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Full text of "Synthetic organic chemicals"

Given By 
n. If?. StTTPT. OFr>0aTMF,NTS 



UNITED STATES TARIFF COMMISSION 

SYNTHETIC 
ORGANIC CHEMICALS 

United States Production 
and Sales, 1963 



Supenntfcnd(.-nt of !),,. 



TC Publication 143 



':8-iyc4 




RECENT REPORTS OF THE UNITED STATES TARIFF COMMISSION ON SYNTHETIC 

ORGANIC CHEMICALS 

*Synthetic Organic Chemicals, United States Production and Sales, 1958 (Rept. No. 205, 2d ser., 

1959) 
•Synthetic Organic Chemicals, United States Production and Sales, 1959 (Rept. No. 206, 2d ser., 

1960) 
Synthetic Organic Chemicals, United States Production and Sales, 1960 (TC Publication 34, 

1961), $1.25 

Synthetic Organic Chemicals, United States Production and Sales, 1961 (TC Publication 72, 

1962), $1.25 
Synthetic Organic Chemicals, United States Production and Sales, 1962 (TC Publication 114, 

1963), $1.50 



NOTE. — The reports preceded by an asterisk (*) are out of print. The other reports listed may be purchased 
from the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C., 20402. See inside 
back cover for additional reports. All U.S. Tariff Commission reports reproduced by the Government Printing 
Office may be consulted in the official depository libraries throughout the United States. 



UNITED STATES TARIFF COMMISSION 



SYNTHETIC 
ORGANIC CHEMICALS 

United States Production 
and Sales, 1963 



UNDER THE PROVISIONS OF 
SECTION 332 OF THE TARIFF 
ACT OF 1930, AS AMENDED 



U.S. GOVERNMENT PRINTING OFFICE 
WASHINGTON : 1964 



TC Publication 143 



UNITED STATES TARIFF COMMISSION 

Ben Dorfman, Chairman 

Dan H. Fenn, Jr., I ice Chairman 

Joseph E. Talbot 

Glenn W. Sutton 

James W. Culliton 

Donn N. Bent, Secretary 



Address all communications 

UNITED STATES TARIFF COMMISSION 

Washington, D.C. 20436 



For sale liy the Siu)erintendent of Documents, U.S. Governineiit Printing OflBce 
Washington, D.C, 2(H02 - Price $1.50 



CONTENTS 

Page 



Introduction- 
Summary 



PART I. PRODUCTION AND SALES OF TARS, TAR CRUDES, AND CRUDES 
DERIVED FROM PETROLEUM AND NATURAL GAS 

Tars -- - - - 1 

Tar crudes 2 

Crude products from petroleum and natural gas for chemical conversion 4 

PART II. PRODUCTION AND SALES OF INTERMEDIATES AND FINISHED 
SYNTHETIC ORGANIC CHEMICALS, BY GROUPS 

General "^ 

Cyclic inte rmediates 10 

Dyes - - 14 

Synthetic organic pigments 26 

Medicinal chennicals 31 

Flavor and perfume materials 36 

Plastics and resin materials 38 

Rubber -processing chemicals 42 

Elastomers (synthetic rubbers) -i 3 

Plasticizers -14 

Surface -active agents 46 

Pesticides and other organic agricultural chemicals 52 

Miscellaneous synthetic organic chemicals 53 

PART III. ALPHABETICAL LIST OF INDIVIDUAL PRODUCTS, BY GROUPS, 
AND NAMES OF MANUFACTURERS 

Tar crude s 61 

Crude products from petroleum and natural gas for chemical conversion 62 

Cyclic intermediates 64 

Dyes 91 

Synthetic organic pigments 116 

Medicinal chemicals 120 

Flavor and perfume materials 13" 

Plastics and resin materials 1^13 

Rubber-processing chemicals 147 

Elastomers (synthetic rubbers) 151 

Plasticizers 152 

Surface-active agents 155 

Pesticides and other organic agricultural chemicals 170 

Miscellaneous synthetic organic chemicals 176 

Directory of manufacturers 205 

APPENDIXES 

A. U.S. imports of coal-tar intermediates and finished coal-tar products 225 

B. Glossary of synonymous names of cyclic intermediates 226 

C. Cross-reference list of Colour Index and common names of synthetic organic pigments -- 244 



Introduction 

This is the forty-seventhannual report of the U. S. Tariff Commission on domestic production 
and sales of synthetic organic chemicals and the raw materials from which they are made. The 
report presents statistics for 1963 on production and sales of crude organic chemicals derived 
from coal, natural gas, and petroleum; of intermediates; and of finished synthetic organic chemi- 
cal products. The finished products are grouped according to their principal use--dyes, synthetic 
organic pigments, medicinal chemicals, flavor and perfume materials, plastics and resin ma- 
terials, rubber-processing chemicals, elastomers, plasticizers, surface -active agents, pesti- 
cides and other organic agricultural chemicals, and miscellaneous chemicals. The use classifica- 
tions of finished synthetic organic chemicals are based principally on the manufacturers' annual 
reports to the Tariff Commission; other sources include trade associations, the chemical litera- 
ture, chemical dictionaries, encyclopedias, and consultants in the chemical industry. With a few 
exceptions, the report does not cover organic chemicals (such as wood-distillation products, 
essential oils, and naval stores) that are derived from natural (vegetable) sources by simple 
extraction or distillation. The Commission has compiled the statistics given in this report 
from information supplied by the 783 primary manufacturers listed in part III. 

The first section of the report includes the statistics on all products and groups of products 
which conform to the general rules of publishability. The second section lists all the chemicals 
and chemical products on which data were reported and identifies the manufacturers of each. 
Each reporting company has been assigned an identification symbol consisting of a combination 
of not more than three capital letters, selected in most instances with the approval of the manu- 
facturer, and usually bearing some relationship to the company name. The identification synn- 
bols are permanent and, except for such changes as may be necessary, will be used in all future 
reports in this series. Like the five immediately preceding reports, this report includes data on 
only those individual chemicals for which the volume of production or sales in the year covered 
exceeded 1,000 pounds or for which the value of sales exceeded $1,000. Data for chemicals 
produced in Puerto Rico are included in the report, but no data were reported from Alaska or Hawaii. 

The raw materials referred to in this report are obtained from coal, crude petroleum, natural 
gas, and certain other natural materials, such as vegetable oils, fats, rosin, and grains. Crude 
organic chemicals are derived from coal by thermal decomposition, from petroleum and natural 
gas by catalytic cracking and by distillation or absorption, and fronn other natural sources by 
fermentation. Production of these crude organic chemicals is the first step in the manufacture of 
synthetic organic chemicals. From these crudes, intermediates are obtained by synthesis or re- 
fining; most of the intermediates are then converted into finished chemical products, such as 
medicinal chemicals, plastics and resin nnaterials, and dyes. More than half of the total pro- 
duction of intermediates is not sold directly to the ultimate consumer, but is used by the pro- 
ducing companies themselves in their manufacturing processes. The statistics given in this re- 
port include data for all known domestic producers and are therefore virtually complete. 

In this report, the statistics on production of the individual chemicals reported by manufac- 
turers include the total output of the companies' plants, i.e., the quantities produced for con- 
sumption within the producing plants, as well as the quantities produced for sale. The quantities 
reported as produced, therefore, generally exceed the quantities reported as sold. Some of these 
differences, however, are attributable to changes in inventories. As specified in the reporting 
instructions that the Commission sends to manufacturers, and as used in this report, production 
and sales (unless otherwise specifically indicated) are defined as follows: 

Production is the total quantity of a commodity made available by original manufacture only. It is 
the sum (expressed in terms of 100-percent active ingredient unless otherwise specified) of the 
quantities of a commodity- - 

(1) Produced, separated, and consumed in the same plant or establishment (a commodity 

is considered to be separated when it is isolated from the reaction system and/or 
when it is weighed, analyzed, or otherwise measured). Byproducts and coproducts 
not classified as waste materials are also included; 

(2) Produced and transferred to other plants or establishments of the same firm; 

(3) Produced and sold to other firms (including production for others under toll agree- 

ments '); and 

(4) Produced and held in stock. 



' A toll agreement is an agreement between tvo firms, under which one firm furnishes the raw materials and pays the processing costs 
and the other firm prepares the finished product and returns it to the first firm. 



vi INTRODUCTION 

Production excludes -- 

(1) Purification of a commodity unless specifically requested in the reporting instruc- 

tions; 

(2) Intermediate products that are fornned in the manufacturing process but are not iso- 

lated from the reaction system-- that is, not weighed, analyzed, or otherwise 
measured; and 

(3) Materials that are used in the process but are recovered for reuse or sale; and 

waste products that have no economic significance. 

Sales are defined as actual sales of commodities by original manufacturers only. Sales include-- 

(1) Shipments of commodities for domestic use and for export, or segregation in a 

warehouse when title has passed to the purchaser in a bona fide sale; 

(2) Shipments of a commodity produced ftyoMer* under toll agreements; and 

(3) Shipments to subsidiary or affiliated companies. 

Sales exclude -- 

(1) All intracompany transfers within a corporate entity; 

(2) All sales of purchased commodities; and 

(3) All shipments of a commodity produced /or ot/iers under toll agreements. 

The value of a sale is the net selling value, f. o. b. plant or warehouse, or delivered value, 
whichever represents the normal industry practice. 

Data on the chemicals covered in this report are usually given in terms of undiluted materials. 
Products of 95 percent or more purity are considered to be 100 percent pure. The principal ex- 
ceptions are the statistics on dyes and a few solvents, which are reported in terms of commercial 
concentrations; the statistics on certain plastics and resins, which are reported on a dry basis; 
and the data on sales of antibiotics, which are reported on the basis of specific conditions men- 
tioned in the section on medicinal chemicals. The report specifically notes those products for 
which the statistics are reported in terms of connmercial concentrations. 

The average unit values of sales for groups of products shown in the tables accompanying 
this report are weighted averages for products which vary widely in unit values and in the quan- 
tities sold. 

In this report, statistics are presented in as great detail as is possible without revealing 
the operations of individual producers. Statistics for an individual chemical or group of chennicals 
are not given if there are fewer than three producers. Moreover, even when there are three or 
more producers, statistics are not given if there is any possibility that their publication would 
violate the statutory provisions relating to unlawful disclosure of information accepted in confi- 
dence by the Commission.' 

Statistics on tars and tar crudes include data furnished directly to the Tariff Commission by 
distillers of coal tar, water-gas tar, and oil-gas tar, and data furnished to the Division of Bitu- 
minous Coal, U.S. Bureau of Mines, by coke-oven operators. 



«Sec. 5, U.S.C. 139b and sec. 18, U.S.C. 1905. 



Summary 

Combined production of all synthetic organic chemicals, tars, tar crudes, and crude products 
from petroleum and natural gas in 1963 was 120,928 million pounds--an increase of 7. 5 percent 
over the output in 1962 (see table 1). Sales of these materials in 1963, which totaled 63,898 million 
pounds, valued at $8,517 million, were 0. 8 percent larger than in 1962 in terms of quantity and 
2.4 percent larger in terms of value. These figures include data on production and sales of chem- 
icals measured at several successive steps in the manufacturing process, and therefore they nec- 
essarily contain some duplication. 

In 1963, production of all synthetic organic chemicals, including cyclic intermediates and 
finished chemical products, totaled 70,343 million pounds, or 9. 6 percent more than the output in 
1962. Production of plastics and resin materials (8, 968 million pounds) was 12. 9 percent larger 
in 1963 than in 1962; that of cyclic intermediates (12, 768 million pounds) was 12. percent larger; 
that of miscellaneous chemicals (41, 153 million pounds) was 9. 5 percent larger; and that of medic- 
inal chemicals (139 million pounds) was 9. 2 percent larger. 

The output of most of the other groups of synthetic organic chemicals also increased in 1963 
compared with 1962. Production of dyes (204 million pounds) was 8.0 percent greater; that of 
plasticizers (835 million pounds) was 6. 9 percent greater; that of synthetic organic pigments (39 
million pounds) was 6.0 percent greater; that of pesticides and other organic agricultural chemicals 
(763 million pounds) was 4.6 percent greater; that of rubber-processing chemicals (234 million 
pounds) was 2. 3 percent greater; and that of surface-active agents (1, 981 million pounds) was 1.6 
percent greater. The output of flavor and perfume materials in 1963 (74 million pounds) was 3. 3 
percent below the output of 76 million pounds in 1962. 



TABLE 1.-- Synthetic organic chemicals and their raw materials: U.S. production and sales, 1962 and 1963 



decrease 
(-), 1963 
over 1962^ 



Quantity 



decrease 
(-), 1963 
over 1962-^ 



decrease 
(-), 1963 
over 1962 •■■ 



Grand total 

Tar 

Tar crudes 

Crude products from petroleum and 
natural gas 

Synthetic organic chemicals, total- 
Intermediates 

E^yes 

Synthetic organic pigments 

Medicinal chemicals 

Flavor and perfume materials 

Plastics and resin materials 

Rubber-processing chemicals 

Elastoners (synthetic rubbers) 

Plasticizers 

Surface-active agents 

Pesticides and other organic 

agricultural chemicals 

Miscellaneous chemicals 



Million 
pounds 

1:12, ^78 



Uillion 
pounds 
120,928 



Percent 
7.5 



Uillion 

pounds 

63,416 



Millior. 
pounds 
63,898 



dollars 
8,313 



dollars 
8,517 



6,694 
8,654 



32,960 



64,170 



6,719 
8,745 



35,121 
70,343 



1.1 
6.6 
9.6 



3,181 
5,255 



20,352 
34,628 



2,907 
5,485 



18,460 
37,046 



-8.6 
4.4 



38 
130 



7,490 



7,793 



11,400 

139 

37 

127 

76 

7,942 

228 

3,134 

781 

1,949 

730 
37,577 



12,768 

204 

39 

139 

74 

8,968 

234 

3,185 

835 

1,981 

763 
41,153 



12.0 
8.0 
6.0 
9.2 
-3.3 
12.9 
2.3 
1.6 
6.9 
1.6 

4.6 
9.5 



4,572 

178 
32 

104 

63 

7,116 

172 
2,730 

666 
1,758 

634 
16,603 



5,429 

187 
34 

114 

67 

7,516 

177 
2,836 

750 
1,790 

651 
17,495 



18.7 

5.0 



9.9 
5.6 



12.6 
1.8 



2.8 
5.4 



632 

227 

74 

601 

76 

1,884 

115 

774 

168 

317 

346 
2,276 



643 
240 

80 
639 

77 
2,003 
119 
767 
168 
325 

369 
2,363 



-17.9 
-8.2 



7.1 
6.4 
1.9 
6.3 
3.7 
-1.0 



Percentages calculated from figures rounded to thousands. 



I 



PART I. PRODUCTION AND SALES OF TARS, TAR CRUDES, 
AND CRUDES DERIVED FROM PETROLEUM AND NATURAL GAS 

Tars 

Coal tar is produced chiefly by the steel industry as a byproduct of the manufacture of coke; 
water-gas tar and oil-gas tar are produced by the fuel-gas industry. Production of coal tar, 
therefore, depends on the demand for steel; production of water-gas and oil-gas tar reflects the 
consumption of manufactured gas for industrial and household use. Water-gas and oil-gas tars 
have properties intermediate between those of petroleum asphalts and coal tars. Petroleum as- 
phalts are not usually considered to be raw materials for chemicals. 

The quantity of tar produced in the United States from coal in 1963 was 672 million gallons, 
or 3. 3 percent nnore than the 650 million gallons produced in 1 962. U. S. production of water- 
gas and oil-gas tar was not reported to the Commission for 1963; production of these tars in 
1962 amounted to 19 million gallons (see table 2). 

Total consumption of tar in 1963 amounted to 692 million gallons, of which 573 million gal- 
lons was consumed by distillation, 91 million gallons as fuel, and 27 million gallons in miscel- 
laneous uses. 



TABLE 2. --Tar.- U.S. production and consumption, 1962 and 1963 



[ in thousands of gallons . Leaders are used where the reported data are accepted in confidence and may not be 
published or where no data were reported ] 



PRODUCTION 
Total 

Water-gas and oil-gas tar^ 

Coal tar from coke-oven byproduct plants^ 

CONSUMPTION 
Total 

Tar consumed by distillation, total 

Coal tar distilled or topped by coke-oven operators^ 

Coal tar, water-gas and oil-gas tar distilled by producers and tar distillers-' — 

Tar consumed chiefly as fuel^ 

Tar consumed otherwise than by distillation or as fuel, total 

Coal tar consiomed at coke-oven plants for roads and upkeep^ 

Coal tar, water-gas tar, and oil-gas tar processed at tar refineries, crude tar 
consumed for upkeep at such refineries, wid tar consimied in making gas and in 
special-purpose tar blends* 



669,398 



19,286 
650,112 



676,531 



609,639 



306,137 
303,502 



<;6,373 
20,519 



19,978 



671,876 



671,876 



691,509 



573,096 



289,569 
283,527 



91,313 
27,100 



"55? 



26,5^2 



Reported to the American Gas Association for 1962. 
' Reported to the U.S. Bureau of Mines. 

^ Reported to U.S. Tariff Commission. Represents tar purchased from companies operating coke ovens and 
retort plants and distilled by companies operating tar-distillation plants. 

' Water-gas tar and oil-gas tar reported to the American Gas Association for 1962. 
' Excludes data for water-gas tar and oil-gas tar. 



2 SYNTHETIC ORGANIC CHEMICALS, 1963 

Tar Crudes 

Tar crudes are obtained from coke -oven gas and by distilling coal tar, water-gas tar, and oil - 
gas tar. The most innportant tar crudes are benzene, toluene, xylene, naphthalene, and creosote oil. 
Some of the products produced from coal tar are identical with those produced from petroleum and 
natural gas. Data for materials derived fronn these latter sources are included, for the most part, 
in or with the statistics for materials derived from coal tar, which are shown in tables 3 and 4 A. ■"■ 

Total domestic production of industrial and specification grades of benzene in 1963 amounted 
to 647 million gaUons--18.5 percent nnore than the 546 million gallons reported for 1962. These 
totals include data for benzene produced from tars, light oil, and petroleum. Sales of benzene 
by coke-oven operators and petroleum operators in 1963 amounted to 421 million gallons, valued 
at $96 million, compared with 405 million gallons, valued at $99 million, in 1962. In 1963 the 
output of toluene from all sources (including material produced for use in blending in aviation 
fuel) amounted to 406 million gallons--12. 5 percent more than the 361 million gallons reported 
for 1962. Sales of toluene in 1963 were 207 million gallons, valued at $35 million, compared 
with 207 million gallons, valued at $40 million in 1962. The output of xylene in 1963 (including 
that produced for blending in motor fuels) was 335 million gallons, compared with 354 million 
gallons in 1962. About 98 percent of the xylene produced in 1963 was obtained from petroleum 
sources. 

Production of crude naphthalene in 1963 (including 288 million pounds of petroleum-derived 
naphthalene) amounted to 627 million pounds, compared with 591 million pounds in 1962. Sales 
of coal-tar-derived naphthalene^ in 1963 were 209 million pounds, valued at $7 nnillion, com- 
pared with 262 million pounds, valued at $12 million, in 1962. In 1963 the output of creosote oil 

TABLE 3. — Tar and tar crudes: Summary of U.S. production of specified products, average 1950-54, 

annual 1962 and 1963 

[Leaders are used where the reported data are accepted in confidence and may not be published 
or where no data were reported] 



Unit 

of 

quantity 



Average 
1950-5^; 



Increase, or decrease (-) 



1963 over 
1950-5A. 



1963 over 
1962 



Tar^ 

Benzene : ^ 

Tar distillers-' 

Coke-oven operators 

Petroleum operators 

Total 

Toluene : 

Tar distillers 

Coke-oven operators 

Petroleum operators 

Total 

Xylenes, mixed: 

Tar distillers 

Coke-oven operators 

Petroleum operators 

Total- -- 

Naphthalene, crude: 

Solidifying at less than 79° Cj — 
Petroleum naphthalene, all grades - 

Total - 



1,000 gal— 

1,000 gal— 
1,000 gal— 
1,000 gal— 
1,000 gal— 

1,000 gal— 
1,000 gal— 
1,000 gal— 
1,000 gal— 

1,000 gal— 
1,000 gal— 
1,000 gal— 
1,000 gal- 

1,000 lb— 
1,000 lb— 
1,000 lb— 



876,070 

41,389 
163,356 
46,635 



251,380 

7,497 

32,981 

3,725 



669,398 

14,039 
114,227 
418,131 



121,203 

1,373 

9,028 

78,188 



546,397 

2,981 

27,231 

330,709 



671,876 

9,098 
112,427 
525,889 



-78.0 
-31.2 

1,027.7 



647,414 

3,204 

25,794 

377,205 



0.4 

-35.2 
-1.6 
25.8 
18.5 



-57.3 
-21.8 
367.3 



88,589 
307,537 



360,921 



7,578 
•^ 346,593 



406,203 

509 

6,888 

327,460 



7.5 



14.1 
12.5 



-62.9 
-23.7 
318.8 



424,205 
167,089 



Creosote oil (Dead oil)'' 1,000 gal- 



307, 537 
109,946 



591,294 
82,261 



334, 857 



338,715 
288,240 



626,955 
87,894 



-20.2 

72.5 

6.0 



6.8 



■'- Includes data for oil-gas, water-gas, and gas-retort tar reported to the American Gas Association for 1950-54 
and for 1962 only, and for coal tar reported to the Division of Bituminous Coal, U.S. Bureau of Mines. 

^ Includes data for motor-grade benzene in 1950-54. Separate statistics on production of motor-grade benzene have 
not been published since 1954. Production in recent years, if any, has been negligible. 

^ Includes data for benzene produced from imported crude light oil. 

* Includes data for material produced for use in blending motor fuels. Statistics are not comparable with monthly 
figures, which included seme o-xylene now shcvn in table 7A. 

' Figures include production by tar distillers and coke-oven operators and represent combined data for the com- 
mercial grades of naphthalene to avoid disclosure of the operations of individual companies. Because of conversion 
between grades, the figures may include some duplication. 

* Includes data for creosote oil produced by tar distillers and coke-oven operators and used only in wood pre- 
serving. Data for production of creosote oil in coal-tar solution have been excluded because the figures for 1950-54 
are not comparable with the figures for 1962 and 1963. Production figures for 1950-54 are for the distillate sold or 
consumed as such; and, for 1962 and 1963, the production of the distillate is on a lOO-percent-creosote basis. 



■"■ See also table 4B, pt. m, which hsts these products alphabetically and identifies the manufacturers. 
2 For sales of peDoleiun-derived naphthalene, see table 5A. 



TAR CRUDES : 

TABLE 4A.-- Tar crudes: U.S. production and sales, 1963 

[Listed below are all tar crudes for which any reported data on production or sales may be published. (Leaders are 
used where the reported data are accepted in confidence and may not be published or where no data were reported.) 
Table "iB in pt. Ill lists separately all products for which data on production or sales were reported and iden- 
tifies the manufacturers reporting to the U.S. Tariff Commission] 



Quantity 



Unit 
valued- 



Crude light oil: Coke-oven operators 

Intermediate light oil: Coke-oven operators 

Light-oil distillates: 

Benzene, specification and industrial grades, total- 
Tar distillers^ ^-- 

Coke-oven operators 

Petroleum operators 

Toluene, all grades, total-' 

Tar distillers 

Coke-oven operators 

Petroleum operators 

Xylenes, mixed, total^ 

Tar distillers 

Coke-oven operators 

Petroleum operators 

Solvent naphtha, total 

Tar distillers 

Coke-oven operators 

Other light-oil distillates, total 

Tar distillers 

Coke-oven operators 

Naphthalene, crude (tar distillers and coke-oven 

operators), total* 

Solidifying at-- 

Less than V^i" C 

1^° C. to less than 79° C 

Crude tar-acid oils: 

Tar distillers 

Coke-oven operators 

Creosote oil (Dead oil) (tar distillers and coke-oven 

operators) (lOOjt creosote basis), total' 

Distillate as such (IOO56 creosote basis) 

Creosote content of coal-tar solution (lOO^t 

creosote basis) 

All other distillate products^ 

Tar, road 

Tar (crude and refined) for other lises' 

Pitch of tar: 

Hard (water softening point above 160° F. ) 

Other* - - 



1,000 gal- 
1,000 gal- 

1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,0C0 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,00c gal- 



1,000 lb— 



1,000 lb— 
1,000 lb— 



1,000 gal— 
1,000 gal— 



1,000 gal— 
1,000 gal— 

1,000 gal— 

1,000 gal— 
1,000 gal— 
1,000 gal— 

1,000 tons- 
1,000 tons- 



218,166 

■4,8A7 

647,<;i<i 

9,098 

112, «7 

525,889 

'i06,203 

3,204 

25,794 

377,205 

334,857 

509 

6,888 

327,460 

9,090 

5,529 

3,561 

11,444 

4,105 

7,339 



338,715 



32,610 
3,378 



110,200 
310,671 



24,826 

182,332 

130,622 

413 

7,124 

123,085 

7,714 

4,355 

3,359 

9,059 

3,570 

5,489 



209,097 



45,914 
292,801 



526 

25,170 



98,110 
87,894 



47,544 
161,553 



532 
26,183 



93,443 
83,556 



10,216 

31,793 
58,042 
18,228 

848 
940 



9,887 

19,298 
56,766 
17,743 

590 
465 



1,000 
dollars 
3,633 

374 



24,192 

72,088 



4,849 

30,414 

24,663 

129 

1,694 

22,840 

1,587 

874 

713 

1,213 

481 

732 



7,130 



1,102 
6,028 



171 
4,804 



19,681 



16,614 

3,067 

3,417 
8,303 
3,352 

23,521 
15,763 



39.87 
33.90 



^ Unit value per gallon, pound, or ton, as specified. 

2 Includes data for benzene produced from imported crude light oil. 

-^ Includes data for material produced for use in blending motor fuels. 

* Statistics represent combined data for the commercial grades of naphthalene. Because of conversion of naphtha- 
lene from one grade to another, the figures may include some duplication. 

' Statistics include data only for creosote oil sold for, or used in, wood preserving. In 1963, production of 
creosote in coal-tar solution (lOO^t solution basis) amounted to 15,792 thousand gallons; sales were 16,050 thousand 
gallons, valued at 3,067 thousand dollars, with a unit value of $0.19 per gallon. 

* Includes data for pyridine crude bases in addition to those for crude cresylic acid and neutral oils produced 
by tar distillers, and for crude sodium phenolate produced by coke-oven operators. 

^ Includes data for tar used for paint, pipe covering, saturating, and other uses. 

Includes soft and medium pitch of tar (water softening points less than 110° F., and 110° F. to 160° F. ASTM 
D61-24), pitch of tar coke, and pitch emulsion. 

Note. — Statistics for materials produced in coke and gas-retort ovens are compiled by the Division of Bituminous 
Coal, U.S. Bureau of Mines, Department of the Interior. Statistics for materials produced in tar and petroleum 
refineries are compiled by the U.S. Tariff Commission. 



4 SYNTHETIC ORGANIC CHEMICALS, 1963 

(100-percent creosote basis), used principally in wood preserving, was 98 million gallons, com- 
pared with 91 million gallons in 1962. Production of road tar in 1963 was 58 naillion gallons, 
compared with 62 million gallons in 1962. 

Some of the products included in the statistics in table 4A are derived fronn other products 
for which data are also included in the table. The statistics, therefore, involve considerable 
duplication, and for this reason no group totals or grand totals are given. After duplication has 
been eliminated insofar as possible, it is estimated that the net value of the output of these prod- 
ucts and of tar burned as fuel was $406 million in 1963, compared with $423 million in 1962 
and $440 million in 1961. 

Crude Products From Petroleum and Natural Gas for Chemical Conversion 

Crude products that are derived from petroleunn and natural gas are related to the inter- 
mediates and finished products made from such crudes in much the same way that crude products 
derived from the distillation of coal tar are related to their intermediates and finished products. 
Many of the crude products derived from petroleum are identical with those derived from coal 
tar (e.g., benzene, toluene, and xylene). Considerable duplication exists in the statistics on the 
production and sales of petroleum crudes because some of these crude chemicals are converted 
to other crude products derived from petroleum and because data on some production and sales 
are reported at successive stages in the conversion processes (see table 5A^ ). Notwithstanding 
these duplications, the statistics are sufficiently accurate to indicate trends in the industry and 
to serve as a basis for general comparison. Many of the crude products for which data are in- 
cluded in the statistics may be used either as fuel or as basic materials from which to derive 
other chemicals, depending on prevailing economic conditions. In this report, every effort has 
been made to exclude data on materials that are used as fuel. However, data are included on 

TABLE 5A.-- Crude products from petroleum and natural gas for chemical conversion: U.S. production 

and sales, 1963 

(Listed below are the crude products from petroleum and natural gas for chemical conversion for which any reported 
data on production or sales may be published. (leaders are used where the reported data are accepted in confidence 
and may not be published or where no data were reported.) Table 5B in pt. Ill lists separately all products from 
petroleum and natural gas for chemical conversion for which data on production or sales were reported and iden- 
tifies the manufacturer of each] 



Sales 



Quantity 



Value Unit value-"- 



Grand total 

AROMATICS AND NAPHTHENES^ 

Total - -- 

Alkyl aromatics, distillates, and solvents 

Benzene (1° and 2"), total 

Benzene, 1° 

Benzene, 2° 

Cresylic acid, crude 

Naphthalene, all grades 

Naphthenic acids, total 

Acid No. 150-199 

All other 

Toluene, all grades, total 

Nitration grade, 1° 

Pure commercial grade, 2° 

All other^ 

Xylenes, mixed, total 

3° - 

5° 

All other^ 

All other aromatics and naphthenes* 

See footnotes at end of table. 

3 See also uble 58, pt. Ill, which lisu ihese producu alphabetically 



1,000 
pounds 
35,120,735 



11,292,008 



1,875,909 
3,881,061 



3,091,652 
789, 'i09 



31,4^1 
288,240 



25,335 



4,535 
20,800 



2,742,280 



1,711,445 
115,666 
915,169 

2,360,986 



541,161 

565,920 

1,253,905 

86,756 



1,000 

pounds 

18,460,167 



6,845,885 



2,024,373 
2,292,752 



14,031 
232,783 



13,596 



3,920 
9,676 



1,325,553 



1,032,9U 
292,639 
887,442 



198,455 
244,383 
444,604 

55,355 



1,000 
dollars 
573, 1A4 



163,575 



23,271 
72,088 



401 
11,806 



1,228 



355 
873 



30,414 



24,697 
5,717 
22,840 



5,654 

5,610 

11,576 

1,527 



Per 

pound 

$0,031 



.024 
.011 
.031 



.028 
.051 



.090 
.090 
.090 



.023 
T02Z" 



.026 
7023" 
.023 
.026 



and identifies the manufacturers. 



CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS 



TABLE 5A.--Crude products from petroleum and natural gas for chemical conversion: U.S. production 

and sales, 1963- -Continued 



Qiiantity 



Unit 
value ■"■ 



ALIPHATIC HYDROCAHBONS 



l.nnn 

pounds 
23,828,727 



i.ono 

pounds 
ll,61<i,282 



i.ono 

dollars 
409,569 



pound 

$0.035 



Cj hydrocarbons, total- 



8,886,184 



2,549,555 



104,120 



Acetylene 

Ethane 

Ethylene — 



C} hydrocarbons, total- 



355,642 
1,012,990 
7,517,552 

6,257,833 



14,431 

326,865 

2,208,259 

4,045,022 



1,485 

2,925 

99,710 

61,890 



Propane 

Propane-propylene mixture- 
Propylene 



C4 hydrocarbons, total 

1,3-Butadiene, grade for rubbers (elastomers) 



3,045,598 

502,247 

2,709,988 

6,324,923 



2,488,749 
1,556,273 
3,762,385 



24,424 
37,466 
198,932 



Butadiene and butylene fractions- 

n-Butane 

1-Butene 

1-Butene and 2-butene mixture* 

Isobutane 

Isobutylene 

All other'' 



C5 hydrocarbons, total - 



2,324,362 

504,447 

1,465,596 

94^,764 
618,015 
212,799 
254,940 

521,049 



1,362,401 

817,575 
13,222 
885,940 
284,368 
146,090 
252,789 

85,536 



146,071 

9,408 
906 
27,892 
3,528 
5,601 
5,526 

3,844 



.103 
.009 
.045 

.015 

.010 

.024 
.053 
.107 

.012 
.068 
.031 
.012 
.038 
.022 



Isoprene (2-methyl-l,3-butadiene)- 
All other^ 



All other aliphatic hydrocarbons and derivatives, total- - 

Diisobutylene (Diisobutene) 

n-Heptane 

Heptenes, mixed 

Hexane 

Nonene (Tripropylene) 

Polybutene' 

Hydrocarbon derivatives ^° 



94,739 
426,310 

1,838,738 



1,171,784 



40,783 



Tetrapropylene - 
All other^^ 



29,105 
92,690 
158,427 
163,570 
144,101 
146,436 
15,863 
400,305 
688,241 



27,156 

70,923 

121,172 
122,921 
14,347 
335,198 
480,067 



1,735 
2,397 



3,608 
6,882 



10,589 
10,884 



.035 
.064 



.030 
.056 
.327 
.032 
.023 



^ Calculated from ro\mded figures. 

^ The chemical raw materials designated as aromatics are in some cases identical with those obtained from the dis- 
tillation of coal tar. However, the statistics given in the table above relate only to such materials as are derived 
from petroleum and natural gas. Statistics on aromatic chemicals from all sources are given in table 4A "Tar Crudes." 

^ Includes toluene and xylene xised as solvents, as well as that which is blended in aviation and motor gasolines, 

* Includes data for 90-percent benzene, sodium cresylate, sodium carbolate and phenate, and miscellaneous cyclic 
hydrocarbons. 

^ Production figures on acetylene from calcium carbide for chemical synthesis are collected by the U.S. Bureau of 
the Census. 

* The statistics represent principally the butene content of crude refinery gases from which butadiene is manu- 
factured. 

'' Includes data for 1-butene, 2-butene, mixed butylenes, and mixed olefins. 

* Includes data for pentanes, pentenes, and Cj hydrocarbon mixtures. 
' Includes compounds having a molecular weight of 3,000 or less. 

10 Includes data for di-tert-butyldisulfide and miscellaneous mercaptans. 

11 Includes data for alpha olefins, methane, octanes, 1-dodecene, eicosane, and hydrocarbon mixtures. 

toluene and xylene which are not used directly as fuel but in blending aviation and motor-grade 
gasolines. 

The output of crude products derived from petroleum and natural gas as a group amounted to 
35, 121 million pounds in 1963, or 6.6 percent more than the 32,960 million pounds reported for 
1962. The larger output in 1963 is accounted for chiefly by increased production of benzene, 
naphthalene, toluene, ethylene, propylene, and 1, 3-butadiene. Sales of crude chemicals from 
petroleum in 1963 were 18,460 million pounds, valued at $573 million, compared with 20,352 mil- 
lion pounds, valued at $656 million, in 1962. 

The output of all aromatic and naphthenic products amounted to 11, 292 million pounds in 1963, 
compared with 10, 152 million pounds in 1962. Sales in 1963, which amounted to 6, 846 million 
pounds, valued at $164 million, were 534 million pounds larger, and valued at $2 million less, 
than those in 1962. Naphthalene was produced from petroleum sources in substantially greater 
quantities in 1963 than in 1962. The output of 1° and 2^ benzene from petroleum amoxinted to 



6 SYNTHETIC ORGANIC CHEMICALS 1963 

3,881 million pounds in 1963--25. 8 percent more than the 3,086 million pounds produced in 1962. 
The output of toluene in 1963 was 2, 742 million pound S--14. 1 percent more than the 2, 404 million 
pounds produced in 1962. Production of xylene was 2, 361 million pounds in 1963, compared with 
2,499 million pounds in 1962. These figures include toluene and xylene used in blends in aviation 
and motor-grade gasolines. The output of naphthenic acids amounted to 25 million pounds in 1963, 
about the same as that produced in 1962. Production of cresylic acid in 1963--31 million pounds-- 
was 4. 5 percent more than in 1962. 

Production of all aliphatic hydrocarbons and derivatives from petroleum and natural gas was 
23, 829 million pounds in 1963, compared with 22, 808 million pounds in 1962. Sales of these prod- 
ucts were 11, 614 million pounds, valued at $410 million, in 1963, compared with 14, 040 million 
pounds, valued at $490 million, in 1962. The statistics on production of acetylene (table 5A) in- 
clude only acetylene produced from natural gas and used as a raw material in the production of 
other chemicals. Total production of acetylene for chemical synthesis is reported to the U.S. 
Bureau of the Census. In 1961, the latest year for which statistics were published, production of 
acetylene for chemical synthesis from all sources amounted to 801 million pounds. Production of 
ethylene was 7, 518 million pounds in 1963, or 19. 6 percent more than the 6, 283 million pounds 
produced in 1962. The output of propane and propylene, including mixtures, was 6,258 million 
pounds in 1963--6. 6 percent less than the 6, 700 million pounds produced in 1962. Production of 
1, 3-butadiene, one of the principal ingredients of S-type synthetic rubber, was 2, 324 million 
pounds in 1963, compared with 2, 144 million pounds in 1962. The output of 1, 3-butadiene in 
1963--the largest on record--was 8. 4 percent more than that in 1962. 



PART n. PRODUCTION AND SALES OF INTERMEDIATES AND 
FINISHED SYNTHETIC ORGANIC CHEMICALS, BY GROUPS 

General 

On the basis of their principal uses, the synthetic organic chemicals covered in this report 
are classified either as intermediates or as finished products. Finished products, in turn, are 
grouped as follows: Dyes, synthetic organic pigments, medicinal chemicals, flavor and perfume 
materials, plastics and resin materials, rubber-processing chemicals, elastomers (synthetic 
rubbers), plasticizer s, surface -active agents, pesticides and other organic agricultural chemi- 
cals, and miscellaneous synthetic organic chemicals. Most of these groups are further subdi- 
vided, according to chemical classes, into cyclic and acyclic compounds. As most of the inter- 
mediates are used in the manufacture of finished products, aggregate figures that cover both 
intermediates and finished products necessarily include considerable duplication. 

Total production of synthetic organic chemicals (intermediates and finished products com- 
bined) in 1963 was 70, 343 million pounds, or 9. 6 percent more than the output of 64, 170 million 
pounds reported for 1962 (see table 6). Sales of synthetic organic chennicals in 1963 amounted to 
37,046 million pounds, valued at $7,793 million, compared with 34,628 million pounds, valued 
at $7,490 million, in 1962. Production of all cyclic products (intermediates and finished products 
combined) in I 963 totaled 22, 490 million pounds, or 8. 7 percent more than the 20, 690 million 
pounds produced in 1962. The output of acyclic organic chemicals in 1963 amounted to 47, 853 
million pounds--! 0.0 percent more than the 43, 480 million pounds reported for 1 962. 



TABLE 6. -- Synthetic organic chemicals: Summary of U.S. production and sales of intermediates and finished 
products, average 1957-59, annual 1962 and 1963 

[ Production and sales in thousands of pounds; sales value in thousands of dollars ] 



Organic chemicals, cyclic and acyclic, 
grand total: 

Production 

Sales 

Sales value 

Cyclic, total: 

Production 

Sales 

Sales value 

Acyclic, total: 

Production 

Sales 

Sales value 

1. Intermediates. Cyclic 

Production 

Sales 

Sales value 

2. Dyes, Cyclic 

Production 

Sales 

Sales value 

3. Synthetic Organic Pigments, Cyclic 

Production 

Sales 

Sales value 



Average 
1957-59 



45,598,853 


64,169,916 


70,343,302 


23,7^4,812 


34,628,386 


37,046,363 


5,7"43,7&i 


7,490,218 


7,793,226 


U, 381, 651 


20,689,673 


22,490,017 


8,829,037 


12,253,042 


13,477,603 


2,785,100 


3,472,358 


3,631,620 


31,217,202 


43,480,243 


47,853,285 


1-4,915,775 


22,375,344 


23,568,760 


2,958,664 


4,017,860 


4,161,606 


7,343,167 


11,399,541 


12,768,168 


2,919,264 


4,572,116 


5,428,713 


481,920 


632,249 


642,884 


150,830 


188,904 


204,046 


141,731 


178,031 


186,951 


182,513 


227,231 


239,676 


38,603 


37,156 


39,399 


30,218 


31,602 


33,534 


58,648 


74,313 


79,600 



Increase, or decrease (- 



1963 over 
1957-59 



54.3 
56.0 
35.7 

56.4 
52.6 
30.4 

53.3 

58.0 
40.6 



73.9 
86.0 
33.4 



35.3 

31.9 



2.1 

11.0 



1963 over 
1962 



8.7 
10.0 
4.6 

10.0 
5.3 
3.6 



12.0 
18.7 
1.7 



8.0 
5.0 
5.5 



6.0 
6.1 

7.1 



SYNTHETIC ORGANIC CHEMICALS, 1963 

TABLE 6. — Synthetic organic chemicals.- Summary of U.S. production and sales of intermediates and finished 
products, average 1957-59, annual 1962 and 1963 — Continued 



[Production and sales in thousands of pounds; sales value in thousands of dollars] 



Average 
1957-59 



Increase, or decrease (-) 



1963 over 
1957-59 



^. Medicinal Chemicals 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic : 

Production 

Sales 

Sales value 

5. Flavor and Perfume Materials 
Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 

6. Plastics and Resin Materials 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 

7. Rubber-Processing Chemicals 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 

8. Elastomers (Synthetic Rubbers) 

Cyclic : 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 

9. Plastlcners 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 



70,65A 
5.4, 151 
535,297 

31,592 
28,738 
35,660 



27,312 
22,^6 
33,903 

19,033 
19,958 
21,912 



2,278,862 

1,900,032 

518,501 

2,628,779 

2,«8,853 

864,523 



159,182 
115,704 
74,479 

29,150 
22,127 
14,289 



1,938,732 

1,726,757 

40^,897 

521,811 
509,262 
199,627 



348,210 

297,^23 

83,509 

118,118 
100,984 
38,772 



87,724 
68,228 
567,396 

39,707 
35,399 
33,383 



42,771 
32,049 
47,260 

33,496 
31,399 
28,702 



3,159,236 

2,685,314 

665,679 

4,782,410 
4,430,423 
1,217,962 



195,900 
148,139 
97,363 

32,521 
23,985 
17,055 



2,263,105 

1,907,319 

464,581 

871,290 
823,068 
309,7-45 



570,963 
A86,050 
103,705 

209, 980 
179,885 
64,358 



94,125 

73,606 

605,080 

45,071 
40,314 
33,875 



41,338 
34,671 
51,4A6 

32,430 
32,343 
25,940 



3,489,361 

2,886,387 

736,760 

5,479,112 
4,629,750 
1,266,359 



199,282 
152,835 

101,757 

34,350 
24,367 
16,906 



2,174,183 

1,925,751 

434,474 

1,010,731 
910,544 
332,457 



621,687 
557,979 
103,000 

212,837 
191,771 
65,181 



33.2 
35.9 
13.0 

42.7 
40.3 
-5.0 



51.4 
54.5 
51.7 

70.4 
62.1 
18.4 



108.4 
89.8 
46.5 



25.2 
32.1 
36.6 

17.8 
10.1 
18.3 



93.7 
78.8 
66.5 



78.5 
87.6 
23.3 

80.2 
89.9 
68.1 



GENERAL 



TABLE 6. Synthetic organic chemicals : Summary of U.S. production and sales of intermediates and finished 

products, average 1957-59, annual 2962 and 1963 — Continued 

[ Production and sales in thousands of pounds; sales value in thousands of dollars] 



Average 
1957-59 



Increase, or decrease (-) 



1963 over 
1957-59 



1963 over 
1962 



10. Surface-Active Agen 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 

11. Pesticides and Othe 
Organic Agricultural Chemi, 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic : 

Production 

Sales 

Sales value 

i2. Miscellaneous Chemical 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 



852, 3U 
800,432 
127,936 

502,715 
432,135 
113,215 



440,384 
375,627 
150,837 

105,080 
91,938 

49,049 



733,401 
445,252 
132,660 

27,260,924 
11,271,780 
1,621,617 



1,301,878 

1,221,295 

162,509 

646,689 
537,099 
154,618 



584,975 
496,583 
271,266 

144,743 
137,379 
75,035 



857,520 
426,316 
158,806 

36,719,407 
16,176,707 
2,117,002 



1,308,791 

1,222,238 

159,963 

671,867 
567,445 
165,011 



597,072 
498,082 
286,045 

166,405 
153,389 
83,095 



952,565 
476,856 
190,935 

40,200,482 

17,018,837 

2,172,782 



53.6 
52.7 
25.0 

33.6 
31.3 
45.8 



35.6 
32.6 
89.6 

58.4 
66.8 
69.4 



29.9 

7.1 
43.9 

47.5 
51.0 
34.0 



5.6 
6.7 



2.1 
.3 

5.4 

15.0 
11.7 
10.7 



U.l 
11.9 
20.2 

9.5 
5.2 
2.6 



The following tabulation shows, by chemical groups, the number of companies that reported 
production in 1963 of one or more of the chemicals included in the groups listed in table 6: 



MiMber 

of 

conpanies 



Chemical group of Chemical group 

Intermediates 195 Rubber-processing chemicals 

Dyes 51 Elastomers (synthetic rubbers) — 

Synthetic organic pigments 41 Plasticlzers 



fumber 

of 

companies 



31 

34 

63 

Medicinal chemicals 116 Surface-active agents 191 

Flavor and perfume materials 51 Pesticides andotherorganlcagrlculturalchemicals 87 

Plastics and resin materials 316 Miscellaneous chemicals 319 



749-026 O - 64 



SYNTHETIC ORGANIC CHEf/iCAlS 1963 



Cyclic Intermediates 

Cyclic intermediates are synthetic organic chemicals derived principally from coal-tar 
crudes produced by destructive distillation (pyrolysis) of coal and from petroleum and natural 
gas. Most cyclic intermediates are used in the manufacture of more advanced synthetic organic 
chemicals and finished products, such as dyes, medicinal chemicals, elastomers (synthetic 
rubbers), pesticides, and plastics and resin materials. Some intermediates, however, are sold 
as end products without further processing. For example, refined naphthalene may be used as a 
raw material in the manufacture of 2-naphthol or of other more advanced intermediates, or it 
may be packaged and sold as a moth repellant or as a deodorant. In general, the way in which 
the greater part of the output of a given chemical is consumed determines its use classification 
in this report. Table 7A^ gives statistics or. production and sales of cyclic intermediates in 1963. 
Individual statistics given in the table represent more than 80 percent of the total quantity of 
intermediates produced. Since many of the intermediates included in the statistics represent 
successive steps in production, the totals necessarily include considerable duplication. In 1963 
about two-fifths of the total output of cyclic intermediates was sold; the rest was consumed 
chiefly by the producing plants in the manufacture of more advanced intermediates and finished 
products. 

Total production of cyclic intermediates in 1963--12,768 million pounds- -was the largest on 
record, and was 12.0 percent larger than the output of 11, 400 million pounds reported for 1962. 
The larger output of cyclic intermediates in 1963 was attributable to increased demand by a 
number of industries that consume large quantities of intermediates, particularly those indus- 
tries that produce dyes and plasticizers. Sales of cyclic intermediates in 1963 amounted to 
5 , 429 million pounds, valued at $643 million, compared with 4, 572 million pounds, valued at 
$632 million, in 1962. In terms of quantity, sales of cyclic intermediates in 1963 were 18. 7 
percent larger than those in 1 962 and, in terms of value, 1 . 7 percent larger. 



TABLE TA. --Cyclic intermediates: U.S. production and sales , 1963 

'Listed below are all cyclic Intermediates for which any reported data on production or sales may be published. 

■ (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were 
reported ) Table 7B in pt. Ill lists alphabetically all cyclic intermediates for which data on production or sales 
were reported and identifies the manufacturer of each. Appendix B lists alphabetically all the inportajit common 
names of cyclic intermediates usually encountered in the trade and gives the corresponding standard (Chemwal AbaltacU) 
name under which data are presented in tables 7A and 7B] 



Total 

Acetanilide, tech 

<;'-Aminoacetanilide (Acetyl-p-phenylenediamine) 

5-Amino-2-(p-aminoanilino)benzenesulfonic acid 

1-Aminoanthraquinone and salt 

2-Aminoanthraquinone and salt 

6-Amino-3,<i' -azodi(benzenesulfonic acid) 

l-Amino-<i-benzainidoanthraquinone 

6-(p-Aminobenzamido) -l-naphthol-3-sulfonic acid 

2-Aiiiino-p-benzenedisulfonic acid [SOsH^l] 

l-Amino-4-bromo-2-anthraquinonesulfonic acid and sodium salt- 

2-Amino-l-bromo-3-chloroanthraquinone 

l-Amino-2-bromo-4-(p-toluidino)anthraquinone 

l-Amino-5-chloroanthraquinone 

l-Amino-5(and 8)-ohloroanthraquinone 

o-(3-Amino-<l-chlorobenzoyl) benzoic acid 

6-Ainlno-4-chloro-l-phenol-2 -sulfonic acid 

2-Amino-5-chloro-p-toluenesulfonic acid [s03H=l] 

6-Amino-4-chloro-m-toluenesulfonic acid [S03H=l] 

l-Amino-2,'4-dibromoanthraquinone 

l-Amino-4-hydroxyanthraquinone 

See footnotes at end of table. 



1, iMO 
pounds 

12,768,168 



3,548 

385 

24 

1,234 

752 

36 



25 

187 

18 

26 

33 

10 

106 

15 

1,062 



222 

10 



Quantity 



5,428,713 



467 
244 



i.OOO 
dollars 

642,884 



441 
316 



Unit 
value^ 



pound 

$0.12 



^See also table VB, pt. Ill, which lists these products alphabetically and identifies the manufacturers: appendix A, which shows imports 
of intermediates and related products during 1961-63; and appendix B, which is a glossary of synonymous names of cyclic intermediates. 



CYCLIC INTERMEDIATES 



TABLE TA. --Cyclic intermediates : U.S. production and sales , 1963 — Continued 



Quantity 



Unit 
value^ 



l-Ainino-2-methoxy-'i-(p-toluenesulfonainido)anthraquinone 

i'-Ajnino-N-methylacetanilide 

2-Amino-l,5-naphthalenedisulfonic acid 

3-Amino-l,5-naphthalenedisulfonic acid (Cassella acid) 

6-Aiiiino-l,3-naphthalenedisulfonic acid (Amino I acid) 

7-Aiiiino-l,3-naphthalenedisulfonic acid (Amino G acid) 

2-Amino-l-naphthalenesulfonic acid (Tobias acid) 

5-Amino-2-naphthalenesulfonio acid (l,6-Cleve's acid) 

5(and 8)-Aminc-2-naphthalenesulfonic acid (Cleve's acid, mixed) — 

6-Amino-2-naphthalenesulfonic acid (Broenner's acid) 

8-Amino-l-naphthalenesulfonic acid (Peri acid) 

S-Amino-2-naphthalenesulfonic acid (l,7-Cleve's acid) 

8-Aiiiino-2-naphthol 

8-Amino-l-naphthol-3,6-disulfonic acid (H acid), monosodium salt- 

l-Ainino-2-naphthol-4-sulfonic acid (1,2,^-acid) 

6-Amino-l-naphthol-3-sulfonic acid (J acid), sodium salt 

7-Amino-l-naphthol-3-sulfonic acid (Gamma acid), sodium salt 

2-Amino-5-nitrobenzenesulfonic acid [S03H=1] 

2-Amino-A-nitrophenol 

2-Amino-l-phenol-4-sulfonamide 

2-Amino-l-phenol-4-sulfonic acid 

p-(p-Aminophenylazo)benzenesulfonic acid 

■i-Amino-m-toluenesulfonic acid [S03H=1] 

6-Amino-m-toluenesulfonic acid [S03H=1] 

16-Aminoviolanthrone 

2-Amino-3,5-xylenesulfonic acid [SOsH^l] 

Aniline (Aniline oil) 

Anillnomethanesulfonic acid and salt 

8 -Ani 11 no -1 -naphthalene sulfonic acid (Phenyl peri acid) 

6-Anilino-l-naphthol-3-sulfonio acid (phenyl J acid) 

o-Anisldlne 

o-Anisidinomethanesulfonic acid 

Anthra[l,9] pyrazol-6(2H)-one (Pyrazoleanthrone) 

Anthraquinone, 100^ 

1, 5 -Anthraquinonedi sulfonic acid 

1,8-Anthraquinonedlsulfonic acid, potassium salt 

2,6-Anthraqulnonedlsulfonic acid and salt 

l-Anthraquinonesulfonlc acid and salt 

N,N '-(l,5-Anthraquinonylene)dianthranilic acid 

Anthrarufln (1,5-Dlhydroxyanthraquinone) 

Benzaldehyde, tech 

l-Benzamido-5-chloroanthraqulnone 

7H-Benz[de]anthracen-7-one (Benz an throne) 

Benzidine hydrochloride and sulfate 

Benzoic acid, tech 

o-Benzoylbenzoic acid 

3,3'-Blanthra[l,9]pyrazole-6,6'(2H,2'H)-dione (Pyrazoleanthrone 

yellow) 

[ 'i,'i'-Bl-7H-ben2[de]anthracen]-7,7'-dione 

[1,1 -Blnaphthalene]-8,8'-dicarboxylic acid 

l,4-Bis[l-anthraquinonylamino] anthraquinone 

-^.A'-Bls [dimethylamino] benzophenone (Michler's ketone) 

3-Bromo-7H-ben2[de] anthracen-7-one (Bromobenzanthrone) 

l-Bromo-'i-methylaminoanthraquinone 

l-Chloroanthraquinone 

2-Chloroanthraqulnone 

o-Chlorobenzaldehyde 

Chlorobenzene, mono 

o-(p-Chlorobenzoyl) benzoic acid 

l-Chloro-2,<i-dinitrobenzene (Dinitrochlorobenzene) 

l-Chloro-2-methylanthraquinone 

2-Chloro-4-nitroanillne (o-Chloro-p-nitroanillne) 

A-Chloro-2-nitroaniline (p-Chloro-o-nitroanillne) 

l-Chloro-5-nitroanthraquinone 

l-Chloro-2-nitrobenzene (Chloro-o-nitrobenzene) 

l-Chloro-2(and A) -nitrobenzene (Chloronitrobenzenes, o- and p-) — 
l-Chloro-3-nitrobenzene (Chloro-m-nitrobenzene) 



1.000 
pounds 



18 

59 

XbA 

1,001 

725 

3,980 

189 

215 

97 

-427 

231 

77 

3,212 

1,206 

546 

580 

56 

132 

57 

111 

110 

221 

250 

16 

94 

154, 648 

194 

344 

48 

1,588 

274 

8 

4,123 

175 

268 

217 

2,561 

43 

291 

3,605 

96 

2,129 

1,325 

15,320 

5,286 



11 

450 

48 

128 

110 

231 

37 

205 

773 

392 

518,817 

1,214 

8,164 

363 

289 

413 

95 

18,879 

3,920 

6,435 



1,000 
pounds 



1.000 
dollars 



$1.00 



860 
6,988 



924 
1,230 



1.07 
.18 



69, 073 
1,580 



267 
249 



10,715 



4,584 
262 



234 
209 



.07 

.17 

.88 
.84 

.06 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1963 
TABLE 7A. — Cyclic intermediates: U.S. production and sales , 1963 — Continued 



Sales 



Quantity 



Unit 
value""" 



4-Chloro-3-nitrobenzenesulfonamide 

■4-Chloro-3-nitrobenzenesulfonic acid 

4-Chloro-3-nitrotenzenesulfonyl chloride 

o-(4-Chloro-3-nitrobenzoyl)benzoic acid 

"i-Chloro-2-m.trotoluene 

a-Chlorotoluene (Benzyl chloride) 

5-Chloro-o-toluidine [NH2=l] and hydrochloride 

4.-Chloro-a,a,a-trifluoro-3-nitrotoluene 

Cresols, total^ 

o- and p-Cresols 

(m,p)-Cresol, total 

From coal tar 

From petroleum 

(o,m,p)-Cresol^ 

Cresylic acid, refined, total^ 

From coal tar 

From petroleum 

Cumene 

Cyolohexane 

Cyclohexanol 

Cyclohexanone 

1,4— Diaminoanthraquinone 

2,6-Diaminoan"thraquinone 

4,4' -Diamino-2,2'-biphenyldisulfonic acid 

4,4'-Diamino-2, 2'-stilbenedisulfonio acid 

4.,5'-Dibenzamido-l,l'-iminodianthraquinone 

1, 5-Dibenzoylnaph"thalene 

3,9-Dibromo-7H-benz[de] anthracen-7-one 

2,5-Dichloroaniline and hydrochloride [NH2=i] 

1,5-Dichloroanthraquinone 

1,8-Dichloroanthraquinone 

o-Dichlorobenzene 

o(and p)-Dichlorobenzene 

p-Dichlorobenzene 

3,3 '-Dichlorobenzidine base and salts 

2,5-Dichloro-4-(3-methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonio 

acid 

2,6-Dichloro-4-nitroaniline 

l,4-Dichloro-2 -nitrobenzene (Nitro-p-dichlorobenzene) 

2,5-Dichlorosulfanilic acid [S03H=1] 

2, 6-Dichloro toluene 

p-Diethylaminobenzaldehyde 

N,N-Diethylaniline 

l,5-Dihydroxy-4,8-dinitroanthraquinone 

16, 17-Dihydroxyviolanthrone (Dihydroxydibenzanthrone) 

2, 5-Dimethoxyaniline 

3,3'-Dime"thoxybenzidine 

N,N-Dimethylaniline 

NjN-Dimethylbenzylamine — 

2, 2 '-Dimethyl-1, 1' -bianthraquinone 

N,N-Dime"thyl-p-nitrosoam.line 

4, 5-Dinitroohrysazin 

2,4-Dinitrophenol, tech 

4,4'-Dinitro-2, 2'-Etilbenedisulfonio acid 

1,5-Diphenoxyanthraquinone 

l,4-Di(p-toluidino)anthraquinone 

Dodecylbenzene* 

Dodeoylphenol 

N-Ethylaniline, refined 

2-(N-Ethylanilino)ethanol 

a-(N-Ethylanilino) -p-toluenesulfonio acid 

Ethylbenzene 



164 
190 
141 
134 
696 
39,738 
471 
21 

64,505 



23,424 
27,491 
8,539 
18,952 
13,590 

55,853 



21,691 
34,162 

433,179 

1,078,698 

225,214 

72 

93 

9 

2,082 

135 

106 

265 

140 

79 

90 

52,332 

13,378 

74,614 

1,982 

292 

172 

396 

116 

22 

23 

1,330 

83 

437 

61 

473 

9,512 

41 

202 

81 

159 

1,035 

3,423 

46 

164 

489,896 

16,047 

735 

102 

583 

2,450,866 



1,000 
dollars 



217 
515 
708 
807 



522 

Oil 



045 
458 
749 
111 



657 
182 



pound 



See footnotes at end of table. 



CYCLIC INTERMEDIATES 
TABLE IK.— Cyclic intermediates: U.S. production and sales , 1963— Continued 



N-Ethyl-N-phenylbenzylamine 

2-Ethi'l-2-pheiiylmalonio acid, diethyl ester 

3-(N-Ethyl-m-toluidino)propionitrile 

o-Fonnylbenzenesulfonic aoid (o-Sulfobenzaldehyde) 

p-Hydrazinobenzenesulfonic acid 

p-Hydroxyben2oic aoid, methyl ester 

p-Hydroxybenzoic aoid, propyl ester 

l,l'-Iminobi3 [4-aminoanthraquinone] 

Ijl'-Iminobisp-benzaniidoanthraquinone] 

6,6'-Iminobis [l-naphthol-3-sulfonic aoid] 

1, l'-Iminobis[4-nitroanthraquinone] 

l,l'-Iminodianthraquinone (Dianthrimide) 

Isooyanic aoid derivatives, total 

Diphenylmethane 'ij-i'-diisooyanate (MDI) 

Toluene 2,4- and 2,6-diisocyanate (80/20 mixture) 

All other 

4,4'-Isopropylidenediphenol (Bisphenol A) 

Isoviolanthrone (Isodibenzanthrone) 

Leuoo-1, 4-diaminoanthraquinDne 

Leuoo tetrahydroxyanthraquinone 

Metanilio aoid (m-Amlnobenzenesulfonio aoid) 

1-Methylaminoanthraquinone 

'i,'i'-Methylenebis[N,N-dimethylaniline] (Itethane base) 

2-i\lethyl-l-nitroanthraquinone 

p-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonio aoid 

3-Methyl-l-phenyl-2-pyrazolin-5-one (Developer Z) 

:t-Methylstyrene 

1,4,5,8-Naphthalenetetraoarboxylio aoid 

Naphthalic anhydride 

Naphthionio aoid (4-Ainlno-l-naphthalenesulfonio acid) 

2-Naphthol-3,6-disulfonlo aoid, disodium salt 

2-Naphthol-6-sulfonio acid (Schaeffer's acid) and sodium salt 

Naphth[l,2]oxadiazole-5-sulfonio aoid --. 

p-Nitroaniline 

■4-Nitro-o-anisidine [NH2=1] 

5-Nitro-o-anisidine [nH2=1] 

l-Nitro-2-anthraquinonecarboxylic aoid 

5-Nitro-l-anthraquinonesulfonio acid 

Nitrobenzene 

m-Nitrobenzenesulfonio aoid and sodium salt 

m-Nitrobenzenesulfonyl chloride 

m-Nitrobenzoio aoid and sodium salt 

3-Nitro-l,5-naphthalenedisulfonio acid 

7(and 8)-Nitronaphth[l,2]oxadiazole-5-sulfonio aoid 

p-Nitrophenol 

5-Nitro-o-toluenesulfonio acid [sOjHsl] 

3-Nitro-p-toluenesulfonio acid [S03H=1] 

4-Nitro-o-toluidine [ NH2=l] 

5-Nitro-o-toluidine [ NH2=1] 

2-Nitro-p-toluidine [NH2=1] 

16-Nitroviolan throne 

Nonylphenol 

l-(7-0xo-7H7benz[de]anthracen-3-ylamino)anthraqulnone 

l)l'-('7-Oxo-7H-benz[de]anthraoen-3,9-ylenediimino)dianthraquinone- 
5-Oxo-l-(p-sulfophenyl)-2-pyrazoline-3-oarboxylic acid (Pyrazo- 
lone T) 

3,4,9,10-Perylenetetraoarboxylic diimide 

Phenol, grand total^ 

Natural, total 

From coal tar 

From petroleum 

Synthetic, total 

From ouraene 

Other synthetic 

See footnotes at end of table. 



771 
488 

63 
188 
UO 
250 

40 
118 

38 

10 
103 
121 

130,613 



3,553 
116,823 
10,237 

72,392 

45 

303 

60 

619 

147 

1,079 

112 

143 

252 

11, 270 

44 

37 

277 

1,453 

377 

928 

9,808 

83 

284 

35 

102 

219,971 

2,092 

23 

259 

128 

913 

16, 161 

5,403 

86 

11 

300 

1,195 

101 

46,453 

266 

453 

42 
30 

935,378 



50, 679 

37,639 

13,040 

884,699 

325,282 

559,417 



Quantity Value 



1,000 
pounds 



162 
22 



117, 006 



1.000 
dollars 



1,683 

107,989 

7,334 

31, 284 



131 
6,890 



9,421 
2,065 



219 
44 



68,954 



2,065 

61,731 

5,158 

7,728 



230 
378 



107 
2,978 



633 
15,252 



480,239 



52,041 

40,780 

11,261 

428,248 

219,395 

208,853 



734 
1,84A 



45,705 



4,831 

3,711 

1,120 

40,874 

19,272 

21,602 



SYNTHETIC ORGANIC CHEMICALS, 1963 
TABLE lA. --Cyclic intermediates: U.S. production and sales , 1963 — Continued 



Production 



Quantity 



Unit 
value^ 



l-Phenol-"4-sulfonic acid 

Phenylacetic acid, potassiimi salt 

phenylacetonitrile (u-Tolunitrile) 

p-Pheno'lazoaniline (p-Aminoazobenzene) and hydrochloride — 

Phthalic anhydride 

2-Picoline (ci-Picoline)' 

Fiperidine 

Propiophenone 

Pyranthrone 

2° Pyridine' 

Quinaldine 

IJjinizarin 

2-Quinizarinsulfonic acid 

Salicylic acid, tech 

Styrene, all grades 

Sulfanilic acid (p-Aminobenzenesulfonic aoid) and salt 

"i-Sulfoanthranilic acid 

Terephthalic acid 

Terephthalic acid, dimethyl ester 

l,^,5,S-Tetrachloroanthraquinone 

o(and p)-Toluenesulfonic acid 

o-(p-Toluoyl) benzoic acid 

4-(o-Tolylazo)-o-toluidine 

6,6'-Ureylenebis[l-naphthol-3-sulfonic acid] (J acid urea)- 

Violanthrone (Dibenzanthrone) 

o-Xylene 

p-Xylene 

All other cyclic intermediates 



1.000 
pounds 

5,A59 
935 

1,475 

161 

458,630 

442 

504 

24 

3,053 

24 

1,414 

28 

24,643 

,154,363 

2,410 



330,927 

48 

5,415 

639 

397 

272 

601 

303,967 

262,528 

,951,955 



i.OOO 
pounds 

6,276 
915 
726 



225,787 

260 



1,096 



220 
246 
995 



1.000 
dollars 

755 
335 

419 

21,973 

103 



2,095 



1,120 
101, 538 



3.12 
.37 
.58 

.10 

.40 



.35 

.09 



7,634 

22,583 

218,783 



.03 
.09 
.22 



Unit values calculated from rounded figures. 

^ Includes data for coke ovens and gas-retort ovens, reported to the Division of Bitiminous Coal, U.S. Bureau of 
Mines, Department of the Interior, and for tar and petroleum refineries and other producers, reported to the U.S. 
Tariff Commiscion. 

^ Includes some mixed cresols. Figures include (o,m,p)-cresol from coal tar and from petroleum. 

* Includes tridecylbenzene . 

' Includes data for coke ovens and gas-retort ovens, reported to the Division of Bituminous Coal, U.S. Bureau of 
Mines, Department of the Interior, and for tar refineries and other producers, reported to the U.S. Tariff Commis- 
sion. 

In 1963, production of two of the largest volume internnedlates amounted to over 2 billion 
pounds each. The output of ethylbenzene totaled 2,451 million pounds (21, 9 percent more than in 
1962) and that of styrene, 2, 154 million pounds (10. 9 percent more than in 1962). Ethylbenzene is 
used almost entirely in the manufacture of styrene, which, in turn, is used almost entirely in the 
manufacture of plastics materials and synthetic rubber. The output of other large-volume inter- 
mediates in 1963 compares with the output in 1962 as follows: Cyclohexane, 24. 9 percent larger; 
phenol, 13.3 percent larger; phthalic anhydride, 7.3 percent larger; nitrobenzene, 10.2 percent 
larger; aniline, 12.5 percent larger; and toluene diisocyanate (80/20 mixture), 24.6 percent 
larger. Production of dodecylbenzene (including tridecylbenzene) in 1963 was 8.2 percent smaller 
than that in 1962, and that of monochlorobenzene was 6.4 percent smaller. Production of ortho- 
xylene amounted to 304 million pounds in 1963, compared with 272 million pounds in 1962-- 
representing an increase of 11.9 percent. 



Dyes 

Dyes are synthetic organic chemicals derived from cyclic intermediates. About three- 
fourths of the dyes consumed in the United States are used by the textile industry to dye natural 
and synthetic fibers or fabrics; the rest are used chiefly by the industries that produce organic 
pigments, paper, and leather. Of the several thousand different synthetic dyes that are known, 
more than two thousand are manufactured by one or more domestic producers. The large number 
of dyes results from the many different types of materials to which dyes are applied, the different 



DYES 



conditions of service for which dyes are required, and the costs that a particular use can bear. 
Dyes are sold as pastes, powders, lumps, and solutions; concentrations vary from 6 percent to 
100 percent. The concentration, form, and purity of a dye are determined largely by the use for 
which it is intended. 

Table SA^ shows U.S. production and sales of dyes in 1963, total and by individual dyes, 
using the Colour Index classification and terminology (which was used for the first time in the 
Commission's 1958 report). 

Total domestic production of dyes in 1963 amounted to 204 million pounds--8.0 percent 
more than the 189 million pounds produced in 1962, and 22. 5 percent more than the 167 million 
pounds reported for 1961. Sales of dyes in 1963 amounted to 187 million pounds, valued at $240 
million, compared with 178 million pounds, valued at $227 million, in 1962. In terms of quan- 
tity, sales of dyes in 1963 were 5.0 percent larger than in 1962, and in terms of value. 5.5 per- 
cent larger. 

For many important individual low- and medium-priced dyes for which statistics are given 
in table 8A, production was larger in 1963 than in 1962. The output of Vat Blue 6 was 3. 2 million 
pounds in 1963, or 22.6 percent more than the 2.6 million pounds produced in 1962. Other im- 
portant dyes whose output was substantially larger in 1962 than in 1962 were Direct Black 80 
(35.4 percent), Vat Green 9 (29. percent), and Disperse Blue 3 (18. 2 percent). 



TABLE 8A. -- Coat-tar dyes: U.S. production and sales, 1963 

[ Listed below are all coal-tar dyes for which any reported data on production or sales may be published. (Leaders 
are used where the reported data are accepted in confidence and may not be published or where no data were 
reported.) Table 8B in pt. Ill lists all dyes for which data on production or sales were reported and identifies 
the manufacturer of each ] 



Dye 



Quantity 



Unit 
value^ 



Grand total 

ACID DYES 

Total 

Acid yellow dyes, total 

Acid Yellow 3 

Acid Yellow 11 

Acid Yellow 17 

Acid Yellow 23 

Acid Yellow 36 

Acid Yellow AO 

Acid Yellow ^2 

Acid Yellow -W- 

Acid Yellow 5^ -- 

Acid Yellow 73 

Acid Yellow 99 

All other 

Acid orange dyes, total 

Acid Orange 1 

Acid Orange 7 

Acid Orange 8 

Acid Orange 10 

Acid Orange 2^ 

Acid Orange 60 

All other 

Acid red dyes, total 

Acid Red 1 

Acid Red ^ 

Acid Red W 

Acid Red 18- — - 

See footnotes at end of table. 



1,000 
pounds 



17,858 



27 

61 

i87 

295 

254 



1,301 
2,532 



779 
298 
358 
417 
39 
612 

3,427 



"722r 

195 
90 
161 



1,000 
pounds 

186,951 



16,287 



2,341 



32 

438 
228 
257 
102 
24 



87 
991 



2,442 



26 
704 
322 
320 
460 



2,804 



620 
179 
78 
153 



1.000 
dollars 

239,676 



32,812 



5,293 



923 
505 
357 
282 
48 
51 
157 
134 
190 
2,452 

3,511 



593 
342 
407 
598 
75 
1,427 

5,425 



~b9W 
316 
107 
173 



2.01 



2.26 
3.51 
2.00 
2.11 
2.21 
1.39 
2.76 
2.00 
3.00 
2.28 
2.27 
2.18 
2.47 



1.44 

2.65 

.84 

1.06 



1.27 
1.30 
2.50 
2.46 



1.77 
1.37 
1.13 



2 See also table 8B, pu in, which Lists these products and identifies the manufacturers, and appendix A (uble 23), which shows imporu 
of dyes during 1961 -C3. 



SYNTHETIC ORGANIC CHEMICALS, 1963 
TABLE 8A. --Coal-tar dyes: U.S. production and sales , i565— Continued 



Dye 



Production 



Quantity 



ACID DYES— Continued 

Acid red dyes — Continued 

Acid Red 26 

Acid Red 37 

Acid Red 73 

Acid Red 35 

Acid Red 87 

Acid Red 88 

Acid Red 89 

Acid Red lU 

Acid Red 115 

Acid Red 137 

Acid Red 151 

Acid Red 182 

Acid Red 186 

All other 

Acid violet dyes, total 

Acid Violet 1 

Acid Violet 3 

Acid Violet 7 — - - 

Acid Violet 12 

Acid Violet 17 

Acid Violet A3 

All other--' 

Acid blue dyes, total 

Acid Blue 7 

Acid Blue 9 

Acid Blue 22 

Acid Blue 25 

Acid Blue ^0 

Acid Blue 41 

Acid Blue A3 

Acid Blue A5 

Acid Blue 78 

Acid Blue 90 

Acid Blue 113 

Acid Blue 158 and 158A 

All other 

Acid green dyes, total 

Acid Green 3 

Acid Green 9 

Acid Green 12 

Acid Green 15 

Acid Green 20 

Acid Green 25 

Acid Green 50 

All other 

Acid brown dyes, total 

Acid Brown lA 

All other 

Acid black dyes, total 

Acid Black 1 

Acid Black 24 

Acid Black 48 

All other 



1,000 
pounds 



213 
177 
540 
131 



102 
104 



2,896 



"72" 
534 
37 



90 

18 

523 

28 

16 

321 

195 

989 



18 
187 



317 

414 



4,365 



1,724 
123 



2,479 



i.OOO 
pounds 



1,000 
dollars 



208 
165 
110 
150 



714 
433 



2,793 



477 
37 
65 



525 

30 

291 
192 
995 



164 
47 
189 



290 
374 



4,158 



1,591 

117 

33 

2,417 



82 
166 
451 
274 
206 
206 



27 
1,984 



63 
206 
121 

57 
130 

28 
219 

8,233 



"135" 
560 
124 
343 
61 
272 
217 
1,777 
200 

442 

443 

3,608 



174 
63 



1,521 



403 
1,118 



6,291 



1,852 
204 
167 

4,068 



See footnotes at end of table. 



DYES 



TABLE 8A. — Co2l-tar dyes: U.S. production and sales, 1963 --Continued 



riye 



Quantity 



A20IC DYES AND COMPONENTS 

Azoic Compositions 

Total 

Azoic Yellow 1 

Azoic Yellow 2 

Azoic Orange 3 

Azoic red dyes, total 

Azoic Red 1 

Azoic Red 2 

Azoic Red 6 

All other 

Azoic Blue 3 

Azoic Brown 9 

Azoic Black A 

All other azoic compositions 

Azoic Diazo Components, Bases 
(Fast Color Bases) 

Total 

Azoic Diazo Component A, base 

Azoic Diazo Component 10, base 

Azoic Diazo Component 12, base 

Azoic Diazo Component 13, base 

Azoic Diazo Component 32, base 

Azoic Diazo Component "iS, base 

All other azoic diazo components, bases 

Azoic Diazo Components, Salts 
(Fast Color Salts) 

Total— 

Azoic Diazo Component 1, salt 

Azoic Diazo Component 2, salt 

Azoic Diazo Component 3, salt 

Azoic Diazo Con^ionent 5, salt 

Azoic Diazo Component 6, salt 

Azoic Diazo Component 8, salt 

Azoic Diazo Component 9, salt 

Azoic Diazo Component 10, salt 

Azoic Diazo Component 11, salt 

Azoic Diazo Component 12, salt 

Azoic Diazo Component 13, salt 

Azoic Diazo Component 20, salt 

Azoic Diazo Component 28, salt 

Azoic Diazo Component 36, salt 

Azoic Diazo Component •42, salt 

Azoic Diazo Component '*8, salt 

Azoic Diazo Component A9, salt 

All other azoic diazo components, salts 

Azoic Ckiapling Components 
(Naphthol AS and Derivatives) 

Total- 

Azoic Covgjling Conqjonent 2 

Azoic Coi5)ling Con5>onent 3 



1,000 
pounds 



2,100 



305 
157 



202 
295 
727 



l.^O 



266 
467 
281 
35 
338 



2,333 



235 
190 



84 
335 



152 
493 



175 
24 



3,018 



1,000 
pounds 



2,125 



212 
131 



127 

320 

1,005 



1,268 



276 
445 
278 



2,197 



9 

263 

178 

12 

68 

319 

67 

60 

141 

433 

19 

167 

35 



47 
303 



2,432 



3,717 



188 
143 
375 
224 

91 

411 

435 

1,669 



1,947 



48 

16 

367 

540 

438 



2,340 



23 

lA 

203 

220 



205 
104 
109 
159 
318 
56 
190 



63 
152 
360 



4,826 



201 
18 



69 



73 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1963 
TABLE SA.-- Coal-tar dyes. ■ U.S. production and sales, 7965 --Continued 



Dye 



Sales 



Production 



Quantity 



AZOIC DYES AND COMPONENTS— Continued 

Azoic Coupling Components 
(Naphthol AS and Derivat ives ) --Conlinuei 

Azoic Coupling Component <V 

Azoic Coupling Component 5 

Azoic Coupling Component 7 

Azoic Coupling Component 14 

Azoic Coupling Congjonent 17 

Azoic Coupling Component 18 

Azoic Coupling Component 20 

Azoic Coupling Component 21 

Azoic Coupling Component 29 

Azoic Coupling Component 3<i 

Azoic Coupling Component 35 

All other azoic coupling components 

BASIC DYES 

Total 

Basic Yellow 2 

Basic orange dyes, total 

Basic Orange 1 

Basic Orange 2 

Basic Orange 21 

All other 

Basic Red 2 

Basic Violet 1 

Basic Violet A- 

Basic Violet 10 

Basic Violet 16 

Basic blue dyes, total 

Basic Blue 1 

Basic Blue 7 

Basic Blue 9 

Basic Blue 26 

All other 

Basic Green 1 

Basic Green 4 

Basic Brown 1 

Basic Brown A 

All other basic dyes 

DIRECT DYES 

Total-- 

Direct yellow dyes, total 

Direct Yellow 4 

Direct Yellow 5 

Direct Yellow 6 

Direct Yellow 11 

Direct Yellow 12 

Direct Yellow 26 

Direct Yellow 28 

Direct Yellow 29 

Direct Yellow 44 

Direct Yellow 50 

Direct Yellow 59- 



1,000 
pounds 



767 
165 
211 
922 
172 



8,750 



249 

420 

236 

75 

176 

1,247 

31 



1,032 



T2" 
167 
415 
73 
363 

78 
514 
215 
665 
3,046 



28,399 



4,959 



1,000 
pounds 



1,000 
dollars 



29 

748 



174 
736 



23 

514 



7,787 



"223" 

438 

205 

72 

171 

939 

38 

245 



297 

62 

453 

73 

477 

218 

602 

2,534 



27,677 



4,811 



1,455 



324 
867 



20 
121 

1,592 



18,142 



1,415 
1,727 



262 
529 
669 
267 

505 
1,212 
111 
900 
204 

2,661 

— wr 



676 

188 

1,710 

252 

1,262 

292 

797 

6,804 



41,660 



8,844 



392 


349 


750 


82 


83 


247 


893 


854 


1,335 


735 


742 


923 


393 


353 


881 


8 


7 


18 


228 


231 


476 


91 


84 


127 


388 


386 


666 


209 


250 


480 



See footnotes at end of table. 



DYES 



19 



TABLE 8A. — Coal-tar dyes: U.S. production and sales , 1963 — Continued 



Dye 



Quantity 



DIRECT DYES— Continued 

Direct yellow dyes — Continued 

Direct Yellow 81 

Direct Yellow 8<4 

All other 

Direct orange dyes, total 

Direct Orange 1 

Direct Orange 8 

Direct Orange 15 

Direct Orange 26 

Direct Orange ^i, 

Direct Orange 37 

Direct Orange 39 

Direct Orange 72 

Direct Orange 73 

Direct Orange 81 

Direct Orange 102 

All other 

Direct red dyes, total 

Direct Red 1 

Direct Red 2 

Direct Red A 

Direct Red 10 

Direct Red 13 

Direct Red 16 

Direct Red 23 

Direct Red 24 

Direct Red 26 

Direct Red 28 

Direct Red 31 — - -- — 

Direct Red 37 

Direct Red 39 

Direct Red 75 

Direct Red 79 

Direct Red 80 — 

Direct Red 81 

Direct Red 83 

Direct Red 122 

Direct Red 1-49 

Direct Red 152 

All other 

Direct violet dyes, total 

Direct Violet 1 

Direct Violet 9 

Direct Violet 48 

All other 

Direct blue dyes, total 

Direct Blue 1 

Direct Blue 2 

Direct Blue 6 

Direct Blue 8 

Direct Blue 14 

Direct Blue 15 

Direct Blue 22 

Direct Blue 24 

Direct Blue 25 

Direct Blue 26 

Direct Blue 67 

Direct Blue 71 

Direct Blue 76 

Direct Blue 78 



1,000 
pounds 



175 
1,338 



1,850 



13 
149 
182 



57 
72 
247 

36 
186 
747 

3,398 



206 
384 



283 

283 

135 

171 

18 

77 

58 

34 

194 

525 

291 

85 

27 

18 
483 



5,435 



254 
1,662 

28 

102 

59 

19 



21 
82 

303 
77 



1,000 
pounds 



1,000 
dollars 



138 
1,286 



1,672 



123 
169 
58 



174 
625 



3,281 



201 

396 

30 

17 

62 

40 

268 

243 

123 

167 

19 

72 

48 

27 

221 

510 

275 



5,418 



237 
1,707 

388 
37 
93 
53 
20 



28 

228 

2,642 

3,710 



180 
203 
112 
169 
140 
176 
498 
131 
151 
476 
1,474 

6,974 



336 
654 

83 

25 
100 

80 
608 
465 
328 
203 

68 
189 
138 

93 
501 
1,000 
695 
160 

40 

44 

1,164 



30 
332 



7,859 



548 
1,504 

218 
69 
89 
75 



115 
181 
576 
240 



See footnotes at end of table. 



20 SYNTHETIC ORGANIC CHEMICALS, 1963 

TABLE 8A.-- Coal-tar dyes: U.S. production and sales , 1963— Continued 



Dye 



Production 



Quantity 



Unit 
value-"- 



DIRECT DTES— Continued 

Direct blue dyes — Continued 

Direct Blue 80 

Direct Blue 86 

Direct Blue 98 

Direct Blue 120 and 120A 

Direct Blue 126 

All other 

Direct green dyes, total 

Direct Green 1 

Direct Green 6 

Direct Green 8 

Direct Green 12 

Direct Green 38 

All other 

Direct brown dyes, total 

Direct Brown 1 and lA 

Direct Brown 2 

Direct Brown 6 

Direct Brown 31 

Direct Brown 74 

Direct Brown 95 

Direct Brown 111 

Direct Brown 15A 

All other 

Direct black dyes, total 

Direct Black 'i 

Direct Black 9 

Direct Black 19 

Direct Black 22 

Direct Black 37 

Direct Black 38 

Direct Black 51 

Direct Black 80 

All other 

DISPERSE DYES 

Total 

Disperse yellow dyes, total 

Disperse Yellow 1 

Disperse Yellow 3 

Disperse Yellow 5 

Disperse Yellow 23 

Disperse Yellow 37 

All other 

Disperse orange dyes, total 

Disperse Orange 3 

Disperse Orange 5 

Disperse Orange 17 

All other 

Disperse red dyes, total 

Disperse Red 1 

Disperse Red 5 

Disperse Red 11 

Disperse Red 13 

Disperse Red 15 

Disperse Red 17 

All other 



1,000 
pounds 



115 

92 

125 

75i 



1,974 



397 
182 



179 
314 



9,636 



262 

48 



796 

11 

5,977 

73 

1,682 

787 



11,318 



1,819 



660 
52 
49 
118 
940 



105 
60 
196 
323 

1,813 



226 

61 



136 

1,351 



1,000 
pounds 



1,000 
dollars 



282 
959 
114 
136 
105 
722 



185 

389 

21 



1,904 



202 
86 
94 
53 

669 
48 

159 

246 

9,418 



~23T 

50 

181 

836 

12 

5,921 

90 

1,455 

616 



9,526 



1,566 



617 
52 
46 
109 
724 



91 
62 
139 
320 

1,421 



190 
51 
33 
22 
90 
125 
910 



436 
1,547 
196 
263 
244 
1,369 

2,068 



215 

443 

24 

53 
1,333 

2,534 



366 
299 
100 
263 
88 
482 
168 
219 
549 

9,092 



268 

66 

287 

708 

16 

4,852 

242 

1,542 

1,111 



22,198 



3,258 



~Z3 
1,127 
170 
125 
176 
1,617 

1,059 



150 
138 
163 
608 

4,063 



292 
59 



258 
136 

3,110 



See footnotes at end of table. 



DYES 
TABLE 8A.— Coal-tar dyes: U.S. production and sales, 7965— Continued 



Dye 



Quantity 



DISPERSE DYES— Continued 

Disperse Violet 1 

Disperse Violet 'i 

Disperse blue dyes, total 

Disperse Blue 1 

Disperse Blue 3 

Disperse Blue 7 

Disperse Blue 6A 

All other 

Disperse brown dyes 

Disperse Black 1 

Disperse Black 9 

All other disperse dyes 

FIBER-REACTIVE DYES 

Fiber- reactive dyes 

FLUORESCENT BRIGHTENING AGENTS^ 

FOOD, DRUG, AND COSMETIC COLORS 

Total - 

Food, Drug, and Cosmetic Dyes 

Total- 

FDiC Blue No. 1- 

FD&C Red No. 2 

FD&C Red No. 3— 

FD&C Red No. i, - — - 

FD&C Yellow No. 5- — 

FD&C Yellow No. 6 - • 

All other food, drug, and cosmetic dyes 

Drug and Cosmetic and External Drag 
and Cosmetic Dyes 

Total - 

D&C Red No. 7 - 

D&C Red No. 8- - - 

D&C Red No. 19- - - 

D&C Red No. 21 - 

All other drug and cosmetic and external drug and cosmetic 
dyes 

MORDANT DYES 

Total— - ■ 

Mordant yellow dyes, total 

Mordant Yellow 1 

Mordant Yellow 8 

All other 

Mordant orange dyes, total 

Mordant Orange 1 

All other 



1.000 
pounds 



4,526 



365 

1,535 

223 

133 

2,270 

197 

356 

1,380 



1,132 



2,-405 



2,195 



4,056 



1.000 
pounds 



1,000 
dol lars 



3,684 



272 

1,175 

226 

2,011 

125 

324 

1,259 

477 



1,061 



2,546 



2,343 



4,165 



206 



37 

8 

161 

136 



90 
121 



10,730 



1,043 
1,957 
1,232 

6,498 

210 

406 

1,281 



4,375 



10,242 



9,178 



43 


50 


591 


617 


654 


1,862 


36 


39 


696 


322 


315 


1,585 


531 


590 


1,977 


440 


533 


1,594 


206 


162 


873 



1,064 



10 
32 

107 



5,545 



368 



47 

15 

306 



32 
104 



See footnotes at end of table. 



22 



SYNTHETIC ORGANIC CHEMICALS, 1963 
TABLE 8A. — Coal-tar dyes: U.S. production and sales , 1963 — Continued 



Dye 



Quantity 



MORDANT DYES— Continued 

Mordant red dyes, total 

Mordant Red 7 

All other 

Mordant blue dyes, total 

Mordant Blue 1 

All other 

Mordant brown dyes, total 

Mordant Brown 1 

Mordant Brown 19 

Mordant Brown AO 

All other 

Mordant black dyes, total 

Mordant Black 3 

Mordant Black 5 

Mordant Black 11 

Mordant Black 13 

Mordant Black 17 

Mordant Black 38 

All other 

All other mordant dyes 

SOLVENT DYES 

Total 

Solvent yellow dyes, total 

Solvent Yellow 2 

Solvent Yellow 3 

Solvent Yellow lA 

Solvent Yellow A7 

All other 

Solvent orange dyes, total 

Solvent Orange 3 

Solvent Orange 7 

Solvent Orange 20 

All other 

Solvent Red 26 

Solvent Red 49 

Solvent violet dyes, total 

Solvent Violet 8 

All other 

Solvent blue dyes, total 

Solvent Blue 38 

All other 

Solvent green dyes, total 

Solvent Green 3 

All other 

Solvent brown dyes 

All other solvent dyes 



1,000 
pounds 



3,176 



54 
2,411 



7,649 



1,062 



24 
43 
722 



26 

85 

22 

109 

296 
29 



307 

120 



172 
636 



74 
4,643 



1,000 
pounds 



1,000 
dollars 



3,330 



2,661 



6,850 



850 



27 
38 

555 
42 
188 



297 
117 



157 
575 



64 
4,238 



87 
241 



109 
72 



116 
25 
43 

530 

3,697 



23 

67 

2,738 

124 

393 

83 

269 

33 



11,826 



1,790 



41 
62 
609 
213 
865 



35 
151 



421 
163 



439 
388 



766 
2,551 



205 
119 



228 
4,216 



See footnotes at end of table. 



DYES 



23 



TABLE ik.--Coal-tav dyes: U.S. production and sales , 1963 — Conimxied 



Dye 



Production 



Quantity 



SULFUR DYES^ 
VAT DYES 



Total- 



Vat yellow dyes, total 

Vat Yellow 2, S-l/Zi- — 
Vat Yellow i, \2-\/2$— 
All other 



Vat orange dyes, total 

Vat Orange 1, 2Q>'% 

Solubilized Vat Orange 1, 2b'% — 

Vat Orange 2, 1256 

Vat Orange U, 6% 

Vat Orange 5, IO56- 

Solubilized Vat Orange 5, 30^- 

Vat Orange 7, II56 

Vat Orange 9, 12ll> 

Vat Orange 15, lOjt 

All other 



Vat red dyes, total 

Vat Red 1, U^t- 

Solubilized Vat Red 1, 37^- 

Vat Red 13, II56 

Vat Red 15, IO56 

Vat Red 32, 20;( 

All other 



Vat violet dyes, total 

Vat Violet 1, 11»6 

Vat Violet 2, 20»fr- - 

Vat Violet 9, 12i6 

Vat Violet 13, e-l/A'f,-— 
Vat Violet 17, 12-1/2^- 
All other 



Vat blue dyes, total 

Vat Blue ■!,, 10?, 

Vat Blue 5, I656 

Vat Blue 6, 8-1/3^6 

Solubilized Vat Blue 6, 17-1/25&— 

Vat Blue 1^, 3-1/3* 

Vat Blue 18, 13i 

Vat Blue 20, Wjlr- 

All other 



Vat green dyes, total 

Vat Green 1, 656 

Vat Green 3, lO^fe 

Solubilized Vat Green 3, 26*-- 

Vat Green 8, 8-1/2'i- 

Vat Green 9, 12-1/2*-- - — 

All other 



Vat brown dyes, total- 
Vat Bro?m 1, 1156 

Vat Brown 3, 11^--- 
Vat Brown 5, 13 5t— -- 
All other 



1.000 
pounds 



52,596 



2,858 



1,758 
427 
673 

2,281 



-iOO 
89 
171 

170 
152 
iOl 
430 



420 
5 

33 
144 

38 
264 

1,121 
JOF 



468 
32 
180 

20,550 



242 

3,211 

47 

582 

905 

1,117 

14,446 

11,434 



4,929 
3,209 
8 
1,423 
1,722 
143 

5,440 



1,000 
865 
240 

3,335 



1.000 
pounds 



1,000 
dollars 



48,815 



2,719 



1,633 
492 
594 

1,957 



191 
105 
400 
354 



1,022 



417 
34 
78 

408 
28 
57 

18,993 



72 

276 

2,856 

32 

453 

793 

992 

13,519 

10,649 



4,612 
2,699 
7 
1,361 
1,410 
560 

5,053 



213 
3,109 



46,347 



3,782 



1,484 

620 

1,678 

4,571 



1,007 
79 
632 
267 
238 
40 
519 
259 
855 
675 



201 
152 
104 
950 

1,904 



672 

85 

295 

638 



11,610 



TZT 

272 

3,076 

200 

559 

1,298 

1,328 

4,735 

7,857 



2,672 
1,974 
48 
1,002 
1,359 
802 

6,870 



1,713 

1,434 

307 

3,416 



See footnotes at end of table. 



24 



SYNTHETIC ORGANIC CHEMICALS, 1963 

TABLE 8A. — Coal-tar dyes: U.S. production and sales , 1963 — Continued 



Dye 



Quantity 



Unit 
value "■ 



VAT DYES— Continued 

Vat black dyes, total 

Vat Black 9, 16!t- 

Vat Black 25, 12-l/25t- - 

Vat Black 27, 12-l/2Jt- 

All other 

All other dyes^ 



1,000 
pounds 
8,008 



1,000 
pounds 
7,558 



1,000 
dollars 



7,656 



177 
3,377 

907 
3,547 

61,012 



15<; 
2,8A9 

786 
3,769 

54,215 



38A 
2,192 
1,029 
4,051 

33,699 



$1.01 



2.49 

.77 

1.31 

1.07 

.62 



Calculated from rounded figures. 

^ Included in "All other dyes." 

•* Includes oxidation bases, ingrain dyes, miscellaneous dyes, sulfur dyes, and fluorescent brightening agents (pro- 
duction of fluorescent brightening agents in 1963 increased somewhat over 1962). Statistics for these groups of dyes 
may not be published separately because publication would disclose information received in confidence. 



On the other hand, the output of a few important dyes was smaller in 1963 than in 1962. 
Production of Direct Black 38 was 6. nnillion pounds in 1963, or 7. 2 percent less than the 6. 4 
million pounds produced in 1962; that of Vat Green 1 was 4.9 million pounds, or 7.4 percent 
less than the 5. 3 million pounds reported for 1962. Other important dyes whose output was 
smaller in 1963 than in 1962 were Vat Yellow 2 (24. 3 percent), Mordant Black 11 (23. 9 percent), 
Vat Green 8 (16. 6 percent), Direct Blue 2 (16. percent), and Vat Black 25 (12. 9 percent). 

Table 9 summarizes production and sales of dyes in 1963, by class of application. Three 
classes of dyes accounted for 48. 4 percent of the total output of dyes in 1963. Vat dyes accounted 
for 25. 8 percent of the total; direct dyes, for 13.9 percent; and acid dyes, for 8. 8 percent. In 
1963 the output of two of the three classes was larger than in 1962. Production of direct dyes 
was 3.6 percent larger, and that of acid dyes, 11.8 percent larger. Production of vat dyes in 
1963 was about the same as in 1962. 

Of the remaining classes, the output of fiber-reactive dyes was 1. 1 million pounds in 1963, 
or 107 percent more than the 546, 000 pounds in 1 962 but 5. 4 percent less than the 1 . 2 million 
pounds produced in 1961. Production of azoic dyes and components was 17.4 percent larger in 
1 963 than in 1962; basic dyes, 15.0 percent larger; and disperse dyes, 9. 5 percent larger. Pro- 
duction of solvent dyes in 1963 was about the same as in 1962. On the other, hand, the output of 
mordant dyes was 26.5 percent smaller in 1963 than in 1962, and that of food, drug, and cos- 
metic colors, 10. 7 percent smaller. 

Table 10 shows production and sales of dyes in 1963 by chemical class. In 1963, three 
chemical classes of dyes accounted for approximately one -half of all the dyes produced: Azo 
dyes accounted for 26. 2 percent of the total; anthraquinone dyes, for 20. I percent; and stilbene 
dyes, for 7.8 percent. The output of two of these three classes was larger in 1963 than in 1962: 
Stilbene dyes was 14.0 percent larger; and azo dyes, 2.9 percent larger. The output of anthra- 
quinone dyes in 1963 was 3.6 percent smaller than in 1962. Of the remaining chemical classes, 
production of eight classes was larger in 1963 than in 1962, and production of one class--xan- 
thene--was smaller in 1963 than in 1962. Production of triarlymethane dyes in 1963 was about 
the same as that in 1962. In terms of value of sales, the most important classes of dyes in 1963 
were the azo dyes ($87. 1 million), the anthraquinone dyes ($61. I million), the stilbene dyes 
($25.1 million), and the azoic dyes ($ 1 2. 8 million) . 



DYES 



25 



TABLE 9.— Coal-tar dyes: U.S. production and sales, by class of application, 1963 



Class of application 



Production 



Quantity 



Unit 
value-' 



Total— - 

Acid 

Azoic dyes and components : 

Azoic compositions 

Azoic diazo components, bases (Fast color bases) 

Azoic diazo components, salts (Fast color salts) 

Azoic coupling components (Naphthol AS and derivatives )- 

Basic 

Direct 

Disperse 

Fiber-reactive 

Food, drug, and cosmetic colors 

Mordant 

Solvent 

Vat 

All other^ 



1,000 
pounds 
204,046 



1,000 
pounds 
186,951 



1,000 
dollars 
239,676 



17,858 

2,100 
1,420 
2,333 
3,018 
8,750 
28,399 
11,318 
1,132 
2,405 
4,056 
7,649 
52,596 
61,012 



16,287 

2,125 
1,268 
2,197 
2,432 
7,787 
27,677 
9,526 
1,061 
2,546 
4,165 
6,850 
48,815 
54,215 



32,812 

3,717 

1,947 

2,340 

4,826 

18,142 

41,660 

22,198 

4,375 

10,242 

5,545 

11,826 

46,347 

33,699 



2.01 

1.75 
1.54 
1.06 
1.98 
2.33 
1.51 
2.33 
4.12 
4.02 
1.33 
1.73 
.95 
.62 



Calculated from rounded figures. 
^ Includes oxidation bases, ingrain dyes, miscellaneous dyes, sulfur dyes, and fluorescent brightening agents 
(production of fluorescent brightening agents in 1963 increased somewhat over 1962). Statistics for these groups of 
dyes may not be published separately because publication would disclose information received in confidence. 



TABLE 10. -- Coal-tar dyes: U.S. production and sales, by chemical class, 1963 



Chemical class 



(iiantity 



Unit 
value ^ 



Total 

Anthraquinone — 

Azo, total 

Monoazo 

Disazo 

Trisazo 

Polyazo 

Not specified- 

Azoic 

Ketone imine 

Methine 

Nitro 

Oxazine 

Phthalocyanine-- 

Quinoline 

Stilbene 

Thiazine 

Thiazole 

Triarylmethane-- 

Xanthene 

All other^- 



1,000 
pounds 
204,046 



40,934 
53,359 



16,200 
16,016 
10,855 
2,233 
8,055 

8,871 
695 
758 
652 
107 

1,457 

464 

15,935 

469 

417 

5,979 

1,311 
72,638 



1,000 
pounds 
186,951 



36,722 
51,294 



15,702 
15,327 
10,644 
2,172 
7,449 

8,022 

672 

647 

568 

92 

1,432 

392 

14,616 

344 

393 

5,243 

688 

65,826 



1,000 
dollars 
239,676 



61,084 
87,135 



31,440 
26,094 
11,447 
3,625 
14,529 

12,830 

1,452 

2,299 

1,016 

347 

3,806 

1,294 

25,072 

964 

858 

11,955 

3,144 

26,420 



pound 



$1.28 



1.66 



1.70 
2.00 
1.70 
1.08 
1.67 
1.95 



1.60 
2.16 
3.55 
1.79 
3.77 
2.66 
3.30 
1.72 
2.80 
2.18 
2.28 
4.57 
.40 



^ Calculated from rounded figures. 

^ Includes acridine, aminoketone, azine, coumarin, hydroxyketone, indigoid, nitroso, sulfur, vat sulfur, and mis- 
cellaneous dyes. Statistics for these groups of dyes may not be published separately because publication would dis- 
close information received in confidence. 



26 SYNTHETIC ORGANIC CHEMICAIS, 1963 

Synthetic Organic Pigments 

As the terms are used in this report, synthetic organic pigments are toners and lakes. 
They are used in paints and related products, in printing inks, and in plastics and resin mate- 
rials. 

Statistics on production and sales of all synthetic organic pigments in 1963 are given in 
table llA.'' Statistics on sales of a few selected pigments by commercial forms (dry full- 
strength form, dry extended form, dry dispersions, aqueous dispersions, and flushed colors) 
are given in table 12. Prior to 1961, statistics for toners included the quantities and values of 
extenders and diluents. Beginning in 1961, data were collected for both the full-strength and 
extended toners on a full-strength-toner-content basis. Individual toners and lakes are identified 
in this report by the names used in the second edition of the Colour Index rather than by their 
common names. "^ 

Total production of synthetic organic pigments in 1963 was 39.4 million pounds- -6.0 per- 
cent more than the 37. 2 million pounds produced in 1962 and 12.4 percent more than the 35.1 
million pounds produced in 1961. Total sales of synthetic organic pigments in 1963 amounted to 
33. 5 million pounds, valued at $79. 6 million, compared with 31 . 6 million pounds, valued at 
$74. 3 million, in 1962 and 29.5 million pounds, valued at $66. 3 million, in 1961. In terms of 
quantity, sales of synthetic organic pigments in 1963 were 6. 1 percent larger than in 1962 and 
13.8 percent larger than in 1 96 1 ; in terms of value, sales in 1963 were 7. I percent larger than 
in 1962 and 20.0 percent larger than in 1961. 

Production of toners in 1963 amounted to 35. 6 million pounds--6. 3 percent more than the 
33.4 nnillion pounds reported for 1962. Sales in I 963 were 30. I million pounds, valued at $76.2 
million, compared with 28.4 million pounds, valued at $70.7 million, in 1962. Sales in 1963 
were thus 6. 1 percent larger than in 1962 in terms of quantity, and 7. 7 percent larger in terms 
of value. Production of red toners in 1963 amounted to 17.2 million pounds, or 48.4 percent of 
the total output of toners. The individual toners produced in the largest quantities in 1963 were 
Pigment Blue 15, alpha form, 3. 3 million pounds; Pigment Green 7, 3. 1 million pounds; Pig- 
ment Red 49, barium toners, 3. million pounds; Pigment Yellow 12, 2.9 million pounds; and 
Pigment Red 48, 2. 2 million pounds. 

Production of lakes totaled 3.8 million pounds in 1963--3.7 percent more than the 3.7 
million pounds reported in 1962. Sales of lakes in 1963 amounted to 3.4 million pounds, valued 
at $3.4 million, compared with sales in 1 962 of 3. 2 million pounds, valued at $3.6 million. 
Sales in 1963 were thus 6. 5 percent larger than in 1962 in terms of quantity, but 4. I percent 
smaller in terms of value. Pigment Blue 24, with an output of 1 . 9 million pounds, was the lake 
produced in largest quantity in 1963. 

Table 12 gives data on sales by commercial forms for each of 16 selected pigments or 
groups of pigments. Pigment Yellow 12, Pigment Red 90, Pigment Blue 19, and Pigment Blue 
24 were sold principally in flushed fornn. The remaining 12 pigments or groups of pigments for 
which data are shown were sold principally in dry full-strength fornn. 



See also table IIB, pi. IB, which lists these products alphabetically and idenufies the manufacturers, and table 23 in appendix A, 
which shows imports of synthetic organic pigments during the years 1961-63. 

*See appendix C, which lists the common names of all the pigments mentioned in this report. 



SYNTHETIC ORGANIC PIGMENTS 



27 



TABLE llA. --Synthetic organic pigments: U.S. production and sales, 1963 

[Listed below are all toners and lakes for which any reported data on production or sales may be published. (Leaders 
are used where the reported data are accepted in confidence and may not be published or where no data were 
reported.) Table IIB in pt. Ill lists all toners and lakes for which data on production or sales were reported and 
identifies the manufacturer of each] 



Production 



(Jiantity 



Grand total 

TONERS 

Total 

Yellow toners, total 

Hansa yellows, total 

Pigment Yellow 1, C.I. 11 680 

Pigment Yellow 3, C.I. 11 710 

Other Hansa yellows 

Benzidine yellows, total 

Pigment Yellow 12, C.I. 21 090 • 

Pigment Yellow 13, C.I. 21 100 

Pigment Yellow U, C.I. 21 095— 

Pigment Yellow 17, C.I. 21 105— • 

Other benzidine yellows 

All other 

Orange toners, total 

Pigment Orange 2, C.I. 12 060 

Pigment Orange 5, C.I. 12 075 

Pigment Orange 13, C.I. 21 110 

Pigment Orange 16, C.I. 21 160 

All other 

Red toners, total 

Naphthol reds, total 

Pigment Red 2, C.I. 12 310 

Pigment Red 5, C.I. 12 490 

Pigment Red 13, C.I. 12 395 

Pigment Red 17, C.I. 12 390 - 

Pigment Red 18, C.I. 12 350 - 

Pigment Red 22, C.I. 12 315 - 

Pigment Red 23, C.I. 12 355 — 

Pigment Red 31, C.I. 12 360— -- 

Other naphthol reds 

Pigment Red 1, C.I. 12 070, dark 

Pigment Red 1, C.I. 12 070, light 

Pigment Red 3, C.I. 12 120 — 

Pigment Red 4, C.I. 12 085 

Pigment Red 38, C.I. 21 120 

Pigment Red 48, C.I. 15 865 

Pigment Red 49, C.I. 15 630: 

Barium toner 

Calcium toner 

Sodium toner 

Pigment Red 52, C.I. 15 860- 

Pigment Red 53, C.I. 15 585, barium toner-- 
Pigment Red 54, C.I. 14 830, calcium toner- 
Pigment Red 57, C.I. 15 850, calcium toner- 
Pigment Red 63, C.I. 15 880 

Pigment Red 81, C.I. 45 160, RIA 

Pigment Red 81, C.I. 45 160, PTA 

Pigment Red 90, C.I. 45 380 

All other 

Violet toners, total 

Pigment Violet 1, C.I. 45 170, ™a 

Pigment Violet 1, C.I. 45 170, PTA 

Pigment Violet 3, C.I. 42 535, fugitive 

Pigment Violet 3, C.I. 42 535, BiA 

Pigment Violet 3, C.I. 42 535, PTA 

All other 

See footnotes at end of table. 



1,000 
pounds 
39,399 



35,557 



5,386 



976 
526 
110 
340 
4,275 
2,900 
165 
989 
154 
67 
135 

714 



169 
110 
152 
283 

17,192 



112 

7 

84 

14 

104 

121 

20 

236 

212 

281 

1,850 

314 

165 

2,205 

3,048 

1,624 

331 

713 

1,723 

870 

52 

174 

116 

1,214 

1,553 

1,019 



398 
370 
42 

114 



1,000 
pounds 
33,534 



1,000 
dollars 



79, 600 



30,112 



Sir 

420 
69 

322 

2,992 

1,923 

95 

816 

111 
47 
83 

631 



149 
104 
133 
185 

14,601 
577" 



5 
113 
119 
14 
128 
190 
234 

1,393 
266 
133 

2,059 

2,726 

1,487 
297 
669 

1,457 
34 
767 
40 
170 
119 
653 

1,333 

948 



380 
322 
37 

lU 



76,165 



9,790 



2,029 

801 

166 

1,062 

6,974 

4,187 

300 

1,943 

369 

175 

787 

3,161 



232 

345 

366 

2,129 

30,221 

2,403 

128 

333 

22 

237 

17 

334 

449 

74 

809 

232 

283 

2,136 

371 

600 

3,802 

2,656 

1,523 
313 
996 

1,857 
79 

1,141 
77 

1,058 
759 

1,181 

8,754 

3,171 



171 
246 
575 
929 
155 
1,095 



28 SYNTHETIC ORGANIC CHEMICALS, 1963 

TABLE 11 A. -Synthetic organic pigments .- U.S. production and sales, iS63 --Continued 



Product 



Production 



Quantity 



Unit 
value ^ 



TONERS--Continued 

Blue toners, total 

Pigment Blue 1, C.I. 42 595, MA 

Pigment Blue 1, C.I. 42 595, PTA 

Pigment Blue 9, C.I. 42 025, BJA 

Pigment Blue 9, C.I. 42 025, PTA 

Pigment Blue 14, C.I. 42 600, HJA 

Pigment Blue 15, C.I. 74 160, alpha form 

Pigment Blue 15, C.I. 74 160, beta form 

Pigment Blue 19, C.I. 42 750A— 

Pigment Blue 25, C.I. 21 180 

All other 

Green toners, total 

Pigment Green 1, C.I. 42 040, IMA 

Pigment Green 1, C.I. 42 040, PTA 

Pigment Green 2, C.I. 42 040 and 49 005, MA- 
Pigment Green 2, C.I. 42 040 and 49 005, PTA- 

Pigment Green 4, C.I. 42 000, PMA 

Pigment Green 4, C.I. 42 000, PTA 

Pigment Green 7, C.I. 74 260 

Pigment Green 8, C.I. 10 006 

All other 

Brown toners 

Black toners 

LAKES 

Total 

Yellow laies 

Red lakes, total 

Pigment Red 60, C.I. 16 105 

Pigment Red 83, C.I. 58 000 

(Acid Red 26), C.I. 16 150 

All other 

Violet lakes, total 

Pigment Violet 5, C.I. 58 055 

All other 

Blue lakes, total 

Pigment Blue 24, C.I. 42 090— 

All other 

Black lakes: (Natural Black 3\ C.I. 75 291 

All other lakes^ 



1000 
pounds 
7,433 



TS7" 

28 

3 

12 

52 

3,291 

1,734 

1,905 

74 

187 

3,570 



3,067 
188 
201 

127 
116 



3,842 



100 
70 

567 
74 



1,933 



1,901 
32 



104 
887 



1.000 
pounds 
6,654 



1,00 
dolla 



137" 
28 



2,903 
1,430 
1,865 



3,179 



2,761 
162 
135 



3,422 



1,549 



1,518 
31 



97 
773 



19,626 



715 

136 

17 

61 

494 

8,129 

4,321 

4,575 

1,178 

9,828 



62 
34 
242 
225 



8,266 
224 
702 

231 
137 



3,435 



151 
222 
261 



1,834 



1,814 
20 



94 
433 



$2.95 



4.86 
4.86 
4.25 
5.55 
9.15 
2.80 
3.02 
2.45 

5.56 



3.09 
"576?' 
5.67 
5.15 
6.08 



3.91 



2.38 

1.18 



1.00 
1.39 



1.57 
3.36 



2.06 
2.16 
1.40 



1.18 

1.19 

.65 

.97 
.56 



■"■ Calculated from rounded figures. 

Includes all brown, green, and orange lakes and all other black lakes, production of yellow lakes, and sales of 
all other red lakes. 



SYNTHETIC ORGANIC CHEMICALS, 1962 



29 



TABLE 12. — U.S. sales of selected dry full-strength colors, dry extended colors , dry dispersions, 
aqueous dispersions , and flushed colors, 1963 



Selected pigments by commercial forms 



Quantity^ 



Pigment Yellow 12, C.I. 21 090, total 

Dry full-strength toner 

Dry extended toner, dry dispersions, and aqueous dispersions-' * 

Flushed color 

Pigment Yellow 13, C.I. 21 100; Pigment Yellow K, C.I. 21 095; and 

Pigment Yellow 17, C.I. 21 105, total 

Dry full-strength toner 

Dry extended toner and dry dispersions^ 

Aqueous dispersions* 

Flushed color 

Pigment Red 3, C.I. 12 120, total 

Dry full-strength toner and dry extended toner-' 

Aqueous dispersions* 

Flushed color 

Pigment Red A8, C.I. 15 865, total 

Dry full-strength toner 

Dry extended toner 

Do' dispersions 

Aqueous dispersions* and flushed color^ 

Pigment Red 49, C.I. 15 630, barium toner, total 

Dry full-strength toner 

Dry extended toner, dry dispersions, and aqueous dispersions^ * — 
Flushed color 

Pigment Red -49, C.I. 15 630, calcium toner, total 

Dry full-strength toner 

Aqueous dispersions* and flushed oolor^ 

Pigment Red A9, C.I. 15 630, sodium toner, total 

Dry full-strength toner 

Dry extended toner, aqueous dispersions,* and flushed color-' 

Pigment Red 53, C.I. 15 585, barium toner, total^^ 

Dry full-strength toner 

Flushed color 

Pigment Red 90, C.I. 45 380, total 

Dry full-streng-th toner and dry extended toner-* 

Flushed color 

Pigment Violet 3, C.I. 42 535, fugitive, total 

Dry full-streng-th toner and dry extended toner-* 

Aqueous dispersions* and flushed color^ 

Pigment Violet 3, C.I. 42 535, permanent (IMA and PTA), total 

Dry full-streng-th toner 

Dry extended toner 

Dry dispersions and aqueous dispersions^ * 

Flushed color 

Pigment Blue 15, C.I. 74 160, alpha form, total 

Dry full-strength toner 

Dry extended toner 

Dry dispersions 

Aqueous dispersions* 

Flushed color 

Pigment Blue 15, C.I. 74 160, beta form, total 

Dry full-strength toner 

Dry extended toner and dry dispersions^ 

Aqueous dispersions* and flushed oolor^ 



1,000 
pounds 

1,923 



745 

61 

1,117 



1,022 



714 
40 
136 
132 

1,393 



902 

60 

431 



1,902 
35 
32 



2,726 



10 
830 



1,487 
1,073 



190 
107 



971 
486 



247 
133 



221 
28 
25 
85 

2,903 



1,450 
482 
111 
683 
177 

1,430 



"5IT 
27 
490 



1.000 
dollars 

4,365 



1,622 

165 

2,578 



2,796 



1,977 
110 
330 
379 

2,116 



1,358 
99 
659 

3,826 



3,507 
67 



2,829 



1,837 

14 

978 



1,583 
1,057 



203 
124 



1,913 



1,237 
676 



116 
1,149 



377 
203 



617 
150 



8,307 



4,061 
1,608 

346 
1,814 

478 

4,320 



2,S76 
88 
1,356 



See footnotes at end of table. 



30 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 12.-- U.S. sales of selected dry full-strength colors, dry extended colors, dry dispersions, 
aqueous dispersions, and flushed colors, 1963 — Continued 



Selected pigments by commercial forms 



Quantitjr'- 



Unit 
value ^ 



Pigment Blue 19, C.I. U2 750A, total 

Dry full-strength toner and dry extended toner- 
Aqueous dispersions* and flushed color-' 

Pigment Blue 2A, C.I. 42 090^ 

Pigment Green 7, C.I. 7<i 260, total 

Dry full-strength toner 

Dry extended toner and dry dispersions-' 

Aqueous dispersions* 

Flushed color 



1,000 
pounds 

1,865 



1,684 



1,518 



2,761 



1,846 
352 

425 
138 



1.000 
dollars 



4,603 



4,162 



2,156 
8,289 



5,419 

1,253 

1,178 

439 



pound 

$2.47 



1.42 
3.00 



2.94 
3.56 
2.77 
3.18 



■"• Quantity of the various commercial forms is given in terms of dry full-strength toner (or dry lake) content. 
^ Calculated from rounded figures. 

' Separate data on these commercial fonns may not be published without revealing the operations of individual 
companies. 

* Includes presscake. 

Note. — The C.I. (Colour Index) numbers shown in this report are the identifying numbers given In the second edition 
of the Colour Index. 

The abbreviations FMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic) 
acids, respectively. 



MEDICINAL CHEMICALS 31 

Medicinal Chemicals 

Medicinal chemicals include the medicinal and feed grades of all organic chemicals having 
therapeutic value, whether obtained by chennical synthesis, by fermentation, by extraction from 
naturally occurring plant or animal substances, or by refining the technical grade material. They 
include alkaloids, antibiotics, antihistamines, hormones, sulfa drugs, sympathomimetic agents, 
tranquilizers, vitamins, and other therapeutic agents for human or veterinary use and for ani- 
mal feed supplements. 

Statistics on the production of medicinal chemicals are in terms of 100-percent content of 
the medicinal chemical itself, exclusive of all diluents or other materials used in mixing or 
compounding tablets, solutions, and suspensions for consumer use. Except for antibiotics, the 
statistics on sales include only that part of the original (primary) production that was sold in 
undiluted or uncompounded form. Sales of antibiotics include all sales by the primary producers, 
both diluted and undiluted, in bulk or in dosage forms. 

Statistics on U.S. production and sales of medicinal chemicals in 1963 are given in table 
1 3A. Total production of n-iedicinal chemicals in 1963 amounted to 139 million pounds, or 9.2 
percent nnore than the 1 27 million pounds produced in 1 962, and 1 8. 4 percent more than the 118 
million pounds produced in I 961 . Total sales of medicinal chemicals in 1 963 amounted to 1 14 
million pounds, valued at $639 million, compared with sales in 1962 of 104 million pounds, 
valued at $601 million, and sales in 1961 of 92 million pounds, valued at $577 million. Sales in 
1 963 were thus 9.9 percent larger than in 1 962 and 23.2 percent larger than in 1 961 in terms 
of quantity, and 6.4 percent larger than in 1962 and 10.8 percent larger than in 1961 in terms 
of value. 

Since 1962, the data published on medicinal chemicals have been divided into antibiotics 
and benzenoid and nonbenzenoid groups, instead of into cyclic and acyclic groups as in previous 
years. Totals for the cyclic and acyclic groups are shown in this report, however, in order to 
permit comparison of the statistics for 1963 with those for the years prior to 1962. Production 
of cyclic medicinal chemicals in 1963 amounted to 94 million pounds, or 7. 3 percent more than 
the output of 88 million pounds reported for 1962. Sales of cyclic medicinals in 1963 amounted 
to 74 million pounds, valued at $605 million, compared with sales in 1962 of 68 million pounds, 
valued at $567 million. Production of acyclic medicinals in 1963 amounted to 45 million pounds, 
or 13. 5 percent more than the output of 40 million pounds reported for 1962. Sales of acyclic 
medicinals in 1963 amounted to 40 nnillion pounds, valued at $34 million, compared with sales 
in 1962 of 35 million pounds, valued at $33 million. 

Production of antibiotics for all uses in 1963 amounted to 6. 7 million pounds, of which 4. 2 
million pounds was for human or veterinary use and 2. 5 million pounds was for animal feed 
supplements, food preservation, and crop spraying. Sales amounted to 5.5 million pounds, 
valued at $388 million. The most important antibiotics, in terms of value, were the penicillin 
salts and tetracycline. Production of penicillin salts, for all uses, amounted to 957 trillion 
U.S. P. units; sales totaled 715 trillion U.S. P. units, valued at $71.7 million. Production of 
tetracycline for human or veterinary use amounted to 192 nnillion grams of activity; sales 
totaled 150 million grams of activity, valued at $66. 5 million. 

Production of benzenoid medicinals in 1963 amounted to 76. million pounds; sales totaled 

59.7 million pounds, valued at $151 million. The benzenoid medicinal chemicals that were pro- 
duced in largest quantity in 1963 were acetylsalicylic acid (aspirin), 28.4 million pounds; sali- 
cylic acid, 12.1 million pounds; and sulfa drugs, 4. 6 million pounds. 

Production of nonbenzenoid medicinals in 1963 amounted to 56. 5 million pounds; sales 
totaled 48.7 nnillion pounds, valued at $100 million. The most innportant nonbenzenoid medi- 
cinal chemical, in terms of quantity, was choline chloride, production of which amounted to 

23.8 million pounds. 

Production of all vitamins, both benzenoid and nonbenzenoid, amounted to 14. 9 million 
pounds in 1963; sales amounted to 10.5 million pounds, valued at $64.5 million. The most im- 
portant vitamins, in ternns of value, were vitamins A, B22' '''^d C. Production of vitamin A 
alcohol and esters amounted to 499 trillion U.S. P. units; sales totaled 448 trillion U.S. P. units, 
valued at $22.5 million. Production of vitamin Bj^ amounted to 857,000 grams; sales amounted 
to 516,000 grams, valued at $8.5 million. Production of vitamin C (ascorbic acid) and deriva- 
tives announted to 7.9 million pounds; sales totaled 5.2 million pounds, valued at $10.8 million. 



See also table 13B, pt. ni, which lists these products alphabetically and identifies the manufacturers, and uble 23 in appendix A, 
which shows imports of coal-tar medicinal chemicals and pharmaceuticals durmg the years 1961-63. 



32 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE ISA. --Medicinal chemicals: U.S. production and sales , 1963 



[Listed below are all synthetic organic medicinal chemicals for which any reported data on production or sales may 
be published. (Leaders are used where the reported data are accepted in confidence and may not be published or 
where no data were reported.) Table 13B in pt. Ill lists alphabetically all medicinal chemicals for which data on 
production or sales were reported and identifies the manufacturer of each] 



Production 



Grand total 

Cyclic'' - 

Acyclic* 

ANTIBIOTICS^ 

Total— - 

For human or veterinary use, total 

Bacitracin • 

Dihydrostreptomycin 

Neomycin, base 

dl-a-Ehenoxyethylpenicillin and potassium salt 

Potassium penicillin G 

Procaine penicillin G 

Other penicillin G salts 

Tetracycline 

All other' - -- 

For animal feed supplements, food preservation, and crop 

spraying, total 

Bacitracin 

Procaine penicillin G 

All other* — — 

benzenoid' 

Total - - 

Alialoids and related products, total 

Dihydrocodeinone bitartrate 

Homatropine methyl bromide 

All other 

p-Aminobenzoic acid and derivatives 

Antihistamines, total 

2- [p-Chloro-a -(2-dimethylaminoethyl)benzyl] pyridine 
(Chlorpheniramine) maleate 

2- [ 3- (Dimethylamino ) -1-phenylpropyl] pyridine 

( Pheniramine ) maleate 

All other 

Antimony, arsenic, bismuth, and mercury compounds, total ^ 

Bismuth ' subgallate 

All other 

Barbiturates : 

5-Ethyl-5-phenylbarbiturio acid (Phenobarbital) 

5-Ethyl-5-phenylbarbituric acid, sodium salt 

Benzothiadlazlne dioxide derivatives 

E^es, medicinal 

Estrogens, steroid and nonsteroid 

p-I^droxyacetanilide 

p-H,rdroxybenzoic acid esters: 

Ifethyl p-hydroxybenzoate 

Propyl p-hydroxybenzoate 

Imidazoline derivatives 

Hienols and derivatives, total 

Gualacol glyceryl ether-^ 

All other 

See footnotes at end of table. 



139,196 



9A, 125 
45,071 



6,689 



';,180 

— W 



■■ 1 
323 I 

637 

57. 

2,649 



2,509 



135 

352 

1,972 



75,975 



705 
287 



250 
2,346 



W 
2,308 



351 
10 



277 

132 



26 
1,748 



1,000 
pounds 
113,920 



73,606 
40,314 



5,494 



3,170 



440 
50 
19 

269 

524 
38 

330 
1,492 



2,324 



172 

319 

1,833 



59,703 



634 
169 



281 

10 



247 
139 



(') 



1,000 
dollars 
638,955 



605,080 
33,875 



388,112 



330,916 

17273" 

5,461 
4,881 
4,353 
17, 163 
11,473 
10,687 
66,473 
209,150 



57,196 



3,875 
2,382 
50,939 



150,862 



4,020 



300 

60 

3,660 

2,284 

6,046 



489 
5,231 



739 

41 

4,756 

422 
557 

467 
322 



1,324 



95 
1,229 



MEDICINAL CHEMICALS 
TABLE 13A.—Medtcin3l chemicals: U.S. production and sales, 7 965 --Continued 



33 



Production-'- 



Quantity 



BENZENOID'— Continued 

8-Quinolinol and derivatives, total 

5,7-Diiodo-8-quinolinol 

8-Quinolinol 

S-Quinolinol benzoate 

8-Quinolinol sulfate 

All other 

Salicylic acid and derivatives, total 

Acetylsalicylic acid (Aspirin) 

Salicylic acid 

Salicylic acid salts 

All other 

Sulfonamides and sulfones, total 

Phenylsulfonylurea derivatives 

Sulfa drugs 

All other 

Sympathomimetic (Adrenergic) agents, total 

d-, 1-, and dl-N,a-Dimethylphenethylamine (Desoxyephed- 

rine) base hydrochloride 

d- and dl-a-Methylphenethylamine (Amphetamine and 

Dextroamphetamine) base and salts 

Norephedrine hydrochloride 

Phenylephrine hydrochloride 

All other 

Tranquilizers, total 

Phenothiazine derivatives 

All other 

Vitamins, total 

B2 (Riboflavin) 
Bi2 (All grades )^°- 

K3 (Menadione) 

Niacin (Nicotinic acid) (All grades) 

Niacinamide (Nicotinamide) 

All other 

All other benzenoid medioinals 

NONBENZENOID^^ 

Total 

Amino acids 

Barbiturates 

Bile acids and salts 

Bismuth and mercury compounds^ 

Camphor and derivatives, -total 

Camphoric acid 

All other 

Carbohydrates and derivatives, total 

Calcium gluconate (including feed grade) 
All other — 

Choline derivatives, total 

Choline bitartrate 

Choline chloride, all grades 

Choline dihydrogen citrate 

Succinylcholine dlchloride 

All other— - 



1.000 
pounds 



37 
103 



4A,541 



28,400 

12,055 

1,459 

2,627 

6,412 



4,639 
791 



57 
171 
45 



214 
4,282 



2,542 

783 
361 

13,180 



56,532 



3,057 
562 
253 



608 
286 



24,172 



207 
23,809 
81 



1,000 
dollars 



39,300 



24,693 

10, 525 

1,655 

2,427 

2,012 



2,012 
287 



166 
57 



3,141 



555 

1 

3 

1,629 

773 

180 

11,910 



48,723 



3,283 
189 



98 
838 



522 
316 



186 
22,973 



32 
221 



21,503 



13,467 
4,105 
1,207 
2,724 

9,977 



9,977 
3,982 



1,311 

1,772 

754 



170 
117 



5,952 
8,519 
21 
1,884 
1,456 
3,873 

71,969 



99,981 



4,256 
1,607 



93 

1.007 



313 
694 



180 

5,102 

73 



See footnotes at end of table. 



34 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 13A. — Medicinal chemicals : U.S. production and sales, 1963 — Continued 



Production 



Sales 2 



Quantity 



Unit 
value ^ 



NONE ENZENOID^^ — Continued 

Hormones, total 

Hydrocortisone alcohol and acetate 

Prednisone 

All other 

Ifydantoin derivative: Allantoin 

Piperazine and derivatives, total 

Piperazine ■ 

Piperazine hydrochloride 

Piperazine phosphate 

All other 

Purine derivatives, total ^ 

Caffeine, natural and synthetic 

Theophylline ethylenediamlne ( Aminophylline ) • 
All other 

Tranquilizers 

Trihalogenated compounds 

Uracil derivatives 

Vitamins, total 

A, total^° -• 

A palmltate, except feed grade 

All other 

C (Ascorbic acid) and derivatives, total 

Ascorbic acid 

All other 

Dj (Irradiated ergosterol)''-^ 

Pantothenic acid and derivatives, total 

Pantothenic acid, dl-calcium salt 

All other 

All other nonbenzenoid vitamins 

All other nonbenzenoid medlcinals 



1,000 
pounds 



1.000 
pounds 



33 



1.000 
dollars 
18,742 



pound 

$567.94 



24 

22 

3,546 



2,174 

389 

16,179 

139 

3,255 



271.75 
389.00 
674.12 



543 

174 

4,4^0 

2,399 



2,313 
44 
42 

1,063 
43 



10,592 



921 

578 

166 

1,881 

2,271 



900 

676 

165 

1,514 

5,667 



2,214 



57 



7,378 



557 

180 

377 

7,851 

6,459 

1,392 

1 

1,573 

1,279 

294 

610 

8,108 



506 

170 

336 

5,196 

4,085 

1,111 

1 

1,112 

875 

237 

563 

6,791 



4,830 



2,912 
137 
231 

42,769 



3.04 

3.34 

231.00 

5.80 



22,459 

7,469 

14,990 

10,849 

8,354 

2,495 

242 

3,587 

2,129 

1,458 

5,632 

13,722 



44.39 

43.94 

4^.61 

2.09 

2.04 

2.25 

242.00 

3.23 

2.43 

6.15 

10.00 

2.02 



^ The data on production are those for medicinal chemicals in bulk; they do not include finished preparations, 
such as tablets, capsules, and ampoules, which are manufactured from bulk chemicals. 

^ Except for antibiotics, sales include only that part of the original production which is sold in undiluted or 
uncompounded form, including that sold in bulk and that sold in packages (tablets, ampoules, etc.). Sales of antibi- 
otics include all forms (both undiluted or unoonjiounded and diluted or conjjounded ) , Including that sold in bulk and 
that sold in packages. 

-^ Calculated from rounded figures. 

* Since 1962, medicinal chemicals have been divided into antibiotics, benzenold, and nonbenzenoid groups. Instead 
of into cyclic and acyclic groups, as in previous reports. Totals for the cyclic and acyclic groups are shown in this 
report in order to facilitate comparison of the statistics for 1963 with those for the years prior to 1962. 

For statistical purposes, reported quantities of antibiotics have been converted from grams of activity or U.S. P. 
units to pounds by means of the following conversion factors: Procaine penicillin G, 453.6 million unlts=l pound; 
penicillin V salts, 768.9 million units=l pound; other penicillin salts and hygromycln B, 756 million units=l pound; 
aterrlmln and bacitracin, 22.7 million units=l pound; polymyxin B sulfate, 2,812.3 million units=d pound; all other 
antibiotics, 453.6 grams of activlty=l pound. Statistics for all individually publishable antibiotics are given in 
the following tabulation in terms of million U.S.P. units (MU), billion U.S. P. units (BU), or kilograms of activ- 
ity (Kg.): 



Sales 



Quantity 



Unit value 



Bacitracin (MU), total 

For human or veterinary use- 
For other uses 

Footnotes continued on page 35. 



4,425,947 



217,927 
4,208,020 



4,102,405 



187,882 
3,914,523 



5,150 



$1.26 



1,275 
3,875 



MEDICINAL CHEMICALS 
Footnotes for table 13A — Continued 



35 



Quantity 



Value 



Dlhydrostreptomycln, for human or veterinary 

use (Kg. ) 

Neomycin base, for human or veterinary use (Kg.) 



Penicillin salts, (BU), total 

dl-a-Ehenoxyethyl penicillin and potassium salt, 
for human or veterinary use 

Potassium penicillin G, for human or 

veterinary use 

Procaine penicillin G, total 

For human or veterinary xise 

For other uses 

Other penicillin G salts, for human or 
veterinary use 

Other penicillin salts, for all uses 



36,372 
957,013 



199,57-; 
22,715 



7U,637 



1.000 

dollars 

5,^61 

^,881 
71,690 



$27.36 
214.88 



Streptomycin, for all uses (Kg.) 

Tetracycline, for human or veterinary use (Kg.)- 



243,838 
448,558 
288,962 
15y,596 

43,080 
221,537 

496,040 
192,175 



14,011 

203,119 
382,651 
237,894 
144, 757 

28,350 
86,506 

394,814 
149,717 



4,353 

17, 163 
13,855 
11,473 
2,382 

10, 687 
25,632 

9,340 
66,473 



310.68 

84.50 
36.21 
48.23 
16.46 

376.97 
296.30 

23.66 
443.99 



Includes "All other" penicillin salts and streptomycin, for wMch separate statistics cannot be published by use 
category, because publication might reveal the operations of individual companies. Statistics for "All other" peni- 
cillin salts and streptomycin are given in terms of grams or U.S. P. units In footnote 5 above. 

' The term "benzenoid, " as used in this report, describes any cyclic medicinal chemical, other than antibiotics, 
whose molecule contains any one or more of the following types of rings: 6-membered carbocyclic rings with conjugated 
double bonds, e.g., the benzene ring or the quinone ring; 6-membered heterocyclic rings with 1 hetero atom and con- 
jugated double bonds, e.g., the pyridine ring; or 6-membered heterocyclic rings with 2 hetero atoms and conjugated 
double bonds, except the pyrimidine ring, e.g., the pyrazlne ring or the pyridazine ring. 

Production of all antimony, arsenic, and bismuth compounds, both benzenoid arxJ nonbenzenoid , amounted to 
2,289,000 pounds. Production of all mercury compounds, both benzenoid and nonbenzenoid, amounted to 82,000 pounds. 

' Sales of imidazoline derivatives amounted to 442 pounds. 

'■° For statistical purposes, reported quantities of vitamins A, B^j, and D2 have been converted from grams or 
U.S. P. units to pounds by means of the following conversion factors: Vitamin A acetate, 1.307 billion units=l pound; 
vitamin A alcohol, 1.510 billion units=l pound; vitamin A palmitate, 0.816 billion units=l pound; vitamin B12, 
453.6 grams=l pound; vitamin Dj, 18.14 billion units=l poimd. Statistics for these vitamins are given in the follow- 
ing tabulation in terms of grams or U.S. P. units: 



Unit of 
quantity 



Quantity 



Unit 
value 



Vitamin A, total 

Palmitate, except feed grade- 
All other 

Vitamin B12 --- 

Vitamin D2 



Billion units 

do 

do 

Grams 

Billion units 



498,908 



146,891 
352,017 



857,191 
20,341 



447, 701 



139,126 
308,575 



515,802 
15,076 



l.UOO 
dollars 
22,459 



7,469 
14,990 



8,519 
242 



$50.17 



53.69 
48.58 



16.52 
16.05 



The term "nonbenzenoid, " as used in this report, describes any cyclic or acyclic medicinal chemical, other than 
antibiotics, whose molecule does not contain any of the types of rings described in footnote 7 above. All acyclic 
compounds and any cyclic compound whose molecule contains only one or more of the following types of rings are clas- 
sified as "nonbenzenoid": Fully or partially reduced rings, e.g., the plperldlne ring or the cyclohexadiene ring; 
rings with more or less than 6 members, e.g., the imidazole ring or the azepine ring; heterocyclic rings with mor^ 
than 2 hetero atoms, e.g., the triazine ring; or the pyrimidine ring. 



36 



SYNTHETIC ORGANIC CHEMICALS, 1963 



Flavor and Perfume Materials 

Flavor and perfume materials are chemicals- -with desirable flavors or odors--that are 
used in the manufacture of foods, beverages, cosmetics, and soaps, and to disguise unpleasant 
odors in industrial products. This report includes data on materials derived from natural 
products by actual chemical processes and from coal tar; it does not include data on purely 
natural products, such as floral essences, essential oils, and other materials that are obtained 
by simple extraction or by distillation from natural vegetable and animal sources. 

The flavor and perfume materials covered in this report are grouped as either cyclic or 
acyclic materials, according to their chemical structure. Cyclic materials are further classi- 
fied as (1) benzenoid and naphthalenoid, and (2) terpenoid, heterocyclic, and alicyclic. Statistics 
on production and sales of flavor and perfume materials in 1963 are given in table 14A. 

Production of flavor and perfume materials in 1963 announted to 73.8 million pounds--3.3 
percent less than the output of 76.3 million pounds in 1962. Sales in 1963 amounted to 67. mil- 
lion pounds, valued at $77. 4 million, compared with 63. 4 million pounds, valued at $76.0 nnil- 
lion, in 1962. 

Production of cyclic flavor and perfunne materials in 1963 amounted to 41.3 million pounds-- 
3,4 percent less than the 42.8 million pounds reported for 1962. Sales of cyclic flavor and per- 
fume materials in 1963 were 34. 7 million pounds, valued at $51.4 million, compared with 32. 
million pounds, valued at $47. 3 million, in 1962. The individual chemical in the cyclic group 
that was produced in the greatest volume in 1963 was methyl salicylate (4. I million pounds). 
Production of synthetic sweeteners, as a group, accounted for 5.7 million pounds. 

The output of acyclic flavor and perfume materials in 1963 amounted to 32.4 million 
pounds--3.2 percent less than the 33.5 million pounds reported for 1962. By far the most im- 
portant of the acyclic materials was monosodium glutamate, production of which totaled 
30.4 million pounds. Sales of acyclic flavor and perfume materials in 1963 amounted to 
32. 3 million pounds, valued at $25.9 million, compared with 31 . 4 million pounds, valued at 
$28.7 million, in 1962. 

TABLE I'iA. --Flavor and perfume materials.- U.S. production and sales, 1963 



[ Listed below are all synthetic organic flavor and perfume materials for which any reported data on production or 
sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be pub- 
lished or where no data were reported.) Table 14B in pt. Ill lists alphabetically all flavor and perfume materials 
for which data on production or sales were reported and identifies the manufacturer of each] 



Unit value-"- 



Grand total 

FLAVOR AND PERFIME MATERIAI£, CYCLIC 
Total 

Benzenoid and Naphthalenoid 
Total 

"i-Allylveratrole (Eugenyl methyl ether) 

Ane thole (p-Propenylanisole) 

p-Anis aldehyde ( p-Methoxybenzaldehyde ) 

Benzophenone^ 

Benzyl acetate 

Benzyl alcohol^ 

Benzyl cinnamate 

Benzyl propionate 

Cinnamaldehyde 

Cinnamyl alcohol 

a, -x -Dimethy Iphenethyl acetate 

2-Ethoxynaphthalene (Ethyl p -naphthyl ether) 

Eugenol 

Isobutyl phenylaoetate (Isobutyl a-toluate) 

Isobutyl salicylate 

Isoeugenol 

Isopentyl salicylate (Amyl salicylate) 

See footnotes at end of table. 



73,768 



^1,338 



19, 93-; 



13 

1,393 

806 

288 

1,183 

1,889 

5 

11 

851 

215 

13 

14 

327 

32 

69 

102 

343 



1.000 
pounds 



67,014 



34,671 



18,490 



10 

1,284 

688 

205 

1,274 

2,080 

4 

11 

815 

181 

18 



1,000 
dollars 
77,386 



51,446 



22,605 



32 

1,007 

1,022 

215 

521 

844 

14 

13 

566 

245 



57 
265 
293 



$1.15 



1.48 

1.05 

.41 

.41 

3.47 

1.14 

.69 

1.35 

4.90 

1.83 

.93 

1.00 

2.93 

.69 



*See also table 14B, pi. 111. which lists these products alphabetically and identifies the manufacturers, and table 23 in appendix A, 
which shows imports of coal-tar flavor and perfume materials during the years 1961-63. 



FLAVOR AND PERFUME MATERIALS 
TABLE lAA. — Flavor and perfume materials: U.S. production and sales , 1963--Contmued 



37 



Material 



Production 



Sales 



Quantity 



Unit value-'- 



FLAVOR AND PERFUME MATERIAl^, CYCLIC— Continued 
Benzenoid and Naphthal eno id- -Continued 

p-Isopropyl-d-methylhydrocinnanialdehyde (Cyclamen aldehyde) 

Methyl anthranilate 

Methyl cinnamate 

Methyl phenylacetate (Methyl a-toluate) 

Methyl salicylate (Synthetic wintergreen oil) 

a-Pentylcinnamaldehyde (a-Amylcinnamaldehyde) 

Phenethyl acetate 

Phenethyl phenylacetate (Phenethyl a -tolimte) 

■i-Propenylveratrole (Isoeugenyl methyl ether) 

All other benzenoid and naphthalenoid materials 

Terpenoid, Heterocyclic, and Alicyclic 

Total — - 

Cedrol 

Cedryl acetate 

Citral (Geranial) 

Citronellol 

Citronellyl acetate 

Citronellyl formate 

Coumarin 

Essential oils, chemically modified 

Geraniol 

Geranyl acetate 

Geranyl formate 

Hydrocoumarin (3,4-Dihydrocoumarln) 

Hydroxycitronellal 

Hydroxycitronellal, dimethyl acetal 

lonones 

Isobomyl acetate 

Linalool 

Unalyl acetate 

Menthol, synthetic, tech. and U.S.P 

Methylionones, total 

a,p, Y, a^i^ 6) individually 

a and 3 , mixed 

Nerol 

Piperonal (Heliotropin) 

Rhodinol 

Sweeteners, synthetic 

Terpineols 

Terplnyl acetate 

Vetivenyl acetate 

All other terpenoid, heterocyclic, and alicyclic materials- 

FLAVOR AND PERFUME MATERIALS, ACYCLIC 

Total ^ — 

Allyl hexanoate (Allyl caproate) 

Decanal ( Capraldeliyde ) (Cio) 

£thyl butyrate 

Ethyl hexanoate (Ethyl caproate) 

Glutamic acid, monosodium salt (Monosodium glutamate) 

4-Hydroxyundecanoic acid, Y-laotone (Y-Undecalactone) 

Isopentyl butyrate (Aayl butyrate) 

Lauraldehyde (Dodecyl aldehyde) (Cij) 

All other acyclic materials 

Calculated from the unrounded figures. 
Includes some technical grade. 



197 

335 

98 

22 

A, 065 

i75 

87 



7,086 



21,'iOA 



84 
229 
539 

17 

22 
953 
189 
551 

53 
7 

23 

506 

6 

293 

1,461 

423 
347 



317 
142 

12 

272 

13 

5,715 

3,284 

610 

20 

5,316 



32,430 



00 


1,000 


ds 


dollars 


179 


514 


97 


211 


82 


144 


13 


11 


3,828 


2,098 


463 


646 


76 


82 


6 


20 


8 


32 


6,269 


13,098 



16,181 



28,841 



23 
901 
183 
420 



482 
5 
254 
1,318 
447 
268 
321 

406 



268 
138 

5 

247 

11 

4,853 

3,148 

688 

16 

1,426 



32,343 



133 

194 

386 

992 

46 

79 

2,295 

202 

782 

117 

26 

89 

2,712 

35 

1,146 

527 

1,163 

1,001 

1,320 

2,042 



1,348 
694 

50 
515 
310 

6,745 
811 
299 
370 

4,454 



25,940 



24 


22 


68 


12 


11 


46 


261 


245 


166 


6 






30,393 


30,453 


23,714 


6 


6 


31 


61 


53 


43 




16 


101 


1,667 


1,537 


1,771 



38 



SYNTHETIC ORGANIC CHEMICALS, 1963 



Plastics and Resin Materials 

Plastics and resin materials are condensation or polymerization products of organic 
chemicals containing necessary fillers, plasticizers, and extenders. At some stage in their 
manufacture they exist in such physical condition that they can be shaped or processed by the 
application of heat and pressure. Some types of plastics may be molded, cast, or extruded into 
finished or semifinished forms. Other types are used as adhesives, for the treatment of textiles 
and paper, and for protective coatings. Still other types of plastics materials may be processed 
into sheets, rods, and tubes, which are further manufactured into finished articles. Except for 
vinyl resins, the statistics given in the foUcrwing tables are based on the total weight of the mate- 
rials, excluding liquids. Statistics for vinyl resins are given on the basis of resin content. 

Statistics on production and sales of plastics and resins in 1963 are given in table 15A' 
according to chemical composition and broad end uses. In general, this table follows the outline 
of the Tariff Commission's monthly report on the production and sales of synthetic plastics and 
resin materials (S.O.C. Series P-63). However, data are included for plastics materials which 



TABLE 15A. — Plastics and resin materials: U.S. production and sales, by chemical classes 

and uses, 1963 

[Quantities and values are given in terms of the total weight of the materials (dry basis). Listed below are all 
plastics and resin materials for which any reported data on production or sales may be published. (Leaders are 
used where the reported data are accepted in confidence and may not be published or where no data were reported . ) 
Table 15B in pt. Ill lists all plastics and resin materials for which data on production or sales were reported 
and identifies the manufacturer of each] 



Kind and use 



Quantity 



Unit value ■"■ 



Grand total 

Plastics and resin materials, benzenoid 

Plastics and resin materials, nonbenzenoid 

THERMOSETTING RESINS 

Total 

Alkyd resins, total 

Protective coatings : 

Phthalic anhydride type, total 

Unmodified 

Modified 

Polybasic acid type 

All other uses^ 

Sales for export 

Coumarone-indene and petroleum polymer resins, total- 
Floor tile 

Rubber oompoiinding 

All other uses 

Sales for export 

Epoxy resins : 

Unmodified, total 

Bonding and adhesives 

Protective coatings 

Reinforced plastics 

All other uses 

Sales for export 

Madifled— — 

Polyester resins,* total 

Reinforced plastics : 

Sheets, flat and corrugated 

All other 

Surface coatings 

All other uses 

Sales for export 

Silicone resins 

See footnotes at end of table. 



i.OOO pounds, 
8,968,^73 



3, "489, 361 
5,479,112 



2,715,676 



605,949 



512,164 
363,048 
149,116 
69,552 
24,233 



343,742 



109,340 
57,499 
176,903 



81,404 



5,874 
254,858 



9,878 



1,000 pounds, 
dry basis ^ 
7,516,137 



1,000 
dollars 

2,003,119 



2,886,387 
4,629,750 



2,158,410 



309,204 



230,367 
162,727 
67,640 
51,967 
22,567 
4,303 

325,321 



96,700 

55,207 

146,710 

26,704 

82,140 
10,870 
39,263 
10,823 
13,536 
7,648 
2,825 

228,592 



35,141 
141,392 

1,840 
44,336 

5,883 

9,622 



736,760 
1,266,359 



604,927 



83, 846 



63,676 
43,030 
20,646 
10,417 
8,198 
1,555 

31,587 



52,197 



2,642 
77,211 



22,832 



$0.27 



.26 
.27 



.94 

.34 



''See also table ISB, pt. in, which lists these products according to chemical composition, and identifies the manufactutets. 



PLASTICS AND RESIN MATERIALS 

TABLE 15A. — Plastics and resin materials.- U.S. production and sales, by chemical classes 
and uses, i965--Continued 



39 



Quantity 



Unit 
value"'' 



THERMOSETTING RESINS— Continued 

Phenolic and other tar acid resins, total 

Molding materials 

Bonding and adhesive resins for: 

Laminating 

Coated and bonded abrasives 

Friction materials 

Thermal insulation 

Foundry or shell molding 

Plywood 

Fibrous and granulated wood 

All other bonding and adhesive iises 

Protective coatings, unmodified and modified — 

All other uses 

Sales for export 

Polyurethane and diisocyanate resins 

Rosin modifications, total 

Rosin and rosin esters, unmodified (ester gums 
All other 

Styrene-allsyd polyesters and styrenated alkyds-- 

Urea and melamine resins, total 

Textile treating and coating resins 

Paper treating and coating resins 

Bonding and adhesive resins for: 

Laminating 

Plywood 

Fibrous and granulated wood 

All other bonding and adhesive uses 

Protective coatings 

All other uses (including molding) 

Sales for export 

All other thermosetting resins* 

THERMDPLASTIC RESINS 

Total -- 

Cellulose plastics materials, total 

Sheets, continuous: 

Under 0.003 gage 

0.003 gage and over 

All other sheets, rods, and tubes 

Molding and extrusion materials and exports 

Polyamide resins'' 

Styrene type plastics materials: 

Production and sales 

Used by reporting companies in processing 

Sales and use, total 

Jtolding 

Textile and paper treating and coating 

Emulsion paint 

Extrusion 

All other uses 

Sales for export 

See footnotes at end of table. 



1,000 
pounds, 
dry basis^ 
7i0,51<; 



229,309 

105,"i23 
19,308 
27,503 

103,569 
49,009 
71,718 
21,8A5 
30,903 
31,959 
49,968 



50,394 
95,461 



3,121 
37,340 

6,281 

517,847 



52,638 
48,273 

42,922 

120,305 
67,187 
15,835 
50,891 

119,796 



3,474 



6,252,797 



151,979 



17,957 
33,852 
4,769 
95,401 

61,625 

1,494,130 



1,000 

pounds 

dry basi 

601,811 



207,764 

63,749 
17,127 
24,559 
44,295 
44,478 
69,544 
21,547 
26,880 
22,504 
46,498 
12,866 

47,590 



159,042 



54,525 
34,329 



6,531 
453,608 



33,356 
19,076 



46,525 
35,597 

27,031 
110,434 
58,892 
15,165 
34,858 
108,505 
16,601 

2,312 



5,357,727 



9,860 
9,216 



1,711 
119,929 



1,498 



1,398,192 



144,387 



99,592 



16,235 

30,556 

5,586 

92,010 

51,435 

1,361,610 
114,269 

1,475,879 
696,456 
115,376 
43,608 
191,397 
299,115 
129,927 



48,786 
315,338 



40 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 15A. — Plastics and resin materials: U.S. production and sales , by chemical classes 
and uses, 1963 — Continued 



Kind and use 



Production 



Quantity 



Unit value ^ 



THERMOPLASTIC RESINS--Continued 

Vinyl resins (resin content basis): 
Polyvinyl acetate: 

Production and sales 

Used by reporting companies in processing 

Sales and use, total 

Bnulsion paint 

Adheslves 

Bonding and sizing 

All other uses 

Sales for export 

Polyvinyl chloride and copolymer resins : 

Production and sales 

Used by reporting companies iii processing 

Sales and use, total 

Calendering : 

Film, under 6 mils 

Sheet, 6 mils and over 

Flooring 

Coating, bonding, and adhesives : 

Paper and textile coating (including 

calendering) 

Flooring 

Extrusion: 

Wire and cable 

Garden hose 

All other extrusions 

Molding : 

Records 

Slush and rotational molding 

All other moldings 

All other uses 

Sales for export 

All other vinyl resins : 

Production and sales 

Used by reporting companies in processing 

Sales and use, total 

Polyolefin plastics materials: 

Polyethylene, density 0.94-0 and below: 

Production and sales 

Used by reporting companies in processing 

Sales and use, total 

Injection molding 

Blow molding 

Extrusions: 

Film and sheet 

Wire and cable coating 

Extrusion coating on paper and other substrates- 
Pipe 

All other extrusions 

All other iises 

Sales for export 

Polyethylene, density over 0.9A0: 

Production and sales 

Used by reporting companies in processing 

Sales and use, total 

Injection molding 

Blow molding 

Extrusions : 

Film and sheet 

Wire and cable coating 

Pipe 

All other extrusions (including extrusion 

coating and filament) 

All other uses 

Sales for export 



2iO,6A8 



1,385,8A5 



133,833 



1,754,041 



515,905 



1,000 



194,609 
41,278 

235,887 
79,110 
99,304 
12,628 
42,299 
2,546 

1,207,102 

158,832 

1,365,934 

83,059 
200,479 
205,140 



128,413 
52,314 

183,654 

8,349 

125,179 

78,481 
33,633 
18,803 
206,022 
42,408 

90,663 
40,008 
130,671 



1,515,617 
236,068 

1,751,685 
187,331 
35,033 

617,877 
172,073 
209,255 
27,643 
18,642 
186,808 
297,023 

392,541 
61,852 

454,393 
71,513 

195,971 

19,522 
13,373 
16,521 

21,180 
72,056 
4A,257 



1,000 
dollars 
61,760 



218,114 



pound 



57,875 



275,339 



91,972 



See footnotes at end of table. 



PLASTICS AND RESIN MATERIALS 

TABLE 15A. — Plastics and resin materials: U.S. production and sales, by chemical classes 
and uses, 1963 — Continued 



Kind and use 



Production 



Quantity 



Unit value-'- 



THEKMOPLASTIC RESINS—Continued 

Polyolefin plastics materials — Continued 
Polypropylene : 

Production and sales 

Used by reporting companies in processing- - 

Sales and use, total 

Molding 

Extrusion 

All other uses (including export) 

All other thermoplastic resins-"-" 






196,910 



317,881 



1.000 
pounds , 

146, A86 

26,019 

' 172,505 

' 8^,-^20 

' 67,349 

' 20,736 

253,277 



1.000 
dollars 



42,463 



186,953 



.74 



^ Calculated from rounded figures. 

^ For the purposes of this report, "dry basis" is defined as the total weight of the material, including resin, 
plasticizers, fillers, extenders, colors and stabilizers, and excluding water, solvents, and other liquid diluents. 

■' Includes saturated polyesters for urethanes. 

* The term "polyester resins" includes unsaturated allsyds oopolymeri zed with a monomer such as styrene, and 
polyallyl resins such as diallyl phthalate and allyl diglycol carbonate. 

' Production includes 368 million pounds of urea- formaldehyde type, and 149 million pounds of melamlne-formalde- 
hyde type. 

' Includes data for acetone-formaldehyde resins, furane resins, and other thermosetting resins, which were pro- 
duced in small quantities. 

' Includes both nylon and non-nylon types. 

5 Production includes straight polystyrene, 515 million pounds; rubber modified polystyrene, 564 million pounds; 
styrene-butadiene copolymers, 188 million pounds; and all other, including ABS and SAN, 227 million pounds. 

' Partially estimated. 
^° Includes data for acrylic, fluorocarbon, polycarbonate, polyether, polyoxymethylene, polyterpene, and other 
thermoplastic resins. 



are not covered in the monthly report and for a number of smaller producers that do not report 
monthly. The monthly data for 1963, moreover, were returned to the reporting companies for 
verification or correction. In consequence, many of the figures in the following table are revised 
from those shown in the monthly release of March 20, 1964, which contained yearend cumulative 
totals for 1963. The figures in the thermoplastics section of the table under "Used by reporting 
companies in processing" represent captive use of the materials. The quantities reported under 
"Sales and use" in this section include data for captive consumption, and for outside sales as de- 
fined in the introduction to this volume. 

In 1963, total U.S. production of synthetic plastics and resin materials, including cellulosics, 
amounted to 8,968 million pounds, or 10.7 percent more than the 8, 100 million pounds reported 
for 1962. Sales of synthetic plastics and resin materials in 1963 amounted to 7,516 million 
pounds, valued at $2,003 million. Production of benzenoid plastics and resin materials in 1963 
amounted to 3,489 million pounds, and that of nonbenzenoid materials, to 5,479 million pounds. 
These figures compare with production in 1962 of 3,159 million pounds, and 4,941 million pounds, 
respectively. Production of all thermosetting resins in 1963 was 2,716 million pounds, and that 
of thermoplastic resins was 6.253 million pounds. 

In 1963, polyethylene, polystyrene, and polyvinyl chloride resins were the materials pro- 
duced in the largest volume. The total output of high-density and low-density polyethylene resins 
in 1963 amounted to 2,270 million pounds, compared with 2,016 million pounds in 1962. Sales of 
polyethylene resins in 1963 were 1,908 million pounds, valued at $367 million. Production of 
polystyrene and copolymer resins in 1963 was 1,494 million pounds, compared with 1,274 mil- 
lion pounds in 1962. Sales of styrene resins in 1 96 3 were 1,362 million pounds, valued at $315 
million. The output of polyvinyl chloride and copolymer resins in 1963 amounted to 1,386 mil- 
lion pounds, compared with 1,215 million pounds in 1962. Sales of polyvinyl chloride resins in 
1963 totaled 1,207 million pounds, valued at $218 million. Other synthetic plastics and resin 
materials produced in 1963 in large volume were phenolic and other tar acid resins (741 nnillion 
pounds), alkyd resins (606 million pounds), urea and melamine resins (518 million pounds), 
coun-iarone-indene resins (344 million pounds), polyester resins (255 million pounds), and poly- 
vinyl acetate resins (241 nnillion pounds). 



749-026 O - 64 ■ 



42 



SYNTHETIC ORGANIC CHEMICALS, 1963 
Rubber- Processing Chemicals 



Rubber -processing chemicals are organic compounds that are added to natural and synthetic 
rubbers to give them qualities necessary for their conversion into finished rubber goods. In this 
report, statistics are given for cyclic and acyclic compounds, by use--such as accelerators, 
antioxidants, and peptizers. Statistics on production and sales of rubber-processing chemicals 
in 1963 are given in table 16A.^ 

Production of rubber-processing chemicals as a group in 1963 amounted to 234 million 
pounds, or 2. 3 percent more than the 228 million pounds reported for 1962. The larger total 
output of rubber-processing chemicals in 1963 is attributable principally to increased produc- 
tion of antioxidants and thiuram and thiazole accelerators. Sales of rubber-processing chemi- 
cals in 1963 amounted to 177 million pounds, valued at $119 million, compared with 172 million 
pounds, valued at $114 million, in 1962. 



TABLE 16A. — Rubber-processing chemicals: U.S. production and sales , 1963 

[listed below are all rubber-processing chemicals for which any reported data on production or sales may be pub- 
lished. Table 16B in pt. Ill lists separately all rubber-processing chemicals for which data on production or 
sales were reported and identifies the manufacturer of eaohl 



Production 



Quantity 



Unit 
value ^ 



Grand total 

RUBBER- PROCESSING CHJMICALS, CYCLIC 

Total 

Accelerators, total 

Aldehyde-amines 

Dlthiocarbamic acid derivatives 

Thiazole derivatives, total 

N-Cyclohexyl-2-benzothiazolesulfenamide 

2,2'-Dithiobis(benzothiazole) 

2-Mercaptobenzo thiazole 

All other^ 

All other accelerators 

Antioxidants, amino and hydroxy compounds, total-'- 

Amino compounds, total 

N,N'-Dlphenyl-p-phenylenediamlne 

All other 

Jfydroxy compounds, total 

Phenol, alkylated 

All other 

N-Nitrosodiphenylamine 

Peptizers 

All other cyclic rubber-processing chemicals' 

R!JBBZR- PROCESSING CHEMICALS, ACYCLIC 
Total 

Accelerators, total 

Dlthiocarbamic acid derivatives, total' 

Dibutyldithiocarbamlc acid, sodium salt 

Dlbutyldithiocarbamic acid, zinc salt 

Diethyldithlocarbamic acid, zinc salt 

Dlmethyldlthiocarbamic acid, potassium salt — 

Dlmethyldlthlocarbamic acid, sodium salt 

Dimethyldlthiocarbamic acid, zinc salt 

All other 



233,632 



199,282 



V'^.lOl 



1,774 

325 

62,477 

7,213 
18,388 

7,102 
29,774 

9,525 

96,208 



79,239 
1,994 
77,245 
16,969 
7,168 
9,801 

2,651 
4,853 
21,469 



34,350 



21,602 



11,526 

792 

1,316 

974 

268 

5,464 

1,066 

1,646 



1 , 000 
pounds 

177,202 



152,835 



49,849 



1,260 
240 

39,839 
5,784 
9,746 
5,668 

18,641 
8,510 

77,456 



64,819 

1,690 

63,129 

12,637 

3,494 

9,143 

1,982 
4,513 
19,035 



24,367 



13,037 



7,012 
366 

1,143 

699 

63 

2,255 
939 

1,547 



118,663 



101,757 



29,804 



1,265 
387 

21,188 
3,660 
4,941 
2,257 

10,330 
6,964 

54,635 



42,375 
1,575 

40,800 

12,260 
1,869 

10,391 

1,114 
3,070 
13,134 



16,906 



10,639 



5,747 
285 

1,342 

609 

30 

865 

764 

1,852 



.67 



.60 
1.00 
1.61 
.53 
.63 
.51 
.40 
.55 
.82 



.71 
.65 
.93 
.65 
.97 
.53 
1.14 



.56 
.68 
.69 



.69 
.82 



.82 
.78 

1.17 
.87 
.48 
.38 
.81 

1.20 



See footnotes at end of table. 



'See also table 16B, pt. ID, which Lsts these products alphabetically and identifies the manufacturers. 



ELASTOMERS (SYNTHETIC RUBBERS) 



43 



TABLE IQA. --Rubber -processing chemicals: U.S. production and sales, 1963— Continued 



Production 



quantity 



Unit 
value ^ 



RUBB£R- PROCESSING CHEMICALS, ACYCLIC--Continued 

Ac o e le rators — Continued 

Thiurams, total* 

Bis ( dime thylthiocarbanioyl)disulfide 

Bis ( dime thylthiocarbamoyl) sulfide 

All other 

All other accelerators 



Dodecyl meroaptans 

All other acyclic rubber-processing chemicals' 



i , 000 

pounds 
9,795 
5,375 
1,229 
3,191 
281 

8,963 
3,785 



1,000 

5,854 

4,278 

927 

649 

171 

8,604 
2,726 



4,710 

3,141 

992 

577 

182 

3,954 
2,313 



$0.80 
.73 

1.07 
.89 

1.06 

.46 
.85 



^ Calculated from rounded figures. 

^ Includes small quantities produced and sold for uses other than rubber processing. 

^ Data on production and sales of aldehyde and acetone amine antioxidants are included below in "All other cyclic 
rubber-processing chemicals." 

' Includes aldehyde and acetone amines, blowing agents, Inhibitors, modifiers, stabilizers, and tacMfiers. 

^ Data on dithiocarbamates included in this table are for materials used chiefly in the processing of natural and 
synthetic rubbers. Data on dithiocarbamates which are used chiefly as fungicides are reported in the section "Pesti- 
cides and Other Organic Agricultural Chemicals." 

' Includes data for small amounts of tetramethylthluram sulfides for uses other than in the processing of natural 
and synthetic rubbers. 

' Includes blowing agents, peptizers, modifiers, and conditioning and lubricating agents. 

The output of cyclic rubber-processing chemicals in 1963 amoxinted to 199 million pounds, or 
1.7 percent more than the 196 million pounds reported for 1962. Sales in 1963 were 153 million 
pounds, valued at $102 million, compared with 148 million pounds, valued at $97 million, in 1962. 
Of the total output of cyclic rubber-processing chemicals in 1963, accelerators accounted for 
37.2 percent and amino and hydroxy antioxidants, for 48.3 percent. Production of amino and 
hydroxy antioxidants, which amounted to 96.2 million pounds in 1963, included 79.2 m.illion 
pounds of amino compovmds and 17. million pounds of hydroxy comipounds. In 1962 the output of 
amino antioxidants amounted to 75. 1 million pounds, and that of hydroxy antioxidants, to 18.2 
million pounds. Sales of amino antioxidants in 1963 were 64.8 million pounds, valued at $42.4 
million; sales of hydroxy antioxidants were 12. 6 million pounds, valued at $12. 3 million. 

Production of acyclic rubber-processing chemicals in 1963 amounted to 34.4 million pounds, 
compared with the 32. 5 million pounds reported for 1962. Sales in 1963 totaled 24.4 million 
pounds, valued at $16. 9 million, compared with 24. million pounds, valued at $17. 1 million, in 
1962. Accelerators, principally dithiocarbamic acid derivatives and tetramethylthluram sulfides, 
accounted for about 63. percent of the output of acyclic rubber-processing chemicals in 1963. 
Peptizers and modifiers--chiefly dodecyl mercaptans - -together with blowing agents and lubri- 
cating and conditioning agents, accounted for 37. 1 percent of the output in the acyclic group. 



Elastomers (Synthetic Rubbers) 

The synthetic rubber industry in the United States had its beginning during World War II and 
has continued to thrive since that time. The styrene-butadiene, or S-type, rubber, which was 
the first to be developed, is a general-purpose material used in the manufacture of tires and 
other rubber goods; it is still the most important type of synthetic rubber, in ternns of quantity 
produced. Several other types of synthetic rubbers are also produced in large quantities; among 
them are the polybutadiene-acrylonitrile type, or N-type, the polybutadiene-isoprene type, or 
Butyl-type, neoprene, and stereo elastomers. Production of stereo elastomers, or synthetic 
natural rubbers, was reported separately for the first time in 1962. 

The total output of all types of elastomers in the United States in 1963 amounted to 3, 185 mil- 
lion pounds--slightly more than the 3, 134 million pounds reported for 1962. Sales of elastomers 
covered in this report amounted to 2,836 million pounds, valued at $767 million, in 1963, com- 
pared with 2, 730 million pounds, valued at $774 million, in 1962. Statistics on the production and 
sales of elastomers are given in table 17A.' 

See also table 17B, pi. HI, which lists these products alphabetically and identifies the manufacturers. 



44 SYNTHETIC ORGANIC CHEMICALS, 1963 

Production of cyclic elastomers, which consisted chiefly of the polybutadiene-styrene type 
(S-type), amounted to 2, 174 million pounds in 1963, compared with 2,263 million pounds in 1962. 
Sales of these elastomers amounted to 1, 926 million pounds, valued at $434 million, in 1963, 
connpared with 1, 907 million pounds, valued at $465 million, in 1962. Production of polyurethane 
type elastomers in 1963 amounted to 6 nnillion pounds. 

TABLE 17A, —Elastomers (synthetic rubbers):^ U.S. production and sales, 1963 

[Listed below are all elastomers (synthetic rubbers) for which reported data on production or sales may be pub- 
lished. (Leaders are used where the reported data are accepted in confidence and may not be published or where no 
data were reported.) Table 17B in pt. Ill lists alphabetically all elastomers for which data on production or 
sales were reported and identifies the manufacturer of each] 



Production 



Quantity 



Unit value^ 



Grand total 

ELASTOMERS, CYCLIC 
Total — 

Polybutadiene-styrene type (S-type) 

Polybutadiene-styrene-vinylpyridine type- 
Polyure thane type 

ELASTOMERS, ACYCLIC 
Total 

Polybutadiene-acrylonitrile type (N-type) 

Polychloroprene type (Neoprene) 

Polyisobutylene-isoprene type (Butyl) 

Silicone elastomers 

Stereo elastomers 

All other acyclic elastomers' 



3,18<;,9U 



2,836,295 



766,931 



$0.27 



2,17A,183 



1,925,751 



i34,<i7'; 



2,U9,823 
18,301 
6,059 



1,010,731 



1,910,652 
10,538 
4,561 



910, 5"^ 



422,382 
6,689 
5,403 



332,457 



.37 



108,368 
288,714 
242,235 
8,234 
312,807 
50,373 



95,506 

6,406 
808,632 



46,189 

25,768 
260,500 



.48 

4.02 
.32 



The term "elastomers" is defined as substances in bale, crumb, powder, latex, and other crude forms which can 
be vulcanized or similarly processed into materials that can be stretched at 68° F. to at least twice their original 
length and, after having been so stretched and the stress removed, will return with force to approximately their 
original length. 

^ Calculated from rounded figures. 

^ Elastomer-content basis. 

* Partly estimated. 

' Includes data for the production and sales of polyalkalene sulfide, and polylsobutylene elastomers, and 
natural rubber modifications; and for sales of neoprene. Butyl, and stereo elastomers. 

Note. — Statistics on the production of S-type, N-type, Butyl, neoprene, and stereo elastomers were compiled in 
cooperation with the U.S. Bureau of the Census. Revised statistics on production of polyurethane elastomers for 1961 
and 1962 are 3,330,000 pounds and 4,126,000 pounds, respectively. 

The output of acyclic elastomers, including N-type, neoprene. Butyl, silicone, and stereo 
elastomers, amounted to 1, Oil million pounds in 1963, compared with the 871 million pounds 
reported for 1962. Sales of these elastomers amounted to 911 million pounds, valued at $332 mil- 
lion, in 1963, compared with 823 million pounds, valued at $310 million, in 1962. The output of 
silicone elastomers in 1963 amounted to 8.2 million pounds, and that of stereo elaston-iers, to 313 
million pounds. 

Plasticizers 

Plasticizers are organic chemicals that are added to synthetic plastics and resin materials 
to (1) improve workability during fabrication, (2) extend or modify the natural properties of these 
resins, or (3) develop new improved properties not present in the original resins. Plasticizers 
reduce the viscosity of the resins and make it easier to shape and form them at high temper- 
atures and pressures. They also impart flexibility and other desirable properties to the finished 
product. Statistics on production and sales of plasticizers are given in table 18A,-'-° 



••■Osee also table 18B, pt. Ill, which lists these products alphabetically and identifies the manufacturers. 



PLASTICIZERS 45 

TABLE 18A. --Plasticizers:^ U.S. production and sales, 1963 

[Listed below are all plastioizers for which reported data may be published. (Leaders are used where the reported 
data are accepted in confidence and may not be published or where no data were reported.) Table 18B in pt. Ill 
lists all plasticizers for which data on production or sales were reported and identifies the manufacturer of 
each] 



Producticn 



Grand total 

PIASTICIZ2RS, CYCLIC 

Total - 

Phosphoric acid esters : 

Cresyl diphenyl phosphate^ 

Trioresyl phosphate-' 

Triphenyl phosphate 

Fhthalio anhydride esters, total 

Butyl octyl phthalate 

Ea(2-butoxyethyl) phthalate 

Dibutyl phthalate 

Dieyolohexyl phthalate 

Diethyl phthalate 

Dihexyl phthalate 

Diisodecyl phthalate 

Di(2-methoxyethyl) phthalate 

Dimethyl phthalate 

Dioctyl phthalates, total 

Di(2-ethylhexyl) phthalate 

Diiso-octyl and mixed dioctyl phthalates 

Ditridecyl phthalate 

Octyl decyl phthalates, total 

Iso-octyl isodecyl phthalate 

n-Octyl n-decyl phthalate 

All other phthalic anhydride esters 

Trimellitic acid esters 

All other cyclic plasticizers* 

PLASTICIZERS, ACYCLIC^ 

Total - 

Adipic acid esters, total 

Di(2-(2-butoxyethoxy)ethyl) adipate 

Di(2-ethylhexyl) adipate -■ 

Diisobutyl adipate 

Diisodecyl adipate 

Diiso-octyl adipate 

Ootyl decyl adipate 

All other 

Azelaic acid esters 

Complex linear polyesters and polymeric plasticizers- 

Epoxidized esters, total 

Epoxidized soya oils 

Ootyl epoxy tallates 

All other 

Glycerol monoricinoleate 

Isopropyl myristate 

Isopropyl palmitate 

See footnotes at end of table. 



unds 
83'i,524 



621,687 



11,278 
30,713 
10,034 

521,9-^3 



17,903 

557 

18,183 

6, SO 

U,602 

595 

66,91i 

6,9-46 

3,843 

275,829 

175,398 

100,431 

7,643 

17,823 

709 

17,114 

84,562 



46,837 



212,837 



28,255 



~55T 
6,032 
461 
7,920 
3,967 
8,226 
1,156 

16,254 
35,740 



39,965 
15,915 
2,872 

237 

1,833 

892 



749,750 



i.OOO 
dollars 
168,181 



557,979 



9,440 

30,963 

3,013 

467,491 



17,006 
537 
14,011 
3,967 
9,612 
579 
52,519 

3,432 

255,973 

160, 518 

95,455 

5,737 

17,943 

716 

17,227 

86, 175 

756 
46,316 



191,771 



23,004 



^57" 
4,244 

438 
6,094 
2,961 
7,886 

884 

15,325 
33,451 



37,538 
13,940 
2,977 

199 
1,814 



103,000 



2,538 
9,003 
1,068 

76,187 



2,483 

170 
2,885 
1,517 
1,867 

117 
7,903 

720 

37,595 

23,712 

13,883 

1,216 

3,166 

114 

3,052 

16,548 

330 
13,874 



65,181 



6,653 



""537" 
1,118 

168 
1,817 

787 
2,313 

213 

4,539 
13,936 



10,776 
3,924 
1,273 

78 
595 
265 



46 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 18A. --Plasticizers:'' U.S. production and sales, 1963 — Continued 



Isanti ty 



'Jnlt_ 
value"^ 



PLASTICIZERS, ACYCLIC— Continued 

Oleic acid esters, total 

Butyl oleate 

Glycerol trioleate (Triolein) 

Isopropyl oleate 

Methyl oleate 

n- Propyl oleate 

All other 

Phosphoric acid esters 

Sebacic acid esters: 

Di butyl sebacate 

Di(2-ethylhexyl) sebacate 

Stearic acid esters, total 

n- Butyl stearate 

All other 

Triethylene glycol di(caprylate-caprate) 

All other acyclic plastlcizers' 



1,000 

pounds 

10,037 



2,999 
3,480 

536 
1,173 

480 
1,369 

12,068 

4,276 
7,580 

7,433 



2,739 
4,694 



2,022 
27,458 



1,000 
dollars 



7,974 



1,863 

3,258 

100 

948 

386 

1,419 

9,797 

2,744 
7,740 

7,135 



2,618 
4,517 



1,778 
25,487 



1,876 



332 
654 
23 
169 

76] 
572 i 

3,943 j 

1,717 I 
4,414 

1,728 ! 



638] 
1,090 



578 I 
8,886 



to. 24 



.20 
.23 



Does not Include data for clearly defined extenders or secondary plasticizers. 
^ Calculated from rounded figures. 
^ Includes material produced for use as motor-fuel additive. 

* Includes data for toluenesulfonamides, tetrahydrofurfuryl oleate, and other cyclic plasticizers. 
' Dibutyl maleate is now published in table 22A, "Miscellaneous Chemicals." 

* Includes data for citric and acetylcitric, lauric, myristic, palmitic, ricinoleio, sebacic and tartaric acid 
esters, glycerol and glycol esters of certain fatty acids, glycerol tripropionate, and other acyclic plasticizers 



Total U.S. production of plasticizers in 1963 amounted to 835 million pounds--representing 
an increase of 6. 9 percent over the output of 781 million pounds reported for 1962, Sales in 1963 
of the plasticizers covered by this report amounted to 750 million pounds, valued at $168 million, 
compared with 666 million pounds, valued at $168 million, in 1962, 

Production of cyclic plasticizers in 1963, which consisted chiefly of the esters of phthalic 
anhydride and phosphoric acid, amounted to 622 million pounds, compared with 571 million pounds 
in 1962. Sales of cyclic plasticizers in 1963 amovmted to 558 million pounds, valued at $103 mil- 
lion, compared with 486 million pounds, valued at $104 million, in the previous year. 

Production of acyclic plasticizers in 1963 amounted to 213 million pounds, compared with 
210 million pounds in 1962, Sales of acyclic plasticizers in 1963 amovinted to 192 million pounds, 
valued at $65 million, compared with 180 million pounds, valued at $64 million in 1962, Produc- 
tion of complex linear polyesters in 1963 amounted to 36 million pounds, and that of epoxidized 
esters, to 59 million pounds. Other products included in the acyclic class are the esters of adipic, 
azelaic, oleic, sebacic, and stearic acids. 



Surface-Active Agents 

The surface-active agents covered in this report include synthetic organic detergents and 
wetting, emulsifying, and dispersing agents that function in either aqueous or nonaqueous systems. 
Soaps, waxes, and plasticizers are not included. The data are reported in terms of 100-percent 
organic, surf ace -active ingredients, and thus exclude all inorganic salts, water, and other 
diluents. Originally developed as soap substitutes for the textile industry, surface-active agents 
have proved valuable in many other applications. A major part of the output of surface-active 
agents is consumed in the form of packaged household and industrial detergents. The remainder 
is used as wetting, dispersing, penetrating, and emulsifying agents in the processing of textiles 
and leather, in ore flotation and oil-drilling operations, and in the maniifacture of paints, agri- 
cultural sprays, lubricants, cosmetics, foods, pharmaceuticals, and many other products. 



SURFACE-ACTIVE AGENTS 



47 



Statistics on U.S. production and sales of surface-active agents in 1963 are given in table 
19A. ■'■■'■ Total production of surface-active agents in 1963 amounted to 1,981 million pounds--1.6 
percent more than the 1, 949 million pounds produced in 1962, and 14. 5 percent more than the 
1,729 million pounds produced in 1961. Sales in 1963 totaled 1,790 nnillion pounds, valued at 
$325 million, compared with 1, 758 million pounds, valued at $317 million, in 1962, and 1, 583 
million pounds, valued at $292 nnillion, in 1961. Sales in 1963 were thus 1.8 percent larger than 
in 1962 and 13. percent larger than in 1961 in terms of quantity, and 2. 5 percent larger than in 
1962 and 11.4 percent larger than in 1961 in terms of value. 

TABLE 19A.— Surface -active agents: U.S. production and sales , 1963 



[Listed below are all surface-active agents for which reported data on production or sales may be published. 
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data 
were reported.) Table 19B in pt. Ill lists all surface-active agents for which data on production or sales were 
reported and identifies the manufacturer of each] 



Production^ 



Quantity^ 



Unit 
value ^ 



Grand total 

Amphoteric 

Anionic 

Cationic 

Nonionic 

BENZENOID SURFACE-ACTIVE AGENTS 
Total — 

Sot Sulfated or Sulfonated 

Total 

Amides, amines, and quaternary amnonlum salts, total 

Benzyldimethyloctadecylammonium chloride 

Benzyldodecyldimethylammonium chloride 

(3,'»-Dichloroben2yl)dodecyldimethylaimnonium chloride 

(Dodecylbenzyl)trimethyl3™''°i^um chloride 

Heterocyclic compounds 

Oxygen-containing conpounds 

All other 

Carboxylic acid esters and ethers, total 

Dodecylphenol, ethoxylated 

Iso-octylphenol, ethoxylated 

Noi^lphenol, ethoxylated 

Phenol, ethoxylated 

Other carboxylic acid esters and ethers 

Phosphoric and polyphosphorlc acid esters and salts, total 

Nonylphenol, ethoxylated and phosphated 

All other -- 

Sulfattd and Sulfonated 

Total - — 

Alkylphenols, ethoxylated and sulfated, total 

Nonylphenol, ethoxylated and sulfated 

All other 

See footnotes at end of table. 



1,000 

pounds 

1,980,658 



3,321 

1,368,802 

83,i36 

525,099 

1,308,791 



6,403 



250" 

676 

29 

219 

806 
3,879 

236, 108 



i5,366 

1,091 

12A,963 

4,049 

60,639 

2,193 



2,036 
157, 



1,064,087 



39,342 



21,484 
17,858 



1,000 
pounds 

1,789,683 



3,169 

1,316,423 

74,921 

395,170 

1,222,238 



195,533 



224 
716 

228 

530 

758 

3,889 

188,074 



96,831 

91,243 

1,114 



955 
159 



1,026,705 



1,000 
dollars 
324,974 



2,066 
186,850 
34,892 
101, 166 

159,963 



39,439 



6,065 



^36" 
597 

108 

680 

933 

3,511 

32,959 



15,814 

17, 145 

415 



354 

61 



120, 524 



4,496 



pound 



$0.18 



1.05 
.83 

.47 
1.28 
1.23 

.90 

.18 



.16 
.19 



.37 
.37 
.38 



■""See also table 198, pi. in, which hsu these products alphabetically and identifies the manufacturers. 



SYNTHETIC ORGANIC CHEMICALS, 1963 
TABLE 19A. — Surface -active agents : U.S. production and sales , 1963 — Continued 



Production''' 



Quantity^ Value 



BENZENOID SUHFACE-ACTIVE AGENTS— Continued 
Sulfated and Sulfonated — Continued 

Benzenesulfonates, total 

Benzene-, toluene-, and xylenesulfonates, total 

Toluenesulfonic acid, potassium salt 

Toluenesulfonic acid, sodium salt 

Xylenesulfonio acid, ammonium salt 

Xylenesulfonic acid, sodium salt 

All other 

Dodecylbenzenesulfonates , total 

Etodecylbenzenesulfonic acid 

Dodecyltenzenesulfonic acid, calcium salt 

Do'decylbenzenesulfonic acid, isopropylamine salt 

Dodecylbenzenesulfonlc acid, mixed alkylamine salt- 

Dodecylbenzenesulfonic acid, sodium salt 

Dodecylbenzenesulfonlc acid, trie"thanolamine salt-- 

All o-ther 

Other benzenesulfonates, total 

Tridecylbenzenesulfonic acid, sodium salt 

All other^ 

Lignosulfonates, total 

Lignosulfonic acid, calcium salt 

All o-ther 

Naphthalenesulf onates , total 

Butylnaph"thalenesulfonie acid and sodium salt 

Diisopropylnaphthalenesulfonic acid 

Isopropylnaph"tharenesulfonic acid 

All o'ther 

Other benzenoid surface-active agents, sulfated and 
sulfonated* 

NONBENZENOID SURFACE-ACTIVE AGENTS 

Total - 

Not Sulfated or Sulfonated 

Total - 

Amides, amines, and quaternary ammonium salts, total 

Acyclic quaternary ammonium salts, total 

Bis(hydrogenated tallow alkyl)dimethylammonium 

chloride ■- 

Dodeoyltrimethylammonium bromide and chloride 

Hexadecyltrimethylammonium salts 

All other . 

Amines salts, total 

Amine acetates 

Oleic acid, triethanolamine salt 

All other 

Amines, alkoxylated, total 

(Hydrogenated tallow alkyl)amine, ethoxylated 

(Mixed aliyl)amine, ethoxylated 

Rosin amine, ethoxylated 

(Tallow alkyl)amine, ethoxylated 

All other 

Fatty acid - alianolamine condensates, total 

Diethanolamine condensates, total 

Capric acid 

Coconut oil acids (amine/acid ratio=2/l) 

Coconut oil acids (amine/acid ratio=l/l) 

Laurie acid 

Oleic acid (amine/acid ratio = 2/l) 

See footnotes at end of table. 



1.000 
597,<il4 



10, 077 
16, 191 
19,287 

412,219 

60,966 

8,699 

3,832 

378 

326,994 

3,375 

7,975 

139, 640 

104, 714 

34,926 

415,035 



317,268 
97, 767 



,893 



929 

283 

420 

5,261 



5,403 



671,867 



386,068 



146,683 



22,039 

19,075 

215 

487 

2,262 

2,581 

1,880 

110 

591 

9,886 

155 

1,564 

904 

437 

6,826 

67,245 

49, 977 

204 

11,095 

15,426 

16,541 

1,531 



1,000 
pounds 

584,604 



1,000 
dollars 

92,358 



58,951 
15,057 
9,835 

16,905 
17,154 

57,883 
5,115 
3,835 
277 
330, 175 
2,973 

125,395 

125,395 

395,610 



299,666 
95,944 



222 
5,359 



19,063 



297, 143 



134,767 
20, 541 

17,686 
241 
473 
2,141 
2,334 
1,786 

548 
9,558 

1,473 
1,015 

7,070 
61,220 
44,840 

9,073 
14,991 
15,131 

1,266 



4,979 

1,325 

785 

1,508 
1,361 

14,772 

1,547 

1,149 

85 

42,557 



26,381 
26,381 
13,698 



9,381 
4,317 



2,173 



122 
1,953 



T, 799 



165,011 



108,302 



58, 714 
8,913 

6,535 
284 
465 

1,629 
948 
620 

328 
3,313 

727 
319 

2,267 
23,372 
15,915 

5,663 

4,354 

4,251 

356 



SURFACE-ACTIVE AGENTS 
TABLE 19A. --Surface-active agents.- U.S. production and sales , 1963- 



49 



NONBENZENOID SURFACE-ACTIVE AGENTS- -Continued 



Not Sulfa 



Sulfonat ed — Cont inued 



Amides, amines, and quaternary annnonium salts — Continued 
Fatty acid - alkanolamine condensates — Continued 
Diethanolamine condensates — Continued 

Oleic acid (amine/acid ratio=l/l) 

Stearic acid 

Tall oil acids 

All other 

Other alkanolamine condensates, total 

Stearic acid - ethanolamine condensates; 

(Amine/acid ratio =1/1) 

(All other ratios) 

All other 

Fatty acid - polyamine condensates, total 

Stearic acid - diethylenetriamine condensate 

All other 

Fatty acid - polyamine condensates, ethoxylated, total — 
Stearic acid - ethylenediamine condensate, monoethoxy- 

lated 

All other 

Heterocyclic compounds, total 

2-(8-Heptadecenyl)-l-(2-hydroxyethyl)-2-imidazoline--- 

2-Heptadecyl-l-(2-hydroxyethyl)-2-imidazoline 

All other 

N-Substituted amino acids and polypeptides 

Other amides, amines, and quaternary ammonium salts 

Carboxylio acid esters, total 

Diethylene glycol esters, total 

Diethj'lene glycol monolaurate 

Diethylene glycol mono-oleate 

Diethylene glycol monostearate 

All other 

Ethylene glycol esters, total 

Ethylene glycol monostearate 

All other 

Glycerol esters, total 

Complex glycerol esters' 

Glycerol mono- and diesters of chemically defined 

fatty acids, total 

Glycerol distearate 

Glycerol mono-oleate 

Glycerol monostearate 

All other 

Glycerol mono- and diesters of mixed fatty acids 

Polyethylene glycol esters, total 

Polyethylene glycol esters of chemically defined fatty 

acids, total , 

Polyethylene glycol dilaurate 

Polyethylene glycol dioleate 

Polyethylene glycol distearate 

Polyethylene glycol monolaurate 

Polyethylene glycol mono-oleate 

Polyethylene glycol monostearate 

All other 

Polyethylene glycol mono- and diesters of mixed fatty 

acids, total 

Polyethylene glycol coconut oil ester 

Polyethylene glycol tall oil ester 

All other 

Other carboxylic acid esters, total 

Ethoxylated anhydrosorbitol mono-oleate 

Ethoxylated anhydrosorbitol monostearate 

1,2-Propanediol monolaurate 

1, 2-Propanediol monostearate 

All other 

See footnotes at end of table. 



Production-'- 



659 

1,916 

422 

2,183 

17,268 

85 
70 
17,113 
11,027 
632 
10,395 
7,539 

1,934 

5,605 

4,017 

508 

96 

3,413 

3,902 

18,447 

112,031 



2,675 
750 
105 

1,302 
518 

1,402 

565 

837 

61,458 

3,251 

19,370 
210 
807 

18,248 
105 

38,837 

20,494 

13,592 

771 

2,256 

370 

3,056 

2,745 

4,054 

340 

6,902 

320 

5,058 

1,524 

26,002 

2,727 

1,547 

203 

1,014 

20,511 



Quantity-"- 



1,000 
pounds 

656 
1,668 

2,055 
16,380 

58 
68 
16,254 
10,785 
482 
10,303 
5,058 

1,273 
3,785 
3,862 

'"87 
3,775 
3,088 
18,321 

94, 174 



2,397 
760 
144 
971 
522 

1,420 

545 

875 

52,512 

1,852 

18,611 
153 
728 

17,622 
108 

32,049 

14,303 

8,995 

719 

776 

347 

1,946 

1,878 

3,214 

115 

5,308 

187 

3,732 

1,389 

23, 542 

2,666 

1,543 

211 

924 

18, 198 



1,000 
dollars 



201 
655 

435 
7,457 

22 

29 
7,406 
2,997 
289 
2,708 
3,559 

1,276 
2,283 
2,090 

52 
2,038 
5,503 

8,019 

30,829 



"SOT 
235 
39 
284 
247 
452 
202 
250 
13,915 
807 

5,592 

49 

257 

5,245 
41 

7,516 

5,004 

3,488 
251 
265 
136 
784 
731 

1,276 
45 

1,516 

51 

880 

585 

10,653 

1,225 

710 

81 

279 

8,358 



50 SYNTHETIC ORGANIC CHEMICALS, 1963 

TABLE 19A. -Surface -active agents: U.S. production and sales , i963--Continued 



Production^ 



Quantity-'- Value 



NONBENZENOID SURFACE-ACTIVE AGENTS- -Continued 
/Vo( Sulfateil or Su(/ono;e// -Continued 

Ethers, total 

Castor oil, ethoxylated 

n-Dodeoyl alcohol, ethoxylated 

Lanolin, ethoxylated 

9-Octadecenyl alcohol, ethoxylated 

n-Oetadecyl alcohol, ethoxylated 

Tridecyl alcohol, ethoxylated 

All other 

Fatty acids, potassiujn and sodium salts, total 

Castor oil acids, sodium salt 

Coconut oil acids, potassium salt 

Laurie acid, potassium salt 

Oleic acid, potassium salt 

Oleic acid, sodium salt 

Rosin acids, sodium salt 

Stearic acid, sodium salt 

Tall oil acids, potassium salt 

Tall oil acids, sodium salt 

Tallow acids, potassium and sodium salts 

All other 

Phosphoric and polyphosphoric acid esters, total 

Alcohols, phosphated and polyphosphated, total 

2-Ethylhexyl phosphate, sodium salt 

All other 

Other phosphoric and polyphosphoric acid esters 

Other nonbenzenoid surface-active agents, not sulfated or 
sulfonated 

Sulfated and Sulfonated 

Total - 

Dicarboxylic acid amides, sulfated and sulfonated 

Dicarboxylic acid esters, sulfated and sulfonated, total — 

Sulfosuccinic acid, bis(2-ethylhexyl) ester 

All other 

Fats, oils, and waxes, sulfated and sulfonated, total 

Animal (including fish and marine animal) fat? and oils, 

sulfated and sulfonated, total 

Cod oil, sulfonated 

Grease, other than wool, sulfonated 

Neat's-foot oil, sulfonated 

Sperm oil, sulfonated 

Tallow, sulfonated 

All other 

Vegetable oils, sulfated and sulfonated, total 

Castor oil, sulfonated 

Coconut oil, sulfonated 

Peanut oil, sulfonated 

Rice-bran oil, sulfonated 

Soybean oil, sulfonated 

All other 

Other fats, oils, and waxes, sulfated and sulfonated' — 

Other nonbenzenoid surface-active agents, sulfated and 

sulfonated, total 

n- Butyl sulfo-oleate 

Coconut oil acids - ethanolamine condensate, sulfated, 

potassium salt 

See footnotes at end of table. 



109,486 



2,129 
51,3';3 



7,586 
46,736 



13,807 



53 

56 

740 

1,423 

49 

1,911 

4,563 

240 

1,400 

3,363 

3,592 



,043 

104 

2,939 

549 



285,799 



1,206 
4,407 



3,439 



29,286 



17, 938 
2,114 

636 
1,014 
6,512 
7,276 

386 

6,796 

1,347 

1,377 

367 

217 

1,244 



1.000 

pounds 

51,649 

1,944 

1,846 

68 

1,697 

168 

6,739 

39,187 

13,550 



1.000 
dollars 

13,497 



52 

56 

470 

1,416 

48 

1,948 

4,555 

238 

1,397 

3,362 

2,535 



2,173 
135 

2,038 
362 



270,302 



3,044 
1,425 



19, 105 



1,582 

582 

398 

3,983 

5,767 

5,810 
3,468 

710 
1,271 

113 

197 
51 

983 



246,728 



638 
44 



877 

29 

823 

69 

1,508 

9,505 

3,147 



261 

13 
981 
798 

35 

141 
814 



1,446 



1,397 
271 



56,709 



1,522 
729 



3,662 



224 

90 

71 

738 

646 

1,614 

1,014 

180 

319 

26 

63 

12 

279 



50,796 



170 



SURFACE-ACTIVE AGENTS 51 

TABLE 19A. --Surface-active agents: U.S. production and sales , 1963 --Continued 



Chemical 



Production 



Quantity^ 



Unit 
value^ 



NONBENZENOID SURFACE-ACTIVE AGENTS- -Continued 

Sulfated and Sulfonated- -Tontinued 

Other nonbenzenoid surface-active agents, sulfated and 
sulfonated- -Continued 

n-Dodecyl sulfate, ammoniujn salt 

n-Dodecyl sulfate, sodium salt 

n-Dodecyl sulfate, triethanolamine salt 

Isopropyl sulfo-oleate 

N-Methyl-N-oleoyltaurine 

Oleic acid, sulfonated 

n-Propyl sulfo-oleate 

Tridecyl alcohol, ethoxylated and sulfated, sodium salt- 
All other' 



1,000 
pounds 
1,436 
13,151 

6,71-; 

828 
2,993 
2,910 
1,031 

77b 
220,331 



1,000 


1.000 


pounds 


dollars 


l,4i8 


790 


11,596 


6,008 


6,260 


1,924 


531 


161 


2,948 


1,597 


1,880 


598 


1,081 


264 



39,237 



3.55 
.52 
.31 
.30 
.54 



"'" All quantities are given in terms of 100-percent organic surface-active ingredient. 

^ Calculated frcm rounded figures. 

^ Includes production of "All other" benzene-, toluene-, and xylenesulfonates and sales of "All other" 
dodecylbenzenesulf onates . 

' Includes sales of "All other" allijrlphenols, ethoxylated and sulfated. 

' E.g., glycerol lactate palmitate and glycerol diacetyltartrate monostearate. 

' Includes sales of "All other" animal and fish oils, sulfated and sulfonated, and production of "All other" 
vegetable oils, sulfated and sulfonated. 

' Includes alcohols, alkanes, amines, ethers, fatty acid amides, fatty acid esters, and quaternary ammonium 
compounds, sulfated and sulfonated. 



Production of anionic materials in 1962 amounted to 1,369 million povmds, or 69. 1 percent 
of total production; sales of anionic materials were 1,316 million pounds, valued at $187 million. 
Production of those surface-active agents which are generally considered nonionic amounted to 
525 million pounds, or 26. 5 percent of the total; sales were 395 million pounds, valued at $101 
million. Production of cationic materials amounted to 83 million pounds, or 4.2 percent of the 
total; sales totaled 75 million pounds, valued at $35 million. Production of amphoteric materials 
amounted to 3,3 million pounds, or approximately 0.2 percent of the total; sales totaled 3.2 mil- 
lion pounds, valued at $2. 1 million. 

Production of benzenoid surface-active agents in 1963 amounted to 1,309 million pounds, or 
0. 5 percent more than the 1, 302 million pounds reported for 1962. Sales of benzenoid surface- 
active agents in 1963 totaled 1,222 million pounds, valued at $160 million, compared with sales 
in 1962 of 1,221 million pounds, valued at $163 million. Of the benzenoid surface-active agents 
for which individual statistics are shown in the table, those produced in largest quantity were 
dodecylbenzenesulfonic acid, sodium salt, 327 million pounds; lignosulfonic acid, calcium salt, 
317 million pounds; nonylphenol, ethoxylated, 125 million pounds; tridecylbenzenesulfonic acid, 
sodium salt, 105 million pounds; and dodecylbenzenesulfonic acid, 61 million pounds. 

Production of nonbenzenoid surface-active agents in 1963 amounted to 672 million pounds, or 
3.9 percent more than the 647 million poxmds reported for 1962. Sales of nonbenzenoid surface- 
active agents in 1963 totaled 567 million pounds, valued at $165 million, compared with the 537 
million pounds, valued at $155 million, reported for 1962. Of the nonbenzenoid surface-active 
agents for which individual statistics are shown in the table, those produced in largest quantity 
were n-dodecyl alcohol, ethoxylated, 51 million pounds; bis(hydrogenated tallow alkyl)dimethyl- 
ammonium chloride, 19 million pounds; glycerol monostearate, 18 million potuids; lauric acid - 
diethanolamine condensate, 17 million pounds; and coconut oil acids - diethanolamine condensate 
(amine/acid ratio = 1/1), 15 million pounds. 



52 



SYNTHETIC ORGANIC CHEMICAIS^ 1963 
Pesticides and Other Organic Agricultural Chemicals 



This section of the report covers pesticides (fiongicides, herbicides, insecticides, and 
rodenticides) and other organic agricultural chemicals, such as plant hormones, seed disin- 
fectants, soil conditioners, and soil fumigants. The data are given in terms of 100-percent active 
material; they thus exclude such materials as diluents, emulsifiers, synergists, and wetting 
agents. Statistics on production and sales of pesticides and other organic agricultural chemicals 
in 1963 are given in table ZOA.-"-^ 

TABLE 20A. — Pesticides and other organic agricultural chemicals : U.S. production and sales, 1963 

[listed below are all pesticides and other organic agricultural chemicals for which any reported data on production 
or sales may be published. (leaders are used where the reported data are accepted in confidence and may not be 
published or where no da'ta were reported.) Table 20B In pt. Ill lists all pesticides and other organic agricul- 
tural chemicals for which data on production or sales were reported and Identifies the manufacturer of each] 



Production 



Qoantity 



Unit 
value ^ 



Grand total- 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICALS, CYCLIC 

Total - - - 

Fungicides, total 

Mercury fungicides 

Naphthenlc acid, copper salt 

Pentaohlorophenol (PCP) 

S-Quinollnol (8-Hydroxyquinoline), copper salt 

2,'4-,5-Trlohlorophenol and salts 

All other 

Herbicides and plant hormones, total 

Phenoxyacetlc acid derivatives: 

(2,<4-Dichlorophenoxy)acetic acid (2,A-D) 

(2,4-Dlchlorophenoxy)acetic acid esters and salts, total 

(2,4-Dichlorophenoxy)acetlo acid, n-butyl ester 

(2,'i-Dlchloropheno3cy)acetlc acid, dlmethylamine salt- 

(2,'i-Dlchlorophenoxy)acetlc acid, ethyl ester 

(2,4— Dlchlorophenoxy) acetic acid, iso-octyl ester 

(2,4-Dichlorophenoxy)acetic acid, Isopropyl ester 

All other 

(2,';,5-Trlchlorophenoxy)acetlc acid {2,A,5-T) 

(2,4,5-Trichlorophenoxy)acetic acid esters and salts, 

total 

(2,<i,5-Trichlorophenoxy)acetlc acid, n-butyl ester 

(2,'i,5-Trichlorophenoxy)acetio acid, iso-octyl ester- 
All other - 

Phenylmercury acetate (PMA) 

All other - - — 

Insecticides and rodenticides, total 

Aldrln-toxaphene group 

Ifexachlorocyclohexane (Benzene hexaohlorlde ) and 

lindane^ 

Organophosphorus insecticides, total 

0,0-Dlethyl O-(p-nitrophenyl) phosphorothioate 

(Parathion) 

0, 0- Dimethyl O-(p-nitrophenyl) phosphorothioate 

(Jfethyl parathion) 

All other 

l,l,l-Trlohloro-2,2-bls(p-ohlorophenyl)ethane (DDT) 

All other - 

See footnotes at end of table. 



763,477 



597,072 



75,325 



1,376 

1,834 

33,912 

56 

12,423 

26,224 

150,119 



46,312 

44,484 
5,795 

10,398 
1,322 
5,811 
4,815 

16,343 
9,090 

10,015 
1,336 
1,592 
7,087 
749 

39,469 

371,128 



105,986 



6,778 
35,711 



15,999 

19,712 

178,913 

43,740 



651,471 



498,082 



57,814 
1,248 
1,844 

26,255 
58 

28,409 

100,480 



20,825 
36,007 
5,547 
8,552 
1,019 
5,389 
2,930 
12,570 
4,251 

5,699 

800 

1,810 

3,089 

517 

33,181 

339,788 



101,097 

9,819 
38,317 

8,618 

19, 174 
10,525 
155,402 
35,153 



dollirs 
369,140 



286,045 



19,406 
3,038 

548 
4,509 

212 

11,099 
98,223 



6,209 
12,838 
1,609 
3,764 
291 
2,190 
1,055 
3,929 
3,312 

4,833 

571 

1,690 

2,572 

2,638 

68,398 

168,411 



58,845 

1,599 
44,703 

6,053 

15,465 

23,185 
25,380 
37,384 



.57 



.34 

2.43 

.30 

.17 

3.66 

.39 



.30 
.36 
.29 
.44 
.29 
.41 
.36 
.31 
.78 

.85 

.71 
.93 
.83 

5.10 



1.17 
.70 

.81 

2.20 

.17 

1.06 



■^See alio table 20B, pt. Ill, which lists these products alphabetically and identifies the manufacturer. 



MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 



53 



TABLE 20A. — Pesticides ami other organic agricultural chemicals: U.S. production and sales, 1963 — Continued 



Quantity 



Unit 
value ■'■ 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICALS, ACYCLIC 

Total - - 

Fungicides, total 

Dimethyldithlooarbamlc acid, ferric salt (Ferbam) 

Ethylene bl3(dlthlocarbajnlc acid), disodium salt (Nabam)- 

Ethylene bis(dlthlocarbainlc acid), zlno salt (Zineb) 

All other 

Herbicides and plant hormones, total 

Methanearsonic acid, disodium salt 

All other 

Insecticides, rodentlcides, fumigants, and soil 

conditioners, total 

Bromomethane (Xfethyl bromide) 

l,2-Dibromo-3-chloropropane 

Organophosphorus insecticides, total 

Ethyl pyrophosphate (Tetraethyl pyrophosphate) (TEPP)-- 

All other 

All other insecticides, rodentlcides, fumigants, and 
soil conditioners 



1 . DUU 
pound. 

166,405 



35,239 



2,500 

2,420 

3,575 

26,744 

24,408 



2,497 
21,911 



106,758 



17,394 
4,268 
38,351 

37,874 

46,745 



dollars 



153,389 



35,451 



2,693 

2,461 

4,078 

26,219 

22,392 



2,225 

20,167 



95,546 



16,373 

3,641 

22,030 

372 

21,658 

53,502 



83,095 



26, 876 



1,023 

1,090 

2,143 

22,620 

17,665 



995 
16,670 



38,554 



6,260 
1,740 

23,247 
237 

23,010 

7,307 



$0.54 



■ 40 
.38 
.48 

1.06 
.64 

1.06 



^ Calculated from rounded figures. 

^ Production of gamma isomer content in benzene hexachloride and lindane totaled 1.8 million pounds; sales 
amounted to 2.2 million pounds. 

Production of pesticides and other organic agricultural chemicals in 1963 amounted to 763 
million pounds--about 4 percent more than the 730 naillion pounds reported for 1962, Sales in 
1963 were 651 million pounds, valued at $369 million, compared with 634 million pounds, valued 
at $346 million, in 1962. 

The output of cyclic pesticides and other chemicals included in the cyclic group amounted to 
597 million pounds in 1963--about 2 percent more than the 585 million pounds produced in 1962. 
Sales in 1963 were 498 million pounds, valued at $286 million, compared with 497 million pounds, 
valued at $271 million, in 1962. The chemical in this group which was produced in the greatest 
quantity in 1963--as in each year since it was first separately reported in 1944--was the insec- 
ticide DDT. The output of this product in 1963 amounted to 179 million pounds. 

Production of acyclic pesticides and other acyclic organic agricultural chemicals in 1963 
amounted to 166 million pounds - -about 15 percent more than the 145 million pounds reported for 
1962. Sales in 1963 were 153 million pounds, valued at $83 million, compared with 137 million 
pounds, valued at $75 million, in 1962. 



Miscellaneous Synthetic Organic Chemicals 

As used in this report, the term "miscellaneous synthetic organic chemicals" refers to those 
products that are not included in the use groups covered in the preceding sections of the report. 
These miscellaneous chemicals, which account for about three-fifths of the output of all synthetic 
organic chemicals, include products that are employed in a great variety of uses; the number of 
chemicals used exclusively for only one purpose is not large. Among the products covered are 
those used for gasoline and lubricating oil additives, paint driers, photographic chennicals, 
tanning materials, flotation reagents, refrigerants, textile polymers, sequestering agents, 
organic fertilizers, antifreeze chemicals, solvents, and acyclic intermediates. 

Production of miscellaneous chemicals in 1963 amounted to 41.2 billion pounds, or 9.5 per- 
cent more than the output of 37. 6 billion pounds reported for 1962. Sales of miscellaneous chem- 
icals in 1963 amounted to 17. 5 billion pounds, valued at $2. 4 billion, compared with 16, 6 billion 
povuids, valued at $2.3 billion, in 1962. Statistics on production and sales of miscellaneous 
chemicals in 1963 are given in table 21A, 



■■^^e also table 21B, pt. m, which lists these products alphabetically and identifies the manufacturers. 



54 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 21A. — Miscellaneous chemicals: U.S. production and sales, 1963 

[Listed below are all miscellaneous chemicals for which any reported data on production or sales may be published. 
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data 
were reported.) Table 21B in pt. Ill lists alphabetically all miscellaneous chemicals for which data on produc- 
tion or sales were reported and identifies the manufacturer of each] 



Quantity 



Grand total 

MISCELLANEOUS CHEMICALS, CYCLIC 

Total - 

Benzoic acid salts: Sodium benzoate, tech. and U.S.P — 

Benzoyl peroxide 

Cyclohexanone peroxide 

Cyclopropane 

2,6-Di-tert-butyl-p-cresol: 

Food grade 

Tech 

Ethylmorpholine 

Flotation reagents, total 

Thiocarbanilide (Diphenyl thiourea) 

All other 

Gasoline additives, total^ 

N, N-Di-sec-butyl-p-phenylenediamine 

N, N'-Disalicylidene-l,2-propanediamine 

All other 

Hexamethylenetetramine, tech 

Lubricating oil and grease additives, total 

Oil soluble petroleum sulfonate, barium salt 

Oil soluble petroleum sulfonate, calcium salt 

Oil soluble petroleum sulfonate, sodium salt 

All other 

Morpholine 

Naphthenic acid salts, total^ '• 

Calcium naphthenate 

Cobalt naphthenate 

Iron naphthenate 

Lead naphthenate 

Manganese naphthenate 

Zinc naphthenate 

All other 

Photographic chemicals : 

Benzotriazole ' 

p-M.ethylaminobenzenediazonium chloride (p-Dlazo-N,N- 
diethylaniline) - zinc chloride 

Pinene 

Tall oil salts, total^ 

Calcium tallate 

Cobalt tallate 

Lead tallate 

Manganese tallate 

All other 

Tanning materials, synthetic, total 

2-Naphthalenesulfonic acid, formaldehyde condensate 

and salts 

All other 

See footnotes at end of table. 



1.000 
pounds 
il, 153,047 



952,555 



6,824 
4,209 



6,847 

13,027 

699 

5,133 



104 
5,029 



10,616 



2,611 
1,246 
6,759 

41,312 

374,141 



45,775 
121,422 

87,003 
119,937 

13,216 

15,893 



1,364 

2,670 

244 

9,308 

1,247 

777 

283 



100 
2,386 



7,583 



401 

2,154 

3,554 

886 

588 

31,710 



27,330 
4,380 



1,000 

pounds 

17,495,693 



1.000 
dollars 
2,363,717 



476,856 



6,011 
4,105 



6,289 

10,613 

705 



7,199 



2,862 

821 

3,516 

24,577 

203,802 



37,375 
166,427 



11,874 



14,232 
1,185 



2,326 

171 

8,506 

1,091 

690 

263 



100 
2,361 



7,291 



419 

2,000 

3,482 

835 

555 

31,510 



27,391 
4,119 



190,935 



1,722 
3,405 

2,434 

3,602 

5,846 

864 



6,452 



2,550 
1,333 
2,569 

4,576 

47,924 



6,098 
41,826 



5,590 
5,082 



357" 

1,589 

54 

2,059 

414 

259 

153 



253 
303 



2,406 



142 

1,019 

859 

244 

142 

6,712 



5,205 
1,507 



MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 
TABLE 21A. — Miscellaneous chemicals.- U.S. production and sales , i 563-- Continued 



55 



Quantity 



MISCELLANEOUS CHJWICALS, CYCLIC— Continued 



Textile chemicals, other than surface-active agents- 
All other miscellaneous cyclic chemicals 



MISCELLANEOUS CHEMICALS, ACYCLIC 



Acetaldehyde 

Acetic acid, synthetic, lOOjt^- 



Aoetio acid salts, total- 
Ammonium acetate 

Copper acetate 

Potassium acetate 

Sodium acetate 

Zinc acetate 

All other 



Acetic anhydride, 100^, from all sources- 



Acetone, total 

F^om isopropyl alcohol- 
All other 



Acrylic acid — 
Ac ry loni tr i le - 
Adipic acid 



Alcohols, monohydrlc, unsubstltuted, total- 
Alcohols C9 or lower, total 

Allyl alcohol 

Butyl alcohols, total 

Normal (n- Propylcarbinol) 

All other 

Ethyl alcohol, synthetic' 

Hexyl alcohol 

Iso-octyl alcohols 

Isopropyl alcohol 

lifethanol, synthetic 

All other 

Alcohols Cio or higher, total 

Decyl alcohol 

Dodecyl alcohol (Lauryl alcohol) (955t)- 

1-Hexadecanol (Cetyl alcohol) (95^ 

1-Octadecanol (Stearyl alcohol) {95<f,) — 
All other 



Amines, total 

Coconut oil amine 

Diethylamlne 

Dimethylamlne 

Dodecylamine 

Merthy lamine , mono 

Octadecylamine 

Oleylamine 

Tallow amine 

Tallow amine, dihydrogenated and hydrogenated- 

Trlme thy lamine 

All other 



Arayl acetates, 905t 

Bis(2-ehloroethyl) ether { Wchlorodlethyl ether), all grades 

2-Butanone oxime 

2-Butanone peroxide 



1,909 
-^16,680 



40,200,482 



1,027,875 
18,136 



128 

1,481 

11,510 

666 

4,351 

1,271,527 

943,399 



717,623 
225,776 

24,735 
455,314 
670,433 

7,161,687 



6,837,757 

16,118 

640,754 

294,608 

346,146 

1,950,631 

5,077 

64,065 

1,465,520 

2,333,472 

362,120 

323,930 

59,278 

17,854 

1,452 

245,346 

554,779 



859 

6,023 
59,665 

13,213 

1,048 

998 

3,191 

4,203 

11,488 

454,091 

6,361 

2,473 
1,168 



1,000 
pounds 



145,982 



17,018,837 



1.000 
dollars 



93,576 



2,172,782 



110, 549 
204,378 



14,715 



520 
122 
1,396 

478 
12,199 



536,678 



385,729 
150,949 

4,900 

212,357 

57,864 

3,403,095 



3,2^1,543 

300,980 

219,511 

81,469 

1,103,213 

52,098 

541,710 

1,059,113 

234,429 

111,552 



1,305 

5,254 

104,993 

150,236 



651 

2,858 

36,824 

1,034 

13,153 

828 

674 

2,294 

3,914 

88,006 

6,012 
11,836 
2,444 
1,137 



8,480 
15,096 



192 

85 

309 

158 
2,608 



26,512 



19,589 
6,923 

1,938 
29,476 
14,635 

224,504 



205,544 

31,969 

24,012 

7,957 

67,996 

5,835 
32,046 
36,323 
31,375 
18,960 



409 

924 

17,627 

49,605 



353 

1,279 

7,953 

657 

2,315 

383 

244 

829 

1,265 

34,327 

998 

226 

1,868 

2,127 



See footnotes at end of table. 



56 



SYNTHETIC ORGANIC CHEMICALS. 1963 
TABLE 21A. — Miscellaneous chemicals: U.S. production and sales , iii65— Continued 



Production 



(Quantity 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Butyl acetates, total 

Normal 

All other 

tert-Butyl peroxide (Di-tert-butyl peroxide) 

Caprolactam (Hexahydro-2H-azepin-2-one) 

Carbon disulfide 

Cellulose esters and ethers, total 

Cellulose esters, total 

Cellulose acetate 

All other 

Cellulose ethers, total 

Sodium oarboxymethylcellulose, lOO^J 

All other 

Chloral (Trichloroaoetaldehyde) 

Chloroacetio acid, mono- 

Chloroaoetic acid, ethyl ester 

2-Chloro-N, N-dimethylethylamine (Dime thy laminoe thy 1 

chloride) hydrochloride 

l-Chloro-2-propanone ( Chloraoetone ) 

Dibutyl fumarate 

Dibutyl maleate 

methylene glycol 

Dilauryl 3,3'-thlodipropionate 

2-Dimethylaminoethanol 

Dipropylene glycol 

Dodecenylsuccinic anhydride 

Ethanolamines, total 

2-Aminoethanol (Monoethanolamine) 

2,2'-Iminodiethanol (Diethanolamine) 

2, 2', 2" -Nitrilotriethanol ( Triethanolamine ) 

2-Ethoxyethanol (Ethylene glycol monoethyl ether) 

Ethyl acetate, 8556 

Etl^l acetoaoetate 

Ethyl aorylate 

Ethylene glycol 

Ethylene oxide 

Ethyl ether, all grades 

Etl^l formate 

2-Ethylhexanoic acid (a-£thylcaproic acid) salts, total- 
Calcium 2-ethylhexanoate 

Cobalt 2-ethylhexanoate 

Lead 2-ethylhexanoate 

Manganese 2-ethylhexanoate 

Zinc 2-ethylhexanoate 

All other 

2-Bthyl-l-hexyl aery late 

Ethyl silicate (Tetraethoxysilane) 

Formaldehyde (375t by weight) 

Formic acid, 905t- 

Formic acid salts, total 

Aluminxim formate 

All other 

Fumaric acid 

Gluconic acid, tech 

Gluconic acid, sodium salt, tech 

Glycerol, synthetic 

See footnotes at end of table . 



111,558 



76,79A 
3^,764 

735 
187,612 
652,021 

8^1,682 



762,155 
603,736 
158,^19 
79,527 
42,741 
36,786 

79,766 

53,550 

1,443 

261 

4,580 

8,494 

122,433 

728 

1,165 

26,252 



145,788 



43,487 
61,073 
41,228 



117,507 

1,436 

79,820 

1,659,614 

1,888,760 

83,020 

47 

3,384 



687 
453 
223 
38 
179 
1,804 

15,415 

4,535 

2,537,236 

18,272 

28,992 



28,992 

23,775 

2,947 

6,397 

161,648 



1,000 

pounds 

105,901 



73,584 
32,317 

708 

90,415 

494,399 

240,263 



1,000 
dollars 

12,024 



167,925 

167,925 
72,338 
41,495 
30,843 



171 

46 

3,973 

3,391 

104,543 

645 

884 

22,480 

740 

109,450 



35,013 
40,598 
33,839 

33,601 

107,692 

789 

30,016 

1,068,426 

170,386 

82,654 

58 

2,673 



164 
388 
196 
36 
150 
1,739 

13,848 

3,538 

919,763 

17,559 

21,623 



466 
21,157 

23,099 

3,274 

5,836 

161,911 



J76gr 

3,341 

1,234 
33,759 
20, 190 

101,558 



61,938 

61,938 
39,620 
18,532 
21,088 



237 
38 
889 
786 
11,823 
638 
612 
2,809 
354 

21,626 



7,361 
7,766 
6,499 

5,918 

11,830 

338 

9,259 

96,546 

18,698 

5,736 

23 

2,771 



100 

364 

80 

17 

82 

2,128 

5,056 

1,519 

27,799 

2,477 

1.109 



81 
1,028 

3,722 

1,061 

1,661 

26, 974 



MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 
TABLE 21A. — Miscellaneous chemicals: U.S. production and sales, 1963 — Continued 



57 



Chemical 



Sales 



Production 



MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued 

Halogenated hydrocarbons, total 

l-Bromobutane (n-Butyl bromide) 

1-Bromopentane (n-Amyl bromide) 

l-Bromopropane (n-Propyl bromide) 

Carbon tetrachloride 

Chlorinated paraffins, total 

35io-(:>^$ Chlorine 

All other 

Chlorodifluoromethane 

Chloroethane (Ethyl chloride) 

Chloroform, total 

Tech 

U.S.P 

Chloromethane (Methyl chloride) 

Dlchlorodlfluorome thane 

1,2-Diohloroethane (Ethylene dichloride) 

Dichloromethane (Methylene chloride) 

1,2-Dichloropropane (Propylene dichloride) 

Wchlorotetrafluoroe thane 

lodomethane (Mtethyl iodide) 

Tetrachloroethylene (Perchloroethylene) 

1,1, 2 -Trl chloroethane (Vinyl trichloride) 

Trichloroethylene 

Trichlorofluorome thane 

Vinyl chloride, monomer ( Chloroethylene ) 

All other 

Isopropyl acetate 

Isopropyl ether 

Lactic acid 

Lauroyl chloride 

linoleio acid salts, total^ 

Calcium linoleate 

Cobalt linoleate 

All other 

Lubricating oil additives, total 

Phosphorodithioates (Dithiophosphates) 

Sulfurized lard oil 

Sulfurized sperm oil 

All other 

Maleic anhydride 

Mercaptoacetic (Thioglycollc) acid derivatives, total 

2-Aminoethyl mercaptoaoetate (Monoethanolamine 

thioglyoolate) 

All other 

2-Methoxyethanol (Ethylene glycol monoethyl ether) 

2-[2-(2-Vtethoxyethoxy)ethoxy]ethanol (Triethylene glycol 

monomethyl ether) 

Ifethyl acetate 

4-Methyl-2-pentanone (Methyl isobutyl ketone) 

Oleic acid salts'' 

Oxalic acid 

Oxalic acid salts 

Palmitic acid salts 

Palmitoyl chloride 

Pentaerythritol 

Pentaerythrltol tetranitrate 

Phosgene (Carbonyl chloride) 

Phosphorus acid esters, not elsewhere specified, total--' 

Tributyl phosphate 

All other 

See footnotes at end of table. 



1,000 
pounds 
7,185,827 



519,168 

37,939 

28,868 

9,071 

591,847 

105,149 

104,073 

1,076 

114,042 

217,433 

1,793,335 

147,950 

35,539 

11,612 

24 

325,054 

6,169 

368,179 

140,130 

1,435,209 

1,336,991 

35,742 
5,253 
5,298 

13,384 

409 



Quantity Value 



105 
158 
146 

328,303 



97,632 

2,068 

22,255 

206,348 

86,568 

3,437 



217 
3,220 



67,337 



10,741 

157,884 

329 

21,440 

6,113 

274 

163 

69,190 

4,240 

212,072 

9,487 



2,677 
6,810 



1.000 
pounds 



10 

421,125 

37,764 

28,646 

9,118 

36,006 

233,731 

77,312 

76,241 

1,071 

54,718 

207,263 

325,600 

133,249 

27,475 

9,232 

278,124 
2,223 
362,571 
131,569 
500,812 

34,876 
2,876 
5,518 



1,000 
dollars 



133,902 



50,770 

83,132 

57,072 

3,247 



3,247 

58,442 

161 

148,736 

313 

19,901 

5,560 



61,109 
2,426 



2,211 
6,664 



19 

32,281 

4,836 

3,363 

1,473 

23,928 

17,550 

6,968 

6,757 

211 

4,741 

61,062 

14,788 

12,307 

666 

5,483 

26,511 
253 
32,610 
26,944 
34, 966 

3,816 

239 

2,286 



27,961 



12,800 

15,161 
7,597 
4,317 



4,317 

10,551 

22 

19,228 

251 

3,528 

1,321 



14,581 
1,895 



3,900 



1,027 
2,873 



749-026 O - 64 ■ 



58 



SYNTHETIC ORGANIC CHEMICALS, 1963 
TABLE 21A. — Miscellaneous chemicals: U.S. production and sales , 1963 — Continued 



Chemical 



Production 



Quantity 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 



Polyacryllo acid salts- 
Polyethylene glycol 



Polypropoxy ethers, total 

Glycerol tri ( polyoxypropylene ) ether- 
All other 



Polypropylene glycol 

Propionic acid 

Propionic acid salts: 

Calcium propionate 

Sodium propionate 

Propylene glycol (1,2-Propanediol)- 

Propylene oxide 

Sarcosine and salt 



Sequestering agents, total 

(Diethylenetrlnltrilo)pentaacetic acid, sodium salt 

CEthylenedlnltrilo)tetraaoetic acid ( Ethylenediamlne- 

tetraaoetic acid) 

(EthylenedlnitriloHetraaoetic acid, monosodium Iron salt 

(Ethylenedinitrllo)tetraacetic acid, tetrasodium salt 

( N-ftydroxyethylethylenedinitrilo)triacetio acid, 

trisodium salt 

All other 



Sodium formaldehydesulfoxylate 

Sodium methoxide (Sodium methylate)- 

Stearlc acid salts, total* 

Aluminum stearates, total 

Aluminum disteeirate 

Aluminum stearate, other 

Calcium stearate 

l£ad stearate 

Lithium stearate 

Magnesium stearate 

Zinc stearate 

All other 



Triethylene glycol 

Urea in compounds or mixtures (100)6 basis) 

In feed compounds 

In liquid fertilizer 

In solid fertilizer 

All other 



Vinyl acetate, monomer 

All other miscellaneous acyclic chemicals- 



1,000 
pounds 

2,577 
32,809 

134,711 



i,951 
47,760 

79,488 
30,451 

15,401 

4,956 

199,759 

496,921 

1,125 

28,144 



1,155 

4,042 

271 

15,499 

3,013 
4,164 

6,050 
6,486 

30,885 



4,971 

3,693 

1,278 

10,836 

646 

279 

1,235 

8,567 

4,351 

37,701 

2,182,645 



252,702 
751,274 
957,039 
221,630 

405,252 
7,272,865 



1,000 
pounds 
2,501 
27,251 

112,500 



1,000 
dollars 

2,818 
6,820 

24,665 



72,512 
39,988 



61,486 
8,270 



171, 172 
51,625 



19,385 



15,397 
9,268 



8,358 
1,068 



18,883 
6,072 



8,048 



2,072 
10,681 



2,127 
4,505 



5,182 
5,169 



28,457 



4,992 

3,727 

1,265 

10,689 

420 

266 

1,237 

8,240 

2,613 

30,368 

2,029,688 



3,990 



1,211 
1,988 



1,114 
1,327 



9,963 



259,140 
667,308 
958,608 
144,632 

171,806 
2,350,805 



1,' 

1,385 
523 

2,984 
152 
137 
492 

3,119 

1,171 

4,957 
^° 87,412 



11,258 

29,505 

40,461 

6,188 

22,703 
751,118 



.32 



^ Calculated from rounded figures. 

^ Statistics exclude production and sales of tricresyl phosphate. Statistics on tricresyl phosphate are given in 
the section "Plasticlzers. " 

^ Quantities are given on the basis of solid naphthenate, tallate, or llnoleate content. 

' Statistics exclude production and sales of copper naphthenate. Statistics on copper naphthenate are given in the 
section "Pesticides and Other Organic Agricultural Chemicals." 

' In addition, sales of recovered acetic acid totaled 57,931,000 pounds, valued at $2,942,000. 

' Statistics on production of ethyl alcohol from natural sources by fermentation are issued by the Alcohol Tax 
Unit, U.S. Internal Revenue Service. 

'' Statistics exclude production and sales of potassium and sodium oleate. Statistics on these oleates are included 
In the section "Surface-Active Agents." 

' Statistics exclude production and sales of potassium and sodium stearates. Statistics on these stearates are in- 
cluded in the section "Surface-Active Agents." 

' Production of urea in primary solution totaled 2,211,558 thousand pounds. 

^° Includes estimated values for sales of urea in nitrogen compounds. 



MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 59 

The total output of miscellaneous cyclic chemicals in 1963 was 953 million pounds, or 11.1 
percent more than the output of 858 million poimds reported for 1962. Sales in 1963 totaled 477 
million pounds, valued at $191 million, connpared with 426 million pounds, valued at $159 mil- 
lion, in 1962. The most important subgroup of cyclic connpoxinds was the lubricating oil additives, 
the output of which was 374 million pounds in 1963. 

Total production of miscellaneous acyclic chemicals in 1963 was 40.2 billion pounds --9. 5 
percent more than the output of 36. 7 billion pounds reported for 1962. Sales in 1963 totaled 17. 
billion pounds, valued at $2.2 billion, connpared with 16.2 billion pounds, valued at $2. 1 billion, 
in 1962. 

Production of alcohols and halogenated hydrocarbons in 1963 each exceeded that of any of the 
use groups of synthetic organic chemicals except cyclic intermediates and plastics and resin 
materials. Production of monohydric, unsubstituted alcohols totaled 7.2 billion pounds in 1963, 
about 8. 9 percent nnore than in 1962. Alcohols are used as solvents, intermediates, and anti- 
freeze materials, and for other purposes. Production of halogenated hydrocarbons totaled 7.2 
billion pounds in 1963, or 5. 5 percent more than the 6. 8 billion poiinds reported for 1962. 
Halogenated hydrocarbons are used as solvents, intermediates, refrigerants, and aerosol pro- 
pellants, and for other purposes. 

Individual miscellaneous chemicals the output of which exceeded 1 billion pounds in 1963 
were formaldehyde (2. 5 billion pounds, compared with 2.4 billion pounds in 1962); synthetic 
methanol (2.3 billion pounds, compared with 2.2 billion pounds); urea (2.2 billion pounds, com- 
pared with 2. billion pounds); ethyl alcohol (2. billion pounds, compared with 1. 7 billion 
pounds); ethylene oxide (1.9 billion pounds, compared with 1. 5 billion pounds); dlchloroethane 
(1.8 billion pounds in each year); ethylene glycol (1.7 billion pounds, compared with 1.4 billion 
pounds); isopropyl alcohol (1.5 billion pounds, connpared with 1. 3 billion pounds); vinyl chloride 
(1.4 billion pounds, compared with 1. 3 billion pounds); and acetic anhydride (1.3 billion pounds, 
connpared with 1. 2 billion potmds). 



PART m. ALPHABETICAL LIST OF INDIVIDUAL PRODUCTS, BY GROUPS, 
AND NAMES OF MANUFACTURERS 

This section of the report consists of (1) a series of tables that supplement the statistical in- 
formation given in parts I and II, and (2) a Directory of Manufacturers. The tables with numbers 
that include the letter "B" supplement the tables in part I or part II with numbers that include the 
letter "A"; for example, table 8B in part III supplements table 8A in part II. 

Each table in part III lists alphabetically the individual items in each group for which data on 
production or sales were reported for 1963. The tables include data on only those chemicals for 
which the volume of production or sales in 1963 exceeded 1, 000 pounds or for which the value of 
sales exceeded $1, 000. Where separate statistics for an item are given in the tables m part I or 
part II, an asterisk (*) precedes the name of the item in the tables in part III. The manufacturers 
of each product are indicated by identification codes which are listed in the Directory of Manufac- 
turers (table ZZ). A few companies, however, have specifically requested that they not be identified 
as having produced or sold certain items. These manufacturers are indicated by a small letter "x" 
in the tables. 

Tar Crudes 

TABLE AB.—Tar crudes for which U.S. production or sales were reported, identified by manufacturer, 1963 

[Tar crudes for which separate statistics are given in table ^k are marked below with an asterisk (•); products not 
so marked do not appear in table ^k because the reported data are accepted in confidence and may not be published. 
Manufacturers' identification codes shown below eire taken from table 22. Table 22 identifies all U.S. producers of 
tar crudes (except producers that report to the Division of Bituminous Coal, U.S. Bureau of Mines)] 



tonufaoturers ' identification codes 
(according to list in table 22)^ 



»Crude light oil 

Light-oil distillates: 

»Benzene, specification and Industrial grades 

"Toluene, specification and other grades 

•Xylene, all grades 

•Solvent naphtha 

All other light-oil distillates - 

Pyridine crude bases 

•Naphthalene, crude, solidifying at — 

•Less than 74° C -- 

»7<i° C. to less than 76° C- 

•76° C. to less than 79° C 

Crude tar-acid oils having a tar-acid content of — 

5^ to less than 245' 

2^i to 515t - - 

Cresylic acid, crude 

•Creosote oil (Dead oil): 

•Distillate as such 

•Creosote in coal-tar solution 

All other distillate products 

•Tar, road 

•Tar for other uses: 

Crude 

Refined 

Pitch of tar: 
•Soft and medium (water softening points less than 
110° F., and 110° F. to 160° F.). 

•Hard (water softening point above 160° F.) 

•Pitch-of-tar coke and pitch emulsion 



CBT, RUR. 



ACP, 


ACY, 


COS, 


KPP. 








ACY, 


COS, 


KPP. 










ACP, 


ACY, 


COS, 


KPP. 








ACY, 


KPT, 


NEV, 


PAI. 








ACP, 
ACP, 


NEV, 
KPT. 


PAI. 










COP, 


NEV, 


PAI. 










KPT. 














ACP, 


KPT, 


PRD, 


RIL, 


RUR, 


WTC. 




ACP, 


COP, 


RIL. 










ACP, 


KPT, 


NEV, 


RIL, 


WTC. 






ACP, 


KPT, 


PRD. 










ACP, 


ACY, 


CBT, 


COP, 


KPT, 


RIL, 


RUR, WTC 


ACP, 


HUS, 


JEN, 


KPT, 


RIL, 


RUR, 


WTC. 


ACP, 


KPT, 


PAI. 










ACP, 


KPT, 


RIL, 


WTC. 








KPT, 


RIL, 


WTC. 










ACP, 


KPT, 


RIL, 


RUR, 


WTC. 






ACP, 


CBT, 


COP, 


JEN, 


KPT, 


RIL, 


RUR, WTC 


ACP, 


COP, 


KPT, 


RIL, 


WTC. 






JEN, 


RIL, 


WTC. 











^ Does not include manufacturers ' identification codes for producers that report to the Division of Bituminous 
Coal, U.S. Bureau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey, June 8, 
1964, entitled "Coke Producers in the U.S. in 1963." 

^ Crude light oil production and sales of these 2 companies are not included with the U.S. Bureau of Mines 
fig ures given in table 4A. 



61 



62 



SYNTHETIC ORGANIC CHEMICALS. 1963 
Crude Products From Petroleum and Natural Gas for Chemical Conversion 



TABLE 5B. — Crude products from petroleum and natural gas for chemical conversion for which U.S. production 
or sales were reported, identified by manufacturer , 1963 

[crude products from petroleum and natural gas for chemical conversion for which separate statistics are given in 
table 5A are marked below with an asterisk (»); products not so marked do not appear in table 5A because the 
reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown be- 
low are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the 
designated product] 



Manufacturers ' identification codes 
(according to list in table 22) 



ARCMATICS AND NAPHTHENES 

^Alkyl aromatics, distillates, and solvents 

»Benzene (except motor grade): 

»Benzene, 1° 

"Benzene, 2° 

»Cresylio acid, crude 

"Naphthalene, all grades 

»Naphthenic acids: 

Acid number lower than 150 

»Acid number 150-199 

Acid number 200-224 --- 

Aold number 225-249- -- 

Sodium oarbolate and phenate, crude 

"Toluene : 

"Nitration grade, 1° 

"Pure commercial grade, 2° 

Solvent grade 

All other 

"Xylenes, mixed: 

Aviation grade 

"3° 

"5° 

All other 

All other aromatics and naphthenes 

ALIPHATIC HTOROCARBONS 

Ci hydrocarbon: Methane 

"C2 hydrocarbons: 

"Acetylene 

"Ethane 

"Ethylene 

C2 and C3 hydrocarbons, mixed 

"C3 hydrocarbons: 

"Propane 

"Propane -propylene mixture 

"Propylene 

"C4 hydrocarbons: 

"1,3-Butadiene, grade for rubbers (elastomers )- 

"Butadiene and butylene fractions 

»n-Butane 



ACC, CSD, DUP, DXS, ENJ, FG, GOC, GRS, JCC, MOC, MON, 
QMC, PAS, PLC, SIO, SM, SOG, USI, VPT, VfYN. 

APR, ASH, AIR, CCP, CSD, DLH, DXS, ELP, ENJ, GOC, GRS, 
MOC, MON, PLC, PLP, PRO, RIC, SHO, SM, SNT, SOG, STH, 
SUN, VPT, TOC, TX. 

ACC, AMO, CO, DOW, SHO, SOC, UCC. 

ATR, PRD, RIC, SHO, SOI. 

ASH, COL, CSO, MON, SUN, TID. 

RIC, SUN, TX. 
RIC, SM, SOC, SUN. 
RIC, SM, SOC. 
NOP, RIC, SM, SOC. 
ATR, GOC, SIN. 

ASH, ATR, CCP, CSD, DLH, ENJ, GOC, GRS, LEN, MOC, MON, 

PRO, RIC, SHC, SHO, SIN, SNT, SOG, SUN, TOC, TX, VPT. 
DOW, MON, RIC. 
ASH, CO, FG, PLP, UCC. 
CSD, DXS, ENJ, GRS, RIC, SHO, SM, SOC, SUN, TOC, TX, VEL. 

CSD, CSO, SOG. 

ASH, ATR, DLH, ENJ, GRS, MON, PRO, SNT. 

CCP, MOC, SIN. 

AMO, CSD, DXS, ENJ, GRS, LEN, MON, SHO, SM, SOC, SOG, 

SUN, TOC, VPT. 
ELP, ENJ, LEN, MON, PLC, SM. 



CCP, MOC, PAN. 

ACY, DOW, DUP, MNO, MON, UCC, x. 

CCP, COR, ENJ, MOC, MON, PAN, SHC, SHO, SM, SOI, TX, UCC, 

USI. 
CCP, COR, DOW, DUP, EKX, ELP, ENJ, GOC, JCC, KPP, MOC, 

MON, OMC, PET, PLC, RIC, SHC, SM, SNO, TX, UCC, USI. 
COR, GYR, SM. 

AMO, ASH, CCP, COR, CSD, DXS, ENJ, MOC, OMC, PAN, PLC, 
PLP, RIC, SHO, SIN, ai, SNT, SOG, SOI, SPI, UCC, USI. 

ELP, GOC, PLC, TX. 

ASH, CCP, COR, DOW, EKX, ELP, ENJ, GOC, JCC, MOC, MON, 
PET, PLC, RIC, SHC, SHO, SIN, SM, SOG, SOI, SPI, SUN, 
UCC, UOC. 

CPY, DOW, ELP, ENJ, FRS, GGC, ILC, MON, PET, PLC, PTT, 

SHC, SM, SOC, SPI, TID, TUS, UCC. 
DOW, GYR, PLC, SHC, SHO, SIN, SOC, SPI. 
CCP, CSD, DXS, ELP, MOC, OMC, PAN, PLC, PLP, SHM, SHO, 

SM, SNT, SOC, SOG, SOI, UCC, USI. 



CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS 



63 



TABLE 5B. 



- Crude products from petroleum and natural gas for chemical conversion for which U.S. production 
or sales were reported, identified by manufacturer, 7 563 --Continued - — 



Manufacturers' identification codes 
(according to list in table 22) 



ALIPHATIC HYDROCARBONS— Continued 

*Ci, hydrocarbons — Continued 

»1-Butene 

2-Butene 

»1-Butene and 2-butene mixtiire 

»Isobutane 

»Isobutylene 

All other 

»C5 hydrocarbons: 

lEopentane ( 2-Methylbutane ) 

»Isoprene (2-Methyl-l,3-butadiene) 

n-Pentane 

All other 

Cft liydrooarbons; 

Diisopropyl (2,3-Dimethylbutane ) 

*Hexane 

Neohexane ( 2 , 2-Dijnethy Ibutane ) 

All other 

C7 hydrocarbons: 

»n-Heptane 

»Heptenes, mixed 

All other 

Cs hydrocarbons: 

»Dlisobutylene ( Diisobutene ) 

n-Ootane 

2,2,'i-Triniethylpentane (Iso-oetane) 

All other 

Hydrocarbons, Cg and above: 

1-Dodecene 

Eicosane 

»Nonene (Tripropylene) 

Pentadecene 

«Polybutene 

»Tetrapropylene 

Tridecene concentrate 

Triisobutylene 

All other 

•Hydrocarbon derivatives: 

1-Butanethiol 

tert-Butyl meroaptan (2-Methyl-2-propanethiol) 

Di-tert-butyl disulfide 

Di-tert-nonyl polysulfide 

tert-Dodecyl mercaptan 

Ethyl mercaptan (Ethanethiol) 

Isopropyl meroaptan 

Methyl mercaptan (Methanethiol) 

tert-Octyl mercaptan 

n-Propyl mercaptan (1-Propanethiol) 

All other 

All other aliphatic hydrocarbons 



PLC, 
MON, 
AMD, 

CCP, 
CCP, 
APR, 

APR, 
EN J, 
APR, 
ENJ, 

PLC. 
ENJ, 
PLC. 
APR, 

CSD, 
ACC, 
PLC. 

ATR, 
ENJ, 
ENJ. 
PLC. 



PTT, SPI. 

PLC, PTT, SPI. 

CCP, ENJ, GOC, MOC, PLC, PRO, SHO, SOC, SOI, TX. 

DXS, ELP, MOC, CMC, PAN, PLC, SHO, SOI, UCC, USI. 

ENJ, PRO, PTT, SIN. 

JCC, MON, SM, SOI, UCC, USI, x. 

CCP, CSD, ENJ, PLC, SHO, SM, SOI, UCC. 

GYR, PLC, SHC. 

PLC. 

GYR, MOC, MON, PAS, PET, PLC, SOI, USI. 



PLC, PRO, SOG. 
PLC. 



EKX, ENJ, PLC, PRO. 

ENJ, GOC, HOU, SIN, SOG, TID. 



PTT, SHC, TX. 
PLC. 



CSD, SOC, SOI, TX. 

DXS, ENJ, GOC, MOC, PRO, RIC, SNT, SOC, SUN, TX. 



CO. 

ATR. 

ACC, AMO, ENJ, GOC, PRO, RIC, SUN. 

CO. 

ACC, 

ACC, 

ENJ. 

ATR. 

CO, EKX, ENJ, GOC, HOU, KEN, PLC, RIC, SOC, SOI, TID. 



PAS. 
PAS, 
PLC. 
PAS. 
PAS, 
CSD, 
PAS, 
ACC, 
PLC. 
PAS. 
EKX, 
ATR, 



PAS, SOC. 

SOC. 

PAS. 



PAS, PLC, SOC. 
GOC, SOC. 



64 



SYNTHETIC ORGANIC CHEMICALS, 1963 
Cyclic Intermediates 



TABLE IB. --Cyclic intevmediates for which U.S. production or sales were reported, identified by 

manufacturer, 1963 

[Cyclic intermediates for which separate statistics are given in table 7A are marked below with an asterisk (*); 
cyclic intermediates not so marked do not appear in table 7A because the reported data are accepted in confidence 
and may not be published. Manufacturers' identification codes shown beloff are taken from table 22. An x signifies 
that the manufacturer did not consent to his identification with the designated product. V^pendix B lists alpha- 
betically all the important common names of cyclic intermediates usually encountered in the trade and gives the 
corresponding standard (Chemical Abstracts) name under which the manufacturers' identification codes are given in 
this table] 



Manufacturers' identification codes 
(according to list in table 22) 



Aceanthryleno[2,l-a] aceanthrylene-5,13-dione 

3-(2-Acetamido-'4-aminophenyla2o)-l, 5-naphthalenedi- 
sulfonic acid. 

p-Acetamldobenzoic acid 

2-Acetamido-3-chloroanthraquinone 

8-Acetamido-l-(2-hydroxy-5- [N-methylsulf amide] - 

phenylazo) -2-naphthol. 
8-Acetamido-2-naphthalenesulfonic acid 

»Acetanilide, tech 

Acetoacetanilide 

o-Acetoacetanisidide 

o-Acetoacetotoluidide 

1' -Acetonaphthone 

Acetone phenylbydrazone 

Aoetophenone, tech 

p-Acetotoluidide 

N-Acetylanthranilic acid 

p-Acetylbenzenesulfonamide 

p-Acetylbenzenesulfonic acid, sodium salt 

p-Acetylbenzenesulfony lure thane 

N-Acetylsulfanilyl chloride 

Adenine 

Alkylbenzene 

Alkylphenol, mixed 

a-dl-5- Allyl-6-imlno-l-methyl-5- ( l-methyl-2-pentynyl) - 

barbituric acid. 
Aminoaceanthryleno[2,l-a] aceanthrylene-5,13-dione 

»<i'-Amlnoacetanllide (Acetyl-p-phenylenediamine) 

3'-Aminoacetophenone 

*5-Amino-2-(p-a7in'noam. lino) benzene sulfonic acid 

l-Amino-4— (3-amino—4-sulfoanllino)-2-anthraqulnonesul- 

fonic acid. 
l-Araino-<i-(4— amlno-3-sulfoanilino)-2-anthraquinonesul- 
fonic acid. 

5-Amlno-2-anilinobenzenesulfonio acid 

2-(p-Aminoanllino)-5-nitrobenzenesulfonic acid 

3-Amino-p-anisamide 

3-Amino-p-anisanilide 

»l-Aminoanthraquinone and salt 

»2-Aminoanthraquinone and salt 

l-Amino-2-anthraquinonecarboxylic acid 

l-Amino-2-anthraquinonesulfonic acid 

5(and 8)-Amino-l-anthraquinonesulfonic acid 

N-(A-Amino-l-anthraquinonyl) anthranilio acid 

N-(5-Amino-l-anthraqulnonyl) anthranilic acid 

N-[5(and 8)-Amino-l-anthraquinonyl]anthranilic acid — 
"i-Aninoantipyrine 

»6-Amino-3,'4' -azodi(benzenesulfonic acid) 

8-Aminobenz[a]acridln-7(12H)-one 

♦l-Amino-^-benzamldoanthraquinone 

l-Amino-5-benzamidoanthraquinone 



ICI. 




TRC. 




DUP. 




ICI, 


G. 


TRC. 




DUP. 




EKT, 


MRK, SAL, SW. 


FlvlP, 


UCC. 


FMP, 


UCC. 


FMP, 


UCC. 


GIV. 




DUP. 




ACP, 


UCC. 


ACY. 




DUP. 




LIL. 




LIL. 




LIL. 




ACY, 


MRK, SAL. 


ARA. 




ATR. 




G. 




LIL. 




ICI. 




DUP, 


G, NAC, TRC. 


SDH. 




CMG, 


DUP, TRC, YAW 


TRC. 





NAC. 

CMG, DUP, NAC, TRC. 



AAP, ACY, DUP, G, ICI, MAY, NAC, TRC. 

ACY, DUP, G, NAC, TRC. 

DUP. 

G. 

ICI, TRC. 

G. 

DUP. 

DUP. 

NAC, SDW. 

AAP, CMG, NAC. 

NAC. 

ACY, MAY, NAC, TRC. 

G, ICI, NAC, TRC. 



CYCLIC INTERMEDIATES 



65 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer , 1963 — Continued 



Manufacturers' identification cedes 
(according to list in table 22) 



6-[ p-(p-Aminobenzamido)benzaiiiido] -l-naphthol-3-sulfonlc 
acid. 

*6-(p-Aiiiinobenzamido)-l-naphthol-3- sulfonic acid 

^'-Aminobenzanilide 

«2-Amino-p-benzenedisulfonic acid [S03H=1] 

o-Aminobenzenesulfonic acid 

2-Anilnobenziiiu.dazole 

5-Amino-2-benzimidazolinone 

p-Minobenzoic acid, tech 

p-itaiinobenzoic acid, diethylaminoethyl ester ( Procaine) --- 

2-Amino-6-benzothiazolecarboxylic acid 

5(and 8)-Amino-8(and 5)-bromo-l,6(and l,7)-anthraquinone- 
disulfonic acid. 

»l-Amino-'i-bromo-2-antliraquinonesulfonic acid and sodium 
salt. 

»2-Amino-l-bromo-3-chloroanthraquinone 

l-Amino-2-bromo-'V-hydroxyanthraquinone 

l-Anino-'i-bromo-2-inethylanthraquinone 

»l-Mino-2-bromo-4-(p-toluidino)anthraquinone 

l-Amino-2-chloroanthraqulnone 

»l-Amino-5-chloroanthraquinone 

»1- Amino- 5 (and 8)-chloroanthraquinone 

l-Amino-8-chloroanthraquinone 

2-Aiiino-l-chloroanthraquinone 

2-Amino-3-chloroanthraquinone 

l-Amino-N-(3-chloro-2-anthraquinonyl)-2-anthraqulnone car- 
boxamide. 

^-Anino- 6- chloro-m-benzenedi sulfonamide 

5-Aminochlorobenzolc acid 

2-Aniino-6-chlorobenzothiazole hydrochloride 

*o-(3-Amino-'i.-chlorobenzoyl)benzoic acid 

4-Amino-6-chloro-N,N'-dimethyl-m-benzenedisulfonamide 

2-Amlno-5-ohloro-<i-ethylbenzenesulfonic acid 

l-Mino-2-chloro-4-hydroxyanthraquinone 

2-Amino-A-chlorophenol 

»6-Aiiino-i-chloro-l-phenol-2- sulfonic acid 

3-Amino-6-chloropyridazine 

»2-Amino-5-chloro-p-toluenesulfonic acid [S03H=l] 

*6-Aiiino-'i-chloro-m-toluenesulfonic acid [SOjHsl] 

2-Anlno-p-cresol 

»l-Amino-2,'4-dibromoanthraquinone 

l-Amino-5,8-dichloroanthraquinone 

i.' -tmlno-2 ', 5'-diethoxybenzanilide 

3-iimino-7-diethylamino-5-phenylphenazium chloride 

l-Mino-2,'4-dihydroxyanthraquinone - 

3- Amino-N,N-dimethyl-p-toluene sulfonamide 

5-Mino-2-(2-ethoxyanllino)benzenesulfonic acid, sodium 
salt. 

3-Amino-9-ethyloarbazole 

3-Amino-6-ethoxypyTidazine 

p-Mino-N-ethyl-N-1-naphthylbenzamide 

2-Amino-N-ethyl-5-nitrobenzenesulfonanilide 

2-Amino-5-ethyl-l,3,'i-thiadiazole 

»l-Aiiino-'i-hydroxyanthraquinone 

3-Amino-2-hydroxyanthraquinone 

l-Amino-<i-hydroxy-2-anthraquinonesulfonic acid 

2-Amino-'4-hydroxybenzenearsonic acid 



CMG, 


DUP, G, NAC. 


TRC. 




DUP, 


G, NAC, VPC. 


DUP. 




EK. 




DUP. 




DUP, 


G, NAC. 


LEM, 


SDW. 


DUP. 




TEC. 




AAP, 


DUP, G, ICI, NAC, TRC. 


AAP, 


ICI, MAY. 


DUP, 


G, ICC, TRC. 


ICI. 




G, ICI, TRC. 


AAP. 




ACY, 


DUP, ICI, MAY, NAC, TRC 


ACY, 


DUP, NAC. 


DUP, 


NAC. 


DUP, 


G. 


G, ICI, MAY. 


TRC. 




ABB. 




TRC. 




DUP. 




AAP, 


G, ICI, MAY. 


ABB. 




ACY. 




AAP. 




G, MEE, NAC. 


CMG, 


NAC, TRC. 


ACY. 




ACY, 


HCC, sue, SW. 


ACY, 


DUP, HCC, SW. 


TRC. 




DUP, 


G, ICC, ICI, NAC, TRC. 


TRC. 




G. 




DUP. 




TRC. 




G. 




NAC. 




DUP. 




ACY. 




G. 




G. 




ACY. 




AAP, 


DUP, G. 


G, NAC. 


TRC. 




SOT. 





66 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



8- [^-(g-Amino-l-hydroxy-S.e-disulfo-a-naphthylazoj-S- 
methoxy-o-tolylazo] -l-naphthol-3,6-disulfonic acid, 
benzenesulfonate. 
l-Amlno-'i-[m-(2-hydroxyethylsulfonyl) anilino] -2-anthra- 
quinonesulfonic acid. 

3-Amino-6-hydroxy-2-methylphenazlne (Tolazine base) 

l-(6-Amino-l-hydroxy-3-sulfo-2-naphthylazo)-6-nitro-2- 
naphthol-'4-Eulfonlc acid. 

5-Aminoisophthalic acid 

2- Aiiino-N-isopropyl-l-phenol-4- sulfonamide 

l-Amino-4— methoxyanthraquinone 

N- ( <i- Amino-3-niethoxy- 1-anthr aquinonyl) -p- toluenesulf on- 
amide. 

5-Amino-6-methoxy-2-naphthalenesulfonic acid 

m-('4-Araino-3-methoxyphenylazo)benzenesulfonic acid 

3-Mino-6-methoxypyridazine 

*l-Amino-2-methoxy-A-(p-toluenesulfonamido)anthraqulnone 

3-(<i-Amino-5-methoxy-o-tolylazo)-l, 5-naphthalenedlsulfonio 

acid. 
7-('i-Ainino-5-methoxy-o-tolylazo)-l,3-naphthalenedisulfonic 

acid. 
8-('4-Amino-5-methoxy-o-tolylazo)-l-naphthol-3,6-disulfonic 
acid, benzenesulfonate. 

»'4'-Ainino-N-methylacetanilide 

l-Amino-2-methylanthraquinone 

4'-Amino-6'-methyl-ni-benzanisidide 

4-Ainino-4'-(3-methyl-5-oxo-2-pyrazolin-l-yl)-2,2'-stilbene- 
di sulfonic acid. 

8-Amlno-7-methyl-2-phenazinol . 

2- Amino- N-me thy l-l-phenol-'i- sulfonamide 

2-Amino-<i-methylpyrimidine (2-Mino-<i-methyldiazine) 

2-Amino-4-(methylsulfonyl)phenol 

2-Aiiilno-5-methyl-l,3,'i-thiadiazole 

l-Amino-2-methyl-A-(p-toluidino)anthraquinone 

4-Aminonaphth[2,3-c] acridan-SjSjl^-trione 

6-Aminonaphth[2,3-c] acridan-5,8,l<i(13H)trione 

l(and 'i)-Aminonaphth[2,3-c] acridine-5,8,l'i(13H)trione 

*2- Amino- 1,5-naphthalenedi sulfonic acid 

*3- Amino- 1,5-naphthalenedisulfonic acid (Cassella acid) 

3-Aniino-2,7-naphthalenedisulfonic acid 

A-Amino-ljS-naphthalenedisulfonic acid 

4-Amino-l,6-naphthalenedisulfonic acid 

»6-Amino-l,3-naphthalenedisulfonic acid (Amino I acid) 

•7-Amino-l,3-naphthalenedisulfonic acid (Amino G acid) 

2-Amino-l-naphthalenemethanesulfonio acid 

l-Amino-2-naphthalenesulfonlc acid (o-Naphthionlo acid) 

»2-Amino-l-naphthalenesulfonic acid (Tobias acid) 

4(and 5)-Amlno-l-naphthalenesulfonic acid 

5-Amino-l-naphthalenesulfonic acid (Laurent's acid) 

•5-Amino-2-naphthalenesulfonic acid (l,6-Cleve's acid) 

»5(and 8)-Amino-2-naphthalenesulfonio acid (Cleve's acid, 
mixed) . 

6-Amino-l-naphthalenesulfonic acid 

»6-Amino-2-naphthaleneEulfonic acid (Broenner's acid) 

*8- Amino- 1-naphthalenesulfonic acid (Peri acid) 

♦8-Amino-2-naphthalenesulfonic acid (1,7-Cleve's acid) 

7- Amino- 1, 3, 6-naphthalenetri sulfonic acid 

8-Amino-l,3,6-naphthalenetrisulfonic acid (Koch's acid) 



Manufacturers' identification codes 
(according to list in table 22) 



MAC. 
THC. 



TEC. 
DUP. 
DUP. 

NAC, TRC. 

DUP, TRC. 

ACY. 

AAP, G, TRC. 

TRC. 

TRC. 



CMC, 


G, NAC. 


DUP, 


ICI. 




G. 






TRC. 






DUP. 






TRC. 






ACY. 






NAC, 


TRC. 




ACY. 






ICI. 






DUP. 






G. 






DUP, 


NAC. 




ACY, 


SDH, 


sw. 


G, NAC, TRC. 


NAC, 


TRC. 




NAC. 






DUP, 


NAC. 




ACY, 


CMG, 


DUP, G, NAC, TRC 


ACY, 


DUP, 


G, NAC, TRC. 


ACY. 






DUP. 






ACY, 


IMP, 


sue, SW. 


ACY. 






DUP, 


NAC. 




ALL, 


DUP, 


Gi NAC, TRC. 


ALL, 


DUP, 


G, NAC. 


VPC. 






KLS, 


NAC, 


SNA, TRC. 


DUP, 


NAC, 


SDC, TRC. 


ALL, 


DUP, 


G, NAC, TRC. 


DUP. 






DUP, 


NAC. 





CYCLIC INTERMEDIATES 



67 



TABLE 7B. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, j 965-- Continued 



Manufacturers' identification codes 
(according to list in table 22) 



Aiiinc-l,3,5-naphthalenetrisulfcnic acid, ^,5-sultam, 
triscdium salt. 

Amino- 1- naphthoic acid 

Amino- 1-naphthol 

and :?)-Amino-2-naphthol 

Amino-2-naphthol 

Amino- l-naphthol-3,6-disulfonic acid, benzenesulfonate 

Amino- l-naphthol-3,6-di£ulfonic acid (2R acid), mono- 
sodium salt. 

Aminc-l-naphthcl-3,6-disulfonic acid (H acid), mono- 
sodi'jm sal". 

Amino-l-naphthol-5,7-disulfonic acid (Chicago acid) 
(2S acid), raonoscdium salt. 

Amino-2-naphthcl-A-sulfonic acid (1,2,'i-acid) 

Amino- l-naphthol-3- sulfonic acid (J acid), sodium salt 

Amino-l-naphthol-3-sulfonio acid (Gamma acid), sodium 
salt. 

Amino- l-naphthol-5-sulfonic acid (S acid), sodium salt 

Amino-5-nitrobenzenesulfonic acid [S03H= l] 

Amino-3-nitrcbenzcio acid 

Amino-^-nitrophenol 

Amino-5-nitrcphenol 

Amino-'i-nitro-l-phenol-2- sulfonic acid 

2-Amino-l-(p-nitrophenyl)-l,3-propanediol 

Amino-'4'-nitro-2,2'-sxilbenedisulfonic acid 

Amino- S-nitrothiazcle 

-Aniinooxanilic acid 

-Aminooxanilic acid 

Aminophenethyl alcohol 

Aminophenol 

Amino- l-phenol-2,4-disulfonic acid 

Ami no-1-phenol-A- sulfonamide 

Amino- l-phenol-'i-sulfonanilide 

Amino- l-phenol-'V- sulfonic acid 

(p-Aminophenylazolbenzenesulfonic acid 

■(p-Aminophenylazo)benzenesulfonic acid 

■(p-Aminophenylazo) salicylic acid 

■(p-Aminophenyl)-6-methylbenzothiazole 

(p-Aminophenyl) -6-methyl-7-benzothiazolesulfonio acid 
and salt. 

.(m-Aminophenyl)-5-oxo-2-pyrazoline-3-carboxylic acid 

(p-Aminophenylsulfonyl) ethyl sulfate 

•Aminopyridine 

■Aminopyridine 

•Aminopyrimidine 

•Aminosalicylic acid 

■(4-Amino-3-sulfoanthraquinonyl)anthranilio acid 

■Amino-5-(p-Eulfophenylazo)benzenesulfonic acid 

• ['i-(Amino-2-sulfophenylazo)-3-methyl-5-ox'o-2-pyrazolin-l- 
yl] -2,5-dichlorobenzenesulfonic acid. 
■-( 3-Amino-4- sulf ophenylsulf amoyl) -3" -sulfamoyl-3- 
phthalocyaninesulfonic acid, copper derivative. 

■Aminothiazole 

■ Ami no-A- (p-toluenesulf onamido ) -2- an thraquinone sulfonic 
acid. 

■Amino-4-(p-toluenesulfonamido) -2- anthraquinone sulfonic 
acid, sodium salt. 
•Amino-o-toluenesulfonanllide 



ALL, CMG, DUP, G, TRC, VPC. 

TRC. 

DUP, NAG. 

DUP, MON, NAC. 

DUP, NAC. 

ACY, DUP, G, NAC, TRC, VPC. 

ACY, CM3, DUP, G, NAC, TRC. 

DUP, G, NAC, TRC. 



NAC. 

ACY, 

DUP. 

DUP, 

NAC. 

TRC. 

PD. 

NAC, 

EKT. 

CMG. 

DUP. 

EKT. 

ABB, 

TRC. 

CMG, 

TRC. 

AAP, 

AAP, 

ACY, 

TRC, 

DUP, 

DUP. 



DUP, NAC, TRC. 
G, NAC, IRC. 



DUP, SDC. 

DUP, NAC, TRC, VPC. 

CWN, DUP, NAC, TRC. 

TRC. 

CMG, DUP, G, NAC, TRC. 

VPC. 

NAC. 



VPC. 

HST. 

NEP, RIL. 

RIL. 

ACY. 

AAP. 

G. 

DUP. 

DUP. 

DUP. 

ACY, MRK. 
AAP. 

DUP, G. 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer , 1963 — Continued 



Manufacturers ' Identification codes 
(aooordlng to list in table 22) 



*4-Amino-m-tolueneEulfonic acid [ SO3H = l] 

»6-Anino-m-toluenesulfonic acid [SOjHil] 

5-Amino-2-(p-toluidino)benzenesulfonic acid 

m-('4-Amino-3-tolylazo)benzenesulfonic acid 

V-J-i-Amino-o-tolylazo) -1,5-naphthalenedisulfonic acid 

6-Amino-s-triazine-2,4-dithiol 

2-Amino-3,A,6-trlchlorophenol 

»16-Aminoviolanthrone 

»2-Amino-3,5-xylenesulfonic acid [SO3H =l] 

5-Amino-2,'i-xylldinesulfonic acid 

♦Aniline (Aniline oil) 

Aniline hydrochloride 

l-Anilino-2-anthraquinonecarboxylio acid 

*Anilinoinethanesulfonic acid and salt 

*8-Anilino-l-naphthaleneEulfonic acid (Phenyl peri aoid)--- 

*6-Anllino-l-naphthol-3-sulfonic acid (Phenyl J acid) 

7-Anilino-l-naphthol-3-sulfonic acid (Phenyl gamma acid)-- 

m-Anilinophenol 

Anisic acid 

o- Anisic acid 

«o-Anlsidine 

p-Anisidine 

p-Anisidine hydrochloride 

l-p-Anisidino-4-hydroxyanthraquinone 

■»o-Anisidinomethanesulfonio acid 

Anisole, tech 

'i-(o-Anisylazo)-o-anlsidine 

Anthracene, refined 

Anthraflavic acid (2,6-Dihydroxyanthraquinone) 

Anthranilic acid (o-Aminobenzoio acid) 

»Anthra[l,9]pyrazol-6(2H)-one ( Pyrazoleanthrone ) 

»Anthraquinone, lOO^t 

2-Anthraquinonecarboxylic acid 

*1,5-Anthraquinonedisulfonic acid 

1, 5-Anthraquinonedisulf onic acid, disodium salt 

l,5(and l,8)-Anthraquinonedisulfonic acid and salt 

1,8-Anthraquinonedisulfonic acid 

■»l,8-Anthraquinonedisulfonic acid, potassium salt 

*2,6-Anthraquinonedisulfonlc acid and salt 

*l-Anthraqiiinonesulfonic acid and salt 

2-Anthraquinonesulfonic acid and salt (Silver salt) 

1,1'- [1,5 (and 1,8)-Anthraquinonylenediamlno]bisnaphth- 
[ 2,3-c] acridan-5, 8, l-i-trione . 

»N, N'-(l,5-Anthraquinonylene)dianthranilic acid 

N,N '-(l,5-Anthraquinonylene)dloxamic acid 

l-(l-Anthraquinonyl)-l,2-hydrazinedisulfonic acid, 
disodium salt. 

»Anthrarufin (1,5-Dihydroxyanthraquinone) 

Arbutin (Ifono-p-hydroquinone gluooside) 

Arsanilic acid and salt, tech 

^' ,U' ' '-Azobis ["i-biphenylcarboxylic acid] 

<4,A-Azobis[p-phenylbenzoic acid] 

Barbituric acid 

Barbituric acid, sodium derivative 

»Benzaldehyde , tech 

5-Benzamido-l,4-bis(l-anthraquinonylamino)anthraquinone — 

l-Benzamido-'+'broraoanthraquinone 

l-Benzamldo-'i-ohloroanthraquinone 

«l-Benzamido-5-chloroanthraquinone 



ACY, DUP, G, SNA. 

DUP, NAC, SDH, SW. 

DUP, NAC, TRC. 

TRC. 

TRC. 

RBC. 

TRC. 

ACY, G, TRC. 

NAC, SDH, STG, WJ. 

DUP. 

ACY, DOW, DUP, NAC. 

ACY. 

NAC. 

AAP, ACY, DUP, NAC, TRC, VPC. 

CMG, DUP, G, NAC, SDC. 

ALT, CMG, DUP, G, NAC, TRC. 

DUP, G, NAC. 

G. 

HN, ICI. 

ACY. 

AAP, AXL, DUP, MON. 

DUP, MON. 

EK. 

AAP. 

DUP, G, NAC, TRC, VPC. 

DUP, LIL. 

AAP. 

ACP. 

G, NAC. 

DUP, LEM, MEE, NAC. 

DUP, NAC, TRC. 

ACY, DUP, G, NAC, TRC. 

ACY, NAC. 

ACY, DUP, ICI, TRC. 

DUP, G, TRC. 

AAP, DUP, TRC. 

DUP. 

G, ICI, NAC, TRC. 

AAP, DUP, G, ICI, NAC, TRC, VPC. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC. 

ACY, DUP, NAC. 

DUP. 

DUP, ICI, TRC. 

G, MEE. 

DUP. 

ACY, CMG, DUP, G, NAC, TRC. 

UP J. 

ABB. 

DUP, TRC. 

G. 

ABB, KF, LIL. 

ABB. 

BPC, HN, TNP. 

TRC. 

AAP. 

DUP, G, TRC. 

ACY, DUP, G, ICI, MAY, NAC, TRC. 



CYCLIC INTERMEDIATES 



69 



• Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



l-Benzajiu.do-5,8-dichloroanthraquinone 

l-(';-Benzaiiiido-2,5-diethoxyphenyl)-3-inethyl-3-(2-sulfo- 

ethyl) triazene. 
[3-(4-Benzaniido-6-methoxy-in-tolyl)-l-methyltriazen-3-yl]- 
acetic acid. 

8-Benzainido-l-naphthol-3,5-dlsulfonic acid 

Benzanilide 

»7H-Benz[de] anthracen-7-one ( Benzanthrone ) 

m-Benzenedisulfonic acid 

Benzenesulfonamide 

Benzenesulfonic acid 

Benzenesulfonic acid, 2-propyn-l-ol ester 

Benzenesulfonyl chloride 

Benzhydrol ( Diphenylmethanol ) 

Benzidine base 

»Benzidlne hydrochloride and sulfate 

Benzil (Bibenzoyl) 

Benzilic acid 

l-Benzamido-5- (p-toluenesulf onamido ) anthraquinone 

2-Benzofuranacetonitrile 

■"Benzoic acid, tech 

Benzoin 

a-Benzoin oxime 

Benzonitrile 

IH-Benzotriazole 

Benzoylacetic acid, ethyl ester 

*o-Benzoylbenzoic acid 

Benzoyl chloride 

2-Benzoyl-4-sulfobenzoic acid 

2-Benzoyl-4' -( p-toluenesulf onamido) acetanilide 

Benzylamine 

Benzyl chloroformate 

4-Benzyl-6-chloro-2-methyl-3-oxo-7-sulfaiiioyl-l,2,'i-benzo- 

thladiazine-1, 1-dloxide . 
4-Benzyl-6-chloro-3-oxo-7-sulfajiioyl-l,2,4-benzothla- 
diazlne-l,l-dioxide. 

Benzyl disulfide 

Benzylethanolamine 

Benzyl ether (Dibenzyl etherj 

A-(N-Benzyl-N-ethylamino)-o-toluenesulfonic acid 

N-Benzyl-N-ethyl-m-toluidine 

Benzylldene phthalide 

■i-Benzylidineiminoantipyrine 

N-Benzylmethylamine 

p-{Benzyloxy)phenol 

Benzyl polysulfide 

Benzyltrimethylammonium hydroxide 

Benzyltrimethylammonium methoxide 

*3,3'-Bianthra[l,9]pyrazole-6,6'-(2H,2'H)-dione (Pyrazole- 
anthrone yellow). 
[3,3'-Bi-7H-benz[de] anthracen] -7,7' -dione 

*[4,A'-Bi-7H-benz[de] anthracen] -7,7' -dione 

endo-cis-Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic 
anhydride. 

»[l,l' -Binaphthalene]-8,8'-dicarboxylic acid 

Biphenyl 

3,3 ',4,4' -Biphenyltetramine 

2,2',4,4'-Biphenyltetrol 



ACY, ATL, CMG, DUP, G, ICI, MAY, NAC, SDC, TRC. 

NES, UPF. 

TBK. 

FIN, LAK, NAC, x. 

LEM. 

HK, HN, KLK, (ON, TNP. 



DUP, G, NAG. 
HN, TNP. 



TRC. 
G. 



G. 

DUP. 

AAP, 

KPT. 

NES. 

EK, 

ABB. 

NES. 

HEX, 

NAC. 

CWN, 

LEM. 

BPC, 

ICI. 

EK. 

ACC, 

BPC. 

FMT. 

TNP, 

MEE. 

FW. 

ACY, 

HK, 

DUP. 

EK. 

ICO, 

RSA. 

ABB. 

ABB. 



CCW. 

MI£. 

BPC, TBK. 

NAC. 

DUP, NAC. 

LIL. 

SDW. 

MLS. 

EK. 

HK. 

MLS. 

ML£. 

DUP, G, TRC. 

DUP. 

ACY, DUP, G, ICI, MAY, NAC. 

NAC. 

DUP, G, NAC. 

DOW, mu. 

AAP. 
IDC. 



70 



SYNTHETIC ORGANIC CHEMICALS 1963 



TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



2,2'-Biquinoline 

»1,'4-Bis [l-anthraquinonylamino] anthraquinone 

l,<i-Bis [l-anthraquinonylamino] anthraquinone and 

l,<i-Bis [5-chloro-l-arithraquinonylamino] anthraquinone 

(mixed) . 

l,5-Bis[l-anthraquinonylamino] anthraquinone 

Bis[l-anthraquinonylamino] violanthrene 

a^,a''-Bis[5-tert-butyl-6-hydroxy-m-tolyl]mesitol 

N,N'-Bis[l-ohloro-2-anthraquinonyl]-4.' ,A" ' -azobis-['i-bi- 

phenyloarboxamide] . 
Bis(chloro sulfonyl)phthalocyaninedisulfonic acid, copper 

derivative. 

^,4'-Bis[diethylaiiiino] benzhydrol 

'1,4' -Bis [diethylamino] benzhydrol salt, 2,7-naphthalene- 

disulfonic acid mixture. 

"ij'i' -Bis[diethylaniino]benzophenone (Ethyl ketone base) 

4, "i' -Bis [dimethylamino] benzhydrol (Michler's hydrol) 

ffij^'-Bis [dimethylamino] benzophenone (Michler's ketone) 

Bis [p-dimethylamino] methanesulfonio acid and salt 

l,5(and l,8)-Bis[2,'i-dinitrophenoxy] -4,8(and 4,5)-di- 

ni troanthraquinone . 
a,a-Bis['i-(N-ethyl-<i'-sulfobenzylaim.no)-2-tolyl] -a- 

hydroxy-p-toluenesulfonic acid. 
ci,a-Bis[4-(N-ethyl-4'-EUlfobenzylamino)-2-tolyl] -p- 

toluenesulfonic acid. 
4,4' -Bis [p-hydroxyphenylazo] -2,2' -stilbenedisulfonic acid- 

4,4' -Bis[ p-hydroxyphenyl] valeric acid 

N,N' -Bis(2-hydroxypropyl)-2-methylpiperazine 

Bis (o-nitrophenyl) sulfide 

2-Bromoacetophenone 

o-Bromo aniline 

p-Brorao aniline 

4-Bronioanisole 

*3-Bromo-7H-benz [de] anthracen-7-one ( Bromobenzanthrone ) 

Bromobenzene , mono 

p-Bromobenzenesulfonyl chloride 

4-Bromobenzophenone 

p-Bromo-N,N-bis(2-hydroxyethyl)benzenesulfonaniide 

Bromochlorobenzene 

6-Bromo-5-chlorobenzoxazolone 

2-Bromo-6-chloro-4-nitroaiiiline 

2-Bromodibenzofuran 

6-Bromo-2,4-dinitroaniline 

Bromoethylbenzene 

2-Bromo-3 '-hydroxyacetophenone, benzoate 

l-Bromo-4-(N-methylacetaim" do) anthraquinone 

»l-Bromo-4-methylaminoanthraquinone 

2-Bromo-3-methylanthraquinone 

3'-Bromo-4'-methyl-2-biphenylcarboxylio acid 

6-Bromo-3-methyl-7H-dibenz[f ,ij] isoquinoline-2,7(3H)- 

dione. 

1-Bromonaphthalene 

4-Bromonaphthalio anhydride 

l-(9-Bromo-7-oxo-7H-benz[de]anthracen-3-yla]iiino) anthra- 
quinone . 

p-BromoBhenyl phenyl ether 

Bromopicrin 

2-BroiDopyridine 

, 3-Broioopyridine 



ACY, DUP, G, MAY, NAP, TRC. 
TRC. 



DUP. 

nSC, SDH. 

DSC, SDH. 

DSC, DUP, G, MAC, SDH. 

MAC. 

DUP. 

TRC. 



TRC. 
JNS. 
WYW. 

X. 

EK. 

EK. 

EK. 

EK, OPC. 

DUP, G, ICI, MAY, NAC. 

DOW. 

EK. 

ICO. 

G. 

DOW. 

MEE. 

AAP. 

G. 

TRC. 

DOW. 

SDH. 

G. 

DUP, G, ICI. 

DUP. 

DUP. 

G, ICI. 

EK. 



EK. 
EK. 
RIL. 
RIL. 



CYCLIC INTERMEDIATES 

■J'ABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



:<-Bromotoluene 

p-Bromotoluene 

l-Bromo-2,'4,6-triethylbenzene 

Butoxyphenol 

'i-[3-(p-Butoxyphenoxy)propyl] morpholine 

p-n-Butoxy-a-piperidine propiophenone hydrochloride 

N-Butylacetanilide 

p-n-Butylaminobenzoic acid, ethyl ester 

p -But ylani line 

2-tert-Butylanthraquinone 

p-tert-Butylbenzaldehyde 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

p-tert-Butylbenzoic acid 

o-(p-tert-Butylbenzoyl)benzoic acid 

6-Butyl-m-oresol [OH 1] 

6-tert-Butyl-m-cresol 

2-tert-Butyl-p-cresol 

2' -tert-Butyl-A' ,6' -dimethylacetophenone 

2-tert-Butyl-<i-ethylphenol 

1, l,l-tris-( 5-tert-Butyl-';-hydroxy-2-methylphenyl) butane- - 

N' -Butyl --i-methoxymetanilamide 

2-tert-Butyl-5-methylanisole 

o-sec-Butylphenol 

p-sec-Butylphenol 

o-tert-Butylphenol 

p-tert-Butylphenol 

Butylphenols, mixed 

p-tert-Butyltoluene 

5-tert-Butyl-l,2,3-trimethylbenzene 

5-tert-Butyl-m-xylene 

6-tert-Butyl-2,i-xylenol -- 

Carbazole, refined 

2,4 '-Carbonyldibenzoic acid 

6(and 2)-Carboxybenzene-2(and •4)-diazo-l-oxide 

5'-(o-Carboxybenzoyl)-2-chlorooxanilic acid 

3-Carboxy-2(and 4)-hydroxybenzenediazoniujn sulfate 

3-Carboxymethyl-l-(4-chloro-o-tolyl)-3-ethyltriazene 

3-Carboxyniethyl-l-(5-chloro-o-tolyl)-3-methyltriazene 

3-(Carboxymethyl)-3-methyl-l-p-tolyltriazene 

5-(o-Carboxyphenylsulfamoyl)anthranilic acid 

3- ( 2-Carboxy-'i-sulf ophenyl ) -1- ( 2, 5-dichlorophenyl) - 

3-ethyltriazene. 
3-(2-Carboxy-'i-sulfophenyl)-l-(5-dimethylBUlfamoyl-o- 

tolyl ) -3 -methyltr iazene . 
3- ( 2-Carboxy-4-sulf ophenyl ) -3-ethyl-l - ( 5-nitro-o-anisyl ) - 

triazene. 

Cedrene 

Chelidamlc acid 

Chlorendio acid 

2'-Chloroacetoacetanilide 

2-Chloroacetophenone 

2'-Chloroacetophenone 

4' -Chloroacetophenone 

"♦'-(Chloroacetyljacetanilide 

N-(<i-Chloro-2-aminotoluene)sarcosine 

m-Chloro aniline 

o-Chloro aniline 

p-Chloro aniline 



BPC, EK. 

EK. 

DUP. 

ABB. 

ABB. 

ICO. 

UCC. 

ICO. 

DUP. 

DUP. 

GIV. 

PLC. 

PLC. 

PLC. 

SHC. 

DUP. 

KPT. 

PIT. 

ACY. 

GIV. 

ACY. 

ICI. 

G, KI^. 

GIV. 

DOW, PRD. 

DOW. 

TNA. 

DOW, PRD, UGP. 

DOW. 

GIV, SHC. 

GIV. 

GIV, x. 

PIT. 

SDC. 

ACY. 

DUP. 

G. 

NAC. 



TRC. 
G. 



GIV. 




SDW. 




HK. 




FMP. 




RBC. 




EK. 




LIL, 


NES. 


DUP. 




BUC. 




DUP, 


G. 


DUP, 


KDN, NAC 


DUP, 


MON. 



72 



SYNTHETIC ORGANIC CHEMICALS 1963 



TABLE 7b. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i965— Continued 



Manufacturers ' 
I according 1 



identification codes 
list in table 22; 



2-(Chloroanilino)ethanol 

3-(o-Chloroamlino)propionitrile 

5-Chloro-o-anisidine [NH2-I] (i-Chloro-o-anisidine 
[0CH3=1] ) . 

5-Chloro-o-anlsidine hydrochloride 

N-(5-Chloro-o-anisidine)methyltaiirine 

■i-Chloroanthranilic acid 

»1-Chloroanthraquinone 

*2-Chloroanthraquinone 

*o-Chlorobenzaldehyde 

p-Chlorobenzaldehyde 

Chloro-7H-benz[de] anthracen-7-one (Chlorobenzanthrone)- 

*Chlorobenzene, mono 

l-Chlorobenzene-4^-methylsulfone 

4-ChlorobenzeneEulfinic acid 

p-Chlorobenzenesulfonamide 

p-Chlorobenzenesulfonic acid 

"i-Chlorobenzenesulfonyl chloride 

l-('i-Chlorobenzhydrol)-'i-niethylpiperazine 

o-Chlorobenzoic acid 

p-Chlorobenzoio acid 

p-Chlorobenzonitrile 

5-Chloro-2-benzoxazolinone 

*o-(p-Chlorobenzoyl) benzoic acid 

p-Chlorobenzoyl chloride 

4,4'-(o-Chlorobenzylidene)di-2,5-xylidine 

2-Chloro-5-(o-carboxyphenylsulfamoyl)benzoic acid 

2-Chloro-l,'i-dibutoxy-5-nitrobenzene 

Chloro-(p-chlorophenyl)phenylmethane 

2-Chloro-l,4--diethoxy-5-nitrobenzene 

2-Chloro-N,N-diethyl-l-m.troaiiiline 

N- ( 3-Chloro-9 , lO-dihydroxy-2-aiithryl ) acetamide-bis [acid 
sulfate] . 

■4' -Chloro-2' ,5'-dimethoxyacetoacetanilide 

4-Chloro-2,5-diinethoxy aniline 

5-Chloro-2,4-diiQethoxy aniline 

<4-Chloro-N,N-dimethyl-3-nitrobenzenesulfonamide 

5-Chloro-<i,7-diinethyl-3(2Hj-thianaphthenone 

*l-Chloro-2,4-dinitrobenzene (Dinltrochlorobenzene; 

l-Chloro-2,'4-dinitrobenzene and 2-chloro-l,3-dinitro- 
benzene mixture . 

5-Chloro-2,'4-dinitrobenzenesulfonic acid 

3-Chlorodiphenylamine 

Chlorodiphenylmethane 

a -Chloro-o( and/or p)-dodecyltoluene [CH3=l] 

p-[ (2-Chloroethyl)methylamino]benzaldehyde 

2-Chloro-N-ethyl-5-nitrobenzenesulfonanilide 

Chloroformic acid, phenyl ester 

4-Chloro-3-hydrazinobenzenesulfonic acid 

l-Chloro-'i-hydroxyanthraquinone 

5'-Chloro-3-hydroxy-2-naphthol-o-anisidide 

3-Chloro-<i-hydroxyquinoline-3,4-carbom.c acid 

6-Chloroisatoic anhydride 

5-Chloro-'i-isopropylmetanilic acid — '■ 

A-Chloro-N-isopropyl-3-nitrobenzenesulfonainide 

"i-Chlorometanilic acid 

5-Chlorometanilic acid 

6-Chlorometanilio acid 

5-Chloro-2-inethoxybenzenedlazonium chloride 



EKT. 
DUP. 
KLS. 



BUG, 

DUP. 

ACY, 

ACY. 

HN, 

HN. 

ACY, 

ACS, 

TRC. 

TRC. 

ACY. 

G. 

NES. 



HN, SDH. 



DUP, G, Id, MAY. MAC, TRC. 
G, NAC, TRC. 

NAG, SDH. 

TRC. 

DOW, DUP, DVC, GGY, HK, HKD, M3N, MTO, OMC, PPG. 



ACY, DUP, G, ICI, NAC. 

HN. 

G. 

OPC, TRC. 

G. 

TBK. 

G. 

DUP. 



PCW. 

PCW. 

ALL, G, PCW. 

G. 

NAC. 

AAP, DUP, NAC, SDC. 

DUP. 



OPC, TBK. 

ORO. 

G. 

G. 

EK. 

G. 

ICI. 

PCW. 

SDH. 

MEE. 

SW. 

TRC. 

DUP, G. 

NAC. 

DUP. 

G. 



CYCLIC INTERMEDIATES 



73 



TABLE 7B. --Cyclic intermediates for mhich U.S. production or sales were reported, identified by 
manufacturer, 7965--Contmued 



Manufacturers' identification codes 
(according to list in table 22) 



N-(5-Chloro-2-methoxyphenylazo)sarcosine 

»l-Chloro-2-methylanthraquinone 

6-Chloro-'4-methylbenzo-l,3-thiaza-2-thionium chloride 

6-Chloro-2-methyl-7-chlorosulfamoyl-2H-l,2,'i-benzo- 

thiadiazin-3(<lH) -one, 1,1-dioxide. 
6-Chloro-2-methyl-7-(N-methylsulfamoyl)-2H-l,2,4-benzo- 
thiadiazin-3(iH) -one, 1,1-dioxide. 

a-Chloromethylnaphthalene, crude 

4-Chloro-N-methyl-3-nitrobenzenesulfonaiiiide 

A-Chloro-3-(3-iiiethyl-5-oxo-2-pyrazolin-l-yl)benzene- 
sulfonic acid. 

2-Chloro-5-(N-methylsulfamoyl) sulfanilamide 

5-Chloro-2-(n-methyl)-sulfainyl-4-sulfaiiiyl-n-benzylaniline- 

Chloronaphthalenes 

8-Chloro-l-naphthalenesulfonyl chloride 

9-Chloronaphtho[l,2-b]thiophen-3(2Hjone 

(8-Chloro-l-naphthylmercaptoJ -acetic acid 

*2-Chloro-^-nitroam.line (o-Chloro-p-nitroaniline) 

*4-Chloro-2-m.troamline (p-Chloro-o-nltroaniline) 

•l-Chloro-S-nitroanthraquinone 

l-Chloro-5(and 8)-nitroanthraquinone 

l-Chloro-8-nitroanthraquinone 

*l-Chloro-2-nltrobenzene {Chloro-o-nltrobenzenej 

*l-Chloro-2(arid 4 ) -nitrobenzene (Chloronltrobenzenes, o- 
and p-) . 

»l-Chloro-3-nltrobenzene { Chloro-m-nitrobenzene ) 

l-Chloro-'i-nitrobenzene (Chloro-p-nitrobenzene) 

♦A-Chloro-S-nitrobenzenesulfonamide 

<•- Chloro-3-nitrobenzenesulfonanilide 

2-Chloro-5-nitrobenzenesulfonic acid 

2-Chloro-5-nitrobenzenesulfonlc acid, sodium salt 

»4-Chloro-3-nitrobenzenesulfonic acid 

<V-Chloro-3-nitrobenzenesulfonmorphollde 

*i-Chloro-3-nitrobenzenesulfonyl chloride 

2-Chloro-'i-nitrobenzoio acid 

2-Chloro-5-m.trobenzoic acid 

*o-(4—Chloro-3-nitrobenzoyl) benzoic acid 

4-Chloro-2-nitrophenol 

4-Chloro-6-nitro-l-phenol-2-sulfonic acid 

'i-Chloro-3-nitrophenyl methyl sulfone 

2-Chloro-'i-nitrotoluene 

2-Chloro-6-nitrotoluene 

»4-Chloro-2-nitrotoluene 

"i-Chloro-S-nitrotoluene 

m-Chlorophenol 

o-Chlorophenol 

p-Chlorophenol 

2-Chlorophenothiazine 

p-Chlorophenylaoetonitrile 

4-Chloro-:i-phenyl-o-cresol 

■4-Chloro-o-phenylenediamine 

3-(o-Chlorophenyl)-5-methyl-<i-isoxazole carbonyl ohloride- 

l-(m-Chlorophenyl)-3-methyl-2-pyrazolin-5-one 

l-(p-Chlorophenyl)-3-methyl-2-pyrazolin-5-one 

2-Chloro-'i-phenylphenol 

4-Chlorophthallc acid 

Chlorophthalic anhydride 

l-C3-Chloropropyl)-'i-methylpiperazine 

N -(6-Chloro-3-pyridazinyl) sulfanilamide 



ATL, SDH. 

AAP, ACY, CMG, G, ICI, NAC, IRC. 

DUP. 

ABB. 

ABB. 

BPC. 
TRC. 



ABB. 
ABB. 
KPT. 



ACY, 


DOW, 


DUP, 


sue. 




DOW, 


DUP, 


VPC. 






ACY, 


DUP, 


MAY, 


NAC, 


TRC 


DUP. 










DUP, 


NAC. 








AAP, 


DUP, 


M3N, 


UPM. 




AAP, 


DUP, 


SDC. 







DUP, G, MDN, UPM. 

AAP, DUP, M3N, UPM. 

AAP, DUP, EKT, ICC, TRC. 

TRC. 

CMj, NAC. 

DUP, G, TRC. 

0, NAC, TRC. 

G. 

AAP, DUP, EKT. 

SAL. 

TRC. 

AAP, G, ICI, NAC. 

DUP, MEE. 

TRC. 

TRC. 

DUP. 

DUP. 

AAP, BUC, DUP. 

AAP, BUC. 

EK. 

DOW, MDN. 

DOW, KON. 

SK. 

ICO, TBK. 

MDN. 

FMT. 

ICO. 

TRC. 

TRC. 

DOW. 

DUP, SW, TRC. 

HK. 

SK. 

ACY. 



749-026 O - 64 



74 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i563-- Continued 



Manufacturers' identification codes 
(according to list in tatle 22) 



2-Chloropyridine 

6-Chloroquinaldine 

2-Chloroquinizarin 

7-ChlQro-4-quinolinol 

'4-(7-Chloro-'i-quinolylaniino)-a-diethylainino-o-oresol--- 
^-(7-Chloro-i-quinolylamno)-a-diethylamino-o-cresol 
hydrochloride . 

6-Chloroquinophthalone 

^-Chlororesorcinol 

5-Chlorosalioylic acid 

8-Chlorotheophylline 

2-Chlorothiaxanthenone 

m-Chlorotoluene 

m-Chlorotoluene mixed 

o-Chlorotoluene 

p-Chlorotoluene 

*a-Chlorotoluene (Benzyl chloridej 

l-Chloro-5-p-toluenesulfonamidoanthraquinone 

3-Chloro-o-toluidine [ tlH2=l] 

3-Chloro-p-toluidine [ MH2=1] 

4- Chloro-o-toluidine [NH2=1] and hydrochloride 

«5-Chloro-o-toluidine [ NH2=1] 

»5-Chloro-o-toluidine hydrochloride [NH2=1] 

N-(5-Chloro-o-tolylazo)sarcosine 

l-(6-Chloro-o-tolyl)-3-methyl-2-pyrazolin-5-one 

l-(5-Chloro-o-tolyl)-l-tetrazene 

(A-Chloro-o-tolylthio) acetic acid 

3-Chloro-*,",'*-trifluoro-6-nitrotoluene 

•4-Chloro-a ,ci ,a -trif luoro-3-nitrotoluene 

p-Chloro-oi,a,a-trifluorotoluene 

A-Chloro^ ,a ,a -trif luoro-m-toluidine 

6-Chloro-a,a,a-trifluoro-m-toluidine 

l-(6-Chloro-a,a,a-trifluorotolyl)-3-methyl-3-(2-sulfo- 
ethyl)triazene. 

2-Chloro-l,3,5-trinitrobenzene 

Chlorotriphenylmethane 

a-Chloro-p-xylene 

2-Chloro-p-xylene 

i-Chloro-2,5-xylenesulfonyl chloride 

<V-Chloro-3,5-xylenol 

'4-Chloro-2,5-xylylthioacetic acid 

Chrysazin (1,8-Dihydroxyanthraquinone) 

Cinnamoyl chloride 

s-Collidine (2,'i,6-Trimethylpyridine) 

»Cresols : ^ 

m-Cresol 

»o-Cresols: 

From coal tar 

From petroleum 

«p-Cresol 

Cresols, mixed :■'• 
»(m,p)-Cresol: 

*From coal tar 

*From petroleum 

*(o,m,p)-Cresol: 

From coal tar 

From petroleum 

2,3-Cresotio acid 

»Cresylio acid, refined:""" 

•»From coal tar 

»From petroleum 

See footnote at end of table. 



FMT, NEP. 

DUP. 

HSH, NAC, TRC. 

SDW. 

PD. 

PD. 



DUP. 
AAP, 


G. 




PCW. 
MAL, 


TRC. 




KF. 






HK. 






BPC. 






HN. 






HN. 






BPC, 


HK, 


HN, MDN, TNP. 


ICI. 






DUP, 


NAC. 




DUP. 






AAP, 


ACY, 


PCW. 


BUG, 


DUP, 


NAC, SDH. 


ALL, 


ATL, 


AUG, BUC, DUP, KLS, SDH 


ATL, 


BUG. 




TRC. 






G. 






ACY, 


NAC. 




MEE. 






AAP, 


G, MEE. 


HK. 






AAP. 






MEE. 






G. 






EK. 






EK. 






BPC. 






DUP. 






G, NAC. 




OTA. 






G, NAC. 




DUP, 


G. 




EK, 


TBK. 




KPT, 


NAC, 


RIL. 


KPT. 






KPT 


PRD 


RIL. 


MER, 


PRD, 


SW. 


ACY, 


HPC, 


SW. 



ACP, KPT, PRD. 
MER, PIT, PRD. 

ACP, KPT. 
FIT, PRD. 
DOW. 

ACP, ACY, KPT, PRD, RIL. 
MER, PIT, PRD, SHO, SM, SOC. 



CYCLIC INTERMEDIATES 



75 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, ;965--Continued 



Manufacturers' identification codes 
(according to list in table 22; 



oCumene 

2- rp-(2-Cyaiioacetimido) phenyl] -6-methyl-7-benzothiazole- 
sulfonic acid. 

i-[(2-Cyanoethyl)ethylaniino] -o-tolualdehyde 

p-[(2-Cyanoethyl)ethylamino] -o-tolualdehyde 

p-[(2-Cyanoethyl)raethylamino]benzaldehyde 

8-Cyano-l-naphthalenesulfonio acid 

Cyanuric chloride 

»Cyclohexane 

1,4-Cyclohexanedicarboxylic acid, dimethyl ester 

1,2-Cyclohexanedicarbcxylic anhydride 

»Cyclohexanol 

tCyclohexanone 

Cyclohexanone oxime 

Cyclohexene 

4-Cyclohexene-l,2-dicarboxiinide 

4-Cyclohexene-l,2-dicarboxylic anhydride 

3-Cyclohexene-l,l-dlmethaiiol 

Cyclohexyl acetone 

Cyclohexylamine 

N-Cyclohexyltaurine, sodium salt 

1,5-Cyclooctadiene 

Cyclopentanepropionic acid 

Cyolopentene 

(2-Cyclopenten-l-yl, acetone 

Cycloso(propylbutylbenzene) 

p-Cymene 

Decylbenzene 

n-Decylgallaphenone 

Decylphenol 

1,5 (and l,8)-Diacetamldoanthraquinone 

'i,4'-Diacetylamino-3,3' -dinitrobiphenyl 

NjN-Diacetyl-ij-i' -dlaminobiphenyl 

N,N-Diallylcamphoramlc acid 

Diallyl Isophthalate 

N^,N^-Diallylmelamine 

Diallyl phthalate 

*l,'4-Dianiinoanthraquinone 

1,5-Diaminoanthraquinone 

l,5(and l,8)-Diaininoanthraquinone 

»2,6-Di amino anthraquinone 

l,'V-Diamino-2,3-anthraquinonedicar'bonitrile 

l,'4-Diamino-2,3-anthraquinonedicarboximide 

AjS-Diamlnoanthrarufin 

2,4-Diaminobenzenesulfonic acid [S03H=l] 

2,5-Diaminobenzenesulfonio acid [S03H=l] 

4,4' -Diamino-l,l'-bianthraquinone-3,3'-disulfonic acid, 
disodlum salt. 

■»4,4'-Diamino-2,2'-biphenyldisulfonic acid 

3,7-Diaminodibenzothiophenedisulfonio acid, 5,5-dioxlde, 
disodium salt. 

Diamlnodlbromodi-p-toluidino anthraquinone 

l,4-Diamino-2,3-dichloroanthraquinone 

1,5-Di ami no-4,8-dihydroxy anthraquinone 

l,5(and l,8)-Diamino-4,8(and 4,5)-dihydroxyanthraquinone — 

4, 5-Diamino-l,8-dihydroxy anthraquinone 

4,8-Diamlno-l,5-dlhydroxy-2,6-anthraquinonedisulfonic acid 

3,6-Diamino-2,7-dimethylacridine 

3,6-Diamino-2,7-dimethylacridine sulfate 

4,4'-Diamlno-3,3' -dimethyltriphenylmethane 



ACC, ACP, DOW, GOC, HPC, PLC, SHC, SOC, x. 
DUP. 

G. 

DUP. 

DUP, G. 

DUP, G. 

ACY, GGY, NIL. 

CO, DUP, GOC, PLP, PRO, SOG. 

NAC. 

CS, DOW, DUP, MDN, NAC. 

CS, DBG, DUP, NAC. 

NAC, X. 

KF, PLC. 

CHO. 

NAC. 

TRC. 

GIV. 

ABB, X. 

G. 

PLC. 

ARA. 

PLC. 

LIL. 

SHC. 

HNW, 

NAC. 

AHA. 



AAP. 
AAP. 
AAP. 
WYT. 
FMP. 
ACY. 
FMP. 
DUP, 
ACY. 
AAP, 
AAP, 
DUP. 
DUP. 
AAP. 
DUP, 
TRC. 
TRC. 



HPC, NAC. 



G, NAC, TRC. 

DUP, G, TRC. 

ACY, Id, TRC. 

ACY, DUP, G, NAC, TRC, VPC. 



G, NAC, TRC. 



AAP, ACY, NAC. 
ACY. 

ICI. 
DUP. 
VPC. 
DUP. 
ICI. 
TRC. 
DUP. 
DUP. 
ACY. 



76 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 7B. 



■ Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



2,4-Diaminodiphenylainine 

1,/4-Di amino- 5-nitroanthraqui none 

^,6-Diamino-5-nitroso-2-phenylpyTimidine 

2,'4-Diamino-6-phenyl-s-triazene 

2,6-Diaminopyridine 

»A,4'-Diamino-2,2' -stilbenedisulfonic acid 

Diamine tetrabromoanthraqulnone 

<i,6-Diaiiiino-ra-tolueneEulfonic acid [S03H=l] 

Di-tert-amylphenoxyacetyl chloride 

l,5-Dianilino-2,6-anthraquinonedioarboxylio acid 

2,-4-01 anilino-1-hydroxyanthraquinone 

N-(o-Dianisidine)methyltaurine 

Diarylguanidine 

p-Diazo-N,N-dimethylanlline-l-ainino-8-naphthol-3- 
sulfonate-6-sulfonic acid, sodium salt. 

1,5-Dibenzamidoanthraquinone 

<i,9-Dibenzamido-3','»',6' ,7'-diphthaloylcarbazole 

«<4.,5'-Dibenzamido-l,l'-iiiiinodianthraquinone 

5,5 '-Dibenzamido-1,1' -iminodianthraqulnone 

Dibenzothiophene 

»l,5-Dibenzoylnaphthalene 

1' ,2' ,6' ,7' -Dibenzpyrene-7,14-quinone 

N,N'-Dibenzylethylenediamine 

N,N'-Dibenzylethylenediamine diaoetate 

2,4'-Dibromoacetophenone 

»3,9-Dibromo-7H-benz[de] anthracen-7-one 

m-Dibromobenzene 

o-Dibromobenzene 

p-Dibromobenzene 

Dibromoethylbenzene 

2,6-Dibromo-l,5-naphthalenediol 

Dlbromoviolanthrone 

2,4— Di-tert-butylphenol 

2,5-Diohanil 

2,'4-Dicliloroaniline 

3,4--Dichloroaniline 

»2,5-Dichloroaniline and hydrochloride [NH2=1] 

«1,5-Diohloroanthraquinone 

1,5 (and l,8;-Dichloroanthraquinone 

»l,8-Dichloroanthraquinone 

2,3-Dichloroanthraquinone 

4, 5-DiGhloro-l,8-anthraquinonedisulf onic acid 

3-(3,'4-Dichlorobenzaiiiido)-l-phenyl-2-pyrazolin-5-one 

m-Dichlorobenzene 

»o-DicM.orobenzene 

»o(and p)-Dichlorobenzene 

*p-Dichlorobenzene 

<4,6-Dichloro-m-benzenedisulfonamide 

4,6-Dichloro-m-benzenedisulfonyl chloride 

»3,3'-Dichlorobenzidine base and salts 

2,'4-Diohloroben2oic acid 

2,'4-Diohlorobenzoyl chloride 

2 , 5-Diohloro-3 , 6-bis ( 9-ethylcarbazol-3-ylamino ) -p-benzo- 
quinohe . 

2,3-Dlchloro-5,6-dicyanobenzoquinone 

8,18-Dlchloro-5,15-diethyl-5,15-dihydrodiindolo- 
(3,2-b:3' ,2'-m)triphenodioxazine. 

2,6-Diohloro-3,6-dihydroxy-p-benzoquinone 

4,5-Diohloro-3,6-dioxooyclohexene-l,2-dioarbonitrile 



RBC. 

G. 

ARA. 

RH, TNP. 

NEP, RIL. 

ACY, DUP, G, MAC, SDH, TRC, VPC. 

ICl. 

MAC. 

EK. 

G, NAG. 

G, TRC. 

BUG. 

DUP. 

IDC. 

G, TRC. 

ICI. 

ACY, DUP, G, ICI, MAY, MAC, TRC. 

ACY. 

EVN. 

ACY, DUP, G, HST, ICI, TRC, VPC. 

ATL, ICI. 

VfYT. 

WYT. 

EK. 

DUP, G, MAY, MAC, TRC. 

EK. 

EK. 

DOW. 

DOW. 

EK. 

G. 

DOW. 

G. 

EK. 

DUP, MON. 

DUP, KI^, NAC, SDH. 

DUP, G, ICI, NAC, TRC. 

DUP, NAC. 

G, ICI, NAC, TRC. 

TRC. 

G. 

EK. 

EK, G, X. 

ACS, CPD, DOW, DUP, DVC, M3N, OMC, PPG, SCC, SVT, WOI. 

GGY, HKD, MTO. 

ACS, CPD, DOW, DUP, DVC, HK, MON, PPG, SCC, SVT, WOI. 

ABB. 

ABB. 

ALL, CWN, IMP, LAK, NAC. 

HN. 

HN. 

TRC. 



LIL. 
AAP. 



EK. 
ARA. 



CYCLIC INTERMEDIATES 



77 



TABLE I'Q. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



Dichlorodiphenylsilane 

2' ,7' -Diohiorofluorescein 

2,5-Dichloro-<i-hydrazino'benzenesulfonic acid 

7,16-Dichloroindanthrene 

*2,5-Dichloro-4-(3-methyl-5-oxo-2-pyrazolin-l-yl)'benzene- 
sulfonic acid. 

*2,6-Dichloro-4-nitroaniline 

l,2-Diohloro-<i-nitrobenzene 

»l,'i-DichIoro-2-nitrobenzene (Nitro-p-dichlorobenzenej 

2,'i-Dichlorophenol 

3,6-Dichloropyridazine 

<;,7-Dichloroquinoline 

3,5-Dichlorosalicylic acid 

»2,5-Dichlorosulfanilic acid [s03H=l] 

2,5-Dichloro-4.-sulfobenzenediazonium siilfate 

^.,a-Dichlorotoluene (Benzal chloride) 

p,a-Dichlorotoluene 

»2,6-Dichlorotoluene 

2,'4-Dichloro-5-(p-toluenesulfonanildo)-l-naphthol 

2,'4-Dichloro-3,5-xylenol 

Dicyclohexylamine 

Dicyclohexylcarbodiinu.de 

Dicyolopentadiene and cyolopentadiene 

2, '4-Di(l,l-dimethylpropyl) phenol (Di-tert-amylphenol) 

2, 5-Diethoxy aniline 

2 ', 5 '-Diethoxybenzanilide 

p-Dlethoxybenzene 

2,5'-Diethoxy-4-'-nitrobenzanilide 

l,'i-Diethoxy-2-nitrobenzene 

*p-Diethylaminobenzaldehyde 

a-(2-Diethylaininoethyl)-a-phenylcyclohexanemethanol, 
hydrochloride. 

m-Diethylaminophenol (N,N-Diethyl-3-anu.nophenol) 

3-Diethylaininopropiophenone 

*N,N-Diethylaniline 

N,N-Diethyl-m-anisidine 

Diethylbenzene 

N,N-Diethylcyclohexylamine 

N,N-Diethylmetanilic acid 

N jN""" -Diethyl-4— methoxymetanllamide 

N,N-Diethyl-p-nitrosoaniline 

N,N-Diethyl-'4-nitroso-m-anisidine hydrochloride 

N,N-Diethyl-m-phenetidlne 

Diethyl terephthaloyldi acetate 

N,N-Diethyl-m-toluidlne 

b,\5-X)i.hydTo-5 ,9 ,1A ,l&-ai\Xhra.zi.n.eteXTone 

10,ll-Dihydro-5H-dibenzo[a,d]oyclohepten-5-one 

3,4-Dihydro-3,4-dioxo-l-naphthalenesulfonic acid, sodium 

salt. 
10,ll-Dihydro-5-[3-(methylaiiiino)propyl] -5H-dibenzo[a,d]- 
oyclohepten-5-ol. 

2,3-Dihydro-'4H-pyran 

1,5 (and 1 , 8 ) -Dihydroxyanthraquinone 

3,4-Dihydroxybenzoio acid (Protocatechulc acid) 

Dihydroxydinitroanthraquinone 

»1,5-Di hydroxy-'*, 8-dinitroanthraqul none 

l,5(and l,8)-Dihydroxy-'i,8(and 4,5)-dinitroanthraquinone— 
l,5-Dihydroxy-<i,S-dinitro-2,6-anthraquinonedisulfonic acid 
•4,5-Dihydroxy-2,7-naphthalenedisulfonic acid ( Chromotropic 

acid). 
6,7-Dihydroxy-2-naphthalenesulfonio acid 



Dec. 

EK. 

G. 

ICI. 

ACY, CMC, DUP, G, KLS, TRG, VPC. 



AAP, 

DUP, 

AAP, 

DOW, 

ACY. 

SDW. 

ICO. 

CMG, 

TRC. 

NAC. 

HN. 

DUP, 

EK. 

OTA. 

ABB, 

G. 

EN J, 

PAS. 

ALL. 

G. 

EXT, 



DUP, 
ACY. 



DUP, EKT, G, mi., PCW, TRC. 

MDN. 

DUP, NAC, VPC. 

^DN. 



DUP, G, VPC. 



G, NAC. 

MDN. 
UCC. 



G, NAC. 



ACY, DUP, ^DN. 

ACY. 

ACY, DSC, DUP, NAC, SDH. 

DUP. 

DOW, KPP. 

DUP. 

DUP. 

G, PCW. 

G. 

DUP. 

G. 

G. 

DUP. 

TRC. 

LIL. 

EK. 

LIL. 

QKO. 

DUP, NAC. 

AMB. 

DUP. 

AAP, G, ICI, VPC. 

TRC. 

TRC. 

NAC. 

FMI, G, IDC, NAC. 



78 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



3,5-Dihydroxy-2-naphthoic acid 

*16,17-Dihydroxyviolanthrone ( Dihydroxydibenzanthrone j 

m-Diiodobenzene 

I!,N'-Diisopropyl-p-phenylenediainine 

Z'jA-'-Dimethoxyacetophenone 

2,5-Dimethoxyacetophenone 

»2,5-Dimethoxy aniline 

1,5 (and l,8)-Dimethoxyanthraquinone 

2,5-Dimethoxybenzaldehyde 

3,'i-Dimethoxybenzaldehyde 

m-Dimethoxybenzene 

p-Dimethoxybenzene 

»3,3' -Dimethoxybenzidine 

3,3' -Dimethoxybenzidine hydrochloride 

2,'4-Dimethoxybenzoic acid 

2,6-Dimethoxybenzoyl chloride 

l,l-(3,3 '-Dimethoxy-'ij'i '-biphenylene)bis [3-methyl-3-(2- 
sulfoethyl)triazene] . 

l,4-Diniethoxy-2-nitro benzene 

3,4-Dimethoxyphenethylaiiiine (Homoveratrylamine) 

4-(2 ',5'-Dimethoxyphenethyl)aniline hydrochloride 

( 3, 4-Dimethoxyphenyl) acetic acid 

(3,<i-Dimethoxyphenyl)acetonitrile 

16,17-Dimethoxy-/iolanthrone 

m-Dimethylaminobenzoic acid 

a-Dimethylamino-o-cresol 

6-Dimethylamino-2- ( 2- ( 2 , 5-dimethyl-l-phenyl-3-pyrryl ) - 
vinyl )-l-methyl-l-quinoliniuin methyl sulfate. 

o-(2-Diniethylaminoethyl)phenol 

2- [(2-Dimethylaminoethyl)thenylamino] pyridine (non- 
medicinal grade). 

o-(Dimethylaminomethyl)-p-butylphenol 

6-(Dimethylaminomethyl)-2-methoxy-<i-nltrophenol 

m-Dimethylaminophenol 

N-(p-Diinethylaminophenyl)-l,'i-naphthoquinoneimine 

5-Dimethylaminoquinaldine 

«N,N-Dimethylaniline 

7,12-Dimethylbenz [a] anthracene 

»N,N-Dimethylbenzylamlne 

a, a' -Dimethylbenzyl hydroperoxide 

»2,2'-Dimethyl-l,l'-biaiithraqulnone 

2,4-Di(l-methylbutyl)phenol 

cis-l,2-Dimethylcyolohexane 

trans -1,2-Dijnethylcyclohexane 

N,N-Dljnethylcyclohexylamine 

N,N-Dimethyl-2,2-diphenylacetamlde 

2',7'-Dimethylfluoran 

Dimethylhydantoin ' 

2,8-Dimethyl-13P-hydroxy-9(13|3 )-ceroxenone 

2,3-Dimethylindole 

2 , 5-Dimethyl-A ( 2 ) -morpholinylmethylphenol , hydrochloride- 

»N,N-Dimethyl-p-nitrosoaniline 

N,N-Dimethyl-3-nitro-p-toluenesulfonamde 

N,N-Dimethyl-p-phenylazo aniline 

N,N-Dimethyl-p-phenylenediamlne 

N,N-Dimethyl-p-phenylenediamine hydrochloride 

2,5-Dimethylphenylpyrrole 

2,5-Diinethyl-l-phenyl-3-pyrrolecarboxaldehyde 

1,4-Dlmethylpiperazine 



ACY, DUP, G, ICI, MAY, MAC. 

EK. 

DUP. 

DUP. 

BPC. 

DUP, EKT, G, US. 

TRC. 

OWN. 

OPC. 

ACY, DUP, ICO. 

G, ICO. 

ALL, CWN, DUP, SDH. 

OWN. 

ACY, DUP. 

ICO. 

G. 

EKT. 
LIL. 
UP J. 
LIL. 
LIL. 

ICI, MAY. 
SDH. 
TKL. 



RH. 

MEE. 

ACY. 

NAC. 

EK. 

ACY, 

EK. 

ICO, 

ACP. 

AAP, 

PAS. 

PLC. 

PLC. 

DUP, 

UPJ. 

WLM. 

GLY. 

WM. 

DUP. 

IDC. 

ACY, 



DSC, DUP, NAC, SDH. 

MLS, X. 

ACY, CMG, DUP, G, ICI, NAC, TRC. 



DUP, G, NAC. 



EK. 

EKT, 

EK. 



CYCLIC INTERMEDIATES 



79 



TABLE 7B. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



p-(l,l-Dimethylpropyl)phenol 

N,N-Dimethylsulfanilic acid 

2, '♦-Dlnitro aniline 

p-(2,'4-Dlnitroanilino)phenol 

1,5 (and l,8)-Dinitroanthraquinone 

2,'4-Dinitro-N,N'-(l,5-anthraquinonylene)dioxamlo acid 

m-Dinitrobenzene 

2,'4-Dinitrobenzenesulfonic acid 

3,5-Dinitrobenzoic acid 

3,5-Dinltrobenzoyl chloride 

Dinitro(3,3'-bi-7H-benz[de] anthraoen)-7,7'-dione 

»'i,5-Dinitrochrysazin 

2,'4-Dinitrooumene 

»2,'i-Dinitrophenol, tech 

2,'i-Dinitrophenylhydrazine 

p-Dinitrosobenzene 

»4,<i'-Dinitro-2,2' -stilbenedisulfonic acid 

2,i-Dinltrotoluene 

2,4.(and 2,6)-Dlnitrotoluene 

3,5-Dinitro-p-toluenesulfonic acid 

•1,5-Diphenoxyanthraquinone 

l,5(and l,8)-Diphenoxyanthraquinone 

1,8-Diphenoxyanthraquinone 

Diphenylacetic acid 

Diphenylacetonitrile, tech 

2-Diphenylacetyl-l,3-indandione 

Diphenylamine 

6,8-Diphenylamlno-l-naphthalenesulfonic acid 

2,8-Diphenylanthra[l,2-d: 5,6-d']bisthiazole-6,12-dione 

a-d-l,2-Dlphenyl-4-dimethylamino-2-hydroxy-3-methylbutane, 
camphor sulfonate. 

1,1-Dlphenylethylene 

N,N'-Diphenylethylenediamine 

l,3-Diphenyl-l,3-propanedione 

l,3-Diphenyl-2-propanone 

1,3-Diphenyltrlazene 

2, 4-Disulfonyl-5-chloro-(N-benzyl) -aniline 

Dithiodibenzoic acid 

»l,'i-Di(p-toluidino)anthraquinone 

l,5-Di(p-toluidlno)anthraquinone 

l,8-Di(p-toluidino)anthraquinone 

l,4-Di(p-toluidino)-5,8-dihydroxyanthraquinone 

Dlvinylbenzene 

l,3-Di-2,6-xylylguamdine 

Dodecylaniline 

»Dodecylbenzene (including tridecylbenzene) 

Dodecylmethylbenzene 

Dodecylmethylbenzyl chloride 

Dodecylnitrobenzene 

»Dodecylphenol 

o-Ethoxybenzoio acid 

(o-Ethoxybenzoyl)aoetonitrile 

6-Ethoxy-2-mercaptobenzothiazole 

2-Ethoxynaphthalene 

p-Ethoxynaphthoic acid 

2-Ethoxy-l-naphthoyl chloride 

N^-(6-Ethoxy-3-pyrldazinyl) sulfanilamide 

3-Ethylaiiiino-p-cresol 



Manxif aoturers ' identification codes 
(according to list in table 22) 



KPT, MAC, PAS, UCP. 



AAP, ACY. 




G, MAC. 




AAP, ACY, 


ICI, TRC. 


TRC. 




DUP, NAC. 




G, TRC. 




DUP, GAM, 


SAL, SDH. 


EK. 




DUP, MAY. 




DUP, EKT, 


G, ICI. 


DUP. 




AAP, DUP, 


NAC, SDC. 


EK. 




FIN. 




ACY, DUP, 


G, SDH, TRC. 


DUP, NAG. 




DUP, M3B. 




G, NAC. 




G, ICI, VPC. 


AAP, DUP. 




EKT, G, ICI. 


BPC, KF, 


LIL. 


KF. 




NES. 




ACY, DOW, 


DUP. 


NAC. 




ICI. 




LIL. 




EK. 




DOW, RFC 




EK. 




TBK. 




NAC. 




ABB. 




KF, MEE. 




ATL, CMC 


G, NAC, TRC. 


ICI. 




ICI. 




ICI. 




DOW, FG, 


KPP. 


ACY. 




MON. 




ATR, CO, 


M3N, NAC, sec 


X. 




X. 




MDN. 




G, MDN, X. 


ACY. 




ACY. 




ARA, DUP 




NAC. 




OPC. 




ICO. 




ACY. 




DUP. 





SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 7B. 



--Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



3-Ethylaiiiino-p-toluenesulfonic acid [ S03H=l] 

»N-Ethylaniline, refined 

»2-(N-Ethylanllino)ethanol 

[2- (N-Ethylani lino) ethyl] trimethylammonium chloride 

(N-Ethylanilino)propionitrile 

a- (N-Ethylani lino )-m-toluenesulfonic acid 

*a-(N-Ethylanllino)-p-toluenesulfonic acid 

N-Ethyl-p-anisidine 

N-Ethylanthranilic acid 

2-Ethylanthraquinone 

»Ethylbenzene 

o-(p-Ethylbenzoyl) benzoic acid 

Ethylbenzyl chloride 

Ethyl bis ( 2, 4.-dinitrophenyl) acetate 

N-Ethyl-N-(2-chloroethyl) aniline 

l-Ethyl-7-methyl-l,8-naphthyridin-'i-one-3-carboxylic acid- 

NrEthyl-l-naphthylamine 

9-Ethyl-3-nltrocarbazole 

p-Ethylphenol 

»N-Ethyl-N-phenylbenzylamine 

»2-Ethyl-2-phenylmalonic acid, diethyl ester 

5-Ethyl-2-picoline (2-Methyl-5-ethylpyrldlne) (MEP) 

2-Ethylpyrldlne 

N-Ethyl-5-sulfoanthranilic acid 

6-Ethyl-l,l,4,'i-tetramethyl-l,2,3,'i-tetrahydronaphthalene- 

N-Ethyl-m-toluidlne 

N-Ethyl-o-toluidine 

3-(N-Ethyl-m-toluidino)-l,2-propanediol 

-*3-(N-Ethyl-m-toluidino)propionitrile 

1-Ethynylcyclohexanol 

Fluoren-9-one 

o-Fluoroaniline 

l-Fluoro-2,'t-d}. nitrobenzene 

o-Fluorotoluene 

4-Formyl-m-benzenedisulfonic acid 

»o-Forniylbenzenesulfonlc acid (o-Sulfobenzaldehyde) 

m-Formylbenzenesulfonic acid, sodium salt 

N- (p-Formylphenyl ) -N-methyltaurine 

Fur an 

Furfuryl alcohol 

Hexaohlorobenzene 

Hexachlorocyclopentadlene 

Hexachlorophenyl ether 

N-Hexadecylmorpholine 

2, 2', 4, 4' ,6,6' -Hexanitrodiphenylamine 

Hippuric acid 

*p-Hydrazinobenzenesulfonic acid 

Hydroabietyl alcohol 

Hydroquinone , tech 

2 ' -Hydroxyacetophenone 

3 ' -Hydroxy acetophenone ■ 

3 '-Hydroxyacetophenone benzoate 

6 '-Hydroxy -m-acetotoluldide 

p-Hydroxybenzaldehyde 

2-Hydroxy-llH-benzo [a] carbazole-3-carboxyllc add 

p-Hydroxybenzoic acid 

p-Hydroxybenzoic acid, butyl ester 

p-Hydroxybenzoic acid, ethyl ester 

*p-Hydroxybenzolc acid, methyl ester 

p-Hydroxybenzoic acid, methyl ester, sodlijm derivative 

»p-Hydroxybenzoio acid, propyl ester 



DUP. 






ACY, 


DUP 


NAC, SDH. 


DUP, 


EKT 


G, TRC. 


DUP. 






EKT. 






DUP, 


G. 




ICC, 


NAC 


SDH, TRC, WJ. 


EKT. 






SDH. 






G, NAC. 




ACP, 


DOW 


ENJ, FG, KPP, KPT, MON, SHC, SIN, SKC, SNT 


TOC, UCC. 


G, NAC. 




BPC. 






EK. 






DUP. 






SDH. 






DSC, 


DUP 


NAC. 


DUP 


TRC 




ACY. 






DUP 


NAC 


SDH. 


BPC 


MAL 


VPC. 


UCC. 






RIL. 






SDH. 






GIV. 






DUP 


NAC 




DUP. 






EKT. 






DUP 


EKT, 


G. 


AIR 


NAC 




EK. 






NEP. 






EK. 






EK. 






G, SDH. 




G, ICC, NAC, SDH, VPC. 


G. 






DUP. 






DUP. 






QKO. 






KPT 


sec 




HK, 


VEL. 




DOW. 






APD. 






EK. 






BPC. 






G, STG, WJ. 


HPC. 






CRS, 


EKT. 




KF, 


PRR. 




SDH. 






SDH. 






TRC. 






DOW. 






G. 






HN. 






HN, 


ICO. 




HN, 


ICO. 




HN, 


ICO, 


LEM, WSN. 


WSN. 






HN, 


ICO, 


LEM, WSN. 



CYCLIC INTERMEDIATES 



TABLE 7B. ■ 



• Cyclic intermediates for which U.S. production or sales Mere reported, identified by 
manufacturer, i56J --Continued 



p-Hydroxybenzolc acid, propyl ester, sodium derivative 

^-Hydroxycoumarin 

l-Hydroxy-2,<4-dianisidinoaiithra(iiiinone 

3-(N-2-Hydroxyethylanilino)propionitrile 

3-(N-2-Hydroxyethylanilino)propionitrile acetate 

N-p-Hydroxyethyl-2,'i-dihydroxybenzamide 

N-|3-Hydroxyethyl-3-hydroxynaphthainide 

N-g-Hydroxyethyl-o-toluidine 

6'-Hydroxy-5 '-(2-hydroxy-5-nitrophenylazo)-m-acetotoluidide 

Hydroxyisophthalic acid 

2-Hydroxy-:i-'-,a^-mesitylenediol 

2-Hydroxy-3-methyloi'nohoninic acid 

3-Hydroxy-2-methylcinchoninic acid 

N-Hydroxymethylphthal amide 

7-Hydroxy-l-naphthalenecarbaiiiic acid, methyl ester 

3-Hydroxy-2-naphthanilide (Naphthol AS) 

l-Hydroxy-2-naphthoic acid 

2-Hydroxy-l-naphthoic acid 

3-Hydroxy-2-naphthoic acid (B.O.N. J 

3-Hydroxy-2-naphthoic acid, methyl ester 

l-Hydroxy-2-naphthoic acid, phenyl ester 

3-Hydroxy-2-naphtho-o-toluidide 

3-Hydroxy-3-naphtho-o-toluidide 

N-(7-Hydroxy-l-naphthyljaoetamide 

2-(m-Hydroxyphenoxy)ethanol 

l-[4.'-{p-Hydroxyphenylazo)-l,l-biphenyl-<i-azo]-2-naphthol- 

6,8-disulfonic acid. 
l-[";'-(p-Hydroxyphenylazo)-3,3'-dimethyl-l,l-biphenyl-";- 

azo] -2-naphthol-6,8-disulfonic acid. 
2-Hydroxy-4-sulfo-l-naphthalenediazonium hydroxide, inner 
salt. 

l-Hydroxy-<i-(p-toluidino lanthraquinone 

2-Imidazolidinone 

2-Imidazolidinone modifications 

«1,1' -Iminobis [<i-aminoanthraquinone] 

1,1' -Iminobis [4-benzamidoanthraquinone] 

*1,1' -Iminobis [5-benzainidoanthraquinone] 

»6,6'-Iminobis [l-naphthol-3-sulfonic acid] 

*1,1 '-Iminobis [4--nitroaiithraquinone] 

*l,l'-Iminodianthraquinone (Dianthrimide) 

2,2 '-Iminodipyridine 

1,3-Indandione 

1-Iodonaphthalene 

Isatin 

Isatoic anhydride 

Isobutylbenzene 

*Isocyanic acid derivatives; 

Bitolylene diisocyanate (TODI) 

Dianisidine diisocyanate (DADI) 

3,'i-Dichlorophenylisocyanate 

»Diphenylmethane 4,4' -diisocyanate (MDI) 

4,4' -Methylenebis [o-tolylisocyanate] 

Polylsocyanates (complex) 

Polymethylene polyphenylisocyanate 

Toluene 2,4-dlisocyanate 

Toluene 2,4- and 2,6-diisooyanate (65/35 mixture) 

»Toluene 2,4- and 2,6-diisocyanate (80/20 mixture) 

Other isocyanic acid derivatives 

Isonicotinic acid 

Isonitrosopropiophenone 



Manufacturers ' identification codes 
(according to list in table 22) 



WSN. 

ABB. 

G. 

ICC. 

EKT. 

IDC. 

IDC. 

EKT. 

TRC. 

SDH. 

ACY. 

G. 

DUP, 

ACY. 

TRC. 

ATL, 

NAG. 

BL. 

AUG, 

PCW. 

EK. 

ATL. 

PCW. 

CMG, 

G. 

TRC. 

TRC. 



DUP, HN, MAC, PCW. 



ICI. 






SEY. 






RH. 






ACY, CMG, 


DUP, G, ICI, MAY, 


NAC, TRC 


ACY, MAY. 






G, ICI, TRC. 




DUP, G, MAC. 




ACY, DUP, 


ICI, MAY, TRC. 




ACY, DUP, 


G, ICI, MAY, NAC, 


TRC. 


RIL. 






PIC. 






EK. 






MAC. 






MEE. 






PLC. 






CWN, MAC. 






CWN. 






DUP. 






CWN, DUP, 


MOB, NAC. 




CWN. 






MOB. 






CWN. 






DUP. 






DUP, NAC. 






DUP, MOB, 


NAC. 




CWN, MOB. 






ICO, NEP. 







82 



SYNTHETIC ORGANIC CHEMICALS, 1963 



-Cyclic intermediates for which U.S. production or sales mere reported, identified by 
manufacturer , iS63- -Continued 



Isooctylphenone 

Isophorone 

Isophthalic acid (1,3-Benzenedicarboxylio acid) 

Isophthalic acid, diphenyl ester 

Isophthalonitrile 

5,5'-Isopropylidenebis(2-hydroxy-m-xylene-a, a'-diol) 

»4,'4'-Isopropylldenediphenol (Bisphenol A) 

4,^'-Isopropylidenediphenol, ethoxylated 

4,4'-Isopropylidenediphenol, propoxylated 

o-Isopropylphenol 

4-Isopropyl-m-phenylenedianiine 

Isothiocyanic acid, phenyl ester 

»Isoviolanthrone ( Isodibenzanthrone ) 

»Leuco-l,4-diamlnoanthraquinone 

Leuco quinizarin (1,4.,9,10-Anthratetrol) 

*Leuco tetrahydroxyanthraquinone 

2,'i-Lutidine 

Mandelonitrile 

Melamine 

dl-p-Mentha-l,8-diene (Limonene) 

p-Mentha-l,'4(8)-diene 

o-Mercaptobenzoic acid 

Metanilanilide 

»Metanilic acid (m-Aminobenzenesulfonic acid) 

l-Methoxyanthraquinone 

N-(2-Methoxy-l-naphthyl)acetamide 

6-Methoxymetanilic acid 

l-Methoxy-A-nitroanthraquinone 

2-Methoxy-4-nitrophenol 

p-Methoxyphenylacetic acid 

4' -Methoxypropiophenone 

N'--(6-Methoxy-3-pyTidazinyl) sulfanilamide 

«l-Methylaminoanthraquinone 

l-Methylamino-4-(p-toluidino)anthraqulnone 

N-Methylaniline 

2-(N-Methylanillno)ethanol 

3-(N-Methylamlino)propionitrile 

5-Methyl-o-anisidine [NH2=1] 

N-Methylanthranllic acid 

2-Methylanthraquinone 

l-C3-Methyl-2-aiithraquinonylajnino)-5-(7-oxo-7H-benz[de] - 
anthracen-3-ylaniino) anthraquinone . 

3-Methylbenzo[f]quinoline 

a-Methylbenzyl alcohol 

N-Methylbenzylamine 

Methyl benzyl ether 

3-Methylcholanthrene 

Methylcyclohexane 

N-Methylcyclohexylamine -> 

N-Methyleneanlline 

"ijA'-Methylenebis [2-chloroaniline] 

<l,4'-Methylenebis [N,N-diethylanlllne] 

■»4,4-'-Methylenebis [N,H-dimethylaniline] (Methane base) 

4,4' -Methylenebis [N,N-dimethyl-3-nitroanlline] 

5,5'-Methylenebis [toluene-2,4-diamine] 

Me thylenedi aniline 

Me thy lenedi salicylic acid 

5-Methylene-2-norbornene 

Methi'lfuran 

l-Methyl-2-heptadecylbenziiiiadazoliniummethylol sulfate 

l-Methyl-3-indolecarboxaldehyde 



Manufacturers' identification codes 
(according to list in table 22) 



G. 

ucc. 

ACC, SOC. 
BJL. 

X. 

ARK. 

DOW, MON, SHC, UCP. 

APD. 

APD. 

TNA. 

DUP. 

EK. 

ACY, DUP, G, MAY. 

ACY, DUP, G, ICC, ICI, MAY, TRC. 

AAP, ACY, DUP, EKT, ICC, MAC, TRC. 

G, ICC, TRC. 

ACP, KPT. 

KF. 

ACN, ACY, RCI. 

GIV, HNW. 

GIV. 

LIL, MED. 

G, VPC. 

ACY, DUP, NAC, TRC. 

DUP, G. 

TRC. 

G. 

DUP. 

MEE. 

TBK. 

LIL. 

ACY. 

AAP, ACY, DUP, G, ICI, NAC. 

G, ICI. 

ACY, DUP. 

G. 

DUP. 

BUG, DUP, TRC. 

ICC. 

ACY, NAC. 

DUP. 

ACY. 

UCC. 

ABB. 

UCC. 

EK. 

DOW, PLC. 

DUP. 

DUP. 

DUP. 

DUP. 

ACY, DUP, G, NAC, SDH, x. 

G. 

DUP, NAC. 

DOW, NAC. 

HN. 

DOW. 

CiKO. 

TRC. 



CYCLIC INTERMEDIATES 



83 



TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufacturers ' Identification codes 
(according to list in table 22) 



"i-Kfethylmercapto-m-cresol 

6-Methyl-2-(2-methyl-6-quinolyl)-7-benzothiazolesulfonio 
acid. 

Methylnaphthalene, crude 

N-Kfethyl-4'-nltroaoetanillde 

N-Methyl-p-nltroanlline 

'4-Methyl-2-nitroanisole 

»2-Methjrl-l-nltroanthraquinone 

3-Methyl-l-(m-nitrophenyl) -2-pyrazolin-5-one 

N-Methyl-N-nitroso-p-toluenesulfonamide 

Methylnorbomene-2,3-dicarboxylio anhydride. Isomers 

ni.( 3-Methyl-5 -0X0-2 -pyrazolin-l-yl)benzenesuironaniide 

p-(3-Afethyl-5-oxo-2-pyrazolln-l-yl)benzenesulfonaiiilde 

p-(3-Jfethyl-5-oxopyrazolin-l-yl)benzenesulfonic acid 

m-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonlc acid — 

»p-(3-Methyl-5-oxo-2-pyrazolln-l-yl)benzenesulfonio acid — 
3-(3-lfethyl-5-oxo-2-pyrazolin-l-yl) -1,5-naphthalenedisul- 

fonic acid. 
4-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-in-toluenesulfonic 
acid [SOjH^l]. 

5-Methyl-3-phenyl-4-isoxazolecarboxyllc acid 

5-Methyl-3-phenyl-4-isoxazolecarboxylic acid hydrochlo- 
ride. 

*3-Methyl-l-phenyl-2-pyrazolln-5-one (Developer Z) 

2-Methylpiperazine 

16a-Methyl-l,'i,9(ll)pregnatriene-17a-21-diol-3,20-dione, 
21-etl^l carbonate. 

Methylpropylcarbinylbarbituric acid 

2-Methylpyrazine 

3-Methyl-2-pyrazolin-5-one 

»a-Methylstyrene 

2-Methylsulfonyl-i-nitroaniline 

Methyltetrahydrobenzaldehyde 

p-Methylthloaniline 

3-Kfethyl-6-(p-toluidlno)-7H-dibenz[f,ij]isoquinoline- 
2,7(3H)-dione. 

3-Methyl-l-(p-tolyl)-2-pyrazolin-5-one 

6 '-Methyl-^.'-p-tolylsulfonamido-m-benzanlsidide 

Naphthalene, solidifying at 79° C. or above (refined 
flake) (from domestic crude). 

Naphthalene ace tonitrile 

1,5-Naphthalenedisulfonic acid 

2,7-Naphthalenedisulfonic acid 

l-Naphthalenesulfonic acid 

1-Naphthalenesulfonic acid, sodium salt 

2-Naphthalenesulf onic acid 

2-Naphthalenesulfonic acid, sodium salt 

2-Naphthalenesulfonyl chloride 

»l,^,5,8-Naphthalenetetracarboxylic acid 

1,3,6-Naphthalenetrisulfonic acid 

»Naphthalic anhydride 

»Naphthalimide 

»Naphthionic acid (4-Amino-l-naphthalenesulfonic acid) 

Naphthionic acid, sodium salt 

1-Naphthol (c< -Naphthol) - 

2-Naphthol, tech. ( p -Naphthol) —- — 

p-Naphtholbenzein 

l-Naphthol-3,6-disulfonic acid, monosodium salt 

2-Naphthol-3,6-disulfonic acid (R acid) 

*2-Naphthol-3,6-disulfonic acid, disodium salt 

2-Naphthol-6,8-disulfonlc acid (G acid) 



MEE. 






DUP. 






KPT, 


VEL. 




G, NAC. 




ACY, 


G. 




DUP. 






DUP, 


G, ICI, NAC. 


DUP. 






EK. 






NAC. 






TEC, 


VPC, 


X. 


CMG. 






KLS. 






TRC, 


VPC. 




AAP, 


ACY, 


DUP, G, TRC, VPC. 


TRC. 






CMG. 






ICO, 


X. 




ICO. 






DOW, 


DUP, 


NAC, SDH, SDW, VPC 


WYN. 






SCH. 






LIL. 






WYN. 






DUP. 






ACP, 


DOW, 


HPC. 


EKT. 






UCC. 






EVN. 






G, ICI. 




VPC. 






G, NAC. 




KPT, 


RIL, 


STN. 


COK. 






DUP, 


G, NAC. 


DUP. 






TRC. 






TRC. 






ACY, 


NAC. 




ACY. 






DUP. 






AAP, 


G, HST, TRC. 


G, TRC. 




DUP, 


G, NAC. 


DUP, 


G, NAC. 


ACY, 


DUP, 


NAC. 


DUP, 


NAC. 




DUP, 


NAC. 




ACY, 


NAC, 


SW. 


EK. 






TRC. 






ATL. 






ACY, 


DUP, 


G, NAC, TRC, WJ. 


DUP, 


TRC. 





SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Mamif aoturers' identification codes 
(according to list in table 22) 



2-Naphthol-6,8-disulfonic acid, dipotassium salt 

2-Naphthol-6,8-disulfonic acid, disodium salt 

l-Naphthol-3-sulfonamide 

2-Naphthol-6-sulfonainide, p-toluenesulfonate 

l-Naphthol-A-sulfonio acid (Nevile & Winther's acid) 

l-Naphthol-5 -sulfonic acid 

l-Naphthol-8-sulfonic acid 

*2-Naphthol-6-sulfonic acid (Schaeffer's acid) 

*2-Naphthol-6-Eulfonlc acid, sodium salt 

2-Naphthol-6-sulfonic acid, sodium salt, p-toluenesul- 
fonate . 

2-Naphthol-7-sulfonic acid 

l-Naphthol-3-sulfonic acid, benzenesulfonate, sodium salt- 
l-Naphthol-8-sulfonic acid sultone (1,8-Naphthosultone) — 

1,2 -Naphthoquinone 

Ij'i -Naphthoquinone 

Naphthostyril 

»Naphth[l,2]oxadiazole-5-sulfonlo acid 

1-Naphthylamine (a -Naphthylamine) 

p-2-Naphthylainlnophenol ( N-( p-Hydroxyphenyl) -2-naphthyl- 
amine) . 

2 -(Naphthylthlo) acetic acid 

Nicotlnonitrile (3-CyanopyTidine) 

Nitro-aceanthra [2 , 1-a] aceanthrylene-5 , 13-dione 

4' -Nitroacetanilide 

4-' -Nitro-o-acetanisidide 

2-Nitro-p-acetanisidide 

3'-Nitroacetophenone 

i' -Nitroacetophenone 

5'-Nitro-o-acetotoluidide 

m-Nitroanlline 

o-Nltroaniline 

»p-Nitroaiiillne 

*4-Nitro-o-anisidine [NH2=1] 

»5-Nitro-o-anisidine [NHjil] 

2-Nitro-p-anlsidine [NH2=1]' 

o-Nitroanisole 

p-Nltroanlsole 

A-Nitroanthranlllc acid 

l-Nitroanthraquinone 

1' -Nitroanthraqulnone-2' -cart)Oxyaminoaceanthra[2,l-a] - 
ac e anthry lene -5 , 13 -d ione . 

*l-Nitro-2-anthraquinonecarboxylic acid 

*5-Nitro-l-anthraquinonesulfonlc acid 

5(and 8)-Nitro-l-aiithraquinonesulfonio acid 

8-Nitro-l-anthraquinonesulfonic acid 

8-Nitro-l-anthraquinonesulfonic acid, sodium salt 

2 -( l-Nltro-2 -anthraquinonyl) anthra[ 2, 3] oxazole -5 , 10-dione- 

m-Nitrobenzaldehyde 

6-[p-(p-Nitrobenzamido)benzamido]-l-naphthol-3-sulfonic 
acid. 

6-(p-Nitrobenzamldo) -l-naphthol-3-sulfonlc acid 

4 ' -Nitrobenzanlllde 

^Nitrobenzene 

3-Nitrobenzenesulfonanlllde 

»m-NitrobenzeneEulfonic acid 

»m-Nitrobenzenesulfonic acid, sodium salt 

o-Nitrobenzenesulfonic acid, sodium salt 

o-Nitrobenzenesulfonic chloride 

»m-Nitrobenzenesulfonyl clJ.oride 

p-Nitrobenzenesulfonyl chloride 

5-Nltro-2(3H)-beiizimidazolone 



ACY, NAG. 

G. 

DUP. 

ATL, DUP, NAG. 

NAG. 

G, VPC. 

NAG, SNA, TMS. 

ACY, TRC, WJ. 

DUP. 

DUP. 

G. 

AGY, TRC. 

EK. 

EKT. 

NAG. 

GIC, DUP, G, NAG, TRC, VPC. 

DUP, NAC. 

G, NAC. 

AAP, ACY, DUP. 

NEP, RIL. 

IGI. 

G, TRC. 

DUP. 

DUP, SDH. 

SDH. 

NES. 

DUP. 

ACY, DUP. 

AAP, MON. 

AAP, MON, SDC, UPM. 

AAP, DUP, SDH. 

ACY, AUG, BUG, DUP, KLS. 

DUP, SDH. 

DUP, MON. 

DUP. 

DUP. 

NAC. 

IGI. 

DUP, G, NAG, TRC. 

DUP, MAY, NAC, TRC. 

IGI, NAG, TRC. 

NAC. 

DUP. 

G, NAC. 

NAC, SDH. 

DUP. 

DUP, G. 

G, TRC. 

ACY, DUP, G, MON, NAG. 

G. 

ACY, DUP, NAG. 

AAP, G, MAY, MON, MRA. 

DUP. 

EK. 

ACY, DUP, G. 

EK. 

DUP. 



CYCLIC INTERMEDIATES 



85 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 7965- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



'«ni-Nitrobenzoic acid 

»m-Nitrobenzoic acid, sodium salt 

p-Nitrobenzoic acid 

p-Nitrobenzoic acid, isobutyl ester 

m-Nitrobenzoyl chloride 

p-Nitrobenzoyl chloride 

p-Nitrobenzyl chloroformate 

4-Nitrobenzyl cyanide 

'i'-Nitro-'i-biphenyloarboxylic acid 

3-NitTo— 4-chloro-N, N-diraethylbenzenesulfonamide 

2-Nitro-p-cresol 

Nitrocyclohexane 

Nitrodiphenylamine 

<i-Nitro-6-(5-hydroxy-3-methyl-l-phenyl-'i-pyTazolylazo)- 
l-phenol-2 -sulfonic acid. 

5-Nltroisophthalic acid 

l-Nitronaphthalene 

*3-Nitro-l,5-naphthalenedisulfonlc acid 

8(and 5)-Nitro-l(and 2 )-naphthalenesulfonic acid 

"l-Nitronaphthalic anhydride 

»7(and 8 )-Nitronaphth [l,2]oxadiazole-5-sulfonio acid 

^'-Nitrooxanilic acid 

p-Nitrophenethyl acetate 

Nitrophenethyl alcohol 

o-Nitrophenol 

*p-Nitrophenol 

p-Nitrophenol, sodium salt 

p-Nitrophenylacetic acid 

(p-Nitrophenyl)acetonitrile 

4.' -(p-Nitrophenyl )acetophenone 

A-Nitro-o-phenylenediamine 

Cp-Nitrophenyl )hydrazlne 

2-(';-Nitrophenyl )-(2H )-naphtho [1,2] trlazole-6,8-disulfonio 
acid. 

l-(m-Nitrophenyl )-5-oxo-2-pyrazoline-3-carboxylic acid 

Nitrophthalic. anhydride 

•i-Nitrophthalimide 

5-Nitrosalicylaldehyde 

3(and 5 )-Nitrosalicylic acid 

2-Nitroso-l-naphthol 

p-Nltrosophenol 

p-Nltrostyrene 

2-[4-(<i-Nitro-2-sulfostyryl)-3-sulfophenyl]-2H-naphtho- 
[1,2] triazole-5-sulfonic acid. 

m-Nitro toluene 

o-Nitrotoluene 

p-Nitro toluene 

Nitre toluene mixtures 

5-Nitro-o-toluenesulfonanllide 

»5-Nitro-o-toluenesulfonic acid [S03H = 1] 

*3-Nitro-p-toluenesulfonlc acid [S03H=1] 

-i'-Nitro-p-toluenesulfono-o-toluidide 

5-Nitro-o-toluenesulfonyl chloride 

»4-Nitro-o-toluidine [ NH2=l] - 

»5-Nitro-o-toluidine [ NH2=l] 

*2-Nitro-p-toluidine [ NH2=l] 

2-Nitro-3,4.,6-trichlorophenol 

*16-Nltroviolanthrone 

4-Nitro-m-xylene 

Nitroxylenes, mixed 



HK, 


SDH, 


WAY. 


WAX. 






DUP. 






ICO. 






HK. 






DUP, 


HK. 




EK. 






ICC. 






DUP. 






EKT. 






DUP, 


SW. 




X. 






Acy. 






TRC. 






GAM. 






DUP, 


NAC 




G, NAC, THC. 


G. 






G. 






G, NAC, TRC, VPC. 


DUP, 


NAC. 




EKT. 






EKT. 






DUP, 


NAC. 




DUP, 


MON, 


SDc, vm. 


MON, 


u™. 




BPC, 


ICO. 




BPC. 






DUP, 


G. 




DUP, 


FMI. 




EK. 






TRC. 






VPC. 






EK 






DUP. 






EK. 






G. 






EK. 






ACY, 


DUP, 


NAC. 


CWN. 






TRC. 






DUP, 


NAC. 




DUP, 


NAC. 




DUP, 


NAC. 




ACY, 


DUP, 


NAC. 


G. 






ACY, 


DUP, 


G, NAC, SDH, TRC. 


AAP, 


CMG, 


G, TRC. 


G. 






G. 






ABB, 


DUP, 


G. 


DUP, 


KLS, 


SDH. 


AAP, 


ACY, 


DUP, NAC, SDH, SW 


TRC. 






ACY, 


ATL, 


G, MAY, TRC. 


DUP. 






DUP, 


NAC. 





SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 7B. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



2-tert-Nonyl-p-cresol 

Nonyl-dinonylphenol, mixture 

*Nonylphenol 

2,5-Norbomadlene 

Ctetylphenol 

7-CKabloyclo['i.l.0]heptane 

Qxanitide 

*1- ( 7 -Oxo-7H-benz [de] anthracen-3 -y lamino )anthraqulnone 

»l,l' -(7-0xo-7H-benz [de] anthracen-3, 9-ylenediimlno )- 
dianthraquinone . 

2-Qxooyolopentaneoarboxyllc acid, ethyl ester 

5-Qxo-l-phenyl-2-pyTazoline-3-carboxylio acid 

5-0x0-1 -phenyl-2-pyrazoline-3-oarboxyllc acid, ethyl estei 
»5-0xo-l-(p-sulfophenyl )-2-pyTazoline-3-carboxylio acid 
( Pyrazolone T ) . 

^,^' -Oxydianiline 

Pentadecyltoluene 

1,1,3,3, 5 -Pentamethylindan 

Pentylnaphthalenes (Amylnaphthalenes) 

o-Pentylphenol (o-Amylphenol ) 

3,'i,9,10-Perylenetetracarboxylic acid 

*3,4, 9,10-Perylenetetracarboxylic diimide 

P -Phenethylamine 

p-Phenethylamine sulfate 

o-Phenethylbenzoic acid 

o-Phenetidine 

p-Phenetidlne 

*Phenol : 
»Natural : 

»From coal tar : ■"■ 

39° C, m.p 

S2i,-&A$ • 

All other 

»From petroleum 

^Synthetic : 

By caustic fusion: 

U.S.P 

All other 

From chlorobenzene by liquid-phase hydrolysis: U.S.P- 
From chlorobenzene by vapor-phase hydrolysis: U.S.P--' 

»From cumene 

Other 

Phenolsulfonaphthaleln, sodium salt 

»l-Phenol-4.-sulfonlc acid 

l-(Phenothiazin-2-yl)-l-propanone 

a-Phenoxybutyroyl chloride 

2-Phencxyproplonic acid 

a-Phenoxypropionyl chloride 

Phenylacetic acid (a-Toluic acid) 

Phenylaoetic acid, ethyl ester, tech 

*Phenylaoetio acid, potassium salt 

Phenylacetic acid, sodium salt 

»Hienylacetonitrile (a-Tolunitrile ) 

2-Phenylacetophenone 

4'-naenylaoetophenone 

2-Phenylanthr[2,3]oxazole-5,10-dione 

»p-Phenylazoaniline (p-Aminoazobenzene } and hydrochloride- 

"i-Phenylazodiphenylamine 

l-Phenyl-l,3-butanedione 

2-Phenylbutyric acid 

See footnote at end of table. 



USR. 






G, JCC. 




G, JCC, MON, RH, UCP, USR. 


SHC. 






PRD, 


RH. 




ARA. 






FIN. 






ACY, 


DUP, 


G, ICI, TRC. 


ACY, 


DUP, 


G, ICI, MAY, NAC, TRC 


ARA. 






NAC, 


SDW. 




G, VPC. 




AAP, 


CMC, 


G, ICI, VPC. 


x. 






CO. 






GIV. 






PAS. 






PAS. 






DUP, 


G. 




DUP, 


G, NAC. 


MLS. 






MLS. 






LIL. 






MON. 






DOW, 


DUP, 


MON. 


KPT, 


PRD. 




ACP, 


KPT. 




ACP, 


KPT, 


PRD. 


MER, 


PIT, 


PRD, SW. 


MAL, 


MON, 


RCI. 


HKD. 






van. 






UCP. 






ACP, 


HPC, 


MON, SHC, SOC. 


SKO. 






EK. 






DOW, 


MON, 


UPF. 


WYT. 






ICO. 






ICO. 






ICO, 


OPC. 




BPC, 


GIV, 


TBK. 


BPC, 


MAI, 


TBK. 


BPC, 


OPC, 


TBK. 


BPC. 






BPC, 


OPC, 


SDW, TBK. 


EK. 






DUP, 


G. 




G. 






AAP, 


ACY, 


DUP, G. NAC. 


EK. 






EK. 






BPC. 







CYCLIC INTERMEDIATES 



87 



TABLE 7B. 



Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i 565— Continued 



a-Phenyl-o-oresol 

l-Phenylcyclopentanecarbonitrile 

l-Phenylcyolopentanecarboxyllc acid 

N,N'-p-Phenylenebis [acetamlde] 

m-Phenylenediamine 

o-Phenylenediamine 

p-Phenylenediamine 

1-Phenylephrine base, crude 

Phenyl ether (Dlphenyl oxide ,i 

d(-) Phenylglycine 

Phenylglyoine, sodium salt 

5-Phenylhydantoin 

Phenylhydrazine 

Phenylhydrazine hydrochloride 

2,2' -(Phenylimino)diethanol (Phenyldiethanolamine) 

3,3' -{Phenyliminojdlpropionitrile 

PhenyLmagnesium bromide 

Phenylmalonic acid, diethyl ester 

Phenylmercaptoacetic acid 

o-Phenylphenol 

o-Phenylphenol, chlorinated 

o-Phenylphenol , sodium salt 

p-Phenylphenol 

N-Phenyl-p-phenylenediamine 

Phenylphosphonous acid 

Phenylphosphonous acid, sodium salt 

Phenyl -2-propanone 

N-3-Phenylpropyl-p-toluidine 

Phenyl 2-pyridyl ketone 

Phenyl <i-pyridyl ketone 

Phloroglucinol 

Phthalazinone 

l(2H)-Phthalazinone - - , 

Phthalic acid - 

*Phthallc anhydride 

Phthalide 

Phthalimide — - 

Phthalimide, potassium salt 

Phthalocyanine , copper derivative 

Phthalocyanine , iron derivative 

Phthalooyaninedlsulfonic acid, copper derivative — 

Phthaloyl chloride (Phthalyl chloride) 

Picolines:^ 

»2-Picoline (a-Picoline) 

3-Picoline (p-Picoline) 

-i-Picoline C>' -Plcollne) 

Piooline (3,4-mixture) 

Picramic acid and salt 

Picric acid (Trinitrophenol) 

2-Pipecoline 

Piperazine mixture, crude 

»Piperidine 

3-Piperldinopropiophenone hydrochloride 

Polychlorobiphenyl 

Polydodecylbenzene 

Polyethylbenzene (80^ Diethylbenzene) 

Potassium phenoxlde 

Primuline base 

Primulinesulfonlc acid 

See footnote at end of table. 



Manufacturers' identification codes 
(according to list in table 22) 



RBC. 

SK. 

SK. 

ACY. 

ACY, DUP, G, MAC. 

FMI, NEE, MRT, TRC. 

ACY, BFG, SW. 

CAN. 

DOW. 

PRR. 

DUP, MC. 

ABB, KF. 

DOW. 

FIN. 

AAP, EKT, G. 

DUP. 

ARA. 

BPC. 

e™. 

DOW, RCI. 

DOW. 

DOW, RIG. 

DOW. 

DUP, USR. 

VIC. 

VIC. 

ORT, SK. 

EK. 

RIL. 

RIL. 

MRT. 

AAP. 

KPT. 

HN, KF. 

ACP, ACY, GRH, KPS, MON, PCC, RCI, SOC, SW, THC, UCC, 

WTC. 
FMT, MAC. 
MEE, NAG, SFA. 
EK. 
ICI. 
DUP. 
ICI. 

mii. 

ACP, KPT, RIL, UCC. 

RIL. 

RIL, UCC. 

ACP, KPT. 

DUP, NAG. 

DUP, NAG, SDC. 

LIL. 

JCG. 

ABB, DUP, MRK, RIL. 

ACY. 

MON. 

CO. 

UCC. 

DUP. 

DUP, NAC. 

AIL. 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 7B. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i 965 --Continued 



Manufacturers ' identification codes 
(according to list in tatle 22) 



10-Propionylphenothiazine 

»Propiophenone 

•Pyranthrone 

Pyrazole 

Pyridine, refined :■"■ 

*2° Pyridine 

Other grades 

Pyridine hydrochloride 

3-Pyridinemethaiiol 

Pyridine-N-oxide 

3-Pyridinol 

2(lH)-Pyridone ^^ 

Pyrimidine bromide perbromide 

2-Pyrimidinol 

Pyromellitio acid 

Pyromellitio dianhydride 

Pyrrolidine 

2-Pyrrolidinone 

»Quinaldine 

»Quinizarin 

»2-Quinizarinsulfonic acid 

Quinoline : 

1° and 2° Quinoline 

Other grades 

2,'i-Ciuinolinediol 

Quinoline yellow, base 

8-Quinolinol (8-Hydroxyquinoline, tech.) 

Resorcinol, monoacetate (nonmedicinal grade) 

Resorcinol, tech 

P-Resorcylaldehyde 

p-Resorcylic acid 

p-Resorcylic acid, lead salt 

Salicylaldehyde 

Salicylanilide 

»Salicylic acid, tech 

Salicylic acid, ammonium chromium complex 

Salicylic acid, sodium salt (crudej 

Salicylideneaminoguanidine oleate 

Sodium phenoxide 

Styphnic acid 

Styphnic acid, lead salt 

*StyTene, all grades 

/i' -Sulf amoylaoetanilide 

5-Sulfamoylanthranilic acid 

»Sulfanilic acid (p-Aminobenzenesulfonio acid) and salt- 

M-Sulfoanthranilic acid 

5-Sulfoisophthalic acid, dimethyl ester 

4,4-' -Sulfonyldiphenol (■4,4' -Dihydroxydiphenylsulfone)-- 
4-Sulfophthalio acid 

*Terephthalic acid 

Terephthalic acid dihydrazide 

«Terephthalic acid, dimethyl ester 

Terphenyl (Phenylbiphenyl) 

Tetraaminophthalocyanine, copper derivative 

Tetrabromobisphenol A 

3', 3" ,5' ,5"-Tetrabromophenolphthalein 

Tetrabromophenolphthalein, ethyl ester 

Tetrabromophthalic anhydride 

Tetrabromo-8,16-pyranthrenedione 

See footnote at end of table. 



ABB. 

LIL, OPC, TBK. 

CMG, ICI, TRC. 

LIL. 

ACP, KPT, RIL. 

KPT. 

EK. 

RIL. 

RIL. 

MEP. 

FMT. 

ARA. 

GGY. 

DUP. 

DUP. 

ASL. 

G. 

ACY, DUP, NAG. 

AAP, ACY, CMG, DUP, EKT, G, HSH, ICC, ICI, JTC, MAY, 

NAC, TRC. 
HSH, NAC, PAT. 

ACP, KPT. 

EK. 

DUP, MEE. 

NAC. 

GAM. 

AAP. 

KPT. 

EK. 

ACY, KPT. 

ACY. 

DOW, HN. 

PCW. 

CFC, DOW, HN, M3N, SDH. 

TRC. 

DOW. 

DUP. 

DUP, FIN. 

EK. 

REM. 

ACC, CSD, DOW, ELP, FG, KPP, MCB, MON, SHC, SKC, SNT, 

UCC. 
ACY. 
TRC. 

ACY, DUP, NAC. 
CMG, G, TRC. 

X. 

G, ^DN, UPF. 

CWN, NAC. 

ACC, DUP, SOC. 

DUP. 

ACC, DUP, EKI, HPC. 

ARA, M3N. 

DUP. 

DOW. 

EK. 

EK. 

MCH. 

G, NAC, TRC. 



CYCLIC INTERMEDIATES 



TABLE 7B. 



Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i 965- -Continued 



Manufacturers 
(according ^ 



identification codes 

list in table 22) 



1,3,6,8-Tetrabromopyrene 

»l,4,5,8-Tetrachloroanthraquinone 

1,2,4, 5-Tetrachlorobenzene 

Tetrachlorodiphenol 

Tetraehloronitrobenzene 

a,i,2,6-Tetrachlorotoluene 

Tetrahydrofuran 

Tetrahydro-2-methylfuraji 

Tetrahydrophthalic anhydride 

l,2,3,i-Tetrahydroqulnoline 

l,"i,5,8-Tetrahydroxyanthraauinone 

l,'i,5,8-Tetrald.s [ l',l",l"' ,1"" -anthraquinonylamino] 
anthraquinone ( Pentanthr imide ) . 

p-(l,l,3,3-Tetramethylbutyl)phenol 

Tetranitrophthalocyanine, copper derivative 

Tetraoxyphthalophenone 

2- (2-Thenylamino) pyridine 

Thlanthrene-X,Y-dicarboxylic acid 

Thianthrene-X,y-dinitrile 

Thioanisole 

3,3'-Thiobis[7H-benz[de]anthracen-7-one] 

4.,'i'-Thiodiam.line 

6,6'-Thiodimetanilic acid 

2-Thiophenecarboxaldehyde 

Thiosalicylic acid 

sym-Thymol 

m-Tolidine dihydroohloride 

o-Tolidine 

2,2 '-o-Tolidinedlsulfonic acid 

o-Tolidine hydrochloride 

Toluene-2,4.-diainine (<i-m-Tolylenediamine) 

Toluene-2,'i-disulfonic acid 

o-Toluenesulfonamide 

o(and p ) -Toluenesulf onamide 

p-Toluenesulfonamide 

o(and p) -Toluenesulf onic acid 

p-Toluenesulfonic acid 

p-Toluenesulfonic acid, 2-chloroethyl ester 

p-Toluenesulfonic acid, ethyl ester 

p-Toluenesulfonic acid monohydrate 

p-Toluenesulfono-o-toluidide 

p -Toluenesulf onyl chloride 

p-Toluhydroquinone (MethyUiydroquinone; 

m-Toluic acid 

o-Toluic acid 

p-Toluic acid 

m-Toluidine 

o-Toluidine 

o-Toluidine hydrochloride 

p-Toluidine 

N-(p-Toluidine)methyltaurine 

Toluidines, mixed 

m-Toluldinomethanesulfonic acid 

o-Toluidinomethanesulfonic acid 

8-(p-Toluidino}-l-naphthalenesulfonic acid 

2-(p-Toluidino/-5-nitrobenzenesulfom.c acid 

«o-(p-Toluoyl) benzoic acid 

*<l-(o-Tolylazo)-o-toluidine 

"♦-(o-Tolylazo) -o-toluidine hydrochloride 

2,2 '- ( m-Tolyli mi no ) diethanol 

4-,5,6-TriaminopyTimidine sulfate hydrate 

3,'i',5-Tribromosalicylanilide 

l,2,3(and l,2,'i)-Triohlorobenzene 

1,2,4-Trichlorobenzene 



AAP, G. 

DUP, G, ICI, MAC. 

DOW, UK. 

MON. 

SDH. 

DUP. 

DUP. 

QKO. 

PTT. 

EK. 

NAG. 

ICI, MAC. 



TRC. 






TRG. 






PIT. 






DUP, 


G, IGI. 


ACY, 


MAC 




NAG. 






EVN. 






GIV. 






GWN. 






CWN, 


DUP 


NAC. 


AAP. 






AAP, 


DUP 


EK. 


AGY, 


BL, 


DUP, G, NAC, SDC, TRG 


G. 






^DN. 






AGY. 






MON. 






MON, 


NAG 


NES, SW, UPF. 


AGY, 


TN. 




G. 






AGY, 


ICI 


MAG. 


UPF. 






G. 






MON. 






EKT. 






CWL. 






GWL. 






CWL, 


EK. 




DUP, 


NAG 




DUP, 


NAG 




ACY. 






DUP, 


NAG 




BUG. 






DUP. 






TRC, 


VPC 




TRC. 






NAG. 






TRC. 






AGY, 


DUP 


NAC, TRC. 


AGY, 


DUP 


G, KLS, NAC, SDH. 


G. 






EKT, 


G, NAG. 


ARA. 






VEE. 






PPG. 






DOW, 


HK, 


SVT. 



749-026 O - 64 • 



90 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 7B. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i 565 --Continued 



Manufacturers' identification codes 
(according to list in table 22) 



N,2,6-Trichloro-p-benzoquinoneimine 

1, 2, <*-Trichloro-5 -nitrobenzene 

Trichlorophenylsilane 

:'.,a,a-Trichlorotoluene (Benzotrl chloride) 

ci,2,'i— Triehlorotoluene 

a,2,<i(and ^,2,6) -Triohlorotoluene 

ajSj'i-Trichlorotoluene 

1,3,5-Triethylbenzene 

3-Trif luoromethyldiphenylamine 

2-Trif luoromethylphenothiazine 

a,a,a-Trif luoro-4-nitro-m-cresol 

a^a ^a-Trif luoro-m-nitrotoluene 

a,a>a-Trlf luorotoluene 

a, a, a-Trif luoro-m-toluidine 

1,2,'i-Trihydroxyanthraquinone 

Sj'ijS-Trlmethoxybenzolc acid 

2,'i,5-Trimethylanlline (Pseudociimidine) 

1,2,'i-Trimethylbenzene ( Pseudocumene) 

2,3,3-Trimethyl-3H-indole 

1,3,3-Triinethyl-A^'"' -indolineacetaldehyde 

l,3,3-Trimethyl-2-methyleneindoline (Trimethyl base)- 

Trimethylphenylammonlmn iodide 

l,2,<l-Trimethylpyrazine 

1,3,5-Trinitrobenzene 

2,'i,6-Trinitrobenzenesulfonic acid 

Triphenylmethanol 

a,o' ,a" -Tris(dimethylamino)mesitol 

2,4,6-Tris[dimethylaminomethyl]phenol 

»6,6 '-Ureylenebis[l-naphthol-3-sulfonio acid] (J acid 
urea) . 

Veratraldehyde (3,4-Dimethoxybenzaldehyde) 

p-Vlnylbenzenesulf onic acid, sodium salt 

2-Vinylcyclohexene 

i-Vinylcyclohexene 

2,2'-Vinylenebis[benzimldazole] 

5-Vinyl-2-picoline (MVP) 

2-Vinylpyridlne 

■i-Vinylpyridine 

*Violanthrone (Dibenzanthrone) 

9-X£inthenecarboxylic acid 

m-Xylene 

»o-Xylene 

*p-Xylene 

m-Xylene-ci,a' -diamine 

Xylenesulfonio acid 

2,5-Xylenesulfonic acid 

Sj-i-Xylenol 

Xyienol crystals 

Xylenols : 

Low b.p 

Medium b.p 

Not classified as to b.p 

Xylidines : 

2,'i-Xylidine (m^-Xylidine) — 

2,5-Xylidine (p-Xylidine) 

Original mixture 

^-(2,4-Xylylazo)-o-toluldine 

<4-(2,5-Xylylazo) -o-toluidine 

't-(Xylylazo)xylidine 

'l-(2,4-Xylylazo)-2,5-xylldine 

All other cyclic intermediates 



ALL, 


PCW. 




DCC, 


UCS. 




HK, 


HN. 




HN. 






BPC. 






HN. 






DUP. 






SK. 






SK. 






MEE. 






MEE. 






ACC, 


HK. 




MEE. 






G. 






ICO. 






NAC. 






EN J, 


PLC. 




G. 






DUP, 


G. 




DUP, 


G. 




EK. 






vmi. 






EK. 






EK. 






EK. 






TKL. 






RH. 






ACY, 


ATL, 


CMG, G, NAC, TRC, VPC. 


LIL, 


SLV. 




DUP. 






UCC. 






PLC. 






TRC. 






PLC. 






RIL. 






RIL. 






ACT, 


ATL, 


DUP, G, ICI, MAY, TRC. 


MAL. 






PLC, 


SNT, 


SOC. 


ASH, 


CCP, 


CSD, CSO, DLH, ENJ, GRS, MQN, PLC, SIN 


SNT, SOC, TOC. 


CSD, 


EN J, 


SIN, SNT, SOC. 



ACP, 


KPT. 




PIT, 


PRD. 




KPT, 


PIT, 


PRD 


KPT, 


PRD. 




DUP, 


NAC. 




DUP, 


NAC. 




DUP, 


NAC. 




NAC. 
ACY. 







NAC. 

ACY, APD, CCW, G, ICC, KF, SWR, WLM, UPJ, x. 



Does not include manufacturers' identification codes for producers that report to the Division of Bituminous 
Coal, U.S. Bureau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey Coke 
Producers in the United States in 1963, June 8, 1964. 



DYES 



Dyes 



TABLE 8B. — Coal-tar dyes for which U.S. production or sales were reported, 
identified by manufacturer, 1963 



[Dyes for which separate statistics are given in table 8A are marked below with an asterisk (»); dyes not so marked 
do not appear in table 8A jecause the reported data are accepted in confidence and may not be published. Manufac- 
turers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not 
consent to his identification with the designated product] 



Dye 



ACID DYES 

»Acid yellow dyes: 

Acid Yellow 1 

Acid Yellow 2 

»Acid Yellow 3 

Acid Yellow -4 

Acid Yellow 7 

Acid Yellow 9 

*Acid Yellow 11 

Acid Yellow U 

»Acid Yellow 17 

»Acid Yellow 23 

Acid Yellow 25 

Acid Yellow 29 - 

Acid Yellow 34 -- 

Acid Yellow 35 

»Acid Yellow 36 

Acid Yellow 38 - 

»Acid Yellow 4-0- 

»Acid Yellow 42-- 

Acid Yellow 43- 

*Acid Yellow 44 

»Acid Yellow 54 

Acid Yellow 59 

Acid Yellow 60 

Acid Yellow 63 

Acid Yellow 65— - - 

»Acid Yellow 73-- 

Acid Yellow 76 

Acid Yellow 90 — --- 

Acid Yellow 95 

»Acid Yellow 99 

Acid Yellow 114 

Acid Yellow 121- --- 

Acid Yellow 124--- 

Acid Yellow 127- 

Acid Yellow 128 

Acid Yellow 129 

Acid Yellow 151 

Acid Yellow 152- 

Other acid yellow dyes 

»Acld orange dyes: 

»Acid Orange 1 

Acid Orange 2 

Acid Orange 5 

Acid Orange 6 

*Acid Orange 7 

♦Acid Orange 8 

»Acid Orange 10 

Acid Orange 12 

Acid Orange 19 



Manufacturers' identification codes 
(according to list in table 22) 



ACY. 

DUP. 

ACY, DUP, G, MAC. 

SDH. 

MAC. 

ACY. 

CMG, DUP, VPC. 

TRC. 

ACY, ATL, BKS, CMG, DUP, G, NAC, PDC, SDH, TRC, VPC. 

AAP, ACY, G, MRX, NAC, SDH, TRC, VPC. 

G. 

G, TRC. 

MAC. 

VPC. 

DUP, G, NAC, TRC. 

NAC. 

ACY, DUP, G, NAC, TRC, VPC. 

AAP, ACY, G, TRC, VPC. 

NAC. 

AAP, G, NAC, VPC. 

ACY, BKS, CMG, G, NAC, TRC, VPC. 

VPC. 

NAC. 

AAP, NAC. 

TRC. 

NAC, mrC, SDH. 

TRC. 

NAC. 

CMG. 

G, NAC, TRC, VPC. 

CMG, TRC. 

G. 

DUP, NAC. 

TRC. 

TRC. 

TRC. 

ACY. 

ACY. 

ACY, ALT, CMG, DUP, TRC, VPC. 

ALT, BKS, G, NAC. 

NAC, TRC. 

ACY. 

NAC. 

AAP, ACY, ATL, CPC, G, NAC, PDC, TRC, YAW. 

ACY, DUP, G, NAC, TRC. 

ACY, ATL, DUP, G, NAC, TRC, VPC, YAW. 

NAC. 



92 



TABLE 8B. 



SYNTHETIC ORGANIC CHEMICALS, 1963 

-Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



ACID DYES--Continued 

»Acid orange dyes — Continued 

»Acid Orange 2<i 

Acid Orange 28 

Acid Orange 31 

Acid Orange 3"^ 

Acid Orange 45 

Acid Orange 49 

Acid Orange 51 

Acid Orange 52 

Acid Orange 56 

»Acid Orange 60 

Acid Orange 62 

Acid Orange 63 

Acid Orange 64 

Acid Orange 69 

Acid Orange 72 

Acid Orange 74 

Acid Orange 76 

Acid Orange 85 

Acid Orange 86 

Other acid orange dyes 

■»Acid red dyes; 

»Acid Red 1 

»Acid Red 4 

Acid Red 12 

»Acid Red 14 

Acid Red 17 

*Acid Red 18 

Acid Red 25 --- 

*Acid Red 26 

Acid Red 27 

Acid Red 29 

Acid Red 32 

Acid Red 33 

Acid Red 34- 

Acid Red 35 

»Acid Red 37 

Acid Red 42 

Acid Red 51 

Acid Red 52 

Acid Red 57 

Acid Red 60 

Acid Red 66- 

»Acid Red 73 

Acid Red 76 

Acid Red 80 

»Aoid Red 85 

»Acid Red 87 

»Acid Red 88 

»Acid Red 89 

Acid Red 92 

Acid Red 94 

Acid Red 97 - 

Acid Red 99 

Acid Red 100 — 

Acid Red 106- 

Acid Red 113 



ACY, DUP, G, NAC, TRC, YAW. 

MAC. 

AAP. 

ACY. 

NAC, TRC. 

TRC. 

CMC, MAC, TRC. 

NAC. 

0. 

CMG, DUP, G. 

TRC. 

G, TRC. 

ACY, DUP, NAC. 

ACY. 

G. 

CMG, G, NAC, TRC. 

NAC, TRC. 

NAC. 

NAC, TRC. 

ALT, TRC, VPC. 

AAP, ACY, BKS, DUP, G, NAC, SDH, TRC, VPC, YAW. 

ATL, CMG, DUP, G, TRC, VPC, YAW. 

G, TRC. 

ATL, CMG, DUP, G, NAC, PDC. 

NAC, TRC. 

ACY, ATL, DUP, G, NAC, TRC. 

TRC. 

ACY, ATL, G, NAC, TRC, x. 

NAC. 

NAC. 

G, NAC. 

NAC, YAW. 

DUP, NAC. 

AAP, G. 

CMG, DUP, G, NAC, TRC. 



NYC. 



TRC. 

TRC. 

AAP, NAC. 

ACY, DUP, G, NAC, TRC. 

NAC. 

G, ICI. 

ACY, ALT, ATL, BKS, CMG, DUP, G, NAC, PDC, TRC, VPC, 

YAW. 
AMS, NYC, SDH. 

ACY, ATL, DUP, G, NAC, SDH, TRC, YAW. 
AAP, G, TRC, VPC. 
NYC, SDH. 
NYC. 
G. 

CMG, NAC, TRC. 
VPC. 
YAW. 
DUP. 



DYES 

TABLE 8B. — Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



93 



Dye 



Maniifacturers ' identification codes 
(according to list in table 22) 



ACID DYES--Continued 

»Aoid red dyes — Continued 

»Aeid Red lU 

♦Acid Red 115 -- 

Acid Red 119 

Acid Red 133 

Acid Red 134 

»Acid Red 137 

"Acid Red 151 

Acid Red 167 

Acid Red 172 - 

Acid Red 175 

Acid Red 178 

Acid Red 179 

»Acid Red 182- 

Acid Red 183 

Acid Red ISA 

»Acid Red 186 

Acid Red 190 

Acid Red 191- - — 

Acid Red 19^— 

Acid Red 197- -- 

Acid Red 207 

Acid Red 212- 

Acid Red 213 

Acid Red 292 — - 

Acid Red 299 - 

Other acid red dyes 

*Acid violet dyes: 

»Acid Violet 1 

»Acid Violet 3 

Acid Violet 6 

»Acid Violet 7 

»Acid Violet 12 

Acid Violet 13 

Acid Violet 14 --■ 

»Acid Violet 17 

Acid Violet 21- - 

Acid Violet 29 

Acid Violet 34 

*Acid Violet 43 

Acid Violet 49 

Acid Violet 56 

Acid Violet 76 

Acid Violet 78 

Other acid violet dyes 

»Aoid blue dyes: 

Acid Blue 1 

»Acid Blue 7 

»Aoid Blue 9 

Acid Blue 10 

Acid Blue 13 

Acid Blue 15 

Acid Blue 20 

»Aoid Blue 22- - 

Acid Blue 23 

"Acid Blue 25 

Acid Blue 26 

Acid Blue 27 



ATL, DUP, G. 




0, NAC, TRC. 




MAC. 




G. 




TRC. 




ACY, DUP, G, NAC, TRC. 


AAP, ACY, TRC 


YAW. 


BKS, NAC, TRC 




VPC. 




DUP. 




DUP. 




CMG, TRC. 




ACY, BKS, CMG 


DUP, G, NAC. 


CMG, TRC. 




TRC. 




CMG, G, TRC, 


/PC. 


ACY. 




TRC. 




TRC. 




DUP. 




NAC. 




TRC. 




TRC. 




ACY. 




TRC. 




ACY, ALT, TRC 


, VPC. 


CMG, G, NAC. 




ACY, DUP, NAC 


, TRC, YAW. 


NAC. 




AAP, CMG, DUP 


, G, NAC, TRC, VPC 


CMG, DUP, G, 


[RC. 


DUP. 




TRC. 




DUP, G, SDH, 


TRC. 


DUP. 




HSH. 




ICI, NAC. 




DUP, HSH, ICI 




ACY, NAC, SDH 




CMG, G. 




NAC. 




NAC. 




ALT. 




G, NAC, SDH. 




ACY, G, NAC, 


SDH. 


G, NAC, SDH, 


VPC. 


AAP, NAC. 




DUP, SDH. 




DUP, G. 




ACY, NAC. 




ACY, G, NYC. 




NAC, TRC. 




CMG, DUP, G, 


NAC, TRC. 


NAC. 




CMG, G. 





94 



SYNTHETIC ORGANIC CHEMICALS 1963 



TABLE 8B. — Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer , 1 963--Contiimed 



Manufacturers ' identification codes 
(according to list in table 22) 



ACID DYES— Continued 

*Acid blue dyes — Continued 

Acid Blue 29 - 

Acid Blue 3A 

Acid Blue 35 

»Acid Blue ^0 

»Acid Blue -il 

»Acid Blue <i3 

»Acid Blue ^15 

Acid Blue A7 

Acid Blue A8 

Acid Blue 58 

Acid Blue 59 

Acid Blue 62 

Acid Blue 63 

Acid Blue 67 

Acid Blue 69 

Acid Blue ?<; 

»Acid Blue 78 

Acid Blue 79 

Acid Blue 80 

Acid Blue 81 

Acid Blue 83 

Acid Blue 89 

»Acid Blue 90 

Acid Blue 92 

Acid Blue 93 --- 

Acid Blue 102 

Acid Blue 10<i 

»Acid Blue 113 

Acid Blue 118 

Acid Blue 120 

Acid Blue 122 — - -- 

Acid Blue 137 

Acid Blue U5- 

»Acid Blue 158 and 158A 

Acid Blue 165 

Acid Blue 179 — - 

Other acid blue dyes 

»Acid green dyes: 

Acid Green 1 -- 

»Acid Green 3 

Acid Green 5 

»Acid Green 9 

Acid Green 10 

■»Acid Green 12 

»Acid Green 16 

*Acid Green 20-- 

Acid Green 22 

*Acid Green 25 

Acid Green 35 

Acid Green 41 

Acid Green 44 

■»Acid Green 50 

Other acid green dyes 

»Acid brovm dyes: 

Acid Brown 1 

Acid Brown 2 

Acid grown 6 



PDC, YAW. 

MAC. 

MAC. 

G, ICI, MAC, TRC. 

CMG, G, MAC. 

ACY, G, MAC, TRC. 

ACY, CMG, DUP, G, NAC, TRC. 

DUP, ICI. 

sue. 

DUP. 

NAC. 

G, VPC. 

CMG, NAC. 

CMG, NAC. 

DUP, G. 

DUP, NAC. 

DUP, G, ICI, NAC. 

DUP. 

NAC, TRC. 

ICI. 

G. 

NAC. 

G, NAC, TRC. 

NAC. 

sue. 

NAC, TRC. 

DUP, G, NAC. 

CMG, DUP, G. 

G, NAC. 

G, NAC. 

DUP. 

NAC. 

DUP. 

ACY, BKS, DUP, G, NAC, TRC, VPC. 

DUP. 

G. 

ACY, ALT, CMG, PAT, TRC, VPC. 

ACY, NAC. 

ACY, DUP, G, NAC, SDH, TRC, VPC. 

G. 

ACY, DUP, G, NAC, VPC. 

NAC. 

G, NAC, TRC. 

DUP, G, MAC, SDH, TRC. 

ATL, CMG, DUP, G, NAC, TRC. 

G, HSH, NAC. 

AAP, ATL, CMG, G, ICI, NAC, TRC, VPC. 

TRC. 

ICI, VPC. 

VPC. 

ACY, G, NAC, VPC. 

ALT, DUP, TRC, VPC. 



DYES 



95 



TABLE 8B. — Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 565- -Continued 



Dye 



Manufacturers ' identification codes 
(according to list in table 22) 



ACID DYES — Continued 

«Acid brown dyes — Continued 

»Acid Brown U 

Acid Brown 19 

Acid Brown 22 

Acid Brown 28 

Acid Brown 29 

Acid Brown 31 

Acid Brown A5 

Acid Brown 96 

Acid Brown 97 

Acid Brown 98 

Acid Brown 152 

Acid Brown 158 

Acid Brown 223 

Acid Brown 243 

Other acid brown dyes 

»Acid black dyes: 

»Acid Black 1 

Acid Black 2 

Acid Black 12 

Acid Black 16 

Acid Black 18 

»Acid Black 2A 

Acid Black 26, 26A, and 26B 

Acid Black 29 

Acid Black Al 

»Acid Black 48 

Acid Black 52 

Acid Black 53--- -- 

Acid Black 58- - --- - 

Acid Black 60 -— 

Acid Black 92 

Acid Black 107 

Acid Black 138- --- - -- 

Acid Black 140 

Other acid black dyes 

AZOIC DYES AND CCMPONENTS 
Azoic Compositions 

Azoic yellow dyes: 

♦Azoic Yellow 1 

»Azoic Yellow 2 

Azoic Yellow 3 

Azoic Yellow 10 

Azoic orange dyes: 

»Azoic Orange 3 

Azoic Orange 4 

»Azoic red dyes: 

»Azoic Red 1 

»Azoic Red 2 

»Azoio Red 6 

Azoic Red 12 

Azoic Red 13 

Azoic Red 14 

Azoic Red 15 

Azoic Red 16 



AAP, ACY, DUP, G, NAC, TRC, YAW. 

TRC. 

DUP. 

TRC. 

DUP, NAC. 

G. 

TRC. 

ACY. 

ACY. 

ACY, TRC. 



ALT, DUP, G, VPC. 

AAP, ACY, ATL, BKS, CMC, DUP, G, NAC, PDC, TRC, YAW. 

ACY, NAC. 

NAC. 

NAC. 

NAC. 

CMG, DUP, G, NAC. 

DUP, NAC, TRC. 

NAC. 

G, NAC. 

ACY, CMG, DUP, G, ICI, NAC, TRC. 

G, NAC, TRC. 

NAC. 

CMG, NAC, TRC. 

TRC. 

ACY. 

G, NAC. 

VPC. 

G. 

ALT, BL, DUP, G, PDC. 



ALL, ATL, G, HST, VPC. 
ALL, ATL, 0, HST, x. 
ATL, G. 
DUP. 

ALL, ATL, G, HST, x. 



ALL, ATL, BUC, G, HST, X. 

ALL, ATL, BUC, G, x. 

ALL, ATL, BUC, G, HST, VPC, X. 



G. 
ATL, G. 



96 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 8B. — Coal-tar dyes for which U.S. production or sales uiere reported, identified by 
manufacturer , i965--Continued 



Dye 



Manufac^ure^s ' identification codes 
(according to list in table 22) 



AZOIC DYES AND COMPONENTS— Continued 



■ Compo 



-Cnnr inued 



«Azoio red dyes — Continued 

Azoic Red 73 

Azoic Red 74 

Other azoic red dyes 

Azoic violet dyes: 

Azoic Violet 1 

Other azoic violet dyes 

Azoi-j tlue dyes: 

Azoic Blue 2 

»Azoio Blue 3 

Azoic Blue U 

Azoic Blue 5 

Azoic Blue 6 

Azoic Blue 7 

Other azoic blue dyes 

Azoic green dyes: 

Azoic Green 1 

Other azoic green dyes 

Azoic brovm dyes: 

■»Azoic Brovm 9 

Azoic Brown 10 

Azoic Brown 26 

Other azoic brown dyes 

Azoic black dyes: 

Azoic Black 1 

Azoic Black 2 

»Azoic Black <* 

Azoic Black 15 

Other azoic black dyes 

All other azoic compositions 

\:tjic Diazo Component 
(Fasl Color Ba. 

Azoic Diazo Component 1, base 

Azoic Diazo Component 2, base 

Azoic Diazo Component 3, base 

■»Azoic Diazo Component A, base 

Azoic Diazo Component 5, base 

Azoic Diazo Component 8, base 

Azoic Diazo Component 9, base 

»Azoic Diazo Component 10, base 

Azoic Diazo Component 11, base 

*Azoic Diazo Component 12, base 

»Azoic Diazo Component 13, base 

Azoi: Diazo Component 14, base 

Azoic Diazo Component 20, base 

Azoic Diazo Component 24, base 

Azoic Diazo Component 28, base 

»Azoic Diazo Component 32, base 

Azoic Diazo Component 34, base 

Azoic Diazo Component 41, base 

Azoic Diazo Component 42, base 

*Azoic Diazo Conqjonent 48, base 

Azoic Diazo Component 121, base 

Other azoic diazo components, bases- 



BUC, G, VPC, X. 
ATL, G, HST, X. 



ATL, G. 






ALL, ATL, 


G, 


HST, X. 


G. 






G. 






ATL, G. 






G. 






G, VPC. 






ATL, G. 






VPC. 







ATL, G, HST, VPC, x. 

G. 

G. 

G, VPC, x. 

G, HST. 

DUP. 

ALL, ATL, G. 

G. 

ATL, G, VPC. 

ALL. 



G, SDH. 

AAP, ATL. 

KLS, SDH, VPC. 

ALL, G, KLS, MAC, SDH. 

G, NAC, SDH. 

DUP. 

AAP, DUP. 

BUG, G, KLS, VPC. 

BUC. 

AAP, ALL, AUG, KLS, SDH. 

AAP, ALL, ATL, AUG, BUC, DUP, KLS, SDH. 

AAP. 

ALL, G. 

KLS. 

ALL, KLS. 

AAP, ALL, ATL, AUG, BUC, DUP, KLS, SDH. 

G. 

ALL, G. 

ALL. 

ALL, CWN, DUP, G. 

PCW. 

G, VPC. 



DYES 



97 



TABLE SB. --Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, i963--Continued 



Dye 



Manufacturers ' identification codes 
(according to list in table 22) 



AZOIC DYES AND COMPONENTS— Continued 

Azoic Diu=o Componenls. ^al:s 
(Fasl Color Sails) 

»Azoic Diazo Component 1, salt 

»Azoic Diazo Component 2, salt 

»Azoic Diazo Component 3, salt 

Azoic Diazo Component 4, salt 

»Azoic Diazo Component 5, salt 

»Azoic Diazo Component 6, salt 

*Azoic Diazo Component 8, salt 

•»Azoic Diazo Component 9, salt 

»Azoic Diazo Component 10, salt 

»Azoic Diazo Component 11, salt 

»Azoic Diazo Component 12, salt 

»Azoic Diazo Component 13, salt 

Azoic Diazo Component 14, salt 

«Azoio Diazo Component 20, salt 

»Azoic Diazo Component 28, salt 

Azoic Diazo Component 32, salt 

Azoic Diazo Component 33, salt 

Azoic Diazo Component 3^, salt 

Azoic Diazo Component 35, salt 

»Azoic Diazo Con^jonent 36, salt 

Azoic Diazo Component 37, salt 

Azoic Diazo Component 41, salt 

»Azoio Diazo Component 42, salt 

Azoic Diazo Component 44, salt 

»Azoic Diazo Conqjonent 48, salt 

»Azoio Diazo Component 49, salt 

Other azoic diazo components, salts 

Azoic Coupling Components 
(Naphthol AS and Derivatives) 

»Azoic Coupling Component 2 

■»Azoic Coupling Component 3 

»Azoic Coupling Component 4 

»Azoic Coupling Component 5 

»Azoic Coupling Component 7 

Azoic Coupling Component 8 

Azoic Coupling Component 10 

Azoic Coupling Component 11 

Azoic Coupling Component 12 

Azoic Coupling Component 13 

»Azoic Coupling Component 14 

Azoic Coupling Component 15 

Azoic Coupling Component 16 

■»Azoic Coupling Component 17 

»Azoic Coupling Component 18 

Azoic Coupling Component 19 

»Azoic Coupling Component 20 

»Azoic Coupling Component 21 

Azoic Coupling Component 23 

Azoic Coupling Component 24 

»Azoic Coupling Component 29 

Azoic Coupling Con^ionent 31 

•Azoic Coupling Component 34 

»Azoic Coupling Component 35 



AAP, 

ALL, 

AAP, 

ALL, 

AAP, 

AAP, 

AAP, 

AAP, 

AUG, 

AAP, 

AAP, 

AAP, 

AAP. 

ALL, 

ALL, 

ALL, 

AUG. 

G. 

G. 

AAP, 

G. 

ALL, 

ALL, 

G. 

AAP, 

AAP, 



G, KI^, SDH. 

G, KLS. 

ALL, AUG, BUC, G, KLS, NAC, SDH, VPC. 

AUG. 

AUG, G, KLS, SDH, VPC. 

G, KLS, SDH. 

ALL, AUG, BUC, G, KLS. 

ALL, AUG, BUC, G, KI^, NAC, SDH, VPC. 

BUC, G, KLS, SDH. 

G, KLS. 

ALL, AUG, BUC, G, Kl£, SDH. 

ALL, AUG, BUC, G, KLS, NAC, SDH, VPC. 

G, SDH. 

BUC, G, KLS, NAC, SDH, VPC. 

KLS. 



G, NAC. 



G, KI^. 



ALL, G, NAC, SDH. 
BUC, G, KLS. 



ACY, ATL, DUP, G, NAC, PCW. 

BUC, G, PCW. 

ATL, BUC, G, PCW. 

AAP, G, PCW, SDH. 

AAP, AUG, G, NAC, PCW. 

ATL, G, PCW. 

ATL, PCW. 

G, PCW. 

ALL, BUC, G, PCW. 

ALL, G, PCW. 

ALL, ATL, BUC, PCW. 

0. 

G, SDH. 

ACY, ALL, ATL, BUC, DUP, PCW. 

ACY, ATL, BUC, DUP, G, NAC, PCW. 

AAP, G, PCW. 

ALL, ATL, BUC, DUP, G, PCW. 

AAP, ALL, ATL, BUC, PCW. 

G, PCW. 

G, PCW. 

ATL, AUG, G, PCW. 

PCW. 

BUC, G, PCW. 

ALL, G, PCW. 



SYNTHETIC ORGANIC CHEMICALS, 1963 

TABLE 8B. — Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Dye 



Manufacturers ' identification codes 
(according to list in table 22) 



AZOIC DYES AND CCJCONENTS— Continued 

Azoic Coupling Components 
(Naphthol AS and DeHvativesj-ContinveA 

Azoic Coupling Component 36 

Azoic Coupling Component 43 

Other azoic coupling components 

BASIC DYES 

Basic yellow dyes: 

Basic Yellow 1 

•Basic Yellow 2 

Basic Yellow 5 

Basic Yellow 11 

Basic Yellow 13 

Basic Yellow 15 

Basic Yellow 26 

Basic Yellow 27 

Other basic yellow dyes 

•Basic orange dyes: 

•Basic Orange 1 

•Basic Orange 2 

Basic Orange 14 

Basic Orange 17 

•Basic Orange 21 

Basic Orange 22 

Basic Orange 24 

Basic Orange 25 

Basic Orange 26 

Basic Orange 31 

Basic red dyes: 

Basic Red 1 

•Basic Red 2 

Basic Red 9 

Basic Red 12 

Basic Red 13 

Basic Red 14 

Basic Red 15 

Basic Red 16 - 

Basic Red 17 

Basic Red 18 

Basic Red 20 

Basic Red 30 - - 

Other basic red dyes 

Basic violet dyes: 

•Basic Violet 1 

Basic Violet 2 

Basic Violet 3 

•Basic Violet 4 

Basic Violet 5 - 

Basic Violet 7 

•Basic Violet 10 

Basic Violet 13 

Basic Violet 14— - — 

Basic Violet 15 

•Basic Violet 16 - — 

Basic Violet 18- - 

Other basic violet dyes 



ALL, ATL, G. 
ATL, BUC, G. 



DUP. 

ACY, DUP, MAC. 

NAC. 

DUP, G, NAC, VPC. 

DUP, G, NAC. 

DUP. 

ACY. 

ACY. 

G, DUP. 

ACY, DUP, G, NAC. 

ACY, DUP, G, NAC, PDC, TRC. 

G. 

NAC. 

DUP, G, NAC, VPC. 

G, NAC. 

DUP. 

DUP. 

DUP. 

ACY. 

DUP, G, NAC. 

DUP, G, NAC. 

ACY, sue. 

DUP. 

G, NAC. 

ACY, DUP, G, NAC. 

DUP, G. 

DUP. 

DUP. 

DUP. 

DUP. 

ACY. 

ACY. 

ACY, DSC, NAC, SUC. 

ACY. 

DSC, DUP, G, NAC, SDH. 

DSC, DUP, G, NAC. 

NAC. 

G, NAC. 

ACY, DUP, G, NAC. 

DSC. 

ACY, NYC. 

DUP. 

DUP, G, VPC. 

ACY. 

DUP, G. 



DYES 



99 



TABLE BB. --Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



BASIC DYES — Continued 

»Basic blue dyes: 

»Basic Blue 1 

Basic Blue 3 

Basic Blue 4 

Basic Blue 5 

Basic Blue 6 

•Basic Blue 7 

•Basic Blue 9 

Basic Blue 11 

Basic Blue 21 

Basic Blue 22 

•Basic Blue 26 

Basic Blue 27 

Basic Blue 35 

Basic Blue 36 

Basic Blue 38 

Bksic Blue 39- - 

Basic green dyes: 

•Basic Green 1 

Basic Green 3 

•Basic Green 4 

Basic Green 5 

Other basic green dyes 

Basic brown dyes: 

•Basic Brown 1 

Basic Brown 2 

•Basic Bro?m <i 

Basic black dyes: 

Basic Black 3 

Other basic black dyes 

DIHECT DYES 

•Direct yellow dyes: 

•Direct Yellow 4 

•Direct Yellow 5 

•Direct Yellow 6 

Direct Yellow 7 

Direct Yellow 8 

Direct Yellow 9 

•Direct Yellow 11 

•Direct Yellow 12 

Direct Yellow 19 

Direct Yellow 20 

Direct Yellow 23 - 

-•Direct Yellow 26 

Direct Yellow 27 

•Direct Yellow 28 

•Direct Yellow 29 

Direct Yellow 39 - - 

•Direct Yellow U, 

•Direct Yellow 50 

•Direct Yellow 59 

Direct Yellow 62 

Direct Yellow 63 

•Direct YejLlow 81 

•Direct Yellow 8A 

Direct Yellow 103 



Manufacturers ' identification codes 
(according to list in table 22) 



DSC, 


G, NAC, 


SDH. 


G. 








DUP. 








DSC, 


SDH. 






ACY, 


NAC. 






DSC, 


DUP, 


G, 


NAC, SDH. 


ACY, 


G, NAC, 


SDH. 


DSC, 


DUP. 






DUP. 








DUP, 


NAC. 






DSC, 


DUP, 


G, 


NAC, SDH. 


G. 








DUP. 








DUP. 








ACY, 


DUP. 






DUP. 








ACY, 


DSC, 


DUP, NAC, SDH 


DUP. 








ACY, 


DSC, 


NAC, SDH. 


ACY. 








DUP. 








ACY, 


DUP, 


G, 


NAC, TRC. 


G, NAC. 






ACY, 


DUP, 


G, 


NAC, TRC. 


G. 








DUP. 









ACY, DUP, G, NAC, TRC. 

ACY, G, NAC. 

ACY, DUP, G, NAC, TRC. 

ATL. 

G, NAC. 

DUP. 

ACY, DUP, G, NAC, TRC. 

BKS, DUP, G, NAC, TRC. 

TRC. 

NAC, TRC. 

DUP. 

ALT, BKS, DUP. 

G. 

ATL, DUP, G, NAC, TRC. 

ATL, DUP, G. 

TRC. 

ALT, ATL, BKS, DUP, G, NAC, TRC, VPC. 

ATL, BL, DUP, G, NAC, TRC, VPC. 

ATL, DUP, NAC. 

NAC. 

DUP. 

BKS, NAC, TRC. 

G, NAC, TRC. 

NAC. 



100 SYNTHETIC ORGANIC CHEMICALS, 1963 

TABLE 8B.--Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer , 1963 — Continued 



DIRECT DYES--Continued 

»Direot yellow dyes — Continued 

Direct Yellow 105 

Direct Yellow 106 

Direct Yellow 107 

Direct Yellow 11<* 

Direct Yellow 117 

Direct Yellow 118 

Direct Yellow 121 

Other direct yellow dyes 

«Direct orange dyes : 

»Direot Orange 1 

Direct Orange 6 

■^Direct Orange 8 

Direct Orange 10 

Direct Orange 11 

»Direct Orange 15 

»Direct Orange 26 

Direct Orange 29 

♦Direct Orange 3<» 

♦Direct Orange 37 

Direct Orange 38 

♦Direct Orange 39 

Direct Orange 40 

Direct Orange 48 

Direct Orange 55 

Direct Orange 59 

Direct Orange 61 

Direct Orange 67 

Direct Orange 70 

♦Direct Orange 72 

♦Direct Orange 73 

Direct Orange 74 

Direct Orange 76 

Direct Orange 78 

Direct Orange 79 

Direct Orange 80 

♦Direct Orange 81 

Direct Orange 83 

Direct Orange 88 

♦Direct Orange 102 

Direct Orange 105 

Direct Orange 110 

Other direct orange dyes 

♦Direct red dyes: 

♦Direct Red 1 

♦Direct Red 2 

♦Direct Red 4 

Direct Red 5 

♦Direct Red 10 

♦Direct Red 13 

♦Direct Red 16-- 

Direct Red 20 — 

♦Direct Red 23 

♦Direct Red 24-- 

♦Direct Red 26 

♦Direct Red 28- - 

♦Direct Red 31 

Direct Red 32 - — 



Manufacturers ' identification codes 
(according to list in table 22) 



TRC. 










TRC. 










G. 










ACY. 










TRC. 










TRC. 










TRC. 










AAP, 


ACY, 


ALT 


ATL, BL, 


DUP, FAB, 


AAP, 


BKS, 


NAC 


VPC. 




AAP, 


NAC. 








ATL, 


DUP, 


G, NAC, TRC. 




AAP, 


NAC. 








G. 










ACY, 


DUP, 


G, NAC, TRC. 




ATL, 


CMG, 


DUP 


G, NAC, 


TRC. 


ATL, 


BKS, 


TRC 






ACY, 


CMG, 


DUP 


G, NAC. 




ACY, 


CMG. 


DUP 


G, TRC. 




NAC. 










BKS, 


CMG, 


DUP 


G. 




DUP. 










DUP. 










DUP, 


NAC. 








G, DUP. 








TRC. 










NAC, 


VPC. 








TRC. 










ACY, 


ATL, 


BKS 


, BL, NAC 


TRC, VPC. 


DUP, 


G, NAC, 


IRC, VPC. 




DUP. 










DUP, 


NAC. 








DUP, 


VPC. 








DUP. 










DUP, 


VPC. 








DUP, 


G, NAC, 


«'C. 




G, NAC. 








DUP. 










ACY, 


DUP 


G, 


NAC. 




BKS. 










TRC. 










ALT, 


ATL, 


BL, 


DUP, VPC 





AAP, ATL, DUP, G, NAC, TRC, YAW. 

ATL, BKS, DUP, NAC, TRC. 

NAC, TRC, VPC. 

NAC. 

AAP, ACY, NAC. 

AAP, ATL, DUP, G, NAC, TRC, YAW. 

AAP, ATL, DUP, G, NAC, TRC. 

G, NAC. 

ATL, BKS, CMG, DUP, G, NAC, TRC, VPC. 

AAP, ATL, BKS, BL, FAB, NAC, TRC, VPC. 

ATL, BKS, CMG, DUP, G, NAC, TRC, VPC. 

ATL, DUP, NAC, TRC. 

ATL, DUP, G, NAC. 

DUP, NAC. 



DYES 

TABLE 8B. -- Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



101 



DIRECT DYES — Continued 

•Direct red dyes — Continued 

•Direct Red 37 

•Direct Red 39 - 

Direct Red ^6 

Direct Red 53 

Direct Red 62 

Direct Red 72 

Direct Red 73 

•Direct Red 75 

Direct Red 76 

•Direct Red 79 

•Direct Red 80 

•Direct Red 81 

•Direct Red 83 

Direct Red 8A 

Direct Red 94 

Direct Red 111 

Direct Red 117 

•Direct Red 122 

Direct Red 123 

Direct Red 127 and 127A 

Direct Red 138 

Direct Red 139 

Direct Red 148 

•Direct Red 149 

•Direct Red 152 -- 

Direct Red 153 

Direct Red 155 

Direct Red 209 -- - ■ 

Other direct red dyes 

•Direct violet dyes: 

•Direct Violet 1 

Direct Violet 7 

•Direct Violet 9 

Direct Violet 14 

Direct Violet 22 

Direct Violet 30 

Direct Violet 47 -- 

•Direct Violet 48 

Direct Violet 49 

Direct Violet 51 

Direct Violet 60 

Direct Violet 67 - 

Other direct violet dyes 

•Direct blue dyes: 

•Direct Blue 1 

•Direct Blue 2 

Direct Blue 3 

•Direct Blue 6 

•Direct Blue 8 

Direct Blue 10 

•Direct Blue 14 

•Direct Blue 15 

Direct Blue 21 

•Direct Blue 22 - 

•Direct Blue 24 

•Direct Blue 25 



Manufacturers' identification codes 
(according to list in table 22) 



AAP, ACY, ATL, G, NAC, TRC, YAW. 

ATL, G, NAC, TRC, YAW. 

ATL, TRC. 

MAC. 

TRC. 

G, TRC. 

DUP, NAC. 

ACY, CMG, DUP, G, NAC. 

G, NAC. 

CMG, TRC, VPC. 

AAP, ATL, BKS, BL, CMG, DUP, FAB, G, NAC, TRC, VPC. 

AAP, ACY, ALT, ATL, BKS, BL, CMG, DUP, G, NAC, SDH, 

TRC, VPC, YAW. 
ALT, ATL, BKS, CMG, DUP, NAC, TRC, VPC. 
G, NAC, TRC. 
NAC. 
G. 

DUP. 

CMG, DUP, G, NAC, TRC, VPC. 
G, NAC. 

DUP, NAC, TRC. 
NAC. 
VPC. 
DUP. 

AAP, DUP, G, NAC, TRC. 
CMG, DUP, NAC. 
CMG, NAC. 
G. 

TRC. 
ALT, BL, DUP. 

AAP, ATL, DUP, NAC. 

G, NAC. 

AAP, ATL, BKS, DUP, G, NAC, TRC. 

NAC. 

NAC. 

AAP. 

DUP, G. 

DUP, NAC, TRC. 

NAC. 

DUP, NAC. 

NAC. 

DUP, NAC. 

ALT. 

AAP, ACY, ATL, BKS, BL, DUP, G, NAC, TRC, VPC, YAW. 

AAP, ATL, BKS, BL, DUP, FAB, G, MAC, TRC, VPC, YAW. 

NAC. 

AAP, ACY, ATL, BL, DUP, G, NAC, TRC, YAW. 

ACY, BKS, DUP, G, NAC, TRC. 

DUP. 

ATL, DUP, NAC, TRC. 

ATL, DUP, G, MAC, TRC. 

TRC. 

ATL, CMG, DUP, MAC. 

BKS, NAC, TRC, YAW. 

DUP, G, NAC, TRC, YAW. 



102 



SYNTHETIC ORGANIC CHEMICALS. 1963 

TABLE 8B. --Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Dye 



DIRECT DYES— Continued 

•Direct blue dyes — Continued 

•Direct Blue 26 

Direct Blue 27— - 

Direct Blue 55 

Direct Blue 61 

Direct Blue 66 

•Direct Blue 67 

•Direct Blue 71 

Direct Blue 7^ 

Direct Blue 75 

•Direct Blue 76 

•Direct Blue 78- - 

Direct Blue 79 

•Direct Blue 80 

Direct Blue SA 

•Direct Blue 86 

•Direct Blue 98 

Direct Blue 99 

Direct Blue 100 

Direct Blue lOA 

•Direct Blue 120 and 120A 

•Direct Blue 126 

Direct Blue 127 

Direct Blue 130 

Direct Blue 133 

Direct Blue 136 

Direct Blue 1^3 

Direct Blue 151 

Direct Blue 180 

Direct Blue 191 

Direct Blue 199 - 

Direct Blue 238 

Other direct blue dyes 

•Direct green dyes: 

•Direct Green 1 

•Direct Green 6 

•Direct Green 8 

•Direct Green 12 

Direct Green lA 

Direct Green 15 

Direct Green 26 

Direct Green 27 

Direct Green 28- 

•Direct Green 38 

Direct Green 39 

Direct Green <il 

Direct Green 4-5 

Direct Green -47 

Other direct green dyes 

•Direct brown dyes: 

•Direct Brown 1 

•Direct Brown lA 

•Direct Brown 2 

•Direct Brown 6 

Direct Brown 11 

Direct Brown 21 

Direct Brown 25 



Manufacturers ' identification codes 
(according to list in table 22) 



ATL, DUP, G, HAC. 

DUP. 

NAC. 

YAW. 

DUP, VPC. 

DUP, NAC, TRC. 

DUP, G, NAC, TRC. 

DUP. 

TRC. 

ATL, BL, DUP, G, NAC, TRC, VPC. 

ATL, CMG, DUP, G, NAC, TRC. 

TRC. 

ALT, ATL, BKS, DUP, G, NAC, STD, TRC. 

DUP. 

AAP, ACY, ATL, BKS, CMG, DUP, FAB, G, ICC, ICI, NAC, 

TMS, TRC, VPC. 
AAP, ALT, ATL, BL, G, ICC, NAC, TRC, VPC. 



ALT, 


NAC. 






DUP. 








BKS, 


DUP, 


G, TRC. 


DUP, 


G, NAC, TRC, VPC. 


G. 








NAC. 








G. 








G. 








DUP. 








ATL, 


NAC, 


TRC. 




NAC, 


TRC. 






G. 








G. 








ACY. 








AAP, 


ALT, 


ATL, 


BL, DUP, ICI, NAC. 


AAP, 


ACY, 


ATL, 


DUP, G, NAC, TRC, YAW 


AAP, 


ATL, 


BKS, 


DUP, G, NAC, THC, YAW 


ATL, 


NAC, 


TRC, 


YAW. 


DUP, 


NAC, 


TRC. 




NAC. 








DUP. 








NAC, 


TRC. 






ATL, 


NAC, 


TRC. 




TRC. 








DUP, 


G, NAC, TRC. 


G. 








DUP 








VPC 








DUP 


G. 






ACY, 


ALT 


ATL, 


BL, DUP. 



ACY, ATL, BKS, BL, DUP, NAC. 

G, TRC, YAW. 

AAP, ACY, ATL, BKS, BL, DUP, G, NAC, TRC, YAW. 

DUP, G, NAC, TRC. 

NAC. 

DUP. 

DUP, NAC. 



DYES 



103 



TABLE SB. --Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, 7963 --Continued 



Manufacturers ' identification codes 
(aooordlng to list in table 22) 



DIRECT DYES — Continued 

»Direct brown dyes — Continued 

Direct Brown 27 

Direct Brown 29 

»Direct Brown 31 

Direct Brown 32 

Direct Brown 33 

Direct Brown 35 

Direct Brown 40 

Direct Brown 4<i 

Direct Brown A-8 

Direct Brown 59 

«Direct Brown 7<i 

"Direct Brown 95 

Direct Brown 101 

Direct Brown 105 

Direct Brown 106 

»Direct Brown 111 

Direct Brown 112 

Direct Brown 125 

"Direct Brown 15A 

Other direct brown dyes 

"Direct black dyes: 

Direct Black 3 

"Direct Black <+ 

Direct Black 8 

"Direct Black 9 

Direct Black 17 

"Direct Black 19 

"Direct Black 22-- 

Direct Black 36 

"Direct Black 37 

"Direct Black 38 

Direct Blaqk 44 

"Direct Black 51 

Direct Black 55 

Direct Black 56 

Direct Black 61 

Direct Black 67 

Direct Black 71 

Direct Black 75 

Direct Black 78 - 

•Direct Black 80 

Direct Black 109 

Direct Black 130 

Other direct black dyes 

DISPERSE DYES 

"Disperse yellow dyes : 

"Disperse Yellow 1 

Disperse Yellow 2 

"Disperse Yellow 3 

"Disperse Yellow 5 

Disperse Yellow 8 

Disperse Yellow 17 

"Disperse Yellow 23 

Disperse Yellow 31 

Disperse Yellow 32 



AAP, ATL, DUP, G, NAG, YAW. 

G. 

DUP, MAC. 

NAC. 

AAP, DUP. 

G, YAW. 

AAP. 

ACY. 

AAP, DUP, NAC. 

AAP, ALT, ATL, DUP, G, NAC, TRC, YAW. 

G. 

DUP. 

G, NAC. 

DUP, G, TRC, VPC. 

ATL, NAC. 

G. 

DUP, G, TRC, YAW. 

ALT, BL, DUP, NAC, TRC, VPC, YAW. 

DUP. 

ATL, DUP, G, NAC, TRC, YAW. 

TRC, YAW. 

ATL, DUP, G, NAC, TRC. 

G, NAC, TRC. 

ATL, BKS, G, NAC, TRC. 

ALT, ATL, BKS, CMG, DUP, G, NAC, TRC, VPC, YAW. 

AAP. 

AAP, DUP, NAC. 

AAP, ACY, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, YAW. 

TRC. 

AAP, ATL, DUP, G, NAC, TRC. 

DUP. 

NAC, TRC. 

TRC. 

DUP, NAC. 

ATL, VPC. 

G. 

BKS, DUP, NAC. 

AAP, ATL, BKS, BL, FAB, G, NAC, TRC, VPC, YAW. 

G. 

ACY. 

ACY, ALT, ATL, BL, DUP, TRC, YAW. 



DUP, G, ICC. 

DUP. 

AAP, DUP, EKT, G, HSH, ICC, NAC, SDH, STD, TRC. 

EKT, G, ICC, STD. 

DUP, TRC. 

AAP. 

DUP, EKT, G, ICC. 



DUP. 



104 



SYNTHETIC ORGANIC CHEMICALS, 1963 



--Coal-tar dyes for ivhich U.S. production or sales were reported, identified by 
manufacturer, i565 --Continued 



Pye 



Manufacturers ' identification codes 
(according to list In table 22) 



DISPERSE DYES--Continued 

»Disperse yellow dyes — Continued 

Disperse Yellow 33 

Disperse Yellow 3<i 

^Disperse Yellow 37 

Disperse Yellow ^2 

Disperse Yellow 50 

Disperse Yellow SA 

Other disperse yellow dyes 

^Disperse orange dyes: 

^Disperse Orange 3 

^Disperse Orange 5 

Disperse Orange 15 

Disperse Orange 16 

»Disperse Orange 17 

Disperse Orange 21 

Disperse Orange 25 

Disperse Orange 26 

Disperse Orange 28 

Disperse Orange 38 

Other disperse orange dyes 

•Disperse red dyes: 

•Disperse Red 1 

Disperse Red A 

•Disperse Red 5 

Disperse Red 7 

Disperse Red 9 

•Disperse Red 11 

•Disperse Red 13 

•Disperse Red 15 

•Disperse Red 17 

Disperse Red 20 

Disperse Red 21 

Disperse Red 30 

Disperse Red 31 

Disperse Red 32 

Disperse Red 55 

Disperse Red 56 

Disperse Red 59 

Disperse Red 60 

Disperse Red 61 

Disperse Red 65 

Disperse Red 66 

Other disperse red dyes 

Disperse violet dyes: 

•Disperse Violet 1 

•Disperse Violet 4 

Disperse Violet 8 

Disperse Violet 11 

Disperse Violet l-i 

Disperse Violet 17 

Disperse Violet 18 

Disperse Violet 22 

Disperse Violet 26 

Disperse Violet 27 

Other disperse violet dyes 

•Disperse blue dyes: 

•Disperse Blue 1 

•Disperse Blue 3 



AAP 

AAP 

AAP 

AAP 

AAP 

0, 

AAP 

NAC 

EKT 

EKT 

ICC 

G. 

TRC 

DUP 

DUP 

AAP 

DUP 

DUP 

AAP 

DUP 

AAP 

AAP 

G. 

EKT 

DUP 

ACY 

DUP 

G. 

DUP 

DUP 

EKT 

AAP 
AAP 



EKT, ICC. 



EKT, ICC. 
G, TRC. 



G, ICC. 
EKT, G, ICC. 



DUP, EKT, G, ICC, STD, TRC. 
EKT, G, NAC. 



EKT, G, HSH, ICC, NAC, STD. 



DUP, EKT, G, ICC. 

DUP, EKT, G, ICC, NAC, SDH, STD, TRC, YAW. 

EKT, G, HSH, ICC, SDH, STD. 

DUP. 

DUP, G, TRC. 

DUP, G, ICC. 

HSH, ICC, NAC. 

DUP, EKT, G, HSH, ICC, STD, TRC. 



DUP, VPC. 



EKT, G, ICC, TRC, VPC. 



DUP, G, ICC, STD, TRC. 
DUP, G, ICC, NAC. 



G, TRC. 

EKT, G, ICC, NAC, STD, TRC. 



DYES 



105 



TABLE 8B. ■ 



■ Coal-tar dyes foy which U.S. production or sales were reported, identified by 
manufacturer, 7 565 --Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



DISPERSE DyES--Continued 

♦Disperse blue dyes — Continued 

♦Disperse Blue 7 

Disperse Blue 8 

Disperse Blue 9 

Disperse Blue 27 

Disperse Blue 35 

Disperse Blue 41 

Disperse Blue 51 

Disperse Blue 55 

Disperse Blue 59 

Disperse Blue 60 

Disperse Blue 61 

Disperse Blue 62 

Disperse Blue 63 

♦Disperse Blue 6A 

Disperse Blue 67 

Disperse Blue 70 

Disperse Blue 71 

Other disperse blue dyes 

♦Disperse brown dyes: 

Disperse Brovm 2 

Other disperse brov/n dyes 

Disperse black dyes: 

♦Disperse Black 1 

Disperse Black 2 

Disperse Black 6 

Disperse Black 7 

♦Disperse Black 9 

Other disperse black dyes 

FIBER-REACTIVE DYES 

Reactive yellow dyes: 

Reactive Yellow 1 

Reactive Yellow 2 

Reactive Yellow 3 

Reactive Yellow <i 

Reactive Yellow 6 

Reactive Yellow 7 

Reactive Yellow 18 

Other reactive yellow dyes 

Reactive orange dyes: 

Reactive Orange 1 

Reactive Orange 2 

Reactive Orange A 

Reactive Orange 5 

Other reactive orange dyes 

Reactive red dyes: 

Reactive Red 1 

Reactive Red 2 

Reactive Red 3 

Reactive Red 4 

Reactive Red 5 

Reactive Red 8 

Reactive Red 11 

Reactive Red 13 

Reactive Red 16 

Other reactive red dyes 



G, HSH, 


ICC, 


NAC, 


TRC. 


DUP. 










G, ICC. 








EKT. 










ICI. 










MAC. 










G. 










TRC. 










DUP. 










DUP. 










DUP. 










DUP. 










DUP. 










DUP, 


G, 


TRC. 






DUP. 










VPC. 










EKT, 


G, 


ICC, 


STD, 


TRC, VPC. 


DUP. 










EKT, 


G, 


ICC, 


TRC. 





AAP, ATL, DUP, G, TRC. 

DUP, TRC. 

DUP. 

YAW. 

AAP, BL, DUP, EKT, G, KLS, NAC. 

DUP, EKT, ICC, YAW. 



ICI. 
TRC. 
TRC. 
ICI. 
TRC. 
ICI. 
ICI. 
DUP, HST, ICI. 

ICI. 
TRC. 
ICI. 
TRC. 
HST, ICI. 

ICI. 
ICI. 
ICI. 
TRC. 
ICI. 
ICI. 
ICI. 
ICI. 
TRC. 
DUP, HST, ICI. 



106 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 8B. — Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Rye 



Manufacturers ' identification codes 
(according to list in table 22) 



FIBER-REACTIVE DYES —Continued 

Reactive violet dyes: 

Reactive Violet 1 

Reactive Violet 2 

Other reactive violet dyes 

Reactive blue dyes: 

Reactive Blue 1 

Reactive Blue 2 

Reactive Blue 3 

Reactive Blue 4 

Reactive Blue 5 

Reactive Blue 7 

Reactive Blue 9 

Other reactive blue dyes 

Reactive green dyes 

Reactive brown dye: Reactive Brown 1 

Reactive black dyes: 

Reactive Black 1 

Other reactive black dyes 

FLUORESCENT BRIGHTENING AGENTS 

Fluorescent Brightening Agent 1 

Fluorescent Brightening Agent <* 

Fluorescent Brightening Agent 6 

Fluorescent Brightening Agent 8 

Fluorescent Brightening Agent 9 

Fluorescent Brightening Agent 22 

Fluorescent Brightening Agent 24 

Fluorescent Brightening Agent 25 

Fluorescent Brightening Agent 28 

Fluorescent Brightening Agent 30 

Fluorescent Brightening Agent 33 

Fluorescent Brightening Agent 34 

Fluorescent Brightening Agent 37 

Fluorescent Brightening Agent 45 

Fluorescent Brightening Agent 46 

Fluorescent Brightening Agent 49 

Fluorescent Brightening Agent 52 

Fluorescent Brightening Agent 54 

Fluorescent Brightening Agent 61 

Fluorescent Brightening Agent 66 

Fluorescent Brightening Agent 68 

Fluorescent Brightening Agent 71 

Fluorescent Brightening Agent 72 

Flxiorescent Brightening Agent 75 

Fluorescent Brightening Agent 101 

Fluorescent Brightening Agent 102 

Fluorescent Brightening Agent 109 

Fluorescent Brightening Agent 113 

Fluorescent Brightening Agent 114 

Fluorescent Brightening Agent 125 

Fluorescent Brightening Agent 134 

Fluorescent Brightening Agent 135 

Fluorescent Brightening Agent 136 

Fluorescent Brightening Agent 139 

Other fluorescent brightening agents 



ICI. 
TRC. 

HST. 

ICI. 

TRC. 

ICI. 

ICI. 

TRC. 

TRC. 

ICI. 

DUP, HST. 

HST. 

TRC. 

TRC. 
HST, ICI. 



GGY. 
ACY. 
ACY. 
ACY. 
ACY, 
GGY. 
GGY. 



FBC, G, TRC. 



G, SDH. 



ACY, FBC, DUP. 



DUP. 

TRC. 

TRC. 

GGY. 

S. 

S. 

GGY. 

ACY. 

SDH. 

CCW, 

ACY, 

GGY. 

G. 

GGY. 

DUP. 

G. 

VPC. 

VPC. 

ACY. 

TRC. 

TRC. 

TRC. 

TRC. 

ACY, 



CCW, DUP, FBC, G, GGY, S, TRC, VPC. 



DYES 

TABLE 8B.— Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 965 --Continued 



107 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



FOOD, DRUG, AND COSMETIC COLORS 



Food. Drag, mdCo 



■Dye 



»FD&C Blue No. 1 

FD&C Blue No. 2 

FD&C Green No. 1 

FD&C Green No. 2 

FD&C Green No. 3 

»FD&C Red No. 2-— - - 

»FD&C Red No. 3- - 

»FD&C Red No. ^ 

FDtC Violet No. 1 

FD&C Yellow No. 3 

»FD&C Yellow No. 5 

»FD&C Yellow No. 6 

Other food, drug, and cosmetic dyes 

Drug and Cosmetic Dyi 

D&C Black No. 1 

DScC Blue No. A-- --- 

D&C Blue No. 6 

D&C Blue No. 7 

D&C Blue No. 9- 

D&C Brown No. 1 

D&C Green No. 5 

D&C Green No. 6 

D&C Green No. 8 

D&C Orange No. 3 

D&C Orange No. ^ 

D&C Orange No. 5 

D&C Orange No. 10 

D&C Orange No. 17 

D&C Red No. 2 - 

D&C Red No. 3— - - 

D&C Red No. 6- — 

»D&C Red No. 7 

»D&C Red No. 8 

D&C Red No. 9 

D&C Red No. 10 

D&C Red No. 11 — 

D&C Red No. 12 - ■ 

D&C Red No. 13 

D&C Red No. 17 

»D&C Red No. 19 - — 

»D&C Red No. 21 - 

D&C Red No. 22 - — 

D&C Red No. 27 - 

D&C Red No. 28 - 

D&C Red No. 30 ■ 

D&C Red No. 31 ■ 

D&C Red No. 33 

D&C Red No. 34 ■ 

D&C Red No. 36 - ■ 

D&C Red -No. 37 - ■ 

D&C Red No. 39— - - ■ 

D&C Violet No. 2 

D&C Yellow No. 5 

D&C Yellow No. 6— 



BAT, 
BAT, 
NAC, 
BAT, 
BAT, 
BAT, 
BAT, 
BAT, 
NAC, 
SDH. 
BAT, 
BAT, 
KON, 



KON, NAC, SDH, WJ. 

KON, NAC, SDH. 

WJ. 

NAC, WJ. 

WJ. 

KON, NAC, SDH, STG, WJ. 

KON, NAC, SDH, STG. 

KON, NAC, SDH, STG, WJ. 

SDH. 

KON, NAC, SDH, STG, WJ. 
KON, NAC, SDH, STG, WJ. 



KON, 
NAC. 
KON, 
KON. 
NAC. 
NAC. 
KON, 
KON, 
KON, 
KON. 
NAC, 
KON, 
TMS. 
KON, 
KON. 
KON, 
SNA, 
KON, 
KON, 
KON, 
KON, 
KON, 
SNA, 
SNA, 
KON, 
KON, 
KON, 
KON. 
TMS. 
NAC. 
KON. 
KON. 
KON, 
TMS. 
KON, 
NAC. 
SDH. 
NAC. 
KON, 
KON. 



NAC, YAW. 
NAC. 



NAC. 
NAC. 
SDH. 

SNA. 
SNA, TMS. 

SNA. 

BE. 
TMS. 

SNA, TMS. 
SNA, TMS. 
SNA, TMS. 
SNA. 
SNA. 
TMS. 
TMS. 
NAC. 

SNA, TMS. 
SNA, TMS. 



NAC. 

Be. 



SNA, TMS. 



108 SYNTHETIC ORGANIC CHEMICALS, 1963 

TABLE SB. --Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, iS63 --Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



FOOD, DRUG, AND COSMETIC COLORS— Continued 



Dn 



nd Cos 



■ Dyes— Continued 



D&C Yellow No. 7 

D&C Yellow No. 8 - 

D&C Yellow No. 10 

D&C Yellow No. 11 

Druf and Cosmetic Dyes, External 

Ext. D&C Blue No. 1 - 

Ext. D&C Green No. 1 

Ext. D&C Orange No. 3 

Ext. DStC Orange No. <1 

Ext. D&C Red No. 15 

Ext. D&C Violet No. 2 

Ext. D&C Yellow No. 1 

Ext. D&C Yellow No. 3 

Ext. D&C Yellow No. 5 - 

Ext. D&C Yellow No. 7 - 

INGRAIN DYES 

Ingrain blue dyes: 

Ingrain Blue 1 

Ingrain Blue 2 

Ingrain Blue 3 

Ingrain Blue 4 

Ingrain Blue 8 

Ingrain green dye: Ingrain Green 2 

MORDANT DYES 

■»Mordant yellow dyes : 

»Mordant Yellow 1 

Mordant Yellow 3 

Mordant Yellow 5 

«Mordant Yellow 8 

Mordant Yellow 10 

Mordant Yellow 14 

Mordant Yellow 16 

Mordant Yellow 20 

Mordant Yellow 26 

Mordant Yellow 29 

Mordant Yellow 30 

Mordant Yellow 36 

♦Mordant orange dyes: 

»Mordant Orange 1 

Mordant Orange 3 

Mordant Orange A- 

Mordant Orange 6 

Mordant Orange 8 

Mordant Orange 30 

*Mordant red dyes: 

Mordant Red 3 

Mordant Red 5 

Mordant Red 6 

»Mordant Red 7 

Mordant Red 9 



TMS. 

NAC, TMS. 
KON, NAC. 
NAC. 



NAC. 

NAC. 

KON, NAC. 

NAC. 

KON. 

KON. 

KON, NAC. 

KON. 

KON. 

KON. 



ICI. 
VPC. 
ICI. 
ICI. 
ICI. 
ICI. 



G, PDC, TRC. 


ATL, 


NAC. 


DUP, 


NAC, TRC. 


DUP, 


G, NAC, VPC 


DUP. 




NAC, 


TRC. 


ACY, 


NAC. 


NAC. 




NAC, 


VPC. 


G. 




TRC. 




PDC. 





AAP, ACY, G, PDC, TRC. 

VPC. 

G. 

ATL, G, TRC. 

NAC, TRC. 

NAC. 

ACY, ICI, NAC. 

NAC. 

G. 

ACY, CMG, G, NAC, TRC, VPC. 

G, MRX, NAC. 



DYES 



109 



-Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



MORDANT DYES— Continued 

»Mordant red dyes — Continued 

Mordant Red 11- 

Mordant Red 19 

Mordant Red 36 

Mordant Red 59 

Mordant Red 6<i 

Mordant violet dyes: 

Mordant Violet 5 

Mordant Violet 11 

Mordant Violet 20 

»Mordant blue dyes: 

»Mordant Blue 1 

Mordant Blue 3 

Mordant Blue 7 

Mordant Blue 9 

Mordant Blue 13 

Mordant green dyes: 

Mordant Green 9 

Mordant Green 11 

Mordant Green 36 

Mordant Green ■47 

♦Mordant brown dyes: 

»Mordant Brown 1 

Mordant Brown 12 

Mordant Brown 13 

Mordant Brown 15 

Mordant Brown 17 

Mordant Brown 18 

♦Mordant Brown 19 

Mordant Brown 21 

Mordant Brown 33 

*Mordant Brown "iO 

Mordant Brown 43 

Mordant Brown 50 

Mordant Brown 63 

Mordant Brown 70 

♦Mordant black dyes : 

Mordant Black 1 

♦Mordant Black 3 

♦Mordant Black 5 

Mordant Black 7 

Mordant Black 8 

Mordant Black 9- 

♦Mordant Black 11 

♦Mordant Black 13 

Mordant Black 16 

♦Mordant Black 17 

Mordant Black 19 

Mordant Black 26 

♦Mordant Black 38 

OXIDATION BASES 

Oxidation Base 8 and 8A 

Oxidation Base 22 

Oxidation Base 25 

Other oxidation beises 



ACY, NAC. 

NAC. 

TRC. 

TRC. 
PDC. 

NAC, PDC. 



AAP, DUP, G, NAC, TRC. 

G. 

NAC, TRC. 

G, NAC. 

HSH, NAC. 

NAC. 
ACY. 

PDC, TRC. 
NAC. 

CMG, DUP, G, NAC, TRC, YAW. 

PDC. 

NAC. 

G. 

CMG, G. 

DUP, NAC. 

G, NAC, TRC. 

G, VPC. 

DUP, NAC, TRC. 

CMG, DUP, G, NAC, PDC, TRC, VPC. 

G. 

TRC. 

TRC. 

DUP, PDC. 

G, NAC. 

G, NAC, TRC. 

G, NAC, TRC. 

G. 

VPC. 

NAC, VPC. 

G, NAC, TRC, VPC. 

G, HSH, -ICI, NAC, TRC. 

NAC. 

ACY, DUP, G, NAC, TRC. 

PDC. 

TRC. 

CMG, DUP, G, NAC, TRC, VPC. 



ACY. 
ACY. 
ACY. 
ACY. 



110 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 8B. — Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Dye 



Manufacturers ' identification codes 
(according to list in table 22) 



SOLVENT DYES 

•Solvent yellow dyes: 

Solvent Yellow 1 

•Solvent Yellow 2-- - 

"Solvent Yellow 3 

Solvent Yellow 13 

•Solvent Yellow 14- 

Solvent Yellow 16- 

Solvent Yellow 19 

Solvent Yellow 29- - -- 

Solvent Yellow 33--- 

Solvent Yellow 3'4 

Solvent Yellow 40- 

Solvent Yellow 42 

Solvent Yellow 43- - - 

Solvent Yellow 44 

Solvent Yellow 45 

•Solvent Yellow 47 

Solvent Yellow 53 - 

Solvent Yellow 56 

Solvent Yellow 66 

Solvent Yellow 71 

Solvent Yellow 72 

Other solvent yellow dyes 

•Solvent orange dyes: 

Solvent Orange 2 

•Solvent Orange 3 

Solvent Orange 4 

Solvent Orange 5 

•Solvent Orange 7 

•Solvent Orange 20 

Solvent Orange 23 

Solvent Orange 24 

Solvent Orange 25 

Solvent Orange 31 

Solvent Orange 48 

Other solvent orange dyes 

Solvent red dyes: 

Solvent Red 8 

Solvent Red 22- 

Solvent Red 24 

•Solvent Red 26- 

Solvent Red 27 

Solvent Red 33 

Solvent Red 34- - - 

Solvent Red 35 

Solvent Red 40- 

•Solvent Red 49 

Solvent Red 52-- - 

Solvent Red 63- 

Solvent Red 65 

Solvent Red 68 

Solvent Red 69 

Solvent Red 74 

Solvent Red 76 

Solvent Red 80 - 

Solvent Red 105 

Solvent Red 111 

Other solvent red dyes 



ACY. 






AAP, 


DUP, 


G, PAT. 


AAP, 


DUP, 


G, NAC, SDH. 


ACY, 


G, TRC. 


AAP, 


ACY, 


DUP, FH, G, NAC, PAT, SDH 


PAT. 






G. 






G, NAC. 




ACY, 


NAC. 




DUP. 






NAC. 






NAC. 






0, NAC. 




G, NAC. 




DUP, 


NAC. 




ACY, 


DUP, 


G, NAC. 


NAC. 






ACY. 






NAC. 






ACY. 






ACY. 






AAP, 


nsc. 


DUP, FH. 


AAP, 


PAT. 




ACY, 


DSC, 


G, NAC. 


PAT. 






G, TRC. 




ACY, 


G, NAC. 


ACY, 


G, NAC. 


NAC. 






DUP. 






ACY, 


DUP. 




NAC. 






ACY. 






AAP, 


ACY, 


DSC, DUP. 


G. 






G. 






ACY, 


DUP, 


FH, G, NAC, PAT, SDH. 


AAP, 


ACY, 


NAC. 


NAC. 






DUP. 






DUP. 






G. 






G. 






ACY, 


DUP, 


G. 


G, ICI. 




NAC. 






NAC. 






NAC. 






DUP. 






NAC. 






NAC. 
ACY, 


NAC. 




ACY. 






AAP, 


ACY, 


DSC, DUP, FH, PAT. 



DYES 



TABLE SB. — Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Pye 



Manufacturers' identification codes 
(according to list in table 22) 



SOLVENT DYES— Continued 

»Solvent violet dyes: 

Solvent Violet 7 

•Solvent Violet 8 

Solvent Violet 9 

Solvent Violet 13 

Solvent Violet 14.- - 

Solvent Violet 17 - 

Other solvent violet dyes 

•Solvent blue dyes : 

Solvent Blue 3 

Solvent Blue A 

Solvent Blue 5 

Solvent Blue 7 

Solvent Blue 9 

Solvent Blue 11 

Solvent Blue 12 

Solvent Blue 16 

Solvent Blue 30 

Solvent Bliie 31 

Solvent Blue 33 

Solvent Blue 36 

Solvent Blue 37 

•Solvent Blue 38 

Solvent Blue 39--- -- 

Solvent Blue ^i 

Solvent Blue 58 

Solvent Blue 59 - 

Solvent Blue 60 

Other solvent blue dyes 

•Solvent green dyes: 

Solvent Green 1 

Solvent Green 2 

•Solvent Green 3 

Solvent Green 10 

Solvent Green 11 

Other solvent green dyes 

•Solvent brown dyes : 

Solvent Brown 11 

Solvent Brown 12 

Solvent Brown 17 

Solvent Brown 19 

Solvent Brown 20 

Solvent Brown 21 

Solvent Brown 38 

Other solvent brown dyes 

Solvent black dyes: 

Solvent Black 3 

Solvent Black 5 

Solvent Black 7 

Solvent Black 12 

Solvent Black 13-- 

Solvent Black 17 

Solvent Black 19 

Solvent Black 20 

Solvent Black 26 

Other solvent black dyes 



MAC. 






ACY, 


DSC, 


NAC. 


DSC. 






AAP, 


HSH. 




ICI. 






MAC. 






DSC, 


PAT. 




ACY. 






DSC, 


DUP, 


G, SDH. 


DSC. 






ACY, 


NAC. 




G. 






G, ICI. 




DUP, 


NAC. 




NAC. 






MAC. 






NAC. 






G. 






DUP, 


NAC. 




DUP. 






ACY, 


CMG, 


DUP, NAC. 


NAC. 






NAC. 






ACY. 






ACY. 






ACY. 






AAP, 


DSC, 


G, ICI, PAT, SDH, SW. 


ACY, 


SDH. 




G. 






AAP, 


ACY, 


CMG, G, HSH, ICI, NAC 


DUP. 






DUP. 






DSC, 


NAC. 




G. 






ACY, 


DSC, 


G. 


DUP. 






DUP. 






ACY, 


DUP. 




NAC. 






ACY. 






DSC, 


FH, 


G. 


NAC. 






ACY, 


NAC. 




ACY, 


NAC. 




NAC. 






NAC. 






DUP. 






G 






NAC. 






ACY. 






DSC, 


FH. 





SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 8B. 



-Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer . 1963 — Continued 



Dye 



Manufacturers ' identification codes 
(according to list in table 22) 



SULFUR DYES 

Sulfur yellow dyes: 

Sulfur Yellow 2 

Leuco Sulfur Yellow 2 

Solubilized Sulfur Yellow 2 

Sulfur Yellow A 

Other sulfur yellow dyes 

Sulfur orange dye: Sulfur Orange 1-- 

Sulfiir red dyes: 

Sulfur Red 1 

Leuco Sulfur Red 1 

Sulfur Red 6 

Sulfiir Red 8 

Sulfxir blue dyes: 

Sulfur Blue 5 

Sulfur Blue 7 

Leuco Sulfur Blue 7 

Solubilized Sulfur Blue 7 

Sulfur Blue 9 

Leuco Sulfur Blue 9 

Sulfur Blue 11 

Sulfur Blue 13 

Solubilized Sulfur Blue 13 

Sulfur Blue 15 

Other sulfur blue dyes 

Sulfur green dyes: 

Sulfur Green 1 

Leuco Sulfur Green 1 

Sulfur Green 2 

Leuco Sulfur Green 2 

Solubilized Siilfur Green 2 

Sulfur Green 3 

Sulfur Green 11 

Sulfur Green lA 

Other sulfur green dyes 

Sulfur brown dyes: 

Sulfur Brown 3 

Leuco Sulfur Brown 3 

Sulfur Brown 10 

Leuco Sulfur Brown 10 

Solubilized Sulfur Brown 10 

Sulfur Brown l-C 

Solubilized Sulfur Brown 14 

Sulfur Brown 20 

Sulfur Brown 26 

Sulfur Brown 30 

Sxilfur Brown 33 

Sulfur Brown 37 

Leuco Sulfur Brown 37 

Sulfur Brown 39 

Sulfur Brown 40 

Sulfur Brown 43 

Leuco Sulfur Brown 43 

Sulfur Brown 44 

Leuco Sulfur Brown 44 

Sulfur Brown 45 

Sulfur Brown 50 

Sulfur Brown 76 

Other sulfur brown dyes 



NAG. 

NAG. 

AGY. 

DUP, SDC. 

AGY. 

SDG. 

AGY, NAG. 

NAG. 

AGY, DUP, NAG. 

DUP. 

ACY. 

AGY, DUP, NAG, SDC. 

MAC, SDC. 

AGY. 

AGY, NAG. 

NAG. 

DUP, HAG. 

ACY. 

ACY. 

ACY, DUP, NAG. 

SDG. 

MAC. 

NAC. 

DUP, NAC, SDC. 

SDC. 

SDH. 

NAC. 

DUP. 

DUP. 

AUG. 

SDC. 

SDC. 

DUP, NAC, SDC. 

NAC, SDC. 

AUG. 

ACY. 

ACY. 

DUP. 

DUP. 

AGY. 

ACY. 

SDC. 

SDC. 

DUP. 

DUP. 

NAC. 

NAG. 

NAC. 

NAC. 

NAC. 

NAC. 

ACY. 

ACY, NAG. 



DYES 



113 



TABLE 8B. 



■ Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Dye 



Manufacturers ' identification codes 
(according to list in table 22) 



SULFUR DYES--Continued 

Sulfur black dyes: 

Sulfur Black 1 

Leuco Sulfur Black 1 

Solubilized Sulfur Black 1 

Sulfur Black 2 

Leuco Sulfur Black 2 

Solubilized Sulfur Black 2 

Sulfur Black 6 

Leuco Sulfur Black 6 

Sulfur Black 10 

Leuco Sulfur Black 10 

Solubilized Sulfur Black 10 

Sulfur Black 11 

Leuco Sulfur Black 11 

VAT DYES 

»Vat yellow dyes: 

Vat Yellow 1, 12-V25t 

»Vat Yellow 2, 8-1/2^ 

Solubilized Vat Yellow 2, 255t 

Vat Yellow 3, 12-l/2?t 

•Vat Yellow A, 12-l/2^S 

Solubilized Vat Yellow A, 37-1/2^6 

Vat Yellow 10, lO^t 

Vat Yellow 13, 6-1/25^ 

Vat Yellow 14, 12-V2^t 

Vat Yellow 15, ll-l/25t 

Vat Yellow 16, 16-2/3^ 

Vat Yellow 21, 9-l/25t- 

Vat Yellow 22, lO^t 

Vat Yellow 27 

Vat Yellow 33 ■ 

Vat Yellow 41, 9^-- 

Other vat yellow dyes 

»Vat orange dyes: 

»Vat Orange 1, 20^6 

•Solubilized Vat Orange 1, 26$ 

•Vat Orange 2, 12^6 

Vat Orange 3, 13-1/2% — 

•Vat Orange 4, 6$ 

•Vat Orange 5, lO^t 

•Solubilized Vat Orange 5, 305t 

•Vat Orange 7, ll^t 

•Vat Orange 9, 12!t 

Vat Orange 11, 6$ 

•Vat Orange 15, lOjt- — 

Vat Orange 16 

Vat Orange 23, 17-l/2?t — — 

Vat Orange 24 

Other vat orange dyes 

•Vat red dyes: 

•Vat Red 1, 13^t — -- 

•Solubilized Vat Red 1, 37^6 

Vat Red 10, 18^— 

Solubilized Vat Red 10, 31^t 

Vat Red 12, 8-l/25t- 

•Vat Red 13, lljt— 



ACY, DUP, 


NAC, 


SDC 


NAC, SDC. 






ACY. 






DUP, NAC. 






NAC, SDC. 






ACY. 






G. 






NAC. 






ACY, DUP. 






NAC. 






ACY. 






G, SDC. 






SDC. 







NAC. 

AAP, ATL, DUP, G, HST, ICI, NAC, TRC, VPC. 

G, ICI. 

DUP. 

AAP, ATL, CMG, G, HST, ICI, TRC, VPC. 

G, HST. 

G. 

ICI. 

TRC. 

ACY. 

DUP. 

ATL, DUP. 

DUP, G. 

VPC. 

ICI, TRC. 

ACY. 

MAY, NAC, VPC. 

CMG, G, HST, ICI, NAC, TRC, VPC. 

G, HST, ICI. 

AAP, ACY, CMG, DUP, G, ICI, NAC, TRC. 

AAP, CMG, DUP, G. 

ACY, CMG, DUP. 

AAP, ACY, DUP, HST, NAC. 

G, HST, ICI. 

G, HST, TRC. 

AAP, ACY, CMG, DUP, G, ICI, MAC, TRC. 

DUP, NAC. 

AAP, ACY, G, ICI, NAC, TRC, VPC. 

NAC. 

ACY, DUP. 

DUP. 

DUP, G, NAC, SDC. 

AAP, ACY, DUP, HST. 

G, HST, ICI. 

G, NAC, TRC. 

G, NAC. 

DUP. 

DUP, G, NAC, TRC. 



TABLE 8B. 



SYNTHETIC ORGANIC CHEMICALS, 1963 

. Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Dye 



VAT DYES — Continued 

»Vat red dyes — Continued 

Vat Red U, Wf, 

»Vat Red 15, 10?t 

Vat Red 16, Hi - 

Vat Red 17, 105^ 

Vat Red 29, 18^ 

»Vat Red 32, 20% -- 

Vat Red 35, 12-1/2^ -- — 

Vat Red <;i, 20!t- 

Vat Red -Vi, 17<fr- — 

Vat Red 52, 10^6 

Vat Red 53, 12^- 

Vat Red 56 

Vat Red 62- — - - 

Other vat red dyes 

»Vat violet dyes: 

»Vat Violet 1, ll^t 

Solubilized Vat Violet 1, 26^- — - 

»Vat Violet 2, 20^ 

Vat Violet 3, 15^t 

Solutilized Vat Violet 3, ^3% 

»Vat Violet 9, 12^t 

Vat Violet 12, lOjt— - 

»Vat Violet 13, 6-1/^^t 

Vat Violet U, 12-1/2^ — 

»Vat Violet 17, 12-1/25^ 

Other vat violet dyes 

»Vat blue dyes : 

Vat Blue 1, 205t— --- 

Solubilized Vat Blue 1, 25% 

Vat Blue 3, 16^6 

»Vat Blue 4, lO^t 

■»Vat Blue 5, 16^6 

Solubilized Vat Blue 5, 38?t 

»Vat Blue 6, 8-l/3?( 

»Solubilized Vat Blue 6, 17-l/2^t 

Vat Blue 7, 12-1/2^6 

Solubilized Vat Blue 9, 3i% 

Vat Blue 12, 6-1/2^ - 

»Vat Blue U, 8-l/35t— - — - 

Vat Blue 16, 16^6 

■»Vat Blue 18, 13^t --- 

»Vat Blue 20, Ui - 

Vat Blue 29 

Vat Blue 39, 12^6 

Vat Blue -43 

Vat Blue 53 

Vat Blue 60 

Vat Blue 61, 16^6 

Other vat blue dyes 

»Vat green dyes: 

•Vat Green 1, 656 

Solubilized Vat Green 1, I2-I/256 

»Vat Green 3, lO^t 

♦Solubilized Vat Green 3, 26'jt 

»Vat Green 8, 8-I/256 

•Vat Green 9, 12-1/2^6 - - 

Vat Green 15, IVjt- 



Manufacturers ' identification codes 
(according to list in table 22) 



G, HST. 

G, HST, TRC. 

DUP. 

G. 

G, MAC. 

DUP, G, NAC. 

MAC, TRC. 

HST. 

TRC. 

DUP. 

DUP. 

ACY. 

DUP. 

DUP, G. 

ACY, DUP, G, ICI, MAY, NAC, TRC. 

G, ICI. 

ACY, G, HST, NAC, VPC. 

G, HST, NAC. 

G. 

DUP, G, ICI, MAY, NAC, TRC. 

DUP. 

ACY, CMG, DUP, G, ICI, NAC, TRC. 

DUP, NAC. 

DUP, G, NAC. 

NAC. 

DUP, NAC. 

G. 

HST. 

ACY, DUP, G. 

ATL, DUP, HST, NAC, VPC. 

G, HST. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC, VPC. 

G, HST, ICI. 

NAC. 

G. 

DUP. 

DUP, G, NAC, TRC. 

ACY, DUP, NAC. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC. 

AAP, ACY, ATL, DUP, G, ICI, MAY, NAC, TRC. 

G. 

G. 

SDC. 

G. 

DUP. 

DUP. 

G, MAY, SDC, X. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC. 

G, HST, ICI. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC. 

G, HST, ICI. 

DUP, G, ICI, NAC. 

ACY, DUP, G, MAY, NAC, SDC, TRC. 

NAC. 



DYES 



115 



■Coal-tar dyes for which U.S. production or sales were reported, identified by 
manufacturer, 7965— Continued 



Dye 



VAT DYES— Continued 

»Vat green dyes — Continued 

Vat Green 18, 8i — 

Vat Green 19, 135t 

Vat Green 20, 6%- 

Other vat green dyes 

»Vat brown dyes: 

»Vat Brown 1, ll^t 

Solubilized Vat Brown 1, 175t 

»Vat Brown 3, ll^t 

»Vat Brown 5, 13% 

Solubilized Vat Brown 5, 17^t 

Vat Brown 6, 17-l/2?t 

Vat Brown 11, 12?t 

Vat Brown 12, 12-V2^ -- 

Vat Brown 13, IVjt- - 

Vat Brown 14, 12^6 

Vat Brown 20, 10-1/25^ - 

Vat Brown 25, 11-1/2^6 

Vat Brown 29, 13ifr- - 

Vat Brown 31, 2856- - 

Vat Brown 38, 20% 

Vat Brown 40, 1A% — - -. 

Vat Brown 51 

Vat Brown 57 

Other vat brown dyes 

»Vat black dyes: 

Vat Black 1 - 

Solubilized Vat Black 1, Z7-l/2i 

»Vat Black 9, 16^ -. 

Vat Black 11, 17-l/25t— 

Vat Black 13, U^t - 

Vat Black 14, ll-l/2?t ■ 

Vat Black 18, 15-l/25t- - 

Vat Black 21, 18-1/2^- 

Vat Black 22, 19^ - 

»Vat Black 25, 12-V25( - ■ 

Vat Black 26, 245t— - 

»Vat Black 27, 12-l/25t 

Vat Black 34, 16^— 

Vat Black 38 - 

Other vat black dyes 

All other dyes 



Manxifacturers ' Identification codes 
(according to list in table 22) 



DUP. 
DUP. 
DUP. 
ACY, G, MAY, SDC, VPC. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC. 

G, ICI. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC, VPC. 

AAP, ACY, G, HST, NAC, VPC. 

G. 

TRC. 

MAY, TRC. 

DUP, NAC. 

MAY. 

HST. 

DUP, G, NAC. 

G. 

ACY. 

AAP. 

ICI. 

DUP. 

DUP. 

TRC. 

DUP, G, MAY, NAC, SDC, VPC. 



G, HST, ICI. 

G, NAC, TRC. 

ACY. 

DUP, NAC. 

DUP. 

G, NAC. 

ACY. 

ACY, TRC. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC. 

NAC. 

AAP, ACY, CMG, DUP, G, ICI, MAY, NAC, TRC, VPC. 

ICI. 

G. 

ACY, DUP, G, MAY, NAC, SDC, TRC, VPC. 

PAT, WM. 



116 



SYNTHETIC ORGANIC CHEMICALS, 1963 



Synthetic Organic Pigments 

TABLE MB. --Synthetic organic pigments for which U.S. production or sales were reported, identified 

by manufacturer, 1963 

[ Synthetic organic pigments for which separate statistics are given in table llA are marked below with an asterisk 
( *) ; products not so marked do not appear in table llA because the reported data are accepted in confidence and 
may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies 
that the manufacturer did not consent to his identification with the designated product ] 



Synthetic organic pigment 



Manufacturers' identification codes 
(according to list in table 22) 



TONERS 

»Yellow toners : 
*Hansa yellows : 

*Pigment Yellow 1, C.I. 11 680 

»Pigment Yellow 3, C.I. 11 710 

Pigment Yellow 4, C.I. 11 665 

Pigment Yellow 5, C.I. 11 660 

Pigment Yellow 6, C.I. 11 670 

Pigment Yellow 9, C.I. 11 720 

Pigment Yellow -19, C.I. 11 765— -- 

Pigment Yellow 60 '■ 

Pigment Yellow 73 — - 

Pigment Yellow 7'i 

All other Hansa yellows 

♦Benzidine yellows : 

♦Pigment Yellow 12, C.I. 21 090 - 

♦Pigment Yellow 13, C.I. 21 100 - - ■ 

♦Pigment Yellow 14, C.I. 21 095 - ■ 

♦Pigment Yellow 17, C.I. 21 105 ■ 

Pigment Yellow 65 

Pigment Yellow 83 

All other benzidine yellows 

Pigment Yellow 18, C.I. 49 005 - ■ 

(Basic Yellow 2), C.I. 41 000, fugitive- - • 

(Vat Yellow 1 ), C.I. 70 600 

(Vat Yellow 20), C.I. 68 420 — 

All other 

♦Orange toners : 

Pigment Orange 1, C.I. 11 725 

♦Pigment Orange 2, C.I. 12 060 

♦Pigment Orange 5, C.I. 12 075 

Pigment Orange 9 

♦Pigment Orange 13, C.I. 21 110- • 

Pigment Orange 15, C.I. 21 130 

♦Pigment Orange 16, C.I. 21 160 

Pigment Orange 30 

(Vat Orange 2), C.I. 59 705- • 

(Vat Orange 3), C.I. 59 300- 

(Vat Orange 4), C.I. 59 710 

(Vat Orange 7), C.I. 71 105 • 

(Vat Orange 15), C.I. 69 025- ■ 

All other 

♦Red toners : 
♦Naphthol reds : 

♦Pigment Red 2, C.I. 12 310 

♦Pigment Red 5, C.I. 12 490 

Pigment Red 7, C.I. 12 420 

Pigment Red 9, C.I. 12 460— 

Pigment Red 10, C.I. 12 440— - - ■ 

♦Pigment Red 13, C.I. 12 395— - • 

See note at end of table for definition of abbreviations 



ACY, AMS, DUP, EAK, FCL, G, HAH, HCC, HSH, ICI, IMP, 

KON, PPG, S, SDH, SNA, SUC, SW. 
HAH, HCC, HST, IMP, KCW, KON, PPG, S, SW. 
HAR, HSH, SNA. 
IMP. 

CIK, IMP. 
SNA. 
ICI. 
SW. 
SW. 

DUP, SW. 
DUP, HCC, IMP, KCW, SDH, SNA, WDC. 

ACY, AMS, DUP, FCL, G, HAR, HCC, HSH, .ICC, IMP, KON, 

LVY, MRX, S, SDH, SNA, SUC, SW, WDC. 

FCL, G, HAR, HST, ICC, IMP, RCM, SNA, SW. 

ACY, AMS, DUP, FCL, G, HAR, HCC, HST, ICC, IMP, KON, 

MRX, ROM, S, SDH, SNA, SW, x. 

ACY, AMS, HST, ICC, IMP, SDH, SNA, SW. 
SW. 
HST. 

HST, ICC, IMP, SW. 
IMP. 

MHX, S. 

HAH, THC. 
HAH. 

ACY, ICC, S, SW. 

HAR, KCW, SNA. 

FCL, IMP, SDH, SUC, SW. 

ACY, EAK, HSH, IMP, SNA, SUC, SW. 

DUP. 

ACY, AMS, G, HAR, IMP, KON, S, SW. 

G, HAR. 

DUP, G, HAH, HST, ICC, IMP, RCM, SDH, SNA, SW. 

SW. 

G. 

HAH, TRC. 

HAR. 

G. 

HAR. 

ICC, KON, SDH, SNA. 



EAK, G, HAR, HCC, IMP, KCW, KON, S, SDH, SW. 

DUP, G, HAR, ICC, ICI, IMP, ROM, S, SDH, SNA, SW. 

ICI, S. 

IMP. 

KCW. 

HAR, IMP, KCW, SW. 



SYNTHETIC ORGANIC PIGMENTS 



117 



TABLE IIB. — Synthetic organic pigments for which U.S. production or sales were reported, identified 
by manufacturer, 7 565- -Continued 



Synthetic organic pigment 



Manufacturers' identification codes 
(according to list in table 22) 



TONERS— Continued 

*Red toners — Continued 
*Naphthol reds — Continued 

Pigment Red 14, C.I. 12 380 

Pigment Red 15, C.I. 12 465 

♦Pigment Red 17, C.I. 12 390 

♦Pigment Red 18, C.I. 12 35C — 

Pigment Red 19, C.I. 12 400 

♦Pigment Red 22, C.I. 12 315— 

♦Pigment Red 23, C.I. 12 355 - 

♦Pigment Red 31, C.I. 12 360 

All other naphthol reds 

♦Pigment Red 1, C.I. 12 070, dark 

♦Pigment Red 1, C.I. 12 070, light 

♦Pigment Red 3, C.I. 12 120 

♦Pigment Red 4, C.I. 12 085- 

Pigment Red 6, C.I. 12 090 

♦Pigment Red 38, C.I. 21 120 

Pigment Red 40, C.I. 12 170 

Pigment Red 41, C.I. 21 200 

♦Pigment Red 48, C.I. 15 865— 

Pigment Red 49, C.I. 15 630: 
♦Barium toner 

♦Calcium toner 

♦Sodium toner 

All other Pigment Red 49 toners 

♦Pigment Red 52, C.I. 15 860— - 

Pigment Red 53, C.I. 15 585: 
♦Barium toner 

Sodium toner 

♦Pigment Red 54, C.I. 14 830, calcium toner 

Pigment Red 55, C.I. 15 820 

♦Pigment Red 57, C.I. 15 850, calcium toner 

Pigment Red 58, C.I. 15 825 

Pigment Red 60, C.I. 16 105 

♦Pigment Red 63, C.I. 15 880 - - 

Pigment Red 64, C.I. 15 800 

Pigment Red 77, C.I. 15 826 

Pigment Red 78 

Pigment Red 81, C.I. 45 160, fugitive 

♦Pigment Red 81, C.I. 45 160, FMA— 

♦Pigment Red 81, C.I. 45 160, PTA- 

Pigment Red 83, C.I. 58 000 - 

Pigment Red 87, C.I. 73 310 

Pigment Red 88 

♦Pigment Red 90, C.I. 45 380 - - 

Pigment Red 101 

Pigment Red 117, C.I. 15 603 - - 

Pigment Red 122 

See note at end of table for definition of abbreviations 



DUP. 

DUP. 

ACY, BIN, FCL, ICC, IMP, S, SNA, SW. 

HAR, HSH, IMP, SW. 

HAR. 

ACY, DUP, FCL, HAR, IMP, MRX, SNA, SW. 

ACY, DUP, FCL, HAR, HCC, ICC, IMP, RCM, SDH, SNA, SUC, SW. 

ICC, SNA, SW. 

ICC, IMP, KCW, S, SDH, SW, x. 

ACY, AMS, APC, FCL, HAR, HCC, HSH, IMP, KON, LVY, SNA, 

SUC, SW, WDC. 
ACY, APC, EAK, HCC, HSH, IMP, KON, PPG, SDH, SUC, SW. 
ACY, APC, BLN, CIK, DUP, EAK, FCL, HAM, HAR, HCC, HSH, 

IMP, KCW, KON, MRX, PPG, SDH, SNA, SUC, SW, UHL, 

TOC. 
ACY, AMS, FCL, HCC, IMP, KON, SDH, SNA, SUC, SW, WDC. 
DUP, G, HCC, SW. 
DUP, G, HAH, ICC, SNA, SW. 
IMP. 
G, HAR. 
ACY, AMS, BLN, DUP, FCL, G, HAR, HCC, HSH, IMP, KON, 

LVY, S, SNA, SUC, SW, WDC. 

ACY, AMS, CIK, FCL, HCC, IMP, KON, LVY, SDH, SNA, SUC, 

SW, UHL, WDC. 
ACY, AMS, EAK, FCL, G, HCC, IMP, KON, LVY, PPG, SDH, 

SNA, SUC, SW. 
ACY, AMS, CIK, FCL, G, KON, SDH, SUC, SW. 
KON. 
AMS, FCL, HCC, HSH, IMP, SNA, SUC, SW. 

ACY, ADC, AMS, CIK, FCL, HCC, IMP, KON, LVY, MGR, MRX, 

SDH, SNA, SUC, SW, WDC. 
ADC. 

IMP, MRX, SDH. 
DUP, HAR. 
ADC, AMS, BLN, CIK, DUP, FCL, HAR, HCC, HSH, IMP, KON, 

LVY, S, SDH, SNA, SUC, SW, WDC. 
DUP, IMP. 
SW. 

FCL, HAR, HSH, IMP, SNA, SW. 
HAR. 
SW. 
DUP. 

BLN, KCW, SNA. 
BLN, DUP, G, IMP, KON, LVR, LVY, MGR, MRX, NYC, S, 

SNA. 
ACY, AMS, BLN, DUP, FCL, G, HCC, IMP, KCW, KON, MGR, 

MRX, S, SDH, SNA. 
SW. 
HAR. 
HAR. 

ACY, AMS, FCL, ICC, IMP, LVR, LVY, NYC, SDH, SNA, WDC. 
SW. 



118 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE IIB.-- Synthetic organic pigments for which U.S. production or sales were reported, identified 
by manufacturer, 1963 — Continued 



Synthetic organic pigment 



Manufacturers' identification codes 
(according to list in table 22) 



TONERS— Continued 

*Red toners — Continued 

Piginent Red 123 

(Batic Red 2), C.I. 50 2^0 

(Vat Red 10), C.I. 67 000 

(Vat Red 23) - 

(Vat Red 29), C.I. 71 UO 

All other 

»Violet toners : 

Pigment Violet 1, C.I. 45 170, fugitive - 

»Pigment Violet 1, C.I. 45 170, PMA 

^Pigment Violet 1, C.I. 45 170, PTA 

«Pigment Violet 3, C.I. 42 535, fugitive 

»Pigment Violet 3, C.I. 42 535, FMA— 

^Pigment Violet 3, C.I. 42 535, PTA - 

Pigment Violet 19 

(Vat Violet 1), C.I. 60 010 - 

(Vat Violet 2), C.I. 73 385 - 

(Vat Violet 3), C.I. 73 395 

(Vat Violet 23) - 

All other 

*Blue toners : 

»Hgment Blue 1, C.I. 42 595, mk - — ■ 

»Pigment Blue 1, C.I. 42 595, PTA 

Pigment Blue 2, C.I. 44 045, fugitive 

Pigment Blue 2, C.I. 44 045, PMA - 

Pigment Blue 2, C.I. 44 045, PTA 

Pigment Blue 3, C.I. 42 140, BIA - 

Pigment Blue 3, C.I. 42 140, PTA 

Pigment Blue 5, C.I. 42 600 

^Pigment Blue 9, C.I. 42 025, FMA 

^Pigment Blue 9, C.I. 42 025, PTA 

Pigment Blue 10, C.I. 44 040, FMA ■ 

Pigment Blue 10, C.I. 44 040, PTA 

»Pigment Blue 14, C.I. 42 600, MA 

Pigment Blue 14, C.I. 42 600, PTA 

•Pigment Blue 15, C.I. 74 160, alpha form 

•Pigment Blue 15, C.I. 74 160, beta form 

•Pigment Blue 19, C.I. 42 750A - - • 

Pigment Blue 22, C.I. 69 810 • 

•Pigment Blue 25, C.I. 21 180 — 

(Basic Blue 7), C.I. 42 595, PTA- - 

(Vat Blue 4), C.I. 69 800 

(Vat Blue 6), C.I. 69 825 

(Vat Blue 14), C.I. 69 810 ■ 

All other 

•Green toners : 

•Pigment Green 1, C.I. 42 040, FMA 

•Pigment Green 1, C.I. 42 040, PTA 

•Pigment Green 2, C.I. 42 040 and C.I. 49 005, FMA- 
•Pigment Green 2, C.I. 42 040 and C.I. 49 005, PTA- 

Pigment Green 4, C.I. 42 000, fugitive 

•Pigment Green 4, C.I. 42 000, FMA 

•Pigment Green 4, C.I. 42 000, PTA 

•Pigment Green 7, C.I. 74 260 



HAH. 

HCC. 

G, HAR. 

HAR. 

HAR. 

DUP, G, HAM, HCC, SW, TRC, x. 

BLN, UHL. 

BLN, G, IMP, LVR, MRX. 

ACY, AMS, BLN, DUP, FCL, G, HCC, IMP, KON, MRX, S, 

SNA. 
ACY, ADC, AMS, BLN, HCC, IMP, LVY, MGR, SDH, SUC, UHL. 
ADC, AMS, BLN, CIK, DUP, EAK, G, HCC, IMP, KON, LVR, 

LVY, MGR, MRX, NYC, PPG, S, SDH, SNA, SUC, SW, UHL. 
ACY, AMS, G, HCC, IMP, KON, MRX, SNA, SW. 
HAR. 
DUP. 
HAR. 
HAR. 
TRC. 
ACY, G, ICC, X. 

ADC, BLN, DUP, EAK, G, HCC, IMP, KON, LVR, LVY, MGR, 

MRX, NYC, SDH, SNA, SW, UHL. • 

AMS, G, HAM, HAR, IMP, MGR, S, SNA, SW, UHL. 
BLN. 
G, LVR. 
G, HAM. 
MGR. 

MGR, MRX. 
G. 

IMP, LVR, MRX, NYC, UHL. 

BLN, G, IMP, MGR, MRX, SDH. 

IMP, SDH. 
IMP. 

DUP, G, IMP, NYC. 

DUP, G, NYC. 

ACY, DUP, FCL, G, HAR, ICC, ICI, IMP, SNA, SUC, SW, 

TMS, TRC. 

ACY, DUP, FCL, MP, KON, LVY, SNA, SUC, SW, TMS, TRC. 

ACY, ERD, NYC, SUC, SW. 

DUP, IMP. 

DUP, G, HAR, ICC. 
DUP. 
G. 

ICI, TRC. 

HAR, TRC. 

ICC, IMP, MGR, S, SDH. 

BLN, G, IMP, MGR, MRX, NYC, UHL. 

BLN, IMP, MGR, SDH. 

ADC, G, IMP, Vn, MGR, MRX, SDH, SNA, UHL. 

ACY, AMS, BLN, DUP, IMP, KON, LVY, MGR, MRX, S, SDH, 

SNA, UHL. 

BLN, G. 

ADC, BLN, HCC. 

ACY, AMS, HAM, IMP, MGR, SNA. 

ACY, DUP, FCL, G, HAR, IMP, SNA, SUC, SW, TMS, TRC. 



See note at end of table for definition of abbreviations. 



SYNTHETIC ORGANIC PIGMENTS 



119 



TABLE IIB. 



-Synthetic organic pigments for which U.S. production or sales were reported, identified 
by manufacturer, i 965- -Continued 



Synthetic organic pigment 



f&nuf aoturers ' identification codes 
(according to list in table 22) 



TONERS— Continued 

»Green toners — Continued 

•Pigment Green 8, C.I. 10 006 

Pigment Green 10, C.I. 12 775 

Pigment Green 38 

All other 

»Brown toners : 

Pigment Brown 1, C.I. 12 -iSO 

Pigment Brown 2, C.I. 12 071 ■ 

Pigment Brown 3, C.I. 21 010, fugitive- 
Pigment Brown 3, C.I. 21 010, IMA 

Pigment Brown 5, C.I. 15 800 

(Vat Brown 3), C.I. 69 015 ■ 

All other 

»Black toners: 

Pigment Black 7 

All other 

LAKES 

»Yellow lakes : 

(Acid Yellow 1), C.I. 10 316 

(Acid Yellow 3), C.I. 47 005 ■ 

(Acid Yellow 23), C.I. 19 UO 

(Natural Yellow 10), C.I. 75 720- 

All other 

Orange lakes : 

Pigment Orange 17, C.I. 15 510 

All other 

»Red lakes : 

•Pigment Red 60, C.I. 16 105 ■ 

•Pigment Red 83, C.I. 58 000 

(Acid Red 17), C.I. 16 180 - 

(Acid Red 25), C.I. 16 050 

•(Acid Red 26), C.I. 16 150 

(Natural Red A), C.I. 75 470 

(Natural Red 24), C.I. 75 280 

All other 

•Violet lakes: 

•Pigment Violet 5, C.I. 58 055 

Pigment Violet 20, C.I. 58 225- — 

(Acid Violet 17), C.I. 42 650— - 

All other 

•Blue lakes : 

Pigment Blue 17, C.I. 74 180— 

•Pigment Blue 24, C.I. 42 090 

(Acid Blue 93), C.I. 42 780- 

(Acid Blue 104), C.I. 42 735 

Green lakes : 

(Acid Green 3), C.I. 42 085— 

All other 

Brown lakes 

Black lakes: 

•(Natural Black 3 ), C.I. 75 291 — 

All other 



DUP, EAK, G, HSH, IMP, KCW, SW. 

DUP. 

HAH. 

ACY, S. 

ICI. 

HSH, SDH. 

KON. 

BLN, KCW. 

HAH, SMA, X. 

G, HAR. 

HSH, ICG, SDH, SW. 

SW. 

BLN, DUP, G, MGR, SNA, UHL. 



IMP. 














IMP. 














IMP, 


KON, 


MGR, 


MRX. 








IMP. 














IMP. 














CIK, 


CPC, 


IMP, 


KCW, 


MGR. 






APC, 


HAM. 












BLN, 


DUP, 


HSH, 


KON, 


MRX, 


SNA, 


SW. 


IMP, 


KCW, 


KON, 


MRX, 


UHL. 






IMP, 


KCW, 


WDC. 










KON. 














CPC, 


EAK, 


HAM, 


IMP, 


KCW, 


UHL. 




KON. 














IMP. 














APC, 


G, IMP. 










BLN, 


DUP, 


HAR, 


IMP, 


SNA. 






SW. 














BLN. 














HAM, 


HCC. 












BLN, 


CPC. 












ADC, 


AMS, 


BLN, 


CIK, 


ICC, 


IMP, 


KON, LVY, MGR, SDH 


LVR. 














CPC, 


KCW. 












BLN, 


CPC. 












HAM. 














CPC, 


KON, 


MYC. 










HAM. 















Note. — The C.I. (Colour Index) numbers shown in this report are the identifying codes given in the second edition of 
the Colour Index. 

When the name of a color is enclosed in parentheses, it indicates that this name Is that of the dye from which the 
pigment can be made and that no name for the pigment itself is given in the Colour Index. 

The abbreviations IMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic ) 
acids, respectively. 



120 



SYNTHETIC ORGANIC CHEMICALS, 1963 



Medicinal Chemicals 

TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer , 1963 

[Medicinal chemicals for which separate statistics are given in table 13A in pt. II are marked below with an asterisk 
(«■) ; medicinal chemicals not so marked do not appear in table 13A because the reported data are accepted in con- 
fidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x 
signifies that the manufacturer did not consent to his identification with the designated product] 



Manufacturers ' identification codes 
(according to list in table 22) 



MEDICINAL CHEMICALS, ANTIBIOTICS 

•Antibiotics for human or veterinary use: 

Aii5>hotericin B 

»Bacltraoin 

Chloramphenicol 

7-Chloro-6-demethyltetraoycline 

Chlortetracycline hydrochloride 

Cycloheximide 

Cycloserine 

»Dlhydrostreptomycin 

Erythromycin 

Fumagillin 

Gramicidin 

Kananycin 

•Neomycin, base 

Novobiocin 

Nystatin 

Oleandomycin 

Oleandomycin triacetate 

Oxytetracycline hydrochloride 

Paromomycin 

Penicillin salts: 

d-c-Aminobenzylpenicillin 

2,6-Dimethoxyphenylpenicillin, sodium 

Methylphenylisoxazolylpenicillin, sodium 

NEP penicillin 

•Penicillin G, benzathine 

•Penicillin G, potassium 

•Penicillin G, procaine 

•Penicillin G, sodium 

Penicillin 0, chloroprocaine 

Penicillin 0, sodium 

Penicillin V - — - 

Penicillin V, benzathine 

Penicillin V, hydrabamine 

Penicillin V, potassium 

•dl-c.-Phenoxyethylpenicillin 

•dl-a-Phenoxyethylpeniclllin, potassium 

Polymyxin B sulfate 

Ristocetin 

Streptomycin 

•Tetracycline 

Thiostrepton 

Tyrothricin 

Vancomycin 

Vionycin 

•Antibiotics for animal feed supplements, food preserva- 
tion, and crop spraying: 

•Bacitracin 

Chlortetracycline hydrochloride 

Hygronycin B 

Novobiocin mixture 

Oxytetracycline hydrochloride 



PBS, PEN, PFZ. 



CMS, PFZ. 
LIL. 



CMS, PEN, PFZ, UPJ. 
UP J. 



CMS. 

CCM, 

PD. 

ACY. 

ACY. 

UPJ. 

CCM. 

MRK, 

ABB, 

ABB. 

BAX, 

BRS. 

ACY, 

MRK, 

CMS. 

PFZ. 

PFZ. 

PFZ. 

MRK. 

BR£. 
BH£. 
BRS. 
MRK. 
PFZ, 
ABB, 
ABB, 
MRK, 
UPJ. 
UPJ. 
LIL. 
VfYT. 
ABB. 
ABB, 
OMS, 
BRS, 
PFZ. 
ABB. 
LIL, 
ACY, 
CMS. 
BAX, 
LIL. 
PFZ. 



CCM, DLI, GPR, PBS, PEN. 

ACY- 

LIL. 

UPJ. 

PFZ. 



WYT. 

LIL, MRK, CMS, PFZ, WYT. 
LIL, MRK, CMS, PFZ, WYT. 
QMS, PFZ. 



LIL. 
PFZ. 
WYT. 



MRK, CMS, PFZ. 
BRS, PFZ. 



MEDICINAL CHEMICALS 



121 



TABLE 13B. --Medicinal chemicals for mhich U.S. production or sales were reported, identified by 

manufacturer , 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MEDICINAL CHEMICALS, ANTIBIOTICS--Continued 

^Antibiotics for animal feed supplements, food preservation, 
and crop spraying — Continued 
Penicillin salts: 

Penicillin G, benzathine 

*Penicillin G, procaine 

Streptomycin 

Tylosin 

MEDICINAL CHEMICALS, BENZENOID 

^Alkaloids and related products: 

Anisotropine raethylbromide 

Berberine hydrochloride 

Caffeine sodium benzoate 

Colchicine 

■»Dihydrocodeinone bitartrate 

Dihydrohydroxycodeinone hydrochloride 

Ergonovine raaleate 

Eserine salicylate 

Ethylmorphine hydrochloride 

Homatropine 

Homatropine hydrobromide 

*Homatropine methyl bromide 

Hydrastine 

Hydrastine hydrochloride 

Lobelia sulfate 

d-3-Methoxy-N-methylmorphinan hydrobromide 

Papaverine hydrochloride, synthetic 

Qainidine gluconate 

Quinidine sulfate 

Rauwolfia serpentina (Alseroxylon) fraction 

Reserpine 

Tuboourarine 

Vincaleukoblastine sulfate 

Amino acids : 

dl-Acetyltryptophane 

3,5-Diiodotyrosine 

dl-Phenylalanine 

*p-Aminobenzoic acid and derivatives: 

p-Aminobenzoic acid 

p-Aminobenzoic acid, calcium salt 

p-Aminobenzoic acid, magnesium salt 

p-Aminobenzoic acid, potassium salt 

p-Aminobenzoic acid, sodium salt 

p-Amino-N-(2-diethylaminoethyl)benzamide (Procainamide) 
hydrochloride . 

Benzocaine (Ethyl p-aminobenzoate) 

Butacaine base 

n-Butyl p-aminobenzoate 

p-Butylaminobenzoic acid, 2-dimethylaminoethyl ester 
(Tetracaine) base and hydrochloride. 

Di(n-butyl p-aminobenzoate) trinitrophenol 

2-Diethylaminoethyl <i-amino-2-propoxybenzoate 

Isobutyl p-aminobenzoate (Cycloform) 

u)-Methoxypoly(ethyleneoxy) ethyl p-butylaminobenzoate 

Procaine base 

Procaine hydrochloride 

Propyl p-aminobenzoate 

All other 



WYT. 

ABB, LIL, MRK, OMS, PFZ, ITfl. 

MRK, PFZ. 

LIL. 



CTN, 


EN. 


ABB, 


PEN. 


PEN. 




EN, 


WAL, MRK, PEN 


EN. 




LIL. 




PEN. 




MAL, 


MRK. 


CTN, 


HEX. 


CTN. 




CTN, 


EN, HEX. 


PEN. 




PEN. 




ABB. 




HOP. 




LIL. 




HEX. 




HEX. 




RIK. 




CBP, 


PEN. 


ABB, 


OMS. 


LIL. 




SEW. 




EK. 




SDW. 




LEM. 




LEW. 




LEM. 




GAN, 


LEM. 


GAN, 


LiM. 


QMS. 




ABB, 


LEM. 


ABB. 




ABB. 




ICO, 


SEW. 


ABB. 




SLW. 




ICO. 




CBP. 




ABB. 




ABB, 


LEM. 


ICO. 




ABB. 





149-026 O - 64 



122 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE \3B.-- Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer , i 965- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MEDICINAL CHEMICALS, BENZENOID--Continued 

2-(p-Aminophenyl)-2-ethylglutarimlde 

l-[ (^-Amino-2-propyl-5-pyrlmldlnyl)methyl] -2-picolinium 

chloride hydrochloride. 
p-Anisoin (i,-; '-Dimethoxybenzoin) 

Anthranilic acid, cadmium salt 

♦Antihistamines : 

l-Benzhydryl-4-methylpiperazine (Cyolizine) base and 

hydrochloride . 
2-(Benzhydryloxy) -N, N-dimethylethylamine 8-chloro- 

theopl^llinate (Dimenhydrinate) . 
2-(Benzhydryloxy) -N,N-dimethylethylamine (Diphenhydra- 
mine) hydrochloride. 
2- [ Benzyl ( 2 -dime thy laminoethyl ) amino Jpyridine 

(Tripelennamine) . 

2-[Benzyl(2-dimethylaminoethyl)amlno] pyridine citrate 

2-[Benzyl(2-dimethylaminoetl^l) amino] pyridine hydro- 
chloride . 
2-[ (p-Bromo-a-phenylbenzyl)oxy]-N,N-dimethylethylamine 

(Bromodiphenhydramine) hydrochloride. 
2-[l-(p-Bromophenyl)-3-dimethylaminopropyl]pyridine 

(Brompheniramine) maleate. 
d-2-[l-(p-Bromophenyl)-3-dime thy laminop ropy 1] pyridine 

(Dexbrompheniramine) maleate. 
l-("4-Chlorobenzhydryl)-'4-(p-tert-butylbenzyl)piperazine 

(Buclizine) dihydrochloride . 
1- ( 4-Chlorobenzhydryl ) -^- ( 3-methylbenzyl) piperazine 

(Meclizine) dihydrochloride. 
l-('4-Chlorobenzhydryl) -^-methylplperazine ( Chlor- 

cyolizine) hydrochloride. 
2-[p-Chloro-oi-(2-dimethylaminoethoxy)benzyl] pyridine 

(Carbinoxaraine) . 
I -2-[ p-Chloro-a - ( 2-dimethylaminoethoxy ) benzyl]pyridlne — 
»2-[p-Chloro-a-(2-dlmethylaminoethyl)benzyl] pyridine 

(Chlorpheniramine) maleate. 
d-2- [p-Chloro-^- ( 2-dimethylaminoethyl) benzyl] pyridine 

(Dexohlorpheniramine) maleate. 

l-(p-Chlorophenyl)-2-phenyl-'4-pyrrolidyl-2-butanol 

1- (p-Chlorophenyl) -2-phenyl-4-pyrrolidyl-l-butene 

(Pyrrobutaraine) diphosphate, hydrobromlde and hydro- 
chloride. 
4-(5H-Dibenzo [a, d] cyolohepten-5-ylidine) -1-methyl- 

piperidine. 
2-[a-(2-Dimethylaminoethoxy)-a-methylbenzyl]pyTidine 

(Doxylamine) succinate. 
2-(l-[ 2-(2-Dimethylaminoethyl)inden-3-yl]ethyl)pyridine 

(Dimethindene) maleate. 
2-[(2-Dimethylaminoethyl)(p-methoxybenzyl)amino] 

pyridine (Pyrilamine) maleate. 
2- [ ( 2-Dimethy laminoethyl ) ( p-methoxybenzyl) amino] 

fyrimidine (Thonzylamine) . 
(2-Dimethylaminoethyl)-2-thenylamino] pyridine (Metha- 
pyrilene) fumarate. 
2- [ ( 2-Dimethy laminoethyl) -2-thenylamino] pyridine hydro- 
chloride. 
2- [(2-Dimethy laminoethyl) -2-thenylamino] pyridine o-(p- 
hydroxybenzoyl ) benzoate . 
»2-[ 3- (Dimethylamino)-l-phenylpropyl] pyridine (Phenlra- 
mine) maleate. 



CBP. 
MRK. 

CTN. 
MAL. 

BUR. 

SRI. 



CBP, 


RSA. 




CBP. 






PD. 






SCH. 






SCH. 






PFZ. 






PFZ. 






ABB, 


BUR. 




SCH. 






SCH. 






HEX, 


PYL, 


SCH, SK, x 


SCH. 






LIL. 






LIL. 






X5RK. 






BKC. 






CBP. 






HEX, 


Mta, 


PYL. 


NEP. 






ABB. 






ABB, 


SOT. 




LIL. 






HEX, 


SCH, 


X. 



MEDICINAL CHEMICALS 



123 



TABLE IZB.-- Medic irjal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



MEDICINAL CHEMICALS, BENZENOID- -Continued 

wAntihistamines — Continued 

N,N-Dimethyl-2-(o-methyl-a-phenylbenzyloxy)ethylamine 

(Orphenadrine) citrate and hydrochloride. 
N,N-Dijnethyl-2-( i-phenyl-o-tolyloxy)ethylajnine dihydrogen 

citrate (Phenyltoloxamine) . 
2,3,4,9-Tetrahydro-2-methyl-9-phenyl-lH-indeno[2,l-c]- 
pyridine (Phenindamine) hydrogen tartrate. 
♦Antimony, arsenic, bismuth, and mercury compounds: 
Antimony, arsenic, and bismuth compounds: 

3-Acetamido-'i-hydroxydithiobenzenearsonous acid, 3- 
hydroxypropylene ester (Arsthinol) . 

Acetarsone (N-Acetyl-i-hydroxy-m-arsanilic acid) 

Arsanilic acid (p-Aminobenzenearsonio acid) 

Arsanilic acid, sodium salt 

Bismuth resorcinol 

Bismuth salicylate, basic 

»Bismuth subgallate -■ 

p-Carbamidobenzenearsonio acid 

N-Glycoloylarsanilic acid, bismuth salt 

<i-Hydroxy-3-nitrobenzenearsonic acid 

p-Nitrobenzenearsonic acid 

Sodium antimony (III) -bis (oatechol-2,'i-disulfonate) 
(Fouadin) . 
Mercury compounds: 

o-Chloromerouriphenol (o-Hydroxyphenylmercuric 
chloride) . 

Ethylmerourithiosalicylio acid 

Ethylmercurithiosalicylic acid, sodium salt 
(Thimerosal) . 

Hydroxymercuri-'i-nitro-o-oresol anhydride 

Merbromin (Dibromohydroxymerourifluorescein, sodium 
salt) . 

Mercuric salicylate 

Phenylmercuric acetate 

Phenylmercuric benzoate 

Phenylmercuric borate 

Phenylmercuric nitrate 

Barbiturates : 

5-Ethyl-l-methyl-5-phenylbarbiturio acid (Mephobarbital) 

»5-Ethyl-5-phenylbarbituric acid (Phenobarbital) 

»5-Ethyl-5-phenylbarbituric acid, sodium salt 

Benzaldehyde 

Benzoic acid 

Benzoic acid, ammonium salt 

»Benzothiadiazine dioxide derivatives: 

3-Benzyl-3,4-dihydro-6-(trifluororaethyl)-2H-l,2,4-benzo- 
thiadiazine-7-sulfonamide 1,1-dioxide (Benzhydro- 
flumethiazide) . 
3-Benzylthiomethyl-6-chloro-2H-l,2,';-benzothiadiazine-7- 

sulfonamlde 1,1-dioxide (Benzthiazide) . 
6-Chloro-2H-l,2,4-benzothiadiazine-7-sulfonamide 1,1- 
dioxide (Chlorothiazide) . 
6-Chloro-3-ohloromethyl-3,4-dihydro-2-methyl-2H-l,2,4- 
benzothiadiazine-7-sulfonamide 1,1-dioxide (Methyclo- 
thiazide) . 
6-Chloro-3-dichloromethyl-3,'i-dihydro-2H-l,2,4-benzo- 
thiadiazine-7-sulfonamide 1,1-dioxide (Hydrotrichloro- 
thiazide) . 



Manufacturers' identification codes 
(according to list in table 22) 



RIK. 
BRS. 

HOF. 

EN. 

srw. 

SAL, WHL. 

WHL. 

NEP. 

MAL, NOR, PEN. 

BKC, MAL, PEN. 

LIL, PYL, WHL. 

WHL. 

SAL. 

SAL. 

SOT. 



LIL. 








LIL, 


PYL. 






ABB. 
HYN. 








MTL. 
WRC. 
MTL, 


WRC. 






MTL, 


WRC. 






MTL, 


WRC. 






SDW. 








BPC, 


GAH, 


MAL, 


SOT 


BPC, 


GAN, 


MAL, 


SOT 


HN. 








MON. 








PEN. 









QMS. 

PFZ. 
MRK. 

ABB. 

SCH. 



124 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 13B. -- Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer , 1963 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MEDICINAl. CHEMICALS, BENZENOID--Continued 

»Benzothiadiazine dioxide derivatives — Continued 

6-Chloro-3,<»-dihydro-2H-l,2,'i-benzothladiazine-7-sulfon- 
amide 1,1-dioxide (Hydrochlorothiazide). 

6-Chloro-3,'4-dihydro-2-methyl-3-(2,2,2-trifluoroethyl- 
thiomethyl) -2H-1, 2,'4-benzothiadiazine-7-sulfonamide 
1,1-dioxide (Polythiazide) . 

6-Chloro-3,'i-dlhydro-3-(5-norbomen-2-yl)-2H-l,2,4- 
benzothiadiazine-7 -sulfonamide 1,1-dioxide (Cyclo- 
thiazide) . 

3,4-Dihydro-6-(trifluoromethyl)-2H-l,2,4-benzothiadia- 
zine-7-sulfonaiiiide 1,1-dioxide (Hydroflumethiazide). 

6-(Trif luoromethyl ) -2H-1, 2, 4-benzothiadiazine-7-sulf on- 
amide 1,1-dioxide ( Flume thiaz ide ) . 

l-[2-(Benzylcarbamoyl)ethyl] -2-isonicotinoylhydrazine 

Bis(3-nitrophenyl) disulfide 

2-Butoxy-N- [ 2- ( diethylamino) ethyl Joinchoninamide 

(Dibucaine) hydrochloride. 
4-[3-(p-Butoxyphenoxy)propyl]morpholine (Pramoxine) hydro- 
chloride . 
2-(n-Butylaminomethyl) -8-ethoxy-l,4-benzodioxane hydro- 
chloride. 
<i-n-Butyl-2-(p-hydroxyphenyl)-l-phenyl-3,5-pyTazolidine- 

dione . 
Carbaraic acid, 2-hydroxy-2-phenylbutyl ester (Hydroxy- 

phenamate) . 
Carbamic acid, 2-hydroxy-2-phenylethyl ester (Styramate)-- 
(3-Carbamoyl-3,3-diphenylpropyl)diisopropylmethylaramonium 

iodide. 
( 3 -Carbauioyl-j , 3 -diphenylpropyl ) ethyldimethylammonluin 

(Ambutonium) bromide. 

5-Chloro-2-benzoxazolidinone 

7-Chloro-<t- (4--diethylamino-l-methylbutylamino ) quinoline 

(Chloroquine) . 
7-Chloro-4-('i-diethylamino-l-methylbutylamino)quinoline 

sulfate. 

p-Chloro-a,a-dimethylphenethylamine hydrochloride 

7-Chloro-4- (4- [ ethyl ( 2-hydroxyethyl) amino ] -1-methylbutyl- 

amino)quinoline (Hydroxychloroquine) sulfate. 

2-Chloro-'*-nltrobenzaraide 

2-(';-Chlorophenyl)tetrahydro-3-methyl-4H-l,3-thiazin-4- 

one, 1,1-dioxide. 

Cozymase 

l-Cyclohexyl-3-diethylamino-l-phenyl-l-propanol ethiodide- 
a-Cyclohexyl-4-methyl-c*-phenyl-l-piperazineethanol (Hexo- 

oyclium) dimethyl sulfate. 

ci-Cyclohexyl-a-phenyl-1-piperidinepropanol 

Desoxyanisoin 

2,4-Diamino-5-(p-ohlorophenyl)-6-ethylpyrimidine 

2,5-Diaminotoluene sulfate 

4-(2,5-Diethoxy-<i-nitrophenyl)morpholine 

a-Diethylamino-2,6-acetoxylidide 

6-(2-Diethylaminoethoxy)-2-dimethylaminobenzothiazole 

hydrochloride . 

P-Diethylaminoethyl diphenylthioacetate hydrochloride 

N, N-Diethylaminoethylf luorene-9-carboxylate hydroohloride- 
N,N-Diethylaminoethylxanthene-9-oarboxylate methobromide-- 
Diethylaminopropiophenone 



ABB, CBP, MRK. 
PFZ. 



QMS. 

OMS. 

PFZ. 
ACY. 
CBP. 

ABB. 

LIL. 

GGY. 

AKP. 

AHP. 
SK. 



SDW. 

RDA. 

NEP. 
SEW. 

SAL. 
SDW. 

PBS. 
ACY. 
ABB. 

ACY, SDW. 

CTN. 

BUR. 



AST. 
HOF. 



SRL. 
SRL. 
BKC, X. 



MEDICINAL CHEMICALS 



125 



TABLE 13B. 



-Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 565 --Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MEDICINAL CHaUCALS, BENZENOID— Continued 

10,ll-Dihydro-N,N-dimethyl-5H-dibenzo[a,d]cycloheptene- 
A ^ >'*' -propylamine . 

Sji-Dihydroxyphenylacetic acid 

/-3-(3,<i-Dihydroxyphenyl)-2-methylalanine 

N,N-Diisopropylaininoe thy lxanthene-9-oarboxy late methyl- 
bromide (Propantheline bromide). 
6 , 7-Dimethoxy-l-( 4-ethoxy-3 -methoxybenzyl) -3-methylquino - 

line (Dioxyline) phosphate, 
a -d-A-Dimethylamino-1, 2-diphenyl-3-methyl-2-propoxy butane 

hydrochloride. 
4.-(2-Dimethylaminoethoxy)-N-(3,4,5-trlmethoxybenzoyl)- 
benzylamine hydrochloride. 

p,a-Dimethylbenzyl camphorate, diethanolamine salt 

( [(2,3-Dimethyl-5-oxo-l-phenyl-3-pyrazolin-4-yl)methyl]- 
amino)methanesulfonic acid, sodium salt (Dipyrone) . 

3,<i-Dimethyl-2-phenylmorpholine 

N,2-Dimethyl-2-phenylsuccinimide 

N, N-Dimethyl-4-piperidylidene-l, 1-diphenylmethane ( Diphem- 
anil) methyl sulfate. 

Dimethyl-p-toluidine 

3,5-Dinitrobenzamide 

Dipheny lac etyldi ethylaminoethanol hydrochloride 

»Dyes, medicinal: 

Acriflavine (3,6-Diamino-lO-methylacridine chloride) 

2,6-Diamino-3-phenylazopyridine hydrochloride 

Gentian violet 

lodocyanine green 

Methylene blue 

Phenolphthalein 

Phenolphthalein, yellow 

Pyrvinium pgjnoate 

Scarlet red (Phenol red) 

Other : 

♦Estrogens, steroid and nonsteroid: 
Steroid: 

Estrogenic substance 

Piperazine estrone sulfate 

Nonsteroid: 

3,4-Bis(p-acetoxyphenyl)-2,'t-hexadiene 

oc ,a' -Diethyl -4, 4.' -stilbenediol (Diethylstilbestrol) — 

N-Ethyl-3,3' -diphenyldipropylamine 

N-Ethyl-3,3' -diphenyldipropylamine citrate 

N-Ethyl-3,3' -diphenyldipropylamine hydrochloride 

Ethyl l-methyl-4-phenylisonipecotate 

2-Ethyl-2-phenylglutarlmide (Glutethimide) 

N-Ethyl-3-piperidyl benzilate methobromide 

N-Ethyl-3-piperidyl diphenylacetate hydrochloride 

Hesperidin methyl chalcone 

1-Hexadecylpyridinium chloride 

Hexahydro-l-methyl-4-phenylazepine-4-carboxylic acid, 
ethyl ester, (Ethoheptazine) citrate. 

Hexamethylenetetramine mandelate 

Hydantoin derivatives: 

5,5-Diphenylhydantoin 

5,5-Diphenylhydantoin, sodium salt 

3-Ethyl-5-phenylhydantoin 



LIL. 
MRK. 
SRL- 

LIL. 

LIL. 

HOF. 

X. 

SEW. 



PD. 
SCH. 

EK, RSA. 

SAL. 

CBP. 

NAC. 

HOF, NEP. 
NAC, SDH. 

X. 

ACY, NAC. 

MON. 

WLI. 

X. 

NAC. 
NAC. 



ORG. 
ABB. 

SCH. 

CTN, LIL. 

CTN. 

CTN. 

CTN. 

SDW, WYT. 

CBP. 

LKL. 

LKL. 

SKG. 

FIN, GAN, HEX. 

WYT. 

LEM, NEP, PYL, TNC. 



PD. 

ABB. 



126 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 13B. 



■Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 965 --Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MEDICINAL CHEMICALS, BENZENOID--Gontinued 

1-Hydrazinonaphthalazine hydrochloride 

»p-Hydroxyacetanilide 

p-Hydroxybenzoic acid esters: 

Benzyl p-hydroxybenzoate 

n-Butyl p-hydroxybenzoate (Butoben) 

Ethyl p-hydroxybenzoate 

■"•Methyl p-hydroxybenzoate 

»Propyl p-hydroxybenzoate 

o-(p-Hydroxyben2oyl) benzoic acid 

"i-Hydroxycomiiarin 

N-(2-Hydroxyethyl)gentisamide 

2,2'-(2-Hydroxyethylimino)bis[N-(a,a-dlinethylphenethyl)- 
N-methylacetamide] (Oxethazaine) . 

3-Hydroxy-l-inethylpyridiniuin bromide dimethylcarbamate 

"Imidazoline derivatives: 

2-Benzyl-2-imidazoline (Tolazoline) hydrochloride 

l-Methyl-2-undecyl-3-benzylimidazolium bromide 

2-(l-Naphthylmethyl)-2-imidazoline hydrochloride 

a-2-(l,2,3,"i-Tetrahydro-l-naphthyl)-2-imidazoline hydro- 
chloride. 

Isonicotinic acid hydrazide 

Mandelio acid (Phenylglycolic acid) 

Mandelic acid, calcium salt 

p-Methoxycinnamic acid, benzyl ester 

p-Methoxycinnamic acid, 2-methoxyethyl ester 

5-(o-Methoxyphenoxymethyl)-2-oxazolidinone 

2-Methylbenzothiazole 

<i-Methyl-a,a -diphenyl-l-piperazineethanol dihydroohloride- 

3,3'-Methylenebis(4-hydroxycoumarin) 

5-Methyl-3-isoxazolecarboxylic acid, 2-benzylhydrazide 

3-Metl^rl-2-phenylraorpholine hydrochloride 

N-Methyl-2-phenylsuccinijnide 

2-Methyl-l-piperidinepropanol, benzoate (Piperocaine) 
hydrochloride. 

N-Methyl-3-piperidyl benzilate methyl bromide 

3-(2-Methyl-l-piperidyl)propyl p-cyclohexyloxybenzoate 

N-Methyl-N-2-propylbenzylamine hydrochloride 

2-Methyl-3-o-tolyl-i(3H)-quinazolinone -• 

Neostigmine bromide 

Neostigmine methyl sulfate 

Nikethamide 

Phenacaine [ (Di-p-ethoxyphenyl)acetajiiidine] hydrochloride- 

Phenacetin (Acetophenetidin) 

•Phenols and derivatives : 

Chlorothymol 

Gallic acid 

»Guaiacol glyceryl ether 

Guaiaool, liquid and crystalline 

Hexylresorcinol 

2-Naphthol ( p-Naphthol) — - - 

Phenolsulfonic acid, aluminum salt 

Phenolsulfonic acid, ammonium salt 

Phenolsulfonic acid, sodium salt 

Phenolsulfonic acid, zinc salt 

Pyrogallic acid 

Resorcinol 

Resorcinol dimethyl ether 

Resorcinol monoacetate 



CBP. 

ABB, MLS, NEP. 

HN. 

HN, ICO, WSN. 

HN. 

HN, ICO, LEM, PYL, WSN. 

HN, ICO, LEM, PYL, WSN. 

LIL. 

FIN. 

ICO. 

WYT. 

HOP. 

CTN. 
LIL. 
CBP. 
PFZ- 

NEP, RIL. 

MAL. 

MAL. 

GIV. 

GIV. 

ACY. 

FMT. 

ABB. 

ABB, FIN. 

HOF. 

GGY. 

PD. 

LIL. 

LKL. 

LIL. 

ABB. 

HEX. 

HEX. 

HEX, MED. 

CBP. 

GAN. 

DOW, MON. 



OPC. 

MAL. 

GAN, 

HN, 

HEX, 

ACY, 

MAL. 

SAL. 

MAL, 

MAL. 

MAL. 

LIM. 

ASL. 

KPT. 



HEX, ICO, LM, OTC. 
MON. 
MRK. 
FIN. 



MEDICINAL CHEMICALS 



127 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i 963 --Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MEDICINAL CKEMICALS, BENZENOID- -Continued 

»Phenols and derivatives — Continued 

Resorcinol monobenzoate 

Thymol 

Thymol iodide 

3-o-Toloxy-l,2-propanediol (o-Cresyl-a-glyoeryl ether) — 

Phenothiazine 

Phenylacetylurea (Phenurone) 

1-Phenyloyclohexaneglycolic acid, l-methyl-l,'t,5,6-tetra- 

hydro-2-pyrimidinemethanol ester. 
1-Phenylcyclopentanecarboxylic acid, 2- (2-diethylami no- 

ethoxy) ethyl ester, citrate. 
1-Phenylcyclopentanecarboxylic acid, 2-diethylaminoethyl 
ester ethanedisulf onate . 

Phenylethylhydrazine dihydrogen sulfate 

2-Phenyl-l,3-indandione 

Phenylundecanoic acid 

l-(2H)-Phthalazone 

Podophyllin powder 

Primaquine (8-(^-Amino-l-methylbutylainino) -6-methoxy- 
quinoline) phosphate. 

Pyrazine-2-carboxamide 

2-PyTidinemethanol tartrate 

a-(2-Pyridylaminomethyl)benzyl alcohol (Phenyramidol) 
hydrochloride. 

1-Pyrrolidineacetoxylidide (Pyrrocaine) hydrochloride 

»8-Quinolinol and derivatives; 

5-Chloro-7-iodo-8-quinolinol (lodochlorohydroxyquinoline) 

»5,7-Diiodo-8-quinolinol 

8-Hydroxyquinoline-5-sulfonic acid 

■»8-C3uinolinol 

«8-Quinolinol benzoate 

8-Quinolinol citrate 

»8-Quinolinol sulfate (Quinosol) 

8-Quinolinol, zinc salt 

Roentgenographic contrast media: 

3-Acetamido-2,4,6-triiodobenzoic acid (Acetrizoate) and 

sodium salt. 
3- (3-Amino-2, 4, 6-triiodophenyl) -2-ethylpropiom.c 

(lodopanoic) acid. 
3,5-Diacetamido-2,'l,6-triiodobenzoio acid (Diatrizoate), 

sodium salt. 
3,5-Dipropionamido-2,'4,6-triiodobenzoic acid (Dipro- 
trizoate) and sodium salt. 

Ethyl (iodophenyl)hendecanoate 

"Salicylic acid and derivatives: 

»Acetylsalicylic acid (Aspirin) 

Acetylsalicylic acid, aluminum basic salt 

"i-Aminosalicylic acid 

'i-Aminosalicylic acid, calcium salt 

"i-Aminosalicylic acid, potassium salt 

<V-Amlnosalicylic acid, sodium salt 

N-Butyl-3-phenylsalicylamide 

Dipropylene glycol salicylate 

Dithiosalicylic acid 

Ethyl salicylate carbonate 

Glycol monosalicylate 

Magnesium salicylate 

Menthyl salicylate 



EKT. 

GIV. 

MAL. 

BKl, HEX. 

CLV. 

ABB. 

PFZ. 

PFZ. 

SK. 

NEP. 

CTN, GAN. 

EK. 

NAC, SDH. 

ABB. 

PD. 

MRX. 
HOF. 



CBP, 


PYL. 






im, 


PYL, 


RSA, 


SRL. 


LEM, 


MIL. 






GAM, 


im, 


MIL. 




GAM, 


LIM, 


MTL. 




GAM. 








GAM, 


LEM, 


MIL, 


PYL. 


FMT. 








MAX. 








SOT. 








SOT. 








MAI. 








x. 








CFC, 


DOW, 


MLS, 


MON, NOR, SDG 


ABB, 


SCH. 






MLS. 








MLS. 








MLS. 








MLS. 








KF. 








SBC. 








LIL. 








PD. 








RDA. 








MAL. 








ICO. 









128 



SYNTHETIC ORGANIC CHEMICALS, )963 



TABLE 13B. 



-Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1963 --Continued 



Manufacturers' Identification codes 
(according to list in table 22) 



MEDICINAL CHIMICALS, BENZENOID--Continued 

^Salicylic acid and derivatives — Continued 

homo-Menthyl salicylate 

Potassium salicylate 

Salicylamide 

Salicylanllide 

*Salicylio acid 

Salol (Phenyl salicylate) 

Sodium salicylate 

Strontiiun salicylate 

Thiosalicylic acid 

All other 

Sodium benzyl succinate 

8-Saccinoylf luoranthene (Florantyrone) 

^Sulfonamides and sulfones: 

N,N'-Bls(3-nitrobenzenesulfonyl)ethylenediamlne 

Chloramine T (Sodium p-toluenesulfonchloramide) 

3-('i-Chloro-3- sulf amoy Ipheny 1 ) -3 -hydroxyphthalimidine ■ 

■ijS-Dichloro-m-benzenedisulfonamide 

Diphenyl sulf one 

p-(Di-n-propylsulfamoyl)benzoic acid 

■»Phenylsulfonylurea derivatives: 

l-(p-Acety Ipheny lsulfonyl)-3-cyolohexylurea 

l-Butyl-3-p-tolylsulfonylurea 

3-(p-ChlorophenylEulfonyl)-l-propylurea 

»Sulfa drugs: 

6-Acetamido-<i-hydroxy-3-(«+' -sulfajnoylphenylazo)-2,7- 
naphthalenedisulfonic acid, disodium salt. 

N"'"-Aoetyl-3,'i-dimethyl-5-sulfanilaiid.doisoxazole 

N'''-Acetylsulfamethoxypyridazine 

'i'-(Acetylsulfamoyl)phthalanilic acid 

Benzoylsulfanilamide 

Benzoylsulfanilamide, sodium salt 

p-Benzylaminobenzenesulfonamide 

N"'"-( 2, 6-Diraethoxy -4 -pyrimidinyl) sulfanilamide 

N'"'- (3, ^-Dimethyl-5-isoxazolyl) sulfanilamide 

N^-(5-Ethyl-l, 3, 4-thiadiazol-2-yl) sulfanilamide 

N-''-(5-Methyl-3-isoxazolyl)sulf anilamide 

N^ - ( 5-Methyl-l, 3 , -V-thiadiazol-a-yl) sulfanilamide 
(Sulfamethizole) . 

<i'-(p-Nitrophenylsulfamoyl)acetanllide 

p-Nitrosulfathiazole 

Succinylsulfathiazole 

Sulfabromomethazine sodium 

Sulfadiazine 

Sulfadiazine, sodium salt 

Sulfaguanidine 

Sulfamerazine 

Sulfamerazine, sodium salt 

Sulfamethazine 

Sulfamethoxypyridazine 

Sulfanilanilide 

N-Sulfanilylacetamide (Sulfacetamide) 

N-Sulfanilylacetamide, sodium salt 

Sulfapyridine 

Sulfapyridine, sodium salt 

Sulfaquinoxaline 

Sulfathiazole 



HST, 


PEN. 




CFC, 


PEN. 




LEM. 






DOW, 


HN, HST, MON, 


SDH 


DOW, 


MAL, PEN. 




DOW, 


HN, MON. 




MAI. 






LIL. 






TNC. 






LEM. 






SRL. 






SAL. 






MON. 






GGY. 






MRK. 






HEX. 






MRK. 






LIL. 






HST, 


X. 




PFZ. 






SDW. 






HOP. 






ACY. 






LEM. 






ACY. 






ACY. 






stw. 






HOP. 






HOP. 






ACY. 






HOP. 






ACY. 






SAL. 






SDW. 






LEM, 


MRK. 




MRK. 






ACY. 






ACY. 






ACY. 






ACY, 


PYL. 




ACY. 






ACY, 


PYL. 




ACY. 






LEM, 


SAL. 




LEM, 


SCH. 




LEM, 


SCH. 




ACY, 


MRK- 




ACY, 


MRK. 




MRK. 






ACY, 


LEM, MRK. 





MEDICINAL CHEMICALS 



129 



TABLE 13B. --Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 7963 --Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MEDICINAL CHEMICALS, BENZENOID— Continued 

»Suli"onamideE and sulfones — Continued 
»Sulfa drugs — Continued 

Sulfathiazole, sodium salt 

4.'-(2-Thiazolylsulfamoyl)phthalanilic acid 

[ Sulforylbis(p-phenyleneimino)] dimethanesulf inic acid 
(Sulfoxone), disodium salt. 
*Synipathoiniraetic agents: 

d-N-Benzyl-N , a-dimethylphenethylamine hydrochloride 

3,'i-Dihydroxynorephedrine hydrochloride 

a,a-Diraethylphenethylainine 

*N,^ -Diraethylphenethylamine (Desoxyephedrine) base and 
hydrochloride : 

N,'^ -Dimethylphenethylainine 

1-N,a -Dimethylphenethylamine 

N, a-Dimethylphenethylamine hydrochloride 

d-N,a -Dimethylphenethylamine hydrochloride 

Epinephrine 

m-Hydroxynorephedrine 

m-Hydroxynorephedrine bitartrate 

a-(Isopropylaminomethyl)protocatechuyl alcohol (Iso- 
proterenol) . 
o-Methoxy-N, a -dimethylphenethylamine (Methoxyphenamine ) 
hydrochloride. 

Methylaminoethanoloatechol, raoemic 

a-(l-Methylaminoethyl)benzyl alcohol (Pseudoephedrine) 
hydrochloride. 

a -(l-Methylajninoethyl)benzyl alcohol sulfate 

N-[2-(3,'i-Methylenedioxyphenyl)isopropyl] -a-aminomethyl- 
protocatechuyl alcohol hydrochloride (Caytine). 
»a-Methylphenethylaiiiine (Ajuphetamine and Dextroamphet- 
amine) base and salts: 

a-Methylphenethylamine (Amphetamine) 

a-Methylphenethylamine sulfate 

a-Methylphenethylamine tannate 

d-a-Methylphenethylamine (Dextroamphetamine) 

d-ct-Methylphenethylamine hydrochloride 

d-a-Methylphenethylamine sulfate 

»Norephedrine hydrochloride 

trans-2-Phenyloyclopropylamine sulfate 

l-Phenylephrine base 

Phenylephrine bitartrate 

•Phenylephrine hydrochloride 

2-(i-Thiazolyl)ben2imidazole 

•Tranquilizers : 

1- (p-Chlorobenzhydryl) -'i-[ 2- (2-hydroxyethoxy )ethyl ] 

piperazine (Hydroxyzine) dihydrochloride . 
1- (p-Chlorobenzhydryl ) --i-i 2 - ( 2 -hydroxyethoxy ) ethyl] di - 

ethylenediamine pamoate. 
7-Chloro-l,3-dihydro-l-methyl-5-phenyl-2H-l,A-benzo- 

diazepin-2-one. 
trans-2 -Chloro-N, N-dimethylthioxanthene- a' ' '"-propyl- 
amine (Chlorprothixene) . 
7-Chloro-2-methylamino-5-phenyl-3H-l,4-benzodiazepine- 
•i.'oxide (Chlordiazepoxide) hydrochloride. 

2-(p-Chlorophenyl)-3-methyl-2,3-butanediol 

»Phenothiazine derivatives : 

2-Chloro-10-(3-dimethylaminopropyl)phenothiazine 
(Chlorpromazine) hydrochloride. 



ACY, MRK. 
LEM, MRK. 



SEW. 








HEX. 








HEX, 


PRH. 






ABB. 








GAN, 


HEX, 


PRH. 




ABB, 


GAN, 


HEX. 




SDW. 








SIM. 








X. 








CTN, 


GAN. 






X. 








DOD, 


VB. 






BUR, 


GAN. 






GAN. 








LKL. 








HEX, 


ORT, 


PRR. 




HEX, 


SK. 






PRR. 








HEX. 








HEX. 








HEX, 


PRH, 


SK. 




GAM, 


GAN, 


HEX, 


ICO, NEP, ORT 


X. 








CTN, 


GAN. 






GAN. 








CTN, 


GAN, 


HEX, 


srw. 


MRK. 








PFZ. 








PFZ. 








HOP. 








HOP. 








HOP. 








LIL. 








SK. 









130 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 13B. --Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 7965--Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MEDICINAL CHEMICALS, BENZENOID- -Continued 

♦Tranquilizers- -Continued 

»Phenothiazine derivatives — Continued 

2-Chloro-10-(3-[<V-(2-hydroxyethyl)piperazinyl] - 

propyl) phenothiazine (Perphenazine) . 
2-Chloro-10-[3-(l-methyl-4-piperazinyl)propy]^ pheno- 
thiazine (Prochlorperazine) diraaleate. 
2-Chloro-10-[ 3- (l-methyl-'i-piperazinyl)propyl] pheno- 
thiazine ethanedisulfonate. 

10- (2-Diethylami nop ropyl) phenothiazine 

10-(3-Dimethylaminopropyl)phenothiazine (Promazine) 

hydrochloride. 
10-(2-Dimethylaininopropyl)phenothiazine (Promethazine) 

hydrochloride. 
1- [10-(3-[ 4- (2-Hydroxyethyl) -1-piperazinyl] propyl)- 
phenothiazine-2-yl]-l-propanone (Carphenazine) and 
raaleate. 
N-Methylpiperidyl-3-methylphenothiazine hydrochloride 

hydrate . 
a-('4-Piperidyl)benzhydrol (Azacyolonol) hydrochloride- 
2-Trifluoromethyl-10-(3-diiiiethylaminopropyl)pheno- 

thiazine (Triflupromazine) hydrochloride. 
'4-(3-[2-(Trifluoromethyl)phenothiazin-10-yl]propyl)-l- 
piperazineethanol (Fluphenazine) dihydrochloride . 

Triphosphopyridine nucleotide 

Tropine benzhydryl ether methanesulfonate 

* Vitamins : 

*B2 (Riboflavin) (100^): 

For animal and poultry consumption 

For human consumption 

B6 (Pyridoxine) 

<<Bi2 (100^): 

Feed grade 

Pharmaceutical 

U.S. P. Crystalline 

E (a -Tocopherol) 

E (a-Tocopherol acetate) 

Folic acid 

Ki (2-Methyl-3-phytyl-l,"4-naphthoquinone) 

iiK3 (Menadione) (2-Methyl-l,<i-naphthoquinone) 

K3 (Menadione) (2-Methyl-l,A-naphthoquinone) sodium bi- 
sulfite. 
K4 (2-Methyl-l,<i-naphthalenedlol diacetate and di- 
phosphate, tetrasodlum salt). 

K5 (<i-Aminp-2-methyl-l-naphthol) hydrochloride 

Magnesium nicotinate 

•Niacin (Nicotinic acid): 

Animal feed grade 

Medicinal grade 

•Niacinamide (Nicotinamide) 

Nicotinamide hydrochloride 

Riboflavin-5' -phosphate, monosodlum salt 

Sodium nicotinate 

MEDICINAL CHEMICALS, NONBENZENOID 

2-Aoetamido-5-nitrothiazole 

5-Aoetamido-l,3,'«-thiadiazole-2-sulfonamide 



SCH. 

SK. 

SK. 

NEP. 
WYT. 

WYT. 

WYT. 



BKC. 






OMS, 


SK. 




QMS, 


SCH. 




PBS. 






X. 






COM, 


GPR, 


HOF, MRK, PBS. 


HOF, 


MRK. 




HOF, 


MRK. 




CCM, 


GPR, 


IMC, MRK, PBS. 


IMC, 


MRK. 




MRK. 






CW, 


HOF. 




HOF. 






ACY. 






MRK. 






ABB, 


HET, 


HFT. 


ABB, 


HET, 


vrai. 


HOF. 






PD. 






NEP. 






MRK, 


NEP, 


RIL. 


ABB, 


ACP, 


CKL, MRK, NEP, NOP, RIL, SCR 


MRK, 


NEP, 


PD, RIL, SCR. 


NEP. 






HOF. 






MRK. 







ACY. 
ACY. 



MEDICINAL CHEMICALS 



131 



TABLE 13B. 



■Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i565— Continued 



Manufacturers' identification codes 
(according to list in table 22} 



MEDICINAL CHUnCALS, NONBENZENOID-- Continued 

Acetylcarbromal (l-Acetyl-3-(2-bromo-2-ethylbutyryl)urea)- 

Acetylmethionine 

Acrylic acid copolymer 

Alkaloids and related products: 
Digitalis glucosides: 

Digitonin 

Digi toxin 

Veratrum viride (Alkavervir) 

* Amino acids: 

P -Alanine 

l(+) -Arginine hydrochloride 

Aspartic acid and salts: 

dl-Aspartic acid 

Magnesium hydrogen aspartate 

Potassium hydrogen aspartate 

Glutamic acid and salts: 

l(+) -Glutamic acid 

l(+) -Glutamic acid, calcium salt 

1(+) -Glutamic acid hydrochloride 

1(+) -Glutamic acid, monoaramonium salt 

l(+) -Glutamic acid, monopotassium salt 

Glycine (Aminoacetio acid) 

Glycine hydrochloride 

Histidlne hydrochloride 

l(+) -Lysine hydrochloride 

l(+)-Lysine hydrochloride (feed grade) 

dl -Methionine (except feed grade) 

Methionine, feed grade 

Amino acid mixtures 

2-Amino-5-nitrothiazole 

3-Amino-2-oxazolidinone 

Amyl nitrite (Isoac^yl nitrite) 

"Barbiturates: 

5-Allyl-5-sec-butylbarbituric acid 

5-Allyl-5-(2-cyclopenten-l-yl)barbituric acid and salt — 

5-Allyl-5-isobutylbarbiturio acid and salt 

5-Allyl-5-(l-methylbutyl)barbituric acid (Secobarbital) 

and salt. 
5-Allyl-5-(l-methylbutyl) -5-thiobarbituric acid 

(Surital) . 
dl-5-Allyl-l-methyl-5-(l-methyl-2-pentynyl)barbituric 
acid and salt. 

5-sec-Butyl-5-ethylbarbituric acid 

5-sec-Butyl-5-ethylbarbituric acid, sodium salt 

5-(l-Cyclohexen-l-yl)-l,5-dimethylbarbituric acid 

5-(l-Cyclohexen-l-yl)-l,5-dlmethylbarbituric acid, 
sodium salt. 

5-(l-Cyclohexen-l-yl)-5-ethylbarbitul'ic acid and salt 

5,5-Diethylbarbituric acid (Barbital) 

5,5-Diethylbarbituric acid, sodium salt 

5-Ethyl-5-isoamylbarbituric acid and salt 

5-Ethyl-5-isopropylbarbituric acid and salt 

5 -Ethyl-5-(l-methyl-l-butenyl) barbituric acid 

5-Ethyl-5-(l-methyl-n-butyl)barbituric acid (Pento- 
barbital) . 
5-Ethyl-5-(l-methyl-n-butyl)barbituric acid, sodium salt 
5-Ethyl-5-(l-methyl-n-butyl)-2-thiobarbituric acid and 
salt. 



MLS. 




DOW. 




RSA. 




PEN. 




BUR. 




PEN, 


RIK. 


BFG, 


NOP. 


GNM. 




HEX, 


NAC. 


WYT. 




WYT. 




IMC, 


LEM. 


LM. 




IMC, 


LM. 


IMC. 




IMC. 




BPC, 


DOW. 


EK. 




GNM. 
MRK. 




MRX. 
DOW, 


LEM. 


DOW. 




ABB, 


CUT, STA 


ACY. 




NOR. 
MAL. 




SDW. 




GAN. 




GAN. 




BPC, 


GAN. 



ABB, 


BPC, 


GAN 


ABB, 


BPC, 


GAN 


GAN, 


SDW. 




SDW. 






srw. 






GAN. 






GAN. 






BPC, 


GAN, 


LIL 


BPC. 






X. 






ABB, 


BPC, 


GAN 


ABB, 


BPC, 


GAN 


ABB. 







132 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 13B. 



-Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1963 Continued 



Manufacturers ' identification codes 
(according to list in table 2.2) 



MEDICINAL CHEMICALS, NONBENZENOID— Continued 

»Barbi turates — Continued 

5-Ethyl-5-n-pentylbarbituric acid, sodium salt 

Betaine base 

Betaine hydrate 

Betaine hydrochloride 

»Bile acids and salts: 

Bile salts, natural, conjugated, unoxidized 

Bilirubin 

Cholio acid 

Dehydrocholic acid 

Dehydrocholic acid, sodium salt 

Desoxycholio acid 

Ketocholanio acids 

Mixed oxidized bile salts 

Ox bile extract 

»Bismuth and mercury compounds: 
Bismuth compounds: 

2-Propylvaleric acid, bismuth salt 

Sodium bismuth triglycolamate 

Mercury compounds : 

N - [ 3 - ( Carboxyme thylmercaptomercuri ) -2 -methoxypropyl ] • 
ct-camphoramate, disodium salt. 

3-Chloromercuri-2-methoxypropylurea 

Ethylmercuric chloride 

|3 -Methoxy-c-hydroxymercuric propylamide of camphoric 
acid, sodium salt with theophylline. 

Ifethoxyoxymercuripropylsuccinylurea 

Theophylline methoxymercuripropylsuccinylurea 

Calcium lactophosphate 

Calcium succinate 

■"•Camphor and derivatives: 

Bromocamphor, mono 

■»Camphoric acid 

Camphoric anhydride 

Camphor, synthetic, U.S.P 

Camphosulfonic acid, calcium salt 

"■Carbohydrates and derivatives; 

Aurothioglucose 

Carboxymethylcellulose, sodium salt (medicinal grade) -- 

Cellulose, oxidized 

Dextran 

Fructose (Levulose) 

Galactose 

Glucoheptonic acid, calcium salt 

Gluconic acid salts: 

Ammonium gluconate 

■"Calcium gluconate (including feed grade) 

Copper gluconate 

Iron (ferrous) gluconate 

Magnesium gluconate 

Manganese gluconate 

Potassium gluconate 

Glucosamine hydrochloride 

Maltose 

Methyl glucamine 

Sucrose octa-acetate 

Carbromal (Bromodiethylaoetylcarbamide) 



BPC. 

HFT, LEM. 
HFT. 
HFT, LEM. 

LIL. 
PFN. 

SRL, WIL. 
MRK, WIL. 
WIL. 

MRK, WIL. 
MRK, SRL. 
WIL. 
ABB. 



LKL. 
LIL. 
FIN. 

LKL. 
LKL. 

MAL. 
LEM. 

MAL, PEN. 

FIN, PRE, PYL. 

FIN. 

HNW. 

FIN, PYL. 

SCH. 
CBP. 
EKT. 
PHR. 
DLL 
PFN. 
PFN. 

PFZ. 

MAL, PFZ, WHL. 

PFZ. 

PFZ. 

PFZ. 

PFZ. 

PFZ. 

PFZ. 

PFN. 

ABB. 

PD. 



MLS, PD. 



MEDICINAL CHEMICALS 



133 



TABLE 13B. 



-Medicinal chemicals for which U.S. production or sales were reported, identified by- 
manufacturer, i 965 --Continued 



MEDICINAL CHEMICALS, NONBENZENOID- -Continued 

2-Chlorothiophene 

p-Chlorovinylethylethynylcarbinol 

»Choline derivatives : 

Acetylcholine bromide 

Acetylcholine chloride 

Acetyl-p-methyloholine chloride 

Choline bicarbonate 

♦Choline bitartrate 

♦Choline chloride: 

Feed grade 

Medicinal grade 

Technical grade 

♦Choline dihydrogen citrate 

♦Succinylcholine dichloride 

Trioholine citrate 

Coenzyme A 

Cyclopentyl bromide 

l-Cyclopentyl-2-methylpropylamine (Cyclopentamine) hydro- 
chloride . 

Diallylacetic acid 

Diethylaminocarbethoxybioyclohexyl (Dicyclomine) hydro- 
chloride. 
Diethyl(2-hydroxyethyl)inethylaiiimoniujii bromide, a-cyclo- 
pentyl-2-thiopheneglycolate . 

3,3-Diethyl-5-methyl-2,'4-piperidinedione 

3,5-Diiodo-i-pyridone-N-acetic acid, diethanolamine salt- 

2-DimethylamlnoethanOl bitartrate 

N, a-Dimethylcyclohexaneethylamine (l-Cyclohexyl-2-methyl- 
aminopropane) (Propylhexedrine). 

Di vinyl ether 

Ethyl carbamate (Urethane) 

2-Ethyl-cis-crotonyl urea 

5-Ethyl-3,5-diniethyl-2,';-oxazolidinedione 

Ethj-lenediamine diiodide 

Ethyl iodide 

2-Ethyl-2-methylsuecinimide 

Ethyl nitrite 

l-Ethyl-3-(5-nitro-2-thiazolyl)urea 

Ethynylcyclohexyl carbamate 

Glutathione (oxidized) 

Hendecenoic (Undecylenic) acid, zinc salt 

Heparin sodium 

Hexajnethyldiaminoisopropanol diiodide 

HexamethylenebisCtrimethylammonium chloride) (Hexa- 
methonium chloride) . 

Hexamethylenetetramine 

Hexokinase 

•Hormones : 

17a-Acetoxy-6a-methylprogesterone 

17a-Acetoxyprogesterone 

3-(7a-Acetylthio-17g-hydroxy-3-oxo-';-androsten-17a-yl) 
propionic acid-Y-lactone. 

Adrenocorticotropic hormone (ACTH) 

Dehydroisoandrosterone alcohol 

21-DesOxy-9a-fluoro-6Dc-methylpredm.solone 

Dexamethasone 

Dexamethasone acetate 



Manufacturers ' identification code 
(according to list in table 22) 



EK. 

MRK. 

RSA. 

cm, HFT. 

ACy, CFC, HFT. 

CCM, HFT. 

CFC, HFT. 

DLI, JCC, RH. 

ACY, CFC, HFT. 

ABB, BUR, CTN, SOT. 

ACY, HFT. 

PBS. 

LIL. 

LIL. 



HOF. 




SDW. 




X. 




SK. 




MRK. 




FMP. 




MLS. 




ABB. 




FYL, 


TNG, WHL 


FMT, 


RSA. 


PD. 




MAL. 




MRK. 




LIL. 




SBR. 




LEM, 


MCO. 


ABB, 


RIK. 


SDW. 




NEP, 


RSA. 



JUL. 
JUL. 
SRL- 

ARP, ORG, WIL. 

JUL. 

UP J. 

MRK, SCH. 

SCH. 



134 



SYNTHETIC ORGANIC CHEMiCALS, 1963 



TABLE 13B. --Medicinal chemicals for which U.S. production or sales aiere reported, identified by 

manufacturer, i 965- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MEDICINAL CHEMICALS, NONBENZENOID--Continued 

»Hormones — Continued 

9a,llp-Dichloro-17a,21-dihydroxypregna-l,4-diene-3,20- 
dione, 21-acetate. 

Dienediol 

17a, 21-Dihydroxy-<i-pregnene-3,20-dione 

17o, 21-Dihydroxy-<i-pregnene-3,20-dione, 21-acetate 

17a-Ethynyl-17|3-hydroxy-5(10)-estren-3-one (Norethyno- 
drel). 

9a-Fluorohydrocortisone acetate 

9a- Fluoro-iep -methyl-lip , 17 a, 21-trlhydroxypregna-l, <;- 
diene-3 , 20-dione . 

9a-Fluoroprednisolone 

Fluoxymesterone 

^Hydrocortisone alcohol and acetate 

Hydrocortisone diethylaminoacetate hydrochloride 

17-Hydroxy-ll-dehydrocorticosterone (Cortisone) and 
acetate. 

17p-Hydroxy-17a-methylandrostano[3,2-c]pyrazole 

17-Hydroxy-4-pregnene-3, 20-dione 

lla-Hydroxyprogesterone 

Methylprednisolone 

Methyltestosterone 

Prednisolone 

Prednisolone acetate 

^Prednisone 

Progesterone 

Testosterone 

Triamcinolone 

Trienediol 

Hydantoin derivatives: 

*Allantoin 

N-(5-Nitro-2-furfurylidene)-l-aminohydantoin 

tranE-[4-(Hydroxydi-2-thienylmethyl)cyolohexyl]trimethyl- 
ammonium bromide. 

l-(2-Hydroxyethyl)-2-methyl-5-nitroimidazole 

2-Hydroxy-'i-methylisobutyrio acid, calcium salt 

2-Hydroxy-4-(methylthio)butyric acid, calcium salt 

<4.,5-Imidazoledicarboxamide (Glycarbylamide) 

2-Iodoetliyl-1.3-dioxolane-<i-methanol 

lodomethanesulfonic acid, sodium salt 

Iron (ferrous) oxalate 

Lecithin, purified 

Magnesium citrate 

2-Mercapto-l-methylimidazole 

2-Methyl-2-propyl-l,3-propanediol 

5-Nitro-2-furaldehyde acetylhydrazone 

5-Nitro-2-furaldehyde dlacetate 

5-Nitro-2-furaldehyde semicarbazone 

5-Nitro-2-furaldehyde semioxamazide 

3-[(5-Nitro-2-furfurylidene)ajiiino]-2-oxazolidinone 

Nucleic acid 

Nucleic acid salts 

[ 2-(0ctahydro-l-azocinyl)ethyl]guanidine sulfate 

Pantolactone, racemic 

Phytic acid 

Pl^rtic acid, calcium salt 

»Plperazlne and derivatives : 

N-Aminoethylpiperazine 

l-W.ethyloarbanorl-'V-methylpiperazine dihydrogen citrate-' 



SCH. 

UP J. 
JUL. 
JUL. 
SRL. 

UP J. 
SCH- 

UP J. 

UP J. 

MRK, PFZ, UP J. 

PFZ. 

MRK, UP J. 

SDW. 

SCH. 

UP J. 

UP J. 

JUL. 

MRK, SCH, UP J. 

SCH. 

MRK, SCH, UPJ. 

JUL, X. 

JUL. 

ACY, (MS. 

UPJ. 

CTN, FIN, HFT, SCL. 

NOR. 

SCH. 

RDA. 
MON. 
DUP. 
MRK. 

X. 

SOT. 

BKL. 

ARP. 

MAL. 

LIL. 

ABB. 

NOR. 

NOR. 

NOR. 

NOR. 

NOR. 

SBR. 

SBR. 

CBP. 

ABB, CKL, NOP. 

STA. 

STA. 

UCC. 
ACY. 



MEDICINAL CHEMICALS 



135 



TABLE 13B. --Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MEDICINAL CHEMICALS, NONBENZENOID— Continued 

»Plperazine and derivatives — Continued 

Dime thy lajiiinoethyl-<i-me thy Ipiperazine 

Methyl-N-methyl-N-piperazine acetate 

N-Methylpiperazine 

»Piperazine 

Piperazine adipate 

Piperazine calcium ethylenediamine tetraacetate (Perin) 

Piperazine citrate 

Piperazine dihydrochloride 

Piperazine hexahydrate 

"Piperazine hydrochloride 

»Piperazine phosphate 

Piperazine sulfate 

Piperazine tartrate 

Propylene glycol diacetate 

2-Propyl valeric acid 

*Purine derivatives: 

Adenosine 

Adenosine-5-phosphoric acid 

Adenosinetriphosphoric acid 

Adenosinetriphosphoric acid, salt 

Adenylic acid 

»Caffeine: 

Natural 

Synthetic 

Caffeine citrate 

6-Chloropurine 

6-Mercaptopurine 

Theobromine, sodium acetate 

Theophylline (1,3-Dimethylxanthine) and derivatives: 

Theophylline aminoisobutanol 

Theophylline, anhydrous 

Theophylline cholinate 

•Theophylline ethylenediamine (Aminophylline) 

Theophylline ethylenediamine, sodium biphosphate 

Theophylline magnesium 

Theophylline monoethanolamine 

Theophylline sodium acetate 

Uric acid and derivatives 

Sitosterol B 

Sodium succinate 

Sodium tartrate 

Sulfosuccinic acid, bis(2-ethylhexyl) ester 

Terpinol hydrate 

Tetraethylammonium chloride 

Tetramethylammonium chloride 

Tetramethylammonium hydroxide 

Thiosemicarbazide 

•Tranquilizers : 

2-Methyl-2-sec-butyl-l,3-propanediol dicarbamate 

2-Methyl-2-n-propyl-l,3-propanediol dicarbamate 
(Meprobamate) . 
»Trihalogenated compounds: 

Bromof orm (Tribromomethane) 

Chloretone (tert-Trichlorobutyl alcohol) 

Iodoform 

2,2,2-Tribromoethanol 

3,5,5-Trtmethyl-2,'i-oxazolidinedione 



ABB. 








UCC. 








DOW, 


JCC, 


UCC, 


X. 


JCC, 


PYL. 






EN. 








JCC, 


LEM, 


RDA. 




ACY, 


DOW, 


JCC, 


PYL. 


JCC, 


RDA. 






DOW, 


JCC, 


RDA, 


WHL. 


BUR, 


JCC, 


PYL, 


RDA, WHL 


JCC, 


RDA. 






PYL, 


RDA. 






X. 








X. 








PBS, 


SBR. 






PBS, 


SBR. 






SBR. 








PBS, 


SBR. 






SBR. 








GNF, 


MYW. 






MON, 


PFZ. 






MAL, 


MRK. 






BUR. 








BUR. 








MAL. 








GAN. 








LEM. 








NEP. 








GAN, 


LEM, 


SRL. 




GAN. 








MAL. 








LIL. 








MAL. 








SCL. 








UP J. 








PEN. 








MAL. 








ACY. 








PEN. 








RSA. 








ASL, 


EK,- 


RSA. 




RSA. 








FMT. 









ABB, BKL, ICO, PEN, x. 



DOW. 
BPC, 
MAL, 
SD*. 
ABB. 



PD. 
PEN. 



136 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 13B. 



■-Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer. 7965 --Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MEDICINAL CHEMICALS, NONBENZENOID--Continued 

3-Tropanol (Tropine) 

»Uraoil derivatives; 

6-Propyl-2-thiouracil 

Thymidine 

Thymine 

Uridine 

Uridine triphosphate 

l-Vinyl-2-pyrrolidinone iodine complex polymer 

»Vitamins: 

»A, from all sources; 

A acetate 

A acetate (feed grade) 

A alcohol 

»A palmitate 

A palmitate (feed grade) 

Bi (Thiamin hydrochloride) 

Bi (Thiamin nitrate) 

Biotin 

•»C (Ascorbic acid) and derivatives: 

^Ascorbic acid 

Ascorbic acid, calcium salt 

Ascorbic acid, sodium salt 

Ascorbyl palmitate 

p -Carotene 

*D2 (Irradiated ergosterol) 

D3 (Irradiated animal sterol) 

Inositol 

♦Pantothenic acid and derivatives; 

Pantothenic acid 

Pantothenic acid, dl-calcium chloride complex 

Pantothenic acid, d-calcium salt 

♦Pantothenic acid, dl-calcium salt 

Pantothenic acid, sodium salt 

d-Pantothenyl alcohol (a, Y-Dihydroxy-N-(3-hydroxy' 
propyl) -)3,fi-dimethylbutyramide) . 

dl-Pantothenyl alcohol 

Provitamin D3 (7-Dehydrocholesterol) 



PYL. 






SBR. 






ACY. 






PBS, SBR 






PBS, SBR 






G. 






EF, HOP, 


PFZ. 




HOP. 






CW, HOP. 






EK, HOP, 


MRK, 


PFZ. 


EK, HOP. 






HOP, MRK 






HOP, MRK. 






HOP. 






HOP, MRK, 


PFZ. 




PFZ. 






HOP, MRK, 


PFZ. 




PPZ. 






HOP. 






DLI, SCR, 


VTM. 




DLI, JUL, 


NOP, 


VTM. 


STA. 






DLI. 






NOP. 






ACY, MRK, 


X. 




ABB, CKL, 


HPT, 


MRK, NOP, PRR 


PD. 
HOP. 






HOP. 
JUL. 







FLAVOR AND PERFUME MATERIALS 



137 



Flavor and Perfume Materials 



TABLE 14B. 



-Flavor and perfume materials for which U.S. production or sales were reported, identified by 
manufacturer, 1963 



[Flavor and perfume materials for which separate statistics are given in table lAA are marked below with an asterisk 
(*); those not so marked do not appear in table 14A because the reported data are accepted in confidence and may 
not be published. XJanufacturers' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Manufacturers' Identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIALS, CYCLIC 

Bfnzenoid and ^aphthalenold 

2'-Acetonaphthone (Methyl f!-naphthyl ketone) 

Aeetophenone 

7-Acetyl-6-ethyl-l,l,'i,'i-tetramethyl-l,2,3,4-tetrahydro- 
naphthalene. 

p-Allylanlsole 

Allyl phenoxyacetate 

•i-Allylveratrole (Eugenyl methyl ether) 

•Anethole (p-Propenylanisole) 

«p-Anisaldehyde (p-Methoxybenzaldehyde ) 

Anisole (Methyl phenyl ether) 

Anlsyl acetate 

Anisyl alcohol 

»Benzophenone 

*Benzyl acetate 

♦Benzyl alcohol 

Benzyl benzoate 

Benzyl butyrate 

*Benzyl clnnamate 

Benzyl ether 

Benzyl formate 

Benzyl glyceryl acetal 

Benzylidene acetone 

Benzyl isoeugenyl ether 

Benzyl Isopentyl ether 

Benzyl phenylacetate (Benzyl a-toluate) 

»Benzyl propionate 

Benzyl salicylate 

a-Bronoetyrene 

4'-tert-Butyl-2',6'-dimethyl-3' ,5'-dinitroacetophenone 

(Uxsk ketone ). 
6-tert-Butyl-3-methyl-2,'i-dinitroanl8ole (kJusk ambrette )-- 
p-tert-Butyl-a-methylhydroclnnamaldehyde (a-Methyl-p-(p- 

tert-butylphenyl )proplonaldehyde ). 
5-tert-Butyl-l,2,3-trlmethyl-4,6-dlnltrobenzene (5-tert- 
Butyl-4,6-<linitrohemliiiellltene ) . 

5-tert-Butyl-2,'4,6-trinitro-m-xylene (lAisk xylol) 

Carvacrol (2-p-Cymenol ) •' 

•Cinnamaldehyde 

Clnnamic acid 

Clnnanyl acetate — — • 

^^^.^Tmomy^ alcohol 

Clnnanyl anthranllate 

c iimaniy i cinnai&ate 

Clnnamyl fomiate 

Clnnanyl Isovalerate 

Clnnangrl propionate 

trans-Dec ahydro-2-naphthol 

p,a-Dlinethylben2yl alcohol (p-lfethylphenylmethyloarbinol)- 

«o,a-DiiBethylphenethyl acetate 

a,a-Dliiietl^lphenethyl alcohol 

a,a-Dlji>ethyl-3-phenyl-l-propanol 



GIV, 


TBK. 








GIV, 


TBK. 








GIV, 


TBK. 








GIV. 










GIV. 










FB, 


GIV, 


ICO, 


TBK. 




FB, 


OLD, 


HNW, 


HPC, 


UNG. 


GIV, 


ICO, 


OPC 


TBK, 


UNG. 


GIV. 










GIV, 


TBK. 








GIV, 


TBK. 








G, GIV, ICO, NEC, TBK. 


GIV, 


OPC, 


RDA 


SHL, 


TBK, X. 


BPC, 


GIV, 


OPC 


SHL, 


TBK, TNP 


MON, 


OPC, 


TBK 


TNP. 




FB, 


TBK. 








FB, 


GIV, 


ICO, 


TBK. 




OPC, 


SHL. 








TBK. 










GIV. 










FB. 










GIV, 


TBK. 








GIV. 










GIV, 


TBK. 








FB, 


GIV, 


TBK. 






GIV, 


TBK. 








TBK. 










GIV. 










GIV. 










GIV, 


TBK. 








GIV. 










GIV. 










GIV. 










FB, 


OPC, 


RDA, 


TBK. 




BPC. 










FB, 


GIV, 


TBK. 






FB, 


GIV, 


NEO, 


TBK. 




FEL, 


GIV, 


RT. 






TBK. 










TBK. 










TBK. 










FB. 










IFF. 










CIV. 










GIV, 


IFF 


RDA 


TBK. 




IFF. 










IFF, 


TBK. 









-026 O - 64 - 10 



138 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 14B. --Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIAIS, CYCLIC— Continued 
Bcmenoid and N<'phthaUnoid--Canttnue<i 

^,6-Dinitro-l,l, 3,3,5-pentamethylindan 

Diphenylme thane 

l,3-Diphenyl-2-propanone (Dibenzyl ketone) 

6-Ethoxy-m-anol (Propenyl methylguaethol) 

»2-Ethoxynaphthalene (Ethyl p-naphthyl ether) 

Ethyl anisate 

Ethyl anthranilate 

Ethyl benzoate 

Ethyl cinnamate 

Ethyl cijp-epoxy-p-methylhydrocinnainate 

2-Ethylhexyl salicylate 

Ethyl 3-phenylglycidate 

Ethyl salicylate 

Ethyl vanillin 

«Eugenol i - 

Eugenol acetate 

Geranyl benzoate 

Hexylcinnamaldehyde 

Itydratropaldehj'de (a-Phenylpropionaldehyde ) 

}fydratropaldehyde, dimethyl acetal 

Ify^drocinnamaldehyde (3-Phenylpropionaldehyde) 

2-H(fdroxypropyl p-N, N-bis(2-hydroxypropyl )aininobenzoate — 

Isobutyl cinnamate 

"■Isobutyl phenylacetate ( Isobutyl a -toluate ) 

»lsobutyl salicylate 

*Isoeugenol 

Isoeugenyl acetate 

*Isopentyl salicylate (Amyl salicylate) 

p-Isopropylbenzaldehyde (Cumaldehyde ) 

p-Isopropylcyclohexanol 

»p-Isopropyl-a-methylhydrocinnamaldehyde (Cyclamen aldehyde) 

-i' -Methoxyaoetophenone 

2-Methoxynaphthalene (Methyl P-naphthyl ether) 

^-(a-Methoxyphenyl )butanone 

'V'-Methylacetophenone (Methyl p-tolyl ketone) 

p-Methylanisole (p-Cresyl methyl ether) 

*Methyl anthranilate 

Methyl benzoate 

a-Methylbenzyl acetate 

p-Methylbenzyl acetate 

ct-Methylcinnamaldehyde 

«Methyl cinnamate 

Methyl N-methylanthranilate (Dimethyl anthranilate) 

i<Methyl phenylacetate (Methyl a-toluate) 

»Methyl salicylate (Synthetic wlntergreen oil) 

*a-Pentylclnnamaldehyde (:i-Aniylcinnamaldehyde) 

»Phenethyl acetate 

Phenethyl alcohol 

Phenethyl formate 

Phenethyl isobutyrate 

Phenethyl isovalerate 

Phenethyl methacrylate 

*Phenethyl phenylacetate ( Phenethyl a -toluate ) 

Phenethyl salicylate 

2-Phenoxyethyl isobutyrate 

Phenylacetaldehyde (a -Tolualdehyde ) 



GIV. 

TBK. 

GIV. 

SHL. 

GIV, 

ICO. 

FB, 

TBK. 

GIV, 

GIV, 

FEL. 

GIV, 

TBK. 

MON, 



ICO, TBK. 
FMT. 



TBK. 
TBK. 



RDA. 



FB, GIV, ICO, LUE, NEC, PEN, TBK, UNG, VLY. 

GIV. 

GIV. 

GIV, 

GIV, 

GIV. 

TBK. 

SHL. 

TBK. 

FB, 

FB, 

FB, 

TBK 

FB, 

GIV, 

GIV, 

GIV, 

GIV 

GIV 

TBK, 

TBK, 

GIV, 

FB,' 

HN. 

GIV 

ICO 

FB, 

FB, 

GIV 

GIV 

CFC' 

FB, 

GIV 

GIV, 

iff! 

GIV 
FB.' 
GIV, 
GIV, 
TBK. 
GIV, 
GIV, 



IFF, TBK. 
IFF. 



GIV, TBK. 

GIV, TBK. 

GIV, SHL, TBK, VLY. 

GIV, ICO, OPC, TBK. 



OPC, RDA. 

ICO. 

TBK. 



TBK. 
GIV, MEE, OPC, SHL, UNG. 



TBK, 
IFF. 
GIV, 
ICO, 
OPC. 
OPC, 
DOW, 
GIV, 
IFF, 
IFF, 



VLY. 
TBK. 

TBK. 

HN, MON, PEN. 
IFF, NEO, RDA, TBK, VLY. 
NEO. 
OPC. 



IFF, TBK. 



IFF. 
IFF, TBK. 



TBK. 
TBK. 



FLAVOR AND PERFUME MATERIALS 



139 



TABLE 14B. — Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



FLAVOR AND PERFIME MATERIALS, CYCLIC— Continued 
Penzenoid and haphthalenoid--Cont±nxe(i 

Phenylacetaldehyde, dimethyl acetal 

o-Phenylanisole (2-Methoxybiphenyl) 

3-Phenyl-l-propanol (Hydrocinnamic alcohol) 

3 -Phenyl -1 -propyl acetate 

5-Propenyl-2-ethoxyphenol (Propenylguaethol) 

»4-Propenylveratrole (Isoeugenyl methyl ether) 

p-Propylanisole 

Styrolyl acetate 

l,2,3,6-Tetrahydro-2,3,5-triniethylben2aldehyde 

p-Tolualdehyde (p-Methylbenzaldehyde) 

p-Tolyl acetate (p-Cresyl acetate) 

p-Tolyl isobutyrate (p-Cresyl isobutyrate) 

p-Tolyl phenylacetate (p-Cresyl a- toluate) 

a-(Trichloromethyl )benzyl acetate (Rosetone) 

Vanillin 

All other 

Terpenoid, Heterocyclic, and AUcyclic 

Allyl cyolohexyl propionate 

Allyl ionone 

Aniyris acetate 

Bornyl acetate 

4-tert-Butylcyclohexanol 

■i-tert-Butylcyclohexyl acetate 

Cadinene . 

Carvone (Carvol) 

Caryophyllene 

Cedranone 

Cedrenol 

*Cedrol 

«Cedryl acetate 

<K;itral (Geranial) 

Citral dimethyl acetal 

Citronellal 

■»Citronellol 

"Citronellyl acetate 

Citronellyl butyrate 

«Citronellyl formate 

Citronellyl isobutyrate 

Citronellyl oxyacet&ldehyde 

Citronellyl propionate 

»Coumarin 

Cyclohexadecanolide 

Cyclohexylcyclohexanone 

Cyclopentanol 

Cyclopentanone 

Dihydrogeraniol 

Dihydroterpinyl acetate 

•Essential oils, chemically modified: 

Cedarwood acetate 

Citronella oil, acetone condensation product 

Ethyl oxyhydrate 

Gufliacwood acetate 

Lavandin, acetylated 

Oil clove stem, acetylated 

Sassafras oil, hydrogenated 

a-Furfural mercaptan 



GIV, TBK. 






GIV. 






FB, GIV, TBK. 






GIV. 






ICO. 






GIV, ICO, TBK 






GIV. 






FB. 






IFF. 






HN. 






GIV, IFF. 






IFF. 






GIV, TBK. 






ICO, TBK. 






MDN, SLV. 






FB, GIV, X. 






GIV. 






GIV, IFF. 






GIV, TBK. 






FEL. 






IFF. 






DOW, IFF. 






FB. 






FB, FRM, OPC. 






FB, GIV. 






TBK. 






GIV. 






GIV, IFF, TBK 


UNO 




GIV, IFF, NEC 


TBK 


UNG. 


FB, FEL, GIV, 


LUE, 


NEO, RT, TBK 


GIV. 






GIV, IFF, TBK 






FB, GIV, GLD, 


IFF, 


TBK, VLY. 


GIV, IFF, TBK 






an. 






FB, GIV, IFF, 


TBK. 




IFF, TBK. 






IFF, TBK. 






GIV. 






DOW, MDN, NEO, 


RDA 


TBK. 


IFF. 






GIV. 






ARA. 






ARA. 






ICO. 






GIV. 






FB. 






CP. 






FEL, FLO, LUE, 


RT, 


VND. 


FB, GIV, TBK. 






FEL. 






FB. 






GIV. 






RT. 







140 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 14B. --Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer, i 963-- Continued 



Mamif acturers ' identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued 
Terpenoid, Heterocyclic, and 4iicycHc--Contlnued 

•tGeraniol 

«Geranyl acetate 

Geranyl butyrate 

»Geranyl formate 

Geranyl isovalerate 

Geranyl phenylacetate (Geranyl :i-toluate ) 

2-Hexyl-2-cyclopenten-l-one 

«Hydrocoumarin (3,4-Dihydrocoumarin) 

♦Hydroxycitronellal 

"Hydroxycitronellal, dimethyl aoetal 

'4-('4-Hydroxy-'V-methylpentyl)-3-oyclohexene-l-carboxalde- 

hyde. 
Indole 

■»Ionones : 

a-Ionone 

P -lonone 

lonone (a- and p-) 

Isoborneol (Isobornyl alcohol) 

»Isobornyl acetate 

Isobutylquinoline 

Isomenthone 

Isopropylquinoline 

Isopulegol 

Isosafrole 

d-Limonene 

«Linalool 

*Linalyl acetate 

Linalyl anthranilate 

Linalyl benzoate 

Linalyl cinnamate 

Linalyl isobutyrate 

Linalyl propionate 

p-Menth-l-en-3-one 

•Menthol, synthetic: 

Tech 

U.S.? 

Menthone 

Menthyl acetate 

6-Methylcoumarin 

■"Methylionones : 

«Methyl-ix-ionone 

*Methyl-|3-ionone 

»Methylionone (a- and P-) 

*Methyl-Y-ionone 

*Methyl-5-ionone 

»Nerol 

Nopyl acetate 

p-tert-Pentylcyolohexanone 

Phellandrene 

•Piperonal (Heliotropin) 

Piperonal, sodium bisulfite complex 

Pseudolinalyl acetate (Ktyrcenyl acetate, principally)-- 

»Rhodinol 

Rhodinyl acetate 

Rhodinyl formate 

Safrole 

Santalol 

Santalyl acetate- -i 



FB, 

FEL, 

FMT, 

GIV, 

FB. 

GIV, 

IFF. 

GIV, 

GIV, 

FB, 

IFF. 



GIV, 
MYW, 
GIV, 
RDA, 
FB, 
FMT, 
GIV, 
FMT. 
GIV, 
GIV, 
RT, 
FB, 
DOW, 
FMT, 
FMT, 
TBK. 
TBK, 
FB, 
GIV. 

GIV, 
GIv' 
GIV, 
FB, 
GIV. 

GIV, 

iff! 

GIV, 
TBK. 
TBK. 
FB, 
SHL, 

X. 

ICO. 
GIV, 
SHL, 
IFF. 
FB, 
FB, 
GIV. 
GIV. 
GIV, 
GIV, 



FEL, GIV, GLD, IFF, NEO, TBK, VLY. 
GIV, IFF, NEO, TBK, VLY. 
GIV. 
TBK, VLY. 

TBK. 

ICO, OPC, TBK. 
IFF, OPC, TBK, VLY. 
GIV, TBK. 



MYW, TBK. 
NEO, TBK. 
IFF, LUE, MYW, NEO, TBK. 

GIV, OPC, RDA, TBK, UNG. 
IFF. 
TBK. 



FEL, GIV, GLD, HOF, IFF, NEO, TBK, UNG. 
FB, GIV, GLD, HOF, LUE, NEO, SHL, TBK, UNG. 



ICO. 

GLD, HNW, NEO. 
HNW, NEO. 
GIV. 



IFF, MYW, NEO. 

TBK. 

LUE, MYW, TBK, UNG. 



GIV, GLD, IFF, TBK, VLY. 
VLY. 



NEO, SHL, TBK. 



FEL, GIV, IFF, LUE, RDA, SHL, UNG. 
GIV, IFF. 



FLAVOR AND PERFUME MATERIALS 



141 



TABLE 14B.- 



■ Flavor and perfume materials for which U.S. production or sales were reported, identified by 
manufacturer, 7965— Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued 
Terpenoid^ Heterocyclic, and 4HcycHc--Contlnued 

^Sweeteners , synthetic: 

Cyclohexanesulfajnic acid 

Cyclohexanesulfamic acid, calcium salt 

Cyclohexanesulfajnic acid, sodium salt 

Saccharin 

Saccharin, calcium salt 

Saccharin, sodium salt 

»Terpineols : 

a-Terpineol 

P-Terpineol 

Terpineol (a- andg-) 

Terpinol hydrate (Terpln hydrate), tech 

■iTerpinyl acetate 

Terpinyl propionate 

Tetrahydro alloocimenol 

3,5,5-Trimethylcyclohexanal 

3,5,5-Trimethylcyclohexanol 

Vertofix (Acetyl cedrene, principally) 

Vetivenol 

»Vetivenyl acetate 

All other 

FLAVOR AND PERFUME MATERIALS, ACYCLIC 

Allyl heptanoate (Allyl enanthate) 

»Allyl hexanoate (Allyl caproate) 

Allyl isothiocyanate (Synthetic mustard oil) 

Allyl sulfide (Diallyl sulfide) 

Butyl butyrate 

Butyl isovalerate 

Butyrone (Di-n-propyl ketone) 

Butyroyl butyl lactate 

»Decanal (Capraldehyde) (Cio) 

Diethyl sebacate (Ethyl sebacate) 

Diethyl succinate 

Diethyl tridecanedioate (Ethylene brassy late) 

3,6-Dimethyl-3-octanol 

3,7-Dlmethyl-l-octanol 

3,7-Dimethyl-3-octanol 

Dimethyl succinate 

»Ethyl butyrate 

Ethyl decylate 

Ethyl heptanoate (Ethyl enanthate) 

»Ethyl hexanoate (Ethyl caproate; 

Ethyl isovalerate 

Ethyl laurate 

Ethyl levulinate 

Ethyl nonanoate (Ethyl pelargonate) 

Ethyl octanoate (Ethyl caprylate ) 

Ethyl pentanone 

■xGlutamic acid, monosodium salt (Monosodium glutamate)-- 

Heptanal (Enanthaldehyde) (C7) 

Heptyl alcohol (Heptanol) 

Heptyl ether (Enanthic ether) 

cis-3-Hexen-l-ol 

Hexyl octanoate (Hexyl caprylate) 

cis-3-Hexyn-l-ol 

^-Hydroxy-2-butanone (Acetoin) 



ABB, NRS, 


PBY. 


ABB, NRS, 


PBY. 


MEE, WU. 




MEE, X. 




MEE, M3N. 




GLD, HNW, 


HPC. 


HNW. 




GIV, NEO. 




HPC. 




GIV, HNW, 


OPC, RDA, TBK. 


GIV, TBK. 




X. 




OPC. 




ICO. 




X. 




GIV, TBK. 




FB, GIV, 


IFF, NEO, TBK, VLY 



DOW 


FB, TBK. 


DOW 


FB, GIV, TBK. 


ICO 


MRT, OPC. 


RT. 




TBK. 




TBK. 




TBK. 




ICO. 




GIV 


IFF, TBK. 


FEL 


TBK. 


UCC. 




RDA, 


VLY. 


AIR. 




GIV, 


TBK. 


GIV. 




ICO. 




FB, 


NW, RT, TBK. 


TBK. 




FEL, 


TBK. 


FB, 


NW, TBK. 


FB, 


TBK. 


FB. 




IFF. 




FB, 


TBK. 


FB. 




GIV. 




COM, 


GRW, HPC, IMC, MRK, PFZ 


BAC. 




BAC, 


UCC. 


TBK. 





142 



SYNTHETIC ORGANIC CHEMICALS. 1963 



TABLE 14B. Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



FLAVOR AND PERFIME MATERIA1£, ACYCLIC— Continued 

"i-Hydroxynonanoio acid, Y-l3°'''°"^ (y-Nonalactone) 

•4-Hydroxyoctanoic acid, Y-laotone (Y-Octalactone) 

•»4-I^droxyundecanoic acid, y -lactone (Y-Undecalactone)- 
Isobutyl acetate 

"Isopentyl butyrate (Amyl butyrate) 

Isopentyl formate (Amyl formate) 

Isopentyl heptanoate (Amyl caproate) 

Isopentyl isovalerate (Amyl isovalerate) 

Isopentyl propionate 

»Lauraldehyde (Dodecyl aldehyde) (C12) 

6-Methyl-5-hepten-2-one 

Methyl isovalerate 

2-Methylundecanal (2-Methylnonylacetaldehyde ; 

h/5yrist aldehyde 

Nonanal ( Pelargonaldehyde ) (C9, 

Nonanediol monoacetate 

Nonanol 

Nonyl acetate 

Nonynol acetate, isomeric (Tepyl acetate; 

Octanal (Caprylaldehyde) (Cb) 

Octanol 

Octyl acetate 

Octyl isobutyrate 

Ootyl salicylate 

Omega decenol 

Pentyl propionate (Amyl propionate) 

Tepyl acetate 

Trimethylhexanal , sodium bisulfite complex 

3,5,5-Trimethylhexyl acetate 

Trimethylundecenal 

2,6,10-Trimethyl-9-undecen-l-ol 

Undecanal (Hendecanaldehyde) (On, 

2-Undecanone (Methyl nonyl ketone; 

Undecenal (Hendecenaldehyde) 

10-Undecen-l-ol 

Valerolactone 

All other 



QIV, 


TBK. 




GIV, 


TBK. 




FB, 


GIV, 


TBK. 


FB. 






FB, 


GIV, 


NW, RT, TBK 


FEL, 


TBK. 




FEL. 






FB, 


TBK. 




FB. 






GIV, 


IFF, 


TBK. 


GIV, 


TBK. 




FB. 






GIV, 


TBK. 




GIV. 






GIV, 


TBK. 




GIV. 






TBK 






TBK. 






IFF. 






GIV, 


IFF, 


TBK. 


GIV. 






FB, 


TBK. 




FB, 


ICO. 




FB. 






X. 






GIV. 






TBK. 






SHL. 






OPC. 






VPC. 






GIV. 






GIV, 


TBK. 




GIV. 






GIV, 


TBK. 




GIV. 






GIV. 






GIV, 


TBK. 





PLASTICS AND RESIN MATERIALS 



143 



Plastics and Resin Materials 



TABLE 15B.-- Plastics and resin materials for which U.S. production or sales were reported, identified by 

manufacturer , 1963 

[plastics and resin materials for which separate statistics are given in table 15A are marked below with an asterisk 
(»); chemicals not so marked do not appear in table 15A because the reported data are accepted in confidence and 
may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that 
the manufacturer did not consent to his identification with the designated product] 



Material and use 



Manufacturers ' identification codes 
(according to list in table 22) 



THERMOSETTING RESINS 



»Alkyd resins: 

Protective coatings: 
•Phthalic anhydride type- 



»Polybasic acid type 

»A11 other uses 

»Coi imn rone - indene and petroleum polymer resins: 

•Floor tile 

♦Rubber compounding 

*A11 other uses 

«Epoxy resins: 
Unmodified: 

♦Bonding and adhesives 

♦Protective coatings 

♦Reinforced plastics 

♦All other uses 

♦Jtodified — 



♦Polyester resins: 

Reinforced plastics: 
♦Sheets, flat and corrugated 

♦All other 

♦Surface coatings 

♦All other uses 

♦Silicone resins 

♦Phenolic and other tar acid resins: 
♦Molding materials 

Bonding and adhesive resins for: 
♦Laminating 

♦Coated and bonded abrasives 

♦Friction materials 



AAI, ABR, ACP, ACY, ATM, AMF, APV, ARO, SAL, BEN, BOY, 
BRU, CIK, CM, COM, CPL, CPV, DAV, DEC, DSO, DUN, DUP, 
EW, FAR, FBR, FCD, FLW, FOG, FRE, FSH, GEI, GIL, GLD, 
GRG, GRV, HAN, HPC, HRS, ICF, JAM, JOB, JQD, JWL, KZL, 
KPS, KFV, KYN, LON, MCC, MID, MNP, MR, MRW, NCI, NPV, 
NTL, ORG, OSB, PER, PFP, PPG, PRT, QCP, RCI, RED, 
REL, RH, RMC, SCF, SCN, SED, SIP, SPP, SRR, SW, TV, 
VTV, WAS, WPC. 

ACP, ACY, AIM, AMF, APT, APV, ARO, BEN, CGL, CM, COM, 
CPV, DSO, DUN, DUP, EW, FAR, FBR, FCD, FLW, FOC, FSH, 
GEI, GLD, GRV, HPC, ICF, KYN, LON, MID, NCI, NON, 
NOP, NPV, ORO, OSB, PPG, PRT, RCI, RH, RMC, TV, VTV. 

ACP, ACY, AMR, CIK, DUP, FAR, HPC, JSC, KPS, MCC, MMM, 
MOB, ORO, REL, RH, SNW, WTC, x. 

ACC, ACP, CFX, NEV, NSP, PAI, VEL. 

ACC, ACP, CFX, NEV, NSP, PAI, VEL, WTC. 

ACC, ACP, CFX, DSO, DUP, ENJ, KPI, MCA, NEV, PAI, PPG, 
VEL, VSV. 



CBA, DOW, JOD, SHC, UCP. 

CBA, DOW, JOD, RCI, SHC, UCP. 

CBA, DOW, RCI, SHC, UCP. 

CBA, DOW, SHC, UCP. 

ACP, AMF, BEN, CM, DSO, FMP, GLD, HAP, ISO, JOB, KPT, 

MID, MNP, MRB, NON, ORO, OSB, PYR, REZ, SPP, SRR, 

TV, WAS. 



ACP, ACY, ADM, DA, DSO, EW, FHE, GLD, HKD, ICF, LAS, 

MFC, ORO, PPG, RCI, RH, SCN, SIC, SW, USR. 
AAI, ACP, ACY, AIM, APD, CAP, CPV, DA, DSO, FRE, GLD, 

GRV, HKD, ICF, IPC, KPS, LAS, MFG, MRO, PPG, RCI, 

SPP, SW, USR. 
ACP, ACY, ADM, APD, COM, CPV, DA, DAV, GLD, GYR, ICF, 

IPC, PPG, SW, USR. 
ACP, ACR, ACY, AMR, CIK, DA, DSO, EPC, EW, FMP, GEI, 

GLD, GNT, GRG, GYR, HKD, HYC, LAS, OCF, ORO, PLU, 

PPG, RCI, SCN, SW, X. 
ACP, DCC, SPD, UCS. 

DUR, GE, HER, HKD, HVG, IRC, MRB, PLS, RCI, RGC, SYR, 
UCP, VAR, VSV. 

ACP, AMR, BOR, CAT, CBR, CD, DRL, EW, FOM, GE, HKD, 
IRI, MCA, MON, NPI, NPP, NVF, PGU, PYZ, RCD, HCI, 
SCN, SPL, SYR, TAY, TKL, UCP, VAR. 

BME, BOR, CAT, CBR, HKD, t«M, MON, PYZ, SYR, UCP, VAR. 

ABS, ACP, BME, BOR, GE, HKD, MON, PYZ, RAB, SCN, SYR, 
SYV, UCP, VAR. 



144 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 15B.-- Plastics and resin materials for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



Material and iise 



Manufacturers ' identification codes 
(according to list in table 22) 



THERMOSETTING RESINS—Continued 

»Phenolic and other tar acid resins — Continued 
Bonding and adhesive resins for — Continued 
^Thermal insulation 

♦Foundry or shell molding 

♦Plywood 

♦Fibrous and granulated wood 

♦All other bonding and adhesive uses 

♦Protective coatings 

♦All other uses 

♦Polyurethane and diisocyanate resins 

♦Rosin modifications : 

♦Rosin and rosin esters, unmodified (ester gums' 
♦All other 

♦Styrene and alkyd polyesters 

♦Urea and melamine resins: 

♦Textile treating and coating resins 

♦Paper treating. and coating resins 

Molding materials 

Bonding and adhesive resins for: 

♦Laminating 

♦Plywood 

♦Fibrous and granulated wood 

♦All other bonding and adhesive uses 

♦Protective coatings 

All other uses 

All other thermosetting resins 

THERMOPLASTIC RESINS 

Acrylic resins 

♦Cellulose plastics materials: 
Sheets, continuous: 

♦Under 0.003 gage 

♦0.003 gage and over 

♦All other sheets, rods, and tubes 

♦Molding and. extrusion materials 

♦Polyamlde resins 



ACP, AMR, CAT, GE, HKD, ICF, MON, NPL, OCF, PYZ, RCI, 

syv, UCP. 
ACP, ACR, AMR, BOR, GE, HKD, MON, PYZ, RCI, UCP, VAR, 

WCA. 
ACP, AMR, BGC, BOR, CAT, CBC, DA, HKD, MON, PGU, PYZ, 

RCI, RH, Sm, X. 
AMR, BOR, HKD, MCA, MON, MRB, NPI, PYZ, RCI, SIM, UCP. 
ACP, AMR, ARK, BME, BOR, CAT, GE, HKD, IRI, KPT, MON, 

NTC, PYZ, RPC, SCN, SNC, SYR, UCP, USR, VAR. 
ACP, AIM, AMF, AMR, CIK, CPV, DSO, EW, FCD, GE, GEI, 

GRG, GRV, HER, HKD, ICF, INL, KND, KRM, MON, NCI, 

NPI, OHO, PFP, PYZ, RCI, RH, RMC, SCN, SNC, SPP, SW, 

UCP, VAR, WAS. 
ACP, ACR, AMR, CAT, DA, EVM, EW, GEI, HKD, IOC, IRC, 

MMM, MON, MRB, PLS, PYR, PYZ, RCI, REZ, RGC, RH, SCN, 

SNC, UCP, VAR, VSV. 
ACB, ADM, APV, ARK, BFG, CWN, DUP, GPM, HAP, IPI, NOP, 

PEL, PFP, PYR, QUN, SCN, SFC, SW. 

ADM, APV, CBY, DPP, FAR, FCD, FRP, HPC, KRM, MCC, SRR. 
ADM, APV, CBY, CPT, DPP, DSO, DUN, FAR, FCD, FLW, FRP, 

HPC, KRM, MCC, OSB, REL, RH, SCF, SRR, VSV, x. 
ADM, BRR, DEG, .FLW, REL, SNW. 

ACY, APX, BRY, CAT, CRC, DAN, DEP, DUP, HNC, HRT, JSC, 
MON, MRA, ONX, PC, QCP, RCI, RH, RPC, S, SNW, SYN, 
TRC, TV, USO, VAL, WIC, WON. 

ACP, ACY, AMR, BME, BOR, BRR, CBR, DUP, EDY, HPC, MMM, 
MON, RH, RCI, X. 

ACP, ACY, BOR, CAP, FMW, GDN, SFA. 

ACY, CAT, FOM, GE, MON, NPP, NTC, PGU. 

ACY, BGC, BOR, BRR, CAT, CBC, DA, MON, NPI, NTC, PGU, 

RCI, RH, SBJ, SOR, x. 

ACY, BGC, BOR, IPR, MON, NTC, PGU, RCI, SOR, SYV, UPL. 

ACP, ACY, AMR, BOR, MON, NTC, RCI. 

ACP, ACY, AMR, APV, CPV, DUP, GLD, GRV, HNC, JOD, KPS, 

MON, PPG, RCI, REL, RH, SW. 

ACY, GGY, HNC, MMM, MON, MRA, RCI, VAL, VAR. 

ACY, GGY, HPC, HVG, KRM, MON, RPC. 



AGO, ACY, CAT, CLD, DUP, FLH, GLC, GLX, HCO, JSC, PII, 
PPG, QUN, RH, RPI, SAR, TRC, USP, WIC. 



CEL, DOW, DUP, EKT. 
CEL, EKT, MON, MPP, NIX, PDJ, SPY. 
CEL, MPP, NIX, PDJ, RSB, SPY. 
CEL, DOW, EKT, MON, PMP, RPI, RSB. 

ALF, APX, BCM, DEP, DUP, EMR, FBF, FG, GNM, HN, JSC, 
KRM, MRA, POL, RPC, SNW, SPN, TRC, x. 



PLASTICS AND RESIN MATERIALS 



145 



TABLE 15B. — Plastics and resin materials for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



Material and use 



Manufaotirrers ' identification codes 
(according to list in table 22) 



THEHMOPLASTIC RESINS— Continued 

»Styrene type plastics materials: 

^Molding 

•Textile and paper treating and coating 

•Emulsion paint 

•Extrusion 

•All other uses 

Vinyl resins : 
•Polyvinyl acetate resins: 

•Emulsion paint 

•Adhesives 

•Bonding and sizing 

•All other uses 

•Polyvinyl chloride and copolymer resins: 

•Film, under 6 mils 

•Sheet, 6 mils and over 

•Flooring 

•Paper and textile coating 

Extrusion: 
•Wire and cable 

•Garden hose 

•All other extrusions 

Molding : 
•Records -. 

•Slush and rotational molding 

•All other moldings 

•All other uses 

•All other vinyl resins 

Polyolefin plastics materials: 
•Polyethylene, density 0.940 and below: 

•Injection molding 

•Blow molding 

Extrusions: 
•Film and sheet 

•Wire and cable coating 

•Extrusion coating on paper and other substrates- 



BFG, BKC, BPL, CST, DOW, FBF, FG, GOR, GRP, GYR, KPP, 

MON, MPL, PLA, RCC, SHC, SOL, TIC, UCP, USE, x. 
BFG, BOR, DOW, FIR, GNT, CTR, ILC, KPP, MON, MRT, USR, 

WAS, WIC. 
BFG, BOR, DOW, FIR, GLD, GNT, GYR, KPP, MON, RMC, USR. 
BFG, BKC, CSD, DOW, GRP, KPP, MON, RCC, UCP, USR, x. 
ACC, BCN, BFG, BOR, DOW, DSO, DUP, FIR, GRD, GRP, GYR, 

IOC, KPP, MON, MRT, ONX, PAI, POL, PVI, RH, SHC, SPI, 

UBS, UCP, UNC, WAS, x, x. 



ACP, AIR, AML, APV, BOR, CEL, DAV, DSO, DUP, FAR, FLH, 

GLD, GRD, HAN, JOD, MCC, NPV, NSC, RCI, REL, SED, 

SRC, SW, UCP, WAS, WIC. 
ACP, AIR, BOR, CEL, CST, DUP, ESC, FC, FLH, GRD, HNC, 

MRN, NSC, OCF, PII, RCI, SH, SRC, SYR, UCP, WIC. 
AAE, AML, CST, DAN, DUP, GRD, PII, QCP, RFC, SRC, WIC. 
BOR, CEL, CST, DUP, ESC, GRD, HRT, JSC, NSC, PVI, RFC, 

SCO, SRC, UCP, WIC, X. 

ATU, BFG, BOR, CRY, DA, DOW, ESC, FCP, FIR, GNT, GYR, 

MON, PNT, THC, UCP. 
ATU, BFG, BOR, CRY, DA, DOW, ESC, FCP, FIR, GNT, GYR, 

MON, PNT, THC, UCP, USR. 
AME, BFG, BOR, CRY, CUC, DA, ESC, FCP, FIR, GNT, GYR, 

MON, PNT, THC, UCP, USR. 
ATU, BFG, BOR, CRY, DA, ESC, MON, ONX, UCP, USR. 

BFG, BOR, CRY, DA, DOW, ESC, FIR, MON, PNT, THC, UCP, 

USR. 
ATU, BFG, BOR, DA, DOW, ESC, MON, THC. 
BFG, BOR, CRY, DA, DOW, ESC, FCP, FIR, GNT, GYR, MON, 

THC, UCP, USR. 

BFG, BOR, CRY, DA, ESC, KYS, MON, PLA, PNT, THC, UCP, 

USR. 

BFG, CRY, DA, ESC, FIR, MON, UCP, USR. 

BFG, CRY, DA, DOW, ESC, GYR, MON, UCP. 

ATU, BFG, BOR, CLR, CRY, DA, DOW, ESC, FCP, FIR, GRA, 

GYR, MON, NSC, PNT, PYR, UCP, USR. 

ADM, AIR, BEN, BOR, BOY, CLD, DOW, DSO, DUP, FC, FCD, 

G, GLD, GRD, IOC, JOD, MR, NSC, RMC, RFC, SRC, SW, 

UCP. 



CEL, DOW, DUP, EKX, ENJ, GRP, KPP, MON, PLC, RCC, SHC, 

SPN, JCP, USI. 
CEL, DOW, DUP, EKX, GRP, KPP, MON, PLC, RCC, SHC, SPN, 

UCP, USI. 

CEL, DOW, DUP, EKX, ENJ, GRP, KPP, MON, PLC, RCC, SHC, 

SPN, UCP, USI. 
CEL, DOW, DUP, EKX, GRP, KPP, MON, PLC, SHC, SPN, UCP, 

USI. 
CEL, DUP, EKX, GRP, KPP, MON, PLC, RCC, SHC, SPN, UCP, 

USI. 



146 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 15B. --Plastics and resin materials for which U.S. production or sales were reported, identified by 

manufacturer, i 963 --Continued 



Material and use 


Manufacturers ' identification codes 
(according to list in table 22) 


THERMOPLASTIC RESINS— Continued 

Polyolefin plastics materials — Continued 
^Polyethylene, density 0.9i0 and below— Continued 
^Extrusions — Continued 


ACP CEL DOW DUP, EKX, GRP, KPP, MON, SHC, SPN, UCP, 




USI. 
CEL, DOW, DUP, EKX, GRP, KPP, MON, RCC, SPN, UCP. 




»P3lyethylene, density over 0.940: 


SPN, UCP, USI. 

CEL, DOW, DUP, EKX, GRP, HPC, KPP, PLC, RCC, SHC, UCP, 

USI. 
CEL, DOW, DUP, EKX, GGC, GRP, HPC, KPP, PLC, SHC, UCP 

USI. 

CEL, DOW, DUP, EKX, GGC, GRP, HPC, KPP, MON, PLC, SHC 

UCP, USI. 
CEL, DUP, EKX, GRP, HPC, PLC, UCP. 
ACP, CEL, DUP, EKX, GGC, GRP, HPC, KPP, PLC, SHC, UCP 

USI. 
CEL, DUP, EKX, GGC, GRP, HPC, KPP, PLC, UCP, USI. 
ACP, CEL, DOW, DUP, GGC, GRP, MON, PLC, UCP, USI. 

AVS DOW DUP EKX ENJ, GRP, HPC, NVT, SHC, SPN, UCP 




Extrusions : 
»Film and sheet 








•Polypropylene : 




AVS DOW EKX ENJ GRP HPC, RCC, SHC, SPN, UCP. 




DOW, EKX, GRP, HPC, SHC, SPN, UCP'. 

ACG, ACY, CBY, CWN, DUP, FBF, GE, HPC, MMM, MOB, SCN, 
UCP. 







RUBBER PROCESSING CHEMICALS 
Rubber-Processing Chemicals 



147 



TABLE 16B. — Rubber -processing chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1963 

[Rubber-processing chemicals for which separate statistics are given in table 16A are marked below with an asterisk 
(«); chemicals not so marked do not appear in table 16A because the reported data are accepted in confidence and 
may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that 
the manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 22) 



RUBBER-PROCESSING CHEMICALS, CYCLIC 

»Accelerators: 
»Aldehyde-amines : 

Acetaldehyde-anlline 

n-Butyraldehyde-aniline 

Butyraldehyde-butylidene-aniline 

•ijA'-Dithiodimorpholine 

ci-Ethyl-P-propylacrylanllide 

Formaldehyde-p-toluidine (Methylene-p-toluidine ) 

Heptaldehyde-aniline 

Triethyltrimethylenetriamlne 

p-Benzoquinone dioxime 

Dibenzoyl-p-qulnonedioxime 

Dibenzylamine 

Di-N-pentamethylenethiuram tetrasulfide 

wDithiocarbamic acid derivatives: 

Dibenzyldithiocarbamic acid, sodium salt 

Dibenzyldithiocarbamic acid, zinc salt 

Dibutyldithiocarbamic acid, N,N-dimethyloyolohexylamlne 
salt. 

Dibutyldithiocarbamic acid, dlphenylguanidine salt 

Dimethylethylene diphenyldithiocarbamic acid, lead 
salt. 

2,^-Dinitrophenyl dimethyldithiocarbamate 

Piperidineoarbodithioic acid, piperidinlum-potassium 
salts. 
Guanidines : 

Dicatechol borate, di-o-tolylguanidine salt 

Diphenylguanidine 

Dlphenylguanidine phthalate 

Di-o-tolylguanidine 

1,2,3-Triphenylguanidine 

2-Imidazollne-2-thiol 

Poly-p-dinitrosobenzene 

•Thiazole derivatives: 

2-Benssothiazyl N,N-diethylthiocarbamoyl sulfide 

l,3-Bis(2-benzothiazolylmercaptomethyl)urea 

N-tert-Butyl-2-benzothlazolesulfenamide 

»N-Cyclohexyl-2-benzothiazolesulfenamide 

N,N-Diisopropyl-2-benzothiazolesulfenamide 

N- ( 2 , 6-Dimethylmorphollno ) - 2-benzothiazolesulf enamlde — 

«2,2'-Dithiobis{benzothlazole) 

»2-Mercaptobenzothiazole 

2-Uercaptobenzothiazole, sodium salt 

2-lfcrcaptobenzothiazole, zinc salt 

'i-Morpholinyl-2-benzothiazyl disulfide 

N-Oxydiethylene-2-benzothiazolesulfenamide 

Thiazoline-2- thiol 

All other cyclic accelerators 

Antioxidants : 

Aldehyde- and acetone-amines: 

Acetaldehyde-anlline hydrochloride — ■ 

Aldol-a-naphthylamine condensate 

Diphenylamine-acetone 

Phenyl-2-naphthylnm1 ne-acetone 



USR. 

DUP, MDN, USR. 

JON. 

MON. 

CCO. 

DUP. 

USR. 

USR. 

CTA, DUP. 

CTA, USR. 

MLS, USR. 

DUP, VNC. 

USR. 
USR. 
MON. 

CCO. 
CCO. 

USR. 
DUP. 



DUP. 
ACY. 
MON. 

ACY, DUP. 
NAC. 

DUP, RBC. 
DUP. 



PAS. 
MON. 
MON. 
ACY, 
ACY. 
MON. 
ACY, 
ACY, 
ACY, 
ACY, 
GYR. 
ACY, 
ACY. 
DUP, 



BFG, MON, USR. 

BFG, GYR, MON, USR. 

BFG, GYR, MDN, USR. 

GYR, MON. 

GYR, USR. 

MON. 

VNC. 



USR. 

BFG. 

ACY, BFG, USR. 

USR. 



SYNTHETIC ORGANIC CHEMICALS, 1963 

TABLE 16B.— Rubber -processing chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i56^— Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



RUBBER-PROCESSING CHEMICALS, CYCLIC— Continued 

Antioxidants — Continued 
»Ainino and hydroxy compounds : 
»Amino compounds: 

p-Anilinophenol 

N-sec-Butyl-N'-phenyl-p-phenylenediamine 

N-Cyclohexyl-N'-phenyl-p-phenylenediamine 

Diarylarylene diamines, mixed 

N, N '-Di ( l-ethyl-3-methylpentyl ) -p-phenylenediamine 

l,2-Dihydro-6-dodeoyl-2,2,'i-trimethylquinoline 

l,2-Dihydro-6-ethoxy-2,2,'i-trimethylquinoline 

l,2-Dihydro-2,2,'i-trimethylquinoline 

p , p ' -Dimethoxydipheny lami ne 

N,N'-Di(l-methylheptyl) -p-phenylenediamine 

N,N '-Di-2-naphthyl-p-phenylenediamine 

"ij-i'-Dioctyldiphenylamine 

N,N'-Di-2-octyl-p-phenylenediamine 

N,N'-Diphenylethylenediamine 

»N,N'-Diphenyl-p-phenylenediamine 

N,N'-Diphenyl-l,3-propanediamine 

N,N'-Di-o-tolylethylenediamine 

p-Isopropoxydlphenylamine 

N-Isopropyl-N'-phenyl-p-phenylenediamine 

■ijA'-Methylenedianiline 

N- ( 1-Methylheptyl ) -N -phenyl-p-phenylenediamine 

Octyldiphenylamine 

Ootyldiphenylamine mixture (mono-, nonyl-, and di-) — 

N-Phenyl-1-naphthylamine 

N-Phenyl-2-naphthylamine 

Tetramethyldiphenylethylenediamine 

p-(p-Toluenesulfonamido)diphenylamine 

All other amino antioxidants 

»Hydroxy compoimds: 

Alkylated bis-phenol and alkylated and phosphited 
bis -phenol, mixed. 

p-Benzyloxyphenol 

4,<i'-Butylidenebis(6-tert-butyl-m-cresol) 

2,5-Di(l,l-dimethylpropyl)hydroquinone 

N-Lauroyl-p-aminophenol 

2,2'-Methylenebis(6-tert-butyl-p-cresol) 

2,2'-Methylenebis(6-tert-butyl-'V-ethylphenol) 

»Phenol, alkylated 

Phenol, hindered 

Phenol, styrenated 

N-Stearoyl-p-aminophenol 

2,2'-Thiobis('4,6-di-sec-amylphenol) 

'*,4'-Thiobis(6-tert-butyl-m-cresol) 

Blowing agents: 

N,N'-Dimethyl-N, N'-dlnitrosoterephthalamide 

Dlnitrosopentamethylenetetramine 

p,p'-Oxybis(benzenesulfonhydrazide) 

Inhibitors, modifiers, and stabilizers: 

Alkylated o-cresol 

Dioresyl disulfide 

N.A-Dinitroso-N-methylaniline 

»N-Nitrosodiphenylamine 

Nony Ipheny Iphosphites , mixed 



BFG, 


DUP. 






USR. 








MON, 


USR. 






GYR. 








EKT, 
MON. 


MON, 


UPM. 




MON. 
BFG, 


MON. 






DUP. 








EKT, 


MON, 


UPM. 




BFG. 








BFG. 








BFG. 








CCO, 


NOP, 


X. 




BFG, 


DUP, 


USR. 




CCO. 








CCO. 








BFG. 








MON, 


USR. 






USR. 








UPM. 








PAS, 


USR. 






BFG. 








DUP. 








BFG, 


DUP. 






NOP. 








USR. 








EKT, 


X. 






BFG. 








BFG. 








MON. 








MON. 








MLS. 








ACY. 








ACY. 








ACY, 


BFG, 


CCO, GYR, PAS, USR 


DUP, 


GYR, 


PIT. 




BFG, 


GYR. 






MI£. 








MON. 








MON. 








DUP. 








DUP, 


NPI. 






USR. 








PIT. 








USR. 








CTA, 


MON. 






BFG, 


CTA, 


GYR, USR. 




USR. 









RUBBER-PROCESSING CHEMICALS 



149 



TABLE 16B. -- Rubber-processing chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



RUBBER-PROCESSING CHEMICALS, CYCLIC— Continued 

■»Pepti zers : 

Alliylated o-thiocresol 

Alkylated thiophenol, zinc salt 

Aryl mercaptans 

2-Benzamidothiophene, zinc salt 

2',2' ' '-Dithiobis(benzanilide) 

Dixylyl disulfides, mixed 

2-Naphthalenethiol 

Pentachlorobenzenethiol 

Pentachlorobenzenethiol, zinc salt 

Thiocresol 

Thiophenol 

Xylenethiol 

Tackifiers: p-tert-Amylphenol sulfide 

RUBBER-PROCESSING CHEMICALS, ACYCLIC 

^Accelerators : 

n-Butyraldehyde-butylamine 

Di-n-butylammonlum oleate 

NjN'-Ditatyldithioadipamide 

»Dithiocarbainic acid derivatives: 

»Dibutyldithiocarbaiiu.c acid, sodium salt 

»Dibutyldithiocarbamic acid, zinc salt 

Diethyldithiocarbamio acid, cadmium salt 

Diethyldithlocarbamic acid, selenium salt 

Diethyldithiocarbamic acid, sodium salt 

Diethyldithiocarbamic acid, telluriimi salt 

^Diethyldithiocarbamic acid, zinc salt 

Dimethyldithiocarbamic acid, bismuth salt 

Dimethyldithiocarbamic acid, copper salt 

Dimethyldithiocarbamic acid, lead salt 

*Dimethyldithiocarbamic acid, potassium salt 

Dimethyldithiocarbamic acid, selenium salt 

♦Dimethyldithiocarbamic acid, sodium salt 

Dimethyldithiocarbamic acid, sodium salt and sodium 
polysulfide. 

»Dimethyldithiocarbamic acid, zinc salt 

All other 

»Thiurams : 

Bis(dibutylthiocarbamoyl) sulfide 

Bis(diethylthiocaTbamoyl) disulfide 

»Bis(dimethylthiocarbamoyl) disulfide 

»Bis (dimethyl thiocarbamoyl) sulfide 

Bis(ethylmethylcarbamoyl) sulfide 

Thiuram blend 

Xanthates and sulfides: 

Di-n-butylxantho disulfide 

Di-isopropylxantho disulfide 

Zinc dibutylxanthate 

All other acyclic accelerators: 

3-Ethyl-l,l-dimethyl-2-thiourea 

Ethylenediamine carbamate 

Polyoxyalkylene tetrasulfide 

l,l,3-Trimethyl-2-thlourea 

Blowing agents: 

l,l'-Azobisformamide 

Urea-biuret mixture 



PIT. 

PIT. 

PIT. 

ACY. 

ACY. 

DUP, PIT. 

DUP. 

DUP. 

DUP. 

PIT. 

PIT. 

DUP. 

PAS. 



DUP. 
DUP. 
DUP. 



DUP, 
ALC, 
VNC. 
VNC. 
ALC, 
VNC. 
ALC, 
VNC. 
VNC. 
VNC. 
GYR, 
VNC. 
ALC, 
BFG, 



PAS, USR, VNC. 

DUP, PAS, RBC, USR, VNC. 



USR. 

GYR, RBC, USR, VNC. 



PAS, USR. 



BFG, DUP, GYR, PAS, USR. 
GNT. 



ALC, FMN, GYR, PAS, RBC, USR, WRC. 
PAS, VNC. 

USR. 

DUP, GYR, PAS. 

BFG, CLY; DUP, GNT, GYR, PAS, RBC, USR, VNC. 

DUP, GYR, USR. 

VNC. 

VNC. 

USR. 
BFG. 
USR. 

VNC. 
DUP. 
TKL. 
VNC. 

FMT, NPI, USR. 
SW. 



'50 SYNTHETIC ORGANIC CHEMICALS, 1963 

TABLE 16B. — Rubber -processing chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i 565 --Continued 



Chemical 


Manufacturers ' identification codes 
(according to list in table 22) 


RUBBER-PROCESSING CHEMICALS, ACYCLIC— Continued 

Conditioning and lubricating agents: 

Methyl stearyl-10-sulfonio acid, sodium salt 

Mono- and dialkyl acid phosphates, mixed 

Mono- and dialiyl phosphate ammonium salts, mixed 

Peptizers and modifiers: 

Allsyl mercaptans, mixed 


DUP. 
DUP. 
DUP. 

PLC. 

HK, PAS, PLC. 

USR. 

ACY, TKL, USR, x. 


Zinc laurate 

All other - 



ELASTOMERS (SYNTHETIC RUBBERS) 151 

Elastomers (Synthetic Rubbers) 

TABLE 17B. — Elastomers (synthetic rubbers) for which U.S. production or sales were reported, identified by 

manufacturer , 1963 

[ELastomers (synthetic rubbers) for which separate statistics are given in table 17A are marted below with an as- 
terisk (»); products not so marked do not appear in table 17A because the reported data are accepted in confidence 
and may not be published. Manufacturers' identification codes shown below are taken from table 22] 



Product 


Manufacturers ' identification codes 
(according to list in table 22) 


ELASTOMERS, CYCLIC 






PLC, RUB, SHC, TUS, URC, USR. 






ELASTOMERS, ACYCLIC 












*Polychloroprene type (Neoprene) 


DUP. 






Reaction products of natural rubber 


GYR, HPC. 















152 



SYNTHETIC ORGANIC CHEMICALS, 1963 
Plasticizers 



TABLE 18B, 



-Plasticizers for which U.S. production or sales were reported, identified by 
manufacturer , 1963 



[Plasticizers for which separate statistics are given in table 18A are marked below with an asterisk (»); products 
not so marked do not appesir in table 18A because the reported data are accepted in confidence and may not be pub- 
lished. Manufacturers' identification codes shown below are taken from table 22] 



Manufacturers ' identification codes 
(according to list in table 22) 



PLASTICIZERS, CYCUC 

Covimarone-indene plastlcizer 

Methylene glycol dibenzoate 

Di-tert-octylphenyl ether 

Dlphenyl cyclohexane, o-, m-, p- 

Dipropanediol dibenzoate 

N-Ethyl-p-toluenesulfonamide 

Isopropylidenediphenoxypropanol 

Naphthalene, alkylated 

Riosphoric acid esters: 

♦Cresyl diphenyl phosphate 

Dlbutyl phenyl phosphate 

Diphenyl mono-o-xenyl phosphate 

Diphenyl octyl phosphate 

Methyl diphenyl phosphate 

»Tricresyl phosphate 

<Tri phenyl phosphate 

»Phthalic anhydride esters: 

Butyl benzyl phthalate 

Butyl cyclohexyl phthalate 

Butyl decyl phthalate 

♦Butyl octyl phthalate 

Butyl phthalyl butyl glycolate 

•Di{2-butoiyethyl) phthalate 

♦Dibutyl phthalate 

Dicarbitol phthalate 

"Dicyclohexyl phthalate 

Diethylene glycol phthalate 

♦Diethyl phthalate 

•Dlliexyl phthalate 

•Diisodecyl phthalate 

•Di(2-methoxyethyl) phthalate 

•Dimethyl phthalate 

Dinonyl phthalate 

♦Dioctyl phthalates: 

»Di(2-ethylhexyl) phthalate- 

»Dliso-octyl and mixed dioctyl phthalates— 

Diphenyl phthalate 

•Dltridecyi phthalate 

Ethyl (and methyl) phthalyl ethyl glycolate- 

Hexyl iso-octyl phthalate- 

Isodecyl trldeeyl phthalate 

•Octyl decyl phthalates: 

*Iso-octyl isodecyl phthalate 

•n-Octyl n-decyl phthalate 

Polyglycol phthalate esters 

All other phthalic anhydride esters 

Tetrahydrofurfuryl oleate 



NEV. 
TNP. 
DOW. 
MON. 
TNP. 
MON. 
DOW. 
ACC. 

CEL, KLK, MON, WIR, SPP. 

MON. 

DOW. 

MON. 

MON. 

CEL, FMP, KLK, MON, MIR. 

CEL, DOW, EK, MON. 

GRH, MON. 

AGP. 

ACP, GRH, PCC, RUB, THC, UCC. 

ACP, GRH, MON, PCC, PFZ, RCI, RUB, UCC. 

MON, NOP. 

HMP, GRH, KES, WM. 

ACP, AIR, COM, DUP, EKT, GRD, GRH, HAL, KLK, LAS, MON, 

PCC, PFZ, RCI, RUB, SW, WTH, UCC. 
FMP. 

ACP, DUP, FMP, MON. 
ARK. 

DUP, EKT, KF, MON. 

ACP, CCA, ENJ, GRH, ROS. 

ACP, BFG, EKT, ENJ, FCP, GRH, MON, PCC, PFZ, RCI, ROS, 

RUB, THC, UCC, WTH. 

CEL, DUP, EKT, FMP, RCI. 

ACP, DUP, EKT, KF, KLK, MON, PFZ. 
RCI. 

ACP, BFG, EKT, ENJ, FCP, GRH, MON, PCC, PFZ, RCI, ROS, 

RUB, SW, THC, UCC, WTH. 
ACP, ADM, BFG, EKT, ENJ, GDL, GRH, LEH, MON, PCC, PFZ, 

RCI, ROS, RUB, THC, UCC, WTH. 
MON. 

ACP, ENJ, GRH, kJON, PCC, PFZ, RCI, RUB, THC, UCC. 
MON. 
PFZ. 
THC. 

ACP, EKT, PCC, PFZ, THC. 

ACP, GRH, HPC, MON, PCC, PFZ, RCI, RUB, THC, UCC. 

ARC, FMP, HAL, HPC. 

ACP, BFG, DUP, H(, MON, PCC, PFZ, UCC. 

CCW, EMR. 



PIASTICIZERS 



153 



TABLE 18B. — Plasticizers for which U.S. production or sales were reported, identified by 
manufacturer, i9&5-- Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



PLASTICIZERS, CYCLIC— Continued 

Toluenesulfonamide, o-, p- mixtures 

»Trimellitic acid esters 

All other cyclic plasticizers 

PLASTICIZERS, ACYCLIC 

«Adipic acid esters : 

*Di(2-(2-butoxyethoxy)ethyl) adipate 

»Dil2-ethylhexyl) adipate 

»Dlisobutyl adipate 

*Dilsodeoyl adipate 

»Diiso-octyl adipate 

«Octyl decyl adipate 

All other adipic acid esters •• 

»Azelaic acid esters : 

Di(2-ethyLhexyl) azelate 

Wisobutyl azelate 

Dilso-octyl azelate 

All other azelaic acid esters 

Citric and acetylcitric acid esters 

^Complex lineEir polyesters and polymeric plasticizers- 

I>i(2-(2-buto3tyethoxy)ethyl)methane 

methylene glycol dinonanoate 

Diiso-octyl diglycolate 

»Epoxldized esters : 

Butyl epoxytallate 

»Epoxidized soya oils 

Iso-octyl epoxystearates ...— . 

«Octyl epoxy tallates 

All other 

Glycerol pelargonate 

Glyceryl tributyrate and tripropionate 

Glycol pelargonate 

Isodecyl nonanoate (Isodecyl pelargonate) 

Laurie acid esters 

^ty^istic acid esters : 

Butyl myristate 

♦Isopropyl myristate 

Methyl myristate 

Oleic acid esters: 

»Butyl oleate 

^Glycerol trioleate (Triolein) 

*Isopropyl oleate 

«Methyl oleate 

«n- Propyl oleate 

All other oleic acid esters 

Palmitic acid esters: 

«Isopropyl palmitate 

All other palmitic acid esters 

•Phosphoric acid esters : 

Tri(2-butoxyethyl) phosphate 

Triethyl phosphate 

Trioctyl phosphate 

Tris ( chloropropyl ) phosphate 



M3N. 

PCC, PFZ, RUB. 

EKT, MON, TNP, WTH. 



™p, GRH, HAL, RCI, TKL. 

EKT, LEH, MON, PCC, PFZ, THC, UCC, WTH. 

FMP, GRH, HAL, RCI. 

ACP, EKT, GRH, HAL, LEH, MON, PCC, PFZ, RCI, RH, RUB, 

THC, UCC. 

ACP, GDL, GRH, HAL, LEH, PFZ, RCI, RH, RUB. 

ACP, BFG, GRH, LEH, MON, NOP, PCC, PFZ, RCI, RUB, THC. 

ACP, EKX, KES, LEH, PCC, PFZ, RCI, THC, TKL. 

DUP, EKT, EMR, HAL, LEH, PFZ, RCI, RUB, THC, UCC. 

HAL, RCI. 

IMR, GDL, GRH, RCI. 

ACP, am, LEH, PFZ. 

PFZ. 

ADM, EKT, IMR, HAL, HPC, LEH, MON, PFZ, RH, ROS, RUB, 

UCC, WM, WTC. 
TKL. 

BMR, RUB. 
CCA, PW. 



ADM, THC. 

ADM, ARG, BAC, 

ROS. 

ADM, ARG, BAC, 

ADM, ARG, BAC, 

EMR. 

EKT. 

EMR. 

MR, LEH. 

FOR, HAL. 

ICI, KES. 

DRW, ICI, KES, 
FOR. 

CIN, HAL, ICI, 

DRW, am, HAL, 

Qffi, ICI, KES, 

CHL, EMR, FOR, 

CHL, aiR, WM. 

DRW, HAL, ICI, 

DRW, ICI, KES, 

WI, FOR, KES, 

CEL, FtSP. 
EKT. 
UCC. 
CSL. 



CCW, RCI, RH, SWT, THC, UCC. 



RH, THC, UCC. 

CCW, EMR, RCI, RH, THC. 



KES, LAS, NOP, RUB, SWT, WM, WTH. 

SWT, WM. 

WM, WTC. 

ICI, NOP, SWT. 

KES, RH. 

PRP, WM. 
NOP, RUB. 



749-026 O - 64 



154 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 18B. — Plasticizers for which U.S. production or sales were reported, identified by 
manufacturer, i565--Continuecl 



Manufacturers ' Identification codes 
(according to list in table 22) 



PLASTICIZERS, ACYCLIC— Continued 

Polyethylene glycol di-2-etl3ylhexanoate 

Rioinoleio and aoetylricinoleic acid esters : 

^Glycerol monorioinoleate 

All other riclnoleic and acetylrlclnoleic acid esters- 
«Sebacic acid estejrs: 

»Dibutyl sebacate 

»Di(2-ethylhexyl) sebacate 

All other sebacio acid esters 

^Stearic acid esters : 

«n- Butyl stearate 

All other stearic acid esters 

Sucrose acetate isobutyrate 

»Triethylene glycol di(caprylate-caprate) 

Triethylene glycol dl-2-ethylbutyrate 

Trimethyl pentanediol diisobutyrate 

All other acyclic plasticizers 



BAG, GLY, HAL, NOP. 

BAG, KES, RCI. 

EKT, GRH, HAL, PCC, PFZ, RCI, RH, WTH. 

GRD, GRH, HAL, LEH, PCC, PFZ, RCI, RH, WTH. 

KES, LEH, NOP, RCI, RUB. 

CHL, HAL, ICI, KES, LAS, RUB, SCP, SWT, WTH. 

BAC, CHL, DRW, KMP, HK, HPC, JNS, KES, RCI, RH, ROS, WM. 
EKT. 

DRW, FOR, GRH, HAL, RUB. 
UCC. 
EKX. 

EKT, EKX, EMR, HAL, KES, LEH, PFZ, RH, RUB, TKL, UCC, 
WM. 



SURFACE ACTIVE AGENTS 



155 



Surface-Active Agents 



TABLE 19B. --Surface -active agents for which U.S. production or sales were reported, identified by 

manufacturer. 1963 

[Surface-active agents for which separate statistics are given in table 19A are marked below with an asterisk (»); 
products not so marked do not appear in table 19A because the reported data are accepted in confidence and may not 
be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 22) 



BENZENOID SURFACE-ACTIVE AGENTS 

Not Sulfated or Sulfonated 

»Amides, amines, and quaternary ammonium salts: 
^Heterocyclic compounds : 

l-Benzyl-2-heptadeoyl-l-(2-hydroxyethyl)-2-iinidazo- 
linium chloride. 

l-Benzyl-:'.-picolinium bromide 

2-Dodecyllsoqulnolinium bromide 

1-Dodecylpyridinlum chloride 

2-(2-Lauroyloxyethyl )carbamoyl-l-methylpyTidinium 

chloride. 
l-Methyl-2-(2-stearoyloxyethyl)carbamoylpyridinium 
chloride. 
•Oxygen-containing compounds ; 

Benzylbis(2-hydroxyethyl )(2-stearamidamethoxyethyl )- 

ammonium chloride. 
Benzyl (ethoxylated coconut oil alkyl )diinethylaimnonium 

chloride. 
( Dodecylbenzyl ) ( 2 -hydroxyethyl )dlmethylammonium 

chloride. 
( Ethoxybenzy 1 )d ime thy 1 ( oc ty Iphenoxy ) ammoni um chloride - ■ 
(Ethoxyben2yl)dimethyl(octyltolyloxy )ammonium chloride- 

N-(2-Hydroxyethyl)-l,2-dlphenylethylenediamine 

(Tridecylbenzyl )diethyl(2-hydroxyethyl )ammonium 
chloride. 
Trl alkyl ( alkylbenzyl )ammonium salts: 

(Dodecylbenzyl )dlmethyloctadeoylanmonium chloride 

(Dodecylbenzyl )trlethylammonium chloride 

»( Dodecylbenzyl )trimethylammonium chloride 

(Dodecylmethylbenzyl )trtmethylammonium chloride 

(Ethylbenzyl)dimethyl(mlxed alkyl )nniiionium chloride 

Trlalkylbenzylammonium salts : 

Benzyl( coconut oil alkyl )dimethylammonlum chloride 

Benzyldijnethyl(mlxed alkyl )ammonium chloride 

»Ben2yldlmethyloctadecylammonium chloride 

Benzyldlmethyltetradecylammonlum chloride 

*Benzyldodeoyldiinethylaiiinonlum chloride 

Benzylhexadecyldimethylammonlum chloride 

Benzyl (hydrogenated tallow alkyl )dimethylammonlum 
chloride. 

Benzyltrimethylammonium chloride 

•(Sj-i-Dichlorobenzyl )dodecyldimethylainmonluin chloride-— 
»Carboxylic acid esters and ethers: 

Alkylphenol - formaldehyde, alkoxylated: 

(Mixed alkyl )phenol - formaldehyde, alkoxylated 

Nonylphenol - formaldehyde, alkoxylated 

t-Octylphenol - formaldehyde, ethoxylated 

Pentylphenol - formaldehyde, alkoxylated 

Cresol, ethoxylated , 



PCS, uvc. 

FIN. 

ONX, WSN. 
BC, HK. 
WTC. 

WTC. 



RH. 




RH. 




APX. 




ORO. 




AML. 




PC. 




BC, VIS, WSN, 


WTC. 


RH. 




ONX. 




BC, FIN. 




BC, FIN, ONX, 


PCS, RH, VAC 


ONX, RET, WSN 




WSN. 




DEP, ONX, SDH 


WSN. 


FIN, ONX, RH, 


SDW. 


ARC, GNM, ONX 




CCW. 




BC, ONX, SDW, 


VAC, WSN. 


RTF, VIS. 




RTF. 




SDW. 




APD, RTF. 




VIS. 





156 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 19B. -Surface-active agents for uihich U.S. production or sales were reported identified by 
manufacturer, i565— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



BENZENOID SURFACE-ACTIVE AGENTS— Continued 

Not Sulfated or Sui/onaleri— Continued 

*Carboxylio acid esters and ethers — Continued 

Diisobutylphenol, ethoxylated 

Dinonylphenol, ethoxylated 

»Dodecylphenol, ethoxylated 

*Iso-octylphenol, ethoxylated 

(Mixed alkyDphenol, ethoxylated 

(Mixed alkyDphenol, ethoxylated, butyl ether 

*Nonylphenol, ethoxylated 

Nonylphenoxypoly(ethyleneoxy )ethyl iodide 

Pentadecylphenol, ethoxylated 

»Phenol, ethoxylated 

Phthalic acid, octadecyl ester, potassium salt 

Tall oil acids, alkoxylated pentylphenol - formaldehyde 
ester. 

Tetradeoylphenol, ethoxylated 

Trideoylphenol , ethoxylated 

Xylenol, ethoxylated 

All other 

^Phosphoric and polyphosphoric acid esters and salts : 

Dodecylphenol, ethoxylated and phosphated 

Dodecylphenol, ethoxylated and phosphated, sodium salt— • 

»Nonylphenol, ethoxylated and phosphated 

Octylphenol, ethoxylated and phosphated, magnesium salt-. 
All other 

Sulfated and Sulfonated 

*All!ylphenols , ethoxylated and sulfated: 

Dodecylphenol, ethoxylated and sulfated 

(Mixed alkyl )phenol, ethoxylated and sulfated 

*Nonylphenol, ethoxylated and sulfated 

Nonylphenol, ethoxylated and sulfated, ammonium salt 

Nonylphenol, ethoxylated and sulfated, triethanolamlne 
salt. 

n-Octylphenol, ethoxylated and sulfated 

•Benzenesulf onates : 

»Benzene-, toluene-, and xylenesulfonates : 

Benzenesulfonic acid, sodium salt 

p-Toluenesulfonio acid, hexadeoyltrimethylammoniujn 
salt. 

*Toluenesulfonlc acid, potassium salt 

»Toluenesulfonic acid, sodium salt 

*Xylenesulfonic acid, ammonium salt 

Xylenesulfonic acid, potassium salt 

*)^lenesulfonic acid, sodium salt 

*Dodeoylbenzenesulf onates : 

»Dodecylbenzenesulfonic acid 

Dodecylbenzenesulfonic acid, ammonium salt 

Dodeoylbenzenesulfonlc acid, butylamine salt 

^Dodecylbenzenesulfonic acid, calcium salt 

Dodecylbenzenesulfonic acid, diethanolamlne condensate, 
fatty acid' monoester. 

Dodecylbenzenesulfonic acid, diethanolamlne salt 

Dodecylbenzenesulfonic acid, ethylenediamine salt 



G, RH. 

G, STP, VIS. 

G, MON, PCS, UCC. 

APX, DRW, NOP, QMC. 

G, PCS, RH, STP. 

RH. 

APD, CLY, DOW, DRW, FBC, G, HPC, JCC, MON, CMC, PCS, 

RH, RTF, STP, TRC, UCC, VIS. 
G. 
G. 

APD, G, NOP, UCC. 
TRC. 
APD. 

ORO. 
PCS. 
VIS. 
PRC. 

TXZ. 

TXZ. 

CIN, G, PCS, RZL, TCC, UVC, WAY, WTC. 

SMC. 

RZL. 



EFH, G, LEV, STP. 



G, CMC, STP, WTC. 
MYW, TRC, TXZ. 



UPF. 
FIN. 

MYW, NES, RCD, STP, WTC. 

CO, MYW, NES, PIL, STP, WTC. 

ATR, CO, MYW, RCD, STP, WTC. 

ATR, MYW, WTC. 

ATR, CO, MYW, NES, PIL, STP, WTC. 

ARD, CIN, CO, HLI, LEV, MON, MYW, NAG, NOP, PCI, PIL, 

PRX, RCD, SEY, STP, TDC, TN, TXZ, WTC. 
ARL, CTL, MYW, PRX, RCD, TXZ. 
WTC. 

AFD, ROD, RH, SMC, STP, VIS, WTC. 
MAH. 

PCS, WON. 
APD. 



SURFACE-ACTIVE AGENTS 



157 



TABLE 19B. 



■Surface -active agents for which U.S. production or sales were reported, identified by 
manufacturer, J 965 --Continued 



Manufacturers' identification codes 
(according to list in table 22) 



BENZENOID SURFACE-ACTIVE AGENTS— Continued 

Sulfated and Sulfonated — Continued 

*Benzenesulf onates — Continued 

♦Dodecylbenzenesulfonates — Continued 

Dodecylbenzenesulfonlo acid, isopropanolamine salt — 

»Dodeoylbenzenesulfonic acid, isopropylamine salt 

»Dodecylbenzenesulf onio acid, (niixed alkyl) amine salt- 

Dodeoylbenzenesulfonlc acid, propoxylated ethylene- 
diamine salt. 

»Dodecylbenzenesulfonic acid, sodium salt 

»Dodecylbenzenesulf onic acid, triethanolnmi ne salt 

Dodecylbenzenesulfonic acid, zinc salt 

"Other benzenesulf onates ; 

Decylbenzenesulfonic acid, sodium salt 

Didodeoylbenzenesulfonlc acid 

Nonylbenzenesulfonic acid, sodium salt 

Pentylbenzenesulfonic acid, sodiiim salt 

Tridecylbenzenesulf onic acid 

Tridecylbenzenesulfonic acid, ammonium salt 

»Tridecylbenzenesulfonio acid, sodium salt 

Tridecylbenzenesulfonic acid, triethanolamine salt — • 

All other 

»Lignosulf onates : 

Llgnosulfonic acid, aluminxm salt 

Lignosulf onic acid, ammonium salt 

*Lignosulf onic acid, calcium salt 

Llgnosulfonic acid, chromium salt 

LignOEulfonlo acid, iron salt 

Llgnosulfonic acid, magnesium salt 

Llgnosulfonic acid, sodium salt 

»Naphthalenesulf onates : 

Benzylnaphthalenesulfonlc acid 

»Butyliiaphthalenesulfonlc acid 

»Eeo-Butylnaphthalenesulfonlc acid 

»Butylnaphthalenesulfonic acid, sodium salt 

Dibutylnaphthalenesulfonic acid 

Dldodecylnaphthalenesulfonlc acid, sodium salt 

»Diisopropylnaphthalenesulfonic acid 

Diisopropylnaphthalenesulfonic acid, sodium salt 

Dipentylnaphthalenesulfonic acid 

Dipentylnaphthalenesulfonic acid, (mixed alkyl) amine 
salt. 

»Isopropylnaphthalenesulfonio acid 

Methylenebls(2-naphthalenesulfonic acid) 

Metlyrlnaphthalenesulfonic acid, sodium salt 

Methylnonylnaphthaleneeulfonlc acid, sodium salt 

Pentylnaphthalenesulfonic acid 

Tetrahydronaphthalenesulfonic acid, sodium salt 

»Other benzenoid surface -active agents: 

Butylhydroxybiphenyleulf onic acid 

Dodecyldiphenj'loxldedisulfonic acid, sodium salt 

Heptadecylmethylbenzimidazollnesulfonlc acid, sodium 
salt. 

n-Octylphenol, ethoxylated and sulfonated 

Petroleumsulfonlc acid, water soluble (acid layer), 

sodium salt. 
Triohlorophenol sulfate, ethanolamlne salt 



SMC, WON. 

APD, ARD, CIN, CTL, PCS, RCD, SNW, STF, WTC. 

PCS, STP, WTC. 

PCS. 

AAC, AML, APX, AHD, ARL, ATR, CLD, CO, CP, CTL, DEP, 
EFH, EMK, HLI, HRT, ICI, LEV, MON, NAC, NOP, PCI, 
PC, PIL, PRX, RCD, SEY, STP, TN, UNP, WIC, WON, WTC. 

AML, ARD, ARL, ATR, CIN, CO, CTL, HLI, NAC, PCS, PEK, 
PIL, RCD, RZL, SOS, STP, WTC. 

CHM. 

MDN. 

CO. 

WTC. 

MON. 

RCD. 

PRX. 

BLA, CP, PRX, RCD, WTC. 

AAC. 

PRC. 

MAR. 

CRZ. 

CRZ, CWP, INP, LKY, LPC, MAR, PSP. 

MAR. 

CRZ. 

LPC, MAR. 

CRZ, CWP, IN?, MAR, WVA. 

G. 

SCP. 

PFZ. 

CLD, CMG, GGY. 

G, MRA, S. 

PFZ. 

DUP, G, GRD. 

G, PFZ. 

GGY. 

VIS. 

DUP, NAC, NOP, ONX. 

DUP. 

UDI. 

UDI. 

ONX. 

DUP. 

ICO, RBC. 

DOW. 

TRC. 

RH. 

SIN, SON. 



158 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 19B. 



-Surface -active agents for which U.S. production or sales were reported, identified by 
manufacturer, i565--Contmued 



Chemical 






Manufacturers' identification 
(according to list in table 


codes 
22) 


NONBENZENOID SURFACE-ACTIVE AGENTS 










Not Sulfated or Sulfonated 










»Aniides, amines, and quaternary ammonium salts: 










»Acyolio quaternary ammonium salts: 










AUcylethyldiraethylaramonium salts ; 










Ethyldimethyl(9-OGtadeoenyl) ammonium bromide 


ONX. 








Ethyldimethyloctadecylammoniiim ethyl hydrogen 


APD. 








phosphite. 










Ethyldimethyl ( soybean oil alkyl) ammonium bromide 


BC. 








Alkyltrimethylaramonium salts: 










(Coconut oil alkyl)trimethylammonium chloride 


ARC. 








*Dodecyltriraethylammonium bromide 


DUP. 








*Dodeoyltrimetliylammonium chloride 


ARC, 


GNM, 


RCD. 




»Hexadecyltrimethylammonium bromide 


DUP, 


FIN, 


ICI. 




-»Hexadecyltrimethylaramonium chloride 


ARC, 


WSN. 








FIN. 












(Hydrogenated tallow alkyl)trimethylammonium 


ARC. 








chloride . 










Trimethyl(mixed alkyl) ammonium chloride 


GNM. 








Trimethyloctadecylammoniura chloride 


ARC. 








Trimethyl ( soybean oil aUcyl) ammonium chloride 


ARC, 


VAC. 






Trimethyl( tallow allcyl) ammonium chloride 


ARC, 


GNM. 






Dialkyldimethylammonium salts : 










Bis(coconut oil alkyl) dimethylammonium chloride 


ARC, 


GNM. 






*Bis (hydrogenated tallow aliyl ) dimethylammonium 


ATM, 


ARC, 


FOR, GNM, VAC. 




chloride. 










Didodecyldimethylammonium bromide 


ONX. 








Dimethylbis( soybean oil a liyl) ammonium chloride 


ARC. 








Dime thy Idiootadeoylaramonium chloride 


PG. 








Other acyclic quaternary ammonium salts; 










(Coconut oil alkyl)bis(2-hydroxyethyl, ethoxylated)- 


ARC, 


VAC. 






methylammonium chloride. 


DUP. 








Decylbetaine — — — — — — — •— 






DUP. 








fieAaaecyj-Dextime— -" - — — — — •-.. — • — .. _ 




( 2 -Hydroxyethy 1 ) dimethyl ( stearamidopropyl ) ammonium 


ACY. 








dihydrogen phosphate. 










( 2-Hydroxyethyl) dimethyl ( stearamidopropyl ) ammonium 


ACY. 








nitrate. 










2-Hydroxy-l,3-propylenebis[ (coconut oil alkyl) - 


TRC. 








dimethylammonium chloride]. 










Methyltrioctylaramonium chloride --- 


GNM. 








Methyltris(mixed allsyl )anmonium chloride 

Qctadecvlbetaine 


AIM, 

DUP. 


VAC. 










Triethyloctadeoyloxymethyl ammonium chloride 


X. 








«Amine salts: 










»Amine acetates: 












AIM, 
ATM, 


ARC. 
ARC, 






^ooconux oix ajjcyx,) amine acetaxe 

(Hydrogenated tallow alkyl)amine acetate 


CIN, WAY. 




(9-Octadecenyl) amine acetate 


GNM. 










ACY, 
ARC. 


ARC. 






y 












ARC. 
ADM, 
PG. 
APD. 








f'Pallow alkvl)amine acetate 


ARC. 












N-tlailow alKyl Jdiethanolamine acetate 

Naphthenic acids, N-(tallow alltyl)-l,3-propylene- 








diamine salt. 










Oleic acid, diethylamine salt-- 


WTC. 








»01eic acid, triethanolamine salt 


DOM, 


HAL, 


NOP, TCC. 





SURFACE-ACTIVE AGENTS 



159 



TABLE 19B. 



-Surface -active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



NONBENZENOID SURFACE- ACTIVE AGENTS— Continued 
Not Sulfated or Sulfonated— Continued 

•Amides, amines, and quaternary ammonium salts — Continued 
»Amine salts — Continued 

Rosin acids, triethanolamine salt 

Stearic acid, ethoxylated ethylenediamine salt 

Stearic acid, N,N,N',N'-tetra]d.s(2-hydroxyethyl)- 
ethylenediamine salt. 

Stearic acid, triethanolamine salt 

»Amines , alkoxy lated : 

N,N-Bis(2-hydroxyethyl)dodecylamine 

N,N-Bis(2-hydroxyethyl)octadecy lamina 

(Coconut oil alj£yl)amine, ethoxylated 

•(Hydrogenated tallow aliyl) amine, ethoxylated 

N-(2-Hydroxyethyl)-N,N',N'-tris(2-hydroxypropyl) 
ethylenediamine . 

»(Mixed alkyl)amlne, ethoxylated 

(9-Ootadecenyl) amine, ethoxylated 

Octadecylamine, ethoxylated 

Polyethylenepolyamine, alioxylated 

»Rosin amine, ethoxylated 

(Soybean oil alkyl)amine, ethoxylated 

»(Tallow alkyl)amine, ethoxylated 

N-(Tallow alkyl)-l,3-propylenediamine, ethoxylated--- 

N,N,N',N'-Tetrakis(2-hydroxyethyl)ethylenediamine 

N, N, N' , N' -Tetrakis(2-hydroxypropyl) ethylenediamine, 
propoxylated and ethoxylated. 

Triethanolamine, ethoxylated 

*Fatty acid - alkanolamine condensates: 
*Diethanolamine condensates : 

»Capric acid - diethanolamine condensate 

Castor oil acids - diethanolamine condensate 

Coconut oil acids - diethanolamine condensates: 
»(Amine/acid ratio=2/l) 



Manufacturers' identification codes 
(according to list in table 22) 



*(Amine/acid ratio=l/l)- 



All other ratios 

»Lauric acid - diethanolamine condensate- 



Linoleic acid - diethanolamine condensate- 
Myristic acid - diethanolamine condensate- 
Oleic acid - diethanolamine condensates: 

«(Amine/acid ratio=2/l) 

»(Amine/acid ratio=l/l) 

•Stearic acid - diethanolamine condensate — 



•Tail oil acids - diethanolamine condensate — 

Tallow acids - diethanolamine condensate 

Other diethanolamine condensates 

Ethanolamine condensates : 

Coconut oil acids - ethanolamine condensate- 
Laurie acid - ethanolamine condensate 

Myristic acid - ethanolamine condensate 

Stearic acid - ethanolamine condensates: 

»(Amine/acid ratio=l/l) 

«(Amine/acid ratio=3/2) 

*A11 other ratios 

Tall oil acid - ethanolamine condensate 



RTF. 
CSI. 
ICI. 

AMI, TCC. 

FIN. 

FIN. 

APD, ARC, VAC, VIS. 

TCH, TRC, VAC. 

VIS. 

APD, G, NOP, RH, TRC, VAC. 

ARC. 

ARC, ICI, VAC. 

VIS. 

APD, HPC, PCS, RTF, VIS. 

ARC, VAC. 

ARC, DUP, TRC. 

ARC. 

VIS. 

WYN. 

JCC. 



GGY, ONX, PCS, RZL. 
PCS, VND. 

AML, ARD, BSC, BS«, CIN, CLI, CTL, DEP, DR», HLI, HRT, 
JOR, KNP, LEV, LUR, MOA, NOP, ONX, PC, PCS, PG, PNX, 
RCD, RFC, RZL, SBC, SNW, TCC, TRC, TXC, TXZ, UNN, UVC, 
VAL, VND, WTC. 

APX, ARD, ARL, CLI, CST, CTL, DRW, EFH, EMK, GCT, HLI, 
MOA, MRV, NOP, ONX, PCS, PEK, QCP, RCD, RPC, RZL, SBC, 
SCO, STP, TXZ. 

JRG, PCS. 

ARD, CLI, CTL, HLI, MOA, NOP, ONX, PCS, PG, RCD, RZL, 
SBC, WON, WTC. 

VND. 

CLI. 

CCW, CLI, MRA, ONX, RCD, SEY, STP, WTC. 

GGY, NOP, PCS, SBC, SCP, SEY, STP. 

AML, APX, ARD, BSC, CLI, DEP, Qffi, GGY, GLY, JOR, MRA, 

NOP, ONX, RPC, SCO, TXC, VAL, WTC. 

EFH, MRA, RCD, SEY, WTC. 

PCS, PG, SEY. 

BSC, HLI, RPC, SEY, WTC. 

AML, APX, CCL, CLI, HRT, MOA, PCS, PQ, VND, WTC. 
WTC. 

WTC. 

ARD, CIN, KES, STP, VND. 

SBC, WTC. 

CLI. 

JCC. 



160 



SYNTHETIC ORGANIC CHEMICALS^ 1963 



TABLE 19B. 



-Surface -active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1963— Conimaed 



Chemical 






Manufacturers' identification codes 






(according to list in table 22) 


NONBENZENOID SUHFACE-ACTIVE AGENTS— Continued 










Not Sulfated or Sui/ona !ed— Continued 










*Amides, amines, and quaternary anmonium salts--Continued 










»Fatty acid - alkanolamine condensates — Continued 










Isopropanolamine condensates : 










Coopnut oil acids - isopropanolamine condensate 


LEV, 


STP 






Laurie acid - isopropanolamine condensate 


ARC, 


ARD, 


CLI, 


PCS, WTC. 


Myristic acid - isopropanolamine condensate 


ARD. 








Oleic acid - isopropanolamine condensate 


WTC. 








Fatty acid - alkanolamine condensates, ethoxylated: 










Hydrogenated tallow acids - ethanolamine condensate. 


ARC. 








ethoxylated. 










Oleic acid - ethanolamine condensate, ethoxylated 


ARC, 


G. 






Oleic acid - methanolamine condensate, ethoxylated 


G. 








Tall oil acids - ethanolamine condensate, ethoxylated- 


JCC. 








»Fatty acid - polyamine condensates: 










Adipic and stearic acids - diethylenetriamlne con- 


APX. 








densate. 










Coconut oil acids - diethylenetriamine condensate 


APX, 


NOP. 






Mixed fatty acid - polyalkylenepolyamine condensate 


VIS. 








Oleic acid - aminoethylpiperazine condensate 


PCS. 








Oleic acid - diethylenetriamine condensate 


HDG, 


PCS. 






Oleic acid - diethylenetriamine condensate, acetic 


PCS, 


UVC. 






acid salt. 










Oleic acid - N,N-dimethyl-l,3-propylenediamine con- 


CCW, 


DUP, 


SNW, 


TRC. 


densate. 










Oleic acid - ethylenediamine condensate (amine/acid 


CCW. 








ratio = 1/2). 










Pelargonic acid - tetraethylenepentamine condensate 


ICI. 








^Stearic acid - diethylenetriamine condensate 


APX, 


CST, 


DEP, 


HRT, NOP, ONX, QCP, S. 


Stearic acid - N,N-diethylethylenediamine condensate — 


CBP. 








Stearic acid - N,N'-diethylethylenediamine condensate 


SNW. 








(amine/acid ratio = 1/2). 










Stearic acid - dipropylenetriamine condensate 


X. 








Stearic acid - etliylenediamine condensate (amine/acid 


CCW, 


ICI. 






ratio = 1/2). 










Stearic acid - tetraethylenepentamine condensate 


ICI, 


ONX. 






Tall oil acids - diethylenetriamine condensate 


NCW. 








All other - 


WM. 








»fatty acid - polyamine condensates, ethoxylated: 










Coconut oil acids - diethylenetriamine condensate. 


TCC. 








polyethoxylated . 










Coconut oil acids - ethylenediamine condensate. 


DEX, 


NOP. 






monoethoxylated . 










Mixed fatty acid - aliylenediaraine condensate, poly- 


G. 








ethoxylated. 










Oleic acid - ethylenediamine condensate, mono- 


CLD, 


DEX, 


NOP, 


SOC, TNA. 


ethoxylated. 










Palm oil acids - ethylenediamine condensate, mono- 


APX, 


SCP. 






ethoxylated . 










Stearic acid - diethylenetriamine condensate, poly- 


TCC, 


TRC. 






ethoxylated . 










Stearic acid - ethylenediamine condensate, diethoxy- 


TCC. 








lated. 










*Stearic acid - ethylenediamine condensate, mono- 


AML, 


CLD, 


DEP, 


DEX, ICI, MRA, NOP, S, SCP, SNW. 


ethoxylated . 










Stearic acid - ethylenediamine condensate, poly- 


APD, 


EFH, 


TCC. 





ethoxylated. 



SURFACE-ACTIVE AGENTS 



161 



TABLE 19B.— Surface -active agents for which U.S. production or sales were reported, identified by 
manufactured, 1963 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



NONBENZENOID SURFACE-ACTIVE AGENTS—Continued 
Not Sulfated or Sulf ana ted— Conlinued 

♦Amides, amines, and quaternary ammonium salts — Continued 
♦Heterocyclic amides, amines, and quaternary ammonium 
salts: 
Imidazole derivatives : 

l,l-Bis(carboxymethyl)-2-undecyl-2-imidazolinium 

chloride, disodium salt. 
1, l-Bis(carboxymethyl )-2-undecyl-2-imidazolinium 

hydroxide, disodium salt. 
l-Carboxymethyl-2-heptadecyl-l- ( 2-hydroxyethyl) -2- 
imidazolinium hydroxide, sodium derivative, sodium 
salt. 
1-Carboxymethy 1-1- (2-hydroxyethyl )-2-nonyl-2-imidazo- 

linium chloride, sodium salt. 
1- ftarboxymethy 1-1- (2-hydroxyethyl ) -2 -nonyl -2 -imidazo- 

linium hydroxide, sodium derivative, sodium salt. 
1-Carboxymethyl-l- (2-hydroxyethyl ) -2-undecyl-2- 

imldazolinivim hydroxide, sodium derivative, sodium 
salt. 
1-Ethy 1-2- ( 8-heptadec enyl ) - 1- (2-hydroxyethyl ) - 2- 
imidazolinium bromide. 
*2- ( 8-Heptadecenyl ) -1- ( 2-hydroxyethyl ) -2-imidazoline— 

2-(8-Heptadecenyl)-2-imidazollne 

*2-Heptadecyl-l-( 2-hydroxyethyl) -2-imidazoline 

2-Heptadecyl-2-imidazollne 

l-(2-Hydroxyethyl)-2-nonyl-2-imidazoline 

'^l-(2-Hydroxyethyl)-2-tridecyl-2-imldazolinium 
chloride . 

l-(2-Hydroxyethyl)-2-undecyl-2-imidazoline 

Rosinpolyamidoimidazoline 

Oxazole derivatives: 

2- (8-Heptadecenyl) -A, "4-bis(hydroxymethyl) -2- 

oxazoline. 
2- (8-Heptadecenyl )-<i-hydroxymethyl-4-methyl-2- 
oxazoline. 
»N-Substituted amino acids and polypeptides: 

N-[ 2- ( Carboxymethylamino) ethyl] -N- ( 2-hydroxyethyl ) - 
coconut oil amide, sodium salt. 

N-(Coconut oil acyl)sarcosine 

N-(Coconut oil aLkyl)-)3-alanine 

N-Dodecyl-3-iminodipropionic acid 

N- ( 2-Hydroxyethyl ) -N- ( 2-stearamidoethyl)glycine 

N-Lauroylpolypeptide 

N-Lauroylsarcosine, sodium salt 

N-Oleoylpolypeptide 

N-Oleoylsarcosine, sodium salt 

Polypeptide 

N-Stearoylsarcosine, sodium salt -- 

N-(Tallow alkyl) -3-tminodiproplonic acid, sodium salt 
Other amides, amines, and quaternary ammonium salts: 
N, N-Bis ( 2-hydroxyethyl ) -2- ( stearamidomethoxy ) ethyl- 
amine. 

N-(Coconut oil alkyl )-i,3-propylenediamine 

N-Dodecyldiethylenetriamine 

Hexadecyldimethylamine oxide 

N- (Mixed alliyl)polyethylenepolyamine 

N-(9|-Octadecenyl)-l,3-propylenediamine 



PCS. 
MIR. 
MIR. 

PCS. 
MIR. 

MIR. 

BC. 

FBC, GGY, PCS, UVC. 

HDG. 

GGY, ONX, UVC. 

SCO. 

PCS. 

GGY. 

GGY, UVC. 
GRD, UVC. 

COM, NOP, SEY. 

COM, UVC. 

TCC. 

GGY. 

GNM. 

GNM. 

G. 

MYW. 

CP, GGY, ONX. 

MYW. 

G, GGY. 

MYW. 

GGY. 

GNM. 

TRC. 

GNM. 
FIN. 
ONX. 
CCW. 
GNM. 



162 



SYNTHETIC ORGANIC CHEMICALS. 1963 



TABLE 19B. — Surface -active agents for which U.S. production or sales were reported, identified by 
manufacturer , 1963 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 

Not Sulfated or Sulfonated— Continued 

»Amides, amines, and quaternary ammonium salts — Continued 
»Other amides, amines, and quaternary ammonium 
salts — Continued 
Stearic acid - M-(2-cyanoethyl)diethylenetriainine 
condensate (amine/acid ratio=l/2). 

Stearoylbiguanidine hydrochloride 

N-( Tallow alkyl)-l,3-propylenedlamine 

All other 

»Cartioxylic acid esters: 
Anhydrosorbltol esters : 

Anhydrosorbitol dioleate 

Aniiydrosorbitol mixed fatty acid ester 

Anhydrosorbitol monolaurate 

Anhydrosorbltol mono-oleate 

Anhydrosorbitol monopalmitate 

Anhydrosorbitol monostearate 

Anhydrosorbitol sesqui-oleate 

Anhydrosorbitol tall oil ester 

Anhydrosorbitol tetrastearate 

Anhydrosorbitol trioleate 

Anhydrosorbitol tririoinoleate 

Anhydrosorbitol tristearate 

»Diethylene glycol esters : 

Diethylene glycol distearate 

Diethylene glycol mono(coconut oil)ester 

*Diethylene glycol monolaurate 

^Diethylene glycol mono-oleate 

Diethylene glycol monoricinoleate 

^Diethylene glycol monostearate 

Diethylene glycol tall oil ester 

Ethoxylated anhydrosorbitol esters: 

Ethoxylated anhydrosorbitol castor oil ester 

Ethoxylated anhydrosorbitol monolaxirate 

^Ethoxylated anhydrosorbitol mono-oleate 

Ethoxylated anhydrosorbitol monopalmitate 

»Ethoxylated anhydrosorbitol monostearate 

Ethoxylated anhydrosorbitol tall oil ester 

Ethoxylated anhydrosorbitol trioleate 

Ethoxylated anhydrosorbitol tristearate 

Ethoxylated sorbitol esters: 

Ethoxylated sorbitol beeswax ester 

Ethoxylated sorbitol distearate 

Ethoxylated sorbitol hexaoleate 

Ethoxylated sorbitol hexa(tall oil) ester 

Ethoxylated sorbitol lanolin ester 

Ethoxylated sorbitol mono-oleate 

Ethoxylated sorbitol pentalaurate 

Ethoxylated sorbitol pentaoleate, acetylated 

Ethoxylated sorbitol penta(tall oil) ester 

Ethoxylated sorbitol tall oil ester 

Ethoxylated sorbitol tetra(laurate, oleate) 

Ethoxylated sorbitol tetra(tall oil) ester 



GNM. 








CGL, 


STC, 


TRC, 


x. 


APD. 
GLY. 








APD, 


GLY, 


HDG. 




APD, 


GLY, 


HDG, 


PCS. 


APD, 


GLY. 






APD, 


GLY, 


HDG, 


PCS. 


GLY. 








APD, 


GLY, 


HDG. 




APD. 








APD, 


GLY, 


HDG. 




APD. 








APD. 








KES. 








DRW. 









CCW, DRW, GLY, HAL, HDG, KAL, KES, NOP, SEY, WTC. 

EMR, GLY, HAL, KES, WTC. 

GLY. 

AML, CCW, CIN, CLI, GLY, HAL, HDG, KES, NOP, PC, PCS, 

QCP, SEY, TCC, VAL, VND, WM, WTC. 
HDG, QCP, WTC. 

APD. 

AAC, APD, DRW, GLY, TCH. 

AAC, APD, DRW, GLY, HDG, PCS, TCH. 

APD, TCH. 

AAC, APD, DRW, GLY, HDG, PCS, TCH. 

APD, TCH. 

AAC, APD, GLY, TCH. 

APD, DRW, GLY, TCH. 

APD. 

APD. 

APD. 

APD, RTF. 

APD. 

APD, VAC. 

APD. 

APD. 

APD. 

APD. 

APD. 

APD. 



SURFACE-ACTIVE AGENTS 



163 



TABLE 19B. — Surface -active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufaotui-ers ' identification codes 
(according to list in table 22) 



Chemical 



NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 
Not Sulfated or Sulfonated— Continued 

»Carboxylic acid esters — Continued 
^■Ethylene glycol esters: 

Ethylene glycol distearate 

Ethylene glycol mono-oleate 

^Ethylene glycol monostearate 

All other 

»Glycerol esters: 

^Complex glycerol esters: 

Glycerol diacetyltartrate monostearate 

Glycerol lactate palmitate 

Glycerol lactate stearate 

Glycerol maleate mono-oleate 

Glycerol mono-oleate, acetylated 

♦Glycerol mono- and diesters of chemically defined 
fatty acids: 

Glycerol dioleate 

♦Glycerol distearate 

Glycerol monocaprylate 

Glycerol monolaurate 

♦Glycerol mono-oleate 

Glycerol monoricinoleate 

♦Glycerol monostearate 

♦Glycerol mono- and diesters of mixed fatty acids: 

Glycerol diester of lard 

Glycerol diester of unspecified mixed fatty acids 

Glycerol ester of castor oil acids 

Glycerol mono- and diesters of unspecified mixed 
fatty acids. 

Glycerol monoester of coconut oil acids 

Glycerol monoester of cottonseed oil acids 

Glycerol monoester of edible fats and oils 

Glycerol monoester of hydrogenated cottonseed oil 

acids. 
Glycerol monoester of hydrogenated soybean oil acids 

Glycerol monoester of lard 

Glycerol monoester of unspecified mixed fatty acids- 
♦Polyethylene glycol esters: 

♦Polyethylene glycol esters of chemically defined 
fatty acids: 

♦Polyethylene glycol dilaurate 

♦Polyethylene glycol dioleate 

♦Polyethylene glycol distearate 

♦Polyethylene glycol monolaurate 

♦Polyethylene glycol mono-oleate 

Polyethylene glycol monopalmltate 

Polyethylene glycol monoricinoleate 

♦Polyethylene glycol monostearate 

All other 



EMR, HAL, HDG, KES. 

EFH, HAL. 

CCW, CLI, GLY, HAL, HDG, KES, KNP, PCS, VND, WM. 



DRW, PCS, WTC. 
DRW, GLD. 
APD, GLD. 
NOP, WTC. 



KES. 

APX, EFH, KES, PCS. 

KES. 

GLY, KES, KNP. 

ACT, APD, CCW, DRW, EK, EMR, GLY, HAL, HDG, KES, PAR, 

PCS, VND, WM. 
CCW, HAL. 
CCW, DRW, EK, GLY, HAL, HDG, KES, LUR, MCO, MRA, NOP, 

NW, PCS, PG, SNW, TCC, VND, WM, WTC, x. 



EFH, PCS. 
HAL. 
GLY. 
APD. 












DRW, EFH, 
DRW, GLD, 
EK. 


HAL, 
PCS. 


HDG, 


JRG, 


WM. 




LEV. 












DRW. 
EK, GLD. 

EFH, am. 


GLD, 


GLY, 


HDG, 


LEV, 


WTC 



EFH, GLY, HAL, HDG, JOR, KES, PCS, UVC, WM. 

CLD, EFH, GGY, GLY, HAL, HDG, KES, NOP, OTH, SPP, UVC, 

WM. 
GLY, HAL, KES, PCS, QCP. 
AAC, ARC, BSC, CCA, DRW, GGY, GLY, HAL, ICI, JOR, KES, 

KNP, NOP, QCP, SYC, TCH, UVC, WM. 
ARC, CCA, CLD, CRC, DEX, DRW, G, GGY, GLY, HAL, HDG, 

ICI, KES, NOP, ONX, PAR, PCS, QCP, SPP, SYC, TCH, 

UVC, WTC. 
APD, CST. 
AAC, HAL, NOP. 
AML, APD, ARC, CCW, CIN, DEP, DEX, DRW, G, GGY, GLY, 

HAL, HDG, ICI, JOR, KES, KNP, NOP, ONX, PC, PCS, PD, 

RH, RFC, SEY, TCH, UNN, UVC, VND, WTC. 
CCA. 



164 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 19B.— Surface -active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufacturers ' Identification codes 
(according to list in table 22) 



NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 

Nat Sulfated or Sulfonated— Continued 

*Carboxylic acid esters — Continued 

♦Polyethylene glycol esters — Continued 

♦Polyethylene glycol esters of mixed fatty acids: 

Polyethylene glycol ester of castor oil acids 

♦Polyethylene glycol ester of coconut oil acids 

Polyethylene glycol ester of rosin acids 

♦Polyethylene glycol ester of tall oil acids 

Polyethylene glycol ester of tallow acids 

Polyethylene glycol ester of unspecified mixed fatty 
acids. 
1,2-Propanediol esters: 

1,2-Propanediol distearate 

♦1,2-Propanediol monolaurate 

1,2-Propanediol mono-oleate 

♦1,2-Propanediol monostearate 

Other carboxylic acid esters : 

Anhydrosorbitol glycerol monolaurate 

Coconut oil acids, ethoxylated methanol ester 

Diisobutylene maleate 

Disorbitolethoxyethylpropoxypropyl diglycolate 

Ethoxylated glucose distearate 

Ethoxylated 1,2-propanediol stearate 

Mannitol dioleate, propoxylated 

Methyl glucoside laurate 

Methyl glucoside oleate 

Pentaerythritol distearate 

Polyaliylene glycol adipate 

Polyalltylene glycol diglycolate 

Polyaliylene glycol dimaleate 

Polyalkylene glycol naphthenate 

Polyglycerol monoester of cottonseed oil acids 

Polyglyoerol oleate 

Sucrose esters of fatty acids 

All other 

♦Ethers : 

n-Butyl alcohol, ethoxylated 

♦Castor oil, ethoxylated 

Coconut oil alcohols, ethoxylated 

n-Decyl alcohol, ethoxylated 

♦n-Dodecyl alcohol, ethoxylated 

n-Hexadecyl alcohol, ethoxylated 

Hydrogenated castor oil, ethoxylated 

Iso-octyl alcohol, ethoxylated 

♦Lanolin, ethoxylated 

Mixed primary straight-chain alcohols, ethoxylated 

Mixed primary straight-chain alcohols, propoxylated 

*9-0ctadecenyl alcohol, ethoxylated 

♦n-Octadecyl alcohol, ethoxylated 

Polyethylene glycol tert-dodecyl thioether 

Poly(mixed ethylene, propylene) glycol 

Polypropylene glycol, ethoxylated • 

Ricingleyl alcohol, propoxylated and ethoxylated 

Rosin alcohol, ethoxylated 

Sorbitol, alkoxylated 

Sperm oil alcohol, ethoxylated 



G, GGY, GLY, NOP, UVC, WTC, 

ARL, GLY, JRG, NOP, ONX, PG, VND. 

APD, HPC, QCP. 

AML, APD, APX, ARC, DRW, GLY, HDG, JCC, KES, MON, NOP, 

OMC, RTF, TCH, UVC, WTC. 
ONX, SOS. 
GLY, HDG, SYC. 



PCS. 

HAL, KES, SBC, WM. 

HAL, KES. 

APD, CCW, GLY, HAL, HDG, KES, PCS, PG, WTC. 

APD. 

DRW, JOR. 

RH. 

APD. 

APD. 

APD. 

APD. 

HDG. 

HDG. 

VAL. 

PFZ. 

RTF, VIS. 

VIS. 

APD. 

DRW. 

DRW, WTC. 

SUG. 

WM. 

VAC. 

AAC, APD, BAC, DRW, ICI, NOP, PCS, TCH, VIS. 

G. 

G, ICI, PCS. 

AAC, APD, DRW, DUP, G, GLY, JCC, NAC, CMC, PCS, UCC. 

APD, ICI, JCC, TRC. 

APD, TCH. 

G. 

AAC, APD, VAC. 

CO, G, JCC, RH, RTF, TCH, VAC. 

JCC. 

AAC, APD, DRW, DUP, G, ICI, NOP, TCH, TRC. 

AAC, APD, G. 

MON, PAS. 

UCC, WYN. 

RTF, VIS, WYN. 

PCS. 

HPC, TRC, VIS. 

APD, VAC. 

DUP. 



SURFACE-ACTIVE AGENTS 



165 



TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 
Not Sulfated or Sulfonated- -Continued 

»Ethers — Continued 

Tallow alcohol, ethoxylated 

2,'i,7,9-Tetramethyl-5-decyne-i,7-diol, ethoxylated 

*Trideoyl alcohol, ethoxylated 

Tridecyl alcohol, ethoxylated and carbonated, sodium 
salt. 

Tridecyl alcohol, propoxylated and ethoxylated 

Trimethylheptanol, ethoxylated 

Trijnethylnonyl alcohol, ethoxylated 

Trimethylolpropane, alkoxylated 

All other 

*Fatty acids, potassium and sodium salts : 

Castor oil acids, potassium salt 

*Castor oil acids, sodium salt 

*Coconut oil acids, potassium salt 

Coconut oil acids, sodium salt 

Com oil acids, potassium salt 

Com oil acids, sodium salt 

Cottonseed oil acids, sodium salt 

*Lauric acid, potassium ssilt 

Mixed vegetable fatty acids, potassium salt 

*01eic acid, potassium salt 

*01elc acid, sodium salt — 

Olive oil acids, sodium salt 

Palm oil acids, sodium salt 

Peanut oil acids, potassium salt 

Rosin acids, potassium salt 

»Rosin acids, sodium salt 

Soybean oil acids, potassium salt 

Stearic acid, potassium salt 

^Stearic acid, sodium salt 

»Tall oil acids, potassium salt 

»Tall oil acids, sodium salt 

•Tallow acids, potassium salt 

»Tallow acids, sodium salt 

All other 

•Phosphoric and polyphosphoric acid esters : 

Alcohols, alkoxylated and phosphated or polyphosphated : 

Dodecyl alcohol, ethoxylated and phosphated 

Dodecyl alcohol, propoxylated and polyphosphated 

2-Ethylhexyl alcohol, ethoxylated and phosphated 

9-Octadecenyl alcohol, ethoxylated and phosphated 

Ootyl phosphate, ethoxylated 

Propylene glycol, propoxylated and phosphated 

Tridecyl alcohol, ethoxylated and phosphated 

•Alcohols, phosphated and polyphosphated: 

Decyl, octyl phosphate 

2-Ethylhexyl phosphate 

»2-Ethylhexyl phosphate, sodium salt 

2-Ethylhexyl polyphosphate 

Hexyl polyphosphate, potassium salt 

Mixed alkyl phosphate, dlethanolamine salt 

Mixed decyl, dodecyl, and octyl phosphates, morphollne 
salt. 



AAC, AHC, APD, DRW, EFH, G, GLY, ICI, JCC, WON, CMC, 
PCS, RTF, TCH, UCC, VIS. 



JCC, 


PCS. 
















PCS. 


















UCC. 


















RTF. 


















UCC. 


















BAG, 


OTT, 


SEA. 














BAG, 


MRV, 


SEA, 


WHI. 












ARL, 


LUR, 


OTT, 


PGH. 












CON. 


















PGH. 


















LUR. 


















rai. 


















BSC, 


DRW, 


NOP. 














AML, 


ARL, 


PGH. 














AMI, 


BSC, 


DAN, 


DEX, 


EFH, 


NOP, 


OTH, 


OTT, QCP, S, SHP 


TRC, WBG, WTC. 












BSW, 


LUR, 


NOP, 


QCP, 


SEA, 


WBG, 


WTC. 






LUR. 


















LUR. 


















KAL, 


SLC. 
















OTT, 


SNW. 
















MRA, 


OPT, 


QCP. 














CON, 


KAL. 
















DRW, 


VAL. 
















BSW, 


LEV, 


MAL, 


NOP, 


WTC. 










BSC, 


GIN, 


CON, 


KAL, 


LUR, 


OTT, 


PNX, 


QCP. 




BSW, 


DEX, 


PCS, 


QGP, 


UNP. 










OTT. 


















CON, 


LUR, 


NOP, 


QCP. 












SLC. 


















G. 


















VIC. 


















WAY. 


















G. 


















DUP. 


















APD. 


















G, RZL, SEY. 














UVC. 


















UVC. 


















TXZ, 


UCC, 


UVC. 














UVC. 


















x. 


















DUP. 


















DUP. 



















166 



SYNTHETIC ORGANIC CHEMICALS 1963 



TABLE 19B. — Surface -active agents for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 

Not Sulfated or Sulfonated- -Continued 

»Phosphoric and polyphosphoric acid esters--Continued 
»Alcohols, phosphated and polyphosphated — Continued 

Mixed mono- and dialkyl phosphate 

9-Octadeoenyl phosphate 

Ootyl phosphate, alkylamine salt 

Octyl polyphosphate 

Octyl- polyphosphate, potassium salt 

Octyl polyphosphate, sodium salt 

Tri(mixed alkyl) phosphate 

Other phosphoric and polyphosphoric acid esters 

•Other nonbenzenoid surface-active agents, not sulfated or 
sulfonated : 

2,4,7,9-Tetraniethyl-5-decyne-<i,7-diol 

All other 

Sulfated and Sulfonated 

Acids, sulfated and sulfonated : 

Acetyloleic acid, sulfonated 

»01eio acid, sulfonated 

Ricinoleic acid, sulfonated 

Alcohols, sulfated and sulfonated: 

Branched hexadecyl sulfate, sodium salt 

n-Deoyl sulfate, sodium salt 

n-Deoyl sulfate, triethanolamine salt 

3,9-Diethyl-6-tridecyl sulfate 

n-Dodeoyl sulfate, 2-amino-2-methylpropanol salt 

*n-Dodecyl sulfate, ammonium salt 

n-Dodecyl sulfate, dlethanolamine salt 

n-Dodecyl sulfate, N,N-diethyloyclohexylamine salt 

n-Dodecyl sulfate, isopropanolamine salt 

n-Dodecyl sulfate, magnesium salt 

n-Dodecyl sulfate, potassium salt 

«n-Dodecyl sulfate, sodium salt 

*n-Dodecyl sulfate, triethanolamine salt 

2-Ethylhexyl sulfate, sodium salt 

7-Ethyl -2 -methyl -4-undecyl sulfate 

Hexadecyl and octadecenyl sulfate 

n-Hexadeoyl sulfate 

Hexyl sulfate, potassium salt 

Mixed coconut oil allsyl and sperm oil allsyl sulfate, 

sodium salt. 

Nonyl sulfate 

n-Octadecyl sulfate 

n-Octadeoyl sulfate, sodium salt 

n-Oetadecyl sulfate, triethanolamine salt 

n-Octyl sulfate, sodium salt 

n-Tetradecyl sulfate, sodium salt 

Tridecyl sulfate, sodium salt 

Amides, amines, and quaternary ammonium salts, sulfated 

and sulfonated: 
»Dicarboxylic acid' amides, sulfated and sulfonated: 

N-(l,2,'Dlcarboxyethyl )-N-octadecylsuIfosuccinamic 
acid, tetrasodium salt. 



DUP, 


UVC. 




DUP. 






DUP. 






BCN, 


DEX, 


UVC 


x. 






VIC. 






VIC. 






VIC, 


WTC. 




AIR. 






AIR, 


LMI, 


STC 



ACT, ACY, BRY, DRW, G, ICI, LEA, LUR, MRV, NOP, PCI, 

QCP, SCO, SWT, TN, WHI, WHW. 
NOP. 

APX. 

DUP, ONX, PCS. 

DUP. 

UCC. 

DUP. 

AAC, DUP, ONX, PCS, STP. 

AAC, DUP, HLI, JRG, ONX, STP. 

DUP. 

JRG, PCS. 

AAC, HLI. 

HLI, PG. 

AAC, DUP, HLI, JRG, MYW, ONX, PCl, PCS, PG, RCD, RET, 

STP. 
AAC, DUP, HLI, MYW, ONX, PCS, PG, RCD, RET, STP. 
AAC, UCC, WTC. 
UCC. 
CMG. 

AAC, DUP. 
DEX. 
DUP. 

TN. 

AAC, DUP, BDC, PG. 

ONX. 

DUP. 

DUP, PCS. 

ONX. 

AAC. 



SURFACE-ACTIVE AGENTS 



167 



TABLE 19B. -Surface-active agents for which U.S. production or sales were reported, identified by 

raavufacturer, 1963 — Continued 



Chemical 




Manufacturers' identification codes 
(according to list in table 22) 


NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 






Sulfated and Sulfonated— Continued 






Amides, amines, and quaternary ammonium salts, sulfated 






and sulfonated --Continued 






»Dicarboxylic acid amides, sulfated and sulfonated — Con. 






N-( 2 -[^droxyethyl)-N-( tallow alkyl)sulfosucoinamide 


SCP. 




N-Octadecylsulfosuccinamlde, disodium salt 


ACY. 




N-( Oleoyloxyisopropyl )sulfosucoinamide 


WTC. 




Fatty acid - alkanolamine condensates, sulfated: 






^Coconut oil acids - ethanolamine condensate, sulfated. 


DEX, MK, 


HRT, ONX. 


potassium salt. 






Coconut oil acids - ethanolamine condensate, sulfated. 


AML, DEP. 




sodium salt. 






Laurie acid - isopropanolamine condensate, sulfated 


PCS. 




Neat's-foot oil acids - ethanolamine condensate. 


APX. 




sulfated, ammonium salt. 






Oleic acid - ethanolamine condensate, sulfated 


SCP. 




Stearic acid - diethanolamine condensate, methyl 


DUP. 




sulfate. 






Stearic acid - ethanolamine condensate, sulfated 


NOP. 




All other- 


IMR. 




Heterocyclic amides, amines, and quaternary ammonium 






salts, sulfated and sulfonated: 






l-Ethyl-2-(8-heptadecenyl )-l-(2-hydroxyethyl )-2- 


APD. 




imidazolinium ethyl sulfate. 






N-Ethyl-N-hexadecylmorpholinium ethyl sulfate 


APD. 




N-Ethyl-N-octadecylmorpholinium ethyl sulfate 


APD. 




N-Ethyl-N-(soybean oil allsyl )morpholinium ethyl 


APD. 




sulfate. 






Taurine derivatives : 








G. 










G. 








*N-Methyl -N-oleovltaurine -- - - - 


CRC, DEP, 
G. 


DRW, G, HRT, MRA, NOP, PCI, VAL. 


N-Methvl-N-palmitovl taurine 






N-Methyl-N-(tall oil acyl )taurine, sodium salt 


G. 






G. 








N-Methyl-N-( tallow acyl)taurine, sodium salt 


LEV. 




Other amides, amines, and quaternary ammonium salts. 






sulfated and sulfonated: 






Bis(hydrogenated tallow allsyl )dimethylammonium methyl 


X. 




sulfate. 






Dimethyldioctadecylammonium ethyl sulfate 


RPC. 




Dimethyldioctadecylammonium methyl sulfate 


ONX. 




Ethyldimethyl(mixed alkyl jammonium ethyl sulfate 


X. 




N-(2-Hydroxyethyl )-N, N ',N '-tris(2-hydroxypropyl )- 


DUP. 




ethylenediamine, distearate methyl sulfate. 






( Lauramidopropyl )trimethylammonium methyl sulfate 


ACY. 




Laurie acid, 2-sulfoacetamidoethyl ester, potassium 


WTC. 




salt. 






N-(Mlxed allsyl sulfonyl)glycine, sodium salt 


G. 




Mixed primary amines, ethoxylated and sulfated 


RH, TRC. 




Stearic acid - ethylenediamine condensate, mono- 


WTC. 




ethoxylated, ethyl sulfate. 






Tall oil acids - polyalkylenepolyamine condensate. 


VIS. 




sulfated. 






N, N, N ', N ' -Tet raid, s ( 2 -hydroxypropyl ) ethylenediamine 


DUP. 




dioleate methyl sulfate. 






All other 


S. 





168 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 19B. --Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer, 7 56.?- -Continued 



Manufacturers ' idenxif ication codes 
(according to list in table 22) 



NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 

Sulfated and 5u//ona(ed--Continued 

Carboxylic acid esters, sulfated and sulfonated: 
*Dioarboxylic acid esters, sulfated and sulfonated: 

»Sulfosuccinic acid, bis(2-ethylhexyl) ester 

Sulfosuccinic acid, bis(tallow monoglyceride) ester--- 

Sulfosuocinio acid, didecyl ester, sodium salt 

Sulfosuccinic acid, dihexyl ester 

Sulfosuccinic acid, dioctyl ester, sodium salt 

Sulfosuccinic acid, dipentyl ester, sodium salt 

Sulfosuccinic acid, ditridecyl ester, sodium salt 

All other 

Esters of sulfated and sulfonated alcohols: 

Coconut oil isethionate 

Coconut oil isethionate, sodium salt 

Glycerol mono(coconut oil) ester, sulfated, ammonium 

salt. 
Glycerol mono(coconut oil) ester, sulfated, sodium 
salt. 

2-Lauroyloxy-l-propanesulfonic acid 

Esters of sulfated and sulfonated fatty acids: 

2-Butoxyethyl sulfo-oleate 

»n-Butyl sulfo-oleate 

n- Butyl sulforicinoleate 

Dodecyl sulf oacetate 

Ethyl sulfo-oleate 

Glycerol monostearate sulfoacetate 

Glycerol tri(sulfo-oleate) 

»Isopropyl sulfo-oleate 

Methyl sulfo-oleate 

»n-Propyl sulfo-oleate 

All other 

Ethers, sulfated and sulfonated: 

n-Dodecyl alcohol, ethoxylated and sulfated, ammonium 

salt. 
n-Dodecyl alcohol, ethoxylated and sulfated, sodium 

salt. 
n-Dodecyl alcohol, ethoxylated and sulfated, tri- 
ethanolamine salt. 

2-Hexyloxyethyl sulfate, sodium salt 

Hexyloxypropyl sulfate, sodium salt 

Sperm oil alcohol, ethoxylated and sulfated 

Tridecyl alcohol, ethoxylated and sulfated, ammonium 
salt. 
»Tridecyl alcohol, ethoxylated and sulfated, sodium salt 

All other 

»Fats, oils, and waxes, sulfated and sulfonated : 
»Aiiimal (including fish and marine animal) fats and 
oils, sulfated and sulfonated: 
»Cod oil, sulfonated 

*Grease, other than wool, sulfonated 

Herring oil, sulfonated 

Lard, sulfonated 

Mixed fish oils, sulfonated 

»Neat's-foot oil, sulfonated 

Red fish oil, sulfonated 



ACY, CIN, CRC, CST, DAN, EFH, EMK, GGY, HRT, ICI, MOA, 

MRA, PC, TXZ. 
ACY. 
WTC. 

ACY, MOA. 
RH. 
ACY. 
ACY, WTC. 



DRW. 
G, LEV. 
CP. 



AML, 


CIN, 


ICI, 


ONX, 


PC. 






NOP. 














NAC. 














G, KAL, NOP. 










WTC. 














DRW, 


MRV, 


SCP. 










BRY, 


DEX, 


MR, 


ICI, 


LEA, 


LUR, 


OCP 


ICI, 


NOP. 












ACY, 


BSC, 


EFH, 


HRT, 


MRV, 


NOP, 


WM. 


EMR. 














AAC. 














AAC, 


PCS, 


RET. 










PG. 














SEY. 














X. 














DUP. 














PCS, 


VIS. 












AAC, 


ARL, 


RCD, 


SEY. 








APX, 


PG. 













ACT, BAO, DRW, LEA, MRD, NOP, OTT, S, SEA, WAW, WHI, 

WHW. 
NOP, SEA, WHI, WHW. 
NOP. 

EFH, WAW. 
AML, SCO. 
ACT, APX, BAO, KAL, LEA, LUR, MRD, NOP, OTT, PC, SEA, 

SEY, WHW. 
WHI. 



SURFACE-ACTIVE AGENTS 

TABLE 19B. -Surface -active agents for which U.S. production or sales were reported, identified by 
manufacturer, i563— Continued 



169 



Manufacturers ' identification codes 
(according to list in table 22) 



NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 

Sulfated and Sulfonated-Continued 

»Fats, oils, and waxes, sulfated and sulfonated — Con. 
KAnimal (including fish and marine animal) fats and 
oils, sulfated and sulfonated — Continued 
«Sperm oil, sulfonated 

*Tallow, sulfonated 

Whale oil, sulfonated 

xVegetable oils, sulfated and sulfonated: 

Oastor oil, sulfonated 

Ooconut oil, sulfonated 

Cottonseed oil, sulfonated 

Linseed oil, sulfonated 

Mixed vegetable oils, sulfonated 

Mustard seed oil, sulfonated 

*Peanut oil, sulfonated 

Rapeseed oil, sulfonated 

*Klce-bran oil, sulfonated 

♦Soybean oil, sulfonated 

Other fats, oils, and waxes, sulfated and sulfonated 

Oleostearin, sulfonated 

Tall oil, sulfonated 

Other nonbenzenoid surface-active agents, sulfated and 
sulfonated: Mixed alkanesulfonic acids, sodium salt- 



ACT, BAO, CLD, DRW, HRI, KAL, KNG, LEA, MRD, NOP, ONX, 

OTT, QCP, RIC, S, SEA, SWT, WHI, WHW. 
ACT, ACY, BCC, BRY, BSW, DRW, EFH, FRR, ICI, LEA, LUR, 

MRA, MRD, NOP, ONX, OTT, PC, PCI, SCP, SEY, SID, SOS, 

SNW, WHI, WHW. 
KNG. 

AAE, ACT, ACY, AML, APX, BAO, BRY, BSC, BSW, CLD, DEX, 
DRW, DUP, G, HRT, ICI, KAL, KNG, LEA, LUR, MRA, MRD, 
MRV, NOP, ONX, OTT, PC, PCI, S, SCO, SCP, SEA, SLC, SWT, 
WHI, WHW. 

ACY, BAO, MRD, NOP, RTC, SEA, WHW. 

NOP, RTC. 

LEA. 

LEA. 

LUR, NOP. 

ACY, ICI, LEA, LUR, NOP, SCP, SEY, SLC, SOS. 

LEA. 

EFH, HRI, KNG, LUR, NOP, OTT, QCP. 

APX, DRW, HRT, KAL, LEA, MRD, ONX, SWT. 

SEA. 

ACY, APX, BAO, ICI, QCP, SEA, WHW. 

DUP. 



749-026 O - 64 - 12 



170 



SYNTHETIC ORGANIC CHEMICALS, 1963 



Pesticides and Other Organic Agricultural Chemicals 



TABLE 20B. 



-Pesticides and other organic agricultural chemicals for which U.S. production or sales were 
reported, identified by manufacturer, 1963 



[Pesticides and other organic agricultural chemicals for which separate statistics are given in table 20A are marked 
below with an asterisk (*); products not so marked do not appear in table 20A because the reported data are ac- 
cepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from 
table 22. An X signifies that the manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 22) 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHE^aCALS, CYCLIC 

•Fungicides: 

2,6-Bis(dijnethylamlnomethyl)cyclohexanone 

5-Chloro-2-mercaptobenzothiazole, laurylpyridlum salt 

2,4-Dichloro-6-o-chloroanilino-s-trlazlne 

2,3-Dlchloro-l,"i-naphthoqulnone (Dichlone) 

Diphenylammonium propionate 

2-Heptadecyl-2-iinidazoline acetate (Glyodin) 

2-Mercaptobenzothlazole, monoethanolamlne salt 

«iAjrcury fungicides: 

2-Chloro-4-{ hydro xymercuri)phenol 

N-( EthylJiiercuri)-p-toluenesulfonanllide 

1,4,5,6,7, 7-Hexachloro- N- ( ethylmercuri ) -5-norbomene- 
2,3-dicarboximlde. 

4-(lfydroxymercurl)-2-nitrophenol 

8-(Xfethylmercurioxy)qulnollne 

2-( Ehenylmercuriamlno)ethyl acetate 

Phenylmercuriammonium acetate 

N-Rienylmercuriformamide 

Phenylmercury hydroxide 

Phenyljnercury lactate 

Phenylmercury oleate 

Phenyljnercury propionate 

Tris(2-hydroxyethyl)(phenylJiiercuri) ammonium lactate 

All other 

2-(l-Methylheptyl)-4,6-dinltrophenyl crotonate 

»Naphthenic acid, copper salt 

Pentachloronitrobenzene 

»Pentachlorophenol (PCP) 

Pentachlorophenol, sodium salt 

•6-Qulnolinol (S-Hydroxyqulnollne), copper salt 

Tetrachloro-p-benzoqxiinone (Chloranil) 

2,3,4,6-Tetrachlorophenol 

2,3,4,6-Tetrachlorophenol, sodium salt 

Tetrahydro-3,5-dimethyl-2H,l,3,5-thiadiazine-2-thione 

N- ( Trichloromethylthio) -4-cyclohexene-l, 2-dicarboximide 
(Captan). 

N-(Trlchloromethylthio)phthfllimlde (Folpet) 

«2,4,5-Trichlorophenol 

»2,4,5-Trichlorophenol, ethanolamine salt 

»2,4,5-Trlchlorophenol, sodium salt 

2,4,6-Trichlorophenol 

•Herbicides and plant hormones : 

5-Bromo-3-sec-butyl-6-methyluracll 

5-Bromo-3-lsopropyl-6-methyluracll 

l-Butyl-3-(3,4-dichlorophenyl)-l-methylurea (Neburon) 

2-sec-Butyl-4,6-dinitrophenol (DNBP) 

2-sec-Butyl-4,6-dinitrophenol, ammonium salt 

2-sec-Butyl-4,6-dinitrophenol, trlethanolamine salt 

2-Chloro-4,6-bls(ethylamlno)-s-triazine (Simflzine) 

4-Chloro-2-butynyl m-chlorocarbanilate (Barban) 

2-Chloro-4-ethylamino-6-isopropylamlno-s-triazine 
( Atrazlne ) . 



MIL. 
VNC. 
CHG. 
USE. 
MIL. 
UCC. 

rac. 

DUP. 
DUP. 
RBC. 

DUP. 

MIL. 

CLY. 

GUA, 

VIN. 

WRC. 

WRC. 

CLY, 

MIL. 

CLY. 

SCI. 

RH. 

CCA, 

MON, 

EXT, 

DOW, 

GAM, 

USR. 

DOW. 

DOW. 

CLY, 

CHO, 



SCI, TRO. 



HNX, MIL, TRO, WRC. 



FER, HNX, HSH, MID, SM, SOC, SRR, TGL, TRO, WTC. 

OMC. 

DOW, FRO, MON, RCI. 

MON, RCI. 

HNX, MTL. 



SF. 
MIL. 



CHO. 

DA, DOW, HK. 

G. 

DOW, MON. 

DOW. 

DUP. 

DUP. 

DUP. 

CIS, DOW, FWN, TNA. 

CIS, DOW, FMN. 

CIS, DOW, FMN. 

GGY. 

SPN. 

GGY. 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS 



171 



TABLE 20B. — Pesticides and other organic agricultural chemicals for which U.S. production or sales mere 
reported, identified hy manufacturer , 1963 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



PESTICIDES ADD OTHER ORGANIC AGRICULTURAL 
CHEMICALS, CYCLIC— Continued 

»Herbicides and plant hormones--Continued 

3'-Chloro-2-methyl-p-valerotoluidide 

3-(p-Chlorophenyl)-l,l-dimethylurea (hfonuron) 

3-(p-Chlorophenyl)-l,l-dlinethylurea triohloroacetate 

2,5-Diohloro-3-aniinobenzoic aoid, ammonium salt 

3,6-Dichloro-2-anisic acid 

3' ,A'-Dichloro-2-methylacrylanilide (Dicryl) 

2-(2,"i-Dichlorophenoxy)ethanol sulfate, sodium salt 

3-(3,'4-Dichlorophenyl)-l,l-dimethylurea (Diuron) 

3-(3,'4-Dichlorophenyl)-l-methoxy-l-methylurea (linuron)- 

2,4-Dichlorophenyl-4--nitrophenyl ether 

3,'i-Dichloropropionanilide 

l,2-Dihydro-3,6-pyridazinedione (Maleic hydrazide) 

N,N-Dimethyl-2,2-diphenylacetamide (Diphenamide) 

l,l-Diiiiethyl-3-phenylurea (Fenuron) 

1, l-Dimethyl-3-phenyluTea trichloroacetate 

Dimethyl tetrachloroterephthalate 

Aje-Dinitro-o-cresol (DNOC) 

A,6-Dinitro-o-cresoI, sodium salt 

Diphenylacetonitrile 

N,N-Dipropyl-2,6-dinitro-4-trifluoromethyl aniline 

Gibberellic acid 

3-(Hexaliydro-'4,7-methanoindan-5-yl)-l,l-dimethylurea 
(Norea) . 

Indolebutyric acid 

Isopropyl carbanilate (Isopropyl N-phenylcarbamate)(IPC) 
Isopropyl 3-chlorooarbanilate (Isopropyl N-(3-ohloro- 

phenyl) carbamate) (CIPC). 
1-Naphthaleneacetic acid and derivatives: 

1-NaphthaIeneacetamide 

1-Naphthaleneacetic acid 

1-Naphthaleneacetic acid, methyl ester 

1-Naphthaleneacetic acid, sodium salt 

2-Naphthyloxyacetic acid 

2-Naphthyloxyacetic acid, sodium salt 

N-1-Naphthylphthalamlc acid (NPA) 

7-Oxabicyclo[2.2.l]heptane-2,3-dloarboxylic acid, 

disodiujn salt (Endothal). 
Phenoxyacetic acid derivatives : 

('i-Chloro-o-tolyloxy)acetic acid (MCPA) 

('*-Chloro-o-tolyloxy)acetio acid, potassium salt 

»(2,'4-Dichlorophenoxy)acetic acid (2,4-D) 

»(2,'>-Diohlorophenoxy)acetic acid esters and salts: 

(2,'4-Dichlorophenoxy)acetic acid, 2-butoxyethyl ester 
(2,'i-Diohlorophenoxy)acetic acid, butoxypolypropyl- 
eneglycol ester. 

»(2,4--Dichlorophenoxy)acetio acid, n-butyl ester 

(2,4-Diohlorophenoxy)aoetic acid, sec-butyl ester 

*(2,A-Dichlorophenoxy)acetic acid, dimethylamine salt 
( 2, i-Dichlorophenoxy) acetic acid, ethanolamine and 
isopropanolamine salt. 

»(2,'4-Dichlorophenoxy)acetio acid, ethyl ester 

(2,A-Dichlorophenoxy)acetic acid, 2-ethylhexyl ester 

*(2,'4-Dichlorophenoxy)acetic acid, iso-ootyl ester 

*(2,4-Dichlorophenoxy)acetic acid, isopropyl ester 

(2,4-Dichlorophenoxy)acetic acid, lithium salt 

(2,'i-Dichlorophenoxy)acetic acid, sodium salt 



FMN. 

DUP. 

ACG. 

G. 

VEL. 

FMN. 

G. 

DUP. 

DUP. 

X. 

MON, X. 

ACY, USR. 

LIL. 

DUP. 

ACG. 

DA. 

FMN. 

CIS, FMN. 

LIL. 

X. 

ABB, MRK. 
HPC. 

ARA. 

FMP, PPG. 
PPG. 



AMC. 

AMC, COK. 
AMC, COK. 
AMC, BKL. 
BKL. 
BKL. 
USR. 
PAS. 



CMC, DOW. 

GTH. 

CHC, DA, DOW, HPC, MON. 

AMC. 
DOW. 

AMC, DA, DOW, HPC, IMR, MON, RIV. 

CHC, MON. 

ALC, AMC, CHC, DA, DOW, HPC, RIV, TMH. 

CHC, DOW. 

AMC, DOW, MON. 

DA, HPC. 

CHC, DOW, MON, RIV. 

AMC, CHC, DA, DOW, HFC, MON, RIV. 

GTH. 

DOW. 



172 



SYNTHETIC ORGANIC CHEMICALS 1963 



TABLE 20B. — Pesticides and other organic agricultural chemicals for which U.S. production or sales were 
reported, identified by manufacturer, 1963 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICALS, CYCLIC— Continued 

•Herbicides and plant hormones — Continued 
Phenoxyacetic acid derivatives — Continued 

»(2,'i,5-Triohlorophenoxy)acetic acid (2,4,5-1) 

*(2,<i,5-Trichlorophenoxy)acetio acid esters and salts: 

(2,'4,5-Trichlorophenoxy)acetic acid, amyl ester 

(2,'i,5-Trichlorophenoxy)acetic acid, 2-butoxyethyl 

ester. 
(2,4,5-Triohlorophenoxy)aoetio acid, butoxypoly- 
propyleneglycol ester. 
*(2,4-,5-Trichlorophenoxy)acetio acid, n-butyl ester — 
(2,'i,5-Trichlorophenoxy)acetic acid, sec-butyl ester 
(2,4,5-Trichlorophenoxy)aoetio acid, 2-ethylhexyl 
ester. 
»(2,'i, 5-Trichlorophenoxy)acetio acid, iso-octyl ester 
(2,'4,5-Trichlorophenoxy)acetic acid, isopropyl ester 
(2,4,5-Triohlorophenoxy)aoetic acid, trlethylamine 
salt. 

»Ehenylmercury acetate (PMA) 

Polychloro-tetrahydro-methanoindene ( Polychlorodicyclo- 
pentadiene ) isomers . 

N-Tolylphthalamic acid 

Tributyl(2,4-dlchlorobenzyl)phosphoniujn chloride 

2-(2,'*,5-Trichlorophenoxy)propionic acid (Silvex) 

2-(2,'t,5-Trichlorophenoxy)propionic acid, 2-ethylhe3cyl 
ester. 

Tris[2-(2,<i-dichlorophenoxy)ethyl] phosphite (2,'i-DEP) 

Insect attractants: tert-Butyl 4-(and 5)-chloro-2-methyl- 
cyclohexanecarboxylate . 
•Insecticides: 

Allethrin (Allyl homolog of Cinerin I) 

Benzyl thiocyanate 

•Chlorinated insecticides : 
•Aldrin-toxaphene group: 

Heptachloro-tetrahydro-methanoindene (Heptachlor) 

Hexachloro-epoxy-ootahydro-endo, endo-dimethano- 

naphthalene (Endrin). 
Hexachloro-epoxy-octahydro-endo, exo-dimethano- 

naphthalene (Dieldrin). 
Hexaohloro-hexahydro-endo, exo-dimethanonaphthalene 
(Aldrin). 

Octahydro-tetrahydro-methanoindan (Chlordan) 

Toxaphene (Chlorinated camphene) 

l,l-Bis(p-ohlorophenyl)-2-nltrobutane 

l,l-Bis(p-chlorophenyl)-2-nltropropane 

2-(p-tert-Butylphenoxy)-l-methylethyl 2-ohloroethyl 
sulfite . 

p-Chlorophenyl p-chlorobenzenesulfonate (Ovex) 

p-Chlorophenyl 2,'i,5-trichlorophenyl sulfone 

4,4' -Dichlorobenzilic acid 

l,l-Dichloro-2,2-bis(p-chlorophenyl)ethane (DDD) (TDE) 

l,l-Dichloro-2,2-bis(p-ethylphenyl) ethane 

4,4'-Dichloro-a-(trichloromethyl)benzhydrol 

•Hexachlorocyclohexane (Benzene hexachloride) 

•Hexaohlorooyclohexane, lOO^i Y-isomer (lindane) 

Hexachloro-hexahydro-methano-benzodioxathiepinoxide 
(Qidosulfan). 



DA, DOW, 


HPC, 


MON. 


HPC. 






AMC. 






DOW. 






DA, DOW, 


HPC, 


MON, RIV 


MON. 






DA, HPC. 






DOW, MON, 


RIV 


TMH. 


DA, MON. 






DOW, HPC, 


RIV, 


TMH. 


BKM, CLY, 


GUA 


MIL, SC] 


VEL. 






USR. 






DOW, HPC. 






HPC. 






USR. 






TBK. 







VEL. 
SHC, VEL. 



VEL. 
HPC. 
COM. 
COM. 
USR. 

CIS, DA, DOW. 

FMN. 

GGY. 

ACQ, PIC, RH. 

RH. 

RH. 

DA, FRO, HK, PPG, SF. 

HK. 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS 



173 



TABLE 20B.- 



-Pesticides and other organic agricultural chemicals for which U.S. production or sales were 
reported, identified by manufacturer, 1963 — Continued 



Manxifactuxers ' identification codes 
(according to list in table 22) 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICALS, CYCLIC— Continued 

♦Insecticides — Continued 

■"Chlorinated insecticides — Continued 

■»l,l,l-Trichloro-2,2-bis(p-ohlorophenyl) ethane (DOT) 

l,l,l-Trichloro-2,2-bis(p-methoxyphenyl) ethane 
(Methoxychlor) . 

N, N-Diethyltoluamide 

Isobomyl thiooyanatoacetate 

1-Naphthyl methylcarbamate 

Organophosphorus insecticides : 

'i-tert-Butyl-2-chlorophenyl methyl methylphosphor- 

amidate. 
2-Chloro-l-(2,'4-dlohlorophenyl)vinyl diethyl phosphate 
0-(3-Chloro-<i-methyl-2-oxo-2H-l-benzopyran-7-yl) 0,0- 

diethyl phosphorothioate . 
S-(p-Chlorophenylthio)methyl 0,0-diethyl phosphoro- 

dithioate (Carbophenothion). 
S-(p-Chlorophenylthio)iiiethyl 0,0-dimethyl phosphoro- 

dithioate . 
0,0-Diethyl 0-(2-isopropyl-4-methyl-6-pyriniidinyl) 
phosphorothioate (Diazinon). 
■i<0,0-Diethyl O-(p-nitrophenyl) phosphorothioate 
(Parathion) . 
0,0-Dijnethyl 0-['i-(methylthio)-m-tolyl] phosphoro- 
thioate . 
O,0-Dimethyl O-(p-nitrophenyl) phosphorothioate 

(Methyl parathion). 
0,0-DlmetI^l S-(4-oxo-l,2,3-benzotriazin-3('iH)- 

ylmethyl) phosphorodithloate . 
0,0-Diiiiethyl 0-(2,'4,5-trichlorophenyl) phosphoro- 
thioate ( Ronne 1 ) . 

p-Dioxane-2,3-diyl ethyl phosphorodithloate 

0-Ethyl O-(p-nitrophenyl) phenylphosphonothioate 

a-Methylbenzyl 3-hydroxycrotonate, dimethyl phos- 
phate ester. 
Nematocides: 0-2,4-Diohlorophenyl 0,0-diethyl phosphoro- 
thioate. 
»Rodenticldes : 

3-(Aoetonylbenzyl)-4-hydroxyooumarin 

2-Pivaloyl-l,3-indandione 

PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEKaCALS, ACYCLIC 

♦Fungicides: 

Bis-l,<*-bromoacetoxy-2-butene 

Bis(triohloromethyl)sulfone 

Cadmium succinate 

3,3-Diacetoxypropene-l 

Disodium eyanodithioi mi doearbonate 

Dithioearbamic acid fungicides: 

♦Dimethyldithiocarbamic acid, ferric salt (Ferbam) 

Dimethyldithiocarbamic acid, manganese salt 

Ethylene bis (dithioearbamic acid), diammonlum salt 

♦Ethylene bis (dithioearbamic acid), disodium salt 
(Nabam). 



DA, GGY, LEB, MTO, OMC, RBC. 



AGO, 
DUP. 

HPC. 
CIS, 
UCC. 



SHC. 
CHG. 

SF. 

SF. 

GGY. 

ACY, AMP, MON, SF. 

CHG. 

AMP, MON, SF, SHC. 

CHG. 

DOW. 

HPC. 

X. 

SHC. 
VC. 



ABB, PEN. 
MOT, PIC. 



VIN. 

SF. 

MAL. 

SHC. 

BKM. 



DUP, FMN, RBC, WRC. 

FIJN. 

CIS, RBC. 

ALC, CIS, DUP, FMN, RBC, RH. 



174 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 20B. --Pesticides and other organic agricultural chemicals for which U.S. production or sales were 
reported, identified by manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



PESTICIDES AND OTHER ORGANIC AGRICULTLIRAL 
CHEMICALS, ACYCLIC— Continued 

»Fungicides — Continued 

Dithlooarbamic acid fungicides — Continued 

Ethylene bis(dithiocarbamic acid), manganese salt 
( Maneb ) . 
♦Ethylene bis{dithiocarbaniic acid), zinc salt (Zineb) — 

Dodecylguanidine acetate (Dodine) 

Mercury fungicides : 

Chloromethoxypropylmeroury acetate 

3-Ethyl-(mercurithio)-l,2-propanediol 

Ethylmercury acetate 

Ethylmercury chloride 

BthylmercuTy phosphate 

ffydroxyethylmercury acetate 

2-Methoxyethylmercury acetate 

Methoxyethylmercury chloride 

3-Methyl (mercurithio)-l,2-propanediol 

lifethylmercury acetate 

Methylmercury hydroxide 

Ifethylmercxiry nitrile 

♦Herbicides and plant hormones: 

Cacodylic acid 

2-Chloroallyl diethyldithiocarbamate (CDEC) 

N,N-Diallyl-2-chloroacetamide (CDAA) 

2,3-Dichloroallyl diisopropylthiocarbamate 

2,2-Dichloroproplonlc acid, sodium salt 

Diethyl dithiobis(thionoformate) 

S- Ethyl dlpropylthiocarbamate (EPIC) 

Hexachloroacetone 

♦Methanearsonic acid, disodium salt 

Kfethanearsonic acid, dodecyl- and ootylaramonium salts — 

Methanearsonic acid, monosodium salt 

S- Propyl butylethylthiocarbamate 

S, S, S-Tributyl phosphorotrithioate 

Tributyl phosphorotri thiol te 

Trichloroacetic acid, sodium salt (TCA) 

2,3,3-Trichloroallyl diisopropylthiocarbamate 

♦Insecticides : 

2-(2-Butoxyethoxy)ethyl thiocyanate 

Butoxypolypropylene glycol (Fly repellant) 

Metaldehyde 

♦Organophosphorus insecticides: 

Bis(dlalkoxyphosphinothioyl) disulfides 

S-[l,2-Bis(ethoxycarbonyl)ethyl] 0,0-diinethyl phos- 

phorodithioate (Malathlon). 
l,2-Dibromo-2,2-dichloroethyl dimethyl phosphate 
(Naled). 

2,2-Dichlorovinyl dimethyl phosphate (DDVP) 

0,G-Diethyl S-[2-(ethylthlo)ett^l] phosphorodithioate- 
0,0-Diethyl 0-[2-(ethylthio)ethyl] phosphorothioate--- 
0,0-methyl S-[2-(ethylthio)ethyl] phosphorothioate— - 
0,0-Diethyl S-[ (ethyl thio)methyl] phosphorodithloate-- 

0,0-Diethyl phosphoroehloridothloate 

Diethyl phosphoroohloridothionate 

0,0-Ey.ethyl phosphorodithloate, sodium salt 

Dimethyl 3-hydroxyorotonate, dimethyl phosphate ester- 
0,0-Dimethyl phosphoroehloridothloate 



CIS, DUP, RH. 

CIS, DUP, FMN, RH. 
ACY. 

TRO. 
DUP. 
DUP. 
DUP. 
DUP. 
WRC. 
WRC. 
MTL. 
DUP. 
DUP. 
MRI. 
WRC. 

ASL. 

MON. 

MON. 

MON. 

DOW. 

RBC. 

SF. 

ACG. 

ASL, CLY, VTN. 

CLY, VIN. 

ASL. 

SF. 

CHG. 

VC. 

DOW. 

MON. 



UCC. 
COM. 

FMN. 
ACY. 

SHC. 

MTR, SHC. 

CHG. 

CHG. 

CHG. 

ACY. 

MON. 

SF. 

MON. 

SHC. 

MON. 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS 



175 



TABLE 20B. — Pesticides and other organic agricultural chemicals for which U.S. production or sales were 
reported, identified by manufacturer, 1963 — Continued 



Manufacturers identification codes 
(according to list in table 22) 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEKQCALS, ACYCLIC— Continued 

•Insecticides — Continued 

Organophosphorus insecticides — Continued 

Dimethyl phosphorochloridothionate 

Ethyl methylene phosphorodithioate (Bthion) 

»Ethyl pyrophosphate (Tetraethyl pyrophosphate) (TEPP)- 
S-2-(Ethylsulfinyl)ethyl 0,0-diinethyl phosphoro- 
dithioate. 

Methyl 3-hydroj(ycrotonate, dimethyl phosphate ester 

2-Thiocyanatoethyl laurate 

»RodentioideE : Sodium fluoroacetate 

■»Soil conditioners: Polyacrylonitrile, hydrolyzed, sodium 

salt. 
«Soil fumigants : 

•Bi-omome thane (Jfethyl bromide) 

Chloropicrin ( Trichloronitromethane ) 

»l,2-Dibromo-3-ohloropropane 

1,3-Dichloropropene 

1,3-Dichloropropene, 1,2-dichloropropane 

N-Methyldithiocarbamic acid, sodium salt 



FMN. 










ALC, 


AMP, 


OTH, 


TGL. 




CHG. 










SHC. 










RBC. 










ACY. 










AMP, 


DOW, 


GTL, 


KLK, 


MCH 


DOW, 


IMC. 








AMP, 


DOW, 


SHC. 






DOW. 










DOW, 


SHC. 








DUP, 


SF, 


X. 







176 



SYNTHETIC ORGANIC CHEMICALS, 1963 
Miscellaneous Synthetic Organic Chemicals 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer , 1963 

[Miscellaneous chemicals for which separate statistics are given in table 21A are marked with an asterisk (*); 
chemicals not so marked do not appear in table 21A because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHUJICAI^, CYCLIC 

6-Aoetoxy-2,<i-dimethyl-m-dioxane 

Adenine and sulfate 

Adenosine derivatives 

AUcylpiperazine quaternary ammonium compounds 

2-Amlnobenzothlazole 

l-(2-Aminoethyl)piperazine 

Aminopropylmorpholine 

Ary Idiamlnes , mixed 

Barium octylphenate 

Benzoic acid salts: 

Ammonium benzoate 

Barium benzoate 

Cadmimn benzoate 

Calcium benzoate 

Ferric benzoate 

»Sodium benzoate, tech 

»Sodium benzoate, U.S.P 

Zinc benzoate 

p-Benzoquinone (p-Quinone) 

Benzothlazole 

♦Benzoyl peroxide 

Benzoylresorcinol 

Bibenzyl (Dibenzyl) 

Biological stains 

Bis(2,"i-dichlorobenzoyl) peroxide 

Bis[l-(2-methyl)aziridinyl] phenyl phosphine oxide 

1,'4-Bis[ 2- ('i-methyl-S-phenyloxazolyl)] benzene 

l,'i-BiE[2-(5-phenyloxazolyl)] benzene 

Boron fluoride -phenol coTDplex 

a-[2-(2-Butoxyethoxy)ethoxy]-"l,5-methylenedioxy-2-propyl- 
toluene (Piperonyl butoxide) . 

Butyl benzoate 

p-tert-Butylbenzoic acid, barium bis-salt 

2 (and 3)-tert-Butyl-"i-methoxyphenol 

p-tert-Butyl-a-methylcinnamaldehyde 

tert-Butyl peroxybenzoate 

■i-tert-Butylpyrocatechol 

Camphene 

Centralite-l (N,N'-Dlethyl-N,N'-dlphenylurea) 

Chemical indicators 

Chemical reagents 

Chloramine B (Sodium derivative of N-chlorobenzenesulfon- 
amide) . 

Chlorinated terphenyls 

o-Chlorobenzylidenemalononitrlle 

Chlorocyclohexane 

Chlorophyllin, sodium-potassium-copper 

Copper phthalocyaninedisulfonic acid 

Cumene hydroperoxide 

Cyanuric acid, sodium salt 

tCyclohexanone peroxide 



GIV. 

KF. 

PBS, SBR. 

HOU. 

FMT. 

JCC. 

JCC. 

DA. 

CCA. 



GAM. 

CCW. 

CCW. 

HN. 

RBC. 

HN, 

HK, 

CCW. 

EKT, 

ACY. 

CAD, 



TNP. 

HN, MON, TNP. 



G. 

GIV. 

EKT, 

CAD, 

ICO. 

ARA. 

ARA. 

ACG. 

FMN, 

CIN, 
CCA. 
EKT, 
GIV. 
WTL. 
DOW, 
GLD, 

ore, 

EK, 

ACG, 

NES, 



NOC, OXY, RCI, SDH, UPR, WTL. 



HLC, NAC. 
OXY. 



KLK, TNP. 
UPM. 



HPC. 
PAS. 
HLC, LAM, NAC. 
EK, GFS, HLC, NAC, PIC. 



KPT. 
GAM. 
CLB. 
KCH. 
NAC. 
HPC. 
FMW. 
NOC, UPR, WTL. 



MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 



177 



TABLE 21B. 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 7963- -Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, CYCLIC— Continued 

Cyclohexene-1, 2-dicarlDoxylio acid (Tetrahydrophthalic acid) 

disubstituted, polyester salts: Barium and cadmium salts 

l,<i-Cyclohexylenedimethanol 

♦Cyclopropane 

Cytidine and derivatives 

Deoahydronaphthalene (Decalin) 

Decyl diphenyl phosphite 

Deoxyribonucleic acid 

2,5-Di-tert-ainylhydroquinone 

l,<i-DiazabicyclQ[2.2.2]octane (Triethylenediamine) 

Diazodinltrophenol 

1, 3-Dibromo-5,5-dimethylhydantoin 

4' , 5-Dibromo(and 3,4' , 5-tribromo)salicylanillde 

»2,6-Di-tert-butyl-p-cresol: 

»Food grade 

»Tech 

2,5-Di-tert-butylhydroquinone 

l,3-Dichloro-5,5-dimethylhydantoin 

Diohloro-s-triazine-2,'4,5(lH,3H,5H)trione (Dichloroiso- 

cyanuric acid) . 
Diohloro-s-triazine-2,'i,6(lH,3H,5H)trione, potassium salt- 

Dichloro-s-triazine-2,4,6(lH,3H,5H)trione, sodium salt 

Dioyclohexylammonium nitrite 

Dicyclopentadienyliron 

Didecyl phenyl phosphite 

2,2'-Dihydroxy-'4,'i'-dimethoxybenzophenone 

2,6-Dihydroxyisom.cotinic acid (2,6-Dihydroxy-<i-carboxy- 
pyridine) . 

2,2'-DihydrQxy-4-methoxybenzophenone 

2,2' -Dihydroxy-'V- ( octadeoyloxy )benzophenone 

3,5-Diiodosalicylic acid 

Diisopropylbenzene hydroperoxide, mixed isomers 

Diisopropyl-m,p-cresols 

p-Dimethoxybenzene (Dimethyl ether of hydroquinone ) 

2,5-Dimethylhexane-2,5-di(peroxybenzoate) 

'4,"i-Dinitrocarbanilide-'»,6-dimethyl-2-pyrimidinol 

Dioxane (1,4-Diethylene oxide) 

2,5-Diphenyl-p-benzoquinone 

Diphenyloxazole 

'4-Dodecyloxy-2-hydroxybenzophenone 

Enzymes: 

Hydro lytic : 

Amylases 

Proteases 

Other 

Nonhydro lytic 

1, 2-Epoxy-3-phenoxypropane (Glycidyl phenyl ether) 

6-Ethoxy-m-anol (Propenylmethylguaethol) 

Ethylenediaminebis[o-hydroxyphenylacetic acid], monosodlum 
ferric salt. 

2-Ethylhexyl octylphenyl phosphite 

2-Ethylhexyl salicylate 

2-Ethylhexyl tallate 

Ethyl hydrocaffeate 

»4-Ethylmorpholine 

Fenchone 



RCI. 

EKT. 

MAL, OH, QMS, TAE. 

PBS, SBR. 

DUP. 

HK. 

SBR. 

EKT. 

HOU. 

HPC. 

AHA. 

FIN. 

CAT, EKT, HPC, KPT, SHC. 

CAT, EKT, HPC, KPT, PIT, SHC. 

EKT. 

GLY. 

MON. 

MON. 

FMW, MON. 

QMC. 

ARA, TNA. 

HK. 

0. 

EK. 

ACY. 

ACY. 

MRT. 

HPC. 

GIV. 

ASL, EKT, ICO. 

UPR, WTL. 

MRK. 

DOW, UCC. 

EKT. 

AHA. 

EKT. 



BAX, CRN, PBS, RH. 

BAX, PBS, RH. 

RH. 

FMO, MLS. 

SHC. 

ICO. 

GGY. 

VC. 

ICO. 

UCC. 

ICO. 

BC, JCC, UCC. 

HNW. 



178 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales Mere reported, identified by 

manufacturer, 1963 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



^aSCELLA^rEOUS CHEMICAIS, cyclic --continued 

•Flotation reagents: 

Benzoylthiono-l-ethylpropyl carbamate 

Dicresylphosphorodithioic acid (Dioresylthiophosphorii 
acid ) . 

Dicresylphosphorodithioic acid, anraionium salt 

Dicresylphosphorodithioic acid, sodium salt 

2,2 '-Dimethyl thiocarbanilide (Di-o-tolylthiourea) 

Rosin amines 

•Thiocarbanilide (Diphenyl thiourea) 

Furan derivatives: 

2-Furaldehyde (Furfural) 

Tetrahydrofurfuryl alcohol 

Gallic acid, tech 

•Gasoline additives: 

N,N'-Bis(l,<i-dimethylpentyl)-p-phenylenediamlne 

p-Butylaminophenol 

N'-sec-Butyl-N-phenyl-o-phenylenediamine 

2,6-Di-tert-butylphenol 

*N,N'-Di-sec-butyl-p-phenylenediamine 

N,N '-Diisopropyl-p-phenylenediamine 

Di(nonylphenol) salt of triethylenetetramine 

»N,N'-Disalicylidene-l,2-propanediamine 

Methylcyclopentadienylmanganese trioarbonyl 

2,2'-Thiobis[6-tert-butyl-^-methylphenol] 

All other 

Glyceryl p-aminobenzoate 

Guanosine phosphates 

Hesperidin 

»Hexamethylenetetramine, tech 

o-(2-Hydroxy-p-anisoyl) benzoic acid 

2-Hydroxy-4--methoxybenzophenone 

2-Hydroxy-<l-methoxy-5-sulfobenzophenone trihydrate 

Hydroxymethyl-5,5-dimethylhydantoin 

2-Imidazolidinethione (l,3-Ethylene-2- thiourea) 

Inosine phosphates 

Isocyanuric acid 

Isopropylcresols 

p-Isopropyl-a-methylcinnamaldehyde 

Isopropyl tallate 

Laurylmorpholine 

Lemon biflavonoid 

•Lubricating oil and grease additives: 

Chlorosulfur i zed and sulfurized compounds: 

Alicyolic compounds, sulfurized 

Heterocyclic compounds, sulfurized 

Liquid disulfide 

Tall oil ester, sulfurized 

Terpenes, sulfurized 

Oil-soluble petrolexim sulfonates: 

Oil-soluble petroleum sulfonate, ammonium salt 

•Oil-soluble petroleum sulfonate, barium salt 

•Oil-soluble petroleum sulfonate, calci>jm salt 

•Oil-soluble petroleum sulfonate, sodium salt 

Phenol salts: 

Barium salt of dodecylphenol 

Barium salt of nonylphenol 

Barium salts of other alkylphenols 

Calcium salt of octylphenol-formaldehyde 



DOW. 
ACY. 

ACY. 

KCU. 

DUP, RBC. 

HPC. 

ACY, I«N, NAC. 



QKO. 
MAL. 

EKT. 

DUP. 

UPM. 

TNA. 

DUP, EKT, UPM. 

DUP, EKT. 

SPP. 

DUP, EKT, SOI, SPP, TNA, TX, UPM. 

TNA. 

CAT. 

EKT, UPM. 

VND. 

PBS, SBR. 

SKG. 

BOR, DUP, HKD, HMP, HN, PLS, UCP. 

ACY. 

ACY, G. 

ACY. 

GLY. 

PAS. 

PBS, SBR. 

MON. 

CP, GIV. 

GIV. 

DEX. 

BC. 

SKG. 



SOI. 

ORO. 

HK. 

LUB. 

LUB. 

SIN. 

ATR, CO, LUB, SIN, SON, TX. 

CO, LUB, ORO, SHO, SOI, SON, X. 

CO, ENJ, MOR, NOP, PAR, SHO, SOC, SOI, SON, 

TX. 

CCA. 

LUB, TX, X. 

SHC. 



MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 



179 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i 565 --Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, CYCLIC— Continued 

»Lubricating oil and grease additives — Continued 
Phenol salts — Continued 

Calcium salt of polypropylphenol 

Calcium salts of other alkylphenols 

All other 

Phosphorodithioates (Dithlophosphates ) 

All other 

p-Menthane 

8-p-Menthyl hydroperoxide 

4-Methoxyphenol 

N-Methylanthranilic acid 

2-Methylaziridine 

2,2'-Methylenebis [6-tert-butyl-A-methylphenol] 

2,2'-Methylenebis [^-chlorophenol] (Dichlorophene) 

<»,'i' -Methylenebis [2,6-di-tert-butylphenol] 

Methylenebis [5,5-dimethylhydantoin] 

2,2' -hfethylenebis [3,"4,6-trichlorophenol] (Hexachlorophene) 
2,2'-Methylenedi-p-cresol (Bis(5-methyl-2-hydroxyphenyl) 
methane ) . 

Ifethylenenorbornylene 

Methylglucoside 

A-Methylmorpholine 

Methylnorbornene-2,3-dicarboxylic anhydride (Methylbi- 
cyclo-(2.2.1)heptene-2,3-carboxylic anhydride) . 

Methyl phenyl phosphates 

l-Methyl-2-pyrrolidone, monomer 

Methyl tallate — - 

»Morpholine 

Morpholine salt of p-toluenesulfonic acid 

«Naphthenic acid salts: 

Aluminum naphthenate 

Barium naphthenate 

Cadmiim naphthenate 

»Calcium naphthenate 

Cobalt lead manganese naphthenate 

»Cobalt naphthenate 

•Iron naphthenate 

»Lead naphthenate 

Lithium naphthenate 

•Manganese naphthenate 

Mercury naphthenate 

Nickel naphthenate 

Rare earths naphthenate 

Sodium naphthenate 

Strontium naphthenate 

»Zinc naphthenate 

Other 

o-Nitrobenzoic acid and sodium salt 

5-Norbomene-2 -methanol (Bicyclo [2.2.1 ]hept-5-ene-2- 

methanol) and acrylate ester 

Ootafluorocyclobutane 

Octylphenyl acid phosphate 



SIN. 

LUB, ORG, SIN, TNA. 



ORG. 

LUB, 

EN J, 

ORG, 

DOW, ENJ, ICO, LUB, MON, ORG, RBC, SIN, SPP, VC, X. 

HPC. 

HNW, HPC. 

ASL, EKT, ICO. 

GIV. 

ICO. 

CAT. 

GIV. 

SHC. 

GLY. 

GIV. 

GIV. 

RBC. 
CRN. 

JCC, UCC. 
ICO. 

TNA. 

G. 

CHM. 

DOW, JCC, UCC. 

AMB. 

HSH, mc. 

CCA, QCP. 

CCA. 

CCA, FER, HNX, HSH, MLD, MR, SHP, SGC, SPP, SRR, SW, 

TRG, WIC. 
HNX, HSH. 
CCA, CCC, CS, FER, HNX, HSH, MLD, MR, SHP, SGC, SPP, 

SRR, SW, TRO, WTC. 
CCA, HNX, HSH, MLD, SGC, SRR, WIC. 
CCA, CCC, CCW, FER, HNX, HSH, MLD, MR, QCP, SHP, SGC, 

SPP, SRR, SW, TRO, WTC. 
CCA. 
CCA, CCC, FER, HNX, HSH, MLD, SHP, SOC, SPP, SRR, SW, 

TRO, WTC. 
MIL. 
CCA. 

CCA, HNX, MLD, WTC. 
CCA. 
CCA. 
CCA, CCC, FER, HNX, HSH, MLD, SHP, SOC, SRR, SW, TRG, 

WTC. 
SPP. 
WAY. 



ICG. 
DUP. 
VC. 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 21B. -- Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELIANEOUS CHEMICALS, CYCLIC— Continued 

Organic mercury compounds; 

Phenyl mercuric borate 

Pyridyl mercuric acetate 

Pentaerythrltyl tetra(diphenyl phosphite) 

o-Phenanthroline 

Phenolthlosulfonic acid 

2-Phenoxyethanol (Ethylene glycol monophenyl ether) 

2-(2-Phenoxyethoxy)ethanol (Diethylene glycol phenyl 
ether) . 

Phenyl acid phosphate 

Phenyl benzoate 

2,2'-(p-Phenylene)diethanol 

Phenylraagnesiujn bromide 

"i-Phenylmorpholine 

Photographic chemicals: 

N-(o-Aoetamidophenylmethyl)-l-hydroxy-2-naphthamide 

2-(4— Amino-N-ethyl-m-toluidino)ethyl sulfate 

4-Amino-6-methylguaiacol (S-Methyl-G-methoxy-'i-amino- 
phenol hydrochloride ) . 

3-Amino-l,2,'i-triazole (5-Amino-l,3,'i-triazole) 

»Benzotriazole 

p-Benzylaminophenol hydrochloride 

2,2',.4,4'-Bipheryltetrol 

Catechol (Pyrocatechin) 

3-Chloro-4-diethylaiiiinobenzenediazonium chloride 

(p-Diazo-2-chloro-N,N-diethylaniline) - zinc chloride, 

Chlorohydroquinone 

2,'i-Diaminophenol dihydrochloride (Amidol) 

N-(4-Diazo-2,5-dibutoxyphenyl)morpholine 

N-("4-Diazo-2,5-diethoxyphenyl)morpholine 

2,5-Diethoxy-4-morphinyldiazonium chloride - zinc 
chloride . 
*p-Diethylani1 nobenzenediazonium chloride (p-Diazo-N,N- 
diethylaniline) - zinc chloride. 
p-Diethylaminobenzenediazonium (p-Diazo-N, N-Diethyl- 
aniline) f luoroborate . 

N,N-Diethyl-p-phenylenediamine hydrochloride 

N,N-Diethyltoluene-2,5-diamine, monohydroohloride 

2,5-Dlhydroxybenzenesulfonic acid 

p-Dimethylaminobenzenediazonium chloride (p-Diazo- 

N,N-dimethylaniline) - zinc chloride. 
'i-(2' ,6' -DimethyliQorpholinyl)benzenediazonium chloride - 
zinc chloride. 

p-Dlphenylaminediazonium sulfate 

p-(N-Ethylbenzimido)benzenediazonlum chloride (p-Diazo- 

N-benzyl-N-ethylaniline) - zinc chloride, 
p- [Ethyl (2-hydroxyethyl) amino Ibenzenediazonium chloride 
(p-Diazo-N-ethyl-N-hydroxyethylaniline) - zinc chlo- 
ride. 

N-Ethyl-N-hydroxyethyl-p-phenylenedlamine sulfate 

N-Ethyl-N-(j3-methanes\ilfonamidoethyl)toluene-2,5-diaiiiine 
sulfate. 

Hydroquinone (Hydroquinol) 

p-[(2-Hydroxyethyl)methylamino]benzenedlazonlum chloride 
(p-Diazo-N-hydroxyethyl-N-methylaniline) - zinc 
chloride. 
3-Hydroxy-N- ( 2-hydroxyethyl ) -2-naphthamide (p -Oxynaph- 

thoicmonoethanolamide ) . 
N-(p-Hydroxyphenyl) glycine 



WRC. 

MAL. 

HK. 

COK. 

G. 

DOW. 

DOW. 

VC. 

CIN. 

EKI. 

ARA. 

UCC. 

EKT. 
EKT. 



FMT. 

EK, FMT, MEE, MRT. 

EK. 

FMT. 

KPT. 

FMT. 

EK. 
VPC. 

FMT, IDC. 
FWT, IDC. 



FMT, G, IDC, 



EKT, FWr, IDC. 
EKT, FMT. 



FMT, G, IDC. 
IDC. 



FMT. 
FMT, MRT. 



FMT, IDC. 



IDC. 
EKT. 



EKT. 
FMT, IDC. 



FMI. 
IDC. 



MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 



TABLE 21B. 



■Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 965- -Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



^aSCELIANEOUS CHEMICALS, CYCLIC— Continued 

Photographic chemicals — Continued 

l-(3-Hydroxyphenyl)urea 

"i-Methoxy-l-naphthol 

p-Methylaminophenol sulfate (Metol) 

5-Methylbenzotriazole 

^-Methyl-l-phenyl-3-pyrazolidinone 

2-Methylthiazoline 

5-Methyl-s-tria2olo[l,5-a]pyrimidin-7-ol (7-Hydroxy-5- 
methyl-l,3,"i-triazoindolizine) . 

4-Morpholinylhenzenediazoniuni chloride 

"i-Morpholinylbenzenediazonium fluoroborate 

6-Nitrobenziiiu.dazole ■ 

Octylphenyl salicylate 

Phenyl-5-meroaptotetrazole 

l-Phenyl-3-pyrazolidinone 

4-Phenylpyrocatechol 

<V,4' -Thiodiresorcinol (Diresorcyl sulfide) 

l-{2,'i,6-Trichlorophenyl)-3-(4-nitroanilino)-2-pyraz- 
olin-5-one . 

All other 

Phthalic acid, lead salt, dibasic 

»Pinene 

Polyethylene terephthalate 

Polyvinyl phthalate 

Propyl gallate 

Pyridylborane 

Pyrogallol (Pyrogallic acid) 

Rosin acid salts: 

Aluminuni resinate 

Calcium resinate 

Copper resinate 

Iron resinate 

Lead resinate 

Manganese resinate 

Zinc resinate 

Salicylanilide 

Salicylic acid, lead salt 

Silicones 

Sodium cresoxide (Cresylic acid, sodium salt) 

Sterols, soya, crude 

trans -St ilbene 

Sucrose benzoate 

Sulfosalicylic acid 

Tall oil fatty acid chloride 

*Tall oil salts (Linoleic-rosin acid salts): 

Barixim zinc tallate 

»Calcium tallate 

<«Cobalt tallate 

Copper tallate 

Iron tallate 

Lead manganese tallate 

"Lead tallate 

"Manganese tallate 

Zinc glyceryl tallate 

Zinc tallate 

Tannic acid 



FMT, IDC. 

X. 

EK. 

EK. 

WAY. 

FMT. 

FMT. 

FMT, IDC. 
IDC. 

EK, F^t^. 
EKT. 

Fltr, TNC. 
GGY, WAY. 

X. 

BKC. 
EKT. 

EK, EKT, FMT, G, IDC. 

NTL. 

CBY, GLD, HPC. 

DUP, EK. 

EK. 

EKT, HN. 

CAL. 

MAL. 

JMS, MAL. 
JMS, SW. 
JMS. 

HSH, JMS. 
JMS. 

jm. 

JMS, SW. 

DUP, FIN, MEE, ICIN. 

NTL. 

DCC. 

DEX, GOC. 

GNM. 

EK. 

TNP. 

MDN, MRK. 

G. 



HSH. 
CCA, 
CCA, 
MLD, 
CCA, 
HSH. 
CCA, 
CCA, 
CCA. 
CCA, 
HSH, 



HNX, MLD, TRO, WTC. 

CCC, FER, HNX, HSH, MLD, SHP, SRR, TRO, vnC. 

SHP. 

MCA, MLD, SRR, WTC. 

CCC, FER, HNX, MLD, SHP, SPP, SRR, TRO, WTC. 

CCC, PER, HNX, HSH, MLD, SHP, SRR, TRO, WTC. 



HSH. 
MAL. 



182 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 21 B. 



■ Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufacturers ' Identification codes 
(according to list in table 22) 



MISCELLANEOUS CHiMICALS, CYCLIC— Continued 

^Tanning materials, synthetic: 

Hydroxytoluenesulfonic acid, formaldehyde condensate 
(Cresol-formaldehyde sulfonate), sodium salt. 
»2-Naphthalenesulfonic acid, formaldehyde condensate and 
salts. 

l-Phenol-2-sulfonio acid, formaldehyde condensate 

Styrene maleic anhydride interpolymer, partial sodium 

salt. 
Sulfonyldiphenolsulfonic acid, formaldehyde condensate-- 

All otlier 

1,2,3,4-Tetrahydronaphthalene (T-etralin) 

Tetrahydro-2-naphthylmethylidyne-l-ootadecenylpyTimidine-- 

Tetrahydrothiophene 

Tetraphenylbutadiene 

Tetraphenyltin 

^Textile chemicals, other than surface-active agents: 
l,3-Bis(hydroxymethyl)-2-imidazolidone (Dimethylol 
ethylene urea) . 

l-[(Octadecyloxy)methyl]pyridinium chloride 

Phenol, sulfurated 

Tetrahydro-3,5-bis (methoxymethyl) -iH-l, 3, 5-oxadiazin-<i- 
one. 

2,2','4,'4'-Tetrahydroxybenzophenone 

2-Thenoyltrifluoroaoetone 

2,2 '-Thiobis[4-chlorophenol] 

2, 2' -Thiobis[<;, 6-dichlorophenol] 

[ 2, 2'-Thiobis('i-octylphenolate) ] -n-butylamine nickel 

Tocopherol, soya, crude 

o-Toluidine-formaldehyde hydrochloride 

o-Tolylbiguanide 

Tribenzylamine 

3,4',5-Tribromosalicylanilide 

3,i,4. '-Trichlorocarbanilide 

Trichloromelamine 

l,J,5-Trichloro-s-triazine-2,'i,6(lH,3H,5H)trione (Tri- 
chloroisocyanuric acid) . 

Tri-(m,p)-cresyl borate 

Triphenyl phosphite 

Triphenylphosphorus 

Tris(l-aziridinyl)phosphine oxide 

Tris [l-(2-methylaziridinyl)]phosphine oxide 

Uridine and derivatives 

Vinyl cyclohexenedioxide 

l-Vinyl-2-pyrrolidinone, monomer and polymer 

l-Vinyl-2-pyrrolidinone - styrene copolymer 

l-Vinyl-2-pyrrolidinone - vinyl acetate copolymer 

l-Vinyl-2-pyrrolidinone - ethyl acrylate, copolymer 

MISCELLANEOUS CHEMICALS, ACYCLIC 

Acetaoetamidoaoetamide 

»Acetaldehyde 

Acetamide 

Acetamidine hydrochloride 

2-Acetamidoethanol (N-Aoetylethanolamine) 

»Acetic acid, synthetic, 100^ 



G, GGY. 






GRD, NOP, 


NYC, 


RH 


NAC, NOP, 


RH. 




DUP. 






G. 






NOP. 






DUP. 






SPP. 






ORG, PAS. 






ARA. 







ACY, X. 



DUP. 



CLE. 

GIV, OPC. 

MON, SDH. 

ACY. 

(MA. 

RBC. 

MON. 

EK. 

FIN. 

MON. 

WTM. 

FMW, MON. 

USB. 
HK, MON. 

MET. 

cm. 

ICO. 

PBS, SBR. 

UCC. 

G. 

G. 

G. 



RBC. 

BFG, CEL, COM, DUP, EKT, HPC, MON, PUB, SHC, UCC. 

ACG. 

MRK. 

RBC. 

CEL, CCM, EKT, HPC, PUB, UCC. 



MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 



183 



TABLE 21B. --Miscellaneous chemicals for ivliich U.S. production or sales were reported, identified by 

manufacturer, i 963- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



KaSCELLANEOUS CHIMICALS, ACYCLIC— Continued 

*Acetio acid salts: 

Aluminum acetate 

Aluminum subacetate 

»Ammoniun acetate 

Barium acetate 

Cadmium acetate 

Calcium acetate 

Chromium acetate 

Cobalt acetate 

*Copper acetate 

Lead acetate 

Lead subacetate 

Lead tetraacetate 

Magnesium acetate 

Manganese acetate 

Mercuric acetate 

Methylmercury acetate 

Nickel acetate 

♦Potassium acetate 

Silver acetate 

*Sodlum acetate 

Sodium diacetate 

Strontium acetate 

♦Zinc acetate 

Zirconium acetate 

♦Acetic anhydride, 100^: 

From acetaldehyde 

From acetic acid, other than recovered, by the vapor- 
phase process. 
From acetic acid, recovered, by the vapor-phase procesi 

From ethylene 

Acetin: 

Mono 

Tri . 

♦Acetone: 

By fermentation 

From cumene 

♦From isopropyl alcohol 

All other 

Acetone, dimethyl aoetal (2,2-Dimethoxypropanone) 

Acetone semicarbazone 

Aoetonitrile 

Acetyl chloride 

Acetyl peroxide 

Aconitic acid 

Acrolein (Acrylaldehyde) 

♦Acrylic acid 

♦Acrylonitrile 

♦Adipic acid 

Adiponitrile 

Adipoyl chloride 

♦Alcohols, monohydric, unsubstituted: 
♦Alcohols C9 or lower: 

♦Allyl alcohol 



ACY, 
MAL. 
ACQ, 
ACG, 
ACQ, 
ACG, 
ACY. 
BKC, 
ACG, 
BKC, 
ACG, 
ARA. 
ACG, 
HSH, 
ACG, 
DUP. 
BKC, 
ACG, 
MAL. 
ACG, 
UCC. 
BKC 
ACG, 
NTL. 



UCC 

BKC, MAL, WSN. 
BKC, MAL. 
BKC. 
BKC, MAL. 

HSH, SHP. 
BKC, UCC. 
MAL, SRR, SW. 
BKC, MAL. 

BKC. 
SHP. 
BKC, MAL. 

HSH, SHP. 

BKC, CWL, MAL, UCC, WSN. 

BKC, DAN, EKT, MAL, UCC, WSN. 



BKC, HSH, MAL, SNW, UCC 



HPC. 
CEL, EKT. 



CEL. 
UCC. 



HAL, KES. 
EKT, WM. 



PUB. 

ACP, 

EKT, 

CEL, 

DOW. 

NOR. 

EKX, 

TBK. 

WTL. 

PCW. 

SHC, 

BFG, 

ACY, 

CS, 

CS, 

TBK. 



HPC, MON, SHC, SKO, SOC. 

ENJ, SHC, UCC 

HPC. 



UCC. 

CEL, DBC, MMM, RH, UCC. 

BFG, DUP, MON, SOH, UCC. 
DUP, MON, NAC, RH. 
DUP. 



DOW, CMC, SHC, UCC 



184 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 21B. 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 565 --Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHIMICALS, ACYCLIC— Continued 

♦Alcohols, monohydric, unsubstituted — Continued 
♦Alcohols C9 or lower — Continued 
Amyl alcohols: 
Unmixed: 

Isopentyl alcohol C3-Methyl-l-butanol) 

2-Methyl-2-butanol (tert-Amyl alcohol) 

1-Pentanol 

2-Pentanol 

3-Pentanol 

Mixed: 

Fusel oil, refined 

Other than fusel oil: 

Primary mixed 

Secondary mixed 

Other 

♦Butyl alcohols: 
Primary: 

ISO (Isopropylcarbinol) 

♦Normal (n-Propylcarbinol) 

Secondary (Methylethylcarbinol) 

Tertiary (Trimethylcarbinol) 

Mixed 

♦Ethyl alcohol, synthetic 

2-Ethyl-l-butanol (sec-Hexyl alcohol) 

2-Etl^l-l-hexanol 

2-Ethyl-'i-methyl-l-pentanol 

"i-Ethyl-l-octyn-a-ol 

♦Hexyl alcohol 

l-Hexyn-3-ol 

♦Iso-octyl alcohols 

♦Isopropyl alcohol 

♦Methanol, synthetic 

2-Methyl-3-buten-2-ol 

2-Methyl-3-butyn-2-ol- 

'i-Methyl-2-pentanol ( l-Methylisobutylcarbinol) -• 

3-MetlQrl-l-pentyn-3-ol (Methylparafynol) 

1-Octanol 

2-Octanol 

Octanols, mixed 

Propyl alcohol (Propanol) 

2-Propyn-l-ol 

All other 

♦Alcohols Cio and higher: 

♦Decyl alcohol 

3,9-Diethyl-6-tridecanol 

♦Dodecyl alcohol (Lauryl alcohol) 

7-Ethyl-2-methyl-'*-hendeoanol 

♦1-Hexadecanol (Cetyl alcohol) 

♦1-Octadecanol (Stearyl alcohol) 

ois-9-Ootadecen-l-ol (Oleyl alcohol) 

1-Tridecanol 

Tridecanols, mixed 

2,6,8-Triraethyl-A-nonanol 

All other • 

Aldol (Acetaldol) — 

Alkyl and alkylene hydrocarbons 

Alkyl sulfides, mixed 



FB. 








PAS. 








PAS. 








UCC. 








EK, UCC. 






PUB. 








PAS, 


UCC. 






PAS. 








PAS. 








CEL, 


DEC, EKT, EKX, ENJ, SHC, 


UCC. 




CEL, 


CO, DBC, ENJ, EKX, PUB, 


SHC, UCC. 




CEL, 


ENJ, SHC. 






SHC. 








CEL, 


EKX. 






DUP, 


EKX, ENJ, HPC, SHC, UCC, 


USI. 




UCC. 








CEL, 


EKX, ENJ, SHC, UCC 






EKX. 








AIR. 








ENJ, 


EKX, PG, UCC. 






AIR. 








EKX, 


ENJ, GOG, HOU, SOI, TID, 


UCC. 




ENJ, 


SHC, UCC. 






ACN, 


BOR, CEL, COM, DUP, ESC 


HPC, MON, RH, 


SPN, UCC 


AIR. 








AIR. 








ENJ, 


SHC, UCC. 






AIR. 








DUP. 








RH, 


WTH. 






PG. 








CEL, 


UCC. 






G. 








CEL, 


CO, EKX. 






DUP, 


ENJ, GOC, HOU, PG, TID, 


UCC. 




UCC. 








DUP, 


PG, RH. 






UCC 








AIM, 


DUP, ENJ, GIV, RH. 






AIM, 


DUP, PG, RH. 






ADM, 


DUP. 






ENJ 


GOC. 






UCC 








UCC 








ADM, 


CO, NEP, PG, RH, UCC. 






UCC 








ADM 


AIR, HMY. 






ORO 









MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 



185 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



Manuf aot'orers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEIfflCALS, ACYCLIC— Continued 

l-Allyl-3-(2-hydroxyethyl) -2 -thiourea (N-fi-ffydroxyethyl- 
N'-allylthiourea) . 

Allyl isothiocyanate, nonflavoring grade 

Allyl methacrylate 

Allyl nitrile (Allyl cyanide) 

l-(Allyloxy)-2,3-epoxypropane (Allyl glycidyl ether) 

3-(Allyloxy)-l,2-propanediol (Allyl glyceryl ether) 

Aluminum isopropoxide (Aluminum isopropylate) 

Amidinourea (Guanylurea) phosphate and sulfate 

•Amines: 

Butylamine 

tert-Butylamine 

Cetyl diraethylamne 

*Cooonut oil amine 

Coootrimethylenedi amine 

Cottonseed oil amines 

Diallylamine 

Dibutylamine 

»Diethylamine 

Diethylamine hydrochloride 

Diethylenetri amine 

N, N-Diethylethylenediamine- 

N , N-'--Diethyl-l,'i-pentanediamine ( Novoldiamine ) 

N, N-Diethyl-l,3-propanediamine 

Diisobutylamine 

Diisopropylamine 

»Dimethylamine 

Dimethylamine hydrochloride 

Dimethylamine sulfate 

Dime thy Imyrystylamine 

N,N-Dimethyloctadeoylamine (Stearyldimethylamine) 

N,N-Dimethyl-l,3-propanedi amine 

Dipentylamine (Dlamylamine) 

Dipropylamine 

Dipropylenetri amine 

«Dodecylamine 

Ethylamine 

Ethylenedi amine 

Ethylenediamine dihydrochloride 

Ethylenediamine sulfate 

Hexadecylamine 

1,6-Hexanediamine (Hexamethylenediamine) 

3,3'-Iminobispropylamine 

Isobutylamine 

Isopropylamine 

Lauryl dimethylamine 

•Methylamine 

»Octadecylamine 

Octylamine 

»01eylamine 

Primary amines, mixed 

1,2-Propanedi amine (Propylenedi amine) 

1,3-Propanediamine 

Propylamine 

Soybean oil amine 

•Tallow amine 

•Tallow amine, dihydrogenated 

•Tallow amine, hydrogenated 



FMT, 


IDC. 






ICO. 








SAR. 








RBC. 








DOW, 


SHC. 






SHC. 








SFA. 








ACT. 








EKT, 


PAS, 


UCC. 




MON, 


RH. 






BC. 








ADM, 


ARC, 


FOR, 


GNM. 


ARC, 


FOR. 






FOR. 








SHC. 








PAS, 


UCC. 






DUP, 


PAS, 


UCC. 




BKL, 


TNC. 






DOW, 


UCC. 






ALB, 


COK. 






SDH. 








UCC. 








PAS. 








PAS, 


UCC. 






COM, 


DUP, 


PAS, 


RH. 


EK, 


TNC. 






RH. 








BC. 








ARC. 








JCC, 


UCC. 






PAS. 








PAS, 


UCC. 






UCC. 








ADM, 


ARC, 


FOR, 


GNM. 


DUP, 


PAS, 


UCC. 




DOW, 


UCC. 






BKC. 








EK. 








ADM, 


ARC, 


GUM. 




CS, 


DUP. 






UCC. 








PAS. 








PAS, 


UCC. 






ARC, 


BC. 






COM, 


DUP, 


ESC, 


PAS, RH 


ADM, 


ARC, 


FOR, 


GNM. 


ARC, 


RH, 


UCC. 




ARC, 


FOR, 


GUM. 




RH. 








UCC. 








UCC. 








PAS, 


UCC. 






ARC. 








ADM, 


ARC, 


FOR, 


GNM. 


FOR. 








ADM, 


ARC, 


FOR, 


GNM. 



749-026 O - 64 - 13 



186 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAI^, ACYCLIC- -Continued 

*Amines — Continued 

Tallow methylamines, dihydrogenated 

Tetraethylenepentamine 

N, N,N',N' -Tetrame thy 1-1, 3-butanedi amine 

Tetramethylsthylenediamine 

Trial lylamine 

Tributylamine 

Tricapryl^flamine 

Tridodecylamine 

Triethylamine 

Triethylenetetr amine 

*Trimethylamine 

Trimethylenedi amine fatty derivatives 

Tripentylamine 

All other 

2-Amino-l-butancI 

1-Aminoethanol (Acetaldehyde ammonia) 

Aminoethoxypropylsilane 

2- ( 2-Amlnoethylamino) ethanol ( Aminoethylethanolamine ) — 

2-Amino-2-ethyl-l, 3-propanediol 

Aminoguanidine bicarbonate 

2-Amino-2-(hydroxymethyl)-l,3-propanediol (Tris(hydroxy- 
methyl)aminome thane). 

2-Amino-2-methyl-l,3-propanediol 

2-Amino-2-methyl-l-propanol 

2-Amino-2-methyl-l-propanol hydrochloride 

3-Amlno-l-propanol 

ff-A-nyl acetates, 90^: 

Amyl acetate (n-Pentyl acetate) 

Isopentyi acetate (Isoamyl acetate) 

Mixed 

Azelaic acid -- 

2,2'-A2obls[2-methylpropionitrile] (a, a'-Azodiisobu- 
tyronitrile) . 

Behenamide (Docosanamide) 

Behenic acid 

Bis(2-butoxyethyl) ether (Diethylene glycol di-n- 
butyl ether) . 

Bis(2-chloroethoxy)methane (Diohloroethylformal) 

*Bis(2-chloroethyl) ether (Dichlorodiethyl ether) 

Bis(2-chloro-l-methylethyl) ether (Diohloroisopropyl 
ether) . 

Bis(2,6-diraethyl-<i-heptyl) maleate 

Bis(2-ethoxyethyl) ether (Diethylene glycol diethyl 
ether). 

Bis(hydroxyethyl) ether butynediol 

Bis(2-hydrcxyethyl) sulfone 

l,3-BiE(hydroxymethyl)urea (Dimethylolurea) 

Bis [2-(2-methoxyethoxy) ethyl] ether ( Tetraethylene 

glycol dimethyl ether). 
Bis(2-methoxyethyl) ether (Diethylene glycol dimethyl 
ether) . 

Bis(tributyltin) oxide 

Biuret 

Boron organic compounds: 

AXkylboranes 

Boron alcoholate 

Boron fluoride ethyl ether complex 

Boron trifluoride monoethylamlne complex 

Trie thy Iborane 



FOR. 
UCC. 



UCC. 

DOW, UCC. 
DUP, PAS, RH. 
FOR. 



ALB, ARC, BRD, DUP, GNM, ONX, PAS, RH, SDH. 



UCC. 
TRJ. 



ARC, 

DOW, 

UCC. 

RH. 

SHC. 

PAS. 

GNM. 

cm. 

PAS, 
CCW, 
COM, 
ARC, 
PAS. 
ADM, 
COM. 
PAS. 
UCS. 
DOW, 
COM. 
FMT, 
COM. 

COM. 
COM. 
SNW. 
UCC. 



COM, PUB, TBK. 

FB, NW. 

PAS, UCC. 

EMR. 

DUP. 

HUM. 
ADM. 
DOW, UCC. 

TKL. 

DOT, JCC, OMC, WIN. 

DOW, WYN. 

G. 
UCC. 



GLY, X. 

ASL. 



ASL, OMC. 



SW. 

CAL. 
SFA. 
ACG. 
ACG. 
CAL, TMA. 



MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 



187 



TABLE 21B. 



■Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer. 1963 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



KttSCELIANEOUS CHEMICAIS, ACYCLIC— Continued 

Boron organic compounds--Continued 

Triethyl borate 

Trimethoxyboroxine 

All other 

N-Bromoacetamide 

N-Bromosuccinimide CSuccinibromimidej 

l,2(and l,3)-Butanediol (Butylene glycol) 

1,4-Butanediol 

2,3-Butanediol (2,3-Butylene glycol) 

2,3-Butanedione 2-oxime 

1,2,4-Butanetriol 

2-Butanone (Methyl ethyl ketone) 

Butanone mixture 

*2-Butanone oxirae 

»2-Butanone peroxide 

2-Butene-l,'i-diol 

l-Butoxy-2,3-epoxypropane i^Butyl glycidyl ether) 

2-Butoxyethanol (Ethylene glycol monobutyl ether) 

2-(2-Butoxyethoxy)ethanol (Diethylene glycol monobutyl 

e ther ) . 
2-[2-(2-Butoxyethoxy)ethoxy]ethanol (Triethylene glycol 

monobutyl ether) . 

2-(2-Butoxyethoxy)ethyl acetate 

l-Butoxyethoxy-2-propanol 

2-Butoxyethyl acetate 

«Butyl acetates, ^0<f,■. 

Iso 

»Normal 

Secondary 

l»Uxed 

Butyl acrylate 

Butylene oxide 

Butyl ether (Di-n-butyl ether) 

Butylethyl thiourea •• 

tert-Butyl hydroperoxide 

2 , 2 ' - ( Butylimino ) diethanol ( N , N -Bis ( 2-hydroxyethyl ) butyl- 

amine) . 

Butyl isocyanate 

Butyl lactate 

n-Butyllithium 

Butylraagnesium chloride 

■»tert-Butyl peroxide (Di-tert-butyl peroxide) 

tert-Butyl peroxyacetate 

tert-Butyl peroxyisobutyrate 

tert-Butyl peroxypivalate 

1-Butyne (Ethylaoetylene; 

2-Butyne-l,'i-diol 

Butyr aldehyde 

Butyraldehyde oxime 

Butyric acid 

Butyric anhydride 

Butyrolactone 

Butyronitrile 

»Caprolactam (2-Oxohexamethylenimine) (Hexahydro-2H-azepin- 

2 -one) . 

Caprolactone 

»Carbon disulfide 

Castor oil maleate 



USB. 










CAL. 










CAL, 


USB. 








ARA. 










CEL. 










G. 










UCC. 










EK, 


[CO. 








G. 










EN J, 


RUB, 


SHC, 


UCC. 




CEL. 










ALB, 


CCA, 


MLD, 


NAC, 


TRO. 


CAD, 


NOC, 


RCI, 


UPR, 


WTL. 


G. 










DOW, 


SHC. 








JCC, 


OMC, 


UCC. 






OMC, 


UCC. 








DOW, 


OMC. 








UCC. 










UCC. 










UCC. 










CEL, 


EKT, 


ENJ, 


PAS, 


UCC. 


CEL, 


COM, 


EKT, 


ENJ, 


PUB, UCC 


EN J, 


HPC, 


PUB, 


SHC. 




CEL. 










CEL, 


DBC, 


UCC. 






DOW, 


UCC. 








UCC. 










PAS. 










CAD, 


UPR, 


WTL. 






PAS. 










CWN. 










COM. 










FTE. 










ARA. 










SHC, 


UPR, 


WTL. 






WTL. 










WTL. 










WTL. 










AIR. 










G. 










CEL, 


EKX, 


UCC. 






NAC. 










EKT, 


UCC. 








EKT, 


UCC. 








G. 










EKX, 


UCC. 








DBC, 


DUP, 


NAC. 







ACG, BKT, FMW, OLH, PAS, PPG, SF. 
RH. 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 21B. 



• Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEIvaCALS, ACYCLIC— Continued 

^Cellulose esters: 

■Oellulose acetate 

Cellulose acetate butyrate 

Cellulose acetate propionate 

Cellulose propionate 

Nitrocellulose (Cellulose nitrate) 

All other 

^Cellulose ethers; 

Ethylcellulose 

Ethylhydroxyethylcellulose 

Hydroxyethylcellulose 

Methylcellulose 

^Sodium carboxymethylcellulose, 100^ 

Sodium oarboxymethylhydroxyethylcellulose 

Cetyl chloride 

»Chloral (Triohloroacetaldehyde) 

Chloroacetamide 

*Chloroacetic acid, mono- 

Chloroacetic acid, mono, derivatives: 

Butyl chloroacetate 

»Ethyl chloroacetate 

Methj'l chloroacetate 

Sodium chloroacetate 

Chloroacetonitrile 

Chloroacetyl chloride 

2-Chloro-N,N-diethylamine hydrochloride 

2-Chloro-l,l-dimethoxyethaiie (Dimethyl ohloroaoetal) 

»2-Chloro-N,N-dimethylethylamine (Dimethylaminoethyl 
chloride) hydrochloride. 

2-Chloro-N,N-dimethylpropylamine 

2-Chloro-N,N-dimethylpropylaraine hydrochloride 

3-Chloro-N,N-dlmethylpropylamine hydrochloride 

Chlorodimethylvinylsilane 

2-Chloroethanol (Ethylene chlorohydrin) 

2-(2-Chloroethoxy)ethyl 2-ohloroethyl ether (Triethylene 
glycol dichloride). 

2-Chloroethylamine hydrochloride 

2-Chloroethyl vinyl ether 

<i-Chloro-3-hydroxybutyronitrile 

Chloromaleic anhydride 

p-Chloro-N-methylallylamine 

Chloromethyl methyl ether 

l-Chloro-l-penten-3-one (P -Chlorovinyl ethyl ketone) 

3-Chloro-l,2-propaiiediol (Glycerols- chlorohydrin) 

»l-Chloro-2-propanone ( Chloroacetone ; 

N-Chlorosuccinimide (Suocinichlorimlde j 

2-Chlorotriethylamine hydrochloride 

Chlorotrimethylsilane 

Citric acid 

Citric acid salts: 

Ammonium citrate 

Barium citrate 

Calcium citrate 

Ferric ammonium citrate 

Ferric citrate 

Ferrous calcium citrate 

Potassium citrate 

Sodium citrate 



AV, CEL, DUP, 


EKT. 


EKT. 




EKT. 




CEL. 




DUP, HPC. 




EK. 




DOW, HPC. 




HPC. 




HPC, UCC. 




DOW. 




BUK, DUP, HPC 


KON, WYN. 


HPC. 




BC. 




DA, FMW, GGY, 


MPG. 


BPC, DOW. 




BUK, DOW, HPC 


MON. 


MON. 




DOW, KF, MON. 




BPC, DOW, KF. 




DOW. 




BPC. 




DOW. 




NES. 




LIL. 




ABB, GAM, HEX 


MCH, NES, WYI 


SK. 




NES, WYT. 




MCH. 




DCC. 




OMC, UCC. 




UCC. 




ICI. 




UCC. 




X. 




RBC. 




LIL. 




HK, X. 




ABB. 




EVN, ICO. 




BPC, EK, GAJjI, 


MRK. 


NAC. 




HEX, M;H, X. 




DCC, UCS. 




BZ, MLS, PFZ. 




MAL, PFZ. 




SW. 




PFZ. 




MAL, PFZ. 




MAL. 




BKL. 




MLS, PFZ. 




MLS, PFZ. 





MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 



189 



TABLE 21B. 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAI5, ACYCLIC— Continued 

Coconitrile 

Coconut oil amide 

Cottonseed oil nitrile 

Creatine and creatinine 

Crotonaldehyde 

Crotonic acid (2-Butenoio acid) 

2-Cyanoacetamlde 

Cyanoacethydrazide 

Cyanoacetic acid and salt 

Cyanogen bromide 

1,10-Decanediol 

Decanoic acid (Capric acid) 

Decanoyl chloride 

Decanoyl peroxide 

l-.Decene 

Dialdehyde starch 

Diallyl maleate 

1,2-Dibutoxyethane (Ethylene glycol di-n-butyl ether 

2-Dibutylaminoethanol 

Dibutylaminopropanol 

Dibutyl ammonium laurate 

»Dibutyl fumarate 

«Dibutyl maleate 

l,3-Dibutyl-2-thiourea 

Dibutyltin compounds: 

Dibutylmethoxytin (Dibutyltin methoxide) 

Dibutyltin bis(lauryl mercaptide) 

Dibutyltin dichloride 

Dibutyltin dilaurate 

Dibutyltin maleate 

Dibutyltin mercaptopropionate 

Dibutyltin oxide 

All other 

Dichloroacetaldehyde 

Dichloroacetic acid 

Dichloroacetyl chloride 

2,2-Dichloro-l,l-difluoroethyl methyl ether 

Dichlorodimethylsilane 

Diohlorohydrogenmethylsilane 

Dichloromethylvinylsilane 

l,3-Dichloro-2-propanol 

2,3-Dichloro-l-propanol 

Dicyanobutene 

Diethoxydimethylsilane 

Diethylaluminum chloride 

Diethyl allyl(l-methylbutyl)malonate 

2-Diethylaminoethanethiol hydrochloride 

2-Diethylaminoethanol 

2-(2-Dlethylaminoethoxy)ethanol 

2-Diethylaminoethyl methacrylate 

Diethylaminopropionamide 

Diethyl sec-butylethylmalonate 

Diethyl butylmalonate 

Diethyl sec -butylmalonate 

Diethylcarfiamoyl chloride 

Diethyl carbonate (Ethyl carbonate) 

Diethyl diethylmalonate (Diethyl malonic ester) 

»Diethylene glycol 



FOR. 

AHC, KES, PG. 

FOR. 

PFN. 

GEL, EKT, UCC. 

EKT. 

KF. 

KF. 

KF. 

EK. 

NEP. 

FOR. 

TBK. 

CAD, UPR, WIL. 

HMY. 

MLS. 

FWP. 

DOW. 

AAC, PAS. 

ABB. 

UCC. 

M)N, PCC, RCI, RUB. 

AIR, DUP, GRD, GRH, LAS, MDN, PCC, RCI, RUB. 

PAS, RBC. 

CCA. 
x. 

X, X. 

CCA, CCW, X. 
CCA, X. 
CCA, X. 



nm. 

KF. 

EK. 

DOW. 

DCC, UCS. 

Dec, UCS. 

DCC. 

PRH. 

UCC . 

X. 

UCS. 

TNA, TSA. 

BPC. 

EVN. 

AAC, PAS, UCC. 

PAS. 

DUP. 

X. 

ABB. 

BPC. 

ABB. 

GAM. 

CTN, FMP. 

BPC, LIL. 

ACN, CAU, DOW, G, HCH, JCC, OhC, UCC, WYN. 



190 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 21B.- 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

Diethylene glycol chlorofonnate 

Diethyl ( ethoxymethylene ) malonate 

Diethyl ethylisopentylmalonate 

Diethyl ethylmalonate (Ethyl malonic ester) 

Diethyl ethyl(l-methylbutyl) malonate 

Diethyl ethyl (3-methylbutyl)malonate 

Diethyl ethyl (1-me thy IpropyDmalonate 

Diethyl fmnarate 

Di-2-ethyl-l-hexyl fumarate 

Di-2-ethyl-l-hexyl maleate 

N,N-DiethyIhydroxylamine sulfate 

Diethyl maleate 

Diethyl malonate (Malonic ester) 

Diethyl (l-methylbutyl)malonate 

Diethyl (3-methylbutyl)malonate 

Diethyl methylmalonate 

Diethyl (l-methylpropyl)malonate 

Diethyl oxalate (Ethyl oxalate) 

2,2-Diethylpropanediol 

Diethyl thiophosphoryl chloride 

l,3-Diethyl-2-thlourea 

Diethylzinc 

Diglycolic acid 

Dihydropseudoionone 

3,<i-Dihydro-2H-pyran-2-carboxaldehyde (Acrolein dimer) 

l,4-Dihydroxy-2-butanone 

l,3-Dihydroxy-2-propanone (Dihydroxy acetone) 

2-Diisopropylaminoethanol (NjN-Diisopropylethanolamine) 

Diisopropylaramonium nitrite 

0,0-Diisopropyl dithiobis(thioformate) 

Diisopropyl peroxydicarbonate (Isopropyl peroarbonate) 

l,3-Diisopropyl-2-thiourea 

»Dilaiiryl 3,3'-thiodipropionate (Didodecyl thiodipropio- 
nate ) . 

Dimethoxyethane (Ethylene glycol dimethyl ether) 

N,N-Di(methoxyethyl)hydroxylajiiine 

N,N-Dimethylacetamde 

NjN-Dimethylacetoaoetajnide 

»2-Dimethylaminoethanol 

Dimethylami no-2-propanol 

3-Dimethylamlnopropionitrile 

Dimethyloarbamoyl chloride 

Dimethyl carbonate 

N-(1,1-Dimethyldecyl)methylenimine 

2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane 

2,5-Dimethyl-2,5-di(tert-butylperoxy)hexyne-3 

N,N-Dimethylform amide 

Dimethylglyoxime 

2,6-Dimethyl-4-heptanol (Diisobutylcarbinol) 

2,5-Dimethyl-2,5-hexanediol 

2,5-Dimethyl-3-hexyne-2,5-diol 

1,1-Dimethylhydrazine 

Dimethyl malonate 

Di(4-methyl-2-pentyl) maleate 

2,2-Dimethyl-l,3-propanediol (Neopentyl glycol) 

1,3-Dimethylurea 

Dioctanoyl peroxide (Caprylyl peroxide) 

Dioctyl fumarate 



PPG. 

KF. 

LIL. 

LTL. 

ABB, BPC. 

BPC. 

BPC. 

MOM. 

RUB. 

GIN. 

EK. 

ACY, UCC. 

ABB, KF, LIL. 

ABB, BPC, LIL. 

BPC. 

BPC. 

BPC. 

FMP. 

RBC. 

ACY. 

PAS, RBC. 

TNA. 

DUP. 

GIV. 

UCC. 

G. 

BAX, PFZ. 

PAS, UCC. 

OMC. 

DUP. 

PPG. 

G. 

ACY, CCW, EVN, HAB. 

ASL, OMC. 

UP J. 

DUP. 

EICI. 

PAS, RH, UCC. 

COM. 

ACY. 

GAM. 

FMP. 

SPP. 

WTL. 

WTL. 

DUP. 

EK. 

UCC. 

AIR. 

AIR. 

FMP, FMW. 

KF. 

RUB. 

EKX. 

PAS. 



MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 



191 



TABLE 21B.- 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Meinuf acturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAI^, ACYCLIC--Continued 

Dioctyl maleate 

l,3-Diootyl-2-thiourea 

«Dipropylene glycol 

P,P -Dipropylenlmine sulfone 

Distearyl 3,3'-thiodipropionate 

Dithiooxamide 

Ditridecyl maleate 

Divlnyl sulfone 

n-Dodeoane 

»Dodecenylsuccinio anhydride 

Epiohlorohydrin 

Eruc amide 

Ethanedlthlol 

»Ethanolamines : 

«2-Aiiiinoethanol (Monoethanolamine ) 

»2,2'-IrQlnodiethanol ( Diethanolamine ) 

«2,2',2"-Nitrilotriethanol (Triethanolamine) 

Ethanolamine hydrochloride 

Ethanolamine sulfite 

*2-Ethoxyethanol (Ethylene glycol monoethyl ether) 

2-(2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl 

ether) . 
2- [2-(2-Ethoxyethoxy)ethoxy]ethanol (Triethylene glycol 
monoethyl ether ) . 

2-(2-Ethoxyethoxy)ethyl acetate 

2-Ethoxyethyl acetate 

3-Ethoxypropanol (Propylene glycol monoethyl ether) 

3-Ethoxypropionitrile 

l-Ethoxy-l,3,3-trimethoxypropane 

*Ethyl acetate, 85^ 

*Ethyl acetoacetate 

•Ethyl acrylate 

Ethylaluminum dichloride 

Ethylaluminum sesquichloride 

2-Ethylaminoethanol ( Ethylmonoethanolamine ) 

Ethyl bromoacetate 

2-Ethylbutyr aldehyde 

2-Ethylbutyric acid (Diethylaeetic acid) 

Ethyl carbamate 

Ethyl chloroformate 

Ethyl 3-(chloroformyl)propionate ( |3 -Carbethoxypropiony 1 
chloride) . 

Ethyl oyanoacetate 

Ethylene, from ethyl alcohol 

Ethylene carbonate 

•Ethylene glycol 

Ethylene glycol diacetate 

Ethylene glycol dlmercaptoacetate 

Ethylene glycol dlmethacrylate 

•Ethylene oxide 

•Ethyl ether: 

Absolute 

Tech 

U.S.P — - — 

•Ethyl formate 

2-Ethylhexanal (a -Ethylcaproaldehyde) 

2-Etl^l-l,3-hexanediol 

2-Ethylhexanoic acid (a-Ethylcaproic acid) 



MDN, 
PAS. 
CEL, 
RBC. 
CCW. 
MAL. 
RUB. 
RBC. 
HMY. 
HMy, 
DOW, 
FIN, 
RBC. 



RUB. 

DOW, jcc, om, UCC. 



MON, NAG. 
SHC, UCC. 
HUM. 



ACN, DOW, JCC, UCC. 

ACN, DOW, JCC, UCC. 

ACN, DOW, JCC, UCC. 

WSN. 

EVN, SUM. 

DOW, JCC, CMC, UCC. 

DOW, OMC, UCC. 



DOW, 


OMC. 




UCC. 






UCC. 






UCC. 






KF. 






CEL, 


COM, EKT, ENJ, HPC, PUB, SRC, UCC. 




EKT, 


FMP, UCC. 




CEL, 


DBC, RH, UCC. 




TNA. 






TNA, 


TSA. 




PAS. 






GAM. 






UCC. 






UCC. 






FMP. 






FMP. 






ABB. 






KF. 






OH. 






DOW, 


JCC. 




ACN, 


APD, CAU, CEL, DOW, DUP, ENJ, G, GOC, 


HCH, JCC 


OMC, UCC, WYN. 




UCC. 






EVN. 






SAR. 






ACN, 


CAU, DOW, G, HCH, JCC, OMC, SNO, UCC, 


WYN. 


MAL. 






EN J, 


HPC, UCC, USI. 




MAL, 


OMS. 




COM, 


FB, TBK, UCC. 




EKX, 


UCC. 




UCC. 






EKT, 


UCC. 





192 



SYNTHETIC ORGANIC CHEMICALS 1963 



TABLE 2\B.— Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i 963 --Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

*2-Ethylhexanoic acid (a-Ethylcaproic acid) salts: 

Aluminum 2-ethylhexanoate 

Barium 2-ethyIhexanoate 

Cadmium 2-ethyIhexanoate 

«Caloium 2-etl^lhexanoate 

i»Cobalt 2-ethylhexanoate 

Copper 2-ett^lhexanoate 

Dibutyltin di-2-ethylhexanoate 

Iron 2-ethylhexanoate 

»Lead 2-ethylhexanoate 

^Manganese 2-ethylhexanoate 

Potassium 2-ethylhexanoate 

Rare earths 2-ethylhexanoate 

Stannous 2-ethylhexanoate 

Strontium 2-ethylhexanoate 

»Zinc 2-ethylhexanoate 

Zirconium 2-ethylhexanoate 

2-Ethyl-l-hexyl acetate 

»2-Ethyl-l-hexyl acrylate 

2-Ethylhexyl oyanoacetate 

2-Ethylhexyl methacrylate 

Ethyl 2-hydroxy-3-methylbutyTate (Ethyl a-hydroxyiso- 

valerate ) . 
2-Bthyl-2-(hydroxymethyl)-l,3-propanediol (Trimethylol- 
propane ) . 

2-Ethyl-2-(hydroxymethyl)-l,3-propanediol allyl ethers 

Ethyl isooyanate 

Ethyl lactate 

Ethylmagnesiiim bromide 

2-( Ethylmercapto)ethanol 

Ethyl 2-methyllactate ( Ethyl a -hydroxyisobutyrate ) 

Etl^l propionate 

»Ethyl silicate (Tetraethoxysilane) 

Ethyl sulfate (Diethyl sulfate)— 

Ethyl vinyl ether 

Fats and oils, chemically modified: 

Castor oil, phosphonated 

Lard oil, nitrated 

Oxy stearin 

Vegetable oils, brominated 

Other 

Fatty acids, chemically modified: 

a-Bromo(lauric-stearic) acids 

Castor oil fatty acids, dehydrated 

All other 

Fatty acid esters, not included with plasticizers or 
surface-active agents : 

Ethyl stearate 

Jfethyl caprylate 

Methyl esters of coconut oil fatty acid 

Ifethyl esters of tallow 

Methyl linoleate 

All other 

Fish oil fatty acid amide 

Flotation reagents : 

Isopropyl ethylthionocarbamate 

Phosphorodithioates (Dithiophosphates) : 

Potassium dihexyl phosphorodithioate 

Sodium di-sec-butyl diethyl phosphorodithioate 



WTC. 

CCA. 

CCA. 

CCA, FER, HNX, HSH, MLD, SRR, SW, WTC. 

CCA, FER, HNX, HSH, MLD, SHP, SRR, SW, WTC. 

CCA, SRR. 



CCA, 


HNX, 


HSH, MLD, 


SHP, SRR, SW, WTC 


CCA, 


HNX, 


MLD, SRR. 




CCA. 








CCA, 


MLD. 






WTC, 


x. 






CCA. 








CCA, 


HNX, 


HSH, SRR, 


WTC, X. 


CCA, 


HNX, 


WTC. 




EKT, 


UCC. 






CEL, 


DBC, 


RH, UCC. 




KF. 








DUP. 








RH. 








CEL. 








CEL. 








ore. 








KF. 








ARA. 








PAS. 








RH. 








FB, 


NW, TBK. 




KfTR, 


SFA, 


UCC. 




UCC. 








UCC. 








VIC. 








SPP. 








BCN. 








ABB, 


DCW, 


HT. 




CHL. 








DUP. 








BAG. 








GNM, 


RH, 


RI. 




ICO. 








FOR. 








PPG. 








BFR. 








CLI. 








CLI, 


ICO 


RT, X. 




Am. 








DOW. 








ACY. 








ACY. 









MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 



193 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1963— Continued 



Jfenuf acturers ' identification codes 
(according to list in table 22) 



LaSCELLANEOUS CHEMICALS, ACYCLIC— Continued 

Flotation reagents — Continued 

Phosphorodithioates ( Dithiophosphates ) — Continued 

Sodium di-seo-butyl phosphorodithioate 

Sodium diethyl phosphorodithioate 

Sodium dihexyl phosphorodithioate 

Sodium diisopropyl phosphorodithioate 

Other 

Xanthates : 

Potassium n-butylxanthate 

Potassium ethylxanthate 

Potassium isopropylxanthate 

Potassium pentylxanthates 

Potassiiim sec-pentylxanthate 

Sodium n-butylaanthate 

Sodium sec-butylxanthate 

Sodium ethylxanthate 

Sodium isobutylxanthate 

Sodium isopropylxanthate 

All other 

•Formaldehyde, 37^ by weight 

Formamide 

»Formio acid, 90^t 

*Formic acid salts : 

•Aluminum formate 

Ammonium formate 

Calcium formate 

Chromic formate 

Copper formate 

Lead formate 

Nickel formate 

Potassium formate 

Sodium formate, refined 

Sodium formate, tech 

Thallous formate 

»Fumaric acid 

•Gluconic acid, tech 

Gluconic acid, calcium salt 

•Gluconic acid, sodium salt, tech 

Glucono-delta-lactone 

Glucose pentaacetate 

Glutaraldehyde bis [sodium bisulfite] 

Glutaric acid 

•Glycerol, synthetic 

Glycidol (2,3-IiJoxy-l-propanol) 

Glycine (Aminoacetic acid), tech 

Glycine ethyl ester hydrochloride 

Glycolic acid ( ffydroxyacetic acid) 

Glycolic acid salts : 

Alximinum glycolate 

Sodium glycolate 

Glycolonltrile 

Glyoxal 

Guanidine hydrochloride 

■i-Guanyl-l-isonitrosoguanyl-l-tetrazene 



ACY. 
ACY. 
ACY. 
ACY. 
ACY. 

USR. 

ACY, DOW. 

DOW. 

ACY, DOW. 

DOW. 

KCC, USR. 

ACY, DOW. 

ACY, ADM, DOW. 

DOW. 

ACY, DOW. 

ACY, PJM. 

ACN, BOR, GEL, COM, DUP, HKD, HN, HPC, MON, RCI, RH, 

SPN, TRJ, UCP. 
DUP. 
DUP, HN, VIC. 



SNW, 

ACG. 

TRJ. 

G. 

CTN. 

NTL. 

HSH. 

TNC. 

ACG, 

HN, 

EK. 

BZ, 

CWL, 

DLL 

CWL, 

DLI, 

BiCL. 

IDC, 

CS, 

APD, 

ore. 

BPC. 
BPC. 
DUP. 

TRC. 
MED. 
ACY. 
UCC. 
ACY. 
RBJ. 



UCC, VIC. 



BKC. 
HPC. 



HN, MON, NAC, NTL, PCC, PTT, SOC. 
DLI, IBI, PFZ. 



DLI, PFZ. 
PFZ. 



RZL. 
EK. 
DOW, IBI, 



C, RH, SHC, UCC. 



194 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

»Halogenated hydrocarbons: 

»l-Bromobutane (n-Butyl bromide) 

2-Bromobutane (sec-Butyl bromide) 

Bromochloromethane 

l-Bromo-3-ohloropropane (Trimethylenechlorobromide) 

2-Bromo-2-chloro-l,l,l-trifluoroethane 

Bromoethane (Ethyl bromide) 

1-BroiBohexane t;n-Hexyl bromide) 

l-Bromo-2-methylbutane 

l-Bromo-octadecane 

»l-Bromopentane (n-Amyl bromide) 

2-Bromopentane ( 1-Methylbutyl bromide) 

»l-Bromopropane (n-Propyl bromide) 

2-Bromopropane 

3-Bromopropene (Allyl bromide) 

3-Bromopropyne 

Bromotrichloromethane 

Bromotrifluorome thane 

•Carbon tetrachloride 

•Chlorinated paraffins: 

Less than 35^ chlorine 

»35^-64'i chlorine 

65^ or more chlorine 

1-Chlorobutane (n-Butyl chloride) 

l-Chloro-l,l-difluoroe thane 

•Chlorodifluoromethane 

»Chloroethane (Ethyl chloride): 

Tech 

U.S.P - 

•Chloroform: 

•Tech 

•U.S.P — - 

2-Chloro-3-hexyne 

•Chloromethane (Methyl chloride ) : 

Crude 

Refined (refrigerant grade) 

2-Chloro-2-methylpropane (tert-Butyl chloride) 

3-Chloro-2-methylpropene (Methallyl chloride) 

Chloropentafluoroethane 

1-Chloropentane (n-Amyl chloride) 

Chloropentanes , mixed isomers 

2-ChloropropaDe (Isopropyl chloride) 

3-Chloropropene (Allyl chloride) 

Chlorotrifluoroethylene (Trifluorovinyl chloride) — 

Chlorotrifluoroethylene, polymerized 

Chlorotrifluoromethane 

l,2-Dibromo-l,l-diohloroethane 

Ditromodifluoromethane 

1,2-Dibromoethane (Ethylene dibromide) 

Dibromomethane (Methylene bromide) 

1,3-Dibromopropane 

l,2-Dibromo-l,l,2,2-tetrafluoroethane 

1,4-Dichlorobutane 

l,<i-Diohlorobutene 

•Dichlorodifluoromethane 

•1,2-Dichloroethane (Ethylene dichloride) 

1,2-Diohloroethylene 

Diohlorofluoromethane 



ABB 


BPC 


CLB, DOW, MCH. 


ABB 


BPC. 




DOW. 






DOW, 


yen. 




ICI. 






DOW, 


MCH 




BPC. 






LIL. 






DUP, 


G. 




BPC, 


CLB, 


DOW. 


ABB, 


LIL. 




CLB, 


DOW, 


EK. 


BPC, 


DOW. 




CLB, 


DOW. 




G. 






DOW. 






DUP. 






ACQ, 


ACS, 


DA, DOW, FMW, FRO, KLK 


HK, 


WOI. 




CCH, 


DA, 


DVC, HK, HPC, KPT, WOI. 


DA, 


DVC, 


WOI. 


PUB, 


UCC. 




ACQ. 






ACQ, 


DUP, 


KAI, PAS, UCC. 



AME, DOW, DUP, HPC, TNA, USI. 
DOW, SHC. 

ACS, DA, DOW, DUP, FRO, KLK, SF. 

ACS, DA, DOW. 

LIL. 



ANM 

ACS 

DUP 

FMP 

DUP 

CLB 

PAS 

DOW, 

DOW 

ACG 

HK, 

ACG, 

DOW. 

DOW. 

DOW, 

DOW. 

EK. 

DUP. 

DUP, 

DUP. 

ACG, 

AME, 

DUP. 

ACG. 



DCC, DOW, TNA. 
DA, DOW, DUP, KLK. 
EK, RBC. 



SHC. 

^MM. 

MMM. 
DUP, PAS. 



ETD, FMW, HCH, MCH. 



DUP, KAI, PAS, UCC. 

DA, DOW, JCC, ION, OMC, PPG, TNA, UCC, WYN. 



4 



MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 



195 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHE^^;CAI£, ACYCLIC— Continued 

»Halogenated hydrocarbons --Continued 

»Dichloromethane (Methylene chloride) 

Dichloropentanes, mixed isomers 

«l,2-Liichloropropane (Propylene dichloride) 

2,3-Dichloropropene 

»Dichlorotetrafluoroethane 

1,1-Difluoroethane 

1,1-Difluoroethylene 

Difluorotetrachloroethane 

Diiodomethane (Methylene iodide) 

Hexaf luoropropylene , monomer 

lodoethane (Ethyl iodide), tech 

»Iodomethane (Methyl iodide) 

Poly-2,3-dichlorobutadiene-l,3-brominated 

1,1,2,2-Tetrabromoethane (Acetylene tetrabromide ) 

Tetrabromomethane 

1,1,2,2-Tetraohloroethane (Acetylene tetrachloride) — 

»Tetrachloroethylene ( Perchloroethylene ) 

Tetrafluoroethane polymer 

Tetrafluoroethylene, monomer 

Tetrafluoromethane 

1,1,1-Trichloroethane (Methyl chloroform) 

»l,l,2-Trichloroethane (Vinyl trichloride) 

«Trichloroethylene 

«Trichlorofluoromethane 

1,2,3-Trichloropropane 

1,2,3-Trichloropropene 

Trichlorotrifluoroethane 

"•Vinyl chloride, monomer ( Chloroethylene ) 

Vinyl fluoride 

Vlnylidene chloride, monomer (1,1-Dichloroethylene) — 

Vinylidene fluoride 

All other 

2-Heptanone (Methyl amyl ketone) 

3-Heptanone (Ethyl butyl ketone; 

Hexachloro-2-propanone 

Hexadecane 

Hexadecenyl succinic anhydride 

Hexamethylenediamine dicarbamate 

Hexamethylenediammonium adipate 

2,5-Hexanedione (Acetonylacetone) 

1,2,6-Hexanetriol 

1,2,6-Hexanetriol octoate 

Hexanoic acid (Caproic acid) 

5-Hexen-2-one (Allylacetone) 

Hexyl acetate 

n-Hexyl ether 

2-[2-(Hexyloxy)ethoxy]ethanol 

Hydracrylonitrile (Ethylene oyanohydrin) ■ 

Hydrazine and salts 

2-Hydrazinoethanol 

2-(Hydroxymethyl) -2-methyl-l,3-propanediol (Trlmethylol 

ethane) . 
2-(Hydroxymethyl)-2-nltro-l,3-propanediol (Tris( hydroxy - 

methyDnitromethane) . 
N-(Hydroxyiiiethyl)octadecanamide (N-Hydroxymethylsteara- 
mide) . 



ACS, DA, DOW, DUP, FRO, KLK, SF. 

PAS. 

DOW, JCC, UCC, WYN. 

DOW, UCC. 

ACQ, DUP, PAS. 

ACQ, DUP. 

ACG. 

DUP. 

NTB, SDW, X. 

DUP. 

CLB, EK. 

CLB, EK, NTB, RSA. 

CWN. 

DOW. 

DOW. 

DUP, PPG. 

DA, DOW, DUP, FRO, HK, PPG, SF, TTX. 

DUP. 

DUP. 

DUP. 

DOW, PPG. 

DOW, TNA, UCC. 

DOW, J)UP, HK, PPG, TTX. 

ACG, DUP, KAI, PAS, UCC. 

DOW, SHC. 

DOW. 

ACG, DUP, PAS. 

ACS, AME, BFG, BOR, CUM, DA, DOW, GNT, GYR, 

TNA, UCC. 
DUP. 

DOW, TNA. 
DUP. 

CLB, KPT, NES, SDH, X. 
UCC. 
UCC. 
DUP. 
HMY. 
HMY. 
BKL. 
CS. 
RBC. 
UCC. 
KES. 

FB, TBK. 
FMP. 
EN J. 
UCC. 
UCC. 
UCC. 

FMT, OMC. 
NOR. 
TRJ. 

CCM. 

DUP. 



3, ^DN, 



196 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAIS, ACYCLIC— Continued 

<4--Hydroxy-4-methyl-2-pentanone (Diacetone alcohol) 

(Hydroxymethyl)urea (Methylol-urea) 

Hydroxypropyl methacrylate 

3,3'-Iininodipropionitrile 

lodomethylmercury iodide 

N-Iodosuccinimide 

Isethionlc acid C2-Hydroxyethanesulfonio acid) 

Isethionic acid, sodium salt 

Isoasoorbic acid 

Isoascorbic acid, sodium salt 

Isobutoxyethanol 

Isobutyl acrylate 

Isobutyl isobutyrate 

Isobutyl vinyl ether 

Isobutyr aldehyde 

Isobutyrlc acid and anhydride 

Isobutyronitrlle 

Isodecaldehyde, mixed isomers 

Isodecanoic acid, mixed isomers 

Isodecyl acrylate 

Iso-octanoic acid, mixed isomers 

Isopentyl ether (Isoamyl ether) 

Isopropanolamines : 

l-Amino-2-propanol (Monoisopropanolamine) 

1,1' -Iminodl-2-propanol (Diisopropanolamine) 

1,1' ,1" -Nitrilotri-2-propanol (Trilsopropanolamine) — 

Isopropenyl acetate (Methyl vinyl acetate) 

3-Isopropoxypropylamine 

»Isopropyl acetate 

2-lsopropylaminoethanol 

Isopropyl chloroformate 

»Isopropyl ether 

Isovalerone (Diisobutyl ketone) 

Itaconlc acid (Methylenesuocinio acid) 

»Laotio acid, lOOjt: 

»Edible 

•Medicinal 

*Teohnlcal 

Lactic acid salts: 

Aluminum lactate 

Aluminum sodium chlorohydroxylactate 

Aluminum sodium lactate ■ 

Calcium lactate 

Lactic anhydride 

Laotide (3,6-Dimethyl-2,5-p-dioxanedione) 

Laioric acid salts 

Lauronitrile 

Lauroyl bromide 

»Lauroyl chloride 

Lauroyl peroxide 

Levulinlc acid 

»Llnoleic acid salts: 

»Calcium linoleate 

»Cobalt linoleate 

Copper linoleate 

Iron linoleate 

Lead linoleate-- 



SHC, 


UCC. 




DUP. 






JCC. 






ACY. 






NTB. 






G. 






WTC. 






MRK, 


PFZ. 




BAX, 


MRK, 


PFZ. 


UCC. 






DBC. 






EKX. 






G, UCC. 




EKX, 


UCC. 




EKT. 






EKX. 






UCC. 






UCC. 






UCC. 






UCC. 






GIV. 






DOW, 


UCC. 




DOW, 


UCC. 




DOW, 


UCC. 




UCC. 






DUP. 






EKT, 


EN J, 


HPC, UCC. 


PAS, 


WTC. 




era, 


FMP, 


PPG. 


EN J, 


SHC, 


UCC. 


EKT, 


UCC. 




PFZ. 






AMZ, 


CLN, 


DUP. 


DUP, 


PFN. 




AMZ, 


CLN, 


DUP. 


TNC. 






REH. 






REH. 






AMZ, 


SHF. 




FB. 






CLN. 






CCW. 






FOR. 






DOW. 






BC, 


G, HK 


, MDN, TBK 


CAD, 


UPR, 


WTL. 


CRZ, 


QKO. 




CCA, 


LEF, 


SHP, SRR. 


HSH, 


SHP, 


SRR. 


WTC. 






HSH. 






SHP, 


SRR. 





MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 



197 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i 565 --Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAI£, ACYCLIC— Continued 

»Linoleic acid salts — Continued 

Lead manganese linoleate 

Manganese linoleate 

♦Lubricating oil additives: 

Chloronaphtha xanthate 

Chlorosulfurized hydrocarbon 

Chlorosulfurlzed lard oil 

Chlorosulfurized sperm oil 

High-molecular-weight hydrocarbons and their phosphorus 
derivatives. 

Oxidized hydrocarbons 

»Phosphorodithioates (Dithiophosphates) : 

Barium alkyl phosphorodithioates 

Barium dioctyl phosphorodithioate 

Bariim polyisobutylene phosphorodithioate 

Nickel zinc allcyl phosphorodithioates 

Zinc alkyl phosphorodithioates 

Zinc di(butylhexyl) phosphorodithioate 

Zinc dihexyl phosphorodithioate 

Zinc hexyl isopropyl phosphorodithioate 

All other 

Phosphorosulfurlzed compounds 

SuLfurized butenes 

»Sulfurized lard oil 

Sulfurized methyl oleate 

»Sulfurized sperm oil 

Tetradecyl selenide 

All other 

Magnesium methylate 

Maleic acid 

Maleic acid, tribasic lead salt 

*Maleic anhydride 

Malic acid 

Malonic acid 

Malonic acid salts 

Malononitrile 

Mannitol 

Mannltol hexanitrate 

Mercaptoacetic acid ( Thioglycolic acid) 

♦Mercaptoacetic acid (Thioglycolic acid) derivatives: 
■>f2 -Aminoethyl mercaptoacetate (Ifonoethanolamine thio- 
glycolate) . 

Ammonium mercaptoacetate (AmmoniiMi thloglycolate) 

Antimony mercaptoacetate 

Calcixim mercaptoacetate 

Dibutyltin bis(iso-octylmercaptoacetate) 

Dibutyltin mercaptoacetate 

Iso-octyl mercaptoacetate 

Potassium mercaptoacetate 

Sodium mercaptoacetate 

3-hfercapto-l,2-propanediol ( Thioglyoerol) 

p-Kfercaptopropionio acid 

Mercaptosuocinlc acid (Thlomalic acid) 

kfetal soaps of oxidized hydrocarbons 

Methacrylamide --^ 

ftethacrylate monomers, above methyl 

kfethacrylic acid 



SDH, SRR. 




SHP, SRR. 




MON. 




EN J. 




CCW. 




CCW. 




SOI. 




ALX. 




LUB. 




ACY. 




X. 




SIN. 




EN J, LUB. 




ORG. 




MON, SIN. 




TX. 




ACY, LUB, MON, TX. 




ENJ, SIN. 




LUB. 




CCW, GOC, SIN, SOI. 




SIN. 




CCW, LUB, eCP, SIN, SOI, WBG. 




ORO. 




CCW, ENJ, HK, LUB, MDN, ORO, SIN, 


SOI, X. 


MRT. 




NAC, PFN. 




NTL. 




ACY, HN, KPS, MON, NAC, PCC, PTT, 


RCl, SOC 


EK, NAC, PFN. 




KF. 




EK, GIV. 




KF. 




APD. 




APD. 




EVN, RET. 




EVN, HAB, RET. 




EVN, HAB, RET. 




CCA. 




Era. 




X. 




CCA. 




CCW, e™. 




Era. 




Era. 




ETO. 




Era. 




Era. 




ALX. 




RH, X. 




DUP, SAR. 




DUP, RH. 





SYNTHETIC ORGANIC CHEMICALS 1963 

TABLE 2\B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i563--Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MSCEIiANEOUS CHMICALS, ACYCLIC— Continued 

Ifethaerylic acid, potassium salt 

Ifethacryloyl chloride 

Me thane sulfonic acid 

»2-lfethoxyethanol (Ethylene glycol monomethyl ether) 

2-(2-Kfethoxyethoxy)ethanol (Diethylene glycol mono- 
methyl ether). 

»2-[ 2- ( 2-Methoxyethoxy ) ethoxy lethanol ( Triethylene 
glycol monomethyl ether). 

2-Methoxyethyl acetate 

2-Methoxyethylamine 

'i-Jfethoxy-4-methyl-2-pentanol 

<»-Methoxy-^-methyl-2-pentanone 

Methoxypolyethylene glycol 

l-Methoxy-2-propanol 

3-Methoxypropionitrile 

3-(3-Methoxypropoxy)propanol (Dipropylene glycol methyl 

ether) . 
3- [ 3- ( 3 -Jfe thoxypropoxy ) propoxy ] propanol ( Tripropylene 
glycol methyl ether) . 

3-MBthoxypropylamine 

Methoxytriethyleneglycol acetate 

"Methyl acetate 

MetJ^fl acetoacetate 

Methyl acrylate, monomer 

Methylal (Dimethoxyme thane) 

Methylaluminum sesquichloride 

2-Methylamlnoethanol ( N-Methylethanolamine ) 

Methyl borate 

Methyl butynoxyethanol 

Ifethyl carbamate 

Ifethyl chloroformate 

Methyl cyanoacetate 

Msthyl 2-cyanoacrylate 

Methyl dichloroacetate 

Methyl disulfide (Dimethyl disulfide) 

N, N'-Methylenebisacrylamide 

N, N'-Methylenebisoctadecanamlde 

Methyl ether (Dimethyl ether) 

Methyl ethyl carbamate (Methyl urethane) 

Jfethyl formate 

N-Methylglucamine 

Methylglyoerol 

Methyl hexanoate (Methyl caproate) 

5-Methyl-2-hexanone (Methyl isoamyl ketone) 

2,2'-(Methylimino)diethanol (Methyl diethanolamine) 

Methyl isocyanate 

2-Methyllactonitrile (Acetone cyanohydrin) 

Methylmagnesium bromide 

Methylmagnesium chloride 

Methyl methacrylate, monomer 

2-Msthyl-2-nitro-l,3-propanediol 

2-lfethyl-2-nltro-l-propanol 

2-Methyl-2,4-pentanediol (Hexylene glycol) 

«<i-Methyl-2-pentanone (Methyl isobutyl ketone) 

4-Methyl-2-pentanone oxime (Msthylisobutyl ketoxime) 

'i-Msthyl-3-penten-2-one (Sfcsityl oxide) 

4-Methyl-2-pentyl acetate 

Methylpolyethanolamine 



DUP. 






DUP. 






m, PAS. 






DOW, JCC, 


OMC, 


UCC. 


DOW, JCC, 


OMC, 


UCC. 


DOW, OMC, 


UCC. 




ucc. 






EKT, WYN. 






SHC. 






SHC. 






JCC, UCC. 






DOW, SHC. 






ACY. 






DOW. 






DOW. 






DUP, EKT. 






RBC. 






BOR, EK, 


GRD, 


SRC, UCC 


EKT, UCC. 






CEL, DEC, 


RH. 




CEL. 






TNA. 






UCC. 






CAL, MHI, 


SFA. 




AIR. 






mp. 






CTN, FMP. 






KF. 






EKT. 






KF, PD. 






CRZ. 






ACY. 






ARC. 






COM, DUP. 






BKL. 






DUP. 






DUP. 






APD. 






FOR. 






EKT, UCC. 






DOW, UCC. 






ore. 






RH, X. 






ARA. 






ARA. 






DUP, RH, 


USP. 




COM. 






COM. 






EKT, SHC, 


UCC. 




EKT, ENJ, 


SHC, 


UCC. 


ALB. 






SHC, UCC. 






PUB, SHC, 


UCC. 





MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 



199 



TABLE 21B.- 



■ Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1963 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



mSCELLANEOUS CHEMICAI£, ACYCLIC—Continued 

2-Methyl-2 -propyl -1,3-propanediol 

Methylpseudoionone 

Methyl sulfate (Dimethyl sulfate) 

Methyl sulfide (Dimethyl sulfide) 

Ifcthyl sulfone 

Methyl sulfoxide (Dimethyl sulfoxide) 

N-Methyltaurine 

2-J*thylvaleraldehyde (2-Methylpentaldehyde) 

2-Methylvaleric acid 

Methyl vinyl ether 

Mucochloric acid (2,3-Dichloro-3-formylaorylio acid)' 

K^istoyl chloride 

Naringin 

Nitriminobispropionic acid 

2-Nitro-l-butanol 

Nitroethane 

Nitromethane 

1-Nitropropane 

2-Nitropropane 

Nonanoic acid (Pelargonlc acid) 

Nonenylsuccinio anhydride-- 

Nylon 

1-Octadeoene 

Octadecyl isocyanate 

Octadecyl vinyl ether 

1-Octanethiol (n-Octyl mercaptan) 

Octanoic acid (Caprylic acid) 

Octanoic acid (Caprylic acid) salts: 

Aluminum octanoate ' 

Barium octanoate 

Cadmium octanoate 

Zinc octanoate 

2-Octanone (Hexyl methyl ketone) 

Octanoyl chloride 

1-Octene 

l-(and 2-)0ctene 

2-Octene 

Ootenylsuocinic anhydride 

Octyltins 

Oleamide (Octadecene amide) 

*01eic acid salts: 

Aluminum oleate 

Ammonium oleate 

Barium zinc oleate 

Copper oleate 

Lead oleate 

Stannous oleate 

Oleonltrile 

Oleoyl chloride 

Oleylpalmltamide 

«-Oxalic acid 

»Oxalic acid salts: 

Ammonium oxalate 

Calcium Oxalate 

Ferric ammonium oxalate 

Ferric oxalate 

Ferric sodium oxalate 

Potassium blnoxalate 



ICO. 

GIV. 

DOT. 

CRZ, PAS. 

CRZ. 

CRZ. 

G. 

UCC. 

UCC. 

G. 

EK. 

BC, G. 

SKG. 

ACY. 

COM. 

COM. 

COM. 

COM. 

COM. 

am. 

HMY. 

CS, DUP. 

HMY. 

CWN, MOB. 

G. 

PAS. 

FOR. 

NOP. 

CCW. 

CCW. 

BKC. 

EKT, RH, TBK, WTH. 

HK, TBK. 

ADM, mi. 

WTH. 
HMY. 
HMY. 

X. 

a™, arc, fin, hum. 



MAL, 
BCN. 
HSH, 
SHP, 
SHP, 
CCW, 
ARC, 
DEP, 
FIN. 
ACG, 



WTC. 

WTC. 
■WTC. 
WTC. 

X. 

FOR, GNM. 



HK, MAL, PFZ, VIC. 



ACG, BKC, PFZ. 

VIC. 

PFZ. 

PFZ. 

PFZ. 

BKC. 



200 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

•Oxalic acid salts — Continued 

Potassium oxalate 

Sodium binoxalate 

Sodium oxalate 

Oxidized hydrocarbon mixtures, other than lubricating oil 
additives. 
•Palmitic acid salts: 

Aluminum palmitate 

Zinc palmitate 

*Palmltoyl chloride 

Paraformaldehyde 

Paraldehyde (Paracetaldehyde) 

*Pentaerythritol 

Pentaerythritol, di- and tri- 

Pentaerythrltol pelargonate 

•Pentaerythritol tetranltrate 

2,'i-Pentanedione (Acetylaoetone) 

2,4-Pentanedione, metallic complexes: 

Ferric 

Other 

2-Pentanone (Methyl propyl ketone) 

3-Pentanone (Diethyl ketone) 

Pentyl nitrate (Amyl nitrate) 

Perchloromethanethiol ( Perchloromethyl mercaptan) 

Peroxyacetlo acid 

•Phosgene (Carbonyl chloride) 

•Phosphorus acid esters, not elsewhere specified {See also 
Plastloizers, Surface-Active Agents, Pesticides, Flo- 
tation reagents, and Lubricating oil additives ) : 

Bis(2-chloroethyl) vlnylphosphonate 

Bls(2-ethylhexyl) hydrogen phosphate 

Bis(2-ethylhexyl) hydrogen phosphite 

Butyl phosphates (mono and di) 

Chloropropyl phosphorothloate 

Dlbutyl butylphosphonate 

Didodecyl hydrogen phosphate 

Diethyl hydrogen phosphite 

Dimethyl hydrogen phosphite 

Dimethyl methylphosphonate 

Dlootyl hydrogen phosphite 

Dodeoyl phosphates (mono) 

2-Ethylhexyl phosphates (mono and di) 

Ethyl phosphates (mono and di) 

Iso-ootyl hydrogen phosphate 

Isopentyl octyl hydrogen phosphate 

Methyl phosphates (mono and di) 

Octyl phosphates (mono and di) 

Pentyl phosphates (Mono and diamyl phosphates) 

•Tributyl phosphate 

Tri-n-butyl phosphorotrithioate 

Tridecyl phosphite 

Triethyl phosphite 

Triiso-octyl phosphite 

Trimethyl phosphite 

Trls(2-chloroethyl) phosphate 

Tris(2-chloroethyl) phosphite 

Tris(2,3-dibromopropyl) phosphate 

Tris(2-ethylhexyl) phosphite 

All other 



ACQ, BKC, PFZ. 




VIC. 




ACQ, BKC, MAL, 


VIC. 


ALX. 




NOP, WTC. 




ACY, NOP, WTC. 




G, HAL, TBK. 




CEL, HN. 




UCC. 




COM, DCI, HN, 


HPC, RCI, TRJ 


HPC. 




DRW. 




APD, DUP, HPC, 


TRJ. 


UCC. 




MAK. 




MAK. 




UCC. 




UCC. 




TNA. 




CHO. 




FMB. 




CTN, DUP, MOB, 


NAC, PPG, SF 


VIC. 




UCC, vc. 




vc. 




vc, VIC. 




TNA. 




VC. 




DUP. 




VC. 




VC. 




VC. 




HK. 




VIC. 




VIC. 




VC, VIC. 




VC. 




VC. 




HK, VC, VIC. 




DUP. 




VIC. 




CEL, COl, FMP. 




X, 




HK. 




VC. 




VC. 




TNA, VC. 




CEL, ENJ. 




VC. 




DUP, MCH. 




HK, VC. 




DUP, ENJ, MON, 


VC. 



MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 



201 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1963 — Continued 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Pine oil, synthetic 

Polyaorylamide 

Polyacrylio acid 

»Polyacryllc acid salts: 

Ammonium polyaorylate 

Sodium polyacrylate 

All other 

Polyacrylonitrile 

Polyethoxyethylglycerol 

Polyethoxyethylsorbitol 

^Polyethylene glycol 

Polyethylene glycol dimethaorylate 

Polyethylene oxide 

Polyethylene polysulfide 

Polygalacturonic acid 

Polyglycerol 

Polyglycols, ethylene glycol and glycol ethers, mixtures 

Polymethacrylic acid esters 

Polymethacrylic acid, sodium salt 

»Polypropoxy ethers : 

^Glycerol tri(polyoxypropylene) ether 

Polypropoxysorbitol 

l,2,3-Tri(polypropoxypropyl)hexane 

Tri(polypropoxy) sorbitol 

Other 

"Polypropylene glycol 

Polytetramethylene glycol ether 

Potassium methylate 

Propanedithiol 

Propanone peroxide (Acetone peroxide) 

Fropionaldehyde 

♦Propionic acid 

Propionic acid salts: 

Oalcium propionate 

»Sodium propionate 

Zinc propionate 

Propionic anhydride 

Propionyl chloride 

Propionyl peroxide 

Propyl acetate 

Propylene carbonate 

"Propylene glycol (1,2 -Propanediol) 

"Propylene oxide 

n- Propyl isocyanate ■ 

Propyl 4-methylvalerate (Propyl Isocaproate) 

2 -Propyl valeric acid ( Di-n-propylacetic acid) 

Propyne (Methylacetylene) 

Pseudolonone 

Pyruvaldehyde 

Quaternary ainmonium compounds (butyl and lower) 

Rare sugars 

Rlcinolamide 

Riclnoleic acid salts: 

Calcium rlcinoleate 

Lithium rlcinoleate 

"Sarcosine ( N-Msthylaminoaoetic acid) 

"Sarcosine, sodium salt 

Sebacic acid 



Manufacturers' identification codes 
(according to list in table 22) 



CBY. 
ACY. 

BFG, NOP, RH. 



BFG. 
BFG, 
ALC, 
DUP. 
GLY. 
APD, 
ACN, 
SAR. 
UCC. 
BFG. 
SKG. 
DRW, 
DOW. 
DUP. 
GRD. 



JOR, RH. 
BFG. 



GLY, TCH. 

DOW, G, JCC, OMC, UCC, WYN. 



JCC, 


OMC, 


UCC, 


WYN. 






APD. 












UCC. 












JCC, 


UCC. 










ACS, 


DOW, 


WYN. 








DOW, 


JCC, 


OMC, 


UCC, 


VIS, 


WYN. 


X. 












RBC. 












RBC. 












SDH. 












EKX, 


UCC. 










CEL, 


COM, 


DUP, 


EKT, 


UCC. 




CEL, 


CPR, 


DUP, 


HFT, 


ISC, 


UCC, WSN 


CEL, 


CPR, 


DUP, 


ISC, 


UCC, 


WSN. 


BKC. 












CEL, 


EKT, 


UCC. 








ABB, 


ICO, 


TBK. 








WTL. 












CEL, 


EN J, 


PUB. 


UCC. 






DOW, 


JCC. 










APD, 


CEL, 


TOW, 


DUP, 


JCC, 


OMC, UCC 


CEL, 


DOW, 


JCC, 


OMC, 


UCC, 


WYN. 


CWN, 


ore. 










COM. 












BPC. 












AIR. 












GIV. 












UCC. 












EK, 


asA. 










PFN. 












TKL. 












BAC. 












BAC. 












ATL, 


G, HMP, VPC. 






GGY. 












WTH, 


X. 











202 



SYNTHETIC ORGANIC CHEMICALS 1963 



TABLE 21B. 



• Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 7 565- -Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

Sebaooyl chloride 

Semicarbazide base and hydrochloride 

Seinioxamazide 

»Sequestering agents: 

N,N-Bis(2-hydroxyethyl)glycine, sodium salt 

(Diethylenetrinitrilo)pentaacetic acid 

(Diethylenetrinitrilo)pentaacetio acid, monosodium 
hydrogen ferric salt. 

»(Diethylenetrinitrilo)pentaaoetio aold, sodium salt 

N,N-Dihydroxyethylglyoine, sodium salt 

*(Ethylenedinitrilo)tetraacetic acid (Ethylenediamine- 
tetraacetic acid) . 
(Ethylenedinitrilo)tetraacetic acid, dihydrogen, 
disodium salt. 

(Ethylenedinitrilo)tetraacetic acid, dipotasslum salt 

(Ethylenedinitrilo)tetraaoetic acid, disodium calcium 

salt. 
(Ethylenedinitrilo)tetraacetic acid, disodium zinc salt, 
dihydrate . 

(Ethylenedinitrilo)tetraacetic aold, manganese salt 

(Ethylenedinitrilo)tetraacetio acid, monohydrogen 
trisodium salt. 
*(Ethylenedinltrilo)tetraaoetic acid, monosodium iron 
salt. 
(Ethylenedinitrilo)tetraaoetic acid, tetraammonium salt- 
(Ethylenedinitrllo)tetraacetic acid, tetrapotassium salt 

»(Ethylenedinitrilo)tetraacetic acid, tetrasodium salt 

Glucoheptonic acid, sodium salt 

Hexahydroxyheptanoic acid, sodium salt 

»(N-Hydroxyethylethylenedinitrilo)triacetic acid, 
trisodium salt. 
(N-Hydroxyethylethylenedinltrilo)triacetic acid, other 
salts. 

Nitrilotriacetic acid, trisodium salt 

Sodium salts of sugar acids 

Silicones 

Sodium ethoxide 

Sodium ethyl oxalacetate 

Sodium formaldehydebisulfite 

*Sodi\mi formaldehydesulfoxylate 

»Sodium methoxide (Sodium methylate) 

Sodium polypectate 

Sodium sorbitol borate 

Sorbaldehyde (Hexadienal) 

Sorbic acid (2,4-Hexadienoic acid), and potassium and 
sodium salts. 

Sorbitol 

Stearamide (Octadeoane amide) 

■^Stearic acid salts: 
»Aluminum stearates: 

^Aluminum monostearate 

•Aluminum distearate 

•Aluminum tristearate 

Ammonium stearate 

Barium stearate 

Cadmium stearate 

•Calcium stearate 

Cobalt stearate 



EK, TBK. 

FMT. 

NOR. 

DOW, HKD, M3A, RKD. 

HMP. 

GGY. 

DOW, GGY, HMP, tJDA, RFC, TCC. 
DOW, HMP, MOA, RKD. 
DOW, GGY, HMP, MOA, VIC. 

DOW, EK, GGY, HMP. 

EK. 
DOW. 



GGY. 
GGY, HMP. 



DOW, GGY, HMP. 



DOW. 
GGY. 



ACY, DOW, GGY, HMP, HRT, UDk, NOP, RKD, RPC, TCC. 

RFC. 

PCW. 

DOW, GGY, HMP, MOA, RKD, RPC, TCC. 



GGY, 


HMP 








HMP. 










PFN. 










DCC, 


ORO 








FMP. 










FMP. 










EK, 


IDC. 








NOP, 


RH, 


ROY. 






HSH, 


KF, 


OMD, 


RBC, 


SFA, X 


SKG. 










APD. 










UCC. 










UCC. 










APD, 


MRK 








ADM, 


DUP 


FIN 


HUM 





MAL, MCO, NOP, SYP. 

ACY, JTC, MAL, MCO, NOP, PRP, SYP, WTC. 

ACY, MAL, WO, NOP, PRP, SYP, WTC. 

DEX, FRH, NOP, WTC. 

MCO, NOP, PRP, SYP, WTC. 

NOP, SYP, WTC. 

ACY, HNX, JTC, LEF, MAL, MCO, NOP, PRP, SYP, WTC. 

WTC. 



MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS 



20: 



TABLE 21B. 



■ Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 7965 --Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELIANEOUS CHEMICAI£, ACYCLIC— Continued 

^Stearic acid salts--Continued 

Copper stearate 

Ferric and ferrous stearates 

»Lead stearate 

Lead stearate, dibasic 

«Lithium siearate 

^Magnesium stearate 

Manganese stearate 

Nickel stearate 

»Zino stearate 

All other 

Stearonitrile (Ootadecanenitrile) 

Stearoyl chloride 

Stearyl-2-lactic acid 

Succinic acid 

Succinic acid, sodium salt 

Succinic anhydride 

Succinimide 

Succinonitrile 

Succinyl peroxide 

Sucrose octa-acetate 

Tallow amide, hydrogenated 

Tallow nitrile 

Tallow nitrile, hydrogenated 

Tartaric acid salts, nonmedicinal 

Tetrabutylphosphonium hydroxide 

n-Tetradecane 

1,1,3,3-Tetraethoxypropane 

Tetra(2-ethylbutyl) ortho-silicate 

Tetraethylene glycol 

Tetraethylene glycol dimethacrylate 

Tetraethyllead 

Tetraf attytetramide of triethylenetetramine 

2,2,3,3-Tetrafluoro-l-propyl acetate 

Tetrahydroxysuccinic acid (Dioxytartaric acid) 

Tetrakis(hydroxymethyl)phosphoniuin chloride 

N,N,N',N'-Tetra}d.s(2-hydroxypropyl)ethylenediamlne-- 

1,1,3,3-Tetraniethoxypropane 

Tetramethyl(and etliyljlead 

Tetramethylguanidine 

Tetramethyllead 

Tetraoctyl orthosilicate 

Thioacetamide 

2,2'-Thiodiethanol (Thiodiethylene glycol) 

3,3'-Thiodipropionic acid 

3,3'-Thiodipropionltrile 

Titanic acid esters 

Triacetoxyvinylsilane 

Triallyl cyanurate 

Trichloroacetic acid 

Trichloroacetyl chloride 

Trichloroethylsilane (Ethyl silicone trichloride) — 

Trichloromethylsilane 

Trichloropentylsilane 

Trichloropropylsilane 

Trichlorovinylsilane 

Triethoxyethylsilane 



MCO. 

WTC. 

HSH, LEF, NOP, NTL, VflC. 

MCO, NTL, WTC. 

FTE, LEF, NOP, PRP, SYP, WTC. 

ACY, LEF, MAL, MCO, NOP, PRP, SYP, WTC. . 

MCO, WTC. 

WTC. 

ACY, BCN, CCA, HNX, JTC, LEF, MAL, MCO, NOP, PRP, SYP, 

WTC. 
APD. 
FOR. 
a, TBK. 

X. 

BKC, CS, NAC. 

MAL. 

NAC. 

NAC. 

ACY, RSA. 

WTL. 

UCC. 

ADM, ARC, HUM. 

FOR, GNM. 

FOR. 

BKC, PFZ. 

RSA. 

HMY. 

KF. 

UCC. 

DOW, JCC, UCC. 

SAR. 

DUP, HCH, TNA. 

DCH. 

DUP. 

ACY. 

HK. 

WYN. 

KF. 

DUP. 

ACY. 

DUP, TNA. 

M3N. 

BKC. 

UCC. 

CCW, EVN. 

ACY, HAB. 

DUP. 

DCC. 

ACY. 

DOW. 

EK. 

UCS. 

DCC. 

UCS. 

DCC. 

DCC, UCS. 

UCS. 



204 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 21B. 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer , J 565 --Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAIS, ACYCLIC— Continued 

Triethoxyvinylsilane 

Triethyl acetylcltrate 

Triethylaliiniinum 

*Triethylene glycol 

Trlethylene glycol dimethacrylate 

Triethyl orthoacetate 

Triethyl orthoformate 

Triethyl orthopropionate 

Trlf luoroacetic anhydride 

Triisobutylaluminuin 

Triisodecyl orthoformate 

Trimethylaluminum 

2,6,8-Triniethyl-4-nonanone 

Trimethyl orthoformate 

2,2,'4-Trimethyl-l,3-pentanediol 

2,2,'i-Trlinethyl-l,3-pentanediol monoisobutyrate 

Trimethylpentanol 

Tripropylalumlnum 

Trlpropylene glycol 

2-Undecanone 

Undecenolo acid (Undecylenic acid) 

Undecenoio acid salts: 

Calcliim undecenoate 

Sodium undecenoate 

Zinc undecenoate 

»Urea in compounds or mixtures, IOO56: 

»In feed compounds 

*In liquid fertilizer 

»In solid fertilizer 

In plastics 

All other 

Urea peroxide 

Urea urethane copolymer 

Valeraldehyde 

Valeric acid 

*Vinyl acetate, monomer 

Zinc formaldehydesulfoxylate 



UCS. 

PFZ. 

TNA. 

ACN, CAU, DOW, G, HCH, JCC, OMC, UCC. 

SAR. 

KF. 

KF. 

KF. 

EK. 

TNA. 

KF. 

TNA. 

UCC. 

KF. 

EKX. 

EKX. 

EKX. 

TKA. 

DOW, UCC. 

TBK. 

BAC. 

WTL. 
BAC. 
BAC, TNC, WTL. 



ACN, 
ACN, 
NI 
ACN, 
DUP, 
ACN, 
FMB. 
DUP. 
UCC. 
UCC. 
AIR, 
NOP, 



DUP, GCC, JDC, MON, MSC, SHC, SDH. 
ARM, CFA, DUP, ESC, FCA, GCC, HPC, JDC, MON, MSC, 
T, SHC, SNI, SOH, SPN. 
DUP, GCC, HPC, JDC, MON, MSC, SHC, SNO, SOH, SPN. 
MON. 
DUP, MON, MSC, SOH. 



BOR, CEL, DUP, MON, NSC, UCC. 
ROY. 



DIRECTORY OF MANUFACTURERS 



205 



Directory of Manufacturers 

The Directory of Manufacturers lists the companies that report their production of synthetic 
organic chemicals to the U.S. Tariff Commission, The nanne of each manufacturer is preceded 
by an alphabetical identification symbol. These identification symbols consist of not more than 
three capital letters, and usually bear a relation to the company name. 

For 1963, the Directory of Manufacturers lists 783 primary manufacturers (see table 22). 
Some of the companies that report production of synthetic organic chemicals do not sell the ma- 
terials, but consume their entire output in further manufacturing. 

The Directory of Manufacturers lists the reporting companies in two ways: Section 1 lists 
them in alphabetical order by identification symbols; section 2 lists the reporting companies 
in alphabetical order by company name, and gives the corresponding identification symbol and 
the company address. Company divisions are usually listed under the parent company's name. 



TABLE 22. — Synthetic organic chemicals : Directory of manufacturers, 1963 

SECTION 1. ALPHABETICAL DIRECTORY BY CODE 

[Names of synthetic organic chemical mamifacturers that reported production or sales to the U.S. Tariff Commission 
for 1963 are listed below in the order of their identification codes as used in tables in pt. III. See. 2 of this 
table lists these manufacturers alphabetically and gives their office address] 



Code 


Name of company 


Code 


Name of confiany 


AAC 


Alcolac Chemical Corp. 


ARA 


Arapahoe Chemicals, Inc. 




AAE 


American Aniline & Extract Co., Inc. 


ARC 


Armour & Co., Armour Industrial Chemical Co. 


Div. 


AAI 


American Alkyd Industries . 


ARD 


Ardmore Chemical Co. 




AAP 


American Aniline Products, Inc. 


ARC 


Argus Chemical Corp. 




ABB 


Abbott Laboratories 


ARK 


Armstrong Cork Co. 




ABR 


Andrew Brown Co. 


ARL 


Arol Chemical Products Co. 




ABS 


American Brake Shoe Co., American Brakeblok 


ARM 


Armour Agricultural Chemical Co. 






Div. 


ARO 


Mobil Finishes Co., Inc., Arco Div. 




ACB 


Allied Chemical Corp., Barrett Div. 


ARF 


Armour Pharmaceutical Co. 




ACC 


Amoco Chemical Corp. 


ASH 


Ashland Oil & Refining Co. 




ACG 


Allied Chemical Corp., General Chemical Div. 


ASL 


Ansul Chemical Co. 




ACN 


Allied Chemical Corp., Nitrogen Div. 


AST 


Astra Pharmaceutical Products, Inc. 




ACO 


Acralite Co., Inc. 


ASY 


American Synthetic Rubber Corp. 




ACP 


Allied Chemical Corp., Plastics Div. 


ATL 


Atlantic Chemical Corp. 




ACR 


Acme Resin Corp. 


ATR 


Atlantic Refining Co. 




ACS 


Allied Chemical Corp., Solvay Process Div. ' 


ATU 


Atlantic Tubing & Rubber Co. 




ACT 


Arthur C. Trask Co. ] 


AUG 


Augusta Chemical Co. 




ACY 


American Cyanamid Co. 


AV 


FMC Corp., American Viscose Div. 




ADC 


Ad-Co Color Corp. 


AVS 


Avisun Corp. 




ADM 


Archer-Daniels-Midland Co. 








AIR 


Air Reduction Co., Inc., Air Reduction Chemical 


BAC 


Baker Castor Oil Co. 






& Carbide Co. Div. 


BAL 


Baltimore Paint Sc Chemical Corp. 




ALB 


Ames Laboratories, Inc. } 


BAO 


Bayoil Co., Inc. 




ALC 


Alco Chemical Corp. 1 


BAT 


Bates Chemical Co. 




ALD 


Aldrioh Chemical Co., Inc. 


BAX 


Baxter Laboratories, Inc. 




ALF 


Allied Chemical Corp., Fibers Div. 


BC 


Barlow Chemical Corp. 




ALL 


Alliance Color & Chemical Co. 


BCC 


Bercen Chemical Co., Inc. 




ALT 


Crompton & Knowles Corp. , Althouse Chemical Co. 


BCM 


Belding Chemical Industries 






Div. 


BCN 


Beacon Chemical Industries, Inc. 




ALX 


Alox Corp. 


BEN 


Bennett 's 




AMB 


American Bio-Synthetics Corp. 


BFG 


B. F. Goodrich Co., B. F. Goodrich Chemical 


Co. Div. 


AMC 


Amchem Products, Inc. 


BFR 


Branchflower Co. 




AME 


American Chemical Corp. 


BGC 


Balfour Chemicals, Inc. 




AMF 


Mobil Finishes Co., Inc., Ferbert-Sohomdorfer 


BJL 


Burdick & Jackson Laboratories, Inc. 






Div. 


BKC 


J. T. Baker Chemical Co. 




AML 


Amalgamated Chemical Corp. 


BKL 


Millmaster Chemical Corp., Berkeley Chemical 


Dept. 


AMD 


American Oil Co. (Texas) 


BKM 


Buckman Laboratories, Inc. 




AMP 


American Potash & Chemical Corp. 


BKS 


Berkshire Color & Chemical Co. 




AMR 


Pacific Resins & Chemical Co. 


BKT 


J. T. Baker Chemical Co., Taylor Div. 




AMS 


Martin-Marietta Corp., Rldgway Color & Chemical 


BL 


Belle Chemical Co., Inc. 






Div. 


BLA 


Blue Arrow, Inc. 




AMZ 


American Maize Products Co. 


BLN 


Brooklyn Color Works, Inc. 




ANM 


Ancon Chemical Co. 


BLS 


Beech-Nut Life Savers, Inc. 




APC 


Appleton Coated Paper Co. 


BME 


Bendix Corp., Marshall-Eclipse Div. 




APD 


Atlas Chemical Industries, Inc., Chemicals Div. 


BOR 


Borden Co., Borden Chemical Co. Div. 




APR 


Atlas Processing Co. 


BOY 


Walter N. Boysen Co. 




APT 


American Petrochemical Corp. 


BPC 


Benzol Products Co. 




APV 


Armstrong Paint & Varnish Works, Inc. 


BPL 


Brand Plastics Co. 




APX 


Apex Chemical Co., Inc. 


BRD 


Baird Chemical Industries, Inc. 





206 SYNTHETIC ORGANIC CHEMICALS, 1963 

TABLE 22.-- Synthetic organic chemicals: Directory of manufacturers , 7963--Continued 



Name of conrpany 



Name of company 



Raymond Chemical Co. 

Bristol-Meyers Co., Bristol Laboratories Div. 

M. A. Bruder & Sons, Inc. 

Bryant Chemical Corp. 

Burkart-Schier Chemical Co. 

Original Bradford Soap Works, Inc. 

Blackman-Uhler Chemical Co. 

Buckeye Cellulose Corp. 

Burroughs-Wellcome & Co. (U.S.A.), Inc. 

J. H. Baxter & Co. 

Bzura Chemical Co., Inc. 

Cadet Chemical Corp. 

Callery Chemical Co. 

Cap-Roc, Inc., Capital Plastics Div. 

Catalin Corp. of America 

Calcasieu Chemical Corp. 

Ciba Corp., Ciba Products Co. Div. 

Georgia-Pacific Corp., Coos Bay Div. 

Columbian Carbon Co., Pigments & Elastomers 

Div. 
Ciba Corp., Ciba Pharmaceutical Co. Div. 
Colab Resin Corp. 
Samuel Cabot, Inc. 
Crosby Chemicals, Inc. 

Carlisle Chemical Works, Inc., Advance Div. 
Chase Chemical Corp. 
Pearsall Chemical Co. 
Charlotte Chemical Laboratories 
Chemico, Inc. 

Crown Central Petroleum Corp. 
Carlisle Chemical Works, Inc. 
Budd Co., Polychem Div. 
Celanese Corp. of America: 

Celanese Chemical Co. Div. 

Celanese Plastics Co. Div. 

Celanese Polymer Co. Div. 
Chemirad Corp. 

Cooperative Farm Chemicals Association 
Rexall Chemical Co. - Kearny 
Chemfax, Inc. 
Cargill, Inc. 

Chipman Chemical Co., Inc. 
Chemagro Corp. 
Chemol, Inc. 
Chapman Chemical Co. 

Stauffer Chemical Co., Calhio Chemicals Div. 
California Ink Co., Inc. 
Cindet Chemicals, Inc. 
Chemical Insecticide Corp. 
Chemlek Laboratories, Inc. 
Columbia Organic Chemicals Co., Inc. 
Colloids, Inc. 
Clintwood Chemical Co. 
Standard Brands, Inc., Clinton Com Processing 

Co. Div. 
Clover Chemical Co. 
W. A. Cleary Corp. 
Carpenter-Morton Co. 
Chemical Manufacturing Co., Inc. 
Continental Oil Co. 
Cockerllle Chemicals, Inc. 
Collier Carbon & Chemical Corp. 
Commercial Solvents Corp. 
Concord Chemical Co., Inc. 
Coopers Creek Chemical Corp. 
Commonwealth Oil Refining Co., Inc. 
Coastwise Petroleum Co. 
Colgate-Palmolive Co. 
Childs Pulp Colors, Inc. 
Chemical Products Corp. 
Reliance Varnish Co., Coast Paint & Lacquer 

Co. Div. 



CPR 

CPT 

CPV 

CPY 

CRC 

CRN 

CRS 

CRY 

CRZ 

CS 

CSD 

CSO 

CST 

CTA 

CTL 

CTN 

cue 

CUT 

CW 

CWL 

CWN 

CWP 

DA 

DAN 

DAV 

DBC 

DCG 

DCH 

DCI 

DEG 

DEP 

DEX 

DLH 

DLI 

DOD 

DOM 

DOW 

DPP 

DRL 

DRW 

DSC 

DSO 

DUN 

DUP 

DUR 

DVC 

DXS 

EAK 

EDY 

EFH 

EK 

EKT 

EKX 

ELP 

EMK 

EMR 

EN 

ENJ 

EPC 
ERD 
ESC 
ETD 
EVM 
EVN 



FAB 
FAR 
FB 



Certified Proteins Corp. 
Consolidated Paint Co. 
Cook Paint & Varnish Co. 
Copolymer Rubber & Chemical Corp. 
Crown Chemical Corp. 
Corn Products Co. 
Carus Chemical Co., Inc. 
Cary Chemicals, Inc. 

Crown Zellerbach Corp., Chemical Products Div. 
Chemstrand Corp. 
Cosden Oil 8: Chemical Co. 
Cities Service Oil Co. 
Charles S. Tanner Co. 
Conestoga Chemical Corp. 
Continental Chemical Co. 

Chemetron Corp., Chemetron Chemicals, Organic Chemi- 
cal Dept. 
Cumberland Chemical Corp. 
Cutter Laboratories, Inc. 
Collett-Week Corp. 
Cowles Chemical Co. 
Upjohn Co., Carwin Co. Div. 
Consolidated Papers, Inc. 

Diamond Alkali Co., and Western Div. 

Dan River Mills, Inc. 

Conchemco, Inc., H. B. Davis Co. Div. 

Dow Badische Chemical Co. 

Dow Coming Corp. 

Dearborn Chemical Co. 

Delaware Chemicals, Inc. 

Degen Oil & Chemical Co. 

DePaul Chemical Co., Inc. 

Dexter Chemical Corp. 

Hess Oil & Chemical Corp. 

Dawe's Laboratories, Inc. 

Donald A. Dodd 

Dcminion Products, Inc. 

Dow Chemical Co. 

Dixie Pine Products Co., Inc. 

Caradco, Inc., Durel Div. 

Drew Chemical Corp. 

Dye Specialties, Inc. 

DeSoto Chemical Coatings, Inc. 

Frank W. Dunne Co. 

E . I . duPont de Nemoiirs & Co . , Inc . 

Duraphene Corp. 

Dover Chemical Co. 

Sunray DX Oil Co. 

J. S. & W. R. Eakins, Inc. 

Eddystone Manufacturing Co. 

E. F. Houghton & Co. 

Eastman Kodak Co. 

Eastman Kodak Co., Tennessee Eastman Co. Div. 

Eastman Kodak Co., Texas Eastman Co. Div. 

El Paso Natural Gas Products Co. 

Emkay Chemical Co. 

Emery Industries, Inc. 

Endo Laboratories, Inc. 

Enjay Chemical Co., Div. of Humble Oil & Refining 

Co. 
Epoxylite Corp. 
Erdmann Chemical Co., Inc. 
Escambia Chemical Corp. 
Ethyl-Dow Chemical Co. 
Everledge Manufacturing, Inc. 
Evans Chemetios, Inc. 
Westinghouse Electric Corp., Micarta Div. 

Fabricolor Chemical Corp. 
Famow, Inc. 
Fritzsohe Bros., Inc. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. --Synthetic organic chemicals: Directory of manufacturers , 1963 — Continued 



207 



Code 


Name of conipany 


Code 


Name of company 


FBC 


Diamond Alkali Co., Fiber Chemical Dept. 


GTL 


Great Lakes Chemical Corp. 




FBF 


Fiberfil, Inc. 


GUA 


Guard Chemical Co., Inc. 




FBR 


Fibreboard Paper Products Corp. 


GYR 


Goodyear Tire & Rubber Co. 




FC 


Franklin Chemical Co. 








FCA 


Farmers Chemical Association, Inc. 


HAB 


Halby Products Co., Inc. 




FCD 


France, Campbell & Darling, Inc. 


HAL 


C. P. Hall Co. of Illinois 




FCL 


Federal Color Laboratories, Inc. 


HAM 


Hampden Color & Chemical Co. 




FCP 


J. P. Frank Chemical & plastic Corp. 


HAN 


Hanna Paint Manufacturing Co., Inc. 




F-EL 


Felton Chemical Co., Inc. 


HAP 


Applied Plastics Co., Inc. 




FER 


Ferro Corp., Ferro Chemical Div. 


HAR 


Allied Chemical Corp., National Aniline Div., 




FG 


Foster Grant Co., Inc. 




Harmon Color Works 




FH 


Foster-Heaton Co. 


HCC 


Holland Color & Chemical Co. 




FIN 


Fine Organics, Inc. 


HCH 


Houston Chemical Corp. 




FIR 


Firestone Tire & Rubber Co., Firestone 


HCO 


Hamilton Chemical Corp. 






Plastics Co. Div. 


HDG 


Hodag Chemical Corp. 




FLH 


H. B. Fuller Co. 


HER 


Heresite & Chemical Co. 




FLO 


Florasynth Laboratories, Inc. 


HET 


Heterochemioal Corp. 




FLW 


W. P. Fuller & Co. 


HEX 


Hexagon Laboratories, Inc. 




FUB 


FMC Corp., Inorganic Chemicals Div. 


HFT 


Hoffman-Taff, Inc. 




FMN 


FMC Corp., Niagara Chemical Div. 


HK 


Hooker Chemical Corp. 




FMO 


Fermco Laboratories, Inc. 


HKD 


Hooker Chemical Corp., Durez Plastics Div. 




FMP 


FMC Corp., Organic Chemicals Div. 


HLC 


Hartman-Leddon Co. 




FMT 


Fairmount Chemical Co., Inc. 


HLI 


Haag Laboratories, Inc. 




FMW 


FMC Corp., Chemical Div. 


HMP 


Hampshire Chemical Corp. 




FOC 


Farac Oil & Chemical Co. 


HMY 


Humphrey Chemical Co. 




FQM 


Formica Corp. 


HN 


Heyden Newport Chemical Corp. 




FOR 


Foremost Chemical Products Co. 


HNC 


H & N Chemical Co. 




FRE 


Freeman Chemical Corp. 


HNW 


Heyden Newport Chemical Corp., Newport Industries 


FRM 


Farmers' Chemical Co. 




Div. 




FRO 


Vulcan Materials Co., Frontier Chemical Co. 


HNX 


Heyden Newport Chemical Corp., Nuodex Products 


Div. 




Div. 


HOF 


Hoffmann-LaRoche, Inc. 




FRP 


Filtered Rosin Products Co. 


HOU 


Air Products & Chemicals, Inc., Houdry Process 


& 


FRR 


Estate of W. U. Farrington 




Chemical Co. Div. 




FRS 


Firestone Tire & Rubber Co., Firestone Syn- 


HPC 


Hercules Powder Co. 






thetic Rubber & Latex Co. Div. 


HRS 


Bemz-0-Matic, Harris Paint Co. Div. 




FSH 


Frisoh & Co., Inc. 


HRT 


Hart Products Corp. 




FTE 


Foote Mineral Co. 


HSH 
HST 


Harshaw Chemical Co. 
Hoeohst Chemical Corp. 




G 


General Aniline & Film Corp. 


HUM 


National Dairy Products Corp., Humko Products 




GAM 


Gamma Chemical Corp. 




Chemical Div. 




GAN 


Gane's Chemical Works, Inc. 


HUS 


Husky-Dominion Briquets 




GCC 


W. R. Grace & Co., Nitrogen Products Div. 


HVG 


Haveg Industries, Inc., Resin & Compound Div. 




GDL 


Gordon-Lacey Chemical Products Co., Inc. 


HYC 


Hysol Corp. 




GDN 


Gordon Chemicals, Inc. 


HYN 


Hynson, Westcott & Dunning, Inc. 




GE 


General Electric Co., Chemical Materials 










Dept. 


IBI 


Industrial Biochemicals 




GEI 


General Electric Co., Insulating Materials 


ICC 


Interchemioal Corp., Color & Chemicals Div. 






Dept. 


ICF 


Interchemical Corp., Finishes Div. 




GFS 


G. Frederick Smith Chemical Co. 


ICI 


I.C.I. (Organics), Inc. 




GGC 


Goodrich-Gulf Chemicals, Inc. 


ICO 


Interchemical Corp., Organic Chemicals Dept. 




GGY 


Geigy. Chemical Corp. 


IDC 


Industrial Dyestuff Co. 




GIL 


Oilman Paint & Varnish Co. 


IFF 


International Flavors & Fragrances, Inc. 




GIV 


Givaudan Corp. 


ILC 


International Latex Corp. 




GLC 


General Latex & Chemical Corp. 


IMC 


International Minerals & Chemical Corp. 




GLD 


Glidden Co. 


IMP 


Herciiles Powder Co., Ligjerial Color & Chemical 


Dept. 


GLX 


Glasflex, Inc. 


BJR 


Imperial Chemical Co., Inc. 




GLY 


Glyco Chemicals, Inc. 


IMS 


lJig5orters Service Corp. 




GNF 


General Foods Corp., Maxwell House Div. 


INL 


Inland Steel Container Co. 




GUM 


General Mills, Inc. 


INP 


International Paper Co. 




GNT 


General Tire & Rubber Co., Chemical Div. 


IOC 


Pfaudler Permutit, Inc., lonao Chemical Co. Div. 


GOC 


Gulf Oil Corp. 


IPC 


Interplastic Corp., Commercial Resins Div. 




GOH 


Gordon Chemical Co., Inc. 


IPI 


Isooyanate Products, Inc. 




GPM 


General Plastics Manufacturing Co. 


IPR 


Inter-Pacific Resins, Inc. 




GPR 


Grain Processing Corp. 


IRC 


International Resistance Co. 




GRA 


Great American Chemical Corp. 


IRI 


Ironsides Resins, Inc. 




GRD 


W. R. Grace & Co., Dewey & Almy Chemical Div. 


ISO 


Isochem Resins Co. 




ORG 


P. D. George Co. 








GHH 


W. R. Grace & Co., Hatco Chemical Div. 


JAM 


Jamestown Paint & Varnish Co. 




GRP 


W. R. Grace & Co., Polymer Chemicals Div. 


JCC 


Jefferson Chemical Co., Inc. 




GRS 


Pontiac Refining Corp. 


JDC 


John Deere Chemical Co. 




GRV 


Guardsman Chemical Coatings, Inc. 


JEN 


Jennison-Wright Corp. 




GRW 


Great Western Sugar Co. 


JMS 


J. Meyer & Sons, Inc. 




GTH 


Guth Chemical Co. 


JNS 


S. C. Johnson & Son, Inc. 





208 SYNTHETIC ORGANIC CHEMICALS, 1963 

TABLE 22. --Synthetic organic chemicals: Directory of manufacturers , 1963 — Continued 



Name of company 



Code 



Name of oon^iany 



Jones-Blair Paint Co. 

Joolin Manufacturing Co. 

Devoe & Reynolds Co., Inc., Jones-Dabney Div. 

W. H. & F. Jordan, Jr. Manufacturing Co., Inc. 

Andrew Jergens Co. 

Jersey State Chemical Co. 

Joseph Turner & Co. 

Julian Laboratories, Inc. 

Jewel Paint & Varnish Co. 

Kaiser Aluminum & Chemical Corp. 

Kali Manufacturing Co. 

Kennecott Copper Corp., Chino Mines Div. 

Keystone Chemurgic Corp. 

Kennecott Copper Corp., Utah Copper Div. 

Keystone Color Works, Inc. 

Kelly-Pickering Chemical Corp. 

Kendall Refining Co. 

Armour Industrial Chemical Co., Kessler Chemi- 
cal Div. 

Kay-Fries Chemicals, Inc. 

Kolker Chemical Corp., DBA Frontier Chemical 
Co. 

Kilsdonk Chemical Corp. 

Knoedler Chemical Co. 

Far-Best Corp., 0. L. King Div. 

Knapp Products, Inc. 

H. Kohnstaram & Co. , Inc. 

Kenrich Petrochemicals, Inc. 

Koppers Co., Inc., Plastics Div. 

Koppers Pittsburgh Co. 

Koppers Co., Inc., Tar Products Div. 

Keystone Paint & Varnish Corp. 

Lawter Chemicals, Inc., Krumbhaar Resin Div. 

Kyanize Paints, Inc. 

Keysor Chemical Co. 

Lakeway Chemical Co. 
LaMotte Chemical Products Co. 
Lasco Industries, Inc. 
Leatex Chemical Co. 
Lebanon Chemical Corp. 
Leffingwell Chemical Co. 
Lehigh Chemical Co. 

B. L. Lemke & Co., Inc. 
Leonard Refineries, Inc. 
Lever Brothers Co. 

Eli Lilly & Co. 

Lakeside Laboratories, Intf. 

St. Regis Paper Co., Lake States Yeast & 

Chemical Div. 
Lawrence Mills, Inc. 
Mobil Finishes Co., Inc., American-Marietta 

Paint Div. 
Lignin Products Co. 
Lubrizol Corp. 
George Lueders & Co. 
Laurel Soap Manufacturing Co. 

C. Lever Co., Inc. 
Fred'k H. Levey Co., Inc. 

Maher Color & Chemical Co. 

MacKenzie Chemical Works, Inc. 

Mallinckrodt Chemical Works 

American Can Co., Marathon Div. 

Otto B. May, Inc. 

Masonite Corp., Alpine Chemical Div. 

Borg-Wamer Corp., Marbon Chemical Div. 

McCloskey Varnish Co. 

Michigan Chemical Corp. 

Mathe Chemical Co. 

Medical Chemicals Corp. 

Maijmee Chemical Co. 



MER 

MET 

MFC 

MGR 

MHI 

MID 

MIR 

MLD 

MI£ 

MMM 

MNO 

MNP 

MOA 

MOB 

MOC 

MON 

MGR 

MOT 

MPL 

MPP 

MR 

MRA 

MRB 

MRD 

MRK 

MRN 

MRO 

MRT 

MRV 

MRW 

MRX 

MSC 

MTL 

MTO 

MTR 



NAC 
NCI 
NCW 
NEO 
NEP 
NES 
NEV 
NIL 
NIT 
NIX 
NOC 
NON 
NOP 
NOR 
NPI 
NPP 
NPV 
NRS 
NSC 
NSP 
NTB 
NTC 
NTL 
NVF 
NVT 



OCF 
OH 



OLH 
QMC 



Jefferson Lake Sulphur Co., Chemical Div. 

M & T Chemicals, Inc. 

Molded Fiber Glass Body Co., Resin Div. 

Magruder Color Co., Inc. 

Metal Hydrides, Inc. 

Midland Industrial Finishes Co. 

Miranol Chemical Co., Inc. 

Metalead Products Corp. 

Miles Laboratories, Inc. 

Minnesota Mining & Manufacturing Co. 

Monochem, Inc . 

Minnesota Paints, Inc. 

Mona Industries, Inc. 

Mobay Chemical Co. 

Marathon Oil Co., Texas Refining Div. 

Monsanto Co. 

Mineral Oil Refining Co. 

Motomco, Inc. 

Massachusetts Plastic Corp. 

Midwest Plastic Products Co. 

Benjamin Moore & Co. 

Metro-Atlantic, Inc. 

Marblette Corp. 

Marden-Wild Corp. 

Merck & Co., Inc. 

Momingstar Paisley, Inc. 

Marco Chemical Corp. 

Morton Salt Co., Morton Chemical Co. Div. 

Marlowe-Van Loan Corp. 

Morwear Paint Co. 

Max Marx Color & Chemical Co. 

Mississippi Chemical Corp. 

Metalsalts Corp. 

Montrose Chemical Corp. of California 

Baldwin-Montrose Chemical Co., Inc., Montrose 

Chemical Div. 
Stepan Chemical Co., Maywood Div. 

Allied Chemical Corp., National Aniline Div. 
Nelio Chemicals, Inc. 
Nostrip Chemical Works , Inc . 
Norda Essential Oil & Chemical Co., Inc. 
Nepera Chemical Co., Inc. 
Nease Chemical Co., Inc. 
Neville Chemical Co. 
Nilok Chemicals, Inc. 
Nitrin, Inc . 

Nixon-Baldwin Chemicals, Inc. 
Norac Co., Inc. 
A. P. Nonweiler Co. 
Nopco Chemical Co., Inc. 
Norwich Pharmacal Co. 
National Polychemicals, Inc. 
National Plastic Products Co., Inc. 
Norrls Paint & Varnish Co. 
Norse Chemical Corp. 
National Starch & Chemical Corp. 
Alabama Binder & Chemical Corp. 
National Biochemical Co. 
National Casein Co. 
National Lead Co. 
National Vulcanized Fibre Co. 
Novamont Corp. 
Northwestern Chemical Co. 

American Dyewood Co., Inc., New York Color & Chemi- 
cal Co. Div. 



Owens-Coming Fiberglas Corp. 

Air Reduction Co., Inc., Ohio Chemical & Surgical 

Equipment Co. Div. 
Old Hickory Chemical Co. 
Olin Mathieson Chemical Corp. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. — Synthetic organic chemicals : Directory of manufacturers , 1963 — Continued 



209 



Code 


Name of company 


Code 


Name of company 


CMS 


Olin Mathieson Chemical Corp., E. R. Squibt & 


QCP 


Quaker Chemical Products Corp. 




Sons Div. 


QKO 


Quaker Oats Co. 


ONX 


Onyx Chemical Corp. 


QUN 


K. J. Quinn & Co., Inc. 


OPC 


Orbis Products Corp. 






ORG 


Organics, Inc. 


RAB 


Raybestos-Manhattan, Inc., Raybestos Div. 


ORO 


California Chemical Co., Oronite Div. 


RBC 


Roberts Chemicals, Inc. 


ORT 


Roehr Chemicals, Inc. 


RCC 


Rexall Chemical Co. 


ORU 


Eagle-Pitcher Co., Ohio Rubber Co. Div. 


RCD 


Richardson Co., Krystall Chemical Corp. Div. 


OSB 


C. J. Osbom Co. 


RCI 


Reichhold Chemicals, Inc. 


OTA 


Ottawa Chemical Co. 


RDA 


Rhodia, Inc. 


OTC 


Ott Chemical Co. 


RED 


Red Spot Paint & Varnish Co., Inc. 


OTH 


California Chemical Co., Ortho Div. 


REH 


Armour Pharmaceutical Co., Reheis Co. Div. 


OTT 


Ottol Oil Co., Inc. 


REL 


Reliance Varnish Co. 


oxy 


Oxy Chemical Co. 


REM 


Remington Arms Co., Inc. 






RET 


Rayette, Inc. 






REZ 


Rezolin, Inc. 


PAI 


Pennsylvania Indiistrial Chemical Corp. 


RGC 


Rogers Corp. 


PAN 


Pan American Petroleum Corp. 


RH 


Rohm & Haas Co. 


PAR 


Pennsylvania Refining Co. 


RIC 


Richfield Oil Coi-p. 


PAS 


Pennsalt Chemicals Corp. 


RIK 


Riker Laboratories, Inc. 


PAT 


Patent Chemicals, Inc. 


RIL 


Reilly Tar & Chemical Corp. 


PBS 


Pabst Brewing Co. 


RIV 


Riverdale Chemical Co. 


PBY 


Pillsbury Co. 


RKD 


Rockland Industries 


PC 


Proctor Chemical Co., Inc. 


RMC 


Rinshed-Mason Co. 


PCC 


Pittsburgh Chemical Co. 


ROC 


Rock Hill Printing & Finishing Co. 


PCH 


Peerless Chemical Co. 


ROM 


Roma Chemical Corp. 


PCI 


Pioneer Chemical Works, Inc. 


RQS 


Rosett Chemicals, Inc. 


PCS 


Emery Industries, Inc., Western Div. 


ROY 


Royce Chemical Co. 


PCW 


Pfister Chemical Works 


RPC 


Refined Prodiicts Co. 


PD 


Parke, Davis Sc Co. 


RPI 


Rowland Products, Inc. 


PDC 


Bemcolors-Poughkeepsie, Inc. 


RSA 


R. S. A. Corp. 


PDJ 


Joseph Davis Plastics Co. 


fiSB 


Rosenberg Bros. & Co. 


PEK 


Peck's Products Co. 


RT 


F. Ritter & Co. 


PEL 


Pelron Corp. 


RTC 


Ritter Chemical Co., Inc. 


PEN 


S. B. Penick & Co. 


RTF 


Retzloff Chemical Co. 


PER 


Perry & Derrick Co. 


RUB 


Rubber Corp. of America 


PET 


Petroleum Chemicals, Inc. 


RUR 


Ruberoid Co. 


PFN 


Pfanstiehl Laboratories, Inc. 


R2L 


Rozilda Laboratories, Inc. 


PF? 


Phelan- Faust Paint Manufacturing Co. 






PFZ 


Chas. Pfizer & Co., Inc. 


S 


Sandoz, Inc. 


PC 


Procter & Gamble Co., Procter & Gamble Manu- 


SAL 


Dr. Salsbury's Laboratories 




facturing Co. Div. 


SAR 


Sartomer Resins, Inc. 


PGU 


Perkins Glue Go. 


SBC 


Scher Bros. 


PHR 


Pharmachem Corp. 


SBR 


Schwarz Bioresearch, Inc. 


PIC 


Pierce Chemical Co. 


see 


Standard Chlorine Chemical Co., Inc. 


PII 


Polymer Industries, Inc. 


SCF 


Schaefer Varnish Co., Inc. 


PIL 


Pilot Chemical Co. 


SCH 


Schering Corp. 


PIT 


Pitt-Consol Chemical Co. 


SCI 


Stecker Chemicals, Inc. 


PLA 


Richardson Co., Richardson Polymers Div. 


SCL 


Schuylkill Chemical Co. 


PLC 


Phillips Petroleum Co. 


SCN 


Schenectady Chemicals, Inc. 


PLP 


Phillips Petroleum Co., Chemical Dept. 


SCO 


Scholler Bros . , Inc . 


PLS 


Plastics Engineering Co. 


SCP 


Standard Chemical Products, Inc. 


PLU 


Plumb Chemical Corp. 


SCR 


R. P. Soberer Corp. 


FMP 


Plastics Material & Polymers, Inc. 


SDC 


Martin-Marietta Corp., Southern Dyestuff Co. Div. 


PNT 


Pantasote Co. 


SDG 


Sterling Drug, Inc., Glenbrook Laboratories Div. 


PNX 


Phoenix Oil Co. 


SDH 


Sterling Drug, Inc., Hilton-Davis Chemical Co. Div. 


POL 


Polymer Corp. 


SDW 


Sterling Drug, Inc., Winthrop Laboratories Div. 


PPG 


Pittsburgh Plate Glass Co. 


SEA 


Seaboard Chemicals, Inc. 


PRC 


Psiragon Chemicals 


SED 


Seidlitz Paint & Varnish Co. 


PRD 


Productol Chemical Co. 


SEY 


Seydel-Woolley & Co., Inc. 


PRO 


Pure Oil Co. 


SF 


Stauffer Chemical Co. 


PRP 


S. B. Penick & Co., Parsons-Plymouth Div. 


SFA 


Stauffer Chemical Co., Anderson Chemical Co. Div. 


PRR 


L. Perrigo Co. 


SFC 


Stahl Finish Co. 


PRT 


Pratt & Lambert, Inc. 


SH 


Stein, Hall & Co., Inc. 


PRX 


Purex Corp., Ltd. 


SHC 


Shell Oil Co., Shell Chemical Co. Div. 


PSP 


Georgia-Pacific Corp., Puget Sound Div. 


SHF 


National Dairy Products Corp., Sheffield Chemical 


PTT 


Petro-Tex Chemical Corp. 




Co. Div. 


PUB 


Publicker Industries, Inc. 


SHL 


Shulton, Inc., Fine Chemicals Div. 


FVI 


Polyvinyl Chemicals, Inc. 


SHM 


Shamrock Oil & Gas Corp. 


PYL 


Polychemical Laboratories, Inc. 


SHO 


Shell Oil Co. 


PYR 


Poly Resins 


SHP 


Shepherd Chemical Co. 


PYZ 


Polyrez Co., Inc. 


SIC 


Silmar Chemical Corp. 



210 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 22.-- Synthetic organic chemicals: Directory of manufacturers , i965--Continued 



Code 


Name of company 


Code 


Name of company 


SID 


George F. Siddall Co., Inc. 


THC 


Thompson Chemical Co. 




SIM 


Simpson Timber Co. 


TIC 


Ticonderoga Chemical Corp. 




SIN 


Sinclair Refining Co. 


TID 


Tidewater Oil Co. 




SIO 


Standard Oil Co. of Ohio 


TKL 


Thiokol Chemical Corp. 




SIP 


James B. Sipe & Co. 


TMH 


Thompson-Hayward Chemical Co. 




SK 


Smith, Kline & French Laboratories 


TMS 


Sterling Drug, Inc., Thomasset Colors Div. 




SKC 


Sinclair Koppers Chemical Co. 


TN 


Tennessee Corp. 




SKG 


SunkLst Growers, Inc. 


TNA 


Ethyl Corp. 




SKO 


Skelly Oil Co. 


TNC 


Tennant Development Corp., Chemical Div. 




SLC 


Soluol Chemical Co., Inc. 


TNP 


Velsicol Chemical Corp., Tensyn Div. 




SLV 


Sterling Drug, Inc., Salvo Chemical Div. 


TOC 


Tenneco Oil Co. 




SM 


Sooony Mobil Oil Co., Inc.: 


TRC 


Toms River Chemical Corp. 






Mobil Chemical Co. Div. 


TRJ 


Trojan Powder Co. 






Mobil Oil Co. Div. 


TRO 


Troy Chemical Co. 




SMC 


Stamford Chemical Co. 


TSA 


Texas Alky Is, Inc. 




SNA 


Ansbacher-Siegle Corp. Div. of Sun Chemical 


TTX 


Detrex Chemical Industries, Inc. 






Corp. 


TUS 


Texas-U.S. Chemical Co. 




SNC 


Sonoco Products Co. 


TV 


Tousey Varnish Co. 




SNI 


Southern Nitrogen Co., Inc. 


TX 


Texaco, Inc. 




SNO 


SunOlin Chemical Co. 


TXC 


Tex Chemical Co. 




SNT 


Suntide Refining Co. 








SNW 


Sun Chemical Corp., Warwick Chemical Co. Div. 


UBS 


A. E. Staley Manufacturing Co., UBS Chemical Co. 


SOC 


Standard Oil Co. of California, Western 




Div. 






Operations, Inc. 


UCC 


Union Carbide Corp., Chemicals Div. 




SOG 


Signal Oil Sc Gas Co., Houston Div. 


UCP 


Union Carbide Corp., Plastics Div. 




SOH 


Sohio Chemical Co., Agent: 


UCS 


Union Carbide Corp., Silicones Div. 






Sohio Petroleum Co. 


UDI 


Universal Detergents, Inc. & Petrochemicals 


Co. 




Solar Nitrogen Chemicals, Inc. 


UHL 


Paul Uhlich & Co., Inc. 




SOI 


American Oil Co. (Maryland) 


UNC 


United Cork Companies 




SOL 


Solar Chemical Corp. 


UNG 


Ungerer Sc Co. 




SON 


Sonnebom Chemical & Refining Corp. 


UNN 


United Chemical Corp. of Norwood 




SOR 


Thomason Industries, Inc., Southern Resin Div. 


UNP 


United Chemical Products Corp. 




SOS 


Southern Sizing Co. 


UCC 


Union Oil Co. of California 




SPD 


General Electric Co., Silicone Products Dept. 


UPF 


United States Pipe & Foundry Co. 




SPI 


Sinclair Petrochemicals, Inc. 


UPJ 


Upjohn Co. 




SPL 


Spaulding Fibre Co., Inc. 


UPL 


United States Plywood Corp. 




SPN 


Spencer Chemical Co. 


UPM 


Universal Oil Products Co. 




SPP 


Socony Paint Products Co. 


UPR 


U.S. Peroxygen Corp. 




SPY 


Standard Pyroxoloid Corp. 


URC 


United Carbon Co. 




SRC 


Shawinigan Resins Corp. 


USB 


U.S. Borax Research Corp. 




SRL 


G. D. Searle & Co. 


US I 


National Distillers & Chemical Corp., U.S. 


Industrial 


SRR 


Fred 'k A. Stresen-Reuter, Inc. 




Chemicals Co. Div. 




STA 


A. E. Staley Manufacturing Co. 


USO 


U.S. Oil Co. 




STC 


Sou-Tex Chemical Co., Inc. 


USP 


U.S. Plastic & Chemical Corp. 




STD 


Standard Dyestuff Corp. 


USR 


Naugatuck Chemical Div. of U.S. Rubber Co. 




STG 


Wm. J. Stange Co. 


UTR 


Utah Resin Co., Inc. 




STH 


South Haarpton Co. 


UVC 


Universal Chemicals Corp. 




STN 


Standard Naphthalene Products Co., Inc. 








STP 


Stepan Chemical Co. 


VAC 


Vamey Chemical Co. 




sue 


Standard Ultramarine & Color Co. 


VAL 


Valchem 




SUG 


Colonial Sugars Co., Sucro-Chemical Div. 


VAR 


Reichhold Chemicals, Inc., Varcum Chemical 


Div. 


SUM 


Summit Chemical Products Corp. 


VB 


Vermi lye-Bell 




SUN 


Sun Oil Co. 


VC 


Socony Mobil Oil Co., Inc., Virginia-Carolina 


SVT 


Solvent Chemical Co., Inc. 




Chemical Co. Div. 




SW 


Sherwin-Williams Co. 


VEL 


Velsicol Chemical Corp. 




SWR 


Switzer Bros., Inc. 


VIC 


Stauffer Chemical Co., Victor Chemical Works Div. 


SWT 


Swift & Co. 


VIN 


Vineland Chemical Co. 




SYC 


Synthetic Chemicals, Inc. 


VIS 


Nalco Chemical Co., Visco Div. 




SYN 


Synthron, Inc . 


VLY 


Chem-Fleur, Inc . 




SYP 


Synthetic Products Co. 


VNC 


Vanderbilt Chemical Corp. 




SYR 


Synoo Resins, Inc. 


VND 


Van Dyk & Co., Inc. 




SYV 


Synvar Corp. 


VPC 
VPT 


Verona-Pharma Chemical Corp. 
Vickers Refining Co., Inc. 




TAE 


Thomas A. Edison Industries, McGraw-Edison Co., 


VSV 


Valentine Sugars, Inc., Valite Div. 






Medical Gas Div. 


VTM 


Vitamins, Inc. 




TAY 


Taylor Corp. 


VTV 


Vita-Var Corp., Div. of Textron Industries, 


Inc. 


TBK. 


Universal Oil Products Co., Trubek Chemical Co. 










Div. 


WAS 


Washbum-Purex Co. 




TCC 


Tanatex Chemical Corp. 


WAW 


W. A. Wood Co-. 




TCH 


Trylon Chemical Corp. 


WAY 


Wayland Chemical Co. 




TCI 


Texize Chemicals, Inc. 


WBG 


White & Bagley Co. 




TDC 


Dlversey Corp. 


WCA 


West Coast Adhesives Co. 




TGL 


Triangle Chemical Co. 


WDC 


Western Dry Color Co. 





DIRECTORY OF MANUFACTURERS 



211 



TABLE 22. — Synthetic organic chemicals : Directory of manufacturers , 1963 — Continued 



Code 


Name of company 


Code 


Name of company 


WHI 


White & Hodges, Inc. 


WRC 


Wood Ridge Chemical Corp. 




WHL 


Whltmoyer Laboratories, Inc. 


WHD 


Weyerhaeuser Co., Wood Products Div. 




raw 


Whittemore-Wright Co., Inc. 


WSN 


Washine Chemical Corp. 




WIC 


Wica Chemicals, Inc. 


WTC 


Witco Chemical Co., Inc. 




WIL 


Wilson & Co., Inc., Wilson Laboratories Div. 


WTH 


Wallace & Tieman, Inc., Harchem Div. 




WJ 


Warner- Jenkinson Manufacturing Co. 


WTL 


Wallace & Tieman, Inc., Luoidol Div. 




WLI 


White Laboratories, Inc. 


wm 


Wallace & Tieman, Inc. 




WIM 


Wilmot & Cassidy, Inc. 


WVA 


West Virginia Pulp & Paper Co., Polychemicals 


Div. 


•*M 


Wilson & Co., Inc., Wilson-Martin Div. 


WYN 


Wyandotte Chemicals Corp. 




WOI 


Neville Chemical Co., Chlorinated Products 


WYT 


American Home Products Corp., Wyeth Laboratories, 




Div. 




Inc. Div. 




WON 


Woonsocket Color & Chemical Co. 








WPC 


Warren Paint & Color Co. 


YAW 


Young Aniline Works, Inc. 





212 



SYNTHETIC ORGANIC CHEMICALS, 1963 



TABLE 22. — Synthetic organic chemicals: Directory of manufacturers , 1963— Continued 

SECTION 2. ALPHABETICAL DIRECTORY BY COMPANY 

[Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. Tariff Commission 
for 1963 are listed below alphabetically, together with their identification codes as used in tables in pt. III. 
Sec. 1 of this table lists these manufacturers in the order of their identification codes] 



Name of company 



Abbott Laboratories 

Acme Resin Corp 

Acralite Co., Inc 

Ad-Co Color Corp 

Air Products & Chemicals, Inc., Houdry Process 

& Chemical Co. Div. 
Air Reduction Co., Inc.: 

Air Reduction Chemical & Carbide Co. Div 

Ohio Chemical & Surgical Equipment Co. Div 

Alabama Binder & Chemical Corp 

Aloo Chemical Corp 

Alcolac Chemical Corp 

Aldrich Chemical Co., Inc 

Alliance Color & Chemical Co 

Allied Chemical Corp. : 

Barrett Div 

Fibers Div 

General Chemical Div 

National Aniline Div 

Harmon Color Works 

Nitrogen Div 

Plastics Div 

Solvay Process Div 

Alox Corp 

Amalgamated Chemical Corp 

Amchem Products, Inc 

American Allsyd Industries 

American Aniline & Extract Co., Inc 

American Aniline Products, Inc 

American Bio-Synthetics Corp 

American Brake Shoe Co., American Brakeblok Div- 

American Can Co., Marathon Div 

American Chemical Corp 

American Cyanamld Co 

American Dyewood Co., Inc., New York Color & 

Chemical Co. Div. 
American Home Products Corp.,ll^eth Laboratories, 
Inc. Div. 

American Maize Products Co 

American Oil Co. (Maryland) 

American Oil Co. (Texas) 

American Petrochemical Corp 

American Potash & Chemical Corp 

American Synthetic Rubber Corp 

Ames Laboratories, Inc 

Amoco Chemicals Corp 

Ancon Chemical. Co 

Ansbacher-Siegle Corp. Div. of Sun Chemical Corp 

Ansul Chemical Co 

Apex Chemical Co., Inc 

Appleton Coated Paper Co 

Applied Plastics Co., Inc. 

Arapahoe Chemicals, Inc 

Archer-Daniels -Midland Co 

Ardmore Chemical Co 

Argus Chemical Corp 

Armour Agricultural Chemical Co 

Armour & Co. : 

Armour Industrial Chemical Co. Div 

Kessler Chemical Div 

Armour Pharmaceutical Co 

Reheis Co. Div 

Armstrong Cork Co 

Armstrong Paint & Varnish Works, Inc 

Arol Chemical Products Co 

Ashland Oil & Refining Co 



Office address 



14th St. and Sheridan Rd., N. Chicago, 111. 60664. 

14-01 Circle Ave., Forest Park, 111. 60130. 

59 Kent St., Brooklyn, N.Y. 11222. 

66 Lister Ave., Newark, N.J. 07105. 

Widener Bldg., 1339 Chestnut St., Philadelphia, Pa. 19107. 



150 E. 42d St., New York, N.Y. 10017. 

1400 E. Washington Ave., Madison, Wis. 53703. 

P.O. Box 3179, Tuscaloosa, Ala. 35404. 

Trenton Ave. and William St., Philadelphia, Pa. 19134. 

3440 Fairfield Rd., Baltimore, Md. 21226. 

2371 N. 30th St., Milwaukee, Wis. 53210. 

33 Avenue P, Newark, N.J. 07015. 

40 Rector St., New York, N.Y. 10006. 

40 Rector St., New York, N.Y. 10006. 

P.O. Box 70, Morristown, N.J. 07960. 

40 Rector St., New York, N.Y. 10006. 

40 Rector St., New York, N.Y. 10006. 

Drawer 61, Hopewell, Va. 23860. 

P.O. Box 365, Morristown, N.J. 07960. 

P.O. Box 271, Syracuse, N.Y. 13201. 

3943 Buffalo Ave., Niagara Falls, N.Y. 14302. 

Ontario and Rorer Sts., Philadelphia, Pa. 19134. 

Brooks ide Ave., Ambler, Pa. 19002. 

Broad and 14th Sts., Carlstadt, N.J. 07072. 

Venango and F Sts., Philadelphia, Pa. 19134. 

P.O. Box 2086, Paterson, N.J. 07509. 

710 W. National Ave., Milwaukee, Wis. 53204. 

P.O. Box 21, Birmingham, Mich. 48012. 

Menasha, Wis. 54957. 

2112 E. 223d St., Long Beach, Calif. 90810. 

Berdan Ave., Wayne, N.J. 07470. 

374 Main St., Belleville, N.J. 07109. 

P.O. Box 8299, Philadelphia, Pa. 19101. 

250 Park Ave., New York, N.Y. 10017. 

910 S. Michigan Ave., Chicago, 111. 60680. 

910 S. Michigan Ave., Chicago, 111. 60680. 

3134 California St., N.E., Minneapolis, Minn. 55418. 

3000 W. 6th St., Los Angeles, Calif. 90054. 

P.O. Box 360, Louisville, Ky. 40201. 

200 Rook Lane, Milford, Conn. 06463. 

130 E. Randolph Dr., Chicago, 111. 60601. 

P.O. Drawer 37, Westlake, La. 70669. 

92 Chestnut Ave., Staten Island, N.Y. 10305. 

1 Stanton St., Marinette, Wis. 54143. 

200 S. 1st St., Elizabethport, N.J. 07206. 

825 E. Wisconsin Ave., V^pleton, Wis. 54910. 

130 Penn St., El Segundo, Calif. 90245. 

2855 Walnut St., Boulder, Colo. 80301. 

500 Investors Bldg., Minneapolis, Minn. 55440. 

840 Valley Brook Ave., Lyndhurst, N.J. 07071. 

633 Court St., Brookl^m, N.Y. 11231. 

P.O. Box 1685, Atlanta, Ga. 30301. 

110 N. Wacker Dr., Chicago, 111. 60606. 

State Rd. and Cottman Ave., Philadelphia, Pa. 19135. 

P.O. Box 511, Kankakee, 111. 60901. 

235 Snyder Ave., Berkeley Heights, N.J. 07922. 

W. Liberty St., Lancaster, Pa. 17604. 

1330 S. Kilboum Ave., Chicago, 111. 60623. 

371 Wayne St., Jersey City, N.J. 07302. 

1401 Winchester Ave., Ashland, Ky. 41101. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. — Synthetic organic chemicals .- Directory of manufacturers , 1963 --Continued 



213 



Name of company 



Office address 



Astra Pharmaceutical Products, Inc 

Atlantic Chemical Corp 

Atlantic Refining Go 

Atlantic Tubing & Rubber Co 

Atlas Chemical Industries, Inc., Chemicals Div- 

Atlas Processing Co 

Augusta Chemical Co 

Avisun Corp 

Baird Chemical Industries, Inc 

Baker Castor Oil Co 

J. T. Baker Chemical Co 

Taylor Div 

Baldwin-Montrose Chemical Co., Inc., Montrose 
Chemical Div. 

Balfour Chemicals, Inc 

Baltimore Paint & Chemical Corp 

Barlow Chemical Corp 

Bates Chemical Co 

Baxter laboratories, Inc 

J. H. Baxter & Co 

Bayoil Co., Inc 

Beacon Chemical Industries, Inc 

Beech-Nut Life Savers, Inc 

Belding Chemical Industries 

Belle Chemical Co., Inc 

Bendix Corp., Marshall-Eclipse Div 

Bennett's 

Benzol Products Co 

Bercen Chemical Co., Inc 

Berkshire Color & Chemical Co 

Bemcolors-Poughkeepsie, Inc 

Bemz-0-Matio, Harris Paint Co. Div 

Blackman-Uhler Chemical Co 

Blue Arrow, Inc 

Borden Co., Borden Chemical Co. Div 

Borg -Warner Corp., Marbon Chemical Div 

Walter N. Boysen Co 

Branchf lower Co 

Brand Plastics Co 

Bristol -Meyers Co., Bristol laboratories Div — 

Brooklyn Color Works, Inc 

Andrew Brown Co 

M. A. Bruder & Sons, Inc 

Bryant Chemical Corp 

Buckeye Cellulose Corp 

Buciman Laboratories, Inc 

Budd Co., Polychem Div 

Burdick & Jackson laboratories, Inc 

Burkart-Schier Chemical Co 

Burroughs-Welloome & Co. (U.S.A. ), Inc 

Bzura Chemical Co., Inc 

Samuel Cabot, Inc 

Cadet Chemical Corp 

Calcasieu Chemical Corp 

California Chemical Co. : 

Oronite Div 

Ortho Div 

California Ink Co., Inc 

Callery Chemical Co 

Cap-Roc, Inc., Capital Plastics Div 

Caradco, Inc., Durel Div 

Cargill, Inc 

Carlisle Chemical Works, Inc 

Advance Div 

Carpenter-Morton Co 

Carus Chemical Co., Inc 

Cary Chemicals, Inc 

Catalin Corp. of America 

Celanese Corp. of America: 

Celanese Chemical Co. Div 

Celanese Plastics Co. Div 

Celanese Polymer Co. Div 



7 Neponset St., Worcester, Mass. 01606. 

P.O. Box 216, Nutley, N.J. 07110. 

260 S. Broad St., Philadelphia, Pa. 19101. 

Mill St., Cranston, R.I. 02905. 

New ttirphy Rd. and Concord Pike, Wilmington, Del. 19899. 

P.O. Box 1786, Shreveport, La. 71102. 

P.O. Box 660, Augusta, Ga. 30903. 

P.O. Box 312, New Castle, Del. 19720. 

10 W. 33d St., New York, N.Y. 10001. 

40 Avenue A, Bayonne, N.J. 07002. 

600 N. Broad St., Phillipsburg, N.J. 08865. 

600 N. Broad St., Phillipsburg, N.J. 08865. 

100 Lister Ave., Newark, N.J. 07105. 

501 Milwaukee Waterway, Taooma, Wash. 98421. 

2325 Hollins Ferry Rd., Baltimore, m. 21230. 

Barlow Lane, Ossining, N.Y. 10562. 

Soottdale Rd., Lansdowne, Pa. 19050. 

6301 N. Lincoln Ave., Morton Grove, 111. 60053. 

120 Montgomery St., San Francisco, Calif. 94104. 

4 Union St., Peabody, Mass. 01960. 

33 Richdale Ave., Cambridge, Mass. 02140. 

Canajoharie, N.Y. 13317. 

1407 Broadway, New York, N.Y. 10018. 

P.O. Box 848, Lowell, N.C. 28089. 

P.O. Box 238, Troy, N.Y. 12180. 

65 W. 1st S., Salt Lake City, Utah 84110. 

237 South St., Newark, N.J. 07114. 

285 Valley St., Providence, R.I. 02908. 

12th and BemSts., Reading, Pa. 19604. 

45 Taylor Ave., Poughkeepsie, N.Y. 12602. 

1026 N. 19th St., Tampa, Fla. 33601. 

P.O. Box 1869, Spartanburg, S.C. 29301. 

P.O. Box B, Jacksonville, Fla. 32203. 

350 Madison Ave., New York, N.Y. 10017. 

P.O. Box 68, Washington, W. Va. 26181. 

1001 42d St., Oakland, Calif. 94608. 

4501 Shilshole St. NW., Seattle, Wash. 98107. 

8400 Willow Springs Rd., Willow Springs, 111. 60480. 

P.O. Box 657, Syracuse, N.Y. 13201. 

681 Morgan Ave., Brooklyn, N.Y. 11222. 

5431 District Blvd., Los Angeles, Calif. 90022. 

52d St. -and Grays Ave., Philadelphia, Pa. 19143. 

6 North St., N. Quincy, Mass. 02171. 

2899 Jackson Ave., Memphis, Tenn. 38108. 

1256 N. McLean Blvd., Memphis, Tenn. 38108. 

70 S. Chapel St., Newark, Del. 19711. 

1953 S. Harvey St., Muskegon, Mich. 49442. 

1228 Chestnut St., Chattanooga, Tenn. 37402. 

1 Scarsdale Rd., Tuckahoe, N.Y. 10707. 

Clark St. and Broadway, Keyport, N.J. 07735. 

246 Summer St., Boston, Mass. 02210. 

2153 Lockport-Olcott Rd., Burt, N.Y. 14028. 

P.O. Box 1522, Lake Charles, La. 70604. 

200 Bush St., San Francisco, Calif. 94120. 

Lucas and Ortho Way, Richmond, Calif. 94800. 

711 Camelia St., Berkeley, Calif. 94710. 

Callery, Pa. 16024. 

250 Mill St., Rochester, N.Y. 14614. 

1098 Jackson St., Dubuque, Iowa 52001. 

Room 2008, 3 Penn Center Plaza, Minneapolis, Minn. 19102. 

West St., Reading, Ohio 45215. 

500 Jersey Ave., New Brunswick, N.J. 08903. 

376 3d St., Everett, Mass. 02149. 

1375 8th St., LaSalle, 111. 61301. 

P.O. Box 38, E. Brunswick, N.J. 08816. 

1 Park Ave., New York, N.Y. 10016. 

522 5th Ave., New York, N.Y. 10036. 
744 Broad St., Newark, N.J. 07102. 
744 Broad St., Newark, N.J. 07102. 



214 SYNTHETIC ORGANIC CHEMICALS, 1963 

TABLE 22. — Synthetic organic chemicals: Directory of manufacturers , i965--Continued 



Name of company 



Office address 



Certified Proteins Corp 

Chapman Chemical Co 

Charlotte Chemical Laboratories 

Chase Chemical Corp 

Chemagro Corp 

Chemetron Corp., Chemetron Chemicals, Organic 
Chemical Dept. 

Chemfax, Inc 

Chem-Fleur, Inc 

Chemical Insecticide Corp 

Chemical Manufacturing Co., Inc 

Chemical Products Corp 

Chemico, Inc 

Chemirad Corp 

Chemlek Laboratories, Inc 

Chemol, Inc 

Chemstrand Corp 

Childs Pulp Colors, Inc 

Chipman Chemical Co., Inc 

Ciba Corp. : 

Clba Pharmaceutical Co. Div 

Ciba Products Co. Div 

Cindet Chemicals, Inc 

Cities Service Oil Co 

W. A. Cleary Corp 

Clintwood Chemical Co 

Clover Chemical Co 

Coastwise Petroleum Co 

Cookerille Chemicals, Inc 

Colab Resin Corp 

Colgate-Palmolive Co 

Collett-Week Corp 

Collier Carbon & Chemical Corp 

Colloids, Inc 

Colonial Sugars Co., Sucro-Chemical Div 

Columbian Carbon Co., Pigments & Elastomers Div 

Columbia Organic Chemicals Co., Inc 

Commercial Solvents Corp 

Commonwealth Oil Refining Co., Inc 

Conchemco, Inc., H. B. Davis Co. Div 

Concord Chemical Co., Inc 

Conestoga Chemical Corp 

Consolidated Paint Co 

Consolidated Papers, Inc 

Continental Chemical Co 

Continental Oil Co 

Cook Paint & Varnish Co 

Cooperative Farm Chemicals Association 

Coopers Creek Chemical Corp 

Copolymer Rubber & Chemical Corp 

Com Products Co 

Cosden Oil & Chemical Co 

Cowles Chemical Co 

Crompton & Khowles Corp., Althouse Chemical Co. 
Div. 

Crosby Chemicals, Inc 

Crown Central Petroleum Corp 

Crown Chemical Corp 

Crown Zellerbach Corp., Chemical Products Div — 

Cumberland Chemical Corp 

Cutter laboratories, Inc 

Dan River Mills, Inc 

Joseph Davis Plastics Co 

Dawe's Laboratories, Inc 

Dearborn Chemical Co 

John Deere Chemical Co 

Degen Oil & Chemical Co 

Delaware Chemicals, Inc 

DePaul Chemical Co., Inc 

DeSoto Chemical Coatings, Inc 

Detrex Chemical Industries, Inc 

Devoe & Reynolds Co., Inc., Jones-Dabney Div 



320 W. Ohio St., Chicago, 111. 60610. 

P.O. Box 9158, Memphis, Tenn. 38109. 

50<i6 Old Pinesville Rd., Charlotte, N.C. 28201. 

3527 Smallman St., Pittsburgh, Pa. 15201. 

P.O. Box 4913, Station "F", Kansas City, Mo. 64120. 

386 Park Ave. S. , New York, N.Y. 10016. 

P.O. Box 215, Gulfport, Miss. 39502. 

200 Pulaski St., Newark, N.J. 07105. 

30 Whitman Ave., hfetuohen, N.J. 08840. 

Magunco Rd., Ashland, Mass. 01721. 

P.O. Box 815, Cartersville, Ga. 30120. 

2508 E. Bailey fid., Cuyahoga Falls, Ohio 44221. 

P.O. Box 187 (I^ders lane), E. Brunswick, N.J. 08816. 

4040 W. 123d St., Alsip, 111. 60658. 

P.O. Box 3227, Greensboro, N.C. 27402. 

350 5th Ave., New York, N.Y. 10001. 

42 Summit St., Brooklyn, N.Y. 11231. 

1801 Murchison Dr. , Burlingame, Calif. 94011. 

556 Morris Ave., Summit, N.J. 07901. 

Route 208, Fair Lawn, N.J. 17410. 

P.O. Box 907, Greensboro, N.C. 27402. 

P.O. Box 300, Tulsa, Okla. 74119. 

P.O. Box 749, New Brunswick, N.J. 08903. 

1 N. LaSalle St., Chicago, 111. 60602. 

P.O. Box 10865, Pittsburgh, Pa. 15236. 

1127 Munsey Bldg., Baltimore, Md. 21202. 

Greenwood, Va. 22943. 

Main St., Tewksbury, Mass. 01876. 

300 Park Ave., New York, N.Y. 10022. 

Quimby St., Ossining, N.Y. 10562. 

714 W. Olympic Blvd., Los Angeles, Calif. 90015. 

394 Frelinghuysen Ave . , Newark, N.J. 07114. 

Drawer G, Grameroy, La. 70052. 

380 Madison Ave., New York, N.Y. 10017. 

P.O. Box 5273, Columbia, S.C. 29205. 

260 Madison Ave., New York, N.Y. 10016. 

P.O. Box 4423, San Juan, Puerto Rico 10017. 

Bayard and Severn Sts., Baltimore, Md. 21230. 

205 S. 2d St., Camden, N.J. 08103. 

Wilmington Industrial Park, Wilmington, Del. 19801. 

3101 E. 11th St., Los Angeles, Calif. 90023. 

Wisconsin Rapids, Wis. 54494. 

270 Clifton Blvd., Clifton, N.J. 07015. 

1300 Main, Houston, Tex. 77001. 

1412 Knox, N. Kansas City, Mo. 64116. 

P.O. Box 80, Lawrence, Kans. 66044. 

River Rd., W. Conshohocken, Pa. 19428. 

P.O. Box 2591, Baton Rouge, La. 70821. 

P.O. Box 345, Argo, 111. 60502. 

P.O. Box 1311, Big Spring, Tex. 79721. 

12000 Shaker Blvd., Cleveland, Chio 44120. 

P.O. Box 341, Reading, Pa. 19603. 

P.O. Drawer 32, DeRidder, La. 70634. 

P.O. Box 1168, Baltimore, Md. 21203. 

12 Dudley St., Providence, R.I. 02901. 

Camas, Wash. 98607. 

150 E. 42d St., New York, N.Y. 10017. 

4th and Parker Sts., Berkeley, Calif. 94710. 

Danville, Va. 24540. 

450 Schuyler Ave., Kearny, N.J. 07032. 

4800 S. Richmond St., Chicago, 111. 60632. 

Rm. 375, Merchandise Mart Plaza, Chicago, 111. 60654 

P.O. Box 1736, Tulsa, Okla. 74101. 

200 Kellogg St., Jersey City, N.J. 07305. 

726 King St., Wilmington, Del. 19801. 

44-27 Purvis St., Long Island City, N.Y. 11101. 

1700 S. Mt. Prospect Ave., Des Plaines, 111. 60018. 

P.O. Box 501, Detroit, Mich. 48232. 

P.O. Box 8248, Station "E", Louisville, Ky- 40208. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. --Synthetic organic chemicals.- Directory of manufacturers , 1963 — Continued 



215 



Name of company 



Office address 



Dexter Chemical Corp 

Diamond Alkali Co 

Western Div 

Fiber Chemical Dept 

Diversey Corp 

Dixie Pine Products Co., Ino 

Donald A. Dodd 

Dominion Products, Inc 

Dover Chemical Co 

Dow Badische Chemical Co 

Dow Chemical Co 

Dow Coming Corp 

Drew Chemical Corp 

Frank W. Dunne Co 

E. I. duPont de Nemours & Co., Inc 

Duraphene Corp 

Dye Specialties, Inc 

Eagle-Pitcher Co., Ohio Rubber Co. Div 

J. S. & W. R. Eakins, Inc 

Eastman Kodak Co 

Tennessee Eastman Co. Div 

Texas Eastman Co. Div 

Eddystone Manufacturing Co 

Thomas A. Edison Industries, MoGraw-Edison Co. 

Medical Gas Div. 

El Paso Natural Gas Products Co 

Emery Industries, Inc 

Western Div 

Bukay Chemical Co 

Endo Laboratories, Inc 

Enjay Chemical Co., Div. of Humble Oil & 

Refining Co. 
Epoxylite Corp 

Erdmann Chemical Co., Inc 

Escambia Chemical Corp 

Ethyl Corp 

Ethyl-Dow Chemical Co 

Evans Chemetics, Inc 

Everledge Manufacturing, Inc 

Fabricolor Chemical Corp 

Fairmount Chemical Co., Inc 

Farac Oil & Chemical Co 

Far-Best Corp., 0. L. King Div 

Farmers Chemical Association, Inc 

Farmers' Chemical Co 

Famow, Inc 

Estate of W. U. Farrington 

Federal Color Laboratories, Inc 

Felton Chemical Co., Inc 

Fermco Laboratories, Inc 

Ferro Corp., Ferro Chemical Div 

Fiberfil, Inc 

Fibreboard Paper Products Corp 

Filtered Rosin Products Co 

Fine Organios, Inc 

Firestone Tire & Rubber Co. : 

Firestone Plastics Co. Div 

Firestone Synthetic Rubber & Latex Co. Div-- 

Florasynth Laboratories, Inc 

FMC Corp . : 

American Viscose Div 

Chemical Div 

Inorganic Chemicals Div 

Niagara Chemical Div 

Organic Chemicals Div 

Foote Mineral Co 

Foremost Chemical Products Co 

Formica Corp 

Foster Grant Co., Inc 

Foster-Heaton Co 

France, Campbell & Darling, Inc 



845 Edgewater Rd., Bronx, N.Y. 10474. 

300 Union Commerce Bldg., Cleveland, Ohio 44114. 

300 Union Commerce Bldg., Cleveland, Ohio 44114. 

300 Union Commerce Bldg., Cleveland, Ohio 44114. 

212 W. Monroe St., Chicago, 111. 60606. 

P.O. Box 470, Hattiesburg, Miss. 39402. 

8002 53d Ave. W., Everett, Wash. 98202. 

882 3d Ave., Brooklyn, N.Y. 11232. 

15th and Davis Sts., Dover, Ohio 44244. 

P.O. Box 875, Freeport, Tex. 77541. 

Main St., Midland, Mich. 48640. 

P.O. Box 592, Midland, Mich. 48641. 

416 Division St., Boonton, N.J. 07005. 

1007 41st St., Oakland, Calif. 94608. 

1007 Market St., Wilmingtcn, Del. 19898. 

Route 14, Sterling, Conn. 06377. 

26 Journal Sq., Jersey City, N.J. 07306. 

Ben Hur Ave., Willoughby, Ohio 44094. 
55 Berry St., Brooklyn, N.Y. 11211. 
343 State St., Rochester, N.Y. 14650. 
P.O. Box 511, Kingsport, Tenn. 37662. 
P.O. Box 2068, Longview, Tex. 75603. 
P.O. Box 471, Wilmington, Del. 19899. 
Stuyvesant Falls, N.Y. 12174. 

P.O. Box 1161, El Paso, Tex. 79999. 

4300-Carew Tower, Cincinnati, Ohio 45202. 

8733 S. Dice Rd., Santa Fe Springs, Calif. 90670. 

319 2d St., Elizabeth, N.J. 07206. 

1000 Stewart Ave., Garden City, N.Y. 11533. 

60 W. 49th St., New York, N.Y. 10020. 

P.O. Box 3397, 1428 N. Tyler Ave., S. El Monte, Calif. 

91733. 
66 Lister Ave., Newark, N.J. 07105. 
P.O. Box 467, Pensaoola, Fla. 32502. 
100 Park Ave., New York, N.Y. 10017. 
Midland, Mich. 48640. 
250 E. 43d St., New York, N.Y. 10017. 
P.O. Box 178, Harrison City, Pa. 15636. 

24-1/2 Van Houten St., Paterson, N.J. 07505. 

117 Blanchard St., Newark, N.J. 07105. 

147th and Indiana Ave., Chicago, 111. 60627. 

640 Oilman St., Berkeley, Calif. 94710. 

P.O. Box 67, Tyner, Tenn. 37392. 

P.O. Box 591, Kalamazoo, Mich. 49005. 

77 Jacobus Ave., S. Kearny, N.J. 07032. 

P.O. Box 389, E. Greenwich, R.I. 02818. 

4526 Chickering Ave., Cincinnati, Ohio 45232. 

599 Johnson Ave., Brooklyn, N.Y. 11237. 

4941 S. Racine Ave., Chicago, 111. 60609. 

P.O. Box 349, Bedford, Ohio 44014. 

1701 N. Heidelbach Ave., Evansville, Ind. 47711. 

1550 Powell St., Bneryville, Calif. 94600. 

P.O. Box 349, Baxley, Ga. 31513. 

205 Main St., Lodi, N.J. 07644. 

P.O. Box 699, Pottstown, Pa. 19464. 
381 W. Wilbeth Rd., Akron, Ohio 44301. 
900 Van Nest Ave., Bronx, N.Y. 10462. 

1617 Pennsylvania Blvd., Philadelphia, Pa. 19103. 

633 3d Ave., New York, N.Y. 10017. 

Sawyer Ave. and River Rd., Tonawanda, N.Y. 14207. 

100 Niagara St., Middleport, N.Y. 14105. 

P.O. Box 1616, Baltimore, Md. 21203. 

Route 100, Exton, Pa. 19341. 

P.O. Box 599, Oakland, Calif. 94604. 

4614 Spring Grove Ave., Cincinnati, Ohio 45232. 

289 N. Main St., Leominster, Mass. 01453. 

16 E. 5th St., Paterson, N.J. 07524. 

N. Michigan Ave., Kenilworth, N.J. 11234. 



216 SYNTHETIC ORGANIC CHEMICALS, 1963 

TABLE 22. — Synthetic organic chemicals: Directory of manufacturers , i565--Continued 



Name of company 



HNW 
HNX 
HDG 
HST 



J. P. Frank Chemical & Plastic Corp 

Franklin Chemical Co 

Freeman Chemical Corp 

Frisch & Co., Inc 

Fritzsche Bros., Inc 

H. B. Fuller Co— — - 

W. P. Fuller & Co 

Ganma Chemical Corp 

Gane's Chemical Works, Inc 

Geigy Chemical Corp 

General Aniline & Film Corp 

General Electric Co. : 

Chemical Materials Dept 

Insulating Materials Dept 

Silicone Products Dept 

General Foods Corp., Maxwell House Div 

General latex & Chemical Corp 

General Mills, Inc 

General Plastics Manufacturing Co 

General Tire & Rubber Co., Chemical Div 

P. D. George Co 

Georgia-Pacific Corp. : 

Coos Bay Div 

Puget Sound Div 

Oilman Paint & Varnish Co 

Givaudan Corp 

Glasflex, Inc 

Glidden Co 

Glyoo Chemicals, Inc 

B. F. Goodrich Co., B. F. Goodrich Chemical 
Co. Div. 

Goodrich-Gulf Chemicals, Inc 

Goodyear Tire & Rubber Co 

Gordon Chemical Co., Inc 

Gordon Chemicals, Inc 

Gordon-Lacey Chemical Products Co., Inc 

W. R. Grace & Co. : 

Dewey & Almy Chemical Div 

Hatco Chemical Div 

Nitrogen Products Div 

Polymer Chemicals Div 

Grain Processing Corp 

Great American Chemical Corp 

Great Lakes Chemical Corp 

Great Western Sugar Co 

Guard Chemical Co., Inc 

Guardsman Chemical Coatings, Inc 

Gulf Oil Corp 

Guth Chemical Co 

H & N Chemical Co 

Haag Laboratories, Inc 

Halby Products Co., Inc 

C. P. Hall Co. of Illinois 

Hamilton Chemical Corp 

Hampden Color & Chemical Co 

Hampshire Chemical Corp 

Hanna Paint Manufacturing Co., Inc 

Harshaw Chemical Co 

Hartman-Leddon Co 

Hart Products Corp 

Haveg Industries, Inc., Resin 8: Compound Div- 

Hercules Powder Co 

Imperial Color & Chemical Dept 

Heresite & Chemical Co 

Hess Oil & Chemical Corp 

Heterochemical Corp 

Hexagon laboratories, Inc 

Heyden Newport Chemical Corp 

Newport Industries Div 

Nuodex Products Div 

Hodag Chemical Corp 

Hoechst Chemical Corp 



Office address 



5410 Avenue U, Brooklyn, N.Y. 11234. 

2020 Bruck St., Columbus, Ohio 43207. 

222 E. Main St., Port Washington, Wis. 53074. 

88 E. 11th St., Paterson, N.J. 07509. 

76 9th Ave., New York, N.Y. 10011. 

4819 Industrial Ct., Cincinnati, Ohio 45217. 

450 E. Grand Ave., S. San Francisco, Calif. 94080. 

355 Lexington Ave., New York, N.Y. 10017. 
535 5th Ave., New York, N.Y. 10017. 
P.O. Box 430, Yonkers, N.Y. 10702. 
435 Hudson St., New York, N.Y. 10014. 

1 Plastics Ave., Pittsfield, Mass. 01203. 
1 Campbell Rd., Schenectady, N.Y. 12306. 
Waterford, N.Y. 12188. 
1125 Hudson St., Hoboken, N.J. 07030. 
566 Main St., Cambridge, Mass. 02139. 
S. Kensington Rd., Kankakee, 111. 60901. 
3481 S. 35th St., Tacoma, Wash. 98409. 
1708 Englewood Ave., Akron, Ohio 44309. 
5200 N. 2d St., St. Louis, Mo. 63147. 

P.O. Box 869, Coos Bay, Qreg. 97420. 

300 Laurel St., Bellingham, Wash. 98225. 

W. 8th and Pine Sts., Chattanooga, Tenn. 37401. 

109-201 Delawanna Ave., Delawanna, N.J. 07014. 

Stirling, N.J. 07980. 

900 Union Commerce Bldg., Cleveland, Ohio 44114. 

417 5th Ave., New York, N.Y. 10016. 

3135 Euclid Ave., Cleveland, Ctoio 44115. 

1717 E. 9th St., Cleveland, Ohio 44114. 
1144 E. Market St., Akron, Ohio 44316. 
88 Webster St., Worcester, Mass. 01603. 
500 A St., Wilmington, N.J. 19800. 
57-02 48th St., Maspeth, N.Y. 11378. 

62 Whittenmore Ave., Cambridge, Mass. 02140. 

King George Post Rd., P.O. Box 27, Fords, N.J. 08863. 

P.O. Box 277, Memphis, Tenn. 38101. 

225 Allwood Rd., Clifton, N.J. 07015. 

1600 Oregon St., Muscatine, Iowa 52761. 

650 Water St., Fitohburg, Mass. 21420. 

P.O. Box 472, W. Lafayette, Ind. 47906. 

P.O. Box 5308, Terminal Annex, Denver, Colo. 80217. 

N. Water St., Ossining, N.Y. 10563. 

1350 Steele Ave. SW. , Grand Rapids, Mich. 49502. 

P.O. Drawer 2100, Houston, Tex. 77001. 

1455 W. Congress Pkwy., Chicago, 111. 60607. 

Maltese Dr., Totowa, N.J. 07512. 

14010 S. See:ey, Blue Island, 111. 60406. 

P.O. Box 366, Wilmington, Del. 19899. 

5245 W. 73d St., Chicago, 111. 60638. 

45 Andrews St., Lowell, Mass. 01853. 

5 Albany St., Springfield, Mass. 01101. 

PoissonAve., Nashua, N.H. 03060. 

1313 Windsor Ave., Columbus, Ohio 43211. 

1945 E. 97th St., Cleveland, Ohio 44106. 

60th and Woodland Ave., Philadelphia, Pa. 19143. 

1440 Broadway, New York, N.Y. 10018. 

900 Greenbank Rd., Wilmington, Del. 19808. 

Hercules Tower, 910 Market St., Wilmington, Del. 19899. 

P.O. Box 231, Glens Falls, N.Y. 12801. 

822 S. 14th St., Manitowoc, Wis. 54221. 

State St., Perth Amboy, N.J. 08861. 

Ill E. Hawthorne Ave., Valley Stream, N.Y. 11582. 

3536 Peartree Ave., Bronx, N.Y. 10469. 

300 E. 42d St., New York, N.Y. 10017. 

P.O. Box 911, Pensacola, Fla. 32501. 

830 Magnolia Ave., Elizabeth, N.J. 07114. 

7247 N. Central Park Ave., Skokie, 111. 60076. 

129 IJiidnick St., W. Warwick, R.I. 02893. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. --Synthetic organic chemicals: Directory of manufacturers . 1963 --Continued 



217 



Name of company 



Office address 



Hoffmaim-LaRoche, Inc 

Hoffman-Taff, Inc 

Holland Color & Chemical Co 

Hooker Chemical Corp 

Durez Plastics Div 

E. F. Houghton & Co 

Houston Chemical Corp 

Humphrey Chemical Co 

Husky -Dominion Briquets 

Ifynson, Westcott & Dunning, Inc 

Hysol Corp 

I.C.I. (Organics), Inc 

Imperial Chemical Co., Inc 

Importers Service Corp 

Industrial Biochemieals 

Industrial Dyestuff Co 

Inland Steel Container Co 

Interchemical Corp. : 

Color & Chemicals Div 

Finishes Div 

Organic Chemicals Dept 

International Flavors & Fragrances, Inc 

International Latex Corp 

International Minerals & Chemical Corp 

International Paper Co 

International Resistance Co 

Inter-Pacific Resins, Inc 

Interplastic Corp., Commercial Resins Div 

Ironsides Resins, Inc 

Isochem Resins Co 

Isocyanate Products, Inc 

Jamestown Paint & Varnish Co 

Jefferson Chemical Co., Inc 

Jefferson lake Sulphur Co., Chemical Div 

Jennison -Wright Corp 

Andrew Jergens Co 

Jersey State Chemical Co 

Jewel Paint & Varnish Co 

Joclin Manufacturing Co 

S. C. Johnson & Son, Inc 

Jones-Blair Paint Co 

W. H. & F. Jordan, Jr. Manufacturing Co., Inc— ■ 
Julian Laboratories, Inc ' 

Kaiser Aluminum & Chemical Corp 

Kali Manufacturing Co 

Kay-Fries Chemicals, Inc 

Kelly-Pickering Chemical Corp 

Kendall Refining Co 

Kennecott Copper Corp. : 

Chine Mines Div 

Utah Copper Div 

Kenrich Petrochemicals, Inc 

Keysor Chemical Co 

Keystone Chemurgic Corp 

Keystone Color Works, Inc 

Keystone Paint & Varnish Corp 

Kilsdonk Chemical Corp 

Knapp Products, Inc 

Knoedler Chemical Co 

H. Kohnstamm & Co., Inc 

Kolker Chemical Corp., DBA Frontier Chemical Co' 
Koppers Co . , Inc . : 

Plastics Div 

Tar Products Div 

Koppers Pittsburgh Co 

Kyanize Paints, Inc 

Lakeside laboratories, Inc 

Lakeway Chemical Co 

LaMotte Chemical Products Co 



Sa-i Kingsland Rd., Nutley, N.J. 07110. 

P.O. Box 12-^6 SSS, Springfield, Mo. 65805. 

AVI Howard Ave., Holland, Mich. A9A2A. 

Buffalo Ave. and -iVth St., Niagara Falls, N.Y. W302. 

Walck Rd., N. Tonawanda, N.Y. 1-4121. 

303 W. Lehigh Ave., Philadelphia, Pa. 19133. 

200 Madison Ave., New York, N.Y. 10016. 

Devine St., North Haven, Conn. 06473. 

P.O. Box 380, Cody, Wyo. 8241'4. 

Charles and Chase Sts., Baltimore, Md. 21201. 

1100 Seneca Ave., Olean, N.Y. 14761. 

55 Canal St., Providence, R.I. 02901. 

W. 6th and Grass Sts., Shenandoah, Iowa 51601. 

233 Suydam Ave., Jersey City, N.J. 07304. 

Edison Industrial Center, Edison, N.J. 08817. 

Dexter Rd., E. Providence, R.I. 02914. 

6532 S. Menard Ave., Chicago, 111. 60638. 

150 Wagaraw Rd., Hawthorne, N.J. 07507. 
1255 Broad St., Clifton, N.J. 07012. 

P.O. Box 8, Route 17, Carlstadt, N.J. 07072. 
521 W. 57th St., New York, N.Y. 10019. 
Playtex Park, Dover, Del. 19901. 
5A01 Old Orchard Rd., Skokie, 111. 60078. 

220 E. 42d St., New York, N.Y. 10017. 

401 N. Broad St., Philadelphia, Pa. 19104. 
P.O. Box 445, Sweet Home, Oreg. 97386. 
102 W. Fairfield Ave., St. Paul, Minn. 55107. 
270 W. Mound St., Columbus, Ohio 43216. 

221 Oak St., Providence, R.I. 02909. 

900 Wilmington Rd., New Castle, Del. 19720. 

108 Main St., Jamestown, Pa. 16134. 

P.O. Box 53300, Houston, Tex. 77052. 

1914 Haden Rd., Houston, Tex. 77015. 

P.O. Box 4187, Station E, Toledo, Ohio 43609. 

2535 Spring Grove Ave., Cincinnati, Ohio 45214. 

59 Lee Ave., Haledon, N.J. 07508. 

345 N. Western Ave., Chicago, 111. 60612. 

Lufbery Ave., Wallingford, Conn. 06492. 

1525 Howe St., Racine, Wis. 53403. 

6969 Denton Dr., Dallas, Tex. 75235. 

Barclay Bldg., 1 Belmont Ave., Bala Cynwyd, Pa. 19004. 

9352-58 W. Grand Ave., Franklin Park, 111. 60131. 

P.O. Box 337, Gramercy, La. 70052. 
427 E. Moyer St., Philadelphia, Pa. 19125. 
360 Lexington Ave., New York, N.Y. 10017. 
956 Bransten Rd., San Carlos, Calif. 94070. 
1177 Kendall Ave., Bradford, Pa. 16701. 

Hurley, N. Mex. 88043. 

P.O. Box 1650, Salt Lake City, Utah 84110. 

Foot of E. 22d St., Bayonne, N.J. 07002. 

26000 Bouquet Canyon Rd., Saugus, Calif. 91350. 

R.D. #2, Bethlehem, Pa. 18017. 

151 W. Gay Ave., York, Pa. 17403. 

71 Otsego St., Brooklyn, N.Y. 11231. 

101 Canal St., Lock Haven, Pa. 17745. 

180 Hamilton Ave., Lodi, N.J. 07644. 

651 High St., Lancaster, Pa. 17604. 

161 Avenue of the Americas, New York, N.Y. 10013. 

600 Doremus Ave., Newark, N.J. 07105. 

Koppers Bldg., 430 7th Ave., Pittsburgh, Pa. 15219. 

Koppers Bldg., 430 7th Ave., Pittsburgh, Pa. 15219. 

Koppers Bldg., 430 7th Ave., Pittsburgh, Pa. 15219. 
2d and Boston, Sts., Everett, Mass. 02149. 

1707 E. North Ave., Milwaukee, Wis. 53201. 
5025 Evanston Ave., Muskegon, Mich. 49443. 
Chestertown, Md. 21620. 



749-026 O - 64 - 15 



218 SYNTHETIC ORGANIC CHEMICALS. 1963 

TABLE 22. -Synthetic organic chemicals: Directory of manufacturers , 1963 --Continued 



Name of company 



Lasco Industries, Inc 

Laurel Soap Manufacturing Co 

Lawrence Mills, Inc 

Lawter Chemicals, Inc., Krumbhaar Resin Div — 

Leatex Chemical Co 

Lebanon Chemical Corp 

Lefflngwell Chemical Co 

Lehigh Chemical Co 

B. L. Lemke & Co., Inc 

Leonard Refineries, Inc 

Lever Brothers Co 

C. Lever Co., Inc 

Fred'k H. Levey Co., Inc 

Lignin Products Co 

Eli Ully Sc Co— --- 

Lubrizol Corp 

George Lueders & Co 

M & T Chemicals, Ino 

MacKenzie Chemical Works, Inc 

Magruder Color Co., Inc 

Maher Color & Chemical Co 

Mallinckrodt Chemical Works 

Marathon Oil Co., Texas Refining Div 

Marblette Corp 

Marco Chemical Corp 

Marden-Wild Corp 

Marlowe-Van Loan Corp 

Martin-Marietta Corp. : 

Rldgway Color & Chemical Div 

Southern Dyestuff Co. Div 

Max Marx Color & Chemical Co 

Masonlte Corp., Alpine Chemical Div 

Massachusetts Plastic Corp 

Mathe Chemical Co 

Maumee Chemical Co 

Otto B. May, Inc 

MoCloskey Varnish Co 

Medical Chemicals Corp 

Merck & Co., Inc 

Metalead Products Corp 

Metal [fydrldes, Inc 

Metalsalts Corp 

Metro-Atlantic, Inc 

J. Meyer & Sons, Inc 

Michigan Chemical Corp 

Midland Industrial Finishes Co 

Midwest Plastic Products Co 

Miles Laboratories, Inc 

Millmaster Chemical Corp., Berkeley Chemical 
Dept. 

Mineral Oil Refining Co 

Minnesota Mining & Manufacturing Co 

Minnesota Paints, Ino 

Miranol Chemical Co., Inc 

Mississippi Chemical Corp 

Mobay Chemical Co 

Mobil Finishes Co., Inc.: 

American-Marietta Paint Div 

Arco Div 

Ferbert-Schomdorfer Div 

Molded Fiber Glass Body Co., Resin Div 

Mona Industries, Inc 

Monochem, Inc 

Monsanto Co. : 

Chocolate Bayou Plant 

Gering Plastics Dept 

Organic Chemical Div 

Plastics Div 

Western Div 

Montrose Chemical Corp. of California 

Benjamin Moore & Co 



Office address 



1561 Chapin Rd., Jfontebello, Calif. 90640. 

Thompson and Tioga Sts., Philadelphia, Pa. 19134. 

19 S. Canal St., Lawrence, Mass. 01843. 

3550 Touhy Ave., Chicago, 111. 60645. 

2722 N. Hancock St., Philadelphia, Pa. 19133. 

P.O. Box 693, Lebanon, Pa. 17042. 

P.O. Box 1187, Perry Annex, Whittier, Calif. 90604. 

P.O. Box 120, Chestertown, Md. 21620. 

199 Main St., Lodi, N.J. 07644. 

E. Superior St., Alma, Mich. 48801. 

390 Park Ave., New York, N.Y. 10022. 

Howard and Huntington Sts., Philadelphia, Pa. 19133. 

380 Madison Ave., New York, N.Y. 10017. 

P.O. Box 960, Erie, Pa. 16512. 

740 S. Alabama St., Indianapolis, Ind. 46206. 

29400 Lakeland Blvd., Wiokliffe, Ohio 44092. 

427 Washington St., New York, N.Y. 10013. 

Woodbridge Rd. and Randolph Ave., Rahway, N.J. 07065. 

1 Cordello Ave., Central Islip, L.I., N.Y. 11722. 

2385 Richmond Terrace, Staten Island, N.Y. 10302. 

1700 N. Elston Ave., Chicago, 111. 60622. 

P.O. Box 5439, St. Louis, Mo. 63160. 

P.O. Box 1191, Texas City, Tex. 77591. 

37-31 30th St., Long Island City, N.Y. 11101. 

1711 W. Elizabeth Ave., Linden, N.J. 07036. 

500 Columbia St., Somerville, Mass. 02143. 

1511 Joshua Circle, High Point, N.C. 27261. 

75 Front St., Ridgway, Pa. 15853. 

P.O. Box 10098, Charlotte, N.C. 28201. 

192 Colt St., Irvington, N.J. 07111. 

P.O. Box 2392, Gulfport, Miss. 39503. 

West Ave., Ludlow, Mass. 01056. 

169 Millbank St., Lodi, N.J. 07644. 

1310 Expressway Dr., Toledo, Ohio 43608. 

52 Amsterdam St., Newark, N.J. 07105. 

7600 State Rd., Philadelphia, Pa. 19136. 

4122 W. Grand Ave., Chicago, 111. 60639. 

Lincoln Ave., Rahway, N.J. 07065. 

P.O. Box 11005, 2901 Park Blvd., Palo Alto, Calif. 94306. 

12-24 Congress St., Beverly, Mass. 01915. 

200 Wagaraw Rd., Hawthorne, N.J. 07507. 

2072 anith St., Centerdale, R.I. 02911. 

4321 N. 4th St., Philadelphia, Pa. 19140. 

500 N. Bankson St., St. Louis, Mich. 48880. 

P.O. Box 620, E. Water St., Waukegan, 111. 60086. 

3251 Chicago Rd., Steger, 111. 60475. 

1127 Myrtle St., Elkhart, Ind. 46514. 

99 Park Ave., New York, N.Y. 10016. 

P.O. Drawer C, Dickinson, Tex. 77539. 

2501 Hudson Rd., St. Paul, Minn. 55119. 

1101 S. 3d St., Minneapolis, Minn. 55415. 

277 Colt St., Irvington, N.J. 07111. 

P.O. Box 388, Yazoo City, Miss. 39194. 

Penn Uncoln Parkway, W. Pittsburgh, Pa. 15205. 

1630 West Hill St., Louisville, Ky. 40210. 
7301 Bessemer Ave., Cleveland, Ohio 44127. 
12815 Elrawood Ave., Cleveland, Ohio 44111. 
4601 Benefit Ave., Ashtabula, Chio 44004. 
65 E. 23d St., Paterson, N.J. 07509. 
P.O. Box 488, Geismar, La. 70734. 

P.O. Box 711, Alvln, Tex. 77511. 

N. 7th St. and Monroe Ave., Kenilworth, N.J. 07033. 

800 N. Lindbergh Blvd., St. Louis, Mo. 63166. 

812 Monsanto Ave., Springfield, Mass. 01102, and P.O. Box 

1311, Texas City, Tex. 77591. 
9229 E. Marginal Way S., Seattle, Wash. 98108. 
500 S. Virgil Ave., Los Angeles, Calif. 90005. 
548 5th Ave., New York, N.Y. 10036. 



DIRECTORY OF MANUFACTURERS 219 

TABLE 22. --Synthetic organic chemfcals: Directory of manufacturers , 1963 — Continued 



Name of company 



Office address 



Momingstar Paisley, Inc 

Morton Salt Co., Morton Chemical Co. Div — 

Morwear Paint Co 

Motomoo, Inc 

Naloo Chemical Co., Visoo Div 

National Biochemical Co 

National Casein Co 

National Dairy Products Corp.: 

Humko Products Chemical Div 

Sheffield Chemical Co. Div 

National Distillers & Chemical Corp. : 

A-B Chemical Corp 

National Petro Chemical Corp 

U.S. Industrial Chemicals Co. Div 

National Lead Co 

National Plastic Products Co., Inc 

National Polychemicals, Inc 

National Starch & Chemical Corp 

National Vulcanized Fibre Co 

Naugatuok Chemical Div. of U.S. Rubber Co- 

Nease Chemical Co., Inc 

Nelio Chemicals, Inc 

Nepera Chemical Co., Inc 

Neville Chemical Co 

Chlorinated Products Div 

Nilok Chemicals, Inc 

Nitrin, Inc 

Nixon-Baldwin Chemicals, Inc 

A. P. Nonweiler Co 

Nopoo Chemical Co., Inc 

Norac Co., Inc 

Norda Essential Oil & Chemical Co., Inc — 

Norris Paint & Varnish Co 

Norse Chemical Corp 

Northwestern Chemical Co 

Norwich Pharmacal Co 

Nostrip Chemical Works, Inc 

Novamont Corp 

Old Hickory Chemical Co 

Clin Mathieson Chemical Corp 

E. R. Squibb & Sons Div 

Onyx Chemical Corp 

Orbis Products Corp 

Organics, Inc 

Original Bradford Soap Works, Inc 

C. J. Osbom Co 

Ottawa Chemical Co 

Ott Chemical Co 

Ottol Oil Co., Inc 

Owens-Corning Fiberglas Corp 

Oxy Chemical Co 

Pabst Brewing Co 

Pacific Resins & Chemical Co 

Pan American Petroleum Corp 

Pantasote Co 

Paragon Chemicals 

Parke, Davis & Co 

Patent Chemicals, Inc 

Pearsall Chemical Co 

Peck's Products Co 

Peerless Chemical Co 

Pelron Corp 

S. B. Penick & Co 

Parsons -Plymouth Div 

Pennsalt Chemicals Corp 

Pennsylvania Industrial Chemical Corp 

Pennsylvania Refining Co 

Perkins Glue Co 



1770 Canalport Ave., Chicago, 111. 60616. 
110 N. Wacker Dr., Chicago, 111. 60606. 
568 Uth St., Oakland, Calif. 9-4612. 
89 Terminal Ave., Clark, N.J. 07066. 

P.O. Box 87, Sugar Land, Tex. 77478. 
3127 W. Lake St., Chicago, 111. 60612. 
601 W. SOthSt., Chicago, 111. 60620. 

P.O. Box 398, Memphis, Tenn. 38101. 
P.O. Box 630, Norwich, N.Y. 13815. 

99 Park Ave., New York, N.Y. 10016. 

99 Park Ave., New York, N.Y. 10016. 

99 Park Ave., New York, N.Y. 10016. 
Ul Broadway, New York, N.Y. 10006. 
Odenton, m. 21113. 

51 Eames St., Wilmington, Mass. 01887. 

1700 W. Front St., Plainfield, N.J. 07063. 

Maryland Ave. and Beech St., Wilmington, Del. 19899. 

Naugatuck, Conn. 06771. 

P.O. Box 221, State College, Pa. 16801. 

2051 Lane Ave., Jacksonville, Fla. 32205. 

Route 17 and Averill Ave., Harriman, N.Y. 10926. 

Neville Island, Pittsburgh, Pa. 15225. 

Neville Island, Pittsburgh, Pa. 15225. 

Mill St. and N. Transit, Lockport, N.Y. U094. 

P.O. Box 233, Cordova, 111. 61242. 

Nixon, N.J. 08818. 

P.O. Box 1007, Oshkosh, Wis. 54902'. 

60 Park PI., Newark, N.J. 07101. 

405 S. Motor Ave., Azusa, Calif. 91703. 

601 W. 26th St., New York, N.Y. 10001. 

1710 Front St. NE., Salem, Greg. 97303. 

2121 Norse Ave., Cudahy, Wis. 53110. 

120 N. Aurora St., W. Chicago, 111. 60185. 

17 Eaton Ave., Norwich, N.Y. 13815. 

182 Liberty Ave., Jamaica, N.Y. 11412. 

P.O. Box 189, Kenova, W. Va. 25530. 

P.O. Box 3408, Richmond, Va. 23234. 

460 Park Ave., New York, N.Y. 10022, and 445 W. 59th St. 

New York, N.Y. 10019. 
460 Park Ave., New York, N.Y. 10022. 
190 Warren St., Jersey City, N.J. 07302. 
601 W. 26th St., New York, N.Y. 10001. 
1724 Greenleaf Ave., Chicago, 111. 60626. 
200 Providence St., W. Warwick, R.I. 02893. 
1301 W. Blanoke St., Linden, N.J. 07036. 
700 N. Wheeling St., Toledo, Ohio 43605. 
500 Agard Rd., Maskegon, Mich. 49945. 
455 Cortlandt St., Belleville, N.J. 07109. 
National Bank Bldg., Toledo, Ohio 43601. 
P.O^ Box 28, Hackettstown, N.J. 07840. 

917 W. Juneau Ave., >jtLlwaukee, Wis. 53201. 
3400 13th Ave. SW. , Seattle, Wash. 98134. 
P.O. Box 591, Tulsa, Okla. 74102. 
26 Jefferson St., Passaic, N.J. 07056. 
221 Oak St., Providence,' H.I. 02909. 
Foot of Jos. Campau, Detroit, Mich. 48232. 
335 McLean Blvd., Paterson, N.J. 07504. 
P.O. Box 108, Phllllpsburg, N.J. 08865. 
610 E. Clarence Ave., St. Louis, Mo. 63147. 
3850 Oakman Blvd., Detroit, Mich. 48204. 
7847 W. 47th St., Lyons, 111. 60534. 

100 Church St., New York, N.Y. 10008. 
100 Church St., New York, N.Y. 10008. 

3 Penn Center, Philadelphia, Pa. 19102. 
120 State St., P.O. Box 240, Clairton, Pa. 15025. 
Commonwealth Bank & Trust Co. Bldg., Butler, Pa. 16001. 
632 Cannon Ave., Lansdale, Pa. 19446. 



220 



SYNTHETIC ORGANIC CHEMICALS, 1963 
TABLE 22. -Synthetic organic chemicals: Directory of manufacturers , i 963- -Continued 



L. Perrigo Co 

Perry & Derrick Co 

Petroleum Chemicals, Ino 

Petro-Tex Chemical Corp 

Pfanstiehl Laboratories, Inc 

Pfaudler Perrautit, Inc., lonao Chemical Co. Di 

Pfister Chemical Works 

Chas. Pfizer & Co., Inc 

Pharmachem Corp 

Phelan-Faust Paint Manufacturing Co 

Phelan's Resins & Plastics Div 

Phillips Petroleum Co 

Chemical Dept 

Phoenix Oil Co 

Pierce Chemical Co 

Pillsbury Co 

Pilot Chemical Co 

Pioneer Chemical Works, Inc 

Pitt-Consol Chemical Co 

Pittsburgh Chemical Co 

Pittsburgh Plate Glass Co 

Plastics Engineering Co 

Plastics Material & Polymers, Inc 

Plumb Chemical Corp 

Polychemical Laboratories, Inc 

Polymer Corp 

Polymer Industries, Inc 

Poly Resins 

Polyrez Co., Inc 

Polyvinyl Chemicals, Inc 

Pontiac Refining Corp 

Pratt & Lambert, Inc -^ 

Procter & Gamble Co., Procter & Gamble Manu- 
facturing Co. Div. 

Proctor Chemical Co., Inc 

Productol Chemical Co 

Publicker Industries, Inc 

Pure Oil Co 

Purex Corp., Ltd 

Quaker Chemical Products Corp 

Quaker Oats Co 

K. J. Quinn & Co., Inc 

R. S. A. Corp 

Raybestos-Manhattan, Inc., Raybestos Div 

Rayette, Inc 

Raymond Chemical Co 

Red Spot Paint & Varnish Co., Inc 

Refined Products Co 

Reichhold Chemicals, Inc 

Varcum Chemical Div 

Reilly Tar & Chemical Corp 

Reliance Varnish Co 

Coast Paint & Lacquer Co. Div 

Remington Arms Co., Inc 

Retzloff Chemical Co 

Rexall Chemical Co 

Rexall Chemical Co. - Kearny 

Rezolin, Inc 

Rhodia, Inc 

Richardson Co 

Krystall Chemical Corp. Div 

Richardson Polymers Div 

Richfield Oil Corp 

Riker Laboratories, Inc 

Rinshed -Mason Co 

F. Rltter & Co- 

Ritter Chemical Co., Inc 

Rlverdale Chemical Co 

Roberts Chemicals, Ino 

Rock Hill Printing & Finishing Co 



Office address 



Allegan, Mich. "igOlO. 

2510 Highland Ave., Norwood, Ohio 45212. 

P.O. Box 1522, Lake Charles, La. 7060A. 

P.O. Box 258'i, Houston, Tex. 77001. 

1219 Glen Rock Ave., Waukegan, 111. 60086. 

Birmingham, N.J. 08011. 

Linden Ave., Ridgefield, N.J. 07657. 

235 E. 42d St., New York, N.Y. 10017. 

Broad and Wood Sts., Bethlehem, Pa. 18015. 

932 Loughborough Ave., St. Louis, Mo. 63111. 

P.O. Box 189, Burlington, Iowa 52602. 

Bartlesville, Okla. 7<;00'i. 

Bartlesville, Okla. 7'4004. 

9505 Cassius Ave., Cleveland, Ohio 44105. 

P.O. Box 117, Rockford, 111. 61105. 

608 2d Ave. S., Minneapolis, Minn. 55402. 

11756 Burke St., Santa Fe Springs, Calif. 90670. 

940 N. Delaware Ave., Philadelphia, Pa. 19123. 

191 Doremus Ave., Newark, N.J. 07105. 

200 Grant Bldg. , Pittsburgh, Pa. 15219. 

1 Gateway Center, Pittsburgh, Pa. 15222. 

1607 Geele Ave., Sheboygan, Wis. 53082. 

New South Rd., Hicksville, N.Y. 11801. 

4837 James St., Philadelphia, Pa. 19137. 

490 Hunts Point Ave., New York, N.Y. 10474. 

2120 Fairmont Ave., Reading, Pa. 19603. 

Viaduct Rd., Springdale, Conn. 06879. 

11655 Wicks St., Sun Valley, Calif. 91352. 

S. Columbia St., Woodbury, N.J. 08096. 

26 Howley St., Peabody, Mass. 01961. 

P.O. Box 1581, Corpus Christi, Tex. 78403. 

75 Tonawanda St., Buffalo, N.Y. 14207. 

Ivorydale Technical Center, Cincinnati, Ohio 45217. 

P.O. Box 399, Salisbury, N.C. 28144. 
615 S. Flower St., Los Angeles, Calif. 90017. 
1429 Walnut St., Philadelphia, Pa. 19102. 
200 E. Gulf Rd., Palatine, 111. 60067. 
5101 Clark Ave., Lakewood, Calif. 90712. 

Elm, Lime, and Sandy Sts., Conshohocken, Pa. 19428. 
Merchandise Mart Plaza, Chicago, 111. 60654. 
195 Canal St., Maiden, Mass. 02148. 

690 Saw Mill River Rd., Ardsley, N.Y. 10502. 

P.O. Box 1021, Bridgeport, Conn. 06601. 

261 E. 5th St., St. Paul, Minn. 55101. 

401 E. Broadway, Swanton, Ohio 43558. 

110 Main St., Evansville, Ind. 47708. 

624 Schuyler Ave., limdhurst, N.J. 07071. 

525 N. Broadway, White Plains, N.Y. 10602. 

Niagara Falls, N.Y. 14302. 

1615 Merchants Bank Bldg., Indianapolis, Ind. 46204. 

4730 Crittenden Dr., Louisville, I^. 40221. 

6901 Cavalcade, Houston, Tex. 77001. 

939 Bamum Ave., Bridgeport, Conn. 06602. 

P.O. Box 45296, Houston, Tex. 77045. 

8480 Beverly Blvd., Los Angeles, Calif. 90054. 

1106 Harrison Ave., Kearny, N.J. 07029. 

1651 18th St., Santa Monica, Calif. 90404. 

60 E. 56th St., New York, N.Y. 18901. 

27th Ave. and Lake St., Melrose Park, 111. 60160. 

27th Ave. and Lake St., Melrose Park, 111. 60160. 

345 Morgan Lane, West Haven, Conn. 06516. 

555 S. Flower St., Los Angeles, Calif. 90054. 

19901 Nordhoff St., Northridge, Calif. 91326. 

5935 Milford Ave., Detroit, Mich. 48210. 

4001 Goodwin Ave., Los Angeles, Calif. 90039. 

403 W. Main St., Amsterdam, N.Y. 12011. 

220 E. 17th St., Chicago Heights, 111. 60411. 

P.O. Box 546, Nitro, W. Va. 25143. 

Rock Hill, S.C. 29731. 



DIRECTORY OF MANUFACTURERS 221 

TABLE 22. — Synthetic organic chemicals: Directory of manufacturers, 7 963- -Continued 



Name of company 



Office address 



Rockland Jndug tries 

Roehr Chemicals, "In&.^ 

Rogers Corp --' — 

Rohm & Haas Co 

Roma Chemical Corp 

Rosenberg Bros. & Co 

Rosett Chemicals, Ino 

Rowland Products, Inc 

Royoe Chemical Co 

Rozilda Laboratories, Inc 

Rubber Corp. of America 

Ruberoid Co 

St. Regis Paper Co., Lake States Yeast 

Chemical Div. 

Dr. Salsbury's Laboratories 

Sandoz, Inc 

Dyestuff Div., Pigment Dept 

Sartomer Resins, Inc 

Schaefer Varnish Co., Ino 

Schenectady Chemicals, Inc 

Scher Bros 

R. P. Scherer Corp 

Schering Corp 

Scholler Bros., Inc 

Schuylkill Chemical Co 

Schwarz Bioresearch, Inc 

Seaboard Chemicals, Inc 

G. D. Searle & Co 

Seidlitz Paint & Varnish Co 

Seydel-Woolley & Co., Inc 

Shamrock Oil & Gas Corp 

Shawinigan Resins Corp 

Shell Oil Co - 

Shell Chemical Co. Div 

Shepherd Chemical Co 

Sherwin-Williams Co 

Shulton, Inc., Fine Chemicals Div 

George F. Slddall Co., Ino 

Signal Oil & Gas Co., Houston Div 

Silmar Chemical Corp 

Simpson Timber Co 

Sinclair Koppers Chemical Co 

Sinclair Petrochemicals, Inc 

Sinclair Refining Co 

James B. Sipe & Co 

Skelly Oil Co — 

G. Frederick Smith Chemical Co 

Smith, Kline & French Laboratories 

Socony Mobil Oil Co., Inc. : 

Mobil Chemical Co. Div 

Mobil Oil Co. Div 

Virginia-Carolina Chemical Co. Div — 

Socony Paint Products Co 

Sohio Chemical Co., Agent: 

Sohio Petroleum Co 

Solar Nitrogen Chemicals, Inc 

Solar Chemical Corp 

Soluol Chemical Co., Inc 

Solvent Chemical Co., Inc 

Sonnebom Chemical & Refining Corp 

Sonooo Products Co 

Sou-Tex Chemical Co., Ino 

Southern Nitrogen Co., Inc 

Southern Sizing Co 

South Hampton Co 

Spaulding Fibre Co., Inc 

Spencer Chemical Co 

Stahl Finish Co 

A. E. Staley Manufacturing Co 

UBS Chemical Co. Div 

Stamford Chemical Co 



Mayflower Dr., W. Hanover, Mass. 02380. 

52-20 37th St., Long Island City, N.Y. 11101. 

Mill St., Rogers, Conn. 06263. 

222 W. Washington Sq. , Philadelphia, Pa. 19105. 

900 Passaic Ave., E. Newark, N.J. 07029. 

100 Landing Ave., Smithtown, N.Y. 11787. 

6'i9 Ferry St., Newark, N.J. 07105. 

Fairview Lane, Kensington, Conn. 06037. 

Carlton Hill P.O., E. Rutherford, N.J. 07073. 

314 Madison St., Hoboken, N.J. 07030. 

New South Rd., Hicksville, N.Y. 11802. 

S. Bound Brook, N.J. 



603 W. Davenport St., Rhinelander, Wis. 5'i501. 

500 Gilbert St., Charles City, Iowa 50616. 

P.O. Box 357, Fair Lawn, N.J. 07-^10. 

61-63 Van Dam St., New York, N.Y. 10013. 

32d and Spring Garden Sts., Philadelphia, Pa. 19104. 

15th and Magnolia Sts., Louisville, Ky. 40210. 

Congress St. and 10th Ave., Schenectady, N.Y. 12301. 

P.O. Box 538, Allwood Station, Clifton, N.J. 07012. 

9425 Grinnell Ave., Detroit, Mich. 48213. 

1011 Morris Ave., Union, N.J. 07083. 

Collins and Westmoreland Sts., Philadelphia, Pa. 19134. 

2346 W. Sedgley Ave., Philadelphia, Pa. 19132. 

Mountain View Ave., Orangeburg, N.Y. 10962. 

30 Foster St., Salem, Mass. 01971. 

P.O. Box 5110, Chicago, 111. 60680. 

18th and Garfield, Kansas City, Mo. 64141. 

P.O. Box 2345, Atlanta, Ga. 30318. 

P.O. Box 631, Amarillo, Tex. 79105. 

644 Monsanto Ave., Springfield, Mass. 01101. 

50 W. 50th St., New York, N.Y. 10020. 

110 W. 51st St., New York, N.Y. 10020. 

2803 Highland Ave., Cincinnati, Ohio 45212. 

101 Prospect Ave., NW. , Cleveland, Ohio 44101. 

697 Route 46, Clifton, N.J. 07015. 

P.O. Box 925, Spartanburg, S.C. 29301. 

P.O. Box 5008, Harrisburg Station, Houston, Tex. 77012. 

12335 S. Van Ness Ave., Hawthorne, Calif. 90250. 

2301 N. Columbia Blvd., Portland, Oreg. 97217. 

P.O. Box 5536, Houston, Tex. 77012. 

600 5th Ave., New York, N.Y. 10020. 

600 5th Ave., New York, N.Y. 10020. 

P.O. Box 8010, Pittsburgh, Pa. 15216. 

P.O. Box 1650, Tulsa, Okla. 74102. 

867 McKinley Ave., Columbus, Ohio 43222. 

1500 Spring Garden St., Philadelphia, Pa. 19101. 

150 E. 42d St., New York, N.Y. 10017. 

612 S. Flower St., Los Angeles, Calif. 90054, and 

P.O. Box 3311, Beaumont, Tex. 77704. 
401 E. Main St., Richmond, Va. 23208. 
Metuohen, N.J. 08840. 

621 Republic Bldg. , Cleveland, Ohio 44115. 

621 Republic Bldg., Cleveland, Ohio 44115. 

Solar Park, Leominster, Mass. 01453. 

Green Hill and Market Sts., W. Warwick, R.I. 02893. 

341 Commercial St., Maiden, Mass. 02148. 

300 Park Ave. S. , New York, N.Y. 10010. 

Hartsville, S.C. 29550. 

E. Catawba Ave., Mount Holly, N.C. 28120. 

P.O. Box 246, Savannah, Ga. 31402. 

P.O. Box 391, East Point, Ga. 30044. 

P.O. Box 6966, Houston, Tex. 77005. 

310 Wheeler St., Tonawanda, N.Y. 14152. 

610 Dwight Bldg., Kansas City, Mo. 64105. 

26 Howley St., Peabody, Mass. 01960. 

N. 22d and Eldorado Sts., Decatur, 111. 62525. 

491 Main St., Cambridge, Mass. 02142. 

45 Jefferson St., P.O. Box 1131, Stamford, Conn. 06940. 



222 



SYNTHETIC ORGANIC CHEMICALS 1963 



TABLE 22. — Synthetic organic chemicals: Directory of manufacturers , i 565 --Continued 



Name of company 



Office address 



Standard Brands, Inc., Clinton Com Processing 
Co. Div. 

Standard Chemical Products, Ino 

Standard Chlorine Chemical Co., Inc 

Standard Dyestuff Corp 

Standard Naphthalene Products Co., Inc 

Standard Oil Co. of California, Western 
Operations, Inc. 

Standard Oil Co. of Ohio-- 

Standard Pyroxoloid Corp 

Standard Ultramarine & Color Co 

Wm. J. Stange Co 

Stauffer Chemical Co 

Anderson Chemical Co. Div 

Calhio Chemicals Div 

Victor Chemical Works Div 

Stecker Chemicals, Inc 

Stein, Hall & Co., Inc 

Stepan Chemical Co 

Maywood Div 

Sterling Drug, Inc . : 

Glenbrook Laboratories Div 

Hilton-Davis Chemical Co. Div 

Salvo Chemical Div 

Thomasset Colors Div 

Winthrop Laboratories Div 

Fred'k A. Stresen-Reuter, Inc 

Summit Chemical Products Corp 

Sun Chemical Corp., Warwick Chemical Co. Div — 

Sunkist Growers, Ino 

Sun Oil Co 

SunOlin Chemical Co 

Sunray DX Oil Co 

Suntide Refining Co 

Swift & Co 

Switzer Bros., Inc 

Synco Resins, Inc 

Synthetic Chemicals, Inc 

Synthetic Products Co 

Synthron, Inc 

Synvar Corp 

Tanatex Chemical Corp 

Charles S. Tanner Co 

Taylor Corp 

Tennant Development Corp., Chemical Div 

Tenneco Oil Co 

Tennessee Corp 

Texaco, Ino 

Texas Alkyls, Ino 

Texas-U.S. Chemical Co 

Tex Chemical Co 

Texize Chemicals, Inc 

Thiokol Chemical Corp 

Thomason Industries, Inc., Southern Resin Div — 

Thompson Chemical Co 

Thompson-Hayward Chemical Co 

Tioonderoga Chemical Corp 

Tidewater Oil Co 

Toms River Chemical Corp 

Tousey Varnish Co 

Arthur C. Trask Co 

Triangle Chemical Co 

Trojan Powder Co 

Troy Chemical Co 

Trylon Chemical Corp 

Joseph Turner & Co 

Paul Uhlioh & Co., Inc 

Ungerer & Co 

Union Carbide Corp. : 

Chemicals Div 

Plastics Div 

Silicones Div 



Clinton, Iowa 52733. 

1301 Jefferson St., Hoboken, N.J. 07030. 

1015 Belleville Turnpike, S. Kearny, N.J. 07032. 

19 E. 5th St., Paterson, N.J. 07524. 

1015 Belleville Turnpike, S. Kearny, N.J. 07032. 

P.O. Box AAQ, San Francisco, Calif. 94120. 

Midland Bldg., Cleveland, Ohio 44115. 

85 Pleasant St., Leominster, Mass. 01453. 

P.O. Box 2166, Huntington, W. Va. 25722. 

342 N. Western Ave., Chicago, 111. 60612. 

380 Madison Ave., New York, N.Y. 10017. 

380 Madison Ave., New York, N.Y. 10017. 

380 JvIadiEon Ave., New York, N.Y. 10017. 

380 Madison Ave., New York, N.Y. 10017. 

50 North Franklin Turnpike, Ho-Ho-Kus, N.J. 07423. 

605 3d Ave., New York, N.Y. 10016. 

R.R. No. 1, Elwood, 111. 60421. 

100 W. Hunter Ave., Maywood, N.J. 07607. 

1450 Broadway, New York, N.Y. 10018. 

2235 Langdon Farm Rd., Cincinnati, Ohio 45237. 

Military Rd., Rothschild, Wis. 54474. 

120 Lister Ave., Newark, N.J. 07105. 

1450 Broadway, New York, N.Y. 10018. 

400 W. Roosevelt Ave., Bensenville, 111. 60106. 

11 William St., Belleville, N.J. 07109. 

Wood River Junction, R.I. 02894. 

707 W. 5th St., Los Angeles, Calif. 90017. 

1608 Walnut St., Philadelphia, Pa. 19103. 

1608 Walnut St., Philadelphia, Pa. 19103. 

P.O. Box 2039, Tulsa, Okla. 74102. 

P.O. Box 658, Corpus Christi, Tex. 78403. 

115 W. Jackson Blvd., Chicago, 111. 60604. 

4732 St. Clair Ave., Cleveland, Ohio 44103. 

30 Henry St., Bethel, Conn. 06801. 

335 McLean Blvd., Paterson, N.J. 07504. 

1636 Wayside Rd., Cleveland, Ohio 44112. 

Ryan Ave., Ashton, R.I. 02805. 

726 King St., Wilmington, Del. 19801. 

P.O. Box 388, Lyndhurst, N.J. 07071. 

250 S. Water St., Providence, R.I. 02901. 

Valley Forge, Pa. 19481. 

100 Park Ave., New York, N.Y. 10017. 

P.O. Box 2511, Houston, Tex. 77001. 

61 Broadway, New York, N.Y. 10006. 

P.O. Box 52332, Houston, Tex. 77052. 

P.O. Box 988, Pasadena, Tex. 77501. 

P.O. Box 667, Port Neches, Tex. 77651. 

20-21 Wagaraw Rd., Fair Lawn, N.J. 07412. 

P.O. Box 368, Greenville, S.C. 29602. 

P.O. Box 27, Bristol, Pa. 19007. 

P.O. Box 352, Fayetteville, N.C. 28302. 

90 Mendor Ave., Pawtucket, R.I. 02862. 

P.O. Box 768, Kansas City, Mo. 64141. 

P.O. Box 11, Leominster, Mass. 01453. 

Delaware City, Del. 19706. 

P.O. Box 71, Toms River, N.J. 08753. 

135 W. Lake St., North Lake, 111. 60164. 

327 S. LaSalle St., Chicago, 111. 60604. 

206 Lower Elm St., Macon, Ga. 31202. 

17 N. 7th St., Allentown, Pa. 18105. 

338 Wilson Ave., Newark, N.J. 07105. 

P.O. Box 5101, Station B, Greenville, S.C. 29606. 

P.O. Box 88, Ridgefield, N.J. 07451. 

90 West St., New York, N.Y. 10006. 

161 Avenue of the Americas, New York, N.Y. 10013. 

270 Park Ave., New York, N.Y. 10017. 
270 Park Ave., New York, N.Y. 10017. 
270 Park Ave., New York, N.Y. 10017. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. -Synthetic organic chemicals: Directory of manufacturers , 1963 — Continued 



223 



Name of company 



Office address 



Union Oil Co. of California 

United Carbon Co 

United Chemical Corp. of Norwood 

United Chemical Products Corp 

United Cork Companies 

U.S. Borax Research Corp 

U.S. Oil Co - 

U.S. Peroxygen Corp 

United States Pipe & Foundry Co 

U.S. Plastic & Chemical Corp 

United States Plywood Corp 

Universal Chemicals Corp 

Universal Detergents, Inc. & Petrochemicals Co- 
Universal Oil Products Co 

Trubek Chemical Co. Div 

Upjohn Co 

Carwin Co. Div 

Utah Resin Co., Inc 

Valchem 

Valentine Sugars, Inc., Valite Div 

Vanderbilt Chemical Corp 

Van Dyk & Co., Inc 

Vamey Chemical Co 

Velsiool Chemical Corp 

Tensyn Div 

Vermi lye-Bell 

Verona-Pharma Chemical Corp 

Vickers Refining Co., Inc 

Vineland Chemical Co 

Vitamins, Inc 

Vita-Var Corp., Div. of Textron Industries, Inc 
Vulcan Materials Co., Frontier Chemical Co. Div 

Wallace & Tieman, Inc 

Harchem Div 

Lucidol Div 

Wamer-Jenkinson Manufacturing Co 

Warren Paint Sc Color Co 

Washbum-Purex Co 

Washine Chemical Corp 

Wayland Chemical Co 

West Coast Adhesives Co 

Western Dry Color Co 

Westlnghouse Electric Corp., Micarta Div 

West Virginia Pulp & Paper Co., Polychemicals 
Div. 

Weyerhaeuser Co., Wood Products Div 

White & Bagley Co 

White & Hodges, Inc 

White laboratories, Inc 

Whltmoyer laboratories, Inc 

Whlttemore-Wright Co., Inc 

Wica Chemicals, Inc 

Wilmot & Cassidy, Inc 

Wilson & Co., Inc. : 

Wilson laboratories Div 

Wilson-Martin Div 

Witco Chemical Co., Inc 

W. A. Wood Co 

Wood Ridge Chemical Corp 

Woonsocket Color & Chemical Co 

Wyandotte Chemicals Corp 

Young Aniline Works, Inc 



461 S. Boylston St., Los Angeles, Calif. 90017. 

P.O. Box 149, Baytown, Tex. 77520. 

P.O. Box 327, Endioott St., Norwood, Mass. 02062. 

York and Colgate Sts., Jersey City, N.J. 07302. 

50 Central Ave., Kearny, N.J. 07032. 

3075 Wilshire Blvd., Ijos Angeles, Calif. 90005. 

P.O. Box 4228, E. Providence, R.I. 02914. 

850 Morton Ave . , Richmond, Calif. 94804. 

3300 1st Ave. N., Birmingham, Ala. 35202. 

122 E. Railroad Ave., W. Haverstraw, N.Y. 10927. 

P.O. Box 1688, Redding, Calif. 96002. 

48 Hunt St., Central Falls, R.I. 02863. 

1825 E. Spring St., Long Beach, Calif. 90806. 

30 Algonquin Rd., Des Plaines, 111. 60018. 

State Highway 17, E. Rutherford, N.J. 07073. 

7000 Portage- Rd., Kalamazoo, Mich. 49001. 

Stiles Lane, North Haven, Conn. 06473. 

418 Keams Bldg., Salt Lake City, Utah 84101. 

1407 Broadway, New York, N.Y. 10018. 

726 Whitney Bldg., New Orleans, La. 70130. 

230 Park Ave., New York, N.Y. 10017. 

11 William St., Belleville, N.J. 07109. 

2001 Afton fid., Janesville, Wis. 53545. 

330 E. Ohio St., Chicago, 111. 60611. 

4902 Central Ave., Chattanooga, Tenn. 37410. 

21707 Bothell Way, Bothell, Wash. 98011. 

P.O. Box 385, Union, N.J. 07083. 

P.O. Box 2240, Wichita, Kans. 67201. 

W. Wheat Rd., Vineland, N.J. 08360. 

809 W. 58th St., Chicago, 111. 60621. 

177 Oakwood Ave., Orange, N.J. 07050. 

P.O. Box 545, Wichita, Kans. 67201. 

25 Main St., Belleville, N.J. 07109. 
25 Main St., Belleville, N.J. 07109. 
1740 Military Rd., Buffalo, N.Y. 14240. 
2526 Baldwin St., St. Louis, Mo. 63106. 
700 Wedgewood Ave., Nashville, Tenn. 37202. 
2244 Elston Ave., Chicago, 111. 60614. 
165 Main St., Lodi, N.J. 07644. 
Industrial Circle, Lincoln, R.I. 02865. 
11104 NW. Front Ave., Portland, Oreg. 97208. 
600 W. 52d St., Chicago, 111. 60609. 
Trafford, Pa. 15085. 
P.O. Box 5207, N. Charleston, S.C. 29406. 

118 S. Palmetto St., Marshfield, Wis. 54449. 
P.O. Box 1171, Worcester, Mass. 01601. 
576 Lawrence St., Lowell, Mass. 01852. 
Galloping Hill Rd., Kenilworth, Pa. 07033. 
19 N. Railroad St., Jfyerstown, Pa. 17067. 
62 Alford St., Boston, Mass. 02129. 
P.O. Box 506, Charlotte, N.C. 28201. 
108 Provost St., Brooklyn, N.Y. 11222. 

4221 S. Western Blvd., Chicago, 111. 60609. 

Snyder Ave. and Swanson St., Philadelphia, Pa. 19148. 

P.O. Box 305, Paramus, N.J. 07652. 

108 Spring St., Everett, Mass. 02149. 

Park PI. E., Wood Ridge, N.J. 07075. 

176 Sunnyside Ave., Woonsocket, R.I. 02895. 

1609 Biddle Ave., Wyandotte, Mich. 48193. 

2731 Boston St., Baltimore, Md. 21224. 



APPENDIXES 

A. U. S. Imports of Coal-Tar Intermediates 
and Finished Coal -Tar Products 

Table 23 summarizes, for the period 1961-63, U.S. imports of coal-tar products dutiable 
under paragraphs 27 and 28 of the Tariff Act of 1930.^ The data, which were obtained by analyz- 
ing invoices covering imports through all U.S. customs districts, are given in detail in a sepa- 
rate report of the Tariff Commission.^ 

In 1963, general imports of coal-tar chemicals entered under paragraph 27 comprised 778 
items with a total weight of 29. 1 million pounds, and a foreign invoice value of $16. 7 nnillion. In 
1962, imports consisted of 806 items with a total weight of 21.3 million pounds, valued at $14. 2 
million. About half of the coal-tar chemicals imported in 1963 were declared to be competitive 
(duty based on "American selling price"). In terms of quantity, about 34 percent of the total imports 

TABLE 23. — Coal-tar intermediates and finished coal-tar products: U.S. general imports, classified by use, 

1961-63 



^entity 



Foreign 
invoice 
value 



(Jiantity 



Foreign 
invoice 
value 



Quantity 



Foreign 
Invoice 
value 



Intermediates •'- 



Finished coal-tar products, total 

Dyes, total 

Acid 

Azoic compositions 

Basic 

Direct 

Disperse 

Fiber-reactive 

Fluorescent brightening agents 

Ingredn 

Jfordant 

Solvent 

Sulfur 

Vat 

All other 

Synthetic organic pigments (toners and 

lakes) 

Sfedicinals and pharmaceuticals 

Flavor and perfume materials 

All other 



pounds 
19,C29 

12,393 



5,152 

1,313 

5 

439 

771 

177 

1,003 

424 

20 

112 

55 

4 

702 

127 

278 
2,579 

779 
3,605 



1,00(1 
dollars 
12,339 

25,950 

11,060 

2,938 

12 

812 

1,640 

403 

2,716 

936 

125 

238 

172 

3 

845 

220 

803 

10,885 

1,339 

1,863 



1 . 000 
pounds 
21,300 

12,823 



5,416 
1,545 

5 

403 

1,014 

183 

373 

438 

5 

241 

85 

319 

769 

36 

402 
2,988 
1,368 
2,649 



1 , 000 
dollars 
14,193 

24,908 



1.000 



10,997 

3,227 

9 

831 

2,254 

426 

1,004 

1,182 

26 

489 

253 

296 

970 

30 

1,058 j 
8,839 
2,206 
1,808 



29,131 
16,227 



7,626 

1,712 

13 

456 

950 

454 

395 

82 

5 

232 

112 

29 

3,163 

23 

363 
2,961 
1,957 
3,320 



1,000 
dollars 
16,686 

26,923 

11,208 

3,718 

23 

892 

2,121 

904 

1,028 

425 

15 

459 

380 

16 

1,187 

40 

616 

10,150 
2,862 
2,087 



^ Includes small quantities of organic pesticides and agricultural chemicals, rubber-processing chemicals, and 
surf ace -active agents. 



Source: Compiled from the records of the U.S. Bureau of Customs. 



Sf 



^ To ilmpUfy the sutitUcal dlKunion and tucUUcal tablet In thii report, imporu for the year 1963 are refened to a> Imporu entered un- 
der par. 27 or par. 28, even though coal-tar producu entered for coosumpUon during the Ian 4 raonthi of 1963 were entered under the pro- 
vlsioni of the new Tariff Schedules of the United Sutes, which became effective on Aug. 31, 1963. Import natlnlci for the Lait 4 monthj 
of 1963 are not itrlctly comparable with those for the first 8 months. The differences resulting from the above-mentioned change are small, 
however, so that comparljoiu between the dau for 1963 and those for earlier years are meanlngfuL 

2 Imports of Coal-Tor Products, /963,TC Publication 131, 1964 [processed]. 



225 



226 SYNTHETIC ORGANIC CHEMICALS, 1963 

of these products in 1963 came from West Germany; imports from that country amounted to 9. 9 
million pounds, connpared with 11.5 million pounds in 1962. In 1963, imports from Canada 
amounted to 7. 3 million pounds, compared with 432, 000 pounds in 1962. Imports from Japan 
amounted to 3. 1 million pounds, compared with 1. 6 million pounds in 1962. Imports from the 
United Kingdom totaled 2. 8 million pounds in 1963, compared with 3. million pounds in 1962; 
and imports from Italy amounted to 2.4 million pounds in 1963, compared with 1.2 million 
pounds in 1962. In 1963, sizable quantities of intermediates also were imported from Switzer- 
land (1, 248, 000 pounds), France (592, 000 pounds), Denmark (523, 000 pounds), and the Nether- 
lands (523,000 pounds). Smaller quantities came from Belgium (454,000 pounds), and Sweden 
(227, 000 pounds). 

The most important intermediates imported in 1963 were tridecylbenzene, adiponitrile, poly- 
alkylbenzene, refined anthracene, maleic hydrazide, anthraquinone, acetoacetanilide, 2-naphthol, 
3 -hydroxy-2 -naphthoic acid (BON), 8-amino- 1 -naphthol-3, 6-disulfonic acid (H-acid), phthalic 
anhydride, methyl parathion, and refined naphthalene (see table 3). In 1963, imports of tridec- 
ylbenzene, which amounted to 5. 1 million pounds, and of adiponitrile, which totaled 2.2 million 
pounds, all came from Canada; imports of polyalkylbenzene, which amounted to 1.4 million 
pounds, all came from Italy. Imports of refined anthracene, which came from West Germany 
and Switzerland, totaled 732,000 pounds in 1963; imports of maleic hydrazide, which came from 
Japan and West Germany, amounted to 701,000 pounds; imports of anthraquinone, which came 
from the United Kingdom, Japan, France, and West Germany, totaled 674,000 pounds; and im- 
ports of acetoacetanilide, which came from the United Kingdom, Switzerland, West Germany, 
and Japan, amounted to 508, 000 pounds. Imports of 2-naphthol, which came from West Germany, 
Japan, and the United Kingdom, totaled 508,000 pounds; imports of BON, which came from Italy, 
West Germany, and Japan, amounted to 479,000 pounds; imports of H-acid, which came from 
West Germany and the Netherlands, amounted to 453, 000 pounds; imports of phthalic anhydride, 
which came from Japan, Italy, and Belgium, totaled 441,000 pounds; and imports of methyl 
parathion, which all came from Denmark, totaled 436, 000 pounds. Imports of refined naphtha- 
lene, which came from Belgium, the Netherlands, France, West Germany, the United Kingdom, 
and Canada, amounted to 420,000 pounds. Among the other important individual chemicals im- 
ported, p-toluenesulfonamide all came from Japan, and cyclohexylamine and adipic acid came 
principally from West Germany. 

Imports in 1963 of all finished coal-tar products that are dutiable under paragraph 28 com- 
prised 1,874 listed items, with a total weight of 16.2 million pounds and a foreign invoice value 
of $26. 9 million. In 1962, imports consisted of 1, 903 items, with a total weight of 12. 8 million 
pounds and a foreign invoice value of $24.9 million. Imports of dyes announted to $11.2 million 
(foreign invoice value), or 41. 6 percent of the value of all imports under paragraph 28. In 1962, 
imports of dyes (excluding synthetic organic pigments) amounted to $11.0 million (foreign in- 
voice value), or 44. 2 percent of the value of all imports under paragraph 28. 

Imports of medicinals and pharmaceuticals, the next most important group of products en- 
tered under paragraph 28 in 1963, were about the same in that year as in 1962 and 15 percent 
larger than in 1961. In 1963, imports of medicinals and pharmaceuticals were valued at $10.2 
million (foreign invoice value), or 38 percent of the total value of imports under paragraph 28. 
In 1962, imports of medicinals and pharmaceuticals were valued at $8.8 million, or 35 percent 
of the total value of imports under paragraph 28. In 1963, imports of synthetic organic pigments 
(toners and lakes) were valued at $616,000, compared with $1,058,000 in 1962. Imports of flavor 
and perfume materials in 1963 ($2.9 million) were 30 percent greater than in 1962 ($2.2 million). 
In 1963, imports of other coal-tar products entered under paragraph 28 (chiefly synthetic resins) 
were valued at $2. 1 million, compared with $1. 8 million in 1962. 

B. Glossary of Synonymous Names of Cyclic Intermediates 

Many cyclic intermediates are known in the chemical industry and trade by a variety of 
names. Individuals in the industry and trade frequently are not acquainted with all the synonymous 
names for a given product. To bring together the synonymous names for each product, the tables 
on intermediates in this report (table 7A in pt. U and table 7B in pt. Ill) show the standard name, 
in accordance with the system used by Clu-mical Ujstrarts. the standard name is frequently fol- 
lowed by the nnost common synonymous name in parentheses. 

In this report, as in previous reports in this series, the Tariff Commission has included a 
glossary of synonymous names of cyclic intermediates. This glossary, which was originally 
compiled at the suggestion of the Industry Advisory Committee on Government Reports, is in- 
tended to serve principally as an index to the standard names used in the statistical tables on in- 
termediates. The first column of the glossary lists alphabetically the common, or trivial, names 
usually encountered in the trade. The second column gives the corresponding standard (Chemical 
Abstracts) names, under which the data are presented in tables 7A and 7B. 



APPENDIX B 
Cyclic intermediates: Glossary of synonymous names 



227 



Caramon name 



Standard (Chemical Abstracts) name 



Acedianthrone 

1, 2-Acenaphthenedione 

4-Acetamido-2-aminophenol hydrochloride 

p-Acetamidobenzenesulf onyl chloride 

5-Acetamido-2-hydroxybenzoic acid 

l-Acetainido-2-methoxynaphthalene 

l-Acetamido-2-naphthol 

l-Acetamido-7-naphthol 

2-Acetamido-A-nitrophenol 

5-Acetamido-orthanilic acid 

Acetanilide-p-sulfonic acid 

Acetanilid sulfon chloride 

Acetate leuco violet 

p-Aoetoacetchloranilide 

Acetoaoet-o-chloroanilide 

o-Acetoacetochloroanilide 

Acetoaceto-1-naphthylamide 

N-Acetoaceto-1-naphthylamine 

m-Acetoacetoxylidide 

Acetoacet-o-toluidide 

Acetoacet-o-toluidine 

Acetoacetyl-o-anisidine 

Acetoacetyl benzidine 

Acetyl-p-amlno-o-aminophenol hydrochloride 

l-Ace^yl-3-('»-anlno-m-anleyl)\rrea 

Acetylamino Cleve's acid 

N-Acetyl-l-amino-8-naphthol-3,6-disulfonic acid 

Acetyl-o-anisidine 

Acetyl-p-anisidine 

Acetyldiaminoanthraquinone 

Acetyl-2,A-diaminophenol hydrochloride 

Acetyl H acid 

Acetyl-l,'C-naphthalenediamine-6(and 7)-sulfonic acids 

Acetyl-p-nitro-o-aminophenol 

Acetyl-m-phenylenediamine 

Acetyl-p-phenylenedi amine 

Acetyl-p-phenylenedi amine sulfate 

N*-Acetyl-N'''-2-pyTimidinylsulf anllamide 

Acetylsulfadiazine 

Acetylsulf amerazine 

Acetylsulf amethazine 

N-"-- Acetylsulf anilamide 

N*- Acetylsulf anilamide 

2- (N* -Acetylsulf anilamido)thiazole 

Acetylsulfathiazole 

N*-Acetyl-2-su If o-p-phenylenedi amine 

N-Acetyl-o-toluidine 

l,2,A-Aoid — 

Amichin 

m-Aminoacetanilide 

p-Aminoacetanilide 

p-Aminoacetanilide sulfate 

m-Ami noacetophenone 

6-(p-Amlnoanlllno)metanilic acid 

p-Amlnoazobenzene 

Aminoazobenzene disulfo acid 

Aniinoazobenzene-3,A-disulfonic acid 

p-Aminoazobenzene hydrochloride 

Amlnoazobenzene-m-sulfonic acid 

Aminoazobenzene-p-sulfonic acid 

o-Aminoazotoluene 

o-Aminoazotoluene sulfate 

4— Aminoazotoluene-4-sulfonic acid and salt 

o-AminoazotoluenesuLfonic acid and salt 



Aceanthra[ 2,1-a] aceanthrylene-5,13-dione. 
Acenaphthenequinone . 

3 '-Amino-'i '-hydroxyacetanllide hydrochloride . 
N-Acetylsulfanilyl chloride. 
5-Acetamidosalicylic acid. 
N-(2-Methoxy-l-naphthyl)acet amide. 
N-(2-Hydroxy-l-naphthyl)acet amide. 

N- (7-Hydroxy- 1-naphthyl ) acet amide . 

2 -Hydroxy-5 -nitroacetanilide. 

5-Aeetamido-2-aniiTinbenzenesulfonic acid. 

N-Acetylsulfanilic acid. 

N-Acetylsulfanilyl chloride. 

1, <i-Diamino-2, 3-dihydroanthraquinone . 

"C'-Chloroacetoacetanilide. 

2 ' -Chloroacetoacet ani lide . 

2 ' -Chloroacetoacetanilide . 

N-1-Naphthylacetoacetamide . 

N-1-Naphthylacetoacetamide. 

2 ,A -Acetoacetoxylidide. 
o- Acetoacetotoluidide . 
o-Acetoacetotoluidide. 

o- Acetoacetanisidide . 

4 ,<i -Biacetoacetanilide. 

3 -Amino-4 -hydroxyacetanllide hydrochloride. 
l-Acetyl-3-(A-amlno-3-methoxyphenyl)urea. 
8-Acetamido-5-amino-2(and 3)-naphthalenesulfonic acid. 
8-Acetamido-l-naphthol-3,6-disulfonic acid. 
o-Acetanisidide. 

p-Acetanisidide . 

lj5(or l,8)-Diacetainidoanthraqulnone. 

3 -Amino-'i -hydroxyacetanllide hydrochloride. 

8-Acetamido-l-naphthol-3,6-dlsulfonic acid. 

8-Acetamido-5-amino-2(and 3)-naphthalenesulfonic acid. 

2' -Hydroxy-5' -nitroacetanilide . 

3 '-Aminoacetanllide . 

A ' - Aminoacet ani lide . 

p-Aminoacetanilide sulfate. 

A '- ( 2-Pyrimidinylsulf amoyl ) acetani lide . 

■4'-(2-Pyrtmldlnylsulfamoyl) acetanlllde. 

A ' - ( 4-Methyl-2-pyrimidinylsu If amoyl ) acetani lide . 

A -('l,6-Dimethyl-2-pyrimidinylsu If amoyl) acet ani lide. 

N-Sulf anllylacetanlde . 

4 ' -Su If amoylacetani lide . 

4'-(2-Thiazolylsulf amoyl)acetanilide. 

4 '- ( 2-Thiazolylsulf amoyl ) acet ani lide . 

5-Acetamido-2-aminobenzenesulf onic acid. 

o-Acetotoluidide. 

l-Amino-2-naphthol-A-sulfonio acid. 

8-Amino-6-methoxyquinoline . 

3 '-Aminoacetanllide. 

4 '-Aminoacetanllide . 

4 '-Aminoacetanllide sulfate. 

3 -Aminoacetophenone . 

5-Amino-2-(p-aminoani lino )benzenesulf onic acid. 

p-Phenylazoanl line . 

6-Amino-3,A'-azodlfben2enesulfonic acid] . 

6-Amino-3,<V'-azodi[benzenesulfonic acid] . 

p-Phenylazoanlline hydrochloride. 

m-(p-Aminophenylazo)benzenesulf onic acid. 

p-(p-Aminophenylazo)benzenesulfonlc acid. 

'4-(o-Tolyla2o)-o-toluldine [NH2=ll . 

A-(o-Tolylazo)-o-toluldlne sulfate. 

4-(4-Amino-m-tolyla2o)-m-toluenesulfonic acid and 

salt. 
^-(A-Amino-m-tolylazoJ-m-toluenesulfonic acid and 

salt. 



228 



SYNTHETIC ORGANIC CHEMICALS, 1963 



Cyclic intermediates: Glossary of synonymous names — Continued 



Conmion name 



Standard CChemical Abstracts! name 



Aminoazoxylenetoluidine 

p-Aminobenzenearsonic acid 

3-Aminobenzenesulfonanilide 

^•-Aminobenzenesulfonanilide 

m-Aminobenzenesulfonic acid 

p-Aminobenzenesulfonic acid 

o-Aminobenzoic acid 

m-Aminobenzoyl I(or J) acid 

p-Aminobenzoyl I(or J) acid 

p-Aminobenzoyl-m-phenylenediamine 

o-Aminobiphenyl 

2-Am±nobiphenyl 

A-Amlnobiphenyl 

l-Amino-'i-brcimoanthraquinone-2,5-disulfonic acid 

l-Amino-2-bramo-4-(p-toluidine)anthraquinone 

3-Amino-N-butyl-p-anisolesulfonamide 

p-Amino-N-(n-butyl) phenol 

2-Amino-A'-chloroacetanilide 

5-Amino-2-chlorobenzenesulfonic acid 

5-Amino-3-chlorobenzeneEulfonic acid 

5-Amino-'i-chlorobenzeneeulfonic acid 

2-Amino-4— chlorobenzoic acid 

3-Amino-6-chlorobenzoio acid 

Aminochlorodipheny 1 

Aminochlorodiphenyl ether 

Aminochlorodipheny 1 ether 

2-Amlno-3-chlorotoluene [ CH3=l] 

2-Amino-'+-chlorotoluene [ CHj^l] 

2-Amino-5-chlorotoluene [ CH3=l] 

2-Amino-6-chlorotoluene [ CH3=l] 

2-Amino-5-chlorotoluene hydrochloride 

m-Amlno-p-cresol [CH3=l] 

3-Amino-p-cresol methyl ether [CH3=l] 

3-Amino-p-cresyl methyl ether 

omega- Amino-psi-cumene 

<i)-Amino-^-cumene 

Aminodichlorobenzenesulfonic acid 

2-Amino-l,'i-diethoxybenzene 

2-Amino-5-diethylaminotoluene hydrochloride 

p-Aminoethylaniline 

<i-Amlno-l,3-dihydroxyanthraquinone 

2-Amino-l,A-dimethoxybenzene 

p-Aminodimethylaniline 

p-Aminodimethylaniline sulfate 

2-Amfno-'4,6-dtnitrophenol and salt 

o-Aminodiphenyl 

p-Aminodiphenyl 

p-Aminodiphenylamine 

'i-Amlnodiphenylamine-2-suironic acid 

Aminodiphenyl ether 

A-Aminoethoxyethylaniltne 

Amino G acid 

2-Ami-no-4— hydroxybenzenearsonic acid 

Amino I(or J) acid 

p-Amino-N-isobutylphenol 

ii-Amlno-2-methylanisole [CH30=ll 

-;-Amino-4' - (3-metbyl-5-pyrazolone ) -2,2' -Btllbenedl- 
sulfonic acid. 

4-Amlno-l-naphthalenesulfonlc >cid 

2-Aminonaphthalene-3,6,8-trisulfonic acid' 

8-Amino-l-naphthoic lactam 

l-Amino-7-naphthol 

l-Aaiino-8-naphthol -2,^-41801X0010 acid 

l-Amino-8-naphthol-3,6-disulfonlc acid 

l-Amlno-8-naphthol-^,6-di6uironlc acid 

2-Amlno-8-naphthol-3,6-disulfonic acid 

A-Amlno-5-naphthol-l,3-disulfonlo acid 



'i-(2,4-Xylylazo)-o-toluidlne [NH2=1]. 

Arsanilic acid [As03H2=l]. 

Metanilani lide . 

Sulfanilanilide. 

Metanilic acid [S03H=1]. 

Sulfanilic acid [SOsHrlJ. 

Anthranilic acid [COOH=l]. 

6-(m-ATm'nobenzamido)-l-naphthol-3-sulfonie acid. 

6-(p-Aminobenzamido)-l-naphthol-3-sulfonic acid. 

2,A,<t -Triaminobenzophenone. 

2-Biphenylamine . 

2-Biphenylamlne . 

4— Biphenylamine . 

5-Aiiiino-8-bromo-l,6-anthraqutnonedisulfonic acid. 

l-Amlno-2-br(3ao-A-(p-toluidino)anthraquinone. 

N^-Butyl-4-methoxymetanilamide [S02NH2=l]- 

p-Butylami nophenol . 

A -Chloroglycinanilide. 

6-Chlorometanilic acid [ S03H=ll. 

5-Chlorometanilic acid [S03H=1J. 

A-Chlorometanilic acid [S03H=1]. 

-V-Chloroanthranilic acid [C00H=1 ]. 

5-Amino-2-chlorobenzoic acid. 

Chloro-2-(or 3, or A ) -blphenylamlne . 

5-Chloro-2-phenoxyaiiiliiie . 

p- (p-Chlorophenoxy) aniline 

6-Chloro-o-toluldlne rNH2=ll. 

5-Chloro-o-toluidine [NH2=i]. 

■i-Chloro-o-toluidine [NH2=l]. 

3-Chloro-o-toluidine [NH2=l]. 

4.-Chloro-o-toluidine hydrochloride. 

2-Amlno-p-cresol [OH=l]. 

5-Methyl-o-anisidlne [NH2=l]. 

5-Methyl-o-anisidlne [NH2=1] . 

2, A-Dlmethylbenzylamine . 

2,4-Dlmethylbenzylamine . 

2,5-Dichlorosulfanilic acid. 

2.5-Dlethoxyaniline . 

N^,N'-Diethyltoluene-2,5-diamine hydrochloride. 

N, N-Diethyl-p-phenylenediamine . 

A-Amlnoxanthopurpurin. 

2 , 5-Dlmethoxyani line . 

N,N-Dimethyl-p-phenylenediamine. 

N , N-Dimethyl-p-pheny lenediamlne su If ate . 

Picramic acid and salt. 

2-Bijihenylamine . 

-i-Biphenylamlne . 

N-Phenyl-p-phenjrlenedlainlne . 

5-Amlno-2-anlltnobenzenesulfonlc acid. 

p-Phenoxyanlline . 

2-{p-Amino-N-ethylanilino)ethanol. 

7-Amlno-l,3-naphthalenedisulfonic acid. 

4-Hydroxy-o-arsanillc acid [As03H2=l]. 

6-Amlno-l,3-naphthalenedisulfonic acid. 

(p-Isotuty]amino)phenol. 

3-Wethyl-p-ani6idine [nH2=i]. 

4'-Amlno-4'-(3-methyl-5-oxo-2-pyTa2olln-l-yl)-2,2' 
stllbenedisulfonic acid. 

Naphthionic acid. 

7-Amino-l,3,6-naphthalenetrisulfonlc acid. 

N aphthos tyri 1 . 

8-Amino-2-naphthol . 

8-Ainlno-l-naphthol-5,7-dloulfonlc acid. 

8-Amlno-l-naphthol-3,6-disulfonlc acid. 

8-Anilno-l-naphthol-3,5-dlsulfonlc acid. 

7-AiQlno-l-naphthol-3,6-dlsulfonlc acid. 

8-Ainlno-l-naphthol-5,7-dlsuifonlc acid. 



APPENDIX B 



229 



Cyclic intermediates: Glossary of synonymous names — Continued 



Conmon name 



Standard (Chemical Abstracts) name 



-;-Aniino-5-naphthol-l,7-disxilfonlc acid 

5-Amino-<i-naphthol-2,7-disulfonic acid 

6-Aniino-'4-naphthol-2,7-disulfonic acid 

l-Amlno-8-naphthol-4- -sulfonic acid 

2-Amino-5-naphthol-7-sulfonic acid 

2-Amlno-6-naphthol-8-siilfonic acid 

2 ■ "'-'^-8-naphthol-6-sulfonic acid 

4-Amino-3-naphthol-l -sulfonic acid 

A-Amino-5-naphthol-l-sulfonic acid 

6-Amino-'i-naphthol-2-sulfonic acid 

7-Amino-3-naphthol-l -sulfonic acid 

7-Ainino-<i-naphthol -2 -sulfonic acid 

2-Amino-4--nitroanisole [ CH3O =1] 

2-Amino-5-nitroanisole 

2-Ainino-6-nitroanisole 

A-Amino-3-nitroanlsole 

A-Amino-4-nitrodlphenylamlne-2-sulfonic acid 

2-Amlno-'i-nltro-l_-phenol-6 -sulfonic acid 

2-Aminophenetole [C2H50=l] 

Aminophenol sulf amide 

o-Aminophenol-p-sulfonamide 

o-Aminophenol-p-sulfonic acid 

m-Aminophenylcarboxypyrazolone 

l-(m-Aminophenyl)-3-iiiethyl-5-pyrazolone 

Aminophenylphenyl ether 

m-Aminophenylpyrazolonecarboxylic acid 

l-(m-Aminophenyl)-5-pyrazolone-3-carboxylic acid 

p-Aminophenyl-p-tolylaminesulfonic acid 

2-Amino-'i(3H)-pyrimidone 

Amino R acid 

5-Aminosaligenin-2-methyl ether 

6-Am'ino-3- (p-toluenesulf one ) amlno-A-methoxytoluene- 

3'-Amino-(p-toluenesulfone)ethoxytoluene 

2-Aminotoluene-5-sulfonic acid 

N-(<i-Amlno-m-tolyl)-p-qulnone imine 

u-Amino-1,2,'4— trimethylbenzene 

Amlnoviolanthrene 

Amylnaphthalenes 

o-Amylphenol 

p-sec-Amylphenol 

p-tert-Amylphenol 

Anlline-2,A-disulfonic acid 

Aniline-2,5-disulfonic acid 

Aniline oil 

Aniline salt 

Aniline-m-sulfonlc acid 

Aniline-p-sulfonic acid 

Aniltne-cmega-sulfonic acid 

A-Aniltno-'i'-hydroxydiphenylamine 

6-Anillnometanllic acid 

2-Anlside-'>-acetylurea 

o-Anisidine nitrate 

2-Anisidine-'i-sulfobutylamide 

o-Anisidine-p-sulfonic acid 

2-(m-Ani8yl)-<V-chloroanthranilic add 

N-(p-Anlsyl)-4-chloroanthranilic acid 

N-(m-Anlsyl)->i-ohloroanthranlllc acid 

a-(p-Anlsyl)-a-ethyl-p-methoxyacetophenone 

a-(p-Anisyl)-p-methoxyacetophenone 

N-(p-Anisyl)-A-nltroanthranilic acid 

N-(p-Anisyl)-p-phenylenediamine 

1,2-AnthrapyTidine 

Anthraqulnonylamlnoanthraqii 1 none 

1,A,9,10-Anthratetrol 



8-Amlno-l-naphthol -3,5 -disulf onic acid . 
8-Amlno-l-naphthol-3,6-dlsulfonic acid. 
7-Amlno-l-naphthol-3,6-disulfonic acid. 
8-Amino-l-naphthol-5-sulfonic acid. 
6-Amino-l-naphthol-3-sulfonic acid. 
6-Amino-2-naphthol-4-sulfonic acid. 
7-Amino-l-naphthol-3-Bulfonic acid. 
l-Amino-2-naphthol-4-sulfonic acid. 
8-Amino-l-naphthol-5-sulfonic acid. 
7-Amino-l-naphthol-3-sulfonic acid. 
6-Amlno-2-naphthol-.4-sulfonic acid. 
6-Amlno-l-naphthol-3-sulfonic acid. 
5-Nitro-o-ani6idine [ NH2=l]. 
/;-Nitro-o-anlsidine [nHj^iJ- 
3-Nitro-o-anisidine [ NH2=l]. 
2-Nitro-p-anisidine [nH2=i]. 

2-(p-Aminoanilino)-5-nitrobenzenesulfonlc acid. 
6-Aiiiino-4-nltro-l -phenol -2-sulfonlc acid. 
o-Phenetidlne I NH2=l] . 
2-Amino-l-phenol-'i-sulfonamide. 
2-Amino-l-phenol-i-sulf onamlde . 
2-Am1no-l-phenol-4-sulfonic acid. 
l-(m-Aminophenyl)-5-oxo-2-pyTazollne-3-carboxylic 

acid. 
l-(m-Amlnophenyl)-3-methyl-2-pyrazolin-5-one. 
p-Phenoxyani line . 
1- (m-Aminophenyl ) -5-oxo-2-pyrazoline-3-oarboxylic 

acid. 
1- (m-Aminophenyl )-5-oxo-2-pyrazoline-3-car boxy lie 

acid. 
5-Amino-2-(p-toluidino)ben2enesulfonic acid. 
Isocytosine. 

3-Amlno-2,7-naphthalenedisulfonic acid. 
5-Amino-2-methoxybenzyl alcohol. 
4-'-Amino-5'-methyl-p-toluenesulfon-o-anisidide. 
3-Methyl-N-(p-toluenesulfono)-p-phenetlllne. 
'i-Amino-m-toluenesulfonic acid [S03H=1]. 
N-(A-Amlno-m-tolyl)-p-benzoquinone imine. 
2,'i-Dimethylbenzylamine . 
16-Aminoviolan throne . 
Pentylnaphthalenes . 
o-Pentylphenol . 
p- ( 1-Methylbutyl ) phenol . 
p- ( 1, 1-Dimethylpropyl )phenol. 
A-Amlno-m-benzenedisulfonic acid. 
2-Amino-p-benzenedisulfonie acid. 
Aniline. 

Aniline hydrochloride. 
Metanllic acid [SOsHn]. 
SulfaniUc acid [SOsHn]. 
Anillnanethanesulfonic acid, 
p- ( p- Anl linoani lino ) pheno 1 . 
5-Amino-2-aaillnobenzenesulfonic acid. 
1 -Acetyl -3-( 'V-ajnino-3 -me thoxyphenyl ) urea . 
'4(or 5)-Nltro-o-anleidlne [fm2=l] . 
N -Butyl-A-methoxymetanilamide. 
A-Methoxymetanilic acid [S03H=l]. 

A-Chloro-N-(m-methoxyphenyl)anthranllic acid fCOOH=ll. 
'i-Chloro-N-(p-methoxyphenyl)anthranllic acid [C00H=1] . 
'i-Chloro-N-(m-methoxyphenyl)anthranllic acid [C00H=1] . 
2-Ethyl-'i' -methoxy-2- (p-methoxyphenyl ) acetophenone . 
"i' -Methoxy-2- (p-methoxyphenyl ) acetophenone . 
N- ( p-Methoxypheny 1 ) --i-nit roanthr ani lie ac id . 
N- ( p-Methoxyphenyl ) -p-phenylenedi amine . 
Naphtho [2, 3-h] qu incline . 
1, 1' -Iminodianthraquincme . 
Leucoquinizarln . 



230 



SYNTHETIC ORGANIC CHEMICALS, 1963 
Cyclic intermediates: Glossary of synonymous names — Continued 



Common name 



Standard (Chemical Abstracts) name 



4-Antipyrtnecarboxylic acid 

p,p'-Azobis(N,N-dimethylaniline hydrochloride ) - 

A,4'-Azoblsdiphenylamane 

Azohydroxy aniline 

Azoxy aniline 

m,m'-A2oxybisaniline 



Benzal chloride 

Benzaldehydedlsulfonic acid 

Benzaldehydemonosulfonic acid 

l-(<i-Benzamido-l-anthraquinonylimino)-5-benzamido- 

anthraquinone . 
2-[3-(4-Benzamido-2,5-diethoxyphenyl)-l-methyldiazo- 

aminolethanesulfonic acid. 
N-('>-Benzamido-2,5-diethoxyphenyl)-N-methyldiazo- 

taurine . 
3-('4-Benzamido-2,5-diethoxyphenyl)-3-sulfoethyl-l- 

methyltriazene . 
[ 3.(A-Benzamido-6-methoxy-m-tolyl)-l-methyldiazo- 

amino] acetic acid. 
[ 3- ( A-Benzamldo-6-methoxy-m-tolyl ) -N-methyldiazo ] - 

glycine. 

Benzanthrone 

Benzanthronedianthraquinonyldiimide 



Benzene azobenzene 

Benzene- 1,3-dicarboxy lie acid 

p-Benzenedicarboxylic acid 

1,3,5-Benzenetriol 

Benzidine disulfonic acid 

2,2'-Benzidinedisulfonic acid 

Benzidine sulfonic acid 

Benz[cd]indol-2(lH)-one 

Benzocaine (nonmedicinal grade) 

2-Benzofurylcyanomethyl ketone 

2H-l-BenzopyTan-2-one 

1,2-Benzopyrone 

Benzotri chloride 

Benzoylacetanilide 

a-Benzoylacetanilide 

l-Benzoylamino-A-aminoanthraquinone 

2-Ben2oylamino-l,'i-diethoxybenzene 

2-Benzoylamino-l,4-dimethoxybenzene 

5-Benzoylamlno-2-nitrodimethoxybenzene 

5-Benzoylamino-2-nitrohydroquinone, diethyl ester-- 

Benzoyl J acid 

2-Benzoylthiophene 

cf-Benzylacetamide 

m-Benzyl-p-aminophenol hydrochloride 

Benzyl chloride 

o-Benzyl-p-chlorophenol 

Benzyl cyanide 

N-Benzyl-ethylanillne 

N-Benzyl-N-ethyl-p-nitrosoaniline 

3-Benzyl-7-hydroxy-A-methylcoumarin 

Benzylidineacetophenone 

4-Benzylldineamlnoantipyrine 

Benzyl mercaptan 

p-Benzylphenylcarbamate 

p,p'-Biacetoacetanilide 

Bibenzal 

Bibenzoyl 

Bibenzylidene 

o-Biphenylamine 

Biphenylene oxide 

p,p'-Bis(acetoacetanlllde) 



Antipyric acid. 

p-Dlmethylaminobenzenediazonium chloride . 
p-Anilinobenzenediazonium chloride, 
p- (p-Aminophenylazo )phenol . 
3,3' -Azoxydianiline. 
3,3' -Aaoxydianiline. 



a,a-Dichlorotoluene . 
4-Formyl-m-benzenedisulf onic acid . 
o-Formylbenzenesulf onic acid . 
<l,5' -Dibenzamido-l,l' -Iminodianthraquinone . 

2-[3-(A-Benzamido-2,5-di8thoxyphenyl)-l-methyl- 

triazen-3-yllethanesulfonic acid. 
2-[3-('i-Benzamido-2,5-diethoxyphenyl)-l-methyl- 

triazen-3-yl]ethanesulfonic acid. 
2-[3-('C-Benzamido-2,5-diethoxyphenyl)-l-methyl- 

triazen-3-yl] ethanesulf onic acid. 
[3-('4-Benzamido-6-methoxy-m-tolyl)-l-methyltriazen- 

3-yl] acetic acid. 
[ 3- (<i-Benzamido-6-methoxy-m-tolyl ) -l-methyltriazen- 

3-yl] acetic acid. 
7H-Benz[de] anthracen-7-one . 
3,9-Bis [l-anthraquinonylamino] -7H-benz [de] anthracen- 

7-one . 
Azobenzene . 
Isophthalic acid. 
Terephthalic acid. 
Phloroglucinol . 

<i,<V -Diamino-2,2^-biphenyldisulfonic acid. 
'4,'i'-Diamlno-2,2'-biphenyldisulfonic acid. 
A-,A -Diamino-3-biphenylsulfonic acid. 
Naphthostyril. 

p-Aminobenzoic acid, ethyl ester. 
2-Benzofuranacetonitrile . 
Coumarin. 
Coumarin. 

a, a, a -Xrlchlorotoluene. 
2-Benzoylacetani lide . 
2-Benzoylacetanilide . 
l-Amino-ii-benzamidoanthraquinone . 
2 ',5 '-Diethoxybenzanilide. 
2 ',5 '-Dimethoxybenzanilide . 
2 ',5 '-Dimethoxy-A '-nitrobenzanilide . 
2',5 '-Diethoxy-4 -nitrobenzanilide. 
6-Benzamido-l-naphthol-3-sulfonic acid. 
Phenyl-2-thienyl ketone. 
Hydrocinnamamide . 

<i-Anino-a-pheDyl-m-cresol hydrochloride. 
o-Chlorotoluene . 

4.-Chloro-a-phenyl-o-cresol [OH=l]. 
Phenylacetonitrile . 
N-Ethyl-N-phenylbenzylamine . 
N-Ethyl-N- ( p-nitrosophenyl ) benzylamine . 
3-Benzyl-4-methyl\iinbeHlf erone . 
Chalcone . 

4-Benzylideneimlnoantipyrine . 
a-Toluenethiol. 
a-Phenyl-p-cresol carbamate. 
<;',^'"-Biaoetoaoetanllide. 
Stllbene . 
Benzil. 
Stilbene . 
2-Biphenylamine . 
Dibenzofuran. 
A ' ,1, "'-Biaoetoacetaullide . 



APPENDIX B 
Cyclic intermediates: Glossary of synonymous names — Continued 



231 



Common name 



Standard (Chemical Abstracts) name 



N,N'-Bis(acetoacetyl)benzidine 

l,3-Bis('i-biphenyl)-2-thiourea 

N,N-Bis(2-hydroxyethyl) aniline 

N,N-Bis(2-hydroxyethyl-m-toluidine) 

2,2'-Bis("i-hydroxyphenyl)propane 

N,N'-Bis-6-(l-naphthol-3-sulfonic acid )urea 

Blsphenol A 

Bisphenol B 

Bisphenol C 

Bisphenol G 

3,3'-Bitolylene-<+,'4'-diisocyanate 

B.O.N 

Broenner's acid 

Bromamine acid 

p-Bromoacetamidoanthraquinone 

Bromobenzanthrone 

2-Bromobipheny lene oxide 

p-Bromomethylaminoanthraquinone 

"i-Bromo-N-methyl-ljg-anthrapyridone 

a-Bromo-p-nitroacetophenone 

Bromoquinizarin 

o-(3-Bromo-p-tolyl)benzoic acid 

6-tert-Butyl-2,'+-dimethylacetophenone 

n-Butyl-p-nitrobenzoate 

p-C arboxybenzenesulf onamide 

3-Carboxy-4-hydroxyacetanilide 

3- (Carboxymethyl ) -1- (5-chloro-2-methoxyphenyl ) -3- 

methyltri azene . 

(o-Carboxyphenyl) acetic acid 

Cassella acid 

Chicago acid 

Chlorinated cresols 

2-Chloro-3-acetamino-9,10-anthrahydroquinone acid 

ester. 

2-Chloro-3-acetaminoanthraquinone 

2-Chloro-3-acetamino-9,10-dihydroxyanthracene-9,10 

dlsulfonic acid ester. 

o-Chloroacetoacetanilide 

Chloroacetylarsanilic acid 

5-Chloro-2-aininoanisole [CH30=l] 

A-Chloro-2-amino-6-benzenesulfonic acid 

6-Chloro-3-aminobenzot rif luoride 

Chloroaminophenol 

2-Chloro-'4-aminotoluene [CHjr]^ 

3-Chloro-2-aminotoluene [CH3=1] . 

5-Chloro-2-aminotoluene [CH3=1] 

m-Chloroaniline-o-sulfonic acid 

p-Chloroaniltne-m-sulfonic acid 

p-Chloroaniline-0-sulfonic acid 

4-Chloro-o-anisidine [ CH30=1] 

5-Chloro-o-anisidine [CH30=1] 

3-Chloro-2-anthracenecarboxylic acid 

2-Chloroanthraquinone-3-oarboxylic acid 

Chloroarsacetin 

2-Chlorobenzaldehyde-5 -sulfonic acid 

A-Chlorobenzaldehyde-2-sulfonic acid 

l-Chloro-5-benzamideanthraquinone 

Chlorobenzanthrone 

4-Chlorobenzotrif luoride 

Chlorobenzyl cyanide 

l-Chloro-2-carharyaiithraquliione 

p-Chloro-m-cresol [ CH3=1] 

2-Chloro-l,'i-dihydroxyanthraquinone 

Chloro H acid 

5-Chloro-8-hydroxyquinoline 

3-Chloro-3'-methoxy-6-diphenylaminecarboxylic acid 



W ,it" '-Biacetoacetanilide . 
•4,4 -Diphenylthiocarbanilide. 
2, 2 '- C Phenylimino )diethanol . 
2,2'- (m-Tolylimino )diethanol . 
4,4 -Isopropylidinediphenol. 
6,6'-Ureylenebis [l-naphthol-3-sulfonic acid ]. 
4,4 -Isopropylidinediphenol. 
2,2 -Bis(4-hydroxyphenyl)butane. 
4,4 -Isopropylidinedi-o-cresol. 
4,4 -Isopropylidinebis [2-isopropylphenol] . 
Isocyanic acid, (3,3 '-dimethyl -4, 4 '-biphenylene ester. 
3-Hydroxy-2-naphthoic acid. 
6-Amino-2-naphthalenesulfonic acid. 
l-Amino-4-brQmo-2-anthraquinonesulf onic acid . 
l-Acetamido-4-bromoanthraqutnone . 
3-Bromo-7H-benz[de]anthracen-7-one. 
2-Bromodibenzofuran. 
4-BrQmo-l-methylaminoanthraquinone . 

6-Bromo-3-methyl-7H-dibenz[f ,ij]isoquinoline-2,7(3H)- 
dione. 
2-Bromo-4 '-nitroaoetophenone . 
2-Bromoquiniz arin . 

3 -Bromo-4 -methyl-2-biphenylcarboxylic acid. 
2 '-tert-Butyl-4 ',6 '-dtmethylacetophenone . 
p-Nitrobenzoic acid, n- butyl ester. 



p-Sulfamoylbenzoic acid. 

5-Acetamidosalicylic acid. 

N- ( 5 -Chloro-2-methoxyphenylazo ) -N-methylglycine . 

a -Carboxy-o-toluic acid. 
3-Amino-l,5-naphthalenedisulfonic acid. 
8-Amino-l-naphthol-5,7-disulfonic acid. 
Cresols, chlorinated. 
2-Acetainido-3-chloro-9 , lO-dihydro-9 , 10-anthradiol- 

9,10-disulfonic acid, diethyl ester. 
2-Acetamido-3-chloroanthraquinone . 
2-Acetamido-3-chloro-9,10-dihydro-9,10-anthradiol-9, 

10-disulfonic acid, diethyl ester. 
2' -Chloroacetoacetanilide. 
N-Acetyl-2-chloroarsanilic acid [As03H2=1]. 
4-Chloro-o-anisidine [NHa^l]. 
5-Chlorometanilic acid [ S03H=l] . 
6-Chloro-a,a,a-trifluoro-m-toluidine [NH2=1] • 
2-Amino-4-chlorophenol . 
3-Chloro-p-toluidine [NH2=1]. 
6-Chloro-o-toluidine [NH2=1]. 
4-Chloro-o-toluidine [NH2=l]. 
2-Amlno-6-chlorobenzenesulfonic acid. 
6-Ghlorometanilic acid. 
2-Amlno-5-chlorobenzenesulfonic acid. 
5-Chloro-o-anisidine [ NH2 =1 ] . 
4-Chloro-o-anisidine [NH2=l]. 
3-Chloro-2-anthroic acid. 
3-Chloro-2-anthraquinonecarboxylic acid. 
N-Acetyl-2-chloroarsanilic acid [As03H2=l]. 
4-Chloro-3-f ormylbenzenesulf onic acid . 
5-Chloro-2-f ormylbenzenesulf onic acid . 
l-Benzamido-5-chloroanthraquinone . 
Chloro-7H-benz [de] anthracen-7-one. 
4-Chloro- <'',«, a-trifluorotoluene. 
(p-Chlorophenyl ) acetonitrile . 
l-Chloro-2-anthraquinonecarboxylic acid. 
6-Chloro-m-cresol [OH=l]. 
2-Chloroquinizarin. 

8-Chloro-l-naphthol-3,6-disulfonic acid. 
5-Chloro-8-quinolinol. 
4-Chloro-N-(m-methoxyphenyl)anthranilic acid [C00H=1] 



232 



SYNTHETIC ORGANIC CHEMICALS, 1963 
Cyclic intermediates: Glossary of synonymous «awes-- Continued 



Common name 



3-Chloro-4'-methoxy-6-diphenylaminecarboxylic acid 

a-Chloro-2-methoxy-5-nitrotoluene 

[ 3- (5-Chloro-2-methoxyphenyl)-l-methyldiazoamino] - 
acetic acid. 

Chloromethylanthraquinone 

o-Chloro-p-nitroaniline 

p-Chloro-c-nitroaniline 

Chloro-o-nitrobenzene 

4-Chloro-3-nitrobenzotrifluoride 

4-Chloro-2-nitro-l-phenol-6-sulfonic acid 

'i-Chloro-2-nitrophenyl ether 

2-Chlorophenol 

A-Chlorophenol 

ChlorophenyLhydrazine-p-sulfonic acid 

l-(m-Chlorophenyl)-3-methyl-5-pyTazolone 

2-Chloro-o-phenyl phenol 

l-(6-Chloro-'i-sulfophenyl)-3-methyl-2-pyrazolin-5-one 

l-(2-Chloro-A-sulfophenyl)-3-methyl-5-pyrazolone 

l-(6-Chloro-3-sulfophenyl)-3-methyl-5-pyraZQlone 

o-Chloro-p-toluene sodium sulfonate 

<t-Chlorotoluene-2-sulfonic acid 

m-Chlorotoluenethioglycolic acid 

4-Chloro-o-toluidine [CH3=l] 

5-Chloro-2-toluldine [CH3=l] 

5-Chloro-o-toluidine [CH3=l] 

o-Chloro-m-toluidine-p-sulfonic acid 

2-Chloro-p-toluidine-5-sulfonic acid 

2-Chloro-5-toluidine-4-sulfonic acid 

4-Chloro-o-tolylmercaptoacetic acid 

l-(5-Chloro-o-tolyl)-3-raethyl-3-triazeneacetic acid— 

Chlorotolylthioglycolic acid 

Chloro-sym-xylenol 

Chloroxylidenesulfonic acid 

'+-Chloro-2,5-xylyliiiercaptoacetlc acid 

Chromotropic acid 

Cinnamene 

1,6-Cleve 's acid 

1,7-Cleve's acid 

Cleve's acid, mixed 

m-Cresidine 

Cresidine or p-Cresidine 

m-Cresol methyl ether 

m-Cresolsulfonic acid 

o-Cresotic acid 

Y-Cresotic acid 

o-Cresotinic acid 

CresyldisuLfide 

m-Cresyl methyl ether 

Cumaldehyde 

psi-Cumene 

psi-Cumidine 

CuEiinaldehyde 

2-Cyanopyridine 

3-CyanopyTidine 

<+-Cyanopyridine 

Dahl's acid 

Dehydrothio-p-toluidine 

Desoxyanisoin 

Developer Z 

3,6-Diamlnoacridine 



Standard (Chemical Abstracts) name 



'i-Chloro-N-(p-methoxyphenyl)anthranilic acid. 

2- ( Chloromethyl ) -4-nitroanisole [ CH3O ^ ] . 

N- (5-Chloro-2-methoxyphenylazo ) -N-methylglyclne . 

l-Chloro-2-methylanthraquinone . 

2-Chloro-4-nitroanlline . 

<+-Chloro-2-nltroaniline . 

l-Chloro-2-nitrobenzene . 

<i-Chloro-a, a, a-trif luoro-3-nitrotoluene . 

'4-Chloro-6-nitro-l-phenol-2-sulf onlc acid . 

l-(4-Chloro-2-nitrophenoxy)benzene. 

o-Chlorophenol. 

p-Chlorophenol . 

4-Chloro-3-hydrazinobenzenesulf onic acid . 

1- (m-Ghlorophenyl ) -3-methyl-2-pyrazolin-5-one . 

2-Chloro-6-phenylphenol . 

5 -Chloro-<+- ( 3-methyl-5-oxo-2-pyTazolin- 1-yl )benzene- 

sulfonic acid. 
5-Chloro-4-(3-methyl-5-oxo-2-pyrazolin-l-yl)benzene- 

sulfonic acid. 
4-Chloro-3-(3-methyl-5-oxo-2-pyrazolln-l-yl)benzene- 

sulfonic acid. 
3-Chloro-p-toluenesulfonlc acid, sodium salt [S03H=l] 
5-Chloro-o-toluenesulfonlc acid [S03H=l]. 
(<+-Chloro-o-tolylthio) acetic acid. 
5-Chloro-o-toluidlne [NH2=l]. 
4-Chloro-o-toluldlne [NHj^l]. 
4-Chloro-o-toluidine [ MHz =1 ] . 

2-Amino-5-chloro-p-toluenesulfonic acid [S03H=l]. 
6-Amino-4-ohloro-m-toluenesulfonic acid [S03H=l]. 
2-Amino-5-chloro-p-toluenesulfonic acid [S03H=l]. 
(4-Chloro-o-tolylthio) acetic acid. 
N-(5-Chloro-o-tolyl)-N-methylglycine. 
( 4-Chloro-o-tolylthio ) acetic acid . 
4-Chloro-3 , 5-xylenol . 

6-Amino-3-chloro-2,5-xylenesulfonic acid [S03H=l]. 
(4-Chloro-2,5-xylylthio) acetic acid. 
4, 5-Dihydroxy-2,7-naphthalenedisulf onic acid . 
Styrene . 

5-Amino-2-naphthalenesulfonic acid. 
8-Amino-2-naphthalenesulfonic acid. 
5 (and 8)-Amino-2-naphthalenesulfonic acid. 
2-Methyl-p-anisidine [ NH2=l] . 
5-Methyl-o-anlsidine [ NH2=l] . 
m-Methylanisole [CH30=l]. 
5-Hydroxy-m-toluenesulfonic acid [S03H=l]. 
2,3-Cresotic acid. 
2,4-Cresotic acid. 
2,3-Gresotic acid. 
p-Tolyl disulfide. 
m-Methylanisole [CHjO^l]. 
p-Isopropylbenzaldehyde . 
1,2,4 -Trimethylbenzene . 
2,4,5 -Tr imethy lanl line . 
p-Isopropylbenzaldehyde . 
Picolinonitrile . 
Nicotinonitrile . 
Isonicotinonitrlle . 



6-Amino-l-naphthalenesulfonic acid. 
2-(p-Aminophenyl)-6-methylbenzothiazole. 
4 '-Methoxy-2- ( p-methoxyphenyl ) acetophenone . 
3-Methyl-l-phenyl-2-pyTazolin-5-one. 
Proflavine base. 



APPENDIX B 



233 



Cyclic intermediates: Glossary of synonymous names — Continued 



Conmon name 



Standard (Chemical Abstracts) name 



m-Diaminoanisole 

3,3'-Diamlnoazoxybenzene 

2,2'-Diamino-5,5'-bi-m-toluenesulfonic acid 

4^, A '-Diamino-l,l' -dianthraquinonylamine 

A,A-' -Diamino-l,l' -dianthrimide 

Diamino-'i,A '-dibenzoyl-1, l' -dianthraquinoneimlne 

Diamino-4 , 5 ' -dibenzoyl- 1 , l' -dianthraquinonylamine 

l,A-Diamino-2,3-dihydroxyanthraquinone 

3,6-Diamino-2,7-dimethylacridine hydrochloride 

A, a' -Diamino-2,2 -dimethylbiphenyl 

'i,<i'-Diamino-2,2'-dimethyldiphenylmethane 

AjA- -Diamlnodiphenyl 

^,^ '-Diaminodiphenylamine-2-suLfonic acid 

p,p -Diamlnodiphenylme thane 

p,p -Diamlnodiphenylsulfide 

3,3 -Diaminodiphenyl urea 

Di(p-aminophenyl) sulfide 

l,3-Di(m-aminophenyl)urea 

2,6-Diaminotoluene-'i-sulfonic acid 

Diamylphenol 

l,5-Dianilinoanthraquinone-o,o'-dicarboxylic acid 

o-Dianisidine 

l,2-Di-p-anisyl-l,2-ethanediol 

2,4-Di(p-anisyl)-3-ethyIhexane 

2,4-Di(p-anisyl)-3-ethyIhexene 

a,P-Dianisylglycol 

3,-4-01 (p-anisyl)hexane 

l,l'-Dianthraquinoneimine 

1,1 '-Dianthraquinonylamine -- 

Dianthrimide 

Dlazoaminobenzene 

Diazobenzene chloride 

4,5 -Dibenzamido-l,l'-amlnodianthraquinone 

5,5 -Dibenzamido-l,l'-imincdianthraquinone- 

Dibenz an throne 

2,2 -Dibenzanthronyl 

13,13-Dibenzanthronyl 

Dibenzopyran 

Dlbenzopyrrole 

Dibenzoyl 

"ijS-Dibenzoylamidodianthraquinonylamine 

4-, 4- '-Dibenzoyldiamino- 1,1^ -dianthrimide 

Dibenzyl 

Dibenzyl aniline 

Dibenzyl disulphide 

Dibenzyl ether 

Dibenzyl sodium sulfanilate 

Dlbromoaminoanthraqulnone 

7, 16-Dibromo-6, 15-dihydro-5 , 9, lA, 18-anthrazinetetrone 

p-Dibromodihydroxynaphthalene 

2,6-Dibrano-l,5-dihydroxynaphthalene 

<i,5-Dibromo-l,8-dihydroxynaphthalene 

l,A-Dichloro aniline 

2,5-Dichloroaniline-'i-sulfonic acid 

l,5-Dichloro-A,8-anthraqulnonedisulfonic acid 

l,8-Dichloro-'i,5-anthraquinonedisulfonic acid 

2,6-Dichlorobenzalchloride 

o,o'-Dichlorobenzidine 

3,3'-Dichlorobenzidine base 

m,m'-Dichlorobenzidine hydrochloride 

2,'+-Dichlorobenzyl chloride 

2,'i-Dichlorobenzylidene chloride 

2,6-Dichlorobenzylidene chloride 

2,5-Dichlorophenylhydrazlnesulfonic acid 

l-(2,5-Dichlorophenyl)-5-pyrazolone-3-carboxylic acid 

749-026 O - 64 - 16 



5-Methoxy-m-phenylenediam±ne . 
3,3 -Azoxydianiline. 

2.2 -Diamino-5,5 -dimethyl-3,3 -biphenyldisulfonic 
acid. 

l,l' - Iminobis [ 4- ami noanthraquinone ] . 

1,1 -Iminobisl^-aminoanthraquinone] . 

1,1 -Iminobis[4— benzamidoanthraquinonel . 

■4,5 -Dibenzamido-1,1 -tminodianthraquinone. 

1,4-Diaminohystazarin. 

Acridine yellow. 

m-Tolidine. 

4,<4 -Methylenedi(m-toluidine) . 

Benzidine. 

5-Amino-2-(p-aminoanilino)benzenesulfonic acid. 

4,4' -Methylenedlaniline . 

4,4 '-Thiodiani line. 

3.3 -Diaminocarbanilide. 
4,4'-Thiodianiline. 

3,3 -Diaminocarbanilide. 
3,5-Dlamlno-p-toluenesulfonic acid. 
2,4-Dipentylphenol. 

l,5-Dianilino-2,6-anthraquinonedicarboxylic acid. 
3,3 '-Dimethoxybenzidine . 
l,2-Di(p-methoxyphenyl)-l,2-ethanediol. 
2,4-Di (p-methoxyphenyl) -3-ethylhexane . 
2,4-Dl(p-methoxyphenyl)-3-ethylhexene. 
1,2-Di (p-methoxyphenyl) -1,2-ethanediol. 
3 , 4-Di (p-methoxyphenyl )hexane . 
1 , 1 ' - Iminodi anthr aqu inone . 
1 , 1 ' - Iminodi anthraquinone . 
1,1 -Imlnodianthraqulnone. 
1,3-Diphenyltriazene. 
Benzenediazonium chloride. 
4,5 -Dibenzamido-1,1 -iminodianthraquinone. 
1,1 -Iminobis [5-benzaiiildoanthraquinone] . 
Violanthrone . 

(4,4^-Bi-7H-benz[de] anthracen)-7,7'-dione. 
(3,3'-Bi-7H-benz[de]anthracen)-7,7'-dione. 
Xanthene. 
Carbazole. 
Benzil. 

4, 5 '-Dibenzamido-1,1 -iminodianthraquinone. 
1,1 '-Iminobis [4-benzamldoanthraquinone] . 
Bibenzyl. 

N-Phenyldibenzylamine . 
Benzyl disulfide. 
Benzyl ether. 

N,N-Dlbenzylsulf anillc acid, sodium salt. 
l-Anilno-2,4-dibramoanthraqulnone . 
7, 16-Dibramoindanthrene . 
4,5-Dibromo-l,8-naphthalenediol. 
2 , 6-Dibramo-l , 5-naphthalenediol . 
4,5-Dlbromo-l,8-naphthalenedlol. 
2, 5-Dichloro aniline. 
2,5-Dichlorosulfanilic acid [S03=l]. 
4,8-Dlohloro-l,5-anthraquinonedisulfonlc acid. 
4,5-Dichloro-l,8-anthraqulnonedisulfonlc acid. 
a , a , 2 , 6-Tetrachlorotoluene . 
3 , 3 ' -Dlchlorobenzldine . 
3,3' -Dlchlorobenzldine . 
2,2'-Dichlorobenzidine hydrochloride. 
a,2,4-Triohlorotoluene. 
a, a,2,4-Tetrachlorotoluene. 
a, a, 2 , 6-Tetrachlorotoluene . 

2,5-Dichloro-4-hydrazlnobenzenesulfonlc acid. 
l-(2,5-Dichlorciphenyl)-5-oxo-2-pyrazollne-3-carboxyllc 
acid. 



234 



SYNTHETIC ORGANIC CHEMICALS, 1963 



Cyclic intermediates: Glossary of synonymous names — Continued 



Common name 



Standard (Chemical Abstracts) name 



SjS-Dichloro-A-sulfobenzenedlazohydroxide 

1- (2, 5-Dichloro-'i-sulfophenyl) -3-methyl-5-py^azolone- 
2,'i-Dlchloro-5-(p-toluenesulfonamldo)-l-naphthol 

Dicresyldisulf ide 

Dlcyclohexyl 

Diethanolaniline 

Diethanol-m-toluidine 

1,'i-Diethoxybenzene 

N-(2,5-Diethoxy-<i-nitrophenyl)ben2amide 

N-(2,5-Diethoxyphenol)benzamlde 

Dlethylanlllne-m-suLfonic acid 

Diformyl-m-tolylenedi amine 

1 , 2 -Dihydroacenaphthy lene 

9,10-Dihydroacridine 

l,4-Dihydro-4--oxo-2,6-pyridinedicarboxylic acid 

1,3-Dihydroxyanthraquinone 

Ij'i-Dlhydroxyanthraquinone 

1,5-Dihydroxyanthraquinone 

1 , 8 -Dihyd roxy anthr aquinone 

2 , 6-Dihydroxyanthraquinone 

2,<t-Dihydroxybenzoic acid 

Dihyd roxybi phenyl 

2,3-Dlhydroxy-l,4-dlaminoanthraquinone 

Dihydroxydibenzanthrone 

5,5 '-Dihydroxydi-2-naphthylamine-7,7'-disulfonic acid 

1,5 -Dihyd roxy-'+,8-dinitroanthraqulnone 

p, p '-Dihydroxydipheny Idlmethylmethane 

4.4 '-Dihydroxydipheny Isulf one 

5 . 5 -Dlhydroxy-7 , 7 ' -dlsulf onlc-.2, 2 '-dinaphthylamine 

Dihyd roxyethylanlline 

N,N-Di(P-hydroxyethyl) aniline 

Dihydroxyethyl-3-toluldine 

H,N-Di(P-hydroxyethyl)-m-toluidlne 

3 ' ,4' -Dihydroxy- 2-me thylaminoacetophenone 

1,5-Dihydroxynaphthalene 

2,3-Dihydroxynaphthalene 

l,8-Dlhydroxynaphthalene-3,6-dlsulfonlc acid 

l,8-Dihydroxynaphthalene-4-sulfonlc acid 

2,3-Dihydroxynaphthalene-6-sulfonic acid 

p-Di-p-hydroxyphenylpropane 

7,8-Diketoacenaphthene 

2,3-Dimethoxybenzaldehyde 

3,'i-Dlmethoxybenzaldehyde 

o-Dlme thoxybenzene 

1,2-Dl.Tiethoxybenzene 

3,3'-Dlmethoxybenzidine-4,'4'-diisocyanate 

4,4' -Dlmethoxybenzoin 

p,p'-Dimethoxybenzoylphenylcarblnol 

3,4-Dimethoxybenzyl alcohol 

3,3'-Dlmethoxy-4,4'-blphenylbls[3-methyl-3- 

trlazeneethanesulfonic acid] . 
N,ir-(3,3'-Dimethoxy-4,4'-blphenylenebisazo)bi£(N- 

methyltaurlne) . 
2,2'-[3,3'-(3,3'-Dimethoxy-4,4'-biphenylene)bis(l- 

methyldiazoamincj] dl(ethanesulfonio acid) . 
l,l'-(3,3'-Dimethoxy-4,4'-biphenyleneJbis(3-methyl-3- 

(sulfoethyljtrlazene,/ . 

Di-p-raethoxyethylchalcone 

4,4' -Dime thoxy-a-hydroxy-a-phenylacetone 

N-(2,5-Dlmethoxy-4-nitrophenyl)benzamide 

II-(2,5-Dimethoxyphenyl,/benzamide 

Dimethylacetanilide 

Dime thy lamlnoacetylcatechol 

4-Dimethylamino-2,3-dimethyl-l-phenyl-3-pyrazolin-5- 

one. 



2,6-Dlchloro-4-hydroxydiazobenzenesulfonic acid. 
2,5-Dichloro-4-(3-methyl-5-oxo-2-pyTazolin-l-yl) 

benzenesulfonic acid. 
N- ( 6 , 8-Dichloro-5 -hydroxy- 1-naphthyl ) -p-toluene- 

sulf onamide [ S02NH2=1] . 
p-Tolyl disulfide. 
Bicyclohexyl. 

2, 2 '- ( Phenylimino ) diethanol . 
2 , 2 '- ( m-Tolyllmlno ) diethanol . 
p-Dlethoxybenzene . 
2 ',5 '-Dlethoxy-4 '-nltrobenzanllide. 
2 ,5 -Diethoxybenzanilide. 
N.N-Diethylmetanilic acid [S03H=l]. 
N^,N*-Diformyltoluene-2,5-diamine [CH3=1] . 
Acenaphthene. 
Acridan. 

Chelidamlc acid. 
Xanthopu rpu r in . 
(^inizarin. 
Anthraruf in. 
Chrysazln. 
Anthraflavic acid. 
t--Resorcylic acid. 
Biphenol. 

1,4-Diamlnohystazarin. 
16, 17-Dihydroxyviolanthrone . 
6,6 -Imlnobls[ l-naphthol-3-sulfonic acid]. 
4 , 8-Dinitro anthraruf in . 
4,4 -Isopropylldenedlphenol. 
4,4 -Sulfonyldiphenol. 

6,6 -Iminobis[l-naphthol-3-sulfonic acid). 
2,2 -(Phenyllmlno)diethanol. 
2 , 2' - ( Phenylimino ) diethanol . 
2,2'-(m-Tolyllmino)diethanol. 
2,2'-(m-Tolyllmino)diethanol. 
Adrenalone . 

1,5-Naphthalenediol. 

2 , 3 -Naphthalened iol . 

4,5-Dihydroxy-2,7-naphthalenedisulfonic acid. 

4,5-Dihydroxy-l-naphthaleneEulfonic acid. 

6,7-Dlhy*roxy-2-naphthalenesulfonic acid. 

4,4'-Isopropylidinedlphenol. 

Acenaphthenequlnone . 

o-Veratraldehyde . 

Veratraldehyde . 

Veratrole. 

Veratrole. 

Isocyanlc acid, 3,3'-dimethoxy-4,4'-biphenylene 
ester. 

p-Anisoln. 

p-Anlsoin. 

Veratryl alcohol. 

3,3'-Dimethoxy-4,4'-bis[3-methyl-3-£ulfoethyltriazen- 
1-yl] biphenyl. 

3,3'-Dimethoxy-4,4'-bi£[3-methyl-3-sulfoethyltriazen- 
1-yl] biphenyl. 

3,3' -Dimethoxy-4 , 4 ' -bis [ 3 -methy 1-3-sii If oethyltri azen- 
1-yl] biphenyl. 

3,3'-Di.'nethoxy-4,4'-bis[ 3-ne thyl-3-3u If oethyltriazen- 
1-yl] biphenyl. 

a-Ethyl-4,4'-dlraethoxychalcone. 

p-Anisoin. 

2 ' , 5' -Dlinethoxy-4 '-nltrobenzanllide . 

2', 5 '-Dlmethoxybenzanillde. 

Acetoxylidide. 

3 ',4 '-Dlhydroxy-2-dimethylaminoacetophenone. 

Aminopyrlne . 



APPENDIX B 



235 



Cyclic intermediates: Glossary of synonymous names — Continued 



Common name 



Standard (Chemical Abstracts, nair.e 



N,N-Dimethyl-3-aminophenol 

Dimethylaniline 

Dimethylbenzene 

2 ',4-Dtmethylbenzenesulfonanilide 

2,2'-Dimethylbenzidine 

3,3 '-Dime thy Ibenzidine 

2,<i-Dimethyl-6-tert-butylacetophenone 

l,3-Dimethyl-5-tert-butylbenzene 

2,7-Dimethylceroxanol 

Dimethy Idi anthraquinony 1 

2,2 '-Dimethyl-l,l-dianthraquinonylamine 

Dimethy Ihydroresorcinol 

3,3 '-Dimethyl-4,4 '-methylenediphenyl isocyanate 

Dimethyl-a-naphthylamine 

2,3-Dimethyl-5-oxo-l-phenyl-3-pyTazoline-'4-carboxylic 
acid. 

2,3-Dimethyl-l-phenyl-3-pyrazolin-5-one 

2,7-Dimethylquinoline 

Dtnaphtho[l,2,3-cd,l',2',3'-lm]perylene-9,18-dione 

Dinaphtho[l,2,3-cd,3',2',l '-lm]perylene-5,19-dione 

1,'i-Dinitrobenzene 

2 , ir -Dini t robenzene 

Dinit rochlorobenzene 

Dinitrochlorobenzenesulfonic acid 

3,5-Dinitro-'i-chlGrobenzoic acid 

2,6-Dinitro-4-chlorophenol 

Dinitro-o-cyclohexylphenol 

A,'i'-Dinitro-l,l '-di anthraquinony lamine 

Dinit rodibenzanthronyl 

Dlnitrohydroxydiphenylamine 

Dinitrotetramethyldiaminodiphenylmethane 

2,A-DinitrotoluenesulfGnic acid 

1 , 2-Dioxoacenaphthene 

Dioxy S acid 

Diphenol 

Dipheny 1 

2,'i-Diphenylamine-l-hydroxyanthraquinone 

2,'4-Diphenylamino-l-oxyanthraquinone 

Dipheny Icarbazide 

Diphenyleneimine 

Dipheny lene oxide 

Diphenyl epsilon acid 

Dipheny 1 ether 

Diphenyl ketone 

Dipheny Imethanol 

Diphenyl oxide 

l,3-Diphenyl-2-propen-l-one 

Diphenyl silicon dichloride 

1,3 -Dipheny lurea 

N , N-Dipheny lure a 

sym-Dipheny lure a 

Dipyrazoledianthrone 

1,3-Di-p-toluidineanthraquinone 

1,'4-Di-p-toluidineanthraquinone 

l,3-Di(p-tolylamino)anthraqulnone 

l,<i-Di-p-tolylaminoanthraquinone 

S-Dixenylthlourea 

Durene 

N-Ethanol-N-ethyl-A-nitrosoanlline 

2-EthanolpyTidine 

2-Ethoxy aniline 

4-Ethoxyaniline 

2-Ethoxy-6-sulfonaphthalene 

Ethyl-p-aminobenzoate 



m- (Dimethylamino )phenol . 

Xylidine. 

Xylene. 

p-Toluenesulf ono-o-toluidide . 

m-Tolidine. 

o-Tolidine. 

2'-tert-Butyl-4',6'-dimethylacetophenone. 

5-tert-Butyl-m-xylene. 

2,8-Dimethyl-13b-hydroxy-9(13b)-ceroxenone. 

2,2'-Dimethy.l-l,l -bianthraquinone. 

l,l'-Iminobis [2-methylanthraquinone] . 

Dimethyl-l,3-cyclohexanedione. 

Isocyanlc acid, 2,2'-dimethyl-4,A' -methylenedi- 

phenylene ester. 
N , N-Dimethyl-1-naphthylamine . 
Antipyric acid. 

Antipyrine. 

m-Toluquinaldine . 

Isoviolanthrone. 

Violanthrone. 

p -Dinit robenzene . 

m-Dinitrobenzene . 

l-Chloro-2,'i-dinit robenzene. 

4-Chloro-3,5-dinitrobenzenesulfonio acid [S03H=l]. 

<4-Chloro-3,5-dinitrobenzoic acid [COOH=l]. 

A-Chloro-2,6-dinitrophenol [OH=l]. 

2-Cyclohexyl-<;,6-dinitrophenol [ OH=l] . 

l,l'-Iminobis['i-nitroanthraquinone] . 

Dinitro(3,3 -bi-7H-benz[de] anthracene) -7,7 -dione. 

p- ( 2 ,'1-Dinitroani lino )phenol . 

A,4'-Methylenebis [M,N-dimethyl-2-nitroaniline] . 

3,5-Dinitro-o-toluenesulfonic acid [S03H=l]. 

Acenaphthenequlnone . 

4 , 5 -Dihydroxy- 1-naphthalenesu If onic ac id . 

Biphenol. 

Biphenyl. 

2 , 4 -Di ani lino- 1-hydroxyanlhraquinone . 

2,'4-Dianiltno-l-hydroxyanthraquinone. 

1 , 5 -Dipheny Ic arbohydraz i de . 

Carbazole. 

Dibenzofuran. 

8-Diphenylamino-l,6-naphthalenedisulfonic acid. 

Phenyl ether. 

Benzophenone . 

Benzhydrol. 

Phenyl ether. 

Chalcone . 

Dichlorophenylsilane . 

Carbanilide. 

Carbanilide. 

Carbanilide. 

[3,3 '-Blanthra[l,9]pyrazole]-6,6'(2H,2'H)-dione. 

1 , 3-Di ( p-toluidino ) anthraquinone . 

1 ,4-Di (p-toluidino ) anthraquinone . 

1, 3-Di (p-toluidino) anthraquinone. 

1,4— Di (p-toluidino ) anthraquinone . 

'i,4'-Dlphenylthiocarbanilide. 

1,2,4,5-Tetramethylbenzene. 



2- ( N-Ethyl-A-nitrosoanl lino ) ethanol . 
2-PyTidineethanol . 
o-Phenetidine [NH2=1]. 
p-Phenetidine [NH2=l]. 
6-Ethoxy-2-naphthalene3ulfonlc acid. 
p-Aminobenzoic acid, ethyl ester. 



236 



SYNTHETIC ORGANIC CHEMICALS, 1963 



Cyclic intermediates: Glossary of synonymous naw«s— Continued 



Common name 



Ethyl-o-amino-p-cresol 

Ethylanlline (mono) 

N,N-Ethylbenzylaiiiline 

EthylbenzylanilinesulXonic acid 

Ethylbenzyl-m-toluidine 

Ethylbenzyl-m-toluidino-o-sulfonic acid 



Standard (Chemical Abstracts) name 



Ethyleneglycol monophenylether 

Ethyl hydrol 

N-Ethyl-N-(P-hydroxyethyl) aniline 

Ethyl ketone base 

2-[l-Ethyl-3-(2-methoxy-5-nitrophenyl)dia2oamino]-5- 
sulfobenzoic acid.. 

5-Ethyl-2-methylpyTidine 

p-Ethylnitrobenzene 

Ethyl-p-nitrobenzoate 

Ethyl-p-nitrobenzoylacetate 

Ethyl phenyl ether 

Ethylsulfobenzylaniline 

N-Ethyl-o-toluidine-p-sulfonic acid 



Fast red TR base 

p-Formylaniline 

p-Formyl-N, N-diethylaniline-- 
4.-Formyl-3-pyrazolin-5-one 



G acid 

Gamma acid 

Gamma disulfo acid 

Glycerolmonoethylanillne- 



H acid 

Halocrin 

Hexahydrobenzoic acid 

Hexahydropyridine 

Homophthalic acid 

a-m-Homosalicylic acid 

p-Homosalicylic acid 

Homoverat ric acid 

o-Homoveratric acid 

Homoveratronitrile 

Homoverat rylamine 

1,2-1,2-Hydrazinedibromoanthraquinone 

Hydrol - 

Hydroquinone dimethyl ether 

l-Hydroxy-A-aminoanthraquinone 

V-Hydroxycoumarin 

4-Hydroxydiphenol 

P-Hydroxyethyl-o-chloroaniline 

Hydro xye thy lethylani line 

Hydroxyethylmethylaniltne 

N-(P-Hydroxyethyl)-N-methylaniline 

Hydro xyethyl-3-toluidine 

2-Hydroxymetanilic acid 

4-Hydroxymetanilic acid 

2-Hydroxy-3-methoxybenzaldehyde 

2-Hydroxy-3-methylbenzoic acid 

2-Hydroxy-4-methylbenzoic acid 

2-Hydroxy-5-methylbenzoic acid 

7 -Hyd roxy-4-methylcoumarin 

2-Hydroxy-5-nitrometanilic acid 

A-Hydroxy-5-nitrometanilic acid 

2-Hydroxyphenetole 

p-Hydroxyphenylarsonio acid 



3-Ethylamino-p-cresol [OH-l]. 

N-Ethylaniline. 

N-Ethyl-N-phenylbenzylamine . 

a-(N-Ethylanilino)-p-toluenesulfonic acid [S03H=l]. 

M-Benzyl-N-ethyl-m-toluidine [ NH2=l] • 

4- ( N-Benzyl-N-ethylamino ) -o-toluenesulf onic acid 

[ SOjH =1] . 
2-Phenoxyethanol . 
A , A ' -Bis [ dlethylamino ]benzhydrol . 
2- ( N-Ethylanillno ) ethanol . 
4, A '-Bis [dlethylamino ]benzophenone. 
2-il-Ethyl-3-(2-methoxy-5-nitrophenyl)triazen-3- 

yl]-5-sulfobenzoic acid. 
5-Ethyl-2-picoline . 
l-Ethyl-<V-nitrobenzene . 
p-Hitrobenzoic acid, ethyl ester. 
p-Nitrobenzoylacetic acid, ethyl ester. 
Phenetole . 

a-(N-EthylaniHno)-p-toluenesulfonic acid [S03H=l]. 
3-Ethylamino-p-toluenesuIfonic acid [S03H=l]. 



4-Chloro-o-toluidine [NH2=l]. 

p-Aminobenzaldehyde . 

p - ( Dlethylamino ) benz aldehyde . 

5-0xo-3-pyrazoline-4.-carboxaldehyde. 



2-Naphthol-6,8-disulfonic acid. 
7-Amino-l-naphthol-3-sulfonic acid. 
7-Amlno-l-naphthol-3,6-disulfonic acid. 
3- (N-Ethylanilino ) -1, 2-propanedicl . 



8-Amino-l-naphthol-3,6-disulfonic acid. 

6,9-Dichloro-2-methoxyacridine. 

Cyclohexanecarboxylic acid. 

Piperidine. 

a-Carboxy-o-toluic acid. 

2,A-Cresotic acid [COOH=l]. 

2,5-Cresotic acid [COOH=ll . 

( 3, -i-Dimethoxyphenyl) acetic acid. 

(2,3-Dimethoxyphenyl)acetic acid. 

( 3, A-Dimethoxyphenyl ) acetonitrile . 

3 , <i-0imethoxyphenethy lamlne . 

7, 16-Dibromoindanthrene . 

A , 4- '-Bis ( dimethy lamino )benzhydrol . 

p-Dimethoxybenzene . 

l-Amino-4-hydroxyanthraquinone . 

Umbellif erone . 

p-Pheny Iphenol . 

2- ( o-Chloroani lino ) ethanol . 

2- ( N-Ethylanilino ) ethanol . 

2- ( N-Methylanilino ) ethanol . 

2- ( N-Methylani lino )ethanol . 

2- (m-Toluidino ) ethanol . 

6-Amlno-l-phenol-2-suLfonic acid. 

2- Amino- 1-phenol-A-sulf onic acid. 

o-Vanillin. 

2,3-Cresotic acid [ COOH=l] . 

2,4-Cresotic acid [ COOH=ll . 

2,5-Cresotic acid [ COOH=ll . 

4-Methylumbellif erone. 

6-Amino-'4-nitro-l-phenol-2-sulfonic acid. 

2-Amino-6-nitro-l-phenol-'i-sulfonic acid. 

o-Ethoxyphenol . 

p-Hydroxybenzenearsonic acid [As03H2=1]. 



APPENDIX B 



237 



Cyclic intermediates: Glossary of synonymous names — Continued 



Common name 



Standard (Chemical AbstrRCts) name 



p-Hydroxypheny 1-n-buty l;unine 

3-(p-Hydroxyphenyl)hydratropic acid 

N-(p-Hydroxyphenyl)-2-naphthylamine 

P- (p-Hydroxypheny l)-a-phenylpropionic acid 

3- ( p-Hydroxypheny H-S-phenylpropionic acid 

A-Hydroxypyridine-2,6-dicarboxylic acid 

8-Hydroxyquinoline 

m-Hydroxytoluene 

o-Hyd roxyto luene 

p-Hydroxytoluene 

6-Hydroxy-m-toluidine [ NH2=l] 

2-Hydroxy-p-toluic acid 

I acid 

I acid imide 

2,2 '- ( 1 , 3- Indandlone )quinollne 

Isobutyl p-nitrobenzoate 

Isodibenzanthrone 

p-Isopropylaniline 

Isopropylbenzene 

Isopropyl p-toluenesulfonate 

J acid 

J acid imide 

J acid urea 

K acid 

Koch's acid 

Lake red C amine 

Laurent 's acid 

Lead styphnate 

Lead trinitroresorclnate 

Leuco-l,'i-di(methylamino)anthraquinone 

Methandrone 

Methane base 

Methane salt 

o-Methoxyacetanilide 

p-Methoxyacetanilide 

"i-Methoxy-A -aminodiphenylamine 

2-Methoxy-4-aminodiphenylamine-2 -sulfonic acid 

Methoxy aniline 

o-Methoxyanilinomethanesulfonlc acid 

2-(o-Methoxyanilino)-5-nitrobenzenesulfonic acid 

o-Methoxyanilino-p-sulfonlc acid 

Methoxybenzene 

p-Methoxybenzoic acid 

'i-Methoxy-3 -chloro-6 -carboxydiphenylamine 

2-Methoxy-6,9-dichloroacridlne 

A -Methoxy-A-nitrodiphenylamlne-2'-sulf onic acid 

2-[ 3-(2-Methoxy-<i-nitrophenyl)-l-methyltriazeno] -5- 
sulfobenzoic acid. 

i-Methoxy-m-toluidine [CH3=1 1 — 

6-Methoxy-m-toluidine [NHa^l] 

[ 3-(6-Methoxy-m-tolyl)-l-methyltriazeno]aoetic acid 

A-Methyl-A- aminodiphenylamine-2-sulfonlc acid 

Methylaminosulfobenzoic acid 

o-Methylaniline 

Methylaniline (mono) 



p-Buty laminophenol . 
a-Phenylphloretic acid. 
p-2-Naphthylaminophenol . 
3t-Phenylphloretic acid. 
a-Phenylphloretic acid. 

Chelidamic acid. 

P-Quinolinol. 

m-Cresol [OH=l]. 

o-Cresol [oH=l] . 

p-Cresol [oH=l] . 

2^Amino-p-cresol [OH=l]. 

2,'4-Cresotic acid [COOH=l] 



c-Amino-l-naphthol-3-sulf onic acid . 

6,6 '-Iminobis [l-naphthol-3-sulfonic acid]. 

Quinophthalone . 

p-Nitrobenzoic acid, isobutyl ester. 

Isoviolanthrone . 

Cumidine. 

Cumene. 

p-Toluenesulfonic acid, isopropyl ester [S03H=l]. 



6-Amino-l-naphthol-3-suLfonic acid. 

6, 6 '-Iminobis [l-naphthol-3-sulf onic acid]. 

6,6 '-Ureylenebis[l-naphthol-3-sulfonic acid]. 



8-Amino-l-naphthol-3,5-disulfonic acid. 
3-Amino-l,3,6-naphthalenetrisulfonic acid. 



2-Amino-5-chloro-p-toluenesulfonic acid [ S03H=1] , 
5-Ami no-l-naphthalenesuLfonic acid. 
Styphnic acid, lead salt. 
Styphnic acid, lead salt. 
l,'i-Dimethylamino-9,10-anthradlol. 



3 'jA '-Dihydroxy-2-(dimethylamino)acetophenone. 

4,'i__'-Methylenebis [N,N-dimethylanlline] . 

A,^ -Methylenebis[3-hydroxy-2-naphthoic acid]. 

o-Acetanisidlde . 

p-Acetanisidide. 

N- (p-Methoxyphenyl ) -p-phenylenediamine . 

o-('t-Aiiilno-2-anisidino)benzenesulfonic acid [S03H=l]. 

Anisidine [NH2=l]. 

o-Anisldinomethanesulfonlc acid. 

2-(o-Anisidino)-5-nitrobenzenesulfonic acid. 

'i-Methoxymetanili.c acid [S03H=l]. 

Anlsole. 

Anisic acid [COOH=l]. 

A-Chloro-N- (p-methoxyphenyl ) anthranilic acid 

[C00H=l]. 
6,9-Dichloro-2-methoxyacridine. 

2-(p-Anisidino)-5-nitrobenzenesulfonic acid [S03H=l]. 
2- [3- ( 2-Methoxy-A-nitrophenyl ) - 1-methy ltriazen-3-yl ] - 

5-sulfobenzoic acid. 
5-Methyl-o-anisldlne [ NH2=l]. 
5-Methyl-o-anlsidine [ NH2=l] • 
[3- (6-Methoxy-m-tolyl) -1-methy ltrlazen-3-yl] acetic 

acid. 
5-Amino-2-(p-toluidino)benzenesulfonic acid. 
N-Methyl-5-sulfoanthranillc acid. 
o-Toluidine [ NH2=l]. 
N-Methylanillne . 



238 



SYNTHETIC ORGANIC CHEMICALS, 1963 



Cyclic intermediates: Glossary of synonymous names— Continued 



Common name 



Standard (Chemical Abstracts) name 



2-Me thy Ibenzanth rone 

Methylbenzoi c acid 

Methylenebis(toluenediamine) 

A.-i'-Methylenebisfo-tolylisocyanate] 

Methylenedl-p-phenylenelsocyanate 

-^j-i'-Methylenedipheiiylisocyanate 

Methylenedl-o-tolylene isocyanate 

2-Methyl-5-ethylpyridlne (MEP) — - 

4-Methyl-7-hydroxycoumarin 

Methyl-p-hydroxy-m-nitrobenzoate 

l-Methyl-'i-hydroxyquinolone 

3-Methyl-4-(3-methyl-5-oxo-2-pyrazolin-l-yl)benzene 

sulfonic acid. 
3-Methyl-l-(2-raethyl-'i-sulfophenyl)-5-pyrazolone 

N-(5-Methyl-'i-nitro-o-anisyl)-p-toluenesulfonamide- 

2-Methyl-5-nitrodiphenylamine 

3-Methyl-l-(m-nitrophenyl)-5-pyrazolone 

m-Methylphenol 

o-Methylphenol 

p-Methylphenol 

4-Methyl-m-phenylenediisocyanate 

3-Methyl-l-phenyl-5-pyrazolone 

MethylphenylpyTazolone-3-sulfonlc acid 

Methylphenylpyrazolone-'+-sulfonic acid 

2-Me thy Ipiperidine 

4-(3-Methyl-5-pyrazolone)-m-toluenesulfonic acid 

Methylpyxidine 

2-Methylquinoline 

3-Methyl-l-(m-sulfophenyl)-2-pyrazolin-5-one 

3-Methyl-l-(p-sulfophenyl)-2-pyTazolin-5-one 

Methylsulfophenylpyrazolcme, mixed 

3-Methyl-l-(p-sulfophenyl) -5 -pyrazolone 

Methyl-p-toluenesulf onate 

P-Methylumbelliferone 

2-Methyl-5-vinylpyrldine (MVP)— 

Miohler's hydrol 

Mlchler's ketone 

Monobromobenzene 

Monochlorobenzene 

Naphthalene sodium sulfonates 

Naphthalene- P-thioglycollc acid 

2(lH)-peri-Naphthazolone 

o-Naphthionic acid 

a-Naphthol 

P-Naphthol— — 

l-Naphthol-8-chloro-3,5-disulfonic acid 

2-Naphthol ethyl ether 

Naphthosulfochloride 

1,8-Naphthosultone 

Naphthylacetonitri le 

a-Naphthylamine 

P-Naphthylamine 

l-Naphthylamlne-3,6-disulfonic acid 



2-Methyl-7H-benz [de] anthracen-7-one . 
p-Toluic acid [COOH=l]. 
5,5 -Methylenebis [toluene-2,'i-diamlne ]. 
Isocyanlc acid, 3,3'-dimethyl-A,'i'-methylenedi- 

phenylene ester. 
Isocyanlc acid, methylenedi-p-phenylene ester. 
Isocyanlc acid, methylenedi-p-phenylene ester. 
Isocyanlc acid, 3,3 '-dimethyl -^,'i'-methylenedi- 

phenylene ester. 
5-Bthyl-2-picoline . 
"i-Methylumbellif erone . 

p-Hydroxy-m-nitrobenzoic acid, methyl ester. 
1-Methyl-A ( lH ) -quinolone . 
'>-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-m-toluene- 

sulfonic acid [S03H=l]. 
'i-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-m-toluene- 

sulfonic acid. 
N-(5-Methyl-A-nitro-o-methoxyphenyl)-p-toluene- 

sulfonamlde. 
5-Nitro-N-phenyl-o-toluidine [NH2=l] . 
3-Methyl-l-(m-nitrophenyl)-2-pyra2olin-5-one. 
m-Cresol [ OH=l] . 
o-Cresol [ OH=ll. 
p-Creaol [ 0H=1J. 

Isocyanlc acid, A-methyl-m-phenylene ester. 
3-Methyl-l-phenyl-2-pyTazolin-5-cine. 
m-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic 

acid. 
p-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic 

acid. 
2-Pipecoline. 
'>-(3-Methyl-5-oxo-2-pyra2olin-l-yl)-m-toluenesulfonic 

acid. 
Picollne. 
Qainaldine. 
m-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic 

acid. 
p-(3-Methyl-5-oxo-2-pyTazolin-l-yl)benzenesuIfonic 

acid. 
m(and p)-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzene- 

sulfonic acid. 
p-(3-Methyl-5-oxo-2-pyrEizoltn-l-yl)benzenesulfonic 

acid. 
p-Toluenesulfonic acid, methyl ester [S03H=l]. 
4-Methylumbellif erone . 
5-Vinyl-2-plcoline . 
-ijA'-Bisidimethylaminolbenzhydrol. 
<i , <4 ' -Bis [ dime thylamino] benzophenone . 
Bromobenzene . 
Chlorobenzene (mono). 



Naphthalenesulfonic acids, sodium salt (mixed). 

(2-Naphthylthio) acetic acid. 

Naphthostyrl 1 . 

l-Amlno-2-naphthalenesulfonic acid. 

1-Naphthol. 

2-Naphthol. 

8-Chloro-l-naphthol-3,6-disulfonlc acid. 

2-Ethoxynaphthalene . 

1-Naphthalenesulfonyl chloride. 

l-Naphthol-8-sulfonic acid sultone. 

Naphthaleneacetonitrile . 

1-Naphthylamine . 

2-Naphthylamine . 

5-Amino-2,7-naphthaJ.enedisulfonic acid. 



APPENDIX B 



239 



Cyclic intermediates: Glossary of synonymous names — Continued 



Common name 



Standard (Chemical Abstracts) name 



l-Naphthylamine-3,8-disulfonic acid 

l-Naphthylamine-4,7-disulfonic acid 

l-Naphthylaiiu.ne-4,8-disulfonic acid 

2-Naphthylamine-l,5-disulfonic acid 

2-Naphthylamine-3,6-disulfonic acid 

2-Naphthylamine-'i,8-disulfonic acid 

2-Naphthylamine-5,7-disulfonic acid 

2-Naphthylamine-6,8-disulfonic acid 

l-Naphthylamine-2-sulfonic acid 

l-Naphthylamine-3-3ulfonic acid 

1-Naphthylamine-A-sulfonic acid 

l-Naphthylamine-5-sulfonic acid 

l-Naphthylamine-6-sulf onic acid 

l-Naphthylamine-6(and 7)-sulfonic acid 

l-Naphthylamine-7-sulfonic acid 

l-Naphthylamine-8-sulfonic acid 

2-Naphthylamine-l-suLfonic acid 

2-Naphthylamine-5-sulfonic acid 

2-Naphthylamine-6-sulfonic acid 

2-Naphthylamine-8-sulfonic acid 

l-Naphthylamine-3,6,8-triBulfonic acid 

2-Naphthylamine-3,6,8-trisulfonic acid 

l-Naphthylamino-2-carboxylic acid anthraquinone 

1-llaphthylisocyanate 

c-Naphthyl isocyanate 

2-Naphthyimeroaptoacetic acid 

Naphthylmethanesulfonic acid 

P-Naphthylthioglycolic acid 

Nevile & Winther's acid 

3-Nitro-A-aninoanisole [ CHaO^l] 

4-Nitro-2-aminoanisole [ CHsO^lj 

5-Nitro-2-aminoanisole [ CH30=l] 

6-Nitro-2-amnoanisole [ CH30=1] 

o- Ni t ro-p - aminophenol 

p-Nitro-o-aminophenol 

5-Nitro-o-aminophenol 

4-tIitro-2-aminophenol-6-sulfonic acid 

6-Nitro-2-aminophenol-A-sulfonic acid 

A-Hitro-'i'-amino-2-sulfGdiphenylamine 

5-Nitrc-2-aminotoluene [ CH3 =l] 

p-Hitrcaniline-o-sulfonic acid 

m-llitro-p-anisidine rCH30=l] 

3-Nitro-p-anisidine [ CH30=1] 

'i-Hitro-2-anlsidine [ CH30=1] - 

5-MitrG-2-anisidine [ CH30=1] 

2-'Iitrcanisole-4.-siilfodiethylamlde 

l-:JitrGanthraqulnGne-2-carboxylic acid 

HitrGbenzene-2,5-disulfonic acid 

l-NitrGbenzene-<i-sulfonic acid 

2-Hitrobenzenesulfonic acid 

3-Nitrobenzenesulf onic acid 

3-Nitrobenzenesulfonyl chloride 

m-Nitrobenzoyl J acid 

p-Nitrobenzoyl J acid 

m-tlitrochlorobenzene 

o-Nitrochlorobenzene 

p-Nitrochlorobenzene 

2-Hitro-l-chlorGbenzene-^-sulfobutylamlde 

2-Nitro-l-chlorobenzene-'i-sulf odiethylamlde 

o-Nitrochlorobenzene-p-sulfonic acid 

p-MitrGchlorcbenzene-o-3ulfonic acid 

3-flltro-'i-chlorobenzoylbenzolc acid 

'i-NitrG-6-chloi\3-l,3-dimethoxybenzene 

2-NltrG-'i-chlorophenol 

2-Nitro-'i-chlorcphenol-6-Eulfonic acid 

m-Nitro-p-chlorotoluene 

o-Nitro-p-chlorotoluene 



8-Amino-l,6-naphthalenedisulfonic acid. 
'4-Amino-l,6-naphthalenedisulfonic acid. 
4-Amino-l,5-naphthalenedisulfonic acid. 
2-Amino-l, 5-naphthalenedisulf onic acid . 
3-Amino-2,7-naphthalenedisulfonic acid. 
3- Amino-1, 5-naphthalenedisulf onic acid. 
6-Amino-l,3-naphthalenedisulfonic acid. 
7-Amino-l,3-naphthalenedisulfonic acid. 
l-Amino-2-napthalenesulfonic acid. 
'i-Amino-2-naphthalenesulfom.c acid. 
Naphthionic acid. 

5-Amino-l-naphthalenesulfonic acid. 
5-Amino-2-naphthalenesulfonic acid. 
5 (and 8 } -Amino-2-naphthalenesulf onic acid. 
8-Amino-2-naphthalenesulf onic acid . 
8-Amino-l-naphthalenesulfonic acid. 
2-Amino-l-naphthalenesulfonic acid. 
6-Amino-l-naphthalenesulfonic acid. 
6-Amino-2-naphthalenesulfonic acid. 
7-Amlno-l-naphthalenesulfonic acid. 
8-Amino-l,3,6-naphthalenetrisulfonic acid. 
7-Anlno-l,3,6-naphthalenetrisuironic acid. 
l-(l-Naphthylamino)-2-anthraquinonecarboxylic acid. 
Isocyanic acid, 1-naphthyl ester. 
Isocyanic acid, 1-naphthyl ester. 
(2-Naphthylthio)acetic acid. 
1-Naphthalenemethanesulfonic acid. 
(2-Naphthylthio)acetlc acid. 
l-Naphthol-4-sulfonic acid. 
2-Nitro-p-anisidine [ 1^2=11. 
5-Nitro-o-anisidine [nH2=i]. 
A-Nitro-o-anisidine [NH2=1]. 
3-Nitro-o-anisidine [tffl2~l]' 
A- Amino-2-nitrophenol. 
2-Amlno-<i-nitrophenol. 
2-Amino-5-nitrGphenol. 

6-Amino-A-nitrG-l-phenol-2-suIfonic acid. 
2-Aniino-6-nitrG-l-phenol-4-sulfonic acid. 
2-(p-Aminoani lino )-5-nitrcben2enesulf onic acid. 
<;-Nitro-o-toluidine [NH2 = i]. 
2-Amino-5-nltrobenzenesulfonic acid. 
2-Hitro-p-anisidine [NH2=l]- 
2-Hltro-p-anisidine [ NH2=1] . 
5-Nitro-o-anisidine [ NH2=li . 
A-Nitro-o-anisidine [ NH2=l] • 

N,N-Diethyl-3-nitro-p-nethoxybenzenesulfonanide. 
l-Nitro-2-anthraquinonecarboxylic acid. 
2-Nitro-p-benzenedisulfonic acid. 
P-Nitrobenzenesulfonic acid [S03H=l]. 
o-Nitrobenzenesulf onic acid [S03H=1]. 
m-Nltrobenzenesulfonic acid [S03H=l]. 
m-Nitrobenzenesulfonyl chloride [S03Cl=l]. 
6-(m-Nitrobenzamldo)-l-naphthol-3-sulfonic acid. 
6-(p-Nitrobenzamido)-l-naphthol-3-culfonic acid. 
l-Chloro-3-nitrGbenzene . 
l-Chloro-2-nltrobenzene. 
l-Chloro-'i-nitrGbenzene . 

N-Butyl-A-chloro-3-nitrobenzenesulfGnamide. 
A-Chloro-H,N-diethyl-3-nitrobenzenesulfonamide. 
A-Chloro-3-nitrobenzeneEulf onic acid . 
2-Chloro-5-nitrobenzeneEulf onic acid . 
o-('i-Chloro-3-nitrGbfenzoyl)benzoic acid. 
fc-Chloro-l,3-dinethGxy-<4-nitrobenzene. 
i-ChlGro-2-nitrGphenol. 

A-Chloro-6-nitrG-l-phenol-2-3ulfonic acid. 
^-Chloro-3-nitrotolQene . 
'4-Chloro-2-nitrotGluene. 



240 



SYNTHETIC ORGANIC CHEMICALS 1963 



Cyclic intermediates: Glossary of synonymous names — Continued 



Common name 



Standard (Chemical Abstracts) name 



p-Nitro-o-chlorotoluene 

2-Nitro-'+-chlorotoluene 

m-Nitro-p-cresol [CH3=l] 

Nitrocresyl methyl ether 

Nit r o-p -dichlorobenzene 

o-Nitrodiphenyl 

p-Nitrodiphenyl 

4-Nitro-2-diphenylaminesulfonic acid 

4-Nit rodiphenylamino-2-3ulf onic acid 

2-Nitrohydroquinone, diethyl ether 

2-Nitrohydroquinone, dimethyl ether 

3-NitrG-'i-hydroxy-l-phenylarsonlc acid 

b-Nitro-^-methoxy-S-aminotoluene [CH3=l] 

2-Nitro-'i-raethoxy-5-(p-toluenesu If onamido) toluene-- 

-i-Nitro-l-methylaniline 

l-Nitro-2-methylanthraquinone 

2-Nitronaphthalene-'4,8-disulfonic acid 

7-Nitro-l,5-naphthalenedisulfonic acid 

4— Nitronaphthalic acid tolylimide 

2-Nitro-l-phenol-'4,6-disulfonic acid 

3-Nitrophenylhydrazine 

p-{p-Nitrophenylmercapto) aniline 

l-(m-Nitrophenyl)-5 -pyrazolone -3-carboxylic acid — 

Nitropyrazolonecarboxylic acid 

p-Nitrosodiethylaniline 

p-Nitrosodimethylaniline 

Nitroso-|3-naphthol 

3-Nitro-5-stearoylamino-p-toluenesulfonic acid 

A-Nitrotolueneanllide 

6-Nitro-3-(p-toluenesulfone)amino-'4-methoxytoluene- 

■4 -Nitro-p-toluenesulfone-o-toluide 

o-Nitrotoluenesulfonic acid 

p-Nitrotoluene-o-sulfonic acid 

m-Nitro-o-toluidine [CH3=l] 

m-Nitro-p-toluidine [CH3=l] 

p-Nitro-o-toluidine [CH3=l] 

3-Nitro-4-toluidine [CH3=l] 

<;-Nitro-2-toluidine [CH3=l] 

5-Nitro-2-toluidine [ GH3=l] 

Nitrotoluidine sulfone 

6-Nitro-o-toluidine-4-sulfonic acid 

N-(4-Nitro-o-tolyl)-p-toluenesulfonamide 

5-Nitro-l,2,'i-trichlorobenzene 

Nit roviolanthrene 

p-Nitro-o-xylene 

4-Nit ro- 1 , 3-xy lene 

2-Nitro-l,4-xylol 

4-Nitro-l,3-xylol 

Orthanilic acid 

Oxalyl-p-nitro aniline 

Oxalyl-p-nitrophenylamine 

Oxalyl-m-phenyldi amine 

Oxaly 1-p-phenyldi amine 

4-0xo-4H-pyran-2,6-dicarboxylic acid 

2-Oxycarbazole 

a-Oxynaphthoic acid 

P -Oxynaphthoic acid 

Pent aanthr amide 



2-Ghloro-4-nitrotoluene . 

4-Chloro-2-nitrotoluene . 

2-Nitro-p-cresol [0H=1] . 

4-Methyl-2-nitroani£ole [CH30=l]. 

1 , 4-Dichloro-2-nitrobenzene . 

2-Nitrobiphenyl. 

4-Nit rob iphenyl. 

2-Anilino-5-nitrobenzenesulfonic acid [S03H=1]. 

2-Anilino-5-nitrobenzenesulfonio acid [S03H=1]. 

1 , 4-Diethoxy-2-nitrobenzene . 

l,4-Diinethoxy-2-nitrobenzene . 

4-Hydroxy-3-nitrobenzenearsonic acid. 

5-Methyl-4-nitro-o-anisidiiie [ NH2=l]. 

N- (5-Methyl-4-nitro-o-methox>'phenyl) -p-toluenesulf on- 

amide. 
5-Nitro-o-toluidine [nH2=i]. 
2-Methyl-l-nitroanthraquinone . 
3-Nitro-l,5-naphthalenedisulfonic acid. 
3-Nitro-l,5-naphthalenedisulfonic acid. 
4-Nitro-N-(p-tolyl)naphthalimide. 
6-Nitro-l-phenol-2,4-disulfonic acid. 
m-Nitrophenylhydrazine . 
p-(p-Nitrophenylthio) aniline. 
l-(m-Nitrophenyl)-5-oxo-2-pyrazoline-3-carboxylic 

acid. 
l-(m-Nitrophenyl)-5-oxo-2-pyTazoline -3-carboxylic 

acid. 
N, N-Diethyl-p-nitrosoaniline . 
N,N-Dimethyl-p-nitrosoaniline. 
l-Nitroso-2-naphthol. 
3-Nitro-5-stearoylamido-p-toluenesulfonic acid 

[S03H=1]. 
5-Nltro-n-phenyl-o-toluldine [ NH2=1] . 
N-(5-Methyl-4-nitro-o-methoxyphenyl)-p-toluene- 

sulfonamlde. 
4 -Nitro-p-toluenesulf ono-o-toluidide . 
3-Nitro-p-toluenesulfonic acid [S03H=l]. 
5-Nitro-o-toluenesulfonic acid [S03H=l]. 
4-Nitro-o-toluidine [NH2=l]. 
2-Nitro-p-toluidine [NH2=l]. 
5-Nitro-o-toluidine [NH2=l]. 
2-Nitro-p-toluidine [ NHs =1] . 
5-Nitro-o-toluidine [NH2=l]. 
4-Nitro-o-toluidine [NH2=l]. 
4 '-Nitro-p-toluenesulf ono-o-toluidide. 
4-Amino-5-nitro-m-toluenesulfonic acid [S03H=l]. 
4' -Nitro-p-toluenesulf ono-o-toluidide. 
l,2,4-Trichloro-5-nitrobenzene. 
16-Nitroviolanthrone . 
4-Nitro-o-xylene . 
4-Nitro-m-xylene . 
2- Nitro-p -xylene . 
4-Nitro-m-xylene . 



o-Aminobenzenesulfonic acid [S03H=1]. 
4 -Nitrooxanilic acid. 
4 -Nitrooxanilic acid. 
3 '-Aminooxanilide . 
4 ' - Aminooxani lide . 
Chelidonic acid. 
2-Hydroxycarbazole. 
l-Hydroxy-2-naphthoio acid. 
3-Hydroxy-2-naphthoic acid. 



1,4,5,8-Tetrald.s[l',l",l '",1 ""-anthraquinonyl- 
amino] anthraquinone . 



APPENDIX B 
Cyclic intermediates: Glossary of synonymous names — Continued 



241 



Uommon name 



Standard (Cliemlcal Atstracts) naae 



Peri acid 

Phenethylene 

Phenol, sodium salt 

l-Phenylacetylcarbinol 

3-Phenylacrylophenone 

2-Phenylamine-5-naphthol-7-sulfonic acid 

2-Phenylamine-8-naphthol-6-sulfonic acid 

N-Phenylaniline 

Phenylarsonic acid 

N-Phenylazoaniline 

Pheny Ibipheny 1 

Phenyl b romi de 

l-Phenyl-3-carboxy-5-pyTazolone— 4-sulfonic acid 

Pheny Id iethanolamlne 

N,N -p-Phenylenebis [acetamide] 

m- Pheny lenedi aminedisulf onic acid 

m-Phenylenedi aminesu ] f onic acid 

p-Phenylenediaminesulfonic acid 

Phenylene nerol acid 

Pheny lethanolamine 

Phenyl gamma acid 

Pheny Ihydrazine-p-sulf onic acid 

Pheny lhydrazine-2- sulfonic acid 

Pheny lhydrazine-3-sulf onic acid 

N-Phenyl-N'-(p-hyd re xyethyl) thiourea 

Phenyl isocyanate 

Phenyl J acid 

Pheny Imalonic ester 

Pheny Imethanesulf onic acid 

Phenyl- P-naphthylamine 

N-Phenyl-l-nephthylamine-8-sulfonic acid 

a-Phenyl-p-('4-oxophenyl)propionic acid 

Phenyl peri acid 

N-Phenyl-p-phenylenedi aminesulf onic acid 

l-Phenyl-5-pyTa2olone-3-carboxylic acid, ethyl ester- 

Phenyl silicon chloride 

Pheny Istyryl ketone 

l-Phenyl-'4'-sulfo-5-pyrazolone-3-carboxylic acid 

Phthalyl chloride 

3-Piperidino-l-propanol 

Piperidinopropyl alcohol 

Potassium-3-chloro-6-carboxy-3'-methoxydiphenylamlne- 

n-Propyl-p-nitrobenzoate 

Pseudocumene 

Pseudocumidine 

Purpuroxanthin 

Pyrazoleanthrone 

Pyrazole anthrone ye How 

3-PyrazGlin-'i-ylacetic acid 

3 -Pyr azo lone 

5-Pyrazolone 

Pyrazolone G 

Pyrazolone T 

2-Pyridylethanol 

R acid 

2R acid --- - 

Red KB base • 

Rhoduline acid 



8-Amino-l-naphthalenesulf onic acid . 

Styrene . 

Sodium phenoxide . 

l-Hydroxy-l-phenyl-2-propanone. 

Chalcone . 

6-Anilino-l-naphthol-3-sulfonic acid. 

7-Anilino-l-naphthol-3-£ulfonic acid. 

Diphenylamine . 

Benzenearsonic acid. 

1, 3-Diphenyltriazene . 

lerphenyl. 

Bromobenzene . 

5-Oxo-l-(p-sulfophenyl)-2-pyrazoliiie-3-oarboxylic 

acid. 
2,2 -( Pheny limino)diethanol. 
N,M - (p-Phenylene)bis[ acetamide J . 
A,6-Diamino-m-benzenedisuLfonic acid. 
2,'i-Diaminobenzenesulfonic acid. 
2,5-DiaminobenzeneEuli'onic acid. 
5-Amino-2-(p-aminoanilino)benzenesulfcnic acid. 
2-Anilinoethanol. 

7-Anilino-l-naphthol-3-sulfonic acid. 
p-Hydrazinobenzenesulfonic acid [S03H=l]. 
o-Hydrazinobenzenesulfonic acid [S03H=l]. 
m-Hydrazinobenzenesulf onic acid [SOjH^lj. 
l-(2-Hydroxyethyl)-3-phenyl-2-thiourea. 
Isocyanic acid, phenyl ester. 
6-Anilino-l-naphthol-3-Eulfonic acid. 
Phenylnalonic acid, diethyl es^er. 
a-Toluenesulfonic acid. 
N-Phenyl-2-naphthylani-ne . 
8-Ani lino- 1-naphthalenesulf onic acid. 
a-Phenylphloretic acid. 
S-Anilino-1-naphthalenesulfonic acid. 
5-Amino-2-anilinobenzenesuLfonic acid [S03H=l]. 
5-0xo-l-phenyl-2-pyrazoline-3-carboxylic acid, 

ethyl ester. 
Tr i chloropheny Is i lane . 
Chalcne . 
5-0xo-l-(p-sulfophenyl;-2-pyrazoline-3-carboxylic 

acid. 
Phthaloyl chloride. 
1-Piperidinepropanol . 
l-Piperidinepropanol . 
4-Chloro-N-(m-nethoxyphenyl}anthranilic acid, 

potassium salt [COOH=l]. 
p-!iitrobenzoic acid, n-propyl ester. 
1 , 2 , "C-Trimethy Ibenzene . 
2,^^, 5-TrijneT,hylaniline . 
Xanthopurpurin . 
Anthra [1,9] pyrazol-6 ( 2H i -one . 

[3,3'-Bianthra[l,9]pyrazole]-6,6'(2H,2'H>-dione. 
3-Pyrazcline-'i-acetic acid. 
3-Pyrazolin-5-one. 
2-Pyrazolin-5-one . 
p-(3-Methyl-5-oxo-2-pyrazolin-l-yl,benzenesulfonic 

acid. 
5-0x0-1- (p-sulfophenyl)-2-pyrazoline-3-carb&xy lie 

acid. 
2-Pyridineethanol. 



2-Naphthol-3,6-disulfonic acid. 
7-AEiino-l-naphthol-3,6-disulfonic acid. 
5-Chloro-o-toluidine [NH2=l]. 
6,6'-Irainobis[l-naphthol-3-sulfonic acid] 



242 



SYNTHETIC ORGANIC CHEMICALS, 1963 
Cyclic intermediates: Glossary of synonymous names — Continued 



Common name 



Standard (Chemical Abstracts) name 



S Acid 

2S (SS) acid ■ 

Schaeffer's acid 

Silver salt 

Sodium carbolate 

Sodium naphthionate 

Sodium phenate 

Sodium phenolate 

Sodium-o-phenylphenolate 

Sodium tetrachlorophenolate 

Sodium trichlorophenolate 

Styrol— 

Sulfo BB acid- - 

o-Sulfobenzaldehyde 

4-Sulfo-o-benzoylbenzoic acid 

l-Sulfo-5-nitroanthraquinone 

SuLfophenylmethylpyrazolone 

l-Sulfophenyl-5-pyrazolone-3-carboxylic acid 



Tetraaminoditolylmethane 

Tetrachloro-p-benzoquinone 

Tetrachloroquinone 

Tetraethyldiaminobenzhydrol 

Tetraethyldiaminobenzophenone 

Tetraethyldiaminodiphenylmethane 

Tetraethyldiaminotriphenylmethane 

Tetrahydrcphthalimide 

Tetramethyldiaminoacridine hydrochloride 

Tet r amethy Idi aminobenzophenone 

Tetramethyldiaminobenzoylhydrol 

Tetrame thy Idiaminodiphenylme thane 

Tetrametl^ldiaminotriphenylmethane 

Thicaniline 

Thioanilinedisulfonic acid 

p,p -Thiobis('i-amino-o-benzenesulfonic acid) 

Thiosalicylic acid 

Tobias acid 

a-Toluamide 

Toluene-2,'i-diisocyanate 

p-Ioluenesulfochloride 

4-Toluenesulfonamido-l-aminoanthraquinonesulfonic 
acid. 

P-Toluenesulfonic acid 

Toluene-2,'V,6-triol 

A-Toluic acid 

a-Toluic acid 

m-Toluidine-o-sulfonic acid 

m-Toluidine-p-sulfonic acid 

o-Toluidine-m-sulfonic acid 

o-Toluidine-omega-sulfonic acid 

p-Toluidine-m- sulfonic acid 

p-Toluidine-o-sulfonic acid 

p-Toluidine-o-sulfonic acid, isopropyl ester 



3-Toluidine-6-sulfonic acid 

6-(p-Toluidino)metanilic acid 

a-Tolunitrile 

"i-Tolunitrile 

1,3- ( p-Tolylamino ) anthraquinone- 

p-Tolyl-o-benzoic acid 

o-Tolylcarbinol 

Tolylenediamine 

p-m-Tolylenediamlne 

<V-m-Tolylenediamine 



8-Amino-l-naphthol-5-sulfonic acid. 

8-Amino-l-naphthol-5,7-disulfonic acid. 

2-Naphthol-6-sulfonic acid. 

2-Anthraquinonesulfonic acid, sodium salt. 

Sodium phenoxide. 

Naphthionic acid, sodium salt. 

Sodium phenoxide. 

Sodium phenoxide. 

o-Phenylphenol, sodium salt. 

2,3,'V,6-Tetrachlorophenol, sodium salt. 

2,'V,5-Trichlorophenol, sodium salt. 

Styrene . 

2-Benzoyl-'4-sulfobenzoic acid [COOH=l]. 

o-Formylbenzenesulfonic acid [S03H=l]. 

2-Benzoyl-4-sulfobenzoic acid [COOH=l]. 

5-Nitro-l-anthraquinonesulfonic acid. 

p-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic 

acid. 
5-0xo-l-{p-sulfophenyl)-2-pyTazoline-3-carboxylic 

acid. 



5,5'-Methylenebis [toluene-2,'t-diamine] . 

Chloranil. 

Chloranil. 

'i,4 '-Bis[diethylamino]benzhydrol. 

<i,'4'-Bis [diethylamino]benzophenone. 

4,'i'-Methylenebis [N,N-diethylaniline] . 

A^,^' -Benzylidenebis [ N , N-diethy laniline ] . 

"i-Gyclohexene-l,2-dicarboximide. 

2,7-Bis[diiaethylamino] acridine hydrochloride. 

A, 4 -Bis[dimetliylamino]benzophenone. 

<i,'i '-Bis[dlethylainino]benzhydrol. 

A , 4 ' -Methylenebis [N , N-dimethy laniline ] . 

'i,<i'-Benzylidinebis[N,N-dimethylaniline] . 

4,A^-Thiodianiline. 

6,6 -Thiodimetanilic acid [S03H=l]. 

6,6 '-Thiodimetanilic acid [S03H=l]. 

o-Mercaptobenzoic acid [COOH=l]. 

2-Amino-l-naphthalenesulfonic acid. 

2-Phenylacetamide . 

Isocyanic acid, ^(and 2) -methyl -m-phenylene ester. 

p-Toluenesulfonyl chloride [SOjCl^l]. 

l-Amino-A- (p-toluenesulf onamido ) -2-anthraquinone- 

sulfonic acid. 
p-Toluenesulfonic acid, methyl ester [S03H=l]. 
2-Methylphlorogluclnol. 
p-Toluic acid [COOH=l] . 
Phenylacetlc acid. 

•4-Amino-o-toluenesulfonic acid [S03H=l]. 
2-Amino-p-toluenesulfonic acid [S03H=l]. 
"i-Amino-m-toluenesulfonic acid [S03H=l]. 
(o-Toluidino)methanesulfonic acid [ S03H=l]. 
6-Amino'-m-toluenesulfonic acid [S03H=l]. 
5-Amino-o-toluenesulfonic acid [S03H=l]. 
5-Amino-o-toluenesulfonic acid, isopropyl ester 

[ SO3H =^1] . 
"i-Amino-o-toluenesulfonic acid [S03H=l]. 
5-Amino-2-(p-toluidino)benzenesull'onic acid. 
Phenylacetonitrile. 
p-Tolunitrile. 

l,3-Di(p-toluidino)anthraquinone. 
o-(p-Tolyl)benzoic acid [COOH=l]. 
o-Methylbenzyl alcohol. 
Toluenedl amine . 
Toluene -2 , 5 -diamine . 
Toluene-2,A-diamlne. 



APPENDIX B 



243 



Cyclic intermediates: Glossary of synonymous names — Continued 



Common name 



Standard (Chemical Abstracts) name 



5-m-Tolylenediamine 

m-Tolylenedi amine su If onic acid 

m-Tolylene d i isocyanates 

[ 3- (p-Tolyl)-l-methyltriazeno] acetic acid- 

Tolyl peri acid 

2,4,6-Triaminobenzene trihydrochloride 

2,'4,6-Triaminotoluene trihydrochloride 

Trianthraquinonyldi-imide 

1,4-Trlanthriniide 

Trichlorophenylsilicane 

1,2,4-Trihydroxyanthraquinone 

1,2 , 6-Trihydroxyanthraquinone 

2,'4,6-Trihydroxytoluene 

1,3,5-Trimethylbenzene 

2,'4,6-Trimethylpyridine 

Trinitrophenol 

2,<i,6-Trinitroresorcin 

1,2,4-Trloxyanthraquinone 

1,3,5-Trlphenylhexahydro-s-triazlne 

Triphenyl silicon chloride 

3 , 3 '-U rey lene ani line 

Vinylbenzene 

Vinyltoluene 

Viclanthrene 

Xeny lamine 

m-Xy lidine acetate 

m-Xylidinesulf onic acid 

Xyly 1 chloride 



Toluene-3,5-diamine. 

4,6-Diamino-m-toluenesulfonic acid [S03H=l]. 

Isocyanic acid, <i(and2) -methyl -m-phenylene ester. 

[3-(p-Tolyl)-l-methyltriazen-3-ylJ acetic acid. 

8-(p-Toluidino)-l-naphthalenesulfonic acid. 

1,3,5-Benzenetriainine trihydrochloride. 

Toluene-2,4,6-triamine trihydrochloride. 

l,<i-Bis [l-anthraquinonylamino] anthraquinone . 

1,4-Bis [l-anthraquinonylamino] anthraquinone. 

Trichlorophenylsilane . 

Purpurin. 

Flavopurpurin. 

2-Methylphloroglucinol . 

Mesitylene. 

s-Collidine. 

Picric acid. 

Styphnic acid. 

Purpurin . 

Hexahydro-l,3,5-triphenyl-s-triazine. 

Chlorotriphenylsilane . 

3,3' -Dl aminocarbanilide . 



Styrene . 

Methylstyrene . 

Dinaphtho [l,2,3-cd,3 ,2 ',1 '-lm]perylene. 



•4 -Biphenylamine . 
2,<4-Xylidine acetate. 

2-Amino-3,5-xylenesulfonic acid [S03H=l], 
<C-Chloro-m-xylene . 



244 



SYNTHETIC ORGANIC CHEMICALS, 1963 



C. List of Colour Index and Common Names for Synthetic Organic Pigments 
(Toners and Lakes) 

In the Commission's reports for 1957 and earlier years, individual toners and lakes were 
identified by the names by which they were most commonly known in the literature and in the 
trade. Since 1958 they have been identified by the names used in the second edition of the Colour 
Index. 

The following list of all Colour Index names which appear in tables HA and 12 of this re- 
port is appended for quick reference. The list gives the common names (and coupling compo- 
nents, in the case of azo pigments) for each Colovr Index pigment listed. 





Synthetic organic pigments: List of Colour Index and common nances 


Colour Index name 


Cji.TTisn na.T,e 


Pigment 


Yellow 1 


Hansa Yellow G (2-nitro-p-toluidine and acetoaoetanilide) . 


Pigment 


Yellow 3 


Hansa Yellow lOG (4-chloro-2-nitroaniline and o-chloroacetoacetanilide, . 


Pigment 


Yellow 12 


Benzidine Yellow (3,3 '-dichlorotenzidine and acetoacetanilide; . 


Pigment 


Yellow 13 


Benzidine Yellow (3,3 '-dichlorobenzidine and 2,'4-acetcacetoxylidide) . 


Pigment 


Yellow U 


Benzidine Yellow (3,3 '-dichlorobenzidine and o-acetoacetotoluidide, . 


Pigment 


Yellow 17 


Benzidine Yellow '3,3 '-dichlorobenzidine and o-acetoacetanisldide, . 


Pigment 


Orange 5 


Dinitroaniline Orange (2,4-dinitroaniline and 2-naphthol; . 


Pigment 


Orange 13 


Benzidine Orange (3,3 '-dichlorobenzidine and 3-methyl-l-phenyl-2-pyrazolin-5-cne; . 


Pigment Orange 16 


Dianisidine Orange (o-dianisidine and acetoacexanilide; . 


Pigment 


Red 1 


Para Red (p-nitroaniline and 2-naphthol;. 


Pigment 


Red 2 


Naphthol Red (2,5-diohloroaniline and Naphthol AS). 


Pigment 


Red 3 


loluidine Red (2-nitro-p-tcluidine and 2-naphthol;. 


Pigment 


Red A- 


Chlorinated para Red (2-chloro-<i-nitrc2r,iline and 2-naphthol). 


Pigment 


Red 5 


Naphthol Red (H^,N^-diethyl-4-meth&xymetanilamide and Naphthol AS-ITR;. 


Pigment 


Red 13 


Uaphthol Red (2-nltro-p-toriidine and Uaphthol AS-D, . 


Pigment 


Red 17 


Naphthol Red (5-nitro-o-t&l'-;idine ajid liaphthol A2-D; . 


Pigment 


Red 18 


Toluidine Maroon (2-nitrc-p-tcrjidine and Naphthol AS-BS,. 


Pigment 


Red 22 


Naphthol Red (5-nitro-o- toluidine and tJaphihDl A£j . 


Pigment 


Red 23 


Naphthol Red (5-nitro-o-anisidine and Naphthol AS-BS) . 


Pigment 


Red 38 — 


Pyrazolone Red (3,3 '-dichlorobenzidine and 5-oxo-l-phenyl-2-pyTazoline-3-carboxylic 
acid, ethyl ester). 


Pigment 


Red -;8 


Permanent Red 2B (6-amino-'i-chlGrc-m-tcluenesulfonic acid and 3-hydroxy-2-naphthoic 

acid) . 
Lithol Red R {2-amino-l-naphthalenesulfonic acid and 2-naphthol). 


Pigment 


Red A9 


Pigment 


Red 52 


Lithol Red 2G''' (2-amino-5-chloro-p-toluenesulfonic acid and 3-hydrcxy-2-naphthoic 

acid). 
Red Lake C (2-amino-5-chloro-p-toluenesulfonic acid and 2-naphthol;. 


Pigment 


Red 53 - 


Pigment 


Red 54 


Helio Bordeaux BL ( 1-naphthylamine and l-naphthol-5-sulfonic acid . 


Pigment 


Red 57 


Lithol Rubine B (6-amino-m-toluenesulfonic acid and 3-hydroxy-2-naphthoic acid, . 


Pigment 


Red 60 


Pigment Scarlet 3B (anthranilic acid and 2-naphthol-3,6-diEulfonic acid,. 


Pigment 


Red 63 


BON Maroon (2-amino-l-naphthalenesulfonic acid and 3-hydroxy-2-naphthoic acid, . 


Pigment 


Red 81 


Rhodamine 6G. 


Pigment 


Red 83 


Alizarin Red B. 


Pigment 


Red 90 


Bromo Acid; Eosin. 


(Acid Red 26) 


Scarlet 2R (2.i-xylidine and 2-naphthol-3,6-disulfonic acid,. 


Pigment 


Violet 1 -- 


Rhodamine B. 


Pigment 


Violet 3 


,*thyl Violet B. 


Pigment 


Violet 5 


Helio Fast Rubine ABL. 


Pigment 


Blue 1 


Victoria Pure Blue BO. 


Pigment 


Blue 2 


Victoria Blue B. 


Pigment 


Blue 9 


Setoglaucine. 


Pigment 


Blue K 


Ethyl Violet. 


Pigment 


Blue 15 - 


Phthalocyanine Blue. 


Pigment 


Blue 19 


Aliali Blue. 


Pigment 


Blue 2A 


Peacock Blue Lake. 


Pigment 


Blue 25 


Dianisidine Blue (o-dianisidine and Naphthol AS). 


Pigment 


Green 1 


Brilliant Green. 


Pigment 


Green 2— 


Brilliant Green and Thioflavine. 


Pigment 


Green A 


Malachite Green. 


Pigment 


Green 7 


Phthalocyanine Green. 


Pigment 




Figment Green B. 




Pigment 


Brov/n 3 


Bismarck Brown R ( toluene-2,'i-diamlne, . 




Log«ood Black. 







■"■ Lithol Red 2G has become generally accepted as the name for Pigment Red 52, although the 2d edition of the '-"/ 
Inilex lists this name for Pigment Red 69. 

Note. — When the name of a color is enclosed in parentheses, it indicates that this name is that of the dye from 
which the pigment can be made and that no name for the pigment itself is given in the Colour Index. 



U. S. GOVERNMENT PRINTING OFFICE : 1964 O - 749-026 



REPORTS OF THE UNITED STATES TARIFF COMMISSION ON THE OPERATION OF THE 

TRADE AGREEMENTS PROGRAM 

*Operation of the Trade Agreements Program, June 1934 to April 1948 (Rept. No. 160, 2d ser., 1949) : 
Part I. Summary 

Part II. History of the Trade Agreements Program 
Part III. Trade-Agreement Concessions Granted by the United States 
Part IV. Trade-Agreement Concessions Obtained by the United States 
Part V. Effects of the Trade Agreements Program on United States Trade 

*Operation of the Trade Agreements Program : Second Report, April 1948— March 1949 (Rept. No. 
163, 2d ser., 1950) 

*Operation of the Trade Agreements Program: Third Report, April 1949-June 1950 (Rept. No. 172, 
2d ser., 1951) 

*Operation of the Trade Agreements Program: Fourth Report, July 1950- June 1951 (Rept. No. 
174, 2d ser., 1952) 

*Operation of the Trade Agreements Program: Fifth Report, July 1951-June 1952 (Rept. No. 191, 
2d ser., 1954) 

*Operation of the Trade Agreements Program: Sixth Report, July 1952-June 1953 (Rept. No. 193, 
2d ser., 1954) 

*Operation of the Trade Agreements Program: Seventh Report, July 1953— June 1954 (Rept. No. 
195, 2d ser., 1955) 

*Operation of the Trade Agreements Program : Eighth Report, July 1954-June 1955 (Rept. No. 197, 
2d ser., 1956) 

•Operation of the Trade Agreements Program: Ninth Report, July 1955-June 1956 (Rept. No. 199, 
2d ser., 1957) 

•Operation of the Trade Agreements Program: 10th Report, July 1956-June 1957 (Rept. No. 202, 
2d ser., 1959) 

•Operation of the Trade Agreements Program: 11th Report, July 1957-June 1958 (Rept. No. 204, 

2d ser., 1959) 
•Operation of the Trade Agreements Program: 12th Report, July 1958-June 1959 (TC Publication 

9, 1961) 

Operation of the Trade Agreements Program: 13th Report, July 19.59-June I960 (TC Publication 

51, 1962), 45ff 

Operation of the Trade Agreements Program: 14th Report, July 1960-June 1962 (TC Publication 
120, 1964), 35fS 



NOTE. — The reports preceded by an asterisk (*) are out of print. Those followed by a price may be purchased 
from the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C., 20-i02. See inside 
front cover for additional reports. All U.S. Tariff Commission reports reproduced by the Government Printing 
Office may be consulted in the official depository libraries throughout the United Slates. 



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