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Full text of "Synthetic organic chemicals"

Given By 



V. 5. 5UFT. OF E>OaTMENTS 




^' " 



f^/ M^' 



1 



UNITED STATES TARIFF COMMISSION 



SYNTHETIC 



ORGANIC CHEMICALS 



United States Production 
and Sales, 1964 



TC Publication 167 



Boston Public Library 

■superintendent of Docl'.p .-ifs 



FEB 1 




RECENT REPORTS OF THE UNITED STATES TARIFF COMMISSION ON SYNTHETIC 

ORGANIC CHEMICALS 

*Synthetic Organic Chemicals, United States Production and Sales, 1959 (Rept. No. 206, 2d ser., 

1960) 
*Synthetic Organic Chemicals, United States Production and Sales, 1960 (TC Publication 34, 1961) 
Synthetic Organic Chemicals, United States Production and Sales, 1961 (TC Publication 72, 1962), 

$1.25 
Synthetic Organic Chemicals, United States Production and Sales, 1962 (TC Publication 114, 1963), 

$1.50 
Synthetic Organic Chemicals, United States Production and Sales, 1963 (TC Publication 143, 
1964), $1.50 



NOTE. — ^The reports preceded by an asterisk (*) are out of print. The other reports listed may be purchased from 
the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C., 20402. Seeinside back cover 
for additional reports. All U.S. Tariff Commission reports reproduced by the Government Printing Office may be 
consulted in the official depository libraries throughout the United States. 



UNITED STATES TARIFF COMMISSION 



SYNTHETIC 
ORGANIC CHEMICALS 

United States Production 
and Sales, 1964 



UNDER THE PROVISIONS OF 
SECTION 332 OF THE TARIFF 
ACT OF 1930, AS AMENDED 



U.S. GOVERNMENT PRINTING OFFICE 
WASHINGTON : 1965 



TC Publication 167 



UNITED STATES TARIFF COMMISSION 

Joseph E. Talbot 
Glenn W. Sutton 
James W. Culliton 
Dan H. Fenn, Jr. 
Penelope H. Thunberg 

Donn N. Bent, Secretary 



Address all communications 

UNITED STATES TARIFF COMMISSION 

Washington, D.C. 20436 



For sale by the Superintendent of Documents, Government Printing Office 
Washington, D.C, 20402 - Price $1.25 



CONTENTS 

Page 



Introduction- 
Summary 



PART I. PRODUCTION AND SALES OF TARS, TAR CRUDES, AND CRUDES 
DERIVED FROM PETROLEUM AND NATURAL GAS 

Tars 1 

Tar crudes 1 

Crude products from petroleunn and natural gas for chemical conversion 4 

PART II. PRODUCTION AND SALES OF INTERMEDIATES AND FINISHED 
SYNTHETIC ORGANIC CHEMICALS, BY GROUPS 

General ' 

Cyclic§ intermediates 10 

Dyes 14 

Pigments 26 

Medicinal chemicals 31 

Flavor and perfume materials 36 

Plastics and resin materials 38 

Rubber -processing chemicals 42 

Elastomers (synthetic rubbers) 43 

Plastic izers 44 

Surface -active agents 46 

Pesticides and other organic agricultural chemicals 52 

Miscellaneous chemicals 53 

PART III. ALPHABETICAL LIST OF INDIVIDUAL PRODUCTS, BY GROUPS, 
AND NAMES OF MANUFACTURERS 

Tar crudes 61 

Crude products from petroleum and natural gas for chemical conversion 62 

Cyclic intermediates 64 

Dyes 91 

Pigments 116 

Medicinal chemicals 120 

Flavor and perfume materials 138 

Plastics and resin materials 144 

Rubber -processing chemicals 148 

Elastomers (synthetic rubbers) 152 

Plasticizers 153 

Surface -active agents 156 

Pesticides and other organic agricultural chemicals 172 

Miscellaneous chemicals 178 

Directory of manufacturers 207 

APPENDIXES 

A. U.S. imports of benzenoid intermediates and finished benzenoid products 227 

B. List of Colour Index and common names for synthetic organic pigments (toners and lakes) 229 

C. Employment in the synthetic organic chemicals industry, 1964 (original manufacturers 

only) - --- 230 



Introduction 

This is the forty-eighth annual report of the U.S. Tariff Commission on domestic production 
and sales of synthetic organic chemicals and the raw materials from which they are made. The 
report presents statistics for 1964 on production and sales of crude organic chemicals derived 
from coal, natural gas, and petroleum; of intermediates; and of finished synthetic organic chemi- 
cal products. The finished products are grouped according to their principal use- -dyes, synthetic 
organic pigments, medicinal chemicals, flavor and perfume materials, plastics and resin ma- 
terials, rubber-processing chemicals, elastomers, plasticizers, surface-active agents, pesti- 
cides and other organic agricultural chemicals, and miscellaneous chemicals. The use classifi- 
cations of finished synthetic organic chemicals are based principally on the nnanufacturers ' annual 
reports to the Tariff Commission; other sources include trade associations, the chemical litera- 
ture, chemical dictionaries, encyclopedias, and consultants in the chemical industry. With a few 
exceptions, the report does not cover organic chemicals (such as wood-distillation products, 
essential oils, and naval stores) that are derived from natural (vegetable) sources by simple 
extraction or distillation. The Commission has compiled the statistics given in this report from 
information supplied by the 800 primary manufacturers listed in part III. 

The first section of the report includes the statistics on all products and groups of products 
which conform to the general rules of publishability. The second section lists all the chemicals 
and chenaical products on which data are reported and identifies the manufacturers of each. Each 
reporting company has been assigned an identification symbol consisting of a combination of not 
more than three capital letters, selected in most instances with the approval of the manufac- 
turer, and usually bearing some relationship to the company name. The identification symbols 
are permanent and, except for such changes as may be necessary, will be used in all future re- 
ports in this series. Like the six immediately preceding reports, this report includes data on 
only those individual chemicals for which the volume of production or sales in the year covered 
exceeded 1, 000 pounds or for which the value of sales exceeded $1, 000. 

The raw materials referred to in this report are obtained from coal, crude petroleum, natural 
gas, and certain other natural materials, such as vegetable oils, fats, rosin, and grains. Crude 
organic chemicals are derived from coal by thermal decomposition, from petroleum and natural 
gas by catalytic cracking and by distillation or absorption, and from other natural sources by fer- 
mentation. Production of these crude organic chemicals is the first step in the manufacture of 
synthetic organic chemicals. From these crudes, intermediates are obtained by synthesis or re- 
fining; most of the intermediates are then converted into finished chemical products, such as 
medicinal chemicals, plastics and resin materials, and dyes. More than half ot the total produc- 
tion of intermediates is not sold directly to the ultimate consumer, but is used by the producing 
companies themselves in their manufacturing processes. The statistics given in this report in- 
clude data for all known domestic producers of the items covered and are therefore virtually 
complete. 

In this report the statistics on production of the individual chemicals reported by manufac- 
turers include the total output of the companies' plants, i. e. , the quantities produced for con- 
sumption within the producing plants, as well as the quantities produced for domestic and 
foreign sale. The quantities reported as produced, therefore, generally exceed the quantities 
reported as sold. Some of these differences, however, are attributable to changes in inventories. 
As specified in the reporting instructions that the Commission sends to manufacturers, and as 
used in this report, production and sales (unless otherwise specifically indicated) are defined as 
follows: 

Production is the total quantity of a commodity made available by original manufacture only. It is 
the sum (expressed in terms of 100-percent active ingredient unless otherwise specified) of the 
quantities of a commodity- - 

(1) Produced, separated, and consumed in the same plant or establishment (a connmodity 

is considered to be separated when it is isolated from the reaction system and/or 
when it is weighed, analyzed, or otherwise measured). Byproducts and coproducts 
not classified as waste materials are also included; 

(2) Produced and transferred to other plants or establishments of the same firm; 

(3) Produced and sold to other firms (including production for others under toll agree- 

ments-'-); and 

(4) Produced and held in stock. 



A toll agreement is an agreement between two firms, under which one firm furnishes the raw materials and pays the processing costs 
and the other firm prepares the finished product and returns it to the first firm. 



vi INTRODUCTION 

Production excludes-- 

(1) Purification of a commodity unless specifically requested in the reporting instructions; 

(2) Intermediate products that are formed in the manufacturing process but are not iso- 

lated from the reaction system--that is, not weighed, analyzed, or otherwise 
measured; and 

(3) Materials that are used in the process but are recovered for reuse or sale; and waste 

products that have no economic significance. 

Sales are defined as actual sales of commodities by original manuiactwreTS only. Sales include-- 

(1) Shipments of commodities for donnestic use and for export, or segregation in a ware- 

house when title has passed to the purchaser in a bonafide sale; 

(2) Shipments of a commodity produced 6y oiAers under toll agreements; and 

(3) Shipments to subsidiary or affiliated companies. 

Sales exclude-- 

(1) All intracompany transfers within a corporate entity; 

(2) All sales of purchased commodities; and 

(3) All shipments of a commodity produced for others under toll agreements. 

The value of a sale is the net selling price, f. o. b. plant or warehouse, or delivered value, 
whichever represents the normal industry practice. 

Data on the chenaicals covered in this report are usually given in terms of undiluted mate- 
rials. Products of 95 percent or more purity are considered to be 100 percent pure. The principal 
exceptions ai;e the statistics on dyes and a few solvents, which are reported in terms of commer- 
cial concentrations; the statistics on certain plastics and resins, which are reported on a dry 
basis; and the data on sales of antibiotics, which are reported on the basis of specific conditions 
mentioned in the section on medicinal chemicals. The report specifically notes those products for 
which the statistics are reported in terms of commercial concentrations. 

The average unit values of sales for groups of products shown in the tables accompanying 
this report are weighted averages for products which vary widely in unit values and in the quan- 
tities sold. 

In this report, statistics are presented in as great detail as is possible without revealing the 
operations of individual producers. Statistics for an individual chemical or group of chemicals 
are not given unless there are three or more producers no one or two of which may be predomi- 
nant. Moreover, even when there are three or more producers, statistics are not given if there 
is any possibility that their publication would violate the statutory provisions relating to unlaw- 
ful disclosure of information accepted in confidence by the Commission. 2 

Statistics on tars and tar crudes include data furnished directly to the Tariff Commission by 
distillers of coal tar, water-gas tar, and oil-gas tar, and data furnished to the Division of 
Bituminous Coal, U.S. Bureau of Mines, by coke-oven operators. 

Statistics on U. S. general imports in 1964 of benzenoid intermediates and finished benzenoid 
products that entered under schedule 4, parts IB and IC, of the Tariff Schedules of the United 
States are given in appendix A. Appendix B is a cross-reference list of the Colour Index and com- 
mon names of synthetic organic pigments. Appendix C presents the results of a one-time survey 
on employment in the synthetic organic chemical industry made at the request of the Special 
Representative for Trade Negotiations. Statistics are given on total employment, employnnent by 
States, and by product groups, in 1964. 

The Glossary of Synonymous Names of Cyclic Intermediates, which appeared as appendix B 
in previous reports, has been deleted from this report. Information formerly included in the 
glossary may now be found in the more comprehensive SOCMA Handbook: Commercial Organic Chemical 
Names, recently published by the Chemical Abstracts Service of the American Chemical Society, 
or in the Colour Index (2d edition), published in 1956 by the Society of Dyers and Colourists. 



2 Sec. 5, U.S.C. 139b and sec. 18, U.S.C. 1905. 



Summary 

Combined production of all synthetic organic chemicals, tars, tar crudes, and crude products 
from petroleum and natural gas in 1964 was 135, 716 million pounds--an increase of 12. 2 percent 
over the output in 1963 (see table 1). Sales of these materials in 1964, which totaled 72, 668 mil- 
lion pounds, valued at $9, 242 million, were 13. 7 percent larger than in 1963 in terms of quantity 
and 8. 5 percent larger in terms of value. These figures include data on production and sales of 
chemicals measured at several successive steps in the manufacturing process, and therefore they 
necessarily contain some duplication. 

In 1964, production of all synthetic organic chemicals, including cyclic intermediates and 
finished chemical products, totaled 78, 678 million pounds, or 11.8 percent more than the output 
in 1963. Production of flavor and perfume materials (91 million pounds) was 22. 8 percent larger 
in 1964 than in 1963; that of cyclic intermediates (14,896 million pounds) was 16.7 percent 
larger; that of plasticizers (951 million pounds) was 14. percent larger; and that of plastics 
and resin materials (10, 103 million pounds) was 12. 6 percent larger. 

The output of most of the other groups of synthetic organic chemicals also increased in 1964 
compared with 1963. Production of synthetic organic pigments (44 million pounds) was 11.8 
percent greater; that of rubber-processing chemicals (261 million pounds) was 11.5 percent 
greater; that of miscellaneous organic chemicals (45,681 million pounds) was 11. percent 
greater; that of elastomers (3,421 million pounds) was 7.4 percent greater; that of surface- 
active agents (2, 119 million pounds) was 7. percent greater; that of medicinal chemicals (144 
million pounds) was 3. 5 percent greater; and that of pesticides and other organic agricultural 
chemicals (783 million pounds) was 2.5 percent greater. The apparent decline of 9. 6 percent in 
the production of dyes is the result of a change in the method of reporting data on certain dyes. 
Therefore, the figures on production (184 million pounds) and on the quantity of sales (178 mil- 
lion pounds) are not comparable with those for previous years. The value of sales of dyes ($264 
million) in 1964 was 10. 2 percent higher than in 1963. 

TABLE 1. — Synthetic organic chemicals and their raw materials: U.S. production and sales, 1963 and 1964 



Increase 

or 

decrease 

(-), 1964 

over 

1963^ 



Quanti ty 



Increase 

or 

decrease 

(-), 1964 

over 

1963^ 



Increase 
or 

decrease 

(-), 1964 

over 

1963^ 



Grand total 

Tar 

Tar crudes 

Crude products from petroleum and 
natural gas ■ 

Synthetic organic chemicals, total- 
Intermediates 

Dyes 

Synthetic organic pigments 

Medicinal chemicals 

Flavor and perfume materials 

Plastics and resin materials 

Rubber-processing chemicals 

Elastomers (synthetic rubbers) — 

Plasticizers 

Surface -active agents 

Pesticides and other organic 

agricultural chemicals 

Miscellaneous chemicals 



120,928 



135,716 



Million 
poands 
63,898 



Million 
pounds 
72,668 



Million 
dollars 
8,517 



9,242 



6,719 
8,745 



35,121 
70,343 



7,629 
9,547 



39,862 
78,678 



13.6 
9.0 



11.8 



2,907 
5,485 



18,460 
37,046 



3,361 
6,076 



20,465 
42,766 



15.6 
10.8 



32 

119 



7,793 



34 
131 



619 
8,458 



12,768 

204 

39 

139 

74 

8,968 

234 

3,185 

835 

1,981 

763 
41,153 



14,896 

184 

44 

144 

91 

10,a03 

261 

3,421 

951 

2,119 



783 



45, e 



16.7 
-9.6 
11.8 

3.5 
22.8 
12.6 
11.5 

7.4 
14.0 

7.0 

2.5 

11.0 



5,429 

187 
34 

114 

67 

7,516 

177 
2,836 

750 
1,790 

651 
17,495 



6,470 

178 
35 

119 

80 

8,727 

184 
2,958 

905 
1,900 

692 
20,518 



19.2 
-4.6 
4.6 
4.2 
19.4 
16.1 
4.0 
4.3 
20.7 
6.2 

6.3 
17.3 



643 

240 

80 

639 

77 

2,003 

119 

767 

168 

325 

369 
2,363 



711 
264 

84 
646 

84 
2,120 
123 
810 
188 
350 

427 
2,651 



10.8 
9.9 



8.5 



10.6 
10.2 
5.7 
1.0 
8.2 
5.8 
3.7 
5.6 
11.5 



44.2 
12.2 



■"• Percentages calculated from figures rounded to thousands. 



PART I. PRODUCTION AND SALES OF TARS, TAR CRUDES, 
AND CRUDES DERIVED FROM PETROLEUM AND NATURAL GAS 



Tars 

Coal tar is produced chiefly by the steel industry as a byproduct of the manufacture of coke; 
water-gas tar and oil-gas tar are produced by the fuel-gas industry. Production of coal tar, 
therefore, depends on the demand for steel; production of water-gas tar and oil-gas tar reflects 
the consumption of manufactured gas for industrial and household use. Water-gas and oil-gas 
tars have properties intermediate between those of petroleum asphalts and coal tars. Petroleum 
asphalts are not usually considered to be raw materials for chemicals. 

The quantity of tar produced from coal in the United States in 1964 was 763 million gallons, 
or 13. 6 percent more than the 672 million gallons produced in 1963. U. S. production of water- 
gas tar and oil-gas tar was not reported to the Commission for 1963 or 1964; production of these 
tars amounted to 19 million gallons in 1962, the last year for which production was reported to 
the Tariff Connmission. 

Total consumption of tar in 1964 amounted to 747 million gallons, of which 602 million gal- 
lons was consumed by distillation, 128 million gallons as fuel, and 17 nnillion gallons in miscel- 
laneous uses. 



TABLE 2. 



• Tar: U.S. production and consumption, 1963 and 1964 

[in thousands of gallons] 



PRODUCTION 

Coal tar from coke-oven byproduct plants"'' 

CONSUMPTION 
Total 

Tar consumed by distillation, total 

Coal tar distilled or topped by coke-oven operators^ 

Coal tar, water-gas tar, and oil-gas tar distilled by producers and tar 
distillers^ 

Tar consumed chiefly as fuel'"' 

Tar consumed otherwise than by distillation or as fuel, total 

Coal tar consumed at coke-oven plants for roads and upkeep''" 

Coal tar, water-gas tar, and oil-gas tar processed at tar refineries, crude tar 
consumed for upkeep at such refineries, and tar consumed in making gas and in 
special-purpose tar blends 



671,876 



691,509 



762,918 



7'i6,900 



573,096 



289,569 
283,527 
91,313 
27,100 



601,753 



55§" 



26,542 



293,957 
307,796 
127,872 
17,275 



371 



16,9(X 



Reported to the U.S. Bureau of Mines. 

Reported to U.S. Tariff Commission. Represents tar purchased from companies operating coke ovens and gas-retort 
plants and distilled by companies operating tar -distillation plants. 

Tar Crudes 

Tar crudes are obtained from coke-oven gas and by distilling coal tar, water-gas tar, and 
oil-gas tar. The most important tar crudes are benzene, toluene, xylene, naphthalene, and 
creosote oil. Some of the products produced from coal tar are identical with those produced from 
petroleunn and natural gas. Data for materials derived from these latter sources are included, 
for the most part, in or with the statistics for materials derived from coal tar, which are shown 
in tables 3 and 4A.-'- 



^ See also table 4B, pt. m, which lists these pio ducts alphabetically and identifies the manufactuieis. 



2 SYNTHETIC ORGANIC CHEMICALS, 1964 

Domestic production of industrial and specification grades of benzene reported by coke-oven 
operators and petroleum operators^ in 1964 amounted to 730 million gallons--12.8 percent more 
than the 647 million gallons reported for 1963. These statistics include data for benzene pro- 
duced from light oil and petroleum. Sales of benzene by coke-oven operators and petroleum 
operators in 1964 amounted to 464 million gallons, valued at $104 million, compared with 421 
million gallons, valuea at $96 million, in 1963. In 1964 the output of toluene2 (including material 
produced for use in blending in aviation fuel) amounted to 495 million gaIlons--21. 9 percent 
more than the 406 million gallons reported for 1963. Sales of toluene in 1964 were 261 million 
gallons, valued at $44 million, compared with 207 million gallons, valued at $35 million, in 
1963. The output of xylene^ in 1964 (including that produced for blending in motor fuels) was 343 
million gallons, compared with 335 million gallons in 1963. About 98 percent of the 343 million 
gallons of xylene produced in 1964 was obtained from petroleum sources. 

Production of crude naphthalene in 1964 (including 315 million pounds of petroleum-derived 
naphthalene) amounted to 740 million pounds, compared with 627 million pounds in 1963. Sales 
of coal-tar-derived naphthalene^ in 1964 were 234 million pounds, valued at $6 million, com- 
pared with 209 million pounds, valued at $7 million, in 1963. In 1964 the output of creosote oil 
for wood preservation was 113 million gallons (100-percent creosote basis), compared with 98 
million gallons in 1963. Production of road tar in 1964 was 56 million gallons, compared with 
58 million gallons in 1963. 

TABLE 3 —Tar and tar crudes- Summary of U.S. production of specified products, average 1950-54, 

annual 1963 and 1964 

[ Leaders are used where the reported data are accepted in confidence and may not be published 
or where no data were reported] 



Tar^ 

Benzene : ^ 

Tar distillers^ 

Coke-oven operators 

Petroleum operators 

Total 

Toluene : 

Tar distillers 

Coke-oven operators 

Petroleum operators 

Total 

Xylene : 

Tar distillers 

Coke-oven operators 

Petroleum operators 

Total 

Naphthalene, crude: 

Solidifying at less than 79° C.^ — 

Petroleum naphthalene, all grades - 

Total 



Creosote oil (Dead oil)^ 1,000 gal 



Unit 

of 

quantity 



1,000 gal- 

1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 

1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 

1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 

1,000 Ib-- 
1,000 lb — 
1,000 lb- 



Average 
1950-5A 



876,070 

41,389 
163,356 
46,635 



251,380 

7,497 
32,981 
3,725 



121,203 

1,373 
9,028 
78,188 



88,589 
307,537 



307,537 
109,946 



671,876 

9,098 
112,427 
525,889 



647,414 

3,204 

25,794 

377,205 



406,203 

509 

6,888 

327,460 



334,857 



338,715 
288,240 



626,955 

87,894 



762,918 



118,944 
611,294 



730,238 



25,521 
469,519 



495,040 



7,119 
336,079 



343,198 



425,690 
314,664 



740,354 
102,114 



Increase, or decrease (-) 



1964 over 
1950-54 



-27.2 
1,210.8 



-22.6 
481.6 



-21.2 
329.8 



287.4 
38.4 



140.7 
-7.1 



1964 over 
1963 



-1.1 
24.5 
21.9 



3.4 
2.6 
2.5 



25.7 
9.2 

18.1 



^ Includes data for oil-gas, water-gas, and gas-retort tar reported to the American Gas Association for 1950-54 
only, and for coal tar reported to the Division of Bituminous Coal, U.S. Bureau of Mines. 

2 Includes data for motor-grade benzene in 1950-54. Production in 1964 by coke-oven operators was 864 thousand 
gallons, with sales of 864 thousand gallons, valued at 197 thousand dollars. 

^ Includes data for benzene produced from imported crude light oil. 

'• Includes data for material produced for use in blending motor fuels. Statistics are not comparable with monthly 
figures, which included some o-xylene now shown in table 7A. 

5 Figures include production by tar distillers and coke-oven operators and represent combined data for the com- 
mercial grades of naphthalene to avoid disclosure of the operations of individual companies. Because of conversion 
between grades, the figures may include some duplication. 

^ Includes data for creosote oil produced by tar distillers and coke-oven operators and used only m wood preserv- 
ing. Data for production of creosote oil in coal-tar solution have been excluded because the figures for 1950-54 are 
not comparable with the figures for 1963 and 1964. Production figures for 1950-54 are for the distillate sold or 
consumed as such; and, for 1963 and 1964, the production of the distillate is on a 100-percent-oreosote basis. 



2 Statistics on production and sales of benzene, toluene, and xylene by tar distillers cannot be shown because publication would reveal the 
operations of individual companies, 

3 For sales of petroleum-derived naphthalene, see table 5A, 



TAR CRUDES 



TABLE 4A. — Tar crudes.- U.S. production and sales, 1964 

[Listed below are all tar crudes for which any reported data on production or sales may be published. (Leaders are 
used where the reported data are accepted in confidence and may not be published or where no data were reported.) 
Table "iB in pt. Ill lists separately all products for which data on production or sales were reported and iden- 
tifies the manufacturers reporting to the U.S. Tariff Commission] 



Sales 



Quantity 



Unit 
value-"- 



Crude light oil: Coke-oven operators 

Intermediate light oil: Coke-oven operators 

Light-oil distillates: 

Benzene, specification and industrial grades, total^ 

Coke-oven operators 

Petroleum operators 

Toluene, all grades, total^ ^ 

Coke-oven operators 

Petroleimi operators 

Xylene, total^ 3 

Coke-oven operators 

Petroleum operators 

Solvent naphtha: Coke-oven operators^ 

Other light-oil distillates, total 

Tar distillers 

Coke-oven operators* 

Pyridine crude bases (dry basis) 

Naphthalene, crude (tar distillers and coke-oven 

operators), total' 

Solidifying at — 

Less than 74° C 

74° C. to less than 79° C 

Crude tar-acid oils: 

Tar distillers 

Coke-oven operators 

Creosote oil (Dead oil) (tar distillers and coke-oven 

operators) (100^ creosote basis), total^ 

Distillate as such (100^ creosote basis) 

Creosote content of coal-tar solution (100^ 

creosote basis) 

All other distillate products^ 

Tar, road 

Tar (crude and refined) for other uses' 

Pitch of tar: 

Hard (water softening point above 160° F. ) 

Other^° — 



1,000 gal- 
1,000 gal- 

1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 



1,000 Ib- 



1,000 Ib- 
1,000 Ib- 



1,000 gal- 
1,000 gal- 



1,000 gal— 
1,000 gal— 

1,000 gal— 

1,000 gal— 
1,000 gal— 
1,000 gal— 

1,000 tons- 
1,000 tons- 



248,669 
5,392 

730,238 

118,944 

611,294 

495,040 

25,521 

469,519 

343,198 

7,119 

336,079 

4,484 



9,101 

464 



425,690 



53,702 
2,185 

464,032 

119,070 

344,962 

260,796 

25,530 

235,266 

153,927 

7,135 

146,792 

4,193 

8,721 

3,004 

5,717 



234,362 



1,000 
dollars 
6,709 
224 

104,182 

25,263 

78,919 

43,524 

4,729 

38,795 

28,455 

1,617 

26,838 

839 

1,002 

378 

624 



6,237 



78, 179 
347,511 



328 
24,893 



113,272 



70,804 
163,558 



317 
24,145 



98,007 



102,114 
11,158 



55,696 
19,968 



87,310 

10,697 

14, 617 
54,879 
18,950 

701 
418 



1,350 
4,887 



139 
3,749 



21,014 



17,701 

' 3,313 

2,550 
7,549 
3,743 

27,600 
16,085 



.20 

■' .31 

.17 
.14 
.20 

39.37 
38.48 



■'- Unit value per gallon, pound, or ton, as specified. 

^ Data reported by tar distillers are not included because publication would disclose the operations of individual 
companies. Production of benzene, toluene, and solvent naphtha by tar distillers decreased in 1964, compared with 
1963; production of xylene increased. The annual production statistics for petroleum operators on benzene, toluene, 
and xylene are not comparable with the combined monthly production figures, due to fiscal year revisions. 

^ Includes data for material produced for use in blending motor fuels. 

* Production reported by coke-oven operators Includes 864 thousand gallons of motor-grade benzene, sales of which 
were 864 thousand gallons, valued at 197 thousand dollars. 

' Statistics represent combined data for the commercial grades of naphthalene. Because of conversion of naph-tha- 
lene from one grade to another, the figures may include some duplication. 

* Statistics include only data for creosote oil sold for, or used in, wood preserving. In 1964, production of 
creosote in coal-tar solution (1005^ solution basis) amounted to 19,291 thousand gallons; sales were 17,444 thousand 
gallons, valued at 3,313 thousand dollars, with a unit value of $0.19 per gallon. 

' Includes value of coal tar used in preparing creosote in coal-tar solution. 

* Includes data for crude cresylic acid, dry distilled tar acid, and neutral oils produced by tar distillers, and 
for crude sodium phenolate produced by coke-oven operators. 

' Includes data for tar used for paint, pipe covering, satiiratlng, and other uses. 
■^° Includes soft and medium pitch of tar (water softening points less than 110° F. , and 110° F. to 160° F. ASIM 
D61-24), pitch of tar coke, and pitch emulsion. 

Note. — Statistics for materials produced in coke and gas-retort ovens are compiled by -the Division of Bituminous 
Coal, U.S. Bureau of Mines, Department of the Interior. Statistics for materials produced in tar and petroleum re- 
fineries are compiled by the U.S. Tariff Commission. 



4 SYNTHETIC ORGANIC CHEMICALS, 1964 

Some of the products included in the statistics in table 4A are derived from other products 
for which data are also included in the table. The statistics, therefore, involve considerable 
duplication, and for this reason no group totals or grand totals are given. After duplication has 
been eliminated insofar as possible, it is estimated that the net value of the output of these 
products and of tar burned as fuel was $460 million in 1964, compared with $406 million in 1963 
and $423 million in 1962. 



Crude Products from Petroleum and Natural Gas for Chemical Conversion 

Crude products that are derived from petroleum and natural gas are related to the interme- 
diates and finished products made from such crudes in much the same way that crude products 
derived from the distillation of coal tar are related to their intermediates and finished products. 
Many of the crude products derived from petroleum are identical with those derived from coal 
tar (e. g. , benzene, toluene, and xylene). Considerable duplication exists in the statistics on 
the production and sales of petroleum crudes because some of these crude chemicals are con- 
verted to other crude products derived from petroleum and because data on some production and 
sales are reported at successive stages in the conversion processes (see table 5A*). Notwith- 
standing these duplications, the statistics are sufficiently accurate to indicate trends in the in- 
dustry and to serve as a basis for general comparison. Many of the crude products for which 
data are included in the statistics may be used either as fuel or as basic materials from which to 
derive other chemicals, depending on prevailing economic conditions. In this report, every effort 
has been made to exclude data on materials that are used as fuel. However, data are included on 
toluene and xylene which are not used directly as fuel but in blending aviation and motor- grade 
gasolines. 

TABLE 5A.-- Crude products from petroleum and natural gas for chemical conversion: U.S. production 

and sales, 1964 

[Listed below are the crude products from petroleum and natural gas for chemical conversion for which any reported 
data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence 
and may not be published or where no data were reported.) Table 5B in pt. Ill lists separately all products from 
petroleum and natxiral gas for chemical conversion for which data on production or sales were reported and iden- 
tifies the manufacturer of each] 



Production 



Sales 



Qiiantity 



Value Unit value^ 



Grand total 

AROMATICS AND NAPHTHENES^ 
Total 

Alkyl aromaticE, distillates, and solvents 



Benzene (1° and 2°), total- 
Benzene, 1° 

Benzene, 2° 



1,000 

pounds 

39,862,500 



1,000 

pounds 

20,465,279 



1.000 
dollars 
618,971 



Per 
pound 

$0,030 



12,574,423 



7,578,662 



180,150 



1,658,622 
4,511,350 



1,935,826 
2,545,820 



22,155 
78,919 



.011 
.031 



Cresylic acid, crude 

Naphthalene, all grades- 

Naphthenic acids, total- 
Acid No. 150-199 

All other 



3,616,761 
894,589 



37,655 
314,664 



30,482 



235,419 
14,625 



9,961 
1,412 



5,399 
25,083 



4,122 
10, 503 



Toluene, all grades, total- 
Nitration grade, 1° 

Pure commercial grade, 2° 
All other^ 



Xylenes, mixed, total - 

3° - 

All other^ 



2,290,312 
163,401 
959,691 

2,423,129 



All other aromatlcs and naphthenes*- 
See footnotes at end of table. 



364,797 
2,058,332 



185,117 



1,377,294 

333,089 

1,058,371 



415 
997 



38,795 



31,976 

6,819 

26,838 



237,310 
821,061 



78,218 



6,617 
20,221 



2,070 



.097 
.101 
.095 

.023 
.023 



.025 
.028 
.025 



4 See also table 5B, p. III, which lists these products alphabetically and identifies the manufacturers. 



CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS 



TABLE 5A. 



-Crude products prom petroleum and natural gas for chemical conversion: U.S. production 
and sales, i 964 --Continued 



Quantity 



Unit 
value -^ 



ALIPHATIC HyDROCARBONS 

Total- 

C2 hydrocarbons, total 

Acetylene' 

Ethane 

Ethylene 

C3 hydrocarbons J total 

Propane 

Propylene 

C^ hydrocarbons, total 

1,3-Butadiene, grade for rubbers (elastomers) 

Butadiene and butylene fractions 

n-Butane 

1-Butene and 2-butene mixture^ 

Isobutane 

Isobutylene 

All other'' 

C5 hydrocarbons, total 

Isoprene (2-lfethyl-3-butadiene) 

All other^ 

All other aliphatic hydrocarbons and derivatives, total- 

Diisobutylene (Diisobutene) 

n-Heptane 

Heptenes, ■mixed 

Hexane 

Nonene ( Tripropylene) 

Polybutene' 

Tetrapropylene 

Ifydrocarbon derivatives •'-° 

All other^^ 



1,000 

pounds 

27,288,077 



10,2^8,95^ 



437,190 
1,170,562 
8,641,202 

7,227,166 



3,656,661 
3,570,505 



6,671,545 



2,491,C 

305,092 
1,700,843 
1,175,713 
552,766 
220,467 
225,578 

477,941 

81,423 

396,518 

2,662,471 



21,474 

66,395 

254,143 

130,192 

161,544 

124,954 

432,839 

29,262 

1,441,668 



1,000 

pounds 

12,886,617 



2,795,106 



34,198 
383,540 
2,377,368 

4,085,337 



2,624,874 
1,460,463 



4,164,309 



1,508,684 
68,961 
927,488 

1,039,428 
328,306 
130,134 
161,308 

79,847 



1,762,018 
22,113 



140,561 

143,166 

343,891 

17,109 

1,095,178 



1,000 
dollars 
438,821 



3,475 

3,172 

110,792 

56,548 



24,548 
32,000 



214,454 



157,260 
1,571 
10,737 
31,140 
4,204 
5,898 
3,64^ 

3,360 



47,020 



1,386 

5,328 

4,292 

9,479 
5,821 
20,714 



pound 

$0,034 



.102 
.008 
.047 



.014 
.009 
.022 



.051 
.104 
.023 
.012 
.030 
.013 
.045 
.022 



.063 

.038 

.030 

.028 
.340 
.019 



^ Calculated from rounded figures. 

^ The chemical raw materials designated as aromatios are in some cases identical with those obtained from the dis- 
tillation of coal tar. However, the statistics given in the table above relate only to such materials as are derived 
from petroleum and natural gas. Statistics on aromatic chemicals from all sources are given in table 4A, "Tar Crudes." 

^ Includes toluene and xylene used as solvents, as well as that which is blended In aviation and motor gasolines. 

* Includes data for 90-percent benzene, sodium cresylate, sodium oarbolate and phenate, and miscellaneous cyclic 
hydrocarbons . 

' Production figures on acetylene from calcium carbide for chemical synthesis are collected by the U.S. Bureau of 
the Census. 

* The statistics represent principally the butene content of crude refinery gases from which butadiene is manu- 
factured. 

"^ Includes data for 1-butene, 2-butene, mixed butylenes, and mixed olefins. 

^ Includes data for pentanes, pentenes, and C5 hydrocarbon mixtures. 

' Includes compounds having a molecular weight of 3,000 or less. 
^° Includes data for di-tert-butyldisulfide and miscellaneous mercaptans. 

■'■•'■ Includes data for alpha olefins, methane, propane -propylene mixture, octanes, 1-dodecene, eicosane, and hydro- 
carbon mixtures. 

The output of crude products derived from petroleum and natural gas as a group amounted 
to 39, 862 million pounds in 1964, or 13. 5 percent more than the 35, 121 million pounds reported 
for 1963. The larger output in 1964 is accounted for chiefly by increased production of benzene, 
toluene, ethylene, and propylene. Sales of crude chemicals from petroleum in 1964 were 20,465 
million pounds, valued at $619 million, compared with 18, 460 million pounds, valued at $573 
million, in 1963. 

The output of all aromatic and naphthenic products amounted to 12, 574 million pounds in 
1964, compared with 11,292 million pounds in 1963. Sales in 1964, which amounted to 7, 579 
million pounds, valued at $180 million, were 733 million pounds larger, and valued at $16 mil- 
lion more, than those in 1963. Naphthalene was produced from petroleum sources in substan- 
tially greater quantities in 1964 than in 1963. The output of 1° and 2° benzene from petroleum 
amounted to 4, 511 million pounds in 1964- -16. 2 percent more than the 3, 881 million pounds 
produced in 1963. The output of toluene in 1964 was 3,413 million pounds--24. 5 percent more 



^ SYNTHETIC ORGANIC CHEMICALS, )964 

than the 2, 742 million pounds produced in 1963. Production of xylene was 2,423 million pounds 
in 1964, compared with 2, 361 million pounds in 1963. These figures include toluene and xylene 
used in blends in aviation and motor- grade gasolines. The output of naphthenic acids amounted 
to 30 million pounds in 1964, comipared with 25 million pounds produced in 1963. Production of 
cresylic acid in 1964--38 million pounds--was 19. 8 percent more than in 1963. 

Production of all aliphatic hydrocarbons and derivatives from petroleum and natural gas was 
27,288 million pounds in 1964, compared with 23,829 million pounds in 1963. Sales of these prod- 
ucts were 12, 887 million pounds, valued at $439 million, in 1964, compared with 11, 614 million 
pounds, valued at $410 million, in 1963. The statistics on production of acetylene (table 5A) in- 
clude only acetylene produced from natural gas and used as a raw material in the production of 
other chemical. Total production of acetylene for chemical synthesis is reported to the U.S. 
Bureau of the Census. In 1964, production of acetylene from all sources except that produced by 
railroad shops, shipyards, and small establishments using portable generators, amounted to 
1,051 million pounds . Production of ethylene was 8, 641 million pounds in 1964, or 14.9 percent 
more than the 7, 518 nnillion pounds produced in 1963. The output of propane and propylene was 
7, 227 million pounds in 1964-- 25. 6 percent more than the 5, 756 million pounds produced in 
1963. Production of 1 , 3-butadiene, one of the principal ingredients of S-type synthetic rubber, 
was 2,491 million pounds in 1964, compared with 2, 324 million pounds in 1963. The output of 
1 , 3-butadiene in 1 964-- 7. 2 percent more than that in 196 3 --was the largest on record. 

The following tabulation shows the number of companies that reported production of organic 

chemical crudes in 1964: ,, , 

number 

of 
Chemical group companies 

Tar crudes 14 

Petroleum crudes 74 



PART II. PRODUCTION AND SALES OF INTERMEDIATES AND 
FINISHED SYNTHETIC ORGANIC CHEMICALS, BY GROUPS 

General 

On the basis of their principal uses, the synthetic organic chemicals covered in this report 
are classified either as intermediates or as finished products. Finished products, in turn, are 
grouped as follows: Dyes, synthetic organic pigments, medicinal chemicals, flavor and perfume 
materials, plastics and resin materials, rubber-processing chemicals, elastomers (synthetic 
rubbers), plasticizers, surface-active agents, pesticides and other organic agricultural chemi- 
cals and miscellaneous synthetic organic chemicals. Most of these groups are further subdi- 
vided according to chemical classes, into cyclic and acyclic compounds. As most of the inter- 
mediates are used in the manufacture of finished products, aggregate figures that cover both 
intermediates and finished products necessarily include considerable duplication. 

Total production of synthetic organic chemicals (intermediates and finished products com- 
bined) in 1964 was 78, 678 million pounds, or 11.8 percent more than the output of 70, 343 million 
pounds reported for 1963 (see table 6). Sales of synthetic organic chemicals in 1964 amounted to 
42 766 million pounds, valued at $8, 458 million, compared with 37, 046 million pounds, valued 
at $7 793 million, in 1963. Production of all cyclic products (intermediates and finished products 
combined) in 1964 totaled 25, 506 million pounds, or 13.4 percent more than the 22, 490 million 
pounds produced in 1963. The output of acyclic organic chemicals in 1964 amounted to 53, 172 
million pounds-- 11. 1 percent more than the 47, 853 million pounds reported for 1963. 



TABLE 6. — Synthetic organic chemicals; Summary of U.S. production and sales of intermediates and finished 
products, average 1957-59, annual 1963 and 1964 

[ Production and sales in thousands of pounds; sales value in thousands of dollars ] 



Average 
1957-59 



Increase, or decrease (-) 



1964 over 
1957-59 



1964 over 
1963 



Organic chemicals, cyclic and acyclic, 
grand total: 

Production . 

Sales 

Sales value 

Cyclic, total: 

Production 

Sales 

Sales value 

Acyclic, total: 

Production 

Sales r 

Sales value 

I. Intermediates, Cyclic 

Production 

Sales 

Sales value 

2. Dyes, Cyclic 

Production 

Sales 

Sales value 

3. Synthetic Organic Pigments, Cyclic 

Production 

Sales 

Sales value 



45,598,853 

23,744,812 

5,743,764 

14,381,651 
8,829,037 
2,785,100 

31,217,202 
14,915,775 
2,958,664 



7,343,167 

2,919,264 

481,920 



150,830 
141,731 
182,513 



38,603 
30,218 
58,648 



70,343,302 

37,046,363 

7,793,226 

22,490,017 
13,477,603 
3,631,620 

47,853,285 
23,568,760 
4,161,606 



12,768,168 

5,428,713 

642,884 



204,046 
186,951 
239,676 



39,399 
33,534 
79,600 



78,677,699 

42,766,420 

8,457,909 

25,505,853 
15,241,685 
3,890,571 

53,171,846 
27,524,735 
4,567,338 



14,895,573 

6,470,072 

711,119 



184,387 
178,273 
264,023 



44,053 
35,081 
84,131 



80.1 
47.2 



77.3 
72.6 
39.7 

70.3 
84.5 
54.4 



102.8 
121.6 
47.6 



22.2 
25.8 
44.6 



14.1 
16.1 
43.4 



11.8 
15.4 



13.4 
13.1 



11.1 
16.8 
9.7 



16.7 
19.2 
10.6 



-9.6 
-4.6 
10.2 



11.8 
4.6 
5.7 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 6.— Synthetic organic chemicals: Summary of U.S. production and sales of intermediates and finished 
products, average 1957-59, annual 1963 and 1964 --Continued 

[Production and sales in thousands of pounds; sales value in thousands of dollars] 



^. Medicinal Chemicals 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic : 

Production 

Sales 

Sales value 

5. Flavor and Perfume Maten 

Cyclic : 

Production 

Sales 

Sales value 

Acyclic : 

Production 

Sales 

Sales value 

6. Plastics and Resin Mater 

Cyclic : 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 

7. Rubber -Processing Chemic 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic : 

Production 

Sales 

Sales value 



(Synthetic Rubbers) 



Cyclic: 

Production-- 

Sales 

Sales value- 
Acyclic : 

Production — 

Sales 

Sales value- 



Cyclic: 

Production — 

Sales 

Sales value - 

Acyclic: 

Production — 

Sales 

Sales value- 



Average 
1957-59 



70,654 

54,151 

535,297 

31,592 
28,738 
35,660 



27,312 
22,446 
33,903 

19,033 
19,958 
21,912 



2,278,862 

1,900,032 

518,501 

2,628,779 

2,438,853 

864,523 



159,182 
115,704 
74,479 

29,150 
22,127 
14,289 



1,938,732 

1,726,757 

404,897 

521,811 
509,262 
199,627 



348,210 

297,423 

83,509 

118,118 
100, 984 
38,772 



94,125 
73,606 
605,080 

45,071 
40,314 
33,875 



41,338 
34,671 
51,446 

32,430 
32,343 
25,940 



3,489,361 

2,886,387 

736,760 

5,479,112 
4,629,750 
1,266,359 



199,282 
152,835 
101,757 

34,350 
24,367 
16,906 



2,174,183 

1,925,751 

434,474 

1,010,731 
910,544 
332,457 



621,687 
557,979 
103,000 

212,837 
191,771 
65,181 



97,579 

76,946 

612,233 

46,511 
41,732 
33,459 



49,563 
41,235 
56,571 

41,007 
38,802 
27, 163 



3,915,046 

3,256,105 

777,342 

6,188,018 
5,470,616 
1,342,942 



222,461 
161,660 
108,656 

38,095 
22,567 
14,371 



2,332,436 

1,961,181 

450,913 

1,088,782 
996,403 
358,989 



717,624 
689,647 
119,565 

233,784 

215,240 

67,903 



Increase, or decrease (-) 



1964 over 
1957-59 



81.5 
83.7 
66.9 

115.4 
94.4 



71.8 
71.4 
49.9 

135.4 
125.3 



39.8 
39.7 



20.3 
13.6 
11.4 

108.6 
95.6 
79.8 



31.9 
43.2 

97.9 
113.1 
75.1 



GENERAL 



TABLE 6. Synthetic organic chemicals : Summary of U.S. production and sales of intermediates and finished 

products, average 1957-59, annual 1963 and 1964 --Continued 

[Production and sales in thousands of pounds; sales value in thousands of dollars] 



Average 
1957-59 



Increase, or decrease (-) 



1964. over 
1957-59 



1964 over 
1963 



10. Surface-Active Agent! 

Cyclic : 

Production 

Sales 

Sales value 

Acyclic : 

Production 

Sales 

Sales value 

11. Pesticides and Other 
Organic Agricultural Chemicc 
Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 

11. Miscellaneous Chemicals 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 



852,314 
800,432 
127,936 

502,715 
432,135 
113,215 



440,384 
375,627 
150,837 

105,080 
91,938 
49,049 



733,401 
445,252 
132,660 

27,260,924 

11,271,780 

1,621,617 



1,308,791 

1,222,238 

159,963 

671, 867 
567,445 
165,011 



597,072 
498,082 
286,045 

166,405 
153,389 
83,095 



952,565 
476,856 
190, 935 

40,200,482 
17,018,837 
2,172,782 



1,347,809 

1,245,176 

165,132 

770, 879 
654,754 
185,010 



584,698 
522,691 
316,556 

198,051 
169,664 
110,555 



1,114,624 
603,618 
224,330 

44,566,719 
19,914,957 
2,426,946 



51.5 
63.4 



32.8 
39.2 
109.9 



84.5 
125.4 



3.0 
1.9 
3.2 



4.9 
10.7 



19.0 
10.6 



10.9 
17.0 
11.7 



The following tabulation shows, by chemical groups, the number of companies that reported 
production in 1964 of one or more of the chemicals included in the groups listed in table 6: 



number 
Chemical group of 

companies 

Intermediates 203 

Dyes . 51 

Synthetic organic pigments 39 

Medicinal chemicals 114 

Flavor and perfume materials 53 

Plastics and resin materials 337 



Numbe r 
Chemical group of 

companies 
Rubber-processing chemicals 33 

Elastomers (synthetic rubbers) . 30 

Plasticlzers 61 

Surface-active agents 182 

Pesticides and other organic agricultural chemicals 86 

Miscellaneous chemicals 325 



10 



SYNTHETIC ORGANIC CHEMICALS, 1964 



Cyclic Intermediates 

Cyclic intermediates are synthetic organic chemicals derived principally from coal-tar 
crudes produced by destructive distillation (pyrolysis) of coal and from petroleum and natural 
gas. Most cyclic intermediates are used in the manufacture of more advanced synthetic organic 
chennicals and finished products, such as dyes, medicinal chemicals, elastomers (synthetic 
rubbers), pesticides, and plastics and resin materials. Some intermediates, however, are sold 
as end products without further processing. For example, refined naphthalene may be used as a 
raw material in the manufacture of 2-naphthol or of other more advanced intermediates, or it 
may be packaged and sold as a moth repellent or as a deodorant. In general, the way in which 
the greater part of the output of a given chemical is consumed determiines its use classification 
in this report. Table TA"*" gives statistics on production and sales of cyclic intermediates in 
1964. Individual statistics given in the table represent more than 85 percent of the total quantity 
of intermediates produced. Since many of the intermediates included in the statistics represent 
successive steps in production, the totals necessarily include considerable duplication. In 1964 
about two-fifths of the total output of cyclic intermediates ^vas sold; the rest was consumed 
chiefly by the producing plants in the manufacture of more advanced intermediates and finished 
products. 

Total production of cyclic intermediates in 1964--14, 896 million pounds--was the largest 
on record, and was 16.7 percent larger than the output of 12, 768 million pounds reported for 
1963. The larger output of cyclic intermediates in 1964 was attributable to increased demand by 
a number of industries that consume large quantities of intermediates, particularly those indus- 
tries that produce dyes, plastics and resin materials, and plasticizers. Sales of cyclic interme- 
diates in 1964 amounted to 6,470 million pounds, valued at $711 million, compared with 5,429 
million pounds, valued at $643 million, in 1963. In terms of quantity, sales of cyclic interme- 
diates in 1964 were 19.2 percent larger than those in 1963 and in terms of value, 10. 6 percent 
larger. 

TABLE 7A. — Cyclic intermediates : U.S. production and sales, 1964 

[Listed telow are all cyclic intermediates for which any reported data on production or sales may be published. 

( Leaders are used where the reported data are accepted in confidence and may not be published or where no data were 
reported.) Table 7B in pt. Ill lists alphabetically all cyclic Intermediates for which data on production or sales 
were reported and identifies the manufacturer of each] 



Production 



Quantity 



Unit 
value""" 



Total 

Acetanilide, tech 

4-'-Aminoacetanilide ( Acetyl -p-phenylenediamlne) 

5-Amlno-2-(p-aminoanillno)benzenesulfonlc acid 

2-(p-Amlnoanilino) -5-nitrobenzenesulf onic acid 

1-Aminoanthraquinone and salt 

2 -Aminoanthraquinone and salt 

S-Amino-SjV -azodi(benzenesulfonic acid) 

1-Amino-A-benzamidoanthraquinone 

l-Amino-5-benzamidoanthraquinone 

6-(p-Aminobenzamldo) -l-naphthol-3 -sulfonic acid 

2-Amlno-p-benzenedlsulfonic acid [ S03H=1] 

l-Amino-4-bromo-2-anthraquinonesulfonio acid and sodium salt- 

l-Amino-2-bromo-4--hydroxyanthraquinone 

l-Amino-5-chloroanthraqulnone 

2-Amlno-3-chloroanthraquinone 

o-( 3 -Amino -4 -chlorobenzoyl) benzoic acid 

6-Amlno-4—chloro-l-phenol-2 -sulfonic acid 

6-Amino-4— chloro-m-toluenesulfonlo acid [S03H=l] 

See footnotes at end of table. 



1,000 

pounds 

l^i, 895,573 



1,000 

pounds 

6,470,072 



1,000 
dollars 
711,119 



Per 
pound 



3,905 

'i75 

15 

33 

1,152 

965 

60 

75 

104 

38 

21 

253 

113 

86 

48 

106 



1,305 
164 



341 
255 



.26 

1.55 



See also table 7B, pt. Ill, which lists these products alphabetically and identifies the manufacturers, and appendix A, wlucn snows imports 
of intermediates and related products during 1963 and 1964. 



CYCLIC INTERMEDIATES 



TABLE lA.— Cyclic intermediates.- U.S. production and sales , 2564— Continued 



Production 



Quantity 



Unit 
value-'- 



2-Amno-5-ohloro-p-toluenesulfQnio acid [S03H=1] 

l-Amino-2,'i-dibromoanthraquinone 

4.'-Amino-N-methylacetanilide 

2-Ajiiino-l,5-naphthalenedisulfoniG acid 

3-Ajnino-l,5-naphthalenedisulfonic acid (Cassella acid) 

6-Ainino-l,3-naphthalenedisulfonio acid (Amino I acid) 

2-Aiiiino-l-naphthalenesulfonic acid (Tobias acid) 

5-Amino-2-naphthalenesuli'onic acid (1,6-Cleve's acid) 

5(and 8) -Ainino-2-naphthalenesulfonio acid (Cleve's acid, mixed)-- 

6-Amino-2-naphthalenesuli'onic acid (Broenner's acid) 

8-Ajiiino-l-naphthalenesulfonic acid (Peri acid) 

8-Amino-2-naphthalenesulfonic acid (l,7-Cleve's acid) 

8-Amino-2-naphthol 

8-Amino-l-naphthol-3,6-disulfonio acid (H acid), monosodium salt- 

l-Amino-2-naphthol-<4-sulfonic acid (1,2,'i-acid) 

6-Amino-l-naphthol-3-sulfonic acid (J acid), sodium salt 

7-Amino-l-naphthol-3-sulfonic acid (Gamma acid), sodium salt 

2-Amino-5-nitrobenzenesulfonic acid rS03H=l] 

2 -Aminos -nitrophenol 

2 -Amino-l-phenol-4 -sulfonamide 

2 -Amino-1-phenol-^ -sulfonic acid 

p-(p-Aminophenylazo)ben2,enesulfonlc acid 

4-Amino-m-toluenesulfom.o acid [S03H=1] 

5-Amino-m-tQluenesulfonic acid rS03H=l] 

16-Aminoviolanthrone 

2-Amlno-3,5-xylenesulfonic acid [S03H=1] 

Aniline (Aniline oil) 

Anilinomethanesulfonio acid and salt 

8-Anilino-l-naphthalenesulfonic acid (Phenyl peri acid) 

6-Anilino-l-naphthol-3-sulfonic acid (Phenyl J acid) 

o-Anisidine 

o-Anisidinomethanesulfonic acid 

Anthra[l,9]pyrazol-6(2H)-one (Pyrazoleant'hrone) 

Anthraquinone , 100^ 

1,5-Anthraquinonedisulfonic acid 

IjS-Anthraquinonedisulfonic acid, potassium salt 

2,6-Anthraquinonedisulfonic acid and salt 

1-Anthraquinonesulfonic acid and salt 

Anthraruf in (l,5-Dihydroxyanthraquinone) 

Benzaldehyde, tech 

l-Benzamido-5-chloroanthraqulnone 

7H-Benz[de ]anthracen-7-one^ (Benzanthrone) 

Benzidine hydrochloride and sulfate 

Benzoic acid, tech 

o-Benzoylbenzoic acid 

3,3'-Bianthra[l,9]pyrazole-6,6'-(2H,2'H)dione ( Pyrazoleanthrone 

yellow) 

[■4j4'-Bi-7H-benz[de]anthracen]-7,7'-dione 

[ ljl'-Binaphthalene]-8,8'-dicarboxylic acid 

l,4-Bis[l-anthraquinonylamino] anthraquinone 7- 

"+,4' -Bis [dimethylaminojbenzophenone (Michler's ketone) 

3-Bromo-7H-benz[de] anthracen-7-one ( Bromobenzanthrone ) 

o-sec-Butylphenol 

Camphoric acid 

1-Chloroanthraquinone 

2-Chloroanthraquinone 

Chlorobenzene , mono- 

o-(p-Chlorobenzoyl)benzoic acid 

l-Chloro-2,<4-dinitrobenzene (Dinitroohlorobenzene) 

6-Chlorometanilic acid 

l-Chloro-2-methylanthraquinone 

2-Chloro-4.-nitroaniline (o-Chloro-p-nitroaniline) 

l-Chloro-5-nitro anthraquinone 

l-Chloro-8-nitro anthraquinone 

l-Chloro-2-nitrobenzene (Chloro-o -nitrobenzene) 

l-Chloro-3 -nitrobenzene (Chloro-m-nitrobenzene) 

l-Chloro-4 -nitrobenzene (Chloro-p-nitrobenzene) 

See footnotes at end of table. 



1,000 

pounds 

1,334 

245 

14 

85 

241 

1,168 

4,506 

149 

303 

90 

476 

224 

59 

3,506 

1,151 

596 

578 

36 

98 

62 

100 

205 

223 

280 

21 

69 

169,909 

242 

364 

66 

1,672 

372 

30 

2,760 

261 

312 

271 

2,691 

255 

3,338 

109 

1,987 

1,369 

15,864 

5,786 

19 



145 

1,093 

10 

197 

1,010 

537,500 

1,633 

8,193 

24 

215 

301 

103 

46 

20,088 

8,063 

86,902 



i.ono 

founds 



1,000 
dollars 



pound 



3,615 

64 

893 

7,998 



1,452 

109 

906 

1,392 



1.70 
1.01 



,238 
252 



.89 
.07 



SYNTHETIC ORGANIC CHEMICALS, 1964 
TABLE 7A.-- Cyclic intermediates: U.S. production and sales , i564— Continued 



Qaantity Value 



Unit 
value "^ 



4-Chloro-3-nltrobenzenesulfonaiiilde 

"i-Chloro-S-nitrobenzenesulfonyl chloride 

o-(4-Chloro-3-nitrobenzoyl) benzoic acid 

'4-Chloro-2-nitrotoluene 

a -Chlorotoluene (Benzyl chloride) 

5-Chloro-o-toluidine [NH2=l] and hydrochloride 

Cresols, total^ 

m-, 0-, and p-Cresols 

(m,p)-Cresol (from coal tar and petroleum) 

(o,m,p)-Cresol^ 

Cresylio acid, refined, total^ 

From coal tar 

From petroleum 

Cumene 

Cyclohexane 

Cyclohexanol 

Cyclohexanone 

l,<i-Diaminoanthraquinone 

1,5-Diaminoanthraquinone 

2,6-Diaminoanthraquinone 

■4,4' -Diamino-2,2' -biphenyldisulfonic acid 

■4,4' -Diamino-2, 2'-stilbenedisull"onic acid 

4,5' -Dibenzamido-1,1' -iminodianthraquinone 

1,5-Dibenzoylnaphthalene 

3,9-Dibromo-7H-benz[de ]anthraoen-7-one 

2,5-Dichloroaniline and hydrochloride [NH2=l] 

1,8-Dichloroanthraquinone 

o-Dichlorobenzene 

o(and p) -Dichlorobenzene 

p-Dichlorobenzene 

3,3'-Dichlorobenzidine base and salts 

2,5 -Dichloro^ -( 3 -methyl-5 -oxo-2 -pyrazolin-l-yl) benzenesulf onic acid 

2,6-Dichloro-4-nitroaniline 

l,4-Dichloro-2 -nitrobenzene (Nitro-p-diohlorobenzene) 

2,5-Dichlorosulfanilio acid [S03H=l] 

p-Diethylaminobenz aldehyde 

N,N-Diethylanlline 

l,5-Dihydroxy-4,8-dinitroanthraquinone 

l,8-Dihydroxy-4,5-dinitroanthraquinone (4,5-Dinitroohrysazin) 

16,17-Dihydroxyviolanthrone (Dihydroxydibenzanthrone) 

3 j3^ -Dimethoxybenzidine 

N,N-Dimethylaniline 

N,N-Dime thy Ibenzy lamina 

2, 2 '-Dime thy 1-1,1' -bianthraquinone 

N,N-Dime thy 1-p-nitrosoani line 

p-( 2, 4-Dinitroanilino) phenol 

2,4-Dinitrophenol, tech 

4,4'-Dinitro-2,2'-stilbenedisulfonio acid 

Dlphenylacetic acid 

l,4-Di(p-toluidino)anthraquinone 

Dodecylbenzene* 

Dodecylphenol 

N-Ethylaniline, refined 

Ethylbenzene 

N-Ethyl-N-phenylbenzylamine 

2-Ethyl-2-phenylraalonic acid, diethyl ester 

3-(N-Ethyl-m-toluidino)propionitrlle 

o-Formylbenzenesulfonic acid (o-Sulf obenzaldehyde) 

p-Hydrazinobenzenesulf onic acid 

p-Hydroxybenzoic acid, methyl ester 

p-Hydroxybenzoic acid, propyl ester 

l,l'-Iminobis[4-aminoanthraquinone] 

l,l'-Iminobis[5-benzamidoanthraquinone] 

6,6'-Iminobis[l-naphthol-3-sulfonic acid] 



1.000 
pounds 
258 
235 
93 
396 
52,408 
657 

62,467 



1,000 
pounds 



8,471 
159 



26,147 
24,445 
11,875 



22,208 
41,482 



549,841 
1,367,142 



116 

4 

2,882 

129 

183 

224 

138 

77 

52,308 

12,997 

63,154 

2,345 

313 

225 

417 

102 

26 

1,480 

137 

186 

448 

776 

10,855 

78 

118 

89 

33 

1,037 

4,159 

7 

162 

413,972 

25,783 

409 

2,953,879 

493 

259 

61 

239 

153 

255 



1,064 



20 
200 



1,000 
dollars 



1,551 
218 



135 
247 
569 



679 
721 



865 
901 
895 



295 
184 



1.48 
2.30 



See footnotes at end of table. 



CYCLIC INTERMEDIATES 



TABLE 7A. — Cyclic intermediates: U.S. production and sales , 1964 — Continued 



Quantity 



Unit 
value ■*■ 



1, l'-Iininobis[4-nitroanthraquinone] 

1, I'-Iminodianthraquinone (Dianthrimide) 

Isooyanio acid derivatives, total 

Diphenylmethane -ij^'-diisocyanate (MDI) 

Toluene 2,4- and 2,6-diisocyanate (80/20 mixture) 

All other 

'i,'i'-Isopropylidenediphenol (Bisphenol A) 

Isoviolanthrone (Isodibenzanthrone) 

Leuco-l,<4-diamnoanthraquinone 

Leuco quinizarin ( 1,4,9, 10-Antliratetrol) 

Leuco tetrahydroxyanthraquinone 

Iifelamine 

o-kfercaptotenzoio acid 

1-lfethylaminoanthraquinone 

<i,'i'-Methylenebis[N,N-dlethylaniline] 

4,'i'-Methylenebls[N,N-dimethylaniline] (ifethane base) 

2-Iifethyl-l-nitroanthraquinone 

p-(3-Methyl-5-oxo-2-pyTazolln-l-yl)benzenesuli'onie acid 

3-Methyl-l -phenyl -2 -pyrazolin-5-one (Developer Z) 

ct-lfethylstyrene 

1,5-Naphthalenedisulfonic acid 

2,7-Naphthalenedisuli'onic acid 

1,4,5,8-Naphthalenetetraoarboxylic acid 

1-Naphthol (a-Naphthol) — 

2-Naphthol-3,6-disuironic acid, disodium salt 

2-Naphthol-6-sulfonic acid (Sehaeffer's acid) and sodium salt 

Naphth[l,2] oxadiazole-5-suLfonio acid 

2-(Naphthylthio) acetic acid 

p-Nitroaniline 

4-Nitro-o-anisidine [ NH2=1] 

5-Nitro-o-aiiisidine [nH2=1] 

l-Nitro-2-anthraquinoneoarboxylic acid 

5-Nitro-l-anthraquinonesulfonic acid 

5(and 8) -Nitro-l-anthraquinonesulfonic acid 

Nitrobenzene 

m-Nitrobenzenesulfonic acid and sodium salt 

m-Nitrobenzoio acid and sodlvim salt 

3-Nitro-l,5-naphthalenedisulfonio acid 

7(aiid 8) -Nitronaphth[ 1, 2] oxadiazole-5-sulfonic acid 

p-Nitrophenol 

5-Nitro-o-toluenesulfonic acid [ SO H=l] 

5-Nltro-o-toluidine [NH2=l] 

2-Nitro-p-toluidine [NH2=1] 

16 -Nitroviolanthrone 

Nonylphenol : 

l-(7-0xo-7H-benz[de]anthracen-3-ylaraino)anthraquinone 

1,1' -(7-0xo-7H-benz[de]anthracen-3,9-ylenedilmino)dianthraquinone- 
5-0xo-l-(p-suLfophenyl) -2-pyrazoline-3-carboxylic acid 

(Pyrazolone T) 

Phenol, grand total^ 

Natural, total 

From coal tar 

From petroleum 

Synthetic, total 

From cumene 

Other synthetic 

l-Phenol-4 -sulfonic acid 

Phenylacetic acid, potassium salt 

Phenylaoetonitrlle (a -Tolunitrile) 

p-Phenylazoaniline (p-Aminoazobenzene) and hydrochloride 

2, 2' - ( Phenylimino )diethanol ( Phenyldiethanolamine ) 

l(2H)-Phthalazlnone 

Phthalic anhydride 



1,000 
pounds 



137,960 



3,899 
113,627 
20,434 

92,948 
40 
332 



13 
227 

59 

1,340 

108 

125 

279 

14,112 

62 
111 



2,059 
366 



10,890 

73 

331 

37 

116 

25 

239,216 

3,090 

255 

207 

758 

18,935 

6,680 

358 

941 

69 

60,585 

181 

447 



1,113,056 



50,287 

35,639 

14,648 

1,062,769 

443,872 

618,897 

6,646 

1,414 

1,740 

133 

545 

135 

557,517 



1,000 
pounds 



1,000 
dollars 



2,600 

107,265 

16,654 

41,146 



25,246 



54 

38 

15 

439 

199 

239 



135 
283,736 



902 
676 
621 



66 
355 



579 

716 



699 
2,271 



47,735 



5,054 

3,470 

1,584 

42,681 

18,149 

24,532 

966 
526 
369 



659 
27,605 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE tA. --Cyclic intermediates: U.S. production and sales , 1964--Contirme(i 



Production 



Quantity 



Unit 
value '■ 



2-Piooline (a-Pieoline) ^ 

Piperidine 

Propiophenone 

Pyranthrone 

2° Pyridine' 

CJuinaldine 

Quinizarin 

2-Quinizarinsulfonie acid 

Salicylaldehyde 

Salicylic acid, tech 

Styrene, all grades 

Terephthalic acid, dimethyl ester 

Ij'ijSjS-Tetrachloroanthraquinone 

o(and p) -Toluenesulf onic acid 

o-(p-Toluoyl) benzoic acid 

i-Co-Tolylazo) -o-toluidine 

l,3,3-Trimethyl-A^»"-indolineacetaldehyde 

l,3,3-Trimethyl-2-methyleneindoline 

6,6'-Ureylenebis[ l-naphthol-3-sulfonic acid] (j acid urea) 

Violanthrone (Dibenzanthrone) 

o-Xylene 

p-Xylene 

Xylenols, medium b.p 

All other cyclic intermediates 



1.000 
pounds 

3,297 

^01 

587 

20 

5,503 

33 

1,411 

2,156 

20,769 

,571,395 

355,587 

34 

4,348 

318 

443 

89 

185 

258 

436 

336,557 

295,730 

5,930 

,173,805 



1,000 

pounds 

1,042 
256 



74 

18 

2,055 

3,199 

1,368,179 



1,000 
dollars 



81 

39 

2,249 

1,095 

110,845 



4,306 



306,049 

313,019 

6,058 

1,165,579 



8,087 

26,978 

656 

244,919 



pound 



$0.36 
1.18 



.21 



■'■ Calculated from rounded figures. 

^ Includes data for coke ovens and gas-retort ovens, reported to the Division of Bituminous Coal, U.S. Bureau of 
Mines, Department of the Interior, and for tar and petroleum refineries and other producers, reported to the U.S. 
Tariff Commission. 

■^ Includes some mixed cresols. Figures include (o,m,p)-cresol from coal tar and from petroleum. 

* Includes branched- and straight-chain dodeoylbenzene and tridecylbenzene. 

' Includes data for coke ovens and gas-retort ovens, reported to the Division of Bituminous Coal, U.S. Bureau of 
Mines, Department of the Interior, and for tar refineries and other producers, reported to the U.S. Tariff Commission. 



In 1964, production of two intermediates amounted to over 2 billion pounds each. The output 
of ethylbehzene totaled 2, 954 million pounds (20. 5 percent more than in 1963) and that of styrene, 
2, 571 million pounds (19.4 percent more than in 1963). Ethylbenzene is used almost entirely in 
the manufacture of styrene, which, in turn, is used almost entirely in the manufacture of plas- 
tics materials and synthetic rubber. The output of other large-volume intermediates in 1964 
compared with production in 1963 was as follows: Cyclohexane, 26. 7 percent larger; phenol, 
18.9 percent larger; and phthalic anhydride, 21.6 percent larger. Production of cumene and 
monochlorobenzene was larger by 26. 9 percent and 3. 6 percent, respectively, in 1964 than in 
1963. Production of dodeoylbenzene (including tridecylbenzene) in 1964 was 15. 5 percent 
smaller than that in 1963. The output of terephthalic acid, dim:ethyl ester amounted to 356 
million pounds in 1964, representing an increase of 7.4 percent over the 331 million pounds pro- 
duced in 1963. Production of orthoxylene amounted to 337 million pounds in 1964, compared 
with 304 million pounds in 1963--representing an increase of 10. 8 percent. 

Dyes 

Dyes produced in the United States are all derived in whole or in part from cyclic interme- 
diates. About three-fourths of the dyes consumed in the United States are used by the textile 
industry to dye natural and synthetic fibers or fabrics; the rest are used chiefly by the industries 
that produce organic pignnents, paper, and leather. Of the several thousand different synthetic 
dyes that are known, more than two thousand are manufactured by one or more domestic pro- 
ducers. The large number of dyes results from the many different types of materials to which 
dyes are applied, the different conditions of service for which dyes are required, and the costs 
that a particular use can bear. Dyes are sold as pastes, powders, lumps, and solutions; concen- 
trations vary from 6 percent to 100 percent. The concentration, form, and purity of a dye are 
determined largely by the use for which it is intended. 



DYES 



15 



Table 8A^ shows U.S. production and sales of dyes in 1964, total and by individual dyes, 
using the Colour Index classification and terminology (which was used for the first time in the 
Commission's 1958 report). 

Total domestic production of dyes in 1964 amounted to 184 million pounds, while sales 
amounted to 178 million pounds, valued at $264 million. The value of dyes sold in 1964 was 10 
percent larger than that in 1963. Statistics on the quantity of dyes produced and sold in 1964 are 
not comparable with those for 1963 because of a change in the method of reporting sulfur dyes. 
Data on production and sales of two forms of sulfur dyes, the solubilized and leuco forms, were 
reported in commercial concentrations in 1963; these same dyes were reported on a more con- 
centrated active ingredient basis in 1964. 

For many important individual low- and medium-priced dyes, for which statistics are given 
in table 8A, production was larger in 1964 than in 1963. The output of Direct Black 38 was 6. 3 
million pounds in 1964, or 5.0 percent more than the 6.0 million pounds produced in 1963; that 
of Vat Green 1 was 5. 9 million pounds, or 19. V percent more than the 4. 9 million pounds pro- 
duced in 1963. Other important dyes whose output was substantially larger in 1964 than in 1963 
were Disperse Black 9 (53.8 percent). Disperse Yellow 3 (41.4 percent). Direct Blue 86 (22.5 
percent), and Vat Blue 6 (10. 6 percent). 

TABLE 8A. — Benzenoid dyes: U.S. production and sales, 1964 



[Listed below are all benzenoid dyes for which any reported data on production or sales may be published. (Leaders 
are used where the reported data are accepted in confidence and may not be published or where no data were 
reported.) Table 8B in pt. Ill lists all dyes for which data on production or sales were reported and identifies 
the manufacturer of each] 



Dye 



Quantity 



Unit 
value''" 



Grand total 

ACID DYES 

Total 

Acid yellow dyes, total 

Acid Yellow 3 

Acid Yellow 11 

Acid Yellow 17 

Acid Yellow 23 

Acid Yellow 36 

Acid Yellow 40 

Acid Yellow 4-2 

Acid Yellow 44 

Acid Yellow 54 

Acid Yellow 73 

Acid Yellow 99 

All other 

Acid orange dyes, total 

Acid Orange 1 

Acid Orange 7 

Acid Orange 8 

Acid Orange 10 

Acid Orange 24 

Acid Orange 60 

Acid Orange 74 

All other 

Acid red dyes, total 

Acid Red 1 

Acid Red 4 



1,000 
pounds 

184,387 



17,794 



2,766 



482 
385 
196 



219 

83 

1,151 

2,687 



38 
763 
354 
319 
479 



456 
143 



1,000 
pounds 

178,273 



17,090 



2,481 



28 

53 

445 

280 

212 

82 

35 

22 

57 

59 

82 

1,126 

2,511 



684 
306 
319 
457 
32 



2,600 



496 
147 



1,000 
dollars 

264,023 



35,812 



5,556 



84 

109 

972 

592 

315 

223 

62 

71 

123 

136 

185 

2,684 

3,735 



121 
600 
355 
409 
610 
83 
100 
1,457 

5,281 



557 
266 



pound 



$1.48 



2.10 



2.24 
3.00 
2.06 
2.18 
2.11 
1.49 
2.72 
1.77 
3.23 
2.16 
2.31 
2.26 
2.38 

1.49 
3.10 



1.16 
1.28 
1.33 
2.59 
2.22 
2.32 

2.03 



See footnotes at end of table. 



"^ See also table 8B, pt. Ill, which lists these products and identifies the manufacturers, and appendix A (table 23), which shows imports of 
dyes during the years 1963-64. 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE QA.-- Benzenoid dyes: U.S. production and sales , 1964 — Continued 



E)ye 



Production 



aantlty Value 



ACID DY£S--Continued 

Acid red dyes--Continued 

Acid Red lA 

Acid Red 18 

Acid Red 26 

Acid Red 37 

Acid Red 73 

Acid Red 85 

Acid Red 87 

Acid Red 88 

Acid Red 89 

Acid Red 99 

Acid Red 115 

Acid Red 137- 

Acid Red 151 

Acid Red 182 

Acid Red 186 

All other 

Acid violet dyes, total 

Acid Violet 1 

Acid Violet 3 

Acid Violet 7 

Acid Violet 12 

Acid Violet 17 

Acid Violet 43 

All other 

Acid blue dyes, total 

Acid Blue 7 

Acid Blue 9 

Acid Blue 25 

Acid Blue 40 

Acid Blue 41 

Acid Blue 43 

Acid Blue 45 

Acid Blue 78 

Acid Blue 113 - 

Acid Blue 158 and 158A 

All other 

Acid green dyes, total 

Acid Green 3 

Acid Green 9 

Acid Green 12 

Acid Green 16 

Acid Green 20 

Acid Green 22 

Acid Green 25 

All other 

Acid brown dyes, total 

Acid Brown 14 

All other 

Acid black dyes, total 

Acid Black 1 

Acid Black 24 

Acid Black 48 

Acid Black 52 

Acid Black 107 

All other 



1,000 
pounds 



188 
150 
465 
163 

29 
135 

20 
119 



104 
101 



3,369 



566 
99 



1,492 



157 
289 



274 
410 



4,104 



1,381 

92 

33 

438 

84 

2,076 



1,000 

pounds 



1,000 
dollars 



82 
120 

49 

57 
190 
163 

83 
136 

39 

18 
128 
55 
33 



3,234 



82 
474 
110 



347 

210 

1,243 



169 
18 
13 

113 
32 
64 

177 

186 



261 
439 



1,499 
128 
27 



2,661 



118 
137 

57 
155 
427 
276 
161 
194 

66 

29 
405 
119 
101 

53 
2,160 

745 



144 
115 

30 
148 

20 
220 



228 
586 
593 
64 
260 
172 

1,918 
338 
482 
479 

4,770 

2,210 



196 
79 



135 
649 
598 



373 
1,258 



1,723 
228 
148 

246 
4,419 



See footnotes at end of table. 



DYES 



TABLE 8A. —Benzenoid dyes : U.S. production and sales , i56-^— Continued 



Oye 



Quantity Value 



AZOIC DYES AND COMPONENTS 

Azoic Conipositions 

Total 

Azoic Yellow 1 

Azoic Yellow 2 

Azoic Orange 3 

Azoic red dyes, total 

Azoic Red 1 

Azoic Red 2 

Azoic Red 6 

Azoic Red 16 

All other 

Azoic Blue 2 

Azoic Blue 3 

Azoic Brown 9 

Azoic black dyes 

All other azoic compositions 

Azoic Diazo Components, Bases 
(Fast Color Bases) 

Total 

Azoic Diazo Component 4, base 

Azoic Diazo Component 9, base 

Azoic Diazo Component 12, base 

Azoic Diazo Component 32, base 

Azoic Diazo Component A-8, base 

All other azoic diazo components, bases 

Azoic Diazo Components, Salts 
(Fast Color Salts) 

Total 

Azoic Diazo Component 1, salt 

Azoic Diazo Component 3, salt 

Azoic Diazo Component 5, salt 

Azoic Diazo Component 6, salt 

Azoic Diazo Component 8, salt 

Azoic Diazo Component 9, salt 

Azoic Diazo Component 10, salt 

Azoic Diazo Component 11, salt 

Azoic Diazo Component 12, salt 

Azoic Diazo Component 13, salt 

Azoic Diazo Component 28, salt 

Azoic Diazo Component 32, salt 

Azoic Diazo Component 36, salt 

Azoic Diazo Component 48, salt 

Azoic Diazo Component 49, salt 

All other azoic diazo components, salts 

Azoic Coupling Components 
(Naphthol AS and Derivatives) 

Total 

Azoic Coupling Component, 2 

Azoic Coupling Component 3 



1.000 
pounds 
2,041 



187 
78 

302 

7 

85 



155 
685 
277 



1,391 



31 



267 
266 



2,137 



3,218 



1,000 
pounds 
1,707 



1,000 
dollars 



44 



172 
9 

71 

9 

83 

114 

677 

287 



1,272 



33 
52 
266 
258 
35 
628 



1,973 



2,447 



3,441 



73 
83 
849 



261 
110 
291 
24 
163 

17 

141 

363 

1,304 

611 



1,984 



42 

43 

350 

419 

61 

1,069 



2,028 



14 


13 


19 


290 


266 


179 


105 


111 


136 


15 


16 


17 


44 


49 


49 


222 


235 


153 


20 


13 


20 


38 


36 


60 


129 


139 


151 


419 


414 


290 


180 


181 


210 


201 


57 


63 




73 


132 


36 


36 


39 


31 


34 


101 


393 


300 


409 



4,696 



227 
18 



197 
17 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 8A.-- Benzenoid dyes.- U.S. production and sales, i 564 --Continued 



Dye 



Quantity Value 



AZOIC DYES AND COMPONENTS— Continued 

Azoic Coupling Component s 
(Naphthol AS and Derivatives) -ContxxwieA 

Azoic Coupling Component 4 

Azoic Coupling Component 7 

Azoic Coupling Component 1<+ 

Azoic Coupling Component 17 

Azoic Coupling Component 18 

Azoic Coupling Component 19 

Azoic Coupling Component 20 

Azoic Coupling Component 21 

Azoic Coupling Component 29 

All other azoic coupling components 

BASIC DYES 

Total 

Basic Yellow 2 

Basic Yellow 11 

Basic Yellow 13 

Basic orange dyes, total 

Basic Orange 1 

Basic Orange 2 

Basic Orange 21 

All other 

Basic red dyes, total 

Basic Red 2 

Basic Red K 

All other 

Basic violet dyes, total 

Basic Violet 1 

Basic Violet 3 

Basic Violet 4- 

Basic Violet 14- 

Basic Violet 16 

All other 

Basic blue dyes, total 

Basic Blue 1 

Basic Blue 7 

Basic Blue 9 

Basic Blue 26 

All other 

Basic Green 1 

Basic Green 4 

Basic Brown 1 

Basic Brown 4 

All other basic dyes 

DIRECT DYES 

Total 

Direct yellow dyes, total 

Direct Yellow 4 

Direct Yellow 5 

Direct Yellow 6 

Direct Yellow 11 • 



1,000 
pounds 



1,041 
148 
203 

744 

106 
79 
28 

624 



9,154 



714 

332 

56 

1,330 



294 
581 
367 



176 
317 
546 

2,650 



914 
1,056 
42 
116 
104 
418 

1,201 



123 
403 



90 
489 
240 
605 
408 



31,490 



5,752 



414 
145 
783 
871 



7 
775 
103 
160 
658 
14 



8,553 



768 
337 
49 

1,141 



276 

482 

304 

79 



166 
313 
454 

2,605 



865 
1,120 
44 
81 
98 

397 



18 
106 
307 



85 
509 
219 
609 
314 



31,939 



5,548 



410 
123 
737 



15 

1,415 

219 

313 

782 

67 
176 
139 

53 
1,261 



20,878 



1,570 

1,353 

172 

2,116 



297 
580 
955 
284 



477 

941 

1,731 

5,277 



1,112 

2,034 

125 

290 

353 

1,363 

3,292 



82 

354 

716 

188 

1,952 

273 

1,334 

317 

808 

1,217 



46,807 



10,021 



866 

351 

1,202 

981 



See footnotes at end of table. 



DYES 



19 



TABLE 8A. — Benzenoid dyes : U.S. production and sales, 1964—Contm\ied 



Dye 



DIRECT DYES- -Continued 

Direct yellow dyes — Continued 

Direct Yellow 12 

Direct Yellow 26 

Direct Yellow 28 

Direct Yellow 29 

Direct Yellow 44 

Direct Yellow 50 

Direct Yellow 59 

Direct Yellow 84 

All other 

Direct orange dyes, total 

Direct Orange 1 

Direct Orange 8 

Direct Orange 15 

Direct Orange 26 

Direct Orange 34 

Direct Orange 37 

Direct Orange 39 

Direct Orange 72 

Direct Orange 73 

Direct Orange 81 

Direct Orange 102 

All other 

Direct red dyes, total 

Direct Red 1 

Direct Red 2 

Direct Red 4 

Direct Red 10 

Direct Red 13 

Direct Red 16 

Direct Red 23 

Direct Red 24 

Direct Red 26 

Direct Red 28 

Direct Red 31 

Direct Red 37 

Direct Red 39 

Direct Red 75 

Direct Red 79 

Direct Red 80 

Direct fled 81 

Direct Red 83 

Direct Red 149 

Direct Red 152 

All other 

Direct violet dyes, total 

Direct Violet 1 

Direct Violet 9 

Direct Violet 48 

All other 

Direct blue dyes, total 

Direct Blue 1 

Direct Blue 2 

Direct Blue 6 

Direct Blue 8 

Direct Blue 14 

Direct Blue 15 

Direct Blue 22 

Direct Blue 24 







Sales 




Production 


Quantity 


Value 


Unit 
value^ 




1,000 
pounds 

368 

8 

262 

122 

401 

331 

45 

172 

1,830 

1,726 


1,000 
pounds 

292 

6 

279 

98 

378 

349 

50 

211 

1,807 

1,834 


1,000 
dollars 

700 

17 

551 

148 

646 

664 

75 

309 

3,511 

4,002 


Per 
pound 

$2.40 
2.83 






1.97 




1.51 




1.71 




1.90 




1.50 




1.46 




1.94 




2.18 




21 
143 
129 
47 
97 
56 
98 
248 
19 
49 
164 
655 

3,291 


14 

135 

161 

62 

97 

60 

100 

285 

31 

36 

166 

687 

3,400 


33 
204 
201 
127 
233 
145 
208 
598 
126 
110 
446 
1,571 

7,220 


2.36 




1.51 




1.25 




2.05 




2.40 




2.42 




2.08 




2.10 




4.06 




3.06 




2.69 




2.29 




2.12 




175 

381 

30 

18 

69 

34 

265 

326 

130 

200 

36 

58 

61 

37 

197 

427 

291 

128 

14 

414 

253 


167 

402 

31 

19 

84 

56 

297 

346 

113 

177 

31 

67 

65 

33 

201 

444 

293 

105 

13 

5 

451 

194 


261 

709 

85 

32 

138 

104 

656 

640 

295 

235 

126 

172 

189 

111 

482 

812 

751 

165 

44 

25 

1,188 

570 


1.56 




1.76 




2.74 




1.68 




1.64 




1.86 




2.21 




1.85 




2.61 




1.33 




4.06 




2.57 




2.91 




3.36 




2.40 




1.83 




2.56 




1.57 




3.38 




5.00 




2.63 




2.94 




16 
174 
34 
29 

7,049 


15 
118 
30 

31 

7,186 


33 
282 
118 
137 

10,076 


2.20 




2.39 




3.93 




4.42 




1.40 




417 

1,828 

522 

55 

96 

41 


404 
1,977 

523 
55 

123 
48 
20 
44- 


710 
1,659 
271 
103 
104 
79 
34 
57 


1 76 




.84 




.52 




1.87 




.85 




1.65 




1.70 




1.30 



See footnotes at end of table. 



20 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 8A. — Benzenoid dyes : U.S. production and sales, 1964 — Continued 



Efire 



Production 



Quantity 



DIRECT DYES— Continued 

Direct blue dyes — Continued 

Direct Blue 25 

Direct Blue 26 

Direct Blue 67 

Direct Blue 71 

Direct Blue 76 

Direct Blue 78 

Direct Blue 80 

Direct Blue 86 

Direct Blue 98 

Direct Blue 120 and 120A 

Direct Blue 126 

Direct Blue 151 

All other 

Direct green dyes, total 

Direct Green 1 

Direct Green 6 

Direct Green 8 

Direct Green 12 

Direct Green 38 

All other 

Direct brown dyes, total 

Direct Brown 1 and lA 

Direct Brown 2 

Direct Brown 6 

Direct Brown 31 

Direct Brown 74 

Direct Brown 95 

Direct Brown 111 

Direct Brown IS^- 

All other 

Direct black dyes, total 

Direct Black A 

Direct Black 9 

Direct Black 19 

Direct Black 22 

Direct Black 37 

Direct Black 38 

Direct Black 51 

Direct Black 80 

All other 

DISPERSE DYES 

Total 

Disperse yellow dyes, total ■ 

Disperse Yellow 1 

Disperse Yellow 3 

Disperse Yellow 5 

Disperse Yellow 23 

Disperse Yellow 33 

Disperse Yellow 37 

Disperse Yellow 54 

All other 

Disperse orange dyes, total 

Disperse Orange 3 

Disperse Orange 5 

Disperse Orange 17 

All other 

See footnotes at end of table. 



1,000 
pounds 



33 

62 
622 

83 

431 

1,186 

155 

91 
185 

1,171 

1,140 



230 
424 
48 



1,910 



378 
157 
97 
116 



184 
230 



10,369 



271 

52 

224 

690 

6,338 
118 

1,883 
793 



13,132 



2,126 
23 



234 
103 
207 
557 



1.000 
pounds 



1.000 
dollars 



606 
107 
448 

1,182 
1A7 
116 
158 
28 

1,013 

1,046 



159 
401 
37 
17 
11 
421 

1,989 



426 

200 

81 

96 

52 

696 

37 

194 

207 

10,742 



174 
678 



297 

61 

238 

648 

13 

6,615 

113 

2,005 

752 



11,993 



60 
226 

98 
155 
506 



119 
511 



164 
9 
138 
223 
861 
302 
722 

1,850 

271 

240 

391 

36 

1,852 

2,466 



200 

458 

48 

17 

40 

1,703 

2,569 



424 
295 

89 
270 

86 
543 
133 
248 
481 



334 

543 

17 

5,155 

328 

1,836 

1,289 



28,032 

4,030 
50 

1,438 
214 
167 
358 
198 
564 

1,041 

1,434 
168 
152 
145 
969 



DYES 



TABLE SA.—Benzenoid dyes: U.S. production and sales , 1964— Continued 



Dye 



DISPERSE DYES- -Continued 

Disperse red dyes, total 

Disperse Red 1 

Disperse Red 5 

Disperse Red 11 

Disperse Red 13 

Disperse Red 17 

Disperse Red 60 

All other 

Disperse violet dyes, total 

Disperse Violet 1 

All other 

Disperse blue dyes, total 

Disperse Blue 1 

Disperse Blue 3 

Disperse Blue 7 

Disperse Blue 64 

All other 

Disperse trown dyes 

Disperse black dyes, total 

Disperse Black 1 

Disperse Black 9 

All other 

FIBER-REACTIVE DYES 

Fiber-reactive dyes, total 

Reactive yellow dyes 

Reactive blue dyes— 

All other reactive dyes 

FLUORESCENT BRIGHTENING AGENTS 

Total 

Fluorescent Brightening Agent 68 

All other fluorescent brightening agents 

FOOD, DRUG, AND COSMETIC COLORS 

Total 

Food, Drug, and Cosmetic Dyes 

Total 

FD&C Blue No. 1 

FE&C Red No. 2 - 

FDSiC Red No. 3 

FDScC Red No. 4 

FE&C Yellow No. 5 

FSScC Yellow No. 6 

All other food, drug, and cosmetic dyes 

Drug and Cosmetic and External Drug 
and Cosmetic Dyes 

Total- 

DiC Red No. 7 

DScC Red No. 19— - 

See footnotes at end of table. 



Production 



1,000 
pounds 
1,620 



211 
63 
64 

189 

59 

1,034 



38 
331 



5,056 



306 

1,741 

252 

179 

2,578 

131 

2,863 



2,122 
399 



1,640 



Quantity 



243 
683 
714 



16,675 



31 
16,644 



2,909 



2,710 



65 
786 

49 
277 
700 
659 
174 



1,000 
pounds 



227 
35 
42 
13 

123 
73 

998 



30 
285 



4,790 



311 

1,565 

271 

2,643 

140 

2,465 



1,000 
dollars 



332 

1,744 

389 



1,526 



225 
621 
680 



15,673 



33 
15,640 



2,846 



2,630 



58 
785 

43 
324 
644 
595 
181 



4,679 



352 
46 
218 
19 
145 
259 
3,640 

817 



117 
700 



13,831 



1,285 
2,563 
1,702 

8,281 

227 

3,014 



392 

1,879 

743 



6,261 



851 
3,019 
2,391 



27,802 



354 
27,448 



9,970 



638 
2,220 

720 
1,620 
2,135 
1,768 

869 



1,099 



22 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 8A. — Benzenoid dyes : U.S. production and sales , 1964 — Continued 



Dye 



Production 



Quantity Value 



FOOD, DRUG, AND COSMETIC COLORS- -Continued 



Drug and Cos 
and Cosm. 



c and Extei 
Dyes--Cont 



nal Dr 
.nued 



1,000 
pounds 



D«tC Red No. 21 

E&C Red No. 36 

All other drug and cosmetic and external drug and cosmetic 
dyes 

MORDANT DYES 

Total 

Mordant yellow dyes, total 

Mordant Yellow 1 

Mordant Yellow 8 

Mordant Yellow 16 

All other 

Mordant orange dyes, total 

Mordant Orange 1 

Mordant Orange 6 

All other 

Mordant red dyes, total 

Mordant Red 7 

All other 

Mordant blue dyes, total 

Mordant Blue 1 

All other 

Mordant brown dyes, total 

Mordant Brown 1 

Mordant Brown 33 

Mordant Brown 40 

All other 

fcfardant black dyes, total 

Mordant Black 3 

Mordant Black 11 

Ifcirdant Black 13 

Mordant Black 17 

Mordant Black 38 

All other 

All other mordant dyes 

SOLVENT DYES 

Total — 

Solvent yellow dyes, total 

Solvent Yellow 2 

Solvent Yellow 3 

Solvent Yellow 14 

Solvent Yellow 47 

All other 

Solvent orange dyes, total 

Solvent Orange 3 

Solvent Orange 7 

All other 



3,551 



10 
159 



2,736 



2,054 
409 
273 



8,547 



45 
747 

41 
262 



121 
225 



1.000 
dollars 



3,976 



3,164 



20 
2,273 



7,974 



38 
516 



108 
220 



140 
30 



4,995 



138 
232 



182 
139 



33 
483 



3,138 



25 

1,968 

111 

522 

41 
471 

36 



13,380 



1,816 



49 

59 

512 

184 

1,012 

671 



37 
165 
469 



See footnotes at end of table. 



DYES 
TABLE 8A. — Benzenoid dyes : U.S. production and sales , 1964 — Continued 



23 



Dye 



Production 



CJuantity 



SOLVENT DYES— Continued 

Solvent red dyes, total 

Solvent Red 24 

Solvent Red 26 

Solvent Red 49 

All other 

Solvent violet dyes, total 

Solvent Violet 8 

All other 

Solvent green dyes, total 

Solvent Green 3 

All other 

Solvent brown dyes 

All other solvent dyes 

SULFUR DYES^ 

Total 

Sulfur Blue 7 

Leuco Sulfur Blue 7 

Sulfur Blue 11 

Sulfur Brown 10 

Sulfur Black 1 

Leuco Sulfur Black 2 

All other sulfur dyes 

VAT DYES 

Total 

Vat yellow dyes, total 

Vat Yellow 2, 8-I/25S 

Vat Yellow 4, 12-l/2?t- — 

All other 

Vat orange dyes, total 

Vat Orange 1, 20^S 

Solubllized Vat Orange 1, 26$ 

Vat Orange 2, 12^ 

Vat Orange 4, 6f- 

Vat Orange 5, 105^ 

Solubilized Vat Orange 5, SOjt 

Vat Orange 7, II56 

Vat Orange 9, 12^4 

Vat Orange 15, 10^ 

All other 

Vat red dyes, total 

Vat Red 1, 13% 

Solubilized Vat Red 1, 375^ 

Vat Red 13, 11^6 

Vat Red 15, lOf 

Vat Red 32, 20;^ 

All other 

Vat violet dyes, total 

Vat Violet 1, 1156 

Vat Violet 2, 205^ 

Vat Violet 9, 125^ 

Vat Violet 13, 6-1/4^6 • 

All other 

See footnotes at end of table. 



1,192 



293 

300 

20 

579 



163 



146 
47 



5,055 



17,776 



52,518 



3,394 

1,784 

764 

846 

2,296 



485 
8 
300 



6 
207 
101 
471 
656 

1,126 



"52S" 



100 
171 



283 
36 



308 
156 



1.000 
pounds 



1,000 
dollars 



1,140 



295 

257 

21 

567 



318 
148 



60 
4,987 



17,268 



121 


123 


639 




21 


16 


47 


50 


1,076 


1,188 


2,776 


2,452 


13,096 


13,439 



51, 699 



3,431 



1,884 
735 
812 

2,077 



373 

12 

263 

93 

119 

4 

225 

106 

464 

418 

1,056 



501 



234 
29 
82 

380 
82 



2,215 



530 

450 

136 

1,099 

950 



472 
478 



252 
175 



227 
7,074 



9,798 



19 

35 

407 

974 

8,260 



46, 162 



4,641 



1,637 

835 

2,169 

4,729 



1,060 
88 
550 
258 
170 
42 
591 
255 
980 
735 



783 
38 
263 
172 
127 
923 

1,578 



287 
473 
245 



24 



SYNTHETIC ORGANIC CHEMICALS, 1964 
TABLE 8A. — Benzenoid dyes: U.S. production and sales, 1964 — Continued 



r>ye 



Production 



Sales 



Quantity 



Unit 
value^ 



VAT DYES— Continued 



Vat blue dyes, total 

Vat Blue 4, 10$ 

Vat Blue 6, 8-I/356 

Solubilized Vat Blue 6, 17-1/2^- 

Vat Blue 18, 135^ 

Vat Blue 20, W?^ 

All other 



1,000 
pounds 
20,894 



1,000 
pounds 
20,519 



Vat green dyes, total 

Vat Green 1, 656 

Vat Green 3, 10^ - 

Solubilized Vat Green 3, 265^- 

Vat Green 8, 8-l/2?6 - 

Vat Green 9, I2-I/256- — 

All other 



74 

3,550 

31 

960 

1,152 
15,127 

11,378 



Vat brown dyes, total- 
Vat Brown 1, lljS 

Vat Brown 3, lljt 

Vat Brown 5, 13$ 

All other 



5,902 
2,955 

17 
1,127 
1,302 

75 

5,063 



66 

3,353 

39 

1,034 

992 

15,035 

11,436 



1,000 
dollars 
11,969 



3.58 



148 
3,457 

244 
1,655 
1,097 
5,368 

7,916 



2.24 
1.03 
6.26 
1.60 
1.11 
.36 



Vat black dyes, total 

Vat Black 9, 16?^ 

Vat Black 25, 12-1/2$-- 
Vat Black 27, 12 -1/2 ?^- 
All other 



1,018 
990 
144 

2,911 

7,584 



5,599 
2,959 

1,347 

1,444 

87 

4,632 



All other dyes-^ 



las' 

3,120 

966 

3,390 

41A 



964 

891 

100 

2,677 

7,741 



3,325 
2,092 

966 

1,275 

258 

6,325 



1.37 



123 
3,313 

909 
3,396 

337 



1,735 

1,422 

145 

3,023 

6,698 



1.80 
1.60 
1.45 
1.13 

.87 



295 
2,364 
1,059 
2,980 

878 



2.40 

.71 

1.16 



■'■ Calculated from rounded figures. 

^ Production and sales quantities of C.I. Leuco Sulfur and C.I. Solubilized Sulfur dyes are reported in terms of 
the usual commercial concentration of the C.I. Sulfur dyes. 

^ Includes oxidation bases, ingrain dyes, and miscellaneous dyes. Statistics for these groups of dyes may not be 
published separately because publication would disclose information received in confidence. 

On the other hand, the output of a few important dyes was smaller in 1964 than in 1963. Pro- 
duction of Vat Green 3 was 3. nnillion pounds in 1964, or 7. 9 percent less than the 3. 2 million 
pounds produced in 1963; that of Mordant Black 11 was 2. 1 million pounds, or 14. 8 percent less 
than the 2.4 million pounds produced in 1963. The output of Vat Green 9 was 24.4 percent 
smaller in 1964 than in 1963; that of Vat Green 8 was 20. 8 percent smaller; and that of Acid 
Black 1 was 19.9 percent smaller. 

Table 9 summarizes production and sales of dyes in 1964, by class of application. Five 
classes of dyes grouped by class of application accounted for 74 percent of the total output of 
dyes in 1964. Vat dyes accounted for 28. 5 percent of the total; direct dyes, for 17. 1 percent; 
acid dyes, for 9. 6 percent; sulfur dyes, for 9. 6 percent; and fluorescent brightening agents, for 
9. 1 percent. Of the above five classes, the output for acid and vat dyes remained about the same 
in 1964 as in 1963. The output of direct dyes was 10. 9 percent larger in 1964 than in 1963. Sta- 
tistics on sulfur dyes and fluorescent brightening agents were not published separately for 1963. 

Of the remaining classes, the output of fiber- reactive dyes was 1. 6 million pounds in 1964, 
or 44. 9 percent more than the 1. 1 million pounds in 1963. Production of food, drug, and cos- 
metic colors was 21.0 percent larger in 1964 than in 1963; disperse dyes, 16.0 percent larger; 
solvent dyes, 11.7 percent larger; and basic dyes, 4.6 percent larger. On the other hand, the 
output of mordant dyes was 12. 5 percent smaller in 1964 than in 1963, and that of azoic dyes 
and components, 1.0 percent smaller. 

Table 10 shows production and sales of dyes in 1964, by chemical class. In 1964, three 
chemical classes of dyes accounted for approximately two-thirds of all the dyes produced: Azo 
dyes accounted for 31. 4 percent of the total; anthraquinone dyes, for 22. 6 percent; and stilbene 
dyes, for 10. percent. The output of each of these three classes was larger in 1964 than in 
1963; Stilbene dyes were 16. percent larger; azo dyes, 8. 5 percent larger; and anthraquinone 
dyes, 1.8 percent larger. Of the remaining chemical classes for which 1963 and 1964 statistics 
are published, production of eight classes was larger in 1964 than in 1963. No comparable sta- 
tistics for 1963 were published on the following classes of dyes: Cyanine, indigoid, and sulfur. 
In terms of value of sales, the most important classes of dyes in 1964 were the azo dyes ($96. 6 
million), the anthraquinone dyes ($66.9 million), the stilbene dyes ($29.2 million), and the tri- 
arylmethane dyes ($12.7 million). 



DYES 



25 



TABLE 9. — Benzenoid dyes : U.S. production arid sales , by class of application, 1964 



Class of application 



Total 

Acid 

Azoic dyes and components: 

Azoic compositions 

Azoic dlazo components, bases (Fast color bases) 

Azoic dlazo components j salts (Fast color salts) 

Azoic coupling con?!onents (Naphthol AS and derivatives) 

Basic 

Direct 

Disperse 

Fiber-reaotlve 

Fluorescent brightening agents 

Food, drug, and cosmetic colors 

Mordant 

Solvent 

Sulfur^ 

Vat 

All other^— 



Production 



1,000 
pounds 
l8<i.,387 



Quantity 



1,000 
pounds 
178,273 



17,090 

1,707 

1,272 

1,973 

2,447 

8,553 

31,939 

11,993 

1,526 

15,673 

2,846 

3,976 

7,974 

17,268 

51,699 

337 



1,000 
dollars 
264,023 



35,812 

3,441 

1,984 

2,028 

4,696 

20,878 

46,807 

28,032 

6,261 

27,802 

11,069 

4,995 

13,380 

9,798 

46,162 

878 



Unit 
value'"' 



md 
$1.48 



2.10 

2.02 
1.56 
1.03 
1.92 
2.44 
1.47 
2.34 
4.10 
1.77 
3.89 
1.26 
1.68 
.57 



Calculated from rounded figures. 

2 Production and sales quantities of C.I. Leuco Sulfur and C.I. Solubilized Sulfur dyes are reported in temiB of 
the usual commercial concentration of the C.I. Sulfur dyes. 

^ Includes oxidation bases, ingrain dyes, and miscellaneous dyes. Statistics for these groups of dyes may not be 
published separately because publication would disclose information received in confidence. 



TABLE 10.— Benzenoid dyes: U.S. production and sales , by chemical class, 1964 



Chemical class 



Total 

Anthraquinone— 

Azo, total 

Manoazo 

Disazo 

Trisazo 

Polyazo 

Not specified- 

Azoic 

Cyanine 

Indigoid 

Ketone imine 

Methine 

Nitro 

Oxazine 

Phthalooyanine- ■ 

Quinoline 

Stilbene 

Sulfur^ 

Thlazole 

Triarylmethane- 

Xanthene 

All other^ 



Production 


Sales J 






Unit 5 




Quantity 


Value 


value 


1,000 


1,000 


1,000 


Per 


pounds 


pounds 


dollars 


pound 


184,387 


178,273 


264,023 


$1.48 


41,661 


40,675 


66,889 


1.64 


57,897 


57,367 


96,579 


1.68 


21,084 


19,932 


38,522 


1.93 


16,873 


17,278 


28,867 


1.67 


11,883 


12,303 


12,730 


1.03 


2,344 


2,218 


3,819 


1.72 


5,713 


5,636 


12,641 


2.24 


8,787 


7,399 


12,149 


1.64 


373 


362 


1,113 


3.07 


5,729 


6,144 


3,302 


.54 


731 


782 


1,614 


2.06 


1,074 


974 


3,367 


3.46 


720 


679 


1,258 


1.85 


172 


144 


601 


4.17 


1,987 


1,868 


4,800 


2.57 


637 


519 


1,658 


3.19 


18,488 


17,640 


29,166 


1.65 


17,776 


17,268 


9,798 


.57 


462 


480 


1,043 


2.17 


5,607 


5,312 


12,682 


2.39 


1,312 


737 


3,473 


4.71 


20,974 


19,923 


14,531 


.73 



1 



Calculated from rounded figures. 

^ Production and sales quantities of C.I. Leuco Sulfur and C.I. Solubilized Sulfur dyes are reported in terms of 
the usual commercial concentration of the C.I. Siilfur dyes. 

' Includes aoridine, amlnoketone, azine, coumarin, hydroxylcetone, nltroso, oxidation bases, thiazine, vat sulfur, 
and miscellaneous dyes. Statistics for these groups of dyes may not be published separately because publication 
would disclose information received in confidence. 



26 SYNTHETIC ORGANIC CHEMICALS, 1964 

Pigments 

As the terms are used in this report, synthetic organic pigments are toners and lakes de- 
rived in whole or in part from benzenoid chemicals and colors. They are used in paints and 
related products, in printing inks, and in plastics and resin materials. 

Statistics on production and sales of all benzenoid pigments in 1964 are given in table llA.^ 
Statistics on sales of a few selected pigments by connmercial forms (dry full-strength form, dry 
extended fornn, dry dispersions, aqueous dispersions, and flushed colors) are given in table 12. 
Prior to 1961, statistics for toners included the quantities and values of extenders and diluents. 
Beginning in 1961, data were collected for both the full- strength and extended toners on a full- 
strength-toner- content basis. Individual toners and lakes are identified in this report by the 
names used in the second edition of the Colour Index rather than by their common names.'* 

Total production of benzenoid pigments in 1964 was 44. 1 million pounds--ll. 8 percent more 
than the 39.4 million pounds produced in 1963 and 18. 6 percent more than the 37. 2 million 
pounds produced in 1962. Total sales of benzenoid pigments in 1964 amounted to 35. 1 million 
pounds, valued at $84. 1 million, compared with 33. 5 million pounds, valued at $79. 6 million, in 
1963 and 31. 6 million pounds, valued at $74. 3 million, in 1962. In terms of quantity, sales of 
benzenoid pignnents in 1964 were 4. 6 percent larger than in 1963 and 11.0 percent larger than in 
1962; in terms of value, sales in 1964 were 5. 7 percent larger than in 1963 and 13.2 percent 
larger than in 1962. 

Production of toners in 1964 amounted to 40. million pounds--12. 6 percent more than the 
35.6 million pounds reported for 1963. Sales in 1964 were 31.4 million pounds, valued at $80.9 
million, compared with 30. 1 million pounds, valued at $76. 2 million, in 1963. Sales in 1964 
were thus 4.4 percent larger than those in 1963 in terms of quantity, and 6. 2 percent larger in 
terms of value. Production of red toners in 1964 amounted to 17. 8 million pounds, or 44. 5 per- 
cent of the total output of toners. The individual toners listed in the report ■which were produced 
in the largest quantities in 1964 were Pigment Green 7, 4. million pounds; Pigment Blue 15, 
alpha form, 3. 9 million pounds; Pigment Yellow 12, 3. 2 million pounds; Pigment Red 49, bar- 
ium toner, 3. 1 million pounds; and Pigment Blue 19, 3.0 million pounds. 

Production of lakes totaled 4. million pounds in 1964--4. 8 percent more than the 3. 8 mil- 
lion pounds reported for 1963. Sales of lakes in 1964 amounted to 3. 7 million pounds, valued at 
$3. 3 million, compared with sales in 1963 of 3.4 million pounds, valued at $3.4 million. Sales 
in 1964 were thus 6. 8 percent larger than those in 1963 in terms of quantity, but 5. 1 percent 
smaller in terms of value. Pigment Blue 24, with an output of 2.0 million pounds, was the lake 
produced in largest quantity in 1964. 

For each of 14 selected pigments, or groups of pigments, the Commission's report gives 
figures on sales by commercial forms. Pigment Yellow 12, Pigment Red 90, and Pigment Blue 
19 were sold principally in the flushed form. The rennaining 11 pigments, or groups of pigments, 
for which statistics are published were sold principally in the dry full- strength form. Statistics 
on sales by commercial forms could not be published for Pigment Red 49, sodium toner and 
Pigment Blue 24 without revealing the operations of individual companies. 

^ See also table IIB, pt. Ill, which lists these products alphabetically and identifies the manufacturers, and table 23 in appendix A» which 
shows imports of benzenoid pigments during the years 1963-64, 

■♦See appendix C, which lists the common names of all the pigments mentioned in this report. 



PIGMENTS 



27 



TABLE llA.—Benzenoid pigments : U.S. production and sales , 1964 

[Listed below are all toners and lakes for which any reported data on production or sales may be published. (Leaders 
are used where the reported data are accepted in confidence and may not be published or where no data were 
reported.) Table IIB in pt. Ill lists all toners and lakes for which data on production or sales were reported and 
identifies the manufacturer of each] 



Pigment 



Grand total 

TONERS 

Total 

Yellow toners, total 

Hansa yellows, total 

Pigment Yellow 1, C.I. 11 680 

Pigment Yellow 3, C.I. 11 710 - 

Other Hansa yellows 

Benzidine yellows, total 

Pigment Yellow 12, C.I. 21 090 

Pigment Yellow 13, G.I. 21 100 

Pigment Yellow 1-4, G.I. 21 095 

Pigment Yellow 17, C.I. 21 105 

Other benzidine yellows 

All other 

Orange toners, total 

Pigment Orange 2, C.I. 12 060 

Pigment Orange 5, C.I. 12 075 

Pigment Orange 13, C.I. 21 110 

Pigment Orange 16, C.I. 21 160 

All other 

Red toners, total 

Naphthol reds, total 

Pigment Red 2, C.I. 12 310 

Pigment Red 5, C.I. 12 A90 

Pigment Red 13, C.I. 12 395 

Pigment Red 17, G.I. 12 390 

Pigment Red 18, C.I. 12 350 

Pigment Red 22, G.I. 12 315 

Pigment Red 23, C.I. 12 355 

Other naphthol reds 

Pigment Red 1, C.I. 12 070, dark 

Pigment Red 1, G.I. 12 070, light 

Pigment Red 3, C.I. 12 120 

Pigment Red 4, C.I. 12 085 

Pigment Red 38, C.I. 21 120 

Pigment Red 48, G.I. 15 865 

Pigment Red 49, C.l. 15 630: 

Barium toner 

Calcium toner 

Sodium toner 

Pigment Red 52, G.I. 15 860 

Pigment Red 53, C.I. 15 585, barium toner-. 
Pigment Red 57, G.I. 15 850, calcium toner. 

Pigment Red 63, C.I. 15 880 

Pigment Red 81, C.I. 45 160, PMA 

Pigment Red 81, C.I. 45 160, PTA 

Pigment Red 90, C.I. 45 380 

All other 

Violet toners, total 

Pigment Violet 1, G.I. 45 170, BIA 

Pigment Violet 1, C.I. 45 170, PTA 

Pigment Violet 3, C.I. 42 535, fugitive- 
Pigment Violet 3, C.I. 42 535, PMA 

Pigment Violet 3, C.I. 42 535, PTA— 

All other 

See footnotes at end of table. 



1,000 
pounds 

44,053 



40,028 



5,958 



1,152 
540 
128 

484 
4,642 
3,180 
195 
978 
176 
113 
164 

768 



206 
155 
179 
192 

17,817 



11 
98 
123 
291 
198 
241 

1,913 
372 
144 

2,365 

3,058 

1,425 

240 

910 

1,884 

937 

41 

228 

131 

1,243 

1,696 

1,077 



(iiantlty 



444 

359 

30 

143 



1,000 
pounds 

35,081 



925 

401 

88 

436 

2,931 

1,791 

116 

793 

130 

101 

97 

651 



161 

. 145 

152 

193 

14,949 



605 
51 



86 
117 
194 
171 
198 

1,395 
259 
131 

2,076 

2,926 

1,349 
282 
828 

1,534 
836 
32 
169 
128 
595 

1,435 

1,015 



1.000 
dollars 

84,131 



424 
333 



),870 



10,583 



2,437 

748 

208 

1,481 

6,994 

3,900 

375 

1,889 

436 

394 

1,152 

2,814 



255 

487 

418 

1,654 

31,964 



2,665 

159 

385 

20 

235 

252 
431 

1,183 
212 
239 

2,155 
362 
594 

3,881 

2,844 
1,375 

291 
1,232 
1,934 
1,259 
67 
1,059 

818 
1,109 
9,868 

3,673 



172 
239 
624 
982 
129 
1,527 



28 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE llA. — Benzenoid pigments : U.S. production and sales , 1964 — Continued 



Pigment 



Quantity 



Unit 
value •'■ 



TONEES--Continued 

Blue toners, total 

Pigment Blue 1, C.I. 42 595, MA 

Pigment Blue 1, C.I. <i2 595, PTA 

Pigment Blue 9, C.I. 42 025, FMA 

Pigment Blue 9, C.I. 42 025, PTA 

Pigment Blue U, C.I. 42 600, PMA 

Pigment Blue 15, C.I. 74 160, alpha form 

Pigment Blue 15, c!l. 74 160, beta foim 

Pigment Blue 19, C.I. 42 750A 

Pigment Blue 25, C.I. 21 180 

All other 

Green toners, total 

Pigment Green 1, C.I. 42 040, BJA 

Pigment Green 1, C.I. 42 040, PTA 

Pigment Green 2, C.I. 42 040 and 49 005, IMA- 
Pigment Green 2, C.I. 42 040 and 49 005, PTA- 

Pigment Green 4, C.I. 42 000, PTA 

Pigment Green 7, C.I. 74 260 

Pigment Green 8, C.I. 10 006 

All other 

Brown toners, total 

Pigment Brown 5, C.I. 15 800 

All other 

Blaot toners 

LAKES 

Total 

Red lakes, total 

Pigment Red 60, C.I. 16 105 

Pigment Red 83, C.I. 58 000 

(Acid Red 26), C.I. 16 150 

All other 

Violet lakes, total 

Pigment Violet 5, C.I. 58 055 

All other 

Blue lakes, total 

Pigment Blue 24, C.I. 42 090 

All other 

Black lakes: (Natural Black 3), C.I. 75 291 

All other lakes^ 



10 

56 

3,864 

2,007 

3,033 

142 

202 

4,581 



4,004 
174 
282 



4,025 



113 
78 

575 
94 



2,058 



,026 
32 



1.000 


1,000 


pounds 


dollars 


7,460 


21.229 


142 


672 


30 


152 


3 


12 


8 


50 


57 


511 


3,149 


8,417 


1,577 


4,596 


2,235 


5,342 



3,169 



11 

6 

50 

37 

6 

2,760 

145 

154 

74 



3,653 



110 
74 

575 
89 



1,690 



1,660 



10,170 



60 

37 

230 

236 

21 

8,292 

187 

1,107 



82 

183 



3,261 



195 
249 
255 
152 



1,586 



67 
466 



$2.85 



5.45 
6.17 



3.58 
1.78 



1-00 



1.77 
3.36 



2.30 
1.50 



1.02 
.50 



^ Calculated from rounded figures. 

^ Includes all brown, green, orange, and yellow lakes and all other black lakes. 

Note. —The C.I. (Colour Index) numbers shown in this report are the identifying numbers given in the second edition 
of the Colour Index, 

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic) acids, 
respectively. 



PIGMENTS 



29 



TABLE 12.- 



■U.S. sales of selected dp full-strength colors, dry extended colors dry dispersions 
aqueous dispersions, and flushed colors, 1964 



Selected pigments by commercial forms 



Quantity^ 



Unit value ^ 



Pigment Yellow 12, C.I. 21 090, total 

Dry full-strength toner 

Dry extended toner, aqueous dispersions^ and flushed color'' 



Pigment Yellow 13, C.I. 21 100; Pigment Yellow 14, C.I. 21 095; Pigment 

Yellow 17, C.I. 21 105; and other "benzidine yellows, total 

Dry full-strength toner 

Diy extended toner and dry dispersions'' 

Aqueous dispersions-' 

Flushed color 



Pigment Red 3, C.I. 12 120, total- - 

Dry full-strength toner and diy extended toner''- 
Aqueous dispersions^ 

Flushed color 



Pigment Red 48, C.I. 15 865, total 

Dry full-strength toner 

Dry extended toner 

Dry dispersions 

Aqueous dispersions-' and flushed color* 



Pigment Red 49, C.I. 15 630, barium toner, total- 
Dry full-strength toner 

Diy dispersions and aqueous dispersions-' "^ 

Flushed color 



Pigment Red 49, C.I. 15 630, calcium toner, total- 
Dry full-strength toner and dry dispersions'* 

Aqueous dispersions^ and flushed color* 



Pigment Red 49, C.I. 15 630, sodium toner'*- 



Pigment Red 53, C.I. 15 585, barium toner, total- 

Diy full-strength toner 

Flushed color 



Pigment Red 90, C.I. 45 380, total 

Dry full-strength toner and dry extended toner'' 
Flushed color 



Pigment Violet 3, C.I. 42 535, fugitive, total 

Diy full-strength toner and dry extended toner''- 
Flushed color 



Pigment Violet 3, C.I. 42 535, permanent (PMA and PTA), total 

Diy full-strength toner 

Diy extended toner, dry dispersions and aqueous dispersions ^ *- 
Flushed color 



Pigment Blue 15, C.I. 74 160, alpha form, total- 
Diy full-strength toner 

Dry extended toner 

Dry dispersions 

Aqueous dispersions^ 

Flushed color 



Pigment Blue 15, C.I. 74 160, beta form, total- 
Dry full-strength toner 

Dry extended toner and diy dispersions'' 

Aqueous dispersions^ 

Flushed color 



Pigment Blue 19, C.I. 42 750A, total 

Dry full- strength toner and diy extended toner ''- 
Aqueoiis dispersions^ and flushed color'' 



1,000 
pounds 

1,791 



607 
1,184 



1,140 



83 
112 

145 

1,395 



863 

57 

475 

2,076 



1,932 
37 
28 
79 

2,926 



2,072 



1,349 



1,108 
241 



1,534 



958 
576 



53 

542 



279 
145 



3,149 



1,756 

447 

80 

714 

152 

1,577 



863 

36 

402 

276 

2,235 



454 
1,781 



1.000 
dollars 

4,102 



1,314 
2,788 



3,169 



2,207 
196 
298 
468 

2,212 



1,332 

97 

783 

3,915 



3,626 

75 

60 

154 

2,992 



2,016 

5 

971 



1,454 



1,127 
327 



2,003 



1,205 
798 



114 
1,095 



409 
220 



610 
226 
291 

8,588 



4,527 
1,560 

178 
1,924 

399 

4,594 



2,749 
127 

1,090 
628 

5,430 



1,097 
4,333 



See footnotes at end of table. 



30 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 12. — U.S. sales of selected dry full-strength colors, dry extended colors, dry dispersions, 
aqueous dispersions, and flushed colors, 1964 — Continued 



Selected pigments by commercial forms 



Quantity""" 



Unit value ^ 



Pigment Blue 2^, C.I. ^2 090* 

Pigment Green 7, C.I. 74 260, total- 

Diy full-strength toner 

Dry extended toner 

Dry dispersions 

Aqueous dispersions- 

Flushed color 



1.000 
pounds 

1,660 

2,760 



1,000 
dollars 



1,7-40 
258 
130 
MA 
168 



8,529 



5,235 
924 
482 

1,459 
429 



$1.18 
3.09 



3.01 
3.58 



""" Quantity of the various commercial forms is given in terms of dry full-strength toner (or dry lake) content. 
^ Calculated from rounded figures. 
^ Includes presscake. 

'' Separate data on these commercial forms may not be published without revealing the operations of individual 
companies. 

Note. — Kie C.I. (Colour Index) numbers shown in this report are the identifying numbers given in the second 
edition of the Colour Index. 

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic) 
acids, respectively. 



MEDICINAL CHEMICALS 31 

Medicinal Chemicals 

Medicinal chemicals include the medicinal and feed grades of all organic chemicals having 
therapeutic Value, whether obtained by chemical synthesis, by fermentation, by extraction from 
naturally occurring plant or animal substances, or by refining the technical grade material. 
They include alkaloids, antibiotics and other anti- infective agents, antihistamines, autonomic 
drugs, central-nervous-system depressants and stimulants, hormones, vitamins, and other 
therapeutic agents for human or veterinary use and for animal feed supplements. 

Statistics on the production of medicinal chemicals are in terms of 100-percent content of 
the medicinal chemical itself, exclusive of all diluents or other materials used in mixing or 
compounding tablets, solutions, and suspensions for consumer use. Except for antibiotics, the 
statistics on sales include only that part of the original (primary) production that was sold in 
undiluted or uncompounded form. Sales of antibiotics include all sales by the primary producers, 
both diluted and undiluted, in bulk or in dosage forms. 

Statistics on U. S. production and sales of medicinal chemicals in 1964 are given in table 
13A.^ Total production of medicinal chemicals in 1964 amounted to 144 million pounds, or 3. 5 
percent more than the 139 million pounds produced in 1963, and 13.1 percent more than the 127 
nnillion pounds produced in 1962. Total sales of medicinal chemicals in 1964 amounted to 119 
million pounds, valued at $646 nnillion, compared with sales in 1963 of 114 million pounds, 
valued at $639 million, and sales in 1962 of 104 million pounds, valued at $601 million. Sales in 
1964 were thus 4. 2 percent larger than in 1963 and 14. 5 percent larger than in 1962 in terms of 
quantity, and 1. percent larger than in 1963 and 7. 5 percent larger than in 1962 in terms of 
value. 

Since 1962, the data published on medicinal chemicals have been divided into antibiotics and 
benzenoid and nonbenzenoid groups, instead of into cyclic and acyclic groups as in previous 
years. Totals for the cyclic and acyclic groups are shown in this report, however, in order to 
permit comparison of the statistics for 1964 with those for the years prior to 1962. Production 
of cyclic medicinal chemicals in 1964 amounted to 98 million pounds, or 3. 7 percent more than 
the output of 94 million pounds reported for 1963. Sales of cyclic medicinals in 1964 amounted 
to 77 million pounds, valued at $612 million, compared with sales in 1963 of 74 million pounds, 
valued at $605 million. Production of acyclic medicinals in 1964 amounted to 47 million pounds, 
or 3. 2 percent more than the output of 45 million pounds reported for 1963. Sales of acyclic 
medicinals in 1964 amounted to 42 million pounds, valued at $33 million, compared with sales 
in 1963 of 40 nnillion pounds, valued at $34 million. 

Production of antibiotics for all uses in 1964 amounted to 6. 5 million pounds, of which 3. 9 
million pounds was for human or veterinary use and 2. 6 million pounds was for animal feed 
supplements, food preservation, and crop spraying. Sales amounted to 5.7 million pounds, 
valued at $386 million. The most important antibiotics, in terms of value, were the penicillin 
salts and tetracycline. Production of penicillin salts for all uses amounted to 1,202 trillion 
U. S. P. units; sales totaled 965 trillion U. S. P. units, valued at $86 million. Production of tetra- 
cycline for human or veterinary use amounted to 176 million grams of activity; sales totaled 
152 nnillion grams of activity, valued at $55 million. 

Production of benzenoid nnedicinals in 1964 amounted to 78 million pounds; sales totaled 61 
million pounds, valued at $162 nnillion. The benzenoid nnedicinal chennicals that Tvere produced 
in largest quantity in 1964 were aspirin, 28. 2 million pounds; salicylic acid, 13. 1 million 
pounds; and the anti- infective sulfonamides, 5. million pounds. 

Production of nonbenzenoid medicinals in 1964 amounted to 60 million pounds; sales to- 
taled 52 million pounds, valued at $98 million. The most important nonbenzenoid nnedicinal 
chennicals, in terms of quantity, were choline chloride, production of which amounted to 25. 2 
million pounds, piperazine and salts, 7. million pounds, and methionine and its hydroxy ana- 
logue, 6. million pounds. 

Production of all vitamins, both benzenoid and nonbenzenoid, amounted to 14. 1 million 
pounds in 1964; sales amounted to 10. 6 million pounds, valued at $60. 6 million. The most im- 
portant vitamins, in ternns of value, were vitamins A, Bj, B12, and C. Production of vitamin 
A alcohol and esters announted to 618 trillion U. S. P. units; sales totaled 470 trillion U. S. P. 
units, valued at $19.7 million. Production of vitamin B2 (riboflavin) amounted to 662,000 
pounds; sales totaled 701,000 pounds, valued at $6.4 million. Sales of vitamin B12 (cyanoco- 
balannin) announted to 398,000 grams, valued at $6.9 million. Production of vitamin C (ascor- 
bic acid) and derivatives amounted to 7.4 million pounds; sales totaled 5.3 million pounds, 
valued at $10. 3 million. 



5 See also table 13B, pt. lU, which lists these products alphabetically and identifies the manufacturers, and table 23 in appendix A, which 
shows imports of coal-tar medicinal chemicals and pharmaceuticals during the years 1963-64. 



32 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 13A. — Medicinal chemicals: U.S. production and sales , 1964 



[Listed below are all synthetic organic medicinal chemicals for which any reported data on production or sales may be 

published. (Leaders are used where the reported data are accepted in confidence and may not be published or where 

no data were reported.) Table 13B in pt. Ill lists alphabetically all medicinal chemicals for which data on pro- 
duction or sales were reported and identifies the manufacturer of each] 



Production 



Sales'^ 



Quantity 



Grand total 

Cyclic'^ 

Acyclic*^ 

MEDICINAL CHEMICALS, AOTIBIOTICS^ 

Total 

For human or veterinary use, total 

Bacitracin 

Dihydrostreptomyoin 

Neomycin 

Penicillins, total 

Penicillin G, potassium 

Penicillin G, procaine 

Penicillin G, other 

Phenethicillin and potassium salt 

All other penicillins 

Tetracycline 

All other^ — 

For animal feed supplements, food preservation, and crop 

spraying, total 

Bacitracin -- 

Penicillin G, procaine 

All other^ - - 

MEDICINAL CHEMICALS, BENZENOID'' 

Total 

Alkaloids, except those affecting the autonomic or central 
nervous system 

Antihistamines, total 

Antinauseants 

2-[p-Chloro-a -(2-dimethylaminoethyl)benzyl] pyridine 

(Chlorpheniramine) maleate 

2-[a-(2-Dimethylaminoethyl)benzyl] -pyridine (Pheniramine) 

maleate 

2- [ ( 2-Dimethylami noethyl ) (p-methoxybenzyl)amino]pyridine 

(Pyrilamine) maleate 

All other 

Anti-infective agents, total 

Antimony, arsenic, bismuth, and mercury compounds* 

1-Hexadecylpyridinium (Cetylpyridinium) chloride 

Phenolic antiseptics and disinfectants 

Quinoline derivatives, total 

5-Chloro-7-iodo-8-qulnolinol (lodochlorhydroxyquin) 

5,7-Diiodo-8-quinolinol (Diiodohydroxyquin) 

8-Quinolinol (Oxyquinoline) benzoate 

8-Quinolinol (Oxyquinoline) sulfate 

All other 

Sulfonamides, total 

Sulfathlazole 

All other 

Other anti-Infective agents, total 

Anthelmintic, antifungal, and antlprotozoan agents 

All other' - — 

Autonomic drugs, total 

Parasympatholytic (anticholinergic) agents 



1,000 
pounds 
1^4,090 



97,579 
46,511 



6,540 



3,913 



92 

1,569 

505 

799 

54 

14 

197 

388 

1,857 



2,627 



565 
1,904 



77,557 



17,736 



2,937 

10 

157 

320 

11 

21 



10 
275 
4,964 
144 
4,820 
9,345 
7,229 
2,119 

338 



i.OOO 
pounds 

118,678 



76,946 
41,732 



5,729 



3,235 



436 

70 

1,215 

413 

623 

31 

12 

136 

336 

1,173 



2,494 



136 

515 

1,843 



61,344 



20 
167 



150 
10,887 



136 
227 



225 
1,476 

111 
1,365 
9,048 
6,616 
2,432 

230 

— 2r 



1,000 
dollars 

645,692 



612,233 
33,459 



385,910 



328,445 



1,128 

6,306 

5,069 

82,389 

18,411 

12,204 

10,972 

3,954 

36,848 

54,570 

178,983 



57,465 



3^< 
3,659 
50,717 



162,067 



656 
4.810 



269 
269 



4,272 
60,669 



299 
2,905 



2,897 

6,783 
291 

6,492 
50,682 
45,179 

5,503 

4,815 



See footnotes at end of table. 



MEDICINAL CHEMICALS 
TABLE ISA.— Medicinal chemicals: U.S. production and sales , i 564— Continued 



33 



Production''' 



Quantity 



MEDICKWl CHEMICALS, BENZENOID'— Continued 

Autonomic drugs — Continued 

Sympathomimetic (adrenergic) agents, total 

Epinephrine 

a-(lEopropylamlnomethyl)protocatechuyl alcohol 

(Isoproterenol) 

Norephedrine (Phenylpropanolamine) hydrochloride — 

Phenylephrine hydrochloride 

All other 

All other autonomic drugs 

Benzothiadiazine derivatives 

Bismuth subgallate 

Central depressants, total 

Dihydrocodeinone (Hydrocodone) bitartrate 

5-Ethyl-5-phenylbarbituric acid (Phenobarbital) 

5-Ethyl-5-phenylbarbituric acid, sodium derivative 

p-Hydroxyacetanilide (Acetaminophen) 

Salicylates, total 

Aspirin 

Sodium salicylate 

All other 

Skeletal muscle relaxants and tranq\iilizers , total 

Phenothiazine derivatives 

3-o-Tolyloxy-l,2-propanediol (Mephenesin) 

All other 

All other central depressants 

Central stimulants, total 

Amphetamines, total 

Anjjhetamine, dextroamphetamine, and levamphetamine 

base and salts 

Methamphetamine base and hydrochloride 

Antidepressants 

All other central stimulants 

Guaiacol glyceryl ether 

Salicylic acid 

Synthetic hypoglycemic agents 

Vitamins, total 

Ba (Riboflavin) (All grades) 

Bi2 (Cyanocobalamin) (All grades) ■'■■'■ 

Niacin (Nicotinic acid) (All grades) 

Niacinamide (Nicotinamide) 

All other 

All other benzenoid medioinals^^ 

MEDICINAL CHEMICALS, NONBENZENOID^^ 

Total 

Anti-infective agents, total 

Caprylates and undecylenates 

Derivatives of 5-nitrofurane, 5-nitroimidazole, and 5- 

nitrothiazole 

Halogen coii5)ounds 

Plperazine and salts, total 

Piperazine 

Piperazine hydrochloride 

Piperazine phosphate 

All other 

All other anti-infective agents 



1.000 
pounds 



(10) 



35,«^69 



242 

8 

1,060 

30,935 

28,221 

2,714 
400 



338 
2,823 



41 
70 

32 
13,127 
1,010 



1,549 
802 
429 

5,782 



59,993 



8,219 



1,000 
pounds 



(10) 



1,000 
dollars 



140 
40 



31,883 



1,037 

27,712 

24,864 

465 

2,383 

162 

3 

159 
2,674 



35 
10,587 



2,911 



701 

1 

1,218 

757 

234 

4,394 



51,605 



5,935 



397 



619 


547 


5,684 


140 






6,950 


4,774 


3,831 


2,631 


917 


854 


417 


413 


459 


196 


191 


154 


3,706 


3,253 


2,364 


93 


217 


566 



29 
1,038 
1,596 



6,777 
95 



33,445 



203 

759 

36 

1,357 

16,323 

13,560 

337 

2,426 

5,533 

158 

5,375 
9,234 

5,504 



2,690 
2,298 



113 
4,143 



21,747 



6,383 
6,852 
1,505 
1,369 
5,638 

19,293 



97,715 



10,583 



See footnotes at end of table. 



34 



SYNTHETIC ORGANIC CHEMICALS, '964 
TABLE 12 A. --Medicinal chemicals.- U.S. production and sales , 7564— Continued 



Production 



Quantity Value 



MEDICINAL CHEMICALS, NONBENZENOID^^--Continued 

Autonomic drugs 

Central depressants and stimulants, total 

Barbiturates, total 

S-seo-Butyl-S-ethylbarbituric acid (Butabarbital) and 

sodium derivative 

5-Ethyl- 5- (1-methylbutyl) barbituric acid (Pentobar- 
bital) 

All other 

Caffeine (natural and synthetic) 

2-Methyl-2-propyl-l,3-propanediol dicarbamate 

(Meprobamate) 

Succinylcholine chloride 

All other central depressants and stimulants 

Digestants and lipotropic agents, total 

Betaine base, hydrate, and hydrochloride 

Bile acids and salts 

Choline salts: 

Choline bitartrate 

Choline chloride (All grades) 

Choline dihydrogen citrate 

Tricholine citrate 

Methionine and hydroxy analogue 

All other digestants and lipotropic agents 

Hormones, total 

Hydrocortisone alcohol and acetate 

Prednisone 

All other 

Theobromine and theophylline derivatives 

Therapeutic nutrients, total 

Amino acids, total 

Amino acid mixtures 

Aspartic acid and salts 

Glutamic acid 

All other 

Calcium gluconate 

All other therapeutic nutrients 

5-Ureidohydantoin (Allantoin) 

Vitamins, total 

Ascorbic acid and derivatives, total 

Ascorbic acid 

All other 

Pantothenic acid and derivatives, total 

dl-Calcium pantothenate 

All other 

Vitamin A alcohol and esters, total^"'' 

Vitamin A palmitate (medicinal grade) 

All other 

Vitamin D; (Ergooalciferol )■'■■'• 

All other vitamins''"'^ 

All other nonbenzenoid medicinal chemicals''''^ 



pounds 



529 
2,791 

1,173 

8 

428 

31,787 



44 
117 



208 
25,194 



6,049 
104 



1,739 
23 
37 
81 
1,598 
652 
371 



1,000 
pounds 



1,000 
dollars 



155 
2,441 

902 

154 

30,654 



210 

24,3U 

64 

18 

5,860 

188 

30 



2,612 



1,663 



58 

1,605 

575 

374 

17 

7,718 



1,604 

358 

50 
1,196 
4,260 

2,430 

1,224 

12,705 



197 
5,042 



6,203 
1,183 



19,850 



2,800 

17,050 

192 

3,196 



2,407 



2,313 
367 
422 



38,831 



7,409 


5 


,348 


10,329 


6,080 


4 


,405 


8,291 


1,329 




943 


2,038 


1,711 


1 


,208 


3,017 


1,359 




986 


1,893 


352 




222 


1,124 


694 




533 


19,700 


211 




172 


6,787 


483 




361 


12,913 


1 




1 


325 


848 




628 


5,460 



1,522 



2,757 



See footnotes on following page. 



MEDICINAL CHEMICALS 



35 



Footnotes for table 13A 

■'• The data on production are those for medicinal chemicals In bulk; they do not include finished preparations, 
such as tablets, capsules, and ampoules, which are manufactured from bulk chemicals. 

^ Except for antibiotics, sales include only that part of the original production which is sold in undiluted or 
uncompounded form, including that sold in bulk and that sold in packages (tablets, ampoules, etc.). Sales of anti- 
biotics include all forms (both undiluted or uncompounded and diluted or compounded), including that sold in bulk 
and that sold in packages. 

^ Calculated from rounded figures. 

^ Since 1962, medicinal chemicals have been divided into antibiotics, benzenoid, and nonbenzenoid groups, instead 
of into cyclic and acyclic groups, as in previous reports. Totals for the cyclic and acyclic groups are shown in 
this report in order to facilitate comparison of the statistics for 196^ with those for the years prior to 1962. 

^ For statistical purposes, reported quantities of antibiotics have been converted from grams of activity or 
U.S. P. units to pounds by means of the following conversion factors: Procaine penicillin G, A53.6 million units=l 
pound; penicillin V salts, 768.9 million unlts=l pound; other penicillin salts and hygromycin B, 756 million units= 
1 pound; bacitracin, 22.7 million unlts=l pound; polymyxin B, 2,812.3 million units=l pound; all other antibiotics, 
453.6 grams of aotivlty=l pound. Statiistics for all individually publishable antibiotics are given in the following 
tabulation in terms of 'million U.S. P. units (MU), billion U.S. P. units (BU), or kilograms of activity (Kg.): 



Antibiotic 



Production 



Sales (bulk and dosage forms) 



ftiantity 



Bacitracin (MU), total 

For human or veterinary use- 
For other uses 



3,728,231 



3,217,150 



1,000 dollars 

4,235 



$1.32 



Dihydrostreptomycin, for human or veterinary 
use (Kg. ) 

Neomycin, for human or veterinary use (Kg.)-- 



Penioillin salts (BU), total 

dl-a-Phenoxyethyl penicillin (Phenethicillln) 
and potassium salt, for human or veterinary 
use 

Potassium penicillin G, for human or veterinary 

use 

Procaine penicillin G, total 

For human or veterinary use 

For other uses 

Other penicillin G salts, for human or veteri- 
nary use 

Other penicillin salts, for human or veteri- 
nary use 

Streptomycin, for all uses (Kg.) 

Tetracycline, for human or veterinary use (Kg. ) — 



150,095 
3,578,136 



41,763 
1,202,328 



119, 140 
3,098,010 

197,692 
31,798 

964,857 



1,128 
3,107 

6,306 

5,069 

86,048 



9.47 
1.00 

31.90 
159.41 

89.18 



10,723 

381,729 
618,575 
362,115 
256,460 

40,905 

150,396 

280,995 
176,269 



9,197 

312,057 
516,097 
282,738 
233,359 

23,441 

104,065 

259,378 

152,154 



3,954 

18,411 
15,863 
12,204 
3,659 

10,972 

36,848 

7,543 
54,570 



429.92 

59.00 
30.74 
43.16 
15.68 

468.07 



29.08 
358.65 



^ Includes streptomycin, for which separate statistics cannot be published by use category, because publication 
would reveal the operations of individual companies. Statistics for streptomycin are given in tenns of kilograms in 
footnote 5. 

' The term "benzenoid, " as used in this report, describes any cyclic medicinal chemical, other than antibiotics, 
whose molecule contains any one or more of the following types of rings : 6-membered carbocyclic rings with conju- 
gated double bonds, e.g., the benzene ring or the quinone ring; 6-membered heterocyclic rings with 1 hetero atom and 
conjugated double bonds, e.g., the pyridine rings; or 6-membered heterocyclic rings with 2 hetero atoms and conju- 
gated double bonds, except the pyrimidine ring, e.g., the pyrazine ring or the pyridazine ring. 

Production of all antimony, arsenic, and bismuth compounds, both benzenoid and nonbenzenoid. Including bismuth 
subgallate, amounted to 2,918,000 pounds. Production of all mercury compounds, both benzenoid and nonbenzenoid, 
amounted to 51,000 pounds. 

' Includes sales of antimony, arsenic, bismuth, and mercury compounds and of 1-hexadecylpyridinium chloride. 

^° Production of epinephrine amounted to 266 pounds; sales amounted to 258 pounds. 

■'■■'■ For statistical purposes, reported quantities of vitamins A, Bi2j ^z> and Dj have been converted from grams or 
U.S. P. units to pounds by means of the following conversion factors: Vitamin A acetate, 1.307 billion units = 1 
pound; vitamin A alcohol, 1.510 billion units=l pound; vitamin A natural esters, 1.080 billion units=l pound; vita- 
min A palmitate, 0.816 billion units=l pound; vitamin B^j' ^53.6 grams=l pound; vitamins D^ and D^, 18.14 billion 
units=l pound. Statistics for these vitamins (except vitamin D3, for which reported statistics cannot be published 
because publication would reveal the operations of individual companies) are given in the following tabulation in 
terms of grams or U.S. P. units: 



Unit of 
quantity 



Sales 



Vitamin A, total 

Palmitate, except feed grade 

All other 

Vitamin B12 

Vitamin Da 



Billion units 



Grams 

Billion units 



617,508 



172,232 
445,276 



22,398 



140,734 

329,309 

397,876 

19,674 



1.000 dollar 
19.700 



6,787 
12,913 

6,852 
325 



$41.91 



48.23 
39.21 
17.22 
16.52 



^^ Includes production of benzothiadiazine derivatives and sales of synthetic hypoglycemic agents. 

■"■ The tenn "nonbenzenoid, " as used in this report, describes any cyclic or acyclic medicinal chemical, other than 
antibiotics, whose molecule does not contain any of the types of rings described in footnote 7 above. All acyclic 
compounds and any cyclic compound whose molecule contains only one or more of the following types of rings are clas- 
sified as "nonbenzenoid": FUlly or partially reduced rings, e.g., the piperidine ring or the cyclohexadiene ring; 
rings with more or less than 6 members, e.g., the Imidazole ring or the azepine ring; heterocyclic rings with more 
than 2 hetero atoms, e.g., the triazine ring; or the pyrimidine ring. 

■■■* Includes production of hydrocortisone alcohol and acetate and "all other" hormones and sales of autonomic drugs. 



36 



SYNTHETIC ORGANIC CHEMICALS, 1964 
Flavor and Perfume Materials 



Flavor and perfume materials are organic chemicals that are used in the manufacture of 
foods, beverages, cosmetics, and soaps, and to disguise unpleasant odors in industrial prod- 
ucts. Most of them have desirable flavors or odors, and some have the quality of enhancing 
natural flavors when added to certain foods. This report includes data on materials derived 
from natural products by actual chemical processes and from coal tar; it does not include data 
on purely natural products, such as floral essences, essential oils, and other materials that are 
obtained by simple extraction or by distillation from natural vegetable and animal sources. 

The flavor and perfume materials covered in this report are grouped as either cyclic or 
acyclic materials, according to their chemical structure. Cyclic materials are further classi- 
fied as (1) benzenoid and naphthalenoid, and (2) terpenoid, heterocyclic, and alicyclic. Statistics 
on production and sales of flavor and perfume materials in 1964 are given in table 14A.^ 

Production of flavor and perfume materials in 1964 amounted to 90. 6 million pounds--22. 8 
percent more than the output of 73. 8 million pounds in 1963. Sales in 1964 amounted to 80. 
million pounds, valued at $83. 7_ million, compared with 67. million pounds, valued at $77. 4 
million, in 1963. 

Production of cyclic flavor and perfume materials in 1964 amounted to 49. 6 million 
pounds-- 19. 9 percent more than the 41. 3 million pounds reported for 1963. Sales of cyclic fla- 
vor and perfume materials in 1964 were 41. 2 million pounds, valued at $56. 6 million, compared 
with 34. 7 million pounds, valued at $51. 4 million, in 1963. The individual chemical in the cyclic 
group that was produced in the greatest volume in 1964 was methyl salicylate (3. 8 million 
pounds). Production of synthetic sweeteners, as a group, amounted to 12. 2 million pounds, rep- 
resenting an increase of 113.7 percent over the quantity produced in 1963. 

The output of acyclic flavor and perfume materials in 1964 amounted to 41.0 million 
pounds--26.4 percent more than the 32. 4 million pounds reported for 1963. By far the most im- 
portant of the acyclic materials in 1964 was monosodium glutamate, a flavor-enhancing product, 
production of which totaled 38. 6 million pounds. Sales of acyclic flavor and perfume materials 
in 1964 amounted to 38. 8 million pounds, valued at $27. 2 million, compared with 32. 3 million 
pounds, valued at $25. 9 million, in 1963. 

TABLE 14A. — Flavor and perfume materials: U.S. production and sales , 1964 

[Listed beloi? are all synthetic organic flavor and perfume materials for which any reported data on production or 
sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be piib- 
lished or where no data were reported.) Table 14-B in pt. Ill lists alphabetically all flavor and perfume materials 
for which data on production or sales were reported and identifies the manufacturer of each] 



Quantity 



Unit value^ 



Grand total 

FLAVOR AND PERFUME MATERIAI5, CYCLIC 
Total 

Benzenoid and Naphthalenoid 
Total - — 

■i-Allylveratrole (Eagenyl methyl ether) 

Anethole (p-Propenylanlsole) 

p-Anlsaldehyde (p-Methoxybenzaldehyde) 

Benzophenone^ 

Benzyl acetate 

Benzyl alcohol^ 

Benzyl cinnamate 

Benzyl ether 

Benzyl propionate 

Benzyl salicylate 

Cinnamaldehyde 

Clnnamyl alcohol 

a,oi-Dimethylphenethyl acetate 

Eogenol 

Isobutyl phenylacetate (Isobutyl a-toluate) 

Isobutyl salicylate 

Isoeugenol 

See footnotes at end of table. 



1,000 
pounds 

90,570 



80,037 



1,000 
dollars 

83,73A 



Per 
pound 



$1.05 



'^9,563 



41,235 



56,571 



21,054 



20, U7 



24,547 



1.22 



18 

1,576 

699 

264 

1,116 

3,373 

3 

103 

13 

222 

804 

209 

26 

274 

19 

46 

95 



11 

1,438 

766 

278 

1,202 

2,970 

4 

102 

12 

203 

605 

153 



34 

1,102 

1,105 

252 

506 

1,159 

13 

19 

13 

272 

411 

213 

100 

534 

19 

45 

267 



2.97 

.76 

1.44 

.91 

.42 

.39 

3.57 

.19 

1.14 

1.34 

.68 

1.39 

4.56 

2.02 

.90 

1.01 

2.88 



See also table 14B, pt. Ill, which lists these products alphabetically and Identifies the manufacturers, and table 23 in appendix A, which 

shows imports of benzenoid flavor and perfume materials during the years 1963-64. 



FLAVOR AND PERFUME MATERIALS 
TABLE lAA. — Flavor and perfume materials: U.S. production and sales , 1964 --Continued 



37 



FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued 

Bemenoid and JVopht/iaieno id- -Continued 

Isopentyl salicylate (Amyl salicylate) 

"4 ' -Methoxyacetophenone ■ 

Methyl anthranilate 

a-Wethylcinnamaldehyde 

Methyl salicylate (gynthetio wlntergreen oil) 

a-Pentyloinnamaldehyde (a -, Amylcinnamaldehyde ) 

Phenethyl isotutyrate 

Phenethyl phenylacetate (Phenethyl a-toluate) 

3- Phenyl- 1-propanol (Kbrdrocinnajiiie alcohol) 

4-Propenylveratrole (Isoeugenyl methyl ether) 

All other benzenoid and naphthalenoid materials 

Terpenoid, Heterocyclic, and Alicyclic 

Total 

Cedryl acetate 

Citral (Geranlal) 

Citronellol 

Citronellyl acetate 

Cltronellyl formate 

Coumarin 

Essential oils, chemically modified 

Geraniol 

Geranyl acetate 

Geranyl formate 

Hydrocoumarin (3,4- Dihydrocoumarin) 

H^roxycitronellal 

lonones 

Isobomyl acetate 

linalyl acetate 

Msnthol, synthetic, tech. and U.S.P 

Msnthone 

Methylionones , total 

a,p, Y, find 6, individually 

a and P , mixed 

Nerol 

Piperonal (Heliotropin) 

Rhodinol 

Sweeteners, synthetic 

Terpineols 

Terpinyl acetate 

Vetivenyl acetate 

All other terpenoid, heterocyclic, and alicyclic materials 

FLAVOR AND PERFUME MATERIAI£, ACYCLIC 

Total 

Allyl hexanoate (Allyl oaproate) 

Decanal ( Capraldehyde ) (Cio) 

Ethyl butyrate 

Ethyl hexanoate (Ethyl oaproate) 

Ethyl nonanoate (Ethyl pelargonate) 

Glutamic acid, monosodium salt (Itonosodlum glutamate) 

4-I^roxyundecanoic acid, Y-lactone (Y-Undeoalactone) 

Isopentyl butyrate (knyl butyrate) 

Laiiraldehyde (Dodecyl aldehyde) (Cia) 

All other acyclic materials 



410 

412 

14 

3,784 

433 



7,103 



28,509 



112 

218 

675 

31 

20 

1,030 

118 

845 

78 

10 

26 

556 

206 

1,373 

659 

289 



Quantity 



363 
113 



210 

10 

12,215 

3,532 

641 

19 

5,160 



41,007 



46 
13 
310 
3 
3 
38,632 
5 
57 

1,938 



1,000 
pounds 



3,738 
4A4 



7,224 



21,088 



107 

63 

448 

23 

20 

1,000 

117 

557 

68 

9 

23 

538 

161 

1,330 

407 

280 

7 

444 



1,000 
dollars 



355 
89 



252 

11 

8,658 

3,607 

677 

18 

2,256 



38,802 



47 

13 

237 



36,630 

4 

47 

18 

1,804 



263 

18 

258 

2,006 

610 

15 



29 
15,222 



32,024 



229 

248 

821 

42 

60 

2,464 

160 

852 

123 

25 

96 

2,469 

645 

528 

1,286 

983 

17 

1,929 



Unit value-"- 



1,496 
433 

40 

506 

293 

9,721 

901 

317 

1,007 

6,262 



27,163 



174 

50 

165 

3 

4 

24,843 

24 

37 

105 

1,758 



^ Calo\ila-ted from the unrounded figures. 
^ Includes some technical grade. 



38 



SYNTHETIC ORGANIC CHEMICALS, 1964 
Plastics and Resin Materials 



Plastics and resin materials are condensation or polymerization products of organic chem- 
icals containing necessary fillers, plasticizers, and extenders. At some stage in their manufac- 
ture they exist in such physical condition that they can be shaped or processed by the application 
of heat and pressure. Some types of plastics may be molded, cast, or extruded into finished or 
semifinished forms. Other types are used as adhesives, for the treatment of textiles and paper, 
and for protective coatings. Still other types of plastics materials may be processed into sheets, 
rods, and tubes, which are further manufactured into finished articles. Except for vinyl resins, 
the statistics given in the following tables are based on the total weight of the materials, exclud- 
ing liquids. Statistics for vinyl resins are given on the basis of resin content. 

Statistics on production and sales of plastics and resins in 1964 are given in table 15A' ac- 
cording to chemical composition and broad end uses. In general, this table follows the outline of 
the Tariff Commission's monthly report on the production and sales of synthetic plastics and 
resin materials (S. O. C. Series P-64). However, data are included for plastics materials which 
are not covered in the monthly report and for a number of smaller producers that do not report 

TABLE 15A. --Plastics and resin materials: U.S. production and sales, by chemical classes 

and uses, 1964 

[Quantities and values are given in terms of the total weight of the materials (dry basis). Listed below are all 
plastics and resin materials for which any reported data on production or sales may be published. (Leaders are 
used where the reported data are accepted in confidence and may not be published or where no data were reported.) 
Table 15B in pt. Ill lists all plastics and resin materials for ,which data on production or sales were reported 
and identifies the manufacturer of each] 



Kind and use 



Sales 



Quantity 



Unit value 



Grand total- 



1,000 pounds, 
dry basis ^ 

10,103,06<i 



1,000 pounds, 
8,726,721 



1.000 
dollars 

2,120,28-; 



Plastics and resin materials, benzenoid 

Plastics and resin materials, nonbenzenoid- 



THERMOSETTING RESINS 



Total- 



3,915,046 
6,188,018 



2,954,795 



3,256,105 
5,470,616 



2,343,943 



777,342 
1,342,942 



618,213 



Alkyd resins, total 

Protective coatings : 

Phthalic anhydride type, total- 
Unmodified 

Modified 

Polybasic acid type 

All other uses^ 

Sales for export 



593,627 



309,696 



80,621 



Coumarone-indene and petroleum polymer resins, total- 
Floor tile 

Rubber compounding 

All other uses 

Sales for export 

Epoxy resins : 

Unmodified, total 

Bonding and adhesives 

Protective coatings 

Reinforced plastics 

All other uses 

Sales for export 

Itidified 



524,942 

387,520 

137,422 

55,716 

12,969 



354,349 



Polyester resins,* total 

Reinforced plastics : 

Sheets, flat and corrugated- 
All other 

Surface coatings 

All other uses 

Sales for export 

Silicone resins 



91,556 

57,431 
205,362 



96,204 



8,941 
316,628 



254,618 

194,959 

59,659 

43,597 

7,905 

3,576 

328,311 



66,949 

49,300 

17,649 

9,417 

2,686 

1,569 

33,269 



80,031 

55,615 

165,071 

27,594 

95,923 
12,569 
42,328 
13,322 
16,109 
11,595 
4,936 

276,282 



3,278 
84,556 



10,981 



33,231 
168,670 

2,377 
62,314 

9,690 

10,051 



22,963 



See footnotes at end of table. 



^ See also table 15B, pt. III, which lists these products according to chemical composition, and identifies the manufacturers. 



PLASTICS AND RESIN MATERIALS 

TABLE 15A.-- Plastics and resin materials.- U.S. production and sales, by chemical classes 
and uses, 2 964 --Continued 



39 



Kind and use 



Production 



Quantity 



Unit 
value"'' 



THERmSETTING RESINS— Continued 

Phenolic and other tar acid resins, total 

Molding materials 

Bonding and adhesive resins for — 

Laminating 

Coated and bonded abrasives 

Friction materials 

Thermal insulation 

Foundry or shell molding 

Plywood 

Fibrous and granulated wood 

All other bonding and adhesive uses 

Protective coatings, immodifled and modified 

All other uses 

Sales for export 

Polyurethane and diisooyanate resins 

Rosin modifications, total 

Rosin and rosin esters, unmodified (ester gums) 
All other 

Urea and melamine resins, total 

Textile treating and coating resins 

Paper treating and coating resins 

Bonding and adhesive resins for — 

Laminating 

Plywood 

Fibrous and granulated wood 

All other bonding and adhesive uses 

Protective coatings 

All other uses (including molding) 

Sales for export 

All other thermosetting resins* 

THERMDPLASTIC RESINS 

Total - 

Cellulose plastics materials, total 

Sheets, continuous: 

Under 0.003 gage 

0.003 gage and over 

All other sheets, rods, and tubes 

Jtolding and extrusion materials 

Polyamide resins'' 

Styrene type plastics materials : 

Production and sales 

Used by reporting companies in processing 

Sales and use, total 

Jfclding 

Textile and paper treating and coating 

Bmilsion paint 

Extrusion 

All other uses 

Sales for export 

Vinyl resins (resin content basis): 
Polyvinyl acetate resins: 

Production and sales 

Used by reporting oon^ianies in processing 

Sales and use, total 

Smilsion paint 

See footnotes at end of table. 



1,000 
pounds, 

832, 5.40 



247,326 

113, S-W 
21,701 
31,584 

107,141 
53,799 
99,073 
28,546 
40,469 
32,271 
56,786 



35,634 
119,492 



74,284 
45,208 



570,274 



56,107 
48,355 

57,605 
116,607 
84,665 
17,820 
56,882 
132,233 



16,125 



7,148,269 



161,281 

17,927 

39,692 

4,609 

99,053 

75,597 

1,727,864 



282,307 



1,000 
pounds , 
dry basis^ 
685 , 169 



1,000 
dollars 
166,002 



Per 

pound 



225,351 

66,612 
18,038 
29,376 
47,992 
53,551 
89,683 
27,806 
36,591 
23,427 
50,436 
16,306 

31,066 



71,437 
43,556 



473,827 



18,100 
22,521 



13,401 
9,120 



49,079 
33,801 

37,683 
100,407 
72,267 
16,068 
35,735 
111,238 
17,549 

13,689 



6,382,778 



5,140 



1,502,071 



156,991 

17,739 

38,207 

6,222 

94,823 

58,408 

1,559,534 
128,265 

1,687,799 
843,117 
128,698 
39,704 
229,585 
282,399 
164,296 



228,233 
51,416 

279,649 
96,760 



107,170 



54,115 
333,927 



66,497 



40 SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 15 A. --Plastics and resin materials: U.S. production and sales , by chemical classes 
and uses, 1964 — Continued 



Kind and use 



- Continued 



THERMOPLASTIC RESINS--Continued 

Vinyl resins (resin content basis) — Continued 
Polyvinyl acetate resins — Continued 

Used by reporting companies in processing 
Sales and use--Continued 

Adhesives 

Bonding and sizing 

All other uses 

Sales for export 

Polyvinyl chloride and copolymer resins : 

Production and sales 

Used by reporting companies in processing 

Sales and use, total 

Calendering : 

Film, under 6 mils 

Sheet, 6 mils and over 

Flooring 

Coating, bonding, and adhesives : 

Paper and textile coating (including calendering 

Flooring 

Extrusion: 

Wire and cable 

Garden hose 

All other extrusions 

Molding : 

Records 

Sliish and rotational molding 

All other moldings 

All other uses 

Sales for export 

All other vinyl resins : 

Production and sales 

Used by reporting companies in processing 

Sales and use, total 

Polyolef in plastics materials : 

Polyethylene, density C.g-iO and below: 

Production and sales 

Used by reporting companies in processing 

Sales and use, total 

Injection molding 

Blow molding 

Extrusions : 

Film and sheet 

Wire and cable coating 

Extrusion coating on paper and other substrates- 
Pipe 

All other extrusions 

All other uses 

Sales for export 

Polyethylene, density over C.g^VO: 

Production and sales 

Used by reporting companies in processing 

Sales and use, total 

Injection molding 

Blow molding 

Extrusions : 

Film and sheet 

Wire and cable coating 

Pipe 

All other extrusions (including extrusion coating 

and filament) 

All other uses 

Sales for export 



1,636,891 



Quantity 



147,629 



1,955,095 



658,320 



dry 

basis' 

100,868 

17,927 

60,505 

3,589 

1,373,740 

273,569 

1,647,309 

79,449 
248,993 
243,657 

155,773 
62,972 

195, 4S5 

13,806 

190,095 

74,703 
39,185 
24,293 
249,026 
69,872 

96,836 
44,427 
141,263 



1,930,267 
170,387 

2,100,654 

257,436 

38,585 

745,365 
194,317 
255,288 
25,172 
14,541 
198,867 
371,083 

550,472 
55,449 
605,921 
100,144 
238,870 

24,959 
20,294 
21,417 

21,524 
114,890 
63,823 



1.000 
dollars 



240,056 



Unit value 



pound 



60,857 



320,752 



113,948 



See footnotes at end of table. 



PLASTICS AND RESIN MATERIALS 

TABLE 15A.— Plastics and resin materials.- U.S. production and sales, by chemical classes 
and uses, 7554 --Continued 



Kind and use 



Quantity 



Unit value-"- 



THERMDPLASTIC RESINS--Continued 

Polyolefin plastics materials — Continued 
Polypropylene : 

Production and sales 

Used by reporting companies in processing- 
Sales and use, total 

Molding 

Extrusion 

All other uses (including export) 

All other thermoplastic resins'"-'^ 



dry ba 



dry 



270, 176 



233,109 



unds. 


1,000 


basis' 


dollars 


225,712 


5^,823 


35,156 




260,868 




108, "iSS 




113,5^3 




38,870 




202,585 


1-49,926 



pourid 



.74 



■"- Calculated from rounded figures. 

^ For the purpose of this report, "dry basis" is defined as the total weight of the material, including resin, 
plasticizers, fillers, extenders, colors and stabilizers, and excluding water, solvents, and other liquid diluents. 
^ Includes saturated polyesters for urethanes. 

* The term "polyester resins" includes unsaturated aliyds oopolymerized with a monomer such as styrene, and 
polyallyl resins such as diallyl phthalate and allyl diglycol carbonate. 

' Includes 418,314 thousand pounds of urea- formaldehyde type, and 151,960 thousand pounds of melamine-formalde- 
hyde type. 

^ Includes data for acetone-formaldehyde resins, styrene-alkyd polyesters, toluenesulfonamide resins, and other 
thermosetting resins, which were produced in small quantities. 

'' Includes both nylon and non-nylon types. 

* Includes straight polystyrene, 592,151 thousand pounds; rubber modified polystyrene, 683,850 thousand pounds; 
styrene-butadiene copolymers, 188,161 thousand pounds; and all other, including ABS and SAN, 263,702 thousand 
pounds . 

' Includes 32,382 thousand pounds of polyvinyl alcohol. 

■'-° Includes data for acrylic, fluorocarbon, polycarbonate, polyoxymethylene, polyterpene, and other thermoplastic 
resins. 



monthly. The monthly data for 1964, moreover, -were returned to the reporting companies for 
verification or correction. In consequence, many of the figures in the following table are revised 
from those sho-wn in the monthly release of March 23, 1965, which contained yearend cumulative 
totals for 1964. The figures in the thermoplastics section of the table under "Used by reporting 
companies in processing" represent captive use of the materials. The quantities reported under 
"Sales and use" in this section include data for captive consumption, and for outside sales as 
defined in the introduction to this volume. 

In 1964, total U.S. production of synthetic plastics and resin materials, including cellu- 
losics, amounted to 10, 103 million pounds, or 12. 6 percent more than the 8, 968 million pounds 
reported for 1963. Sales of synthetic plastics and resin materials in 1964 amounted to 8, 727 mil- 
lion pounds, valued at $2, 120 million. Production of benzenoid plastics and resin materials in 
1964 amounted to 3, 915 million pounds, and that of nonbenzenoid materials, to 6, 188 million 
pounds. These figures connpare with production in 1963 of 3, 489 million pounds, and 5, 479 mil- 
lion pounds, respectively. Production of all thermosetting resins in 1964 was 2, 955 million 
pounds, and that of thermoplastic resins was 7, 148 million pounds. 

In 1964, polyethylene, polystyrene, and polyvinyl chloride resins were the materials pro- 
duced in the largest volume. The total output of high-density and low-density polyethylene resins 
in 1964 amounted to 2, 613 million pounds, compared with 2, 270 nmillion pounds in 1963. Sales of 
polyethylene resins in 1964 were 2,481 million pounds, valued at $435 million. Production of 
styrene type plastics materials in 1964 was 1, 728 million pounds, compared with 1, 494 million 
pounds in 1963. Sales of such materials in 1964 were 1, 560 million pounds, valued at $334 mil- 
lion. The output of polyvinyl chloride and copolymer resins in 1964 amounted to 1, 637 million 
pounds, compared with 1, 386 million pounds in 1963. Sales of polyvinyl chloride resins in 1964 
totaled 1, 374 million pounds, valued at $240 million. Other synthetic plastics and resin materials 
produced in 1964 in large volume were phenolic and other tar acid resins (833 million pounds), 
alkyd resins (594 million pounds), urea and melamine resins (570 million pounds), coumarone- 
indene and petroleum polymer resins (354 million pounds), polyester resins (317 million pounds), 
and polyvinyl acetate resins (282 million pounds). 



42 



SYNTHETIC ORGANIC CHEMICALS, '964 
Rubber-Processing Chemicals 



Rubber-processing chemicals are organic compounds that are added to natural and synthetic 
rubbers to give them qualities necessary for their conversion into finished rubber goods. In this 
report, statistics are given for cyclic and acyclic compounds, by use--such as accelerators, 
antioxidants, and peptizers. Statistics on production and sales of rubber-processing chemicals 
in 1964 are given in table 16A.^ 

Production of rubber-processing chemicals as a group in 1964 amounted to 261 million 
pounds, or 11.5 percent more than the 234 million pounds reported for 1963. The larger total 
output of rubber-processing chemicals in 1964 is attributable principally to increased produc- 
tion of antioxidants and thiazole accelerators. Sales of rubber-processing chemicals in 1964 
amounted to 184 million pounds, valued at $123 million, compared with 177 naillion pounds, 
valued at $119 million, in 1963. 

TABLE 16A. — Rubber-processing chemicals: U.S. production and sales , 1964 

[Listed below are all rubber-processing chemicals for which any reported data on production or sales may be pub- 
lished. (Leaders are used where the reported data are accepted in confidence and may not be published "or where 
no data were reported. ) Table 16B in pt. Ill lists separately all rubber-processing chemicals for which data 
on production or sales were reported and identifies the manufacturer of each] 



Quantity 



Unit 
value ^ 



Grand total 

RUBBER- PROCESSING CHBJICAIS, CYCLIC 

Total - 

Accelerators, total 

Aldehyde-amines 

Dithiooarbamic acid derivatives 

Thiazole derivatives, total 

N-Cyolohexyl-2-benzothlazolesulfenamide-- 

2,2'-Dithlobis{benzothiazole) 

2-Mercaptobenzothiazole 

All other^ 

All other accelerators 

Amino and hydroxy compounds, total-' 

Amino compounds, total 

N, N'-Diphenyl-p-phenylenediamine 

All other 

Itydroxy compounds, total 

Phenol, alkylated 

All other 

N-Nitrosodiphenylamine -— 

Peptizers 

All other cyclic rubber-processing chemicals* — 

RUBBER- PROCESSING CHEMICALS, ACYCLIC 

Total 

Accelerators, total 

Dithiooarbamic acid derivatives, total^ 

Wbutyldithiooarbamlo acid, sodium salt 

Dibutyldithiocarbamic acid, zinc salt 

Diethyldithiocarbamic acid, zinc salt 

Dimethyldithiocarbamic acid, potassium salt- 

Dimethyldithiocarbamic acid, sodium salt 

Dimethyldithiocarbamic acid, zinc salt 

All other 



pounds 
260,556 



222,4.61 



87,295 



1,983 

270 

75,015 

10,100 

21,045 

7,972 
35,898 
10,027 

105,357 



85,406 
1,609 

83,797 

19,951 
9,312 

10,639 

3,089 

5,003 

21,717 



38,095 



25,255 



13,003 
974 

1,424 

1,058 
298 

6,618 
955 

1,676 



184,227 



53,317 



1,382 

204 

42,220 

5,652 
10,316 

5,018 
21,234 

9,511 

82,382 



67,950 
1,587 
66,363 
14,432 
4,904 
9,528 

2,164 
4,631 
19,166 



22,567 



13,431 



7,277 

1,119 
704 

'2,484 

903 

2,067 



123,027 



108,656 



31,493 



1,463 
333 

22,222 
3,564 
5,247 
1,937 

11,474 
7,475 

59,984 



46,707 
1,406 

45,301 

13,277 
2,623 

10,654 

1,173 
3,101 
12,905 



14,371 



10,369 



5,802 

1,249 
570 

947 

757 

2,279 



.67 



.59 
1.06 
1.63 
.53 
.63 
.51 
.39 
.54 



.73 
.69 



.92 
.53 
L.12 



.64- 

.77 



1.12 
.81 

.38 

.84 

1.10 



See footnotes at end of table. 



'See also table 16B, pt. Ill, which lists these products alphabetically and identifies the manufacturers. 



ELASTOMERS (SYNTHETIC RUBBERS) 
TABLE 16A. — Rubber-processing chemicals: U.S. production and sales, 1964 — Continued 



43 



Production 



ijiantity 



Unit 
value ■"■ 



RUBBER-PROCESSING CHEMICALS, ACYCLIC— Continued 

Accelerators — Continued 

Thiurams, total^ 

Bis (dime thy lthiocartiainoyl)disulfide 

Bis(dimethylthlocarbaiiioyl)sulfide 

All other 

All other accelerators 



1,000 
pounds 



1,000 
pounds 



pound 



Dodeoyl mercaptans 

All other acyclic rubber-processing chemicals'' 



11,896 



11,896 
356 



10,2^9 
2,591 



5,934 

4,132 

1,071 

731 

220 

8,129 
1,007 



4,337 

2,651 

1,141 

545 

230 

3,489 
513 



1.07 

.75 

1.05 



""" Calculated from rounded figures. 

^ Includes small quantities produced and sold for uses other than rubber processing. 

^ Data on production and sales of aldehyde and acetone amine antioxidants are included below in "All other cyclic 
rubber-processing chemicals . " 

* Includes aldehyde and acetone amines, blowing agents, inhibitors, modifiers, stabilizers, and taekifiers. 

^ Data on dithiocarbamates Included in this table are for materials used chiefly in the processing of natural and 
synthetic rubbers. Data on dithiocarbamates which are used chiefly as fungicides are reported in table 20A "Pesti- 
cides and Other Organic Agricultural Chemicals." 

^ Includes data for small amounts of tetramethylthiuram sulfides for uses other than in the processing of natural 
and synthetic rubbers. 

' Includes blowing agents, peptizers, modifiers, and conditioning and lubricating agents. 



The output of cyclic rubber-processing chemicals in 1964 amounted to 222 million pounds, or 
11. 6 percent more than the 199 million pounds reported for 1963. Sales in 1964 were 162 million 
pounds, valued at $109 million, compared with 153 million pounds, valued at $102 million, in 1963. 
Of the total output of cyclic rubber-processing chemicals in 1964, accelerators accounted for 39.2 
percent and amino and hydroxy antioxidants, for 47. 4 percent. Production of amino and hydroxy 
antioxidants, which amounted to 105.4 million pounds in 1964, included 85.4 million pounds of 
amino compounds and 20. nnillion pounds of hydroxy compounds. In 1963 the output of amino 
antioxidants amounted to 79. 2 million pounds and that of hydroxy antioxidants, to 17. million 
pounds. Sales of amino antioxidants in 1964 were 68. million pounds, valued at $46. 7 million; 
sales of hydroxy antioxidants were 14.4 million pounds, valued at $13. 3 million. 

Production of acyclic rubber-processing chemicals in 1964 amounted to 38. 1 million pounds, 
compared with the 34. 4 million pounds reported for 1963. Sales in 1964 totaled 22. 6 million 
pounds, valued at $14. 4 million, compared with 24. 4 million pounds, valued at $16. 9 million, in 

1963. Accelerators, principally dithiocarbamic acid derivatives and tetramethylthiuram sulfides, 
accounted for 66. 3 percent of the output of acyclic rubber-processing chemicals in 1964. Dodecyl 
mercaptans, together with blowing agents, peptizers, modifiers, and lubricating and conditioning 
agents, accounted for the remainder of the output in the acyclic group. 

Elastomers (Synthetic Rubbers) 

The synthetic rubber industry in the United States continued to operate at a high level of 
capacity in 1964. The styrene-butadiene, or S-type, rubber is a general- purpose material used 
in the manufacture of tires and other rubber goods, and is the most important type of synthetic 
rubber, in terms of quantity produced. Several other types of synthetic rubbers are also pro- 
duced in large volume; among them are the polybutadiene-acrylonitrile type, or N-type, the 
polybutadiene-isoprene type, or Butyl-type, neoprene, and stereo elastomers. 

The total output of all types of elastomers in the United States in 1964 amounted to 3,421 
million pounds-- somewhat more than the 3, 185 million pounds reported for 1963. Sales of 
elastomers covered in this report amounted to 2, 958 million pounds, valued at $810 million, in 

1964, compared with 2, 836 million pounds, valued at $767 million, in 1963. Statistics on the 
production and sales of elastomers are given in table 17 A. 5 



See also table 173, pt. ni, which lists these products alphabetically and identifies the manufacturers. 



SYNTHETIC ORGANIC CHEMICALS, 1964 




polyurethane type elastomers in 1964 amounted to 7. 3 nnillion pounds. 

TABLE 17A. --Elastomers (synthetic rubbers):'' U.S. production and sales, 1964 

[Listed below are all elastomers (synthetic rubbers) for which reported data on production or sales may be pub- 
lished. (Leaders are used where the reported data are accepted in confidence and may not be published or where no 
data were reported.) Table 17B in pt. Ill lists alphabetically all elastomers for which data on production or 
sales were reported and identifies the manufacturer of each] 



Quantity 



Unit value^ 



Grand total 

ELASTOMERS, CYCLIC 
Total 

Polybutadiene-styrene type (S-type) 

Polybutadiene-styrene-vinylpyridine type- 
Polyurethane type 

ELASTOMERS, ACYCLIC 

Total 

Polybutadiene-acrylonitrile type (N-type) 

Polychloroprene type (Neoprene) 

Poljrisobutylene-isoprene type (Butyl) 

Silicone elastomers 

Stereo elastomers 

All other acyclic elastomers^ 



Sj^i^ais 



1,000 
pounds^ 
2,957,58^ 



1,000 
dollars 
809, 902 



2,332,436 



1,961,181 



450,913 



2,306,065 
19,075 
7,296 



1,088,782 



1,944,595 
10,520 
6,066 



996,403 



437, 616 
6,868 
6,429 



358,989 



117,443 
316,040 
221,558 
8,276 
364,826 
60,639 



102,439 



6,286 
285,230 
602,448 



49,161 



23,714 

65,430 

220,684 



.23 



.36 
.48 



3.77 
.23 
.37 



"'" The term "elastomers" is defined as substances in bale, crumb, powder, latex, and other crude forms which can be 
vulcanized or similarly processed into materials that can be stretched at 68° F. to at least twice their original 
length and, after having been so stretched and the stress removed, will return with force to approximately their 
original length. 

^ Calculated from rounded figures. 

^ Elastomer-content basis. 

* Partly estimated. 

' Includes data for the production and sales of polyalkalene sulfide, and polylsobutylene elastomers, and natiiral 
rubber modifications; and for sales of neoprene and Butyl elastomers. 

Note. — Statistics on the production of S-type, N-type, Butyl, neoprene, and stereo elastomers were compiled in 
cooperation with the U.S. Bureau of the Census. 

The output of acyclic elastomers, including N-type, neoprene, Butyl, silicone, and stereo 
elastomers, amounted to 1,089 million pounds in 1964, compared with the 1,011 million pounds 
reported for 1963. Sales of these elastomers amounted to 996 million pounds, valued at $359 
million, in 1964, compared with 911 million pounds, valued at $332 million, in 1963. The out- 
put of silicone elastomers in 1964 amounted to 8. 3 million pounds, and that of stereo elas- 
tomers, to 365 million pounds. 

Plasticizers 



Plasticizers are organic chemicals that are added to synthetic plastics and resin materials 
to (1) improve workability during fabrication, (2) extend or modify the natural properties of these 
resins, or (3) develop new improved properties not present in the original resins. Plasticizers 
reduce the viscosity of the resins and make it easier to shape and form them at high tempera- 
tures and pressures. They also impart flexibility and other desirable properties to the finished 
product. Statistics on production and sales of plasticizers are given in table 18A."''° 



^^ See also table 18B, pt. III, which lists these products alphabetically and identifies the manufacturers. 



PIASTICIZERS 45 

TABLE 18A. --Plasticizers:^ U.S. production and sales. 1964 

[Listed below are all plastloizers for which reported data may be published. (Leaders are used where the reported 
data are accepted in confidence and may not be published or where no data were reported.) Table 18B in pt. Ill 
lists all plasticizers for which data on production or sales were reported and identifies the manufacturer of 
each] 



Quantity 



Grand total 

PLASTICIZERS, CYCLIC 

Total— 

Phosphoric acid esters : 

Cresyl diphenyl phosphate^ 

Tricresyl phosphate-' 

Triphenyl phosphate 

Phthalic anhydride esters, total 

Butyl octyl phthalate 

Di butyl phthalate 

Dicyolohexyl phthalate 

Diethyl phthalate 

Dihexyl phthalate 

Diisodecyl phthalate 

Di(2-methoxyethyl) phthalate 

Dimethyl phthalate 

Diootyl phthalates, total 

Di(2-ethylhexyl) phthalate 

Diiso-octyl and mixed dioctyl phthalates 

Ditridecyl phthalate 

Octyl deoyl phthalates 

All other phthalic anhydride esters 

Trimellitic acid esters 

All other cyclic plasticizers'^ 

PLASTICIZERS, ACYCLIC' 

Total 

Adipic acid esters, total 

Di(2-(2-butoxyethoxy) ethyl) adipate 

Di(2-ethylhexyl) adipate 

Diisobutyl adipate 

Diisodecyl adipate 

Diiso-octyl adipate 

Octyl decyl adipate 

All other 

Azelaic acid esters 

Complex linear polyesters and polymeric plasticizers 

Epoxidized esters, total 

Epoxidized soya oils 

Octyl epoxy tallates 

All other 

Glycerol monoricinoleate 

Isopropyl myristate 

Isopropyl palmltate 



1,000 
pounds 
951,408 



717,624 



16,061 

32,419 

8,982 

601,403 



12,422 

18,228 

6,730 

15,058 

713 

77,963 

8,939 

4,253 

323,619 

188,761 

134,858 

11,528 

21,475 

100,475 

1,140 
57,619 



233,784 



36,143 



957 
6,053 

730 

8,051 

5,862 

10,280 

4,210 

13,359 
43,272 

58,020 



38,455 

17,007 
2,558 

423 
2,682 
1,316 



1.000 
pounds 
904,887 



1.000 
dollars 
187,468 



689,647 



119,565 



L3,855 

30,123 

1,970 



16,595 
14,902 

9,975 

776 

73,521 

5,964 

3,978 

326,626 

196,105 

130,521 

11,072 

24,185 

102,512 

1,335 
52,258 



215,240 



33,040 



913 
6,117 

786 
6,974 

10,156 
8,094 

12,972 
40,626 

62,993 



43,522 
16,833 
2,638 

170 
2,598 
1,377 



3,488 

8,027 

708 

91,775 



2,365 
2,889 

1,936 

143 

10,934 

1,143 

841 

45,907 

27,847 

18,060 

2,387 

4,164 
19,066 

579 
14,988 



67,903 



8,527 



360 
1,494 

244 
2,067 

2,700 
1,662 

3,966 
16,316 

15,346 



10,265 
4,004 
1,077 



904 
448 



See footnotes at end of table. 



46 SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 18A. --Plasticizers-' U.S. production and sales, i 964 --Continued 



Chemical 



Production 



Quantity 



Unit 
value ^ 



PLASTICIZERS, ACYCLIC— Continued 



Oleic acid esters, total 

Butyl oleate 

Glycerol trioleate (Triolein) 

Isopropyl oleate 

tethyl oleate 

n-Propyl oleate 

All other 



1,000 



1,000 
8,046 



1,000 
dollars 

1,947 



Phosphoric acid esters 

Sebacic acid esters: 

Dibutyl sebacate 

Di(2-ethylhex3rl) sebaoate- 



Stearic acid esters, total- 

n-Butyl stearate 

All other 



2,769 
3,767 

281 
1,708 

801 
2,121 

11,731 

4,521 
7,547 

7,399 



1,792 
2,506 



633 

3,115 



8,211 



2,759 
7,703 



6,957 



All other acyclic plasticizers" 



3,019 
4,380 



35,924 



2,823 

4,134 



27,788 



~3ST 
521 



116 

927 



1,693 
4,034 



1,718 



1,038 
9,703 



■'■ Does not include data for clearly defined extenders or secondary plasticizers. 

^ Calculated from rounded figures. 

^ Includes material produced for use as motor-fuel additive. 

* Includes data for toluenesulfonamides, tetrahydrofurfuryl oleate, and other cyclic plasticizers. 
' Dibutyl maleate is now published in table 22A, "Miscellaneous Chemicals." 

* Includes data for citric and aoetylcitric, lauric, myristic, palmitic, ricinoleic, sebacic, and tartaric acid 
esters, glycerol and glycol esters of certain fatty acids, glycerol tri propionate, and other acyclic plasticizers. 

Total U.S. production of plasticizers in 1964 amounted to 951 million pounds-- representing 
an increase of 14.0 percent over the output of 835 million pounds reported for 1963. Sales in 
1964 of the plasticizers covered by this report amounted to 905 million pounds, valued at $187 
million, compared with 750 million pounds, valued at $168 million, in 1963. 

Production of cyclic plasticizers in 1964, which consisted chiefly of the esters of phthalic 
anhydride and phosphoric acid, amounted to 718 million pounds, compared with 622 million 
pounds in 1963. Sales of cyclic plasticizers in 1964 amounted to 690 million pounds, valued at 
$120 million, compared with 558 million pounds, valued at $103 million, in the previous year. 

Production of acyclic plasticizers in 1964 amounted to 234 million pounds, compared with 
213 million pounds in 1963. Sales of acyclic plasticizers in 1964 amounted to 215 million pounds, 
valued at $68 million, compared with 192 million pounds, valued at $65 million, in 1963. Pro- 
duction of complex linear polyesters in 1964 amounted to 43 million pounds, and that of epoxi- 
dized esters, to 58 million pounds. Other products included in the acyclic class are the esters 
of adipic, azelaic, oleic, sebacic, and stearic acids. 



Surface-Active Agents 

The surface-active agents covered in this report include synthetic organic detergents and 
wetting, emulsifying, and dispersing agents that function in either aqueous or nonaqueous sys- 
tems. Soaps, waxes, and plasticizers are not included. The data are reported in terms of 100- 
percent organic, surface-active ingredients, and thus exclude all inorganic salts, water, and 
other diluents. Originally developed as soap substitutes for the textile industry, surface-active 
agents have proved valuable in many other applications. A major part of the output of surface- 
active agents is consumed in the form of packaged household and industrial detergents. The 
rennainder is used as wetting, dispersing, penetrating, and emulsifying agents in the processing 
of textiles and leather, in ore flotation and oil-drilling operations, and in the manufacture of 
paints, agricultural sprays, lubricants, cosmetics, foods, pharmaceuticals, and many other 
products. 

Statistics on U.S. production and sales of surface- active agents in 1964 are given in table 
igA.-"-^ Total production of surface-active agents in 1964 amounted to 2, 119 million pounds--?. 
percent more than the 1, 981 million pounds produced in 1963, and 8. 7 percent more than the 
1, 949 million pounds produced in 1962. Sales in 1964 totaled 1, 900 million pounds, valued at 



11 See also table 19B, pt. Ill, which lists these products alphabetically and identifies the manufacturers. 



SURFACE-ACTIVE AGENTS 



47 



$350 million, compared with 1,790 million pounds, valued at $325 million, in 1963, and 1,758 
million pounds, valued at $317 million, in 1962. Sales in 1964 were thus 6.2 percent larger 
than in 1963 and 8. percent larger than in 1962 in terms of quantity, and 7. 7 percent larger 
than in 1963 and 10. 4 percent larger than in 1962 in terms of value. 

Production of anionic materials in 1964 amounted to 1,434 million pounds, or 67. 7 percent 
of total production; sales of anionic materials were 1, 365 million pounds, valued at $196 mil- 
lion. Production of those surface- active agents which are generally considered nonionic amounted 
to 581 million pounds, or 27.4 percent of the total; sales were 434 million pounds, valued at 
$108 million. Production of cationic materials amounted to 98 million pounds, or 4. 6 percent of 
the total; sales totaled 96 million pounds, valued at $43 million. Production of amphoteric mate- 
rials amounted to 4, 6 million pounds, or approximately 0. 2 percent of the total; sales totaled 
4. 5 million pounds, valued at $2. 8 million. 

TABLE 19 A.— Surface -active agents: U.S. production and sales, 1964 



[Listed below are all surface-active agents for which reported data on production or sales may be published. 
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data 
were reported.) Table 19B in pt. Ill lists all surface-active agents for which data on production or sales were 
reported and identifies the manufacturer of each] 



Production''' 



Quantity-'' 



Unit 
value ^ 



Grand total 

Amphoteric 

Anionic 

Cationic 

Nonionic 

BENZENOID SURFACE-ACTIVE AGENTS 

Total 

Not Sulfated or Sulfonated 

Total 

Amides, amines, and quaternary ammonium salts, total 

Benzyl( coconut oil alkyl)dimethylammonium chloride 

Benzyldimethyl(mixed aliyl) ammonium chloride 

Benzyldimethylootadeoylammonivun chloride 

Benzyldodecyldimethylammonium chloride 

(3,4— Dichlorobenzyl)dodeoyldimethylammonlum chloride 

(Dodecylbenzyl)trimethylammonium chloride 

Heterocyclic compounds 

Oxygen- containing' compounds 

All other 

Carboxylic acid esters and ethers, total 

Dodecylphenol, ethoxylated 

Iso-octylphenol, ethoxylated 

Nonylphenol, ethoxylated 

Phenol, ethoxylated 

Other carboxylic acid esters and ethers 

Phosphoric and polyphosphoric acid esters and salts, 'to'tal 

Nonyl and dinonylphenol, ethoxylated and phosphated 

All ether 

Sulfated and Sulfonated 
Total 

Alkylphenols, ethoxylated and sulfated, total 

Nonylphenol, ethoxylated and sulfated 

All other 

See footnotes at end of table. 



2,118,688 



<i,562 

1,434,399 

98,348 

581,379 

1,347,809 



273,786 



8,018 



3,548 
309 
789 
31 
158 
696 
706 

1,723 

263,545 



52,483 

1,676 

132,778 

4,027 

72,581 

2,223 



2,045 
178 



1,074,023 



40,579 



20,213 
20,366 



1,899,930 



4,536 

1,365,424 

95,518 

434,452 

1,245,176 



209,146 



7,602 



56 

3,468 

286 

747 

30 

149 

475 

694 

1,697 

199,570 



22,680 

114,822 

2,774 

59,294 

1,974 



1,799 
175 



1,036,030 



20,079 



i,000 
dollars 

350,142 



2,755 
196,092 
43,228 
108,067 

165,132 



46,006 



7,217 



47 
3,166 
260 
651 
37 
113 
563 
923 
1,457 

38,062 



6,394 

18, 198 

620 

12,850 



662 
65 



119,126 



4,253 



pound 



.61 
.14 
.45 
.25 



.22 



.95 

.84 

.91 

.91 

.87 

1.23 

.76 

1.19 

1.33 

.86 

.19 
.28 



.16 
.22 
.22 



.37 
.37 
.37 



SYNTHETIC ORGANIC CHEMICALS, 1964 
TABLE 19A.--Surface-active agents: U.S. production and sales , i564--Continued 



Production^ 



Sales 



Quantity^ 



BENZENOID SURFACE-ACTIVE AGENTS- -Continued 
Sulfated and Sulfonated — Continued 

Benzenesulfonates, total 

Benzene-, toluene-, and xylenesulfonates : 

Toluenesulfonio acid, sodium salt 

}fylenesulfonio acid, anmonium salt 

i^lene sulfonic acid, potassium salt 

^lenesulfonic acid, sodium salt 

Branched chain dodeeyl- and tridecylbenzenesulfonates, 

total 

Dodecylhenzenesulfonic acid-- 

Dodecylbenzenesulfonlo acid, ammonium salt 

Dodecylbenzenesulfonic acid, calcium salt 

Dodecylbenzenesulfonic acid, diethanolamine salt 

Dodecylbenzenesulfonic acid, isopropylamine salt 

Dodecylbenzenesulfonic acid, (mixed alkyl) -amine salt- 

Dodecylbenzenesulfonlc acid, sodium salt 

Dodecylbenzenesulfonic aoid, triethanolamine salt 

Tridecylbenzenesulfonic acid, sodium salt 

All other 

Straight chain dodeeyl- and tridecylbenzenesulfonates : 

Dodecylbenzenesulfonic acid 

Dodecylbenzenesulfonic aoid, sodium salt 

Dodecylbenzenesulfonic aoid, triethanolamine salt 

All other benzenesulfonates-' 

lignosulfonates, total 

lignosulfonio acid, calcium salt 

All other 

Naphthalenesulfonates, total 

Diisopropylnaphthalenesulfonio aoid 

Isopropylnaphthalenesulfonio aoid 

All other 

Other benzenoid surface -active agents, sulfated and 

sulfonated 

NONEENZENOID SURFACE-ACTIVE AGENTS 

Total 

Not Sulfated or Sulfonated 

Total 

Amides, amines, and quaternary ammonium salts, total 

Acyclic quaternary ammonium salts, total 

Bis(hydrogenated tallow alkyl) dimethylaramonium 

chloride ■ 

Hexadeoyltrimethylammonium salts 

All other 

Amine acetates, total 

( i^drogenated tallow aliyl) amine acetate 

All other 

Amine salts, anionic, total 

Oleic acid, triethanolamine salt 

All other 

Amines, alkoxylated, total 

(Mixed alkyl)amine, ethoxylated 

(Tallow alkyl)amine, ethoxylated 

All other 

Fatty acid - alianolamine condensates, total 

Diethanolamine condensates, total 

Castor oil acids - diethanolamine condensate 



1,000 
pounds 
590, 670 



9,253 
I8,<i59 

1,4.98 
23,612 

445,453 

61,219 

8,177 

9,932 

184 

3,907 

388 

320,020 

3,204 

30,911 

7,511 

3,834 

48,886 

127 

39,548 

426,788 



325,574 
101,214 



9,634 



333 

427 

8,874 



6,352 



770,879 



461, 149 



162,816 



17,610 

13,223 

410 

3,977 

1,585 

444 

1,141 

694 

74 

620 

11, 852 

2,383 

691 

8,778 

71,293 

54,499 



1,000 
pounds 
575, 756 



9,209 
18,549 

20,970 

436,787 
59,844 

5,501 

187 

3,611 

349 

324,658 

3,176 

27, 884 

11,577 

1,213 
49,079 

39,949 

412,943 



311,843 
101, 100 



5,521 



223 
5,298 

* 21,731 



366,605 



156,104 



20,048 

15,798 

434 

3,816 

1,865 

1,865 

559 

17 

542 

11,421 

2,157 

658 

8,606 

67,340 

51,102 

12 



1,000 
dollars 
90,497 



721 
1,441 

2,042 

73,655 
14,295 

1,719 

72 

1,122 

102 

47,867 

939 

5,278 

2,261 

267 
5,517 

6,854 

14,762 



10,130 
4,632 



2,289 



120 
2,169 



* 7,325 



185,010 



120, 802 



61,992 



6,746 

3,909 
440 

2,397 
587 

587 

344 

8 

336 

4,925 

982 

550 

3,393 

19,846 

15,366 

7 



See footnotes at end of table. 



SURFACE-ACTIVE AGENTS 
TABLE \QA.- -Surface -active agents: U.S. production and sales , i 964 --Continued 



49 



Production""" 



Quantity"" 



NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 

Not Sulfated or Sal fonated— Continued 

i^jnides, ajidnes, and quaternary ammonium salts — Continued 
Fatty aoid - alkanolamine condensates — Continued 
Diethanolamine condensates — Continued 

Coconut oil acids - diethanolamine condensates : 

(Amine/acid ratio=2/l) 

(Amine/aoid ratio=l/l) 

Laurlo acid - diethanolamine condensate 

Oleic acid - diethanolamine condensates : 

(Amine/acid ratio=2/l) 

(Amine/acid ratio=l/l) 

Stearic acid - diethanolamine condensate 

Tall oil acids - diethanolamine condensate 

Other diethanolamine condensates 

Other alianolamine condensates, total 

Laurie aoid - isopropanolamine condensate 

Stearic acid - ethanolamine condensates 

All other 

Fatty acid - polyamine condensates, total 

Oleic acid - dlethylenetriamlne condensate 

Stearic aoid - dlethylenetriamlne condensate 

All other 

Fatty acid - polyamine condensates, ethoxylated, total — 
Oleic aoid - ethylenedlamine condensate, monoethoxy- 

lated 

Stearic acid - ethylenedlamine condensate, mono- 

ethoxylated 

All other 

Heterocyclic compounds, total 

2-Heptadeoyl-l-(2-hydroxyethyl)-2-imldazoline 

Hosinpolyamldoimldazollne 

All other 

N-Substituted amino acids and polypeptides 

Other amides, amines, and quaternary ammonium salts, 

total 

N-(Coconut oil alkyl)-l,3-propylenediamine 

N-(9-0ctadecenyl)-l,3-propylenediamlne 

N- (Tallow alkyl)-l,3-propylenediamine 

All other 

Carboxylic acid esters, total 

Ethylene glycol and dlethylene glycol esters, total 

methylene glycol dl- and sesquistearate 

Dlethylene glycol monolaurate 

methylene glycol mono-oleate 

methylene glycol monostearate 

Ethylene glycol distearate 

Ethylene glycol monostearate 

All other 

Glycerol esters, total 

Complex glycerol esters' 

Glycerol esters of chemically defined fatty acids, 

total 

Glycerol mono-oleate 

Glycerol monostearate 

All other 

Glycerol esters of mixed fatty acids, total 

Glycerol monoester of coconut oil acids 

Glycerol monoester of cottonseed oil acids 

All other 

Polyethylene glycol esters, total 

Polyethylene glycol esters of chemically defined fatty 

acids, total 

Polyethylene glycol dilaurate 

Polyethylene glycol dioleate 

Polyethylene glycol distearate 



13,858 
16,712 
16, 194- 

1,298 

1,097 

1,9U 

334 

3,092 

16,794 

1,394 

269 

15,131 

16, 877 

1,216 

905 

14,756 

6,109 

3,357 

2,517 
235 

7,443 
123 
208 

7,112 

4,974 

24,379 

989 

1,400 

3,720 

18,270 

132,281 



5,347 
285 
536 
132 

1,025 
212 
888 

2,269 
67,083 

4,700 

21,613 
940 

20,246 
427 

40,770 

361 

1,455 

38,954 

21,169 

15,323 

596 

2,774 

322 



1,000 
dollars 



11,850 
15,973 
16,789 

937 
1,084 
1,931 

2,526 
16,238 

249 
15,989 
15,378 

749 
14,629 
4,281 



1,532 

2,749 

.6,683 

120 

6,563 
4,350 

24,179 
1,084 
1,194 
3,837 

18,064 

102,689 



4,904 
262 
559 
126 
828 
213 
776 

2,140 
56,936 

2,754 

20,217 
905 

18,923 
389 

33,965 
4^9 

33,516 
14,157 

9,218 
590 
611 
276 



4,196 
4,541 
4,701 

224 
396 
726 

575 
4,480 

95 
4,385 
5,494 

469 
5,025 
3,476 



1,650 
1,826 
3,362 



3,296 
7,293 

9,919 
832 

471 
1,762 
6,854 

33,516 



1,525 

73 

172 

30 

209 

73 

320 

648 

15,336 

1,192 

6,239 
314 

5,797 
128 

7,905 
117 

7,788 
4,911 

3,491 
^13 
214 
103 



See footnotes at end of table. 



50 SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 19A. —Surface -active agents.- U.S. production and sales , J964- 



Chemical 



Production""" 



Quantity^ 



NONBENZENOID SURFACE-ACTIVE AGENTS--Continued 
Not Sulfaled or Sulfonated-Continued 

Carboxylio acid esters — Continued 

Polyethylene glycol esters — Continued 

Polyethylene glycol esters of chemically defined 
fatty acids — Continued 

Polyethylene glycol monolaurate 

Polyethylene glycol mono-oleate 

Polyethylene glycol monostearate 

All other 

Polyethylene glycol esters of mixed fatty acids, 

total 

Polyethylene glycol coconut oil ester 

Polyethylene glycol rosin ester 

Polyethylene glycol tall oil ester 

All other 

Other carboxylic acid esters, total 

Anhydrosorbitol tall oil ester 

Ethoxylated anhydrosorbitol monolaurate 

Ethoxylated anliydrosorbitol raono-oleate 

Ethoxylated anhydrosorbitol monostearate 

Ethoxylated anhydrosorbitol trioleate 

Ethoxylated anhydrosorbitol tristearate 

1, 2-Propanediol monolaurate 

1,2-Propanediol monostearate 

All other 

Ethers, total 

Castor oil, ethoxylated 

n-Dodecyl alcohol, ethoxylated 

Mixed primary straight chain alcohols, ethoxylated 

9-Ootadeoenyl alcohol, ethoxylated 

Tridecyl alcohol, ethoxylated 

All other 

Fatty acids, potassium and sodium salts: 

Coconut oil acids, potassium and sodium salts 

Laurie acid, potassium salt 

Mixed vegetable fatty acids, potassium salt 

Oleic acid, potassium salt 

Oleic acid, sodium salt 

Rosin acids, sodium salt 

Stearic acid, sodium salt 

Tall oil acids, potassium salt 

Tall oil acids, sodium salt 

Phosphoric and polyphosphoric acid esters, total 

Alcohols, phosphated and polyphosphated, total 

2-Ethylhexyl phosphate, sodium salt 

Mixed mono- and diaUcyl phosphate 

Octyl polyphosphate 

All other 

Other phosphoric and polyphosphoric acid esters 

Other nonbenzenoid surface-active agents, not sulfated or 
sulfonated^ 

Sulfated and Sulfonated 
Total— - - 

Dicarboxylio acid amides, sulfated and sulfonated 

Dicarboxylic acid esters, sulfated and sulfonated, total 

Sulfosuooinic acid, bis(2-ethylhexyl)ester 

Jill other 



1,000 

pounds 

3,887 

2,64A 

4,611 

489 

5,846 
350 

3,596 

1,900 

38,682 

401 

2,600 

3,446 

1,970 

430 

708 

174 

1,042 

27,911 

119,474 



2,593 

43,947 

17, 974 

2,934 

7,524 

39,502 



289 

102 

494 

863 

1,034 

90 

1,841 

6,379 

97 



JlA 



3,862 

229 

324 

112 

3,197 

1,028 



30,499 



309,730 



1,492 
5,427 



1,000 

pounds 

2,111 

1,987 

3,398 

245 

4,939 

274 

671 

2,929 

1,065 

26,692 

2,482 

3,135 

1,906 

415 

987 

179 

847 

16,741 

63,139 



2,131 
1,930 

15,233 
1,966 
6,994 

34, 885 



287 

100 

487 

708 

1,011 

90 

1,865 

6,375 

81 

3,665 



2,651 

201 

276 

112 

2,062 

1,014 



30,004 



288, 149 



1,521 
5,515 



1,000 
dollars 

833 

771 

1,276 

81 

1,420 

86 

213 

670 

451 

11,744 

1,065 

1,372 

832 

184 

415 

68 

270 

7,538 

15,495 



756 

900 

2,237 

942 

1,546 

9,114 



107 
215 
188 
21 
947 
1,090 



1,807 

63 

215 

44 

1,485 

683 



4,661 



64,208 



3,993 
1,434 



3,880 
1,635 



935 
2,592 



1,780 
812 



See footnotes at end of table. 



SURFACE-ACTIVE AGENTS 51 

TABLE 19A. — Surface-active agents: U.S. production and sales, 1964 — Continued 



Production''" 



Sales 



Quantity^ 



Unit 
value ^ 



NONBENZENOID SURFACE-ACTIVE AGENTS- -Continued 



Sulfated and Sulfonated- -Continued 



n-Dodeoyl sulfate salts, total 

n-Dodecyl sulfate, aminonium salt 

n-Dodecyl sulfate, sodium salt 

n-Dodeoyl sulfate, triethanolamine salt- 
All other 



1,000 
pounds 
■41,097 



1,000 
dollars 



36,704 



Fats, oils, and waxes, sulfated and sulfonated, total- 
Castor oil, sulfonated 

Coconut oil, sulfonated 

Cod oil, sulfonated 

Grease, other than wool, sulfonated 

Neat's-foot oil, sulfonated 

Peanut oil, sulfonated 

Rice-bran oil, sulfonated 

Soybean oil, sulfonated 

Sperm oil, sulfonated 

Tall oil, sulfonated 

Tallow, sulfonated 

All other 



ijS-ig 

12,777 
10,018 
16,-453 

31,692 



1,836 
10,948 

8,584 
15,336 

19,522 



12,028 



Other nonbenzenoid surface-active agents, sulfated and 

sulfonated, total 

Butyl sulfo-oleate 

Coconut oil acids - ethanolamlne condensate, sulfated, 

potassium salt 

n-Dodeoyl alcohol, ethoxylated and sulfated, sodium salt 

Isopropyl sulfo-oleate 

N-lfethyl-N-oleoyltaurine 

Oleic acid, sulfonated 

Propyl sulfo-oleate 

All other' 



8,119 
1,686 
2,222 

660 
1,166 
1,309 

187 

2U 
6,948 

714 
7,312 
1,155 



230,022 



3,799 
813 

1,702 
625 
491 

1,183 

196 
4,152 

5,383 
1,178 



224, 887 



921 
5,724 
1,928 
3,455 

4,193 



.50 
.52 



1,195 
171 
265 
98 
107 
309 

71 
795 

853 
329 



44,460 



.36 
.19 



.16 
.28 



1,564 

45 

579 

1,123 

2,780 

4,837 

810 

218,284 



1,499 

45 

413 

665 

2,763 

3,607 

719 

215,176 



357 

48 
255 
194 
1,473 
849 
184 
41, 100 



""■ All quantities are given in terms of 100-percent organic surface-active ingredient. 

^ Calculated from rounded figures. 

-^ Includes sales of xylenesulfonio acid, potassium salt, and of straight chain dodeoylbenzenesulfonic acid, tri- 
ethanolamine salt; also includes production and sales of "All other" benzene-, toluene-, and xylenesulfonates, of 
"All other" straight chain dodecyl- and tridecylbenzenesulfonates, and of all branched chain alkylbenzenesulfonates 
other than dodecyl- and tridecylbenzenesulfonates. 

'• Includes sales of "All other" alkylphenols, ethoxylated and sulfated. 

' E.g., glycerol lactate palmitate and glycerol diacetyltartrate monostearate. 

^ Includes production and sales of "All other" fatty acids, potassium and sodium salts. 

'' Includes alcohols, alkanes, amines, ethers, fatty acids, fatty acid amides, fatty acid esters, and quaternary 
ammonium compounds, sulfated and sulfonated. 

Production of benzenoid surface- active agents in 1964 amounted to 1,348 million pounds, or 
3. percent more than the 1,309 million pounds reported for 1963. Sales of benzenoid surface- 
active agents in 1964 totaled 1,245 million pounds, valued at $165 million, compared with sales 
in 1963 of 1,222 million pounds, valued at $160 million. Of the benzenoid surface- active agents 
for which individual statistics are shown in the table, those produced in largest quantity were 
lignosulfonic acid, calcium salt, 326 million pounds; branched chain dodecylbenzenesulfonic 
acid, sodium salt, 320 million pounds; nonylphenol, ethoxylated, 133 million pounds; branched 
chain dodecylbenzenesulfonic acid, 61 million pounds; dodecylphenol, ethoxylated, 52 million 
pounds; and straight chain dodecylbenzenesulfonic acid, sodium salt, 49 million pounds. 

Production of nonbenzenoid surface- active agents in 1964 amounted to 771 million pounds, 
or 14. 7 percent more than the 672 million pounds reported for 1963. Sales of nonbenzenoid 
surface-active agents in 1964 totaled 655 million pounds, valued at $185 million, compared with 
the 567 million pounds, valued at $165 million, reported for 1963. Of the nonbenzenoid surface- 
active agents for which individual statistics are shown in the table, those produced in largest 
quantity were n-dodecyl alcohol, ethoxylated, 49 million pounds; glycerol monostearate, 20 
million pounds; coconut oil acids - diethanolamine condensate (amine/acid ratio=l/l), 17 nnil- 
lion pounds; and lauric acid - diethanolamine condensate, 16 million pounds. 



52 



SYNTHETIC ORGANIC CHEMICALS, 1964 
Pesticides and Other Organic Agricultural Chemicals 



This section of the report covers pesticides (fungicides, herbicides, insecticides, and 
rodenticides) and other organic agricultural chemicals, such as plant hormones, seed disin- 
fectants, soil conditioners, and soil fumigants. The data are given in terms of 100-percent 
active material; they thus exclude such materials as diluents, emulsifiers, synergists, and 
wetting agents. Statistics on production and sales of pesticides and other organic agricultural 
chemicals in 1964 are given in table 20A.12 

Production of pesticides and other organic agricultural chemicals in 1964 amounted to 783 
million pounds--about 2 percent more than the 763 million pounds reported for 1963. Sales in 
1964 were 692 million pounds, valued at $427 million, compared with 651 million pounds, 
valued at $369 million, in 1963. 

The output of cyclic pesticides and other chemicals included in the cyclic group amounted 
to 585 million pounds in 1964--about 2 percent less than the 597 million pounds produced in 1963. 

TABLE 20A. — Pesticides and other organic agricultural chemicals : U.S. production and sales, 1964 

[listed below are all pesticides and other organic agricultural chemicals for which any reported data on production 
or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be 
published or where no data were reported.) Table 20B in pt. Ill lists all pesticides and other organic agricul- 
tural chemicals for which data on production or sales were reported and identifies the manufacturer of each] 



Sales 



Qaantity 



Unit 
value ^ 



Grand total 

PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICALS, CYCLIC 

Total — 

Fungicides, total 

Ifercury fungicides 

Naphthenic acid, copper salt 

Pentachlorophenol (PCP) 

2,4-,5-Trichlorophenol and salts 

All other^ 

Herbicides and plant hormones, total 

2-sec-Butyl-4,6-dinitrophenol (DNBP) 

2-seo-Butyl-4-,6-dinitrophenol, ammonium salt 

Phenoxyacetic acid derivatives: 

(2,A-Dichlorophenoxy)acetic acid (2,4-D) 

(2,4-Dichlorophenoxy)aoetic acid esters and salts, total 

( 2, 'i-Dichlorophenoxy) acetic acid, n-butyl ester 

( 2, 4--Dichlorophenoxy) acetic acid, dimethylamine salt- 

(2, li-Dichlorophenoxy) acetic acid, ethyl ester 

( 2, -i-Diohlorophenoxy) acetic acid, iso-octyl ester 

( 2, 4-Dichlorophenoxy) acetic acid, isopropyl ester 

All other 

(2,<i,5-Trichlorophenoxy)aoetic acid (2,4,5-1) 

(2,4,5-Trichlorophenoxy)acetic acid esters and salts, 

total 

(2,'i,5-Trichlorophenoxy) acetic acid, n-butyl ester 

(2,4., 5-Trlohlorophenoxy) acetic acid, Iso-ootyl ester- 
(2,'i,5-Trichlorophenoxy)acetic acid, triethylamine 

salt 

All other 

Phenylmercury acetate (PMA) 

All other^ 

Insecticides and rodenticides, total 

Aldrin-toxaphene group* 

Hexaohlorocyclohexane (Benzene hexachloride ) and lindane' 

Organophosphorus insecticides, total 

0,0-Diethyl O-(p-nitrophenyl) phosphorothioate 

(Parathlon) 

0,0-Dlmethyl O-(p-nitrophenyl) phosphorothioate 

(Methyl parathion) 

All other^ 

l,l,l-Trichloro-2,2-bis(p-chlorophenyl) -ethane (DDT) 

All other'' 

See footnotes at end of table. 



1,000 
pounds 
782,749 



692,355 



1,000 
dollars 
427,111 



584,698 



522,691 



316,556 



3,774 



1,138 

1,897 

36,901 

13,662 

27,176 

186,344 



63,115 



1,132 

1,860 

29,236 

30,887 
117,! 



21,415 



4,146 
55 

53,714 

54,366 

7,242 

14,091 

607 

6,159 

4,508 

21,759 

11,434 

12,963 
1,754 
3,699 

361 

7,149 

495 

49,171 

317,580 



105,296 

39,661 

12,768 

18,640 

8,253 

123,709 

48,914 



2,691 
52 

25,006 
40,262 
5,766 
9,618 
749 
6,010 

18,119 
3,729 

6,895 

551 

2,933 

414 

2,997 

468 

38,765 

341,708 



3,164 

540 

5,005 

12,706 
124,611 



105,551 
11,765 
42,769 

10,338 

21,713 

10,718 

129,373 

52,250 



1,497 
108 

7,573 
15,827 
2,498 
4,094 
194 
2,414 

6,627 
3,174 

5,056 

439 

2,514 

410 

1,693 

2,248 

89,128 

170,530 



1,934 
51,527 

7,349 

16,431 
27,747 
18,993 
47,141 



1 2 See also table 20B, pt. Ill, which lists these products alphabetically and identifies the manufacturers. 



MISCELLANEOUS CHEMICALS 53 

TABLE 20A. — Pesticides and other organic agricultural chemicals: U.S. production and sales, 1964 — Continued 



Quantity 



Unit 
value ^ 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICALS, ACYCLIC 

Total 

Fungicides, total 

Dimethyldithiooartamio acid, ferric salt (Ferbam) 

Ethylene bis(dit)iiooarbamio acid), disodium salt (Nabam) 

Ethylene bis(dithiooarbaniio acid), zinc salt (Zineb) 

All other^ 

Herbicides and plant hormones, total 

Methanearsonio acid, disodiiim salt 

All other' 

Insecticides, rodenticides, and soil conditioners and 

fumigants, total 

Bromomethane (ifethyl bromide) 

l,2-Dibromo-3-chloropropane 

Organophosphorus insecticides, total 

Ethyl pyrophosphate (Tetraethyl pyrophosphate) (TEPP)- 

All other ^° 

All other insecticides, rodenticides, and soil condi- 
tioners and fumigants-''''' 



1,000 
pounds 

198,051 



pounds 
169,664 



1.000 
dollars 



110,555 



31,929 



1,838 

2,251 

6,664 

21,176 

40,042 



32,441 



24,050 



2,167 
37,875 



126,080 



1,863 
2,238 
4,039 
24,301 

34,159 



2,667 
31,492 



103,064 



735 

859 

1,780 

20,676 

38,839 



.38 
.44 
.85 



16,994 

5,314 

41,501 

669 

40,832 

62,271 



16,042 
3,910 
30,486 
538 
29,948 

52,626 



1,128 
37,711 



47,666 



.42 
1.20 



.46 



6,712 
1,756 

31,839 
450 

31,389 

7,359 



.42 
.45 

1.04 
.84 

1.05 

.14 



■'■ Calculated from rounded figures. 

^ Includes captan, dlohlone, glyodin,. sodium pentachlorophenate, tri- and tetrachlorophenols , and others. 

^ Includes dimethylurea compounds, dinitrophenol compounds, endothal, isopropyl carbanilates (IPC and CIPC), maleio 
hydrazide, triazines, and others. 

* Includes aldrin, ohlordane, dieldrin, endrln, heptachlor, and toxaphene. 

' Production of gamma isomer content is not publishable because publication would reveal the operations of the 
Individual producers. Sales of gamma isomer content In benzenehexachlorlde and lindane totaled 3.2 million pounds. 

^ Includes carbophenothlon, diazlhon, other phosphorothioates and phosphorodithloates, and others. 

■^ Includes DDD, endosulfan, methoxychlor, tetradifon and other chlorinated Insecticides, 1-naphthyl methyl- 
carbamate, small amounts of rodenticides and Insect repellents, hexachlorocyolohexane and lindane (production only), 
and others. 

^ Includes dodlne, mercury compounds, maneb, and others. 

' Includes CDAA, thiocarbamate and organophosphorus herbicides, sodium dichloropropionate, sodium TCA, and others. 
■^° Includes DD'VP, ethlon, malathion, naled, phorate, and others. 
^^ Includes soil conditioners and fumigants, small quantities of rodenticides, and others. 

Sales in 1964 were 523 million pounds, valued at $317 million, compared with 498 million pounds, 
valued at $286 m^illion, in 1963. The chemical in this group which was produced in the greatest 
quantity in 1964--as in eachyear since it was first separately reported in 1944--was the insecti- 
cide DDT. The output of this product in 1964 amounted to 124 million pounds, compared with 179 
million pounds in 1963. The sharp decline in the production of DDT in 1964 was due in part to the 
large inventory carried over from the preceding year and in part to a sharp decrease in exports. 

Production of acyclic pesticides and other acyclic organic agricultural chemicals in 1964 
amounted to 198 million pounds--about 19 percent more than the 166 million pounds reported 
for 1963. Sales in 1964 were 170 million pounds, valued at $111 million, compared with 153 
million pounds, valued at $8 3 million in 1963. 



Miscellaneous Chemicals 
As used in this report, the term "miscellaneous chemicals" refers to those s-ynthetic organic 
products that are not included in the use groups covered in the preceding sections of the report. 
These miscellaneous chemiicals, which account for about three-fifths of the output of all synthetic 
organic chemicals, include products that are employed in a great variety of uses; the number of 
chemicals used exclusively for only one purpose is not large. Among the products covered are 
those used for gasoline and lubricating oil additives, paint driers, photographic chemicals, 
tanning materials, flotation reagents, refrigerants, textile polymers, sequestering agents, 
organic fertilizers, antifreeze chemicals, solvents, and acyclic intermediates. 

Production of miscellaneous chemicals in 1964 amounted to 45. 7 billion pounds, or 11.0 
percent more than the output of 41. 2 billion pounds reported for 1963. Sales of mis,cellaneous 
chemicals in 1964 amounted to 20. 5 billion pounds, valued at $2.7 billion, compared with 17. 5 
billion pounds, valued at $2.4 billion, in 1963. Statistics on production and sales of miscel- 
laneous chemicals in 1964 are given in table 21A.-'-3 

13 See also table 21 B, pt. III, which lists these products alphabetically and Identifies the manufacturers. 



54 



SYNTHETIC ORGANIC CHEMICALS, 1964 
TABLE 2i.A.— Miscellaneous chemicals.- U.S. production and sales, 1964 



rusted below are all miscellaneous chemicals for which any reported data on production or sales may be published. 
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data 
were reported.) Table 21B in pt. Ill lists alphabetically all miscellaneous chemicals for which data on produc- 
tion or sales were reported and identifies the manufacturer of each] 



Grand total 

MISCELLANEOUS CHEMICALS, CYCLIC 

Total 

Benzoic acid salts: Sodium benzoate, tech. and U.S.P — 

Benzoyl peroxide 

Butyl benzoate 

Cyclopropane 

2,6-Di-tert-butyl-p-cresol: 

Food grade 

Tech 

Ethylmorpholine 

Flotation reagents 

Gasoline additives, total^ 

N,N-Di-sec-butyl-p-phenylenediamine 

N,N'-Disalioylidene-l,2-propanediamine 

All other 

Hexamethylenetetramine , tech 

Lubricating oil and grease additives, total 

Oil soluble petroleum sulfonate, barium salt 

Oil soluble petroleum sulfonate, calcium salt 

Oil soluble petroleum sulfonate, sodium salt 

All other 

Morpholine 

Naphthenic acid salts, total^ * 

Calcium naphthenate 

Cobalt naphthenate 

Iron naphthenate 

Lead naphthenate 

Manganese naphthenate 

Zinc naphthenate 

All other 

Photographic chemicals: 

Benzotrlazole 

p-Diethylamlnobenzenediazonium chloride (p-Diazo-N,N- 

diethylaniline) - zinc chloride 

p-Dimethylaminobenzenediazonium chloride (p-Diazo-N,N 

dimethylaniline) - zinc chloride 

Pinene 

Tall oil salts, total^ 

Calcium tallate 

Cobalt tallate 

Iron tallate 

Lesid tallate 

Manganese tallate 

Zinc tallate 

All other 

See footnotes at end of table. 



1,000 
pounds 

45,681,3»;3 



1,1U,624 



5,6U 

5,022 

577 

163 

4,316 

15,537 

879 

4,523 

11,333 



1,403 
9,930 



42,776 
466,691 



34,847 
156,041 
127,430 
148,373 

15,102 

20,427 



1,383 
3,122 

161 

12,903 

1,323 

1,069 

466 



20 

119 

63 

9,007 



704 
2,391 

519 
4,262 

899 
58 

174 



Qaantity 



20,518,575 



603,618 



5,110 
4,832 



4,063 

12,822 

870 



6,633 



2,441 

915 

3,277 

28,755 

276,352 



83,628 

68,396 

124,328 

12,638 

18,784 



1,231 

2,521 

137 

12,305 

1,250 

906 

434 



10,042 



589 
2,337 

479 
3,494 

862 
36 

167 



1,000 
dollars 
2,651,276 



224,330 



1,497 
4,558 

2,271 

2,381 
7,044 
1,011 



6,110 



2,133 
1,610 
2,367 

5,241 

58,132 



16,518 
10,420 
31,194 

6,114 

6,012 



549 

1,637 

48 

2,709 

473 

337 

259 



84 
247 



1,398 
2,729 



191 

1,242 

127 

859 

247 

11 

52 



MISCELLANEOUS CHEMICALS 
TABLE 21A. — Miscellaneous chemicals.- U.S. production and sales , 1964 — Continued 



55 



Production 



CJuantity 



Unit 
value ■"• 



MISCELIANEOUS CHEMICAI£, CYCLIC— Continued 

Tanning materials, synthetic, total 

2-Naphthalenesulfonic acid, formaldehyde condensate and 

salts 

l-Phenol-2-sulfonio acid, formaldehyde condensate 

(Phenol-formaldehyde, sulfonated) 

All other 

Textile chemicals, other than surface-active agents 

All other miscellaneous cyclic chemicals 

MISCELLANEOUS CHEMICAI£, ACYCLIC 

Total 

Acetaldehyde 

Acetic acid, synthetic, 100^ 

Acetic acid salts, total 

Copper acetate 

Potassium acetate 

Sodium acetate 

Zinc acetate 

All other . 

Acetic anhydride, IOO5J, from all sources 

Acetone, total 

From isopropyl alcohol 

All other 

Acrylic acid 

Acrylonitrile 

Adipic acid 

Alcohols, monohydrio, unsubstituted, total 

Alcohols Cg or lower, total 

Amyl alcohols 

Butyl alcohols, total 

Normal (n-Propyloarbinol) 

All other 

Ethyl alcohol, synthetic^ 

Hexyl alcohol 

Iso-octyl alcohols 

Isopropyl alcohol 

Methanol, synthetic 

All other 

Alcohols Cio or higher, total 

Deoyl alcohols 

Dodecyl alcohol (Lauryl alcohol) (955^) 

1-Hexadecanol (Cetyl alcohol) (955^) 

1-Octadecanol (Stearyl alcohol) (955^) 

All other 

Amines, total 

Coconut oil amine 

Diethylamine 

Dlmethylamine 

Isopropylamlne 

Methylamlne, mono- 

Octadecylamine 

Oleylamlne 

Tallow amine 

Tallow amine, hydrogenated 

Trimethylamine 

All other 



1,000 
pounds 
34)001 



29,871 



3,318 
812 



1,928 
476,526 



44,566,719 



1,058,013 
1,099,986 



23,154 



171 
2,853 
14,649 

5,481 

1,399,203 

1,054,756 



761,154 
293,602 



32,532 
594,177 



7,936,892 



7,567,198 

32,179 

799,219 

388,540 

410,679 

2,071,116 

5,208 

142,042 

1,503,957 

2,631,657 

381,820 

369,694 

64,720 

16,672 

1,777 

286,525 

611,134 



1,157 

8,260 

54,129 

7,729 

18,003 

749 

931 

3,153 

9,951 

12,129 

494,943 



i ,000 
dollars 

6,616 



28,086 



3,024 
1,065 



1,14^ 
181,152 



19,914,957 



4,991 



994 
631 



700 
122,185 



2,426,946 



100,466 
234,477 



17,596 



6,613 
17,025 



132 
2,974 



322 

14,168 



672,093 



450,771 
221,322 

4,369 

311,147 

60,830 

4,165,648 



160 
3,194 



31,997 



22,879 
9,118 

1,471 
48,808 
14,810 

261,812 



4,011,240 

22,080 

399,164 

288,133 

111,031 

1,163,477 

128,256 
538,651 
1,497,380 
262,232 
154,408 
50,431 

1,837 

5,321 

96,819 

183,344 



986 

30,865 

18,091 

830 

650 

2,858 

9,572 

5,381 

114,111 



236,818 

3,007 

38,305 

28,789 

9,516 

73,325 

14)972 
33,541 
42,683 
30,985 
24,994 
5,719 

496 

889 

17,890 

57,419 



505 
6,038 

2,971 
383 
274 
877 

2,636 

829 

42,906 



56 



SYNTHETIC ORGANIC CHEMICALS, 1964 
TABLE 21A. — Miscellaneous chemicals.- U.S. production arid sales , 1964- 



-Continued 



Chemical 



MISCELLANEOUS CHEMICALS, ACyCLIC--Continued 

Amjrl acetates, 905t 

Bis(2-chloroethyl) ether (Dichlorodiethyl ether), all 

grades 

2-Butaiione (Methyl ethyl ketone) 

2-Butanone oxime 

2-Butanone peroxide 

Butyl acetates, total 

Normal 

All other 

tert-Butyl hydroperoxide 

tert-Butyl peroxide (Di-tert-butyl peroxide) 

Butyric acid 

Caprolactam (Hexahydro-2H-azepin-2-one) 

Carbon disulfide 

Cellulose ethers, total 

Sodium carboxymethylcellulose, lOOjt 

All other 

Chloral (Trichloroacetaldehyde ) 

Chloroaoetic acid, mono- 

Chloroacetic acid, ethyl ester 

2-Chloro-N,N-dimethylethylamine (Dimethylaminoethyl 

chloride) hydrochloride 

2-Chlorotriethylamine hydrochloride 

Decanoyl peroxide 

Dibutyl fumarate 

Dibutyl maleate — • 

2-Dlethylaminoethanol 

Diethylene glycol 

Diethyl malonate (Malonic ester) 

Dllauryl 3,3'-thiodipropionate 

2-Diinethylaminoethanol 

Dioctyl maleate 

Dipropylene glycol 

Dodeoenylsuceinic anhydride 

Epichlorohydrin 

Erucamide 

Ethanolamines , total 

2-Aminoethanol (Monoethanolamine ) 

2,2'-Iminodiethanol (Diethanolamine) 

2,2',2"-Nitrilotriethanol (Triethanolamine) 

2-Ethoxyethanol (Ethylene glycol monoethyl ether) 

2-(2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl 

ether) 

2-[2-(2-Ethoxyethoxy)ethoxy]ethanol (Triethylene glycol 

monoethyl ether) 

Ethyl acetate, 8556 

Ethyl acetoacetate 

Ethyl acrylate 

Ethylene glycol 

Ethylene oxide 

Ethyl ether, all grades 

Ethyl formate 

2-Ethylhexanoio acid (o -Ethylcaproic acid) salts, total' 

Calcium 2-ethylhexanoate 

Cotalt 2-ethylhexanoate 

Lead 2-ethylhexanoate 

Manganese 2-ethylhexanoate 

Zinc 2-ethylhexanoate 

See footnotes at end of table. 



Production 



8,664 



88,934 
2,760 
1,486 



77,782 
38,811 



130 
1,074 



245,688 
668,780 



44,930 
40,875 

57,614 

60,511 

1,734 



314 
5,143 
6,052 

151,475 

937 

1,257 

165 

27,101 

968 



173,937 



60,286 
65,521 
48,130 



36,294 

8,277 

117,746 

980 

90,831 

1,814,600 

2,163,035 

87,807 



Quantity 



773 
274 



7,106 

8,832 

276,416 

2,675 

1,448 

112,822 



75,047 
37,775 



633 

121,777 
601,201 

79,294 



42,454 
36,840 



40 

288 

4,630 

3,653 

2,240 

125,051 

607 

905 

947 

25,225 
830 

32,045 
429 

14^,107 



48,225 
49,043 
46,839 

47,216 

29,154 

1,378 

101,212 

799 

36,177 

1,202,562 

198,209 

79,680 

168 

2,966 



143 
638 
227 



1,000 
dollars 
1,193 

165 

31,157 

2,009 

2,492 

11,539 



7,804 
3,735 

249 
1,531 

151 
41,065 
24,191 

43,521 



18,712 
24,809 



49 
423 
984 
791 
1,054 
13,818 
4A2 
895 
664 

3,158 
390 

7,165 
503 

26,728 



9,770 
8,165 
8,793 

7,740 

5,056 

228 

10,366 

348 

9,737 

110,085 

20,502 

5,353 

56 



649 
96 
28 

102 



MISCELLANEOUS CHEMICALS 
TABLE 21A. — Miscellaneous chemicals: U.S. production and sales , 1964- 



57 



Quantity- 



Unit 
value -"^ 



MISCELLAHEOUS CHEMICAIS, ACYCLIC— Continued 

2-Ethylhexanoio acid (a-Ethyloaproio acid) salts — 
Continued 
All other 

2-Ethyl-l-hexyl acrylate 

Ethyl propionate 

Ethyl silicate (Tetraethoxysilane) 

Formaldehyde (3795 by weight) 

Fonnio acid, 905&- 

Formic acid salts 

Fumario acid 

Gluconic acid, tech 

Gluconic acid, sodium salt, tech ■ 

Halogenated hydrocarbons, total 

1-Bromobutane (n-Butyl bromide) 

Carbon tetrachloride 

Chlorinated paraffins, total 

355^64 i^ chlorine 

All other 

Chlorodifluorome thane 

Chloroethane (Ethyl chloride) 

Chloroform 

Chloromethane (Methyl chloride) 

Diohlorodifluoromethane 

1,2-Dichloroethane (Ethylene diohloride) 

Diohloromethane (Methylene chloride) 

1,2-Dlchloropropaiie (Propylene diohloride) 

Dichlorotetrafluoroethane 

lodomethane (Methyl iodide) 

Tetraohloroethylene (Perohloroethylene) 

Triohloroethylene 

Trichlorofluoromethane 

Vinyl chloride, monomer ( Chloroethylene ) 

All other 

Isoascorbic acid, sodium salt 

Isopropyl acetate 

Isopropyl ether 

Lactic acid, lOOjt 

Lauroyl chloride 

Lauroyl peroxide — ^ 

Linoleic acid salts, total^ 

Calcium linoleate 

Cobalt linoleate 

All other '■ 

Lubricating oil additives, total 

Phosphorodithioates (Dithiophosphates ) 

Sulfurized sperm oil 

All other 

Maleic anhydride 

Meroaptoacetic (Thioglycolio) acid derivatives, total— 
2-Aminoethyl mercaptoacetate (Monoethanolamine 

thioglyoolate) 

Ammonium mercaptoacetate 

All other 

2-Methoxyethanol (Ethylene glycol monoethyl ether) 

2-(2-Methoxyethoxy)ethaiiol (Diethylene glycol monoethyl 
ether) 

See footnotes at end of table. 



1,000 
pounds 

3,011 

22,590 

24 

4,871 

2,839,884 

19,396 

30,572 

30,145 

3,503 

8,904 

8,116,012 



4J 
535,891 
39,887 
29,664 
10,223 

666,111 

119,210 

134,011 

227,873 

2,199,378 

179,602 

58,489 

13,401 

20 

365,729 

370,465 

148,498 

1,614,981 

1,442,423 

2,631 
38,048 



9,353 
1,427 



128 
231 
183 

380,686 



101,928 

23,484 

255,274 

118,109 

4,671 



225 
1,723 
2,723 

73,376 

11,022 



1,000 
pounds 
1,724 

20,464 

3^924 

1,067,340 

18,769 

23,629 
3,269 
7,530 

3,704,041 



464,547 



43,380 

252,660 

98,104 

67,199 

226,327 

445,508 

156,693 

32,294 

12,629 

10 

335,619 

370,076 

139,367 

597,124 

462,504 

2,363 
33,559 
2,970 
8,069 

1,397 

523 



133 
390 
165,733 



53,282 

112,451 

67,792 

4,180 



4,180 
61,819 
3,764 



1,000 
do I lars 
2,062 

6,521 

"l,577 
27,973 
2,597 

3,844 
1,110 
2,285 

417,943 



33,719 



27,093 

18,322 

8,199 

5,233 

65,680 

•20,671 

14,020 

816 

7,020 

30 

31,704 

32,122 

28,504 

37,895 

86,915 

3,141 

3,717 

246 

2,956 

1,687 

182 



28 

154 

34,511 



13,492 
21,019 
8,271 
5,709 



5,709 

10,757 

656 



58 SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 21A. — Miscellaneous chemicals: U.S. production and sales , 1964 — Continued 



MISCELLANEOUS CHEMICALS, AOfCLir^-Continued 

2-[2-(2-Methoxyethoxy)ethoxy]ethanol (Triethylene glycol 

monoraethyl ether) 

Methyl acetate 

4-Methyl-2-pentanone (Methyl isobutyl ketone) 

Oleic acid salts, total' 

Copper oleate 

All other 

Oxalic acid 

Oxalic acid salts 

Palmitic acid salts, total 

Aluminum palmitate 

Zinc palmitate 

Palmitoyl chloride 

Pentaerythritol 

Pentaerythritol tetranitrate 

Phosgene (Carbonyl chloride) 

Phosphorus acid esters, not elsewhere specified 

Polyethylene glycol 

Polypropoxy ethers, total 

Glycerol tri(polyoxypropylene) ether 

All other 

Polypropylene glycol 

Propionic acid 

Propionic acid salts : 

Calcium propionate 

Sodium propionate 

Propylene glycol (1,2-Propanediol) 

Propylene oxide 

Saroosine and salt 

Sequestering agents, total 

(Diethylenetrinitrilo)pentaacetic acid, sodium salt 

N,N-Dihydroxyethylglycine, sodium salt 

(Ethylenedinitrilo)tetraacetic acid (Ethylenediamine- 

tetraaoetic acid) 

(Ethylenedinitrilo)tetraacetic acid, disodium salt 

(Ethylenedinitrilo)tetraacetic acid, tetrasodium salt-- 
(N-Hydroxyethylethylenedinitrilo)triacetic acid, 

trisodium salt 

All other 

Sodium formaldehydesulfoxylate 

Sodium methoxide (Sodium methylate) ■ 

Stearic acid salts, total* 

Aluminum stearates, total 

Aluminum distearate 

Aluminum monostearate 

Aluminum tristearate 

Calcium stearate 

Lead stearate 

Lithium stearate 

Magnesium stearate 

See footnotes at end of table. 



8,897 
158,607 



52 
287 



22,935 
4,677 



159 

137 

69,296 

4,776 

244,965 

9,749 

39,120 

173,224 



117,120 
56,104 

95,987 
39,117 

11,404 

5,357 

236,357 

569,060 

1,566 

34,883 



1,541 
150 

5,706 

680 

19,010 

3,294 
4,502 

4,673 
5,440 

31,884 



5,0l4 

3,639 

855 

520 

11,046 

411 

339 

1,326 



1,000 
pounds 

343 

134,822 

327 



1,000 
dollars 



35 



19,655 
4,469 



64,208 
2,668 



3,308 
33,650 



157,167 



110,347 
46,820 



11,572 



211,454 
60,319 



23,839 



1,300 
124 



2,968 
11,755 



2,814 
4,878 



4,778 
5,240 



29,906 



4,630 

3,334 

816 

480 

10,427 

359 

361 

1,367 



17,131 



14 
266 



2,778 
1,238 



15,517 
2,108 



4,184 
8,220 



31,841 



21,775 
10,066 



1,302 



22,593 
7,583 



9,031 



411 
84 



1,108 
4,196 



1,320 
1,912 



1,032 
1,604 



10,830 



1,716 
1,236 
310 
170 
2,951 
140 
184 
531 



MISCELLANEOUS CHEMICALS 
TABLE 21A. —Miscellaneous chemicals.- U.S. production and sales , 1964— Continued 



59 



MISCELLANEOUS CHEMICAI£, ACYCLIC— Continued 

Stearic acid salts — Continued 

Zino stearate 

All other 

Tallow amide, hydrogenated 

Tetraethyllead 

Triethylene glycol 

Urea in compounds or mixtures (IOO5S "basis), total-— 

In feed compounds 

In liquid fertilizer 

In solid fertilizer 

All other 

Vinyl acetate, monomer 

Zinc formaldehydesulfoxylate 

All other miscellaneous acyclic chemicals 



1,000 
pounds 

9,982 
3,766 

824 
586,956 
44,539 

2,419,764 



238,872 

869,879 

1,092,287 

218,726 

440,331 

1,380 

7,543,372 



Quantity 



9,880 
2,882 

796 
571,565 
35,610 

2,296,736 



257,925 

838,043 

1,058,971 

141,797 

217,310 

1,405 

1,813,971 



3,948 
1,360 

298 

304,715 

6,137 

° 97,813 



11,325 

37,441 

42,826 

6,221 

24,731 

631 

486,933 



Unit 
value ■"■ 



Calculated from rounded figures. 

= Statistics exclude production and sales of tricresyl phosphate. Statistics on tricresyl phosphate are given in 
the section "Plasticizers." ■' r r s " j-" 

^ ftuantities are given on the basis of solid naphthenate, tallate, or linoleate content. 

Statistics exclude production and sales of copper naphthenate. Statistics on copper naphthenate are given in the 
section "Pesticides and Other Organic Agricultural Chemicals." e = 

6 J? f?'3"i°n. sales of recovered acetic acid totaled 70,784 thousand pounds, valued at 3,992 thousand dollars. 
T, .* „ o^ i"! °" production of ethyl alcohol from natural sources by fermentation are issued by the Alcohol Tax 
Unit, U.S. Internal Revenue Service. 

_ ■^ Statistics exclude production and sales of potassium and sodium oleate. Statistics on these oleates are included 
m the section "Surface-Active Agents." 

_ Statistics exclude production and sales of potassium and sodium stearates. Statistics on these stearates are 
included m the section "Surface-Active Agents." 

^^Production of urea in primary solution totaled 2,487,279 thousand pounds. 
Includes estimated values for sales of urea in nitrogen compounds. 



60 SYNTHETIC ORGANIC CHEMICALS, 1964 

The total output of miscellaneous cyclic chemicals in 1964 was 1. 1 billion pounds, or 17. 
percent more than the output of 95 3 million pounds reported for 1963. Sales in 1964 totaled 604 
million pounds, valued at $224 million, compared with 477 nnillion pounds, valued at $191 mil- 
lion, in 1963. The most important subgroup of cyclic compounds was the lubricating oil addi- 
tives, the output of which was 467 million pounds in 1964. 

Total production of miscellaneous acyclic chemicals in 1964 was 44. 6 billion pounds-- 10. 9 
percent more than the output of 40.2 billion pounds reported for 1963. Sales in 1964 totaled 
19. 9 billion pounds, valued at $2. 4 billion, compared with 17. billion pounds, valued at $2. 2 
billion, in 1963. 

Production of alcohols and halogenated hydrocarbons in 1964 each exceeded that of any of 
the use groups of synthetic organic chemicals except cyclic intermediates and plastics and resin 
materials. Production of monohydric, unsubstituted alcohols totaled 7. 9 billion pounds in 1964, 
about 10. 8 percent more than in 1963. Alcohols are used as solvents, intermediates, and anti- 
freeze materials, and for other purposes. Production of halogenated hydrocarbons totaled 8. 1 
billion pounds in 1964, or 12. 9 percent more than the 7. 2 billion pounds reported for 1963. 
Halogenated hydrocarbons are used as solvents, intermediates, refrigerants, and aerosol 
propellants, and for other purposes. 

Individual chemicals the output of which exceeded 1 billion pounds in 1964 were formalde- 
hyde (2. 8 billion pounds, compared with 2. 5 billion pounds in 1963); synthetic nnethanol (2. 6 
billion pounds, compared with 2. 3 billion pounds); urea (2.4 billion pounds, compared with 2. 2 
billion pounds); ethylene oxide (2. 2 billion pounds, compared with 1. 9 billion pounds); dichloro- 
ethane (2. 2 billion pounds, connpared with 1. 8 billion pounds); ethyl alcohol (2. 1 billion pounds, 
compared with 2. billion pounds); ethylene glycol (1. 8 billion pounds, compared with 1. 7 
billion pounds); vinyl chloride (1.6 billion pounds, compared with 1.4 billion pounds); isopropyl 
alcohol (1. 5 billion pounds in each year); and acetic anhydride (1. 4 billion pounds, compared 
with 1. 3 billion pounds). 



PARTm. 



ALPHABETICAL LIST OF INDIVIDUAL PRODUCTS, BY GROUPS, 
AND NAMES OF MANUFACTURERS 



This section of the report consists of (1) a series of tables that supplement the statistical 
information given in parts I and II, and (Z) a Directory of Manufacturers. The tables with num- 
bers that include the letter "B" supplement the tables in part I or part II with numbers that in- 
clude the letter "A"; for example, table 8B in part III supplements table 8A in part II. 

Each table in part III lists alphabetically the individual items in each group for which data on 
production or sales were reported for 1964. The tables include data on only those chemicals for 
which the volume of production or sales in 1964 exceeded 1, 000 pounds or for which the value of 
sales exceeded $1, 000. Where separate statistics for an item are given in the tables in part I or 
part n, an asterisk (=!=) precedes the name of the item in the tables in part III. The manufacturers 
of each product are indicated by identification codes which are listed in the Directory of Manu- 
facturers (table 22). A few companies, however, have specifically requested that they not be 
identified as having produced or sold certain items. These manufacturers are indicated by a 
small letter "x" in the tables. 

Tar Crudes 
TABLE 4B. — Tar crudes for which U.S. production or sales were reported, identified by manufacturer, 1964 

[Tar crudes for which separate statistics are given in table Ak are marked below with an asterisk (**); products not 
so marked do not appear in table "iA because the reported data are accepted in confidence and may not be published. 
Manufacturers' identification codes shown below are taken from table 22. Table 22 identifies all U.S. producers of 
tar crudes (except producers that report to the Division of Bituminous Coal, U.S. Bureau of Mines)] 



Manufacturers ' identification codes 
(according to list in table 22)^ 



*Crude light oil 

Light-oil distillates : 

*Benzene, specification and industrial grades 

»Toluene, specification and other grades 

*}^lene, all grades 

^Solvent naphtha 

»A11 other light-oil distillates 

•^Pyridine crude bases 

♦Naphthalene, crude, solidifying at — 

*Less than 74° C 

*'7^" C. to less than 76° C 

»76° C. to less than 79° C 

Crude tar-acid oils having a tar-acid content of — 

»55fc to less than 245t- 

*2A$ to 515^ 

Cresylic acid, crude 

*Creosote oil (Dead oil) : 

♦Distillate as such 

♦Creosote in coal-tar solution 

All other distillate products 

♦Tar, road 

♦Tar for other uses: 

Crude 

Refined 

Pitch of tar: 
♦Soft and medium (water softening points less than 
110° F., and 110° F. to 160° F.). 

♦Hard (water softening point above 160° F.) 

Pitch-of-tar coke and pitch emulsion 



CBT. ■= 

ACY, KPP. 

ACT, KPP. 

ACT, KPP. • 

ACT, KPT, NEV, PAI. 

ACP, NEV, PAI. 

ACP, KPT. 

COP, NEV. 

KPT. 

ACP, KPT, PRD, RIL. 

ACP, RIL. 

ACP, KPT, RIL. 

ACP, KPT, PHD. 

ACP, ACT, CBT, COP, KPT, RIL, WTC. 

ACP, HUS, JEN, KPT, RIL. 

ACP, KPT, NEV, PAI. 

ACP, KPT, RIL, WTC. 

KPT, RIL. 

ACP, KPT, RIL, RUR. 

ACP, CBT, COP, JEM, KPT, RIL. 

ACP, COP, KPT, RIL. 

JEN, RIL. 



Does not include manvif acturers ' identification codes for producers that report to the Division of Bituminous 
Coal, U.S. Bureau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey, May 17, 
1965, entitled "Coke Producers in the U.S. in 1964-." 

^ Crude light oil production and sales of this company are not included with the U.S. Bureau of Mnes figures 
given in table 4A. 

61 



62 



SYNTHETIC ORGANIC CHEMICALS, 1964 



Crude Products From Petroleum and Natural Gas for Chemical Conversion 



TABLE 5B. Crude products from petroleum and natural gas for chemical conversion for which U.S. production 

or sales were reported, identified by manufacturer, 1964 

[Crude products from petroleum and natural gas for chemical conversion for which separate statistics are given in 
table 5A are marked below with an asterisk ( *) ; products not so marked do not appear in table 5A because the 
reported data are accepted in confidence and may not be published. Jifanufacturers ' identification codes shown be- 
low are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the 
designated product] 



Manufacturers' identification codes 
(according to list in table 22) 



AROMATICS AND NAPHTHENES 

*Alkyl aromatics, distillates, and solvents 

^Benzene (except motor grade) : 

^Benzene, 1° 

»Benzene, 2° 

*Cresylic acid, crude 

*Naphthalene , all grades 

*Naphthenic acids : 

Acid number lower than 150 

*Acid number 150-199 

Acid number 200-224 

Acid number 225-24-9 

Sodiiim carbolate and phenate, crude 

*Toluene : 

■^Nitration grade, 1° 

*Pure commercial grade, 2° 

Solvent grade 

All other 

»}(ylenes , mixed : 

Aviation grade 

*3° 

5° 

All other 

All other aromatics and naphthenes 

ALIPHATIC HYDROCARBONS 

Ci hydrocarbon: Methane 

»C2 hydrocarbons : 

*Aoetylene 

»Ethane 

^Ethylene 

C2 and C3 hydrocarbons, mixed 

*C3 hydrocarbons: 

*Propane 

Propane-propylene mixture 

^Propylene 

*Ci. hydrocarbons : 

*1,3-Butadiene, grade for rubbers (elastomers)- 

^Butadiene and butylene fractions 



ACC, DUP, ELP, ENJ, FG, GOC, JCC, MOC, MON, OMC, PLC, 
SM, SOG, USI, VPT, WTN. 

APR, ASH, ATR, CCP, CSD, DLH, DXS, ELP, ENJ, GOC, GRS, 
M3C, MON, PLC, PRO, RIC, SHO, SM, SNT, SOG, SUN, TOC, 
TX, VPT. 

Aid, CO, DOW, SHO, SKO, SOC, UCC. 

ATR, PRD, RIC, SHO, SOI. 

ASH, COL, CSO, MON, SUN, TID. 

RIC, SUN, TX. 

PRO, RIC, SM, SOC, SUN. 

PRO, RIC, SM, SOC. 

NOP, PRO, RIC, SM, SOC. 

ATR, GOC, SIN. 

ASH, ATR, CSD, DLH, ENJ, GOC, GRS, LEN, MOC, MON, PLC, 
PRO, RIC, SHC, SHO, SIN, SNT, SOG, SUN, TOC, TX, UCC, 
VPT. 

DOW, M3N, RIC. 

CO, FG. 

CSD, DXS, ELP, GRS, RIC, SHO, SM, SOC, SUN, TOC, TX, 
VEL. 

CSD, CSO, SOG. 

ASH, ATR, DLH, MON, PRO, SNT. 

MOC, SIN. 

AMD, CCP, CSD, ENJ, GRS, LEN, MON, RIC, SHO, SM, SOC, 

SUN, TOC, TX, VPT. 
ACC, ELP, ENJ, JCC, LEN, PAS, PLC, SM. 



CCP, MOC, PAN. 

ACY, DOW, DUP, MNO, MON, UCC, X. 

ACU, CCP, ENJ, MOC, MON, PAN, SHC, SHO, SM, SOI, TX, 

UCC, USI. 
CCP, DOW, DUP, EKX, ELP, ENJ, GOC, JCC, KPP, M3C, MON, 

OMC, PET, PLC, RIC, SHC, SM, SNO, TX, UCC, USI. 
GYR, PLC, SM. 

ASH, CCP, CSD, DXS, ENJ, GRS, MOC, OMC, PAN, PLC, SHO, 
SIN, SM, SNT, SOG, SOI, SPI, UCC, UOC, USI. 

GOC, TX. 

ASH, CCP, DOW, EKX, ELP, ENJ, GOC, JCC, MOC, MON, PET, 
PLC, RIC, SHC, SHO, SIN, SIO, SM, SOG, SOI, SPI, SUN, 
UCC, UOC. 



CPY, DOW, ELP, ENJ, FRS, GGC, ILC, 

SHC, SM, SOC, SPI, TID, TUS, UCC. 
DOW, GYR, PLC, SHC, SHO, SIN, SOC. 



i, PET, PLC, PIT, 



CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS 



63 



TABLE 5B. — Crude products from petroleum and natural gas for chemical conversion for which U.S. production 
or sales were reported, identified by manufacturer , 1964 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



ALIPHATIC HTOROCABBONS— Continued 

*Ci, hydrocarbons — Continued 

*n-Butane 

1-Butene 

2-Butene 

*1-Butene and 2-butene mixture 

»Isobutane 

»Isobutylene 

All other 

*C5 hydrocarbons : 

Isopentane ( 2-Methy Ibutane ) 

*Isoprene (2-Methyl-l,3-butadiene) 

n-Pentane 

All other 

Ce hydrocarbons: 

Diisopropyl (2, 3-Dimethy Ibutane) 

*Hexane 

Neohexane ( 2, 2-Dimethy Ibutane) 

All other 

C7 hydrocarbons: 

*n-Heptane 

»Heptenes, mixed 

All other 

Cs hydrocarbons : 

*Diisobutylene (Diisobutene) 

n-Octane 

2,2,4-Trlmethylpentane (iso-octane) 

All other 

Hydrocarbons, C9 and above: 

1-Dodecene 

Eicosane 

»Nonene (Tripropylene) 

Pentadecene 

*Polybutene 

»Tetrapropylene 

Trideoene concentrate 

Triisobutylene 

All other 

■^Hydrocarbon derivatives: 

1-Butanethiol 

tert-Butyl mercaptan ( 2-Methy 1-2-propanethiol) 

Di-tert-butyl disulfide 

tert-Dodecyl mercaptan 

Ethyl mercaptan (Ethanethiol) 

Isopropyl mercaptan 

Methyl mercaptan (Methanethiol) 

tert-Ootyl mercaptan 

n-Propyl mercaptan (l-Propanethiol) 

All other 

All other aliphatic hydrocarbons: Alpha olefins, molecular 
weight ranges: 

C6-C7 ' 

Cg-Cio 

C11-C15— 

C16-C20 

All other 



PLC, PRO. 
SIN, SOG, TID. 



CCP, CSD, DX3, 
SM, SNT, SOC, 

PLC, PTT, SPI. 

MON, PLC, PTT. 

AMO, CCP, ENJ, 
SOI, SPI, TX, 

CCP, DXS, EIP, 
USI. 

CCP, ENJ, PRO, 

APR, JCC, MON, 

CCP, CSD, ENJ, 

ENJ, am, PLC, 

APR, PLC. 

ENJ, GYR, MOC, 

PLC. 

ENJ, PLC, PRO, 

PLC. 

APR, PLC. 

CSD, EKX, ENJ, 
ENJ, GOC, HOU, 
PLC. 

ATR, PTT, TX. 
ENJ, PLC. 
PLC. 
PLC. 

CO. 

ATR. 

AMO, ATR, ENJ, 

CO. 

CSD, SOC, SOI. 

DXS, ENJ, GOC, 

ENJ. 

ATR. 

ENJ, GOC, HOU, 

PAS. 

PAS, PLC. 

PLC. 

PAS. 

CSD, PAS, SOC. 

PAS, SOC. 

ACC, PAS. 

PAS, PLC. 

PAS. 

EKX, PAS, PLC, 



ATR, GOC, GYR, PLC, SOC. 

ATR, ENJ, GOC, SOC. 

ENJ, GOC, SOC. 

ENJ. 

EKX, GOC, SOC. 



ELP, MOC, OMG, PAN, PLC, SHM, SHO, 
SOI, UCC, USI. 



GOC, MOC, PLC, PRO, PTT, SHO, SOC, 
MOC, OMG, PAN, PLC, SHO, SOI, UCC, 



PTT, SIN. 

PLC, SM, SOI, UCC, USI. 



PLC, SHO, SM, SOI, UCC. 
SHC. 



MON, PAS, PET, PLC, SHC, USI. 



GOC, PAS, PRO, RIC, SUN. 

MOC, PRO, RIC, SNT, SOC, SUN, TX. 

KEN, PLC, SOC, TID, UCC, x. 



64 



SYNTHETIC ORGANIC CHEMICALS, 1964 
Cyclic Intermediates 



TABLE 7B. 



• Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1964 



fCyolio intermediates for which separate statistics are given in table 7A are marked below with an asterisk (*); 
cyclic intermediates not so marked do not appear in table 7A because the reported data are accepted in confi- 
dence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x 
signifies that the manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 22) 



Aoeanthryleno[2,l-a]aceanthrylene-5,13-dione 

8-Acetamido-l-('i-acetamido-2-hydroxy-5-nitrophenylazo)- 
2-naphthol. 

3-Acetamido-6-aminobenzenesulfonic acid 

5-Acetamido-2-aminobenzenesulfonic acid 

3-(2-Acetamido-A-aminophenylazo)-l,5-naphthalenedi- 
sulfonlc acid. 

p-Acetamidobenzoic acid 

2-Aoetamido-3-chloroanthraqulnone 

*Acetanilide, tech 

Acetoacetanilide 

o-Acetoacetanisidide 

o-Acetoacetotoluidide 

Acetoacetoxylidide 

I'-Acetonaphthone 

Acetone phenylhydrazone 

Acetophenone, tech 

p-Acetotoluidide 

N-Acetylanthranilic acid 

p-Acetylbenzene sulfonamide 

p-Acetylbenzenesulfonic acid, sodium salt 

p-Acetylbenzenesulfony lure thane 

N'^-Acetylsulfamethoxypyridazine 

N-Acetylsulfanilyl chloride 

Adenine 

Alkylbenzene 

Alkylphenol, mixed 

a-dl-5-Allyl-6-imino-l-methyl-5-(l-methyl-2-pentynyl)- 

barbituric acid. 
Aioinoaceanthryleno[2,l-a]aoeanthrylene-5,13-dione 

*4' -Aminoacetanillde ( Acetyl-p-phenylenediamine) 

3'-Aminoacetophenone 

*5-Amino-2-(p-aminoanilino)benzenesulfonlc acid 

l-Amino-'i-(3-amino-'4-sulfoanilino)-2-anthraqulnonesul- 

fonic acid. 
l-Amlno-4-('i-amino-3-sulfoanilino)-2-anthraquinonesul- 

fonic acid. 
5-Amino-2-anilinobenzenesulfonio acid 

*2-(p-Aminoanllino)-5-nitrobenzenesulfonic acid 

3-Amino-p-anisanilide 

5-Amino-2-o-anisidinobenzenesulfonic acid 

*l-Aminoanthraquinone and salt 

*2-Aminoanthraquinone and salt 

l-Amino-2-anthraquinonecarboxylic acid 

l-Amino-2-anthraqulnonesulfonlc acid 

5(and 8)-Amino-l-anthraquinonesulfonic acid 

N-(4-Amino-l-anthraquinonyl)anthranilic acid 

N-(5-Amino-l-anthraqulnonyl)anthranilic acid 

l-Amino-N^-anthraquinonyl-2-anthraquinonecarboxamide — 
4-Aminoantipyrine 

*6-Amino-3,4-' -azodi(benzenesulfom.c acid) 

8-Aminobenz[a]acridin-7(12H)-one 

^l-Amino-'i-benzamidoanthraquinone 

*l-Amino-5-benzamidoanthraquinone 



ICI. 
TRC. 



DUP. 






G, ICI. 




CTN, 


EKT, 


MRK, SAL, SW. 


FMP, 


UCC. 




FMP, 


UCC. 




FMP, 


UCC. 




FMP. 






GIV. 






DUP. 






ACP, 


UCC. 




ACY. 






DUP. 






LIL. 






LIL. 






LIL. 






ACY. 






ACY, 


CTN, 


MRK, 


AHA. 






ATR, 


MON, 


UCC. 


G. 






LIL. 






ICI. 






DUP, 


G, NAC, TRC. 


SDH. 






om. 


G, TRC, YAW. 


TRC. 






TRC. 






NAC. 






CMC, 


DUP, 


TRC, VPC. 


PCW. 






TRC. 






AAP, 


ACY, 


DUP, G, ICI, MAY, NAC, TRC 


ACY, 


DUP, 


G, NAC, TRC. 


DUP. 






G. 






ICI. 






G. 






DUP. 






G. 






SDW. 






AAP, 


CM3, 


DUP, G, NAC, TRC. 


NAC. 






ACY, 


MAY, 


NAC, TRC. 


G, ICI, NAC, TRC. 



CYCLIC INTERMEDIATES 



65 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



6- [p-( p-Ajninobenzamido) benzamido] -l-naphthol-3-sulfonic 
acid. 

i<6-(p-Amlnobenzaiiiido) -l-naphthol-3 -sulfonic acid 

3' -Aminobenzanilide 

A' -Aminobenzanilide 

»2-Amlno-p-benzenedisulfonio acid [S03H=l] 

o-Amlnobenzenethiol 

2-Aininobenz imidazole 

5-Amino-2(3H) -benzimidazolone 

p-Aminobenzoic acid, tech 

p-Aminobenzoic acid, diethylami noethyl ester (Procaine) — 

2-Aiiiino-6-benzothiazoleoarboxylic acid 

l-Amino-2-bromo-4-('i' -aminoanilino)anthraquinone-5(and 8)- 

sulfonic acid. 
5(and 8) -Amino-8( and 5) -bromo-l,6(and 1,7) -anthraquinone- 
disulTonio acid. 

*l-Amino-4-bromo-2-anthraquinonesulfonic acid and sodium 
salt. 

l-Amino-4-bromo(benzamdo)anthraquinone 

2-Amino-l-bromo-3-chloroanthraquinone 

»l-Amino-2-bromo-<i-hydroxyanthraquinone 

l-Amino-4-bromo-2-methylanthraquinone 

l-Amino-2-bromo-4-(p-toluidino)anthraquinone 

l-Amino-2-chloroanthraqulnone 

»l-Amino-5-chloroanthraquinone 

l-Amino-8-chloroanthraquinone 

2-Amino-l-chloroanthraquinone 

»2-Amino-3-chloroanthraquinone 

A-Amino-6-chloro-m-benzenedisulfonamide 

4-Amino-6-chloro-m-benzenedisulfonamide hydrochloride 

2-Amlno-5-chlorobenzophenone 

2-Amino-6-chlorobenzothlazole hydrochloride 

«o-(3-Amino-4-ohlorobenzoyl) benzoic acid 

2-Amino-5-ohloro-p-c\imenesulfonic acid 

2-Amino-5-ohloro-4-ethylbenzenesulfonic acid 

l-Amino-2-chloro-4-hydroxyanthraquinone 

2-Amlno-4-ohloro-6-nitrophenol 

2-Amino-4-chlorophenol 

«6-Amino-4-chloro-l-phenol-2 -sulfonic acid 

2-Amino-6-chloropyrazine 

3-Amino-6-chloropyridazine 

«6-Amino-<*-chloro-m-toluenesulfonic acid [S03H=l] 

»2-Amiuo-5-chloro-p-toluenesulfonic acid [S(iH=l] 

2-Amino-p-cresol 

»l-Amino-2,'4-dibromoanthraquinone 

l-Amino-2,4— dibromoanthraquinone-5(and 8) -sulfonic acid— 

<i'-Amino-2',5'-diethoxybenzanilide 

5-Amino-2-(2,3-dihydro-2-oxobenzimidazol-5-ylamino) - 
benzenesulfonic acid. 

4--Amino-l,3-dihydroxyanthraquinone 

2-Amino-4-( dime thy Ibenzyl) phenol 

3-Amino-9-ethylcarbazole 

p-Amino-N-ethyl-N-l-naphthylbenzamide 

2-Aiiilno-N-ethyl-5-nltrobenzenesulfonanilide 

Aminoethylpiperazine 

l-Amino-4-hydroxyanthraquinone 

2-Amino-3-hydroxyanthraqulnone 



DUP. 

DUP, G, NAC, TRC, VPC. 

DUP. 

0, TRC. 

DUP, G, NAC, TRC. 

GAM. 

EK. 

DUP. 

DUP, G. 

SDW. 

DUP. 

ICI. 

TRC. 

AAP, DUP, G, ICI, NAC, TRC. 

AAP. 

ICI, MAY. 

AAP, DUP, ICC, TRC. 

ICI. 

G, ICI. 

AAP. 

ACY, DUP, ICI, MAY, NAC, TRC. 

DUP, NAC. 

DUP, G. 

G, ICI, MAY. 

ABB. 

ABB. 

ICI. 

DUP. 

AAP, G, ICI, MAY. 

SW. 

ACY. 

AAP. 

CMG. 

G, MEE, NAC. 

CMl, NAC, TRC. 

ACY. 

ACY. 

ACY, DUP, HSC, NAC, SW. 

ACY, HSC, SW. 

TRC. 

AAP, DUP, G, ICI, NAC, TRC. 

ICI. 

G. 

DUP. 

G, TRC. 
TRC. 
AAP. 
G. 
G. 

UCC. 
AAP, G. 
G, NAC. 



66 



SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 7B -Cyclic intermediates for which U.S. production or sales were reported, identified by 
lAauc. ID. y manufacturer, 1 964 — Continued 



8- K-( 8-Aiiiino-l-hydroxy-3,6-disuLfo-2-naphthylazo) -5- 
methoxy-o-tolylazo]-l-naphthol-3,6-disulfonic acid, 

benzenesuLfonate. 
l-Amlno-i-[in-(2-hydroxyethylsulfonyl)anilinoJ-2-anthra- 

quinonesulfonio acid. 
3'-Amino-2'-hydroxy-5'-nitroacetaiillide 

2-( 2-Aiiiino-5-hydroxy-7-sulf o-1-naphthylazo) -5-nitro- 

benzoic acid. 
l-(6-Amino-l-hydroxy-3-sulfo-2-naphthylazo)-6-nitro-2- 

naphthol-4--suLfonio acid. 

S-Amlnoisophthalic acid 

2-Aiiiino-N-isopropyl-l-phenol^-suironainide 

4-Ainino-3-(|3-methanesuLfanaiiiidoethyl)-N,N-diethylaniline 

hydrochloride . 
N-(4-Amino-3-methoxy-l-anthraquinonyl)-p-toluenesuiron- 

ajmide. 
5-Amino-6-methoxy-2-naphthalenesulfonic acid 

m-("i-Aniino-3-methoxyphenylazo)benzenesulfonic acid 

8-Ainino-6-methoxyquinoline 

l-Amino-2-methoxy-4-(p-toluenesulfonainldo)anthraquinone 

3-(4-Amino-5-methoxy-o-tQlylazo)-l,5-naphthalenedisulfonic 

acid. 
7-(4-Amino-5-methoxy-o-tolylazo)-l,3-naphthalenedisulfonic 

acid. . ,„ 

8-('!K-Amino-5-methoxy-o-tolylazo)-l-naphthol-3,6-disulfonic 

acid, benzenesuLfonate. 

*4'-Aiiiino-N-methylacetanilide 

l-Aniino-2-methylanthraquinone 

2-Amino-5-(6-methyl-2-benzothiazolyl)benzenesulfonic acid— 
A-Mino-4'-(3-methyl-5-oxo-2-pyTazolin-l-yl)-2,2'-stilbene- 

disulfonic acid. 

2-Aiiiino-5-methylpyridine 

2-Ainino-6-metl:^lpyTidine 7 " 

2-Ainino-4-methylpyTimidine (2-Amino-4.-methyldiazine) 

2-Amino^-Cmethylsulfonyl) phenol 

2-Aiiiino-5-methyl-l,3,A-thiadiazole 

l-Amlno-2-methyl-A-(p-toluidino)anthraquinone 

l-Aminonaphth[2,3-c]aoridan-5,8,14-trione 

4-AiBinonaphth[2,3-c]acridan-5,8,lA-trione 

6-Aminonaphth[2,3-c]acridan-5,8,li(13H)trione 

*2-Aiiiino-l,5-naphthalenedisulfonic acid 

»3-Aiiiino-l,5-naphthalenedisuironic acid (Cassella acid) 

3-Amno-2,7-naphthalenedisulfonio acid 

4-Ainino-l,5-naphthalenedisuironic acid 

'i-Amlno-l,6-naphthalenedisulfonic acid 

*6-Ainino-l,3-naphthalenedisulfonic acid (Amino I acid) 

7-Aniino-l,3-naphthalenedisulfonic acid (Amino G acid) 

l-Amino-2-naphthalenesulfonic acid (o-Naphthionlo acid) 

*2-Amlno-l-naphthalenesuli'onic acid (Tobias acid) 

4(and 5)-Aim.no-l-naphthalenesulfonio acid 

5-Amino-l-naphthalenesulfonic acid (Laurent's acid) 

*5-Aniino-2-naphthalenesulfonlc acid (l,6-01eve's acid) 

*5(and 8) -Aiiiino-2-naphthalenesulf onio acid (Cleve's acid, 
mixed) . 

*6-Amino-2-naphthalenesulfonic acid (Broenner's acid) 

»8-Amlno-l-naphthalenesulfonio acid (Peri acid) 

*8-Amlno-2-naphthalenesulfonic acid (l,7-Cleve's acid) 

7-Amino-l,3,6-naphthalenetrisulfonic acid 

8-Amino-l,3,6-naphthalenetrisulfonic acid (Koch's acid) — 



Manufacturers' identification codes 
(according to list in table 22) 



TRC. 
TRC. 



G. 

TRC. 

EKT. 

DUP. 

NAC, TRC. 
DUP, TRC. 
SDW. 
AAP, G. 
TRC. 

TRC. 



CM3, 


G, NAC. 


DUP, 


ICI. 




G. 






TRC. 






RIL. 






NEP, 


RIL. 




ACY. 






NAC, 


TRC. 




ACY. 






ICI. 






DUP. 






DUP. 






G. 






ACY, 


SDH, 


SW. 


G, NAC, TRC. 


TRC. 






NAC. 






DUP. 






ACY, 


DUP, 


G, NAC, TRC. 


ACY, 


DUP, 


G, NAC, TRC 


DUP. 






ACY, 


HSC, 


IMP, SW. 


ACY, 


TRC. 




DUP. 






ALL, 


DUP, 


G, NAC, TRC 


ALL, 


DUP, 


G, NAC, TRC 


KLS 


NAC, 


SNA. 


DUP, 


NAC, 


SDC, TRC. 


ALL 


DUP, 


G, NAC, TRC 


DUP 






DUP 


NAC. 





CYCLIC INTERMEDIATES 



67 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



4--Amino-l,3,5-naphthalenetrisulfonio acid, 4,5-sultam, 

trlsodium salt. 
8- Amino-l- naphthoic acid 

5-Amino-l-naphthol 

5 (and 8)-Amino-2-naphthol 

»8-Amino-2-naphthol 

8-JSniino-l-naphthol-3,6-diEulfonio acid, benzenesulfonate- 
7-Amino-l-naphthol-3,6-disulfonic acid (2R acid), mono- 
sodium salt. 
*8-Amino-l-naphthol-3,6-disulfonic acid (H acid), mono- 
sodium salt. 
8-Anino-l-naphthol-5,7-disulfonic acid (Chicago acid) 
(2S acid), monosodium salt. 

»l-Aiiino-2-naphthol-4-sulfonic acid (1,2,4-acid) 

*6-Aiiino-l-naphthol-3-sulfonic acid (J acid), sodium salt- 
*7- Amino- l-naphthol-3-sulfonic acid (Gamma acid), sodium 
salt. 
8-Amino-l-naphthol-5-sulfonic acid (S acid), sodium salt- 

3-Jtoiino-5-(m-nitrobenzamido)-p-toluenesulfonic acid 

*2-Mino-5-nltrotienzenesulfonic acid[S03H=l] 

4-Amino-3-nitrobenzoic acid 

*2- Amino— 4-nitrophenol 

2-Amino-5-nitrophenol 

4--Amino-2-nitrophenol 

i -2- Amino-l- (p-nitrophenyl)-l,3-propanediol 

4-Amino-4-'-nitro-2,2'-stil'benedisulfonic acid 

2-Amino-5-nitrothiazole 

3'-Aminooxanilic acid 

4' -Aminooxanilio acid 

3-Amino-2-oxazolidlnone 

p-Aminophenethyl alcohol 

5-Amino-2-o-phenetidinobenzenesulfonio acid, sodium salt- 

o-Aminophenol 

p-Aminophenol 

*2-Amino-l-phenol-4-sulfonamide 

2-Amino-l-phenol-4-sulfonanilide 

*2 -Amino- l-phenol-4-sulfonic acid 

m-(p-Aminophenylazo)benzenesulfonio acid 

*p-(p-Aminophenylazo)benzenesulfonic acid 

7-(4-Aminophenylazo)-l,3-naphthalenedisulfonic acid 

5-(p-Aminophenylazo) salicylic acid 

2-(p-Aminophenyl)-6-methylbenzothiazole 

2-(p-Aminophenyl) -6-methyl-7-benzothiazolesulfonic acid 
and salt. 

l-(m-Aminophenyl) -5-oxo-2-pyrazoline-3-carboxylio acid 

2-Aminopyridine 

4-Aminopyridine 

2-Aminopyrimidine 

3-Aminoquinoline 

5-Aminosalicylio acid 

N-(4-Amino-3-sulfo,anthraqulnonyl) anthranilio acid 

3'-(3-Amino-4-sulfophenylsulfamoyl)-3"-sulfamoyl-3- 
phthalocyaninesulfonic acid, copper derivative. 

2-Aminothiazole 

3-Amino-p-toluamide 

l-Amino-4- (p- toluene sulfonamido) -2- anthraquinonesulf onic 

acid. 
l-Amlno-4-(p-toluenesulfonamido)-2-anthraquinone sulfonic 

acid, sodium salt. 
5-Amino-o-toluenesulfonanilide 



Manufacturers' identification codes 
(according to list in table 22) 



G. 






NAG 






G. 






ALL, 


CMG 


DUP, G, TRC, VPC 


TRC. 






DUP, 


NAC. 




DUP, 


MON, 


NAC. 


DUP, 


NAC. 




ACY, 


G, NAC, TRC, VPC. 


CMG, 


DUP, 


G, NAC, TRC. 


DUP, 


G, NAC, TRC. 


NAG. 






G. 






ACY, 


DUP, 


G, NAC, TRC. 


DUP. 






DUP, 


G, NAC, TRC. 


NAC. 






ACY. 






PD. 






DUP, 


NAC, 


TRC. 


ACY, 


EKT. 




CMG. 






DUP. 






NOR. 






EKT. 






NAC. 






FMT. 






ABB, 


DUP, 


SDC. 


CMG, 


DUP, 


NAC, TRC, VPC. 


TRC. 






AAP, 


CWN, 


DUP, NAC, TRC. 


AAP, 


TRC. 




ACY, 


CMG, 


DUP, G, NAC, TRC. 


TRC. 






VPC. 






DUP, 


NAC. 




DUP, 


TRC. 




VPC. 






NEP, 


RIL. 




RIL. 






ACY. 






EK. 






AAP, 


TRC. 




G. 






DUP. 






ACY, 


MRK. 




SDH. 






AAP. 







DUP, G. 



SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE IB. -Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i964~Continued 



Chemical 



*4-Andno-m-toluenesulfonie aoid[S03H=l] ----- 

»6-Amino-m-toluenesulfoiiio acid [S03H=1] 

5-Amino-2-(p-toluidino)benzenesulfonic acid 

m-(4-Amino-3-tolylazo)'benzenesulfonio acid 

3- (4-Amino-o-tolylazo) -1, 5-naphthalenedisulf onic acid — 

A-U-Amino-m-tolylazoi-m-toluenesulfonic acid 

*16-Aininoviolaiithrone 

»2-Amino-3,5-xylenesiilfonio acid [S03H=1J 

5-Ajm.no-2,4-xylenesulfonic acid -• 

<;-Amino-2,6-xylenol 

■^Aniline (Aniline oil) "' 

Aniline hydrochloride ~ 

l-Anilino-2-anthraquinonecar"boxylic acid 

*Anilinomethanesulfonic acid and salt --- 

*8-Anilino-l-naphthalenesulfonlc acid (Phenyl pen aoidj 

«6-Anilino-l-naphthol-3-sulfonio acid (Phenyl J acid) — 

7-Anilino-l-naphthol-3-sulfonic acid (Phenyl gamma acid 

Anisic acid 

o-Anisic acid 

m-Anisidine 

*o-Anisidine 

p-Anisidine 

l-p-Anisidino-A-hydroxyanthraquinone 

«o-Anisidinomethanesulfonio acid 

2-o-Anisidlno-5-nitrobenzenesulfonic acid 

p-Anisoin 

Anisole, tech 

Anthracene, refined " 

Anthraflavic acid (2,6-Dihydroxyanthraq\u.none) -- 

Anthranilic acid (o-Aminobenzoic acid) 

*Anthra[l,9]pyrazol-6(2H)-one (Pyrazoleanthrone) 

*Anthraquinone , 100^ 

2-Anthraquinonecar'boxylio acid 

*1, 5-Anthraquinonedisulf onic acid 

1,5-Anthraquinonedisulfonic acid, disodium salt 

1 5(and 1,8)-Anthraquinonedisulfonio acid and salt 

1,8-Anthraquinonedisulfonic acid 

»l,8-Anthraq\iinonedisulfonic acid, potassium salt 

*2,6-Anthraquinonedisulfonic acid and salt 

*l-Anthraquinonesulfonic acid and salt 

2-Anthraquinonesulfonic acid and salt (Silver salt) 

l,l'-[l,5(!"i<J 1,8) -Anthr aqulnonylenediamino] bisnaphth- 
' [2,3-c] aoridan-5,8,U-trione. 

N,N'-(1,5-Anthraqulnonylene)dianthranilio acid 

N,N '-(l,5-Anthraquinonylene)dioxamic acid 

l-(l-Anthraquinonyl) -1,2-hydrazinedisulf onic acid, 
disodium salt. 

*Anthrarufin (1,5-Dihydroxyanthraquinone)- 

Anthrone 

Arsanilio acid and salt, tech 

4', 4' ' '-Azobis [4-biphenylcarboxylic acid] 

Barbituric acid 

Barbituric acid, sodium derivative : 

«Benzaldehyde , tech - 

4-(4-Benzamido-l-anthraquinonylamino)naphth [2,3-oJ - 

acridan-5 ,8, K-trione . 
N-(5-Benzamido-l-anthraquinonyl)-p-toluenesulfonamide- 

l-Benzamido-4-chloroanthraquinone 

*l-Benzamido-5-chloroanthraquinone 



Manufacturers' identification codes 
(according to list in table 22) 



ACY, DUP, G, SDH, SNA. 

DUP, HSC, MAC, SW. 

DUP, MAC, TRC. 

TRC. 

TRC. 

MAC. 

ACY, G, TRC. 

DUP, NAC, SDH, STG, WJ. 

DUP. 

UPJ, X. 

ACY, DOW, DUP, NAC. 

ACY. 

NAC. 

AAP, ACY, DUP, NAC, TRC. 

CMG, DUP, NAC, SDC. 

ALT, CMG, DUP, G, NAC, TRC. 

DUP, G, NAC. 

HN, ICO. 

ACY. 

EK. 

AAP, ALL, DUP, KIS, MON. 

DUP, HON. 

AAP. 

AAP, DUP, G, NAC, TRC, VPC. 

TRC. 

CTN. 

DUP, LIL. 

ACP. 

DUP, G, TRC. 

DUP, LEM, MKE, NAC. 

DUP, G, TRC. 

ACY, DUP, G, TRC. 

ACY, NAC. 

ACY, DUP, ICI, TRC. 

DUP, G, TRC. 

DUP, TRC. 

DUP. 

G, ICI, TRC. 

AAP, DUP, G, ICI, NAC, TRC, VPC. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC. 

DUP, NAC. 

DUP. 

DUP, ICI. 
G, MEE, TRC. 
DUP, G. 

ACY, CMG, DUP, G, NAC, TRC. 

ICI. 

ABB. 

DUP, G, TRC. 

KF, LIL. 

ABB, KF. 

BPC, HN, TNP. 

DUP. 

ICI. 

DUP, G. 

ACY, DUP, G, ICI, MAY, NAC, TRC. 



CYCLIC INTERMEDIATES 



69 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer , 1964 — Continued 



l-(4-Benzamido-2,5-diethoxjrphenyl)-3-methyl-3-(2-sulfo- 

ethyl) triazene. 
[ 3- (4-Benzaniido-6-methoxy-ni-tolyl ) -l-methyltriazen-3-yl] - 
acetic acid. 

8-Benzamido-l-naphthol-3,5-disulfonic acid 

3-Benzamido-l-naphthol-3-sulfonic acid 

Benzanilide 

*7H-Benz [de] anthraoen-7-one ( Benzanthrone ) 

Benzeneboronic acid 

m-Benzenedisulfonic acid 

Benzenesulfonamide 

Benzenesulfonic acid 

Benzenesulfonio acid, 2-propyn-l-ol ester 

Benzenesulfonyl chloride " 

1,2,4— Benzenetrioarboxy lie acid, 1,2-anhydride 

Benzhydrol (Diphenylmethanol) 

Benzidine base 

^Benzidine hydrochloride and sulfate 

Benzil (Bibenzoyl) 

Benzilic acid 

2-Benzofuranacetonitrile 

^Benzoic acid, tech 

Benzoic anhydride 

Benzoin 

Benzonitrile 

Benzophenonetetracarboxylic dianhydride 

Benzo[b] thiophen-3(2H)-one 

IH-Benzotriazole 

Benzoylacetio acid, ethyl ester 

»o-Benzoylbenzoic acid 

Benzoyl chloride 

'i-Benzoyl-3-hydroxyphenyl methacrylate 

2-Benzoyl-'4-sulfobenzoic acid 

2-Benzoyl-4' -(p-toluenesulfonanildo)acetanilide 

Benzylamine 

dl-Benzyl-2-aid.no-l-propanol 

<+-Benzyl-6-chloro-3-keto-2-methyl-7-sulfamyl-l,2,4-benzyl- 

thiadiazine-1, 1-dioxide . 
4-Benzyl-6-chloro-3-keto-7-sulfamyl-l,2,4-benzylthia- 
diazine-1, 1-dioxide. 

Benzyl disulfide 

Benzylethanolamine 

Benzyl ether (Dibenzyl ether) 

4-(N-Benzyl-N-ethylamino)-o-toluenesulfonio acid 

N-Benzyl-N-ethyl-m-toluidine 

Benzylidene phthalide 

4- Benzylidineiminoantipyrine 

p-(Benzyloxy)phenol 

Benzyl polysulfide 

Benzyltrimethylammonium hydroxide 

Benzyltrimethylammonium methoxide 

*3,3'-Bianthra[l,9]pyrazole-6,6'-(2H,2'H)dione (Fyrazole- 
anthrone yellow) . 
[3,3'-Bi-7H-benz[de] anthracen] -7,7' -dione 

*[4,4'-Bl-7H-benz[de] anthracen] -7,7' -dione 

endo-cis-Bicyolo[2.2.1]hept-5-ene-2,3-dloarboxyllc 
anhydride . 

*[1,1' -Binaphthalene]-8,8'-dicarboxyllc acid 

Biphenyl 

2,2',4,4'-Biphenyltetrol 



Manufacturers ' identification codes 
(according to list in table 22) 



ACY, ATL, CMG, DUP, G, ICI, MAY, NAG, SDC, TEC. 



G. 

TRC 
TRC 
DUP 

AAP; 

EDO- 
KPT 
NES, 
EK, 
ABB, 
NES. 
ACC. 
ARAj 
MAC, 
OWN, 
HN, 

BPG; 

EK. 

ACC; 

EK. 

BPC, 

TNP, 

GOG. 

G. 

MEE. 

FMP. 

ACY, 

HK, 

X. 

DUP. 

EK. 

ICO, 

LIL. 

ABB. 

ABB. 



GCW. 

MLS. 

BPC, TBK. 

NAC. 

DUP, NAC. 

LIL. 

SDW. 

EK. 

HK. 

MLS. 

MLS. 

DUP, G, TRC. 

DUP. 

ACY, DUP, ICI, MAY. 

MAC. 

DUP, G, NAC. 
DOW, MON. 
IDC. 



FIN, LAK, NAC, X. 

LEM. 
LEM. 

FRO, HK, HN, MON, TNP. 

HN. 



DUP, G, NAC. 
HN, TNP. 



70 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



Manufacturers' Identification codes 
(according to list in table 22) 



2,2' -Biquinoline 

»l,4--Bis[l-anthraquinonylamino]anthraquinone 

Iji-Bis [l-anthraquinonylamino] anthraquinone and 

1,4— Bis [ 5 -chloro-l-anthraquinonylamino] anthraquinone 

(mixed) . 

1,5-Bis [1-anthraqulnonylamino] anthraquinone 

Bis[l-anthraquinonylamlno] violanthrene 

a^,a^ -Bis[5-tert-butyl-6-hydroxy-ra-tolyl] mesitol 

N,N' -Bis[l-chloro-2-anthraquinonyl] -4' ,4" ' -azol)is-[4-bi- 

phenylcarboxamlde] . 
Bis(chloro sulf onyl)phthalocyaninedisulfonic acid, copper 

derivative . 

4,4' -Bis[diethylamino]benzhydrol 

4,4' -Bis[diethylamino]benzhydrol, 2,6-naphthalene- 

disulfonate. 
4,4' -Bis [diethylamino]benzhydrol salt, 2,7-naphthalene- 

disulfonic acid mixture. 

4,4' -Bis[diethylamino]benzophenone (Ethyl ketone base) 

4-Bis [ ( p -die thy laminophenyl) methyl ] -2 , 7-naphthalene - 

disulfonic acid, leuco form. 

4,4' -Bis[dimethylamino] benzhydrol (Michler's hydrol) 

*4,4' -Bis[dimethylamino] benzophenone (Michler's ketone) 

Bis[p-dimethylaminophenyl]methanesulfonic acid and salt — 
l,5(and 1,8) -Bis[2,4-dinitrophenoxy ]-4,8(and 4,5)-di- 

nitroanthraquinone . 
4,4' -Bis[p-hydroxyphenylazo]-2,2' -stilbenedisulfonic acid- 

4,4' -Bis[p-hydroxyphenyl]valeric acid 

2,4-Bis(methylsulfamyl)-5-chloroaniline 

Bis (o-nitrophenyl) sulf ide 

m-Bis(m-phenoxyphenoxy) benzene 

2-Bromoaoetophenone 

p-Bromoaniline 

4-Bromoanlsole 

*3-Bromo-7H-benz[de]anthracen-7-one (Bromobenzanthrone) 

Bromobenzene , mono- 

p-Bromobenzenesulf onyl chloride 

Bromobenzoic acid 

o-Bromobenzoic acid 

4 -Bromobenzophenone 

6-Bromo-5-chlorobenzoxazolone 

2 -Bromo-6-chloro-4-nitro aniline 

Bromocyclopentane 

2-Bromodibenzofuran 

2-Bromo -4, 6-dinitro aniline 

Bromoethylbenzene 

2-Bromo-3'-hydroxyacetophenone, benzoate 

l-Bromo-4-(N-methylacetamido) anthraquinone 

l-Bromo-4-me thy laminoanthraqui none 

6-Bromo-3-methyl-7H-dibenz[f ,ij] isoquinQline-2,7(3H) - 

dione. 

1-Bromonaphthalene 

4-Bromonaphthalic anhydride 

l-(9-Bromo-7-oxo-7H-benz[de] anthracen-3-ylamino) anthra- 
quinone . 

p-Bromophenol 

(p-Bromophenyl)aoetonitrile 

(p-Bromophenyl) hydrazine hydrochloride 

2-Bromopyridine 



ACY, DUP, G, MAY, NAC, TRC. 
TRC. 



DUP, NAC. 



DUP, TRC. 

SDH. 
TRC. 

SDH. 

DUP, G, NAC, SDH. 

NAC. 

DUP. 

TRC. 
JNS. 



ICO, OPC. 

ACY, DUP, G, MAY. 

DOW. 

EK. 

RSA. 

EK. 

ICO. 

MEE. 

AAP. 

UL. 

G. 

TRC. 

DOW. 

SDH. 

G. 

AAP, DUP, G. 

G. 



CYCLIC INTERMEDIATES 

■Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer , i 554— Continued 



a-Bromotoluene 

p-Bromotoluene 

l-Bromo-2,'i,6-triethylbenzene 

p-Butoxyphenol 

<i-[3-(p-Butoxyphenoxy)propyl] morpholine 

4-'-Butoxy-2-piperidinopropiophenone hydrochloride 

p-n-Butylaminobenzolc acid, ethyl ester 

p-Butylaniline 

2-tert-Butylanthraquinone 

p-tert-Butyltenzaldehyde 

n-Butylbenzene 

seo-Butylbenzene 

tert-Butylbenzene 

p-tert-Butylbenzoio acid 

o-(p-tert-Butylbenzoyl)benzoic acid 

6-Butyl-m-cresol [OH=l] 

6-tert-Butyl-m-cresol 

2-tert-Butyl-p-cresol 

2' -tert-Butyl-4-' ,6'-dimethylacetophenone 

2-tert-Butyl-4-ethylphenol 

N'-Butyl-'i-methoxymetanilamide 

N'''-Butyl-4--methoxymetam.lamide 

2-tert-Butyl-5-methylamsole 

»o-seo-Butylphenol 

p-seo-Butylphenol 

o-tert-Butylphenol 

p-tert-Butylphenol 

Butylphenols, mixed 

p-tert-Butyltoluene 

5-tert-Butyl-l,2,3-triinethylbenzene 

5-tert-Butyl-m- xylene 

6-tert-Butyl-2,4-xylenol 

Butyrophenone 

^Camphoric acid 

Camphoric anhydride 

Camphosulfonic acid 

Carbazole, refined 

Carbonic acid, diphenyl ester 

1- (4- Carbonyl-o- anisyl) -3-methyl-3- ( 2-sulf oethyl) triazene- 

2,4- '-Carbonyldibenzoic acid 

6(and 2 ) - Carboxybenzene-2 ( and <V)-diazo-l-oxide 

5 -(o-Carboxybenzoyl)-2-ohlorooxanilic acid 

3-Carboxy-2(and 4)-hydroxybenzenediazonium sulfate 

3-(Carboxymethyl-3-methyl)-l-p-tolyltriazene 

o-(Carboxymethylthlo)benzoio acid 

5-(o-Carboxyphenylsulfamoyl)anthranilic acid 

[ (o-Carboxyphenyl)thio]ethylmercury 

3-(2-Carboxy-4-sulfophenyl)-l-(2,5-dichlorophenyl)- 

3-ethyltriazene. 
3-(2-Carboxy-<t-Eulfophenyl)-l-(5-dimethylsulfamoyl-o- 

tolyl) -3-methyltriazene. 
3-(2-Carboxy-4-sulfophenyl)-3-ethyl-l-(5-nitro-o-aniEyl)- 
triazene. 

Cedrene 

Chelidamic acid 

Chlorendic acid 

2'-Chloroacetoacetanilide 

ci-Chloroacetophenone 

2'-Chloroacetophenone 

3'-Chloroacetophenone 

4' -Chloroacetophenone 

4' -(Chloroaoetyl)acetanilide 

m-Chloroaniline 

o-Chloroaniline 

p-Chloroaniline 



Marnif acturers ' identification codes 
(according to list In table 22) 



BPC, 


EK. 




BPC. 






DUP. 






ABB. 






ABB. 






ICO. 






ICO. 






DUP. 






DUP. 






GIV. 






PLC. 






PLC. 






PLC. 






SHC. 






DUP. 






KPT. 






PIT. 






ACY. 






GIV. 






ACY. 






KLS. 






G. 






GIV. 






DOW, 


PRD, 


TNA. 


DOW. 






TNA. 






DOW, 


KPT, 


PRD, UCP 


DOW. 






GIV, 


SHC. 




GIV. 






GIV, 


x. 




KPT, 


PIT. 




TBK. 






FIN, 


OTC, 


PYL. 


FIN, 


OTC. 




OTC, 


PYL. 




SDC. 






BKL. 






G. 






ACY. 
DUP. 







G, NAC. 



TRC. 
LIL. 



G. 

G. 

GIV. 

SDW. 

HK. 

FMP, UCC. 

EK. 

EK. 

RBC. 

LIL. 

DUP. 

DUP, G. 

DUP, MON. 

DUP, MON. 



72 SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 7B. —Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer , i 564— Continued 



2-(Chloroamllno)ethanol 

3-(o-Chloroaiiilino)propionitrile 

5-CM.oro-o-anisidlne [NH2=l] (4-Chloro-o-amsidlne 

[0CH3=l] ) . 

5-Chloro-o-£misldine hydrochloride 

/i-Chloroanthranillo acid 

*l-Chloroanthraquinone 

*2-Chloroanthraquinone 

m-Chlorobenzaldehyde 

o-Chlorohenzaldehyde 

p-Chlorobenzaldehyde """ 

Chloro-7H-benz[ de ] anthrao en-7-one ( Chlorobenzanthrone ) — 

*Chlorobenzene , mono- 

l-Chlorobenzene-4-niethylsulfone 

4-Chlorobenzenesulfinic acid 

p-Chlorobenzenesulfonamide 

l-(4-Chlorobenzhydrol)-4-methylpiperazine 

o-Chlorobenzoic acid 

5-Chloro-2-benzoxazolinone 

»o-(p-Chlorobenzoyl)benzoic acid 

o-(p-Chlorobenzoyl) chloride 

p-Chlorobenzoyl chloride 

4,<i'-(o-Chlorobenzylidene)di-2,5-xylidine 

Chloro-(p-chlorophenyl)phenylmethaiie 

Chlorocyolohexane 

2-Chloro-l,4-dibutoxy-5-nitrobenzene 

2-Chloro-l,A-diethoxy-5-nitrobenzene 

2-Chloro-N,N-diethyl-4-nitroamllne 

N- (3-Chloro-9 ,10-dihydroxy-2-aiithryl) acetamide-bis [ acid 
sulfate] . 

A' -Chloro-2' ,5' -dimethoxyaoetoacetanilide 

4-Chloro-2,5-dimethoxyamline 

5-Chloro-2,4-dimethoxy aniline 

4-Chloro-N,N-diinethyl-3-nitrobenzenesulfonamide 

5-Chloro-4,7-dimethyl-3(2H)-thiaiiaphthenone 

»l-Chloro-2,4-dinitrobenzene (Dinitrochlorobenzene ) 

l-Chloro-2,4-diiiitrobenzene and 2-chloro-l,3-dim.tro- 
benzene mixtiire. 

3-Chloro-4,6-dinitrobenzenesulfonio acid 

3-Chlorodiphenylainine 

Chlorodiphenylmethane 

a-Chloro-o(aiid/or p ) -dodeoyltoluene [CH3=l] 

4-[(2-Chloroethyl)ethylamino]-o-tolualdehyde 

p- [(2-Chloroethyl)methylaiiiino]benzaldehyde 

2-Chloro-N-ethyl-5-nitrobenzenesulfonanilide 

Chloroformio acid, benzyl ester 

Chloroformlc acid, phenyl ester 

4-Chloro-3-hydrazinobenzenesulfonic acid 

l-Chloro-4-hydroxyaiithraquinone 

5'-Chloro-3-hydroxy-2-naphthol-o-anlsidide 

3-Chloro-4-hydroxyquinoline-3,4-carbonio acid 

6-Chloroisatoic anhydride 

o-Chloro-a-[ (isopropylamino) methyl] benzyl alcohol 
hydrochloride . 

4-Chloro-N-isopropyl-3-nitrobenzenesulfonamide 

5-Chlorometanilio acid 

»6-Chlorometanilic acid 

5-Chloro-2-methoxybenzenediazonium chloride 



Manufacturers' identification codes 
(according to list in table 22) 



EKT. 
DUP. 
BUG, KI£. 



DUP. 

ACT, DUP, G, ICI, MA.Y, NAG, TRC. 

ACY, G, NAG, TRC. 

RSA. 

HN, NAG, SDH. 

HN. 

AGY, DUP. 

AGS, DOW, DUP, GGY, HK, HKD, M3N, IfTO, QMC, PPG. 

TRG. 

TRC. 

ACY. 

ABB. 

HN, SDH. 



AGY, DUP, G, IGI, NAG. 

HN. 

HN. 

G. 

OPG, TBK. 

ACY. 

FMT. 

FMT, G. 

DUP. 



PCW. 

PGW. 

ALL, PCW. 

EEC, G. 

NAG. 

AAP, DUP, NAG, 

DUP. 

TRG. 
SK. 
TBK. 
ORO. 



G. 

RSA. 

EK. 

G. 

ICI. 

PGW. 

SDH. 

MEE. 

LIL. 

TRG. 
NAG. 
AAP, DUP, 



CYCLIC INTERMEDIATES 



73 



TABLE 7B. —Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1964— Continued 



ilamifacturers ' identif loatlon codes 
(according to list in table 22) 



N-(5-Chloro-2-methoxyphenylazo)saroosine 

»l-Chloro-2-methylanthraquinone 

6-Chloro-2-methyl-7-ohlorosulfamoyl-2H-l,2,4-benzo- 
tM.adiazin-3(4H)-one, 1,1-dioxide. 

l-(Chloromethyl)-2,'i-dimethylbenzene 

A-(Chloromethyl)-l,2-dimetl^lbenzene 

S-Chloro-l-methylisatoic anhydride 

6-Chloro-2-methyl-7- (N-methylsulf amoyl) -2H-l,2,<i-benzo- 
thiadiazin-3(4H)-one, 1,1-dioxide. 

a-Chloromethylnaphthalene 

<i-Chloro-3-(3-methyl-5-oxo-2-pyrazolin-l-yl)benzene- 
sulfonic acid. 

2-Chloro-5- ( N-methylsulf amoyl)sulf anllami de 

5-Chloro-2- ( n-methyl ) -sulf ainyl-4-sulf amyl-n-benzylaniline- 

Chloronaphthalenes 

»2-Chloro-4-nitroaniline (o-Chloro-p-nitroaniline) 

4-Chloro-2-nitroaniline (p-Chloro-o-nitroaniline) 

*l-Chloro-5-nitroanthraquinane 

»l-Chloro-8-nitroaiithraquinone 

*l-Cliloro-2-nitrobenzene ( Chloro-o-nitrobenzene ) 

l-Cliloro-2(and 4-) -nitrobenzene (Chloronitrobenzenes, o- 
and p-) . 

*l-Chloro-3-m.trobenzene (Chloro-ra-nitrobenzene) 

*l-Cliloro-4-nitrobenzene ( Chloro-p-nitrobenzene ) 

*4-Chloro-3-nitrobenzenesulf onaTni de 

<i-Chloro-3-nitrobenzenesulfouaiiilide 

2-Chloro-5-m.trobenzenesulfonio acid 

2-Chloro-5-nitrobenzenesulfonic acid, sodium salt 

4— Cliloro-3-nitrobenzenesulfonic acid 

■>«4-Chloro-3-nitrobenzenesulfonyl chloride 

2-Chloro-4— nitrobenzoic acid 

2-Chloro-5-nitrobenzoic acid 

*o-('i— Chloro-3-m.trobenzoyl)benzoic acid 

4-Chloro-2-nitrophenol 

'i-Chloro-6-nitro-l-phenol-2-sulfonic acid 

4-Chloro-3-nitrophenyl methyl sulfone 

2-Chloro-4-nitrotoluene 

2-Chloro-6-nitrotoluene 

»4-Chloro-2-nitrotoluene 

4-Chloro-3-nitrotoluene 

m-Chlorophenol 

o-Chlorophenol 

p-Chlorophenol 

2-Chlorophenothiazine 

p-Chlorophenylacetonitrile 

4— Chloro-(x -phenyl-o-cresol 

4- Chloro-o-phenylenediamine 

3-(o-Chlorophenyl)-5-methyl-4-isoxazole carbonyl chloride — 

3-(o-Chlorophenyl) -5-methyl-4-isoxazolecaj:"boxylic acid 

l-(m-Chlorophenyl)-3-methyl-2-pyrazolin-5-one 

2-Chloro-4-phenylphenol 

p-Chlorophenyl-2-pyridyl carbinol 

4-Chlorophthalic acid 

Chlorophthalic anhydride 

l-(3-Chloropropyl)-4-methylpiperazine 

N'''-(6-Chloro-3-pyTidazinyl)sulfanilamide 



AAP, 


ACY, 


CMG, G, ICI, NAG, TRC 


ABB. 






BPC. 






BPC. 






MEE. 






ABB. 






BPC. 






DUP, 


G. 




ABB. 






ABB. 






G, KPT. 




ACY, 


DOW, 


DUP, HSG. 


DOW, 


DUP, 


VPC. 


ACY, 


DUP, 


MAY, NAG, TRC. 


DUP, 


MAY, 


NAG. 


AAP, 


DUP, 


MON, UPM. 


AAP, 


SDC. 




DUP, 


G, MDN, UPM. 


AAP, 


DUP, 


MDN, UPM. 


AAP, 


DUP, 


EKT, G, ICG, TRC. 


TRC. 






CMG, 


MAC. 




DUP, 


G. 




G, HAG. 




AAP, 


DUP, 


EKT. 


SAL. 






TRC. 






AAP, 


G, ICI, MAC. 


DUP, 


MEE. 




TRC. 






TRC. 






DUP. 






DUP. 






AAP, 


BUG, 


DUP. 


AAP, 


BUG. 




EK. 






DOW, 


MDN. 




DOW, 


ION. 




SK. 






ICO, 


TBK. 




mn. 






mr. 






ICO. 






ICO. 






TRC. 






DOW. 






RIL. 






DUP, 


SW. 




HK. 






SK. 






ACY. 







74 



SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 7B -Cyclic intermediates for which U.S. production or sales were reported, identified by 
■ manufacturer, i 564— Continued 



2-Chloropyridine """^ 

2-Chloroquinlzarin 

7-Chloro-'i-quinollnol 

4— Chlororesorcinol 

2-Chloro-5-sulfamoylbenzoic acid 

8-Chlorotheophylline 

2-Chlorothiaxanthenone 

2-Chlorothiophene 

m-Chlorotoluene 

o-Chlorotoluene 

p- Chlorotoluene 

*o-Chlorotoluene (Benzyl chloride) 

l-Chloro-S-p-toluenesulfonamidoanthraqulnone 

6-Chloro-m-toluldlne 

3-Chloro-o-toluidine [NH2=1] 

4-Chloro-o-toluidine [NH2=l] an<i l^'^^°°h^°='^'^?::'"""';""::T 
*5-Chloro-o-toluldlne [NH2=l] (-V-Chloro-o-toluidme [CH3=1] ) 

*5-Chloro-o-toluidine hydrochloride [NH2=1] """ 

3-Chloro-p-toluidine [NH2=1] 

N-(5-Chloro-o-tolylazo)sarcoslne 

Chloro-p-tolylmercury 

l-(6-Chloro-o-tolyl)-3-methyl-2-pyrazolin-5-one 

l-(5-Chloro-o-tolyl)-l-tetrazene 

(4-Chloro-o-tolylthio) acetic acid 

3-Chloro-a ,a ," -trlf luoro-6-nitrotoluene 

4.-Chloro-a,a,a-trlfluoro-3-nitrotoluene 

p-Chloro-a,a,a-trifluorotoluene 

2-Chloro-l,3,5-trinitrQbenzene 

Chlorotriphenylmethane 

a-Chloro-p-xylene 

2-Chloro-p-xylene 

A-Chloro-2,5-xylenesulfonyl chloride 

4-Chloro-3,5-xylenol 

6-Chloro-3,'i-xylylmethylcarbainate 

4-Chloro-2,5-xylylthioacetic acid 

Cholic acid 

Chrysazin (1,8-Dihydroxyanthraquinone) 

Cinnamoyl chloride 

s-Collidine (2,4,6-Trimethylpyridine) 

*Cresols:-'- 

m-Cresol 

o-Cresol: 

From coal tar 

From petroleum 

p-Cresol 

Cresols, mixed: ■"■ 
*(m,p)-Cresol: 

From coal tar 

From petroleum 

*(o,m,p)-Cresol: 

From coal tar 

From petroleum 

2,3-Cresotic acid 

»Cresylic acid, refined: ■"■ 

*From coal tar 

*From petroleum 

See footnote at end of table. 



Manufacturers ' identification codes 
(according to list in table 22) 



FMI, 


NEP. 




iSR. 






SDW. 






AAP, 


G. 




TRC. 






MAL. 






KF. 






am. 






HK. 






HN. 






HN. 






BPC, 


HK, HN, MON, TNP. 


ICI. 






BUG. 






DUP. 






AAP, 


PCW. 




AAP, 


BUG, 


DUP, NAC, SDH 


ATL, 


AUG, 


BUG, KLS, SDH 


DUP. 






ATL, 


BUG, 


G. 


EK. 






TRC. 






G. 






NAG. 






MEE. 






G. 






HK. 






EK. 






EK. 






BFG. 






DUP. 






G, NAG. 




OTA. 






UPJ. 






NAG. 






SRL, 


WIL. 




DUP, 


G. 




TBK, 


X. 




KPT, 


NAG, 


RIL. 


KPT. 






KPT, 


PRD. 




MER, 


NPC, 


PRD, SW. 


ACY, 


HPC, 


SW. 


AGP, 


KPT, 


PIT, PRD. 


MER, 


NPC, 


PRD. 


AGP 


KPT. 




PIT 


PRD. 




DOW 







AGP, KPT, PRD. 

MER, NPC, PIT, PRD, SHO, SM. 



CYCLIC INTERMEDIATES 



75 



-Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer , 1964 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



Cryptocyanine 

*Cuinene 

2-[p-(2-Cyanoacetiiiiido) phenyl] -6-methyl-7-benzothiazole- 
sulfonic acid. 

N-(P-Cyanoethyl) -N-(P-aoetoxyethyl) aniline 

4--[(2-Cyanoethyl)ethylamino]-o-tolualdehyde 

p-[(2-Cyanoethyl)methylamino]benzaldehyde 

8-Cyano-l-naphthalenesulfonic acid 

Cyanuric chloride 

*Cyclohexane 

1,4--Cyolohexanedicarboxylic acid, dimethyl ester 

1,2-Cyclohexanedicarboxylic anhydride 

1,2-Cyclohexanedione 

*Cyclohexanol 

*Cyclohexanone 

Cyolohexanone oxime 

Cyclohexene 

4--Cyolohexene-l,2-dicarboxiiiiide 

4-Cyolohexene-lj2-dicarboxylic anhydride 

Cyolohexylamine 

p-Cyelohexyloxy benzoic acid 

Cyolohexyl-2-propanone 

N-Cyclohexyltaurate, sodium salt 

Cyclopentanepropionic acid 

Cyclopentanol 

Cyclopentene 

(2-Cyclopenten-l-yl) -2-propanone 

Cyolopentylphenylglycolic acid, methyl ester 

p-Cymene 

Cytosine arabinoside hydrochloride 

Decylbenzene 

Decylphenol 

Dehydroaoetic acid, sodium salt 

Desoxycholic acid 

l,5(and 1,8) -Diacetamidoanthraquinone 

3'-[Di(2-acetoxyethyl)-aminQ]-p-acetophenetidide 

<+,4'-Diaoetylamino-3,3'-dinitrobiphenyl 

N,N-Diaoetyl-4,4' -diaminobiphenyl 

N,N-Diallyloamphoramic acid 

N^,N^-Diallylmelamine 

«1,4— Diaminoanthraquinone 

*l,5-Diaminoanthraquinone 

l,5(and 1,8) -Diaminoanthraquinone 

*2,6-Diaminoanthraquinone 

l,4-Diamino-2,3-anthraquinonedicarbom.trile 

l,"i-Diamino-2,3-anthraquinonedicarboximide 

4,8-Diaininoanthrarufin 

3,3'-Diaminobenzanilide 

3,4--DiaMnobenzanilide 

2,4-Diaminobenzenesulf onic acid [S03H=l] 

2,5-Diaminobenzenesulfonic acid [s03H=l] 

*4,4'-Diamino-2,2'-biphenyldisulfom.o acid ■■ 

3,7-Diaminodibenzothiophenedisulfonic acid, 5,5-dioxide, 
disodium salt. 

Diamlnodibromodi-p-toluidinoanthraquinone 

l,4-Diamino-2,3-dichloroanthraquinone 

l,5-Diamino-4,8-dihydroxyanthraquinone 

l,5(and l,8)-Diamino-4-,8Cand 4-,5)-dihydroxyaiithraquinone — 

4,5-Diamino-l,8-dihydroxyanthraquinone 

4, 8-Diamino-l,5-dihydroxy-2,6-anthraquinonedisulf onic acid 
4,4'-Diamino-3,3' -dimethyltriphenylmethane 



ACC, ACP, CLK, DOW, GOG, HPC, PLC, SHC, SKO, SOG, TX. 
DUP. 

EKT. 

DUP, G. 

DUP, G. 

DUP, G. 

AGY, GGY, NIL. 

CO, DUP, GOG, PLC, PRO, SOG. 

X. 

NAC. 

RSA. 

DUP, MON, NAC. 

DBC, DUP, MON, NAC. 

NAC, X. 

KF, PLC. 

CHO. 

NAC, PTT. 

ABB, JCC, PAS, VGC, X. 

LIL. 

GIV, TBK. 

G. 

AHA. 

LIL. 

PLC. 

LIL. 

AHA. 

HNW, HPC, NAC. 

UP J. 

NAC. 

G. 

GAN. 

WIL. 

AAP. 

TRC. 

AAP. 

AAP. 

wn. 

AGY. 

CMl, DUP, G, NAC, TRC. 

DUP, G, TRC. 

AAP, TRC. 

AAP, DUP, G, NAC, TRC, VPC. 

DUP. 

DUP. 

G, ICC. 

AAP. 

AAP. 

DUP, NAC, TRC. 

TRC. 

AAP, ACY, NAC. 

AGY. 

ICI. 

cue, DUP. 

VPC. 

DUP. 

ICI. 

TRC. 

ACY. 



76 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 7B. 



- Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i554~Continued 



l,4-Dlamino-5-nitroanthraquinone 

2,'i-Dlaiiiino-6-phenyl-s-triazine 

2,6-Dlainlnopyridine 

Mj-i'-Diamino-aja' -stilbenedisulfonlc acid 

Diaminotetrabromoanthraqulnone 

4.,6-Diamino-m-toluenesulfomc acid [SOjHil] 

3,5-Diainino-p-toluenesulfonic acid [S03H=1] 

Di-tert-amylphenoxyacetyl chloride 

1, 5-Diaiiilino-2,5-aiithraquinonedicarboxylic acid 

o-Dianisidine 

N-(o-Dianisidine)methyltaurine 

l,2-Dianthroiiyl-l,2-ethanediol 

Diary Iguanidine 

p- Di azo- N, N- dime thy lani line- 1- aniino-8-naphthol-3- 
sulfonate-6-sulfonic acid, sodium salt. 

1,5-Dibenzaiiiidoanthraquinone 

4,9-Dibenzamido-3' ,4' ,6' ,7' -diphthaloyloarbazole 

*i,5'-Dibenzaiiiido-l,l'-iminodlanthraquinone 

5,5'-Dibenzamido-l,l' ,4,l"-trianthrimide 

2-Dibenzofuranol 

Dibenzothiophene 

«l,5-Dibenzoylnaphthalene 

1' ,2', 6', 7' -Dibenzpyrene-7,14— quinone 

NjN'-Dibenzylethylenediamine 

N,,N'-Dibenzylethylenediamine diacetate 

N, N-Dibenzylsulf anilic acid 

2,4'-Dibromoacetophenone 

*3,9-Dibroino-7H-benz[de] anthraoen-7-one 

m-Dibromobenzene 

p-Dibromobenzene 

2,2'-Dibromobipheiiyl 

Dibromodibenzo[b,def ]chrysene-7,14-dione 

ar-Dibromoethylbenzene 

2,6-Dibromo-l,5-naphthalenediol 

Dibromo-8, 15-pyraiithrenedione 

X,Y-Dibromothianthrene 

Dibromoviolanthrone 

2, 5-Dibutoxy aniline 

2,6-Di-tert-butyl-4-nonylphenol 

2,4-Di-tert-butylphenol 

2,4-Dichloroanlline 

3,4-Dichloroaniline 

*2,5-Dichloroaniline and hydrochloride [nH2=1J 

3,4-Dichloroanlline-6-sulfonic acid 

3.(2,4-Dichloroanilino)-l-(2,4,6-triohlorophenyl)-2- 
pyr azolin-5 - one . 

1, 5-Dichloroanthraqulnone 

1,5 (and l,8)-Dichloroanthraquinone 

*l,8-Dichloroanthraquinone 

4,5-Dlchloro-l,8-anthraquinonediEulfonio acid 

2,2'-Dichloroazobenzene 

3-(3,4-Dichlorobenzamido)-l-phenyl-2-pyrazolin-5-one 

Dichlorobenzanthrone 

m-Dichlorobenzene 

*o-Dichlorobenzene 

*o(and p)-Diohlorobenzene 

*p-Dichlorobenzene 

4,6-Diohloro-m-benzenedlsulfonamlde 

4,6-Dichloro-m-benzenedisulfonyl chloride 

*3,3'-Dichlorobenzidine base and salts 

2,4-Diohlorobenzoic acid 

2,6-Dlchlorobenzonitrile 

2,5-Diohloro-3,6-bis(9-ethyloarbazol-3-ylaniino)-p-benzo- 

quincne . 
8, 18-Diohloro-5, 15-diethyl-5, 15-dihydrodllndolo- 
(3,2-b:3' ,2'-m)triphenodioxazine. 

2,5-Diohloro-3,6-dihydroxy-p-benzoquinone 

4,5-Diohloro-3,6-dioxo-l,4-cyclohexadiene-l,2-dicar- 

bonitrile. 
4,5-Dlchloro-3,6-dioxocyolohexene-l,2-dicarbonitrile 



Manufacturers' identification codes 
(according to list in table 22) 



RH, TNP. 

NEP, RIL. 

ACY, DUP, G, MAC, SDH, TRC, VPC. 

ICI. 
MAC. 



G, NAC. 

LAK. 

BUG. 

ICI. 

DUP. 

IDC. 

G, TRC. 

ICI. 

ACY, DUP, G, ICI, MAY, NAC, TRC. 

ICI. 



G, HST, ICI, TRC, VPC. 



EK, EVN. 

ACY, DUP, 

ATL, ICI. 

WYT. 

WYT. 

ICI. 

EK. 

DUP, G, MAY, NAC, TRC. 

EK. 

DOW. 

EDC. 

ICI. 

DOW. 

EK. 

DUP. 

TRC. 

G. 

EKT. 

G. 

DOW. 

EK. 

DUP, MON. 

AAP, DUP, KLS, NAC, SDH. 

SW. 

EK. 

DUP, ICI, NAC. 

DUP, NAC. 

G, ICI, TRC. 

G. 

DUP. 

EK. 

ACY. 

EK, WOI, X. 

ACS, CPD, DCW, DUP, DVC, MON, CMC, PPG, SCC, SVT, WOI. 

GGY, HKD, MTO. 

ACS, CPD, DOW, DUP, DVC, HK, MON, PPG, SCC, SVT, WOI. 

ABB. 

ABB. 

ALL, OWN, IMP, LAK, NAC. 

HN. 



AAP, TRC. 



EK. 



CYCLIC INTERMEDIATES 



77 



TABLE 1^.— Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 7564— Continued 



Manufacturers' identification codes 
(according to list in tatle 22) 



Diohlorodiphenylsilane 

Diohlorodiphenyl sulfone 

2' ,7'-Dichlorofluorescein 

2,5-Dichloro-'i-hydrazinoben2;enesulfonio acid 

2-(5,8-Dichlcro-l-hydroxy-2-naphthylazo)-l-phenol-4- 
suifonamlde . 

7,16-Dichloroindanthrene 

Dichloroisoviolanthrone 

»2,5-Dichloro-4-(3-methyl-5-oxo-2-pyrazolin-l-yl)'benzene- 
sulfonic acid. 
Dichloromethylphenol 

*2,6-Dichloro-4— nltroaniline 

l,2-Dichloro-4-nitrobenzene 

*l,4-Dichloro-2-nitrobenzene (Nitro-p-diohlorobenzene ) 

2,4-Dichlorophenol 

l-(2,5-Dichlorophenyl)-3-triazene-car'bonitrile 

2,6-Dichloropyrazine 

3,6-DichloropyTldazine 

4,7-Dichloroquinollne 

3,5-Dichlorosalicylic acid 

*2,5-Diohlorosulfanilic acid [S03H=1] 

2,5-Dichloro-4-sulfobenzenediazoniuin sulfate 

a,a-Dichlorotoluene (Benzal chloride) 

p,a-Diohlorotoluene 

2,4-Dichloro-5-(p-toluenesulfonaniido)-l-naphthol 

2,<i-Dichloro-3,5-xylenol 

Dicyclohexylamine 

Dicyclohexylcarbodiimlde 

Dicyclopentadiene and cyclopentadiene 

Dioyclopentadiene dioxide 

2,4-Di(l,l-dijiiethylpropyl)phenol (Di-tert-amylphenol) 

2,5-Diethoxyaniline 

2 ',5 '-Diethoxybenzanilide 

p-Diethoxybenzene 

2,5'-Diethoxy-4' -nitrobenzanilide 

l,4-Diethoxy-2-nitrobenzene 

*p-Dlethylaminobenzaldehyde 

a- ( 2-Diethylaminoethyl) -a-phenylcyclohexanemethanol, 
hydrochloride . 

m-Diethylami nophenol ( N, N-Diethyl-3-aiiiinophenol) 

3-(p-Diethylaminophenylazo)-lH-ly2,4.-triazole 

3-Diethylmm" nopropiophenone 

4-Diethylainino-o-tolualdehyde 

*N,N-Diethylaniline 

N,N-Diethyl-m-anisidine 

Diethylbenzene 

N, N-Diethyloyclohexylamine • 

N.N-Diethylmetanilic acid 

N ,>}■'■ -Diethyl-4-methoxyinetanilaiiiide 

N,N-Diethyl-l-naphthylamine 

N,N-Dlethyl-p-nitrosoaniline 

N,N-Diethyl-4-nitroso-ni-anisidine hydrochloride 

N,N-Diethyl-4-nitroso-m-phenetidine 

N,N-Diethyl-m-phenetidine 

Diethyl terephthaloyldiacetate 

N,N-Diethyl-m-toluidine 

6,15-Dihydro-5,9,14,18-anthrazinetetrone 

10, ll-Dihydro-5H-dibenzo [a, d] cyeloljepten-5-one — 

3,4-Dihydro-3,4-dioxo-l-naphthalenesulfonic acid, sodium 
salt. 

3,4-Di}-vc.o-6-methoxy-l(2H)-naphthalenone 

10,ll-Dihydro-5-[3-(methylamino)propyl] -5H-dibenzo [a,d] - 
cyclohepten- 5-ol . 

2,3-Dihydro-4H-pyran 

1,4-Diliydroxyanthraquinone 

1,5 (and l,8)-Dihydroxyanthra(iiilnone 

2,5-Dihydroxybenzenesulfonlc acid 

3,4-Dihydroxybenzoic acid (Protocatechuic acid) 

4,4'-Dihydroxy-3,3'-dimethylbiphenyl 



Dec. 
NES. 



ICI. 
ICI. 



ACY, CMG, DUP, G, KI£, TEC, VPC. 



EKT. 

AAP, 

DUP, 

AAP, 

DOW, 

G. 

ACY. 

ACY. 

SDW. 

ICO. 

CMG, 

TEC. 

MAC. 

HN. 

EK. 

OTA. 

ABB, 

G. 

ENJ, 

UCC. 

PAS. 

ALL. 

G. 

G. 

G. 

G. 

DUP, 

ACY. 



DUP, EKT, G, MEE, PCW, TEC. 

MON. 

DUP, MAC, VPC. 

MON. 



DUP, G, VPC. 



VGC. 
UCC. 



G, MAC. 



ACY, DUP, MON. 

TRC. 

ACY. 

DUP. 

ACY, nSC, DUP, NAC, SDH. 

DUP. 

DOW, KPP. 

DUP. 

DUP. 

G, PCW. 

DUP. 

G. 

DUP. 

G. 

G. 

G. 

DUP. 

TRC. 

LIL. 

EK. 

GAM. 
LIL. 

QKO. 

DUP. 

DUP, NAC, SDH. 

NES. 

AMB. 

EK. 



78 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer , 1964- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



Dihydroxydinitroanthraquinone 

*l,5-Dlhydroxy-4,8-dlnitroanthraqulnone 

*l,8-Dlhydroxy-4,5-dinitroanthraquinone (4, 5-Dinitro- 

chrysazin). 
l,5-Dlhydroxy-4,8-dlnitro-2,6-anthraqulnonedisulfonio acid- 
l,8-Dihydroxy-4,5-dinitro-2,6-anthraquinonedlsulfonic aoid- 
4,5-DihydrQxy-2,7-naphthalenedlsulfonic acid ( Chromotropic 
acid) . 

6,7-Dihydroxy-2-naphthalenesulfonic acid 

3 J 5-Dihydroxy-2 -naphthoic acid 

ll|3,21-Dihydroxypregna-4,17(20)-cis-dien-3-one 

ll/3,21-Dlhydroxypregna-l,4,17(20)-cis-trien-3-one 

4,5 -Dihydroxy-3 -( p-sulf ophenylazo) -2,7-naphthalene - 
disulfonic acid, trisodium salt. 

*16,17-Dihydroxyviolanthrone (Dihydroxydihenzanthrone) 

m-Diiodohenzene 

2,5-Diiodobenzoic acid 

3,5-Diiodo-L-tyrosine 

NjN'-Diisopropyl-p-phenylenediamine 

2,5-Dlmethoxyaniline 

l,5(and 1,8) -Dlmethoxyanthraqulnone 

m-Dimethoxybenzene 

p-Dimethoxybenzene 

*3,3' -Dimethoxybenzidine 

3,3' -Dimethoxybenzidine hydrochloride 

2,4-Dljnethoxybenzoic acid 

l,l-(3,3 '-Dimethoxy-4,4 '-biphenylene)bis [3-methyl-3-(2- 
sulf oethyl) triazene] . 

1, 4 -Dimethoxy-2 -nitrobenzene 

2,5-Dimethoxy-4' -nitrostilbene 

3,4-Dimethoxyphenethylamlne (Homoveratrylamine) 

4-(2',5'-Dimethoxyphenethyl)aniline hydrochloride 

N-(3,4-Dimethoxyphenethyl)-2-(o-nitrophenyl)acetamide 

( 3, 4-Dimethoxyphenyl) acetic acid 

(3,4-Dimethoxyphenyl)acetonltrile 

16,17-Dimethoxyviolanthrone 

m-Dimethylaminobenzoic acid 

a-Dimethylamino-o-cresol 

6 -Dime thy lamlno-2-( 2-( 2 , 5 -dimethyl-l-phenyl-3 -pyrryl) - 
vinyl) -l-methyl-l-quinolinivuD methyl sulfate . 

6-(Dliiiethylaiiiinoethyl) -2-methoxy-4-nitrophenol 

Dimethylamlnoethyl-4-methylpiperazine 

o-( 2 -Dimethylamlnoethyl) phenol 

2-[ ( 2-Diiiiethylaminoethyl) thenylamino] pyridine (non- 
medicinal grade) . 

a, a', a"-tris(Dimethylamiuo)mesitol 

o-(Dlmethylamlnomethyl) -p-butylphenol 

m-Dimethylaminophenol 

N-( p-Dimethylaminophenyl) -1,4-naphthoquinoneimine 

»N,N-Dimethylaniline 

7,12-Dimethylbenz [a] anthracene 

*N,N-DimethylbenzylaJilne 

a, a'-Dimethylbenzyl hydroperoxide 

4-(a,a-Diniethylbenzyl)-2-phenylazophenol 

*2,2' -Dimethyl-1,1' -bianthraquinone 

2,4-Di( 1-me thy Ibutyl) phenol 

5,5-Dimethyl-l,3-cyclohexanedione 

N,N-Dimethylcyclohexylamine 

N, N-Dimethyl-2 , 2 -diphenylacetnml de 

2 ',7' -Dimethylfluoran 

Dimethylhydantoin 

2,6-Dijiiethylhydroqulnone 

2,8-Dimethyl-13P-hydroxy-9(l3P)-oeroxenone 

2,3-DimetlQflindole 

2,5-Dimethyl-^(2) -morpholinylmethylphenol, hydrochloride 

*N,N-Dimethyl-p-nitrosoaniline 

N,N-Dimethyl-p-phenylenediamine 

N,N-Dimethyl-p-phenylenediamine hydrochloride 

Dlmethylplperazine 

1,4-Dimethylpiperazine 



DUP. 

G, ICI, TRC, VPC. 

DUP, EKT, G, ICI, MAC. 

VPC. 
DUP. 
HSH, MAC. 

FMT, G, IDC, NAC. 

G. 

UP J. 

UP J. 

EK. 

ACY, DUP, G, ICI, MAY, NAC. 

EK. 

RSA. 

EK. 

DUP. 

EKT, KIS. 

TRC. 

ACY, ICO. 

G, ICO. 

ALL, CWN, DUP, SDH. 

CWN. 

ACY. 



EKT. 
UP J. 
LIL. 
UP J. 

X. 

LIL. 
LIL. 

ICI, MAY. 
SDH. 
TKL. 



NAC. 

DEC, DUP, NAC, SDH. 

MIS, X. 



MEE. 
UCC. 



TKL. 

RH. 

ACY, 

NAC. 

ACY, 

EK. 

ICO, 

ACP. 

TRC. 

AAP, ACY, CMG, DUP, G, ICI, NAC, TRC. 

PAS. 

EKT. 

DUP, EKT. 

UPJ. 

WIM. 

GLY. 

UPJ. 

WIM. 

DUP. 

IDC. 

ACY, DUP, G, NAC. 

EKT, NAC. 

EK. 

WYN. 

JCC, SEL. 



CYCLIC INTERMEDIATES 



79 



TABLE IB.— Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i 964— Continued 



p-(l,l-Dimethylpropyl)phenol 

N, N-Dimethylsulf anilio aoid 

Dimethyl-p-toluldine 

N,N-Dimethyl-p-toluidine 

2,4-Dinitroaniline 

*p-(2,4-Dinltroanilino)phenol 

lj5(and l,8)-DinltroanthTaqulnone 

2j4-Dinitro-N,N'-(l,5-anthraqulnonylene)dioxamlo acid 

3,4-'-Dinitrobenzanilide 

m-Di nitrobenzene 

2,4-Dinltrobenzenesulfonlo acid 

3,5-Dinitrobenzoio acid 

3,5-Dinitrobenzoyl chloride 

ninitro(3,3'-bi-7H-benz[de]anthracen)-7,7'-dione- — 

2 , 4— Dinitrocumene 

l-(3,5-Dinitro-2-hydroxyphenylazo)-2-naphthol 

*2,4-Dinitrophenol, tech 

2,4-nlnitrophenylhydrazine 

3,5-Dinitrosalicylic acid 

*'i-,<i'-Dinitro-2,2' -stilbenedisulfonio acid 

2,4-Dinitrotoluene 

2,4(and 2,6)-Dinitrotoluene 

3,5-Dinitro-p-toluenesulfonic acid 

1,5-Diphenoxyanthraquinone 

1,5 (and l,8)-Diphenoxyanthraquinone 

1, 8-Diphenoxyanthraquinone 

*Diphenylacetic acid 

Diphenylaeetone 

Diphenylamine 

6,8-Diphenylamlno-l-naphthalenesulfonic aoid 

2,8-Dlphenylanthra[l,2-d:5,6-d']bisthiazole-6,12-dione 

a-d-l,2-M.phenyl-4-diinethylaiiiino-2-hydroxy-3-methylbutane, 
camphor sulfonate. 

N,N' -Diphenylethylenediamine 

l,3-Diphenyl-l,3-propanedione 

1,3-Diphenyltriazene 

2, 4-Disulforiyl-5-chloro-(N-benzyl) -aniline 

2,5-nithiobl\n-ea 

Dithiodibenzoic aoid 

2,2'-Dithiodibenzoic aoid 

*1, 4-Di(p-toluidino)anthraquinone 

1, 5-Di(p-toluidino)anthraquinone 

l,8-Di(p-toluldino)anthraquinone 

l,4-ni(p-toluidino)-5,8-dihydroxyanthraquinone 

Divinylbenzene 

Edxylylethane 

Dixylylguanidine 

Dodeoylaniline 

*Dodecylbenzene (including trideoylbenzene ) : 

Straight-chain 

Other 

Dodecylmethylbenzene 

Dodecylmethylbenzyl chloride 

Dodecylnitrobenzene 

*Dodeoylphenol 

o- Ethoxybenzoic acid 

(o-Ethoxybenzoyl)aoetonitrile 

6-Ethoxy-2-mercaptobenzothiazole 

2-Ethoxynaphthalene 

2-Ethoxy-l-naphthoyl chloride 

■4-Ethoxy-o-phenylenediamine 

3-Ethylamino-p-cresol 



Manufacturers' identification codes 
(according to list in table 22) 



PAS, UCP. 



SEL. 



AAP, ACY. 




DUP, G, NAC. 


AAP, TRC. 




TRC. 




AAP. 




DUP, NAC. 




TRC. 




DUP, GAM, 


SAL, SDH. 


EK. 




DUP, MAY. 




DUP. 




TRC. 




AAP, DUP, 


NAC, SDC. 


EK. 




EK. 




ACY, DUP, 


G, NAC, SDH, TRC 


DUP, NAC. 




DUP, MOB. 




G. 




ICI, VPC. 




AAP, DUP. 




EKT, G, ICI. 


ARA, BPC, 


LIL. 


TBK. 




ACY, DOW, 


DUP. 


NAC. 




ICI. 




LIL. 




DOW, RPC. 




EK. 




NAC. 




ABB. 




ACY. 




MEE. 




LIL. 




ATL, CMG, 


G, ICI, NAC, TRC, 


ICI. 




ICI. 




ICI. 




DOW, FG, KPP. 


GOC. 




ACY. 




MON. 




CO. 




ATR, CO, MON, NAC, SOC. 


X. 




X. 




MON. 




G, MON, X 




ACY. 




ACY. 




ARA, DUP. 




ICO, NAC. 




ICO, OPC. 




TRC. 
DUP. 





SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE TB.-Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i 564 —Continued 



3-Ethylaim.no-p-toluenesulfoiiic acid [S03H=lJ 
»N-Ethylaiallne, refined 

2-(N-Ethylanilino)ethanol 7-— 

[ 2-(N-Ethylanilino)ethyl] trimethylaimiionium chlonde- 
(N-Ethylaiillino)propionltrile 

a-(N-Ethylaniltno)-m-toluenesiilfonlc acid 

a-(N-Ethylaiilltno)-p-toluenesulfonio acid 

N-Ethyl-p-anisidine 

N-Ethylanthranilic acid 

2-Ethylaiit)iraquinone 

*Ethylbenzene 



(MEP)- 



o-(p-Etliylbenzoyl)benzoic acid 

Etl^rlbenzyl chloride 

N-Ethyl-N-(2-chloroetliyl) aniline 7 J-— 

l-Ethyl-7-methyl-l,8-naphtl)yridln-4-one-3-carboxylio acid— 

N-Ethyl-l-naphthylamlne 

9-Ethyl-3-nitrocarbazole 

p-Ethylphenol 

»N-Etl^l-N-phenylbenzylamine 

»2-Ethyl-2-phenylmalonic acid, diethyl ester-^ 
5-Ethyl-2-picollne (2-Methyl-5-ethylpyridine 

1-Ethylpiperidine 

N-Ethyl-5-sulfoanthranillo acid 7 

6-Ethyl-l,l,'4,4-tetramethyl-l,2,3,4-tetrahydronaphthalene- 

N-Ethyl-m-toluidine 

N-Ethyl-o-toluidine 

3-(N-Ethyl-m-toluidino)-l,2-propanediol 

»3-(N-Ethyl-m-toluidino)propionitrile 

1-Ethynylcyclohexanol ~_ 

o-Fluoroaniline 

l-Fluoro-2,4-dinitrobenzene 

o-Fluorotoluene 

A-Fonnyl-m-benzenedisulfonic acid 7 

»o-Foniiylbenzenesulfonic acid (o-Sulfobenzaldehyde) — 

m-Formylbenzenesulfonio acid, sodium salt 

Furan 

Furfuryl alcohol 

Hexachlorobenzene 

Hexachlorocyclopentadiene 

Hexachlorophenyl ether 

N-Hexadeoylmorpholine 

2 2' ,U,U' ,6,6' -Hexanitrodiphenylamlne 

Hippurlo acid 

«p-Hydrazinobenzenesulfonio acid 

3-Hydrazino-5-nitro-p-toluenesulfonic acid [S03H=1J 

Hydroquinone , tech 

2' -Hydroxyacetophenone 

3' -Hydroxyaoetophenone 

"i' -Hydroxyacetophenone 

3 '-Hydroxyaoetophenone benzoate 

6'-Hydroxy-m-aoetotoluidide 

1-Hydroxyanthraqulnone 

p-HydToxybenzaldehyde 

2-Hydroxy-llH-benzo [a] carbazole-3-oarboxylic acid 

p-I^roxybenzoic acid 

p-Hydroxybenzoio acid, butyl ester 

p-Hydroxybenzolc acid, ethyl ester 

«p-Hydroxybenzoio acid, methyl ester 

»p-Hydroxybenzolc acid, propyl ester 



Manufacturers' identification codes 
(according to list in table 22) 



DUP. 

ACY, DUP, NAG, SDH. 

DUP, EKT, G. 

DUP. 

EKT. 



ICC, NAG, SDH, THC, WJ. 




EKT. 




G, SDH. 




NAC. 




DOW, ENJ, FG, KPP, KPT, 


MON 


TOO, UCC. 




NAC. 




BPC. 




DUP. 




SDH. 




DSC, DUP. 




TRC. 




ACY. 




DUP, NAC, SDH. 




BPC, MAL, VPC. 




UCC. 




RIL. 




SDH. 




GIV. 




DUP. 




DUP. 




EKT. 




DUP, EKT, G. 




EKT, NAC. 




NEP. 




EK. 




EK. 




G. 




G, NAC, SDH, VPC. 




G. 




DUP. 




QKO. 




KPT, sec 




HK, VEL. 




D01». 




APD. 




EK. 




BPC. 




ACY, G, STG, WJ. 




G. 




CRS, EKT. 




arc 




SDH. 




OTC. 




SDH. 




TRC. 




AAP. 




DOW. 




G. 




HN. 




HN, WSN. 




HN, ICO, WSN. 




HN, ICO, LEM, WSN. 




HH, ICO, LEM, WSN. 





SHC, SIN, SKC, SNT, 



CYCLIC INTERMEDIATES 

TABLE 7B. -- Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



Manufacturers' identification codes 
(according to list in tatle 22) 



6' -Itydroxy-m-benzotoluidide 

o-(p-Ifydroxybenzoyl)benzoie acid 

A-Ify'droxycoumarin 

'4-I^roxy-N-'-,N-'--diinethylmetanilandde 

3-(N-2-I^droxyethylam.lino)propionitrile 

N-P-Hrdroxyethyl-2,4-dihydroxybenzamide 

3-l^droxy-N-2-hydroxyethyl-2-naphthaiTn'de 

6'-Hydroxy-5 '- (2-hydroxy-5-nitrophenylazo)-in-aoetotoluidide 
N-[ 7-}^droxy-8-( 2-hydroxy-5-nitrophenylazo ) -1 -naphthyl] - 
aoetamide. 

ifydroxyisophthalio acid 

2-Hydroxy-C"'',a^-mesitylenediol 

2-Itrdroxy-3-methylcinchoninic acid 

3-Hydroxy-2-methylcinchoninlc acid 

N-I^dro3(ymethylphthalamide 

V-Ifydroxy-l-naphthalenecarbamic acid, methyl ester 

l-l^droxy-2-naphthalenesulfonio acid, potassium salt 

3-}fcrdroxy-2-naphthanilide (Naphthol AS) 

1-Itydroxy -2 -naphthoic acid 

2-ffydroxy-l -naphthoic acid 

3 -Ify-droxy -2 -naphthoic acid (B.O.N.) 

3 -Ilydroxy-2 -naphthoic acid, methyl ester 

l-Hydroxy-2-naphthoio acid, phenyl ester 

3-Hydroxy-2-naphtho-o-toluidide 

N-(7-Itydroxy-l-naphthyl)acetamide 

l-(2-Ifydroxy-l-naphthylazo)-6-nitro-2 -naphthol -4-sulfonio 
acid. 

N-(7-Hydroxynaphthyl)benz amide 

3'-[(7-Hydroxy-l-naphthyl)carbamoyl]acetaiiilide 

l-(2-Ifydroxy-4-nitrophenylazo) -2 -naphthol 

^-Hydroxypropiophenone 

2-I^droxy-4— sulfo-1-naphthalenediazonimn hydroxide, inner 
salt. 

l-}trdroxy-4--(p-toluidino)anthraquinone 

2-Tmidazolidinone modifications 

»l,l' -Iminobis[4-aminoanthraquinone] 

1,1' -Iminobis /--benzamldoanthraquinone] 

5-benzamidoanthraquinone] 

l-naphthol-3-sulfonic acid] 

A-nitroanthraquinone] 

*l,l'-Iiziinodianthraquinone ( Dianthrimide ) 

2,2' -Tmi nodipyridine 

1,3-Indandione 

1-Iodonaphthalene 

Isatin 

Isatoic anhydride 

*Isooyanio acid derivatives: 

Bitolylene diisocyanate (TODI) 

Dianisidine diisocyanate (DADI) 

3-,4— Diohlorophenyli"sooyanate 

*Diphenylmethane 4-,A' -diisocyanate (MDI) 

Phenylisocyanate 

Polyisocyanates (complex) 

Polymethylene polyphenylisocyanate 

Toluene 2,4-diisocyanate 

Toluene 2,A- and 2,6-diisocyanate (65/35 mixture) 

*Toluene 2,4- and 2,6-diisocyanate (80/20 mixture) 

Other isocyanio acid derivatives 

Isonicotinic acid, methyl ester 

Isonicotinonitrile 

Isonitrosopropiophenone 



»1,1' -Iminobis 
»6,6'-Iminobis 
*l,l'-Iminobis 



TRC. 






LIL. 






ABB. 






G. 






ICC. 






IDC. 






X. 






TRC. 






TRC. 






SDH. 






ACY. 






G. 






DUP, 


TRC. 




ACY. 






TRC. 






EK. 






ATI, 


PCW. 




NAC. 






BL. 






AUG, 


DUP, 


HN, PCW. 


PCW. 






EK. 






ACY, 


ATL. 




CMG, 


TRC. 




TRC. 






TRC. 






TRC. 






TRC. 






MLS. 






ACY. 






ICI. 






RH. 






ACY, 


CMG, 


DUP, G, ICI, MAY, NAC, TRC 


ACY, 


MAY. 




G, ICI, TRC. 


DUP, 


G, NAC, TRC. 


ACY, 


DUP, 


ICI, MAY, TRC. 


ACY, 


DUP, 


G, ICI, MAY, NAC, TRC. 


RIL. 






PIC. 






EK. 






NAC. 






MEE. 






CWN. 






CWN. 






DUP. 






CWN, 


DUP, 


MOB, NAC. 


CWN. 






MOB. 






CWN. 






DUP. 






DUP, 


NAC. 




DUP, 


MOB, 


NAC. 


CWN, 


MOB, 


UCC, UPC. 


RIL. 






RIL. 






ICO, 


NEP. 





82 



TABLE 7B. 



SYNTHETIC ORGANIC CHEMICALS, 1964 

-Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 2564— Continued 



Isoootylphenol "" '"^ '_ 

Isophorone "7 T"7" 

Isophthalic acid (1,3-Benzenedlcarboxylic acid) — -— 

Isophthallc acid, dimethyl ester 

Isophthalic acid, diphenyl ester — - 

Isophthalonitrile " 

N-Isopropylaniline 

p-Isopropylbenzoic acid " 

5,5'-Isopropylidenebis(2-hydroxy-ni-xylene-a,a'-diol) 

*<i,4'-Isopropylidenediphenol (Bisphenol A) 

4 4'-Isopropylidenediphenol, ethoxylated 

i.',A' -Isopropylidenediphenol, propoxylated 

o-Isopropylphenol 

<V-Isopropyl-m-phenylenediajiiine 

Isothiooyanic acid, phenyl ester 

*Isoviolanthrone (Isodibenzanthrone) 

*Leuco-l,4-diaiiiinoanthraquinone 

*Leuco quinizarin (1,4,9,10-Anthratetrol) 

»Leuco tetrahydroxyanthraquinone 

2,4-Lutidine 

3,'4-Lutidine 

Mandelonitrile 

*Melaniine 

dl-p-Mentha-l,8-diene (Limonene) 

p-Mentha-l,'i(8)-diene 

p-Mentha-l,8-diene ^ 

*o-Mercaptot)enzoic acid 

Metanilamide " 

Metanilic acid (m-Amlnobenzenesulfonic aoid) 

1-Methoxyanthraquinone 

4-Methoxymetanilic aoid 

4'-Methoxy-2-(p-methoxypheiiyl)acetophenone 

N-(2-Methoxy-l-naphthyl)acetamide 

2-Methoxy-4-nitrophenol 

p-Methoxyphenylaoetic acid ''"^"s 

S-Methoxy-m-phenylenediamine (m-Diaminoanisole) 

crude 



Me thoxypropi ophenone 

i-l-Methylaminoanthraqulnone 

l-Methylaiiiino-<i-(p-toluidino)anthraquinone 

N-Me thy lani line 

2-(N-Methylanilino)ethanol 

3-(N-Methylanilino)propionitrile 

5-Methyl-o-anisidine [NH2=1] 

m-Methylanlsole 

N-Methylanthranilic acid 

2-Methylanthraquinone """" 

1- ( 3-Methyl-2-anthraquinonylamino ) -5- (7-oxo-7H-benz [dej - 

anthracen-3-ylamino) anthraquinone . 

3-Methylbenzo [f]quinoline 

2-Methylbenzothiazole 

N-Me thy Ibenzylamine 

Methyl benzyl ether 

3-Methylcholanthrene 

Methylcyclohexane 

N-Methylcyclohexylamine 

-i-Methyl-a ,a-diphenyl-l-piperazineethanol dihydrochloride- 

N-Methyleneaniline 

4.,4'-Methylenebls[2-chloroaniline] 

iH 4'-Methylenebls[N,N-diethylaniline] 

*4,4'-Methylenebis[N,N-dimethylaniline] (Methane base) 

4,4'-Methylenebis[N,N-dimethyl-3-nitroaniline] 

5,5'-Methylenebis[toluene-2,4-diaiiiine] 

Methylenedianiline 

Methylenedisalicylic acid 

5-Methylene-2-norbornene 

l-Methylindole-3-carboxaldehyde 



Manufacturers ' identification codes 
(according to list in table 22) 



G. 

UCC. 

ACC, SOC. 

MTR. 

BJL. 

X. 

ACY, EKT. 

EK. 

ARK. 

DOW, MON, SHC, UCP. 

APD. 

APD. 

TNA. 

DUP. 

TNC. 

ACY, DUP, G, MAY. 

ACY, ATL, DUP, G, ICC, ICI, MAY, TRC. 

AAP, ACY, EKT, HSH, ICC, MAC. 

G, ICC, TRC. 

ACP, KPT. 

RIL. 

KF. 

ACN, ACY, RCI. 

HNW. 

GIV. 

GIV. 

EVN, LIL, MED. 

CMG, VPC. 

DUP, NAG, TRC. 

G. 

G. 

CTN. 

TRC. 

MEE. 

TBK. 

AAP. 

LIL. 

AAP, ACY, DUP, G, ICI, MAC. 

G, ICI. 

ACY, DUP, MAC. 

G. 

DUP. 

DUP. 

GIV. 

ICC. 

ACY, MAC. 

DUP. 

ACY, G. 

FMI. 

ABB, MLS. 

UCC. 

EK. 

DOW, PLC. 

DUP. 



DUP. 

DUP. 

DUP, 

ACY, 

G. 

NAC. 

DOW, 

HN. 

DOW. 

G. 



G, SDH, TRC. 

DSC, DUP, G, MAC, SDH, x. 



CYCLIC INTERMEDIATES 



83 



TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



Jfethyl-N-methyl-N-piperazine acetate 

6-Jfethyl-2- ( 2-methyl-6-quinolyl ) -7-"benzothlazolesulf onio 
acid. 

Methylnaphthalene, crude 

1-Jfethylnaphthalene 

N-Methyl-4'-nitroacetanilide 

N-lfethyl-p-nltroaniline 

5-Methyl-4— nitro-o-anisidine 

4-Methyl-2-nitroanisole 

*2-Methyl-l-nitroanthraquinone 

2-Methyl-5-nitro imidazole 

N-Methyl-N-nitroso-p-toluenesulfonamide 

Methylnorbomene-2,3-dicarboxylic anhydride, isomers 

m-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzene sulfonamide 

p-(3-Methyl-5-oxopyrazolin-l-yl)benzenesulfonic acid 

m-(3-^fethyl-5-oxo-2-pyTazolin-l-yl)benzenesulfonio acid — 

*p-(3-lfetliyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic acid — 
3-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-l,5-naphthalenedisul- 

fonic acid. 
4-- ( 3-Methyl-5-oxo-2-pyrazolin-l-yl ) -m- toluenesulf onic 
acid [ S03H=1] . 

2-Wtethyl-5-phenylbenzoxazole 

1-Methyl-l-phenylhydrazine 

5-Jfethyl-3-phenyl-<i-isoxazolecarboxylic acid 

5-Metliyl-3-phenyl-4-isoxazolecarboxylic acid hydrochlo- 
ride. 

*3-tfethyl-l-phenyl-2-pyrazolin-5-one (Developer Z) 

N-lfethylpiperazine 

3-(a-Methylpiperidino)propaiiol-- 

16a-Methyl-l,,4,9( 11) pregnatriene-17a-21-diol-3,20-dione, 
21-ethyl carbonate. 

Ifethylpropylcarbinylbarbituric acid- 

Ifethylpyrazine 

1-Msthylpyrrole 

*a-Hfethylstyrene 

N-Msthyl-5-sulfoanthranilic acid 

2-Methylsulfonyl-'i-nitroaniline 

Methyl 2-thlenyl ketone 

p-Methylthioaniline hydrochloride 

<i-(tfethylthio)-in-oresol 

p-(Methylthio)phenol 

3-lfethyl-6-(p-toluidino)-7H-dibenz [f , ij Jisoqiiinoline- 
2,7(3H)-dione. 

3-Methyl-l-(p-tolyl)-2-pyrazolin-5-one 

6 '-Methyl-A'-p-tolylsulfonamido-m-benzanisidide 

Morpholino propylchloride 

Naphthalene, solidifying at 79° C. or above (refined 
flake) (from domestic crude). 

1, 3-Naphthalenediol 

1, 5-Naphthalenediol ( 1, 5-Dihydroxynaphthalene ) 

*l,5-Naphthalenedisulfonio acid 

*2,7-Naphthalenedisulfonic acid 

l-Naphthalenesulfonic acid 

1-Naphthalenesulfonic acid, sodium salt 

2-Naphthalenesulfonio acid 

2-Naphthalenesulfonic acid, sodium salt 

2-Naphthalenesulfonyl chloride 

*1,4, 5,8-Naphthalenetetraoarboxylio acid 

1,3,6-Naphthalenetrisulfonio acid 

Naphthalic anhydride 

Naphthallmide 

Naphthionic acid (4-Jtaiino-l-naphthalenesulfonio acid) 

Naphthionio acid, sodium salt 

»l-Naphthol (a-Naphthol) 

2-Naphthol, tech. (|3-Naphthol) 

p-Naphtholbenzein ' 

2-Naphthol-3,6-disulfonic acid (R acid) 

*2-Naphthol-3,6-disulfonio acid, disodium salt 

2-Naphthol-6, 8-disulf onic acid (G acid) 



ABB. 




DUP. 




KPT, 


VEL. 


RIL. 




G, NAC. 


EK, 


G. 


Few. 




DUP. 




DUP, 


G, ICI, NAC. 


RDA. 




EK. 




NAC. 




CMG, 


VPC. 


KLS. 




G, TRC. 


AAP, 


ACY, CMG, DUP, G, TRC, VPC 


TRC. 




CMG, 


G, TRC. 


EK. 




EK. 




ICO, 


X. 


ICO. 




DOW, 


DUP, NAC, SDH, SDW, VPC. 


UCC. 




LIL. 




SCH. 




LIL. 




WYN, 




DUP. 




ACP, 


CLK, DOW, HPC. 


G. 




EKT. 




GAM. 




EVH. 




CRZ. 




CRZ. 




ICI. 




VPC. 




NAC. 




ABB. 




KPT, 


RIL. 


EK. 




NAC. 




G, MAC, TRC. 


DUP, 


NAC, TRC. 


TRC. 




TRC. 




ACY, 


NAC. 


ACY. 




DUP. 




G, HST, TRC. 


G. 




DUP. 




DUP, 


NAC. 


ACY, 


DUP. 


DUP, 


NAC. 


DUP, 


NAC, UCC, UCP. 


ACY, 


MAC, SW. 


EK. 




ATL. 




ACY, 


G, NAC, TRC, WJ. 


DUP, 


TRC. 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



2-Naphthol-6,8-disulfonlc acid, dipotassium salt 

2-Naphthol-6,8-disulfonlc acid, disodlum salt 

l-Naphthol-3-sulfonainide 

l-Naphthol-A-sulfonic acid (Nevile & Winther's acid) 

l-Naphthol-5-sulfonic acid 

l-Naphthol-8-sulfonic acid 

»2-Naphthol-6-sulfonic acid (Schaeffer's acid) 

*2-Naphthol-6-sulfonic acid, sodium salt 

2-Naphthol-7-sulfonic acid 

l-Naphthol-3-sulfonic acid, benzenesulfonate, sodium salt- 

l-Naphthol-8-sulfonio acid sultone (1,8-Naphthosultone) 

l,"i-Naphthoquinone 

Naphthostyril 

»Naphth[l,2]oxadiazole-5-sulfonio acid 

1-Naphthylamine (a -Naphthylamine ) 

l-(2-Naphthylamino)anthraqulnonecarboxylic acid 

*2-(Naphthylthio) acetic acid 

Nlootinonitrile (3-Cyanopyridine) 

Nitro-aceanthra[2,l-a] aceanthrylene-5,13-dione 

3' -Nitroacetanilide 

4' -Nitroaoetanilide 

<4'-Nitro-o-acetanisidide 

2-Nitro-p-acetanisidide 

3 ' -Nitroaoetophenone 

5' -Nitro-o-acetotoluidide 

m-Nitroanlline 

o-Nitroaniline 

*p-Nitroaniline 

3-Nitro-p-anisamide 

*<i--Nitro-o-aiiisidine [rH2=1] 

»5-Nitro-o-anisidine [nH2=i] 

2-Nitro-p-anisidine [NH2=1] 

o-Nitroanisole 

p-Nitroanisole 

4-Nitroanthranllic acid 

S-Nitroanthranilic acid 

1-Nitroanthraquinone 

1' -Nitroaiithraquinone-2' -carboxyaminoaceanthra [2,1-^ - 
aceanthrylene-5,13-dione . 

»l-Nitro-2-aiithraquinonecarboxylic acid 

*5-Nitro-l-anthraquinonesulfonic acid 

»5(and 8)-Nitro-l-anthraquinonesulfonic acid 

S-Nitro-l-anthraquinonesulfonio acid 

8-Nitro-l-anthraquinonesulfonic acid, sodlimi salt 

2-(4-Nitro-2-anthraqulnonyl)anthra[2,3]oxazole-5,10-dione- 

m-Nitrobenzaldehyde 

6-(p-Nitrobenzamido)-l-naphthol-3-sulfonio acid 

3'-Nitrobenzanilide 

4'-Nltrobenzanilide 

*Nitrobenzene 

3-Nitrobenzenesulfonanilide 

*m-Nitrobenzenesulfonic acid 

*m-Nitrobenzenesulfonio acid, sodium salt- 

m-Nitrobenzenesulfonyl chloride 

p-Nitrobenzenesulfonyl chloride 

5-Nitro-2(3H)-benzimidazolone 



ACY, 


NAC. 






G. 








ATL, 


DUP, 


NAC. 




NAC. 








G, VPC. 






NAC, 


SNA, 


TMS. 




ACY, 


TRC, 


WJ. 




DUP. 








G. 








ACY, 


TRC. 






EKT. 








DUP, 


NAC. 






CMG, 


G, NAC, TRC, VPC 


DUP, 


NAC. 






TRC. 








AAP, 


ACY, 


VPC. 




KEP, 


RIL. 






ICI. 








G. 








G, TRC. 






DUP. 








DUP, 


SDH. 






SDH. 








DUP. 








ACY, 


DUP. 






AAP, 


MDN. 






AAP, 


M3N, 


SDC, 


UPM. 


X. 








AAP, 


DUP, 


SDH. 




ACY, 


AUG, 


DUP, 


KLS. 


DUP, 


SDH. 






DUP, 


MON. 






DUP. 








DUP. 








TRC. 








ACY. 








ICI. 








DUP, 


G, MAY, NAC, TRC 


DUP, 


NAC, 


TRC. 




ICI, 


NAC, 


TRC. 




NAC. 








DUP, 


TRC. 






G, NAC. 






SDH. 








DUP, 


G. 






DUP. 








G, TRC. 






ACY, 


DUP, 


G, MDN, NAC 


G. 








ACY, 


DUP, 


NAC. 




AAP, 


G, MAY, MON, MRA 


ACY. 









DUP, G. 



CYCLIC INTERMEDIATES 



85 



-Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i5«— Continued 



*m-Nitrobenzoio acid 

*m-Nitrobenzoic acid^ sodium salt 

p-Nitrobenzoio acid 

p-Nitrobenzoio acid, ethyl ester 

p-Nitrobenzoic acid, propyl ester 

m-Nitrobenzoyl chloride 

p-Nitrobenzoyl chloride 

<♦' -Nitro-4-bipheiiylcarboxylic acid 

2-Nitro-p-cresol 

Nitrooyclohexane 

Nitrodiphenylamine 

5-Nitro-2-furaldehydediacetate 

5-Nitro-2-furaldehyde semioxamazide 

4-Nitro-6-(5-hydroxy-3-inethyl-l-phenyl-<i-pyrazolylazo) 
l-phenol-2-sulfonic acid. 

5-Nitroisophthalic acid 

1-Nitronaphthalene 

*3-Nitro-l,5-naphthalenedisulfonic acid 

8(and 5) -Nitro-l(aiid 2) -naphthalenesulfonio acid 

4.-Nitronaphthalic anhydride 

*7(and 8) -Nitronaphth[l,2]oxadiazole-5-sulfoiiio acid 

p-Nitrophenethyl acetate 

Nitrophenethyl alcohol 

o-Nitrophenol 

»p-Nitrophenol 

p-Nitrophenol, sodium salt 

4'-(p-Nitrophenyl)acetophenone 

4-Nitro-o-phenylenediamine 

(p-Nitrophenyl) hydrazine 

(p-Nitrophenyl) hydrazine hydrochloride 

2-(p-Nitrophenyl) -(2H) -naphtho[l,2-d]triazole-6,8- 

disulfonic acid. 
l-(m-Nitrophenyl) -5-oxo-2-pyrazoline-3-carboxylic acid 

o-Nitrophenyl phenyl sulfone 

"i-Nitrophthalic acid 

3-Nitrophthalic anhydride 

^-Nitrophthalimide 

l-Nitropyrene 

5-Nitro-4,6-pyrimidinediol 

5-Nitrosalicylaldehyde 

3(arid 5) -Nitrosalicylic acid 

p-Nitrosophenol 

p-Nitrostyrene 

2-U-(4-Nitro-2-sulfostyTyl) -3-sulf ophenyl] -2H-naphtho. 
[l,2]triazole-5-suli'onlc acid. 

m-Nitrotoluene 

o-Nitrotoluene 

p-Nitrotoluene 

Nitrotoluene mixtures 

»5-Nitro-o-toluenesulfonic acid [S03H=l] 

3-Nitro-p-toluenesuli'onic acid [S03H=l] 

'i'-Nitro-p-toluenesulfono-o-toluidide 

3-Nitrotoluic acid chloride 

3-Nitro-p-toluic acid, methyl ester 

4-Nitro-o-toluidine [nH2=1] 

*5-Nitro-o-toluidine [nH2=1] 

»2-Nitro-p-toluidine [ NH2=l] 

5-Nitro-2-p-toluidinobenzenesulfonic acid 

*16-Nitroviolanthrone _. 

4--Nitro-m-xylene 

Nitroxylenes, mixed 



Manufacturers' identification codes 
(according to list in table 22) 



HK, 


SDH, 


WAY. 


WAY. 






DUP. 






ICO. 






ICO. 






HK. 






DUP, 


HK. 




DUP, 


TRC 




SW. 






X. 






ACY. 






NOR. 






NOR. 






TRC. 






G, GAM. 




DUP, 


NAC 




G, NAC, TRC. 


G. 






G. 






G, NAC, TRC, VPC. 


EKT. 






EKT. 






DUP. 






DUP, 


MON, 


SDC, UPM 


MON, 


UPM. 




DUP, 


G. 




DUP, 


FMT. 




EK. 







DUP. 






TRC. 






KF. 






EK. 






G. 






ACY, 


DUP, 


NAC. 


CWN. 






TRC. 






DUP. 






DUP, 


NAC. 




DUP, 


NAC. 




DUP, 


NAC. 




ACY, 


DUP, 


G, NAC, SDH, TRC. 


AAP, 


CIC. 




G. 






X. 






SDH. 






DUP, 


G. 




DUP, 


KLS, 


SDH. 


AAP, 


ACY, 


DUP, NAC, SDH, SW 


TRC. 






ACY, 


ATL, 


G, MAY, TRC. 


DUP. 






DUP, 


NAC. 





SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 7B. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



2-tert-Nonyl-p-cresol 

Nonyl-dinonylphenol, mixture 

*Nonylphenol 

Ctetylphenol 

7-CR;abicyclo[ 4. 1.0] heptane 

Qxanilide 

*l-(7-0xo-7H-benz[de] anthracen-3-ylamino)anthraquinone 

*l,l' -(7-CKo-7H-benz [de] anthracen-3j 9-ylenediimino )- 
di anthraquinone . 

2-Oxocyolohexanecarboxylic acid, ethyl ester 

5-CKo-l-phenyl-2-pyrazoline-3-carboxylic acid 

5-Qxo-l-phenyl-2-pyraaoline-3-oarboxylic acid, ethyl ester- 
*5-CKo-l-(p-sulfophenyl) -2-pyrazoline-3-carboxylic acid 
( Pyrazolone T ) . 

5-0xo-l-(p-sulfotolyl)-2-pyTazoline-3-carboxylic acid 

Oxydianiline 

"4, 4' -Oxydianiline 

4,4' -CKydiphenol 

Penicillin, N-ethylpiperidine salt 

Pentadecyltoluene 

1,1,3,3,5-Pentamethylindan 

Pentylnaphthalenes ( Aniylnaphthalenes ) 

o-Pentylphenol (o-Amylphenol) 

3,4,9,10-Perylenetetracarboxylio acid 

3,4,9,10-Perylenetetracarboxylic diimide 

Phenacetyl chloride 

P- Phenethylamine 

(j-Phenethylamine sulfate 

o-Phenethylbenzoic acid 

o-Phenetidine 

p-Phenetidine 

•x-Phenol : 
*Natural : 

^From coal tar : -^ 

39° C, m.p 

82^-84 5t 

All other 

*-Froni petroleum 

^Synthetic : 

By caustic fusion: U.S.P 

From ohlorobenzene by liquid -phase hydrolysis: U.S.P — 

From chlorobenzene by vapor-phase hydrolysis: U.S.P 

*From cumene by oxidation: U.S.P 

Phenolsulfonaphthalein, sodium salt 

»l-Phenol-4-sulfonic acid 

Phenoxypropanol 

2-Phenoxypropionic acid 

a-Phenoxypropionyl chloride 

Phenylacetic acid (a-Toluic acid) 

Phenylacetic acid, ethyl ester, tech 

*Phenylacetic acid, potassium salt 

Phenylacetic acid, sodium salt 

*Phenylaoetonitrile (a -Tolunitrile) 

4' -Phenylacetophenone 

2-Phenylanthr[2,3]oxazole-5,10-dione 

*p-Phenylazoaniline (p-Jlminoazobenzene) and hydrochloride — 

4-Hienylazodiphenylamine 

4-Phenylazo-l-naphthylamine 

5-Phenylazosalicylic acid 

N-'--Phenyl-l,2,4-benzenetriamine 

l-Phenyl-l,3-butanedione 

2-HienylbutyTic acid 



USR. 






JCC. 






G, JCC, MON, RH, UCP, USR. 


G, PRD, RH. 


ARA. 






WSN. 






ACY, 


DUP, 


G, ICI, TRC. 


ACY, 


DUP, 


G, ICI, MAY, NAC, TRC. 


ARA. 






NAC, 


SDW. 




0, VPC. 




AAP, 


G, ICI, VPC. 


VPC. 






ore. 






X. 






EK. 






MEK. 






CO. 






GIV. 






PAS. 






PAS. 






DUP, 


G. 




DUP, 


NAC. 




ICO. 






MLS. 






MLS. 






LIL. 






MON. 






DOW, 


MON. 




KPT, 


PRD. 




ACP, 


KPT. 




ACP, 


KPT, 


PRD. 


MER, 


NPC, 


PIT, PRD, SW. 


MAL, 


MON, 


RCI. 


DOW. 






HKD, 


UCP. 




ACP, 


CLK, 


HPC, MON, SHC, SKO, SOC, UCC 


EK. 






DOW, 


MON, 


UPF. 


ICO. 






ICO. 






ICO. 






BPC, 


GIV, 


TBK. 


BPC, 


MAL. 




BPC, 


OPC, 


TBK. 


BPC. 






BPC, 


OPC, 


SDW, TBK. 


DUP, 


NES. 




G. 






AAP, 


ACY, 


DUP, G, NAC. 


EK. 






DUP. 






TRC. 






RBC. 







See footnote at end of table. 



CYCLIC INTERMEDIATES 



87 



TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1964— Contiimed 



a-Phenyl-o-cresol 

N.N' -p-Phenylenebis[acetamide] 

m-Phenylenediamine 

o-Phenylenediamine 

p-Phenylenediamine 

Phenyl ether (Diphenyl oxide) 

Phenylglycine 

D(-)-2-Phenylglyclne 

D(-)Phenylglycine and derivatives 

Phenylglycine, sodium salt 

D(-)-2-Phenylglycyl chloride hydrochloride 

5-PhenyLhydantoin 

Phenylhydrazine 

Phenylhydrazine hydrochloride 

*2,2' -(Phenylimino)diethanol (Phenyldiethanolamine) 

3,3' -(Phenylimino)dipropiom.trile 

Phenylmalonic acid, diethyl ester 

o-Phenylphenol 

o-Phenylphenol, chlorinated 

o-Phenylphenol, sodium salt 

p-Phenylphenol 

N-Phenyl-p-phenylenediamine 

Phenylphosphonous acid 

Phenylphosphonous acid, sodium salt 

Phenylpiperazine 

l-Phenyl-l,2-propanedione, 2-oxime 

Phenyl-2-propanone 

N-3-Phenylpropyl-p-toluidine 

Phenyl 2-pyridyl ketone 

Phenyl sulfone 

o-(Phenylsulfonyl) aniline 

Phenylthioacetic acid 

l-Phenyl-2-thiourea 

Phenylimdecanoic acid 

Phloroglucinol 

Phthalazinone 

*l(2H)-Phthalazinone 

Phthalio acid 

Phthalio acid, disodium salt 

*Phthalic anhydride 

Phthalide 

Phthalimide 

Phthalocyaninato(2-)iron 

[Phthalooyanine( 2-)] copper 

Phthalocyaninedisulfonic acid, copper derivative 

Phthalocyaninetetrasulfonyl chloride, copper derivative- 

Phthaloyl chloride (Phthalyl chloride) 

Picollnes ; ■"• 

«2-Piooline (tx-Picoline) 

3-Picoline (p -Picoline) 

4-Piooline (Y -Picoline) 

Picoline (3,4--mixture) 

Picolinic acid 

3-Picolylamine 

Picramio acid and salt 

Picric acid (Trinitrophenol) 

2-Pipecoline 

Piperazine mixture, crude 

»Piperidine 

3-Piperidinopropiophenone hydrochloride 

Polychlorobiphenyl 

Polydodecylhenzene 

Polyethylbenzene (8O5S Diethylbenzene) 

Primuline base 

Primulinesulfonio acid 

See footnote at end of table. 



Manufacturers' identification codes 
(according to list in table 22) 



RBC. 

ACY. 

ACY, DUP, G, NAC. 

FMT, MEE, TRC. 

BFG. 

ACY, DOW. 

KF. 

ore. 

KF. 

MAC. 

OTC. 

ABB, X. 

DOW. 

EK, VPC. 

AAP, DUP, EKT, G. 

DUP. 

BPC. 

DOW, RCI. 

DOW. 

DOW. 

DOW. 

DUP, USR. 

VIC. 

VIC. 

RSA. 

BKL. 

ORT, SK. 

EK. 

RIL. 

NES. 

G. 

EVN. 

EK. 

EK. 

MRT. 

AAP. 

KPT, NAC, SDH. 

EK, KF. 

TNG. 

AGP, GHH, HN, KPS, M3N, PCC, RCI, SOC, SW, THC, UCC, 

WTC. 
FMT, NAC. 

DUP, MEE, NAC, SFA. 
DUP. 
ICI. 
ICI. 
DUP. 
MDN. 

ACP, KPT, RIL, UCC. 

RIL. 

RIL, UCC. 

ACP, KPT. 

NEP. 

RIL. 

DUP. 

DUP, NAC, SDC. 

LIL. 

JCC. 

ABB, DUP, MRK, RIL. 

AGY. 

MON. 

CO. 

UCC. 

DUP, NAC. 

ATL. 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 7B. 



. Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer , 1964 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



*Propiophenone 

Propylbenzene 

2-PropylpyTidine 

»Fyranthrone 

1-Fyrene amine 

lyridine, refined :■"■ 

»2° IVridine 

Other grades 

2,5-IVridinedicarboxylic acid 

lyridine hydrochloride 

3-Fyridlneniethanol 

3-Fyridinol 

2(lH)-Pyridone 

4-, 6-Pyrimidinedlol 

2-iyriiiiidinol 

Fyromellitio acid 

I^romellltic dlanhydrlde 

2-Pyrrolidinone 

3-(l-Pyrrolidlnyl)propiophenone hydrochloride 

*Quinaldine 

*Quinizarin 

*2-Quinizarinsulfonic acid 

Quinoline : 

1° and 2° Quinoline 

Other grades 

2,4-(Jiinolinediol 

8-Quinolinol (8-}fydroxyquinoline, tech.) 

Quinophthalone 

Quinothalone (Quinoline yellow, base) 

Resorcinol, monoacetate (nonmedicinal grade) 

Resorcinol, tech 

P-Resorcylaldehyde 

P-Resoroyllo acid 

(j -Resorcylic acid, lead salt 

*Salioylaldehyde 

Salicylanilide 

*Salicylic acid, tech 

Salicylic acid, ammonium chromium complex 

Salicylic acid, sodium salt (crude) 

Salicylideneaminoguanldine oleate 

Sodium phenoxide 

Styphnic acid, lead salt 

*StyTene, all grades 

p-Styrenesulfonic acid, sodium salt 

i,' -Sulfamoylacetanilide 

5-Sulfamoylanthranilio acid 

Sulfanllic acid (p-Aminobenzenesulfonio acid) and salt- 

■4-Sulfoanthranilio acid 

5-Sulfoanthranilic acid 

o-Sulfobenzoio, cyclic anhydride 

5-Sulfoisophthalic acid, dimethyl ester 

4,4' -Sulfonyldiphenol (4,4' -Dihydroxydiphenylsulfone) -■ 

4-Sulfophthalic acid 

Terephthalic acid 

*Terephthalic acid, dimethyl ester- 

Terephthaloyldiacetic acid, diethyl ester 

Terphenyl (Phenylbiphenyl) 

[4,4',i" ,4'" -Tetraaminophthalocyaninato(2-)] copper— 

Tetrabromobisphenol A 

Tetrabromophenolphthaleln, ethyl ester 

Tetrabromophthallc anhydride 

Tetrabromo-8,16-pyranthrenedione 



LIL, 


OPC, 


TBK. 


EK. 






RIL. 






CMC, 


ICI, 


TRC. 


TRC. 






ACP, 


KPT, 


RIL. 


KPT. 






RIL. 






EK. 






RIL. 






NEP. 






FMT. 






KF. 






GGY. 






DUP. 






DUP, 


HEX. 




G. 






LIL. 






ACY, 


DUP, 


NAG. 


AAP, 


ACY, 


CMG, DUP, EKT, HSH, ICC, ICI, JTC, MAY, 


NAG, TRC. 


G, HSH, NAG, PAT. 


AGP, 


KPT. 




EK. 






DUP. 






GAM. 






DUP. 






NAG. 






AAP. 






KPT. 






EK, 


G. 




ACY, 


KPT. 




ACY. 






DOW, 


HN, 


MTR. 


PCW. 






CFC, 


DOW, 


HN, MON, SDH. 


TRG. 






DOW. 






DUP. 






DUP, 


FIN. 




RIM. 






AGG, 


CSD, 


DOW, ELP, FG, KPP, MCB, MON, SHC, SKG, 


SNT, UGG. 


BKL. 






ACY, 


CTN. 




TRG. 






ACY, 


CTN, 


NAG. 


CMG. 






ICI. 






EK. 






X. 






MON, 


UPF. 




GWN. 






ACC, 


DUP, 


SOG. 


AGG, 


DUP, 


EKT, HPC. 


PGW. 






MON. 






DUP. 






DOW. 






EK. 






MGH. 






G, NAG. 





See footnote at end of table. 



CYCLIC INTERMEDIATES 



89 



TABLE IB. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



1,3,6,8-Tetrabromopyrene 

*l,4-,5,8-Tetrachloroanthraquinone 

l,2,<i,5-Tetraohlorobenzene 

Tetraohloronitrobenzene 

a,a,2,6-Tetraohlorotoluene 

Tetrachloroviolanthrone 

Tetrahydrofuran 

1,4,5,8-Tetrahydroxyaiithraquinone 

l,4-,5,8-Tetrald.s[ l',l" ,1"' ,1"" -anthraquinonylamino]-- 
anthr aquinone ( Pentanthrimide ) . 

2-(l,l,3,3-Tetramethyl'butyl)-p-cresol 

p-(l,lj3,3-TetramethyllDutyl)phenol 

N,N,N ' ,N '-Tetramethyl-p-phenylenediamine dihydroohloride- 

[4-,4',4",'4"'-Tetramtrophthalooyanlnato(2-)]copper 

2- ( 2 -Thenylamino) pyridine 

Thianthrene-XjY-dicartoxylic aoid 

Thianthrene-XjY-dinitrile 

Thioanisole 

2-Thiobarbituric acid 

3,3'-Thio'bis[7H-benz[de] anthracen-7-one] 

4,4-'-Thiodianiline 

6,6 '-Thiodimetanilic aoid 

Thiolbenzoic acid 

2-Thiophenecarboxaldeliyde 

sym-Thymol 

o-Tolidine 

2,2 '-o-Tolidinedisulfonio acid 

o-Tolidine hydrochloride 

Toluenediamine 

Toluene-2,4-diaTiiine (4-m-Tolylenediaiiiine) 

Toluene-3,4-diaiiiine 

Toluene-2,5-diaiin.ne sulfate 

Toluene-2,'i-disulfonic acid 

o-Toluenesulfonamide 

p-Toluenesulfonamide 

»o(and p ) -Toluenesulf onic acid 

p-Toluenesulfonic acid 

Toluenesulfonio acid, aniline salt 

p-Toluenesiilfonio acid, 2-chloroethyl ester 

p-Toluenesulfonic acid, ethyl ester 

p-Toluenesulfonic acid, methyl ester 

p-Toluenesulfonic acid monohydrate 

p-Toluenesulfonyl chloride 

p-Toluhydroquinone (Methylhydroquinone) 

m-Toluio aoid 

o-Toluic aoid 

p-Toluic acid 

m-Toluidine 

o-Toluldine 

o-Toluidine hydrochloride 

p-Toluldine 

N-(p-Toluidine)methyltaurine '■ 

Toluldines, mixed 

2-o-Toluidlnoethanol 

N-(2-(m-Toluidino)ethyl)suocinimide 

m-Toluidinomethanesulfonio acid 

o-Toluidinomethanesulfonio aoid 

8-(p-Toluidino) -1-naphthalenesulfonio acid 

*o-(p-Toluoyl)benzoic acid -> 

*<i-(o-Tolylazo)-o-toluidlne 

4-(o-Tolylazo)-o-toluidine hydrochloride 

2,2 '-(m-Tolylimlno)diethanol 

3,4',5-Tribromosalioylanilide 

l,2,3(and 1,2,4) -Trichlorobenzene 

1,2,4-Trichlorobenzene 



Manufacturers' identification codes 
(according to list in table 22) 



DUP, 


G, ICI, 


NAC. 


DOW, 


HK. 






SDH. 








DUP. 








ICI. 








DUP, 


0^0 






NAC. 








ICI, 


NAC 






ACY. 








G. 








EK. 








DUP. 








ABB. 








TRC. 








TRC. 








PIT. 








EK. 








ACY, 


DUP 


G. 




ACY. 








NAC. 








EVN. 








ABB. 








GIV. 








CWH, 


DUP 


LAK 




AAP. 








AAP, 


DUP 


EK. 




OMC. 








ACY, 


BL, 


DUP, 


G, NAC, SDC, TRC. 


X. 








EK. 








G. 








MQN. 








MON. 








CTN, 


MDN 


NAC 


, NES, SW, UPF. 


ACY, 


TN, 


UPF. 




NES. 








G. 








NAC. 








ICI. 








CTN, 


NES. 






MDN. 








EKT. 








CWL. 








CWL. 








CWL. 








DUP, 


NAC. 






DUP, 


NAC. 






ACY, 


EK. 






DUP, 


NAC. 






BUG. 








DUP. 








EKT. 








EKT. 








TRC. 








TRC. 








NAC. 








ACY, 


DUP, 


NAC 




ACY, 


DUP, 


G, KLS, NAC, SDH, TRC 


G. 








EKT, 


G. 






DOW, 


MEE. 






PPG. 








DOW, 


HK, 


SVT. 





90 



SYNTHETIC ORGANIC CHEMICALS. 1964 



TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



N, 2,6-Triohloro-p-benzoquinoneimine 

l,2,4-Trichloro-5-nitrobenzene 

Trichlorophenylsilane 

a,aja-Ti-ichlorotoluene (Benzotri chloride) 

ctjaj'i-Trichlorotoluene 

ct ,2,4- (and a,2,6)-Trichlorotoluene 

C( ,3j4— Trichlorotoluene 

IjSjS-Triethylbenzene 

3-Trifluoromethyldiphenylaiiiine 

2-Trifluoromethylphenothiazine 

a,a,a-Trlfluoro-4-nitro-m-cresol 

a,o ja-Trifluoro-m-nitrotoluene 

a^a^a-Trifluorotoluene 

a,a,a-Trifluoro-m-toluidine 

1,2,4-Trihydroxyanthraquinone 

2,3,5-Triiodobenzoic acid 

3,'4,5-Trimethoxybenzoic acid 

2,4,5-Trimethylaniline (Pseudocumidine) 

1,2,4- Trimethylbenzene (Pseudocuraene) 

2,3,3-Trimethy-3H-indole 

*l,3,3-Trimethyl-A^j^-indolineacetaldehyde 

*l,3,3-Trimethyl-2-methyleneindoline (Trimethyl base)' 

Trimethylphenylammonium iodide 

a, a',2-Trimethyl-l,4-piperazine diethanol 

1,3,5-Trinitrobenzene 

2,4,6-Trinitrobenzoic acid 

2,4,7-Trinitrofluorenone-9-one 

Triphenylmethanol 

2,4,6-Tris [dimethylaminomethyl] phenol 

Tropine 

m-Ureidoaniline 

*6,6'-Ureylenebis[l-naphthol-3-sulfonic acid] (J acid 
urea) . 

Veratraldehyde (3,4-Dimethoxybenzaldehyde) 

p-Vinylbenzenesulfonic acid, sodium salt 

2-Vinylcyclohexene 

4-Vinylcyclohexene 

2,2'-Vinylenebis[benzimidazole] 

5-Vinyl-2-picoline (MVP) 

2-Vinylpyridine 

4-Vinylpyridine 

*Violanthrone (Dibenzanthrone) 

9-Xanthenecarboxylio acid 

m-}(ylene 

*o-Xylene 

*p-Xylene 

m-Xylene-a,a' -diamine 

Xylenesulfonic acid 

2,5-Xylenesulfonic acid 

}(ylenol crystals 

Xylenols : 

Low b.p 

^Medium b.p 

Not classified as to b.p 

Xylldines: 

2,4-Xylidine (m-4-Xylidine) 

2,5-Xylidine (p-Xylidine) 

Original mixture 

4-(2,4-Xylylazo)-o-toluidine 

4-(2,5-Xylylazo) -o-toluidine 

4-(Xylylazo)xylldine 

4-(2,4-Xylylazo)-2,5-xylidine 

All other cyclic intermediates 



ALL, PCW. 




Dec, UCS. 




HK, HN, TNP. 




HN. 




BPC. 




HN. 




DUP. 




SK. 




SK. 




MEE. 




MEE. 




HK. 




MEE. 




G. 




EK. 




ICO. 




NAG. 




ENJ, PLC. 




G. 




DUP, G, VPC. 




DUP, G, VPC. 




EK. 




WYN. 




EK. 




EK. 




EK. 




EK. 




RH. 




CTN. 




ICI. 




ACY, ATL, CMG, 


G, NAC, TRC, VPC. 


GIV, LIL, SLV. 




DUP. 




UCC. 




PLC. 




TRC. 




PLC. 




RIL. 




RIL. 




ACY, ATL, DUP, 


G, ICI, MAY, TRC. 


MAL. 




PLC, SNT, see. 




ASH, CCP, CSD, 


CSC, DLH, ENJ, MON, PLC, SIN, SNT 


SOC, TOC. 




CSD, ENJ, SIN, 


SNT, SOC. 


X. 




NES. 




EK. 




ACP, KPT. 




NPC, PIT, PRD. 




KPT, NPC, PIT, 


PRD. 


KPT, NPC, PHD. 




DUP, MAC. 




DUP, NAC. 




DUP, NAC. 




NAC. 




ACY, NAC. 





CCW, G, HPC, ICC, LIL, UPJ, x, x, x. 



■■■ Does not include manufacturers ' identification codes for producers that report to the Division of Bitiminous 
Coal, U.S. BiJreau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey Coke 
Producers in the United States in 196/,, May 17, 1965. 



DYES 
Dyes 



TABLE SB.— Benzenoid dyes for which U.S. production or sales were reported 
identified by manufacturer, 1964 ' 

[Ayes for which separate statistics are given in table 8A are marked below with an asterisk (*); dyes not so marked 
do not appear in table 8A because the reported data are accepted in confidence and may not be published. Manufac- 
turers' Identification codes shown below are taken from table 22. An x signifies that the manufacturer did not 
consent to his identification with the designated product] 



Dye 



ACID DYES 

*Acid yellow dyes: 

Acid Yellow 1 

Acid Yellow 2 

*Acid Yellow 3 

Acid Yellow 4- 

Acid Yellow 7 

Acid Yellow 9 

*Acid Yellow 11 

Acid Yellow 1^ 

*Acid Yellow 17 

»Acid Yellow 23— 

Acid Yellow 25 

Acid Yellow 29 

Acid Yellow 34 

*Acid Yellow 36 

Acid Yellow 38 

*Acid Yellow 4-0 

*Acid Yellow 42 

*Acid Yellow 44 

»Aoid Yellow 54 

Acid Yellow 59 

Acid Yellow 60 

Acid Yellow 63 

Acid Yellow 65 

*Aeid Yellow 73 

Acid Yellow 76 

Acid Yellow 90 

Acid Yellow 95 

*Aoid Yellow 99 

Acid Yellow 114 

Acid Yellow 121 

Acid Yellow 124 

Acid Yellow 127 

Acid Yellow 128 

Acid Yellow 129 

Acid Yellow 151- 

Acid Yellow 152 

Acid Yellow 159— 

Other acid yellow dyes 

*Acid orange dyes: 

*Aoid Orange 1 

Acid Orange 2 

Acid Orange 5 

Acid Orange 6 

*Acid Orange 7 

*Acid Orange 8 

«-Acid Orange 10 

Acid Orange 12 

Acid Orange 19 



Manufacturers' identification codes 
(according to list in table 22) 



ACY. 

DUP. 

ACY, DUP, NAG. 

SDH. 

NAC. 

ACY. 

CMG, DUP, VPC. 

THC. 

ACY, ATL, BKS, CMG, DUP, G, NAC, PBC, SDH, TRC, VPC. 

AAP, ACY, G, MRX, NAC, SDH, TRC, VPC. 

G. 

G, TRC. 

NAC. 

DUP, G, NAC, TRC. 

NAC. 

ACY, DUP, G, NAC, TRC, VPC. 

AAP, ACY, G, VPC. 

AAP, G, NAC, VPC. 

ACY, BKS, CMG, G, NAC, TRC, VPC. 

VPC. 

NAC. 

AAP, NAC. 

TRC. 

G, NAC, NYC, SDH. 

TRC. 

NAC. 

CM}. 

CMG, G, NAC, TRC, VPC. 

CMG, TRC. 

G. 

DUP, NAC. 

TRC. 

TRC. 

TRC. 

ACY. 

ACY. 

TRC. 

ACY, ALT, CMG, DUP, VPC. 

ALT, BKS, G, NAC. 

NAC. 

ACY. 

NAC. 

AAP, ACY, ATL, BKS, CPC, G, NAC, PDC, TRC, YAW. 

ACY, AIL, BKS, DUP, G, NAC, IRC. 

ACY, ATL, DUP, G, NAC, TRC, VPC, YAW. 

NAC. 

G. 



92 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 8B. 



-Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



Dye 



ACID DYES- -Continued 

»Acld orange dyes — Continued 

»Acld Orange 24 

Acid Orange 28 

Acid Orange 31 

Acid Orange 32 

Acid Orange 34 

Acid Orange 45 

Acid Orange 49 

Acid Orange 51 

Acid Orange 52 

Acid Orange 56 

»Acid Orange 60 

Acid Orange 62 

Acid Orange 63 

Acid Orange 64 

Acid Orange 69 

Acid Orange 72 

*Acid Orange 74 

Acid Orange 76 

Acid Orange 85 

Acid Orange 86 

Acid Orange 114 

Acid Orange 116 

Acid Orange 119 

Other acid orange dyes 

*Acid red dyes: 

»Acid Red 1 

»Acid Red 4 

Acid Red 12 

*Acid Red 14 

Acid Red 17 

»Acid Red 18 

Acid Red 25 

»Acid Red 26 

Acid Red 27 

Acid Red 29 

Acid Red 32 

Acid Red 33 

Acid Red 34 

Acid Red 35 

*Acid Red 37 

Acid Red 42 

Acid Red 52 -• 

Acid Red 57 

Acid Red 60 

Acid Red 66 

»Acid Red 73 

Acid Red 76 

Acid Red 80 

*Acid Red 85 

»Acid Red 87 

*Acid Red 88 

*Acid Red 89 

Acid Red 92 

Acid Red 94 

Acid Red 97 ■ 

»Acid Red 99 

Acid Red 100 

Acid Red 106 

Acid Red 109 

Acid Red 113 - 



Manufacturers' identification codes 
(according to list in table 22) 



AAP, ACY, 


DUP, G, 


NAC. 




AAP. 




AAP. 




ACY. 




NAC, TRC. 




TRC. 




CMG, NAC, 


TRC. 


NAC. 




G. 




CMG, DUP, 


G. 


TRC. 




G, TRC. 




ACY, DUP, 


NAC. 


ACY. 




G. 




CMG, G, NAC, TRC 


NAC, TRC. 




NAC. 




NAC, TRC. 




ACY. 




BKS, TRC. 




TRC. 




ALT, VPC. 





NAC, TRC, YAW. 



AAP, ACY, BKS, DUP, G, NAC, SDH, TRC, VPC, YAW. 

ATL, CMG, DUP, G, TRC, VPC, YAW. 

G, NAC, TRC. 

ATL, DUP, G, NAC, PDC. 

ATL, NAC, TRC, YAW. 

ACY, ATL, DUP, G, NAC, TRC. 

TRC. 

ACY, ATL, CPC, G, NAC. 

NAC. 

NAC. 

G, NAC. 

NAC, YAW. 

DUP, NAC. 

AAP, G. 

BNS, CMG, DUP, G, NAC, TRC. 

G. 

G. 

TRC. 

TRC. 

AAP, NAC. 

ACY, DUP, G, NAC, TRC. 

NAC. 

G, ICI. 

ACY, ALT, ATL, BKS, CMG, DUP, G, NAC, PDC, TRC, VPC, 

YAW. 
AMS, NYC, SDH. 

ACY, ATL, DUP, G, NAC, SDH, TRC, YAW. 
AAP, G, TRC, VPC. 
NYC, SDH. 
NYC. 
ATL, G. 

CMG, NAC, TRC, VPC. 
VPC. 
YAW. 
VPC. 
DUP. 



DYES 

TABLE 8B. —Bemenoid dyes for which U.S. production or sales were reported identified by 
manufacturer, 1964— Continued 



93 



Dye 



ACID DYES--Continued 



*Aoid red dyes — Continued 

Acid Red lU 

»Acid Red 115 

Aoid Red 119 

Acid Red 133 

Acid Red 134 

»Acld Red 137 

»Aoid Red 151 

Aoid Red 153 

Acid Red 167 

Acid Red 172 

Acid Red 175 

Acid Red 178 

Aoid Red 179 

*Aoid Red 182— ■ 

Acid Red 183 ■ 

Aoid Red 184- 

»Acid Red 186 

Acid Red 190— - 

Aoid Red 191 

Aoid Red 194— ■ 

Acid Red 207— 

Aoid Red 212 — 

Acid Red 213 

Acid Red 218 

Aoid Red 273 

Acid Red 292 

Acid Red 299— 

Aoid Red 309— — 

Other aoid red dyes 

*Acid violet dyes : 

*Acid Violet 1 

*Aold Violet 3— 

Acid Violet 6 

*Aoid Violet 7 

Aoid Violet 11 

*Aoid Violet 12 

Aoid Violet 13 

Acid Violet 14 

*Acid Violet 17 

Aoid Violet 21 

Aoid Violet 29 

Aoid Violet 34 

Acid Violet 41 

*Aoid Violet 43 

Acid Violet 49 

Acid Violet 56 

Acid Violet 58-; 

Acid Violet 76 

Acid Violet 78 

Other acid violet dyes — 
*Acid blue dyes: 

Aoid Blue 1 

»Acid Blue 7 

*Acid Blue 9 

Aoid Blue 10 

Acid Blue 13 

Aoid Blue 15 

Aoid Blue 20 

Acid Blue 22 

Aoid Blue 23 

»Aoid Blue 25 

Acid Blue 26 

Acid Blue 27 



Manufacturers ' identification codes 
(according to list in table 22) 



ATL, DUP, G. 

G, NAG, TRC. 

NAC. 

G. 

TRC. 

ACY, DUP, G, NAC, TRC. 

AAP, ACY, BKS, THG, YAW. 

YAW. 

BKS, NAC, TRC. 

VPC. 

DUP. 

DUP. 

CMG. 

ACY, BKS, CMG, DUP, G, NAC. 

CMG, TRC. 

TRC. 

ACY, BKS, CMG, DUP, G, TRC, VPC. 

ACY. 

TRC. 

TRC. 

NAC. 

TRC. 

TRC. 

NAC. 

G. 

ACY. 

TRC. 

TRC. 

ACY, ALT, ATL, TRC, VPC. 

CMS, G, NAC. 

ACY, DUP, NAC, TRC, YAW. 

NAC. 

AAP, CMG, DUP, G, NAC, THC, VPC. 

G. 

CMG, DUP, G. 

DUP. 

THC. 

DUP, G, SDH, TRC. 

DUP. 

HSH. 

ICI, NAC. 

CMG. 

DUP, HSH, ICI. 

ACY, NAC. 

CMG, G. 

G. 

NAC. 

NAC. 

ALT, DUP, TRC. 

G, NAC, SDH. 

ACY, G, NAC, SDH, VPC. 

G, NAC, SDH, VPC. 

AAP, NAC. 

DUP. 

DUP, G. 

ACY, NAC. 

ACY, NYC. 

NAC, TRC. 

ATL, CMG, DUP, G, NAC, TRC. 

NAC. 

CMC, G. 



94 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 8B. 



-Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer , 1964 — Continued 



Rye 



ACID DYES- -Continued 

*-Acid blue dyes — Continued 

Acid Blue 29 

Acid Blue 34 

Acid Blue 35 

*Acid Blue 40 

*Acld Blue 4-1 

*Acid Blue 43 

-fAcid Blue 45 

Acid Blue 47 

Acid Blue 48 

Acid Blue 58 

Acid Blue 59 

Acid Blue 62 

Acid Blue 63 

Acid Blue 67 

Acid Blue 69 

Acid Blue 74 

*Acid Blue 78 

Acid Blue 80 

Acid Blue 81 

Acid Blue S3 

Acid Blue 89 

Acid Blue 90 

Acid Blue 92 

Acid Blue 93 

Acid Blue 102 

Acid Blue 104 

*Acid Blue 113 

Acid Blue 118 

Acid Blue 120 

Acid Blue 122 - 

Acid Blue 137 

Acid Blue 145 

*Aeid Blue 158 and 158A 

Acid Blue 165 — 

Acid Blue 179 

Acid Blue 230 

Aold Blue 231 

Other acid blue dyes 

«Aoid green dyes : 

Acid Green 1 

»Acid Green 3 

Acid Green 5 

*Acld Green 9 

*Acid Green 12 

»Aoid Green 16 

*Acid Green 20 

*Acid Green 22 

»Aoid Green 25 

Acid Green 35 

Acid Green 41 

Acid Green 44 

Acid Green 50 

Acid Green 58 

Other acid green dyes 

ifAold brown dyes : 

Acid Brown 1 

Acid Brown 2 

Acid Brown 6 



Manufacturers ' identification codes 
(according to list in table 22) 



YAW. 




NAC. 




NAC. 




ATL, 


G, ICI, NAC, TRC. 


CMG, 


G, NAC. 


ACY, 


G, NAC, TRC. 


ACY, 


CMG, DUP, G, NAC, TRC, VPC. 


DUP, 


ICI. 


HSG. 




DUP. 




NAC. 




G, VPC. 


CMG, 


NAC. 


CMG, 


NAC. 


DUP, 


G. 


DUP, 


NAC. 


DUP, 


G, ICI, NAC, TRC. 


NAC, 


TRC. 


ICI. 




G. 




NAC. 




G, NAC, TRC. 


NAC. 




HSC. 




NAC, 


TRC. 


DUP, 


G, NAC. 


CMG, 


DUP, G. 


BKS, 


G, NAC. 


BKS, 


G, NAC. 


DUP. 




NAC. 




DUP. 




ACY, 


BKS, G, NAC, TRC, VPC. 


DUP. 




G. 




TRC. 




TRC. 




ACY, 


ALT, CMG, DUP, TRC, VPC. 


ACY, 


NAC. 


ACY, 


DUP, G, NAC, TRC, VPC. 



G. 

ACY, DUP, G, NAC, VPC. 

G, NAC, TRC. 

DUP, G, NAC, SDH, TRC. 

CMG, DUP, G, NAC, TRC. 

G, HSH, NAC. 

AAP, ATL, CMG, G, ICI, NAC, TRC, VPC. 

TRC. 

ICI, VPC. 

VPC. 

ACY, G, VPC. 

TRC. 

ALT, TRC, VPC. 

CM3, G. 

AAP. 

G. 



DYES 



95 



TABLE BB.--Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i564-- Continued 



Dye 



ACID DYES— Continued 

*Aoid brown dyes — Continued 

«Acid Brown lA 

Acid Brown 19 

Acid Brown 22 

Acid Brown 28 

Acid Brown 29 

Acid Brown 31 

Acid Brown A5 

Acid Brown 96 

Acid Brown 97 

Acid Brown 98 

Acid Brown 152 

Acid Brown 158 

Acid Brown 223 

Acid Brown 243 

Other acid brown dyes 

*Acid black dyes: 

»Aoid Black 1 

Acid Black 2 

Acid Black 12 

Acid Black 16 

Acid Black 18 

*Acid Black 24 

Acid Black 26, 26A, and 26B 

Acid Black 29 

Acid Black 41 

*Acid Black 48 

»Acld Black 52 

Acid Black 53 

Acid Black 58 

Acid Black 60 

Acid Black 92 

*Acid Black 107 

Acid Black 138 

Other acid black dyes 

AZOIC DYES AND COMPONENTS 
Azoic Compositions 

Azoic yellow dyes: 

*Azoio Yellow 1 

*Azoic Yellow 2 

Azoic Yellow 3 

Azoic orange dyes: 

*Azoic Orange 3 

Azoic Orange 4 

*Azoic red dyes: 

»Azoic Red 1 

*Azoic Red 2 

*Azoic Red 6 

Azoic Red 13 

Azoic Red 14 

Azoic Red 15 

*Azoio Red 16 



Manufacturers' identification codes 
(according to list in table 22) 



ACY, DUP, G, NAC, TRC, YAW. 



AAP, 

TRC. 

DUP. 

TRC. 

DUP, NAC. 

G. 

TRC. 

ACY. 

ACY. 

ACY, TRC. 

G. 

G. 

G. 

G. 

ALT, DUP, G, VPC 

AAP, ACY, ATL, BKS, CMG, DUP, FAB, G, NAC, PDC, TRC, 

YAW. 
ACY, NAC. 
NAC. 
NAC'. 
NAC. 

CMG, DUP, G, NAC. 
DUP, NAC, TRC. 
G, NAC. 
G, NAC. 

ACY, CMG, DUP, G, ICI, NAC, TRC. 
G, NAC, TRC. 
CMG, NAC. 
CMG, NAC, TRC. 
TRC. 
ACY. 

G, NAC, TRC. 
VPC. 
ALT, BL, DUP, PDC. 



ALL, ATL, BUG, G, HST, VPC. 
ALL, BUC, HST, x. 
ATL, BUC, G. 



ALL, 


ATL, 


BUC, 


G, 


VPC, 


X. 


G. 












ALL, 


ATL, 


BUC, 


G, 


HST, 


X. 


ALL, 


ATL, 


BUC, 


G, 


X. 




ALL, 


ATL, 


BUC, 


G, 


HST, 


VPC, X 


G. 












G. 












G. 












ATL, 


BUC, 


G. 









96 



TABLE 8B. 



SYNTHETIC ORGANIC CHEMICALS, 1964 

-Bemenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer , 1964 — Continued 



Cye 



AZOIC DYES AND COMPONENTS- -Continued 

Azoic Compositions— Contiuued 

»Azoio red dyes — Continued 

Azoic Red 73 

Azoic Red lA 

Other azoic red dyes 

Azoic violet dyes: 

Azoic Violet 1 

Other azoic violet dyes 

Azoic "blue dyes: 

»Azoic Blue 2 

*Azoic Blue 3 

Azoic Blue 4- 

Azoic Blue 6 

Azoic Blue 7 

Other azoic blue dyes 

Azoic green dyes: 

Azoic Green 1 

Other azoic green dyes 

Azoic brown dyes: 

*Azoic Brown 9 

Azoic Brown 10 

Azoic Brown 26 

Other azoic brown dyes 

»Azoic black dyes: 

Azoic Black 1 

Azoic Black 2 

Azoic Black <> 

Azoic Black 15 

Other azoic black dyes 

Other azoic compositions 

Azoic Diazo Components, Bases 
(Fast Color Bases) 



Component 1, base — 
Component 2, base — 
Component 3, base — 
Component 4, base — 
Component 5, base — 
Component 8, base--- 
Component 9, base — 
Component 10, base-- 
Component 11, base-- 
Component 12, base-- 
Component 13, base-- 
Component 14-, base-- 
Component 20, base-- 
Component 24-, base-- 
Component 28, base-- 
Component 32, base-- 
Component 3A, base-- 
Component ■41, base-- 
Component 42, base- 
Component "W-, base-- 
Component A6, base- 
Component 48, base- 
Component 49, base- 
Component 121, base 



Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


*Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


» Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


»Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


»Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


*Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 



Manufacturers' identification codes 
(according to list in table 22) 



ATL, BUC, G, VFC, x. 



ATL, G, X. 
G. 




ATL, BUC, G. 

ALL, ATL, BUC, 

G. 

ATL, G. 

G. 

G, VPC. 


G, HST, 


ATL, G. 
VPC. 





ATL, BUC, G, HST, VPC, x. 

BUC. 

G. 

BUC, G, VPC, X. 

G, HST. 

BUC. 

ALL, ATL, G. 

G. 

ATL, G, VPC. 

ALL. 



SDH. 

AAP, ATL. 

AAP, KLS, SDH. 

ALL, G, KLS, NAC, SDH. 

G, SDH. 

DUP, NAC. 

AAP, DUP, VPC. 

BUC, G, KLS. 

BUC. 

AAP, ALL, AUG, KLS, SDH. 

AAP, ALL, AUG, KLS, SDH. 

AAP. 

ALL, G. 

KLS. 

ALL, KLS, SDH. 

AAP, ALL, ATL, AUG, BUC, DUP, KLS, SDH. 

G. 

ALL, G. 

ALL. 

AAP. 

ATL. 

ALL, CWN, DUP, G. 

KLS. 

PCW. 



DYES 



97 



TABLE 8B.- 



-Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



Eye 



AZOIC DYES AND COMPONENTS- - Ctontinued 

Azoic Diazo Components, Salts 
(Fast Color Salts) 

»Azoio Diazo Component 1, salt 

Azoic Diazo Component 2, salt 

**Azoic Diazo Component 3, salt 

Azoic Diazo Component 4, salt 

»Azoio Diazo Component 5, salt 

■''Azoio Diazo Component 6, salt 

*Azoic Diazo Component 8, salt 

*fAzoio Diazo Component 9, salt 

*Azoio Diazo Component 10, salt 

«Azoio Wazo Component 11, salt 

*Azoic Diazo Component 12, salt 

*Azoic Diazo Component 13, salt 

Azoic Diazo Component 14, salt 

Azoic Diazo Component 20, salt 

*Azoic Diazo Component 28, salt 

»Azoic Diazo Component 32, salt 

Azoic Diazo Component 34, salt 

Azoic Diazo Component 35, salt 

*Azoic Diazo Component 36, salt 

Azoic Diazo Component 37, salt 

Azoic Diazo Component 41, salt 

Azoic Diazo Component 42, salt 

Azoic Diazo Component 44, salt 

»Azoic Diazo Component 48, salt 

»Azoic Diazo Component 49, salt 

Azoic Diazo Component 121, salt 

Other azoic diazo components, salts 

Azoic Coupling Components 
(Naphthol AS and Derivatives) 

Azoic Coupling Component 1 

»Azoio Coupling Component 2 

*Azoic Coupling Component 3 

»Azoic Coupling Con^ionent 4 

Azoic Coupling Component 5 

*Azolc Coupling Component 7 

Azoic Coupling Component 8 

Azoic Coupling Component 10 

Azoic Coupling Component 11 

Azoic Coupling Component 12 

Azoic Coupling Component 13 

»Azoic Coupling Component 14 

Azoic Coupling Component 15 

Azoic Coupling Component 16 

*Azoic Coupling Component 17 

*Azoic Coupling Component 18 

*Azoic Coupling Component 19 

■KAzoic Coupling Component 20 

wAzoic Coupling Component 21 

Azoic Coupling Component 23 

Azoic Coupling Component 24 

*Azoic Coupling Component 29 

Azoic Coupling Component 34 

Azoic Coupling Component 35 



Manufacturers ' identification codes 
(according to list in table 22) 



AAP, 


AUG, G, KLS, SDH. 










ALL, 


BUC, KLS. 












AAP, 


ALL, AUG, 


BUC, G, 


KLS, 


NAC, 


SDH, 


VPC 


ALL, 


AUG, DUP. 












AAP, 


AUG, BUC, 


G, KLS, 


SDH, 


VPC. 






AAP, 


G, KLS, SDH. 










AAP, 


ALL, AUG, 


BUC, G, 


KLS. 








AAP, 


ALL, AUG, 


BUC, G, 


KLS, 


NAC, 


SDH, 


VPC 


AUG, 


BUC, G, KIS. 










AAP, 


G, KLS. 












AAP, 


ALL, AUG, 


BUC, G, 


KLS, 


SDH. 






AAP, 


ALL, AUG, 


BUC, G, 


KLS, 


NAC, 


SDH, 


VPC 


AAP. 














ALL, 


G. 












ALL, 


AUG, BUC, 


G, KLS, 


SDH, 


VPC. 






ALL, 


AUG, BUC, 


KLS, SDH. 








G. 














G. 














AAP, 


G, NAC. 












G. 














ALL, 


G. 












ALL, 


G, KLS. 












G. 














AAP, 


ALL, G, KLS, NAC, 


SDH. 








AAP, 


BUC, G, KLS. 










BUC. 















ATL, AUG. 

ACY, ATL, BUC, DUP, G, NAC, PCW. 

BUC, G, PCW. 

ATL, BUC, G. 

AAP, G. 

AAP, AUG, G, PCW. 

ATL, G, PCW. 

PCW, SDH. 

BUC, G, PCW. 

ALL, BUC, G, PCW. 

ALL, G. 

ALL, ATL, BUC, G, PCW. 



ACY, ALL, ATL, BUC, DUP, PCW. 

ACY, ATL, BUC, DUP, G, PCW. 

AAP, BUC, G, PCW. 

ALL, ATL, BUC, DUP, G, PCW. 

ATL, BUC, PCW. 

G, PCW. 



ATL, BUC, G, PCW. 
BUC, G, PCW. 
ALL, G, PCW. 



98 



TABLE 8B. 



SYNTHETIC ORGANIC CHEMICALS, 1964 

-Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 564 — Continued 



AZOIC DYES AND COh/IPONENTS-- Continued 

Azoic Coupling Components 
(Naphlkol AS and Denvativesj-CtrntinuBd 

Azoic Coupling Component 36 

Azoic Coupling Component 43 

Other azoic coupling components 



Basic yellow dyes : 

Basic Yellow 1 

*Basic Yellow 2 

Basic Yellow 5 

*Basic Yellow 11 

*Basic Yellow 13 

Basic Yellow 15 

Basic Yellow 26 

Basic Yellow 27 

Basic Yellow 28 

Cither basic yellow dyes — 
*Basic orange dyes : 

*Basic Orange 1 

»Basic Orange 2 

Basic Orange 10 

Basic Orange 14 

Basic Orange 17 

ifBasic Orange 21 

Basic Orange 22 

Basic Orange 24 

Basic Orange 25 

Basic Orange 26 

Basic Orange 31 

*BaEic red dyes: 

Basic Bed 1 

*Basio Red 2 

Basic Red 9 

Basic Red 12 

Basic Red 13 

*Basic Red 14 

Basic Red 15 

Basic Red 16 

Basic Red 17 

Basic Red 18 

Basic Red 19 

Basic Red 20 

Basic Red 22 

Basic Red 30 

»Basic violet dyes : 

**Basic Violet 1 

Basic Violet 2 

ifBasic Violet 3 

*Basic Violet 4 

Basic Violet 7 

Basic Violet 10 

Basic Violet 13 

*Basic Violet 14 

Basic Violet 15 

*Basic Violet 16 

Basic Violet 18 

Other basic violet dyes- 



li'lanuf aoturers ' identification codes 
(according to list in table 22) 



AIL, G. 
ATL, G, VPC. 



DUP. 

ACY, DUP, NAG. 

NAG. 

DUP, G, NAG, VPC. 

DUP, G, NAG. 

DUP. 

ACY. 

ACY. 

VPC. 

G, DUP. 

ACY, DUP, G, NAG. 

ACY, DSC, DUP, G, NAG, PDG, TRC. 

VPC. 

G. 

NAC. 

DUP, G, NAC, VPC. 

G, NAC. 

DUP. 

DUP. 

DUP. 

ACY. 

DUP, G. 

DUP, G, NAC. 

DSC, HSC. 

DUP. 

G, NAC. 

ACY, DUP, G, NAC, VPC. 

DUP, G. 

DUP. 

DUP. 

DUP. 

DUP. 

DUP. 

ACY, TRC. 

ACY. 

ACY, DSC, HSC, NAC. 

ACY, NYC. 

DSC, DUP, G, NAG, SDH. 

DSC, DUP, G, NAG. 

G, NAG. 

ACY, DUP, G. 

DSC. 

ACY, DSC, NYC. 

DUP. 

DUP, G, VPC. 

ACY. 

DUP, G. 



TABLE 8B.- 



DYES 

-Benzerwid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



99 



BASIC DYES— Continued 

*Basio blue dyes: 

»Basic Blue 1 

Basic Blue 3 

Basic Blue 4 

Basic Blue 5 

Basic Blue 6 

*Basic Blue 7 

»Basio Blue 9 

Basic Blue 11 

Basic Blue 21 

Basic Blue 22 

*Basic Blue 26 

Basic Blue 35 

Basic Blue 36 

Basic Blue 38 

Basic Blue 39 

Basic Blue 54 

Other basic blue dyes 

Basic green dyes: 

«Basic Green 1 

Basic Green 3 

*Basic Green 4 

Basic Green 5 

Other basic green dyes 

Basic brown dyes : 

*Basic Brown 1 

Basic Brown 2 

*Basic Brown 4 

Basic black dyes: 

Basic Black 3 

Other basic black dyes 

DIRECT DYES 

^Direct yellow dyes: 

«Direot Yellow 4 

^Direct Yellow 5 

*Direct Yellow 6 

Direct Yellow 7 

Direct Yellow 8 

Direct Yellow 9 

*Direct Yellow 11 

«Direct Yellow 12 

Direct Yellow 19 

Direct Yellow 20 

Direct Yellow 23 

*Direct Yellow 26 

Direct Yellow 27 

^Direct Yellow 28 

^Direct Yellow 29 

Direct Yellow 39 

*Direct Yellow 44 

*Direct Yellow 50 

*Direct Yellow 59 

Direct Yellow 63 

Direct Yellow 81 

*Direct Yellow 84 

Direct Yellow 103 . 



Manufacturers' identification codes 
(according to list in table 22) 



DSC, G, NAC, SDH. 

G. 

DUP. 

DSC, SDH. 

ACY, NAG. 

DSC, DUP, G, MAC, SDH. 

ACY, G, NAC, SDH. 

ESC, DUP, SDH. 

DUP. 

DUP, NAC. 

DSC, DUP, G, NAC, SDH. 

DUP. 

DUP. 

ACY, DUP. 

DUP. 

ACY. 

ACY, G. 

ACY, DSC, DUP, NAC, SDH. 

DUP. 

ACY, DSC, NAC, SDH. 

ACY. 

DUP. 

ACY, DUP, G, NAC, TRC. 

G, NAC. 

ACY, DUP, G, NAC, TRC. 

G. 
DUP. 



ACY, DUP, G, NAC, TRC. 

ACY, BL, G, NAC. 

ACY, DUP, G, NAC, TRC. 

ATI. 

G, NAC. 

DUP. 

ACY, DUP, G, NAC, TRC. 

BKS, DUP, G, NAC, TRC. 

TRC. 

TRC. 

DUP. 

ALT, BKS, DUP. 

G. 

ATL, DUP, G, NAC, TRC, 

ATL, DUP, G. 

TRC. 

ALT, ATL, BKS, DUP, G, NAC, TRC, VPC. 

AIL, BKS, BL, DUP, G, NAC, TRC, VPC. 

ATL, DUP, NAC. 

DUP. 

BKS, TRC. 

G, NAC, TRC. 

NAC. 



100 



TABLE 8B. 



SYNTHETIC ORGANIC CHEMICALS, 1964 

-Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



DIRECT DYES— Continued 

»Direot yellow dyes — Continued 

Direct Yellow 105 

Direct Yellow 106 

Direct Yellow 107 

Direct Yellow IW 

Direct Yellow 117 

Direct Yellow 118 

Direct Yellow 121 

Direct Yellow 125 

Other direct yellow dyes 

»Direct orange dyes: 

^Direct Orange 1 

Direct Orange 6 

*Direct Orange 8 

Direct Orange 10 

Direct Orange 11 

*Direct Orange 15 

»Direct Orange 26 

Direct Orange 29 

»Direct Orange 34 

*Direct Orange 37 

Direct Orange 38 

*Direct Orange 39 

Direct Orange 40 

Direct Orange 48 

Direct Orange 55 

Direct Orange 59 

Direct Orange 61 

Direct Orange 67 

Direct Orange 70 

^Direct Orange 72 

♦Direct Orange 73 

Direct Orange 74 

Direct Orange 76 

Direct Orange 78 

Direct Orange 79 

Direct Orange 80 ■ 

♦Direct Orange 81 

Direct Orange 83 

Direct Orange 88 

♦Direct Orange 102 

Direct Orange 105 

Direct Orange 110 

Other direct orange dyes 

♦Direct red dyes: 

♦Direct Red 1 

♦Direct Red 2 

♦Direct Red 4 

Direct Red 5 

Direct Red 7 

♦Direct Red 10 

♦Direct Red 13 

♦Direct Red 16 -• 

Direct Red 20 

♦Direct Red 23 

♦Direct Red 24 

♦Direct Red 26 

♦Direct Red 28 

Direct Red 30 

♦Direct Red 31 

Direct Red 32 



TRC. 








BKS, 


TRC. 






G. 








ACY. 








TRC. 








ACY, 


TRC. 






TRC. 








ACY. 








ALT, 


ATL, 


BL, 


DUP, FAB, G, VPC. 


AAP, 


CMG, 


NAC 


VPC. 


NAC. 








ATL, 


DUP, 


G, 


■lAC, TRC. 


AAP, 


NAC. 






G. 








ACY, 


DUP, 


G, 


\IAC, TRC. 


ATL, 


CMG, 


DUP 


G, NAC, TEC. 


ATL, 


BKS, 


TRC 




ACY, 


ATL, 


CMG 


DUP, G, NAC. 


ACY, 


CMG, 


DUP 


G, TRC. 


NAC. 








ATL, 


BKS, 


CMG 


DUP, G. 


DUP. 








DUP. 








DUP, 


NAC. 






DUP, 


G. 






TRC. 








NAC, 


VPC. 






TRC. 








ACY, 


AIL, 


BKS 


, BL, FAB, NAC, TRC, VPC 


DUP, 


G, TRC, 


VPC. 


DUP. 








DUP. 








DUP, 


VPC. 






DUP. 








DUP, 


VPC. 






DUP, 


G, NAC, 


VPC. 


G, NAC. 






DUP. 








ACY, 


DUP, 


G, 


NAC. 


BKS. 








TRC. 








ALT, 


ATL, 


BL, 


DUP, G, VPC. 



AAP, ATL, DUP, G, NAC, TRC, YAW. 

ATL, BKS, DUP, NAC, TRC. 

NAC, TRC, VPC. 

NAC. 

DUP. 

AAP, ACY, ATL, NAC. 

AAP, AIL, DUP, G, NAC, TRC, YAW. 

ATL, DUP, G, NAC, TRC. 

G, NAC. 

ATL, BKS, CMG, DUP, FAB, G, NAC, TRC, VPC. 

AAP, ATL, BKS, BL, FAB, NAC, TRC, VPC. 

ATL, BKS, CMG, DUP, G, NAC, TRC, VPC. 

ATL, DUP, NAC, TRC. 

VPC. 

ATL, DUP, G, NAC. 

DUP, NAC. 



DYES 



101 



Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer , 1964 — Continued 



DIRECT DYES--Continued 

»Direot red dyes — Continued 

*Direot Red 37 

^Direct Red 39 

Direct Red 4-6 

Direct Red 53 

Direct Red 62 

Direct Red 72 

Direct Red 73 

»Direct Red 75 

Direct Red 76 

^Direct Red 79 

«Direct Red 80 

*Direct Red 81 

*Direct Red 83 

Direct Red 84 

Direct Red 94 

Direct Red 95 

Direct Red 100 

Direct Red 111 

Direct Red 117 

Direct Red 122 

Direct Red 123 

Direct Red 127 and 127A 

Direct Red 139 

Direct Red 148 

^Direct Red 149 

*Direot Red 152 

Direct Red 153 

Direct Red 155 

Direct Red 209 

Other direct red dyes 

*Direct violet dyes: 

^Direct Violet 1 

Direct Violet 7 

»Direct Violet 9 

Direct Violet 14 

Direct Violet 22 

Direct Violet 30 

Direct Violet 47 

»Direct Violet 48 

Direct Violet 49 

Direct Violet 51 

Direct Violet 60 

Direct Violet 67 

Direct Violet 68 

Other direct violet dyes 

*Direct blue dyes: 

*Direct Blue 1 

*Direct Blue 2 

*Direct Blue 6 

*Dlrect Blue 8 

Direct Blue 10 

^Direct Blue 14 

»Direct Blue 15 

Direct Blue 21 

^Direct Blue 22 

»Direct Blue 24 

»Direct Blue 25 



Manufacturers' identification codes 
(according to list in table 22) 



ACY, ATL, G, NAC, TRC, YAW. 

ATL, G, NAC, TRC, YAW. 

ATL, TRC. 

NAC. 

ATL, TRC. 

G, TRC. 

DUP, NAC. 

ACY, DUP, G, NAC, VPC. 

G, NAC. 

ATL, BKS, CKi, NAC, TRC, VPC. 

AAP, ATL, BKS, BL, CM), DUP, FAB, G, NAC, TRC, VPC. 

AAP, ACY, ALT, ATL, BKS, BL, CMG, DUP, G, NAC, THC, 

VPC, YAW. 
ALT, ATL, BKS, CMG, DUP, NAC, TRC, VPC. 
G, NAC, TRC. 
NAC. 
VPC. 
NAC. 
G. 

BL, DUP. 

cm, G, TRC, VPC. 
G. 

CMG, DUP, TRC. 
VPC. 
DUP. 

ATL, CMG, DUP, G, NAC, TRC. 
CMG, DUP, NAC. 
NAC. 
G. 

TRC. 
ALT, BL, DUP, TRC. 

AAP, ATL, DUP, NAC. 

G, NAC. 

ATL, BKS, DUP, G, NAC, TRC. 

ATL, NAC. 

DUP. 

AAP. 

DUP, G. 

DUP, NAC, TRC. 

NAC. 

DUP, NAC. 

NAC. 

DUP, NAC. 

DUP. 

ALT. 

AAP, ACY, ATL, BKS, BL, DUP, FAB, G, NAC, THC, VPC, 

YAW. 

AAP, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, VPC, YAW. 

AAP, ACY, ATL, BKS, BL, DUP, G, NAC, TRC, YAW. 

ATL, BKS, DUP, G, NAC, TRC. 
DUP. 

ATL, DUP, NAC, TRC. 

ATL, DUP, G, NAC, YAW. 
TRC. 

ATL, CM}, DUP, NAC. 

BKS, NAC, TRC, YAW. 
DUP, G, NAC, TRC, YAW. 



102 



SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 8-B.—Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 564— Continued 



Dye 



DIRECT DYiS — Continued 



^Direct blue dyes-- 

*Direot Blue 26- 

Direct Blue 27-' 

Direct Blue 55- 

Direct Blue 66- 

*Direct Blue 67- 

wDlrect Blue 71- 

Direct Blue 74- 

Direct Blue 75- 

*nirect Blue 76- 

*Direct Blue 78- 

Direct Blue 79- 

*Direot Blue 80- 

Direct Blue 84- 

»Direot Blue 86- 



Mreot Blue 87 ■ 

Direct Blue 91 

^Direct Blue 98 

Direct Blue 100— ■ 

Direct Blue 104 

♦Direct Blue 120 and 120A- 

*Direct Blue 126 

ELreet Blue 127 

Direct Blue 130 

Direct Blue 133 

Direct Blue 136 

Direct Blue 143 

♦Direct Blue 151 

Direct Blue 160 

Direct Blue 180 

Direct Blue 189 

Direct Blue 191 

Direct Blue 199 

Direct Blue 238 

Other direct blue dyes — 
♦Direct green dyes: 

♦Direct Green 1 

♦Direct Green 6 

♦Direct Green 8 

♦Direct Green 12 

Direct Green 14 

Direct Green 15 

Direct Green 26 

Direct Green 27 

Direct Green 28 

♦Direct Green 38 

Direct Green 39 

Direct Green 41 

Direct Green 45 

Direct Green 47 

Other direct green dyes- 
♦Dlrect brown dyes : 

♦Direct Brown 1 

♦Direct Brown lA 

♦Direct Brown 2 

♦Direct Brown 6 

Direct Brown 11 

Direct Brown 21 

Direct Brown 25 



Manufacturers ' identification codes 
(according to list in table 22) 



ATL, 


DUP, 


G, NAC. 




DUP. 








NAG. 








DUP. 








ATL, 


DUP, 


NAC, TRC. 




ATL, 


DUP, 


G, NAC, TRC. 




DUP. 








TRC. 








ATT,, 


BKS, 


BL, DUP, G, NAC, TRC, VPC. 




ATL, 


CMG, 


DUP, G, NAC, TRC. 




TRC. 








ALT, 


ATL, 


BKS, DUP, FAB, G, NAC, STD, 


TRC. 


DUP. 








AAP, 


ACY, 


ATL, BKS, CMG, DUP, FAB, G, 


ICC, ICI, NAC 


SDH, TMS, TRC, VPC. 




ICI. 








TRC. 








AAP, 


ALT, 


ATL, G, ICC, TRC, VPC. 




ALT, 


NAC. 






DUP. 








ATL, 


BKS, 


DUP, G, TRC. 




BL, 


DUP, 


G, NAC, TRC, VPC. 




G. 








NAC. 








G. 








G. 








DUP. 








AIL, 


DUP 


NAC, TRC. 




TRC. 








CMG, 


NAC 


TRC. 




TRC. 








AAP, 


G. 






G. 








ACY 








ALT 


ATL 


BL, DUP, FAB, G, NAC, VPC. 





AAP, ACY, ATL, BKS, DUP, G, NAC, TRC, YAW. 

AAP, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, YAW. 

ATL, NAC, TRC, YAW. 

DUP, NAC, TRC. 

NAC. 

DUP. 

NAC, TRC. 

NAC, TRC. 

TRC. 

DUP, G, NAC. 

G. 

DUP. 

VPC. 

DUP, G. 

ACY, ALT, ATL, BL, DUP. 

ACY, ATL, BKS, BL, DUP, FAB, NAC. 

G, TRC, YAW. 

AAP, ACY, ATL, BKS, BL, DUP, G, NAC, TRC, YAW. 

DUP, G, NAC, TRC. 

NAC. 

DUP. 

DUP, NAC. 



DYES 

TABLE 8B. — Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer , 1964 — Continued 



103 



Eye 



Manufacturers ' identification codes 
(according to list in table 22) 



DIRECT DYES— Continued 

»Direct brown dyes — Continued 

Direct Brown 27 

Direct Brown 29 

*Direot Brown 31 

Direct Brown 32 

nlreot Brown 33 

Mrect Brown 35 

Direct Brown 'tO 

Direct Brown 44 

Direct Brown iS 

Direct Brown 59 

*Direct Brown 74 

»Direot Brown 95 

Direct Brown 101 

Direct Brown 105 

Direct Brown 106 

♦Direct Brown 111 

Direct Brown 112 

Direct Brown 125 

♦Direct Brown 154 

Other direct brown dyes 

♦Direct black dyes: 

Direct Black 3 

♦Direct Black 4 

Direct Black 8 

♦Direct Black 9 

Direct Black 17 

♦Direct Black 19 

♦Direct Black 22 

Direct Black 29 

Direct Black 36 

♦Direct Black 37 

♦Direct Black 38 

Direct Black 44 

♦Direct Black 51 

Direct Black 55 

Direct Black 56 

Direct Black 61 

Direct Black 67 

Direct Black 71 

Direct Black 74 

Direct Black 75 

Direct Black 78 

♦Direct Black 80 

Direct Black 109 

Direct Black 130 

Other direct black dyes 

DISPERSE DYES 

♦Disperse yellow dyes: 

♦Disperse Yellow 1 

Disperse Yellow 2 

♦Disperse Yellow 3 

♦Disperse Yellow 5 

Disperse Yellow 8 

Disperse Yellow 17 

♦Disperse Yellow 23 

Disperse Yellow 31 

Disperse Yellow 32 



G. 

NAC. 

AAP, ATL, DUP, G, NAC, YAW. 

G. 

DUP, NAC. 

NAC. 

AAP. 

G, YAW. 

AAP. 

ACY. 

AAP, DUP, NAC. 

AAP, ALT, ATL, BKS, DUP, G, NAC, TRC, YAW. 

G. 

DUP. 

G, NAC. 

DUP, G, TRC, VPC. 

NAC. 

G. 

DUP, G, TRC, YAW. 

ALT, BL, NAC, TRC, VPC, YAW. 

DUP. 

ATL, BKS, DUP, G, NAC, TRC, YAW. 

TRC, YAW. 

BKS, DUP, G, NAC, TRC. 

G, NAC, TRC. 

ATL, BKS, G, NAC, TRC, VPC. 

AAP, ALT, ATL, BKS, CMG, DUP, G, NAC, TRC, VPC, YAW. 

ATL. 

AAP. 

AAP, DUP, NAC. 

AAP, ACY, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, YAW. 

TRC. 

AAP, ATL, DUP, G, NAC, TRC. 

DUP. 

NAC, TRC. 

TRC. 

DUP, NAC. 

AIL, VPC. 

NAC. 

G. 

BKS, NAC. 

AAP, ATL, BKS, BL, FAB, G, NAC, TRC, VPC, YAW. 

G. 

ACY. 

ACY, ALT, ATL, VPC, YAW. 



DUP, G, ICC. 

DUP. 

AAP, BL, DUP, EKT, G, HSH, ICC, NAC, SDH, STD, TRC. 

EKT, G, ICC, STD. 

DUP, TRC. 

AAP. 

DUP, EKT, ICC. 

G. 

DUP. 



104 



SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 8B -Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 564 —Continued 



DISPERSE DYES—Continued 



♦Disperse yellow dyes — Continued 

♦Disperse Yellow 33 

Disperse Yellow 34 

♦Disperse Yellow 37 

Disperse Yellow 42 

Disperse Yellow 50 

♦Disperse Yellow 54 

Disperse Yellow 67 

Other disperse yellow dyes 

♦Disperse orange dyes: 

♦Disperse Orange 3 

♦Disperse Orange 5 

Disperse Orange 16 

♦Disperse Orange 17 

Disperse Orange 21 

Disperse Orange 25 

Disperse Orange 26 

Disperse Orange 29 

Disperse Orange 30 

Disperse Orange 38 

Disperse Orange 44- 

Other disperse orange dyes 

♦Disperse red dyes: 

♦Disperse Red 1 

Disperse Red 4 

♦Disperse Red 5 

Disperse Red 7 

Disperse Red 9 

♦Disperse Red 11 

♦Disperse Red 13 

Disperse Red 15 

♦Disperse Red 17 

Disperse Red 20 

Disperse Red 21 

Disperse Red 30 

Disperse Red 31 

Disperse Red 32 

Disperse Red 53 

Disperse Red 55 

Disperse Red 56 

Disperse Red 59 

♦Disperse Red 60 

Disperse Red 61 

Disperse Red 65 

Disperse Red 66 

Disperse Red 73 

Disperse Red 96 

Other disperse red dyes 

♦Disperse violet dyes: 

♦Disperse Violet 1 

Disperse Violet 4 

Disperse Violet 8 

Disperse Violet 11 

Disperse Violet 14 

Disperse Violet 17 

Disperse Violet 18 

Disperse Violet 22 

Disperse Violet 26 

Disperse Violet 27 

Other disperse violet dyes — 
♦Disperse blue dyes: 

♦Disperse Blue 1 

♦Disperse Blue 3 



Manufacturers' identification codes 
(according to list in tahle 22) 



AAP, EKT, ICC. 

AAP, EKT, ICC. 

AAP, EKT, ICC. 

DUP, TEC. 

TRC. 

AAP, DUP, G, ICC, TRC. 

DUP. 

DUP, EKI, G. 

AAP, DUP, EKT, G, ICC, NAC, STD, TRC. 

AAP, EKT, G. 

AAP. 

AAP, EKI, G, HSH, ICC, NAC, STD. 

TRC. 

DUP. 

DUP. 

AAP. 

TRC. 

TRC. 

DUP. 

DUP, EKT, G, ICC, TRC. 

AAP, DUP, EKT, G, ICC, NAC, STD, TRC, YAW. 

G, TRC. 

AAP, EKI, G, HSH, ICC, STD. 

AAP. 

DUP. 

AAP, DUP, G, TRC. 

DUP, G, ICC. 

G, HSH, ICC, NAC. 

AAP, DUP, EKT, G, HSH, ICC, STD, TRC. 

NAC. 

EKT. 

EKI, TRC. 

ICC. 

G. 

TRC. 

TRC. 

DUP. 

DUP, G. 

AAP, DUP, VPC. 

DUP. 

DUP. 

AAP. 

TRC. 

ACY. 

DUP, EKT, G, ICC, TRC, VPC. 

AAP, DUP, G, ICC, STD, TRC. 

AAP, G, ICC. 

G. 

EKI, NAC. 

DUP. 

ACY. 

DUP. 

G. 

DUP. 

AAP, BL, DUP, G. 

EKT, ICC. 



AAP, G, TRC. 
AAP, EKT, G, ICC, 



NAC, STD, TRC. 



DYES 



105 



TABLE 8B. —Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer , 1964 — Continued 



Dye 



DISPERSE DYES^-Continued 

*Dlsperee blue dyes — Continued 

^Disperse Blue 7 

Disperse Blue 8 

Disperse Blue 9 

Disperse Blue 27 

Disperse Blue 35 

Disperse Blue 41 

Disperse Blue 51 

Disperse Blue 55 

Disperse Blue 59 

Disperse Blue 60 

Disperse Blue 61 

Disperse Blue 62 

Disperse Blue 63 

»Dlsperse Blue 64 

Disperse Blue 67 

Disperse Blue 70 

Disperse Blue 71 

Disperse Blue 73 

Disperse Blue 79 

Other disperse blue dyes 

»Dlsperse brown dyes: 

Disperse Broim 2 

Other disperse brown dyes 

*Disperse black dyes: 

«Dlsperse Black 1 

Disperse Black 2 

Disperse Black 6 

Disperse Black 7 

*Disperse Black 9 

Other disperse black dyes 

FIBER-REACTIVE DYES 

^Reactive yellow dyes: 

Reactive Yellow 1 

Reactive Yellow 2 

Reactive Yellow 3 

Reactive Yellow 4 

Reactive Yellow 6 

Reactive Yellow 7 

Reactive Yellow 15 

Reactive Yellow 18 

Reactive Yellow 22 

Other reactive yellow dyes 

Reactive orange dyes: 

Reactive Orange 1 

Reactive Orange 2 

Reactive Orange 4 

Reactive Orange 5 

Reactive Orange 7 

Reactive Orange 12 

Reactive Orange 13 

Reactive Orange 14 

Other reactive orange dyes 

Reactive red dyes: 

Reactive Red 1 

Reactive Red 2 

Reactive Red 3 

Reactive Red 4 

Reactive Red 5 

Reactive Red 8 

Reactive Red 11 

Reactive Red 13 

Reactive Red 16 

Reactive Red 29 

Reactive Red 31 

Reactive Red 33 

Other reactive red dyes 



Manufacturers' identification codes 
(according to list in table 22) 



EKT, G, 


HSH, 


ICC, TRC. 


DUP. 






G, ICC. 






EKT. 






G. 






NAC. 






G. 






TRC. 






DUP. 






DUP. 






DUP. 






DUP. 






DUP. 






DUP, G, 


TRC. 




DUP. 






AAP. 






VPC. 






TRC. 






TRC. 






EKT, G, 


ICC, 


STD. 


DUP, G. 






EKT, IOC 






AAP, BL, 


DUP 


G, TRC. 


DUP, TRC 






DUP. 






YAW. 






AAP, BL, 


DUP 


EKT, G, KLS, NAC 


DUP, EKT 


, G, 


ICC, YAW. 



ICI. 
TRC. 
TRC. 
ICI. 
TRC. 
ICI. 
DUP. 
ICI. 
ICI. 
G, HST. 

ICI. 
TRC. 
ICI. 
TRC. 
DUP. 
ICI. 
ICI. 
ICI. 
HST. 

ICI. 
ICI. 
ICI. 
TRC. 
ICI. 
ICI. 
ICI. 
ICI. 
TRC. 
ICI. 
ICI. 
ICI. 
DUP, G, HST. 



106 



TABLE 8B. 



SYNTHETIC ORGANIC CHEMICALS, 1964 

-Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 964— Continued 



FIBEH-REACTIVE DYES— Continued 



Reactive violet dyes: 

Reactive Violet 1 

Reactive Violet 2 

Other reactive violet dyes- 
*Reactive blue dyes: 

Reactive Blue 1 

Reactive Blue 2 

Reactive Blue 3 

Reactive Blue 4 

Reactive Blue 5 

Reactive Blue 7 

Reactive Blue 9 

Reactive Blue 19 

Reactive Blue 25 

Other reactive blue dyes--- 

Reactive green dyes 

Reactive brown dyes: 

Reactive Brown 1 

Reactive Brown 10 

Reactive black dyes: 

Reactive Black 1 

Reactive Black 9 

Other reactive black dyes-' 



FLUORESCENT BRIGHTENING AGENTS 



Fluorescent Brightening Agent 1 

Fluorescent Brightening Agent 6 

Fluorescent Brightening Agent 8 

Fluorescent Brightening Agent 9 

Fluorescent Brightening Agent 22 

Fluorescent Brightening Agent 24- 

Fluorescent Brightening Agent 25 

Fluorescent Brightening Agent 28 

Fluorescent Brightening Agent 30 

Fluorescent Brightening Agent 33 

Fluorescent Brightening Agent 34 

Fluorescent Brightening Agent 37 

Fluorescent Brightening Agent 45 

Fluorescent Brightening Agent 46 

Fluorescent Brightening Agent 49 

Fluorescent Brightening Agent 52 

Fluorescent Brightening Agent 61 

Fluorescent Brightening Agent 66 

^Fluorescent Brightening Agent 68 

Fluorescent Brightening Agent 71 

Fluorescent Brightening Agent 75 

Fluorescent Brightening Agent 102 

Fluorescent Brightening Agent 108 

Fluorescent Brightening Agent 113 

Fluorescent Brightening Agent 114 

Fluorescent Brightening Agent 125 

Fluorescent Brightening Agent 134 

Fluorescent Brightening Agent 135 

Fluorescent Brightening Agent 136 

Fluorescent Brightening Agent 139 

Fluorescent Brightening Agent 155 

Fluorescent Brightening Agent 159 

Fluorescent Brightening Agent 161 

Other fluorescent brightening agents- 



Manufacturers' identification codes 
(according to list in table 22) 



ICI. 
TRC. 
HST. 

ICI. 

TRC. 

ICI. 

ICI. 

TRC. 

TRC. 

ICI. 

DUP. 

ICI. 

DUPj G, HST. 

HST. 

TRC. 
ICI. 

TRC. 
ICI. 
HST. 



GGX. 

ACY. 

ACY. 

ACY, G. 

GGY. 

GGY. 

G. 

ACY, DUP. 

G. 

G. 

DUP. 

CIB. 

TRC. 

GGY. 

S. 

S. 

ACY. 

SDH. 

CCW, G, SDH. 

ACY, G. 

G. 

DUP. 

G. 

VPC. 

VPC. 

ACY. 

CIB. 

CIB. 

CIB. 

CIB. 

WLM. 

ACY. 

ACY. 



ACY, CCW, CIB, DUP, G, GGY, S, VPC. 



DYES 



107 



TABLE 8B.- 



-Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 7564--Continued 



FOOD, DRUG, AND COSMETIC COLORS 
Food, Drug, and Cosmetic Dyes 



»FDaC Blue No. 1 

FD&C Blue No. 2 

FD&C Green No. 1 

FD&C Green No. 3 

»FD&C Red No. 2 

*FD&C Red No. 3 

*FD&C Red No. -4 

FD&C Violet No. 1 

*FD&C Yellow No. 5 

*FD&C Yellow No. 6 

Other food, drug, and cosmetic dyes- 
Drug and Cos 



■ Dye. 



D&C Black No. 1 

D&C Blue No. 6 

D&C Blue No. 9 

D&C Brown No. 1 

D&C Green No. 5 

D&C Green No. 6 

D&C Green No. 8 

D&C Orange No. 4- 

D&C Orange No. 5 

D&C Orange No. 10 

D&C Orange No. 14- 

D&C Orange No. 17 

D&C Red No. 2 

D&C Red No. 3 

D&C Red No. 6 

*D&C Red No. 7 

D&C Red No. 8 

D&C Red No. 9 

D&C Red No. 10 

D&C Red No. 11 

E&C Red No. 12 

E&C Red No. 13 

D&C Red No. 17— 

*D&C Red No. 19 

*D&C Red No. 21 

D&C Red No. 22 

D&C Red No. 27 

D&C Red No. 28 

D&C Red No. 30 

D&C Red No. 31 

D&C Red No. 33 

D&C Red No. 34 

*D&C Red No. 36 ^ 

D&C Red No. 37 

D&C Red No. 39 

D&C Violet No. 2 

D&C Yellow No. 5 



Manufacturers ' identification codes 
(according to list in table 22) 



BAT 


KON 


NAC, 


SDH, 


WJ. 




KON 


NAC 


SDH. 








NAC 












WJ. 












BAT 


KON 


NAC, 


SDH, 


STG, 


WJ 


BAT 


KON 


NAC, 


SDH, 


STG. 




BAT 


KON 


NAC, 


SDH, 


STG, 


WJ 


NAC 












BAT 


KON 


NAC, 


SDH, 


STG, 


WJ 


BAT, 


KON 


NAC, 


SDH, 


STG, 


WJ 


KON, 


WJ. 










KON, 


NAC. 










KON, 


NAC. 










NAC. 












NAC. 












KON, 


NAC. 










KON, 


NAC. 










KON, 


SDH. 










KON, 


SNA. 










KON, 


SNA, 


TMS. 








TMS. 












TMS. 












KON, 


SNA. 










KON. 












KON, 


T^B. 










SNA, 


TMS. 










KON, 


SNA, 


TMS. 








TMS. 












KON, 


SNA, 


TMS. 








KON, 


SNA. 










KON, 


SNA. 










KON, 


SNA, 


TMS. 








KON, 


SNA, 


TMS. 








KON, 


NAC. 










KON, 


SNA, 


IMS. 








KON, 


SNA, 


TWB. 








KON. 












KON, 


SDH, 


TMS. 








NAC, 


TMS. 










KON. 












KON. 












KON, 


NAC. 










KON, 


TMS. 










KON, 


SNA, 


TMS. 








NAC. 












SDH. 












NAC. 












TMS. 













108 



SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 8B. —Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 964— Continued 



FOOD, DRUG, AND COSMETIC COLORS— Continued 
Drug and Cosmetic Dyes--Continued 

D&C Yellow No. 7 

D&C Yellow No. 8 

D&C Yellow No. 10 

D&C Yellow No. 11 

Drug and Cosmetic Dyes, External 

Ext. D&C Blue No. 1 

Ext. D&C Green No. 1 

Ext. D&C Orange No. 3 

Ext. D&C Red No. 8 

Ext. D&C Red No. U 

Ext. D&C Red No. 15 ■ 

Ext. D&C Violet No. 2 

Ext, D&C Yellow No. 1 

Ext. D&C Yellow No. 5 

Ext. D&C Yellow No. 7 

INGRAIN DYES 

Ingrain blue dyes: 

Ingrain Blue 1 

Ingrain Blue 3 

Ingrain Blue A 

Ingrain green dye: Ingrain Green 2 

^DRDANT DYES 

*Mbrdant yellow dyes: 

*Mordant Yellow 1 

Mordant Yellow 3 

Mordant Yellow 5 

^Mordant Yellow 8 

Mordant Yellow 10 

Mordant Yellow U 

■xMordant Yellow 16 

Mordant Yellow 20 

Mordant Yellow 26 

Mordant Yellow 29 — 

Mordant Yellow 30 

Mordant Yellow 36 

^Mordant orange dyes: 

ifMordant Orange 1 

Mordant Orange A 

^Mordant Orange 6 

Mordant Orange 8 

Mordant Orange 30 

XMordant red dyes : 

Mordant Red 3 

Mordant Red 5 

Mordant Red 6 

^Mordant Red 7 

Mordant Red 9 '■ 



Manufacturers' identification codes 
(according to list in table 22) 



KON, 


TMS. 


KON, 


NAC, TMS 


KON, 


NAC. 


NAC. 




NAC. 




NAC. 




KON, 


NAC. 


SNA. 




NAC. 




KON, 


NAC. 


KON. 




KON, 


NAC. 


SNA. 




KON. 





ICI. 
ICI. 
ICI. 
ICI. 



ATL, G, PDC, TRC. 

ATL, NAC. 

NAC, TRC. 

DUP, G, NAC, VPC. 

DUP. 

NAC, TRC. 

ACY, DUP, NAC. 

NAC. 

NAC, VPC. 

G. 

TRC, VPC. 

PDC. 

ACY, G, PDC, TRC, VPC. 

G, VPC. 

ATL, G, TRC. 

NAC, TRC. 

NAC. 

ACY, NAC. 

NAC. 

G. 

ACY, CMG, G, NAC, TRC, VPC. 

G, MRX, NAC. 



DYES 

TABLE 8B. —Benzenoid dyes for which U.S. production or sales were reported identified by 
manufacturer, 7964— Continued 



109 



I3ye 



Manufacturers' identification codes 
(according to list in table 22) 



MORDANT DYES— Continued 

«}tordant red dyes — Continued 

Mordant Red 11 

Mordant Red 36 

Ifordant Red 59 

Mordant violet dyes: 

Mordant Violet 5 

Mordant Violet 11 

Mordant Violet 26 

^Mordant blue dyes: 

«M3rdant Blue 1 

Mordant Blue 3 

Mordant Blue 7 

Mordant Blue 9 

Mordant Blue 13 

Mordant Blue 19 

Mordant green dyes: 

Mordant Green 9 

Mordant Green 11 

Mordant Green 36 

MDrdant Green 4-7 

*MDrdant brown dyes: 

*Mbrdant Broim 1 

Mordant Brown 12 

Mordant Brown 13 

Mordant Brown 15 

Mordant Brown 17 

Ifordant Brown 18 

Mordant Brown 19 

Mordant Brown 21 

*Mordant Brown 33 

■xMordant Brown 4-0 

Mordant Brown 43 

Mordant Brown 50 

Mordant Brown 63 

Mordant Brown 70 

Mordant Brown 78 

^Mordant black dyes: 

Mordant Black 1 

^ftfordant Black 3 

Mordant Black 5 

Mordant Black 7 

Mordant Black 8 

Mordant Black 9 

«Mordant Black 11 

<<Mordant Black 13 

Mordant Black 16 

»Mbrdant Black 17 

Mordant Black 19 

Mordant Black 26 

^Mordant Black 38 

Other mordant black dyes 

OXIDATION BASES 

Oxidation Base 8 and SA. 

Oxidation Base 21 

Oxidation Base 22 

Oxidation Base 25 

Other oxidation bases 



ACY, NAC. 

TRC. 

TRC. 

NAC. 

G. 

G. 

AAP, DUP, G, NAC, TRC. 

G, NAC. 

TRC. 

G, NAC. 

HSH, NAC. 

CMG. 

NAC. 
ACY. 
PDC. 
NAC. 

cm, DUP, G, NAC, TRC, YAW. 

PDC. 

NAC. 



DUP, NAC. 

G. 

G, VPC. 

DUP, MAC, TRC. 

CMG, DUP, G, NAC, VPC. 

G. 

TRC. 

TRC. 

DUP, PDC. 

CM}. 

G, NAC. 

G, NAC, TRC. 

NAC, TRC. 

G. 

VPC. 

NAC, VPC. 

G, NAC, TRC, VPC. 

G, HSH, NAC, TRC. 

NAC. 

ACY, DUP, G, NAC, TRC. 

PDC. 

TRC. 

CM}, DUP, NAC, TRC, VPC. 

VPC. 



ACY. 
PDC. 
ACY. 
ACY. 
ACY. 



110 



TABLE 8B.- 



SYNTHETIC ORGANIC CHEMICALS, 1964 

■ Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1964 —Continued 



Dye 



SOLVENT DYES 



^Solvent yellow dyes: 

Solvent Yellow 1 

^Solvent Yellow 2 

^Solvent Yellow 3 

Solvent Yellow 8 

Solvent Yellow 13 

♦Solvent Yellow 14- 

Solvent Yellow 16 

Solvent Yellow 19 

Solvent Yellow 29 

Solvent Yellow 33 

Solvent Yellow 34 

Solvent Yellow 40 

Solvent Yellow 4-2 

Solvent Yellow 43 

Solvent Yellow 4^ 

Solvent Yellow 45 

♦Solvent Yellow 47 

Solvent Yellow 53 

Solvent Yellow 56 

Solvent Yellow 66 

Solvent Yellow 71 

Solvent Yellow 72 

Other solvent yellow dyes- 
♦Solvent orange dyes: 

Solvent Orange 2 

♦Solvent Orange 3 

Solvent Orange 5 

♦Solvent Orange 7 

Solvent Orange 20 

Solvent Orange 23 

Solvent Orange 24 

Solvent Orange 25 

Solvent Orange 31 

Solvent Orange 47 

Solvent Orange 48 

Solvent Orange 51 

Other solvent orange dyes- 
♦Solvent red dyes: 

Solvent Red 8 

Solvent Red 22 

♦Solvent Red 24 

♦Solvent Red 26 

Solvent Red 27 

Solvent Red 33 

Solvent Red 34 

Solvent Red 35 

Solvent Red 40 

Solvent Red 41 

♦Solvent Red 49 

Solvent Red 52 — 

Solvent Red 63 

Solvent Red 65 

Solvent Red 68 

Solvent Red 69 

Solvent Red 74 

Solvent Red 76 

Solvent Red 80 

Solvent Red 105 

Solvent Red 108 

Solvent Red 111 

Solvent Red 115 

Other solvent red dyes 



Manufacturers' identification codes 
(according to list in table 22) 



ACY. 

AAP, AIL, DUP, FH, G. 

AAP, DUP, FH, a, NAC, SDH. 

PAT. 

ACY, G, TRG. 

AAP, ACY, ATL, DUP, FH, G, NAC, PAT, SDH. 

PAT. 

G. 

G, NAC. 

ACY, NAC. 

DUP. 

NAC. 

NAC. 

G. 

G, NAC. 

DUP, NAC. 

ACY, DUP, G, NAC. 

NAC. 

ACY, FH. 

NAC. 

ACY. 

ACY. 

ACY, DSC. 

AAP. 

ACY, DSC, G, NAC. 

G, TRC. 

ACY, ATL, FH, G, NAC. 

ACY, G, NAC, TRC. 

NAC. 

DUP. 

ACY, DUP. 

NAC. 

FH. 

ACY. 

ACY. 

DSC, DUP, PAT. 

G. 

G. 

ACY, DUP, G, NAC, PAT, SDH. 

AAP, ACY, FH, NAC. 

NAC. 

DUP. 

DUP. 

G. 

G. 

DSC. 

ACY, DUP, G. 

G, ICI. 

NAC. 

NAC. 

NAC. 

DUP. 

NAC. 

NAC. 

ACY, NAC. 

ACY. 

ACY. 

ACY. 

ACY. 

ACY, DSC, DUP, ICI, PAT. 



DYES 



TABLE 8B. —Bemenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



Pye 



SOLVENT DYES— Continued 

*Solvent violet dyes : 

Solvent Violet 7 

^Solvent Violet 8 — . 

Solvent Violet 9 

Solvent Violet 13 

Solvent Violet U 

Solvent Violet 17 

Other solvent violet dyes 

Solvent blue dyes : 

Solvent Blue 3 

Solvent Blue A 

Solvent Blue 5 

Solvent Blue 6 

Solvent Blue 7 

Solvent Blue 9 

Solvent Blue 11 

Solvent Blue 12 

Solvent Blue 16 

Solvent Blue 30 

Solvent Blue 31 

Solvent Blue 32 

Solvent Blue 33 

Solvent Blue 36 

Solvent Blue 37 

Solvent Blue 38 

Solvent Blue 39 

Solvent Blue .43 

Solvent Blue 58 

Solvent Blue 59 

Solvent Blue 60 

Other solvent blue dyes 

»Solvent green dyes: 

Solvent Green 1 

Solvent Green 2 

*Solvent Green 3 

Solvent Green 10 

Solvent Green 11 

Other solvent green dyes 

»Solvent brown dyes: 

Solvent Brown 11 

Solvent Brown 12 

Solvent Brown 17 

Solvent Brown 19 — 

Solvent Brown 20 

Solvent Brown 21 

Solvent Brown 38 

Other solvent brown dyes 

Solvent black dyes : 

Solvent Black 3- 

Solvent Black 5 

Solvent Black 7 

Solvent Black 12 

Solvent Black 13 

Solvent Black 17 

Solvent Black 19 

Solvent Black 20 

Solvent Black 26 

Other solvent black dyes 



Manufacturers ' identification codes 
(according to list in table 22) 



ACT, 


DSC 


NAC. 


DSC. 






AAP, 


HSH, 


ICI. 


ICI. 






NAC. 






DSC, 


PAT. 




SW. 






DSC, 


DUP, 


SDH. 


DSC. 






DSC. 






ACY, 


NAC. 




G. 






G, ICI. 




DUP, 


NAC. 




NAC. 






NAC. 






NAC. 






AAP. 






G. 






DUP, 


NAC. 




DUP. 






ACY, 


CMl, 


DUP, NAC. 


NAC. 






NAC. 






ACY. 






ACY. 






ACY. 






AAP, 


DSC, 


G, ICI, PAT, SDH 


ACY, 


DSC, 


SDH. 



AAP, ACY, AIL, CIG, G, HSH, ICI, NAC. 

DUP. 

DUP. 

DSC, NAC. 

G. 

ACY, G. 
DUP. 
DUP. 

ACY, DUP. 
NAC. 
ACY. 
ACY, DSC. 

NAC. 

ACY, NAC. 

ACY, FH, NAC. 

NAC. 

NAC. 

DUP. 

G. 

NAC. 

ACY. 

DSC, DUP. 



TABLE 8B. 



SYNTHETIC ORGANIC CHEMICALS, 1964 

-Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



SULFUR DYES 

Sulfur yellow dyes: 

Sulfur Yellow 2 

Leuoo Sulfur Yellow 2 

Sulfur Yellow 4 

Leuco Sulfur Yellow 4 

Leuoo Sulfur Yellow 15 

Other sulfur yellow dyes 

Sulfur red dyes: 

Sulfur Red 1 

Leuco Sulfur Red 1 

Sulfur Red 6 

Sulfur Red 8 

Sulfur blue dyes: 

»Sulfur Blue 7 

*Leuco Sulfur Blue 7 

Leuoo Sulfur Blue 8 

Sulfur Blue 9 

Leuoo Sulfur Blue 9 

»Sulfur Blue 11 

Sulfur Blue 13 

Leuoo Sulfur Blue 13 

Sulfur Blue 15 

Sulfur Blue 16 

Other sulfur blue dyes 

Sulfur green dyes: 

Sulfur Green 1 

Sulfur Green 2 

Leuoo Sulfur Green 2 

Solubilized Sulfur Green 2 

Sulfur Green 3 

Leuoo Sulfur Green 3 

Sulfur Green 8 

Sulfur Green 11 

Sulfiir Green 14 

Leuoo Sulfur Green 16 

Other sulfur green dyes 

Sulfur brown dyes: 

Sulfur Brown 3 

Leuoo Sulfur Brown 3 

Solubilized Sulfur Brown 3 

»Sulfur Brown 10 

■ Leuoo Sulfur Brown 10 

Solubilized Sulfur Brown 10 

Sulfur Brown 14 

Leuoo Sulfur Brown 14 

Sulfur Brown 20 

Sulfur Brown 30 

Sulfur Brown 33 

Leuoo Sulfur Brown 37 

Sulfur Brown 39 

Sulfur Brown 40 

Sulfur Brown 43 

Sulfur Brown 44 

Leuoo Sulfur Brown 44 

Sulfur Brown 45 

Sulfur Brown 50 ■ 

Sulfur Brown 76 

Other sulfur brown dyes 



Manuf aoturers ' identification codes 
(according to list in table 22) 



NAC. 




ACY, NAC. 




AUG, DUP, 


SDC. 


SDG. 




ACY. 




ACY, SDC 




DUP, NAC. 




NAC. 




ACY, DUP, 


NAC. 


DUP. 




ACY, DUP, 


NAC, SDC 


ACY, NAC, 


SDC. 


SDC. 




ACY, NAC. 




SDC. 




DUP, NAC, 


SDC. 


ACY, NAC. 




ACY. 




ACY, DUP, 


NAC. 


ACY, NAC. 




ACY, SDC. 




NAC. 




DUP, NAC, 


SDC. 


SDC. 




SDH. 




NAC, SDC. 




SDC. 




AUG. 




DUP. 




DUP. 




SDC. 




SDC. 




SDC. 




SDC. 




AUG. 




DUP, NAC 


SDC. 


NAC, SDC 




AUG. 




ACY, AUG 




ACY. 




DUP. 




ACY. 




ACY. 




SDC. 




DUP, SDC 




DUP. 




NAC. 




NAC. 




NAC. 




NAC. 




NAC. 




ACY. 




ACY, NAC 


, SDC. 



DYES 



113 



TABLE 8B.- 



-Bemenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



I^e 



SULFUR DYES— Continued 

Sulfur black dyes: 

»Sulfur Black 1 

Leuco Sulfur Black 1 

Sulfur Black 2 

»Leuco Sulfur Black 2 

Sulfur Black 6 

Leuco Sulfur Black 6 

Sulfur Black 10 

Leuco Sulfur Black 10 

Sulfur Black 11 

Leuco Sulfur Black 11 

Other sulfur black dyes 

VAT DYES 

*Vat yellow dyes: 

Vat Yellow 1, 12-1/2?J 

»Vat Yellow 2, 8-1/2^^ 

Solubllized Vat Yellow 2, 2ii 

Vat Yellow 3, 12-1/2^6 

»Vat Yellow 4, 12-l/25t 

Solubllized Vat Yellow 4-, 37-1/25^ 

Vat Yellow 10, lO^fr- 

Vat Yellow 13, t-l/Z'i, 

Vat Yellow U, 12-'L/2i 

Vat Yellow 15, 11-1/2^^ 

Vat Yellow 16, 16-2/35^ 

Vat Yellow 20 

Vat Yellow 21, 9-1/2$ 

Vat Yellow 22, 1.0$ 

Vat Yellow 27 

Vat Yellow 28, 10$ 

Vat Yellow 33 

Vat Yellow 34, 8-1/25^ 

Vat Yellow 41, 9$ 

Other vat yellow dyes 

*Vat orange dyes: 

»Vat Orange 1, 205t 

»Solubilized Vat Orange 1, 26$ 

»Vat Orange 2, 125^ 

Vat Orange 3, 13-1/2$ 

»Vat Orange 4, 6$ 

*Vat Orange 5, lOjt 

»Solubilized Vat Orange 5, 305^ 

»Vat Orange 7, lli^ 

»Vat Orange 9, 12?^ 

Vat Orange 11, 6$ 

»Vat Orange 15, IO56 

Vat Orange 23, 17-l/25( 

Vat Orange 24 

Other vat orange dyes 

*Vat red dyes: 

»Vat Red 1, 13$ 

»Solubilized Vat Red 1, 375S 

Vat Red 10, I856 

Solubllized Vat Red 10, 315t 

Vat Red 12, 8-l/25t 

»Vat Red 13, lljt 



Manufacturers' identification codes 
(according to list in table 22) 



DUP, 


NAC, 


SDC 


ACY, 


NAC, 


SDC 


ACY, 


DUP, 


NAC 


ACY, 


NAC, 


SDC 


G. 






NAC. 






ACY, 


DUP. 




ACY, 


NAC. 




a, SDC. 




SDC. 






SDC. 







NAC. 

AAP, ATL, DUP, G, ICI, NAC, TRC, VPC. 

G, ICI. 

DUP. 

AAP, ACY, AIL, CMG, G, HST, ICI, TRC, VPC. 

G, HST, ICI. 

G. 

ICI. 

TRC. 

ACY. 

DUP. 

G. 

ATL, DUP. 

DUP, G. 

VPC. 

NAC. 

ICI, TRC. 

DUP. 

ACY. 

MAY, NAC, VPC. 

CMG, G, HST, ICI, NAC, TRC, VPC. 

G, HST, ICI. 

AAP, ACY, CMG, DUP, G, ICI, NAC, TRC. 

CMG, DUP, G. 

ACY, CMG, DUP, NAC. 

AAP, ACY, DUP, HST. 

G, HST, ICI. 

G, HST, TRC. 

AAP, ACY, CMG, DUP, G, ICI, NAC, TRC. 

DUP, NAC. 

AAP, ACY, G, ICI, NAC, TRC, VPC. 

ACY, DUP. 

DUP. 

G, SDC. 

AAP, ACY, DUP, HST. 

G, HST, ICI. 

G, NAC, TRC. 

G. 

DUP. 

DUP, G, NAC, TRC. 



114 SYNTHETIC ORGANIC CHEMICALS. 1964 

TABLE 8B. -Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



VAT DYES — Continued 



2656— 



*Vat red dyes — Continued 

"Vat Red U, 105t 

*Vat Red 15, lO^i 

Vat Red 16, 115^ 

Vat Red 17, 105^ 

Vat Red 23 

Vat Red 29, I856 

»Vat Red 32, 20^ 

Vat Red 35, I2-I/25S 

Vat Red 44, 175t 

Vat Red 52, IO56 

Vat Red 53, 12^ 

Vat Red 56 

Vat Red 62 

Other vat red dyes 

*Vat violet dyes: 

»Vat Violet 1, 115^- 

Solubilized Vat Violet 

*Vat Violet 2, 20^ 

Vat Violet 3, XSfl, 

Solubilized Vat Violet 3, 43^ 

*Vat Violet 9, 12^— 

Vat Violet 12, IO5S 

*Vat Violet 13, 6-1/4^6 

Vat Violet 14, 12-1/2^6 

Vat Violet 17, I2-I/256 

Other vat violet dyes 

Wat "blue dyes: 

Vat Blue 1, 20?^ 

Solubilized Vat Blue 1, 25?^ 

Vat Blue 3, I656 

*Vat Blue 4, lOjt 

Vat Blue 5, 16i 

Solubilized Vat Blue 5, 3856 

Wat Blue 6, 8-1/35^ 

*Solubilized Vat Blue 6, 17-1/2^ 

Vat Blue 7, 12-l/2^i ■ 

Solubilized Vat Blue 9, 35^ 

Vat Blue 12, 6-I/256 

Vat Blue 14, 8-1/35^ - 

Vat Blue 16, 16^^ 

*Vat Blue 18, 135^ 

*Vat Blue 20, 14^6 

Vat Blue 29 - 

Vat Blue 39, 12^6 

Vat Blue 43 

Vat Blue 53 

Vat Blue 60 

Vat Blue 61, I656 

Other vat blue dyes 

Wat green dyes: 

Wat Green 1, 65S 

Solubilized Vat Green 1, 12-1/2^- 

Wat Green 3, lOjt 

»Solubilized Vat Green 3, 2656 

Wat Green 8, 8-l/2';t 

Wat Green 9, I2-I/256 

Vat Green 15, 175^— 



Manufacturers' identification codes 
(according to list in table 22) 



G, HST. 

G, HST, TRC. 

DUP. 

G. 

DUP. 

G, NAG. 

DUP, G, MAC. 

NAC, TRC. 

TRC. 

DUP. 

DUP. 

ACY. 

DUP. 

DUP, G, TRC, VPC. 

ACY, DUP, G, ICI, MAY, NAC, TRC. 

G, ICI. 

ACY, G, HST, NAC. 

G, HST, NAC. 

G. 

DUP, G, ICI, MAY, NAC. 

DUP. 

CMG, DUP, G, ICI, NAC, TRC. 

DUP, NAC. 

DUP, G, NAC. 

NAC. 

DUP, NAC. 

G. 

HST. 

ACY, DUP, G. 

ATL, DUP, HST, NAC, VPC. 

G, HST. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC, VPC. 

G, HST, ICI. 

NAC. 

G. 

DUP. 

DUP, G, NAC, TRC. 

ACY, DUP, NAC. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC. 

AAP, ACY, AIL, DUP, G, ICI, MAY, NAC, TRC. 

G. 

G. 

SDC. 

G. 

DUP. 

DUP. 

G, SDC, X. 

AAP, ACY, ATL, DUP, G, ICI, MAY, NAC, TRC. 

G, HST, ICI. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC. 

G, HST, ICI. 

DUP, G, ICI, NAC. 

ACY, ATL, DUP, G, MAY, NAC, SDC, TRC. 

NAC. 



DYES 



115 



TABLE 8B. — Bemenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i564— Continued 



Dye 



VAT DYES—Continued 

*Vat green dyes — Continued 

Vat Green 18, B$ 

Vat Green 20, e^ 

Other vat green dyes 

*Vat bromn dyes; 

*Vat Brown 1, 11$ 

Solubllized Vat Brown 1, 17i6 

»Vat Brown 3, 115t 

«Vat Brown 5, 13^6 

Vat Brown 6, 17-l/25t 

Vat Brown 11, 12ifr 

Vat Brown 12, 12-l/2?6 

Vat Brown 13, 1756 

Vat Brown 14, 125^ 

Vat Brown 20, IO-I/256 

Vat Brown 25, II-I/256 

Vat Brown 29, 13;^- 

Vat Brown 31, 28$ 

Vat Brown 38, 20i6- 

Vat Brown 40, I456 

Vat Brown 57 

Other vat brown dyes 

Wat black dyes: 

Solubllized Vat Black 1, 27-1/2!^ 

*Vat Black 9, I656 — ■ 

Vat Black 11, 17-l/25t 

Vat Black 13, XU$ ■ 

Vat Black' 14, ll-l/2i6 

Vat Black 15 

Vat Black 18, 15-l/2;6- 

Vat Black 21, 18-l/25t 

Vat Black 22, 195t 

*Vat Black 25, 12-1/25^ 

Wat Black 27, 12-1/2;^- 

Vat Black 34, 16$ 

Vat Black 36- — 

Vat Black 38 

Vat Black 52 — — 

Other vat black dyes 

All other dyes 



Manufacturers' identification codes 
(according to list in table 22) 



DUP. 
DUP. 
SDC. 

ACY, DUP, G, ICI, MAY, NAC, TRC. 

G, ICI. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC, VPC. 

AAP, ACY, G, HST, NAC, VPC. 

TRC. 

MAY, TRC. 

DUP, NAC. 

MAY. 

HST. 

DUP, G, NAC. 

G. 

ACY. 

AAP. 

ICI. 

DUP. 

TRC. 

DUP, G, NAC, SDC, VPC. 

G, HST, ICI. 

G, NAC, TRC. 

ACY. 

DUP, NAC. 

DUP. 

AAP. 

G, NAC. 

ACY. 

ACY, TRC. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC. 

AAP, ACY, CMG, DUP, G, ICI, MAY, NAC, TRC. 

ICI. 

DUP. 

G. 

ACY. 

DUP, G, NAC, SDC, TRC. 

ACY, FH, PAT, VPC. 



1)6 



SYNTHETIC ORGANIC CHEMICALS, 1964 



Pigments 

TABLE IIB. — Benzenoid pigments for which U.S. production or sales were reported, identified 

by manufacturer, 1964 

[Benzenoid pigments for which separate statistics are given in table llA are marked below with an asterisk (»); 
products not so marked do not appear in table llA because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that 
the manufacturer did not consent to his identification with the designated product] 



Pigment 



Manufacturers ' identification codes 
(according to list in table 22) 



TONERS 

*Yellow toners: 
»Hansa yellows: 

♦Pigment Yellow 1, C.I. 11 680 

»Pigment Yellow 3, C.I. 11 710 — 

Pigment Yellow 4, C.I. 11 665 

Pigment Yellow 5, C.I. 11 660 

Pigment Yellow 6, C.I. 11 670 

Pigment Yellow 9, C.I. 11 720 

Pigment Yellow 49, C.I. 11 765 

Pigment Yellow 60 

Pigment Yellow 73 

Pigment Yellow 74 

All other Hansa yellows 

♦Benzidine yellows: 

♦Pigment Yellow 12, C.I. 21 090 

♦Pigment Yellow 13, C.I. 21 100 

♦Pigment Yellow 14, C.I. 21 095 

♦Pigment Yellow 17, C.I. 21 105 

Pigment Yellow 65, C.I. 11 740 

Pigment Yellow 83 

All other benzidine yellows 

Pigment Yellow 18, C.I. 49 005 

(Basic Yellow 2), C.I. 41 000, fugitive 

(Vat Yellow 1), C.I. 70 600 

(Vat Yellow 20), C.I. 68 420 

All other 

♦Orange toners: 

Pigment Orange 1, C.I. 11 725 

♦Pigment Orange 2, C.I. 12 060 

♦Pigment Orange 5, C.I. 12 075 

Pigment Orange 9 

♦Pigment Orange 13, C.I. 21 110 

Pigment Orange 15, C.I. 21 130 

♦Pigment Orange 16, C.I. 21 160 

Pigment Orange 30 

(Vat Orange 3), C.I. 59 300 -- 

(Vat Orange 4), C.I. 59 710 

(Vat Orange 7), C.I. 71 105 

(Vat Orange 15), C.I. 69 025—- - — 

All other 

♦Red toners: 
♦Naphthol reds: 

♦Pigment Red 2, C.I. 12 310 

♦Pigment Red 5, C.I. 12 490 

Pigment Red 7, C.I. 12 420 

Pigment Red 9, C.I. 12 460 

Pigment Red 10, C.I. 12 440 

♦Pigment Red 13, C.I. 12 395 



ACY, AMS, CIK, DUP, FCL, G, HAR, HSC, HSH, ICI, IMP, 

KON, PPG, S, SDH, SNA, SW, WDC. 
HAR, HSC, HSH, HST, IMP, KCW, KON, S, SW, WDC. 
HAR, HSH, SNA. 
HSH, IMP. 
CIK, IMP. 
SNA. 
ICI. 
SW. 

HAR, SW. 
DUP, SW. 
DUP, HSC, IMP, KCW, SDH, SNA, WDC. 

ACY, AMS, DUP, FCL, G, HAR, HSC, HSH, HST, ICC, IMP, 

KON, LVY, MRX, S, SDH, SNA, SW, WDC. 
FCL, G, HAR, HST, ICC, IMP, ROM, SNA, SW. 
ACY, AMS, BUC, CPC, DUP, FCL, G, HAR, HSC, HSH, HST, 

ICC, IMP, KON, MRX, ROM, S, SDH, SNA, SW, x. 
ACY, AMS, DUP, HST, ICC, IMP, SDH, SNA, SW. 
SW. 
HAR. 

HSH, HST, ICC, IMP, ROM, S, SW. 
IMP. 
MRX, S. 
HAR, TRC. 
HAR. 
ACY, HSH, ICC, S, SW. 

HAR, KCW, SNA. 

FCL, HSC, IMP, SDH, SW. 

ACY, HSC, IMP, SNA, SW. 

DUP. 

ACY, AMS, BUC, G, HAR, ICC, ICI, IMP, KON, S, SNA, SW. 

G, HAR. 

BUC, DUP, FCL, G, HAR, HST, ICC, IMP, ROM, SDH, SNA, 

SW. 
SW. 

HAR, TRC. 
HAR. 
G, HAR. 
HAR. 
ICC, KON, ROM, SDH, SNA, SW. 



EAK, G, HAR, HSC, IMP, KCW, KON, MRX, SDH, SW. 

DUP, G, HAR, HST, ICC, ICI, IMP, ROM, S, SDH, SNA, SW. 

ICI, S, 

IMP. 

KCW. 

HAR, IMP, KCW. 



See note at end of table for definition of abbreviations. 



PIGMENTS 



117 



TABLE IIB. —Bemenoid pigments for which U.S. production or sales were reported, identified 
by manufacturer, iS64- -Continued 



Pigment 



TONERS— Continued 

»Red toners — Continued 
»Naphthol reds — Continued 

Pigment Red li, C.I. 12 380 

Pigment Red 15, C.I. 12 ^65 

»Pigment Red 17, C.I. 12 390 

^Pigment Red 18, C.I. 12 350 

Pigment Red 19, C.I. 12 400 

»Pigment Red 22, C.I. 12 315 

^Pigment Red 23, C.I. 12 355 

Pigment Red 31, C.I. 12 360 

All other naphthol reds 

*Pigment Red 1, C.I. 12 070, dark 

^Pigment Red 1, C.I. 12 070, light 

^Pigment Red 3, C.I. 12 120 

^Pigment Red 4, C.I. 12 085 

Pigment Red 5 

Pigment Red 6, C.I. 12 090 

»Pigment Red 38, C.I. 21 120 

Pigment Red 41, C.I. 21 200 

*Pigment Red 48, C.I. 15 865 

Pigment Red 49, C.I. 15 630: 
*Barium toner 

*Caloium toner 

*Sodium toner 

♦Pigment Red 52, C.I. 15 860 

♦Pigment Red 53, C.I. 15 585, barium toner- 
Pigment Red 54, C.I. 14 830, calcixun toner- 
Pigment Red 55, C.I. 15 820 

♦Pigment Red 57, C.I. 15 850, calcium toner- 
Pigment Red 58, C.I. 15 825 

♦Pigment Red 63, C.I. 15 880 

Pigment Red 64, C.I. 15 800 

Pigment Red 77, C.I. 15 826 

Pigment Red 78 

Pigment Red 81, C.I. 45 160, fugitive 

♦Pigment Red 81, C.I. 45 160, PMA. 

♦Pigment Red 81, C.I. 45 160, PTA 

Pigment Red 87, C.I. 73 310 

Pigment Red 88 

♦Pigment Red 90, C.I. 45 380 

Pigment Red 117, C.I. 15 603 

Pigment Red 122 



Manufacturers' identification codes 
(according to list in table 22) 



DUP. 

DUP. 

ACY, BLN, FCL, ICC, IMP, S, SNA, SW. 

HAR, HSH, IMP, SW. 

HAR. 

ACY, DUP, FCL, HAR, IMP, MRX, SNA, SW. 

ACY, BUG, DUP, FCL, HAR, HSC, ICC, IMP, S, SDH, SNA, 

SW. 
SNA, SW. 

BUC, ICC, IMP, KCW, ROM, S, SDH, SW. 
ACY, AMS, APC, FCL, HAR, HSC, HSH, IMP, KON, LVY, 

PPG, SNA, SW, WDC. 
ACY, APC, CIK, EAK, FCL, HSC, HSH, IMP, KON, PPG, SDH, 

SW. 
ACY, APC, BLN, CIK, DUP, EAK, FCL, HAR, HSC, HSH, 

IMP, KCW, KON, PPG, SDH, SNA, SW, UHL, WDC. 
ACY, AMS, FCL, G, HSC, IMP, KON, MRX, SDH, SNA, SW, 

WDC. 
IMP. 

DUP, HSC, SW. 

DUP, G, HAR, ICC, SNA, SW. 
G, HAR. 
ACY, AMS, BLN, DUP, FCL, G, HAR, HSC, HSH, IMP, KON, 

LVY, MRX, S, SNA, SW, WDC. 

ACY, AMS, CIK, FCL, HSC, IMP, LVY, SDH, SNA, SW, UHL, 

WDC. 
ACY, AMS, EAK, FCL, HSC, IMP, LVY, PPG, SDH, SNA, SW. 
ACY, AMS, CIK, FCL, HSC, SDH, SW. 
AMS, FCL, HSC, HSH, IMP, SNA, SW. 
ACY, ADC, AMS, CIK, FCL, HSC, IMP, KON, LVY, MRX, 

SDH, SNA, SW, WDC. 
IMP, MRX, SDH. 
DUP, HAR. 
ADC, AMS, BLN, CIK, DUP, FCL, HAR, HSC, HSH, IMP, 

KON, LVY, SDH, SNA, SW, WDC. 
DUP, G, IMP. 

FCL, HAR, HSH, IMP, SNA, SW. 
HAH. 
SW. 
DUP. 

BLN, KCW, SNA. 
BLN, CPC, DUP, FCL, G, IMP, KON, LVR, LVY, MGR, MRX, 

NYC, SNA. 
ACY, AMS, BLN, DUP, FCL, G, HSC, IMP, KCW, KON, MGR, 

MRX, S, SDH, SNA. 
HAR. 
HAR. 
ACY, AlB, FCL, ICC, IMP, LVR, LVY, NYC, SDH, SNA, 

WDC. 
SW. 
HAR. 



See note at end of table for definition of abbreviations. 



118 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE IIB.—Benzenoid pigments for which U.S. production or sales were reported, identified 
by manufacturer, 1964 — Continued 



Pigment 



TONERS— Continued 

»Red toners — Continued 

Pigment Red 123 

(Vat Red 10), C.I. 67 000 

(Vat Red 23) 

(Vat Red 29), C.I. 71 140 

All other 

*Violet toners: 

Pigment Violet 1, C.I. 45 170, fugitive 

*Pigment Violet 1, C.I. 45 170, PMA. 

«Pigment Violet 1, C.I. 45 170, PTA 

^Pigment Violet 3, C.I. 42 535, fugitive 

^Pigment Violet 3, C.I. 42 535, PMA 

^Pigment Violet 3, C.I. 42 535, PTA 

Pigment Violet 19 

Pigment Violet 23 

(Vat Violet 1), C.I. 60 010 

(Vat Violet 2), C.I. 73 385- 

(Vat Violet 3), C.I. 73 395 

(Vat Violet 23) 

All other 

*Blue toners: 

♦Pigment Blue 1, C.I. 42 595, PMA 

♦Pigment Blue 1, C.I. 42 595, PTA 

Pigment Blue 2, C.I. 44 045, fugitive 

Pigment Blue 2, C.I. 44 045, PMA 

Pigment Blue 2, C.I. 44 045, PTA 

Pigment Blue 3, C.I. 42 140, PMA 

Pigment Blue 3, C.I. 42 140, PTA 

Pigment Blue 5, C.I. 42 600 

♦Pigment Blue 9, C.I. 42 025, PMA 

♦Pigment Blue 9, C.I. 42 025, PTA 

Pigment Blue 10, C.I. 44 040, PMA 

Pigment Blue 10, C.I. 44 040, PTA— 

♦Pigment Blue 14, C.I. 42 600, PMA 

Pigment Blue U, C.I. 42 600, PTA 

♦Pigment Blue 15, C.I. 74 160, alpha form 

♦Pigment Blue 15, C.I. 74 160, beta form 

♦Pigment Blue 19, C.I. 42 750A 

Pigment Blue 22, C.I. 69 810 

♦Pigment Blue 25, C.I. 21 180 - 

(Basic Blue 7), C.I. 42 595, PTA 

(Vat Blue 4), C.I. 69 800 

(Vat Blue 6), C.I. 69 825 

(Vat Blue 14), C.I. 69 810 

All other 

♦Green toners: 

♦Pigment Green 1, C.I. 42 040, PMA 

♦Pigment Green 1, C.I. 42 040, PTA 

♦Pigment Green 2, C.I. 42 040 and 49 005, PMA- 
♦Pigment Green 2, C.I. 42 040 and 49 005, PTA- 

Pigment Green 4, C.I. 42 000, fugitive 

Pigment Green 4, C.I. 42 000, PMA 

♦Pigment Green 4, C.I. 42 000, PTA 

♦Pigment Green 7, C.I. 74 260 



Manufacturers ' identification codes 
(according to list in table 22) 



HAR. 
HAR. 
HAR. 
HAR. 
DUP, G, HAM, HSC, SW, TRC, x. 

BLN, UHL. 

BLN, G, IMP, LVR, MRX. 

ACY, AMS, BLN, DUP, FCL, G, HSC, IMP, KON, MRX, S, 

SNA. 
ACY, ADC, AMS, BLN, HSC, IMP, LVY, MGR, SDH, UHL. 
ADC, AMS, BLN, CIK, DUP, EAK, G, HSC, IMP, KON, LVE, 

LVY, MGR, MRX, NYC, PPG, SDH, SNA, SW, UHL. 
ACY, AMS, G, IMP, KON, MRX, SNA, SW. 
HAR. 
G. 

DUP. 
HAR. 
HAR. 
TRC. 
ACY, HST, ICC, ROM. 

ADC, BLN, DUP, EAK, FCL, G, HSC, IMP, KON, LVR, LVY, 

MGR, MRX, NYC, SDH, SNA, SW, UHL. 
AMS, G, HAM, HAR, IMP, MGR, SNA, SW, UHL. 
BLN. 

CIK, G, LVR. 
G, HAM, WS.. 
MGR. 
MGR. 
G. 

LVR, MRX, NYC, UHL. 
BLN, G, IMP, M3R, MRX, SDH. 
IMP, SDH. 
IMP. 

DUP, G, IMP, NYC. 
DUP, G, NYC. 
ACY, DUP, G, HAR, HSC, ICC, ICI, IMP, SNA, SW, TMS, 

TRC. 
ACY, DUP, FCL, HSC, IMP, KON, LVY, SNA, SUC, SW, TMS, 

TRC. 
ACY, AMS, HSC, NYC, SW. 
DUP, IMP. 
DUP, G, HAR, ICC. 
DUP. 
G. 

ICI, TRC. 
HAR, TRC. 
ICC, IMP, M5R, S, SDH. 

BLN, G, IMP, MGR, MRX, SNA, UHL. 

BLN, IMP, MIR, S, SDH. 

ADC, G, IMP, LVY, MiR, MRX, S, SDH, UHL. 

ACY, AJ/B, BLN, DUP, IMP, KON, LVY, MjR, MRX, S, SDH, 

UHL. 
BLN, G. 
ADC, BLN. 

ACY, AMS, HAM, MGR. 
ACY, DUP, FCL, G, HAR, HSC, IMP, SNA, SW, TMS, TRC. 



See note at end of table for definition of abbreviations. 



PIGMENTS 



119 



TABLE IIB. 



-Benzenotd pigments for which U.S. production or sales were reported, identified by 
manufacturer, i 564- -Continued 



Pigment 



TONERS— Continued 

«<}reen toners — Continued 

♦Pigment Green 8, C.I. 10 006 

Pigment Green 10, C.I. 12 775 

Pigment Green 36 

Pigment Green 38 

All other 

*Brown toners: 

Pigment Brown 1, C.I. 12 4-80 

Pigment Brown 2, C.I. 12 071 

Pigment Brown 3, C.I. 21 010, PMA. 

♦Pigment Brown 5, C.I. 15 800 

(Vat Brown 3), C.I. 69 015 

All other 

*Blaok toners: 

Pigment Black 1 

All other 



Manufacturers' identification codes 
(according to list in table 22) 



Yellow lakes: 

(Acid Yellow 1), C.I. 10 316 

(Acid Yellow 3), C.I. 4-7 005 

(Acid Yellow 23), C.I. 19 14-0 

All other 

Orange lakes: 

Pigment Orange 17, C.I. 15 510 

All other 

♦Red lakes: 

♦Pigment Red 60, C.I. 16 105 

♦Pigment Red 83, C.I. 58 000 

(Acid Red 17), C.I. 16 180 

(Acid Red 25), C.I. 16 050 

♦(Acid Red 26), C.I. 16 150 

(Acid Red 27} 

(Natural Red 4), C.I. 75 470 

(Natural Red 24), C.I. 75 280 

All other 

♦Violet lakes: 

♦Pigment Violet 5, C.I. 58 055 

Pigment Violet 20, C.I. 58 225 

(Acid Violet 17), C.I. 42 650 

All other 

♦Blue lakes: 

Pigment Blue 17, C.I. 74 180 

♦Pigment Blue 24, C.I. 42 090 

(Acid Blue 93), C.I. 42 780 

(Acid Blue 104), C.I. 42 735 

Green lakes: (Acid Green 3), C.I. 42 085- 

Brown lakes -r 

Black lakes: 

♦(Natural Black 3), C.I, 75 291 

All other 



DUP, G, HSH, KCW, LVY, SW. 

DUP. 

G. 

HAR. 

ACY. 

ICI. 

SDH. 

BLN, KCW. 

BUC, HAR, ROM, SNA. 

G, HAR. 

ICC, SDH, SW. 

SNA. 

BLN, DUP, G, MGR, SNA, SW, UHL. 



IMP. 
IMP. 
KON, 
IMP. 

CIK, 

HAM. 

BLN, 
IMP, 
IMP, 
KON. 
CPC, 
KON. 
KON. 
IMP. 
APC, 

BLN, 
SW. 
BLN. 
HAM, 

BLN, 
ADC, 
LVR. 
CPC, 
BLN, 
HAM, 

CPC, 
HAM. 



Mffi, MRX. 

CPC, IMP, KCW, MGR. 



DUP, HSH, KON, MRX, SNA, SW. 
KON, MRX, SW, UHL. 
KCW, WDC. 

EAK, HAM, IMP, KCW, UHL. 



G, HAM, IMP. 
DUP, HAR, IMP. 



CPC. 

AMS, BLN, CIK, ICC, KON, LVY, MGR, SDH. 

KCW. 
CPC. 
KON. 



KON, NYC. 



of^the'co'w Ind« ^^'°"'" ^""^"^ numbers shown in this report are the identifying codes given in the second edition 

When the name of a color is enclosed in parentheses, it indicates that this name is that of the dye from which the 
pigment can be made and that no name for the pigment Itself is given in the Colour Index 

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic) 



120 



SYNTHETIC ORGANIC CHEMICALS, 1964 



Medicinal Chemicals 

TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1964 



[Medicinal chemicals for which separate statistics are given in table 13A in pt. II are marked below with an asterisk 
(*); medicinal chemicals not so marked do not appear in table 13A because the reported data are accepted in con- 
fidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x 
signifies that the manufacturer did not consent to his identification with the designated product ] 



Manufacturers' identification codes 
(according to list in table 22) 



MEDICINAL CHIMICALS, ANTIBIOTICS 

^Antibiotics for human or veterinary use : 

Amphotericin B 

■^Bacitracin 

Cephalothin, sodium 

Chloramphenicol 

Chlortetracycline 

Cycloserine 

Dactinomycin 

Demethylchlortetracycline 

^Dihydrostreptomycin 

Erythromycin 

Fumagillin 

Gentamicin 

Gramicidin 

Kanamycin 

Lincoraycin 

*Neomycin 

Novobiocin 

Nystatin 

Oleandomycin 

Oxytetracycline 

Paromomycin 

■^Penicillins : 

Ampicillin 

Cloxacillin, sodium 

Methioillin, sodium 

Nafcillin, sodium 

Oxacillin, sodium 

♦Penicillin G, potassium 

♦Penicillin G, procaine 

♦Penicillin G, other: 

Penicillin G, benzathine 

Penicillin G, sodium 

Penicillin 0, chloroprocaine 

Penicillin 0, sodium 

Penicillin V 

Penicillin V, benzathine 

Penicillin V, hydrabamine 

Penicillin V, potassium 

♦Phenethicillin and potassium salt: 

Phenethicillin 

Phenethicillin, potassium 

Polymyicin B 

Ristocetin 

Streptomycin 

♦Tetracycline 

Thiostrepton 

Triacetyloleandomycin 

Tyrothricin 

Vancomycin 

Viomycin 

♦Antibiotics for animal feed supplements, food preserva- 
tion, and crop spraying; 

♦Bacitracin 

Chlortetracycline 

ffygromycin B 

Oxytetracycline 

♦Penicillin G, procaine 

Streptomycin 

I^losin 



PFZ, MP, X. 



CMS, PFZ. 
LIL. 



CMS, PEN, PFZ, UPJ. 
UPJ. 



CMS. 

CCM, 

LIL. 

PD. 

ACY. 

CCM. 

MRK. 

ACY. 

MRK, 

ABB, 

ABB. 

SCH. 

BAX, 

BRS. 

X. 

ACY, 
MRK, 
QMS. 
PFZ. 
PFZ. 
MRK. 



BRS. 

BRS. 

BRS. 

WYT. 

BRS. 

LIL, MRK, CMS, PFZ, WYT. 

ABB, LIL, MRK, CMS, PFZ, WYT. 

PFZ, WYT. 

MRK, OMS, PFZ. 

UPJ. 

UPJ. 

LIL. 

WYT. 

ABB. 

ABB, LIL. 

CMS, PFZ. 

BRS, WYT. 

PFZ. 

ABB. 

LIL, MRK, CMS, PFZ. 

ACY, BRS, PFZ, RLS. 

CMS. 

PFZ. 

BAX, PEN. 

LIL. 

PFZ. 



COM, DLI, GPR, PMP, x. 

ACY. 

LIL. 

PFZ. 

LIL, MRK, am, PFZ, WYT. 

MRK, PFZ. 

LIL. 



MEDICINAL CHEMICALS 



121 



TABLE 13B. 



• Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 964 --Continued 



MEDICINAL CHEMICALS, BENZENOID 

^Alkaloids, except those affecting the autonomic or central 
nervous system: 
Berberine hydrochloride 

Ergonovine maleate 

Hydrastine 

Ifydrastine hydrochloride 

Lobeline sulfate 

Papaverine hydrochloride, synthetic 

Quinidine gluconate 

Qainidine sulfate 

Eauwolfia serpentina fraction (Alseroxylon) 

Resoinnamine 

Reserpine 

Theobromine sodium salicylate 

Vinblastine sulfate 

^Antihistamines : 
*Antinauseants : 

N-Benzhydryl-N-'--methylpiperazine (Cyclizine) base and 
hydrochloride. 

2-(Benzhydryloxy)-N, N-dimethylethylamine 8-chloro- 
theophyllinate (Dlmenhydrinate). 

l-(p-Chlorobenzhydryl)-<i-(3-methylbenzyl)piperazine 
(Meclizine) dihydrochloride . 

4-(2-Dimethylamlnoethoxy)-N-(3,4,5-trimethoxybenzoyl)- 
benzylamine (Trimethobenzamide) hydrochloride. 
2-(Benzhydryloxy)-N, N-dimethylethylamine (Diphenhydra- 
mine) hydrochloride. 
2 -[ Benzyl ( 2-dimethylaminoettiyl ) amino] pyridine ( Tri - 

pelenamine ) . 
2-[Benzyl(2-dimethylaminoethyl)amino]pyridine (Tri- 

pelenamine) citrate. 
2-[ Benzyl( 2-dimethylaminoethyl )amino]pyridine ( Tri- 

pelenamine) hydrochloride. 
2-[ p-Bromo-a- ( 2-dimethylaminoethyl )benzyl] pyridine 

(Brompheniramine) maleate. 
d-2-[ p-Bromo-a-(2-dimethylaminoethyl )benzyl] pyridine 

( Dexbrompheniramine ) maleate . 

Bromodiphenhydramine hydrochloride 

l-(4-Chlorobenzhydryl)^-methylpiperazine ( Chlor- 

cyclizine ) hydrochloride . 
2-[p-Chloro-a-(2-dimethylaminoethoxy)benzyl] pyridine 

( Carbinoxamine ) . 
l-2-[p -Chloro-a - ( 2 -dimethylaminoethoxy )benzyl] pyridine 

(Rotoxamine). 
*2-[p-Chloro-a-(2-dlmethylaminoethyl)benzyl] pyridine 

( Chlorpheniramine ) maleate . 
d-2-[p-Chloro-a-( 2-dimethylaminoethyl )benzyl] pyridine 

( Dexchlorpheniramine ) maleate . 
l-(p-Chlorophenyl)-2-phenyl-4-pyrrolidyl-l-butene 

( lyrrobutamine ) diphosphate and hydrochloride. 
4-(5H-Dibenzo [a,d]eyclohepten-5-ylidene)-l-methyl- 

piperidine ( Cyproheptadine } . 
2-[a -(2-Dimethylaminoethoxy)-a-methylbenzyl] pyridine 

(Doxylamine) succinate. 



Manufacturers' identification codes 
(according to list in table 22) 



PEN. 
LIL. 
PEN. 
PEN. 
ABB. 
LIL. 
HEX. 
HEX. 
RIK. 
CEP. 
PEN. 
CLC. 
LIL. 



PD. 

ABB, BUR. 



HEX, LEM, PYL, SCH, SK, x. 



SCH. 



122 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 13B. 



-Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



MEDICINAL CHEJAICALS, BENZENOID— Continued 

»Antiliistamines — Continued 

*2-[a-(2-Diiiiethylaminoethyl)"benzyl] pyridine ( Phenir amine ) 
maleate. 
2-[l-[2-(2-Dimethylaiiiinoethyl)inden-3-yl]ethyl] pyridine 
(Dimethindene) maleate. 
*2 - [ ( 2 -Dime thy laminoe thyl ) ( p -me thoxybenzyl ) amino J pyr id ine 
(lyrilamine) maleate. 
2-[ ( 2-Dimethylaminoethyl ) (p-me thoxybenzyl ) amino] pyr- 

imidine ( Thonzylamine ) l^rdroohloride . 
2 - [ ( 2 -Dime thy laminoe thyl ) -2 -thenylamino] pyridine 

(Methapyrilene) fumarate. 
2-L (2-Dimethylaminoethyl )-2-thenylamino] pyridine 

(Methapyrilene) hydrochloride. 
2-[ (2-Dimethylaminoethyl) -2-thenylamino] pyridine 

(Methapyrilene) o-(p-hydroxybenzoyl)'benzoate. 
2 - [ (2-Dimethylaminoethyl ) -3 -thenylamino] pyridine 

( Thenyldi amine ) hydrochloride . 
N,N-Dimethyl-2-[(a-phenyl-o-tolyl)oxy]ethylamine (Phenyl- 

toloxamine) dihydrogen citrate. 
2,3,4,9-Tetrahydro-2-methyl-9-phenyl-lH-indeno[2,l-o]- 
pyridine ( Phenindamine ) hydrogen tartrate. 
*Anti-infective agents : 

*Antimony, arsenic, bismuth, and mercury compounds: 
Antimony, arsenic, and bismuth compounds: 

N-Acetyl-4-hydroxy-m-arsanilic acid (Acetarsone) 

Arsanilic acid 

Arsanilic acid, sodium salt 

Bismuth subsalicylate 

N-Carbamoylarsanilic acid (Carbarsone) 

2-( 2-Hydroxy-3 , 5 -disulXophenoxy) -1,3 , 2-benzodioxa- 
stibole-i,6-disulfonic acid, tetrasodium salt 
( Stibophen ) . 

'i-Hydroxy-3-nitrobenzenearsonic acid 

4-Ifydroxy-3-nitrobenzenearsonic acid, sodium salt 

p-Nitrobenzenearsonic acid 

1,2,5,6-Tetrahydro-l-methylniootinic acid, methyl 
ester, N-acetyl-4-hydroxy-m-arsanilate (Drocarbil) 
Mercury compounds : 

o-Chloromercuriphenol ( o-Ifydroxyphenylmercuric 

chloride ) . 
Dibromohydroxymercurifluorescein, sodium salt (Mer- 

bromin ) . 
Ethylmercurithiosalicylic acid, sodium salt 

(Thimerosal). 
6-(Hydroxymercuri)-5-nitro-o-cresol, inner salt 
(Nitromersol). 

Mercuric salicylate 

Phenylmerouric acetate 

Phenylmerouric benzoate 

Phenylmercuric borate 

Phenylmerouric nitrate 

»l-Hexadeoylpyridinium (Cetylpyridinium) chloride 

*Phenolic antiseptics and disinfectants: 

Chlorothymol 

2-Naphthol ( |3-Naphthol)' 

Resoroinol 

Resorcinol monoacetate 

Thymol 

Thymol iodide 



Manufacturers ' identification codes 
(according to list in table 22) 



HEX, 


SCH, X. 




CBP. 






HEX, 


MRK, PYl, 


RSA 


NEP. 






ABB. 






ABB. 






LIL. 






SDW. 






BRS. 






HOF. 







SDW. 






SAL, 


WHL. 




SAL, 


WHL. 




MAL, 


NOR, 


PEN. 


LIL, 


PYL, 


RSA, WHL. 


SDW. 






SAL. 






SAL. 






SAL. 






SDW. 






MTL. 






HYN. 






LIL, 


PYL. 




ABB. 






MAL, 


MTL. 




WRC. 






MTL, 


WRC. 




MTL, 


WRC. 




MTL, 


WRC. 




BKL, 


FIN, 


CAN, HEX 


OPC. 






ACY. 






LEM. 






KPT. 






GIV. 






MAL. 







MEDICINAL CHEMICALS 



123 



TABLE 13B. 



-Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i964— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MEDICINAL CHIMICALS, BENZENOID— Continued 

*Anti -infective agents — Continued 
*Quinoline derivatives : 

8-[(4-Amino-l-methylbutyl) amino] -6-methoxyquinoline 

( Primaquine ) . 
8-[ ('i-Amino-l-methylbutyl )amino] -6-methoxyquinollne 

( Primaquine ) diphosphate . 
7-Chloro-4-(4-diethylaTm"no-l-methylbutylamino)quin- 

oline ( Chloroquine ) . 
7-Chloro-4-(4-[ethyl(2-hydroxyethyl)amino] -1-methyl- 

butylamino)quinoline (hydroxychloroquine) sulfate. 

*5-Chloro-7-iodo-8-quinolinol ( lodochlorhydroxyquin) 

'i-(7-Chloro-4-quinolylamino)-a-diethylamino-o-cresol 

(Amodiaquin). 
4-(7-Chloro^-quinolylainino)-a-diethylamino-o-cresol 

(Amodiaquin) hydrochloride. 

»5,7-Diiodo-8-quinolinol (Diiodohydroxyquin) 

8-Ifydroxyquinoline-5-sulfonic acid 

8-l3uinolinol ( Qxyquinoline ) 

*8-Quinolinol (Qxyquinoline) benzoate 

8-Quinolinol (Qxyquinoline) citrate 

8-Q(iinolinol (Qxyquinoline) potassium sulfate 

»8-Quinolinol (Qxyquinoline) sulfate 

*Sulf onamides : 

6-Acetamido-4-hydroxy-3-(<t-sulf amoylphenylazo) -2,7- 

naphthalenedisulfonio acid, disodium salt (Azo- 

sulfamide). 
N-'--Acetyl -N^- ( 3,4-dlmethyl-5 -isoxazolyl )sulf anilamide 

( Acetylsulf isoxazole ) . 

N^-Acetylsulfamethoxypyridazine 

- 4'-(Acetylsulfamoyl)phthalanilio acid (Phthalyl- 

sulf acetamlde ) . 

N*-Benzylsulfanilamide 

N,N'-Bis(3-nitrobenzenesulfonyl)ethylenediamine 

N^- ( 6-Chloro-2 -pyrazinyl ) sulfanilamide ( Sulf achloro- 

pyrazine), sodium derivative. 
N-'--(2,6-Dimethoxy-4-pyrimidinyl)sulfanilamide (Sulfa- 

dimethoxine ) . 
N-'--(3,4-Dimethyl-5-isoxazolyl) sulfanilamide (Sulf isoxa- 
zole) . 
N^-(5-Ethyl-l,3,4-thiadiazol-2-yl)sulfanilamide (Sulfa- 

ethidole). 
N-'--( 5 -Methyl-3-isoxazolyl) sulfanilamide (Sulfamethoxa- 
zole ) . 
N^-(5-Methyl-3,4-thiadiazol-2-yl)sulfanilamide (Sulfa- 

methizole ) . 
4' - ( p -Ni trophenyls ulf amoyl ) aeetanilide (Sulfanitran)— ■ 

p-Nitrosulfathiazole 

Succinylsulfathiazole 

Sulfabromomettiazine, sodium 

Sulfanilamide 

Sulfanilanilide 

N-Sulfanilylacetamide (Sulfacetamide) 

N-Sulfanilylacetamide, sodium derivative 

N-Sulfanilylbenzajnide ( Sulf abenzamide ) 

N-Sulfanilylbenzamide, sodium derivative 

Sulfadiazine 

Sulfadiazine, sodium 



SDW. 

PD. 

SDW. 

SDW. 

CBP, MTL, PYl. 
PD. 

PD. 

LEM, PYL, PSA, SHI. 

MTL. 

GAM, LEM, MTL. 

GAM, LEM, MTL. 

GAM. 

LEM. 

GAM, LEM, MTL, PYL. 

SDW. 



ACY. 
LEM. 

SDW. 

SAL. 
ACY. 

HQF. 

HOP. 



ACY. 

SAL. 

SDW. 

LEM, MRK. 

MRK. 

MRK. 

LEM, SAL. 

LEM, SCH. 

LEM, SCH. 

ACY. 

ACY. 

ACY, LEM. 

ACY. 



124 



SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 13B -Mediciml chemicals for which U.S. production or sales were reported, identified hy 
lABLii!- iJo. manufacturer, i 964 —Continued 



Chemical 



MEDICIKAL CHEMICALS, BENZENOID— Continued 

»Anti -infective agents— Continued 
^Sulfonamides — Continued 

Sulfaguanidlne " "" 

Sulfamerazine 

Sulfamerazine, sodium 'J'S" 

Sulfamethazine 

Sulfamethoxypyridazine 'J^ 

Sulfapyridine " 

Sulfapyridine, sodium 

Sulfaqulnoxallne 

*Sulfathiazole " "' 

Sulfathiazole, sodium ''"/TllZ'V-, 

<i'-(2-Thlazolylsulfajiioyl)phthalanilic acid (Phthalyl- 

sulf athiazole ) . 
*Other antl -Infective agents: 

^Anthelmintic, antifungal, and antiprotozoan agents : 
l-[ ('i-Amino-2-propyl-5-pyrlmidlnyl)methyl] -2- 
pioollnium chloride hydrochloride (Amprolium). 

Anthranlllc acid, cadmium salt 

Benzoic acid " 

Bis(3-nltrophenyl) disulfide ( Nitrophenide ) 

2-Chloro^-nitrohenzamlde (Aklomlde) 

2,4-Diamlno-5-(p-ohlorophenyl)-6-ethylpyrlmldine 

( I^lmethamine ) . 
6-(2-Diethylaminoethoxy)-2-dimethylaminobenzo- 
thiazole ( Diamthazole ) dlhydrochloride. 

Fuchsin, basic " 

Gentian violet (Methylrosanlllne chloride) 

Hexylresorclnol 

p-Ifydroxybenzolc acid esters : 

n-Butyl p-hydroxybenzoate 

Ethyl p-hydroxybenzoate 

Methyl p-hydroxybenzoate 

Propyl p-hydroxybenzoate 

Phenothlazine 

P5mrinlum pamoate " 

2-(4-Thiazolyl)benzimldazole (Thiabendazole) 

*A11 other anti-infective agents: 

Acriflavine 

Aeri violet 

Aminosalicylic acid and salts: 

4-Amlnosallcylic acid 

Calcium ^-aminosalicylate 

Potassium ^-aminosalicylate 

Sodium -^-aminosalicylate 

Ammonium benzoate 

Calcium mandelate 7 

N-Chloro-p-toluenesulfonamide, sodium derivative 

(Chloramine T). wj™ 

2,4-Dlamino-4'-ethoxyazobenzene (Ethoxazene) nyaro- 

chlorlde. . 

2, 6-Dlamlno-3-phenylazopyrldlne ( Phenazopyridme ) 

hydrochloride . 

3j5-Dlnltrobenzamide 7 

l-Ethyl-l,4-dlhydro-7-methyl-4-oxo-l,8-naphthyri- 

dine-3-carboxylic (Nalidixic) aold. 
Hexamethylenetetramlne (Methenamine) mandelate 



Manufacturers' Identification codes 
(according to list in table 22) 



ACY, LEM. 

ACY, LEM. 

ACY. 

ACY, LEM. 

ACY. 

ACY, MRK. 

ACY. 

MRK. 

ACY, LEM, MRK. 

ACY, MRK. 

LEM, MRK. 



MRK. 

MAL. 

MON, PFZ. 
ACY. 
SAL. 
BUR. 

HOP. 

NAC. 

NAC, SDH. 
HEX, MRK. 

HN, ICO. 
HN. 



HN, ICO, LEM, FYL. 
HN, ICO, LEM, PYL. 
CLV. 



NAC. 
NAC. 

MLS. 
MLS. 
MLS. 
MLS. 
PEN. 
MAL. 
MON. 

KON. 

HOF, KON, NEP. 

SAL. 
SDW. 

LEM, NEP, PYL, TNC. 



MEDICINAL CHEMICALS 



125 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, iderdified by 

manufacturer, i 564- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MEDICINAL CHmiCALS, BENZENOID— Continued 

*Anti -infective agents — Continued 

mother anti-infective agents —Continued 

*A11 other anti -infective agents — Continued 

Isonicotinic acid hydrazide- (Isoniazid) 

Magnesium salicylate 

Mandelic acid 

Methylene blue 

Fyrazine-2-oarboxamide ( I^azinainide ) 

[ Sulf onylbis (p -phenyleneimino ) ] dimethanesulf inic 
acid (Sulfoxone), discdium salt. 

3,4',5-Tribromosalioylanilide (Tribromsalan) 

^Autonomic drugs : 

*ParaEymatholytic (anticholinergic) agents: 

Anisotropine methyl bromide 

(3 -Carbamoyl -3, 3-diphenylpropyl)diisopropy Imethyl- 

ammonium ( Isopropamide ) iodide. 
(3 -Carbamoyl -3, 3-diphenylpropyl) ethyldimethyl- 

aramonlum (Ambutonium) bromide. 
l-Cyclohexyl-3-diethylamino-l-phenyl-l-propanol 

ethiodide ( Tridihexethyl iodide). 
<i-(P -Cyolohexyl-g -hydroxyphenethyl ) -1, 1-dimethyl- 

piperazinium (Hexccyclium) methyl sulfate. 
a-Cyclohexyl-a-phenyl-1-piperidinepropanol (Tri- 
hexyphenidyl ) . 
a-Cyolohexyl-a-phenyl-1-piperidinepropanol (Tri- 
hexyphenidyl ) hydrochloride . 
P-Diethylaminoethyl diphenylthioaoetate ( Thiphenamil ) 

hydrochloride . 
10-(2-Diethylaminopropyl)phenothiazine (Bthopropazine)- 
Diethyl(2-hydroxyethyl)methylammonium bromide, 

xanthene-9-carboxylate (Methantheline bromide). 
4- ( Dimethylami no ) -2, 2 -diphenylvaleramide (Aminopenta- 

mide) sulfate. 
N, N-Dimethyl-2-( o-methyl-a-phenylbenzyloxy) ethylamine 

(Orphenadrine) citrate. 
N,N-Dimethyl-2-( o-methyl-a-phenylbenzyloxy) ethylamine 

( Orphenadrine ) hydrochloride . 
N,N-Dimethyl-4-piperidylidene-l,l-diphenylme thane 

(Diphemanil) methyl sulfate. 
Diphenylaoetyldiethylaminoethanol (Adiphenine) hydro- 
chloride . 
N- Ethyl -3-piperidyl benzilate methobromide (Pipenzo- 

late bromide). 
N-Ethyl -3-piperidyl diphenylacetate ( Piperidolate ) 

hydrochloride . 
Fluorene-9-carboxylio acid, 2-(diethylamino)ethyl 

ester (Pava trine) hydrochloride. 

Homatropine ■ 

Homatropine hydrobromide 

Homatropine methyl bromide 

4-Ifydroxy-l,l-dimethylpiperidinium methyl sulfate, 

3-methyl-2-phenylvalerate ( Pentapiperide methyl 

sulfate). 
(2-Hydroxyethyl)diisopropylmethylammonium bromide, 

xanthene-9-carboxylate (Propantheline bromide). 
N-Methyl -3-piperidyl benzilate methobromide (Mepenzo- 

late bromide ) . 



RIL. 
MAI. 
MAL. 
ACY, NAC. 

MRK. 
ABB. 

TRO. 



SK. 

ICO. 

ACY. 

ABB. 

SDW. 

ACY. 

X. 

NEP. 
SRL. 

ICO. 

RIK. 

RIK. 

SCH. 

CBP. 

LKL. 

LKl. 

SRL. 



CTN, HEX. 

CTN. 

CTN, EN, HEX. 



SRL. 
LKL. 



126 



SYNTHETIC ORGANIC CHEMICALS. 1964 



TABLE 13B. 



. Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



MEDICINAL CHEMICAIS, BENZENOID— Continued 

^Autonomic drugs — Continued 

^Parasympatholytic (anticholinergic) agents --Continued 
l-Phenylcyclohexaneglycolio acid, ( 1,4,5, 6-tetrahydro- 
l-methyl-2-pyTimidinyl)inethyl ester (Oxyphen- 
cyclimine) hydrochloride. 
1-Phenylcyolopentaneoarboxylio acid, 2-diethylamino- 

ethyl ester ( Caramiphen) ethanedisulf onate . 
Tropine benzhydryl ether methanesulf onate (Benztropine 
mesylate ) . 
^-Sympathomimetic (adrenergic) agents: 

i_3,<i_DihydroxyTiorephedrine (Nordefrin) hydrochloride— 

*Epinephrine 

l-(p-Hydroxyphenyl) -2-(l-niethyl-3-phenylpropylamine) - 
propanol (Nylidrin) hydrochloride. 
»a-(lsopropylaminomethyl)protocatechuyl alcohol (Iso- 
proterenol ) . 
o-Methoxy-N,a-diinethylphenethylamine (Methoxyphena- 

mine) hydrochloride. 
a-(l-Methylaminoethyl)benzyl alcohol ( Pseudoephedrine ) 

hydrochloride . 
a-(l-Methylaminoethyl)ben2yl alcohol (Pseudoephedrine) 

sulfate. 
a-[([x-Methyl-3,4-methylenedioxyphenethylamino)- 
methyl]protocatechuyl alcohol ( Protoltylol ) hydro- 
chloride . 

^Norephedrine (Phenylpropanolamine) hydrochloride 

1 -Phenylephrine base 

^Phenylephrine hydrochloride 

2-(l,2,3,4-Tetrahydro-l-naphthyl)-2-imidazoline 
( Tetrahydrozoline ) hydrochloride . 
*111 other autonomic drugs : 

2-Benz;yl-2-imidazoline (Tolazoline) hydrochloride 

1-Hydrazinophthalazine (Ifydralazine) hydrochloride 

3-Ifydroxy-l-methylpyridinium bromide, dimethyl- 
carbamate (I^idostigmine bromide). 

Neostigmine bromide 

Physostigmine 

*Benzothiadiazine derivatives : 

3-Benzyl-3,'4-dihydro-6-(trifluoromethyl)-2H-l,2,4-benzo- 
thiadiazine-7-sulfonamlde 1,1-dioxide (Bendroflu- 

me thiazide). 
3-Benzylthlomethyl-6-chloro-2H-l,2,'i-benzothladia- 

zine-7 -sulfonamide 1,1-dioxide (Benzthiazlde). 
6-Chloro-2H-l, 2, •i-benzothiadiazine-7 -sulfonamide 1,1- 
dioxide (Chlorothiazide). 
6-Chloro-2-chloromethyl-3,<i-dihydro-2-methyl-2H-l,2,'4- 

benzothiadiazine-7-sulfonamide 1,1-dioxide (Methy- 

clo thiazide ) . 
6-Chloro-3-dichloromethyl-3,'i-dihydro-2H-l,2,4-benzo- 

thiadiazine-7-sulfonamide 1,1-dioxide (Trichlor- 

methiazide). 
6-Chloro-3,4-dihydro-2H-l,2,4-benzothiadiazine-7-sul- 

fonamide 1,1-dioxide (Ifydrochlorothiazide). 
6-Chloro-3, 4-dihydro-2 -methyl -3-(2, 2, 2-trif luoroethyl- 

thiomethyl)-2H-l, 2, 4-benzothladiazine-7 -sulfonamide 

1,1-dioxide (Polythiazide). 
6-Chloro-3,4.-dihydro-3-(5-norbomen-2-yl)-2H-l,2,4-ben- 

zothiadiazine-7 -sulfonamide 1,1-dioxide (Cyclo- 

thiazide). 



Manufacturers' identification codes 
(according to list in table 22) 



SDW. 

DQD, SDW, VB. 



ABB, CTN, GAH. 



BUR, CAN. 
CAN. 



BKL, GAM, CAN, HEX, ICO, NEP, ORT. 

CTN, GAN. 

CTN, GAN, SDW. 
PFZ. 



CTN. 
GBP. 

HOF. 

HEX. 
PEN. 

CMS. 



MRK. 
ABB. 



SCH. 



ABB, CBP, MRK. 
PFZ. 



LIL. 



MEDICINAL CHEMICALS 



127 



TABLE 13B.-- Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1964 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MEDICINAL CHIMICAIS, BENZENOID— Continued 

*Benzothiadiazine derivatives — Continued 

3,4-Dihydro-6-(trifluoromethyl)-2H-l,2,'^-'benzothia- 

diazine-V-sulfonamide 1,1-dioxide (Hydroflumethiazide). 
6-(Trifluoromethyl)-2H-l,2,'i-benzothiadiazine-7-sulfon- 
andde 1,1-dioxide (Flume thiazide). 

*Bismuth subgallate 

^Central depressants : 

*Dihydrooodeinone (Hydrooodone) bitartrate 

*5-Ethyl-5-phenylbarbituric acid (phenobarbital) 

*5-Ethyl-5-phenylbarbituric acid, sodium derivative 

*p-Ifydroxyacetanilide (Acetaminophen) 

^-Salicylates : 

Aluminum aspirin 

*Aspirin 

Ethyl salicylate carbonate 

Glycol monosalicylate 

Phenyl salicylate (Salol) 

Potassium salicylate 

Salicylamide 

Salicylsalicylic acid 

*Sodium salicylate 

Strontium salicylate 

^Skeletal muscle relaxants and tranquilizers: 
*Phenothiazine derivatives : 

2-Chloro-10-(3-dimethylaminopropyl)phenothiazine 

( Chlorpromazlne ) hydrochloride . 
2-Chloro-10-[3-(l-methyl-4-piperazinyl)propyl] - 

phenothiazine (Prochlorperazine) dimaleate. 
2-Chloro-10-[3-(l-methyl-4-piperazinyl)propyl] - 

phenothiazine (Prochlorperazine) ethanedisulfonate. 
'i-[3-(2-Chlorophenothiazin-10-yl)propyl]-l-piper- 

azineethanol ( Perphenazine ) . 
10-(2-DiinethylaTninopropyl)phenothiazine (Prometh- 
azine) hydrochloride. 
10 - ( 3 -Dimethylrimi nopropyl )phenothiazine ( Promazine ) 

hydrochloride . 
10 - ( 3 -Dimethylaminopropyl ) -2 - ( trif luoromethyl ) - 
phenothiazine (Triflupromazine) hydrochloride. 
1- [ 10- ( 3 -[<+-( 2 -Hydroxyethyl ) -1-piperazinyl] propyl ) - 
phenothiazin-2-yl] -1-propanone ( Cairphenazine ) 
base and maleate. 
10-[(l-Methyl-3-piperidyl)methyl]phenothiazine 

(Mepazine) hydrochloride hydrate. 
4-(3-[ 2- ( Trif luoromethyl )phenothiazin-10-yl] propyl ) - 
1-piperazineethanol ( Fluphenazine ) dihydro- 
ohloride. 

*3-o-Tolyloxy-l,2-propanediol (Mephenesin) 

*A11 other skeletal muscle relaxants and tranquilizers : 
2-(Butylaminomethyl)-8-ethoxy-l,4-benzodioxane 

( Ethoxybutamoxane ) hydrochloride , 
l-(p-tert-Butylbenzyl)-4-(p-chloro-a-phenylbenzyl)- 

piperazine (Buclizine) dihydrochloride. 
Carbamic acid, 2-hydroxy-2-phenylbutyl ester 

( ^ydroxyphenamate ) . 
Carbamic acid, 2-hydroxy-2-phenylethyl ester 
( Styramate ) . 



BKC, MAI, PEN. 



EN, MAL, MRK, 


PEN. 


BPC, GAN, MAL, 


SDW. 


BPC, GAH, MAL, 


SDW. 


ABB, ATP, MLS, 


NEP. 


ABB, SCH. 




CFC, DOW, MI5, 


MON, NOR, SDG 


PD. 




EDA. 




DOW, MAL, PEN. 




HST, PEN. 




CFC, X. 




TNC. 




DOW, HN, MON. 




MAL, TNC. 





SK. 

SK. 

SK. 

SCH. 

WYT. 

WYT. 

CMS, SK. 

wn. 

NEP. 
CMS, SCH. 

BKL, HEX, QMS. 

LIL. 

PFZ. 

AHP. 

ARP. 



128 SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 13B. -Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i 564— Continued 



MEDICINAL CHEMICALS, BE^EENOID— Continued 

K-Central depressants — Continued 

*Skeletal muscle relaxants and tranquilizers— Continued 
*A11 other skeletal muscle relaxants and tranquilizers— 
Continued 
l-(p-Chlorobenzhydryl )-A-[2-{2 -hydroxyethoxy) ethylj - 

piperazine (hydroxyzine) dihydrochloride . 
l-(p-Chlorobenzhydryl) -A-i 2-( 2-hydroxyethoxy) ethyl] - 

piperazine (Hydroxyzine) pamoate. 
7-Chloro-l,3-dihydro-l-metl:^l-5-phenyl-2H-l,4-t)enzo- 

diazepin-2-one- (Diazepam). Y 

trans-2-Chloro-N,';N-dimethylthioxanthene-A^' -propyl- 
amine (Chlorprothlxene). 
7-Chloro-2-methylamino-5-phenyl-3H-l,'4-benzodi- 

azepine-4-oxide ( Chlordiazepoxide ) hydrochloride. 
2-(p-Chlorophenyl)-3-methyl-2,3-butaiiediol (Phena- 

glycodol ) . 
2 - ( 4-Chlorophenyl ) tetr ahydro -3 -methyl -4H-1, 3 -thiazin- 

<i-one 1,1-dioxide ( Ghlormezanone ) . 
5 - ( o-Methoxyphenoxymethyl ) -2 -oxazolidinone (Mephen- 

oxalone ) . 
2-Jfethyl-3-o-tolyl-'i ( 3H) -quinazolinone ( Methaqualone ) 
a-(4-Piperidyl)benzhydrol (Azacyclonol) hydro- 
chloride. 
3-o-Tolyloxy-l,2-propajiediol 1-carbamate (Mephenesin 
carbamate). 

Tubocurarine 

*A11 other central depressants : 

Acetanilide 

Aoetophenetidin (Phenacetin) 

p-Aminobenzoic acid and salts : 

p-Aminobenzoic acid 

Calcium p-aminobenzoate 

Magnesium p-aminobenzoate 

Potassium p-aminobenzoate 

Sodium p-aminobenzoate 

l-(p-Aminophenethyl)-'i-phenylisonipecotic acid, ethyl 

ester (Anileridine) dihydrochloride. 
2-(p-Aminophenyl) -2-ethylglutarimide (Aminoglutethi- 

mide. 
<i-Butyl-2-p-hydroxyphenyl-l-phenyl-3,5-pyrazolidine- 

d ione ( Oxyphenbutazone ) . 

Colchicine 

Dihydrohydroxycodeinone (Cixycodone) hydrochloride 

a-d-4-Dlmethylamino-l,2-diphenyl-3-methyl-2-propoxy- 

butane (Propoxyphene) hydrochloride. 
( [ (2,3-Dimethyl-5-oxo-l-phenyl-3-py^azolin-'i-yl)- 
methyl]-amino)methanesulfonio acid, sodium salt 

(Dipyrone). 

N,2-Dimethyl-2-phenylsucoinimide (Ifethsuximide ) 

5,5-Di^henylhydantoin 

5, 5-Diphenylhydantoln, sodium salt 

5-Ethyl-l-methyl-5-phenylbarblturle acid (Mepho- 

barbital) . 

Ethyl l-methyl-4-phenylisonipecotate (Meperidine) 

Ethylmorphlne hydrochloride 

5-Ethyl-5-phenylbarblturic acid (Phenobarbital), 

calcium derivative. 

2-Ethyl-2-phenylglutarlmide ( Glutethimide ) 

3-Ethyl-5-phenyIhydantoin (Ethotoin ) 

Hexahydro-l-methyl-4-phenylazepine-4-carboxyllc acid, 

ethyl ester ( Ethoheptazine ) citrate. 



Manufacturers' identification codes 
(according to list in table 22) 



PFZ. 

PFZ. 

HOF. 

HOF. 

HOF. 

LIL. 

SDW. 

ACY. 

HEX. 
BKC. 

CMS. 

ABB, CMS. 

CTN. 
DOW, MON. 

LEM. 
LEM. 
LEM. 

CAN, LEM. 
CAN, LEM. 
MEK. 

CBP. 

GGY. 

PEN. 

EN. 

LIL. 



SDW, WYT. 
MAL, MRK. 
CAN. 

CBP. 
ABB. 
WYT. 



MEDICINAL CHEMICALS 



129 



TABLE 13B. Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1964 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MEDICINAL CHEMICALS, BENZENOID— Continued 

♦Central depressants — Continued 

*A11 other central depressants — Continued 

lodoantipyrine (lodopyrine) 

d-3-Methoxy-N-methylmorphinan (Dextromethoiphan) hydro- 
bromide. 
oj-MethoxypolyCethyleneoxy) ethyl p-butylaminobenzoate 
( Benzonatate ) , 

N-Methyl-2-phenylsuccinimide ( Phensuximide ) 

10-Hienothiazineoarboxylio acid, 2-(2-diinethylamino- 
ethoxy)ethyl ester (Dimethoxanate) hydrochloride. 

Fhenylacetylurea ( Phenacemide ) 

1-Phenylcyclopentaneoarboxylic acid, 2-(2-diethylaiiu.no- 

ethoxy)ethyl ester ( Carbetapentane ) citrate. 
a-(2-iyridylajninomethyl)benzyl alcohol ( Phenyramidol ) 
hydrochloride . 
♦Central stimulants : 
♦Amphetamines : 

♦Amphetamine, dextroamphetamine, and levan^hetamine 
base and salts : 

d-a-Methylphenethylamine (Dextroamphetamine) base 

d-a-Methylphenethylamine, carboxymethylcellulose salt 

d-a-Methylphenethylamine hydrochloride 

d-a-Methylphenethylamine phosphate 

d-a-Methylphenethylamine sulfate 

d-a-Metl^rlphenethylamine tannate . 

dl-a-Methylphenethylamlne (Amphetamine) base 

dl-a-Methylphenethylamine hydrochloride 

dl-a-Methylphenethylamine sulfate 

2 -a-Methylphenethylamine ( Levamphetamine ) succinate — 
♦Methamphetamine base and hydrochloride : 

d-N,a-Dimethylphenethylamine (Methamphetamine) hydro- 
chloride. 
dl-N,a-Dimethylphenethylamine (Methamphetamine) base- 
dl-N,a -Dimethylphenethylamine (Methamphetamine ) 

hydrochloride. 
Z -N,a -Dimethylphenethylamine (Methamphetamine) base — 
♦Antidepressants : 

l-[2-(Benzylcarbamoyl)ethyl]-2-isonicotinoylhydrazine 

( Nialamide ) . 
10,11-Dihydro-N, N-dimethyl-5H-dibenzo[a,d] cycloheptene- 

45, Y -propylamine ( Amitriptyline ) . 
10,ll-Dihydro-N-methyl-5H-dibenzo[a,d]cyoloheptene- 
A 5, Y -propylamine (Nortriptyline). 

Phenethylhydrazlne (Phenelzine) sulfate 

trans-2-Phenylcyclopropylamine (Tranylcypromine) sulfate 
♦All other central stimulants : 

d-N-Benzyl-N,a -dimethylphenethylamine (Benzphetamine ) 
hydrochloride . 

Caffeine sodium benzoate 

p-Chloro-a ,a-dimethylphenethylamine ( Chlorphentermine ) 
hydrochloride . 

Diethylaminopropiophenone (Diethylpropion) 

2-(Dlmethylamino)ethanol, p-acetamidobenzoic acid salt 
(Deanol acetamidobenzoate ) . 

a , a -Dimethylphenethylamine ( Phentermine ) 

3,'4-Dimethyl-2-phenylmorpholine ( Phendimetrazine ) 

3-Methyl-2-phenylmorpholine ( Phenmetrazine ) hydro- 
chloride . 
Nikethamide 



MAL. 
HOF. 



CBP. 
PD. 



ABB. 
PFZ. 



HEX. 




arc. 




HEX. 




ore. 




HEX, 


SK. 


OTC. 




HEX, 


ORT. 


HEX. 




HEX, 


SK. 


OTC. 




ABB, 


GAN, HEX 


HEX, 


OTC. 


GAN, 


HEX. 


ABB. 




PFZ. 




MRK. 




LIL. 




NEP. 





GAN, MAL. 
NEP. 

BKC, GAN. 
RIK. 

HEX. 

x. 

GGY. 

CBP. 



130 



SYNTHETIC ORGANIC CHEMICALS. 1964 



TABLE 13B.- 



■ Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i564 --Continued 



MEDICINAL CHEMICALS, BENZENOID--Continued 



*Guaiaool glyceryl ether 

*Salioylio aold 

*Synthetlo hypoglycemic agents : 

1- [(p-Acetylphenyl )sulfonyl] -3-oyclohexylurea ( Aceto- 
hexamide ) . 

l-Butyl-S-p-tolylsulConylurea (Tolbutamide) 

l-(p-Chlorobenzenesulfoiiyl)-3-propylurea (Chlorpropamide) 
l-(Hexahydro-l-azepinyl)-3-p-tolylsulfonylurea (Tolaz- 
amide). 

l-Phenethylbiguanide (Phenformin) hydrochloride 

*Vitajnins : 

«B2 (Riboflavin): 

For animal and poultry consumption 

For human consumption 

""B 12 ( Cyanocobalamin ) : 

Feed grade 

Pharmaceutical 

U.S. P. Crystalline 

■x-Niacin (Nicotinic acid): 

Feed grade 

Medicinal grade 

*Niaoinamide (Nicotinamide ) 

»A11 other vitamins : 

Folic acid 

Magnesium nicotinate 

Menadione 

Menadione sodium bisulfite 

2-Methyl-3-phytyl-l,4-naphthoquinone ( Phytonadione ) 

Nicotinamide hydrochloride 

I^idoxine 

Riboflavin-5' -phosphate, monosodium salt 

Sodium nicotinate 

a -Tocopherol 

a -Tocopherol acetate 

*A11 other benzenoid medioinals : 
Amino acids : 

dl-Acetyltryptophane 

dl-Phenylalanine 

dl-Tryptophane 

p-A[iiino-N-(2-diethylaminoethyl)benzamide (Procainamide) 
hydrochloride . 

Benzaldehyde 

3 -(4-Chloro-3 -sulf amoylphenyl ) -3 -hydroxyphthalimidine 

( Chlorthalidone ) . 
'i,5-Dichloro-m-benzenedisulfonamide (Dichlorphenamide) — 
l,l-Dichloro-2-(o-chlorophenyl)-2-(p-chlorophenyl)ethane- 
l -3-(3,4-Dlhydroxyphenyl)-2-methylalanine (Methyldopa)--- 
6,7-Dimethoxy-l-(4-ethoxy-3-methoxybenzyl)-3-methyl- 

quinoline (Dioxyline) phosphate. 
p,a-Dimethylben2yl camphorate, diethanolamine salt 
(Tooamphyl). 

p-(Di-n-propylsulfamoyl)benzoic acid (Probenecid) 

Estrogens : 

3,4-Bis(p-hydroxyphenyl)-2,4-hexadiene (Dienestrol) 

diacetate. 
«,£(' -Diethyl-Aj^'-stilbenediol (Diethylstllbestrol) --■ 
Estrogenic substance 



Manufacturers' identification codes 
(according to list in table 22) 



BKL, GAN, HEX, ICO, OTC. 
DOW, HN, HST, MON, SDH. 



HST, X. 
PFZ. 
UP J. 



GPR, HOF, MRK, IMP. 
HOF, MRK. 

GPR, MRK, FMP. 
IMC, MRK. 
MRK. 

ABB, CKL, MRK, NEP, RIL. 
MRK, NOP, PD, RIL, SCR. 
MRK, NEP, PD, RIL, SCR. 

ACY. 

NEP. 

ABB, HET, HFT. 

ABB, HET, WHL. 

MRK. 

NEP. 

HOF, MRK. 

HOF. 

MRK, NEP. 

CW, HOF. 

HOF. 



SDW. 
SDW. 
SDW. 
OMS. 



GGY. 

MRK. 
EDC. 
MRK. 
LIL. 



MRK. 
SCH. 



CTN, LIL. 
ORG. 



MEDICINAL CHEMICALS 



131 



TABLE 13B.-- Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1964 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MEDICINAL CHEMICALS, BENZENOID— Continued 

*A11 other benzenoid medicinals — Continued 

N-Ethyl-3,3' -diphenyldipropylamine 

N-Ethyl-3,3' -diphenyldipropylamine citrate 

N-Ethyl-3,3' -diphenyldipropylamine hydrochloride 

2-Formyl-l-methylpyridinium chloride, oxime (Pralidoxime 
chloride ) . 

Guaiacol, liquid and crystalline 

Hesperidin methyl chalcone 

Indocyanine green 

Local anesthetics : 

Benzocaine (Ethyl p-aminobenzoate) 

2-Butoxy-N-(2-diethylajiiinoethyl)cinchoninamide (Di- 

bucaine). 
<+- [3- (p-Butoxyphenoxy )propyl] morpholine ( Pramoxine ) 
hydrochloride . 

n-Butyl p-aminobenzoate (Butesin) 

Di(n-butyl p-ajninobenzoate) trinitrophenol (Butesin 
piorate). 

a-Diethylaniino-2,6-acetcxylidide (lidooaine) 

2-Diethylajiiincethyl '4-amino-2-propoxybenzoate (Propoxy- 

caine ) . 
p-Ethoxybenzoic acid, 2-(diethylamino)ethyl ester 

(Parethoxycaine) hydrochloride. 
2,2' -(2-lfydroxyethylimino )bis [n- (a , a-dimethylphenethyl) ■ 
N-methylacetamide] (Oxethazaine) . 

Isobutyl p-aminobenzoate (Cyoloform) 

2-Methyl-l-piperidinepropanol benzoate (Plperocaine ) 

hydrochloride . 
3-(2-Methyl-l-piperidyl)propyl p-oyolohexyloxybenzoate 

( Cyclomethycaine ) . 
Phenacaine [(Di-p-ethoxyphenyl)acetamidine] hydro- 
chloride. 

Procaine base (2-Diethylaininoethyl p-aminobenzoate) 

Procaine hydrochloride 

Propyl p-amincbenzoate 

l-iyrrolidineaceto-2',5'-xylidide (lyrrocaine) hydro- 
chloride . 
Tetracaine (2-Diinethylaininoethyl p-butylaminobenzoate) 
base. 

Tetracaine hydrochloride 

2-(p-Methoxyphenyl)-l,3-indandione (Anisindione ) 

2-Methyl-l, 2-di-3-pyridyl-l-propanone (Metyrapone ) 

3,3' -Methylenebis(4-hydroxycouniarin) (Bishydroxycoumarin) 
N-Methyl-N-(2-propynyl)benzylamlne (Pargyline) hydro- 
chloride . 

Phenolphthalein 

Phenolphthalein, yellow 

Phenolsulf onic acid salts : 

Aluminum phenolsulf onate 

Ammonium phenolsulf onate 

Sodium phenolsulf onate 

Zinc phenolsulf onate 

2-Phenyl-l,3-indandione ( Phenindione ) 

Podophyllum resin 

2-iyridinemethanol (Nicotinyl alcohol) tartrate 

Roentgenographic contrast media: 

3-Acetamido-2,4, 6-triiodobenzoio acid and sodium salt 

(Sodium acetrizoate). 
3-(3-Amino-2,'i,6-triiodophenyl)-2-ethylpropicnic acid 
(lopanoic acid). 



CTN. 
CTN. 
CTN. 
NEP. 

HN, MON. 
SKG. 



ABB, Lai. 
CBP. 



AST. 
SDW. 

ICO. 

WYT. 

ICO. 
LIL. 

LIL. 

SDW. 

ABB. 

ABB, LEM. 
ICO. 
EN. 

ICO. 

ICO, SDW. 
SCH. 
CBP. 
ABB, FIN. 



WLI. 

MAL. 

SAL. 

MAL, SAL. 

MAL. 

CTN, GAN. 

ABB. 

HOF. 

MAL. 

SDW. 



)32 SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 13B.— Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1 964 - -C ontinued 



MEDICINAL CHEMICALS, BENZENOID— Continued 

*A11 other benzenoid medicinals — Continued 
Roentgenographio contrast media — Continued 

3,5-Diacetamido-2,'4,6-triiodobenzoio acid, N-methyl 

gluoamine salt (Meglumine diatrizoate ) . 
3,5-Diacetamido-2,'i,6-triiodobenzcic acid, sodium salt 

(Sodium diatrizoate). 
3,5-Dipropionamido-2,'4,6-triiodobenzoic acid and sodium 
salt (Sodium diprotrizoate). 

Ethyl (iodophenyl)hendecanoate ( lophendylate ) 

Meglumine iothalamate 

Sodium o-iodohippurate dihydrate 

Sodium iothalamate 

Rutin 

Scarlet red 

Sodium benzoate 

8-Sucoinoylfluoranthene ( Florantyrone ) 

Sunscreens : 

Dipropylene glycol salicylate 

homo-Menthyl salicylate 

p-Methoxyoinnamic acid, benzyl ester 

p-Methoxycinnamic acid, 2-ethoxyethyl ester 

2,4,7-Triamino-6-phenylpteridine (Triamterene) 

MEDICINAL CHEMICAIS, NONBENZENOID 

*Anti-infective agents : 

»Caprylates and undecylenates : 

Calcium undecylenate 

Sodium caprylate 

Sodium undecylenate 

Undecylenic acid 

Zinc undecylenate 

»Derivatives of 5-nitrofurane, 5-nitroimidazole, and 
5-nitrothiazole : 

2-Acetamido-5-nitrothiazole ( Acini trazole) 

2-Amino-5-nitrothiazole 

l-Ethyl-3-(5-nltro-2-thiazolyl)urea (Ni thiazide) 

l-(2-}fydroxyethyl)-2-methyl-5-nitroimidazole (Metro- 
nidazole). 

5-Nitro-2-furaldehyde aoetylhydrazone ( Nihydrazone ) 

5-Nitro-2-furaldehyde semicarbazone (Nitrofurazone) 

N-(5-Nitro-2-furfurylidene)-l-aminohydantoin (Nitro- 
furantoin ) . 
3-( 5-Nitro-2-furfurylideneamino)-2-oxazolidinone ( Fura- 
zolidone). 
»Halogen compounds : 

Bromocamphor, mono- 

Bromoform (Tribromome thane) 

Chlorobutanol (tert-Triohlorobutyl alcohol) 

Iodoform 

l-Vinyl-2-pyrrolidinone iodine complex polymer 
(Povidone - iodine complex). 
*Piperazine and salts ; 

*Piperazine 

Piperazine adipate 

Piperazine calcium edetate 

Piperazine citrate 

Piperazine dihydrochloride 



Manufacturers' identification codes 
( according to list in table 22 ) 



SDW. 
SDW. 
MAL. 



MAI. 
MAI. 
MAL. 
PEN. 
NAC. 
PFZ. 
SRL. 

SBC. 
ICO. 
CIV. 
GIV. 



WTL. 
INC. 
BAC. 
BAC. 
BAC, LEM, MCO, TNC, WTL. 



ACY. 
ACY. 

MRK. 



NOR. 
NOR. 
NOR. 



MAL, 


PEN. 






DOW. 








BPC, 
MAL, 


PD. 
PEN. 






G. 








DOW, 


JCC, 


UCC, X. 




JCC, 


PYL, 


RDA. 




EN. 








JCC, 


RDA. 






DOW, 


JCC, 


PYL, RDA, 


WHL 



MEDICINAL CHEMICALS 



133 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1964 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MEDICINAL CHMICALS, NOMBENZENOID— Continued 

»Anti -infective agents — Continued 
*Piperazine and salts — Continued 

Piperazine hexahydrate 

*Piperazine hydrochloride 

*Piperazine phosphate 

Piperazine sulfate 

Piperazine tartrate 

All other 

*A11 other anti-infective agents ; 

l-Mamantanamine (Amantadine) hydrochloride 

l-Diethyloarhamoyl-4-methylpiperazine (Diethyl- 
carhamazine) dihydrogen citrate. 

Hexamethylenetetrajnine (Methenamine) 

p-(Hydroxymethoxy)trioarballylic acid, Y-lactone, 
hexamethylenetetramine salt (Citramin). 

4,5-Imidazoledioarboxamide ( Glyoarbylamide ) 

2-Propylvaleric acid and bismuth salt 

Sodium bismuth triglycollamate 

*Aatonomic drugs : 

Acetylcholine chloride 

Acetyl -P-methyloholine (Methacholine) chloride 

l-Cyclopentyl-2-methylpropylajnine ( Cyclopentamine ) hydro- 
chloride . 
Diethylaminocarbethoxybicyolohexyl (Dicyclomine) hydro- 
chloride. 
Diethyl ( 2 -hydroxyethyl)methylaiiimoniujii bromide, a-cyclo- 

pentyl-2-thiopheneglycolate (Penthienate bromide). 
N, a-Dimethyloyclohexaneethylamine (l-Cyclohexyl-2-methyl- 

aminopropane ) ( Propylhexedrine ) . 
Hexamethylenebis(trimethylajnmonlum chloride) (Hexa- 

methoniujn chloride). 
trans-['i-(l^droxydi-2-thienylmethyl)oyolohexyl]trimethyl- 
ammonium bromide (Thihexinol methylbromide). 

Tetraethylaranonium chloride 

^Central depressants and stimulants : 
*Barbiturates : 

5-ALlyl-5-sec-butylbarbituric acid (Talbutal) 

5-Allyl-5-(2-cyclopenten-l-yl)barbituric acid and salt- 
5-Allyl-5-isobutylbarbituric (Allylbarbituric) acid 

and salt. 
5-Allyl-5-(l-methylbutyl)barbiturio acid (Secobarbital) 

and salt. 
5-Allyl-5-(l-methylbutyl)-5-thiobarbituric acid (Thia- 

ncrlal), sodium derivative. 
dl-5-Allyl-l-methyl-5 -( l-methyl-2-pentynyl )barbituric 
acid (Methohexital), sodium derivative. 

*5-seo-Butyl-5-ethylbarbituric acid (Butabarbital) 

*5-sec-Butyl-5-ethylbarbituric acid, sodium derivative — 
5-(l-Cyolohexen-l-yl)-l,5-dimethylbarbiturio acid 

( Hexobarbital ) . 
5-(l-Cyolohexen-l-yl)-l, 5-dimethylbarbiturlc acid, 

sodium derivative. 
5-(l-Cyclohexen-l-yl)-5-ethylbarbiturio acid (Cyclo- 
barbital) and salt. 

5,5-Diethylbarbituric acid (Barbital) 

5,5-Diethylbarbiturio acid, sodium derivative 

5,5-Diethyl-l-methylbarbituric acid (Metharbital) 



JCC, RDA. 

DOW, JCC, RDA. 

BUR, JCC, PYL, RDA, WHL. 

JCC, RDA. 

PYL, RDA. 

PYL. 



HN. 
SDW. 



MRK. 

MRK, RSA. 
LIL. 

BKC. 

SDW. 

SK. 

RSA. 

SCH. 

RSA. 



SDW. 
GAN. 
GAN. 



ABB, BPC, GAN. 
ABB, BPC, GAN. 
GAN. 

SDW. 

GAN, SDW. 

GAN. 
GAN. 
ABB. 



134 



SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 13B -Medicinal chemicals for which U.S. production or sales were reported, identified by 
iAai.li. loD. manufacturer, 1964— Continued 



MEDICINAL CHEMICALS, NONBENZENOID— Continued 

^Central depressants and stimulants — Continued 
i^Barbiturates — Continued 

S-Ethyl-S-isoamylbarbituric acid (Amobarbital), sodium 

derivative. 
5-Ethyl-5-(l-inethyl-l-butenyl)barbiturio aoid (Vin- 
barbital ) . 
*5-Ethyl-5-(l-methylbutyl)barbituric aoid (Pento- 
barbital). 
5-Ethyl-5-(l-methylbutyl)barbituric acid, sodium de- 
rivative. 
5-Ethyl-5-(l-methylbutyl)-2-thiobarbitiiric acid (Thio- 
pental) and sodium derivative. 
5-Ethyl-5-n-pentylbarbituric aoid, sodium derivative — 
*Caf f eine : 

Natural 

Synthetic 

*2-Methyl-2-propyl-l,3-propanediol dicarbamate (Mepro- 
bamate ) . 

»Suooinylcholine chloride 

*A11 other central depressants and stimulants : 

Acetylcarbromal [ l-Aoetyl-3-(2-bromo-2-ethylbutyryl)- 
urea]. 

Bis(2,2,2-trifluoroethyl)ether (Flurothyl) 

2-sec-Butyl-2-methyl-l, 3 -propanediol dicarbamate 

(Mebutamate). 
N-Butyl-2-methyl-2-propyl-l,3-propanediol dicarbamate 
(Tybamate). 

Caffeine citrate 

Calcimn succinate 

Carbromal (Bromodiethylacetylcarbamide ) 

p-Chlorovinylethylethynyloarbinol (Ethchlorvynol) 

3,3-Diethyl-5-methyl-2,'4-piperidinedione (Methyprylon)- 

2-(Dimethylamino)ethanol (Deanol) bitartrate 

Divinyl ether 

2-Ethyl-ois-orotonylurea (Eotylurea) 

5-Ethyl-3,5-dimethyl-2,'i-oxazolidinedione ( Parametha- 
dione ) . 

2-Ethyl-2-methylsuooinimide (Ethosuximide) 

Ethynylcyclohexyl carbamate (Ethinamate) 

N-Isopropyl -2 -methyl -2 -propyl -1,3-propanediol dicar- 
bamate (Carisoprodol). 

Sodium hydroxydione succinate 

Sodium succinate 

2,2,2-Tribromoethanol 

3,5,5-Trimethyl-2,4-oxazolidinedione (Trlmethadione) — 
*Digestants and lipotropic agents : 

»Betaine base, hydrate, and hydrochloride: 

Betaine base 

Betaine hydrate 

Betaine hydrochloride 

»Bile acids and salts : 

Bile acids, oxidized 

Dehydrocholic acid 

Dehydrocholic acid, sodium salt 

Iron bile salts 

Oxbile extract 

^Choline bitartrate 



Manufacturers' identification codes 
(according to list in table 22) 



BPC, GAN, LIL. 

GAN. 

ABB, BPC, GAN. 

ABB, BPC, GAN. 



GNF, luffW. 
MON, PFZ. 
ABB, BKL, ICO, PEN, x. 

ABB, BUR, SDW. 

MLS. 

TBK. 

X, X. 



MAL, MRK. 
LEM, PEN. 
MLS, PD. 



MRK. 
MLS. 



PFZ. 
PEN. 
SDW. 
ABB. 



MAL. 
HFT. 
HFT, LEM, INC. 

MRK, SRL, WIL. 

WIL. 

WIL. 

LIL. 

ABB. 

ACY, CFC, HFT. 



MEDICINAL CHEMICALS 



135 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1964 — Continued 



MEDICINAL CHIMICALS, NONBENZENOID— Continued 

*Digestants and lipotropic agents — Continued 
^Choline chloride : 

Feed grade 

Medicinal grade 

Technical grade 

^Choline dihydrogen citrate 

'•Methionine and hydroxy analogue : 

Methionine, feed grade 

dl-Methionine, medicinal grade 

Methionine, hydroxy analogue 

»Trioholine citrate 

*A11 other digestants and lipotropic agents : 

Acetylmethionine 

Choline bicarbonate 

Sitosterols 

*Hormones : 

Corticotropin 

Dexamethasone 

Dexamethasone acetate 

Dexamethasone 21 -phosphate 

9,lip-Dichloro-17,21-dihydroxypregna-l,4.-diene-3,20- 

dione (Dichlorisone) 21-aoetate. 
17a-Ethynyl-17P-hydroxy-5(lO)-estrene-3-one (Norethyno- 
drel). 

9c4-Fluorohydrooortisone acetate (Fludrocortisone) 

Fluorometholone 

9-Fluoro-llfi,17,21-trihydroxy-16j3-methylpregna-l,4-diene 
3,20-dione (Betamethasone). 

Fluoxymesterone 

Fluprednisolone 

*Hirdrocortisone alcohol and acetate 

hydrocortisone dlethylaminoaoetate ( Ifydrocortamate ) 
hydrochloride . 

Ifydrocortisone phosphate 

J.7-Ifydroxy-ll-dehydrooortioosterone (Cortisone) and 

acetate. 
17-^ydroxypregna-4-ene-3,20-dione (Ifydroxyprogesterone)- 

lla-Hydroxyprogesterone 

Insulin (salt cake) 

Medroxyprogesterone acetate 

17 -Methyl -5a-androstano[3,2-c] pyrazole-17/3-ol (Stano- 
zolol ) . 

Methylprednisolone 

Prednisolone 

*Prednlsone 

Progesterone 

Triamcinolone 

^Theobromine and theophylline derivatives : 

Theobromine, sodium acetate 

Theophylline aminoisobutanol (Ambuphylllne) 

Theophylline cholinate (Oxtriphylline) 

Theophylline ethylenediamine (Aninophylline) 

Theophylline ethylenediamine, sodium biphosphate 

Theophylline monethanolamine 

^Therapeutic nutrients : 
*Amino acids ; 

|S -Alanine 

*Amino acid mixtures 



Manufacturers' identification codes 
(according to list -in table 22) 



CCM, 


HFT. 




CFC, 


HFT. 




DLI, 


RH. 




ACY, 


CFC, 


HFT 


DOW. 






DOW, 


LEM. 




DUP, 


MON. 




ACY, 


CFC, 


HFT 


DOW. 






CCM, 


HFT. 




HP J. 






AHP, 


ORG, 


WIL 


MHK, 


SCH. 




SCH. 






MRK. 






SCH. 






SRL. 






UPJ. 






UP J. 






SCH. 






UPJ. 






UPJ. 






MRK, 


PFZ, 


UPJ 


PFZ. 






MRK. 






MRK, 


UPJ. 




SCH. 






UPJ. 






ARP. 






X. 






SDW. 






UPJ. 






MRK, 


SCH, 


UPJ. 


MRK, 


SCH, 


UPJ. 


X. 






ACY, 


OMS. 




MAL. 






GAN. 






NEP. 






GAN, 


LIM, 


SRL. 


GAN. 






LIL. 






BFG, 


NOP. 




ABB, 


CUT, 


STA. 



136 



SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 13B -Mediciml chemicals for which U.S. production or sales were reported, identified by 
TABLh, iJhi. ivjeui^c manufacturer, i 564 -Continued 



Chemical 



MEDICINAL CIDMICALS, NONBENZENOID— Continued 

x-Therapeutio nutrients— Continued 
*Amino acids — Continued 
*Aspartic acid and salts : 

dl-Aspartic acid 

Magnesium hydrogen aspartate 

Potassium hydrogen aspartate 

Glutamic acid and salts : 

^♦Glutaniic acid 

Glutamic acid, calcium salt 

Glutamic acid hydrochloride 

Glutamic acid, monoammonium salt 

Glutamic acid, monopotassium salt 

Glycine (Aminoaoetic acid) 

lysine, feed grade 

lysine hydrochloride 

*Calcium gluconate 

*A11 other therapeutic nutrients: 

Calcium glucoheptonate 

Calcium glycerophosphate 

Calcium lactophosphate 

Calcium levulinate 

Calcium phytate 

Copper gluconate 

Fructose (Levulose) 

Iron (ferrous) gluconate 

Lecithin, purified 

Magnesium gluconate 

Manganese gluconate 

Potassium gluconate 

Sodium glycerophosphate 

*5-Ureidohydantoin (Allantoin) 

^Vitamins : 

*Ascorbio acid and derivatives : 

*Ascorbic acid 

Ascorbic acid, calcium salt 

Ascorbic acid, sodium salt 

Ascorbyl palmitate 

^Pantothenic acid and derivatives: 

d-Calcium pantothenate 

»dl-Calcium pantothenate: 

Feed grade 

Medicinal grade 

dl-Caldium pantothenate, calcium chloride complex- 

d-Pantothenyl alcohol (Dexpanthenol) 

dl-Pantothenyl alcohol (Panthenol) 

Sodium pantothenate 

*Vitajiiin A alcohol and esters : 

Vitamin A acetate (feed grade) 

Vitamin A acetate (medicinal grade) 

Vitamin A alcohol 

Vitamin A natural esters 

Vitamin A palmitate (feed grade) 

»Vitamin A palmitate (medicinal grade) 

*Vitamin Da (Ergocalciferol) 

*A11 other vitamins : 

Biotin 

P -Carotene 

Inositol 

Thiamin hydrochloride 

Thiamin mononitrate 

Vitamin D3 ( Cholecalcif erol ) 



Manufacturers' identification codes 
(according to list in table 22) 



HE}{, MAC. 

WYT. 

WYT. 



MC, 


LIM, 


PFZ. 


LEM. 






IMC, 


LEM. 




IMC. 






IMC, 


LEM, 


PFZ. 


BPC, 


DOW. 




MRK. 






MRK. 






MAL, 


PFZ, 


WHL. 


PFN. 






SEL. 






MAI. 






SEL. 






STA. 






PFZ. 






DLL 






PFZ. 






ARP. 






PFZ. 






PFZ. 






PFZ. 






SEL. 






CTN, 


FIN, 


HFT. 


HOF, 


MRK, 


PFZ. 


PFZ. 






HOF, 


MRK, 


PFZ. 


PFZ. 






ACY, 


DLI, 


MRK, X. 


NOP. 






ABB, 


CKL, 


HFT, MRK, NOP 


NOP. 






HOF. 






HOF. 






PD. 






HOF 






HOF 


PFZ 




CW, 


HOF. 




CW. 






EK, 


HOF. 




n. 


HOF, 


PFZ. 


DLI 


NOP 


SCR, VTM. 


HOF 






HOF 






STA 






HOF 


, MRK 




HOF 


, MRK 




DLI 


, VTM 





MEDICINAL CHEMICALS 



137 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1964 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MEDICINAL CHEMICALS, NONBENZENOID— Continued 

*A11 other nonbenzenoid meaioinal chemicals : 

5-Aoetamido-l,3,'i-thiadiazole-2-sulfonajnide (Acetazol- 

amide). 
2-(2-Aminoethyl)-2-thiopseudourea dihydrobromide (AET)— ■ 

6-Aminohexanoic (Aminooaproic) acid 

Calcium camphosulfonate 

Cellulose, oxidized 

Dextran 

Digitoxin 

3,5-Dliodo-4-pyridone-N-aoetio acid, diethanolajnine salt 

( lodopyracet ) . 

Ethyl carbamate (Urethane) 

Ethylenediamine dihydriodide 

Ethyl nitrite 

Galactose 

Gitalin 

Glyceryl trinitrate 

Heparin, sodium 

17-}fydroxy-7a-meroapto-3-oxo-17a-pregn-4-ene-21-carbox- 

ylic acid, Y -lactone, 7-acetate (Spironolactone). 
2-Iodoethyl-l,3-dioxolane-4-methanol (lodinated glycerol 

lodomethanesulfonic acid (Methiodal), sodium salt 

Isosorbide dinitrate 

Magnesium citrate 

6-Mercaptopurine 

Mercury compounds : 

N-[3-(Carboxymethylthiomercuri)-2-methoxypropyl] -a- 
oamphoramic acid, disodium salt (Mercaptomerin, 
sodium). 

[ 3 - ( Chloromercur i ) -2 -methoxypropyl] urea ( Chlormero - 
drin) . 

N- [ 3 - ( ^droxymercuri ) -2 -me thoxypropyl] -a -c amphor ami c 
acid, sodium salt and theophylline (Mercurophylline, 
sodium). 

l-[3-(Hydroxymercuri) -2 -methoxypropyl] -3-succinylurea 
and theophylline (Meralluride ) . 

l-Methylimidazole-2-thiol (Methimazole ) 

Polyacrylic acid ( Polyearbophil ) 

Polyaorylic acid, calcium salt 

6-Propyl-2-thiouracil 

Sodium carboxymethylcellulose (medicinal grade) 

Sodium tartrate 

Sulfosuccinic acid, bis(2-ethylhexyl)ester, sodium salt 

(Dioctyl sodium sulfosuccinate). 

Terpinol hydrate 

Veratrum viride (Alltavervir) 



ACY. 

SBR. 

ACY. 

FIN, PYL. 

EKT. 

PHR. 

BUR. 

SDW. 

FMP. 

PYL, TOL. 
MAL. 
PFN. 
PEN. 
APD. 

ABB, RIK. 
SRL. 



SDW. 
APD. 
MAL. 
BUR. 

WYT. 



LKL. 
FIN. 

LKL. 

LIL. 
WLI. 
WLI. 
PYL. 
CBP. 
MAL. 
ACY. 

LEM, PEN. 
PEN, RIK. 



138 



SYNTHETIC ORGANIC CHEMICALS, 1964 



Flavor and Perfume Materials 



TABLE 14B. 



-Flavor and perfume materials for which U.S. production or sales were reported, identified by 
manufacturer , 1964 



[Flavor and perfume materials for which separate statistics are given in tatle 14A are marked below with an asterisk 
(»); those not so marked do not appear in table WA because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Manufacturers ' identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIALS, CYCLIC 

Benzenoid and ^aphthalenoid 

2'-Aoetonaphthone (Methyl P-naphthyl ketone) 

Acetophenone 

7-Acetyl-6-ethyl-l,l,4,4-tetramethyl-l,2,3,4-tetrahydro- 
naphthalene . 

p-Allylanlsole 

Allyl phenoxyacetate 

»4-Allylveratrole (Eugenyl methyl ether) 

p-tert-Amylcyclohexanone 

*Anethole (p-Propenylanisole) 

*p-Anisaldehyde (p-Methoxybenzaldehyde ) 

Anisole (Methyl phenyl ether) 

Anisyl acetate 

Anisyl alcohol 

^Benzophenone 

*Benzyl acetate 

*Benzyl alcohol 

Benzyl benzoate 

Benzyl butyrate 

^Benzyl cinnamate 

*Benzyl ether 

Benzyl formate 

Benzyl glyceryl acetal 

Benzylidene acetone 

Benzyl isoeugenyl ether 

Benzyl isopentyl ether 

Benzyl phenylacetate (Benzyl a-toluate) 

*Benzyl propionate 

^Benzyl salicylate 

a-Bromostyrene 

4- ' -tert-Butyl-2' , 6' -dimethyl -3 ' , 5 ' -dinitroaoetophenone 

(Musk ketone ). 
6-tert-Butyl-3-methyl-2,'i-dinitroanisole (Musk ambrette)-- 
p-tert-Butyl-a-methylhydroclnnamaldehyde (a-Methyl-p-(p- 

tert-butylphenyl )propionaldehyde ). 
5-tert-Butyl-l,2,3-trimethyl-4-,6-dlnitrobenzene (5-tert- 
Butyl-'t, 6-dlnitrohemimellitene ) . 

5-tert-Butyl-2,<i,6-trinitro-m-xylene (Musk xylol) 

Carvacrol (2-p-Cymenol ) 

*Cinnamaldehyde 

Cinnamlc acid 

Cinnamyl acetate 

*Cinnaiiiyl alcohol 

Cinnamyl anthranllate 

Cinnamyl cinnamate 

Cinnamyl formate 

Cinnamyl isovalerate 

Cinnamyl propionate 

trans -Decahydro-2-naphthol 

p,a-Dimethylbenzyl alcohol (p-Methylphenylmethylcarbinol)- 

*fa,a-Dimethylphenethyl acetate 

a,a-Dimethylphenethyl alcohol 

a,a-Dimethyl-3-phenyl-l-propanol 



GIV, 


TBK. 








GIV, 


TBK. 








GIV. 










GIV. 










GIV. 










FB, 


GIV, 


ICO, 


TBK. 




IFF. 










AHZ, 


GLD, 


HNW, 


HPC, 


UNG. 


GIV, 


ICO, 


OPC, 


TBK, 


UNG. 


GIV. 










GIV, 


TBK. 








GIV, 


TBK. 








G, GIV, ICO, NEO, TBK. 


GIV, 


OPC, 


RDA 


SHL, 


TBK, TNP 


BPC, 


GIV, 


OPC, 


SHL, 


TBK, TNP 


MON, 


TBK, 


TNP. 






FB, 


TBK. 








GIV, 


ICO, 


TBK 






OPC, 


SHL, 


TNP 






TBK. 










GIV. 










FB. 










GIV, 


TBK. 








GIV. 










MYW, 


TBK. 








FB, 


GIV, 


TBK. 






GIV, 


OPC, 


TBK, 


UNG. 




TBK. 










GIV. 










GIV. 










GIV, 


TBK 








GIV. 










GIV. 










GTV. 










FB, 


OPC, 


TBK. 






BPC 










FB, 


GIV, 


TBK. 






FB, 


GIV, 


NEO, 


TBK. 




FEL 


GIV, 


RT. 






TBK 










TBK 










TBK 










GIV 










IFF 










GIV 










GIV 


IFF 


RDA 


TBK. 




IFF 










IFF, 


TBK 









FLAVOR AND PERFUME MATERIALS 



139 



TABLE 14B.-Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer, 1964 --Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued 

Benzenoid and I^aphthalenoid- -Contliaied 

4-,6-Dinitro-l,l,3,3,5-pentamethyllndan 

Diphenylme thane 

l,3-Diphenyl-2-propanone (Dibenzyl ketone) 

6-Ethoxy-m-anol (Propenyl methylguaethol) 

2-Ethoxynaphthalene (Ethyl p-naphthyl ether) 

Ethyl anisate 

Ethyl anthranilate 

Ethyl benzoate 

Ethyl cinnamate 

Ethyl a,p-epoxy-p-niethyUiydrocinnamate 

2-Ethylhexyl salicylate 

Ethyl 3-phenylglycidate 

Ethylvanillin 

»Eugenol 

Eugenol acetate 

Geranyl benzoate 

Hexylcinnamaldehyde 

Ifydratropaldehyde (a-Phenylpropionaldehyde) 

I^dratropaldel^rde, dimethyl acetal 

Hy-drocinnamaldehyde (3-Phenylpropionaldehyde) 

Iftrdroxycitronellal methyl anthranilate 

2-Hydroxypropyl p-N, N-bis ( 2-hydroxypropyl) aminobenzoate 

Isobutyl cinnamate 

wisobutyl phenylacetate (Isobutyl a-toluate)-- 

»Isobutyl salicylate 

*Isoeugenol 

Isoeugenyl acetate 

*Isopentyl salicylate (Amy! salicylate) 

p-Isopropylbenzaldehyde ( Cumaldehyde ) 

p-Isopropylcyclohexanol 

p-Isopropyl-a-methylhydrocinnamaldehyde (Cyclamen 
aldehyde ) . 

p-Isopropyl-a-methylhydrooinnamyl alcohol 

Laevo carveol 

*4-' -Methoxyacetophenone 

2-Methoxynaphthalene (Methyl p-naphthyl ether) 

4-ta-Methoxyphenyl)butanone 

l-(p-Methoxyphenyl)-l-pentene-3-one 

"i'-Methylacetophenone (Methyl p-tolyl ketone) 

Methyl anisate 

p-Methylanisole (p-Cresyl methyl ether) 

«Methyl anthranilate 

Methyl benzoate 

a-Methylbenzyl acetate 

p-Methylbenzyl acetate 

*a-Methyloinnamaldehyde 

Methyl cinnamate 

4- Methyl-7-ethoxy coumarin 

p-Methyl hydratropic aldehyde 

Methyl N-methylanthranilate (Dimethyl anthranilate) 

Methyl phenylacetate (Methyl a-toluate) 

Methyl phenylcarbinol acetate 

*Methyl salicylate (Synthetic wintergreen oil) 

*a-Pentylcinnamaldehyde (a-Amylcinnamaldehyde) 

Phenethyl acetate 

Phenethyl alcohol 

Phenethyl formate 

*Phenethyl isobutyrate 

Phenethyl isovalerate 

Phenethyl methacrylate 

*Phenethyl phenylacetate (Phenethyl a-toluate) 

Phenethyl propionate 

Phenethyl salicylate 

2-Phenoxyethyl isobutyrate I tBK 

Phenylacetaldehyde (a-Tclualdehyde) | GIV, TBK. 



GIV. 

TBK. 

GIV. 

SHL. 

GIV, TBK. 

ICO. 

FB, PMT. 

TBK. 

GIV, TBK. 

GIV, TBK. 

FEL. 

GIV, TBK. 

MON, RDA. 

FB, GIV, ICO, LUE, NEO, PEN, RT, SHL, TBK, UNG, VLY. 

GIV. 

GIV. 

GIV, IFF, TBK. 

GIV, IFF. 

GIV, IFF. 

TBK. 

GIV. 

SHL. 

TBK. 

FB, GIV, MYW, TBK. 

FB, GIV, TBK. 

FB, GIV, NEO, SHL, TBK, VLY. 

TBK. 

FB, GIV, ICO, OPC, RDA, TBK, UNG. 

GIV. 

GIV. 

GIV, OPC, RDA. 

GIV. 

FB. 

GIV, ICO, OPC. 

GIV, TBK. 

TBK. 

GIV. 

TBK. 

ICO. 

GIV, TBK. 

DOW, FB, GIV, MEE, OPC, SHL, UNG. 

HN. 

GIV, TBK. 

ICO, IFF. 

FB, GIV, VLY. 

FB, ICO, TBK. 

GIV. 

GIV. 

GIV. 

GIV, TBK. 

VLY. 

CFC, DOW, HN, MON, x. 

FB, GIV, IFF, NEO, RDA, TBK, VLY. 

GIV, IFF. 

GIV, IFF, OPC. 

IFF. 

GIV, IFF, TBK. 

FB, GIV. 

IFF. 

GIV, IFF, TBK. 

IFF. 

IFF, TBK. 



140 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE UB. -Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer, 1964 — Continued 



FLAVOR AND PERFUME MATERIALS, nYCLIC— Continued 

Bemenoid and Naphthalenoid— Continued 

Phenylacetaldehyde, dimethyl aoetal 

Phenylacetaldehyde, ethylene acetal 

o-Phenylanlsole (2-Methoxybiphenyl) 

Phenylethyl tiglate 

*3-Phenyl-l-propanol (Hydrocinnamlc alcohol) 

3-Phenyl-l-propyl acetate 

5-Propenyl-2-ethoxyphenol (Propenylguaethol) 

M-Propenylveratrole (Isoeugenyl methyl ether) 

p-Propylanisole 

n-Propyl phenethyl acetal 

Styrolyl acetate 

l,2,3,6-Tetrahydro-2,3,5-trimethylbenzaldehyde 

p-Tolualdehyde (p-Methylbenzaldehyde) 

p-Tolyl acetate (p-Cresyl acetate) 

p-Tolyl isobutyrate (p-Cresyl isobutyrate) 

p-Tolyl phenylacetate (p-Cresyl a-toluate) 

a-(Trlchloromethyl)benzyl acetate (Rosetone) 

p-o,a-Trimethylphenethyl alcohol 

Trimethyltetrahydrobenzylidene acetone 

Vanillin 

All other 

Terpenoid, Heterocyclic, and Alicyclic 

Allyl cyclohexyl propionate 

Allyl lonone ■" 

An^rris acetate 

Bornyl acetate 

<V-tert-Butylcyclohexanol 

4-tert-Butylcyclohexyl acetate 

Cadinene 

Carvone (Carvol) 

Caryophyllene 

Cedranone 

Cedrenol 

Cedrol 

*Cedryl acetate 

»Cltral (Geranlal) 

Cltral dimethyl acetal 

Cltronellal 

*Citronellol 

*Citronellyl acetate 

Cltronellyl butyrate 

»Gitronellyl formate 

Cltronellyl Isobutyrate 

Cltronellyl oxyaoetaldehyde 

Cltronellyl propionate 

*Coumarin 

Cyclohexadecanollde 

Cyclohexylcyclohexanone 

Cyclopentanone 

Dihydrogeraniol 

Dlhydronordicyolopentadienyl acetate 

Dihydroterpinyl acetate 

^Essential oils, chemically modified: 

Cedarwood, terpeneless 

Cltronella oil, acetone condensation product 

Citronella oil, aoetylated 

Clove leaf oil terpenes 

Ethyl oxyhydrate 

Gualacwood acetate 

Hexene-2-al-l 

Lavandln, acetylated 

Oil clove stem, acetylated 

Sassafras oil, hydrogenated 

a- Furfural mercaptan 



Manufacturers ' identification codes 
(according to list in table 22) 



GIV, 


TBK. 


GIV. 




GIV. 




FB. 




FB, 


GIV, OPC, TBK 


GIV. 




ICO. 




GIV, 


ICO, TBK. 


GIV. 




GIV. 




FB. 




IFF. 




GIV, 


HN. 


GIV, 


IFF. 


IFF. 




GIV, 


TBK. 


GIV, 


ICO, TBK. 


IFF. 




TBK. 




MON, 


SLV. 


PFW. 





GIV. 










GIV, 


IFF. 








GIV, 


TBK. 








FEL. 










IFF. 










DOW, 


IFF. 








FB. 










FB, 


J-RM, 


OPC. 






FB, 


GIV. 








TBK. 










GIV. 










GIV, 


IFF 


NEO, 


TBK. 




GIV, 


IFF 


NEO, 


TBK 


UNG. 


FB, 


FEL, 


GIV, 


LUl, 


MYW, NEO, RT, TBK, UNG 


GIV. 










FB, 


GIV, 


IFF, 


TBK. 




FB, 


GIV, 


GLD, 


IFF, 


NEO, OPC, TBK, VLY. 


GIV, 


IFF 


TBK, 


VLY 




GIV. 










FB, 


GIV, 


IFF, 


TBK. 




GIV, 


IFF 


TBK 






IFF, 


TBK 








IFF. 










DOW, 


MON 


NEO 


RDA 


TBK. 


IFF. 










GIV. 










AEA 










ICO 










GIV 










GIV 










TBK 










CP. 










IFF 










SHL 










FEL 


FLO 


LUE 


RT, 


VND. 


FB, 


GIV, 


TBK. 






OPC 










FEL 


IFF 


, UNG 






FB. 










GIV 










RT. 











FLAVOR AND PERFUME MATERIALS 



141 



TABLE 14B. 



-Flavor and perfume materials for which U.S. production or sales were reported, identified by 
manufacturer, i 564 — Continued 



Manufactiirers ' identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued 
Terpenoid, Heterocyclic, and Alicyclic--Continiied 

*Cieraiiiol 

Geranoxy acetaldehyde 

«Geranyl acetate 

Geranyl butyrate 

»Geraiiyl formate 

Geranyl isobutyrate 

Geranyl isovalerate . 

Geranyl phenylaoetate (Geranyl a-toluate) 

2-Hexyl-2-cyolopenten-l-one 

»Hydrocoumarin (3,4-DihydroeoiimRrin) 

*I^droxycitronellal- 

li^droxycitronellal, dimethyl acetal 

4-(4-Iftrdroxy-4-methylpentyl)-3-eyclohexene-l-carboxalde 
hyde. 

Indole 

»Ionones : 

a-Ionone 

P-Ionone 

lonone (a- and p-) 

Isobomeol (Isobomyl alcohol) 

*Isobomyl acetate 

Isobutylquinoline 

Isomenthone 

Isopropylgiiinoline 

Isopulegol 

Is OS af role 

d-Hmonene 

Linalool 

*Linalyl acetate 

Linalyl anthranilate 

Linalyl cinnamate 

Linalyl isobutyrate 

Linalyl propionate 

»MBnthol, synthetic : 

Tech 

U.S.P 

*Menthone 

Menthyl acetate 

6-Methylcoumarin 

*Methylionones : 

<<Methyl-a-ionone 

*Methyl-P-ionone 

*lfethylionone (a- and fi-) 

*Methyl-Y-ionone 

«Jfethyl-5-ionone 

»Nerol 

Nopyl acetate 

Phellandrene 

»Piperonal (Heliotropin) 

Piperonal, sodium bisulfite complex 

Piperonal terpenes 

Pseudolinalyl acetate (J^cenyl acetate, principally) — 

»Ehodinol 

Rhodinyl acetate 

Rhodinyl formate 

Safrole 

Santalol 

Santalyl acetate 



FB, 
IFF. 
FEL, 
GIV. 
GIV, 
IFF. 
FB. 
GIV, 
IFF. 
GIV, 
GIV, 
GIV, 
IFF. 



GIV, 

MYW, 

GIV, 

RDA. 

FB, 

FMT, 

GIV, 

FMT. 

GIV. 

GIV. 

RT, 

FB, 

DOW, 

FW. 

TBK. 

GIV, 

GIV. 

GIV, 

GIV, 

GIV, 

FB, 

GIV. 

GIV, 

TBK. 

GIV, 

TBK. 

TBK. 

GLD, 

MYW, 

ICO. 

GIV, 

SHL. 

SHL. 

IFF. 

FB, 

GIV, 

GIV. 

GIV. 

GIV, 

GIV. 



FEL, GIV, GLD, IFF, MYW, NEO, TBK, UNG, VLY. 

GIV, IFF, NEO, TBK, UNG, VLY. 

TBK, VLY. 

TBK. 

ICO, OPC, TBK. 

GLD, IFF, OPC, TBK, VLY. 

TBK. 



IFF, MYW, TBK. 
NEO, TBK. 
LHE, MYW, TBK. 

GIV, OPC, RDA, TBK, UNG. 
IFF. 
TBK. 



FEL, GIV, GLD, HOF, LUE, NEO, SHL, TBK, UNG. 
FB, GIV, GLD, HOF, LUE, SHL, TBK, UNG. 



ICO, NEO. 
GLD, H^W, NEO. 
HNW, NEO. 
GIV. 



IFF, MYW, NEO. 

LUE, MYW, TBK, UNG, VLY. 



IFF, TBK, VLY. 
SHL, VLY. 



3, SHL, TBK. 



FEL, GIV, IFF, LUE, NEO, SHL, VLY. 
IFF. 



142 



SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 14B —Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer, 1964 — Continued 



FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued 

Terpenoid, Heterocyclic, and Alicyclic--CGntinue6 

^Sweeteners , synthetic : 

Cyclamic acid 

Cyclohexanesulfamic acid 

CyclohexanesuLfamic acid, calciimi salt 

Cyclohexanesulfamic acid, sodium salt 

Saccharin 

Saccharin, calcium salt 

Saccharin, sodium salt 

All other 

*Terpineols: 

ar-Terpineol 

p-Terpineol 

Terpineol (a- andg-) 

Terpinol hydrate (Terpin hydrate), tech 

■J^Terpinyl acetate 

Terpinyl propionate 

Tetrahydro alloocimenol 

3,5,5-Trimethylcyclohexanol 

Vertofix (Acetyl cedrene, principally) 

Vetivenol 

wVetivenyl acetate 

All other 

FLAVOR AND PERFUME MATERIALS, ACYCLIC 

Allyl heptanoate (Allyl enanthate) 

*Allyl hexanoate (Allyl caproate) 

Allyl isothiocyanate (Synthetic mustard oil) 

Allyl sulfide (Diallyl sulfide) 

Amyl propionate 

Butyl butyrate 

Butyl isovalerate 

Butyrone (Di-n-propyl ketone) 

Butyroyl butyl lactate 

*Decanal ( Capraldehyde ) (Cio) 

Diallyl disulfide 

Diethyl sebacate (Ethyl sebacate) 

Diethyl succinate 

Diethyl trideoanedioate (Ethylene brassylate) 

2,6-Dimethyl-5-hepten-l-al 

3,5-Dimethyl-3-octanol 

3,7-Dimetl:^l-l-octanol 

3,7-Diraethyl-3-octanol 

Dimethyl succinate 

*Ethyl butyrate 

Ethyl decanoate 

Etl^rlene brassylate 

Ethyl heptanoate (Ethyl enanthate) 

»Ethyl hexanoate (Ethyl caproate) 

Ethyl isovalerate 

Ethyl laurate 

Ethyl levulinate 

•»Ethyl nonanoate (Ethyl pelargonate) 

Ethyl octanoate (Ethyl caprylate) 

»GHutamic acid, monosodium salt (Monosodium glutamate)— 

Heptanal (Enanthaldehyde) (C7) 

Heptyl alcohol (Heptanol) 

Heptyl ether (Enanthic ether"! 

cis-3-Hexen-l-ol 

Hexyl octanoate (Hexyl caprylate) 

cis-3-Hexyn-l-ol 

3-Hydroxy-2-butanone (Acetoin) 



Manufacturers' identification codes 
(according to list in table 22) 



MRS. 

ABB. 

ABB, DRW, NRS, PBY, PFZ. 

ABB, NRS, PBY, PFZ, UNS. 

MEE, MON, NRS. 

MEE, MON, NRS, PBY. 

MEE, MON, NRS. 

VLY. 



GLD. HNW, HPC. 




HNW. 




GIV, NEO. 




HPC. 




GIV, HNW, OPC, RDA, 


TBK, UNG 


GIV, TBK. 




IFF. 




ICO. 




IFF. 




GIV, TBK. 




GIV, IFF, NEO, TBK, 


UNG. 


FB, OPC, TBK. 




DOW, TBK. 




DOW, FB, GIV, TBK, 


UNG. 


ICO, MRT. 




DOW, RT. 




GIV. 




TBK. 




TBK. 




TBK. 




ICO. 




GIV, IFF, OPC, TBK 




RT. 




FEL, TBK. 




UCC. 




RDA. 




GIV. 




AIR. 




GIV, TBK. 




GIV. 




ICO. 




FB, NW, RT, TBK. 




TBK. 




VLY. 




FEL, TBK. 




FB, NW, TBK. 




FB, TBK. 




FB. 




FMT. 




FB, FEL, TBK. 




FB. 




COM, GRW, HPC, DjIC 


, MRK. 


BAC. 




BAC, UCC. 




TBK. 





FLAVOR AND PERFUME MATERIALS 



143 



TABLE 14B. —Flavor and perfume materials for which U.S. production or sales were reported identified by 

manufacturer, 1964- - Continued 



FLAVOR AND PERFUME MATERIALS, ACYCLIC— Continued 

"i-Hydroxynonanoic acid, y-lactone (y-Nonalactone) 

4-Hydroxyoctanoio acid, y-lactone (Y-Octalaotone) 

*4-Hydroxyundecanoic acid, y-lactone (Y-Undeoalactone)- 

*Isopentyl butyrate (Amyl butyrate) 

Isopentyl formate (Amy! formate) 

Isopentyl geranate 

Isopentyl heptanoate (Amyl caproate) 

Isopentyl isovalerate (Amyl isovalerate) 

*Lauraldehyde (Dodeoyl aldehyde) (C12) 

6-Methyl-5-hepten-2-one 

Methyl isovalerate 

Methyl-P-methylthiopropionate 

Methyl-3-thiopropionaldehyde 

2-Methylundecanal (2-Methylnonylaoetaldehyde) 

IVJyristic aldehyde 

Nonanal (Pelargonaldehyde) (C9) 

Nonanediol monoacetate 

Nonanol 

Nonyl acetate 

Nonynol acetate, isomeric (Tepyl acetate) 

Ootanal ( Caprylaldehyde ) (Cg) 

n-Ootyl acetate 

n-Ootyl isobutyrate 

Omega decenol 

n-Propyl acetal 

d-Pulegone 

Tepyl acetate 

2,6,10-Triinethyl-9-undecen-l-ol 

Undecanal (Hendecanaldehyde) (Cn) 

2-Undecanone (Methyl nonyl ketone) 

Undecenal (Hendecenaldehyde) 

10-Undecen-l-ol 

Valerolactone 

All other 



Manufacturers ' identification codes 
(according to list in table 22) 



GIV 


TBK. 




GVl 


TBK 




FB, 


GIV, 


TBK. 


FB, 


GIV, 


ICO, NW, RT, TBK 


FEL 


TBK. 




FB. 






FEL 






FB, 


TBK. 




GIV 


IFF, 


TBK. 


GIV. 






FB. 






RT. 






RT. 






GIV, 


TBK. 




GIV. 






GIV, 


TBK. 




GIV. 






TBK. 






TBK. 






IFF. 






GIV, 


IFF, 


OPC, TBK. 


FB, 


TBK. 




FB, 


ICO. 




IFF. 






GIV. 






GIV. 






TBK. 






GIV. 






GIV, 


IFF, 


TBK. 


GIV. 






GIV, 


TBK. 




GIV. 






GIV. 






GIV, 


SHL. 





144 



SYNTHETIC ORGANIC CHEMICALS, 1964 



Plastics and Resin Materials 

TABLE 15B. — Plastics and resin materials for which U.S. production or sales were reported, identified by 

manufacturer , 1964 

[Plastics and resin materials for which separate statistics are given in table 15A are maxked below with an asterisk 
( «) ; chemicals not so marked do not appear in table 15A because the reported data are accepted in confidence and 
may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that 
the manufacturer did not consent to his identification with the designated product] 



Material and use 



Manufacturers ' identification codes 
(according to list in table 22) 



THEEMOSETTING RESINS 



»Alkyd resins : 

Protective coatings : 
»Phthalic anhydride type- 



*Polybasio acid type- 



*A11 other uses 

«Coumarone-indene and petroleum polymer resins ; 

*Floor tile 

*Eubber compounding 

*A11 other uses 

Epoxy resins : 

*lftraiodif led : 

■^Bonding and adheslves 

^Protective coatings 

*Reinforoed plastics 

»A11 other uses 

*MDdified 



*Polyester resins : 

Reinforced plastics : 
*Sheets, flat and corrvigated 

*A11 other 

»Surface coatings 

*A11 other uses 

^Silicone resins 

*Phenolic and other tar acid resins 
♦Molding materials 

Bonding and adhesive resins for-- 
♦Laminating 

♦Coated and bonded abrasives 

♦Friction materials 



AAI, ACP, ACY, ADM, AMF, APV, ARD, BAL, BEN, BOY, 
BRU, CGL, CIK, CM, COM, CPV, DAV, DBG, DSO, DUN, 
DUP, EW, FAR, FBR, FCD, FLW, FOC, FRE, FSH, GEI, 
GIL, GLD, GRV, HAN, HPC, HRS, ICF, JAM, JOB, JOD, 
JWL, KEL, KMC, KMP, KPS, KYN, LON, MCC, MID, MNP, 
MR, NCI, NPV, NTL, ORO, OSB, PER, PFP, PPG, PRT, 
RCI, RED, REL, RH, RMC, SCF, SCN, SED, SIP, SPP, 
SRR, SVC, SW, SYV, TV, VTV, WAS, WPC. 

ACP, AMF, APT, APV, ARD, BEN, CGL, CM, COM, CPV, DSO, 
DUN, DUP, EW, FAR, FBR, FCD, FLW, FOC, FSH, GEI, GLD, 
GRG, GRV, HPC, ICF, LON, MID, NCI, NON, NPV, ORO, 
OSB, PPG, PRT, RCI, RED, REL, RH, RMC, SHA, SPP, SRR, 
TV, VTV. 

ACP, ACY, AMR, CIK, DUP, FAR, FLW, GLD, HPC, JSC, KPS, 
MCC, MMM, MOB, NOP, ORO, PPG, QCP, RCI, RH, SIP, SNW. 

ACC, ACP, NEV, NSP, PAI, VEL. 

ACC, ACP, NEV, NSP, PAI, VEL, WTC. 

ACC, ACP, CM, DSO, DUP, ENJ, ICF, MCA, NEV, PAI, PPG, 
VEL, X. 



CBA, DOW, JOD, SHC, UCP. 

CBA, DOW, JOD, RCI, SHC, UCP. 

CBA, DOW, RCI, SHC, UCP. 

CBA, DOW, SHC, UCP. 

ACP, AMF, BEN, DSO, FMP, GLD, HAP, ICF, ISO, KPI, KPT, 

LEF, MID, MNP, MRB, NON, ORO, OSB, PPG, PYR, REZ, 

RMC, SPP, SRR, WAS. 



ACP, ACY, ADM, DA, EW, FRE, GLD, HKD, ICF, LAS, MFG, 

ORO, PPG, RCI, RH, SW, USR. 
AAI, ACP, ACY, ADM, APD, CAP, CPV, DA, DSO, FRE, GLD, 

GRV, HKD, ICF, IPC, KPS, LAS, MFG, MRO, PLU, PPG, 

RCI, SIC, SPP, SW, USR. 
ACP, ACY, APD, COM, CPV, DA, GLD, GYR, ICF, PPG, SW, 

USR. 
ACP, ACR, ACY, AMR, APD, DA, DAV, DSO, EKT, EPC, EW, 

FMP, FRE, GEI, GLD, GNT, GRG, GYR, HKD, HYC, LAS, MID, 

OCF, PLU, PPG, RCI, RH, SCN, SW, USR, UTR, VAL. 
ACP, BOR, DCC, GLD, SPD, UCS. 

ACP, BOR, DUH, FRL, GE, HER, HKD, HVG, IRC, MRB, PLS, 
RCI, RGC, SYR, UCP, VAR, VSV. 



ACP, AMR, BOR, CAT, CBR, CD, DRL, EW, FOM, GE, HKD, 
IRI, MCA, MON, NPI, NPP, NTC, NVF, PGU, PYZ, RCD, 
RCI, SCN, SPL, SYR, TAY, TKL, UCP, VAR. 

BME, BOR, CAT, CBM, CBR, HKD, MMM, MON, PYZ, SYR, UCP, 
VAR. 

ABS, BME, BOR, FRL, GE, HKD, MON, PYZ, RAB, SCN, SYR, 
SYV, UCP, VAR. 



I 



PLASTICS AND RESIN MATERIALS 



145 



TABLE 15B»- — Plastics and resin materials for which U.S. production or sales were reported, identified by 

manufacturer, 1964 — Continued 



Material and use 



Manufacturers' identification codes 
(according to list in table 22) 



THERMOSETTING RESINS— Continued 

»Phenolio and other tar acid resins — Continued 
Bonding and adhesive resins for — Continued 
^Thermal insulation 

♦Foundry or shell molding 

♦Plywood 

♦Fibrous and granulated wood 

*A11 other bonding and adhesive uses 

♦Protective coatings 

♦All other uses 

♦Polyurethane and diisocyanate resins 

♦Rosin modifications: 

♦Rosin and rosin esters, unmodified (ester gums) 

♦All other 

Styrene and aliyd polyesters 

♦Urea and melamine resins: 

♦Textile treating and coating resins 

♦Paper treating and coating resins 

Ifclding materials 

Bonding and adhesive resins for — 

♦Laminating 

♦Plywood 

♦Fibrous and granulated wood 

♦All other bonding and adhesive uses 

♦Protective coatings 

All other uses 

All other thermosetting resins 



THERMDPLASTIC RESINS 



Acrylic resins- 



♦Cellulose plastics materials: 
Sheets, continuous: 

♦Under 0.003 gage 

♦0.003 gage and over 

♦All other sheets, rods, and tubes - 

♦Molding and extrusion materials — 

♦Polyamide resins 



ACP, AMR, CAT, GE, HKD, ICF, MON, QCF, PYZ, RCI, SYV, 

UCP. 
ACP, ACR, ARM, BOR, GE, HKD, MON, PYZ, RCI, SCN, UCP, 

UNO, VAR, WOD. 
ACP, AMR, BGC, BOR, CAT, CBC, CBD, DA, MON, PGU, PYZ, 

RCI, RH, SIM, WCA, WRD. 
AMR, BOR, CBD, HKD, MCA, MON, PYZ, RCI, SIM, UCP. 
ACP, AMR, BME, BOR, CAT, GE, HKD, IRI, KPT, MON, MRB, 

NPI, PYZ, RPC, SCN, SHA, SNC, SPP, SYR, UCP, USR, 

VAR. 
ACP, ADM, AMF, AMR, CIK, CPV, DSO, EW, FCD, PRE, GE, 

GEI, GRG, GRV, HER, HKD, ICF, INL, KRM, MD, MON, 

NCI, ORO, OXR, PFP, PYZ, RCI, RH, RMC, SCN, SHA, SNC, 

SW, UCP, VAR, WAS. 
ACP, ACR, AMR, BOR, CAT, EW, FRL, GEI, HER, HKD, IOC, 

IRC, KND, MMM, MON, MRB, NPI, PLS, PYR, PYZ, RAB, 

RCI, REZ, RGC, RH, SCN, SNC, UCP, USR, VAR, VSV. 
ACB, ADM, APV, ARK, BFG, BKL, DUP, GPM, HOU, IPI, MCC, 

MID, NOP, NPV, PEL, PFP, QUN, RCI, SCN, SW, TRN, UPC. 

ADM, APV, CBY, DPP, FAR, FCD, FRP, HPC, KRM, MCC, RCI, 

RH, SRR. 
ADM, APV, CBY, CPT, DPP, FAR, FCD, FLW, FRP, HPC, JNS, 

KRM, MCC, RCI, SCF, SRR. 
ADM, DEG, FLW, RCI. 

ACY, APX, BRY, CAT, CIB, CKM, CRC, DAN, DEP, DUP, ECC, 
HNC, HRT, JSC, MON, MRA, ONX, PC, QCP, RCI, RH, RPC, 
RTX, S, SBC, SEY, SNW, SYN, TV, USO, VAL, WIC, x. 

ACY, AMR, BME, BOR, CBD, CBR, DEP, DUP, HPC, MMM, MON, 
RCI, RH, X. 

ACP, ACY, BOR, CAP, FMP, GDN, PMC. 

ACY, BOR, CAT, FOM, GE, MON, NPP, NTC, PGU, PPL, SAC. 
ACY, BGC, BOR, CAT, CBC, CBD, MON, NPI, NTC, PGU, RCI, 

RH, SAC, SIM, SOR, WRD. 
ACY, BGC, BOR, IPR, MON, NTC, PGU, RCI, SAC, SOR, SYV, 

UPL, WOD. 
ACP, ACY, AMR, BOR, GEO, MON, RCI, SWP, TXT, UNO. 
ACP, ACY, APV, CPV, DUP, FRP, GLD, GRV, JOD, KPS, MON, 

OXR, PPG, RCI, REL, RH, SW. 
ACP, ACY, AMR, BOR, CMP, DUP, EFH, FMP, GEO, GGY, HPC, 

HID, MMM, MON, RCI, RH, STC, SWR, VAL, VAR, WON. 
ACP, ACY, CEM, G, GGY, HPC, HVG, JNS, MON, SNW, SWR, 

UNO, WTC, X. 



AGO, ACY, CAT, CIB, CMG, DUP, FLH, GLC, GLX, HCO, JNS, 
JSC, PII, PPG, QUN, RCI, RH, RPC, SAR, SEY, USP, VAL, 
VPC, WIC. 



CEL, DOW, DUP, EKT. 

CEL, DOW, EKT, MON, MPP, NIX, PDJ, SPY. 

CEL, MPP, NIX, PDJ, R5B, SPY. 

CEL, DOW, EKT, MON, PMA, RPI, RSB. 

ALF, BCM, DUP, EMR, FG, GNM, HN, JNS, KRM, POL, SNWj 
SPN. 



146 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 15B. Plastics and resin materials for which U.S. production or sales were reported, identified by 

manufacturer , 1964 — Continued 



Material and use 



Manufacturers' identification codes 
(according to list in table 22) 



THERMOPLASTIC RESINS--Continued 

*Styrene type plastics materials: 

«Mblding 

*Textile and paper treating and coating 

♦Emulsion paint 

♦Extrusion 

*A11 other uses 

Vinyl resins: 
♦Polyvinyl acetate resins: 

♦Emulsion paint 

♦Adhesives 

♦Bonding and sizing 

♦All other uses 

♦Polyvinyl chloride and copolymer resins: 

♦Film, under 6 mils 

♦Sheet, 6 mils and over 

♦Flooring 

♦Paper and textile coating 

Extrusion: 
♦Wire and cable 

♦Garden hose 

♦All other extrusions 

Molding : 
♦Records 

♦Slush and rotational molding 

♦All other moldings 

♦All other uses 

♦All other vinyl resins 

Polyolefin plastics materials: 
♦Polyethylene, density 0.940 and below: 

♦Injection molding 

♦Blow molding 

Extrusions: 
♦Film and sheet 

♦Wire and cable coating 

♦Extrusion coating on paper and other substrates- 



BFG, BKC, BPL, CSD, DOW, FBF, FG, FIR, GOR, GRP, GYR, 
KPP, MON, MPL, PLA, RCC, SHC, SOL, TIC, UCP, USR, x. 

BOR, DOW, FIR, FLH, GNT, GYR, ILC, KPP, MON, MET, USR, 
WAS, WIC. 

BOR, DOW, FIR, GLD, GNT, GYR, KPP, MON, USR. 

BFG, BKC, CSD, DOW, FIR, GRP, KPP, MON, PMA, RCC, UCP, 
USR, X. 

ACC, ARD, BCN, BFG, BOR, CSD, DOW, DSO, DUP, FIR, GNT, 
GRD, GRP, GYR, ICG, JNS, KPP, MON, MRT, ONX, PAI, 
POL, PVI, RCC, RH, SEK, SHC, SPI, UBS, UCP, UNC, USR, 
WAS, WIC, X. 



ACP, AIR, AML, APV, BAL, BEN, BOR, CEL, DAV, DSO, DUP, 
FAR, FLH, GLD, GRD, HAN, JOD, KMC, KMP, MCC, MR, NPV, 
NSC, PPG, RCI, REL, SED, SPC, SRC, SW, UCP, WAS, WIC. 

ACP, AIR, BAL, BOR, CEL, DUP, FC, FLH, GLC, GRD, HNC, 
MRN, NSC, NTC, PII, RCI, SH, SRC, SYR, UCP, WIC. 

AIR, AML, CAT, CEL, GST, DUP, GLC, GRD, PII, QCP, RFC, 
SEY, SRC, WIC. 

AML, BAL, BLS, BOH, CEL, DAN, DUP, FC, GRD, HET, JNT, 
JSC, NEP, NSC, OCF, HPC, SCO, SED, SRC, UCP, WIC. 

ATU, BFG, BOR, CRY, DOW, ESC, FCP, FIR, GNT, GYR, MON, 

PNT, THC, UCP. 
ATU, BFG, BOR, CHY, DA, DOW, ESC, FCP, FIR, GNT, GYR, 

MON, PNT, THC, UCP, USR. 
AME, BFG, BOR, CRY, CUC, DA, ESC, FCP, FIR, GNT, GYR, 

KYS, MON, THC, UCP, USR. 
ATU, BFG, BOR, CRY, DA, DOW, ESC, FCP, MON, ONX, PNT, 

UCP, USR. 

BFG, BOR, CRY, DA, DOW, ESC, FIR, MON, PNT, THC, UCP, 

USR. 
ATU, BFG, BOR, CRY, DA, DOW, ESC, FIR, MON, THC. 
BFG, BOR, CRY, DA, DOW, ESC, FCP, FIR, GNT, GYR, LAS, 

MON, THC, UCP, USR. 

BFG, BOR, CRY, CUC, DA, ESC, KYS, MON, PNT, THC, UCP, 

USR. 

BFG, BOR, CRY, DA, ESC, FIR, MON, UCP, USR. 

ATU, BFG, BOR, CRY, DA, DOW, ESC, GYR, MON, UCP. 

ATU, BFG, BOR, CBR, CRY, CUC, DA, DOW, ESC, FCP, FIR, 

GNT, GRA, GYR, MON, PNT, PYR, UCP, USR. 

ADM, AIR, BOR, BOY, DOW, DSO, DUP, FC, G, JOD, MCC, 

NSC, SNW, SRC, SW, UCP. 



CEL, DOW, DUP, EKX, ENJ, GRP, KPP, MON, PLC, RCC, SHC, 

SPN, UCP, USI. 
CEL, DOW, DUP, EKX, GRP, KPP, MON, PLC, RCC, SHC, SPN, 

UCP, USI. 

CEL, DOW, DUP, EKX, ENJ, GRP, KPP, MON, PLC, RCC, SHC, 

SPN, UCP, USI, X. 
CEL, DOW, DUP, EKX, GRP, KPP, MON, PLC, SHC, SPN, UCP, 

USI. 
CEL, DOW, DUP, EKX, GRP, KPP, MON, PLC, RCC, SHC, SPN, 

UCP, USI. 



PLASTICS AND RESIN MATERIALS 



147 



TABLE 15B. — Plastics and resin materials for which U.S. production or sales were reported, identified by 

manufacturer, ^964 — Continued 



Material and use 



Manufacturers' identification codes 
(according to list in table 22) 



THERMOPLASTIC RESINS— Continued 

Polyolefin plastics materials — Continued 
^Polyethylene, density 0.94-0 and below — Continued 
Extrusions — Continued 
»Plpe 

*A11 other extrusions 

*A11 other uses 

*Polyethylene, density over 0.940: 

*Injeotion molding 

»Blow molding 

Extrusions: 
*Film and sheet 

*Wire and cable coating 

*Pipe 

*A11 other extrusions 

*A11 other uses 

^Polypropylene : 

^Molding 

^Extrusion 

*A11 other uses 

All other thermoplastic resins 



CEL, DOW, DUP, EKX, GRP, KPP, 

USI. 
DOW, DUP, EKX, GRP, KPP, PLC, 
ACP, CEL, DOW, DUP, EKX, ENJ, 

SHC, SPN, UCP, USI. 

CEL, DOW, DUP, EKX, GRP, HPC, 

USI. 
CEL, DOW, DUP, EKX, GGC, GRP, 

UCP, USI. 

CEL, DOW, DUP, EKX, GGC, GRP, 

USI. 

CEL, DUP, EKX, GGC, GRP, HPC, 

ACP, CEL, DUP, EKX, GGC, GRP, 

CEL, DOW, DUP, EKX, GGC, GRP, 

USI. 

ACP, CEL, DOW, DUP, EKX, GGC, 

RCC, UCP, USI. 

AVS, DOW, EKX, ENJ, GRP, HPC, 
SPN, UCP, USI. 

AVS, EKX, ENJ, GRP, HPC, ORO, 

AVS, DOW, EKX, ENJ, GRP, HPC, 
USI, X. 

ACG, AGO, ACP, ACY, CAT, CBY, 
FLH, GE, GLC, GLX, HCO, JNS, 
PAI, PII, PPG, QUN, RCI, RH, 
SNW, USP, VAL, VPC, WIC. 



UCP. 
GRP, 



KPP, 
HPC, 



PLC, SHC, SPN, UCP, 

KPP, MON, PLC, RCC, 

PLC, RCC, SHC, UCP, 

KPP, MON, PLC, SHC, 



HPC, KPP, PLC, SHC, UCP, 



PLC, 


UCP, 


USI. 






HPC, 


KPP, 


PLC, 


SHC, 


UCP. 


HPC, 


KPP, 


PLC, 


SHC, 


UCP, 


GRP, 


HPC, 


KPP, 


MON, 


PLC, 


NVT, 


ORO, 


PLC, 


RCC, 


SHC, 


PLC, 


SHC, 


UCP, 


USI, 


X. 


ORO, 


PLC, 


RCC, 


SHC, 


UCP, 


CIB, 


CMG, 


DEP, 


DUP, 


ECC, 


JSC 


, KRK 


MCC 


, MMM 


, MOB 


RFC 


, SAR 


SBC 


, SCN 


SEZ 



148 



SYNTHETIC ORGANIC CHEMICALS, 1964 



Rubber- Processing Chemicals 

TABLE 16B. — Rubber-processing chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1964 

Rubber-processing chendoals for which separate statistics are given in table 16A are marked below with an asterisk 
(*); chendoals not so marlr.d io not appear in table 16A because the reported data are accepted in confidence and 
may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that 
the manufacturer did not consent to his identification with the designated product] 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



RUBBER-PROCESSING CHMECALS, CYCLIC 

^Accelerators : 
«Aldehyde- amines : 

Acetaldehyde-aniline 

n-Butyraldehyde-aniline 

Butyraldehyde-butylidene-aniline 

<i,4'-Dithiodimorpholine 

a-Ethyl-P-propylacrylanilide 

Heptaldehyde- aniline 

Triethyltrime thy lenetri amine 

p-Benzoquinone dioxime 

Dibenzoyl-p-quinonedioxime 

Dibenzylamine 

Di-N-pentamethylenethiuram tetrasulfide 

*Dithiocarbamlc acid derivatives : 

Dibenzyldithiocarbamio acid, sodium salt 

Dibenzyldithiooarbamio acid, zinc salt 

Dibutyldithiooarbamic acid, N, N-dimethylcyclohexyl- 
amine salt. 

Dibutyldithiocarbamlo acid, diphenylguanidine salt 

Dimethylethylene diphenyldithiooarbamic acid, lead salt 

2,'i-Dinitrophenyl dlmethyldithiocarbamate 

Piperidinecarbodithioie acid, piperidinium-potassium 
salts . 
Guanidines : 

Dicatechol borate, di-o-tolylguanidine salt 

Diphenylguanidine 

Diphenylguanidine phthalate 

Di-o-tolylguanidine 

1,2,3-Triphenylguanidine 

2-Imidazoline-2-thlol 

Poly-p-dinitrosobenzene 

»Thiazole derivatives : 

2-Benzothiazyl N, N-diethylthiooarbamoyl sulfide 

l,3-Bis(2-benzothiazolylmercaptomethyl)urea 

N-tert-Butyl-2-benzothiazolesulfenamide 

*N-Cyclohexyl-2-benzothiazolesulfenamide 

N, N-Diisopropyl-2-benzothiazolesulfenamlde 

N-(2,6-Dimethylmorpholino)-2-benzothiazolesulfenamide — 

*2,2'-Dithiobis(benzothiazole) 

*2-Msrcaptobenzothiazole 

2-lfcrcaptobenzothiazole, sodium salt 

2-lfercaptobenzothiazole, zinc chloride 

2-Meroaptobenzothiazole, zinc salt 

4-te)rpholinyl-2-benzothiazyl disulfide 

N-Oxydiethylene-2-benzothiazolesulfenamide 

Thiazoline-2-thiol 

All other cyclic accelerators 

Antioxidants : 

Aldehyde- and acetone-amines: 

Acetaldehyde-aniline hydrochloride 

Aldol-a-naphthylamine condensate 

Diphenylamine-aoetone 

Hienyl-2-naphthylamine-aoetone 



USE. 








DUP, 


USR. 






MON. 








MON. 








ceo. 








USR. 








USR. 








CTA, 


DUP. 






OTA, 


USR. 






MLS, 


USR. 






DUP, 


TOC. 






USR. 








USR. 








MON. 








ceo. 








COO. 








USR. 








DUP. 








DUP. 








ACY. 








MON. 








ACY, 


DUP. 






NAC. 








DUP, 


RBC. 






DUP. 








PAS. 








MON. 








MON. 








ACY, 


BFG, 


MON, 


USR. 


ACY. 








MON. 








ACY, 


BFG, 


GYR, 


MON, USR 


ACY, 


BFG, 


GYR, 


MON, USR 


ACY, 


GYR, 


MON. 




DUP. 








ACY, 


GYR, 


USR. 




GYR. 








ACY, 


MON. 






ACY. 








DUP, 


VNC. 






USR. 








BFG, 


CLY. 






ACY, 


BFG, 


USR. 




USR. 









RUBBER-PROCESSING CHEMICALS 



149 



TABLE 16B. -- Rubber-processing chemicals for which U.S. production or sales were reported, identified by 

manufacturer , 1964 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



RUBBER- PROCESSING CHEMICALS, Of CLIC— Continued 

Antioxidants — Continued 
*Amino and hydroxy compounds ; 
*Amino compounds : 

p-Anilinophenol 

N-sec-Butyl-N' -phenyl -p-phenylenediamine 

N-Butyroyl-p-aminophenol 

N-Qyolohexyl-N'-phenyl-p-phenylenediamine 

Dlarylaiylene diamines, mixed 

N, N '-Di( l-ethyl-3-methylpentyl) -p-phenylenediamine 

l,2-Dihydro-6-dodeoyl-2,2,'4-trimethylquinoline 

l,2-Dihydro-6-ethoxy-2,2,<»-trimetliylqulnoline 

l,2-Dihydro-2,2,4-trimethylquinoline 

PjP'-Diiiethoxydiphenylamine 

N, N'-Di(l-me thy Iheptyl) -p-phenylenediamine 

N,N'-Di-2-naphthyl-p-phenylenediamine 

A, A' -Diocty Idiphenylami ne 

N,N'-Di-2-octyl-p-phenylenediamine 

N,N'-Diphenylethylenediamine 

*N,N'-Diphenyl-p-phenylenediamine 

N, N'-Diphenyl-l,3-propanediamine 

N,N'-Dl-o-tolylethylenediamine 

p-Isopropoxydiphenylamine 

N-Isopropyl-N'-phenyl-p-phenylenediamine 

4,4'-Methylenedianiline 

N-(l-Methylheptyl)-N '-phenyl-p-phenylenediamine 

Ootyldiphenylamine 

Ootyldiphenylamine mixture (mono-, nonyl-, and di-) — - 

N-Hienyl-1-naphthylamine 

N-Hienyl-2-naphthylamine 

p-(p-Toluenesulfonamido)diphenylamine 

All other amino antioxidants 

*Hydroxy compounds : 

p-Benzyloxyphenol 

4,4'-Butylidenehis(6-tert-butyl-m-cresol) 

2,5-Di(l, l-dimethylpropyl)hydroquinone 

N-Lauroyl-p-aminophenol 

2,2'-Methylenebis(6-tert-butyl-p-cresol) 

2,2'-Methylenebis(6-tert-butyl-4--ethylphenol) 

2,2'-Methylenebis(6-tert-octyl-p-cresol) 

»Phenol, allsylated 

Phenol, hindered 

Phenol, styrenated 

Polyphenolic phosphite, polyaliylated 

N-Stearoyl-p-aminophenol 

A, A' -Thiobis(6-tert-butyl-m-oresol) 

2,2'-Thiobis(4,6-di-sec-amylphenol) 

l,l,3-Tri(2-methyl-4— hydroxy-5-tert-butylphenyl)butane 
Blowing agents : 

N,N'-Dimethyl-N, N'-dinitrosoterephthalamide 

DinitroEopentamethylenetetramine 

p,p' -Oxybis(benzenesuli'onhydrazide) 

Inhibitors, modifiers, and stabilizers: 

Alkylated o-oresol 

Dioresyl disulfide 

Nj't-Dinitroso-N-methylaniline 

*N-Nitrosodiphenylamine 

Nonylphenylphosphites, mixed 



BFG. 








USE. 








MLS. 








USE. 








GYR. 








EKT, 


MON, 


UPM. 




MON. 








MON. 








BFG, 


MON. 






DUP. 








EKT, 


MON, 


UPM. 




BFG. 








BFG. 








BFG. 








ceo. 


NOP, 


X. 




BFG, 


DUP, 


USR. 




ceo. 








ceo. 








BFG. 








MON, 


USR. 






USR. 








UPM. 








ACY, 


PAS, 


USR. 




BFG. 








DUP. 








BFG, 


DUP. 






USR. 








EKT, 


NOP, 


X. 




BFG. 








M3N. 








M3N. 








MLS. 








ACY, 


CAT. 






ACY. 








ACY. 








ACY, 


BFG, 


eeO, GYR, PAS, 


PIT, USR 


DUP, 


GYR, 


PIT. 




BFG, 


GYR. 






BFG. 








MLS. 








MON. 








MON. 








ICI. 








DUP. 








DUP, 


NPI. 






USR. 








PIT. 








USR. 








CTA, 


MON. 






BFG, 


CTA, 


GYR, USR. 




USR. 









150 



TABLE 16B. 



SYNTHETIC ORGANIC CHEMICALS, 1964 

-Rubber -processing chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 964 --Continued 



RUBBER-PROCESSING CHEMCAIS, CYCLIC— Continued 



^Peptizers: 

Aryl mercaptans 

Z-Benzamidothlophene, zinc salt 

2' 2 ' ' '-Dithlo'bis(tienzaiiilide) 

Dlxylyl disulfides, mixed 

2 -Naphthalene thiol 

Pentachlorobenzenethiol 

Pentaohlorobenzenethiol, zinc salt — 

Thlocresol 

Thiophenol 

Xylenethiol 

Tackifiers: p-tert-Amylphenol sulflde- 



RUBBER-PROCESSING CHHECAIS, ACYCLIC 



^Accelerators : 

n-Butyraldehyde-butylamlne 

Di-n-butylammonium oleate 

*Dithiocarhamic acid derivatives: 

Dibutyldithiocarbamio acid, potassium salt 

*Dibutyldithiooarhainic acid, sodium salt 

■x-Dibutyldithiocarbamic acid, zinc salt 

Diethyldithiocarbamic acid, cadmium salt and 
bis(dlethylthiocarbamoyl) disulfide mixture. 

Diethyldithiocarbamic acid, selenium salt 

Diethyldithiocarbamic acid, sodium salt 

Diethyldithiocarbamic acid, tellurium salt 

♦Diethyldithiocarbamic acid, zinc salt 

Dimethyldithiocarbamic acid, bismuth salt 

Dimethyldithiocarbamic acid, copper salt 

Dimethyldithiocarbamic acid, lead salt 

♦Dimethyldithiocarbamic acid, potassium salt 

Dimethyldithiocarbamic acid, selenium salt 

♦Dimethyldithiocarbamic acid, sodium salt 

Dimethyldithiocarbamic acid, sodium salt and, sodium 
polysuLf ide . 

♦Dimethyldithiocarbamic acid, zinc salt 

All other 

♦Thiurams : 

Bis(dibutylthiocarbamoyl) sulfide 

Bis(diethylthiocarbamoyl) disulfide-- 

♦Bis(dimethylthiocarbamoyl) disulfide 

♦Bis (dime thy Ithiocarbamoyl) sulfide 

BisCethylJuethylthioearbamoyl) sulfide 

Thiuram blend 

Xanthates and sulfides: 

Di-n-butylxantho disulfide 

Di-isopropylxantho disulfide 

Zinc dibutylxanthate 

All other acyclic accelerators: 

3-Ethyl-l,l-dimethyl-2-thiourea 

Ethylenediamine carbamate ■ 

Polyoxyaliylene tetrasulfide 

l,l,3-Trimethyl-2-thiourea 

Blowing agents: 

Urea-biuret mixture 

All other blowing agents 



Manufacturers' identification codes 
(according to list in table 22) 



PIT. 

ACY. 

ACY. 

DUP, PIT. 

DUP. 

DUP. 

DUP. 

PIT. 

PIT. 

DUP. 

PAS. 



DUP. 
DUP. 



VWG. 
DUP, 
ALC, 
VNC. 



PAS, USR, VNC. 

DUP, GYR, PAS, RBC, USR, VNC. 



PAS. 

GYR, RBC, USR, VNC. 



VNC. 

ALC, 

VNC. 

ALC, 

VNC. 

VNC. 

VNC. 

GYR, PAS, USR. 

VNC. 

ALC, 

BFG, 



ALC, 
PAS. 

USR. 
DUP, 
BFG, 
DUP, 
VNC. 
DUP, 

USR. 
BFG. 
USR. 

VNC, 
DUP. 
TKL. 
VNC. 

sw. 

DUP. 



BFG, DUP, GYR, PAS, USR. 
GNT. 

DUP, FMN, GYR, PAS, RBC, USR, WRC. 



GYR, PAS. 

DUP, GNT, GYR, PAS, RBC, USR, VNC. 

GYR, USR. 



RUBBER-PROCESSING CHEMICALS 



151 



TABLE 16B.- 



■ Rubber -processing chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



RUBBER- PROCESSING CHMICALS, ACYCLIC- -Continued 

Conditioning and lubricating agents : 

Ifethyl stearyl-10-sulfonio acid, sodium salt 

ttono- and diaUsyl acid phosphates, mixed 

Ifono- and dialkyl phosphate ammonium salts, mixed 

Peptizers and modifiers : 

Alkyl mercaptans, mixed 

»Dodecyl mercaptans 

Tetradecyl mercaptan 

Zinc laurate 

All other 



DUP. 
DUP. 
DUP. 

PAS, PLC. 

HK, PAS, PLC. 

PAS. 

USE. 

ACY, TKL, USR. 



152 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 17B. 



Elastomers (Synthetic Rubbers) 

-Elastomers (synthetic rubbers) for which U.S. production or sales were reported, identified by 
manufacturer, 1964 



[Elastomers (synthetic rubbers) for which separate statistics are given in table 17A are marked below with an as- 
terisk (*); products not so marked do not appear in table 17A because the reported data are accepted in confidence 
and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies 
that the manufacturer did not consent to his identification with the designated product] 



Product 


Manufacturers ' identification codes 
(according to list in table 22) 


ELASTOMEES, CYCLIC 


ASY, BFG, CPY, FIR, FHS, GGC, GNT, GYR, ILC, MCB, 

PLC, RUB, SEP, SHC, TOS, URC, USR, WIG. 
BFG, FIR, FRS, GNT, GYR, PLC, USR. 
ACY, BFG, DUP, GNT, MDB, ORU, PRC, TKL, USR. 






ELASTOMERS, ACYCLIC 










»Polybutadiene-aorylonitrile type (N-type) 


BFG, FRS, GYR, ILC, USR, WIC. 

DUP. 

CBN, EN J. 

GYR, HPC. 

DCC, SPD, UCS. 

ASY, DUP, ENJ, FRS, GGC, GNT, GYR, PLC, SHC, TUS. 

DUP, ENJ, X. 




Reaction products of natural rubber 

^-Silicone elastomers 







PLASTICIZERS 



153 



Plasticizers 



TABLE 18B.— Plasticizers for which U.S. production or sales were reported, identified by 

manufacturer, 1964 

[Plasticizers for which separate statistics are given in table ISA are marked below with an asterisk (»); products 
not so marked do not appear in table 18A because the reported data are accepted in confidence and may not be pub- 
lished. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manu- 
facturer did not consent to his identification with the designated product] 



PLASTICIZEHS, CYCLIC 



Coumarone-indene plasticizer 

N-Cyclohexyl-p-toluenesulfonamide-- 

Diethylene glycol dibenzoate 

Di-tert-octylphenyl ether 

Diphenyl cyclohexane, o-, m-, p- -- 

Dipropanediol dibenzoate 

N-Ethyl-p-toluenesulfonamide 

Isopropylidenediphenoxypropanol 

Naphthalene, alkylated 

Phosphoric acid esters: 

*Cresyl diphenyl phosphate 

Dibutyl phenyl phosphate 

Diphenyl mono-o-xenyl phosphate — 

Diphenyl octyl phosphate 

tfethyl diphenyl phosphate 

*Tricresyl phosphate 

*Triphenyl phosphate 

All other phosphoric acid esters- 
»Phthallc anhydride esters: 

Alkyl benzyl phthalates 

Butyl benzyl phthalate 

Butyl cyclohexyl phthalate 

Butyl deoyl phthalate 

Butyl 2-ethyl hexyl phthalate 

n-Butyl isodecyl phthalate 

»Batyl octyl phthalate 

Butyl phthalyl butyl glycolate 

Di(2-butoxyethyl) phthalate 

*Dibutyl phthalate 



Dioarbitol phthalate 

*Dlcyolohexyl phthalate 

Diethylene glycol phthalate- 
*Diethyl phthalate 

*Dlhexyl phthalate 

Diisobutyl phthalate 

*Diisodeoyl phthalate 



*Di(2-methoxyethyl) phthalate-- 
Dimethyl cyclohexyl phthalate- 

Dimethyl Isophthalate 

*Dlmethyl phthalate 

Dinonyl phthalate 

*Dioctyl phthalates: 

Dioapryl phthalate 

Di ( ethylhexyl ) Isophthalate - - 
»Di(2-ethylhexyl) phthalate— 



*Diiso-octyl and mixed dioctyl phthalates- 



Manuf acturers ' identification codes 
(according to list in table 22) 



Di-n-ootyl phthalate 

All other dioctyl phthalates 

Diphenyl isophthalate 

Diphenyl phthalate 

*Ditridecyl phthalate 

2-(Ethyl hexyl) isodecyl phthalate 

Ethyl (and methyl) phthalyl ethyl glycolate 

Glycol phthalate fatty acid esters 

Glycol phthalic esters 

Hexyl isodecyl phthalate 

Hexyl Iso-octyl phthalate 

Hydrogenated castor oil phthalate I DUP, 

Octyl deoyl fatty acid phthalates | PFZ. 



NEV. 
MON. 
TNP. 
DOW. 
MON. 
TNP. 
MON. 
DOW. 
ACC. 

CEL, FMP, MON, MTR, SF, SPP. 

MON. 

DOW. 

MON. 

FMP, MON. 

CEL, FMP,. FRO, MON, MTR, SF. 

CEL, DOW, EK, MON, SF. 

SF. 

MON. 

GRH, MON. 

ACP. 

ACP, PCC. 

ACP, MON, PFZ, UCC. 

GRH, PCC, THC. 

GRH, PCC, RCI, RUB. 

MON. 

FMP, GRH, KES, WM. 

ACP, AIR, COM, DUP, EKT, GED, GRH, HAL, LAS, MON, PCC, 

PFZ, RCI, RUB, SW, WTH, UCC. 
FMP. 

ACP, DUP, FMP, MON, PFZ. 
ARK. 

DUP, EKT, KF, MON, PFZ. 
ACP, CCA, ENJ, GRH. 
EKT, MON. 
ACP, BFG, EKT, ENJ, GRH, LEH, MON, PCC, PFZ, RCI, RUB, 

THC, UCC, WTH. 
CEL, DUP, EKT, FMP, RCI, SF. 
DUP. 
PFZ. 

ACP, EKT, FRO, KF, MON. 
RCI. 

GRH, WTH. 

UCC. 

ACP, BFG, EKT, ENJ, GRH, MON, PCC, PFZ, RCI, RUB, SH, 

THC, UCC, WTH. 
ACP, BFG, EKT, ENJ, GRH, LEH, MON, PCC, PFZ, RCI, RUB, 

THC, UCC. 
ADM. 

EKT, THC. 
BJL. 
MON. 



ACP, ENJ, GRH, MON, PCC, PFZ, RCI, RUB, THC, UCC. 

UCC. 

MON. 

HPC. 

ARG, UCC. 

PFZ. 

PFZ. 



154 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 18B. — Plasticizers for which U.S. production or sales were reported, identified by 
manufacturer , 1964 — Continued 



Manufacturers' Identification codes 
(according to list in table 22) 



PLASTICIZERS, CYCLIC— Continued 

*Phthalic anhydride esters — Continued 
*Octyl deoyl phthalates: 

Iso-octyl isodecyl phthalate 

n-Octyl n-decyl phthalate 

All other phthalic anhydride esters 

Polyethylene glycol dibenzoate 

Tetrahydrofurfuryl oleate 

Toluenesulfonamide, o-, p- mixtures 

Triethylene glycol dibenzoate 

»Trimellitic acid esters 

All other cyclic plasticizers 

PLASTICIZERS, ACYCLIC 

»Adipio acid esters: 

*Di(2-(2-butoxyethoxy)ethyl) adipate 

*Di(2-et±iylhexyl) adipate 

»Dlisobutyl adipate 

*Diisodeoyl adipate 

*Diiso-octyl adipate 

Iso-octyl isodecyl adipate 

*Octyl decyl adipate 

All other adipic acid esters 

*Azelaic acid esters: 

Di(2-ethylhexyl) azelate 

Dllsobutyl azelate 

Diiso-octyl azelate 

All other azelaic acid esters 

Citric and acetylcitrio acid esters 

«Complex linear polyesters and polymeric plasticizers- 

Di(2-(2-buto}(yethoxy)ethyl)me thane 

Diethylene glycol dinonanoate 

Diiso-octyl diglycolate 

*Epoxidized esters: 

Butyl epoxytallate 

*Epoxidized soya oils 

2-Ethylhexyl epoxytallates 

Ootyl epoxystearates 

*Octyl epoxytallates 

All other epoxidized esters 

Glycerol pelargonate 

Glyceryl tributyrate and tripropionate 

Glycol pelargonate 

Isodecyl nonanoate (Isodecyl pelargonate) 

Laurie acid esters 

J/(yristic acid esters: 

Butyl myristate 

*Isopropyl myristate 

*01eic acid esters: 

*Butyl oleate 

*Glycerol trioleate (triolein) 

*Isopropyl oleate 

»Methyl oleate 

»n- Propyl oleate 

*A11 other oleic acid esters 

Palmitic acid esters: 

*Isopropyl palmitate 

All other palmitic acid esters 

♦Phosphoric acid esters: 

Tri(2-butoxyethyl) phosphate 

Triethyl phosphate 

Triootyl phosphate 

All other phosphoric acid esters 



ACP, PCC, PFZ. 

ACP, GRH, HPC, MON, PCC, PFZ, RCI, RUB, THC, UCC. 

ERG, MP, PCC, PFZ, UCC. 

TNP. 

CCW, EMR. 

ACY, MON. 

TNP. 

ACC, PCC, PFZ, RUB. 

CCW, EKT, WTH. 



CCW, EUP, GRH, PCC, TKL. 

EKT, HAL, MON, PCC, PFZ, RCI, RUB, THC, UCC, WTH. 

FMP, GRH, HAL, PCC, RCI, WTH. 

ACP, EKT, GRH, LEH, MON, PCC, PFZ, RCI, RH, RUB, THC, 

UCC. 

GRH, HAL, LEH, PCC, RCI, RH, RUB. 

BFG, GRH, MON, PCC, RCI. 

ACP, GRH, LEH, PCC, RCI, RUB, THC, TKL, UCC. 

ACP, EKX, KES, LEH, PCC, PFZ, THC. 

DUP, EKT, EMR, PFZ, RCI, RUB, UCC. 

HAL, RCI. 

EMR, MON. 

ACP, EMR, 
PFZ. 

ADM, EKT, 
WM, WTC 
GRD. 

EMR, RUB. 

CCA, FMP. 



LEH, PFZ, UCC. 

EMR, GLY, HAL, HPC, LEH, MON, PFZ, EH, RUB, 



ADM. 

ADM, ARG, 
ADM, UCC. 
ARG. 

ARG, CCW, 
ADM, BAC, 
EMR. 
EKT. 
EMR. 

EMR, LEH. 
HAL. 

ICI, KES. 
DRW, EMR, 



CCW, RCI, EH, SWT, THC, UCC. 



RH, THC, UCC. 

EMR, RCI, RH, SWT, THC. 



ICI, KES, NOP, PCS, PEP. 



CIN, 
DRW, 


HAL, 
EMR, 


ICI, 
SWT, 


KES, 
WM. 


LAS, 


NOP, 


RUB, 


SWT, 


WM, 


WTH. 


CRT, 


ICI, 


KES, 


WM. 














EMR, 


ICI, 


NOP, 


SWT. 














CHL, 


EMR, 


WM. 
















HAL, 


ICI, 


KES, 


RH. 














DRW, 


EMR, 


ICI, 


KES, 


PRP, 


WM. 










DRW, 


EKT, 


KES, 


RUB. 














FMP. 




















EKT. 




















UCC. 




















VC. 





















PLASTICIZERS 



155 



TABLE ISB.—Plasticizers for which U.S. production or sales were reported, identified by 
manufacturer, i 56^ --Continued 



PLASTICIZEES, ACYCLIC— Continued 

Polyethylene glycol di-2-ethylhexanoate 

Rlclnolelo and acetylriclnoleio aoid esters: 

^Glycerol monoricinoleate 

All other rlolnolelc and aoetylricinoleio aoid esters- 
Sebaoio aoid esters: 

*Di butyl sebacate 

*Di(2-ethylhexyl) sebacate 

All other sebaoic acid esters 

^Stearic aoid esters: 

*n- Butyl stearate 

All other stearic aoid esters 

Sucrose acetate isobutyrate 

Triethylene glycol di(eaprylate-caprate) 

Triethylene glycol di-2-ethylbutyrate 

All other acyclic plastioizers 



Manufacturers' identification codes 
(according to list in table 22) 



BAG, GLY, HAL, NOP. 

BAG, KES, RCI, WTH. 

£KT, GRH, HAL, PFZ, RCI, RH, WTH. 

GRD, GRH, HAL, PCC, PFZ, RCI, RH, RUB, WIH. 

KES, LEH, NOP, PCC, RCI, RH, RUB. 

EMR, HAL, IGI, KES, LAS, RUB, SCP, SWT, WTH. 

BAG, CHL, DRW, IMP, HK, HPC, IGI, ICO, KES, RCI, EH, 

WM. 
EKT. 

DRW, FOR, HAL, RUB. 
UCC. 

DRW, EKT, EKX, EMR, HAL, IGI, JNS, KES, LEH, PFZ, EH, 

RUB, TKL, UCC, x. 



156 



SYNTHETIC ORGANIC CHEMICALS, 1964 



Surface-Active Agents 



TABLE 19B. 



-Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1964 



[Surface-active agents for which separate statistics are given in table 19A are marked below with an asterisk (»); 
products not so marked do not appear in table 19A because the reported data are accepted in confidence and may not 
be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 







Manufacturers ' identification codes 




Chemical 




(according to list in table 22) 




BENZENOID SUHFACE-ACTIVE AGENTS 








Not Sulfated or Sulfonated 








*Amides, amines, and quaternary ammonium salts: 








*Benzyl( coconut oil alkyl) dimethylamTnonium chloride 


BC, 


CRT, FIN, TXT. 




*Benzyldimethyl( mixed aliyl) ammonium chloride 


BC, 


CUL, FIN, ONX, PCS, RH, TXT, VAC. 




»Benzyldimethylootadecylammonium chloride 


ONX, 


PCS, RET, WSN. 




*Benzyldodecyldimethylaramonium chloride 


DEP, 


ONX, SDH, WSN. 




*(3,4-Diohlorobenzyl)dodecyldimethylammonium chloride 


ONX, 


VAC, WSN. 




«(Dodecylbenzyl)trimethylaramonium chloride 


BC, 


CUL, ROD, VIS, WSN, WTC. 




^Heterocyclic compounds: 








l-Benzyl-2-( coconut oil aliyl) -l-(2-hydroxyethyl) -2- 


NLC. 






imidazolinlum chloride. 








l-Benzyl-2-heptadecyl-l-( 2-hydroxyethyl) -2-imidazo- 


PCS, 


uvc. 




linium chloride. 








l-Benzyl-l-(2-hydroxyethyl)-2-(tall oil alkyl)-2- 


NLC. 






imidazolinium chloride. 








l-Benzyl-3-methyl-2-undecylimidazoliuin bromide 


LIL. 






l-Benzyl-2-picolinium bromide 


FIN. 






2-Dodecylisoquinolinium bromide 


ONX. 






l-Dodeoylpyridinium chloride 


BC, 


HK. 




2-(2-Lauroyloxyethyl)carbamoyl-l-methylpyridinium 


WTC. 






chloride . 








l-Kfethyl-2-( 2-stearoyloxyethyl) carbamoylpyridinium 


WTC. 






chloride . 








«Oxygen-containing compounds: 








Benzylbis (2-hydroxyethyl) (2 -stearamidomethoxyethyl) - 


CIB. 






ammonium chloride. 








Benzyl( oocoamido ethyl)dimethylamraonium chloride 


TXT. 






Benzyl( coconut oil alkyl)bis(2-hydroxyethyl) ammonium 


CIB. 






chloride . 








Benzyl( ethoxylated coconut oil alkyl) dimethylammonium 


G. 






chloride . 








( Ethoxybenzyl)dimethyl(octylphenoxy) ammonium ohloride-- 


RH. 






(Ethoxybenzyl)dimethyl(octyltolyloxy) ammonium chloride- 


RH. 








APX. 






rj- ^ ^— nyaroxyeTinyx^ — Xj.c— uipneny-Le itjiy^eiiecxriiiu xie 




(Tridecylbenzyl)diethyl( 2-hydroxyethyl) ammonium 


ORO. 






chloride . 








»A11 other: 








Benzyldimethyltetradecylammonium chloride 


SNW, 


WSN. 




Benzylhexadecyldlmethylammonium chloride 


FIN, 


ONX, RH, SDW. 




Benzyl(hydrogenated tallow aliyl) dimethylammonium 


ARC, 


GNM, ONX, PCS. 




chloride . 








Benzyltrimethylammonium chloride ■ 


COM. 






(Dodecylbenzyl)dimethyloctadecylammonium chloride 


AML. 






(Dodecylbenzyl)triethylammonium chloride 


PC. 






( Dodecy Imethylbenzyl) trimethylammonium chloride 


RH. 






(Ethylbenzyl)dimethyl(mixed aliyl) ammonium chloride 


ONX. 






*Carboxylio acid esters and ethers: 








*Dodecylphenol, ethoxylated 


G, MON, PCS, UCC. 






APX, 


CIB, DRW, NOP, OMC. 




*iso— oc^yxpnenox, exnoxyxaxeo 






APD, CIB, DOW, DRW, G, HPC, JCC, MON, OMC, PCS, 
RTF, STP, UCC, VIS. 


RH 


, 




»Phenol, ethoxylated 


APD, 


CLY, G, JCC, NOP, UCC. 





SURFACE-ACTIVE AGENTS 



157 



TABLE 19B. 



--Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, i564--Continued 



Manufacturers' identification codes 
(according to list in table 22) 



BENZENOID SUHFACE-ACTIVE AGENTS— Continued 

Not Sulfated or Sulfonated— Continued 

*Carboxyllo acid esters and ethers — Continued 
*Other oarboxylic acid esters and ethers: 
Aliylphenol - formaldehyde, alioxylated : 

(Mixed alkyl)phenol - formaldehyde, aUtoxylated 

Nonylphenol - formaldehyde, alkoxylated 

t-Ootylphenol - formaldehyde, ethoxylated 

Pentylphenol - formaldehyde, alioxylated 

Diisobutylphenol, ethoxylated 

Dinonylphenol, ethoxylated 

(Mixed aliyl) phenol, ethoxylated 

(Mixed aliyl) phenol, ethoxylated, butyl ether 

Nonylphenoxypoly ( ethyleneoxy) ethyl iodide 

n-Octylphenol, ethoxylated 

Phthalic acid, octadeoyl ester, potassium salt 

Tetradeoylphenol, ethoxylated 

Tridecylphenol, ethoxylated 

Xylenol, ethoxylated 

All other 

*Phosphoric and polyphosphoric acid esters and salts: 
»Nonyl- and dinonylphenol, ethoxylated and phosphated: 

Dinonylphenol, ethoxylated and phosphated 

Nonylphenol, ethoxylated and phosphated 

Nonylphenol, ethoxylated and phosphated, barixjm salt- 
Other phosphoric and polyphosphoric acid esters and 
salts: 

Dodeoylphenol, ethoxylated and phosphated 

Octylphenol, ethoxylated and phosphated, magnesium 

salt. 
Phenol, ethoxylated and phosphated 

Sulfated and Sulfonated 

*Alkylphenols, ethoxylated and sulfated: 

Dodecylphenol, ethoxylated and sulfated 

(Mixed aliyl) phenol, ethoxylated and sulfated 

*Nonylphenol, ethoxylated and sulfated 

Nonylphenol, ethoxylated and sulfated, ammonium salt — 
Nonylphenol, ethoxylated and sulfated, triethanolamlne 
salt. 

n-Ootylphenol, ethoxylated and sulfated 

»Benzenesulf onates : 

Benzene-, toluene-, and xylenesulf onates : 

Benzenesulfonio acid, sodium salt 

2,4--Dinitrobenzenesulfom.c acid, sodium salt 

■ Ethylene glycol dibenzenesulfonate 

■ p-Toluenesulfonio acid, hexadecyltrimethylammonium 
■ salt. 

Toluenesulfonio acid, potassium salt 

»Toluenesulfonlc acid, sodium salt 

»}iylenesulfonio acid, ammonium salt 

*Xylenesulfonic acid, potassium salt 

^Xylenesulfonic acid, sodium salt 

^Branched chain dodecyl- and trideoylbenzenesulf onates : 
*Dodecylbenzenesulfonic acid 



RTF, VIS. 

RTF. 

SDW. 

RTF. 

0, BE. 

a, JCC, STP. 

G, PCS, STP. 

RH. 

G. 

ICI. 

CIB. 

ORO. 

PCS. 

VIS. 

RH. 



CIN, G, RZL, SEY, TCC, TXT, UVC, WAY, WTC. 



TCI. 
SMC. 



G, LEV, STP. 

G. 

CRT, G, OMC, STP, TXT, WTC. 

CIB, MYW. 



NES, UPF. 
NES. 
NES. 
FIN. 

MYW, NES, RCD, STP, WTC. 

CO, NES, PIL, RCD, STP, WTC. 

CO, NES, RCD, STP, WTC. 

MYW, NES, STP, WTC. 

ATR, CO, MYW, NES, PIL, RCD, STP, WTC. 

ARD, CIN, CO, CRT, HU, LEV, MON, MYW, NAC, PCI, PIL, 
PRX, RCD, SEY, STP, TCI, TDC, TN, TXT, WON, WTC. 



158 



TABLE 19B. 



SYNTHETIC ORGANIC CHEMICALS, 1964 

- Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer , 1964 — Continued 







Manufacturers ' identification codes 


Chemical 




(according to list in table 22) 


BENZENOID SURFACE -ACTIVE AGENTS —Continued 






Sulfated and Sui/ona terf—Contlnued 






»Benzenesulf onates —Continued 






*Branohed chain dodeoyl- and trideoylbenzenesulfonates-- 






Continued 






*Dodecylbenzenesu3-fonic acid, ammonium salt 


ARL, 


CTL, MYW, PRX, RCD, TXT. 


*Dodecylbenzenesulfonic acid, calcium salt 


APD, 


RCD, RH, SMD, STP, VIS, WTC. 


»Dodecylbenzenesulfonic acid, diethanolamine salt 


PCS, 


VAL, WON. 


*Dodecylbenzenesulfonic acid, isopropylamine salt 


APD, 


ARD, CIN, CTL, RCD, SNW, STP, WTC. 


»Dodecylbenzeuesulfonic acid, (mixed aliyl) amine salt — 


PCS, 


STP, TXT, WTC. 


*Dodeoylbenzenesulfonic acid, sodium salt 


AAC, 


ARD, ARL, ATR, CO, CP, CTL, DEP, EFH, EMK, HLI, 




HRT, ICI, LEV, MON, NAC, NOP, PCI, PG, PIL, PfiX, 




RCD, SEY, SIP, SWT, TN, TXT, VAL, WIC, WTC. 


^Dodecylbenzenesulfonio acid,' triethanolamine salt 


ML, 


APX, ARD, ARL, ATR, CIN, CO, CTL, HLI, NAC, PCS, 




PEK, PIL, RCD, RZL, SOS, STP, SWT, TXT, VAC, WTC. 


*Tridecylbenzenesulfonlc acid, sodium salt 


BLA, 


CO, CP, PRX, RCD, TXT, WTC. 


*Other branched chain dodecyl- and tridecylbenzene- 






sulf onates: 






Dodecylbenzenesulfonic acid, butylamine salt 


WTC. 




Dodecylbenzenesulfonic acid, diethanolamine 


MAH. 




condensate, fatty acid monoester. 






Dodecylbenzenesulfonic acid, ethylenediamine salt 


APD. 




Dodecylbenzenesulfonic acid, isopropanolamine salt — 


SMC, 


WON. 


Dodecylbenzenesulfonic acid, potassium salt 


VAL. 




Dodecylbenzenesulfonic acid, propoxylated ethylene - 


PCS. 




diamine salt. 






Tridecylbenzenesulfonic acid, ammonium salt 


PRX, 


TXT. 


Straight chain dodecyl- and tridecylbenzenesulf onates : 






*Dodecylbenzenesuli'onic acid 


ARD, 


HLI, LEV, MON, NAC, PIL, RCD, RZL, TCI. 


»Dodecylbenzenesuli'onic acid, sodium salt 


ATR, 


CP, LEV, MON, PG, PIL, PRX, RCD, UNP. 


■"■Dodecylbenzenesulfonic acid, triethanolamine salt 


ATR, 


RZL, TXT. 


Tridecylbenzenesulfonic acid, sodium salt 


CP, 


NAC. 


Other benzenesulf onates : 








MON. 




uecyiDenzenesun onic acj.a, soaium fadxu 






CO. 




uiuOaecyiDenzenesuii onic acia 




Nonylbenzenesulfonic acid, sodium salt 


WTC. 




Pentadecylbenzenesulfonic acid, sodium salt 


CP. 




Pentylbenzenesulf onic acid, sodium salt 


MON. 




All other 


SWT. 




■flignosulf onates ; 






lignosulfonic acid, aluminum salt 


MAR. 




lignosulfonic acid, ammonium salt 


CRZ. 




^lignosulfonic acid, calcium salt 


CRZ, 


CWP, INP, LKY, LPC, MAR, PSP. 


Lignosulfonic acid, chromium salt 


MAR. 




Lignosulfonic acid, iron salt 


CRZ. 




Lignosulfonic acid, magnesium salt 


LPC, 


MAR. 


Lignosulfonic acid, sodium salt 


CRZ, 


CWP, INP, MAR, WVA. 


■"■Naphthalenesulf onates : 








G. 




Deniyjjidpiiijiiciienebujj. uiu-c city j.q 




Butylnaphthalenesulfonic acid 


SCP. 




Butylnaphthalenesulfonic acid, sodium salt 


CLD, 


CMG, GGY, PFZ. 


Di butylnaphthalenesulfonic acid 


G, MRA, S. 


Didodecylnaphthalenesulfonic acid, sodium salt 


PFZ. 




*Diisopropylnaphthalenesulf onic acid 


DUP, 


G, GRD. 


DiisopropylnaphthalenesulTonic acid, sodium salt 


G, PFZ. 


Dipentylnaphthalenesulf onic acid 


GGY. 




DipentyLnaphthalenesulfonic acid, ammonium salt 


VIS. 




»IsopropylnaphthalenesuLfonic acid 


DUP, 


NAC, NOP, ONX. 



SURFACE-ACTIVE AGENTS 



159 



TABLE 19B. 



-Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer , 1964 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



BENZENOID SUHFACE-ACTIVE AGENTS— Continued 

Sulfated and Sulfonated- -ContimieA 

^Naphthalene sulfonates — Continued 

Methylenebis(2-naphthalenesulf onic acid) 

6,6'-Methylene'bis(2-naphthalenesulfonic acid), calcium 
salt. 

Methylnaphthalenesulfonlc acid, sodium salt 

Methylnonylnaphthalenesulfonlo acid, sodium salt 

Tetrahydronaphthalenesulfonlc acid, sodium salt 

ifOther benzenoid surface-active agents: 

Butylhydroxyblphenylsulfonlc acid 

Dodecyldiphenyloxidedlsulfonlc acid, sodium salt 

Heptadecylmethylbenzlmidazollnesulf onlc acid, sodium salt 

n-Octylphenol, ethoxylated and sulfonated 

Petroleumsulfoulc acid, water soluble (acid layer), 

sodium salt. 
Trlchlorophenol sulfate, ethanolamlne salt 

NONBENZENOID SURFACE-ACTIVE AGENTS 

Not Sulfated or Sulfonated 

^Amides, amines, and quaternary ammonium salts: 
*Acycllc quaternary ammonium salts: 

*Bis ( hydrogenated tallow aliyl) dime thy lammonium 

chloride . 
*Hexadecyltrimethylammonium salts : 

Hexadecyltrimethylammonium bromide 

Hexadecyltrimethylammonlum chloride 

Hexadecyltrimethylammonium stearate 

mother acyclic quaternary ammonium salts: 
Alkylethyldimethylammonium salts ; 

Ethyldlmethyl(9-octadeoenyl) ammonium bromide 

Ethyldimethyl( soybean oil alkyl) ammonium bromide 

Ethylhexadecyldlmethylammonlum bromide 

Aliyltrimethylammonlum salts: 

(Coconut oil alkyl) trlmethylammonium chloride 

Dodecyltrimethylammonlum bromide 

Dodecyltrimethylammonium chloride 

(Hydrogenated tallow alley 1) trlmethylammonium 
chloride . 

Trlmethyl( mixed aliyl) ammonium chloride 

Trlmethyloctadecylammonlum chloride 

Trlmethyl( soybean oil aliyl) ammonium chloride 

Trlmethyl( tallow alkyl) ammonium chloride 

Trimethyl(tetradecyl) ammonium bromide 

Dialiyldlmethylammonium salts: 

Bls( coconut oil alkyl) dimethylammonium chloride 

Dldodecyldimethylammonium bromide 

Dimethyldioctadecylammonliim chloride 

Oxygen-containing compounds: 

( Carboxyraethyl) ( coconut oil amldopropyl) dimethyl- 
ammonium chloride, sodium salt, 

(Coconut oil alkyl) betalne 

(Coconut oil alkyl) bis(2-hydroxyethyl, ethoxy- 
lated) methylammonium chloride. 
Deeylbetalne 



DUP. 
DUP. 

UDI. 
UDI. 
DUP. 



ICO, RBC. 

DOW. 

CIB. 

RH. 

SIN, SON. 



G. 



ADM, ARC, FOR, GNM, VAC. 



DUP, 


FIN, ICI 


ARC, 


WSN. 


FIN. 




ONX. 




BC. 




FIN. 




ARC, 


GNM. 


DUP. 




ARC. 




ARC. 




GNM. 




ARC. 




ARC. 




ARC, 


GNM. 


FIN. 




ARC, 


GNM. 


ONX. 




PG. 




JRG. 




CUL. 




ABC, 


VAC. 



160 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 19B. 



-Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, iSSi— Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



NONBENZENOID SURFACE-ACnVE AGENTS— Continued 
Not Sulfated or Sulfonated— Continuea 

♦Amides, amines, and quaternary ammonium salts — Continued 
*Acyclio quaternary ammonliim salts — Continued 

*Other acyclic quaternary ammonium salts — Continued 
Oxygen-containing compounds — Continued 

Hexadeoylbetaine 

( 2-Hydroxyethyl) dimethyl( stearamidopropyl) - 

ammonium dihydrogen phosphate. 
( 2-Hydroxyethyl) dimethyl( stearamidopropyl) - 

ammonium nitrate. 
2-Hydroxy-l,3-propylenebis [(coconut oil allqrl)- 
dlmethylaramonium chloride] . 

Mixed fatty betaines 

Octadecylbetalne 

Trlethyloctadecyloxymethylammonium chloride 

Trlaliylmethylammonium salts: 

Methyltrioctylammonium chloride 

lfethyltrls(mixed alkyl) ammonium chloride 

*Amine acetates; 

(Coconut oil alkyl)amine acetate 

(Coconut oil alkyl) amine, ethoxylated, acetate 

*(Hydrogenated tallow aUtyl) ami ne acetate 

(9-Octadecenyl) amine acetate 

Octadecylamine acetate 

Octylamine acetate 

(Tallow alkyl) amine acetate 

N-( Tallow alkyl) diethanolamine acetate 

*Amine salts, anionic: 

Oleic acid, diethylamine salt 

»01eic acid, triethanolamine salt 

Rosin acids, triethanolamine salt 

Stearic acid, N,N,N ',N'-tetrakis(2-hydroxyethyl)ethyl- 
enediamlne salt. 

Stearic acid, triethanolamine salt 

All other 

»Amlnes , alioxylated : 

N,N-Bis(2-hydroxyethyl)dodecylamine 

N,N-Bis(2-hydroxyethyl) octadecylamine 

N,N-Bis(2-hydroxyethyl) -2-(stearamidomethoxy)ethyl- 

amlne. 
N,N-Bis(2-hydroxyetbyl)-2-(stearamidomethoxy)ethyl- 
amlne - raelamine ether condensate. 

N,N-Bls(2-hydroxyethyl) (tallow alkyl amine) 

(Coconut oil alkyl) amine, ethoxylated 

(Hydrogenated tallow aLkyl)amine, ethoxylated 

N-( 2-Hydroxyethyl) -N,N',N'-tris( 2-hydroxypropyl)ethyl- 
enedlaim'ne. 

»(Mixed alkyl) amine, ethoxylated 

(9-Octadecenyl) amine, ethoxylated 

Octadecylamine, ethoxylated 

Polyethylenepolyamlne, alkoxylated 

Rosin amine, ethoxylated 

(Soybean oil alkyl) amine, ethoxylated 

»( Tallow aliyl) amine, ethoxylated 

N-( Tallow alkyl) -1,3-propylenedlamine, ethoxylated 

N,N,N',N'-TetraJils(2-hydroxyethyl)ethylenediamine 



DUP. 








ACY. 








ACY. 








CIB. 








TXT. 








DUP. 








DAK. 








GNM. 








ADM, 


VAC. 






ADM, 


ARC. 






RPC. 








ADM, 


ARC, 


GIN, 


WAY. 


GNM. 








ACY, 


ARC. 






ARC. 








ADM, 


ARC, 


GNM. 




PG. 








WTC. 








DOM, 


H.U,, 


NOP, 


TCC. 


RTF. 








ICI. 








AML, 


TCC. 






PCS. 








FIN. 








FIN. 








CIB. 








CIB. 








FIN. 








APD, 


ARC, 


VAC, 


VIS. 


CIB, 


TCH. 






VIS. 








APD, 


CIB, 


G, NOP, RH 


ARC, 


PCS. 






ARC, 


ICI. 






VIS. 








HPC, 


PCS, 


RTF, 


VIS. 


ARC, 


VAC. 






ADM, 


ARC, 


CIB, 


DUP.. 


ARC. 








VIS. 









SURFACE-ACTIVE AGENTS 

TABLE 19B. — Surface-active agents for which U.S. production or sales were reported identified by 
manufacturer, 1964— Continued 



161 



NONBENZENOID SUHFACE-ACTIVE AGENTS— Continued 
Not Sulfated or Sulfonated— Continued 

*Amides, amines, and quaternary ammonium salts — Continued 
*Amines, alkoxylated — Continued 

N,N,N',N'-Tetrakis(2-hydroxypropyl)ethylenediaim.ne, 
propoxylated and ethoxylated. 

Triethanolamine, ethoxylated 

*Fatty acid - aUcanolamine condensates: 
*Dlethanolamine condensates : 

Caprio acid - diethanolamine condensate 

»Castor oil acids - diethanolamine condensate 

Coconut oil acids - diethanolamine condensates: 
»(Amine/acid ratio = 2/1) 

»(Amine/aold ratio = l/l) 

All other ratios 

*Lauric acid - diethanolamine condensate 

linoleic acid - diethanolamine condensate 

Hyrlstio acid - diethanolamine condensate 

Oleic acid - diethanolamine condensates: 

*(-Amlne/aoid ratio = 2/1) 

»(Amine/acld ratio = l/l) 

»Steario acid - diethanolamine condensate 

»Tall oil acids - diethanolamine condensate 

Tallow acids - diethanolamine condensate 

Other diethanolamine condensates 

Other alianolamine condensates: 

Coconut oil acids - ethanolamine condensate 

Coconut oil acids - isopropanolamine condensate 

Laurie acid - ethanolamine condensate 

*Lauric acid - isopropanolamine condensate 

Myrlstic acid - ethanolamine condensate 

Ifcrristic acid - isopropanolamine condensate 

Oleic acid - ethanolamine condensate 

Oleic acid - Isopropanolamine condensate 

^Stearic acid - ethanolamine condensates: 

(Amiue/acid ratio = l/l) 

(Amine/acid ratio = 1/2) 

All other ratios 

All other fatty acid - aUcanolamine condensates 

*Fatty acid - polyamine condensates: 

Adipic and stearic acids - diethylenetriamine 
condensate. 

Coconut oil acids - diethylenetriamine condensate 

Coconut oil acids - N,N-dimethyl-l,3-propylenediamine 
condensate . 

Coconut oil acids - propylenediamine condensate 

Mixed fatty acids - polyaliylenepolyamine condensate — 

Oleic acid - aminoethylpiperazine condensate 

*01eic acid - diethylenetriamine condensate 

Oleic acid - diethylenetriamine condensate, acetic 

acid salt. 
Oleic acid - N,N-dimethyl-l,3-propylenediamine 
condensate. 



Manufacturers' identification codes 
(according to list in table 22) 



WYN. 
JCC. 



GGY, ONX, PCS, RZL. 
PCS, VAL, VND. 

AML, ARD, BSC, CIB, CIN, CLI, CRT, CTL, DEP, DRW, EFH, 
HLI, HRT, JOR, KNP, LEV, LUR, MDA, NOP, ONX, PC, PCS 
PC, PNX, RCD, RZL, SBC, SEY, SWT, TCC, TXC, TXT, UNN 
UVC, VAC, VAL, VND, WTC. 

APX, ARD, ARL, CLI, CTL, DRW, EMK, GGY, HLI, MDA, MRV 
NOP, ONX, PCS, PEK, QCP, SBC, SEY, STP, TXT, VAC. 

JRG, PCS. 

ARD, CLI, CTL, HLI, ICI, MOA, ONX, PCS, PC, RZL, SBC 
TXT, WON, WTC. 

VND. 

CLI. 

CCW, CLI, HLI, MRA, ONX, SEY, STP, WTC. 

CUL, GGY, NOP, SBC, SCP, SEY, STP, SWT, TXT. 

AML, APX, ARD, BSC, CLI, DEP, EMR, GGY, GLY, JOR, MRA, 

NOP, ONX, RPC, SCO, SEY, TXC, UVC, VAL, WTC. 

EFH, MRA, MRV, SEY, WTC. 
PCS, PG, RPC. 

BSC, HLI, RCD, WTC, 

APX, CCL, HRT, MOA, PCS, PG, RCD, TXT, VND, WIC WTC. 

LEV, STP, TXT. ' 

RCD, WTC. 

ARC, ARD, CLI, MOA, PCS, TXT, WTC. 

WTC. 

ARD, TXT. 

ARD. 

WTC. 

ARD, CIN, KES, MOA, STP, VND. 

GLY, WTC. 
CLI. 

CLI, GLY. 

APX. 

APX, NOP, SEY. 
JHG. 

TXT. 

VIS. 

PCS. 

HDG, PCS, SEY. 

PCS, UVC. 

CCW, SNW. 



162 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 19B.- 



- Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, i564 —Continued 









Manufacturers' identification codes 


Chemical 






(according to list in table 22) 


NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 










Not Sulfated or Sulfonated— Continued 










^Amides, amines, and quaternary anmioniuni salts — Continued 










*Fatty acid - polyamine condensates — Continued 










Oleic acid - ethylenedi amine condensate (amine/acid 


ccw. 


GLY, 


HDG. 




ratio = 1/2) . 










Pelargonic acid - tetraethylenepentamine condensate 


ICI. 








»Stearic acid - diethylenetrlamine condensate 


APX, 


CRT, 


CST, 


DEP, HRT, ONX, QCP, S. 


Stearic acid - N^N-diethylethylenediamine condensate 


CBP. 








Stearic acid - N,N'-diethylethylenedianiine condensate 


SNW. 








( amine/acid ratio = l/2) . 










Stearic acid - dipropylenetriamlne condensate 


JOR. 








Stearic acid - ethylenediamine condensate (amine/acid 


CCW, 


GLY, 


ICI. 




ratio = 1/2) . 










Stearic acid - tetraethylenepentamine condensate 


ICI, 


ONX. 






Tall oil acids - diethylenetrlamine condensate 


NCW. 








Tall oil acids - polyamine condensate 


TXT. 








AIT nthea-p . 


EMR 


VAL, 


VND, 


WM. 


iixj. ubiiei — — 

*Fatty acid - polyamine condensates, ethoxylated: 










Coconut oil acids - diethylenetrlamine condensate. 


TCC. 








polyethoxylated . 










Coconut oil acids - ethylenediamine condensate, mono- 


NOP, 


RFC. 






ethoxylated. 










Mixed fatty acids - aUkylenedi amine condensate, poly- 


VIS. 








ethoxylated . 










*01elc acid - ethylenediamine condensate, monoethoxy- 


CID, 


GST, 


DEX, 


NOP, SOC, TNA. 


lated. 










Palm oil acids - ethylenediamine condensate, mono- 


APX. 








ethoxylated . 










Stearic acid - diethylenetrlamine condensate, poly- 


TCC. 








ethoxylated . 










Stearic acid - ethylenediamine condensate, diethoxy- 


TCC. 








lated. 










^Stearic acid - ethylenediamine condensate, monoethoxy- 


AML, 


CLD, 


CST, 


DEP, DEX, ICI, MRA, NOP, S, SNW. 


lated. 










Stearic acid - ethylenediamine condensate, polyethoxy- 


APD, 


GLY, 


TCC. 




lated. 










^Heterocyclic compounds : 










Imidazole derivatives: 










l-(2-Aminoethyl)-2-(tall oil alkyl) -2-lmldazoline 


NLC. 








1, 1-Bis( carboxymethyl) -2-undeoyl-2-imidazolinium 


PCS. 








chloride, dlsodium salt. 










l,l-Bis( carboxymethyl) -2-undecyl-2-lmidazolinium 


MIR. 








hydroxide, disodium salt. 










l-Carboxymethyl-2-heptadecyl-l-(2-hydroxyethyl) -2- 


MIR. 








imidazolinium hydroxide, sodium derivative, sodium 
salt. 
l-Carboxymethyl-l-(2-hydroxyethyl) -2-nonyl-2-imidazo- 










PCS. 








linium chloride, sodium salt. 












MIR. 








linium hydroxide, sodium derivative, sodium salt. 










l-Carboxymethyl-l-( 2-hydroxyethyl) -2-undecyl-2- 


WR. 








imidazoliniiim hydroxide, sodium derivative, sodium 
salt. 
l-Ethyl-2-(8-heptadeoenyl) -l-( 2-hydroxyethyl) -2- 










BC. 








imidazolinivim bromide. 










2-(8-Heptadecenyl) -l-( 2-hydroxyethyl) -2-imidazoline — 


GGY, 


NLC, 


PCS, 


UVC. 


»2 -Heptadecyl-l-( 2 -hydroxyethyl) -2-imidazoline 


GGY, 


HDG, 


ONX, 


UVC. 



SURFACE-ACTIVE AGENTS 



163 



TABLE 19B. 



-Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 7564— Continued 



Manufacturers' identification codes 
(according to list in tatle 22) 



NONBENZENOID SURFACE-ACnVE AGENIS— Continued 

Not Sulfated or Sulfonated— Continued 

*Amides, amines, and quaternary ammonium salts — Continued 
■^Heterocyclic compounds — Continued 
Imidazole derivatives — Continued 

2-Heptadecyl-2-imidazoline 

l-(2-ffydroxyetl]yl)-2-nonyl-2-imidazoline 

l-(2-Hydroxyethyl)-2-(tall oil alkyl)-2-imldazoline- 
l-(2-Ifydroxyethyl)-2-tridecyl-2-imida2olinium 
chloride. 

l-(2-Ifydroxyethyl)-2-undecyl-2-imidazoline 

2- (Mixed aliyl)-2-imidazoline 

*Rosinpolyamidoimidazoline 

Oxazole derivatives : 

2- ( 8-Heptadecenyl) -4, <4-bis ( hydroxymethyl) -2- 

oxazoline. 
2-(8-Heptadeoenyl)-'t-hydroxymethyl-4-methyl-2- 
oxazoline. 
*N-Substltuted amino acids and polypeptides: 

N-[ 2-( Carboxymethylamino) ethyl J -N-( 2-hydroxyethyl) - 
coconut oil amide, sodium salt. 

N-( Coconut oil acyl)sarcosine 

N-( Coconut oil aliyl) -p-alanlne 

N-Dodeoyl-3-iminodipropionic acid 

N-(2-Hydroxyethyl)-N-(2-stearamidoethyl)glycine 

N-Lauroylpolypeptide 

N-Lauroylsarcosine, sodium salt 

N-Oleoylpolypeptide 

N-Oleoylsarcoslne, sodium salt 

Polypeptide 

N-Stearoylsarcosine, sodiimi salt 

N-(Tallow alkyl) -3-iminodipropionic acid, sodium salt- 
*Other amides, amines, and quaternary ammonium salts: 
Fatty acid - aUcanolamine condensates, ethoxylated: 
Hydrogenated tallow acids - ethanolamine condensate, 
ethoxylated. 

Oleic acid - ethanolamine condensate, ethoxylated 

Oleic acid - methanolamine condensate, ethoxylated — 
Tall oil acids - ethanolamine condensate, ethoxy- 
lated. 
All other amides, amines, and quaternary ammonium 
salts : 

*N-(Goconut oil aliyl)-l,3-propylenediamine 

(Cottonseed oil alkyl) amine 

N-Dodecyldiethylenetri amine 

N-(Mixed alkyl)polyethylenfipolyamine 

*N-(9-0etadecenyl) -1,3-propylenedlamine 

N-(Soybean oil aliyl) -1,3-propylenediamlne 

Stearic acid - N-(2-cyanoethyl)diethylenetrlamine 
condensate (amine/acid ratio = 1/2) . 

*N-( Tallow alkyl) -1,3-propylenediamine 

All other 

*Carboxyllc acid esters: 

^Ethylene glycol and diethylene glycol esters: 
*Diethylene glycol di- and sesquistearate: 

Diethylene glycol distearate 

Diethylene glycol sesquistearate 

*Diethylene glycol monolaurate 

^-Diethylene glycol mono-oleate 

*Diethylene glycol monostearate 



RZL, 


SCO. 




PCS. 






NLC. 






GGY. 






GGY, 


UVC. 




TXT. 






GRD, 


PCS, 


UVC 


COM. 






COM, 


UVC. 





GGY. 

GNM. 

G^M. 

G. 

MYW. 

CP, GGY, HMP, ONX. 

MYW. 

G, GGY. 

MYW. 

GGY. 

GNM. 



ARC, G. 



ARC, 


FOR, GNM. 


GNM. 




FIN. 




CCW. 




ARC, 


FOR, GNM. 


ARC. 




CIB. 




ARC, 


FOR, GNM. 


CIB, 


G, ONX, X 



KES. 

GLY, WM. 

CCW, DRW, EMR, GLY, HAL, HDG, KAL, KES, NOP, WTC. 

HAL, KES, WTC. 

CCW, CIN, CLI, HAL, KES, NOP, PCS, QCP, VAl, VHD, WTC. 



164 SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 19B.— Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



Chemical 



NONBENZENOID SUHFACE-ACTIVE AGENTS— Continued 

Not Sulfated or Sui/ona ted— Continued 

«Cartoxyllc acid esters — Continued 

»Ethylene glycol and diethylene glycol esters— Continued 

♦Ethylene glycol distearate 

♦Ethylene glycol monostearate 

♦Other ethylene glycol and diethylene glycol esters: 

Diethylene glycol mono( coconut oil) ester 

Diethylene glycol monorioinoleate 

Diethylene glycol sesquilaurate 

Diethylene glycol sesquioleate 

Diethylene glycol tall oil ester 

Ethylene glycol mono-oleate 

Ethylene glycol sesquistearate 

♦Glycerol esters: 

♦Complex glycerol esters: 

Glycerol diacetyltartrate mono-oleate 

Glycerol diacetyltartrate monostearate 

Glycerol lactate laurate 

Glycerol lactate palmitate 

Glycerol lactate stearate 

Glycerol maleate mono-oleate 

Glycerol mono-oleate, aoetylated 

All other 

♦Glycerol esters of chemically defined fatty acids: 

Glycerol dioleate 

Glycerol distearate 

Glycerol monooaprylate 

Glycerol monolaurate 

♦Glycerol mono-oleate 

Glycerol monorioinoleate 

♦Glycerol monostearate 

♦Glycerol esters of mixed fatty acids: 

Glycerol diester of lard 

♦Glycerol monoester of coconut oil acids 

♦Glycerol monoester of cottonseed oil acids 

Glycerol monoester of hydrogenated cottonseed oil 

acids. 
Glycerol monoester of hydrogenated soybean oil acids 

Glycerol monoester of lard 

Glycerol monoester of peanut oil acids 

All other 

♦Polyethylene glycol esters: 

♦Polyethylene glycol esters of chemically defined 
fatty acids: 

♦Polyethylene glycol dilaurate 

♦Polyethylene glycol dioleate 

♦Polyethylene glycol distearate 

Polyethylene glycol methylcarbitol maleate 

♦Polyethylene glycol monolaurate 



Manufacturers' identification codes 
(according to list in table 22) 



EMR, HAL, HDG, KES. 

CCW, CLI, DRW, EFH, GLY, HAL, HDG, KES, KNP, PCS, TOD, 

WM. 



DRW. 






GLY. 






GLY. 






GLY. 






HDG, 


QOP, 


SEY, WTC 


EFH. 






WM. 






DRW. 






DRW, 


PCS, 


WTC. 


APD. 






DRW, 


GLD. 




APD, 


GLD. 




NOP, 


WTC. 





EK. 



HAL, KES. 

APX, KES, PCS. 

KES. 

GLY, KES, KNP. 

APD, CCW, DRW, EFH, EK, EMR, GLY, HAL, HDG, KES, SWT, 

VND, WM. 
CCW. 
CCW, CHL, CRT, DRW, EK, EMR, GLY, HAL, HDG, JRG, KES, 

LUR, MRA, NOP, NW, PCS, PG, SNW, SWT, TCC, VND, WM, 

WTC, X. 

DRW, GLY, HAL, HDG, SWT, WM. 

DRW, EK, GLD, PCS. 

LEV. 

DRW. 

EK, GLD. 

DRW. 

APD, EFH, EK, GLD, GLY, HDG, LEV, PCS, SWT, WTC. 



DEX, EFH, GLY, HDG, JOR, KES, PCS, UVC, WM. 

CLD, EFH, GGY, GLY, HAL, HDG, KES, NOP, PCS, SPP, UVC, 

VND, WM. 

GLY, HAL, KES, PCS, QCP. 
CCA. 

AAC, ARC, BSC, CCA, DEX, DRW, GGY, GLY, HAL, ICI, JOR, 

KES, KNP, NOP, SYC, TCH, UVC. 



SURFACE-ACTIVE AGENTS 



165 



TABLE 19B.— Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 7564— Continued 



Chsfflica.! 






Manufacturers ' 


identification codes 








(ac 


cording tc 


list in table 22) 


NONBENZENOID SURFACE -ACTIVE AGENTS— Continued 














Wot Sulfated or Sul fona ted- -Continued 














*Carboxylic acid esters — Continued 














*Polyethylene glycol esters— Continued 














^Polyethylene glycol esters of chemically defined 














fatty acids— Continued 














^Polyethylene glycol mono-oleate 


AAC, 


ARC, 


CCA, 


CLD, 


CRC, 


CRT, DEX, DRW, EMR, G, GGY, 




GLY, HAL, ICI, KES, NOP, ONX, PCS, QCP, SPP.'SWT,' 




SYC, TCH, UVC, VAC, WW 


, WTC. 


Polyethylene glycol monopalraitate 


APD. 












Polyethylene glycol monoricinoleate 


AAC, 
AML, 


HAL, 
APD, 


KES, 
ARC, 


NOP. 
CCW, 






^Polyethylene glycol monostearate 


CIN, 


CRT, DEP, DEX, DRW, G, GGY. 




GLY, HAL, HDG, ICI, JOR, KES, KNP, NOP, ONX,' PC, 




PCS, PD 


, RH, 


TCC, 


TCH, 


UVC, VND, WTC. 


*Polyethylene glycol esters of mixed fatty acids: 














Polyethylene glycol castor oil ester 


G, GGY, GLY, NOP, UVC, WTC. 


*Polyethylene glycol coconut oil ester 


APX, 


ARL, 


GLY, 


HAL, 


NOP, 


PCS, PG, VND. 


^Polyethylene glycol rosin ester 


APD, 


HPC, 


QCP, 


VIS. 






*PolyetlQrlene glycol tall oil ester 


AML, 


APD, 


APX, 


ARC, 


DRW, 


GLY. HAL. HDG, KES, MCN, NOP, 




OMC, PCS, SOS, TCH, UVC, WTC. 


Polyethylene glycol tallow ester 


ONX, 


SOS. 










All other 


GLY, 


HDG, 


PCS, 


SYC. 






*Other oarhoxylic acid esters: 






Anhydrosorbitol esters : 














Anhydrosorbitol dioleate 


APD. 












Anhydrosorbitol mixed fatty acid ester 


GLY. 












Anhydrosorbitol monolaurate 


AAC, 


APD, 


GLY, 


HDG, 


PCS. 




Anhydrosorbitol mono-oleate 


AAC, 


APD, 


DRW, 


GLY, 


HDG, 


PCS. 


AnlQfdrosorbitol monopalmitate 


AAC, 


APD, 


GLY. 








Anhydrosorbitol monostearate — — 


AAC, 
GLY. 


APD, 


DRW, 


GLY, 


HDG, 


PCS. 


Anhydrosorbitol sesquioleate 


^Anhydrosorbitol tall oil ester 


APD, 


GLY, 


HDG. 








Anhydrosorbitol tetrastearate 


AAC, 


APD. 










Anhydrosorbitol trioleate 


AAC, 


APD, 


GLY. 








Anhydrosorbitol tristearate 


APD, 


GLY. 










Ethoxylated anhydrosorbitol esters: 














Ethoxylated anhydrosorbitol castor oil ester 


APD. 












*Ethoxylated anhydrosorbitol monolaurate — 


AAC, 
AAC, 


APD, 

APD, 


DRW, 
DRW, 


GLY, 
GLY, 


HDG, 
HDG, 


PCS, TCH. 
PCS, TCH. 


*Ethoxylated anhydrosorbitol mono-oleate 


Ethoxylated anhydrosorbitol monopalmitate — — 


AAC, 
AAC, 
APD, 


APD, 
APD, 
TCH. 


GLY, 
DRW, 


TCH. 
GLY, 






^Ethoxylated anhydrosorbitol monostearate — — 


HDG, 


PCS, TCH. 


Ethoxylated anhydrosorbitol tall oil ester 


^Ethoxylated anhydrosorbitol trioleate — — 


AAC, 
AAC, 


APD, 
APD, 


GLY, 
DRW, 


TCH. 
GLY, 






*Ethoxylated anhydrosorbitol tristearate—- 


PCS, 


TCH. 


Ethoxylated sorbitol esters: 


Ethoxylated sorbitol beeswax ester 


APD. 












Ethoxylated sorbitol distearate 


APD. 












Ethoxylated sorbitol hexaoleate 


APD. 












Ethoxylated sorbitol hexa(tall oil)ester 


APD. 












Ethoxylated sorbitol lanolin ester -^ 


APD. 












Ethoxylated sorbitol mono-oleate 


APD. 












Ethoxylated sorbitol oleate stearate 


APD. 












Ethoxylated sorbitol pentalaurate 


APD. 












Ethoxylated sorbitol pentaoleate, acetylated 


APD. 












Ethoxylated sorbitol penta(tall oil) ester 


APD. 












Ethoxylated sorbitol tetra( laur ate , oleate) 


APD. 












Ethoxylated sorbitol tetra(tall oil)ester 


APD. 













166 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 19B. —Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer, 1964 — Continued 



NONBENZENOID SURFACE -ACTIVE AGENTS- -Continued 

Not Sulfated or Siilfonated--Continued 

»Carboxylio acid esters — Continued 

*Other oarboxylio acid esters — Continued 
All other carboxylic acid esters: 

Anhydrosorbitol glycerol monolaurate 

Calcium stearolactate 

Coconut oil acids, ethoxylated methanol ester — 

Diisobutylene maleate 

Ethoxylated glycerol mono- and diester of mixed 
fatty acids. 

Ethoxylated 1,2-propanediol mono-oleate 

Ethoxylated 1,2-propanediol stearate 

Mannitol dioleate, propoxylated 

Methyl glucoside laurate 

Methyl glucoside oleate 

Pentaerythritol distearate 

Polyaliylene glycol adipate 

PolyaUjylene glycol diglycolate 

PolyaUjylene glycol dimaleate 

Polyaliylene glycol naphthenate 

Polyglycerol lactate oleate 

Polyglycerol raonoester of cottonseed oil acids— 

Polyglycerol oleate 

Polyglycerol stearate 

1,2-Propanediol distearate 

1,3-Propanediol mono( coconut oil) ester 

*1, 2 -Propanediol monolaurate 

1,2 -Propanediol mono-oleate 

*l,2-Propanediol monostearate 

Propylene glycol mono esters 

Sucrose esters of fatty acids 

All other 

*Ethers: 

*Castor oil, ethoxylated 

Coconut oil alcohols, ethoxylated 

n-Decyl alcohol, ethoxylated 

n-Decyl alcohol, ethoxylated and chlorinated 

*n-Dodecyl alcohol, ethoxylated 

n-Hexadecyl alcohol, ethoxylated 

Hydrogenated castor oil, ethoxj'lated 

Iso-octyl alcohol, ethoxylated 

Lanolin, ethoxylated 

*Mixed primary straight chain alcohols, ethoxylated- 

*9-0ctadeoenyl alcohol, ethoxylated 

n-Ootadecyl alcohol, ethoxylated 

Polyethylene glycol tert-dodecyl thioether 

Poly(mlxed ethylene, propylene) glycol 

Polypropylene glycol, ethoxylated 

Rosin alcohol, ethoxylated 

Sorbitol, alkoxylated 

Soybean oil, ethoxylated 

Sperm oil alcohol, ethoxylated 

Tallow alcohol, ethoxylated 

2,4,7,9-Tetramethyl-5-decyne-4.,7-diol, ethoxylated- 
»Tridecyl alcohol, ethoxylated 



Manufacturers ' Identification codes 
(according to list in table 22) 



APD. 

GLY. 

JOR. 

RH. 

APD. 

APD. 
APD. 
APD. 
HDG. 
HDG. 
VAL. 
PFZ. 
VIS. 
VIS. 
APD. 
DRW. 
DRW. 
DRW, 
PCS. 
PCS. 
DRW. 
HAL, 
KES. 
APD, 
GLD. 
SUG. 
WM. 



KES, SBC, WM. 

CCW, EK, GLY, HAL, HDG, JRG, EES, PCS, PG, WTC. 



AAC, APD, BAG, DRW, ICI, NOP, PCS, RTF, TCH, VAC, VIS. 
G. 

G, ICI, PCS. 
G. 

AAC, APD, DRW, G, GLY, JCC, NAC, CMC, PCS, UCC. 
ADM, APD, CIB, ICI. 
AAC, APD. 
G. 

APD. 

CO, JCC, RH, RTF, TCH, VIS, WW. 
AAC, ADM, APD, CIB, DUP, G, ICI, NOP, TCH. 
ACC, APD, CIB. 
MON, PAS. 
UCC, VIS. 
PCS, VIS, WYN. 
HPC. 
VAC. 
CGL. 
DUP. 
G. 

AIR. 

AAC, APD, DRW, EFH, G, ICI, JCC, MON, OMC, PCS, RTF, 
TCH, UCC, VIS. 



TABLE 19B.- 



SURFACE-ACTIVE AGENTS 

-Surface-active agents for which U.S. production or sales were 
manufacturer, i564— Continued 



167 



reported, identified by 



NONBENZENOID SURFACE -ACTIVE AGENIB— Continued 
Not Sulfated or Sulfonated--Continued 

(•■Ethers —Continued 

Tridecyl alcohol, ethoxylated and carbonated, sodium 
salt. 

Tridecyl alcohol, ethoxylated and chlorinated 

Tridecyl alcohol, propoxylated and ethoxylated 

Trimethylheptanol, ethoxylated 

Trimethylnonyl alcohol, ethoxylated 

Trimethylolpropane , alioxylated 

All other 

Fatty acids, potassium and sodium salts: 

Castor oil acids, potassium salt 

Castor oil acids, sodium salt 

»Coconut oil acids, potassium and sodium salts: 

Coconut oil acids, potassium salt 

Coconut oil acids, sodium salt 

Corn oil acids, potassium salt 

Com oil acids, sodium salt 

*Lauric acid, potassium salt 

*Mixed vegetable fatty acids, potassium salt 

*01eiG acid, potassium salt 

*01eic acid, sodium salt 

Olive oil acids, sodium salt 

Palm oil acids, sodium salt 

Peanut oil acids, potassliim salt 

*Rosin acids, sodiiim salt 

Soybean oil acids, potassium salt 

Stearic acid, potassium salt 

*Stearic acid, sodium salt 

»Tall oil acids, potassium salt 

*Tall oil acids, sodium salt 

Tallow acids, potassium salt 

Tallow acids, sodium salt 

All other 

*Phosphorlc and polyphosphorlc acid esters; 
^Alcohols, phosphated and polyphosphated: 

Deoyl, octyl phosphate 

Decyl phosphate, ethanolamine salt 

Decyl polyphosphate, sodium salt 

*2-Ethylhexyl phosphate, sodium salt 

2-Ethylhexyl polyphosphate 

Hexyl polyphosphate, potassium salt 

Mixed aliyl phosphate, diethanolamlne salt 

Mixed decyl, dodecyl, and octyl phosphate, morpholine 
salt. 

*Mixed mono- and dialiyl phosphate 

9-Octadecenyl phosphate 

Ootadecyl phosphate, ethanolamine salt 

Octyl phosphate, aliylamine salt 

*Octyl polyphosphate 

Octyl polyphosphate, potassium salt 

Octyl polyphosphate, sodium salt 

Tri(castor oil alkyl) phosphate 

Tri(mixed alkyl) phosphate 

*Other phosphoric and polyphosphorlc acid esters: 

Dodecyl alcohol, ethoxylated and phosphated 

Dodecyl alcohol, ethoxylated and polyphosphated 



Manufacturers' identification codes 
(according to list in table 22) 



S. 

G. 

JCC, PCS. 

PCS. 

UCC. 

RTF. 

JCC, VPC. 

BAG, SEA. 
MRV, SEA. 



ARL, 
CON. 
PCH. 
LUR. 
BSC, 
AMI, 
AML, 
LUR, 
LUR. 
LUR. 
KAL, 
CRT, 
CON, 
VAL. 
LEV, 
BSC, 
DEX, 
SWT. 
CON, 
SLC, 



LUR, PCH, SWT. 



DRW, NOP, VAL. 

ARL, PCH, SWT. 

BSC, CIB, DAN, DEX, EFH, NOP, 

MRV, NOP, SEA, SWT, WTC, x. 



P, S, SHP, WTC, X. 



SLC. 

MRA, QCP. 
DRW. 

MAL, NOP, SLC, WTC. 

CIN, CON, DRW, LUR, PNX, QCP, VAL. 

PCS, QCP, UNP. 

LUR, NOP, QCP, SWT. 
VAL. 



UVC. 

RCD. 

SEY. 

SEY, TCI, UCC, UVC. 

UVC. 

CST, DEX. 

DUP. 

DUP. 

CST, DUP, UVC. 

DUP. 

RCD. 

DUP, TXT. 

BCN, DEX, TXT. 

X. 

VIC. 
GLY. 
VIC. 



168 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 19B.— Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, i 564 --Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 
Not Sulfated or Sulfonated- -Continued 

*Phosphoric and polyphosphoric acid esters — Continued 
»Other phosphoric and polyphosphoric acid esters — Con. 

2-Ethylhexanol, ethoxylated and phosphated 

Mixed primary straight chain alcohols, ethoxylated and 
phosphated . 

9-Octadecenyl alcohol, ethoxylated and phosphated 

Ootyl phosphate, ethoxylated 

Propylene glycol, propoxylated and phosphated 

Tridecyl alcohol, ethoxylated and phosphated 

All other 

Other nonbenzenoid surface-active agents, not sulfated or 
sulfonated : 

3,5-Dimethyl-l-hexyn-3-ol 

3,6-Dimethyl-"+-octyne-3,6-diol 

2,<i,7,9-Tetramethyl-5-deoyne-4.,7-diol 

All other 

Sulfated and Sulfonated 

»Dicarboxylic acid amides, sulfated and sulfonated: 

N-(l,2-Dicarboxyethyl) -N-octadecylsulfosuooinamic acid, 
tetrasodiujn salt. 

N-(2-Hydroxyethyl)-N-( tallow aliyl) suLfosuooinamide 

N-OctadecylsulXosuccinamide, disodium salt 

N-(01eoyloxyisopropyl)sulfosuocinamide 

*Dicarboxylic acid esters, sulfated and sulfonated: 

*Sulfosucoinio acid, bis(2-ethylhexyl;ester 

Sulfosuocinic acid, bis(tallow monoglyceride) ester 

Sulfosuccinic acid, dihexyl ester 

Sulfosuccinic acid, dioctyl ester, sodium salt 

Sulfosuccinic acid, dipentyl ester, sodium salt 

Sulfosuocinic acid, ditrideoyl ester, sodium salt 

All other 

«ii-Dodecyl sulfate salts: 

n-Dodecyl sulfate, 2 -ami no -2 -me t hy Ipropanol salt 

*n-Dodecyl sulfate, ammonium salt 

n-Dodecyl sulfate, diethanolamine salt 

n-Dodecyl sulfate, N,N-diethylcyclohexylamine salt 

n-Dodecyl sulfate, isopropanolamine salt 

n-Dodecyl sulfate, magnesium salt 

n-Dodeeyl sulfate, potassium salt 

»n-Dodecyl sulfate, sodium salt 

*n-Dodecyl sulfate, triethanolamine salt 

*Fats, oils, and waxes, sulfated and sulfonated: 

*Castor oil, sulfonated 

*Coconut oil, sulfonated 

*Cod oil, sulfonated 

Cottonseed oil, sulfonated 

^Grease, other than wool, sulfonated 



DUP. 




APD. 




G, LUH. 




VIC, WTC. 




AIR. 




AIB. 




AIR. — 




GLY, JCC, LMI, 


STC 



SCP. 
ACY. 
WTC. 



ACY, CIN, CRC, CRT, CST, DAN, EFH, EMK, GGY, HRT, ICI , 

MOA, MRA, PC, SBC, TCI. 
ACY. 

ACY, MDA. 
RH. 
ACY. 

ACY, MOA, WTC. 
G. 

DUP. 

AAC, DUP, ONX, PCS, STP. 

AAC, CUL, DUP, HLI, JRG, ONX, STP. 

DUP. 

JRG, PCS. 

AAC, HLI. 

HLI, PG. 

AAC, DUP, HLI, JRG, MYW, ONX, PCI, PCS, PG, RCD, RET, 

STP, TXT. 
AAC, CUL, DUP, HLI, MYW, ONX, PCS, PG, RCD, RET, STP, 

TXT. 

AAE, ACT, ACY, AML, APX, BAO, BRY, BSC, CRT, DEX, DRW, 

DUP, EFH, G, HRT, ICI, KAL, KNG, LEA, LUR, MRA, MRD, 
MRV, NOP, ONX, PC, PCI, S, SCO, SCP, SEA, SLC, WHI, 
WHW. 

ACY, BAO, MRD, NOP, RTC, SEA, WHW. 

ACT, BAO, CRT, DRW, LEA, MRD, NOP, S, SEA, WAW, WHI, 
WHW. 

NOP, RTC. 

CRT, NOP, SEA, WHI, WHW. 



SURFACE-ACTIVE AGENTS 



169 



TABLE 19B. 



-Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, i56<?— Continued 



NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 
Sulfated and Sulfonated— eontiimed 

*Fats, oils, and waxes, sulfated and sulfonated — Continued 

Lard, sulfonated 

Mixed fish oils, sulfonated 

Mixed vegetable oils, sulfonated 

Mustard seed oil, sulfonated 

*Neat's-foot oil, sulfonated 

Oleostearin, sulfonated 

»Peanut oil, sulfonated 

Red fish oil, sulfonated 

«Rice-bran oil, sulfonated 

^Soybean oil, sulfonated 

»Sperm oil, sulfonated 

*Tall oil, sulfonated 

»Tallow, sulfonated 

Whale oil, sulfonated 

All other 

*Other nonbenzenoid surface-active agents, sulfated and 
sulfonated: 
Alcohols, except dodecyl, sulfated and sulfonated: 

Branched hexadeoyl sulfate, sodium salt 

n-Decyl sulfate, sodium salt 

n-Decyl sulfate, triethanolamine salt 

3,9-Diethyl-6-trideeyl sulfate 

2-Ethylhexyl sulfate, sodium salt 

7-Ethyl-2 -methyl -4— undecyl sulfate 

n-Hexadecyl sulfate 

Hexyl sulfate, potassium salt 

Mixed coconut oil alkyl and sperm oil aliyl sulfate, 
sodium salt. 

Nonyl sulfate 

n-Octadecyl sulfate — ^ 

n-Ootadecyl sulfate, sodium salt 

n-Octadecyl sulfate, triethanolamine salt 

n-Octyl sulfate, sodium salt 

n-Tetradecyl sulfate, sodium salt 

Tridecyl sulfate, sodium salt 

Alianes, sulfated and sulfonated: 

Mixed alianesulfonic acids 

Mixed alkanesulfonic acids, sodium salt— r 

Amines, fatty acid amides, and quaternary ammonium 

salts, sulfated and sulfonated: 

Fatty acid - alianolamine condensates, sulfated: 

*Coconut oil acids - ethanolamine condensate, 

sulfated, potassium salt. 

Coconut oil acids - ethanolamine condensate, 

sulfated, sodium salt. 
Laurie acid - isopropanolamine condensate, sulfated- 
Neat's-foot oil acids - ethanolamine condensate, 
sulfated, ammonium salt. 

Oleic acid - ethanolamine condensate, sulfated 

Stearic acid - diethanolamine condensate, methyl 

sulfate . 
All other 



Manufacturers' identification codes 
(according to list in table 22) 



WAW. 

AMI, EFH, SCO. 

LEA. 

LUR, NOP. 

ACT, BAO, CRT, KAL, LUR, MRD, NOP, PC, SEA, WHW. 

SEA. 

ACY, CRT, ICI, LEA, LUR, NOP, SCP, SEY, SLC, SOS. 

WHI. 

HRT, KNG, LUR, NOP-^ 

APX, CRT, DRW, HRT, KAL, LEA, MRD, ONX. 

ACT, BAO, CLD, CRT, DRW, HRT, KAL, KNG, LEA, MRD, 

NOP, ONX, RTC, S, SEA, WHI, WHW. 
ACy, APX, BAO, CRT, ICI, QCP, SEA, WHW. 
ACT, ACY, BRY, DRW, EFH, ICI, KAL, LEA, LUR, MRA, MRD, 

NOP, ONX, PC, PCI, SCP, SID, SOS, SNW, WHI. 
KNG. 
EFH. 



APX. 






DUP, 


ONX, 


PCS. 


DUP. 






UCC. 






AAC, 


UCC, 


WTC. 


UCC. 






AAC, 


DUP. 




DEX. 






DUP. 






TN. 






DUP, 


EMK, 


PG. 


ONX. 






DUP. 






DUP, 


PCS. 




ONX. 






AAC. 






VPC. 






DUP, 


WSN. 




DEX, 


EMK, 


HRT, ONX 


DEP. 






PCS. 






APX. 






SCP. 






DUP. 







170 



SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 19B. —Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer , 1964 — Continued 



NONBENZENOID SURFACE-ACTIVE AGENTS -Continued 

Sulfated <md'Sulfonated--ContinuBd 

*Other nonbenzenoid surfaoe-aotive agents, sulfated and 
sulfonated --Continued 
Amines, fatty acid amides, and quaternary ammonium 
salts, sulfated and sulfonated--Continued 
Quaternary ammonium salts, sulfated and sulfonated: 

N-Aliyl dimethyl ethyl ammonium ethyl sulfate 

(2-Aminoethyl)ethyl(hydrogenated tallow alkyl)(2- 

hydroxy ethyl) ammonium ethyl sulfate. 
Bis(hydrogenated tallow alkyl)dimethylammonium 
methylsulf ate . 

Dlmethyldloctadeoylammonlum methyl sulfate 

l-Ethyl-2-(8-heptadeoenyl) -l-(2-hydroxyethyl) -2- 
Imidazollnlum ethyl sulfate. 

N-Ethyl-N-hexadecylmorpholinium ethyl sulfate 

N-Ethyl-N-( soybean oil alkyl) morpholinium ethyl 

sulfate. 
2-Heptadecyl-l-(2-stearamidoethyl)-2-lmadazollnium 

methyl sulfate. 
(3-Lauramidopropyl)trlmethylammonlum methyl sulfate- 

Mlxed aliyl sulfobetalnes 

Trlmethyl(3-oleamldopropyl) ammonium methyl sulfate- 
Taurine derivatives: 

N-Cyclohexyl-N-palmitoyltaurine 

N-Methyl-N-( coconut oil aoyl) taurine 

«-N-lfethyl-N-oleoyltaurlne 

N-Metl^l-N-palmltoyltaurine 

N-Methyl-N-(tall oil aoyl) taurine, sodium salt 

N-Methyl-N-( tallow acyl) taurine 

Other amines, fatty acid amides, and quaternary 
ammonium salts, sulfated and sulfonated: 
N-( 2-Hydroxyethyl) -N, N ' , N' -tris ( 2-hydroxypropyl) - 

ethylenediaraine , distearate methyl sulfate. 
Laurie acid, 2-sulfoaoetamidoethyl ester, potassium 
salt. 

N-(Mixed alkyl sulfonyl) glycine, sodium salt 

Mixed primary amines, ethoxylated and sulfated 

Oleic acid - ethylenedlamine condensate, propoxy- 

lated and sulfated, sodium salt. 
Stearic acid - ethylenedlamine condensate, mono- 

ethoxylated, ethyl sulfate. 
Tall oil acids - polyalkylenepolyamine condensate, 

sulfated. 
N, N, N ', N ' -Tetraiis ( 2-hydroxypropyl) ethylenedlamine 
dioleate methyl sulfate. 
Ethers, sulfated and sulfonated: 

n-Dodecyl alcohol, ethoxylated and sulfated, ammonium 
salt. 
»n-Dodecyl alcohol, ethoxylated and sulfated, sodium 
salt. 
n-Dodecyl alcohol, ethoxylated and sulfated, trl- 
ethanolamine salt. 

Hexyloxypropyl sulfate, sodium salt 

Mixed primary straight chain alcohols, ethoxylated 

and sulfated. 
Mixed primary straight chain alcohols, ethoxylated 

and sulfated, ammonium salt. 
Sperm oil alcohol, ethoxylated and sulfated 



Manufacturers ' identification codes 
(according to list in table 22) 



JOR. 
LUR. 



ONX. 
APD. 



APD. 
APD. 



ACY. 
TXT. 
CIB. 



ORG, CRT, DEP, DRW, G, HRT, MRA, NOP, VAL. 



AAC, DUP, ONX, PCS, RCD, RET, TXT. 



PG. 



SURFACE-ACTIVE AGENTS 

TABLE 19B.— Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1964— Continued 



171 



NONBENZENOID SURFACE-ACTIVE AGENTS —Continued 
Sulfated and 5ui/onaf ec/--Continued 

*Other nonbenzenoid surface-active agents, sulfated and 
sulfonated — Continued 
Ethers, sulfated and sulfonated — Continued 

Tridecyl alcohol, ethoxylated and sulfated, ammonium 

salt. 
Tridecyl alcohol, ethoxylated and sulfated, sodium 
salt. 

All other 

Fatty acids, sulfated and sulfonated: 

Acetyloleic acid, sulfonated 

*01eic acid, sulfonated 

Rioinoleic acid, sulfonated 

Fatty acid esters, sulfated and sulfonated: 

2-Butoxyethyl sulfo-oleate 

*Butyl sulfo-oleate 

Butyl sulforicinoleate 

Coconut oil isethionate 

Coconut oil isethionate, sodium salt 

Dodeoyl sulfoacetate 

Ethyl sulfo-oleate 

Glycerol mono( coconut oil) ester, sulfated, ammonium 

salt. 
Glycerol mono( coconut oil) ester, sulfated, sodium 
salt. 

Glycerol monostearate sulfoacetate 

Glycerol tri( sulfo-oleate) 

*Isopropyl sulfo-oleate 

2-Lauroyloxy-l-propanesulfonic acid 

Methyl sulfo-oleate 

^Propyl sulfo-oleate 

All other 



Manufacturers' identification codes 
(according to list in table 22) 



LEV. 

AAC, ARL, RCD. 

APX, PG. 

DUP. 

ACT, ACY, BRY, CRT, DRW, EMR, G, ICI, LEA, LUR, MRV, 

NOP, PCI, QCP, SCO, TN, WHl, WHW. 
NOP. 



AML, CIN, ICI, NOP, ONX, PC. 

NOP. 

DRW. 

G, LEV. 

NAC. 

G, KAL. 

CP. 

CP. 

WTC. 

ACT, MRV, SCP. 

BRY, DEX, EMR, HRT, ICI, LEA, LUR. 

SDH. 

ICI. 

ACY, BSC, CHL, EFH, MRV, WM. 

EMR. 



172 



SYNTHETIC ORGANIC CHEMICALS, 1964 



Pesticides and Other Organic Agricultural Chemicals 

TABLE 20B. — Pesticides and other organic agricultural chemicals for which U.S. production or sales were 
reported, identified by manufacturer , 1964 

[Pesticides and other organic agricultural chemicals for which separate statistics are given in table 20A are marked 
below with an asterisk (»); products not so marked do not appear in table 20A because the reported data are ac- 
cepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from 
table 22. An x signifies that the manufacturer did not consent to his identification with the designated product] 



Manufacturers ' identification codes 
(according to list in table 22) 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICALS, OrCLIC 

^Fungicides : 

2,6-Bis(dimethylaminomethyl)cyclohexanone 

5-Chloro-2-mercaptobenzothiazole, lauiylpyridium salt 

2,<V-Dichloro-6-o-chloroanilino-s-triazine 

2,3-Dichloro-l,<*-naphthoquinone (Dichlone) 

Diphenylammonium propionate 

3,3' -Ethylenebis ( tetrahydro-^ , 6-dimethyl-2H-l, 3,5,5- 
thiadiazine-2-thione) . 

2-Heptadecyl-2-imidazoline acetate (Glyodin) 

2-Mercaptobenzothiazole, monoethanolamine salt 

*Mercury fungicides : 

2-Chloro-4-(hydroxymercuri)phenol 

Chloromethoxypropylmercuric acetate 

N-(Ethylmercuri)-p-toluenesulfonanilide 

1,4,5,6 , 7, 7-Hexachloro-N- ( ethylmercuri ) -5-norbomene- 
2, 3-dicarboximide. 

'i-(^ydroxymercuri)-2-nitrophenol 

8-(Methylmercurioxy)quinoline 

2 - ( Phenylmercuriamino ) ethyl acetate 

Phenylmercuriammonium acetate 

N-Phenylmercuriformamide 

Phenylmercury hydroxide 

Phenylmercury lactate 

Phenylmercury naphthenate 

Phenylmercury oleate 

Phenylmercury propionate 

Tris(2-hydroxyethyl) (phenylmercuri)aiiimoniuin lactate — 

2-(l-Methylheptyl)-4,6-dinitrophenyl crotonate 

»Naphthenic acid, copper salt 

Pentachloronitrobenzene 

*Pentachlorophenol (PCP) 

Pentachlorophenol, sodium salt 

8-Quinolinol (8-Hjrdroxyquinoline), copper salt 

Tetrachloro-p-benzoquinone ( Chloranil) 

2,3,4,6-Tetrachlorophenol 

Tetrahydro-3,5-dimethyl-2H, l,3,5-thiadiazine-2-thione 

N- ( Trichloromethylthio ) -<4-cyclohexene-l, 2-dicarboximide 
(Captan) . 

N-( Trichloromethylthio )phthalimide (Folpet) 

*2,4,5-Trichlorophenol 

■t2,'4,5-Trichlorophenol, ethanolamine salt 

»2,4,5-Trichlorophenol, sodium salt 

2,4,6-Trichlorophenol 

^Herbicides and plant hormones : 

5-Bromo-3-sec-butyl-6-methyluracil 

5-Bromo-3-isopropyl-6-methyluracil 

l-Butyl-3-(3,4-dichlorophenyl)-l-methylurea (Neburon) 

*2-sec-Butyl-4,6-dinitrophenol (DNBP) 

*2-sec-Butyl-4,6-dinitrophenol, ammonium salt 

2-seo-Butyl-4,6-dinitrophenol, triethanolamine salt 

2-sec-Butyl-4,6-dinitrophenyl-3,3-dime thy lacry late — 

2-sec-Butyl-4,6-dinitrophenyl-3-methyl-2-butenoate 
(Binapacryl). 

2-Chloro-4, 6-biE(ethylamino)-s-trlazine (Simazine) 

4-Chloro-2-butynyl m-chlorocarbanilate (Barban) 

2-Chloro-4-ethylamino-6-isopropylamino-s-triazine 

( Atrazine ) . 
N- ( 3- Chloro-4-methylphenyl ) -2-methylpentanamide ( Solan ) - 



MTL. 
VNC. 
CHG. 
USR. 
MTL. 
DUP. 

UCC. 
VNC. 

DUP. 
TRC. 
DUP. 
RBC. 

DUP. 

MTL. 

CLY. 

GUA, 

VIN. 

WRC. 

WflC. 

MTL. 

CLY, 

MTL. 

CLY. 

RH. 

CCA, 

MON, 

BXT, 

DOW, 

GAM, 

USR. 

DOW. 

CLY, 

CHO. 



HNX, MTL, TRO, TOC. 



FER, HNX, MCI, MLD, SM, SOC, SRR, TGL, TRO, WTC. 

CMC. 

DOW, FRO, ION, RCI. 

M3N, RCI. 

HNX, MTL. 



MTL, SF. 



CHO. 

DA, DOW, HK. 

G. 

DOW. 

DOW. 

DUP. 

DUP. 

DUP. 

CIS, DOW, FMN, TNA. 

CIS, DOW, FMN. 

CIS, DOW, FMN. 

FMP. 

FMN. 

GGY. 
SPN. 
GGY. 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS 



173 



TABLE 20B. — Pesticides and other organic agricultural chemicals for which U.S. production or sales were 
reported, identified by manufacturer , 1964 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICALS, CYCLIC- -Continued 

*Herbioides and plant hormones — Continued 

3-(p-Chlorophenyl)-l, 1-dlmethylurea (Mjnuron) 

3-(p-Chlorophenyl)-l, 1-dimethylurea triohloroacetate 

Chlorophenyl-N-methylcarbamate 

2,5-Dichloro-3-aiiilnobenzoic acid, ainmonlum salt 

3,6-Dichloro-2-anisio acid 

2,5-Dlohloro-3-nitrobenzoic acid 

2-(2,4-Diohlorophenoxy)ethanol sulfate, sodium salt 

3- (3, ■4-Dichlorophenyl)-l, 1-dimethylurea (Dluron) 

N-(3,4-Diohlorophenyl) methaorylamide (Dicryl) 

3-(3,4-Dichlorophenyl)-l-methoxy-l-methylurea ( linuron)- 

2,4-Dichlorophenyl-4-nitrophenyl ether 

3,4-Dichloropropionanilide 

l,2-Dihydro-3,6;pyTidazinedione (Maleic hydrazide) 

N,N- Dimethyl -2, 2-diphenylacetamlde ( Diphenamide ) 

1, l-Dimethyl-3-phenylurea (Fenuron) 

1, l-Dimethyl-3-phenylurea trichloroaoetate 

Dimethyl tetraohloroterephthalate 

4,6-Dlnitro-o-oresol (DNOC) 

<i,6-Dlnitro-o-cresol, sodium salt 

Dlphenylacetonitrile 

N, N-Dipropyl-2,6-dinltro-'i-trifluoromethyl aniline 

Gibberellic acid 

3- ( Hexahydro-4-, 7-methanoindan-5-yl) - 1, 1-dimethylurea 
(Norea). 

Indolebutyric acid 

Isopropyl oarbanilate (Isopropyl N-phenyloarbamate ) 

(IPC). 
Isopropyl 3-chlorocarbanilate (Isopropyl N-(3-ohloro- 

phenyl) carbamate) (CIPC). 
1-Naphthaleneacetlc acid and derivatives : 

1-Naphthaleneacetamide 

1-Naphthaleneaoetic acid 

1-Naphthaleneacetic acid, methyl ester 

1-Naphthaleneacetio acid, sodium salt 

2-Naphthyloxyacetic acid 

2-Naphthyloxyaoetic acid, sodium salt 

N-1-Naphthylphthalamic acid (NPA) 

7-Q)cabicyclo[2.2.1]heptane-2,3-dicarboxylio acid, 

disodium salt ( Qidothal) . 
Ehenoxyacetic acid derivatives: 

(4-Chloro-o-tolyloxy)acetic acid (MCPA) 

(4-Chloro-o-tolyloxy)acetic acid, potassium salt 

*(2,'4-Dichlorophenoxy)acetic acid (2,4-D) 

»( 2, A-Dichlorophenoxy) acetic acid esters and salts: 
( 2, "i-Dlchlorophenoxy) acetic acid, 2-butoxyethyl 

ester. 
(2,<i-Dichlorophenoxy)acetic acid, butoxypolypropyl- 
eneglycol ester. 

»(2,4-Diohlorophenoxy)acetic acid, n-butyl ester 

(2,4-Dlchlorophenoxy)acetic acid, sec-butyl ester 

«{2,4-Dichlorophenoxy)aoetic acid, dimethylamine salt 
(2,4-Dichlorophenoxy)acetic acid, ethanolamlne and 
isopropanolamine salt. 

»(2,4-Dichlorophenoxy)acetic acid, ethyl ester 

( 2, 'i-Diohlorophenoxy) acetic acid, 2-ethylhexyl ester 

»(2,4-Dlchlorophenoxy)acetio acid, iso-octyl ester 

*{2,'4-Dlchlorophenoxy)acetic acid, isopropyl ester 

(2,A-Dlchlorophenoxy)aoetio acid, lithium salt 

(2,4— Dlchlorophenoxy) acetic acid, sodium salt 

All other (2,'i-Dichlorophenoxy)acetio acid esters 
and salts. 



DUP. 
ACG. 

X. 

G. 

VEL. 

G. 

G. 

DUP. 

FMN. 

DUP. 

X. 

MON, X. 

ACY, USR. 

LIL. 

DUP. 

ACG. 

DA. 

CIS, FMN. 

CIS, FMN. 

LIL. 

X. 

ABB, MRK. 
HPC. 

AHA. 
PPG. 



AMC. 








AMC, 


COK. 






AMC. 








AMC, 


BKL. 






BKL. 








BKL. 








USR. 








PAS. 








CHC, 


DOW. 






GTH. 








CHC, 


DA, DOW, 


HPC, 


MON 



AMC, 


DA, 


DOW, HPC, IMR, MON, 


RIV. 


CHC. 








ALC, 


AMC, 


CHC, DA, DOW, HPC, 


RIV, TMH 


CHC, 


DOW. 






AMC, 


DOW, 


MON. 




DA, 


HPC. 






CHC, 


DOW, 


MON, RIV, TMH. 




AMC, 


CHC, 


DA, DOW, HPC, MON, 


RIV. 


GTH. 








DOW. 








CWN. 









174 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 20B.- 



■ Pesticides and other organic agricultural chemicals for which U.S. production or sales were 
reported, identified by manufacturer, i 964- -Continued 



PESTICIDES AM) OTHER ORGANIC AGRICULTURAL 
CHEMICAI£, CYCLIC--Continueci 

*Herbicldes and plant hormones — Continued 
Phenoxyacetio acid derivatives--Contlnued 

4_(2,<i-Dichlorophenoxy)butyric acid, dimethylamine 
salt. 

»(2,4,5-Triclilorophenoxy)aoetic acid (2,4,5-T) 

*(2,'4,5-Trichloroplienoxy)aoetic acid esters and salts: 

(2,4,5-Triohlorophenoxy)aoetio acid, amyl ester 

(2,4,5-Trlchlorophenoxy)aoetio acid, 2-butoxyethyl 

ester. 
(2,4,5-Triohlorophenoxy)acetic acid, butoxypoly- 
propyleneglycol ester. 
*(2,4,5-TricW.orophenoxy)acetic acid, n-butyl ester— 
(2,'i,5-Triohlorophenoxy)acetio acid, sec-butyl ester 
(2,4,5-Trichlorophenoxy)aoetic acid, 2-ethylliexyl 
ester. 
*(2,4,5-Trichlorophenoxy)acetic acid, iso-octyl ester 
(2,'i,5-Triohlorophenoxy)acetio acid, isopropyl ester 
*(2,4,5-Triohlorophenoxy)aoetic acid, triethylamine 
salt. 

All other phenoxyacetic acid derivatives 

*Phenylmercury acetate (PMA) 

Polyehloro-tetrahydro-methanoindene (Polychlorodicyclo- 
pentadiene) isomers. 

N-Tolylphthalamic acid 

Tributyl(2,4-dichlorobenzyl)phosphonium chloride 

2-(2,'4,5-Trichlorophenoxy)propionic acid (Silvex) 

2-(2,4,5-Triohlorophenoxy)propionic acid, 2-ethylhexyl 

ester. 
2-(2,4-,5-Trichlorophenoxy)propionic acid, triethenol- 
amine salt. 

Tris[2-(2,4-diohlorophenoxy)ethyl]phosphite (2,4-DEP) 

All other cyclic herbicides and plant hormones 

Insect attractants: 

4-(p-Acetoxyphenyl)-2-butanone 

tert-Butyl 4(and 5)-chloro-2-methylcyclohexane- 
carboxylate . 
^Insecticides : 

Allethrin (Allyl homolog of Cinerin I) 

Benzyl thiocyanate 

Chlorinated insecticides : 
*Aldrin-toxaphene group : 

Heptachloro-tetrahydro-methanoindene (Heptachlor) 

Hexachloro-epoxy-octahydro-endo, endo-dimethano- 

naphthalene (Endrin) . 
Hexachloro-epoxy-octaliydro-endo, exo-dimethano- 

naphthalene (Dieldrin) . 
Hexachloro-hexahydro-endo, exo-dimethanonaphthalene 
(Aldrin) . 

Octahydro-tetrahydro-methanoindan (Chlordan) 

Terpene polychlorinates 

Toxaphene (Chlorinated caraphene) 

l,l-Bis(p-chlorophei]yl)-2-nitrobutane 

l,l-Bis(p-chlorophenyl)-2-nltropropane 

2-(p-tert-Butylphenoxy) -1-methylethyl 2-chloroethyl 
sulfite. 

p-Chlorophenyl p-ohlorobenzenesulfonate (Ovex) 

p-Chlorophenyl 2,4,5-triohlorophenyl sulfone 

4,4'-Dichlorobenzilate 

l,l-Dichloro-2,2-bis(p-chlorophenyl)ethane (DDD) (TDE) 

l,l-Dichloro-2,2-bis(p-ethylphenyl) ethane 

4,4'-Dichloro-a-(trichloromethyl)benzhydrol 

*Hexaohlorocyclohexane (Benzene hexaohloride ) 

*Hexachlorocyclohexane , 100^ y-isomer (Lindane) 

Hexaohloro-hexahydro-methano-benzodloxathiepinoxide 
(Endosulfan). 



Manufacturers ' identification codes 
(according to list in table 22) 



DA, DOW, HPC, ION. 



HPC. 
AMC. 



DA, 

MON. 

DA, 

DOW, 
DA, 
CIS, 

TMH. 
BKM, 
VEL. 

USR. 
VC. 
DOW, 
HPC. 



USR. 
ARA, 



TBK. 
TBK. 



DOW, HPC, ION, RIV. 

HPC. 

, MON, RIV, TMH. 

MDN. 

, DOW, HPC, RIV. 

CLY, GUA, MIL, TRO, WRC. 



DUP, HPC, SF. 



VEL. 
SHC, VEL. 



VEL. 
HN. 
HPC. 
COM. 

COM. 
USR. 



CIS, DOW. 

FMN, FMP. 

GGY. 

ACG, RH. 

RH. 

RH. 

DA, FRO, HK, PPG. 

HK. 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS 



175 



TABLE 20B. 



-Pesticides and other organic agricultural chemicals for which U.S. production or sales were 
reported, identified by manufacturer, 1964 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICALS, CYCLIC— Continued 

^Insecticides — Continued 

♦Chlorinated insecticides — Continued 

»l,l,l-Triohloro-2,2-bis(p-chlorophenyl)ethane (DDT) 

l,l,l-Trichloro-2,2-bis(p-methoxyphenyl)ethane 
( Ifethoxychlor ) . 

All other chlorinated insecticides 

N,N-Diethyltoluaniide 

Isohomyl thiocyanatoacetate 

1-Naphthyl methylcarhamate 

*Organophosphorus insecticides : 

A-tert-Butyl-2-chlorophenyl methyl methylphosphor- 

amidate . 
2-Chloro-l-(2,'l-diohlorophenyl)viiiyl diethyl phosphate 
0-(3-Chloro-'4-niethyl-2-oxo-2H-l-benzopyran-7-yl) 0,0- 

diethyl phosphorothioate . 
S-(p-Chlorophenylthio)methyl 0,0-diethyl phosphoro- 

dithioate (Carbophenothion). 
0,0- Diethyl 0-(2-isopropyl-4-methyl-6-pyrimldinyl 
phosphorothioate (Diazinon). 
*O,0-Diethyl O-(p-nitrophenyl) phosphorothioate 
(Parathion) . 
0,0-Dliiiethyl 0-[4-(methylthio)-ni-tolyl] phosphoro- 
thioate . 
0,0- Dimethyl O-(p-nitrophenyl) phosphorothioate 
(Methyl parathion). 
0,0-nimethyl S-(4-oxo-l,2,3-benzotriazin-3(4H)- 

ylmethyl) phosphorodithloate . 
0,0-IlLmethyl 0-(2,4,5-trichlorophenyl) phosphoro- 
thioate (Ronnel). 

p-Dioxane-2,3-diyl ethyl phosphorodithloate 

0-Ethyl O-(p-nitrophenyl) phenylphosphonothioate 

a-Methylbenzyl 3-hydroxycrotonate, dimethyl phosphate 
ester. 

All other organophosphorus insecticides 

Nematocides: 0-2,'4-Dlchlorophenyl 0,0-diethyl phosphoro- 
thioate . 
*iiDdenticides : 

3-(Aoetonylbenzyl)-<t-hydro2ycoumarin 

2-Isovaleiyl-l, 3-indandione, calcium salt 

2-Plvaloyl-l,3-indandione 

PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICALS, ACYCLIC 

♦Fungicides : 

Bis-l,4-bromoacetoxy-2-butene 

Bis(trichloromethyl)sulfone 

Cadmium succinate 

l-Chloro-2-nitropropane (Korax) 

3,3-Diacetoxypropene-l 

Disodium oyanodlthioimldocarbonate 

Dithiocarbamic acid fungicides : 

♦Dimethyldithiocarbamlo acid, ferric salt (Ferbam) 

Dimethyldithiocarbamic acid, manganese salt 

Ethylene bis(dithiocarbaniic acid), diammonium salt 

♦Ethylene bis(dithiocarbaiiiic acid), disodium salt 
( Nabam) . 



DA, GGY, LEB, MTO, CMC, RBC. 



USR. 
PFZ. 
CIS, HPC. 



ACG, 
DUP. 

LIL, 
HPC, 
BKC, 
UCC. 

DOW. 

SHC. 
CHG. 

SF. 



GGY. 

ACY, AMP, MON, SHC, VIC. 

CHG. 

AMP, MON, SHC, VIC. 

CHG. 

DOW. 

HPC. 
VIC. 
SHC. 



ABB, PEN. 
MOT. 
MOT, PIC. 



VIN. 

SF. 

MAL. 

FMN. 

SHC. 

BKM. 

DUP, FMN, RBC, WRC. 

FMN. 

CIS, RBC. 

CIS, DUP, FMN, RBC, RH. 



176 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 20B. 



Pesticides and other organic agricultural chemicals for which U.S. production or sales were 
reported, identified by manufacturer, i 564 —Continued 



PESTICIDES ANB OTHER ORQAHIC AGRICULTURAL 
CHEMICALS, ACYCLIC— Continued 

» Fungicides-- Continued 

Dithiocarbamic acid fungicides— Continued 

Ethylene bis( dithiocarbamic acid), manganese salt 
(Maneb). 
^Ethylene bls{ dithiocarbamic acid), zinc salt (.ZinebJ — 

Polyethylenethiuram disulfide (PETD) 

Dodeoylguanidlne acetate (Dodine) 

Mercury fungicides : 

3-Ethyl(mercurithlo)-l,2-propanediol 

Ethylmercury acetate 

Ethy Mercury chloride 

Ethylmercury phosphate 

Ifydroxyethylmercury acetate 

3-Methyl(mercurlthio)-l,2-propaiiediol 

Methylmercury acetate 

Methylmeroury hydroxide 

Methylmercury nitrile 

All other acyclic fungicides 

^Herbicides and plant hormones : 

Cacodylic acid 

2-Chloroallyl diethyldithiocarbamate (CDEC) 

N,N-Diallyl-2-chloroacetamde (CDAA) 

2,3-Dichloroallyl diisopropylthiocarbamate 

2,2-Dichloropropionic acid, sodium salt 

Diethyl dithiobis(thionoformate) 

S-Ethyl dipropylthiocarbamate (EPTC) 

Hexachloroacetone 

»Methanearsonic acid, disodium salt 

Methanearsonic acid, dodecyl- and octylaramonium salts 

Methanearsonic acid, monosodium salt 

Methanearsonic acid, sodium salt 

S- Propyl butylethylthlocarbamate 

S,S,S-Tributyl phosphorotrithioate 

Tributyl phosphorotrithioite 

Trichloroacetic acid, sodiiim salt (TCA) 

2,3,3-Trlchloroallyl diisopropylthiocarbamate 

All other acyclic herbicides and plant hormones 

*Insectioides : 

2-(2-Butoxyethoxy)ethyl thiooyanate 

Butoxypolypropylene glycol (Fly repellent) 

Metaldehyde 

»Organophosphorus insecticides: 

Bis(dialkoxyphosphinothioyl) disulfides 

S-[l,2-Bis(ethoxycarbonyl)ethyl] 0,0-dimethyl phos- 

phorodithioate (Malathlon). 
l,2-Dibromo-2,2-diohloroethyl dimethyl phosphate 
(Naled). 

2,2-Dichlorovinyl dimethyl phosphate (DDVP) 

0,0- Diethyl S- [2- ( ethylthio ) ethyl] phosphorodlthioate- 
0,0-Diethyl 0-[2-(ethylthio)ethyl1 phosphorothioate— - 
0,0-Diethyl S- [2- ( ethylthio ) ethyl] phosphorothioate- -- 
0,0-Diethyl S-[( ethylthio )methyl] phosphorodithioate-- 

0,0- Diethyl phosphorochloridothioate 

Diethyl phosphorochloridothionate 

Dimethyl 3-hydroxycrotonate, dimethyl phosphate ester- 
0,0- Dimethyl phosphorochloridothioate 



Ifenufacturers ' identification codes 
(according to list in table 22) 



CIS, DUP, RH. 

CIS, DUP, FMN, RH. 

FMN. 

ACT. 

DUP. 
DUP. 
DUP. 
DUP. 
WHC. 
DUP. 
DUP. 
MRT. 
WRC. 
MLD. 

ASL. 
MON. 
MON. 



DOW. 

RBC. 

SF. 

ACG. 

ASL, 

CLY, 

ASL. 

VIN. 

SF. 



CHG. 

VC. 

DOW. 

MON. 

LIL, 



UCC. 
COM. 



FMN. 
ACY. 



SHC. 
CHG. 
CHG. 
CHG. 
ACY. 
MON. 
VIC. 
SHC. 
MDN. 



CLY, VIN. 
VIN. 



SF, UCC, USR, VIN. 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS 



177 



TABLE 20B. 



-Pesticides and other organic agricultural chemicals for which U.S. production or sales were 
reported, identified by manufacturer, i564--Continued 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICAI^, ACYCLIC— Continued 

*Inseotioides — Continued 

*Organophosphorus insecticides — Continued 

Dimethyl phosphorochloridothionate 

Ethyl methylene phosphorodithioate (Ethion) 

»Ethyl pyrophosphate (Tetraethyl pyrophosphate) (TEPP) 
S-2-(Ethylsulfinyl)ethyl 0,0-dimethyl phosphoro- 
dithioate . 
Methyl 3-hydroxycrotonate, dimethyl phosphate ester--- 

All other organophosphorus insecticides 

2-Thiooyanatoethyl laurate 

■xRodentioides: Sodium fluoroaoetate 

*Soil conditioners: Polyacrylonitrile, hydrolyzed, sodium 

salt. 
*Soil fumigants: 

*Bromomethane (Methyl bromide) 

Chloropiorin (Trichloronitromethane) 

*l,2-Dibromo-3-chloropropane 

1,3-Dichloropropene 

1,3-Dichloropropene, 1,2-dichloropropane 

N-Methyldithiooarhamic acid, sodium salt 



Manufacturers' identification codes 
(according to list in table 22) 



VIC. 

FMNj EMP. 
ALC, AMP, OTH. 
CHG. 

SHC. 
ACY. 

X. 

RBC. 
ACY. 



AMP, DOW, FRO, GTL, MCH. 

DOW, IMC. 

AMP, DOW, SHC. 

DOW. 

DOW, SHC. 

DUP, SF, X. 



178 



SYNTHETIC ORGANIC CHEMICALS, 1964 



Miscellaneous Chemicals 



TABLE 21B.- 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer , 1964 



[Miscellaneous chemicals for which separate statistics are given in table 21A are marked with an asterisk (■•*); 
chemicals not so marked do not appear in table 21A because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes shown below are taken from table 22. Jto x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, CYCLIC 

6-Acetoxy-2,4-dimethyl-m-dioxane 

Adenine 

Adenosine derivatives 

Alkylpiperazine quaternary ammonium compounds 

2-Aminobenzothiazole 

l-(2-Aminoethyl)piperazine 

Aminopropylmorpholine 

Aryldiamines, mixed 

Barium octylphenate 

Benzoic acid salts: 

Aluminum benzoate 

Ammonium benzoate 

Bari\mi benzoate 

Cadmium benzoate 

Calcium benzoate 

*Sodium benzoate, tech 

*Sodium benzoate, U. S.P 

Zinc benzoate 

All other 

p-Benzoquinone (p-Quinone) 

Benzothiazole 

^Benzoyl peroxide 

Benzoylresorcinol 

Bibenzyl (Dibenzyl) 

Biological stains 

2,6-Bis(C5-C2o alkyl)-p-cresol 

Bis(2,'4-dichlorobenzoyl) peroxide 

Bis[l-(2-methyl)aziridinyl]phenyl phosphine oxide 

1,'4-Bis[ 2- (A-me thy 1-5-phenyloxazolyl)] benzene 

l,'4-Bis[2-(5-phenyloxazolyl)] benzene 

Boron fluoride-phenol complex 

a-[2-(2-Butoxyethoxy)ethoxy] -4,5-methylenedioxy-2-propyl- 
toluene (Piperonyl butoxide) . 

*Butyl benzoate 

p-tert-Butylbenzoic acid, barium bis-salt 

(n-Butylcyclopentadienyl-cyclopentadienyl) iron 

2(and 3)-tert-Butyl-i-methoxyphenol 

p-tert-Butyl-a-methylcinnamaldehyde 

tert-Butyl peroxybenzoate 

4-tert-Butylpyrocatechol 

Camphene 

d-Camphor-p-sulfonic acid 

Catecholdisulfonio acid, disodium salt 

Cellulose acetate phthalate 

Centralite-1 (N, N'-Diethyl-N, N'-diphenylurea) 

Chemical indicators 

Chemical reagents 

Chloramine B (, Sodium derivative of N-chlorobenzenesulfon- 
amide) . 

Chlorinated terphenyls 

o-Chlorobenzylidenemalononitrile 

Chlorophyllin, sodium-potassium-copper 

Cobalt phthalocyaninedisulfonic acid 

Copper phthalocyaninedisulfonic acid 

Cumene hydroperoxide 

Cyanuric acid 

Cyolohexanone peroxide 



GIV. 

KF. 

PLB, SBR. 

HOU. 

FMT. 

JCC. 

JCC. 

DA. 

CCA. 



GAM. 
CCW. 
CCW. 
QIC. 



HN. 

HK, HN, MON, TNP. 

CCW. 

PLB. 

EKT. 

ACY. 

AZT, CAD, NOC, OXY, RCI, SDH, UPR, WTL. 

BKL, G. 

GIV. 

HLC, NAC. 

EKT. 

CAD, OXY. 

ICO. 

ARA. 

ARA. 

ACG. 

FMN, FMP. 



CIN, 
CCA. 
ARA. 
EKT, 
GIV. 
WTL. 
BKL, 
GLD, 
ARA. 
ICO. 

X. 

OTC, 
EK, 
ACG, 
NES. 



FRO, TNP. 



DOW. 
HPG. 



PAS. 
HLC, LAM, NAC. 
EK, GFS, HLC, LAM, NAC, PIC. 



KPT. 
GAM. 
KCH. 
NAC. 
NAC. 
HPC. 
FMB. 
NOC, UPR, WTL. 



MISCELLANEOUS CHEMICALS 

TABLE 21B. -Miscellaneous chemicals for which U.S. production or sales were reported identified bv 

manufacturer, i 564 —Continued ' 



179 



MISCELLANEOUS CHEMICALS, CYCLIC— Continued 

Cyclohexene-l,2-dioarboxyliG acid (Tetrahydrophthalio 
acid) disubstituted, polyester salts: Barium and cadmlu 
salts . 

1,4-Cyclohexylenedimethanol 

^Cyclopropane 

Cytidine and derivatives 

Decahydronaphthalene (Decalin) 

Decyl diphenyl phosphite 

2,5-Di-tert-ainylhydroquinone 

l,4-Diazabicyclo[2.2.2] octane ( Triethylenediamine ) 

Diazodinitrophenol 

l,3-Dibromo-5,5-dimethylhydantoin 

3,5-nibrofflo(and 3j4',5-tribroino)salicylanilide 

4',5-Dibroiiio(and 3,4',5-tribromo)salicylic acid 

2, 6-Di-tert-butyl-p-eresol : 

*Food grade 

«Tech -.VSSS.". 

2,5-Di-tert-butylhydroquinone . 

ZjS-Di-tert-butylquinone 

Dibutyltinbis(cyolohexyl maleate) 

2j 6-Dichlorobenzaldehyde oxime 

l,3-Diohloro-5,5-dimethylhydantoin 

Dichloro-s-triazine-2, 4, 6( IH, 3H, 5H) trione ( niohloroiso- 

cyanuric acid) . 
nichloro-s-triazine-2,4,6(lH,3H,5H)trione, potassium salt- 

nlohloro-s-triazine-2,4,6(lH,3H,5H)trione, sodium salt 

Dioyclohexylammonium nitrite 

Mcyclopentadienyloobalt 

Dicyclopeutadienyliron 

Dideoyl phenyl phosphite 

Digitonin 

2,2'-Dihydroxy-<i,4.'-dimethoxybenzophenone 

2,6-mhydroxylsonicotinic acid (2,6-Dihydroxy-4-carboxy- 
pyridine ) . 

2>2'-Dihydroxy-4-methoxybenzophenone 

2)2'-nihydroxy-4-(ootadecyloxy)benzophenone 

3,4-Dihydroxyphenylacetic acid 

3,5-Diiodosalicyllc acid 

Misopropylbenzene hydroperoxide, mixed isomers 

Dilsopropyl-m,p-oresols ; 

Diisopropyl-m,p-cresols, mixed 

p-Dimethoxybenzene (Dimethyl ether of hydroquinone ) — 

2,5-Dimethyl-2,5-di(peroxyphenyl)hexane 

2,5-Dimethylhexane-2,5-di(peroxybenzoate) 

DLmethyljnorpholine 

4,4-mnitrocarbanilide-4,6-diiiiethyl-2-pyrimldinol 

rdoxane (1,4- methylene oxide) 

2,5-ia.phenyl-p-benzoquinone 

M-phenyloxazole 

Diphenyl phosphite 

l>3-Ei--o-tolylthlourea 

4-Dodeeyloxy-2-hydroxybenzophenone 

Hizymes : 

l^rolytic : 

Amylases 

Proteases 

Other I.IIII 

Nonhydrolytio 

Other IIIIIIII. 

l,2-Epoxy-3-phenoxypropane (Glyoidyl phenyl ether) 

6-Ethoxy-m-anol (Propenylmethylguaethol) 

5-Ethyl-10,10-diphenylphenylphenazasiline 

Ethylenediaminebis[o-hydroxyphenylacetio acid], monosodium 

ferric salt. 

Ethylglucosyl p-aminobenzoate 

2-Ethylhexyl oetylphenyl phosphite 

2-Ethylhexyl salicylate 

2-Ethylhexyl tallate 

Ethyl hydrocaffeate 

*Ethylmorpholine 

Fenchone 



Manufacturers ' identification codes 
(according to list in table 22) 



EKT. 

MAL, OH, OMS, TAE. 

PLB, SBR. 

DUP. 

HK. 

EKT. 

HOU. 

HPC. 

AHA. 

FIN. 

FIN. 

CAT, EKT, HPC, KPT, SHC. 
CAT, EKT, HPC, KPT, PIT, SHC. 
EKT. 
EKT. 

X. 

ore. 

GLY. 

FMB, MON. 

FMB, MON. 

EMB. 

OMC. 

AHA. 

ARA, TNA. 

HK. 

PEN. 

G. 

EK. 

ACY. 
ACY. 

LIL. 

MRT. 

HPC. 

GIV. 

GIV. 

ASL, ICO. 

WTL. 

UPR. 

DOW. 

MRK. 

DOW, UCC. 

EKT. 

ARA. 

HK. 

PBC. 

EKT. 



BAX, CRN, OMS, PMP, RH, WBC. 

BAX, PMP, RH, WBC. 

RH, WBC. 

MO, MLS, WBC. 

PLB. 

SHC. 

ICO. 

MRK. 

GGY. 

VND. 

VC. 

ICO. 

UCC. 

ICO. 

BC, JCC, UCC. 

HNW. 



180 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 21B.- 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1964— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAI£, CYCLIC— Continued 

*Flotation reagents: 

BenzoyIthiono-1-ethylpropyl carbamate (Benzamate) 

Dioresylphosphorodithioic acid (Dioresylthiophosphorio 
acid) . 

Dioresylphosphorodithioic acid, ammonium salt 

Dioresylphosphorodithioic acid, sodium salt 

2,2'-Dimethylthiooarbanilide (Di-o-tolylthiourea) 

Rosin amines 

Thiocarbanilide (Diphenyl thiourea) 

Furan derivatives: 

2-Furaldehyde (Furfural) 

Tetraliydrofurfuryl alcohol 

Gallic acid, all grades 

gasoline additives: 

N,N'-Bis(l,4— dimethylpentyl)-p-phenylenediamine 

2,6-Di-tert-butylphenol 

*N,N'-Di-sec-butyl-p-phenylenedi amine 

N,N'-Diisopropyl-p-phenylenediamine 

Di(nonylphenol) salt of triethylenetetramine 

*N,N'-Disalioylidene-l,2-propanediamine 

Methylcyolopentadienylmanganese trioarbonyl 

2,2'-Thiobis [6-tert-butyl-4-methylphenol] 

All other 

Glyceryl p-amlnobenzoate 

Guanosine phosphates 

Hesperidin 

Hexa(2-methylaziridinyl)-l,3,5-phosphotriazine 

*Hexamethylenetetr amine , tech 

Humic acids, sodium salts 

Hydrocinnamio acid 

o-(2-Hydroxy-p-anisoyl)benzoic acid 

N-(2-Hydroxyethyl)gentisamide 

2-Hydroxy-'i-methoxybenzophenone 

2-Hydroxy-4-methoxy-5-sulfobenzophenone trihydrate 

Hydroxymethyl-5,5-dimethylhydantoin 

2-(2'-Hydroxy-5'-methylphenyl)benzotriazole 

2-Hydroxy-4— n-octoxybenzophenone 

2-(2-Hydroxyphenyl)-4(3)-quinazolone 

l-Hydroxy-2-pyridine (Omadine) 

2-Imidazolidinethione (l,3-Ethylene-2-thiourea) 

Inosine and phosphates 

Isoamyl p-dlmethylaminobenzoate 

Isocyanuric acid 

Isocyanuric acid, sodium salt (Sodium isocyanurate) 

Isopropyl-o-cresol 

Isopropyl-p-cresol 

p-Isopropyl-a-methylcinnamaldehyde 

Isopropyl tallate 

Isosorbide 

Ketene, dimer 

Laurylmorpholine 

Lemon biflavonoid 

*Lubricating oil and grease additives: 

Chlorosulfurized and sulfurized compounds: 

Alicycllc compounds, sulfurized 

Heterocyclic compounds, sulfurized 

Liquid disulfide 

Tall oil ester, sulfurized 

Terpenes, sulfurized 

Oil-soluble petroleum sulfonates: 

Oil-soluble petroleum sulfonate, ammonium salt 

*Oil-soluble petroleum sulfonate, barium salt 

*Oil-soluble petroleum sulfonate, calcium salt 

*Oil-soluble petroleum sulfonate, sodium salt 

All other 

Phenol salts: 

Bariimi salt of dodecylphenol 

Barium salt of nonylphenol 

Calcium salt of ootylphenol-formaldehyde 



DOW. 
ACY. 

ACY. 
KCU. 

ACY, DUP. 
HFC. 
ACY, NAC. 

QKO. 
QKO. 
MAL. 

EKT. 

TNA. 

DUP, EKT, UPM. 

DUP, EKT. 

SPP. 

DUP, 

TNA. 

CAT. 

EKT, UPM. 

VND. 

PLB, SBR. 

SKG. 

ICO. 



EKT, SOI, SPP, TNA, TX, UPM. 



NLC. 
ICO. 
ACY. 
ICO. 
ACY. 
ACY. 
GLY. 
GGY. 
ACY. 

X. 

OMC. 

PAS. 

PLB, 

VND. 

MON. 

FMB. 

CP. 

GIV. 

GIV. 

DEX. 

APD. 

EKT. 

BC. 

SKG. 



G, SOI. 
ORO. 



LUB. 
LUB. 



DUP, HKD, HMP, HN, PLS, UCP. 



SIN. 

ATR, LUB, TX, WTC. 

LUB, ORO, SHO, SOI, SON, WTC, x. 

ENJ, MDR, NOP, PAR, SHO, SOC, SOI, SON, TX, WTC. 

CO. 

TX. 

CCA. 

SHC. 



MISCELLANEOUS CHEMICALS 



181 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1964 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLAMEOUS CHEMICALS, CYCLIC— Continued 

*Lubrioating oil and grease additives — Continued 

Phenol salts — Continued 

Calcium salt of polypropylphenol 

All other phenol salts 

All other 

p-Menthane 

8-p-Menthyl hydroperoxide 

•4-Methoxyphenol 

N-Methylanthranilic acid 

2-Methylaziridine 

Methylcentralite (N,N'-Diinethyloarbanilide) 

2,2'-Methylenebis ["4-ohlorophenol] ( Diohlorophene ) 

4,4'-Methylenebis [2,6-di-tert-butylphenol] 

Msthylenebls[5,5-dimethylhydantoin] 

2,2' -Methylenebis[ 3, <i, 6-triohlorophenoll ( Hexaohlorophene 
2,2'-lfethylenedi-p-cresol (Bis(5-methyl-2-hydroxyphenyl) 

methane ) . 

Methylglucoside 

"i-Methylmorpholine 

lfethylnorbomene-2,3-dioarboxylic anhydride (Methylbi- 

oyolo-(2.2.1)heptene-2,3-carboxyllo anhydride). 

Methyl phenyl phosphates 

5-Methyl-5-n-propyl-in-dioxan-2-one 

l-Methyl-2-pyrrolidone, monomer 

»Morpholine 

Mbrpholine salt of p-toluenesulfonic acid 

*Naphthenic acid salts: 

Aluminum naphthenate 

Barium naphthenate 

Cadmium naphthenate 

»Caloium naphthenate 

Cobalt lead manganese naphthenate 

»Cobalt naphthenate 

*Iron naphthenate 

Lead manganese naphthenate 

»Iiead naphthenate 

Lithium naphthenate 

*Manganese naphthenate 

Nickel naphthenate 

Rare earths naphthenate 

Sodium naphthenate 

Strontium naphthenate 

*Zinc naphthenate 

o-Nitrobenzoic acid and sodium salt 

5-Norbomene-2-methanol (Bicyclo [2.2.1] hept-5-ene-2- 

methanol) and acrylate ester. 
Ootylphenyl acid phosphate 



LUB, MDN, OHO, SIN, x. 

LUB, MDN, ORO, SIN, SPP, TNA, TX. 



OKD. 

ENJ, 

ENJ, 

HPC. 

HNW, HPC. 

ASL, EKT, ICO. 

GIV. 

ICO. 

OTC. 

GIV. 

SHC. 

GLY. 

GIV. 

GIV. 

CRN. 

JCC, UCC. 
ICO. 



DOW, JCC, UCC. 
AMB. 

HSH, WTC. 
CCA, QCP. 
CCA, HSH. 
CCA, FER, HNX, HSH, MCI, MLD, MR, SHP, SOC, SPP, SRR, 

SW, TRO, WTC. 
HNX, HSH. 
CCA, CCC, FER, HNX, HSH, MCI, MLD, MON, MR, SHP, SOC, 

SPP, SRR, SW, TRO, WTC. 
CCA, HNX, HSH, MCI, MLD, SOC, WTC. 
CCA. 
CCA, CCC, CCW, FER, HNX, HSH, MCI, MLD, MR, QCP, SHP, 

SOC, SPP, SHE, SW, TRO, WTC. 
CCA. 
CCA, CCC, FER, HNX, HSH, MCI, MLD, SHP, SOC, SPP, SRR, 

SW, TRO, WTC. 
CCA. 

CCA, HNX. 
CCA. 
CCA. 
CCA, CCC, FER, HNX, HSH, MCI, MLD, SHP, SOC, SRR, SW, 

TRO, WTC. 
WAY. 
ICO. 



VC. 



182 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 21B.-- Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1964 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



IQSCEIiANEOUS CHEMICALS, CYCLIC— Continued 

Organic mercury compounds: 

Phenyl mercuric borate 

Pyridyl mercuric acetate 

Pentachloronitrobenzene 

Pentaerythrityl tetra( diphenyl phosphite) 

o-Phenanthroline 

Phenolthiosulfonic acid 

2-Phenoxyethanol (Ethylene glycol monophenyl ether) 

2-(2-Phenoxyethoxy)ethanol (Diethylene glj-col phenyl 
ether) . 

2-Phenoxy-l-propanol 

Phenyl acid phosphate 

Phenyl benzoate 

2j2'-(p-Phenylene)diethanol 

Phenyltrimethylammonium chloride 

Photographic chemicals: 

N-(o-Aoetamidophenethyl)-l-hydroxy-2-naphthamide 

2-(<i-Jtaiino-N-ethyl-in-toluidino) ethyl sulfate 

^-Mino-6-methylguaiacol (2-Methyl-6-methoxy-'i-amino- 
phenol hydrochloride). 

3-Amino-l,2,'i-triazole (5-Amino-l,3,4-triazole) 

»Benzotriazole 

p-Benzylaminophenol hydrochloride 

2,2','V,'4'-Biphenyltetrol 

Catechol (Pyrocatechin) 

3-Chloro-<i-diethylaminobenzenediazonium chloride 

(p-Dlazo-2-chloro-N,N-diethylaniline) - zinc chloride. 

2,4-Diaminophenol dihydrochloride (Amidol) 

N-(A-Diazo-2,5-dibutoxyphenyl)morpholine 

N-('4-Diazo-2,5-diethoxyphenyl)morpholine 

4-Diazo-l-morpholine benzene 

2,5-Diethoxy-4-morphinyldiazonium chloride - zinc 
chloride . 
*p-Diethylaminobenzenediazonium chloride (p-Diazo-N, N- 
diethylanlline) - zinc chloride. 
p-Diethylaminobenzenediazonium (p-Diazo-N, N-diethyl- 
aniline) f luorobor ate . 

N, N-Diethyl-p-phenylenediamine hydrochloride 

N,N-Dlethyltoluene-2,5-diamine, monohydrochloride 

2,5-Dihydroxy-p-benzenedisulfonio acid, dipotassium salt 

2,5-Dihydroxybenzenesulfonic acid 

2,7-Dihydroxy-3,6-naphthalene sulfonate 

»p-Dlniethylaminobenzenediazonium chloride (p-Diazo- 
N,N-dimethylaniline) - zinc chloride. 
4-(2',6'-Dimethylmorpholinyl)benzenediazonium chloride - 
zinc chloride. 

p-Diphenylaminediazonium sulfate 

p-(N-Ethylbenzimldo)benzenediazonium chloride (p-Diazo- 

N-benzyl-N-ethylaniline) - zinc chloride. 
p-[Ethyl(2-hydr6xyethyl) amino] benzenediazonium chloride 
(p-Diazo-N-ethyl-N-hydroxyethylaniline) - zinc chlo- 
ride. 

N-Ethyl-N-hydroxyethyl-p-phenylenediamlne sulfate 

N-Ethyl-N-(p-methanesulfonamidoethyl)toluene-2,5-di amine 
sulfate . 

Hydroquinone (Hydroquinol) 

p- [(2-Iferdroxyethyl)methylamino] benzenediazonium chloride 
(p-Diazo-N-hydroxyethyl-N-methylaniline) - zinc 
chloride . 
3-Ifydroxy-N-(2-hydroxyethyl)-2-naphthamide (p-Oxynaph- 

thoicmonoethanolamlde) . 
N-(p-Hydroxyphenyl) glycine 



WRC. 

MAI. 

OTC. 

HK. 

COK. 

G. 

DOW, JCC. 

DOW. 

ICO. 

VC. 

CIN. 

EKT. 

BKL. 

EKT. 
EKT. 



FMT. 

EK, FMT, MEE, MRT. 

EK. 

FMT. 

KPT. 

FMT. 

VPC. 
IDC. 
IDC. 
FMT. 
G. 

FMT, G, IDCj MRT. 

IDC. 

EKT, FMT. 
EKT, FMT. 

X. 

EK. 

FMT. 

FMT, G, IDC. 



FMT. 
FMT, MRT. 

FMT, IDC. 



IDC. 

EKT. 



EKT. 
FMT, IDC. 



FMT. 
IDC. 



MISCELLANEOUS CHEMICALS 



183 



TABLE 21B.- 



- Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer , 1964 — Continued 



Manufacturers ' Identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, CYCLIC— Continued 

Photographic chemicals — Continued 

l-(3-I^droxyphenyl)urea 

4— Methoxy-1-naphthol 

p-Methylaminophenol sulfate (Jfetol) 

S-lfethylbenzotriazole 

•4-M)rpholinylbenzenediazonium chloride - zinc chloride 
salt. 

"i-MDrpholinylbenzenediazonium fluoroborate 

6-Nitrobenzimldazole 

Octylphenyl salicylate 

Phenyljnercaptotetrazole 

l-Phenyl-3-pyTazolidinone 

4- Phenylpyrooatechol 

2-Resorcylic monoethanolamide 

ij'i'-Thiodlresoroinol (Diresorcyl sulfide) 

l-(2,'i,6-Triohlorophenyl)-3-('i-nitroanillno)-2-pyraz- 
olln-5-one. 

All other 

Phthalio acid, lead salt, dibasic 

*Plnene 

Polyethylene terephthalate 

Poly-2-hydroxy-4.-inethacryloxybenzophenone 

Polyvinyl phthalate 

Propyl gallate 

i^ogallol (I^ogallio acid) 

Eesorcinol monobenzoate 

Ribonucleic acid and derivatives 

Rosin acid salts : 

Aluminum resinate 

Calcium resinate 

Copper resinate 

Iron resinate 

Lead resinate 

Manganese resinate 

Zinc resinate 

Salicylanillde 

Salicylic acid, lead salt 

Silicones 

Sodium oresoxide (Cresylio acid, sodium salt) 

Sucrose benzoate 

Sulfosalicylic acid 

Tall oil fatty acid chloride- 

*Tall oil salts ( linolelc-rosin acid salts): 

*Calcium tallate 

*Cobalt tallate 

Copper tallate 

*Iron tallate 

Lead manganese tallate 

*Lead tallate • 

*<Manganese tallate 

Zinc glyceryl tallate 

ifZino tallate 

Tannic acid 



EK, 


FMT. 


IDC. 




IDC. 




EK, 


FMT. 


EKT. 




TNC. 




GGY, 


WAY. 


X. 




FMT. 




BKC. 




EKT. 




EK, 


EKT, FMT, G. 


NTL. 




CBY, 


GID, HNW, HPC 


DUP. 




DUP. 




EK. 




EKT, 


HN, HSH. 


MAL. 




EKT. 




SBR. 




JMS. 




JMS, 


SW. 


JMS. 




HSH, 


JMS. 


JMS, 


MCI. 


JMS. 




JMS, 


SW. 


DUP, 


FIN, MEE. 


NTL. 




DCC. 




DEX, 


GOC. 


TNP. 




MON, 


MRK. 



CCA, HNX, HSH, MCI, MLD, TRO, WTC. 

CCA, CCC, FER, HNX, MCI, MLD, SHP, SRR, TRO, WTC. 

CCA, MCI, MLD, SHP, SRR. 

CCA, MCA, MCI, MLD, SRR, WTC. 

HSH, MCI. 

CCA, CCC, FER, HNX, HSH, MCI, MLD, SHP, SPP, SRR, TRO, 

WTC. 
CCA, CCC, FER, HNX, HSH, MCI, MLD, SHP, SRR, TRO, WTC. 
CCA. 

CCA, HSH, MCI. 
HSH, MAL. 



184 



SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 21B.-Miscellaneou^ chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 964— Continued 



Chemical 



mSCELLANEOUS CHE1CCAI5, CYCLIC— Continued 

wTarniing materials, synthetic: 

Hydroxytoluenesulfonio acid, formaldehyde condensate 
(Cresol-formaldehyde sulfonate), sodium salt. 
»2-Naphthalenesulfonic acid, formaldehyde condensate and 

salts. ^ . 

*l-Phenol-2-sulfonic acid, formaldehyde condensate 
(Phenol-formaldehyde, sulfonated). 
Styrene malelc anhydride Interpolymer, partial sodium 

Sulfonyldiphenolsulfonlc acid, formaldehyde condensate- 
All other " ' 

Tetra(n-butyl) ammonium picrate 

1,2,3,4-Tetrahydxonaphthalene (Tetralln) 

Tetrahydrothiophene '2". 

Tetraphenyltin " 

^<Textile chemicals, other than surface-active agents: 
l,3-Bis(hydroxymethyl)-2-imidazolidone (Dlmethylol 

ethylene urea). 

N',N'-Diphenyl-l,2-propaiiediamlne 

1- ICOctadecyloxyimethyl] pyridinlum chloride 

Phenol, Eulfurated '7"T""J"' 

Tetrahydro-3,5-bis(methoxymethyl)-4H-l,3,5-oxadiazin-<;- 

one. 

2,2' ,4,'i' -Tetrahydroxybenzophenone 

2-Thenoyltrifluoroacetone — 

2,2'-ThiobiB[4-ohlorophenol] 

2,2'-Thlohis[4,6-dlchlorophenolJ 

[ 2,2'-Thiobis(4-octylphenolate)] -n-butylamlne nickel 

Thymidine and phosphates 

o-Toluidine-formaldehyde hydrochloride 

o-Tolylbiguanlde 

3,4' ,5-Tribromosallcylanilide 

3,4,4' -Triohlorooarbanlllde 

Triohloromelamine """7 '"' 

l,3,5-Trichloro-s-trlazlne-2,4,6(lH,3H,5H)trione (Trl- 

ohloroisocyanuric acid) . 
Tri-(m,p)-creByl borate 

Triethanolamlne salicylate 

s-Trioxane 

Trlphenyl phosphite 

Triphenylphosphorus 

Triphenyltln hydroxide 

Tris(l-azirldinyl)phoEphlne oxide 

2,4,6-Tris(2-hydroxy-4-ootyloxyphenyl)-s-triazine 

Tris[l-(2-methylaziridinyl)]phosphine oxide— 

Tris(2-methylazirldtnyl)-l,3,5-trlazine- 

Uridine and derivatives 

l-VInyl-2-pyrrolldlnone, monomer and polymer 

l-Vinyl-2-pyrrolldinone - vinyl acetate copolymer 

MISCELLANEOUS CHEMICALS, ACYCLIC 



Aoetacetamidoacetamide 

»Acetaldehyde 

Aoetamide 

Acetamidine hydrochloride 

2-Acetamldoethanol (N-Acetylethanolamlne) - 
*Acetio acid, synthetic, 100^ 



Manuf actiirers ' identification codes 
(according to list in table 22) 



AKS, GRD, NOP, NYC, RH. 
MAC, NOP, RH. 



G. 

MS. 
MED. 
DUP. 
ORO, PAS. 



ACY, AKS, X. 

SNW. 
DUP. 
G. 
DEX. 

G. 

CLE. 

GIV. 

MDN, SDH. 

ACY. 

SBR. 

HBC. 

MON. 

FIN. 

MON. 

IIVTH. 

FMB, M)N. 

USB. 
ICO. 
CEL. 
HK, MON. 



CEM. 

X. 

ICO. 

ICO. 

PLB, SBR. 

G. 

G. 



RBC. 

BFG, CEL, COM, DUP, EKT, HPC, MDN, PUB, SHC, UCC. 

ACG. 
MRK. 
RBC. 
CEL, EKT, HPC, PUB, UCC. 



MISCELLANEOUS CHEMICALS 



185 



TABLE 21B. 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1964— Continued 



MISCELLANEOUS CHE\aCAI£, ACYCLIC— Continued 

»Aoetic acid salts : 

Aluminum acetate 

Alujninum subacetate 

Ammonium acetate 

Barium acetate 

Cadmium acetate 

Calcium acetate 

Chromium acetate 

Cobalt acetate 

*Copper acetate 

Lead acetate 

Lead subacetate 

Lead tetraacetate 

Magnesium acetate 

Manganese acetate 

Mercuric acetate 

Methylmercuiy acetate 

Nickel acetate , 

*Potassiimi acetate 

Silver acetate 

»Sodiijm acetate 

Sodium diacetate 

Strontium acetate 

Uranyl acetate 

»Zinc acetate 

Zirconium acetate 

*Aoetic anhydride, IOO56: 

From acetaldehyde 

From acetic acid, other than recovered, by the vapor - 

phase process. 
From acetic acid, recovered, by the vapor-phase process 

From ethylene 

Acetin : 

Ifono 

Tri 

*Acetone : 

From cumene 

*From isopropyl alcohol 

All other 

Acetone, dimethyl acetal (2,2-Dimethoxypropaiione) 

Acetone semicarbazone 

Acetonitrile 

Acetyl chloride 

Acetyl peroxide 

Aconitlc acid 

Acrolein (Acrylaldehyde) 

^Acrylic acid 

Acrylic monomers 

*Acrylonitrile ■ 

*Adlpic acid 

Adiponitrile 

Adipoyl chloride 

*Alcohols, monohydric, unsubstituted : 
*Alcohols C9 or lower: 

Allyl alcohol 



Manufacturers ' identification codes 
(according to list in table 22) 



AQf 


UCC. 










MAL 












ACG 


BKC 


MAL 


WSN 






ACG 


BKC 


MAL 








HSH 


MAL. 










ACG 


BKC, 


MAL 


WSN. 






ACY. 












BKC, 


HSH, 


SHP. 








ACG, 


BKC, 


UCC. 








ACG, 


BKC, 


MAL, 


SRR, 


SW. 




ACG, 


BKC, 


MAL. 








AHA. 












ACG, 


BKC. 










HSH, 


SHP. 










BKC, 


MAL. 










DUP. 












BKC, 


HSH, 


SHP. 








ACG, 


BKC, 


CWL, 


MAL, 


ncc 


WSN. 


MAL. 












ACG, 


BKC, 


CEL, 


DAN, 


EKT 


MAL, UCC 


UCC, 


WSN. 










BKC. 












BKC. 












ACG, 


BKC, 


HSH, 


MAL, 


SNW, 


UCC. 


NTL, 


SNW. 










HPC. 












CEL, 


EKT. 










CEL. 












UCC. 












KES. 












EKT, 


WM. 










ACP, 


CLK, 


HPC, 


MON, 


SHC, 


SKO, SOC. 


EKT, 


EN J, 


SHC, 


UCC. 






CEL, 


HPC. 










DOW. 












NOR. 












EKX, 


UCC. 










TBK. 












WTL. 












PCW. 












SHC, 


UCC. 










BFG, 


CEL, 


DBC, 


MMM, 


RH, 


UCC. 


RH. 












ACY, 


BFG, 


DUP, 


MON, 


SOH, 


UCC. 


DUP, 


MDN, 


NAC, 


RH. 






DUP, 


MON. 










TBK. 












DOW, 


SHC. 











SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLiE 21B. -- Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1964 — Continued 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

»AlcoholE, monohydric, unsubstltuted — Continued 
*AloolioIs C9 or lower — Continued 
*Amyl alcohols: 
Unmixed : 

a-Methyl-a-tutanol (tert-Amyl alcohol) 

1-Pentanol 

2-Pentanol 

3-Pentanol 

Mixed: 

Fusel oil, refined 

(Jther than fusel oil: 

Primary mixed 

Secondary mixed 

Other 

*Butyl alcohols: 
Primary: 

Iso { Isopropylcarbinol) 

^Normal (n- Propylcarbinol) 

Secondary (Methylethyloarbinol) 

Tertiary ( Trimethylcarbinol) 

Mixed 

*Ethyl alcohol, synthetic 

2-Ethyl-l-butanol (sec-Hexyl alcohol) 

2-Ethyl-l-hexanol 

2-Ethyl-4-methyl-l-pentanol 

4-Ethyl-l-octyn-3-ol 

»Hexyl alcohol 

l-Hexyn-3-ol 

*Iso-octyl alcohols 

*Isopropyl alcohol 

»Methanol, synthetic 

2-Methyl-3-buten-2-ol 

2-Methyl-3-butyn-2-ol - - 

4-fcfethyl-2-pentanol ( 1-Methylisobutylcarbinol) 

3-Methyl-l-pentyn-3-ol (Methylparafynol) 

1-Octanol 

2-Octanol 

Pinacolyl alcohol (3,3-Dimethyl-2-butanol) 

Propyl alcohol (Propanol) 

2-Propyn-l-ol 

All other 

*Aloohols Cio or higher: 

»Decyl alcohols 

3,9-Diethyl-6-tridecanol 

»Dodecyl alcohol (Lauryl alcohol) (95^) 

7-Ethyl-2-methyl-4-hendecanol 

*l-Hexadecanol (Cetyl alcohol) (95^) 

»1-Octadecanol (Stearyl alcohol) (955t) — 

cis-9-Octadecen-l-ol (Oleyl alcohol) 

Tallow alcohol 

1-Tridecanol ■ 

2,6,8-Trimethyl-4-nonanol 

All other 

Aldol (Acetaldol) 

Aliyl and aliylene hydrocarbons 

Aliyl mercaptoacetic acid 

Aliyl sulfides, mixed 



Manufacturers' identification codes 
(according to list in table 22) 



PAS, UCC. 
PAS, UCC. 
UCC. 
EK. 

PUB. 



PAS. 
PAS. 
CEL, 



PAS, UCC. 



USI. 



CEL, DBC, EKX, ENJ, SHC, UCC. 

CEL, CO, DBC, EKX, ENJ, SHC, UCC. 

ENJ, SHC. 

SHC. 

CEL, DBC, EKX. 

DUP, EKX, ENJ, HPC, PSP, SHC, UCC, 

UCC. 

CEL, EKX, ENJ, SHC, UCC. 

EKX. 

AIR. 

EKX, ENJ, UCC. 

AIR. 

EKX, ENJ, GOC, HOU, 0X0, SOI, TID, UCC. 

ENJ, SHC, UCC. 

"' ', MON, HH, SPN, 



ACN, BOR, CEL, COM, 


DUP, ESC, GH 


UCC. 




AIR. 




AIR. 




ENJ, SHC, UCC. 




AIR. 




DUP. 




PG, RH, WIH. 




KF. 




CEL, UCC. 




G. 




CEL, EKX. 




DUP, ENJ, GOC, HOU, 


PG, TID, UCC 


UCC. 




DUP, PG, RH. 




UCC. 




ADM, DUP, ENJ, GIV, 


RH. 


ADM, DUP, PG, RH. 




ADM, DUP. 




ADM. 




ENJ, GOC. 




UCC. 




CO, PG, RH. 




UCC. 




ADM, GOC, HMf. 




ENJ. 




ORO. 





miscellaneous! chemicals 



187 



TABLE 21B. 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, iS64 --Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

l-Allyl-3-(2-hydroxyethyl)-2-thiourea (N-|3-Hydroxyethyl- 
N'-allyl thiourea) . 

Allyl isocyanate 

Allyl isothiooyanate, nonflavoring grade 

Allyl methacrylate 

Allyl nitrile (Allyl cyanide) 

l-(Allyloxy)-2,3-epoxypropane (Allyl glycidyl ether) 

3-(Allyloxy)-l,2-propanediol (Allyl glyceryl ether) 

2-Allyl-4-pentenoic acid (Diallylacetic acid) 

Allylpseudoionone 

Aluminum isopropoxide (Aluminum isopropylate) 

Amidinourea (Guanylurea) phosphate and sulfate 

*Amines : 

Butylamine 

tert-Butylamine 

Butylethylamine 

Butylmethylainine 

Cetyl dimethylamine 

*Coconut oil amine 

Cottonseed oil amines 

Diallylamine 

Dibutylamine 

«Diethylamine 

Diethylamine hydrochloride 

2,2'-Diethyldihexylamine 

Diethylenetriamine 

N.N-Diethylethylenediamine 

N ,N-'--Diethyl-l,4-pentaiiediamine ( Novoldiamine ) 

N,N-Diethyl-l,3-propaiiediamine 

Diisobutylamine 

Diisopropylamine 

Dilaurylamine 

*Dimethylamine 

Dimethylamine hydrochloride 

Dimethylamine sulfate 

Dimethylmyrystylamine 

N,N-Dimethyloctadecylamine (Stearyldimethylamine) 

N,N-Dimethyl-l,3-propanediamine 

Dipentylamine (Diamylamine) 

Dipropylamine 

Dipropylenetriamine 

Dodeoylamine 

Ethylamine 

Ethylenediamlne 

Ethylenediamine dihydrochloride 

Ethylenediamlne sulfate 

Hexadecylamine 

1,6-Hexanedlamlne (Hexamethylenediamine) 

3,3'-Iminobispropylamine 

Isobutylamlne 

*Isopropylamine 

Lauryl dimethylamine 

Methylamine hydrochloride 

*Methylamine , mono- 

Methyltriethylenedi amine 

*Octadeoylamine 

Octylamlne 

^Oleylamine 

Pentylamine (Monoamylamine ) 

Primary allsylamines , mixed 

1,2-Propanediamine (Propylenediamine) 

1,3-Propanediamine 

Propylamine 

Soybean oil amine 

Tall oil amine 

*Tallow amine 

Tallow amine, dihydrogenated 

*Tallow amine, hydrogenated 



FMI, IDC. 



CTN. 








ICO. 








SAH. 








KF, RBC. 








DOW, SHC 








SHC. 








X. 








GIV. 








CHT. 








ACY. 








EKT, PAS, 


UCC 






MDN, RH. 








PAS, UCC. 








PAS. 








EC. 








ADM, ARC, 


CGL 


FOR 


GNM. 


FOR. 








SHC. 








PAS, UCC. 








DUP, PAS, 


UCC 






X, 








VGC. 








DOW, UCC. 








COK. 








SDH. 








UCC. 








PAS. 








PAS, UCC. 








GNM. 








COM, DUP, 


PAS, 


RH. 




ICO, TNC. 








RH. 








BC. 








ARC. 








JCC, UCC. 








PAS. 








PAS, UCC. 








UCC. 








ARC, FOR, 


GNM. 






ESC, PAS, 


UCC. 






DOW, JCC, 


UCC. 






BKC. 








EK. 








ADM, ARC. 








DUP, MON. 








JCC, UCC. 








PAS. 








ESC, PAS, 


UCC, 


VGC. 




BC. 








RBC. 








COM, DUP, 


ESC, 


PAS, 


RH. 


JCC. 








ADM, ARC, 


CGL, 


FOR, 


GNM. 


ADM, ARC, 


RH, 


UCC. 




ARC, CGL, 


FOR, 


GNM. 




ALB, EK, 


PAS. 






RH. 








UCC. 








UCC. 








PAS, UCC. 








ARC, CGL. 








CGL, GNM. 








ADM, ARC, 


CGL, 


FOR, 


GNM. 


ARC, FOR. 








ADM, ARC, 


CGL, 


FOR, 


GNM, HUM 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 21B.- Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1964 — Continued 



^aSCELLANEOUS CHEMICALS, ACYCLIC— Continued 

•Amines — Continued 

Tallow methylamlnes, dihydrogenated 

Tetraethylenepentamine 

N,N,N',N'-Tetraiiiethyl-l,3-"butaiiedlaiiiine 

Tetramethylethylenediajnlne 

Tributylamine 

Tricaprylylamine 

Tridodecylamine 

Triethylamine 

Triethylenetetramine 

Trimethylainlne 

Tripentylamine- 

All other 

2-Aiiiino-l-butaiiol 

l-Aminoethanol ( Aeetaldehyde ammonia) 

Aminoethoxyethanol 

Aminoethoxypropylsilane 

2- ( 2-Aminoethylamino) ethanol ( Aminoethylethanolamine ) 

2-Amlno-2-ethyl-l,3-propanediol 

2-Aminoethyl vinyl ether 

Aminoguanidine bicarbonate 

2-Amino-2-(hydroxymethyl)-l,3-propanediol (Tris(hydroxy- 
methyl ) aminome thane ) . 

2-Amino-2-methyl-l,3-propanediol 

2-Amino-2-methyl-l-propanol 

2-Aiiiino-2-methyl-l-propanol hydrochloride 

*Amyl acetates, 90?t: 

Aiiyl acetate (n-Pentyl acetate) 

Isopentyl acetate (Isoamyl acetate) 

Mixed 

Azelaic acid 

1,1' -AzobisfortDamide ( Azodicarbonamide ) 

2 , 2' -Azobis [2-methylpropionitrile] ( a , a' -Azodiisobutyro- 
nitrile). 

Behenamide (Docosanainide) 

Behenic acid 

Bis[2-(2-butoxyethoxy)ethyl] ether ( Tetraethylene glycol 

dibutyl ether) . 
Bis(2-butoxyethyl) ether (Diethylene glycol di-n-butyl 
ether). 

Bis(2-chloroethoxy)methane ( Dichloroethylf ormal ) 

*Bis(2-ohloroethyl) ether ( Dichlorodiethyl ether) 

Bls(2-chloro-l-methylethyl) ether (Dichloroisopropyl 
ether). 

Bis(2,6-dimethyl-'i-heptyl) maleate 

Bis(2-ethoxyethyl) ether (Diethylene glycol diethyl 
ether) . 

Bis(hydroxyethyl) ether butynediol 

l,3-Bis(hydroxymethyl)urea (Dimethylolurea) 

Bis [2-(2-methoxyethoxy) ethyl] ether (Tetraethylene 

glycol dimethyl ether) . 
Bis(2-metho3cyethyl) ether (Diethylene glycol dimethyl 
ether) . 

Bis(perfluoroall!yl) phosphate diethanolamine salt 

Bis(tributyltin) oxide 

Biuret 

Boron organic compounds: 

Boron alcoholate 

Boron fluoride ethyl ether complex 

Boron trifluoride monoethylamine complex 

Triethylborane 



Manufacturers' identification codes 
( according to list in table 22) 



ARC, 


FOR. 






DOW, 


UCC. 






UCC. 








RH. 








PAS. 








GNM. 








GNM. 








PAS, 


UCC. 






CCW, 


DOW, 


UCC. 




COM, 


DUP, 


PAS, 


RH. 


PAS. 








ALB, 


ARC, 


BRD, 


CGL, DUP, 


COM. 








PAS. 








JCC. 








UCS. 








DOW, 


UCC. 






COM. 








MEE. 








TRI. 








COM. 








COM. 








COM. 








SNW. 








PUB, 


TBK. 






FB, 


NW. 






CEL, 


PAS, 


UCC. 




EMR. 








FMT, 


NPI, 


USE. 




DUP. 








HUM. 








ADM. 








RBC. 








DOW, 


UCC. 






TKL 








DOW 


JCC 


OMC 


UCC, WYN 


DOW 


WYN 







DEX, GLY, 
ASL. 



SW. 

SFA. 
ACG. 
ACG. 
CAL, TNA. 



MISCELLANEOUS CHEMICALS 



189 



TABLE 21B. —Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1 964 ~ C ontinue d 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

Boron organic compounds — Continued 

Triethyl borate 

Trimethoxyboroxine 

All other 

N-Bromoaoetamide 

2-Bromo-N, N-dimethylethylamine ( Dimethylaminoethyl 
bromide) hydrobromide. 

N-Bromosuoolnimide (Succinibromimide) 

l,2(and l,3)-Butanediol (Butylene glycol) 

l,<t-Butanediol 

2,3-Butanedione 2-oxime 

1,2,'4-Butanetriol 

*2-Butanone (Methyl ethyl ketone) 

Butanone mixture 

*2-Butanone oxlme 

*2-Butanone peroxide 

2-Butene-l,<;-diol 

l-Butoxy-2,3-epoxypropane (Butyl glycidyl ether) 

2-Butoxyethanol (Ethylene glycol monobutyl ether) 

2-(2-Butoxyethoxy)ethanol (Methylene glycol monobutyl 

ether) . 
2-[2-(2-Butoxyethoxy)ethoxy]ethanol (Triethylene glycol 
monobutyl ether). 

2-(2-Butoxyethoxy)ethyl acetate 

l-Butoxyethoxy-2-propanol 

2-Butoxyethyl acetate 

*Butyl acetates : 

Iso — ^^ 

^Normal 

Secondary 

Tertiary 

Mixed 

Butyl acrylate 

Butylene oxide 

Butyl ether (Di-n-butyl ether) 

Butylethylthiourea 

»tert-Butyl hydroperoxide 

2,2' -(Butyllmino)diethanol (N,N-Bis(2-hydroxyethyl)butyl- 
amine). 

Butyl lactate 

n-Butyllithium 

Butyl maleate, mono- 

*tert-Butyl peroxide (Di-tert-butyl peroxide) 

tert- Butyl peroxyacetate 

tert-Butyl peroxylsobutyrate 

tert-Butyl peroxypivalate 

Butyl vinyl ether 

1-Butyne ( Ethylacetylene ) 

2-Butyne-l,'i-diol 

Butyraldehyde 

Butyraldel^rde oxime 

*Butyric acid 

Butyric anhydride 

Butyrolactone 

Butyronitrile 

Butyxyl chloride 

*Caprolactam (Hexahydro-2H-azepin-2-one) 

Caprolactone 

*Carbon disulfide 



Manufacturers ' Identification codes 
(according to list in table 22) 



USB. 










CAL. 










CAL, 


USB. 








ARA. 










BKL. 










ARA. 










CEL. 










G. 










EK. 










G. 










EN J, 


SHC, 


SPI, 


UCC. 




CEL. 










ALB, 


CCA, 


MLD, 


NAC, 


TRO. 


CAD, 


NOC, 


RCI, 


UPR, 


WTL. 


G. 










DOW, 


SHC. 








JCC, 


QMC, 


UCC. 






JCC, 


OMC, 


UCC. 






DOW, 


CMC. 








UCC. 










UCC. 










UCC. 










CEL, 


EKT, 


ENJ, 


PAS, 


UCC. 


CEL, 


EKT, 


ENJ, 


PUB, 


UCC. 


EN J, 


HPC, 


PUB, 


SHC. 




ENJ. 










CEL. 










CEL, 


DBC, 


UCC. 






DOW, 


UCC. 








UCC. 










PAS. 










AZT, 


CAD, 


UPR, 


WTL. 




PAS. 










COM, 


CWN, 


UPC. 






FTE. 










RUB. 










AZT, 


CAD, 


RCI, 


SHC, 


UPR, WTL. 


WTL. 










WTL. 










WTL. 










UCC. 










AIR. 










G. 










CEL, 


EKX, 


UCC. 






NAC. 










CEL, 


EKT, 


UCC. 






EKT, 


UCC. 








G. 










EKX, 


UCC. 








HK. 










DEC, 


DUP, 


NAC. 






UCC. 










ACG, 


BKT, 


EMB, 


OLH, 


PAS, PPG, SF 



190 SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i 964- -Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

Cellulose esters: 

Cellulose acetate butjrrate 

Cellulose acetate propionate 

Nitrocellulose (Cellulose nitrate) 

^Cellulose ethers: 

Ethyloellulose 

Ethylhydroxyethylcellulose 

Hydroxyethylcellulose 

Methyloellulose 

*Sodium carboxymethyloellulose, IOO56 

Sodium carboxymethylhydroxyethylcellulose 

Cetyl chloride 

Cetyl lactate 

*Chloral (Triohloroaoetaldehyde) 

Chloroacetamide 

*Chloroaoetic acid, mono- 

Chloroacetic acid, mono-, derivatives: 

Butyl chloroacetate 

*Ethyl chloroacetate 

Methyl chloroacetate 

Sodium chloroacetate 

Chloroaoetonitrile 

Chloroacetyl chloride 

Chlorocholine chloride 

2-Chloro-l,l-dimethoxyethane (Dimethyl chloroacetal) 

*2-Chloro-N,N-dimethylethylamine (Dimethylaminoethyl 
chloride) hydrochloride. 

2-Chloro-N,N-dimethylpropylamine 

2-Chloro-N,N-dlmethylpropylamine hydrochloride 

3-Chloro-N,N-dimethylpropylamine hydrochloride 

Chlorodimethylvinylsilane 

2-Chloroethanol (Ethylene ohlorohydrin) 

2-(2-Chloroethoxy)ethyl 2-chloroethyl ether (Triethylene 
glycol dichloride) . 

2-Chloroethylamine 

2-Chloroethyl vinyl ether 

4— Chloro-3-hydroxybutyronitrile 

Chloromaleic anhydride 

P-Chloro-N-methylallylamine 

Chloromethyl methyl ether 

l-Chloro-l-penten-3-one (P-Chlorovlnyl ethyl ketone) 

3-Chloro-l,2-propanediol (Glycerol a-chlorohydrin) 

l-Chloro-2-propanone (Chloroacetone) 

N-Chlorosucoinimide (Succinichloriiolde) 

*2-Chlorotriethylamlne hydrochloride 

Chlorotrimethylsilane 

Citric acid 

Citric acid salts: 

Ammonium citrate 

Barium citrate 

Calcium citrate 

Ferric ammonium citrate 

Ferric citrate 

Ferrous calcium citrate 

Potassium citrate 

Sodium citrate 

All other 



EKT. 






EKT. 






DUP, 


HPC. 




DOW, 


HPC. 




HPC. 






HFC, 


UCC. 




DOW. 






BUK, 


DUP, HPC, 


KON, WYN. 


HPC. 






BC. 






VND. 






DA, 


FMB, GGY, 


MTO. 


BPC, 


DOW. 




BUK, 


DOW, HPC, 


MDN. 


MON. 






DOW, 


KF, MON. 




BPC, 


DOW, KF. 




DOW. 






BPC. 






DOW, 


DUP. 




Acy. 






LIL. 






ABB, 


GAM, HEX, 


MCH, NES, PAS 


SK. 






NES. 






MCH. 






DCC. 






CMC, 


UCC. 




UCC. 






ICI. 






UCC. 






X. 






RBC. 






LIL. 






HK, 


X. 




ABB. 






BKL, 


ICO, ore. 




EK, 


MRK. 




NAC. 






HEX, 


MCH, NES, 


PAS, X. 


DCC, 


UCS. 




MLS, 


PFZ. 




MAL, 


PFZ. 




SW. 






PFZ. 






MAL, 


PFZ. 




MAL. 






X. 






MLS, 


PFZ. 




MLS, 


PFZ. 




MLS. 







MISCELLANEOUS CHEMICALS 



191 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 7564— Continued 



Manuf aoti^rers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAI£, ACYCLIC— Continued 

Coconitrile 

Coconut oil amide 

Cottonseed oil acids^ ammonium salt 

Cottonseed oil nitrile 

Creatine and creatinine 

Crotonaldehyde 

Crotonic acid (2-Butenoic acid) 

Crotononitrile 

2-Cyanoacetamide 

Cyanoaoethydrazide 

Cyanoaoetio acid 

Cyanogen bromide 

3-Cyanopropylamine 

1,10-Deoanediol 

Decanoyl chloride 

*Decaiioyl peroxide 

Dialdehyde starch 

Diallylcyanamide 

1,2-Dibutoxyethane (Ethylene glycol di-n-butyl ether). 

2-Dibutylaminoethanol 

»Dibutyl fumarate 

*Dibutyl maleate 

1,3-Di butyl -2-thioiirea 

Dibutyltin compoiinds : 

Dibutylmethoxytin (Dibutyltin methoxide) 

Dibutyltin bis(lauryl mercaptide) 

Dibutyltin dichloride 

Dibutyltin dilaurate 

Dibutyltin maleate 

Dibutyltin mercaptopropionate 

Dibutyltin oxide 

All other 

Dichloroacetaldehyde 

Dichloroaoetic acid 

2,2-Dichloro-l,l-diflviciroethyl methyl ether 

Dichlorodimethylsllane 

Dichlorohydrogenmethylsllane 

Dichloromethylsilane 

Diohloromethylvinylsilane r 

l,3-Dichloro-2-propanol 

2,3-Dichloro-l-propanol 

Dicyanobutene 

Diethoxydimethylsilane 

Diethyl acetylsuccinate 

Diethyl allyl(l-methylbutyl)malonate 

Diethylaluminim chloride 

Diethylaluminiim iodide 

*2-Diethylaminoethanol 

2-(2-Diethylaminoethoxy)ethanol 

2-Diethylaminoethyl methacrylate 

Diethylaminopropionamide 

Diethyl sec-butylethylmalonate 

Diethyl butylmalonate 

Diethyl sec -butylmalonate 

Diethylcarbamoyl chloride 

Diethyl carbonate (Ethyl carbonate) 

Diethyl diethylmalonate (Diethyl malonio ester) 

*Diethylene glycol 

Diethylene glycol, borated 



FOR. 










ARC, 


CRT, 


KES, 


PC. 




GLY. 










FOR. 










PFN. 










CEL, 


EKT, 


UCC. 






EKT. 










KF. 










KF. 










KF. 










KF. 










EK. 










EKT. 










NEP. 










TBK. 










CAD, 


UPR, 


WTL. 






MLS. 










ACY. 










DOW. 










AAC, 


PAS. 








MON, 


PCC, 


PFZ, 


RCI, 


RUB. 


AIR, 


DUP, 


MON, 


PCC, 


RCI, RUB 


PAS, 


RBC. 








CCA. 










X. 










CCW, 


X. 








CCA, 


X. 








CCA, 


GRH, 


X. 






CCA, 


X. 









FMB. 

KF. 

DOW. 

DCC, UCS. 

UCS. 

DCC. 

DCC. 

EK. 

UCC. 

X. 

UCS. 

BPC. 

HPC. 

TNA, TSA. 

TSA. 

AAC, PAS, UCC. 

PAS. 

DUP. 



BPC. 

ABB. 

GAM. 

CTN, FMP. 

BPC, LIL. 

ACN, CAU, DOW, G, HCH, JCC, 

GLY. 



:, UCC, WYN. 



192 



SYNTHETIC ORGANIC CHEMICALS, )964 

TABLE 21B.-MiscelUineous chemicals for which U.S. production or sales were reported, identified by 
lABi^£- iii-D. manufacturer, 1964— Contvmed 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAIS, ACYCLIC— Continued 



Diethylene gljcol chloroformate 

Diethyl (ethoxymethylene)malonate 

Diethyl ethylisopentylmalonate 

Diethyl ethylmalonate (Ethyl malonic ester) 

Diethyl ethyl(l-methylbutyl)malonate 

Diethyl ethyl(l-methylpropyl)malonate 

Dl-2-ethyl-l-hexyl fumarate 

Di-2-ethyl-l-hexyl maleate 

N, N-Diethylnydroxylamine sulfate 

Diethyl maleate 

^Diethyl malonate (Malonic ester) 

Diethyl ( 1-methylbutyl) malonate 

Diethyl (3-metlQrlbutyl) malonate 

Diethyl methylmalonate 

Diethyl (l-methylpropyl)malonate 

Diethyl oxalate (Ethyl oxalate) — 

Diethyl succinate 

Diethylthiophosphoryl chloride 

l,3-Diethyl-2-thiourea 

Diethylzino 

Diglycolic acid 

Dihexyl fumarate 

Dihydropseudoionone "" 

l,3-Dihydroxy-2-propanone (Dihydroxy acetone )- 

Diisobutylaluminum 

Diisobutylaluminum chloride 

Diisononyl maleate- 



Diisopropyl adipate "T'li," i ~'\ 

2-Diisopropylaminoethaiiol ( N, N-Diisopropylethanolamine) - 



Diisopropylaninionium nitrite- 

Diisopropylcarbodiimide 

0-Diisopropyl dithiobis(thioformate) ---- 

Diisopropyl peroxydi carbonate (Isopropyl percarbonate)- 

l,3-Diisopropyl-2-thiourea "'7'.'Z'. '■" 

*Dilauryl 3,3'-thiodipropionate (Didodecyl thiodipropio- 

nate) . ^ , j.%, \ 

Dlmethoxyethane (Ethylene glycol dimethyl ether) -— 

N, N-Dimethylacetamide 

N, N-Dimethylacetoacetamlde 

*2-Dimethylaminoethanol 

Dimethylamino-2-propanol 

3-Dimethylaminopropionitrile 

N-(3-Dimethylajninopropyl)oleamide 

Dimethylcarbamoyl chloride 

Dimethyl carbonate 

2 5-Dimethyl-2,5-di(tert-butylperoxy)hexane 

2^5-Dimethyl-2,5-di(tert-butylperoxy)hexyBe-3— --— -- 

N, N-Dimethylf ormamide ^" 

Dlmethylglyoxime T"''r 

2,6-Dimethyl-4-heptanol (Diisobutylcarbmol) 

2',5-Dimethyl-2,5-hexanediol "--■ 

2,5-Dimethyl-3-hexyne-2,5-diol ■ --"- --' 

1, 1-DimethyIhydrazine "" 

Dimethyl malonate _" 

2,3-Dimethylpentaldehyde J" 

Di(4-methyl-2-pentyl) maleate 

2,2-Dimethyl-l,3-propanediol (Neopentyl glycol)— 

Dimethyltin dichloride 



1,3-Dimethylurea- 

Diootanoyl peroxide (Caprylyl peroxide) - 

Dioctyl fumarate 



PPG. 

KF. 

LIL. 

LIL. 

ABB, BPC. 

BPC. 

RUB. 

CIN, RUB. 

EK. 

ACY, ICO, UCC. 

ABB, KF, LIL. 

ABB, BPC, LIL. 

BPC. 

BPC. 

BPC. 

FMP. 

ICO. 
ACY. 

PAS, RBC. 

TNA. 

DUP. 

FB. 

GIV. 

BAX, PFZ. 

TSA. 

ISA. 

RUB. 

VND. 

PAS, UCC. 

OMC. 

G. 

DUP. 

PPG. 

G, PAS. 

ACY, CCW, EVN, HAB. 

ASL, OMC. 

DUP. 

EKT. 

AAC, PAS, RH, UCC. 

COM, PAS. 

ACY. 

DUP. 

GAM, OTC. 

FMP. 

WTL. 

WTL. 

DUP. 

EK. 

UCC. 

AIR. 

AIR. 

FMP. 

KF. 

UCC. 

RUB. 

EEC. 



MISCELLANEOUS CHEMICALS 



193 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported identified by 

manufacturer, i£>fri— Continued 



MrSCELLANEOUS CHEMICALS, ACYCLIC— Continued 

*Diootyl maleate 

l,3-Diootyl-2-thiourea 

*Dipropylene glycol 

Dlstearyl 3,3'-thiodipropionate 

Dithiooxamide 

Ditridecyl maleate 

n-Dodeoane 

»Dodecenylsuooinio anhyriride 

n-Eicosane 

*Epichlorohydrin 

»Eruoajnide 

Enioio acid 

Ethanedithiol 

*Ethanolamines : 

*2-Aminoethanol ( Jtonoethanolamine ) 

*2,2'-Iininodiethanol (Diethanolamine) 

*2,2' ,2" -Nltrilotriethanol ( Triethanolamine ) 

Ethanolamine hydrochloride 

Ethanolamine sulfite 

*2-Ethoxyethanol (Ethylene glycol monoethyl ether) 

*2-(2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl 

ether) . 
»2-[2-(2-Ethoxyethoxy)ethoxy]ethaiiol (Triethylene glycol 
monoethyl ether). 

2-(2-Ethoxyethoxy)ethyl acetate 

2-Ethoxyethyl acetate 

Ethoxymethylene malononitrlle 

3-Ethoxypropionitrile 

1-Ethoxy-l, 3,3-trimethoxypropane 

»Ethyl acetate, S5$ 

*Ethyl acetoaoetate 

*Ethyl aery late 

Ethylali imi num dichloride 

Ethylaluminum sesquichloride 

2-Ethylaminoethanol (Ethylmonoethanolamine) 

2-Ethylbutyraldehyde 

2-EthylbutyTic acid (Diethylacetic acid) 

Ethyl carbamate 

Ethyl carbethoxyacetimidate 

Ethyl carbodiimide 

Ethyl <i-chlorobutyrate 

Ethyl chloroformate 

Ethyl 3-(chlorofonnyl)propionate (p-Carbethoxypropionyl 
chloride ) . 

Ethyl cyanoacetate 

Ethylene, from ethyl alcohol 

Ethylene carbonate 

*Ethylene glycol 

Ethylene glycol diacetate 

Ethylene glycol dimercaptoacetate 

Ethylene glycol dimethaorylate 

«Ethylene oxide 

*Ethyl ether: 

Absolute 

Tech 

U.S.P 

*Ethyl formate 

2-EthyIhexanal (a-Ethyloaproaldehyde) 

2-Etliyl-l,3-hexanediol 

2-Ethylhexanoic acid (a-Ethyloaproic acid) 



Manufacturers ' identification codea 
(according to list in table 22) 



CRT 


ION 


PCC 


RUB. 






PAS 












CEL 


DOW 


JCC 


OMC, 


UCC 




CCW 












MAL. 










^ 


RUB. 












HMf. 












HMf 


MON, 


NAG. 








HMI. 












DOW, 


SHC, 


UCC. 








ADM, 


FIN, 


HUM. 








ADM. 












RBC. 












ACN, 


DOW, 


JCC, 


UCC. 






ACN, 


DOW, 


JCC, 


UCC. 






ACN, 


DOW, 


JCC, 


UCC. 






WSN. 












EVN, 


SUM. 










DOW, 


JCC, 


OMC, 


UCC. 






DOW, 


OMC, 


UCC. 








DOW, 


OMC, 


UCC. 








UCC. 












EKT, 


UCC. 










KF. 












ACT. 












KF. 












CEL, 


EKT, 


EN J, 


HPC, 


PUB, 


SRC, UCC. 


EKT, 


FMP, 


UCC. 








CEL, 


DEC, 


RH, 


UCC. 






TNA, 


TSA. 










TNA, 


TSA. 










PAS. 












UCC. 












UCC. 












BKL, 


FMP. 










KF. 












OTC. 












ABB. 












FMP. 












ABB. 












KF. 












OH. 












DOW, 


JCC. 










ACN, 


APD, 


CAU, 


CEL, 


DOW. 


DUP, G, GOC, HCH, JCC, OMC 


UCC, WYN. 








UCC. 












EVN. 












SAR. 












ACN, 


CAU, 


DOW, 


G, HCH, JCC, OMC, SNO, UCC, WYN. 


MAL. 












EN J, 
MAL, 


HPC, 
OMS. 


UCC, 


USI. 






COM, 


FB, TBK, UCC. 






EKX, 


UCC. 










UCC. 












EKT, 


UCC. 











194 



SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 21B.- Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
lAtsL,Ji ^iD. manufacturer, 1964— Continued 



MISCELLANEOUS CHMICALS, ACYCLIC— Continued 



*2-Ethylhexanoic aoid (a-Ethylcaproic acid) salts: 

Aluminum 2-ethyLhexanoate 

Barium 2-ethylhexanoate 

Cadmium 2-ethylhexanoate 

*Calcium 2-ethylhexanoate 

*Cobalt 2-ethylhexanoate 

Copper 2-ethylhexanoate 

Dibutyltin di-2-ethylliexanoate -■ 

Iron 2-ethylhexanoate ^ 

*Ijsad 2-ethylhexanoate "' 

^Manganese 2-ethylhexanoate 

Nickel 2-ethylhexanoate 

Potassium 2-ethylhexanoate 

Rare earths 2-ethylhexanoate 

Stannous 2-ethylhexanoate 

Strontium 2-ethylhexanoate 

*Zinc 2-ethylhexanoate 

Ziroonivmi 2-ethylhexanoate 

All other 

2-Ethyl-l-hexyl acetate 

*2-Ethyl-l-hexyl aery late 

2-Bthylhexyl cyanoacetate 

2-EthyUiexyl methacrylate 

2-Ethyl-2-(hydroxymethyl)-l,3-propanediol (Trimethylol- 

propane). 
2-Ethyl-2-(hydroxymethyl)-l,3-propanediol allyl ethers — 

Ethylidine diacetate 

Ethyl isocyanate 

2-( Ethylmercapto)ethanol 

Ethylmerciirio chloride " 

Ethyl 2-methyllaotate (Ethyl a-hydroxyisobutyrate) 

Ethyl (I-methyl-2-pentynyl) cyanoacetate 

*Bthyl propionate 

*Ethyl silicate (Tetraethoxysilane) 

Ethyl sulfate (Diethyl sulfate) 

N-Ethylurea """ 

Ethyl vinyl ether — 

Fats and oils, chemically modified: 

lard oil, nitrated 

Vegetable oils, brominated 

Other 

Fatty acids, chemically modified: 

a-Bromo(lauric-steaTic) acids 

Castor oil fatty acids, dehydrated 

All other 

Fatty acid esters, not included with plasticizers or 
surface-active agents: 

Deoyl oleate 

Ethyl stearate 

Isopropyl linoleate 

Isopropyl palmyristate 

Methyl esters of tallow 

All other 

Fish oil fatty aoid amide 

Flotation reagents: 

Isopropyl ethylthionocarbamate 

Phosphorodithioates (Dithiophosphates) : 

Potassivun dihexyl phosphorodithioate 

Sodium di-sec-butyl diethyl phosphorodithioate 



Manufacturers ' identification codes 
(according to list in table 22) 



WTC. 
CCA. 
CCA. 



CCA, FER, ma, HSH, MCI, MLD, SRR, SW, mC. 
CCA, FER, HNX, HSH, MCI, MLD, SHP, SRR, SW, WTC. 
CCA, SRR. 



CCA, 


HNX, 


HSH, MCI, 


MLD, NTL, SHP, SRR, SW, WTC 


CCA, 


HNX, 


MCI, MLD, 


SHP, SKR. 


MCI. 








CCA. 








CCA. 








WTC, 


X. 






OCA. 








CCA, 


HNX, 


HSH, MCI, 


SRR, WTC, X. 


CCA, 


HNX, 


WTC. 




SW. 








GEL, 


EKT, 


UCC. 




CEL, 


DBC, 


RH, UCC. 




KF. 








DUP. 








CEL. 








CEL. 








CEL. 








ore. 








PAS. 








LIL. 








RH. 








LIL. 








FB, 


NW, TBK. 




MIR, 


SEA, 


UCC. 




UCC. 








MED. 








UCC. 








SPP. 








DOM, 


RT. 






CHL. 








DUP. 








BAC. 








ABB, 


RH, 


HI. 




VND. 








ICO. 








VND 








PCS 








BFR, 


CHL 






ADM 


EMR 


, EMJ, PG, 


RT, X. 


ADM 








DOW 








Acy 








Acy 









TABLE 21B. 



MISCELLANEOUS CHEMICALS 

-Miscellaneo^ chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 7564— Continued ' '""'"■'J '■^" °y 



195 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

Flotation reagents — Continued 

Phosphorodithioates (Dithiophospiiates) — Continued 

Sodium di-seo-butyl phosphorodlthioate 

Sodiiim diethyl phosphorodithioate 

Sodium dihexyl phosphorodithioate 

Sodium diisopropyl phosphorodithioate 

Other 

Xanthates : 

Potassiiom n-butylxanthate 

Potassium ethylxanthate 

Potassium hexylxanthate 

Potassium isopropylxanthate 

Potassium pentylxanthates 

Potassium sec-pentylxanthate 

Sodium n-butylxanthate 

Sodium sec-butylxanthate 

Sodium ethylxanthate 

Sodium isobutylxanthate 

Sodium isopropylxanthate 

Ail other 

^Formaldehyde, 37^ by weight 

Formamide 

*Formic acid, 9Q<jo 

*Formio acid salts: 

Aluminum formate 

Ammonium formate 

Calcium formate 

Chromic formate 

Copper formate 

Lead formate 

Nickel formate 

Potassium formate 

Sodium foimate, refined 

Sodium formate, tech 

Thallous formate 

Fumarate polymer 

*Fumaric acid 

Geranyl orotonate 

^■Gluconic acid, tech 

Gluconic acid, ammonium salt 

^Gluconic acid, sodium salt, tech 

Glucono-delta-laotone 

Glucosamine hydrochloride 

Glucose pentaacetate 

Glutar aldehyde 

Glutaraldehyde bis(potassium metabi sulfite) 

Glutaraldehyde bis [sodium bisulfite] 

Glutaric acid 

Glycerol, synthetic 

Glycidol (2,3-Epoxy-l-propaiiol) 

Glycine (Aminoacetic acid), tech 

Glycine, cupric salt 

Glycine ethyl ester hydrochloride 

Glycolic acid (Hydroxy acetic acid) 

Glyoolio acid salts; 

Aluminum glycolate 

Sodium glycolate 

Glycolonitrile 

Glyoxal 

Guanidine hydrochloride 

4-Guaiiyl-l-isonitrosoguanyl-l-tetrazene 



Manufacturers ' identification codes 
(according to list in table 22) 



ACY. 
ACY. 
ACY. 
ACY. 
ACY. 

USE. 

ACY, DOW. 

DOW. 

DOW. 

ACY, DOW. 

DOW. 

KCC, USE. 

ACY, DOW, 

ACY, DOW. 

DOW. 

ACY, DOW. 

ACY. 

ACN, BOH, CBC, CEL, COM, DUP, HKD, HN, HPC, MON, HCI, 

RH, SPN, THJ, UCP. 
DUP. 
DUP, HN, VIC. 

SNW, UCC, VIC. 

ACG, WSN. 

THJ. 

G. 

GTN. 

NTL. 

HSH. 

TNC. 

ACG, BKC. 

DCI, HN, HPC. 

EK. 

EN J. 

HN, MON, NAC, NTL, PCC, PFZ, PIT, SOC. 

FB. 

CWL, DLI, IBl, PFZ. 

PFZ. 

CWL, DLI, IBI, PFZ. 

DLI, PFZ. 

PFZ. 

BKL. 

UCC. 

RZL. 

IDC, HZL. 

MON. 

APD, DOW, EH, SHC, UCC. 

OTC. 

BPC. 

BPC. 

BPC. 

DUP. 

CIB. 

MED, TNC. 

ACY. 

UCC. 

ACY. 

REM. 



196 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 21B.- 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



MSCELLAMEOUS CHEMICALS, ACYCLIC— Continued 

»Halogenated hydrocartons: 

«l-Bramobutane (n-Butyl bromide) 

2-Bromobutaiie (seo-Butyl bromide) 

Bromochloromethane 

l-Bromo-3-chloropropane (Trimethyleneohlorobromide) 

2-Bromo-2-chloro-l,l,l-trifluoroethane 

Bromoethane (Ethyl bromide) 

1-Bromohexadeoane (Cetyl bromide) 

l-Bromohexane (n-Hexyl bromide) 

l-Bromo-2-methylbutane 

l-Brofflo-3-methylbutane 

1-Bromo-octadecane 

l-Bromopentane (n-Amyl bromide) 

2-Bromopentaiie (l-Methylbutyl bromide) 

1-Bromopropane (n-Propyl bromide) 

3-Broraopropene (Allyl bromide) 

3-Bromopropyne 

Bromotrifluoromethane 

*Carbon tetrachloride 

^Chlorinated paraffins: 

Less than 355^ chlorine 

*35^64-5S chlorine 

65?J or more chlorine 

1-Chlorobutane (n-Butyl chloride) 

2-Chlorobutane (sec-Butyl chloride) 

l-Chloro-l,l-difluoroethane 

*Chlorodifluoromethane 

«Chloroethane (Ethyl chloride) : 

Tech 

U.S.P 

*Chloroform: 

Tech 

U.S.P 

2-Chloro-3-hexyne 

*Chloromethane (Methyl chloride) : 

Crude 

Refined (refrigerant grade) 

2-Chloro-2-methylpropane (tert-Butyl chloride) 

3-Chloro-2-methylpropene (Methallyl chloride) 

Chloropentafluoroethane 

Chloropentanes , mixed isomers 

2-Chloropropane (Isopropyl chloride) 

3-Chloropropene (Allyl chloride) 

Chlorotrifluoroethylene (Trifluorovinyl chloride)-- 

Chlorotr if luoroethylene , polymerized 

Chlorotrifluoromethane 

l,2-Dibromo-l,l-dichloroethane 

Dibromodifluoromethane 

1,2-Dibromoethane (Ethylene dibromide) 

Dibromomethane (Methylene bromide) 

1,3-Dibromopropane 

l,2-Dibromo-l,l,2,2-tetrafluoroethane 

Dichlorobutadiene 

1,4-Dichlorobutene 

*Dichlorodifluoromethane 

*l,2-Dichloroethane (Ethylene diohloride) 



Manufacturers' identification codes 
(according to list in table 22) 



ABB, BPC, DOW, MCH. 

ABB, BPC. 

DOW. 

DOW, MCH. 

ICI. 

DOW, MCH. 

EK. 

BPC. 

LIL. 

BPC. 

DUP, G. 

CLB, EK. 

ABB, BPC, LIL. 

BPC, EK. 

CLB, DOW. 

G. 

DUP. 

ACG, ACS, DA, DOW, FMB, FRO, PPG, SF. 

HK. 

CCH, DA, DVC, HK, HPC, KPT, WOI. 

DA, DVC, WOI. 

PUB, UCC. 

ICO, PLC. 

ACG, DUP. 

ACG, DUP, KAI, PAS, UCC. 

AME, DOW, DUP, HPC, TNA, USI. 
DOW, SHC. 

ACS, DA, DOW, DUP, FRO, SF. 

ACS, DA, DOW. 

LIL. 

ANM, DOW, TNA. 

ACS, DA, DCC, DOW, DUP, FRO. 

DUP, EK, RBC. 

FMP. 

DUP. 

PAS. 

DOW. 

DOW, SHC. 

ACG, MMM. 

HK, MMM. 

ACG, DUP, PAS. 

DOW. 

DOW. 

AMP, DOW, ETD, HCH, MCH. 

DOW. 

EK. 

DUP. 

DUP. 

DUP, RBC. 

ACG, DUP, KAI, PAS, UCC. 

AME, DA, DOW, DUP, JCC, M3N, 



OMC, PPG, TMA, UCC, WYN. 



MISCELLANEOUS CHEMICALS 



197 



TABLE 21B. —Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i 564— Continued 



MISCELLANEOUS CHEMICAIS, ACtCLIC—Continued 

♦Halogenated hydrooartons — Continued 

*Diohloromethane (Methylene chloride) 

Diohloropentanes , mixed isomers 

*1,2-Diohloropropaiie (Propylene diohloride) 

2,3-Diohloropropene 

*Diohlorotetrafluoroethane 

Ijl-Difluoroethane 

Difluorotetrachloroethane 

Diiodomethane (Methylene iodide) 

Hexaohloroe thane 

Hexafluoropropylene, monomer 

lodoethane (Ethyl iodide), teoh 

*Iodomethane (Methyl iodide) 

lodotrifluoromethane 

1,1,2,2-Tetrabromoethane (Acetylene tetrahromide) 

Tetrabromomethane 

1,1,2,2-Tetrachloroethane (Acetylene tetrachloride)-- 

*Tetrachloroethylene (Perohloroethylene) 

Tetrafluoroethylene, monomer 

Tetrafluoroethylene, polymer 

Tetrafluoromethane 

1,1,1-Trichloroethane (Methyl chloroform) 

1,1,2-Trichloroethane (Vinyl trichloride) 

*Trichloroethylene 

*Triohlorofluoromethane 

1,2,3-Trichloropropane 

1,2,3-Trichloropropene 

Triohlorotrifluoroethane 

»Vinyl chloride, monomer ( Chloroethylene ) 

Vinyl fluoride 

Vinylidene chloride, monomer (1,1-Dichloroethylene)— 

Vinylidene fluoride 

All other 

Heptaf luorobutanol 

2-Heptanone (Methyl amyl ketone) 

3-Heptanone (Ethyl butyl ketone) 

Heptanoyl chloride 

9H-Hexadecaf luorononanoic acid, ammonium salt 

Hexadecane 

Hexadecenyl succinic anhydride 

n-Hexadecyl disulfide 

Hexa(2-ethylbutoxy)disiloxane 

Hexamethylenediamlne dicarbamate 

Hexamethylenediammonium adipate 

Hexamethylene diisocyanate 

2,5-Hexanedione (Aoetony lace tone) 

1,2,6-Hexanetriol 

1,2,6-Hexanetriol ootoate 

Hexanoio acid (Caproic acid) 

Hexyl acetate 

2-[2-(Hexyloxy)ethoxy]ethanol 

Hydracrylonltrile (Ethylene cyanohydrin) 

Ifydrazine and salts 

2-Hydrazinoethanol 

Hydrocarbon polymer 

N-[ 3-(Hydroxymercuri) -2-methoxypropyl]carbamoylsuc- 

cinamic acid (Methoxyoximercuripropylsuccinyl urea) . 
2-(Hydroxymethyl) -2-methyl-l,3-propanediol ( Trimethylol 

ethane) . 
2-(Hydroxymethyl)-2-nitro-l,3-propanediol ( Tris( hydroxy • 

methyl) nitromethane) . 
N-( Ifydroxymethyl) octadeeanamide ( N-Hydroxymethylsteara- 
mlde) . 



Manufacturers ' identification codes 
(according to list in table 22) 



ACS 


DA, 


DOW, 


DUP, 


FRO, 


SF. 


PAS 












DOW 


JCC 


UCC 


, WYN 






DOW 












ACQ 


DUP 


PAS 








ACQ 


DUP 










DUP 












NTB 


SDW 


X. 








NES 












DUP. 












EK, 


FMT. 










CLE 


EK, 


FMT, 


NTB, 


RSA. 




CLB. 












DOW. 












DOW. 












DUP, 


PPG. 










DA, 


DOW, 


DUP, 


FRO, 


HK, PPG, SF, TTX. 


DUP. 












DUP. 












DUP. 












DOW, 


PPG, 


TNA 








DOW, 


TNA, 


UCC 








DOW, 


DUP, 


HK, 


PPG, 


TTX. 




ACQ, 


DUP, 


KAI 


PAS 


UCC 




DOW, 


SHC. 










DOW. 












ACQ, 


DUP, 


PAS. 








ACS, 


AME, 


BFG 


BOR 


cue 


DA, DOW, GNT, GYR, MNO, MON 


TNA, UCC. 








X. 












DOW, 


TNA. 










X. 












DUP, 


KPT, 


SDH. 








CLB. 












UCC. 












UCC. 












EK. 












DUP. 












ma. 












HMY. 












PAS. 












UCC. 












BKL. 












MON. 












OTC. 












RBC. 












UCC. 












KES. 












FB, TpK. 










ENJ. 












UCC. 












UCC. 












FMT, 


QMC. 










NOH. 












ENJ. 












LKL. 













198 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1964 — Continued 



MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued 

4-Hydroxy-4-methyl-2-pentanone (Diacetone alcohol) — 

(ffydroxyniethyl)urea (Methylol-urea) 

Hydroxypropyl methacrylate 

3,3'-Iininodiproplonitrile 

lodoacetic acid, sodium salt 

lodomethylmercury Iodide 

Isethlonic acid (2-Itsrdroxyethanesulfonlc acid) 

Isoascorblc acid 

*Isoascort)ic acid, sodium salt 

Isobutoxyethanol 

Isobutyl aciylate 

Isobutyl isobutyrate 

Isobutyl vinyl etber 

Isobutyraldehyde 

Isobutyrle acid and anhydride 

Isobutyronltrlle 

Isodeoaldehyde, mixed isomers 

Isodeeanoic acid, mixed Isomers 

Isodecyl aery late 

Iso-octanoic acid, mixed Isomers 

Isopentanoio acid 

Isopentyl ether (Isoamyl ether) 

Isoprenylalumlnum 

Isopropanolamines : 

l-Amino-2-propanol (Mbnoisopropanolamine) 

1,1' -Iminodi-2-propanol (Diisopropanolamine) 

1,1' ,1" -Nitrilotri-2-propanol (Triisopropanolamli 

*Isopropyl acetate 

2- IsopropylRTTii noethanol 

Isopropyl ohloroformate 

*Isopropyl ether 

Isopropyl isocyanate 

Isovalerone (Diisobutyl ketone) 

Itaconic acid (Methylenesuccinic acid) 

o-Ketoglutario acid 

*Lactic acid, 100^: 

Edible 

Medicinal- 

Technical 

Lactic acid salts : 

Aluminum lactate 

Aluminum sodium_ chlorohydroxylactate 

Aluminum sodium lactate 

Calcium lactate 

Sodium lactate 

Lactic anhydride 

Lactide (3,6-Dimethyl-2,5-p-dioxanedlone) 

Lactonitrile 

Laurie acid salts 

Lauronitrile 

Lauroyl bromide 

*Lauroyl chloride — — 

*Lauroyl peroxide 

Lauryl lactate 

Levulinic acid 

*Linoleic acid salts : 

^-Calcium linoleate 

^Cobalt linoleate 

Copper linoleate 

Iron linoleate 

Lead linoleate 



Manufacturers ' identification codes 
(according to list in table 22) 



CEL, LIL, 


SHC, 


UCC. 


DUP. 






JCC. 






ACY. 






RSA. 






NTB. 






G. 






MRK, PFZ. 






BAX, MRK, 


PFZ. 




UCC. 






DBC. 






EKX. 






G, UCC. 






EKX, UCC. 






EKT. 






EKX. 






UCC. 






UCC. 






UCC. 






UCC. 






UCC. 






GIV. 






ISA. 






DOW, UCC. 






DOW, UCC. 






DOW, UCC. 






EKT, EN J, 


HPC, 


UCC. 


PAS. 






CTN, PPG. 






EN J, SHC, 


UCC. 




OTC. 






EKT, UCC. 






PFZ. 






PIC. 






CLN, DUP, 


MON. 




DUP. 






CLN, DUP, 


MON. 




TNC. 






REH. 






REH. 






SHF. 






PEN. 






FB. 






CLN. 






MON. 






CCW. 






FOR. 






DOW. 






BC, G, HK 


, MON 


, TBK 


AZT, CAD, 


UPR, 


WTL. 


VND. 






CRZ. 






CCA, LEF, 


SHP, 


SRR. 


HSH, SEP, 


SRR. 




WTC. 






HSH. 






SHP, SRR. 







MISCELLANEOUS CHEMICALS 



199 



TABLE 21.B. -Miscellaneous chemicals for which U.S. production or sales were reported identified bv 

manufacturer, 1964— Continued r , j y 



MISCELLANEOUS CHEKQCALS, ACYCLIC— Continued 

*Llnoleio acid salts — Continued 

Lead manganese linoleate 

Manganese linoleate 

»Iubricating oil additives: 

Chloronaphtha xanthate 

Chlorosulfurized hydrocarbon 

Chlorosulfurized lard oil 

Chlorosulfurized sperm oil 

High-molecular-weight liydrooarbons and their phosphorus 
derivatives. 

Oxidized hydrocarbons 

*Phosphorodithioates (Dithiophosphates) : 

Barium aliyl phosphorodithioates 

Zinc aliyl phosphorodithioates 

Zinc di(butylhexyl) phosphorodithioate 

Zinc dihexyl phosphorodithioate 

Zinc hexyl isopropyl phosphorodithioate 

All other 

SuLfurized butenes 

Sulfurized lard oil 

Sulfurized methyl oleate 

*Sulfurized sperm oil 

Tetradecyl selenide 

All other 

Magnesium metiiylate 

Maleic acid 

Maleic acid, tribasic lead salt 

*Maleic anhydride 

Malic acid 

Malonio acid 

Malonic acid salts 

Malononitrile 

Mamiitol 

Mannitol hexanitrate 

Mercaptoaoetic acid ( Thioglycolic acid) 

»lferoaptoaoetic acid (Thioglycolic acid) derivatives: 
»2-Aminoethyl mercaptoacetate (MDnoethanolamine thio- 
glycolate ) . 

*Ammonium mercaptoacetate (Ammonium thioglycolate) 

Antimony mercaptoacetate 

Calcium mercaptoacetate 

Dibutyltin bis(iso-octylmeroaptoaoetate) 

Dibutyltin mercaptoacetate 

Iso-octyl mercaptoacetate 

Ifethyl mercaptoacetate 

Octadecyl mercaptoacetate 

Potassium mercaptoacetate 

Sodium mercaptoacetate 

3-Iiferoapto-l,2-propanediol (Thioglycerol) 

/3-lfercaptopropionic acid 

Mercaptosuccinic acid (Thiomalic acid) 

Ifetal soaps of oxidized hydrocarbons 

Methacrylamide 

Jfethaorylate copolymers 

Ifethacrylate monomers, above methyl 

Ifethacrylic acid 



Manufacturers ' identification codes 
(according to list in table 22) 



SDH 


SRR. 




SHP 


SRR. 




MON 






ENJ 






CCW 






ccw 






SOI 






ALX 






LUB. 






ENJ, 


LUB. 




ORO. 






MON, 


SIN. 




TX. 






ACY, 


LUB, MON 


SIN, TX. 


LUB. 






ccw. 


GOC, SIN 


SOI. 


SIN. 






ccw. 


LUB, QCP, 


SIN, SOI, X. 


ORO. 






CCW, 


ENJ, HK, 


LUB, MON, ORO, 


MET, 


SFA. 




NAC, 


PFN. 




NTL. 






HN, 


KPS, MON, 


NAC, PCC, PTT, 


EK„ 


^AC, PFN. 




KF. 






EK, 


3IV. 




KF. 






APD. 






APD. 






EVN, 


HAB, RET. 




EVN, 


HAB, RET. 




EVN, 


HAB, RET, 


TNI. 


CCA. 






Era. 






X. 






CCA. 






CCW, 


Era. 




Era. 






e™. 






Era. 






Era. 






Era. 






ETO. 






Era. 






ALX. 






RH, X 






X. 






DUP, 


SAR. 




DUP, 


RH. 





200 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 21B.-- Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1964 — Continued 



MISCELLANEOU:. CHEMICALS, ACYCLIC— Continued 

Iifethaoryloyl chloride 

tfethalylldene .iacetate 

Jfcthanesulfonlo acid 

»2-Msthoxyethanol (Ethylene glycol monoethyl ether) 

*2-(2-hfethoxyethoxy)ethanol (Diethylene glycol monoethyl 

ether) . 
»2-[2-(2-lfethoxyethoxy)ethoxy]ethanol (Triethylene glycol 
monomethyl ether). 
2-(2-hfethoxyethoxy)ethyl 2-methoxyethyl ether (Triethylene 
glycol dimethyl ether). 

2-Methoxyethyl acetate 

2-Methoxyethylainine 

'i-lfethoxy-<i-methyl-2-peutanol 

4-Methoxy-<i-methyl-2-pentanone 

Jfcthoxypolyethylene glycol 

l-Methoxy-2-propanol 

3-hfethoxypropionitrile 

3-(3-Methoxypropoxy)propanol (Dipropylene glycol methyl 

ether) . 
3-[3-(3-lfethoxypropoxy)propoxy]propanol ( Tripropylene 
glycol methyl ether). 

3-Methoxypropylamine 

Ifethoxytriethyleneglycol acetate 

*Jfethyl acetate 

Jfethyl acetoacetate 

Metlyrl acrylate, monomer 

Methylal ( Dimethoxymethane ) 

Ifethylaluminum sesquichloride 

2-lfethylaminoethanol (N-Methylethanolamine) 

Methyl borate 

3-I*thyl-2-butenoie acid 

2-Methyl-l-buten-3-yne ( Isopropenylacetylene ) 

2-Methyl-2-(sec-butyl)-l,3-propanediol 

lifethyl butynoxyethancl 

Methyl carbamate 

Ifethyl chloroformate 

Methyl oyanoacetate 

Methyl 2-oyanoacrylate 

Methyl diohloroacetate 

Methyl disulfide (Dimethyl disulfide) 

NjN'-Jfethylenebisacrylamide 

N, N' -Ifethylenebisoctadecanamlde 

Ifethyl ether (Dimethyl ether) 

Ifethyl formate 

N-Jfethylglucamine 

Methylglyoerol 

5-Methyl-2-hexanone (Methyl isoamyl ketone) 

2,2'-(Methylimino)diethanol (hfethyl diethanolamine) 

Ifethyl isocyanate 

2-Methyllactic acid (a-Hydroxyisobutyrio acid) 

2-Methyllactonltrile (Acetone cyanohydrin) 

Methylmagnesium bromide 

Methylmagnesiiom chloride 

Methyl methacrylate, monomer 

7-Kfethyl-3-methylene-l,6-ootadiene (h/tyrcene) 

2-Msthyl-2-nitro-l,3-propanediol 

2-^fethyl-2-nitro-l-p^opanol 

2-MBthyl-2,'i-pentanediol (Hexylene glycol) 

*4-lfethyl-2-pentanone (tfethyl isobutyl ketone) 

4-Afcthyl-2-pentanone oxime (Methylisobutyl ketoxime) 

4-lfethyl-3-penten-2-one (^fesityl oxide) 

4^-Methyl-2-pentyl acetate 

Methylpolyethanolamine 



Manufacturers ' Identification codes 
(according to list in table 22) 



DUP. 






UCC. 






EK, PAS. 






DOW, JCC, 


OMC, 


UCC. 


DOW, JCC, 


OMC, 


UCC. 


DOW, CMC, 


UCC. 




ASL. 






UCC. 






JCC, WYN. 






SHC. 






SHC. 






JCC, UCC. 






DOW, SHC. 






ACY. 






DOW. 






DOW. 






DUP, EKT, 


JCC. 




RBC. 






BOR, EK, 


GRD, 


SRC, UCC. 


EKT, UCC. 






CEL, DEC, 


RH. 




CEL. 






TNA. 






UCC. 






MHI, SFA. 






UCC. 






AIR. 






BKL. 






AIR. 






BKL. 






CTN. 






KF. 






EKT. 






KF, PD. 






CRZ. 






ACY. 






ARC. 






COM, DUP. 






DUP. 






ABB, DUP. 






APD. 






EKT, UCC. 






DOW, UCC. 






CTN, OTC. 






EK. 






RH, x. 






ARA. 






ARA. 






ACY, DUP, 


RH, 


USP. 


IFF. 






COM. 






COM. 






CEL, EKT, 


ICO 


SHC, UCC 


EKT, ENJ, 


SHC 


UCC. 


ALB. 






SHC, UCC 






PUB, SHC, 


UCC 





MISCELLANEOUS CHEMICALS 



201 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i564~ Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAI£, ACYCLIC— Continued 

2-Methyl-2-propyl-l,3-propanediol 

2-lfethyl-2-n-propyl-l,3-propanediol monocarbamate 

Methylpseudoionone 

Methyl sulfate (Dimethyl sulfate) 

Methyl sulfide (Dimethyl sulfide) 

Methyl sulfone 

^fethyl sulfoxide (Dimethyl sulfoxide) 

N-Jfethyltaurine 

N-Jfethyltaurine, sodium salt 

2-Methylvaleraldehyde (2-Methylpentaldehyde) 

2-Methylvaleric acid 

Methyl vinyl ether 

Micochlorio acid (2,3-Dlchloro-3-fonnylaciylic acid) 

Ifyristoyl chloride 

Ifyristoyl lactate 

Naringin 

Neodecanoic acid ( Trialiylaoetic acid) salts 

Nitriminobispropionic acid 

2-Nitro-l-butanol 

Nitroethane 

Nitromethane 

1-Nitropropane 

2-Nitropropane 

Nonanoic acid (Pelargonic acid) 

Nonenylsuccinio anhydride ■ 

Nylon 

1-Octadeoene 

Octadecyl isocyanate 

Octadecyl mercaptopropionate 

Octadecyl vinyl ether 

1-Octanethiol (n-Octyl meroaptan) 

Octanoic acid (Caprylic acid) salts: 

Aluminum octanoate 

Barium octanoate 

Cadmium octanoate 

Zinc octanoate 

2-Octanone (Hexyl methyl ketone) 

Octanoyl chloride 

1-Octene 

l(and 2)-0ctene 

2-Octene 

Ootenylsuocinio anhydride 

Octyltins 

Oleamide (Octadecene amide) 

Oleic acid salts: 

Aluminum oleate 

Ammonium oleate 

Barium zinc oleate 

*Copper oleate 

Lead oleate 

Stannous oleate 

Oleonitrile 

Oleoyl chloride 

Oleylpalmitamide 

*Qxalic acid 

Oxalic acid salts : 

Ammonium oxalate 

Calcium oxalate 

Copper oxalate 

Ferric ammonium oxalate 

Ferric oxalate 

Ferric sodium oxalate 

Ferrous oxalate 

Potassium binoxalate 



ABB, BKL, DUP, ICO. 

X. 

GIV. 

DUP. 

CR2, PAS. 

CRZ. 

CRZ. 

G. 

TNA. 

UCC. 

UCC. 

G, UCC. 

EKT. 

BC, X. 

TOD. 

SKG. 

MCI, MLD. 

ACY. 

COM. 

COM. 

COM. 

COM. 

COM. 

EMR. 

HMY. 

DUP, MDN. 

HMY. 

CWN, ICO, MDB. 

ETO. 

G. 

PAS. 

NOP. 

CCW. 

CCVf. 

BKC. 

EKT, TBK, WTH. 

HK, TBK. 

ADM. 

WTH. 

HMY. 

HMY. 

X. 

ADM, ARC, FIN, HUM. 



WTC. 
MCI. 
HSH, 
LEF, 
SHP. 
CCW, 
ARC, 
CRT, 
FIN. 
ACG, 



WTC. 

MLD, SHP, WTC. 



FOR. 
DEP, G. 



HK, MAL, PF2, VIC. 



ACG, BKC, PFZ. 

VIC. 

TNC. 

PFZ. 

PFZ. 

PFZ. 

BKL. 

BKC. 



202 



SYNTHETIC ORGANIC CHEMICALS, )964 

TABLE 21B.— Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 964 — Continued 



Chemical 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

*Oxalio acid salts--Continued 

Potassium oxalate 

Sodium binoxalate 

Sodium oxalate ~~ 

Oxidized hydrooarton mixtures, other than lubricating oil 
additives. 
*Palmitic acid salts : 

*Aluminum palmitate 

*Zinc palmitate 

*Palmitoyl chloride 

Pantolaotone 

Paraformaldehyde 

Paraldehyde (Paracetaldehyde) 

*Pentaerythritol 

Pentaerithritol caprylate 

Pentaerythritol, di- and other 

Pentaerythritol, di- and tri- 

Pentaerythritol pelargonate 

*Pentaerythritol tetranitrate 

Pentafluoropropanol 

2,4--Pentanedione ( Acety lacetone ) 

2,4-Fentanedione, metallic complexes: 

Cobalt 

Ferric 

Other 

2-Pentanone (Methyl propyl ketone) 

3-Pentanone (Diethyl ketone) 

Pentyl nitrate (An^rl nitrate) 

Perchloromethanethiol (Perchloromethyl mercaptan) 

Peroxyacetic acid 

*Phosgene (Carbonyl chloride) 

♦Phosphorus acid esters, not elsewhere specified {See also 
Plastioizers, Surface-Active Agents, Pesticides, Flo- 
tation reagents, and Lubricating oil additives): 

Bis(2-chloroethyl) vlnylphosphonate 

Bis(2-ethylhexyl) hydrogen phosphate 

Bis(2-ethylhexyl) hydrogen phosphite 

Butyl phosphates (mono- and di-) 

Chloropropyl phosphorothloate 

Dibutyl butylphosphonate 

Dibutyl hydrogen phosphite 

Didodecyl hydrogen phosphate 

Diethyl hydrogen phosphite 

Dimethyl hydrogen phosphite 

Dimethyl methylphosphonate 

Dioctyl hydrogen phosphate 

Dioctyl hydrogen phosphite 

2-Ethylhexyl phosphates (mono- and di-) 

Ethyl phosphates (mono- and di-) 

Iso-oetyl hydrogen phosphate 

Isopentyl ootyl hydrogen phosphate 

Lauryl dihydrogen phosphate 

Methyl phosphates (mono- and di-) 

Pentyl phosphates (Mono- and diainyl phosphates) 

Tributyl phosphate 

Tributyl phosphite 

Tridecyl phosphite 

Triethyl phosphite 

Triiso-octyl phosphite 

Trimethyl phosphate 

Trimethyl phosphite 

Tris(2-chloroethyl) phosphate 

Tris(2-chloroethyl) phosphite 

Tris(2,3-dibromopropyl) phosphate 

Tris(2-ethylhexyl) phosphite 

Tris(octadecyl) phosphite 

All other 



Manufacturers ' identification codes 
(according to list in table 22) 



ACG, BKC, PFZ. 

VIC. 

ACG, BKC, MAL, VIC. 

ALX. 



ACY, NOP, WTC. 

ACY, NOP, WTC. 

G, HAL, OPC, TBK. 

CKL, NOP. 

CEL, HN. 

UCC. 

COM, DCI, HN, HPC, RCI, TRJ. 

DRW. 

HPC. 

HPC. 

DRW. 

APD, DUP, HPC, TRJ. 

CLB. 

UCC. 

MLD. 

MAK. 

MAK. 

UCC. 

DUP. 

TNA. 

CHO. 

FMB. 

CTN, DUP, EKT, GE, MOB, NAC, OMC, PPG, SF, UCC, UPJ, 

VDM. 



VIC. 

UCC. 

VC. 

VIC. 

TNA. 

VC. 

VC. 

DUP. 

VC. 

VC. 

VC. 

VIC. 

HK. 

VIC. 

VIC. 

VC. 

VC. 

VIC. 

HK, VIC. 

VIC. 

CEL, COM. 

VC. 

HK. 

VC. 

VC. 

TNA. 

VC. 

CEL, ENJ. 

VC. 

DUP, MCH. 

HK, VC. 

VC. 



CEL, DUP, ENJ, MON, VC. 



MISCELLANEOUS CHEMICALS 



203 



TABLE 21B.— Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer , 1964 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAI5, ACYCLIC— Continued 



Pine oil, synthetic 

Polyacrylamide 

Polyacrylic acid 

Polyacrylic acid salts: 

immonium polyaciylate 

Sodium polyaorylate 

All other 

Polyacrylonitrile 

Polyohlorinated propyl ether 

Polyethoxyethylglycerol 

Polyethoxyethylsorbltol 

♦Polyethylene glycol 

Polyethylene glycol dimethaorylate 

Polyethylene polysulfide 

Polygalacturonic acid 

Polyglycols, ethylene glycol and glycol ethers, mixtures — 

Polyisobutyl succinic anhydride 

Polymethaorylic acid esters 

Polymethacrylic acid, sodium salt 

Polymethyl vinyl ether 

*Polypropoxy ethers : 

glycerol tri(polyoxypropylene) ether 

Polyp ropoxysorbitol 

Other 

♦Polypropylene glycol 

Polytetramethylene glycol ether 

Propanedithlol 

Propanone peroxide (Acetone peroxide) 

|3-Propiolactone 

Propionaldehyde 

♦Propionic acid 

Propionic acid salts r 

♦Calcium propionate 

♦Sodium propionate 

Propionic anhydride 

Propionyl peroxide 

2-[2-(Propo2y)ethoxy]ethanDl (Diethyleneglycol monopropyl 
ether). 

Propyl acetate 

Propylene carbonate 

♦Propylene glycol (1,2-Propanediol) 

Propylene glycol, mixed ethers 

n- Propyl isooyanate 

Propyl nitrate 



2-Propylvaleric acid (Dl-nr-propylacetic acid)- 

Propyne ( Methylacetylene ) 

Pseudoionone 

Pyruvaldehyde 



Quaternary ammonium- compounds (butyl and lower)- 

Rare sugars 

RicinoLamide 

Hicinoleic acid salts: 

Barium ricinoleate 

Calcium ricinoleate 

lithium ricinoleate 

♦Sarcosine ( N-lfethylaminoacetio acid) 

♦Sarcosine, sodium salt 



CBY. 








ACY, 


NLC. 






BFG, 


NOP, 


RH. 




BFG. 








AlC, 


BFG, 


JOR, RH. 




BFG. 








DUP. 








JCC. 








GLY. 








APD, 


GLY, 


TCH. 




ACN, 


DOW, 


DUP, G, JCC, OMC, UCC, WYN. 


SAH. 








BFG. 








SKG. 








DRW, 


OMC. 






DOW. 








EN J. 








DUP. 








GRD. 








G. 








JCC, 


OMC, 


UCC, WYN. 




APD. 








ACS, 


APD, 


UCC, WYN. 




DOW, 


JCC, 


UCC, VIS, 


WYN. 


X. 








RBC. 








SDH. 








CEL. 








EKX, 


UCC. 






CEL, 


COM, 


DUP, EKT, 


UCC. 


CEL, 


DUP, 


HFT, PFZ, 


UCC, WSN. 


CEL, 


DUP, 


PFZ, UCC, 


WSN. 


BKC. 








CEL, 


EKT, 


UCC. 




ABB, 


TBK. 






WTL. 








UCC. 








CEL, 


EKT, 


ENJ, PUB, 


UCC. 


DOW, 


JCC. 






APD, 


CEL, 


DOW, DUP, 


JCC, OMC, UCC, WYN 


DOW. 








CEL, 


DOW, 


JCC, OMC, 


UCC, WYN. 


CWN, 


UPC. 






TNA. 








X. 








AIR. 








GIV. 








UCC. 








ASL, 


EK, 


PAS, RSA. 




PEN. 








TKL. 








BAG. 








BAG. 








BAG. 








ATL, 


G, HMP, VPC. 




GGY. 
WTH, 


X. 







204 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELIANEOUS CHEMICALS, ACYCLIC— Continued 

Sebacoyl chloride 

Semicarbazide base and hydrochloride 

*Sequestering agents: 

(Diethylenetrinltrilo)pentaacetic acid 

(Diethylenetrinitrllo)pentaacetio acid, monosodium 
hydrogen ferric salt. 

*(Diethylenetrinitrilo)pentaacetic acid, sodium salt 

*N,N-Dihydroxyethylglycine, sodium salt 

*(Ethylenedinitrilo)tetraacetio acid (Ethylenediamine- 
tetraacetic acid), 

(Ethylenedinitrilo)tetraacetlc acid, diammonium salt 

(Ethylenedinitrilo)tetraacetiG acid, dipotasslum salt 

*(Ethylenedinitrilo)tetraacetio acid, disodium salt 

(Ethylenedinltrilo)tetraaoetic acid, disodium calcium 

salt. 
(Ethylenedinitrilo)tetraacetic acid, disodium copper 

salt. 
(Ethylenedinitrilo)tetraaoetic acid, disodium zinc salt, 
dihydrate . 

(Ethylenedlnitrilo)tetraacetio acid, manganese salt 

(Ethylenedinitrilo)tetraaoetic acid, monohydrogen 

trisodium salt. 
(Ethylenedinitrilo)tetraaoetic acid, monosodium iron 

salt. 
(Ethylenedinitrilo)tetraaoetic acid, tetrapotassiimi salt 

*(Etlyrlenedlnitrilo)tetraacetic acid, tetrasodium salt 

Hexahydroxyheptanoic acid, sodium salt 

(N-Hydroxyethylethylenedinitrilo)trlacetic acid 

(N-Hydroxyethy letter lenedinitrilo)triacetic acid, iron 
sodium salt. 
*(N-Hydroxyethylethylenedinitrilo ) triacetic acid , 
trisodium salt. 
(N-Hydroxyethylethylenedlnltrilo)triacetic acid, other 
salts. 

Nitrilotriacetic acid, tripotassiinn salt 

Nitrilotriacetic acid, trisodium salt 

All other 

Silicones 

Sodium ethoxide 

Sodium ethyl oxalaeetate 

Sodium formaldehydebisulfite 

»Sodium formaldehydesulfoxylate 

^Sodium methoxlde (Sodium methylate) 

Sodium polypectate 

Sodium sorbitol borate 

Sorbaldehyde (Hexadienal) 

Sorbic acid (2,4-Hexadienoic acid), and potassiim and 
sodiimi salts. 

Sorbitol 

Stearamide (Octadecane amide) 

^Stearic acid salts: 
»Aluminum stearates: 

*Aluminuiii distearate 

»Aliminum monostearate 

^Aluminum tristearate 

Ammonium stearate 

Barium stearate 

Cadmium stearate 

■sfCaloium stearate 

Cobalt stearate 



EK, ' 
FMT. 

HMP. 
GGY. 

DOW, 
DOW, 
DOW, 

DOW. 
EK. 
DOW, 
DOW, 



GGY. 
GGY, 



GGY. 
CRT, 
PCW. 
GGY. 
DOW. 



GGY, HMP, RPC, TCC. 

HMP, MDA. 

GGY, HMP, MDA, VIC. 



EK, GGY, HMP, RPC. 
GGY. 



HMP. 

GGY, HMP, RPC. 



CWL, DOW, G, GGY, HMP, HRT, IBI, NOP, RPC, TCC. 



CRT, CWL, DOW, GGY, HMP, IBI, ^DA, RPC, TCC. 



HMP. 



GGY. 








GGY, HMP, PEN. 








DCC, ORO. 








fMP. 








FMP. 








EK, IDC. 








NOP, RH, ROY. 








BRF, DA, DUP, HSH, KF, 


OMC, 


RBC, 


SFA 


SKG. 








APD. 








UCC. 








UCC. 








APD, BRD, MRK. 








AIM, DUP, FIN, HUM. 









ACY, JTC, LEF, MAL, MCO, NOP, PRP, SYP, WTC. 

ACY, LEF, MAL, MCO, NOP, SYP, WTC. 

ACY, LEF, MAL, MCO, NOP, PRP, SYP. 

DEX, NOP, WTC. 

LEF, MCO, NOP, PRP, SYP, WTC. 

NOP, PRP, SYP, WTC. 

ACY, HNX, JTC, LEF, MAL, MCO, NOP, PRP, SYP, WTC. 

WTC. 



MISCELLAtslEOUS CHEMICALS 



205 



TABLE 21B.- 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1964 — Continued 



Chemical 



MISCELLANEOUS CHEMICAI5, ACYCLIC— Continued 

^<Steario acid salts — Continued 

Copper stearate 

Ferric and ferrous stearates 

*Lead stearate 

Lead stearate, dibasic 

wLithium stearate 

■xMagnesium stearate 

Nickel stearate 

*Zinc stearate 

All other 

Stearonitrile (Ootadecanenitrile) 

Stearoyl chloride 

Stearyl-2-lactic acid 

Succinic acid 

Succinic acid, calcium salt 

Succinic acid, sodium salt 

Succinic anhydride 

Succinimide 

Suocinonitrile 

Suocinyl peroxide 

Sucrose octa-acetate 

*Tallow amide, hydrogenated 

Tallow fatty acyl chloride 

Tallow nitrile 

Tallow nitrile, hydrogenated 

Tartaric acid salts: 

Antimony potassium tartrate 

Potassiimi bitartrate 

Potassium sodium tartrate 

Sodium bitartrate 

All other 

Tetrabutylphosphonium hydroxide 

n-Tetradecane 

1,1,3,3-Tetraethoxypropane 

Tetra(2-ethylbutyl) ortho-silicate 

Tetraethylene glycol 

Tetraethylene glycol dimethacrylate 

*Tetraethyllead 

Tetrahydropseudoionone 

Tetrahydroxysuccinio acid (Dioxytartaric acid) 

TetraMs ( hydr oxymethyl ) phosphonium chloride 

N,N,N',N'-Tetrald.s(2-hydroxypropyl)ethylenediamine— 

1,1,3,3-Tetramethoxypropane 

Tetramethyl(and ethyl) lead 

Tetramethylguanldine 

Tetramethyllead 

Tetraoctyl orthosilicate 

Tetrapropenylsuccinio acid 

Thioacetamide 

Thioaoetic acid 

2,2'-Thiodiethanol (Thiodiethylene glycol) 

3,3' -Thiodipropionic acid 

3,3' -Thlodipropionitrlle 

Thiosemioarbazide 

Titanic acid esters 

Triacetoxyvinylsilane 

Tributylphosphine 

Tributyltin chloride 

Trichloroacetic acid 

Trichloroacetyl chloride 

Trichloroethylsilane (Ethyl silicone trichloride) — 

Trichloromethylsilane 

Trichloropentylsilane 

Trichloropropylsilane 

Triohlorovinylsilane 



Manufacturers' Identification codes 
(according to list in table 22) 



MCO, 


WTC. 
















MCI 


WTC. 
















HSH 


LEF, 


NOP, 


NTL, 


PRP, 


WTC. 








MCO 


NOP, 


NTL. 














FIE 


LEF, 


NOP, 


PRP, 


SYP, 


WTC. 








ACY 


JTC, 


MAL, 


MCO, 


NOP, 


PRP, 


SYP, 


WTC. 




WTC. 


















ACY, 


BCN, 


CCA, 


HNX, 


JTC, 


LEF, 


MAL, 


MCO, NOP, PRP, SYP 


WTC. 
















APD. 


















FOR. 


















G. 


















X. 


















BKC, 


M3N, 


NAC. 














OTC. 


















MAL. 


















NAG. 


















MAC. 


















ACY, 


RSA. 
















ICO, 


WTL. 
















PD, 


UCC. 
















ADM, 


ARC, 


CRT, 


HUM. 












G. 


















FOR, 


GNM. 
















FOR. 


















PFZ. 


















ATC. 


















PFZ. 


















PFZ. 


















BKC. 


















RSA. 


















HMY. 


















KF. 


















UCC. 


















DOW, 


UCC. 
















SAR. 


















DUP, 


HCH, 


TNA. 














GIV. 


















ACY. 


















HK. 


















WYN. 


















KF. 


















DUP. 


















ACY. 


















DUP, 


NLF, 


TRA. 














MON. 


















X. 


















BKC. 


















e™. 


















UCC. 


















CCW, 


ETO. 
















ACY, 


HAB. 
















ACY, 


FMT. 
















DUP. 


















DCC. 


















CCW, 


COK, 


X. 














X. 


















DOW. 


















EK. 


















UCS. 


















DCC. 


















UCS. 


















DCC. 


















DCC, 


UCS. 












- 





206 



SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 2i.B.— Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i 964— Continued 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

Triethoxyvinylsilane 

Triethylaluminum 

*Triethylene glycol 

Trlethylene glycol dlmethaorylate 

Triethyl orthoacetate 

Triethyl orthoformate 

Trietl^rl orthopropionate 

Trifluoroacetaldehyde 

Trifluoroacetio anhydride 

Tri(hexylene glycol) biborate 

Triisobutylaluminum 

Triisodecyl orthoformate 

Trimethoxyboroxine 

Trlmethylaluminum 

Trimethylamine-sulfur trioxide 

2,6,8-Triinethyl-4-nonanone 

Trlmethyl orthoformate 

2,2,'i-Trimethyl-l,3-pentanediol 

2,2,4-Triiiiethyl-l,3-pentanediol monoisobutyrate 

Trimethylpentanol 

Tripropylalumimim 

Tripropylene glycol 

2-Undecanone 

*Urea in compounds or mixtures, 100^: 

»In feed compounds 

*In liquid fertilizer 

*In solid fertilizer 

In plastics 

All other 

Urea peroxide 

Urea urethane copolymer 

Valeraldehyde 

Valeric acid 

*Vinyl acetate, monomer 

Vinyl crotonate 

*Zinc formaldehydesulfoxylate 



Manufacturers ' identification codes 
(according to list in table 22) 



UCS. 

TNA, TSA. 

ACN, CAU, DOW, G, HCH, JCC, OMC, UCC. 

SAR. 

KF. 

KF. 

KF. 

CLB. 

EK. 

USB. 

TNA, TSA. 

KF. 

SFA. 

TNA. 

HEX. 

UCC. 

KF. 

EKX. 

EKX. 

EKX. 

TNA, TSA. 

DOW, UCC. 

TBK. 

ACN, DUP, GCC, JDC, MON, MSC, SHC, SOH. 

ACN, AHM, CFA, CO, DUP, ESC, FCA, GCC, HEC, HPC, JDC, 

KET, MON, MSC, NIT, SHC, SNI, SOH, SPN. 
ACN, DUP, GCC, HPC, JDC, MON, MSC, SHC, SNO, SOH, SPN. 
DUP, MON. 

ACN, DUP, HPC, MON, SHC, SOH. 
FMB. 
DUP. 
UCC. 
UCC. 

AIR, BOR, CEL, DUP, MON, NSC, UCC. 
BKL. 
NOP, RH, ROY. 



DIRECTORY OF MANUFACTURERS 



207 



Directory of Manufacturers 

The Directory of Manufacturers lists the companies that report their production of synthetic 
organic chemicals to the U.S. Tariff Commission. The name of each manufacturer is preceded 
by an alphabetical identification symbol. These identification symbols consist of not more than 
three capital letters, and usually bear a relation to the company name. 

For 1964, the Directory of Manufacturers lists 800 primary manufacturers (see table 22). 
Some of the companies that report production of synthetic organic chemicals do not sell the 
materials, but consume their entire output in further manufacturing. 

The Directory of Manufacturers lists the reporting companies in two ways: Section 1 lists 
them in alphabetical order by identification symbols; section 2 lists the reporting companies in 
alphabetical order by company name, and gives the corresponding identification symbol and the 
company address. Company divisions are usually listed under the parent company's name. 



TABLE 22, — Synthetic organic chemicals: Directory of manufacturers , 1964 

SECTION 1. ALPHABETICAL DIRECTORY BX CODE 

[Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. Tariff Commission for 
1964 are listed below in the order of their identification codes as used intables in pt. III. Sec. 2 of this table 
lists these manufacturers alphabetically and gives their office address] 



Code 


Name of company 


Code 


Name of company 


AAC 


Aloolac Chemical Corp. 


APX 


Apex Chemical Co., Inc. 


AAE 


American Aniline & Extract Co . , Inc . 


AHA 


Arapahoe Chemicals, Inc. 


AAI 


American Alkyd Industries 


ARC 


Armour & Co., Armour Industrial Chemical Co. Div. 


AAP 


American Aniline Products, Inc. 


AHD 


Ardmore Chemical Co. 


ABB 


Abbott Laboratories 


ARC 


Argus Chemical Corp. 


ABS 


American Bralce Shoe Co., American Brakeblok Div. 


ARK 


Armstrong Cork Co. 


ACB 


Allied Chemical Corp. , Barrett Div. 


ARL 


Arol Chemical Products Co. 


ACC 


Amoco Chemicals Corp. 


ARM 


Armour Agricultural Chemical Co. 


ACQ 


Allied Chemical Corp., General Chemical Div. 


ARO 


Mobil Finishes Co., Inc., Arco Div. 


ACN 


Allied Chemical Corp. , Nitrogen Div. 


ARP 


Armour Pharmaceutical Co. 


ACO 


Aerallte Co., Inc. 


ARZ 


Arizona Chemical Co. 


ACP 


Allied Chemical Corp., Plastics Div. 


ASH 


Ashland Oil & Refining Co. 


ACR 


Acme Resin Corp. 


ASL 


Ansiil Chemical Co. 


ACS 


Allied Chemical Corp., Solvay Process Div. 


AST 


Astra Pharmaceutical Products, Inc. 


ACT 


Arthur C. Trask Co. 


ASY 


American Synthetic Rubber Corp. 


ACU 


Allied Chemical Corp., Union Texas Petroleum 


ATC 


American Tartars Corp. 




Div. 


ATL 


Atlantic Chemical Corp. 


ACY 


American Cyanamid Co. 


ATP 


Atco Chemical- Industrial Products, Inc. 


ADC 


Ad-Co Color Corp. 


ATR 


Atlantic Refining Co. 


ADM 


Archer-Daniels -Midland Co. 


ATU 


Atlantic Tubing & Rubber Co. 


AIR 


Air Reduction Co., Inc., Air Reduction Chemical 


AUG 


Augusta Chemical Co. 




& Carbide Co. Div. 


AV 


FMC Corp., American Viscose Div. 


AKS 


Arkansas Co., Inc. 


ATC 


Avisun Corp. 


ALB 


Ames Laboratories, Inc. 


AZT 


Aztec Chemicals, Inc. 


ALC 


Alco Chemical Corp. 






ALD 


Aldrlch Chemical Co., Inc. 


BAC 


Baker Castor Oil Co. 


ALF 


Allied Chemical Corp., Fibers Div. 


BAL 


Baltimore Paint & Chemical Corp. 


ALL 


Alliance Color & Chemical Co. 


BAO 


Bayoil Co., Inc. 


ALO 


Alamo Polymer Corp. 


BAT 


Bates Chemical Co. 


ALT 


Cronipton & Khowles Corp., Althouse Chemical Co. 


BAX 


Baxter Laboratories, Inc. 




Div. 


BC 


Barlow Chemical Corp. 


ALX 


Alox Corp. 


BCM 


Beldlng Chemical Industries 


AMB 


American Bio-Synthetics Corp. 


BCN 


Beacon Chemical Industries, Inc. 


AMC 


Amohem Products, Inc. 


BEN 


Bennett ' s 


AME 


American Chemical Corp. 


BFG 


B. F. Goodrich Co., B. F. Goodrich Chemical Co. Div. 


AMF 


Mobil Finishes Co., Inc., Ferbert-Schomdorfer 


BFR 


Branchf lower Co. 




Div. 


BGC 


Balfour Chemicals, Inc. 


AML 


Amalgamated Chemical Corp. 


BJL 


Burdlck & Jackson Laboratories, Inc. 


AMD 


American Oil Co. (Texas) 


BKC 


J. T. Baker Chemical Co. 


AMP 


American Potash & Chemical Corp. 


BKL 


Millmaster Onyx Corp., Berkeley Chemical Dept. 


AMR 


Pacific Resins & Chemical Co. 


BKM 


BncVman TjihnTstnTlps, Tnn . 


AMS 


Martin-Marietta Corp., Ridgway Color & Chemical 


BKS 


Berkshire Color & Chemical Co. 




Div. 


BKT 


J. T. Baker Chemical Co., Taylor Div. 


ANM 


Ancon Chemical Co. 


BL 


Belle Chemical Co., Inc. 


APC 


Apple ton Coated Paper Co. 


BLA 


Blue Arrow, Inc. 


APD 


Atlas ChemicsLl Industries, Inc., Chemicals Div. 


BLN 


Brooklyn Color Works, Inc, 


APR 


Atlas Processing Co. 


BLS 


Beech-Nut Life Savers, Inc. 


APT 


American Petrochemical Corp. 


BME 


Bendix Corp., Marshall-Eclipse Div. 


APV 


Armstrong Paint & Varnish Works, Inc. 


BOR 


Borden Co., Borden Chemical Co. Div. 



208 SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 22. —Synthetic organic chemicals: Directory of manufacturers , 1964 — Continued 



Name of company 



Walter N. Boysen Co. 

Benzol Products Co. 

Brand Plastics Co. 

Baird Chemical Industries, Inc. 

Bristol-Meyers Co., Bristol Laboratories Div. 

M. A. Bruder & Sons, Inc. 

Bryant Chemical Corp. 

Burkart-Schier Chemical Co. 

Blaciman-Uhler Chemical Co. 

Buckeye Cellulose Corp. 

Burroughs -Wellcome & Co. (U.S.A.), Inc. 

J. H. Baxter & Co. 

Cadet Chemical Coi-p. 

Callery Chemical Co. 

Cap-Roc, Inc., Capital Plastics Div. 

Catalin Corp. of America 

Calcasieu Chemical Corp. 

Ciba Corp., Ciba Products Co. 

Georgia-Pacific Corp., Coos Bay Div. 

Central Processing Co. 

Carborundum Co., Coated Abrasives Div. 

Columbian Carbon Co., Pigments & Elastomers 

Div. 
Ciba Corp., Ciba Pharmaceutical Co. Div. 
Colab Resin Corp. 
Samuel Cabot, Inc. 
Crosby Chemicals, Inc. 

Carlisle Chemical Works, Inc., Advance Div. 
Chase Chemical Corp. 
Pearsall Chemical Co. 
Checkmate Chemicals, Inc. 
Charlotte Chemical Laboratories 
Chemioo, Inc. 

Crown Central Petroleum Corp. 
Carlisle Chemical Works, Inc. 
Budd Co., Polychem Div. 
Celanese Corp. of America: 

Celanese Chemical Co. Div. 

Celanese Plastics Co. Div. 
Chemirad Corp. 

Cooperative Farm Chemicals Association 
Rexall Chemical Co. - Kearny 
Cargill, Inc. 

Chipman Chemical Co., Inc. 
Chemagro Corp. 
Chemol, Inc. 

Stauffer Chemical Co., Calhio Chemicals Div. 
Chattanooga Medicine Co., Chattem Chemicals 

Div. 
Ciba Chemical & Dye Co. 
Cal/Ink Co., Inc. 
Cindet Chemicals, Inc. 
Chemical Insecticide Corp. 
Chemlek Laboratories, Inc. 
Columbia Organic Chemicals Co., Inc. 
Charles L. Huisking & Co., Inc., Clintbrook 

Chemical Co. Div. 
Colloids, Inc. 
Clintwood Chemical Co. 
Clark Oil & Refining Corp. 
Standard Brands, Inc., Clinton Com Processing 

Co. Div. 
Clover Chemical Co. 
W. A. Cleary Corp. 
Carpenter-Morton Co. 
Nyanza, Inc. 

Commercial Products Co., Inc. 
Continental Oil Co. 
Cockerille Chemicals, Inc. 
Collier Carbon & Chemical Corp. 
Commercial Solvents Corp. 
Concord Chemical Co., Inc. 



COP 

CP 

CPC 

CPD 

CPT 

CPV 

CPY 

CRC 

CRN 

CRS 

CRT 

CRY 

CRZ 

CSD 

CSO 

CST 

CTA 

CTL 

CTN 

cue 

CUL 

CUT 

CW 

CWL 

CWN 

CWP 

DA 

DAN 

DAV 

DBC 

DCC 

DCI 

DEG 

DEP 

DEX 

DLH 

DLI 

DOD 

DOM 

DOW 

DPP 

DRL 

DRW 

DSC 

DSO 

DUN 

DUP 

DUR 

DVC 

IX/S 

EAK 

ECC 

EDO 

EFH 

EK 

EKT 

EKX 

ELP 

EMK 

EMR 

EN 

ENJ 

EPC 

ESC 

ETD 

EVN 

EW 

FAB 
FAR 



Name of conpany 



Coopers Creek Chemical Corp. 

Colgate-Palmolive Co. 

Childs Pulp Colors, Inc. 

Chemical Products Corp. 

Consolidated Paint Co. 

Cook Paint & Varnish Co. 

Copolymer Rubber & Chemical Corp. 

Crown Chemical Corp. 

Com Products Co. 

Carus Chemical Co., Inc. 

Crest Chemical Corp. 

Tenneco Manufacturing Co., Tenneco Plastics Div. 

Crown Zellerbach Corp., Chemical Products Div. 

Cosden Oil & Chemical Co. 

Cities Service Oil Co. 

Charles S. Tanner Co. 

Conestoga Chemical Corp. 

Continental Chemical Co. 

Chemetron Corp., Chemetron Chemicals, Organic 

Chemical Dept. 
Cumberland Chemical Corp. 
Culver Chemical Co. 
Cutter Laboratories, Inc. 
General Mills, Inc., Chemical Div. 
Cowles Chemical Co. 
Upjohn Co., Carwin Co. Div. 
Consolidated Papers, Inc. 

Diamond Alkali Co., and Western Div. 

Dan River Mills, Inc. 

Conchemco, Inc., H. B. Davis Co, Div. 

Dow Badische Chemical Co. 

Dow Coming Corp. 

Delaware Chemicals, Inc. 

Degen Oil & Chemical Co. 

DePaul Chemical Co., Inc. 

Dexter Chemical Corp. 

Hess Oil & Chemical Corp. 

Dawe's Laboratories, Inc. 

Donald A. Dodd 

Dominion Products, Inc. 

Dow Chemical Co. 

Dixie Pine Products Co., Inc. 

Caradco, Inc., Durel Div. 

Drew Chemical Corp. 

Dye Specialties, Inc. 

DeSoto Chemical Coatings, Inc. 

Frank W. Dunne Co. 

E. I. duPont de Nemours & Co., Inc. 

Duraphene Corp. 

Dover Chemical Co. 

Sunray DX Oil Co. 

J. S. & W. R. EaMns, Inc. 

Eastern Color & Chemical Co. 

Edoan Laboratories 

E. F. Houghton S; Co. 

Eastman Kodak Co. 

Eastman Kodak Co., Tennessee Eastman Co. Div. 

Eastman Kodak Co., Texas Eastman Co. Div. 

El Paso Natural Gas Products Co. 

Emkay Chemical Co. 

Emery Industries, Inc. 

Endo Laboratories, Inc. 

Enjay Chemical Co., Div. of Humble Oil & Refining Co. 

Epoxylite Corp. 

Escambia Chemical Corp. 

Ethyl-Dow Chemical Co. 

Evans Chemetics, Inc. 

Westinghouse Electric Corp., Wicarta Div. 

Fabricolor Manufacturing Corp. 
Famow, Inc. 



DIRECTORY OF MANUFACTURERS 209 

TABLE 22. —Synthetic organic chemicals.- Directory of manufacturers , 2964— Continued 



FB 

FBF 

FBR 

FC 

FCA 

FCD 

FCL 

FCP 

FEL 

FEE 

FG 

FH 

FIN 

FIR 



Name of company 



Fritzsohe Bros., Inc. 

FlberfU, Inc. 

Fibreboard Paper Products Corp. 

Franliin Chemical Co. 

Farmers Chemical Association, Inc. 

France, Canipbell & Darling, Inc. 

Federal Color Laboratories, Inc. 

J. P. Frank Chemical & Plastic Corp. 

Felton Chemical Co., Inc. 

Ferro Corp., Ferro Chemical Div. 

Foster Grant Co., Inc. 

Foster-Heaton Co. 

Fine Organios, Inc. 

Firestone Tire & Rubber Co., Firestone 

Plastics Co. Div. 
H. B. Fuller Co. 

Florasynth Laboratories, Inc. 

W. P. Fuller Paint Co. 

FMC Corp., Inorganic Chemicals Div. 

FMC Corp., Niagara Chemical Div. 

Fermoo Laboratories, Inc. 

FMC Corp., Organic Chemicals Div. 

Fairmount Chemical Co., Inc. 

Farac Oil & Chemical Co. 

Formica Corp. 

Foremost Chemical Products Co. 

Freeman Chemical Corp. 

Firestone Tire & Rubber Co., Firestone 

Rubber & Latex Products Co. Div. 
Farmers' Chemical Co. 
Vulcan Materials Co., Frontier Chemical Co. 

Div, 
Filtered Rosin Products Co. 
Firestone Tire & Rubber Co., Firestone 

Synthetic Rubber & Latex Co. Div. 
Frisch & Co., Inc. 
Foote Mineral Co. 

General Aniline & Film Corp. 

Gamma Chemical Corp. 

Gane's Chemical Works, Inc. 

W. H. Grace & Co., Nitrogen Products Div. 

Lancaster Chemical Corp., Gordon Chemicals Co 
Div. 

General Electric Co., Chemical Materials 
Dept. 

General Electric Co. , Insulating Materials 
Dept. 

Geolina Business, Inc. 

G. Frederick Smith Chemical Co. 

Goodrich-Gulf Chemicals, Inc. 

Geigy Chemical Corp. 

Gilman Paint & Vamish Co. 

Givaudan Corp. 

General Latex & Chemical Corp. 

Glidden Co. 

Glasflex, Inc. 

Glyco Chemicals, Inc. 

General Foods Corp., Maxwell House Div. 

General Mills, Inc. 

General Tire & Rubber Co., Chemical Div. 

Gulf Oil Corp. 

Gordon Chemical Co., Inc. 

General Plastics Manufacturing Co. 

Grain Processing Corp. 

Great American Chemical Corp. 

W. R. Grace & Co., Dewey & Almy Chemical Div. 

P. D. George Co. 

W. R. Grace & Co., Hatco Chemical Div. 

W. R. Grace & Co., Polymer Chemicals Div. 

Pontiac Refining Corp. 

Guardsman Chemical Coatings, Inc. 

Great Western Sugar Co. 

Guth Chemical Co. 



Code 



GTL 
GUA 
GYR 

HAB 
HAL 
HAM 
HAN 
HAP 
HAR 

HCH 

HCO 

HDG 

HER 

HET 

HEX 

HFT 

HK 

HKD 

HKT 

HLC 

HLI 

HMP 

ma 

HN 

HNC 

HNW 

HNX 

HOF 

HOU 

HPC 
HRS 
HRT 
HSC 
HSH 
HST 
HUM 

HUS 
HVG 
HYC 
HYN 

IBI 
ICC 
ICF 
ICI 
ICO 
IDC 
IFF 
ILC 
IMC 
IMP 
IMR 
INL 
INP 
IOC 
IPC 

IPI 

IPR 
IRC 
IRI 
ISO 

JAM 
JCC 
JDC 
JEN 
JMS 
JNS 
JNT 
JOB 



Name of company 



Great Lakes Chemical Corp. 
Guard Chemical Co., Inc. 
Goodyear Tire & Rubber Co. 

Halby Products Co., Inc. 

C. P. Hall Co. of Illinois 

Hampden Color & Chemical Co. 

Hanna Paint Manufacturing Co., Inc. 

Applied Plastics Co., Inc. 

Allied Chemical Corp., National Aniline Div., 

Harmon Color Works 
Houston Chemical Corp. 
Hamilton Chemical Corp. 
Hodag Chemical Corp. 
Heresite & Chemical Corp. 
Heteroohemlcal Corp. 
Hexagon Laboratories, Inc. 
Hoffman-Taff, Inc. 
Hooker Chemical Corp. 

Hooker Chemical Corp., Durez Plastics Div. 
Hawkeye Chemical Co. 
Hartman-Leddon Co. 
Haag Laboratories, Inc. 
Hampshire Chemical Corp. 
Humphrey Chemical Corp. 
Tenneco Chemicals, Inc. 
H & N Chemical Co. 

Tenneco Chemicals, Inc., Newport Div. 
Tenneco Chemicals, Inc., Nuodex Div. 
Hoffmann-LaRoche, Inc. 
Air Products & Chemicals, Inc., Houdry Process 

& Chemical Co. Div. 
Hercules Powder Co. 
Bernz-o-Matio, Harris Paint Co. Div. 
Hart Products Corp. 
Holland-Suoo Color Co. 
Harshaw Chemical Co. 
Hoechst Chemical Corp. 
National Dairy Products Corp., Humko Products 

Chemical Div. 
Husky-Dominion Briquets 

Haveg Industries, Inc., Resin & Compound Div. 
Hysol Corp. 
Hynson, Westoott & Dunning, Inc. 

Industrial Bioohemicals 

Interohemical Corp., Color & Chemicals Div. 

Interchemioal Corp., Finishes Div. 

I.C.I. (Organios), Inc. 

Interchemical Corp.,. Organic Chemicals Dept. 

Industrial Dyestuff Co. 

International Flavors & Fragrances, Inc. 

International Latex Corp. 

International Minerals & Chemical Corp. 

Hercules Powder Co., Imperial Color & Chemical Dept. 

Imperial Chemical Co., Inc. 

Inland Steel Container Co. 

International Paper Co. 

Pfaiidler Permutlt, Inc., lonao Chemical Co. Div. 

Interplastio Corp., Commercial Resins Div. 

Isooyanate Products, Inc. 

Inter-Pacific Resins, Inc. 

International Resistance Co. 

Ironsides Resins, Inc. 

Isoohem Resins Co. 

Jamestown Paint & Vamish Co. 

Jefferson Chemical Co., Inc. 

John Deere Chemical Co. 

Jennison-Wright Corp. 

J. Meyer & Sons, Inc. 

S. C. Johnson & Son, Inc. 

Jennat Corp. 

Jones -Blair Paint Co. 



210 SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 22. — Synthetic organic chemicals: Directory of manufacturers , 1964 — Continued 



Code 


Name of company 


Code 


Name of company 


JOD 


Devoe & Reynolds Co., Inc., Jones-Dabney Dlv. 


MET 


M & T Chemicals, Inc. 


JOR 


W. H. & F. Jordan, Jr. Manufacturing Co., 


MFC 


Molded Fiber Glass Body Co., Resin Div. 




Inc. 


MGR 


Magruder Color Co., Inc. 


JRG 


Andrew Jergens Co. 


MHI 


Metal Hydrides, Inc. 


JSC 


Jersey State Chemical Co. 


MID 


Midland Industrial Finishes Co. 


JTC 


Joseph Turner & Co. 


MIR 


Miranol Chemical Co., Inc. 


JWL 


Jewel Paint & Varnish Co. 


MLD 


Metalead Products Corp. 






MLS 


Miles Laboratories, Inc., Miles Chemical Co. Div. 


KAI 


Kaiser Aluminum & Chemical Corp. 


MMM 


Minnesota Mining & Manufactijring Co. 


KAl 


Kali Manufacturing Co. 


MNO 


Monochem, Inc. 


KCC 


Kenneeott Copper Corp., Chino Mines Div. 


MNP 


Minnesota Paints, Inc. 


KCH 


Keystone Cheraurgic Corp. 


MOA 


Mona Industries, Inc. 


KCU 


Kenneeott Copper Corp., Utah Copper Div. 


MOB 


Mobay Chemical Co. 


KCW 


Keystone Color Works, Inc. 


MOC 


Marathon Oil Co., Texas Refining Div. 


KEL 


Kelly-Piokering Chemical Corp. 


MON 


Monsanto Co. 


KEN 


Kendall Refining Co. 


MOR 


Mineral Oil Refining Co. 


KES 


Armour Industrial Chemical Co., Kessler 


MOT 


Motomco, Inc. 




Chemical Dlv. 


MPL 


Massachusetts Plastic Corp. 


KET 


Ketona Chemical Corp. 


MPP 


Midwest Plastic Products Co. 


KF 


Kay-Fries Chemicals, Inc. 


MR 


Benjamin Moore & Co. 


KLS 


Kilsdohk Chemical Corp. 


MRA 


Metro-Atlantic, Inc. 


KMC 


Kohler-McLister Paint Co. 


MRS 


Marble tte Corp. 


KMP 


Kelly-Moore Paint Co. 


MRD 


Marden-Wild Corp. 


KND 


Knoedler Chemical Co. 


MRK 


Merck & Co., Inc. 


KNG 


Far-Best Corp., 0. L. King Div. 


MRN 


Morningstar Paisley, Inc. 


KHP 


Knapp Products, Inc. 


MRO 


Marco Chemical Corp. 


KON 


H. Kohnstamm & Co., Inc. 


MRT 


Morton Salt Co., Morton Chemical Co. Div. 


KPI 


Kenrich Petrochemicals, Inc. 


MRV 


Marlowe-Van Loan Corp. 


KPP 


Koppers Co., Inc., Plastics Div. 


MRX 


Max Marx Color & Chemical Co. 


KPS 


Koppers Pittsburgh Co. 


MSC 


Mississippi Chemical Corp. 


KPT 


Koppers Co., Inc., Tar & Chemical Div. 


MIL 


Metals alts Corp. 


KRM 


Lawter Chemicals, Inc., Krumbhaar Resin Div. 


MIO 


Montrose Chemical Corp. of California 


KYN 


Kyanize Paints, Inc. 


MTR 


Baldwin-Montrose Chemical Co., Inc., Montrose 


KYS 


Keysor Chemical Co. 




Chemical Div. 






MYW 


Stepan Chemical Co., Maywood Dlv. 


LAK 


Lakeway Chemical Co. 






LAM 


LaMotte Chemical Products Co. 


NAC 


Allied Chemical Corp., National Aniline Div. 


LAS 


Lasco Industries, Inc. 


NCI 


Union Bag-Camp Paper Corp., Nelio Chemical Div. 


LEA 


Leatex Chemical Co. 


NOW 


Nostrip Chemical Works, Inc. 


LEB 


Lebanon Chemical Corp. 


NED 


Norda Essential Oil & Chemical Co., Inc. 


LEF 


Leffingwell Chemical Co. 


NEP 


Nepera Chemical Co., Inc. 


LEH 


Lehigh Chemical Co. 


NES 


Nease Chemical Co., Inc. 


LEM 


B. L. Lemke & Co., Inc. 


NEV 


Neville Chemical Co. 


LEN 


Leonard Refineries, Inc. 


NIL 


Nilok Chemicals, Inc. 


LEV 


Lever Brothers Co. 


NIT 


Nitrin, Inc. 


LIL 


Eli Lilly & Co. 


NIX 


Nixon-Baldwin Chemicals, Inc. 


LKL 


Lakeside Laboratories, Div. of Colgate- 


NLC 


Nalco Chemical Co. 




Palmolive Co. 


NLF 


Nalco Chemical Co., Freeport Div. 


LKY 


St. Regis Paper Co., Lake States Yeast & 


NOC 


Norac Co., Inc. 




Chemical Div. 


NON 


A. P. Nonweiler Co. 


LMI 


Lawrence Mills, Inc. 


NOP 


Nopco Chemical Co., Inc. 


LON 


Mobil Finishes Co . , Inc . , American-Marietta 


NOR 


Norwich Pharmacal Co. 




Paint Div. 


NPC 


Northwest Petrochemical Corp. 


LPC 


Lignin Products Co. 


NPI 


National Polychemicals, Inc. 


LUB 


Lubrizol Corp. 


NPP 


National Plastic Products Co., Inc. 


LUE 


George Lueders & Co. 


NPV 


Norris Paint & Varnish Co. 


LUH 


Laurel Soap Manufacturing Co. 


NRS 


Norse Chemical Corp. 


LVR 


C . Lever Co . , Inc . 


NSC 


National Starch & Chemical Corp. 


LVY 


Fred'k H. Levey Co., Inc. 


NSP 


Alabama Binder & Chemical Coit>. 






NTB 


National Biochemical Co. 


MAH 


Maher Color & Chemical Co. 


NTC 


National Casein Co. 


MAK 


MaoKenzie Chemical Works, Inc. 


NTL 


National Lead Co. 


MAL 


Mallinckrodt Chemical Works 


NVF 


National Vulcanized Fibre Co. 


MAR 


American Can Co., Marathon Div. 


NVT 


Novamont Corp. 


MAY 


Otto B. May, Inc. 


NW 


Northwestern Chemical Co. 


MCA 


Masonite Corp., Alpine Chemical Div. 


NYC 


American Dyewood Co., Inc., New York Color & 


MCB 


Borg-Wamer Corp., Marbon Chemical Div. 




Chemical Co. Div. 


MCC 


McCloskey Varnish Co. 






MCH 


Michigan Chemical Corp. 


OCF 


Owens -Coming Fiberglas Corp. 


MCI 


Mooney Chemical Corp. 


OH 


Air Reduction Co., Inc., Ohio Chemical & Surgical 


MCO 


Mathe Chemical Co. 




Equipment Co. Div. 


MED 


Medical Chemicals Corp. 


OLH 


Old Hickory Chemical Co. 


MEE 


Maumee Chemical Co. 


OMC 


Olin Mathieson Chemical Corp. 


MER 


Jefferson Lake Sulphin? Co., Chemical Div. 


OMS 


Olin Mathieson Chemical Corp., E.R. Squibb & Sons Div. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. — Synthetic organic chemicals.- Directory of manufacturers , 1964 — Continued 



Name of company 



Name of company 



Millmaster Onyx Corp., Onyx Chemloal Co. Div. 

Orbis Products Corp. 

Organics, Inc. 

California Chemical Co., Oronite Div. 

Roehr Chemicals, Inc. 

Eagle-Picher Co., Ohio Rubber Co. Div. 

C. J. Osborn Co. 

Ottawa Chemical Co. 

Ott Chemical Co. 

California Chemloal Co., Ortho Div. 

Oxo Chemicals Co. 

Onyx Oils & Resins, Inc. 

Oxy Chemical Co. 

Pennsylvania Indiistrial Chemical Corp. 

Pan American Petroleum Corp. 

Pennsylvania Refining Co. 

Pennsalt Chemicals Corp. 

Patent Chemicals, Inc. 

Pillsbury Co., Chemical Div. 

Proctor Chemical Co., Inc. 

Pittsburgh Chemical Co., Div. of U.S. Steel 
Co. 

Peerless Chemical Co. 

Pioneer Chemical Works, Inc. 

Emery Industries, Inc., Western Div. 

Pfister Chemical Works 

Park, Davis & Co. 

Bemoolors-Poughkeepsie, Inc. 

Joseph Davis Plastics Co. 

Peck's Products Co. 

Pelron Corp. 

S. B. Penick & Co. 

Perry & Derrick Co. 

Petroleum Chemicals, Inc. 

Pfanstiehl Laboratories, Inc. 

Phelan-Faust Paint Manufacturing Co. 

Polak's Frutal Works 

Chas. Pfizer & Co., Inc. 

Procter & Gamble Co., Procter & Gamble Manu- 
facturing Co. Div. 

Gulf Oil Corp., Spencer Chemical Div., 
Perkins Glue Branch 

Pharmachem Corp. 

Pierce Chemical Co. 

Polymer Industries, Inc. 

Pilot Chemical Co. 

Pitt-Consol Chemloal Co. 

Richardson Co., Richardson Polymers Div. 

P-L Biochemicals, Inc. 

Phillips Petroleum Co. 

Plastics Engineering Co. 

Plumb Chemical Corp. 

Plastics Materials, Inc. 

Plastics Manufacturing Co. 

Premier Malt Products, Inc. 

Pantasote Co. 

Phoenix Oil Co. 

Polymer Corp. 

Pittsburgh Plate Glass Co. 

Pioneer Plastics Corp. 

Products Research Co. 

Productol Chemical Co. 

Pure Oil Co. 

S. B. Penick & Co., Parsons -Plymouth Div. 

Pratt & Lambert, Inc. 

Purex Corp . , Ltd . 

Georgia-Pacific Corp., Puget Sound Div. 

Petro-Tex Chemloal Corp. 

Publioker Industries, Inc. 

Polyvinyl Chemicals, Inc. 

Polyohemioal Laboratories, Inc. 

Poly Resins 

Polyrez Co., Inc. 



QCP 
QKO 

auN 

RAB 
RBC 
RCC 
RCD 
HCI 
RDA 
RED 
REH 

REL 

REM 

RET 

REZ 

RGC 

RH 

RIC 

RIK 

RIL 

RIV 

RLS 

RMC 

ROC 

ROM 

ROY 

RFC 

RPI 

RSA 

BSE 

RT 

RTC 

RTF 

RTX 

RUB 

RUR 

R2X 



SAC 
SAL 
SAR 
SBC 
SBR 

sec 

SCF 

SCH 

SON 

SCO 

SCP 

SCR 

SDC 

SDG 

SDH 

SDW 

SEA 

SED 

SEK 

SEL 

SEP 

SEY 

SF 

SFA 

SH 

SHA 

SHC 

SHF 

SHL 
SHM 
SHO 
SHP 



Quaker Chemical Corp. 

Quaker Oats Co. 

K. J. Quinn & Co., Inc. 

Raybestos-Manhattan, Inc., Raybestos Div. 

Roberts Chemicals, Inc. 

Rexall Chemical Co. 

Richardson Co. 

Reiohhold Chemicals, Inc. 

Rhodia, Inc. 

Red Spot Paint & Varnish Co., Inc. 

Rebels Chemical Co., Div. of Armour Pharmaceutical 

Co. 
Reliance Universal, Inc. 
Remington Arras Co . , Inc . 
Rayette , Inc . 
Rezolin, Inc. 
Rogers Corp. 
Rohm & Haas Co. 
Richfield Oil Corp. 
Riker Laboratories, Inc. 
Reilly Tar & Chemical Corp. 
River dale Chemical Co. 
Rachel Laboratories 
Rinshed-Mason Co. 

Rook Hill Printing & Finishing Co. 
Roma Chemical Corp. 
Royoe Chemical Co. 
Refined Products Co. 
Rowland Products, Inc. 
R. S. A. Corp. 
Rosenberg Bros. & Co. 
F. Hitter & Co. 
Hitter Chemical Co., Inc. 
Retzloff Chemical Co. 
Riegel Textile Corp. 
Rubber Corp. of America 
Ruberoid Co. 
Rozilda Laboratories, Inc. 

Sandoz, Inc. 

Southeastern Adhesives Co. 

Dr. Salsbury's Laboratories 

Sartomer Resins, Inc. 

Scher Bros . , Inc . 

Schwarz BioResearoh, Inc. 

Standard Chlorine Chemical Co., Inc. 

Schaefer Varnish Co., Inc. 

Sobering Corp. 

Schenectady Chemicals, Inc. 

Soholler Bros., Inc. 

Standard Chemical Products, Inc. 

H. P. Soberer Corp. 

Martin-Marietta Corp 

Sterling Drug, Inc., 

Sterling Drug, Inc., 

Sterling Drug, Inc., 

Seaboard Chemicals, Inc 

Seidlitz Paint & Varnish Co. 

Sekisui Plastics Corp. 

Selney Co., Inc. 

Southeast Polymers, Inc. 

Seydel-Woolley & Co., Inc. 

Stauffer Chemical Co., Industrial Chemloal Div. 

Staiiffer Chemical Co., Anderson Chemloal Co. Div. 

Stein, Hall & Co., Inc. 

Shanco Plastics & Chemicals, Inc. 

Shell Oil Co., Shell Chemical Co. Div. 

National Dairy Products Corp . , Sheffield Chemical 

Co. Div. 
Shulton, Inc., Fine Chemioals Div. 
Shamrock Oil & Gas Corp. 
Shell Oil Co. 
Shepherd Chemical Co. 



, Southern Dyestuff Co. Div. 
Glenbrook Laboratories Div. 
Hilton-Davis Chemical Co. Div. 
Winthrop Laboratories Div. 



212 



SYNTHETIC ORGANIC CHEMICALS, 1964 
TABLE 22. -Synthetic organic chemicals: Directory of manufacturers , 1964— Conthived 



Name of company 



Silmax Chemical Corp. 
George F. Siddall Co., Inc. 
Simpson Timber Co. 
Sinclair Refining Co. 
Standard Oil Co. of Ohio 
James P. Sipe & Co. 
Smith, Kline & French Laboratories 
Sinclair Koppers Chemical Co. 
SunJd-St Growers, Inc. 
Skelly Oil Co. 
Soluol Chemical Co., Inc. 
Sterling Drug, Inc., Salvo Chemical Div. 
Socony Mobil Oil Co., Inc.: 
Mobil Chemical Co. Div. 
Mobil Oil Co. Div. 
Stamford Chemical Co. 
Ansbaoher-Siegle Corp., Div. of Sun Chemical 

Corp. 
Sonooo Products Co. 
Southern Nitrogen Co., Inc. 
SunOlin Chemical Co. 
Suntide Refining Co. 

Sun Chemical Corp., Warwick Chemical Co. Div. 
Standard Oil Co. of California, California 

Chemical Co. Div. 
Signal Oil & Gas Co., Houston Div. 
Sohio Chemical Co., Agent: 
Sohio Petroleum Co. 
Solar Nitrogen Chemicals, Inc. 
American Oil Co. (Maryland) 

Solar Chemical Corp. 

Witco Chemical Co., Inc., Sonneborn Div. 

Thomason Industries, Inc., Southern Resin 
Div. 

Southern Sizing Co. 

Sinclair Paint Co. 

General Electric Co., Silicone Products Dept, 

Sinclair Petrochemicals, Inc. 

Spaulding Fibre Co., Inc. 

Gulf Oil Corp., Spencer Chemical Div. 

Socony Paint Products Co. 

Standard Pyroxoloid Corp. 

Shawinigan Resins Corp. 

G. D. Searle & Co. 

Fred'k A. Stresen-Reuter, Inc. 

A. E. Staley Manufacturing Co. 

Sou-Tex Chemical Co., Inc. 

Standard Dyestuff Corp. 

Stange Co. 

Stepan Chemical Co. 

Sucro-Chemical Div. of Colonial Sugars Co. 

Summit Chemical Products Corp. 

Sun Oil Co. 

Sullivan Varnish Co. 

Solvent Chemical Co., Inc. 

Sherwin-Williams Co. 

Soiihegan Wood Products, Inc. 

Switzer Bros., Inc. 

Swift & Co. 

Synthetic Chemicals, Inc. 

Synthron, Inc . 

Synthetic Products Co. 

Synoo Resins, Inc. 

Synvar Corp. 

Thomas A. Edison Industries, McGraw-Edison 

Co., Medical Gas Div. 
Taylor Corp. 
Universal Oil Products Co., Trubek Chemical 

Co. Div. 
Tanatex Chemical Corp. 
Trylon Chemical Corp. 
Texlze Chemicals, Inc. 
Diversey Corp. 



Name of company 



TEN 

TGL 

THC 

TIC 

TID 

TKL 

TMH 

TMS 

TNA 

TNC 

TNI 

TNP 

TOG 

TRC 

TRJ 

TRN 

TRO 

TSA 

TTX 

TUS 

TV 

TX 

TXC 

TXT 



UCC 
UCP 
UCS 
UDI 
UHL 
UNC 
UNG 
UNN 
UNO 
UNP 
UNS 
UOC 
UPC 
UPF 
UPJ 
UPl 

UPM 
UPR 
URC 
USB 
USI 



USD 
USP 
USR 
UTR 
UVC 

VAC 

VAL 

VAR 

VB 

VC 

VDM 
VEL 
VGC 
VIC 
VIN 
VIS 
VLY 
VNC 
VND 
VPC 



Tennessee Copper Co. 

Triangle Chemical Co. 

Thompson Chemical Co. 

Tioonderoga Chemical Corp. 

Tidewater Oil Co. 

Thiokol Chemical Corp. 

Thompson-Hayward Chemical Co. 

Sterling Drug, Inc., Thomasset Colors Div. 

Ethyl Corp. 

Tennant Development Corp., Chemical Div. 

Toni Co. 

Velsicol Chemical Corp., Tensyn Div. 

Tenneco Oil Co. 

Toms River Chemical Corp. 

Trojan Powder Co. 

Trancoa Chemical Corp. 

Troy Chemical Go. 

Texas Alky Is, Inc. 

Detrex Chemical Industries, Inc. 

Texas-U.S. Chemical Co. 

Tousey Varnish Co. 

Texaco, Inc. 

Tex Chem Co. 

Textilana Corp. 

A. E. Staley Manufacturing Co., UBS Chemical 

Co. Div. 
Union Carbide Corp., Chemicals Div. 
Union Carbide Corp., Plastics Div. 
Union Carbide Coirp., Silicones Div. 
Universal Detergents, Inc. & Petrochemicals Co. 
Paul Uhlich & Co., Inc. 
United Cork Companies 
Ungerer & Co. 

United Chemical Corp. of Norwood 
United Oil Manufacturing Co. 
United Chemical Products Corp. 
Union Starch & Refining Co., Inc. 
Union Oil Co. of California 
Upjohn Co., Polymer Chemicals Div. 
United States Pipe & Foundry Co. 
Upjohn Co. 
United States Plywood Corp., California Div., 

Shasta Operations 
Universal Oil Products Co. 
U.S. Peroxygen Corp. 
United Carbon Co. 
U.S. Borax Research Corp. 
National Distillers & Chemical Corp.: 

A-B Chemical Corp. Div. 

National Petro Chemical Corp. Div. 

U.S. Industrial Chemicals Co. Div. 
U.S. Oil Co. 

U.S. Plastic & Chemical Corp. 
Naugatuok Chemical Div. of U.S. Rubber Co. 
Utah Resin Co., Inc. 
Universal Chemicals Corp. 

Vamey Chemical Co. 

Valchem 

Reichhold Chemicals, Inc., Varcum Chemical Div. 

Verml lye-Bell 

Socony Mobil Oil Co., Inc., Virginia-Carolina 

Chemical Co. Div. 
Van De Mark Chemical Co. 
Velsicol Chemical Corp. 
Virginia Chemicals, Inc. 

Stauf fer Chemical Co. , Victor Chemical Works Div. 
Vineland Chemical Co. 
Nalco Chemical Co., Visco Div. 
Chem-Fleur, Inc. 
Vanderbilt Chemical Corp. 
Van Dyk & Co., Inc. 
Verona-Pharma Chemical Corp. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. Synthetic organic chemicals: Directory of manufacturers , 1964 — Continued 



213 



Code 


Name of company 


Code 


Name of company 


VPT 


Vickers Refining Co., Inc. 


WLI 


White Laboratories, Inc. 


VSV 


Valentine Sugars, Inc., Valite Div. 


WLM 


Wilmot & Cassidy, Inc. 


VTM 


Vitamins , Inc . 


WM 


Wilson & Co., Inc., Wilson-Martin Div. 


VTV 


Vita-Var Corp., Div. of Textron Industries, 


WOD 


Wood Chemicals, Inc. 




Inc. 


WOI 


Neville Chemical Co. , Chlorinated Products Div. 






WON 


Woonsocket Color & Chemical Co. 


WAS 


Washtum-Purex Co. 


WPC 


Warren Paint & Color Co. 


WAW 


W. A. Wood Co. 


WRC 


Wood Ridge Chemical Corp. 


WAY 


Philip A. Hunt Chemical Corp., Way land Chem- 


WRD 


Weyerhaeuser Co., Wood Products Div. 




ical Div. 


WSN 


Washine Chemical Corp. 


WBC 


Worthlngton Biochemical Corp. 


WTC 


Witco Chemical Co., Inc. 


WBQ 


White & Bagley Co. 


WTH 


Wallace & Tieman, Inc., Harchem Div. 


WCA 


West Coast Adhesives Co. 


WTL 


Wallace & Tieman, Inc., Lucidol Div. 


WDC 


Western Diy Color Co. 


WVA 


West Virginia Pulp & Paper Co. , Polychemioals 


WHI 


White & Hodges, Inc. 




Div. 


WHl 


Whitmoyer Laboratories, Inc. 


WYN 


Wyandotte Chemicals Corp. 


WHW 


Whltteraore -Wright Co., Inc. 


WYT 


American Home Products Corp., Wyeth Laboratories, 


WIC 


Wica Chemicals, Inc. 




Inc. Div. 


WIL 


Wilson & Co., Inc., Wilson Laboratories Div. 






WJ 


Wamer-Jenkinson Manufacturing Co. 


YAW 


Young Aniline Works, Inc. 



2,4 SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 22.— Synthetic organic chemicals: Directory of manufacturers , 1964— Contmued 

SECTION 2. ALPHABETICAL DIRECTORY BY COMPANY 

[Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. Tariff Connnission 
for 1964 are listed below alphabetically, together with their identification codes as used in tables in pt. III. 
Sec. 1 of this table lists these manufacturers in the order of their identification codes] 



ARD 
AHG 
ARZ 
AKS 
ARM 

ARC 
KES 
AEP 



Name of company 



Abbott Laboratories 

Acme Resin Corp 

Acralite Co., Inc 

Ad-Co Color Corp 

Air Products & Chemicals, Inc., Houdry Process 

& Chemical Co. Div. 
Air Reduction Co., Inc.; 

Air Reduction Chemical & Carbide Co. Div 

Ohio Chemical & Surgical E^iuipment Co. Div 

Alabama Binder & Chemical Corp 

Alamo Polymer Corp 

Alco Chemical Corp 

Alcolac Chemical Corp 

Aldrich Chemical Co., Inc 

Alliance Color & Chemical Co 

Allied Chemical Corp.: 

Barrett Div 

Fibers Div 

General Chemical Div 

National Aniline Div 

Harmon Color Works 

Nitrogen Div 

Plastics Div 

Solvay Process Div 

Union Texas Petroleum Div 

Alox Corp 

Amalgamated Chemical Corp 

Amchem Products, Inc 

American Alkyd Industries 

American Aniline & Extract Co., Inc 

American Aniline Products, Inc 

American Bio-Synthetics Corp 

American Brake Shoe Co., American Brakeblok Div-- 

American Can Co., Marathon Div 

American Chemical Corp 

American Cyanamid Co 

American I^ewood Co., Inc., New York Color & 

Chemical Co. Div. 
American Home Products Corp., Wyeth Laboratories, 
Inc. Div. 

American Oil Co. (Maryland) 

American Oil Co. (Texas) 

American Petrochemical Corp 

American Potash S; Chemical Corp 

American Synthetic Rubber Corp 

American Tartars Corp 

Ames Laboratories, Inc 

Amoco Chemicals Corp 

Ancon Chemical Co 

Ansbacher-Siegle Corp., Div. of Sun Chemical Corp- 

Ansul Chemical Co 

J^ex Chemical Co., Inc 

Appleton Coated Paper Co 

Applied Plastics Co., Inc 

Arapahoe Chemicals, Inc 

Archer- Daniels-Midland Co 



Office address 



Ardmore Chemical Co 

Argus Chemical Corp 

Arizona Chemical Co 

Arkansas Co., Inc 

Armour Agricultural Chemical Co 

Armour & Co. : 

Armour Industrial Chemical Co. Dlv- 

Kessler Chemical Div 

Armour Pharmaceutical Co 



Uth St. and Sheridan Rd., N. Chicago, 111. 60664. 

UOl Circle Ave., Forest Park, 111. 60130. 

59 Kent St., Brooklyn, N.Y. 11222. 

66 Lister Ave., Newark, N.J. 07105. 

Widener Bldg., 1339 Chestnut St., Philadelphia, Pa. 19107. 



150 E. A-2d St., New York, N.Y. 10017. 

UOO E. Washington Ave., Madison, Wis. 53701. 

P.O. Box 3179, Tuscaloosa, Ala. 35404. 

Phillips Bldg., 16th Fl., Bartlesville, Okla. 74004. 

Trenton Ave. and William St., Philadelphia, Pa. 19134. 

3440 Fairfield Rd., Baltimore, m. 21226. 

2371 N. 30th St., Milwaukee, Wis. 53210. 

33 Avenue P, Newark, N.J. 07105. 

40 Rector St., New York, N.Y. 10006. 

40 Rector St., New York, N.Y. 10006. 

P.O. Box 70, Morristo'.vn, N.J. 07960. 

40 Rector St., New York, N.Y. 10006. 

40 Rector St., New York, N.Y. 10006. 

P.O. Drawer 61, Hopewell, Va. 23860. 

P.O. Box 365, Morristown, N.J. 07960. 

P.O. Box 271, Syracuse, N.Y. 13201. 

P.O. Box 2120, Houston, Tex. 77001. 

3943 Buffalo Ave., Niagara Falls, N.Y. 14302. 

Ontario and Rorer Sts., Philadelphia, Pa. 19134. 

Brookside Ave., Ambler, Pa. 19002; 

Broad and Uth Sts., Carlstadt, N.J. 

Venango and F Sts., Philadelphia, Pa. 

P.O. Box 2086, Paterson, N.J. 07509. 

710 W. National Ave., Milwaukee, Wis. 

900 W. Maple Rd., Troy, Mich. 48012. 

Neenah, Wis. 54957. 

P.O. Box 9247, Long Beach, Calif. 90810. 

Berdan Ave., Wayne, N.J. 07470. 

374 Main St., Belleville, N.J. 07109. 



07072. 
19134. 



53204. 



P.O. Box 8299, Philadelphia, Pa. 19101. 

910 S. Michigan Ave., Chicago, 111. 60680. 

910 S. Michigan Ave., Chicago, 111. 60680. 

3134 California St., N.E., Minneapolis, Minn. 55418. 

3000 W. 6th St., Los Angeles, Calif. 90054. 

P.O. Box 360, Louisville, Ky. 40201. 

420 Lexington Ave., New York, N.Y. 10017. 

200 Rock Lane, Milford, Conn. 06463. 

130 E. Randolph Dr., Chicago, 111. 60601. 

P.O. Drawer 37, Westlake, La. 70669. 

441 Tompkins Ave., Staten Island, N.Y. 10305. 

1 Stanton St., Marinette, Wis. 54143. 

200 S. 1st St., Elizabethport, N.J. 07206. 

825 E. Wisconsin Ave., i^pleton, Wis. 54910. 

130 Penn St. , El Segundo, Calif. 90246. 

2855 Walnut St., Boulder, Colo. 80301. 

733 Marquette Ave., P.O. Box 532, Minneapolis, Minn. 

55440. 
840 Valley Brook Ave., I^mdhurst, N.J. 07071. 
633 Court St., Brooklyn, N.Y. 11231. 
Ill W. 50th St., New York, N.Y. 10020. 
185 Foundry St., P.O. Box 210, Newark, N.J. 07101. 
P.O. Box 1685, Atlanta, Ga. 30301. 

110 H. Waoker Dr., Chicago, 111. 60606. 

State Rd. and Cottman Ave., Philadelphia, Pa. 19135. 

P.O. Box 511, Kankakee, 111. 60901. 



DIRECTORY OF MANUFACTURERS 
TABLE 22.— Synthetic organic chemicals: Directory of manufacturers , i5« —Continued 



215 



Name of company 



Armstrong Cork Co 

Armstrong Paint & Varnish Works, Inc 

Arol Chemical Products Co 

Aishland Oil & Refining Co 

Astra Pharmaceutical Products, Inc 

Atco Chemical- Industrial Products, Inc 

Atlantic Chemical Corp 

Atlantic Refining Co 

Atlantic Tubing & Rubber Co 

Atlas Chemical Industries, Inc., Chemicals Dlv- 

Atlas Processing Co 

Augusta Chemical Co 

Avisun Corp 

Aztec Chemicals, Inc 



Baird Chemical Industries, Inc 

Baker Castor Oil Co 

J. T. Baker Chemical Co 

Taylor Div 

Baldwin-Montrose Chemical Co., Inc., Montrose 
Chemical Div. 

Balfour Chemicals, Inc 

Baltimore Paint & Chemical Corp 

Barlow Chemical Corp 

Bates Chemical Co 

J. H. Baxter & Co 

Baxter Laboratories, Inc 

Bayoil Co., Inc 

Beacon Chemical Industries, Inc 

Beech-Nut Life Savers, Inc 

Belding Chemical Industries 

Belle Chemical Co., Inc 

Bendix Corp., Marshall-Eclipse Div 

Bennett 's- 
Benzol Products Co- 
Berkshire Color & Chemical Co- 
Bernoolors-Poughkeepsle, Ino- 
Bernz-o-Matic, Harris Paint Co. Div- 
Blackman-Uhler Chemical Co- 
Blue Arrow, Inc- 

Borden Co., Borden Chemical Co. Div- 
Borg-Warner Corp., Marbon Chemical Div- 
Walter N. Boysen Co- 
Branchflower Co- 
Brand Plastics Co 

Bristol-Meyers Co., Bristol Laboratories Div— - 

Brooklyn Color Works, Inc 

M. A. Bruder & Sons, Inc 

Bryant Chemical Corp 

Buckeye Cellulose Corp 

Buckman Laboratories, Inc 

Budd Co., Polychem Div 

Burdlck & Jackson Laboratories, Inc 

Burkart-Schier Chemical Co 

Burroughs-Wellcome & Co. (U.S.A.), Inc 



Samuel Cabot, Ino 

Cadet Chemical Corp 

Calcasieu Chemical Corp 

California Chemical Co. : 

Oronite Div 

Ortho Div 

Cal/Ink Co., Inc 

Gallery Chemical Co 

Cap-Roc, Inc., Capital Plastics Div 

Caradco, Inc., Dure 1 Div 

Carborundum Co., Coated Abrasives Div- 
Cargill, Ino 



Carlisle Chemical Works, Inc- 

Advance Div 

I Carpenter-lforton Co 



Office address 



W. Liberty St., Lancaster, Pa. 176CK. 

1330 S. Kilbourn Ave., Chicago, 111. 60623. 

371 Wayne St., Jersey City, N.J. 07302. 

UOl Winchester Ave., Ashland, Ky. 41101. 

7 Neponset St., Worcester, Mass. 01606. 

1259 Route 46, Parsippany, N.J. 07054-. 

P.O. Box 216, Nutley, N.J. 07110. 

260 S. Broad St., Philadelphia, Pa. 19101. 

Mill St., Cranston, R.I. 02905. 

New Mirphy Rd. and Concord Pike, Wilmington, Del. 19899. 

P.O. Box 1786, Shreveport, La. 71102. 

P.O. Box 660, Augusta, Ga. 30903. 

P.O. Box 312, New Castle, Del. 19720. 

P.O. Box 756, Elyria, Ohio 44036. 

185 Madison Ave., New York, N.Y. 10016. 
40 Avenue A, Bayonne, N.J. 07002. 
600 N. Broad St., Phillipsburg, N.J. 08865. 
600 N. Broad St., Phillipsburg, N.J. 08865. 
100 Lister Ave., Newark, N.J. 07105. 

1754 Thome Rd., Tacoma, Wash. 98421. 

2325 Hollins Ferry Rd., Baltimore, Mi. 21230. 

Barlow Lane, Ossining, N.Y. 10562. 

Scottdale Rd. , Lansdowne, Pa. 19050. 

120 Montgomery St., San Francisco, Calif. 94104. 

6301 N. Lincoln Ave., Morton Grove, 111. 60053. 

2 Union St., Peabody, Mass. 01961. 

33 Richdale Ave., Cambridge, Mass. 02140. 

Canajoharle, N.Y. 13317. 

1407 Broadway, New York, N.Y. 10018. 

P.O. Box 848, Lowell, N.C. 28089. 

P.O. Box 238, Troy, N.Y. 12180. 

65 W. 1st S., Salt Lake City, Utah 84110. 

237 South St., Newark, N.J. 07114. 

12th and Bern Sts., Reading, Pa. 19603. 

45 Taylor Ave., Poughkeepsie, N.Y. 12602. 

1026 N. 19th St., Tampa, Fla. 33601. 

P.O. Box 1869, Spartanburg, S.C. 29301. 

P.O. Box B, Jacksonville, Fla. 32203. 

350 Madison Ave., New York, N.Y. 10017. 

P.O. Box 68, Washington, W. Va. 26181. 

1001 42d Sts., Oakland, Calif. 94608. 

4501 Shilshole St. NW. , Seattle, Wash. 98107. 

8400 Willow Springs Rd., Willow Springs, 111. 60480. 

P.O. Box 657, Syracuse, N.Y. 13201. 

681 Morgan Ave., Brooklyn, N.Y. 11222. 

52d St. and Grays Ave., Philadelphia, Pa. 19143. 

6 North St., N. Quincy, Mass. 02171. 

2899 Jackson Ave., Memphis, Tenn. 38108. 

1256 N. McLean Blvd., Memphis, Tenn. 38108. 

70 S. Chapel St., Newark, Del. 19711. 

1953 S. Harvey St., ^4iskegon, MLch. 49442. 

1228 Chestnut St., Chattanooga, Tenn. 37402. 

1 Scarsdale Rd., Tuckahoe, N.Y. 10707. 

246 Summer St., Boston, Mass. 02210. 

2153 Lookport-Oloott Rd., Burt, N.Y. 14028. 

P.O. Box 1522, Lake Charles, La. 70604. 

200 Bush St., San Francisco, Calif. 94120. 

Lucas and Ortho Way, Richmond, Calif. 94800. 

711 Camelia St., Berkeley, Calif. 94710. 

Gallery, Pa. 16024. 

250 Mill St., Rochester, N.Y. 14614. 

1098 Jackson St., Dubuque, Iowa 52001. 

P.O. Box 477, Niagara Falls, N.Y. 14302. 

Room 2008, 3 Penn Center Plaza, Philadelphia, Pa. 19102, 

and Cargill Bldg., Minneapolis, Minn. 55402. 
West St., Reading, Ohio 45215. 
500 Jersey Ave., New Brunswick, N.J. 08903. 
376 3d St., Everett, Mass. 02149. 



216 SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 2Z.—Synthetic organic chemicals: Directory of manufacturers , i 564 —Continued 



Name of company 



CES 
CAT 

CEL 



CBD 
CCL 
CCC 
CHT 
CCI 
CHG 
CTN 

VLY 
CIS 
CPD 

ceo 

CEM 
CKL 
CHL 
CPC 
CHC 
CIB 

CBP 

CBA 

CIN 

CSO 

CLK 

CLY 

CLI 

CLV 

COK 

CBR 

CP 

COL 

CLD 

CBN 

CLE 

CMP 

COM 

DAV 

CON 

CTA 

CPT 

CWP 

CTL 

CO 

CPV 

CFA 

COP 

CPY 

CRN 

CSD 

CWL 

CRT 

ALT 

CBY 
CCP 
CHC 
CRZ 
CUL 

cue 

CUT 

DAN 
PDJ 
DLI 



Carus Chemical Co., Ino 

Catalln Corp. of America 

Celanese Corp. of America: 

Celanese Chemical Co. Div 

Celanese Plastics Co. Div 

Central Processing Co 

Charlotte Chemical Laboratories 

Chase Chemical Corp 

Chattanooga Medicine Co., Chattem Chemicals Div 

Checlsmate Chemicals, Ino 

Chemagro Corp 

Chemetron Corp., Chemetron Chemicals, Organic 
Chemical Dept. 

Chem-Fleur, Inc 

Chemical Insecticide Corp 

Chemical Products Corp 

Chemico, Inc 

Chemirad Corp 

Chemlek Laboratories, Ino 

Chemol, Ino 

Chllds Pulp Colors, Ino 

Chipman Chemical Co., Ino 

Ciba Chemical & Dye Co 

Ciba Corp . : 

Ciba Pharmaceutical Co. Div 

Ciba Products Co 

Cindet Chemicals, Ino 

Cities Service Oil Co 

Clari: Oil & Refining Corp 

W. A. Cleary Corp 

Clintwood Chemical Co 

Clover Chemical Co 

Cockerille Ghemioals, Ino 

Colab Resin Corp 

Colgate-Palmolive Co 

Collier Carbon & Chemical Corp 

Colloids, Ino 

Columbian Carbon Co., Pigments & Elastomers Div 

Columbia Organic Chemicals Co., Ino 

Commercial Products Co., Inc 

Commercial Solvents Corp 

Conchemco, Inc., H. B. Davis Co. Div 

Concord Chemical Co., Ino 

Conestoga Chemical Corp 

Consolidated Paint Co 

Consolidated Papers, Inc 

Continental Chemical Co 

Continental Oil Co 

Cook Paint & Varnish Co 

Cooperative Farm Chemicals Association 

Coopers Creek Chemical Corp 

Copolymer Rubber & Chemical Corp 

Corn Products Co 

Cosden Oil & Chemical Co 

Cowles Chemical Co 

Crest Chemical Corp 

Crompton & Knowles Corp., Althouse Chemical Co. 
Div. 

Crosby Chemicals, Ino 

Croim Central Petroleum Corp 

Crown Chemical Corp 

Crovm Zellerbaoh Corp., Chemical Products Div~ 

Culver Chemical Co 

Cumberland Chemical Corp 

Cutter Laboratories, Ino 



Office address 



Mo. 64120. 



Dan River Mills, Ino 

Joseph Davis Plastics Co- 
Dawe's Laboratories, Inc- 



1375 8th St., LaSalle, 111. 61301. 
1 Park Ave., New York, N.Y. 10016. 

522 5th Ave., New York, N.Y. 10036. 
744 Broad St., Newark, N.J. 07102. 
P.O. Box 270, Springfield, Oreg. 97477. 
P.O. Box 948, Charlotte, N.C. 28201. 
3527 Smallman St., Pittsburgh, Pa. 15201. 
1717 W. 38th St., Chattanooga, Tenn. 37409 
P.O. Box 2164, Greenville, S.C. 29602. 
P.O. Box 4913, Station "F", Kansas City, 
386 Park Ave. S., New York, N.Y. 10016. 

200 Pulaski St., Newark, N.J. 07105. 

30 Whitman Ave., Metuchen, N.J. 08840. 

P.O. Box 815, Cartersvllle, Ga. 30120. 

2508 E. Bailey Rd., Cuyahoga Falls, Ohio 44221. 

P.O. Box 187 (Ryders Lane), E. Brunswick, N.J. 08816. 

4040 W. 123d St., Alsip, 111. 60658. 

P.O. Box 3227, Greensboro, N.C. 27402. 

43 Summit St., Brooklyn, N.Y. 11231. 

1801 Murchlson Dr., Burlingame, Calif. 94011. 

Route 208, Fair Lawn, N.J. 07410. 

556 Morris Ave., Summit, N.J. 07901. 

556 Morris Ave., Summit, N.J. 07901. 

P.O. Box 907, Greensboro, N.C. 27402. 

P.O. Box 300, Tulsa, Okla. 74101. 

131st St. and Kedzie Ave., Blue Island, 111. 60406. 

P.O. Box 749, New Brimswiok, N.J. 08903. 

1 N. LaSalle St., Chicago, 111. 60602. 

360 Regis Ave., Pittsburgh, Pa. 15236. 

Greenwood, Va. 22943. 

Main St., Tewksbury, Mass. 01876. 

300 Park Ave., New York, N.Y. 10022. 

714 W. Olympic Blvd., Los Angeles, Calif. 90015. 

394 Frelinghuysen Ave., Newark, N.J. 07114. 

380 Madison Ave., New York, N.Y. 10017. 

912 Drake St., Columbia, S.C. 29205. 

117 Ethel Ave., Hawthorne, N.J. 07641. 

260 Madison Ave., New York, N.Y. 10016. 

Bayard and Severn Sts., Baltimore, Md. 21230. 

205 S. 2d St., Camden, N.J. 08103. 

Wilmington Industrial Park, Wilmington, Del. 19801. 

3101 E. nth St., Los Angeles, Calif. 90023. 

Wisconsin Rapids, Wis. 54494. 

270 Clifton Blvd., Clifton, N.J. 07015. 

1300 Main, Houston, Tex. 77001. 

P.O. Box 389, N. Kansas City, Mo. 64141. 

P.O. Box 80, Lawrence, Kans. 66044. 

River Rd., W. Conshohocken, Pa. 19428. 

P.O. Box 2591, Baton Rouge, La. 70821. 

717 5th Ave., New York, N.Y. 10022. 

P.O. Box 1311, Big Spring, Tex. 79721. 

12000 Shaker Blvd., Cleveland, Ohio 44120. 

235 Emmet St., Newark, N.J. 07114. 

500 Pear St., Reading, Pa. 19603. 

P.O. Drawer 460, Picayune, Miss. 39466. 

P.O. Box 1168, Baltimore, Md. 21203. 

12 Dudley St., Providence, R.I. 02901. 

Camas, Wash. 98607. 

1502 N. 25th St., Melrose Park, ,111. 60160. 

150 E. 42d St., New York, N.Y. 10017. 

4th and Parker Sts., Berkeley, Calif. 94710. 

Danville, Va. 24540. 

450 Schuyler Ave., Kearny, N.J. 07032. 

4800 S. Richmond St., Chicago, 111. 60632. 



JDC 
DEG 
DCI 
DEP 
DSO 
TTX 
JOD 
DEX 



DIRECTORY OF MANUFACTURERS 
TABLE 22. Synthetic organic chemicals.- Directory of manufacturers , 1 964— Continued 



217 



Name of company 



John Deere Chemloal Co 

Degen Oil & Chemical Co 

Delaware Chemicals, Ino 

DePaul Chemical Co., Inc 

DeSoto Chemical Coatings, Inc 

Detrex Chemical Industries, Inc 

Devoe & Reynolds Co., Inc., Jones-Dabney Div- 

Dexter Chemical Corp 

Diamond Alltali Co 

Western Div 

Diversey Corp 

Dixie Pine Products Co., Inc 

Donald A. Dodd 

Dominion Products, Ino 

Dover Chemical Co 

Dow Badisohe Chemical Co 

Dow Chemical Co 

Dow Corning Corp 

Drew Chemical Corp 

Frank W. Dunne Co 

E. I. duPont de Nemours & Co., Inc 

Duraphene Corp 

Dye Specialties, Inc 



Eagle-Pioher Co., Ohio Ruhber Co. Div 

J. S. & W. R, EaMns, Ino 

Eastern Color & Chemical Co 

Eastman Kodak Co 

Tennessee Eastman Co. Div 

Texas Eastman Co. Div 

Edcan Laboratories 

Thomas A. Edison Industries, MoGraw-Edison Co. 

Medical Gas Div. 

El Paso Natural Gas Products Co 

Emery Industries, Inc 

Western Div 

Emkay Chemical Co 

Endo Laboratories, Inc 

Enjay Chemical Co., Div. of Humble Oil & 

Refining Co. 
Epoxylite Corp 



Escambia Chemical Corp- 
Ethyl Corp 

Ethyl -Dow Chemical Co — 
Evans Chemetics, Inc 



Fabricolor Manufacturing Corp 

Fairmount Chemical Co., Inc 

Farac Oil & Chemical Co 

Far-Best Corp., 0. L. King Div 

Farmers Chemical Association, Inc 

Farmers' Chemical Co 

Farnow, Inc 

Federal Color Laboratories 

Felton Chemical Co., Inc 

Fermoo Laboratories, Inc 

Ferro Corp., Ferro Chemical Div 

Fiberfll, Inc 

Fibreboard Paper Products Corp 

Filtered Rosin Products Co 

Fine Organios, Ino 

Firestone Tire & Rubber Co.: 

Firestone Plastics Co. Div 

Firestone Rubber & Latex Products Co. Div 

Firestone Synthetic Rubber & Latex Co. Div— 

Florasynth Laboratories, Ino 

EMC Corp.: 

American Viscose Div 



Office address 



P.O. Box 1736, Tulsa, Olcla. 74101. 

200 Kellogg St., Jersey City, N.J. 07305. 

726 King St., Wilmington, Del. 19801. 

44-27 Purvis St., Long Island City, N.Y. 11101. 

1700 S. Mt. Prospect Ave., Des Plalnes, 111. 60018. 

P.O. Box 501, Detroit, Mich. 48232. 

1481 S. 11th St., Louisville, Ky. 40208. 

845 Edgewater Rd., Bronx, N.Y. 10474. 

300 Union Commerce Bldg., Cleveland, Ohio 44114. 

300 Union Commerce Bldg., Cleveland, Ohio 44114, 

212 W. Monroe St., Chicago, 111. 60606. 

P.O. Box 470, Hattiesburg, Miss. 39402. 

8002 53d Ave. W., Everett, Wash. 98202. 

882 3d Ave., Brooiayn, N.Y. 11232. 

15th and Davis Sts., Dover, Ohio 44622. 

P.O. Box 875, Freeport, Tex. 77541. 

Main St., Midland, Mich. 48640. 

P.O. Box 592, Midland, Mioh. 48641. 

416 Division St., Boonton, N.J. 07005, 

1007 41st St., Oakland, Calif. 94608. 

1007 Market St., Wilmington, Del. 19898. 

Route 14, Sterling, Conn. 06377. 

26 Journal Sq., Jersey City, N,J. 07306. 

Ben Hur Ave., Willoughby, Ohio 44094, 
55 Berry St., Brooklyn, N.Y. 11211. 
P.O. Box 6161, Providence, R.I. 02904. 
343 State St., Rochester, N.Y. 14650. 
P.O. Box 511, Kingsport, Tenn. 37662. 
P.O. Box 2068, Longview, Tex. 75$03. 
10 Pine St., S. Norwalk, Conn. 06856. 
Stuyvesant Falls, N.Y. 12174. 

P.O. Box 3986, Odessa, Tex. 79760. 

4300 Carew Tower, Cincinnati, Ohio 45202. 

8733 S. Dice Rd., Santa Fe Springs, Calif. 90670. 

319 2d St., Elizabeth, N.J. 07206. 

1000 Stewart Ave., Garden City, N.Y. 11533. 

60 W. 49th St., New York, N.Y. 10020, 

P.O. Box 3397, 1428 N. Tyler Ave., S. El Monte, Calif. 

91733. 
P.O. Box 467, Pensaoola, Fla. 32502. 
100 Park Ave., New York, N.Y. 10017, 
Midland, Mich. 48640. 
250 E. 43d St., New York, N.Y. 10017. 

24-1/2 Van Houten St., Paterson, N,J, 07505. 

117 Blanchard St., Newark, N.J. 07105. 

147th St. and Indiana Ave., Chicago, 111. 60627. 

640 Gilman St., Berkeley, Calif. 94710. 

P.O. Box 67, Tyner, Tenn. 37392. 

P.O. Box 591, Kalamazoo, Mich. 49005. 

77 Jacobus Ave., S. Kearny, N.J. 07032. 

4526 Chickering Ave., Cincinnati, Ohio 45232. 

599 Johnson Ave., Brooklyn, N.Y. 11237. 

4941 S. Racine Ave., Chicago, 111. 60609. 

P.O. Box 349, Bedford, Ohio 44014. 

1701 N. Heidelbaoh ;ive., Evansville, Ind. 47711. 

1550 Powell St., Emeryville, Calif. 94608. 

P.O. Box 349, Baxley, Ga. 31513. 

205 Main St., Lodi, N.J. 07644. 

P.O. Box 699, Pottstown, Pa. 19464. 
1 Firestone Ave,, Fall River, Mass. 02722. 
381 W. Wilbeth Rd., Akron, Ohio 44301. 
900 Van Nest Ave., Bronx, N.Y. 10462. 

1617 John F. Kennedy Blvd., Philadelphia, Pa. 19103. 



218 SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 22. —Synthetic organic chemicals.- Directory of manufacturers , 1964 --Continued 



Name of company 



FMC Corp. — Continued 

Inorganic Chemicals Div 

Niagara Chemical Div 

Organic Chemicals Div 

Foote Mineral Co 

Foremost Chemical Products Co 

Formica Corp 

Foster Grant Co., Inc 

Foster- Heaton Co 

France, Campbell & Darling, Inc 

J. P. Frank Chemical Sc Plastic Corp 

Franklin Chemical Co 

Freeman Chemical Corp 

Frisch & Co., Inc 

Fritzsche Bros., Inc 

H. B. Fuller Co 

W. P. Fuller Paint Co 

Gamma Chemical Corp -- 

Gane's Chemical Works, Inc 

Geigy Chemical Corp 

General Aniline S: Film Corp 

General Electric Co.: 

Chemical Materials Dept 

Insulating Materials Dept 

Silicone Products Dept 

General Foods Corp., Maxwell House Div 

General Latex & Chemical Corp 

General Mills, Inc 

Chemical Div 

General Plastics Manufacturing Co 

General Tire & Rubber Co., Chemical Div 

Geolina Business, Inc 

P. D. George Co 

Georgia-Pacific Corp.: 

Coos Bay Div 

Puget Sound Div 

Gilman Paint & Varnish Co 

Givaudan Corp 

Glasflex, Inc 

Glidden Co 

Glyco Chemicals, Inc 

B. F. Goodrich Co., B. F. Goodrich Chemical Co 
Div. 

Goodrich-Gulf Chemicals, Inc 

Goodyear Tire & Rubber Co 

Gordon Chemical Co., Inc 

W. R. Grace & Co.: 

Dewey & Almy Chemical Div 

Hatco Chemical Div 

Nitrogen Products Div 

Polymer Chemicals Div 

Grain Processing Corp 

Great American Chemical Corp 

Great Lakes Chemical Corp 

Great Western Sugar Co 

Guard Chemical Co., Inc 

Guardsman Chemical Coatings, Inc 

Gulf Oil Corp 

Spencer Chemical Div 

Perkins Glue Branch 

Guth Chemical Co 

H & N Chemical Co 

Haag Laboratories, Inc 

Halby Products Co., Inc 

C. P. Hall Co. of Illinois 

Hamilton Chemical Corp 



Office address 



Sawyer Ave. and River Rd., Tonawanda, N.Y. K207, and 633 

3d Ave., New York, N.Y. 10017. 
100 Niagara St., Middleport, N.Y. UIOS. 
P.O. Box 1616, Baltimore, m. 21203. 
Route 100, Exton, Pa. 1934-1. 
P.O. Box 599, Oakland, Calif. 94604. 
4614 Spring Grove Ave., Cincinnati, Ohio 45232. 
289 N. Main St., Leominster, Mass. 01453. 
16 E. 5th St., Paterson, N.J. 07524. 
N. Michigan Ave., Kenilworth, N.J. 07033. 
5410 Avenue U, Brooklyn, N.Y. 11234. 
2020 Bruck St., Columbus, Ohio 43207. 
222 E. Main St., Port Washington, Wis. 53074. 
88 E. 11th St., Paterson, N.J. 07509. 
76 9th Ave., New York, N.Y. lOOll. 
1150 Eustis St., St. Paul, Minn. 55108. 
450 E. Grand Ave. , S. San Francisco, Calif. 94080. 

355 Lexington Ave., New York, N.Y. 10017. 
535 5th Ave., New York, N.Y. 10017. 
P.O. Box 430, Yonkers, N.Y. 10704. 
P.O. Box 12, Linden, N.J. 07036. 

1 Plastics Ave., Pittsfield, Mass. 01203. 
1 Campbell Rd., Schenectady, N.Y. 12306. 
Waterford, N.Y. 12188. 
1125 Hudson St., Hoboken, N.J. 07030. 
666 Main St., Cambridge, Mass. 02139. 
S. Kensington Rd. , Kankaiee, 111. 60901. 
Quimby St., Ossining, N.Y. 10562. 
3481 S. 35th St., Taooma, Wash. 98409. 
1708 Englewood Ave., Akron, Ohio 44309. 
P.O. Box 1557, Savannah, Ga. 31402. 
5200 N. 2d St., St. Louis, Mo. 63147. 

P.O. Box 869, Coos Bay, Oreg. 97420. 

300 Laurel St., Bellingham, Wash. 98225. 

W. 8th and Pine Sts., Chattanooga, Tenn. 37401. 

109-201 Delawanna Ave., Delawanna, N.J. 07014. 

Stirling, N.J. 07980. 

900 Union Commerce Bldg. , Cleveland, Ohio 44115. 

417 5th Ave., New York, N.Y. 10016. 

3135 Euclid Ave., Cleveland, Ohio 44115. 

1717 E. 9th St., Cleveland, Ohio 44114. 
1144 E. Market St. , Akron, Ohio 44316. 
88 Webster St., Worcester, Mass. 01603. 

62 Whittemore Ave., Cambridge, Mass. 02140. 

King George Post Rd., P.O. Box 27, Fords, N.J. 08863. 

P.O. Box 277, ttJmphis, Tenn. 38101. 

225 Allwood Rd., Clifton, N.J. 07015. 

1600 Oregon St. , Muscatine, Iowa 52761. 

650 Water St., Fitchburg, Mass. 21420. 

2024 Filer City Rd., Filer City, Mich. 49634. 

P.O. Box 5308, Terminal Annex, Denver, Colo. 80217. 

N. Water St., Ossining, N.Y. 10563. 

1350 Steele Ave. SW., Grand Rapids, Mich. 49502. 

P.O. Drawer 2100, Houston, Tex. 77001. 

610 Dwight Bldg., Kansas City, Mo. 64105. 

632 Cannon Ave., Lansdale, Pa. 19446. 

1455 W. Congress Pkwy., Chicago, 111. 60607. 

Maltese Dr., Totowa, N.J. 07512. 
14010 S. Seeley, Blue Island, 111. 60406. 
P.O. Box 366, Wilmington, Del. 19899. 
5245 W. 73d St., Chicago, 111. 60638. 
45 Andrews St., Lowell, Mass. 01853. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. — Synthetic organic chemicals: Directory of manufacturers , 1964 --Continued 



219 



Name of company 



Hampden Color S: Chemical Co 

Hampshire Chemical Corp 

Haima Paint Manufacturing Co., Ino 

Harshaw Chemical Co 

Hartman-Leddon Co 

Hart Products Corp 

Haveg Industries, Inc., Resin & Compound Div 

Hawkeye Chemical Co 

Hercules Powder Co 

Imperial Color & Chemical Dept 

Heresite & Chemical Co 

Hess Oil & Chemical Corp 

Heterochemical Corp 

Hexagon laboratories, Inc 

Hodag Chemical Corp 

Hoechst Chemical Corp 

Hoffmann-LaRoche, Inc 

Hoffman-Taff, Inc 

Holland-Suco Color Co 

Hooker Chemical Corp 

Durez Plastics Div 

E. F. Houghton & Co 

Houston Chemical Corp 

Charles L. Huisking & Co., Inc., Clintbrook 

Chemical Co. Div. 

Humphrey Chemical Co 

Philip A. Hunt Chemical Corp., Wayland Chemical 

Div. 

Husky -Dominion Briquets 

I^son, Westcott & Dunning, Inc 

f^sol Corp 

I.C.I. (Organlcs), Inc 

Imperial Chemical Co., Ino 

Industrial Biooheralcals 

Industrial Dyestuff Co 

Inland Steel Container Co 

Interchemlcal Corp. : 

Color & Chemicals Div 

Finishes Div 

Organic Chemicals Dept 

International Flavors & Fragrances, Inc 

International latex Corp 

International Minerals & Chemical Corp 

International Paper Co 

International Resistance Co 

Inter-Pacific Resins, Inc 

Interplastic Corp., Commercial Resins Div 

Ironsides Resins, Inc 

Isochem Resins Co 

Isooyanate Products, Inc 



Office address 



KAI 

KAl 

KF 

KMP 

KEL 



Jamestown Paint &. Varnish Co 

Jefferson Chemical Co., Ino 

Jefferson Lake Sulphur Co., Chemical Div- 

Jennat Corp 

Jennison-Wright Corp 

Andrew Jergens Co 

Jersey State Chemical Co 

Jewel Paint & Varnish Co 

S. C. Johnson & Son, Inc 

Jones-Blair Paint Co 

W. H. & F. Jordan, Jr. Manufacturing Co., 



Kaiser Aluminum & Chemical Corp- 

Kali Manufacturing Co 

Kay-Fries Chemicals, Ino 

Kelly-Moore Paint Co 

Kelly-Pickering Chemical Corp— - 



5 Albany St., Springfield, Mass. 01101. 

PoissonAve., Nashua, N. H. 03060. 

1313 Windsor Ave., Columbus, Ohio 43211. 

1945 E. 97th St., Cleveland, Ohio 44106. 

60th St. and Woodland Ave., Philadelphia, Pa. 19143. 

1440 Broadway, New York, N.Y. 10018. 

900 Greenbank Rd., Wilmington, Del. 19808. 

P.O. Box 899, Clinton, Iowa 52733. 

Hercules Tower, 910 Market St., Wilmington, Del. 19899. 

P.O. Box 231, Glens Falls, N.Y. 12803. 

822 S. 14th St., Manitowoc, Wis. 54221. 

State St., Perth Amboy, N.J. 08861. 

Ill E. Hawthorne Ave., Valley Stream, N.Y. 11582. 

3536 Peartree Ave., Bronx, N.Y. 10469. 

7247 N. Central Park Ave., Skokie, 111. 60076. 

129 Quidnlck St., W. Warwick, R.I. 02893. 

324 Kingsland Rd., Nutley, N.J. 07110. 

P.O. Box 1246 SSS, Springfield, Mo. 65805. 

471 Howard Ave., Holland, Mich. 49424. 

Buffalo Ave. and 47th St., Niagara Falls, N.Y. 14302. 

Walck Rd., N. Tonawanda, N.Y. 14121. 

303 W. Lehigh Ave., Philadelphia, Pa. 19133. 

200 Madison Ave., New York, N.Y. 10016. 

417 5th Ave., New York, N.Y. 10016. 

Devine St., North Haven, Conn. 06473. 
Industrial Circle, Lincoln, R.I. 02865. 

P.O. Box 380, Cody, Wyo. 82414. 

Charles and Chase Sts., Baltimore, IJH. 21201. 

1100 Seneca Ave., Olean, N.Y. 14761. 

55 Canal St., Providence, R.I. 02901. 

W. 6th and Grass Sts., Shenandoah, Iowa 51601. 

Edison Industrial Center, Edison, N.J. 08817. 

Dexter Rd., E. Providence, R.I. 02914. 

6532 S. Menard Ave., Chicago, 111. 60638. 

150 Wagaraw Rd., Hawthorne, N.J. 07506. 

1255 Broad St., Clifton, N.J. 07015. 

P.O. Box 8, Route 17, Carlstadt, N.J. 07072. 

521 W. 57th St., New York, N.Y. 10019. 

Playtex Park, Dover, Del. 19901. 

5401 Old Orchard Rd., Skokie, 111. 60078. 

220 E. 42d St., New York, N.Y. 10017. 

401 N. Broad St., Philadelphia, Pa. 19108. 

P.O. Box 445, Sweet Home, Oreg. 97386. 

102 W. Fairfield Ave., St. Paul, Minn. 55107. 

270 W. Mound St., Columbus, Ohio 43215. 

Cook St., Unoom, R.I. 02865. 

900 Wilmington Rd., New Castle, Del. 19720. 

108 Main St., Jamestown, Pa. 16134. 

P.O. Box 53300, Houston, Tex. 77052. 

1914 Haden Rd., Houston, Tex. 77015. 

137 W. 168th St., Gardena, Calif. 90247. 

P.O. Box 4187, Station E, Toledo, Ohio 43609. 

2535 Spring Grove Ave., Cincinnati, Ohio 45214. 

59 Lee Ave., Haledon, N.J. 07508. 

345 N. Western Ave., Chicago, 111. 60612. 

1525 Howe St., Racine, Wis. 53403. 

6969 Denton Dr., Dallas, Tex. 75235. 

Barclay Bldg., 1 Belmont Ave., Bala Cynwyd, Pa. 19004. 

P.O. Box 337, Gramercy, La. 70052. 
427 E. Mayer St., Philadelphia, Pa. 19125. 
360 Lexington Ave., New York, N.Y. 10017. 
1015 Commercial St., San Carlos, Calif. 94070. 
956 Bransten Rd., San Carlos, Calif. 94070. 



220 



SYNTHETIC ORGANIC CHEMICALS, 1964 
TABLE 22. — Synthetic organic chemicals.- Directory of manufacturers , 1964— Continued 



Name of compaiiy 



Office address 



Kendall Refining Co 

Kennecott Copper Corp. : 

Chino Mines Div 

Utah Copper Div 

Kenrioh Petrochemicals, Inc 

Ketona Chemical Corp 

Keysor Chemical Co 

Keystone Chemurgio Corp 

Keystone Color Works, Inc 

Kilsdoni Chemical Corp 

Koapp Products, Inc 

Knoedler Chemical Co 

Kohler-McLister Paint Co 

H. Kohnstanm & Co., Ino 

Koppers Co., Inc.: 

Plasties Div 

Tar & Chemical Div 

Koppers Pittsburgh Co 

Kyanize Paints, Ino 

lalsBSide laboratories, Div. of Colgate- 
Palmolive Co. 

Lakeway Chemical Co 

LaMotte Chemical Products Co 

Lancaster Chemical Corp., Gordon Chemicals Co 
Div. 

Lasco Industries, Inc 

Laurel Soap Manufacturing Co 

Lawrence Mills, Inc 

Lawter Chemicals, Inc., Krumbhaar Resin Div — 

Leatex Chemical Co 

Lebanon Chemical Corp 

Leffingwell Chemical Co 

Lehigh Chemical Co 

B. L. Lemke & Co., Inc 

Leonard Refineries, Inc 

Lever Brothers Co 

C. Lever Co., Inc 

Fred'k H. Levey Co., Ino 

Lignin Products Co 

Eli Ully & Co 

Lubrizol Corp 

George Lueders & Co 

M & T Chemicals, Ino 

MaoKenzie Chemical Works, Ino 

Magruder Color Co., Inc 

Maher Color & Chemical Co 

Mallinokrodt Chemical Works 

Marathon Oil Co., Texas Refining Div 

Marblette Corp 

Marco Chemical Corp 

Marden-Wild Corp 

Marlowe-Van Loan Corp 

Martin-Marietta Corp. ; 

Ridgway Color & Chemical Div 

Southern Dyestuff Co. Div 

Max Marx Color & Chemical Co 

Masonite Corp., Alpine Chemical Div 

Massachusetts Plastic Corp 

Mathe Chemical Co 

Maumee Chemical Co 

Otto B. May, Inc 

McCloskey Varnish Co 

Medical Chemicals Corp 

Merck & Co., Inc 

Metalead Products Corp 

Itetal Hydrides, Inc 

Metalsalts Corp 

Metro-Atlantic, Ino 



1177 Kendall Ave., Bradford, Pa. 16701. 

Hurley, N. Mex. 850^3. 

P.O. Box 1650, Salt Lake City, Utah 84110. 

Foot of E. 22d St., Bayonne, N.J. 07002. 

P.O. Box 6565, Tarrant Branch, Birmingham, Ala. 35217. 

26000 Bouquet Canyon Rd., Saugus, Calif. 91350. 

R.D. #2, Bethlehem, Pa. 18017. 

151 W. Gay Ave., York, Pa. 17403. 

c/o Pfister Chemical Works, Ridgefield, N.J. 07657. 

180 Hamilton Ave., Lodi, N.J. 07644. 

651 High St., Lancaster, Pa. 17604. 

P.O. Box 546, Denver, Colo. 80201. 

161 Avenue of the Americas, New York, N.Y. 10013. 

Koppers Bldg., Pittsburgh, Pa. 15219. 
Koppers Bldg., Pittsburgh, Pa. 15219. 
Koppers Bldg., Pittsburgh, Pa. 15219. 
2d and Boston Sts., Everett, Mass. 02149. 

1707 E. North Ave., Milwaukee, Wis. 53201. 

5025 Evanston Ave., Muskegon, Mich. 49443. 

Chestertown, Md. 21620. 

Broad and 13th Sts., Carlstadt, N.J. 07071. 

1561 Chapin Rd., Montebello, Calif. 90640. 

Thompson and Tioga Sts., Philadelphia, Pa. 19134. 

19 S. Canal St., Lawrence, Mass. 01843. 

3550 Touhy Ave., Chicago, 111. 60645. 

2722 N. Hancock St., Philadelphia, Pa. 19133. 

P.O. Box 693, Lebanon, Pa. 17042. 

P.O. Box 1187, Perry Annex, Whittier, Calif. 90604. 

P.O. Box 120, Chestertown, Md. 21620. 

199 Main St., Lodi, N.J. 07644. 

E. Superior St., Alma, Mich. 48801. 

390 Park Ave., New York, N.Y. 10022. 

Howard and Huntington Sts., Philadelphia, Pa. 19133. 

380 Madison Ave., New York, N.Y. 10017. 

P.O. Box 960, Erie, Pa. 16512. 

740 S. Alabama St., Indianapolis, Ind. 46206. 

29400 Lakeland Blvd., Wiokliffe, Ohio 44-092. 

427 Washington St., New York, N.Y. 10013. 

Woodbridge Rd. and Randolph Ave., Rahway, N.J. 07065. 

1 Cordello Ave., Central Islip, L. I., N.Y. 11722. 

2385 Richmond Terrace, Staten Island, N.Y. 10302. 

1700 N. Elston Ave., Chicago, 111. 60622. 

P.O. Box 5439, St. Louis, Mb. 63160. 

P.O. Box 1191, Texas City, Tex. 77591. 

37-31 30th St., Long Island City, N.Y. 11101. 

1711 W. Elizabeth Ave., Linden, N.J. 07036. 

500 Columbia St., Somerville, Mass. 02143. 

1508 Joshua Circle, High Point, N.C. 27261. 

75 Front St., Ridgway, Pa. 15853. 

P.O. Box 10098, Charlotte, N.C. 28201. 

192 Coit St., Irvington, N.J. 07111. 

P.O. Box 2392, Gulf port. Miss. 39503. 

West Ave., Ludlow, Mass. 01056. 

169 Milbank St., Lodi, N.J. 07644. 

1310 Expressway Dr., Toledo, Ohio 43608. 

52 Amsterdam St., Newark, N.J. 07105. 

7600 State Rd., Philadelphia, Pa. 19136. 

4122 W. Grand Ave., Chicago, 111. 60639. 

126 E. Lincoln Ave., Rahway, N.J. 07065. 

P.O. Box 11005, 2901 Park Blvd., Palo Alto, Calif. 94 

12-24 Congress St., Beverly, Mass. 01915. 

200 Wagaraw Rd., Hawthorne, N.J. 07507. 
2072 Smith St., Centerdale, R.I. 02911. 



DIRECTORY OF MANUFACTURERS 221 

TABLE 22. -Synthetic organic chemicals: Directory of manufacturers , i564— Continued 



Name of company 



J. Meyer & Sons, Inc 

Michigan Chemical Corp 

Midland Industrial Finishes Co 

Midwest Plastic Products Co 

Miles Laboratories, Inc., Miles Chemical Co. Div 
Millmaster Onyx Corp. : 

Berkeley Chemical Dept 

Onyx Chemical Co. Div 

Mineral Oil Refining Co 

Minnesota Mining & Manufacturing Co 

Minnesota Paints, Ino 

Miranol Chemical Co., Inc 

Mississippi Chemical Corp 

Mobay Chemical Co 

Mobil Finishes Co., Inc.: 

Aneri can- Marietta Paint Div 

Arco Div 

Ferbert-Schorndorfer Div 

Molded Fiber Glass Body Co. , Resin Div 

Mona Industries, Inc 

Monochem, Inc 

Monsanto Co. : 

Chemstrand Co. Div 

Chocolate Bayou Plant 

Gering Plastics Dept 

Organic Chemical Div 

Plastics Div 



Western Div 

Montrose Chemical Corp. of California 

Mooney Chemical Corp 

Benjamin Moore & Co 

Morningstar Paisley, Inc 

Morton Salt Co., Morton Chemical Co. Div- 
Motomoo, Inc 



Nalco Chemical Co 

Freeport Div 

Visco Div 

National Biochemical Co 

National Casein Co 

National Dairy Products Corp. : 

Humio Products Chemical Div 

Sheffield Chemical Co. Div 

National Distillers & Chemical Corp. : 

A-B Chemical Corp. Div 

National Petro Chemical Corp. Div 

U.S. Industrial Chemicals Co. Div 

National Lead Co 

National Plastic Products Co., Ino 

National Polychemicals, Inc 

National Starch & Chemical Corp 

National Vulcanized Fibre Co 

Naugatuck Chemical Div. of U.S. Rubber Co- 

Nease Chemical Co., Inc 

Nepera Chemical Co., Inc 

Neville Chemical Co 

Chlorinated Products Div 

Nilok Chemicals, Inc 

Nitrin, Inc 

Nixon-Baldwin Chemicals, Inc 

A. P. Nonweiler Co 

Nopco Chemical Co., Ino 

Norac Co., Ino 

Norda Essential Oil & Chemical Co. , Inc--- 

Norris Paint & Varnish Co 

Norse Chemical Corp 

Northwestern Chemical Co 



Office address 



-1321 N. ith St., Philadelphia, Pa. 19140. 

500 N. Bankson St., St. Louis, Mich. 48880. 

P.O. Box 620, E. Water St., Waukegan, 111. 60086. 

3251 Chicago Rd., Steger, 111. 64075. 

1127 Myrtle St., Elkhart, Ind. 46514. 

99 Park Ave., New York, N.Y. 10016. 

190 Warren St., Jersey City, N.J. 07302. 

4401 Park Ave., Dickinson, Tex. 77539. 

2501 Hudson Rd., St. Paul, Minn. 55119. 

1101 S. 3d St., Minneapolis, Minn. 55415. 

277 Coit St., Irvington, N.J. 07111. 

P.O. Box 388, Yazoo City, Miss. 39194. 

Penn Lincoln Parkway, W. Pittsburgh, Pa. 15205. 

1630 West Hill St., Louisville, Ky. 40210. 
7301 Bessemer Ave., Cleveland, Ohio 44127. 
12815 Elrawood Ave., Cleveland, Ohio 44111. 
4501 Benefit Ave., Ashtabula, Ohio 44004. 
65 E. 23d St., Paterson, N.J. 07524. 
P.O. Box 488, Geismar, La. 70734. 

350 5th Ave., New York, N.Y. 10001. 

P.O. Box 711, Alvin, Tex. 77511. 

N. 7th St. and Monroe Ave., Kenilworth, N.J. 07033. 

800 N. Lindbergh Blvd., St. Louis, Mo. 63166. 

812 Monsanto Ave., Springfield, Mass. 01102; P.O. Box- 1311, 

Texas City, Tex. 77591; and River Ed., Addyston, Ohio 

45001. 
9229 E. Marginal Way S. , Seattle, Wash. 98108. 
500 S. Virgil Ave., Los Angeles, Calif. 90005. 
2303 Scranton Rd., Cleveland, Ohio 44113. 
548 5th Ave., New York, N.Y. 10036. 
1770 Canalport Ave., Chicago, 111. 60616. 

110 N. Waoker Dr., Chicago, 111. 60606. 
89 Terminal Ave., Clark, N.J. 07066. 

6216 W. 66th Place, Chicago, 111. 60638. 
6216 W. 66th Place, Chicago, 111. 60638. 
P.O. Box 87, Sugar Land, Tex. 77478. 
3127 W. Lake St., Chicago, 111. 60612. 
601 W. 80th St., Chicago, 111. 60620. 

P.O. Box 398, Hfemphis, Tenn. 38101. 
P.O. Box 630, Norwich, N.Y. 13815. 

99 Park Ave., New York, N.Y. 10016. 

99 Park Ave., New York, N.Y. 10016. 

99 Park Ave., New York, N.Y. 10016. 

111 Broadway, New York, N.Y. 10006. 
Odenton, Vd. 21113. 

51 Eames St., Wilmington, Mass. 01887. 

750 3d Ave., New York, N.Y. 10017. 

Maryland Ave. and Beech St., Wilmington, Del. 19899. 

Naugatuck, Conn. 06771. 

P.O. Box 221, State College, Pa. 16801. 

Route 17 and Averill Ave., Harriman, N.Y. 10926. 

Neville Island P.O., Pittsburgh, Pa. 15225. 

Neville Island P.O., Pittsburgh, Pa. 15225. 

Mill St. and N. Transit, Lookport, N.Y. 14094. 

P.O. Box 233, Cordova, 111. 61242. 

Nixon, N.J. 08818. 

P.O. Box 1007, Oshkosh, Wis. 54902. 

60 Park PI., Newark, N.J. 07101. 

405 S. Motor Ave., Azusa, Calif. 91703. 

475 10th Ave., New York, N.Y. 10001. 

1710 Front St. NE. , Salem, Oreg. 97303. 

2121 Norse Ave., Cudahy, Wis. 53110. 

120 N. Aurora St., W. Chicago, 111. 60185. 



222 SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 22.— Synthetic organic chemicals: Directory of manufacturers , i564— Continued 



NPC 
NOR 
NOW 
NVT 



CMC 
CMS 
OXR 
OPC 
OEG 
OSB 

cyiA 

OTC 
OCF 
0X0 
OXY 

PLB 

iiMR 

PAM 

PNT 

PD 

PAT 

CCH 

PEK 

PCH 

PEL 

PEN 

PRP 

PAS 

PAI 

PAR 

PER 

PET 

PTT 

PEN 

IOC 

PCW 

PFZ 

PHR 

PFP 

PLC 
PNX 
PIC 
PBY 
PIL 
PCI 
PPL 
PIT 
PCC 
PPG 
PIS 
PMC 

aiA 

PLU 
PFW 
PYL 
POL 
PI I 
PYR 
PYZ 
PVI 
GRS 
PRT 
PMP 
PG 



Name of company 



Northwest Petrochemical Corp- 

Norwich Pharmacal Co 

Nostrip Chemical Works, Inc-- 

Novamont Corp 

Nyanza, Inc 



Old Hickory Chemical Co- 



Office address 



Olin Mathieson Chemical Corp- 

E. R. Squibb & Sons Div 

Onyx Oils & Resins, Ino 

Orbis Products Corp 

Organics, Inc 

C. J. Osbom Co 

Ottawa Chemical Co 

Ott Chemical Co 

Owens-Corning Fiberglas Corp- 

Oxo Chemicals Co 

Oxy Chemical Co 



Div- 



P-L Biochemicals, Inc 

Pacific Resins & Chemical Co 

Pan American Petroleum Corp 

Pantasote Co 

Parke, Davis & Co 

Patent Chemicals, Inc 

Pearsall Chemical Co 

Peck's Products Co 

Peerless Chemical Co 

Pelron Corp 

S. B. Peniok & Co 

Parsons-Plymouth Div 

Pennsalt Chemicals Corp 

Pennsylvania Industrial Chemical Corp 

Pennsylvania Refining Co 

Perry & Derrick Co 

Petroleum Chemicals, Ino 

Petro-Tex Chemical Corp 

Pfanstiehl Laboratories, Ino 

Pfaudler Permutit, Inc., lonao Chemical Co, 

Pfister Chemical Works 

Chas. Pfizer & Co., Inc 

Pharmachem Corp 

Phelan-Faust Paint Manufacturing Co 

Phelan's Resins & Plastics Div 

Phillips Petroleum Co 

Phoenix Oil Co 

Pierce Chemical Co 

Pillsbury Co., Chemical Div 

Pilot Chemical Co 

Pioneer Chemical Works, Ino 

Pioneer Plastics Corp 

Pitt-Consol Chemical Co 

Pittsburgh Chemical Co., Div. of U.S. Steel Co-' 

Pittsburgh Plate Glass Co 

Plastics Engineering Co ^^ 

Plastics Manufacturing Co 

Plastics Materials, Inc 

Plumb Chemical Corp 

Polak's Frutal Works 

Polychemioal Laboratories, Ino 

Polymer Corp 

Polymer Industries, Inc 

Poly Resins 

Polyrez Co., Inc 

Polyvinyl Chemicals, Inc 

Pontiao Refining Corp 

Pratt & Lambert, Ino 

Premier Malt Products, Inc 

Procter & Gamble Co., Procter & Gamble Manu- 
facturing Co. Div. 



P.O. Box 99, Anaoortes, Wash. 98221. 
17 Eaton Ave., Norwich, N.Y. 13815. 
182 Liberty Ave., Jamaica, N.Y. 11412. 
P.O. Box 189, Kenova, W. Va. 25530. 
Magunco Rd., Ashland, Mass. 01721. 

c/o Stauffer Chemical Co., 380 Madison Ave., 

New York, N.Y. 10017. 
AA5 W. 59th St., New York, N.Y. 10019. 
460 Park Ave., New York, N.Y. 10022. 
95 Broad St., New York, N.Y. 10004. 
475 10th Ave., New York, N.Y. 10018. 
1724 Greenleaf Ave., Chicago, 111. 60628. 
1301 W. Blancke St., Linden, N.J. 07036. 
700 N. Wheeling St., Toledo, Ohio 43605. 
500 Agard Rd., Muskegon, Mich. 49945. 
National Bank Bldg., Toledo, Ohio 43614. 
130 E. Randolph Dr., Chicago, 111. 60601. 
P.O. Box 28, Hackettstown, N.J. 07840. 

1037 W. McKinley Ave., Milwaukee, Wis. 53205. 

3400 13th Ave. SW. , Seattle, Wash. 98134. 

P.O. Box 591, Tulsa, Okla. 74102. 

26 Jefferson St., Passaic, N.J. 07056. 

Foot of Jos. Campau, Detroit, Mich. 48232. 

335 McLean Blvd., Paterson, N.J. 07504. 

P.O. Box 108, Phillipsburg, N.J. 08865. 

P.O. Box 14508, St. Louis, Mo. 63178. 

3850 Oatanan Blvd., Detroit, Mich. 48204. 

7847 W. 47th St., ^yons, 111. 60534. 

100 Church St., New York, N.Y. 10008. 

100 Church St., New York, N.Y. 10008. 

3 Penn Center, Philadelphia, Pa. 19102. 

120 State St., P.O. Box 240, Clairton, Pa. 15025. 

Union Bank Bldg., Butler, Pa. 16001. 

2510 Highland Ave., Norwood, Ohio 45212. 

P.O. Box 1522, Lake Charles, La. 70604. 

P.O. Box 2584, Houston, Tex. 77001. 

1219 Glen Rook Ave., Waukegan, 111. 60086. 

Birmingham, N.J. 08011. 

Linden Ave., Ridgefield, N.J. 07657. 

235 E. 42d St., New York, N.Y. 10017. 

Broad and Wood Sts., Bethlehem, Pa. 18015. 

932 Loughborough Ave., St. Louis, Mo. 63111. 

Oak St. and Buff Rd., Burlington, Iowa 52602. 

Bartlesville, Okla. 74004. 

9505 Cassius Ave., Cleveland, Ohio 44105. 

P.O. Box 117, Rockford, 111. 61105. 

1152 Pillsbury St., Minneapolis, Minn. 55402. 

11756 Burke St., Santa Fe Springs, Calif. 90670. 

940 N. Delaware Ave., Philadelphia, Pa. 19123. 

Pioneer Ave . , Sanf ord , Maine 04073 . 

191 Doremus Ave., Newark, N.J. 07105. 

Grant Bldg., Pittsburgh, Pa. 15219. 

1 Gateway Center, Pittsburgh, Pa. 15222. 

1607 Geele Ave., Sheboygan, Wis. 53082. 

2700 S. Westmoreland, Dallas, Tex. 75224. 

New South Rd., Hicksville, N.Y. 11801. 

4837 James St., Philadelphia, Pa. 19137. 

33 Sprague Ave., Middletown, N.Y. 10941. 

490 Hunts Point Ave., New York, N.Y. 10059. 

2120 Fairmont Ave., Reading, Pa. 19603. 

Viaduct Rd., Springdale, Conn. 06879. 

11655 Wicks St., Sun Valley, Calif. 91352. 

P.O. Box 320, Woodbury, N.J. 08096. 

26 Howley St., Peabody, Mass. 01961. 

P.O. Box 1581, Corpus Christi, Tex. 78403. 

75 Tonawanda St., Buffalo, N.Y. 14207. 

917 W. Juneau Ave., Milwaukee, Wis. 53201. 

Ivorydale Technical Center, Cincinnati, Qhio 45217. 



PRD 
PRC 
PUB 
PRO 
PKX 



RSA 
ELS 

RAB 
RET 
RED 
RPC 
REH 

RCI 
VAE 
RIL 
REL 

REM 

RTF 

RCC 

CFC 

EEZ 

RDA 

RCD 

PIA 

RIC 

RTX 

RIK 

RMC 

RT 

RTC 

RIV 

RBC 

ROC 

ORT 

RGC 



RSB 
RPI 
ROY 
RZL 
RUB 
RUR 



SAL 
S 

SAR 
SCF 
SON 
SBC 
SCR 
SCH 
SCO 
SBR 
SEA 
SRL 
SED 



DIRECTORY OF MANUFACTURERS 
TABLE 22. —Synthetic organic chemicals: Directory of manufacturers , 1964— Continued 



223 



Name of company 



Proctor Chemical Co., Inc- 

Productol Chemical Co 

Products Research Co 

Publicker Industries, Inc- 

Pure Oil Co 

Purex Corp., Ltd 



Quaker Chemical Corp 

Quaker Oats Co 

K. J. Quinn & Co., Inc- 



R. S. A. Corp 

Rachel Laboratorles- 



Rayhestos-Manhattan, Inc., Raybestos Div 

Rayette, Inc 

Red Spot Paint & Varnish Co., Inc 

Refined Products Co 

Rehels Chemical Co., Dlv. of Armour Pharma- 
ceutical Co. 

Relchhold Chemicals, Inc 

Varcum Chemical Dlv 

Rellly Tar & Chemical Corp 

Reliance Universal, Inc 



Remington Arms Co., Inc 

Retzloff Chemical Co 

Rexall Chemical Co 

Rexall Chemical Co. - Kearny 

Rezolin, Inc 

Rhodia, Inc 

Richardson Co 

Richardson Polymers Div 

Richfield Oil Corp 

Riegel Textile Corp 

Hiker Laboratories, Inc 

Rinshed-Mason Co 

F. Ritter & Co 

Ritter Chemical Co., Inc 

Rlverdale Chemical Co 

Roberts Chemicals, Inc 

Rock Hill Printing & Finishing Co- 

Roehr Chemicals, Inc 

Rogers Corp 

Rohm & Haas Co 

Roma Chemical Corp 

Rosenberg Bros. & Co 

Rowland Products, Inc 

Royce Chemical Co 

Rozilda Laboratories, Inc 

Rubber Corp. of America 

Ruberoid Co 



St. Regis Paper Co 

Chemical Dlv. 
Dr. Salsbury's Laboratories— 
Sandoz, Inc 

Dyestuff Div., Pigment Dept 

Sartomer Resins, Inc 

Schaefer Vamlsh Co., Inc 

Schenectady Chemicals, Inc 

ScherBros., Inc 

R. P. Scherer Corp 

Schering Corp 

Scholler Bros., Inc 

Schwarz BioResearch, Inc 

Seaboard Chemicals, Inc 

G. D. Searle & Co 

Seidlitz Paint & Vamish Co — 



Lake States Yeast & 



Office address 



P.O. Box 399, Salisbury, N.C. 28144.. 
615 S. Flower St., Los Angeles, Calif. 90017. 
2919 Empire Ave., Burbank, Calif. 91504. 
1429 Walnut St., Philadelphia, Pa. 19102. 
20C E. Gulf Rd., Palatine, 111. 60067. 
5101 Clark Ave., Lakewood, Calif. 90712. 

Elm, Lime, and Sandy Sts . , Conshohocken, Pa. 19428. 
Merchandise Mart Plaza, Chicago, 111. 60654. 
195 Canal St., Maiden, Mass. 02148. 

690 Saw Mill River Rd., Ardsley, N.Y. 10502. 

P.O. Box 9095, 700 Henry Ford Ave., Long Beach, Calif. 

90810. 
75 E. Main St., Stratford, Conn. 06601. 
261 E. 5th St., St. Paul, Minn. 55101. 
110 Main St., Evansville, Ind. 47711. 
624 Schuyler Ave., Lyndhurst, N.J. 07071. 
325 Snyder Ave., Berkeley Heights, N.J. 07922. 

525 N. Broadway, White Plains, N.Y. 10602. 

Niagara Falls, N.Y. 14302. 

1615 Merchants Bank Bldg., Indianapolis, Ind. 46204. 

4730 Crittenden Dr., Louisville, Ky. 40221, and P.O. E 

1113, Houston, Tex. 77001. 
939 Bamum Ave., Bridgeport, Conn. 06602. 
P.O. Box 45296, Houston, Tex. 77045. 
8480 Beverly Blvd., Los Angeles, Calif. 90054. 
1106 Harrison Ave., Kearny, N.J. 07029. 
1651 18th St., Santa Monica, Calif. 90404. 
60 E. 56th St., New York, N.Y. 08901. 
27th Ave. and Lake St., Melrose Park, 111. 60160. 
345 Morgan Lane, West Haven, Conn. 06516. 
555 S. Flower St., Los Angeles, Calif. 90054. 
260 Madison Ave., New York, N.Y. 10016. 
19901 Nordhoff St., Northridge, Calif. 91326. 
5935 Milford Ave., Detroit, Mich. 48210. 
4001 Goodwin Ave., Los Angeles, Calif. 90039. 
403 W. Main St., Amsterdam, N.Y. 12011. 
220 E. 17th St., Chicago Heights, 111. 60411. 
P.O. Box 546, Nltro, W. Va. 25143. 
Rock Hill, S.C. 29731. 

52-20 37th St., Long Island City, N.Y. 11101. 
Main St., Rogers, Conn. 06263. 
222 W. Washington Sq., Philadelphia, Pa. 19105. 
900 Passaic Ave., E. Newark, N.J. 07029. 
100 Landing Ave., Smithtown, N.Y. 11787. 
Fairview Lane, Kensington, Conn. 06037. 
Carlton Hill P.O., E. Rutherford, N.J. 07073. 
814 Madison St., Hoboken, N.J. 07030. 
New South Rd., Hicksville, N.Y. 11802. 
S. Bound Brook, N.J. 08880. 

603 W. Davenport St., Rhlnelander, Wis. 54501. 

500 Gilbert St., Charles City, Iowa 50616. 

P.O. Box 357, Fair Lawn, N.J. 07410. 

61-63 Van Dam St., New York, N.Y. 10013. 

P.O. Box 56, Essington, Pa. 19029. 

15th and Magnolia Sts., Louisville, Ky. 40210. 

Congress St. and 10th Ave., Schenectady, N.Y. 12301. 

P.O. Box 538, Allwood Station, Clifton, N.J. 0701?^. 

9425 Grinnell Ave., Detroit, Mich. 48213. 

1011 Morris Ave., Union, N.J. 07083. 

Collins and Westmoreland Sts., Philadelphia, Pa. 1913 

Mountain View Ave., Orangeburg, N.Y. 10962. 

30 Foster St., Salem, Mass. 01971. 

P.O. Box 5110, Chicago, 111. 60680. 

18th and Garfield Sts., Kansas City, Mo. 64141. 



224 SYNTHETIC ORGANIC CHEMICALS. 1964 

TABLE 22. — Synthetic organic chemicals: Directory of manufacturers , i 964- -Continued 



Name of company 



Office address 



Seklsui Plastics Corp 

SeLney Co., Inc 

Seydel-Woolley & Co., Inc 

Shamrock Oil & Gas Corp 

Shanco Plastics & Chemicals, Inc 

Shawinigan Resins Corp 

Shell Oil Co 

Shell Chemical Co. Div 

Shepherd Chemical Co 

Sherwin-Williams Co 

Shulton, Inc., Fine Chemicals Div 

George F. Siddall Co., Inc 

Signal Oil & Gas Co., Houston Div 

Silmar Chemical Corp 

Simpson Timber Co 

Sinclair Koppers Chemical Co 

Sinclair Paint Co 

Sinclair Petrochemicals, Inc 

Sinclair Refining Co 

James B. Sipe & Co 

Skelly Oil Co 

G. Frederick Smith Chemical Co 

Smith, Kline & French Laboratories 

Socony Mobil Oil Co., Inc. : 

Mobil Chemical Co. Div 

Mobil Oil Co. EtLv 

Virginia- Carolina Chemical Co. Div 

Socony Paint Products Co 

Sohio Chemical Co., Agent: 

SoMo Petroleum Co 

Solar Nitrogen Chemicals, Inc 

Solar Chemical Corp 

Soluol Chemical Co., Inc 

Solvent Chemical Co., Inc 

Sonoco Products Co 

Souhegan Wood Products, Inc 

Sou- Tex Chemical Co., Inc 

Southeastern Adhesives Co 

Southeast Polymers, Inc 

Southern Nitrogen Co., Inc 

Southern Sizing Co 

Spaulding Fibre Co., Inc 

A. E. Staley Ifenufacturing Co 

UBS Chemical Co. Div 

Stamford Chemical Co 

Standard Brands , Inc . , Clinton Com Processing 
Co. Div. 

Standard Chemical Products, Inc 

Standard Chlorine Chemical Co., Inc 

Standard Eyestuff Corp 

Standard Oil Co. of California, California 
Chemical Co. Div. 

Standard Oil Co. of Ohio 

Standard Pyroxoloid Corp 

Stange Co 

Stauffer Chemical Co. ; 

Anderson Chemical Co. Div 

Calhio Chemicals Div 

Industrial Chemical Div 

Victor Chemical Works Div 

Stein, Hall & Co., Inc 

Stepan Chemical Co 

Maywood Div 

Sterling Drug, Inc.: 

Glenbrook Laboratories Div 

Hilton-Davis Chemical Co. Div 

Salvo Chemical Div 

Thomasset Colors Div 

Winthrop Laboratories Div 



666 Dietrich Ave., Hazelton, Pa. 18201. 

65 9th St. Bldg. 15, Brooklyn, N.X. 11215. 

748 Rice St. NW. , Atlanta, Ga. 30318. 

P.O. Box 631, Amarillo, Tex. 79105. 

2716 Kenmore Ave., Tonawanda, N.Y. 1<H50. 

6M- Monsanto Ave., Springfield. Mass. 01101. 

50 W. 50th St., New York, N.Y. 10020. 

110 W. 51st St., New York, N.Y. 10020. 

2803 Highland Ave., Cincinnati, Ohio ■i5212. 

101 Prospect Ave. NW. , Cleveland, Ohio 44101. 

697 Route 46, Clifton, N.J. 07015. 

P.O. Box 925, Spartanburg, S.C. 29301. 

P.O. Box 5008, Harrisburg Station, Houston, Tex. 77012. 

12335 S. Van Ness Ave., Hawthorne, Calif. 90250. 

2301 N. Columbia Blvd., Portland, Oreg. 97217. 

P.O. Box 5536, Houston, Tex. 77012. 

3960 E. Washington Blvd., Los Angeles, Calif. 90023. 

600 5th Ave., New York, N.Y. 10020. 

600 5th Ave., New York, N.Y. 10020. 

P.O. Box 8010, Pittsburgh, Pa. 15216. 

P.O. Box 1650, Tulsa, Okla. 74102. 

867 McKinley Ave., Columbus, Ohio 43223. 

1500 Spring Garden St., Philadelphia, Pa. 19101. 



150 E. 42d St., New York, N.Y. 
612 S. Flower St., Los Angeles. 
P.O. Box 3311, Beaumont, Tex. 
401 E. Main St., Richmond, Va. 
Ifetuchen, N.J. 08840. 



10017. 

Calif. 90054, and 

77704. 
23208. 



621 Republic Bldg., Cleveland, Ohio 44115. 

621 Republic Bldg., Cleveland, Ohio 44115. 

36 Ifonument Sq., Leominster, Mass. 01453. 

Green Hill and Market Sts., W. Warwick, R.I. 02893. 

341 Commercial St., Maiden, Ifess. 02148. 
Hartsville, S.C. 29550. 

Wilton, N.H. 03086. 

E. Catawba Ave., Atount Holly, N. C. 28120. 

P.O. Box 791, Lenoir, N. C. 28645. 

P.O. Box 309, Chattanooga, Tenn. 37401. 

P.O. Box 246, Savannah, Ga. 31402. 

P.O. Box 391, East Point, Ga. 30044. 

310 Wheeler St., Tonawanda, N.Y. 14152. 

N. 22d and Eldorado Sts., Decatur, 111. 62525. 

491 Main St., Cambridge, Mass. 02142. 

45 Jefferson St., P.O. Box 1131, Stamford, Conn. 06940 

Clinton, Iowa 52733. 

1301 Jefferson St., Hoboken, N.J. 07030. 
1015 Belleville Turnpike, Kearny, N.J. 07032. 
19 E. 5th St., Paterson, N.J. 07524. 
200 Bush St., San Francisco, Calif. 94120. 

Midland Bldg., Cleveland, OMo 44115. 

85 Pleasant St., Leominster, Mass. 01453. 

342 N. Western Ave., Chicago, 111. 60612. 

380 Madison Ave., New York, N.Y. 10017. 
380 Madison Ave., New York, N.Y. 10017. 
380 fedison Ave., New York, N.Y. 10017. 
380 Madison Ave., New York, N.Y. 10017. 
605 3d Ave., New York, N.Y. 10016. 
R.R. No. 1, Elwood, 111. 60421. 
100 W. Hunter Ave., Maywood, N.J. 07607. 

90 Park Ave., New York, N.Y. 10016. 

2235 Langdon Farm fid., Cincinnati, Ohio 45237. 

Military Rd., Rothschild, Wis. 54474. 

120 Lister Ave., Newark, N.J. 07105. 

90 Park Ave., New York, N.Y. 10016. 



SRR 
SUG 
SVC 
SUM 
SNW 
SKG 
SUN 
SNO 
DXS 
SNT 
SWT 
SWR 
SYR 
SYC 
SYP 
SYN 
SYV 

TCC 

CST 

TAY 

TNC 

HN 

HNW 

HNX 

CRY 

TOC 

TEN 

TX 

TSA 

TUS 

TXC 

TCI 

TXT 

TKL 

SOR 

THC 

TMH 

TIC 

TID 

TRC 

TNI 

TV 

TRN 

ACT 

TGL 

TRJ 

TRO 

TCH 

JTC 

UHL 
UNG 
NCI 

UCC 
UCP 
UCS 
UOC 
UNS 
URC 
UNN 
UNP 
UNO 
UNO 
USB 
USO 



DIRECTORY OF MANUFACTURERS 
TABLE 22. —Synthetic organic chemicals : Directory of manufacturers , 1964— Continued 



225 



Name of company 



Fred'k A. Stresen-Reuter, Ino 

Sucro-Chenloal Div. of Colonial Sugars Co 

Sullivan Varnish Co 

Summit Chemical Products Corp 

Sun Chemical Corp., Warwick Chemical Co. Div- 

Surikist Growers, Inc 

Sun Oil Co 

SunOlin Chemical Co 

Sunray DX Oil Co 

Suntide Refining Co 

Swift & Co 

Switzer Bros., Ino 

Synco Resins, Inc 

Synthetic Chemicals, Inc 

Synthetic Products Co 

Synthron, Inc 

Synvar Corp 



Office address 



Tanatex Chemical Corp 

Charles S. Tanner Co 

Taylor Corp 

Tennant Development Corp., Chemical Div 

Tenneco Chemicals, Inc 

Newport Div 

Nuodex Div 

Tenneco Manufacturing Co., Tenneco Plastics Dlv- 

Tenneoo Oil Co 

Tennessee Copper Co 

Texaco, Inc 

Texas Alkyls, Inc 

Texas-U.S. Chemical Co 

Tex Chem Co 

Texlze Chemicals, Inc 

Textllana Corp 

Thiokol Chemical Corp 

Thomason Industries, Inc., Southern Resin Div— - 

Thompson Chemical Co 

Thompson-Hayward Chemical Co 

Ticonderoga Chemical Corp 

Tidewater Oil Co 

Toms River Chemical Corp 

Toni Co 

Tousey Varnish Co 

Trancoa Chemical Corp 

Arthur C. Trask Co 

Triangle Chemical Co 

Trojan Powder Co 

Troy Chemical Co 

Trylon Chemical Corp 

Joseph Turner & Co 



Ine- 



Paul Uhllch & Co, 

Ungerer & Co 

Union Bag- Camp Paper Corp 
Union Carbide Corp.: 

Chemicals Div 

Plastics Div 

Silicones Div 

Union Oil Co. of California 

Union Starch & Refining Co., Inc 

United Carbon Co 

United Chemical Corp. of Norwood 

United Chemical Products Corp 

United Cork Companies 

United Oil Manufacturing Co 

U.S. Borax Research Corp 

U.S. Oil Co 



Nelio Chemical Dlv- 



400 W. Roosevelt Ave., Bensenvllle, 111. 60106. 

P.O. Drawer G, Gramercy, La. 70052. 

"ilO N. Hart St., Chicago, 111. 60622. 

11 William St., Belleville, N.J. 07109. 

Wood River Junction, R.I. 02894. 

707 W. 5th St., Los Angeles, Calif. 90054. 

1608 Walnut St., Philadelphia, Pa. 19103. 

P.O. Box F, Claymont, Del. 19703. 

P.O. Box 2039, Tulsa, Okla. 74102. 

P.O. Box 658, Corpus Christ!, Tex. 78403. 

115 W. Jackson Blvd., Chicago, 111. 60604. 

4732 St. Clair Ave., Cleveland, Ohio 44103. 

30 Henry St. , Bethel, Conn. 06801. 

335 McLean Blvd., Paterson, N.J. 07504. 

1636 Wayside Rd., Cleveland, Ohio 44112. 

Ryan Ave., Ashton, R.I. 02805. 

726 King St., Wilmington, Del. 19801. 

P.O. Box 388, liyndhurst, N.J. 07071. 

250 S. Water St. , Providence, R. I. 02901. 

Valley Forge, Pa. 19481. 

100 Park Ave., New York, N.Y. 10017. 

300 E. 42d St., New York, N.Y. 10017. 

P.O. Box 911, Pensacola, Fla. 32501. 

830 Magnolia Ave., Elizabeth, N.J. 07114. 

P.O. Box 38, East Brunswick, N.J. 08816. 

P.O. Box 2511, Houston, Tex. 77001. 

Copperhlll, Tenn. 37317. 

P.O. Box 52332, Houston, Tex. 77052. 

P.O. Box 988, Pasadena, Tex. 77501. 

P.O. Box 667, Port Neches, Tex. 77651. 

20-21 Wagaraw Rd., Fair Lawn, N.J. 07410. 

P.O. Box 368, Greenville, S.C. 29602. 

12607 Cerise Ave., Hawthorne, Calif. 90250. 

P.O. Box 27, Bristol) Pa. 19007. 

P.O. Box 352, Fayettevllle, N.C. 28302. 

90 Mendor Ave., Pawtuoket, R.I. 02852. 

P.O. Box 768, Kansas City, Mo. 64141. 

P.O. Box 11, Leominster, Mass. 01453. 

Delaware City, Del. 19706. 

P.O. Box 71, Toms River, N.J. 08753. 

456 Merchandise Mart, Chicago, 111. 60654. 

135 W. Lake St., North Lake, 111. 60164. 

312 Ash St., Reading, Mass. 01867. 

327 S. LaSalle St., Chicago, 111. 60604. 

P.O. Box 4528, Macon, Ga. 31208. 

17 N. 7th St., Allentown, Pa. 18105. 

338 Wilson Ave., Newark, N.J. 07105. 

P.O. Box 5101, Station B, Greenville, S.C. 29606. 

P.O. Box 88, Rldgefield, N.J. 07451. 

90 West St., New York, N.Y. 10006. 

161 Avenue of the Americas, New York, N.Y. 10013. 

P.O. Box 6170, Jacksonville, Fla. 32205. 

270 Park Ave., New York, N.Y. 10017. 

270 Park Ave., New York, N.Y. 10017. 

270 Park Ave., New York, N.Y. 10017. 

461 S. Boylston St., Los Angeles, Calif. 90017. 

301 Washington St., Columbus, Ind. 47201. 

P.O. Box 149, Baytown, Tex. 77520. 

P.O. Box 327, Endlcott St., Norwood, Mass. 02062. 

York and Colgate Sts., Jersey City, N.J. 07302. 

50 Central Ave., Kearny, N.J. 07032. 

2d and Cascade Sts., Erie, Pa. 16512. 

3075 Wllshlre Blvd., Los Angeles, Calif. 90005. 

P.O. Box 4228, E. Providence, R.I. 02914. 



226 SYNTHETIC ORGANIC CHEMICALS, 1964 

TABLE 22. — Synethic organic chemicals.- Directory of manufacturers , i564— Continued 



Name of company 



U.S. Peroxygen Corp. 

United States Pipe & Foundry Co 

U.S. Plastic & Chemical Corp 

United States Plywood Corp., California Div., 

Shasta Operations. 

Universal Chemicals Corp 

Universal Detergents, Inc. & Petrochemicals Co- 
Universal Oil Products Co 

Trubek Chemical Co. Div 

Upjohn Co 

Carwin Co. Div 

Polymer Chemicals Div 

Utah Resin Co., Inc 

Valchem 

Valentine Sugars, Inc., Valite Div 

Van De Mark Chemical Co 

Vanderbilt Chemical Corp 

Van Dyk & Co., Inc 

Vamey Chemical Co 

Velsicol Chemical Corp 

Tensyn Div 

Vermi lye-Bell 

Verona-Pharma Chemical Corp 

Vickers Refining Co., Inc 

Vineland Chemical Co 

Virginia Chemicals, Inc 

Vitamins, Inc 

Vita-Var Corp., Div. of Textron Industries, Inc- 
Vulcan Materials Co., Frontier Chemical Co. Div- 

Wallaoe & Tieman, Inc. : 

Harohem Div 

Lucidol Div 

Wamer-Jenkinson Manufacturing Co 

Warren Paint & Color Co 

Washhum-Purei Co ' 

Washine Chemical Corp 

West Coast Adhesives Co 

Western Dry Color Co 

Westinghouse Electric Corp., Micarta Div 

West Virginia Pulp & Paper Co., Polychemicals 
Div. 

Weyerhaeuser Co., Wood Products Div 

■White & Bagley Co 

White & Hodges, Inc 

White Laboratories, Inc 

Whitmoyer Laboratories, Inc 

Whittemore-Wright Co. Inc 

Wica Chemicals, Inc 

Wilmot & Cassidy, Inc 

Wilson & Co., Inc. : 

Wilson Laboratories Div 

Wilson-Martin Div 

Witco Chemical Co., Inc 

Sonnebom Div 

W. A. Wood Co 

Wood Chemicals, Inc 

Wood Ridge Chemical Corp 

Woonsocket Color & Chemical Co 

Worthington Biochemical Corp 

Wyandotte Chemicals Corp 

Young Aniline Works, Inc 



Office address 



850 Morton Ave., Richmond, Calif. 9480^. 

3300 1st Ave. N. , Birmingham, Ala. 35202. 

122 E. Railroad Ave., W. Haverstraw, N.Y. 10927. 

P.O. Box 1688, Redding, Calif. 96002. 

1224 ttrndon Rd., P.O. Box 1224, Ashton, R.I. 028£ 
1825 E. Spring St., Long Beach, Calif. 90806. 
30 Algonquin fid., Des Plaines, 111. 60018. 
State Highway 17, E. Rutherford, N.J. 07073. 
7000 Portage Rd., Kalamazoo, Mich. 49001. 
Stiles Lane, North Haven, Conn. 06473. 
Battle Ground Rd., Houston, Tex. 77001. 
418 Keams Bldg., Salt Lake City, Utah 84101. 

1407 Broadway, New York, N.Y. 10018. 

726 Whitney Bldg., New Orleans, La. 70130. 

N. Transit Rd., Lockport, N.Y. 14094. 

33 Winfield St., E. Norwalk, Conn. 06855. 

11 William St., Belleville, N.J. 07109. 

2001 Afton Rd., Janesville, Wis, 53545. 

330 E. Ohio St., Chicago, 111. 60611. 

4902 Central Ave., Chattanooga, Tenn. 37410. 

21707 Bothell Way, Bothell, Wash. 98011. 

P.O. Box 385, Union, N.J. 07083. 

P.O. Box 2240, Wichita, Kans. 67201. 

W. Wheat Rd., Vineland, N.J. 08360. 

West Norfolk, Va. 23703. 

809 W. 58th St., Chicago, 111. 60621. 

177 Oakwood Ave., Orange, N.J. 07050. 

P.O. Box 545, Wichita, Kans. 67201. 



25 Main St., Belleville, N.J. 07109. 

1740 Military Rd., Buffalo, N.Y. 14240. 

2526 Baldwin St., St. Louis, Mo. 63106. 

P.O. Box 1307, Nashville, Tenn. 37202. 

2244 Elston Ave., Chicago, 111. 60614. 

165 Main St., Lodi, H.J. 07644. 

11104 NW. Front Ave., Portland, Oreg. 97231. 

600 W. 52d St., Chicago, 111. 60609. 

Trafford, Pa. 15085. 

P.O. Box 5207, N. Charleston, S.C. 29406. 

118 S. Palmetto St., Marshfield, Wis. 54449. 
P.O. Box 1171, Worcester, Mass. 01601. 
576 Lawrence St., Lowell, Mass. 01852. 
Galloping Hill Rd., Kenilworth, N.J. 07033. 
19 N. Railroad St., %erstown. Pa. 17067. 
62 Alford St., Boston, Mass. 02129. 
P.O. Box 506, Charlotte, N.C. 28201. 
108 Provost St., Brooklyn, N.Y. 11222. 

4221 S. Western Blvd., Chicago, 111. 60609. 

Snyder Ave. and Swanson St., Philadelphia, Pa. 19148. 

P.O. Box 305, Paramus, N.J. 07652. 

277 Park Ave., New York, N.Y. 10017. 

108 Spring St., Everett, Mass. 02149. 

P.O. Box 3545, Eugene, Oreg. 97401. 

Park PI. E., Wood Ridge, N.J. 07075. 

176 Sunnyside Ave., Woonsocket, R.I. 02895. 

Freehold, N.J. 07728. 

1609 Biddle Ave., Vfyandotte, Mich. 48193. 

2731 Boston St., Baltimore, m. 21224. 



APPENDIXES 

A. U. S. Imports of Benzenoid Intermediates 
and Finished Benzenoid Products 

Table 23 summarizes, for 1963 and 1964, U.S. imports of benzenoid chemicals and products 
entered in 1963 under paragraphs 27 and 28 of the Tariff Act of 1930-'- and entered in 1964 under 
the Tariff Schedules of the United States (TSUS), schedule 4, part 1, subparts B and C. The data, 
which were obtained by analyzing invoices covering imports through all U.S. customs districts, 
are given in detail in 5. separate report of the Tariff Commission. 2 

In 1964, general imports of benzenoid intermediates entered under schedule 4, part IB, com- 
prised 651 items with a total weight of 18. 8 million pounds, and an invoice value of $14. 4 million. 
In 1963, imports consisted of 778 items with a total weight of 25. 2 million pounds, valued at 
$12. 6 million. About half of the benzenoid intermediates imported in 1964 were declared to be 
competitive (duty based on "American selling price"). In terms of quantity, about 40 percent of 
the total imports of these products in 1964 came from West Germany; imports from that country 
amounted to 7. 6 million pounds in 1964, compared with 8.3 million pounds in 1963. In 1964, 
imports from the United Kingdom amounted to 2. 2 million pound s , compared with 2. 5 million 



TABLE 23. 



. Benzenoid intermediates and finished benzenoid products : U.S. general imports, 
classified by use, 1963 and 1964 



Quantity 



Invoice 
value 



Quantity 



Invoice 
value 



Intermediates""" ' 

Finished benzenoid products, total 

Dyes, total 

Acid 

Azoic dyes 

Azoic components : 

Fast color "bases 

Fast color salts 

Naphthol AS and its derivatives- 
Basic 

Direct 

Disperse 

Fiber-reactive 

Fluorescent brightening agents 

Ingrain 

ttordant 

Solvent 

Sulfur 

Vat 

All other 

Benzenoid pigments (toners and lakes) 

Medicinals and pharmaceuticals 

Flavor and perfume materials 

All other 



25,249 
20,109 



8,917 

1,712 

13 

169 

118 

1,00A 

456 

950 

454- 

395 

82 

5 

232 

112 

29 

3,163 

23 

363 

2,961 

1,957 

5,911 



1,000 
dollars 
12,617 

^ 30,992 



1,000 
pounds 
18,789 

23,682 



10,096 
2,093 

14 

311 
113 
901 
1,018 
1,015 
900 
416 
151 

292 

128 

11 

2,713 

3 20 

684 

3,127 

1,613 

8,162 



1,000 
dollars 



14,410 
34,670 



16,261 



^ Includes small quantities of rubber-processing chemicals. 

^ Revised to include azoic dye components, formerly classified as inteimediates. 
^ Includes ingrain dyes. 

* Revised to include organic pesticides and agricultural chemicals, plasticlzers, surface-active agents, and 
textile assistants, formerly classified as intennediates . 

Source: Compiled from the records of the U.S. Bureau of Customs. 



The import statistics for 1963 have been revised to account for the transfer of such commodities as fast color bases, fast color salts, 
n^hthol AS and derivatives, pesticides, and textile assistants to schedule 4,pt. IC, TSUS. 

^Imports of Benzenoid Chemicals and Products, 1964, TC Publication 159, 1965 [processed]. 

227 



228 SYNTHETIC ORGANIC CHEMICALS, 1964 

pounds in 1963. Imports from Japan amounted to 2.2 million pounds, compared with 2. 1 million 
pounds in 1963. Imports from Canada totaled 2.0 million pounds in 1964, compared with 7.3 mil- 
lion pounds in 1963; and imports from Italy amounted to 1 . 6 million pounds in 1964, compared 
with 2.4 million pounds in 1963. In 1964, sizable quantities of intermediates also were imported 
from France (1,049,000 pounds), Switzerland (1,043,000 pounds), Sweden (629,000 pounds), and 
the Netherlands (254,000 pounds). Smaller quantities came from Belgium (120,000 pounds), and 
Czechoslovakia (55,000 pounds). 

The most important intermediates imported in 1964 were adipic acid; refined anthracene; 
p-nitrotoluene; 1 , 6-hexanediamine; polyalkylbenzene; cyclohexane sulfamic acid, calcium salt; 
acetoacetanilide; 3-hydroxy-2-naphthoic acid (B.O. N. ); and p-toluenesulfonamide. In 1964, imports 
of adipic acid, which amounted to 1 . 9 million pounds, were principally from Canada; imports of 
refined anthracene, which totaled 900, 000 pounds, all came from West Germany; imports of 
p-nitrotoluene, which came from Sweden and West Germany, totaled 748, 000 pounds; imports of 

1, 6-hexanediamine, which came from France, Italy, and West Germany, amounted to 741, 000 
pounds; imports of polyalkylbenzene (725, 000 pounds) all came from Italy; imports of cyclohexane- 
sulfamic acid, calcium salt (714,000 pounds), all came from Japan; and imports of acetoacet- 
anilide, which came from the United Kingdom, Switzerland, West Germany, and Japan, amounted 
to 599,000 pounds. Among the other important individual chemicals imported, imports of 3- 
hydroxy-2-naphthoic acid (B.O.N.) came from Italy, Japan, and West Germany; p-toluene- 
sulfonamide came principally from Japan. 

Imports in 1964 of all finished benzenoid products that are dutiable under part IC comprised 

2, 292 listed items, with a total weight of 23. 7 million pounds and an invoice value of $34. 7 mil- 
lion. In 1963, imports consisted of 2, 005 items, with a total weight of 20. 1 million pounds and an 
invoice value of $31. million. Imports of dyes in 1964 amounted to $16. 3 million (invoice value), 
or 46. 9 percent of the value of all imports under part IC. In 1963, imports of dyes amounted to 
$12. 6 million (invoice value), or 40. 5 percent of the value of all imports under part IC. 

Imports of medicinals and pharmaceuticals, the next most important group of products 
entered under part IC in 1964, were about 4 percent less in that year than in 1963 and 1962. In 
1964, imports of medicinals and pharmaceuticals were valued at $9. 8 million (invoice value), or 
28. 2 percent of the total value of imports under part IC. In 1963, imports of medicinals and 
pharmaceuticals were valued at $10. 2 million, or 38 percent of the total value of imports under 
part IC. In 1964, imports of benzenoid pigments (toners and lakes) were valued at $1, 128, 000, 
compared with $616, 000 in 1963. Imports of benzenoid flavor and perfume materials in 1964 
($2. 3 million) were 19 percent less than in 1963 ($2. 9 million). In 1964, imports of other benze- 
noid products entered under part IC (chiefly synthetic resins and pesticides) were valued at $5. 2 
million, compared with $4.8 million (revised) in 1963. 



APPENDIX B 



229 



List of Colour Index and Common Names for Synthetic 
Organic Pigments (Toners and Lakes) 



In the Commission's reports for 1957 and earlier years, individual toners and lakes were 
identified by the names by which they were most commonly known in the literature and in the 
trade. In the reports for 1958 and the years since, they have been identified by the names used 
in the second edition of the Colour Index. 

The following list of all Colour Index names which appear in tables 1 lA and 12 of this report 
is appended for quick reference. The list gives the common names (and coupling components, in 
the case of azo pigments) for each Colour Index pigment listed. 

Synthetic organic pigments: List of Colour Index and common names 



Colour Index name 


Common name 


Pigment 


Yellow 1 


Hansa Yellow G (2-nitro-p-toluidine and aoetoaoetanilide) . 


Pigment 


Yellow 3 


Hansa Yellow lOG (<i-chloro-2-nitroaniline and o-ohloroacetoaoetanilide). 


Pigment 


Yellow 12— 


Benzidine Yellow (3,3 '-dlohlorobenzidine and aoetoacetanilide) . 


Pigment 


Yellow 13 


Benzidine Yellow (3,3 '-dlchlorobenzidine and 2,4-acetoacetoxylidide) . 


Pigment 


Yellow U- — 


Benzidine Yellow (3,3 '-dichlorobenzldine and o-aoetoacetotoluidide). 


Pigment 


Yellow 17 


Benzidine Yellow (3,3 '-dichlorobenzidine and o-aoetoacetanisidide) . 


Pigment Orange 5 


Dinltroaniline Orange (2,4.-dinitroaniline and 2-naphthol) . 


Pigment Orange 13 


Benzidine Orange (3,3 '-dlohlorobenzidine and 3-methyl-l-phenyl-2-pyrazolin-5-one). 


Pigment Orange 16 


Dianlsidine Orange (o-dianisidine and acetoaoetanilide) . 


Pigment 


Red 1 


Para Red (p-nitroaniline and 2-naphthol) . 


Pigment 


Red 2 


Naphthol Red (2,5-dichloroaniline and Naphthol AS). 


Pigment 


Red 3 


Toluidine Red (2-nitro-p-toluidine and 2-naphthol), 


Pigment 
Pigment 




Chlorinated Para Red (2-chloro-4-nitroaniline and 2-naphthol). 
Naphthol Red (N^,N^-diethyl-4-methoxymetanilamide and Naphthol AS-ITR). 


Red 5 


Pigment 


Red 13 - 


Naphthol Red (2-nitro-p-toluidine and Naphthol AS-D) . 


Pigment 


Red 17 


Naphthol Red (5-nitro-o- toluidine and Naphthol AS-D). 


Pigment 


Red 18 


Toluidine Maroon (2-nitro-p-toluidine and Naphthol AS-BS). 


Pigment 


Red 22 


Naphthol Red (5-nitro-o- toluidine and Naphthol AS). 


Pigment 


Red 23 


Naphthol Red (5-nitro-o-anisidine and Naphthol AS-BS). 


Pigment 


Red 38 


Pyrazolone Red (3,3 '-dlohlorobenzidine and 5-oxo-l-phenyl-2-pyrazoline-3-oarboxylio 
acid, ethyl ester) . 


Pigment 




Permanent Red 2B (6-amino-4-chloro-m-toluenesulfonio acid and 3-hydroxy-2-naphthoio 

acid) . 
Lithol Red R (2-amino-l-naphthalenesulfonic acid and 2-naphthol). 




Pigment 






Pigment 


Red 52 


Lithol Red 2G''- (2-amino-5-chloro-p-toluenesulfonic acid and 3-hydroxy-2-naphthoic 

acid) . 
Red Lake C (2-amino-5-chloro-p-toluenesulfonio acid and 2-naphthol). 


Pigment 


Red 53- 


Pigment 


Red 54 


Helio Bordeaux BL ( 1-naphthylamine and l-naphthol-5-sulfonio acid). 


Pigment 


Red 57 


Lithol Rubine B (6-amino-m-toluenesulfonic acid and 3-hydroxy-2-naphthoic acid). 


Pigment 


Red 60 


Pigment Scarlet 3B (anthranilic acid and 2-naphthol-3,6-disulfonlc acid). 


Pigment 


Red 63 


BON Maroon (2-amino-l-naphthalenesulfonlc acid and 3-hydroxy-2-naphthoio acid). 


Pigment 


Red 81 


Rhodamine 6G. 


Pigment 


Red 83 


Alizarin Red B. 


Pigment 


Red 90 


Bromo Acid; Eosin. 


(Acid Red 26) 


Scarlet 2R (2,4-xylidine and 2-naphthol-3,6-disulfonic acid). 


Pigment 


Violet 1 


Rhodamine E. 


Pigment 


Violet 3 


Methyl Violet B. 


Pigment 
Pigment 




Helio Fast Rubine 431. 
Victoria Pure Blue BO. 


Blue 1 


Pigment 


Blue 2 


Victoria Blue B. 


Pigment 


Blue 9 


Setoglauoine . 


Pigment 


Blue lA 


Ethyl Violet. 


Pigment 


Blue 15 — 


Phthalocyanine Blue. 


Pigment 


Blue 19 


Aliali Blue. 


Pigment 


Blue 24 


Peacock Blue Late. 


Pigment 


Blue 25— 


Dianlsidine Blue (o-dianisidine and Naphthol AS). 


Pigment 


Green 1 


Brilliant Green. 


Pigment 


Green 2 


Brilliant Green and Thioflavine. 


Pigment 
Pigment 




Malachite Green. 
Phthalocyanine Green. 








Pigment Green B. 








Bismarck Brown R (toluene-2,4-diamine). 
Logwood Black. 









^ Lithol Red 2G has become generally accepted as the name for Pigment Red 52, although the 2d edition of the Colo 
Index lists this name for Pigment Red 69. 

Note. — When the name of a color is enclosed in parentheses, it indicates that this name is that of the dye from 
which the pigment can be made and that no name for the pigment itself is given in the Colour Index. 



230 SYNTHETIC ORGANIC CHEMICALS, 1964 



C. Employment in the Synthetic Organic Chemicals Industry, 1964 
(Original Manufacturers Only) 

At the request of the Special Representative for Trade Negotiations, the Tariff Commission 
conducted a one-time survey of original manufacturers in the synthetic organic chemicals industry 
to obtain employment data by product groups, by plants, for 1964. The survey also included pro- 
ducers of crude products from coal tar, petroleum, and natural gas. Figures in table 24 show 
employment as of December 31, 1964, or the pay period nearest the end of 1964. 

There were 275,299 persons employed in the production and sales of synthetic organic chem- 
icals, including crudes, in December 1964; 262,261 were employed in the synthetic organic 
chemicals industry and 13, 038 in the tar crudes and petroleum crudes industries. Employment 
data were submitted by 696 companies, operating 1, 156 plants, out of a total of 803 companies 
that reported production and sales datatothe Commission for 1964. The companies which reported 
employment accounted for 92.4 percent of the 1964 production of synthetic organic chemicals, for 
99. 1 percent of production of tar crudes, and for 96i 6 percent of the production of crude products 
from petroleum and natural gas. For the most part, ^the chemical companies which did not report 
employment are relatively small in size; a few large, integrated companies also did not report. 
Production by these large companies, however, amounted to only a small part of total U.S. 
production of synthetic organic chemicals. 

No attempt was made to collect separate data on production workers. Supervisory employees 
and research or sales personnel located at the plants are included in the figures on plant employ- 
ment. Therefore, the figures on employment at plants shown in table 24 cannot be used to deter- 
mine the number of production workers in the industry. 

Coverage of the industry, by product groups, is also given in table 24. The percent of the 
industry covered is based on the production accounted for by those companies reporting employ- 
ment in each respective product group. The reporting companies accounted for more than 85 per- 
cent of production in 1964 in 13 of the 15 product groups. Companies reporting employment in 
two product groups--elastomer s and miscellaneous cyclic chemicals --accounted for less than 71 
percent of production in each group in 1964. (See table 24. ) 

Employment in December 1964 in the synthetic organic chemicals industry, by States having 
three or more plants, is given in table 25. Similar data on employment in the tar crudes and 
petroleum crudes industries cannot be published without disclosing the operations of individual 
companies . 

Total employment of 1, 087 in the tar crudes industry was reported by plants in the following 
States: Alabama, California, Illinois, Maryland, Massachusetts, Michigan, New Jersey, New 
York, Ohio, Pennsylvania, Texas, and Wyoming. 

Employment in the petroleum crudes industry, Twhich amounted to 11, 951 in December 1964, 
was reported by plants located in California, Connecticut, Delaware, Illinois, Indiana, Kansas, 
Kentucky, Louisiana, Massachusetts, Michigan, Mississippi, New Jersey, New York, Ohio, 
Oklahoma, Pennsylvania, South Carolina, Texas, and West Virginia. 



APPENDIX C 



231 



TABLE 2A. — Synthetic organic chemicals industry, including crudes : Employment 
as of Dec. 31, 1964, or pay period nearest end of 1964 



Product group 



Grand total 

Tar and tar crudes 

Crude products from petroleum^ total 

A. Aromatios and naphthenes 

B. Aliphatic hydrocarbons 

Synthetic organic chemicals, total 

Benzenoid, jnodified benzenoid, and benzenoid raw 

materials 

Other 

Cyclic intermediates, total 

A. Benzenoid 

B. Other 

Dyes 

Synthetic organic pigments 

Medicinal chemicals, total 

A. Benzenoid 

B. Other 

Flavor and perfume materials, iiotal- 

A. Benzenoid and modified benzenoid 

B. Other 

Plastics and resin materials, total 

A. Benzenoid 

B. Other 

Rubber-processing chemicals, total 

A. Benzenoid 

B. Other 

Elastomers, total 

A. Benzenoid 

B. Other 

Plastioizers, total 

A. Benzenoid 

B. Other 

Surf ace -active agents, total 

A. Benzenoid 

B. Other 

Pesticides, total 

A. Benzenoid 

B. Other 

Miscellaneous cyclic chemicals, total 

A. Benzenoid 

B. Other 

Miscellaneous aoyclio chemicals, total 

A. From benzenoid raw materials 

B. Other 

Other synthetic organic chemicals, total** 

A. Benzenoid 



Total employment-'- 



275,299 



2,920 
9,031 



262,261 



115,611 
146,650 

21,625 

20,294- 

1,331 

9,347 

3,873 

30,842 

14,989 

15,853 

2,533 

1,223 

1,310 

68,648 

29,708 

38,940 

3,618 

2,199 

1,419 

14,306 

4,097 

10,209 

3,811 

1,928 

1,883 

13,932 

6,796 

7,136 

7,459 

2,874 

4,585 

7,334 

3,751 

3,583 

68,035 

13,217 

54,818 

6,898 

1,315 

5,583 



Percent of 
industry 



99.1 
96.6 



99.8 
99.0 
92.5 



65.8 
93.6 
93.8 



Distribution of employment 



At 
plants 



214,777 



2,211 
7,997 



203,609 



89, 937 
113,672 

16,843 

15,815 

1,028 

7,064 

3,308 

19,497 

9,365 

10,132 

2,220 

1,055 

1,165 

54,735 

23,995 

30,740 

2,784 

1,590 

1,194 

12,283 

3,448 

8,835 

3,001 

1,572 

1,429 

11,870 

5,651 

6,219 

5,192 

2,018 

3,174 

6,060 

3,209 

2,851 

53,324 

10,771 

42,553 

5,428 

1,076 

4,352 



At other 
locations' 



Bnployment at those locations -where the same persons handle more than a single product group was allocated be- 
tween the applicable products by the reporting congsany. 

^ Coverage shown is based on the production accounted for by those companies reporting eraplo3nnent in each respec- 
tive product group. 

^ Includes employees engaged in sales, research, administration, etc. 

Production and sales of chemicals reported in this group were transferred to the appropriate product groups 
shown above. Bnployment figures, however, were not allocated. 
' Not available. 



232 



SYNTHETIC ORGANIC CHEMICALS, 1964 



TABLE 25. — Synthetic organic chemicals industry: Employment by States, 
as of Dec. 31, 1964, or pay period nearest end of 1964 



Number 

employed 



Number 
eii5)loyed 



New Jersey 

Texas 

New York 

West Virginia — 
Pennsylvania — 

Michigan 

Ohio 

Tennessee 

Illinois 

California 

Louisiana 

Kentucky 

Massachusetts — 

Virginia 

Connecticut 

South Carolina- 
Missouri 

North Carolina- 



29,675 

26,236 

18,376 

13,330 

13,111 

12,915 

9,571 

8,510 

8,333 

6,738 

5,877 

5,589 

5,243 

5,000 

4,031 

3,819 

3,545 

3,077 



Alabama 

Indiana 

Delaware 

Rhode Island 

Wisconsin 

Kansas 

Georgia 

Maryland 

Colorado 

Mississippi 

Washington 

Iowa 

All other States^ 

Total employment at plants - 
finployment at other than plant 



locations - 



Grand total- 



2,592 

2,521 

1,947 

945 

917 

839 

812 

743 

567 

539 

522 

337 

7.352 



203,609 
58,652 



262,261 



■'■ All States listed have 3 or more producing plants. Qnployment is distributed among the plants in such a manner 
as not to disclose individual company operations. 

^ Includes Arkansas, Florida, Maine, Minnesota, Montana, Nebraska, Nevada, New Hampshire, New Mexico, Oklahoma, 
Oregon, and Utah. 



»U. S. GOVERNMENT PRINTING OFFICE: 1965 O - 796-332 



REPORTS OF THE UNITED STATES TARIFF COMMISSION ON THE OPERATION OF THE 

TRADE AGREEMENTS PROGRAM 

♦Operation of the Trade Agreements Program, June 1934 to April 1948 (Rept. No. 160, 2d ser., 1949) : 
Part I. Summary 

Part II. History of the Trade Agreements Program 
Part III. Trade-Agreement Concessions Granted by the United States 
Part IV. Trade-Agreement Concessions Obtained by the United States 
Part V. Effects of the Trade Agreements Program on United States Trade 
♦Operation of the Trade Agreements Program: Second Report, April 1948-March 1949 (Rept. No. 

163, 2d ser., 1950) 
♦Operation of the Trade Agreements Program: Third Report, April 1949-June 1950 (Rept. No. 172, 

2d ser., 1951) 
♦Operation of the Trade Agreements Program: Fourth Report, Jidy 1950-June 1951 (Rept. No. 174, 

2d ser., 1952) 
♦Operation of the Trade Agreements Program: Fifth Report, July 1951- June 1952 (Rept. No. 191, 

2d ser., 1954) 
♦Operation of the Trade Agreements Program: Sixth Report, July 1952- June 1953 (Rept. No. 193, 

2d ser., 1954) 
♦Operation of the Trade Agreements Program: Seventh Report, July 1953- June 1954 (Rept. No. 

195, 2d ser., 1955) 
♦Operation of the Trade Agreements Program: Eighth Report, July 1954r-June 1955 (Rept. No. 

197, 2d ser., 1956) 
♦Operation of the Trade Agreements Program: Ninth Report, July 1955-June 1956 (Rept. No. 199, 

2d ser., 1957) 
♦Operation of the Trade Agreements Program: 10th Report, July 1956- June 1957 (Rept. No. 202, 

2d ser., 1959) 
♦Operation of the Trade Agreements Program: 11th Report, July 1957- June 1958 (Rept. No. 204, 2d 

ser., 1959) 
♦Operation of the Trade Agreements Program : 12th Report, July 1958- June 1959 (TC Publication 

9, 1961) 
♦Operation of the Trade Agreements Program : 13th Report, July 1959-June 1960 (TC Publication 

51, 1962) 
Operation of the Trade Agreements Program : 14th Report, July 1960-June 1962 (TC Publication 

120, 1964), B5i 
Operation of the Trade Agreements Program : 15th Report, July 1962- June 1963 (TC Publication 
147, 1965), 35^ 



NOTE. — The reports preceded by an asterisk (*) are out of print. Those followed by a price may be purchased from 
the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C., 20402. See inside front 
cover for additional reports. All U.S. Tariff Commission reports reproduced by the Government Printing Office may 
be consulted in the official depository libraries throughout the United States. 



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