41A 


9,773,197 
6,145,375 
2,107,761 


19,506,444 
9,812,250 
1,991,653 


4,805,597 

1,859,597 

339,459 


161,817 
150,743 
171,767 


113,600 
105,795 
89,329 


30,277 
28,267 
49,262 


17,940 
16,681 
33,176 


42,914 
37,064 
55,129 


55,870 

44,630 

420,337 

14,441 
12,233 
26,479 


19,789 
16,804 
24,354 

13,951 
U,098 
20,967 


35,206,358 
19,469,342 
4,834,644 


12,122,951 
7,581,717 
2,485,768 


23,083,407 
11,887,625 
2,348,876 


6,016,480 

2,284,607 

408,046 


168,005 
155,980 
183,628 


118,986 
110,980 
96,970 


33,083 
30,469 
53,599 


15,936 
14,531 
33,059 


44,481 
38,042 
64,304 


61,965 

50,583 

435,993 

16,762 
17,950 
29,128 


24,116 
20,144 
30,961 

17,858 
15,699 
21,594 


40,752,268 

20,742,146 

5,115,614 


13,068,747 
7,953,733 
2,566,569 


27,683,521 
12,788,413 
2,549,045 


6,599,759 

2,556,405 

443,844 


151,575 
154,547 
185,443 


108,856 
111,889 
99,249 


28,134 
27,762 
50,673 


14,585 
14,896 
35,521 


40,992 
33,066 
57,788 


65,802 

53,499 

473,717 

23,573 
19,642 
32,212 


25,391 
20,723 
32,865 

19,267 
18,446 
21,809 


39.2 

30.0 
24.8 


29.4 
21.8 


41.9 
30.3 

28.0 


37.3 
37.5 
30.8 


-6.3 
2.5 

8.0 


-4.2 
5.8 

11.1 


-7.1 

-1.8 

2.9 


-18.7 

-10.7 

7.1 


-4.5 
-10.8 


17.8 
19.9 


63.2 
60.6 
21.7 


28.3 
23.3 

34.9 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


TARLE  6. -Synthetic  organic  cheiiicals:    Summary  of  United  States  production  and  sales  of  inter 
and  finished  products,    average  1951-55,    annual    1955  and   /956-- Con tinned 

[  Production  and  sales  in  thousands  of  pounds;  sales  value  in  thousands  of  dollars] 


Average 
1951-55 


Increase  or 
decrease  (-) 


1956 
over 
1951-55 


1956 
over 
1955 


«.    Plastics    and   Utsin   Materials 

Cyclic: 

Production 

Sales 

Sales  value 

Acyclic: 

Production 

Sales 

Sales  value 


7. 


(he 


cals 


Kubber-Proc 

Cyclic: 

Production 

Sales 

Sales  value 

Acyclic: 

Production 

Sales 

Sales  value 

8.    Elastomers    (Synthetic  Rubbers) 

Cyclic: 

Production 

Sales 

Sales  value 

Acyclic: 

Production 

Sales - 

Sales  value 

S.  Plasticizers 

Cyclic: 

Production 

Sales 

Sales  value 

Acyclic: 

Production 

Sales 

Sales  value 

10.    Surface-Active   Agents^ 

Cyclic: 

Production 

Sales 

Sales  value 

Acyclic: 

Production 

Sales 

Sales  value 

11.    Pesticides    and   Other   Organic 
Agricultural    Chemicals 

Cyclic: 

Production 

Sales 

Sales  value 

Acyclic: 

Production 

Sales 

Sales  value 


1,597,590 

1,312,585 

359,919 

1,226,004 

1,118,831 

-^82,185 


120, 7A9 
91,326 
50,916 

22,769 
18,420 
13,012 


1,397,056 

1,395,930 

335,319 

476,533 
465,154 
184,967 


229,175 
183,014 
59,463 

78,436 
63,575 
26,199 


562,338 

476,709 

93,252 

320,076 

285,066 

69,984 


372,562 
304,620 
114,29: 

60,083 
51,618 
21,551 


2,021,233 

1,650,022 

439,443 

1,717,683 

1,569,366 

638,390 


148,431 
120,639 
70,454 

28,689 
22,385 
15,340 


1,642,679 

1,643,752 

402,460 

"■439,943 
^425,193 
^  170, 138 


296,294 

252,834 

71,794 

99,762 
85,247 
31,911 


641,228 
600,738 
135,972 

389,342 

360,648 

93,115 


429,367 
354,102 
125,530 

77,009 
61,208 
27,242 


2,018,274 

1,654,687 

455,068 

1,959,195 

1,810,023 

687,351 


141,494 
111, 173 
67,253 

25,655 
21,058 
13,409 


1, 807, 694 

1,679,569 

402,738 

506,339 
476,287 
184,845 


315,343 

243,656 

72,502 

101,4-45 
87,677 
33,987 


751,614 
689,722 
110,374 

396,392 

357,099 
97, 624 


473,965 
342,863 
135,257 

95,962 
56,538 
37,651 


59.8 
61.8 
42.5 


17.2 
21.7 
32.1 

12.7 
14.3 


29.4 
20.3 
20.1 

6.3 
2.4 


37.6 
33.1 
21.9 

29.3 
37.9 
29.7 


44.7 
18.4 


23.8 
25.3 


27.2 
12.6 
18.3 


15.3 
7.7 


-10.6 
-5.9 
-12.6 


10.0 
2.2 


15.1 
12.0 
8.6 


6.4 
-3.6 

1.0 

1.7 
2.9 
6.5 


17.2 
14.8 
-18.8 

1.8 

-1.0 


10.4 
-3.2 
7.7 

24.6 
-7.6 
38.2 


See  footnotes  at  end  of  table. 


10 


UNITED  STATES  TARIFF  COMMISSION 


TARLE  6, -'Synthetic  organic  chemicals:    Summary  of  United  States   production   and  sales  of  intermediates 
and   finished  products,    average    1951-55,    annual    1955  and   795(5- -Continued 

[Production  and  sales  In  thousands  of  pounds;  sales  value  In  thousands  of  dollars] 


Average 
1951-55 


Increase  or 
decrease  (-) 


1956 
over 
1951-55 


1956 
over 
1955 


Cyclic: 

Production — 

Sales - 

Sales  value- 

Acyollc: 

Production- - 

Sales- 

Sales  value- 


407,740 

272,353 

83,555 

17,294,151 
7,784,255 
1,146,309 


628,672 
410,274 
117,183 

20,296,359 
9,329,929 
1,322,018 


676,844 
413,823 
129, 72Q 

24,555,693 
9,941,643 

1,440,157 


66.0 
51.9 
55.3 

42.0 
27.7 
25.6 


7.7 
1.0 
10.7 

21.0 
6.6 
8.9 


^  Adjusted  to  eliminate  data  for  vinyl  elastomers  which  are  covered  in  the  statistics  on  plastics  and 
resin  materials  on  the  basis  of  their  components. 

^  For  1955  and  1956,  data  are  adjusted  for  the  transfer  of  oil-soluble  type  of  petroleum  sulfonates  from 
the  group  of  surface-active  agents  to  lubricating  oil  additives  in  the  group  of  miscellaneous  chemicals. 


The  following  tabulation  shows,  by  chemical  groups,  the  num- 
ber of  companies  that  reported  production  in  1956  of  one  or  more 
of  the  chemicals  included  in  the  groups  listed  in  table  6: 


Vunber 
of 
Group  companies 

Intermediates 153 

Dyes - 49 

Toners  and  lakes 40 

Medicinals 126 

Flavor  and  perfume  materials 54 

Plastics  and  resin  materials 170 

Rubber -processing  chemicals  -- 25 


tlunber 

of 

companies 
Group 

Elastomers  (synthetic  rubbers) 26 

Plasticizers   51 

Surface -active  agents 154 

Pesticides  and  other  organic 

agricultural  chemicals 80 

Miscellaneous  chemicals 256 


Cyclic  Intermediates 


Cyclic  intermediates  are  synthetic  organic  chemicals  derived 
principally  from  coal-tar  crudes  produced  by  destructive  distilla- 
tion (pyrolysis)  of  coal  and  from  petroleum  and  natural  gas.    Most 
cyclic  intermediates  are  used  in  the  manufacture  of  more  advanced 
synthetic  organic  chemicals  and  finished  products,    such  as  dyes, 
medicinals,    explosives,    elastomers  (synthetic  rubbers),    pesticides, 
and  plastics  and  resin  materials.    Some  intermediates,    however, 
are  sold  as  end  products  without  further  processing.    For  example, 
refined  naphthalene  may  be  used  as  a  raw  material  in  the  manu- 
facture of  2-naphthol  or  of  other  more  advanced  intermediates,    or 
it  may  be  packaged  and  sold  as  a  moth  repellent  or  as  a  deodorant. 
In  general,    the  way  in  which  the  greater  part  of  the  output  of  a 
given  chemical  is  consumed  determines  its  use  classification  in  this 


SYNTHETIC  ORGANIC  CHEMICALS,  1956  11 

report.    Table   YA-"-    shows  statistics  on  production  and  sales  of 
cyclic  intermediates  in  1956.    Intermediates  for  which  individual 
statistics  are  given  in  the  table  represent  more  than  80  percent  of 
the  total  quantity  produced.    Since  many  of  the  intermediates  in- 
cluded in  the  statistics  represent  successive  steps  in  production, 
the  totals  necessarily  include  considerable  duplication.    In  1956 
about  two-fifths  of  the  total  output  of  cyclic  intermediates  was  sold; 
the   rest  was  consumed  chiefly  by  the  producing  plants  in  the  manu- 
facture of  more  advanced  intermediates  and  finished  products. 

Because  of  the  increased  demand  by  most  consuming  industries 
(particularly  the  industries  that  produce  plastics,    surface-active 
agents,    and  rubber),    the  total  output  of  cyclic  intermediates  in 
1956  was  6,  600  million  pounds,    or  9.  7  percent  more  than  the 
previous  record  high  of  6,  016  million  pounds  reported  for  1955. 
Sales  of  cyclic  intermediates  in  1956  amounted  to  2,  556  million 
pounds,    valued  at  444  million  dollars,    compared  with  2,  285  million 
pounds,    valued  at  408  million  dollars,    in  1955. 

The  output  of  many  individual  intermediates  was  substantially 
larger  in  1956  than  in  1955.    Production  of  each  of  two  intermediates 
exceeded  1  billion  pounds  in  1956;  the  output  of  styrene  totaled 
1,  176  million  pounds  (an  increase  of  15.9  percent,    compared  with 
1955)  and  that  of  ethylbenzene,    1,  171   million  pounds  (an  increase 
of  8.4  percent).    Ethylbenzene  is  used  almost  entirely  in  the  manu- 
facture of  styrene;   styrene,    in  turn,    is  used  in  the  manufacture  of 
plastics  materials  and  synthetic  rubber.    Production  of  dodecylben- 
zenes,    used  chiefly  in  the  manufacture  of  surface-active  agents, 
amounted  to  486  inillion  pounds  in  1956,    or  24.  9  percent  more  than 
the  389  million  pounds  reported  for  1955.    Other  large-volume  inter- 
mediates,   the  output  of  which  was  substantially  larger  in  1956  than 
in  1955,    were  cresylic  acid  (an  increase  of  22.6  percent),    cresols 
(an  increase  of  15.  2  percent),    phenol  (an  increase  of  6.  3  percent), 
and  monochlorobenzene  (an  increase  of  3.  9  percent).    Production  of 
many  important  intermediates,    on  the  other  hand,    was  smaller  in 
1956  than  in  1955;  the  output  of  refined  naphthalene  declined  13.9 
percent;  that  of  nitrobenzene,    7.  3  percent;  that  of  aniline,    6.  5  per- 
cent; and  that  of  phthalic  anhydride,    4.  9    percent. 

Data  on  a  number  of  important  intermediates  becanne  available 
for  the  first  time  in  1956.    The  output  of  each  of  these  intermediates 
in  1956  was  as  follows:  Cyclohexanone,    125  million  pounds; 
cyclohexanol,    88  million  pounds;  4,  4 -isopropylidenediphenol 
(Bisphenol  A),    25  million  pounds;  and  a-methylstyrene,    11  million 
pounds. 


iSee  also  table  7B,  part  III,  which  lists  these  products  alphabetically  and  identifies  the  manu- 
facturers; part  A  of  the  appendix,  which  shows  imports  of  intermediates  and  related  products 
during  1954-56;  and  part  C  of  the  appendix,  which  is  a  glossary  of  synonymous  names  of  cyclic 
intermediates. 


12 


UNITED  STATES  TARIFF  COMMISSION 

icals:   United  States  production  and  sales  of  cyclic   intermediates,    1956 


TAHLE  7A.  -Synthetic  organi 

[  Listed  below  are  all  cyclic  intermediates   for  which  any  reported  data  on  production  or  sales  may  be  pub- 
lished.   (Leaders   are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or 
where  no  data  were  reported.)  Table  7B  in  part  III  lists  alphabetically  all  cyclic   intermediates   for  which 
data  on  production  or  sales  were  reported  and  identifies  the  manufacturer  of  each.    Part  C   in  the  appendix 
lists  alphabetically  all  the  important  common  names  of  cyclic   intermediates  usually  met  with  in  the  trade 
and  gives  the  corresponding  standard  (Cheraical  Abstracts)  name  under  which  data  are  presented  in  tables  7A 
and  7B] 


Quantity       Value 


Unit 
value^ 


Total —  - 

Chemicals   for  which  separate  statistics  may  not  be  shown 

Chemicals   for  which  sepeirate  statistics  are  shown  below 

Acetanllide,   tech.    and  U.S.P 

i '-Aminoacetanilide   (Acetyl-p-phenylenediamine) 

5-Amino-2-(p-aminoanllino)benzenesulfonic   acid 

2-(p-Amlnoanilino) -5-nltroben2enesulf onic  acid 

1-Amlnoanthraquinone   and  salt 

2-Arainoanthraquinone  and  salt 

6-Amlno-3,<i'  -azobis[benzenesulfonic   acid] 

l-Amino-^-benzamidoanthraquinone 

6-(p-Amlnobenzaiiiido)-l-naphthol-3-sulfonic  acid 

2-Amlno-p-benzenedisulfonic  acid  [S03H=1] 

p-Aminobenzoic  acid,   tech 

l-Amino-'i-bromo-2-anthraquinonesulfonic  acid 

l-Amlno-5-chloroanthraquinone 

2-Amino-3-chloroanthraquinone 

2-Amino-'i-chlorophenDl 

2-Amino-5-chloro-p-toluenesulfonic  acid  [S03H=l] 

l-Amino-2,'4-dibromoanthraqulnone 

3-Amino-l,5-naphthalenedisulfonic  acid  (Caasella  acid) 

6-Amlno-l,3-naphthalenedisulfonic  acid  (Amino  I  acid) 

2-Amlno-l-naphthalenesulfonic  acid   (Tobias   acid) 

5-Amino-l-naphthalenesulfonic   acid   (Laurent's   acid) 

5-Amlno-2-naphthaleneEulfonlc  acid   (1,6-Cleve's  acid) 

5(and  8)-Amino-2-naphthalenesulfonlc   acid  (Cleve's  acid,  mixed)—- 

6-Amino-2-naphthalenesulfonlc  acid  (Broenner's  acid) 

8-Amino-l-naphthalenesulfonlc  acid  (Perl  acid) 

8-Amino-2-naphthalenesulfonic  acid  (1,7-Cleve's  acid) 

8-Amlno-l,3,6-naphthalenetrisulfonic  acid  (Koch's  acid) 

8-Amino-2-naphthol 

8-AiiiinD-l-naphthol-3,6-dlsulfonic  acid   (H  acid),  monosodium  salt- 
8-AminD-l-naphthol-5,7-dlsulfonic  acid  (Chicago  acid),  monosodium 

salt 

l-Amlno-2-naphthol-<--sulfonic   acid   (1,2,4-Aold) 

6-AmlnD-l-naphthol-3-sulfonic  acid   (J  acid),   sodium  salt 

7-Amino-l-naphthol-3-3ulfonic  acid   fGamma  acid),   sodium  salt 

2-Amlno-5-nltrobenzenesulfonlc  acid  [S03H=1] 

2-Amino-i-nitrophenol 

4'-Amlnooxanilic  acid 

2-Amlno-l-phenol-'i-sulfonamide 

2-Amino-l-pheQDl-<i-sulfonic  acid 

p-(p-Aminophenylazo)benzenesulfonlc   acid 

l-(m-Amlnophenyl)-5-oxo-2-pyTazoline-3-carboxyllc  acid 

^-Amino-m-toluenesulfonic  acid  [  SO^H^l] 

4-(4-Amlno-m-tolylazo)-m-toluenesulfonlc  acid 

2-Amino-3,5-xyleneEulfonic  acid  [  S03H=l] 

Aniline  (Aniline  oil) 

Anilinomethanesulfonic  acid  and  salt 

8-Anillno-l-naphthalenesulfonic  acid  (Phenyl  peri  acid) 

6-Anilino-l-naphthol-3-sulfonic  acid  (Phenyl  J  acid) 

7-AnilinD-l-naphthol-3-sulfonlc  acid  (Phenyl  gamma  acid) 

o-Anisidine 

o-Anlsidinomethanesulfonic  acid,  and  sodium  salt 

Anthranlllc  acid  (o-Amlnobenzoic  acid) 

Anthra[l,9l  pyrazol-6(2H)-one  (Pyrazoleanthrone) 

1,5-Anthraquinonedisulfonic  acid 

2,6-AnthraquinDnedisulfonic  acid  and  salt 

1-Anthraqulnonesulfonlc  acid  and  salt 

3-(l-AnthraqulnDnylamino)-7H-ben2[de  ]anthracen-7-one 

Anthrarufin  (1,5-Dihydroxyanthraquinone) 

Benzaldehyde,  tech 

l-Benzamido-4-chloroanthraqulnone 

l-Benzamido-5-chloroanthraquinone 

7H-Benz[de]anthracen-7-one  ( Benzanthrone ) 

Benzidine  hydrochloride  and  sulfate 

Benzilic  acid 

Benzoic  acid,  tech 

o-Benzoylbenzolo  acid 

Benzyl  ether  (Dibenzyl  ether) 

[  <i,4.'-Bl-7H-benz[de]anthracen  1-7,7  -dlone- 

See  footnotes  at  end  of  table. 


1,000 

pounds 

6,599,759 


1,000 

pounds 

2,556,^05 


1,000 
dollars 
443,844 


1,054,559 
5,545,200 


650,897 
1,905,508 


151,593 
292,251 


2,804 
270 
40 
50 
816 
658 
38 


38 

16 

1,239 

59 

105 

631 

2,764 

162 

167 

69 

360 

253 

2,745 

87 

2,735 

64 

1,045 

441 

703 

35 

65 

21 

20 

101 

151 


22 

123,149 

168 

257 

50 

15 

833 

69 

317 

10 

586 

244 

1,815 

207 

189 

1,849 

70 

106 

1,490 

1,307 

49 


4,731 


2,923 


857 
115 


50,711 


9,900 

74 


1,619 


2,572 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


13 


TABLR  .7A.  -  -Syntheti 


chemicals:    United  States   production  and  sales  of  cyclic    intermediates, 
J95<S- -Continued 


Quantity 


l,<i-BlE[l-aiithraquinonylamlnD]anthraqulnone 

3,9-Bls[l-aiithraquinonylanilno)-7H-ben2[de]anthracen-7-one 

^,'t' -Blsfdimethylajnlnojbenzhydrol   (Michler's  hydrol) 

■4,^' -Blsldiinethylaminojbenzophenone   (Michler's  ketone) 

3-Bromo-7H-benz[de] anthracen-7-one  (Bromobenzanthrone) 

l-Chloroanthraqulnone 

2-Chloroanthraquinone 

o-Chlorobenz aldehyde 

Chlorobenzene,  mono 

o-(p-Chlorobeuzoyl)benzolc   acid 

l-Cl'LLoro-2,4-dl  nitrobenzene ■ 

4-Chlorometanllic   acid 

6-Chlorometanlllc  acid 

l-Chloro-2-methylanthraqulnone 

2-Chloro-'i-nltroanlllne   (o-Chloro-p-nitroanillne) 

4-Chloro-2-nltroanlltne   (p-Chloro-o-nltroanlllne) 

l-Chloro-5-nltroanthraqulnone 

l-Chloro-8-nitroanthraqulnone 

l-Chloro-2(and  'i)-nitrobenzene  (Chloronitrobenzenes,   o-  and  p-)    

2-Chloro-5-nltrobenzenesulfonlc  acid 

4-Chloro-3-nltrobenzenesulfonic  acid 

^-Chloro-3-nitrobenzenesulfonyl  chloride 

o-CA-Chloro-S-nltrobenzoyllbenzolc  acid 

2-Chloroqulnlzartn 

o-Chlorotoluene   (Benzyl  chloride) 

4-Chloro-o-toluldine  [NHj  =1]  (5-Chloro-o-toluidlne  [CH3  =1]  ) 

5-Chloro-o-toluidlne  hydrochloride   [NHj=1] 

Creeols,   total^ 

0-,   m-,   and  p-Cresols,   total 

(m, p)-Cresol 

(o,m,p)-Cresol'' 

Cresyllc  acid,  refined,  total^ 

From  coal  tar 

From  petroleum 

Cmnene 

Cyclohexane 

Cyclohexanol 

Cyolohexanone 

p-Cymene 

l,i-Di  amino anthraquinone 

1,5-DlaminDanthraquinone 

2,6-Dlamlnoanthraquinone 

2,'4-Diaminobenzenesulfonic  acid  [SOjH-l] 

A, A  -DiaminD-3,3 '-blphenyldlsulfonic  acid 

A, A  -Diamino-2,2  -stllbenedisulfonic  acid 

l,5-Dianillno-2,6-anthraquinonedicarboxyllc  acid 

2,'*-Dianillno-l-hydroxyanthraquinDne 

■ijS'-Dibenzamldo-ljl'-iminodlanthraquinone 

1,5-Dlbenzoylnflphthalene 

3,9-Dlbramo-7H-benz[de]anthracen-7-one 

2,5-Dichloroanillne  and  hydrochloride   [NHj^l] 

1, 5-Dlchloroanthraqulnone 

1,8-Dichloroanthraqulnone 

o-Dichlorobenzene 

p-Dlchlorobenzene 

3,3' -Dichlorobenzidine  base  and  salts 

2, A-  and  2,5-Dlchlorobenzolc   acids,   total 

2,5-Dichloro-4-(3-methyl-5-oxo-2-pyrazolln-l-yl)benzenesulfonic   acld- 

N,N-Diethylaniline— 

4,5-Dlhydroxy-2,7-naphthalenedisulfonic  acid   (Chromotropic  acid) 

4,5-Dihydroxy-l-naphthalenesulfonlc   acid  (Dioxy  S  acid) 

6,7-Dihydroxy-2-naphthalenesulfonic  acid 

16,17-Dihydroxyviolanthrone  (Dihydroxydibenzanthrone) 

2, 5-Dimethoxy aniline 

N,N-Dimethylaniline 

2,2'-Dimethyl-l,l'-bianthraquinone 

m-Dlnitrobenzene 

2,'i--DlnitrophenDl,  tech 

4,4 '-Dinitro-2,2'-stilbenedisulfonlo   acid  and  disodlum  salt 

l,4-Di(p-toluidlno)anthraquinDne 

Dodecyl benzenes* 

2-(N-Ethylanilino)ethanol 

a-(N-Ethylanilino)-p-toluenesulfonic   acid 

Ethylbenzene 

N-Ethyl-N-phenylbenzylamine  (N,N-Ethylbenzylaniline) 

o-Formylbenzenesulfonic  acid  (o-Sulfobenzaldehyde) 

p-Hydrazinobenzenesiilfonic  acid 

3-HydToxy-2-naphthoio  acid  (B.O.N. ) 

See  footnotes  at  end  of  table. 


1,000 
pounds 

77 

187 

36 

119 

164 

173 

<192 

2<i3 

452,434 

964 

3,112 

32 

19 

131 

28-4 

371 

32 

60 

8,622 

171 

154 

93 

46 

18 

12,644 

49 


1,000 
pounds 


1.000 
dollars 


12,873 
12,631 
15,499 

80,768 


38,818 
41,950 

159,768 
267,408 
88,044 
125,013 

85 

205 

117 

42 

7 

1,009 

23 

18 

194 

60 

140 

272 

60 

33 

25,273 

57,565 

1,116 

25 

81 

991 


331 

386 

21 

7,746 

103 

1,785 

510 

1,474 

53 

486,005 

115 

419 

,170,595 

779 

192 

142 

3,165 


4,485 


3V.526 


11,324 
10,321 
15,881 

61,190 


27,244 
33,946 


3,571 


16,160 

46,280 

1,013 


386,116 
98 


1,403 


907 

19 

7,720 


3,976 
2,149 
1,595 

6,764 


3,660 
3,104 


1,733 
5,981 
1,384 


40,916 
87 


1,454 


14  UNITED  STATES  TARIFF  COMMISSION 

TABLE   7A. --Synthetic   organic   chemicals:    United  States   production  and  sales   of  cyclic   intermediates, 

1956- -Continued 


Production 


(Juairtity       Value 


N-(7-HycJroxy-l-naphthyl)acetamlde 

l,l'-IinlnobisK-aiiilnoaiithraq\ilnone] 

l,l'-Iminobls  [5-beiizamidoanthraquinone] 

6,6'-Imlnobls[l-naphthol-3-sulfonic  acid] 

l,l'-Imlnodlanthraquinone   (Dianthrimlde ) 

Isooyaulc  acid,  methylenedi-p-phenylene  ester 

.i,<i'-Isopropylldenedlphenol   (Bisphenol  A) 

Isoviolanthrone   (Isodlbenzanthrone) 

Leuco-l,4-diamlnoanthraqulnone 

Leuco  quinizarin  (1,4,9,10-Anthratetrol) 

Leuco  tetrahydroxyanthxaqulnone 

2,4-Lutldlne--- --- 

Metanllic   acid  (m-AminobenzeneEulfonlo  acid) 

2-Methyl-l-nltroanthraqulnone 

p- (3-Methyl-5-oxo-2-pyrazolin-l-yl )benzenesulf onlc   acld- 

3-Methyl-l-phenyl-2-pyrazolln-5-one   (Developer  Z) 

a-Methylstyrene 


Naphthalene,   solidifying  at  79"C.,   or  above   (refined  Qake),   total 

From  American  crude  naptithalene 

From  imported  crude  naphthalene 


1,5-Naphthalenedlsulfonic  acid — . 

Naphthionlc   acid,   sodium  salt 

1-Naphthol   (a-Naphthol) 

2-Naphthol-3,6-disulfonlc  acid   (R  acid),    and  disodium  salt 

2-Naphthol-6,8-dlsulfonic  acid  (G  acid) 

l-Naphthol-5-sulfonlc  acid 

2-Naphthol-6-sulfonlc   acid  (Schaeffer's  acid) 

1,8-NaphthoEultone 

Naphth[l,2]  oxadiazole-5-sulfonic  acid 

2-(Naphthylthlo)acetlc  acid  (p-Naphthylthloglycolic  acid) 

p-Nitroacetanllide 

m-Nltro aniline 

2-,   3-,    and  -V-Nltro-o-anlsidines   [NH2=i1.   total 

5-Nitro-o-anlsidlne  (  NH2»l] 

l-Nltro-2-anthraquinonecarboxylic  acid 

5-Nitro-l-anthraquinonesulfonic  acid 

Nitrobenzene 

m-Nltrobenzenesulfonlc   acid  and  sodium  salt 

5-Nitro-o-toluenesulfonio  acid  [S03H=l] 

2-Nitro-p-toluidlne  [NHj-I] 

16-Nltrovlolanthrone 

Nonyl phenol 

5-0xo-l-(p-sulfophenyl)-2-pyrazoline-3-oarboxylic  acid   (Pyrazolone  T)- 

Phenol,   grand  total^ 

Natural,    total 

From  coal  tar 

From  petroleum 

Synthetic,   total 

From  cumene 

Other  synthetic 


Phenylacetlo  acid  (a-Tolulo  acid) 

Phenylacetic  acid,  potassium  salt 

Phenylacetonitrile  (o  -Tolunltrile) 

p- Phenyl azoanlllne  (p-Amlnoazobenzene)  and  hydrochloride 

m-Phenylenediamine 

o-Phenylenedl amine 

p-Phenylenedi amine 

Phenylglycine,  potassium  and  sodium  salts,  total 

2,2'-(Phenylimlno)dlethanol 

Phthalic  anhydride 

Phthallmide 

Plcoline  (3,4-mixture)' -- 

2-Plcoline  (a-Plooline)^ — 

2°  Pyridine' 

Qulnaldine 

Quinizarin 

/^Resorcylic   acid 

Salicylic  acid,   tech 

Styrene,    all  grades 

Tetrabramo-8,16-pyranthrenedione 

l,'i,5,8-Tetrachloroanthraqulnone 

l,2,'4-,5-Tetra''hlorobenzene 

1,4,5,8-Tetrakis[l',l",l'",l  ""-anthraqulnonylamino]  anthraqulnone 

(Pentaanthrajnlde) 

3,3'-Thiobis[7H-benz  [de]anthracen-7-one] 

o-Tolldlne  and  salts 

Toluene- 2, 4-diamlne  (4-m-Tolylenedlamlne) 


See  footnotes  at  end  of  table. 


10 
156 

73 

10 

119 

100 

25,152 

41 
176 
133 

41 

181 

1,652 

134 

78 

392 

10,530 

3,564 


.000 
mnds 


U,776 


000 
dollar. 


3,299 


62,774 
17,790 

155 

1,077 

513 

1,316 

1,807 

34 

431 

44 

599 

108 

203 

145 

139 

169 

49 

110 

163,028 

1,204 

2,013 

1,646 

43 

20,101 

29 

549,163 


117 

14 


41,320 


30,300 
11,020 


5,679 


4,102 
1,577 


39,811 

34,548 

5,263 

509,352 
93,778 

415,574 

480 

1,126 

659 

132 

935 

67 

624 

3,116 

389 

315,237 


7,179 
864 

742 

4,260 

302,615 


35,725 

34,619 

5,106 

262,890 
85,617 

177,273 

353 

1,206 

139 


267,668 


797 
312 


1,155 
978 


47,567 
5,813 


5,025 

788 

41,754 

12,823 

28,931 

209 
519 
89 


50,094 


572 

516 

289 

446 

506 

207 

1,260 

1,351 

950 

19 

924 

38 

56 

21 

54 

1,369 

469 

1,175,645 

573,921 

89,961 

17 

48 

9,393 

227 

52 

142 

3,386 

381 

364 

SYNTHETIC  ORGANIC   CHEMICALS,  1956 


15 


TABLE  7A. --Synthetic  organic  chemicals:   United  States  production  and  sales  of  cycli 

/95«--ContinueH 


ntermedi  ates , 


o-(p-Toluyl)benzoio  acid 

i-(o-Tolylazo)-o-toluidine   (o-Amtnoazotoluene) 

a,  a,a-Trichlorotoluene   (Benzotrichloride) 

6,6'-Ureylenebis[l-naphthol-3-sulfonic  acid]   (J  acid  urea)- 

Veratraldehyde   (3,'i-Dimethoxybenzaldehyde) 

Violanthrone   (Dibenzanthrone) 

o-Xylene 

Xylenols,  total 

2,'^-  and  (o-,p-)  Xylidines,   total 

2^5-Xylidine   (p-Xylidine) 


Production 


263 
■iSl 


3,757 


Quantity 


1.000 
pounds 


1,000 
dollars 


Unit 
value^ 


pound 

$0.17 

3.24 

.05 


^  Unit  values  calcxaated  on  rounded  figures. 

^  Includes  data  for  coke  ovens  and  gas-retort  ovens  reported  to  the  Division  of  Bituminous  Coal,  U.  S. 
Bureau  of  Mines,  and  for  tar  and  petroleum  refineries  and  other  producers  reported  to  the  U.  S.  Tariff 
Commission. 

^  Includes  some  mixed  cresols. 

*  Includes  keryl-type  benzenes. 

'  Includes  data  for  coke  ovens  and  gas-retort  ovens  reported  to  the  Division  of  Bituminous  Coal,  U.  S. 
Bureau  of  Mines,  and  for  tar  refineries  and  other  producers  reported  to  the  U.  S.  Tariff  Commission. 


Dyes 


Dyes  are   synthetic   organic  chemicals  derived  from  cyclic 
intermediates  (see  the  preceding  section  of  this  report).    About 
three-fourths  of  the  dyes  consumed  in  the  United  States  are  used 
by  the  textile  industry  to  dye  natural  and  synthetic  fibers  or  fabrics; 
the  rest  are  used  chiefly  by  the  industries  that  produce  organic  pig- 
ments,   paper,    and  leather.    Of  the   several  thousand  different  syn- 
thetic dyes  that  are  known,    more  than  two  thousand  are  manufac- 
tured by  one  or  more  domestic  producers.    The  large  number  of 
dyes  results  from  the  many  different  types  of  materials  to  which 
dyes  are  applied,    the  different  conditions  of  service  for  which  dyes 
are   required,    and  the  costs  that  a  particular  use  can  bear.    Dyes 
are   sold  as  pastes,    powders,    lumps,    and  solutions;  concentrations 
vary  from  6  percent  to   100  percent.    The  concentration,    form,    and 
purity  of  a  dye  is  deternnined  largely  by  the  use  for  which  the  dye 
is  intended. 

Dyes  are  broadly  grouped  by  chemical  structure  and  by  class  of 
application.    In  terms  of  chemical  structure,    the  most  important 
dyes  are  the  azo  and  anthraquinone  dyes;  in  terms  of  class  of  appli- 
cation,   the  most  important  are  the  vat,    direct,    and  acid  dyes. 

Table  8A^   shows  United  States  production  and  sales  of  dyes  in 
1956,    total  and  by  individual  dyes,    grouped  by  Colour  Index  number 
and  prototype  number.    The  total  domestic  output  of  dyes  in  1956  was 
152  million  pounds;  this  output  was  9.  8  percent  less  than  the   168 
million  pounds  produced  in   1955,    but  6.  0  percent  more  than  the   143 
million  pounds  produced  in   1954.    Fluctuations  in  output  during  the 
past  several  years  reflect  variations  both  in  domestic  consumption 
by  the  textile  industry  and  in  sales  to  export  markets.    Sales  of  dyes 
amounted  to   155  million  pounds,    valued  at  185  million  dollars,    in 
1956,    compared  with   156  million  pounds,    valued  at  184  million 
dollars,    in  1 955 --indicating  a  decline  of  0.9  percent  in  quantity  and 
an  increase  of  1 .  0  percent  in  value. 


2  See  also  table  8B,  part  m,  which  lists  these  products  and  identifies  the  manufacturers,  and  part 
A  (table  28)  of  the  appendix,  which  shows  imports  of  dyes  during  1954-56. 


16 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  8A. -Synthetic  organic  chemicals:   United  States  product! 


nd  sales  of  coal- tar  dyes,    1956 


[Listed  below  are  all  coal-tar  dyes  for  which  any  reported  data  on  production  or  sales  may  be  published. 
(Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where 
data  were  reported.  )  Table  8B  in  part  III  lists  all  dyes  for  which  data  on  production  or  sales  were  re- 
ported and  identifies  the  manufacturer  of  each] 


Dye 


Grand  total - 


Dyes  for  which  separate  statistics  may  not  be  shown 
Dyes  for  which  separate  statistics  are  shown  below- - 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBER 


Monoazo  Dyes 


Spirit  yellow  R 

Oil  yellow 

Chrysoidine  Y 

Chrysoidine  R 

Sudan  I 

Orange  G 

Amido  naphthol  red  G — 

Chrome  yellow  2G 

Chrome  yellow  R 

A20  alizarin  yellow  GP- 
Amido  naphthol  red  5B-- 

Fast  scarlet  G  base 

Fast  red  GL  base 

Fast  red  GL  salt 

Sudan  II 

Ponceau  R 

Fast  red  B 

Chrome  brown  R 

Azo  eosine  G 

Fast  red  B  salt 

Fast  scarlet  R  base 

Fast  scarlet  R  salt 

Metanil  yellow 

Azoflavine  RS 

Orange  II 

Orange  R 

Acid  chrome  garnet  R 

Fast  red  A 

Azo  rubine 

Cochineal  red  A 

Chrome  blue  black  R 

Chrome  black  T 

Acid  chrome  red  B 

Chrome  flavine  A 


i.OOO 
pounds 

151,575 


Dlsazo  Dyes 


Resorcin  brown 

fiesorcin  dark  brown 

Acid  black  lOB 

Azo  dark  green  A 

Brilliant  croceine  M 

Cloth  red  B 

Milling  orange 

Cloth  scarlet  G 

Direct  fast  red  8BL 

Fast  acid  cyanlne  5R  ex 

Acid  chrome  black  F 

Fast  acid  black  2BN 

Fast  acid  cyanlne  black  B- 

Dlrect  fast  heliotrope 

Direct  fast  scarlet 

Direct  fast  scarlet  iBA — 

Bismarck  brown  G 

Bismarck  brown  R 

Chrome  fast  yellow  C 

Direct  fast  yellow  5GL 

See  footnotes  on  page  22. 


28,739 
122,836 


108,856 


538 

163 
,030 
392 
322 


563 
,691 


377 

331 

1,.65'; 

60 
279 
27 


263 

370 
107 


671 
192 
130 
934. 


29  I 


Quantity 


1,000 
pounds 
154,547 


27,091 
127,456 


111,889 


601 
161 
941 
424 
372 
32 


1,000 
dollars 
185,443 


42,662 
142,781 


93 

94 

87 

187 

189 

265 

248 

267 

241 

50 

47 

51 

91 

105 

149 

60 

76 

112 

99 

130 

134 

179 

161 

196 

852 

764 

569 

256 

289 

301 

21 

69 

967 

1,007 

647 

346 

385 

292 

148 
104 
497 
128 
998 
450 
464 
32 


102 

97 

947 

750 

1,960 

2,250 

15 

17 

10 

21 

416 

462 

350 

411 

1,774 

1,754 

37 

62 

304 

533 

32 

36 

24 

21 

9 

15 

246 

556 

394 

451 

109 

165 

239 

317 

320 

420 

19 

72 

824 

1,573 

210 

414 

120 

93 

1,001 

1,035 

SYNTHETIC  ORGANIC  CHEMICALS,  1956 


17 


TAHLE  8A. --Syntheti 


icals:    Vniteri  States  products 


19  56 --Continue  A 


657 
658 
662 
666 
667 
671 
676 
680 
681 
682 
698 
720 
722 
729 


Dye 


DYES  GROUPED  BY  COLOUR  INDEX  mMBER--Continued 


Azo  Z)yes--Contlnued 


Dlsazo  Dyes--Continued 


Direct  fast  pink  2BL--- 

3rilllant  yellow 

Chrysophenine  G 

Congo  red 

Congo  corinth  G 

Direct  scarlet  B 

Direct  violet  B 

Direct  violet  N 

Developed  black  BH 

Direct  blue  23 

Direct  orange  R 

Direct  fast  red  F 

Direct  brown  M 

Polar  red 

Milling  red  G 

Benzopurpurine  'iB 

Benzo  new  blue  5B 

Direct  blue  3B 

Acid  anthracene  red  3B- 

Fast  blue  B  base 

Fast  blue  B  salt 

Direct  azurine  G 

Direct  blue  RW 

Direct  sl<y  blue  FF 

Direct  pure  blue 


Trlsazo  Dyes 


Direct  fast  blue  FR-- 
Direct  fast  black  FF- 

Direct  brown  BT 

Direct  black  EW 

Direct  black  RX 

Direct  green  ET 

Direct  green  B 

Direct  brown  3G0 

Congo  brown  G 


Direct  yellow  R 

Chloramine  orange  G- 
Stilbene  yellow 


Pyrazalo 


Fast  light  yellow  G- 
Xylene  light  yellow - 

Tartrazlne 

Polar  yellow 

Chrome  red  B 

Pyrazol  orange 


i«  Dy< 


TriphenyUe  thane   and  Diphenylnaphthylm 


Malachite  green 

Rhoduline  blue  6G 

Brilliant  green 

Acid  green  B 

Fast  acid  green  B 

Acid  glaucine  blue 

Para  fuchsine 

Methyl  violet  B  and  base- 
Crystal  violet 

Ethyl  violet 

Acid  violet 

Acid  chrome  azurol  B 

Acid  chrome  cyanine  R 

Victoria  blue  B 


1,000 
pounds 
30 
289 

126 
63 

109 


2,293 
505 

114 
189 
398 
205 

525 
26 


116 
72 
56 
24 

307 
63 


35 

147 
121 
5,404 
442 
173 
428 
672 


50 
184 
372 


91 

147 

22 

606 

37 

1,575 

660 

53 

72 

60 


327 
328 
147 

73 

129 

6 

12 
2,692 
609 
126 
172 
460 
216 

11 
605 

27 
124 


35 
203 
149 
6,120 
475 
171 
509 
739 
134 


54 

189 
340 


84 
140 

23 
552 

1,206 

614 

30 

101 

63 

7 

158 


1,000 
dollars 


510 
784 
132 


25 


2,090 
278 
116 
211 
502 
353 
25 
795 


81 
216 


106 
62 
566 


74 


209 
381 
4,099 
373 
159 
487 
639 
129 


644 

183 

1,168 


112 
353 
555 

111 
130 


1,565 


227 
160 
90 
630 

1,476 

1,562 

85 

184 

180 


See  footnotes  on  page  22. 


18 

TABLE  8A. -Syntheti 


UNITED  STATES  TARIFF  COMMISSION 


als:    Vniteri  States  product i 


ales  of  coal-tar  dyes,    J956- -Continued 


Dye 


Production 


Quantity 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBER--Continued 


Triphenylme thane   and  Diphenylnaphthylne  thane 
Dyes --Continued 


Naphthalene  green  V- 
V/ool  green  S 


1.000 
pounds 


Fluorescein 

Uranine  (Fluorescein,  alkali  salt)- 
Tetrabromofluorescein 


Quinoline  yellow- 


Thiazole  Dye 


Primuline 

Direct  fast  yellow - 


Anne   Dye 


Safranine 

Induline,  water-soluble- 


Methylene  blue- 


Sulfur 


Sulfide  Dye 


Total^ 


Sulfur  blaok-- 
Sulfur  maroon- 
Sulfur  ollve-- 
Sulfur  yellow- 
All  other 


Anthraqai 


Alizarin  VI 

Alizarin  red  S 

Acid  alizarin  blue  SE 

Acid  alizarin  blue  B 

Alizarin  irisol  R 

Alizarin  cyanine  green 

Anthraquinone  blue  black  B 

Acid  anthraquinone  sky  blue  B- 


Anthraqui 


Vat  Dyes 


Anthraquinone 
Anthraquinone 
Anthraquinone 
Vat  navy  blue 
Anthraqu  inone 
Anthraquinone 
Anthraquinone 
Anthraquinone 
Anthraquinone 
Anthraquinone 
Anthraquinone 
Anthraquinone 
Anthraquinone 
Anthraquinone 


vat  golden  orange  G,  12"^- 
vat  scarlet  G,  16-2/3'* — > 

vat  dark  blue  BO,  25^ 

NTP 


vat  jade  green,  6% 

vat  green  B  and  black  B,  12-1/2 ' 

vat  violet  2R,  12-1/2? 

vat  blue  RS,  10* 

vat  blue  GCS,  8-l/3°J 

vat  blue  GCD,  8-l/3^— 

vat  olive  R,  12-1/2?. 

vat  brown  R,  12-1/2^ - 

vat  brown  G,  12-1/2'J--- 

vat  violet  BN,  25^ 


Indigoid  and  Thioindigoid  Dyes 


Indigo,  synthetic,  20? — 
Bromindigo  blue  2BD,  !(/<,- 

Vat  red  3B,  20:fc — 

Vat  orange  R,  10^ 


Food,    Drug,  and  Cosmetic  Dye 
Total 

See  footnotes  on  page  22. 


1,879 


1.000 

pounds 


1,000 

dollars 

156 


104 
260 


81 
291 


16,811 

16,938 

l<i6 

167 

435 

278 

258 

8,407 

8,246 

35 
571 

23 
366 
104 


565 

222 

348 

330 

646 

627 

688 

625 

5,704 

6,268 

1,847 

2,113 

322 

288 

1,261 

881 

903 

2,368 

2,668 

1,286 

1,011 

1,152 

1,081 

670 

1,004 

143 

138 

9,442 

10,154 

580 

570 

1,710 


561 
28 


6,953 


3,738 
176 
120 
110 

2,309 


36 
126 

1,698 
119 

1,050 
252 
136 


461 
919 
1,306 
1,117 
4,129 
2,023 
578 

870 
3,344 
1,167 
1,814 
1,339 

801 


2,779 
495 

131 
592 


6,681 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


19 


TAHLE  8A. --SynfhetJ 


icals:   UniteH  States  product! 


7956--Continued 


Dye 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBER— Continued 
Food,    Drug,    and  Cosmetic   Dye5--Contlnued 

Food,  Drug,  and  Cosmetic  Colors 
Total 


Blue  #1— 
Blue  #2  — - 
Orange  #1- 

Red  #1 

Red  #2 

Red  #3 

Red  #4 

Yellow  #3- 
Yellow  #<.- 
Yellow  #5- 
Yellow  #6- 
All  other- 


Drug  and  Cosmetic  Colors 


Total- 
Orange  jfA- 

Red  #7 

Red  #9 

Red  #19  —  - 
Red  #21— 
Yellow  #5- 
All  other- 


All   Other  Dyes   Grouped   by  Colour   Indei  Numbe 

Total 

DYES  GROUPED  BY  PROTOTYPE  NUMBER 
Total 


Acid  alizarin  flavine  R 

Acid  anthracene  brown  PG 

Acid  chrome  blue  2R 

Algol  yellow  GO 

Alizarin  direct  blue  A2G 

Alizarin  supra  blue  A 

Anthracene  chromate  brown  EB — 

Artificial  silk  black  G 

Benzo  Bordeaux  6B 

Benzo  chrome  black  blue  B 

Benzo  copper  blue  B 

Benzo  fast  black  L 

Benzo  fast  blue  <iGL 

Benzo  red  12B 

Brilliant  benzo  violet  B 

Brilliant  wool  blue  FFR 

Celliton  orange  GR 

Chlorantine  fast  brown  BRL 

Chlorantine  fast  yellow  4GL 

Chlorantine  fast  yellow  RL 

Cibacete  sapphire  blue  G 

Diamine  Bordeaux  B 

Diamine  catechine  3G 

Diamine  fast  blue  FFB 

Diamine  fast  orange  EG 

Diamine  fast  orange  ER 

Diaminogen  blue  N2B 

Diazo  Bordeaux  7B 

Diazo  brilliant  green  3G 

Diaizo  brilliant  scarlet  2BL  ex- 

Diazo  brilliant  scarlet  ROA 

Diazo  fast  red  5BL 

Diazo  fast  red  7BL 

Fast  scarlet  2G  salt 

Guinea  carmine  B 

Guinea  fast  red  BL 

Helindon  pink  R  ex 

Indanthrene  brown  BR 

Indanthrene  brown  RRD 

Indanthrene  khaki  2G 


Production 


1,696 


171 
23 


402 

303 

84 


1,000 
pounds 

1,514 


10 
156 


16,033 


28,134 


,354 
27 
28 
130 


76 
271 
346 

22 
126 


24 

750 
607 
615 
947 


163 

156 

406 

26 

49 

29 

56 

288 

253 

55 


1,000 
dollars 
5,970 


14,828 


1,497 
20 
31 
161 
197 
15 
64 
41 
184 


441 
323 


125 
52 
166 


17 
126 
20 
32 
735 
631 
601 
920 


429 

452 
784 
1,285 
484 
208 
83 
167 
862 
790 
426 


12,576 


Unit 
value -"^ 


50,673 


2,112 
71 
145 
269 
198 
23 
106 
53 
322 
157 


$3.94 


13.00 

2.77 
5.03 
3.16 
18.62 
4.24 
2.86 
2.98 
2.93 
3.12 
7.75 


3.33 
2.09 
1.36 
4.50 

3.12 
1.78 


1.83 


1.50 
2.41 
1.56 
1.41 
3.55 
4.65 
1.67 
1.01 
1.53 
1.66 
1.29 
1.75 
2.66 
3.71 
2.24 


88 

1.47 

313 

.71 

576 

1.78 

22 

2.00 

331 

2.53 

77 

1.45 

75 

1.23 

203 

2.21 

254 

2.03 

103 

1.98 

321 

1.93 

57 

3.00 

51 

3.19 

208 

3.47 

60 

2.22 

22 

3.14 

49 

2.88 

93 

.74 

24 

1.20 

67 

2.09 

1,179 

1.60 

1,283 

2.03 

1,064 

1.77 

1,044 

1.13 

aee  footnotes  on  page  22. 


20  UNITED  STATES  TARIFF  COMMISSION 

TABLE   8A. -Synthetic  organic   chemicals:    United  States   production   and  sales   of  coal-tar   dyes,    1956--CnntLr 


Ctolour 
Index 

or 
proto- 
type 
No. 


Dye 


DYES  GROUPED  BY  PROTOTYPE  NUMBER- -Continued 


Indanthrene  rublne  R 

Milling  yellow  H5G 

Neolan  blue  GG 

Oxydiaminogen  OB 

Paper  red  A  ex 

Rapidogen  blue  D 

Rapidogen  Bordeaux  R 

Rapidogen  red  GS 

Rapidogen  red  RS 

Rapidogen  scarlet  RS 

Rapidogen  yellow  G 

Rosanthrene  fast  Bordeaux  2BL-- 

Rosanthrene  orange  R 

Sulphon  yellow  R 

Victoria  fast  violet  2R  ex 

Victoria  pure  blue  B 

Alizarin  fast  gray  BBLW 

Brilliant  indocyanine  G 

Celliton  fast  blue  FFR 

Celliton  fast  brown  3R 

Celliton  fast  pink  B 

Celliton  fast  pink  FF3B 

Celliton  fast  red  GG 

Celliton  fast  red  violet  RN 

Celliton  fast  rubine  B 

Celliton  fast  rubine  3B 

Celliton  fast  violet  6B 

Celliton  fast  yellow  G 

Celliton  scarlet  B 

Celliton  yellow  5G 

Chlorantine  fast  red  5BRL 

Diazo  fast  yellow  2G 

Fast  blue  BB  base 

Fast  Bordeaux  GP  base 

Fast  Bordeaux  GP  salt 

Fast  orange  GC  base 

Fast  orange  GC  salt 

Fast  orange  GR  salt 

Fast  red  XL   salt 

Fast  red  3GL  base 

Fast  red  3GL  salt 

Fast  red  KB  base 

Fast  red  KB  salt 

Fast  red  RC  base 

Fast  red  RC  salt 

Fast  red  TR  salt 

Sirius  supra  orange  GG 

Sirius  supra  turquoise  blue  GL-- 
Indanthrene  brilliant  violet  3B- 

Indanthrene  direct  black  RB 

Indanthrene  golden  orange  3G 

Indanthrene  golden  yellow  GK 

Indanthrene  golden  yellow  RK 

Indanthrene  olive  green  B 

Indanthrene  red  FEB- 

Monochrome  black  blue  G 

Naphthol  AS 

Naphthol  AS-BO-- 

Naphthol  AS-BR 

Naphthol  AS-BS 

Naphthol  AS-D - 

Naphthol  AS-G 

Naphthol  AS-OL - 

Naphthol  AS-RL 

Naphthol  AS-SW 

Neolan  orange  G 

Neolan  yellow  GR 

Palatine  fast  green  BLN 

Palatine  fast  marine  blue  REN 

Palatine  fast  pink  BN 

Palatine  fast  yellow  ELN 

Rapidogen  blue  N 

Rapidogen  brown  IPT 

Rapidogen  orange  R 

Rapidogen  violet  B 

Cotonerol 

Fast  red  ITR  salt 


Production 


236 
719 

150 


231 
102 
181 


311 
127 
22 

161 


31 
l'i2 


207 
122 


255 
702 

155 


307 
161 


217 
104 


52 

48 

602 

553 

73 

79 

365 

395 

495 

505 

497 

518 

85 

71 

383 

1,322 

269 

106 

867 

411 

27 

24 

12 

190 

100 

338 

266 

36 

12 

900 

21 


1.000 
dollars 
117 

25 
445 
810 
397 
195 

21 
369 
158 
394 
182 

27 
223 


380 
261 


780 
78 
233 


135 
499 
212 
60 
403 


29 
221 


143 
225 


82 

88 

1,445 

237 

779 

1,072 

1,044 

255 

1,426 

228 
660 


233 

421 

195 

111 

33 

923 

123 

105 

22 

43 

122 

89 

116 

412 

89 

46 

714 


See  footnotes  on  page  22. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


21 


TARLE  SA.-Syntheti 


chemicals:    United  States   rrodiiction   and  sales   of  coal-tar   dyes,    J956- -Cont  inueH 


Production 


Quantity 


DYES  GROUPED  BY  PROTOTYPE  NUMBER- -Continued 

Sirius  supra  gray  VOL 

Indanthrene  orange  <iR 

Chlorantine  fast  red  6BLL 

Chlorantine  fast  violet  5BL 

Chlorazol  blue  5GKS ■ 

Sirius  light  blue  FBGL ■ 

Chlorantine  fast  violet  2RL 

Fast  red  PDC  base 

Fast  red  PDC  salt 

Indanthrene  red  violet  RRN 

Naphthol  AS-LG 

Gellitazol  AZN 

Chrome  fast  green  G 

Direct  chinoline 

Eastman  fast  yellow  GLF 

Indanthrene  olive  T 

Naphthol  AS-MX 

Naphthol  AS-PH - 

Pontamlne  black  AWG 

Pontamlne  navy  blue  DB 

Solantine  orange  4-G 

Sirius  supra  yellow  R  ex 

Superlite  fast  blue  8GLN 

Superlite  fast  blue  RL 

All  other  dyes  grouped  by  prototype  number 

UNGROUPED  DYES 

Total 

Acetate  rayon  dyes,  total  (see  table  10  for  total  of 

all  acetate  rayon  dyes)* 

Black,  B,  EC,  3G,  GGN,  GS,  GY,  JRW,  LNB,  MPB,  NC,  . 
PL,  RB,  SS' - 

Blue  A8-7,  AS-<i5,  B,  2B,  BG,  CR,  FSI,  G,  2G,  GBN, 
GFD,  3G-GFD,  5G-GFD,  GLF,  GLT,  GP,  GR,  GSF, 
GSFR,  GSS,  LWGF,  MJ,  NBN,  NBNJ,  NSP,  2R,  A-R, 
RB,  RBN,  3RL,  SS,  WNBN^ - 

Navy  blue  BP,  BR,  Direct,  EC,  LB,  MG,  NVY,  R,  RG--- 

Red  VI-X,  B,  2B,  3B,  2B-GLF,  <iBLL,  C,  FSI,  G,  GLF, 
GSF,  NB,  N-GLF,  R,  RP,  Y,  YP' 

Scarlet  III,  B,  FS,  GSF 

Yellow  IX,  XI,  #91,  CW,  FSI,  3G,  5G,  8-GLF,  GR,  M, 
N,  R,  5R,  R-GFD,  2R-GLF,  4.RL,  ABIA,   AKLF,   RN, 
W-GLF,  YL^-- 

All  other  acetate  rayon  dyes 

Acid  black  AR,  4B,  GRF,  N,  NRB,  RB 

Acid  blue,  B,  BRL,  G,  L,  NB,  R 

Acid  brown  BL,  CRTA,  ITGA,  M-130,  NY,  PGMA,  RD,  2RL-- 

Acid  orange  R,  2R,  RL 

Acid  violet  BD,  R,  2R,  3RL,  RNL 

Azoic  dyes  and  their  components,  total  (see  table  10 

and  table  lA   for  data  on  all  azoic  dyes  and  their 

components)' 

Chrome  yellow  2GN,  GRR,  SW 

Direct  black  CW,  5G,  3GR,  HH,  NV,  20B,  RCW,  SBJ 

Direct  brown  #230,  BY,  CH,  DB,  DW,  FF,  GB,  3GS,  KRS, 

R,  RB,  4RL,  RRF,  RRK,  RY 

Direct  fast  blue  BFL,  BLL,  BRN,  CPL,  8G,  4GLR,  LBFU, 

LBGL,  LBL,  LBR,  L5GA,  L5R,  ML,  NPC,  RL,  3RL,  UGLL-- 
Direct  fast  brown  BCL,  CS,  LBT,  LLC,  R,  ■iR,  RL,  2RL, 

-iRL,  RLL,  SKRL,  3YL 

Direct  fast  gray  #3^749,  BL,  GL,  2GL,  3GL,  LBUL, 

LGL,  LWBG — 

Direct  fast  orange  2GL,  L8GL,  LWF,  3LWF,  NAR,  R 

Direct  fast  yellow  EFC,  5G,  AGLP,  LLR,  L-2RX 

Direct  green  FFW,  5GSC,  Y -- — 

Direct  white,  B,  <;b,  CN,  DPS,  DS-86,  GG,  GO,  HS-76, 

K,  LD,  MR,  M2R,  P-iB,  2R,  RN,  RW,  RWS,  SB,  SC, 

WANS,  WCN - 

Oil  blue  A,  AP,  NE - 

Oil  red,  ED,  EGN,  N-1700,  0,  OB,  RO 

All  other  ungrouped  dyes 


1,000 

1,000 

1,000 

pounds 

pounds 

dollars 

8 

14 

3A 

47 

165 

112 

117 

269 

9 

29 

152 

165 

228 

213 

193 

298 

76 

81 

172 

81 

82 

210 

269 

253 

400 

149 

123 

138 

28 

29 

126 

894 

1,030 

792 

30 

18 

24 

169 

41 

74 

110 

1,380 

1,282 

1,629 

24 

15 

31 

202 

183 

209 

33 

32 

35 

50 

56 

77 

59 

67 

172 

222 

211 

462 

44 

77 

57 

66 

114 

6,283 

5,687 

14,629 

14,585 


2,080 


1,057 


139 
273 


1,359 


3,635 

38 

591 

6,423 


14,896 


1,172 


180 
204 


3,477 


600 
6,576 


4,661 


2,548 
126 


380 

440 


2,899 
8 
67 


126 
28 


10,415 
194 


See  footnotes  on  page  22. 


22  UNITED  STATES  TARIFF  COMMISSION 

Fnntnotps    fnr    table    !>A 

^   Calculated  on  rounded  figures. 

^  Does  not  include  derivatives  of  carbazole  (Colour  Index  Nos.  948,  969). 

^  Includes  drug  and  cosmetic  colors,  external,  data  on  which  cannot  be  published  separately  without  dis- 
closing information  received  in  confidence. 

^  Excludes  acetate  rayon  dyes  that  appear  under  "Dyes  grouped  by  prototype  number." 

'  Includes  developed  black,  diazo  black,  and  printing  black. 

*  Includes  brilliant  blue,  fast  blue,  and  violet  blue. 

'  Includes  rubine. 

'  Includes  fast  yellow,  golden  yellow,  and  printing  yellow. 

'  Does  not  include  azoic  dyes  and  their  components  that  appear  under  "Dyes  grouped  by  Colour  Index  number" 
and  "Dyes  grouped  by  prototype  number. " 

Production  of  dyes  grouped  by  Colour  Index  number  ^vas   109  mil- 
lion pounds  in  1956,    compared  with  an  output  of  119  million  pounds 
in  1955- -representing  a  decline  of  8.  5  percent.    Sales  of  Colour 
Index  dyes  totaled   112  million  pounds,    valued  at  99  million  dollars, 
in   1956,    compared  with   111   million  pounds,    valued  at  97  million 
dollars,    in   1955--an  increase  of  0.8  percent  in  quantity  and  2.4 
percent  in  value.    Production  and  sales  of  prototype  dyes  showed  the 
greatest  declines.    The  output  of  prototype  dyes  in  1956  was  28  mil- 
lion pounds,    or  15.0  percent  less  than  the  33  million  pounds  pro- 
duced in  1955.    Sales  of  these  dyes  in  1956  totaled  28  million  pounds, 
valued  at  51   million  dollars,    compared  with  sales  in  1955  of  30  mil- 
lion pounds,    valued  at  54  million  dollars- -representing  a  decline  of 
8.  9  percent  in  quantity  and  5.  5  percent  in  value.    Production  of  un- 
grouped  dyes  in  1956  totaled  15  million  pounds,    or  8.  5  percent  less 
than  the   16  million  pounds  produced  in  1955.    Sales  of  these  dyes 
amounted  to  15  million  pounds,    valued  at  36  million  dollars,    in 
1956,    compared  with  15  million  pounds,    valued  at  33  million  dollars, 
in   1955--showing  an  increase  of  2.  5  percent  in  quantity  and  7.  4  per- 
cent in  value . 

Among  the  individual  dyes  for  which  statistics  are  given  in  this 
report,    substantial  increases  in  production  were   reported  for  many 
low^-  and  medium-priced  dyes.    The  output  of  sulfur  black  was   16.8 
million  pounds  in   1956,    compared  with   16.  3  million  pounds  in  1955 
and  11.5  million  pounds  in  1954;  that  of  direct  white  dyes  was  3.6 
million  pounds  in  1956,    compared  with  3.  1  million  pounds  in  1955 
and  1.4  million  pounds  in  1954.    The  increase  in  output  between 

1955  and  1956  for  acid  black  lOB  (C.  I.    dye  246)  was  23.  2  percent; 
the  increase  for  indanthrene  olive  T  (Pr.    dye  547)  was   18.6  percent; 
and  that  for  Sudan  I  (C.  I.    dye  24)  was  18.  1   percent. 

On  the  other  hand,    production  of  many  important  dyes  was 
smaller  in   1956  than  in  1955.    The  output  of  synthetic   indigo  in  1956 
was  9.  4  million  pounds,    or   24.  6  percent  less  than  the   12.5  million 
pounds  reported  for   1955;  that  of  direct  black  EW  (C.  I.    dye  581) 
was   5.4  million  pounds,    or   11.6  percent  less  than  the  6.  1   nnillion 
pounds  reported  for  1955.    The  decline  in  output  between  1955  and 

1956  for  chrome  blue  black  R  (C.  I.    dye   202)  was  70.  1   percent;  that 
for  indanthrene  brown  BR  (Pr.    dye    1  18)  was  44.  0  percent;  that  for 
anthraquinone  vat  green  B  and  black  B  (C.  I.    dye   1102),    was  37.  1 
percent;  and  that  for  algol  yellow  GC  (Pr.    dye  9),    was  35.  0  percent. 

Table  9  shows  production  and  sales  of  dyes  in  1956,    by  chemical 
class.    Four  chemical  classes  of  dyes  accounted  for  82.  2  percent  of 
the  total  quantity  of  dyes  produced  in  1956.    Azo  dyes  accounted  for 
33.7  percent  of  the  total;  anthraquinone  vat  dyes,    for   19.  1  percent; 
sulfur  or  sulfide  dyes,    for   21.  2  percent;  and  indigoid  and  thioindigoid 
dyes,    for  8.  2  percent.    The  output  of  all  these  dyes,    except  sulfur 
dyes,    was  smaller  in   1956  than  in  1955.    Production  of  anthraquinone 
vat  dyes  declined  26.6  percent;  indigoid  and  thioindigoid  dyes,    20.8 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


23 


percent;  and  azo  dyes,    14.  5  percent.    The  putput  of  sulfur  dyes,    on 
the  other  hand,    increased  25.8  percent. 

Table    10  shows  the  average  annual  production  of  dyes  in  the  5 
years   1950-54,    together  with  annual  data  for   1955  and  1956,    by  class 
of  application.    Table   11  gives  corresponding  data  for  sales.    Two 


TABLE  9.--Syntheti 


rganic  chemicals:   United  States 


proriih 
1956 


■tion  and  sales  of  coal- tar  dyes ,  by  chemical  class, 


Chemical  class 


Quantity 


Unit 
value  ■"■ 


.  Total - 

Azo 

Sulfur  or  sulfide^ 

Anthraquinone  vat^ 

Indigoid  and  thioindigoid 

Triphenylmethane  and  diphenylnaphthylmethane- 

Anthraqulnone 

Stilbene 

Pyrazolone 

Phthalocyanine 

Xanthene 

Ketonimine 

Thiazole 

Thiazine 

Quinoline 

Acridlne 

All  other* 


1.000 
pounds 

151,575 


1,000 


154,  S-i? 


1,000 
dollars 

185, iA3 


pound 
$1.20 


50,977 

32,160 

28,920 

12,'i98 

5,778 

5,736 

5,360 

1,486 

763 

732 

670 

410 

280 

256 

84 

5,465 


54,317 

32,627 

28,576 

13,124 

4,411 

5,915 

5,365 

1,315 

692 

662 

798 

419 

344 

250 

67 

5,665 


77,517 

8,910 

39,880 

6,933 

9,028 

12,706 

12,759 

3,093 

2,149 

2,609 

1,565 

805 

601 

894 

163 

5,831 


1.43 

.27 

1.40 


•'^  Calculated  on  rounded  figures. 

^  Colour  Index  dyes  only. 

^  Includes  carbazole  vat  dyes. 

*  Includes  azine,  oxazine,  and  sulfur  dyes  not  included  in  Colour  Index  group,  and  miscellaneous,  dyes. 
Statistics  for  these  groups  cannot  be  published  separately  without  disclosing  information  received  in  confi- 
dence. 


TARU^  10. -Syntheti 


rganic   chemicals 


United  States  product io 
6e    1950-54,    annual    1955 


jf  coal-ta 
1  1956 


dyes,    by  cla 


,f  appli 


Class  of  application 


Average 
1950-54 


Quantity  (1,000  pounds) 


Total— -- 

Acetate  rayon 

Acid 

Azoic 

Basic 

Direct 

Lake  and  spirit-soluble- 

Xfcirdant  and  chrome 

Sulfur 

Vat,  total - 

Indigo 

All  other 

All  other  coal-tar  dyes- 
Total 

Acetate  rayon 

Acid 

Azoic 

Basic 

Direct 

Lake  and  spirit-soluble- 

Kordant  and  chrome 

Sulfur 

Vat,  total 

Indigo 

All  other 

All  other  coal-tar  dyes- 


167,358 


6,869 

16,020 

8,375 

7,655 

32,491 

5,956 

5,117 

21,850 

59,882 


18,559 
41,323 


168,005 


5,737 
14,918 
8,983 
8,790 
32,437 
7,031 
6,376 
25,572 

55.300 


12,518 
42,782 


151,575 


5,129 

13,460 

8,073 

8,076 

29,720 

6,856 

4,147 

25,642 

47,969 


9,442 
38,527 


2,503 


Percent  of  total  quantity 


4.1 

3.4 

9.6 

8.9 

5.0 

5.4 

4.6 

5.2 

L9.4 

19.3 

3.6 

4.2 

11.1 

24.7 


7.5 
25.4 


25.4 

1.8 


24 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  n.--Syntheti 


United  States   sales  of  coal- tar  dyes,    by  class  of  applicat i 
erage   1950-54,    annual    1955  and  1956 


Class  of  application 


Quantity  (1,000  pounds) 


Total 

Acetate  rayon 

Acid 

Azoic 

Basic 

Direct 

Lake  and  splrit-soluble- 

Mordant  and  chrome 

Sulfur 

Vat,  total 

Indigo 

All  other 

All  other  coal-tar  dyes- 


Total- 

Acetate  rayon 

Acid 

Azoic 

Basic 

Direct 

Lake  and  spirit-soluble- 

Mordant  and  chrome 

Sulfur 

Vat,  total 

Indigo 

All  other 

All  other  coal-tar  dyes- 


Total 

Acetate  rayon 

Acid 

Azoic 

Basic 

Direct 

Lake  and  spirit-soluble- 

Mordant  and  chrome 

Sulfur 

Vat,  total 

Indigo 

All  other 

All  other  coal-tar  dyes- 


Total 

Acetate  rayon 

Acid 

Azoic 

Basic 

Direct 

Lake  and  spirit-soluble- 

Mordant  and  chrome 

Sulfur 

Vat,  total - 

Indigo 

All  other 

All  other  coal-tar  dyes- 


157,223 


6,528 

1^,363 

7,116 

6,88i 

31,686 

5,602 

5,052 

21,897 

55,196 


18,266 
36,930 


2,899 


155,9 


5,337 

U,185 

7,937 

7,666 

31,106 

6,725 

5,803 

25,401 

49,311 


11,566 
37,745 


2,509 


154, 547 


5,550 

14,449 

7,014 

7,085 

32,030 

6,777 

5,046 

26,044 

48,305 


10,154 
38,151 


2,247 


Percent  of  total  quantity 


4.2 
9.1 
4.5 
4.4 

20.2 
3.6 
3.2 

13.9 


7.4 
24.2 


3.6 
9.3 
4.5 
4.6 

20.7 
4.4 
3.3 

16.9 

31.2 
6.6 


Value  (1,000  dollars) 


173,198 


10,206 

18,233 

13,641 

10,743 

38,454 

5,884 

5,764 

6,865 

55,790 


4,662 
51,128 


7,618 


183,628 


9,729 

20,429 

14,179 

13,928 

44,469 

7,672 

7,284 

6,639 

52,179 


3,327 
48,852 


7,120 


185,443 


9,861 

22,226 

13,558 

13,766 

47,993 

8,510 

6,502 

6,953 

48,897 


2,779 
46,118 


7,177 


Percent  of  total  value 


6.2 
22.2 

3.4 


7.7 
7.6 
24.2 
4.2 
4.0 
3.6 

28.4 


7.4 
25.9 
4.6 


SYNTHETIC  ORGANIC   CHEMICALS,  1956 


25 


classes  of  dyes  accounted  for  more  than  half  the  total  output  of  all 
dyes  in  1956;  vat  dyes  accounted  for  31.6  percent  of  the  total,    and 
direct  dyes,    for   19.6  percent.    The  output  of  both  classes  of  dyes 
was  smaller  in   1956  than  in  1955;  production  of  vat  dyes  declined 
1  3.  3  percent  and  that  of  direct  dyes,    8.4  percent.    Compared  with 
the   1950-54  average,    the  output  of  only  sulfur  dyes  was  greater  in 
1956  (17.4  percent).    The  output  of  each  of  the   remaining  large 
groups  of  dyes  in   1956  was   smaller;  that  of  the  vat  dyes  in  1956  was 
19.9  percent  smaller  than  the  annual  average  for   1950-54;  acid 
dyes,    16.  0  percent  smaller;   and  direct  dyes,    8.  5  percent. 

Production  and  sales  of  ungrouped  dyes  (those  having  neither  a 
Colour  Index  nor  a  prototype  number)  are   shown  by  chemical  class 
in  table   12  and  by  class  of  application  in  table   13.    Three  chennical 
classes  of  ungrouped  dyes  accounted  for  84.  5  percent  of  the  total 
output  of  these  dyes  in  1956.    Azo  dyes  accounted  for  41.  1   percent 
of  the  total  output;   stilbene  dyes,    for  25.  7  percent;  and  anthraquinone 
vat  dyes,    for  17.7  percent.    The  output  of  stilbene  dyes  was   16.4 
percent  larger  in  1956  than  it  was  in  1955;  on  the  other  hand,    the 
output  of  ungrouped  anthraquinone  vat  dyes  was   15.4  percent  smaller 
and  that  of  azo  dyes  was  2.  0  percent  smaller.    For  ungrouped  dyes 
arranged  by  class  of  application,    three  classes  of  dyes  accounted 
for  72.  3  percent  of  the  total  output  of  these  dyes:  Direct  dyes  ac- 
counted for  39.6  percent,    vat  dyes,    for  18.4  percent,    and  acetate 
rayon  dyes,    for  14.  3  percent.    The  output  of  all  three  of  these 
classes  was  smaller  in  1956  than  in   1955;  production  of  ungrouped 


TABLE  12-  -Synthetic  orga 


chemicals:    United  States   production  and  sale 
chemical   class,    1956 


of  ungrouped  dyes,    by 


Chemical  class 


Production 


Quantity 


Total 

Anthraquinone 

Anthraquinone  vat 

Azo 

Stilbene 

Triphenylmethane  and  diphenylnaphthylmethane- 
All  other^— - 


U,585 


14, e 


1,000 
dollars 
35,521 


$2.38 


1,787 
2,586 
6,001 
3,742 
8 
461 


1,810 
2,798 
6,234 
3,576 

478 


3,984 

6,185 

13,047 

10,568 

1,737 


2.20 
2.21 
2.09 
2.81 

3.63 


Calculated  on  rounded  figures, 
^  Includes  sulfur,   indigoid  and  thioindigoid,   triphenylmethane   (sales),  pyrazolone,   xanthene,   acridine, 
quinoline,   and  miscellaneous  dyes. 


TABLF    13. -Synthetic   organic   chemicals:    United  States   production   and  sales   of  ungrouped  dyes,    by  class   of 

application,    1956 


Class  of  application 


Quantity 


Unit 
value "'" 


po 


Total 

Acetate  rayon 

Acid 

Azoic 

Direct 

Lake  and  spirit -soluble- 

Mordant  and  chrome 

Vat 

All  other^ 


1,000 
mds 

14,585 


1,000 
pounds 

14,896 


1,000 
dollars 

35,521 


2,080 

692 

1,359 

5,792 

1,356 

61 

2,680 

565 


2,374 
788 
1,275 
5,640 
1,333 


4,661 
1,735 
2,899 
14,771 
2,960 
154 
6,487 
1,854 


$2.38 


1.96 
2.20 
2.27 
2.62 
2.22 
2.33 
2.25 
3.43 


^   Calculated  on  rounded  figures. 

^  Includes  basic,  sulfur,  and  miscellaneous  dyes. 


26  UNITED  STATES  TARIFF  COMMISSION 

vat  dyes  declined  25.  1  percent,    acetate  dyes,    20.  2  percent,    and 
direct  dyes,    2.9  percent. 

Table   14  shows  production  and  sales  of  azoic  dyes  and  their 
components  in  1956.    The  output  of  these  products  totaled  8.  1  mil- 
lion pounds,    or  9.  7  percent  less  than  the  8.  9  million  pounds  pro- 
duced in  1955.   Sales  of  these  products  were  7.  0  million  pounds, 
valued  at  13.6  million  dollars,    in  1956,    compared  with  7.9  million 
pounds,    valued  at  14.  2  million  dollars,    in  1955--showing  a  decline 
of  11.6  percent  in  quantity  and  4.4  percent  in  value.    Except  for  the 
Rapidogens  - -production  of  which  was  0.8  percent  higher  in   1956 
than  in  1955--the  output  of  the  remaining  three  groups  was  smaller 
in  1956  than  in  1955;  the  output  of  fast  color  salts  declined  17.  9 
percent,    that  of  Naphthols,    7.9  percent,    and  that  of  fast  color  bases, 
7.  7  percent. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


27 


TABLE    lA. -Synthetic  organic   chemicals 


Uni  ted  States  product  i 
1956 


dyes  and  their  components t 


Dye  or  component 


Produc- 
tion 


Quantity 


Grand  total^ 

Dyes  and  components  for  which  separate  statistics  may 
not  be  shown^ 

Dyes  and  components  for  which  separate  statistics  are 
shown  below 

DTES 

Rapidogen,  total 

Black 

Blue  D 

Blue  N 

Blue,  other^ 

Bordeaux  R 

Brown  IPT 

Orange  R 

Red  OS 

Red  RS 

Red,  other 

Scarlet  RS 

Violet  B 

Yellow  G 

Yellow,  other 

COMPONENTS 

Fast  color  bases,  total 

Blue  B 

Blue  BE 

Bordeaux  GP 

Orange  GC 

Red  GL— - 

Red  3GL 

Red  KB 

Red  PDC 

Red  RC 

Scarlet  R 

All  other 

Fast  color  salts,  total 

Blue  B 

Bordeaux  GP 

Orange  GC 

Orange  W. 

Red  AL 

Red  B 

Red  GL 

Red  3GL 

Red  ITR 

Red  KB —  - 

Red  PDC 

Red  RC 

Red  TR - 

Red,  other 

Scarlet  2G 

Scarlet  R 

All  other 

Naphthols,  total 

Naphthol  AS 

Naphthol  AS-BO 

Naphthol  AS-BR 

Naphthol  AS-BS 

Naphthol  AS-D 

Naphthol  AS-G 

Naphthol  AS-LG— 

Naphthol  AS-MX 

Naphthol  AS-OL 

Naphthol  AS-PH 

Naphthol  AS-RL -- 

Naphthol  AS-SW- 

All  other 


8,073 


180 
7,893 


1,812 


668 
92 


231 
102 
U2 
181 


116 
18 


122 

81 


179 


2,195 


120 
852 
101 

2,902 


867 


190 
338 


731 


1,000 
pounds 

7,014 


1,000 

dollars 

13,558 


172 
6,842 


1,771 


546 
13,012 


4,150 


657 
97 
60 

102 
10 


124 
175 


1,641 
195 
116 
193 

21 
412 

89 
369 
158 
283 
394 

46 
182 


1,308 


129 
12 


35 
27 
104 
82 
9 
161 
337 


21 
225 
210 
■  25 
196 
275 

2,476 


34 
142 
130 


126 
764 
131 

1,993 


29 
221 
134 

87 
143 

72 

24 
400 

12 

82 
124 

93 
569 
332 

5,078 


12 
100 
266 


40 
183 


438 

417 


660 

54 

41 

233 

421 

195 

126 

31 

111 

209 

33 

923 

2,041 


Calculated  on  rounded  figures. 
^  Totals  shown  represent  all  azoic  dyes  and  their  components.  Totals  shown  in  tables  8A  and  13  represent 
ungrouped  dyes  and  their  components  only. 

^  Includes  rapid  fast  dyes,  fur  dyes,  and  "all  other"  rapidogen  dyes. 
*  Includes  navy  blue. 
'  Colour  Index  number. 


28 


UNITED  STATES  TARIFF  COMMISSION 

Toners  and  Lakes 


As  the  terms  are  used  in  this  report,    toners  and  lakes  are   syn- 
thetic organic  pigments.    Statistics  on  production  and  sales  of  all 
toners  and  lakes  are  given  in  table   15A.'    Statistics  on  the  commer- 
cial forms  of  a  few  selected  pignnents  (dry,    flushed,    pulp,    or  dis- 
persed) are  given  in  table  16.    Wherever  possible,    individual  toners 
and  lakes  are  identified  by  their  Colour  Index  or  prototype  number, 
by  the  Colour  Index  or  prototype  number  of  the  dye  from  which  they 
may  be  made,    or  by  abbreviations  indicating  the  intermediates  used 
in  their  manufacture. 

Synthetic  organic  pigments  are  used  in  paints  and  related  prod- 
ucts,   in  printing  inks,    and  in  plastics  and  resin  materials.    Toners 
are  full-strength  pigments;  reduced  toners  and  lakes  are  extended 
or  diluted  colors. 

The  total  output  of  full-strength  toners,    reduced  toners,    and 
lakes  was  41.  0  million  pounds  in  1956,    or  7.  8  percent  less  than  the 
44.  5  million  pounds   reported  for   1955,    but  slightly  more  than  the 
40.  0  million  pounds  reported  for  1954.    Sales  amounted  to  33.  1  mil- 
lion pounds,    valued  at  57.8  million  dollars,    in  1956,    compared  with 
38.  0  million  pounds,    valued  at  64.  3  million  dollars,    in  1955--a 
decline  of  13.  1  percent  in  quantity  and  10.  1  percent  in  value. 


TABLE    \5A.--Syntheti 


chemicals:    United  States   prortuction   anti  sales   of   toners   and  lake 


1956 


[Listed  below  are  all  toners  and  lakes  for  which  any  reported  data  on  production  or  sales  may  be  published. 
(Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no 
data  are  reported. )  Table  15B  in  part  III  lists  all  toners  and  lakes  for  which  data  on  production  or  sales 
were  reported  and  identifies  the  manufacturer  of  each] 


Production 


Quantity 


Unit 
value'' 


Grand  total 

TONERS  OR  FULL-STREKJTH  COLORS 

Total—- — - - 

Black  toners 

Blue  toners,  total 

Alkali  blue,  C.I.  704 - - - 

Phthalocyanine  blue  B  (alpha  modification),   Pr.   <i81 

Setoglaucine  (Peacock  blue  G)  (C.I.  658),  PMA 

Setoglaucine  (Peacock  blue  G)  (C.I.  658),  PTA 

Victoria  blue  B   (C.I.    729),    HJA  and  PTA 

Victoria  pure  blue  B   (Pr.   198),   BJIA 

Victoria  pure  blue  B  (Pr.  198),  PTA 

All  other 

Brown  toners 

Green  toners,  total 

Brilliant  green  (C.I.  662),  IMA — - 

Brilliant  green  (C.I.  662)  and  thioflavine  (C.I.  815),  FMA- 
Brilliant  green  (C.I.  662)  and  thioflavine  (C.I.  815),  PTA- 

Malachite  green  (C.I.  657),  PTA 

Phthalocyanine  green,  Pr.  483 

Pigment  green  B,  Pr.  149 

All  other 

Maroon  toners,  total 

B.O.N,  maroon  (Lithol  maroon)  (Tobias  acid  and  ton) 

Toluidine  maroon  (Naphthol  AS-BS  and  mnpt) 

All  other 

See  footnotes  at  end  of  table. 


1,000 
<ounds 
40,992 


28,532 


2,273 


20 
101 


30 
450 


2,279 


1,744 
373 


1,000 
pounds 
33,066 


1,000 
dollars 
57,788 


22,396 


34 
2,944 


932 
1,453 


29 
362 


2,040 


343 
1,590 


45,685 


8,900 


2,107 

4,560 

19 

100 

404 

217 

149 

1,344 

291 

6,843 


31 
181 
297 


454 
5,811 


2,688 


257 

113 

2,318 


$1.75 


1.47 


3.02 
2.26 
3.14 
4.75 


4.34 
4.02 


3.35 
3.87 
5.32 


3.65 


4.01 
1.66 
3.77 
4.78 


3 See  also  table  15B,  part  III,  which  lists  these  products  alphabetically  and  identifies  the  manu- 
facturers. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 

TAHLE  ISA.  - -.Synthetic  organic  chemicals:    United  States   production  and  sales  of   toners   and  lakes, 

1956'- Cont  inued 


29 


Production 


Quantity     Value    ^^^i 


TONERS  OR  FULL-STREN3TH  COLORS- -Continued 

Orange  toners,  total 

Benzidine  orange  (dob  and  pup) 

Dianisidine  orange  (dianisidine  and  aaa  or  aaot) 

2,A-Dinitroaniline  orange  (dna  and  bn) 

o-Nitroaniline  orange  (ona  and  bn) 

All  other 

Red  toners,  total 

o-Chloro-p-nitroaniline  red  (Chlorinated  para  red)  (ocpna 

and  bn) 

Eosine  (Bromo  acid  toner)  (C.I.  76S) 

Lithol  red  2G  (C.I.  166) - 

Lithol  red  R,  C.I.  189,  total 

Barium  toner 

Calcium  toner 

Sodium  and  other  toners 

Lithol  rubine  B  (C.I.  163) 

Naphthol  reds,  total 

Naphthol  AS  (Pr.  302)  and  dca 

Naphthol  AS  (Pr.  302)  and  pnot— 

Naphthol  AS-BS  (Pr.  305)  and  pnoa 

Naphthol  AS-D  (Pr.  306)  and  pnot 

Naphthol  reds,  other 

Para  red,  light,  C.I.  44 

Para  red,  dark 

Permanent  red  2B  (Pr.  563) 

Pyrazolone  red 

Red  lake  C,  C.I.  165 

Rhodamine  B  (C.I.  749),  IMA 

Rhodamine  B  (C.I.  749),  FTA 

Rhodamine  6G  (Rhodamine  6GDN)  (Rhodamine  Y)  (C.I.  752),  FMA- 
Rhodamine  6G  (Rhodamine  6GDN)  (Rhodamine  Y)  (C.I.  752),  PTA- 

Toluidine  red,  C.I.  69 

All  other 

Violet  toners,  total 

Methyl  violet  B  (C.I.  680),  fugitive 

Methyl  violet  B  (C.I.  680),  IMA 

Ail  other 

Yellow  toners,   total 

Benzidine  yellow  (deb  and  aaa) 

Benzidine  yellow   (deb  and  aaot) 

Hansa  yellov/s,   total 

Hansa  yellow  G,   Pr.   103 

Hansa  yellow  5G,   Pr.   104 

Hansa  yellow  lOG,    Pr.    105 

Hansa  yellow,   other 

All  other 


pounds 


1.000 
dollars 

818 


116 
162 


16,219 


105 
146 


13,110 


213 
277 
215 
82 


18,714 


546 

1,386 

187 

5,381 

3,282 

1,575 

524 

688 

500 

56 

109 

98 

115 

122 

734 

388 

1,398 

189 

1,322 

16 

23 


2,671 
635 


346 
335 
158 

3,927 


340 

159 

4,715 

2,760 

1,432 

523 

772 

343 

51 

104 

89 

67 

32 

610 

329 

1,387 

157 

973 

12 

21 


2,196 
989 


676 

~23T 

250 

139 


431 

232 

4,388 

2,534 

1,348 

506 

1,066 

1,109 

144 

285 

318 

223 

139 

653 

359 

2,554 

624 

1,347 

63 

131 

279 

345 

3,572 

1,561 

1,396 


1,655 
744 

1,246 
773 
17 
159 
297 
282 


2,438 
§37" 
563 
915 
600 
19 
110 
186 
123 


422 
652 
322 

5,985 


1,< 

1,337 

2,427 

1,367 

39 

251 

770 

352 


Production 


Toner 
content 


Quantity 


REDUCED  OR  EXTENDED  TONERS 
Total— - 

Products  for  which  separate  statistics  may  not  be 
shown^ 

Products  for  which  separate  statistics  are  shovni 
belov/ 

Black  toners,  reduced:  Basic  black 

Blue  toners,  reduced,  total 

Peacock  blue  R  (C.I.  664),  IMA— - 

Phthalocyanine  blue  B  (alpha  modification), 

Pr.  481 

Setoglaucine  (Peacock  blue  G)  (C.I-:  658),  PMA--- 

Victoria  blue  B  (C.I.  729),  fugitive 

All  other 


1,000 
pounds 

7,278 


1,873 


1,000 
pounds 

7,018 


8,829 


121 
7,157 


1,332 


127 
6,891 


8,735 


2,091 


1,978 


12 


1,500 


10 
556 


1,430 


2,144 
21 


See  footnotes  at  end  of  table. 


30 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  ISA. --Syntheti 


United  States  produ 
7956 --Continued 


Toner 

content 


Quantity 


REDUCED  OR  EXTENDED  TOKEHS- -Continued 
Brown  toners,  reduced 

Green  toners,  reduced,  total 

Brilliant  green  (C.I.  662),  BtA 

Brilliant  green  (C.I.  662)  and  thioflavine  (C.I 

815),  IMA—- - 

Brilliant  green  (C.I.  662)  and  thioflavine  (C.I 

815),  PTA - 

Pigment  green  B,   Pr.   K9 

All  other 

Orange  toners,  reduced,  total 

o-Nitroaniline  orange  (ona  and  bn) 

All  other 

Red  toners,  reduced,  total 

Eosine  (Bromo  acid  toner)  (C.I.  768) 

Lithol  red  R,  C.I.  189 

Lithol  rubine  B  (C.I.  163)— 

Naphthol  reds,  total 

Naphthol  AS-BS  (Pr.  305)  and  pnoa 

Naphthol  reds,  other 

Para  red,  light,  C.I.  ^ 

Para  red,  dark 

Permanent  red  2B  (Pr.  563) 

Rhodamine  B  (C.I.  74.9),  IMA,  PTA,  and  fugitive- 
Rhodamine  6G  (Rhodamine  6GDN)  (Rhodamine  Y) 

(C.I.  752),  mk - 

Rhodamine  6G  (Rhodamine  6GDN)  (Rhodamine  Y) 

(C.I.  752),  PTA — - 

Toluldine  red,  C.I.  69 --- 

All  other 

Violet  toners,  reduced,  total 

Ethyl  violet  (C.I.  682),  BIA  and  PTA 

Methyl  violet  B  (C.I.  680),  fugitive 

Methyl  violet  B  (C.I.  680),  BAA 

All  other 

Yellow  toners,  reduced: 

Benzidine  yellow  (deb  and  aaa) 

Benzidine  yellow  (deb  and  aaot) 

Hansa  yellows 


1,000 


1,508 


1,000 
pounds 


1,000 
dollars 


1,488 


2,070 


10 

360 

1,065 


62 
330 


366 
1,037 


29 


197 
1,713 


1,765 

3" 

198 

42 
600 
336 
264 

18 

39 
395 

81 


39 

115 


1,701 


1,626 


621 
346 
275 
18 
38 
363 


38 
123 


213 
38 


69 
187 
592 


122 
27 
34 


508 
83 

216 
37 


130 
577 


42 
523 

277 

246 

4 

10 

557 


132 

32 
78 
88 

1,207 


"65§" 
95 
208 
246 


119 
105 
344 


Production 


Quantity 


LAKES  OR  LAKED  COLORS 
Total 

Products  for  which  separate  statistics  may  not  be  shovm-' 
Products  for  which  separate  statistics  are  shown  below — 

Black  lakes:  Logwood  black  (C.I.  1253) 

Blue  lakes,  total 

Brilliant  wool  blue  FFR  (Pr.  40) 

Peacock  blue,  fugitive  (Patent  blue)  (C.I.  671) 

All  other 

Brovm  lakes 

Green  lakes 

Maroon  lakes 

Orange  lakes:  Persian  orange  (Acid  orange  Y)  (Orange  II) 
(C.I.  151) — - 


1,000 
ounds 

5,182 


'.,000 
ounds 
3,652 


1,000 
dollars 
3,274 


165 
5,017 


103 
3,549 


3,193 


91 
2,639 


1,300 


2,507 
104 


IT 
1,194 
78 


1,223 


1,172 
35 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


31 


TARLE  15\.--Synthetic  organic   chemicals 


United  States  produ 
/956 --ContinueH 


Quantity 


Unit 
value""^ 


LAKES  OR  LAKED  COLORS--Continued 

Red  lakes,  total 

Alizarin  red  B  (C.I.  1027)— - 

Pigment  scarlet  3B  (C.I.  216) 

Scarlet  2R  (C.I.  79) 

All  other 

Violet  lakes,  total 

Methyl  violet 

All  other 

Yellow  lakes: 

Fast  light  yellow  (C.I.  636) 

"Tartrazine  (C.I.  640) 


1,000 
pounds 

1,087 


1ST 
186 
307 
-ill 


1,000 
pounds 
997 


1,000 
dollars 
1,167 


104 
184 
318 
391 


240 
285 
178 
464 


$1.17 


1.15 
.89 


1.62 
1.  14 


Calculated  on  rounded  figures. 
^  Includes  all  maroon  reduced  toners  and  unspecified  black  reduced  toners. 
^  Includes  unspecified  black,  orange,  and  yellow  lakes. 

Note. — The  C.I.  (Colour  Index)  and  Pr.  (prototype)  numbers  shown  in  this  report  are  the  identifying 
numbers  given  respectively  in  the  Colour  Index  and  in  the  prototype  list  of  the  Technical  Manual  and 
Yearbook  of  the  American  Association  of  Textile  Chemists  and  Colorists.  A  C.I.  or  Pr.  number  enclosed  in 
parentheses  is  alv/ays  the  number,  in  the  Index  or  Manual,  of  the  dye  from  v^hich  the  specified  toner  or  lake 
v/as  produced.  If  the  C.I.  or  Pr.  number  is  not  enclosed  in  parentheses,  it  indicates  that  the  named  toner 
is  itself  listed  in  the  Index  or  Manual. 

The  abbreviations  BIA  and  PTA  stand  for  phosphomolybdic  and  phosphotungstic  acids,  respectively.  Pigments 
formerly  listed  as  FIMA  (phosphotungstoraolybdic  acid)  are  now  included  with  FTA  colors. 

Intennediates  used  in  the  manufacture  of  certain  colors  are  abbreviated  as  follows: 


dca 
deb 


acetoacetanilide 
acetoacet-ortho-toluidide 
beta-naphthol 
beta-oxynaphthoic  acid  (3- 

hydroxy-2-naphthoic  acid) 
dichloro aniline 
dichlorobenzidine 


dna    dlnitroaniline 

mnpt   meta-nitro-para-toluidine 

(4-chloro-ortho-toluidine ) 
ocpna  ortho-chloro-para- 

nitroaniline  (2-chloro-4- 

nitroaniline ) 
ona    ortho-nitroaniline 


pup  phenylmethylpyrazolone 
pnoa  para-nitro-ortho-anlsidine 

(5-nitro-ortho-anisidine) 
pnot  para-nitro-crtho-toluidine 

( 5-m.tro-ortho-toluidine ) 


Production  of  full-strength  toners  totaled  28.  5  million  pounds 
in  1956,    or  8.  5  percent  less  than  the  31.  2  million  pounds  reported 
for  1955.    Sales  of  full-strength  toners  also  declined;  they  totaled 
22.4  million  pounds,    valued  at  45.7  million  dollars,    in  1956,    com- 
pared with  26.  2  million  pounds,    valued  at  52.4  million  dollars,    in 
1955--a  decline  of  14.  5  percent  in  quantity  and  12.  9  percent  in 
value.    Fifty-seven  percent  of  the  output  of  full-strength  toners  in 
1956  consisted  of  red  toners  (16.  2  million  pounds).    Individual 
toners  produced  in  the  largest  quantities  were  lithol  red  R,    5.4 
million  pounds;  toluidine  red,    2.  7  million  pounds;  benzidine 
yellows,    2.4  million  pounds;  phthalocyanine  blue  B,    2.3  million 
pounds;  phthalocyanine  green,    1.  7  nnillion  pounds;  permanent  red 
2B  and  eosine,    1.4  million  pounds  each;  and  red  lake  C,    1.3  mil- 
lion pounds . 

Production  of  reduced  (or  extended)  toners  amounted  to  7.  3 
million  pounds  in  1956,    or  6.  4  percent  less  than  the  7.  8  million 
pounds  reported  for  1955.    Sales  of  reduced  toners  amounted  to 
7.  0  million  pounds,    valued  at  8.  8  million  dollars,    in  1956,    com- 
pared with  7.  5  million  pounds,    valued  at  7.  9  million  dollars,    in 

1955.  Sales  of  reduced  toners  in  1956  thus  were  5.  9  percent 
smaller  in  quantity  but  12.  0  percent  greater  in  value  than  in  1955. 
Phthalocyanine  blue  B  was  the  reduced  toner  produced  in  the 
largest  quantity  in  1956;  the  output  of  this  pigment  was   1.  5  million 
pounds. 

Production  of  lakes  (laked  colors)  totaled  5.  2  million  pounds  in 

1956,  or  6.  3  percent  less  than  the  5.  5  million  pounds  produced  in 


32 


UNITED  STATES  TARIFF  COMMISSION 


TARLE  Ifi.  --Synthetic   organic   chemicals:    United  States   production   and  sales   of  selected  dry,    flushed,    pulp, 

and  dispersed  colors,    1956^ 

[Listed  below  are  selected  dry,  flushed,  pulp,  and  dispersed  colors  for  which  data  on  production  and 

sales  may  be  published] 


Dry,  flushed,  pulp,  and  dispersed  foiros 


Produc- 
tion 


Quantity 


Unit 
value' 


Alkali  blue,  C.I.  70A:^ 

Dry  form 

Flushed  form 

Benzidine  yellow;' 

Dry  fonii 

Flushed  form 

Pulp  form 

Dispersed  fomi 

Eosine  (C.I.  768):'' 

Dry  form 

Flushed  form 

Lithol  red  R,  C.I.  189,  barium  toner:' 

Dry  fonn 

Flushed  form 

Pulp  form 

Lithol  red  R,  C.I.  189,  calcium  toner; '' 

Dry  form 

Flushed  form 

Pulp  fomi 

Lithol  red  R,  C.I.  189,  sodium  toner:' 

Dry  form 

Flushed  form 

Methyl  violet  B  (C.I.  630),  fugitive:^ 

Dry  foim 

Flushed  forai 

Methyl  violet  B  (C.I.  680),  permanent;' 

Dry  form 

Flushed  form 

Pulp  form 

Peacock  blue  (C.I.  671),  fugitive:'' 

Dry  form 

Flushed  form 

Phthalocyanine  blue  B,  Pr.  431: 

Dry  form 

Flushed  form 

Pulp  form 

Dispersed  form 

Phthalocyanine  green,  Pr.  -^83 :  ' 

Flushed  form 

Dispersed  form 

Red  lake  C,  C.I.  165,  barium  toner: ^ 

Dry  form 

Flushed  form 

Toluldine  red,  C.I.  69: 

Dry  form 

Flushed  form 

Pulp  form 

Dispersed  form 


1,000 
pounds 

156 
3,061 

1,521 
3,272 


205 
2,<i58 

2,518 

2,102 

357 

1,305 
629 
215 


402 
307 


213 
522 


255 
298 


727 
3,079 

2,071 

639 

1,243 

407 

54 


947 
931 

1,985 
704 
294 
147 


1,000 
pounds 

167 
3,090 

1,331 
3,117 


1,438 


2,228 
2,084 


1,199 
635 


394 
166 


217 
458 


282 

308 


365 
2,041 

1,984 
826 

1,240 
382 

206 


1,828 
381 
305 
144 


1,000 
dollars 
348 
3,546 

2,802 

1,832 

186 


180 
1,004 

1,841 
969 
35 

1,015 
361 


380 

103 


514 
285 


338 
1,195 

3,312 
664 

1,407 
273 

175 
120 

926 
592 

2,882 
331 
156 


Per 
pound 

$2.08 
1.15 

2.11 

.59 

2.09 


.83 
.46 
.62 


.96 

.62 

1.33 
.74 

1.82 

.93 

1.17 


1.67 

.80 

1.13 


.85 
2.40 

1.11 

.67 

1.58 
.87 
.51 


•"■  Statistics  on  production  and  sales  of  the  organic  pigments  (color  lakes  and  toners)  listed  in  this  table 
are  given  in  terms  of  the  commercial  (physical)  forms  in  which  they  enter  commercial  channels.  Data  on  the 
flushed,  pulp,  and  dispersed  forms,  therefore,  are  in  terms  of  total  weight,  including  pigment  and  vehicle 
(water  or  oil). 

'  Calculated  on  rounded  figures . 

^  Data  on  the  pulp  and  dispersed  forms  were  accepted  in  confidence  and  may  not  be  published  because  pub- 
lication would  reveal  the  operations  of  individual  companies. 

''  Data  on  the  pulp  form  of  production  were  accepted  in  confidence  and  may  not  be  published  because  publi- 
cation would  reveal  the  operations  of  individual  companies. 

'  Data  on  the  dispersed  form  were  accepted  in  confidence  and  may  not  be  published  because  publication 
v;culd  reveal  the  operations  of  individual  companies. 

'  Data  on  the  pulp  form  of  sales  and  all  data  on  the  dispersed  form  were  accepted  in  ccnfidenoe  and  may 
not  be  published  because  publication  would  reveal  the  operations  of  individual  companies. 

'  Data  on  the  pulp  form  were  accepted  in  confidence  and  may  not  be  published  because  publication  would 
reveal  the  operations  of  individual  companies. 

'  Data  on  the  pulp  form  of  production  and  all  data  on  the  dispersed  form  were  accepted  in  confidence  and 
may  not  be  published  because  publication  would  reveal  the  operations  of  individual  companies. 

'  Data  on  the  dry  and  pulp  forms  were  accepted  in  confidence  and  may  not  be  published  because  publication 
would  reveal  the  operations  of  individual  companies. 

Note. — The  C.I.  (Colour  Index)  and  Pr.  (prototype)  numbers  shown  in  this  report  are  the  identifying  num- 
bers given  respectively  in  the  Colour  Index  and  in  the  prototype  list  of  the  Technical  Manual  and  Yearbook 
of  the  American  Association  of  Textile  Chemists  and  Colorists.  A  C.I.  or  Pr.  number  enclosed  in  parentheses 
is  always  the  number,  in  the  Index  or  Manual,  of  the  dye  from  which  the  specified  toner  or  lake  was  pro- 
duced. If  the  C.I.  or  Pr.  number  is  not  enclosed  in  parentheses.  It  indicates  that  the  named  toner  is  itself 
listed  in  the  Index  or  Manual. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956  33 

1955.    Sales  totaled  3.  7  million  pounds,    valued  at  3.  3  million 
dollars --representing  a  decline  of  16.  7  percent  in  quantity  and  18.  0 
percent  in  value  from  the  4.4  million  pounds,    valued  at  4.  0  million 
dollars,    reported  for  1955.    Fugitive  peacock  blue,    the  output  of 
which  was  2.  5  million  pounds,    was  the  lake  produced  in  the  largest 
quantity  in  1956. 

Statistics  on  the  dry,    flushed,    pulp,    and  dispersed  forms  of  1 3 
selected  colors  are  given  in  table   16.   Of  these  colors,    alkali  blue, 
benzidine  yellow,    eosine,    the  methyl  violets,    and  fugitive  peacock 
blue  were  made  chiefly  in  the  flushed  form;  the  lithol  reds, 
phthalocyanine  blue  B,    phthalocyanine  green,    red  lake  C,    and 
toluidine  red  were  made  principally  in  the  dry  form. 

Medicinals 

In  this  report,    medicinal  chemicals  are  divided  into  three  major 
groups:  (1)  Benzenoid  compounds,    derived  principally  from  coal 
tar;  (2)  alicyclic  and  heterocyclic  compounds,    usually  derived  from 
vegetable  products  and  animal  tissues,    but  sometimes  also  from 
coal  tar;  and  (3)  acyclic  compounds,    usually  derived  from  petroleum 
and  from  natural  gas,    or  from  grain  by  fermentation. 

Statistics  on  the  production  of  medicinals  are  in  terms  of  100- 
percent  content  of  the  medicinal  itself,    exclusive  of  all  diluents  or 
other  materials  used  in  mixing  or  compounding  tablets,    solutions, 
and  suspensions  for  consumer  use.    Except  for  antibiotics,    the 
statistics  on  sales  include  only  that  part  of  the  original  (primary) 
production  that  was  sold  in  undiluted  or  uncompounded  form,    in- 
cluding that  sold  in  bulk  and  that  sold  in  packages  (tablets, 
ampoules,    etc.).    Sales  of  antibiotics  include  all  forms --diluted 
or  undiluted- -in  bulk  or  in  packages. 

In  1956  the  output  of  all  the  medicinal  chemicals  covered  in  this 
report  amounted  to  89.4  million  pounds  (see  table   17A*),    or  13.5 
percent  more  than  the  78.  7  million  pounds  reported  for  1955.    Sales 
totaled  73.  1  million  pounds,    valued  at  505.  9  million  dollars,    in 
1956,    compared  with  sales  of  68.  5  million  pounds,    valued  at  465.  1 
million  dollars,    in  1955. 

The  output  of  all  cyclic  medicinals  in  1956  was  65.  8  million 
pounds,    of  which  40.  6  million  pounds  consisted  of  benzenoid  medic- 
inals and  25.  2  million  pounds,    of  alicyclic  and  heterocyclic  medic- 
inals.   Production  of  acyclic  medicinals  was  23.6  million  pounds  in 
1956,    compared  with  I6.  8  million  pounds  in  1955.    In  terms  of 
quantity,    acetylsalicylic    acid    (aspirin)  was  the  most  important 
medicinal  produced  in  1956.    The  output  in  that  year  was  I6.6  mil- 
lion pounds,    compared  with  15.  1  million  pounds  in  1955;  sales 
amounted  to  13.5  million  pounds,    valued  at  7.  0  million  dollars,    in 
1956,    compared  with  13.  2  million  pounds,    valued  at  7.  0  million 
dollars,    in  1955.    Production  of  sulfa  drugs  in  1956  totaled  3.8  mil- 
lion pounds,    compared  with  2.  8  million  pounds  in  1955.    Production 
of  barbituric  acid  and  derivatives  totaled  756,  000  pounds  in  1956, 
compared  with  864,000  pounds  in  1955--representing  a  decline  of 
12.  5  percent.    Sales  of  barbituric  acid  and  derivatives  totaled 
467,000  pounds,    valued  at  2.5  million  dollars,    in  1956,    compared 
with  486,  000  pounds,    valued  at  2.  8  million  dollars,    in  1955. 

*See  also  table  17B,  part  in,  which  lists  these  products  alphabetically  and  identifies  the  manufac- 
turers, and  table  28  in  part  A  of  the  appendix,  which  shows  imports  of  medicinals  and  pharmaceuticals 
during  the  years  1953-56. 


34 


UNITED  STATES  TARIFF  COMMISSION 


TAHLE    17A.  -Syntheti 


rgani 


chemicals:    United  States   production   and  sales   of  medicinals 


1956 


[Listed  below  are  all  synthetic  organic  medicinals  for  uhlch  any  reported  data  on  production  or  sales  may  be 
published.  (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published 
or  where  no  data  were  reported.)  Table  17B  in  part  III  lists  alphabetically  all  medicinals  for  which  data 
on  production  or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Grand  total 

MEDICINALS,  CYCLIC 

Total 

Chemicals  for  which  separate  statistics  may  not  be  shiwn--- 
Chemicals  for  which  separate  statistics  are  shown  below 

Benz^noid 

Total - - - 

Acetylsalicylic  acid  (Aspirin) 

Amino  acids 

p-Aminobenzoic  acid  and  derivatives,  total 

Procaine  hydrochloride 

Tetracaine  base  and  hydrochloride 

All  other 

p-Aminobenzolc  acid  salts,  total 

Potassium  p-aminobenzoate* 

Sodium  p-aminobenzoate 

Antihistamines 

Bismuth  subgallate 

Bismuth  subsalicylate 

N,a-Dimethylphenethylamine  (Desoxyephedrine)  hydrochloride- 

d,N, a-Dimethylphenethylamine  hydrochloride 

Dyes,  medicinal 

3-{o-Methoxyphenoxy)-l,2-propanediol  (Glyceryl  guaiacyl 

ether) 

a-Methylphenethylamine  (Amphetamine)  base 

a-Methylphenethylamine  sulfate 

2-Naphthyl  benzoate 

Neostigmine  methyl  sulfate 

Phenolsulfonlc  acid  salts 

Phenyl  mercuric  derivatives 

SsLlicylamide 

Salicylic  acid 

Salicylic  acid  salts,  total 

Ammonium  salicylate 

Calcium  salicylate 

Sodium  salicylate 

All  other 

Sulfa  dnigs 

3-o-Tolo}ty-l,2-propanedlol  (o-Cresyl  a-glyoeryl  ether) 

Vitamin  K 

All  other  benzenold  medicinals 

Alicyclic    and  Heterocyclic 

Total -- — 

Alkaloids  and  related  products,  total 

Digitalis  glucosldes 

Homatroplne 

Reserplne 

All  other 

Amino  acids 

Antibiotics  for  human  or  veterinary  use,  total 

Dihydrostreptomycin 

Neomycin,  base 

Penicillin  salts,  total' 

Potassium  penicillin 

Procaine  penicillin 

All  other  penicillin  salts 

Streptomycin 


Pro- 
duction^ 


Sales'^ 


5,375 


65,802 


23,673 
42,129 


40,599 


16,603 

1 

780 


586 

3 

191 


100 
29 


(5) 


776 
187 


3,817 


9,565 


25,203 


(^ 


1,967 


631 

U8 
363 

150 
130 


1,000  1,000 

pounds  dolU 

73,141     505,929 


53,499 


20,169 
33,330 


31,477 


13,524 
4 

740 


556 


182 


(  =  ) 


370 
6,585 


473,717 


43,996 
429,721 


47,586 


7,007 
59 

2,207 


1,549 
51 
607 


202 
86 


86 

103 


50 
289 


709 
86 

1,635 

86 

4 

7,284 

22,022 


1,737 


593 
137 
343 
113 
147 


451 
2,373 


466 
121 


9,750 
177 


23,762 


426,131 


1,523 


59 

513 
951 

121 

271,371 


18,198 
5,989 
63,529 
14,085 
22,500 
26,944 
5,604 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956  35 

TAnLE  17A. --Synf/ief  ic  organic  chemicals:    United  States  production   and  sales  of  medicinals,    7956- -Cont  inueH 


Pro- 
duction^ 


Quantity 


MEDICINAI£,  CYCLIC--Continued 

Alicyclic   and  Heterocyclic — Continued 

Antibiotics  for  human  or  veterinary  use — Continued 

Tetracycline 

All  other  antibiotics 

Antibiotics  for  animal  feed  supplements,  food  preservation, 

snd  crop  spraying 

Antihistamines 

Barbituric  acid  and  derivatives,  total 

5-Allyl-5-(l-methylbutyl)barbiturio  acid  (Secobarbital) 

and  salt 

5-sec-Butyl-5-ethylbarbiturlc  acid 

5,5-Diethylbarbituric  acid  (Barbital) 

5-Ethyl-5-(l-methyl-n-butyl)barbituric  acid 

(Pentobarbital) ■ 

5-Ethyl-5-phenylbarbiturio  acid  (Phenobarbital)  (Luminal) 

5-Ethyl-5-phenylbarbiturio  acid,  sodium  salt 

All  other 

Bile  acids  and  salts,  total 

Dehydrocholic  acid 

Desoxycholic  acid 

Ketocholanic  acids 

All  other 

Bromocamphor,  mono 

Caffeine,  natural  and  synthetic 

Camphoric  acid  and  anhydride 

5-Chloro-7-iodo-8-quinolinol  (lodochlorohydroxyquinoline) — 

Dlhydrocodeinone  bi tartrate 

5,7-Diiodo-8-qulnolinol 

5,5-Diphenylhydantoin,  sodium  salt 

Hormones  (steroid),  total 

Hydrocortisone  alcohol  and  acetate 

17-Hydroxy-ll-dehydrocortioosterone  (Cortisone)  and 

acetate 

Prednisolone 

All  other 

Methyl  nicotinate 

Piperazine,  hexahydrate 

Piperazine  derivatives,  total 

Piperazine  citrate 

Piperazine  tartrate 

All  other 

Theobromine  sodium  salicylate 

Theophylline  base 

Theophylline  derivatives 

Tranquillizers  (including  benzenoid) 

Vitamins,  total 

A  (Alcohol  and  esters),  ^°  ^'^   from  all  sources 

Bi  (Thiamine  derivatives) 

B2  (Riboflavin  for  human  consumption)  (lOO^i) 

B2  (Riboflavin  for  animal  and  poultry  consumption)  (100^) 

Be  (Pyridoxine) 

B12  All  grades 

D2  (Irradiated  ergosterol)"'"^ 

D3  (Irradiated  animal  sterol) ""^^ 

Niacin  (Nicotinic  acid),  niacinamide,  and  niacinamide 

hydrochloride 

All  other 

All  other  alicyclic  and  heterocyclic  medicinals 

MEDICINALS,  ACYCLIC 

Total 

Chemicals  for  which  separate  statistics  may  not  be  shown 

Chemicals  for  which  separate  statistics  are  shown  below 


1,000 
pounds 

220 

un 

211 
756 


1,758 
7 


7 

7 

38 

3 
879 

297 


138 
159 


102 
112 
122 

3,807 


196 
266 
164 
206 


(^  =  ) 


2,721 
215 


U,108 


23,573 


1.000 
pounds 

186 
366 


1,000 
dollars 

72,903 
105,  U8 

28,150 
2,309 

2,4^3 


1,640 


1,009 
261 


2,895 


162 
168 
101 
144 
24 
(") 


2,098 
196 


12,885 


19,642 


67 
36 
19 

36 

794 

52 

1,479 

1,741 


351 
564 

826 

24 
4,783 
17 
25 
446 
33 
24 

25,908 


^552 


7,455 
8,901 


2,758 
723 


358 

18 
347 


248 

357 


62,831 


15,278 

4,228 

2,493 

2,828 

3,615 

22,640 

389 

496 

6,711 
4,153 

20,234 


32,212 


7,635 
15,938 


9,305 
10,337 


5,845 
26,367 


See  footnotes  at  end  of  table. 


36 


UNITED  STATES  TARIFF  COMMISSION 


TABLE    17 A.  -Synthet ic  organic  chemicals:    United  States  prorhjcti 


eHicinals.    J956--Conti 


Pro- 
duct ion-'- 


Quantity 


Unit 
value-' 


MEDICINALS,  ACYCLIC— Continued 

Amino  acids,  total 

P -Alanine 

1(  +  ) -Glutamic  acid 

All  other 

Betaine  base 

Betaine  hydrocM.oride 

Chloretone  (tert-Trichlorobutyl  alcohol) 

Choline  salts,   total 

Choline  bitartrate 

Choline  chloride,  for  animal  and  poultry  feed  and  for  use 

as  an  intermediate 

Choline  chloride,  medicinal  grade  only 

Choline  dihydrogen  citrate 

All  other 

Gluconic  acid  salts 

Tranquillizers:  2-Methyl-2-n-propyl-l,3-propanediol 

dicarbamate 

Vitamins,  total 

Ascorbic  acid  and  derivatives,  total 

Ascorbic  acid 

All  other 

Pantothenic  acid  and  derivatives,  total 

Pantothenic  acid,  d-oaloium  salt 

All  other 


34g" 
220 

3,031 


5,215 


33r 

171 


1,000 
dollar: 

6,760 


'i,817 


127 
72 


3,326 


3,383 


2,866 

2,498 

368 

517 
172 
345 


— i3r 

3,926 
28 

108 
61 


2,749 


"Tar 

296 

5,744 

39 

44 

21 

1,631 


$2.29 


1.73 
2.35 


1.50 
.38 


1,278 


2,503 
15,369 


1.32 

1.12 


5.59 


2,455 

12,884 

2,107 

11,123 

348 

1,761 

294 

2,485 

49 

450 

245 

2,035 

5.25 
5.28 
5.06 
8.45 
9,18 
8.31 


Production  of  medicinals  is  in  bulk  only.  The  statistics  do  not  include  the  production  of  finished  prep- 
arations, such  as  tablets,  capsules,  and  ampoules,  which  are  manufactured  from  bulk  medicinals. 

^  Except  for  antibiotics,  sales  include  only  that  part  of  the  original  production  which  is  sold  in  undi- 
luted or  uncompounded  form  including  that  sold  in  bulk  and  that  sold  in  packages  (tablets,  ampoules,  etc.). 
Sales  of  antibiotics  include  elII  forms  (both  undiluted  or  uncompounded  and  diluted  or  compounded)  including 
that  sold  in  bulk  and  that  sold  in  packages. 

•'  Calculated  on  rounded  fig\ires. 

*  Contains  small  quantities  of  the  calcium  salt. 

'  Production  of  neostigmine  methyl  sulfate  was  50  pounds;  sales  were  39  pounds. 

^  Production  of  digitalis  glucosides  totaled  300  pounds. 

'  Sales  of  reserpine  were  258  pounds;  unit  value  of  sales,  $1,913. 

'  Penicillin  salts  in  terms  of  international  units  based  on  1,667  units  per  milligram  of  penicillin  G 
standard  of  the  Food  and  Dr\ig  Administration  were  reported  as  follows: 


Quantity 


Unit  value 


Penicillin  salts,  total — 
Potassium  penicillin  G- 
Procaine  penicillin  G — 
All  other 


Pllhor, 
ternalional 

448%99 


1,000 
dollars 

63,529 


39,192 
274,512 
114,555 


103,381 
259,013 
86,205 


14,085 
22,500 
26,944 


Per   billi 

internatio 

anits 

$141.61 


136.24 
86.87 
312.54 


'  Commercial  sales  are  based  on  international  units. 

-"-^  Quantities  reported  in  units  have  been  converted  to  pounds  using  as  a  factor  the  average  units  per 
pound  of  the  medicinal  grade  as  determined  by  the  Food  and  Drug  Administration. 

■'■■'■  Production  of  vitamin  A  alcohol  and  esters  from  all  sources  totaled  196,621  billion  U.S. P.  units;  sales 
totaled  166,221  billion  U.S. P.  units. 

-"-^  Production  of  vitamin  B121   all  grades,  totaled  655  pounds;  sales  totaled  450  pounds. 

^^  Production  of  vitamin  D2  totaled  23,280  billion  U.S. P.  units;  sales  totaled  16,945  billion^J.S.P.  units. 
Calculated  at  the  rate  of  18.14  billion  units  per  pound,  production  totaled  1,283  pounds  and  sales  totaled 
934  pounds. 

"■*  Production  of  vitamin  D3  totaled  23,488  billion  U.S. P.  units;  sales  totaled  14,139  billion  U.S. P.  units. 
Calculated  at  the  rate  of  18.14  billion  units  per  pound,  production  totaled  1,295  pounds  and  sales  totaled 
779  pounds. 

In  terms  of  valUe,    the  antibiotics --as  a  group--were  the  most 
important  medicinals  produced  in  1956.    Total  production  of  anti- 
biotics for  human  and  veterinary  use  was   1,967,000  pounds  in  1956, 
or  395,  000  pounds  more  than  the  output  of  1,  572,  000  pounds  re- 
ported for  1955.    Sales  totaled  1,  737,  000  pounds,    valued  at  271.  4 
million  dollars,    in  1956,    compared  with   1,367,000  pounds,    valued 
at  242.4  million  dollars,    in  1955.    Production  of  penicillin  salts 
totaled  478  trillion  international  units  in   1956,    compared  with  344 
trillion  international   units,    in  1955.    Sales  of  penicillin  salts  totaled 


SYNTHETIC  ORGANIC   CHEMICALS,  1956  37 

449  trillion  international  units,    valued  at  63.  5  million  dollars,    in 
1956,    compared  with  336  trillion  international  units<    valued  at  44.  0 
million  dollars,    in  1955.    The  output  of  dihydrostreptomycin 
amounted  to  492,000  pounds  in  1956,    compared  with  the  369,000 
pounds  reported  for  1955;   sales  totaled  431,000  pounds,    valued  at 
18.  2  million  dollars,    in  1956,    compared  with  332,  000  pounds, 
valued  at  16.  3  million  dollars,    in  1955.    The  output  of  streptomycin 
amounted  to  130,000  pounds  in  1956,    compared  with  1  54,  000  pounds 
in  1955.    Production  of  neomycin  base  amounted  to  17,  000  pounds 
in  1956;  sales  were   14,  000  pounds,    valued  at  6.  0  nnillion  dollars. 
Production  of  tetracycline  was   220,  000  pounds  in  1956;  sales  were 
186,  000  pounds,    valued  at  72.  9  million  dollars. 

The  combined  output  of  other  medicinal  antibiotics,    such  as 
chlorotetracycline,    chloramphenicol,    and  oxytetracycline,    totaled 
477,  000  pounds  in  1956;   sales  of  these  products  in  1956  amounted  to 
366,  000  pounds,    valued  at  105  million  dollars.    Total  production  of 
antibiotics  for  animal  feed  supplements,    food  preservation,    and 
crop  spraying  in  1956  was  779,000  pounds,    compared  with  the 
520,  000  pounds  reported  for  1955;  sales  of  these  products  in  1956 
amounted  to  683,  000  pounds,    valued  at  28.  2  million  dollars. 

Among  the  other  important  groups  of  nnedicinal  products  in  1956 
were  the  vitamins.    In  1956  the  combined  output  of  vitamins--as  a 
group- -was  7.  2  million  pounds,    connpared  with  6.  1  million  pounds 
in  1955.    Sales  of  vitamins  totaled  5.  6  million  pounds,    valued  at 
78.  3  million  dollars,    in  1956,    compared  with  5.  1  million  pounds, 
valued  at  82.  8  million  dollars,    in  1955.    In  terms  of  quantity,    the 
1956  output  of  some  of  the  more  important  vitamins  was  as  follows: 
Niacin  and  derivatives,    2.  7  million  pounds;  ascorbic  acid  and  de- 
rivatives,   2.  9  million  pounds;    pantothenic  acid  and  derivatives, 
517,  000  pounds;  thiamine  derivatives,    266,  000  pounds;  and  vitamin 
A  alcohol  and  esters,    196,  000  pounds  (196,  621  billion  U.  S.  P.    units). 
In  terms  of  value  of  sales,    vitamin  B  jj     w^as  the  most  important. 
Sales  of  this  medicinal  in  1956  totaled  450  pounds,    valued  at  22.6 
million  dollars.    Sales  of  ascorbic  acid  and  derivatives  were  2.  5 
million  pounds,    valued  at  12.  9  million  dollars,    and  of  vitamin  A, 
162,  000  pounds,    valued  at  15.  3  million  dollars. 

In  1956  the  combined  production  of  all  hormones  was  56,  000 
pounds;  sales  totaled  26,  000  pounds,    valued  at  25.  9  million  dollars. 

The  output  of  tranquillizers  in  1956  totaled  468,  000  pounds,    of 
which  2-methyl-2-n-propyl-l ,  3-propanediol  dicarbamate  accounted 
for  346,  000  pounds;  sales  of  this  medicinal  in  1956  were  325,  000 
pounds,    valued  at  2.  5  million  dollars. 

Flavor  and  Perfume  Materials 

Flavor  and  perfume  materials  are  chemicals- -with  desirable 
flavors  or  odors --that  are  used  in  the  manufacture  of  food,    bev- 
erages,   cosmetics,    and  soaps  and  to  disguise  unpleasant  odors  in 
industrial  products.    This  report  includes  data  on  materials  derived 
from  natural  products  by  actual  chemical  processes  and  from  coal 
tar;  it  does  not  include  data  on  purely  natural  products,    such  as 
floral  essences,    essential  oils,    and  other  materials  that  are  ob- 
tained by  simple  extraction  or  by  distillation  from  natural  vegetable 
and  animal  sources. 

The  flavor  and  perfume  materials  covered  in  this  report  are 
grouped  as  either  cyclic  or  acyclic  nnaterials,    according  to  their 


38 


UNITED  STATES  TARIFF  COMMISSION 


chemical  structure.    Cyclic  materials  are  further  classified  as 
(1)  benzenoid  and  naphthalenoid,    and  (2)  terpenoid,    heterocyclic, 
and  alicyclic.    Statistics  on  the  production  and  sales  of  flavor  and 
perfume  materials  in  1956  are  given  in  table   18A.^ 

Production  of  flavor  and  perfume  naaterials  as  a  group  totaled 
44.7  million  pounds  in  1956,    showing  an  increase  of  6.4  percent 
from  the  42.  0  million  pounds  produced  in  1955.    Sales  were  39.  2 
million  pounds,    valued  at  54.  7  million  dollars,    in  1956,    compared 
with  35.8  million  pounds,    valued  at  52.6  million  dollars,    in  1955. 

Th^  output  of  benzenoid  and  naphthalenoid  flavor  and  perfume 


TABLE   lH^...Syntheti 


rganic   chemicals:    Vn 


ted  States  produ 
terials,    1956 


and  perfume 


[Listed  below  are  all  synthetic  organic  flavor  and  perfume  materials  for  which  any  reported  data  on  produc- 
tion or  sales  may  be  published.  (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and 
may  not  be  published,  or  where  no  data  were  reported.  )  Table  18B  in  part  III  lists  alphabetically  all 
flavor  and  perfume  materials  for  which  data  on  production  or  sales  were  reported  and  identifies  the  manu- 
facturer of  each] 


Produc- 
tion 


Quantity 


Unit 
value ^ 


Grand  total 

FLAVOR  AND  PERFUME  MATERIALS,  CYCLIC 

Total--- 

Materials  for  which  separate  statistics  may  not  be  shown- 
Materials  for  which  separate  statistics  are  shown  below-- 

Benitnoid  and  Naphthalenoid 

Total 

o-Amylcinnamaldehyde 

Anethole 

Benzophenone 

Benzyl  acetate 

Benzyl  alcohol^ 

Benzyl  benzoate^ 

Benzyl  propionate 

Ethyl  a,/3-epoxy-/>-methylhydrocinnamate 

Eugenol 

Isobutyl  phenylacetate 

Isoeugenol 

p-Methoxyacetophenone 

Methyl  salicylate  (Synthetic  wintergreen  oil) 

Phenethyl  acetate 

Phenethyl  alcohol 

3-Phenyl-l-propyl  alcohol  (Hydrooinnamic  alcohol) 

All  other  benzenoid  and  naphthalenoid  materials 

Terpenoid,    Heterocyclic,    and  Alicyclic 

Total 

Cedryl  acetate 

Citral  (Geranial) 

Cltronellal 

Citronellol 

Citronellyl  acetate 

Citronellyl  formate 

Coumarin 

Ethyl  oxyhydrate 

Geraniol 

Geranyl  acetate 

Geranyl  formate 

Hydroxyoltronellal 

See  footnotes  at  end  of  table. 


1,000 
pounds 
4^,658 


25,391 


10,378 
15,013 


330 
1,398 
lU 
715 
673 
157 


135 
25 


3,518 
60 

1,315 
13 

6,962 


9,882 


100 

22-1 

246 

7 

13 
780 

32 
331 


1,000 
pound, 
39,169 


1.000 
dollars 

5-4,674 


20,723 


32,865 


8,220 
12,503 


15,509  ;   12,860 


15,454  1 
17,411 j 


16,424 


213 
1,141 
119 
693 
685 
150 


3,283 

24 

960 

11 

5,365 


7,863 


360 
1,272 
133 
365 
322 


241 

12 

1,664 

30 

1,015 

22 

10,620 

16,441 


40 


279 
35 


25 
56 
2,000 
23 
951 
125 

923 


1.28 


1.69 

1.11 

1.12 

.53 

.47 

.53 

1.33 

2.07 

3.54 
1.71 
.51 
1.25 
1.06 
2.00 
1.98 


2.00 
4.29 


3.74 
4.17 
5.09 
3.03 
.92 
3.41 
3.57 


5  See  also  table  18B,  part  III,  which  lists  these  products  alphabetically  and  identifies  the 
manufacturers. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


39 


TABLE   ISA. --Synthetic  organic  chemicals 


United  States   product i 
J956- -Continued 


nd  sales  of   Flavor  and  per/ume  materials 


Produc- 
tion 


Quantity       Value         ^^^^i 


FLAVOR  AND  PERFUME  MATERIALS,    CYCLIC— Continued 
Terpenoid,    Heterocyclic,    and  Alicyc lie- -Continued 

lonones,    total 

a-Ionone 

All  other 

Isobomyl  acetate 

Linalool 

Linalyl  acetate 

Menthol,  synthetic 

Methylionones 

Plperonal  (Heliotropin) 

Rhodinol 

Safrole 

Terpineols 

Terpinyl  acetate 

Terpinyl  propionate 

Vetivenyl  acetate 

All  other  terpenoid,  heterocyclic,  and  alicyclic  materials- 

FLAVOR  AND  PERHJME  MATERIALS,  ACYCLIC 

Total--- 

Materials  for  which  separate  statistics  may  not  be  shown — 
Materials  for  which  separate  statistics  are  shown  below 

Allyl  caproate 

Ethyl  butyrate 

Glutamic  acid,  monosodium  salt  (Monosodium  glutamate) 

Isoamyl  butyrate  (Amyl  butyrate) 

Isoamyl  formate  (Amyl  formate) 

^  Calculated  on  rounded  figures. 

^  Includes  some  technical  and  medicinal  grades. 

^   Includes  chemically  modified  essential  oils. 


1,000 
pounds 
271 


2A0 


110 

382 

249 

281 

11 

194 

2,136 

315 

12 

15 

3,416 


19,267 


1,254 
18,013 


156 

17,821 

27 


1,000 
pounds 
238 


1,000 
dollars 
927 


54 
100 
292 
226 
334 


1,927 
315 


2,855 


18,446 


270 

465 

1,579 

1,283 

706 

274 

39 

532 

155 

210 
4,834 


21,809 


962 
17,484 


902 
20,907 


154 
17,294 


106 
20,761 


pound 
$3.89 


7.75 
3.76 


5.00 
4.65 
5.41 
5.68 
2.11 
24.91 
1.00 
.28 


23.33 
1.69 


.94 

1.20 


2.67 
.69 

1.20 


materials  in  1956  was   15.  5  million  pounds,    an  increase  of  8.  8  per- 
cent from  the   14.  3  million  pounds   reported  for   1955.    In  this  group, 
chemicals    the    output  of  which  exceeded  1  million  pounds  in  1956 
were  methyl  salicylate  (synthetic    wintergreen    oil),    3.5  million 
pounds;  anethole,    1.4  million  pounds;  and  phenethyl  alcohol,    1.  3 
million  pounds.    Sales  of  benzenoid  and  naphthalenoid  flavor  and 
perfume  materials  as  a  group  totaled  12.9  million  pounds,    valued 
at  16.4  million  dollars,    in  1 956- -figures  only  slightly  higher  than 
those  reported  for  1955. 

Production  of  terpenoid,    heterocyclic,    and  alicyclic  flavor  and 
perfume  materials  in  1956  was  9.9  million  pounds- -about  the  same 
as  in  1955.    The  chemicals  in  this  group  produced  in  the  largest 
volume  were  the  terpineols;  production  of  these  materials  was  2.  1 
million  pounds  in  1956,    or  15.6  percent  less  than  in  1955.    Sales  of 
terpenoid,    heterocyclic,    and  alicyclic  materials  as  a  group  totaled 
7.  9  million  pounds,    valued  at  16.  4  million  dollars,    in  1956,    com- 
pared with  7.  5  million  pounds,    valued  at  14.  8  million  dollars,    in 
1955. 

The  output  of  acyclic  flavor  and  perfume  materials  totaled  19.  3 
million  pounds  in   1956--an  increase  of  7.  9  percent  over  the  output 
in   1955.    By  far  the  most  important  product  in  this  group  was 
monosodium  glutamate,    production  of  which  totaled  17.8  million 
pounds,    or  about  92  percent  (by  weight)  of  the  acyclic  group.    Sales 
of  acyclic  materials  totaled  18.4  million  pounds,    valued  at  21.8 
million  dollars,    in  1956,    compared  with  15.7  million  pounds, 
valued  at  21.6  million  dollars,    in  1955. 


40  UNITED  STATES  TARIFF  COMMISSION 

Plastics  and  Resin  Materials 

Plastics  and  resin  materials  are  formed  by  the  condensation  or 
polymerization  of  organic  chemicals  with  the  addition  of  necessary 
fillers,  plasticizers,  extenders,  and  colors.    At  some   stage  in  their 
manufacture  they  exist  in  such  physical  condition  that  they  can  be 
shaped  or  processed  by  the  application  of  heat  and  pressure.    Some 
types  of  materials  may  be  molded,    cast,    or  extruded  into  finished 
and  semifinished  forms.    Other  types  are  used  as  adhesives,    for  the 
treatment  of  paper  and  textiles,    and  for  protective  coatings.    Still 
other  types  of  plastics  materials  are  processed  into  sheets,    rods, 
and  tubes  which,    in  turn,    are  further  manufactured  into  finished 
products  such  as   rainwear,    shower  and  other  curtains,    buttons 
and  buckles,    and  decorative  articles.    Except  for  vinyl  resins,    the 
statistics  given  in  the  following  tables  are  based  on  the  total  weight 
of  the  materials,    excluding  liquids.    Statistics  on  vinyl  resins  are 
given  on  the  basis  of  resin  content.    Cellulose  plastics,    being  de- 
rived from  natural  raw  materials,    are  not  covered  in  this  section 
of  the   report.    (See  part  D  of  the  appendix.  ) 

Statistics  on  the  production  and  sales  of  plastics  and  resins  are 
given  in  table   19A     according  to  chemical  composition,    and  in  table 
20  according  to  broad  end  uses.    In  1956  the  total  production  of  all 
synthetic  plastics  and  resin  materials  (except  cellulosics)  amounted 
to  3,977  million  pounds--6.4  percent  more  than  the  3,739  million 
pounds  produced  in  1955.    Sales  amounted  to  3,465  million  pounds, 
valued  at  1,  14Z  million  dollars,    in  1956,    compared  with  3,  219  mil- 
lion pounds,    valued  at  1,  078  million  dollars,    in  1955.    Production 
of  cellulose  plastics  in  1956  amounted  to  147  million  pounds. 

Total  production  of  benzenoid  plastics  and  resins  was  2,  018  mil- 
lion pounds  in  1956--about  the   same  as  in  1955.    Sales  in  1956 
amounted  to  1,655  million  pounds,    valued  at  455  million  dollars. 
Of  the  benzenoid  group,    styrene  resins  were  produced  in  the  largest 
volume  in  1956,    as  they  were  in  1955.    The  output  of  styrene  resins 
in  1956  amounted  to  680  million  pounds;  sales  totaled  603  million 
pounds,    valued  at  191  million  dollars. 

In  1956,    as  in  previous  years,    phenolic  and  other  tar-acid  resins 
ranked  second  in  volume  of  production  in  the  benzenoid  group.    Pro- 
duction of  these  resins  in  1956  was  563  million  pounds,    the  same  as 
in  1955.    Sales  amounted  to  497  million  pounds,    valued  at  129  mil- 
lion dollars,    in  1956,    compared  with  483  million  pounds,    valued  at 
127  million  dollars,    in  1955.    The  phthalic  alkyd  resins,    used  prin- 
cipally in  the  manufacture  of  protective  coatings,    were  third  in 
volume  of  production  in  the  benzenoid  group;  production  in  1956 
amounted  to  392  million  pounds.    The  output  of  polyester  resins  in 
1956  was  79  million  pounds. 

Production  of  nonbenzenoid  plastics  and  resins  in   1956  amounted 
to  1,  959  million  pounds,    or  14.  I  percent  more  than  the   I,  718  mil- 
lion pounds  reported  for  1955.    Sales  of  these  resins  amounted  to 
1,  810  million  pounds,    valued  at  687  million  dollars,    in  1956,    com- 
pared with  1,  569  million  pounds,    valued  at  638  million  dollars,    in 
1955.    Of  the  nonbenzenoid  group,    vinyl  resins  were  produced  in 
the  largest  volume  in  1956,    as  they  have  been  for  the  past  several 


6 See  also  table  19B,  part  111,  which  lists  these  products  according  to  chemical  composition,  and 
identifies  the  manufacturers. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


41 


TAHLF  19\. -Syntheti 


chemicals:   United  States  production  and  sal: 
grouped  according   to  chemical   composition. 


fs  of  plastics  and 
1956 


[Quantities  and  values  are  given  in  terms  of  the  total  weight  of  the  materials  (dry  basis).  Listed  below  are 
all  synthetic  plastics  and  resin  materials  for  which  any  reported  data  on  production  or  sales  may  be  pub- 
lished. (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or 
where  no  data  were  reported. )  Table  19B  in  part  III  lists  all  plastics  and  resin  materials  for  which  data 
on  production  or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Grand  total 

PLASTICS  AND  RESIN  MATERIALS,  BENZENOID 

Total — 

Materials  for  which  separate  statistics  may  not  be  shown^ 

Materials  for  which  separate  statistics  are  shown  below 

Coumarone-indene  and  petroleum  polymer  resins 

Epoxy  resins: 

Unmodified:  Epichlorohydrin-phenol  and  bisphenol 

Modified 

Phenolic  and  other  tar-acid  resins,  total 

Unmodified,  total 

Bisphenol-formaldehyde 

p-tert-Butylphenol-foimaldehyde 

Cresols -formaldehyde 

Cresylic  acid-formaldehyde 

Phenol-formaldehyde 

Phenol-furfural 

Resorcinol-fonnaldehyde 

All  other 

Modified,  total 

Bisphenol-formaldehyde-rosin 

p-tert-Butylphenol-formaldehyde-rosin 

Phenol-formaldehyde-aniline 

Phenol-formaldehyde-rosin 

All  other 

Phthalic  alkyd  resins,  total 

Unmodified,  total 

Phthalic  anhydrlde-glycerol 

Phthalic  anliydride-glycerol-glycol 

Phthalic  anhydrlde-glycerol -pentaerythrltol 

Phthalic  anhydrlde-glycerol-Borbitol 

Phthalic  anhydride-glycol -pentaerythrltol 

Phthalic  anhydride -pentaerythrltol 

All  other 

Modified,  total 

Phthalic  anhydride-adiplc  acid-glycol 

Phthalic  anhydride-benzoic  acld-glyoerol 

Phthalic  anhydride-fumaric  aoid-glycerol 

Phthalic  anhydride-fumaric  acid-glycerol-rosin 

Phthalic  anhydride-glycerol-pentaerythritol-phenol- 

foiroaldehyde-rosin 

Phthalic  anhydride-glycerol-pentaerythritol-rosin  and  tall 

oil 

Phthalic  ahhydride-glycerol-phenol-formaldehyde 

Phthalic  anhydrlde-glycerol -phenol-formaldehyde-rosin 

Phthalic  anhydride-glycerol-rosin 

Phthalic  anhydride-maleic  anhydrlde-glycerol 

Phthalic  anlyrdride-maleic  anhydride-glycerol- 

pentaerythritol 

Phthalic  anhydride-maleic  anhydride-glycerol- 

pentaerythritol-rosin 

Phthalic  anhydride-maleic  anhydride-glycerol-rosin 

Phthalic  anhydride-maleic  anhydride-pentaerythritol 

Phthalic  anhydride-maleic  anhydride-pentaerythritol-rosin 

or  tall  oil 

Phthalic  anhydride-pentaerythritol-rosin  or  tall  oil 

All  other 

Polyester  resins,  total* 

Phthalic  anhydride-maleic  anhydride-glycol-styrene 

All  other 

Styrene  resins,  total 

Polystyrene 

Styrene-acrylonitrile  copolymer 

See  footnotes  at  end  of  table. 


1,000 
pounds, 
dry    basis' 
3, 977,  "469 


2,018,274 


7,256 
2,011,018 


260,332 


34,088 
2,013 


563,413 


504,176 

346 

8,044 

7,882 

9,581 

447,745 

859 

2,394 

27,325 

59,237 

3,991 

4,431 

4,267 

22,629 

23,919 

392,415 


287,282 

123,623 

5,630 

35,576 

1,511 

38,355 

76,901 

5,686 

105,133 

501 

5,026 

1,565 

976 

4,714 

12,892 
5,712 
9,120 

12,118 
5,854 

8,315 

2,735 
1,582 
3,681 

5,604 
13,746 
10,992 

79,128 


Oiantity 


1,000 
pounds. 


3,464,710 


1,654,687 


6,327 
1,648,360 


267,261 


23,264 
320 


496,925 


453,228 

204 

7,169 

4,574 

2,179 

418,373 

2,293 

18,436 

43,697 

3,875 

4,219 

2,959 

14,367 

18,277 

187,841 


46,701 
32,427 


679,629 


475,512 
16,721 


130,094 

48,868 

1,966 

10,527 

912 

26,940 

35,982 

4,899 

57,747 

401 

473 

570 


3,372 


2,058 

7,770 
7,488 
2,970 

5,628 

1,232 

515 

3,514 

2,615 

8,098 

11,043 

69,286 


41,756 
27,530 


603,463 


415,867 


1,000 
dollars 
1,142,419 


455, C 


3,660 
451,408 


27,376 


15,482 
325 


129,495 


117,129 

114 

2,740 

1,574 

615 

103,968 

1,762 

6,356 

12,366 

855 
1,013 

952 
3,634 
5,912 

59,042 


40,646 

16,339 

738 

3,149 

285 

8,502 

10,471 

1,162 

18,396 

213 

138 

179 


679 
1,758 
2,793 
1,054 

1,835 

467 

263 

1,004 

861 
2,433 
3,742 

28,302 


14,654 
13,643 


191,386 


122,763 


42 


UNITED  STATES  TARIFF  COMMISSION 


T\PSL?-    19\. -Synthetic   organic   chemicals:    United  States  production   and  sales  of  plastics   and  resin  materials 
grouped  according    to  chemical    composi  tion ,    1956  - -Continued 


Production 


©jantity    Value    ""^*, 
value 


PLASTICS  AND  RESIN  MATERIALS,  BENZENOID--Continued 

Styrene  resins--Contlnued 

Styrene-alkyd  polyester  resins,  total 

Phthalic  anhydride-glycerol-pentaerythritol-styrene 

Phthalic  anhydride-glycerol-styrene 

All  other 

Styrene -butadiene  copolymer 

Styrene-divinylbenzene  copolymer 

All  other  styrene  resins 

PLASTICS  AND  RESIN  MATERIALS,  NONBENZENOID 

Total 

Materials  for  which  separate  statistics  may  not  be  shown^ 

Materials  for  which  separate  statistics  are  shown  below 

Acetone-formaldehyde  resins 

Alkyd  resins  (except  phthalic),  total 

Unmodified,  total 

Maleic  anhydride-pen taerythritol 

All  other 

Modified,  total 

Fumaric  acid-glycerol-rosin 

Fumaric  acid-pentaerythritol-rosin 

Maleic  anhydride-glycerol-pentaerythritol-rosin 

Maleic  anhydride-glycerol-rosin 

Maleic  anhydride-glycol-rosln 

Maleic  anhydride-pentaerythritol-rosin 

Maleic  anhydride-pentaerythrltol-tall  oil 

All  other 

Polyethylene  resins 

Rosin  and  terpene  adduct  resins,  total 

Fumaric  acid-rosin 

All  other 

Rosin  and  tall  oil  esters,  unmodified,  total 

Rosin-glycerol 

Rosin-glycerol-pentaerythritol 

Rosin-pentaerythritol 

Tall  oil-pentaerythritol 

All  other 

Silicone  resins 

Urea  and  melamine  resins,  total 

Urea-formaldehyde  type,  total 

Butylurea-fonnaldehyde 

Urea-formaldehyde 

All  other 

Melami ne-f ormaldehyde  type,  total 

Melamine-formaldehyde 

All  other 

Vinyl  and  vinyl  copolymer  resins   (resin  content),    total 

Polyvinyl  acetate' 

Polyvinyl  chloride  and  copolymer  resins    (containing  50  per- 
cent or  more  polyvinyl  oMoride) 

All  other  vinyl  resins' 


1,000 

pounds, 

dry    basis' 

19,860 

2,826 

11,260 

5,77A 

128,78-; 

29,211 

9,5^1 


1,000 

pounds. 

dry    basis' 

16,355 

1,852 

9,0<;9 

5,4.5^ 

121,084 

27,811 

22,346 


1,959,195     1,810,023 


U3,759 
1,815,436 


81,431 


24, 223 
869 

23,354 

57,208 

4,118 

5,912 

598 

19,482 
2,444 

19,398 
2,975 
2,281 

565,705 

6,494 


2,190 
4,304 


56,414 


25,504 
1,901 
17,260 
280 
11,469 

3,496 

341,516 


245,211 
18,336 

214,550 
12,325 
96,305 
70, 999 
25,306 

759,896 


78,892 


636,850 
44,154 


1.000 

dollars 

6,669 

741 

3,578 

2,350 

40,109 

13,762 

8,078 


687,351 


134, 527 
1,675,496 


118,172 
569,179 


66,351 


21,887 

495 

21,392 

44,464 

3,283 

3,394 

260 

16,835 

1,739 

17,231 

1,208 

514 

514,097 

6,519 


21,142 


2,097 
4,422 


52,259 


10,782 

128 

10,654 

10,360 

836 

1,013 

68 

3,769 

547 

3,676 

263 

188 

187,707 

2,040 


450 
1,590 


9,291 


22,709 

16,549 

66 

12,935 

2,742 

310,773 


4,235 

3,170 

14 

1,872 

8,423 

91,955 


224,318 
13,498 

199,832 
10,988 
86,455 
63,619 
22,836 

722,305 


50,980 
5,351 
41,416 
4,213 
40,975 
28,319 
12,656 

248,441 


73,522 


611,961 
36,822 


25,924 


187,402 
35,115 


^  Calculated  on  rounded  figures. 

^  Dry  basis,  for  the  purpose  of  this  report,  is  defined  as  the  total  weight  of  the  material,  including 
resin,  plasticizers,  fillers,  extenders,  colors,  and  stabilizers,  and  excluding  water,  solvents,  and  other 
liquid  diluents. 

Includes  data  for  aniline-foimaldehyde,  toluenesulfonamide,  and  other  benzenoid  plastics  and  resin 
materials. 

*  Polyester  resins,  for  the  purpose  of  this  report,  include  unsaturated  alkyds,  copolymerized  with 
monomers  such  as  styrene,  and  polyallyl  resins  such  as  diallyl  phthalate  or  allyl  diglycol  carbonate.  Data 
for  styrene-alkyd  polyesters  for  protective  coatings  are  not  included  in  this  group. 

'  Includes  data  for  acr^'lic,  polyamide,  and  other  ncnbenzenoid  plastics  and  resin  materials. 

'  Includes  some  data  for  copolymers  of  polyvinyl  chloride  and  polyvinyl  acetate  which  are  included  in 
table  20  in  the  statistics  for  polyvinyl  chloride  and  copolymers. 

'  Includes  data  for  polyvinyl  alcohol,  butyral  and  formal,  and  for  copolymers  containing  less  than  50  per- 
cent polyvinyl  chloride. 


SYNTHETIC  ORGANIC   CHEMICALS,  1956 


43 


years.    The  output  of  vinyl  resins  amounted  to  760  million  pounds 
tn  1956,    connpared  with  703  million  pounds  in  1955.    Sales  of  vinyl 
resins  in  1956  were  722  million  pounds,    valued  at  248  million 
dollars.    Production  of  polyethylene  resins,    which  were  second  in 

TAHLE  70.  -Synthetic   organic  chemicals:    United  States  production  anH  sales  of  plastics   and  resin  materials, 
grouped  according   to  classes  and  uses,    1956 

[in  thousands  of  poimds,  dry  basis'"'] 


Phenolic  and  other  tar  acid  resins: 
Molding  materials 

Bonding  and  adhesive  resins  for — 

Laminating  (except  ply\';ood) 

Coated  and  bonded  abrasives 

Friction  materials  (brake  linings,  clutch  facings,  etc.  ) 

Thermal  insulation  (rock  wool,  fiber  glass) 

Plyvfood 

All  other  bonding  and  adhesive  uses 

Protective-coating  resins,  unmodified  and  modified,  except  by  rosin--- 

Resins  for  all  other  uses 

Urea  and  melamine  resins: 

Textile-treating  and  textile-coating  resins 

Paper-treating  and  paper-coating  resins 

Bonding  and  adhesive  resins  for-- 

Plywood 

All  other  bonding  and  adhesive  uses,  including  laminating 

Protective-coating  resins,  straight  and  modified 

Resins  for  all  other  uses.  Including  molding 

Styrene  resins: 

Molding  materials 

Protective-coating  resins,  straight  and  modified-' 

Resins  for  all  other  uses 

Vinyl  and  vinyl  copolymer  resins  (resin  content),  total 

Polyvinyl  chloride  and  copolymer  resins  (50  percent  or  more  polyvinyl 
chloride)  for — 

Film  (under  0.010  gage) 

Sheeting  (0.010  gage  and  over) 

Molding  and  extrusion 

Textile-  and  paper-treating  and  coating 

Flooring 

Protective  coatings 

All  other  uses 

All  other  vinyl  resins  for-- 

Adhesives 

All  other  uses 

Alkyd  resins: 

For  protective  coatings: 
Phthalic  anhydride  types: 

Unmodified 

Modified 

Polybasio  acid  types: 

Unmodified 

Modified 

For  all  other  uses 

Rosin  modifications : 

Rosin  esters  for  protective  coatings: 

Unmodified  (ester  gums ) 

Modified  (hard  resins ) 

All  other  modifications  for  protective  coatings  and  other  uses 

Coumarone-indene  and  petroleum  polymer  resins 

Polyester  resins 

Polyethylene  resins 

Miscellaneous  synthetic  plastics  and  resins:* 

Molding  materials 

Protective-coating  resins 

Resins  for  all  ether  uses 


287,821 
103,989 

8,531 
12,291 
17,650 


33,001 
62,299 
37,600 

260, 292 
79,129 

565,705 

43,520 

24,706 

124,130 


204,170 

43,673 
16,506 

55,165 
41,728 
47,678 
25,875 
36,811 

39,767 
25,520 

102,578 
24,022 
28',  740 
90,145 

401,610 
93,379 
108,470 

722,269 


78,447 
52,565 
204,828 
63,222 
65,752 
28,516 
73,796 

41,727 
113.416 


129,175 
53,425 

6,887 
5,962 
15,024 


29,402 
57,012 
35,910 

267,260 
69,285 

514,097 

40,967 

14,112 

112,919 


Dry  basis,  for  the  purpose  of  this  report,  is  defined  as  the  total  weight  of  the  material,  including 
resin,  plasticizers,  fillers,  extenders,  colors,  and  stabilizers,  and  excluding  the  weight  of  water,  sol- 
vents, and  other  liquid  diluents. 

^  Included  with  "All  other  bonding  and  adhesive  uses." 

^  Includes  data  for  styrene-alkyd  polyester  resins. 

*  Includes  data  for  acrylic,  epichlorohydrin,  polyamide  (nylon),  silicone,  and  other  synthetic  plastics 
and  resin  materials. 


Note. — The  figures  in  the  above  table  are  based  on  the  Commission's  monthly  reports  on  the  production  and 
sales  of  synthetic  plastics  and  resin  materials.  They  are  partially  estimated,  and  may  not  be  correlated 
exactly  with  those  given  in  table  19A.  The  data  given  in  the  above  table  are  in  substantial  agreement  with 
those  given  in  the  Commission's  release  for  January  1957,  which  gave  a  summation  of  the  data  reported  by 
months  for  1956.  Changes  in  classification  and  a  minor  increase  in  coverage  on  some  products  result  in  some 
differences  in  the  detail  figures  given  in  this  table  from  those  given  in  the  January  1957  report. 


44  UNITED  STATES  TARIFF  COMMISSION 

volume  of  production  in  the  nonbenzenoid  group,    was   566  million 
pounds  in-  1956,    compared  with  402  million  pounds  in  1955.    Sales 
of  polyethylene  resins  amounted  to  514  million  pounds,    valued  at 
1  88  million  dollars,  in  1956,  compared  with  350  million  pounds,  valued 
at  1  38  million  dollars,  in  1955.   The  output  of  urea  and  nraelamine  resins 
was  342  million  pounds  in  1956,  compared  with  328  million  pounds  in 
1955.  Sales  of  these  resins  amounted  to  31  1  million  pounds,  valued  at  9  2 
million  dollars,   in  1956,  conripared  with  300  million  pounds,  valuedat 
92  million  dollars,  in  1955.  Other  important  resins  in  the  nonbenzenoid 
group  are  acrylic,  polyamide,  silicone,  and  nonphthalic  alkyd  resins. 
The   statistics  on  the  production  and  sales  of  plastics  and  resins 
by  uses,    given  in  table   20,    were  compiled  principally  from  the 
Tariff  Commission's  monthly  surveys  of  production  and  sales  of 
synthetic  plastics  and  resin  materials.    The  largest  single  use  re- 
ported for  plastics  materials  in  1956--as  in  previous  years--was 
for  nnolding  and  extruding  into  finished  and  semifinished  forms. 
Other  important  uses  for  which  statistics  are  shown  are  for  sheet- 
ing and  film,    for  treatment  of  textiles  and  paper,    for  adhesives, 
and  for  protective  coatings. 

Rubber- Processing  Chemicals 

Rubber-processing  chemicals  are  organic  connpounds  that  are 
added  to  natural  and  synthetic  rubbers  to  give  them  qualities  neces- 
sary for  their  conversion  into  finished  rubber  goods.  In  this  report, 
statistics  are  given  for  cyclic  and  acyclic  compounds  by  use--such 
as  accelerators,  antioxidants,  and  peptizers.  Statistics  on  the  pro- 
duction and  sales  of  rubber-processing  chemicals  in  1956  are  given 
in  table  21A.^ 

Production  of  rubber-processing  chemicals  as  a  group  in  1956 
amounted  to  l67  million  pounds,    or  5.6  percent  less  than  the  177 
million  pounds  reported  for  1955.    The  decline  in  the  output  of 
rubber-processing  chemicals  resulted  from  a  decrease  in  the  con- 
sumption of  rubber  in  1956.    Sales  of  rubber-processing  chemicals 
were   132  million  pounds,    valued  at  81  million  dollars,    in  1956, 
compared  with  143  million  pounds,    valued  at  86  million  dollars,    in 
1955. 

The  output  of  cyclic   rubber-processing  chemicals  in  1956 
amounted  to  141  million  pounds,    or  4.  7  percent  less  than  the   148 
million  pounds  reported  for  1955.    Sales  were  111  million  pounds, 
valued  at  67  million  dollars,    in  1956,    compared  with  121  million 
pounds,    valued  at  70  million  dollars,    in  1955.   Also  included  in  this 
report  are  statistics  for  the  dithiocarbamic  acid  and  benzothiazole 
derivatives  that  are  used  as  accelerators.    Of  the  total  production 
of  cyclic  rubber-processing  chemicals  in  1956,    accelerators  ac- 
counted for  44.  7  percent,    antioxidants  for  50.6  percent,    and  other 
uses,    for  about  5  percent.    Statistics  on  the  production  and  sales  of 
amino  and  hydroxy  antioxidants  cannot  be  given  in  this  report  be- 
cause their  release  would  disclose  the  operations  of  individual  com- 
panies.   Analysis  of  the  data  on  amino  antioxidants,    however,    shows 
that  production  of  these  compounds  was  about  15  percent  lo^ver  in 
1956  than  in   1955.    Sales  of  "nonstaining"  antioxidants  in  1956  are 
estimated  to  have  been  12  million  pounds,    valued  at  8  million 
dollars. 


TSee  also  table  21B,  part  III,  which  lists  these  products  alphabetically  and  identifies  the  manu- 
facturers. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


45 


TARLE   21\. -Syntheti 


rganic   che 


icais:    United  States  product! 
1956 


and  sales  of  rubber-processing  chemicals , 


I  Listed  belcw  are  all  rubber-processing  chemicals  for  which  any  reported  data  on  production  or  sales  may  be 
published.  (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or 
where  no  data  were  reported.)  Table  21B  in  part  III  lists  separately  all  rubber-processing  chemicals  for 
which  data  on  production  or  sales  were  reported  and  identifies  the  manufacturer  of  each  ] 


Produc- 
tion 


Quantity 


Unit 
value''^ 


Grand  total 

RUBBER-PROCESSI^E  CHEMICALS,  CYCLIC 
Total 

Accelerators,  total 

Dithiocarbamic  acid  derivatives 

Thiazole  derivatives,  total 

2,2'-Dithiobis[ben2othiazole] 

2-Mercaptobenzothiazole^ 

All  other^ 

All  other  accelerators 

Antioxidants,  total^ 

Amino  and  hydroxy  compounds* 

Phenol,  alkylated 

All  other*— - 

Peptizers,   tackifiers.    Inhibitors,   and  blowing  agents 

RUBBER-PROCESSING  CHEMICALS,    ACYCLIC 

Total 

Accelerators,  total 

Dithiocarbamic  acid  derivatives,  total^ 

Dibutyldithiocarbamic  acid,  zinc  salt 

Diethyldithiocarbamic  acid,  zinc  salt 

Dimethyldithiocarbamic  acid,  potassium  salt 

Dimethyldithiocarbamic  acid,  sodium  salt  and  sodium  polj-sulfide- 
All  other 

Tetramethylthiuram  sulfides,  total^ 

Tetramethj'lthiuram  disulfide 

Tetramethylthiuram  monosulfide 

All  other 

Peptizers,  stabilizers,  and  lubricating,  conditioning,  and  blowing 

agents,  total 

Dodecyl  meroaptans 

All  other 


1,000 
pounds 

167,  U9 


1.000 
pounds 
132,231 


1,000 

dollars 

80,662 


wi,';9'; 


111,173 


67,253 


63,26^ 


265 
53,121 
18,202 
15,727 
19,192 
9,878 

71,553 


40,7.C8 


255 
31,851 
10,995 

3,221 
17,635 

8,642 

64,067 


24,138 


54,903 

1,630 

15,020 

6,677 


25,655 


49,631 
1,071 
13,365 

6,358 


21,058 


429 

17,118 

5,288 

1,204 

10,626 

6,591 

36,784 


28,738 
508 
7,538 

6,331 


13,409 


13,484 


9,469 


7,976 
1,271 
1,787 

208 
3,035 
1,675 
4,805 
3,515 
1,290 

703 


7,109 
5,062 


4,784 
1,084 
1,526 

1,089 
1,085 
4,297 
3,292 
1,005 


11,589 


8,362 


3,536 
952 


410 
1,284 
4,429 
3,313 
1,116 

397 


7,101 
4,488 


3,219 
1,828 


pound 

$0.61 


■  59 
1.68 
.54 
.48 
.37 
.60 
.76 


.58 
.47 
.56 


.64 

.88 
.74 


.38 
1.18 
1.03 
1.01 
1.11 
1.02 


.44 

.45 
.41 


^  Calculated  on  rounded  figures. 

^  Includes  small  quantities  produced  and  sold  for  uses  other  than  rubber  processing. 

^   Sales  of  "nonstaining"  antioxidants  are  estimated  at  12  million  pounds,  valued  at  8  million  dollars. 

*  Data  on  aldehyde-  and  acetone-amines  were  transferred  from  "all  other"  to  "amino  and  hydroxy  compounds" 
in  1955  and  1956  in  order  to  avoid  disclosing  the  operations  of  individual  producers  and  to  show  data  on 
total  antioxidants. 

'  Data  on  dithiocarbamates  included  in  this  table  are  for  material  used  exclusively  in  the  processing  of 
natural  and  synthetic  rubbers.  Data  on  dithiocarbamates  which  are  used  as  fungicides  are  reported  in  the 
section  "Pesticides  and  Other  Organic  Agricultural  Chemicals." 

'  Includes  data  for  small  amounts  of  tetramethylthiuram  sulfides  for  uses  other  than  in  the  processing  of 
natural  and  synthetic  rubbers. 


Production  of  acyclic   rubber-processing  chemicals  in  1956 
amounted  to  25.  7  million  pounds,    compared  with  the  28.  7  million 
pounds  reported  for  1955.    Sales  were  21.  1  million  pounds,    valued 
at  13.4  million  dollars,    in  1956,    compared  with  22.4  million  pounds, 
valued  at  15.  3  million  dollars,    in  1955.   Accelerators,    principally 
dithiocarbamic  acid  derivatives  and  tetramethylthiuram  sulfides, 
accountedfor  about  53  percent  of  the  output  of  acyclic   rubber- 
processing  chemicals  in  1956.    Peptizers  and  modifiers--chiefly 
dodecyl  mercaptans,    together  with  lubricating,    conditioning,    and 
blowing  agents  - -accounted  for  approximately  47  percent  of  the  out- 
put in  the  acyclic  group. 


46 


UNITED  STATES  TARIFF  COMMISSION 


Elastomers  (Synthetic  Rubbers) 

The  total  domestic  output  of  all  types  of  elastomers  (except 
vinyl  elastomers)  amounted  to  2,  314  million  pounds  in  1956,    com- 
pared with  2,  083  million  pounds  in  1955.    Vinyl  elastomers,    which 
previously  were  included  in  this  group,    are  now  included  in  the 
statistics  on  plastics  and  resin  materials  on  the  basis  of  their 
chemical  composition.    Sales  of  all  types  of  elastomers  in  1956 
amounted  to  2,  156  million  pounds,    valued  at  588  million  dollars. 
Statistics  on  the  production  and  sales  of  elastomers  are  given  in 
table  22A.» 

Production  of  cyclic  elastomers,    which  consisted  almost  en- 
tirely of  the  polybutadiene-styrene  (S-type),    amounted  to  1,808  mil- 
lion pounds  in  1956,    or   10  percent  more  than  the   1,  643  million 
pounds  reported  for  1955.    Sales  of  cyclic  elastomers  were  1,680 
million  pounds,    valued  at  403  million  dollars,    in  1956,    compared 
with  1,644  million  pounds,    valued  at  402  million  dollars,    in  1955. 
The  S-type  rubbers  are  used  principally  in  the  manufacture  of 
automobile  and  truck  tires. 

The  output  of  acyclic  elastomers  (except  vinyl  elastomers) 
amounted  to  506  million  pounds  in  1956,    compared  with  440  million 


TABLE  22A. -Syn  the  ti 


rganic   chemicals:    Vniteri  States   prociu 
1956 


nd  sales   of  elastc 


(synthetic    rubbers) , 


[Listed  below  are  all  synthetic  elastomers  for  which  reported  data  on  production  or  sales  may  be  published. 
(Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where 
no  data  were  reported.)  Table  22B  in  part  III  lists  alphabetically  all  elastomers  for  which  data  on 
production  or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Produc - 
tion 


Quantity 


Value    Unit  value^ 


Grand  total 

ELASTOMERS,  CYCLIC 

Total 

Polybutadiene-styrene  type  (S-type) 

All  other' 

ELASTOMERS,  ACYCLIC 

Total 

Polybutadiene-acrylonltrlle  type   (N-type)- 

Polychloroprene  type   ^Neoprene) 

Polylsobutylene-isoprene  type   (Butyl) 

All  other  acyclic  elastomers^ 


1,000 

pounds ^ 

2,3K,033 


1.000 

pounds^ 

2,155,856 


1,000 
dollars 
587,583 


Per 
pound 

$0.27 


1,807,69^ 


1,679,569 


'102,738 


1,797,637 
10,057 


506,339 


1,671,770 
7,799 


<;76,287 


398,695 
^,0^3 


76,286 
222,700 
165,8<il 

'il,512 


63,063 
218,600 


19^,  62^1 


31,069 
9-1,000 


59,776 


^  An  elastomer  is  defined  as  a  material  which  will  stretch  repeatedly  to  150  percent  or  more  of  its  origi- 
nal length  and  will  return  rapidly  and  with  force  to  its  approximate  original  state. 

^  Calculated  on  rounded  figures. 

^  Elastomer  content  basis. 

*  Includes  data  for  modified  S-types  and  for  polyurethane . 

'  Estimated  from  published  data  on  consumption,  inventories,  and  unit  prices. 

'  Includes  data  for  the  production  and  sales  of  THIOKOL  polysulfide  polymers,  polybutadlene,  polyiso- 
butylene,  and  silicone  elastomers,  and  natural  rubber  modifications;  and  for  sales  of  butyl  elastomer. 

Note. --Polyvinyl  elastomers,  formerly  shown  in  this  report,  are  now  covered  in  the  section  on  plastics  and 
resin  materials  on  the  basis  of  their  components.  Statistics  on  the  production  of  S-type,  N-type,  butyl,  and 
neoprene  elastomers  were  compiled  in  cooperation  with  the  Business  and  Defense  Services  Adioinistration, 
U.  S.  Department  of  Commerce. 


8  See  also  table  22B,  part  in,  which  lists  these  products  alphabetically  and  identifies  the  manu- 
facturers. 


SYNTHETIC  ORGANIC   CHEMICALS,  1956  47 

pounds  in  1955.    Sales  of  acyclic  elastomers  were  476  million 
pounds,    valued  at  185  million  dollars,    in  1956,    connpared  with  425 
million  pounds,    valued  at  170  nnillion  dollars,    in  1955,    The  acyclic 
group  of  elastomers  includes  oil-resistant  types  such  as  neoprene, 
special-purpose  types  such  as  butyl  (used  in  the  manufacture  of 
inner  tubes  for  tires),    N-types,    and  silicone  elastomers. 

Plasticizers 

Plasticizers  are  organic  chemicals  that  are  added  to  plastics 
and  resin  materials  to  extend  or  modify  the  natural  properties  of 
the  resins,    and  to  develop  new  and  improved  properties  not  present 
in  the  resins  themselves.    They  innpart  qualities  of  relatively  perma- 
nent flexibility,    toughness,    and  improved  flowing  properties  in  the 
molding  and  extrusion  presses.    Statistics  on  plasticizers  are  given 
in  table  23A.' 

The  total  domestic  output  of  all  types  of  plasticizers  amounted 
to  417  million  pounds  in  1956,    or  5.  2  percent  more  than  the  396 
million  pounds  reported  for  1955.    Sales  of  plasticizers  were  331 
million  pounds,    valued  at  106  million  dollars,    in  1956,    compared 
with  338  million  pounds,    valued  at  104  million  dollars,    in  1955. 

Production  of  cyclic  plasticizers  in  1956,    which  consisted  prin- 
cipally of  the  esters  of  phosphoric  acid  and  phthalic  anhydride, 
amounted  to  315  million  pounds- -slightly  more  than  the  output  of 
296  million  pounds  reported  for  1955.    Sales  of  cyclic  plasticizers 
were  244  million  pounds,    valued  at  73  million  dollars,    in  1956, 
compared  with  253  million  pounds,    valued  at  72  million  dollars,    in 
1955.    As  in  previous  years,    phthalic  anhydride  esters,    used  pri- 
marily in  the  production  of  vinyl  resins,    were  the  class  of  cyclic 
plasticizers  produced  in  the  largest  volume  in  1956.    The  output  of 
phthalic  anhydride  esters  in  1956  was  237  million  pounds;  sales 
amounted  to  176  million  pounds,    valued  at  51  million  dollars. 

Production  of  acyclic  plasticizers,    consisting  of  the  esters  of 
adipic,    azelaic,    oleic,    phosphoric,    sebacic,    stearic,    and  other 
acids,    amounted  to  101  million  pounds  in  1956,    compared  with  100 
million  pounds  in  1955.    Sales  of  acyclic  plasticizers  were  88  million 
pounds,    valued  at  34  million  dollars,    in  1956,    compared  with  85 
million  pounds,    valued  at  32  million  dollars,    in  1955. 


9 See  also  table  23B,  part  ni,  which  lists  these  products  alphabetically   and  identifies  the  manu- 
facturers. 


48 


TAHLE  23\.- -Syntheti 


UNITED  STATES  TARIFF  COMMISSION 

ganic   chemicals:    United  States   production   and  sales  of  plasticizers,    1956 


[Listed  below  are  all  plasticizers  for  which  reported  data  on  production  or  sales  may  be  published.  (Leaders 
are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were 
reported.  )  Table  23B  in  part  III  lists  all  plasticizers  for  which  data  on  production  or  sales  were  re- 
ported and  identifies  the  manufacturer  of  each] 


Produc - 
tion 


Sales 


Grand  total 

PLASTICIZERS,  CYCLIC 

Total 

Chemicals  for  which  separate  statistics  may  not  be  shown^ 

Chemicals  for  which  separate  statistics  are  shown  below 

Phosphoric  acid  esters; 

Tricresyl  phosphate-' 

Triphenyl  phosphate 

Phthalic  anhydride  esters,  total 

Butyl  decyl  phthalate 

Dibutyl  phthalate 

Dicapryl  phthalate 

Dicyclohexyl  phthalate 

Diethyl  phthalate 

Diisodecyl  phthalate 

Di(2-methoxyethyl)  phthalate  (Di (methyl  oellosolve)  phthalate] 

Dimethyl  phthalate 

Dioctyl  phthalates,  total 

Di(2-ethylhexyl)  phthalate 

Diiso-octyl,  di-n-octyl,  and  mixed  octyl  phthalates 

Octyl  deoyl  phthalate 

All  other 

PLASTICIZERS,  ACYCLIC 

Total 

Chemicals  for  which  separate  statistics  may  not  be  shown^ 

Chemicals  for  which  separate  statistics  are  shown  below 

Adipic  acid  esters,  total 

Didecyl  adipate 

Di(2-ethylhexyl)  adipate 

Dilso-octyl  adipate 

All  other 

Azelaic  acid  esters 

Glyceryl  monor ic inoleate 

Oleic  acid  esters,  total 

Butyl  oleate 

Methyl  oleate 

Ail  other 

Phosphoric  acid  esters 

Sebacic  acid  esters,  total 

Dibutyl  sebacate 

All  other 

Stearic  acid  esters,  total 

Butyl  stearate 

All  other 

Triethylene  glycol  difcaprylate-caprate) 


416,788 


315,30 


37,378 
277,965 


32,265 

8,318 


2.37,382 


3,869 

22,017 

3,667 

18,661 
17,038 
3,2-17 
A,  037 
111,661 
80,632 
31,029 
11,269 
41,916 


101,445 


42,789 
58,656 


8,504 


1,150 
1,128 
2,218 


9,474 
301 


1,858 

693 

7,533 

6,565 

11,702 


3,111 
8,591 


10,586 


7,085 

3,501 


1,440 


1,000 
pounds 
331,333 


1,000 
dollars 
106,489 


243,656 


72,502 


37,203 
206,453 


11,762 
60,740 


30,843 


175,610 


4,003 
15,481 
3,769 
2,292 
9,053 
10,015 

3,474 
81,624 
53,271 
28,353 

10,710 
35,189 


87,677 


9,834 


50,906 


1,1 

4,024 

1,070 

1,273 

2,270 

2,935 

899 
23,037 
15,065 
7,972 
3,357 
10,973 


33,987 


36,325 
51,352 


13,418 
20,569 


6,561 


2,867 


1,742 

1,536 

996 

2,287 

8,946 


7,691 


393 
7,298 
6,785 
9,386 


696 

614 

437 

1,120 

3,785 
93 

2,455 


90 
2,365 
2,937 
5,421 


8,586 
10,360 


6,904 
3,456 


1,335 


5i: 

4,908 


2,459 


1,492 
967 


^  Calculated  on  rounded  figures. 

^  Includes  data  for  synthetic  camphor,  certain  phosphoric  acid  esters,  toluenesulfonamides,  tetrahydro- 
furfuryl  oleate,  and  other  cyclic  plasticizers. 

^   Includes  material  produced  for  use  as  motor-fuel  additive. 

*  Includes  data  for  citric  and  acetylcitrio,  palmitic,  tartaric,  and  ricinoleic  acid  esters,  and  for  butyl 
myristate,  glyceryl  and  glycol  esters  of  certain  fatty  acids,  glyceryl  tripropionate,  complex  polymeric 
materials,  and  other  acyclic  plasticizers. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956  49 

Surface-Active  Agents 

The  surface-active  agents  covered  in  this  report  include  syn- 
thetic organic   detergents,    and  wetting,    dispersing,    penetrating, 
and  emulsifying  agents;  soaps  are  not  included.    As  the  data  in  this 
report  on  surface -active  agents  are  given  in  terms  of  100-percent 
active  material,    they  exclude  all  inorganic   salts,    water,    and 
diluents. 

Originally  developed  as  soap  substitutes  for  the  textile  industry, 
surface -active  agents  have  proved  valuable  in  many  other  applica- 
tions because  of  their  varied  and  specific  properties.    Today, 
packaged  household  and  industrial  detergents  account  for  about  75 
percent  of  the  total  output.    The  rest,    used  as  wetting,    dispersing, 
penetrating,    and  emulsifying  agents,    find  many  applications  in  the 
processing  of  textiles  and  leather,    in  ofe  flotation  and  oil-drilling 
operations,    and  in  the  manufacture  of  paints,    agricultural  sprays, 
lubricants,    cosmetics,    foods,    and  many  other  products. 

Statistics  on  production  and  sales  of  surface-active  agents  in 
1956  are  given  in  table  24A."      In  1956,    production  of  surface-active 
agents  as  a  group,    except  oil-soluble  petroleum  sulfonates  (a  type 
previously  included  in  this  group  but  now  included  with  lubricating 
oil  additives  in  the  group  of  miscellaneous  cyclic  chemicals), 
totaled  1,  148  million  pounds,    or  11.4  percent  more  than  the  1,031 
million  pounds  reported  for  1955."     Sales  were   1,047  million 
pounds,  valued  at  208  million  dollars,    in  1956,    compared  with  962 
million  pounds,    valued  at  229  million  dollars,    in  1955. 

In  1956  the  production  of  anionic  surface -active  agents  (sulfated 
and  sulfonated  cyclic  and  acyclic  compounds,    phosphorus -containing 
acyclic  compounds,    and  acyclic  salts  of  fatty  acids)  amounted  to  872 
million  pounds,    or  76.  0  percent  of  the  total  quantity  of  surface- 
active  agents  produced.    This  quantity  was  90  million  pounds  more 
than  the  output  in  1955.    Sales  totaled  805  million  pounds,    valued  at 
128  million  dollars,    in  1956,    compared  with  747  million  pounds, 
valued  at  155  million  dollars,    in  1955.    In  volume  of  production  in 
1956,    the  principal  items  in  the  anionic  group  were  the  dodecylben- 
zenesulfonic  acid  type  of  surface -active  agent  (457  million  pounds) 
and  the  sulfated  and  sulfonated  acids,    alcohols,    and  esters  (146 
million  pounds).    Data  on  production  of  the  nonionic  and  cationic 
surfactants  may  not  be  given  in  this  report  because  their  release 
would  disclose  the  operations  of  individual  companies.   However, 
production  and  sales  of  each  of  these  classes  of  surface -active 
agents  are  increasing  each  year;  production  and  sales  of  the  non- 
ionic  type  have  been  increasing  more  rapidly  than  have  production 
and  sales  of  cationic   surfactants. 


10  See  also  table  24B,  part  III,  which  lists  these  products  alphabetically  and  identifies  the  manu- 
facturers, 

11  Production  and  sales  data  for  1955  adjusted  to  reflect  transfer  of  oil-soluble  petroleum 
sulfonates  to  miscellaneous  chemicals. 


50 

TARLE  2AK--Syntheti 


UNITED  STATES  TARIFF  COMMISSION 


icals:    United  States  product i 


[Listed  below  are  all  surface -active  agents  for  which  reported  data  on  production  or  sales  may  be  published. 
(Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no 
data  were  reported. )  Table  24B  in  part  III  lists  all  surface-active  agents  for  which  data  on  production  or 
sales  were  reported  and  identifies  the  manufacturer  of  each] 


Grand  total 

SURFACE -ACTIVE  AGENTS,  CYCLIC 
Total 

Esters  and  ethers,  nonsulfonated-' 

Nitrogen-containing  surface-active  agents,  nonsulfonated, 

total* • 

Benzyllauryldimethylanmionium  chloride 

All  other 

Sulfated  and  sulfonated  cyclic  surface-active  agents,  total- 
Alkyl  benzenoid  compounds,  sulfated  and  sulfonated,  total- 

Dodecylbenzenesulfonic  acid  type 

All  other 

Lignin  derivatives,  sulfonated 

Naphthalene  derivatives,  sulfonated,  total 

Butylnaphthalenesulfcnic  acid,  mono  and  di 

Diamylnaphthalenesulfonic  acid 

Isopropylnaphthalenesulfonic  acid,  mono  and  di 

All  other 

Petroleum  aromatic  compounds,  sulfonated:^  V/ater-soluble- 

type  petroleum  sulfonate,  sodium  salt 

All  other  sulfated  and  sulfonated  cyclic  surface-active 

agents,  total' 

Toluene  sulfonate,  sodium  salt 

All  other 

SURFACE-ACTIVE  AGEHTS,  ACICLIC 

Total 

Esters  and  ethers,  nonsulfonated,  total' 

Dielhylene  glycol  monclaurate 

Diethylene  glycol  mono-oleate 

Diethylene  glycol  monostearate 

Glycerol  mono-oleate 

Glycerol  monostearate 

Polyethoxyethyl  dilaurate 

Polyethoxyethyl  dioleate 

Polyethoxyethyl  monolaurate 

Polyethoxyethyl  mono-oleate 

Polyethoxyethyl  monos  t  earate 

Polyethoxyethyl  tallow  ester 

Polyethoxyethyl  tridecyl  ether 

1,2-Propylene  glycol  monolaurate 

1,2-Propylene  glycol  monostearate 

All  other 

Nitrogen-containing  surface-active  agents,  nonsulfonated, 
total 

N-(Aminoethyl)-M-(hydroxyethyl)stearamide  'Stearamide  of 

aminoethylethanolajnine) 

Coconut  oil  amide  of  mono(diethanolamine  )  (Diethanol 

lauramide) 

Coconut  oil  amide  of  bis(diethanolamine) 

Coconut  oil  amide  of  diethanolamine,  neither  mono  nor  bis 
N,N-Di(2-hydroxyethyl)oleamide  (Diethanol  oleamide ) 

(Diethanolamine  oleate ) 

N,N-Di(2-hydroxyethyl)stearamide  (Diethanol  stearamide)-- 

Stearamide  of  diethylenetriamine 

All  other^ 

Phosphorus-containing  surface-active  agents,  nonsulfonated - 

Salts  of  fatty  acids,  nonsulfonated,  total 

Coconut  oil,  potassium  salt 

Potassium  laurate 

Potassium  oleate 

Potassium  tallate 

Sodium  oleate 

Sodium  stearate 


1,000 
pounds 

,U8,006 


751, 6U 


vg.-ivg 


12,562 


"593" 
11,964 


659,573 


i62,051 

'V57,267 

<4,78<; 

155,286 

7,655 

2,182 

90 

1,008 

A, 375 


29,322 

7,<!,77 
21,845 


396,392 


1U,20C 


1,046,821 


689,722 


64,633 


8,591 


595 
7,996 


616,498 


440,513 

435,761 

4,752 

137,997 

5,033 

2,177 

94 

2,762 


32,955 
7,394 
25,561 


357,099 


103,487 


~3T3" 

253 

i,690 

7,877 

12,247 

464 

462 

1,065 

2,101 

2,762 

488 

2,828 

173 

835  j 

80,140  i 


69,745 


2,232 

3,069 
3,585 

1,761 


1,287 

466 

56,357 

1,890 

10,322 


^^ 
125 
846 
721 
1,034 
741 


"53r 

219 

1,105 

7,803 

11,773 

465 

271 

859 

1,086 

1,668 

319 

2,879 

172 

837 

73,200 


65,160 


Unit 

Value      ,   2 
value" 


1.000 
dollars 

207,998 


1,937 

2,871 
2,998 
1,488 

1,041 

1,039 

439 

53,347 

1,173 

9,920 


45 
125 
575 
701 
1,015 
661 


18,726 


5,352 


657 
4,695 


86,296 


70,396 
69,176 
1,220 
5,053 
2,611 
1,357 
49 

1,205 


8,236 

756 

7,480 


97,624 


27,165 


273 
70 
301 
3,327 
3,114 
188 
134 
332 
390 
962 


253 
16,748 


2,052 

1,612 

1,073 

531 

399 

435 

271 

22,097 

685 

2,144 


54 
552 
135 
184 
207 


See  foctnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


51 


TABLE   2A^. -Synthetic  organi 


United  States   production  and  s 
Continued 


r face-active  agents,'  195S-- 


Unit 
value ^ 


SURFACE-ACTIVE  AGENTS,  ACYCLIC- -Continued 

Salts  of  fatty  acids,  nonsulfonated- -Continued 

All  other 


Sulfated  and  sulfonated  acyclic  surface-active  agents,  total-- 
Acids,  alcohols,  and  esters,  sulfated  and  sulfonated,  total — 

Oleic  acid,  sulfonated 

Lauryl  sulfate,  diethanolamine  salt 

Lauryl  sulfate,  sodium  salt 

Lauryl  sulfate,  triethanolamine  salt 

Isopropyl  sulfo-ole^te 

n-Propyl  sulfo-oleate 

All  other 

Nitrogen-containing  surface-active  agents,  sulfated  and 

sulfonated,  total 

Coconut  oil  amide  of  monoethanolamine,  sulfated, 

potassium  salt 

Coconut  oil  amide  of  monoethanolamine,  sulfated,  sodium 

salt 

All  other 

Oils,  fats,  and  waxes,  sulfated  and  sulfonated,  total 

Animal  fats  and  oils,  sulfated  and  sulfonated: 

Neat's-foot  oil,  sulfonated 

Tallow,  sulfonated 

Fish  and  marine-animal  oils,  sulfated  and  sulfonated: 

Cod  oil,  sulfonated 

Sperm  oil,  sulfonated 

Tall  oil,  sulfonated 

Vegetable  oils,  sulfated  and  sulfonated: 

Castor  oil,  sulfonated 

Coconut  oil,  sulfonated 

Mustard-seed  oil,  sulfonated 

Peanut  oil,  sulfonated 

Rice-bran  oil,  sulfonated 

Soybean  oil,  sulfonated 

All  other  oils,  fats,  and  waxes,  sulfated  and  sulfonated'- 


1.000 
pounds 

6,811 

200,235 


U6,138 

2,680 

194 

10,506 

3,095 

778 

l,'i91 

127, 39-; 

5,731 

113 

269 

5,349 

48,366 

1,870 
10,394 

3,214 

5,316 

334 

8,968 
599 
224 

2,048 

771 

295 

14,333 


i.OOO 
pounds 

6,798 

177,359 


136,310 

1,656 

178 

9,049 

3,083 

769 

1,269 

120,306 

5,582 

112 

248 

5,222 

35,467 

1,692 
8,526 

3,132 

2,608 

313 

6,917 

407 

94 

1,951 
323 
278 

9,226 


1,000 
dollars 

996 

39,160 


pound 
$0.15 


30,573 
600 
122 
4,879 
861 
381 
303 

23,427 

1,837 


120 
1,641 
6,750 

394 
1,234 

468 
503 
83 

1,370 
],04 
18 
545 
82 
79 
1,870 


.22 
.36 
.69 
.54 
.28 
.50 


"■  Data  are  given  in  terms  of  bulk  surface-active  agents,  that  is,  in  tenns  of  100-percent  content  of 
surface-active  agents,  exclusive  of  all  inorganic  salts,  water,  or  other  ingredients. 

^  Calculated  on  rounded  figures, 

^  Includes  polyhydric  alcohol  and  phenyl  ethers  and  esters. 

*  Includes  quaternary  ammonium  compounds. 

'  Oil-soluble-type  petroleum  sulfonates  used  chiefly  as  lubricating  oil  additives  were  transferred  to  mis- 
cellaneous cyclic  chemicals  in  1956. 

'  Includes  sulfated  and  sulfonated  phenyl  ethers  and  substituted  biphenyls. 

''  Includes  certain  lauric,  oleic,  and  stearic  acid  esters  reported  as  plastioizers  before  1953. 

'  Includes  amine  salts  of  fatty  acids,  esters  of  hydroxyamines ,  fatty  acid  amines,  quaternary  ammonium 
compounds,  salts  of  nitrilo  acids,  and  fatty  acid  derivatives  of  guanidine,  glycine,  polypeptides,  and 
others . 

'  Includes  sodium  salt  of  aliphatic  petroleum  sulfonate,  sulfonated  synthetic  Japan  wax,  sulfonated  re- 
covered grease,  sulfonated  lard  oil,  sulfonated  wool  grease,  and  other  sulfonated  animal,  fish,  and  vege- 
table oils. 

Pesticides  and  Other  Organic  Agricultural  Chemicals 

Pesticides  (fungicides,    herbicides,    insecticides,    and  rodenti- 
cides)  and  other  organic  agricultural  chemicals  such  as  fumigants, 
plant  hormones,    seed  disinfectants,    and  soil  conditioners  are 
covered  in  this  section  of  the  report.    As  in  other  sections  of  the 
report,    the  data  (except  where  otherwise  indicated)  are  given  in 
terms  of  100-percent  active  material;  they  thus  exclude  such  ma- 
terials as  diluents,    emulsifiers,    synergists,    and  wetting  agents. 
Statistics  on  production  and  sales  of  pesticides  and  other  organic 
agricultural  chemicals  in  1956  are  given  in  table  Z5A.  ^ 

In  1956  production  of  all  pesticides  and  other  organic  agricul- 
tural chemicals  amounted  to  570  million  pounds,    or  12.6  percent 


12  See  also  table  25B,  part  III,  which  lists  these  products  alphabetically  and  identifies  the 
manufacturers. 


52 


UNITED  STATES  TARIFF  COMMISSION 


TAHLF    2S\.  -Synthetic  organic  chemicals 


United  States  prodiii 
agricultural   chemica 


1956 


of   pesti 


[  Listed  below  are  all  pesticides  and  other  organic  agricultural  chemicals  for  which  any  reported  data  on 
production  or  sales  may  be  published.  (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence 
and  may  not  be  published  or  where  no  data  were  reported.  )  Table  25B  in  part  III  lists  all  pesticides  and 
other  organic  agricultural  chemicals  for  which  data  on  production  or  sales  were  reported  and  identifies 
the  manufacturer  of  each] 


Produc- 
tion 


Sales 


Quanti  ty 


Unit 
value^ 


Grand  total- 


PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL  CHEMICALS,  CYCLIC 
Total 


Fungicides  and  seed  disinfectants,  total- 
Mercury  fungicides 

Naphthenic  acid,  copper  salt 

Pent achlorophenol 

2,'i-,5-Trichlorophenol 

All  other 


Herbicides  and  plant  hormones,  total 

Naphthaleneacetic  and  naphthyloxyacetic  acid  derivatives- 
Phenoxyacetic  acid,  salts,  and  derivatives: 

(2,'i-Dichlorophenoxy)acetic  acid  (2,4-D) 

(2,'+-Dichlorophenoxy  )acetic  acid  esters,  total 

n-Butyl  2,4-dichlorophencxyaGetate 

Iso-oc tyl  2 , A-dichlorophenoxyace tate 

Isopropyl  2,^-dichlor&phenoxyacetate 

All  other 

(2,'i-Dichlorophenoxy)acetic  acid  salts 

(2,'i,5-Trichlorophencxy )acetic  acid   (2,4,5-T) 

(2,'i,5-Trichlorophenoxy)acetic  acid  esters,  total 

n-Dutyl  2,'4,5-trichlorophenoxyacetate 

Iso-oc  tyl  2,'i,5-trichlorophenoxyacetate 

All  other 

Phenylmeroury  acetate  (PMA) 

All  other 


Insecticides  and  rodenticides,  total 

Hexachlorocyclohexane  (Benzene  hexachloride)^ 

Parathion  (0,0-Dlethyl  O-(p-nitrophenyl)phosphorothioate) 

l,l,l-Trichloro-2,2-bis(p-chlorophenyl)ethane  (DDT) 

All  other' 


PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL  CHEMICALS,  ACYCLIC 


Total - 


Fumigants,  fungicides,  and  seed  disinfectants,  total 

Bromomethane  (Methyl  bromide) 

Diraethyldithiocarbamic  acid,  sodium  salt 

Dimethyldithiocarbamic  acid,  zinc  salt  (Ziram) 

Ethylene  bis(dithiocarbamio  acid),  disodium  salt  (Nabam)- 
All  other 


Herbicides,  insecticides,  rodenticides,  and  soil  conditioners, 

total 

Ethyl  pyrophosphate  (Tetraethylpyrcphosphate)  (TEPP)'^ 

All  other 


1,000 
pounds 
569,927 


72,975 


527 
2,012 

31,385 
6,735 

32,316 

69,884 


160 

28,835 

19, 476 

7,925 

1,210 

5,351 

4,990 

1,766 

5,169 

7,045 

425 

1,621 

4,999 

693 

6,740 

331,106 


84,599 

6,529 

137,659 

102,319 


95,962 


67,186 


10,204 
2,179 
1,436 
5,486 

47,881 


28,776 


28,776 


1,000 
pounds 

399,401 


1,000 
dollars 
172,908 


342,863 


135,257 


59,409 


530 
2,048 

25,055 
2,800 

28,976 

41,894 


18,869 


2,064 
673 
4,603 
2,268 
9,261 

31,200 


14,253 
14,308 
4,146 

821 
4,844 
4,497 
1,772 
1,799 
3,248 

168 

757 
2,323 

645 
5,771 

241 , 560 


70,988 

6,265 

107,892 

56,415 


56,538 


236 

4,951 
5,893 
1,930 

354 
1,749 
1,860 

852 
1,895 
3,278 

178 

730 
2,370 
3,916 
10,179 

85,188 


8,321 

7,842 

21,873 

47,152 


37,651 


31,709 


20,636 


9,148 
1,322 
1,353 
5,709 
14, 177 


24,829 


4,165 
291 
842 

2,826 
12,512 


17,015 


376 
24,453 


447 
16,568 


4;0.43 


.36 

.41 

.48 

1.05 

1.01 

1.06 

.96 

1.02 

6.07 

1.76 


1.25 
.20 
.84 


1.19 
.68 


■""  Calculated  on  rounded  figures. 

^  Production  of  the  gamma  isomer  content  in  benzene  hexachloride  totaled  14.7  million  pounds;  sales 
amounted  to  12.8  million  pounds. 

'  Combined  production  in  this  group  of  aldrin,  chlordan,  dieldrin,  endrin,  heptachlor,  and  toxaphene 
amounted  to  86,659  thousand  pounds.  Sales  totaled  43,041  thousand  pounds,  valued  at  35,936  thousand  dollars. 

*  TEPP  is  40  ethyl  pyrophosphate. 


more  than  the  506  million  pounds  reported  for  1955.    Sales  amounted 
to  399  nnillion  pounds,    valued  at  173  million  dollars,    in    1956,    com- 
pared with  415  million  pounds,    valued  at  153  million  dollars,    in 
1955. 

The  output  of  cyclic  pesticides  and  other  cyclic  chemicals  in 
this  group  totaled  474  million  pounds  in  1956,    or  10.4  percent  more 
than  the  429  million  pounds  produced  in  1955.    Sales  were  343  million 


SYNTHETIC  ORGANIC  CHEMICALS,  1956  53 

pounds,    valued  at  135  million  dollars,    in   1956,    compared  with  354 
million  pounds,    valued  at  1  Z6  million  dollars,    in  1955. 

Production  of  cyclic  insecticides  and  rodenticides  in   1956  was 
331   million  pounds,    or  58.  1   percent  of  the  total  output  of  all  organic 
pesticides  and  70.  0  percent  of  the  tot^al  output  of  cyclic  pesticides. 
Sales  in  1956  totaled  242  million  pounds,    valued  at  85  million 
dollars.    The  chemical  in  this  subgroup  that  was  produced  in  the 
greatest  quantity  in   1956  was  the  insecticide  DDT,    production  of 
which  amounted  to  138  million  pounds. 

The  output  of  acyclic  pesticides  and  other  acyclic  organic  agri- 
cultural chennicals  in  1956  amounted  to  96  million  pounds,    connpared 
with  the  77  million  pounds   reported  for   1955.    Sales  were   57  million 
pounds,    valued  at  38  million  dollars,    in  1956,    compared  with  61 
million  pounds,    valued  at  27  million  dollars,    in  1955. 

Miscellaneous  Synthetic  Organic  Chemicals 

As  used  in  this  report,    the  term  "miscellaneous  synthetic 
organic  chemicals"  refers  to  such  products  as  halogenated  hydro- 
carbons,   paint  driers,    photographic  chemicals,    solvents,    and 
tanning  materials  that  are  not  included  in  the  use  groups  covered  in 
the  other  sections  of  the  report.    Production  of  these  miscellaneous 
chemicals  as  a  group  totaled  25,  233  million  pounds  in  1956,    repre- 
senting an  increase  of  20.6  percent  over  the  20,925  million  pounds 
produced  in  1955.    Sales  totaled  10,  355  million  pounds,    valued  at 
1,  570  million  dollars,    in  1956,    connpared  with  9,  740  million  pounds, 
valued  at  1,439  million  dollars,    in  1955._  Statistics  on  production 
and  sales  of  miscellaneous  chemicals  in  1956  are  given  in  table 
26A .  " 

The  output  of  cyclic  miscellaneous  chemicals  as  a  group  totaled 
677  million  pounds  in  1956,    showing  an  increase  of  7.  7  percent  over 
the  629  million  pounds  reported  for  1955.   Sales  totaled  414  million 
pounds,    valued  at  130  million  dollars,    in  1956,    compared  with  410 
million  pounds,    valued  at  117  million  dollars,    in  1955.   On  the  basis 
of  use,    the  most  important  group  was  the  lubricating  oil  additives, 
including  oil-soluble  petroleum  sulfonates  which  formerly  were  in- 
cluded with  surface-active  agents.    Production  of  lubricating  oil 
additives  totaled  348  million  pounds  in  1956,    compared  with  336 
million  pounds  in   1955. 

In  1956  the  output  of  acyclic  miscellaneous  chemicals  as  a  group 
totaled  24,  556  million  pounds,    an  increase  of  21.  0  percent  from  the 
20,  296  million  pounds  reported  for  1955.    This  miscellaneous  group 
includes  chemicals  used  as  acyclic  intermediates,    solvents,    flota- 
tion reagents,    aerosol  propellents,    refrigerants,    and  for  other 
purposes.    Sales  of  acyclic  miscellaneous  chemicals  totaled  9,942 
million  pounds,    valued  at  1,440  million  dollars,    in  1956,    compared 
with  9,  330  million  pounds,    valued  at  1,  322  million  dollars,    in 
1955.  " 


i3See  also  table  26B,  part  UI,  which  lists  these  products  alphabetically  and  identifies  the  manu- 
facturers. 

"The  large  difference  between  production  and  sales  indicates  that  a  substantial  part  of  the  output 
of  acyclic  miscellaneous  chemicals  is  consumed  at  the  producing  plants  in  the  manufacture  of  more 
advanced  products.  Acyclic  miscellaneous  chemicals  so  used  are,  therefore,  acyclic  intermediates. 
Although  acyclic  intermediates  correspond  in  function  to  cyclic  intermediates,  the  chemical  industry 
does  not  commonly  recognize  any  special  group  of  acyclic  miscellaneous  chemicals  as  intermediates. 


54 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  26^. -Synthetic  organic  cbe 


als:    United  States   product i 


illaneous  chemicals,    1956 


[Listed  below  are  all  miscellaneous  chemicals  for  which  any  reported  data  on  production  or  sales  may  be  pub- 
lished. (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or 
where  no  data  v;ere  reported. )  Table  26B  in  part  HI  lists  alphabetically  all  miscellaneous  chemicals  for 
which  data  on  production  or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Production 


Quantity 


Grand  total - 


MISCELLANEOUS  CHIMICAI^,  CYCLIC 


Chemicals  for  which  separate  statistics  may  not  be  shown- 
Chemicals  for  which  separate  statistics  are  shown  below — 


Benzoic  acid  salts:  Sodium  benzoate,  tech.  and  U.S.P- 

Camphene 

Chemical  reagents 

Cyclopropane 


2,6-Di-tert-butyl-p-cresol,  total - 

Food  grade 

Tech 


Flotation  reagents,  total 

Thiocarbanilide  (Diphenylthiourea)- 
All  other 


Hexamethylenetetramine,  tech- 


Lubricating  oil  additives,  total^ 

Oil-soluble  petroleum  sulfonate,  calcium  salt- 
Oil-soluble  petroleum  sulfonate,  sodium  salt — 
All  other 


Naphthenic  acid  salts,  total-'  ''- 

Calcium  naphthenate 

Cobalt  naphthenate 

Iron  naphthenate 

Lead  naphthenate 

Manganese  naphthenate 

Zinc  naphthenate 

All  other 


Photographic  chemicals,  total 

Benzotriazole 

p-Diazo-N,N-diethylaniline,   zinc  chloride  salt- 
All  other 


n-Propyl  gallate — 
Research  chemicals- 


Rosin  acid  salts,   total-'- 

Lead  resinate 

All  other 


Tall  oil  salts,   total-* 

Cobalt  tallate 

Lead  tallate 

Manganese  tallate — 
All  other 


Tanning  materials,   synthetic,   total 

2-Naphthalenesulfonic  acid,    formaldehyde  condensate  and  salt- 
All  other 


Textile  chemicals,   other  than  surface- active  agents- 
MISCELLAMEOUS  CHBCCALS,    ACYCLIC 
Total 


Chemicals   for  which  separate  statistics  may  not  be  shown- 
Chemicals   for  which  separate  statistics   are  shovm  below — 


25,232,537 


10,355,466 


1.000 

dollars 

1,569,877 


676,844 


190,212 
486,632 


4,110 
22,899 


10,440 


1,673 
8,767 


5,653 


"S9 
5,234 


29, 290 


347,  S 


94,752 

78,509 

174,719 

18,309 


1,13 

3,441 

124 

10,491 

1,794 

812 

515 

4,929 


109 
4,807 


5,367 


2,190 

2,168 

498 

511 

34,945 


26,073 
8,872 


1,270 


24,555,693 


6,766,663 
17,789,030 


413,823 


129,720 


125,286 
288,537 


58,089 
71,631 


4,108 

21 
116 

10,025 


1,525 
8,500 


4,273 


1,518 


128 
1,928 


8,370 


1,514 
6,856 


1,393 


4,273 
19,701 
187,303 


1,393 

3,515 

32,415 


63,570 
123,733 


17,346 


8,737 
23,678 


5,670 


1,077 

3,094 

128 

10,095 

1,704 

795 

453 

4,674 


4,574 


5,097 


2,036 

2,109 

478 

474 

33,608, 


25,237 
8,371 


1,176 


9,941,643 


425 
1,927 
43 
2,290 
529 
296 
160 

6,411 


73 
207 
6,131 

127 
565 


1,782 


1,001 
528 
128 

125 

5,902 


4,034 


1,690 


1,440,157 


2,018,915   618,974 
7,922,728   821,183 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


55 


TABLE   26A. --Synthetic  organic   chemicals:    United  States   production   and  sales  of  . 

/956--ContinueH 


Production 


Quantity         Value 


MISCELLANEOUS  CHEMICALS,   ACYCLIC— Continued 

Acetaldehyde 

Acetic  acid,   synthetic  100^' 

Acetic  acid  salts,   total 

Aluminum  acetate 

Ammonium  acetate 

Lead  subacetate 

Magnesium  acetate 

Potassium  acetate 

Uinc  acetate 

All  other 

Acetic  anhydride,  100^,  from  all  sources 

Acetone,  total 

By  fermentation 

From  isopropyl  alcohol 

All  other 

Acrylonitrile 

Adipic  acid 

Amines,  total 

n-Butylamlne 

Dinethylamine 

Ethylenedi  amine 

Methyl amine,  mono 

Octylamine 

All  other 

Bis(2-chloroethyl)  ether  (Dichlorodiethyl  ether) 

Butyl  acetates,  9056,  total 

Primary,  normal 

All  other 

Butyl  alcohols,  100$,  total 

Primary,  normal 

All  other 

Carbon  disulfide 

Cellulose  esters  and  ethers,  total 

Cellulose  acetate 

Sodium  carboxymethylcellulose,  lOO^t 

All  other 

Chloral  (Trichloroacetaldehyde) 

Chloroacetic  acid,  mono 

2-Chloro-N, N-dimethylethylamine  (Dimethylaminoethyl 
chloride)  hydrochloride 

Citric  acid  salts,  total 

Potassium  citrate 

All  other 

Diethylene  glycol 

Diethyl  malonate  (Malonic  ester) 

2-Dimethylaminoethanol 

Ethanolamines,  total 

Monoethanolamine  ( 2-Aminoethanol ) 

Diethanolamine  (2,2'-Aminodiethanol) 

Triethanolamine  (2,2  ', 2"-Nitrilotriethanol) 

Ethyl  acetate,  855t 

Ethyl  alcohol,  synthetic' 

a-Ethyloaproic  (2-Ethyl-l-hexoic )  acid  salts,  total-- 

Calcium  a-ethylcaproate 

Cobalt  a-ethylcaproate 

Lead  a-ethylcaproate 

Manganese  a-ethylcaproate 

Zinc  a-ethylcaproate 

All  other 


See  footnotes  at  end  of  table. 


1,000 
pounds 


549,818 
17,143 


324 
278 
78 
21 
816 
614 
15,012 

909,736 

606,643 


35,806 
78,575 


16,358 


23,494 

499,184 

83,965 

140,569 


228,865 


353 
275 


735 
14,941 


324,242 


1,000 
dollars 
2,976 
6,589 

3,183 


21,92'' 
228,326 
73,989 

113,412 
21,603 

55,234 


164 

114 
30 

211 

2,664 

21,340 


17,942 
1,871 

208,300 

9,461 

82,253 


64,128 
18,125 


515,031 


"521 

7,937 

14,468 

1,764 

18 

30,626 


76,085 


1,565 
15,539 
4,236 

30,606 
6,806 

23,550 


220 

2,619 

6,306 

548 

12 

13,845 


9,574 


60,327 
15,758 


182,261 


8,105 
1,469 


23,169 


223,414 
291,617 


555,142 
665,918 


142,465 
39,796 


485,420 
198,991 


19,228 
3,941 


24,563 

79,000 


450,306 
24,237 
191,375 

37,105 
45, 


5,441 


198,991 

11,651 
58 


79,000 

2,226 

120 


T36 
5,285 

91,920 

1,188 

617 

93,359 


29,147 
40,428 
23,784 

90,816 
1,275,506 

1,174 


74,920 
269 


76,053 


10,266 
216 


18,050 


'  27,372 
26,227 
22,454 

76,666 
615,974 

1,122 


6,735 
6,303 
5,012 

7,528 
30,993 


210 
123 
19 
154 
570 


93 
210 
115 

19 
136 
549 


pound 


56 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  26^.- -Synthetic   organic   chemicals:    United  States  production   and  sales   of  miscellaneous   che 

7956- -Continued 


Quantity    Value 


MISCELLANEOUS  CHEMICALS,  ACYCLIC --Continued 

Ethylene  glycol 

Ethylene  oxide 

Ethyl  ether,  total 

Technical  grade 

All  other 

Ethyl  formate 

Ethyl  silicate 

Fats  and  oils,  chemically  modified 

Fatty  acid  esters  not  included  with  plasticizers  or  surface- 
active  agents 

Fatty  and  synthetic  higher  alcohols  (Cio  and  higher),  total- 

Decyl  alcohol 

1-Hexadecanol  (Cetyl  alcohol) 

All  other 

Flotation  reagents 

Formaldehyde,   375i  HCHO  by  weight 

Formic  acid,   90?i- 

Formic  acid  salts,   total 

Aliiminum  formate 

Ammonium  formate 

All  other 

Halogenated  hydrocarbons,  total 

Carbon  tetrachloride 

Chlorinated  paraffins,  total 

35-64^  chlorine 

All  other 

Chloroethane  (Ethyl  chloride),  all  grades 

Chlorofonn,  tech.  and  U.S.? 

Chloromethane  (Methyl  chloride),  all  grades 

1,2-Diohloroethane  (Ethylene  dichloride) 

Dichloromethane  (Methj'lene  chloride),  all  grades 

Tetrachloroethylene  (Perchloroethylene) 

Trichloroethylene 

Vinyl  chloride  (Chloroethylene ) ,  monomer 

All  other 

Iso-octyl  alcohol  (6-Methyl-l-heptanol) 

Isopropyl  alcohol'' 

Lactic  acid,  IOO5S,  total 

Edible  and  medicinal 

Tech 

Lauroyl  chloride 

Linoleic  acid  salts,  total^ 

Calcium  linoleate 

Cobalt  linoleate 

Lead  linoleate 

All  other 

Lubricating  oil  additives,   total 

Sulfurized  speim  oil 

All  other 

Methanol,  synthetic* 

Methyl  acetate 

1-  and  2-Octancl 

Oleic  acid  salts,  total'' 

Aluminum  oleate 

Lead  oleate 

All  other 

Oxalic  acid 

Oxalic  acid  salts 

Palmitic  acid  salts:  Zinc  palmitate 

Palmitcyl  chloride 

Pentaeryxhritol 

Pentaerythritol  tetranitrate 

Polyacrylic  acid,  sodium  and  potassium  salts 

Polyethylene  glycol 

See  footnotes  at  end  of  table. 


1,020,656 
1,0A3,097 


84,536 


pounds 

439,233 

130,911 

76,607 


1.000 
dollars 
52,740 

19,5c/. 

6,072 


80,344 
4,192 


6,835 
546 


8,841 
166, 546 


72,937 
3,670 

131 

5,861 

312 

7,736 

44,248 


643 
165,903 

24,491 

1,399,249 

16,642 

22,348 


20,069 

686 

23,493 

21,464 

710,867 

15,829 


3,341 
2,731 


2,596 
129 


2,446 
10,829 


4,059 

221 

6,549 

5,731 
22,649 
2,386 


1,108 
9 
21,231 

3,952,673 


302,480 

52,846 

26,855 

25,991 

645,524 

46,308 

41,564 

613,442 

95,391 

185,628 

346,056 

596,520 

1,026,914 

42,557 
1,062,974 

4,97; 


9 
18,127 


1,674,250 


3,852 
1,120 


1,097 

1,014 


269,603 

43,087 

17,424 

25,663 

145,841 

31,199 

27,327 

109,098 

89,277 

168,951 

303,195 

103,878 

382,794 

36,676 
390,996 

4,751 


1,234 
222,617 


20,626 

6,031 

2,025 

4,006 

10,302 

4,708 

3,213 

6,044 

10,005 

17,256 

32,687 

11,133 

100,612 

6,983 

22,757 


3,679 
1,072 


1,499 
276 


255 

225 

56 

478 

120,760 


6,651 
114,109 

1,592,199 
12,240 
3,809 


34 
627 


21,265 


277 
6,171 


21,265 

888,697 

2,322 

290 


6,171 

34,823 

552 

99 


55 
164 

17,825 
4,169 
417 
86 
57,120 
2,117 
4,710 
24,902 


65 

65 

160 

17,135 
4,286 


49,463 
2,009 
3,831 

21,410 


27 


2,867 
1,062 


16,002 
1,513 
1,427 
5,410 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


57 


TABLE  2f A. --Synthetic  orga 


als:    United  States  product  ion  and  sales  of  miscel laneous   chemicals 
1956- -Continued 


Unit 
value^ 


MISCELLANEOUS  CffiMICAI^,  ACi:CLIC--Continued 


Polyglycerol 

Propionic  acid 

Propylene  glycol  (1,2-Propanediol) 

Research  chemicals 

Sarcosine  (N-Methylaminoacetic  acid)- 


Sequestering  agents,  total 

(Ethylenedinitrilo)tetraacetic  acid  (Ethylenediamine- 

tetraacetic  acid) 

(Ethylenedinltrilo)tetraacetio  acid,  monosodium  iron  salt- 

(Ethylenedinitrilo)tetraacetic  acid,  tetrasodium  salt 

All  other 


52 
18,711 
81,053 

85 

9,815 


1,000 
pounds 

5,977 

72 

6,179 


1.000 
dollars 

1,158 

296 

2,966 


Sodium  formaldehyde  sulfoxylate- 

Stearic  acid  salts,    total^° 

Aluminum  stearates,   total 

Aluminum  distearate 

All  other 

Cadmium  stearate 

Calcium  stearate 

Lead  stearate 

Lithium  stearate 

Magnesium  stearate 

Zinc  stearate 

All  other 


1,823 

5,553 
2,439 

5,898 

23,128 


Thioglycolio  acid  salts:  Ammonium  thioglycolate — 

Tri ethylene  glycol 

Urea  in  compounds  or  mixtures  (lOO^t  basis),  total ^ 

Urea  in  solid  fertilizer 

Urea  in  fertilizer  solution 

All  other 

Vinyl  acetate,  monomer 

Zinc  formaldehyde  sulfoxylate 


6,326 
4,395 
1,931 
8 
4,704 

706 
47 

975 
7,520 
2,842 

1,487 
19,719 
841,801 


1,467 

355 

3,127 

1,230 

5,485 

21,665 


6,138 
4,31 
1,907 
6 
4,471 

576 
56 

812 
6,920 
2,686 

1,393 

15,613 

747,220 


614 

294 

1,437 

621 

1,118 

8,243 


2,231 
1,536 

695 

6 

1,631 

221 
29 

333 
2,697 
1,095 

1,663 

2,873 

36,719 


343,379 
151,093 
347,329 
163,873 
1,318 


288,337 

143,501 

315,382 

83,437 

1,192 


13,322 
7,971 
15,426 
13,210 
513 


Ptr 
pound 


$0.19 
4.11 


.42 

.83 
.46 
.50 


.41 

1.19 
.18 
■  05 
.05 
.06 
.05 


.16 
.43 


^  Calculated  on  rounded  figures. 

^  Includes  oil-soluble  petroleum  sulfonates  which  were  formerly  included  with  surface-active  agents. 

^  Quantities  are  given  on  the  basis  of  solid  naphthenate,  resinate,  tallate,  or  linoleate  content. 

*  Statistics  exclude  production  and  sales  of  copper  naphthenate.  Statistics  on  copper  naphthenate  are 
given  in  the  section  "Pesticides  and  Other  Organic  Agricultural  Chemicals." 

'  In  addition,  production  of  natural  acetic  acid  totaled  22,226  thousand  pounds. 

''  Statistics  on  production  of  ethyl  alcohol  from  natural  sources  by  feimentation  are  issued  by  the  Alcohol 
Tax  Unit,  U.  S.  Internal  Revenue  Service. 

'  Data  which  were  reported  on  the  basis  of  91  percent  isopropyl  alcohol  have  been  converted  to  a  100-per- 
cent basis. 

*  In  addition,  production  of  methanol  from  natural  sources  totaled  15,146  thousand  poimds. 

'  Statistics  exclude  production  and  sales  of  potassium  oleate.  Statistics  on  potassium  oleate  are  given  in 
the  section  "Surface-Active  Agents." 

■'•°  Statistics  exclude  production  and  sales  of  potassium  and  sodium  stearate.  Statistics  on  these  stearates 
are  given  in  the  section  "Surface-Active  Agents." 

^^  Production  of  urea  in  primary  solution  totaled  844,846  thousand  pounds. 


Production  of  halogenated  hydrocarbons  (a  group  consisting  of 
chlorine,    bromine,    fluorine,    and  iodine  derivatives  of  hydrocarbons) 
totaled  3,953  million  pounds  in  1956,    compared  with  3,494  million 
pounds  in  1955.    This  subgroup  includes  such  chemicals  as  ethyl 
chloride,    ethylene  dichloride,    and  monomeric  vinyl  chloride. 

The  output  of  most  of  the  acyclic  miscellaneous  chemicals  that 
are  produced  in  large  volunae  was  higher  in  1956  than  in  1955.    Pro- 
duction of  synthetic  methanol  was   1,  592  million  pounds  in  1956, 
compared  with  1,  344  million  pounds  in  1955;  of  formaldehyde, 
1,  398  million  pounds,    compared  with  1,  259  million  pounds;    of 
synthetic  ethyl  alcohol,    1,  276  million  pounds,    compared  with  1,  215 
million  pounds;  of  isopropyl  alcohol,    1,063  million  pounds,    com- 
pared with  925  million  pounds;  of  ethylene  oxide,    1,  043  million 
pounds,    compared  with  960  million  pounds;  of  ethylene  glycol,    1,021 
million  pounds,    compared  with  888  million  pounds;  and  of  acetic 
anhydride,    910  million  pounds,    connpared  with  842  million  pounds. 


1 

I 


PART  ni.  ALPHABETICAL  LIST  OF  INDIVIDUAL  PRODUCTS, 
BY  GROUPS,  AND  NAMES  OF  MANUFACTURERS 

This  section  of  the  report  consists  of  (l)  a  series  of  tables  that 
supplement  the  statistical  information  given  in  parts  I  and  II,    and 
(2)  a  Directory  of  Manufacturers.    The  tables  with  numbers  that  in- 
clude the  letter  "B"  supplement  the  tables  in  part  I  or  part  II  with 
numbers  that  include  the  letter  "A";  for  example,    table  8B  in  part 
III  supplements  table  8A  in  part  II. 

Each  table  in  part  III  lists  alphabetically  the  individual  items  in 
each  group  for  which  data  on  production  or  sales  were  reported  for 
1956.    Where  an  asterisk  (*)  precedes  the  name  of  an  item  in  the 
tables  in  part  III,    separate  statistics  for  the  item  are  given  in  the 
tables  in  part  I  or  part  II.    The  manufacturers  of  each  product  are 
indicated  by  identification  numbers,    which  are  listed  in  the  Direc- 
tory of  Manufacturers  (table  27).    A  few  companies,    however,    have 
specifically  requested  the  Tariff  Commission  to  withhold  such  in- 
formation on  certain  items.    These  manufacturers  are  indicated  by 
the  letter  "X"  in  the  tables. 

Tar  Crudes 


T^BLE  W. --Organic   chemicals:    Tar   crudes 


for   which  United  States  product i 
by  manufacturer ,    2956 


reported,  identified 


[Tar  crudes  for  which  separate  statistics  are  given  in  table  4A  are  marked  below  with  an  asterisk  (»); 
products  not  so  marked  do  not  appear  in  table  ^A  because  the  reported  data  are  accepted  in  confidence  and 
may  not  be  published.  Manufacturers'  identification  niimbers  shown  below  are  taken  from  table  27.  Table  27 
identifies  all  United  States  producers  of  tar  crudes  (except  producers  who  report  to  the  Division  of 
Bituminous  Coal,  U.  S.  Bureau  of  Mines)] 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27)^ 


«Crude  light  oil 

Light-oil  distillates: 

»Benzene,  specification  and  industrial  grades: 

1° 

2° 

90<t 

All  other 

♦Toluene: 

Nitration  grade,  1° 

Piife  commercial  grade,  2° 

»}!ylene : 

3° 

Commercial 

♦Solvent  naphtha 

»A11  other  light-oil  distillates 

Pyridine : 

Crude  bases 

Semi"  refined  or  denaturing  grade 

♦Naphthalene,  crude,  solidifying  at — 

Less  than  7A°  C 

74°  C.  to  less  than  76°  C 

76°  C.  to  less  than  79°  C 

♦Crude  tar-acid  oils,  having  a  tar-aoid  content  of 

5'f,  to  less  than  2'i% 

2^%  to  50<f, — - 

♦Cresylic  acid,  crude 

♦Creosote  oil  (Dead  oil): 

♦Distillate  as  such 

♦Creosote  in  coal-tar  solution 

♦All  other  distillate  products 

♦Tar,  road 


15-;,  305,  372. 


537,  558. 

367,  558. 

558. 

259,  305,  505,  535. 

535,  537,  558. 

259,  305,  367,  505,  558. 

367,  537. 

259,  505,  535,  537,  558. 

152,  256,  259,  305,  367,  505,  512,  513,  537, 

558. 

152,  367,  558. 

367,  558. 

367,  558. 

131,  152,  382,  512,  513. 

152,  233,  256,  367,  512,  513. 

233,  259,  367,  372,  512,  537,  558,  609. 

233,  393,  512,  537,  558. 

256,  367,  512,  513,  558. 

367,  512,  513,  558,  609. 

131,  15i,  172,  233,  367,  372,  382,  393,  512, 

513,  537,  5^,  558,  562,  572. 

233,  367,  372,  512,  558. 

152,  256,  259,  367,  393,  5*58,  572. 

230,  233,  259,  367,  393,  512,  513,  544,  558. 


See  footnote  at  end  of  table. 


59 


60 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  4B.- -Or^a 


chemicals:    Tar 


rudes    for   which  United  States   product  ion  or 
by  manufacturer ,    J956- -Continued 


ere  reported,    identified 


Product 

Manufacturers'  identification  numbers 

(according  to  list  in  table  27)^ 

»Tar  for  other  uses: 

131,  233,  367,  372,  393,  512,  513,  558,  562, 
572. 

512,  513,  558. 

131,  154,  172,  233,  367,  372,  382,  512,  513, 
544,  558,  562,  572. 

367,  382,  512,  513,  558. 
259,  367,  382,  512,  .513,  558. 
233,  367,  512,  513,  544. 

Pitch  of  tar: 

»Hard:  Water  softening  point -- 

»Pltch  of  tar  coke  and  pitch  emulsion 

■'■  Does  not  include  manufacturers '  identification  numbers  for  producers  who  report  to  the  Division  of 
Bituminous  Coal,  U.  S.  Bureau  of  Mines.  These  producers  are  listed  in  the  U.  S.  Bureau  of  Mines  Information 
Circular  "Oven  Coke  Plants  in  the  United  States  as  of  December  31,  1956"  (in  press). 

Crude  Products  From  Petroleum  and  Natural  Gas 
for  Chemical  Conversion 


TABLE  SB.  'Synthetic  organic  chemicals:   Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion 
for  which  United  States  production  or  sales  were  reported,    identified  by  manufacturer ,    1956 

[Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  separate  statistics  are 
given  in  table  5A  are  marked  below  with  an  asterisk  ( •) ;  products  not  so  marked  do  not  appear  in  table  5A 
because  the  reported  data  are  accepted  in  confidence  and  may  not  be  published.  Manufacturers'  identifica- 
tion numbers  shown  below  are  taken  from  table  27.  An  X  signifies  that  the  manufacturer  did  not  consent 
to  the  publication  of  his  identification  number  with  the  designated  product] 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


ARCMATICS  AND  NAPHTHENES 

»Alkyl  aromatics,  distillates,  and  solvents' 

•Benzene  (except  motor  grade): 

»Benzene,  1° 

•Benzene,  2' 

•Cresyllc  acid,  crude 

Cyclopentadiene 

•Naphthenic  acids: 

Acid  number  less  than  150 

•Acid  number  150-199 

Acid  number  200-224 

•Acid  number  225-249 

Acid  number  250  and  over 

Sodium  carbolate  and  phenate,  crude 

•Toluene : 

•Nitration  grade,  1° 

•Pure  commercial  grade,  2° 

Solvent  grade 

All  other 

•Xylenes,  mixed: 

•Aviation  grade 

•Nitration  grades,  3°  and  5° 

•All  other 

All  other  aromatics  and  naphthenes 

ALIPHATIC  HYDROCARBONS 

Ci  hydrocarbon:  Methane 

•Cj  hydrocarbons: 

Acetylene 

•Ethane-- 

•Ethylene 

•C3  hydrocarbons : 

•Propane 

•Propane -propylene  mixture 

•Propylene 


146,  211, 
565,  X. 

134,  146, 
214,  251, 

552. 
263,  278, 
481. 

408,  419. 
211,  395, 
338,  395, 
211,  311, 
211. 
338. 

134,  146, 
221,  251, 
529. 
304,  479, 

134,  146, 
373,  419, 
134,  214, 
211,  284, 


214,  252,  284,  338,  405,  434,  550, 


325  419,  481. 

252,  284,  304,  331,  446,  479,  529, 


331,  528,  609. 


419,  552. 

552. 

331,  338,  395,  552. 


331,  373,  419,  446. 

252,  331,  419,  434,  479,  4S1,  528. 

552. 

251,  479,  528,  552. 

479. 

331,  419,  434,  479,  552. 

405,  465,  481,  516. 


186,  258,  269,  516. 

221,  481,  537. 

186,  211,  258,  269,  284,  408,  508,  516,  529. 
186,  221,  252,  269,  284,  338,  367,  405,  408, 
444,  480,  481,  508,  529,  X. 

186,  211,  214,  227,  251,  258,  269,  302,  331, 
341,  373,  508,  516,  528,  529,  550. 

338,  408,  X. 

141,  252,  263,  269,  284,  331,  373,  444,  481, 
508,  516,  529,  603,  X. 


\ 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


61 


TABLE  SB. --Synthetic  organic  chemic 
for  which  United  States  product ic 


Crude  products  (rom  petroleum  and  natural   das  for  chemical   conversi 
sales  were   reported,    identified  by  manufacturer ,    J956- -Continued 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


ALIPHATIC  HYDROCARBONS— Continued 

*C^   hydrocarbons: 

*1,3-Butadiene,  grade  for  rubbers  (elastomers) 

»Butadiene  and  butylene  fractions 

Butane-butylene 

»n-Butane 

1-Butene 

2-Butene 

»1-Butene  and  2-butene  mixture 

Butylene  concentrate 

»Isobutane 

»Isobutylene 

All  other 

*C5  hydrocai'bons: 

Isopentane 

Isoprene 

n-Pentane 

1-Pentene,  2-pentene,  and  mixtures 

C6  hydrocarbons: 

Diisopropyl  (2,3-Dimethylbutane) 

Hexane 

Isohexane 

Neohexane 

All  other 

C7  hydrocarbons: 

n-Heptane 

Heptenes 

Isoheptane  and  isoheptene 

All  other 

Cg   hydrocarbons: 

Dlisobutylene 

n-Ootane 

All  other 

Hydrocarbons,  Cg  and  above ; 

»l-Dodecene  (Tetrapropylene) 

Eicosane 

»Nonene  (Tripropylene) 

Polybutene 

Triisobutylene 

All  other 

»Hydrooarbon  derivatives : 

tert-Butyl  mercaptan 

Di-tert-butyl  disulfide 

Isopropyl  mercaptan 

Methyl  mercaptan 

tert-Octyl  mercaptan 

All  other 


129,  13A,    Ul,  200,  252,  28A,  341,  342,  426, 

434,  465,  481,  529,  552. 

134,  252,  373,  405,  552,  603. 
251. 

134,  141,  186,  227,  251,  258,  331,  341,  516, 

528,  550,  552. 

134,  516. 
516. 

214,  269,  284,  331,  338,  341,  408,  465,  528. 
516. 

134,  186,  251,  258,  269,  331,  341,  516,  550. 

134,  269,  284,  311,  341,  373. 

186,  434,  508,  529. 


227, 

251, 

269, 

516. 

284. 

227, 

516. 

1?':., 

227, 

341, 

408,    516,    550,    585. 

516. 

227, 

434, 

516. 

516. 

516. 

516. 

227, 

434, 

44^, 

516. 

214, 

227, 

338. 

516. 

284, 

516. 

278, 

341, 

481. 

227, 

434, 

516. 

516. 

214,  251,  284,  302,  331,  373,  405,  419,  434, 

552. 
278. 

214,  278,  284,  405,  408,  419,  434. 
146,  552. 
278. 
405,  444,  516,  518,  528. 

516. 

516. 

552. 

214,  263,  552. 

516. 

278,  AAA,    516,  552,  585. 


62 


UNITED  STATES  TARIFF  COMMISSION 


Cyclic  Intermediates 


TABLE  7B.  --Synthetic  organic  chemicals:     Cyclic  intermediates   for  which  United  States    production    or  sales 
were  reported,    identified  by  manufacturer,    1956 

[  Cyclic  intermediates  for  which  Eeparate  statistics  are  given  in  table  7A  are  marked  below  with  an  asterisk 
(»);  cyclic  intermediates  not  so  marked  do  not  appear  in  table  7A  because  the  reported  data  are  accepted 
in  confidence  and  may  not  be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from 
table  27.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification 
number  with  the  designated  product.  (Part  C  in  the  appendix  lists  alphabetically  all  the  important  common 
names  of  cyclic  Intermediates  usually  encountered  in  the  trade  and  gives  the  corresponding  standard 
(Chemical  Abstracts)  name  under  which  the  manufacturers'  identification  numbers  are  given  in  this  table)] 


Chemical 


Manufacturers '  Identification  nimibers 
(according  to  list  in  table  27) 


Acenaphthene 

8-Acetamido-5-amino-2-naphthalenesulfonlc  acid 

6(and  7)-(2'-Acetamido-4'-aminDphenylazo)- 
1-naphthalenesulfonic  acid. 

2-Acetamido-3-chloroanthraqulnone 

l-Acetamldo-2-methoxynaphthalene 

8-Acetnmi" do-2-nBphthalenesulf odIc  acid,  magnesium 
salt. 

p-Acetamldophenol 

5-Acetamldosallcyllc  acid 

»Acetanillde,  tech.  and  U.S.P 

o-Acetanlsldide 

Acetoacetanlllde 

o-Acetoacetotoluldlde 

Acetophenone 

p-Acetotoluldlde 

21-Acetoxy-^-bromo-17-hydroxy-3,ll,20-trlketo- 
pregnane. 

21-Aoetoxy-17-hydroxy-3,ll,20-trlketopregnane 

N-Acetylanthranilic  acid 

Acetylphenyl  benzoate 

Acetylsulfadiazlne 

Acetyls ulfamerazine 

Acetylsulfamethazine 

Acetylsulfamethylthiadlazole 

N-Acetylsulfanilic  acid 

N-Acetylsulfanllyl  chloride 

Acridine 

Acridine  yellow 

Alkylbenzene   (high  ncleoular  weight) 

3'-Amlnoacetanilide 

»4'-Amlnoacetanlllde  (Acetyl-p-phenylenediamine) 

<i-AminD-o-aoetanlsldide 

3'-Amlnoacetophenone 

*5-Amino-2-(p-amlnDanllino)benzenesulfonic  acid 
('4,'4'-Dlaminodlphenylamlne-2-sulfonlc  acid) . 
<i-Amlno-'4-(p-amlnobenzamldo) -2,2' -stllbenedisulfonlc 

acid. 
l-Amlno-4-(A''  -amlno-3 '  -sulf  oani  lino)  -2-anthra- 
quinonesulfonlo  acid. 

5-Amlno-2-anlHnobenzenesulfonlc  acid 

2-AminD-"i-(<i-anilino-6-chloro-s-trlazln- 
2 -ylsmi no ) benzenesulf onlc  acid. 

*2-(p-Amlnoanllino)-5-nltrobenzenes\ilfonic  acid 

3-Amino-p-anisanlllde 

5-Amino-2-(o-anlsidino) benzenesulf onlc  acid 

■**l-Aminoanthraqulnone  and  salt 

*2-AminoanthraquinDne  atvI  salt 

l-Amino-2-anthraqulnonecarboxyllc  acid 

l-Aiiiino-2-anthraquinonesulfonlo  acid 

5(and  8)-Amlno-l-anthraqulnonesulfonlo  acid 

N-(4-Amino-l-anthraqulnDnyl)aathranillc  acid 

N-(5-AmlnD-l-anthraquinDnyl)anthranillc  acid 

N-(8-Amlno-l-anthraquinDnyl)anthranillc  acid 

■i-Aminoantlpyrine 

'i-Amino-3, -4' -azodi[ benzenesulf onic  acid] 

*6-Amlno-3,'i'-azodi[benzenesulfonic  acid] 

8-AminDbenz[a]acridin-7(12H)-one 

*l-Amlno-4-benzamldoanthraqulnone 

1 -Ami no-5-benzfflnidoanthraqul none 

6-{  p-(p-Aminobenzamido)benzamldo]  -l-naphthol-3- 

sulfonlc  acid. 
5-(m-Aminobenzamldo) -l-naphthol-3-sulfonic  acid 

*6-(p-Amlnobenzamido) -l-naphthol-3-sulfonlc  acid 

»2-Amlno-p-benzenedisulfonlc  acid  [S03H=1] 

2-Amlnobenzene thiol 

5-AmlnD-2(3H) -benzlmldazolone 

p-Aminobenzoic  acid,  dlethylaminoethyl  ester 

p-Amlnobenzoic  acid,  ethyl  ester  (Benzocaine, 
nonmedicinal  grade) . 

»p-AminDbenzolc  acid,  tech 

5-AmiED-8-bromo-l,6-anthraqulnonedisulfonic  acid 

*l-Amlno-4-bramo-2-anthraiiulnonesulfonlc  acid 


512. 
253. 
577. 

510. 
510, 
253. 

221. 

221,  252,  443,  485. 

506. 

157,  529. 

157,  529. 

558. 

485,  537. 

X. 


253. 
492. 
537. 
537. 
537. 
537. 
604. 
221, 
512. 
506. 
278. 
577. 
253, 
510. 
492. 
253, 


537,  560. 


429,  443,  500,  506,  510,  577,  604. 
288,  329,  401,  506,  510,  577,  604. 


510. 


457,  506,  510,  537,  577,  604,  605. 
506,  510,  537,  577. 


253,  506,  510,  577. 
577. 

288,  401,  506,  577. 

371. 

577. 

253, 

253, 

253. 

510. 

577. 

510. 

253. 

253, 

348. 

401. 

288,  506,  510,  577,  604. 

506. 

253, 

253, 

253. 


506,  510,  537,  605. 
457,  506,  510,  577. 


401,  506,  577,  604. 

253,  288,  401,  506,  510,  604. 

253,  401,  506,  510,  577. 

537. 

253. 

348. 

348, 

253,  506,  510. 

577. 

253,  506,  510. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


63 


TABLE  7B.--Syntheti 


organic    chemicah 
were   reported. 


:    Cyclic    intermediates    for   which  United  State 
identified  by  manufacturer ,   i956- -Continued 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


2-Amlno-l-bromo-3-cliloroanthraqulnone 

l-Amlno-2-bromo-'4-bydroxyanthraiiuinone 

l-AminD-<i-bromo-2-methylanthraqulnDne 

l-AiiiinD-2-bromo-"i-(p-toluidino)anthraqulnone 

l-AnlnD-2-chloroanthraqulnone 

»1 -Ami  no-5-cliloroanthraqul  none 

l-AminD-5(aiid  8)  -chloroanthraqulnone 

l-AminD-8-chloroanthraqulnone 

2-Amino-l-cliloroantliraqulnone 

«2-AmlnD-3-ohloroanthraquinone 

l-Amlno-N-C3-chloro-2-anthraquinonyl)- 
2 -anthraqulnonecarboxamlde . 

3-Amlno-6-olilorobenzolo  acid 

2-AminD-6-clilorobenzothlazole  hydrochloride 

2-Amino-5-chlorobenzoxazole 

o-(3-Amlno-'4-chlorobenzoyl) benzoic  acid 

2-Amlno-5-chloro-A-ethylbenzenesulfonic  acid 

l-Amlno-5-chloro-4-hydroxyanthraquinone 

2-AmlnD-5-chloro-4-lsopropylbenzenesull'onic  acid 

2-AminD-'4-chloro-5-m.trophenol 

2-Ainino-6-ohloro-'4-nltrophenol 

»2 -Amino -'i-chlorophenol 

2-Amino-'4-chloro-l-phenol-6-sulfonic  acid 

2-Amino-4-chlorophenylbenzyl  ether 

«2-Amin£)-5-chloro-p-tolueneEUlfonic  acid  [S03H=l] 

6-Amlno-<4-chloro-m-toluenesulfonlc  acid  [  S03H=1] 

3-Amino-'4-chloro-a,a,a-trifluorotoluene 

»l-AminD-2,'i-dibromoanthraqulnone 

<l'-Amlno-2',5'-diethoxybenzffnilide 

5-Amino-2-{ 2,3-dihydro-2-oxo-5-benzimidazolyl) - 
benzenesulfonic  acid. 

2-AminD-<4,6-dimethylpyrlmidine 

3-Amino-N,N-dimethyl-p-toluenesulfonnTTn"de 

2-AminD-3,5-dinitro-N-ethylbenzenesulfonamide 

2-Amino-N-ethylbenzenesulf onani lide 

3-AmlnD-9-ethylcarbazole( sodium  hydrosulfate) 

p-Amino-N-ethyl-N-1-naphthylbenzamlde 

5-AminD-8-(p-hydToxyanilino)-2-naphthaleneEulfonic 

acid. 
5(and  8) -Amino -8 (and  5)-(p-hydroxyanllino)-2- 
naphthalenesulfonlc  acid. 

l-Amlno-4-hydroxyanthraquinone 

3-Amino-2-hydroxyanthraqulnDne 

3-Amino-6-hydroxy-2-methylphenazinfi  (Tolazine 
base) . 

5-Aminoisophthalio  acid,  dimethyl  ester 

2-Amlno-N-iEopropyl-l-phenol-4-sulfonamide 

l-Amino-A-methoxyanthraquinone 

5-Amino-6-methoxy-2-naphthn1 enesulf onlc  acid 

m-(4-Aminamethoxyphenylazo) benzenesulfonic  acid 

2-AminD-5-methoxy-p-tolueneEulfonamlde 

l-AminD-2-methoxy-'i-(p-toluenesulfonamldo)- 

anthraquinone . 
7-(4-Amino-5-methoxy-o-tolylazo)-l,3- 

naphthalenedisulfonlc  acid. 
8  -  ( "* -Amino  -  5 -methoxy-o -tolylazo )  - 1 -naphthol  -  3 , 6 - 
disulfonic  acid,  benzenesulf onate . 

A'-Amlno-N-methylacetanllide 

l-Amino-2-methylaiithraquinone 

i'-Amlno-6'-methyl-m-benzanlsidlde 

2-Amino-5-(6-methyl-2-benzothlazolyl)benzene- 
sulfonlc  acid. 

2-Amino-4-methyldiazine 

'i-Amlno-<i'-(3-methyl-5-oxo-2-pyrazolln-l-yl)- 

stilbenesulfonic  acid. 
3-AminD-5- ( 3-methyl-5-oxo-2-pyrazolin-l-yl ) - 
p-toluenesulfonlc  acid. 

8-Amino-7-methyl-2-phenazinol 

2-Amino-N-methyl-l-phenol~t-sulfonnnrlde 

2-Amlno-5-methyl-l,3,<i-thladiazole 

l-AminD-2-methyl-'i-(p-toluidlno)anthraxiulnone 

l-Amlnonaphth[2,3-c]  acridane-5,8,l';(13H)  -trlone 

4-Amlnonaphth[2,3-c]  acri.dane-5, 8, 1-^(1311)  -trlone 

2-AmlnD-l,5-naphthalenedisulfonic  acid 

2 -Amino -1,5 (and  1,8) -naphthalenedisulf onlc   acid 

»3-Amlno-l,5-naphthalenedlsiilfonlc  acid   (Cassella 
acid). 

3-Amino-2,7-naphthalenedlsulfonlc  acid 

4-ATin" nn-1 , 5-naphthalenedisulf onlc  acid 

A-Amino-l,6-naphthalenedisulfonlc  acid-- 

'i-Amino-l,7-naphthalenedlsulfonlo  acid 

<»6-Anlno-l,3-naphthalenedlBulfonio  acid   (Amino  I 
acid) . 


510. 

457,    506,    537,   577,   605. 

537. 

506. 

457,    510. 

510,   577. 


440,   506,    510,   577. 
288,    577. 


460,   485,    537. 
485,    510. 


457,   506,   510. 


510. 
510. 
577. 


577. 
577. 


510. 
457. 


506,    510,   577. 


577. 
506. 


61,   253,  401,   506,   510,   577. 


64 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  TB. --Synthetic     organic       chemicals:     Cyclic       intermediates    for   which  United  States   product i 
were   reported ,    identified  by  manufacturer ,    1956--Continued 


Manufacturers '  identification  numbers 
(according  to  list  In  table  27) 


7-Amino-l,3-naphthRl enedisulf onie  acid  (Amino  G 
acid). 

8-Amiiio-l,6-naphthalenedisulfonlc  acid 

l-Amlno-2-naphtlialenesulfonic  acid  (o-Naphthionlo 
acid) . 

»2-Amino-l-naphthalenfiSulfonic  acid  (Tobias  acid) 

"♦(and  5)  -Amino-l-naphthnl  enesulfonic  acid 

»5-Amino-l-naphtbn1 enesulf onic  acid  (Laurent's  acid)- 
»5-Amino-2-naphthalenesulfonic  acid  (1,6-Cleve'6 

acid). 
»5(and  8) -Amino-2-naphthnT enesulfonic  acid  (Cleve's 
acid,  mixed) . 

6-AminD-l-naphthalenesulfonlc  acid 

*6-Amlno-2-naphtha1  enesulfonic  acid  (Broenner's 
acid) . 

6(and  7)-Amino-l-naphthalenesulfonic  acid 

■K6-AminD-l-naphthaleneEUlfonic  acid  (Peri  acid) 

8-Amino-l-naphtha1  enesulfonic  acid,  sodium  salt 

«8-Amino-2-naphthRl enesulfonic  acid  {1,7-Cleve's 
acid). 

7-Amino-l,3,6-naphthalenetrisulfonic  acid 

»8-Amino-l,3,6-naphthalenetriEUlfonlc  acid  (Koch's 

acid) . 
4-Amino-l ,3 , 5-naphtba1.enetri sulfonic  acld-'V,5- 
sultam,  trisodlum  salt. 

S-Amino-l-naphtboic  acid 

5-Amino-l-naphthol 

7-Amino-2-naphthol 

»8-Amlno-2-naphthol 

7-AminD-l-naphthol-3,6-dlsulfonic  acid   (2R  acid), 

monosodlum  salt. 
8-Ainino-l-naphthol-3,6-dlsulfonic  acid, 
benzenesulf onate . 
»8-AminD-l-naphthol-3,6-disulfonlc  acid   (H  acid), 

monosodium  salt. 
»8-Amino-l-naphthol-5,7-disulfonlc  acid   (Chicago 
acid) ,  monosodium  salt. 

»l-Amlno-2-naphthDl-'i-sulfonic  acid   (1,2,'i-Acid) 

»6-Amino-l-naphthol-3-sulfonlc  acid  (J  acid), 

sodium  salt. 
»7-Amino-l-naphthol-3-sulf  onic  acid  (Gamma  sicid) , 
sodium  salt. 
8-Amino-l-naphthol-5-sulfonic  acid  (S  acid) , 
sodium  salt. 

5-AminD-2-(p-nltroanilino) benzenesulf onic  acid 

»2-Amino-5-nitrobenzenesulfonic  acid  [SOjHil] 

*2 -Amino -<4-nitrophenDl 

2-AmlnD-5-nitrophenol 

6-Amino-<4-nitro-l-phenol-2-sulfonic  acid 

'i-AminD~4'-nitro-2,2'-stllbenedlsuli'onic  acid 

3 ' -Aminooxanllic  acid 

*^ ' -Ami nnoxnni lie  acid 

p-Amlnophenethyl  alcohol 

( 2 '-Amlnophenethylthlo) acetic  acid,  sodium  salt 

m-Amlnophenol 

o-Andnophenol 

p-Aminophenol  ani  salts 

6-Amlno-l-phenol-2,4-disulfonic  acid 

«2-Amlno-l-phenol-'4-sulfonamlde 

6-AminD-l-phenol-3-sulfonamlde 

2-Amlno-l -phenol -<l-sulfonanilide 

«2-Amino-l-phenol-'4-sulfonlc  acid 

m-(p-Aminophenylazo) benzenesulf onic  acid 

»p-(p-Aminophenylazo) benzenesulf onic  acid 

5(aiid  8) -Amino -8 (and  5) -phenylazo-2- 
naphthalenesulfonlc  acid, 

5- (p-Aminophenylazo) salicylic  acid 

4-AminD-ci -phenyl -m-cresol  hydrochloride 

2-(p-Aminophenyl)-6-methylbenzothiazole 

2-(p-Aminophenyl) -6-methyl-7-benzothlazoleEulfonic 
acid  and  salt. 
»l-(m-Aminophenyl)-5-oxo-2-pyrazoline-3-carboxylic 
acid. 

2-Amlnopyrldine 

i-AminDpyrldine 

2-Aminopyr1  ml  dine 

S-Ainlnosallcyllc  acid 

2-AmlnD-5-(p-sulfophcnylazo) benzenesulf onic  acid 

2-('>-Amino-3-sulfophenyl)-6-methyl-5-benzothlazole- 

sulfonic  acid. 
2-["i-('i-AminD-2-sulfostyryl)  -3 -sulf ophenyl]  -2H- 

naphtho[l,2]triazole-5-sulfonic  acid. 
2-AminDthiazole 


253, 

506, 

510, 

537, 

577 

510, 

577. 

253. 

ICK, 

485, 

537, 

577, 

X. 

537, 

577. 

253, 

506, 

510, 

577. 

253, 

506, 

510, 

577. 

253, 

506, 

510, 

577. 

-iOl. 

448, 

485, 

502, 

506, 

577 

577. 

253, 

506, 

510, 

577. 

253. 

253, 

506, 

510, 

577. 

253. 

253, 

506, 

510. 

510. 
506, 
577. 
253, 
253, 


221, 
253, 

253, 

61, 

253, 

506, 

604. 

253, 

253, 

401. 

288, 

510, 

401, 

253, 

443. 

253. 

61, 

213. 

213, 

577. 

253, 

577. 

577. 

253, 

577. 

253, 

577. 

577. 
477. 
253, 
253, 


510,    577. 
506. 


253,    506,    510. 
506,   577. 


401,   506,   510,   537,   577. 
191,   253,   288,  401,  453,    510,    537,    577. 


506,   510,    577. 
577. 


506,    537,    577. 
288,    506,   510,   577. 

577. 
577. 
577. 
401,   510. 


510. 

253,  403. 

506,  510,   577. 

267,  447,   506,   510,    577,   604. 

288,  401,    506,   510,    537,   577. 


506. 
577. 


401,   492,    577. 
512. 


577,   604. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 

TABLE  7B, •'Synthetic     organic      chemicals:     Cyclic       intermediates    for   which  United  State 
were  reported ,    identified  by  manufacturer ,    i956- -Continued 


65 


production  or  sales 


Manufacturers'  Identlfloation  numbers 
(according  to  list  In  table  27) 


I 


l-Anlno-^-(p-toluene6Ulfonaiiildo)-2-anthraquinone- 
sulfonlc  acid. 

»4-Amlno-m-toluenesulfonic  acid  [S03H=l] 

4.-Ajnino-o-toluenesulfonlc  acid  [S03H=l] 

5-AiiiinD-o-toluenesuli"onic  acid  [s03H=l] 

6-Amino-m-toluenesulfonlc  acid  [S03H=l] 

5-Aiiiino-2-Cp-toluldino)benzenesulfonic  acid 

7-(4-Amlno-o-tolylazo) -l,5-naphth«1  enedisulfonie 
acid. 

*4-(i-Aiiiino-m-tolylazo)  -m-toluenesulTonlc  acid 

N-(4-Amino-m-tolyl) -p-benzoqulnone  imine 

3-Aniino-l,2,4--triazole 

2-AiiiinD-3,'4,6-trichlorophenol 

16-Aiiiinoviolanthrone 

«2-Ami nn-3 , 5-xylenesulf onic  acid  [SOsH^l] 

Anylnaphthalenes 

o-Anylphenol 

p-tert-Amylphenol 

■"Aniline   (Aniline  oil) 

Aniline  salt 

l-Anllino-2-anthraquinonecarboxylio  acid 

2-AniUnoethanol   ( Phenyletbsnnlamine ) 

5-(p-[4-Anilino-6-(8-hydroxy-3,6-disulfo-l- 
naphthylamino)  -s  -triazin-2-ylaiii1  no]  phenylazo)  - 
salicylic  acid. 

»Anllinomethanesulfonic  acid  and  salt 

«6-Anilino-l-naphthalenesulfonio  acid   (Phenyl  perl 
acid) . 

»6-Anllino-l-naphthol-3-sulfonic  acid   (Phenyl  J 
acid) . 

♦V-Anilino-l-naphthol-S-sulfonic  acid   (Phenyl 
gamma  acid) . 

2-Anilino-5-nitrobenzenesuli'onlc  aold 

Anisic  acid 

«o-Anieldine 

p-Anlsldine 

o-Anisldlne  nitrate 

«3-Anlsidinomethanesulfonic  acid  (o-Methoxyanllino- 
methanesulfonio  aold),   and  sodium  salt. 

5-(p-Anlsidlno) -l-naphthol-3-sulfonic  acid 

2-(o-AnisldlnD)-5-nltrobenzenesulfonic  acid 

(2-(o-Methoxyanllino)-5-nltrobenzenesulfonic  acid] 

Anlsole,  tech 

Anthracene,   refined 

Anthraflavic  acid   (2,6-Diliydroxyanthraquinone) 

•fAnthranillo  acid   (o-Amlnobenzolc  acid) 

»Anthra{l,9]  pyrazol-5(2H)-one   (Pyrazoleanthrone) 

AnthraqijliiDne ,   IOO56 

2-AnthraqulnDnecarboxyllc  aold 

N,N'-(l,5-AnthraquliiDne)dioxamlo  aold 

»1,5-An.1<hraquinonedlsulfonlo  acid 

1,5-AnAhraqulnonedisulfonic  acid,  disodlum  salt 

l,5(ai)d  1,8) -Anthraqulnonedlsulf onic  acid  and  salt-- 
1,8-Aiithraqulnonedisulfonic  acid,  potassium  salt 

»2,6-Anthraquiiioiiedisulfonlc  acid  and  salt 

»l-Anthraqulnonesulfonic  aold  and  salt 

2-Anthra<iuiiionesulfonlc  acid  and  salt   (Silver 
salt). 

»3 - ( 1 -AnthraquinDnylaminD ) -7H-benz [de] airthraoen-7- 
one. 

N,N'-(l,5-Anthraquinonylene)diaiithranillc  acid 

1,1'- [1,5 (and  l,8)-AnthraqulnonylenediiminD]- 

blB[naphth[2,3-c]  aoridane-5,8,l'i-trione]. 
l-(l-Anthra(iuinDnyl)  -1,2-hydrazlnedieulfonlc  acid, 
disodlum  salt. 

■xAnthrarufln  (1,5-Diliydroxyanthraquliione) 

Arsanillc  acid  and  salt,  tech 

Arylsilanes 

4  ',<4"'-A2obls['C-biphenylcarboxylic  aoid] 

l,l'-[Azobis(p-phenyleneoarbor.yl)]bis[2-(l-nltro- 

2-anthraquinonecarbonyl )hydrazine ] . 
2,2'-(Azo-p-phenylene)bis  [5-(l-nitro-2-anthra- 

/    quinonyl)-l,3,'i-oxadiazole]. 

Azoxybenzene 

3,3  '-Azoxydianiline 

»Benzaldehyde ,   tech 

Benzamide 

4-(4-Benza]iiido-l-anthra<iulnonylainino)  - 
naphth[ 2 , 3-c] acridane-5 ,8 , l^-trione . 
l-Benzajnldo-A-bromoanthraqulnone 

*l-Benzamido-A-chloroanthraqulnone 

»l-Benzamldo-5-ohloroanthraquinone 


510. 

253,  A35,  i-92,   502,    506,   510,    537,    577. 

-iOl,  485. 

510. 

253. 

253. 

577. 


401,    506. 


577. 
352,  492,   506,   510. 


252,   253,  455,    506,   537. 

537. 

506. 


253,   288,   401,   506,   537,    577. 
253,   288,    506,   510,   577. 


253,   288,  401,  447,  453,   506,    510,   577,   604. 
253,   288,   510,   577,   604. 


504. 

221, 

253, 

604. 

221, 

253, 

506. 

401, 

510. 

253, 

288, 

401, 

506, 

577. 

604. 

577. 

253, 

365. 

512. 

510. 

252, 

253, 

267, 

385, 

506. 

253, 

506, 

510. 

253, 

510, 

537. 

537. 

510, 

577. 

253, 

-^57, 

510, 

537, 

577. 

253. 

253, 

577. 

457, 

510, 

577. 

253, 

457, 

506, 

510, 

537, 

577,   604. 

253, 

«7, 

506, 

510, 

537, 

577,   604,   605 

253, 

506, 

604. 

510, 

537, 

577, 

605. 

253, 

577. 

253. 

253. 

253, 

288, 

506, 

510, 

537, 

577. 

456. 

484. 

253. 

253. 

253. 

267. 

401, 

510. 

266, 

303, 

504. 

457, 

477. 

253. 

604. 

253,    510,   577,   605. 

253,   457,   506,   510,    537,   577. 


66 

TABLE  7B.  --Syntheti 


UNITED  STATES  TARIFF  COMMISSION 

'ganic     chemicals:    Cyclic      intermediates   for  which  United  State 
were  reported,    identified  by  manufacturer,   1956 --Continued 


product  i 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


l-Benzamldo-5-chloro-'i-methoxyanthraQUlnone 

2- [S-C-i-Benzamido-a ,  5-dletho3typbei'yl) -l-'oethyl- 

trlazen-3-yl]  ethanesulfonio  acid. 
2-{  3-(A-Benzamldo-2,5-dimethoxyphenyl) -1-methyl- 

triazen-3-yl]  ethanesulfonie  acid. 
[  3- (■4-Benzaniido-6-methoxy-in-tolyl) -l-metSyltriazen- 
3-yl]acetic  acid. 

A-Benzamido-S-methyl-o-anisidlne 

6-Benzanildo-l-naphthol-3-sulfonlc  acid   (Benzoyl 

J  acid). 
Benzanilide 

»7H-benz  [de]  aiithracen-7-one  ( Benzanthrone ) 

m-Benzenedlsulfonic  acid  and  sodium  salt 

Benzenephosphonic  acid 

Benzenephosphonic  acid,  dioctyl  ester 

Benzenesulfonamlde 

Benzenesulfonic  acid 

Benzene sulfonic  acid,  propyl  ester 

Benzenesulfonic  acid,  sodium  salt 

Benzenesulfonyl  chloride 

Benzhydrol  (Diphenylmethanol) 

Benzidine  base 

^Benzidine  hydrochloride  and  sulfate 

Benzil  (Bibenzoyl) 

»Benzllic  acid 

2-Benzoazolinone 

2-Benzofuranacetonitrile 

•Benzoic  acid,  teoh 

Benzoin 

Benzonitrile 

2-Benzooxazolinone-6-sulfonamide 

2-Benzooxazolinone-6-sulfonylchloride 

Benzotriazole ,  tech 

Benzoylacetic  acid,  ethyl  ester 

Benzoylacrylic  acid 

«o-Benzoylbenzoic  acid 

10-Benzoyl-3,7-bis[dimethylaminolphenothiazlne 

Benzoyl  chloride 

2-Benzoyl-4--sulfobenzoic  acid  ('i-Sulfo-o-benzoyl- 
benzoic  acid)  (Sulfo  BB  acid). 

2-Benzoyl-'i'-(p-toluenesulfonamido)acetanllide 

Benzyl  alcohol,  tech 

Benzylamine 

o-Benzyl-p-chlorophenol 

Benzyl  disulfide 

»Benzyl  ether  (Dibenzyl  ether) 

'i-(N-Benzyl-N-ethylaminD) -o-toluenesulfonic  acid 

N-Benzyl-N-ethyl-m-toluldine 

•4,4'  -Benzylidinebis[N,N-diethylaniline] 

'i,4.'-Benzylidinebis[N,N-dimethylanlline] 

4-Benzylidineiminoantipyrlne 

Benzyl  polysulfide 

2-Benzylpyridine 

4-Benzylpyridine 

4'-<i"'-Biacetoacetanilide 

3,3'-Bianthra[l,9]pyrazole-6,6'(2H,2'H) -dione  and 

potassium  salt. 
[3,3'  -Bi-7H-benz[de]anthracen]-7,7'-dione 

*[A^,A'  -Bi-7H-benz[de]anthracen]-7,7'-dione 

endo-cis-Bicyclo[2,2,l] -5-heptene-2,3-dicarboxyllc 
anhydride. 

[  l,l'-Binaphth£ilene]  -8,8'-dioarboxylic  acid 

l,l'-Bi-2-napthol 

Biphenyl 

4-Biphenylcarboxylic  acid 

Bis [p-aminophenyl] sulfonic  acid 

»l,'i-Bls  [l-anthraquinDnylamlno]  anthraquinone 

1,5-Bis [l-anthraqulnonylamlno] anthraquinone 

»3 ,9-Bis [l-anthraquinonylamino] -7H-benz [de] anthraoen- 
7 -one. 

Bis[l-anthraquinonylamlno]  vlolanthrene 

N,N'-Bis  [l-chloro-2-anthraquinonyl]-4  ','4"'-azobis- 
[4-biphenylcarboxamide] . 

1, 1-Blsl  2, <V-diamlno-m-tolyl]  ethane 

•4,4' -Bis  [diethylami  no]  benzhydrol 

4,4   -Bis[dietl^laminD]benzophenone   (Ethyl  ketone 

base) . 
4-[  Bis (p-diethylamlnophenyl )methyl] -2 ,7-naphtha- 

lenedisulfonlc  acid. 
2,7-BiE[dimethylamino]acridine  hydrochloride 

»4,4'-Bis[ dimethylamlno]benzhydrol   (Michler 's 
hydrol) . 


510. 
510. 


492,   510. 

401. 
288. 

253. 

253,   288,  457,   506,   510,   537,   577,   604,   605. 

367. 

378. 

378. 

206,  385. 

237. 

206. 

237. 

206,   510,    577. 

353. 

253, 

253, 

205, 

205, 

577. 

477. 

221, 

266, 

303, 

577. 

577. 

218,  385,  492,   581,  604. 

157. 

506. 

253, 

577. 

303, 

253. 


403,    506. 

267,   364,   453,   506,    577. 

504. 

266,   504. 


266,   303,  468,   504. 

504. 

566. 


506,    510,   537. 
468. 


477. 

266. 

365,   375,  455. 

221. 

248,   364. 

266,   303,   353. 

506. 

253,   506. 

355,   510. 

355,   510. 

348. 

468. 

512. 

512. 

401. 

253,    506. 

253,    506. 

253,   457,   510,   577,   605. 

506. 


510. 
252. 


506,    510,   537,   577,   605. 

506. 

506,    510,   537,   577,   605. 


253, 
566. 
221, 
253. 
253. 
457, 
253, 
457, 

510. 
510. 


401. 
577. 
253,   355,  492. 


401. 

253,  355,  492,    577. 


TABLE   73. --Synthetic     nriani 


SYNTHETIC  ORGANIC  CHEMICALS,  I956 

chemicals:  Cycli  c      intermerliates    for   which  Uniterl  .'^t,ites   proriiicti 
reporteri,    identifier!  by  iranufacturer  ,   J9')(?- -Continued 


67 


<fci^ii'-Bis[dimethylamino]benzophenone   (Miohler's 

ketone ) . 

3,7-Bis[dimethylamino]  phenazathionium  chloride 

3,3'-Bls[p-diinethylaniinophenyl]  -6-dijnethylaiiu.no- 

phthallde. 

Bls[p-dimethylajninophenyl]methanesulfonic  acid 

1,5-Bis  [2,'i-dinitrophenDxy] -AjS-dinitro- 

anthraquinone . 

m-Bis[ 2, 3-epoxypropoxy]  benzene 

2,6-Bis[2'-hydroxy-3'-tert-butyl-5'-methylbenzyl]- 

-i-methylphenol. 
N-(,'i-[  Bis  ( 2-hydroxyethyl)  amino  ] -2-raethyl- 

benzylidlne)nietanilic   acid. 
l,2-Bis[l-nitro-2-anthraquinonyloarbonyl]hydrazine — 
2,5-Bis[l-nitro-2-anthraquinonyl] -1,3,4-oxadiazole — 

l,'i-Bis[  2-triohloroethyl]  benzene 

m-Bronioaoetylphenyl  benzoate 

3-Bronio-p-anisic  acid 

p-Bromoanisole 

»3-Brofflo-7H-benz[de]  anthraoen-7 -one 

(Bromobenzanthrone) . 

Bromobenzene ,  mono 

Bromochlorobenzene 

3-Bromo-16,l'7-'liJiiethoxyviolanthrone 

l-Bromo-'«-{N-methylacetamido)anthraquinone 

l-Broino-<i-methylaminoanthraqulnone 

2-Bromo-3-me thy lanthraqul none 

6-Brcimo-3-methyl-7H-dibenz[f  ,ij]isoquinoline- 
2,7(3H)-dione. 

l-Bromonaphthalene 

2-Bromo-4'-nitrcacetophenone 

l-(9-Bromo-7-oxo-7H-benz[de]anthraoen-3-ylamino)- 

anthraquinone . 

p-Bromophenol 

^-Brcmophthalio  anhydride 

2-Bromopyridine 

o-Bromothianthrene 

o-(3-Bromo-p-toluyl) benzoic  acid 

l-Bromo-2,'4,6-triethylbenzene 

2-tert-Butylanthraquinone 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

p-tert-Butylbenzoic  acid 

o-(p-tert-Butylbenzoyl) benzoic  acid 

4-Butyl-m-oresol 

2'-tert-Butyl-4,6'-dimethylaoetophenone 

N^ -Butyl -"i-methoxymetanilaiiiide 

2-tert-Butyl-5-methylaniE0le 

p-tert-Butylphenol 

Butylphenols ,  mixed 

p-tert-Butyltoluene 

5-tert-Butyl-m-xylene 

Carbazole,  refined 

p-CS-Carbazolylami no) phenol 

N-3-Carbazolyl-p-benzoquinone  imine 

2,'i'-Carbonyldibenzoic  acid 

6(and  2) -Carboxybenzene-2(and  /i)-diazo-l-oxlde 

5-{o-Carboxybenzoyl) -2-chlorooxanilic  acid 

3-Carboxy-2(and  A)-hydroxybenzenediazoni\im  sulfate— 
3-Carboxymethyl-l-(5-chloro-2-methoxyphenyl)-3- 

methyltriazene. 
3-Carboxymethyl-l-(5-chloro-o-tolyl)-3-methyl- 

triazene. 

o-CCarboxymethylthlo) benzoic  acid 

5-(o-Carboxyphenylsulfamoyl)anthranilio  acid 

Chelidamlc  acid 

Chlorendic  acid 

Chlorendic  anhydride 

2'-Chloroacetoacetanilide 

2-Chloroacetophenone 

'i'-(Chloroaoetyl)acetanilide 

Chloroacetylcatechol 

m-Chloroaniline 

o-Chloro aniline 

p-Chloroaniline 

3-(o-Chloroanilino)propionitrile 

^-Chloro-o-anisidine  [NH2=l] 

5-Chloro-o-anisidine  [NH2=1]  (•i-Chloro-o-anisidine 
[0CH3=1] ) . 

A-Chloroanthranilic  acid 

•l-Chloroanthraquinone 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


253,  355,  ^92,  506,  510. 

577. 
577. 

506. 
253. 

443. 
537. 

443. 

253. 
253. 
468. 
492. 
604. 
365. 
253,  457,  506,  510,  537,  577,  604,  605. 

252. 

272. 

510. 

510. 

253,  457,  510. 

253. 

510. 

477. 
252. 
253. 

252,  477. 
443. 
512. 
577. 
253. 
253. 

253,  510. 
516. 
516. 

169,  253,  516. 

481. 

253. 

367. 

337. 

401,  510. 

337. 

252,  478. 

478. 

481. 

337. 

512. 

253. 

510. 

537. 

253. 

510. 

506,  510. 

253. 

253. 

510. 

577. 

348. 

468. 

468. 

157,  529. 

253. 

253. 

348. 

221,  253,  506,  510. 

221,  253. 

221,  253. 

253. 

510. 

213,  253,  448. 

253,  515. 

253,  457,  506,  510,  537,  577,  604. 


68 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  7B. --Syntheti 


chemicals:    Cyclic    intermediates    for   which  United  States  production  or   sale 
reported,    identified  by  manufacturer ,    1956  - -Continued 


Manufacturers '  Identification  numbers 
(according  to  list  in  table  27) 


»2-Chloroanthraquinone 

l-Chloro-2-anthraqulno'necarboxylic  acid 

3-Chloro-2-anthraqulnDnecarboxylic  acid 

3-Chloro-2-anthroic  acid 

oo-Chlorobenzaldehyde 

p-Chlorobenzaldehyde 

Chloro-7H-benz[de] anthracen-7-one  (Chloro- 
benzanthrone ) . 

•Chlorobenzene ,  mono 

l-Chlorobenzene-A-methylsulfone 

l-Chlorobenzene-'i-sulfinio  acid 

l-Chlorobenzene-<i-6Ulfochloride 

p-Chlorobenzenesulfonio  acid 

p-Chlorobenzenethiol 

^-Chlorobenzhydrol 

o-Chlorobenzoic  acid 

p-Chlorobenzoic  acid 

"i-Chlorobenzophenone 

2-Chlorobenzothiazole 

5-Chloro-2(3H)-benzoxazolone 

»o-(p-Chlorobenzoyl) benzoic  acid 

p-Chlorobenzoyl  chloride 

2'-Chloro-2,'»'-carbonyldibenzoio  acid 

Chloro-Cp-chlorophenyl,  phenyl) methane 

3-Chloro-2,'i-diethoxyanlline 

N-(3-Chloro-9,10-dihydroxy-2-anthryl)-acetamidebis- 
[acid  sulfate]. 

4'-Chloro-2',5  '-dimethoxyaoetoacetanilide 

5-Chloro-2,'i-dimethoxy  aniline 

l-Chloro-2,'i-dimethoxy-5-nitrobenzene 

5-Chloro-l,3-dLmethoxy-2-nltrobenzene 

5-Chloro-i,7-dimethyl-3(2H)-thianaphthenone 

»l-Chloro-2,'i-dinitrobenzene  (Dinitroehlorobenzene)  — 

2-Chloro-3,5-dinitrobenzenesulfonethylamide 

^-Chloro-3,5-dinitrobenzoic  acid 

3-Chlorodiphenylamine 

a -Chloro-o( and/or  p) -dodecyl toluene   [CH3=l] 

5-Chloro-2-formylbenzenesulfonio  acid 

^-Chloro-3-hydrazinobenzeneEulfonic  acid 

i-Chloro-N-isopropyl-3-nitrobenzene-l-sulfonamide 

«<i-Chlorometanilie  acid 

S-Chlorometanilic  acid 

»6-Chlorometanilic  acid 

N-(5-Chloro-2-methoxyphenyl) -N-methylglyoine 

»l-Chloro-2-methylanthraqulnone 

6-Chloro-'i-methylbenzo-l,3-thiaza-2-thionium 
chloride . 

A-Chloro-N -methyl -3-nltrobenzenesulfonamlde 

'i-Chloro-3-(3-methyl-5-oxo-2-pyrazolin-l-yl)- 
benzenesulfonic  acid. 

Chloronaphthalenes 

8-Chloro-l-naphthol-3,6-disulfonlc  acid   (Chloro 

H  acid). 
9-Chloronaphtho[l,2-b]thlophen-3(2H)-one 

«2-Chloro-i-m.troaid.llne   (o-Chloro-p-nltroaniline) 

»<4-Chloro-2-nitroaniline   (p-Chloro-o-nltroanillne)  — 
•4-Chloro-2-nitroanisole 

■»l-Chloro-5-nitroaiithraquinone 

l-Chloro-5(and  8)-nltroanthraqulnone 

»l-Chloro-8-nitroanthraquinone 

1-Chloro -2-ni trobenzene   ( Chloro -o -nitrobenzene ) 

»l-Chloro-2(and  "*) -nitrobenzene   ( Chloronitro- 
benzenes,  o-  and  p-) . 

l-Chloro-3-nitrobenzene   (Chloro-m-nltrobenzene) 

1-Chloro-i-nitrobenzene   (Chloro-p-nitrobenzene) 

■i-Chloro-S-nitrobenzenesulfonamlde 

4-Chloro-3-nitrobenzenesulfonanilide 

«2-Chloro-5-nitrobenzenesulfonlc  acid 

2-Chloro-5-nitrobenzenesulfonio  acid,   sodium  salt 

M-Chloro-3-nitrobenzenesulfonic  acid 

»4-Chloro-3-nitrobenzenesulfonyl  chloride 

2-Chloro-A-nitrobenzoic  acid 

5-Chloro-6-nitro-2{3H)-benzoxazolone 

■><o-('»-Chloro-3-nltrobenzoyl)benzolo  acid 

2-Chloro-4-nitrophenol 

4-Chloro-2-nitrophenol 

4-Chloro-6-nltro-l-phenol-2-sulfonic  acid 

l-CA- Chloro-2-nitrophenDxy)benzene 

2-Chloro-4-nitrotoluene 

2-Chloro-5-nitrotoluene 

'i-Chloro-2-nitrotoluene 

'i-Chloro-3-nitro-a,a,a-trifluorotoluene 

o-Chlorophenol 


510,    537,    577. 


501,    506. 
506. 


252,   253,   296,   333,   421,   468,   473,   550,   565. 


510. 

457,    506,   510,    537,   577. 


448,    510,    604. 


515. 

253,    506,    510,   604. 


510,   604. 

506. 

485,   506,    577. 

457,    506,    510,    537,    577. 


252,    253,  537,    604. 

252,  253,  510,   604. 

253,  510. 
506,    577,  605. 

506,  605. 
253,  604. 
403,    604. 

253. 

253,  604. 
443,   510. 

506,   510,   537,   577,    604. 

510,   577,   604. 
443,    577. 


506,    510,    604. 
440,    510. 


506,    510. 
510. 


TABLE  7B.--Syntheti 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 

ianic   chemicals:    Cyclic    intermediates    for  which  United  States 
vere  reported,    identified  by  manufacturer ,    1956- -Continued 


69 


p-Chlorophenol 

Cp-Chlorophenyl)acetonitrile 

l-Cp-Chlorophenyljbiguanide  hydrochloride 

A-Chloro-o-phenylenediamlne 

2-[  l-(p-Chlorophenyl)  -5-hydroxy-3-raethyl-'i- 
pyrazolylazo]-N-niethyl-l-phenol-'>-sulfonamlde. 

l-(in-Chlorophenyl)-3-methyl-2-pyTazolin-5-one 

l-(p-Chlorophenyl)-3-methyl-2-pyrazolln-5-one 

4-Chlorophthalic  acid 

Chlorophthalic  anhydride 

2-ChloropyTidine 

6-Chloroquinaldine 

»2-Chloroquim.zarin 

7-Chloro-'i-quinolinol 

6^Chloroquinophthalone 

i-Chlororesorcinol 

Chlororesorcinol,  mono 

8-Chlorotheophylline 

m-Chlorotoluene 

o-Chloro toluene 

p-Chlorotoluene 

»a-Chlorotoluene   (Benzyl  chloride) 

5-Chloro-o-toluenesulfon3-c  acid  and  salt 

3-Chloro-o-toluidine  [  NH^^l] 

3-Chloro-p-toluidine  [  NHi=l] 

•4-Chloro-o-toluidine  [nH2=1]    (5-Chloro-o- 
toluidine  [CH3=l]    (Fast  red  TR  base). 
5-Chloro-o-toluidine  [NH2=1]    (■4-Chloro-o- 
toluidine  [CH3=1]   (Rod  KB  base). 

4-Chloro-o-toluidine  hydrochloride   [NH2=1] 

»5-Chloro-o-toluidine  hydrochloride   [NH2=1] 

5-Chloro-o-toluidine  sulfate  [nH2=1] 

o-(3-Chloro-p-tolyl)benzoic  acid 

<;-Chloro-o-tolyl  ethylxanthate 

N-(5-Chloro-o-tolyl)-N-methylglycine 

l-(o-Chloro-o-tolyl)-3-methyl-2-pyrazolin-5-one 

("i-Chloro-o-tolylthio) acetic  acid 

^-Chloro-a,a,a-trifluoro-3-nitrotoluene 

Chlorotriphenylsilane 

2-Chloro-p-xylene 

4-Chloro-2,5-xylenesulfonyl  chloride 

4-Chloro-2,5-xylenethiol 

(•4-Chloro-2,5-xylylthio) acetic  acid 

Chrysazin  (1,8-Dihydroxyanthraquinone) 

s-Collidine  (2,'i,6-Trtmethylpyridine) 

■»Cresols :  ■'" 

m-Cresol 

o-Cresol 

p-Cresol 

tCresols,  mixed:  •^ 

Cresol  (meta,  para) 

Cresol  (ortho,  meta,  para). 

2,3-Cresotic  acid 

«Cresylic  acid   (refined)-^ 

Cresylic  acid,  potassium  salt 

Cresylic  acid,  sodium  salt 

«Cumene 

a-Cyano-P-['i-bis(2-hydroxyethyl)amino-2-methylI- 
cinnamic  acid,  methyl  ester. 

4.[(2-Cyanoethyl)ethylainino]-o-tolualdehyde 

p-[(2-Cyanoethyl)methylamino]benz aldehyde 

8-Cyano-l-naphthalenesulfonlc  acid 

Cyanuric  acid 

Cyanuric  chloride 

«Cyclohexane 

1,2-CyolohexanedicaTboximide 

1,2-Cyclohexanedicarboxylic  anhydride  (Hexahydro- 
phthalic  anhydride). 

■xCyclohexanol 

*Cyclohexanone 

Cyclohexanone  oxime 

Cyolohexene 

'i-Cyclohexene-l,2-dicarboximide 

4-Cyclohexene-l,2-dicarboxylic  anhydride 
(Tetrahydrophthalic  anhydride) . 

Cyclohexylamine 

l-Cyclohexyl-2-propanone 

Cyclopentene 

»p-Cymene 

Decylbenzene 

l,5(and  l,8)-Diacetamidoanthraquinone 

H,N-Diallylcamphoramic  acid 

N,N-Dlallylmelamine 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


221, 

252. 

330. 

253. 

218. 

577. 

401, 

577. 

577. 

253. 

221, 

430. 

218, 

361. 

253. 

440, 

457, 

506, 

577. 

3AS. 

253. 

510, 

604. 

604. 

564. 

468. 

504. 

504, 

506. 

221, 

266, 

303, 

468,  504 

510. 

253, 

506. 

253, 

510. 

371, 

506, 

537. 

253,  506,  510,  604. 


253. 


253, 

265,  492,  537,  605. 

506. 

510. 

510. 

510. 

577. 

253, 

506,  510,  515,  537. 

510. 

244. 

510. 

510, 

515. 

253. 

253, 

510,  515. 

253, 

510. 

367, 

512,  558. 

367. 

512, 

537,  562,  609. 

212, 

485. 

167, 

512,  513,  537,  558,  562,  609. 

367, 

513,  537,  558,  609. 

?52, 

506. 

89, 

138,  331,  367,  463,  512,  537,  552,  558,  562,  609 

463. 

463. 

212, 

252,  552,  558. 

443. 

253. 

253. 

253, 

510. 

537. 

202, 

537. 

331, 

434,  516,  X. 

253. 

506. 

221, 

250,  252,  253,  468,  506. 

250, 

253,  506. 

506. 

434 

516. 

181 

506. 

506. 

221. 

337. 

516 

212 

369,  X. 

565 

604 

594 

537 

70  UNITED  STATES  TARIFF  COMMISSION 

TABLE   7B. -Synthetic   organic   chemicals:    Cyclic    .nterweri.ates:    for   which  Unites!  Sts 
were   renortled,    identified  by  manufacturer ,    1956- -Continued 


*l,4-Diaiainoanthraquinone 

*lj5-Diai[n.noanthraqiiinone 

l,5(and  1,8) -Diaminoanthraqulnone 

»2,6-Dlai[iinoantliraquinone 

l,A-Dlainlno-2,3-anthraquinonedicarboximlde 

l,4-Dlaiiiino-2,3-anthraquinonedisulfonio  acid 

"ijS-Dlaminoanthrarufln 

2,6-Diamino-A,8-anthrarufindisulfonio   acid --. 

3,3'-Diaminobehzaiiillde 

»2,^-DiaminobenzeneEulfonIc  acid  [  SO3H  =1] 

2,5-DiaiiunobenzeneEulfonic  acid  [  SO3H  =l] 

4, "4'  -Diaiiiino-2,2'  -biphenyldisulfonlc  acid 

*4.,4'  -Diaiiiino-3,3'  -biphenyldisulfonlc  acid 

4,4'-Dlamino-3-biphenylsulfonio  acid 

3,7-Diajiilnodibenzothiophenedisulfonio  acid -5,5- 
dioxlde,  disodium  salt. 

l,4-Diamino-2,3-dichloroanthraq\d.none 

3,6-Diamino-2,7-dimethylacridine 

3,6jDiamino-2,7-diinethylacridine  sulfate 

2,2' -Diaiiiino-5, 5' -dimethyl-3, 3 '-biphenyldisulfonlc 
acid   (2,2'-Dianilno-5,5-bl-m-toluenesulfonic  acid) 

4,4  -Di ami no -5, 5 '-dimethyl -2, 2  '-biphenyldisulfonic 
acid. 

4,4'-Diamino-3,3'-dimethyltriphenylmethane 

5,6-Diaiiiino-l-naphthalenesulfom.c  acid 

l,4-Diamino-5-nltroanthraquinone 

N,N'-Di(m-aiiilnophenyl)oxainlde 

N,N'-Di(p-aiiunophenyl)oxamlde 

2,6-Diaminopyridine 

''4,4'-Diainino-2,2'-stilbenedisulfonic  acid 

4,6-Diaiiiino-m-toluenesulfonic  acid  [S03H=l] 

2,4-Di-sec-amylphenol 

2,4-Di-tert-amylphenol 

»l,5-Diaiiillno-2,6-anthraquinonedicarboxylic  acid 

»2,4-Dianilino-l-hydroxyaiithraquinone 

Diary Iguanidine 

l»5-Dibenzamidoanthraquinone 

*'i,5^-Dibenzamido-l,l   -iminodianthraquinone • 

4,5  -Dibenzamido-4  -methox; -l,l'-irainodianthra- 
qulnone . 

»l,5-Dibenzoylnaphthalene 

N,N'-Dibenzylethylenediamine 

N,N   -Dibenzylethylenediamine  dlacetate 

«3,9-Dibromo-7H-benz[de]anthracen-7-one 

p-Dibromobenzene 

4,4'-Dlbromo-l,l'-diaiithramide 

2,7-Dibromo-3,8-dihydroxy-l,6-pyrenedione 

l,3-Dibromo-5,5-dimethylhydantoin 

5,5'-Dibroiiioindigotin 

2,6-Dibranio-l,5-naphthalenediol 

Dibramo-8,16-pyranthrenedlone 

Dibromoviolanthrone 

ni(and  p) -Dibutoxy-2-nitrobenzene 

2,6-Di-tert-butyl-p-cresol 

3,4-Dichloroaniline ^ 

»2,5-Dichloroanlline  and  hydrpchloride  [NH2=1] 

*l,5-DichloroanthraquinDne-^ 

l,5(and  l,8)-Dlchloroanthraquinone 

»l,8-Dlchloroanthraquinone 

2,3-Dlchloroanthraqulnone 

2,6-Dichlorobenzaldehyde 

3-(3,4-Dichlorobenzamido)-l-phenyl-2-pyrazolin- 
5 -one. 

m-Diohlorobenzene 

*o-Dichlorobenzene 

o(and  p) -Dlohlorobenzene 

*p-Dichlorobenz9ne 

Diohlorobenzenesulfonic  acid 

2,5-Dichlorobenzenesulfonyl  chloride 

*3,3  -Dichlorobenzidine  base  and  salts 

*2,4-DichlorobenzoiG  acid 

*2,5-Dichlorobenzoic  acid 

4,4'-Dichlorobenzophenone 

o-(x,x-Dichlorobenzoyl) benzoic  acid 

2,4-Diohlorobenzoyl  chloride 

N,N'-(2,5-Dichloro-3,6-dioxo-p-phenylene)bls[6-(2- 
(3H)-oxo-5-benziinidazolylamlno)metanillc  acid]  . 

Dichlorodiphenylsilane 

2,5-Dichloro-4-hydrazinobenzenesulfonic  acid 

2,6-Dichloro-4-hydroxydiazobenzenesulfonic  acid 

( 2 , 5-Dichloro-4-sulf obenzenediazohydroxide ) . 
6-(5,8-Dichloro-l-hydroxy-2-naphthylazo)-l-phenol- 
3-sulfonamlde. 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


500,  506,-  510,  577,  604. 

457,  510,  577. 

577. 

401,  457,  506,  510,  537,  577. 

604. 


506,  510,  577. 
577. 

401,  577. 
506,  537. 


253, 
253, 
253, 
253, 
253. 
253. 
253, 
577. 
577. 
253, 
288, 
267, 
401, 
456. 
537. 


253. 
253. 
253. 
401,  506,  604. 

577. 

537. 

510. 

510. 

401. 

401,  453. 

512. 

253, 

253, 

585. 

585. 

457, 

457, 

253. 

253,  510. 

253,  457,  506,  510,  537,  577,  605 

510, 


401,  492,  506,  510,  537,  577. 
506. 


506,  510. 
510,  577. 


160, 

594. 

266, 

253, 

252. 

253. 

510. 

97. 

510. 

477. 

253. 

510. 

443. 

537. 

221, 

213, 

253, 

253, 

253, 

577. 

506, 

477. 


457,  510,  577. 

4S2. 

457,  506,  510,  537,  577. 


253. 

253,  492,  506,  510,  604. 

457,  506,  510,  577,  605. 

506,  604. 

■457,  577. 

510. 


253 
77, 
296 
77, 
492. 
510. 
253, 
504, 
401. 
482. 
577. 
504. 
253. 

244. 
510. 
577. 


221,  252,  253,  333,  468,  473,  550,  590,  592. 
421,  565. 
221,  252,  253,  333,  468,  473,  590,  592. 

267,  485,  506,  515,  577,  592,  604,  X. 
515. 


SYNTHETIC  ORGANIC  CHEMICALS,  1950 


71 


TABLE  7B.--Syntheti 


rganic  chemicaJs:  Cyclic   intermediates   for  which  United  State 
were  reported ,    identified  by  manufacturer ,    i955- -Continued 


Manufacturers '  identification-  numbers 
(according  to  list  in  table  27) 


N-(6,8-Dichloro-5-hydroxy-l-naphthyl)-p-toluene- 
sulfonamlde  (2,'4-Dlohloro-5-(p-toluenesulfonaiiiido) 
1-naphthol) . 
"ijS-Diohlorometanllic  acid 

»2,5-Dlohloro-4-(3-iiiethyl-5-oxo-2-pyrazolin-l-yl)- 
benzenesulfonic  acid  (l-(2,5-Dichloro-4-sulfo- 
phenyl)  -3-metliyl-5-pyrazolone) . 

Dichloromethylphenylsilane 

2, 6-0ichloro-<i-nitro  aniline 

l,2-Diohloro-<V-nitrobenzene 

l,3-Dichloro-'i-nitrobeJizene 

l,'^-Dichloro-2-nltrobenzene   (Nitro-p-dichloro- 
benzene ) . 

Dichloropentadiene 

2,i-Dichlorophenol 

2-[  3-(2,5-Dichlorophenyl)-l-ethyltriazen-3-yl] sul- 
fobenzoic  acid, 

2,5-DichlorophenorLhydrazine 

(2, 5-Dichlorophenylthio) acetic  acid 

Diohlorophthalic  anhydride 

4,7-Dichloroquinoline 

ijb-Diohlororesorcinol 

o-(3,5-Dichlorosalicyloyl)benzoic  acid 

2,5-Dichlorosulfanilic  acid  [S03H=l] 

ijOi-Dichlorotoluene 

a,a-Diohlorotoluene   (Benzal  chloride) 

2,'i-Dichlorotoluene 

2,6-Dichlorotoluene 

Sj-i-Dichlorotoluene 

Dlcyolohexylamine 

2,'4-Diethoxyaniline 

2,5-Dietho3tyaniline 

3, i-Diethoxybenz aldehyde 

2',5'-Diethoxybenzanilide 

2',5'-Diethoxy-<i'-nitrobenzanilide 

N,N-Dietho3£y-m-toluidine 

p-Diethylamlnobenz aldehyde 

N,N-Diethyl-3-aiiiinophenol 

i-Diethylamino-o-tolualdehyde 

«N,N-Diethylaniline 

N,N-Diethyl-m-anisidine 

Diethylbenzene 

N,N-Diethyleyclohexylamine 

N.N-Diethylmetanilic  acid  and  sodium  salt 

N,N^ -Diethyl -4-me the xymetanilamide 

N,N-Diethyl-l-naphthylamine 

N,N-Diethyl-p-nitrosoani  line 

NjN-Diethyl-A-nitroso-m-anisidine  hydrochloride 

2-(3-[ 5-(N,N-Dlethylsulfamoyl) -o-methoxyphenyl] - 
l-ethyltriazen-3-yl)-5-sulfobenzoic  acid. 

N,N-Diethyltetrahydrophthalamic  acid 

N,N-Di ethyl -m-toluidine 

3,3'-Diformamidocarbanilide 

N,N'-Diformyl-2,5-toluenediamine 

2,3-Dihydro-l,'4-bis[methylamlnoanthraquinone] 

2,3-Dihydro-<VH-pyran 

2,3-Dihydroquinizarin 

l,5(an4  1,8) -Dlhydroxyanthraquinone 

»'4,5-Dihydroxy-2,7-naphthalenedisulfonic  acid 
(Chromotropic  acid). 

«A,5-Dihydroxy-l-naphthalenesulfonic  acid  (Dioxy 
S  acid). 

»6,7-Dihydroxy-2-naphthalenesulfonic  acid 

3,5-Dihydroxy-2-naphthoic  acid 

*16 , 17-Dihydroxyviolanthrone  ( Dihydroxydibenz - 
anthrone ) . 

Diisobutyl-o-cresol 

2,'i-Dimethoxyacetophenone 

2,5-DlmethoxyacetophenDne 

•2, S-Dimethoxy  aniline 

m-Dimethoxybenzene 

3,3  '-Dimethoxybenzidine 

2,A-Dimethoxybenzoic  acid 

2,5-Dimethoxybenzoio  acid 

3,3  '-Dimethoxy-<t,A'-bis[  3-methvl-3-sulfoethyltri- 
azen-1-yl] biphenyl  (2,2 '- [3,3'-(3,3'-Dimethoxy- 
<i,i'  -biphenylene)bis(l-methyldla.zoamino;]  di- 
(ethanesulfonio  acid)). 

i,4'-Dlmethoxy-2-hydroxybenzophenol 

l,'i-Dimethoxy-2-nitrobenzene 

3,'4-Dimethoxyphenethylamine  (Hamoveratrylamine) 

(3, "i-Dimethoxyphenyl) acetic  acid  (Homoveratric 
acid) . 


485. 

253,  401,  510,  537,  577. 


244. 

4^3,  510. 

221,  253. 

253. 

213,  253,  506,  510,  604. 

284. 

221,  252,  523. 

510. 

401. 

510. 

430. 

95,  348,  414. 

604. 

506. 

253,  401,  604. 

504. 

468. 

504. 

506,  510. 

504. 

221. 

604. 

510. 

365. 

510. 

510. 

604. 

506,  510. 

253,  510,  537. 

253. 

253,  355,  492,  506,  537. 

253. 

252,  367. 
253. 

253,  510. 
401,  430,  510. 
253. 

510. 
253. 
510. 

506. 
253. 

510. 
506. 
253. 
253. 
253. 
253. 
253,  440,  506,  577. 

253,  510,  577,  604. 


61, 

218, 

394, 

506,   510. 

510. 

253, 

457, 

506, 

510,    577,    605 

566. 

253. 

365. 

253, 

443, 

510. 

365, 

537, 

604. 

253, 

267, 

506 

577,   604. 

253, 

537. 

365. 

253, 

510. 

537. 

253, 

510. 

221. 

422. 

72 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  7B.--Syntheti 


rganic   chemicals:    Cyclic    intermertiatea    for   which  United  States  profiucti 
were  reported,    irient  i  fieri  by  manufacturer  ,    i956- -Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


(3,<V-Dimethoxyphenyl)acetonltrile  (Homoveratro- 
nitrile) . 

16,17-Dimethoxyvlolanthrone 

p-Dimethylaminobenzaldehyde 

4-DimethylaiLino-2,2-diphenylvaleraiiilde 

o-(Dimethylaminomethyl)-p-butylphenol 

m-DlmethylamlnDphenol 

N-Cp-DimethylaminDphenyl) -Ij'V-naphthoquinone  imine — 
o- (Dime thylaminomethyl) phenol 

«N,N-Dimethylanlllne 

N,N-Dimethylbenzylamlne 

»2, 2 '-Dimethyl -1,1'  -bianthraquinone 

Dlmethyl-l,3-oyclohexanedione 

N , N -Dimethylcyelohexylnml ne 

2',7'-Dimethylfluoran 

Dime thy  liydantoin 

2,8-Dimethyl-13P-hydroxy-9(l3p)-ceroxenDne 

2,3-Dtmethylindole 

N,N-Dimethyl-l-naphthylamlne 

NjN-Dlmethyl-p-nitrosoanillne 

N,N-Dimethyl-3-nitro-p-tolu£nesulfonamlde 

N) N-Dimethyl -p-phenylenedlnm1 ne 

2-[3-( 5-DimethylBulf amyl-o-tolyl) -l-methyltriazen- 
3-yl] -5-EUlfobenzolc  acid. 

N,N-Dimethylsulfanilic  acid 

N,N-Dimethyl-p-toluldine 

2',<i'-Dinitroacetanilide 

a.i-Dlnltroaniline 

p-( 2, A-Dinitroanilino) phenol  (Dinitrohydroxydi- 
phenylamine ) . 

2,4-Dinltroanlsole 

1,5-DlnltroanthraqUlnone 

l,5(and  1,8)-Dinltroanthraquinone 

N,N'-(2,'V-Dinitroanthraquinone)  -1,5-dioxamle  acid 

AjS-Dinltroanthrarufln 

3,3'-Dinitrobenzanlllde 

«m-Dl nitrobenzene 

2,'i-Dinitrobenzenesulfonic  acid 

3,5-Dinitrobenzoic  acid 

Dlnitro(3,3'-bl-7H-benz[de]  anthracene-7,7'-dione) 

4,5-DinltrochryBazin 

*2,'i-Dinitrophenol,   tech 

p-Dinltrosobenzene 

•i,<4'-Dlnltro-2,2'-stilbenedlsulfonlc  acid  and 
disodlum  salt. 

2,4-Dlnitrotoluene 

2,'^(and  2,6)-Dlnltrotoluene 

Dlnitrotoluene  (mixed  isomers) 

N,N  '-Dioxide-N,N  '-diphenyl-p-benzoqulnone  dlimlne 

Dlpentene  (Limonene) 

1,5 -DiphenoxyanthraqiH  nnne 

Dlphenylacetic  acid 

Diphenylacetonitrile 

Diphenylamine 

6,8-Dlphenylamino-l-naphthalenesulfonlc  acid 

l,'l-Diphenyl-2-butane-l,'*-dione 

sym-N,N'-Diphenylethylenediamlne 

a,a-Diphenyl-4-piperidinemethaiiol 

Dlphenyl-4-pyridylmethaiiol 

1,3-Diphenyltriazene 

Dlthlodlbenzolo  acid 

2,2'-Dithiodibenzolc  acid,  dimethyl  ester 

•l,'»-Dl(p-toluldino)anthraquinone 

1 , 5-Di (p-toluidino ) anthraqui  none 

l,8-Di(p-toluldino)anthraquinone 

Divinylbenzene 

Dodeoylanillne — 

»Dodecylben2enes  (include  keryl-type  benzenes) 

Dodecyl-N-methylbenzenesulfonamlde -- 

Dodeoylnltrobenzene 

6-Ethoxy-2-fflercaptobenzothia2ole 

3(and  4)-Ethoxy-4(and  3)-methoxybenzeildehyde 

2-Ethoxynaphthalene 

3-EthylaminD-p-cresol 

S-EthylamiDD-p-tolueneeulfonic  acid  [S03H=l] 

o-Ethylaniline 

N-Ethylaniline: 

Crude 

Refined--- 

»2-(N-Ethylanilino)ethanol- 

2- ( N-Ethylanilino) ethyltrljaethylnTnnrinium  chloride 

a-(N-Etl^rlanilino) -m-tolueneeulfonic  acid 

*a- (N-Ethylanilino) -p-toluenesulfonic  acid 


355,   '192,    506,   537. 

385,   566. 

288,    506,    510,    537,    577,   604. 


506,    537. 


422. 

457, 

506. 

564. 

566. 

537. 

506. 

566. 

253, 

365, 

253, 

443. 

221. 

4^. 

253. 

44. 

253. 

477. 

218, 

510. 

506. 

510. 


510. 

477. 

510. 

221,   510,    537. 

253,    506,   510. 

213. 

457. 

253,  288,   577,   604. 

577. 

604. 

577. 

253,    506,    510. 

510,    577. 

253,   459,  477. 

253. 

253,   443,    510. 

253,   506,    604. 

267. 

253,   492,   506,    510,   577. 


253, 
253. 
506. 
267. 
369, 
253, 
266, 
459. 
221, 
506, 
506. 
253. 
512. 
512. 
506. 
385. 
385. 
457, 
457. 
457. 
252, 
221. 
221, 
510. 
221. 
253. 
221. 
506. 
253. 
253. 
221. 


X. 

443,   604. 
330. 

252,  253,  335,   506,   537. 
510,   577. 


506,    510,   577. 

367. 

251,   278,   506,    508,    552. 


537. 

253,   506,    537. 

253,  443,    510,    529,    577. 

253. 

253. 

94,  401,   430,   492,    506,    510,    537,    577. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


73 


TABl£  7B. --Synthetic  organic  chemicah 
or  sales  were  reported. 


:   Cyclic   intermediates   for  which  United  States  production 
identified  by  manufacturer ,    1956- -Continued 


Manufacturers '  Identification  numbers 
(according  to  list  in  table  27) 


N-Ethyl-p-anisldlne 

N-Ethylanthranillo  acid 

2-Ethylanthraciuinone 

»Ethylbenzene 

o-(p-Ethylbenzoyl) benzoic  acid 

9-Ethyloarbazole 

N-Etliyl-N-(2-chloroethyl)  aniline 

N-Ethylcyclohexen-l-ylamlne 

2- [l-Ethyl-3- ( 2-methoxy-5-nitrophenyl) trla2en-3-yl] - 

5-sulfobenzoic  acid. 

N-Ethyl-1-naphthylamine 

N-Etbyl-N-(l-naphthyl)-p-nitrobenzaiiilde 

l-Ethyl-2-nitroben2ene 

N-Ethyl-2-nl  trobenzenesulfonanili.de 

9-Ethyl-3-nitrooarbazole 

p-Ethylphenol 

ttN-Etbyl-N-phenylbenzylamlne  (N,N-Ethylbenzyl- 

aniline) . 

2-Ethyl-2-phenylmalonio  acid,  diethyl  ester 

l-(o-Ethylphenyl)-3-mettiyl-i-phenylazo-2-pyrazolln- 

5 -one. 

l-(o-Ethylphenyl)-3-methyl-2-pyrazolin-5-one 

5-Ethyl-2-piooUne   (2-Methyl-5-etbylpyrldlne)   (MEP)- 

l-Ethylpiperidlne 

2-Ethylpyridlne 

<i-Ethylpyrldine 

N-Ethyl-5-sulfoantliranlllo  acid 

6-Ethyl-l,2,3,'i-tetrahydro-l,l,4,4-tetraiiiethyl- 

naphthalene . 

N-Ethyl-m-toluidine 

N-Ethyl-o-toluldlne 

3-(N-Ethyl-m-toluldino)proplonitrlle 

a-(N-Etbyl^ii-toluldino)  -m-toluenesulfonlc  acid 

5-Ethyl-2-vinylpyridlne 

1-Ethynyloyolohexan-l-ol 

Fluorene 

Formanllide 

p-Formylacetanilide 

<4-Forniyl-m-benzenedisulfonlc  acid 

m-Fonnylbenzenesulfonic  acid,  sodium  salt 

«o-Fonnylbenzenesulfonlo  acid  (o-Sulfobenzaldebyde) — 

Furan 

Furfuryl  alcohol 

3-Glyoyl-3-methyl-l-(6-methDxy-m-tolyl)thlazine 

Hexaohlorobenzene 

Hexaohlorocyclopentadiene 

Hexachlorodiphenyl  oxide 

»p-Hydrazinobenzenesulfonic  acid 

3-Hydrazino-5-nltro-m-toluenesulfonic  acid  [SOsH^lj- 
3-Hydrazino-5-nltro-p-toluenesulfonic  acid  [S03H=l] - 

Hydrazobenzene 

Hydroabietyl  alcohol 

Hydroquinone ,  tech 

o-Hydroxyacetophenone 

p-Hydroxyacetophenone 

6'-Hydroxy-m-acetotoluidide 

l-Hydroxyanthraquinone 

3-Hydroxy-2-anthra(iuinonecarboxylic  acid,  sodium 

salt. 
N- ( 3-Hydroxy-2-anthra(iulnonyl ) -l-nltro-2-anthra- 

quinoneoarboximide . 

4-Hydroxybenzenearsonlc  acid 

2-Hydroxy-llH-benzo-a-carbazole-3-carboxyllc  acid 

p-Hydroxybenzoio  acid 

p-Hydroxybenzoic  acid,  benzyl  ester 

p-Hydroxybenzoic  acid,  butyl  ester 

p-Hydroxybenzoio  acid,  ethyl  ester 

p-Hydroxybenzoic  acid,  methyl  ester -— 

p-Hydroxybenzoic  acid,  propyl  ester 

4-Hydroxyooumarin 

2'-(2-HydroxyethylamlnD)acetaiillide 

N- ( 7-Hydroxy-8- [2-hydroxy-5- (methylsulf amoyl) - 

phenylazo] -1-naphthyl) acetamlde . 

3-Hydroxy-2-methylclnchonlnic  acid 

2-Hydroxy-l-naphthaldehyde 

3-Hydroxy-2-naphthanilide 

l-Hydroxy-2-naphthoic  acid 

»3-Hydroxy-2-naphthoio  acid  (B.O.N.) 

<»N-(7-Hydroxy-l-naphthyl)  acetamlde 

2- ( 2-Hydroxy-l-naphthylazo) -N-isopropyl-l-phenol- 

4-sulfonamide. 
2-(2-Hydroxy-l-naphthylazo)-l-phenol-4-svafonamide-- 
l-Hydroxy-A-nltroanthraqulnone 


<M.3. 

510. 

506. 

221,  252,  367,  529,  558. 

510. 

510,  512. 

253. 

375. 

510. 

253,  355,  506. 

510. 
221. 
577. 
510. 

253,  i92,  506. 

266,  348,  564. 
577. 

577. 
529. 
560. 
512. 
512. 
510. 
337. 


253,    506. 

253. 

253,  443. 

253. 

512. 

108. 

512. 

253. 

510. 

510. 

510. 

401,  430, 

492, 

506, 

510. 

253. 

495. 

253. 

523. 

468. 

252. 

253,  352, 

401, 

510, 

537. 

510. 

94. 

267. 

212. 

443,   445, 

492. 

330. 

252,  330. 

577. 

506,    604. 

510. 

510. 

348,  456. 

510. 

267,    504. 

504. 

504. 

504. 

365,    504. 

504. 

456. 

604. 

577. 

253. 

330. 

371,  492, 

510. 

506,    510. 

104,  253, 

371 

485 

492,    504,   506,    510,   515,    604 

253,   506, 

577. 

577. 

577. 

577. 

74 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  7B. -Synthetic  organic  chemicals:    Cyclic   intermediates    for   which  United  State 
or  sales  were  reported,    identified  by  manufacturer,    1956-. Continued 


production 


Hydroxynitrovlolanthrone 

2-Hydroxyphenetole 

N-(p-Hydroxyphenyl)-2-naphthylamine 

p-(8-Hydroxy-6-sulfo-2-naphthylamlno) benzoic  acid 

l-Hylroxy-<i-(p-toluidlno)antliraqulnone 

*l,l'-IiQi  nobis  ['i-aminoanthraqui  none] 

1,1  -Iininobis[^-benzainidoanthraqiianone] 

»l,l'-Iminobisf5-benzamidoanthraq.uinone] 

«6,6'-Iiiilnobis[l-naphthol-3-sulfonic  acid] 

1,1  -Iiiu.nobis[<i-nltroaiithraqulnone] 

»l,l' -Iminodlanthraquinone   (Dianthrimlde) 

Imlnodipyridine 

2-Iodobenzoic  acid 

Iron  phthal oeyanine 

Isatin 

Isocyanic  acid,  3,3' -dimethyl -A, ^'-biphenylene  ester 

(3,3'-Bitolylenfc-4,4'-diisocyanate). 
Isocyanic  acid,  (3,3'-Dimethoxybenzidine-'i,"i'-di-) 

ester  (3,3'-Dimethoxybenzidine-4,4'-diisocyanflte) . 
Isocyanic  acid,  niethylenebis(3-methyl-p-phenylene)  ester 
»Isocyanic  acid,  methylenedi-p-phenylene  ester  (4,4'- 
Methylenediphenylisocyanate) . 
Isocyanic  acid,  4-methyl-m-phenylene  ester  (4-Methyl- 
m-phenylenediisocyanate)  (Toluene-2,4-dlisocyanate). 

Isocyanic  acid,  phenyl  ester  (Phenylisocyanate) 

Isocyanic  acid,  m-tolylene  esters  (m-Tolylene 
diisocyanates) . 

Isocytosine  (2-Amino-4(3H)-pyrimidone) 

Isonlcotinic  acid 

Isonicotinic  acid,  methyl  ester 

Isonitrosopropiophenone 

Isophorone 

Isophthalic  acid  (1,3-Benzenedicarboxylic  acid) 

Iso^ropylbiphenyl 

«4,4  -Isopropylldenediphenol  (Bisphenol  A) 

N-Isopropyl-2-nitro-l-phenol-4-sulfonflmide 

Isoquinoline 

*Isoviolanthrone  ( Isodibenzanthrone ) 

*Leuco-l,4-diaminoanthraquinone 

»Leuco  quinizarin  (1,4,9,10-Anthratetrol) 

♦Leuco  tetrahydroxyanthraquinone 

2,3-Lutidine - 

»2,4-Lutidine 

2,5-Lutidine 

2,6-Lutidine— 

2,6-Lutidine-N-oxlde 

Melamine 

o-Mercaptobenzoic  acid 

Metanilaniide 

Metanilanilide 

«Metanilic  acid  (m-Aminobenzenesulfonic  acid) 

l-Methoxyanthraquinone 

4-Methoxyinetanilic  acid 

l-Methoxy-4-nitroanthraquinone 

2-[  3-(2-Methcxy-4-nitrophenyl) -1-methyltriazen- 
3-yl]  -S-sulfobenzoic  acid. 

(p-Methoxyphenyl) acetic  acid 

5-lfethoxy-m-phenylenediamine  (m-Dlamlnoanlsole) 

N-(p-Methoxyphenyl) -p-phenylenediamine  sulfate 

[3-(6-MethD3!y-m-tolyl)  -l-methyltriazen-3-yl]  acetic 
acid. 

l-MethylamiAoanthraquinone 

l-Methylamlne-4-(p-toluidino)anthraquinDne 

N-Methylanilins.- - 

2-(N-Methylanilino)ethanol 

/3-(N-Methylanilino)propionitrile 

5-Methyl-o-anisidine  [nH2=1] 

2-MethylanthraquinDne 

l-(3-Methyl-2-anthraquinonylamino)-5-C7-oxo-7H-benz 
[de] anthracen-3-ylamino)anthraquinon£. 

N-Methylbenzenesulfonanilide 

3-Methylbenzo[f  ]quJ-noline 

2-Methylbenzoxazole 

N-Methylbenzylamine 

Methylbicyclo[2,2,l]hept-5-ene-2,3-dicarboxylic 
anhydride. 

Methylcyclohexane 

4-Methylcyclohexene 

N-Methylcyclohexylamlne 

N-Methylene aniline 

4,4'-Methylenebis[2-chloroanilinfi] 

4,4'-Methylenebis[N,N-diethylanllinfi]  


Manufacturers'   identification  numbers 
(according  to  Hat  in  table  27) 


537. 
221. 
510. 
510. 
253, 
253, 
506, 
253, 
253, 
253, 
253, 
512. 
564. 
253. 
506. 
267, 


267. 
253,    506. 


457. 

457,    506,   510,    537,    577,    605. 

537,   605. 

457,    510,    577,   605. 

288,   401,    506,    510,    577. 

457,   577. 

457,    506,   537,    577,   605. 


253,    506,   607. 
253,   506. 


221. 
607. 

537. 

512. 

512. 

365. 

529. 

552. 

221. 

221, 

577. 

512. 

253, 

253, 

440, 

430, 

512. 

367, 

512. 

512. 

512. 

537. 

5-4, 

253 

510 

61, 

253, 

453. 

253. 

510. 


252,  4S1. 


457,   510,    577,   605. 

267,  430,  457,    510,   537,    577,    605. 

506,    577,   604. 

457,   510,    577. 


512,    558. 


385. 

577. 

577. 
253,   288,    506,    510,    537,    577. 

510. 


330. 

213,    537. 
510. 
510. 

253,  457,    506,   510,   604. 

457,   510. 

253. 

443,    510. 

253. 

253,   577. 

506,   537. 

253. 

604. 
510. 

218,   477. 
375. 
506. 

252,   516. 

516. 

253. 

253. 

253. 

510,   537,   577. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 

TABLE  7B. --Synthetic  organic  chemicals:   Cyclic   intermediates   for  which  United  States  producti 
or  sales   were  reported,    identified  by  manufacturer,    I95lS- -Continued 


75 


Manufacturers'  identification  numbers 
(acoording  to  list  in  table  27) 


A,i'-Methylenebis[N,N-diinethylaniline]  (Methane 
base) . 

A,-;' -Me  thy  lenebis[N,N-dimethyl-2-nitro  aniline] 

2,2'-Methylenebls[A-ethyl-6-tert-butylphenol] 

2,2'-Methylenebis[4-methyl-6-tert-butylphenol] 

5,5' -Methylenebis [ toluene-2 ,4-dimni  ne J 

4,4' -Me thy lenedi aniline 

Methylenedlsallcylic  acid 

2-Methylfuran 

2-Methylindole - - - 

l-Methylnaphthalene 

iCand  2 ) -Methylnaphthalene 

2-Methylnaphthalene 

Methylnaphthalene,  crude 

N-Methyl-p-nitroacetanllide 

N-Methyl-p-nitroanlline 

'I -Methyl -o-nitroanisole 

»2-Methyl-l-nitroanthraqulnDne 

N-Methyl-2-nltro-l-phenol-4-sulfonaiiilde 

m- ( 3-Methyl-5-oxo-2-pyrazolin-l-yl ) benzenesulf ona- 

mide. 
m- ( 3-Methyl-5-oxo-2-pyrazolln-l-yl) benzenesulf onic 
acid. 

»p-C3-Methyl-5-oxo-2-pyrazolln-l-yl) benzenesulf onic 
acid  (3 -Methyl - 1 - ( p - sulf opheny 1 ) - 5 -pyrazolone ) . 
6-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-l,3-naphtha- 

lenedisulfonic  acid. 
3-(3-Methyl-5-oxo-2-pyrazolln-l-yl)-5-nltro-p- 

toluenesulfonic  acid. 
•4-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-m-toluenesulfonlc 

acid. 
5-Methyl-o-phenetidine  [NH2=1] - 

»3-Methyl-l-phenyl-2-pyrazolln-5-one  (Developer  Z) 

Jfethylplperazine 

Methylpropylcarbinylbarbituric  acid 

l-Methylpyrrole 

N^fethylpyrrolidine 

»a-Methylstyrene »- 

N-Methyl-5-sulfoanthranilic  acid 

1-Naphthaldehyde 

"Naphthalene,  solidifying  at  79°  C,  or  above 
(refined  flake): 

"From  American  crude  naphthalene ■ 

»From  Imported  crude  naphthalene 

1-Naphthaleneacetonitrile 

1,5-Naphthalenediol  (1,5-Dihydroxynaphthalene) 

2,3-Naphthalenediol 

«l,5-Naphthalenedisulfom.c  acid 

1,5-Naphthalenedisulfonlc  acid,  sodium  salt 

1,6-Naphthalenedisulfonic  acid,  sodium  salt 

2,6-Naphthalenedisulfonlc  acid 

2,7-Naphthalenedisulfonlc  acid 

2-Naphthn1 enesulfonic  acid 

l-Naphthalenes\ilfonlc  acid,  sodium  salt 

2-Naphthn1  enesulfonic  acid,  sodium  salt 

2-Naphthalenesulfonyl  chloride 

1,4,5,8-Naphthalenetetracarboxylio  dianhydride 

1,3,6-Naphthalenetrisulfonlc  acid 

Naphthalic  anhydride 

Naphthallmlde 

Naphthlonlc  acid  ( 4-Amino-l-naphthHl enesulfonic 
acid). 

«Napthlonlo  acid,  sodium  salt 

1-Naphtholc  acid 

»l-Naphthol  (a-Naphthol) 

2-Naphthol,  tech.  (/5-Naphthol)- - 

l-Naphthol-3,6-disulfonic  acid,  monosodlum  salt 

l-Naphthol-3,8-dlsulfonio  acid 

»2-Naphthol-3,6-dlsulfonlc  acid  (R  acid) 

»2-Naphthol-3,6-dlsulfonlc  acid,  disodium  salt 

»2-Naphthol-6,8-dlsulfonic  acid  (G  acid) 

2-Naphthol-6,8-dlsulfonlc  acid,  disodimn  salt 

l-Naphthol-3-sulfonamlde 

2-Naphthol-6-sulfonajiilde 

l-Naphthol-3-sulfonic  acid,  sodium  salt 

l-Naphthol-4-sulfonlc  acid  (Nevlle  &  Winther's 
acid) . 

»l-Naphthol-5-sulfonlo  acid 

l-Naphthol-8-sulfonic  acid 

»2-Naphthol-6-sulfonlc  acid  (Schaeffer's  acid) 

2-Naphthol-6-sulfonlc  acid,  sodium  salt 

2-Naphthol -7-sulfonlc  acid  and  sodium  salt 


253,  506. 


510. 
537. 
537. 
253, 
506. 
iOA. 
253. 
253. 
512. 
512. 
512. 
304, 
510. 
510. 
253. 
253, 
577. 
253, 


457,  506,  510,  577. 
577. 


401,  577. 

253,  288,  401,  447,  453,  510,  537,  604. 

577. 

510. 


577, 

577. 

124, 

456. 

422. 

X. 

422. 

212, 

510, 

316. 


191,  252,  253,  288,  348,  401,  506,  577. 


252,  537,  558. 
577. 


367,  485,  512,  537,  558. 
367,  485,  537,  558. 


510,  577. 


506,  577. 
506,  537. 


537. 
510. 


577. 
537. 


253,  506,  577. 

316. 

253,  506,  510. 

485,  506,  510,  537. 

577. 

253. 

492,  506,  577. 

94,  510,  537. 

253,  506,  510,  577. 

537. 

510. 

253. 

510. 

253,  506,  577. 

253,  506,  577. 

401,  506,  510. 

416,  506,  510,  537,  577. 

94,  253,  485. 

253,  485. 


76  UNITED  STATES  TARIFF  COMMISSION 

TABTi  7B. --Synthetic  organic  chemicals:   Cyclic  intermediates   for  which  United  State 
or  sales  were  reported,    identified  by  manufacturer,    J956--Continued 


2-Naphthol-8-sulfonlo  acid 

l-Naphthol-3,6,8-trlsiafonlo  acid,  trlsodlum  salt-- 

Ij-i-Naphthoqulnone 

Naphthoetyrll 

»l,8-Naphthosultone 

Naphtho[2,l-b]thiophen-l(2H)-one— - 

Naphth[l,2]  oxadlazole-5,9-DaphthaaenedlEulfonlc 
acid. 

t<Naphth[l,2]  oxadlazole-b-sulfonlo  acid 

1-Naplitl)ylamlne   (a-Naphthylamlne) 

l-Naphthylamlne  sulfate 

2-Naphthjrlamliie   {/^ -Naphthylamlne ) 

l-(2-Naphthylainlno)-2-aiithraqulnonecart)Oxyllc  acid- 
»2-(Naphthylthlo)acetlo  acid   (/S-Naphthylthloglycolic 
acid). 

Nicotinic  acid,   tech 

Nicotinic  acid,  n-butyl  ester 

Nicotlnonitrile   O-Cyanopyridine) 

m-Nltroaoetanilide 

<<p-Nitroacetanilide 

2-Nitro-p-acetanlsidide 

41  and  5)-Nltro-o-acetanlsidlde 

p-Nltroacetophenone 

«m-Nitro aniline 

o-Nitro aniline 

p-Nltro aniline 

»2-Nltro-p-anisldlne  [  NH2=1] 

»3-Nltro-o-anisldlne  [  NHj=l] 

*4-Nitro-o-anisldine  [  NH2=1] 

»5-Nitro-o-anlsidine  [  NH2=1] - 

o-Nltroanlsole 

p-Nltroanisole 

l-Nitroanthraqulnone 

l-Nltro-2-anthraquinonecarbonyl  chloride 

*l-Nitro-2-anthraquinoneoar'boxyllc  acid 

l-Nitro-2-anthraqu±noneoarbo3£yllc  acid,  hydrazlde — 

»5-Nltro-l-anthraquinoiiesulfonlc  acid 

5(and  8)-Nltro-l-anthra<iulnonesulfonlc  acid 

8-Nitro-l-anthraquinoneBulfonic  acid 

S-Nltro-l-anthraqulnonesulfonlc  acid,   sodium  salt — 
2-(l-Nltro-2-anthraquinonyl)anthra[2,3]oxazole- 
5,10-dlone. 

m-Nltrobenzaldehyde 

6"[p-(p-Nltrobenzaiiiido)benzamldo]-l-naphthol-3- 

sulfonlc  acid. 
6-(m-Nltrobenzamldo) -l-naphthDl-3-sulfonlc  acid 

(m-Nltrobenzoyl  J  acid). 
6-(p-Nltrobenzamldo) -l-naphthol-3-eulfonic  acid 
(p-Nitrobeuzoyl  J  acid). 

3-(m-Nitrobenzamldo)-l-phenyl-2-pyrazolin-5-one 

"Nitrobenisene 

2-Nltro-p-benzenediEUlfonlc  acid 

m-NltrobenzeneSulfonainide 

3'  -Nitrobenzenesulfonanlllde 

"m-Nltrobenzenesulfonlc  acid  and  sodium  salt 

m-Nitrobenzeneeulfonlc  acid,  trihydrate,  sodium 
salt. 

p-Nitrobenzenesulfonic  acid 

m-Nltrobenzenesulfonyl  chloride 

p-Nitrobenzenesulfonyl  chloride 

5-Nltro-2(3H)-ben2iiiildazolone 

m-Nltrobenzolc  acid 

p-Nltrobenzolc  acid 

p-Nltrobenzolo  acid,  butyl  ester 

p-Nltrobenzoic  acid,  ethyl  ester 

p-Nltrobenzolc  acid,  Isobutyl  ester 

p-Nltrobenzoic  acid,  propyl  ester 

m-Nltrobenzoyl  chloride 

p-Nitrobenzoyl  chloride 

2-Nitrobiphenyl 

2(and  'i)-Nltroblphenyl 

"i-Nltrobiphenyl 

4' -Nltro-4-blphenylcarboxylic  acid 

2-Nltro-p-cresol 

't-Nltro-o-cresol 

Nltrodlphenylamlne 

1-Nitronaphthalene 

3-Nitro-l,5-naphthalenedisulfonlc   acid 

8-Nltro-l-naphthalenesulfonic   acid 

8(and  5)-Nltro-l(and  2)-naphthalenesulfonic   acid — 
8-Nitro-l,3,6-naphthalenetrlsulfonlo  acid, 

calcium  salt. 
7(and  8)-Nltronaphth[l,2]  oxadiazole-5-sulfonlc 
acid. 


Manufacturers'   identification  numbers 
(according  to  list  in  table  27) 


253. 

506. 

253. 

288,  510 

537 

577. 

577. 

577. 

253,  288 

506 

510, 

577. 

253,  506 

510. 

577. 

253,  AA8 

506,  577 

253,  -Wl 

506, 

510, 

537,  577. 

512. 

456. 

361. 

577,  604. 

4^3,  492 

510 

577, 

253,  44.3 

510. 

510. 

206. 

253,  506, 

537, 

577. 

221,  604. 

221,  604. 

253,  492, 

506, 

510. 

506,  604. 

492,  510. 

253,  401, 

448, 

510, 

537. 

221,  253, 

604. 

253. 

604. 

253. 

253,  506, 

510, 

577. 

253. 

253,  506, 

510, 

577, 

605. 

506,  577. 

253. 

253. 

510. 

492. 

253. 

401,  577. 

253,  401. 

477. 

221,  253, 

455, 

506, 

510,  537. 

577. 

253,  577. 

577. 

221,  253, 

288, 

506, 

510,  577,  605 

4ii3. 

537. 

510. 

506. 

253. 

468,  608. 

253,  506, 

510. 

365. 

365. 

365. 

365. 

468. 

253,  371, 

468, 

510. 

221. 

253. 

221,  253. 

253,  510. 

253,  577. 

456. 

537. 

253,  506, 

510, 

510,  577. 

510. 

510. 

510. 

506,  510, 

577. 

SYNTHETIC  ORGANIC  CHEMICALS,  1956 

TABLE  7B.- -Synthetic  organic  chemicals:    Cyclic   intermediates    for   which  United  States  production 
or   sales  were  reported,   identified  by  manufacturer,   1956--Continued 


77 


Manufacturers '   Identification  numbers 
(according  to  Hat  in  table  27) 


•4'-NitrooxanlHc  acid 

Nitrophenethyl  alcohol 

p-Nitrophenethyl  alcohol  acetate 

o-Nltrophenetole 

p-Nitrophenetole 

o-Nitrophenol 

p-Nitrophenol 

2-Nitro-l-phenol-4-sulfonanllide 

4'-(p-Nitrophenyl)aoetophenDne 

N,N'-('V-Nltro-m-phenylene)bis  [aoetamide  ] 

<V-Nitro-m-phenylenedianilne 

4-Nitro-o-phenylenediainine 

2-Nitrophenyl  ether 

p-Nltrophenylhydrazlne 

2-C4-Nltrophenyl) -2H-naphtho [l,2]triazole-6,8- 

dlsulfonlc  acid. 
l-(m-NitropheDyl)-5-oxo-2-pyrazollne-3-carboxylic 
acid. 

p-(p-Nitrophenylthio) aniline 

4-Nitrophthallmide 

3(and  5)-Nitrosalicylic  acid 

4-Nitrosodiphenylaiiilne 

l-NitroBO-2-naphthol 

p-Nitrosophenol 

ti-Nltrostyrene 

2- [4- (4-Nitro-2-sulf ostyryl) -3-sulfophenyl] -2H- 
naphtho[l,2]triazole-5-sulfonlo  acid. 

m-Nitrotoluene 

o-Nltrotoluene 

p-Nitro toluene 

Nitrotoluene  mixtures 

3-Nitro-p-toluenesulfonlc  acid   [S03H=il  

»5-Nitro-o-toluenesulfonic  acid   [SOjH^l] 

i'-Nitro-p-toluenesulfono-o-toluldide 

»2-Nitro-p-toluidine  [NHjn] 

4-Nitro-o-toluidine  [nH2=1] 

5-Nitro-o-toluldine  [nH2=1] 

l-Nltro-2,'i,5-trichlorobenzene 

2-Nitro-3,4,6-trichlorophenol 

»16-Nitroviolanthrone 

2-Nitro-p-xylene 

<i-Nitro-m-xylene 

Nitroxylenes,  mixed 

Nonyl-  and  dodecylbenzenes ,  mixed 

«NonylphenDl 

2-(Nonylphenoxy)ethanol 

Octylphenol 

Oxalacetic  acid,  diethylester,  p-sulfophenyl- 

hydrazone. 
6-0xo-6H-anthr[9,l]lEOthiazole-3-carbonyl  chloride — 

6-0xo-6H-anthr[9,l]isothiazole-3-carboxylic  acid 

l-(7-0xo-7H-benz[de]anthraceu-3-ylajiilno)anthra- 

quinone. 
l,l'-(7-0xo-7H-benz  [de]  anthracen-3,9-ylenedi1m1nn)- 
dianthraquinone . 

5-0xo-l-phenyl-2-pyrazoline-3-carboxylic  acid 

5-Oxo-l-phenyl-2-pyrazoline-3-carboxylic  acid,  ethyl 
ester. 

»5-0xo-l-(p-EUlfophenyl)-2-pyrazoline-3-carboxylic 
acid   (Pyrazolone  T) . 

Pentabromoindigotln 

Pentadecylbenzene 

3,<»,9,10-Perylenetetraoarboxylio  acid 

3,4,9,10-Perylenetetracarboxylic  diimide 

Phenethylamlne 

o-Phenetidine 

p-Phenetidine 

iffherol: 
^Natural: 

From  coal  tar:^ 

U.S.? - 

39°  C,  m.p 

82^8Af- 

All  other 

From  petroleum:     Other 

»Synthetic: 

By  caustic  fusion:  U.S.P 

From  chlorobenzene  by  liquid-phase  hydrolysis: 

U.S.P - 

Fran  chlorobenzene  by  vapor-phase  hydrolysis: 

U.S.P — — 

Fran  cumene 

l-Phenol-2-sulfonlo  acid 

See  footnote  at  end  of  table. 


253, 

510. 

U3. 

i43. 

253. 

253. 

213, 

253. 

221, 

253, 

506, 

510. 

577. 

253. 

510. 

510. 

218, 

253. 

401. 

477. 

577. 

253, 

510, 

577. 

253. 

253. 

510. 

455, 

510. 

477. 

218, 

253, 

506, 

510,    537. 

267. 

577. 

253. 

253, 

506, 

510. 

253, 

506. 

506, 

537. 

288, 

401, 

510, 

537. 

253, 

506, 

510, 

577,   604. 

510. 

253, 

485, 

492, 

515,    537,    604 

253, 

492, 

510. 

253, 

401, 

492, 

604. 

604. 

577. 

510, 

537, 

577. 

253, 

510. 

253, 

510. 

506, 

537. 

278. 

405, 

455, 

510, 

566. 

510. 

338, 

566. 

577. 

253. 

253. 

253. 

253. 

401, 

510. 

510. 

401, 

453, 

510, 

604. 

510. 

251. 

510. 

510. 

266, 

353 

468 

482.  . 

221 

253. 

221, 

253. 

512. 

367,  512,  513,  537,  558. 

367,  512,  558. 

367,  512,  537,  558,  609. 

138,  562,  609. 

221,  466,  564. 

252. 

421,  478. 
212,  552,  558. 
237. 


78 


UNITED  STATES  TARIFF  COMMISSION 


-Synthetic  organic  chemicals 
or  sales  were  reported. 


■    Cyclic  intermediates   for  which  United  States  production 
identified  by  manufacturer,    1956- -Continued 


Uanuf acturere '  Identification  numbers 
(according  to  list  in  table  27) 


l-Phenol-<i-sulfonlo  acid 

Phenoxyacetic  acid 

o-Phenoxyaniline 

»Plienylacetic  acid  (a-Toluio  acid) 

Phenylacetlo  acid,  ethyl  ester,  tech 

Phenylacetlo  acid,  methyl  ester,  tech 

*Phenylacetic  acid,  potaeslum  salt 

Phenylaoetlc  aeld,  sodixjm  salt 

oPhenylacetonltrile  (a-Tolunltrile) 

A'  -Phenylacetophenone 

2-Phenylanthr[2,3]oxazole-5,10-dlone 

"p-Phenylazoanillnfi   (p-JUnlnoazobenzene)   and  hydro- 
chloride . 

4-Phenylazo-2,5-xylldlne  hydrochloride 

N^-Pheiiyl-l,2,'i-'benzenetriamine 

2-Phenylbutyraiiilde 

2-Phenylbutyrlc  acid 

Phenylcyclohexane 

N-Phenyldlbenzylamlne 

N,N'-(p-Phenylene)bis  [acetamldel 

272'-(p-Phenylene)bis  [5-(l-nltro-2-aiithraqulnonyl) 
l,3,'»-oxadlazole] . 

«m-Phenylenediamlne 

*o-Phenylenedi amine 

«p-Phenylenediamine 

m-Phenylenedibenzoate 

l,l'-(p-Phenylenedioarbonyl)bis[2-(l-nltro-2- 

anthraquinonylcarbonyl) hydrazine ] . 
Phenyl  ether  (Dlphenyl  oxide) 

»Phenylglycine  salts: 

Potassium  salt 

Sodium  salt 

Phenylhydrazine 

Phenylhydrazlne  hydrochloride 

»2,2'-(Phenylimino)diethanol  (Phenyldiethanolamlne) 

Phenylmalonic  acid,  diethyl  ester 

o-Phenylphenol 

o-Phenylphenol,  chlorinated 

o-Phenylphenol,  sodium  salt 

p-Phenylphenol 

N-Phenyl-p-phenylenedlamlne 

Phenyl-2-propanone 

Phenyl  2-pyridyl  ketone 

Phenyl  4-pyridyl  ketone 

Phenyl  tetramer 

Phenyl thloacetlc  acid 

Phloroglucinol 

Phthallc  acid 

Phthalic  acid,  dlootyl  ester 

Phthallc  acid,  disodium  salt 

»Phthalic  anhydride . 

Phthallc  anhydride  residue 

«Phthalimide 

Phthalonltrlle 

Phthaloyl  chloride  (Phthalyl  chloride) 

Picollnes:^ 

»2-Pioollne  (a-Pioollne) 

3-Plcollne  (p-Plcollne) 

<;-Picoline  (y-Plcollne) 

»Picoline  (3,4-mlxture) 

Plcollnlc  acid 

Picramlc  acid  and  salt 

Picric  acid  (Trinitrophenol) 

2-Pipecoline  (a-Plpecollne) 

Piperazlne  mixture 

Piperldlne 

Polychloroblphenyl 

Polydodeoylbenzene 

Polyethylbenzene  (80'f>  Diethylbenzene) 

Polylsocyanates 

Polylsopropylblphenyl 

Polypentadecylbenzene 

Primuline  base 

Priraulinesulfonic  acid 

Propiophenone 

Purpurin  (1,2,'i-Trlhydroxyanthraquinoue) 

Pyridine,  refined:^ 

«2°  Pyridine 

Other  grades 

3-Pyrldlnol 

2-Pyrldylbenzhydrol 

A-Pyridylbenzhydrol 

Pyrrolidine 

See  footnote  at  end  of  table. 


221,  252. 

252. 

AOl. 

266,  330,  337,  353. 

266,  5&i. 

266. 

221,  266,  330,  353,  AS2. 

330. 

221,  266,  330,  3AS,   353. 

510. 

510. 

253,  506,  510,  537,  577,  60^. 

253. 
364. 
266. 
266. 

221,  477. 
253. 

510,  537. 
253. 

70,  253,  506,  510,  537,  604. 

218,  385,  492,  577,  581, 

485,  515,  537. 

510. 

253. 


252. 

252. 
253, 
252. 
364, 
253, 
266, 
221, 
252. 
252. 
252. 
253, 
396, 
512. 
512. 
591. 
356. 
581. 
330, 
558. 
385. 
221, 
552, 
252, 
558. 
221. 


506. 

510. 

443,  510,  529,  577. 

348. 

252. 


510. 
490. 


385,  510. 


260,  367,  466,  473,  485,  506,  537,  552,  558. 

558. 

253,  267,  385,  506,  510. 


367,  512,  529,  558. 

512. 

512,  529. 

367,  512,  558. 

361. 

253,  506. 

253,  403. 

422,  512. 

405. 

221,  253,  468. 

221. 

251. 

367. 

607. 

221. 

251. 

253,  506,  510. 

224,  253,  510. 

353,  365,  367. 

510. 

367,  512,  558. 

367,  512. 

361. 

512. 

512. 

253. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 

TABLE  7B. --Synthetic  organic   chemical^:    Cyclic   intermediates   for   which  United  State 
or   sales   were   reported,    identified  by  manufacturer ,    1956- -Continued 


79 


product  i 


Manufacturers'  Identification  numbers 
(according  to  list  in  table  27) 


2-Pyrrolidone 

■xQulnaldlne 

Qulnaldlne  yellow, 
iiQulnizarin 


2-Qulnizarinsulfonlc  acid 

Quinoline : 

Quinollne,   1°   and  2° 

Other  grades 

2,'i-Quinolinediol 

Quinoline  yellow,  base 

Quinophthalone  (2,2'-(l,3-Indandione)quinoline)- 

Resorcinol,  tech 

Resorcinol  monobenzoate 

p-Resorcylaldehyde 

»p-Resorcylic  acid 

Salicylalaminoguanidlne  oleate 

^Salicylic  acid,  tech 

Salicylic  acid  (ammonium  chromium  complex) 

Salicylic  acid  carbonate,  diethyl  ester 

Sodium  phenoxide 

Styphnic  acid,  lead  salt 

«Styrene  (Vinylbenzene) ,  all  grades 

i'-Sulfamoylacetanllide 

N-S>ilfamoyl-p-toliiene  sulfonamide 

Sulfanllic  acid  (p-Amlnobenzolc  acid)  and  salt- 

"i-Sulfoanthranllic  acid 

p-Sulfobenzoio  acid,  sodium  salt 

o-Sulfobenzoio  anhydride 

Sulfonamide,  yellow 

Sulfonamide  chloride,  yellow 

i,,U '-Sulf onyldiphenol  (4,4 '-Dihydroxydiphenyl- 
sulfone) . 

4-Sulfophthalio  acid 

Terephthalic  acid 

Terephthallc  acid,  dimethyl  ester 

Terphenyl  (Phenylbiphenyl) 

»Tetrabromo-8,16-pyranthrenedione 

»l,4,5,8-Tetrachloroanthraq.uinone 

»l,2,4,5-Tetrachlorobenzene 

Tetrachloronitrobenzene 

Tetrachlorophthallc  anhydride 

a, a,2,6-Tetrachlorotoluene 

Tetrahydrofuran 

TetraMsaminophthalocyanlne,  copper  salt 

»1,4,5,8-Tetrald.s[l',  l",  l'",  l""-anthra- 
quinonylamino]  anthraqulnone  (Pentaanthramide) 

TetraJd-snltrophthalocyanine,  copper  salt 

1,2,4,5-Tetramethylbenzene  (Durene) 

2- (2-Thenylidene ami no) pyridine 

Thiamine  hydrobromide 

3(2H)-Thianaphthenone 

Thio  acid ^^ 

«3,3'-Thiobis[7H-benz[de]anthracen-7-one] 

4,4 '-Thlodiani  line — 

6,6 '-Thiodimetanillc  acid 

4,4'-Thiodiresorclnol 

2-Thiophenecarboxaldehyde 

m-Tolidine  dlhydrochlorlde 

«o-Tolidine  and  salts 

o-Tolldine  hydrochloride 

<<Toluene-2,4-diamine  (4-m-Tolylenediamlne) 

Toluene-2,4-disulfonic  acid 

o-Toluenesulfonamide 

o(and  p) -Toluenesulfonamlde 

p-Toluenesulfonamlde 

o(and  p) -Toluenesulf onic  acid 

p-Toluenesulfonlo  acid,  anhydrous 

p-Toluenesulfonic  acid,  2-chloroethyl  ester 

p-Toluenesulfonlc  acid,  ethyl  ester 

p-Toluenesulfonic  acid,  isopropyl  ester 

p-Toluenesulfonic  acid,  methyl  ester 

p-Toluenesulfonic  acid  raonohydrate 

p-Toluenesulfono-o-toluidide 

o-Toluenesulfonyl  chloride 

p -Toluenesulf onyl  chloride 

p-Toluhydroqulnone 

p-Toluic  acid 

m-Toluidine 

o-Toluldine 

o-Toluidine  hydrochloride 

p-Toluldine 

Toluidines,  mixed 


510. 

253,  367,  506,  512,  537. 

537. 

253,  267,  288,  430,  440,  443,  448,  457,  506, 

515,  537,  577,  604,  605. 
370,  515. 


510, 


367,   512,   558. 

218,  477,   512. 

253. 

506,   510. 

253. 

307. 

443. 

510. 

367,    537,  X. 

25  J. 

221,   252,   504. 

577. 

252. 

253,  364. 

56. 

221,   252,   367, 

4S1,    529,  X. 

537. 

604. 

506,   537,   577. 

288,  401,   510. 

510. 

477. 

604. 

604. 

221,   237,   510. 

267. 

253. 

212,   253,    604. 

221. 

506,    510,   577. 

253,  457,   506, 

510. 

221,   252,  468, 

550. 

492. 

468. 

253. 

253. 

253. 

253,  457,    506, 

510. 

253. 

434. 

456. 

560. 

510. 

604. 

253,  457,    510, 

577. 

506. 

506. 

335. 

456. 

267. 

253,   267,    506, 

577. 

253. 

191,   253,   403, 

506,    510,    537, 

577 

510. 

221. 

537. 

221,   537. 

221,  237,  485. 

612. 

510. 

213,    604. 

253,   566. 

213,   221,  457 

237,   510. 

253,    510. 

221. 

221. 

443. 

253. 

253,   367,    506 

510. 

253,    506,    510 

604. 

253,    506. 

537. 

80 


UNITED  STATES  TARIFF  COMMISSION 


TABLE   7B. --Synthetic  organic  chemicals:   Cyclic   intermediates    for   which  United  Stat 
or  sales  were  reported,    identified  by  manufacturer ,    1956- -Continued 


production 


Manufacturers'   identification  numbers 
(according  to  list  in  table  27) 


6-Cp-Toluidino)metanilic  acid 

m-Toluidlnomethanesulfonic  acid 

o-Toluidinomethanesulfonic  acid 

8-(p-Toluldino) -l-naphthalenesulfonio  acid 

2-{p-Toluidino) -5-nitrobenzenesulfonic  acid 

l-(o-Toluidlno)-2-propanol 

o-Tolunitrile 

*o-(p-Toluoyl) benzoic  acid 

»^-(o-Tolylazo)  -o-toluidijie   (o-Ainlnoazotoluene) 

o-(p-Tolyl)benzoio  acid 

2,2'-(m-Tolyliiiilno)diethanol 

[ 3- (p-Tolyl)-l-niethyltriazen-3-yl] acetic  aoi-d 

2,4,6-Tribromophenol 

1,2, 3 (and  l,2,'4)-TrichlorobenzeDe 

1,2,4-Trichlorobenzene 

l,2,A-Trichloro-5-nitrobenzene 

Triohlorophenylsilane 

»a,a, a-Trichlorotcluene   (Benaotrichloride) 

a,2,'i-Trichlorotoluene 

a,2,'4(and   a,2,6)-Triohlorotoluene 

a,3,4-Trichlorotoluene 

l,3,5-Trlchloro-s-triazine-2,'i,6(lH,3H,5H)-trione  — 

1,3,5-Triethylbenzene 

a,a,  o-Trlfluorotoluene 

a,  a,  (x-Trifluoro-m-toluidine 

2,4,5-Trimethylaniline  (Pseudooumidine)  (psi- 
Cumidine). 

l,3,3-Trlinethyl-A^,"-indolineaoetaldehyde 

1 , 3 ,3 -Trimethyl -2 -methyleneindolineacetaldehyde 

2,4,6-Trinitrobenzoic  acid 

2,'l,6-Tris(dlmethylaminomethyl)phenol 

»6,6'-Ureylenebis [l-naphthol-3-sulfonlo  acid] 
(J  acid  urea) . 

»Veratraldehyde  (3,4-Dimethoxybenzaldehyde) 

Veratrole 

9-Vinylcarbazole 

A-Vinylcyclohexene-1 

5-Vinyl-2-picoline  (MVP) 

2-Vinylpyridine 

'♦-Vinylpyridine 

»Violanthrone  (Dibenzanthrone) 

9-Xanthenecarboxylio  acid 

m-Xylene ' 

«o-Xylene 

p-Xylene 

Xylenesulfonic  acid 

Xylenol  crystals 

*Xylenols : 

Low  b.p 

Medium  b.p 

Not  classified  as  to  b.p 

»Xylidines : 

2,';-Xylldine  (m-4-Xylidine) 

2,5-Xylidine  (p-Xylidine) - -: 

Xylidlnes,  mixed: 

Original  mixture 

»Xylidine  (ortho,  para) 

2,5-Xylidlne  hydrochloride 

'4-(2,^-Xylylazo)-o-toluidine 

4-(2,5-Xylylazo)-o-toluidine - 

4-(2,'i-Xylylazo)-2,5-xylidine - 

All  other  intermediates 


506,  577. 

288,  401. 

506. 

506. 

577. 

AA3. 

303. 

253,  510,  537. 

253,  506,  510,  537. 

506. 

4^3,  510, 

510. 

252. 

252,  550. 
221,  468. 
510. 
2M. 

303,  468,  504. 

504. 

266. 

504. 

221. 

253. 

468. 

569. 

147,  506. 

253. 
253. 
581. 
566. 
61,  253,  265,  288,  401,  453,  506,  510,  537,  577. 

221,  282,  337,  365. 

221. 

510. 

516. 

465. 

512. 

512. 

253,  457,  510,  537,  577,  604,  605. 
564. 

337,  552. 

434,  479,  552. 

434,  552. 

206,  237. 
558. 

512,  562,  609. 
512,  562,  609. 
260,  512,  537. 

253,  510. 
253,  506,  510. 

506,  537. 

253,  537. 

506. 

506. 

537. 

506,  604. 

430. 


^   Does  not  include  manufacturers '  identification  numbers  for  producers  who  report  to  the  Division  of  Bitu- 
minous Coal,  U.  S.  Bureau  of  Mines.  These  producers  are  listed  in  the  U.  S.  Bureau  of  Mines  Directory  of 
Oven-Coke  Plants  in   the  United  States,  December  31,  1955,    Mineral  Market  Report  M.M.S.  No.  2509,  issued 
May  1956. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 

Dyes 


81 


TABLE  S3. -Synthetic  organic  chemicals:   Coal-tar  dyes    for  which  United  States  production  or   sales  were 
reported,    identified  by  manufacturer ,   1956 

[Dyes  for  which  separate  statistics  are  given  in  table  8A  are  marked  below  with  an  asterisk  (»);  dyes  not 
so  marked  do  not  appear  in  table  8A  because  the  reported  data  are  accepted  i^  confidence  and  may  not  be 
published.  Manufacturers'  identification  numbers  shown  below  are  taken  from  table  27.  An  X  signifies  that 
the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number  with  the  designated 
product] 


Dye 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBER 
Nitroso  Dyes 

Naphthol  green  B 

yVitro  Dyis 

Naphthol  yellow  S - 

Amldo  yellow  E 

Azo   Dvtt 

Monoazo  Dyes 


Spirit  yellow  G— ■ 

Acid  yellow  G 

•Spirit  yellow  R 

*011  yellow 

•KChryBOidine  Y 

•ChryBOidine  R 

•Sudan  I 

Froceine  orange  G 

♦Orange  G 

Chromotrope  2R 

Fast  acid  fuchsine  B 

»Amido  naphthol  red  G 

Brilliant  sulphon  red — 

•Chrome  yellow  2G 

•Chrome  yellow  R 

Fast  red  2G  salt 

•A20  alizarin  yellow  GP- 

Vlctoria  violet  ABS 

Chromotrope  6B 

•Anido  naphthol  red  6B — 

Fibre  black  V— 

•Fast  scarlet  G  base 

Fast  scarlet  G  salt 

•Fast  red  GL  base 

•Fast  red  GL  salt 

•Sudan  II 

•Ponceau  R 

Double  ponceau 

•Fast  red  B 

Chrcmotrope  lOB 

•Chrome  brown  R 

Chrome  green  2G 

Chromate  brown  B 

Acid  chrome  brown  R 

Chrome  flavlne  G 

Sudan  R 

•Azo  eoslne  G 

Fast  red  B  base 

•Fast  red  B  salt 

•Fast  scarlet  R  base 

•Fast  scarlet  R'salt 

Direct  pink 

Direct  fast  pink  EBN — 

iftJetanil  yellow 

Methyl  orange ^— 

•Azoflavine  RS 

Azo  yellow ~ — -7 

Resorcln  yellow 

•Orange  II 

•Orange  R 

Pigment  rabine  B 

Acid  chrome  brown  B 

•Acid  chrome  garnet  R— 
Acid  chrome  violet  N— 

Chrome  black  PV 

Naphthyl amine  brown 

•Fast  red  A 

•Azo  rublne 

Fast  red  VR 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


AOl,  537. 


506,  537. 
510. 


510, 

537. 

253, 

253, 

253, 

506, 

253, 

506. 

253, 

506. 

329, 

191, 

329, 

510, 

506, 

510, 

506, 

253, 

506, 

191, 

577. 

253, 

510, 

253, 

';92, 

^29, 

253, 

510. 

265, 

253. 

70, 

510. 

70. 

70, 

70, 

429. 

253, 

510, 

"Wl, 

253, 

401, 

506, 

510. 

191, 

265, 

506, 

506, 

506. 

265, 

253, 

253. 

506. 

506, 

70, 

506, 

510. 

253, 

253, 

506, 


506, 
429, 
510, 
537. 
506, 


510,  537,  604. 
506,  510,  537,  604. 
537. 


510,  537,  577,  604. 
265,  492,  506,  510,  537,  577. 


506, 
253, 
506. 
537, 
510, 
604. 
577, 
506, 
577. 
253, 

401, 
604. 
401, 
506, 
506, 
265, 


253, 


253. 
510. 


604. 
401, 

577, 
537, 

604. 
577. 

506, 

492, 

492, 

510, 

,  510, 

,  506, 

,  537, 

506, 


492,  506,  510,  537,  577,  604. 


604. 
577,  604. 


510,  537,  577,  604. 

604. 

596. 

596,  604. 

537,  604. 

510,  537,  577. 

577. 

510,  577. 


265,  288,  329,  401,  510,  577. 

605. 

492,  506,  510,  604,  605. 

506,  510,  596,  604. 

492,  506,  510,  537,  596,  604,  605. 

510. 

253,  492,  506,  537,  577. 

492. 

510,  577. 

604. 

329,  506,  510,  537,  577. 
492,  506,  510,  537,  577. 


510,  577. 
506. 
510,  577. 

265,  506,  510,  537,  577. 
265,  492,  506,  510,  577. 
510,  577. 


82 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  8B. --Syntheti 


rganic   chemicals;   Coal-tar   dyes    for  which  United  States  producti 
reported,    identified  by  manufacturer ,    7956--Continued 


Mamifacturers '  identification  numbers 
(according  to  list  In  table  27) 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBER— Continued 

Azo   Dyes--Contlnued 

Monoazo  Dyes — Continued 

Crocelne  scarlet  3BX 

Amaranth 

*Cochineal  red  A 

Mordant  yellow  0 

Chrome  yellow  RN 

Chrcme  blue  black  B 

••(Chrome  blue  black  R 

^Chrome  black  T 

Chrome  black  A 

Fast  acid  blue  R 

Fast  acid  blue  B 

«Acid  chrome  red  B 

»Chrome  flavine  A 

Direct  pink  2B 

Disazo  Dyes 

»Resoroin  brown 

»Resorcin  dark  brown 

Chrome  brown  G 

»Aoid  black  lOB 

»Azo  dark  green  A 

^Brilliant  crocelne  M 

Ponceau  SS  ex 

Sudan  IV 

•Cloth  red  B 

Neutral  gray  G 

•Milling  orange 

*Cloth  scarlet  G 

•Direct  fast  red  8BL 

Scarlet  EC 

Fast  acid  cyanine  G 

•Fast  acid  cyanine  5R  ex 

Acid  chrome  verdone  A 

Acid  black  B - - 

•Acid  chrome  black  F 

Acid  chrome  green  SS 

•Fast  acid  black  2BN 

Fast  acid  black  R 

Fast  acid  black  F 

•Fast  acid  cyanine  black  B 

Naphthylamine  black  D 

Developed  blue  B 

Naphthylamine  black  V 

•Direct  fast  heliotrope 

Rosanthrene 

•Direct  fast  scarlet 

•Direct  fast  scarlet  'VBA 

•Bismarck  brown  G 

•Bismarck  brown  R 

•Chrome  fast  yellow  C 

•Direct  fast  yellow  5GL 

Direct  fast  yellow  -iGL  ex 

•Direct  fast  pink  2BL 

•Brilliant  yellow 

•Chrysophenine  G 

•Congo  red 

•Congo  oorinth  G 

Congo  rubine 

Direct  orange  G 

•Direct  scarlet  B 

•Direct  violet  B 

Benzo  violet  0 

•Direct  violet  N 

Direct  black  RO 

Direct  brilliant  Bordeaux  R 

•Developed  black  BH 

Diphenyl  fast  gray  B 

Direct  cyanine  R 

•Direct  blue  2B 

Cresotine  yellow  0 

•Direct  orange  R 

•Direct  fast  red  F 


577. 
506, 
';92, 
506, 
506, 
506, 
253, 
506, 
506, 
506, 
506, 
440, 
253, 
253. 


577. 

506,  510,  537,  577. 

510,  577. 

510. 

510,  577. 

506,  510,  537,  577. 

510,  577. 

510,  577. 

510,  577. 

510. 

506,  510,  537,  577. 

506,  510,  577. 


253,  329,  506,  510,  537 

253,  329,  492,  506,  510 

253,  506. 

253,  265,  329,  492,  506 

253,  401,  506,  577. 

253,  265,  492,  506,  510 

506. 

253,  370,  506. 

506,  510,  577. 

253. 

510,  537,  577. 

329,  537,  577,  604. 

191,  253,  265,  288,  329 

510,  537,  577,  604. 
506,  510,  604. 
506,  510. 
253,  506,  510. 
506. 
506. 

506,  510,  577. 
510,  537. 
253,  506,  577. 
577. 
510. 

253,  506,  510. 
510. 

506,  510,  577. 
253. 

253,  401,  506,  577. 
253,  401,  604. 
61,  253,  265,  288,  401, 

537,  577,  604. 
253,  265,  401,  453,  510, 
253,  506,  510,  537,  577. 
253,  506,  510,  537,  577. 
253,  506,  537. 
191,  253,  401,  4^7,  453, 
2S8. 

253,  401,  506,  510,  537. 
253,  453,  506,  510,  537, 
253,  453,  506,  510,  577. 
253,  506,  577. 
265,  329,  506,  510,  537, 
446. 
506. 

329,  506,  510,  537,  577, 
253,  506,  510,  577. 
510. 

253,  430,  506,  510,  577, 
265. 
506. 

253,  265,  329,  453,  506, 
577. 
506. 

253,  265,  329,  506,  510, 
506,  577. 

253,  506,  510,  577. 
191,  253,  265,  329,  506, 


577,  604. 
537,  577,  604. 


510,  537,  577,  604. 
537,  577. 


401,  447,  453,  506, 


447,  453,  506,  510, 

537,  577. 

506,  510. 

577. 

577,  604. 

604. 

604. 

510,  537,  577. 

537,  577,  604. 

510,  577,  604. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


83 


TABLE  8B. --Synthetic  organic  chemicals:   Coal-tar  dyes   for  which  United  States  production  or  sales  were 
reported,    identified  by  manufacturer ,    J9J6--Continued 


Colour 
Index  or 

proto- 
type No. 


423 

430 

431 
436 
441 
443 
446 
448 
464 
466 
471 
472 
477 
478 
487 
495 
499 
499 
502 
508 
512 
515 
516 
518 

520 


533 
534 
539 
552 
561 
576 
581 
582 
583 
589 
593 
594 
596 
598 
601 


620 
621 
622 
626 
628 
631 


636 
639 
640 
642 
652 
653 


Dye 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBER- -Continued 


Azo  i)yes--Contlnued 

Disazo  Dyes — Continued 


itDireot  brown  M- 


Direct  brown  B- 
•Polar  red 


Acid  chrome  red 

Direct  brilliant  red  8B-' 
Chrome  fast  yellow  RD 

^Milling  red  G 

Direct  orange  R 

♦Benzopurpurine  4B 

Direct  blue  3R 

*Beuzo  new  blue  5B 

Direct  blue  4R 

Direct  blue  BX 

♦Direct  blue  3B 

Direct  orange  G 

»Acid  anthracene  red  3B — 
Benzopurpurine  lOB 

»FaBt  blue  B  base 

»Fast  blue  B  salt 

♦Direct  azurine  G 

Direct  brilliant  blue  G- 

»Direct  blue  RW 

Direct  blue  B 

Chicago  blue  B 

♦Direct  sky  blue  FF 


♦Direct  pure  blue- 


Trisazo  Dyes 


♦Direct  fast  blue  FR 

Dispersol  fast  yellow  2G- 
♦Direot  fast  black  FF 

Diazo  blue  black  RS 

♦Direct  brown  BT 

Direct  fast  blue  B 

♦Direct  black  EW 

♦Direct  black  RX 

♦Direct  green  ET 

Chloramine  green  B 

♦Direct  green  B 

Direct  green  G 

♦Direct  brown  3G0 

♦Congo  brown  G 

Congo  brown  R 


Tetrakisazo  Dyes 


Direct  brown  G- 


Stilbe: 

♦Direct  yellow  R 

♦Chloramine  orange  G-- 

♦Stilbene  yellow 

Diphenyl  orange  RR 

Diphenyl  oatechine  G- 
Diphenyl  chrysoine  G- 


Pyrazolc 

♦Fast  light  yellow  G~- 
♦Xylene  light  yellow-- 

♦Tartrazine 

♦Polar  yellow 

♦Chrome  red  B 

♦Pyrazol  orange 


^fjtonminj   Dye 


Manufacturers'    identification  numbers 
(according  to  list  in  table  27) 


191,    253,    265, 

604. 
329,    537,    577. 
191,    253,    288, 

537,    577. 
253. 

265,    577. 
401,    510. 
401,   440,    510, 
506,    604. 
253,    506,    577. 
253. 

253,   329,    506, 
506,    577. 
506,    510,    577. 
253,    265,    506, 
506,    577,    60i. 
401,    506,    510, 
253,    329,    506. 
253,   492,    510, 
401,   492,    506, 
253,    265,   329, 
253,   401. 
253,    288,   453, 
253,    577. 
510. 
253,    265,    288, 

577,    604. 
253,    265,    506, 


288,   329,    506,    510,    537,    577, 
329,   401,   447,   453,    506,    510, 


537,    577,    604. 

510,    577. 

577. 

537,    577,    604. 

596,    604. 

510,   604,    605. 

453,    506,    510,    537,    577,    604. 

506,    510,    577,    604. 

329,   401,   453,    506,    510,    537, 
510,    577. 


253, 
253. 
253, 
506. 
253, 
577. 
253, 
253, 
253, 
253, 
253, 
329, 
253, 
253, 
253. 


265,    577,    604. 
453,    506,    510,    577. 
329,    506,    510,    577,    604. 


329, 
329, 
329, 
329, 
329, 
506, 
329, 
265, 


453, 
453, 
453, 
506, 
506, 
577. 
506, 
506, 


506,    510,  537,  577. 

506,    510,  537,  577. 

506,    510,  537,  577,    604. 

577. 

510,    537,  577,  604. 

510,    537,  577,  60i. 

510,    577,  604. 


329,    510. 


253,    506,    510,    537,    577. 

253,    506,    510,    537. 

253,    506,    510,    537,    577. 

577. 

506. 

577. 


253,   401,    506,    510. 

253,    288,   401,   492,    506,    510,    537,    577. 

191,   401,   492,    506,    510,    537,    577,    604. 

288,   401,    506,    510,    577. 

70,   253,   288,  401,   506,   510,   537,   577. 

191,    288,   401,   447,   453,    506,    510,    577,   604. 


253,    506,    537. 


84 


TABLE  8B. -Synthetic 


UNITED  STATES  TARIFF  COMMISSION 

3nic  chemicals:  Coal-tar  dyes   for  which  United  States  producti 
reported,    ident  i  tied  by  manufacturer ,   i956 --Continued 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBER— Continued 

TriphenyUethane    and 
Diphtnylnaphthylmtthanr    Dyes 

^Malachite  green 

»Rhoduline  blue  6G 

•Brilliant  green 

Setocyanine 

*Acid  green  B 

»Fast  acid  green  B 

Acid  light  green 

»Acid  glaucine  blue 

Xylene  blue  VS 

}^lene  blue  AS 

»Para  fuchslne 

Magenta 

New  fuchsine 

«Methyl  violet  B  and  base 

•Crystal  violet 

•Ethyl  violet 

Benzyl  violet 

Spirit  blue  2B 

Acid  magenta 

Acid  violet  4BN 

Fast  acid  violet  lOB 

Wool  violet 

•Acid  violet 

Acid  fast  violet  BG 

Alkali  blue 

Methyl  blue 

Methyl  cotton  blue 

Soluble  blue 

Patent  blue  A 

•Acid  chrome  azurol  B 

•Acid  chrome  cyanlne  R 

Victoria  blue  R 

•Victoria  blue  B 

•Naphthalene  green  V 

•Wool  green  S 

Xanthene    Dyfs 

Xylene  red  B 

Rhodamlne  B,  20=6 

Rhodamine  B  cone,  IOO56 

Rhodamine  6G  cone,  lOOjt 

Fast  acid  violet  A2R 

•Fluorescein 

•Uranine  (Fluorescein,  alkali  salt) 

Eosine  G  (Tetrabromofluoresoein,  alkali  salt)-- 

•Tetrabromo  fluorescein 

Dinitrodibromo fluorescein 

Erythrosine  bluish 

Phloxine  B 

Rose  bengale  B 

Acridine  Dyes 

Acridine  orange  NO 

Brilliant  phosphine  G 

Phosphlne 

Euchrysine  2G 

Quinoline   Dyes 

Quinoline  yellow,  spirit-soluble 

•Quinoline  yellow 

Quinoline  yellow  KT 

Thiazole    Dyes 

•Prlmuline 

Direct  pure  yellow  M 

•Direct  fast  yellow 

Thioflavine  T 

Direct  brilliant  flavine  S 

Azine   Dyes 

Wool  fast  blue 

•Safranine 


355 

492, 

506, 

510, 

537. 

355 

492, 

506, 

510. 

253 

355, 

492, 

506, 

510, 

537. 

253 

506, 

510. 

253 

401, 

492, 

506, 

510, 

537,  577 

253 

401, 

492, 

506, 

510, 

537. 

510 

401 

492, 

506, 

510, 

537. 

506 

510. 

506 

510. 

104 

537, 

589. 

485 

537, 

589. 

537 

253 

355, 

506, 

510, 

537. 

253 

355, 

492, 

506, 

510. 

253 

355, 

506, 

510. 

355 

589 

510 

506 

253 

577. 

492 

506. 

253 

510, 

537, 

577. 

253 

104 

589. 

104 

104 

537 

589. 

537 

253 

506, 

510, 

577, 

604. 

253 

401, 

492, 

506, 

510, 

577. 

253 

355, 

492. 

253 

355, 

492, 

506, 

510. 

253 

492, 

506, 

510, 

537, 

577. 

401 

492, 

510, 

537. 

510 

253 

506. 

510 

537. 

253 

510. 

51, 

506. 

492 

502, 

537, 

589. 

492 

506, 

589. 

537 

589. 

462 

492, 

537, 

589. 

589 

589 

492 

589. 

589 

401,  506,  510. 

401. 

506,  537. 

401. 


506,  537. 

253,  506,  510,  537. 

253. 


253,  506,  577. 

253. 

224,  253,  506,  510,  577. 

253. 

224. 


506,  510,  577. 
253,  492,  506,  510. 


TABLE  8B. --Synthetic 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 

rganic   chemicals:   Coal-tar  dyes    for   which  United  States  produ 
reported,    identified  by  manufacturer ,    7956- -Continued 


85 


Colour 
Index  or 

proto- 
type No. 


Manufacturers '  Identification  numbers 
(according  to  list  in  table  27) 


842 
853 
860 
861 
864 
865 


871 
875 


883 
909 
913 


922 

924 
931 


948 
969 


1027 
1034 
1035 
1053 
1054 
1062 
1073 
1075 
1076 
1077 
1078 

1080 
1085 
1088 
1089 
1091 


1096 
1098 
1099 
1100 
1101 
1102 
1104 
1105 
1106 
1109 
1112 
1113 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBER— Continued 

Azine   Dyes- -Continued 

Methylene  violet 

Acid  cyanine 

Induline,  spirit-soluble 

»Induline,  water-soluble 

Nigrosine,  spirit-soluble 

Nigrosine,  water-soluble 

Aniline   Black   and  Allied  Dyes 

Diphenyl  black  base 

Pur  black 

Oxaiine  Dyes 

Gallocyanine 

New  blue  R 

Nile  blue  A- 

Thiaiine  Dyes 

^Methylene  blue 

Methylene  green  B 

Brilliant  chrome  blue 

Sulfur   or  Sulfide  Dyes 

Derivatives  of  Carbazole 

Immedial  yellow  D 

Carbazole  vat  blue  R 

Other  Sulfur  or  Sulfide  Dyes 

»Sulfur  black 

Sulfur  blue 

Sulfur  brown 

Sulfur  green 

xSulfur  maroon 

■xSulfur  olive 

Sulfur  orange 

Sulfur  tan 

•xSulfur  yellow 

Anthraqulnone    Dyes 

^Alizarin  VI - — 

»Alizarin  red  S 

Alizarin  brown 

»Acid  alizarin  blue  SE 

»Acid  alizarin  blue  B 

Anthracene  blue  WR 

■^Alizarin  irisol  R 

Alizarin  astrol  B 

Cyananthrol  R 

Cyananthrol  G 

♦Alizarin  cyanine  green 

Acid  anthraqulnone  violet 

»Anthraquinone  blue  black  B 

»Acid  anthraqulnone  sky  blue  B 

Anthraqulnone  blue  SR 

Acid  alizarin  rubine 

Anthraqulnone    Vat   Dyes 

♦Anthraqulnone  vat  golden  orange  0,  12j 

♦Anthraqulnone  vat  scarlet  G,  16-2/3^ 

♦Anthraqiiinone  vat  dark  blue  BO,  25^ 

♦Vat  navy  blue  NTP 

♦Anthraqulnone  vat  Jade  green,  6^ 

♦Anthraqulnone  vat  green  B  and  black  B,  12-1/2^- 
♦Anthraqulnone  vat  violet  2R,  12-1/2^ 

Anthraqulnone  vat  violet  B,  25$ 

♦Anthraqulnone  vat  blue  RS,  10$ 

Anthraqulnone  vat  blue  3G,  10$ 

♦Anthraqulnone  vat  blue  GCS,  8-1/3$ 

♦Anthraqulnone  vat  blue  GCD,  8-1/3$- 


506. 

510. 

506, 

537. 

506, 

510, 

537. 

506, 

510, 

537. 

506, 

510, 

537. 

537. 

537. 

440. 

506, 

537. 

510. 

492, 

506, 

510,    537 

537. 

510. 

510. 
253,  403. 


253,  403,  506,  510,  537. 

253,  394,  403,  506,  510,  537,  577. 

253,  394,  403,  506,  510,  537,  577. 

253,  394,  403,  506,  510,  537. 

253,  394,  506,  510,  537. 

253,  394,  403,  506,  510,  537. 

506. 

253,  394,  403. 

253,  394,  403,  506,  510,  537. 


506,  537,  604. 

401,  457,  506,  510,  537,  604. 

440. 

506,  510,  537,  577. 

253,  288,  506,  510,  537,  577. 

253,  440,  457,  604. 

457,  510. 

253,  457. 

457. 

253,  288,  370,  440,  457,  506,  510,  537,  577, 

604. 
457,  506. 

440,  457,  506,  510,  577,  604. 
253,  457,  506,  510. 
457. 
457,  510. 


253, 
253, 
224, 
253, 
160, 
224, 
253, 
457. 
253, 
253. 
253, 
253, 


288,  457,  506,  510,  537,  577,  604. 

288,  457,  506,  510,  537,  577,  604. 

253,  457,  506,  537,  577,  604,  605. 

457,  510,  537,  577,  604,  605. 

253,  457,  506,  510,  537,  577,  604,  605. 

253,  403,  506,  510,  537,  577,  604,  605. 

457,  506,  510,  537,  577. 

510,  537,  577. 

506,  510,  537,  577. 

401,  457,  506,  510,  537,  577,  604. 


86 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  SB. --Syntheti 


chemicals:   Coal-tar  dyes   for 
>rted.    identified  by  manufactu 


ch  United  States   produ 
1956- -Continued 


Mamif aoturers '  identification  numbers 
(according  to  list  in  table  27) 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBER— Continued 

Anthraqumone    Vat   D>es- -Continued 

Anthraqulnone  vat  yellow  G,  12-1/2^ 

Anthraquinone  vat  yellow  GK,   12-l/25t 

Anthraqulnone.  vat  brilliant  violet  RK,  12-l/25t- 

*Anthraquinone  vat  olive  R,   12-l/25t 

"Anthraqulnone  vat  brown  R,   12-l/2i6 

"Anthraqulnone  vat  brown  G,   12-l/25fc 

Anthraquinone  vat  red  violet  RRN,  12-l/2!t 

Anthraquinone  vat  red  BN,  ex.,  12-1/2^6 

"Anthraqulnone  vat  violet  BN,  25!^- 

Anthraqulnone  vat  yellow  R,  12-1/2^ 

Anthraquinone  vat  blue  3G,   12-l/25t 

Indigoid  and  Thioindigoid  Dyes 

"Indigo,  synthetic,  20'f, - 

Indigo,  white,  20^ 

Indigotin  lA 

Tribromindigo  RB,  20^t 

"Bromindigo  blue  2BD,  165( 

Indigo  blue  6B 

Ciba  pink  B,   205t 

"Vat  red  3B,    205t- 

"Vat  orange  R,   IO56 

Vat  fast  scarlet  G,   20^ 

food.    Drug,    and  Cosnetic   Dyes 
Food,   Drug,    and  Cosmetic  Colors 

"Blue  #1 — 

Blue  #1,  aluminum  lake 

"Blue  #2 - — 

Green  #1,  #2 

Green  #3 

"Orange  #1 

Orange  #2 

"Red  #1 — 

"Red  #2 — - - 

"Red  #3 - - - 

Red  #3,  aluminum  lake 

"Red  #4 - - 

Red  #32 - 

Violet  #1 - - 

Yellow  #1 

"Yellow  #3,  #4 - 

"Yellow  #5,  #6 -- 

Yellow  #5,  aluminum  lake 

Drug  and  Cosmetic  Colors 

Black  #1 - — 

Blue#l 

Blue  #i,    #9 

Blue  #6 

Brown  #1 

Green  #1,  #8 - 

Green  #5,  #6,   #7 — - 

Orange  #1 

Orange  #3 

"Orange  #4 

Orange  #5 

Orange  #15,  #17 -  — 

Orange  #16 

Red  #1,   #2 

Red  #3 -- - — 

Red  #5 - 

Red  #6 - 

"Red  #7,  #9 — 

Red  #8— 

Red  #10,  #11,    #34,  #35 - 

Red  #12,  #13,    #36 

Red  #17,  #18,   #28,  #33,  #37,   #39 

"Red  #19 - —  - 

"Red  #21 - — 

Red  #22 - 

Red  #27 -- 

Red  #30,    #31 - 


253, 

506. 

253, 

506, 

604. 

253, 

506, 

510. 

253, 

288, 

457, 

506, 

510, 

537, 

577, 

605 

253, 

457, 

506, 

510, 

537, 

577, 

605. 

253, 

260, 

506, 

537, 

577, 

605. 

253, 

506. 

506, 

577. 

253, 

457, 

506, 

510, 

577. 

224, 

253. 

506, 

604. 

252, 

253, 

506, 

510. 

457. 

253, 

506. 

252, 

253, 

506. 

160, 

252, 

253, 

401, 

457, 

506, 

510, 

537 

510. 

510, 

605. 

160, 

253, 

401, 

506, 

510, 

537. 

160, 

253, 

510, 

537, 

604. 

160. 

94,  147, 

192, 

492, 

506. 

192. 

147,  192, 

492 

506 

94,  506. 

94. 

94,  147, 

192, 

352, 

506. 

506. 

147,  192, 

492 

506 

94,  147, 

192, 

352, 

492,  506 

147,  192, 

352 

492 

506. 

192. 

94,  192, 

352, 

492, 

506. 

506,  537. 

506. 

192,  492. 

192,  452, 

492 

506 

94,  147, 

192, 

352, 

492,  506 

192. 

506. 

192. 

506. 

192,  506. 

506. 

192. 

506. 

192. 

192,  506. 

192,  502, 

506 

192,  416, 

492 

502 

192,  502. 

506. 

192. 

192,  416. 

192,  506. 

502. 

192,  416, 

502 

192,  502. 

192,  502. 

192,  416, 

502 

506. 

192,  416, 

492 

502 

506. 

192,  416, 

502, 

589 

492,  506, 

589 

416,  502. 

192. 

TABLE  8B. --Syntheti 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 

sanic  chemicals:   Coal-tar  dyes    for  which  United  States  production 
reported,    identified  by  manufacturer ,    /956- -Continued 


87 


Dye 


DYES  GROUPED  BY  COLOUR  INDEX  NUMBER— Continued 

Food,    Drug,     and    Cosmetic    Dyes—Continued 

Drug  and  Cosmetic  Colors — Continued 


Violet  #1 

Yellow  #1,  #10- 

*Yellow  #5 

Yellow  #6 

Yellow  #7 

Yellow  #8 

Yellow  #11 


Drug  and  Cosmetic  Dyes,  External 


Blue  #1 

Green  #1 

Orange  #1,  #3 

Red  #1,  #8,  #10,  #11- 

Red  #13- — 

Violet  #2 

Yellow  #1,  #3 

Yellow  #5 


DYES  GROUPED  BY  PROTOTYPE  NUMBER 


■»Acid  alizarin  flavine  R 

Acid  anthracene  brown  B 

*Acid  anthracene  brown  PG 

»Aoid  chrome  blue  2R 

«Algol  yellow  GC 

«Alizarin  direct  blue  A2G 

Alizarin  direct  blue  AR 

»Alizarin  supra  blue  A 

Alkali  fast  green  ICG 

^Anthracene  chromate  brown  EB- 

»Artificial  silk  black  G 

*Benzo  Bordeaux  6B 

»Benzo  chrome  black  blue  B 

»Benzo  copper  blue  B 

Benzo  dark  brown  ex 

Jf-Benzo  fast  black  L 

*Benzo  fast  blue  4GL 

Benzo  fast  blue  8GL 

Benzo  fast  brown  3GL 

»Benzo  red  12B 

Benzo  rhoduline  red  B 

Benzo  rhoduline  red  3B 

Brilliant  acid  blue  3B 

^Brilliant  benzo  violet  B 

Brilliant  milling  blue  B 

Brilliant  wool  blue  FFB 

♦Brilliant  wool  blue  FFR 

Cellitazol  AZ 

«Celliton  orange  GR 

Chlorantine  fast  blue  2GL 

«Chlorantine  fast  brown  BRL--- 


^Chlorantine  fast  yellow  4GL 

»Chlorantine  fast  yellow  RL 

Chrome  yellow  G 

Clbacete  diazo  black  B 

Cibacete  diazo  black  GN 

Cibacete  diazo  black  J 

»Cibacete  sapphire  blue  G 

Cibacete  scarlet  G 

Cotton  black  X 

Cross  dye  green  B 

♦Diamine  Bordeaux  B 

Diamine  catechine  B 

Diamine  catechine  G 

♦Diamine  catechine  3G 

♦Diamine  fast  blue  FFB 

♦Diamine  fast  orange  EG 

♦Diamine  fast  orange  ER 

♦Diaminogen  blue  N2B 

♦Diazo  Bordeaux  7B 

♦Diazo  brilliant  green  3G 

♦Diazo  brilliant  scarlet  2BL  ex- 

♦Diazo  brilliant  scarlet  ROA 

Diazo  brovm  6G 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


192. 

192, 

506. 

192, 

416, 

502. 

192. 

192, 

416, 

492,    506 

416, 

506. 

506. 

506. 

506. 

192. 

506. 

192, 

506. 

192, 

506. 

192. 

192, 

502. 

253,  288,  401,  506,  510,  537. 

510,  577. 

70,  253,  288,  329,  401,  506,  510,  577,  604. 

506,  510,  577. 

160,  253,  401,  457,  506,  510,  537,  577,  604. 

457,  506,  510,  537,  577. 

506,  510. 

61,  253,  288,  401,  506,  510,  537,  577. 

506,  510. 

253,  288,  329,  506,  510,  537,  577. 

453,  506,  510,  577. 

506,  510,  577,  604. 

253,  265,  506,  510,  577,  604. 

265,  453,  506,  510. 

510. 

253,  265,  506,  510,  577,  604. 

253,  265,  288,  401,  506,  510. 

253,  401. 

506,  510. 

253,  265,  506. 

510,  577. 

265,  506,  510. 

506,  604. 

253,  506,  510,  577,  604. 

253,  506,  510. 

506. 

253,  506,  510. 

510,  604. 

253,  390,  430,  510,  577,  604. 

577. 

191,  253,  329,  401,  447,  453,  506,  510,  577, 

604. 
191,  224,  253,  401,  453,  506,  510,  577. 
265,  447,  577. 
506,  537. 
253,  577. 
577. 
577. 

510,  577,  604. 
430. 

329,  604, 
506,  510,  537. 

253,  265,  329,  506,  510,  604. 
253,  506. 
253,  506,  604. 
253,  506,  510,  604. 

253,  265,  288,  401,  453,  506,  510,  577. 
253,  288,  394,  506,  510,  537,  577. 
253,  288,  394,  510,  537. 
253,  265,  401,  453,  510,  577. 
253,  288,  401,  506,  510,  577,  604. 
253,  401,  506,  510,  577. 
253,  288,  401,  506,  510,  577. 
401,  506,  510,  604. 
506,  510. 


88 


TABLE  SB. -Synthetic 


UNITED  STATES  TARIFF  COMMISSION 

rganic  chemicals:    Coal-tar   dyes    for  which  United  States 
reported ,    identified  by  manufacturer ,    1956- -Continued 


Colour 
Index  or 

proto- 
type No. 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


DTffiS  GROUPED  BY  ffiOTOTYEE  NUMBER— Continued 

Diazo  brown  NR 

Diazo  brovra  3RB 

«Diazo  fast  red  5BL 

«Diazo  fast  red  7BL 

Diazo  indigo  blue  AGL 

Diazo  indigo  blue  ^iRL 

Diazo  rubine  B 

Diazo  sky  blue  B 

Diazo  sky  blue  3GL 

Fast  mordant  blue  B 

Fast  scarlet  2G  base 

*Fast  scarlet  2G  salt 

Sirius  supra  brown  3R 

Sirius  supra  gray  R 

Sirius  supra  orange  5G 

Sirius  supra  yellow  5G 

^Guinea  carmine  B 

«Guinea  fast  red  BL 

Guinea  fast  red  4BL 

Helindon  fast  scarlet  B 

Helindon  fast  scarlet  G 

Helindon  pink  B  ex 

«Helindon  pink  R  ex 

Indanthrene  Irilliant  orange  RK 

»Indanthrene  trown  BR 

»Indanthrene  brown  RRD 

»Indajithrene  khaki  2G 

^Indanthrene  rubine  R 

Indanthrene  yellow  brown  30 

Indo  carbon  CL 

Katigen  chrome  blue  5G 

Metachrome  red  G 

Milling  orange  G 

■"Milling  yellow  H5G 

Milling  yellow  0 

Naphthol  blue  black  S 

Neolan  black  WA - 

»Neolan  blue  GG 

Neolan  Bordeaux  R 

Neolan  orange  R 

Oxydiaminogen  OB 

»Paper  red  A  ex 

Polar  orange  GS 

Polar  orange  R 

Rapidogen  blue  BN 

»Rapidogen  blue  D 

«Rapidogen  Bordeaux  R 

Rapidogen  brown  GN 

*Rapidogen  red  GS 

»Rapidogen  red  ES 

•Rapidogen  scarlet  RS 

•Rapidogen  yellow  G 

*Rosanthrene  fast  Bordeaux  2BL 

•Rosanthrene  orange  R 

Sudan  brown  53 

Sudan  red  BB 

Sulphon  orange  G 

•Sulphon  yellow  R 

Supra  light  rubine  BL 

Suprajnine  black  BR 

Suprainine  blue  R 

Supramine  Bordeaux  B 

Supramine  brown  R 

Supramine  red  3B 

Supramine  red  2G 

Supramine  yellow  R 

•Victoria  fast  violet  2R  ex 

•Victoria  pure  blue  B 

Victoria  violet 

Zambesi  black  D 

Zambesi  black  V 

Acid  anthracene  brown  KE 

•Alizarin  fast  gray  BBLW 

Alizarin  supra  sky  blue  R 

Alphanol  brown  B 

Amido  naphthol  brown  3G 

Anthralan  red  B-CF 

Azosol  fast  orange  G 


510 

253 

288, 

506. 

253 

288, 

401, 

506, 

604. 

510 

510 

401 

510. 

510 

510 

506 

253 

492, 

506, 

510, 

604. 

401 

492, 

604, 

605. 

510 

191 

510. 

510 

506 

510. 

253 

510, 

577. 

253 

288, 

506, 

510, 

577. 

253 

506, 

510. 

604 

253 

604. 

537 

160 

253, 

506, 

510, 

537, 

604. 

253 

288, 

506, 

510, 

515, 

577, 

604. 

160 

253, 

457, 

506, 

510, 

537, 

577,  604,  605 

160 

253, 

401, 

510, 

537, 

577, 

604. 

253 

457, 

506, 

510. 

253 

457, 

506, 

510, 

577, 

605. 

506 

403 

510. 

510 

70, 

440. 

604 

401 

506, 

510, 

577, 

604. 

506 

510. 

506 

506 

510, 

577. 

253 

288, 

401, 

430, 

506, 

510, 

537,  577,  604 

288 

401, 

577. 

253 

506, 

577. 

191 
6 

265, 
V,. 

288, 

329, 

401, 

453, 

506,  510,  577 

253 

506, 

510, 

577. 

577 

506 

510, 

577. 

265 

510. 

253 

265, 

401, 

510. 

265 

401, 

510. 

401 

510. 

160 

253, 

265, 

401, 

430, 

506, 

510,  537. 

160 

253, 

265, 

401, 

430, 

510, 

537. 

160 

253, 

265, 

401, 

430, 

506, 

510,  537. 

160 

265, 

401, 

430, 

510, 

537, 

604. 

253 

288, 

401, 

506, 

510, 

577, 

604. 

253 

401, 

506, 

510, 

577. 

510 

510 

510 

604. 

288 

401, 

510, 

537, 

577, 

604. 

506 

510. 

510 

510 

510 

604 

510 

604. 

510 

401 

510. 

253 

506, 

510, 

537. 

253 

355, 

492, 

510. 

577 

506 

510, 

577. 

253 

453, 

506, 

577. 

401 

510. 

253 

288, 

457, 

506, 

510, 

537, 

577. 

401 

506, 

510. 

510 

510 

510 

510 

SYNTHETIC  ORGANIC  CHEMICALS,  1956 


89 


TABLE  8B. -Synthetic   organic   chemicets:   Coal-tar   dyes    for   which  United  States  production   or   sales   were 
reported,    identified  by  manufacturer ,    J956- -Continued 


Colour 
Index  or 

proto- 
type No. 


Dye 


213 
215 
216 
217 
218 
222 
223 
2ai 
227 
228 
229 
230 
231 
232 
23A 
235 
236 
237 
238 
239 

2<;o 

241 

242 

243 

244 

245 

246 

247 

249 

250 

251 

252 

253 

254 

255 

257 

258 

258 

259 

260 

260 

261 

264 

264 

265 

265 

266 

267 

269 

269 

270 

270 

271 

271 

272 

272 

273 

273 

274 

274 

275 

276 

277 

278 

285 

288 

289 

290 

291 

292 
293 
295 
296 
298 
299 
300 
301 
302 


DXES  GROUPED  BY  PROTOTYPE  NUMBER— Continued 

Azosol  fast  red  3B 

AzoBOl  fast  yellow  CGG 

Azosol  fast  yellow  GR 

Benzo  fast  Bordeaux  6BL 

Benzo  fast  brown  KL 

Brilliant  indocyanine  6B-CF 

^Brilliant  indocyanine  G 

Brilliant  sulpho  flavine  FFA 

Celliton  fast  blue  FR 

•»Celliton  fast  blue  FFR 

Celliton  fast  blue  green  B 

■KCelliton  fast  brown  3R 

Celliton  fast  brown  5R 

Celliton  fast  navy  blue  B 

«Celliton  fast  pink  B 

«Celliton  fast  pink  fT3B 

»Celliton  fast  red  GG 

«Celliton  fast  red  violet  RN 

«Celliton  fast  rubine  B 

•Celliton  fast  rubine  3B 

Celliton  fast  violet  B 

»Celliton  fast  violet  6B 

•Celliton  fast  yellow  G 

Celliton  fast  yellow  RH 

•Celliton  scarlet  B 

•Celliton  yellow  5G 

•Chlorantine  fast  red  5BRL 

Chrome  fast  orange  3RL 

Dianil  yellow  5G 

Diazo  brown  3R 

•Diazo  fast  yellow  2G 

Diazo  fast  yellow  3G 

Erio  chrome  brown  DKL 

Erio  chrome  olive  BL 

Fast  black  B  salt 

Fast  black  LB  base 

•Fast  blue  BB  base 

Fast  blue  BB  salt 

Fast  Bordeaux  BD  salt 

•Fast  Bordeaux  GP  base 

•Fast  Bordeaux  GP  salt 

Fast  corinth  V  salt 

•Fast  orange  GC  base 

•Fast  orange  GC  salt 

Fast  orange  GH  base 

•Fast  orange  GR  salt 

Fast  orange  RD  salt 

•Fast  red  AL  salt 

•Fast  red  3GL  base 

•Fast  red  3GL  salt 

•Fast  red  KB  base 

•Fast  red  KB  salt 

•Fast  red  RC  base 

•Fast  red  HC  salt 

Fast  red  RL  base 

Fast  red  RL  salt 

Fast  red  TR  base 

•Fast  red  TR  salt 

Fast  violet  B  base 

Fast  violet  B  salt 

Fast  yellow  GC  salt 

•Sirius  supra  orange  GG ; 

Sirius  supra  red  violet  RL 

•Sirius  supra  turquoise  blue  GL 

Immedial  new  blue  FBL  ex 

•Indanthrene  brilliant  violet  3B 

•Indanthrene  direct  black  RB 

•Indanthrene  golden  orange  3G 

•Indanthrene  golden  yellow  GK 


•Indanthrene  golden  yellow  RK— 
•Indanthrene  olive  green  B 

Indanthrene  printing  black  BL- 
•Indanthrene  red  FEB 

Metomega  chrome  brown  RLL 

iMonochrome  black  blue  G 

Monochrome  red  FG 

Monochrome  violet  FB 

•Naphthol  AS 


Manufacturers'  Identification  numbers 
(according  to  list  in  table  27) 


510. 

510. 

510. 

510. 

506. 

506,  510. 

506,  510,  577. 

506,  510. 

430,  510,  577,  604. 

390,  430,  440,  443,  506,  510,  577,  604. 

253,  430,  506,  510,  604. 

443,  510,  604. 

510. 

604. 

430,  506,  577,  604. 

253,  430,  510,  604. 

253,  430,  510,  604. 

253,  390,  430,'  506,  510,  577,  604. 

253,  430,  510,  604. 

253,  390,  430,  443,  506,  510,  577,  604. 

510. 

253,  430,  510,  604. 

253,  390,  430,  443,  506,  510,  577,  604. 

510. 

253,  390,  430,  443,  506,  510,  577,  604. 

430,  443,  510,  604. 

191,  253,  265,  288,  401,  453,  506,  510,  604. 

401,  510. 

506,  510. 

510. 

401,  506,  510. 

510. 

506,  510,  577. 

506,  577. 

401,  506. 

510. 

492,  510,  596,  604. 

401,  430,  510,  596. 

510. 

253,  492,  506,  510,  604,  605. 

401,  492,  506,  510,  604,  605. 

510. 

510,  604,  605. 

492,  506,  510,  596,  604,  605. 

510. 

492,  506,  604,  605. 

492,  506,  510,  604. 

401,  492,  506,  510,  596,  604. 

253,  492,  506,  604. 

401,  492,  510,  596,  604,  605. 

253,  265,  492,  506,  510,  537,  596,  604. 

510,  596,  604. 

492,  510,  604,  605. 

510,  604,  605. 

401,  492,  510. 

401,  447,  492,  510. 

605. 

401,  506,  510,  596,  604,  605. 

430,  492,  510,  596. 

401,  492,  510. 

492,  510. 

253,  288,  510. 

253,  510. 

61,  191,  253,  288,  401,  430,  506,  510,  604. 

510. 

253,  510,  577. 

506,  510,  577. 

253,  457,  506,  510,  537,  577,  604,  605. 

160,  253,  288,  401,  457,  506,  510,  537,  577, 

604. 
160,  288,  401,  457,  506,  510. 
253,  457,  506,  510,  537,  577,  604,  605. 
506,  510. 
506,  510,  577. 
577. 

253,  288,  401,  506,  510,  577. 
510. 
510. 

253,  371,  401,  492,  506,  510,  515,  537,  604, 
X. 


90 


TABLE  8B.--Syntheti 


UNITED  STATES  TARIFF  COMMISSION 

^anic  chemicals :   Coat-tar  dyes    for  which  United  States  production 
reported,    identified  hy  manufacturer ,    1956- -Continued 


Manufacturers '   identification  numbers 
(according  to  list  in  table  27) 


DIES  GROUPED  BY  PROTOTYPE  NUMBER— Continued 

»Naphthol  AS-BO 

»Naphthol  AS-BR 

*Naphthol  AS-BS - 

»Naphthol  AS-D 

Naphthol  AS-DB 

Naphthol  AS-E 

»Naphthol  AS-G 

Naphthol  AS-ITH 

»Naphthol  AS-OL 

»Naphthol  AS-RL — - 

»Naphthol  AS-SW 

Naphthol  AS-TR- 

»Neolan  orange  G 

*Neolan  yellow  GR 

Omega  chrome  yellow  ME 

Palatine  fast  blue  BN 

Palatine  fast  blue  RRN 

»Palatine  fast  green  BLN 

*Palatine  fast  marine  blue  REN 

Palatine  fast  orange  RJJ 

»Palatine  fast  pink  BN 

Palatine  fast  red  HH 

Palatine  fast  violet  3RN 

Palatine  fast  violet  5RN 

»Palatine  fast  yellow  ELN 

Pluto   black  G 

Pyrazol  fast  orange  GL 

Rapid  fast  orange  RH 

Rapidogen  black  M3 

Rapidogen  black  brown  IT 

»Rapidogen  blue  N 

Rapidogen  blue  R 

Rapidogen  brown  IB 

*Rapidogen  brown  IFI 

Rapidogen  golden  yellow  R 

Rapidogen  green  B 

Rapidogen  orange  G 

»Rapidogen  orange  R 

Rapidogen  red  violet  RH 

»Rapidogen  violet  B 

Rapidogen  yellow  G 

Rapidogen  yellow  2G 

Variamine  blue  BD  salt 

Variamine  blue  RT  salt 

Acid  chrome  red  B 

Alizarin  rubinol  3G 

Benzochrome  brown  B 

Benzochrome  brown  G 

Benzo  fast  heliotrope  RKL 

Brilliant  benzo  fast  violet  BL 

Brilliant  benzo  green  B 

Celliton  brilliant  yellow  FF 

Celliton  fast  pink  RF 

Chrome  leather  fast  black  S 

«Cotonerol 

Diamond  black  P2B 

Diazo  brilliant  scarlet  5BLN 

Fast  red  ITR  base 

»Fast  red  ITR  salt 

■»Sirius  supra  gray  VGL 

»Indanthrene  orange  4-R 

Janus  black  G 

Naphthol  AS-BG — 

Naphthol  AS-GR -- 

Naphthol  AS-LB 

Naphthol  AS-SG— 

Neolan  pink  B 

Neolan  red  GRE 

Neolan  violet  brown  B 

Oxamine  brilliant  red  B 

Palatine  fast  claret  BN 

Para  brown  V 

Rapidogen  red  ITR 

Rapidogen  scarlet  IL 

Rosanthrene  Bordeaux  R 


371,  510,  596,  tOA. 

492,  506,  510,  604. 

265,  371,  492,  506,  510,  515,  537,  596, 
.,  X. 

253,  265,  371,  401,  492,  506,  510,  515, 
?,  596,  604. 

506,  510. 

371,  492,  506,  510,  537,  604. 

371,  492,  510,  596,  604. 

253,  265,  371,  401,  492,  506,  510,  537, 
i,  604. 

492,  510,  596,  604. 

253,  371,  492,  506,  510,  537,  604. 

371,  506,  510,  604. 

401,  430,  510,  577. 

288,  401,  430,  506,  510,  577. 


506,  510,  577. 
401,  430,  506. 


3,  401,  430,  510,  537,  577. 


537. 

401,  430,  453,  506,  510,  577. 


510. 
510. 
401,  430,  510,  537. 

510. 

401,  510. 
537. 


265,  401,  430,  510. 
265,  401,  510. 


265,  510,  537. 
596. 


510. 

506,  510,  604. 

510. 

510. 

510. 

265,  288,  401,  430,  453,  506,  510,  577, 


401,  506,  510. 

492,  510,  596. 

492,  510,  596. 
506,  510. 

506,  510,  537. 

510,  604. 


492,  510,  604. 

577. 

577. 


510,  577. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


91 


TABLE  8B. -iSynt/ietic  organic  chem 
reported  t 


cats:    Coal-tar   dyes    for    which  United  States  product  ion  or  : 
identified  by  manufacture^- ,    1956 - -Cont inued 


408 
409 
411 
412 
413 
416 
417 
418 
420 
421 
422 
423 
424 
425 
426 
427 
428 
429 
430 
432 

433 

434 

435 

436 

438 

442 

■443 

446 

447 

448 

4^9 

430 

451 

452 

453 

456 

457 

458 

459 

460 

461 

462 

463 

467 

468 

469 

470 

471 

472 

474 

484 

4,85 

487 

488 

489 

490 

491 

492 
493 
494 
495 

498 
498 
499 
501 
501 
503 
505 
506 
507 
508 
509 
511 
513 
514 
515 
516 


Acid  chrome  blue  3G 
Algol  scarlet  B 
Anthracene  navy  blue  BR- 
Azo  rubinol  3GP 
Azosol  fast  blue  HL— 
Benzo  fast  gray  BL- 
Brilliant  congo  blue  BFL 
Brilliant  wool  blue  G 
Celliton  fast  yellow  7G 
Ghlorantine  fast  Bordeaux  2B 
Chlorantine  fast  Bordeaux  BLL 
Ghlorantine  fast  brown  8RLL--- 

Chlorantine  fast  gray  RLN 

Ghlorantine  fast  green  BLL 

Chlorantine  fast  orange  T4RLL' 
Chlorantine  fast  orange  T5RLL 

«Chlorantine  fast  red  6BLL 

«Chlorantine  Cast  violet  5BL-- 

Chlorantine  fast  violet  RLL-- 

«Chlorazol  blue  5GKS 


Derma  brown  G 

Derma  brown  R 

Diazanll  orange  RR 

Diazo  brilliant  blue  2BL 

Diazo  fast  Bordeaux  FBL 

Fast  scarlet  TR  base 

«Sirius  light  blue  FBGL 

Indanthrene  orange  F3R 

Indanthrene  red  brown  R 

Indanthrene  red  brown  5RF 

Indanthrene  scarlet  R 

Indanthrene  yellow  FFRK 

Indanthrene  yellow  GF 

Indanthrene  yellow  3R 

Kiton  fast  red  4BLN 

Metomega  chrome  brown  3GL 

Metomega  chrome  orange  ML 

Metomega  chrome  red  GM 

Monochrome  olive  FBBL 

Naphthol  AS-LC 

Naphthochrome  violet  R 

Neolan  blue  2R 

Neolan  orange  GRE 

Rapldogen  golden  yellow  IFG 

Rapidogen  red  IGG 

Rapidogen  yellow  14G 

Diphenyl  fast  blue  green  BL 

Sudan  red  GG 

Sudan  yellow  GRN 

Supramine  yellow  3GL 

Chromoxane  "brilliant  violet  SB- 
Alizarin  light  blue  4GL 

Azosol  fast  black  M 

Azosol  fast  red  BE 

Brilliant  indo  blue  5GL 

Chloramine  fast  orange  2RN 

•Chlorantine  fast  violet  2RL 


Cloth  fast  yellow  5G 

Diazo  brilliant  scarlet  BA— 
Diazo   brilliant  scarlet  ROL- 

Dlazo  fast  yellow  3GLL 

Fast  blue  RR  base 

Fast  blue  RR  salt 

Fast  oorinth  LB  salt 

»Fast  red  PDC  base 

»Fast  red  PDC  salt 

•Indanthrene  red  violet  RRN-- 

•Naphthol  AS-LG— 

Naphthol  AS-LT 

Neolan  Bordeaux  BE 

Neolan  Bordeaux  RM 

Neolan  red  BRE 

Rapidogen  corinth  IB 

Xylene  fast  orange  PO 

Acid  alizarin  black  RGW 

Acid  leather  brown  EGB 

Alizarin  saphirol  WSA 


510. 

510. 

510. 

577. 

510. 

506. 

506,    510. 

506. 

510. 

191,    506. 

191,    506. 

253,    506. 

506. 

253,    506,    510,    577. 

506,    577. 

506. 

253,    288,  401,   453,    506,    510,    577,   604. 

253,    506,    577. 

506. 

191,    253,    265,   401,   447,   453,   506,    510,   537, 

577,    604. 
577. 
577. 

253,    510. 
506,    510. 
510. 
510. 

191,    265,   390,   401,   453,    506,    510,    537,    577. 
506. 
604. 

253,    506,    510. 
506,    510. 
506. 
506. 
253. 

401,  577. 
577. 

506,    577. 
577. 
510. 

371,  510. 
506,  510. 
506,  577. 
577. 

265,  510. 
265. 

265,  510. 
506,  577. 
510. 

506,  510. 
506,  510. 
510. 

253,  506,  577. 
510. 
510. 
510. 
577. 
191,    224,    253,    265,    288,   401,   447,   453,    506, 

510,  577. 
506,  577. 
253. 
510. 
577. 
510. 
510. 

492,    510. 

492,    510,    596,   604. 
401,   492,    510,    596,    604. 
160,    253,    506,    510. 
160,    510,    596,    604. 
510. 
577. 
577. 
577. 
510. 
506. 
577. 
510. 
253,    510. 


92  UNITED  STATES  TARIFF  COMMISSION 

TABLE  8B. --Synthetic  organic   chemicals:    Coal-tar  dyes    for   which  United  States  production 
reported,    identified  by  manufacturer ,    19 J6- -Continued 


Manufacturers'  Identification  numbers 
(according  to  list  in  table  27) 


DYES  GROUPED  BY  PROTOTYPE  NUMBER— Continued 

Azosol  fast  yellow  R 

Buffalo  black  3G 

Calcofast  spirit  orange  RN 

Calcofast  wool  orange  RN 

Caledon  dark  blue  G 

«Cellitazol  AZN 

Chloramine  copper  blue  3G 

Chloramine  copper  blue  AG 

Chlorantine  fast  yellow  2GLL 

^Chrome  fast  green  G 

Diaminogen  blue  NA 

Diazo  fast  green  GF 

Diazo  fast  violet  BL 

Dipyrazo  scarlet  RP 

»Dlrect  chlnoline 

Durazol  fast  blue  3HS 

Durazol  fast  orange  R 

^Eastman  fast  yellow  GLF 

Eastone  blue  BGF - 

Erie  fast  rubine  B 

Fast  brown  salt  VA 

Fluorol  5G 

Guinea  brown  RD 

Innnedial  black  brown  A 

»Indanthrene  olive  T 

Interchem  acetate  orange  AR 

Leather  brown  5RTX 

Ltixol  brilliant  green  BL 

Luxol  fast  blue  MBS 

Naphthol  AS-L3G - 

»Napbthol  AS-MX. - 

»Naphthol  AS-PH - - 

Naphthol  AS-RC - - 

Neolan  dark  green  B 

Neolan  navy  blue  RLG 

Neutral  brown  RX 

Permanent  red  2B,  sodium  salt 

»Pontamine  black  AWG 

Pontamine  diazo  brown  R 

Pontamine  diazo  orange 

Pontamine  diazo  orange  3G 

»Pontamine  navy  blue  DB 

Rapidogen  black  3G 

Rapidogen  blue  PEN 

Sirius  supra  brown  5G 

Sirius  supra  brown  3RL 

Sirius  supra  orange  RRL 

Sirius  supra  scarlet  GG 

«Solantine  orange  AG 

Supranol  brown  3GL 

Variamine  blue  FG  salt 

»Sirius  supra  yellow  R  ex 

Acid  anthracene  brown  TBL 

Bixamine  fast  blue  AGLL 

Calcogene  direct  blue  GNCF 

Capracyl  orange  R 

Capracyl  red  B 

Capracyl  violet  R 

Carbanthrene  gray  GFL 

Chlorantine  fast  blue  3GLL 

Coprantine  black  brown  S 

Erio  fast  orange  F 

Flavine  AG 

Vat  yellow  PGA 

Metomega  chrome  cyanlne  BLL 

Naphthol  AS-KB- - • 

Neolan  brown  R 

Nyafonn  blue  2B 

Polar  red  brown  V 

Rapidogen  black  IT 

Sirius  light  violet  BL 

Sudan  black  BT 

Superlitefast  blue  GL 

»Superlitefast  blue  8GLN 

*Superlitefast  blue  RL 

Viscolan  black  B 

Indanthrene  black  brown  VA 


537. 
510,  537. 


506. 

443,  506,  510,  577,  604. 


253,  506,  577. 
506. 
510. 
506. 
506. 
510,  537. 


443,  506,  604. 
506. 


260,  288,  457,  506,  510,  537,  577,  60;, 

390,  430. 
510. 
510. 
506. 

265,  371,  510,  596,  604. 

253,  265,  371,  492,  510,  596,  604. 

510. 


506,  577. 

506,  604. 
401,  510. 
288,  506,  577. 

329,  453,  537,  577. 

265,  510. 

510. 


401,  453,  506,  537,  577. 
510. 


224,  253,  265,  288,  401,  430,  453,  506, 
),  577. 


605. 

492,  510,  604. 

453,  506. 

510. 


453,  506. 
537,  577. 
265,  430,  AAV,   453,  506,  510,  537. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


93 


TABLE  8B. --Syntheti 


organic  chemicals:   Coat'tai 
reported,   identified  by 


dyes   for  which  United  States  product  ion   or  sales  were 
manufacturer ,   1956- -Continued 


Manufacturers '  Identification  numbers 
(according  to  list  in  table  27) 


DYES  GROUPED  BY  PROTOTYPE  NUMBEH--Continued 


Interohem  acetate  yellow  GSF- 

Fast  bro\m  3RLL 

Fast  orange  LLLWF 

Fast  yellow  EFC 


UNGROUPED  DYES 

•Acetate  rayon  dyes:'"' 

•Black,  B,  EC,  3G,  GGN,  GS,  GY,  JRW,  LNB,  MPB, 

NC,  PL,  RB,  SS.^ 
•Blue  AB-7,  A8-i5,  B,  2B,  BG,  OR,  FSI,  G,  2G, 
GBN,  GFD,  3G-GFD,  5G-GFD,  GLF,  GLT,  GP,  GR, 
GSF,  GSFR,  GSS,  LWGF,  MJ,  NBN,  NBNJ,  NSP, 
2R,  AR,   RB,  RBN,  3RL,  SS,  WNBN.^ 

Brown  #8,  JG,  R 

Gray  NBN 

Khaki  ODA 

•Navy  blue  BP,  BR,  EC,  LB,  MG,  NVY,  R,  RG* 

Orange  FSI,  GI£,  GR,  GRN,  I,  R,  2R,  3R' 

Pink  3B-GLF- 

•Red  VI-X,  B,  2B,  3B,  2B-GLF,  ABLL,   C.  FSI,  G, 
GLF,  GSF,  NB,  N-GLF,  R,  RP,  Y,  YP/ 

•Scarlet  III,  B,  FS,  GSF'' 

Violet  303,  7BC,  BGF,  BN,  DAC,  2R,  3R-GLF, 
5RLF.^ 
•Yellow  DC,  XI,  #91,  CW,  FSI,  3G,  5G,  8-GLF, 

gr,  m,  n,  r,  5r,  r-gfd,  2r-glf,  a«l,  4rla, 
-;rlf,  rn,  w-glf,  yl.' 

Acid  alizarin  Bordeaux  BLT 

Acid  alizarin  brcuvn  RLL 

•Acid  black  AR,   4B,   GRF,    N,    NRB,   RB 

•Acid  blue,    B,    BRL,   G,   L,    NB,   R 

Acid  Bordeaux  GRL 

Acid  brilliant  green 

Acid  brilliant  pink  3B 

Acid  brilliant  yellow  3GL 

•Acid  brown  BL,  CRTA,  ITGA,  M-130,  NY,  PCMA,  RD, 
2RL. 

Acid  citron 

Acid  dark  brown  B 

Acid  fast  black  RWL 

Acid  fast  blue  5RNA 

Acid  fast  Bordeaux  2BWL 

Acid  fast  brilliant  crimson  RB 

Acid  fast  brown  CGS 

Acid  fast  green  2GWL 

Acid  fast  light  yellow  #25806 

Acid  fast  navy  BWL 

Acid  fast  orange  GLW,  LW 

Acid  fast  red  5BWL,  G 

Acid  fast  scarlet  GWL 

Acid  gray  BL,  G 

Acid  green  B 

Acid  leather  brown 

Acid  milling  orange  AR 

Acid  milling  scarlet  3G 

Acid  na'/y  blue 

•Acid  orange  R,  2R,  RL 

Acid  red  B,  2B,  3B,  G,  GB,  RB,  3RB 

Acid  rose  G 

Acid  ruby  PL 

Acid  sapphire  G 

Acid  scarlet  G,  GN 

Acid  supranyl  black  GRN 

Acid  supranyl  blue  AGN 

Acid  supranyl  gray  2BN 

Acid  supranyl  green  SGN 

Acid  supranyl  orange  RN 

Acid  supranyl  red  SPN 

Acid  supranyl  yellow  2GN 

•Acid  violet  BD,  R,  2R,  3RL,  RNL 

Acid  yellow  FGL,  3G,  6G,  GL,  GW,  NR,  NW,  3RD— 

Alizarin  blue  GS 

Alizarin  brilliant  blue  R 

Alizarin  levelling  blue  2R 

Alizarin  sapphire  UM 

Alizarin  violet  NRR 

Alphazurine  B 

Anthracene  chrome  brown  RL 


430. 
447. 
447. 
447. 


253,  329,  430,  443,  577,  604. 
253,  430,  443,  506,  510,  604. 


430,  443,  604. 

604. 

443. 

253,  430,  443,  604. 

253,  329,  443,  506,  604; 

443. 

253,  329,  430,  443,  506,  577,  604. 


253,  329,  430,  604. 
253,  430,  443,  510. 


191,  253,  430,  4^3,  510,  604. 


510. 

510. 

253,  506,  604. 

253,  401,  510,  577,  604. 

577. 

510. 

253. 

577. 

253,  510,  577. 

401. 

253. 

191. 

510. 

191. 

506. 

253. 

191. 

401. 

191. 

191,  604. 

191. 

191. 

506,  510,  577. 

253. 

537. 

537. 

604. 

537. 

253, 

253, 

401. 

253. 

447. 

401. 

191. 

191. 

191. 

191. 

191. 

191. 

191. 

70, 

253, 

506. 

604. 

604. 

506. 

506. 

506. 

440. 


401,  577. 
401,  506. 


253,  329,  4^0,  506. 
401,  510,  577. 


See  footnotes  at  end  of  table. 


94 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  6B. --Synthetic   organic   chemicals:   Coal-tar  dyes   for   which  United  States  producti 
reported,    identified  by  manufacturer ,    1956 --Continued 


Manufacturers '  Identification  numbers 
(according  to  list  in  table  27) 


UNGROUPED  DYES— Continued 

Anthraqulnone  blue  EGA,  3G,  2GA,  RA 

Anthraquinone  brilliant  violet  3R 

Anthraquinone  milling  blue  BL 

Anthraquinone  vat  black  2G,  J,  R 

Anthraquinone  Vat  black  brown  VA 

Anthraquinone  vat  blue  BCL 

Anthraquinone  vat  blue  green  3B,  Y 

Anthraquinone  vat  brilliant  red  B 

Anthraquinone  vat  brilliant  yellow  3G,  AG,   5G- 

Anthraquinone  vat  brown  BN,  NR,  VR 

Anthraquinone  vat  copper  brown 

Anthraquinone  vat  direct  black  3G,  3GA 

Anthraquinone  vat  fast  yellow 

Anthraquinone  vat  gray  2G,  GNF,  N,  R 

Anthraquinone  vat  navy  blue  VH 

Anthraquinone  vat  olive  G,  2GL 

Anthraquinone  vat  printing  black  GR,  PG,  R 

Anthraquinone  vat  red  TO,   RL,  RRB 

Anthraquinone  vat  red  brown  N,  RB 

Anthraquinone  vat  scarlet  2G,  3GA,  GL 

Anthraquinone  vat  supra  black  AP 

Anthraquinone  vat  supra  dark  brown  BVA,  FCA--' 

Anthraquinone  vat  supra  gray  BR 

Anthraquinone  vat  yellow  GL,  5GLL,  LN,  PQ 

Anthraquinone  violet  A 

Aviation  blue — — 

Azo  cereeine  B 

Azo  eosine  2B 

Azo  fast  yellow  5GN 

Azo  oil  black  B 

»Azoic  dyes  and  their  components:^" 
Dyes,  rapidogen: 

Black  A,  2B,  BF,  EM,  FOR,  I,  J,  JN,  MR 

Blue  B,  2B,  GFC,  2GL ■ 

Bordeaux  AF,  MR 

Brilliant  red 

Brown  BR,  D,  HDG,  I,  IPR,  PC,  PKB,  Y,  YF- 

Dark  brown  AR 

Golden  yellow  MRS 

Gray  R 

Navy  blue  FKR,  GA 

Orange  FFR,  MG 

Red  AS,   B,  2B,  3B,  FB,  FFBB,  GFC,  GNBB, 
GNNHD,  KB,  KBS,  LBB,  RC,  RNHD,  S. 

Scarlet  2G,  RR,  SFC,  SNNHD 

Violet  BN • 

Yellow  AGL,  GFA,  GGN,  GR,  RNA 

Components : 

Fast  color  bases: 

Garnet  GBCP 

Red  FB 

Stabilized  blue,  red,  scarlet,  violet — 
Fast  color  salts: 

Black  GO,  RBN 

Garnet  GBC 

Fur  dyes: 

Fur  #2,  B,  BCA,  NZA,  NZF 

FuBion 

Naphthols : 

Naphthol  AS-BB - — 

Naphthol  AS-BC— • 

Naphthol  AS-BN - 

Naphthol  AS-EL - • 

Naphthol  AS-KB - 

Naphthol  AS-UG 

Naphthol  AS-P • 

Naphthol  AS-PN ■ 

Naphthol  AS-RL-P • 

Naphthol  AS-RR 

Naphthol  AS-ST- - - 

Naphthol  AS-SW-P 

Azosol  brilliant  blue  B 

Azosol  fast  brilliant  red  BN 

Azosol  fast  yellow  GT 

Basic  blue  B,  2G,  5G 

Basic  blue  black  BA 

Basic  brilliant  red  B,   3B,   <VG 

Basic  green  B 

Basic  orange  G,  L 


253. 
253. 
253. 

506,  537. 

288,  510. 

510. 

253,  510. 

253. 

253,  510. 

253,  506. 

537. 

253,  506,  510. 

537. 

253,  510,  537. 

253. 

253,  506. 

506,  604. 

253. 

253. 

253,  510. 

604. 

604. 

604. 

253,  537,  604. 

253. 

537. 

537. 

253. 

510. 

506. 


265,  401,  510,  596. 
401,  492. 
265,  401. 


253, 

224, 

253, 

401. 

265,  401,  510. 

253. 

253. 

401. 

510. 

253,  510. 

253,  265,  401,  430,  4-92,  510,  537. 

401,  492. 

510. 

253,  401,  510. 


596. 
191. 
596. 

401. 
596. 


265,  510. 

265. 

510. 

492. 

160,  371,  492,  510,  596. 

604. 

492. 

537. 

492. 

510. 

510. 

492. 

510. 

510. 

510. 

253. 

510. 

253. 

253. 

253. 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 

TABLE  8B. --.Synthetic  organic  chemicals:     Coal-tar  dyes   for  which  United  States  producti 
reported,    identified  by  manufacturer,    1956--Continued 


95 


Dye 


UNGROUPED  DrES--Continued 


Manufacturers '   identification  numbers 
(according  to  list  in  table  27) 


Basic  phosphine  2GR 

Basic  pink  3G 

Basic  red  GL,   L 

Basic  yellow  5GF,   L,   R,   3RL 

Benzo  fast  copper  yellow  2GL 

Blancophor  AW 

Blue  8GLN,   LBLL,    LF,   UGLL 

Brilliant  blue  B 

Brilliant  cyanine  green  5G 

Brilliant  oil  blue  BAA 

Canary  lake  yellow  PL 

Carbanthrene  gray  BFN 

Celliton  yellow  6D 

Chlorantine  fast  green  5GLL 

Chromate  brown  R,   RL 

Chrome  black  3G 

Chrome  brown  B 

Chrome  cyanine  BLL 

Chrome  flavine  GA 

Chrome  garnet  GRW 

Chrome  gray  BL 

Chrome  green  B,  BL 

Chrome  orange  LC,  3R 

Chrome  soga  yellow  A 

«Chrc(me  yellow  2GN,  GRR,  SW 

Cloth  red  Y - 

Developed  orange  DD,  WD 

Developed  scarlet  GFW 

Developer  assistant  RPN 

Diazo  brilliant  scarlet  GGA 

Diazo  brown  R 

Diazo  fast  orange  GL 

Diazo  orange  LGA 

Diazophen  red  BTB 

Diazophen  yellow  BTP 

Diazo  scarlet  RP 

»Direct  black  CW,  5G,  3GR,  HH,  NV,  20B,  RCW, 
SBJ. 
Direct  blue  BFL,  12BLL,  16BLL,  DB,  G,  8GLN, 
8GUF,  NR,  2R,  2RCF,  3RCF,  RDW,  RG,  2RLCF, 
RLU,  2RW,  SFBL,  3ST,  VRS. 

Direct  blue  green  CW 

Direct  Bordeaux  KLFR 

Direct  brilliant  brown  S 

Direct  brilliant  rayon  blue  J 

Direct  brilliant  scarlet  GLR 

Direct  brilliant  violet  4B,  R— — 

»Direct  brown  #230,  BY,  CH,  DB,  DW,  FF,  GB, 
3GS,  KRS,  R,  RB,  4RL,  RRF,  RRK,  RY. 

Direct  cardinal  WF 

Direct  oatechlne  2BAC 

Direct  developed  garnet  RD 

Direct  diazo  blue  3G,  6G,  5GL 

Direct  diazo  green  BL,  aGL 

Direct  diazo  orange  G,  GR,  N,  WD 

Direct  diazo  scarlet  R,  RN 

Direct  diazo  violet  BL,  RR 

Direct  diazo  yellow  2GL 

Direct  fast  black  #667,  CAN,  LSE 

•Direct  fast  blue  BFL,  BLL,  BRN,  CEL,  8G,  4GLR, 
LBFU,  LBGL,  LBL,  LBR,  L5GA,  L5R,  JE.,  NPC,  RL, 
3RL,  UGLL. 

Direct  fast  blue  green  BLUC 

Direct  fast  brilliant  blue  LWN 

•Direct  fast  brown  BCL,  CS,  LBT,  LLC,  R,  -iR,  RL, 

2RL,  4RL,  RLL,  SKRL,  3YL. 
•Direct  fast  gray  #3^4749,  BL,  GL,  2GL,  3GL, 
LBUL,  LGL,  LWBG. 

Direct  fast  green  2B 

Direct  fast  navy  BG,  LW2B,  RL 

•Direct  fast  orange  2GL,  L8GL,  LWF,  3LWF,  MAR,  R 

Direct  fast  red  8BNL,  RLF,  RLL,  WL 

Direct  fast  rubine  LBL,  WL 

Direct  fast  scarlet  5BS 

Direct  fast  violet  CR,  LBD,  R 

•Direct  fast  yellow  EFC,  5G,  AGLP,  LLR,  L-2RX- 

Dlrect  garnet  RB 

Direct  gray  CRLL,  2GFL,  GL,  3LUF,  LVl,  UFLL 

•Direct  green  FFW,  5GSC,  Y 


-iOl. 

510. 

253. 

253,  510. 

510. 

510. 

-153. 

253. 

457. 

506. 

506. 

506. 

510. 

577. 

288,  440. 

506. 

506. 

577. 

510. 

70. 

440. 

70,  506. 

506,  537. 

510. 

70,  253,  506. 

577. 

506. 

506. 

510. 

510. 

577. 

577. 

510. 

537. 

537. 

577. 

191,  329,  447,  577. 

401,  430,  447,  506,  537. 


506. 

447. 

506. 

447. 

191. 

537, 

604. 

191, 

401, 

447, 

506, 

537,    604 

447. 

506. 

604. 

253. 

253. 

253. 

253. 

253. 

253. 

191. 

191, 

253, 

265, 

288, 

510. 

191. 

191. 

191, 

253, 

506, 

577, 

604. 

191, 

253, 

288, 

506, 

510. 

265. 

191, 

265. 

191, 

253, 

506, 

510, 

577. 

191, 

253, 

329. 

191, 

329. 

401. 

191, 

506. 

191, 

253, 

401, 

506, 

577. 

506. 

401, 

447, 

537. 

253, 

447, 

537. 

96 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  8B.- -Synthetic   organic  chemicals:   Coal-tar  dyes   for   which  United  States  produ 
reported,    identifiedbymanafacturer,    7956- -Continued 


UNGROUPED  DYES--Continued 

Direct  indigo  blue 

Direct  Jet  black 

Direct  lumisol  blue  GIS,   RL 

Direct  lumisol  gray  G 

Direct  lumisol  red  3BIW 

Direct  lumisol  rublne  WLKS 

Direct  lumisol  violet  ARL 

Direct  maroon  LFVS 

Direct  navy  BR,  CW,  LN 

Direct  olive  green  BLN 

Direct  orange  #25206,  BD,  BRS,  DB,  60,  GFL, 
GRN,  LR,  RNC,  RT,  RXA,  UF2G. 

Direct  red  9B,  8BLN,  3BW,  G,  Z 

Direct  royal  blue  L,  S 

Direct  rabine  B,  BE,  G,  S,  WLKS 

Direct  silk  blue  NR 

Direct  supra  blue  FBLL,  7GL,  GLF 

Direct  supra  rubine  BBL 

Direct  turquoise  B,  8GL 

Direct  violet  B,  0,  R,  2R,  RC 

♦Direct  white,  B,  4B,  CN,  DPS,  DS-86,  GG,  GO, 
HS-76,  K,  LD,  MR,  M2H,  PAB,  2R,  RN,  RW,  RWS, 
SB,  SO,  WAIE,  WCN. 

Direct  wine  WF 

Direct  yellow  DW,  ELF,  G,  GR,  S,  S5GP— 

Discharge  yellow  DLW 

Euohrysine  3GA,  3RXA 

Fast  acid  orange  RW 

Fast  black  G 

Fast  Bordeaux  BN,  RB 

Fast  brown  FN,  MF 

Fast  crimson  R 

Fast  olive  brown  G 

Fast  orange  TF 

Fast  red  KL  salt 

Fast  spirit  black  RB — 

Fast  spirit  brown  GN 

Fast  spirit  yellow  G 

Fast  yellow  G,  2G,  N - 

Fluorescent  green  HW 

Fluorescent  yellow  HEB 

Fluorol  VGA,  OB,  OBR - - 

Formaldehyde  blue  2B 

Formaldehyde  red  B 

Formalide  deep  blue  R 

Gasoline  yellow 

Genacron  violet 

Gray  LVLL,  LVLN,  LUFL 

Hectograph  white  A 

Indian  brown  3G 

Ink  blue  PP - 

Luxols 

Methyl  orange 

Milling  orange  RN 

Milling  yellow  GN— - - 

Neolan  pink  G 

Neutral  brown  R 

Neutral  dark  brown  H 

Neutral  silk  brown  RG 

Neutral  sUk  yellow  CGA - 

Nydye  black  J,  JM - 

Nydye  blue  GB 

Nydye  brown  2RH 

Nydye  navy  blue  M 

Nydye  orange  2R 

Nydye  red  3B 

Nydye  scarlet  G 

Nydye  violet  BX 

Nydye  yellow  S 

Nylanthrene  blue  3BLF 

Nylanthrene  navy  LFWG 

Nylanthrene  orange  LRWF 

Nylanthrene  red  2RWF 

Nylanthrene  rublne  5BLF 

Nylanthrene  scarlet  'ILFW 

Nylanthrene  yellow  FLW 

»Oil  blue  A,  AP,  NE 

Oil  brown  M,  Y - 

Oil  color  correctors 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


bOA. 
Wl. 
■ill. 
577. 
577. 
577. 
577. 
447. 
447. 
401. 
253,  401,  447. 

191,  401,  447. 

447. 

447,  604. 

510. 

604. 

604. 

447. 

401,  447,  506,  510. 

253,  401,  492,  510,  520,  537,  577,  608. 


447. 

401,  447,  506. 

447. 

510. 

577. 

537. 

537. 

537. 

506. 

537. 

537. 

401. 

537. 

537. 

537. 

288,  537. 

44. 

537. 

510. 

577. 

577. 

329. 

537. 

510. 

453. 

253. 

510. 

506. 

253. 

253. 

253. 

253,  506. 

577. 

506. 

329. 

447. 

288. 

447. 

447. 

447. 

447. 

447. 

447. 

447. 

447. 

447. 

447. 

447. 

447. 

447. 

447. 

447. 

447. 

253,  537,  604. 

429,  506. 

370. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 

TABLE  Sn.- -Synthetic   organic   chemicals:    Coal-tar   dyes    for   which  United  States   product i 
reported,    identified  by  manufacturer ,    1956- -Continued 


97 


Colour 
Index  or 

proto- 
type No. 


Dye 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


UNGHOUPED  DYES— Continued 

Oil  fast  blue  R- 

Oil  orange  MT 

Oil  pink  B 

Oil  red,  ED,  EGN,  N-1700,  0,  OB,  RO- 

Oil  yellow  HW 

Orange  GLFC,  2GLL 

Oxydiamlnogen  BBA 

Pan  yellow 

Plastic  red  LB 

Pluto  orange  GRA 

Red  brown  RRF 

Resin  brilliant  red  R 

Resin  brown  Z 

Resin  dark  red  Z 

Rhodamine  B  stearate 

Rotalins 

Rubine  BLN 

Soluble  vat  red  H 

Spirit-soluble  black 

Spirit-soluble  blue  6G,  RDA 

Spirit-soluble  brown  2RS 

Spirit-soluble  fast  black 

Spirit-soluble  fast  blue  B 

Spirit-soluble  fast  green  B 

Spirit-soluble  fast  red  M,   X 

Spirit-soluble  fast  yellow  30 

Spirit-soluble  green 

Spirit-soluble  orange  M,   RS 

Spirit-soluble  pink  MBS 

Spirit-soluble  red  MS 

Spirit-soluble  red  brown  NR 

Spirit-soluble  scarlet  MC 

Spirit-soluble  violet  MR 

Spirit-soluble  yellow  GR,  VCS 

Stilbene  yellow  8G 

Sudan  corinth  3B 

Sudan  dark  brown  EG 

Sudan  yellow  GRA 

Sulfur  fast  brown  CLHR 

Supemylite  brown  2R 

Supemylite  maroon  LFS 

Supernylite  scarlet  B 

Supemylite  yellow  G 

Synlan  black  J 

Toluylene  fast  brown  3GA 

Vat  black 

Vat  brown 

Vat  maroon  3N 

Vat  printing  black  R 

Woodstain  black  N 

Wool  blue  CGG 

Yellow  mR,  MFA-3,  RLFC 

All  other 


604. 

370,  429,  537. 

506. 

429,  506,  537,  604. 

537. 

453. 

510. 

510. 

604. 

510. 

577. 

506. 

506. 

506. 

537. 

253. 

453. 

510. 

506. 

440,  506. 

506. 

506. 

506. 

506. 

506. 

506. 

440,  506. 

506. 

506. 

506. 

506. 

506. 

506. 

506. 

537. 

510. 

510. 

510. 

506. 

447. 

447. 

447. 

447. 

577. 

510. 

252. 

403. 

510. 

401. 

253. 

506. 

453,  510,  577. 

253,  370,  401. 


Excludes  acetate  rayon  dyes  that  appear  under  "Dyes  grouped  by  prototype  number. " 
^  Includes  developed  black,  diazo  black,  and  printing  black. 
•'  Includes  brilliant  blue,  fast  blue,  and  violet  blue. 

Includes  direct  navy  blue. 
'  Includes  golden  orange,  light  orange,  and  monocel  orange. 
*  Includes  rubine,  monocel  rubine,  and  polyester  red. 
'  Includes  monocel  scarlet. 

Includes  fast  red  violet. 
'  Includes  fast  yellow,  golden  yellow,  and  printing  yellow. 
^°  Excludes  azoic  dyes  and  their  components  that  appear  under  "Dyes  grouped  by  Colour  Index 
number"  and  "Dyes  grouped  by  prototype  number. " 


98 


UNITED  STATES  TARIFF  COMMISSION 


Toners  and  Lakes 


TABLE  15B. --Synthefi 


organic    chemicals:    Toners  and  liJtes    for  which  United  State 
reported,    identi  fied  by  manufacturer,    1956 


prodiiction  or  saies    vere 


[Toners  and  lakes  for  which  separate  statistics  are  given  in  table  ISA  are  marked  below  with  an  asterisk 
(»);  those  not  so  marked  do  not  appear  in  table  ISA  because  the  reported  data  are  accepted  in  confidence 
and  may  not  be  published.  Manufacturers'  Identification  numbers  shown  below  are  taken  from  table  27.  An 
X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number  with  the 
designated  product] 


Product 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


TONERS  OR  FULL-STRENGTH  COLORS 


•Black  toners: 
Aniline  black- 

PMA  black 

PTA  black 

*Blue  toners: 


»Alkali  blue,  C.I.  70-; 

Dlanlsldine  blue  (Naphthol  AS  (Pr.  302)  and 

dlanisidine) . 
Dlanlsldine  blue  (Naphthol  AS-D  (Pr.  306)  and 

dlanisidine). 
Dlanlsldine  blue  (Naphthol  AS-OL  (Pr.  311)  and 
dlanlsldine). 

Indanthrene  blue  GCD  (C.I.  1113) 

Peacock  blue  GG,  PTA 

Peacock  blue  R  (C.I.  664),  PMA 

Peacock  blue  R  (C.I.  664),  PTA 

•Phthalocyanlne  blue  B  (alpha  modification), 
Pr.  481. 
Phthalooyanine  blue  BO  (Green  shade)  (beta  modi- 
fication). 
Pigment  blue  WNL- 


502. 

210, 

433, 

491. 

433, 

491. 

104, 

485, 

537, 

589 

X. 

492. 

253, 

515. 

I 


•Setoglaucine  (Peacock  blue  G)  (Rhodullne  blue  6G) 
(C.I.  658),  PMA. 

•Setoglaucine  (Peacock  blue  G)  (Rhodullne  blue  6G) 
(C.I.  658),  PTA. 

•Victoria  blue  B  (C.I.  729),  PMA 

•Victoria  blue  B  (C.I.  729),  PTA 

Victoria  blue  B  (C.I.  729),  fugitive 

(Victoria  blue  BGO  (Pr.  198),  PMA 

Victoria  blue  R  (C.I.  728),  PMA 

•Victoria  pure  blue  B  (Pr.  198),  PMA 

•Victoria  pure  blue  B  (Pr.  198),  PTA 


•Brown  toners: 

Bismarck  brown,  PMA 

Bismarck  brown,  PTA 

Copper  brown — 

Gun  metal  brown-— ___— — 

Para  brown — — — 

•Green  toners : 

Benzidine  yellow  and  phthalocyanlne  blue,  Pr. 
481. 

•Brilliant  green  (C.I.  662),  PMA 

Brilliant  green  (C.I.  662),  PTA 

Brilliant  green  (C.I.  662)  and  malachite  green 

(C.I.  657),  PMA. 
Brilliant  green  (C.I.  662),  malachite  green  (C.I. 

657),  and  thloflavine  (C.I.  815),  PMA. 
Brilliant  green  (C.I.  662),  malachite  green  (C.I. 
657),  and  thloflavine  (C.I.  815),  PTA. 
•Brilliant  green  (C.I.  662)  and  thloflavine  (C.I. 

815),  PMA. 
•Brilliant  green  (C.I.  662)  and  thloflavine  (C.I. 
815),  PTA. 

Malachite  green  (C.I.  657),  PMA 

•Malachite  green  (C.I.  657),  PTA 


Peacock  blue  GG  and  thiofl'avlne  (C.I.  815),  PMA- 

Permanent  green  BH ~ — - — 

•Phthalocyanlne  green,  Pr.  483 

•Pigment  green  B,  Pr.  149 

•Maroon  toners: 

Anthranilio/BON  maroon ■  - — -- — 

B.O.N,  lake  red  C  amine- 


•B.O.N,  maroon  (Lithol  maroon)  (Tobias  acid  and 
bon) . 
Hello  Bordeaux  (C.I.  84) 

Hello  fast  rubine  4BL 

Indanthrene  maroons- 

Llthol  red  3G,  manganese  toner- 


253. 
531. 
I  491. 
384,  462,  491. 
61,  74,  104,  160,  253,  416,  485,  502,  506,  510,  515, 

531,  537,  557,  X. 
83,  253,  416,  515,  537. 

510. 

7,  384,  433,  A87,   491,  492,  531. 

7,  192,  210,  384,  415,  433,  462,  487,  491,  492,  531. 

83,  253,  485,  487,  557. 

192,  485,  487,  491,  537,  557. 

433. 

492. 

492. 

7,  127,  210,  310,  339,  384,  433,  460,  487,  491,  502, 

531,  589. 
7,  192,  210,  384,  415,  433,  440,  460,  462,  487,  491, 

502,  515,  531. 

433. 

433. 

485. 

253. 

440,  492,  515. 

74,  X. 

485. 

83,  210,  339,  433,  487,  491,  531. 

7,  210,  384,  433,  462,  487,  491,  492,  510,  531. 

537. 

487. 

487. 

7,  127,  210,  433,  487,  491,  492,  502,  531. 

7,  127,  192,  210,  310,  384,  433,  460,  462,  487,  491, 

492,  502,  531,  537,  557. 
127,  310,  433,  487. 
7,  127,  192,  210,  21S,  415,  433,  462,  487,  492,  502, 

531. 
462,  531. 
510. 

74,  104,  253,  260,  502,  510,  537. 
74,  219,  253,  310,  440,  485,  502,  510,  531. 

253. 
219. 
104,  192,  219,  253,  415,  485,  502,  515,  531. 

384,  440,  531. 

219. 

515. 

253. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


TAFtE  ISn. --Synthetic 


rganic    chemicals:    Toners  and  Jakes   for  which  United  States  production  or  sales  were 
reported,    identi  fied  by  manufacturer ,    1956- -Continued 


Manufacturers'  Identification  numbers 
(according  to  list  In  table  27) 


TONERS  OR  FULL-STRENGTH  COLORS— Continued 

»Maroon  toners — Continued 

Naphthol  AS-D  (Pr.  306)  maroon 

a-Naphthylamlne  maroon,  C.I.  82 

«Toluidine  maroon  (Naphthol  AS-BS  and  mnpt) 

"Orange  toners: 

"Benzidine  orange  (deb  and  pmp) 

"Dlanisldine  orange  (dlanlsidlne  and  aaa  or  aaot)- 

•2,'4-Dlnltroanillne  orange  (dna  and  bn) 

Hansa  orange 

Llthosol  orange  OTP 

•o-Nltroanlllne  orange  (ona  and  bn) 

Permansa  orange  H 

All  other 

»Red  toners: 

Bona  arylamine  (Virginia  red) 

Brilliant  red  N  (Red  lake  R) 

•o-Chloro-p-nltroaniline  red  (Chlorinated  para 
r ed )  ( ocpna  and  bn ) . 

p-Chloronitroanillne  red 

«Eoslne  (Bromo  acid  toner)  (C.I.  768) 

Fuchsine  (C.I.  677),  PMA 

Gentex  red  RP 

Hello  fast  pink  RLA 

Hello  red  RMTA  (Pr.  112)  (mtps  and  bn) 

»Lithol  red  2G  (C.I.  166) 

»Lithol  red  R,  C.I.  189: 
*Barlum  toner: 

Made  from  pigments  of  own  manufacture 


Made  from  purchased  pigments -— 

•Calcium  toner: 

Made  from  pigments  of  own  manufacture 


Made  from  piirchased  pigments — - 

•Sodlim  toner 

«A11  other  lithol  red  R  toners:  Made  from  pig- 
ments of  own  manufacture. 
Lithol  red  R,  C.I.  189  and  red  lake  C,  C.I.  165— 
•Llthol  rubine  B  (C.I.  163) 

Lithol  rubine  B  (C.I.  163)  and  rhodamine  6G  (C.I. 
753). 

Llthosol  red  CSP 

Naphthoic  red  C 

»Naphthol  reds: 

Bona  arylamine — . 

»Naphthol  AS  (Pr.  302)  and  dca 


Naphthol  AS  (Pr.  302)  and  oca 

»Naphthol  AS  (Pr.  302)  and  pnot 

•Naphthol  AS-BS  (Pr.  305)  and  pnoa- 


•Naphthol  AS-D  (Pr.  306)  and  pnot 

Naphthol  AS-ITR  (Pr.  310)  and  ITR  base  (Pr. 
378). 

Naphthol  AS-OL  (Pr.  311)  red 

Naphthol  AS-TR  (Pr.  Sli)  and  TR  base  (Pr.  ^2)- 

All  other  naphthol  reds — ~ — — — 

*Para  red,  light,  C.I.  44 


»Para  red,  dark- 


398)— 


Permanent  carmine  FB  (Pr. 

Permanent  carmine  FR — — — 

Permanent  carmine  FL — ■ — — 

•Permanent  red  2B  (Pr.  563)  (ooptms  and  bon)- 


Permanent  red  FKB— 

Permanent  red  FKR  ex 

Permanent  red  PC 

Permanent  red  RA 

Pigment  rubine  3G  (pcams  and  bon)- 
Polaris  red- 

•Pyrazolone  red -^ 

•Red  lake  C  (C-red),  C.I.  165: 
Barium  toner: 

Made  from  pigments  of  own  manufacture- 
Made  from  purchased  pigments 


310,  515,  531. 

531. 

219,  253,  485,  515,  531. 

7,  192,  253,  462,  485,  492,  515,  531,  537,  557,  X. 

104,  253,  485,  515,  531. 

310,  440,  485,  502,  531,  537. 

192,  515. 

253. 

104,  387,  415,  440,  485,  492,  531. 

485. 

7,  74,  192,  502,  510,  X. 

104. 

7,  440,  515. 

7,  104,  192,  219,  310,  387,  415,  440,  460,  462,  485, 

492,  502,  531,  537,  557. 
192,  253,  415,  440,  485. 
7,  339,  415,  462,  492,  537,  557,  589,  X. 
433. 
510. 
510. 
510. 
7,  460,  485,  531. 


7,  83,  104,  192,  310,  415,  460,  462,  473,  485,  492, 

502,  531,  537,  557. 
339. 

83,  104,  192,  310,  415,  460,  462,  473,  485,  492,  502, 

531,  537,  557. 
339. 

104,  192,  415,  460,  485,  492,  537. 
192,  462,  537. 

485. 

7,  219,  253,  339,  415,--433,  460,  462,  485,  491,  492, 

502,  515,  531,  557.' 
415. 


253. 
515. 


253. 

7,  74,  192,  310,  440,  460,  485,  487,  515,  531. 

7,  192,  219,  253,  384,  415,  460,  485,  515,  531,  537. 

7,  192,  210,  253,  415,  440,  485,  502,  515,  531,  537, 

557. 

7,  192,  415,  433,  485,  502,  515,  531,  537,  557,  X. 

7,  485,  502,  531,  557,  X. 

7,  219,  253,  515,  531. 

7. 

485,  X. 

83,  104,  192,  219,  268,  310,  339,  415,  460,  473,  485, 

492,  502,  515,  531,  537. 
83,  104,  192,  268,  310,  339,  387,  415,  433,  460,  462, 

473,  485,  492,  502,  515,  531,  537. 
510. 
510. 
510. 
7,  192,  219,  253,  339,  415,  433,  440,  460,  462,  485, 

492,  502,  510,  515,  531. 
510. 
510. 
510. 
510. 

219,  433,  510,  531. 
485. 
7,  74,  219,  253,  485,  502,  515,  X. 


7,  83,  104,  192,  415,  460,  462,  485,  492,  502y  515, 

531,  537,  557. 
127,  339,  433. 


100 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  ISB. --Synt/ietiC  organic    chemicals:    Toners   »id  lakes   for  which  United  States  prddiction  or    sales  were 
reported,    identified  by  manufacturer,    7956 --Continued 


Manufacturers'   identification  numbers 
(according  to  list  in  table  27) 


TONERS  OR  FULL-STRENGTH  COLORS— Continued 

*fled  toners—Continued 

•Red  lake  C  (C-red),   C.I.   165— Continued 

Sodium  toner 


Permanent  red  FEL- 


Red  lake  D  (C.I.   2U) 

»Rhodamine  B  (C.I.  749),  PMA ^ 

»Rhodamine  B  (C.I.  7A9),  PTA 

»Rhodamine  60  (Rhodamine  6GDN)  (Rhodamlne  Y) 

(C.I.  752),  PMA. 
•Rhodamlne  60  (Rhodamlne  6GDN)  (Rhodamine  Y) 

(C.I.  752),  PTA. 

•Toluidine  red,   C.I.   69 

Vulcan  fast  red  B   (Pr.  <i76) 

Vulcan  fast  red  BBE 

All  other 

•Violet  toners; 
Cyclo  blues- 
Ethyl  violet  (C.I.  682),  PMA- 
Ethyl  violet  (C.I.  682),  PTA- 
Methyl  vlolet- 
•Methyl  violet  B  (C.I.  680),  fugitive- 


•Methyl  violet  B  (C.I.  680),  PMA- 
Methyl  violet  B  (C.I.  680),  PTA- 


Methyl  violet  oleate — 
Permanent  violet  RL— 
All  other 


•Yellow  toners: 

Acetoaoetanllid  yellow,  PMA 

Benzidine  yellows: 

•Benzidine  yellow  (deb  and  aaa) — 

Benzidine  yellow  (dob  and  aamx)- 

Benzidlne  yellow  (deb  and  aaoa)- 

•Benzidine  yellow  (dob  and  aaot)- 


Benzidine  yellow,  other — — _— 

•Hansa  yellows: 

•Hansa  yellow  G,  Pr.  103  (mnpt  and  aaa) 

•Hansa  yellow  50,  Pr.  lO-i  (ona  and  aaa) 

•Hansa  yellow  100,  Pr.  105  (poona  and  ocaaa)- 

Hansa  yellow  130 

Hansa  yellow  M — 


Hansa  yellow  3R,  Pr.  280 

Hansa  yellow  "^R— — — — 

Hansa  yellow  (mnpt  and  aaa) — 
Hansa  yellow  (mnpt  and  aaot)- 


Lithol  fast  yellow  3QD  (Lithosol  fast  yellow 
3GD). 

Lithol  yellow  0  (Lithosol  yellow  G) 

Hansa  yellow,  other — 
Permanent  yellow  GNVS — 
All  other 


REDUCED  OR  EXTENDED  TONERS 

Black  toners,  reduced: 

•Basic  black 

Carbon  black,  reduced————— — — 

Carbon  black,  toned— — — — 

Indullne  base  (C.I.  860) 

•Blue  toners,  reduced: 

Alkali  blue,  C.I.  704 

Indanthrene  blue  OCD  (C.l.  1113) 

Indanthrene  blue  RS  (C.I.  1106) 

Indanthrene  brilliant  violet  RR 

Methylene  blue  (C.I.  922) 

Methylene  blue  (C.I.  922)  and  methyl  violet  B 
(C.I.  680),  fugitive. 
•Peacock  blue  R  (C.I.  664),  PMA 


492,  537. 

510. 

440. 

7,  310,  339,  384,  433,  487,  491,  531,  589. 

7,  83,  192,  253,  384,  415,  433,  462,  485,  487,  491, 

492,  502,  531,  537. 
192,  310,  384,  433,  460,  485,  487,  491,  492,  502,  531, 

557,  589. 
7,  192,  253,  384,  415,  433,  460,  462,  487,  491,  502, 

531,  537,  557. 
537,  557. 
7,  83,  104,  192,  219,  253,  268,  310,  387,  415,  440, 

460,  462,  473,  485,  492,  502,  515,  531,  537. 
510. 
510. 
192,  485,  537,  X,  X. 

228. 
487. 
487. 
506. 
192,  210,  339,  433,  460,  462,  487,  492,  531,  537, 

557,  589. 
7,  83,  104,  192,  210,  310,  339,  384,  387,  433,  460, 

462,  473,  485,  487,  491,  492,  502,  531,  557,  589. 
7,  192,  384,  415,  433,  460,  485,  487,  502,  515,  531, 

537,  557. 
537. 
510. 


462. 

7,  104,  192,  219,  253,  339,  384,  387,  415,  440,  460, 
485,  492,  502,  515,  531,  537,  557,  589,  X. 

7,  X. 

537. 

7,  104,  192,  253,  384,  440,  460,  485,  492,  502,  510, 
515,  531,  537,  557,  X. 

485,  502,  531. 

7,  104,  192,  219,  253,  310,  387,  415,  440,  457,  460, 

462,  473,  485,  492,  502,  515,  531,  537,  557. 
83. 

7,  219,  310,  440,  460,  531. 

7,  192,  219,  440,  460,  485,  502,  510,  515,  531. 
515. 
485. 

460,  510. 
440,  485. 
502. 
502. 
253. 

510. 
74,  X. 

510. 


384, 

433, 

487 

487. 

487. 

502. 

433. 

515, 

531. 

253. 

253. 

384, 

433, 

487 

384. 

384, 

487, 

.491 

SYNTHETIC  ORGANIC  CHEMICALS,  1956  101 

TAELE  ISB.- -Synthetic    organic    cheaiicala:    Toners  and  lakes    for  which  United  States  production  or  sales  were 
reported,    identi  fied  hy  merufacturer .    1956- -Continued 


Manufacturers'  identification  numbers 
(according  to  list  ^n  table  27) 


REDUCED  OR  EXTENDED  TONERS—Continued 

"Blue  toners,  reduced — Continued 

Peacock  blue  R  (C.I.  6M) ,   PTA 

»Phthalocyanine  blue  B  (alpha  modification), 
Pr.  481. 
Phthalocyanine  blue  BG  (green  shade)  (beta  modi- 
fication) . 

Phthalocyanine  blue  R 

Rhoduline  blue,  fugitive 

»Setoglaucine  (Peacock  blue  G)  (Rhoduline  blue  6G) 

(C.I.  658),  PMA. 
Setoglaucine  (Peacock  blue  G)  (Rhoduline  blue  6G) 

(C.I.  658),  PTA. 
Setoglaucine  (Peacock  blue  G)  (Rhoduline  blue  60) 
(C.I.  658),  fugitive. 

"Victoria  blue  B  (C.I.  729),  fugitive 

Victoria  blue  B  (C.I.  729),  PMA 

Victoria  blue  B  (C.I.  729),  PTA 

Victoria  blue  R  (C.I.  728),  PMA 

Victoria  blue  R  (C.I.  728),  PTA 

Victoria  pure  blue  B  (Pr.  198),  fugitive 

Victoria  pure  blue  B  (Pr.  198),  PMA 

Victoria  pure  blue  B  (Pr.  198),  PTA 

*Brawn  toners,  reduced; 

Bismarck  bro«n  G  (C.I.  331),  fugitive 

Bismarck  brown  R  (C.I.  332),  fugitive 

Indanthrene  brown  RY — _. 

Para  brown 

*Green  toners,  reduced: 

Benzidine  yellow  and  iron  blue 

Benzidine  yellow  and  phthalocyanine  blue 

Benzidine  yellow  and  PTA  green 

Brilliant  green  (C.I.  662),  fugitive 

"Brilliant  green  (C.I.  662),  PMA 

Brilliant  green  (C.I.  662),  PTA 

Brilliant  green  (C.I.  662)  and  auramine  0  (C.I. 

655),  PMA. 
Brilliant  green  (C.I.  662)  and  benzidine  yellow, 
PMA. 
"Brilliant  green  (C.I.  662)  and  thioflavlne 

(C.I.  815),  PMA. 
"Brilliant  green  (C.I.  662)  and  thioflavlne 
(C.I.  815),  PTA. 

Malachite  green  (C.I.  657),  fugitive 

Malachite  green  (C.I.  657),  PMA 

Malachite  green  (C.I.  657),  PTA 

Malachite  green  (C.I.  657)  and  auramine  0  (C.I. 

655). 
Malachite  green  (C.I.  657)  and  thioflavlne  (C.I. 
815),  PMA. 

Phthalocyanine  green,  Pr.  4-83 

"Pigment  green  B,  Pr.  149 

Shamrock  green — — 

Maroon  toners,  reduced: 

B.O.N,  maroon  (Lithol  maroon)  (Tobias  acid  and 
bon). 

Naphthol  AS-QL  (Pr.  311)  and  poona 

a -Naphthylamine  maroon,  C.I.  82 

"Orange  toners,  reduced: 

Benzidine  orange  (deb  and  pmp) 

Dianisidine  orange  (dianisldine  and  aaa  or  aaot)- 

2,4-Dinitroaniline  orange  (dna  and  bn) — — 

Naphthol  AS-D  (Pr.  306)  and  dca  plus  mca 

"o-Nitroaniline  orange  (ona  and  bn) 

Orange  RK  lake 

"Red  toners,  reduced: 

Bona  arylamlne  (Virginia  red) 

o-Chloro-p-nitroanillne  red  (Chlorinated  para 
red)  (ocpna  and  bn) . 

"Eosine  (Bromo  acid  toner)  (C.I.  768) 

Fuchsine  (Magenta)  (C.I.  677),  fugitive 

Lithol  red  2G  (C.I.  166) 

"Lithol  red  R,  C.I.  189: 

Barium  toner — 

Sodium  toner- — ■-  '  ■ —— 

"Lithol  rublne  B  (C.I.  163) 


460,  491,  531. 

74,  104,  253,  310,  384,  433,  485,  487,  502,  515,  531. 


210. 
487. 
384,  433,  487,  491,  531,  589. 

433,  462,  487,  531. 

433. 


384,   433, 

487. 

487,   491. 

487,    502. 

531. 

531. 

384. 

253,   433, 

460,    487,    531,    589. 

192,   433, 

487. 

487. 

7,   433,    502. 

487. 

384. 

531. 

531. 

531. 

433. 

7,    253,    334,   433,   487,    531,    589 

487,    557. 

210,   487. 

253,  433,  531,  557. 

210,  253,  384,  433,  487,  502. 

310,  384,  433. 

433. 

433,  460,  487,  491. 

192,  491. 

433,  487. 

487,  531. 

74,  104,  210,  253,  384,  433,  487,  515. 
74,  253,  310,  487. 
310,  485. 

192,  433. 


253, 

487, 

531. 

253, 

515. 

192, 

384, 

487. 

74. 

387, 

-133, 

485, 

531. 

253. 

487. 

104. 

104, 

487. 

7,    310,   433,    531. 

433. 

460. 

192,  210,  415,  433,  460,  487,  502. 

192,  415,  460,  487. 

460,  487. 

7,  192,  433,  487,  502,  531. 


102 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  15B.  ■■  Synthetic    organic    chemicals:    Toners  and  lakes   for  which  United  States  production  or  sales  were 
reported,    identi  fied  by  manufacturer ,    1956--Cont  inued 


Manufacturers'   identification  numbers 
(according  to  list  in  table  27) 


REDUCED  OR  EXTENDED  TONERS— Continued 

"Red  toners,   reduced—Continued 
»Naphthol  reds: 

Naphthol  AS   (Pr.   302)   and  doa 

Naphthol  AS  (Pr.  302)   and  oca 

Naphthol  AS   (Pr.    302)   and  pnot 

Naphthol  AS   (Pr.   302),   Naphthol  AS-D  (Pr.   306) 
and  dca. 

Naphthol  AS-BS   (Pr.   305)  and  nmpt 

"Naphthol  AS-BS  (Pr.   305)  and  pnoa 

Naphthol  AS-D  (Pr.    306)   and  ranpt 

Naphthol  AS-D  (Pr.   306)   and  ranpt  plus  ona 

Naphthol  AS-D  (Pr.   306)   and  ona 

Naphthol  AS-D  (Pr.   306)   and  pnot 

»Para  red,   light,   C.I.   44 

»Para  red,   dark — — 

"Permanent  red  2B  (Pr.   563)    (ooptms  and  bon) 

Pigment  rubine  30  (pcams  and  bon) 

Pyrazolone  red — 

Red  lake  C  (C-red),   C.I.   165: 

Barium  toner 

Sodium  toner — 

"Rhodamine  B  (C.I.  749),  fugitive 

"Rhodamine  B  (C.I.  749),  PMA 

"Rhodamine  B  (C.I.  749),  PTA 

Rhodamlne  B  (C.I.  749)  and  auramine  0  (C.I.  655) 

PMA. 
Rhodamlne  B  (C.I.  749)  and  rhodamine  6G  (C.I. 

752),  PMA. 
Rhodamine  B  (C.I.  749)  and  rhodamlne  6G  (C.I. 

752),  PTA. 
Rhodamine  6G  (Rhodamine  6GDN)  (Rhodamine  Y) 
(C.I.  752),  fugitive. 
"Rhodamine  6G  (Rhodamine  6GDN)  (Rhodamine  Y) 

(C.I.  752),  PMA. 
"Rhodamine  6G  (Rhodamlne  6GDN)  (Rhodamine  Y) 
(C.I.  752),  PTA. 

"Toluldine  red,  C.I.  69 

Vat  pink  (C.I.  1211) 

"Violet  toners,  reduced: 

"Ethyl  violet  (C.I.  682),  PMA 

"Ethyl  violet  (C.I.  682),  PTA 

Indanthrene  brilliant  violet  RR  (C.I.  1104) 

Indanthrene  red  violet  RHA — 

"Methyl  violet  B  (C.I.  680),  fugitive 

"Methyl  violet  B  (C.I.  680),  PMA 

Methyl  violet  B  (C.I.  680),  PTA 

Methyl  violet  R.S.,  PMA 

Methyl  violet  LA  and  magenta  ABN 

Yellow  toners,  reduced: 

Auramine  0  (C.I.  655),  fugitive 

Auramine  0  (C.I.  655),  PMA 

Benzidine  yellows: 

"Benzidine  yellow  (deb  and  aaa) 

"Benzidine  yellow  (dob  and  aaot) 

Benzidine  yellow,  other 

"Hansa  yellows: 

Hansa  yellow  G,  Pr.  103  (mnpt  and  aaa) 

Hansa  yellow  5G,  Pr.  104  (ona  and  aaa) 

Hansa  yellow  lOG,  Pr.  105  (pcona  and  ocaaa) — 

Lithol  fast  yellow  3GD 

Hansa  yellow,  other 


LAKES  OR  LAKED  COLORS 


Black  lakes: 

Carbon  black 

"Logwood  black  (C.I.  1253)- 

Pulp  bone  black 

All  other 

"Blue  lakes: 

Brilliant  blue  FCF 


74,  210,  310,  487. 

487. 

253,  502,  537. 

74. 

310. 

104,  219,  253,  460,  485,  502,  537. 

74. 

74. 

74. 

433. 

192,  387,  487,  531. 

ly2,  210,  310,  384,  387,  433,  531. 

7,  192,  210,  253,  310,  384,  415,  433,  460,  502. 

487,  502. 

485. 


537. 

210,  310,  433,  487. 

384,  433,  487,  589. 

192,  253,  433,  460,  487,  502. 

557. 

433,  487. 

557. 

433. 

253,  384,  433,  487,  589. 

74,  253,  310,  433,  462,  487,  502. 

104,  192,  210,  253,  387,  420,  433,  485,  487,  531. 
7,  192,  384,  433,  487. 

253,  487,  531,  589. 

253. 

253. 

74. 

192,  210,  384,  433,  460,  487,  502,  557. 

253,  310,  433,  460,  487,  531,  589. 

192,  433,  487. 

491. 

74. 

384,  487. 
487. 

253,  462,  557. 

104,  253,  485,  487,  515,  531,  537. 

485. 

104,  253,  487,  531,  589. 

310. 

253,  384,  487. 

253. 

74,  460. 


"Brilliant  wool  blue  FFR  (Pr.  40) 

Methyl  cotton  blue  (C.I.  706) 

Methylene  blue 

Methylene  base  and  tannic  acid— 

Patent  blue  (C.I.  671) 

"Peacock  blue,  fugitive  (Patent  blue)  (C.I.  671)- 


74,   420. 

192,    326,   420, 

420. 

420,   440. 

589 

192. 

74,    326,   420. 

X. 

310. 

462. 

433. 

7,  83,  127,  192,  310,  339,  420,  433,  ''•62,  487,  491, 
492,  502,  531,  537,  557,  X. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


103 

TfflLE  ISR.^-Synthetic    orimic    chmicala:   Toners  and  lakes    for  which  United  Stntea  production  or  aaiea  were 
reported,    identified  by  manufacturer,    J95tf --Continued 


LAKES  OR  lAKED  COLORS — Continued 

»Blue  lakes — Continued 

Phthalocyanine  blue,   sulfonated 

Phthalocyanine  blue  and  fastusol  yellow — ~ 

True  blue ■    ■    .■■    — — __.. 


Turquoise  blue  (C.I.  661) 

Victoria  blue— —————— —-—— 

»Brown  lakes: 

Bismarck  brown,  tannic  acid  lake — 
Orange  II  and  nigrosine— ——— — — 

All  other —  ■ 


"Green  lakes: 

Acid  green  B  (C.I.  669) 

Brilliant  green  (C.I.  662) 

Brilliant  green  (C.I.  662)  and  naphthol  yellow  S 

(C.I.  10). 
Emerald  green--- — — _______ 


Green  lake  CPS_ 


Malachite  green  (C.I.  657)  and  fast  light  yellow 

(C.I.  636). 
Peacock  blue  (C.I.  671)  and  naphthol  yellow  S 

(C.I.  10). 

Pigment  green  B,  Pr.  l-Vg 

Shamrock  green — .. 

"Maroon  lakes: 

Alizarin  lake — ___ _______ __ 


Alizarin  maroon  (C.I.  10^1) 

Amaranth  (C.I.  IBA) 

Azo  Bordeaux  (C.I.  88) 

Hypemic  (C.I.  120) 

Quinizarin  rubine 

All  other 


Orange  lakes: 

Acid  orange  R  (C.I.  161) 

Naphthol  AS_QL  (Pr.  311) 

"Persian  orange  (Acid  orange  Y)  (Orange  II)  (C.I. 
151). 

All  other^ 

•Red  lakes: 

"Alizarin  red  B  (C.I.  1027) 

Anthosine  red  5B__'  ■ _ — — _— _— 

Azo  rubine  (C.I.  179) 

Carmine  (C.I.  1239) 

Crocein  scarlet  3BX  (Cochineal  lake)  (C.I.  183)- 

Helio  fast  rubine  -iBL  (Pr.  '«36) 

Lithol  rubine  B  (C.I.  163) 

Madder  lake  6B  and  6B  cone 

Magenta 


Magenta  and  rhodamine  B_ 
Pigment  soarlet- 
"Pigment  scarlet  3B  (C.I. 

Polar  red  (C.I.  430) 

Red  lake  C 


216)- 


Rhodamlne  B  (C.I.  7'i9) 

Rhodamine  6G  (C.I.  752) 

Scarlet  GRCL  (GDC) 

"Scarlet  2R  (C.I.  79) 

Turkey  red,  medlum_— — 

All  other — — __ 


"Violet  lakes: 

Acid  violet  (C.I. 

Alizarin  purple 

"Methyl  violet 

Purple  lake  R 

All  other 


Yellow  lakes: 

Benzidine  yellow — — -__ — -__ __ 

"Fast  light  yellow  (C.I.  636) 

Hansa  yellow  G_ 

Naphthol  yellow  S  (C.I.  10) 

Quercitron  (Flavine)  (C.I.  1251) 

Quinoline  yellow  (C.I.  801) 

"Tartrazine  (C.I.  6A0) 

Thioflavine 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


-igi. 

491. 

491. 

192. 

74. 

326,  420. 

7,  326,  433. 

491. 

192. 

310,  531. 

268. 

420. 


485. 
485. 

485. 

515. 

192,  219,  485. 

310,  387,  433,  473,  485,  487,  531. 

531. 

473. 

74,  310,  326,  420. 

83,  491,  531. 

83. 

74,  192,  326,  339,  384,  420,  462,  487,  491,  502,  515, 

531,  537,  557. 
268. 

7,  74,  192,  210,  384,  440,  473,  485,  502,  515,  531. 

487. 

433. 

66,  192. 

192. 

253,  387,  433,  460,  502,  510,  531,  557. 

485. 

440. 

485. 

491. 

268. 

7,  192,  253,  384,  433,  440,  460,  502. 

487. 

485. 

557. 

531. 

387. 

7,  74,  192,  210,  219,  310,  326,  420,  433,  502,  531. 

268. 

268,  326,  491. 

420,  433,  460,  487. 

440. 

326,  420,  440,  491,  531. 

310. 

460. 

485. 

192,  460,  491,  502,  557. 

485. 

491. 

531. 

192,  491,  531. 

7,  83,  192,  310,  339,  384,  491,  505,  531,  537,  557. 

531. 

531. 


See  note  on  p.  104. 


104  UNITED  STATES  TARIFF  COMMISSION 

TABLE  \5B.  --Syntbet ic  organic  cbemicals:    Toners  anri   lakes    for   which  Uniteri  States   prortact ion  or   sales   were 
reported,    i'lent  i  fieri  hy  manufacturer  ,    795fi--Continued 

Hote    to  Tahle  15B 

Note. — The  C.I.  (Colour  Index)  and  Pr.  (prototype)  numbers  shown  in  this  report  are  the  identifying  num- 
bers given  respectively  In  the  Colour  Index  and  in  the  prototype  list  of  the  Technical  Manual  and  Yearbook 
of  the  American  Association  of  Textile  Chemists  and  Colorists.  A  C.I.  or  Pr.  number  enclosed  in  parentheses 
Is  always  the  number,  in  the  Index  or  Manual ,  of  the  dye  from  which  the  specified  toner  or  lake  was  pro- 
duced. If  the  C.I.  or  Pr.  number  is  not  enclosed  in  parentheses,  it  indicates  that  the  named  toner  is  itself 
listed  in  the  Index  or  Manual. 

The  abbreviations  PMA  and  PTA  stand  for  phosphomolybdic  and  phosphotungstio  acids,  respectively.  Pigments 
formerly  listed  as  PTMA  (phosphotungstomolybdlc  acid)  are  now  included  with  PTA  colors. 

Intermediates  used  in  the  manufacture  of  certain  colors  are  abbreviated  as  follows: 

aaa acetoacetanilide 

aaot aoetoacet-ortho-toluldide 

bn beta-naphthol 

bon beta-oxynaphtholc  acid  (3-hydroxy-2-naphthoic  acid) 

dca dichloroaniline 

deb dichlorobenzidine 

dna dinitroaniline 

mnpt meta-nitro-para-toluidine  (A-ohloro-ortho-toluidine) 

oopna ortho-chloro-para-nitroanlline  ( 2-ohloro-'*-nitroanlline ) 

ona ortho-nitroaniline 

pmp phenylmethylpyrazolone 

pnoa para-nitro-ortho-anisidine  (5-nltro-ortho-anisidine) 

pnot para-nitro-ortho-toluidine  (5-nitro-ortho-toluidlne) 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


105 


TADLF.   17B. -Synthetic 


Medicinals 


reported, 


:  MeHicinats    for 
identifinrl  by  man 


ihich  United  states   prnHucti 
•facturer,    1956 


[Medicinals  for  which  separate  statistics  are  given  in  table  17A  are  marked  below  with  an  asterisk  (»); 
medicinals  not  so  marked  do  not  appear  in  table  17A  because  the  reported  data  are  accepted  in  confidence 
and  may  not  be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from  table  27.  An  X 
signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number  with  the 
designated  product] 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


MEDICINALS,  CYCLIC 

Bemenoid 

3-Acetamido-2,4,6-triiodobenzoic  acid  and  sodium 

salt. 
Acetarsone   I'N-Acetyl-^-hydroxy-m-arsanilic  acid) 
(Stovarsol). 

Acetylglycol  salicylate 

»Acetylsalicylic   acid   (Aspirin) 

Adrenaline   (Epinephrine ) 

♦Amino  acids: 

3, 5-Diiodo tyrosine 

d- Phenylalanine 

dl-Phenylalanine 

1-Phenylalanine 

d-Tyrosine 

dl-Tyrosine 

1-Tyrosine 

2-Amino-'i-arsenosophenol  (Mapharsen)  hydrochloride- 
Aminobenzoic  acids,  derivatives,  and  salts: 

o-Aminobenzoic  (Anthranilic )  acid,  cadmium  salt-- 
m-Aminobenzoic  acid  derivatives : 

2-Isobutylaminoethyl  m-aminobenzoate  (Unacaine) 

»p-Aminobenzoic  acid 

*p-Arainobenzoic  acid  derivatives: 

2-Amylaminoethyl  p-aminobenzoate  (Amylsine) 

Benzocaine  (Ethyl  p-aminobenzoate) 

Butacaine  (3-Di-n-butylaminopropyl  p-amino- 
benzoate) base. 

Butacaine  sulfate 

Butesin  (n-Butyl  p-aminobenzoate) 

Butesin  picrate  (Di(n-butyl  p-aminobenzoate) 
trinitrophenol). 

2-Chloroprocaine  hydrochloride 

2-Diethylaminoethyl  4-amlno-2-propoxybenzoate 

(Ravocaine)  hydrochloride. 
2-Diethylamlnoethyl  2-butoxy-3-aminobenzoate 
(Primacaine)  hydrochloride. 

Isobutyl  p-aminobenzoate  (Cycloform) 

2-Isobutylaminoethyl  p-aminobenzoate 

(Monocaine). 
Procaine  base  and  salts : 

Procaine  base  (2-Diethylaminoethyl  p-amino- 
benzoate) (Novacaine  base). 

^Procaine  hydrochloride 

Procaine  isobutyrate 

Propyl  p-aminobenzoate 

♦Tetracaine  (2-Dimethylamlnoethyl  p-butylamino- 
benzoate)  base. 

♦Tetracaine  hydrochloride 

p-Aminobenzoic  acid  salts: 

Calcium  p-aminobenzoate 

♦Potassium  p-aminobenzoate 

♦Sodium  p-amlnobenzoate 

p-Amlnohippuric  acid 

A-Amino-2-methyl-l-naphthol  hydrochloride 
(Synkamin). 

"^-Aminosalicylic  acid 

"♦-Aminosalicylic  acid  salts: 

Calcium  4-amlnoEallcylate 

Potassium  "i-aminosallcylate 

Sodium  ■♦-aminosalicylate 

sec-Amyltrioresol 

Anisoln  ("V,4'-Dimethoxybenzoin) 

1,8,9-Anthratriol  (Anthralin) 

3-Amlno-2,"4,6-trllodophenyl-2-ethylpropionic  acid  — 
•Antihistamines : 

2-(Benzhydryloxy)-N,N-dlmethylethylamine  hydro- 
chloride . 
p-Chlorobenzhydryl-m-methylbenzyldiethylene 

diamine  (Meclizine)  dihydrochloride. 
Diethylamlnoethoxyethyl  l-phenylcyclopentane- 

carboxylate  (Carbetapentone)  citrate. 
N, N-Dlmethyl-2- (a-phenyl-o-toloxy )ethylamlne 
dihydrogen  citrate. 


348,  "ise. 

3b5. 

197,  221,  252,  297,  368. 

17,  283,  348,  375,  392,  "lO?. 

218,  580. 
175. 

252,  348. 
175,  X. 
110. 
252. 
496. 
407. 

564. 

107. 

37,  169,  205. 

107. 

266,  348,  456. 

456. 

60,  456. 
365,  456. 
456. 

283,  335. 
348. 


365. 
107,  266. 


205,  456. 

205,  240,  456,  459,  489. 

365,  580. 


205. 

169,  205,  489. 

169,  205,  442,  489,  506. 


375,  407,  537. 


375, 

537. 

205, 

375, 

490 

375, 

407, 

537 

283. 

231, 

422. 

456. 

348. 

407. 

306. 

306. 

503. 

106 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  17B. --Syntheti 


anic   chemicala:    MpHicinals    fnr  which  United  States   prnHii 
eparted,    irient  i  fieri  by  manufacturer ,    i956--Continued 


Manufacturers'  Identification  numbers 
(according  to  list  in  table  27) 


MEDICINALS,  CYCLIC--Continued 
Btnzeno id- -Continued 

^Antihistamines --Continued 

2-(l,2,3,'i-Tetrahydronaphthyl)-2-imidazollne 
(Tetraiiydrozaline)  hydrochloride. 

Benzaldehyde 

Benzoic  acid 

Benzoic  acid  salts: 

Ammonium  benzoate 

Lithium  benzoate 

Benzyl  alcohol 

Benzyl-2-amlnopropan-l-ol 

l-Benzyl-2-aminopropan-l-ol 

p-Benzylphenyl  carbamate  (Diphenan) 

Benzyl  succinate 

3,'4-Bis(p-hydroxyphenyl)-2,3-hexadiene  diacetate-- 

•Bismuth  subgallate 

♦Bismuth  subsalicylate 

Bismuth  tetrabromopyrocatechol 

N,N'-Bis(3-nltrobenzenesulfonyl)ethylenediamine--- 

Bis('+-nltrophenyl)  disulfide 

tert-Butylcresol 

Calcium  creosote 

Carbarsone   (p-Carbamidobenzenearsonic   acid) ^-- 

Carbobenzoxy  chloride 

Chloramine  T  (Sodium  p-toluenesulfonchloramide  )--■ 

Chloromercuri-A-nitro-o-eresol 

Chloro thymol 

Chlorotrls(p-methoxyphenyl )ethylene  (Tri-p-anisyl 

chloroethylene ) . 

m-Cresyl  acetate  (Cresatin) 

p - ( Cyclohexy loxy )benzoic  acid 

Desoxyanisoln 

3,5-Diacetamido  2,'i,6-triiodo  benzoic  acid, 

sodium  salt. 

Dialuminum  aoetyl-o-salioylate 

p,p'-Diaminodiphenylsulf one -N,N'-di (dextrose 

sodium  sulfonate). 

2,5-Diaminotoluene  sulfate 

a-Diethylamino-2,6-acetoxylidine 

Diethylamino-p-ethoxy-benzoate  hydrochloride 

2-Diethylaminoethyl  diphenylacetate  citrate 

2-Diethylaminoethyl  diphenylacetate  hydrochloride- 
P-Diethylaminoethyl  diphenylthioacetate  hydro- 
chloride. 
N-Diethylaminoethyl  isoamyl  phenyl  glycinate 

dihydrochloride. 

p,p'-(l,2-Diethylethylene)dlphenol  (Hexestrol) 

p,p'-(l,2-Diethylethylene)diphenol  (Hexestrol) 

diphosphoric  ester,  sodium  salt. 
p,p'-(l,2-Diethylethylene)diphenol  (Hexestrol) 

dipropionate. 
N,N-Diethylsalicylamide  (Diethylamine  salicylate)- 
(X.a'-Dlethyl-'V.'i'-stllbenediol  (Diethylstil- 

bestrol). 

a, a'-Diethyl-Aji'-stilbenedlol  diphosphate 

a,  o'-Diethyl-'4,4'-stilbenediol  dipropionate 

3 , 4-Dlhydroxynorephedrine  ( 3, ^-Dihydroxyphenyl- 

propanolamine )  hydrochloride. 
P-(3,5-J)iiodo-'l-hydroxyphenyl)-ct-hydratropic  acid 
6-Dimethylamino-^,4-diphenyl-3-heptanone  hydro- 
chloride (Dolophine)  (Methadone). 

Y-Dimethylamino-<x,a-dlpherylvaleramide 

P-Dimethylaminoethyl(l-hydroxycyclopentyl )  phenyl 

acetate  (Cyclopentolate)  hydrochloride. 

Dimethyl -3 -hydroxyphenylammonium  chloride 

N,a-Dimethylphenethylainine  (Desoxyephedrine )  base 
N,P-Dlmett^lphenethylamine  base  and  hydrochloride 

»N , a-Dimethylphenethylamine  hydrochloride 

»d,N,a-Dlmethylphenethylamine  hydrochloride 

Dimethyl-p-toluidine 

Diphenylacetic  acid 

Diphenylacetyldlethylaminoethanol  hydrochloride -- 
3,5-Dipropionamldo-2,'V,6-triiodobenzolc  acid  and 

sodium  salt. 

Dipropylene  glycol  salicylate 

p-(Di-N-propylsulfamyl)benzoic  acid  (Benemid) 

Dithiosalicylic  acid 

»Dyes,  medicinal: 

Acriflavine  (3,6-Diamino-lO-methylacridine 
chloride ) . 


358. 
337. 


335,  ^2,    560,  56A. 
^2,    560,  5&4. 


50A. 
221. 

^2. 

271, 

266, 

422. 

422. 

238. 

205. 

375. 

306, 

297, 

580. 

345. 

537. 

365. 

564. 

37,  422,  580 

580. 

221. 

456. 

482,  560. 

115. 

560. 
422. 
231. 
348. 

456. 
407. 

477. 

18. 

365. 

365. 

365. 

316. 

490. 


231, 

X. 

X. 

X. 

579. 

231, 

422, 

456,    556 

375. 

231. 

348. 

413, 

551. 

422, 

564. 

503. 

116. 

454. 

375, 

490. 

365. 

375, 

489, 

490. 

375, 

456, 

489,    490 

37. 

205, 

543. 

543. 

564. 

327. 

560. 

422. 

SYNTHETIC  ORGANIC  CHEMICALS,  1956 


107 


TAH-E    17B. --";ynt  he  fi 


wtirp   reporteri , 


icalr;:    Metiicin»ls    for   u 
ifit^nt  i  fieii  hy  manufactv 


ich  United  St/tte-:   prnrliict  i 
nr ,    i95(5- -Continued 


Manufacturers'    identification  numbers 
(according  to  list  in  table  27) 


MEDICINALS,    CYCLIC— Continued 


tnoid--Contln 


»Dyes,  medicinal--Continued 

2,4-Diamino-'»'  -ethoxyazobenzene  hydrochloride 
(Serenium ). 

Gentian  violet 

Merbromin  (Dibromohydroxymercurifluoresceln, 
sodium  salt ), 

Methylene  blue 

Methyl  violet 

Proflavine   (3,6-Diaminoacridine  sulfate) 

Scarlet  red   (Phenol  red) 

Trypan  blue 

All  other 

l-Ephedrine  (a-(l-Methylaininoethyl)benzyl  alcohol) 

Ephedrine,  racemic 

N-Ethyl-3,3'-diphenyldipropylamine 

N-Ethyl-3 , 3 ' -diphenyldlpropylamine  citrate 

N-Ethyl-3,3'-diphenyldipropylamine  hydrochloride — 

Ethylene  glycol  salicylate 

N-Ethylephedrine  hydrochloride 

Ethyl  (iodophenyl)hendecanoate  (Pantopaque) 

a-Ethyl-a-phenylglutarimlde  (Doriden) 

Ethyl  salicylate 

Ethyl  salicylate  carbonate 

Gallic  acid 

Gentisic  acid  (2,5-Dihydroxybenzoic  acid) 

Glycol  monosalicylate 

Guaiacol,  liquid  and  crystalline 

Hexylresorcinol 

p-Hydroxyacetanilide 

m-Hydroxybenzaldehyde 

p-Hydroxybenzoic  acid  esters : 

Benzyl  p-hydroxybenzoate 

n-Butyl  p-hydroxybenzoate  (Butoben) 

Ethyl  p-hydroxybenzoate 

Methyl  p-hydroxybenzoate 

Propyl  p-hydroxybenzoate 

P -Hydroxy-p -(2,5 -dimethoxyphenyl )isopropylamine 

hydrochloride  (Methoxamine ) . 
o-[3-(Hydroxymercuri  )-2-(methoxyethoxy )  propyl- 
carbamoyl]  phenoxyacetic  acid  (Merethoxylline ). 
Hydroxymerouri-'i-nltro-o-cresol  anhydride 
(Metaphen ) . 

A-Hydroxy-3-nitrobenzenearsonic  acid 

p-Hydroxypropiophenone  (Hydrophen ) 

3-Hydroxypropylene  ester  of  3-acetamido-'i-hydroxy- 
dithiobenzenearsonous  acid  (Arsthlnol). 

o-Iodobenzoic  acid 

a- ( Isopropylaminomethyl )protocatechuyl  alcohol 
(Aleudrine). 

Mandelic  acid  ( Phenylglycolic  acid) 

Mandellc  acid  derivatives; 

Ammonium  mandelate 

Calcium  mandelate 

N-2-Hydroxyethylmandelamide 

o-Methoxy-N,^-dimethylphenethylamine  (l-(o- 
Methoxyphenyl )-2-methylamino-propane )  hydro- 
chloride. 
*3-(o-Methoxyphenoxy )-l,2-propanediol  (Glyceryl 

guaiacyl  ether). 
»a-Methylphenethylamine  (Amphetamine)  (Benzedrine) 
base. 

d-a-?;1ethylphenethylamine  base 

a-Methylphenethylamine  salts : 

a -Me thylphene thylamine  hydroc hloride 

a -Me thylphene thylamine  phosphate 

*a-Methylphene thylamine  sulfate 

d-a-Methylphenethylamine  salts; 

d -a-Methylphenethylamine  hydrochloride 

d-a-Methylphenethylamine  phosphate 

d-a-Methylphenethylamine  sulfate 

2-Naphthol  (P-Naphthol) 

♦2-Naphthyl  benzoate 

Neostigmine  bromide 

♦Neostigmine  methyl  sulfate 

Neosynephrine  (Phenylephrine)  hydrochloride 

p-Nitrobenzenearsonic  acid 

'♦-(2-Nitropropenyl)veratrole  (l-(3,'4-Dimethoxy- 
phenyl) -2-nitropropane-l) . 


506. 
34,  ^2. 

506,  537. 

506. 

506. 

506. 

506. 

506. 

560. 

560. 

231. 

231. 

231. 

365. 

115. 

477. 

543. 

221. 

365. 

564. 

365. 

221. 

221,  504. 

490,  560. 

86,  375. 

506. 

504. 

365,  504. 

504. 

37,  86,  365,  504. 

37,  86,  365,  504. 

238. 

422. 

456. 

86,  345. 
375,  456. 
291. 

580. 

231,  456,  489. 

564. 

580. 
564. 
422. 
375. 


37,  86,  489. 

321,  375,  396,  490. 

490. 

490. 

375,  490. 
375,  396,  490. 

375,  490. 

375,  490. 

375,  396,  490. 

364. 

364,  414,  560. 

54,  490. 

54,  490,  580. 

348,  364,  489. 

345. 

422. 


108 


UNITED  STATES  TARIFF  COMMISSION 


-Synthetic   organic  chemicals:    Merlicinals    fnr  which  Vniterl  States   prcrfii 
were   reporter),    iHentifieH  by  manufacturer ,    J 956- -Continued 


MEDICINALS,  CYCLIC- -Continued 


no id--rontlnued 


Norephedrine  (Propadrine)  hydrochloride 

Ootyloresol 

Octylresoroinol 

Paredrine  (p-Hydroxy-a-methylphenethylamine ) 

hydrobromide. 
Phenacaine  [ (Di-p-ethoxyphenyl)acetamidine] 
hydrochloride. 

Phenacetin  (Acetophenetidin) 

Phenolphthalein 

•Phenolsulfonic  acid  salts: 

Aluminum  phenolsulfonate 

Ammonium  phenolsulfonate 

Calcium  phenolsulfonate 

Copper  phenolsulfonate 

Sodium  phenolsulfonate 

Zinc  phenolsulfonate 

2-Phenyl-l,3-indandione  (Danilone ) 

*Phenyl  mercuric  derivatives : 

o-Chloromercuriphenol  (o-Hydroxyphenyimercuric 
chloride ). 

Phenylmercuric  acetate 

Phenylmercuric  benzoa te 

Phenylmercuric  borate 

Phenylmercuric  chloride 

Phenylmercuric  nitrate 

Phthalazone 

Pyrogallic  acid 

Resorcinol  monoacetate 

»Salicylamide 

•Salicylic  acid 

•Salicylic  acid  salts: 

•Ammonium  salicylate 

Bismuth  salicylate 

•Calcium  salicylate 

Magnesium  salicylate 

Mercuric  salicylate 

Potassium  salicylate 

•Sodium  salicylate 

Strontium  salicylate 

Sallcyl  salicylate  (Salysal ) 

Salol  (Phenyl  salicylate) 

Silver  picrate 

Sodium  antimony  III  biscatechol-2,4-disulfonate 
(Fouadin). 

Sodium  benzyl  succinate 

Sodium  ethylmercurl thlosalicylate 

Sodium  o-lodohippurate  dihydrate  (Hippuran) 

Sodium  phenoxyacetate 

•Sulfa  drugs: 

N'''-Acetyl-3,4-dimethyl-5-sulfanilamldo  isoxazole- 

Benzoylsulfanilamide 

Benzoylsulfanilamlde,  sodium  salt 

p-Benzylaminobenzenesulfonamide 

N''--(3,4-Dimethyl-5-isoxazolyl)sulfanilamide 

2-Methyl-l,3,^,5-sulfanilamldothiadiazole 

Neo-Prontosil  "S" 

Nisulfazole 

p-(p-Nitrophenylsulfonamldo)acetanilide 

(N'-Acetyl-N'--(^-nitrophenyl)  sulfanilamide). 

N'*-Phthalylsulfaacetamide 

Phthalylsulfathiazole 

Prontosil  soluble  (Disodium  "i-sulfaminophenyl- 
2-azo-7-acetylaniino-l-hydroxynaphthalene-3, 
6-dlsulfonate). 

Sulfadiazine » 

Sulfadiazine,  sodium  salt 

Sulfaethylthiodiazole 

Sulfaguanidine 

Sulfamerazine  (2-Sulfanllamide-i-methyl- 
pyTimidine ) . 

Sulfamerazine,  sodium  salt 

Sulfamethazine  (Sulf adimethyldiazine) 

Sulfamethoxypyridazine 

Sulfanilamide  (p-Aminobenzenesulfonamide) 

N-Sulfanilylacetamide  (Sulfaacetamide) 

N-Sulfanilylacetamide,  sodium  salt 

Sulfapyridine 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


3W. 
3W. 
396. 

348,  489. 

221,  252. 
221. 

564. 

86,  345. 

564. 

564. 

345,  564,  579. 

564. 

231,  489. 

238,  240,  283. 

307. 

240,  307. 

240,  307. 

307. 

240,  307. 

506. 

564. 

321,  364,  477. 

86,  169,  469,  579. 

221,  252,  492,  504. 

37,  86,  442,  564. 

564. 

86,  252,  564. 

564. 

564. 

86,  442,  564. 

221,  252,  504. 

86,  252,  564. 

86. 

252,  442. 

580,  594. 

348. 

205. 

54,  422,  556. 

564. 

456. 

454. 
537. 
537. 
348. 
454. 
537. 
348. 
348. 
345. 

37,  205,  537,  551. 

413. 

348. 


537. 
537. 
537. 
537. 
537. 


577. 


537. 

537, 

537. 

537.  560. 

37,  205,  551. 

37,  551. 

537,  560. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


109 


TABLE  ITB. --Synthetic  organic  chemicals:   Medicit 
were  reported,    identified  by 


als    for   which  United  States  product i 
manufacturer,    7956- -Continued 


Manufacturers'  Identification  numbers 
(according  to  list  In  table  27) 


MEDICINAl^,  CYCLIC— Continued 


Bent 


id--Contln 


♦Sulfa  drugs — Continued 

Sulfapyridine,  sodium  salt 

Sulfaquinoxaline 

Sulfasuxidine  (Succinylsulfathlazole) 

Sulfathalidine 

Sulfathiazole 

Sulfathiazole,  sodium  salt 

[Sulfonylbis(p-phenyleniniino)l  dimethanesulflnic 
acid,  disodium  salt  (Dlasone). 

Tannin  albuminate  (Tannalbin) 

Tannin-formaldehyde 

Thiophenol 

Thiosallcyllc  acid 

Thymol 

Thymol  Iodide-— 

»3-o-Toloxy-l,2-propanediol  (o-Cresyl  a-glyceryl 
ether). 
Vitamins : 

»K  (Menadione)  (2-Methyl-l,'4-naphthoqulnone) 

K  (Menadione),  sodium  bisulfite 

K  (2-Methyl-l,4-naphthoquinone-diphosphoric 

ester,  tetrasodium  salt). 
Ki  (2-Methyl-3-phytyl-l,<i-naphthoquinone) 

AUcyclic   and  Heterocyclic 

5-Acetamido-l,3,4-thiodiazole-2-sulfonamide 

Adenine  base 

Adenine  hydrochloride 

Adenine  sulfate 

Adenosine 

Adenosinediphosphoric  acid 

Adenosinediphosphoric  acid,  barium  salt 

Adenosine-5-phosphoric  acid 

Adenosinetriphosphoric  acid  and  salt 

Adenylic  acid 

Adenylic  acid,  isomers  A  and  B 

*^Alkalcids  and  related  products; 

Arecoline  (Methyl  1,2,5,6-tetrahydromethyl 
nicotinate)  hydrobromide. 

Atropine  amineoxide  hydrochloride 

Berberine  hydrochloride 

Erucine 

Colchicine 

♦Digitalis  glucosldes : 

Digifolin 

Digitalin 

Digitonin 

Digitoxin 

Digoxin 

Gitalin 

Ergotamine  tartrate 

Eserine  salicylate 

Ethylmorphine  hydrochloride 

Eucatropine  hydrochloride 

»Homatropine 

Homatropine  hydrobromide 

Homatropine  methyl  bromide 

Hydrastine 

Hydras tine  hydrochloride 

1-3-Hydroxy-N-allylmorphinan  tartrate 

1-3-f^droxy-N-methylmorphinan  tartrate 

Hyoscine  (Scopolamine)  amineoxide  hydrobromide- 

d-3-Methoxy-N-methylmorphinan  hydrobromide 

Nicotine  salicylate 

Rauwolfia  serpentina  (Alseroxylon)  fraction 

*Reserpine 

Strychnine 

Totaquine 

Totaquine  sulfate 

Veratrine 

Veratrum  viride   (Alkavervir) 

Allantoin   (5-Ureidohydantoin) 

6-Allyl-6,7-dihydro-5H-dibenz[c,e]azepine, 
phosphate-  salt. 
*Amino  acids : 

dl-Acetyltryptophane 

Histamine  dihydrochloride 

dl  and  1-Histidine 


537, 

560. 

560. 

-ilS, 

560. 

506. 

537, 

560. 

537, 

560. 

Ai6. 

37, 

86,  364. 

36A. 

54. 

422, 

556. 

337, 

369, 

482 

560, 

564. 

86, 

365, 

414, 

490. 

321 

456, 

489 

490,  555 

456 

454 

537. 

175. 

175. 

175,   477. 

175,   470. 

470. 

175. 

175,  470. 

175,   470. 

175. 

175. 

527. 

15. 

456,   469,    474. 

560. 

456,   469. 

543. 

469. 

469. 

533,    594. 

238. 

469. 

474. 

469. 

564. 

60. 

231,   291,   490,    560. 

231,   490. 

231,   490,    560. 

469. 

456,   469. 

454. 

454. 

86. 

454. 

364. 

344. 

306,    344,    469,    519,    543,    560. 

560. 

469. 

469. 

469. 

344. 

364,   X. 

454. 


348. 
454. 
55. 


110 


UNITED  STATES  TARIFF  COMMISSION 


TABLF.    17B. --.Synthetic  organic  chemicals:   Kedicinals   for  which  United  States  prnrhic 
were  reported,    identified  by  manufacturer,    7956- -Continued 


Manufacturers'    Identification  numbers 
(according  to  list  in  table  27) 


MEDICINAL5,    CYCLIC--Continued 


AH 


nd   Hett 


--Tontlnuert 


•Amino  acids --Continued 

dl  and  1-Histidine  monohydrochloride 

1-Histidine  dihydrochloride 

Hydroxy-1-proline 

1-Proline 

d -Tryptophane 

dl-Tryptophane 

2-Amino-5-chlorobenzoxazole 

2-Amino-5-nitrothiazole  (Enheptin) 

•Antibiotics  for  human  or  veterinary  use: 

Actidione 

Amphcmycin 

Bacitracin 

Carbomycin  (Magnamycin) 

Chloroampheniool  (Chloromycetin) 

Chlorotetracycline  (Aureomycin)  hydrochloride 

Cycloserine 

•Dihydrostreptomycin 

Erythromycin 

Fumaglllin 

Gramicidin 

•Neomycin,  base 

Novobiocin 

Nystatin 

Oleandomycin 

Oxytetracycline  (Terramycin)  hydrochloride 

•Penicillin  salts: 

Aluminum  penicillin  G 

Benzathine  penicillin  G 

Benzathine  penicillin  V 

Chloroprocaine  penicillin  0 

1-Ephenamine  penicillin  G 

Hydrobamine  penicillin  V 

Penicillin  V 

•Potassium  penicillin  G 

Potassium  penicillin  0 

Potassium  penicillin  V 

•Procaine  penicillin  G 

Sodium  penicillin  G 

Sodium  penicillin  0 

Polymixin  B  sulfate 

•Streptomycin 

•Tetracycline  (Achromycin) 

Tyrothrlcin 

Vlomycin 

•Antibiotics  for  animal  feed  supplements,  food 
preservation,  and  crop  spraying: 

Bacitracin 

Chlorotetracycline  (Aureomycin)  hydrochloride 

Oxytetracycline  (Terramycin)  hydrochloride 

Penicillin  salts : 

Benzathine  penicillin  G 

Procaine  penicillin  G 

Streptomycin 

•Antihistamines : 

2-(Benzhydryloxy)-N,N-dimethylethylamlne  8- 

chlorotheophylllnate . 
N-Benzyl-N',N'-dimethyl-N-2-pyridylethylenedl- 

amine. 
2-[  Benzyl(2-dimethylaminoethyl  )amino]  pyridine 
(N,N-Dlmethyl-N'-benzyl-N'-pyTidylethylenedi- 
amlne). 
1-^4-Chlorobenzhydryl )-4-methylplperazlne  hydro- 
chloride. 
2-[(p-Chlorobenzyl)(2-dlmethylaminoethyl)]  - 

pyridine . 
2-[ l-(p-Chlorophenyl) -3-dlmethylamlnopropyl] - 
pyridine  maleate  ( Chlorophenylpyridamlne 
maleate) . 
l-(p-Chlorophenyl)-2-phenyl-4-pyrrolidyl-2- 

butanol . 
l-(p-Chlorophenyl)-2-phenyl-'i-pyTrolidyl-l- 

butene  diphosphate  and  hydrochloride. 
l-(p-Chlorophenyl ) -2 -phenyl --i-pyrrolldyl-l- 

butene  hydrobromlde. 
2[(5-Chloro-2-thenyl)  (2-dimethylaminoethyl) amino], 
pyridine  citrate  (N,N-Dlmethyl-N'2-pyTidyl- 
N'2-(5-chlorothenyl)  ethylenediamlne  citrate). 
2-[a-(2-Dimethylamlnoethoxy)-a-methylbenzyl] - 
pyridine  succinate  (2-(Methyl-2'-dimethyl- 
aininoethoxybenzyl  )pyrldlne  succinate ) . 


■422,  X. 

37-1,  .422,  537,  560. 

422,  -456. 


55. 

55. 

578. 

578. 

252. 

3-48. 

375. 

537. 

283. 

503. 

306,  336,  469,  560. 

306. 

407. 

537. 

336, 

306, 

283, 

456. 

469. 

283,  306,  374,  469,  537,  560. 

X,  X. 

374. 

306. 

306. 


306. 
306, 
594. 
283. 
336. 
456. 
422, 
283, 
283. 
456. 
283, 
283, 
283. 
306. 
306, 
306, 
469. 
306. 


594. 

306,  336,  374,  422,  456,  503,  560,  594. 


306,  336,  374,  422,  456,  503,  560,  594. 
306,  374,  560. 


374,  422,  537,  560. 
503,  537. 


336,  366,  470,  560. 

537. 

306. 


306,  374,  422,  456,  503,  560. 
306,  560. 

207. 

543. 

543. 

456. 
551. 
551. 

422. 
422. 
422. 
221,  537. 

335. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


111 


TABLE    17B.  -  -Synthetic  organise  chemicals:   Xedicinals   for  which  United  States  proriucti 
were  reported,    identified  by  manufacturer ,    7956--Cbntinuef1 


Manufacturers'    identification  numbers 
(according  to  list  in  table  27) 


MEDICINALS,   CYCLIC— Continued 


All 


»Alithlstamlne6 — Continued 

2- [  (2-Dimethylaiiiinoethyl  )(p-methoxybenzyl  )- 

amino]  pyridine,  maleate. 
2-((2-Dimethylamlnoethyl)(p-methoxybenzyl)- 
amlno]pyrimldine  (N,N-Dimethyl-N'-p- 
methoxybenzyl-N-2-pyrlmldyletliylenediamlne ) . 
2- [( 2-Dimethylaminoe  tiyl )  tiienylamlno]  pyridine 
fumarate  (N,N-Dimetl^l-N'2-pyridyl-N'2- 
thenylethylenediamine  fumarate). 
2- [(2-Dimethylamlnoethyl )thenylamino] pyridine 
hydrochloride  (N,N-Dimethyl-N'2-pyridyl-N'2- 
thenylethylenediamlne  hydrochloride). 
N- (2 '-Dimethylamlno-2' -methyl)  ethylphenothiazine 

hydrochloride. 
2-  [3- (Dimethylamlno)-l-phenylpropyl]  pyridine 

(l-Phenyl-l-(2-pyridyl)-3-dimethylamlnopropane  ). 
2-[  3-(Diiiiethylaiiiino)-l-phenylpropyl  Jpyrldine 

maleate  ( Prophenpyxldamlne  maleate). 
2-Methyl-9-phenyl-2,3,'i,9-tetrahydro-l- 

pyrldindene  t^drogen  tartrate. 
N-(l-Pyrrolidyl  )ethylphenothiazine  hydrochloride-- 

Antipyrine  (1,5 -Dimethyl -2 -phenyl-3-pyrazolone ) 

^-Barbituric  acid 

»Barbituric  acid  derivatives: 

5-Allyl-5-sec-butylbarbituric  acid 

5-Allyl-5-(2-cyclopenten-l-yl)barbituric  acid 
and  salt  (Cyclopal). 

5-Allyl-5-isobutylbarbituric  acid  and  salt 

5-Allyl-5-isopropylbarbituric  acid   (Alurate) 

»5-Allyl-5-(l-methylbutyl)barbituric  acid  (Seco- 
barbital) and  salt. 
5-Allyl-5-phenylbarbiturlc  acid  and  salt 
(Alphenal ) . 

5-n-Butyl-5-ethylbarbituric  acid   (Neonal) 

»5-sec-Butyl-5-ethylbarbituric  acid 

5-sec-Butyl-5-ethylbarbituric  acid,  sodium  salt--- 
5-(l-Cyclohexen-l-yl )-l, 5-dimethylbarbituric 

acid   (Evipal). 
5-(l-Cyclohexen-l-yl  )-l, 5-dlmethylbarbiturio 

acid,   sodium  salt. 
5-(l-Cyclohe5cen-l-yl)-5-ethylbarbituric  acid  and 
salt. 

5,5-Diallylbarbituric  acid   (Dial) 

»5,5-Diettyrlbarbituric  acid   (Barbital) 

5,5-Dlethylbarbituric  acid,   sodium  salt 

5-Ethyl-5-isoamylbarbituric  acid  and  salt 
(Amytal). 

5-Ethyl-5-isopropylbarbituric  acid  and  salt 

5-Ethyl-5-(l-methyl-l-butenyl)barbituric  acid 
(Delvinal). 
»5-£thyl-5- ( 1 -methyl -n-butyl )barbituric  ac id 
( Pentob  arb  i  tal ) . 
5-Ethyl-5- (1-methyl -n-butyl )barbituric  acid, 

sodium  salt. 
5-Ethyl-5-(l-methyl -n-butyl  )-2-thiobarbiturlo 

acid  and  salt   (Pentothal). 
5-Ethyl-l-methyl-5-phenylbarbituric  acid  (Mepho- 
barbltal) . 
»5-Ethyl-5-phenylbarbiturlc  acid   (Phenobarbital) 
^Luminal ). 

5-Ethyl-5-phenylbarbituric  acid,   calcium  salt 

«5-Ethyl-5-phenylbarbituric  acid,   sodium  salt 

5-[2-(Methylthio)-ethyl]-5-(l-methylbutyl)-2- 
thiobarbituric  acid. 

Barium  inosinate 

l-Benzamido-l-phenyl-3-piperidinopropane 

(Digammacaine)  base  and  hydrochloride. 
N-Benzhydryl-N'-methylpiperazine  (Cyclizine)  base 

and  hydrochloride. 
N-Benzoyl  ethyl-piperidine  oxime  and  hydrochloride-- 
2-Benzyl-2-imida2oline  (Tolazoline)  hydrochloride--- 
»Bile  acids  and  salts: 

Bilirubin --- ■ 

Bilron 

Cholic  acid 

»Dehydrocholic  acid 

Del^drocholic  acid,   sodium  salt 

»Desoxyoholic  acid 


560. 
361. 

221,  ^56. 


221,   3A8,   Ait. 

59-;. 

551. 

551. 

A5A. 

283. 

252. 

330,   456. 

SAS. 

AS9. 

375,    489. 

37,   454. 

29,    266,   414,    422, 

489. 

489. 

456. 

29,    375,   456,   489. 

29,    266,    456,    489. 

266,   348. 

348. 

348. 

489. 

422,   456,   489. 

456,   489. 

266,   422,   489. 

456. 

X. 

29,   266,   456,    489. 

266,    375,   456,   489 

456. 

348. 

266,    330,    348,   456 

489,    564 

266. 

266,    346,   489,    564 

551. 

175. 

422. 

238. 

422. 

231. 

166,   477. 

422. 

97,    166,   308. 

97,    166,   308,    511, 

560. 

308. 

97,   166,   308,   348, 

474,    511. 

112 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  ITS.  '-Synthetic  organic  chemicals:   HfeHicin 
were   reported,    icient i fieti  by 


lis    fnr  which  United  States   production  or    sale 
lanufacturer ,    i95«- -Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


MEDICINALS,  CYCLIC- -Continued 


Ali 


nd  Hete 


rIic--Continued 


"Bile  acids  and  salts — Continued 

»Ketocholanio  acids 

Mixed  oxidized  bile  acids 

*Bromocainphor,  mono 

'i-N-(Butoxy)phenyl-4-morpholinyl  propyl  ether 

hydrochloride. 
a-Butyloxycinchoninic  acid  diethylethylenedlamide 

and  hydrochloride  (Nupercaine) . 

♦Caffeine,  natural ■>'-■ 

"Caffeine,  synthetic 

Caffeine,  derivatives,  natural  and  synthetic: 

Caffeine  citrate 

Caffeine  sodium  benzoate 

Camphor,  synthetic,  U.S.P 

"Camphoric  acid 

•Camphoric  anhydride 

Camphosulfonic  acid 

Camphosulfonic  acid  salts: 

Calcium  camphosulfonate 

Sodium  camphosulfonate 

N-[3-(Carboxymethylmercaptomercuri  )-2-iiiethoxy- 

propyl]-a-cajnphorainate,   disodium  salt. 

Cellulose,   oxidized 

Chlorisondamine   (Ecolid)  chloride 

7-Chloro-<i-(4-diethylamlno-l-methylbutylamino)- 

quinoline   (Aralen). 
»5-Chloro-7-lodo-8-quinolinol   ( lodochlorohydroxy- 

quinoline ) . 
'4-[3-(2-Chlor-10-phenothiazyl)-propyl]  -l-(2- 

hydroxyethyl ) -piperazine . 

P-Cholesterol 

Cinchophen  (2-Phenylquinoline-'i-carboxylic  acid) — 
Cinchophen  (2-Phenylquinoline-<i-carboxylio  acid) 

hydroiodide. 

Cinchophen,  sodium  salt 

Cocarboxylase 

Coenzyme  A 

Co  rami,  ne  (Nikethamide  ) 

Cozymase 

1,4-Cyclohexanedione 

a-Cyclohexyl-a-phenyl-1-piperidinepropanol 

a-Cyclohexyl-a-phenyl-l-pyrrolidinepropanol 

methylchloride . 

Cyclopentanol 

Cyclopentyl  bromide 

l-Cyclopentyl-2-methylpropylamlne  (Cyclopentamine) 

hydrochloride. 

Cytidine  and  cytidine  sulfate 

Cytidylic  acid 

Cytosine 

Desoxyribonucleic  acid 

Dextran  (Glucopyranose  anhydride) 

2,<<-Diamlno-5-(p-chlorophenyl)-6-ethylpyrimidine--- 

2,6-Diamino-3-phenylazopyridine 

d,3,4(l',3'-Dlbenzyl-2'-keto-imidazolido)-l,2- 

trimethylene  thiophanium  d-camphorsulfonate. 

i,7-Dichloroquinoline 

Diethylaminocarbethoxybioyclohexyl  (Dicyclomine) 

hydrochloride  (Bentyl  hydrochloride). 
6-(2-Diethylamlnoethoxy)-2-dimethylaminobenzo- 

thiazole  hydrochloride. 
l-Diethylcarbamyl-'i-methylpiperazine  dihydrogen 

citrate  (Hetrazan). 

3,3-Diethyl-2,'i-dioxopiperidine 

3,3-Diethyl-5-methyl-2,'^-piperidinedione 

N,N-Diethylpicolinamide  (Pyridlne-p-carboxylic 

acid,  diethylamide). 

"Dihydrocodeinone  bi tartrate 

Dihydrohydroxycodeinone  hydrochloride 

3,5-Dilodo-N-methyl-'+-pyridone-2,6-dicarboxylic 

acid. 
3,5-Diiodo-<i-pyridone-N-acetio  acid,  diethanol- 

amlne. 

»5,7-Diiodo-8-quinolinol ■ 

1,'i-Dimethanesulfonoxybutane  (Myleran) 

6,7-Dimethoxy-l-('«-ethoxy-3-methoxyben2yl  )-3- 

methylquinoline  phosphate  (Dioxyline  phosphate). 


207,    291, 

308,    348,    511 

166,    291. 

252,   <i69, 

564. 

456. 

543. 

221,    271, 

350. 

221,    306. 

306,    560, 

564. 

489,    560, 

564. 

253,    369. 

37,    364, 

508. 

37,   364. 

37. 

37,    364. 

37,    364. 

594. 

443. 

543. 

34S. 

37,    205, 

240,    543. 

551. 

166. 

537. 

422. 

537. 

175. 

470. 

37,    543. 

175,   470. 

506. 

537. 

422. 

422. 

422. 

422. 

175,    470 

175. 

175,    330 

588. 

112,   336. 

238. 

29,   361. 

454. 

407. 

335. 

454. 
454. 
321. 

291,  442,  564. 

291. 

551. 


37,  205,  207,  240. 

238. 

422. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


113 


TABLE   ITB.-Syntheti 


r^anic  chemicals:   KetiicinaJa   for  which  United  States  prorlucti 
reported,    identified  by  manufacturer ,    1956- -Continued 


Manufacturers'   identification  nurabere 
(according  to  Hat  in  table  27) 


MEDICINALS,   CYCIJC--Contlnued 


AUcycU 


nd  Hett 


:lic--Contlr 


p,a-DlJn^thylbenzyl  camphorate,   dlethanolamlne 

salt. 
p,o-Dlmethylbenzyl  oamphorate,   N-ethyl-3,3'- 

diphenyldipropylamlne  salt. 
N, g-Dimethylcyclohexane -ethylnml ne  (1-Cyclohexyl- 

2-methylamlnoprcpane ). 
l,3-Dlaiethyl-'i-phenyl-'i-proplonoxypiperidlne 

hydrochloride   (dl  a  form). 
N,  N-Dimethyl-'i-piperidylldene-l,  l-dlphenylmethane 
methyl  sulfate   (Diphenmethanil  methyl  sulfate). 
Diothane   (Piperldlnepropanediol  dlpheny lure thane) 
base. 

Diothane  hydrochloride 

5,5-Dlphenylhydantoin 

»5,5-Diphenylhydantoin,   sodium  salt 

Epoxytropine-tropate  methylbromlde 

5-Ethyl-3,5-dlmethyl-2,'l-oxazolidinedione 

Ethyl  l-methyl-4-phenylisonlpecotate   (Demerol) 

3-Ethyl-5-phenylhydantoin 

N-Ethyl-3-piperidyl  benzllate  metho  bromide 

N-Ethyl-3-piperidyl  diphenylacetate  hydrochloride- 

Ethynyl  cyclohexyl  carbamate   (Valmid) 

Fructose   (Levulose ) 

Fructose-l,6-dlphosphate,   dlcalcium  salt 

Fructose-6-phosphate,  barium  salt 

Furfuryl  methyl  ether 

Galactose 

Glucose-6-phosphate,  barium  salt 

Glucose-1-phosphate,  potassium  salt 

Glucuronolactone 

Guanine 

Guanine  hydrochloride 

Guanine  sulfate 

Guanos ine 

Guanylic  acid,  sodium  salt 

Hexamethylenetetramine 

Hexamethylenetetramine  aoetamlnosalicylio  acid 

(Sallhexln). 
Hexamethylenetetramine  anhydromethylene  citrate 
(Helmitol). 

Hexamethylenetetramine  mandelate 

Hexamethylenetetramine  sulfosalicylate 

Hexamethylenetetramine  tetraiodide 

Hexokinase 

Hexosediphosphorlc  acid  salts: 

Barium  hexosediphosphate 

Calcium  hexosediphosphate 

Magnesium  hexosediphosphate 

•Hormones  (steroid): 

Adrenocorticotropic  hormone  (ACTH) 

l,A-Androstadienedione 

Dehydroisoandrosterone 

Estradiol  17-cyclopentylpropionate 

Estrogenic  substance 

Estrone 

9-a-Fluorohydrocorti3one 

9-a-Fluorohydrocort,isone  acetate 

•Hydrocortisone  alcohol  and  acetate 

Hydrocortisone  cyclopentylpropionate 

Hydrocortisone  diethylamlnoaoetate  hydro- 
chloride. 

Hydrocortisone,  sodium  succinate 

»17-Hydroxy-ll-dehydrocortlcosterone  (Cortisone ) 
and  acetate. 

21-Hydroxypregnanedione,  sodium  succinate ■ 

Methylandrostenedlal 

Methyltestosterone 

Piperazine  estrone  sulfate 

•Prednisolone 

Prednisolone  alcohol  and  acetate 

Prednisone  ( l-Dehydrocortlsone  ) 

Prednisone  alcohol  and  acetate 

5,16-Pregnadiene-3-(P)-ol-20-one-acetate  oxime- 

16,17-epoxy-5-Pregnenolone  acetate 

Progesterone 

Reichsteins  substance  S  acetate 

Reichsteins  substance  S  alcohol 

Testosterone 

19-nDr-Testosterone  17-benzoate 


231. 
231. 
396. 

551. 


115, 

297. 

-iU, 

489. 

29, 

37,  414,  489,  490 

283. 

4.56. 

348. 

456. 

137. 

U7. 

422. 

360. 

175. 

175. 

297. 

360. 

175. 

175, 

588. 

476. 

175. 

175, 

477, 

588. 

175. 

175, 

470. 

175. 

504. 

456. 

37, 

348. 

86, 

361. 

218. 

37. 

470. 

175. 

175. 

175. 

166, 

283, 

407. 

174. 

174. 

283. 

498. 

407. 

374, 

560. 

283. 

283, 

306, 

560. 

283. 

306. 

283. 

283, 

551, 

560. 

306. 

174, 

543. 

174, 

543. 

456. 

306, 

551, 

560. 

283. 

551, 

560. 

283. 

174. 

174 

174 

407, 

X. 

559 

559 

174 

543. 

498 

114 


UNITED  STATES  TARIFF  COMMISSION 


-Synthetic  organic  chemicals:   Kedicinala   for  vhich  United  States  proHu 
were  reported,    identified  hy  manufacturer ,    1956- -Continued 


Manufacturers'  Identification  numbers 
(according  to  list  in  table  27) 


MEDICINALS,  CYCLIC—Continued 


All 


n</  Hett 


-Continued 


•Hormones  (steroid  )--Continued 

Testosterone  cyclopentylpropionate 

Testosterone  propionate 

1-Hydrazlnonaphthalazine  hydrochiorlde 

8-Hydroxy-7-iodo-5-quinolinesulfonic  acid  (Yatren 
acid  and  salt. 

Hydroxy-i-methylmeroaptobutyric  acid 

3-Hydroxy-l-methylpyTidinlum  bromide  dimethyl 
carbamate. 

8-Hydroxy-5-quinolinesulfonlc  acid 

Hypoxanthlne 

lodoantlpyrlne ■ 

Isonicotinic  acid  hydrazlde 

N^-Isonlcotinoyl-N^-sallcylldene  hydrazine 

I^sidlne  bl tartrate 

Maltose 

Menthyl  salicylate 

homo-Menthyl  salicylate 

6-Mercaptopurine 

p-Methoxy-y-hydroxymercurlc  propylamlde  of  cam- 
phoric acid  (Mercurial  acid). 
P-Methoxy-y-hydroxymercurlc  propylamlde  of  cam- 
phoric acid,  sodium  salt  with  theophylline 
(Mercupurin). 
8-(2'-Methoxy-3-hydroxymercurl )propylooumarin- 
3-carboxyllc  acid  (Mercumallyllc  acid). 

Methoxyoximerouripropylsuccinyl  urea 

Methylcholanthrene 

3,3'-Methylenebls  [4-hydroxyooumarin]    (Dioumarol)-- 

«Methyl  nlcotinate 

N-Methyl-3-plperldylbenzilatemethobromide 

N-Methylpiperldyl-3-methylphenothlazine  hydro- 
chloride hydrate. 

3-(2-Methyl-l-piperidyl)propyl  alcohol 

3-(2-Methyl-l-piperidyl)propyl  benzoate 

(Metycalne ) . 
3- (2-Methyl-l-piperidyl )propyl  p-cyclohexyl- 
oxybenzoate . 

Methyl thlouracll 

l-Methyl-2-undeoyl-3-benzyl  Imidazolium  bromide 

l-Methyl-2-undecyl-3-benzyl  Imidazolium  chloride-- 

l-Methyl-2-undecylimidazole 

Methyluracil 

Myristyl-Y-picolinium  chloride   (CJuatresln) 

2-(l-Naphthylmethyl)-2-imldazoline   (Privlne) 

hydrochloride. 
Neocinchophen  (Ethyl  6-methyl-2-phenylcinchoni- 
nate ) . 

5-Nitro-2-furaldehyde  diacetate 

5-Nitro-2-furaldehyde  semicarbazone  (Furacln) 

5-Nitro-2-furfurylidene-l-amlnohydantoin 

(Furadantin). 
N-(5-Nltro-2- furfurylidene) -3-amino-2-oxazolidene- 

5-Nitro-2-furfuryl  methyl  ether ■ 

Novalgln  (l-Phenyl-2, 3 -dimethyl -A-methylamlno-5- 
pyrazolone  formaldehyde  bisulfite). 

Nucleic  acid 

Nucleic  acid  salts 

Pamaquine  (Plasmochin)  (N-Diethylaminolsopentyl- 
8-amlno-6-methoxyquinoline ) . 

Papaverine  hydrochloride,  synthetic 

Perparin  base 

Perparin  hydrochloride 

Phenothlazine 

Phytic  acid 

Phytic  acid,  calcium  salt 

*Piperazine,  hexahydrate 

»Plperazlne  derivatives: 

N-Carbethoxypiperazlne 

N- (P -Cyclohexyl-P -hydroxy-P -phenyl )ethyl-N' - 

methylplperazine  methosulf ate . 
N-(  |3,  p-Dlphenyl-P-hydroxy  )ethyl-N'-methylpip- 
erazine  dihydrochlorlde. 

N-Methyl-N-carbethoxypiperazine 

Methyl-N-methyl-N-piperazine  acetate 

Plperazine  adipate 

Piperazine  ammonium  chloride 

Plperazine  calcium  ethylenediamine  acetate 


283. 
IV-i,  543. 

37,  205,  240. 

253. 
454. 

205,  240. 

175,  588. 

564. 

361,  374. 

361. 

365. 

360. 

365. 

365. 

238. 

364. 

364,  594. 


291. 

137. 

477. 

456,  537. 

37,  86,  321,  361,  365. 

137. 

361. 

422. 
422. 

422. 

175,  588. 

422. 

422. 

422. 

175,  588. 

283. 

543. 

537. 

297. 
297. 
297. 

297. 
297. 
86,  348. 

175. 
175. 
348. 


422, 
365. 
365, 
148, 
496. 
476, 
37,  ! 


375. 

252,  253,  256. 


496. 

16,  365,  405,  456,  529,  580. 


456. 
456. 

456. 

456. 

456. 

37,  86,  365. 

365. 

291. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


115 


-Synthetic  organic  chemicals:   Medicinals   for  which  United  States  pr 
were  reported,    identified  by  manufacturer,    J956- -Continued 


Manufacturers'  Identification  numbers 
(according  to  list  in  table  27) 


MEDICINALS,  CYCLIC--Continued 


Ali 


nd  Hctt 


-Continued 


»Pipera2ine  derivatives — Continued 

Piperazine  chloride 

»Piperazine  citrate 

Piperazine  dihydrochloride 

Piperazine  dihydroiodide 

Piperazine  hydrochloride 

Piperazine  phosphate 

»Piperazine  tartrate 

sym-N-Tetramethylpiperaizine  diiodide 

o-(2-Piperidyl)benzhydrol  hydrochloride 

a-('i-Piperidyl  jbenzhydrol  hydrochloride 

6-Propyl-2-thiouracil 

P-Pyridyl-carbinol  and  tartrate 

Quinacrine  (Atebrln)  (2-Methoxy-6-chloro-9- 

diethylaminopentylaminoacridine ) . 
8-Qulnolinol  (8-Hydroxyquinoline)  salts  and  esters: 

8-Quinolinol  base 

8-CJuinolinol  benzoate 

8-Quinolinol  citrate 

8-Quinolinol  hydrochloride 

8-Quinolinol  sulfate  (Quinosol) 

8-CJuinolinol  sulfate,  magnesium  salt 

8-Quinolinol  sulfate,  potassium  salt 

8-Qulnolinol  sulfate,  zinc  salt 

8-Qainolinol-5-sulfonic  acid 

Rutin 

Terpinol  hydrate 

'i,5,6,7-Tetrachloro-2-(2-dlmethylaminoethyl)- 
isoindoline  dimethiodide. 

Theobromine,  natural 

Theobromine  derivatives: 

Theobromine  calcium  gluconate 

Theobromine  calcium  salicylate 

Theobromine  salicylate . 

Theobromine  sodium  acetate 

♦Theobromine  sodium  salicylate 

•Theophylline  ( 1,3 -Dime thy Ixanthine)  base  and 
derivatives : 

p -Hydroxypropyltheophylline 

Theophylline  base 

Theophylline  cholinate 

Theophylline  ethylenediamine  (Aminophylline) 

Theophylline  ethylenediamine,  sodium  biphosphate-- 

Theophylline  magnesium 

Theophylline  methoxyoximercuripropylsueolnylurea— 

Theophylline  sodium  acetate 

2-Thiouracil 

Thymidine 

•Tranquillizers  (including  benzenoid): 

l-p-Chlorobenzhydrol-'i-[  2-(2-hydroxyethoxy ) 

ethyl] -piperazine  (Hydroxyzine)  dihydrochloride 
2-Chloro-10-(3-dimethylaminopropyl)phenothiazine 
(Chlorpromazlne)  hydrochloride. 

2-(p-Chlorophenyl)-3-methyl-2,3-butanediol 

10- (Y-Dimethylamlnopropyl )phenothiazine 

( Promazine )  hydrochloride . 
a-(<i-Plperidyl)benzhydrol  (Azocyclonol)  hydro- 
chloride. 

3,5,5-Trimethyl-2,4-oxazolidinedione  (Tridione) 

Tropine  benzhydryl  ether  methanesulfonate 

Uracil 

Uric  acid 

Uridine — - 

Uridine  triphosphate 

Uridylic  acid 

•Vitamins : 

•A,  from  all  sources: 

A  acetate 

A  acetate  (feed  grade) 

A  alcohol 

A  esters  (natural) 

A  palmltate 

A  palmitate  (feed  supplement) 

P-Carotene 

•Bi  (Thiamin  hydrochloride) 

•Bi  (Thiamin  nitrate) 


37, 

86,    205,    238,    365,   374,   489 

205. 

580. 

37. 

37, 

86,    238,    580. 

37, 

86,   365,   489. 

37. 

115. 

115. 

537. 

A5A. 

3A8. 

240, 

459. 

205, 

240, 

459. 

205, 

240, 

459. 

240. 

205, 

240, 

459. 

218. 

205. 

459. 

459. 

205, 

469. 

205, 

469. 

543. 

221, 

271. 

511. 

29. 

560. 

560, 

564. 

442, 

560, 

564. 

489. 

266, 

306, 

489,    564. 

361. 

3,   205,    207,    266,    306,   489,    560 

442. 

564. 

137. 

489, 

564. 

537. 

175. 

306. 

396. 

422. 

594. 

335. 

456. 

560. 

175, 

477, 

588. 

360, 

X. 

175, 

470. 

470. 

175. 

306, 

454, 

477,    519,    560. 

306. 

428, 

519, 

560. 

477. 

306, 

454, 

477,    560. 

306, 

454. 

454. 

306, 

454, 

537,    560. 

306, 

454, 

537,    560. 

116 


UNITED  STATES  TARIFF  COMMISSION 


TABLE   1TB. --Synthetic  organic  chemicals:   Hedicin 
were  reported,    identified  by 


for  which  United  States  product i 
jfacturer ,    /956- -Continued 


Manufacturers'   identification  numbers 
(according  to  list  in  table  27) 


MEDICINALS,    CYCLIC--Continued 

AlicycUc    and  Htterocyc  lie- -Continued 

^Vitamins- -Continued 

•  (Riboflavin  for  human  consumption)  (lOO'J) 

(Riboflavin  for  animal  and  poultry  consumption] 
(lOOfc). 

Riboflavin-5'-phosphate,  monosodium  salt 

»B6  (Pyridoxine) 

»Bi2,  IW: 

Feed  grade 

Pharmaceutical  quality 

U.S. P.  Crystalline 

»D2  (Irradiated  ergosterol )  (Calciferol) 

»D3  (Irradiated  animal  sterol)  (Delsterol) 

E  (o-Tocopherol) 

E  (a-Tocopherol  acetate) 

Biotin 

Folic  acid 

Inositol 

•Nicotinamide  (Niacinamide) 

Nicotinamide  hydrobromide 

•Nicotinamide  hydrochloride 

•Nicotinic  acid  (Niacin)- 

Nicotinic  acid,  iron  salt 

Unidentified  growth  factor  (animal  feed) 

Xanthine 

Xanthine,  monosodium  salt 

Xylose 

MEDICINAI^,  ACYCLIC 

Acetylcarbromal  (l-Acetyl-3-(2-bromo-2-ethyl- 
butyryl)urea). 

Acetylcholine  bromide 

Acetylcholine  chloride 

S-Aoetylglutathlone 

Acetylmethionlne 

Acetyl-p-methylchollne  chloride 

•Amino  acids : 

d- Alanine 

dl-Alanine  (dl-a-Alanlne ) 

1-Alanine 

•p-Alanine 

l(  +  )-Arginine 

l(+)-Arginine  hydrochloride 

dl-Asparagine  monohydrate 

dl-Aspartic  acid 

l(+)-Aspartic  acid 

1-Cltrulllne 

1-Cysteine 

l(+.)-Cysteine  hydroghloride 

Glutamic  acid  and  salts: 

•l(+)-Glutamic  acid 

l(+)-Glutamic  acid,  calcium  salt 

l(+)-Glutamlc  acid  hydrochloride 

l(+)-Glutamic  acid,  monoammonium  salt 

l(+)-Glutamic  acid,  monopotassium  salt 

l(  +  )-Glutamine .. 

Glycine  (Amlnoacetic  acid) 

Glycine  hydroiodide 

dl-Ieoleucine 

1-Isoleucine 

dl-Leucine 

1-Leucine 

dl-I^sine  hydrochloride 

1(+) -lysine  hydrochloride 

d-Methionlne 

dl-Methionlne 

1-Methionlne 

Methionine,  feed  grade 

dl-Norleuolne 

1-Omi thine  hydrochloride 

dl-Serine 

dl-Threonine 

d-Valine- ■ 

dl -Valine 

1-Valine -- • 

Amino  acid  mixtures 

2-Amlno-4-methylhexane 


306,  366,  454,  560. 

306,  336,  366,  -iVO,  537,  560. 


454. 

374,  454,  537,  560. 


264, 

560. 

560. 

121, 

121, 

454. 

454. 

454. 

283, 

476, 

226, 

361. 

361. 

39, 

86. 

306. 

175, 

175. 

360. 


375. 


306,  336,  366,  422,  470,  537,  560. 


226,  328,  348,  362,  407,  428,  527. 
348,.  362,  428,  527. 


537. 
496. 
361,  456. 


245,  435,  527,  558,  560. 
588. 


477. 

37,  560. 

175. 

145,  157,  252. 

560,  580. 

175. 

252. 

175. 

456,  515,  527,  560. 

55. 

55,  578. 

55. 

55,  360,  506. 

360. 

175. 

55. 

413. 

110,  328,  379,  496. 

205. 

110,  205,  328. 

328. 

110. 

110. 

252,  266. 

86. 

560. 

175,  252,  358. 

252,  348. 

55,  496,  560. 
252. 

253,  560. 
175. 

252,  253. 
175. 
253. 

360,  560. 
175. 
560. 

348,  360. 
175. 

252,  360,  560. 
175. 

467,  496. 
422. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


117 


TAJl-E  17B. --Synthetic  organic  chemicals:    Medicinals    for   which  United  States  production  or   sales 
were  reported,    identified  by  manufacturer ,    1956- -Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


MEDICINALS,  ACYCLIC--Continued 


Amyl  nitrite  (Isoanyl  nitrite) 

Auro-thioglucose 

a,a'-A2obls(ohloroformainldine)  (Azochlorajnide ) 

»Betaine  base 

Betaine  hydrate 

»Betaine  hydrochloride 

Betaine  hydroiodide 

Bromoform  (Tribromome thane) 

Bromural  (a-Bromoisovalerylurea) 

Caoodylic  acid  derivatives: 

Iron  cacodylate 

Sodium  cacodylate 

Calcium  borogluconate 

Calcium  bromolactobionate 

Calcium  iodobehenate 

Calcium  lactophosphate 

Calcium  levulinate 

Calcium  succinate 

Carbaminol  choline  chloride 

Carbaiiiyl-2-hydroxypropyltrimethylammonium  chloride- - 

Carbromal  (Bromodiethylacetylcarbamide ) 

Chloral  hydrate 

•Chloretone  (tert-Trichlorobutyl  alcohol) 

3-Chloro-l-diethyl-2-propyn-l-ol  (Diethylchloro- 
ethynyl  carbinol). 

3-Chloromercuri-2-methoxypropylurea 

P-Chlorovinylethylethynyl  carbinol 

"Choline  salts : 

Choline  bicarbonate 

♦Choline  bi tartrate 

♦Choline  chloride,  for  animal  and  poultry  feed 
and  for  use  as  an  intermediate. 

♦Choline  chloride,  medicinal  grade  only 

♦Choline  dihydrogen  citrate 

Choline  gluconate 

Choline  tricitrate 

Decamethonium  bromide 

Diallylacetic  acid 

Diallylacetic  acid,  bismuth  salt 

2,2-Diisopropyl-5-hydroxymethyl-l,3-dioxolane 

1,2-Dimeroaptopropanol 

2,3-Dlmercapto-l-propanol  (Dimercaprol) 

Dlsodium  methanearsonate  (Arrhenal) 

Dlvinyl  ether 

Ethyl  carbamate  (Urethane) 

Ethyl  chaulmoograte 

2-Ethyl-cis-crotonyl  urea 

Ethyl  iodide-- 

Ethylmercuric  chloride 

Ethyl  morrhuate 

Ethyl  nitrite 

♦Gluconic  acid  salts: 

Ammonium  gluconate 

Calcium  glucoheptonate 

Calcium  gluconate 

Cobalt  gluconate 

Copper  gluconate 

Iron  (ferrous)  gluconate 

Magnesium  gluconate 

Manganese  gluconate 

Potassium  gluconate 

Sodium  gluconate 

Zinc  gluconate 

Glucono-delta-lactone 

Glutathione 

Glutathione,  monosodium  salt 

Glutathione  (oxidized) 

Glutethamlde 

Glycerophosphoric  acid 

Glycerophosphoric  acid  derivatives: 

Calcium  glycerophosphate 

Iron  glycerophosphate 

Manganese  glycerophosphate 

Sodium  glycerophosphate 

Hendecenoic  acid  (Undecylenic  acid)  salts: 

Copper  hendecenoate 

Sodium  hendecenoate 

Zinc  hendecenoate 

Hexamethyldiaminoisopropanol  diiodide 


-177,  5W. 

551. 

511. 

86,  110,  555,  579. 

110. 

86,  110,  205,  555,  579. 

86. 

252. 

375. 


37,  ^07. 

37,  407. 

364. 

37,  86. 

364. 

564. 

86,  360. 

205,  469. 

560,  580. 

560. 

348,  375, 

414. 

560. 

266,  358, 

365,  407 

422. 

137. 

456. 

86,  435,  537,  555,  579. 

336,  362,  435,  527,  555,  566. 


\ 


86, 

537, 

555,  560,  579 

86, 

537, 

555,  579. 

86, 

555, 

579. 

238. 

231. 

231. 

375. 

335. 

579. 

39. 

560. 

157. 

364. 

375. 

560, 

580. 

422. 

364. 

564. 

306. 

360. 

306, 

564 

86. 

86, 

306. 

86, 

306. 

306 

86, 

306. 

306 

306 

362 

86. 

306 

175 

175 

175 

578 

504 

221 

474 

504. 

221 

504 

221 

504 

221 

504 

86. 

37,  348,  580. 


118 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  ITB. '•Synthetic   organic   chemicals:    Medicinals    for   which  United  States   producti 
were   reported,    identified  by  manufacturer,    1956- -Continued 


Manufacturers'  Identification  nunibera 
(according  to  list  in  table  27) 


MEDICINALS,  ACYCLIC- -Continued 

Hexamethylenebisttrimethylamnionluni  bitartrate] 

(Hexamethonium  bitartrate). 
Hexamethylenebis[  trlmethylammoniuin  bromide]  (Hexa- 
methonium bromide). 
Hexamethylenebis[trlmethylammonium  chloride] 
(Hexamethonium  chloride). 

2-Hydroxy-i-methylisobutyrlc  acid,  calcium  salt 

Iodized  castor  oil 

Iodized  oils 

Iodoform 

lodomethanesulfonic  acid,  sodium  salt 

Iron  (ferrous)  oxalate 

Lactic  acid  salts  (medicinal  grades  only) : 

Aluminum  lactate 

Iron  (ferrous)  lactate 

Potassium  lactate 

Sodium  lactate 

Magnesium  citrate 

Malononitrile 

Methylenecltrlc  acid  and  salts 

Methylene  Iodide 

1-Methylhexylamine  (2-Heptylamine) 

Methyl  iodide 

2-Methyl-2-propyl-l,3-propanediol 

Phosphoglyceric  acid 

2-Propylvaleric  acid,  bismuth  salt 

dl-Pyroglutamic  acid 

d-Rlbose 

Ribose-5-phosphate,  barium  salt 

Silver  protein,  mild 

Silver  protein,  strong 

Sodium  bismuth  triglycolamate 

Sodium  lodopropanol  sulfonate 

Sodium  morrhuate 

Sodium  pyruvate 

Sodium  succinate 

l-Sorbose 

Succinylchollne  dichlorlde 

Succinyl  peroxide 

Tartaric  acid,  medicinal  grade 

Tartaric  acid  salts,  medicinal  grades  only: 

Antimony  potassium  tartrate  (Tartar  emetic) 

Calcium  tartrate 

Potassium  bitartrate 

Potassium  sodium  tartrate  (Blsmosal) 

Sodium  tartrate 

Tetramethylammonlum  hydroxide 

Thiosemicarbazlde 

Thioslnamine  (Allylthiourea) 

♦Tranquillizers :  2-Methyl-2-n-propyl-l,3-propane- 
dlol  dloarbamate  ( Meprobamate )  (Equanll) 
(Mlltown). 

2,2,2-Trlbromoethanol 

Tricholine  citrate 

Triiodoethionic  acid 

»Vltamins ; 

•Ascorbic  acid  and  derivatives : 

»Asoorbic  acid 

Ascorbic  acid,  calcium  salt 

Ascorbic  acid,  sodium  salt 

Ascorbyl  palmltate 

♦Pantothenic  acid  and  derivatives: 

Pantothenic  acid 

♦Pantothenic  acid,  d-calcium  salt 

Pantothenic  acid,  dl-calclum  salt 

Pantothenic  acid,  sodium  salt 

d-Pantothenyl  alcohol  (a,Y-Dihydroxy-N- 
( 3 -hydroxypropy 1 ) -p , P -dime  thylbutyramlde ) . 


-190. 

221. 
365. 

207,  -^22. 
AA2,    564. 
348. 
86,  414. 


564. 

330,  459. 

348. 

348,  477,  560. 

422. 

477,  580. 

365. 

175. 

231. 

578. 

175. 

175. 

407. 

348. 

266. 

365. 

364. 

175. 

205,  442,  560. 

306. 

238. 

365. 

306. 

306. 


189, 
189, 

306. 
306. 

580. 
37, 
365. 
157, 

218. 
330, 

335, 

365, 

X. 

348. 
537. 
551. 

306, 
306. 
306, 
306. 

454, 
454, 

560. 
560. 

560. 
362, 
226, 

407. 
454. 

407, 
422, 

422, 
435, 

527, 
456, 

537, 
527, 

555, 
537, 

560 
555 

SYNTHETIC  ORGANIC  CHEMICALS,  1956 

Flavor  and  Perfume  Materials 


119 


TABLE  18B.  --Synthetic  organic   chemicais:    Flavor   and  per  fume  materials    for  which  United  States    production    or 
sales  were  reported,    ident  i  tied  by  manufacturer ,    1956 

[Flavor  and  perfume  materials  for  which  separate  statistics  are  given  in  table  ISA  are  marked  below  with  an 
asterisk  {•);  those  not  so  marked  do  not  appear  in  table  ISA  because  the  reported  data  are  accepted  in 
confidence  and  may  not  be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from 
table  27.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification 
number  with  the  designated  product] 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


FLAVOR  AND  PERFUME  MATERIALS,  CYCLIC 

Btnzenoid  and  Naphthaleno id 

2-Aoetonaphthone  (Methyl  p-naphthyl  ketone) 

Aoetophenone 

7-Acetyl-6-ethyl-l, 1,4, i-tetramethyl-l, 2,3,4- 
tetrahydronaphthalene . 

»a-Amylcinnamaldehyde 

a-Amylcinnamaldehyde,  dimethyl  acetal 

a-Amylcinnamyl  alcohol 

*Anethole 

Anlsaldehyde 

Anisole  (Methyl  phenyl  ether) 

Anisyl  acetate ^^ 

Anisyl  alcohol 

Anisyl  formate 

Anisyl  propionate 

»Benzophenone 

»Benzyl  acetate 

»Benzyl  alcohol 

•Benzyl  benzoate 

Benzyl  butyrate 

Benzyl  cinnamate 

Benzyl  ether 

Benzyl  formate 

Benzyl  isoamyl  ether 

Benzyl  isobutyrate 

Benzyl  isoeugenyl  ether 

Benzyl  isovalerate 

Benzyl  phenylacetate  (Benzyl  a-toluate) 

•Benzyl  propionate 

Benzyl  salicylate 

Benzyl  valerate 

a-Brcmostyrene 

■4-tert-Butyl-2,6-dimethyl-3,5-dinitroacetophenone 
(Mask  ketone) . 

5-tert-Butyl-<V,6-dinltrohemimellitene 

6-tert-Butyl-3-methyl-2,4-dinitroanisole   (Musk 

ambrette ) . 
5-tert-Butyl-2,4-,6-trinitro-m-xylene   (Musk  xylol)- 

Carvacrol  (Isopropyl-o-cresol) 

Cinnamaldehyde 

Cinnamic  acid 

Cinnamyl  acetate 

Cinnamyl  alcohol 

Cinnamyl  anthranilate 

Cinnamyl  butyrate 

Cinnamyl  cinnamate 

Cinnamyl  formate 

Cinnamyl  isobutyrate 

Cinnamyl  isovalerate 

Cinnamyl  propionate 

Cinnamyl  valerate 

Cumaldehyde  (p- Isopropylbenzaldehyde ) 

p,  a -Dimethylbenzyl  alcohol  (p-Methylphenylmethyl- 
carblnol). 

a ,  a -Dimethylphenethyl  acetate 

«,  a-Dimethylphenethyl  alcohol 

a,  a-Dimethyl-3-phenylpropanol 

'4,6-Dinitro-l,l,3,3,5-pentamethylindan 

Diphenylmethane 

l,3-Diphenyl-2-propanone  (Dibenzyl  ketone) 

2-Ethoxynaphthalene  (Ethyl  |3-naphthyl  ether) 

Ethyl  anlsate 

Ethyl  anthranilate 

Ethyl  benzoate 

Ethyl  cinnamate 

•Ethyl  a,P-epoxy-P-methylhydrocinnamate  (Ethyl 
methylphenylglycidate ) . 

2-Ethylhexyl  salicylate 

Ethyl  p-methoxycinnamate 

Ethyl  methyltolylglycidate 

Ethyl  P-phenylglycidate 

Ethyl  salicylate 

Ethylvanillin 

•Eugenol 


337 

,  353, 

402. 

337 

,  353, 

529, 

558. 

337 

332 

,  337, 

353, 

398, 

402,  472, 

402 

353 

,  398. 

130 

,  212, 

353, 

369, 

X. 

337 

,  353, 

365. 

337 

279 

337, 

353, 

402. 

337 

353, 

402. 

279 

337, 

353, 

402. 

353 

402. 

330 

337, 

353, 

402, 

459. 

337 

353, 

398, 

472, 

474. 

266 

303, 

337, 

353, 

398,  474. 

221 

303, 

332, 

337, 

474. 

279 

337, 

353, 

402, 

409,  472. 

279 

337, 

353, 

365, 

391,  398, 

337 

402. 

271 

279, 

337, 

353, 

402. 

337 

353, 

402. 

279 

337, 

353, 

402. 

337 

353, 

402. 

279 

337, 

353, 

402. 

271 

337, 

353, 

402. 

279 

332, 

337, 

353, 

402,  409. 

337 

353. 

279 

402, 

472. 

353 

337 

474. 

337 

337 

474. 

337 

474. 

337 

337 

353. 

266 

353. 

337 

353, 

402, 

409. 

337 

353, 

600. 

279 

402, 

472. 

279 

337, 

402. 

337 

353. 

337 

353, 

402. 

353 

402, 

472. 

279 

353, 

402. 

337 

353, 

402, 

409. 

337 

402, 

472. 

213 

337. 

337 

398 

398 

398 

337 

353 

337 

337 

353. 

337 

365, 

402. 

218 

402. 

337 

353, 

402. 

337 

353, 

402. 

213 

337, 

353, 

402, 

472. 

472 

337 

402 

213 

353, 

365, 

402, 

472. 

252 

353, 

365. 

221 

332, 

337, 

353, 

365, 

402,  409, 

120 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  lfm.--Syntheti 


organic   chemicals:    Flavor   and  per fim 
sales  were   reported,    identi  tied  by 


laterials  For   which  United  States  product i 
tfacturer,    1956- -Continued 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


FLAVOR  AND  PERFUME  MATERIALS,  CYCLIC— Continued 

Benienoid    and  Naphthalcnoid- -Continued 

Eugenyl  methyl  ether 

Eugeny 1  phenylacet ate 

Hexylolnnamaldehyde 

Hydratropaldehyde  (a-Phenylproplonaldehyde) 

Hydratropaldehyde,  dimethyl  acetal 

Hydrocinnamaldehyde  (p-Phenylpropionaldehyde) 

4- (<i-Hydroxy-3-methoxyphenyl) -3-buten-2-one 
(Vanlllidine  acetone). 

Isoamyl  benzoate  (Amyl  benzoate) '* 

Isoamyl  oinnamate  (Amyl  elnnamate) 

Isoamyl  phenylacetate  (Amyl  a-toluate) 

Isoamyl  salicylate  (Amyl  salicylate) 

Isobutyl  benzoate 

Isobutyl  elnnamate 

»Isobutyl  phenylacetate  (Isobutyl  a-toluate) 

Isobutyl  salicylate 

*Isoeugenol 

Isoeugenyl  acetate 

Isoeugenyl  methyl  ether 

p-Isopropyl-a-methylhydrocinnamaldehyde 
( Cyc lamen  aldehyde ) . 

*p-Methoxyacetophenone 

o-Methoxybenzaldehyde 

2-Methoxybiphenyl 

2-Methoxynaphthalene  (Methyl  P-naphthyl  ether) 

p-Methylacetophenone  (Methyl  p-tolyl  ketone) 

Methyl  anisate 

p-Methylanlsole  (p-Cresyl  methyl  ether) 

Methyl  anthranllate 

Methyl  benzoate 

a-Methylbenzyl  acetate 

p-Methylbenzyl  acetate 

a-Methylbenzyl  alcohol  (Methylphenyl  carbinol) 

a-Methylcinnamaldehyde 

Methyl  elnnamate 

Methyl  N-methylanthranilate  (Dimethyl  anthranllate) 
Methyl  phenylacetate  (Methyl  o-toluate) 

*Methyl  salicylate  (Synthetic  wlntergreen  oil) 

«Phenethyl  acetate 

•Phenethyl  alcohol 

Phenethyl  anthranllate 

Phenethyl  butyrate 

Phenethyl  elnnamate 

Phenethyl  formate 

Phenethyl  isobutyrate 

Phenethyl  isovalerate 

Phenethyl  phenylacetate  (Phenethyl  a-toluate) 

Phenethyl  propionate 

Phenethyl  salicylate 

Phenethyl  valerate 

2-Phenoxyethyl  isobutyrate 

Phenylacetaldehyde  (a-Tolualdehyde) 

Phenylacetaldehyde,  dimethyl  acetal 

4-Phenyl-3-buten-2-one  (Benzylidene  acetone) 

l-Phenyl-2-propanone  (Benzyl  methyl  ketone) 

3-Phenyl-l-propyl  acetate 

»3-Phenyl-l-propyl  alcohol  (Hydrocinnamic  alcohol)--' 

Propyl  elnnamate 

Salicylaldehyde 

p-Tolualdehyde  (p-Methylbenzaldehyde) 

p-Tolyl  acetate  (p-Cresyl  acetate) 

p-Tolyl  isobutyrate  (p-Cresyl  isobutyrate) 

p-Tolyl  phenylacetate  (p-Cresyl  a-toluate) 

a-(Trichloromethyl)benzyl  acetate  (Rosetone) 

p- a,a-Trlmethylphenethyl  alcohol 

2,3,5-Trimethyl-l,2,3,6-tetrahydrobenzaldehyde 

Vanillin 

Terpenoid,    Heterocyclic,    and  AlicycUc 

Allyl  cyclohexanepropionate 

Allylionone 

Bomyl  acetate 

Oarvone  (Carvol) 

Caryophyllene 

Cedrenal 

Cedrol 

»Cedryl  acetate 


337 

353. 

332. 

353 

398. 

337 

353. 

337, 

353. 

337, 

353. 

i02. 

279, 

337, 

353, 

402. 

353, 

402. 

337, 

353, 

402, 

409. 

337, 

353, 

359. 

271, 

337, 

353, 

402. 

279, 

353, 

402. 

332, 

337, 

353, 

402. 

337, 

353, 

402. 

332, 

337, 

353, 

402,   474. 

337, 

353, 

402. 

337, 

353, 

365, 

402. 

213, 

337. 

337, 

353, 

365. 

«I9. 

337, 

398. 

337, 

353, 

402. 

337, 

353. 

365, 

402. 

337, 

353. 

252, 

337, 

474. 

337, 

365, 

504. 

332, 

337. 

365, 

402. 

353. 

213, 

337. 

337, 

353, 

365. 

337, 

402, 

472. 

337, 

353. 

221, 

252, 

492, 

504. 

337, 

398, 

402, 

456,   600. 

252, 

337, 

398, 

469,   600. 

218, 

337, 

402, 

472. 

271, 

337, 

353, 

402. 

353, 

398, 

402, 

472. 

337, 

353, 

398, 

402. 

271, 

337. 

337, 

353, 

402. 

337, 

353, 

402, 

472. 

337, 

353, 

402. 

337, 

353, 

398, 

402. 

402, 

472. 

337, 

353. 

337, 

353. 

337, 

353, 

402. 

353. 

353. 

337, 

353. 

337, 

353, 

459. 

402. 

252. 

337, 

504. 

337, 

353, 

398, 

402. 

353, 

398, 

402. 

337, 

353. 

365, 

398, 

402. 

398. 

393. 

221, 

271, 

282. 

402. 

337. 

402, 

472. 

402, 

409, 

469, 

525,    599,   600 

337. 

353. 

332, 

353, 

398. 

332, 

337, 

353, 

398,    600. 

SYNTHETIC  ORGANIC  CHEMICALS,  1956 


121 


TABLE   I8n.--!>yntheti 


sales  wi 


hemicflis;   Flavor  and  perfume  materials     for    which  United  States  product ic 
reported,    identified  by  manufacturer,    J956--Continued 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


FLAVOR  AND  PERFUME  MATERIALS,   CYCLIC— Continued 


T.rpe 


id,    Hcte 


and   Ali 


--Pontlnued 


Cineole   (Eucalyptol) 

»Citral    (Geranial) 

»Citronellal 

»Citronellol 

»Citronellyl  acetate 

Citronellyl  butyrate 

»Citronellyl  formate 

Citronellyl  propionate 

♦Coumarin 

Cyclohexanesulfamic  acid,   calcium  salt 

Cyclohexanesulf amic  acid,   sodium  salt 

Cyclopentanol 

Cyclopentanone 

Dihydrocitronellol 

3,7-Dimethyl-3-octanol   (Tetrahydrolinalool)- 

»Ethyl  oxyhydrate 

»(jeraniol 

»Geranyl  acetate 

Geranyl  benzoate 

Geranyl  butyrate 

*Geranyl  formate 

Geranyl  isovalerate 

Geranyl  phenylacetate  (Geraryl  a-toluate)-- 

Geranyl  propionate 

a-Heptyl-a-butyrolactone 

2-Hexyl-2-cyclopenten-l-one 

Hydroooumarin  ( 3 , i -Dihydrocoumarin ) 

»Hydroxycitronellal 

Hydroxycitronellal,  dimethyl  acetal 

Hydroxycitronellol 

Indole 

»Ionones : 

■xct-Ionone 

*P-Ionone 

*Ionone   (a-   and  P-) 

Isobomeol   (Isobomyl  alcohol) 

*Isobomyl  acetate 

Isobomyl  propionate 

Isobutylquinoline 

Isopropylquinoline 

Isopulegol 

Isosaf role 

d-Liinonene 

*Lin&lool 

»Linalyl  acetate 

Linalyl  anthranilate 

Linalyl  benzoate 

Linalyl  butyrate 

Linalyl  cinnamate 

Linalyl  formate 

Linalyl  isobutyrate 

Linalyl  isovalerate 

Linalyl  propionate 

*Menthol,  synthetic: 

Tech 

U.S.P 

Menthone 

Menthyl  acetate 

Menthyl  anthranilate 

Menthyl  isovalerate 

Metahomomenthol  (Cyclonol) 

Metahomomenthyl  acetate 

3-Methylcoumarin 

6-Methylcoumarin 

*Methylionones : 

Methyl-a-ionone 

Methyl-P-ionone 

Methylionones  (a-  and  P-) 

6-Me thy Iqu incline 

Nerol 

Neryl  acetate 

Nopyl  acetate 

Phellandrene 

»Piperonal  (Heliotropin) 

♦Rhodinol 

Rhodinol  rose 

Rhodinyl  acetate 

Rhodinyl  formate 


599. 

337, 
337, 
337, 
353, 
353, 
353, 
353, 
252, 
456. 


353, 
279, 
337, 
332, 
337, 
337, 
332, 
402, 
353, 
337, 


353,  402,  409,  423. 

353,  398,  402. 

353,  398,  402,  409,  474. 

398,  402. 

402. 

398,  402. 

398,  402. 

353,  600. 


398. 
365, 
353, 
337, 
402. 
353, 
337, 
472. 
402. 
353, 


391,  402,  423,  472. 

398,  402,  409,  474. 

353,  398,  402,  472,  600. 

402. 

353,  402,  409,  472,  600. 


402,  409. 


365. 

337,  353,  600. 

353,  402. 


337,  353,  398. 
337,  353,  600. 
332,  337,  353,  398,  402,  423,  600. 


353,  469,  X. 


398. 
398. 
337, 
353, 
402. 
337, 
353, 
332, 
337, 
353, 
353, 
337, 
337, 
402. 
353, 


353. 
469. 

353, 
398, 
402. 
402. 
402, 
402. 
353, 
353, 

402. 


398,  402,  409,  472,  474. 
402,  409,  423,  474,  600. 


402,  409. 
402. 


365,  369,  402,  474,  X. 
474,  600. 
337,  369,  X. 

402. 
402. 


337,  398. 

337,  353,  398. 

398,  402. 

402,  409. 
402. 

353,  469,  474. 

337,  353,  398,  402,  409,  423,  472,  474. 


353,  402,  409. 
337,  398,  402. 


122 


UNITED  STATES  TARIFF  COMMISSION 


TAHLF,   18B. --Synthetic 


organic    chemicals:   Flavor  and  per  fume  materials   for  which  United  States  product! 
sales  were  reported,    identified  by  manufacturer,    1956- -Continued 


Material 


FLAVOR  AND  PERFUME  MATERIALS,  CYCLIC— Continued 


Terpenoid.    Hete 


and   AlicycU 


Saccharin 

Saccharin,  calcium  salt 

Saccharin,  sodium  salt 

»Safrole 

Santalol 

Santalyl  acetate' 

Skatole 

»Terpineols: 

a-Terpineol 

P-Terpineol 

Teiplneol  (a-  and  P-) 

Terpinol  hydrate  (Terpin  hydrate),  tech- 

*Terpinyl  acetate 

*Terpinyl  propionate 

l,2,3,'>-Tetrahydro-6-methylquinoline 

Vetivenol 

»Vetivenyl  acetate 


FLAVOR  AND  PEHRJME  MAIERIAI£,   ACYCLIC 


»Allyl  caproate 

Allyl  enanthate   (Allyl  heptanoate) 

Allyl  isothiocyanate   (Synthetic  mustard  oil) 

Allyl  propionate 

Allyl  sulfide   (Diallyl  sulfide) 

2,3-Butanedione   (Biacetyl) 

n- Butyl  butyrate 

Butyl  butyryllactate 

Butyrone   (Di-n-propyl  ketone) 

Capraldehyde   (Decyl  aldehyde)    (Cio) 

Caprylaldehyde   (Octyl  aldehyde)    (Cb) 

Decyl  acetate 

n-Decyl  alcohol 

Diethyl  sebacate   (Ethyl  sebaoate) 

Diethyl  succinate 

Dime thy loctanol 

Dimethyl  succinate 

Dodeoyl  acetate   (Lauryl  acetate) 

Enanthaldehyde   (n-Hept aldehyde)    (C7) ■ 

»Ethyl  butyrate 

Ethyl  oaprate   (Ethyl  decylate) 

Ethyl  caproate   (Ethyl  hexoate) 

Ethyl  caprylate   (Ethyl  octoate) 

Ethyl  enanthate   (Ethyl  heptylate) 

Ethyl  isobutyrate 

Ethyl  isovalerate 

Ethyl  laurate 

Ethyl  levulinate 

Ethyl  myristate 

Ethyl  pelargonate 

Glutamic   acid,  monopotassium  salt 

^■Glutamic  acid,  monosodium  salt   (Monosodium 
glutamate) . 

Hendecanaldehyde   (Undecyl  aldehyde)    (Cn) 

2-Hendecanone   (Methyl  nonyl  ketone) 

Hendecenaldehyde   (Undecylenic  aldehyde) 

Hendeoenoic  acid   (Undecylenic   acid) 

Hendecenol   (Undecylenyl  alcohol) 

2,3-Heptanedlone   (Acetylvaleryl) 

Heptyl  alcohol   (Heptanol) 

2,3-Hexanedlone  (Acetylbutyral) 

3-Hydroxy-2-butanone   (Acetoin) 

y-Hydroxycaprylic  acid,   lactone   (y-Octalaotone) — 
"i-Hydroxyhendecanoic  acid,  y-lactone   (Y-Undeca- 

lactone) . 
Y-Hydroxypelargonic  acid,   lactone   (Y-Nonalactone)- 

»Isoamyl  butyrate   (Amyl  butyrate) 

Isoamyl  caproate   (Amyl  caproate) 

Isoamyl  caprylate   (Amyl  caprylate) 

«Isoamyl  formate   (Amyl  formate) 

Isoamyl  isovalerate   (Amyl  isovalerate) 

Isoamyl  propionate   (Amyl  propionate) 

Isobutyl  acetate 

Ispbutyl  butyrate 

Isobutyl  caproate 

Isobutyl  isovalerate 

Isopropyl  pelargonate 

Lauraldehyde   (Dodeoyl  aldehyde)    (C12) 


Manufacturers '   identification  numbers 
(according  to  list  in  table  27) 


221,   385. 

385. 

221,   385. 

337,   353,  409,  469,  482,    599. 

332,   337,   398. 

337. 

218. 

332,   369,   X. 

369. 

212,   337. 

212. 

332,    337,    353,   369. 

332,    337,    353,   472. 

353. 

332,    337,    353. 

332,    337,    353,    391,   398,   409,    600. 


279, 

353, 

365, 

402, 

402. 

266, 

279, 

365. 

353. 

337, 

337, 

353, 

337, 

218, 

218, 

108, 

365. 

353, 

96, 

91, 

353, 

353, 

353, 

353, 

353, 

353, 

337, 

218, 

402. 

337, 

204. 

110, 

337, 

353. 

337, 

96, 

337, 

353. 

96,  : 

218. 

218. 

337, 

337, 

337, 
337, 
353, 
353, 
337, 
353, 
279, 
279, 
279, 
353, 
279, 
402. 
337, 


337,  353,   365,   398,   402,  409,  472. 

365,  402. 

581. 

472. 

365,  402. 

353,  402,   472. 


353,   402. 
353,   402. 
402. 
353. 

353,  472. 
353,  529. 
213. 

402. 
353,   511. 
353,   402,   409. 

402,   409. 

402,   409. 

402,   409. 

402,   472. 

402. 

402,   409. 

353,   402,   409. 

337,   398. 

353,   365,   402,   472. 
204,   328,   379,   496. 


353. 
511. 
353. 


353,   402. 
353,   402. 


353, 
353, 
402, 
402, 
353, 
402, 
337, 
353, 
353, 
402. 
353, 


402. 

365,   402,   409,   472. 

472. 

409. 

402,   409. 

409. 

353,   402,   409,   472. 

402,   409,   529. 

402. 

402. 


353,   402. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


123 


TABLE  18B. --Synthetic 


ic  chemicals:   Flavor  anrl  perfume  material's   for  which  United  States  production  or 
were  reported,    identified  by  manufacturer ,   I956--Continued 


Manufacturers '   identification  nmnbers 
(according  to  list  In  table  27) 


FLAVOR  AND  PERFUME  MATERIALS,   ACYCLIC— Continued 

2-Methylhendecanaldehyde  ( 2-Methylnonylacet- 
aldehyde ) . 

Methyl  hendecanoate   (Methyl  undecylenate) 

6-Methyl-5-hepten-2-one 

Methyl  p -methylthiolpropionate 

Methyl  nonenoate  (Methyl  nonylenate) 

Methyl  octynoate  (Methyl  heptine  carbonate) 

Nonyl  alcohol  (C9) 

Octenoic  acid 

n-Octyl  acetate 

n-Octyl  formate 

n-Octyl  isobutyrate 

Pelargonaldehyde  (Nonyl  aldehyde)  (C9) 

2,3-Pentanedione 

2-Propene-l-thiol  (Allyl  mercaptan) 

n-Propyl  disulfide 

Propyl  propionate 

Tricaproin 

Trimethylhendecanaldehyde 

Valerolactone 

CHEMICALLY  MODIFIED  ESSENTIAL  OILS 

Citronella  oil,  acetone  condensate 

Citronella  oil,  acetylated 

Lavandin,  acetylated 

Petitgrain  oil,  acetylated 

Rosemary  oil,  acetylated 

Sassafras  oil,  hydrogenated 

Spike  lavender,  acetylated 


337, 

353, 

402. 

337, 

402. 

353. 

402. 

337, 

402, 

472. 

337. 

337, 

353. 

-«52. 

337, 

353, 

402. 

353, 

365, 

402. 

353, 

402. 

337, 

353. 

218. 

402. 

54. 

353, 

402. 

332. 

213. 

337. 

327. 

409. 

337, 

402, 

409,   472 

402, 

409. 

409. 

337. 

409. 

124 


UNITED  STATES  TARIFF  COMMISSION 

Plastics  and  Resin  Materials 


TA'ILF    ion.  --Synthetic  organic  chemicals:    Plastics   and  resin  materials    for   which  United  State 
sales  were  reported,    identified  by  manufacturer,    1956 


product i 


[plastics  and  resin  materials  for  which  separate  statistics  are  given  in  table  19A  are  marked  below  with  an 
asterisk  (*) ;  chemicals  not  so  marked  do  not  appear  in  table  19A  because  the  reported  data  are  accepted 
in  confidence  and  may  not  be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from 
table  27.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification 
number  with  the  designated  product] 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


PLASTICS  AND  RESIN  MATERIALS,  BENZENOID 

Aniline-formaldehyde  resins 

«Coumarone-indene  resins 

Epoxy  resins: 
^Unmodified:  Epichlorohydrin-phenol  and  bisphenol 
^Modified - 

»Petroleum  polymer  and  condensation  resins 

»Phenolio  and  other  tar-acid  resins: 
^Unmodified: 

•Bisphenol-formaldehyde 

»p-tert-Butylphenol-formaldehyde 

»Cresols-formaldehyde 

»Cresylia  acid-formaldehyde 

Phenol-cresols-formaldehyde 

»Phenol-formaldehyde 


»Phenol-furfural 

•Resoroinol- formaldehyde 

Xylenols-formaldehyde 

All  other 

•Modified: 

»Bisphenol-formaldehyde-rosin 

»p-tert-Butylphenol- formaldehyde-rosin 

Phenol-formaldehyde,  ammoniated 

•Phenol-formaldehyde-aniline 

•Phenol-formaldei^de-rosin 

Phenol-formaldehyde,  sulfonated 

41]  other 

•Phthalic  alkyd  resins: 
•Unmodified: 

•Phthalic  anhydride -glycerol 

•Phthalic  anhydride-glycerol-glycol 

Phthalic  anhydride-glycerol-glycol-penta- 

erythritol. 
•Phthalic  anhydride-glycerol-pentaerythritol — 

•Phthalic  anhydride-glycerol-sorbitol 

•Phthalic  anhydride-glycol-pentaerythritol 

•Phthalic  anhydride-pentaerythritol 

All  other 

•Modified: 

•Phthalic  anhydride-adlpic  acid-glycol 

•Phthalic  anhydride-benzoic  aoid-glycerol 

•Phthalic  anhydride-fumaric  acid-glyoerol 

Phthalic  anhydride-fumaric  acid-glycerol- 
pentaerythritol-tall  oil. 
•Phthalic  anhydride-fumaric  acid-glycerol-rosi 


577. 

152,  179,  256,  558. 

Ill,  478,  -^Sl,  583. 

80,  8/i,  158,  196,  199,  209,  232,  235,  241,  249,  346, 

464,  466,  485,  559. 
152,  214,  256,  284,  304,  528. 


24,  209,  322,  334,  438. 

41,  199,  255,  322,  334,  438,  466,  478,  485, 

558,  X. 

38,  135,  162,  209,  322,  417,  438,  466,  478,  553,  558, 

584. 
10,  38,  57,  135,  136,  183,  199,  322,  438,  478,  517, 

537,  591. 
209,  221,  591. 
4,  35,  38,  53,  57,  64,  68,  79,  83,  87,  109,  119,  123, 

125,  135,  136,  183,  198,  199,  209,  221,  249,  255, 

277,  295,  301,  322,  346,  397,  417,  421,  438,  466, 

473,  478,  517,  540,  553,  558,  559,  562,  566,  574, 

584,  591,  601. 
199,  478,  553. 

79,  221,  322,  367,  466,  478,  517,  553,  566. 
57,  478. 
10,  38,  164,  183,  220,  221,  235,  322,  347,  367,  438, 

471,  478,  591. 

41,  78,  212,  334,  349,  485,  558,  X. 

78,  109,  334,  4^1,  485,  558,  566,  X. 

466,  566. 

221,  466,  478,  517,  591. 

69,  212,  313,  322,  334,  346,  466,  473,  478,  537,  558, 

559,  566,  584. 
249,  334. 

126,  209,  249,  295,  322,  466,  478,  566,  584,  591. 


5,  13,  24,  25,  48,  59,  69,  75,  76,  78,  80,  82,  83,  84, 

109,  111,  158,  164,  173,  180,  185,  196,  199,  209, 

232,  235,  236,  253,  313,  319,  322,  334,  343,  346, 

349,  441,  464,  466,  473,  478,  485,  530,  537,  554, 

558,  559,  566,  591,  598. 

5,  13,  24,  25,  33,  111,  158,  209,  253,  334,  346,  473, 

485,  559,  591. 

346,  530. 

5,  13,  25,  48,  59,  69,  76,  80,  82,  84,  98,  158,  164, 

173,  180,  185,  199,  209,  232,  235,  253,  315,  317, 

334,  346,  389,  441,  464,  466,  473,  485,  530,  554, 

558,  559,  591. 

25,  48,  69,  158,  554,  558,  591. 

5,  25,  76,  80,  158,  180,  185,  209,  212,  235,  253, 

315,  334,  346,  347,  389,  406,  441,  466,  473,  485, 

537,  558,  559,  566,  591. 

5,  24,  25,  46,  48,  59,  69,  75,  76,  80,  83,  84,  111, 

158,  164,  173,  180,  185,  199,  209, '  212,  232,  235, 

236,  253,  313,  322,  334,  346,  349,  406,  441,  464, 

466,  473,  485,  530,  537,  548,  558,  566,  591,  X. 

69,  133,  235,  253,  464,  485,  537,  554,  566,  591. 

253,  334,  346,  537,  559,  591. 

24,  25,  164,  196,  209,  334,  346,  406,  466,  473,  559, 
591. 

25,  46,  80,  109,  196,  334,  464,  473,  485. 
46,  82,  196,  485. 

84,  209,  232,  235,  334,  485. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


125 


TABLE  19B.--Synt/ief jc  organic    chemicals:   Plastics  and  resin  materials   for    which  United  States  product! 
sales  were  reported,    identified  by  manufacturer ,   7956--Continued 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


PLASTICS  AND  RESIN  MATERIALS,  BENZENOID— Continued 

»Phtlialic  aliyd  resinB--Continued 
«Modlfied--Continued 

»Phthallo  anhydride-glyoerol-pentaerythrltol- 
phenol- f ormaldehyde-ros in . 

»Phthallo  anhydrlde-glycerol-pentaerythritol- 
rosln  and  tall  oil. 

•Phthalio  anhydride-glycerol-phenol- formalde- 
hyde. 

*Phthallo  anhydrlde-glyoerol-phenol-formalde- 
hyde-rosin. 

»Phthalic  anhydrlde-glyoerol-rosin 


»Phthalio  anhydride-maleic  anhydrlde-glyoerol 

*Phthalio  anhydride-maleic  anhydrlde-glyoerol 

pentaerythr itol . 
»Phthalic  anhydride-maleic  anhydride-glyoerol 

pentaerythritol-rosln. 
Phthalio  anhydride-maleic  anhydrlde-glyoerol 

phenol-formaldehyde-rosin. 
»Phthalio  anhydride-maleic  anhydride-glyoerol 

rosin. 
•Phthalio  anhydride-maleic  anhydride-penta- 

erythrltol. 
»Phthalic  anhydride-maleic  anhydrlde-penta- 

erythrltol-rosin  or  tall  oil. 
»Phthalic  anhydride-pentaerythritol-rosin  or 

tall  oil. 

All  other 

•Polyester  recins ; 

•Phthallc  anhydride-maleic  anhydrlde-glycol- 
styrene. 
All  other 

•Styrene  resins: 

•Polystyrene 

•Styrene-acrylonitrlle  copolymer 

•Styrene-alkyd  polyester  resins; 

•Phthalio  anhydrlde-glycerol-pentaerythrltol- 
styrene. 

•Fhthalic  anhydride-glycerol-styrene 

Phthalio  anhydride-maleic  anhydride-glycol- 

styrene. 
All  other 

•Styrene-butadiene  copolymer 

•otyrene-divinylbenzene  copolymer 

All  other 

Toluenesulfonamide  resins 

All  other  benzenoid  plastics  and  resin  materials- 

PLASTICS  AIID  RESIN  MATERIALS,  NONBENZENOID 

•Acetone-formaldehyde  resins 

Acrylic  resins : 

Polybutyl  methacrylate 

Polyethyl  acrylate 

Polymethyl  methacrylate 

All  other 

•Alkyd  resins  (except  phthalio): 
•Unmodified: 

Adipic  acid  esters 

Fumaric  acid  esters 

Maleio  anhydride  esters : 

•Maleic  anhydride-pentaerythritol 

All  other 

Sebacic  acid  esters: 

Sebaclc  acld-glyoerol 

Sebacic  acld-glycol 

All  other 

•Modified: 

Fumaric  acid  esters: 
•Fumaric  acid-glycerol-rosln 

•Fu^Baric  acld-pentaerythrltol-rosln 

All  other 


25,    69,    80,    196,    209,    315,    33A,    3-^7,    .W6,    55^,    559. 

5,    59,    75,    76,    80,    111,    158,    16^1,    185,    466,    473,    485, 

554,    558,    559. 
69,    180,    199,    253,    334,    346,    466,   473,   485,    558,    559, 

591. 
13,   76,    80,    83,    98,    158,    196,    209,    236,    334,    349,   464, 

466,    473,   478,    435,    537,    558,    559,    591. 
5,    24,    48,    69,    76,    84,    111,    158,    173,    180,    185,    209, 

253,    322,    334,    346,   441,    466,    473,   485,    530,    537, 

558,  559,    566,    591. 

U,    24,    46,    69,    80,    82,    180,    209,    232,    253,    276,    334, 
346,    347,    464,    466,   473,    485,    559,    591. 

13,    25,    46,    69,    80,    180,    209,    253,    276,    334,    466, 
485,    559,    591. 

46,    69,    158,    199,    232,    315,    334,    346,    473,    485,    554, 
559. 

46,    347,   465. 

13,    59,    80,    87,    180,    196,    209,    235,    253,    346,    400, 

473,   485,    559,    591. 
46,    69,    164,    199,    235,    276,    322,    334,    346,    347,   466, 

473,    485,    559,    591. 
164,    180,    196,    209,    232,    276,    334,    406,   466,    473, 

485,    558,    559. 
5,    59,    80,    83,    84,    158,    164,    180,    185,    212,    236,    313, 

322,    346,    349,    441,    464,    466,   473,   485,    537,    559, 

591. 
13,    24,    46,    59,    80,    133,    164,    180,    209,    212,    236, 

276,    334,   406,   464,    466,    473,   485,    537,    554,    559, 

566. 

101,    199,    249,   346,    455,    466,   475,    478,    537,    558, 

559,  566,    591. 

83,    101,    158,    209,    254,    277,   322,    349,    421,    441,    468, 
473,   478,    494,    537,    559,    566,    573,    607. 

221,    249,    252,    290,    305,    367,   478,   485,    553,   X. 
221,    252,    455,    478,    537,    559. 

24,    69,    111,    180,    199,    209,    334,   346,    559. 

24,    111,-  209,    253,    322,    466,    473,    485,    537,    558,    559, 

566. 
199,    221,   334,    346,    485,    517. 

133,    317,    466,   485,    537,    559. 

101,    165,    252,    290,    357,    367,    449,    455,    515,    553. 

241,    247,    249,    252,    566. 

152,    163,    199,    221,    241,    252,    253,    346,    485,    537,   X. 

221,    537. 

80,    421,    510,    527,    558,    577,   X. 


241,    466,    478,    537. 

253,    566. 

209,    343,    553,    566,    598. 

14,    209,    253,    553,    566,   584. 

163,    209,    253,    343,    357,    553,    566. 


199,    253,    334,    346,    566,    591. 
464,    537,    547. 

69,    199,   464,    466,   485,    554,    558. 
212,   464,    485,    537,    554. 

158,    334,    346,    466,    559,    566. 

566. 

83,    119,    133,    537. 


46,    69,    109,    196,    232,    267,    334,   347,   441,    466,   473, 

485,    537,    558,    566,   X. 
46,    98,    322,    334,    464,    466,    473,    485,    566,   X. 
334,    406,    464,   485' 


126 

TABLE    im.-Synthrt 


UNITED  STATES  TARIFF  COMMISSION 


chemicala:    Plaitias   anH  res 
re    report  ei^ ,    irient  i  fieri  by 


■naterifls    for   which  United  'States   rrnrfu 
\ifactnrer ,    1956- -Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


PLASTICS  AND  RESIN  MATERIALS,  NONBENZENOID— 
Continued 

»AlVyd  resins  (except  phthalic) — Continued 
»Modif  led— Continued 

Maleio  anhydride  esters: 
»Maleio  anhydride-glycerol-pentaerythritol- 

rosin. 
»Maleio  anhydride-glyoerol-rosin 

*Maleic  anhydride-glycol-rosin 

»Maleio  anhydride-pentaerythritol-rosin 

*Maleio  anliydride-pentaerythritol-tall  oil 

All  other 

All  other  modified  aliyd  resins 

Dicyandlamide  resins 

Furfuryl  resins 

Polyamide  (nylon)  resins 

»Polyethylene  resins 

Polyfluoroethylene  resins 

»Rosin  and  terpene  adduct  resins: 

»Fumaric  acid-rosin 

Maleio  anhydride-rosin 

All  other 

»Rosin  and  tall  oil  esters,  unmodified: 

*Rosin-glyoerol 

»Rosin-glyoerol-pentaerythritol 

»Rosin-pentaerythrltol 

»Tall  oil-pentaerythrltol 

All  other 

*Silioone  resins 

*Urea  and  melamine  resins : 
»Urea-formaldehyde  type: 

*Butylurea-formaldehyde 

»Urea-formaldehyde 

All  other 

*Melaim' ne-f ormaldehyde  type: 

Butylmelamine-formaldehyde 

•Melamine-formsLldehyde 

All  other 

»Vinyl  and  vinyl  copolymer  resins: 

•Polyvinyl  acetate 

Polyvinyl  alcohol 

Polyvinyl  butyral 

♦Polyvinyl  chloride  and  copolymer  resins: 

Polyvinyl  chloride 

Polyvinyl  chloride-acetate  copolymer 

All  other 

Polyvinyl  chloride-vinylldene  chloride  copolymer-' 

All  other 

All  other  nonbenzenoid  plastics  and  resin  materials 


158,  190,  235,  334,  346,  441,  554. 

24,  41,  48,  78,  80,  130,  158,  185,  196,  212,  313, 
322,  334,  441,  466,  485,  537,  558,  566,  X. 

Ill,  196,  212,  347,  485,  558. 

13,  24,  41,  59,  75,  130,  164,  196,  212,  276,  322,  334, 
347,  466,  473,  485,  548,  554,  558,  566,  X. 

5,  46,  50,  59,  69,  84,  98,  185,  464,  466,  473,  485, 
554,  559. 

24,  199,  209,  478,  485. 

196,  232,  455,  559,  591. 

417,  424,  608. 

421,  517. 

253,  328,  506. 

142,  186,  221,  252,  253,  367,  444,  529,  603. 

253,  357. 

41,  196,  212,  232,  334,  466,  485,  558,  566,  X. 
59,  130,  334,  346,  485,  537,  558. 
83,  212,  485,  559. 

83,  109,  130,  164,  196,  212,  313,  334,  349,  441,  464, 

466,  473,  485,  558,  X. 
130,  212,  334,  346,  441,  466,  485. 
50,  69,  84,  130,  212,  322,  334,  347,  441,  464,  466, 

485,  558,  X. 
164,  232,  334,  346,  406,  -.41,  485,  559. 
24,  212,  334,  346,  466,  473,  478,  558. 
244,  478,  484,  485,  558,  591. 


24,  221,  253,  466,  537,  558,  559,  566. 

1,  20,  24,  79,  111,  119,  125,  182,  194,  209,  212, 
221,  225,  253,  285,  343,  377,  417,  431,  439,  455, 
466,  471,  473,  478,  517,  537,  553,  558,  559,  566, 
584,  598,  601,  602,  X. 

253,  537,  566,  X. 

221,  253,  466,  537,  558,  566. 
221,  253,  473,  517,  537,  558. 
162,  221,  537,  566. 

65,  69,  111,  182,  253,  274,  290,  343,  346,  397,  441, 
466,  475,  521,  527,  529,  541,  553,  566,  584,  598, 
610,  X. 

182,  253,  274,  553. 

253,  274,  529. 

101,  221,  252,  357,  449,  455,  515,  523. 

221,  357,  515,  521,  529,  553. 

252,  357. 

252,  515. 

221,  253,  274,  510. 

152,  221,  235,  267,  322,  357,  441,  473,  553,  566, 
583,  608. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


127 


Rubber-Processing  Chemicals 


TABLE  21B. 


-Syrithetic  orgarii^  cheaiicals:    Ruhher-prdcessing  chcwicals    for  which  United  States    production 
sales   were  reported,    identified  by  manufacturer,    1956 


[Rubber-processing  chemicals  for  which  separate  statistics  are  given  In  table  21A  are  marked  below  with  an 
asterisk  (*);  chemicals  not  so  marked  do  not  appear  in  table  21A  because  the  reported  data  are  accepted  in 
confidence  and  may  not  be  published.  Manufacturers'  Identification  numbers  shovm  below  are  taken  from 
table  27] 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


RUBBER- PROCESSING -CHEMICALS,  CYCLIC 

♦Accelerators: 

Aldehyde- amines: 

Acetaldehyde-anillne 

n-Butyr aldehyde-aniline 

4,4'-Dlthlodlmorphollne 

a-Ethyl-P-propylacrylanilide 

Formaldehyde-p-toluidine  (Methylene-p-toluldlne) 

Hep taldehyde-anl line 

Trlethyltrimethylenetriamlne 

♦Dithlocarbamlc  acid  derivatives: 

Carbon  disulf ide-1, l'  -methylenedlpiperldlne 

Dlbenzyldlthlooarbamic  acid,  zinc  salt 

Dlbutyldlthiocarbamlo  acid,  dlphenylguanldlne 

salt. 
Dimethylethylene  diphenyldlthiooarbamic  acid, 
lead  salt. 

2,A-Dinitrophenyl  dimethyldithiocarbamate 

Piperidinium  pentamethylenedithiocarbamate 

Plperldinlum  pentamett^lenedithiocarbamlc  acid, 
potassium  salt. 
Guanldines: 

Dlcatechol  borate,  dl-o-tolylguanidine  salt 

Dlphenylguanldlne 

Dlphenylguanldlne  phthalate 

Dl-o-tolylguanldine 

Triphenylguanidine 

*Thiazole  derivatives: 

2-Benzothlazyl-N, N-diethylthiocarbamyl  sulfide — 

Bis[N,N'-2(2-benzothlazylthlomethyl)urea] 

N-tert-Butyl-2-benzothiazolesulfenamide 

N-Cyclohexyl-2-benzothiazolesulfenamide 

N-Dlisopropyl-2-benzothlazolesulfenamide 

»2,2'-Dithiobls[benzothlazole]  (2,2'-Benzo- 
thiazyl  disulfide) . 

N-Isoprapylbis[2-benzothlazolesulfenamlde] 

«2-Jfercaptobenzothiazole 

2-Mercaptobenzothiazole,  sodium  salt 

2-Mercaptobenzothiazole,  zinc  salt 

2-MercaptGbenzothiazollne 

N-Oxydlethylene-2-benzothiazolesulfenamide 

Miscellaneous  compounds: 

Dibenzylamlne 

Dl-N-pentamethylenethluram  tetrasulfide 

2-Imidazollne-2-thiol 

Poly-p-dinitrosobenzene 

p-(iilnonedioxime 

p-Quinonedloxime  dibenzoate 

♦Antioxidants: 

Aldehyde-  and  acetone- amines: 

Acetaldehyde-anillne  hydrochloride 

Aniline-acetone,  acid  derivatives 

Dlphenylamlne-acetone 

p-Phenetidine- acetone 

Phenyl-2-naphthylamine-acetone 

♦Amino  and  hydroxy  compounds; 
Amino  compounds: 

Aldol-a-naphthylamine  condensation 

p,p' -Dl ami nophenylme thane 

N, N' -Di( l-ethyl-3-methylpentyl) -p-phenylene- 
di amine. 

p,p'-Dimethoxydiphenylamlne 

N,  N'  -Di( 1-methylpentyl) -p-phenylenediamlne 

N, N'-Dl-2-naphthyl-p-phenylenedlamine 

N,N'-Dlphenylethylenediamine 

N, N'-Dlphenyl-p-phenylenedlamine 

N,N'-Diphenylpropylenediamine 

Dl-o-tolylethylenediamlne 

p-Hydroxydiphenylamine 

p-Isopropoxydlphenylamlne 

Octyldiphenylamlne 

Octyldiphenylamine,  alkylated 

N- Phenyl- 1-naph thy lamine 

N-Phenyl-2-naphthylamlne 

Tetramethyl  dlphenylethylenediamine 

p-(p-Toluenesulfonamldo)dlpheny lamine 

N-o-Toly 1-2- naphthy lamine 


A55. 

221,  253,  455. 

221. 

155. 

253. 

455. 

455. 

221. 
455. 
155. 


455. 
221. 
253. 


253. 

221,  537. 
221. 

253,  537. 
506. 

585. 
221. 
221. 
221. 
537. 
221,  449,  455,  537. 

455. 

221,  449,  455,  537. 

449,  537. 

449,  537. 

139,  537. 

537. 

455. 
253. 
253. 
253. 
253. 
455. 


455. 
221. 

221,  455. 
221. 
455. 


515. 
455. 
443. 

253. 

443. 

515. 

155,  424. 

253,  455,  515. 

155. 

155. 

253,  515. 

515. 

455. 

515. 

253. 

253,  515. 

424. 

455. 

449. 


128 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  21B. -Syntheti 


organic    chemicals:    Pubber^prdcessing  chemicals 
sales  were  reported,    identi  fied  by  manufacturer 


for   which    United   Sta 
J956 --Continued 


production  or 


Chemical 


Manufacturers'   identification  numbers 
(according  to  list  in  table  27) 


RUBBER-PROCESSING  CHE^aCALS,    CYCLIC— Continued 

•Antioxidants — Continued 

»Amino  and  hydroxy  compounds--Continued 
Hydroxy  compoxinds: 

2,5-Di-tert-aiiiylhydroqulnone 

Hydroquinone  monobenzyl  ether 

p,p  '-Isopropylidenedlphenol   ( P-Dl-p -hydroxy - 
phenylpropane) . 

N-Lauroyl-p-aminophenol 

2,2' -Methylenebis [4-ethyl-6-tert-butylphenolJ  - 
2,2' -Methylenebls t^-methyl-d-tert-butylphenol] 

»Phenol,   alkylated 

Phenol,   styrenated 

N-Stearoyl-p-aminophenol 

Thiobis [di-sec-amylphenol] 

<i,'4'-Thiobls[6-tert-butyl-m-cresol] 

Miscellaneous  compounds : 

Dicresyl  disulfide 

Nonj'lphenyl  phosphites,   mixed 

2,2,'i-Trimethyldlhydroquinoline 

Blowing  agents   and  processing   aids; 

Dinitrosopentamethylenetetramine 

p,p'-Oxybls [benzenesulfonhydrazide] 

Inhibitors:   N-Nitrosodlphenylamine 

Peptizers; 

0,0' -Dibenzamidophenyl  disulfide 

Dixylyl  disulfides,  mixed 

2-Naphthalenethlol  (2-Naphthylmercaptan) 

Pentachlorobenzenethlol,  zinc  salt 

Phenylhydrazlne  zinc  chloride 

Xylene  thiol 

)^lene  thiol,  zinc  salt 

Zinc-2-benzainlnothlo  phenate 

Taclcifiers: 

p-tert -Amy! phenol  sulfide 

Bis[iso-octylhydroxyphenylmethylene] 

RUBBER-PROCESSING  CHEMICAIS,  ACYCLIC 

•Accelerators : 

»Dithiocarbamlc  acid  derivatives: 

Dlbutyldithiocarbamlo  acid,  dimethyl-cyclo- 
hexylamine  salt. 

Dibutyldithiocarbamic  acid,  sodiujn  salt 

»Dibutyldlthiocarbamio  acid,  zinc  salt 

Diethyldithlocarbamic  acid,  selenium  salt 

Diethyldithiocarbamlc  acid,  sodium  salt 

Diethyldithlocarbamic  acid,  tellurium  salt 

*Diethyldithlocarbainic  acid,  zinc  salt 

Dlmethyldlthiocarbaralc  acid,  bisraate  salt 

Dlmethyldithiocarbamic  acid,  copper  salt 

Dimethyldithiocarbamic  acid,  dimethylammonlmn 
salt. 

Dlmethyldithiocarbamic  acid,  lead  salt 

•Dimethyldithiocarbamic  acid,  potassium  salt 

Dimethyldithiocarbandc  acid,  selenium  salt 

•Dlmethyldithiocarbamic  acid,  sodium  salt 

•Dlmethyldithiocarbamic  acid,  sodium  salt  and 
sodium  polysulfide. 

All  other 

Thiurams: 

Tetrabutylthiuram  monosulf ide 

Tetraethylthiuram  disulfide 

•Tetramethylthluram  disulfide 

•Tetramethylthiuram  monosulf ide 

Xanthates : 

Di-n-butylxantho  disulfide 

Dlisopropylxantho  disulfide 

Potassium  butyl  xanthate 

Sodium  butyl  xanthate 

Zinc  dibutyl  xanthate 

Miscellaneous  compounds: 

n-Butyraldehyde-butylamlne 

Dl-n-butylammonlum  oleate 

•Peptizers,  stabilizers,  and  lubricating,  condi- 
tioning, and  blowing  agents: 

Allcyl  raercaptans,  mixed 

•Dodecyl  mercaptans 

Zinc  laurate 

Blowing  agents: 

a,a'-Azobisformamide 

Urea-biuret  mixture 

Lubricating  and  conditioning  agents 


221. 
515. 
449. 

375. 

537. 

537. 

155,  449,  515. 

449,  515. 

375. 

221. 

221. 

455. 
455. 
515. 

139,  253. 
455. 
455,  515. 

537. 
253. 
253. 
253. 
253. 
253. 
253. 
537. 

585. 
167. 


253,   324, 

455. 

201,   253, 

324,   449,  455,    585. 

201. 

455,  477, 

515,   585. 

201. 

201,   324, 

449,  455,   585. 

201. 

201. 

455. 

201. 

449,  455, 

585. 

201. 

253,    515. 

449,  455, 

515. 

585. 

455. 

449,  455, 

585. 

45,    201, 

221,    253,  449,  455,   569,    585 

253,   449, 

455. 

455. 

515. 

455. 

455. 

449,  455. 

253- 

253. 

516. 

455,  468, 

516,    585. 

455. 

485. 
253. 

SYNTHETIC  ORGANIC  CHEMICALS,  1956 


129 


TABLE  22B.--Syntheti 


Elastomers  (Synthetic  Rubbers) 

organic  chemicals:    Elastomers  (synthetic   rubbers)    for  which  United  State 
or  sales   were  reported,    identified  by  manufacturer ,    1956 


[Elastomers  (synthetic  rubbers)  for  which  separate  statistics  are  given  in  table  22A  are  marked  below  with 
an  asterisk  ( ») ;  products  not  so  marked  do  not  appear  in  table  22A  because  the  reported  data  are  accepted 
in  confidence  and  may  not  be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from 
table  27.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification 
number  with  the  designated  product  ] 


Product 

Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 

ELASTOMERS,  CYCLIC 

129,  132,  200,  203,  357,  426,  -^9,  455,  465,  481, 
515,  538,  X. 

101,  284,  357,  455,  465,  515. 

ELASTOMERS,  ACYCLIC 

255,  357,  449,  455,  515. 
253. 

284,  434. 
2L2,  449. 

»Polyohloroprene  type  (  Neoprene) 

Reaction  products  of  natural  rubber 

253,  284,  357,  515,  X. 

Plasticizers 


-Synthetic  organic   chemicals:   Plasticizers   for  which  United  States  producti 
identified  by  manufacturer,    1956 


sales  were  reported. 


[Plasticizers  for  which  separate  statistics  are  given  in  table  23A  are  marked  below  with  an  asterisk  (*); 
products  not  so  marked  do  not  appear  in  table  23A  because  the  reported  data  are  accepted  in  confidence  and 
may  not  be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from  table  27.  An  X 
signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  Identification  number  with  the 
designated  product] 


PLASTICIZERS,  CYCLIC 

Camphor,  synthetic 

N-Cyclohexyl-p-toluenesulfonamlde 

Methylene  glared  dibenzoate 

Di-tert-octyldiphenyl  oxide 

Dlphenyl  cyolohexyl,  o-,  m-,  p-  

Dlpropylene  glycol  dibenzoate 

N-Ethyl-p-toluenesulfonamide 

Isopropylidenedlphenoxypropanol 

Naphthalene,  alkylated 

Phosphoric  acid  esters: 

Cresyl  diphenyl  phosphate 

Dibutylphenyl  phosphate 

Dlphenyl  mono-o-xenyl  phosphate 

aiphenyl  octyl  phosphate 

Trl(p-tert-butylphenyl)  phosphate 

*Tricresyl  phosphate 

»Triphenyl  phosphate 

Polyoxyalkalene  phenol 

»Phthallc  anhydride  esters: 

Butyl  benzyl  phthalate 

Butyl  cyclohexyl  phthalate 

«Butyl  decyl  phthalate 

Butyl  octyl  phthalate 

Butyl  phthaljl  butyl  glycolate 

Castor  oil  phthalate,  hydrogeiiated 

Diallyl  phthalate 

Dl(2-butoxyethyl)  phthalate  (Di(2-butyl  cellosolve) 

phthalate) . 
»Di butyl  phthalate 

»Dlcapryl  phthalate 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


253. 

221. 

303. 

252. 

221. 

303,  529. 

221. 

252. 

214. 

221,  597. 

221. 

252. 

221. 

252. 

221,  254,  273,  475,  597. 

221,  252,  477. 

547. 

221. 

558. 

72,  260,  558,  597. 

443,  529,  558. 

221. 

253. 

254. 

254,  359. 

72,  139,  177,  221,  253,  254,  273,  290,  336,  346, 

443,  451,  485,  493,  558,  573,  597. 
177,  254,  558,  566. 


130 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  23Ti.  --Synthetic  organic   chemicals:    Plasticizers    for  which  United  States  producti 
identi  fied  by  manufacturer,    7956 --Continued 


or  sales  were  reported. 


Manufacturers'  identifioation  numbers 
( according  to  list  In  table  27) 


PLASTICIZERS,  CYCLIC— Continued 

*Phthallo  anhydride  esters — Continued 

»Dlcyclohexyl  phthalate 

♦Dldecyl  phthalate 

Dlethylhexyl  hexahydrophthalate 

•Diethyl  phthalate 

Dihexyl  phthalate 

Dllsobutyl  phthalate 

»Diisodeoyl  phthalate 

»Dl(2-methoxyethyl)  phthalate  (Di(methyl  cello- 
solve)  phthalate) . 

»Dijnethyl  phthalate ■«- 

Dinonyl  phthalate 

*Dloctyl  phthalates: 

»Dl(2-ethylhexyl)  phthalate 

»Dliso-octyl  phthalate 

*Dl-n-ootyl  phthalate  and  mixtures 

Dlphenyl  phthalate 

Ethyl  phthalyl  ethyl  glycolate 

Hexyl-iso-octyl  phthalate 

Ifethyl  phthalyl  ethyl  glycolate 

»Octyl  decyl  phthalate 

All  other  phthalic  anhydride  esters 

Tetrahydrofurfuryl  oleate 

Toluenesulfonamide,  o-,  p-  mixture 

All  other  cyclic  plasticizers 

PLASTICIZERS,  ACYCLIC 

»Adlplc  acid  esters: 

Di(2-butoxyethyl)  adlpate  (Dl(butyl  cellosolve) 
adipate) . 

*Dldecyl  adipate 

•Dl(2-ethylhexyl)  adipate 

Dilsoamyl  adipate 

Dllsobutyl  adipate 

»Dliso-octyl  adipate 


Dinonyl  adipate 

Octyl  decyl  adipate 

All  other  adipic  acid  esters 

»Azelaic  acid  esters: 

Dl butyl  azelate 

Di(2-ethylhexyl)    azelate 

Diiso-octyl  azelate 

All  other  azelaio  add  esters 

Butyl  myristate 

Castor  oil  maleate 

Citric  and  acetylcitric  acid  esters 

Di ( butoxyethoxyethyl) methane 

Dl butyl  maleate 

Dlbutyl  fumarate 

Dlbutyl  tartrate 

Dicapryl  dlglyoolate 

Dlethylene  glycol  dlpelargonate 

Diethyl  maleate 

Glyceryl  dlaoetyl  tartrate  monoesters 

Glyceryl  tripropionate 

Isopropyl  myristate 

Laurie  acid  esters 

«01eic  acid  esters: 

2-Butoxyethyl  oleate  (Butyl  cellosolve  oleate) — 

»Butyl  oleate ■ 

Glyceryl  trioleate  (Triolein) 

•Methyl  oleate 

n- Propyl  oleate 

All  other  oleic  acid  esters 

Palmitic  acid  esters 

•Phosphoric  acid  esters 

Polyethylene  glycol  di-2-ethylhexoate 

Rlclnolelc  acid  and  aoetylrlclnolelc  acid  esters: 

n- Butyl  acetylrlclnoleate 

Butyl  riclnoleate 

•Glyceryl  monoriclnoleate 

Glyceryl  triaoetylricinoleate 

2-Methoxyethyl  acetylrlclnoleate  (Methyl  cellosolve 
acetylrlclnoleate) . 

Methyl  acetylrlclnoleate 

Methyl  rlcinoleate 


221, 
451, 
529. 
212, 

177, 

72, 
253, 

221, 
260, 


253,  25A,  558. 

485,  515,  522,  529,  597. 


221,  330,  443. 
499. 


139,  221,  254,  260,  558,  573. 
254,  359,  443. 


253,  330,  443,  527,  558. 
443,  451,  522. 


72,  139,  177,  221,  253,  254,  260,  273,  290,  443, 
451,  485,  493,  515,  529,  558,  573,  597. 

72,  212,  221,  254,  260,  290,  443,  451,  485,  493, 
522,  558,  573,  597. 

346,  515. 

221. 

221. 

573. 

221. 

72,  212,  254,  260,  451,  515,  522,  529,  558,  566, 
573,  597. 

212,  254,  443,  451,  522,  536,  573. 

248,  488. 

221. 

177,  256,  547. 


253,  254,  451. 

72,  254,  260,  451,  515,  522,  529,  558,  573. 

72,  254,  260,  346,  443,  451,  529,  573,  597. 

566. 

290,  443,  451,  522. 

72,  177,  221,  254,  260,  290,  359,  443,  522,  527, 

558,  566,  573. 
260,  536. 

72,  254,  260,  359,  522,  573. 
177,  314,  359,  515,  522,  529,  573. 


359,  443, 

536. 

443,  451, 

488 

522 

573 

597. 

290,  522. 

488,  X. 

359,  457. 

566. 

443. 

3W. 

72,  290. 

72. 

359. 

254. 

488. 

221. 

494. 

443. 

391,  457. 

100,  359, 

536. 

359,  536. 

254,  260, 

359 

457 

527 

536,  598 

248,  488, 

507. 

100,  359, 

457 

488 

527 

170,  488. 

170,  254, 

566. 

72,  100, 

359, 

443, 

457, 

597. 

254,  336, 

443, 

529 

529. 

96,  451. 

96,  451. 

96,  179, 

248, 

359, 

527, 

536. 

96. 

96,  451. 

96,  527. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


131 


TAnLE  23Ti.--Syntheti 


chemicr. 
irient 


's;  Plast icizers    far  which  Uniterl  StBte.t   protiii 
ifieH  hy  manufacturer,    J956--Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


PLASTICIZERS,  ACYCLIC— Continued 

Ricinoleic  acid  and  acetylricinolelc  acid 
esters — Continued 

Propylene  gljrcol  monorlcinoleate 

All  other  ricinoleic  and  acetylricinolelc  acid 
esters. 
»Sebacic  acid  esters: 

»Di butyl  sebacate 

Di(2-ethylhexyl)  sebacate 

Dilso-octyl  sebacate 

Polyethylene  glycol  2-ethylhexyl  sebacate 

All  other  sebacio  acid  esters 

*Stearic  acid  esters: 

2-Butoxyethyl  stearate  (Butyl  cellosolve  stearate) 

Butyl  epoxystearate 

»Butyl  stearate 

Diethylene  glycol  distearate 

Dimethylammonium  stearate 

2-Ethylhexyl  stearate 

Glyceryl  tristearate  (Tristearln) 

2-Methoxyethyl  stearate  (Methyl  cellosolve 
stearate) . 

Methyl  dichlorostearic  acid 

Methyl  pentachlorostearate 

All  other  stearic  acid  esters 

*Triethylene  glycol  di(caprylate-caprate) 

Triethylene  glycol  di-2-ethylbutyTate 

All  other  acyclic  plastioizers 


96,  359. 

179,  «!. 


177,  290,  359,  4^3,  451,  536,  566. 

72,  260,  290,  451,  536,  566,  573. 

72,  177,  260,  566. 

573. 

177,  41A,  451,  566,  X. 

254,  359. 
254. 

72,  170,  177,  254,  336,  359,  451,  457,  493,  527. 

359,  598. 

566. 

254. 

507. 

359. 

468. 

468. 

359,  451,  494,  527. 

72,  100,  507,  573. 

529. 

212,  254,  443,  451,  473,  488,  499,  529,  566,  X. 


132 


UNITED  STATES  TARIFF  COMMISSION 

Surface -Active  Agents 


TAHLE  24P. --Synthetic  oceanic  chemicals:    Surface-active  agents    for  which  United  States    production     or    aalei 
were  reported,    identified  by  manufacturer ,    1956 

[Surface-active  agents  for  which  separate  statistics  are  given  in  table  2^k  are  marked  below  with  an  aster- 
isk (*);  products  not  so  marked  do  not  appear  in  table  2'4A  because  the  reported  data  are  accepted  In  con- 
fidence and  may  not  be  published.  Manufacturers'  Identification  numbers  shown  below  are  taken  from  table 
27.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number 
with  the  designated  product] 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


SURFACE-ACTIVE  AGENTS,  CYCLIC 

*Esters  and  ethers,  nonsulfonated: 

Amylphenoxy  polyethoxyethanol 

Anhydrohexltol  castor  oil  ester 

Anhydrohexltol  castor  oil  polyoxyalkylene  ether 

Anhydrohexltol  dllaurate 

Anhydrohexltol  dllaurate  polyoxyalkylene  ether 

Anhydrohexltol  dloleate 

Anhydrohexltol  glycerol  monolaurate 

Anhydrohexltol  monolaurate 

Anhydrohexltol  monolaurate  polyoxyalkylene  ether — 

Anhydrohexltol  mono-oleate 

Anhydrohexltol  mono-oleate  polyoxyalkylene  ether — 

Anhydrohexltol  monopalmltate 

Anhydrohexltol  moncpalmitate  polyoxyalkylene  ether 

Anhydrohexltol  monostearate — 

Anhydrohexltol  monostearate  polyoxyalkylene  ether- 

Anhydrohexitol  tal:.  oil  ester 

Anhydrohexltol  tall  oil  polyoxyalkylene  ether 

Anhydrohexltol  tetrastearate 

Anhydrohexltol  trioleate 

Anhydrohexltol  trioleate  polyoxyalkylene  ether 

Anliydrohexitol  trlricinoleate 

Anhydrohexltol  trlricinoleate  polyoxyalkylene 
ether. 

Anhydrohexltol  tristearate 

Anhydrohexltol  tristearate  polyoxyalkylene  ether — 

Dlisobutylphenoxy  polyethoxyethanol 

Dodecylphenoxy  polyethoxyethanol 

Glucose  polyoxyalkylene  dlstearate — — 

Glucose  polyoxyalkylene  ether  polyoxyalkylene 

oleate. 
Glucose  polyoxyalkylene  oleate. 


Iso-octylphenoxy  polyethoxyethanol 

Nonylphehoxy  polyethoxyethanol- 


n-Octylphenoxy  polyethoxyethanol 

Tetradecylphenoxy  polyethoxyethanol 

»Nitrogen-contalning  surface-active  agents,  nonsul- 
fonated : 

N-Alkylethylmorpholinium  ethosulfate 

Benzylcetyldimethylammonlum  chloride 

Benzyldlmethyloctylammonlum  chloride — 

"Benzyllauryldlmethylammonium  chloride 

Benzylpolyethoxy  coconut  oil  ammonium  chloride 

Benzyl triraethylammonlum  chloride 

Caprylethyl-5-hydroxycycloimidine,  sodium 

ethylate,  sodium  ethlonate. 
Cetylpyrldinlum  chloride  (Hexadecylpyrldlnium 

chloride) . 
3,'i-Dichlorobenzyllauroyldimethylammonlum 

chloride . 
1 , l-Dihydroxyethyl-2-heptadecenylimidazollnlum 

chloride. 
Dodeeylbenzyldiethyl(2-hydroxyethyl)ajmiionlum 

chloride . 

Dodecylbenzyltrlethylammonium  chloride— — — 

Dodecylbenzyltrlmethylannnonlum  chloride 

Ethoxybenzyldlmethyloctylphenoxyajnmonlum  chloride- 

2-Heptadecyl-l-hydroxyethyl-2-lmidazoline 

Lauroyl-5-ethoxycyclolmidine,  dlsodium  ethlonate — 
Lauroylethyl-5-hydroxycycloimidlne,  sodium 

ethylate,  sodium  ethlonate. 

Lauroylmethylbenzyltrimethylamnionlum  chloride 

2-Laur oyloxy e  thyl c  arbamy Imethylpyr 1 dlnium 

chloride  (Lauroyl  ester  of  colamlnoforrayl- 

methylpyrldinium  chloride). 

tauroylpyri dlnium  chloride — — - 

Mixed  fatty  acid  imidazolines 

Oleoyl  imidazoline- 


5A7. 
547. 
547. 
547. 
547. 
547. 
547. 
547. 
547. 
547. 
547. 
547. 
547. 
547. 
547. 
547. 
547. 
547. 
547. 
547. 
547. 
547. 

547. 

547. 

510,  566. 

221. 

547. 

510. 

547. 

510,  527. 

159,  405,  510,  547,  566,  X. 

529,  547. 

222. 


547. 

348,  364,  566,  598,  611. 

492,  598. 

45,  364,  432,  547,  598. 

510. 

336. 

195. 

115,  364,  365. 

348,  364,  432,  598. 

608. 

222. 

494. 
222. 
566. 
608. 
195. 
195. 

566. 
494. 


Oxazoline,  substituted 

Rosin  amlnopolyethoxyethanol- 
Rosln  polyamidoinildazollne — 


364,  468. 
126. 

439,  497. 

336,  527. 

212,  547. 
290. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


133 


TAS£  24B. 'Synthetic  organic  chemicals:      Surface' act  ive    agents     for  which  United  States  production  or   sales 
were   reported ,    identified  by  manufacturer ,    1956- -Continued 


Manufacturers'  identification  numbers 
(acooraing  to  list  in  table  27) 


SDRFACE-ACTIVE  AGENTS,  CYCLIC— Continued 

•Nitrogen-containing  surface-active  agents,  non- 

sulfonated — Continued 
Stearoylethyl-5-hydroxycycloimidine,  sodium 

ethylate,  sodium  ethionate, 
Stearoyl  imidazoline- 


Stearoyloxyethylcarbanylmethylpyrldinium  chloride- 
N-Xylene  stearamide- 


•Sulfated  and  sulfonated  cyclic  surface-active 
agents: 
»Alkyl  benzenoid  compounds,  sulfated  and 
sulfonated: 

Decylbenzenesulfonic  acid  type— 

Didodecylbenzenesulfonlc  acid  type 

»Dodecyllienzenesulfonic  acid  type 


Dodecylbenzenesulfonic  acid,  butylammonium  salt- 

Dodeoylbenzenesulfonic  acid,  calcium  salt 

Dodecylbenzenesulfonic  acid,  cyolohexylamine 

salt. 
Dodecylbenzenesulfonic  acid,  isopropylaramonlum 

salt. 
Dodecylbenzenesulfonic  acid,  triethanolamine 
salt. 

Dodecyltoluenesulfonio  acid  type 

All  other 

•Lignin  derivatives,  sulfonated: 

Ammonium  lignosulfonate — — — — — 

Calcium  lignosulfonate 

Magnesium  lignosulfonate — 

Sodium  lignosulfonate — — — 

•Naphthalene  derivatives,  sulfonated: 

Benzylnaphthalenesiilfonic  acid,  mono- — — 

Butyllsopropylnaphthalenesulfonic  acid,  sodium 
salt. 

»Butylnaphthalenesulfonic  acid,  mono- 

»Diamylnaphthalenesulfonic  acid — — 

»Dibutylnaphthalenesulfonic  acid 

•Diisopropylnaphthalenesulfonic  acid — — 

*Isopropylnaphthalenesulfonic  acid -— 

1,1' -MethylenebisC2-naphthalenesulfonlc  acid) . 

Mixed  alkylated  naphthalenesulfonic  acid 

Tetrahydronaphthalenesulfonic  acid 

•Petroleum  aromatic  compounds,  sulfonated;  Water- 
soluble-  type  petroleum  sulfonate,  sodium  salt. 
»A11  other  sulfated  and  sulfonated  cyclic  surface- 
active  agents: 

Butylbiphenylsulfonic  acid 

Butylhydroxyblphenylsulfonic  acid-—— 

N-Cyclohexyl-N-palmitoyltaurine 

Dibutyliiydroxybiphenyldisulfonlc  acid 

N,N-Dlethylcyolohexylamlne  salt  of  lauryl 

sulfate. 
Dodecyltriethylammonium  p-toluene  sulfonic  acld- 
N-Methyl-N-didodeoylbenzyltaurine,  sodium  salt — 

Nonylphenoxy  polyethoxyethyl  sulfate — 

Octylphenoxy  polyethoxyethyl  sulfate 

Octylphenoxy  polyethoxyethyl  sulfonate 

•Toluene  sulfonate,  sodium  salt — — — — 

Trichlorophenol  sulfate,  ethanolamine  salt 

Xylene  sulfonate,  sodium  salt 

SURFACE-ACTIVE  AGENTS,  ACYCLIC 


I 


•Esters  and  ethers,  nonsulfonated: 

•Diethylene  glycol  monolaurate 

•Diethylene  glycol  mono-oleate 

•Diethylene  glycol  monostearate 

Diethylene  glycol  tall  oil  ester 

Diisobutylene  maleate 

Dipolyethoxyethyl  ether  of  polyoxypropylene 
glycol. 

Ethylene  glycol  mono-oleate — — 

Ethylene  glycol  monostearate — 

Glycerol  maleate  mono-oleate — 

Glycerol  mono  and  di  esters  of  fatty  acids 

Glycerol  monococate 

Glycerol  monoester  of  lard 


A9A. 
501. 


92,  221. 

573. 

62,  99,  113,  122,  159,  188,  221,  243,  251,  261,  278, 
281,  298,  318,  327,  3A3,  383,  ^2^^,  439,  457,  458, 
494,  497,  501,  506,  547,  552,  563,  565,  566,  567, 
577,  586,  612,  615. 

221,  494. 

494,  545. 

510. 


439,  494,  545,  567. 


545,    567, 

612. 

566. 

221,   497. 

614. 

16,    23,    299,   617,   618. 

16. 

16,    618. 

510. 

288,    376. 

170,    288, 

577. 

159,    343, 

439,    608. 

159,    225, 

439,    510,    608. 

253,    290, 

501,    510,    527,    573, 

217,    253, 

424,    506,    537. 

253. 

126,    144, 

507. 

253. 

85,    373, 

419,   463,    508. 

221. 

221. 

510. 

221. 

253. 

364. 

222. 

510,    567, 

586,    615. 

566. 

566. 

206,    281, 

501,    586,    604,    612 

510. 

206,    501 

545. 

179,  343,  359,  425,  494,  527,  536. 

179,  359,  488,  494,  527,  536. 

62,  179,  248,  327,  343,  359,  391,  494,  527,  536,  549. 

343,  494. 

566. 

565. 

359,  497,  536. 

248,  359,  391,  536,  545. 

359,  547. 

494,  527. 

507. 

327. 

327,  507. 


I 


134 


UNITED  STATES  TARIFF  COMMISSION 


1/a.t  2ATi.- -Synthetic    organic    chemicals:   Surface-active  agents     for    which  Uni  ted  States  production  or  sales 
were  reported,    identified  by  manufacturer,    1956--Continued 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


SURFACE-ACTIVE  AGENTS,  ACYCLIC— Continued 

•Esters  and  ethers,  nonsulfonated — Continued 

Glycerol  monolaurate — 

•Glycerol  mono-oleate 

•Glycerol  monostearate 

Hexitol  polyoxyalkylene  beeswax  ester 

Hexitol  polyoxyalkylene  dioleate 

Hexitol  polyoxyalkylene  fatty  acid  ester 

Hexitol  polyoxyalkylene  hexalaurate 

Hexitol  polyoxyalkylene  hexaoleate 

Hexitol  polyoxyalkylene  hexastearate 

Hexitol  polyoxyalkylene  hexa(tall  oil)  ester 

Hexitol  polyoxyalkylene  lanolin  ester 

Hexitol  polyoxyalkylene  oleate 

Hexitol  polyoxyalkylene  pentalaurate 

Hexitol  polyoxyalkylene  penta(tall  oil)  ester 

Hexitol  polyoxyallQrlene  tetra(oleate,  laurate) 
ester. 

Hexitol  polyoxyalkylene  tetra(tall  oil)  ester 

Methoxy  polyethoxyethyl  coconut  oil  ester 

Polyethoxyethyl  castor  oil  ester 

Polyethoxyethyl  cetyl  ether 

Polyethoxyethyl  coconut  oil  ester 

Polyethoxyethyl  decyl  ether 

•Polyethoxyethyl  dilaurate 

•Polyethoxyethyl  dioleate 

Polyethoxyethyl  distearate 

Polyethoxyethyl  tert-dodeoyl  thloether 

Polyethoxyethyl  lauryl  ether 

Polyethoxyethyl  mixed  fatty  acid  ester 

•Polyethoxyethyl  monolaurate 

•Polyethoxyethyl  mono-oleate 

Polyethoxyethyl  monopalmitate 

Polyethoxyethyl  monoriclnoleate 

•Polyethoxyethyl  monostearate 

Polyethoxyethyl  oleyl  ether 

Polyethoxyethyl  soybean  oil  ester 

Polyethoxyethyl  stearyl  ether 

Polyethoxyethyl  tall  oil  ester 

•Polyethoxyethyl  tallow  ester 

•Polyethoxyethyl  tridecyl  ether 

Folyglycerol  oleate ~ — — 

Polyoxyalkylene  glycollate 

Polyoxyalkylene  lanolin  ether 

Polyoxyalkylene  resin  ester 

1,2-Propylene  glycol  monococate — 

•1,2-Propylene  glycol  monolaurate — 

1,2-Propylene  glycol  mono-oleate 

•1,2-Propylene  glycol  monostearate 

Propylene  glycol  polyoxyalkylene  stearate 

Propylpolyethoxyethyl  ether  of  polyoxypropylene 
glycol . 
•Nitrogen-containing  surface-active  agents,  nonsul- 
fonated: 

Alkylamino  polyethoxyethanol 

Alkylsulfonamidoacetic  acid,  sodium  salt — 

N-(Amlnoethyl)-N-(hydroxyethyl) coconut  oil  amide-- 

N- ( Aminoethyl ) -N- ( hy dr oxyethyl ) oleamide 

N-(Aminoethyl)-N-(hydroxyethyl)palm  oil  amide 

•N-(Aminoethyl)-N-(hydroxyethyl)stearamlde  (Stear- 
amide  of  aminoethylethanolamine) . 

Cetylbetaine  (Hexadecylbetaine ) 

Cetylethyldirael^hylammonium  bromide- — 

Cetyl,  lauroyl  trlmethylammonium  bromide 

Cetyltrimethylammonlum  bromide 

•Coconut  oil  amide  of  mono(diethanolaiiiine) 
(Dlethanol  lauramide) . 

•Coconut  oil  amide  of  bls(diethanolamine) 

•Coconut  oil  amide  of  diethanolamlne,  neither  mono 

nor  bis. 

Coconut  oil  amide  of  diethylenetriamine 

Coconut  oil  amide  of  diisopropanol amine 

Coconut  oil  amide  of  isopropanolamine 

Coconut  oil  amide  of  monoethanolamlne  (Ethanol 

lauramide). 


179,  359. 

32,  179,  188,  2^8,  318,  359,  488,  497,  507,  527,  536, 

545,  547. 
91,  113,  159,  179,  225,  248,  298,  327,  359,  365,  391, 

418,  494,  507,  521,  527,  536,  547,  549. 
547. 
547. 
547. 
547. 
547. 
62. 
547. 
547. 
547. 
547. 
547. 
547. 

547. 

359,  507,  536. 

494,  510,  547,  608. 

547. 

122,  298,  527. 

457,  547. 

179,  239,  359,  536,  598,  608. 

179,  343,  359,  424,  497,  527,  536,  608. 

179,  343,  359,  536,  549. 

221,  497,  585. 

253,  343,  547,  X. 

376,  497,  529,  547. 

21,  153,  179,  232,  343,  359,  499,  507,  510,  527,  536, 

549,  608. 
62,  179,  188,  343,  359,  424,  497,  499,  507,  510,  527, 

536,  547,  549,  598,  608. 
507,  547. 
359,  527,  536. 
45,  62,  179,  239,  359,  457,  494,  527,  536,  547,  549, 

566,  598,  608. 
159,  253,  501,  510,  527,  547. 
598. 

380,  547. 

9,  62,  221,  286,  405,  494,  497,  510,  527,  547. 
170,  323,  359,  424,  497,  510. 
221,  405,  497,  510,  547,  X. 
494. 
547. 
547. 

547,  X,  X. 
327,  507. 

327,  359,  507,  536. 
359,  536. 

248,  298,  327,  359,  494,  536. 
547. 
547. 


510,  547,  X. 

510. 

62,  298,  418,  507,  527,  563. 

399,  501,  527. 

170. 

62,  113,  159,  170,  225,  243,  253,  343,  399,  417,  418, 

424,  457,  501,  510,  527,  598. 
253. 
364. 
253. 
364. 
122,  243,  298,  327,  391,  399,  418,  494,  497,  501, 

527,  545,  563,  608,  613. 
2,  62,  90,  153,  286,  343,  386,  439,  501,  527,  545, 

567. 
28,  92,  113,  159,  176,  239,  417,  586,  598,  X, 

286,  527. 

X. 

545,  586,  X. 

62,  159,  243,  286,  298,  359,  417,  494,  501,  598. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


135 


TABLE  21B.--Synthetic  organic 
were 


Sur  face-act  i 
identified  by 


T  which  Vnite-I  "Staters 
19 56- -Continued 


Manufacturers'  Identification  numbers 
(according  to  list  in  table  27) 


SURFACE-ACTIVE  AGENTS,  ACYCLIC— Continued 

•Nitrogen-containing  surface-active  agents,  non- 
sulfona ted --Continued 

Coconut  oil  trimethylararaoniuin  chloride 

Decylbetaine 

Dicoconut  oil  dimethylammoniuni  chloride 

N,N-Dlethyleth>'lene  bis-stearamlde 

Dihydrogenated  tallow  dimethylanponium  chloride 

N,N-DlC2-hjrdroxyethyl)blsoleaiiiide 

N , N-Di ( 2-hy droxyethyl ) caprami  de 

N , N-Dl ( 2-hydr oxyethy 1 ) lauramide   ( Dlethanolamlne 
laurate). 
•N,N-DiC2-hydroxyethyl)oleaiiiide   (Diethanol 

oleamlde) . 
»N , N-Di ( 2-hydroxyethyl ) s tearamlde   ( Diethanol 
stear amide). 

Dilauroyldimethylammonium  bromide 

N-(3-Dlmethylainino)  oleamlde 

Dlsoybean  oil  dimethylammonium  chloride 

Dltallowdimethylammoniuin  chloride 

N,N-Ethylene  blsoleamide 

N,N-Ethylene  bis-stearamlde 

N-(2-Hydroxyethyl)oleamlde  (Ethanol  oleamlde) 

N-( 2-Hydroxyetl^l ) stearamide 

N-(2-Hydroxymethyl)rayristamide 

N-(2-Hydroxypropyl)laur amide 

N-(2-Hydroxypropyl) oleamlde 

N-(2-Hydroxypropyl) stearamide 

Lauroylamino  polyethoxyethanol 

N-Lauroyl  polypeptide — 

N-Lauroylsaroosln 

Lauroyltrimethylammonium  chloride — . 

Oleamlde  of  dlethylenetriamine 

Oleoylamino  polyethoxyethanol 

Oleoylbiguanide  hydrochloride 

Oleoylpolypeptide 

N-Oleoylsarcosin,  sodium  salt 

Polyethoxyethanol  mixed  fatty  amides  and  amines 

Polypeptide 

Soybean  oil  polyethoxyethyl  dlethylenetriamine, 
ammonium  salt. 

Soybean  oil  trimethylammonium  chloride 

*Stearamide  of  dlethylenetriamine 

Stearamide  of  ethylenedlamine 

Stearamide  of  tetraethylenepentamine 

1-Stearamido-l' -adlpoamido  dlethylenetriamine 

Stearic  acid  ester  of  N- ( 2-hy droxyethyl )  stear- 
amide. 

Stearoylamino  polyethoxyethanol 

Stearoylbiguanide  hydrochloride 

Stearoylethyldimethylammonlum  bromide 

N-Stearoylsarcosin,  sodium  salt 

Stearoyltrlmethylammonium  bromide 

Stearoyltrimethylammonium  chloride 

Tallow  amide  of  dlethanolamlne 

Tallow  trimethylammonium  chloride 

TetralcisChydroxyethyl  polyoxyethylenepolyoxy- 
propylene) ethylenedlamine. 

Triethanolamine  coconut  oil  ester 

Triethanolamine  myristate — — 

Triethanolamine  oleate 

Triethanolamine  stearate 

All  other 

•Phosphorus-containing  sVirfaoe-aotive  agents,  non- 
sulf onated : 

Alky t"  polyphosphates,  mixed,  sodium  salt 

Capryl,  octyl  phosphate 

Dodecyl  phosphate 

Ethylhexyl  phosphate,  sodiim  salt 

Mixed  mono-  and  dlalkyl  acid  phosphates 

Mixed  mono-  and  dlalkyl  acid  phosphates, 
dlethanolamlne  salt. 

Ootyl  polyphosphate,  sodium  salt 

•Salts  of  fatty  acids,  nonsulf onated: 

Castor  oil,  potassium  salt 

•Coconut  oil,  potassium  salt 

Com  oil,  potassium  salt — 

Corn  oil,  sodium  salt 

•Potassium  laurate 

^^otasalum  oleate 


309. 

253. 

309. 

543. 

309. 

62. 

608. 

424,  527,  549,  598. 

170,  248,  494,  527,  545,  608. 

28,  62,  153,  159,  239,  286,  343,  439,  501,  520,  527, 

545,  549,  608,  X. 
253,  598. 
248. 
309. 
328. 
248. 
248,  501,  527,  608. 

417.  N 
545. 

501. 

501,  608. 

494. 

494. 

510. 

271. 

327,  510,  608. 

309. 

527,  547. 

510,  547. 

510. 

271. 

510,  608. 

126,  309,  510. 

271. 

510. 

309. 

217,  286,  343,  399,  417,  424,  457,  598. 

514. 

418,  457,  598. 
286. 

494. 

510,  547. 

510. 

364. 

510,  608. 

253. 

309. 

298. 

309. 

565. 

545. 

524. 

232,  524,  536. 

21,  424. 

206,  418,  497,  510,  583,  612. 


378. 

378,  418. 
253. 
529. 

253,  537. 
253,  378. 

378. 

343. 

36,  47,  62,  225. 
47,  386,  497. 
21. 

153,  507,  527,  549. 

36,  47,  62,  149,  170,  225,  324,  343,  386,  404,  497, 
501,  527»  549,  563. 


136 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  24B. --.Synthetic  organic  chemicals:      Surface-active    agents     for   which  United  States  prorhjcti 
were  reported,    identified  by  manufacturer,    /956-- Continued 


SURFACE-ACTIVE  AGENTS,  ACYCLIC—Contlnued 

»Salts  of  fatty  acids,  nonsulfonated — Continued 

Potassium  resinate 

Potassium  stearate 

*Potassi\jni  tallate 

Rice  oil,  sodium  salt 

Sodium  laurate 

»Sodlum  oleate — • — — 

•Sodium  stearate 

Sodium  tallate 

Soybean  oil,  potassium  salt 

Tallow,  potassium  salt 

Tallovj,  sodium  salt 

•Sulfated  and  sulfonated  acyclic  surface-active 
agents: 
»Aoids,  sulfated  and  sulfonated: 

Aoetyloleic  acid,  sulfonated 

•Oleic  acid,  sulfonated  (Sulfonated  red  oil)- 


Rloinoleic  acid,  sulfonated 

•Alcohols,  sulfated  and  sulfonated: 

Capryl,  octyl  sulfate 

Cetyl,  oleyl  sulfate 

Cetyl  sulfate 

Decyl  sulfate 

Decyl  sulfate,  triethanolamine  salt 

3,9-Diethyl-6-tridecyl  sulfate 

2-Ethylhexyl  sulfate 

7-Ethyl-2-methyl-'i-undecyl  sulfate 

Lauryl,  oleyl  sulfate,  sodium  salt 

Lauryl  sulfate,  2-amino-2-methyl  propanol  salt — 

Lauryl  sulfate,  ammonium  salt 

•Lauryl  sulfate,  diethanolamine  salt 

Lauryl  sulfate,  isopropanolaraine  salt 

Lauryl  sulfate,  magnesium  salt 

Lauryl  sulfate,  monoethanolamine  salt 

Lauryl  sulfate,  potassium  salt 

•Lauryl  sulfate,  sodium  salt  (Sodium  dodecyl 
sulfate) . 

•Lauryl  sulfate,  triethanolamine  salt 

Stearyl  sulfate  (Octadecyl  sulfate) 

Stearyl  sulfate,  triethanolamine  salt 

Tallow  sulfate 

•Esters,  sulfated  and  sulfonated: 

Bis-sulfosuccinate  ester  of  tallov  monoglycerlde 

Bis(tridecyl)  sulfosuccinate 

Butyl  ethylene  glycol  sulfo-oleate 

n-Butyl  sulfo-oleate 

n-Butyl  sulforicinoleate,  sodium  salt 

Diarayl  sulfosuccinate 

Dicapryl  sulfosuccinate 

Di ( 2-ethylhexyl )  sulfosuccinate 

Dihexyl  sulfosuccinate 

Disodium  l-raethyl-2-sulfoethyl  a-sulfolaurate 

Disodium  2-sulfoethyl  a-sulfococate 

Disodium  2-sulfoethyl  a-sulfo-oleate 

Ethyl,  butyl  sulfoaconitate,  sodium  salt 

Ethyl  sulfo-oleate 

Glycerol  mono( coconut  oil)  ester,  sulfated, 

ammonium  salt. 
Glycerol  mono(coconut  oil)  ester,  sulfated, 

sodium  salt. 
Glycerol  monostearate  sulfoacetate,  sodium  salt- 

Glyoerol  tri( sulfo-oleate) 

•I sopropyl  sulfo-oleate 

Lauroyl  sulfoacetate 

Methyl  sulfo-oleate 

Methyl,  ethyl,  propyl  sulfo-oleate 

Mixed  alkyl  ethers,  sulfated 

Polyethoxyethyl  n-decyl  sulfate 

Polyethoxyetliyl  lauryl  sulfate,  triethanolamine 
salt. 

Polyethoxyethyl  stearyl  sulfate 

Polyethoxyethyl  tridecyl  sulfate 

»n-Propyl  sulfo-oleate 

•Nitrogen-containing  surface-active  agents, 
sulfated  and  sulfonated: 
Coconut  oil  amide  of  isopropanolaraine ,  sulfated, 
sodium  salt. 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


501. 


527. 


497 

21,  47,  153,  343,  386,  418,  425,  497,  549. 

439. 

417 

62, 

418 

153 

343. 

149,  343,  507 


90,  343,  404,  417,  418,  493,  501,  507,  527,  549. 

424,  493,  501,  527,  560,  564. 

343,  418,  527. 
507. 


32,  85,  90,  92,  113,  159,  171,  217,  343,  383,  404, 
418,  424,  425,  436,  439,  457,  497,  507,  510,  527, 
537,  571,  612. 

507,  527. 


253,    380, 

418. 

288,    380, 

598. 

253,    380, 

608. 

253,    598. 

253. 

529. 

529. 

529. 

253,    380. 

253. 

380,    567, 

586,    598. 

253,    380, 

567,    586,    611. 

613. 

380. 

376. 

298,    380. 

62,    93,    253,    298,    343,    380,    399,   424,   492,    503,    547 

567,    586,    598,    611,   613,    615,   619. 

253,    298, 

380,    567,    581,    586,    598,    611,   615. 

122,    253, 

298,    380. 

253. 

598. 

537. 

537. 

225,   424 

62,   424, 

439,    457,    598. 

451. 

537. 

566. 

62,    122, 

159,    343,    418,   457,    537. 

537,    608 

510. 

510. 

510. 

62. 

425. 

327. 

327,  492. 

494. 

170,  343,  424. 

28,  217,  243,  343,  418,  573. 

506. 

457. 

527. 

151,  298. 

X. 

298,  380. 

253,  380. 
547,  567. 
153,  170,  323,  488,  497,  537. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


137 


chemicals:   Sur  face -net  ive  agents     for    which  Vnite-i  states  prnrlu, 
repnrterl,    irlentifieH  hy  manufacturer ,    1956- -Continued 


SURFACE-ACTIVE  AGENTS,  ACYCLIC— Continued 

xSulfated  and  sulfonated  acyclic  surface-ective 
agents- -Continued 
»Nitrogen-containlng  surface-active  agents, 
sulfated  and  sulfonated — Continued 
■••Coconut  oil  amide  of  monoethanolajnine,  sulfated, 

potassium  salt. 
"Coconut  oil  amide  of  monoethanolamine,  sulfated, 
sodium  salt. 

Coconut  oil  amine  propionate,  sulfated — — 

N-(2-Hydroxyethyl)oleamlde,  sulfated  (Oleic  acid 

ethanolamide  sulfate),  sodium  salt. 
N-(2-Hydroxyethyl)stearamide,  sulfated  (Stearic 
acid  ethanolamide  sulfate),  sodium  salt. 

N- ( 2-Hydroxypropyl ) oleamide,  sulfated 

Lauroylsulfoacetoethanolamide,  potassium  salt 

Lauroyltrimethylammoniumtosylate 

N-Methyl-N-oleoyltaurine,  sodium  salt 

N-Metliyl-N-palmitoyl  taurine 

N-(Myristoylethyl)sulfosucclnamide 

Neat's-foot  oil  amide  of  ethanolamine,  sulfated, 
ammonium  salt. 

N-(01eoylisopropyl)sulfosuccinamide — 

N-Stearoyl  sulfosuocinamlde,  disodium  salt 

Tallow  amide  of  ethanolamine  sulfosuccinate ~ 

N, N, N, N-Tetrakis ( 2-hydroxypropyl ) -ethylene- 
diamlne  dioleate  methyl  sulfate. 

All  other 

»Oils,  fats,  and  waxes,  sulfated  and  sulfonated: 
Animal  fats  and  oils,  sulfated  and  sulfonated: 

Lard  oil,  sulfonated 

»Neat's-foot  oil,  sulfonated 

Oleostearine,  sulfonated 

«Tallow,  sulfonated 

Wool  grease,  sulfonated 

Fish  and  marine-animal  oils,  sulfated  and 
sulfonated : 
«Cod  oil,  sulfonated 

Herring  oil,  sulfonated 

Menhaden  oil,  sulfonated 

Mixed  fish  oils,  sulfonated 

*Sperm  oil,  sulfonated 

Whale  oil,  sulfonated 

»Tall  oil,  sulfonated 

Vegetable  oils,  sulfated  and  sulfonated: 
»Castor  oil,  sulfonated 


»Coconut  oil,  sulfonated 

Com  oil,  sulfonated 

Cottonseed  oil,  sulfonated. 

Linseed  oil,  sulfonated 

*t4istard -seed  oil,  sulfonated 

Olive  oil,  sulfonated 

Palm-kernel  oil,  sulfonated 

♦Peanut  oil,  sulfonated 

Rapeseed  oil,  sulfonated 

»Rice-bran  oil,  sulfonated 

♦Soybean  oil,  sulfonated - 

»A11  other  oils,  fats,  and  waxes,  sulfated  and  — 
sulfonated : 

Japan  wax,  synthetic,  sulfonated 

Recovered  grease,  sulfonated 

All  other 

Petroleum  aliphatic  compounds,  sulfated  and  sul- 
fonated: Petroleum  sulfonate,  sodium  salt. 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


62, 


,  243,  "ilS,  -^39. 
159,  286,  3«,  417,  418,  501,  598,  608. 


328. 
170, 


494. 

494. 

563. 

62,  99,  159,  243,  417,  424,  436,  439,  510. 

510. 

494. 

286. 

494. 
537. 
170. 
253. 


103,  246,  286,  436,  439,  497,  616. 

32,  36,  113,  171,  246,  286,  294,  404,  425,  507,  520, 
527,  571. 

171. 

22,  26,  32,  62,  71,  113,  159,  170,  171,  217,  243, 
246,  294,  323,  343,  383,  418,  424,  436,  439,  457, 
497,  507,  526,  527,  537,  549,  571,  598. 

246. 


32,  36,  103,  114,  171,  225,  294,  404,  424,  497,  507, 

520,  527,  571. 
171,  507,  527,  571. 
246,  507. 
92,  616. 
32,  36,  85,  99,  103,  114,  122,  171,  176,  225,  243, 

246,  294,  343,  404,  424,  425,  437,  497,  507,  520, 

527,  539,  571,  598,  616. 
539. 
99,  171,  286,  343,  425,  457,  527,  537,  616. 

11,  32,  36,  49,  62,  71,  85,  90,  92,  99,  105,  113, 
153,  159,  170,  171,  176,  217,  225,  243,  246,  253, 
286,  294,  404,  418,  424,  425,  436,  437,  439,  451, 
457,  497,  501,  507,  510,  520,  526,  527,  537,  539, 
549,  571,  575,  586,  616. 

113,  114,  404,  437,  425,  527,  537,  616. 

497,  527,  537,  586. 

527. 

294. 

113,  243,  294,  527,  586. 

424. 

114. 

11,  71,  85,  170,  294,  323,  383,  425,  437,  527,  537. 

343,  425. 

71,  113,  243,  343,  424,  497,  507,  527,  539. 

176,  243,  294,  425,  507,  571. 


404. 
171,  539. 

253. 


138  UNITED  STATES  TARIFF  COMMISSION 

Pesticides  and  Other  Organic  Agricultural  Chemicals 


TABLE  25B. --Synthetic  organic  chemicals:   Pesticides  and  other  organic  agricultural  chemicals  for  which  United 
States  production  or  sales  were  reported,    identified  by  manufacturer,    1956 

r  Pesticides  and  other  organic  agricultural  chemicals  for  which  separate  statistics  are  given  in  table  25A 
are  marked  below  with  an  asterisk  (*);  products  not  so  marked  do  not  appear  in  table  25A  because  the  re- 
ported data  are  accepted  in  confidence  and  may  not  be  published.  Manufacturers'  identification  numbers 
shown  below  are  taken  from  table  27.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publica- 
tion of  his  identification  number  with  the  designated  product] 


PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL 
CHEMICALS,  CYCLIC 
^Fungicides  and  seed  disinfectants: 

Cadmium  aniline  dilactate 

Captan  ( N-Trichloromethylthio-4-cyclohexene- 
1,2-dlcarboximide) . 

Chloranil  ( Tetraohloro-p-quinone) 

5-Chloro-2-mercaptobenzothlazole 

5-Chloro-2-mercaptobenzothiazole,  lauryl- 
pyridium  salt. 

Dichlone  ( 2, 3 -Dichloro- 1,4 -naphthoquinone) 

3,5-Dimethyltetrahydro-2H,l,3,5-thladiazine-2- 
thione . 

Glyodin  C2-Heptadecyl-2-imidazollne  acetate) 

2-Mercaptobenzothlazole,  monoethanolamine  salt — 
«Mercury  fungicides: 

2- Chloro-4-(hydroxymercuri) phenol 

N-( Ethylmercuri) -hexachlorotetrahydro- 
methanophthalimide  (Qnmi). 

N-( Ethylmercuri) -p-toluenesulfonanllide 

<l-(Hydroxymercurl)-2-nltrophenol 

2-(Phenyljnercuriamino)ethanol  acetate 

N-Phenylmercuriformamide " — 

8-(Phenylmercurioxy) qulnoline 

Phenyljaercury  hydroxide 

Phenylmercury  lactate 

Phenylmeroury  naphthenate 

Phenylmercury  oleate 

Phenylmeroury  propionate 

Tris( 2-hydroxyethyl) ( phenylmerouri) ammonium 
lactate. 
2-( 1-Methylheptyl) -4,6-dinitrophenyl  orotonate 

( Karathane) . 
»Naphthenic  acid,  copper  salt 


Manufacturers'  Identification  numbers 
(according  to  list  in  table  27) 


»Pentachlorophenol 

Pentachlorophenol,  sodium  salt — ------- — 

a-Phenyl-p-cresol  (p-Benzylphenol) 

3-Quinolinol  ( 8-Hydroxyqulnoline) ,  copper  salt 

2,3,4,6-Tetraohlorophenol 

»2,'4,5-Trlchlorophenol 

2,A,5-Trichlorophenol,   ethanolamine  salt 

2,4,5-Trichlorophenol,   sodium  salt 

2,4-,6-Trichlorophenol 

2,'i,6-Trlchlorophenol,   potassium  salt 

■^Herbicides  and  plant  hormones: 

2-sec-Amyl-4,6-dinltrophenol 

2-sec-Butyl-'i,6-dinltrojiienol 

2-sec-Butyl-A,6-dinltrophenol,   triethanolamine 
salt. 

3-(p-Chlorophenyl)-l,l-dimethylurea  (CMU) 

2-(2,<i-Dichlorophenoxy)ethanol  hydrogen  sulfate, 
sodium  salt. 

3-(3,A-Dlchlorciphenyl)-l,l-dlmethylurea 

l,2-Dihydro-3,6-pyridazlnedione  (Maleic  hydrazlde) 

l,2-Dihydro-3,6-pyrldazinedione,   sodium  salt 

4,6-Dlnitro-o-cresol  (DNOC) 

"i,6-Dinltro-o-ore6ol,  sodium  salt  (Sinox) 

Isopropyl  carbanllate  ( Isopropyl  N-phenyl- 

carbamate)  ( IPC) . 
Isopropyl-3-ohlorocarbanllate  (Isopropyl  N- 
( 3-chlorophenyl) carbamate)  ( CIPC) . 
"■Naphthalene-  and  naphthyloxyacetic  acid 
derivatives: 

1- Naphthaleneaoetamide 

1-Naph'thaleneacetic  acid 

1-Naphthaleneacetic  acid,  methyl  ester 

1-Naphthaleneacetic  acid,  sodium  salt 

1-Naph'thyloxyacetic  acid 

2- Naphthyloxyacetic  acid 

N-l-Naph thy Iph thalamic  acid 

7-0xebicyclo[2' .2. 1]  heptane-2,3-dioarboxylio 
acid,  disodium  salt  (Endo-thal). 


<;32. 
181,  532. 

455. 
221. 

201. 


529. 
201. 


253. 
569. 


253. 

253. 

432. 

240,  432,   595. 

240. 

240,   253,   307, 

432. 

240. 

229,   240. 

229,   240,    242, 

253, 

432. 

240. 

432. 

566. 

106,    117,   211, 

229, 

232,   234,   312,   340,  493,   499, 

552. 

221,   252,  466. 

221,    252. 

221. 

221,   229,   240, 

459. 

252. 

252,  468,   523, 

550. 

510. 

221,   252. 

252. 

45,    523. 

12. 

252. 

12. 

253. 

529. 

253,   320. 

455. 

455. 

12. 

12. 

157,  473. 

157,   221,  473 

63,  316. 

63,   316,  364. 

63,  316. 

63,  414. 

364. 

364,  414. 

455. 

585. 

SYNTHETIC  ORGANIC  CHEMICALS,  1956 


139 


TABLE  25B.- -Synthetic  organic  ch 
States   product  ion   or 


Is:    Pesticides   and  other    organic   agricultural    chemicals  for   which  United 
were   reported,    ident i fied  by  manufacturer ,    7956--Continued 


Chemical 

Manufacturers 

'  identification  numbers 

(according  to 

Ust  in  table  27) 

PESTICIDES  AND   OTHER  ORGANIC  AC5RICULTURAL 

CHEMICALS,  CYCLIC— Continued 

ifflerbioldes  and  plant  hormones — Continued 

Phenoxyaoetio  acid,  salts,  and  derivatives: 

C2-Chloro-<4-methoxyphenoxy)  acetic  acid. 

509. 

dime thy lamine  salt. 

(4-Chloro-2-methylphenoxy) acetic  acid 

221. 

»(2,4-Dichlorophenoxy) acetic  acid  (2,-^-0) 

143, 

221,  252,  260, 

509 

523. 

»(2,4-Dlohlorophenoxy) acetic  acid  esters: 

Butoxyethoxypropyl  Z.'i-dlchlorophenoxy- 

221, 

523. 

acetate. 

Butoxyethyl  2,4-dichlorophenoxyacetate 

63. 

Butoxypolypropyleneglycol  2,'i-dichloro- 

252. 

phenoxyacetate. 

wn— B\i-tyl  2 .4-dichlorophenoxyacetate -— — — — _™ 

63 

U3,  221,  252, 

509, 

523,  542. 

sec— Butvl  2  4— dlchloronhenoxyacetate — — -# — 

260. 
63. 

Ethyl  2,4-diohlorophenoxyacetate 

2-Ethylhexyl  2,4-dichlorophenoxyacetate 

523. 

»Iso-ootyl  2,'i-diohlorophenoxyacetate 

1A3, 

221,  252,  260, 

509 

523,  542. 

jtlsopropvl  2  A— dichlorophenoxyacetate— — — — — 

63, 
143. 

221,  252,  260, 

509, 

523,  532. 

Tetrahydrofurfuryl  2,'4-dichlorophenoxy- 

532. 

acetate. 

»(2,4-Dlchlorophfenoxy) acetic  acid  salts: 

(2, 4-Dichlorophenoxy) acetic  acid,  dlmethyl- 

amine  salt. 
(2, 4-Diohlorophenoxy) acetic  acid,  sodium  salt- 

63, 

143,  409,  532. 

221, 

252. 

»(2,4,5-Trlchlorophenoxy)acetic  acid  (2,'i,5-T)  — 

143, 

221,  252,  260, 

509 

523. 

»(2,4,5-Trichlorophenoxy)acetio  acid  esters: 

Butoxyethoxypropyl  2,'i,5-trichlorophenoxy- 

221, 

523. 

acetate . 

Butoxyethyl  2,4,5-trichlorophenoxyacetate 

63. 

Butoxypolypropyleneglycol  2,A,5-trlohloro- 

252. 

phenoxyacetate . 

221, 
260, 

252,  260,  509, 
509. 

523 

seo-Butyl  2,4,5-trlchlorophenoxyacetate 

2-Ethylhexyl  2,A,5-trichlorophenoxyacetate 

523. 

»Iso-octyl  2,4,5-trichlorophenoxyacetate 

143, 

221,  252,  260, 

542 

Isopropyl  2,'i,5-trichlorophenoxyacetate 

221, 

260,  523. 

pgji'^Y]^  2  A   5— trichloronhenoxvacetate —————— 

143, 
523. 

542. 

Polyethyleneglycol  2,4, 5-trlchlorophenoxy_ 

acetate . 

Tetrahydrofurfuryl  2,4,5-trichloraphenoxy- 

532. 

acetate. 

*pjigj]y2jDercurY  acetate  (PMA)  — -— — — —————————____ 

455. 

240,  242,  253, 

307, 

432. 

N-Tolylphthalamic  acid 

(2,4, 5- Trichlorophenoxy) propionic  acid 

41A. 

^Insecticides: 

Aldrln  (Hexaohloro-hexahydro-endo,  exo-dimethano- 

481. 

naphthalene) . 

Allethrin  {Allyl  homolog  of  Cinerin  I) 

157, 

266,  469. 

468. 
336. 

l,l-Bis(p-chlorophenyl)-2-nitrobutane 

336. 

2-(p-tert-Butylphenoxy)-l-methylethyl-2-chloro- 

455. 

ethyl  sulfite  (Aramite). 

Chlordan  ( Octachloro-tetrahydro-methanoindan) 

304. 

515 

Ghl    h   1    hi   h       If   t 

252, 
252. 

523. 

2-Cyclohexyl-4,6-dinltrophenol 

1,2-Dihromoethylbenzene  (Styrene  dibromide) 

252. 

4,4'-Dichlorobenzilic  acid 

608. 

1, l-Dichloro-2,2-biB(p-chlorophenyl) ethane 

320, 

566. 

C  DDD) . 

Q_  1— Dlchloro— 2  2-bis(D—ethYlphenyl)  ethane — 

566. 

320. 
223. 

0-(2,4-Dichlorophenyl)  0,0-diethylphosphoro- 

thioate. 

Dleldrin  (Hexachloro-epoxy-octahydro-endo, 

481. 

exo-dimethanonaphthalene) . 

0,0-Diethyl  0-(2-isopropyl-4-methyl-6- 

608. 

pyrlmldinyl) phosphorothioate . 

0, 0- Dimethyl  0- ( p-nltrophenyl) phosphorothioate 

221. 

(Methyl  parathlon) . 

Endrln  ( Hexachloro-epoxy-octahydro-endo, 

304, 

481. 

endo-dimethanonaphthalene) . 

0- Ethyl  0- ( p-nltrophenyl) benzenephosphonothioate 

378. 

(EPN). 

Heptachlor  (Heptachloro-tetrahydromethano- 

304. 

indene. 

»Hexachlorooyolohexane  (Benzene  hexachloride) 

189, 

215,  303,  320, 

468, 

473,  523,  550,  561, 

587. 

Lindane 

*68. 

140 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  25B.- -Synthetic  organic  chemicals:    Pesticide 
States  production   or   sales 


reported,    identified  by  manufactt 


al   cheti 
.    1956- 


icals    for  whi 
■Continued 


PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL 
CHEMICALS,  CYCLIC— Continued 

^Insecticides — Continued 

»Parathion  (0,0-Diethyl  O-(p-nltrophenyL)- 
phosphorothioate) . 

Thanlte  (Isobomyl  thiooyanatoaoetate) 

Toxaphene  (Chlorinated  camphene) 

»l,l,l-Triohloro-2,2-bis(p-chlorophenyl) ethane 
(DDT). 
l,l,l-TrichIoro-2,2-bls(p-methoxyphenyl) ethane 
( Kfethoxy chlor) . 
»Rodentlcldes: 

2-Plvaloyl-l,3-ind£mdione - - 

Trinltrobenzene-anlllne  complex 

Warfarin  (3-(Aoetonylbenzyl)-<i-hydroxycoumarln)  — 

PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL 
CHEMICALS,  ACYCLIC 

»Fuialgants : 

»Bromomethane  (Methyl  bromide) 

Chloropicrin 

l,2-Dibromo-3-chloropropane 

1,3-Dichloropropene,  1,2-dichloropropane 
(D-D  mixture) . 

N-Methyldithiocarbamic  acid,  sodium  salt 

"Fungicides  and  seed  disinfectants: 

3is-l,4-bromoacetoxy-butene-2  

Bis( dimethylthiocarbamoyl) disulfide  ( Thiram) . ^ 

Cadmium  succinate 

Calcium  undecenoate  (Calcium  hendecenoate) 

Copper  undecenoate  (Copper  hendecenoate) 

Dimethyldithiocarbamic  acid,  ferric  salt 
( Ferbam) . 

Dimethyldithiocarbamic  acid,  manganese  salt 

"Dimethyldithiocarbamic  acid,  sodium  salt 

"Dimethyldithiocarbamic  acid,  zinc  salt  (2iram)>- 

Disodlum  cyanodithiolmidocarbonate 

Ethylene  bis(dlthiocarbamic  acid),  manganese 
salt  (Manzate) , 
"Ethylene  bis(dithiocarbamlc  acid),  disodium 
salt  ( Nabam) . 
Ethylene  bis( dithiocarbamic  acid) ,  zinc  salt 
( Zineb) . 

3-Ethyl-(mercurithio)-l,2-propanediol 

Ethylmercury  acetate 

Ethylmercury  chloride 

Ethylmercury  phosphate 

2-Methoxyethylmercury  acetate 

Sodium  undecenoate  (Sodium  hendecenoate) 

Tetralodoethylene 

Zinc  undecenoate  (Zinc  hendecenoate) 

"Herbicides: 

2-Chloroallyl  diethyldithlocarbamate 

N, N-Diallyl-2-chloroaoetamide 

2,2-Dichloropropionic  acid,  sodium  salt 

Diethyl  dlthiobis(thlonoformate) 

Methanearsonic  acid,  disodium  salt 

Trichloroacetic  acid,  sodium  salt  (TCA) 

"Insecticides: 

Aliphatic  thiooyemates 

0,0-Diethyl  S-(ethylthio)methylphOBphoro- 

dithioate. 
0,0- Dimethyl  0-(2-methoxycarbonyl)lsopropenyl- 
phosphate. 
"Ethyl  pyrophosphate  (Tetraethyl  pyrophosphate) 

(TEPP). 
Malathion  (S-(l,2-Bis(ethoxycarbonyl) ethyl) 
0,0-dimethylphoEphorodithioate) . 

Metaldehyde 

Ootamethylpyrophosphoramlde  (GMPA) 

"Rodentlcides:  Sodium  fluoroacetate 

"Soil  conditioners:  Vinyl  acetate-maleic  acid, 
modified. 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


221,  260,  534,  537,  546. 


335. 

212. 


184,  221,  272,  296,  320,  461,  523,  550,  556,  608. 
253. 


581. 
581. 
456,  469. 


252,  272,  546,  597. 
110. 

481. 
481. 

189,  253. 

595. 

564. 
511. 
232,  41A. 

253,  307,  569. 

569. 

201,  324,  449,  569,  585. 

201,  253,  307,  324,  449,  455,  569,  585. 

242. 

253,  566. 


30,   253, 

566,   569. 

253,    566, 

569. 

253. 

240,    253, 

569. 

240,    253. 

253. 

307. 

414. 

511. 

414,    511. 

221. 

221. 

252. 

221,    569. 

45,    595. 

252,  468. 

566. 

537. 

481. 

106,    532, 

546,    561 

537. 

336. 

221. 

221,    569. 

221. 

^  Manufacturers'  identification  numbers  for  thiram  are  given  in  table  21B.  Statistics  are  shown  In  table  21A. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


141 


Miscellaneous  Synthetic  Organic  Chemicals 


TABLE  26B.- -Synthetic  orga 


chemicals:    M iscel laneous  chemicals    for   which  United  States  product ioti 
were   reported ,    ident  if  ied  by  manufacturer  ,    19S6 


[Miscellaneous  chemicals  for  which  separate  statistics  are  given  in  table  26A  are  marked  below  with  an 
asterisk  ( «) ;  chemicals  not  so  marked  do  not  appear  in  table  26A  because  the  reported  data  are  accepted  in 
confidence  and  may  not  be  published.  Manufacturers'  identification  numbers  shown  below  are  taken  from 
table  27.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification 
number  with  the  designated  product] 


Chemical 


Ktanufaoturers '    identification  numbers 
(according  to  list  in  table  27) 


MISCELLAMEOUS  CHEMICALS,    CYCLIC 

l-Acetyl-2-thiohydantoin 

5-Amlno-2-benzimidazolethiol 

2-Aminobenzothlazole 

i-Amino-5-(ethoxymethyl)-2-methylpyrimidine 

3-(2-Aminoethj-l)-2-thiohydantoin 

Anisylacetic  acid 

Anisyl  chloride 

Anisyl  cyanide 

Benzoic  acid  salts : 

Calcium  benzoate 

•Sodium  benzoate,  tech 

♦Sodium  benzoate,  U.S.P 

All  other 

Benzoin  oxime 

Benzothiazole 

Benzoyl  peroxide 

Benzoylresorcinol 

S-Benzyl-'i-me  thy  lumbelllfe  rone 

Biological  stains 

4,-;  '-Bis[phenylureido]  -2,2  '-stilbenedisulfonlc  acid- 
Boron  fluoride-phenol  complex 

Butoxysafrole 

Butyl  benzoate 

2 (and  3)-tert-Butyl-'i-methoxyphenol 

tert-Butyl  peroxybenzoate 

4-tert-Butylpyrocatechol 

Butyrolaotone — 

♦Camphene 

Carotene 

Central!  te-1  (N,N'-Dlethyl-N,  N'-diphenylurea) 

Chemical  indicators : 

Dlbromo-o-cresolsulfonphthalein  ( Bromocresol 
purple ) . 

Dibromothymolsulfonphthalein  (Bromothymol  blue) 

Phenolsulfonphthaleln  (Phenol  red) 

Tetrabromo-m-cresolsulfonphthalein  ( Bromocresol 

green) . 
Tetrabromophenolsulfonphthalein  (Bromophenol  blue) 

Thymolphthalein 

All  other 

♦Chemical  reagents : 

Aurintricarboxylic  acid 

Barium  diphenylamine  sulfonate 

Diphenyl  carbazide 

Diphenyl  carbazone 

Diphenylthiocarbazone  (Dithiazone) 

a,a-Dipyridyl 

Girard  reagents,  P  and  T 

N-(1-Naphthyl)ethylenediamine  dihydrochloride 

Nitrosophenylhydroxylamine  (Cupferron) 

Phloroglucinol 

Potassium  biphthalate 

Quinhy  drone 

Sodium  biphthalate 

Sodium-2,6-dlohloroben2enoneindophenol 

Sulfosallcyllc  acid,  reagent 

All  other 

5 -Chloro-a , a-bls [3, 5-diohloro-2-hydroxyphenyl]  -o- 

toluenesulfonic  acid. 
Chlorophyll  and  chlorophyllins : 
Chlorophyll ; 

Copper  fixed 

Not  fixed 

Chlorophyllins : 

Sodium-copper 

Sodium-iron 

Sodium-magnesium 

Sodium-potassium-oopper 

All  other 

Cholesterol ■ 

Cumene  hydroperoxide 

Cyclohexanone  peroxide 


266. 
477. 
218. 
560. 
266. 
337. 
337. 
337. 

504. 

504. 

221,   303,  468,   50i. 

31. 

218,   477. 

537. 

120,    208,   492. 

510. 

520. 

67,    506. 

510. 

320. 

337. 

529. 

4A3. 

208. 

252. 

510. 

212,    253,   X. 

606. 

492,    585. 

477,    506. 

477,    506. 
364,   477,    506. 
477,    506. 

477,   506. 

364. 

67,   427,   477,    506. 


477. 
477. 


477,    564. 
477,    560. 


477. 
560. 
216,    364,    477,    506,    581. 


606. 
606. 

606. 

606. 

606. 

351,    519. 

606. 

519. 

212. 

208. 


142 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  26B.--Synf/iefic  ortani 


chemicals:    Kiscel laneous   chemicals    for   which  United  State 
reported,    identified  by  manufacturer,    7956- -Continued 


production  or  sales 


MISCELLANEOUS  CHEMICALS,  CYCLIC--Contlnued 

Cyolohexene-l,2-dicarboxylic  acid  (Tetrahydro- 

phthalic  acid),  dlsubstituted,  polyester  salts : 

Barium  salt 

Barium  cadmium  salt 

Cadmium  salt 

•Cyclopropane 

Decahydronaphthalene   (Deoalin) 

Dlazodinitrophenol 

2,5-Di-n-butoxyanlllne   (Aminohydroqulnone,   dibutyl 
ether). 

p-Dlbutoxybenzene   (Hydroquinone,   dibutyl  ether) 

»2,6-Di-tert-butyl-p-cresol: 

•Food  grade 

»Tech T--- 

2,5-Dl-tert-butylhydroquinone 

S.'i-Dichlorobenzoyl  peroxide 

l,3-niohloro-5,5-dimethyLhydaiitoin 

p-(Dlchlorosulfain^l)benzoic  acid   (Halazone) 

Dicyclohexylammonlum  nitrite 

2, 5-Diethoxy aniline 

p-Diethoxybenzene 

7-DiethylaiQino-<»-methylcoumarin 

6,6  -Dihydroxy-<i,4'-diinethoxybenzciphenone  and  3,3'- 
dlsulfonio  acid. 

3,5-Diiodosalicylic  acid 

Diisopropylbenzene  hydroperoxide 

2, 5-Dimethoxy aniline 

p-Dimethoxybenzene   (Dimethyl  ether  of  hydroquinone) 
'i,'i'-Dinitrocarbanllide-'i,6-diinethyl-2-pyrlmldlnol- 

Dloxane   (1,4-Diethylene  oxide) 

N,N-Dlphenylbenzidine 

6-Ethoxy-m-anol  (Propenylmethylguaethol) 

Ethylene  carbonate 

Ethylene  glycol  monophenyl  ether 

Ethylene  g]jcol  terpinyl  ether 

Ethylene thiourea 

2-Ethylhexyl  octylphenyl  phosphite 

Ethyl  hydrocaffeate 

Ethyl  2-phenylbutyrate 

Fenchone 

•Flotation  reagents : 

Dicresyldithlophosphoric  acid 

Dicresyldlthiophosphoric  acid,  ammonium  salt 

Dicresyldithlophosphoric  acid,  sodium  salt 

Dl-o-tolylthlourea 

Rosin  amine 

•Thiooarbanilide  (Diphenylthiourea) 

Furan  derivatives; 

Furfural  (2-Furaldehyde) 

Furoic  acid 

Tetrahydrofurfuryl  alcohol 

Gallic  acid,  tech 

Gallic  acid,  sodium  salt 

Gasoline  antioxidants  and  inhibitors : 

p-Butylami  nophenol 

2,6-Di-tert-butylphenol - 

N,N'-Di-sec-butyl-p-phenylenediamine 

N, N'-Disalicylidene-l,2-propanediamine 

All  other 

Glyceryl  p-aminobenzoate 

Glycidyl  phenj'l  ether 

•Hexamethylenetetramine,  tech 

Hydrocinnamlc  acid 

5-(p-Hydroxyethyl)-4-methylthiazole 

2-Hydroxy-'i-methoxybenzophenone 

Isopropylcresols 

•Lubricating  oil  additives: 

Alicyclic  compounds,  sulfurized 

ALkyl  phenyl  thlophosphates  and  salts 

2,2'-Dlhydroxy-5,5'-di-tert-octylphenol  mono- 
sulfide,  barium  salt. 

Dodecylamidophthalic  acid,  calcium  salt 

Heterocyclic  compounds,  sulfurized 

Octyl  formol 

Oil-soluble  petroleum  sulfonate,  ammonium  salt 

Oil-soluble  petroleum  sulfonate,  barium  salt 

•Oil-soluble  petroleum  sulfonate,  calcium  salt 

•Oil-soluble  petroleum  sulfonate,  sodium  salt 

All  other 


hfanufacturers '   identification  numbers 
(according  to  list  in  table  27) 


451. 

451. 

232,   451. 

156,    257,   374,    564. 

253. 

212. 

443. 

443. 

367,   443,   481. 

367,   443,    481. 

443. 

120. 

179. 

456. 

550. 

443. 

443. 

248,   492,    520. 

510. 

581. 

212. 

4A3. 

365,   443. 

X. 

529. 

477. 

365. 

405. 

252,    529. 

212. 

585. 

223. 

365. 

564. 

369. 

537. 

537. 

450,   537. 

253,    537. 

212. 

221,    506,    537. 

495. 

495. 

468,    495. 

440,    564. 

564. 

253. 

480. 

253,   443. 

253,   443. 

443. 

391. 

481. 

142,    253,   421,   478,    504,    550,    560. 

365. 

560. 

510. 

327,    337. 

373,    508. 

222. 

537. 

338. 

222. 

481. 

373. 

278,    373,    538,    576. 

222,    331,    373,    576. 

42,    85,    188,   278,    311,    331,    408,   419,   463,    508,    527 

552,    566. 

221,   468,   537. 

SYNTHETIC  ORGANIC  CHEMICALS,  1956 


143 


TABLE   26B.--Syntheti 


r^anic   chemicals:   M  iscel  laneo^^   ^.•^•••^^^^^    .«.    ™..*w..  -..-.- 
were  reported,    identified  by  manufacturer ,    1956--Conti 


chemicals   for  which  United  States  product i 


Manufacturers'   identification  numbers 
(according  to  list  in  table  27) 


MSCELLAMEOUS  CHHCCALS,    CYCLIC— Continued 

p-Menthane 

p-Menthyl  hydroperoxide 

p-ltethoxyphenol 

ci-Methylbenzylphenol 

Msthylcyclohexanol 

Methyl  gallate 

2,2  '-Hfethylenebis  ["i-ohlorophenol]    ( Diohlorophene )  — 
2,2  '-Methylenebis  [3,'i,6-trichlorophenol]    (Hexa- 
chlorophene ) . 

2,2'-Methylenedi-p-oresol 

Kfethylglucoside 

l-Methylol-5,5-diinethylhydantoin 

l-Msthyl-2-pyrrolidone 

Methyl  terpinyl  ether 

4-Methyluiiibelliferone 

Morpholine 

MDrpholine  oleate 

Morpholine  toluenesulfonate <-- 

»Naphthenlc  acid  salts : 

Aluminum  naphthenate 

Barium  naphthenate 

Cadmium  naphthenate 

■»Calcium  naphthenate 

Cobalt  lead  manganese  naphthenate 

»Cobalt  naphthenate 

»Iron  naphthenate 

»Lead  naphthenate 

Lithium  naphthenate 

*Manganese  naphthenate 

Ifercury  naphthenate 

Nickel  naphthenate 

Rare  earth  naphthenates 

Sodium  naphthenate 

Strontium  naphthenate 

«Zlnc  naphthenate 

All  other 

Octylphenyl  acid  phosphate 

Organic  mercury  compounds : 

Phenyl  mercuric  borate 

Phenyl  mercuric  salicylate 

Pyridyl  mercuric  acetate 

All  other 

Phenolthlosulfonic  acid 

Phenoxypolyethoxyethanol 

Phenylmagnesium  bromide 

♦Photographic  chemicals : 

5-Amlno-l,3,A-triazole 

»Benzotriazole 

Catechol  (Pyrocatechin) 

Chlorobenzotriazole 

2,<t-Diaminophenol  hydrochloride 

p-Diazo-N-benzyl-N-ethylaniline,  zinc  chloride 

salt. 
p-Diazoohloro-N,N-diethylaniline,  zinc  chloride 
salt. 

«p-Diazo-N,N-diethylaniline,  zinc  chloride  salt 

p-Diazo-N,N-diethyl-m-phenetidine,  zinc  chloride 

salt. 
p-Diazo-N,N-dimethylaniline,  zinc  chloride  salt--- 

Diazodiphenylamine  sulfate 

p-Diazo-N-ethyl-N-hydroxyethylaniline,  zinc 

chloride  salt. 
p-Diazo-N-hydroxyethyl-N-methylaniline,  zinc 

chloride  salt. 
p-Diazo-N-methyl-o-toluidine,  zinc  chloride  salt-- 

N,N-Diethyl-p-phenylenediamine  hydrochloride 

N,N-Diethyltoluene-2,5-diamine,  monohydrochloride- 
2,5-Dihydroxybenzenesulfonic  acid  (Hydroquinone- 

sulfonic  acid),  sodium  salt. 
N-Ethyl-N-hydroxyethyl-p-phenylenediamlne  sulfate- 
N-Ethyl-N-(p-methanesulfonamidoethyl)toluene-2,5- 
diamine  sulfate. 

Hydroquinone  ( Hy droquinol ) 

N-Citydroxyphenyl)  glycine 

3-Hydroxyphenylurea 

A-Methoxy-l-naphthol 

p-Methylaminophenol  sulfate  (Metol) 

5-Mb  thy Ibenzotriazole 


2L2,  369. 

212,  369. 

39,  365,  4^3. 

252. 

468. 

440. 

337. 

337. 

337. 

476. 

253. 

510. 

212. 

248,  520. 

373,  405,  529. 

47,  549. 

73. 

229,  234,  552. 

X. 

232,  499. 

117,  229,-  232,  234,  312,  340,  493,  499,  552,  570. 

229,  234,  552. 

106,  117,  229,  232,  234,  250,  312,  340,  493,  499, 

552,  570. 

229,  232,  234,  340,  493,  499,  552. 

106,  117,  229,  232,  234,  248,  312,  340,  493,  499, 

552,  570,  X. 
499. 

106,  117,  229,  232,  234,  312,  340,  493,  499,  552, 

570. 

229,  240. 
499. 
499. 

338,  493. 
499. 

117,  229,  232,  234,  312,  340,  493,  499,  552,  570. 
552. 
223. 


307. 

240, 

307. 

564. 

240, 

307, 

564. 

510. 

510. 

216. 

218. 

218, 

477, 

510,    581. 

367. 

218. 

213. 

218, 

581. 

218. 

218, 

394, 

506,   510,    581 

218, 

X. 

218, 

394, 

581. 

218. 

218, 

394, 

581. 

218, 

X. 

218, 

X. 

443. 

443. 

477. 

394. 

443. 

443, 

445. 

394. 

218. 

443. 

213, 

440 

477. 

477. 

144 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  XB. -Synthetic    organic   chemicals:    K  iscel  laneous 
were  reported ,    ident if ied  by 


meals 
jfactu 


which  United  States   producti 
I956--Continued 


Manufacturers'  identification  nujnbers 
(according  to  list  in  table  27) 


MISCELLANEOUS  CHEMICALS,  CYCLIC- -  Continued 

•Photographic  chemicals--Continued 

2-Kfethylthiazoline 

6-Nitrobenz  imidazole 

Phenethylresorcinol 

4-Phenylpyrocatechol 

Phthalic  acid,   lead  salt,   dibasic 

Phytol 

Pinene 

Piperonjl  butoxide 

Plperonylcyclonene 

Polyethylene  terephthalate 

P-Propiolactone 

Propylene  carbonate 

«n- Propyl  gallate 

Pyrogallol  (.Pyrogallic  acid) 

8-Quinolinol,   zinc  salt 

p-Quinone 

•Research  chemicals : 

Arallsyl  chlorides 

Aralkyl  esters 

Araliyl  sulfides 

DDT,  carbon  14 

Organic  borates 

Pyridine  derivatives 

All  other 

•Rosin  acid  salts : 

Aluminum  resinate 

Calcium  lead  resinate 

Calcium  resinate 

Cobalt  resinate 

Copper  resinate 

Iron  resinate 

•Lead  resinate 

Manganese  resinate 

Zinc  resinate 

All  other 

Salicylanilide 

Salicylic  acid,  lead  salt 

Silicones 

Sulfosalicylic  acid 

Tall  oil  fatty  acid  chloride 

•Tall  oil  salts  (Linoleic-rosin  acid  salts): 

Barium  zinc  tallate 

Calcium  tallate 

•Cobalt  tallate 

Copper  tallate 

Iron  tallate 

•Lead  tallate 

Lead  manganese  tallate 

•Manganese  tallate 

Zinc  glyceryl  tallate 

Zinc  tallate 

•Tanning  materials,  synthetic: 

Bisphenol- formaldehyde,  bisulfite  type 

Cresol- formaldehyde  sulfonate,  sodium  salt 

1-Naphthalenesulfonic  acid,  formaldehyde  con- 
densate and  salt. 
•2-Naphthalenesulfonic  acid,  formaldehyde  con- 
densate and  salt. 
2-Naphtholsulfonlc  acid,  formaldehyde  condensate, 
sodium  salt. 

Phenol- formaldehyde,  sulfonate 

Styrene-maleic  anhydride  interpolymer,  partial 

sodium  salt. 
Sulfonyldiphenolsulfonic  acid,  formaldehyde  con- 
densate. 

Terpene  hydrocarbons 

1,2,3,'i-Tetrahydronaphthalene  (Tetralin) 

Tstrahydrothiophene 

Tetraphenyl  tin 

•Textile  chemicals,  other  than  surface-active  agents 

N-Benzyl  (and  N,N-dibenzyl)-p-sulfanilic  acid 

Diphenyl-l,2-propanediamine 

l-Phenyl-3-pyrazolidone 

Protalbinic  acid 

Saccharide  bisulfite 

Stearamidemethylpyridinium  chloride 

Sulfurated  phenol 

All  other 

2,2'-Thiobis[4,6-dichlorophenol] 

Toluquinone 


218. 

218,   -477. 

367. 

4k3. 

3b. 

606. 

212,    X. 

157. 

157. 

253. 

515. 

<;05. 

3(A,    AAO,    V-,3,    504. 

4^0,    564. 

193. 

440,    443. 

254. 
254. 
254. 
566. 
568. 
512. 
31,    161,    175,    216,   410,   412,   450,   477,    512,    581. 

8,    564. 

111. 

8,    196,    232. 

117,    232,   493. 


8,    232,    234,    340. 

8,    232,    340. 

8,    232,    234,   X. 

8. 

253. 

389. 

244,    591. 

560. 

510. 


234. 
229, 
106, 
117, 
117, 
106, 
232, 
106, 
499. 
234. 


499. 

117,  229,  232,    234,   312,   340,    493,   499,    570. 

234. 

232,  234,  493. 

117,  229,  232,    234,    312,    340,   493,   499,    570. 

234,  312,  340. 

117,  229,  234,    312,    340,   493,   499,   570. 


424. 

510,    608. 
424. 

290,   424,    506,    566,    589. 

424. 

424,    566. 
253. 

510. 

253. 
253. 
222. 
468. 

510. 

X. 

608. 

288. 

X. 

253. 

510. 

510,   X. 

221. 

443. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


145 


TABLE  26B. -Synthetic   organic  chemicata:    Miscellaneous   chemicals    for   which  United  States  product i 
were  reported,    identified  by  manufacturer,    J956--Continued 


Chemical 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


MISCELLANEOUS  CHEMICALS,  CYCLIC--Continued 

0-Tolylbiguanide 

Tri-tert-amylphenyl  phosphite 

3,i,^'-Trichlorocarbanilide 

N-Triohloromelamine 

Trioxane 

Triphenyl  phosphite 

Xanthophyll 

o-Xenylbiguanide 

l-Vinyl-2-pyrrolldone,  monomer 

1- Vinyl-S -py rrolidone ,  polymer 

MISCELLANEOUS  CHEMICALS,  ACYCLIC 

•Acetaldehyde 

Aoetals 

Acetamide 

•Acetic  acid,  synthetic,  100^ 

»Acetlc  acid  salts: 

•Aluminum  acetate 

Aluminum  subacetate 

•Ammonium  acetate 

Barium  acetate 

Cadmium  acetate 

Calcium  acetate 

Chromium  acetate 

Cobalt  acetate 

Copper  acetate 

Lead  acetate 

•Lead  subacetate 

•Magnesium  acetate 

Manganese  acetate 

Mercuric  acetate 

Nickel  acetate 

•Potassiiim  acetate 

Silver  acetate 

Sodium  acetate 

•Zinc  acetate 

All  other 

•Acetic  anhydride,  100^: 

From  acetaldehyde 

From  ethylene 

From  recovered  acetic  acid  by  the  vapor-phase 

process. 
From  acetic  acid  (other  than  recovered)  by  the 
vapor-phase  process. 
Acetin: 

Mono 

Di 

Tri 

•Acetone : 

•By  fermentation 

From  cumene 

•From  isopropyl  alcohol 

All  other 

Acetone  semicarbazone 

Acetonitrile 

Acetonylacetone  (2,5-Hexaiiedione) 

Acetyl  bromide 

Acetyl  chloride 

Acetylenedicarboxylic  acid,  monopotassium  salt — 

tert-Acetylenic  glycols 

Acrolein  (Acrylaldehyde) 

Acrylamide 

Acrylates,  above  ethyl 

Acrylic  acid 

Acrylic  acid,  calcium  salt 

•Acrylonitrile 

•Adipic  acid 

Adiponitrile 

Aldol  (Acetaldol) 

Alkyl  cocoamine  phosphates 

Alkylene  oxides 

Allsyl  sodium  phosphates 

Allsyl  sulfides 

AUcyl  tetrasilicates 

Allyl  alcohol 

Allyl  glyceryl  ether 

Allyl  glycidyl  ether 

AIJ^l  isothiocyanate,  nonperfume  grade 

Aluminum  isopropoxlde  (Aluminum  isopropylate ) 


221. 
221. 
221. 
511. 

221. 
606. 
221. 
510. 
510. 


212, 
227. 
320. 
212, 

320, 
560, 
320, 
335, 
320, 
320, 

«<;, 

117, 
320, 
232, 
320, 
320, 
234. 
320, 
234, 
335, 
564. 


253,  336,  342,  411,  443,  444,  475,  529,  620. 


336,  342,  443,  475,  529,  620. 

424,  529,  537,  560. 

564. 

335,  564. 

564. 

335,  564. 

335,  560. 

537,  564. 

234,  335,  340. 

335,  340,  529. 

320,  335,  485. 

335,  560,  564. 

335,  340. 

564. 

340,  564. 

529,  560,  564. 

320,  335,  529,  560. 

,  320,  335,  529,  560,  564. 


212. 

529. 

212, 

443, 

475. 

212, 

443, 

475. 

359. 

359, 

536. 

359, 

443. 

145, 

336, 

342. 

212, 

552, 

558. 

284, 

443, 

481,    529 

227, 

475. 

297. 

512, 

529. 

529. 

477. 

353, 

365. 

506. 

108. 

481, 

529. 

537. 

566. 

515, 

566. 

566. 

221, 

515, 

529,    537 

250, 

253, 

506. 

250, 

253. 

529. 

338. 

252. 

338. 

222. 

529. 

481. 

481. 

481. 

365, 

581. 

95, 

218, 

321. 

146 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  26B. -Synthetic   organic   chemical-^:    Xiscr  I  laneon^  chemicals    for   which  United  Statei   production 
were   reported,    identified  hy  manufacturer ,    1956--Continued 


Ifenufacturers '  identification  numbers 
(according  to  list  in  table  27) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

♦Amines ; 

Ally  land  ne 

Anulamine 

»n-Butylamine 

tert-Butylamine 

Coconut  oil  amine 

Diallylamine 

Diamylamine 

Di-n-butylamine 

Diethi'lamine 

Diethylamine  hydrochloride 

2,2'-Diethyldihexylamine 

Diethylenetriamine 

N,N-Diethyl-l,3-propanediai!iine 

Diisobutylamine 

Diisopropylamine 

♦Dimethylamine 

Dime thy lamlne  hydrochloride 

Dime thy lamine  sulfate 

Dimethyloctadecylamine  (Stearyldimethylamine) — 

N,N-Dimethyl-l,3-propanediamine 

Di-n-propylamine 

Dodecylamine 

Ethylamine,  mono 

•Ethylene diamine 

Hexadecy lamlne 

Hexamethylenediamine 

3,3'-Imlnoblspropylamine 

Isobutylamine 

Isopropylamine 

2-Methylally lamlne  (3-Amlnc-2-methylpropene) 

*Me thy lamlne,  mono 

Methylamlne,  mono,  hydrochloride 

Ootadecylamine 

«Octy lamlne 

Polyethyleneamines 

Propylamine ,  mono 

Propylenediami  ne 

Soybean  oil  amine 

Tallo^pf  amine 

Tallow  amine,  hydrogenated 

Triamy lamlne 

Tributy lamlne 

Trlethy lamlne 

Triethylenetetramine 

Trimethylamlne 

Trlme thy lamlne  hydrochloride 

Trimethylamlne  sulfite 

Tripropy lamlne 

All  other 

Amine  acid  reaction  products 

2-Amlno-l-butanol 

Aminoethylethanolamlne  (2-(2-Aminoethylamlno)ethanol) 

2-Amino-2-ethyl-l,3-propanedlol 

Aminoguanidine  bicarbonate 

Ami noguanl dine  sulfate 

2-Amino-2-(hydroxymethyl)-l,3-propanediol  (Trls- 
(hydroxyinethyl)aminome thane) . 

2-Amino-2-methyl-l,3-propanediol 

2-Amino-2-methyl-l-propanol 

3-Amino-l-propanol 

An^l  acetates,  90^,  primary: 

Normal 

Isoamyl 

Mixed  isomers 

Amyl  acid  phosphates 

Ancl  alcohols,  100;^: 
Unmixed : 
Primary : 

Normal  (n-Butylcarbinol) 

Isoamyl  (3-Msthylbutanol-l) 

Secondsiry : 

Pentanol-2   (Methylpropylcarbinol) 

Tertiary : 

Amyl  (2-hfethylbutanol-2) 

Mixed: 

Fusel  oil,  crude 

Fusel  oil,  refined 

Other  than  fusel  oil: 

Primary,  mixed 

Secondary,  mixed 


481,    581. 

585. 

<W.3,    529, 

585. 

221,    566. 

309,    328. 

481,    581. 

585. 

529,    585. 

529,    585. 

86,   414. 

529. 

252,    529. 

537. 

585. 

585. 

253,    336, 

566. 

86. 

566. 

309,    566. 

529,    537. 

585. 

309. 

529,    585. 

252,   405, 

529,    550. 

309. 

250,   X. 

537. 

585. 

529,    585. 

581. 

253,    336, 

566. 

86. 

309. 

309,    529, 

566. 

529. 

585. 

529. 

309. 

309,   328. 

309,    328. 

585. 

585. 

529,    585. 

252,    529. 

253,    336, 

566. 

253. 

320. 

585. 

405,    566. 

481. 

336. 

529. 

336. 

262. 

510. 

336. 

336. 

336. 

537. 

336,    342, 

564. 

91,   409. 

529,    585. 

378. 

585. 

145,    157 

335. 

585. 

585. 

336. 

145,    157 

336,   342 

444,    529 

585. 

585. 

SYNTHETIC  ORGANIC  CHEMICALS,  1956 


147 


TABLE  26B. --Syntheti 


ic   chemicals:    tfisceltaneous    chemicals    for   which  Uniteri  States   production   or    sales 
ere   reported,    identified  by  manufacturer ,    J956-- Continued 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

Amyl  alcohols,  lOO^t- -Continued 
Mixed — Continued 

Other  than  fusel  oil — Continued 

Primary-secondary,  mixed 

Primary-secondary-tertiary,  mixed 

All  other 

An^rl  aldehydes 

Amyl  ether 

Amyl  ethyl  ketone 

Amyl  mercaptan  (1-Pentahethlol) 

Asnyl   nitrate 

Azelaic  acid 

a,a'-Azodiisobutyronltrile 

Barium  salt  of  polyphosphorio  acid 

Behenic  acid 

»Bls(2-chloroethyl)  ether  (Dichloroethyl  ether), 
all  grades. 

Bis(P-chloroethyl)  vinyl  phosphonate-^ 

Bis(ohloroisopropyl)  ether  (Dichloroisopropyl  ether)- 

Bis(2,6-dimethyl-<i-heptyl)  maleate 

Bis(2-ethylhexyl)  hydrogen  phosphite 

2,2-Bis[ethylthiopropane]    (Ethyl  mercaptol) 

Bis(lauryltriinethylainmonlum)  polythionate 

Biuret 

Boron  fluoride  ethyl  ether  complex 

Bromal 

N-Bromoacetamide 

a-Bromolaurlc  acid 

N-Bromosuccinimide  (Sucelnibromimide) 

1, 4.- Butane  dlol 

1,2,'4-Butanetriol 

3-Buten-2-one  (Methyl  vinyl  ketone) 

l-Buten-3-yne 

l-Butoxyethoxy-2-propanol 

"Butyl  acetates,  90%: 
Primary: 

♦Normal 

ISO 

Secondary 

Mixtures 

Butyl  acid  phosphates 

N-tert-Butylaorylamlde 

»Butyl  alcohols,  100!^: 
Primary: 

♦Normal  (n-Propylcarbinol) 

Iso  (Isopropylcarblnol) 

Secondary  (Methylethylcarblnol) 

Tertiary  (Trimethylcarblnol) 

Mixtures 

Butylamlnoethanol 

Butylene  glycol  (1,2-  and  1,3-  mixture) 

Butyl  ether  (Di-n-butyl  ether) 

Butyl  glycidyl  ether 

tert-Butyl  hydroperoxide 

n-Butyl  isocyanate 

Butyl  lactate 

Butyl  maleate 

tert-Butyl  peroxide  (Di-tert-butyl  peroxide) 

tert-Butyl  peroxyaoetate 

tert-Butyl  peroxyisobutyrate 

Butyl  vinyl  ether,  crude 

2-Butyne-l,^-diol,  crude 

Butyraldehyde 

Butyraldehyde  oxlme 

Butyric  acid 

Butyric  acid,  sodium  salt 

Butyric  anliydride 

Butyryl  chloride 

Calcium  d-saccharate 

Capric  acid  (n-Decylic  acid) 

Caprolc  acid 

Caprolactam  (2-Qxohexamethylenimlne) 

Capryl  chloride  (Decanoyl  chloride) 

Caprylic  acid  (Octanoic  acid) 

Caprylic  acid  salts: 

Aluminum  caprylate -^ 

Sodium  caprylate 

Triethanolamine  trioaprylate 

Zinc  caprylate 

»Carbon  disulfide 


585. 

585. 

475,    585. 

402. 

585. 

481. 

585. 

4-80. 

488. 

486. 

499. 

334. 

252,   405,    529, 

550, 

565. 

221. 

252,    529,    565. 

510. 

223. 

221. 

335. 

485. 

234,   320. 

343. 

216. 

253. 

216. 

510. 

510. 

306. 

253. 

529. 

145,    336,    342, 

443, 

475, 

529. 

409,   443. 

342,   X. 

475. 

378. 

537. 

145,    227,    253, 

336, 

342, 

443,   475, 

529,   620 

444,    475,    529, 

620, 

X. 

481,   X. 

481. 

444,    475. 

585. 

475. 

529. 

481. 

208. 

267. 

336. 

102. 

208,  481. 

208. 

208. 

510. 

510. 

444,    529. 

506. 

443,   475,    529. 

330. 

31,   443,    529. 

402,    468. 

306. 

100,    507. 

353,   402,    529. 

253,    506. 

468. 

100,    507. 

527. 

86. 

510. 

86,    335. 

168,    178,    189 

275 

287, 

561. 

148 

TABLE  26B. -Synthetic 


UNITED  STATES  TARIFF  COMMISSION 

ic   chemicals:    Miscellaneous  chemicals    for   which  United  States   producti 
ere   reported,    ident if ied  by  manufacturer ,    1956- -Continued 


KaSCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 


•Cellulose  esters : 

•Cellulose  acetate 

Cellulose  acetate  butyrate 

Cellulose  acetate  propionate 

Cellulose  nitrate 

Cellulose  propionate 

•Cellulose  ethers : 

Ethyl  cellulose 

Ethyl  hydroxyethylcellulose 

Methyl  cellulose 

•Sodium  carboxymethylcellulose,  100% 

Sodium  carboxymethylhydroxyethylcellulose 

•Chloral  (Trichloroaoetaldehyde) 

Chloroaoetaldehyde  dimethyl  acetal 

•Chloroacetic  acid,  mono 

Chloroacetic  acid,  mono,  derivatives : 

Butyl  monochloroacetate 

Ethyl  monochloroacetate 

Methyl  monochloroacetate 

Sodium  monochloroacetate 

Chloroacetone  (l-Chloro-2-propanone) 

Chloroaoetyl  chloride 

•2-Chloro-N,N-dimethylethylamlne  (Dime thy laminoethyl 
chloride)  hydrochloride. 

2-Chloro-N,N-dimethylpropylamine  hydrochloride 

3-Chloro-N,N-dimethylpropylamine  hydrochloride 

Chlorodimethylsilanes 

2-Chloroethyl  acetate 

2-Chloroethyl  methyl  ether  (2-Chloroethoxymethaiie)— - 

Chloromaleic  anhj-dride 

Chloromethyl  methj'l  ether 

p-Chloropropionlc  acid 

Chloropropionitrile 

f:-Chloropropionyl  chloride 

Chloropropyl  thiophosphate 

N-Chlorosuccinimide  (Succinichlorlmide) 

2-Chlorotriethylamine  (Diethy laminoethyl  chloride) 
hydrochloride . 

Chlorotrimethylsilane 

5-Chlorovaleronltrile 

P-Chlorovinyl  ethyl  ketone 

Choline 

Citric  acid,  by  fermentation,  refined 

•Citric  acid  salts : 

Ammonium  citrate 

Ammonium  citrate,  dibasic 

Barium  citrate 

Calcium  citrate 

Ferric  ammonium  citrate 

Ferric  citrate 

Manganese  citrate 

•Potassium  citrate 

Sodium  citrate 

All  other 

Coconut  oil  amide 

Crotonaldehyde 

Crotonlc  acid  (2-Butonic  acid) 

a-Cyanoacetamide 

Cyanoacetic  acid 

Cyanuric  acid 

Dlacetone  alcohol  (^-Hydroxy-4-methyl-2-pentanone)-- 

Diallylcyanamide 

2-Dlbutylaminoethanol 

Dlbutyl  fumarate 

Dibutyl  maleate 

l,3-Dibutyl-2-thlourea 

Dibutyl  tin  methoxide 

Dlchloroacetaldehyde 

Dichloroacetic  acid 

Dichloroacetic  acid,  methyl  ester 

Dichloroacetyl  chloride 

Dichlorodiethylsilane  (Diethyl  silicon  dichloride)-- 

Dichlorodimethylsilane 

Dichloroethyl  formal  (Bis(2-chloroethoxy)methane)  — 

Dichloromethylvinylsilane 

l,3-Dichloro-2-propanol  (Glycerol  dichlorohydrin) 

Dl(l,2-epoxypropane) amine 

Diethoxymethylsilane 

Diethyl  adipate 

Diethy laminoethanethlol  hydrochloride 

2-Diethylaminoethanol 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


81,  212,  253,  ^3,  475. 

443. 

443. 

212,  253. 

475. 

212,  252. 

212. 

252,  253. 

128,  212,  565. 

212. 

296,  523,  561. 

510. 

128,  212,  221,  252,  266,  468. 

221. 

221,  252,  365. 

252,  330. 

252. 

477. 

252. 

206,  272,  414,  456,  490. 


272, 

490. 

272. 

591. 

365. 

314. 

506. 

468, 

566. 

422. 

537. 

477. 

480. 

216, 

506. 

272, 

414,  459,  490 

244. 

253. 

456. 

566. 

306, 

368. 

306, 

564. 

560. 

485. 

306. 

306, 

564. 

306, 

564. 

564. 

306, 

560,  564. 

306, 

560,  564. 

31, 

560,  X. 

309. 

443, 

529. 

529. 

330. 

252, 

330. 

477. 

481, 

529. 

537. 

585. 

221. 

221, 

529,  558. 

585. 

X. 

561. 

330. 

330. 

330. 

244 

244. 

529 

24^ 

477 

253 

244 

102 

356 

529 

585. 

SYNTHETIC  ORGANIC  CHEMICALS,  1956 


149 


» 


TABLE  2(!H. --Synthetic   organic  cheniicaJs: 
were  reported, 


Miscel laneous  chemicals 
identified  by  manufactv 


for   which  United  States   produ 
-er.    W56--Continued 


Manufacturers'   identification  numbers 
(according  to  list  in  table  27) 


MISCELLANEOUS  CHEIGCAI^,    ACYCLIC- -Continued 

Diethylami  noethoxyethanol 

2-Dlethylamlnoethyl  methacrylate 

Diethylanilnopropionitrile 

Diethyl  sec-butylethylinalonate 

Dlethyloarban^rl  chloride 

Diethyl  carbonate 

Diethyl  diethylmalonate   (Diethyl  malonlc  ester) 

»Dlethylene  glycol 

Diethylene  glycol  chloroformate 

Diethylene  glycol  di-n-butyl  ether 

Diethylene  glycol  diethyl  ether  (Bis(2-eth03cyethyl) 

ether). 

Diethylene  glycol  dimethyl  ether 

Diethylene  glycol  monobutyl  ether  (2-(2-Butoxy- 

ethoxy ) ethanol ) . 

Diethylene  glycol  monobutyl  ether  acetate 

Diethylene  glycol  morioethyl  ether  (Carbitol)    (2-(2- 

Ethoxyethoxy)ethanol) . 

Diethylene  glycol  monoethyl  ether  acetate 

Diethylene  glycol  monomethyl  ether  (2-(2-Methoxy- 

ethoxy( ethanol) . 

Diethyl  (ethoxymethylene)malonate 

Diethyl  ethylisoanylmalonate 

Diethyl  ethyl nwlonate  (Ethyl  malonlc  ester) 

Di-2-ethyIhexyl  maleate  (Diootyl  maleate) 

Diethylhydroxylamine  oxalate 

Diethyl  maleate 

•Diethyl  malonate  (Malonio  ester) 

Diethyl  1-methylbutylmalonate 

Diethyl  oxalate  (Ethyl  oxalate) 

Diethylthlophosphoryl  chloride 

l,3-Diethyl-2-thiourea 

Dlglycerol 

Diglyoolic  acid 

2,'i-Dihydroxy-3,3-dimethylbutyric  acid,  y-l^'^'tone 

(Pantolactone) . 

Diisobutyl  ketone  (Isovalerone) 

2-Dlisopropylaminoethanol 

Diisopropyl  peroxydicarbonate  (Isopropyl  percar- 

bonate) . 

l,3-Diisopropyl-2-thiourea 

»2-Dimethylaminoethanol 

Dime thy lamino-2-propanol 

P -Dime  thy laml nop ropionitrile 

N-(3-Dimethylamlnopropyl)oleamide 

N,N-Dimethylformamide 

Dlmethylglyoxime 

2,6-Dlmethyl-4-heptanol  (Diisobutyloarbinol) 

2,5-Dimethylhexanediol-2,5 

2,5-Dimethyl-2-hexyiiediol-2,5 

1,1-Dimethylhydrazine 

Dimethyl  hydrogen  phosphite 

3,6-Diinethyl-<i-octynediol-3,6 - 

Dime thy lolurea 

1,3-Dimethylurea 

Dloleyl  maleate 

Dipropylene  glycol 

Dlpropylene  glycol  methyl  ether 

Dithio-oxamide  (Rubeanic  acid) 

Dodecenylsuccinic  anhydride 

Epichlorohydrin 

Erucic  acid 

»Ethanolamines : 

«Monoethanolamlne  (2-Aminoethanol) 

»Diethanolamine  (2,2'-Aminodiethanol) 

»Triethanolamine  (2,2',2"-NitrllotriethanDl) 

Ethanolamlne  (mono)  salt  with  formaldehyde 

Ethanolamlne  residue 

Ethoxymethylenemalononltrile 

P-Ethoxyproplonltrlle 

»Ethyl  acetate,  85^6 

Ethyl  acetoacetate 

Ethyl  acid  phosphates 

Ethyl  aery late 

«Ethyl  alcohol,  synthetic 

Ethylamlnoethanols,  mixed 

Ethyl  bromoacetate 

2-Ethyl-l-butanol  (sec-Hexyl  alcohol) 

a-Ethylbutyraldehyde 

a -Ethylbutyric  acid  (Diethylaoetic  acid) 

a-Ethyloaproaldehyde  (2-Ethylhexaldehyde) 


253 

537 

456 

459 

157. 

422 

456 

252 

405 

529 

550 

565. 

473. 

529. 

529. 

39. 

252, 

529, 

550 

529. 

252, 

529, 

550. 

529. 

252, 

529, 

550. 

330. 

422, 

456. 

422, 

456. 

529. 

477. 

529, 

537. 

252, 

330, 

422, 

456. 

422, 

456. 

157, 

266, 

336. 

221, 

537. 

585. 

327. 

253. 

529, 

537. 

529. 

585. 

473. 

585. 

529, 

585, 

566. 

585. 

537. 

253. 

253, 

566. 

477. 

529. 

108. 

108. 

561. 

223. 

108. 

253. 

266, 

585. 

221. 

252, 

475, 

529, 

565. 

252. 

564. 

102, 

506. 

252, 

481, 

529. 

334. 

252, 

354, 

405, 

529, 

550. 

252, 

354, 

405, 

529, 

550. 

252, 

354, 

405, 

529, 

550. 

566. 

405. 

330. 

537. 

145, 

274, 

336, 

342, 

443,  529. 

157, 

529. 

378. 

529, 

566. 

186, 

212, 

284, 

44^, 

481,  529,  X 

585. 

252. 

443, 

475, 

529. 

529. 

529. 

529, 

444. 

150 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  26B.  "Synthetic   orga 


chemicals: 
e  reported , 


liscellaneous  , 
ident i  f  ied  by 


ucals    for   whi<^h  United  States  product  ion 
jfacturer ,    1956- -Continued 


Manufacturers'   identification  numbers 
(according  to  list  In  table  27) 


KOSCELLANEOUS  CHEMICALS,    ACYCLIC--Continued 


a-E-ftiylcaprolc  acid  (Z-Ethyl-l-hexoic  acid) 

«»-Ethylcaproic   {2-Ethyl-l-hexolo)   acid  salts: 

flliiTn-JTmrn  a-ethylcaproate 

Barium  a-ethylcaproate 

Cadmium  a-ethyloaproate 

•Calcium  a-ethylcaproate 

■•Cobalt  a-ethylcaproate 

Iron  a-ethylcaproate 

»Lead  a-ethylcaproate 

Lithium  a-ethylcaproate 

•Manganese  a-ethyloaproate 

Rare  earths  a-ethylcaproate 

Strontium  a-ethylcaproate 

•Zinc  a-ethylcaproate 

Zirconium  a-ethylcaproate 

a-Ethylcapryl  acetate 

Ethyl  carbonate 

Ethyl  chlorofonnate 

Ethyl  cyanoacetate 

Ethylene,  from  ethyl  alcohol 

Ethylene  chlorohydrin  (2-Chloroethanol) 

Ethylene  cyanhydrin  (Hydracrylonltrile) 

•Ethylene  glycol 

Ethylene  glycol  diacetate 

Ethylene  glycol  dl-n-butyl  ether 

Ethylene  glycol  diethyl  ether 

Ethylene  glycol  dlformate 

Ethylene  gljcol  dimethyl  ether  (1,2-Dimethoxyethane)- 

Ethylene  glycol  monobutyl  ether  (2-Butoxyethanol) 

Ethylene  glycol  monoethyl  ether  (Cellosolve)  (2- 

Ethoxyethanol) . 
Ethylene  glycol  monoethyl  ether  acetate  (2-Ethoxy- 

ethyl  acetate) . 
Ethylene  glycol  monomethyl  ether  (2-lfethoxyethanol)— 
Ethylene  glycol  monomethyl  ether  acetate  (2-Methoxy-- 
ethyl  acetate) . 

•Ethylene  oxide 

•Ethyl  ether: 

•Tech 

U.S.P- 

Absolute 

•Ethyl  formate 

N-Ethylglyclne 

2-Ethyl-l,3-hexanediol 

2-Ethyl-l-hexanol 

Ethyl  a-hydroxylsobutyrate 

Ethyl  a-hydroxylsovalerate 

2-Ethyl-2-(hydroxymethyl)-l,3-propanedlol 
( Trimethylolpropane ) . 

Ethyl  lactate 

2-(Ethylmercapto)ethanol 

2-Ethyl-'i-methyl-l-pentanol 

2-Ethyl-2-nltro-l,3-propanediol 

Ethyl  propionate 

Ethyl  propyl  nitrate 

•Ethyl  silicate  (Tetraethoxysilane) 

Ethyl  sulfate  (Diethyl  sulfate) 

2-Ethynyl-2-butanol 

•Fats  and  oils,  chemically  modified: 

Castor  oil,  phosphated 

Vegetable  oils,  bromlnated 

All  other 

Fatty  acids,  chemically  modified: 

a-Bromo(lauric-stearic)  acids 

Castor  oil  fatty  acids,  dehydrated 

Stearic  acid,  dehydrated 

•Fatty  acid  esters  not  included  with  plasticizers 
or  surface-active  agents: 

Butyl  palmitate 

Ethylene  glycol  mono-oleate 

Iso-octyl  ester  of  tallow  fatty  acids 

Isopropyl  nyristate 

Isopropyl  oleate 

Isopropyl  palmitate 

Isopropyl  stearate 

Methyl  caprate 

Methyl  caproate 

Methyl  caprylate 

Methyl  ester  of  coconut  oil 

kfethyl  ester  of  tallow 

Methyl  12-hydroxystearate 


443,  529. 


499. 

499. 

229, 

232, 

234, 

493, 

499. 

229, 

232, 

234, 

3L2, 

493,  499. 

234. 

229, 

232, 

234, 

389, 

493,  499. 

493. 

229, 

232, 

234, 

499. 

499. 

499. 

229, 

232, 

234, 

499. 

229, 

499. 

529. 

157. 

157. 

252, 

330. 

157, 

257. 

314, 

529. 

529, 

537, 

566. 

252, 

354, 

405, 

529, 

550,  565,  X 

529. 

252, 

529. 

39. 

529. 

39, 

216. 

529, 

550. 

252, 

529, 

550. 

529. 

252, 

529, 

550. 

529. 

252, 

354, 

405, 

529, 

550. 

186, 

212, 

284, 

444, 

529. 

157, 

374, 

564. 

157, 

564. 

336, 

353, 

402, 

409, 

529. 

537. 

529. 

443, 

444, 

529. 

566. 

566. 

262, 

475. 

537. 

585. 

444. 

336. 

353, 

402, 

409. 

480. 

95, 

273, 

529. 

529. 

512. 

378. 

402, 

524. 

248, 

402. 

253. 

96. 

566. 

359 

527 

532 

X. 

337 

359 

359 

337 

359 

359 

100 

100 

100 

100 

328 

151 

96, 

488. 

SYNTHETIC  ORGANIC  CHEMICALS,  1956 


151 


TABLE  26B. -Synthetic 


rganic   chemicals: 
were   reported. 


leous  chemica Is 
ed  by  manufactv 


for   which  United  St  a 
■er,    19.56- -Continued 


MISCELLANEOUS  CHEMICALS,  ACYCLIC- -Continued 

»Fatty  acid  esters  not  included  with  plasticizers 
or  surface-active  agents — Continued 

Methyl  n^ristate 

Polyethoxyethyl  castor  oil  ether 

Polyethoxyethyl  castor  oil  ether,  hydrogenated- 
»Fatty  and  synthetic  higher  alcohols : 

Decanediol 

«Decyl  alcohol 

3,9-Dlethyl-6-tridecanol — 

Dodecyl  alcohol  (Lauryl  alcohol) 

7-Ethyl-2-inethyl-4-hendecanol 

5-Ethyl-2-nonanol 

»l-Hexadecanol  (Cetyl  alcohol) 

1-Octadeoanol  (Stearyl  alcohol) 

cis-9-Octadecen-l-ol  (Oleyl  alcohol) 

1-Tridecanol 

All  other 

»Flotation  reagents : 
Dithiophosphates : 

Potassium  dihexyl  dithiophosphate 

Sodium  di-sec-butyl  diethyl  dithiophosphate — 

Sodium  di-sec-butyl  dithiophosphate 

Sodium  diethyl  dithiophospliate 

Sodium  dihexyl  dithiophosphate 

Sodium  diisopropyl  dithiophosphate 

Fatty  amine  salts : 

Butylammonium  oleate 

Coconut  oil  amine  acetate 

Cottonseed  oil  diethylenetriamlne  acetate 

Fish  oil  diethylenetriamlne  acetate 

Octadecyl  amine  acetate 

Tallow  amine  acetate 

Tallow  amine  acetate,  hydrogenated 

Xanthates : 

Potassium  amylxanthate 

Potassium  sec -amylxanthate 

Potassium  sec-butylxanthate 

Potassium  ethylxaiithate 

Potassium  hexylxanthate 

Potassium  isopropylxanthate 

Sodium  n-butylxanthate 

Sodium  sec-butylxanthate 

Sodium  ethylxanthate 

Sodium  isopropylxanthate 

»Foniialdehyde,  37%  HCHO  by  weight 


Formamide 

»Formlc  acid,  90^6 

»Foniilc  acid  salts : 

•Aluminum  formate 

»Anmoniiim  formate 

Calcium  formate 

Chromic  formate 

Lead  formate 

Nickel  formate 

Potassium  formate 

Sodium  formate : 

Crude 

Refined 

All  other 

Fumaric  acid 

Fumaryl  chloride 

Gluconic  acid,  tech 

Glutamic  acid,  nonmedicinal 

Glycerol,  synthetic 

Glycerol  carbonate 

Glycerol  a-chlorohydrin  (3-Chloro-l,2-propanediol)- 

Glycidol - 

Glycine  (Amlnoacetio  acid),  tech 

Glycine  ethyl  ester  hydrochloride 

Glycolic  acid  ( Hydroxyacetic  acid) 

Glycolonitrile 

Glyoxal 

Guanidine  hydrochloride 

4-Guanyl-l-isonitrosoguanyl-l-tetrazene 

Guanylurea  (Amldinourea)  phosphate 

Guanylurea  sulfate 

»Halogenated  hydrocarbons : 

1-Bromobutane  (n-Butyl  bromide) 

2-Bromobutane  (sec-Butyl  bromide) 

Bromochlorinated  butadiene 


Manufacturers'  identification  numbers 
(according  to  list  in  table  27) 


100. 
547. 
547. 

597. 
102, 
529. 
102, 
529. 
529. 
102, 
1C2, 
253, 
284. 
102,  298,  334,  566 


253,  284,  444,  508,  529. 
253,  298. 


177,  253,  334. 
253,  334. 
334. 


537. 
537. 
537. 
537. 
537. 
537. 

585. 
309. 
537. 
537. 

309,  537. 
309,  328. 
309,  328. 

252,  537. 

252. 

252. 

252. 

252. 

252. 

88,  537. 

252. 

252,  537. 

252,  537. 

142,  221,  227,  253,  262,  330,  336,  354,  373,  411, 

421,  466,  475,  478,  504,  550,  553,  560,  566. 
253. 

253,  378,  504,  564. 

378,  424,  439,  529,  608. 

86,  320,  490. 

262. 

510. 

389. 

234,  340. 


212,  504,  560. 

320,  335,  358,  560. 

31. 

506. 

506. 

306. 

379. 

252,  455,  481,  566. 

405. 

86,  365,  443. 

569. 

266. 

266. 

253. 

537. 

529. 

459,  537,  589. 

56. 

537. 

537. 

6,  252. 

6,  252,  422,  456. 

364. 


152 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  26B. -Synthetic   organic  chemicals:  Miscellaneous  chemicals    for   which  United  State 
were  reported,    identified  by  manufacturer ,    1956- -Continued 


Kfenuf aoturers ■  identification  numbers 
(according  to  list  in  table  27) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC--Continued 

»Halogenated  hydrocarbons — Continued 

l-Bromo-2-chloroetliane  (Ethylene  ohlorobromide) 

Bromochlorome thane 

l-Bromo-3-chloropropane  ( Trimethylenechlorobromide 

Bromoethane  (Ethyl  bromide) 

1-Bromohexadecane  (Cetyl  bromide) 

l-Bromo-2-methylpropane  (Isobutyl  bromide) 

l-Bromo-octadecane 

1-Bromopentane  (n-Amyl  bromide) 

2-Bromopentane  (1-Methylbutyl  bromide) 

1-Bromopropane  (n-Propyl  bromide) 

2-Bromopropane  (Isopropyl  bromide) 

3-Bromopropene  (Allyl  bromide) 

3-Bromopropyiie 

Bromotriohlorome thane 

Bromotrifluorome thane 

»Carbon  tetrachloride 

•Chlorinated  paraffins : 

Less  than  25%  chlorine 

»35-645S  chlorine - 

65$  or  more  chlorine 

1- Chlorobutane  (n-Butyl  chloride) 

l-Chloro-l,l-difluoroe thane 

Chlorodifluorome thane 

*Chloroethane  (Ethyl  chloride): 

Tech 

U.S.P - 

»Chlorof orm : 

»Tech 

»U.S.P — - 

»Chloromethajie  (Methyl  chloride)  : 

Crude 

Refined,  refrigerant  grade 

l-Chloro-3-methylbutane  (Isoamyl  chloride) 

2-Chloro-2-methylpropane  (tert-Butyl  chloride) 

3-Chloro-2-methylpropene  (Methallyl  chloride) 

Chloropentafluoroe thane 

1-Chloropentane  (n-Anorl  chloride) 

Chloropentanes ,  mixed  isomers 

2-Chloropropane  (Isopropyl  chloride) 

3-Chloropropene  (Allyl  chloride) 

Chlorotrifluoroethylene 

Chlorotrifluorome thane 

Dibromodifluorome thane 

1,2-Dibromoethane  (Ethylene  dibromlde) 

Dlbromomethane  (\fethylene  bromide) 

l,2-Dlbromo-l,l,2,2-tetrafluoroethane 

1,'i-Dichlorobutane 

Dichlorodifluorome thane 

»l,2-Dichloroethane  (Ethylene  dlchloride) 

Dlchlorofluorome thane 

»Dichloromethane  (Ifcthylene  chloride): 

Crude 

Refined,  refrigerant  grade 

Dichloropentanes,  mixed  isomers 

1,2-Dichloropropane  (Propylene  dichloride) 

2,3-Dichloropropene 

Dichlorotetrafluoroe thane 

1,1-Difluoroe thane 

1,1-Difluoroethylene 

Difluorotetrachloroe thane 

Diiodomethane  (Methylene  iodide) 

Hexaohloroe thane 

lodoethane  (Ethyl  iodide) 

Iodoform 

lodomethane  (Methyl  iodide) 

Lauryl  chloride 

Pentachloroe thane 

1,1,2,2-Tetrabromoethane  (Acetylene  tetrabromide) — 
1,1,2,2-Tetrachloroethane  (Acetylene  tetrachloride) 

*Tetrachloroethylene  ( Perchloroethy lene ) 

1,1,1-Triohloroe thane  (Methyl  chloroform) 

1,1,2-Triohloroethane  (Vinyl  trichloride) 

»Trichloroe thy lene 

Triehlorofluorome thane 

1,2,3-Trichloropropane 

Trichlorotrifluoroe thane 

Trlfluorovlnyl  chloride,  polymerized 

»Vinyl  chloride  ( Chloroe thy lene ) ,  monomer 

Vinyl  fluoride 

Vinylidene  chloride,  monomer 

All  other 


252. 

252,  546. 

252,  272. 

252,  272. 

6,  252. 

6. 

6,  253,  510. 

6,  252,  477. 

6,  422,  456. 

6,  252,  477. 

6,  252. 

6,  252. 

510. 

252. 

252,  253. 

189,  215,  252,  333,  523,  561,  564. 

468,  478,  X. 

212,  468,  523. 

523. 

529. 

320. 

253,  320. 

186,  212,  252,  253,  381,  480,  481. 
252,  381. 

215,  252,  253,  333,  523,  597. 

252,  333,  523,  597. 

591. 

39,  252,  253,  333,  523. 

422. 

6,  477. 

266,  581. 

320. 

6,  585. 

585. 

252. 

481. 

253,  320. 
253,  320. 
252,  253. 

252,  363,  546,  561. 
252. 

253. 
253. 

253,  320. 

221,  252,  405,  480,  523,  529,  550,  565. 
320. 

215,  252,  597. 
252,  253,  333,  523. 
585. 

252,  529,  565. 
569. 

253,  320. 
320. 
320. 
253. 

19. 

364. 

6,  477,  564. 

19. 

6,  564,  581. 

6,  253,  492,  494,  510. 

253. 

252. 

253,  473. 

189,  252,  253,  473,  523,  593. 

252. 

529. 

252,  253,  468,  473,  593. 

253,  320. 
481. 

253,  320. 
468. 

221,  252,  333,  449,  455,  515,  523,  529. 

253. 

252. 

6,  102. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


153 


TABLE  26B. -•Synthetic   organic   chemicals:    Miscellaneous   chemicals    for   which  United  States  product i 
were   reported ,    identified  by  manufacturer ,    J956--Continued 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


MISCBXLANEOUS  CHEMICALS,  ACYCLIC— Continued 

3-Heptanol 

2-Heptanone  (Methyl  anyl  ketone) 

3-Heptanone  (Ethyl  butyl  ketone) 

n-Hexadecane 

1-Hexadecene 

Hexadecenylsuccinic  anhydride 

Hexamethylenediammonium  adipate 

2,5-Hexanedione-carbon  disulfide 

Hexyl  acetate  mixture 

Hexyl  alcohol 

Hexyl  alcohol  mixture 

n-Hexyl  ether 

Hydrazine  and  salts 

Hydrogenated  tallow  amide 

N-2 - Hydroxye thy lace  tnmi  de 

a-I^droxyisobutyric  acid  esters,  mixed 

o-Hydroxyisobutyronitrile  (Acetone  cyanhydrln)-- 

l-Hydroxy-3-methyl-2-butanone 

2-(Hydroxymethyl)-2-methyl-l,3-propaiiediol 

( Trimethylolethane ) . 
2-(i5^droxymethyl)-2-nitro-l,3-propanediol  (Tris- 
(hydroxyme thyl)nitrome thane) . 

3-Hydroxy-3-methylpenten-l-yiie-'i 

N-Hydroxymethylstearamide  (N-Methylolstearamlde) 

P,P'-Imlnodipropionltrile 

Inositol  hexanitrate 

Isethionic  acid  (2-Hydroxyethanesulfonio  acid)-- 

Isoascorbic  acid 

Isobutyraldehyde 

Isobutyric  acid 

Isobutyric  anhydride 

*Iso-octyl  alcohol  (6-kfethyl-l-heptanol) 

Iso-octyl  thioglycolate 

Isopropanolamines : 

Ifonoisopropanolamine 

Diisopropanolajnine 

Triisopropanolamine 

Mixed ■' 

Isopropoxypropylamlne 

Isopropyl  acetate 

»Isopropyl  alcohol  (Isopropanol) : 

910^ 

100^ 

Isopropylamlnoethanol 

Isopropyl  chloroformate 

Isopropyl  ether 

Itaconic  acid,  esters,  and  salts 

»Lactic  acid,  100^: 

»Edible 

<ijfedicinal 

♦Technical 

Lactic  acid  salts: 

Aluminum  lactate 

Calcium  lactate 

Sodium  lactate 

Strontium  lactate 

All  other 

Lac tide 

Lactonitrile 

Laurie  acid,  barium  cadmium  salt 

»Lauroyl  chloride 

Lauroyloxyacetic  acid 

Lauroyl  peroxide 

Lauryl  acid  phosphates 

Lead  soaps  of  oxidized  hydrocarbons 

Levulinlc  acid 

♦Llnoleic  acid  salts : 

Ammonium  llnoleate 

»Calclum  llnoleate 

♦Cobalt  llnoleate 

Copper  llnoleate 

Iron  llnoleate 

♦Lead  llnoleate 

Lead  manganese  llnoleate 

Manganese  llnoleate 

Potassium  llnoleate 

Zinc  llnoleate 

♦Lubricating  oil  additives : 

Barium  dl(lauryl-oapryl)  dithiophosphate 

Chloronaphtha  xanthate 

High  molecular  weight  hydrocarbons  and  their 
phosphorus  derivatives. 


529. 
529. 
529. 
102. 
102. 
102. 
253. 
335. 
475. 
529. 
475. 
529. 
218, 
309. 
494, 
566. 
566, 
422. 
262. 


306. 
253. 
537. 
547. 
510. 
375. 
444. 
443. 
4A3. 
284, 
356. 

252, 
252, 
252, 
529. 
537. 
529, 

529. 
227, 
585. 
157, 
284, 
306. 

253, 
253. 
253, 

86. 

300, 

86, 

564. 

31, 

289. 

537. 

248. 

120, 

373. 

120, 

378. 

118. 

495. 

117, 
117, 
117, 
229. 
234. 
117, 
232, 
117, 
232. 
232. 

373, 
221. 
508. 


550,  560. 
529. 


338,  508. 


529. 
529. 
529. 


284,  481. 


473. 
4S1,  529. 


289,  388. 
289,  388. 


388. 
360,  439,  560. 


468,  510. 
208. 


232. 

150,  232,  493,  499. 

232,  234,  492. 


232,  234. 

492. 

232,  234,  340. 


537,  576. 


154 

TABLE  26B. --Synthetic  organic 


UNITED  STATES  TARIFF  COMMISSION 

chemicals:    Miscellaneous   chemicals    for   which  United  States  producti 
e  reported,    identified  by  manufacturer ,   19 56 --Continued 


MISCELLANEOUS  CHEMICALS,  ACICLIC--Continued 

»Lubricatlng  oil  addltives--Contlnued 

Isoanyl  octyl  acid  orthophosphate 

Lauiyl  and  dlethylamlnoethyl  polymethaorylates- 

Oxldized  hydrocarbons 

Phosphosulfurized  mineral  oil 

Sulfoohlorinated  lard  oil 

Sulfochlorinated  sperm  oil 

Sulfurized  lard  oil 

*Sulfurized  sperm  oil 

Zinc  hexyl  dithiophosphate 

All  other 

Magnesium  methj'late 

Maleic  acid 

Maleic  acid,  tribasic  lead  salt 

Maleic  anhydride 

Maleic  liquid 

Malic  acid 

Malonic  acid 

Mannltol 

Mannitol  hexanltrate 

Ifesityl  oxide 

Kfethacrylamlde 

Kfethacrylates,   above  methyl 

Methacrylic  acid 

Methacryllc  acid,   sodium  salt ■ 

Jfcthallyl  Isocyanate 

Jfcthallyl  isothlocyanate 

•Methanol,   synthetic 


Msthoxybutanol 

Methoxypolyethylene  glycol 

3-Methoxypropionitrile 

3-Jfethoxypropylamlne 

Kfethoxytriglyool  acetate 

»Methyl  acetate 

Methyl  acetone  acetal 

Kfethyl  acid  phosphates 

Methyl  acrylate,  monomer 

Jfethylal  ( Dime thoxyme thane) 

Methyl  borate 

Iitethyl-l-buten-3-yiie   ( Isopropenylacetylene ) 

2-Methyl-3-butynol-2 

Methyl  cyanoacetate 

N,N'-Jfcthylenebisalanlne 

N,N'-Methylenebls-stearamlde 

^fcthyl  ether  (Dimethyl  ether) 

Methyl  ethyl  ketone   (2-Butanone) 

Methyl  ethyl  ketone  mixture 

Msthyl  ethyl  ketone  peroxide 

Ifethyl  ethyl  ketoxime 

Methyl  formate 

N-Methylglucamine 

N-Methylglyclne 

Jfethyl  glycolate   (Methyl  hydroxyacetate) 

4-Methyl-2-hexanone 

1-lfcthylisobutylcarbinol  ('i-tfcthyl-2-pentanol) 

1-Methylisobutylcarbinyl  acetate   (A-Jfethyl-2-amyl 
acetate) . 

Methyl  magnesium  bromide 

Methyl  methacrylate,   monomer 

Methyl  methoxyacetate 

2-Iifethyl-2-nltro-l,3-propanediol 

2-lifethyl-2-nltro-l-propanol 

2-lfethyl-2,'4-pentanediol  (Hexylene  glycol) 

'i-Iifethyl-2-pentanone   (Methyl  Isobutyl  ketone) 

2-lfethylpentenol 

3-Methyl-l-pentynol-3--- 

tfethylpolyethanolamlne 

2-Vfethyl-2-n-propyl-l,3-propanediol 

Methyl  sulfate   (Dimethyl  sulfate) 

N-Methyltaurlne 

2-Ktethylvaleraldehyde  (2-Methylpentaldehyde) 

Methyl  vinyl  ether 

Maoochlorlc  acid 

Muoonic  acid  (2,4-Hexadienedioio  acid) 

2-Nltro-l-butanol 

Nitroe thane 

Nitrome thane 

1-Nltropropane 

2-Nitropropane 

Nonyl  alcohol 


Manufacturers '  identification  numbers 
(according  to  list  In  table  27) 


223. 

253. 

118. 

373. 

2^,   373. 

248. 

248,  338. 

248,  343,  373,  576. 

373,  537,  576. 

373,  468,  481,  537,  576. 

169. 

360,  506,  558. 

389. 

221,  466,  506. 

260. 

360,  506. 

73. 

547. 

547. 

481,  529. 

566. 

253,  566. 

566,  X. 

566. 

581. 

581. 

142,  221,  227,  253,  336,  354,  405,  411,  475,  495, 

504,  529,  550,  564. 
475. 
529. 
537. 
537. 
529. 

182,  529,  553,  X. 
4U. 
378. 
566. 

227,  475. 
95. 
108. 
108. 
330. 
401. 
309. 
X. 

4^3,  475,  481,  X. 
475. 

120,  208,  506. 
499. 
253. 
253. 
537. 
X. 

422. 

481,  529. 
529. 

216. 

14,  253,  566. 

330. 

336. 

336. 

481,  529. 

481,  529. 

X. 

108. 

510. 

X. 

253. 

510. 

365,  529,  X. 

510. 

477. 

529. 

336. 

336. 

336. 

336 

336. 

AAA. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


155 


TABLE  26B. --Synthetic  organic  chemicals:   Miscellaneous  chemicals    for  which  United  States  production 
were   reported,    identified  by  manufacturer ,    J956- -Continued 


laSCELLAMEOUS  CHEMICALS,  ACYCLIC- -Continued 


Nylon  ( Polyhexamethylene  adlpamlde ) 

Ootadeoenylsuoolnic  anhydride 

Ootadeoyl  isooyanate 

Octanesulfonyl  chloride 

Octanesulfonyl  fluoride 

»1-Octanol 

*2-0otanol 

2-Octanone   (Hexyl  methyl  ketone) --- 

Ootene-2 

Octenylsuccinlc  anhydride 

Ootyl  acetate 

Ootyl  acid  phosphates 

n-Octyl  mercaptan 

Octyl  oleyl  maleate 

Oleamide  (Ootadecene  amide) 

Oleic  acid  salts: 

♦Aluminum  oleate 

Barium  zinc  oleate 

Calcium  soap  of  hydroxyoleic  acid 

Chromiijm  oleate 

Copper  oleate 

♦Lead  oleate 

Jfcrcury  oleate 

Oleoyl  chloride 

xQxalic  acid 

♦Oxalic  acid  salts : 

Ammonium  oxalate 

Ferric  ammonium  oxalate 

Ferric  oxalate 

Ferric  potassium  oxalate 

Ferric  sodium  oxalate 

Ferrous  oxalate 

Potassium  binoxalate 

Potassium  oxalate 

Sodium  binoxalate 

Sodium  oxalate 

All  other 

Oxidized  hydrocarbons,  other  than  lubricating  oil 
additives. 

3-Oxoglutaric  acid  and  esters 

Palmitic  acid  salts : 

Aluminum  paljnitate 

•Zinc  palmitate 

♦Palmitoyl  chloride 

Paraformaldehyde 

Paraldehyde  (Paracetaldehyde) 

Pelargonlc  acid  (Nonanoic  acid) 

♦Pentaerythritol 

♦Pentaerythritol  tetranitrate 

1,5-Pentanediol 

Perehloromethyl  mercaptan 

Phosgene  (Carbonyl  chloride) 

Pine  oil,  synthetic 

Polyacrylamide 

♦Polyacrylic  acid  salts : 

Potassium  polyacrylate 

Sodium  polyacrylate 

Folyacrylonitrile 

Polyethoxyethylsorbitol 

♦Polyethylene  glycol 

Polyethylene  polysulfide 

♦Polyglycerol 

Polyglycols 

Poly OSes 

Polyoxyalkylene  derivatives 

Polypropylene  glycol 

1-Propane thiol 

Propionaldehyde 

♦Propionic  acid 

Propionic  acid  salts: 

Calcium  propionate 

Sodium  propionate 

Zinc  propionate 

Propionic  anhydride 

Propionyl  chloride 

n- Propyl  acetate 

n-Propyl  alcohol  (Propanol) 

a-Propylene  chlorohydrin  (l-Chloro-2-propanol) 

♦Propylene  glycol  (1,2-Propanediol) 

Propylene  glycol  dioleate 

Propylene  glycol  esters,  mixed 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


250,    253. 

102. 

607. 

585. 

Ab8,    585. 

102,    253,    337. 

177,    566. 

177,   4^3,    558,    566. 

102,    177,    566. 

102. 

451. 

378. 

102,   585. 

221. 

309. 

117,    232,   493,    527, 

564. 

234. 

527. 

234. 

117,    232,   493. 

117,    232,    234,   493. 

564. 

177,   417,   439,    510. 

187,    306,    320,    378, 

564. 

306,    320,    335. 

306. 

306. 

3P6. 

306. 

86,    581. 

320,   335. 

306,    320,    335. 

378. 

320,    378,    560,    564. 

31. 

118. 

306. 

27,    150,   493,    527. 

27,    150,   493,    527, 

537. 

353,    510,    550. 

253,    475,    504. 

529. 

337,   488. 

40,    212,    227,    262, 

336,    466, 

5U4 

212,    253,    262,   547. 

253. 

181. 

473. 

130. 

537. 

324,    525,    527. 

239,    324,    515,    527 

566. 

253. 

547. 

252,   405,    529,    550 

515. 

327,   449,    494. 

252. 

476. 

252. 

252,    529,    565. 

477. 

529. 

253,   336,   443,   475 

529,    620 

86,    205,    253,   475. 

205,   253,   475. 

86,    335. 

443,    529. 

353. 

353,   475. 

227,   475,    529,   X. 

365. 

252,   475,    529,   X. 

507. 

252. 

156 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  26B. -Synthetic 


rganic  chemicals: 
were  reported. 


Miscellaneous 
identified  by 


chemicals    for   which  United  States  produ 
manufacturer ,    J956--Continued 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


KOSCELLANEOUS  CHEiaCALS,  ACYCLIC--Contlnued 


Propylene  glycol  methyl  ether 

Propylene  oxide 

Propyl  Isocaproate  (Propyl  isobutylacetate)- 

n- Propyl  nitrate 

Propyne  (MethylaCetylene) 

pyrophosphatldic  acid 

Pyruvic  acid 

♦Research  chemicals ; 

Alkyl  borates 

Alkyl  ethers 

Alltyl  hydrocarbons 

Allsyl  nitriles 

Alltyl  phosphites 

Rare  sugars 

All  other 


Ricinoleic  acid  salts : 

Bari\;m  cadmium  ricinoleate 

Barium  ricinoleate 

Cadmium  ricinoleate 

Calcium  ricinoleate 

»Sarcosine  ( N-Methylaminoaoetic  acid) 

Sebacic  anhydride 

Semicarbazide  base 

Semicarbazide  hydrochloride --- 

♦Sequestering  agents : 

(Diethylenetrinltrilo)pentaacetic  acid 

(Diethylenetrinitrilo)pentaacetic  acid,  iron 
trisodium  salt. 

N,N-Di(hydroxyethyl)glycine,  sodium  salt 

«(Ethylenedinitrilo)tetraacetic  acid  (Ethylene- 
diaminetetraacetic  acid). 
(Ethylenedinitrilo)tetraacetic  acid,  calcium  salt-- 
(Ethylenedinitrilo)tetraacetic  acid,  copper  salt--- 
(Ethylenedinitrilo)tetraacetlc  acid,  disodium  salt- 
(Ethylenedinltrilo)tetraacetic  acid,  magnesium 

salt. 
(Ethylenedinitrilo)tetraacetio  acid,  manganese 
salt. 
»(Ethylenedinitrilo)tetraaoetic  acid,  monosodium 

iron  salt. 
•»(Ethylenedinitrilo)tetraacetic  acid,  tetrasodium 
salt. 
(Ethylenedinitrilo)tetraacetic  acid,  trisodium 
salt. 

(Ethylenedlnltrilo)tetraaoetic  acid,  zinc  salt 

Glucoheptonic  acid,  sodium  salt 

N- ( Hydroxyethyl ) ethylenedlnltrilotriacetic  acid, 
trisodium  salt. 

Silicones 

Sodium  ethyl  oxalacetate 

Sodium  formaldehyde  bisulfite 

♦Sodium  formaldehyde  sulfoxylate 

Sodium  2-hydroxy-l-propanesulfonate 

Sodium  methoxlde  (Sodium  methylate) 

Sodium  sorbitol  borate 

Sorbitol 

Soya  nltrile 

Soybean  oil,  acyl  chloride  salt  of  sodium  lysalbi- 
nate. 

Stearamlde  (Octadecane  amide) 

♦Stearic  acid  salts : 
♦Aluminum  stearates : 

Aluminum  monostearate 

♦Aluminum  distearate 

Aluminum  tristearate 

Ammonium  stearate 

Barium  stearate 

♦Cadmium  stearate 

♦Calcium  stearate 

Cobalt  stearate 

Ferric  stearate 

Ferrous  stearate 

♦Lead  stearate 

Lead  stearate,  dibasic 

Lithium  hydroxystearate 

♦Lithium  stearate 

♦Magnesium  stearate 

♦Zinc  stearate — ' 

All  other 


252. 

252,  "475,  529. 
336. 

^0. 
108. 
378. 
537. 

568. 
102. 
102. 
6. 

223. 
360. 

6,  31,  102,  175,  216,  218,  223,  330,  358,  360,  ^10, 
-412,  ^77. 

23-;. 

96,  234. 
234. 
96. 

253,  401,  492,  510. 
474. 

218. 
218. 

608. 
608. 

252. 

179,  252,  335,  510,  608. 


608. 
179,  335, 


608. 
360. 
252, 

244, 

157. 

330, 

71, 

510. 

102, 

547. 

547, 

309. 


252,  510,  608. 
252,  510,  527,  608. 
608. 

608. 

484. 

477. 
253,  424,  566. 

550,  X. 


43,  150,  439,  527,  564. 

43,  150,  229,  439,  493,  500,  527,  537,  564. 

43,  150,  229,  439,  493,  527,  537,  564. 

150,  493,  527. 

43,  493,  527. 

493,  527. 

43,  150,  229,  439,  493,  500,  527,  5'37,  564. 


234,  389,  439,  493,  527,  552. 
493. 

150,  271,  493,  527. 

43,  150,  493,  500,  527,  537,  564. 

43,  150,  229,  439,  493,  500,  527,  537,  564. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


157 


TABLE  26B. -Syntheti 


rganic   chemicals:    Miscel laneous  chemicals    for   which  United  States  produ 
were  reported,    identified  by  manufacturer ,    i956- -Continued 


Manufacturers '  identification  numbers 
(according  to  list  in  table  27) 


MISCELLANEOUS  CHHCCALS,  ACYCLIC--Continued 


Stearoyl  chloride 

Succinic  acid 

Succinic  acid,  sodium  salt 

Succinic  anhydride 

Succinimide 

Succinonitrile 

Sucrose  ootaacetate 

Tallow  fatty  acyl  chloride 

Tartaric  acid 

Tartaric  acid  salts,  nonmedicinal 

Tetraethylene  glycol 

Tetraethylene  glycol  dibutyl  ether-- 

Tetraethylene  glycol  dimethyl  ether  ( Bis[ 2- Ca- 
me thoxyethoxy)  ethyl]  ether). 

Tetraethyl  lead 

Tetrahydroxysuccinic  acid  ( Dioxytartaric  acid)- — 

Tetrakis(2-hydroxypropyl)ethylenediamine 

Tetraoctyl  orthosilicate 

Thioacetamide 

Thioacetic  acid  (Sulfoacetic  acid) 

Thioglyoerol 

Thioglycolic  acid  (Mercaptoacetic  acid) 

Thioglycolic  acid  salts : 

♦Ammonium  thioglycolate 

Calcium  thioglycolate 

Ethanolamine ,  mono  thioglycolate 

Sodium  thioglycolate 

Thiomalio  acid 

Triacetoxyvlnylsilane 

Trialkyl  stearyl  ammonium  ethyl  phosphate 

Triallyl  cyanurate 

Trichloroethylsilane  (Ethyl  silicon  trichloride )-- 

Trichlorohexadecylsllane 

Trichloromethanephosphonic  acid 

Trlchloromethylsllane 

Trichloro-octadecylsilane 

Trichlorovlnylsilane 

Triethoxymethoxypropane 

Trlethyl  acetate  citrate 

Trlethyl  citrate 

«Triethylene  glycol 

Trlethj'lene  glycol  dichloride  (2-(2-Chloroethoxy)- 
ethyl  2-chloroethyl  ether). 

Triethylene  glycol  dimethyl  ether 

Trl-2-ethylhexyl  phosphite--- 

Trlethyl  orthoacetate 

Trlethyl  orthoformate 

Trlethyl  orthopropionate 

Triiso-octyl  phosphite 

Triisopropyl  phosphite 

Trimethyl  orthoformate 

Trimethyl  phosphite 

Tripropylene  glycol 

Tripropylene  glycol,  methyl  ether 

Tris(2-ohloroethyl)  phosphite 

Tristearyl  phosphate 

*Urea  in  compounds  or  mixtures : 

Crystal 

In  feed  compounds 

*In  fertilizer  solution 

In  plastics 

*In  solid  fertilizer 

In  urea-formaldehyde  concentrate 

All  other 

Valeraldehyde 

*Vinyl  acetate,  monomer 

Vinyl  stearate 

Waxes,  synthetic 

Xanthic  acid,  ethyl,  sodium  salt 

Zinc  dlamyldithiocarbamate 

Zinc  formaldehyde  dlthiocarbamate 

»Zlnc  fonnaldel^de  sulfoxylate 


356. 
293,  356. 
506. 


49^,  510. 

506. 

564. 

221,  506. 

506. 

537. 

529. 

510. 

189. 

560,  564. 

252,  X. 
569. 
39. 

253,  480. 
537. 
565. 
221. 

216,  335,  477. 

477. 

356. 

293,  356,  619. 

93,  293,  356,  581,  611. 

356. 

293, 

356, 

24^. 

547. 

537. 

244. 

244. 

378. 

244. 

244. 

244. 

330. 

306. 

306. 

252,  405,  529,  550. 

529. 

39. 

223. 

330,  477. 

330. 

330. 

223. 

223. 

330. 

223. 

252. 

252. 

223. 

241. 


280, 
253, 
253, 
253. 
253, 
354. 
253, 
444. 
108, 
108, 
179. 
253. 
585. 
335. 
71, 


354. 

280,  292,  354. 

280,  292,  354,  582. 

280,  292,  354,  481,  582. 

582. 

253,  475,  529. 
510. 


253,  424,  566. 


158  UNITED  STATES  TARIFF  COMMISSION 

Directory  of  Manufacturers 

The  Directory  of  Manufacturers  lists  the  companies  that  report 
their  production  of  synthetic  organic  chemicals  to  the  United  States 
Tariff  Commission.    The  name  of  each  manufacturer  is  preceded 
by  an  identification  number. 

For   1956,    the  Directory  of  Manufacturers  lists  620  companies 
(see  table  27).    Chiefly  as  a  result  of  mergers,    there  were  6  fewer 
reporting  companies  in  1956  than  in  1955.    Some  of  the  companies 
that  report  production  of  synthetic  organic  chemicals  consume 
their  entire  output  in  further  manufacturing. 

The  Directory  of  Manufacturers  lists  the  companies  in  two  ways 
Section   1   lists  them  in  numerical  order,    the  identification  number 
for  each  company  having  been  assigned  in  the  order  in  which  the 
Commission  received  the  company's   reporting  schedule.    This  sys- 
tem makes  it  unnecessary  to  wait  until  all  the  schedules  are  re- 
turned before  assigning  the  identification  numbers,    and  greatly 
speeds  the  preparation  of  the  tables  in  part  III.    Section  2  lists  the 
companies  in  alphabetical  order. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


159 


TABLE  77 .--Synthet ic   organic   chemicals:    Directory  of  manufacturers,    1956 

SECTION  1.  NUMERICAL  DIRECTOHY 

[Names  of  synthetic  organic  chemical  manufacturers  who  reported  production  or  sales  to  the  United  States 
Tariff  Commission  for  1956  are  listed  below  in  the  order  of  their  identification  numbers  as  used  in  tables 
in  part  III.  Section  2  of  this  table  lists  these  mamifaoturers  alphabetically, and  gives  their  office  and 
plant  addresses] 


No. 

Name  of  company 

No. 

Name  of  company 

1 

Southern  Resin  Glue  Co. 

75 

Kyanize  Paints,  Inc. 

2 

Southern  Textile  Chemical  Corp. 

76 

Sipe,  James  B.,  &  Co. 

3 

Premo  Pharmaceutical  Laboratories,  Inc. 

77 

Standard  Chlorine  Chemical  Co.,  Inc. 

A. 

American  Rook  Wool  Corp. 

78 

Cook  Paint  &  Varnish  Co. 

5 

Calvert-Mount  Winans  Co. 

79 

American  Marietta  Co. 

6 

Columbia  Organic  Chemicals,  Inc. 

80 

American  Marietta  Co.  (Ferbert-Sohomdorfer 

7 

Fine  Colors  Co. 

Co.  Div.). 

8 

Meyer,  J.,  &  Sons,   Inc. 

81 

American  Viscose  Corp. 

9 

Olin  Mathieson  Chemical  Corp.  (Blockson 

82 

Bennett's. 

Chemical  Co.  Div.). 

83 

California  Ink  Co.,  Inc. 

10 

Richardson  Co. 

84 

Carpenter-Morton  Co. 

11 

Soluol  Chemical  Co.,  Inc. 

85 

Sonnebom,  L.,  Sons,  Inc. 

12 

Standard  Agricultural  Chemicals,  inc. 

86 

Chemo  Puro  Manufacturing  Corp. 

13 

Standard-Toch-Chemioals,  Inc. 

87 

George,  P.  D.,  Co. 

K 

U.  S.  Plastic  Products  Corp. 

88 

Kennecott  Copper  Corp.  (Chino  Mines  Div.). 

15 

Lobica-Debruille,  Inc. 

89 

Magnolia  Petroleum  Co. 

16 

Marathon  Corp.  (Chemical  Sales  Dept.). 

90 

Marlowe -Van  Loan  Corp. 

17 

Stansbury  Chemical  Co.,  Inc. 

91 

Northwestern  Chemical  Co. 

18 

Astra  Pharmaceutical  Products,  Inc. 

92 

Soholler  Bros.,  Inc. 

19 

National  Biochemical  Co. 

93 

Summit  Chemical  Products  Corp. 

20 

Capital  Plastics,  Inc. 

94 

Warner-Jenkinson  Manufacturing  Co. 

21 

Commonwealth  Color  &  Chemical  Co. 

95 

Anderson  Chemical  Co. 

22 

Farrington,  W.  U.,  Estate  of. 

96 

Baker  Castor  Oil  Co. 

23 

Lake  States  Yeast  Corp. 

97 

Drug  Processors,  Inc. 

24 

Reliance  Varnish  Co.,  Inc. 

98 

Fiberboard  Paper  Products  Corp.  (Pabco  Paint 

25 

Rinshed4teson  Co. 

Div.). 

26 

Siddall,  Geo.  F.,  Co.,  Inc. 

99 

Finetex,  Inc . 

27 

Synthetic  Products  Co. 

100 

Foremost  Food  &  Chemical  Co.  (El  Dorado  Div.) 

28 

Tex  Chemical  Co. 

101 

General  Tire  Sc   Rubber  Co.  (Chemical  Div.). 

29 

Blackman  Brands,  Inc. 

102 

Humphrey-Wilkinson,  Inc. 

30 

Chemical  Insecticide  Corp. 

103 

Kehew-Bradley  Co. 

31 

City  Chemical  Corp. 

104 

Standard  Ultramarine  &  Color  Co. 

32 

Trask,  Arthur  C,  Co. 

105 

American  Aniline  &  Extract  Co.,  Inc. 

33 

Hanna  Paint  Manufacturing  Co. 

106 

Triangle  Chemical  Co. 

(Industrial  Div.). 

107 

United  States  Procaine  Co.,  Inc. 

34 

Hynson,  Westcott  &  Dunning,  Inc. 

108 

Air  Reduction  Chemical  Co. 

35 

Knoedler  Chemical  Co. 

109 

France,  Campbell  &   Darling,  Inc. 

36 

Ottol  Oil  Co. 

110 

International  Minerals  &  Chemical  Corp. 

37 

Polychemlcal  Laboratories,  Inc. 

111 

Jones -Dabney  Co. 

38 

Raybestos  Div.  of  Raybestos-Manhattan,  Inc. 

112 

Laros,  R.  K.,  Co. 

39 

Ansul  Chemical  Co. 

113 

Laurel  Soap  Manufacturing  Co.,  Inc. 

40 

Delaware  Chemicals,  Inc. 

114 

Marden-Wild  Corp. 

41 

Krumbhaar  ChemioEil  Co.,  Inc. 

115 

Merrell,  Wm.  S.,  Co. 

42 

Mineral  Oil  Refining  Co. 

116 

Schieffelin  &  Co. 

43 

Parsons,  M.  W.,  Plymouth,  Inc. 

117 

Shepherd  Chemical  Co. 

44 

Wilmot  &  Cassidy,  Inc. 

118 

Alox  Corp. 

45 

Cleary,  W.  A.,  Corp. 

119 

Booty  Resineers,  Inc. 

46 

Crownoil  Chemical  Co.,  Inc. 

120 

Cadet  Chemical  Corp. 

47 

Peerless  Chemical  Co. 

121 

Douglas  Chemical  Corp. 

48 

Red  Spot  Paint  &  Varnish  Co.,  Inc. 

122 

Emkay  Chemical  Co. 

49 

All-Tex  Specialties  Co. 

123 

Farley  &  Loetscher  Manufacturing  Co. 

50 

Bird  Sc   Son,  Inc.  (Floor  Covering  Div.). 

124 

Organic  Chemical  Corp. 

51 

Guyan  Color  &  Chemical  Works. 

125 

Simpson  Redwood  Co. 

52 

Kalide  Corp. 

126 

Petrolite  Corp.  (Tretolite  Cu.  Div.). 

53 

Loven  Chemical  Co.  of  California. 

127 

Ad -Co  Color  Corp. 

54 

Medical  Chemicals  Corp. 

128 

Buckeye  Cellulose  Corp. 

55 

Nelson- Wells  &  Co. 

129 

Copolymer  Rubber  &  Chemical  Corp. 

56 

Remington  Arms  Co.,  Inc. 

130 

Crosby  Chemicals,  Inc. 

57 

Spaulding  Fibre  Co.,  Inc. 

131 

Crown  Tar  &  Chemical  Works,  Inc. 

58 

Standard  Naphthalene  Products  Co.,  Inc. 

132 

Firestone  Tire  &  Rubber  Co. 

59 

Vita-Var  Corp. 

133 

Freeman  Chemical  Corp. 

60 

Werner  Drug  &  Chemical  Co. 

134 

Great  Southern  Chemical  Corp. 

61 

Wilson  Organic  Chemicals,  Inc. 

135 

Harbor  Plywood  Corp. 

62 

Amalgamated  Chemical  Corp. 

136 

Ironsides  Co. 

63 

American  Chemical  Paint  Co. 

137 

Lakeside  Laboratories,  Inc. 

64 

Armstrong  Cork  Co. 

138 

Merichem  Co. 

65 

Stein,  Hall  &  Co.,  Inc. 

139 

National  Polychemlcals,  Inc. 

66 

General  Color  Co.,  Inc. 

140 

Peck's  Products  Co. 

67 

Hartman-Leddon  Co. 

141 

Petroleum  Chemicals,  Inc. 

68 

Inland  Steel  Container  Co. 

142 

Spencer  Chemical  Co. 

69 

Pacific  Paint  &  Varnish  Co. 

143 

Thompson  Chemicals  Corp. 

70 

Poiighkeepsie  Dyestuff  Corp. 

144 

Universal  Detergents,  Inc. 

71 

Royce  Chemical  Co. 

145 

U.  S.  Industrial  Chemicals  Co.,  Div.  of 

72 

Rubber  Corp.  of  America. 

National  Distillers  Products  Corp. 

73 

American  Bio-Synthetics  Corp. 

146 

Cosden  Petroleum  Corp. 

74 

Keystone  Color  Works,  Inc. 

147 

Bates  Chemical  Co. 

148 

Clover  Chemical  Co. 

160 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  27. --Synthetic   organic  chemicals:    Directory  of  manufacturers ,    J956- -Continued 


No. 

Name  of  company 

No. 

Name  of  company 

U9 

Concord  Chemical  Co.,  Inc. 

226 

Scherer,  R.  P.,  Corp. 

150 

Lefflngwell  Chemical  Co. 

227 

Warren  Petroleum  Corp. 

151 

Lyle  Branchf lower  Co. 

228 

Lever,  C,  Co.,  Inc. 

152 

Pennsylvania  Industrial  Chemical  Corp. 

229 

Nuodex  Products  Co.,  Div.  of  Heyden  Newport 

153 

Burkart-Schier  Chemical  Co. 

Chemical  Co. 

15A 

Cabot,  Samuel,  Inc. 

230 

Old  Colony  Tar  Co.,  Ino. 

155 

Chemico,  Ino . 

231 

Specific  Pharmaceuticals,  Inc. 

156 

Edison,  Thomas  A.,  Inc.  (Medical  Gas  Dlv.). 

232 

Stresen-Reuter,  Fred'k.  A.,  Ino. 

157 

Food  Machinery  &  Chemical  Corp.  (Fairfield 

233 

Tar  Distilling  Co.,  Inc. 

Chemical  Div.) . 

234 

Harshaw  Chemical  Co. 

158 

Grand  Rapids  Varnish  Corp. 

235 

Midland  Industrial  Finishes  Co. 

159 

Metro-Atlantic,  Inc. 

236 

Minnesota  Paints,  Inc. 

160 

Metro  Dyestuff  Corp. 

237 

United  States  Pipe  &.   Foundry  Co. 

161 

Planetary  Chemical  Co.,  Ino. 

238 

Burroughs-Wellcome  &   Co.  (U.S.A.),  Inc. 

162 

Taylor  Fibre  Co. 

239 

Jordan,  Jr.,  W.  H.,  &  F.,  Manufacturing  Co. 

163 

UBS  Chemical  Corp. 

240 

Metalsalts  Corp. 

164 

Wetherill,  George  D.,  Varnish  Co. 

241 

Perrautlt  Co. 

165 

Borg-Warner  Corp.  (Marbon  Chemical  Div.). 

242 

Buckman  Laboratories,  Inc. 

166 

Armour  Laboratories  Div.  of  Armour  &  Co. 

243 

Hart  Products  Corp. 

167 

Harsyd  Chemicals,  Inc. 

244 

Dow  Corning  Corp. 

168 

Old  Hickory  Chemical  Co.,  Inc. 

245 

Cowles  Chemical  Co. 

169 

Purocaine,  Ino. 

246 

Atlas  Refinery,  Ino. 

170 

Standard  Chemical  Products,  Inc. 

247 

Bio-Rad  Laboratories. 

171 

Whittemore-Wright  Co.,  Inc. 

248 

Carlisle  Chemical  Works,  Ino. 

172 

Dakota  Briquets  &  Tar  Products,  Inc. 

249 

Chemical  Process  Co. 

173 

Pratt  &  Lambert,  Inc. 

250 

Chemstrand  Corp. 

174 

Root  Chemicals,  Ino. 

251 

Continental  Oil  Co. 

175 

Schwarz  Laboratories,  Inc. 

252 

Dow  Chemical  Co. 

176 

Swift  &  Co. 

253 

duPont  de  Nemours,  E.  I.,  &  Co.,  Ino. 

177 

Wallace  &  Tiernan,  Ino.  (Harchem  Div.). 

254 

Food  Machinery  &  Chemical  Corp.  (Ohio-Apex 

178 

Baker,  J.  T.,  Chemical  Co.  (Taylor  Chemical 

Div.). 

Div.). 

255 

Heresite  &  Chemical  Co. 

179 

Glyco  Products  Co.,  Ino. 

256 

Neville  Chemical  Co. 

180 

Arco  Co. 

257 

Ohio  Chemical  &  Surgical  Equipment  Co. 

181 

Calhio  Chemicals,  Inc. 

258 

Pan  American  Petroleum  Corp. 

182 

Col ton  Chemical  Co.,  Div.  of  Air  Reduction 

259 

Portland  Gas  &  Coke  Co. 

Co.,  Ino. 

260 

Pittsburgh  Coke  &  Chemical  Co. 

183 

Continental -Diamond  Fibre  Corp. 

261 

Purex  Corp . ,  Ltd  .■ 

184 

Food  Machinery  &  Chemical  Corp.  (Niagara 

262 

Trojan  Powder  Co. 

Chemical  Div.). 

263 

Union  Oil  Co.  of  California. 

185 

Long,  Charles  R.,  Jr.,  Co. 

264 

Pacific  Yeast  Products,  Inc. 

186 

National  Petro-Chemicals  Corp. 

265 

Atlantic  Chemical  Corp. 

187 

Hooker  Electrochemical  Co.  (Oldbury  Products). 

266 

Benzol  Products  Co. 

188 

Pennsylvania  Refining  Co. 

267 

Carwin  Co. 

189 

Stauffer  Chemical  Co. 

268 

Appleton  Coated  Paper  Co. 

190 

Consolidated  Paint  Co. 

269 

Crown  Central  Petroleum  Corp. 

191 

Belle  Chemical  Co.,  Inc. 

270 

Florida  Molasses  Corp. 

192 

Kohnstamm,  H.,  &   Co.,  Inc. 

271 

Maywood  Chemical  Works. 

193 

New  Jersey  Zinc  Co.  (of  Pa.). 

272 

Michigan  Chemical  Corp. 

194 

United  Piece  Dye  Works. 

273 

Montrose  Chemical  Co. 

195 

Miranol  Chemical  Co.,  Inc. 

274 

Shawlnigan  Resins  Corp. 

196 

Osborn,  C.  J.,  Co. 

275 

Wheeler,  Reynolds  &  Stauffer. 

197 

Sterling  Drug,  Inc.  (National  Brands  Div.). 

276 

Bruder,  M.  A.,  &  Sons,  Inc. 

198 

Watertown  Manufacturing  Co. 

277 

Acme  Resin  Corp. 

199 

Westinghouse  Electric  Corp. 

278 

Atlantic  Refining  Co. 

200 

Texas-U.  S.  Chemical  Co. 

279 

Florasynth  Laboratories,  Inc. 

201 

Vanderbilt  Chemical  Corp. 

280 

Grace  Chemical  Co.,  Div.  of  W.  R.  Grace  &  Co. 

202 

Nilok  Chemicals,  Ino. 

281 

Pilot  California  Co. 

203 

United  Rubber  &  Chemical  Co. 

282 

Salvo  Chemical  Corp. 

204 

Great  Western  Sugar  Co. 

283 

Upjohn  Co. 

205 

Lemke,  B.  L.,  &  Co.,  Ino. 

284 

Esso  Standard  Oil  Co.  (Louisiana  Div.). 

206 

Nease  Chemical  Co.,  Inc. 

285 

American  Viscose  Corp.  (Film  Div.). 

207 

Searle,  G.  D.,  &  Co. 

286 

Apex  Chemical  Co.,  Inc. 

208 

Wallace  &.   Tiernan,  Inc.  (Lucidol  Div.). 

287 

Barium  ReduQtion  Corp. 

209 

Interchemlcal  Corp.  (Finishes  Dlv.). 

288 

Chemical  Manufacturing  Co.,  Inc. 

210 

Uhlich,  Paul,  &  Co.,  Ino. 

289 

Clinton  Corn  Processing  Co. 

211 

General  Petroleum  Corp. 

290 

Dewey  &  Almy  Chemical  Co.,  Div.  of  W.  R. 

212 

Hercules  Powder  Co. 

Grace  &  Co. 

213 

Verona  Chemical  Co. 

291 

Endo  Laboratories,  Ino. 

214 

American  Oil  Co.  (Texas). 

292 

Deere  &  Co.  (Grand  River  Chemical  Div.). 

215 

Frontier  Chemical  Co.,  Div.  of  Union  Chemical 

293 

Halby  Products  Co.,  Inc. 

&  Materials  Corp. 

294 

Leatex  Chemical  Co. 

216 

Arapahoe  Chemicals,  Inc.,  &  Arapahoe  Special 

295 

Marblette  Corp. 

Products,  Inc. 

296 

Montrose  Chemical  Corp.  of  California. 

217 

Bryant  Chemical  Corp. 

297 

Norwich  Pharmaoal  Co. 

218 

Fairmount  Chemical  Co.,  Inc. 

298 

Procter  &  Gamble  Co. 

219 

Kentucky  Color  &  Chemical  Co. 

299 

Puget  Sound  Pulp  &  Timber  Co. 

220 

Minnesota  Mining  &  Manufacturing  Co.  (Irvington 

300 

Sheffield  Chemical  Co..  Div.  of  Sheffield 

Chemical  Div.) . 

Farms  Co.,  Inc. 

221 

Monsanto  Chemical  Co. 

301 

Sonoco  Products  Co. 

222 

Oronite  Chemical  Co. 

302 

Suntide  Refining  Co. 

223 

Virginia-Carolina  Chemical  Corp. 

303 

Tennessee  Products  &  Chemical  Corp. 

224 

Peerles  Color  Co.,  Inc. 

304 

Velslcol  Chemical  Corp. 

225 

Sandoz,  Inc . 

305 

Washington  Natural  Gas  Co. 

SYNTHETIC  ORGANIC  CHEMICALS,  1956 


161 


TABLE  27. —Synthetic  orianic  chemicals:   Directory  of  manufacturers,    I9J6- -Continued 


Name  of  con^any 


Pfizer,  Charles,  &  Co.,  Inc. 

Berk,  F.  W.,  &  Co.,  Inc. 

Wilson  Laboratories  Div.  of  Wilson  &  Co., 

Inc. 
Armour  &  Co.  (Chemical  Dlv.). 
Eakins,  J.  S.,  &  W.  R.,  Inc. 
Esso  Standard  Oil  Co. 
Ferro  Chemical  Corp. 
Gllman  Paint  &  Vamlsh  Co. 
Thlokol  Chemical  Corp. 
Wltte,  John  H.,  &  Sons. 
Cookerllle,  F.  0. 
Kelly,  John  F.,  Co. 
Lever  Brothers  Co. 
Nonweller,  A.  P.,  Co. 
Allied  Chemical  &  Dye  Corp.  (General  Chemical 

Dlv.). 
Ortho  Chemical  Corp. 
Schenectady  Varnish  Co.,  Inc. 
Southern  Sizing  Co. 
Alco  Oil  &  Chemical  Corp. 
Atlas  Processing  Co. 
Chi Ids  Pulp  Colors,  Inc. 
Colgate-Palmolive  Co. 
General  Mills,  Inc. 
Young  Aniline  Works,  Inc. 
Kay-Fries  Chemicals,  Inc. 
Shell  Oil  Co. 
Verley  Chemical  Co.,  Inc. 
Allied  Chemical  &  I)ye  Corp.  (Solvay  Process 

Dlv.). 
Archer-Daniels-Midland  Co. 
Baker,  J.  T.,  Chemical  Co. 
Commercial  Solvents  Corp. 
Glvaudan  Corp. 
Gulf  Oil  Corp. 

Levey,  Fred'k.  H.,  Co.,  Inc. 
MoGean  Chemical  Co. 
Petro-Tex  Chemical  Corp. 
Publicker  Industries,  Inc. 
Quaker  Chemical  Products  Corp. 
Hiker  Laboratories,  Inc. 
Dr.  Salsbury's  Laboratories. 
Specialty  Resins  Co. 
Washburn,  T.  F.,  Co. 
Wlnthrop  Laboratories. 
Davis,  H.  B.,  Co. 

General  Foods  Corp.  (Maxwell  House  Div.). 
Keystone  Cheraurgio  Corp. 
Stange,  Wm.  J.,  Co. 
Trubek  Laboratories. 

Allied  Chemical  &  Dye  Corp.  (Nitrogen  Div.). 
r^e  Specialties  Corp.,  Inc. 
Evans  Chemetics,  Inc. 
Firestone  Tire  &  Rubber  Co.  (Firestone  Plastics 

Co.  Div.). 
Premium  Chemicals,  Inc. 
Kessler  Chemical  Co.,  Inc. 
•Pfanstiehl  Laboratories,  Inc. 
Nepera  Chemical  Co.,  Inc. 
Dawe's  Laboratories,  Inc. 
Ethyl-Dow  Chemical  Co. 
Fine  Organics,  Inc. 
Fries  Bros.,  Inc. 
Grain  Processing  Corp. 
Koppers  Co.,  Inc.  (Chemical  Div.  &  Tar  Products 

Div.). 
Miles  Laboratories,  Inc. 
Newport  Industries,  Inc. 
Patent  Chemicals,  Inc. 
Pfister  Chemical  Works,  Inc. 
Ruberoid  Co. 
Sinclair  Refining  Co. 
Olin  Mathleson  Chemical  Corp.  (Squibb,  E.  R., 

&  Sons  Div. ) . 
Sumner  Chemical  Co.,  Div.  of  Miles 

Laboratories,  Inc. 
Synthetic  Chemicals,  Inc. 
Synthetic  Plasties  Co. 
Victor  Chemical  Works. 
Huron  Milling  Co. 
American  Alcolac  Corp. 
Brown  Co. 
Coopers  Creek  Chemical  Corp. 


383 
384 
385 
386 
387 
388 
389 
390 
391 
392 
393 
394 
395 
396 
397 
398 
399 
400 
401 
402 
403 
404 
405 
406 
407 
408 
409 
410 
411 
412 
413 
414 
415 
416 
417 
418 
419 
420 
421 

422 
423 
424 
425 
426 
427 
428 
429 
430 
431 
432 
433 
434 
435 
436 
437 
438 
439 

440 

441 
442 
443 

444 
445 
446 
447 
448 
449 
450 
451 
452 
453 
454 
455 
456 
457 
458 
459 
460 
461 
462 


Name  of  Company 


Industrial  Products,  Inc. 

Marx,  Max,  Color  &  Chemical  Co. 

Maumee  Chemical  Co. 

Phoenix  Oil  Co. 

Western  Dry  Color  Co. 

American  Maize  Products  Co. 

National  Lead  Co. 

Standard  Dyestuff  Corp. 

Van  Dyk  &  Co.,  Inc. 

Dodd,  Donald  A. 

Huggins,   James,   &  Son,    Inc. 

Industrial  Dyestuff  Co. 

Richfield  Oil  Corp. 

Smith,  Kline  &  French  Laboratories. 

Synco  Resins,  Inc. 

van  Ameringen-Haebler,  Inc. 

Alframine  Corp. 

Maas  &  Waldstein  Co. 

Pharma  Chemical  Corp. 

Hitter,  F.,  &  Co. 

Southern  Dyestuff  Corp. 

White  &  Bagley  Co. 

Jefferson  Chemical  Co.,  Inc. 

Morwear  Paint  Co. 

Parke,  Davis  &  Co. 

Texas  Co. 

Fritzsche  Brothers,  Inc. 

Bios  Laboratories,  Inc. 

Cities  Service  Oil  Co. 

Delta  Chemical  Works,  Inc. 

Paul-Lewis  Laboratories,  Inc. 

Berkeley  Chemical  Corp. 

Federal  Color  Laboratories,  Inc. 

Thomasset  Colors,  Inc. 

DePaul  Chemical  Co.,  Inc. 

Dexter  Chemical  Corp. 

Sun  Oil  Co. 

Hampden  Color  &  Chemical  Co. 

Hooker  Electrochemical  Co.  (Durez  Plastics 
Dlv.). 

Lilly,  Eli,  &.Co. 

Lueders,  George,  &  Co. 

Wolf,   Jacques,   &  Co. 

Kali  Manufacturing  Co. 

Goodrlch-Gulf  Chemicals,  Inc. 

LaMotte  Chemical  Products  Co. 

Vitamins,  Inc. 

Foster-Heaton  Co. 

Interohemlcal  Corp.  (Textile  Colors  Div.). 
Maryland  Plastics,  Inc. 

Gallowhur  Chemical  Corp. 
Brooklyn  Color  Works,  Inc. 
Humble  Oil  &  Refining  Co. 

Chemlek  Laboratories,  Inc. 

Crown  Chemical  Corp. 

Hitter  Chemical  Co.,  Inc. 

Varcum  Chemical  Corp. 

Sun  Chemical  Corp.  (Warwick  Chemical  Co. 

Div.). 
Zinsser  &  Co.,  Inc.,  subsidiary  of  Harshaw 

Chemical  Co. 
Alkydol  Laboratories,  Inc. 
New  York  Quinine  &  Chemical  Works,  Inc. 
Eastman  Kodak  Co.  (Tennessee  Eastman  Co. 

Div.). 
Eastman  Kodak  Co.  (Texas  Eastman  Co.  Div.). 
Carus  Chemical  Co.,  Inc. 
Leonard  Refineries,  Inc.  (Roosevelt  Dlv.) . 
Althouse  Chemical  Co.,  Inc. 
Kilsdonk  Chemical  Corp. 
Goodyear  Tire  &  Rubber  Co. 
Kennecott  Copper  Corp.  (Utah  Copper  Div.) 
Deecy  Products  Co. 
Dykem  Co. 

Berkshire  Color  &   Chemical  Co. 
Hoffmann-LaRoche,  Inc. 

U.  S.  Rubber  Co.  (Naugatuck  Chemical  Div.). 
Abbott  Laboratories. 
Arnold,  Hoffman  &  Co.,  Inc. 
Diversey  Corp. 
Gamma  Chemical  Corp. 
Holland  Color  &  Chemical  Co. 
Lebanon  Chemical  Corp. 
Sinclair  &  Valentine  Co. 


162 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  7f,--Syntheti 


chemicals:    Directory   of 


No. 

Name  of  oompany 

No. 

Name  of  company 

-;63 

Sooony-Mobil  Oil  Co.,  Inc. 

537 

American  Cyanamid  Co. 

i6A 

McCloskey  Varnish  Co. 

538 

American  Synthetic  Rubber  Corp. 

465 

Phillips  Chemical  Co. 

539 

King,  0.  L.,  &  Co. 

466 

Relchhold  Chemicals,  Inc. 

540 

Plastics  Engineering  Co. 

467 

Cutter  Laboratories. 

541 

Paisley  Products,  Inc. 

468 

Hooker  Electrochemical  Co. 

542 

Thompson-Hayward  Chemical  Co. 

469 

Penick,  S.  B.,  &   Co. 

543 

Ciba  Pharmaceutical  Products,  Inc. 

470 

Pabst  Brewing  Co. 

544 

Jennlson-Wright  Corp. 

471 

Perkins  Glue  Co. 

545 

Ninol  Laboratories,  Inc. 

472 

Felton  Chemical  Co.,  Inc. 

546 

American  Potash  &  Chemical  Corp. 

473 

Pittsburgh  Plate  Glass  Co. 

547 

Atlas  Powder  Co. 

474 

Shulton,  Inc.  (Fine  Chemicals  Dlv.). 

548 

Keystone  Paint  &  Varnish  Corp. 

475 

Celanese  Corp.  of  America. 

549 

Moretex  Chemical  Products. 

476 

Com  Products  Refining  Co. 

550 

Olin  Mathieson  Chemical  Corp. 

477 

Eastman  Kodak  Co. 

551 

Sobering  Corp. 

478 

Union  Carbide  &  Carbon  Corp.  (Bakelite  Co.). 

552 

Standard  Oil  Co.  of  California. 

479 

Eastern  States  Chemical  Corp. 

553 

Borden  Co.  (Chemical  Div.). 

480 

Ethyl  Corp. 

554 

Fuller,  W.  P.,  &  Co. 

481 

Shell  Chemical  Corp. 

555 

Hoffman-Taff,  Inc. 

482 

Orbis  Products  Corp, 

556 

LaSalle  Chemical  Co. 

483 

Schuylkill  Chemical  Co. 

557 

Sun  Chemical  Corp.  (Pigment  Div.). 

484 

Union  Carbide  &  Carbon  Corp.  (Silicones  Div.). 

558 

Allied  Chemical  &  I^e  Corp.  (Barrett  Div.). 

485 

Sherwin-Williams  Co. 

559 

Glidden  Co. 

486 

Westvllle  Laboratories. 

560 

Merck  &  Co.,  Inc. 

487 

Collway  Colors,  Inc. 

561 

Food  Machinery  &  Chemical  Corp.  (Westvaco 

488 

Emery  Industries,  Inc. 

Chlor-Alkali  Div.,  Westvaco  Mineral 

489 

Gane's  Chemical  Works,  Inc. 

Products  Div.,  &  Chemical  Divisions 

490 

Hexagon  Laboratories,  Inc. 

Management) . 

491 

Magruder  Color  Co.,  Inc. 

562 

Pltt-Consol  Chemical  Co. 

492 

Sterling  Drug,  Inc.  (Hilton-Davis  Chemical  Co. 

563 

Wioa  Co.,  Inc. 

Div.). 

564 

Mallinckrodt  Chemical  Works. 

493 

Witco  Chemical  Co. 

565 

Wyandotte  Chemicals  Corp. 

494 

Eraulsol  Chemical  Corp. 

566 

Rohm  &  Haas  Co. 

495 

Quaker  Oats  Co. 

567 

Treplow  Products,  Inc. 

496 

Staley,  A.  E.,  Manufacturing  Co. 

568 

United  States  Borax  &  Chemical  Corp. 

497 

Houghton,  E.  F.,  &  Co. 

569 

Roberts  Chemicals,  Inc. 

498 

Organlcs,  Inc. 

570 

Chase  Chemical  Corp. 

499 

Advance  Solvents  &  Chemical  Div.  of  Carlisle 

571 

White  &   Hodges,  Inc. 

Chemical  Works,  Inc. 

572 

Lewis  Tar  Products  Co. 

500 

Crown  Chemical  Co.,  Div.  of  Joseph  Turner 

573 

Morton-Withers  Chemical  Co. 

&  Co. 

574 

Poly  Resins,  Inc. 

501 

Ultra  Chemical  Works,  Inc. 

575 

Standard  Chemical  Co. 

502 

Ansbacher-Siegle  Corp. 

576 

Lubrizol  Corp. 

503 

Bristol  Laboratories,  Inc. 

577 

Toms  River-Cincinnati  Chemical  Corp. 

504 

Heyden  Chemical  Corp. 

578 

H.  M.  Chemical  Co. 

505 

Oil  &  Chemical  Products,  Inc. 

579 

Meta  Chemical  Corp. 

506 

Allied  Chemical  &  Dye  Corp.  (National 

580 

R.  S.  A.  Corp. 

Aniline  Div.). 

581 

Ringwood  Chemical  Corp. 

507 

Drew,  E.  F.,  &  Co.,  Inc. 

582 

Sohlo  Petroleum  Co. 

508 

Standard  Oil  Co.  of  Indiana. 

583 

Ciba  Products  Corp. 

509 

Riverdale  Chemical  Co. 

584 

Lebec  Chemical  Corp. 

510 

General  Aniline  &  Film  Corp.  (Dyestuff  & 

585 

Pennsalt  Chemicals  Corp.  (Sharpies 

Chemical  Div.) . 

Chemicals  Dlv.) . 

511 

Wallace  &  Tiernan,  Inc. 

586 

Stepan  Chemical  Co. 

512 

Reilly  Tar  &  Chemical  Corp. 

587 

Pennsalt  Chemicals  Corp. 

513 

Republic  Creosoting  Co. 

588 

Krishell  Laboratories,  Inc. 

514 

Gary  Chemicals,  Inc. 

589 

New  York  Color  &  Chemical  Co.,  Div.  of 

515 

Goodrich,  B.  F.,  Chemical  Co.  (Dlv.  of  B.  F. 

American  Qyewood  Co. 

Goodrich  Co.). 

590 

Solvent  Chemical  Co.,  Inc. 

516 

Phillips  Petroleum  Co. 

591 

General  Electric  Co. 

517 

Catalin  Corp.  of  America. 

592 

Universal  Western  Chemical  Corp. 

518 

Kendall  Refining  Co. 

593 

Detrex  Chemical  Industries,  Inc. 

519 

Collett-Week  Corp. 

594 

U^eth  Laboratories,  Inc. 

520 

Fiber  Chemical  Corp. 

595 

Vineland  Chemical  Co. 

521 

Beech-Nut  Life  Savers,  Inc. 

596 

Alliance  Color  &  Chemical  Co. 

522 

Cabot,  Godfrey  L.,  Inc. 

597 

Kolker  Chemical  Corp. 

523 

Diamond  Alkali  Co. 

598 

Onyx  Oil  &   Chemical  Co. 

524 

Dominion  Products,  Inc. 

599 

Bush,  W.  J.,  &  Co.,  Inc. 

525 

Farmers'  Chemical  Co. 

600 

Norda  Essential  Oil  &  Chemical  Co.,  Inc. 

526 

Greenwood  Textile  Supply  Co. 

601 

Synvar  Corp. 

527 

Nopco  Chemical  Co.,  Inc. 

602 

U.  S.  Oil  Co. 

528 

Pure  Oil  Co. 

603 

Allied  Chemical  &  Dye  Corp.  (Semet-Solvay 

529 

Union  Carbide  &  Carbon  Corp.  (Carbide  & 

Petrochemical  Div.). 

Carbon  Chemicals  Co.). 

604 

Koppers  Co.,  Inc.  (American  Aniline  Products) 

530 

Brown,  Andrew,  Co. 

605 

May,  Otto  B.,  Inc. 

531 

Imperial  Paper  &  Color  Corp.  (Pigment  Color 

606 

National  Chlorophyll  &  Chemical  Co.,  Div.  of 

Div.). 

Hofmann  Industries,  Inc. 

532 

California-Spray  Chemical  Corp. 

607 

Mobay  Chemical  Co. 

533 

Callison,  I.  P.,  &  Sons,  Inc. 

608 

Gelgy  Chemical  Corp. 

534 

Chemagro  Corp. 

609 

Produotol  Co. 

535 

Coastwise  Petroleum  Co. 

610 

National  Starch  Products,  Inc. 

536 

Hall,  C.  P.,  Co.  of  Illinois. 

SYNTHETIC  ORGANIC  CHEMICALS,  1956 


163 


Table  27. --Synthetic  organic  chemicals:   Di 

rector 

K  of  manufacturers,    i95(!- -Continued 

No. 

Name  of  company 

No. 

Name  of  company 

6U 
612 
613 
6U 
615 

Rayette,  Inc.  (Chemical  Div. ) . 

Tennessee  Copper  Co.,  Div.  Tennessee  Corp. 

Jergens,  Andrew,  Co. 

Crown  Zellerbaoh  Corp. 

Krystall  Chemical  Co. 

616 
617 
618 
619 
620 

Salem  Oil  &  Grease  Co. 

New  York  &   Pennsylvania  Co.,  Inc. 

International  Paper  Co. 

Helena  Curtis  Industries,  Inc. 

Amoco  Chemicals  Corp. 

164 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  2T.--Syntheti 


mic   chemicals:    Pirectory   of  wanufactv 
SECTION  2.  ALPHABETICAL  DIRECTORY 


i956- -Continued 


[Names  of  synthetic  organic  chemical  manufacturers  who  reported  production  or  sales  to  the  United  States 
Tariff  Commission  for  lyso  are  listed  below  alphabetically,  together  with  their  identification  numbers 
as  used  in  tables  in  part  III.  Section  1  of  this  table  lists  these  manufacturers  in  the  order  of  their 
identification  numbers] 


Name  of  company 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office) 


Abbott  Laboratories 

Acme  Resin  Corp 

Ad-Co  Color  Corp 

Advance  Solvents  i  Chemical  Div.  of 

Carlisle  Chemical  Works,  Inc. 
Air  Reduction  Chemical  Co 

Alco  Oil  &  Chemical  Corp 

Alframine  Corp 

Aliydol  Laboratories,  Inc 

Alliance  Color  &  Chemical  Co 

Allied  Chemical  i  Dye  Corp. : 

Barrett  Div 


General  Chemical  Div 

National  Aniline  Div 

Nitrogen  Div 

Semet-Solvay  Petrochemical  Div 

Solvay  Process  Div 

All-Tex  Specialties  Co 

Alox  Corp 

Althouse  Chemical  Co.,  Ino 

Amalgamated  Chemical  Corp 

American  Alcolac  Corp 

American  Aniline  &  Extract  Co. ,  Inc 

American  Bio-Synthetics  Corp 

American  Chemical  Paint  Co 

American  Cyanamid  Co 


American  Maize  Products  Co 

American  Marietta  Co 

Ferbert-Schomdorfer  Co.  Div 

American  Oil  Co.  (Texas) 

American  Potash  &  Chemical  Corp 

American  Rock  Wool  Corp 

American  Synthetic  Rubber  Corp 

American  Viscose  Corp 

Film  Div ■ 

Amoco  Chemicals  Corp 

Anderson  Chemical  Co 

Ansbacher-Siegle  Corp 

Ansul  Chemical  Co 

Apex  Chemical  Co.,  Inc 

Appleton  Coated  Paper  Co 

Arapahoe  Chemicals,  Inc.,  St  Arapahoe 

Special  Products,  Inc. 
Aroher-Daniele-Midland  Co 

Arco  Co 

Amour  &  Co. : 

Chemical  Div 

Armour  Laboratories  Div 

Armstrong  Cork  Co 

Arnold,  Hoffman  4  Co. ,  Inc 

Astra  Pharmaceutical  Products,  Inc-- 

Atlantic  Chemical  Corp 

Atlantic  Refining  Co 

Atlas  Powder  Co 

Aquaness  Dept 

Atlas  Processing  Co 

Atlas  Refinery,  Inc 

Baker  Castor  Oil  Co 


14th  St.  and  Sheridan  Rd. ,  North  Chicago,  111. 

1401  Circle  Ave.,  Forest  Park,  111. 

66  Lister  Ave.,  Newark  5,  N.  J. 

500  Jersey  Ave.,  New  Brunswick  (Jersey  City),  N.  J. 

150  E.  42d  St.,  New  York  17,  N.  Y.  (Calvert  City, 

Ky. ,  and  Bound  Brook,  N.  J.). 
Trenton  Ave.  and  William  St.,  Philadelphia  34,  Pa. 
72-76  Putnam  St.,  Paterson  4,  N.  J.  (Los  Angeles,  Calif.). 
3242  S.  50th  Ave.,  Cicero  50,  111. 
33  Avenue  P,  Newark  5,  N.  J. 

40  Rector  St.,  New  York  6,  N.  Y.  (Fairfield,  Ala.;  Calumet 
City  and  Chicago,  111. ;  Detroit,  Mich. ;  Edgewater  and 
Whippany,  N.  J.;  Greensboro,  N.  C;  Ironton,  Toledo,  and 
Youngstown,  Ohio;  and  Bethlehem,  Frankford,  and  Philadel- 
phia, Pa.). 

40  Rector  St.,  New  York  6,  N.  Y.  (Nichols,  Calif.;  Danville, 
111.;  Baton  Rouge,  La.;  Baltimore,  Md.;  Buffalo,  N.  Y.; 
and  Marcus  Hook,  Pa.) 

40  Rector  St.,  New  York  6,  N.  Y.  (Buffalo,  N.  Y.;  Hopewell, 
Va.;  and  Moundsville,  W.  Va.). 

40  Rector  St.,  New  York  6,  N.  Y.  (Omaha,  Nebr.;  South  Point, 
Ohio;  and  Orange,  Tex, ) . 

40  Rector  St.,  New  York  6  (Tonawanda),  N.  Y. 

P.  0.  Box  271,  Syracuse  1  (Solvay  Village),  N.  Y. 

65  Kfeadow  St.,  Warwick,  R.  I. 

3943  Buffalo  Ave.,  Niagara  Falls,  N.  Y. 

540  Pear  St. ,  Reading,  Pa. 

Ontario  and  Rorer  Sts.,  Philadelphia  34,  Pa. 

34^0  Fairfield  Rd. ,  Baltimore  26,  Ml. 

Venango  and  F  Sts.,  Philadelphia  34,  Pa. 

710  W.  National  Ave.,  Milwaukee  4,  Wis. 

Ambler,  Pa. 

30  Rockefeller  Plaza,  New  York  20,  N.  Y.  (Azusa,  Calif.; 
Stamford  and  Wallingford,  Conn.;  Avondale,  La.;  Bound 
Brook,  Linden,  Newark,  Princeton,  and  Woodbrldge,  N.  J.; 
Pearl  River,  N.  Y.;  Charlotte,  N.  C;  Marietta,  Ohio; 
Brldgevllle,  Pa.;  Damascus,  Va. ;  and  Willow  Island,  W.  Va.). 

250  Park  Ave. ,  New  York  17,  N.  Y. 

3400  13th  Ave.,  S.W. ,  Seattle  4,  Wash. 

12815  Elmwood  Ave. ,  Cleveland  11,  Ohio. 

P.  0.  Box  401,  Texas  City,  Tex. 

3030  W.  6th  St.,  Los  Angeles  54,  Calif. 

401  Arlington  Ave.,  Torrance,  Calif. 

P.  0.  Box  360,  Louisville  1,  Ky. 

1617  Pennsylvania  Blvd.,  Philadelphia  3  (Xfeadville),  Pa. 

Fredericksburg,  Va. 

P.  0.  Box  1712,  Brownsville,  Tex. 

3940  S'jmmlt  St.,  Weston,  Mich. 

92  Chestnut  Ave.,  Staten  Island  5,  N.  Y. 

1  Stanton  St.,  Marinette,  Wis. 

200  S.  First  St. ,  Elizabethport,  N.  J. 

1200  N.  Meade  St.,  J^pleton,  Wis. 

2800  Pearl  St.,  Boulder,  Colo. 

700  Investors  Bldg.,  Minneapolis  2,  Minn.  (Los  Angeles, 
Calif.;  Pensacola,  Fla.;  Minneapolis,  Minn.;  and  Newark, 
N.  J.). 

7301  Bessemer  Ave.,  Cleveland  27,  Ohio. 

1355  W.  31st  St.,  Chicago  9  (kfcCook),  111. 

Box  511,  Kankakee,  111. 

W.  Liberty  St.,  Lancaster  (Pittsburgh),  Pa. 

55  Canal  St.,  Providence  1,  R.  I.  (Dlghton,  Mass.;  Charlotte, 

N.  C;  and  Cincinnati,  Ohio). 
7  1/2  Neponset  St.,  Worcester  6,  Mass. 
153  Prospect  St.,  Passaic  (Nutley),  N.  J. 
260  S.  Broad  St.,  Philadelphia  1,  Pa.  (Port  Arthur,  Tex.). 
New  Murray  Road  8:  Concord  Pike,  Wilmington  99,  Del.  (Atlas 

Point,  Del.;  Tamaqua,  Pa.;  Memphis,  Tenn.;  and  Houston, 

Tex. ) . 
Houston  26,  Tex. 
P.  0.  Box  1786,  Shreveport,  La. 
142  Lookwood  St.,  Newark  5,  N.  J. 
120  Broadway,  New  York  5,  N.  Y.  (Los  Angeles,  Calif.,  and 

Bayonne,  N.  J.). 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


165 


TABLE  27. --Synthetic   organic  chemicals:    Di 


ifacturers,   J956- -Continued 


Name  of  caaspany 


Office  address  ( location  of  plant  given  In 
parentheses  If  not  In  same  city  as  office) 


Baker,  J.  T. ,  Qiemloal  Co- 

Taylor  Chemical  Dlv 

Barium  Reduction  Corp 

Bates  Chemical  Co 

Beech-Nut  Life  Savers,  Ino 

Belle  Chemical  Co.,  Inc 

Bennett's 

Benzol  Products  Co 

Berk,  F.  W.,  &  Co.,  Inc 

Berkeley  Chemical  Corp 

Berkshire  Color  &  Chemical  Co 

Blo-Rad  Laboratories 

Bios  Laboratories,  Ino 

Bird  &  Son,  Inc.,  Floor  Covering  Dlv- 

Blackman  Brands,  Inc 

Booty  Reslneers,  Inc 

Borden  Co.,  Chemical  Dlv 


Borg-Wamer  Corp. ,  Marbon  Chemical 
Div. 

Bristol  Laboratories,  Inc 

Brooklyn  Color  Works,  Inc 

Brown  Co 

Brovm,  Andrew,  Co 

Bruder,  M.  A.,  &  Sons,  Inc 

Bryant  Chemical  Corp 

Buckeye  Cellulose  Corp 

Buckman  Laboratories,  Ino 

Burkart-Schier  Chemical  Co 

Burroughs-Wellcome  &  Co.  (U.S.A.),  Inc 

Bush,  W.  J.,  k   Co.,  Ino 

Cabot,  Godfrey  L.,  Inc 

Cabot,  Samuel,  Inc. 

Cadet  Chemical  Corp 

Calhlo  Chemicals,  Inc 

California  Ink  Co.,  Inc 

California-Spray  Chemical  Corp 

Calllson,  I.  P.,  &  Sons,  Inc 

Calvert-Mount  Wlnans  Co 

Capital  Plastics,  Inc 

Carlisle  Chemical  Works,  Inc 

Carpenter-Morton  Co 

Carus  Chemical  Co.,  Inc 

Carwin  Co 

Gary  Chemicals,  Inc 

Catalin  Corp.  of  America 

Celanese  Corp.  of  America 

Marco  Products  Div 

Chase  Chemical  Corp 

Chemagro  Corp 

Chemical  Insecticide  Corp 

Chemical  Manufacturing  Co.,  Ino 

Chemical  Process  Co 

Chemico,  Inc 

Chemlek  Laboratories,  Inc 

Chemo-Puro  Manufacturing  Corp 

Chemstrand  Corp 

Chllds  Pulp  Colors,  Inc 

Clba  Pharmaceutical  Products,  Inc 

Clba  Products  Corp 

Cincinnati  Chemical  Works 

Cities  Service  Oil  Co 

City  Chemical  Corp 

Cleary,  W.  A.,  Corp 

Clinton  Com  Processing  Co 

Clover  Chemical  Co 

Coastwise  Petroleum  Co 

Cockerllle,  F.  0 - 

Colgate-Palmolive  Co 

Collett-Week  Corp 

Collway  Colors,  Inc 

Colton  Chemical  Co. ,  Dlv.  of  Air 

Reduction  Co.,  Inc. 
Columbia  Organic  Chemicals,  Inc 


600  N.  Broad  St.,  Phillipsburg,  N.  J. 

600  N.  Broad  St.,  PhilUpsburg,  N.  J.  (Penn  Yan,  N.  Y.). 

P.  0.  Box  8097,  S.  Charleston  3,  W.  Va. 

Scottdale  Rd. ,  Lansdowne,  Pa. 

Canajoharle,  N.  Y. 

534  Pearl  St. ,  Reading,  Pa. 

65  W.  First  St.,  South,  Salt  Lake  City  10,  Utah. 

237  South  St.,  Newark  5  (Nixon),  N.  J. 

Park  PI. ,  E. ,  Wood-Ridge,  N.  J. 

II  Summit  Ave.,  Berkeley  Heights,  N.  J. 
250  Delawanna  Ave.,  Delawanna,  N.  J. 

800  Delaware  St.,  Berkeley  9,  Calif. 
17  W.  60th  St.,  New  York  23,  N.  Y. 
East  Walpole  (Norwood),  Mass. 

III  Wesley  St.,  S.  Hackensack,  N.  J. 
A2  S.  3d  St.,  Newark,  Ohio. 

350  Madison  Ave.,  New  York  17,  N.  Y.  (Demopolls,  Ala.;  Los 
Angeles  and  Santa  Barbara,  Calif.;  Chicago  and  Illiopolis, 
111.;  Leominster  and  Peabody,  Mass.;  Middlesex,  N.  J.; 
Bainbrldge,  N.  Y. ;  Kernersvllle,  N.  C. ;  Philadelphia,  Pa.; 
Seattle,  Wash.;  and  Browntown  and  Springfield,  Wis.). 

7165  Chicago  Ave.,  Gary,  Ind. 

P.  0.  Box  657,  Syracuse  1,  N.  Y. 

Morgan  &  Norman  Aves.,  Brooklyn  22,  N.  Y. 

650  Main  St. ,  BerUn,  N.  H. 

5';31  District  Blvd.,  Los  Angeles  22,  Calif. 

52d  and  Grays  Ave.,  Philadelphia  43,  Pa. 

6  North  St.,  N.  Quincy  71,  Mass. 

P.  0.  Box  539,  Cincinnati  1,  Ohio  (Memphis,  Tenn.). 

1256  N.  McLean,  Menjihis  8,  Tenn. 

1228  Chestnut  St.,  Chattanooga  2,  Tenn. 

Scarsdale  Rd. ,  Tuckahoe  7,  N.  Y. 

137  Boston  Post  Rd.,  Cos  Cob,  Conn.  (Linden,  N.  J.). 

77  Franklin  St.,  Boston  10,  Mass. 

141  Milk  St.,  Boston  9  (Chelsea),  Mass. 

Burt,  N.  Y. 

380  Madison  Ave.,  New  York  17,  N.  Y.  (Perry,  Ohio). 

545  Sansome  St.,  San  Francisco  11  (Berkeley),  Calif. 

Lucas  and  Ortho  Way,  Richmond  4,  Calif. 

801  Lloyd  Bldg.,  Seattle  1  (Chehalls),  Wash. 
2325  Annapolis  Ave.,  Baltimore  30,  Md. 

1032  Sibley  Tower  Bldg.,  Rochester  4,  N.  Y.  (Brodhead,  Wis.). 

West  St.,  Reading  15,  Ohio. 

376  3d  St.,  Everett  49,  Mass. 

1375  8th  St.,  LaSalle,  111. 

Stiles  Lane,  North  Haven,  Conn. 

fiyders  Lane,  E.  Brunswick,  N.  J. 

1  Park  Ave.,  New  York  16,  N.  Y.  (Calumet  City,  111.;  Fords, 

N.  J.;  and  Ihomasville,  N.  C). 
180  Madison  Ave.,  New  York  16,  N.  Y.  (Amcelle,  IB.;  Celriver, 

S.  C;  Bishop  and  PBTtipa,  Tex.;  Celco,  Va. ;  and  Point 

Pleasant,  W.  Va. ) . 
290  Ferry  St.,  Newark  5  (Linden),  N.  J. 
3527  anallman  St. ,  Pittsburgh  1,  Pa. 
437  5th  Ave.,  New  York  17,  N.  Y.  (Pittsburgh,  Pa.). 
129  Montague  St.,  Brooklyn  1,  N.  Y.  (Metuohen,  N.  J.). 
Megonko  Rd.,  Ashland,  Mass. 
1901  Spring  St. ,  Redwood  City,  Calif. 
2508  E.  Bailey  Rd.,  Cuyahoga  Falls,  Ohio. 
4040  W.  123d  St.,  Worth,  111. 
150  Doremus  Ave.,  Newark  5,  N.  J. 
Courtland  Hwy.,  Decatur,  Ala.  (Gonzales,  Fla.). 
43  S'jmmlt  St. ,  Brooklyn  31,  N.  Y. 
556  Morris  Ave.,  Summit,  N.  J. 
Kimberton,  Pa. 

See   Toms  Rlver-Cinolnnatl  Chemical  Corp. 
Cities  Service  Bldg.,  Bartlesville  (Tallant),  Okla. 
132  W.  22d  St.,  New  York  11,  N.  Y.  (Jersey  City,  N.  J.). 
"Clearacres, "  Rt.  27,  Franklin  Township,  N.  J. 
Clinton,  Iowa. 

P.  0.  Box  10865,  Pittsburgh  36,  Pa. 
1127  Mtmsey  Bldg.,  Baltimore  2,  Md.  (Goodhope,  La.). 
Greenwood,  Va. 
300  Park  Ave.,  New  York  22,  N.  Y.  (Berkeley,  Calif.; 

Jeffersonville,  Ind.;  Kansas  City,  Kans.;  and  Jersey  City, 

N.  J.). 
(Joimby  St.,  Ossining,  N.  Y. 
15  Market  St. ,  Paterson  1,  N.  J. 
1747  Chester  Ave.,  Cleveland  14,  Ohio  (Elkton,  Mi.). 

1012  Drake  St.,  Columbia  5  (Cedar  Terrace),  S.  C. 


166  UNITED  STATES  TARIFF  COMMISSION 

TABLE  27. --Synthetic  organic  chemicals:   Directory  of  manufacturers,    1956 --Continued 


I 


Name  of  company 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office) 


Connnercial  Solvents  Corp 

Commonwealth  Color  &  Chemical  Co 

Concord  Chemical  Co.,  Ino 

Consolidated  Paint  Co 

Continental-Diamond  Fibre  Corp 

Continental  Oil  Co 

Cook  Paint  &  Varnish  Co 

Coopers  Creek  Chemical  Corp 

Copolymer  Rubber  i  Chemical  Corp 

Corn  Products  Refining  Co 

Cosden  Petroleum  Corp 

Cowles  Chemical  Co 

Crosby  Chemicals,  Inc 

Crown  Central  Petroleum  Corp 

Crown  Chemical  Co. ,  Div.  of  Joseph 

Turner  &  Co. 

Crown  Chemical  Corp 

Crownoil  Chemical  Co.,  Inc 

Crown  Tar  &  Chemical  Works,  Inc 

Crown  Zellerbach  Corp 

Cutter  Laboratories 

Dakota  Briquets  &  Tar  Products,  Ino— 

Davis,  H.  B. ,  Co 

Dawe's  Laboratories,  Inc 

Deecy  Products  Co 

Deere  &  Co.,  Grand  River  Chemical  Div 

Delaware  Chemicals,  Inc 

Delta  Chemical  Works,  Inc 

DePaul  Chemical  Co.,  Ino 

Detrex  Chemical  Industries,  Inc 

Dewey  &  Almy  Chemical  Co. ,  Div.  of 

W.  R.  Grace  &   Co. 

Dexter  Chemical  Corp 

Diamond  Alkali  Co 

Diversey  Corp 

Dodd,  Donald  A 

Dominion  Products,  Inc 

Douglas  Chemical  Corp 

Dow  Chemical  Co 

Dow  Coming  Corp 

Drew,   E.    F. ,   &  Co.,    Ino 

Drug  Processors,  Inc 

duPont  de  Nemours,  E.  I.,  &  Co.,  Inc- 


Dye  Specialties  Corp.,  Ino 

I^kem  Co 

Eaklns,  J.  S.,  &  W.  R. ,  Ino 

Eastern  States  Chemical  Corp 

Eastman  Kodak  Co- 

Tennessee  Eastman  Co.  Div •— — . 

Texas  Eastman  Co.  Div 

Edison,  ITiamas  A.,  Inc.,  Medical  Gas 

Div. 

Query  Industries,  Inc 

Qnkay  Chemical  Co 

Qmilsol  Chemical  Corp 

Endo  Laboratories,  Ino 

Esso  Standard  Oil  Co 

Loiilsiana  Div 

Ethyl  Corp 

Ethyl-Dow  Chemical  Co 

Evans  Chemetics,  Ino 

Falnnount  Chemical  Co. ,  Inc -- 


260  Madison  Ave.,  New  York  16,  N.  Y.  (Agnew,  Calif.;  Peoria, 
111.;  Terre  Haute,  Ind.;  Harvey  and  Sterlington,  La.). 

3240  Grace  Ave.,  New  York  69,  N.  Y. 

205  S.  2d  St.,  Camden,  N.  J. 

3101  E.  11th  St.,  Los  Angeles  23,  Calif. 

70  S.  Chapel  St.,  Newark,  Del.  (Bridgeport,  Pa.). 

1000  S.  Pine  St.,  Ponoa  City,  Okla. 

P.  0.  Box  389,  Kansas  City  41,  Mo. 

River  Rd.,  W.  Conshohooken,  Pa. 

P.  0.  Box  2591,  Baton  Rouge  1,  La. 

17  Battery  PI.,  New  York  4,  N.  Y.  (Argo,  111.). 

P.  0.  Box  1311,  Big  Spring,  Tex. 

7016  Euclid  Ave.,  Cleveland  3,  Ohio  (Skaneateles  Falls, 
N.  Y.). 

Box  111,  Picayune,  Miss.  (De  Ridder,  La.). 

American  Bldg.,  Baltimore  3,  Md.  (Houston,  Tex.). 

Pleasantview  Terrace,  Mdgefield,  N.  J. 

240  India  St.,  Providence  3,  R.  I. 

2-lA  49th  Ave.,  Long  Island  City  1,  N.  Y. 

900  Wewatta  St.,  Denver  4,  Colo. 

343  Sansome  St.,  San  Francisco  19,  Calif. 

4th  and  Parker  Sts. ,  Berkeley  1,  Calif. 

Box  446,  Dickinson,  N.  Dak. 

Bush  &  Severn  Sts.,  Baltimore  30,  Mi. 

4800  S.  Richmond  St.,  Chicago  32,  111.  (Newaygo,  Mich.). 

120  Potter  St.,  Cambridge  42,  Mass. 

Pry or,  Okla. 

50  Murray  St.,  Staten  Island  9,  N.  Y. 

23  W.  60th  St.,  New  York  23,  N.  Y. 

44-27  Purvis  St.,  Long  Island  City  1,  N.  Y. 

Box  501,  Detroit,  Mich.  (Ashtabula,  Ohio) . 

62  Whlttemore  Ave.,  Cambridge  40  (Acton),  Mass. 

819  Edgewater  Rd. ,  New  York  59,  N.  Y. 

300  Union  Commerce  Bldg.,  Cleveland  14,  Ohio  (Newark,  N.  J.; 
Painesville,  Ohio;  Houston  and  Pasadena,  Tex.;  and  Belle, 
W.  Va.). 

1820  N.  Roscoe  St.,  Chicago  13,  111. 

Rt.  5,  Box  621,  Everett,  Wash. 

10-40  44th  Dr. ,  Long  Island  City  1,  N.  Y. 

1624  Darrow  Ave.,  Evanston,  111. 

Midland,  Mich.  (Pittsburg  and  Torrance,  Calif.;  Gales  Perry, 
Conn.;  and  Freeport,  Tex.). 

Box  592,  Midland,  Mich. 

15  E.  26th  St.,  New  York  10,  N.  Y.  (Boonton,  N.  J.). 

1219  E.  Church  St.,  Adrian,  Mich. 

10th  and  Market  Sts.,  Wilmington  98,  Del.  (Birmingham,  Ala.; 
Antioch  and  S.  San  Francisco,  Calif.;  Louviera,  Colo.; 
Fairfield,  Conn.;  Edge  Xfoor,  Newport,  and  Seaford,  Del.; 
Tucker,  Ga.;  Chicago  and  Seneca,  111.;  E.  Chicago  and  Fort- 
ville,  Ind.;  Clinton  and  Ft.  Madison,  Iowa;  Louisville  and 
Wurtland,  Ky. ;  Baltimore,  Md.;  Everett  and  Leominster,  Jfass.; 
Ecorse,  Flint,  Montague,  and  Wyandotte,  Mich.;  Carl  Junction, 
Md.  ;  Arlington,  Carney's  Point,  Deepwater  Point,  Glbbs- 
town,  Kearny,  Linden,  Newark,  Parlin,  Perth  Amboy,  and 
Pon5)ton  Lakes,  N.  J.;  Buffalo,  Dresden,  Newburgh,  Niagara 
Falls,  and  Rochester,  N.  Y. ;  Kingston,  N.C.;  Circlevllle, 
Cleveland,  Columbia  Park,  and  Toledo,  Ohio;  Moosic,  Phila- 
delphia, and  Towanda,  Pa. ;  Camden,  S.  C. ;  Chattanooga, 
Columbia,  Memphis,  and  Old  Hickory,  Tenn.;  Beaumont,  LaPorte, 
Orange,  and  Victoria,  Tex.;  Martinsville,  Richmond,  and 
Waynesboro,  Va.;  DuPont,  Wash.;  Belle,  Charleston,  Martins- 
burg,  and  Parkersburg,  W.  Va.;  and  Barksdale,  Wis.). 

26  Journal  Sq. ,  Jersey  City  6,  N.  J. 

2307  N.  nth  St.,  St.  Louis  6,  Mo. 

55  Berry  St.,  Brooklyn  11,  N.  Y. 

P.  0.  Box  5008,  Harrlsburg  Sta. ,  HouBton  12,  Tex. 

343  State  St.,  Rochester  4,  N.  Y. 

Eastman  Rd. ,  Kingsport,  Tenn. 

P.  0.  Box  2068,  Longview,  Tex. 

P.  0.  Box  15,  Stuyvesant  Fills,  N.  Y. 

4300  Carew  Tower,  Cincinnati  2,  Ohio. 
319  2d  St.,  Elizabeth  1,  N.  J. 
75  E.  Wacker  Dr.,  Chicago  1,  111. 
84-40  101st  St.,  Richmond  Hill  18,  N.  Y. 
P.  0.  Box  23,  Linden,  N.  J. 
P.  0.  Box  551,  Baton  Rouge  1,  La. 

100  Park  Ave.,  New  York  17,  N.  Y.  (Baton  Rouge,  La.;  Orange- 
burg, S.  C;  and  Pasadena,  Tex.). 
Midland,  Mich.  (Freeport,  Tex.). 
250  E.  43d  St.,  New  York  17  (Waterloo),  N.  Y. 
600  Ferry  St.,  Newark  5,  N.  J. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 

TABLE  27 .--Synthetic  organic  chemicals:    directory  of  manufacturers,    1956 --Continued 


167 


Name  of  company 


Office  address  (location  of  plant  given  in 
parentheses  If  not  in  same  city  as  office) 


Farley  &  Loetscher  Manufacturing  Co— 

P&rmeTs'   Chemical  Co 

ftorington,  W.  U. ,  Estate  of 

plederal  Color  Laboratories,  Ino 

Pelton  Chemical  Co.,  Inc 

Ferro  Chemical  Corp — 

Fiber  Chemical  Cqrp 

Fiberboard  Paper  Products  Corp. ,  Pab- 

co  Paint  Div. 

Fine  Colors  Co 

Fine  Organios,  Inc 

Flnetex,  Inc 

Firestone  Tire  &   Rubber  Co 

Firestone  Plastics  Co.  Div 

Florasynth  Laboratories,  Inc 

Florida  Molasses  Corp 

Food  Machinery  &  Chemical  Corp: 

Fairfield  Chemical  Div 

Niagara  Chemical  Div 

Ohio- Apex  Div, 

Westvaoo  Chlor-AUcali  Div. ,  West- 
vaoo  Mineral  Products  Div . ,  and 
Chemical  Divisions  Management. 
Fbremost  Food  &  Chemical  Co.,  El 

Dorado  Div. 

Foster-Heaton  Co 

France,  Campbell  &  Darling,  Inc 

Freeman  Chemical  Corp 

Fries  Bros.,  Inc 

Frltzsche  Brothers,  Inc 

Frontier  Chemical  Co. ,  Div.  of  Union 

Chemical  &  Materials  Corp. 

Fuller,  W.  P.,  &  Co 

Gallowhur  Chemical  Corp 

Gamma  Chemical  Corp 

Gane's  Chemical  Works,  Inc 

Geigy  Chemical  Corp 

General  Aniline  Sc   Film  Corp.,  Hye- 

stuff  Sc   Chemical  Div. 

General  Color  Co.,  Ino 

General  Electric  Co. : 

Chemical  Materials  Dept 

Silicone  Products  Dept 

General  Foods  Corp.,  Maxwell  House 

Div. 

General  Mills,  Inc 

General  Petroleum  Corp 

General  Tire  &  Rubber  Co. ,  Chemical 

Div. 

George,  P.  D. ,  Co 

Oilman  Paint  &  Varnish  Co 

Givaudan  Corp- 

Glidden  Co 

Glyco  Products  Co.,  Inc 

Goodrich,  B.  F. ,  Co. : 

Goodrich,  B.  F. ,  Chemical  Co.  Div-- 


Goodrich-Gu-u'  Chemicals,  Ino 

Goodyear  Tire  &  Rubber  Co 

Goodyear  Synthetic  Rubber  Corp 

Pathfinder  Chemical  Corp 

Grace  Chemical  Co. ,  Div.  of  W.  R. 
Grace  &  >  ^. 

Grain  Processing  Corp  

Grand  Rapids  Varnish  Corp 

Great  Southern  Chemical  Corp 

Great  Western  Sugar  Co 

Greenwood  Textile  Supply  Co -- 

Gulf  Oil  Corp 

Guyaji  Color  &  Chemical  Works 

Halby  Products  Co.,  Inc 

Hall,  C.  P.,  Co.  of  Illinois 

Hampden  Color  &  Chemical  Co 

Hanna  Paint  Manufacturing  Co.,  Indus- 
trial Div. 

Harbor  Pl;ywood  Corp 

Harshaw  Chemical  Co 

Harsyd  Chemicals,  Inc 


7th  and  V/hite  Sts.,  Dubuque,  Iowa. 
3713  W.  Main  St.,  Kalamazoo,  Mich. 
Division  St.,  E.  Greenwich  (Warwick),  R.  I. 
-1633  Forest  Ave.,  Norwood,  Cincinnati  12,  Ohio. 
599  Johnson  Ave.,  Brooklyn  37,  N.  Y. 
450  Krick  fid..  Box  349,  Bedford,  Ohio. 
P.  0.  Box  218,  Matawan  (Cllffwood),  N.  J. 
P.  0.  Box  4314,  Oakland  ( Dneryville) ,  Calif. 

21-29  MoBride  Ave.,  Paterson  1,  N.  J. 

211  E.  19th  St.,  New  York  3,  N.  Y.  (Lodi,  N.  J.). 

418  F&lmouth  Ave.,  E.  Paterson,  N.  J. 

381  W.  Wllbeth  Rd. ,  Akron  1,  Ohio  (Lake  Charles,  La.). 

P.  0.  Box  690,  Pottstown,  Pa. 

900  Van  Nest  Ave.,  New  York  62,  N.  Y. 

Box  366,  Aubumdale  (Lake  Alfred  and  Winter  Garden),  Fla. 

1700-1901  Patapsoo  Ave.,  Baltimore  26,  m. 
100  Niagara  St.,  Middleport,  N.  Y.  (Arsenal,  Ark.). 
Nitro,  W.  Va. 

161  E.  42d  St. ,  New  York  17,  N. 
S.  Charleston,  W.  Va.). 


( Newark,  Calif. ,  and 


P.  0.  Box  599,  Oakland  4,  Calif. 

16  E.  5th  St.,  Paterson  4,  N.  J. 

Michigan  Ave. ,  Kenilworth,  N.  J. 

211  E.  Main  St.,  Port  Washington  (Saukville),  Wis. 

Rt.  17,  P.  0.  Box  8,  Carlstadt,  N.  J. 

76  9th  Ave.,  New  York  11,  N.  Y.  (Clifton,  N.  J.). 

Box  545,  Wichita,  Kans. 

P.  0.  Box  111,  S.  San  Francisco,  Calif. 

N.  Water  St.,  Ossining,  N.  Y. 

220  E.  42d  St.,  New  York  17,  N.  Y.  (Great  hfeadows,  N.  J.). 

677  5th  Ave.,  New  York  22,  N.  Y.  (Carlstadt,  N.  J.). 

P.  0.  Box  430,  Yonkers,  N.  Y.  (Cranston,  R.  I.). 

230  Park  Ave.,  New  York  17,  N.  Y.  (Calvert  City,  Ky. ;  Linden, 

N.  J.;  and  Rensselaer,  N.  Y. ). 
24  Ave.  B,  Newark  5,  N.  J. 

1  Plastics  Ave.,  Pittsfield,  Mass.  (Anaheim,  Calif.; 

Pittsfield,  Mass.;  Schenectady,  N.  Y.;  and  Coshocton, 

Ohio). 
Waterford,  N.  Y. 
1125  Hudson  St.,  Hoboken,  N.  J. 

400  2d  Ave.,  S. ,  Minneapolis  1,  Minn. 

612  S.  Flower  St. ,  Los  Angeles  54,  Calif. 

1708  Englewood  Ave.,  Akron  (Ashtabula  and  Mogadore) ,  Ohio. 

5200  N.  2d  St.,  St.  Louis  7,  Mo. 

216  W.  8th  St.,  Chattanooga  1,  Tenn. 

109-201  Delawanna  Ave. ,  Delawanna,  N.  J. 

900  Union  Commerce  Bldg.,  Cleveland  14,  Ohio  (San  Francisco, 
Calif.;  Jacksonville,  Fla.;  Chicago,  111.;  New  Orleans, 
La. ;  Minneapolis,  Minn. ;  Cleveland,  Ohio;  and  Reading,  Pa. ). 

Bnpire  State  Bldg.,  New  York  1,  N.  Y.  (Williamsport,  Pa.). 

3135  Euclid  Ave.,  Cleveland  15,  Ohio  (Calvert  City  and 

Louisville,  Ky. ;  Haledon  and  Kearny,  N.  J.;  Niagara  Falls, 
N.  Y.;  and  Akron  and  Avon  Lake  Village,  Ohio). 

3121  Euclid  Ave.,  Cleveland  15,  Ohio  (Port  Neches,  Tex., 
and  Institute,  W.  Va.). 

1144  E.  Market  St.,  Akron  16,  Ohio. 

P.  0.  Box  5397,  Houston,  Tex. 

5408  Baker  Ave.,    Niagara  Falls,    N.   Y. 

P.  0.  Box  4906,  Memphis  7,  Tenn. 

1600  Oregon  St. ,  Muscatine,  Iowa. 

1350  Steele  Ave.,  S.W.,  Grand  Rapids  2,  KUch. 

P.  0.  Box  4166,  Corpus  Christi,  Tex. 

P.  0.  Box  5308,  Terminal  Annex,  Denver  (Johnstown),  Colo. 

27  Meadow  St.,  Warwick,  R.  I. 

Gulf  Bldg.,  Pittsburgh  30,  Pa. 

Box  1088,  Huntington,  W.  Va. 

P.  0.  Box  366,  Wilmington  99,  Del. 

51A5  W.  67th  St. ,  Chicago  38,  111. 

5  Albany  St.,  Springfield  1,  Mass. 

1313  Windsor  Ave. ,  Columbus  16,  Ohio. 

Box  940,  Aberdeen,  Wash. 

1945  E.  97th  St.,  Cleveland  6,  Ohio  (Gloucester  City,  N.  J.). 

397  W.  21st  St.,  Holland,  Mich. 


168 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  T.-Syntheti 


lie   chemicals:    Directory   of  manufacturers,     7956- -Continued 


Office  address  (location  of  plant  given  in 

No. 

Name  of  company 

parentheses  if  not  in  same  city  as  office ) 

2i3 

1440  Broadway,  New  York  18,  N.  Y.  (Jersey  City,  N.  J.). 

67 

Hartman-Leddon  Co 

5821  Market  St.,  Philadelphia  39,  Pa. 

619 

Helene  Curtis  Industries,  Ino 

4401  W.  North  Ave.,  Chicago  39,  111. 

212 

Hercules  Powder  Co 

900  Market  St.,  Wilmington  99,  Del.  (Bruns-(rlok,Ga.;  Mansfield 
Mass.;  Hattiesburg,  Miss.;  Burlington,  Kenvil,  and  Parlin, 
N.  J.;  and  Hopewell,  Va.). 

255 

Heresite  &  Chemical  Co 

822  S.  14th  St.,  Manitowoc,  Wis. 

490 

Hexagon  Laboratories,  Inc 

3536  Peartree  Ave.,  New  York  69,  N.  Y. 

501 
578 

342  Madison  Ave.,  New  York  17,  N.  Y.  (Fords  and  Garfield, 

N.  J.). 
1754  22d  St.,  Santa  ^tonica,  Calif. 

H.  M.  Chemical  Co 

A% 

Hoffmann- LaRoche,  Inc 

324-424  Kingsland  Rd.,  Nutley  10,  N.  J. 

555 
'160 

P.  0.  Box  16U,  Springfield,  Mo. 
492  Douglas  Ave.,  Holland,  Mich. 

Holland  Color  Sc   Chemical  Co 

468 

Hooker  Electrochemical  Co 

Buffalo  Ave.  &  47th  St. ,  Niagara  Falls,  N.  Y. 

421 

Darez  Plastics  Div 

Walck  Rd.,  N.  Tonawanda,  N.  Y. 

187 

Oldbury  Products 

5001  Buffalo  Ave.,  Niagara  Falls,  N.  Y. 

497 

Houghton,  E.  F. ,  &  Co 

303  W.  Lehigh  Ave.,  Philadelphia  33,  Pa. 

393 

Hugglns,  James,  &   Son,  Inc 

239  Medford  St.,  Maiden  48,  Mass. 

434 

Humble  Oil  &  Refining  Co 

P.  0.  Box  2180,  Houston  1  (Baytown),  Tex. 

102 

Humphrey-Wilkinson,  Ino 

DeVine  St.,  North  Haven,  Conn. 

379 

Huron  Milling  Co - 

Harbor  Beach,  Mich. 

34 

Hynson,  Westoott  &  Dunning,  Inc 

Charles  4  Chase  Sts.,  Baltimore  1,  Md. 

531 

Imperial  Paper  &  Color  Corp. ,  Pigment 
Color  Div. 

P.  0.  Box  231,  Glens  Falls,  N.  Y. 

394 

Industrial  E(yestuff  Co 

Massasoit  Ave.  &  Dexter  Rd.,  P.  0.  Box  4249,  E.  Providence 

14,  R.  I. 
215  S.  Laurens  St. ,  Greenville,  S.  C. 

383 

Industrial  Products,  Ino 

68 

Inland  Steel  Container  Co- 

Interchemioal  Corp.: 

6532  S.  Menard  Ave.,  Chicago  38,  111. 

209 

Finishes  Div- 

224  McWhorter  St.,  Newark  1,  N.  J.  (Los  Angeles, 

Calif.;  Chicago,  111.;  Elizabeth  and  Newark,  N.  J.;  and 
Cincinnati,  Ohio). 

430 

Textile  Colors  Div 

150  Wagaraw  Rd.,  Hawthorne,  N.  J. 

110 

International  Minerals  &  Chemical 

20  N.  Wacker  Dr.,  Chicago  6,  111.  (San  Jose,  Calif.; 

Corp. 

Skokie,  111.;  and  Niagara  Falls,  N.  Y.). 

618 

International  Paper  Co 

220  E.  42d  St.,  New  York  17,  N.  Y.  (Corinth,  N.  Y.,  and 
York  Haven,  Pa. ) . 

136 

Ironsides  Co 

270  W.  Mound  St.  (P.  0.  Box  1999),  Columbus  16,  Ohio. 

405 

Jefferson  Chemical  Co.,  Ino 

P.  0.  Box  303,  Houston  (Port  Neohes) ,  Tex. 

544 

Box  M,  Station  E,  Toledo  9,  Ohio. 

613 

Jergens,  Andrew,  Co 

2535  Spring  Grove  Ave. ,  Cincinnati  14,  Ohio. 

111 

Jones-Dabney  Co 

W81  S.  11th  St.,  Louisville  8,  Ky. 

239 

Jordan,  Jr.,  W.  H. ,  &  F. ,  Manufac- 
turing Co. 

2126  E.  Somerset  St. ,  Philadelphia  34,  Pa. 

425 

Kali  Manufacturing  Co- - - 

427  E.  Moyer  St.,  Philadelphia  25,  Pa. 

52 
330 
103 

19  S.  Canal  St.,  Lawrence,  Mass. 

180  Madison  Ave.,  New  York  16  (West  Haverstraw) ,  N.  Y. 

40  Oliver  St.,  Boston  10  (Everett),  Mass. 

Kehew-Bradley  Co 

317 

Kelly,  John  F. ,  Co 

956  Bransten  Rd.  (Box  791),  San  Carlos,  Calif. 

518 

Kendall  Refining  Co 

Kennecott  Copper  Corp. : 

77  N.  Kendall  Ave.,  Bradford,  Pa. 

88 

Chino  Mines  Div 

Hurley,  N.  Mex. 

450 

Utah  Copper  Div 

310  Keams  Bldg.,  Salt  Lake  City  10  (Arthur  and 
Magna),  Utah. 

219 

Kentucky  Color  &  Chemical  Co 

600  N.  34th  St.,  Louisville  12,  Ky. 

359 

Kessler  Chemical  Co.,  Inc 

State  Rd.  and  Cottman  Ave.,  Philadelphia  35,  Pa. 

351 

R.  D.  #1,  Bethlehem,  Pa. 

74 

Keystone  Color  Works,  Inc 

151  W.  Gay  Ave. ,  York,  Pa. 

548 

Keystone  Paint  &  Varnish  Corp 

71  Otsego  St. ,  Brooklyn  31,  N.  Y. 

448 
539 

101  Canal  St.,  Lock  Haven,  Pa. 

436  Clementina  St.,  San  Francisco  3,  Calif. 

King,  0.  L.,  &  Co 

35 

Knoedler  Chemical  Co 

651  High  St.,  Lancaster  1,  Pa. 

192 

Kohnstamm,  H.,  &  Co.,  Ino 

87  Park  PI.,  New  York  7  (Brooklyn),  N.  Y. 

597 

600  Doremus  Ave.,  Newark  5,  N.  J. 

Koppers  Co. ,  Inc.; 

604 

American  Aniline  Products 

Koppers  Bldg. ,  430  7th  Ave. ,  Pittsburgh  19,  Pa. 

367 

Chemical  Div 

Koppers  Bldg.,  430  7th  Ave.,  Pittsburgh  19,  Pa. 
(Berkeley  Hts.,  N.  J.;  Kobuta,  Oil  City,  and 
Petrolia,  Pa.;  and  Port  Arthur,  Tex.). 

367 

Tar  Products  Div 

Koppers  Bldg. ,  430  7th  Ave. ,  Pittsburgh  19,  Pa. 

(Woodward,  Ala.;  Fontana,  Calif.;  New  Haven,  Conn.; 
Chicago,  111.;  Chalmette,  La.;  Bangor  and  Portland, 
Maine;  Everett  and  Westfield,  Mass.;  St.  Paul,  Minn.; 
Kearny  and  Westfield,  N.  J.;  Buffalo,  Rochester,  and 
Utica,  N.  Y. ;  Hamilton,  Warren,  and  Youngstown,  Ohio; 
Swedeland  and  Swissvale,  Pa.;  E.  Providence,  R.  I.; 
Memphis,  Tenn.;  Houston,  Tex.;  Follansbee,  W.  Va.; 
and  Carrollville,  Wis.). 

588 

Krishell  Laboratories,  Inc 

1735  S.  E.  Powell  Blvd.,  Portland  6,  Oreg. 

41 

Krumbhaar  Chemical  Co.,  Ino 

24-30  Jacobus  Ave.,  S.  Kearny,  N.  J. 

615 

Krystall  Chemical  Co 

2108  N.  Southport  Ave.,  Chicago  lA,  111. 

75 
137 
23 

2d  4  Boston  Sts.,  Everett  49,  Mass. 
1707  E.  North  Ave.,  Milwaukee  1,  Wis. 
603  W.  Davenport  St.,  Rhinelander,  Wis. 

Lake  States  Yeast  Corp 

SYNTHETIC  ORGANIC  CHEMICALS,  1956 


169 


TABLE  27. -Synthetic  organic  chemicals:   Directory  of 


jfacturers,    i956- -Continued 


Name  of  oorapaiiy 


Office  address  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office) 


LaMotte  Chemical  Products  Co 

Laros,  R.  K. ,  Co 

LaSalle  Chemical  Co 

Laurel  Soap  Manufacturing  Co.,  Inc-- 

Leatex  Chemical  Co- 

Lebanon  Chemical  Corp 

Lebec  Chemical  Corp 

Leffingwell  Chemical  Co- 

Lemke,  B.  L. ,  i  Co.,  Inc 

Leonard  Refineries,  Inc. ,  Roosevelt 
Div. 

Lever  Brothers  Co- 

Lever,  C. ,  Co.,  Inc 

Levey,  Fred'k.  H.,  Co.,  Inc 

Lewis  Tar  Products  Co 

Lilly,  Eli,  &   Co- - 

Lobica-Debruille,  Inc 

Long,  Charles  R. ,  Jr.,  Co- 

Loven  Chemical  Co.  of  California 

Lubrizol  Corp 

Lueders,  George,  i  Co 

Lyle  Branchflower  Co 

Maas  Sc  Waldstein  Co 

Magnolia  Petroleum  Co 

Magruder  Color  Co.,  Inc 

Mallinckrodt  ChenlcEil  Works 

Marathon  Corp. ,  Chemical  Sales  Dept- 

Marblette  Corp 

Marden-Wild  Corp — ■ 

Marlowe-Van  Loan  Corp -■ 

Marx,  Max,  Color  &  Chemical  Co 

Maryland  Plastics,  Inc 

Maumee  Chemical  Co- 

May,  Otto  B. ,  Inc 

Maywood  Chemical  Works 

McCloskey  Varnish  Co 

McGean  Chemical  Co- 

Medical  Chemicals  Corp 

Merck  &  Co.,  Inc 

Merichem  Co 

Jiterrell,  Wm.  S. ,  Co - ■ 

(feta  Chemical  Corp 

Ifetalsalts  Corp 

Metro- Atlantic,  Inc 

Metro  Eyestuff  Corp 

Meyer,  J.,  &  Sons,  Inc 

Michigan  Chemical  Corp 

Midland  Industrial  Finishes  Co 

Miles  Laboratories,  Inc 

Mineral  Oil  Refining  Co 

Minnesota  Mining  &  Manufacturing  Co 
Irvington  Chemical  Div. 

Minnesota  Paints,  Inc 

Miranol  Chemical  Co.,  Inc 

Ktobay  Chemical  Co 

Monsanto  Chemical  Co 


Montrose  Chemical  Co 

Montrose  Chemical  Corp.  of  California 

Moretex  Chemical  Products 

Morton-Withers  Chemical  Co 

Marwear  Paint  Co 

National  Biochemical  Co 

National  Chlorophyll  &  Chemical  Co., 
Div.  of  Hofmann  Industries,  Inc. 

National  Distillers  Products  Corp- 

National  Lead  Co 

National  Petro-Chemicals  Corp 

National  Polychemicals,  Inc 

National  Starch  Products,  Inc 

Nease  Chemical  Co.,  Inc 

Nelson-Wells  &  Co— — 

Nepera  Chemical  Co.,  Inc 

Neville  Chemical  Co- 


Chestertown,  Md. 

Broad  &  Wood  Sts.,  Bethlehem,  Pa. 

21-23  Merseles  St.,  Jersey  City  2,  N.  J. 

Tioga  &  Thompson  Sts.,  Philadelphia  34,  Pa. 

2722  N.  Hancock  St.,  Philadelphia  33,  Pa. 

P.  0.  Box  532,  Lebanon,  Pa. 

1A066  S.  Garfield  Ave.,  Paramount,  Calif. 

P.  0.  Box  1016,  Whittier,  Calif. 

199  Main  St.,  Lodi,  N.  J. 

P.  0.  Box  271,  Mt.  Pleasant,  Mich. 

390  Park  Ave.,  New  York  22,  N.  Y. 

Howard  and  Huntington  Sts. ,  Philadelphia  33,  Pa. 

380  Madison  Ave.,  New  York  17  (Brooklyn),  N.  Y. 

P.  0.  Box  A,  lyons  (McCook),  111. 

7'10  S.   Alabama  St. ,    Indianapolis  6,    Ind. 

1841  Broadway,    New  York  23,   N.   Y. 

1630  W.   Hill  St.,   Louisville  10,   Ky. 

2387-4  Pine  St.,   Newhall,   CaUf. 

Cleveland  17,   Ohio. 

427  Washington  St.,    New  York  13  (Brooklyn),    N.   Y. 

15th  Ave.,    N.   W.,   at  Shilshole,  Seattle  7,  Wash. 

2121  McCarter  Hwy. ,   Newark  4,   N.   J. 

P.   0.    Box  900,   Dallas  21  (Beaumont),    Tex. 

2385  Richmond  Ter.,  Staten  Island  2,  N.  Y. 

3600  N.  2d  St.,  St.  Louis  7,  Mo.  (Jersey  City,  N.  J.). 

Rothschild,  Wis. 

37-21  30th  St.,  Long  Island  City  1,  N.  Y. 

500  Columbia  St. ,  Somervllle  43,  Mass. 

Box  1851,  High  Point,  N.  C. 

188-194  Coit  St. ,  Irvington  11,  N.  J. 

251  E.  Central  Ave.,  Federalsburg  (Ridgely),  Mi. 

2  Oak  St.,  Toledo  5,  Ohio. 

52  Amsterdam  St.,  Newark  5,  N.  J. 

lOD  W.  Hunter  Ave.,  Maywood,  N.  J. 

7600  State  Rd. ,  Philadelphia  36,  Pa. 

1040  Midland  Bldg.,  Cleveland  15,  Ohio. 

4122  W.  Grand  Ave.,  Chicago  51,  lU. 

Lincoln  Ave.,  Rahway,  N.  J.  (Albany,  Ga. ; 

Rahway,  N.  J.;  Danville,  Philadelphia,  and 

West  Point,  Pa.;  and  Eliton,  Va.). 
3101  ftonin  St.,  Houston  4  (Green's  Bayou),  Tex. 
Galbraith  Rd.  and  Pennsylvania  R.  R. , 

Cincinnati  15,  Ohio. 
214  1/2  Washington  Ave.,  Carlstadt,  N.  J. 

200  Wagaraw  Rd. ,  Hawthorne,  N.  J. 
2072  Smith  St.,  Centerdale  11,  R.  I. 
129  Quidnlck  St.,  West  Warwick,  R.  I. 
4321  N.  4th  St. ,  Philadelphia  40,  Pa. 
500  N.  Bankson  St.,  St.  Louis,  Mich. 
E.  Water  St.,  Waukegan,  111. 
Elkhart,  Ind. 

P.  0.  Box  625,  Dickinson,  Tex. 
500  Doremus  Ave.,  Newark  5,  N.  J. 

1101  S.  3d  St.,  Minneapolis  15,  Minn. 

277  Coit  St.,  Irvington  11,  N.  J. 

1901  S.  2d  St.,  St.  Louis  4,  Mo.  (New  Martins- 
ville, W.  Va.). 

800  N.  12th  Blvd.,  St.  Louis  1,  Ito.  (Annistcn, 
Ala.;  Long  Beach  and  Santa  Clara,  Calif.; 
Monsanto,  111.;  Kansas  City,  Kans.;  Everett 
and  Springfield,  Mass.;  Trenton,  Mich.; 
Camden,  N.  J.;  Texas  City,  Tex.;  Seattle, 
Wash.;  and  Nitro,  W.  Va.). 

120  Lister  Ave.,  Newark  5,  N.  J. 

824  Wilshire  Blvd.,  Los  Angeles  17  (Torrance),  Calif. 

314  W.  Heniy  St. ,  Spartanburg,  S.  C. 

2110  High  Point  Rd.,  Greensboro,  N.  C. 

568  14th  St.,  Oakland  12,  Calif. 

3106  W.  Lake  St.,  Chicago  12,  111. 

Sinking  Spring,  Pa.  (Lamar,  Colo.). 

See  U.  S.  Industrial  Chemicals  Co. 

Ill  Broadway,  New  York  6,  N.  Y.  (San  Francisco,  Calif. 

Perth  Amboy,  N.  J. ;  and  Philadelphia,  Pa. ) . 
Box  109,  Tuscola,  111. 
Eames  St.,  Wilmington,  Mass. 
270  Madison  Ave.,  New  York  16,  N.  Y.  (Iferedosia,  111., 

and  Plainfield,  N.  J.). 
Lock  Haven,  Pa. 
Box  348,  Red  Bluff,  Calif. 

21  Gray  Oaks  Ave.,  Yohkers  2  (Harriman),  N.  Y. 
Neville  Island,  Pittsburgh  25,  Pa.  (Anaheim,  Calif.). 


170 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  27. --Synthetic  orga 


ry  of 


7956- -Continued 


Name  of  company 


Office  address  (location  of  plant  given  in 
parentheses  If  not  in  same  city  as  office) 


New  Jersey  Zinc  Co.  (of  Pa.) 

Newport  Industries,  Inc 

New  York  Color  &  Chemical  Co.,  Div.  of 
American  Dyewood  Co. 

New  York  &  Pennsylvania  Co. ,  Inc 

New  York  Quinine  &  Chemical  Works, Inc. 

Nilok  Chemicals,  Inc 

Ninol  Laboratories,  Inc 

Nonweiler,  A.  P.,  Co 

Nopco  Chemical  Co.,  Inc 

Norda  Essential  Oil  &  Chemical  Co.,  Inc, 

Northwestern  Chemiceil  Co 

Norwich  Pharmaoal  Co 

Nuodex  Products  Co.,  Div.  of  Heyden 

Newport  Chemical  Co. 
Ohio  Chemical  Sc   Surgical  Equipment  Co 

Oil  &  Chemical  Products,  Inc 

Old  Colony  Tar  Co.,  Inc 

Old  Hickory  Chemical  Co.,  Inc 

Olin  Mathieson  Chemical  Corp 

Blockson  Chemical  Co.  Div 

Squibb,  E.  R. ,  &  Sons  Div 

Oryx  Oil  Sc   Chemical  Co 

Orbis  Products  Corp 

Organic  Chemical  Corp 

Organios,  Inc 

Oronite  Chemical  Co 

Ortho  Chemical  Corp 

Osborn,  C.  J.,  Co 

Ottol  Oil  Co — - 

Pabst  Brewing  Co 

Pacific  Paint  &  Varnish  Co 

Pacific  Yeast  Products,  Inc 

Paisley  Products,  Inc 

Pan  American  Petroleum  Corp 

Parke,  Davis  &  Co 

Parsons,  M.  W. ,  Plymouth,  Inc 

Patent  Chemicals,  Inc 

Paul-Lewis  Laboratories,  Inc 

Peck's  Products  Co 

Peerless  Chemical  Co 

Peerless  Color  Co.,  Inc 

Penick,  S.  B. ,  Sc   Co 

Pennsalt  Chemicals  Corp 

Sharpies  Chemicals  Div 

Pennsylvania  Industrial  Chemical  Corp 

Pennsylvania  Refining  Co 

Perkins  Glue  Co 

Permutit  Co 

Petroleum  Chemicals,  Inc 

Petrolite  Corp.,  Tretolite  Co.  Div — 

Fetro-Tex  Chemical  Corp 

pfanstiehl  Laboratories,  Inc 

Pfister  Chemical  Works,  Inc 

Pfizer,  Charles,  &  Co.,  Inc 

Pharma  Chemical  Corp 

Phillips  Chemical  Co - 

Phillips  Petroleum  Co 

Phoenix  Oil  Co 

Pilot  California  Co-- - 

Pitt-Consol  Chemical  Co 

Pittsburgh  Coke  &  Chemical  Co 

Pittsburgh  Plate  Glass  Co 

Planetary  Chemical  Co.,  Inc 

Plastics  Engineering  Co 

Polychemioal  Laboratories,  Inc 

Poly  Resins,  Ino 

Portland  Gas  4  Coke  Co — 

Poughkeepsie  Dyestuff  Corp 

Pratt  Sc  Lambert,  Ino 

Premium  Chemicals,  Inc 

Premo  Pharaoeutical  Laboratories,  Inc 


160  Front  St.,  New  York  38,  N.  Y.  (Palmerton,  Pa.). 

P.  0.  Box  911,  Pensacola,  Fla. 

J&ln  &  Joralemon  Sts.,  Belleville  9,  N.  J. 

-425  Park  Ave.,  New  York  22,  N.  Y. 

50  Church  St.,  New  York  7,  N.  Y.  (Newark,  N.  J.). 

2000  College  Ave.,  Niagara  I^lls  (Lockport),  N.  Y. 

1719  S.  Clinton  St. ,  Chicago  16,  111. 

Box  1007,  Oshkosh,  Wis. 

1st  and  Essex  Sts.,  Harrison,  N.  J.  (Richmond,  Calif.; 

Cedartown,  Ga. ;  and  Harrison,  N.  J.). 
601  W.  26th  St.,  New  York  1,  N.  Y.  (Boonton,  N.  J.). 
120  N.  Aurora  St.,  West  Chicago,  111. 
17  Eaton  Ave.,  Norwich,  N.  Y. 
830  Magnolia  Ave.,  Elizabeth,  N.  J.  (Long  Beach,  Calif.). 

1400  E.  Washington  Ave.,  Madison  10,  Wis.  (Cleveland,  Ohio). 
295  Madison  Ave.,  New  York  17,  N.  Y.  (Houston,  Tex.). 
500  5th  Ave.,  New  York  36,  N.  Y.  (Cambridge,  Framingham, 

New  Bedford,  and  Worcester,  Mass.). 
P.  0.  Box  U80,  Richmond  12,  Va.  (Old  Hickory,  Tenn. ) . 
Mathieson  Bldg. ,  Baltimore  3,  liW.  (Huntsville  and  Mcintosh, 

Ala.;  Doe  Run,  Ky.;  Lake  Charles,  La.;  Niagara  Falls, 

N.  Y.;  and  Morgantown,  W.  Va.). 
Joliet,  111. 
745  5th  Ave.,  New  York  22,  N.  Y.  (New  Brunswick,  N.  J., 

and  Brooklyn,  N.  Y.). 
Warren  4  Morris  Sts.,  Jersey  City  2,  N.  J. 
601  W.  26th  St.,  New  York  1,  N.  Y.  (Newark,  N.  J.). 
74-84  Valley  St.,  E.  Providence  14,  R.  I. 
1724  Greenleaf  Ave.,  Chicago  26,  111. 
200  Bush  St.,  San  Francisco  4,  Calif.  (Oak  Point,  La.). 
44-26  Purvis  St.,  Long  Island  City  1,  N.  Y. 
UOl  W.  Blanoke  St.,  Linden,  N.  J. 
455  Cortlandt  St.,  Belleville  9,  N.  J. 
917  W.  Jiineau,  Milwaukee  18,  Wis,  (Peoria,  111.). 
4th  and  Cedar  Sts.,  Berkeley  10,  Calif. 
703  5th  St.,  Wasco,  Calif. 
1770  Canalport  Ave.,  Chicago  16,  111. 
Box  591,  Tulsa,  Okla.  (Alvin,  Carthage,  Katy,  Pettus,  and 

Sweeny,  Tex. ) . 
Foot  of  Joseph  Campau,  Detroit  32,  Mich. 
59  Beekman  St.,  New  York  38  (Brooklyn),  N.  Y. 
335  McLean  Blvd.,  Pater son  4,  N.  J. 
4253  N.  Port  Washington  Rd.,  Milwaukee  12,  Wis. 
610  E.  Clarence  Ave.,  St.  Louis  15,  Mo. 
3850  Oakman  Blvd.,  Detroit  4,  Mich. 
521-535  North  Ave.,  Plainfield,  N.  J. 
50  Church  St.,  New  York  8,  N.  Y.  (Jersey  City,  I^yndhurst, 

and  Montville,  N.  J.). 
3  Penn  Center  Plaza,  Philadelphia  2,  Pa.  (Calvert 

City,  Ky.  ). 

3  Penn  Center  Plaza,  Philadelphia  2,  Pa.  (Wyandotte,  Mich.). 
120  State  St.,  Clairton  (Chester),  Pa. 

Butler  (Karns  City),  Pa. 

632  Cannon  Ave.,  Lansdale,  Pa.  (W.  Memphis,  Ark.). 

330  W.  42d  St.,  New  York  36,  N.  Y.  (Birmingham,  N.  J.). 

P.  0.  Box  6,  New  Orleans  (Lake  Charles),  La. 

369  Marshall  Ave.,  Webster  Groves  19,  Mo. 

P.  0.  Box  2584,  Houston  1,  Tex. 

104  Lakeview  Ave.,  Waukegan,  111. 

Foot  of  Linden  Ave.,  Ridgefield,  N.  J. 

630  Flushing  Ave.,  Brooklyn  6,  N.  Y.  (Groton,  Conn.,  and 
Vigo,  Ind. ) . 

175  5th  Ave.,  New  York  10,  N.  Y.  (Bayonne,  N.  J.). 

Adams  Bldg.,  Bartlesville,  Okla.  (Borger  and  Pasadena,  Tex.). 

Bartlesville,  Okla.  (Phillips,  Tex.). 

9505  Cassius  Ave.,  Cleveland  5,  Ohio. 

215  W.  7th  St.,  Los  Angeles  14  (Los  Nietos) ,  Calif. 

191  Doremus  Ave.,  Newark  5,  N.  J. 

Grant  Bldg.,  Pittsburgh  25,  Pa. 

1  Gateway  Center,  Pittsburgh  22,  Pa.  (Torrance,  Calif.; 
Atlanta,  Ga.;  Detroit,  Mich.;  Newark,  N.  J.;  Barberton, 
Cleveland,  and  Dayton,  Ohio;  Springdale,  Pa. ;  Houston, 
Tex.;  New  Martinsville,  W.  Va.;  and  Milwaukee,  V/is.). 

3500  DeKale  St.,  St.  Louis  18,  Mo. 

1607  Geele  Ave.,  Sheboygan,  Wis. 

494  Hunts  Point  Ave.,  New  York  59,  N.  Y. 

11661  Wicks  St.,  Sun  Valley,  Calif. 

Public  Service  Bldg. ,  Portland  4,  Oreg. 

77  N.  Water  St.,  Poughkeepsie,  N.  Y. 

75  Tonawanda  St.,  Buffalo  7,  N.  Y. 

4  Marine  St. ,  Farmingdale,  Long  Island,  N.  Y. 
Ill  Leuning  St. ,  S.  Hackensaok,  N.  J. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


171 


TABLE  27. --Syntheti 


rganic  chemicals:   Directory  of  manufacturers ,    7956 --Continued 


Name  of  compaiiy 


Office  addreee  (location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office) 


Procter  Sc  Gamble  Co- 


Productol  Co 

Publicker  Industries,  Inc 

Puget  Sound  Pulp  &  Timber  Co 

Pure  Oil  Co 

Purex  Corp.,  Ltd 

Purooaine,  Inc 

Quaker  Chemical  Products  Corp 

Quaker  Oats  Co 

R.  S.  A.  Corp 

Raybestos  Div.  of  Raybestos-Manhattan, 
Inc  . 

Rayette,  Inc.,  Chemical  Div 

Red  Spot  Paint  &  Varnish  Co.,  Inc 

Reichhold  Chemicals,  Inc 


Reilly  Tar  Sc  Chemical  Corp 

Reliance  Varnish  Co.,  Inc 

Remington  Arms   Co.,  Inc 

Republic  Creosoting  Co 

Richardson  Co 

Richfield  Oil  Corp 

Rlker  Laboratories,  Inc 

Ringwood  Chemical  Corp 

Rinshed-Mason  Co 

Ritter,  F. ,  Sc   Co - 

Ritter  Chemical  Co.,  Inc 

Rlverdale  Chemical  Co 

Roberts  Chemicals,  Inc 

Rohm  &  Haas  Co 

Root  Chemicals,  Inc 

Royce  Chemical  Co 

Rubber  Corp.  of  America 

Ruberoid  Co 

Salem  Oil  &  Grease  Co 

Dr.  Salsbury's  Laboratories 

Salvo  Chemical  Corp 

Sandoz,  Inc 

Schenectady  Varnish  Co.,  Inc 

Scherer,  R.  P.,  Corp 

Schering  Corp 

SchieffeUn  &   Co - 

Scholler  Bros . ,  Inc 

SchuylJd.ll  Chemical  Co 

Schwarz  Laboratories,  Inc 

Searle,  G.  D. ,  &  Co 

Shawinigan  Resins  Corp 

Sheffield  Chemical  Co.,  Div.  of 

Sheffield  Farms  Co.,  Inc. 
Shell  Chemical  Corp 

Shell  Oil  Co 

Shepherd  Chemical  Co 

Sherwin-Williams  Co 


Shulton,  Inc.,  Fine  Chemicals  Dlv- 

Siddall,  Geo.  F. ,  Co.,  Inc 

Simpson  Redwood  Co 

Sinclair  Refining  Co 

Sinclair  &  Valentine  Co 

Sipe,  James  B.,  Sc  Co 


301  E.  6th  St.,  Cincinnati  2,  Ohio.  (Long  Beach  and 
Sacramento,  Calif.;  Chicago,  111.;  Iowa  City,  Iowa; 
Kansas  City,  Kans.;  Baltimore,  Md.;  Quincy,  Mass.;  St. 
Louis,  Mo.;  Staten  Island,  N.  Y.;  St.  Bernard,  Ohio;  and 
Dallas,  Tex.). 

417  S.  Hill  St.,  Los  Angeles  13  (Santa  Fe  Springs),  Calif. 

U29  Walnut  St.,  Philadelphia  2,  Pa. 

300  Laurel  St. ,  Bellingham,  Wash. 

35  E.  Wacker  Drive,  Chicago  1,  111.  (Toledo,  Ohio;  Dollar- 
hide,  Snyder,  Nederland,  and  Van,  Tex.;  Cabin  Creek, 
W.  Va. ;  and  Worland,  Wyo.). 

9300  Rayo  Ave.,  South  Gate,  Calif.  (St.  Louis,  Mo.). 

Valley  Rd.,  Hockessin,  Del. 

Lime  &  Elm  Sts.,  Conshohocken,  Pa. 

Merchandise  Mart  Plaza,  Chicago  54,  111.  (Cedar  Rapids, 
Iowa;  Omaha,  Nebr.;  and  Memphis,  Tenn.). 

690  Saw  Mill  River  Rd. ,  Ardsley,  N.  Y. 

P.  0.  Box  1021,  Bridgeport,  Conn. 

261  E.  5th  St.,  St.  Paul  1,  Minn. 

110-112  Main  St.,  Evansville  8,  Ind. 

525  N.  Broadway,  V/hite  Plains,  N.  Y.  (Tuscaloosa,  Ala.; 

Azusa,  Calif;  Jacksonville,  Fla.;  Argo,  111.;  Kansas 

City,  Kans.;  Ballard  Vale,  Mass.;  Ferndale,  Mich.; 

Elizabeth,  N.  J.;  Brooklyn,  N.  Y.;  Charlotte,  N.  C;  and 

Seattle  and  Tacoma,  Wash.). 
1615  Merchants  Bank  Bldg.,  Indianapolis  4,  Ind. 

(Chicago  and  Granite  City,  111.;  Indianapolis,  Ind.; 

Newark,  N.  J.;  Cleveland  and  Dover,  Ohio;  Chattanooga, 

Tenn.;  Lone  Star,  Tex.;  and  ftiirmont,  W.  Va.). 
4730  Crittenden  Dr. ,  Louisville  9,  Ky. 
939  Barnum  Ave.,  Bridgeport  2,  Conn. 
1615  Merchants  Bank  Bldg.,  Indianapolis  4,  Ind.  (Florence 

and  Itobile,  Ala.;  Indianapolis,  Ind.;  St.  Louis  Park, 

Minn. ;  Lima,  Ohio;  Ironton,  Utah;  Norfolk,  Va. ;  and 

Seattle,  Wash.). 
27th  Ave.  and  Lake  St.,  Melrose  Park,  111. 
555  S.  Flower  St. ,  Los  Angeles  17  (Watson) ,  Calif. 
8480  Beverly  Blvd.,  Los  Angeles  48,  Calif. 
120  S.  LaSalle  St.,  Chicago  3  (Ringwood),  111. 
5935  Milford  Ave.,  Detroit,  Mich. 
4001  Goodwin  Ave. ,  Los  Angeles  39,  Calif. 
403  W.  Main  St.,  Amsterdam,  N.  Y. 
324  E.  147th  St.,  Harvey,  111. 
Box  446,  Nitro,  W.  Va. 
222  W.  Washington  Sq. ,  Philadelphia  5,  Pa.  (Bristol  and 

Philadelphia,  Pa.;  Knoxville,  Tenn.;  and  Deer  Park,  Tex.). 
Box  246,  Roosevelt,  Puerto  Rico. 
Carlton  Ave.,  Carlton  Hill,  N.  J. 
225  Broadway,  New  York  (Hicksville) ,  N.  Y. 
500  5th  Ave.,  New  York  36,  N.  Y.  (Joliet,  111.;  Baltimore, 

Md.;  and  Erie,  Pa.) . 
60  Grove  St.,  Salem,  Mass. 
500  Gilbert  St. ,  Charles  City,  Iowa. 
Rothschild,  Wis. 

61-63  Van  Dam  St.,  New  York  13,  N.  Y.  (Fair  Lawn,  N.  J.). 
Congress  and  10th  Ave.,  Schenectady  1  (Rotterdam  Jot.),  N.Y. 
9425  Grinnell  Ave.,  Detroit  13,  Mich. 
60  Orange  St.,  Bloomfield  (Union),  N.  J. 
16-26  Cooper  Sq. ,  New  York  3,  N.  Y. 
Collins  and  Westmoreland  Sts.,  Philadelphia  34,  Pa. 
2346  Sedgley  Ave.,  Philadelphia  32,  Pa. 
230  Washington  St.,  Mt.  Vernon,  N.  Y. 
P.  0.  Box  5110,  Chicago  80  (Skokie),  111. 
644  Monsanto  Ave.,  Springfield  1,  Mass. 
P.  0.  Box  630,  Norwich  (Oneonta),  N.  Y. 

50  W.  50th  St.,  New  York  20,  N.  Y.  (Martinez,  Los  Angeles, 
and  Pittsburg,  Calif.;  and  Deer  Park,  Tex.). 

50  W.  50th  St.,  New  York  20,  N.  Y.  (Martinez  and  Wilmngton, 
Calif;  Roxana,  111.;  Norco,  La.;  Deer  Park,  Tex.;  and 
Anacortes,  Wash.). 

2803  Highland  Ave.,  Cincinnati  12,  Ohio. 

101  Prospect  Ave.,  N.  W. ,  Cleveland  1,  Ohio  (Chicago,  111.; 
Detroit,  Mich. ;  Dayton  and  Cleveland,  Ohio;  and  Philadel- 
phia and  Pittsburgh,  Pa.). 

Route  46,  Clifton  (Newark),  N.  J. 

P.  0.  Box  925,  Spartanburg,  S.  C. 

2301  N.  Columbia  Blvd. ,  Portland  17,  Oreg. 

600  5th  Ave.,  New  York  20,  N.  Y.  (E.  Chicago,  Ind.;  Sand 
Springs,  Okla. ;  Marcus  Hook,  Pa.;  and  Houston,  Tex.). 

611  W.  129th  St.,  New  York  27,  N.  Y.  (Ridgway,  Pa.). 

P.  0.  Box  8010,  S.  Hills  Branch,  Pittsburgh  16  (Bridgeville) , 
Pa. 


172 


UNITED  STATES  TARIFF  COMMISSION 


TABLE  27. --Syntheti 


chemicals:    directory   of  manufacturers ,     19 56- -Continued 


Name  of  company 


Office  address  ( location  of  plant  given  in 
parentheses  if  not  in  same  city  as  office) 


auith,  Kline  &  French  Laboratories 

Socony-Mobil  Oil  Co.,  Ino 

Sohio  Petroleum  Co 

Soluol  Chemical  Co.,  Inc 

Solvent  Chemical  Co.,  Inc 

Sonneborn,  L. ,  Sons,  Inc 

Sonooo  Products  Co 

Southern  Dyestuff  Corp 

Southern  Resin  Glue  Co 

Southern  Sizing  Co 

Southern  Textile  Chemical  Corp 

Spaulding  Fibre  Co.,  Inc 

Specialty  Resins  Co 

^ecific  Pharmaceuticals,  Inc 

Spencer  Chemical  Co 

Squibb,  E.  R. ,  &  Sons  Div.  of  Olin 
Mathieson  Chemical  Corp. 

Staley,  A.  E. ,  Manufacturing  Co 

Standard  Agricultural  Chemicals,  Inc-- 

Standard  Chemical  Co 

Standard  Chemical  Products,  Ino 

Standard  Chlorine  Chemical  Co.,  Inc 

Standard  Dyestuff  Corp 

Standard  Naphthalene  Products  Co.,  Inc 
Standard  Oil  Co.  of  California 

Standard  Oil  Co.  of  Indiana 

Standard- Toch- Chemicals,  Inc 

Standard  Ultramarine  &  Color  Co 

Stange,  Wm.  J.,  Co 

Stansbury  Chemical  Co.,  Inc 

Stauffer  Chemical  Co 

Stein,  Hall  &  Co.,  Inc 

Stepan  Chemical  Co 

Sterling  Drug,  Ino,. : 

Hilton-Davis  Chemical  Co.  Div 

National  Brands  Div 

Stresen-Reuter,  Fred'k.  A.,  Ino 

Summit  Chemical  Products  Corp 

Sumner  Chemical  Co. ,  Div.  of  Miles 

Laboratories,  Inc. 
Sun  Chemical  Corp.: 

Pigment  Div 

Wanrick  Chemical  Co.    Div-- -- 

Sun  Oil  Co 

Suntide  Refining  Co 

Swift  &  Co 

Synco  Resins,  Inc 

Synthetic  Chemicals,  Inc 

Synthetic  Plastics  Co 

Synthetic  Products  Co- 

^nvar  Corp 

Tar  Distilling  Co.,  Ino 

Taylor  Fibre  Co 

Tennessee  Copper  Co.,  Div.  Tennessee 

Corp. 
Tennessee  Eastman  Co. ,  Div.  of  Eastman 

Kodak  Co. 
Tennessee  Products  &  Chemical  Corp 

Tex  Chemical  Co 

Texas  Co 

Texas  Eastman  Co.,  Div.  of  Eastman 
Kodak  Co. 

Texas-U.  S.  Chemical  Co 

Thiokol  Chemical  Corp 

Thomasset  Colors,  Inc 

Ihompson  Chemicals  Corp 

Thompson-Hayward  Chemical  Co 

Toms  River-Cincinnati  Chemical  Corp — 

Trask,  Arthur  C,  Co 

Treplow  Products,  Ino 

Triangle  Chemical  Co 

Trojem  Powder  Co 

Trubek  Laboratories 

UBS  Chemical  Corp 


1530  Spring  Garden  St.,  Philadelphia  1,  Pa. 

150  E.  A2d  St.,  New  York  17,  N.  Y.  (Paulsboro,  N.  J.,  and 

Beaumont,  Tex.). 
1453  Guildhall  Bldg.,  Cleveland  15  (Lima),  Ohio. 
Green  Hill  and  Market  Sts.,  Natick,  R.  I. 

341  Commercial  St. ,  Maiden  48,  Mass. 

300  4th  Ave.,  New  York  10,  N.  Y.  (Petrolia,  Pa.). 

Hartsville,  S.  C. 

P.  0.  Box  10098,  Charlotte  1  (Sodyeoo),  N.  C. 

Box  352,  Fayetteville  (Vander),  N.  C. 

601  S.  E.  Main  St. ,  East  Point,  Ga. 

1407  Broadway,  New  York  18,  N.  Y.  (Clearwater,  S.  C). 

310  Wheeler  St.,  Tonawanda,  N.  Y. 

2801  lynwood  Rd.  ,  lynwood,  Calif. 

331  4th  Ave.,  New  York  10,  N.  Y.  (Bayonne,  N.  J.). 

610  Dwight  Bldg.,  Kansas  City  5,  Jfc.  (Calumet  City,  111.; 

Pittsburg,  Kans.;  and  Orange,  Tex.). 
See   Olin  Mathieson  Chemical  Corp. 

2200  E.  Eldorado  St. ,  Deoatur,  111. 

1301  Jefferson  St.,  Hoboken,  N.  J. 

3583  Aramingo  Ave. ,  Philadelphia  34,  Pa. 

1301  Jefferson  St.,  Hoboken,  N.  J. 

115  Jacobus  Ave.,  S.  Kearny,  N.  J. 

5th  St.  &  5th  Ave.,  Paterson  4,  N.  J. 

115  Jacobus  Ave.,  S.  Kearny,  N.  J. 

225  Bush  St.,  San  Francisco  20  (Bakersfield,  El  Segundo,  and 

Richmond),  Calif. 
910  S.  Michigan  Ave.,  Chicago  80,  111.  (Wood  River,  111.; 

Whiting,  Ind.;  and  Sugar  Creek,  Mo.). 
2600  Richmond  Ter. ,  Staten  Island  3,  N.  Y. 
5th  Ave.  and  24th  St.,  Huntington  18,  W.  Va. 

342  N.  Western  Ave. ,  Chicago  12,  111. 
1929  Aurora  Ave.,  Seattle  9,  Wash. 

380  Madison  Ave.,  New  York  17,  N.  Y.  (LaMoyne,  Ala.;  Louis- 
ville, Ky.;  Henderson,  Nev.;  Brooklyn,  Chauncey,  and  Niagara 
Falls,  N.  Y. ;  Perry,  Ohio;  Chester  and  Monongahela,  Pa. ; 
Lowland,  Tenn. ;  and  Bentonville  and  Roanoke,  Va. ) . 

285  Madison  Ave.,  New  York  17,  N.  Y.  (Charlotte,  N.  C). 

20  N.  Wacker  Dr.,  Chicago  6,  111. 

2235  Langdon  Farm  Rd. ,  Cincinnati  13,  Ohio. 

1450  Broadway,  New  York  18,  N.  Y.  (Trenton,  N.  J.). 

325  W.  Main  St.,  Bensenville,  111. 

11  William  St.,  Belleville  9,  N.  J. 

215  N.  Centennial  St. ,  Zeeland,  Mich. 


309  Sussex  St.,  Harrison,  N.  J. 
10-10  44th  Ave.,  Long  Island  City,  N, 

R.  I.,  and  Rock  Hill,  S.  C). 
1608  Walnut  St.,  Philadelphia  3  (Marcus  Hook),  Pa. 
P.  0.  Box  658,  Corpus  Christi,  Tex. 
4115  Packers  Ave.,  Chicago  9,  111. 
Henry  St. ,  Bethel,  Conn. 
335  McLean  Blvd.,  Paterson  4,  N.  J. 
88  St.  Francis  St.,  Newark  5,  N.  J. 
1636  Wayside  Rd.,  Cleveland  12,  Ohio. 
726  King  St.,  Wilmington  99,  Del. 
500  5th  Ave.,  New  York  36,  N.  Y.  (Cleveland,  Ohio) 
Norristown,  Pa. 
61  Broadway,  New  York  6,  N.  Y.  (Copperhill,  Tenn.) 


Wood  River  Junction, 


Nashville  3  (Chattanooga), 


See   Eastman  Kodak  Co. 

First  American  National  Bank  Bldg. 

Tenn. 
20  Wagaraw  Rd.,  Fair  Lawn,  N.  J. 
P.  0.  Box  2332,  Houston  1,  Tex. 
See   Eastman  Kodak  Co. 


P.  0.  Box  1597,  Port  Neches,  Tex. 

780  N.  Clinton  Ave. ,  Trenton  7,  N.  J. 

120  Lister  Ave.,  Newark  5,  N.  J. 

3028  Locust  St.,  St.  Louis  3,  Mo. 

2915  Southwest  Blvd. ,  Kansas  City  8,  Mo. 

P.  0.  Box  20,  Evanston  Sta. ,  Cincinnati  7,  Ohio.  (Toms  River, 

N.  J.;  and  Norwood  and  St.  Bernard,  Ohio). 
4103  S.  LaSalle  St.,  Chicago  9,  111. 
59  Camden  St.,  Paterson,  N.  J. 
206  Lower  Elm  St. ,  Macon,  Ga. 
17  N.  7th  St.,  Allentown  (Seiple),  Pa. 
Box  F,  E.  Rutherford,  N.  J. 
491  Main  St.,  Cambridge  42,  Mass. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


173 


TABLE  27. — Synthetic 


ils:  Directory  of  manufactu 


1956- -Continued 


Name  of  conjiaiiy 


Office  address  (location  of  plant  given  in 
parentheees  if  not  in-  same  city  as  office) 


Uhlich,  Paul,  &Co.,  Inc • 

Ultra  Chemical  Works,  Inc 

Union  Carbide  &  Carbon  Corp.: 

Bakelite  Co 

Carbide  &  Carbon  Chemicals  Co 

Silicones  Div 

Union  Oil  Co.  of  California 

United  Piece  Dye  Works 

United  Rubber  &   Chemical  Co 

United  States  Borax  &  Chemical  Corp-' 
U.  S.  Industrial  Chemicals  Co. ,  Div. 

of  National  Distillers  Products 

Corp. 

U.  S.  Oil  Co- 

United  States  Pipe  &  Foundry  Co 

U.  S.  Plastics  Products  Corp 

United  States  Procaine  Co. ,  Inc 

U.  S.  Rubber  Co. ,  Naugatuck  Chemical 

Div. 

Universal  Detergents,  Inc 

Universal  Western  Chemical  Corp 

Upjohn  Co 

van  Ameringen-Haebler,  Inc 

Vanderbilt  Chemical  Corp 

Van  Dyk  &  Co.,  Inc- 

Varcum  Chemical  Corp 

Velsicol  Chemical  Corp 

Verley  Chemical  Co.,  Inc 

Verona  Chemical  Co 

Victor  Chemical  Works 

Vineland  Chemical  Co 

Virginia-Carolina  Chemical  Corp 

Vitamins,  Inc 

Vita-Var  Corp 

Wallace  &  Tiernan,  Inc 

Harchem  Div 

Lucidol  Div 

Wamer-Jenklnson  Manufacturing  Co 

Warren  Petroleum  Corp 

Washburn,  T.  F. ,  Co 

Washington  Natural  Gas  Co 

Watertown  Manufacturing  Co 

Werner  Drug  &  Chemical  Co 

Western  Dry  Color  Co 

Westinghouse  Electric  Corp 

Westville  Laboratories 

Wetherill,  George  D. ,  Varnish  Co 

Wheeler,  RejTiolds  &  Stauffer 

White  &  Bagley  Co 

llhite   &  Hodges,  Inc 

Whittemore-Wright  Co.,  Inc 

Wica  Co.,  Inc 

Wilmot  4  Cassidy,  Inc 

Wilson  Laboratories  Div.  of  Wilson  & 
Co.,  Inc. 

Wilson  Organic  Chemicals,  Inc 

Winthrop  Laboratories 

Witco  Chemical  Co 

Witte,  John  H. ,  &  Sons 

Wolf,  Jacques,  &  Co 

Wyandotte  Chemicals  Corp 

Wyeth  Laboratories,  Inc 

Young  Aniline  Works,  Inc 

Zinsser  &   Co.,  Inc.,  subsidiary  of 
Harshaw  Chemical  Co. 


90  West  St. 
2  Wood  St., 


,  New  York  6  (Brooklyn),  N.  Y. 
Paterson  A,    N.  J. 


30  E.  '42d  St.,  New  York  17,  N.  Y.  (Ottawa,  111.;  Wyandotte, 
Mich.;  Bound  Brook,  N.  J.;  and  Marietta,  Ohio). 

30  E.  .;2d  St.,  New  York  17,  N.  Y.  (Torrance,  Calif.;  Whiting, 
Ind.;  Niagara  Falls,  N.  Y.;  Fort  Lavaca  and  Texas  City, 
Tex.;  and  Charleston  and  S.  Charleston,  W.  Va.). 

30  E.  42d  St.,  New  York  17,  N.  Y.  (Tonawanda,  N.  Y. ,  and 
Sistersville,  W.  Va.). 

617  W.  7th  St.,  Los  Angeles  17,  CaUf.  (Bakersfield,  Bodeo, 
Santa  Maria,  and  Wilmington,  Calif.;  Cut  Bank,  Mont.;  and 
EdmonSs,  Wash.) . 

Nicholson  St.,  Lodi,  N.  J. 

P.  0.  Box  149,  Baytown,  Tex. 

630  Shattc  PI.,  Los  Angeles  5  (Boron),  Calif. 

99  Park  Ave.,  New  York  16,  N.  Y.  (New  Orleans,  La.). 


Box  1345,  Providence  (Phillipsdale),  R.  I. 

P.  0.  Box  2651,  Birmingham,  Ala. 

Lake  &  Whitman  Aves.,  Metuchen,  N.  J. 

2911  Atlantic  Ave.,  Brooklyn  7  (College  Point),  N.  Y. 

1230  Ave.  of  the  Americas,  New  York  20,  N.  Y.  (Naugatuck, 
Conn. ) . 

1825  E.  Spring  St. ,  Long  Beach  6,  Calif. 

12800  Imperial  Hwy.,  Norwalk,  Calif. 

301  Henrietta  St. ,  Kalamazoo  99,  Mich. 

521  W.  57th  St.,  New  York  19,  N.  Y.  (Elizabeth  and  Union 
Beach,  N.  J.). 

230  Park  Ave.,  New  York  17,  N.  Y.  (Bethel,  Conn.). 

11  William  St.,  Belleville  9,  N.  J. 

P.  0.  Box  476,  Niagara  Falls,  N.  Y. 

330  E.  Grand  Ave.,  Chicago  11,  111.  (Marshall,  111.,  and 
Memphis,  -Tenn.). 

200  Pulaski  St.,  Newark  5,  N.  J. 

26  Verona  Ave.,  Newark  A,  N.  J. 

155  N.  Wacker  Dr.,  Chicago  6,  111. 

West  Wheat  Rd.,  Vineland,  N.  J. 

401  E.  Main  St.,  Richmond  5,  Va.  (Charleston,  S.  C). 

809  W.  58th  St.,  Chicago  21,  111. 

10  Commerce  Ct.,  Newark  2,  N.  J. 

25  Main  St.,  Belleville  9,  N.  J. 

Box  178,  Newark,  N.  J.  (Dover,  Ohio). 

1740  Military  Rd.,  B'jffalo  5,  N.  Y. 

2526  Baldwin  St. ,  St.  Louis  6,  Mo. 

P.  0.  Box  1589,  Tulsa,  Okla.  (Crossville  and  Salem,  111.; 
and  Breckenridge,  Conroe,  Galena  Park,  Gladewater,  Holli- 
day,  and  Longview,  Tex.). 

2244  Elston  Ave. ,  Chicago  14,  111. 

1507  4th  Ave. ,  Seattle  11,  Wash. 

127  Echo  Lake  Rd. ,  Watertown,  Conn. 

759  Beechwood  Ave.,  Cincinnati  32,  Ohio. 

600  W.  52d  St.,  Chicago  9,  111. 

401  Liberty  Ave.,  P.  0.  Box  2278,  Pittsburgh  30  (East  Pitts- 
burgh), Pa. 

Monroe,  Conn. 

Haddon  Ave.  &  White  Horse  Pike,  Camden  3,  N.  J. 

1430  S.  47th  St.,  Richmond,  Calif. 

100  Foster  St.,  Worcester  8,  Mass. 

2  Wellington  Ave.,  Everett  49,  Mass. 

62  Alford  St.,  Boston  29,  Mass. 

P.  0.  Box  506,  Charlotte  1,  N.  C. 

108-112  Provost  St.,  Brooklyn  22,  N.  Y. 

4221  S.  V/estern  Ave. ,  Chicago  9,  111. 

P.  0.  Box  452,  Sayreville,  N.  J. 

1450  Broadway,  New  York  18  (Rensselaer),  N.  Y. 

122  E.  42d  St.,  New  York  17,  N.  Y.  (I^rnwood,  Calif.;  Chicago, 

111.;  and  Brooklyn,  N.  Y. ) . 
206  Jefferson  St. ,  Burlington,  Iowa. 
P.  0.  Box  839,  Passaic  (Clifton),  N.  J. 
1609  Biddle  Ave.,  Wyandotte,  Mich. 
P.  0.  Box  8299,  Philadelphia  1,  Pa.  (Chicago,  111.;  and 

Philadelphia  and  West  Chester,  Pa.). 
2731  Boston  St.,  Baltimore  24,  ^H. 
Railroad  Ave.,  Hastings-on-Hudson  6,  N.  Y. 


APPENDIX 

A.  United  States  Imports  of  Coal- Tar  Intermediates 
and  Finished  Coal- Tar  Products 

Table  28  summarizes,    for  the  period  1954-56,    United  States  im- 
ports of  coal-tar  products  dutiable  under  paragraphs   27  and  28  of 
the  Tariff  Act  of  1930.    The  data,    which  were  obtained  by  analyzing 
invoices  covering  imports  through  all  United  States  customs 
districts,    are  given  in  detail  in  a  separate  report  of  the  Tariff  Com- 
mission. 1 

In  1956  general  imports  of  coal-tar  chemicals  entered  under 
paragraph  27,    virtually  all  of  which  are  intermediates,    totaled  6.  7 
million  pounds,    with  a  foreign  invoice  value  of  4.8  million  dollars, 
compared  with  imports  in  1955  of  6.4  million  pounds,    valued  at 
4.5  million  dollars,    and  imports  in  1954  of  8.6  million  pounds,    also 
valued  at  4.  6  million  dollars.    More  than  two-thirds  of  all  imports 
of  intermediates  in  1956  came  from  West  Germany  and  the  United 
Kingdom;  imports  from  West  Germany  totaled  3.  2  million  pounds 
in  1956,    compared  with  3  million  pounds  in  1955.    Imports  from 
the  United  Kingdom  were  1.  3  million  pounds  in  1956,    compared 
with  822,  000  pounds  in  1955.    In  1956  sizable  quantities  of  inter- 
mediates also  were  imported  from  Switzerland  (406,  000  pounds), 
France  (382,000  pounds),    Italy  (360,000  pounds),    the  Netherlands 
(337,  000  pounds),    and  Denmark  (331,  000  pounds);  lesser  quantities 
came  from  Canada,    Belgium,    and  Sweden. 

In  terms  of  quantity,    the  most  important  individual  intermediates 
imported  in  1956  were  m,  p-cresol,    refined  naphthalene,    anthra- 
quinone,    2-naphthol,    and  acetoacetanilide.    Imports  of  m,  p-cresol 
in  1956,    which  came  principally  from  the  United  Kingdom,    totaled 
700,000  pounds,    compared  with  273,000  pounds  in  1955.    Imports 
of  refined  naphthalene  in  1956,    which  came  principally  from  the 
Netherlands  and  West  Germany,    totaled  444,000  pounds,    connpared 
with  854,000  pounds  in  1955.    In  1956  imports  of  anthraquinone, 
which  came  from  France,    the  United  Kingdom,    and  Switzerland, 
totaled  377,  000  pounds;  imports  of  2-naphthol  (350,  000  pounds) 
came  principally  from  West  Germany;  and  imports  of  aceto- 
acetanilide (343,  000  pounds)  came  principally  from  the  United 
Kingdom.    West  Germany  was  the  source  of  all  imports  of  the 
Desmodurs,    N-phenyl-2-naphthylamine,    and  quinoline,    and  Italy 
was  the  most  important  source  of  R  salt  and  H  acid. 

Imports  in  1956  of  all  finished  coal-tar  products  that  are  dutiable 
under  paragraph  28  totaled  5.  1  million  pounds,    with  a  foreign  in- 
voice value  of  10.4  million  dollars,    compared  with  5.4  million 
pounds,    valued  at  11.1  million  dollars,    in  1955.    In  1956,    as  in 
previous  years,    dyes  were  the  most  important  group  of  finished 
coal-tar  products  imported,    accounting  for  4.8  million  dollars,    or 
46  percent  of  the  total  value  of  all  imports  under  paragraph  28.    Im- 
ports of  dyes  in  1955  amounted  to  6.  2  million  dollars,    or  56  percent 
of  the  total  value  of  all  imports  under  paragraph  28.    West  Germany 
and  Switzerland  were  the  principal  suppliers  of  dyes  to  the  United 


lU.  S.  Tariff  Commission,  Imports  of  Coal-Tar  Products,   1956,  1957  [processed]. 

175 


176 


UNITED  STATES  TARIFF  COMMISSION 


TAELE  28.  --Coal-tar    intermerliates     and    Finished  coal -tar   products:    United  States  general    imports,    classi  tied 

by  t'se,    1954-56 


Oiantity 


Foreign 
invoice 
value 


Quantity 


Foreign 
invoice 
value 


CJuantity 


Foreign 
invoice 
value 


Intermediates-' 

Finished  coal-tar  products,  total- 
Dyes,  total 

Acid 

Vat 

Direct 

Mordant  and  ohrome 

Color- lake  and  spirit- soluble- 
Basic 

Acetate  rayon 

Azoic ■ 

Sulfur 

All  other 

Medlcinals  and  pharmaceuticals — 

Flavor  and  perfume  materials 

All  other 


1,000 
pound, 
8,579 

4.064 


2  3,005 

409 

1,045 

408 

170 

435 

42 

54 

19 

27 

396 

497 

176 

386 


1,000 
dollars 
4,-510 

8.672 


5,832 

1,094 

1,228 

913 

291 

361 

76 

131 

41 

24 

1,673 

2,150 

326 

364 


6,418 
5.412 


^  3,010 

669 

675 

648 

4^2 

136 

124 

50 

31 

19 

216 

924 

311 

1,167 


1,000 
dollars 
4,474 

11.103 


,000 
oands 
0,659 

5,126 


6,249 

1,809 

1,087 

1,411 

538 

215 

261 

100 

72 

16 

740 

3,300 

51A 

1,040 


^  2,804 
551 
825 
529 
277 
247 
Ul 
28 
28 
11 
167 
818 
310 
1,194 


1,000 
dollars 
4,776 

10,439 


4,837 

1,237 

1,139 

1,111 

359 

332 

307 

55 

A9 

11 

237 

4,258 

500 

844 


Includes  small  quantities  of  organic  pesticides  and  agricultural  chemicals,   rubber-processing  chemicals, 
and  surface-active  agents. 
^  Actual  weight. 

Source:   Compiled  from  the  records  of  the  U.  S.   Bureau  of  Customs. 

States  in   1956;   smaller  quantities  came  also  fronn  the  United  Kingdonn 
and  Italy. 

Medlcinals  and  pharnnaceuticals  were   the  next  nnost  innportant 
group  of  products  imported  under  paragraph  28  in  1956.    Imports  of 
these   products  in  that  year  were  valued  at  4.  3  million  dollars,    or 
41   percent  of  the  total  value  of  all  innports  under  paragraph  28.    Im- 
ports of  medlcinals  and  pharmaceuticals  in  1955  were  valued  at  3.  3 
million  dollars,    or  30  percent  of  the  total  value  of  all  imports  under 
paragraph  28.    The  value  of  imports  of  flavor  and  perfume  materials 
was  slightly  lower  in   1956  ($500,  000)  than  it  was  in   1955  ($514,  000). 
Imports  of  other  coal-tar  products  entered  under  paragraph  28  were 
valued  at  $844,  000  in  1956,    compared  with   1   million  dollars  in  1955. 


B.  Research  Workers  and  Research  E^endltures 
In  the  Sjmthetic  Organic  Chemical  Industry 

Because  of  the  interest  of  the   synthetic  organic  chemical  industry 
in  statistics  on  chemical  research,    the  Tariff  Commission  each 
year  collects  and  publishes   statistics  on  the  number  of  technically 
trained  research  workers  in  the  industry,    their  salaries,    and  the 
cost  of  research  (see  table   29).    This  information  is  not  available 
elsewhere.    As  many  of  the  connpanies  that  produce   synthetic  organic 
chemicals  also  manufacture  other  products,    the  cost  of  research 
applicable  to  synthetic  organic  chemicals  must  be  allocated.    For 
some  companies  this  allocation  is  somewhat  arbitrary,    and  the  costs 
of  research  shown  in  this   report  are,    therefore,    only  approximate. 
Moreover,    not  all  companies  that  conduct  research  report  data  on 
their  research  activities;  hence,    the  data  given  in  table   29  are  only 
about  80  percent  complete.    Notwithstanding  these  limitations,    the 
statistics  do  indicate  general  trends  in  the  amount  of  research  con- 
ducted in  the  field  of  synthetic   organic   chemicals. 

In  1956  a  total  of  409  companies  reported  research  activities  in 
the  field  of  synthetic   organic  chemicals.    The  number  of  technically 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


177 


trained  research  workers  reported  for  1956  was   15,498,    a  substan- 
tially larger  number  than  the   14,  191   reported  for   1955.    This  in- 
crease took  place  despite  the  fact  that,    for  reporting  purposes  in 
1956,    a  technically  trained  research  worker  was  defined  as  one 
earning  not  less  than  $4,  500  a  year,    compared  with  $3,  600  a  year 
in  the  period   1952-55.    The  average  salary  paid  in  1956  was  $7,  561, 
compared  with  $7,  385  in  1955.    Total  salaries  paid  research 
workers  in   1956  announted  to   117  million  dollars,    compared  with 
104  million  dollars  in  1955.    In  1956  the  gross  cost  of  research  was 
313  million  dollars--6l   million  dollars  more  than  that  in  1955.    The 
cost  to  the  industry  in  1956  for  research  conducted  for  it  outside 
the  facilities  of  the  reporting  companies--a  cost  not  included  in  the 
gross  cost  given  above--was   12.  6  million  dollars,    or   1.  0  million 
dollars  more  than  in   1955.    This  figure,    however,    probably  does  not 
represent  all  research  projects  conducted  for  the  reporting  com- 
panies in  universities  and  private  laboratories,    or  all  consulting 
services. 


TABLE  29. -Syntheti 


ndus t r 
and   c 


:,f  research,    1952-56 


salaries  paid  research 


Companies 
reporting 


Technically 
trained 
research 
workers'"' 


Salaries 

paid 
research 
workers 


Total  reported  cost  of  research 


Within  the  plant 


Outside 

the 

plant 


1952- 
1953- 
1954- 
1955- 
1956- 


331 
363 
388 


12,203 
12,208 

14,191 
15,498 


1,000 
dollars 
76,701 
83,694 
94,432 
104,804 
117,186 


1,000 
iollars 
194,993 
210,035 
236,524 
252,530 
313,430 


1,000 
iollars 
186,503 
199,829 
221,842 
239,511 
308,376 


-''  For  the  years  1952-55,  a  technically  trained  research  worker  was  defined  as  a  person  with  technical 
training  engaged  in  research  work  and  earning  not  less  than  $3,600  per  year;  for  1956,  a  research  worker  was 
defined  as  a  person  earning  not  less  than  $4,500  per  year. 

^  The  net-cost  figure  is  obtained  by  deducting  from  gross  cost  the  credits  for  salable  products  obtained 
in  the  course  of  research. 


C.  Glossary  of  Synonymous  Names  of 
Cyclic  Intermediates 

Many  cyclic  intermediates  are  known  in  the  chemical  trade  by  a 
variety  of  names.    Individuals  in  the  trade  frequently  are  not 
acquainted  with  all  the  synonymous  names  for  a  given  product.    To 
bring  together  the   synonymous  names  for  each  product,    the  tables 
on  intermediates  in  this   report  (table  7A  in  part  II,    and  table  7B  in 
part  III)   show  the   standard  name,    in  accordance  with  the  system 
used  by  Chemical  Abstracts;  this  standard  name  is  frequently  fol- 
lowed by  the  most  connmon  synonymous  name  in  parentheses. 

In  this  report,    as  in  previous   reports  in  this  series,    the  Tariff 
Commission  has  included  a  glossary  of  synonymous  names  of  cyclic 
intermediates.    This  glossary,    which  was  originally  compiled  at  the 
suggestion  of  the  Industry  Advisory  Committee  on  Government  Re- 
ports,   is  intended  to  serve  principally  as  an  index  to  the   standard 
names  used  in  the  statistical  tables  on  intermediates.    The  first 
column  of  the  glossary  lists  alphabetically  the  common,    or  trivial, 
names  usually  encountered  in  the  trade.    The   second  column  gives 
the  corresponding   standard  (Chemical  Abstracts)  names,    under 
which  the  data  are  presented  in  tables  7A  and  7B. 


178 


UNITED  STATES  TARIFF  COMMISSION 


Cyclic    intermediates:    Glossary  of  synonymous 


Cominon  name 


Standard  (Chemical  Abstracts) 


Acedlanthrone 

1,2-Acenaphthenedione 

<i-Aoetainido-2-amlnophenol  hydrochloride 

p-Acetamidobenzenesulfonyl  chloride 

5-Acetamido-2-hydroxybenzolo  acid 

l-Acetainido-2-methoxynaphthalene-- 

l-Aoetamldo-2-naphthol 

l-Acetamido-7-naphthol 

2-Acetamido-'i-nitrophenol 

5-Acetainido-orthanilic  acid 

Acetanilide-p-sulfonic  acid 

Acetanilid  sulfon  chloride 

Acetate  leuoo  violet 

p-Acetoacetchloranilide 

Acetoacet-o-chloroanilide 

o-Acetoaoetochloroanilide 

Acetoaceto- 1-naphthy lamide 

N-Aoetoaceto-1-naphthylamlne 

m-Acetoacetoxylidide 

Acetoaoet-o-toluidide 

Acetoaoet-o-toluidine 

Aoetoacetyl-o-anisidine 

Acetoacetyl  benzidine 

Aoetyl-p-ainlno-o-aminophenol  hydrochloride 

l-Acetyl-3-C4-amlno-m-anisyl)urea 

Acetylamino  Cleve's  acid 

N-Acetyl-l-amino-8-naphthol-3,6-disulfonic  acid — 

Acetyl-o-anisidine 

Acetyl-p-anisidine 

Acetyldiaminoanthraquinone 

Acetyl-2,'i-diaminophenol  hydrochloride 

Acetyl  H  acid 

Acetyl-l,A-naphthalenediamine-6(and  7)-sulfonic  acids 

Acetyl-p-nitro-o-aminophenol 

Acetyl-m-phenylenediamine 

Ace tyl-p-phenylenedi amine 

Acetyl-p-phenylenedi  amine  sulfate 

N*-Acetyl-N^-2-pyrimidinylsulfanilamide 

Acetylsulfadiazine 

Aoetylsulfamerazine 

Acetylsulfamethazine 

N^ -Acetylsulf anilamide 

N*-Acetylsulfanilamide 

2-(N*-Acetylsulfanilamido)thiazole 

Acetylsulfathiazole 

N*-Acetyl-2-sulfo-p-phenylenediamine 

N-Acetyl-o-toluidine 

1,2,'i-Acid 

Ami chin 

m-Aminoacetanilide 

p-Aminoacetanilide 

p-Aminoacetanilide  sulfate 

m-Aminoacetophenone 

6-(p-AminoaniIino)metanllic  acid 

p-Aminoazobenzene-- 

Aminoazobenzene  disulfo  acid 

Aminoazobenzene-3  j't-disulfonic  acid 

p- Aminoazobenzene  hydrochloride 

Aminoazobenzene-m- sulfonic  acid 

Aminoazobenzene-p-sulfonio  acid 

o-Aminoazotoluene 

o-Aminoazotoluene  sulfate 

"4-Aminoazotoluene-'i-sulfonic   acid  and  salt 

o-Aminoazotoluenesulfonic  acid  and  salt 

Amlnoazoxylenetoluidine 

p-Aminobenzenearsonic  acid 

3-Aminobenzenesulfonanilide 

4-Aminobenzenesulfonanilide 

m-Aminobenzenesulfonic  acid 

p-Arainobenzenesulfonic  acid 

o-Aminobenzoic  acid 

m-Aminobenzoyl   I(or  J)   acid 

p-Aminobenzoyl  I(or  J)   acid 

p-Aminobenzoyl-m-phenylenediamine 

o-Aminobiphenyl 

2-Aminobiphenyl 

"i-Aminobiphenyl 

l-Amino-'i-bromoanthraquinone-2,5-disulfonic   acid- 

l-Amino-2-bromo-'i-(p-toluidine)aiithraquinone 

3-Amino-N-butyl-p-anisolesulf onamide 

p-Amino-N-(n-butyl) phenol 

2-Amino-'4' -chloroacetanilide 


Aceanthra[  2,1-a]  aceanthrylene-5,13-dione. 
Aoenaphthenequlnone . 

3'-Amino-4'-hydroxyacetanilide  hydrochloride. 
N-Acetylsulf anilyl  chloride. 
5-Acetamidosalicylic  acid. 
N-(2-Methoxy-l-naphthyl)acetamide. 
N- ( 2-Hydroxy- 1-naphthyl ) acetamide . 
N- ( 7-Hydroxy- 1-naphthyl ) acetamide . 
2'-Hydroxy-5'-nitroacetanilide. 
5-Acetamido-2-aminobenzenesulfonlc  acid. 
N-Aoetylsulfanilic  acid. 
N-Acetylsulfanilyl  chloride. 
l,4-Diamino-2,3-dihydroanthraquinone. 
A ' -Chloroacetoacetanilide . 
2 ' -Chloroaoetoacet ani lide . 
2 '-Chloroacetoacetanilide. 
N-1-Naphthylacetoacetamide. 
N-1-Naphthylacetoacetamide . 

2  ,<i'-Acetoacetoxylidide. 
o-Acetoacetotoluidide . 
o-Acetoacetotoluidide, 
o-Acetoaoetanisidide. 

4',^   -Biacetoacetanilide. 

3 ' -Amino-A' -hydroxyacetani lide  hydrochloride . 

l-Acetyl-3-(<l-amino-3-methoxyphenyl)urea. 

8-Acetamido-5-amino-2(and  3)-naphthalenesulfonic  acid. 

8-Acetamido-l-naphthol-3,6-disulfonic  acid. 

o-Acetanisidide. 

p-Acetanisidide. 

1 , 5(  or  1,8)^  -Diacet  amidoanthraquinone . 

3  -Amino-4'-hydroxyacetanilide  hydrochloride. 
8-Acetamido-l-naphthol-3,6-disulfonie   acid. 
8-Acetamido-5-amino-2(and  3)-naphthalenesulfonio  acid. 
2' -Hydroxy-5' -nitroacetanilide . 

3 '-Aminoaoetanilide . 

4' -Aminoacetanilide . 

p-Aminoacetanilide  sulfate. 

<V'-(2-Pyrimidinylsulfamoyl)aoetanilide. 

"4 ' -( 2-Pyrimidinylsulf amoyl)   acetanilide . 

4'-(4-Methyl-2-pyrimidinylsulfamoyl)acetanilide. 

4 '-( 'i,6-Dijnethyl-2-pyrimidinylsu  If  amoyl )  acetanilide . 

N-Sulf  anlTylacetamide . 

A'-Sulfamoylacetanilide. 

4' -( 2-Thiazolylsulf amoyl ) acetanilide . 

4 '-(2-Thiazolylsulfamoyl) acetanilide. 

5-Acetamido-2-airiinobenzenesulfonic  acid. 

o-Acetotoluidide, 

l-Amino-2-naphthol-4-sulfonio  acid. 

8-Amtno-6-methoxyquinoline . 

3'-Aminoacetanilide. 

4 ' -Aminoacetanilide . 

<4'-Aminoacetanilide  sulfate. 

3 ' -Aminoacetophenone . 

5-Amino-2-(p-aminoanilino)benzenesulfonic  acid. 

p-Phenylazoaniline . 

6-Amino-3,4'-azodi[benzenesulfonic  acid] . 

6-Amino-3,4'-azodi[benzenesulfonic  acid). 

p-Phenylazoaniline  hydrochloride. 

m-(p-Aminophenylazo)benzenesulfonic   acid. 

p-(p-Aminophenylazo)benzenesulfonic  acid. 

<i-(o-Tolylazo)-o-toluidine     [NH2=1]  • 

4-(o-Tolylazo)-o-toluidine  sulfate. 

4-(4-Amino-m-tolylazo)-m-toluenesulfonic  acid  and 

salt. 
^-(^-Amino-m-tolylazoj-m-toluenesulfonic  acid  and 

salt. 
4- ( 2, 4-Xylylazo ) -o-toluidine  [  NH; =1 ] . 
Arsanilic   acid  [As03H2=l]. 
Metanilanilide . 
Sulfanilanilide. 
Metanilic  acid  [  SO3H  =1] . 
Sulfanilic   acid  [SOsH^lJ. 
Anthranilic  acid  [COOH=l]. 

6-(m-Aminobenzamido)-l-naphthol-3-sulfonic  acid. 
6-(p-Aminobenzamido)-l-naphthol-3-sulfonio  acid. 
2 , 4 , 4 ' -Tri aminobenzophenone . 
2-Biphenylaffline . 
2-Biphenylaiiilne . 
4-Biphenylamine . 

5-Amino-8-bromo-l,6-anthraquinonedisulfonlc  acid. 
l-Amino-2-bromo-4-(p-toluidino)anthraquinone. 
N''--Butyl-4-methoxymetanilamide  [S02NH2=l]. 
p-Butylaminophenol . 
4' -Chloroglycinanilide. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


179 


Cyclic    intermeiiiates:    Gtosfjary  nf  synonymnus   names- -Continued 


Common  name 


Standard  (Chemical  Abstracts)  name 


5-Araino-2-ohlorobenzenesulfonic  acid 

5-Amino-3-ohlorobenzenesulfonic  acid 

5-Aniino-4-chlorobenzenesulf onic  acid 

2-Amino-4-chloroben2oic  acid 

3-Amino-6-chlorobenzoio  acid 

Aminochlorodiphenyl 

Aminochlorodiphenyl  ether 

Aminochlorodiphenyl  ether 

2-Amino-3-ohlorotoluene  [  CH3=l) 

2-Amino-4-ohlorotoluene  [  CH3=lj 

2-Amino-5-chlorotoluene  [  CH3=l] 

2-Amino-6-chlorotoluene  [  CH3=l] 

2-Amino-5-ohlorotoluene  hydrochloride 

m-Amino-p-cresol  [CHjil] 

3-Amino-p-cresol  methyl  ether  [CH3=l] 

3-Amino-p-oresyl  methyl  ether 

omega- Amino-psi-cumene 

(i)-Amino-+-cumene 

Aminodichlorobenzenesulfonic  acid 

2-Amino-l,'i-diethoxybenzene 

2-Amino-5-diethylaminotoluene  hydrochloride 

p-Arainoethylaniline 

A -Amino- 1 , 3-dihydroxyanthraquinone 

2-Amino-l,A-diinethoxybenzene 

p-Aminodimethylaniline 

p-Aminodimethylaniline  sulfate 

2-Amino-4,6-dinitrophenol  and  salt 

o-Amlnodiphenyl 

p-Arainodiphenyl 

p-Aminodiphenylamlne 

'i-Aminodiphenylamlne-2-sulfonic   acid 

Aminodiphenyl  ether 

4-Aminoethoxyethylanillne 

Amino  G  acid 

2-Amino-'i-hydroxybenzenearsonio  acid 

Amino  I(or  J)  acid 

p-Amino-N-isobutylphenol 

'i-Amino-2-methylanisole  [CHsO^l] 

•4  -Amino-'i'  -  (3-methy  1-5-pyrazolone )  -2 , 2'  -stllbenedi  - 
sulfonic  acid. 

4-Amino-l-naphthalenesulfonic  acid 

2-Aminonaphthalene-3,6,8-trisulfonic  acid 

8-Amijio-l-naphthoic  lactam 

l-Amino-7-naphthol 

l-Amino-8-naphthol-2,4-disulfonic  acid 

l-Ainino-8-naphthol-3,6-disalfonic  acid 

l-Amino-8-naphthol-4,6-disulfonlc   acid 

2-Amino-8-naphthol-3,6-disulfonic   acid 

<i-Amino-5-naphthol-l,3-disulf onic   acid 

<i-Amino-5-naphthol-l,7-disulfonic   acid 

5-Amino-4-naphthol-2,7-dlsulfonic   acid 

6-Amino-<i"naphthol-2,7-di3ulfonic  acid 

l-Amino-8-naphthol-4-sulfonic   acid 

2-Amino-5-naphthol-7-sulfonic  acid 

2-Amino-6-naphthol-8-sulfonic  acid 

2-Amino-8-naphthol-6-sulfonlc  acid 

A-Amino-3-naphthol-l -sulfonic   acid 

"i-Amino-5-naphthol-l-sulfonlc  acid 

6-Amino-A-naphthol-2-sulfonic   acid 

7-Amino-3-naphthol-l-sulfonic   acid 

7-Amino-<i-naphthol-2-sulfonic  acid 

2-Amino-^-nitroanisole  [CH3O  =  l] 

2-Amino-5-nitroanisole 

2-Amlno-6-7iitroanisole 

/^ -Amino -3 -nitroani  sole 

^-Amino-4-nitrodiphenylamine-2-sulfonic  acid 

2-Amino-'i-nitro-l_-phenol-6-sulfonic  acid 

2-Am±nophenetole  lC2H50=ll 

Aminophenol  sulf amide 

o-Aminophenol-p-sulfonamide 

o-Amlnophenol-p-sulfonic  acid 

m-Aminophenylcarboxypyrazolone 

l-(m-Aminophenyl)-3-methyl-5-pyrazolone 

Aminophenylphenyl  ether 

m-Aminophenylpyrazolonecarboxylic  acid 

l-(m-Aminophenyl)-5-pyrazolone-3-carboxylic  acid — 

p-Arainophenyl-p-tolylaminesulfonie  acid 

2-Amino-A(3H)-pyTimidone 

Amino  R  acid 

5-Aminosaligenin-2-methyl  ether 

6-Amino-3- (p-toluenesulf one ) amino-A-methoxytoluene- 


6-Chlorometanilic  acid  [SOjHill.' 

5-Chlorometanilic  acid  [S03H=l]. 

"i-Chlorometanilio  acid  [S03H=1]. 

A-Chloroanthranilic   acid   [C00H=1  ). 

5-Amino-2-ohlorobenzoic  acid. 

Chloro-2-(or  3,   or  4.)-biphenylamlne. 

5-Chloro-2-phenoxyaniline. 

p-(p-Chlorophenoxy) aniline 

6-ChlQro-o-toluidine  f  NH2=1  !• 

5-Chloro-o-toluidine  [NH2=l]. 

^-Chloro-o-toluidine  [NHj^l]. 

3-Chloro-o-toluidine  [NHj^l]. 

A-Chloro-o-toluidine  hydrochloride . 

2-Amino-p-cresol  [OH=l]. 

5-Methyl-o-anisidine  [NHs^l]. 

5-Methyl-o-anisidine  [NH2=1] • 

2,4-Dimethylbenzylamine . 

2,'i-Dimethylbenzylamine. 

2,5-Dichlorosulf anilic  acid. 

2,5 -Diethoxyani line . 

N' ,N^-Diethyltoluene-2,5-diamine  hydrochloride. 

N,N-Diethyl-p-phenylenediamine. 

4-Aminoxanthopurpurin . 

2, 5-Dimethoxy aniline. 

NjN-Dimethyl-p-phenylenediamine. 

N,N-Dijiiethyl-p-phenylenediamine  sulfate. 

Picramic  acid  and  salt. 

2-Biphenylamine . 

•i-Biphenylamine . 

N-Phenyl-p-phenylenediamine . 

5-Amino-2-anilinobenzenesulfonic  acid. 

p -Phenoxy ani line . 

2- (p-Amino-N-ethylanilino ) ethanol . 

7-Amino-l,3-naphthalenedisulfonic  acid. 

A-Hydroxy-o-arsanilic  acid  [As03H2=l]. 

6-Amino-l,3-naphthalenedisulfonic  acid. 

( p- Isobutylamino  )phenol . 

3-Methyl-p-anisidine  [hrH2=l]. 

A '  -Amino-«i '  -  ( 3-methyl-5-oxo-2-pyrazolin-l-yl )  -2, 2' 

stilbenedisulfonic  acid. 
Naphthionic  acid. 

7-Amino-l,3,6-naphthalenetrisulfonic  acid. 
Naphthostyril. 
8-Amino-2-naphthol. 

8-Amino-l-naphthol-5,7-disulfonic  acid. 
8-Amino-l-naphthol-3,6-disulfonic  acid. 
8-Amlno-l-naphthol-3 , 5 -disulf onic  acid . 
7-Amlno-l-naphthol-3,6-disulfonic  acid. 
8-Amino-l-naphthol-5,7-disulfonic  acid. 
8-Amlno-l-naphthol -3,5 -disulf onic  acid . 
8-Amlno-l-naphthol-3,6-disulfonic  acid. 
7-Amlno-l-naphthol-3,6-dlsulfonic  acid. 
8-Amlno-l-naphthol-5-sulfonlc  acid. 
6-Amlno-l-naphthol-3-sulfonie  acid. 
6-Amino-2-naphthol-4--sulfonic  acid. 
7-Amino-l-naphthol-3-sulfonic  acid. 
l-Amlno-2-naphthol-4-sulfonic  acid. 
8-Amino-l-naphthol-5-sulfonic  acid. 
7-Amino-l-naphthol-3-sulfonic  acid. 
6-Amino-2-naphthol -^-sulfonic  acid. 
6-Amino-l-naphthol-3-sulfonlc  acid. 
5-Nitro-o-aniEidine  [  NH2=ll. 
/i-Nitro-o-anisidine  [NH2=lj. 
3-Nitro-o-anisidlne  [NH2=1J. 
2-Nitro-p-anisidine  [  NH2=l]. 

2-(p-Aminoanillno)-5-nitrobenzenesulfonic  acid. 
6-Amino-4-nitro-l-phenol-2-suironlc  acid. 
o-Phenetidine  [  NH2=l] . 
2-Amino-l-phenol-^-sulf onamide . 
2-Aniino-l-phenol-"l-sulfonamide. 
2-Amino-l-phenol-'4-sulfonic  acid. 
l-(m-Aminophenyl)-5-oxo-2-pyrazoline-3-carboxylic 

acid. 
l-(m-Aminophenyl)-3-raethyl-2-pyrazolin-5-one. 
p-Phenoxyani line . 
l-(m-Aminophenyl)-5-oxo-2-pyrazoline-3-carboxylio 

acid. 
l-(m-Aminophenyl)-5-oxo-2-pyrazoline-3-carboxylio 

acid. 
5-Amino-2-(p-toluidino)benzenesulfonic  acid. 
Isocytosine. 

3-Amino-2,7-naphthalenediEulfonic  acid. 
5-Amino-2-methoxybenzyl  alcohol. 
'»'-Amino-5'-methyl-p-toluenesulfon-o-anisidide. 


180 


UNITED  STATES  TARIFF  COMMISSION 


synonymous   names- -Continued 


3  -Amino- (p-toluenesulf one )ethoxytoluene 

2-Aniinotoluene-5-sulfonio  acid 

N-(4-Amino-m-tolyl)-p-quinone  imine 

(u-Amino-l,2,4-trimethylbenzene 

Aminoviolanthrene 

Amylnaphthalenes 

o-Ajnylphenol 

p-sec-Araylphenol 

p-tert-Amylphenol 

Aniline-2,i-disulfonic  acid : 

Aniline-2,5-disulfonic   acid 

Aniline  oil • 

Aniline  salt 

Aniline-m-sulfonio  acid 

Aniline-p-sulfonic  acid 

Aniline-omega-sulfonic   acid 

4-Anilino-<i'  -hydroxydiphenylamine 

6-Anilinometanilic  acid 

2-Aniside-<i-acetylurea 

o-Anisidine  nitrate 

2-Anisidine-'4-sulfobutylamide 

o-Anisidine-p-sulfonic   acid 

2-(m-Anisyl)-4-chloroanthranilic  acid 

N-ip-AnisyD-'V-chloroantliranilic  acid 

N-(m-Anisyl)~4-chloroanthranilic   acic" 

a  - (p-Anisyl ) -a-ethyl-p-methoxyacetophenone 

a-(p-Anisyl)-p-methoxyacetophenone 

N- (p-Anisyl )-4-nitroanthranilic  acid 

N- (p-Anisyl )-p-phenylenediamine 

1,2-Anthrapyridine 

Anthraquinonylaminoanthraquinone 

l,'i,9,10-Anthratetrol 

"i-Antipyrinecarboxylic   acid 

p , p' - Azobis ( N , N-dimethylani line  hydrochloride ) 

'Vj'i'-Azobisdiphenyls'nine 

Azohydroxyaniline 

Azoxy aniline 

ni,m'-Azoxybis  aniline 

Benzal  chloride 

Benzaldehydedisulfonic  acid 

Benzaldehydemonosulfonic   acid 

l-(4-Benzaiiiido-l-anthraquinonylimlno)-5-benzamido- 
anthraquinone . 

2- [3- ('i-Benzamido-2, 5-diethoxyphenyl) -l-methyldlazo- 
aininolethanesulfonic  acid. 

N-(<;-Benzamido-2,5-diethoxyphenyl)-N-methyldiazo- 
taurine. 

3-(4-Benzamido-2,5-diethoxyphenyl)-3-sulfoethyl-l- 
methyltriazene . 

[  3-('i-Benzamido-6-methoxy-m-tolyl)-l-methyldiazo- 
aminol acetic  acid. 

[  3-(4-Benzamido-6-methoxy-m-tolyl)-N-methyldiazo]- 
glycine. 

Benzanthrone 

Benzanthronedianthraquinonyldiimide 

Benzeneazobenzene 

Benzene- 1,3-dicarboxylic  acid 

p-Benzenedicarboxylic  acid 

1,3,5-Benzenetriol 

Benzidine  disulfonic  acid 

2,2'-Benzidinedisulfonic  acid 

Benzidine  sulfonic  acid 

Benz[cd]indol-2(lH)-one 

Benzocaine  (nonmedicinal  grade) 

2-Benzofurylcyanomethyl  ketone 

2H-l-Benzopyran-2-one 

1,2-BenzopyTone 

Benzotrichloride 

Benzoylacetanilide 

a-Benzoylacetanilide 

l-Benzoylamino-A-aminoanthraquinone 

2-Benzoylamino-l,'i-diethoxybenzene 

2-BenzoylajTLino-l,4-diinethoxybenzene 

5-Benzoylamino-2-nitrodiinethoxybenzene 

5-Benzoylamlno-2-nitrohydroquinone,  diethyl  ester 

Benzoyl  J  acid 

2-Benzoylthiophene 

a-Benzylacetamide 

m- Benzyl -p-aminophenol  hydrochloride 

Benzyl  chloride 

o-Benzyl-p-chlorophenol 


Standard  (Chemical  Abstracts)  name 


3-Methyl-N-(p-toluenesulfono)-p-phenetidine. 

"i-Amino-m-toluenesulfonic   acid  [S03H=1]. 

N-(4-Amino-m-tolyl)-p-benzoquinone  imine, 

2 ,  <i-Dimethy  Ibenzy  lamine . 

16-Aminoviolanthrone . 

Pentylnaphthalenes . 

o-Pentylphenol . 

p- ( 1-Methylbuty 1 )phenol . 

p- ( 1 , 1-Dimethylpropyl )phenol . 

<i-Amino-m-benzenedisulfonic  acid. 

2-Amino-p-benzenedlsulfonic  acid. 

Ani  line . 

Aniline  hydrochloride. 

Metanilic   acid  [S03H=1]. 

Sulfanilic   acid  [S03H=1]. 

Anilinomethanesulfonic   acid. 

p-(p-Anilinoanilino)phenol. 

5-Amino-2-anilinobenzenesulfonic  acid. 

l-Acetyl-3-(4-amino-3-iiiethoxyphenyl)urea. 

4(or  5)-Nitro-o-anlsidine  [  NHj^l] . 

ti^  -Butyl-4-methoxymet  ani  lamide . 

"i-Methoxymetanilic   acid  [SOjHsl]. 

4-Chloro-N-(m-methoxyphenyl)anthranilio  acid   [COOH^IJ . 

4-Chloro-N-(p-methoxyphenyl)anthranilic   acid    [COOH=1]  . 

4-Chloro-N-(m-methoxyphenyl)anthranilic  acid   [C00H=1] . 

2-Ethyl-4' -methoxy-2-(p-methoxyphenyl)acetophenone. 

4'  -Methoxy-2-  ( p-methoxyphenyl )  acetophenone . 

N-(p-Methoxyphenyl)-<l-nitroanthranilic  acid. 

N- (p-Methoxyphenyl) -p-phenylenediamine . 

Naphtho[2,3-h] quinoline. 

1,1  -Iminodianthraquinone. 

Leucoqulnizarin. 

Antipyric   acid . 

p-Diinethylajiiinobenzenediazonium  chloride. 

p-Anilinobenzenediazonium  chloride. 

p- (p-Arainophenylazo )phenol . 

3,3' -Azoxydianiline. 

3,3' -Azoxydianiline. 


a ,a -Dichlorotoluene . 
"i-Formyl-m-benzenedisulfonic   acid. 
o-Fonnylbenzenesulfonic  acid. 
4,5  -Dibenzamido-l,l' -iminodianthraquinone. 

2-[3-(4-Benzamido-2,5-diethoxyphenyl)-l-methyl- 

triazen-3-yl]ethanesulfonic   acid. 
2-[3-(4-Benzamido-2,5-diethoxyphenyl)-l-methyl- 

triazen-3-yl]ethanesulfonio  acid. 
2- [3- ( 4-Benzamido-2 , 5-diethoxyphenyl ) -1-methyl- 

triazen-3-yl]ethanesulfonic  acid. 
[  3-  (<«-Benzamldo-6-methoxy-m-tolyl)  -1-methyltriazen- 

3-yl]aoetic   acid. 
[3-(4-Benzamido-6-methoxy-m-tolyl)-l-methyltriazen- 

3-yl]acetic  acid. 
7H-Benz[de] anthraoen-7-one . 
3,9-Bis [l-anthraquinonylamino] -7H-benz [de] anthraoen- 

7-one . 
Azobenzene . 
Isophthaiic  acid. 
Terephthalic   acid. 
Phloroglucinol . 

4,4^-Diamino-2,2^-biphenyldisulfonlc  acid. 
4,4^-Diamino-2,2  -biphenyldisulfonic  acid. 
•4,4  -Diamino-S-biphenylsuLfonio  acid. 
Naphthostyril. 

p-Aminobenzolc  acid,   ethyl  ester. 
2-Benzofuranacetonitrile . 
Coumarin. 
Coumarin. 

a,  a,  a  -Trichlorotoluene. 
2-Benzoylacetanilide. 
2-Benzoylacetanilide . 
l-Amino-4-benzamidoanthraquinone . 
2   ,5 '-Diethoxybenzanilide. 
2 ',5 '-Dimethoxybenzanilide. 
2',5'-Dimethoxy-4'-nitrobenzanilide. 
2  ,5  -Diethoxy-4'-nitrobenzanilide. 
6-Benzaiiiido-l-naphthol-3-sulfonic  acid. 
Phenyl-2-thienyl  ketone. 
Hydrocinnamamide . 

4- Amino-  cc-phenyl  -m-c  resol  hydrochloride . 
a-Chlorotoluene . 
4-Chloro-a-phenyl-o-cresol  [  OH=l] . 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


181 


Cyclic    intermediates:    Glossary  of  synnnynotis   names- -Conti 


Common  name 


Standard  (Chemical  Abstracts)  name 


Benzyl  cyanide 

N-Benzyl-ethylaniline-- 

N-Benzyl-N-ethyl-p-nitrosoaniline 

3-Benzyl-7-hydroxy-4-methyloouinarin 

Benzylidineaoetophenone 

■i-Benzylidineaminoantipyrine 

Benzyl  mercaptan 

p-Benzylphenylcarbamate 

p,p'-Biacetoacetanilide 

Bibenzal 

Bibenzoyl 

Bibenzylidene 

o-Biphenylamine 

Biphenylene  oxide 

p,p'-Bis(acetoacetanilide) 

N,N'-Bis(acetoacetyl)benzidine 

l,3-Bis(4-biphenyl)-2-thiaurea 

N,N-Bis(2-hydroxyethyl) aniline 

N,N-Bis(2-hydroxyetl^l-m-toluidine) 

2,2'-Bis('i-hydroxyphenyl)propane 

N,N'-Bis-6-(l-naphthol-3-sulfonic  acid)urea- 

Bisphenol  A 

Bisphenol  B 

Bisphenol  C 

Bisphenol  G 

3,3 '-Bitolylene-4,4'-diisooyanate 

B.O.N —  - 


Broenner's  acid 

Bromamine  acid 

p-Bromoacetamidoanthraquinone 

Bromobenzanthrone 

2-Bromobiphenylene  oxide 

p-Broraomethylaminoanthraquinone 

4.-Bromo-N-methyl-l,9-anthrapyridone 


a-Bromo-p-nitroacfctophenone 

Bromoquinizarin 

o-(3-Brcimo-p-tolyl)benzoic  acid 

6-tert-Butyl-2,4-dimethylacetophenone 

n-Butyl-p-nitrobenzoate 


p-Carboxybenzene sulfonamide 

3-Carboxy-<i-hydroxyacetanilide 

3-(Carboxymethyl)-l-(5-ohloro-2-methoxyphenyl)-3- 

methyltri  azene . 

(o-Carboxyphenyl) acetic  acid 

Cassella  acid 

Chicago  acid 

Chlorinated  cresols 

2-Chloro-3-acetamino-9,10-anthrahydroquinone  acid 

ester. 

2-Chloro-3-acetaminoanthraquinone 

2-Chloro-3-aoetamino-9, lO-dihydroxyanthracene-9, 10- 

disulfonic   acid  ester. 

o-Chloroacetoacetanilide 

Chloroacetylarsanilic  acid 

5-Chloro-2-amlnoanisole  [  CHaO^l] 

<i-Chloro-2-amino-6-benzenesulfonic  acid 

6-Chloro-3-aminobenzotrifluoride 

Chloroaminophenol 

2-Chloro-'4-amlnotoluene  [CH3=]J 

3-Chloro-2-Rininotoluene  [CH3=1] 

5-Chloro-2-aminotoluene  [  CH3=1] 

m-Chloroaniline-o-sulfonic  acid 

p-Chloroani line -m- sulfonic   acid 

p-Chloroaniline-o-sulfonic  acid 

A-Chloro-o-anisidine  [CH30=1) 

5-Chloro-o-anisidine  [CH30=1] - 

3-Chloro-2-anthraoenecarboxylio  acid 

2-Chloroanthraquinone-3-carboxylic   acid 

Chloroarsacetin 

2-Chlorobenzaldehyde-5 -sulfonic  acid 

4-Chlorobenzaldehyde-2-sulfonic  acid 

l-Chloro-5-benzamideanthraquinone 

Chlorobenzanthrone 

•i-Chlorobenzotrifluoride 

Chlorobenzyl  cyanide 

l-Chloro-2-oai;boxyanthraquinone 

p-Chloro-m-cresol  [  CH3=1 ] 

2-Chloro-l,'4-dihydroxyanthraquinone 

Chloro  H  acid 

5-Chloro-8-hydroxyquinoline 

3-Chloro-3'-methoxy-6-diphenylaminecarbo)cylic  acid-- 


Phenylaoetonitrile . 
N-Ethyl-N-phenylbenzylamine . 
N-Ethyl-N- (p-nitrosopnenyl ) benzylamine . 
3-Benzyl-A-methylumbellif erone . 
Chaloone . 

4-Benzylideneiminoantipyrine . 
a-Toluenethiol. 
a-Phenyl-p-cresol  carbamate. 
^'  ,i'  "-Biacetoaoetanilide . 
Stilbene . 
Benzil. 
Stilbene. 
2-Biphenylamine . 
Dibenzofuran. 

4  '."i" '-Biacetoaoetanilide. 
**  ',4  '"- Bi ace toacet anil ide. 
4,4 '-Diphenylthiocarbanilide . 
2, 2 ' - f  Phenylimino )diethanol . 
2,2'-(m-Tolylimino)diethanol. 
4,4'-Isopropylidinediphenol. 
6,6'-Ureylenebis [l-naphthol-3-sulfonlc  acid  ]. 
4,4'-Isopropylidinediphenol. 
2,2 '-Bis (4-hydroxyphenyl)butane . 
4,4'-Isopropylidinedi-o-cresol. 
4,4'-Isopropylidinebis [2-isopropylphenol] . 
Isocyanic  acid,  (3,3 '-dimethyl -4, 4 '-biphenylene  ester. 
3-Hydroxy-2-naphthoic  acid. 
6-Amino-2-naphthalenesulfonic  acid. 
l-Amino-4-bromo-2-anthraquinonesulfonic  acid. 
l-Acetamido-4-bromoanthraquinone . 
3-Bromo-7H-benz [de] anthracen-7-one . 
2-Bromodibenzofuran . 
4-Bromo-l-methylaminoanthraquinone . 
6-Bromo-3-methyl-7H-dibenz[f ,ij]isoquinoline-2,7(3H)- 
dione. 
2-BrQmo-4  -nitroacetophenone, 
2-Bromoquinizarin. 

3'-Bromo-4'-methyl-2-biphenyloarboxylic  acid. 
2  '-tert-Butyl-4 ',  6  '-dijnethylacetophenone . 
p-Nitrobenzoic  acid,  n-butyl  ester. 


p-Sulf amoylbenzoic  acid. 

5-Acetamidosalicylic  acid. 

N- ( 5-Chloro-2-methoxyphenylazo ) -N-methylglycine . 

a -Carboxy-o-toluic  acid . 
3-Amino-l,5-naphthalenedisulfonic  acid. 
8-Amlno-l-naphthol-5,7-disulfonic  acid. 
Cresols,  chlorinated. 
2-Acetamido-3-chloro-9,10-dihydro-9,10-anthradiol- 

9,10-disulfonic  acid,  diethyl  ester. 
2-Acetamido-3-chloroanthraquinone . 
2-Acetaiiu.do-3-chloro-9,10-dihydro-9,10-anthradiol-9, 

10-disulfonic  acid,  diethyl  ester. 
2'  -Chloroacetoacetanilide . 
N-Acetyl-2-chloroarsanilic  acid  [As03H2=1]. 
4-Chloro-o-anisidine  [NH2=1]. 
5-Chlorometanilic  acid  [  S03H=l] . 
6-Chloro-a,a,a-trifluoro-m-toluidine  [NH2=1] • 
2-Amino-4-chlorophenol. 
3-Chloro-p-toluidine  [NH2=l]. 
6-Chloro-o-toluidine  [nH2=1]. 
4-Chloro-o-toluidine  [NHs^lj. 
2-Amino-6-chlorobenzenesulfonic  acid. 
6-Chlorametanilic  acid. 
2-Amino-5-chlorobenzenesulfonic  acid. 
5-Chloro-o-anisldine  [NH2=l]. 
4-Chloro-o-anisidine  [NH2=1]. 
3-Chloro-2-anthroic  acid. 
3-Chloro-2-anthraquinonecarboxylic  acid. 
N-Acetyl-2-chloroarsanilic  acid  [As03H2=l]. 
4-Chloro-3-formylbenzenesulfonic  acid. 
5-Chloro-2-formylbenzenesulfonio  acid. 
l-Benzamido-5-chloroanthraquinone. 
Chloro-7H-benz  [de]  anthracen-7-one. 
4-Chloro-*,a,a-trifluorotoluene. 
(p-Chlorophenyl)acetonitrile. 
l-Chloro-2-anthraquinonecarboxylic  acid. 
6-Chloro-m-cresol  [OH=l] . 
2-Chloroquinizarln. 

8-Chloro-l-naphthol-3,6-disulfonic  acid. 
5-Chloro-8-quinollnol. 
4-Chloro-N-(m-methoxyphenyl)anthranilic  acid  [C00H=1]. 


182 


UNITED  STATES  TARIFF  COMMISSION 


Cyclic   intermediates:    Glossary   of  synonymous   names- -Continued 


Common  name 


3-Chloro-'i'-methoxy-6-diphenylamlneoarboxylic  acid — 

a-Chloro-2-methoxy-5-nitrotoluene 

[3-(5-Chloro-2-methoxyphenyl)-l-methyldlazoamlno] - 
acetic  acid. 

Chloromethylanthraquinone 

o-Chloro-p-nitro aniline 

p-Chloro-o-nitroaniline 

Chloro-o-nitrobenzene 

4.-Chloro-3-nltrobenzotrlfluoride 

'i-Chloro-2-nltro-l-phenol-6-sulfonic  acid 

'4-Chloro-2-nltrophenyl  ether 

2-Chlorophenol 

i-Chlorophenol 

Chlorophenylhydrazine-p-sulfonlo  acid 

l-(m-Chlorophenyl)-3-methyl -5 -pyrazolone 

2-Chloro-o-phenyl  phenol 

l-(6-Chloro-<;-sulfophenyl)-3-methyl-2-pyrazolln-5-one 

l-(2-Chloro-4-sulfophenyl)-3-methyl-5-pyrazolone 

l-(6-Chloro-3-sulfophenyl)-3-methyl-5-pyrazolone 


o-Chloro-p-toluene  sodium  sulfonate 

4-Chlorotoluene-2-sulfonic   acid 

m-Chlorotoluenethioglyoolic  acid 

"i-Chloro-o-toluidlne   [CH3=l]- - - - 

5-Chloro-2-toluidine   [CH3=l] -- - -  — 

5-Chloro-o-toluidlne   [CH3=l] -- 

o-Chloro-m-toluidine-p-sulfonic   acid 

2-Chloro-p-toluidine-5-sulfonic  acid 

2-ChlQro-5-toluidine-"4-sulfonic  acid 

'i-Chloro-o-tolylmercaptoacetic  acid 

l-(5-Chloro-o-tolyl)-3-methyl-3-triazeneaoetic  atid- 

Chlorotolylthloglycollc  acid 

Chloro-sym-xylenol 

Chloroxylidenesulfonio  acid 

'♦-Chloro-2,5-xylylmercaptoacetic  acid 

Chromotropio  acid 

Cinnamene 

1,6-Cleve 's  acid 

1,7-Cleve's  acid 

Cieve's  acid,  mixed 

m-Cresidine 

Cresidine  or  p-Cresidine 

m-Cresol  methyl  ether 

m-Cresolsulfonic  acid 

o-Cresotic  acid 

Y-Cresotic  acid 

o-Cresotinic  acid 

Cresyldisulfide 

m-Cresyl  methyl  ether 

Cumaldehyde 

psi-Cumene 

psi-CXimidine 

Cuminaldehyde 

2-Cyanopyridlne 

3-Cyanopyridine 

A-Cyanopyrldine 


Dahl's  acid 

Dehydrothio-p-toluidine 

Desoxyanisoin 

Developer  Z 

3,6-Diaminoacridine 

m-Diaminoanisole 

3,3'-Diaminoazoxybenzene 

2,2'-Diamino-5,5'-bi-m-toluenesulfonic  acid- 


4,i  '-Diamino-l,l' -dianthraquinonylamine 

i,4'-Diamino-l,l'-dianthrimide 

Diamino-^,4  '-dibenzoyl-l,l'-dianthraquinoneimine — 
Diamlno-4,5'-dibenzoyl-l,l'-dianthraquinonylamine- 

l,'4-Diamino-2,3-dihydroxyanthraquinone 

3,6-Diamlno-2,7-dimethylacridine  hydrochloride 

<i,'i^-Diamino-2,2'-dimethylbiphenyl 

'i,'i^-Diamino-2,2'-dimethyldiphenylmethane 

A,4'-Diaminodiphenyl 

4,<i  ^-Diaininodiphenylamine-2-sulfonic  acid 

P.P,-Diaminodiphenylmethane 

p,p^-Diaralpodlphenylsulfide 

3,3  -Diaminodlphenyl  urea 

Di(p-aminophenyl)sulfide 

l,3-Di(m-aminophenyl)urea 


Standard   (Chemical  Abstracts)  name 


4-Chloro-N-(p-methoxyphenyl)anthranilic  acid. 

2- ( Chloromethyl ) -^-nitroanisole  { CH3O  =1 ] . 

N- (5-Chloro-2-methoxyphenylazo )-N-methylglycine . 

l-Chloro-2-methylanthraquinone . 

2-Chloro-^-nitroaniline . 

4-Chloro-2-nltroanl line . 

l-Chloro-2-nltrobenzene . 

4-Chloro-a, a, a-trifluoro-3-nitro toluene . 

4-Chloro-6-nltro-l-phenol-2-sulfonic  acid. 

l-('i-Chloro-2-nitrophenoxy)benzene. 

o-Chlorophenol. 

p-Chlorophenol. 

<i-Chloro-3-hydrazinobenzenesulfonio  acid. 

l-(m-Chlorophenyl)-3-methyl-2-pyrazolin-5-one. 

2-Chloro-6-phenylphenol. 

5-Chloro-'i-(3-methyl-5-oxo-2-pyrazolin-l-yl)benzene- 
sulfonic  acid. 

5-Chloro-<i-(3-methyl-5-oxo-2-pyrazolin-l-yl)benzene- 

sulfonic  acid. 
4-Chloro-3-(3-methyl-5-oxo-2-pyrazolin-l-yl)benzene- 

sulfonic  acid. 
3-Chloro-p-toluenesulfonic  acid,   sodium  salt  [S03H=l]. 
5-Chloro-o-toluenesulfonlc  acid  [S03H=l]. 
(<i-Chloro-o-tolylthio ) acetic  acid . 
5-Chloro-o-toluidlne  [NHj^l]. 
-i-Chloro-o-toluidine  [NHj^l]. 
i-Chloro-o-toluidine  [NH2=1]. 

2-Amlno-5-chloro-p-toluenesulfonic  acid  [S03H=l]. 
6-Amlno-4-chloro-m-toluenesulfonic  acid  [S03H=l]. 
2-Amino-5-ohloro-p-toluenesuironic  acid  [S03H=l]. 
("4-Chloro-o-tolylthio)acetic  acid. 
N-(5-Chloro-o-tolyl)-N-methylglyclne. 
(i-Chloro-o-tolylthio) acetic   acid. 
'4-Chloro-3 , 5-xylenol . 

6-Amino-3-chloro-2,5-xylenesulfonlc  acid   [S03H=l]. 
(4-Chloro-2,5-xylylthio) acetic  acid. 
'♦,5-Dihydroxy-2,7-naphthalenedisuironic  acid. 
Styrene . 

5-Amlno-2-naphthalenesulfonic  acid. 
8-Amino-2-naphthalenesulfonic  acid. 
5(and  8)-Amino-2-naphthalenesulfonio  acid. 
2-Methyl-p-anisidine  [  NH2=l] . 
5-Methyl-o-anisidine  [  NH2=l] . 
m-Methylanisole   [CH30=l]. 
5-Hydroxy-m-toluenesuironic  acid  [sOsH^l]. 
2,3-Cresotic  acid. 
2,4-Cresotic   acid. 
2,3-Cresotic  acid. 
p-Tolyl  disulfide. 
m-Methylanisole  [CHsOn]. 
p-Isopropylbenzaldehyde. 
1,2,'i-Trimethylbenzene. 
2 , 4 , 5-Trimethylani line . 
p- Isopropylbenzaldehyde . 
Pioolinonitrile . 
Nicotinonltrile . 
Isonicotinonitrile . 


6-Amlno-l-naphthalenesulfonic  acid. 

2- (p-Aminophenyl) -6-methylbenzothiazole . 

<i'-Methoxy-2-(p-methoxyphenyl)acetophenone. 

3-Methyl-l-phenyl-2-pyrazolin-5-one. 

Proflavine  base. 

5 -Methoxy-m-phenylenediamlne . 

3,3 '-Azoxydianiline. 

2,2 '-Diamino-5,5 '-dimethyl-3,3 '-biphenyldisulfonic 

acid. 
1,1^ -IminobisL^-aminoanthraquinone] . 
l,l^-Lninobis['i-aminoanthraquinone] . 
1, 1^ - Iminobis [ i-benzamidoanthraquinone ] . 
4,5  -Dibenzamido-1,1  -iminodianthraquinone. 
l.i-Diaminohystazarin. 
Acridine  yellow. 
m-Tolidine. 

4,4  -Methylenedi(m-toluidlne). 
Benzidine. 

5-Amlno-2-(p-aminoanilino)benzenesulfonic  acid. 
4,4'-Methylenedianiline. 
4,4  -Thiodianiline. 
3,3  -Diaminocarbanilide. 
4,4 ^-Thiodianiline. 
3,3   -Diaminocarbanilide. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


183 


Cyclic    intermediates:    Glossary   of  sYnonymous   names--Cnnti 


Common  name 


Standard   (Chemical  Abstracts)   name 


2,6-Diamlnotoluene-'i-sulfonic  acid 

Dlamylphenol 

l,5-Dianilinoanthraquinone-o,o'-dloarboxylio  acid 

o-Dianisidine 

l,2-Di-p-anisyl-l,2-ethanediol 

2,'i-Di(p-anisyl)-3-ethylhexane 

2,4-Di(p-anisyl)-3-ethylhexene 

a,P-Dlanisylglyool 

3,4-Di(p-anisyl)hexane 

l,l'-Dianthraquinoneimine 

l,l'-Dianthraquinonylamine 

Dianthrimide 

Dlazoaminobenzene 

Diazobenzene  chloride 

<i,5'-Dibenzamido-l,l'-aminodianthraquinone 

5,5'-Dibenzamido-l,l'-iminodianthraquinone 

Dibenzanthrone 

2,2'-Dibenzanthronyl 

13,13-Dibenzanthronyl 

Dibenzopyran 

Dibenzopyrrole 

Dibenzoyl 

4,5-Dibenzoylainidodianthraquinonylamine 

^jii'-Dibenzoyldlamino-ljl' -dianthrimide 

Dibenzyl 

Dibenzylaniline 

Dibenzyl  dlsulphide 

Dibenzyl  ether 

Dibenzyl  sodium  sulfanilate 

Dibronoaminoanthraquinone 

7,16-Dibromo-6,15-dihydro-5,9,l'i,18-anthrazinetetrone 

p-Dibromodlhydroxynaphthalene 

2,6-DlbrQfflO-l,5-dihydroxynaphthalene 

<t,5-Dibramo-l,8-dihydroxynaphthalene 

1,4-Dichloro aniline 

2, 5-Dicliloroaniline-4— sulfonic  acid 

l,5-Diohloro-'4,8-anthraquinonedisuli'onic  acid 

l,8-Dichloro-'i,5-anthraquinonedisuli'onic  acid 

2,6-Dichlorobenzalchloride 

o,o'-Dichlorobenzldine 

3,3'-Dichlorobenzidine  base 

m,m'-Dlchlorobenzidine  hydrochloride 

2,4.-Dichlorobenzyl  chloride 

2,'l-Dichlorobenzylidene  chloride 

2,6-Dichlorobenzylidene  chloride 

2,5-Dichlorophenylhydrazinesulfonlo  acid 

l-(2,5-Diohlorophenyl)-5-pyrazolone-3-carboxylio  acid 

2,5-Dichloro-4-suifobenzenediazohydroxide 

1- (2,5-Dichloro-'4-sulfophenyl) -3-methyl-5-pyrazolone- 

2,'i-Dichloro-5-(p-toluenesulfonamido)-l-naphthol 

Dioresyldisulfide 

Dicyclohexyl 

Diethanolanlline 

Diethanol-m-toluldine 

1,4-Diethoxybenzene 

N-{2,5-Diethoxy-4--nitrophenyl)benzamide 

H-(2,5-Diethoxyphenol)benzamide 

Diethylaniline-m-sulTonlo  acid 

Diformyl-m-tolylenediamllie 

1,2-Dihydroacenaphthylene 

9,10-DiMydroacridirte 

l,4-Dihydro-4-oxo-2,6-pyridinedicarboxylic  acid 

1,3-Dihydroxyanthraqulnone 

Ij'i-Dihydroxyanthraquinone 

1,5-Dihydroxyanthraquinone 

1,8-Dihydroxyanthraquinone 

2,6-Dihydroxyanthraquinone 

2,4-Dihydroxybenzolc  acid 

Diiydroxyblpheuyl 

2,3-Dihydroxy-l,4-diaminoanthraquinoue 

Dihydroxydibenzanthrone 

5,5  '-Dihydroxydi-2-naphthylamine-7,7  '-disulfonio  acid 

l,5-Dihydroxy-'i,8-dinitroanthraquinone 

p,p  '-Dihydroxydiphenyldimethylmethane 

4,4'-Dihydroxydlphenylsulfone 

5,5-Dihydroxy-7,7'-disulfonic-2,2'-dinaphthylamine--- 

Dlhydroxyethylanlline 

N,N-Di(P-hydroxyethyl) aniline 

Dihydroxyethyl-3-toluidlne 

N,N-Di(P-hydroxyethyl)-m-toluidine 

3','4'-Dihydroxy-2-methylaminoacetophenone 


3,5-Diamino-p-toluenesulfonio  acid. 
2,'i-Dlpentylphenol. 
l,5-Dlanilino-2,6-anthraquinonedioarboxylic  acid. 

3.3  '-Dlmethoxybenzidlne . 

1, 2-Dl (p-methoxyphenyl ) - 1, 2-ethanediol . 
2,4-01 (p-methoxyphenyl ) -3-ethylhexane . 
2,4-01 (p-methoxyphenyl) -3-ethylhexene . 
1, 2-Di (p-methoxyphenyl ) -1, 2-ethanediol . 
3 ,4-Di (p-methoxyphenyl )hexane . 
1 , 1 ' - Imlnodi anthraquinone . 
1 , 1 ' - Iminodi anthraquinone . 
1 , 1 ' - Iminodi  anthraquinone . 
1,3-Diphenyltriazene. 
Benzenediazonium  chloride. 

4.5  -Dibenzamido-1,1  -iminodianthraquinone. 

1.1  -Tminobis [5-benzam1doanthraquinone] ■ 
Viclanthrone. 

(4,4^-Bi-7H-benz[de] anthracen)-7,7'-dione. 

(3,3'-Bi-7H-benz[de]anthraoen)-7,-7'-dione. 

Xanthene. 

Carbazole. 

Benzil. 

4, 5 ' -Dibenzamido-1, 1 '-iminodianthraquinone . 

l,l'-Iminobis [4-benzamidoanthraquinone] . 

Bibenzyl . 

N-Phenyldibenzylamine . 

Benzyl  disulfide. 

Benzyl  ether. 

N,N-Dibenzylsulfanilio  acid,  sodium  salt. 

l-Amino-2,4-dlbromoanthraquinone. 

7, 16-Dibrcmoindanthrene . 

4, 5-Dlbromo-l , 8-naphthalenediol . 

2, 6-Dlbromo-l, 5-naphthalenediol . 

4,5 -Dibromo- 1 , 8-naphthalenediol . 

2, 5-Dlohloro aniline. 

2,5-Dichlorosulfanilic   acid   [S03=l]. 

4,8-Dichloro-l,5-anthraquinonedisulfonic   acid. 

4,5-Dichloro-l,8-anthraquinonedisulfonic  acid. 

a , a, 2 , 6-Tetraohlorotoluene . 

3,3' -Diohlorobenzidlne . 

3,3' -Diohlorobenzidlne . 

2,2'-Dichlorobenzldine  hydrochloride. 

a,2,4-Trichlorotoluene. 

oc,  a,2,4-Tetrachlorotoluene. 

a, a, 2, 6-Tetrachlorotoluene . 

2,5-Diohloro-4-hydrazinobenzenesulfonic  acid. 

l-(2,5-Dichlorophenyl)-5-oxo-2-pyrazollne-3-carboxylic 

acid. 
2,6-Dichloro-4-hydroxydiazobenzenesulfonic  acid. 
2,5-Diohloro-4-(3-methyl-5-oxo-2-pyrazolin-l-yl) 

benzenesulfonio  acid. 
H- (6, 8-Dlchloro-5 -hydroxy-l-naphthyl)-p-toiuene- 

sulf  onamide  [  S02NH2=1]  . 
p-Tolyl  disulfide. 
Bicyclohexyl. 

2,2 '-(Phenylimijio)dlethanol. 
2,2 '-(m-Tolyllmino)diethanol. 
p-Diethoxybenzene . 
2  ',5  '-Dlethoxy-4  '-nitrobenzanilide . 
2  ',  5  '-Diethoxybenzanilide . 
N.N-Diethylmetanilic  acid  [S03H=l]. 
N^,N^-Dlformyltoluene-2,5-diamine  [CH3=1] . 
Acenaphthene . 
Acridan. 

Che lid ami c  acid, 
Xanthopurpurln. 
(iiinizarin. 
Anthrarufin. 
Chrysazin. 
Anthraflavic  acid. 
P-Resorcylic   acid. 
Biphenol . 

1,4-Dlaminohystazarin. 
16, 17-Dihydroxyviolanthrone . 

6.6  -Tminobis [ l-naphthol-3-sulf onie  acid]. 
4, 8-Dinltro  anthrarufin. 

4.4  -Isopropylidenedlphenol. 
4,4 ^-Sulf onyldiphenol . 

6,6  -Tml nobis [ l-naphthol-3-sulf onie  aoidJ. 

2.2  -(Phenylimino)diethanol. 
2 , 2^ - ( Phenylimino ) diethanol . 
2,2' -(m-Tolylimino)diethanol. 
2,2'- (m-Tolylimino ) diethanol . 
Adrenalone. 


184 


UNITED  STATES  TARIFF  COMMISSION 


Cyclic   intermediates:    Glossary  of 


synonymous 


S-- Continued 


Common  name 


1,5-Dihydroxynaphthalene 

2,3-Dihydroxynaphthalene 

l,8-Dihydroxynaphthalene-3,6-disulfonio  acid 

l,8-Dihydroxynaphthalene-'i-sulfonio  acid 

2,3-Dihydroxynaphthalene-6-sulfonio  acid 

P-Di-p-hydroxyphenylpropane 

7,8-Diketoacenaphthene 

2, 3-Dijnethoxyben2  aldehyde 

3,4-Dimethoxybenzaldehyde 

o-Dimethoxybenzene 

1,2-Diinethoxybenzene 

3,3'-Dimethoxybenzidine-<i,^'-diisocyanate 

"4,4' -Dime thoxybenzoin • 

p,p'-Dlme"thoxybenzoylphenylcarbinol 

3,"+-Dimethoxybenzyl  alcohol 

3,3 '-Dimethoxy-4,4 '-blphenylbis [3-methyl-3- 

triazeneethanesuLfonic   acid] . 
N,N'-{3,3'-Dimethoxy-4,4'-biphenylenebisazo)bisCN- 

methyltaurine ) . 
2, 2' -[ 3, 3  '- ( 3 , 3 '-Dimethoxy-4 ,4 '-bif henylene )bis ( 1- 

methyldlazoamino)] di(ethanesulfonio  acid). 
1 , 1' - ( 3 , 3  '-Dimethoxy-4 , A ' -bipheny lene ) bis ( 3-methy 1-3- 

(sulfoethyl)triazene) . 

Di-p-methoxyethylchalcone 

4,4' -Dimethoxy- a -hydroxy-a-pheny lacetone 

N-(2,5-Diraethoxy-4-nitrophenylibenzamide 

N-(2,5-Dimethoxyphenyl}benzamide 

Dimethylacetanilide 

Dimethylaminoacetylcatechol 

4-Dimethylamino-2,3-dimethyl-l-phenyl-3-pyrazolln-5- 

one. 

N,N-Dimethyl-3-aminophenol 

Dime thylanl line 

Dime thy Ibenzene 

2  ',4-Dimethylbenzenesulfonanilide 

2,2'-Dimethylbenzidine 

3,3 '-Dime thy Ibenzidine 

2,4-Dimethyl-6-tert-butylacetophenone 

l,3-Dimethyl-5-tert-buty Ibenzene 

2,7-Dimethylceroxanol 

Dime thy Idianthraquinonyl 

2.2  '-Dimethyl-l,l-dianthraquinonylamine 

Dimethylhydroresorclnol 

3.3  '-Dimethyl-4,4  '-methylenediphenyl  isocyanate 

Dijnethyl-a-naphthylamine 

2,3-Dimethyl-5-oxo-l-phenyl-37pyTazoline-4-carboxylic 
acid. 

2,3-Dimethyl-l-phenyl-3-pyTazolin-5-one 

2,7-Dimethylquinoline 

Dinaphtho[l,2,3-cd,l',2',3'-lm]perylene-9,18-dione-— 
Dinaphtho  [l,2,3-cd,3  ',2 ',  1  '-lm]perylene-5, 10-dione— - 

1,4-Dinitrobenzene 

2,4-Dinltrobenzene 

Dinitrochlorobenzene 

Dinitrochlorobenzenesulfonic  acid 

3,5-Dinitro-4-chlorobenzoic  acid 

2,6-Dinitro-4-chlorophenol 

Dinitro-o-cyclohexylphenol 

4,4'-Dinitro-l,l '-dianthraquinonylamine 

Dinltrodibenzanthronyl 

Dinitrohydroxydiphenylamine 

Dinitrotetrame thy Idiaminodiphenylme thane 

2,4-Dinitrotoluenesuli'onic  acid 

1,2-Dioxoacenaphthene 

Dioxy  S  acid 

Diphenol 

Diphenyl 

2,4-Diphenylamine-l-hydroxyanthraquinone 

2,4-Diphenylamlno-l-oxyanthraquinone 

Diphenylcarbazide 

Dlphenyleneimlne 

Diphenylene  oxide 

Diphenyl  epsilon  acid 

Diphenyl  ether 

Diphenyl  ketone 

Diphenylmethanol 

Diphenyl  oxide 

l,3-Diphenyl-2-propen-l-one 

Diphenyl  silicon  dichloride 

1,3-Diphenylurea 

N,N-Diphenylurea 

sym-Diphenylurea 

Dlpyrazoledianthrone 


Standard   (Chemical  Abstracts)   name 


1, 5-Naphthalenediol . 

2, 3-Naphthalenediol . 

4,5-Dihydroxy-2,7-naphthalenedlsulfonic  acid. 

4,5-Dihydroxy-l-naphthalenesulfonic  acid. 

6,7-Dthydroxy-2-naphthalenesulfonic   acid . 

4,4'- Isopropy lidinediphenol . 

Acenaphthenequinone . 

o-Veratraldehyde . 

Veratraldehyde . 

Veratrole. 

Veratrole. 

Isocyanic  acid,   3,3'-dlmethoxy-4,4'-biphenylene 
ester. 

p-Anisoin. 

p-Anisoin. 

Veratryl  alcohol. 

3,3'-Dlmethoxy-4,4'-bis[3-methyl-3-sulfoethyltrlazen- 
1-yl]  biphenyl. 

3 , 3' -Dimethoxy-4, 4' -bis [ 3-methyl-3-sulf oethyltriazen- 
l-yl]  biphenyl. 

3, 3' -Dimethoxy-4, 4' -bis  [3-methyl-3-su  If  oethyltriazen- 
l-yl]  biphenyl. 

3, 3 '-Dimethoxy-4, 4' -bis[  3-methy 1-3-su If oethyltriazen- 
l-yl]  biphenyl . 

«-Ethyl-4,4'-dimethoxychalcone . 

p-Anisoin. 

2 ', 5' -Dimethoxy -4 '-nitrobenzanilide. 

2',5  '-Dimethoxybenzanilide. 

Acetoxylidide. 

3',4'-Dlhydroxy-2-dimethylaminoacetophenone. 

Aminopyrine . 

m- { Dimethylamino )phenol . 

Xylldine . 

Xylene . 

p-Toluenesulf ono-o-toluidide . 

m-Tolidine. 

o-Tolidine. 

2  -tert-Butyl-4  ,6'-dimethylaoetophenone. 

5-tert-Butyl-m-xylene. 

2, 8-Dimethyl-13b-hydroxy-9 { 13b ) -ceroxenone . 

2, 2  -Dimethyl-1, 1  '-bianthraquinone . 

1, I'-Iminobis [2-methylanthraquinone] . 

Dimethyl-1, 3-cyclohexanedione. 

Isocyanic  acid,  2,2 '-dimethyl -4,4' -methylenedi- 

phenylene  ester. 
N,N-Dimethyl-l-naphthylamine . 
Antipyric  acid. 

Antipyrine . 

m-Toluquinaldine . 

Isoviolanthrone . 

Violan throne. 

p-Dinitrobenzene . 

m-Dinit  robenzene , 

l-Chloro-2,4-dinitrobenzene. 

4-Chloro-3,5-dinitrobenzenesulfonic  acid  [S03H=l]. 

4-Chloro-3,5-dinitrobenzoic  acid  [C0OH=l]. 

'.-Chloro-2,6-dinltrophenol  [OH=l]. 

2-Cyclohexyl-4,6-dinitrophenol  [  OH=l] . 

1, 1  -Iminobis [4-nitroanthraquinone ] . 

Dinitro(3,3  '-bi-7H-benz[de] anthracene) -7, 7  -dione. 

p-(2,4-Dinitroanilino)phenol. 

4,4'-Methylenebis  [N,N-dijiiethyl-2-nitroaniline] . 

3,5-Dinitro-o-toluenesuLfonic  acid  [S03H=l]. 

Acenaphthenequinone . 

4,5 -Dihydroxy- 1-naphthalenesulf onio  acid . 

Biphenol . 

Biphenyl . 

2,4-Dianilino-l-hydroxyanthraquinone. 

2,4-Dianilino-l-hydroxyanthraquinone. 

1 , 5 -Dipheny Ic  arbohydrazide . 

Carbazole. 

Dibenzofuran. 

8-Diphenylamino-l,6-naphthalenedisulfohio  acid. 

Phenyl  ether. 

Benzophenone. 

Benzhydrol. 

Phenyl  ether. 

Chalcone. 

Dichlorophenylsilane . 

Carbanilide. 

Carbanilide. 

Carbanilide. 

[3,3'-Bianthra[l,9]pyrazole]-6,6'(2H,2'H)-dione. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


185 


Cyclic   intermediates:    Glossary   of  synonymous   names- -  Continued 


Common  name 


Standard   (Chemical  Abstracts)  name 


1,3-Di-p-toluldineanthraquinone — 
1,4-Di-p-toluldineanthraquinone — 
l,3-Di(p-tolylamino)anthraqulnone- 
1,4-Di-p-tolylaminoanthraquinone — 

S-Dixenylthiourea 

Durene 


N-Ethanol-N-ethyl-4-nitrosoaniline 

2-Ethanolpyridine 

2-Ethoxy aniline 

4-Ethoxyaniline 

2-Ethoxy-6-sulfonaphthalene 

Ethyl-p-aminobenzoate 

Ethyl-o-amino-p-cresol 

Ethylanillne  (mono) 

N,N-Ethylbenzylaniline 

Ethylbenzylanilinesulfonic  acid 

Ethylbenzyl-m-toluidine 

Ethylbenzyl-m-toluidino-o-sulfonlo  ac 


id- 


Ethyleneglyool  monophenylether 

Ethyl  hydrol 

N-Ethyl-N-(P-hydroxyethyl) aniline 

Ethyl  ketone  base 

2-[l-Ethyl-3-(2-methoxy-5-nitrophenyl)diazoamino] -5- 
sulfobenzoic  acid. 

5-Ethyl-2-methylpyridine 

p-Etl^lnitrobenzene 

Ethyl-p-nitrobenzoate 

Ethyl-p-nitrobenzoylacetate 

Ethyl  phenyl  ether 

Ethylsulfobenzylaniline 

N-Ethyl-o-toluidine-p-sulfonic  acid 


Fast  red  TR  base 

p-Formylaniline 

p-Formyl-N,N-diethylaniline- 
4-Formyl-3-pyrazolin-5-one-- 


G  acid 

Gamma  acid 

Gamma  disulfo  acid 

GlyoeroLmonoethylaniline- 


H  acid 

Halocrin 

Hexahydrobenzoic  acid 

Hexahydropyridine 

Hcmophthalic  acid 

a-m-Homosalicylic  acid 

p-Homosalicylic  acid 

Homoveratric  acid 

o-Homoveratric  acid 

Homoveratronitrile 

Homoveratrylamine 

1,2-1,2-Hydrazinedibromoanthraquinone- 
Hydrol 

Hydroquinone  dimethyl  ether 

1-Hydroxy-A-  aminoanthraqu  inone 

7-Hydroxycoumarin 

"i-Hydroxydlphenol 

P-Hydroxyethyl-o-ohloroaniline 

Hydroxyethylethylaniline 

Hydroxyethylmethylaniline 

N-(P-Hydroxyethyl)-N-methylanillne 

Hydroxyethyl-3-toluidine 

2-Hydroxymetanilic  acid 

4-Hydroxymetanilic  acid 

2-Hydroxy-3-methoxybenzaldehyde 

2-Hydroxy-3-methylbenzoic  acid 

2-Hydroxy-'4-methylbenzoic  acid 

2-Hydroxy-5-methylbenzoic  acid 

V-Hydroxy-'i-methylcoumarin 

2-Hydroxy-5-nitrometanilic  acid 

4-Hydroxy-5-nitrometanilic  acid 

2-Hydroxyphenet ole 

p-Hydroxyphenylarsonic  acid 

p-Hydroxyphenyl-n-butylamine 

3-(p-Hydroxyphenyl)hydratroplc  acid 

N- (p-Hydroxyphenyl) -2-naphthylamine- 


P-(p-Hydroxyphenyl)-a-phenylpropionic  acid a-Phenylphloretic  acid 


l,3-Dl(p-toluidlno)anthraqu inone. 
1 ,4-Di (p-toluidlno ) anthraqu inone . 
l,3-Di(p-toluidino)anthraquinone. 
1  ("l-Di  ( p-toluidino )  anthraquinone . 
^j-i'-Diphenylthiocarbanilide . 
1 , 2 ,  <• ,  5 -Tet  ramethy  Ibenzene . 


2-  ( N-Ethyl-'i-nltrosoanilino  )ethanol . 
2-Pyridineethanol . 
o-Phenetidine  [NH2=1]. 
p-Phenetidlne  [NH2=l]  . 
6-Ethoxy-2-naphthalenesulf onio  acid . 
p-Aminobenzoic  acid,  ethyl  ester. 
3-Ethylamino-p-cresol  [OH=l]. 
N-Ethylaniline . 
N-Ethyl-N-phenylbenzylamine . 

a-(N-Ethylanilino)-p-toluenesuli'onio  acid  [S03H=1]. 
N-Benzyl-N-ethyl-m-toluidlne  [  NH2=l]. 
4- ( N-Benzyl-N-ethylamino ) -o-toluenesulf onic  acid 

[  SO3H  =1] . 
2-Phenoxyethanol . 
4,4  -Bis[dlethylamino]benzhydrQl. 
2- ( N-Ethylanilino ) ethanol . 
4,4'-Bis[diethylamino]benzophenone. 
2- [l-Ethyl-3- (2-methoxy-5-nitrophenyl)triazen-3- 

yl]-5-sulfobenzoic  acid. 
5-Ethyl-2-picoline . 
l-Ethyl-4-nitrobenzene . 
p-Mitrobenzoio  acid,  ethyl  ester. 
p-Nitrobenzoylacetio  acid,  ethyl  ester. 
Phenetole . 

a-(N-Ethylanillno)-p-toluenesulfonic  acid  [S03H=l]. 
3-Ethylamiiio-p-toluenesulfonlo  acid  [S03H=l]. 


4-Chloro-o-toluidine  [NH2=l]. 

p-Aminobenz aldehyde . 

p-  (Diethyla'iiino)benzaldehyde . 

5-0xo-3-pyrazoline-4-carboxaldehyde. 


2-Naphthol-6,8-disulfonic  acid. 
7-Amlno-l-naphthol-3-sulfonic  acid. 
7-Amino-l-naphthol-3,6-disulfonic  acid. 
3- ( N-Ethylanilino ) -1, 2-propanediol . 


8-Amino-l-naphthol-3,6-disulfonio  acid. 

6,9-Dichloro-2-methoxyaoridine. 

Cyclohexaneoarboxylic  acid. 

Piperidine. 

a-Carboxy-o-toluio  acid, 

2,4-Cresotic  acid  [COOH=l]. 

2,5-Cresotic  acid  [COOH=l]  . 

(3,4-Diinethoxyphenyl)acetic  acid. 

(2,3-Dimethoxyphenyl)acetic  acid. 

( 3, 4-Dimethoxyphenyl ) aoetonitrile . 

3 , 4-Dimethoxyphenethylamlne . 

7 ,  16-Dibromoindanthrene . 

4, 4 '-Bis ( dimethylamino )benzhydrol . 

p-Dimethoxybenzene . 

l-Amino-4-hydroxyanthraquinone . 

Umbelliferone. 

p-Phenylphenol. 

2-(o-Chloroanilino)ethanol. 

2- ( N-Ethylani lino ) ethanol . 

2-(N-Methylanilino)ethanol. 

2- ( N-Methylanilino )ethanol . 

2- (m-Toluidino) ethanol. 

6-Amino-l-phenol-2-sulfonio  acid. 

2-Amino-l-phenol-4-sulfonic  acid. 

o-Vanillin. 

2,3-Cresotio  acid  [  COOH=l]  . 

2,4-Cresotio  acid  [  CCCH^l] . 

2,5-Cresotic  acid  [  COOH=l] . 

4-Methylumbellif erone . 

6-Amino-4-nitro-l-phenol-2-sulfonic  acid. 

2-Amino-5-nltro-l-phenol-4-sulfonio  acid. 

o-Ethoxyphenol . 

p-Hydroxybenzenearsonio  acid  [As03H2=:1]. 

p-Butylaminophenol . 

a-Phenylphloretic  acid. 

p-2-Naphthylaminophenol. 


186 


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Cyclic   intermediates:    Glossary  of  synonymous   names- -Continued 


Common  name 


3-(p-Hydroxyphenyl)-2-phenylpropionio  acid 

"i-Hydroxypyridine-S.e-dioarboxylic  acid 

8-Hydroxyquinoline 

m-Hydroxytoluene 

o-Hydroxytoluene 

p-Hydroxytoluene 

6-Hydroxy-m-toluidine  [  NH2=l] 

2-Hydroxy-p-toluio   acid 

I   acid 

I  acid  Imide 

2,2  '-(l,3-Indandione)quinoline 

Isobutyl  p-nitrobenzoate 

Isodlbenzanthrone 

p-Isopropylaniline 

Isopropylbenzene 

Isopropyl  p-toluenesulfonate 

J  acid 

J  acid  imide 

J  acid  urea 

K  acid - 

Koch's  acid 

Laie  red  C  amine 

Laurent 's   acid 

Lead  styphnate 

Lead  trinitroresorcinate 

Leuco-lj-i-dlCmethylaminojanthraquinone 

Methandrone 

Methane  base 

Methane  salt 

o-Methoxyacetanilide 

p-Methoxyacetanilide 

<4-Methoxy-'*  -aminodiphenylamine 

2-Methoxy-4^-aminodlphenylamlne-2  '-sulfonic  acid 

Methoxy aniline 

o-Methoxyanilincmethanesulfonio  acid 

2-(o-Methoxyanilino)-5-nitrobenzenesulfonlc  acid 

o-Methoxyanilino-p-sulfonlc  acid 

Methoxybenzene 

p-Methoxybenzoic  acid 

4-Methoxy-3  -ohloro-6  -carboxydiphenylamine 

2-Methoxy-6,9-diohloroacridine 

^  -Methoxy-<t-nitrodiphenylamine-2'-sulfonio  acid 

2-[3-(2-Methoxy-4-nitrophenyl)-l-methyltriazeno]-5- 
sulfobenzoio  acid. 

A-Methoxy-m-toluidine  [CH3=l) 

6-Methoxy-m-toluidine  [NH2=l] 

[ 3-(6-Methoxy-m-tolyl)-l-methyltriazeno) acetic  acid- 

<i-Methyl-i-aminodiphenylamine-2-sulfonic  acid 

Methylamlnosulfobenzoic  acid 

o-Methylaniline 

Methylaniline  (mono) 

2-Me thy Ibenz enthrone 

Methylbenzoic  acid 

Me  thy lenebis(toluenedi amine) 

4., 4- '-Methylene  bis  [o-tolylisooyanate] 

Methylenedl-p-phenyleneisocyanate 

4,4'-Methylenediphenylisocyanate 

Methylenedi-o-tolylene  isooyanate 

2-Methyl-5-ethylpyTidine  (MEP) 

"i-Methyl-V-hydroxycoumarin 

Methyl-p-hydroxy-m-nitrobenzoate 

l-Methyl-4-hydroxyquinolone 

3-Methyl-4-(3-methyl-5-oxo-2-pyrazolin-l-yl)ben2ene- 

sulfonic   acid. 
3-Methyl-l-(2-methyl-4-sulfophenyl)-5-pyrazolone 

N-(5-Methyl-<i-nitro-o-anisyl)-p-toluenesulfonamide— 

2-Methyl-5-nitrodiphenylamine 

3-Methyl-l-(m-nitrophenyl)-5-pyrazolone 

m-Methylphenol 


Standard  (Chemical  Abstracts)  name 


a -Phenylphloretic  acid. 
Chelidamio  acid. 
8-Quinolinol. 
m-Cresol  [OH=l]. 
o-Cresol  [ OH=l] . 
p-Cresol  [  oH=l]  . 
2-Amlno-p-cresol  [OH=l]. 
2,4-Cresotlc  acid  [COOH=l]. 


6-Amino-l-naphthol-3-sulfonic  acid. 

6,6'-Iminobis[l-naphthol-3-sulfonio  acid]. 

Oiinophthalone . 

p-Nitrobenzoio  acid,  isobutyl  ester. 

Isoviolanthrone . 

Cumidine. 

Cumene. 

p-Toluenesulfonlo   acid,   isopropyl  ester  [SOjH^l] . 


6-Amlno-l-naphthol-3-sul/onlc   acid. 

6 , 6 '-Iminobis [ l-naphthol-3-sulf onic  acid ] . 

6,6  '-Ureylenebis[l-naphthol-3-sulfonlc  acid]. 


8-Amino-l-naphthol-3,5-disulfonie   acid. 
8-Amino-l,3,6-naphthalenetrisulfonio  acid. 


2-Amino-5-chloro-p-toluenesulf onic  acid  [  S03H=1] . 
5-Amino-l-naphthalenesulfonio  acid. 
Styphnic  acid,   lead  salt. 
Styphnio  acid,    lead  salt. 
Iji-Dimethylamlno-gjlO-anthradiol. 


3  ',<*  -Dihydroxy-2-(dimethylamino)acetophenone. 

4,4^'-Methylenebis[N,N-diniethylaniline]. 

4,'4'-Methylenebls  [3-hydroxy-2-naphthoic   acid  ] . 

o-Acetanisidide . 

p-Acetanisidide . 

N- (p-Methoxyphenyl ) -p-phenylenediamine . 

o-('i-Amino-2-anisidlno)benzenesulfonic  acid  [S03K=l]. 

Anisidine  [NH2=1  ]. 

o-Anisidinamethanesulfonio  acid. 

2-(o-Anisidino)-5-nltrobenzenesulfonic  acid. 

i-Methoxymetanllic  acid  [S03H=l]. 

Anlsole. 

Anisic  acid  [C0OH=l]. 

'i-Chloro-N-(p-methoxyphenyl)anthranilic  acid 

[C00H=1]. 
6,9-Dichloro-2-methoxyacridlne. 

2-(p-Anisldlno)-5-nitrobenzenesulfonic  acid  [S03H=l]. 
2-  [3- ( 2-Methoxy-';-nitrophenyl ) - l-methyltriazen-3-yl ] - 

5-sulfobenzoic  acid. 
5-Methyl-o-anisidine  [NH2=l]. 
5-Methyl-o-anisidine  [NH2=l]. 
[3-(6-Methoxy-m-tolyl)-l-methyltriazen-3-yl] acetic 

acid. 
5-Amino-2-(p-toluldino)benzenesulfonlc  acid. 
N-Methyl-5-sulfoanthranilio  acid. 
o-Toluidine  [  NH2=l]. 
N-Methylaniline . 

2-Methyl-7H-benz [de] anthracen-7-one. 
p-Toluio  acid  [COOH=l]. 
5,5  -Methylenebis  [toluene-2,'4-diamine  ]. 
Isocyanlc  acid,  3,3'-dimethyl-4,4'-methylenedi- 

phenylene  ester. 
Isooyanic  acid,  methylenedl-p-phenylene  ester. 
Isooyanio  acid,  methylenedi-p-phenylene  ester. 
Isocyanlc  acid,  3,3 '-dimethyl -4,4' -methylenedl- 

phenylene  ester. 
5-Ethyl-2-picoline. 
4-Methylumbellif erone . 

p-Hydroxy-m-nitrobenzoic  acid,  methyl  ester. 
l-Methyl-4( LH ) -quinolone . 
4-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-m-toluene- 

sulfonic  acid  [S03H=l]. 
4- ( 3-Methyl-5-oxo-2-pyrazolin-l-yl ) -m-toluene- 

sulfonic  acid. 

N-(5-Methyl-4-nitro-o-methoxyphenyl)-p-toluene- 

sulfonamide. 
5-Nitro-N-phenyl-o-toluidine  [NH2=l]  ■ 
3-Methyl-l-(m-nitrophenyl)-2-pyrazolin-5-one. 
m-Cresol  [  OH=l]  . 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


187 


Cyclic   intermediates:    Glossary  of  synonymous   names--Continued 


Conmon  name 


Standard  (Chemical  Abstracts)  name 


o-Methylphenol 

p-Methylphenol 

4-Methyl-m-phenylenediisooyanate 

3-Methyl-l-phenyl-5-pyrazolone 

MethylphenylpyTazolone-3-sulfonio  acid 

Methylphenylpyrazolone-4— sulfonic  acid 

2-Methylpiperidine 

<i-(3-Methyl-5-pyTazolone)-m-toluenesulfonio  acid 

Methylpyridine 

2-Methylqu incline 

3-Methyl-l-(m-sulfophenyl)-2-pyrazolin-5-one 

3-Methyl-l-(p-sulfophenyl)-2-pyrazolin-5-one 

Methylsulf ophenylpyrazolone ,  mixed 

S-Methyl-l-lp-sulfophenylj-S-pyrazolone 

Methyl-p-toluenesulfonate 

P-Methylumtelliferone 

2-Methyl-5-vinylpyridine    (MVP) 

Michler's  hydrol 

Michler's  ketone 

Monobromobenzene 

Monoohlorobenzene 

Naphthalene  sodium  sulfonates 

Naphthalene-P-thioglycolio  acid 

2(lH)-peri-Naphtha2olone 

o-Naphthionlc   acid 

a-Naphthol 

P-Naphthol 

l-Naphthol-8-chloro-3,6-disulfonio  acid 

2-Naphthol  ethyl  ether 

Naphthosulfochloride 

1,8-Naphthosultone 

Naphthylaoetonitrile 

a-Naphthylamine 

P-Naphthylamine 

l-Naphthylamine-3,6-disulfonio  acid 

l-Naphthylamlne-3,8-disulfonic  acid 

l-Naphthylamine-'l,7-disulfonio  acid 

l-Naphthylamine-<i,8-disulfonio  acid 

2-Naphthylamine-l,5-disulfonio  acid 

2-Naphthylamine-3,6-disulfonio  acid 

2-Naphthylamine-4, 8-disulf onic  acid 

2-Naphthylamine-5,7-disulfonic  acid 

2-Naphthylamine-6,3-disulfonic  acid 

l-Naphthylam±ne-2-sulfonic  acid 

l-Naphthylamine-3-sulfonic  acid 

l-Naphthylamine-4-sulfonic  acid 

l-Naphthylamine-5-sulfonio  acid 

l-Naphthylamine-6-sulfonio  acid 

l-Naphthylamlne-6(and  7)-sulfonic   acid 

l-Naphthylamine-7-sulfonic   acid 

l-Naphthylamine-8-sulfonic  acid 

2-Naphthylamine-l-sulfonio  acid 

2-Naphthylamine-5-sulfonio  acid 

2-Naphthylamine-6-sulfonic  acid 

2-Naphthylamine-8-sulfonic  acid 

l-Naphthylamine-3,6,8-trisulfonic   acid 

2-Naphthylamine-3,6,8-trisulfonio  acid 

l-Naphthylamino-2-carboxylic  acid  anthraquinone- 

1-Naphthylisocyanate 

a-Naphthyl  isocyanate 

2-Naphthylmercaptoacetic   acid 

Naphthylmethanesulfonio  acid 

p-Naphthylthioglyoolio  acid 

Nevlle  &  Winther's  acid 

3-Nitro-4-aminoanisole  [  CH30=1] 

'i-Nitro-2-aminoanisole  [  CH30=l] 

5-Nitro-2-aminoanisole  [  CH30=1]  --- 

6-Nitro-2-aminoanisole  [  CH30=1] 

o-Nitro-p-ami  nophenol 

p-Nitro-o-aminophenol 

5-Nitro-o-aminophenol 

4-Nitro-2-amlnophenol-6-sulfonic  acid 

6-Nitro-2-aminophenol-4-sulfonic  acid 

A-Nitro-<i'-amino-2-sulfodiphenylamine 

5-Nitro-2-aminotoluene  [  CH3  =l] 


o-Cresol  [Ott=H. 

p-Cresol  [  0H=1]. 

Isocyanic  acid,  4-methyl-m-phenylene  ester. 

3-Methyl-l-phenyl-2-pyrazolin-5-one. 

m-(3-Methyl-5-oxo-2-pyTazolin-l-yl)benzenesulfonic 

acid. 
p-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonio 

acid. 
2-Pipeooline . 
<i-  ( 3-Methyl-5-oxo-2-pyrazolin-l-yl )  -m-toluenesulf  onic 

acid. 
Picoline. 
Quinaldine. 
m-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic 

acid. 
p-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic 

acid. 
m(and  p)-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzene- 

sulfonio  acid. 
p-(3-Methyl-5-oxo-2-pyTazolin-l-yl)benzenesulfonic 

acid. 
p-Toluenesulfonic  acid,  methyl  ester  [S03H=l]. 
4-Methylumbellif erone . 
5-Vinyl-2-picoline . 
4,'*'-Bis[dimethylainino]benzhydrol. 
4, '4' -Bis  [  dimethylamino]  benzophenone . 
Bromobenzene . 
Chlorobenzene   (mono). 


Naphthalenesulfonio  acids,   sodium  salt  (mixed). 
(2-Naphthylthio) acetic  acid. 
Naphthos  tyr i 1 . 

l-Amino-2-naphthalenesulfonio  acid. 
1-Naphthol. 
2-Naphthol. 

8-Chloro-l-naphthol-3,6-disulfonic  acid. 
2-Ethoxynaphthalene . 
1-Naphthalenesulfonyl  chloride. 
l-Naphthol-8-sulfonic   acid  sultone. 
Naphthaleneacetonitrile . 
1-Naphthylamine . 
2-Naphthylamine . 

5-Amino-2,7-naphthalenedisulfonic  acid. 
8-Amino-l,6-naphthalenedisulfonio  acid. 
4-Amino-l,6-naphthalenedisulfonic  acid. 
4-Amlno-l,5-naphthalenedisulfonic  acid. 
2-Amino-l,5-naphthalenedisulfonlc  acid. 
3-Amino-2,7-naphthalenedisulfonic  acid. 
3-Amino-l,5-naphthalenedisulfonic  acid. 
6-Amino-l,3-naphthalenedisulfonic  acid . 
7-Amino-l,3-naphthalenedisuLfonio  acid. 
l-Amino-2-napthalenesulf onic  acid. 
4-Amino-2-naphthalenesulfonic  acid. 
Naphthlonic   acid. 

5-Amlno-l-naphthalenesulfonic  acid. 
5-Amino-2-naphthalenesulfonic   acid. 
5 (and  8)-Amiiio-2-naphthalenesulfonic  acid. 
8-Amino-2-naphthalenesulfonic   acid. 
8-Amino-l-naphthalenesulfonic  acid. 
2-Amino-l-naphthalenesulfonic   acid. 
6-Amino-l-naphthalenesulfonic  acid. 
6-Amino-2-naphthalenesulfonic  acid. 
7-Jtaiino-l-naphthalenesulfonio  acid. 
8-Amlno-l,3,&-naphthalenetrisulfonic  acid. 
7- Amino- 1,3, 6-naphthalenet risulf onic  acid . 
l-(l-Naphthylamino)-2-anthraquinoneoaTboxylic  acid. 
Isocyanic  acid,    1-naphthyl  ester. 
Isocyanic  acid,    1-naphthyl  ester. 
(2-Naphthylthio) acetic   acid. 
1-Naphthalenemethanesulfonic  acid. 
(2-Naphthylthio) acetic   acid. 
l-Naphthol-4-sulfonic  acid. 
2-Nitro-p-anisidine  [NH2=i]. 
5-Nitro-o-anisidine  [nH2=i]. 
4-Nitro-o-anisidine  [NH2=1]. 
3-Nitro-o-anisidine  [nH2=i1. 
4-Amino-2-nitrophenol . 
2- Amino-4-nitrophenol . 
2-Amino-5-nitrophenol. 

6-Amtno-4-nitro-l-phenol-2-sulfonic  acid. 
2-Amino-6-nitro-l-phenol-4-sulfonic  acid. 
2-(p-Aminoanilino)-5-nitrobenzenesulfonic  acid. 
■i-Nitro-o-toluidine   [NH2  =  i]. 


188 


UNITED  STATES  TARIFF  COMMISSION 


Cyclic   intermediates:    Glossary  of  synonymous   names--Continued 


Conmon  name 


Standard   (Chemical  Abstracts)  name 


p-Nltroanlline-o-suLfonic  acid 

m-Nltro-p-anlsldlne  [  CH30=l] 

3-Nltro-p-anlsldine  [  CH30=1] •■ 

<;-Nltro-2-anlsldlne  [  CH30=1]  - 

5-Nitro-2-anlsldine  [  CHsOsl] -- 

2-Nltroanlsole-'i-sulfodlethyi  amide 

l-Nitroantliraquinone-2-carboxyllo   acid 

Nitrobenzene-2,5-dlsulfonic   acid 

l-Nitrobenzene-i-sulfonic   acid 

2-Nltrobenzenesulfonlc  acid 

3-Nltrobenzenesulfonic  acid 

3-Nltrobenzenesulfonyl  chloride 

m-Nitroben2oyl  J  acid 

p-Nitrobenzoyl  J  acid 

m-Nitrochlorobenzene 

o-Nitrochlorobenzene 

p-Nitrochlorobenzene 

2-ttttro-i-chlorobenzene-'i-sulfobutylamlde 

2-Nitro-l-chlorDbenzene-'i-Eulfodiethylamlde 

o-Nltrochlorobenzene-iJ-sulionlc   acid 

p-Nitrochlorobenzene-o-sulfonic  acid 

3-Nitro-^-chlorobenzoylbenzolc  acid 

"i-Nitro-6-chloro-l,3-dimethoxybenzene 

2-Nitro-4— clirorophenol 

2-Nitro-<i-chlorophenol-6-sulfonlo  acid 

m-Nitro-p-chlorotoluene 

o-Nltro-p-chlorotoluene 

p-Nitro-o-chlorotoluene 

2-Nitfo-A-chlorotoluene 

m-Nitro-p-cresol  [CH3=l] 

Nltrocresyl  methyl  ether 

Nltro-p-dlchlorobenzene 

o-Nltrodlphenyl 

p-Nitrodlphenyl 

^-Nltro-2-diphenylamtnesulfonlc  acid 

<i-Nitrodlphenylamino-2-sulfonic  acid 

2-Nitrohydroquinone,  diethyl  ether 

2-Nitrohydroquinone,   dimethyl  ether 

3-Nltro-<V-hydroxy-l-phenylarsonlc   acid 

6-Nitro-4-methoxy-3-amlnotoluene  [CH3=l] 

2-Nitro-4-methoxy-5-(p-toluenesu if on amldo) toluene 

A-Nltro-l-methylanlline 

l-Nitro-2-methylanthraqulnone 

2-Nitronaphthalene-"i,8-disulfonlo  acid 

7-Nitro-l,5-naphthalenedisulfonlc  acid 

"i-Nltronaphthalic   acid  tolyllmide 

2-Nitro-l-phenol-^,6-dlsulfonlc   acid 

3-Nitrophenylhydrazlne 

p-(p-Nitropheny  line  rcapto)  aniline 

1- ( m-Nitrophenyl ) -5 -pyrazolone -3-oarboxyllc  acid 

Nitropyrazolonecarboxyllc  acid 

p-Nitrosodiethylanlline 

p-Nltrosodimethylaniline 

Nltroso-P-naphthol 

3-Nitro-5-stearoylamlno-p-toluenesulfonic  acid 

"i-Nltrotolueneanlllde 

6-Nitro-3-  (p-toluenesuLf  one )  araino-'4-methoxytoluene 

A-  -^Nitro-p-toluenesulfone-o-tolulde 

o-Nltrotoluenesulfonio   acid 

p-Nitrotoluene-o-suIfonic   acid 

m-Nitro-o-toluldine  rCH3=l] -- 

m-Nltro-p-toluidine  [CH3=l] 

p-Nitro-o-toluidine  [CH3=l] — 

3-Nitro-4-toluldine  [  CH3=l]  — 

4-Nitro-2-toluidine  [CH3=l] — 

5-Nitro-2-toluidine  [CH3=l] - 

Nitrotoluidine  sulfone 

6-Nitro-o-toluldine-4-sulfonlc  acid 

N-(4-Nitro-o-tolyl)-p-toluenesulfonamlde 

5-Nltro-l,2,<i-trichlorobenzene 

Nitroviolanthrene 

p-Nltro-o- xylene 

^-Nitro-l,3-xylene 

2-Nitro-l,'i-xylol 

'i-Nltro-l,3-xylol - 

Orthanlllc  acid 

Oxalyl-p-nltroanillne 

Oxalyl-p-nitrophenylamlne 


2-Amino-5-nltrobenzenesulfonlc  acid. 
2-Nitro-p-anlsidlne  [NH2=1]. 
2-Nltro-p-anisldine  [  NH2=1] . 
5-Nltro-o-anisidlne  [  NH2=11  . 
4-Nitro-o-anisidine  [  NH2=lJ • 

N, N-Diethyl-3-nitro-p-methoxybenzenesuLf  onamlde . 
l-Nitro-2-anthraquinonecarboxylic   acid. 
2-Nitro-p-benzenedlsulfonic   acid. 
p-Nitrobenzenesulfonic  acid   [S03H=l]. 
o-Nitrobenzenesulfonic   acid  [S03H=l]. 
m-Nltrobenzenesulfonic  acid  [S03H=l]. 
m-Nitrobenzenesulfonyl  chloride  [  S03Cl=l] . 
6-(m-Nltrobenzamido) -l-naphthol-3-sulfonic  acid. 
6- (p-Nltrobenzamido ) - l-naphthol-3-sulf onic   acid . 
l-Chloro-3-nitrobenzene . 
l-Chloro-2-nitrobenzene . 
l-Chloro-4-nitrobenzene . 

N-Butyl-4-chloro-3-nitrobenzenesulfonamlde. 
4-Chloro-N,N-dlethyl-3-nitrobenzenesulfonamlde. 
4-Chloro-3-nltrobenzenesulfonlc  acid. 
2-Chloro-5-nltrobenzenesulfonic  acid. 
o-('»-Chloro-3-nltrobenzoyl)benzoic  acid. 
6-Chloro-l,3-dimethoxy-<i-nitrobenzene. 
4-Chloro-2-nltrophenol. 

4-Chloro-6-nitro-l-phenol-2-sulfonic  acid. 
'V-Chloro-3-nitrotoluene. 
<i-Chloro-2-nitrotoluene . 
2-Chloro-'i-nitrotoluene . 
4--Chloro-2-nitrotoluene . 
2-Nitro-p-cresol   [0H=1] . 
4-Methyl-2-nltroanisole   [CHsO^l]. 
l,4-Dlchloro-2-nitrobenzene. 
2-Nitrobiphenyl. 
'V-Nltrobiphenyl. 

2-AnHino-5-nltrobenzenesulfonic   acid  [S03H=1). 
2-Anillno-5-nltrobenzenesulfonic   acid  [S03H=1]. 
l,'^-Diethoxy-2-nitrobenzene . 
l,4-Diinethoxy-2-nltrobenzene. 
*+-Hydroxy-3-nltrobenzenearsonic   acid . 
5-Methyl-4-nltro-o-anisidine  [  NH2=l]. 
N-  ( S-Methyl-'l-nitro-o-methoxyphenyl )  -p-toluenesu  If  on- 
amlde. 
5-Nltro-o-toluldine   [nH2=i]. 
2-Methyl-l-nitroanthraqulnone . 
3-Nltro-l,5-naphthalenedlsulfonic  acid. 
3-Nitro-l,5-naphthalenedisulfonlc   acid. 
<i-Nitro-N-(p-tolyl)naphthalimlde. 
6-Nltro-l-phenol-2,<i-disulfonic   acid. 
m-Nitrophenylhydrazine . 
p-(p-Nitrophenylthlo) aniline. 
1- (m-Nltrophenyl) -5-oxo-2-pyrazoline-3-oarboxyllc 

acid. 
l-(m-Nitrophenyl)-5-oxo-2-pyrazollne-3-oarboxylic 

acid. 
N,N-Diethyl-p-nltrosoaniline. 
N, N-Dime thy 1-p-nitrosoani line . 
l-Nitroso-2-naphthol. 
3-Nitro-5-stearoylamldo-p-toluenesulfonic  acid 

[S03H=1]  . 
5-Nltro-n-phenyl-o-toluldine  [ NHj^l] • 
N- ( 5-Methyl-4-nitro-o-methoxyphenyl ) -p-toluene- 
su if  onamide. 
4'-Nitro-p-toluenesulfono-o-toluldide. 
3-Nitro-p-toluenesulfonlc  acid  [SOsH^l]. 
5-Nitro-o-toluenesulfonic  acid  [S03H=l]. 
-i-Nitro-o-toluidine   [  NH2  =1]  • 
2-Nltro-p-toluidine   [NH2=1]. 
5-Nitro-o-toluidine  [NH2=l]. 
2-Nitro-p-toluldine   [NH2=1]' 
5-Nltro-o-toluidine   [NH2=1]. 
4-Nitro-o-toluldine  [NH2=1]- 
"i'-Nitro-p-toluenesulfono-o-toluidide. 
4--Amlno-5-nitro-m-toluenesulfonic   acid  [S03H=l]. 
"i'-Nltro-p-toluenesulfono-o-toluidide. 
l,2,4-Trlchloro-5-nltrobenzene. 
16-Nltroviolanthrone . 
4-NltTO-o-xylene . 
4-Nitro-m-xylene. 
2-Nltro-p-xylene. 
"i-Nltro-m- xylene . 


o-Aminobenzenesulfonlc  acid  [S03H=1]. 
4  -Nltrooxanilic   acid. 
"i'-Nltrooxanilic  acid. 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


189 


Cyclic  intermediates:   Glossary  of  synonymous   names- -Continued 


Common  name 


Standard  (Chemical  Abstracts)  name 


Oxalyl-m-phenyldiamine 

Oxalyl-p-phenyldi amine 

i-0xo-'»H-pyran-2,6-dicarboxylic  acid 

2-Oxycarbazole 

a-Oxynaphthoic  acid 

P-Oxynaphthoic  acid 

Pentaanthramide 

Peri  acid 

Phenethylene 

Phenol,  sodium  salt 

1-Phenylacetylcarbinol 

3-Phenylacrylophenone 

2-Phenylamine-5-naphthol-7-sulfonic  acid 

2-Phenylamine-8-naphthol-6-sulfonic  acid 

N-Phenylaniline 

Phenylarsonic  acid 

N-Phenylazoaniline 

Phenylbiphenyl 

Phenyl  bromide 

l-Phenyl-3-oarboxy-5-pyrazolone-4— sulfonic  acid 

Phenyldiethanolamine 

N,N  -p-Phenylenebis [acetamide] 

m-Pheny ienedi ami"  nedisu If onic  acid 

m-Phenylenediaminesulfonic  acid 

p-Phenylenediaminesulfonic  acid 

Phenylene  nerol  acid 

Phenylethanolamine 

Phenyl  gamma  acid 

Phenylhydrazine-p-sulfonic  acid 

Phenylhydrazine-2-sulfonic  acid 

Phenylhydrazine -3 -sulfonic  acid 

N-Phenyl-N'-(P -hydro  xyethyl)thiciurea 

Phenyl  isocyanate 

Phenyl  J  acid 

Phenylmalonic  ester 

Phenylmethanesulfonic  acid 

Phenyl- P-naphthylamine 

N-Phenyl-l-nephthylamine-8-sulfonio  acid 

o-Phenyl-P-(A-oxophenyl)propionic  acid 

Phenyl  peri  acid 

N- Phenyl -p-phenylenediaminesulf onic  acid 

l-Phenyl-5-pyrazolone-3-carboxylic  acid,  ethyl  ester- 

Phenyl  silicon  chloride 

Phenyls tyryl  ketone 

l-Phenyl-4'-sulfo-5-pyrazolone-3-carboxylic  acid 

Phthalyl  chloride 

3-Piperidino-l-propanol 

Piperidinopropyl  alcohol 

Pot as s ium- 3 - chloro -6- c arboxy- 3 ' -methoxyd ipheny lamlne - 

n-Propyl-p-nitrobenzoate 

Pseudocumene 

Pseudooumidlne 

Parpuroxanthin 

Pyrazoleanthrone 

Pyrazoleanthrone  yellow 

3-Pyrazolin-<4-ylacetic  acid 

3-Pyrazolone 

5-Pyrazolone 

Pyrazolone  G 

Pyrazolone  T 

2-Pyridylethanol 

R  acid— 

2R  acid -  — 

Red  KB  base 

Rhoduline  acid 

S  Acid 

2S   (SS)   acid - 

Schaeffer's   acid 

Silver  salt 

Sodium  carbolate 

Sodium  naphthionate 


3  -Aminooxanilide. 

4  '-Aminooxani lide . 
Chelidonlc  acid. 
2-Hydroxyoarbazole . 
l-Hydroxy-2-naphthoic  acid. 
3-Hydroxy-2-naphthoic  acid. 

l,'i,5,8-TetraM.s[l',l",l  '",1  ""-anthraquinonyl- 

aminol  anthraquinone . 
8-Amino-l-naphthalenesulfonic  acid. 
Styrene . 

Sodium  phenoxide. 
l-Hydroxy-l-phenyl-2-propanone. 
Chalcone. 

6-Anilino-l-naphthol-3-sulfonic  acid. 
7-Anilino-l-naphthol-3-sulfonio  acid. 
Dlphenylamine . 
Benzenearsonic  acid. 
1,3-Diphenyltriazene. 
Terphenyl. 
Bromobenzene . 
5-Oxo-l-(p-sulfophenyl)-2-pyrazoline-3-carboxylio 

acid. 
2,2'-(Phenylimino)diethanol. 
N,N  -(p-Phenylene)bis[ acetamide]. 
'i,6-Diamino-m-benzenedisulfonic  acid. 
2,*i-Diaminobenzenesulfonic  acid. 
2,5-Diaminobenzenesulfonic  acid. 
5-Amino-2-(p- ami noanilino)benzenesulf onic  acid. 
2- Ani linoethanol . 

7-Anilino-l-naphthol-3-sulfonic  acid. 
p-Hydrazinobenzenesulfonic  acid  [S03H=l]. 
o-Hydrazinobenzenesulfonic  acid  iS03H=l]. 
m-Hydrazinobenzenesulfonic  acid  [S03H=l]. 
1- ( 2-Hydroxyethyl ) -3-phenyl-2-thiourea . 
Isocyanic  acid,  phenyl  ester. 
6-Anilino-l-naphthol-3-sulfonic  acid. 
Phenylmalonic  acid,  diethyl  ester. 
a-Toluenesulfonlc  acid. 
N-Phenyl-2-naphthylamine . 
8-Anilino-l-naphthalenesulfonic  acid. 
a-Phenylphlor*etic  acid. 
8-Anilino-l-naphthalenesulfonlc  acid. 
5-Amino-2-anillnobenzenesulfonlc  acid  [S03H=l]. 
5-0xo-l-phenyl-2-pyrazoline-3-carboxyllo  acid, 

ethyl  ester. 
Trichlorophenylsilane. 
Chalone . 
5-0x0-1- (p-su If ophenyl)-2-pyrazoline-3-carboxy lie 

acid. 
Phthaloyl  chloride. 
1-Piperidinepropanol. 
1-Piperldinepropanol . 
«*-Chloro-N-  (m-methoxyphenyl)  anthranllio  acid, 

potassium  salt  [COOH=ll. 
p-Nitrobenzoic  acid,  n-propyl  ester. 
1,2,  <i-Trime  thylbenzene . 
2,^,5-Trimethylaniline . 
Xanthopurpurin . 
Anthra [1,9] pyr azol-6 ( 2H ) -one . 

[3,3'-Bianthra[l,9]pyrazole]-6,6'(2H,2'H)-dlone. 
3-Pyrazoline-4-acetic  acid. 
3-Pyrazolin-5-one . 
2-Pyrazolin-5-one . 
p-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonio 

acid. 
5-0xo-l-(p-sulfophenyl)-2-pyTazoline-3-carboxylic 

acid. 
2-Pyrldlneethanol. 


2-Naphthol-3,6-disulfonic  acid. 
7-Amino-l-naphthol-3,6-dlsulfonic  acid. 
5-Chloro-o-toluidine  [NH2=l]' 
6,6  '-Iminobis[l-naphthol-3-sulfonlc  acid] 


8-Amino-l-naphthol-5-sulfonic  acid. 
3-Amino-l-naphthol-5,7-dlsulfonic  acid. 
2-Naphthol-6-sulfonic  acid. 
2-Anthraquinonesulfonic  acid,  sodium  salt. 
Sodium  phenoxide . 
Naphthionic  acid,  sodium  salt. 


190 


UNITED  STATES  TARIFF  COMMISSION 


Cyclic   intermediates:    Glossary  of  synonymous  names- -Continued 


Common  name 


Standard  (Chemical  Abstracts)  name 


Sodium  phenate 

Sodium  phenolate 

Sodium-o-phenylphenolate 

Sodium  tetrachloEophenolate 

Sodium  triohlorophenolate 

Styrol - 

Sulfo  BB  acid- 

o-Sulfobenzaldehyde 

4-Sulfo-o-benzoylbenzoic  acid 

l-Sulfo-5-nitroanthraquinone 

Sulfophenylmethylpyrazolone 

l-Sulfophenyl-5-pyrazolone-3-oarboxylic  acid- 


Tetraaminoditolylme thane 

Tetrachloro-p-benzoquinone 

Tetrachloroquinone 

Tetraethyldiaminobenzhydrol 

Tet raethy Idi  aminobenzophenone 

Tetraethyldiaminodiphenylmethane 

Tetraethyldiaminotriphenylmethane 

Tetrahydrophthalimide 

Tetramethyldiaminoacridine  hydrochloride 

Tet  ramethy  Idi  aminobenzophenone 

Tetramethyldiaminobenzoylhydrol 

Tetrame  thy  Idi  aminodipheny  line  thane 

Tetramethyldiaminotriphenylme thane 

Thloanlline - 

Thioanilinedisulfonio  acid 

p,p  -ThiobiE(<i-amino-o-benzenesulfonic  acid) 

Thiosalicylic  acid 

Tobias  acid 

a-Tolu amide 

Toluene-2,'i-diisocyanate 

p-Toluenesulfoohloride 

'i-Toluenesulfonamido-l-aminoanthraquinonesulfonic 
acid. 

P-Toluenesulfonic  acid 

Toluene-2,4,6-triol 

4-Toluic  acid 

a-Toluic  acid 

m-Toluidine-o-sulfonio  acid 

m-Toluidine-p-sulfonic  acid 

o-Toluidine-m-sulfonic   acid 

o-Toluidine-omega-sulfonic  acid 

p-Toluidine-m-sulfonio   acid 

p-Toluidine-o-sulfonic  acid 

p-Toluidine-o-sulfonio  acid,   isopropyl  ester 

3-Toluidine-6-sulfonic  acid 

6-(p-Toluidino)metanilic  acid 

a-Tolunitrile 

i-Tolunitrile 

l,3-(p-Tolylamino)anthraquinone 

p-Tolyl-o-benzoic   acid 

o-Tolylcarblnol 

Tolylenediamine 

p-m-Tolylenediamine 

-i-m-Tolylenediamine 

5-m-Tolylenediamlne 

m-Tolylenediaminesulfonic   acid 

m-Tolylene  diisocyanates 

[3-(p-Tolyl)-l-methyltriazeno]acetic   acid 

Tolyl  peri  acid 

2,^,6-Triaminobenzene  trihydrochloride 

2,'+,6-Triaminotoluene  trihydrochloride 

Trianthraquinonyldi-imide 

1,4-Trianthrimide 

Triohlorophenylsilicane 

1,2,'V-Trihydroxyanthraquinone 

1,2,6-Trihydroxyanthraquinone 

2,'i,6-Trihydroxytoluene 

1,3,5-Trijnethylbenzene 

2,'4,6-Trimethylpyridine 

Trinitrophenol 

2,'V,6-Trinitroresorcin 

1,2,4-Trioxyanthraquinone 

1,3,5-Triphenylhexahydro-s-triazine 

Triphenyl  silicon  chloride 


Sodium  phenoxide. 

Sodium  phenoxide. 

o-Phenylphenol,    sodium  salt. 

2,3,'i,6-Tetrachlorophenol,   sodium  salt. 

2,4,5-Trichlorophenol,  sodium  salt. 

Styrene . 

2-Benzoyl-"i-sulfobenzoic  acid  [COOH=l]. 

o-Formylbenzenesulfonic  acid  [SOjH^l]. 

2-Benzoyl-4-sulfobenzoic   acid  [COOH=l]. 

5-Nitro-l-anthraquinonesulfonic  acid. 

p-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonio 

acid. 
5-Oxo-l-(p-sulfophenyl)-2-pyTazoline-3-carboxylio 

acid. 


5,5'-Methylenebis  [toluene-2,'i-diamine]. 

Chloranil. 

Chloranil. 

4,4  -Bis [diethylaminojbenzhydrol. 

4,4  -Bis[diethylamino]benzophenone, 

4,4  -Methylenebis[N,N-diethylaniline] . 

4,4  -Benzylldenebis[N,N-diethylaniline]. 

4-Cyclohexene-l,2-dicarboximide. 

2,7-Bis[dimethylamino]aoridine  hydrochloride. 

4,4  -Bis [dime thy lamino]benzophenone. 

4,4^-Bis[diethylamino] benzhydrol. 

4,4^-Methylenebis[N,N-dimethylaniline] . 

4,4  -Benzylidinebis[N,N-dimethylaniline] . 

4,4^-Thiodianiline. 

6,6  ^-Thiodimetanilic  acid  [S03H=l]. 

6,6'-Thiodimetanilic   acid  [S03H=l]. 

o-Mercaptobenzoic  acid   [COOH=l]. 

2-Amino-l-naphthalenesulfonic  acid. 

2-Phenylacetamide . 

Isocyanio  acid,  4(and  2) -methyl -m-phenylene  ester. 

p-Toluenesulfonyl  chloride  [S02Cl=ll. 

l-Amino-4-(p-toluenesulfonamido)-2-anthraquinone- 

sulfonic  acid. 
p-Toluenesulfonic   acid,   methyl  ester  [S03H=l). 
2-Methylphloroglucinol. 
p-Toluic   acid    [C00H=l]  . 
Phenylacetic  acid. 

4-Amino-o-toluenesulfonic  acid  [S03H=l]. 
2-Amino-p-toluenesulfonic  acid  [S03H=l]. 
4-Amino-m-toluenesulfonic  acid  [S03H=l]. 
(o-Toluidino)methanesulfonic  acid  [S03H=l]. 
6-Amino-m-toluenesulfonic  acid  [S03H=l]. 
5-Amino-o-toluenesulfonic  acid  [S03H=l]. 
5-Amino-o-toluenesulfonic  acid,   isopropyl  ester 

[S03H=l]. 
4-Amino-o-toluenesulfonic  acid   [S03H=l]. 
5-Amino-2-(p-toluidino)benzenesulfonic  acid. 
Phenylacetonitrile. 
p-Tolunitrile. 

l,3-Di(p-toluidino)anthraquinone. 
o-(p-Tolyl)benzoic   acid  [COOH=l]. 
o-Methylbenzyl  alcohol. 
Toluenedi  amine . 
Toluene-2,5-diamine. 
Toluene-2,4-diamine. 
Toluene-3 , 5-diamine . 

4,6-Diamino-m-toluenesulfonic  acid  [SOsH^l]. 
Isocyanic  acid,  4( and2) -methyl -m-phenylene  ester. 
[3- (p-Tolyl)-l-methyltriazen-3-yl] acetic  acid. 
8- (p-Toluidino ) -1-naphthalenesulf onic  acid . 
1,3,5-Benzenetriamine  trihydrochloride. 
Toluene-2,4,6-triamine  trihydrochloride. 
1,4-Bis[l-  anthraqu  inonylamino  ]  anthraquinone . 
1,4-Bis  [l-anthraquinonylamino] anthraquinone. 
Trichlorophenylsilane. 
Purpurin. 
Flavopurpurin. 
2-Methylphloroglucinol . 
Mesitylene . 
s-Collidine. 
Picric  acid. 
Styphnic   acid. 
Purpurin . 

Hexahydro-l,3,5-triphenyl-s-tria2tne. 
Ch lorot  ripheny Is  i lane . 


SYNTHETIC  ORGANIC  CHEMICALS,  1956 


191 


Cyclic   intermediates:    Glossary   of  synonymous   names- -Continued 


Common  name 

Standard  (Chemical  Abstracts)  name 

Styrene . 

Methyls tyrene . 

Dlnaphtho[l,2,3-cd,3',2',l'-lm]perylene. 

A-Biphenylamine . 
2,'i-Xylidine  acetate. 

2-Amino-3,5-xylenesulfonic  acid  [S03H=l]. 
4-Chloro-m- xylene . 

Violanthrene 

m-J^lidinesulfonic  acid 

192  UNITED  STATES  TARIFF  COMMISSION 

D.  Production  and  Sales  of  Cellulose  Plastics 

Cellulose  plastics  are  derived  from  cellulose  acetate,    cellulose 
propionate,    cellulose  butyrate,    and  mixtures  of  cellulose  esters, 
and  from  cellulose  nitrate  and  ethyl  cellulose.    The  most  important 
applications  of  cellulose  plastics  are  in  the  manufacture  of  nnolded 
and  extruded  articles  and  accessories,    such  as  umbrella  handles, 
toys,    buckles  and  decorative  products,    fittings  for  household  and 
automotive  equipment,    and  in  packaging.    The  statistics  given    in 
table   30  were  compiled  from  the  Tariff  Commission's  monthly  re- 
ports on  the  production  and  sales  of  synthetic  plastics  and  resin 
materials. 

Production  of  cellulose  plastics  as  a  group  in  1956  amounted  to 
147  million  pounds,    or   1 .  5  percent  more  than  the   145  million 
pounds  reported  for   1955.    Sales  were   145  million  pounds  in  1956, 
compared  with  142  million  pounds  in  1955.    In  volume  of  output, 
cellulose  acetate  and  mixed  ester  plastics  were  by  far  the  most 
important  products  in  the  cellulose  group.    Production  of  these 
plastics  in  1956  totaled  136  million  pounds,    compared  with  134 
millionpounds  in  1955.   The  output  of  cellulose  nitrate  plastics  was 
5.  3  million  pounds  in  1956,    compared  with  4.  9  million  pounds  in 
1955. 


TABLE  30.--Cellulo 


plast ics:    United  States  prorlucti 
[  In  thousands  of  pounds  ] 


anH  -iales,    1956 


Production 


CelluloBe  plastioB,^  total- 


146,972 


144,924 


Cellulose  acetate  and  mixed  esters,  total- 
Sheets,  under  0.003  gage 

Sheets,  0.003  gage  and  over 

All  other  sheets,  rods,  and  tubes 

Molding  and  extrusion  materials 

Nitrocellulose  sheets,  rods,  and  tubes 

Other  cellulose  plastics^ 


136,067 
19,384 
16,656 
7,282 
92,745 
5,254 
5,651 


134,930 
19,627 
16,533 
7,049 
91,721 
4,835 
5,159 


Includes  weight  of  fillers,   plasticizers,   and  extenders. 
^   Includes  data  for  sheets,   rods,   and  tubes,   and  molding  and  extrusion  materials  derived  from  ethyl  cellu- 
lose and  other  cellulosic  materials. 


■ftU.   S.   GOVERNMENT   PRINTING   OFFICE:   1957  O  -444899 


REPORTS  OF  THE  UNITED  STATES  TARIFF  COMMISSION  ON  THE 
OPERATION  OF  THE  TRADE  AGREEMENTS  PROGRAM 


*Operation  of  the  Trade  Agreements  Program,  June  1934  to  April  1948,  Rept. 
No.  160,  2dser.,  1949: 

*Part  I.       Summary 

*Part  II.     History  of  the  Trade  Agreements  Program 

*Part  HI.  Trade-Agreement  Concessions  Granted  by  the  United   States 

•Part  IV.    Trade- Agreement  Concessions  Obtained  by  the  United  States 

*Part  V.      Effects  of  the  Trade  Agreements  Program  on  United  States 
Trade 

Operation  of  the  Trade  Agreements  Program:  Second  Report,  April  1948- 
March  1949,  Rept.  No.  163,  2d  ser.,  1950 

'Operation  of  the  Trade  Agreements  Program:  Third  Report,  April  1949- 
June  1950,  Rept.  No.  172,  2d  ser.,  1951 

'Operation  of  the  Trade  Agreements  Program:   Fourth  Report,  July  1950- 
June  1951,  Rept.  No.  174,  2d  ser.,  1952 

Operation   of  the  Trade  Agreements   Program:   Fifth   Report,  July   1951- 
June  1952,  Rept.  No.  191,  2d  ser.,  1954 

'Operation  of  the  Trade  Agreements  Program:   Sixth   Report,   July  1952- 
June  1953,  Rept.  No.  193,  2d  ser.,  1954 

Operation  of  the  Trade  Agreements  Program:  Seventh  Report,  July  195^ 
June  1954,  Rept.  No.  195,  2d  ser.,  1955 

Operation  of  the  Trade  Agreements  Program:  Eighth  Report,  July  1954- 
June  1955,  Rept.  No.  197,  2d  ser.,  1956,  550 

tOperation  of  the  Trade  Agreements  Program:  Ninth  Report,  July  1955- 
June  1956,  Rept.  No.  199,  2d  ser.,  1957 


NOTE.^The  reports  preceded  by  an  asterisk  (*)  are  out  of  print;  the  report  preceded  by  a 
dagger  (f)  is  in  press  and  'will  be  available  shortly.  The  other  report  listed  may  be  purchased 
from  the  Superintendent  of  Documents,  U.  S.  Government  Printing  Office,  Washington  25, 
D.  C.  See  inside  front  cover  for  other  reports.  All  U.  S.  Tariff  Commission  reports  reproduced 
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