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Full text of "Synthetic organic chemicals"

Given By 

p. rspct/ct memoirs 

M 3 ^ 



UNITED STATES TARIFF COMMISSION 

SYNTHETIC 
ORGANIC CHEMICALS 

United States Production 
and Sales, 1965 

TC Publication 206 

on Public Lib 

tntcndent of Documents 

JUL 2 11967 

>S!TORY 




RECENT REPORTS OF THE UNITED STATES TARIFF COMMISSION ON SYNTHETIC 

ORGANIC CHEMICALS 

*Synthetic Organic Chemicals, United States Production and Sales, 1960 (TC Publication 34, 1961) 
Synthetic Organic Chemicals, United States Production and Sales, 1961 (TC Publication 72, 1962), 

$1.25 
Synthetic Organic Chemicals, United States Production and Sales, 1962 (TC Publication 114, 

1963), $1.50 
Synthetic Organic Chemicals, United States Production and Sales, 1963 (TC Publication 143, 

1964), $1.50 
Synthetic Organic Chemicals, United States Production and Sales, 1964 (TC Publication 167, 

1965), $1.25 



NOTE. — The report preceded by an asterisk!*) is out of print. The other reports listed may be purchased from 
the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402. See inside back 
cover for additional reports. AH U.S. Tariff Commission reports reproduced by the Government Printing Office 
may be consulted in the official depository libraries throughout the United Stales. 



UNITED STATES TARIFF COMMISSION 



SYNTHETIC 
ORGANIC CHEMICALS 

United States Production 
and Sales, 1965 



UNDER THE PROVISIONS OF 
SECTION 332 OF THE TARIFF 
ACT OF 1930, AS AMENDED 



U.S. GOVERNMENT PRINTING OFFICE 
WASHINGTON : 1967 



TC Publication 206 



UNITED STATES TARIFF COMMISSION 

Paul Kaplowitz, Chairman 
Glenn W. Sutton, Vice Chairman 
James W. Culliton 
Dan H. Fenn, Jr. 
Penelope H. Thunberg 

Donn N. Bent, Secretary 



Address all communications 

UNITED STATES TARIFF COMMISSION 

Washington, D.C. 20436 



For sale by the Superintendent of Documents, U.S. Government Printing Office 
Washington, D.C. 20402 - Price $1.00 



CONTENTS 

Page 



Introduction- 
Summary 



Vll 



PART I. PRODUCTION AND SALES OF TARS, TAR CRUDES, AND CRUDES 
DERIVED FROM PETROLEUM AND NATURAL GAS 

Tars 

Tar crudes '■ 

Crude products from petroleum and natural gas for chemical conversion \ 

PART II. PRODUCTION AND SALES OF INTERMEDIATES AND FINISHED 
SYNTHETIC ORGANIC CHEMICALS, BY GROUPS 

General 

Cyclic intermediates _ 

Dyes """~-'.~."l"l""l"" 10 

Pigments ^ 

Medicinal chemicals , , 

Flavor and perfume materials ,, 

Plastics and resin materials ,□ 

Rubber -processing chemicals .-, 

Elastomers (synthetic rubbers) ., 

P lasticize r s *j? 

Surface -active agents *i? 

Pesticides and other organic agricultural chemicals 52 

Miscellaneous chemicals ?f 

PART III. ALPHABETICAL LIST OF INDIVIDUAL PRODUCTS, BY GROUPS, 
AND NAMES OF MANUFACTURERS 

Tar crudes , , 

Crude products from petroleum and natural gas for chemical conversion 62 

Cyclic intermediates /. 

Dyes :::::::::::::::::::::::: % 

Pigments -- -- 7 

Medicinal chemicals , ,f 

Flavor and perfume materials 12 q 

Plastics and resin materials ,-/. 

Rubber -proce s sing chemicals 13R 

Elastomers (synthetic rubbers) _ , .-, 

Plasticizers ""1 !?, 

Surface -active age nts r*f 

Pesticides and other organic agricultural chemicals w , 

Miscellaneous chemicals ?f 

Directory of manufacturers Jjj^ 

APPENDIX 

U.S. imports of benzenoid intermediates and finished benzenoid products 211 



Introduction 

This is the forty-ninth annual report of the U.S. Tariff Commission on domestic production 
and sales of synthetic organic chemicals and the raw materials from which they are made. The 
report presents statistics for 1965 on production and sales of crude organic chemicals derived 
from coal, natural gas, and petroleum; of intermediates; and of finished synthetic organic chem- 
ical products. The finished products are grouped according to their principal use--dyes, syn- 
thetic organic pigments, medicinal chemicals, flavor and perfume materials, plastics and resin 
materials, rubber-processing chemicals, elastomers, plasticizers, surface- active agents, pesti- 
cides and other organic agricultural chemicals, and miscellaneous chemicals. The use classifi- 
cations of finished synthetic organic chemicals are based principally on the manufacturers' 
annual reports to the Tariff Commission; other sources include trade associations, the chemical 
literature, chemical dictionaries, encyclopedias, and consultants in the chemical industry. With 
a few exceptions, the report does not cover organic chemicals (such as wood- distillation products 
essential oils, and naval stores) that are derived from natural (vegetable) sources by simple ex- 
traction or distillation. The Commission has compiled the statistics given in this report from 
information supplied by approximately 800 primary manufacturers, listed in part III, 

The first section of the report includes the statistics on all products and groups of products 
for which such information can be published. The second section lists all the chemicals and 
chemical products on which data are reported and identifies the manufacturers of each. Each 
reporting company has been assigned an identification symbol consisting of a combination 
of not more than three capital letters, selected in most instances with the approval of the manu- 
facturer, and usually bearing some relationship to the company name. The identification symbols 
are permanent and, except for such changes as may be necessary, will be used in all future re- 
ports in this series. Like the seven immediately preceding reports, this report includes data on 
only those individual chemicals for which the volume of production or sales in the year covered 
exceeded 1,000 pounds or for which the value of sales exceeded $1,000. 

The raw materials referred to in this report are obtained from coal, crude petroleum, nat- 
ural gas, and certain other natural materials, such as vegetable oils, fats, rosin, and grains. 
Crude organic chemicals are derived from coal by thermal decomposition, from petroleum and 
natural gas by catalytic cracking and by distillation or absorption, and from other natural 
sources by fermentation. Production of these crude organic chemicals is the first step in the 
manufacture of synthetic organic chemicals. From these crudes, intermediates are obtained by 
synthesis or refining; most of the intermediates are then converted into finished chemical prod- 
ucts, such as medicinal chemicals, plastics and resin materials, and dyes. More than half of the 
total production of intermediates is not sold directly to the ultimate consumer, but is used by 
the producing companies themselves in their manufacturing processes. The statistics given in 
this report include data for all known domestic producers of the items covered. 

In this report the statistics on production of the individual chemicals reported by manufac- 
turers include the total output of the companies' plants, i.e., the quantities produced for con- 
sumption within the producing plants, as well as the quantities produced for domestic and foreign 
sale. The quantities reported as produced, therefore, generally exceed the quantities reported 
as sold. Some of these differences, however, are attributable to changes in inventories. As speci- 
fied in the reporting instructions that the Commission sends to manufacturers, and as used in 
this report, production and sales (unless otherwise specifically indicated) are defined as follows: 

Production is the total quantity of a commodity made available by original manufacture only. It 
is the sum (expressed in terms of 100-percent active ingredient unless otherwise specified) of 
the quantities of a commodity- - 

(1) Produced, separated, and consumed in the same plant or establishment (a commodity 

is considered to be separated when it is isolated from the reaction system and/or 
when it is weighed, analyzed, or otherwise measured). Byproducts and coproducts 
not classified as waste materials are also included; 

(2) Produced and transferred to other plants or establishments of the same firm; 

(3) Produced and sold to other firms (including production for others under toll agree- 

ments 1 ); and 

(4) Produced and held in stock. 



A toll agreement is an agreement between two firms, under which one firm furnishes the raw materials and pays the processing costs 
and the other firm prepares the finished product and returns it to the first firm. 



vi INTRODUCTION 

Production excludes- - 

(1) Purification of a commodity unless specifically requested in the reporting instructions; 
2) Intermediate products that are formed in the manufacturing process but are not iso- 
lated from the reaction system- -that is, not weighed, analyzed, or otherwised meas- 
ured; and , . 

(3) Materials that are used in the process but are recovered for reuse or sale; and waste 
products that have no economic significance. 

Sales are defined as actual sales of commodities by original manufacturers only. Sales include-- 

(1) Shipments of commodities for domestic use and for export, or segregation in a ware- 

house when title has passed to the purchaser in a bonafide sale; 

(2) Shipments of a commodity produced by others under toll agreements; and 

(3) Shipments to subsidiary or affiliated companies. 

Sales exclude- - 

(1) All intracompany transfers within a corporate entity; 

(2) All sales of purchased commodities; and 

(3) All shipments of a commodity produced for others under toll agreements. 

The value of a sale is the net selling price, f.o.b. plant or warehouse, or delivered value, 
whichever represents the normal industry practice. 

Data on the chemicals covered in this report are usually given in terms of undiluted mate- 
rials. Products of 95 percent or more purity are considered to be 100 percent pure. The prin- 
cipal exceptions are the statistics on dyes and a few solvents, which are reported in terms of 
commercial concentrations, and the statistics on certain plastics and resins, which are reported 
on a dry basis. The report specifically notes those products for which the statistics are reported 
in terms of commercial concentrations. .*.,.., ■ „ 

The average unit values of sales for groups of products shown in the tables accompanying 
this report are weighted averages for products which vary widely in unit values and in the quan- 

tltie inthi S report, statistics are presented in as great detail as is possible without revealing the 
operations of individual producers. Statistics for an individual chemical or group of chemicals 
are not given unless there are three or more producers no one or two of which may be predomi- 
nant. Moreover, even when there are three or more producers, statistics are not given if there 
is any possibility that their publication would violate the statutory provisions relating to unlaw- 
ful disclosure of information accepted in confidence by the Commission. 

Statistics on tars and tar crudes include data furnished directly to the Tariff Commission by 
distillers of coal tar, water-gas tar, and oil-gas tar, and data furnished to the Division of Bitu- 
minous Coal, U.S. Bureau of Mines, by coke-oven operators. ,,..',-„ j 

Statistics on U.S. general imports in 1965 of benzenoid intermediates and finished benzenoid 
products that entered under schedule 4, parts IB and 1C, of the Tariff Schedules of the United 
States are given in the appendix. , 

Information on synonymous names of organic chemicals included in this report may be found 
in the SOCMA Handbook: Commercial Organic Chemical Names, recently published by the Chemical AD- 
stracts Service of the American Chemical Society, or in the Colour Index (2d edition), published in 
1956 by the Society of Dyers and Colourists. 



2 Sec. 5, U.S.C. 139b and sec. 18. U.S.C. 1905. 



Summary 

Combined production of all synthetic organic chemicals, tars, tar crudes, and crude prod- 
ucts from petroleum and natural gas in 1965 was 151,606 million pounds--an increase of 11.7 
percent over the output in 1964 (see table 1). Sales of these materials in 1965, which totaled 
80,204 million pounds, valued at $9,898 million, were 10.4 percent larger than in 1964 in terms 
of quantity and 7.1 percent larger in terms of value. These figures include data on production 
and sales of chemicals measured at several successive steps in the manufacturing process, and 
therefore they necessarily contain some duplication. 

In 1965, production of all synthetic organic chemicals, including cyclic intermediates and 
finished chemical products, totaled 88,864 million pounds, or 12.9 percent more than the output 
in 1964 (see table 1). Production of plastics and resin materials (11,685 million pounds) was 15.7 
percent larger in 1965 than in 1964; that of cyclic intermediates (16,865 million pounds) was 13.2 
percent larger; that of plasticizers (1,073 million pounds) was 12.8 percent larger; that of dyes 
(207 million pounds) was 12.4 percent larger; and that of pesticides and other organic agricul- 
tural chemicals (877 million pounds) was 12.1 percent larger. 

The output of most other groups of synthetic organic chemicals also increased in 1965 com- 
pared with 1964, with miscellaneous chemicals and medicinal chemicals showing increases of 
more than 10 percent. Production of rubber-processing chemicals (252 million pounds) was 3.3 
percent less in 1965 than in 1964. Production and sales statistics for surface-active agents for 
1965 are not comparable with those for previous years. 

TABLE 1. -- Synthetic organic chemicals and their raw materials: U.S. production and sales, 1964 and 1965 



Increase 

or 
decrease 
(-), 1965 

over 
1964 1 



Increase, 
1965 
over 
1964 1 



Increase, 
1965 
over 
1964 1 



Grand total 2 

Tar 

Tar crudes 

Crude products from petroleum and 
natural gas 

Synthetic organic chemicals, total 2 

Intermediates 

Eyes 

Synthetic organic pigments 

Medicinal chemicals 

Flavor and perfume materials 

Plastics and resin materials 

Rubber-processing chemicals 

ELastomers (synthetic rubbers) 

Plasticizers 

Surface-active agents 

Pesticides and other organic 

agricultural chemicals 

Miscellaneous chemicals 



Million 
pounds 
135,716 



Million 
dollars 
9,898 



7,629 
9,547 



78, 678 



8,027 
10,205 



88,864 



5.2 
6.9 



12.9 



3,361 
6,076 



20,465 
42,766 



3,662 
6,332 



23,402 
46, 807 



9.0 
4.2 



34 

131 



9,021 



14, 896 

184 

44 

144 

91 

10, 103 

261 

3,421 

951 

2,119 

783 
45,681 



16,865 

207 

48 

160 

99 

11,685 

252 

3,592 

1,073 

3,170 

877 
50,836 



( 3 ) 



13.2 
12.4 

9.1 
10.7 

9.6 
15.7 
-3.3 

5.0 
12.8 



12.1 
11.3 



6,470 

178 
35 

119 

80 

8,727 

184 
2,958 

905 
1,900 

692 
20, 518 



7,551 

190 

38 

129 

88 

10,053 

194 

3,041 

1,022 

1,698 

764 
22,040 



( 3 ) 



( 3 ) 



10.3 
7.4 



711 
264 

84 
646 

84 
2,120 
123 
810 
188 
350 

427 
2,651 



814 

292 

94 

362 

85 

2,504 

123 

843 

214 

300 

497 
2,890 



6.3 
4.1 



( 3 ) 



( 3 ) 



14.5 

10.7 
11.3 

1.5 

18.1 

.3 

4.1 
14.4 



16.4 
9.0 



Percentages calculated from figures rounded to thousands. 

Because of rounding, figures may not add to the totals shown. 

Data for 1965 are not comparable with those for 1964; for details see the appropriate tables. 



PART I. PRODUCTION AND SALES OF TARS, TAR CRUDES, AND 
CRUDES DERIVED FROM PETROLEUM AND NATURAL GAS 

Tars 

Coal tar is produced chiefly by the steel industry as a byproduct of the manufacture of coke; 
water-gas tar and oil-gas tar are produced by the fuel-gas industry. Production of coal tar, 
therefore, depends on the demand for steel; production of water-gas tar and oil-gas tar reflects 
the consumption of manufactured gas for industrial and household use. Water-gas and oil-gas 
tars have properties intermediate between those of petroleum asphalts and coal tars. Petroleum 
asphalts are not usually considered to be raw materials for chemicals. 

The quantity of tar produced from coal in the United States in 1 965 was 803 million gallons, 
or 5.2 percent more than the 763 million gallons produced in 1964. U.S. production of water-gas 
tar and oil-gas tar was not reported to the Commission for 1964 or 1965; production of these 
tars amounted to 19 million gallons in 1962, the last year for which production was reported to 
the Tariff Commission. 

Total consumption of tar in 1965 amounted to 766 million gallons, of which 616 million gal- 
lons was consumed by distillation, 123 million gallons as fuel, and 27 million gallons in mis- 
cellaneous uses. 

TABLE 2. — Tar; U.S. production and consumption, 1964 and 1965 

[in thousands of gallons] 



PRODUCTION 

Coal tar from coke-oven byproduct plants, total 1 

CONSUMPTION 

Total 

Tar consumed by distillation, total 

Coal tar distilled or topped by coke-oven operators 1 

Coal tar, water-gas tar, and oil-gas tar distilled by producers and tar 

distillers 2 

Tar consumed chiefly as fuel 1 

Tar consumed otherwise than by distillation or as fuel, total 

Coal tar consumed at coke-oven plants for roads and upkeep 1 

Coal tar, water-gas tar, and oil-gas tar processed at tar refineries, crude tar 
consumed for upkeep at such refineries, and tar consumed in making gas and in 
special- purpose tar blends 



762,918 



746, 900 



765,946 



601,753 



615,816 



293,957 

307, 796 

127,872 

17,275 



T7T 



16,904 



312,079 
303,737 
122,961 
27,169 



"371 



26,298 



1 Reported to the U.S. Bureau of Vines. 

2 Reported to U.S. Tariff Commission. Represents tar purchased from companies operating coke ovens and gas-retort 
plants and distilled by companies operating tar-distillation plants. 

Tar Crudes 

Tar crudes are obtained from coke-oven gas and by distilling coal tar, water-gas tar, and 
oil- gas tar. The most important tar crudes are benzene, toluene, xylene, naphthalene, and 
creosote oil. Some of the products produced from coal tar are identical with those produced from 
petroleum and natural gas. Data for materials derived from these latter sources are included, 
for the most part, in or with the statistics for materials derived from coal tar, which are shown 
in tables 3 and 4A. 1 



See also table 4B, pt. Ill, which lists these products alphabetically and identifies the manufacturers. 



2 SYNTHETIC ORGANIC CHEMICALS, 1965 

Domestic production of industrial and specification grades of benzene reported by coke-oven 
operators and petroleum operators 2 in 1965 amounted to 827 million gallons-- 13.2 percent more 
than the 730 million gallons reported for 1964. These statistics include data for benzene pro- 
duced from light oil and petroleum. Sales of benzene by coke-oven operators and petroleum op- 
erators in 1965 amounted to 511 million gallons, valued at $123 million, compared with 464 mil- 
lion gallons, valued at $104 million, in 1964. In 1965 the output of toluene 2 (including material 
produced for use in blending in aviation fuel) amounted to 549 million gallons-- 10.9 percent more 
than the 495 million gallons reported for 1964. Sales of toluene in 1965 were 325 million gallons, 
valued at $54 million, compared with 261 million gallons, valued at $44 million, in 1964. The 
output of xylene 2 in 1965 (including that produced for blending in motor fuels) was 340 million 
gallons, compared with 343 million gallons in 1964. About 98 percent of the 340 million gallons 
of xylene produced in 1965 was obtained from petroleum sources. 

Production of crude naphthalene in 1965 (including 347 million pounds of petroleum-derived 
naphthalene) amounted to 811 million pounds, compared with 740 million pounds in 1964. In 1965 
the output of creosote oil for wood preservation was 124 million gallons (100-percent creosote 
basis), compared with 113 million gallons in 1964. Production of road tar and tar (crude and re- 
fined) for other uses in 1965 was 85 million gallons, compared with 76 million gallons in 1964. 



TABLE 3. --Tar and tar crudes .■ Summary of U.S. production of specified products, average 1950-54, 

annual 1964 and 1965 

[Leaders are used where the reported data are accepted in confidence and may not be published 
or where no data were reported] 



quantity 



Average 
1950-54 



Increase, or 
decrease (-) 



1965 over 
1950-54 



1965 over 
1964 



Tar 1 

Benzene : 2 

Tar distillers 3 

Coke-oven operators 

Petroleum operators 

Total - 

Toluene: 

Tar distillers 

Coke-oven operators 

Petroleum operators 

Total 

Xylene: 

Tar distillers 

Coke-oven operators 

Petroleum operators 

Total — 

Naphthalene, crude: 

Solidifying at less than 79° C. 5 — 
Petroleum naphthalene, all grades- 
Total 



,000 gal- 
,000 gal- 
,000 gal- 
,000 gal- 

,000 gal- 
,000 gal- 
,000 gal- 
,000 gal- 

,000 gal- 
,000 gal- 
,000 gal- 
,000 gal- 

,000 lb— 
,000 lb— 
,000 lb- 



Creosote oil (Dead oil) 6 1,000 



876,070 

41,389 
163,356 
46,635 



7,497 
32,981 
80,725 



1,373 

9,028 

78, 188 



8,589 
307,537 



307,537 
109, 946 



118, 944 
611, 294 



802,738 



121,917 
704, 993 



730,238 



25,521 
469,519 



826,910 



24,816 
524,013 



7,119 

'336,079 



343,198 



425,690 
314,664 



548, 829 



6,741 
1 333,063 



463,980 
346, 620 



810, 600 



-25.4 
1,411.7 



-24.8 
549.1 



-25.3 
326.0 



283.6 



163.6 
1.0 



2.5 
15.3 
13.2 



-.9 
-1.0 

9.0 
10.2 
9.5 



Includes data for oil-gas, water-gas, and gas-retort tar reported to the American Gas Association for 1950-54 
only, and for coal tar reported to the Division of Bituminous Coal, U.S. Bureau of Mines. 

2 Includes data for motor-grade benzene in 1950-54. Production in recent years has been negligible. 

3 Includes data for benzene produced from imported crude light oil. 

* Includes data for material produced for use in blending motor fuels. Statistics are not comparable with monthly 
figures, which included some o-xylene now shown on table 7A. 

5 Figures include production by tar distillers and coke-oven operators and represent combined data for the com- 
mercial grades of naphthalene to avoid disclosure of the operations of individual companies. Because of conversion 
between grades, the figures may include some duplication. 

6 Includes data for creosote oil produced by tar distillers and coke-oven operators and used only in wood preserv- 
ing. Data for production of creosote oil in coal-tar solution have been excluded because the figures for 1950-54 
are not comparable with the figures for 1964 and 1965. Production figures for 1950-54 are for the distillate sold or 
consumed as such, and for 1964 and 1965 the production of the distillate is on a 100-percent-creosote basis. 



Statistics on production and sales of benzene, toluene, and xylene by tar distillers cannot be shown because publication would reveal the 
operations of individual companies. 



TAR CRUDES 
TABLE 4A. -- Tar crudes.- U.S. production and sales, 1965 

[Listed below are all tar crudes for which any reported data on production or sales may be published. (Leaders are 
used where the reported data are accepted in confidence and may not be published or where no data were reported.) 
Table 4B in pt. Ill lists separately all products for which data on production or sales were reported and iden- 
tifies the manufacturers reporting to the U.S. Tariff Commission] 



of 
quantity 



Quantity 



Unit 
value 1 



Crude light oil: Coke-oven operators 

Intermediate light oil: Coke-oven operators 

Light-oil distillates: 
Benzene, specification and industrial grades, 

total 2 3 -■ 

Coke-oven operators 

Petroleum operators 

Toluene, all grades, total 2 3 

Coke-oven operators 

Petroleum operators 

Xylene, total 2 3 

Coke-oven operators 

Petroleum operators 

Solvent naphtha, total 

Tar distillers 

Coke-oven operators 

Other light-oil distillates: Coke-oven operators- 
Naphthalene, crude (tar distillers and coke-oven 

operators) , total* 

Solidifying at— 

Less than 74° C 

74° C. to less than 79° C 

Crude tar- acid oils: 

Tar distillers 

Coke-oven operators 

Creosote oil (Dead oil) (tar distillers and coke- 
oven operators) (100$ creosote basis), total 5 — 

Distillate as such ( 100$ creosote basis) 

Creosote content of coal-tar solution (100$ 

creosote basis) 

All other distillate products 7 

Tar, road, and tar ( crude and refined) for other 

uses 8 

Pitch of tar: 

Hard (water softening point above 160° F. ) 

Other 9 



1,000 gal- 
1,000 gal- 



1,000 gal— 

1,000 gal— 

1,000 gal— 

1,000 gal— 

1,000 gal— 

1,000 gal— 

1,000 gal— 

1,000 gal— 

1,000 gal— 

1,000 gal— 

1,000 gal— 

1,000 gal— 

1,000 gal— 



1,000 lb— 
1,000 lb— 



1,000 gal- 
1,000 gal- 



1,000 gal— 

1,000 gal— 

1,000 gal— 

1,000 gal— 

1,000 gal— 

1,000 tons- 

1,000 tons- 



262,701 
4,939 



826,910 

121,917 

704, 993 

548,829 

24,816 

524,013 

339,804 

6,741 

333,063 

10,016 

4,596 

5,420 

7,995 



463,980 



69,537 
1,815 



510,842 

127,449 

383,393 

324,517 

25,087 

299,430 

201,743 

6,913 

194,830 

7,992 

3,41/4 

4,578 



1,000 
dollars 
9,441 
183 



123,282 

29,652 

93,630 

53,882 

4,622 

49,260 

36,734 

1,523 

35,211 

1,622 

753 

869 

448 



$0.14 
.10 



.24 
.23 
.24 
.17 
.18 
.16 
.18 
.22 
.18 
.20 
.22 
.19 
.09 



81,856 
382, 124 



321 
28,027 



123,602 



111,087 

12,515 

31,445 

84,941 

916 
1,088 



76,963 



317 
28,635 



107,452 



95,927 
11,525 



79,818 



594 
487 



1A3 
4,365 



22,868 



19,268 
3,600 



11,896 



22,638 
16,753 



.20 
.31 



38.11 
34.40 



1 Unit value per gallon, or ton, as specified. 

2 Data reported by tar distillers are not included because publication would disclose the operations of individual 
companies. Production of toluene and xylene by tar distillers decreased in 1965, compared with 1964; production of 
benzene increased. The annual production statistics for petroleum operators on benzene, toluene, and xylene are not 
comparable with the combined monthly production figures, due to fiscal year revisions. 

3 Includes data for material produced for use in blending motor fuels. 

* Statistics represent combined data for the commercial grades of naphthalene. Because of conversion of naphtha- 
lene from one grade to another, the figures may include some duplication. 

5 Statistics include only data for creosote oil sold for, or used in, wood preserving. In 1965, production of 
creosote in coal-tar solution (100$ solution basis) amounted to 21,360 thousand gallons; sales were 19,635 thousand 
gallons, valued at 3,600 thousand dollars, with a unit value of $0.18 per gallon. 

6 Includes value of coal tar used in preparing creosote in coal-tar solution. 

7 Includes data for pyridine crude bases, crude cresylic acid, dry distilled tar acid, and neutral oils produced 
by tar distillers, and for crude sodium phenolate produced by coke-oven operators. 

8 Tar (crude and refined) for other uses includes data on tar used for paint, pipe covering, saturating, and 
other uses. 

9 Includes soft and medium pitch of tar (water softening points less than 110° F. , and 110° F. to 160° F. ASTM 
D61-24), pitch of tar coke, and pitch emulsion. 

Note. — Statistics for materials produced in coke and gas- retort ovens are compiled by the Division of Bituminous 
Coal, U.S. Bureau of Mines, Department of the Interior. Statistics for materials produced in tar and petroleum 
refineries are compiled by the U.S. Tariff Commission. 



4 SYNTHETIC ORGANIC CHEMICALS, 1965 

Some of the products included in the statistics in table 4A are derived from other products 
for which data are also included in the table. The statistics, therefore, involve considerable 
duplication, and for this reason no group totals or grand totals are given. It is estimated that 
after duplication has been eliminated insofar as possible the net value of the output of these 
products and of tar burned as fuel was $500 million in 1965, compared with $460 million in 1964 
and $406 million in 1963. 

Crude Products From Petroleum and Natural Gas for Chemical Conversion 

Crude products that are derived from petroleum and natural gas are related to the inter- 
mediates and finished products made from such crudes in much the same way that crude prod- 
ucts derived from the distillation of coal tar are related to their intermediates and finished 
products. Many of the crude products derived from petroleum are identical with those derived 
from coal tar (e.g., benzene, toluene, and xylene). Considerable duplication exists in the statis- 
tics on the production and sales of petroleum crudes because some of these crude chemicals 
are converted to other crude products derived from petroleum and because data on some pro- 
duction and sales are reported at successive stages in the conversion processes (see table 5A 3 ). 
Notwithstanding these duplications, the statistics are sufficiently accurate to indicate trends in 
the industry and to serve as a basis for general comparison. Many of the crude products for 
which data are included in the statistics may be used either as fuel or as basic materials from 
which to derive other chemicals, depending on prevailing economic conditions. In this report, 
every effort has been made to exclude data on materials that are used as fuel. However, data 
are included on toluene and xylene which are not used directly as fuel but in blending aviation 
and motor- grade gasolines. 

TABLE ^A..— Crude products from petroleum and natural gas for chemical conversion: U.S. production 

and sales, 1965 

[Listed below are the crude products from petroleum and natural gas for chemical conversion for which any reported 
data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence 
and may not be published or where no data were reported.) Table 5B in pt. Ill lists separately all products from 
petroleum and natural gas for chemical conversion for which data on production or sales were reported and identi- 
fies the manufacturer of each ] 



Production 



Quantity 



Unit 
valued- 



Grand total 

ARQMATICS AND NAPHTHENES 2 
Total 

Alkyl aromatics, distillates, and solvents — 

Benzene (1° and 2°), total 

Benzene, 1° 

Benzene, 2° 

Naphthalene, all grades 

Naphthenic acids 

Toluene, all grades, total 

Nitration grade, 1° 

Pure commercial grade, 2° 

Solvent grade, 90$ 

All other 3 — 

Xylenes, mixed, total 

3° - 

All other 3 

All other aromatics and naphthenes* 

See footnotes at end of table. 



1,000 
pounds 
44,509,671 



1,000 
pounds 
23,402,442 



1,000 
dollar. 



pound 



$0,030 



214,832 



1,878,248 
5,202,849 



4,139,487 
1,063,362 



346, 620 
24,365 



3,809,575 



1,877,189 
2,829,440 



21,873 
93,630 



.025 
.012 
.033 



269, 845 
17,217 



10,643 
1,805 



2,375,829 
177,635 
124,855 

1,131,256 

2,401,383 



.039 
.105 



■ 023 
.023 



503, 673 
1,404,723 



444,864 
1,956,519 



100,350 



535J25D 

969,463 



10, 532 
35,211 



11,625 
23,586 



.025 
TTJ2T 
.024 



See also table 5B, pt, HI, which lists these products alphabetically and identifies the manufacturers. 



CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS 



TABLE 5A. - 



- Crude products from petroleum and natural gas for chemical conversion.- U. S. production 
and sales, i965--Continued 



Unit 
value 1 



ALIPHATIC HYDROCARBONS 

Total 

C 2 hydrocarbons, total 

Acetylene 5 

Ethane 

Ethylene 

C 3 hydrocarbons, total 

Propane 

Propylene 

C 4 hydrocarbons, total 

1,3-Butadiene, grade for rubbers (elastomers) 

Butadiene and butylene fractions 

n-Butane 

1-Butene and 2-butene mixture 6 

Isobutane 

Isobutylene 

All other 7 

C 5 hydrocarbons 8 

All other aliphatic hydrocarbons and derivatives, total. 

Alpha olefins 9 

Diisobutylene (Diisobutene) 

Heptenes, mixed 

Nonene (Tripropylene) 

Polybutene 1 " 

Tetrapropylene-- 

Hydrocarbon derivatives 11 

All other 12 



30,746,281 



14,757,498 



465,208 
1, 546, 660 
9,569,885 



4,231,286 
3,740,835 



7,182,182 



2,685,359 
486, 177 
1,879,011 
1,067,303 
516,726 
270,866 
276,740 

456,523 

3,553,702 



125,536 
33,151 
279, 751 
244, 257 
240,482 
462,255 
32, 847 
2,135,423 



663,130 
2,714,873 



3,135,301 
1, 884, 641 



4,568,676 



1,670,936 
102,213 
1,022,371 
1,080,716 
285,391 
167, 671 
239,378 

95,927 



115,065 
26,689 
172,782 
161, 009 
202, 974 
359,033 
20,405 
636,993 



1,000 

dollars 

489,856 



5,781 

109,816 



29,774 
39, 567 



237, 143 



171,807 
4,251 
12,295 
30,630 
3,962 
8,448 
5,750 

2,938 
64,837 



5,489 
1,942 
6,483 
4,755 

12,892 
9,102 
6,101 

18,073 



$0,033 



.009 
.040 



.014 
.009 
.021 



.103 
.042 
.012 
.028 
.014 
.050 
.024 



.038 
.048 
.073 
.038 
.030 
.064 
.025 
.299 
.028 



Calculated from rounded figures. 

2 The chemical raw materials designated as aromatics are in some cases identical with those obtained from the dis- 
tillation of coal tar. However, the statistics given in the table above relate only to such materials as are derived 
from petroleum and natural gas. Statistics on aromatic chemicals from all sources are given in table 4A, "Tar Crudes. ' 

3 Includes toluene and xylene used as solvents, as well as that which is blended in aviation and motor gasolines. 
* Includes data for 90-percent benzene, crude cresylic acid, sodium cresylate, sodium carbolate and phenate, and 

miscellaneous cyclic hydrocarbons. 

5 Production figures on acetylene from calcium carbide for chemical synthesis are collected by the U. S. Bureau of 
the Census. 

6 The statistics represent principally the butene content of crude refinery gases from which butadiene is manu- 
factured. 

7 Includes data for 1-butene, 2-butene, mixed butylenes, and mixed olefins. 

8 Includes data for isoprene, pentanes, pentenes, and C 5 hydrocarbon mixtures. 

9 Includes data for the following molecular weight ranges: C6-C7, C 8 -C 10 , C 1:L -Ci5, Bn ^ Ci6-C2o- 

10 Includes compounds having a molecular weight of 3,000 or less. 

11 Includes data for di-tert-butyldisulfide and miscellaneous mercaptans. 

12 Includes data for hexane, heptane, methane, propane-propylene mixture, octanes, 1-dodecene, eicosane, and hydro- 
carbon mixtures. 



The output of crude products derived from petroleum and natural gas as a group amounted 
to 44,510 million pounds in 1965, or 11.7 percent more than the 39,862 million pounds reported 
for 1964. The larger output in 1965 is accounted for chiefly by increased production of benzene, 
toluene, ethylene, and propane. Sales of crude chemicals from petroleum in 1965 were 23,402 
million pounds, valued at $705 million, compared with 20,465 million pounds, valued at $619 
million, in 1964. 

The output of all aromatic and naphthenic products amounted to 13,763 million pounds in 
1965, compared with 12,574 million pounds in 1964. Sales in 1965, which amountedto 8,645 
million pounds, valued at $215 million, were 1,066 million pounds larger, and valued at $35 mil- 
lion more, than those in 1964. Naphthalene was produced from petroleum sources in substan- 
tially greater quantities in 1965 than in 1964. The output of l c and 2° benzene from petroleum 



6 SYNTHETIC ORGANIC CHEMICALS, 1965 

amounted to 5,203 million pounds in 1965--15.3 percent more than the 4,511 million pounds pro- 
duced in 1964. The output of toluene in 1965 was 3,810 million pounds-- 11.6 percent more than 
the 3,413 million pounds produced in 1964. Production of xylene was 2,401 million pounds in 1965, 
compared with 2,423 million pounds in 1964. These figures include toluene and xylene used in 
blends in aviation and motor-grade gasolines. The output of naphthenic acids amounted to 24 
million pounds in 1965, compared with 30 million pounds produced in 1964. 

Production of all aliphatic hydrocarbons and derivatives from petroleum and natural gas was 
30,746 million pounds in 1965, compared with 27,288 million pounds in 1964. Sales of these prod- 
ucts were 14,757 million pounds, valued at $490 million, in 1965, compared with 12,887 million 
pounds, valued at $439 million, in 1964. The statistics on production of acetylene (table 5 A) in- 
clude only acetylene produced from natural gas and used as a raw material in the production of 
other chemicals. Total production of acetylene for chemical synthesis is reported to the U.S. 
Bureau of the Census. In 1965, production of acetylene from all sources except that produced by 
railroad shops, shipyards, and small establishments using portable generators, amounted to 
1,141 million pounds. Production of ethylene was 9,570 million pounds in 1965, or 10.7 percent 
more than the 8,641 million pounds produced in 1964. The output of propane and propylene was 
7,972 million pounds in 1965--10.3 percent more than the 7,227 million pounds produced in 1964. 
Production of 1,3 -butadiene, one of the principal ingredients of S-type synthetic rubber, was 
2,685 million pounds in 1965, compared with 2,491 million pounds in 1964. The output of 1,3-buta- 
diene in 1965--7.8 percent more than that in 1964--was the largest on record. 

The following tabulation shows the number of companies that reported production of organic 
chemical crudes in 1965: 

Number 

of 
Chemical group companies 

Tar crudes 14 

Petroleum crudes 72 



PART II. PRODUCTION AND SALES OF INTERMEDIATES AND 
FINISHED SYNTHETIC ORGANIC CHEMICALS, BY GROUPS 



General 



On the basis of their principal uses, the synthetic organic chemicals covered in this report 
are classified either as intermediates or as finished products. Finished products, in turn, are 
grouped as follows: Dyes, synthetic organic pigments, medicinal chemicals, flavor and perfume 
materials, plastics and resin materials, rubber-processing chemicals, elastomers (synthetic 
rubbers), plasticizers, surface-active agents, pesticides and other organic agricultural chemi- 
cals, and miscellaneous synthetic organic chemicals. Most of these groups are further sub- 
divided, according to chemical classes, into cyclic and acyclic compounds. As most of the in- 
termediates are used in the manufacture of finished products, aggregate figures that cover both 
intermediates and finished products necessarily include considerable duplication. 

Total production of synthetic organic chemicals (intermediates and finished products com- 
bined) in 1965 was 88,864 million pounds, or 12.9 percent more than the output of 78,678 million 
pounds reported for 1964 (see table 6). Sales of synthetic organic chemicals in 1965 amounted to 
46,807 million pounds, valued at $9,021 million, compared with 42,766 million pounds, valued at 
$8,458 million, in 1964. Production of all cyclic products (intermediates and finished products 
combined) in 1965 totaled 28,229 million pounds, or 10.7 percent more than the 25,506 million 
pounds produced in 1964. The output of acyclic organic chemicals in 1965 amounted to 60,635 
million pounds--14.0 percent more than the 53,172 million pounds reported for 1964. 



: 



TABLE 6. — Synthetic organic chemicals.- Summary of U.S. production and sales of intermediates and finished 
products, average 1957-59, annual 1964 and 1965 

[Production and sales in thousands of pounds; sales value in thousands of dollars] 



Average 
1957-59 



Increase, or decrease (-) 



1965 over 
1957-59 



1965 over 
1964 



Organic chemicals, cyclic and acyclic, 
grand total: 

Production 

Sales 

Sales value 



Cyclic, total: 

Production 

Sales- --- 

Sales value — 

Acyclic, total: 

Production 

Sales 

Sales value--- 



1. Inte 



Cycli 



Production — 

Sales 

Sales value - 



2. Dyes, Cycli 



Production — 

Sales 

Sales value- 



3. Synthetic Organic Pigments, Cycli 



Production- - 

Sales 

Sales value - 



45,598,853 

23,744,812 

5 , 743 , 764 



14,381,651 
8,829,037 
2,785,100 

31,217,202 
14,915,775 
2,958,664 



7,343,167 

2,919,264 

481,920 



150,830 
141,731 
182,513 



38,603 
30,215 
58,648 



78,677,699 

42,766,420 

8,457.909 



25.505,853 
15,241,685 
3,890,571 



53,171,846 
27,524,735 
4,567,338 



14,895,573 

6,470,072 

711, 119 



184,387 
178,273 
264,023 



44,053 
35,081 
84,131 



88,864,092 

46,807,057 

9,020,540 



28,229,128 
16,499, 1B9 
3,855,492 



60,634,964 

30,307,868 

5,165,048 



16,865,164 

7,551,210 

814,383 



207, 193 
189,965 
292,284 



48,045 
38,024 
93,635 



94.9 
97.1 
57.0 



94.2 
103.2 
74.6 



129.7 
158.7 
69.0 



37.4 
34.0 
60.1 



24.5 
25~8 
59.7 



12.9 
9.4 



10.7 
8.2 
-.9 



12.4 
6.6 
10.7 



9.1 
8.4 
11.3 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 6. — Synthetic organic chemicals: Summary of U.S. production and sales of intermediates and finished 
products, average 1957-59, annual 1964 and 1 965- -Continued 

[Production and sales in thousands of pounds; sales value in thousands of dollars] 



Average 
1957-59 



Increase, or decrease (-) 



1965 over 
1957-59 



4. Medicinal Chemicals 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic : 

Production 

Sales 

Sales value 

5. Flavor and Perfume Materials 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 

6. Plastics and Resin Materials 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 

7. Rubber -Processing Chemicals 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic : 

Production 

Sales 

Sales value 

«. Elastomers (Synthetic Rubbers) 

Cyclic : 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 

9. Plasticizers 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic : 

Production 

Sales 

Sales value 

See footnote at end of table. 



70,654 
54,151 
535,297 

31,592 
28,738 
35,660 



27,312 
22,446 
33,903 

19,033 
19,958 
21.912 



2,278,862 

1,900,032 

518,501 

2,628,779 

2,438,853 

864,523 



159,182 
115,704 
74,479 

29,150 
22,127 
1/4,289 



1,938,732 

1,726,757 

404,897 

521,811 
509,262 
199,627 



348,210 

297,423 

83,509 

118,118 
100,984 
38,772 



97,579 

76,946 

612,233 

46,511 
41,732 
33,459 



49,563 
41,235 
56,571 

41,007 
38,802 
27, 163 



3,915,046 

3,256,105 

777,342 

6,188,018 
5,470,616 
1,342,942 



222,461 
161,660 
108,656 

38,095 
22,567 
14,371 



2,332,436 

1,961,181 

450,913 

1,088,782 
996,403 
358,989 



717,624 
689,647 
119,565 

233,784 

215,240 

67,903 



100,040 

72,479 

321,158 

59,480 
56,569 
41,011 



53,223 
44,559 
56,800 

46,001 
43,144 
28,180 



4,452,975 

3,689,722 

873,501 

7,231,900 
6,363,044 
1,630,932 



211,403 
166,21/4 
109,204 

40,542 
27,504 
1/4,189 



2,300,092 

1,897,921 

442,722 

1,291,562 

1,143,242 

400,726 



798,741 
764,736 
133,044 

274,456 
256,887 
81,348 



i 1 ) 
( x ) 



t 1 ) 



1A1.7 

116.2 

28.6 



95.4 
94.2 



175.1 
160.9 



32.8 
43.7 
46.6 

39.1 
24.3 



18.6 
9.9 
9.3 

147. 5 
124.5 
100.7 



129.4 
157.1 
59.3 

132.4 

154.4 
109.8 



GENERAL 

TABLE 6,-Syntketic organic chemicals: Summary of U.S. production and sales of intermediates and finished 
products, average 1957-59, annual 1964 and 1965 — Continued 

[Production and sales in thousands of pounds; sales value in thousands of dollars] 



Average 
1957-59 



Increase, or decrease (-) 



1965 over 
1957-59 



1965 over 
1964 



10. Surface-Acti 



Cyclic: 

Production — 

Sales 

Sales value- 
Acyclic : 

Production — 

Sales 

Sales value - 



Organ 

Cyclic : 

Production — 

Sales 

Sales value - 

Acyclic : 

Production-- 

Sales 

Sales value- 



Agricultu 



and Othe 
il Chemii 



- 



Cyclic : 

Production- 
Sales 

Sales value- 
Acyclic: 

Production — 

Sales 

Sales value- 



852,314 
800,432 
127.936 

502,715 
432,135 
113,215 



440,384 
375,627 
150,837 

105,080 
91,938 
49,049 



733,401 
445,252 
132,660 

27,260,924 

11,271,780 

1,621,617 



1,347,809 

1,245,176 

165,132 

770,879 
654,754 
185,010 



584,698 
522,691 
316,556 

198,051 
169,664 
110,555 



1,114,624 
603,618 
224,330 

44,566,719 
19,914,957 
2,426,946 



1,371,320 

877,202 

96,153 

1,799,158 
820,660 
204,035 



682,671 
582,344 
377,858 

194,526 
181,561 
119,208 



1,138,261 
624,813 
244,750 

49,697,339 

21,415,257 

2,645,419 



55.0 
55.0 
150.5 

85.1 
97.5 
143.0 



55.2 
40.3 
84.5 

82.3 

90.0 



16.8 
11.4 
19.4 

-1.8 
7.0 
7.8 



2.1 
3.5 
9.1 

11.5 
7.5 
9.0 



1 Data for 1965 are not comparable with those for 1964; for details see the appropriate tables. 

The following tabulation shows, by chemical groups, the number of companies that reported 
production in 1965 of one or more of the chemicals included in the groups listed in table 6: 



Number 
Chemical group oj 

comj'atne 

Intermediates 213 

Dyes 53 

Synthetic organic pigments 37 

Medicinal chemicals 111 

Flavor and perfume materials 55 

Plastics and resin materials 320 



Numbe r 
Chemical group of 

cvmpanie 
Rubber-processing chemicals 31 

Elastomers (synthetic rubbers) 29 

Plasticlzers 58 

Surface-active agents 188 

Pesticides and other organic agricultural chemicals 85 

Miscellaneous chemicals 328 



10 



SYNTHETIC ORGANIC CHEMICALS, 1965 
Cyclic Intermediates 



Cyclic intermediates are synthetic organic chemicals derived principally from coal-tar 
crudes produced by destructive distillation (pyrolysis) of coal and from petroleum and natural 
gas. Most cyclic intermediates are used in the manufacture of more advanced synthetic organic 
chemicals and finished products, such as dyes, medicinal chemicals, elastomers (synthetic 
rubbers), pesticides, and plastics and resin materials. Some intermediates, however, are sold 
as end products without further processing. For example, refined naphthalene may be used as a 
raw material in the manufacture of 2-naphthol or of other more advanced intermediates, or it 
may be packaged and sold as a moth repellent or as a deodorant. In general, the way in which 
the greater part of the output of a given chemical is consumed determines its use classification 
in this report. Table 7A gives statistics on production and sales of cyclic intermediates in 
1965. Individual statistics given in the table represent more than 85 percent of the total quantity 
of intermediates produced. Since many of the intermediates included in the statistics represent 
successive steps in production, the totals necessarily include considerable duplication. In 1965 
nearly half of the total output of cyclic intermediates was sold; the rest was consumed chiefly 
by the producing plants in the manufacture of more advanced intermediates and finished 
products. 

Total production of cyclic intermediates in 1 965 — 1 6,865 million pounds--was the largest on 
record, and was 13.2 percent larger than the output of 14,896 million pounds reported for 1964. 
The larger output of cyclic intermediates in 1965 was attributable to increased demand by the 
chemical products industries, particularly those industries that produce dyes, pesticides, plas- 
ticizers, and plastics and resin materials. Sales of cyclic intermediates in 1965 amounted to 
7,551 million pounds, valued at $814 million, compared with 6,470 million pounds, valued at $711 
million, in 1964. In terms of quantity, sales of cyclic intermediates in 1965 were 16.7 percent 
larger than those in 1964 and in terms of value, 14.5 percent larger. 



TABLE 7A. — Cyclic intermediates : U.S. production and sales, 1965 

[Listed below are all cyclic intermediates for which any reported data on production or sales may be published. 

(Leaders are used where the reported data are accepted in confidence and may not be published or where no data were 
reported.; Table 7B in pt. Ill lists alphabetically all cyclic intermediates for which data on production or sales 
were reported and identifies the manufacturer of each J 



Production 



Quantity 



Unit 
value 1 



Total 

Acetanilide, tech 

H-Acetylsulfanilyl chloride 

Alkylbenzenes 2 

4' -Aminoacetanilide (Acetyl-p-phenylenediaraine) 

5-Amino-2-(p-aminoanilino)benzenesulfonic acid 

2-(p-Aminoanilino)-5-nitrobenzenesulfonic acid 

1-Aminoanthraquinone and salt 

2-Aminoanthraquinone and salt 

6-Amino-3,4'-azodibenzenesulfonic acid 

1 -Amino -4-benzamidoanthraqui none 

l-Amino-5-benzamidoanthraquinone 

7-(p-Aminobenzamido)-4-hydroxy-2-naphthalenesulfonic acid 

2-Amino-p-benzenedisulfonic acid [S03H=l] 

l-Amino-4-bromo-9,10-dihydro-9,10-dioxo-2-anthracenesulfonic acid 

and sodium salt 

l-Amino-2-bromo-4-hydroxyanthraquinone 

l-Amino-2-bromo-4-p-toluidinoanthraquinone 

l-Amino-5-chloroanthraquinone 

o-(3-Amino-4-chlorobenzoyl)benzoic acid 

See footnotes at end of table. 



1.000 
pounds 

16,865,164 



3,672 

3,313 

624,894 

602 

21 

47 

1,547 

1,146 

59 

95 

125 



187 
204 
28 
105 
116 



1.000 

pounds 

7,551,210 



1.000 
dollars 

814,383 



583,634 



55,537 



1 See also table 7B, pt. Ill, which lists these products alphabetically and identifies the manufacturers, and table 23 in the appendix, which 
shows imports of intermediates and related products during 1964 and 1965. 



CYCLIC INTERMEDIATES 
TABLE 7A. — Cyclic intermediates ; U.S. production and sales, 1965 — Continued 



Production 



Unit 
value 1 



3-Amino-5-chloro-2-hydroxybenzenesulfonic acid 

2-Amino-5-chloro-p-toluenesulfonic acid [S0 3 H=l] 

6-Amino-4-chloro-m-toluenesulfonic acid [S0 3 H>l] 

l-Amino-2,4-dibromoanthraquinone 

l-Amino-9,10-dihydro-9,10-dioxo-4-p-toluenesulfonamido-2- 

anthracenesulfonic acid, sodium salt 

4-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid (H acid), 

monosodium salt 

4-Amino-3-hydroxy-l-naphthalenesulfonie acid (1,2,4-acid) 

6-Amino-4-hydroxy-2-naphthalenesulfonic acid (Gamma acid), 

sodium salt 

7-Amino-4-hydroxy-2-naphthalenesulfonic acid (J acid), sodium salt- 

N-(4-Aiidno-3-methoxy-l-anthraquinonyl)-p-toluene sulfonamide 

4'-Amino-N-methylacetanilide 

2-Amino-l,5-naphthalenedisulfonic acid 

3-Amino-l,5-naphthalenedisulfonic acid (C acid) 

6-Amino-l,3-naphthalenedisulfonie acid (Amino I acid) 

7-Amino-l,3-naphthalenedisulfonic acid (Amino G acid) 

4-Amino-l-naphthalenesulfonic acid (Naphthionic acid) 

5-Amino-2-naphthalenesulfonic acid (1,6-Cleve's acid) 

5(and 8)-Amino-2-naphthalenesulfonic acid (Cleve's acid, mixed) 

6-Amino-2-naphthalenesulfonic acid (Broenner's acid) 

8-Amino-l-naphthalenesulfonic acid (Peri acid) 

8-Amino-2-naphthalenesulfonic acid (1,7-Cleve's acid) 

8-Amino-2-naphthol 

2-Amino-5-nitrobenzenesulfonic acid [S0 3 H=l] 

2-Amino-4-nitrophenol 

3'-Aminooxanilic acid 

p-[(p-Aminophenyl)azo]benzenesulfonic acid 

4-Amino-m-toluenesulfonic acid [ S03H=l] 

6-Amino-m-toluenesulfonic acid [S0 3 H=1] 

5-Amino-2-p-toluidinobenzenesulfonic acid 

Aniline (Aniline oil) 

7-Anilino-4-hydroxy-2-naphthalenesulfonic acid (Phenyl J acid) 

Anilinomethanesulfonic acid and salt 

8-Anilino-l-naphthalenesulfonic acid (Phenyl peri acid) 

o-Anisidine • 

o-Anisidinomethanesulfonic acid 

Anthranilic acid (o-Aminobenzoic acid) 

Anthra[l, 9-cd]pyrazol-6(2H)-one (Pyrazoleanthrone) 

N,N'-(l,5-Anthraquinonylene)dianthranilic acid 

4',4'"-AzobisL4-biphenylcarboxylic acid] 

Benzaldehyde, tech 

l-Benzamido-5-chloroanthraquinone 

7H-Benz[de]anthracen-7-one ( Benzanthrone ) 

Benzidine hydrochloride and sulfate 

Benzoic acid, tech 

o-Benzoylbenzoic acid 

[3,3'-Bianthra[l,9-cd]pyrazole]-6,6'-(2H,2'H)dione (Pyrazole- 
anthrone yellow) 

[4,4'-Bi-7H-benz[de]anthracen]-7,7'-dione 

l,4-Bis[l-anthraquinonylamino]anthraquinone 

4,4'-Bis[dimethylamino]benzophenone (Mlchler's ketone) 

3-Bromo-7H-benz [de] anthracen-7-one (3-Bromobenzanthrone) 

l-Bromo-4-(methylamino)anthraquinone 

p-tert-Butylphenol 

1-Chloroanthraquinone 

2-Chloroanthraquinone 

Chlorobenzene, mono- 

o-(p-Chlorobenzoyl)benzoic acid 

l-Chloro-2,4-dinitrobenzene (Dinitrochlorobenzene) 

6-Chlorometanilic acid 

l-Chloro-2-methylanthraquinone 

2-Chloro-4-nitroaniline_ (o-Chloro-p-nitroaniline) 

4-Chloro-2-nitroaniline (p-Chloro-o-nitroaniline) 



1.000 
pounds 
13 
1,585 

1,047 
370 



4,723 
1,602 



22 

60 

212 

1,187 

1,123 

145 

136 

229 

135 

790 

165 

65 

48 

137 

19 

196 

266 

207 

31 

195,547 

43 

277 

417 

1,585 

347 

712 

16 

26 

36 

3,979 

115 

2,256 

1,610 

16,190 



107 
239 
43 

184 

1,250 

546,292 

1,864 

8,107 

24 

140 

448 

461 



1,000 
pounds 



1,000 
dollars 



$1.19 



2,929 
184 



2,817 



76,277 



4,168 



1,160 
8,461 



15,276 



82,159 

362 

1,659 



.96 

.74 

1.60 



,959 



1,723 



1,183 
1,522 



3,152 



5,071 
232 
277 



1.02 
.18 



.64 
.17 



See footnotes at end of table. 



12 SYNTHETIC ORGANIC CHEMICALS. 1965 

TABLE TA.— Cyclic intermediates.- U.S. production and sales , 1965- -Continued 



Production 



l-Chloro-5-nitroanthraquinone 

l-Chloro-8-nitroanthraquinone 

l-Chloro-2-nitrobenzene (Chloro-o-nitrobenzene ) - 
l-Chloro-4-nitrobenzene (Chloro-p-nitrobenzene ) - 

4-Chlora-3-nitrobenzenesulfonamide 

2-Chloro-5-nitrobenzenesulfonic acid 

4-Chloro-3-nitrobenzenesulf onyl chloride 

o-(4-Chloro-3-nitrobenzoyl)benzoic acid 

(p-Chlorophenyl)acetonitrile 

K -Chlorotoluene (Benzyl chloride) 

4-Chloro-o-toluidine [NH2=l] and hydrochloride-- 
5-Chloro-o-toluidine [NH2=1] and hydrochloride - - 

N-[(5-Chloro-o-tolyl)azo]sarcosine 

[(4-Chloro-o-tolyl)thio] acetic acid 



Cresols, total 3 

m-, o-, and p-Cresols 

(m,p)-Cresol (from coal tar and petroleum) - 
(o,m,p)-Cresol 4 

Cresylic acid, refined, total 3 

From coal tar 

From petroleum 



Cumene 

Cyclohexane 

Cyclohexanol 

Cyclohexanone 

Cyelohexylamine 

1,4-Diaminoanthraquinone 

1,5-Diaminoanthraquinone 

2,6-Diaminoanthraquinone 

l,4-Diamino-2,3-dihydroanthraquinone 

4,4'-Diamino-2,2'-stilbenedisulfonic acid 

4,5'-Dibenzamido-l,l'-iminodianthraquinone 

1,5-Dibenzoylnaphthalene 

3,9-Dibromo-7H-benz[de]anthracen-7-one 

2,5-Dichloroaniline and hydrochloride [NH 2 =l] 

1,5-Dichloroanthraquinone 

o-Dichlorobenzene 

p-Dichlorobenzene 

3,3'-Dichlorobenzidine base and salts 

2 , 5-Dichloro-4- ( 3-methyl-5-oxo-2-pyrazolin-l-yl ) benzenesulf onic 



acid- 



2,6-Dichloro-4-nltroanillne 

l,4-Dichloro-2-nitrobenzene (Nitro-p-dichlorobenzene) 

2,5-ffl.chlorosulfanilie acid [s0 3 H=l] 

p-(Diethylamino)benzaldehyde 

N,N-Diethylaniline 

9,10-Dihydro-l,4-dihydroxy-9,10-dioxo-2-anthracenesulfonic acid 
(2-Quinizarinsulfonic acid) 

9,10-Dihydro-9,10-dioxo-l,5-anthracenedisulfonic acid and disodium 
salt 

9,10-Dihydro-9,10-dioxo-l,8-anthracenedisulfonic acid, 

potassium salt ; 

9,10-Dihydro-9,10-dioxo-2,6-anthraeenedisulfonic acid and salt 

9,10-Dihydro-9,10-dioxo-l-anthracenesulfonic acid and salt 

9,10-Dihydro-5-nitro-9,10-dioxo-l-anthracenesulfonic acid 

9,10-Dihydro-l-nltro-9,10-dloxo-2-anthroic acid 

1,4-Dihydroxyanthraqulnone (Quinizarin) 

1 , 5-Dihydroxyanthraquinone (Anthrarufin) 

1,8-Dihydroxyanthraquinone (Qirysazin) 

2,6-Dihydroxyanthraquinone (Anthraflavic acid) 

l,8-Dihydroxy-4,5-dinitroanthraquinone (4, 5-Dinitrochrysazin ) 

16,17-Dihydroxyviolanthrone (Dihydroxydibenzanthrone) 



l.nnn 

pounds 

117 

56 

28,290 

109,757 

275 

89 

248 

U5 

34 

62,000 

62 

507 

181 



71,168 



innn 

pounds 



10,536 



32,533 
24,022 
14,613 

50,890 



21,969 
28,921 

663,009 
1,700,245 

321,651 

13,651 

64 

64 

179 

398 

4,784 

142 

231 

330 

123 

199 

41,115 

65,835 

2,677 

292 
259 
705 
110 
30 
1,721 



1,226 

412 
369 

3,066 
135 
29 

1,962 
233 
181 
9 
461 
337 



72,019 



29,268 
27,715 
15,036 

56,966 



21,998 

34, < 



1,474,742 

2,663 

12,269 

5,528 



37,199 
66,546 
2,331 



159 
1,732 



8,636 
3,032 
1,949 

6,192 



2,587 
3,605 



60,166 

679 

3,152 

1,386 



4,239 
5,789 
2,851 



See footnotes at end of table. 



CYCLIC INTERMEDIATES 
TABLE 1A. --Cyclic intermediates.- U.S. production and sales , 1965--Continued 



m-Dimethoxybenzene 

3,3'-Dimethoxybenzidine 

16,17-Dimethoxyviolanthrone 

N,N-Dimethylaniline 

N,N-Dimethyrbenzylamine 

2,2'-Dlmethyl-l,l'-bianthraquinone 

N,N-Dimethyl-p-nitrosoaniline 

p-(2,4-Dinitroanilino)phenol 

2,4-Dinitrophenol, tech 

4,4'-Dinitrostirbene-2,2'-disulfonie acid 

1,4-Di-p-toluidinoanthraquinone 

Divinylbenzene 

p-Dodecylphenol 

N-Ethylaniline, refined 

Ethylbenzene 5 

N-Ethyl-N-phenylbenzylamine 

o-Formylbenzenesulfonic acid (o-Sulfobenzaldehyde) 

p-Hydrazinobenzenesulfonic acid 

p-Hydroxybenzenesulfonic aoid (l-Phenol-4-sulfonic acid) 

p-Hydroxybenzoic acid, methyl ester 

p-Hydroxybenzoic acid, propyl ester 

4-Hydroxymetanilamide 

4-Hydroxymetanilic acid 

3-Hydroxy-2,7-naphthalenedisulfonic acid, disodium salt- 
6-Hydroxy-2-naphthalenesulfonic acid (Schaeffer's acid) 

sodium salt 

3-Hydroxy-2-naphthoic acid (B.O.N.) 

N-(7-Hydroxy-l-naphthyl)acetamide 

l,l'-Iminobis ,4-aminoanthraquinone] 

1,1' -Iminobis . 5-benzamidoanthraquinone] 

7,7'-Iminobis ; 4-hydroxy-2-naphthalenesulfonic acid]- 

1,1' -Iminobis[4-nitroanthraquinone] 

l,l'-Iminodianthraquinone (l,l'-Dianthrimide) 



Isocyanic acid derivatives, total 

Diphenylmethane 4,4'-diisocyanate (MDI) 

Toluene 2,4- and 2,6-diisocyanate (80/20 mixture) 
All other 



4,4'-Isopropylidenediphenol (Bisphenol A) 

Isoviolanthrone ( Isodibenzanthrone ) 

Leuco quinizarin (1,4,9,10-Anthratetrol)- 



o-Mercaptobenzoic acid 

Metanilic acid (m-Aminobenzenesulfonic acid) 

l-(Methylamino)anthraquinone 

4,4'-Methylenebis[N,N-dimethylaniline] (Methane base) 

4,4-'-Methylenedianiline 

p-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic acid 

4-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-m-toluenesulfonic acid [so 3 H=l] ■ 

3-Methyl-l-phenyl-2-pyrazolin-5-one (Developer Z) 

a-Jfethylstyrene 

Naphthalene, solidifying at 79°C. or above, refined from domestic 



crude- 

1,4,5,8-Naphthalenetetracarboxylic acid 

1-Naphthol (a -Naphthol) 

Naphth[l,2-d] [l,2,3]oxadiazole-5-sulfonic acid 

p-Nitroaniline 

4-Nitro-o-anisidine [NH2=l] 

5-Nitro-o-anisidine [NH 2 =l] 

Nitrobenzene 

m-Nltrobenzenesulfonic acid and sodium salt 

3-Nitro-l,5-naphthalenedisulfonic acid 

7(and 8)-Nitronaphth[l,2-d] [l,2,3]oxadiazole-5-sulfonic acid- 
p-Nitrophenol and sodium salt 



Production 



1.000 

567 

133 

11,041 

69 

90 

36 

935 

6,449 

202 

2,748 

11,021 

761 

3,022,730 

838 

271 

175 

6,310 

246 

102 

119 

106 

1,715 

348 
3,951 

24 
138 
45 
21 
103 
145 

184,262 

4,817 

146,578 

32,867 

97,197 

44 

88 

73,201 

17 

917 

175 

1,206 

1,086 

203 

6 

281 

13,553 

4,731 
57 

1,250 

12,478 

103 

108 

280,341 

2,293 

223 

1,084 

19,856 



Quantity 



1.000 
pounds 



6,003 
81 



1,762 



385 
580,332 



6,202 
256 
74 



776 
205 



162,739 



Unit 
value 1 



138,152 
24,587 



56,487 



59,285 



190 
536 



216 
8,480 



801 
6,883 



11,506 
2,397 



11,273 



1,000 
dollars 



1,296 

111 



1,403 



189 
23,614 



956 
375 
164 



703 
164 



61,648 



49,024 
12,624 



11,753 
15,064 



425 
303 



353 
941 



484 
2,988 



1,051 
1,023 



4,292 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1965 
TABLE 7A. — Cyclic intermediates : U.S. production and sales , 1965 — Continued 



Quantity 



Unit 

value 1 



5-Nitro-o-toluenesulf onic acid [ S0 3 H=l] ' 

3-Nitro-p-toluenesulfonic acid [ S0 3 H=l] 

2-Nitro-p-toluidine [NH 2 =l] 

16-Nitroviolanthrone 

Nonylphenol 

l-[(7-0xo-7H-benz[de] anthracen-3-yl) amino] anthraquinone 

l,l'-[(7-0xo-7H-benz[de]anthracen-3,9-ylene)diimino]dianthraquinone 

5-0xo-l-phenyl-2-pyrazoline-3-carboxylic acid, ethyl ester 

5-0xo-l-(p-sulfophenyl)-2-pyrazoline-3-carboxylic acid 

(Pyrazolone T) 

Phenol, grand total 3 

Natural, total 

From coal tar 

From petroleum 

Synthetic, total 

From cumene 

Other synthetic 



Phenylacetic acid and salts 

p-Phenylazoaniline (p-Aminoazobenzene) and hydrochloride 

l-Phenyl-l,2-propanedione, 2-oxime (Isonitrosopropiophenone)- 
Phthalic anhydride 

Picolines, total 6 

2-Picoline (a -Picoline) 

Other picolines 



Piperidine 

Propiophenone 

8,16-Pyranthrenedione 

2°-Pyridine 6 

Quinaldine 

Salicylaldehyde 

Salicylic acid, tech 

Styrene, all grades 

Terephthalic acid, dimethyl ester 

1,4,5,8-Tetrachloroanthraquinone 

1,4,5,8-Tetrahydroxyanthraquinone, leuco derivative 

Toluene-2,4-diamine (4-m-Tolylenediamine) 

o(and p) -Toluenesulfonic acid 

4-(o-Tolylazo)-o-toluidine 

l,3,3-Trimethyl-A 2 ' a -indolineaeetaldehyde 

l,3,3-Trimethyl-2-methyleneindoline 

7,7 '-Ureylenebis[4-hydroxy-2-naphthalenesulfonic acid] (J acid urea) 
Violanthrone (Dibenzanthrone) 



o-Xylene 

p-Xylene 

Xylenols 7 

All other cyclic intermediates- 



1,000 

pounds 

8,429 

73 

1,257 

88 

61,001 

375 

637 



1,229,113 



55,672 

41,055 

U,617 

1,173,441 

560,040 

613,401 

4,056 

166 

248 

608,318 

4,779 



1,000 
pounds 



822 

22,190 



532,704 



2,332 
2,447 

434 

533 

19 

6,488 

38 

2,540 

22,763 

2,864,306 

544,578 

89 

127 

54,411 

5,868 

467 

141 

326 

437 

569 

351,369 

396,333 

14,585 

2,321,922 



52,532 

36,241 

16,291 

480,172 

224,040 

256,132 

3,290 



336,289 
2,493 



1,000 
dollars 



2,424 



50,222 



812 
1,681 



5,751 

1,839 

5,138 

1,248,222 

218,991 



5,183 



343,755 

375,248 

12,440 

990,168 



47f 

3,198 

1,690 

45,334 

20,682 

24,652 

1,285 



28,364 
1,011 



~278~ 
733 



3,313 

1,879 

1,786 

95,190 

52,474 



9,121 

32,714 

1,478 

216,479 



.10 
.09 
.10 



.58 
1.02 



.22 



1 Calculated from rounded figures. 

Principally straight-chain dodecylbenzene and tridecylbenzene, but includes lesser amounts of branched-chain com- 
pounds and other alkylbenzenes. 

3 Includes data for coke ovens and gas-retort ovens, reported to the Division of Bituminous Coal, U.S. Bureau of 
Mines, Department of the Interior, and for tar and petroleum refineries and other producers, reported to the U.S. 
Tariff Commission. 

4 Includes some mixed cresols. Figures include (o,m,p)-eresol from coal tar and from petroleum. 

5 Does not include ethylbenzene produced and consumed in continuous-process styrene manufacture. 

6 Includes data for coke ovens and gas-retort ovens, reported to the Division of Bituminous Coal, U.S. Bureau of 
Mines, Department of the Interior, and for tar refineries and other producers, reported to the U.S. Tariff Commission. 

7 Includes low- and medium-boiling xylenols and xylenols unclassified as to boiling point. 



DYES 15 

In 1965, production of ethylbenzene exceeded 3 billion pounds for the first time, reaching 
3,023 million pounds. Styrene production in 1965 was 2,864 million pounds, an 11.4-percent in- 
crease over the 2,571 million pounds reported for 1964. Ethylbenzene is used almost entirely in 
the manufacture of styrene, which, in turn, is used almost entirely in the manufacture of plastics 
materials and synthetic rubber. Other intermediates whose production exceeded one billion 
pounds in 1965 were cyclohexane at 1,700 million pounds, representing a 24.4-percent increase 
over the 1,367 million pounds reported for 1964, and phenol at 1,229 million pounds, represent- 
ing a 10.4-percent increase over the 1964 production of 1,113 million pounds. The output of 
other large-volume intermediates in 1965 compared with production in 1964 was as follows: 
Cumene, 663 million pounds (20.6 percent larger); phthalic anhydride, 608 million pounds (9.1 
percent larger); monochlorobenzene, 546 million pounds, (1.6 percent larger); terephthalic acid, 
dimethyl ester, 545 million pounds (53.1 percent larger); p-xylene, 396 million pounds (34.0 per- 
cent larger); and isocyanates, 184 million pounds (33.6 percent larger). 

Dyes 

Dyes produced in the United States are all derived in whole or in part from cyclic inter- 
mediates. Approximately two-thirds of the dyes consumed in the United States are used by the 
textile industry to dye natural and synthetic fibers or fabrics; about one-sixth are used for color- 
ing paper; and the rest are used chiefly in the production of organic pigments and in the dyeing of 
leather and plastics. Of the several thousand different synthetic dyes that are known, more than 
two thousand are manufactured by one or more domestic producers. The large number of dyes 
results from the many different types of materials to which dyes are applied, the different con- 
ditions of service for which dyes are required, and the costs that a particular use can bear. 
Dyes are sold as pastes, powders, lumps, and solutions; concentrations vary from 6 percent to 
100 percent. The concentration, form, and purity of a dye are determined largely by the use for 
which it is intended. 

Table 8A 2 shows U.S. production and sales of dyes in 1965, total and by individual dyes, 
using the Colour Index classification and terminology. 

Total domestic production of dyes in 1965 amounted to 207 million pounds, or 12.4 percent 
more than the 184 million pounds in 1964. Sales of dyes in 1965 amounted to 190 million pounds, 
valued at $292 million, compared with 178 million pounds, valued at $264 million, in 1964. In 
terms of quantity, sales of dyes in 1965 were 6.6 percent larger than in 1964, and in terms of 
value, 10.7 percent larger. The average unit value of sales of all dyes in 1965 was $1.54 a pound, 
compared with $1.48 a pound in 1964. 

For many important individual low- and medium-priced dyes for which statistics are given 
in table 8A, production was larger in 1965 than in 1964. The output of Vat Green 8 was 2.0 mil- 
lion pounds in 1965, or 78.8 percent more than the 1.1 million pounds produced in 1964; that of 
Vat Black 25 was 4.5 million pounds, or 44.7 percent more than the 3.1 million pounds produced 
in 1964. Other important dyes whose output was substantially larger in 1965 than in 1964 were 
Disperse Yellow 3 (38.3 percent), Vat Green 3 (34.3 percent). Vat Yellow 2 (33.0 percent), Sulfur 
Black 1 (31.9 percent), Direct Blue 2 (23.0 percent), and Mordant Black 11 (17.4 percent). 

On the other hand, the output of a few important dyes was smaller in 1965 than in 1964. Pro- 
duction of Vat Green 1 was 3.8 million pounds in 1965, or 36.4 percent less than the 5.9 million 
pounds produced in 1964; that of Leuco Sulfur Black 2 was 2.2 million pounds, or 20.5 percent 
less than the 2.8 million pounds produced in 1964. The output of Acid Black 1 was 9.7 percent 
smaller in 1965 than in 1964, and that of Vat Blue 6 was 4.4 percent smaller. 



2 See also table 8B, pt. Ill, which lists these products and identifies the manufacturers, and the appendix (table 23), which shows imports 
of dyes during the years 1964-65. 



SYNTHETIC ORGANIC CHEMICALS, 1965 
TABLE 8A. --Benzenoid dyes.- U.S. production and sales , 1965 



[Listed below are all benzenoid dyes for which any reported data on production or sales may be published. (Leaders 
are used where the reported data are accepted in confidence and may not be published or where no data were 
reported.) Table 8B in pt. Ill lists all dyes for which data on production or sales were reported and identifies 
the manufacturer of each] 



Dye 



Production 



Grand total 

ACID DYES 

Total 

Acid yellow dyes, total 

Acid Yellow 3 

Acid Yellow 11 

Acid Yellow 17 ■ 

Acid Yellow 23 

Acid Yellow 36— - — 

Acid Yellow 40 

Acid Yellow 42 

Acid Yellow 44 

Acid Yellow 54 

Acid Yellow 73 

Acid Yellow 99 

All other 

Acid orange dyes, total 

Acid Orange 1 

Acid Orange 7 

Acid Orange 8 

Acid Orange ID 

Acid Orange 24 

Acid Orange 60 

Acid Orange 64 

All other 

Acid red dyes, total 

Acid Red 1 

Acid Red 4 

Acid Red 1A 

Acid Red 18 

Acid Red 26 

Acid Red 37 

Acid Red 73 

Acid Red 85 

Acid Red 87 

Acid Red 88 • 

Acid Red 89 

Acid Red 99 - ■ 

Acid Red 114 - ~ • 

Acid Red 115 

Acid Red 137- — ■ 

Acid Red 151 • 

Acid Red 182 

Acid Red 186 

All other 

Acid violet dyes, total 

Acid Violet 1 

Acid Violet 3— ■ 

Acid Violet 7 

Acid Violet 12 

Acid Violet 49 

All other 



1,000 
pounds 
207, 193 



20,395 



3,375 



46 
461 
387 
239 
140 



89 

246 



1,633 
2,793 



77 
698 
315 
265 
502 
60 
50 
826 

3,489 



654 
95 
100 
129 
112 
40 
250 
162 



173 
58 



142 
118 



1,171 



67 
71 

104 
73 
77 

102 



1,000 
pounds 
189,965 



1,000 
dollars 
292,284 



18,666 



2,961 



3T 

46 

472 

334 

241 

135 

52 

28 

65 

72 

70 

1,415 

2,789 



T8~ 
717 
354 
294 
516 
47 



2,973 



592 
114 
116 
114 
110 
42 
249 
160 



171 
66 
39 

136 

106 
41 
34 

601 



58 
81 

122 
62 
72 

107 



39,025 



6,743 



111 

96 

1,011 

728 

361 

374 

85 

82 

141 

163 

157 

3,434 

4,271 



100 
672 
404 
384 
693 
120 
168 
1,730 

6,022 



621 

207 
159 
135 
135 
126 
547 
288 
183 
202 

71 
397 
138 

64 
429 
230 
131 
103 
1,856 

944 



83 

1A2 
166 
94 
160 
299 



See footnotes at end of table. 



DYES 



TABLE 8A. --Benzenoid dyes ; U.S. production and sales , 1 965- -Continued 



Eye 



Quantity 



ACID DYES— Continued 

Acid blue dyes, total 

Acid Blue 7 

Acid Blue 9 

Acid Blue 25 — 

Acid Blue 40 

Acid Blue 41 

Acid Blue 43 

Acid Blue 45 

Acid Blue 62 

Acid Blue 78 

Acid Blue 90 

Acid Blue 113 

Acid Blue 118 

Acid Blue 158 and 158A — 

All other 

Acid green dyes, total 

Acid Green 3 

Acid Green 9 

Acid Green 12 

Acid Green 16 

Acid Green 20 

Acid Green 25 

All other 

Acid brown dyes, total 

Acid Brown 1A 

All other 

Acid black dyes, total 

Acid Black 1 

Acid Black 24 

Acid Black 48 — — 

Acid Black 107— - 

All other 

AZOIC DIES AND COMPONENTS 

Azoic Compositions 

Total 

Azoic Yellow 1 

Azoic Yellow 3 

Azoic Orange 3 

Azoic red dyes, total 

Azoic Red 1 

Azoic Red 2 

Azoic Red 6 

Azoic Red 16 

All other 

Azoic Blue 2 

Azoic Blue 3 

Azoic Brown 9 

Azoic black dyes 

All other azoic compositions 



1,000 
pounds 
3,695 



748 
121 



212 
1,343 



1,075 



206 
25 
15 
81 
38 
364 
346 



306 
489 



4,679 



1,247 

1D1 

12 

289 

3,030 



2,100 



202 

67 

304 



115 
1A9 
823 
218 



1,000 
pounds 
3,275 



1,000 
dollars 



74 
24 

538 

26 

39 

9 

351 

188 
1,812 



179 
23 
13 
65 
38 
260 
312 



270 
467 



4,539 



1,178 
120 
25 
187 

3,029 



2,043 



200 
64 

301 
6 
87 

13 
113 
146 
790 
216 



9,582 



647 

59 
247 
181 
1,722 
166 
257 

91 
529 

424 
5,061 

2,431 



211 
101 

54 
245 

73 
782 
965 

1,683 



385 
1,298 



7,349 



1,436 
210 
130 
522 

5,051 



3,968 



94 
4 
91 

1,159 



348 
124 
500 
17 
170 

26 

185 

479 

1,403 

527 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1965 
TABLE 8A. --Benzenoid dyes.- U.S. production and sales, 1 965- -Continued 



Production 



Quantity 



AZOIC DYES AND COMPONENTS— Continued 

Azoic Diazo Components , Bases 
(Fast Color Bases) 

Total- - - 

Azoic Diazo Component 4, base 

Azoic Diazo Component 9, base 

Azoic Diazo Component 10, base 

Azoic Diazo Component 12, base 

Azoic Diazo Component 13, base 

Azoic Diazo Component 32, base 

Azoic Diazo Component 48, base 

All other azoic diazo components, bases 

Azoic Diazo Components , Salts 
(Fast Color Salts) 

Total - 

Azoic Diazo Component 1, salt 

Azoic Diazo Component 2, salt 

Azoic Diazo Component 3, salt 

Azoic Diazo Component 5, salt 

Azoic Diazo Component 6, salt 

Azoic Diazo Component 8, salt 

Azoic Diazo Component 9, salt 

Azoic Diazo Component ID, salt 

Azoic Diazo Component 11, salt 

Azoic Diazo Component 12, salt 

Azoic Diazo Component 13, salt -r -. 

Azoic Diazo Component 28, salt 

Azoic Diazo Component 48, salt 

Azoic Diazo Component 49, salt 

All other azoic diazo components, salts 

Azoic Coupling Components 
(Naphthol AS and Derivatives) 

Total 

Azoic Coupling Component 2 

Azoic Coupling Component 3 

Azoic Coupling Component 4 

Azoic Coupling Component 5 

Azoic Coupling Component 7 

Azoic Coupling Component 8 

Azoic Coupling Component 11 

Azoic Coupling Component 14 

Azoic Coupling Component 17 

Azoic Coupling Component 18 

Azoic Coupling Component 19 

Azoic Coupling Component 20 

Azoic Coupling Component 21 

Azoic Coupling Component 29 

All other azoic coupling components 



1,000 
pounds 
1,558 



107 
54 
71 
237 
377 
307 



2,835 



3,172 



1,310 



1,000 
dollars 
2,057 



46 
224 
341 
276 



2,646 



2,429 



151 
266 
429 
427 
79 
623 



2,683 



296 


309 


200 


357 


327 


373 




40 


43 


153 


123 


125 


435 


384 


246 


92 


89 


132 




42 


72 


103 


102 


111 


421 


371 


254 


340 


338 


364 


90 


86 


96 


39 


38 


110 


464 


352 


495 



271 






39 


14 


44 


53 


23 


46 




ID 


28 


791 


715 


1,454 


19 






22 


21 


70 


215 


141 


276 


176 






817 


616 


736 


7 


6 


35 


137 


92 


198 


112 


69 


150 


32 


24 


55 


481 


698 


1,577 



See footnotes at end of table. 



DYES 



19 



TABLE 8A. — Benzenoid dyes : U.S. production and sales , 1965 — Continued 



Eye 



Quantity 



BASIC DYES 

Total - 

Basic yellow dyes, total 

Basic Yellow 2 

Basic Yellow 11 

Basic Yellow 13 

All other 

Basic orange dyes, total 

Basic Orange 1 

Basic Orange 2 

Basic Orange 21 

All other 

Basic red dyes, total 

Basic Red 14- 

All other 

Basic violet dyes, total 

Basic Violet 1 

Basic Violet 3 

Basic Violet 4 

Basic Violet 16 

All other 

Basic blue dyes, total 

Basic Blue 1 

Basic Blue 5 

Basic Blue 7 

Basic Blue 9 

Basic Blue 26 

All other 

Basic Green 1 

Basic Green 4 

Basic Brown 1 

Basic Brown 4 

All other basic dyes 

DIRECT DYES 

Total- - — 

Direct yellow dyes, total 

Direct Yellow 4 

Direct Yellow 5~- 

Direct Yellow 6 

Direct Yellow 11 

Direct Yellow 12 

Direct Yellow 26 

Direct Yellow 28 

Direct Yellow 44 

Direct Yellow 50 

Direct Yellow 59 

Direct Yellow 84 

Direct Yellow 105 

Direct Yellow 106 

All other 



1,000 
pounds 
10,573 



1,923 



605 
482 



1,353 



339 

543 
358 
113 

1,213 



436 
777 



2,991 



983 

38 

130 

1,840 

1,569 



25 
22 

474 

65 

983 

87 
594 
254 
541 

48 



36,080 



6,719 



"463" 

75 

752 

974 

388 

' 345 
403 
398 
327 
467 
188 
691 

1,443 



1,000 
pounds 
9,553 



1,794 



614 
431 



333 

549 

341 

94 

1,055 



351 

704 



2,750 



932 
1,129 



109 
549 



128 
299 



95 

584 
195 
505 
48 



33,663 



6,214 



422 
105 
703 
865 
393 
6 
300 
395 
365 
122 
398 
220 
592 
1,328 



1,000 
dollars 
23,907 



5,419 



1, 

1,717 

326 

2,088 

2,416 



355 

646 

1,082 

333 

3,428 



1,097 
2,331 



5,582 



1,198 

2,045 

97 

388 

1,854 

4,154 



105 

396 

699 

173 

2,781 

300 
1,506 
290 
669 
143 



50,970 



10,972 



~§97~ 

302 

1,101 

979 

926 

15 

568 

671 

745 

183 

567 

536 

1,008 

2,474 



See footnotes at end of table. 



20 SYNTHETIC ORGANIC CHEMICALS, 1965 

TABLE 8A. --Benzenoid dyes; U.S. production and sales, 1965 — Continued 



Dye 



Production 



DIRECT DYES— Continued 

Direct orange dyes, total 

Direct Orange 1 

Direct Orange 8 

Direct Orange 15 

Direct Orange 26 

Direct Orange 34 

Direct Orange 37 

Direct Orange 39 

Direct Orange 72 

Direct Orange 73 

Direct Orange 81 

Direct Orange 102 

All other 

Direct red dyes, total 

Direct Red 1 

Direct Red 2 

Direct Red 4 

Direct Red 10 

Direct Red 13 

Direct Red 16 

Direct Red 23 

Direct Red 24 

Direct Red 26 

Direct Red 28 

Direct Red 31 

Direct Red 37 

Direct Red 39 

Direct Red 75 

Direct Red 79 

Direct Red 80 

Direct Red 81 

Direct Red 83 

Direct Red 122 

Direct Red 127 and 127A 

Direct Red 149— - -- 

Direct Red 153 

All other 

Direct violet dyes, total 

Direct Violet 1 

Direct Violet 9 

Direct Violet 51- 

All other 

Direct blue dyes, total 

Direct Blue 1 

Direct Blue 2 

Direct Blue 6 

Direct Blue 8 

Direct Blue 14 

Direct Blue 15 

Direct Blue 22 

Direct Blue 24 

Direct Blue 25 

Direct Blue 71 

Direct Blue 76 

Direct Blue 78 

Direct Blue 80 

Direct Blue 86 

Direct Blue 98 

Direct Blue 120 and 120A 

Direct Blue 126 

Direct Blue 151 

All other 

See footnotes at end of table. 



1,901 



164 

201 
68 
137 
63 
132 
344 
34 
57 
165 
500 

4,519 



275 

472 

30 

20 

190 

65 

259 

464 

172 

198 

47 

75 

72 

301 
587 
385 
113 



26 

699 



112 
8,141 



431 

2,248 

571 

30 

129 

62 

24 

43 

39 

80 

574 

124 

438 

1,211 

118 

178 

142 

1,699 



1,000 
pounds 
1,829 



1,000 
dollars 
4,044 



170 
184 



121 
319 
58 
57 
185 
488 

4,198 



~T7S 
463 

17 
165 

64 
227 
412 
178 
203 



28 
284 
513 
344 
115 

36 



84 

7 

60 

7,81/; 



407 

2,177 

527 

43 

113 

65 

22 

38 

54 

86 

583 

108 

404 

1,1D3 

125 

189 

175 

30 

1,565 



36 
228 
222 

87 
272 
153 
250 
685 
231 
178 
474 
1,228 

9,102 



"359" 
803 

28 
264 
124 
553 
810 
451 
277 

95 
219 
158 

99 
684 
901 
872 
179 
178 



1,661 
506 



203 

48 

232 

11,437 



731 

1,928 

267 

80 

102 

111 

40 

53 

146 

252 

1,106 

303 

650 

1,712 

235 

397 

462 

40 

2,822 



DYES 
TABLE 8A. — Benzenoid dyes • U.S. production and sales, 1965 — Continued 



Dye 



Quantity 



DIRECT DYES— Continued 

Direct green dyes, total 

Direct Green 1 

Direct Green 6 

Direct Green 8 

Direct Green 12 

Direct Green 38 

All other 

Direct brown dyes, total 

Direct Brown 1 and 1A 

Direct Brown 2 

Direct Brown 6 

Direct Brown 31 

Direct Brown 74 

Direct Bro»n 95 

Direct Brown 111 

Direct Brown 154 

All other 

Direct black dyes, total 

Direct Black 4 

Direct Black 9 

Direct Black 19 

Direct Black 22 

Direct Black 38 

Direct Black 51 

Direct Black 80 

All other . 

DISPERSE DYES 

Total 

Disperse yellow dyes, total 

Disperse Yellow 3 

Disperse Yellow 5 

Disperse Yellow 23 

Disperse Yellow 33 

Disperse Yellow 34 

Disperse Yellow 42 

Disperse Yellow 54 

All other 

Disperse orange dyes, total 

Disperse Orange 3 

Disperse Orange 5 

Disperse Orange 17- 

All other 

Disperse red dyes, total 

Disperse Red 1 

Disperse Red 5 

Disperse Red 11 

Disperse Red 13 

Disperse Red 17 

Disperse Red 60 

All other 

Disperse Violet 1 

Disperse Violet 4 

Disperse Violet 27 



1,396 



275 
456 

37 
29 



1,883 



266 

200 
84 

102 
56 

560 

369 
246 

11,364 



234 

64 

208 

903 

6,297 

56 

2,148 

1,454 



15,514 



2,707 



1,290 
56 

229 
202 
201 
185 
544 



104 

98 

179 

707 

2,178 



273 
112 
42 
36 
127 



1,000 
pounds 
1,1*9 



201 

471 

32 

1A 
431 

1,756 



227 

184 

103 

93 

62 

498 

61 

322 

206 

10,541 



194 

48 

224 

738 

5,833 

65 

2,087 

1,352 



13,522 



2,484 



1,245 
44 
74 
21B 
171 
189 
155 
388 

801 



115 
523 



1,919 



232 
69 
30 
28 

124 

80 

1,356 

33 
20 
161 



1.000 
dollars 
2,610 



267 

559 
41 

50 
1,693 

2,496 



T0B~ 
283 
119 
270 
93 
437 
217 
313 
456 

9,803 



199 
68 

322 

637 
4,487 

207 
1,850 
2,033 



32,878 



4,822 



2,040 
150 
197 
348 
295 
330 
565 
897 

1,503 



159 

170 
178 
996 

5,899 



379 

85 

128 

38 

170 

291 

4,808 

111 

58 

238 



See footnotes at end of table. 



22 



SYNTHETIC ORGANIC CHEMICALS, 1965 
TABLE 8A. --Benzenoid dyes : U.S. production and sales, 1965- -Continued 



Dye 



Quantity 



DISPERSE DYES— Continued 

Disperse "blue dyes, total 

Disperse Blue 1 

Disperse Blue 3 

Disperse Blue 7 

Disperse Blue 64 

All other 

Disperse "black dyes, total 

Disperse Black 1 

Disperse Black 9 

All other 

All other disperse dyes 

FIBER-REACTIVE DYES 

Fiber- reactive dyes, total 

Reactive yellow dyes 

Reactive red dyes 

Reactive blue dyes 

All other reactive dyes 

FLUORESCENT BRIGHTENING AGENTS 

Total- — — 

Fluorescent Brightening Agent 9 

Fluorescent Brightening Agent 28 

All other fluorescent brightening agents 

FOOD, DRUG, AND COSMETIC COLORS 

Total 

Food, Drug, and Cosmetic Dyes 

Total 

FD&C Blue No. 1 

FD&C Red No. 2 — 

FDScC Red No. 3 - - 

FDScC Red No. 4— — 

FDScC Yellow No. 5 

FD&C Yellow No. 6- 

All other food, drug, and cosmetic dyes 



6,296 



Drug 



nd Cosmetic 
and Cosm 



and Exte 
■tic Dyes 



jl Drug 



348 
1,928 

319 

101 

3,600 

2,723 



344 
2,379 

361 

1,586 



631 
679 



19,420 



3,749 
1,515 
W-, 156 



2,923 



2,681 



Total — - 

D&C Red No. 12 — - — 

D&C Red No. 19 — 

D&C Red No. 21 - 

D&C Red No. 36 - 

All other drug and cosmetic and external drug and 
cosmetic dyes 



1,000 
pounds 
5,559 



250 

1,576 

301 

1A4 

3,288 

2,266 



275 

1,572 

419 



1,558 



271 
337 
613 
337 



18,284 



3,588 
1,568 
13,128 



2,736 



2,493 



1,000 
dollars 
16,700 



1,024 

2,520 

2,041 

464 

10,651 

2,1 



336 

1,607 

945 



6,744 



1,023 
1,223 
3,320 
1,178 



34,516 



5,675 
2,427 
26,414 



10,238 



8,971 



85 


52 


596 


819 


820 


2,223 


111 


90 


1,278 


21 


56 


241 


770 


682 


2,127 


782 


700 


1,949 


93 


93 


557 



1,267 



130 
31 



1,051 



See footnotes at end of table. 



DYES 



23 



TABLE 8A.- -Benzenoid dyes.- U.S. production and sales , i365--Continued 



Eye 



MORDANT DYES 

Total— - 

Mordant yellow dyes, total 

Mordant Yellow 1 

Mordant Yellow 8 

All other 

Mordant orange dyes, total 

Mordant Orange 1 

All other 

Mordant red dyes, total 

Mordant Red 7 

All other 

Mordant blue dyes, total 

Mordant Blue 1 

All other 

Mordant brown dyes, total 

Mordant Brown 1 

Mordant Brown 40 

All other 

Mordant black dyes, total 

Mordant Black 3 

Mordant Black 5 

Mordant Black 11 

Mordant Black 13 

Mordant Black 17 

Mordant Black 38 

All other 

All other mordant dyes 

SOLVENT DYES 

Total 

Solvent yellow dyes, total 

Solvent Yellow 2 — 

Solvent Yellow 3 

Solvent Yellow U 

Solvent Yellow 47 

All other 

Solvent orange dyes, total 

Solvent Orange 2 

Solvent Orange 3 

Solvent Orange 7 

All other 

Solvent red dyes, total 

Solvent Red 24 

Solvent Red 26 

Solvent Red 49 

All other 

Solvent violet dyes, total 

Solvent Violet 8 

All other 

Solvent Blue 38 

See footnotes at end of table. 



Quantity 



31 
136 



117 
90 



3,715 



2,412 

61 

970 



9,837 



1,020 



38 
42 

663 
30 

247 



110 
244 



1,478 



362 
290 
46 
780 



323 
161 



4,246 



43 

12 

187 



43 

101 



23 
180 



3,288 



18 

19 

2,303 

25 

672 

17 

234 

16 



43 
42 

548 
42 

220 



4 

21 

116 

228 

1,362 



284 
272 
40 
766 



1,000 
dollars 
5,706 



23 
336 



205 
279 



169 
135 



137 

58 

434 

3,582 



33 
2,311 

72 
675 

52 
4W 



15,351 



543 
198 

1,004 



7 

45 

164 

475 

2,640 



540 

498 

258 

1,344 

982 



24 



SYNTHETIC ORGANIC CHEMICALS, 1965 
TABLE 8A. — Benzenoid dyes.- U.S. production and sales, 1965 — Continued 



Dye 



Production 



Quantity 



SOLVENT DYES — Continued 

Solvent green dyes, total 

Solvent Green 3 

All other 

Solvent Drown dyes 

All other solvent dyes 

SULFUR DYES 2 

Total 

Sulfur Blue 7 

Sulfur Blue 11 

Sulfur Blue 15 

Sulfur Brown ID 

Sulfur Black 1 

Leuco Sulfur Black 1 

Leuco Sulfur Black 2 

All other sulfur dyes 

VAT DYES 

Total 

Vat yellow dyes, total 

Vat Yellow 2, 8-3/2% 

Vat Yellow 4, 12-1/2% 

All other 

Vat orange dyes, total 

Vat Orange 1, 20% 

Solubilized Vat Orange 1, 26% 

Vat Orange 2, 12% 

Vat Orange 3, 13-1/2% 

Vat Orange 4, 6% 

Vat Orange 5, ]fl% 

Solubilized Vat Orange 5, 30% 

Vat Orange 7, 11% 

Vat Orange 9, 12% 

Vat Orange 15, 10% 

All other 

Vat red dyes, total 

Vat Red 1, 13% 

Vat Red 13, 11% 

Vat Red 15, 10% 

Vat Red 32, 20% 

All other : 

Vat violet dyes, total 

Vat Violet 1, 11% 

Vat Violet 2, 20% 

Vat Violet 9, 12% 

Vat Violet 13, 6-1/4% 

All other 

Vat blue dyes, total 

Vat Blue 6, 8-1/3% 

Vat Blue 18, 13%- 

Vat Blue 20, 14% 

All other- 

See footnotes at end of table. 



5,900 



18,648 



57,511 



4,090 



2,373 
763 
954 

2,794 



322 

110 

113 
7 
312 
124 
687 
493 

1,412 



651 
125 
286 



310 

34 

133 

421 



21,964 



3,395 

1,433 

1,205 

15,931 



97 


360 


56 


220 


86 


304 


,586 


8,270 



17,471 



52,439 



3,897 



2,417 
675 
805 

2,463 



553 



81 
163 

271 
109 
564 
438 

1,143 



201 
30 
265 



214 

33 



391 
68 



19,924 



3,318 

1,125 

1,073 

14,408 



9,960 



120 


130 


92 




26 


26 




6 


13 


47 


50 


34 


1,419 


1,160 


404 


5,827 


5,871 


2,154 


2,207 


2,030 


800 


9,028 


8,198 


6,437 



48,728 



5,303 



2,126 

865 

2,312 

5,846 



1,506 

53 

509 

242 
232 

795 

269 

1,362 

878 

2,436 



~K2~ 
284 
201 
131 
978 



335 
490 

197 

12,659 



3,527 
1,942 
1,450 
5,740 



DYES 



25 



TABLE 8A.--Bemenoid dyes.- U.S. production and sales , 1965— Continued 



Eye 



Production 



Quantity 



Unit 
value 1 



VAT DYES— Continued 

Vat green dyes, total 

Vat Green 1, 6$ 

Vat Green 3, 1A# 

Solubilized Vat Green 3, 26$ 

Vat Green 8, 8- 1/2$ 

Vat Green 9, 12-1/2$ 

All other 

Vat brown dyes, total 

Vat Brown 1, 11$ 

Vat Brown 3, 11$ 

Vat Brown 5, 13% 

All other 

Vat black dyes, total 

Solubilized Vat Black 1, 27-1/2$ 

Vat Black 9, 16$ ■ 

Vat Black 25, 12-1/2$ 

Vat Black 27, 12-1/2$ - ■ 

All other 

All other dyes 3 



1.000 
11,425 



ID, 574 



3,755 
3,970 
16 
2,015 
1,468 
201 

5,037 



629 
1,049 

106 
3,253 

9,793 



3,690 
3,554 
13 
1,878 
1,297 
142 

4,726 



1,000 
dollars 

7,379 



2,425 
2,209 
80 
1,379 
1,057 
229 

5,618 



559 

970 

115 

3,082 

8,910 



176 
4,51/4 

747 
4,356 

296 



4 
153 

4,151 
653 

3,949 

469 



887 
1,493 

177 
3,061 

7,797 



33 
354 

2,904 
792 

3,71A 

884 



pound 

$0.70 



.66 
.62 

6.15 
.73 
.81 

1.61 

1.19 



1.59 
1.54 
1.54 



8.25 
2.31 

.70 
1.21 

.94 

1.88 



1 Calculated from rounded figures. 

2 Production and sales quantities of C.I. Leuco Sulfur and C.I. Solubilized Sulfur dyes are reported in terms of 
the usual commercial concentration of the C.I. Sulfur dyes. 

3 Includes oxidation bases, ingrain dyes, and miscellaneous dyes. Statistics for these groups of dyes may not be 
published separately because publication would disclose information received in confidence. 



Table 9 summarizes production and sales of dyes in 1965, by class of application. Six 
classes of dyes grouped by class of application accounted for more than four-fifths of all the 
dyes produced in 1965. Vat dyes accounted for 27.8 percent of the total; direct dyes, for 17.4 
percent; acid dyes, for 9.8 percent; fluorescent brightening agents, for 9.4 percent; sulfur 
dyes, for 9.0 percent; and disperse dyes, for 7.5 percent. Of the above six classes, the output 
of disperse dyes was 18. 1 percent larger in 1965 than in 1964; that of fluorescent brightening 
agents, 16.5 percent larger; and that of both direct and acid dyes, 14. 6 percent larger. 

Of the remaining classes, the output of mordant dyes was 4. 7 million pounds in 1965, or 
33. 6 percent more than the 3. 6 million pounds in 1964. Production of fast color salts was 32. 7 
percent larger in 1965 than in 1964; basic dyes, 15. 5 percent; solvent dyes, 15. 1 percent; and 
fast color bases, 12.0 percent. On the other hand, the output of fiber- reactive dyes was 3. 3 
percent smaller in 1965 than in 1964, and that of azoic coupling components, 1.4 percent 
smaller. 

Table 10 shows production and sales of dyes in 1965, by chemical class. In 1965, three 
chemical classes of dyes accounted for approximately two-thirds of all the dyes produced: Azo 
dyes accounted for 32. 1 percent of the total; anthraquinone dyes, for 23. percent; and stilbene 
dyes, for 10. 3 percent. The output of each of these three classes was larger in 1965 than in 
1964: Stilbene dyes were 15.4 percent larger; azo dyes, 14.9 percent larger; and anthraquinone 
dyes, 14.4 percent larger. Of the remaining chemical classes for which 1964 and 1965 statistics 
are published, production of most classes was larger in 1965 than in 1964. In terms of value 
of sales, the most important classes of dyes in 1965 were the azo dyes ($107. 1 million), the 
anthraquinone dyes ($72.7 million), the stilbene dyes ($33.0 million), and the triarylmethane 
dyes ($13. 3 million). 



26 



SYNTHETIC ORGANIC CHEMICALS, 1965 
TABLE 9*--Benzenoid dyes.- U.S. production and sales , by class of application, 1965 



Class of application 



Total 

Acid 

Azoic dyes and components: 

Azoic compositions 

Azoic diazo components, bases (Fast color bases) 

Azoic diazo components, salts (Fast color salts) 

Azoic coupling components (Naphthol AS and derivatives) 

Basic 

Direct 

Disperse 

Fiber-reactive 

Fluorescent brightening agents 

Food, drug, and cosmetic colors 

Mordant 

Solvent 

Sulfur 2 

Vat 

All other 3 



1,000 
pounds 
207,193 



20,395 

2,100 

1,558 

2,835 

3,172 

10,573 

36,080 

15,514 

1,586 

19,420 

2,923 

4,745 

9,837 

18,648 

57,511 

296 



Quantity 



1.000 
pounds 
189,965 



18,666 

2,043 
1,310 
2,646 
2,429 
9,553 
33,663 
13,522 
1,558 
18,284 
2,736 
4,246 
8,930 
17,471 
52,439 
469 



1,000 
dollars 
292,284 



39,025 

3,968 

2,057 

2,683 

4,669 

23,907 

50,970 

32,878 

6,744 

34,516 

10,238 

5,706 

15,351 

9,960 

48,728 

884 



Unit 
value 1 



pound 
$1.54 



2.09 

1.94 
1.57 
1.01 
1.92 
2.50 
1.51 
2.43 
4.33 
1.89 
3.74 
1.34 
1.72 
.57 
.93 
1.88 



. I. Solubilized Sulfur dyes are reported in terms of 



1 Calculated from rounded figures. 

2 Production and sales quantities of C.I. Leuco Sulfur and 
the usual commercial concentration of the C.I. Sulfur dyes. 

3 Includes oxidation bases, ingrain dyes, and miscellaneous dyes. Statistics for these groups of dyes may not be 
published separately because publication would disclose information received in confidence. 



TABLE 10. — Benzenoid dyes.- U.S. production and sales, by chemical class, 1965 



Chemical class 



Unit 
value 1 



Total 

Anthr aquinone - - 

Azo, total 

Monoazo 

Disazo 

Trisazo 

Polyazo 

Not specified 

Azoic 

Cyanine 

Indigoid 

Ketone imine — 

Methine 

Nitro 

Oxazine 

Phthalocyanine - 

Quinoline 

Stilbene 

Sulfur 2 

Thiazole 

Triarylmethane - 

Xanthene 

All other 3 



1,000 
pounds 
207,193 



1,000 
pounds 
189,965 



1,000 
dollars 
292,284 



47,674 



66,497 



42,774 



61,737 



24,752 

19,807 

12,155 

3,315 

6,468 

9,754 
518 

5,740 
613 

1,343 
913 
173 

2,197 

576 

21,327 

18,648 

625 

6,690 

1,311 
22,594 



22,390 

18,584 

11,350 

2,937 

6,476 

8,441 

442 
5,533 

620 
1,188 

788 

179 
2,002 

507 
19,874 
17,471 

559 
5,992 

787 
21,071 



72,664 
107,091 



43,337 
32,631 
12,157 
4,727 
14,239 

13,405 
1,423 
3,304 
1,313 
4,160 
1,438 
736 
5,0pl 
1,664 

33,029 
9,960 
1,113 

13,252 
3,887 

18,794 



pound 



$1.54 



1.73 



1.94 
1.76 
1.07 
1.61 
2.20 

1.59 
3.22 
.60 
2.12 
3.50 
1.82 
4.11 
2.52 
3.28 



2.21 
4.94 



Calculated from rounded figures. 

2 Production and sales quantities of C.I. Leuco Sulfur and C.I. Solubilized Sulfur dyes are reported in terms of 
the usual commercial concentration of the C.I. Sulfur dyes. 

3 Includes acridine, aminoketone, azine, coumarin, hydroxyketone , nitroso, oxidation bases, thiazine, vat sulfur, 
and miscellaneous dyes. Statistics for these groups of dyes may not be published separately because publication 
would disclose information received in confidence. 



PIGMENTS 27 



Pigments 



As the terms are used in this report, synthetic organic pigments are toners and lakes 
derived in whole or in part from benzenoid chemicals and colors. They are used in paints and 
related products, in printing inks, and in plastics and resin materials. 

Statistics on production and sales of all benzenoid pigments in 1965 are given in table 11A. 
Statistics on sales of a few selected pigments by commercial forms (dry full- strength form, 
dry extended form, dry dispersions, aqueous dispersions, and flushed colors) are given in 
table 12. Prior to 1961, statistics for toners included the quantities and values of extenders and 
diluents. Beginning in 1961, data were collected for both the full-strength and extended toners 
on a full-strength-toner-content basis. Individual toners and lakes are identified in this report 
by the names used in the second edition of the Colour Index. 

Total production of benzenoid pigments in 1965 was 48. million pounds--9. 1 percent more 
than the 44. 1 million pounds produced in 1964 and 21.9 percent more than the 39. 4 million 
pounds produced in 1963. Total sales of benzenoid pigments in 1965 amounted to 38.0 million 
pounds, valued at $93. 6 million, compared with 35. 1 million pounds, valued at $84. 1 million, in 

1964 and 33. 5 million pounds, valued at $79. 6 million, in 1963. In terms of quantity, sales of 
benzenoid pigments in 1965 were 8.4 percent larger than in 1964 and 13.4 percent larger than 
in 1963; in terms of value, sales in 1965 were 11. 3 percent larger than in 1964 and 17. 6 percent 
larger than in 1963. 

Production of toners in 1965 amounted to 43.7 million pounds--9.2 percent more than the 
40.0 million pounds reported for 1964. Sales in 1965 were 34.1 million pounds, valued at $89.9 
million, compared with 31.4 million pounds, valued at $80.9 million, in 1964. Sales in 1965 were 
thus 8.5 percent larger than those in 1964 in terms of quantity, and 11.1 percent larger in terms 
of value. The individual toners listed in the report which were produced in the largest quantities 
in 1965 were Pigment Blue 15, alpha form, 4.5 million pounds; Pigment Green 7, 4.3 million 
pounds; Pigment Yellow 12, 3.5 million pounds; Pigment Red 49, barium toner, 3.2 million 
pounds; Pigment Red 48, 2.6 million pounds; Pigment Blue 19, 2.5 million pounds; and Pigment 
Blue 15, beta form, 2.2 million pounds. 

Production of lakes totaled 4.3 million pounds in 1965--8.0 percent more than the 4.0 mil- 
lion pounds reported for 1964. Sales of lakes in 1965 amounted to 3.9 million pounds, valued at 
$3.8 million, compared with sales in 1964 of 3.7 million pounds, valued at $3.3 million. Sales in 

1965 were thus 7.3 percent larger than those in 1964 in terms of quantity, and 15.3 percent 
larger in terms of value. Pigment Blue 24, with an output of 2.2 million pounds, was the lake 
produced in largest quantity in 1965. 

For each of 14 selected pigments, or groups of pigments, table 12 gives data on sales by 
commercial forms. Pigment Yellow 12, Pigment Red 90, and Pigment Blue 19 were sold prin- 
cipally in the flushed form. The remaining 11 pigments, or groups of pigments, for which statis- 
tics are published were sold principally in the dry full- strength form. Statistics on sales by 
commercial forms could not be published for Pigment Red 49, sodium toner, or for Pigment 
Blue 24 without revealing the operations of individual companies. 



3 Sec also table 11B, pt. Ill, which lists these products alphabetically and identifies the manufacturers, and table 23 in the appendix, 
which shows imports of benzenoid pigments during the years 1964-G5. 



28 



SYNTHETIC ORGANIC CHEMICALS, 1965 
TABLE 11 A. --Benzenoid pigments: U.S. production and sales , 1965 



[Listed below are all toners and lakes for which any reported data on production or sales may be published. (Leaders 
are used where the reported data are accepted in confidence and may not be published or where no data were 
reported.) Table 11B in pt. Ill lists all toners and lakes for which data on production or sales were reported and 
identifies the manufacturer of each] 



Pigment 



Quantity 



Grand total 

TONERS 
Total 

Yellow toners, total 

Hansa yellows, total 

Pigment Yellow 1, C.I. 11 680 — 

Pigment Yellow 3, C.I. 11 710 

Other Hansa yellows 

Benzidine yellows, total 

Pigment Yellow 12, C.I. 21 090 

Pigment Yellow 13, C.I. 21 100 

Pigment Yellow 14, C.I. 21 095 

Pigment Yellow 17, C.I. 21 1£>5 

Other benzidine yellows 

All other 

Orange toners, total 

Pigment Orange 2, C.I. 12 060 

Pigment Orange 5, C.I. 12 075 

Pigment Orange 13, C.I. 21 110 

Pigment Orange 16, C.I. 21 160 

All other 

Red and violet toners, total 

Naphthol reds, total 

Pigment Red 2, C.I. 12 310 

Pigment Red 5, C.I. 12 490 

Pigment Red 17, C.I. 12 390 

Pigment Red IS, C.I. 12 350 

Pigment Red 22, C.I. 12 315 

Pigment Red 23, C.I. 12 355 

Other naphthol reds 

Pigment Red 1, C.I. 12 070, dark 

Pigment Red 1, C.I. 12 070, light — 

Pigment Red 3, C.I. 12 120 - - 

Pigment Red 4, C.I. 12 085 - 

Pigment Red 6, C.I. 12 090 

Pigment Red 38, C.I. 21 120- 

Pigment Red 48, C.I. 15 865 

Pigment Red 49, C.I. 15 630: 

Barium toner 

Calcium toner 

Sodium toner , 

Pigment Red 52, C.I. 15 860 

Pigment Red 53, C.I. 15 585, barium toner- 
Pigment Red 54, C.I. 14 830, calcium toner- 
Pigment Red 57, C.I. 15 850, calcium toner- 
Pigment Red 63, C.I. 15 880 

Pigment Red 81, C.I. 45 160, PMA 

Pigment Red 81, C.I. 45 160, PTA 

Pigment Red 90, C.I. 45 380 

Pigment Violet 1, C.I. 45 170, PMA 

Pigment Violet 1, C.I. 45 170, PTA 

Pigment Violet 3, C.I. 42 535, fugitive 

Pigment Violet 3, C.I. 42 535, PMA 

Pigment Violet 3, C.I. 42 535, PTA 

All other 



1,000 
pounds 
48,045 



6,935 



1,208 
590 
170 
448 

5,509 

3,541 
316 

1,204 
223 
225 
218 

860 



247 
172 
212 
229 



770 

94 

100 

63 

12 

115 

104 

282 

210 

192 

1,593 

388 

73 

157 

2,627 

3,223 

1,544 

241 

1,181 

1,924 

69 

965 

323 

166 

1,291 

78 

44 

432 

429 

40 

2,594 



1,000 
pounds 
38,024 



1,000 
dollars 
93,635 



34,105 



4,523 



386 

85 

397 

3,515 

2,063 

177 

942 

152 

181 

140 

700 



185 

160 
181 
135 

16,720 



601 
54 



97 
109 
221 
152 
162 
1,250 
251 

127 
2,231 

2,941 

1,384 

268 

1,008 

1,590 

52 

853 

38 

223 

133 

667 



385 

378 

36 

1,870 



12,737 



2,316 

728 

196 

1,392 

8,730 

4,503 

566 

2,184 

526 

951 

1,691 

2,745 



55 

290 

520 

536 

1,344 

38,883 



2,759. 
165 
324 
172 

291 
416 

1,391 
189 
199 

1,915 
351 

576 
4,068 

2,870 
1,413 

272 
1,307 
2,038 

115 

1,272 

71 

1,359 

835 
1,239 

227 

264 

578 
1,096 

147 
13,723 



See footnotes at end of table. 



PIGMENTS 



29 



TABLE HA. --Benzenoid pigments; U.S. production and sales , 1965 — Continued 



Pigment 



Unit 
value 1 



TON ERS- - Cont inued 

Blue toners, total 

Pigment Blue 1, C.I. 42 595, PMA 

Pigment Blue 1, C.I. 42 595, PTA- 

Pigment Blue 2, C.I. 44 045, fugitive, PMA, and PTA- 

Pigment Blue 9, C.I. 42 025, PTA 

Pigment Blue IA, C.I. 42 600, PMA 

Pigment Blue 15, C.I. 74 160, alpha form 

Pigment Blue 15, C.I. 74 160, beta form 

Pigment Blue 19, C.I. 42 750A 

Pigment Blue 22, C.I. 69 810 

All other 

Green toners, total 

Pigment Green 1, C.I. 42 040, PMA 

Pigment Green 1, C.I. 42 040, PTA 

Pigment Green 2, C.I. 42 040 and 49 005, PMA 

Pigment Green 2, C.I. 42 040 and 49 005, PTA 

Pigment Green 4, C.I. 42 000, PMA 

Pigment Green 4, C.I. 42 000, PTA 

Pigment Green 7, C.I. 74 260 

Pigment Green 8, C.I. ID 006 

All other 

Brown toners, total 

Pigment Brown 5, C.I. 15 800 

All other 

Black toners 

LAKES 

Total- - 

Red lakes, total 

Pigment Red 60, C.I. 16 105- - 

Pigment Red 83, C.I. 58 000 

(Acid Red 26), C.I. 16 150 

All other 

Violet lakes, total 

Pigment Violet 5, C.I. 58 055— 

All other 

Blue lakes, total 

Pigment Blue 24, C.I. 42 090 

All other 

Black lakes: (Natural Black 3), C.I. 75 291 

All other lakes 2 



1,000 

pounds 

9,997 



T7D" 

31 

18 

9 

70 

4,538 

2,239 

2,546 

376 



55 

41 

7 

7 

4,252 

184 

337 

164 



220 

83 

623 



2,214 



2,183 



67 

853 



1,000 
pounds 

8,239 



T50" 
22 



66 

3,464 

1,797 

2,450 

17 

240 

3,557 



2,965 
143 
333 



3,919 



958 



~178~ 

70 

625 

85 



1,960 



1,928 



1,000 
dollars 
23,603 



"750" 

123 

46 

55 

522 

9,497 

5,390 

5,661 

343 

1,216 

11,369 



249 
212 



9,270 

190 

1,301 



157 
123 



1,067 



272 
248 
286 
261 



1,872 



1,852 



$2.86 



"4T69" 
5.59 
3.29 
6.11 
7.91 
2.74 
3.00 
2.31 

20.18 
5.07 

3.20 



5.00 
5.62 
4.88 
6.24 
4.33 
3.50 
3.13 
1.33 
3.91 



1.94 
4.39 



1.11 



1.53 
3.54 

.46 
3.07 

2.1A 



1 Calculated from rounded figures. 

2 Includes all brown, green, orange, and yellow lakes, "all other" black lakes, and sales of Natural Black 3. 

Note. — The C.I. (Colour Index) numbers shown in this report are the identifying numbers given in the second edition of 
the Colour Index. 

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic ( including phosphotungstomolybdic) 
acids, respectively. 



30 SYNTHETIC ORGANIC CHEMICALS, 1965 

TABLE 12 — U.S. sales of selected dry full-strength colors, dry extended colors, dry dispersions, aqueous 

dispersions, and flushed colors, 1965 



Selected pigments by commercial forms 



Pigment Yellow 12, C.I. 21 090, total 

Dry full-strength toner 

Dry extended toner, aqueous dispersions 3 and flushed color 

Pigment Yellow 13, C.I. 21 100; Pigment Yellow 14, C.I. 21 095; Pigment 

Yellow 17, C.I. 21 105; and other benzidine yellows, total 

Dry full-strength toner 

Dry extended toner and dry dispersions 4 

Aqueous dispersions 3 

Flushed color 



Pigment Red 3, C.I. 12 120, total 

Dry full-strength toner and dry extended toner 4 

Aqueous dispersions 3 

Flushed color 



Pigment Red 48, C.I. 15 865, total 

Dry full-strength toner 

Dry extended toner 

Dry dispersions and aqueous dispersions 
Flushed color 



Pigment Red 49, C.I. 15 630, barium toner, total - 

Dry full-strength toner --- — 

Dry extended toner and aqueous dispersions 
Flushed color 



Pigment Red 49, C.I. 15 630, calcium toner, total- 
Dry full-strength toner and dry dispersions 4 

Aqueous dispersions 3 and flushed color 4 

Pigment Red 49, C.I. 15 630, sodium toner 4 



Pigment Red 53, C.I. 15 585, barium toner, total 

Dry full-strength toner, dry extended toner, and dry dispersions 4 
Aqueous dispersions 3 and flushed color 4 



Pigment Red 90, C.I. 45 380, total -- 

Dry full-strength toner and dry extended toner 4 - 
Dry dispersions and flushed color 4 



Pigment Violet 3, C.I. 42 535, fugitive, . total— - 
Dry full-strength toner and dry extended toner 
Flushed color 



Pigment Violet 3, C.I. 42 535, permanent (PMA and PTA), total - 

Dry full-strength toner 

Dry extended toner, dry dispersions and aqueous dispersions 
Flushed color 



Pigment Blue 15, C.I. 74 160, alpha form, total - 

Dry full-strength toner 

Dry extended toner 

Dry dispersions 

Aqueous dispersions 3 

Flushed color 



Pigment Blue 15, C.I. 74 160, beta form, total 

Dry full-strength toner r- 

Dry extended toner, dry dispersions and flushed eolor 4 - 
Aqueous dispersions 



Pigment Blue 19, C.I. 42 750A, total 

Dry full-strength toner and dry extended toner 4 
Aqueous dispersions 3 and flushed color 4 



See footnotes at end of table. 



Qjantity 1 



1,000 
pounds 
2,063 



608 
1,455 



1,007 



237 
163 



1,250 



740 

65 

445 



2,062 

41 



2,070 

10 

861 

1,384 



1,110 
274 



1,590 



936 
654 



275 
110 



222 
78 
114 

3,464 



2,036 

497 

34 

721 

176 

1,797 



883 
513 
401 

2,450 



207 
2,243 



1.000 
dollars 

4,734 



1,315 
3,419 



4,302 



3,093 
107 
596 
506 

1,986 



1,126 

108 
752 

4,083 



3,756 
83 

144 
100 

2,981 



2,019 



1,556 



1,131 
425 



1,201 
905 



1,324 



87 
1,237 



418 
162 



693 
226 
338 

9,630 



5,498 
1,618 

153 
1,892 

469 

5,392 



2,760 
1,564 
1,068 



471 
5,190 



MEDICINAL CHEMICALS 

TABLE 12. --U.S. sales of selected dry full-strength colors, dry extended colors , dry dispersions, aqueous 
dispersions , and flushed colors, 1965 — Continued 



Selected pigments by commercial forms 



Quantity 1 



Unit 
value 2 



Pigment Blue 24, C.I. 42 090* 

Pigment Green 7, C.I. 74 260, total - 

Dry full-strength toner 

Dry extended toner 

Dry dispersions 

Aqueous dispersions 3 

Flushed color 



pounds 
1,928 

2,965 



pound 



2,392 
9,341 



$1.24 
3.15 



1,345 

244 

67 

985 

324 



4,314 
903 
279 

2,892 
953 



3.21 
3.70 
4.16 
2.94 
2.94 



1 Quantity of the various commercial forms is given in terms of dry full-strength toner (or dry lake) content. 

2 Calculated from rounded figures. 

3 Includes presscake. 

* Separate data on these commercial forms may not be published without revealing the operations of individual com- 
panies. 

Note. —The C.I. (Colour Index) numbers shown in this report are the identifying numbers given in the second edi- 
tion Of the Colour Index. 

The abbreviations FMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic ) 
acids, respectively. 

Medicinal Chemicals 



Medicinal chemicals include the medicinal and feed grades of all organic chemicals having 
therapeutic value, whether obtained by chemical synthesis, by fermentation, by extraction from 
naturally occurring plant or animal substances, or by refining the technical grade material. They 
include alkaloids, antibiotics and other anti-infective agents, antihistamines, autonomic drugs, 
central-nervous-system depressants and stimulants, hormones, vitamins, and other therapeutic 
agents for human or veterinary use and for animal feed supplements. Statistics on the production 
of medicinal chemicals are in terms of 100-percent content of the medicinal chemical itself, ex- 
clusive of all diluents or other materials used in mixing or compounding tablets, solutions, and 
suspensions for consumer use. Sales include that part of the original production that was sold in 
bulk and exclude all dosage-form products and other finished pharmaceutical preparations. 

Statistics on U.S. production and sales of medicinal chemicals in 1965 are given in table 
13A.* Total production of medicinal chemicals in 1965 amounted to 160 million pounds, or 10.7 
percent more than the 144 million pounds produced in 1964, and 14.6 percent more than the 139 
million pounds produced in 1963. Total sales of medicinal chemicals in 1965 amounted to 129 
million pounds, valued at $362 million. These figures represent sales of bulk medicinal chemi- 
cals only and therefore cannot be compared with sales data for earlier years, which included 
all antibiotics sold by the primary producers, whether they were sold as medicinal preparations 
or as bulk materials. Sales of medicinal chemicals in 1965, exclusive of antibiotics, amounted 
to 125 million pounds, valued at $269 million, compared with sales in 1964 of 113 million 
pounds, valued at $260 million, and sales in 1963 of 108 million pounds, valued at $251 million. 
Sales in 1965 of medicinal chemicals other than antibiotics were thus 10.6 percent larger than 
in 1964 and 15.3 percent larger than in 1963, in terms of quantity, and 3.4 percent larger than 
in 1964 and 7.1 percent larger than in 1963, in terms of value. 

Production of the more important groups of medicinal chemicals in 1965 was as follows: 
Antibiotics, 7.5 million pounds (14.0 percent larger than in 1964), of which 4.7 million pounds was 
for medicinal use and 2.8 million pounds was for other uses; anti-infective agents other than an- 
tibiotics, 27.5 million pounds (5.9 percent larger thanin 1964); central depressants and stimulants, 
42.8 million pounds (5.4 percent larger); and vitamins, 16.3 million pounds (15.5 percent larger). 
Production of some of the more important individual products listed in the report was as follows: 
Aspirin, 29.1 million pounds (3.1 percent larger than in 1964); salicylic acid, 9.9 million pounds 
(24.8 percent smaller than in 1964); choline chloride, 31.1 million pounds (23.6 percent larger); 
methionine and its hydroxy analogue, 10.4 million pounds (72.0 percent larger); ascorbic acid, 
7.3 million pounds (19.6 percent larger); piperazine base and salts, 6.5 million pounds (6.3 per- 
cent smaller); anti-infective sulfonamides, 4.7 million pounds (4.8 percent smaller); vitamin A 
alcohol and esters, 598 trillion units (3.1 percent smaller); penicillins, 1,343 trillion units (11.7 
percent larger); and tetracyclines, 1,157 million grams of antibiotic base. 



See also table 13B. pt. Ill, which lists these products alphabetically and identifies the manufacturers, and table 23 in the appendix 
which shows imports of coal-tar medicinal chemicals and pharmaceuticals during the years l°64-65. 



32 



SYNTHETIC ORGANIC CHEMICALS, 1965 
TABLE 13A. --Medicinal chemicals.- U.S. production and sales , 1965 1 



[Listed below are all synthetic organic medicinal chemicals for which any reported data on production or sales may be 
published. I Leaders are used where the reported data are accepted in confidence and may not be published or where 
no data were reported.) Table 13B in pt. Ill lists alphabetically all medicinal chemicals for which data on produc- 
tion or sales were reported and identifies the manufacturer of each] 



Quantity 



Grand total 

Acyclic 

Benzenoid 3 

Cyclic nonbenzenoid^ 

Antibiotics, total 5 

For medicinal use, total 

Antifungal and antitubercular antibiotics, total 

Streptomycin 

All other 

Bacitracin 

Penicillins, total 

Penicillin G, potassium 

Penicillin G, procaine 

All other 

All other antibiotics for medicinal use 

For other uses, total 

Bacitracin 

Penicillin G, procaine 

All other 

Antihistamines, total 

Antinauseants 

Chlorpheniramine maleate 

Pheniramine maleate 

Pyrilamine maleate 

All other 

Anti-infective agents (except antibiotics), total 

Antimony, arsenic, and bismuth compounds 

Cetylpyridinium chloride 

Mercury compounds 

5-Nitrofurane, -imidazole, and -thiazole derivatives 

Phenolic antiseptics and disinfectants 

Piperazine base and salts, total 

Piperazine 

All other 

Quinoline derivatives, total 

Diiodohydroxyquin 

All other 

Sulfonamides, total 

Sulfathiazole 

All other 

Other anti-infective agents, total 

Anthelmintic, antifungal, antiprotozoan, and antiviral 

agents 

Urinary antiseptics 

All other 

Antineoplastic agents and local anesthetics 

Autonomic drugs, total 

Parasympatholytic (anticholinergic) agents: 
Quaternary ammonium compounds (except tropane 

derivatives) 

Tertiary amines (except tropane derivatives) 

Sympathomimetic (adrenergic) agents, total 

Epinephrine salts 

Isoproterenol salts 

Phenylephrine base and salts, total 

Phenylephrine hydrochloride 

All other 



1,000 
pounds 
159,520 



59,480 
84,678 
15,362 
7,455 



4,656 

1,134 

470 

664 

7 

1,749 

530 

798 

421 

1,766 

2,799 

127 

707 

1,965 

380 



17 
268 



27,493 



3,035 

31 

35 

502 

279 

6,513 

2,891 

3,622 

536 

19 

517 

4,728 

117 

4,611 

11,834 



696 
2,458 

2,189 

436 



( 6 ) 



1,000 
pounds 
129,048 



1,000 
dollars 
362,169 



56,569 
60,977 
11,502 
4, 



2,397 

846 

389 

457 

7 

328 



1,134 

1,689 

132 

1,557 



182 
16,887 



27 

239 
4,455 

712 
3,743 

152 

152 

1,343 

72 

1,271 

10,644 

7,729 

573 

2,342 

1,522 

302 



I 6 ) 



41,011 

224,159 

96,999 

93,593 



53,713 
11,023 
3,539 
7,484 
897 

3,343 

5,996 
32,454 
39,880 

2,943 

36,937 

4,745 



257 
299 



4,189 
67,581 



82 
348 

428 
3,507 

789 
2,718 

495 

495 

6,265 

186 

6,079 

56,456 

46,718 

997 

8,741 

1,724 

5,791 



810 
1,031 
3,603 



1,767 

1,547 

220 



See footnotes at end of table. 



MEDICINAL CHEMICALS 
TABLE 13A. —Medicinal chemicals.- U.S. production and sales, 1965 1 --Continued 



33 



Quantity 



Autonomic drugs — Continued 

Sympathomimetic (adrenergic) agents — Continued 

Phenylpropanolamine hydrochloride 

All other 

All other autonomic drugs 

Cardiovascular agents, total 

Vasodilators 

All other 

Central depressants, total 

Analgesics and antipyretics, total 

Salicylates, total 

Aspirin 

All other 

All other analgesics and antipyretics 

Anticonvulsants, hypnotics, and sedatives, total 

Barbiturates, total 

Butabarbital 

Butabarbital, sodium 

Phenobarbital, sodium 

All other 

All other anticonvulsants, hypnotics, and sedatives 7 — 

Skeletal muscle relaxants, total 

Mephenesin 

Succinylcholine chloride 

All other 

Tranquilizers, total 

Meprobamate 

Phenothiazine derivatives 

All other 7 

Other central depressants, total 8 

Ethyl-aorphine hydrochloride 

All o^her 

Central stimulants, total 

Amphetamines, total 

Amphetamine, dextroamphetamine and levamphet amine base 

and salts, total 

Dextroamphetamine sulfate 

All other 

Methamphetamine base and hydrochloride, total 

Methamphetnnri ne (racemic) 

Methamphetamine hydrochloride (dextro) 

All other 

Antidepressants 

Caffeine (natural and synthetic) 

Other central stimulants 

Dermatological agents, total 

Allantoin 

Bismuth subgallate 

Salicylic acid 

Other dermatological agents 

Expectorants and mucolytic agents 

Gastrointestinal agents, total 

Choleretics and hydrocholeretics 

Choline chloride (all grades) 

Methionine and its hydroxy analogue 

Other gastrointestinal agents 

Hormones and synthetic substitutes, total 

Corticosteroids, total 

Hydrocortisone 



1,000 
pounds 



39,904 



36,320 

32,355 

29,089 

3,266 

3,965 

1,759 

971 

31 

42 

9 

889 

788 

223 



162 
1,548 
1,179 

369 
54 



105 
38 



2,662 
11,255 



32 
9,866 
1,335 

1,021 

43,183 



143 

31,146 

10,402 

1,492 

1,381 



1,000 
pounds 



392 

34,998 



32,859 
29,091 
26,169 
2,922 
3,768 



527 



169 
1,361 
1,272 



( 9 ) 



2,938 



2,741 
101 



6,812 



5,579 
1,233 



1,022 
44,627 



32,459 

10,658 

1,510 



1,000 
dollars 
1,233 
552 
347 

11,731 



11,731 
34,739 



21,726 
17,165 
14,380 
2,785 
4,561 



2,128 
289 

1,839 
899 



899 
5,237 
3,344 

762 

1,131 

4,749 

82 

4,667 

10,169 



753 

471 



471 
282 



5,036 
4,380 



3,286 



2,177 
1,109 



1,613 
19,084 



5,423 
10,368 
3,293 

26,893 



21,713 
2,109 



See footnotes at end of table. 



34 



SYNTHETIC ORGANIC CHEMICALS, 1965 
TABLE 13A. — Medicinal chemicals; U.S. production and sales , 1965 1 Continued 



Quantity 



Unit 
value 2 



Hormones and synthetic substitutes—Continued 
Corticosteroids-- Continued 

All other 

Estrogens 

Synthetic hypoglycemic agents 

Other hormones and synthetic substitutes 

Renal-acting and edema-reducing agents, total 

Mercurial diuretics 

Theobromine and theophylline derivatives, total- 

Aminophylline 

All other 

Other renal-acting and edema-reducing agents 

Therapeutic nutrients, total 

Amino acids and salts, total 

Glutamic acid 

All other 

Calcium gluconate 

Other therapeutic nutrients 

Vitamins, total 

Ascorbic acid and derivatives, total 

Ascorbic acid 

All other 

B-complex vitamins: 

Cyanocobalamin (all grades) 10 

Niacin (all grades) 

Niacinamide 

Pantothenic acid and derivatives, total 

Calcium pantothenate (racemic) (all grades)- 

All other 

Riboflavin (all grades) 

Cholecalciferol (Vitamin D 3 ) 10 

Ergocalciferol (Vitamin D 2 ) 10 

Menadione 

Menadione sodium bisulfite 

Vitamin A alcohol and esters, total 10 

Vitamin A palmitate (feed grade) 

All other 

Other vitamins 

Miscellaneous medicinal chemicals, total 11 

Anticoagulants 

All other 



1,000 
pounds 



27 
1,139 

205 

1,284 



101 



1,174 
3,203 



1,927 

75 

1,852 

656 

620 

16,297 



8,629 
7,274 
1,355 



1,828 

889 

1,610 

1,252 

358 

958 



59 

77 

677 

464 

213 

1,569 

463 



10 
453 



1,000 
pounds 



38 

20 

337 



1,000 

dollars 

19,604 

688 

1,189 

3,303 

7,913 



2,374 



1,334 
56 

1,278 
524 
516 

12,028 



6,089 
4,903 
1,186 



1,461 

858 

1,310 

1,055 

255 

599 

2 



73 

613 

419 

194 

1,021 

261 



28 
262 



262 
7,623 



2,842 



1,879 
345 
529 

65,366 



11,978 
9,349 
2,629 

8,324 
1,812 
1,754 
2,967 
1,780 
1,187 
6,214 
520 
180 

578 
17,249 
8,642 
8,607 
13,790 

5,099 



775 
4,324 



Per 

pound 

$515.89 

34.40 

3.53 

1,101.00 

42.77 



28.00 
2.47 



2.47 
97.73 



TT48" 



,324.00 

1.24 

2.04 

2.26 

1.69 

4.65 

10.37 

260.00 

180.00 

7.92 
28.14 
20.63 
44.37 
13.51 

19.54 



155.00 
16.89 



1 The data on production and sales are for bulk medicinal chemicals; they exclude finished preparations and dosage- 
form products which are manufactured from bulk chemicals. All quantities are given in terms of 100$ active ingredient. 

2 Calculated from rounded figures. 

3 The term "benzenoid," as used in this report, describes any cyclic medicinal chemical whose molecules contain 
either a 6-membered carbocyclic ring with conjugated double bonds (e.g., the benzene ring or the quinone ring) or a 
6-membered heterocyclic ring with 1 or 2 hetero atoms and conjugated double bonds, except the pyrimidine ring (e.g., 
the pyridine ring or the pyrazine ring) . 

** Includes antibiotics of unknown structure. 



MEDICINAL CHEMICALS 



35 



Footnotes for table 13A — Continued 



5 All quantities for antibiotics were reported in terms of grams of antibiotic base or U.S. P. units, but are shown 
in the table in pounds. Statistics for all individually publishable antibiotics are shown below in terms of kilograms 
of antibiotic base (Kg.) or billions of U.S. P. units (BU): 



Quantity 



Bacitracin (BU), total 

For medicinal use 

For other uses 

Neomycin (Kg.), for all uses 

Penicillins (BU), total 

Penicillin G, potassium, for medicinal use- 
Penicillin G, procaine, total 

For medicinal use 

For other uses 

Other penicillins, for medicinal use 

Streptomycin (Kg.), for medicinal use 

Tetracyclines (Kg.), for all uses 



3,054 



169 
2,885 



76,332 
1,343,126 



383,402 
689,433 
365,587 
323,846 
270,291 

213,242 
1,156,705 



3,159 



169 
2,990 



31,783 
773,372 



236,822 
482,669 



53,881 



176,398 
472,551 



1.000 
dollars 
3,840 



897 
2,943 



1,831 
16,444 



3,343 
7,105 



3,539 
29,089 



$1,215.57 



5,307.69 
984.28 



14.12 
14.72 



20.06 
61.56 



6 Production of epinephrine salts amounted to 374 pounds; sales amounted to 370 pounds. 

7 Includes 2 or more of the following 6 drugs which are subject to Federal control under the Drug Abuse Control 
Act: Chlordiazepoxide hydrochloride, diazepam, ethchlorvynol, ethinamate, glutethimide, and methyprylon. U.S. pro- 
duction of these 6 drugs amounted to 524 thousand pounds in 1965. 

8 Includes production and sales of anesthetics and antitussives; also includes sales of "all other" anticonvul- 
sants, hypnotics, and sedatives. 

9 Sales of ethylmorphine hydrochloride amounted to 450 pounds. 

10 The following tabulation shows statistics for vitamins A, Bi 2 , D 2 , and D 3 in terms of kilograms (Kg.) or bil- 
lions of U.S. P. units (BU): 





Production 


Sales 




Quantity 


Value 


Unit value 


Cholecalciferol (Vitamin D 3 ) (BU) 


20,552 
598,264 


29,676 

660 

16,233 

541,147 


1,000 
dollars 

520 

8,324 

180 

17,249 


$17.52 

12,612.12 

11.09 

31.62 


Ergocalciferol (Vitamin D 2 ) (BU) 

Vitamin A alcohol and esters (BU), total 




382,665 
215,599 


345,165 
195,982 


8,642 
8,607 


25.04 
42.96 





Includes diagnostic agents, hematological agents, smooth-muscle relaxants, and miscellaneous unclassified me- 
dicinal chemicals. 



36 



SYNTHETIC ORGANIC CHEMICALS, 1965 



Flavor and Perfume Materials 



Flavor and perfume materials are organic chemicals used in the manufacture of foods, 
beverages, cosmetics, and soaps. Aromatic organic chemicals are utilized to neutralize or to 
mask unpleasant odors in industrial processes and products as well as in consumer products. 
Most of them have desirable flavors or odors, and some have the ability to enhance natural 
flavors when added to certain foods. This report includes data on materials derived from 
natural products by actual chemical processes and from coal tar; it does not include data on 
purely natural products, such as floral essences, essential oils, and other materials that are 
obtained by simple extraction or by distillation from natural plant and animal sources. 

The flavor and perfume materials covered in this report are grouped as either cyclic or 
acyclic materials, according to their chemical structure. Cyclic materials are further classified 
as (1) benzenoid and naphthalenoid, and (2) terpenoid, heterocyclic, and alicyclic. Statistics on 
production and sales of flavor and perfume materials in 1965 are given in table 14A. 5 

Production of flavor and perfume materials in 1965 amounted to 99.2 million pounds--9.6 
percent more than the output of 90.6 million pounds in 1964. Sales in 1965 amounted to 87.7 
million pounds, valued at $85.0 million, compared with 80.0 million pounds, valued at $83.7 
million, in 1964. 

Production of cyclic flavor and perfume materials in 1965 amounted to 53.2 million pounds-- 
7.4 percent more than the 49.6 million pounds reported for 1964. Sales of cyclic flavor and per- 
fume materials in 1965 were 44.6 million pounds, valued at $56.8 million, compared with 41.2 
million pounds, valued at $56.6 million, in 1964. The individual chemical in the cyclic group that 
was produced in the greatest volume in 1965 was methyl salicylate (4.7 million pounds). In 1965, 
production of synthetic sweeteners, as a group, amounted to 12.8 million pounds, representing 
an increase of only 5.1 percent over production in 1964, compared with an increase in 1964 of 
113.7 percent over production in 1963. 

The output of acyclic flavor and perfume materials in 1965 amounted to 46.0 million pounds-- 
12.2 percent more than the 41.0 million pounds reported for 1964. By far the most important of 
the acyclic materials in 1965 was monosodium glutamate, a flavor- enhancing chemical, produc- 
tion of which totaled 43.1 million pounds. Sales of acyclic flavor and perfume materials in 1965 
amounted to 43.1 million pounds, valued at $28.2 million, compared with 38.8 million pounds, 
valued at $27.2 million, in 1964. 

TABLE 14A. — Flavor and perfume materials: U.S. production and sales , 1965 

[Listed below are all synthetic organic flavor and perfume materials for which any reported data on production or 
sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be pub- 
lished or where no data were reported.) Table 1AB in pt. Ill lists alphabetically all flavor and perfume materials 
for which data on production or sales were reported and identifies the manufacturer of each] 



Production 



Quantity 



Unit 
value 1 



Grand total- 



99,224 



87,703 



1,000 
dollars 
84, 980 



Pur 
pound 



$0.96 



FLAVOR AND PERFUME MATERIALS, CYCLIC 



53,223 



44,559 



56,800 



id and Naphthale 



Total- 



24,087 



22,365 



25,307 



1.13 



4-Allylveratrole (Eugenyl methyl ether) - 

Anethole ( p-Propenylanisole) 

p-Anisaldehyde ( p-Methoxybenzaldehyde) -- 

Benzophenone 2 

Benzyl acetate 

Benzyl alcohol 2 

Benzyl cinnamate 

Benzyl propionate 

Benzyl salicylate 

Cinnamaldehyde 

Cinnamyl alcohol 



1,904 

963 

179 

1,324 

3,955 

13 
190 
908 
184 



8 


22 


1,489 


1,053 


922 


1,292 


122 


122 


1,325 


534 


3,725 


1,399 


4 


U 


12 


13 


182 


234 


893 


633 


161 


225 



2.97 

.71 

1.40 

1.00 

.40 

.38 

3.78 

1.11 

1.29 

.71 

1.40 



See footnotes at end of table. 



5 See also table 14B, pt. Ill, which lists these products alphabetically and identifies the manufacturers, and table 23 in the appendix, which 
shows imports of benzenoid flavor and perfume materials during the years 1964-65. 



FLAVOR AND PERFUME MATERIALS 



37 



TABLE 14A. -- Flavor and perfume materials; U.S. production and sales , i365--Continued 



FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued 

Benzenoid and Naphthalenoid— Continued 

Eugenol 

Isobutyl phenylaoetate (Isobutyl a-toluate) 

Isobutyl salicylate 

Isoeugenol 

Isopentyl salicylate (Amyl salicylate) 

p-Isopropyl-a-methylhydrocinnamaldehyde (Cyclamen aldehyde) 

Methyl anthranilate 

a-Methylcinnamaldehyde 

Methyl cinnamate 

Methyl salicylate (Synthetic wintergreen oil) 

a-Pentylcinnamaldehyde (a-Amylcinnamaldehyde) 

Phenethyl acetate 

Phenethyl isobutyrate 

Phenethyl phenylacetate (Phenethyl a-toluate) 

3-Phenyl-l-propanol (Hydrocinnamic alcohol) 

All other benzenoid and naphthalenoid materials 

Terpenoid, Heterocyclic, and Alicyclic 
Total 

Cedryl acetate 

Citral (Geranial) 

Citronellol 

Citronellyl acetate 

Citronellyl formate 

Coumarin 

Essential oils, chemically modified 

Geraniol 

Geranyl acetate 

Hydroxycitronellal 

Ionones 

Isobornyl acetate 

Menthol, synthetic, tech. and U.S.P 

Methylionones 

Nerol 

Piperonal (Heliotropin) 

Rhodinol 

Sweeteners, synthetic 

Terpineols 

Terpinyl acetate 

Vetivenyl acetate 

All other terpenoid, heterocyclic, and alicyclic materials- 

FLAVOR AND PERFUME MATERIALS, ACYCLIC 

Total 

Allyl hexanoate (Allyl caproate) 

Ethyl butyrate 

Ethyl nonanoate (Ethyl pelargonate) 

Glutamic acid, monosodium salt (Monosodium glutamate) 

Isopentyl butyrate (Amyl butyrate) 

Isopentyl formate (Amyl formate) 

Lauraldehyde (Dodecyl aldehyde) (C 12 ) 

All other acyclic materials 

1 Calculated from the unrounded figures. 

2 Includes some technical grade. 



Production 



1,000 
pounds 



4,675 
527 



8,235 



29,136 



46,001 



57 
248 



43,121 
45 



2,528 



Quantity 



1,000 


1,000 


pounds 


dollars 


350 


620 


17 


17 


54 


49 


107 


302 


409 


295 


184 


512 


177 


323 


11 


21 


64 


126 


4,121 


1,850 


451 


624 


73 


74 


6 


14 


12 


39 


18 


33 


7,468 


W,867 



22,194 



125 


122 


252 


171 


80 


286 


555 


460 


737 


29 


29 


51 


25 


21 


53 


1,016 


963 


2,157 


146 


136 


152 


634 


602 


828 


76 


67 


117 


454 


386 


1,553 


262 


248 


830 


942 


910 


346 


381 


384 


1,357 


446 


444 


1,790 


25 


15 


76 


256 


272 


574 


12 


11 


312 


12,841 


10,133 


8,971 


3,418 


3,105 


920 


586 


578 


329 


33 


25 


565 


6,703 


3,203 


9,237 



43,144 



58 

294 



40,366 
58 



19 
2,345 



31,493 



28,180 



216 

201 

7 

25,530 

46 

2 

105 

2,073 



38 



SYNTHETIC ORGANIC CHEMICALS. 1965 



Plastics and Resin Materials 



Plastics and resin materials are condensation or polymerization products of organic chemi- 
cals containing necessary fillers, plasticizers, and extenders. At some stage in their manufac- 
ture they exist in such physical condition that they can be shaped or processed by the application 
of heat and pressure. Some types of plastics may be molded, cast, or extruded into finished or 
semifinished forms. Other types are used as adhesives, for the treatment of textiles and paper, 
and for protective coatings. Still other types of plastics materials may be processed into sheets, 
rods, and tubes, which are further manufactured into finished articles. Except for vinyl resins, 
the statistics given in the following tables are based on the total weight of the materials, exclud- 
ing liquids. Statistics for vinyl resins are given on the basis of resin content. 

Statistics on production and sales of plastics and resins in 1965 are given in table 15A 6 
according to chemical composition and broad end uses. In general, this table follows the outline 

TABLE 15A, — Plastics and resin materials ; U.S. production and sales, by chemical classes 

and uses, 1965 

[Quantities and values are given in terms of the total weight of the materials (dry basis). Listed below are all 
plastics and resin materials for which any reported data on production or sales may be published. (Leaders are 
used where the reported data are accepted in confidence and may not be published or where no data were reported.) 
Table 15B in pt. Ill lists all plastics and resin materials for which data on production or sales were reported 
and identifies the manufacturer of each] 



Kind and use 



Quantity 



Unit 
value 1 



Grand total 

Plastics and resin materials, benzenoid 

Plastics and resin materials, nonbenzenoid 

THERMOSETTING RESINS 

Total 

Alkyd resins, total 

Protective coatings: 

Phthalic anhydride type, total 

Unmodified 

Modified 

Polybasic acid type 

All other uses 3 

Sales for export 

Coumarone-indene and petroleum polymer resins, total- 
Floor tile 

Rubber compounding 

All other uses 

Sales for export 

Epoxy resins: 

Unmodified, total 

Bonding and adhesives 

Protective coatings 

Reinforced plastics 

All other uses 

Sales for export 

Modified 

Polyester resins,* total 

Reinforced plastics: 

Sheets, flat and corrugated 

All other 

Surface coatings 

All other uses 

Sales for export 



1,000 
pounds, 

11, 684-, 875 



4,452,975 
7,231,900 



3,236,701 



639,577 



562,618 

412,648 

149,970 

59,365 

17,594 



324,309 



84,727 

65,631 

173,951 



110,663 



8,559 
398,884 



1,000 
pounds, 

10,052,766 



1,000 
dollars 
2,504,433 



3,689,722 
6,363,044 



2,550,863 



873,501 
1,630,932 



662,392 



334,856 



88,679 



273,148 

207,438 

65,710 

46,701 

9,407 

5,600 

309,494 



74,289 

63,271 

144,623 

27,311 



105,681 
10,124 
48,080 
17,499 
19,224 
10,754 
2,935 

343,605 



73,167 
54,578 
18,589 
10,282 
3,536 
1,694 

30,569 



58,180 



3,390 
99,331 



32,841 

219,725 

6,500 

75,641 



pound 



.24 
.26 



See footnotes at end of table. 



6 See also table 15B, pt. Ill, which lists these products according to chemical composition, and identifies the manufacturers. 



PLASTICS AND RESIN MATERIALS 

TABLE 15A.-- Plastics and resin materials .- U.S. production and sales, by chemical classes 
and uses, i 965- -Continued 



39 



Kind and use 



THERMOSETTING RESINS— Continued 

Phenolic and other tar acid resins, total 

Molding materials 

Bonding and adhesive resins for— 

Laminating 

Coated and bonded abrasives 

Friction materials 

Thermal insulation 

Foundry or shell molding 

Plywood 

Fibrous and granulated wood 

All other bonding and adhesive uses 

Protective coatings, unmodified and modified-- 

All other uses 

Sales for export 

Polyurethane and diisocyanate resins 

Rosin modifications, total 

Rosin and rosin esters, unmodified (ester gums 
All other 

Urea and melamine resins, total 

Textile treating and coating resins 

Paper treating and coating resins 

Bonding and adhesive resins for — 

Laminating 

Plywood 

Fibrous and granulated wood 

All other bonding and adhesive uses 

Protective coatings 

All other uses (including molding) 

Sales for export 

All other thermosetting resins 6 

THERMOPLASTIC RESINS 

Total 

Cellulose plastics materials, total 

Sheets , continuous : 

Under 0.003 gage 

0.003 gage and over 

All other sheets, rods, and tubes 

Molding and extrusion materials 

Polyamide resins, total ' 

Nylon type 

Non-nylon type 

Styrene-type plastics materials: 

Production and sales 

Used by reporting companies in processing 

Sales and use, total 

Molding 

Textile and paper treating and coating 

Emulsion paint 

Extrusion 

All other uses 

Sales for export 

Vinyl resins (resin-content basis): 
Polyvinyl acetate resins: 

Production and sales 

Used by reporting companies in processing — 

See footnotes at end of table. 



921,753 



274,193 

132,732 
27,024 
32,623 

120,626 
68,782 

117,832 
31,815 
32,176 
34, 8H 
49,136 



66,209 
102,962 



Quantity 



62,279 
40,683 



621,179 



65,703 
50,758 

51,764 

135,125 

117,102 

15,138 

58,515 

127,074 



42,606 



8,448,174 



169,476 



24,104 

38,342 

8,316 

98,714 

92,076 



73,415 
18,661 



2,033,147 



313,160 



1,000 
pounds, 

dry 
basis' 

744,657 



246,140 

79,109 
22,013 
28,102 
52,576 
66,651 
110,589 
28,051 
28,580 
24,678 
44,164 
14,004 

55,443 

101,249 



1,000 
dollars 
178,799 



61,735 
39,514 



517,698 



31,226 
20,115 



59,571 
34,698 

34,686 
115,162 
103,054 

15,306 

35,373 
103,103 

16,745 

35,245 



7,501,903 



163,095 



24,350 

35,945 

8,921 

93,879 

73,383 



55,916 
17,467 



1,836,246 

184,245 

2,020,491 

1,063,005 

153,169 

43,062 

310,986 

325,843 

124,426 



220,354 
62,923 



11,321 
8,794 



129,227 



Unit 
value 1 



pound 



22,876 



1,842,041 



107,825 



65,376 
54,884 
10,492 



383,318 



67,974 



TABLE 15A.--Plastics and resin materials.- U.S. production and sales, by chemical classes 
and uses, 1965 — Continued 



Kind and use 



THERMOPLASTIC RES INS --Continued 

Vinyl resins (resin-content basis) — Continued 
Polyvinyl acetate resins — Continued 

Sales and use, total 

Emulsion paint 

Adhesives 

Bonding and sizing 

All other uses 

Sales for export 

Polyvinyl chloride and copolymer resins: 

Production and sales 

Used by reporting companies in processing 

Sales and use, total 

Calendering: 

Film, under 6 mils 

Sheet, 6 mils and over 

Flooring 

Coating, bonding, and adhesives: 

Paper and textile coating (including calendering)- 

Flooring 

Extrusion: 

Wire and cable 

Garden hose 

All other extrusions 

Molding: 

Records 

Slush and rotational molding 

All other moldings 

All other uses 

Sales for export 

All other vinyl resins: Production and sales 

Polyolefin plastics materials: 

Polyethylene, density 0.940 and below: 

Production and sales 

Used by reporting companies in processing 

Sales and use, total 

Injection molding 

Blow molding 

Extrusions: 

Film and sheet 

Wire and cable coating 

Extrusion coating on paper and other substrates — 

Pipe 

All other extrusions 

All other uses 

Sales for export 

Polyethylene, density over 0.940: 

Production and sales 

Used by reporting companies in processing 

Sales and use, total 

Injection molding 

Blow molding 

Extrusions: 

Film and sheet 

Wire and cable coating 

Pipe 

All other extrusions (including extrusion coating 

and filament) 

All other uses 

Sales for export 



1,837,467 



161,659 



Quantity 



1,000 
pounds , 

basis- 
283,277 
104,641 
111,064 
19,856 
45,074 
2,642 

1,715,321 

140,337 

1,855,658 

83,626 

250,374 
262,282 

180,884 
68,507 

217,214 
11,367 
254,781 

89,552 
43,070 
30,993 
294,913 
68,095 
9 154,936 



262,922 


2,046,006 




236,885 




2,282,891 




291,091 




40,468 




938,193 




215,946 




282,610 




19,381 




12,282 




179,326 




303,594 


784,441 


649,084 




90,835 




739,919 




130,111 




272,769 




37,539 




22,600 




29,759 




26,302 




133,254 




87,585 



1,000 
dollars 



Unit 
value 



$0.17 



78,915 



344,431 



119,861 



See footnotes at end of table. 



PLASTICS AND RESIN MATERIALS 

TABLE 15A. — Plastics and resin materials; U.S. production and sales, by chemical class 
and uses, 1 965- -Continued 



Kind and use 



Quantity 



Unit 
value 1 



THERMOPLASTIC RESINS— Continued 

Polyolefin plasties materials — Continued 
Polypropylene : 

Production and sales 

Used by reporting companies in processing — 

Sales and use, total 

Molding 

Extrusion 

All other uses (including export) 

All other thermoplastic resins ° 



1,000 
pounds, 

basis 2 
374,067 



419,759 



1,000 
pounds, 

basis 2 
300,934 
75,671 
376,605 
182,712 
135,991 
57,902 
342,544 



1,000 
dollars 
64,831 



312,321 



$0.22 



1 Calculated from rounded figures. 

2 For the purpose of this report, "dry basis" is defined as the total weight of the material, including resin, 
plasticizers, fillers, extenders, colors and stabilizers, and excluding water, solvents, and other liquid diluents. 

3 Includes saturated polyesters for urethanes. 

The term "polyester resins" includes unsaturated alkyds copolymerized with a monomer such as styrene, and 
polyallyl resins such as diallyl phthalate and allyl diglycol carbonate. 

5 Includes 448,650 thousand pounds of urea-formaldehyde type, and 172,529 thousand pounds of melamine-formaldehyde 
type. 

6 Includes data for acetone -formaldehyde resins, styrene-alkyd polyesters, toluenesulfonamide resins, silicone 
resins, and other thermosetting resins, which were produced in small quantities. 

Includes straight polystyrene, 728,435 thousand pounds; rubber modified polystyrene, 641,884 thousand pounds; 
styrene-butadiene copolymers, 253,146 thousand pounds; and all other, including ABS and SAN, 409,682 thousand 
pounds . 

8 Includes 37,373 thousand pounds of polyvinyl alcohol. 

Data for intra-company consumption may not be shown separately, and are included with sales at an estimated unit 
value . 

10 Includes data for acrylic, fluorocarbon, polycarbonate, polyoxymethylene, polyterpene, and other thermoplastic 
resins. 



of the Tariff Commission's monthly report on the production and sales of synthetic plastics and 
resin materials (S. O. C. Series P-65). However, data are included for plastics materials which 
are not covered in the monthly report and for a number of smaller producers that do not report 
monthly. The monthly data for 1965, moreover, were returned to the reporting companies for 
verification or correction. In consequence, many of the figures in the following table are revised 
from those shown in the monthly release of March 23, 1966, which contained yearend cumulative 
totals for 1965. The figures in the thermoplastics section of the table under "Used by reporting 
companies in processing" represent captive use of the materials. The quantities reported under 
"Sales and use" in this section include data for captive consumption, and for outside sales as 
defined in the introduction to this volume. 

In 1965, total U.S. production of synthetic plastics and resin materials, including cellu- 
losics, amounted to 11, 685 million pounds, or 15. 7 percent more than the 10, 103 million 
pounds reported for 1964. Sales of synthetic plastics and resin materials in 1965 amounted to 
10, 053 million pounds, valued at $2, 504 million. Production of benzenoid plastics and resin 
materials in 1965 amounted to 4,453 million pounds, and that of nonbenzenoid materials, to 
7, 232 million pounds. These figures compare with production in 1964 of 3, 915 million pounds, 
and 6, 188 million pounds, respectively. Production of all thermosetting resins in 1965 was 
3,237 million pounds, and that of thermoplastic resins was 8,448 million pounds. 

In 1965, polyethylene, polystyrene, and polyvinyl chloride resins were the materials 
produced in the largest volume. The total output of high-density and low-density polyethylene 
resins in 1965 amounted to 3, 047 million pounds, compared with 2, 613 million pounds in 1964. 
Sales of polyethylene resins in 1965 were 2, 695 million pounds, valued at $464 million. Produc- 
tion of styrene-type plastics materials in 1965 was 2, 033 million pounds, compared with 1, 728 
million pounds in 1964. Sales of such materials in 1965 were 1, 836 million pounds, valued at 
$383 million. The output of polyvinyl chloride and copolymer resins in 1965 amounted to 1, 837 
million pounds, compared with 1, 637 million pounds in 1964. Sales of polyvinyl chloride resins 
in 1965 totaled 1, 715 million pounds, valued at $297 million. Other synthetic plastics and resin 
materials produced in 1965 in large volume were phenolic and other tar acid resins (922 million 
pounds), alkyd resins (640 million pounds), urea and melamine resins (621 million pounds), 
polyester resins (399 million pounds), coumarone-indene and petroleum polymer resins (324 
million pounds), and polyvinyl acetate resins (313 million pounds). 



42 



SYNTHETIC ORGANIC CHEMICALS, 1965 



Rubber-Processing Chemicals 

Rubber-processing chemicals are organic compounds that are added to natural and synthetic 
rubbers to give them qualities necessary for their conversion into finished rubber goods. In this 
report, statistics are given for cyclic and acyclic compounds, by use--such as accelerators, 
antioxidants, and peptizers. Statistics on production and sales of rubber-processing chemicals 
in 1965 are given in table 16A. 7 

Production of rubber-processing chemicals as a group in 1965 amounted to 252 million 
pounds, compared with the 261 million pounds reported for 1964. This apparent decrease in 1965 
production was due principally to the reclassification of sodium 2-mercaptobenzothiazole (2- 
benzothiazolethiol, sodium salt) from rubber-processing chemicals to cyclic intermediates. 
Sales of rubber-processing chemicals in 1965 amounted to 194 million pounds, valued at $123 
million, compared with 184 million pounds, valued at $123 million, in 1964. 

TABLE 16A. — Rubber-processing chemicals.- U.S. production and sales , 1965 

[Listed below are all rubber-processing chemicals for which any reported data on production or sales may be pub- 
lished. (Leaders are used where the reported data are accepted in confidence and may not be published or where 
no data were reported. ) Table 16B in pt. Ill lists separately all rubber-processing chemicals for which data on 
production or sales were reported and identifies the manufacturer of each] 



Quantity 



Unit 
value 1 



Grand total 

RUBBER-PROCESSING CHEMICALS, CYCLIC 
Total 

Accelerators, activators, and vulcanizing agents, total 

Aldehyde-amine reaction products 

Dithiocarbamic acid derivatives 

Thiazole derivatives, total 

N-Cyclohexyl-2-benzothiazolesulfenamide 

2,2'-Dithiobis(benzothiazole) 

All other 

All other accelerators 

Antioxidants, antiozonants, and stabilizers, total 

Amino antioxidants, antiozonants, and stabilizers, total 
Aldehyde- and acetone-amine reaction products , total — 

Diphenylamine -ace tone condensate 

All other 

Substituted p-phenylenediamines, total 

NjN'-Diphenyl-p-phenylenediamine 

All other 

Octyldiphenylamine 

All other amino antioxidants, antiozonants, and 

stabilizers 

Phenolic and phosphite antioxidants and stabilizers, 

total 

Phenol, alkylated 

All other phenolic and phosphite antioxidants and 

stabilizers 

Blowing agents 

Peptizers 

All other cyclic rubber-processing chemicals, total 

N-Nitrosodiphenylamine (retarder) 

All other 3 

See footnotes at end of table. 



251,945 



193,718 



1,000 
dollars 
123,393 



211,403 



166,214 



109,204 



71,279 



55,841 



32,529 



239 
59,439 
7,228 
21,307 
30,904 
11,601 

127,537 



97,928 

9,374 

8,601 

773 

41,496 
1,732 

39,764 
2,189 

44,869 

29,609 
11,522 

18,087 

3,425 
4,950 

4,212 



1,086 

207 

44,077 

6,232 
10,805 
27,040 
10,471 

99,421 



3,224 



77,166 

7,991 

7,414 

577 

29,538 
1,479 

28,059 
1,982 

37,655 

22,255 
6,693 

15,562 

3,340 
4,404 

3,208 



971 
354 
22,907 
3,501 
5,386 
14,020 
8,297 

67,045 



2,254 
954 



50,380 

4,041 

3,594 

447 

27,249 
1,335 

25,914 
1,044 

18,046 

16,665 
3,508 

13,157 

4,698 
2,842 

2,090 



1,239 
851 



1.71 
.52 
.56 
.50 
.52 
.79 



.48 
.77 
.92 
.90 
.92 
.53 



.52 
.85 



1.41 
.65 



7 See also table 16B, pt. Ill, which lists these products alphabetically and Identifies the manufacturers. 



ELASTOMERS (SYNTHETIC RUBBERS) 
TABLE 16A. — Rubber-processing chemicals .- U.S. production and sales, 1965 — Continued 



43 



Quantity 



Unit 
value 1 



RUBBER-PROCESSING CHEMICALS, ACYCLIC 

Total 

Accelerators, activators, and vulcanizing agents, total 

Dithiocarbamic acid derivatives, total* 

Dibutyldithiocarbamic acid, zinc salt 

Diethyldithiocarbamic acid, zinc salt 

Dimethyldithiocarbamic acid, zinc salt 

All other 

Thiurams, total 5 

Bis(dimethylthiocarbamoyl) disulfide 

Bis(dimethylthiocarbamoyl) sulfide 

All other 

All other accelerators, activators, and vulcanizing 
agents 



1.000 
pounds 
40,542 



27,504 



1.000 
dollars 
14,189 



21,340 



Dodecyl mercaptans" 

Dimethyldithiocarbamic acid, sodium salt 

All other acyclic rubber-processing chemicals 7 



8,575 
1,522 
1,262 
1,478 
4,313 
12,379 
7,045 
1,561 
3,773 

386 

12,551 
3,469 
3,182 



14,144 



6,557 
1,559 
861 
1,288 
2,849 
7,324 
4,708 
1,338 
1,278 

263 

10,748 

2,612 



8,834 



4,802 

1,468 

523 

570 

2,241 

3,746 

2,036 

1,088 

622 

286 

4,218 
1,137 



.44 
.79 
.51 
.43 
.81 



.44 



1 Calculated from rounded figures. 

2 Not comparable with data for previous years owing to reclassification of certain products previously considered 
to be rubber-processing chemicals. 

3 Includes tackifiers and physical-property improvers. 

4 Data on dithiocarbamates included in this table are for materials used chiefly in the processing of natural and 
synthetic rubbers. Data on dithiocarbamates which are used chiefly as fungicides are reported in table 20A, "Pesti- 
cides and Other Organic Agricultural Chemicals . " 

5 Includes data for small amounts of tetramethylthiuram sulfides for uses other than in the processing of natural 
and synthetic rubbers. 

6 Includes some detergent -grade dodecyl mercaptans. 

7 Includes blowing agents, polymerization regulators, shortstops, and conditioning and lubricating agents. 



The output of cyclic rubber-processing chemicals in 1965 amounted to 211 million pounds. 
Sales in 1965 were 166 million pounds, valued at $109 million, compared with 162 million 
pounds, valued at $109 million, in 1964. Of the total output of cyclic rubber-processing chem- 
icals in 1965, accelerators accounted for 33.7 percent and antioxidants for 60.3 percent. Pro- 
duction of amino and phenolic and phosphite antioxidants, which amounted to 127. 5 million 
pounds in 1965, included 97. 9 million pounds of amino compounds and 29. 6 million pounds of 
phenolic and phosphite compounds. Sales of amino antioxidants in 1965 were 77.2 million pounds, 
valued at $50.4 million; sales of phenolic and phosphite antioxidants were 22. 3 million pounds, 
valued at $16. 7 million. 

Production of acyclic rubber-processing chemicals in 1965 amounted to 40. 5 million 
pounds, compared with the 38. 1 million pounds reported for 1964. Sales in 1965 totaled 27. 5 
million pounds, valued at $14. 2 million, compared with 22. 6 million pounds, valued at $14.4 
million, in 1964. Accelerators, principally dithiocarbamic acid derivatives and tetramethyl- 
thiuram sulfides, accounted for 52.6 percent of the output of acyclic rubber-processing chemi- 
cals in 1965. Dodecyl mercaptans accounted for 31.0 percent. Blowing agents, peptizers, 
modifiers, shortstops, and lubricating and conditioning agents accounted for the remainder of 
the output in the acyclic group. 



Elastomers (Synthetic Rubbers) 

The synthetic rubber industry in the United States continued to operate at a high level of 
capacity in 1965. The styrene-butadiene, or S-type, rubber is a general-purpose material used 
in the manufacture of tires and other rubber goods, and is the most important type of synthetic 
rubber, in terms of quantity produced. Several other types of synthetic rubbers are also pro- 
duced in large volume; among them are the polybutadiene-acrylonitrile type, or N-type, the 
polybutadiene-isoprene type, or Butyl-type, neoprene, and stereo elastomers. 



44 SYNTHETIC ORGANIC CHEMICALS, 1965 

The total output of all types of elastomers in the United States in 1965 amounted to 3, 592 mil- 
lion pounds --somewhat more than the 3,421 million pounds reported for 1964. Sales of elastomers 
covered in this report amounted to 3, 041 million pounds, valued at $843 million, in 1965, com- 
pared with 2, 958 million pounds, valued at $810 million, in 1964. Statistics on the production and 
sales of elastomers are given in table 17A.8 

Production of cyclic elastomers, which consisted chiefly of the polybutadiene-styrene type 
(S-type), amounted to 2,300 million pounds in 1965, compared with 2,332 million pounds in 1964. 
Sales of these elastomers amounted to 1, 898 million pounds, valued at $443 million, in 1965, com- 
pared with 1,961 million pounds, valued at $451 million, in 1964. Production of polyurethane type 
elastomers in 1965 amounted to 9. million pounds. 

The output of acyclic elastomers, including N-type, neoprene, Butyl, silicone, and stereo 
elastomers, amounted to 1,292 million pounds in 1965, compared with the 1, 089 million pounds 
reported for 1964. Sales of these elastomers amounted to 1, 143 million pounds, valued at $401 
million, in 1965, compared with 996 million pounds, valued at $359 million, in 1964. The output of 
silicone elastomers in 1965 amounted to 10. 9 million pounds, and that of stereo elastomers, to 
502 million pounds. 



TABLE 17A. — Elastomers (synthetic rubbers) : x U.S. production and sales, 1965 

[Listed below are all elastomers (synthetic rubbers) for which reported data on production or sales may be pub- 
lished. (Leaders are used where the reported data are accepted in confidence and may not be published or where 
no data were reported.) Table 17B in pt. Ill lists alphabetically all elastomers for which data on production or 
sales were reported and identifies the manufacturer of each] 



Qjjantity 



Unit value 2 



Grand total 

ELASTOMERS, CYCLIC 

Total 

Polybutadiene-styrene type (S-type) 

Polybutadiene-styrene-vinylpyridine type-- 
Polyurethane type 

ELASTOMERS, ACYCLIC 

Total 

Polybutadiene-acrylonitrile type (N-type)- 

Polyisobutylene-isoprene type (Butyl) 

Silicone elastomers 

Stereo elastomers, total 

Stereo polybutadiene 

All other stereo elastomers 

All other acyclic elastomers 



3,591,654 



3,041,163 



1,000 
dollars 
843,448 



2,271,647 
19,402 
9,043 



4 1,879,568 
10,432 
7,921 



1,143,242 



427,741 
6,650 
8,331 



400,726 



149, 858 
225,392 
10, 913 



111,695 
8,535 

410,508 



52,812 
30,425 
91,314 



362,278 
139,878 



287, 090 
123,418 



62,158 
29, 156 



$0.28 



.23 

.64 

1.05 



The term "elastomers" is defined as substances in bale, crumb, powder, latex, and other crude forms which can be 
vulcanized or similarly processed into materials that can be stretched at 68° F. to at least twice their original 
length and, after having been so stretched and the stress removed, will return with force to approximately their 
original length. 

2 Calculated from rounded figures. 

3 Elastomer-content basis. 

4 Partly estimated. 



Note. — Statistics on the production of S-type, 
cooperation with the U.S. Bureau of the Census. 



N-type, Butyl, neoprene, and stereo elastomers were compiled in 



8 see also table 17B, pt. m, which lists these products alphabetically and identifies the manufacturers. 



PLASTICIZERS 



45 



Plasticizers 

Plasticizers are organic chemicals that are added to synthetic plastics and resin materials to 
(1) improve workability during fabrication, (2) extend or modify the natural properties of these 
resins, or (3) develop new improved properties not present in the original resins. Plasticizers re- 
duce the viscosity of the resins and make it easier to shape and form them at high temperatures 
and pressures. They also impart flexibility and other desirable properties to the finished product. 
Statistics on production and sales of plasticizers are given in table 18A. 9 

TABLE 18A. --Plasticizers: 1 U.S. production and sales, 1965 



[Listed below are all plasticizers for which reported data may be published. (Leaders are used where the reported 
data are accepted in confidence and may not be published or where no data were reported.) Table 18B in pt. Ill 
lists all plasticizers for which data on production or sales were reported and identifies the manufacturer of 
each] 



Production 



Quantity 



Unit 
value 3 



Grand total 

PLASTICIZERS, CYCLIC 

Total 

Phosphoric acid esters: 

Cresyl diphenyl phosphate 

Tricresyl phosphate 

Phthalic anhydride esters, total 

Butyl octyl phthalates ( including butyl 2-ethyLhexyl 

phthalate) 

Dibutyl phthalates (including diisobutyl phthalate) — 

Dicyclohexyl phthalate 

Diethyl phthalate 

Dihexyl phthalate 

Diisodecyl phthalate 

Di(2-methoxyethyl) phthalate 

Dimethyl phthalate 

Dioctyl phthalates, total 

Di( 2-ethyLhexyl) phthalate 

Diiso-octyl phthalate 

Mixed dioctyl phthalates (including dioctyl iso- 

phthalates) 

Ditrideeyl phthalate 

Octyl decyl phthalates (including iso-octyl isodecyl 

phthalate) 

All other phthalic anhydride esters 

Trimellitic acid esters 

All other cyclic plasticizers 3 

PLASTICIZERS, ACYCLIC* 

Total- - 

Adipic acid esters, total 

Di( 2- ethylhexyl) adipate 

Diisodecyl adipate 

Diiso-octyl adipate ( including di-n-octyl adipate) 

Octyl decyl adipate ( including iso-octyl isodecyl 

adipate) 

All other 

See footnotes at end of table. 



1 000 
pounds 
1,073,197 



798,741 



19, 697 
34, 834 



678, 679 



15,052 

20,012 

7,719 

17,999 

1,702 

89, 552 

10,976 

4,408 

353, 108 

212,360 

121,589 

19,159 



25,416 
119, 847 



65,531 



274,456 



47,760 



1A,704 
9,582 
10,912 

10,065 
2,497 



1,000 

pounds 

1,021,623 



764,736 



17, 103 
37, 627 



646,366 



14, 934 
16,773 

12,035 

1,489 

89,112 

8,107 

3,937 

343,016 

211,466 

115,945 

15,605 
13,145 

25,856 
117,962 

1,981 
61,659 



256,887 



42, 950 



13,205 
8,162 



9,978 
11, 605 



214,392 



133,044 



4,447 
11,338 



97,772 



1,973 
3,1A0 

2,181 

231 

12,523 

1,669 

786 

47, 084 

28, 438 

16, 255 

2,391 
2,662 

4,41A 
21, 109 

801 
18,686 



81,348 



11, K5 



2,989 
2,181 



2,335 
3,640 



See also table 18B, pt. Ill, which lists these products alphabetically and identifies the manufacturers. 



SYNTHETIC ORGANIC CHEMICALS. 1965 



TABLE 18A. --plasticizers.- 1 U.S. production and sales , 1965 --Continued 



Production 



Quantity 



Unit 
value 2 



PLASTICIZERS, ACYCLIC— Continued 

Azelaic aeid esters ' 

Complex linear polyesters and polymeric plasticizers- 

Epoxidized esters, total 

Epoxidized soya oils 

2-Ethylhexyl epoxytallates 

Octyl epoxytallates 

All other 5 - 

Glycerol monoricinoleate 

Isopropyl myristate 

Isopropyl pa Imitate 

Oleic acid esters, total 

Butyl oleate 

Glycerol trioleate (Triolein) 

Isopropyl oleate 

Methyl oleate 

n-Propyl oleate 

All other 6 

Phosphoric acid esters 

Sebacic acid esters: 

Dibutyl sebacate 

Di(2-ethylhexyl) sebacate 

Stearic acid esters, total 

n- Butyl stearate 

All other 

Triethylene glycol di(caprylate-caprate) 

All other acyclic plasticizers 7 



13,167 
40, 265 

75,905 



49,484 



10,642 
15,779 



1,473 
1,008 

9,470 



3,106 

2,666 

168 

2,631 

698 

201 

13,851 

4,692 
5,711 



3,848 
3,848 



1,844 
51,614 



1,000 

pounds 
15,092 
37,759 

81,322 



54,158 
11,362 
9,788 
6,014 
258 
1,397 
942 

6,689 



1,681 

2,174 

139 

1,850 

664 

181 

12,197 

3,137 
5,509 

7,318 



3,540 
3,778 



1,536 
40,781 



1.000 
dollars 
4,435 
14,746 

21,450 



14,395 
2,420 
2,467 
2,168 

92 
626 

348 

1,443 



361 
475 



379 
136 



5,323 



1,908 
2,780 



1,749 



839 
910 



503 
14, 800 



.61 
.50 



.33 
.36 



1 Does not include data for clearly defined extenders or secondary plasticizers. 

2 Calculated from rounded figures. 

3 Includes data for glycol dibenzoates, phosphate esters (including triphenyl phosphate), toluenesulfonamides, 
tetrahydrofurfuryl oleate, trimellitic acid esters (production only), and other cyclic plasticizers. 

4 Dibutyl maleate is now published in table 21A, "Miscellaneous Chemicals." 

5 Includes several items that were included in earlier reports in "All other" oleic acid esters. 

6 Several items that were included here in earlier reports are now included in "All other" epoxidized esters. 

7 Includes data for citric and acetylcitric, lauric, myristic, palmitic, ricinoleic, sebacic, and tartaric acid 
esters, glycerol and glycol esters of certain fatty acids, glycerol tripropionate, and other acyclic plasticizers. 

Note. — The total production and sales statistics are included in this report for some items that are not used 
exclusively as plasticizers. 



Total U.S. production of plasticizers in 1965 amounted to 1, 073 million pounds — representing 
an increase of 12.8 percent over the output of 951 million pounds reported for 1964. Sales in 1965 
of the plasticizers covered by this report amounted to 1, 022 million pounds, valued at $214 mil- 
lion, compared with 905 million pounds, valued at $187 million, in 1964. 

Production of cyclic plasticizers in 1965, which consisted chiefly of the esters of phthalic 
anhydride and phosphoric acid, amounted to 799 million pounds, compared with 718 million pounds 
in 1964. Sales of cyclic plasticizers in 1965 amounted to 765 million pounds, valued at $133 mil- 
lion, compared with 690 million pounds, valued at $120 million, in the previous year. 

Production of acyclic plasticizers in 1965 amounted to 274 million pounds, compared with 234 
million pounds in 1964. Sales of acyclic plasticizers in 1965 amounted to 257 million pounds, 
valued at $81 million, compared with 215 million pounds, valued at $68 million, in 1964. Produc- 
tion of complex linear polyesters in 1965 amounted to 40 million pounds, and that of epoxidized 
esters, to 76 million pounds. Other products included in the acyclic class are the esters of 
adipic, azelaic, oleic, sebacic, and stearic acids. 



SURFACE-ACTIVE AGENTS 



47 



Surface-Active Agents 

The surface-active agents covered in this report include anhydrous potassium and sodium 
soaps, synthetic organic detergents, and dispersing, emulsifying, and wetting agents that function 
in either aqueous or nonaqueous systems. Waxes and plasticizers are not included. The data are 
reported in terms of 100-percent organic, surface-active ingredient, and thus exclude all inor- 
ganic salts, water, and other diluents. A major part of the output of surface-active agents is con- 
sumed in the form of packaged soaps and detergents for household and industrial use. The re- 
mainder is used as dispersing, emulsifying, foaming, penetrating, and wetting agents in the proc- 
essing of textiles and leather, in ore flotation and oil-drilling operations, and in the manufacture 
of agricultural sprays, cosmetics, elastomers, foods, lubricants, paints, pharmaceuticals, and 
many other products. 

Statistics on U.S. production and sales of surface-active agents in 1965 are given in table 
19A. 10 Total production of surface-active agents in 1965 amounted to 3, 170 million pounds. This 



TABLE 19A. — Surface-active agents ; U.S. production and sales, 1965 

[Listed below are all surface-active agents for which reported data on production or sales may be published. 
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data were 
reported.) Table 19B in pt. Ill lists all surface-active agents for which data on production or sales were reported 
and identifies the manufacturer of each] 



Production 1 



Sales" 



Quantity 1 



Unit 
value 3 



Grand total 

Amphoteric 

Anionic 

Cationic 

Nonionic 

BENZENOID SURFACE-ACTIVE AGENTS 

Total - 

Not Sulfated or Sulfonated 
Total 

Amides, ami nes, and quaternary ammonium salts, total — 

Benzyldimethyl( mixed alky 1) ammonium chloride 

Benzyldimethyloctadecylammonium chloride 

Benzyldodecyldimethylammonium chloride 

(3,4-Dichlorobenzyl) dodecyldimethylammonium chloride- 

( Dodecylbenzyl) trimethylammonium chloride 

Heterocyclic compounds, total 

l-Benzyl-2-heptadecyl-l-(2-hydroxyethyl)-2-imidazo- 
linium chloride-; 

All other 

Oxygen- containing compounds (except heterocyclic) 

All other 

Carboxylic acid esters and ethers, total 

Dinonylphenol, ethoxylated 

Dodecylphenol, ethoxylated 

Iso-octylphenol, ethoxylated 

Nonylphenol, ethoxylated 

Phenol, ethoxylated 

Other carboxylic acid esters and ethers 

Phosphoric and polyphosphorie acid esters, total 

Nonylphenol, ethoxylated and phosphated 

All other 

See footnotes at end of table. 



1,000 

pounds 

3,170,478 



5,112 

2,358,173 

148, 001 

659, 192 

1,371,320 



246,024 



8,127 



3,859 
378 
662 
46 
187 
637 

53 
584 
710 



232, 610 



3, 
19,645 
1,940 
129,394 
6,504 
71,322 

5,287 



4,264 
1,023 



1,000 

pounds 

1, 697, 862 



4,899 

1,077,582 

123,213 

492, 168 

877,202 



211,969 



7,760 



3,684 
359 
662 
44 
201 
608 

62 

546 

651 

1,551 

200,950 



2,613 
12,598 

120,243 

65,496 

3,259 



2,502 
757 



1,000 
dollars 
300, 188 



2,940 
133,393 
50, 542 
113,313 

96,153 



43,327 



6,796 



2,967 
312 
533 
28 
129 
654 

24 

630 

869 

1,304 

35,374 



551 
1,932 

18,887 

14,004 

1,157 



297 



.60 
.12 
.41 
.23 



1.15 

1.33 

.84 



.21 
.36 



10 See also table 19B, pt. in, which lists these products alphabetically and identifies the manufacturers. 



SYNTHETIC ORGANIC CHEMICALS, 1965 
TABLE 19A. — Surface-active agents.- U.S. production and sales , 1965 — Continued 



Chemical 



Sales 2 



Production 1 



Quantity 1 Value 



BENZENOID SUHFACE-ACTIVE AGENTS— Continued 

Sulfated and Sulfonated 

Total 

Aliylphenols, ethoxylated and sulfated, total 

Nonylphenol, ethoxylated and sulfated, and salts 

All other 

Benzenesulfonates, total 

Benzene-, cumene-, toluene-, and xylenesulfonates, total 

Xylenesulfonic acid, ammonium salt 

Xylenesulfonic acid, sodium salt 

All other 

Branched chain alkylbenzenesulf onates , total 

Dodecylbenzenesulfonic acid 

Dodecylbenzenesulfonic acid, calcium salt 

Dodecylbenzenesulfonic acid, isopropylamine salt 

Dodecylbenzenesulfonic acid ( mixed alkyl) amine salt 

Dodecylbenzenesulfonic acid, sodium salt 

Dodecylbenzenesulfonic acid, triethanolamine salt 

All other 

Straight chain alkylbenzenesulfonates, total 

Dodecylbenzenesulfonic acid 

Dodecylbenzenesulfonic acid, sodium salt 

Dodecylbenzenesulfonic acid, triethanolamine salt 

All other . 

Lignosulfonates, total 

Lignosulfonic acid, calcium salt 

Lignosulfonic acid, sodium salt 

All other 

Naphthalenesulfonates, total 

Butylnaphthalenesulfonic acid, sodium salt 

Diisopropylnaphthalenesulfonic acid 

All other 

Other benzenoid surface- active agents, sulfated and 

sulfonated* 

NONBENZENOID SUHFACE-ACTIVE AGENTS 

Total - - 

Not Sulfated or Sulfonated 

Total 5 — - — 

Amides, amines, and quaternary ammonium salts, total 

Amines, amine oxides, and amine salts (except hetero- 
cyclic), total 

Amine salts of fatty acids (anionic) 

Amines, not containing oxygen, and salts thereof, 

total 

Amine salts ( cationic) 

Diamines and polyamines, total 

N-( 9-0ctadecenyl) trimethylenediamine 

N-( Tallow alkyl) trimethylenediamine • 

All other 

Primary monoamines, total 6 

(Coconut oil alkyl) amine 

Dodecylamine 

( Hydrogenated tallow alkyl) amine 

Octadecylamine 

(Tallow alkyl) amine 

All other 



1,125,296 



16,729 



4,329 
12,400 



643,179 



78,458 

24,043 

21,558 

32,857 

174, 650 

47,441 

11, 296 

3,722 

670 

88,424 

2,718 

20,379 

390,071 

261,264 

1,113 

127, 694 



288, 165 
44,015 
115,027 

9,626 



943 

481 

8,202 



8,555 



1,799,158 



1,440,633 



944 

48,478 
1,914 
8,839 
1,201 
4, K)l 
3,537 

24,273 
1,544 
1,934 

13,063 

727 

4,736 

2,269 



1,000 
pounds 
665,233 



210,208 



74,093 
23,456 
18, 276 
32,361 
83, 170 
14, 382 
8,800 
3,814 
279 
49,069 
2,754 
4,072 
52,945 
12,606 
37,300 

3,039 

428,055 



269,728 
43, 902 
114,425 

6,780 



6,780 
20, 190 

820, 660 



423,098 



171,396 



59,452 
812 

43,291 
1,861 
8,413 
1,280 
4,003 
3,130 

21,958 
1,299 
1,427 

13,098 

660 

3,620 

1,854 



1,000 
dollars 
52,826 



27, 670 



5,153 
1,573 
1,599 
1,981 
1/4,645 
2,152 
2,318 
1, 1/42 
93 
7,409 
629 
902 
7,872 
1,799 
5,484 

589 

14,985 



6,020 
3,391 
5,574 

2,664 



2,664 



7,507 



204, 035 



125,616 



61,527 



20,300 
561 

1A, 105 

626 
2,795 

518 
1,408 

869 
6,61/4 

610 

778 
2,992 

303 
1,065 

866 



See footnotes at end of table. 



SURFACE-ACTIVE AGENTS 
TABLE 19A. — Surface-active agents; U.S. production and sales , 1 965 --Continued 



49 



NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 

Not Sulfated or Sulfonated— Continued 

Amides, amines, and quaternary ammo nium salts — Continued 
Amines, amine oxides, and amine salts ( except 
heterocyclic) — Continued 

Amines, not containing oxygen, and salts 
thereof — Continued 
Secondary and tertiary monoamines 6 

Oxygen-containing amines and amine oxides, total 

(Mixed alkyl) amine, ethoxylated 

(Tallow aliyl) amine, ethoxylated 

All other 

Fatty acid - alianolamine condensates, total- 

Diethanolamine condensates, total 

Capric acid 

Coconut oil acids (amine/acid ratio=2/l) 

Coconut oil acids (amine/acid ratio=]/l) 

Laurie acid 

Oleic acid (amine/acid ratio^2/l) 

Oleic acid (amine/acid ratio=l/l) 

Stearic acid 

Tall oil acids 

All other 

Other alianolamine condensates, total 

Coconut oil acids - ethanolamine condensate 

Laurie acid - ethanolamine condensate 

Laurie acid - isopropanolamine condensate 

Stearic acid - ethanolamine condensate ( amine/acid 

ratio=l/l) 

All other 

Fatty acid - diamine and polyamine condensates, total 

Oleic acid - diethylenetriamine condensate 

Oleic acid - ethylenediamine condensate ( amine/acid 
ratio=l/2) 

All other 

Fatty acid - diamine and polyamine condensates, 

alioxylated, total 

Oleic acid - ethylenediamine condensate, 

monoethoxylated 

Stearic acid - ethylenediamine condensate, 

monoethoxylated 

All other 

Heterocyclic amines and quaternary ammonium salts, total 

Imidazoline derivatives, total 

2-HeptadecyI-l-(2-hydroxyethyl) -2- imidazoline 

All other 

Morpholine, oxazoline, and piperazine derivatives 

Quaternary ammonium salts (except heterocyclic), total — 

Bis( coconut oil alkyl) dimethylammonium chloride 

Bis(hydrogenated tallow a llsyl) dimethylammonium 

chloride 

Dimethyldioctadecylammonium chloride 

Dodecyltrimethylammonium chloride 

Oxygen- containing compounds 

Other quaternary ammonium salts 

N-Substituted amino acids and polypeptides, total 

N-Lauroylsarcosine, sodium salt 

All other 

Other amides, amines, and quaternary ammonium salts, 

total 

Hydrogenated tallow acids - ethanolamine condensate, 
ethoxylated 

Oleic acid - ethanolamine condensate, ethoxylated 

All other 



Production 1 



13,452 

2,782 

1,086 

( 7 ) 

85,912 

68, U7 

96 

17, 194 

21,526 

20,654 

1,652 

1,262 

1,877 

470 

3,416 

17, 765 



Quantity 1 



1,000 

pounds 

11,059 

15,349 

2,593 

1,051 

11,705 

58,531 

52,493 



21,109 

1,328 
1,231 
1,609 
204 
27,012 
6,038 
2,312 



498 






662 


672 


223 


113 


113 


41 


16,492 


2,941 


1,018 


17, 837 


17, IK) 


6,461 


912 


767 


222 


96 


98 


33 


16, 829 


16,245 


6,206 


8,531 


5,519 


4,597 


4,261 






3,913 


2,476 


2,405 


357 


3,043 


2,192 


9,173 


7,866 


3,553 


7,112 


6,470 


2,762 


481 


473 


212 


6,631 


5,997 


2,550 


2,061 


1,396 


791 


17, 890 


18, 169 


6,476 


1,334 


1,228 


695 


12,894 


13,349 


3,106 


164 


157 


86 


100 


124 


143 


1,361 


1,298 


933 


2,037 


2,013 


1,513 


5,840 


3,569 


1,662 


2,663 






3,177 


3,569 


1,662 




1,180 


647 


250 


277 


100 


103 


108 


74 


7 ) 


795 


473 



1,000 

dollars 

4,070 

5,634 

1,150 

746 

3,738 

17,831 

15,997 



5,850 



424 

415 

759 

43 

8,506 

1,834 

552 



See footnotes at end of table. 



50 



SYNTHETIC ORGANIC CHEMICALS, 1965 
TABLE 19A. -Surface-active agents; U.S. production and sales, 1 965 --Continued 



Production 1 



Sales 2 



Quantity 1 Value 



NONBENZENOID SURFACE-ACTIVE AGENTS--Continued 

Not Sulfated or Sulfonated--Continued 

Carboxylic acid esters, total 

Ethylene glycol and diethylene glycol esters, total— 

Diethylene glycol monolaurate 

Diethylene glycol mono-oleate 

Diethylene glycol monostearate 

Ethylene glycol distearate 

Ethylene glycol monostearate 

All other 

Glycerol esters, total 

Complex glycerol esters 

Glycerol esters of chemically defined acids, total- 

Glycerol monolaurate 

Glycerol mono-oleate 

Glycerol monostearate 

All other 

Glycerol esters of mixed acids 

Polyethylene glycol esters, total 

Polyethylene glycol esters of chemically defined 

acids, total 

Polyethylene glycol dilaurate 

Polyethylene glycol dioleate 

Polyethylene glycol distearate 

Polyethylene glycol monolaurate 

Polyethylene glycol mono-oleate 

Polyethylene glycol monostearate 

All other 

Polyethylene glycol esters of mixed acids, total — 

Polyethylene glycol ester of castor oil acids 

Polyethylene glycol ester of coconut oil acids — 

Polyethylene glycol ester of rosin acids 

Polyethylene glycol ester of tall oil acids 

Polyethylene glycol ester of tallow acids 

All other 

Polyglycerol esters 

Other carboxylic acid esters, total 

Anhydrosorbitol tall oil ester 

Anhydrosorbitol trioleate 

Anhydrosorbitol tristearate 

Ethoxylated anhydrosorbitol monolaurate 

Ethoxylated anhydrosorbitol mono-oleate 

Ethoxylated anhydrosorbitol monopalmitate 

Ethoxylated anhydrosorbitol monostearate 

Ethoxylated anhydrosorbitol trioleate 

Ethoxylated anhydrosorbitol tristearate 

1, 2-Propanediol monolaurate 

1, 2-Propanediol monostearate 

All other 

Ethers, total 

Castor oil, ethoxylated ■ 

n-Dodecyl alcohol, ethoxylated 

Lanolin, ethoxylated 

Mixed linear alcohols, ethoxylated 

9-0ctadecenyl alcohol, ethoxylated 

n-Octadecyl alcohol, ethoxylated 

Tridecyl alcohol, ethoxylated 

All other 



1,000 
pounds 
146,815 



5,179 
519 
77 
911 



2,868 
68, 233 

4,006 

29,399 

81 

3,481 
24,524 

1,313 
34, 828 
24,344 

18,464 

1,067 

3,219 

327 

4,762 

3,205 

4,693 

1,191 

5,880 

999 

461 

435 

3,686 

140 

159 

956 

48, 103 

468 

563 

375 

3,007 

4,316 

320 

2,496 

407 

775 

144 

1,122 

34, 110 

189,975 



3,087 

631 

101, 877 

3,438 

514 

8,029 

72,399 



1,000 
pounds 
112,226 



1,000 
dollars 
37,053 



4,531 

509 

58 

561 

255 

653 

2,495 

59,252 

3,012 

27,956 

57 

3,043 

23,076 

1,780 

28,284 

15,845 

10,567 

818 

651 

282 

2,058 

2,283 

3,686 

789 

5,278 

" 354 

"3,243 

W-9 

1,532 

885 

31,713 

390 

64 

2,526 

3,724 

2,238 
393 

151 

1,047 

21, 180 

117,226 



2,619 

1,937 

268 

75,580 

2,404 

398 

7,293 

26,727 



1,485 

156 

16 

171 

76 

251 

815 

15,912 

1,325 

7,769 

21 

726 

6,495 

527 

6,818 

5,702 

4,187 
283 
242 
100 
821 
888 

1,406 
447 

1,515 



594 

413 

13,541 

152 

23 

1,085 

1,592 

982 
176 

61 

628 

8,842 

21,154 



SgT 

859 

87 

9,407 

1,128 

185 

1,638 

6,969 



See footnotes at end of table. 



SURFACE-ACTIVE AGENTS 
TABLE 19A. — Surface-active agents ; U.S. production and sales, 1965- 



Chemical 



Production- 1 - 



Quantity 1 



NONBENZENOID SURFACE- ACTIVE AGENTS— Continued 
Not Sulfated or Sulfonated— Continued 

Fatty, rosin, and tall oil acids, potassium and sodium 

salts, total 8 

Coconut oil acids, potassium and sodium salts 

Oleic acid, potassium salt 

Oleic acid, sodium salt 

Stearic acid, potassium and sodium salts 

Tall oil acids, potassium and sodium salts, total 

Potassium salt 

Sodium salt 

Tallow acids, sodium salt 

All other 

Phosphoric and polyphosphoric acid esters, total 

2-Ethylhexyl phosphate, sodium salt 

2-Ethylhexyl polyphosphate 

All other 

Sulfated and Sulfonated 

Total 5 

Alcohols, sulfated, total 

n-Dodecyl sulfate salts, total 

n-Dodecyl sulfate, ammonium salt 

n-Dodecyl sulfate, sodium salt 

n-Dodecyl sulfate, triethanolamine salt 

n-Dodecyl sulfate, all other salts 

All other sulfated alcohols 

Amides, amines, and quaternary ammonium salts, sulfated 

and sulfonated, total 

Coconut oil acids - ethanolamine condensate, sulfated, 

potassium salt 

N-Methyl-N-oleoyltaurine 

Quaternary ammonium sulfates 

Sulfosuccinamie acid derivatives 

All other 

Carboxylic acid esters (except natural fats and oils), 

sulfated and sulfonated, total 

Esters of sulfated oleic acid, total 

Isopropyl oleate, sulfated 

Propyl oleate, sulfated 

All other 

Sulfosuccinic acid esters, total 

Sulfosuccinic acid, bis (2-ethylhexyl) ester 

Sulfosuccinic acid, dihexyl ester 

Sulfosuccinic acid, ditridecyl ester, sodium salt 

All other 

Other carboxylic acid esters, sulfated and sulfonated 

Ethers, sulfated and sulfonated, total 

n-Dodecyl alcohol, ethoxylated and sulfated, sodium salt 
All other 

Natural fats and oils, sulfated, total 

Castor oil, sulfated 

Coconut oil, sulfated 

Cod oil, sulfated 

Grease, other than wool, sulfated 

Neat's- foot oil, sulfated 

Peanut oil, sulfated 

Soybean oil, sulfated 

Sperm oil, sulfated 

Tallow, sulfated 

All other 



1,000 



3,361 



101,505 
2,845 
2,035 
2,265 
29, 775 
1/4,460 
15,315 
473,326 
286, 610 

6,656 



249 

380 

6,027 



106, 986 



41,899 
1,961 

15,889 
9,712 

1A,337 
( 7 ) 

15,042 



30 
3,021 
8,767 
1,760 
1,464 



3,701 
1,094 
508 
2,099 
6,817 
4,774 



( 7 ) 



298 
757 



2,120 
( 7 ) 



29,507 



5,518 
2,758 
2,224 

659 
1,253 
1,121 

279 
6,490 
8,272 

933 



1,000 
pounds 



1,000 
dollars 



312 
948 



14, 916 



( 7 ) 



5,186 



232 

380 

4,574 



116,471 



29,644 



1,930 
12,459 
5,467 

9,788 
14,559 



30 
2,943 
8,559 
1,707 
1,320 



11,343 

3,147 

550 

750 

1,847 

6,291 

4,347 

955 

305 

684 

1,905 



42,531 



1,542 
40,989 

18,394 



3,851 

805 

1,625 

589 

1,007 
150 
3,278 
6,061 
1,028 



154 

312 

2,117 



( 7 ) 
3,244 



72 

105 

3,067 



35,297 



12,922 



825 
6,233 
1,755 

4,109 



6,727 



31 

1,458 

3,112 

986 

1,140 

5,812 



1,013 
211 
186 
616 

3,381 

2,464 
328 
187 
402 

1,418 

5,859 



499 
5,360 

3,977 



1,228 
163 
275 

136 
281 

sa 

630 
947 
259 



See footnotes at end of table. 



52 



SYNTHETIC ORGANIC CHEMICALS, 1965 
TABLE 19A. --Surface-active agents; U.S. production and sales , 1965 --Continued 









Sales 2 




Chemical 


Production 1 


















Quantity 1 


Value 


Unit 
value 3 


NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 










Sulfated and Sulfonated- -Continued 










Other nonbenzenoid surface- active agents, sulfated and 
sulfonated: 


1.000 

7,206 
694 


1,000 
pounds 

( 7 ) 

( 7 ) 


1,000 

dollars 

C) 

( 7 ) 


Per 


Nonbenzenoid surface-active agents 
for which separate data cannot be shown 










Total 9 — - - 


251,539 


281,091 


43,122 


$0.15 



All quantities are given in terms of 100-percent organic surface-active ingredient. 

2 Sales include products sold as bulk surface-active agents only. 

3 Calculated from rounded figures. 

4 Includes sales of alkylphenols, ethoxylated and sulfated. 

5 Total shown includes only those products and groups for which separate data are published below. 

6 These products were included in the "Miscellaneous Chemicals" section in previous years. 

7 Data are not separately publishable but are included in the total shown below for "Nonbenzenoid surface- active 
agents for which separate data cannot be shown." 

8 Includes production of approximately 884- million pounds not previously reported. 

9 Includes production of "all other" oxygen-containing amines and amine oxides, "all other" ami des, amines, and 
quaternary ammonium salts, and "all other" sulfated and sulfonated alcohols, carboxylic acid esters, and ethers; 
includes sales of "all other" potassium and sodium salts of fatty, rosin, and tall oil acids, and of sulfated oleic 
acid and sulfated tall oil; also includes production and sales of "all other" nonbenzenoid surface- active agents, 
not sulfated or sulfonated, and of "all other" nonbenzenoid surface-active agents, sulfated and sulfonated. 

total includes data for fatty monoamines, which in previous years were reported in the section on 
miscellaneous organic chemicals, and for potassium and sodium salts of fatty, rosin, and tall oil 
acids (soaps), which were for the most part not reported in previous years. U.S. production in 
1965, exclusive of materials reported for the first time, amounted to approximately 2,248 mil- 
lion pounds--6. 1 percent more than the 2, 119 million pounds reported for 1964, and 13. 5 percent 
more than the 1, 981 million pounds reported for 1963. Sales of bulk surface-active agents in 1965 
amounted to 1, 698 million pounds, valued at $300 million. These figures reflect sales of bulk 
surface-active agents only and cannot be compared with sales data for previous years, which 
included surface-active agents sold as active ingredients in formulated and packaged products, as 
well as strictly bulk materials. 

Production of anionic surface- active agents in 1965 amounted to 2, 358 million pounds, or 
74.4 percent of the total; sales amounted to 1, 078 million pounds, valued at $133 million. Of the 
anionic products for which individual statistics are shown in the table, those produced inlargest 
quantity were tallow acids, sodium salt, 473 million pounds; lignosulfonic acid, calcium salt, 288 
million pounds; straight chain dodecylbenzenesulfonic acid, sodium salt, 261 million pounds; 
coconut oil acids, potassium and sodium salts, 102 million pounds; and branched chain dodecyl- 
benzenesulfonic acid, sodium salt, 88 million pounds. 

Production of those surface-active agents which are generally considered to be nonionic 
amounted to 659 million pounds, or 20.8 percent of the total output for 1965; sales amounted to 
492 million pounds, valued at $113 million. The most important nonionic products, in terms of 
quantity, were nonylphenol, ethoxylated, 129 million pounds, and mixed linear alcohols, ethoxy- 
lated, 102 million pounds. 

Production of cationic materials totaled 148 million pounds, or 4. 7 percent of the total; 
sales amounted to 123 million pounds, valued at $51 million. Production of amphoteric materials 
amounted to 5 million pounds, or approximately 0. 2 percent of the total; sales amounted to 5 
million pounds, valued at $3 million. 



Pesticides and Other Organic Agricultural Chemicals 

This section of the report covers pesticides (fungicides, herbicides, insecticides, and 
rodenticides) and other organic agricultural chemicals, such as plant hormones, seed disinfec- 
tants, soil conditioners, and soil fumigants. The data are given in terms of 100-percent active 
material; they thus exclude such materials as diluents, emulsifiers, synergists, and wetting 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS 



53 



agents. Statistics on production and sales of pesticides and other organic agricultural chemicals 
in 1965 are given in table 20A. 

Production of pesticides and other organic agricultural chemicals in 1965 amounted to 877 
million pounds—about 12 percent more than the 783 million pounds reported for 1964. Sales in 
1965 were 764 million pounds, valued at $497 million, compared with 692 million pounds, valued 
at $427 million in 1964. 

The output of cyclic pesticides and other chemicals included in the cyclic group amounted to 
683 million pounds in 1965--about 17 percent more than the 585 million pounds produced in 1964. 
Sales in 1965 were 582 million pounds, valued at $378 million, compared with 523 million 
pounds, valued at $317 million, in 1964. 

Production of acyclic pesticides and other acyclic organic agricultural chemicals in 1965 
amounted to 195 million pounds, compared with the 198 million pounds reported for 1964. Sales 
in 1965 were 182 million pounds, valued at $119 million, compared with 170 million pounds, 
valued at $111 million, in 1964. The apparent decrease in production was caused by the transfer 
of several chlorothiophosphates used as intermediates, to the acyclic miscellaneous chemicals 
section. 

TABLE 20A. — Pesticides and other organic agricultural chemicals .• U.S. production and sales , 1965 

[Listed below are all pesticides and other organic agricultural chemicals for which any reported data on production 
or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be 
published or where no data were reported.) Table 20B in pt. Ill lists all pesticides and other organic agricul- 
tural chemicals for which data on production or sales were reported and identifies the manufacturer of each ] 



Quantity 



Unit 
value 1 



Grand total 

PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICALS, CYCLIC 

Total- — 

Fungicides, total 

Mercury fungicides 

Naphthenic acid, copper salt 

Pentachlorophenol (PCP) 

Pentachlorophenol, sodium salt 

2,4, 5-Trichlorophenol and salts 

All other 2 - - 

Herbicides and plant hormones, total 

2-sec-Butyl-4, 6-dinitrophenol, ammonium salt 

Phenoxyacetic acid derivatives: 

(2, 4-Dichlorophenoxy) acetic acid (2,4-D) 

( 2, 4-Dichlorophenoxy) acetic acid esters and salts, 

total 

(2, 4-Dichlorophenoxy) acetic acid, n-butyl ester 

(2, 4-Dichlorophenoxy) acetic acid, dimethylamine salt 

(2, 4-Dichlorophenoxy) acetic acid, ethyl ester 

(2, 4-Dichlorophenoxy) acetic acid, iso-octyl ester 

(2, 4-Dichlorophenoxy) acetic acid, isopropyl ester 

All other 

(2,4, 5-Trichlorophenoxy) acetic acid (2,4,5-T) 

(2, 4, 5-Trichlorophenoxy) acetic acid esters and salts, 

total 

(2,4,5-Trichlorophenoxy)acetic acid, n-butyl ester — 
(2,4, 5-Trichlorophenoxy) acetic acid, iso-octyl ester 

All other : 

Phenylmereury acetate (PMA) 

All other 3 - - — 

Insecticides and rodenticides, total 

Aldrin-toxaphene group 4 

Hexachlorocyclohexane (Benzene hexachloride) and 

lindane 5 

See footnotes at end of table. 



1,000 
pounds 
877, 197 



1,000 
pounds 
763, 905 



1,000 
dollars 
497,066 



682,671 



582,344 



377, 858 



87,378 



1,602 
3,268 
39,965 
11,113 
12,969 
18,461 

215,307 



73,328 



1,367 
3,101 
33,320 
12,646 

22,894 

142,123 



24,208 



4,265 

902 

4,625 

2,661 

11,755 

169,478 



63,320 

63,360 

12,084 
13,872 

9,580 

27, 824 
11,601 

13,516 
6,485 
2,292 
4,739 
588 

62, 863 

379,986 



118, 832 



26,049 

47,299 
10,925 
11,435 
628 
7,948 
3,053 
13,310 



13,176 
5,820 
2,401 
4,955 
375 

55,168 

366,893 



110,794 
6,948 



7,664 

21, 179 
4,51A 
4,743 
158 
3,007 
955 
7,802 



9,674 
3,449 
1,831 
4,394 
2,615 
128,275 

184, 172 



49,644 
1,440 



■ 33 

3.12 

.29 



.25 
.38 



.73 
.59 
.76 
.89 
6.97 
2.33 

.50 



11 



See also table 20B, pt. Ill, which lists these products alphabetically and identifies the manufacturers. 



54 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 20A. --Pesticides and other organic agricultural chemicals ; U.S. production and sales, 1965 — Continued 



Production 



Quantity 



Unit 

value 1 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICALS, CYCLIC— Continued 
Insecticides and rodenticides, total — Continued 

Organophosphorus insecticides , total 

0, O-Diethyl O-(p-nitrophenyl) phosphorothioate 

(Parathion) 

0, O-Dimethyl O-(p-nitrophenyl) phosphorothioate 

(Methyl parathion) 

All other 6 

l,l,l-Trichloro-2,2-bis(p-ehlorophenyl) -ethane (DDT) 

All other 7 

PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICALS, ACYCLIC 
Total 

Fungicides, total 

Dime thyldithiocarb ami c acid, ferric salt (Ferbam) 

Ethylene bis(dithiocarbamic acid), disodium salt (Nabam) 

Ethylene bis(dithiocarbamic acid), zinc salt (Zineb) 

All other 8 

Herbicides and plant hormones, total 9 

Insecticides, rodenticides, and soil conditioners and 

fumigants, total 

Bromome thane (Methyl bromide) 

l,2-Dibromo-3-chloropropane 

Organophosphorus insecticides 10 

All other insecticides, rodenticides, and soil 

conditioners and fumigants 11 



1,000 
pounds 
62,029 

16,607 

29,111 

16,311 

140,785 

58,340 



194,526 



55,186 

14,198 

27,440 
13,548 
141,451 
52,514 



181,561 



1.000 
dollars 
63,778 

10,427 

20,662 
32,689 
20,458 
48,852 



119,208 



36,456 



33,014 



25,943 



2,384 
2,489 
5,075 
26,508 

47,617 
110,453 



14,303 
3,433 
33,299 

59,418 



1,745 

2,141 

4,468 

24,660 

40,746 
107,801 



15,127 
3,893 
30,557 

58,224 



675 

813 

2,012 

22,443 

37,798 
55,467 



6,605 
2,013 
39,051 

7,798 



pound 



$1.16 

.73 

.75 

2.41 

.14 

.93 



■ 66 
.79 



.38 
.45 



.52 
1.28 



1 Calculated from rounded figures. 

2 Includes captan, dichlone, glyodin, sodium pentaehlorophenate, tri- and tetrachlorophenols, and others. 

3 Includes dimethylurea compounds, dinitrophenol compounds, endothal, isopropyl carbanilates (IPC and CIPC), 
maleic hydrazide, triazines, and others. 

* Includes aldrin, chlordane, dieldrin, endrin, heptachlor, terpene polyehlorinates, and toxaphene. 

5 Production of gamma isomer content is not publishable because publication would reveal the operations of the 
individual producers. Sales of gamma isomer content in benzenehexachloride and lindane totaled 2.0 million pounds. 

6 Includes carbophenothion, diazinon, other phosphorothioates and phosphorodithioates, and others. 

7 Includes DDD, endosulfan, methoxychlor, tetradifon and other chlorinated insecticides, 1-naphtnyl methylcar- 
bamate, small amounts of rodenticides and insect repellents, hexachlorocyclohexane and lindane (production only), 
and others. 

8 Includes dodine, mercury compounds, maneb, and others. 

9 Includes CDAA, methanearsonic acid, disodium salt, thiocarbamate and organophosphorus herbicides, sodium 
dichloropropionate, sodium TCA, and others. 

10 Includes DDVP, ethion, malathion, naled, phorate, TEPP, and others. 

11 Includes soil conditioners and fumigants, small quantities of rodenticides, and others. 



Miscellaneous Chemicals 



As used in this report, the term "miscellaneous chemicals" refers to those synthetic organic 
products that are not included in the use groups covered in the preceding sections of the report. 
These miscellaneous chemicals, which account for about three- fifths of the output of all synthetic 
organic chemicals, include products that are employed in a great variety of uses; the number of 
chemicals used exclusively for only one purpose is not large. Among the products covered are 
those used for gasoline and lubricating oil additives, paint driers, photographic chemicals, 
tanning materials, flotation reagents, refrigerants, textile polymers, sequestering agents, or- 
ganic fertilizers, antifreeze chemicals, solvents, and acyclic intermediates. 

Production of miscellaneous chemicals in 1965 amounted to 50.8 billion pounds, or 11.3 
percent more than the output of 45. 7 billion pounds reported for 1964. Sales of miscellaneous 
chemicals in 1965 amounted to 22. billion pounds, valued at $2. 9 billion, compared with 20. 5 
billion pounds, valued at $2. 7 billion, in 1964. Statistics on production and sales of miscellane- 
ous chemicals in 1965 are given in table 21A. 12 



" See also table 21B, pt. Ill, which lists these products alphabetically and identifies the manufacturers. 



MISCELLANEOUS CHEMICALS 55 

TABLE 21A. — Miscellaneous chemicals; U.S. production and sales, 1965 

[Listed below are all miscellaneous chemicals for which any reported data on production or sales may be published. 
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data 
were reported. ) Table 21B in pt. Ill lists alphabetically all miscellaneous chemicals for which data on produc- 
tion or sales were reported and identifies the manufacturer of each] 



Quantity 



Grand total 

MISCELLANEOUS CHEMICALS, CYCLIC 

Total 

Benzoic acid salts: Sodium benzoate, tech. and U.S.P- 

Benzoyl peroxide 

Cyclopropane 

2, 6-Di-tert- butyl- p-cresol: 

Food grade 

Tech 

4- Ethylmorpholine 

Flotation reagents 

Gasoline additives, total 2 

N, N'-Di-sec-butyl-p-phenylenediamine 

N, N'-Disalicylidene-l, 2-propanediamine 

All other 

Hexamethylenetetramine, tech 

Lubricating oil and grease additives, total 

Oil-soluble petroleum sulfonate, barium salt 

Oil- soluble petroleum sulfonate, calcium salt 

Oil-soluble petroleum sulfonate, sodium salt 

All other 

Morpholine 

Naphthenic acid salts, total 3 4 

Calcium naphthenate 

Cobalt naphthenate 

Iron naphthenate 

Lead naphthenate 

Manganese naphthenate 

Zinc naphthenate 

All other 

Photographic chemicals: 

Benzotriazole 

p-Diethylaminobenzenediazonium chloride (p-Diazo-N, 

N-diethylaniline) - zinc chloride 

N, N-Diethyltoluene-2, 5- diamine, monohydrochlori.de 

Pinene 

Propyl gallate 

Tall oil salts, total 3 

Calcium tallate 

Cobalt tallate 

Iron tallate 

Lead tallate 

Manganese tallate 

Zinc tallate 

All other 

Tanning materials, synthetic, total 

2-Naphthalenesulfonic acid, formaldehyde condensate 

and salts . 

All other 

See footnotes at end of table. 



pounds 
50, 835, 600 



22,040,070 



1,000 
dollars 
2, 890, 169 



1,138,261 



9,111 

4,835 

126 

7,298 
15,150 
1,086 
5,828 

10,905 
2,064 



8,841 
49,344 
354,1 



45,963 
110, 801 

73, 678 
124,247 

15,831 

21,493 



1,887 
3,364 

381 
12,796 
1,474 
1,049 

542 



127 
156 



29,852 
77 



8,679 



"785" 

2,400 

596 

3,847 

851 

26 

174 

34,225 



29,779 
4,446 



624, 813 



7,474 

4,734 

126 

6,761 

12,147 
974 



6,540 



2,169 

853 

3,518 

34,318 

210, 198 



11, 604 

47,422 
151, 172 

W,248 

18,756 



1,399 
2,780 

252 
11,014 
1,159 

992 
1,160 



103 
162 



23,612 



8,153 



639 
2,441 

445 
3,609 

800 
32 

187 

33,376 



28, 902 
4,474 



244,750 



2,216 
4,580 
1,726 

3,836 
6,687 
1,120 



5,697 



1,915 
1,241 
2,541 

6,064 

50,280 



2,820 



9,467 
37, 993 



6,673 
6,61A 



599 

1,909 

90 

2,602 

435 

362 

617 



254 
452 



3,000 
237 



2,814 



207 
1,287 
134 
893 
227 
9 
57 

7, 666 



5,392 
2,274 



56 



SYNTHETIC ORGANIC CHEMICALS. 1965 
TABLE 21A. — Miscellaneous chemicals; U.S. production and sales , 1965- 



Qaantity 



MISCELLANEOUS CHEMICALS, CYCLIC— Continued 

Textile chemicals, other than surface-active agents — 
All other miscellaneous cyclic chemicals 

MISCELLANEOUS CHEMICALS, ACYCLIC 

Total 

Acetaldehyde 

Acetic acid, synthetic, IWf, 5 

Acetic acid salts, total 

Copper acetate 

Potassium acetate 

Sodium acetate 

Zinc acetate 

Zirconium acetate 

All other 

Acetic anhydride, 100$, from all sources 

Acetone, total 

From cumene 

From isopropyl alcohol 

All other 

Acrylic acid 

Acrylonitrile 

Adipic acid 

Alcohols, monohydrie, unsubstituted, total 

Alcohols C 9 or lower, total 

Butyl alcohols, total 

Iso ( Isopropylcarbinol) 

Normal ( n-Propylcarbinol) 

All other 

Ethyl alcohol, synthetic 6 

2-Ethyl-l-hexanol 

Hexyl alcohol 

Iso-octyl alcohols 

Isopropyl alcohol 

Methanol, synthetic 

All other 

Alcohols C 10 or higher, total 

Decyl alcohols 

1-Hexadecanol (Cetyl alcohol) (95$) 

1-Octadecanol (Stearyl alcohol) (95$) 

All other - 

Amines, total 7 

Butylamine 

Dihutylamine 

Diethylamine 

Dimethylamine 

Ethylamine 

Isopropylamine 

Methylamine, mono- - 

Trimethylamine 

All other- 

Bis(2-chloroethyl) ether ( Dichlorodiethyl ether) , all 

grades 

2-Butanone (Methyl ethyl ketone) 

2-Butanone oxime 

2-Butanone peroxide 

Butyl acetates, total 

Normal 

All other 

See footnotes at end of table. 



1,000 
pounds 

2,820 
566,587 



49,697,339 



1,230,310 
1,346,683 



25,412 



200 

3,138 

16,331 

524 

182 

5,037 

1,531,738 

1, 124, 097 



746, 879 
377,218 

40, 938 
771,622 
865,719 

8, 295, 247 



7,926,726 
827,568 

428, 807 

398,761 

2,039,211 

293,203 

8,335 

126, 742 

1,537,988 

2,868,578 

225, 101 

368,521 

105,942 

2,678 

259,901 

694, 809 



1,206 
2,409 
7,006 
50,005 
8,329 

30,532 

14,085 

581,237 



317,500 
2,735 
1,676 

131,511 



86, 116 
45,395 



1,956 
241,070 



21,415,257 



1,000 
dollars 
1,923 
132,741 



2,645,419 



101,920 
294,468 



23,799 



206 

3,045 

15,662 

323 

4,563 

179, 672 



296,305 

417,691 

27, 669 

7,594 

303,339 

69,991 

4, 241, 634 



4,095,746 

391,484 

67, 962 

291,711 

31,811 

1,315,353 

149,410 

2,183 

112, 668 

581,509 

1,395,137 

148,002 

145,888 

68, 280 

2,752 

6,912 

67,944 

163,652 



1,805 
22,918 

6,789 
26,574 

6,316 
99,250 



1,981 

301, 161 

2,807 

1,622 

123,274 



80,430 
42,844 



6,617 
19, 883 



5,017 



127 

596 

2,398 

183 

1,713 



11, 908 

20,964 

1,127 

2,162 

48,354 
16,446 

266, 120 



242, 869 
36,041 

5,087 
27,383 

3,571 
76, 688 
16,337 
366 
12,852 
35, 982 
43,881 
20,722 
23,251 

8,024 
742 

1,202 
13,283 

49,440 



4,080 

1,177 

3,848 

846 

38, 6 M 



175 

32,376 
1,704 
2,541 

11, 817 



7,781 

4,036 



MISCELLANEOUS CHEMICALS 
TABLE 21A. -- Miscellaneous chemicals.- U.S. production and sales , 1965— Continued 



57 



Production 



Quantity 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

tert- Butyl hydroperoxide 

tert- Butyl peroxide (Di-tert-butyl peroxide) 

Butyric acid 

Caprolactam (Hexahydro-2H-azepin-2-one) 

Carbon disulfide 

Cellulose esters and ethers, total 

Cellulose esters, total 

Cellulose acetate 

All other 

Cellulose ethers, total 

Sodium carboxymethylcellulose, 100$ 

All other 

Chloral (Trichloroaeetaldehyde) 

Chloroacetic acid, mono- 

Chloroacetic acid, methyl ester 

2-Chloro-N, N-dimethylethylamine ( Dimethylaminoethyl 

chloride) hydrochloride 

Decanoyl peroxide 

Dibutyl fumarate 

Dibutyl maleate 

2-Diethylaminoethanol 

Diethylene glycol 

Dilauryl 3,3'-thiodipropionate 

2-Dimethylaminoethanol 

Dioctyl maleate 

Dipropylene glycol 

Erucamide 

Ethanolamines, total 

2-Aminoethanol (Monoethanolamine) 

2,2'-Iminodiethanol (Diethanolamine) 

2, 2 ', 2 " -Nitrilotriethanol ( Triethanolamine) 

2- Ethoxyethanol (Ethylene glycol monoethyl ether) 

2-(2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl 

ether) ; 

2-[2-(2-Ethoxyethoxy)ethoxy]ethanol (Triethylene glycol 

monoethyl ether) 

Ethyl acetate, 85$ 

Ethyl acrylate 

Ethylene glycol 

Ethylene oxide 

Ethyl ether, all grades 

2-Ethylhexanoic acid (a-Ethylcaproic acid) salts, total- 
Calcium 2-ethylhexanoate 

Cobalt 2-ethylhexanoate 

Lead 2-ethylhexanoate 

Manganese 2- ethylhexanoate 

Zinc 2-ethylhexanoate 

All other 

2-Ethyl-l-hexyl acetate 

2-Ethyl-l-hexyl acrylate 

Formaldehyde, 37$ by weight 

Formic acid, 90$- 

Formic acid salts 

Fu marie acid 

Gluconic acid, tech 

Gluconic acid, sodium salt, tech 

Halogenated hydrocarbons, total 

1-Bromobutane (n- Butyl bromide) 

Carbon tetrachloride 

Chlorinated paraffins 

Chlorodifluoromethane 

Chloroethane (Ethyl chloride) 

Chloroform 

Chloromethane (Methyl chloride) 

See footnotes at end of table. 



1,000 
pounds 

145 
1,011 

290,005 
756,512 

930, 700 



839,392 
669, 112 
170, 280 
91,308 
48, 770 
42, 538 

73,502 

71,063 

585 

353 

667 

6,120 

7,513 

3,159 

158, 746 

1,180 

1,794 

494 

33, 904 

451 

200, 836 



67,474 
77, 500 
55,862 



33,733 

6,933 

114,013 

116,796 

1, 797, 935 

2,189,798 

93,164 

4,404 



604 

227 

59 

276 

3,238 

25, 200 
3, 106, 572 
23, 657 
30,518 
33,749 
3,891 
8.01A 

9,362,119 



593, 636 
43,750 

685,768 
152,510 
187,549 



1,000 
pounds 

VA 

1,020 

478 

133,612 

541, 605 

278,425 



193,324 

193,324 
85,101 
45,242 
39, 859 



532 

239 
651 
5,494 
5,419 
2,589 
134, 994 
1,168 
1,458 

30,602 
429 

155,038 



54,108 
52,413 
48,517 

. 46,560 

25,467 

3,310 

100, 197 

47,407 

1,197,846 

255,952 

85, 174 

3,261 



~27T~ 
503 
178 
56 
259 
1,991 

608 
20,529 
1,189,434 
23,241 
25,023 
31,615 
3,501 
7,559 

4,042,963 



1,000 
dollars 

286 

1,672 

144 

41,900 

'21,691 

113,408 



66,528 

66, 528 
46,880 
19,057 
27,823 



190 

301 

897 

1,098 

1,054 

1,122 

13,675 

1,152 

981 

3,652 
51A 

27,708 



10,667 
8,176 
8,865 

7,716 

4,446 

543 
10,425 
10,901 
104,237 
25,994 
5,429 

3,173 



A3 

509,439 
43,635 
49,815 
273,944 
123,320 
94,791 



110 

549 

68 

27 

129 

2,290 

169 
5,752 
30, 199 
2,993 
1,233 
5,181 
1,135 
2,270 

458,045 



32 
37,486 
5,698 
30, 193 
18,576 
9,871 
6,437 



58 SYNTHETIC ORGANIC CHEMICALS, 1965 

TABLE 21A. — Miscellaneous chemicals; U.S. production and sales , 1965- 



Chemical 



Production 



Quantity 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Halogenated hydrocarbons — Continued 

Dichlorodifluorome thane 

1, 2-Dichloroethane (Ethylene dichloride) 

Dichloromethane (Methylene chloride) 

1, 2-Dichloropropane (Propylene dichloride) 

Dichlorotetrafluoroethane 

Iodomethane (Methyl iodide) 

Lauryl chlorides 

Tetrachloroethylene (Perchloroethylene) 

Trichloroethylene 

Trichlorofluoromethane 

Vinyl chloride, monomer ( Chloroethylene) 

All other 

4-Hydroxy-4-methyl-2-pentanone (Diacetone alcohol) 

Isoascorbie acid, sodium salt 

Isopropyl acetate 

Isopropyl ether 

Lauroyl chloride 

Lauroyl peroxide 

Linoleic acid salts, total 3 

Calcium linoleate 

Cobalt linoleate 

All other 

Lubricating oil additives, total 

Phosphorodithioates ( Dithiophosphates) 

Sulfurized lard oil 

Sulfurized sperm oil 

All other 

Maleic anhydride 

Mercaptoacetic acid ( Thioglycolic acid) 

Mercaptoacetic (Thioglycolic) acid derivatives, total 

2-Aminoethyl mercaptoacetate (Monoethanolamine 

thioglycolate) 

Ammonium mercaptoacetate 

Iso-oetyl mercaptoacetate 

All other 

2-Methoxyethanol (Ethylene glycol monomethyl ether) 

2-(2-Methoxyethoxy) ethanol (Diethylene glycol monomethyl 

ether) 

2- [2-(2-Methoxyethoxy) ethoxy] ethanol (Triethylene glycol 

monomethyl ether) 

Methyl acetate 

Methyl ether (Dimethyl ether) 

4-Methyl-2-pentanone (Methyl isobutyl ketone) 

Nylon, 6 and 6/6 polymer for fiber- 

Oleic acid salts, total 8 

Copper oleate 

All other 

Oxalic acid 

Oxalic acid salts 

Palmitic acid salts 

Pal ml toy 1 chloride 

Pentaerythritol 

Pentaerythritol tetranitrate 

Phosgene (Carbonyl chloride) 

Phosphorus acid esters, not elsewhere specified, total — 

Tributyl phosphate 

All other 

See footnotes at end of table. 



271,408 

2,455,907 

210,830 

61,013 

21,762 

14 

911 

429,354 

434,510 

170,461 

2,000,000 

1, 642, 667 



2,835 
45,483 



9,526 
1,333 



138 

197 
124 

417, 817 



102, 269 

2,562 

23,668 

289,318 

128,226 



5,904 



272 
1,599 

4,033 

73,801 

11,416 

3,128 

8,887 

10,393 

168, 874 

980, 596 

282 



247 

19,573 

6,664 

758 

225 

69,338 

4,959 

284,671 

26,988 



4,702 
22,286 



1,000 



poi 



nds 



254, 202 

309, 033 

194,504 

31,122 

18,812 
9 

384, 978 
428, 120 
153, 953 
687,817 
485,426 

28,004 
2,386 

38,033 
4,199 

1,345 

467 



138 

329 

184, 798 



48, 146 



136, 652 



94,411 
558 



5,394 



1,729 
3,431 



66, W7 



151,027 



20,752 
6,803 



69,396 
2,767 



23,445 



4,753 
18, 692 



1,000 

dollars 

72, 191 

13,932 

17, 207 

729 

10, 947 

26 

32,447 
36, 068 
31,318 
42, 178 
92,709 

3,574 

3,288 

4,018 

346 

1,401 

151 



26 

125 

39, 937 



11, 968 



27, 969 



10,976 
525 



6,982 



181 



1,254 
5,547 



11,233 



17,944 



3,782 
1,542 



15,415 
2,111 



9,943 



1,883 
8,060 



59 



TABLE 21A. — Miscellaneous chemicals.- U.S. production and sales , 1965— Continued 



Quantity 



MISCELLANEOUS CHEMICALS, ACXCLIC--Continued 

Polyacrylic acid salts 

Polyethylene glycol 

Polypropoxy ethers, total 

Glycerol tri(polyoxypropylene) ether 

All other 

Polypropylene glycol 

Propionic acid 

Propionic acid salts: 

Calcium propionate 

Sodium propionate 

Propylene glycol ( 1, 2-Propanediol) 

Propylene oxide 

Sarcosine and salt 

Sequestering agents, total 

(Wethylenetrinitrilo)pentaacetic acid, sodium salt-- 
( Ethylenedinitrilo) tetraacetic acid ( Ethylenediamine- 

tetraacetic acid) 

( Ethylenedinitrilo) tetraacetic acid, tetrasodium salt- 
( Ethylenedinitrilo) tetraacetic acid, monohydrogen 

trisodium salt 

(N-Hydroxyethylethylenedinitrilo) triacetic acid, 

trisodium salt 

All other 

Sodium formaldehydesulfoxylate 

Sodium methoxide (Sodium methylate) 

Sorbitol 

Stearand.de ( Octadecanamide) 

Stearic acid salts, total 9 

Aluminum stearates, total 

Aluminum distearate 

Aluminum monostearate 

Aluminum tristearate 

Calcium stearate 

Lead stearate 

Lithium stearate 

Magnesium stearate 

Zinc stearate 

All other 

Tallow amide, hydrogenated 

Tetraethyllead 

Tetramethyllead and tetra(methyl and ethyl) leads 

Triethylene glycol 

Urea in compounds or mixtures (100$ basis), total 

In feed compounds 

In liquid fertilizer 

In solid fertilizer 

All other 

See footnotes at end of table. 



1,000 
pounds 
2,492 
39, 698 

220, 923 



161,250 
59, 673 

94,059 
31,870 

12,248 
4,369 

212,756 

604, 559 

1,698 

35,764 



Ijf 



3,528 
19, 985 



3,721 
6,057 

5,466 

4,891 

62,471 

764 

37,546 



5,469 

3,913 
895 
661 
12,674 
421 
593 

2,370 
12,020 

3,999 

686 
549, 176 
137, 609 
50, 667 

2,572,923 



300, 865 

943,218 

1,092,818 

236, 022 



1,000 
pounds 
3,326 
35,129 

190,858 



134,476 
56,382 

80,416 
16,801 

10,398 
5,168 

188, 933 
69, 254 



26, 662 



1,734 



1,914 
13,736 



3,266 
5,430 

5,253 
4,267 
45,525 



34,433 



5,306 

3,797 

883 

626 

12,324 

372 

522 

2,323 

12,000 

1,586 



548, 177 
136,038 
41, 733 

2,466,882 



1.000 
dollars 
4,030 
8,571 

36,896 



25,767 
11,129 

Li, 085 
1,806 

1,930 

960 

19,709 

8,298 



10, 668 



557 
999 



1,468 
2,408 

1,266 
1,386 
10, 001 



12,588 



305,309 

915,203 

1,085,567 

160, 803 



1,931 

1,366 
341 
224 

4,188 
146 
264 
888 

4,424 
747 



297,480 
78,001 
7,024 

1 99,587 



12,410 

36,791 

43,399 

6,987 



60 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 21A. — Miscellaneous chemicals: U.S. production and sales , 1965 — Continued 



Quantity 



Unit 
value 1 



MISCELLANEOUS CHMICALS, ACYCLIC— Continued 

Vinyl acetate, monomer 

Zinc formaldehydesulfoxylate 

All other miscellaneous acyclic chemicals 



1,000 
pounds 
511,951 
1,490 
6,349,894 



1,000 
pounds 
259,099 
1,454 
1,582,690 



1,000 
dollars 
27, 837 
657 
443,025 



pound 

$0.11 
.45 
.28 



1 Calculated from rounded figures. 

2 Statistics exclude production and sales of tricresyl phosphate. Statistics on tricresyl phosphate are given in 
the section "Plasticizers." 

3 Quantities are given on the basis of solid naphthenate, tallate, or linoleate content. 

* Statistics exclude production and sales of copper naphthenate. Statistics on copper naphthenate are given in 
the section "Pesticides and Other Organic Agricultural Chemicals." 

5 In addition, sales of recovered acetic acid totaled 76,641 thousand pounds, valued at 4,466 thousand dollars. 

6 Statistics on production of ethyl alcohol from natural sources by fermentation are issued by the Alcohol Tax 
Unit, U.S. Internal Revenue Service. 

7 Statistics exclude production and sales of fatty amines. Statistics on fatty amines are given in the section 
"Surface- Active Agents. " 

8 Statistics exclude production and sales of potassium and sodium oleates. Statistics on these oleates are in- 
cluded in the section "Surface- Active Agents." 

5 Statistics exclude production and sales of potassium and sodium stearates. Statistics on these stearates are 
included in the section "Surf ace- Active Agents." 

10 Production of urea in primary solution totaled 2,789,089 thousand pounds. 

11 Includes estimated values for sales of urea in nitrogen compounds. 



The total output of miscellaneous cyclic chemicals in 1965 was 1. 14 billion pounds, or 2. 1 
percent more than the output of 1. 11 billion pounds reported for 1964. Sales in 1965 totaled 625 
million pounds, valued at $245 million, compared with 604 million pounds, valued at $224 million, 
in 1964. The most important subgroup of cyclic compounds was the lubricating oil additives, the 
output of which was 355 million pounds in 1965. 

Total production of miscellaneous acyclic chemicals in 1965 was 49. 7 billion pounds--ll. 5 
percent more than the output of 44. 6 billion pounds reported for 1964. Sales in 1965 totaled 21.4 
billion pounds, valued at $2. 6 billion, compared with 19. 9 billion pounds, valued at $2. 4 billion, 
in 1964. 

Production of alcohols and halogenated hydrocarbons in 1965 each exceeded that of any of the 
use groups of synthetic organic chemicals except cyclic intermediates and plastics and resin 
materials. Production of monohydric, unsubstituted alcohols totaled 8.3 billion pounds in 1965, 
or 4. 5 percent more than in 1964. Alcohols are used as solvents, intermediates, and antifreeze 
materials, and for other purposes. Production of halogenated hydrocarbons totaled 9.4 billion 
pounds in 1965, or 15.4 percent more than the 8. 1 billion pounds reported for 1964. Halogenated 
hydrocarbons are used as solvents, intermediates, refrigerants, and aerosol propellants, and 
for other purposes. 

Individual chemicals the output of which exceeded 1 billion pounds in 1965 were formaldehyde 
(3. 1 billion pounds, compared with 2. 8 billion pounds in 1964); synthetic methanol (2. 9 billion 
pounds, compared with 2. 6 billion pounds in 1964); urea (2.6 billion pounds, compared with 2.4 
billion pounds); dichloroethane (2. 5 billion pounds, compared with 2. 2 billion pounds); ethylene 
oxide (2. 2 billion pounds, in each year); ethyl alcohol (2. 04 billion pounds, compared with 2. 07 
billion pounds); vinyl chloride (2.0 billion pounds, compared with 1.6 billion pounds); ethylene 
glycol (1.8 billion pounds, in each year); isopropyl alcohol (1.5 billion pounds, in each year); 
and acetic anhydride (1. 5 billion pounds, compared with 1.4 billion pounds). 



PART IE. ALPHABETICAL LIST OF INDIVIDUAL PRODUCTS, BY GROUPS, 
AND NAMES OF MANUFACTURERS 



This section of the report consists of (1) a series of tables that supplement the statistical 
information given in parts I and II, and (2) a Directory of Manufacturers. The tables with num- 
bers that include the letter "B" supplement the tables in part I or part II with numbers that in- 
clude the letter "A"; for example, table 8B in part III supplements table 8A in part II. 

Each table in part III lists alphabetically the individual items in each group for which data 
on production or sales were reported for 1965. The tables include data on only those chemicals 
for which the volume of production or sales in 1965 exceeded 1,000 pounds or for which the value 
of sales exceeded $1,000. Where separate statistics for an item are given in the tables in part I 
or part II, an asterisk (*) precedes the name of the item in the tables in part III. The manufac- 
turers of each product are indicated by identification codes which are listed in the Directory of 
Manufacturers (table 22). A few companies, however, have specifically requested that they not 
be identified as having produced or sold certain items. These manufacturers are indicated by a 
small letter "x" in the tables. 



Tar Crudes 
TABLE 4B. — Tar crudes for which U.S. production or sales were reported, identified by manufacturer , 1965 

[Tar crudes for which separate statistics are given in table 4A are marked below with an asterisk (*); products not 
so marked do not appear in table 4A because the reported data are accepted in confidence and may not be published. 
Manufacturers' identification codes shown below are taken from table 22. Table 22 identifies all U.S. producers of 
tar crudes (except producers that report to the Division of Bituminous Coal, U.S. Bureau of Mines)] 



Manufacturers ' identification codes 
(according to list in table 22 J 1 



*Crude light oil 

Light-oil distillates: 

*Benzene, specification and industrial grades 

*Toluene, specification and other grades 

*Xylene, all grades 

^Solvent naphtha 

*A11 other light-oil distillates 

Pyridine crude bases 

*Naphthalene , crude, solidifying at — 

*Less than 74° C 

*74° C. to less than 76° C 

*76° C. to less than 79° C 

Crude tar-acid oils having a tar-acid content of — 

5<f> to less than 24$ 

24$ to 51$ 

Cresylic acid, crude 

*Creosote oil (Dead oil): 

^Distillate as such 

^Creosote in coal-tar solution 

All other distillate products 

*Tar, road 

*Tar for other uses: 

Crude 

Refined 

Pitch of tar: 

Soft and medium (water softening points less than 
110° F., and 110° F. to 160° F.).. 

*Hard (water softening point above 160° F.) 

Pitch-of-tar coke and pitch emulsion 



ACY, 


KPP. 










ACY, 


KPP. 










ACY, 


KPP. 










ACY, 


KPT, 


NEV, 


PAI. 






ACP, 


PAI. 










ACP, 


KPT. 










COP. 












KPT. 












ACP, 


KPT, 


PRD, 


RIL. 






ACP, 


RIL. 










ACP, 


KPT, 


RIL. 








ACP, 


KPT, 


PRD. 








ACP, 


CBT, 


COP, 


HUS, 


KPT, 


RIL, WTC 


ACP, 


JEN, 


KPT, 


RIL. 






ACP, 


KPT, 


PAI. 








ACP, 


KPT, 


RIL, 


WTC. 






KPT, 


RIL. 










ACP, 


KPT, 


RIL, 


RUR. 






ACP, 


CBT, 


COP, 


JEN, 


KPT, 


RIL. 


ACP, 


COP, 


HUS, 


KPT, 


RIL. 




JEN, 


RIL. 











1 Does not include manufacturers ' identification codes for producers that report to the Division of Bituminous 
Coal, U.S. Bureau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey, Aug. 10, 
1966, entitled "Coke Producers in the U.S. in 1965." 

2 Crude light oil production and sales of this company are not included with the U.S. Bureau of Mines figures 
given in table 4A. 

61 



62 



SYNTHETIC ORGANIC CHEMICALS, 1965 



Crude Products From Petroleum and Natural Gas for Chemical Conversion 



TABLE 5B. — Crude products from petroleum and natural gas for chemical conversion for which U.S. production 
or sales were reported, identified by manufacturer, 1965 

[Crude products from petroleum and natural gas for chemical conversion for which separate statistics are given in 
table 5A are marked below with an asterisk (*); products not so marked do not appear in table 5A because the 
reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown be- 
low are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the 
designated product] 



Manufacturers ' identification codes 
(according to list in table 22) 



AROMATICS AND NAPHTHENES 

*Alkyl aromatics, distillates, and solvents 

^Benzene (except motor grade): 

*Benzene, 1° 

*Benzene, 2° 

Cresylic acid, crude 

*Naphthalene, all grades 

*Naphthenic acids: 

Acid number lower than 150 

Acid number 150-199 

Acid number 200-224 

Acid number 225-249 

Sodium carbolate and phenate, crude 

*Toluene : 

^Nitration grade, 1° 

*Pure commercial grade, 2° 

Solvent grade 

All other 

*Xylenes, mixed: 

Aviation grade 

*3°~ — 

5° 

All other 

All other aromatics and naphthenes 

ALIPHATIC HYDROCARBONS 

Ci hydrocarbon: Methane 

*C2 hydrocarbons: 

^Acetylene 

*Ethane 

^Ethylene 

C2 and C3 hydrocarbons, mixed 

*C3 hydrocarbons: 

*Propane 

Propane -propylene mixture 

*Propylene 

*Ci, hydrocarbons: 

*1,3-Butadiene, grade for rubbers (elastomers)' 

*Butadiene and butylene fractions 



ACC, DUP, EN J, FG, GOC, JCC, MOC, MON, CMC, PLC, SHC, 
SM, SOC, SOG, USI, VPT. 

ACU, APR, ASH, ATR, CCP, COR, CSD, DLH, DXS, ENJ, GOC, 
GRS, MOC, MON, PLC, PRO, RIC, SHO, SKO, SM, SNT, SUN, 
TOC, TX, VPT. 

ACC, AMO, CO, DOW, SHO, SOC, UCC. 

ATR, PRD, RIC, SHO. 

ASH, COL, MON, SUN, TID. 

RIC, SUN, TX. 
PRD, RIC, SM, SOC, SUN. 
PRD, RIC, SM, SOC. 
PRD, RIC, SM, SOC. 
ATR, GOC, SIN. 

ASH, ATR, COR, CSD, DLH, ENJ, GOC, LEN, MOC, MON, PLC, 
PRO, SHC, SHO, SIN, SNT, SOG, SUN, TOC, TX, UCC, VPT. 

DOW, MON, RIC. 

CO, FG, SKO. 

ACC, CSD, CSO, DXS, ELP, GRS, RIC, SHO, SM, SOC, TOC, 
TX, VPT. 

CSD, CSO, SOG. 

ASH, ATR, COR, DLH, MON, PRO, SNT. 

SIN, SUN, TX. 

AMO, CCP, CSD, ENJ, GRS, LEN, MOC, RIC, SHO, SM, SOC, 

SOG, SUN, TOC, VEL, VPT. 
COR, ELP, ENJ, JCC, LEN, PAS, PLC, SM, SOI. 



CCP, MOC, MON, PAN. 

ACY, DOW, DUP, MNO, MON, UCC, x. 

ACU, CCP, ENJ, MOC, MON, PAN, PLC, SHC, SHO, SM, SOI, 

TX, UCC, USI. 
CCP, DOW, DUP, EKX, ELP, ENJ, GOC, JCC, KPP, MOC, MON, 

OMC, PET, PLC, RIC, SHC, SM, SNO, TX, UCC, USI. 
COR, GYR, MON, PLC. 



AMO, ASH, CCP, CSD, DXS, ENJ, GRS, 
SHM, SHO, SIN, SM, SNT, SOG, SOI, 

GOC, TX. 

AMO, ASH, CCP, DOW, EKX, ELP, ENJ, 
PET, PLC, RIC, SHC, SHO, SIN, SM, 
UCC, UOC. 

CPY, DOW, ELP, ENJ, FRS, GGC, ILC, 

SHC, SM, SOC, SPI, TID, TUS, UCC. 

DOW, GYR, PLC, PTT, SHC, SHO, SIN, 



MOC, OMC, 
SPI, UCC, 



GOC, JCC, 
SOG, SOI.. 



PAN, PLC, 
UOC, USI. 



MOC, MON, 
SPI, SUN, 



MON, PET, PLC, PTT, 
SOC. 



CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS 



63 



TABLE 5B. —Crude products from petroleum and natural gas for chemical conversion for which U.S. production 
or sales were reported, identified by manufacturer, 1965 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



ALIPHATIC HYDROCARBONS— Continued 

*C* hydrocarbons — Continued 

*n-Butane 

1-Butene 

2-Butene 

*1-Butene and 2-butene mixture 

*Isobutane 

*Isobutylene 

All other 

*d hydrocarbons: 

Isopentane ( 2-Methylbutane ) ; 

Isoprene (2-Methyl-l,3-butadiene) 

n-Pentane 

All other : 

C6 hydrocarbons: 

Diisopropyl (2,3-Dimethylbutane) 

Hexane 

Neohexane (2,2-Dimethylbutane) 

All other 

C7 hydrocarbons: 

n-Heptane 

*Heptenes, mixed 

All other 

Cs hydrocarbons: 

*Diisobutylene (Diisobutene) 

n-Octane 

2,2,4-Trimethylpentane (Iso-octane) 

All other 

Hydrocarbons, C9 and above: 

Eicosane 

*Nonene ( Tripropylene ) 

Pentadecene 

*Polybutene 

*Tetrapropylene 

Tridecene concentrate 

Triisobutylene 

All other 

*Hydrocarbon derivatives : 

1-Butanethiol 

tert-Butyl mercaptan (2-Methyl-2-propanethiol) 

Di-tert-butyl disulfide 

Ethyl mercaptan (Ethanethiol) 

Isopropyl mercaptan 

Methyl mercaptan (Methanethiol) 

tert-Octyl mercaptan 

n-Propyl mercaptan (1-Propanethiol) 

All other '■ 

*A11 other aliphatic hydrocarbons: Alpha olefins, molecular 
weight ranges: 

C6"C7 

C8-C10 

C11-C15 

Cl6 _ C20 

All other 



COR, CSD, DXS, ELP, GRS, MOC, OMC, PAN, PLC, SHO, 

SM, SNT, SOC, SOG, SOI, UCC, USI. 
PLC, PTT. 
MON, PLC, PTT. 

AMD, ENJ, GOC, PLC, PRO, PTT, SHO, SOC, SPI, TX. 
CCP, DXS, ELP, ENJ, GRS, MOC, OMC, PAN, PLC, SHO, 

SOI, UCC, USI. 
CCP, ENJ, PLC, PRO, PTT, SIN. 
APR, JCC, MOC, MON, PLC, SM, SOI, UCC, USI. 

CCP, CSD, PLC, SHO, SM, SOI, UCC. 

ENJ, GYR, SHC. 

APR, PLC. 

ENJ, GYR, MOC, MON, PAS, PET, PLC, USI. 



PLC. 
ENJ, 
PLC. 
APR, 

EKX, 
CSD, 
PLC. 

ATR, 
ENJ, 
ENJ. 
PLC. 

ATR. 
AMO, 



PLC, PRO. 
PLC, SOG. 



ENJ, PLC, PRO. 

ENJ, GOC, HOU, SIN, SOG, SOI, TID. 



ENJ, PTT, TX. 
PLC. 



ATR, CO, ENJ, GOC, PAS, PRO, RIC. 



CSD, SOC, SOI. 
DXS, ENJ, GOC, MOC, PRO, RIC, SNT, SOC, SUN, TX. 



ACC 

CO, 

ENJ. 

ATR. 

CO, ENJ, GOC, HOU, KEN, PLC, SOC, SUN, TID, UCC, x 



PAS. 
PAS, 
PAS, 
CSD, 
PAS, 
ACC, 
PAS, 
PAS, 
EKX, 



PLC. 

PLC. 

PAS, SOC, x. 

SOC. 

PAS. 

PLC. 

PLC. 

PAS, PLC, SOC. 



GOC, GYR, PLC, SOC. 

ENJ, GOC, SOC. 

ENJ, GOC, SOC. 
GOC. 

EKX, SOC. 



64 



SYNTHETIC ORGANIC CHEMICALS, 1965 



Cyclic Intermediates 

TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, 1965 



[Cyclic intermediates for which separate statistics are given in table 7A are marked below with an asterisk (*); 
cyclic intermediates not so marked do not appear in table 7A because the reported data are accepted in confidence 
and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies 
that the manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 22) 



Aceanthryleno[2, 1-a] aceanthrylene-5, 13-dione 

8-Aeetamido-l-(4-acetamido-2-hydroxy-5-nitrophenylazo)- 
2-naphthol. 

4-Acetamido-2-aminobenzenesulfonic acid 

p-Acetamidobenzoic acid 

2-Acetamido-3-chloroanthraquinone 

*Acetanilide, tech 

Acetic acid, phenyl ester 

Acetoacetanilide 

o-Aeetoacetanisidide 

o-Acetoacetotoluidide 

2',4'-Acetoacetoxylidide 

p-Acetoanisidide 

1' -Acetonaphthone 

Acetone phenylhydrazone 

p-Aeetophenetidide 

Acetophenone, tech 

p-Acetotoluidide 

N-Acetylanthranilic acid 

p-Acetylbenzenesulfonamide 

p-Acetylbenzenesulfonic acid, sodium salt 

p-Acetylbenzenesulfonylurethane 

1-(N- Acetyl )methylamino-4-bromo an thraquinone 

N-Acetylsulfanilic acid, sodium salt 

*N-Acetylsulfanilyl chloride 

Adenine 

*Alkylbenzenes : 

Dodecylbenzene (including tridecylbenzene) : 

Straight chain 

Other 

Other alkylbenzenes: 

Straight chain 

Other 

Alkylphenols, mixed 

Alkylpiperazines, mixed 

Alkylpyridine 

a-dl-5-Allyl-6-imino-l-methyl-5-(l-methyl-2-pentynyl)- 

barbituric acid. 
a-dl-5-Allyl-5-(l-methyl-2-pentynyl)-l-methyl barbi- 
turic acid. 
Aminoaceanthryleno [2, 1-a] aceanthrylene-5, 13-dione 

*4-'-Aminoacetanilide (Acetyl-p-phenylenediamine) 

3'-Aminoacetophenone 

*5-Amino-2-(p-aminoanilino)benzenesulfonic acid 

l-Amino-4— (3-amino-<t-sulfoanilino)-9, 10-dihydro-9, 10- 

dioxo-2-anthracenesulfonic acid. 
1- Amino-4- (4-amino-3-sulf oanilino ) -9, 10-dihydro-9, 10- 

dioxo-2-anthracenesulfonic acid. 
5-Amino-2-anilinobenzenesulfonic acid 

*2-(p-Aminoanilino)-5-nitrobenzenesulfonic acid 

3-Amino-p-anisanilide 

5-Amino-2-o-anisidinobenzenesulfonic acid 

*l-Aminoanthraquinone and salt 

*2-Aminoanthraquinone and salt 

N-(4-Amino-l-anthraquinonyl)anthranilic acid 

N-(5-Amino-l-anthraquinonyl)anthranilic acid 

N-(8-Amino-l-anthraquinonyl)anthranilic acid 

4-Aminoantipyrine 

*6-Amino-3,4'-azodibenzenesulfonie acid (C.I. Acid 
Yellow 9). 

8-Aminobenz [a] acridan-12-one 

p-Aminobenzamide 

*l-Amino-4-benzamidoan thraquinone 

*l-Amino-5-benzamidoan thraquinone 



ICI. 
TRC. 

G. 

DUP. 

G. 

CTN, 

UCC. 

FMP, 

FMP, 

FMP, 

FMP, 

AAP. 

GIV. 

DUP. 

AAP. 

ACP, 

ACY. 

DUP. 

LIL. 

LIL. 

LIL. 

AAP. 

ALL. 

ACY, 

AHA. 



EKT, MRK, SAL, SW. 

UCC. 
UCC. 
UCC. 
UCC. 



CTN, MRK, SAL. 



CO, MON, NAC, PLC, SOC, UCC, WCC. 
ATR, CO, NAC. 

CO, SOC. 

ATR. 

G, 0R0. 

HOU. 

UCC. 

LIL. 

LIL. 

ICI. 

DUP, G, NAC, TRC. 

CTN, SDH, SDW. 

AAP, CMG, DUP, G, TRC, YAW. 

TRC. 

TRC. 



NAC. 

CMG, 

PCW. 

TRC. 

AAP, 

ACY, 

G. 

DUP. 

DUP. 

SDW. 

AAP, 



DUP, NAC, TRC. 



ACY, DUP, G, ICI, MAY, NAC, TRC. 
DUP, G, NAC, TRC. 



CMG, DUP, NAC, TRC. 



NAC. 

SDH. 

ACY, MAY, NAC, TRC. 

G, ICI, NAC, TEC. 



CYCLIC INTERMEDIATES 



65 



TABLE 7B. 



-Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



7-[p-(p-Aminobenzamido)benzamido] -4-hydroxy-2-naphthalene- 

sulfonic acid. 
7-(m-Aminobenzamido )-4-hydroxy-2-naphthalenesulf onic acid- 
*7-(p-Aminobenzamido )-4-hydroxy-2-naphthalenesulfonic acid- 
7-(p-Aminobenzamido )-5-hydroxy-3-naphthalenesulf onic acid- 
s'- Aminobenzanilide 

4'-Aminobenzanilide 

*2-Amino-p-benzenedisulfonic acid [S03H = l] 

o-Aminobenzenethiol 

2-Aminobenzimidazole 

5-Amino-2-benzimidazolinone 

p-Aminobenzoic acid, tech 

p-Aminobenzoic acid, 2-(diethylamino)ethyl ester (Procaine 

p-Aminobenzoic acid, 2-(dimethylamino)ethyl ester 

2-Amino-6-benzothiazolecarboxylic acid 

2-(m-Aminobenzoyl)-o-acetanisidide 

l-Amino-4-bromo-2-chloroanthraquinone 

2-Amino-l-bromo-3-chloroanthraquinone 

5(and 8)-Amino-8(and 5)-bromo-9, 10-dihydro-9, 10-dioxo- 
l,6(and l,7)-anthracenedisulfonic acid. 
*l-Amino-4-bromo-9, 10-dihydro-9, 10-dioxo-2-anthracene- 
sulfonic acid and sodium salt. 

*l-Amino-2-bromo-4-hydroxyanthraquinone 

l-Amino-4-bromo-2-methylanthraquinone 

*l-Amino-2-bromo-4- p-toluidinoanthraquinone 

l-Amino-2-chloroanthraquinone 

*l-Amino-5-chloroanthraquinone 

l-Amino-8-chloroanthraquinone 

2-Amino-l-chloroanthraquinone 

2-Amino-3-chloroanthraquinone 

4- Amino-6-chloro-m-benzen edisulfonami.de 

4- Amino-6-chloro-m-benzenedisulfonamide hydrochloride 

5-Amino-2-chlorobenzoic acid 

2-Amino-5-chlorobenzophenone 

2-Amino-6-chlorobenzothiazole hydrochloride 

*o-(3-Amino-4-chlorobenzoyl)benzoic acid 

2-Amino-5-chloro-p-cumenesulfonic acid 

2-Amino-5-chloro-4-ethylbenzenesulfonic acid 

l-Amino-2-chloro-4-hydroxyanthraquinone 

*3-Amino-5-chloro-2-hydroxybenzenesulfonic acid 

2-Amino-4— chlorophenol 

2-Amino-6-chloropyrazine 

3-Amino-6-chloropyridazine 

*2-Amino-5-chloro-p-toluenesulfonic acid [S0 3 H=1] 

*6-Amino-4-chloro-m-toluenesulfonic acid [S0 3 H=1] 

2-Amino-p-cresol 

*l-Amino-2,4-dibromoanthraquinone 

5(and 8)-Amino-6,8(and 5,7)-dibromo-9,10-dihydro-9,10- 
dioxo-1-anthracenesulfonic acid. 

l-Amino-5, 8-dichloroanthraquinone 

4'-Amino-2',5 / -diethoxybenzanilide 

3-Amino-7-(diethylamino)-5-phenylphenazinium chloride 

l-Amino-9, 10-dihydro-9, 10-dioxo-2-anthracenesulf onic acid— 
5(and 8 )-Amino-9, 10-dihydro-9, 10-dioxo-l-anthracenesulfonic 
acid. 
*l-Amino-9, 10-dihydro-9, 10-dioxo-4-p-toluenesulf onamido- 
2-anthracenesulfonic acid, sodium salt. 

4-Amino-l,3-dihydroxyanthraquinone 

5-Amino-4, 5 / -dihydroxy-3,4'-[(2-methoxy-5-methyl-p- 
phenylene)bis(azo)] -di-2,7-naphthalenedisulfonic acid, 
5' -benzenesulf onate. 

2-Amino-4-(a,a-dimethylbenzyl)phenol 

2-Amino-N, N-dimethyl-p-toluenesulfonamide 

2-Amino-4, 6-dinitrophenol and salt 

3-Amino-4-ethoxyacetanilide 

3-Amino-9-ethylcarbazole 

p-Amino-N-ethyl-N-1-naphthylbenzamide 

Aminoethylpiperazine 

l-Amino-4-hydroxyanthraquinone 1 

2-Amino-3-hydroxyanthraquinone 

5-Amino-4-hydroxy-m-benzenedisulfonic acid 



Manufacturers' identification codes 
(according to list in table 22) 



CMG, 


DUP. 




TRC. 






CMG, 


DUP, 


G, NAC. 


VPC. 






DUP. 






G, TRC. 




DUP, 


G, NAC, TRC. 


FMT. 






EK. 






DUP. 






DUP, 


G. 




LM. 






SDW. 






DUP. 






G. 






AAP. 






ICI, 


MAY. 




TRC. 






AAP, 


DUP, 


G, ICI, NAC, TRC. 


AAP, 


DUP, 


ICC, TRC. 


ICI. 






G, ICI, TRC. 


AAP. 






ACT, 


DUP, 


ICI, MAY, NAC, TRC 


DUP, 


NAC. 




DUP, 


G. 




G, ICI. 




ABB. 






ABB. 






TRC. 






COK, 


ICI, 


TBK. 


DUP. 






AAP, 


G, ICI. 


SW. 






ACY, 


SW. 




AAP. 






CMG, 


NAC, 


TRC. 


G, MEE. 




ACY. 






ACY. 






ACY, 


HSC, 


SW. 


ACY, 


DUP, 


HSC, NAC, SW. 


TRC, 


X. 




AAP, 


DUP, 


ICC, ICI, NAC, TRC. 


ICI. 






TRC. 






ALL. 






DUP. 






G. 






ICI, 


TRC. 




AAP, 


DUP, 


G. 



DUP, G. 

AAP. 

AAP. 

G. 

UCC. 

G. 

G, NAC. 

TRC. 



66 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE IB.-- Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i965--Continued 



l-Amino-4- [(m-2-hydroxyethylsulf onyl )anilino] -9, 10- dihydro- 
9, 10-dioxo-2-anthracenesulf onic acid. 

l-Amino-4-hydroxy-2-methoxyanthraquinone 

4-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid, benzene- 

sulfonate. 
3-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid (2R acid), 

monosodium salt. 
4-Amino-5-hydroxy-l,3-naphthalenedisulfonic acid (Chicago 

acid), monosodium salt. 
*4-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid (H acid), 

monosodium salt. 
*4-Amino-3-hydroxy-l-naphthalenesulfonic acid (1,2,4- acid) — 
4-Amino-5-hydroxy-l-naphthalenesulfonie acid (S acid), 

sodium salt. 
*6-Amino-4-hydroxy-2-naphthalenesulfonic acid (Gamma acid), 

sodium salt. 
*7-Amino-4-hydroxy-2-naphthalenesulf onic acid ( J acid ), 

sodium salt. 

3-Amino-l-hydroxy-2-naphthanilide 

3'-Amino-2'-hydroxy-5'-nitroacetanilide 

6-Amiiio-5-[ (2-hydroxy-4-nitrophenyl)azo] -2-naphthalene- 

sulfonic acid. 
2-(2-Amino-5-hydroxy-7-sulfo-l-naphthylazo)-5-nitrobenzoic 

acid. 
l-(6-Anuno-l-hydroxy-3-sulfo-2-naphthylazo)-6-nitro-2- 

naphthol-4-sulfonic acid. 

5-Aminoisophthalic acid 

4-Amino-3- ((3 -methanesulf anamidoethyl )-N, N-diethylaniline 

hydrochloride. 

3-Amino-4- methoxyacetanilide 

*N-(4-Amino-3-methoxy-l-anthraquinonyl)-p-toluenesulfon- 

amide. 

5-Amino-6-methoxy-2-naphthalenesulfonie acid 

m- [(4-Amino-3-methoxyphenyl )azo]benzenesulf onic acid 

8-Amino-6-methoxyquinoline 

4-[(4-Amino-5-methoxy-o-tolyl)azo]-4-hydroxy-2,7- 

naphthalenedisulfonie acid, benzenesulfonate. 
3- [(4- Amino-5-rnethoxy-o-tolyl)azo]-l, 5-naphthalenedi- 
sulf onic acid. 
7-[(4-Amino-5-methoxy-o-tolyl)azo] -1,3-naphthalenedi- 
sulfonic acid. 

*4'-Amino-N-methylacetanilide 

l-Amino-2-methylanthraquinone 

2-Amino-5-(6-methyl-2-benzothiazolyl)benzenesulfonicacid — 
4-Amino-4'-(3-methyl-5-oxo-2-pyrazolin-l-yl)-2,2'-stil- 
benedisulfonic acid. 

8-Amino-7-methyl-l-phenazinol (Tolazine base) 

8-Amino-7-methyl-2-phenazinol 

2-Amino-3-methylpyridine 

2-Amino-5-methylpyridine 

2-Amino-6-methylpyridine — - — 

2-Amino-4-methylpyrimidine (2-Amino-4-methyl-l,3-diazine) — 

2-Amino-4-(methylsulfonyl)phenol 

2-Amino-5-methyl-l,3,4-thiadiazole 

l-Amino-2-methyl-4-p-toluidinoanthraquinone 

l-Aminonaphth[2,3-c]acridan-5,8,14-trione 

l(and 4)-Aminonaphth[2,3-c] acridan-5,8,14-trione 

4-Aminonaphth[2,3-e]acridan-5,8, 14-trione 

6-Aminonaphth[ 2, 3-c]acridan-5, 8, 14-trione 

*2-Amino-l, 5-naphthalenedisulf onic acid 

*3-Amino-l, 5-naphthalenedisulf onic acid (C acid) 

3-Andno-2,7-naphthalenedisulfonic acid 

4- Amino-1, 5-naphthalenedisulf onic acid 

4-Amino-l,6-naphthalenedisulfonic acid 

*6-Anri.no-l,3-naphthalenedisulfonic acid (Amino I acid) 

*7- Amino-1, 3-naphthalenedisulf onic acid (Amino G acid) 

6-Amino-l-naphthalenesulfonamide 

l-Amino-2-naphthalenesulfonic acid (o-Naphthionic acid) 

2-Amino-l-naphthalenesulfonic acid (Tobias acid) 

*4-Amino-l-naphthalenesulfonic acid (Naphthionic acid) 

4-Amino-l-naphthalenesulfonic acid, sodium salt 



Manufacturers ' identification codes 
(according to list in table 22) 



TRC. 

TRC. 

DUP, NAC. 

DUP, NAC. 

DUP, MON, NAC. 

ACY, G, NAC, TRC, VPC. 
NAC. 

DUP, G, NAC, TRC. 

BKS, CMG, DUP, G, NAC, TRC. 



TRC. 
TRC. 



AAP. 

AAP, DUP, G. 

NAC, TRC. 
DUP, TRC. 
SDW. 

TRC. 

TRC. 



CMG, 


G, NAC. 


DUP, 


ICI. 




G. 






TRC. 






NAC. 






DUP. 






RIL. 






RIL. 






NEP, 


RIL. 




ACY. 






NAC, 


TRC. 




ACY. 






ICI. 






DUP. 






NAC. 






DUP. 






G. 






ACY, 


SDH, 


SW. 


G, NAC, TRC. 


TRC. 






NAC. 






DUP. 






ACY, 


DUP, 


G, NAC, 


ACY, 


DUP, 


G, NAC, 


VPC. 






DUP. 






ACY, 


HSC, 


IMP, SW. 


ACY, 


DUP, 


NAC. 


DUP, 


NAC. 





67 



TABLE 7B. 



- Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



4(and 5)-Amino-l-naphthalenesulfonic acid 

5-Amino-l-naphthalenesulfonic acid (Laurent's acid) 

*5-Amino-2-naphthalenesulfonic acid (l,6-Cleve's acid) 

*5(and 8)-Amino-2-naphthalenesulfonic acid (Cleve's acid, 
mixed). 

*6-Amino-2-naphthalenesulfonic acid (Broenner's acid) 

6(and 7)-Amino-l-naphthalenesulf onic acid 

*8-Amino-l-naphthalenesulfonic acid (Peri acid) 

*8-Amino-2-naphthalenesulfonic acid (1,7-Cleve's acid) 

7-Amino-l,3,6-naphthalenetrisulfonic acid 

8-Amino-l,3,6-naphthalenetrisulfonic acid (Koch's acid) 

5 (and 8)-Amino-2-naphthol 

*8-Amino-2-naphthol 

3-Amino-5-(m-nitrobenzamido)-p-toluenesulfonic acid 

*2-Amino-5-nitrobenzenesulfonic acid [S03H=l] 

4-Amino-3-nitrobenzoic acid 

*2-Amino-4-nitrophenol 

2-Amino-5-nitrophenol 

4-Amino-2-nitrophenol 

2-Amino-l-(p-nitrophenyl)-l,3-propanediol 

4-Amino-4'-nitro-2,2'-stilbenedisulfonic acid 

2-Amino-5-nitrothiazole 

*3' -Amlnooxanilic acid 

4' -Aminooxanilic acid 

3-Amino-2-oxazolidinone 

5-Anuno-2-[(2-oxo-5-benzimidazolinyl)amino]benzenesulfonic 
acid. 

p-Aminophenethyl alcohol 

5-Amino-2-o-phenetidinobenzenesulfonie acid 

o-Aminophenol 

p-Aminophenol 

m-[ (p-Aminophenyl)azo] benzenesulfonic acid 

*p-[ (p-Aminophenyl )azo] benzenesulf onic acid 

7-[ (4-Aminophenyl)azo] -1,3-naphthalenedisulfonic acid 

5-Anino-8-(phenylazo)-2-naphthol 

8-Amino-5-(phenylazo)-2-naphthol 

5-[ (p-Aminophenyl )azo] salicylic acid 

2-(p-itainophenyl)-6-methylbenzothiazole 

2-(p-Jtoiinophenyl )-6-methyl-7-benzothiazolesulf onic acid 
and salt. 

l-(m-Aninophenyl)-5-oxo-2-pyrazoline-3-carboxylic acid 

2-JSminopyridine 

4-Aminopyridine 

2-Aminopyrimidine 

5-Jtadnosalicylic acid 

N-(4-Amino-3-sulfo-l-anthraquinonyl)anthranilic acid 

3 ' - (3-Am.no-4-sulf ophenylsulf amoyl ) -3 " -sulf amoyl-3- 

phthalocyaninesulfonic acid, copper derivative. 
l-Jtaiino-2,3, 6, 7-tetr ahydro-4, 5, 8-trihydroxyanthraquinone--- 

2-Aminothiazole • 

3-itad.no-p-toluamide 

5-Amino-o-toluenesulfonanilide 

*4-Anino-ni-toluenesulfonic acid [S0 3 HJ.] 

*6-Amino-m-toluenesulfonie acid [S0 3 H=1] 

*5-Amino-2-p-toluidinobenzenesulfonic acid 

3- [(4-Amino-o-tolyl )azo] -1, 5-naphthalenedisulf onic acid 

7- [(4-Amino-o-tolyl)azo] -1,3-naphthalenedisulfonic acid 

16-Aminoviolan throne 

2-Jimino-3,5-xylenesulfonic acid [S0 3 H=1] 

5-Anino-2,4-xylenesulfonic acid 

*Aniline (Aniline oil) 

Aniline hydrochloride 

l-Anilino-9, 10-dihydro-9, 10-dioxo-2-anthroic acid 

l-Anilino-4-hydroxyanthraquinone 

6-Anilino-4-hydroxy-2-naphthalenesulfonic acid (Phenyl 
gamma acid). 
*7-Anilino-4-hydroxy-2-naphthalenesulfonic acid (Phenyl 
J acid). 

*Anilinomethanesulfonic acid and salt 

*8-Anilino-l-naphthalenesulfonic acid (Phenyl peri acid) 

m-Anilinophenol 

p- Anisic acid 



Manufacturers' identification codes 
(according to list in table 22) 



ACY 


TRC. 


DUP 


NAC. 


DUP 


G, NAC, TRC. 


ALL, 


DUP, G, NAC. 


ALL, 


KLS, NAC, SNA, TRC. 


VPC 




DUP, 


NAC, SDC, TRC. 


DUP, 


G, NAC, TRC. 


DUP. 




DUP, 


NAC. 


G. 




CMG, 


G, TRC, VPC. 


G. 




ACY, 


DUP, G, NAC, TRC. 


DUP. 




DUP, 


G, NAC, TRC. 


NAC. 




ACY, 


VPC. 


PD. 




G, NAC, TRC. 


ACY. 




CMG, 


DUP, TRC, VPC. 


DUP. 




NOR. 




DUP. 




EKT. 




NAC. 




FMT. 




ABB, 


DUP, SDC. 


AAP, 


DUP, TRC. 


ACY, 


CMG, DUP, G, NAC, TRC 


TRC. 




ALL. 




ALL. 




TRC, 


VPC. 


DUP, 


NAC. 


DUP, 


TRC. 


TRC, 


VPC. 


NEP, 


RIL. 


RIL. 




ACY. 




AAP, 


TRC. 


G. 




DUP. 




DUP. 




ACY, 


MRK. 


SDH. 




G. 




ACY, 


DUP, G, SNA. 


DUP, 


HSC, NAC, SW. 


DUP, 


NAC, TRC. 


TRC. 




TRC. 




ACY, 


G. 


DUP. 




DUP. 




ACY, 


DOW, DUP, NAC. 


ACY. 




NAC. 




AAP. 




DUP, 


NAC. 



ALT, CMG, DUP, NAC, TRC. 



AAP, ACY, DUP, NAC, TRC, VPC. 
CMG, DUP, NAC, SDC. 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 7B. 



■Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1965 --Continued 



Manufacturers' identification cedes 
(according to list in table 22) 



m-Anisidine 

*o-Anisidine '—■ 

p-Anisidine 

l-p-Anisidino-4-hydroxyanthraquinone 

*o-Anisidinomethanesulfonic acid 

2-o-Anisidino-5-nitrobenzenesulfonic acid 

p-Anisoin 

Anisole, tech 

4- (o-Anisylazo)-o-anisidine 

Anthracene, refined 

*Anthranilic acid (o-Aminobenzoic acid) 

*Anthra[l,9-cd]pyrazol-6(2H)-one (Pyrazoleanthrone) 

Anthraquinone, 100$ 

1,1' -[l,5 (and 1, 8)-Anthraquinonylenediamino]bisnaphth- 
[ 2,3-c]acridan-5,8, 14-trione. 

*N, N'-(l,5-Anthraquinonylene)dianthranilic acid 

N, N'-(l,5-Anthraquinonylene)dioxamic acid 

N,N'-l,5(and l,8)-Anthraquinonylene dioxamic acid 

(l-Anthraquinonyl)-l,2-hydrazinedisulfonic acid, disodium 
salt. 

Anthrone 

Arsanilic acid and salt, tech 

Aryldiamines, mixed 

*4',4'"-Azobis[4-biphenylearboxylic acid] 

4' , 4' " - Azobis [ N- ( l-ehloro-2-anthraquinonyl )-4-biphenyl- 
carboxamide] . 

Barbituric acid 

Barbituric acid, sodium derivative 

*Benzaldehyde, tech 

4- [(4— Benzamido-l-anthraquinonyl)amino]naphth[2,3-c]- 
acridan-5, 8, 14-trione. 

N-(5-Benzamido-l-anthraquinonyl)-p-toluenesulfonamide 

l-Benzamido-4-bromo anthraquinone 

l-Benzamido-4- chloroanthraquinone 

*l-Benzamido-5-chloroanthraquinone 

l-Benzamido-5, 8-dichloroanthraquinone 

4-Benzamido-5-hydroxy-2, 7-naphthalenedisulfonic acid 

7-Benzamido-4-hydroxy-2-naphthalenesulfonie acid 

N-(4-Benzamido-6-methoxy-m-tolyl)-N-(methylazo)glycine 

Benzanilide 

*7H-Benz[de]anthracen-7-one (Benzanthrone) 

Benzeneboronic acid 

m-Benzenedisulfonic acid 

Benzenesulfonand.de 

Benzenesulfonic acid 

Benzenesulfonyl chloride 

1,2,4, 5-Benzenetetracarboxylic acid 

1, 2,4, 5-Benzenetetracarboxylic-l, 2 :4, 5-dianhydride 

1,3,5-Benzenetricarboxylic acid 

1,2,4-Benzenetricarboxylic acid, 1, 2-anhydride 

Benzhydrol ( Diphenylmethanol ) 

^Benzidine hydrochloride and sulfate 

Benzil (Bibenzoyl) ■ 

Benzilic acid 

2-Benzofuranacetonitrile 

^Benzoic acid, tech 

Benzoic anhydride 

Benzoin 

Benzonitrile 

Benzophenonetetracarboxylic dianhydride 

2-Benzothiazolethiol (2-Mercaptobenzothiazole), sodium 
salt. 

Benzo[b]thiophen-3(2H)-one 

lH-Benzotriazole 

2H-3,l-Benzoxazine-2,4(lH)-dione 

2-Benzoxazolinone 

Benzoylacetic acid, ethyl ester 

*o-Benzoylbenzoic acid 

Benzoyl chloride 

4-Benzoyl-3-hydroxyphenyl methacrylate 

2-Benzoyl-4-sulfobenzoic acid 



EK. 

AAP, 

DUP, 

AAP. 

AAP, 

TRC. 

CTN. 

DUP, 

AAP. 

ACP. 

DUP, 

DUP, 

ACY, 

DUP. 



ALL, DUP, KLS, MON. 
MON. 



DUP, G, NAC, TRC, VPC. 
GIV, LIL. 



LB/1, MEE, NAC. 
G, TRC. 
DUP, G, TRC. 



DUP, ICI, TRC. 
G, MEE. 
G. 
DUP, G. 

ICI. 

ABB, FLM. 

DA. 

DUP, G, TRC. 



KF, LIL. 
ABB, KF. 
BPC, HN, VEL. 
DUP. 



ICI, 

AAP. 

DUP, 

ACY, 

TRC. 

TRC. 

AAP, 

G. 

DUP, 

AAP, 

EDC. 

KPT. 

NES. 

NES, 

NES. 

DUP. 

DUP, 

ACC. 

ACC. 

TBK. 

CWN, 

LEM. 

BPC, 

EK. 

FRO, 

EK. 

BPC, 

VEL. 

GOC. 

ACY, 



MEE. 
MEE. 



NAC. 



DUP, G, ICI, MAY, NAC, TRC. 



ACY, ATL, CMG, DUP, G, ICI, MAY, NAC, SDC, TRC. 



FIN, LAK, NAC, x. 

LEM. 

HK, HN, MON, VEL. 

LEM. 

GYR, MON. 



FMP. 

ACY, DUP, G, NAC. 

HK, HN, VEL. 



CYCLIC INTERMEDIATES 



69 



TABLE 7B. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1965 --Continued 



2-Benzoyl-4'-(p-toluenesulfonamido)acetanilide 

Benzylamine 

4-(Benzylamino)-6-chloro-m-benzenedisulfonic acid 

2-(Benzylamino)ethanol 

4-Benzyl-6-chloro-3-keto-2-methyl-7-sulf amyl-1, 2, 4-benzyl- 

thiadiazine-1, 1-dioxide. 
4-Benzyl-6-chloro-3-keto-7-sulf amyl-1, 2, 4-benzylthia- 
diazine-1, 1-dioxide. 

Benzyl disulfide 

Benzyl ether (Dibenzyl ether) 

5-(Benzylethylamino)-o-toluenesulfonic acid 

N-Benzyl-N-ethyl-m-toluidine 

4- ( Benzylideneamino ) antipyr ine 

4,4'-Benzylidenedi-o-toluidine 

Benzylidene phthalide 

p-(Benzyloxy)phenol 

4- Benzylpiperidine 

Benzjl polysulfide 

4-Berizylpyridine 

Benzyl sulfide 

Benzyl trimethylammonium chloride 

Benzyltrimethylammonium hydroxide 

Benzyl trimethylammonium methoxide 

4',4'"-Biacetophenone 

M>,3'-Bianthra[l,9-cd]pyrazole]-6,6'-(2H,2'H)dione 
( Pyrazoleanthrone yellow). 

[3,3'-Bi-7H-benz[de] anthracene] -7,7'-dione 

*[4,4'-Bi-7H-benz[de] anthracene] -7, 7 '-dione 

[l,l'-Binaphthalene]-8,8'-dicarboxylic acid 

Biphenyl 

3,3',4,4'-Biphenyltetramine . 

2,2',4,4'-Biphenyltetrol 

2,2'-Biqiinoline 

*1,4-Bis[ 1-anthraquinonylamino] anthraquinone 

l,4-Bis[i-anthraquinonylamino] anthraquinone and 1,4-Bis- 
[ 5-chloro-l-anthraquinonylamino] anthraquinone (mixed ) . 

It 5-Bis [1-anthraquinonylamino] anthraquinone > 

l,4-Bis(anthraquinonylamino)anthraquinone carbazole 

Bis[l-anthraquinonylamino]violanthrene 

l,4-Bis[(5-benzamido-l-anthraquinonyl)amino]anthraquinone-— 

a 2 ,a 6 -Bis[5-tert-butyl-6-hydroxy-m-tolyl]mesitol 

Bis(chlorosulfonyl)phthalocyaninedisulfonic acid, copper 
derivative. 

4,4'-Bisrdiethylamino]benzhydrol 

4,4'-Bis[diethylamino]benzhydrol, 2,6-naphthalenedi- 

sulfonate. 
4,4'-Bis[diethylamino]benzhydrol salt, 2,7-naphthalenedi- 
sulfonic acid mixture. 

4,4'-Bis[diethylamino]benzophenone (Ethyl ketone base) 

4-Bis[ (p-diethylaminophenyl )methyl] -2, 7-naphthalenedi- 
sulfonic acid, leuco form. 

4,4'TBis[dimethylamino]benzhydrol (Michler's hydrol) 

*4,4'-Bis[dimethylamino]benzophenone (Michler's ketone) 

Bis[p-(dimethylamino)phenyl]methanesulfonic acid and salt — 

1, 5-Bis[2,4-dinitrophenoxy]-4,8-dinitroanthraquinone 

l,5(and l,8)-Bis[2,4-dinitrophenoxy]-4,8(and 4,5)-dinitro- 
anthraquinone . 

Bis(2,3-epoxycyclopentyl)ether (Epoxide 205) 

4,4'-Bis[(p-hydroxyphenyl)azo]-2,2'-stilbenedisulfonic acid 
(C.I. Direct Yellow 4). 

4,4-Bis[p-hydroxyphenyli valeric acid 

4,4-Bis(p-methoxyphenyl)-3-hexanone 

Bis(2-methyl-l-aziridinyl )phenylphosphine oxide 

2,4-Bis(l-methylbutyl)phenol 

l,4-Bis[2-(4-methyl-5-phenyloxazolyl)l benzene (Dimethyl- 
P0P0P). 

Bis(o-nitrophenyl)sulfide 

m-Bis(m-phenoxyphenoxy)benzene 

l,4-Bis[2-(5-phenyloxazolyl)]benzene (P0P0P) 

2-Brcanoacetophenone 

p-Bromoaniline 

p-Bromoanisole~ 



Manufacturers' identification codes 
(according to list in table 22) 



EK. 

ICO, MLS. 

ABB. 

MLS.. 

ABB. 

ABB. 

CCW. 

BPC, TBK. 

NAC. 

DUP, NAC. 

SDW. 

ACY. 

LIL. 

EK, ICO. 

RIL. 

HK. 

RIL. 

BPC. 

MLS. 

MLS. 

MLS. 

DUP. 

DUP, G, TRC. 

DUP, NAC. 

ACY, DUP, ICI, MAY, NAC. 

DUP, NAC. 

DOW, MON. 

AAP. 

FMT, IDC. 

EK. 

ACY, DUP, G, ICI, MAY, NAC. 

TRC. 

DUP, NAC. 

ICI. 

G. 

ICI. 

ACY. 

TRC. 



DSC, SDH. 
TRC. 

SDH. 

DSC, DUP, G, NAC, SDH. 

NAC. 

DUP. 

DUP. 

UCC. 
TRC. 

JNS. 
LIL. 
ICO. 
PAS. 
ARA. 



EK. 
ARA. 



EK. 

EK, ICO. 



70 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 7B —Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1 965— Continued 



*3-Bromo-7H-benz[de]anthracen-7-one (3-Bromobenzanthrone) 

Bromobenzene, mono- 

p-Bromobenzenesulfonyl chloride 

4-Bromobenzophenone 

Bromochlorobenzene 

o-Bromochlorobenzene 

6-Bromo-5-chlorobenzoxazolone 

2-Bromo-6-chloro-4-nitroaniline 

2-Bromodibenzofuran 

2-Bromo-4,6-dinitroaniline 

Bromoethylbenzene 

2-Bromo-3' -hydroxyacetophenone benzoate 

*l-Bromo-4-(methylamino)anthraquinone 

6-Bronc-3-methyl-7H-dibenz[f,ij],isoquinoline-2,7(3H)dione-- 

1-Bromonaphthalene 

2-Bromo— 4'-nitroacetophenone 

l-[ (9-Bromo-7-oxo-7H-benz [de] anthracen-3-yl )amino] anthra- 
quinone. 

m-Bromophenol 

o-Bromophenol 

(p-Bromophenyl)acetonitrile 

p-Bromophenylhydrazine hydrochloride 

2-Broraopyridine 

o-Bromotoluene 

p- Br omo toluene 

a-Bromo toluene 

2-Bromo-l,3,5-triethylbenzene 

p-Butoxyphenol 

4-[3-(p-Butoxyphenoxy)propyl] morpholine 

4' -Butoxy-2-piperidinopropiophenone hydrochloride 

N-Butylacetanilide 

l-(Butylamino)anthraquinone 

p-(Butylamino)benzoie acid, ethyl ester 

p-Butylaniline 

2-tert-Butylanthraquinone 

p-tert-Butylbenzaldehyde 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

p-tert-Butylbenzoic acid 

o-(p-tert-Butylbenzoyl)benzoic acid 

6-tert-Butyl-m-cresol 

2-tert-Butyl-p-cresol 

2'-tert-Butyl-4',6'-dimethylacetophenone 

4-Butyl-a-(dimethylamino)-o-cresol 

2-tert- Butyl -4-ethylphenol 

^-Butyl-i-methoxymetanilamide 

2-tert-Butyl-5-methylanisole 

o-sec-Butylphenol 

p-sec-Butylphenol 

o-tert-Butylphenol 

*p-tert-Butylphenol ■ 

Butylphenols, mixed 

p-tert-Butyltoluene 

5-tert-Butyl-l,2,3-trimethylbenzene 

5-tert-Butyl-m-xylene 

6-tert-Butyl-2,4-xylenol 

Camphoric acid 

Camphoric anhydride 

Camphosulfonic acid 

Carbamic acid, 2-hydroxy-2-phenylbutyl ester (Hydroxy- 
phenamate ) . 

Carbazole, refined 

N, N'-Carbonylbis[4-methoxymetanilic acid] 

N, N'-Carbonylbis[4-methoxy-6-nitrometanilic acid] 

2,4'-Carbonyldibenzoic acid 

5'_(o-Carboxybenzoyl)-2'-chlorooxanilic acid 

N- [ (3-Carboxy-4-chlorophenyl )-sulf onyl] anthranilic acid 

3-Carboxy-2(and 4)-hydroxybenzenediazonium sulfate 

o-[(Carboxymethyl)thio] benzoic acid 

[ (o-Carboxyphenyl )thio] ethylmercury 

Cedrene 



Manufacturers ' identification codes 
(according to list in table 22) 



ACY, DUP, G, ICI, MAY, NAC. 

DCW. 

EK. 

ICO. 

DOW. 

PIC. 

MEE. 

AAP. 

G. 

AAP, TRC. 

DOW. 

SDH. 

AAP, DUP, G, ICI. 

AAP. 

EK. 

G. 



BPC. 

EK. 

FMT, NEP, 

EK, RSA. 

BPC, PIC. 

BPC, EK. 

DUP. 



ICO. 

UCC. 

AAP. 

ICO. 

DUP, UCC. 

DUP. 

GIV. 

PLC. 

PLC. 

PLC. 

SHC. 

DUP. 

KPT, PED. 

ACY. 

GIV. 

EH. 

ACY. 

ALL, KLS, PCW. 

GIV. 

DOW, TNA, UCC. 

DOW. 

TNA. 

DOW, PRD, UCP. 

DOW. 

GIV, SHC. 

GIV. 

GIV. 

KPT. 

FIN, OTC. 

FIN. 

OTC, FYL. 

AHA. 

SDC. 
G. 



TRC. 
NAC- 



LIL. 
GIV. 



CYCLIC INTERMEDIATES 



TABLE 7B. —Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



2'-Chloroacetoacetanilide 

2'-Chloroacetophenone 

4'-Chloroacetophenone 

4'-(Chloroacetyl)acetanilide 

m-Chloroaniline 

o-Chloroaniline 

p-Chloroaniline 

2-(o-Chloroanilino)ethanol 

3-(o-Chloroanilino)propionitrile 

5-Chloro-o-anisidine [NH 2 = !] (4-Chloro-o-anisidine 
[0CH 3 =1]). 

5-Chloro-o-anisidine hydrochloride 

4— Chloroanthranilic acid 

*l-Chloroanthraquinone 

*2-Chloroanthraquinone 

N-(5-Chloro-l-anthraquinonyl)-p-toluenesulfonamide 

o-Chlorobenzaldehyde 

p-Chlorobenzaldehyde 

4-(p-Chlorobenzamido)anthraquinone-l, 2-acridone : 

Chloro-7H-benz [de] anthracen-7-one ( Chlorobenzanthrone ) 

*Chlorobenzene, mono- 

p-Chlorobenzenesulfinic acid 

p-Chlorobenzenesulf on amide 

p-Chlorobenzenesulfonic acid 

o-Chlorobenzoic acid 

p-Chlorobenzoic acid 

p-Chlorobenzonitrile 

*o-(p-Chlorobenzoyl)benzoie acid 

o(and p)-Chlorobenzoyl chloride 

p-Chlorobenzoyl chloride 

4,4'-(o-Chlorobenzylidene)di-2,5-xylidine 

a-(p-Chlorobenzyl)-ct-phenyl-l-pyrrolidine propanol 

Chloro(p-chlorophenyl)phenylmethane 

Chlorocyclohexane 

l-Chloro-2,5-diethoxy-4-nitrobenzene 

2-Chloro-N, N-diethyl-4-nitroaniline 

2-Chloro-3',4'-dihydroxyacetophenone 

2-Chloro-l,4-dihydroxyanthraquinone 

N-(3-Chloro-9,10-dihydroxy-2-anthryl)acetamidebis [hydrogen 
sulfate ]. 

4'-Chloro-2',5'-dimethoxyacetoaeetanillde 

4-Chloro-2, 5-dimethoxy aniline 

5-Chloro-2,4-dimethoxy aniline 

5-Chloro-4, 7-dimethylbenzo [b] thiophen-3(2H)-one 

4-Chloro-N,N-dimethyl-3-ni trobenzenesulfonanti.de 

*l-Chloro-2,4-dinitrobenzene (Dinitrochlorobenzene) 

l-Chloro-2,4-dinitrobenzene and 2-chloro-l,3-dinitrobenzene 
mixture. 

3-Chloro-4, 6-dinitrobenzenesulf onic acid 

4-Chloro-3, 5-dinitrobenzoic acid 

3-Chlorodiphenylamine 

Chlorodiphenylmethane 

a- Chloro-o( and/or p )-dodeeyltoluene [CH3=1] 

p-[ (2-Chloroethyl )methylamino]benzaldehyde 

Chloroformic acid, benzyl ester 

Chloroformic acid, phenyl ester 

l-Chloro-4-hydroxyanthraquinone 

4-Chloro-5-hydroxy-l, 7-naphthalenedisulf onic acid 

5'-Chloro-3-hydroxy-2-naphth-o-anisidide 

3-Chloro-4-hydroxyquinoline-3,4-carbonic acid 

6-Chloroisatoic anhydride 

4-Chloro-N-isopropyl-3-nitrobenzenesulf on amide 

4-Chlorometanilic acid 

5-Chlorometanilic acid 

*6-Chlorometanilic acid 

5-Chloro-2-methoxybenzenediazonium chloride 

N-[ (5-Chloro-2-methoxyphenyl)azo] sarcosine 

*l-Chloro-2-methylanthraquinone 

4-(Chloromethyl)-l,2-dimethylbenzene 

4-(Chloromethyl)-l,3-dimethylbenzene 

l-(Chloromethyl)naphthalene 

4-Chloro-N-methyl-3-nitrobenzenesulf on amide 



FMP, UCC. 

EK. 

LIL, NES. 

DUP. 

DUP, G. 

DUP, MON, NAC. 

DUP, MON. 

EKT. 

DUP. 

ALL, BUC, KLS. 



BUC, 

DUP. 

ACY, 

ACY, 

ICI. 

HN. 

HN. 

G. 

ACY, 

ACS, 

TRC. 

ACY, 

G. 

HN. 

HN. 

EK. 

ACY, 

HN. 

HN. 

G. 

LIL. 

OPC, 

ACY. 

ALL, 

DUP. 

AAP, 

NAC. 



G. 



DUP, G, ICI, MAY, NAC. 
G, NAC, TRC. 



DOW, DUP, DVC, GGY, HK, HKD, MON, MTO, OMC, PPG, WOI. 
NES. 



DUP, G, ICI, NAC. 

TBK. 
KMT, G. 
SDW. 



PCW. 

PCW. 

G, PCW. 

NAC. 

EKT, G. 

AAP, DUP, NAC, SDC. 

DUP. 

TRC. 

G. 

SK. 

TBK. 

0R0. 

G, NAC. 

RSA. 

EK. 

ICI. 

G. 

PCW. 

SDH. 

MEE. 

TRC. 

DUP. 

NAC. 

AAP, DUP, G, SW. 

G. 

ATL. 

AAP, ACY, CMG, G, ICI, NAC, TRC. 

BPC. 

BPC. 

BPC. 

TRC. 



72 



SYNTHETIC ORGANIC CHEMICALS, 1965 



-Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



2- Chloro-5-(N-methylsulfamoyl) sulfanilamide 

5-Chloro-2-(N-methylsulfamyl)-<4-sulfamyl-N-benzylaniline 

Chloronaphthalen.es 

*2-Chloro-<i-nitroaniline (o-Chloro-p-nitroaniline) 

*4-Chloro-2-nitroaniline (p-Chloro-o-nitroaniline) 

"i-Chloro-2-nitroanisole 

*l-Chloro-5-nitroanthraquinone 

*l-Chloro-8-nitroanthraquinone 

*l-Chloro-2-nitrobenzene (Chloro-o-nitrobenzene) 

l-Chloro-2(and 4)-nitrobenzene (Chloronitrobenzenes, 

o- and p-). 
l-Chloro-3-nitrobenzene (Chloro-m-nitrobenzene) 

*l-Chloro-4-nitrobenzene (Chloro-p-nitrobenzene) 

*4-Chloro-3-nitrobenzenesulfonamide 

4-Chloro-3-nitrobenzenesulfonanilide 

*2-Chloro-5-nitrobenzenesulfonic acid 

2-Chloro-5-nitrobenzenesulfonic acid, sodium salt 

4-Chloro-3-nitrobenzenesulfonic acid 

*4-Chloro-3-nitrobenzenesulfonyl chloride 

2-Chloro-4- nitrobenzoic acid 

2-Chloro-5-nitrobenzoic acid 

*o-(4--Chloro-3-nitrobenzoyl )benzoic acid 

4-Chloro-2-nitrophenol 

4-Chloro-3-nitrophenyl methyl sulfone 

2-Chloro-<i- nitrotoluene 

2-Chloro-6-nitrotoluene 

4-Chloro-2-nitrotoluene 

4- Chloro-3 -nitrotoluene 

m- Chlorophenol 

o-Chlorophenol 

p- Chlorophenol 

2-Chlorophenothiazine 

(m-Chlorophenyl)acetonitrile 

*(p-Chlorophenyl)acetonitrile 

l-(p-Chloro-a-phenylbenzyl)-4-methylpiperazine 

4-Chloro-a-phenyl-o-cresol 

4-Chlqro-o-phenylenediamine 

3-(o-fihlorophenyl)-5-methyl-<i-isoxazolecarbonyl chloride 

3-(o-Chlorophenyl )-5-methyl-4- isoxazolecarboxylic acid- 

l-(m-phlorophenyl)-3-methyl-2-pyrazolin-5-one 

p-Chlprophenyl methyl sulfone 

2-Chloro-<4-phenylphenol 

1- [4-(p-Chlorophenyl )-3-phenyl-3-butenyl]pyrrolidine hydro- 
bromide. 

4-Chlorophthalic acid 

Chlorophthalic anhydride 

l-(3-Chloropropyl)-4-methylpiperazine 

^-(e-Chloro-S-pyridazinylJsulfanilamide 

2-Chloropyridine 

dl-2-[p-Chloro-d-(2-pyridyl )benzyl]oxy-N, N-dimethylethyl- 
amine maleate. 

7-Chloro-4-quinolinol 

2-(6-Chloro-2-quinoyl)-l,3-indandione 

4-Chlororesorcinol 

8-Chlorotheophylline 

2-Chlorothiaxanthen-9-one 

2-Chlorothiophene 

m- Chlorotoluene 

o-Chlorotoluene 

p-Chloro toluene 

*a- Chlorotoluene (Benzyl chloride) 

Chlorotoluenes, mixed 

6-Chloro-m-toluidine 

6-Chloro-m-toluidine hydrochloride 

3-Chloro-o-toluidine [ NH 2 = 1] 

*4-Chloro-o-toluidine [ NH 2 = 1] and hydrochloride 

*5-Chloro-o-toluidine [ NH2 = 1] (4-Chloro-o-toluidine 
[CH 3 = 1]). 

*5-Chloro-o-toluidine hydrochloride [ NH 2 = 1] 

3-Chloro-p-toluidine [NH 2 = 1] 

*N-[(5-Chloro-o-tolyl)azo]sarcosine 



G, KPS, KPT. 




ACY, 


DOW, DUP, 


HSC. 


AAP, 


DOW r DUP, 


VPC. 


ALL. 






ACY, 


DUP, MAY, 


NAC, TRC. 


DUP, 


MAY, NAC. 




AAP, 


DUP, MON, 


UPM. 


SDC. 






DUP, 


G, UPM. 




AAP, 


DUP, MON, 


UPM. 


AAP, 


CMG, DUP, 


EKT, ICC, TRC 


TRC. 






AAP, 


CMG, NAC, 


TRC. 


DUP. 






G, NAC, TRC. 




AAP, 


DUP, EKT. 




SAL. 






TRC. 






AAP, 


G, ICI, NAC. 


DUP. 






TRC. 






DUP. 






DUP. 






BUC, 


DUP. 




AAP, 


BUC. 




EK. 






DOW, 


MON. 




DOW, 


MON. 




SK. 






BPC. 






ICO, 


OPC, TBK. 




ABB. 






MON. 






FMT. 






ICO, 


OTC. 




ICO. 






TRC. 






TRC. 






DOW. 






LIL. 






SW. 






HK. 






SK. 






ACY. 






FMT. 






X. 






SDW. 






DUP. 






AAP, 


G. 




MAL. 






KF. 






GAM. 







BPC, 


GRH, 


HK, HN, 


BPC. 






BUC. 






BUC. 






AAP, 


ACY, 


PCW. 


ATL, 
DUP, 


BUC, 
SDH. 


DUP. 


ALL, 


ATL, 


BUC, G. 



CYCLIC INTERMEDIATES 



73 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1965 --Continued 



l-(6-Chloro-o-tolyl)-3-methyl-2-pyrazolin-5-one 

*[(4-Chloro-o-tolyl)thio]acetic acid 

4-Chloro-a,<x,a-trifluoro-3-nitrotoluene 

5-Chloro-a,x,a-trifluoro-2-nitrotoluene 

p-Chloro-a,a,a-trif luorotoluene 

6-Chloro-oc, a,ct-trifluoro-m-toluidine 

2-Chloro-l,3,5-trinitrobenzene 

Chlorotriphenylmethane 

2-Chloro-p-xylene 

4-Chloro-2, 5-xylenesulf onyl chloride 

4-Chloro-3,5-xylenol 

[ (4-Chloro-2,5-xylyl)thio]acetic acid 

5<x-Cholestan-3/S-ol 

Cholic acid 

Cinnamoyl chloride 

*Cresols : 1 

m-Cresol 

o-Cresol: 

From coal tar 

From petroleum 

p-Cresol 

Cresols, mixed i 1 
*(m,p)-Cresol: 

From coal tar 

From petroleum 

*(o,m,p)-Cresol: 

From coal tar 

From petroleum 

2,3-Cresotic acid 

*Cresylic acid, refined: 1 

*From coal tar 

*From petroleum 

*Cumene 

N-(0-Cyanoethyl)-N-(/3-acetoxyethyl)aniline 

4-[(2-Cyanoethyl)ethylamino]-o-tolualdehyde 

p-[(2-Cyanoethyl)methylamino]benzaldehyde 

8-Cyano-l-naphthalenesulfonic acid 

*Cyclohexane 

1,2-Cyclohexanedicarboxylic acid, diallyl ester 

1,4-Cyclohexanedicarboxylic acid, dimethyl ester 

1,2-Cyclohexanedicarboxylic anhydride 

*Qyclohexanol 

*Cyelohexanone 

Cyclohexanone oxime 

Cyclohexene 

4-Cyclohexene-l,2-dicarboximide 

4-Cyclohexene-l,2-dicarboxylie anhydride 

*Cyclohexylamine 

Cyclohexyl-2-propanone 

N-Qyclohexyltaurine, sodium salt 

Qyclopentanepropionic acid 

Cyclopentanol 

Qyclopentanone 

Qyclopentene 

Cyclopentylphenylglycolic acid, methyl ester 

Cyclopropylcarbox amide 

Cyclopropylcarboxylic acid 

p-Cymene 

Deoxycholic acid 

1,5 (and l,8)-Diacetamidoanthraquinone 

3'-[Di(2-acetoxyethyl)amino]-p-acetophenetidide 

N, N-Diacetyl-4,4' -diaminobiphenyl 

3- (Diallylcarbamoyl )-l, 2, 2-trimethylcyclopentanecarboxylic 
acid. 

N 2 , N 2 -W.allylmelamine 

*l,4-Diaminoanthraquinone 

*1, 5-Diaminoanthraquinone 

1,5 (and l,8)-Diaminoanthraquinone 

*2, 6-Waminoanthraquinone 

3,4-Diaminobenzanilide 

2,4-Diaminobenzenesulfonic acid [S0 3 H=l] 

See footnote at end of table. 



Manufacturers' identification codes 
(according to list in table 22) 



TRC. 








ACY, 


ALL, 


NAC, 


POT 


AAP, 


G, MEE. 




MEE. 








HK. 








AAP. 








EK, 


PIC. 






ARA, 


EK. 






DUP. 








G, NAC. 






OTA. 








G, NAC. 






SDW. 








SRL, 


WIL. 






BPC, 


TBK, 


X. 




KPT, 


PRD. 






KPT, 


PRD. 






MER, 


NPC, 


PRD, 


SW. 


ACY, 


HPC, 


SW. 




ACP, 


KPT, 


PRD. 




MER, 


NPC, 


PIT, 


PRD. 


ACP, 


KPT. 






NPC, 
DOW. 


PIT, 


PRD. 





ACP, KPT. 

MER, NPC, PIT, PRD, SHO. 

ACC, CLK, DOW, GOC, HPC, MON, SHC, SKO, SOC, TX. 

EKT. 

DUP, G. 

DUP, G. 

DUP, G. 

ASH, CO, CSD, DUP, EK, EKX, ENJ, GOC, GRS, PLC, PRO, 

RIC, SOG. 
ICO. 



NAC. 






DUP, 


MON, 


NAC. 


DBC, 


DUP, 


MON, NAC. 


NAC, 


X. 




KF, 


PLC. 




CHO. 






NAC, 


PTT. 




ABB, 


JCC, 


MON, PAS, VGC, x. 


GIV. 






G. 






ARA. 






ARA, 


LIL. 




ARA. 






PLC. 






ARA. 






ABB. 






ABB. 






HNW, 


HPC, 


NAC. 


MRK, 


WIL. 




AAP. 






TRC. 






AAP. 






WYT. 






ACY. 






CMG, 


DUP, 


G, NAC, TRC. 


DUP, 


MEE, 


TRC. 


AAP, 


G, ICI, TRC. 


AAP, 


DUP, 


G, ICI, NAC, TRC, VPC. 


AAP, 


DUP. 




DUP, 


NAC, 


TRC. 



74 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 7B. Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, 1965 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



2,5-Diaminobenzenesulfonic acid [S03H=1] 

4,4'-Diamino-2,2'-biphenyldisulfonic acid 

3,7-Diamino-4, 6-dibenzothiophenedisulfonic acid, 5,5- 

dioxide, disodium salt. 

1, 5-Diamino-2,6-dibromo-4,8-di-p-toluidinoanthraquinone 

l,4-Diamino-2,3-dichloroanthraquinone ■■ 

*l,4-Diamino-2,3-dihydroanthraquinone 

4, 8-Diamino-9, 10-dihydro-l, 5-dihydroxy-9, 10-dioxo-2, 6- 

anthracenedisulfonic acid. 
l,4-Diamino-9, 10-dihydro-9, 10-dioxo-2,3-anthracenedi- 

carbonitrile. 
1, 4-Diamino-9, 10-dihydro-9, 10-dioxo-2, 3-anthracenedicar- 

boximide. 

l,5-Diamino-4,8-dihydroxyanthraquinone 

l,5(and l,8)-Diamino-4, 8(and 4, 5 )-dihydroxyanthraquinone 

4, 5-Diamino-l,8-dihydroxyanthraquinone 

3, 6-Diamino-2, 7-dimethylacridine 

3, 6-Diamino-2, 7-dimethylacridine sulfate 

4,4'-Diaraino-5,5'-dimethyl-2,2' -biphenyldisulfonic acid 

l,4-Diamino-5-nitroanthraquinone 

4,6-Diamino-5-nitroso-2-phenylpyrimidine 

2,4-Diamino-6-phenyl-s-triazine 

2, 6-Diaminopyridine 

*4,4'-Diamino-2,2'-stilbenedisulfonic acid 

l,5-Diamino-2,4,6,8-tetrabromoanthraquinone 

2, 5-Diandnotoluene sulfate 

4,6-Diamino-m-toluenesulfonic acid [S03H=l] 

N-(4,6-Diamino-m-tolyl)-p-benzoquinoneimine 

1, 5-Dianilino-9, 10-dihydro-9, 10-dioxo-2, 6-anthraeenedi- 

carboxylic acid. 

2,4-Dianilino-l-hydroxyanthraquinone 

6, 8-Dianilino-l-naphthalenesulf onic acid 

Diary lguanidine 

p-Diazo-N, N-dimethylaniline-l-amino-8-naphthol-3-sulfonate- 

6-sulfonic acid, sodium salt. 
5(and 3)-Diazo-6-oxo-l,3(and l,4)-cyclohexadiene-l-car- 

boxylic acid. 

1,5-Dibenzamidoanthraquinone 

6,ll-Dibenzamido-16H-dinaphtho[2,3-a J 2 ',3'-l] -carbazole- 

5, 10, 15, 17-tetrone. 

*4, 5' -Dibenzamido-1, 1' -iminodianthraquinone 

Dibenzo[b,def] chrysene-7, 14-dione 

*1, 5-Dibenzoylnaphthalene 

N, N'-Dibenzylethylenediamine 

N, N'-Dibenzylethylenediamine diacetate 

N, N-Dibenzylsulf anilic acid 

2,4' -Dibromoacetophenone 

*3,9-Dibromo-7H-benz[de]anthracen-7-one 

m-Dibromobenzene 

p-Dibromobenzene 

2, 2' -Dibromobiphenyl 

Dibromodibenzo[b,def] chrysene-7, 14-dione 

ar-Dibromoethylbenzene 

2,6-Dibromo-l, 5-naphthalenediol 

2,6-Dibromo-4-nitrophenol 

5, 13-Dibromo-8, 16-pyranthrenedione 

Dibromoviolan throne 

2, 5-Dibutoxy aniline 

p-Dibutoxybenzene 

l,4-Dibutoxy-2-chloro-5-nitrobenzene 

2, 5-Dibutoxy-4-morpholinobenzenediazonium sulfate 

4-(2,5-Dibutoxy-4-nitrophenyl)morpholine 

2,4-Di-tert-butylphenol 

Dibutyltin bis(cyclohexyl maleate) 

3,4-Dichloroaniline 

*2,5-Dichloroaniline and hydrochloride [NH2"l] 

3,4-Dichloroaniline-6-sulfonic acid 

3- ( 2, 4-Dichloroanilino )-l- ( 2, 4, 6-trichlorophenyl ) -2- 

pyr azolin- 5-one . 

*1, 5-Dichloroanthraquinone 

1,5 (and 1, 8)-Dichloroanthraquinone 

1, 8-Dichloroanthraquinone 



TRC. 

AAP, ACY, 
ACY. 

ICI. 

CMG, DUP. 
ACY, ATL, 
TRC. 

DUP. 

DUP. 



DUP, G, ICC, VPC. 

DUP. 

ICI. 

DUP. 

DUP. 

AAP. 



ARA. 

RH, VEL. 
NEP, RIL. 
ACY, DUP, 
ICI. 
EK. 
NAC. 
DUP. 
G, NAC. 



DUP, G, HSH, ICC, ICI, MAY, TRC. 



G, GGY, NAC, SDH, TRC, VPC. 



NAC. 
DUP. 
IDC. 



G, TRC. 










ICI. 










ACY, DUP, 


G, ICI, 


MAY, 


NAC, 


TRC 


ATL, ICI. 










ACY, DUP, 


G, HST, 


ICI, 


TRC, 


VPC 


ICO, WYT. 










WYT. 










ICI. 











DUP, G, MAY, NAC, TRC. 



DOW. 




EDC. 




ICI. 




DOW. 




EK. 




MEE. 




DUP, 


ICI. 


G. 




EKT. 




ALL. 




ALL. 




ALL. 




ALL. 




DOW, 


KPT. 


X. 




DUP, 


MON. 


AAP, 


DUP, KLS, NAC, SDH 


SW. 




EK. 




DUP, 


G, ICI, NAC. 


DUP, 


NAC. 


ICI, 


TRC. 



CYCLIC INTERMEDIATES 



75 



TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1965 --Continued 



Manufacturers 1 identification codes 
(according to list in table 22) 



4, 5-Dichloro-l, 8-anthraquinonedisulfonic acid 

2, 6-Dichlorobenzaldehyde 

2, 6-Dichlorobenzaldehyde oxime 

3-(3,4-Dichlorobenzamido)-l-phenyl-2-pyrazolin-5-one 

Dichlorobenzan throne 

m-Dichlorobenzene 

*o-Dichlorobenzene 

o(and p)-Diehlorobenzene 

*p-Dichlorobenzene 

4, 6-Dichloro-m-benzenedisulf on amide 

4,6-Dichloro-m-benzenedisulfonyl chloride 

*3,3'-Dichlorobenzidine base and salts 

2, A— Diehlorobenzoic acid 

2, 6-Dichlorobenzonitrile 

2,4-Dichlorobenzoyl chloride 

2, 5-Dichlorobenzoyl chloride 1 

8,18-Dichloro-5,15-diethyl-5,15-dihydrodiindolo-(3,2-b: 
3 ',2'-m)triphenodioxazine. 

7 ', 16-Dichloro-6, 15-dihydro-5, 9, 14, 18-anthrazinetetrone 

4, 8 ( and 4, 5 )-Dichloro-9, 10-dihydro-9, 10-dioxo-l, 5 ( and 
l,8)-anthracenedisulfonic acid. 

1, 5-Dichloro-4,8-dihydroxyanthraquinone 

l,5(and l,8)-Dichloro-4, 8(and 4, 5)-dihydroxyanthraquinone — 

6,6'-Diehloro-2,2'-dimethoxybenzidine 

4, 5-Dichloro-3,6-dioxo-l,4-cyclohexadiene-l, 2-dicarboni- 
trile. 

Dichlorodiphenylsilane 

2',7'-Dichlorofluorescein 

2,5-Dichloro-4-hydrazinobenzenesulfonic acid 

2- ( 5, 8-Dichloro-l-hydroxy-2-naphthylazo ) -l-phenol-4-sulf on- 

amide. 
N- ( 6, 8-Dichloro-5-hydroxy-l-naphthyl )-p-toluenesulf on amide- 
s' 14-Dichloroisoviolan throne 

*2,5-Dichloro-4-(3-methyl-5-oxo-2-pyrazolin-l-yl)benzene- 
sulfonic acid. 
2,3-Dichloro-6-methylquinoxaline 

*2,6-Dichloro-4-nitroaniline 

1, 2-Dichloro-4-nitrobenzene 

*l,4-Dichloro-2-nitrobenzene (Nitro-p-dichlorobenzene) 

2,4-Dichlorophenol 

N-[ (2,5-Dichlorophenyl)azo]-N-ethyl-5-sulfoanthranilie acid 
3-(2',6'-Dichlorophenyl)-5-methyl-4-isoxazolecarbonyl 

chloride. 
3-(2',6'-Dichlorophenyl)-5-methyl-4-isoxazolecarboxylic 
acid. 

l-(2,5-Dichlorophenyl)-3-triazenecarbonitrile 

2,6-Dichloropyrazine 

2,5-Dichloro-3,6-di(l-pyrenamino)-p-benzoquinone 

3,6-Dichloropyridazine 

4,7-Dichloroquinoline' 

3, 5-Dichlorosalicylic acid 

*2, 5-Dichlorosulf anilic acid [S0 3 H=1] 

2, 5-Dichloro-4-sulf obenzenediazonium sulfate 

p,oc-Dichlorotoluene 

2, 6-Dichlorotoluene 

a,a'-Dichloroxylene 

2,4-Dichloro-3,5-xylenol 

Dicyclodiepoxycarboxylate (l^ioxide 221) 

Dicyclohexylamine 

Dicyclohexylcarbodiimide 

Dicyclopentadiene (includes cyclopentadiene) 

Dicyelopentadiene dioxide 

2, 5-Diethoxyaniline 

2',5'-Diethoxybenzanilide 

p-Diethoxybenzene 

2, 5-Diethoxy-morpholinobenzenediazonium chloride, zinc 
chloride. 

2',5'-Diethoxy-4'-nitrobenzanilide 

l,4-Diethoxy-2-nitrobenzene 

4-(2, 5-Diethoxy-4-nitrophenyl )morpholine 

«p-(Diethylamino)benzaldehyde 



0. 

DUP. 

OTC. 

EK. 

ACY. 

CPD, 

ACS, 

GGY, 

ACS, 

ABB. 



EK, G. 

CPD, DOW, DUP, DVC, MON, CMC, PPG, SCC, SVT, WOI. 

HKD, MTO. 

CPD, DOW, DUP, DVC, HK, MON, PPG, SCC, SVT, WOI. 



ALL, CWN, IMP, LAK, NAC, UPJ. 



AAP, 


TRC. 


ICI. 




G. 




DUP. 




DUP. 




ALL. 




ARA. 




DCC, 


UCS. 


EK. 




G. 




TRC. 




EK. 




ICI. 




ACY, 


CMG, DUP, G, KLS, PCW, 


X. 




AAP, 


DUP, EKT, G, MEE, TRC 


DUP, 


MON. 


AAP, 


DUP, NAC, PCW, VPC. 


DOW, 


MON. 


G. 




ICO, 


OTC. 


ICO. 




G. 




ACY. 




TRC. 




ACY. 




SDW. 




ICO. 




CMG, 


DUP, G, VPC. 


TRC. 




HN. 




DUP, 


G. 


BPC. 




OTA. 




UCC. 




ABB, 


MON, VGC. 


G. 




ENJ, 


GOC, UCC. 


UCC. 




ALL. 




ALL. 




ALL, 


G. 


ALL. 




ALL. 




ALL, 


G. 


ALL. 




DUP, 


G, NAC. 



76 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 7B. -Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1965 --Continued 



a _ [(2-Diethylamino) ethyl] -cc-phenylcyclohexanemethanol, 
hydrochloride . 

m- (Diethylamino )phenol ( N, N-Diethyl-3-aminophenol ) 

3-[(p-Diethylamino)phenylazo]-lH-l,2,4-triazole 

3-(Diethylamino)propiophenqne 

4-(Diethylamino)-o-tolualdehyde 

*N, N-Diethylaniline 

N, N-Diethyl-m-anisidine 

Diethylbenzene 

Diethyl-[3,3'-biantnra[l,9-cd]pyrazole]-6,6 -dione 

1, l' -Diethyl-4, 4' -carbocyanine iodide ( Cryptocyanine ) 

N, N-Diethylcyclohexylamine 

a,a'-Diethyl-4,4'-dimethoxystilbene 

Nj N-Diethylmetanillc acid 

N :L ,N 1 -Diethyl-4-methoxymetanilamide 

Diethyl-N-methyl-N-piperazine acetate 

N, N-Diethyl-p-nitrosoaniline 

N, N-Diethyl-4-nitroso-m-anisidine hydrochloride 

N, N-Diethyl-4-nitroso-m-phenetidine 

N, N-Di ethyl -p-phenylenediamine 

N, N-Diethyl-m-toluidine 

6, 15-Dihydro-5, 9, 14, 18-anthrazinetetrone 

10,ll-Dihydro-5H-dibenzo[a,d]cyclohepten-5-one 

2,3-Dihydro-l,8-dihydroxyanthraquinone 

9, 10-Dihydro-l, 5-dihydroxy-4, 8-dinitro-9, 10-dioxo-2, 6- 

anthracenedisulfonic acid. 
*9, 10-Dihydro-l, 4-dihydroxy-9, 10-dioxo-2-anthracenesulfonic 

acid (2-Qainizarinsulfonic acid). 
N-( 5, 13-Dihydro-5, 13-dioxoaceanthryleno[ 2, 1-a] -aceanthry- 

l en _7-yl)-9,10-dihydro-l-nitro-9,10-dioxo-2-anthr amide. 

«9, 10-Dihydro-9, 10-dioxo-l, 5-anthracenedisulf onic acid 

*9, 10-Dihydro-9, 10-dioxo-l, 5-ar.thracenedisulf onic acid, 

disodium salt. 
9, 10-Dihydro-9, 10-dioxo-l, 5 (and 1, 8 )-anthracenedisulf onic 

acid and salt. 

9, 10-Dihydro-9, 10-dioxo-l, 8-anthracenedisulf onic acid 

*9, lO-Dihydro-9, 10-dioxo-l, 8-anthracenedisulf onic acid, 

potassium salt. 
*9, 10-Dihydro-9,10-dioxo-2,6-anthracenedisulfonic acid and 

salt. 
*9, 10-Dihydro-9, 10-dioxo-l-anthracenesulf onic acid and salt 

(Gold salt). 
9, 10-Dihydro-9, 10-dioxo-2-anthracenesulfonic acid and salt 

(Silver salt). 

9, 10-Dihydro-9,10-dioxo-2-anthroic acid 

3,4-Dihydro-3,4-dioxo-l-naphthalenesulfonic acid, sodium 

salt. 
10, ll-Dihydro-5-[3-(methylaminopropyl ) J -5H-dibenzol a,d J- 
cyclohepten-5-ol. 
*9, 10-Dihydro-5-nitro-9, 10-dioxo-l-anthracenesulf onic acid— 
9,10-Dihydro-5(and 8 )-nitro-9, 10-dioxo-l-anthracenesulf onic 

acid. 
9, 10-Dihydro-8-nitro-9, 10-dioxo-l-anthracenesulf onic acid— 
9, 10-Dihydro-8-nitro-9, 10-dioxo-l-anthracenesulf onic acid, 
sodium salt. 

*9, 10-Dihydro-l-nitro-9, 10-dioxo-2-anthroic acid 

l,4-Dihydro-4-oxo-2, 6-pyridinecarboxylic acid 

2,3-Dihydro-4H-pyran 

*l,4-Dihydroxyanthraquinone (Ouinizarin) 



Manufacturers' identification codes 
(according to list in table 22) 



*1, 5-Dihydroxyanthraquinone (Anthraimfin) 

1,5 (and 1, 8)-Dihydroxyanthraquinone 

*l,8-Dihydroxyanthraquinone (Chrysazin) 

*2,6-Dihydroxyanthraquinone (Anthraflavic acid) 

2, 5-Dihydroxybenzenesulf onic acid ( tfydroquinone sulfonic 
acid ) . 

2,4-Dihydroxybenzophenone 

1, 5-Dihydroxy-4,8-dinitroanthraquinone 

l,5(and l,8)-Dihydroxy-4,8(and 4,5)-dinitroanthraquinone- 

*l,8-Dihydroxy-4,5-dinitroanthraquinone (4,5-Dinitro- 
chrysazin). 



ACY, 


DUP, MON. 


TRC. 




ACY. 




DUP. 




ACY, 


DSC, DUP, NAC, SDH 


DUP. 




DOW, 


KPP. 


G. 




EK. 




DUP. 




LIL. 




DUP. 




PCW. 




ABB. 




G. 




DUP. 




G. 




FMT. 




DUP. 




TRC. 




LIL. 




DUP. 




VPC. 




AAP, 


HSH, PAT. 


ICI, 


NAC. 


ACY, 


DUP, TRC. 


DUP, 


G, ICI, TRC. 


DUP, 


TRC. 


DUP. 




G, ICI, NAC, TRC. 



AAP, DUP, G, ICI, NAC, TRC, VPC. 

AAR, ACY, DUP, G, ICI, MAY, NAC, TRC. 

DUP, NAC. 

ACY, NAC. 

EK. 



DUP, MAY, NAC, TRC. 

ICI, TRC. 

MAY, NAC. 
DUP. 

DUP, G, NAC, TRC. 

SDW. 

QKO. 

AAP, ACY, CMG, DUP, EKT, G, HSH, ICC, ICI, JTC, MAY, 

NAC, TRC. 

ACY, CMG, DUP, G, NAC, TRC. 

AAP, DUP, TRC. 

DUP, G, ICI. 

DUP, G, NAC, TRC. 
NES. 

DUP, G. 

AAP, ICC, ICI, VPC. 

TRC. 

DUP, EKT, G, ICC, ICI. 



CYCLIC INTERMEDIATES 



77 



--Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



10, 10'- (Dihydroxyethanediylidene)dian throne 

4, 5-Dihydroxy-2,7-naphthalenedisulfonic acid ( Chronotropic 
acid). 

6, 7-Dihydroxy-2-naphthalenesulf onic acid 

3, 5-Dihydroxy-2-naphthoic acid 

lip .21-Dihydroxypregna-4, 17(20 )-cis-dien-3-one 

llp,21-Dihydroxypregna-l,4,17(20)-cis-trien-3-one 

4, 5-Dihydroxy-3-(p-sulfophenylazo)-2,7-naphthalenedisul- 
fonic acid, trisodium salt. 

*16,17-Dlhydroxyviolanthrone (Dihydroxydibenzanthrone) 

m-Diiodobenzene 

2, 5-Diiodobenzoic acid, 2-(2-methoxyethoxy)ethyl ester 

3, 5-Diiodo-4-oxo-l(4H)pyridineacetic acid 

3, 5-Diiodo-L- tyrosine 

N, N '-Diisopropyl-p-phenylenediamine 

2, 5-Dimethoxy aniline 

l,5(and l,8)-Dimethoxyanthraquinone 

2, 5-Dimethoxybenzaldehyde 

*m-Dimethoxybenzene 

*3,3'-Dimethoxybenzidine 

3,3 -Dimethoxybenzidine hydrochloride 

2, 4-Dimethoxybenzoie acid 

2, 6-Dimethoxybenzoyl chloride 

N, N'-[(3,3'-Dimethoxy-4,4'-biphenylylene)bis-(azo)]bis- 
( N-methyltaurine ) . 

2,5-Dimethoxy-P-methyl-|3-nitrostyrene 

N-(3,4-Dimethoxy-a-methylphenethyl)-2-(4-ethoxy-3-methoxy- 
phenyl )acetamide. 

2,5-Dimethoxy-a-methylphenylamine 

1,4— Dimethoxy-2-nitrobenzene 

2, 5-Dimethoxy-4' -nitrostilbene 

3,4-Dimethoxyphenethylamine (Homoveratrylamine) 

4-(2',5'-Dimethoxyphenethyl)aniline hydrochloride 

N-(3,4-Dimethoxyphenethyl)-2-(3,4-dimethoxyphenyl)-acetamide 

3,4-Dimethoxyphenisopropylamine 

(3,4-Dimethoxyphenyl)acetic acid 

(3,4-Dimethoxyphenyl)acetonitrile 

l-(3,4-Dimethoxyphenyl)-2-nitro-l-propene 

*16,17-Dimethoxyviolan throne 

1, 5-(Dimethylamiho)anthraquinone 

m-(Dimethylamino)benzoic acid 

a-(Dimethylaraino)-p-cresol 

6-Dimethylamino-2- [2-(2, 5-dimethyl-l-phenyl-3-pyrryl)- 
vinyl]-l-methyl-l-quinolinium methyl sulfate. 

6-(Dimethylaminoethyl)-2-methoxy-4-nitrophenol 

2-[[ 2-(Dimethylamino)ethyl] -2-thenylamino]-pyridine (non- 
medicinal grade). 

m-(Dimethylamino)phenol 

l-(Dimethylamino)phenylbutyTonitrile 

N-(p-Dimethylaminophenyl)-l,4-naphthoquinoneimine 

*N, N-Dimethylaniline 

7, 12-Dimethylbenz[ a] anthracene 

3,3'-Dimethylbenzidine (o-Tolidine) 

3,3'-Dimethylbenzidine hydrochloride 

*N, N-Dimethylbenzylamine 

a,a-Dimethylbenzyl hydroperoxide 

4-(a,a-Dimethylbenzyl)-2-phenylazophenol 

*2, 2'-Dimethyl-l,l'-bianthraquinone 

Dimethyl-6, 12-ceroxenol acetate 

5,5-Dimethyl-l,3-cyclohexanedione 

N, N-Dimethylcyclohexylamine 

N,a-Dimethylcyclopentaneethylamine 

N, N-Dimethyl-2, 2-diphenylacetamide 

2 ' ,T -Dime thy If luor an 

5,5-Dimethylhydantoin 

2,3-Dimethjrlindole- 

2, 5-Dimethyl-4(2 )-morpholinylmethylphenol hydrochloride 

*N, N-Dimethyl-p-nitrosoaniline 

N, N-Dimethyl-3-nitro-p-toluenesulf on amide 

N, N-Dimethyl-p-phenylenediamine 

N, N-Dimethyl-p-phenylenediamine hydrochloride 

1, 4-Dimethylpiper azine 



ICI. 






HSH, 


NAG. 




FMT, 


-G, IDC, NAC. 


G. 






UPJ. 






UP J. 






EK. 






ACY, 


DUP, 


G, ICI, MAY, NAC. 


EK. 






SDW. 






SDW. 






EK. 






DUP. 






ALL, 


EKT, 


KLS. 


TRC. 






CWN. 






ACY, 


ICO, 


TBK. 


ALL, 


BUC, 


CWN, DUP, LAK, SDH 


ALL, 


CWN. 




ACY. 






ICO. 






ALL, 


BUC, 


G. 



LIL. 

x. 

LIL. 

LIL. 

LIL. 

LIL. 

LIL. 

G, ICI, MAY. 

AAP. 

SDH. 

TKL. 



MEE. 
ABB. 

ACY, 

ICO. 

NAC. 

ACY, 

EK. 

CWN, 

AAP, 

ICO, 

ACP. 

TRC. 

AAP, 

WLM. 

EKT. 

DUP, 

LIL. 

ARA, 

WLM. 

GLY. 

DUP. 

IDC. 

ACY, 

G. 



EKT, 

EK. 

COK, 



DSC, DUP, NAC, SDH. 

DUP. 

DUP, EK. 

MLS, RH. 



ACY, CMG, DUP, G, ICI, TRC. 

EKT. 
UPJ. 



DUP, NAC. 
NAC. 
JCC, SEL. 



78 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



N-[[ 4- (Dimethylsulf amoyl) -o-tolyl] azo] -N-methyl-5-sulfo- 
anthranilic acid. 

N, N-Dimethylsulf anilic acid 

N, N-Dimethyl-p-toluidine 

2,4-Dinitroaniline 

*p-(2,4-Dinitroanilino)phenol 

1, 5(and l,8)-Dinitroanthraquinone 

N, N'-(2,4-Dinitro-l,5-anthraquinonylene)dioxamic acid 

3',4-Dinitrobenzanilide 

m-Dinitrobenzene 

2,4-Dinitrobenzenesulfonic acid 

3, 5-Dinitrobenzoic acid 

3, 5-Dinitrobenzoyl chloride 

10,10'-Dinitro[3,3'-bi-7H-benz[de] anthracene] -7, 7 '-dione 

Dinitrocaprylphenol 

2,4-Dinitrocumene 

3,3'-Dinitro-N, N'-diacetylbenzidine 

3', 5' -Dinitro-2' -hydroxyacetanilide 

l-(3,5-Dinitro-2-hydroxyphenylazo)-2-naphthol 

*2,4-Dinitrophenol, tech 

(2,4-Dinitrophenyl)hydrazine 

3, 5-Dinitrosalicylic acid 

*4,4'-Dinitrostilbene-2,2'-disulfonic acid 

2,4-Dinitrotoluene 

2, 4 (and 2,6)-Dinitrotoluene 

3, 5-Dinitro-p-toluenesulf onic acid 

2,4-Di-tert-pentylphenol 

1, 5-Diphenoxyanthraquinone 

1,5 (and 1, 8 ) -Diphenoxyanthr aquinone 

1,8-Diphenoxyanthraquinone 

Diphenylacetaldehyde 

Diphenylacetic acid 

Diphenylamine 

2, 8-Diphenylanthra [l,2-d: 6, 5-d'] bisthiazole-6, 12-dione 

a-d-l,2-Diphenyl-4-dimethylamino-2-hydroxy-3-methylbutane, 
camphor sulfonate. 

N, N'-Diphenylethylenediamine 

Diphenylme thane 

2-(Diphenylmethoxy)-N, N-dimethylethylamine (Diphenhydra- 
mine base). 

2, 5-Diphenyloxazole 

l,3-Diphenyl-l,3-propanedione 

1, 3-Diphenyltriazene 

2,2'-Dithiodibenzoic acid 

*l,4-Di-p-toluidinoanthraquinone 

1, 5-Di-p-toluidinoanthr aquinone 

1,8-Di-p-toluidinoanthr aquinone 

l,4-Di(p-toluidine )-5;8-dihydroxy an thr aquinone 

*Divinylbenzene 

Dixylylguanidines, mixed 

Dodecylbenzene. (See Aliylbenzenes. ) 

Dodecylbenzyl chloride 

Dodecylmethylbenzyl chloride 

*p-Dodecylphenol 

Bosin (2',4',5',7'-Tetrabromofluorescein) 

Epoxycyelohexyladipate (Ipoxide 289) 

3-(lpoxyethyl)-7-oxabicyclo[4.1.0]heptane (Epoxide 206) 

o-Ethoxybenzoic acid 

6-Ethoxy-2-benzothiazolethiol 

4- Ethoxy-3-methoxybenzaldehyde 

4-Ethoxy-3-methoxybenzyl alcohol 

1- (4- Ethoxy-3-methoxybenzyl )-6, 7-dimethoxy-3-methyl- 
isoquinoline. 

(4-Ethoxy-3-methoxyphenyl )acetic acid 

2-Ethoxy-l-naphthaldehyde 

2-Ethoxynaphthalene 

2-Ethoxy-l-naphthoic acid 

2-Ethoxy-l-naphthoyl chloride 

4-Ethoxy-o-phenylenediamine 

3-(Ethylamino)-p-cresol 

3-(Ethylamino)-p-toluenesulfonic acid [S03H=1] 

*N-Ethylaniline, refined 



G. 




EK, RSA, 


SEL. 


AAP, ACT. 




DUP, G, NAC. 


AAP, ICI, 


TRC. 


TRC. 




DUP. 




DUP, NAC. 




TRC. 




DUP, GAM, 


SAL. 


EK. 




DUP, MAY. 




RH. 




DUP. 




AAP. 




TRC. 




TRC. 




AAP, DUP, 


NAC, SDC, VPC. 


EK. 




EK. 




ACT, DUP, 


G, GGY, NAC, SDH, TRC 


DUP, NAC. 




DUP, MOB. 




NAC. 




PAS. 




DUP, ICI, 


VPC. 


AAP, DUP. 




EKT, ICI. 




ARA. 




ARA, BPC. 




ACY, DOW, 


DUP, 0R0. 


ICI. 




LIL. 




DOW, RPC. 




ARA. 




ARA. 




ARA. 




EK. 




NAC. 




LIL, MEE. 




ATL, CMG, 


G, ICI, NAC, TRC, VPC 


ICI. 




ICI. 




ICI. 




DOW, FG, 


KPP. 


ACT. 




CO. 




x. 




G, MON, UCC, x. 


ICC. 




UCC. 




UCC. 




ACT. 




ARA, DUP. 




LIL. 




LIL. 




LIL. 




LIL. 




ICO. 




ICO, NAC. 




ICO. 




ICO, OPC. 




TRC. 




DUP. 




DUP. 




ACY, DUP, 


NAC, SDH. 



CYCLIC INTERMEDIATES 



79 



TABLE 7B. 



-Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



2-(N-Ethylanilino)ethanol 

[ 2-( N-Ethylanilino )ethyl] trimethylammonium chloride 

3-(N-Ethylanilino)propionitrile 

a-(N-Ethylanilino)-m-toluenesulfonic acid 

<x-(N-Ethylanilino)-p-toluenesulfonic acid 

N-Ethyl-p-anisidine 

2-Ethylanthraquinone 

*Ethylbenzene 

o-(p-Ethylbenzoyl)benzoic acid 

Ethylbenzyl chloride 

9-EthylcarbazQle 

N-Ethyl-N-(2-chloroethyl)aniline 

N-Ethyl-1-cyclohexen-l-ylamine 

3,3'-Ethylenedioxydiphenol 

Ethylenimine 

2-[ N-Ethyl-p- [(6-methoxy-2-benzo-thiazolyl)azo]anilino ]- 
ethanol. 

N-Ethyl-1-naphthylamine 

9-Ethyl-3-nitrocarbazole 

p-Ethylphenol 

*N-Ethyl-N-phenylbenzylamine 

N-Ethyl-N-phenylbenzylamine sulfonic acid 

Ethylphenylmalonic acid, diethyl ester 

l-(o-Ethylphenyl)-3-methyl-2-pyrazolin-5-one 

5-Ethyl-2-picoline (2-Methyl-5-ethylpyridine) (MKP) 

1-Ethylpiperidine 

2-Ethylpyridine 

N-Ethyl-5-sulfoanthranilic acid 

6-Ethyl-l, 2, 3, 4-tetrahydro-l, 1, 4, 4-tetramethylnaphthalene- 

N- Ethyl -m-toluidine 

N-Ethyl-o-toluidine 

2-(N-Ethyl-m-toluidino)ethanol 

3-(N-Ethyl-m-toluidino)-l, 2-propanediol 

3-(N-Ethyl-m-toluidino)propionitrile 

1-Ethynyl-l-eyclohexanol 

Fluorescein (3',6'-Dihydroxyfluoran) 

l-Fluoro-2, 4-dinitrobenzene 

o-Fluorotoluene 

4-Formyl-m-benzenedisulfonic acid 

m-Formylbenzenesulfonic acid, sodium salt 

*o-Formylbenzenesulfonic acid (o-Sulfobenzaldehyde) 

Fur an 

Furfuryl alcohol 

Furfurylamine 

Gentisic acid (2,5-Dimethoxybenzoic acid), methyl ester— 

Hexachlorobenzene 

Hexachlorocyclopentadiene 

1, 4, 5, 6, 7, 7-Hexachloro-5-norbornene-2, 3-dicarboxylic acid 

Hexachlorophenyl ether 

Hexadecachlorophthaloeyanine 

Hexa(2-methyl-l-aziridinyl )-l,3, 5-phosphotriazine 

Hippuric acid 

*p-Hydrazinobenzenesulfonic acid 

4-Hydrazino-m-toluenesulfonic acid 

Hydroquinone, tech 

2'-Hydroxyacetophenone 

3'-Hydroxyacetophenone 

4'-Hydroxyacetophenone 

3 ' -Hydroxyacetophenone benzoate 

6'-Hydroxy-m-acetotoluidide 

p-Hydroxybenzaldehyde 

*p-Hydroxybenzenesulfonic acid 

2-Hydroxy-llH-benzo [a]carbazole-3-carboxylic acid 

p-Hydroxybenzoic acid 

p-Hydroxybenzoic acid, butyl ester 

p-Hydroxybenzoic acid, ethyl ester 

p-Hydroxybenzoic acid, n-heptyl ester 

*p-Hydroxybenzoic acid, methyl ester 

*p-Hydroxybenzoic acid, propyl ester 

4-Hydroxycoumarin 

13b-Hydroxy-2, 8-dimethylnaphtho[3 . 2. 1-kl] xanthen-9(l3bH)- 
one. 



Manufacturers ' identification codes 
(according to list in table 22) 



DUP, 


EKT. 


DUP. 




EKT. 




G. 




NAC, 


SDH, TRC, WJ. 


EKT. 




G, NAC. 


DOW, 


ENJ, FG, KPP, KPT 


G, NAC. 


BPC. 




AAP, 


ICC. 


DUP. 




UCC, 


x. 


IDC. 




DOW. 




TRC. 




DSC, 


DUP. 


AAP, 


ICI. 


ACY. 




DOT, 


NAC, SDH. 


VPC. 




BPC, 


MAL. 


TRC. 




UCC. 




RIL. 




RIL. 




G. 




GIV. 




DUP. 




DUP. 




G. 




EKT. 




DUP, 


EKT, G. 


cue, 


EKT, NAC. 


ICC. 




EK. 




EK, 


PIC. 


G, SDH. 


G. 




G, NAC, SDH, VPC. 


DUP. 




QKO. 




MLS. 




ICO. 




KPS, 


KPT, SCC. 


HK, 


VEL. 


HK. 




DOW. 




ICC. 




ICO. 




BPC. 




G, STG, WJ. 


G. 




CRS, 


EKT, MAN. 


OTC. 




SDH. 




OTC. 




SDH 




TRC 




DOW 




DOW 


MON, UPF. 


G. 




HN, 


WSN. 


UN, 


WSN. 


HN, 


WSN. 


WSN 




HN, 


ICO, SEL, WSN. 


HN, 


ICO, WSN. 



MON, SHC, SIN, SNT, TOC, UCC. 



80 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1 965 --Continued 



Manufacturers' identification codes 
(according to list in table 22) 



3-[N-(2-Hydroxyethyl)anilino]propionitrile 

N-|3-Ifydroxyethyl-2,4-d ihydroxybenzanri.de 

3-Hydroxy-N-(2-hydroxyetnyl)-2-naphthanride 

N-t 7-Ifydroxy-8- [2-hydroxy-5-(methylsulf amoylphenyl )azo] - 

1-naphthyl] acetanri.de. 
N-L~7-Hydroxy-8-[(2-hydroxy-5-nitrophenyl)azo]-l-naphthyl]- 

acetanride. 
7-Hydroxy-8- [[<+'-[ (p-hydroxyphenyl )azo] -4-biphenylyl] azo] - 

1, 3-naphthalenedisulfonic acid. 
7-Hyd roxy-8-[[ 4' -[ (p-hydroxyphenyl )azo] -3, 3-dime thyl-4- 
biphenylyl]azo]-l, 3-naphthalenedisulfonic acid. 

4-Hydroxy-N 1 -isopropy lmetanilanri.de 

2-Hydroxy-a 1 , cc 3 -mesitylenediol 

*4-Hydroxymetanilanride 

4-ffydroxymetanilanilide 

*4-Hydroxymetanilic acid 

N-(4-Hydroxymetanilyl)anthranilic acid 

4-Hydroxy-l-methycarbostyril 

3-Rydroxy-2-methylcinchoninic acid 

4-Ifydroxy-N 1 -methy lmetanilanri.de 

N-(Hydroxymethyl)phthalamide 

Ifydroxynaphthaldehyde 

7-Hydroxy-l-naphthalenecarbamic acid, methyl ester 

3-Hydroxy-2,7-naphthalenedisulfonic acid 

*3-Hydroxy-2, 7-naphthalenedisulfonic acid, disodium salt 

7-Hydroxy-l, 3-naphthalenedisulfonic acid 

7-ffydroxy-l, 3-naphthalenedisulfonic acid, dipotassium salt — 

7-Rydroxy-l,3-naphthalenedisulfonic acid, disodium salt 

4-ifydroxy-2-naphthalenesulfonanri.de 

l-Hydroxy-2-naphthalenesulfonic acid, potassium salt 

4-Ifydroxy-l-naphthalenesulfonic acid 

5-Hydroxy-l-naphthalenesulfonic acid 

*6-Ifydroxy-2-naphthalenesulfonic acid 

*6-Rydroxy-2-naphthalenesulfonic acid, sodium salt 

7-Ifydroxy-2-naphthalenesulfonic acid (Cassella's acid) 

8-Hydroxy-l-naphthalenesulfonic acid 

8-Hydroxy-l-naphthalenesulfonic acid, Y-sultone 

4-Ifydroxy-2-naphthalenesulfonie acid benzenesulfonate, 
sodium salt. 

3-Hydroxy-2-naphthanilide (Naphthol AS) 

l-Rydroxy-2-naphthoic acid 

l-lfydroxy-2-naphthoic acid, phenyl ester 

*3-Ifydroxy-2-naphthoic acid (B.O.N.) 

3-lfydroxy-2-naphthoie acid, methyl ester 

3-Ifydroxy-2-naphtho-o-toluidide 

N-( 2-Ifydroxy- 1-naphthyl Jacetanride 

*N-(7-Rydroxy-l-naphthyl)acetamide 

l-(2-Ifydroxy-l-naphthylazo)-6-nitro-2 -naphthol -4-sulfonic 
acid. 

N-(7-Ifydroxy-l-naphthyl)benzamide 

3'-[(7-Hydroxy-l-naphthyl)carbamoyl]acetanilide 

4-Ifydroxy-7-[ p-(p-nitrobenzanri.do )benzamido ]-2-naphthalene- 

sulfonic acid. 
4-hydroxy-7-(p-nitrobenzamido)-2-naphthalenesulfonic acid — 

2-Ifydroxy-5-nitrometanilic acid 

l-(2-Hydroxy-4-nitrophenylazo)-2-naphthol 

3-Ifydroxy-4-(phenylazo)-2-naphthoic acid 

lla-Hydroxypregn-4-ene-3,20-dione 

4-Hydroxypropiophenone 

a > <x'-[ (a-Hydroxy-p-sulf obenzylidene)bis[ (3-methyl-p- 
phenylene)(ethylimino)]] di-m-toluenesulfonic acid. 
2-Hydroxy-4-sulfo-l-naphthalenediazonium hydroxide, inner 
salt. 

l-Hydroxy-4-p-toluidinoanthraquinone 

2-Inridazolidinone modifications 

*1, l'-Iminobis[4-aminoan'thraquinone] 

1, l'-Iminobis[4-benzamidoanthraquinone] 

*1, l'-Iminobis[5-benzamidoanthraquinone] 

*7,7'-Iminobis[4-hydroxy-2-naphthalenesulfonic acid] 

*1, l / -Iminobis[4-nitroanthraquinone] 

*l,l'-Iminodiaiithraquinone (l,l'-Dianthrimide) 



DUP, ICC. 
IDC. 
IDC. 
TRC. 

TRC. 



TRC. 






ACY. 






CMC, 


DUP, 


NAC, TRC, VPC. 


TRC. 






CWN, 


DUP, 


NAC, TRC. 


TRC. 






ICC. 






DUP, 


ICC, 


TRC. 


TRC. 






ACY. 






ICO. 






TRC. 






ATL. 






ACY, 


G, NAC, TRC, WJ. 


DUP, 


TRC. 




G. 






ACY, 


NAC. 




G. 






EK. 






DUP, 


NAC. 




NAC, 


TRC. 




NAC, 


SNA, 


TMS. 


ACY, 


TRC, 


WJ. 


DUP. 






G, VPC. 




ACY, 


TRC. 




G. 






ATL, 


PCW. 




NAC. 






EK. 






AUG, 


DUP, 


HN, PCW. 


PCW. 






ATL, 


PCW. 




ACY. 






CMG, 


G, TRC. 


TRC. 






TRC. 






TRC. 






DUP. 






DUP, 


G. 




ALL, 


G, TRC. 


TRC. 






ICC. 






UPJ. 






MLS. 






TRC. 






ACY. 






G, ICI. 




RH. 






ACY, 


CMG, 


DUP, G, ICI, MAY, NAC, TRC 


ACY, 


MAY. 




G, ICI, TRC. 


CMG, 


DUP, 


NAC, TRC. 


ACY, 


DUP, 


ICI, MAY, TRC. 


ACY, 


DUP, 


G, ICI, MAY, NAC, TRC. 



CYCLIC INTERMEDIATES 

TABLE 7B. —Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



1,3-Indandione 

Indole-3-acetic acid- 

Indole-2,3-dione 

1-Iodonaphthalene 

Isobutylbenzene 

*Isocyanic acid derivatives : 

Bitolylene diisocyanate (TODI) 

Cyclohexyl isocyanate 

Dianisidine diisocyanate (DADI) 

3,4-Dichlorophenyl ester 

*Diphenylmethane 4,4'-diisocyanate (MDI) 

Phenylisocyanate 

Polymethylene polypheny lisocyanate 

Toluene 2,4-diisocyanate 

Toluene 2,4- and 2,6-diisocyanate (65/35 mixture) 

*Toluene 2,4- and 2,6-diisocyanate (80/20 mixture) 

Other isocyanic acid derivatives 

Isonicotinic acid, methyl ester 

Isonicotinonitrile 

Isooctylphenol 

Isophthalic acid (Benzene-l,3-dicarboxylic acid) 

Isophthalic acid, diallyl ester 

Isophthalic acid, dimethyl ester 

Isophthalic acid, diphenyl ester 

N-Isopropylaniline 

Isopropylbenzyl chloride 

4,4'-Isopropylidenebis[2, 6-dibromophenol] (Tetrabromobis- 

phenol A). 
4,4'-Isopropylidenebis[2,6-dichlorophenol] ( Tetrachloro- 
bisphenol A). 

5,5'-Isopropylidenebis(2-hydroxy-m-xylene-a, a'-diol) 

*4,4'-Isopropylidenediphenol (Bisphenol A) 

4,4'-Isopropylidenediphenol, ethoxylated 

4,4'-Isopropylidenediphenol, propoxylated 

o-Isopropylphenol 

4-Isopropyl-m-phenylenediamine ■ 

Isothiocyanic acid, phenyl ester 

*Isoviolanthrone (isodibenzanthrone) 

*Leuco quinizarin (1,4, 9,10- Anthratetrol) 

2,4-Lutidine ■ 

3,4-Lutidine 

Mandelonitrile 

*Melamine 

dl-p-Mentha-1, 8-diene (Limonene) 

p-Mentha-l,4(8)-diene 

*o-Mercaptobenzoic acid 

Metanilamide 

*Metanilic acid (m-Aminobenzenesulfonic acid) 

1-Methoxyanthraquinone 

4-Methoxymetanilic acid 

6-Methoxymetanilic acid 

4'-Methoxy-2-(p-methoxyphenyl)acetophenone 

4-Methoxy-l-naphthol 

N-(2-Methoxy-l-naphthyl)aeetamide 

2-Methoxy-4-nitrophenol 

6-Methoxy-8-nitroquinoline 

m-Methoxyphenol 

Methoxyphenylacetic acid 

4' -Methoxypropiophenone 

6-Methoxytetralone 

*1- ( Methylanri no ) anthraquinone 

l-(Methylamino)-4-p-toluidinoanthraquinone 

N-Methylaniline 

2-(N-Methylanilino)ethanol 

3-(N-Methylanilino)propionitrile 

5-Methyl-o-anisidine [ NH 2 =l] 

m-Methylanisole 

N-Methylanthranilic acid 

2-Methylanthraquinone 

3-Methylbenzo'[f]quinoline 

2-Methylbenzothiazole 

a-Methylbenzyl alcohol 



PIC. 








SDW. 








NAC. 








EK. 








PLC. 








UPJ. 








CWN, 


OTC. 






CWN, 


UPJ. 






DUP. 








DuT?, 


MOB, 


NAC, UPJ. 




CWN, 


MOB, 


OTC. 




MOB, 


UPJ. 






DUP, 


MOB. 






DUP, 


MOB, 


NAC. 




DUP, 


MOB, 


NAC, CMC, UCC. 




DUP, 


EK, 


MOB, OTC. 




RIL. 








RIL. 








G, PRD. 






ACC, 


SOC. 






FMP. 








MTR. 








BJL. 








ACY, 


EKT. 






BPC. 








DOW. 








DVC. 








ARK. 








DOW, 


MON, 


SHC, UCP. 




APD. 








APD. 








TNA. 








DUP. 








TNC. 








DUP, 


G, MAY. 




AAP, 


ACY, 


BL, EKT, HSH, ICC, NAC, TRC 


ACP, 


KPT. 






RIL. 








KF. 








ACN, 


ACY, 


FIS, RCI. 




GIV, 


HNW. 






GIV. 








EVN, 


LIL, 


MED. 




CMG, 


VPC. 






DUP, 


NAC, 


TRC. 




AAP, 


G. 






ACY, 


CMG. 






G. 








CTN. 








SDH. 








TRC. 








MEE. 








GAM. 








EK. 








SDW. 








LIL. 








GAM. 








AAP, 


ACY, 


DUP, G, NAC, TRC. 




G. 








ACY, 


DUP. 






G. 








DUP. 








DUP. 








GIV. 








ICC. 








ACY, 


NAC. 






ACY, 


G. 






FMT. 








UCC. 









82 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1 965 --Continued 



N-Methylbenzylamine 

Methyl benzyl ether 

5-(l-Methylbutyl)barbituric acid 

3-Methylcholanthrene 

Methylcyclohexane 

Methylcyclohexenecarboxaldehyde 

N-Methylcyclohexylamine 

4-Methyl-a,a-diphenyl-l-piperazineethanol dihydrochloride — 

N-Methyleneaniline 

4,4'-Methylenebis[2-chloroaniline] 

4,4'-Methylenebis[N, N-diethylaniline] 

*4,4'-Methylenebis[N, N-dimethylaniline] (Methane base) 

4,4'-Methylenebis[N, N-dimethyl-3-nitroaniline] 

5,5'-Methylenebis[toluene-2,4-diamine] 

*4, 4'-Methylenedianiline 

5,5'-Methylenedisalicylic acid 

5-Methylene-2-norbornene 

Methylhydroquinone 

6-Methyl-2-(2-methyl-6-quinolyl)-7-benzothiazolesulfonic 

acid. 

Methylnaphthalene, crude 

N-Methyl-4'-nitroacetanilide 

N-Methyl-p-nitroaniline 

5-Methyl-4-nitro-o-anisidine 

4-Methyl-2-nitroanisole 

2-Methyl-l-nitroanthraquinone 

2-Methyl-5-nitroimidazole 

N-Methyl-N-nitroso-p-toluenesulfonamide 

Methylnorbornene-2,3-dicarboxylic anhydride, isomers 

4-Methyl-7-oxabicyclo[4.1.0]heptane-3-carboxylic acid, 

(4-methyl-7-oxabicyclo [4 . 1 . 0] hept-3-yl )methyl ester 

(Epoxide 201). 

m-(3-Methyl-5-oxo-2-pyrazolin-l-yl)beneenesulfonamide 

m-(3-Methyl-5-oxo-2-pyrazolin-l-yl )benzenesulfonic acid 

*p-(3-Methyl-5-oxo-2-pyrazolin-l-yl )benzenesulfonic acid 

3-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-l,5-naphthalenedi- 

sulf onic acid . 
*4-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-m-toluenesulfonic acid 

[S0 3 H=1]. 

2-Methyl-5-phenylbenzoxazole 

1-Methyl-l-phenylhydrazine 

5-Methyl-3-phenyl-4-isoxazolecarboxylic acid 

5-Methyl-3-phenyl-4-isoxazolecarboxylic acid hydrochloride — 

*3-Methyl-l-phenyl-2-pyrazolin-5-one (Developer Z) 

Methyl phenyl sulfide (Thioanisole) 

1-Methylpiperazine 

2-Methyl-l-piperidinepropanol 

l-Methyl-4-piperidinol 

1-Methylpyrrole 

*<x-Methylstyrene 

N-Methyl-5-sulfoanthranilic acid 

2-(Methylsulfonyl)-4-nitroaniline 

p-(Methylthio)aniline hydrochloride— 

4-(Methylthio)-m-cresol 

3-Methylthiophene 

p-(Methylthio)phenol 

3-Methyl-6-p-toluidino-7H-dibenz[f,ij]isoquinoline-2,7(3H)- 

dione. 

3-Methyl-l-p-tolyl-2-pyrazolin-5-one 

1-Naphthaldehyde 

^Naphthalene, solidifying at 79° C. or above (refined flake) 

(from domestic crude). 

1, 5-Naphthalenediol ( 1, 5-Dihydroxynaphthalene ) 

1, 5-Naphthalenedisulf onic acid 

2,7-Naphthalenedisulfonic acid 

1-Naphthalenesulfonic acid 

1-Naphthalenesulfonic acid, sodium salt 

2-Naphthalenesulfonic acid 

2-Naphthalenesulfonic acid, sodium salt 

2-Naphthalenesulfonyl chloride 

*1, 4, 5,8-Naphthalenetetracarboxylie acid 



Manufacturers' identification codes 
(according to list in table 22) 



ICO, MLS. 

UCC. 

LIL. 

EK. 

PLC. 

UCC. 

DUP. 

ABB. 

DUP. 

DUP. 

ACY, G. 

ACY, DSC, DUP, G, NAC, SDH, 

G. 

DUP, NAC. 

DOW, DUP, NAC. 

HN. 

DOW. 

EKT. 

DUP. 

KPT, VEL. 

G, NAC. 

G. 

PCW. 

DUP. 

DUP, G, ICI, TRC. 

PDA. 

EK. 

NAC. 

UCC. 



CMG, VPC. 

G, TRC, VPC. 

AAP, ACY, CMG, DUP, G, TRC, VPC. 

TRC. 



CMG, G, VPC. 



EK. 



EK. 

ICO. 

ICO. 

DOW, DUP, NAC, SDH, SDW, VPC. 

PIT. 

UCC. 

LIL. 

ARA. 

DUP. 

ACP, CLK, DOW, HPC, SKL. 

G. 

EKT. 

evn. 

CRZ. 
SDW. 
CRZ. 



VPC. 
COK. 
KPT, NAC, RIL. 

NAC. 

AUG, DUP, NAC. 

DUP, TRC. 

TRC. 

ICO, TRC. 

ACY, FIN, NAC. 

ACY. 

DUP. 

AAP, G, HST, TRC. 



CYCLIC INTERMEDIATES 



83 



TABLE 7B. 



■ Cyclic intermediates for which U. S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



1,3,6-Naphthalenetrisulfonic acid 

Naphthalic anhydride 

Naphthalimide 

2H-Naphth[l,8-cd]isothiazole-3,5-disulfonic acid, 1,1- 

dioxide, trisodium salt. 
1-Naphthoic acid 

*l-Naphthol (cc-Naphthol) 

2-Naphthol, tech. (8-Naphthol) 

p-Naphtholbenzein 

1,4-Naphthoquinone 

Naphthostyril 

*Naphth[l, 2-d] [l,2,3]oxadiazole-5-sulfonic acid 

1-Naphthylamine (a-Naphthylamine) 

2-Naphthylamine (B-Naphthylamine) 

p- ( 2-Naphthylamino )phenol ( N- (p-Hydroxyphenol ) -2-naphthyl- 
amine). 

cc-Naphthylphenyloxazole 

2- ( Naphthylthio ) acetic acid 

Nicotinonitrile (3-Cyanopyridine) 

Nitro-aceanthra [2, 1-a] aceanthrylene-5, 13-dione 

4'-Nitroacetanilide 

2'-Nitro-p-acetanisidide 

3 ' -Nitro-p-acetanisidide 

4'-Nitro-o-acetanisidide 

2'-Nitro-p-acetophenetidide 

3'-Nitroacetophenone 

5'-Nitro-o-aeetotoluidide 

m-Nitroaniline 

o-Nitroaniline 

*p-Nitroaniline 

2-Nitro-p-anisidine [NH2=1] 

*4-Nitro-o-anisidine [NH2=l]- 

*5-Nitro-o-anisidine [NH2=l]- 

o-Nitroanisole 

p-Nitroaaisole 

4-Nitroanthranilic acid 

4(and 5)-Nitroarithranilic acid '■ 

5-Nitroanthranilic acid 

1-Nitroanthraquinone 

2- (4-Nitro-2-anthraquinonyl )anthra[ 2, 3-d] -oxazole-5, 10- 
dione. 

m-Nitrobenzaldehyde 

3'-Nitrobenzanilide 

4'-Nitrobenzanilide 

*Nitrobenzene 

■xm-Nitrobenzenesulfonic acid 

*m-Nitrobenzenesulfonic acid, sodium salt 

5'-Nitrobenzenesulfono-o-toluidide 

m-Nitrobenzenesulfonyl chloride 

p-Nitrobehzenesulfonyl chloride 

5-Nitro-2-benzimidazolinone 

m-Nitrobenzoic acid 

m-Nitrobenzoic acid, sodium salt 

p-Nitrobenzoic acid 

2-(m-Nitrobenzoyl)-o-acetanisidide 

m-Nitrobenzoyl chloride 

p-Nitrobenzoyl chloride 

4' -Nitro-4-biphenylcarboxylie acid 

2-Nitro-p-cresol 

Nitrocyclohexane 

5-Nitro-4,6-diaminopyrimidine 

Nitrodiphenylamine 

5-Nitro-2-furaldehydesemioxamazone 

5-Nitro-2-furanmethanediol, diacetate 

5-Nitroisatoic anhydride 

5-Nitroisophthalic acid »- 

1-Nitronaphthalene ' 

*3-Nitro-l,5-naphthalenedisulfonic acid 

8(and 5)-Nitro-l(and 2)-naphthalenesulfonic acid 

4-Nitronaphthalic anhydride 

*7(and 8)-Nitronaphth[l,2-d] [l,2,3]oxadiazole-5-sulfonic acid 



DUP. 






DUP, 


G, NAC. 


DUP. 






COK. 






DUP, 


NAC, 


UCC. 


ACY, 


NAC, 


SW. 


EK. 






EKT. 






DUP, 


NAC. 




CMG, 


G, NAC, TRC, VPC. 


DUP, 


NAC. 




X. 






G. 






ARA. 






ACY. 






NEP, 


RIL. 




ICI. 






G, TRC. 




DUP, 


SDH. 




AAP. 






DUP. 






AAP. 






SDH. 






DUP. 






ACY, 


DUP, 


TRC. 


AAP, 


MON. 




AAP, 


MON, 


SDC, UPM. 


DUP, 


SDH. 




AAP, 


DUP, 


SDH. 


ACY, 


ALL, 


DUP, KLS. 


AAP, 


DUP, 


MON. 


DUP. 






DUP. 






DUP. 






MEE, 


TRC. 




ACY. 






G. 






NAC, 


SDH. 




DUP. 






G. 






ACY, 


DUP, 


MON, NAC. 


ACY, 


DUP, 


NAC. 


AAP, 


G, MAY, MON, MRA 


RBC. 






G. 






EK. 






DUP. 






SDH, 


WAY. 




WAY. 






DUP. 






G. 






HK. 






DUP, 


HK. 




DUP, 


TRC. 




SW. 






DUP. 






KF. 






ACY. 






NOR. 






NOR. 






MEE. 






G, GAM. 




DUP, 


NAC. 




G, NAC, TRC. 


G. 






G, NAC. 




G, NAC, TRC, VPC. 



SYNTHETIC ORGANIC CHEMICALS, 1965 

—Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1965— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



4'-Nitrooxanilic acid 

o-Nitrophenol 

*p-Nitrophenol ■ 

*p-Nitrophenol, sodium salt 

4' -(p-Nitrophenyl )acetophenone 

4-[ (p-Nitrophenyl )azo]-o-anisidine 

2-Nitro-p-phenylenediamine 

4- Nitro-o-phenylenediamine 

(p-Nitrophenyl )hydrazine 

(p-Nitrophenyl )hydrazine hydrochloride 

2-(p-Nitrophenyl)-2H-naphtho[l,2-d] triazole-6, 8-disulfonic 
acid. 

l-(m-Nitrophenyl)-5-oxo-2-pyrazoline-3-carboxylic acid 

3-Nitrophthalic acid 

4- Nitrophthalic acid 

3-Nitrophthalic anhydride 

4-Nitrophthalimide 

5-Nitrosalicylaldehyde 

3(and 5)-Nitrosalicylic acid 

p-Nitrosophenol 

[3-Nitrostyrene 

4-Nitro-4'-(5-sulfo-2H-naphthol[l,2-d]triazol-2-yl)-2,2'- 
stilbenedisulfonic acid. 

m-Nitrotoluene 

o-Nitrotoluene 

p-Nitrotoluene 

Nitrotoluene mixtures 

p-Nitrotoluenesulfonic acid 

*3-Nitro-p-toluenesulfonie acid [S03H=l] 

*5-Nitro-o-toluenesulfonic acid [S03H=l] 

4'-Nitro-p-toluenesulfono-o-toluidide 

3-Nitrotoluic acid chloride 

3-Nitro-p-toluic acid, methyl ester 

*2-Nitro-p-toluidine [NH 2 =l] 

4-Nitro-o-toluidine [NH2=l] 

5-Nitro-o-toluidine [NH 2 =l] 

5-Nitro-2-p-toluidinobenzenesulfonic acid 

*16-Nitroviolan throne 

4-Nitro-m-xylene 

Nitroxylenes, mixed 

2-tert-Nonyl-p-cresol 

Nonyl-dinonylphenol, mixture 

*Nonylphenol 

5-Norbornene-2,3-dicarboxylic anhydride 

Octylphenol 

7-0xabicyclo[4.1.0]heptane 

Qxalacetic acid, diethyl ester, (p-sulf ophenyl )hydrazone 

Oxanilide 

*l-[ (7-0xo-7H-benz[de]anthracen-3-yl)amino] anthraquinone 

*1, l'-[(7-Oxo-7H-benz[de]anthracen-3,9-ylene)diimino]di- 
anthr aquinone . 

2-Qxocyclohexanecarboxylic acid, ethyl ester 

2-0xocyclopentanecarboxylic acid, ethyl ester 

5-Qxo-l-phenyl-2-pyrazoline-3-carboxylic acid 

*5-0xo-l-phenyl-2-pyrazoline-3-carboxylic acid, ethyl ester — 
*5-Qxo-l- (p-sulf ophenyl )-2-pyrazoline-3-carboxylic acid 
( Pyrazolone T ) . 

5-Qxo-l-(p-sulfotolyl)-2-pyrazoline-3-carboxylic acid 

4,4'-0xydianiline 

4,4'-0xydiphenol 

Penicillin, N-ethylpiperidine salt 

1, 1, 3,3,5-Pentamethylindan 

Pentylnaphthalenes ( Amy lnaph thai enes ) 

o-Pentylphenol (o-Amylphenol ) 

p-tert-Pentylphenol 

3,4, 9, 10-Perylenetetracarboxylic acid 

3,4, 9,10- Perylenetetracarboxylic 3,4:9, 10-diimide 

Phenethylamine 

Phenethylamine sulfate 

o-Phenethylbenzoic acid 

o-Phenetidine 

p-Phenetidine 



DUP. 

DUP. 

DUP, MON, SDC, UPM. 

MON, UPM. 

DUP, G. 

AAP. 

WAT. 

DUP, FMT. 

EK. 

EK. 



ACY, 


DUP, 


NAC. 


OWN, 


UPJ. 




TRC 






DUP, 


NAC. 




DUP, 


NAC. 




DUP, 


NAC. 




DUP, 


NAC. 




GGY. 






AAP, 


CMG, 


G, TRC. 


ACY, 


DUP, 


G, NAC, SDH, TRC. 


G. 






X. 






SDH. 






ACY, 


DUP, 


NAC, SDH, SW. 


ABB, 


G. 




BUC, 


DUP, 


KLS, PCW. 


TRC. 






ACY, 


ATL, 


G, ICI, MAY. 


DUP. 






DUP, 


NAC. 




USR. 






JCC. 






G, JCC, MON, PRD, RH, STP, UCP, USR 


NAC. 






G, RH. 




ARA. 






TRC. 






WSN. 






ACY, 


DUP, 


G, ICI, MAY, TRC. 


ACY, 


DUP, 


G, ICI, MAY, NAC, TRC. 


ARA. 






ARA. 






NAC. 






G, SDW, VPC. 


AAP, 


G, ICI, VPC. 


VPC. 






OTC, 


X. 




EK. 






MRK. 






GIV. 






PAS. 






PAS. 






PAS, 


UCP. 




DUP, 


G, NAC. 


DUP, 


G, NAC. 


ICO, 


MLS. 




MLS. 






LIL. 






MON. 






DOW, 


MON. 





CYCLIC INTERMEDIATES 



85 



TABLE 7B. 



■Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



•Phenol: 
•Natural : 

•From coal tar: 1 

39° C, m.p 

82^-84% 

All other 

•From petroleum 

•Synthetic: 

By caustic fusion: U.S.P 

From chlorobenzene by liquid -phase hydrolysis: U.S.P 

From chlorobenzene by vapor-phase hydrolysis: U.S.P 

•From cumene by oxidation: U.S.P 

Phenolsulfonaphthalein, sodium salt — 

Phenothiazin-2-yl-l-propanone 

Fhenoxyacetic acid, sodium salt 

2-Phenoxypropanol 

2-Phenoxypropionic acid 

2-Phenoxypropionyl chloride 

•Phenylacetic acid (a-Toluic acid) 

Phenylacetic acid, ethyl ester, tech 

Phenylacetic acid, methyl ester 

•Phenylacetic acid, potassium salt 

•Phenylacetic acid, sodium salt 

Phenylacetonitrile (a-Tolunitrile) 

4'-Phenylacetophenone 

Phenylacetyl chloride 

2-Phenylanthra[2,3-d] oxazole-5, 10-dione 

»p-Phenylazoaniline (C. I. Solvent Yellow 1) and hydrochloride 

p-Phenylazoaniline sulfate 

4- ( Phenylazo )diphenylamine 

4- ( Phenylazo ) -1-naphthylamine 

4- ( Phenylazo )-m-phenylenediamine (C.I. Basic Orange 2) 

5- ( Phenylazo )salicylic acid 

^-Phenyl-l, 2,4-benzenetriamine 

l-Phenyl-l,3-butanedione 

2-Phenylbutyric acid 

a-Phenyl-o-cresol 

1-Phenyldecane ( Decylbenzene ) 

N, N'-p-Phenylenebis[acetamide] 

m-Phenylenediamine 

o-Phenylenediamine 

p-Phenylenediamine 

Phenyl ether (Diphenyl oxide) 

d-2-Phenylglycine 

d-(-)-2-Phenylglycine and derivatives 

dl-2-Phenylglycine (racemic ) 

Phenylglycine, sodium salt 

d-(-)-2-Phenylglycyl hydrochloride 

5-Phenylhydantoin-- 

Phenylhydrazine 

Phenylhydrazine hydrochloride 

2,2'-[(Phenyl)imino]diethanol (N-Phenyldiethanolamine) 

3,3'-[(Phenyl)imino]dipropionitrile 

Phenylmagnesium bromide 

Phenylmalonic acid, diethyl ester 

o-Phenylphenol 

o-Phenylphenol, chlorinated 

o-Phenylphenol, sodium salt 

p-Phenylphenol 

N-Phenyl-p-phenylenediamine 

Phenylphosphinic acid 

Phenylphosphonic dichloride 

Phenylphosphonothioic dichloride 

Phenylphosphonous acid 

Phenylphosphonous acid, sodium salt 

Phenylphosphorous dichloride 

1-Phenylpiperazine " 

«1-Phenyl-1, 2-propanedione, 2-oxime 

Phenyl-2-propanone 

N-3-Phenylpropyl-p-toluidine 

See footnote at end of table. 



Manufacturers ' identification codes 
(according to list in table 22) 



KPT, PRD. 

ACP, KPT. 

ACP, KPT. 

MER, NPC, PIT, PRD, SW. 



MAL, 

DOW. 

HKD, 

ACP, 

EK. 

WYT. 

BPC. 

ICO. 

ICO. 

ICO, 

BPC, 

BPC. 

BPC. 

BPC, 

BPC, 

BPC, 

DUP, 

ICO. 

G. 

AAP, 

DUP. 

EK. 

DUP. 

DUP. 

TRC. 

RBC. 

EK. 

BPC. 

RBC. 

NAC. 

ACY. 

ACY, 

FMT, 

ACY, 

DOW. 

BPC. 

KF. 

KF. 

NAC, 

OTC. 

ABB, 

DOW. 

EK, 

AAP, 

DUP. 

ARA. 

BPC. 

DOW, 

DOW. 

DOW. 

DOW. 

DUP, 

SF. 

SF. 

SF. 



RSA. 
ICC, 
ORT, 



MON, RCI. 



CLK, HPC, MON, SHC, SKO, SOC. 



OPC. 

GIV, MAL, TBK. 



OPC, TBK. 
OPC. 

OPC, SDW. 
G, NES. 



ACY, DUP, G, NAC. 



DUP, G. NAC. 
MEE, TRC. 
BFG. 



VPC. 
DUP, EKT. 



NEP, ORT, x. 
SK. 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 7B. 



-Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 2365--Continued 



Phenyl 2-pyridyl ketone 

Phenyl 4- pyridyl ketone 

Ehenyl sulfone 

l-Fhenyl-2-thiourea 

Phloroglueinol 

l(2H)-Fhthalazinone 

Ehthalic acid 

Ehthalic acid, diallyl ester 

Ehthalic acid, disodium salt 

*Fhthalic anhydride 

Ehthalide 

Ehthalimide 

Ehthalimide, potassium salt 

IEhthalocyaninatoC 2-)] copper 
Ehthalocyaninato(2-)]iron 

Ehthalocyaninetetrasulfonyl chloride, copper derivative 
Ehthaloyl chloride (Ehthalyl chloride) 

♦Ficolines: 1 

*2-Picoline (a-Picoline) 

3-Picoline (fi -Picoline) 

4-Pieoline (y-Picoline) 

Ficoline (3,4-mixture) 

Picolinic acid 

Picolinonitrile (2-Cyanopyridine) 

3-Picolylamine 

Picric acid (Trinitrophenol) 

2-Pipecoline 

4-Pipecoline 

Piperazine mixture, crude 

*Piperidine 

3-Piperidinopropiophenone hydrochloride 

Polychlorobiphenyl 

Primuline base ■ 

Primulinesulfonic acid 

*Propiophenone 

2-Propylpyridine 

*8, 16-Pyranthrenedione 

Pyridine, refined z 1 

*2° Pyridine 

Other grades 

Pyridine hydrochloride 

2-Pyridineethanol 

3-Pyridinemethanol 

Pyridinium bromide perbrond.de 

3-Pyridinol 

2(lH)-Pyridone 

2-Pyrimidinol 

2-Pyrrolidinone 

3-(l-Pyrrolidinyl)propiophenone hydrochloride 

lH-Pyrrolo [2, 3-6] pyridine 

*Quinaldine 

Quinoline : 

1° and 2° Quinoline 

Other grades 

2,4-Quinolinediol 

8-Quinolinol (8-Hydroxyquinoline, tech. ) 

Quinophthalone (Quinoline yellow, base) 

Resorcinol, monoacetate (nonmedicinal grade) 

Resorcinol, tech 

Resorcinol, mono-fi-hydroxyethyl ether 

p-Resorcylaldehyde— 

(3-Resorcylic acid 

(3-Resorcylic acid, lead salt 

*Salicylaldehyde 

*Salicylic acid, tech 

Salicylic acid, ammonium chromium complex 

Salicylic acid, sodium chromium complex 

Salicylic acid, sodium salt (crude) 

Salicylideneaminoguanidine oleate 



Manufacturers ' identification codes 
(according to list in table 22) 



NEP, RIL. 

RIL. 

NES. 

ICO. 

MRT. 

KPT, NAC, SDH. 

EK, KF. 

FMP. 

INC. 

ACP, GRH, HN, KPS, MON, PCC, RCI, SOC, STP, SW, THC, 

UCC, WTC. 
FMT, NAC. 
DUP, MEE, NAC. 
EK. 

ICC, ICI. 
DUP. 
DUP. 
MON. 

ACP, KPT, RIL, UCC. 

NEP, RIL. 

RIL, UCC. 

ACP, KPT. 

NEP. 

NEP, RIL. 

RIL. 

DUP, NAC, SDC. 

LIL. 

RIL. 

FLM, JCC, x. 

ABB, DUP, RIL. 

ACY. 

MON. 

DUP, NAC. 

ATL. 

LIL, OPC, TBK. 

RIL. 

CMG, ICI, TRC. 

ACP, KPT, NEP, RIL. 

KPT. 

EK. 

RIL. 

RIL. 

ARA. 

NEP. 

FMT. 

GGY. 

G. 

LIL. 

SDW. 

ACY, DUP, NAC. 

ACP, KPT. 

EK. 

DUP. 

GAM. 

DUP, NAC. 

AAP. 

KPT. 

BJL. 



ACY, 
ACY. 
DOW, 
CFC, 
TRC. 
TRC. 
DOW. 
DUP. 



HN, MTR, RDA. 
DOW, HN, MON, SDH. 



See footnote at end of table. 



CYCLIC INTERMEDIATES 



87 



TABLE 7B. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Manufacturers' identification cede 
(according to list in table 22) 



Sitosterols, nonmedicinal 

Sodium phenoxide 

*Styrene, all grades 

(3-Styrenesulfonic acid, sodium salt 

4'-Sulfamoylacetanilide 

Sulfanilic acid (p-Aminobenzenesulfonic acid) and salt 

4-Sulfoanthranilic acid 

«>a-[(p-Sulfobenzylidene)bis[(3-methyl-p-phenylene) (ethyl 
imino)]] di-m-toluenesulfonic acid. 

5-Sulfoisophthalic acid, 1,3-dimethyl ester 

3,3'-Sulfonyldianiline 

4,4'-Sulfonyldianiline 

N, 5'-Sulfonyldianthranilic acid 

3,3'-Sulfonyldinitrobenzene 

4,4'-Sulf onyldiphenol (4,4 '-Dihydroxydiphenylsulfone) 

4-Sulfophthalic acid 

Terephthalic acid 

Terephthalic acid, dihydrazide 

*Terephthalic acid, dimethyl ester 

Terephthalic acid, diphenyl ester 

Terephthaloyldiacetic acid, diethyl ester 

Terphenyl ( Phenylbiphenyl ) 

1,2,4, 5-Tetraaminobenzene 

[4,4', 4", 4'" -Tetr aaminophthalocyaninato ( 2- ) ] copper 

3',3",5',5" -Tetrabromophenolphthalein, ethyl ester 

Tetrabromophthalic anhydride 

Tetrabromo-8, 16-pyranthrenedione 

1,3,6, 8-Tetrabromopyrene 

*1, 4, 5, 8-Tetrachloroanthraquinone 

1,2,4, 5-Tetrachlorobenzene 

1, 2, 4, 5-Tetrachloro-3-nitrobenzene 

a,a,2,6-Tetrachlorotoluene 

Tetrachloroviolan throne 

Tetrahydrofuran 

Tetrahydro-2-methylfuran 

*1,4, 5,8-Tetrahydroxyanthraquinone, leuco derivative 

1,4, 5,8-Tetrakis(l-anthraquinonylamino)anthraquinone 
( Pentanthr imid e ) . 

2-(l,l,3,3-Tetramethylbutyl)-p-cresol 

p-(l, l,3,3-Tetramethylbutyl)phenol 

3,3 ', 5, 5' -Tetramethyldiphenoquinone 

N, N, N', N'-Tetramethyl-p-phenylenediamine dihydrochloride- 

[4,4',4",4'"-Tetranitrophthalocyaninato(2-)]copper 

1, 1,4,4-Tetraphenylbutadiene 

2-(2-Thenylamino)pyridine 

3,3'-Thiobis[7H-benz[de]anthracen-7-one] 

4,4'-Thiodianiline 

6, 6'-Thiodimetanilic acid 

2-Thiopheneacetyl chloride ■ 

2-Thiophenecarbox aldehyde 

sym- Thymol 

*Toluene-2,4-diamine (4-m-Tolylenediamine) 

Toluene-2,4-disulfonic acid 

o-Toluenesulfonamide 

p-Toluenesulfonamide 

*o(and p)-Toluenesulfonic acid 

p-Toluenesulfonic acid 

Toluenesulfonic acid, aniline salt 

p-Toluenesulfonic acid, 2-chloroethyl ester 

p-Toluenesulfonic acid, ethyl ester 

p-Toluenesulfonic acid, methyl ester 

p-Toluenesulfonic acid monohydrate 

p-Toluenesulfono-o-toluidide 

p-Toluenesulfonyl chloride 

m-Toluic acid 

o-Toluic acid 

p-Toluic acid 

m-Toluidine 

o-Toluidine 

o-Toluidine hydrochloride 



UPJ. 

DUP. 

ACC, CSD, DOW, ELP, FG, KPP, MCB, MON, SHC, SKC, SNT, 

UCC. 
BKL. 

ACY, CTN. 
ACY, CTN, NAC. 
CMG, TRC. 
TRC. 



RSA. 
TRC. 



G, MON, UPF. 

CWN, UPJ. 

ACC, DUP, EKT, SOC. 

DUP. 

ACC, DUP, EKT, HPC. 

BJL. 

G, PCW. 

ARA, MON. 

BJL. 

DUP. 

EK. 

MCH. 

G, NAC. 

G. 

DUP, G, ICI, NAC. 

DOW, HK. 

SDH. 

DUP. 

G, ICI. 

DUP, OKO. 

DUP, QKO. 

G, ICC, NAC, TRC. 

ICI, NAC. 



ACY. 

G. 

DUP. 

EK. 

DUP. 

ARA. 

ABB. 

DUP, 

ACY, 

NAC. 

LIL. 

ABB. 

GIV. 

ACY, 

G. 



G, ICI. 
NAC. 



DUP, G, NAC, CMC, SDC, TRC, UCC. 



MON. 

MON. 

MON, 

ACY, 

NES. 

G. 

NAC. 

ICI. 

NES, 

G. 

MON. 

CWL. 

CWL. 

CWL, 

DUP, 

DUP, 

ACY. 



NAC, NES, SW, UPF. 
TEN. 



EK. 

NAC. 

NAC. 



SYNTHETIC ORGANIC CHEMICALS, 1965 

TABLE IB. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1 965 --Continued 



Manufacturers' identification codes 
(according to list in table 22) 



p-Toluidine 

p-Toluidine hydrochloride 

N-(p-Toluidine)methyl taurine 

Toluidines, mixed 

m-Toluidinomethanesulfonie acid 

8-p-Toluidino-l-naphthalenesulfonic acid 

o-(p-Toluoyl)benzoic acid 

N-(p-Tolylazo)sarcosine 

*4-(o-Tolylazo)-o-toluidine (C.I. Solvent Yellow 3) 

4-(o-Tolylazo)-o-toluidine hydrochloride 

1-p-Tolyldodecane 

2,2'-(m-Tolylimino)diethanol 

N, N, N-Tribenzylamine 

1, 2, 3( and 1, 2,4 )-Trichlorobenzene 

1, 2,4-Trichlorobenzene 

N, 2, 6-Trichloro-p-benzoquinoneimine 

1, 2,4-Trichloro-5-nitrobenzene 

Trichlorophenylsilane 

<x,a,a-Trichlorotoluene (Benzotrichloride) 

<x,2,4-Trichlorotoluene 

a,2,4(anda,2, 6)-Trichlorotoluene 

2,4, 6-Trichloro-s-triazine 

1,3,5-Triethylbenzene 

N, N, N'-Triethyl-N'-phenylethylenediamine 

2-(Trifluoromethyl)phenothiazine 

a,a,a_Trifluoro-4-nitro-m-cresol 

a , a , a -Trifluoro-m-nitrotoluene 

a , a , a -Trifluoro-N-phenyl-m-toluidine (3-(Trifluoromethyl) 
diphenylamine ) . 

<x,a,«-Trifluorotoluene 

a,a,a_Trifluoro-m-toluidine 

1, 2,4-Trihydroxyanthraquinone 

3,4, 5-Trimethoxybenzoic acid 

2,4, 5-Trimethylaniline (Pseudocumidine) 

1, 2,4-Trimethylbenzene (Pseudocumene) 

2,3,3-Trimethyl-3H-indole 

*l,3,3-Trimethyl-A 2 » a -indolineacetaldehyde 

*l,3,3-Trimethyl-2-methyleneindoline (Trimethyl base) 

Trimethylphenylammonium iodide 

«,«', 2-Trimethyl-l,4-piperazinediethanol 

2,4, 6-Trimethylpyridine 

1,3, 5-Trinitrobenzene 

2,4,7-Trinitrofluoren-9-one 

2,4, 6-Trinltroresoreinol, lead derivative 

Triphenylmethanol 

Triphenylsulfonium chloride 

a., a.', a." -Tris(dimethylamino)mesitol 

Tris(2-methyl-l-aziridinyl)phosphine oxide 

2,4,6-Tris(2-methyl-l-aziridinyl)-s-triazine 

Tropine 

m-Ureidoaniline 

*7, 7'-Ureylenebis[4-hydroxy-2-naphthalenesulfonic acid] 
(J acid urea). 

Veratraldehyde (3,4-Dimethoxybenzaldehyde) 

Veratryl alcohol (3,4-Dimethoxybenzyl alcohol) 

p-Vinylbenzenesulfonic acid, sodium salt 

2-Vinylcyclohexene 

4-Vinylcyclohexene 

2,2 -Vinylenebis[benzimidazole] 

5-Vinyl-2-picoline (MVP) 

2-Vinylpyridine 

4-Vinylpyridine 

*Violanthrone (Dibenzanthrone) 

Xanthene-9-carboxylic acid 

m-}iylene 

*o-Xylene 

*p-Xylene 

Xylenesulfonic acid 

2, 5-Xylenesulf onic acid 

2,4-Xylenol 

Xylenol crystals 



DUP, 


NAC. 




EK. 






BUC. 






DUP. 






TRC, 


VPC. 




NAC. 






ACY, 


NAC. 




G. 






ACY, 


ALL, 


DUP, G, KLS, NAC, SDH. 


G. 






X. 






EKT. 






MLS. 






PPG. 






DOW, 


HK, 


SVT. 


EK. 






PCW. 






DCC, 


UCS. 




HK, 


VEL. 




HN. 






BPC. 






ACY, 


GGY, 


NIL. 


DUP. 






DUP. 






SK. 






MEE. 






SK. 






HK. 






MEE. 






G. 






ICO, 


KF. 




NAC. 






ENJ. 






G. 






DUP, 


G, VPC. 


DUP, 


G, NAC, VPC. 


EK. 






WYN. 






KPT, 


RIL. 




EK. 






EK. 






REM. 






EK. 






GAM. 






RH, 


TKL. 




ICO. 






ICO. 






CTN. 






ICI. 






ACY, 


ATL, 


BKS, BL, CMG, G, NAC, TRC, VPC. 


GIV, 


LIL, 


SLV. 


LIL. 






DUP. 






UCC. 






PLC. 






TRC. 






PLC. 






RIL. 






RIL. 






ACY, 


ATL, 


DUP, G, ICI, MAY, TRC. 


PLC, 


SNT, 


SOC. 


ASH, 


CCP, 


COR, CSD, CSO, DLH, ENJ, SIN, SNT, SOC 


TOC. 




CSD, 


ENJ, 


SIN, SNT, SOC. 


NE3. 






EK. 






EK. 






ACP, 


KPT. 





CYCLIC INTERMEDIATES 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



#Jtylenols : 

Low b.p 

Medium b.p 

Not classified as to b.p 

)iylidines : 

2,4-)fylidine (m-4-Xylidine)- 

2, 5-Xylidine (p-Xylidine ) 

2, 6-Xylidine 

Original mixture 

4- (2, 4-J!ylylazo ) -o-toluidine— ■ 
4- (2, 5-)fylylazo )-o-toluidine-— 

4-(Xylylazo)xylidine 

4- ( 2, 4-Jiylylazo ) -2, 5-xylidine- 
All other cyclic intermediates' 



NPC, 


PIT, 


PRD. 


KPT, 


NPC, 


PIT. 


KPT, 


NPC, 


PRD. 


DUP, 


NAC. 




DUP, 


NAC. 




DUP. 






DUP, 


NAC. 




NAC. 






ACY. 







ARA, G, HPC, ICC, IDC, LIL, UPJ, VPC, x, x, x. 



1 Does not include manufacturers ' identification codes for producers that report to the Division of Bituminous 
Coal, U.S. Bureau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey Coke 
Producers in the United States in 1964, May 17, 1965. 



90 



SYNTHETIC ORGANIC CHEMICALS. 1965 



Dyes 

TABLE 8B. — Benzenoid dyes for which U.S. production or sales were reported, 
identified by manufacturer, 1965 



[Dyes for which separate statistics are given in table 8A are marked below with an asterisk (*); dyes not so marked 
do not appear in table 8A because the reported data are accepted in confidence and may not be published. Manufac- 
turers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not 
consent to his identification with the designated product] 



Dye 



Manufacturers ■ identification codes 
(according to list in table 22) 



ACID DYES 

*Acid yellow dyes: 

Acid Yellow 1 

Acid Yellow 2 

*Acid Yellow 3 

Acid Yellow 4 

Acid Yellow 7 

Acid Yellow 9 

*Acid Yellow 11 

Acid Yellow 14 

*Acid Yellow 17 

*Acid Yellow 23 

Acid Yellow 25 — 

Acid Yellow 29 

Acid Yellow 34 

Acid Yellow 35 

*Acid Yellow 36 

Acid Yellow 38 

*Acid Yellow 40 

*Acid Yellow 42 

Acid Yellow 43- 

*Acid Yellow 44 

*Acid Yellow 54 

Acid Yellow 59 

Acid Yellow 60 

Acid Yellow 63 

Acid Yellow 65 

*Acid Yellow 73 

Acid Yellow 76 

Acid Yellow 79 

Acid Yellow 90 

Acid Yellow 95 

*Acid Yellow 99 

Acid Yellow 113 

Acid Yellow 114— 

Acid Yellow 121 

Acid Yellow 124 

Acid Yellow 127— ■ 

Acid Yellow 128 ■ 

Acid Yellow 129 

Acid Yellow 151 

Acid Yellow 152 - ■ 

Acid Yellow 159 

Other acid yellow dyes 

*Acid orange dyes: 

*Acid Orange 1 

Acid Orange 2 

Acid Orange 5 

Acid Orange 6 

*Acid Orange 7 

*Acid Orange 8 

*Aeid Orange 10 

Acid Orange 12 

Acid Orange 19 

*Acid Orange 24 

Acid Orange 28 

Acid Orange 31 

Acid Orange 34 

Acid Orange 45 

Acid Orange 49 

Acid Orange 50 

Acid Orange 51 

Acid Orange 52 

Acid Orange 56 

*Acid Orange 60- 



ACY. 








DUP. 








ACY, 


DUP, 


NAC. 




SDH. 








NAC. 








ACY. 








CMG, 


DUP, 


VPC. 




BDO, 


TRC. 






ACY, 


ATL, 


BDO, BKS, CMG, DUP, G, 


NAC, PDC, SDH, TRC 


VPC. 






AAP, 


ACY, 


G, MRX, NAC, SDH, TRC, 


VPC. 


G. 








G, TRC. 






NAC. 








VPC. 








DUP, 


G, NAC, TRC. 




NAC. 








ACY, 


DUP, 


G, NAC, TRC, VPC. 




AAP, 


ACY, 


G, VPC. 




NAC. 








AAP, 


G, NAC, VPC. 




ACY, 


BKS, 


CMG, G, NAC, TRC, VPC. 




VPC. 








NAC. 








AAP, 


NAC. 






TRC. 








G, NAC, NYC, SDH. 




TRC. 








VPC. 








NAC. 








CMG. 








CMG, 


G, NAC, TRC, VPC. 




TRC. 








CMG, 


TRC. 






G. 








BKS, 


DUP, 


NAC. 




TRC. 








TRC. 








TRC. 








ACY, 


BKS. 






ACY. 








TRC. 








ACY, 


ALT, 


CMG, DUP, G, VPC. 




ALT, 


BKS, 


G, NAC. 




NAC. 








ACY. 








NAC. 








AAP, 


ACY, 


ATL, BKS, CPC, G, NAC, 


PDC, TRC, YAW. 


ACY, 


ATL, 


BKS, DUP, G, NAC, TRC. 




ACY, 


ATL, 


DUP, G, NAC, TRC, YAW. 




NAC. 








G. 








ACY, 


DUP, 


G, NAC, TRC, YAW. 




NAC. 








AAP. 








ACY. 








NAC, 


TRC. 






TRC. 








AAP. 








CMG, 


NAC, 


TRC. 




NAC. 








G. 








BKS, 


CMG, 


DUP, G. 





DYES 



TABLE 8B. — Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



ACID DYES- -Continued 

*Acid orange dyes — Continued 

Acid Orange 62 

Acid Orange 63 

*Acid Orange 64 

Acid Orange 69 

Acid Orange 72 

Acid Orange 74 

Acid Orange 76 

Acid Orange 85 

Acid Orange 86 

Acid Orange 114 

Acid Orange 116 

Acid Orange 119 

Other acid orange dyes 

*Aeid red dyes: 

*Aeid Red 1 

*Acid Red 4 

Acid Red 12 

*Acid Red 14 

Acid Red 17 

*Acid Red 18 

*Aeid Red 26 

Acid Red 27 

Acid Red 29 

Acid Red 32 

Acid Red 33 

Acid Red 34 

Acid Red 35 

*Acid Red 37 

Acid Red 42 

Acid Red 52 

Acid Red 57 

Acid Red 60 

Acid Red 66 

*Acid Red 73 

Acid Red 76 

Acid Red 80 

*Acid Red 85 

*Acid Red 87 

*Acid Red 88 

*Acid Red 89 

Acid Red 94 

Acid Red 97 

*Acid Red 99 

Acid Red 100 

Acid Red 106 — 

Acid Red 113 

*Acid Red 114 

*Acid Red 115 

Acid Red 119 

Acid Red 133— — 

Acid Red 134 

*Acid Red 137 

*Acid Red 151 

Acid Red 153 

Acid Red 167 

Acid Red 172 

Acid Red 175 

Acid Red 178 

Acid Red 179 

*Acid Red 182 

Acid Red 183 

Acid Red 184 

*Acid Red 186 

Acid Red 190 

Acid Red 191 

Acid Red 194 

Acid Red 207 



TRC. 

G, TRC. 

ACY, DUP, NAC. 

ACY. 

a. 

CMG, G, NAC, TRC. 

NAC, TRC. 

NAC. 

NAC, TRC. 

ACY. 

ATL, TRC. 

TRC. 

ALT, G, VPC. 

AAP, ACY, BDO, BKS, BL, DUP, G, NAC, SDH, TRC, VPC, 

YAW. 
ATL, BDO, CMG, DUP, G, TRC, VPC, YAW. 
G, NAC. 

ATL, BDO, DUP, G, NAC, PDC. 
ATL, NAC, TRC. 
ACY, ATL, BDO, G, NAC, TRC. 
ACY, ATL, CPC, G, NAC. 
NAC. 
NAC. 
G, NAC. 
NAC, YAW. 
NAC. 
AAP, G. 

CMG, DUP, G, NAC, TRC. 
G. 
G. 

TRC. 
TRC. 

AAP, NAC. 

ACY, DUP, G, NAC, PSC, TRC. 
NAC. 
G, ICI. 
ACY, ALT, ATL, BKS, CMG, DUP, G, NAC, PDC, TRC, VPC, 

YAW. 
AMS, NYC, SDH. 

ACY, ATL, DUP, G, NAC, SDH, TRC, YAW. 
AAP, G, TRC, VPC. 
NYC. 
ATL, G. 

BKS, CMG, NAC, TRC, VPC. 
VPC. 
YAW. 
DUP. 

ATL, DUP, G. 
G, NAC, TRC. 
NAC. 
G. 

TRC. 

ATL, DUP, G, NAC, TRC. 
AAP, ACY, BKS, TRC, YAW. 
YAW. 

NAC, TRC. 
VPC. 
DUP. 
DUP. 

CMG, TRC. 

ACY, BKS, CMG, DUP, G, NAC. 
CMG, TRC. 
TRC. 

ACY, BKS, CMG, DUP, G, TRC, VPC. 
ACY. 
TRC. 
TRC. 
NAC. 



92 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 8B. — Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



ACID DYES— Continued 

*Acid red dyes — Continued 

Acid Red 212 

Acid Red 213 

Acid Red 218— 

Acid Red 273 

Acid Red 292 

Acid Red 299 — 

Acid Red 309 

Other acid red dyes 

*Acid violet dyes: 

*Aeid Violet 1 

*Acid Violet 3 

Acid Violet 6 

*Acid Violet 7 

Acid Violet 11 

*Acid Violet 12 

Acid Violet 13 — 

Acid Violet 17 - 

Acid Violet 29 

Acid Violet 34 

Acid Violet 41 

Acid Violet 43 

*Acid Violet 49 

Acid Violet 56 

Acid Violet 76 

Acid Violet 78 

Other acid violet dyes 

*Acid blue dyes: 

Acid Blue 1 

*Acid Blue 7 

*Aeid Blue 9 

Acid Blue 10 

Acid Blue 13 

Acid Blue 15 

Acid Blue 20 

Acid Blue 22 

Acid Blue 23 

*Acid Blue 25 

Acid Blue 26 

Acid Blue 27 

Acid Blue 29 

Acid Blue 34 

Acid Blue 35 

*Acid Blue 40 

*Acid Blue 41 

*Acid Blue 43 

*Acid Blue 45 

Acid Blue 47 

Acid Blue 48 

Acid Blue 58 

Acid Blue 59 

*Acid Blue 62 

Acid Blue 63 

Acid Blue 67 

Acid Blue 69 

Acid Blue 74 

*Acid Blue 78 

Acid Blud 80 

Acid Blue 81 

Acid Blue 83 

Acid Blue 89— - — 

*Acid Blue 90 

Acid Blue 92 

Acid Blue 93 

Acid Blue 102 

Acid Blue 104 

*Acid Blue 113 

*Acid Blue 118 

Acid Blue 120 - 



TRC. 

ALT, ATL, G, TRC, VPC. 

G, NAC. 

DUP, NAC, TRC, YAW. 

BD0, CMG, DUP, G, NAC, TRC, VPC. 

DUP, G. 

G, SDH. 



ICI, NAC. 
NAC, TRC. 
G. 



DUP, TRC. 

NAC, SDH. 

G, NAC, SDH. 
NAC, SDH, VPC. 

NAC. 



NAC. 
NYC. 
TRC. 
BD0, CMG, DUP, G, NAC, TRC. 



G, ICI, NAC. 
CMG, G, NAC. 
G, NAC, TRC. 
CMG, DUP, G, NAC, TRC, VPC. 



G, VPC. 

NAC. 

NAC. 

G. 

NAC. 

G, ICI, NAC, TRC. 

TRC. 



NAC. 

G, NAC, TRC. 

NAC, 

HSC 
NAC 



TRC. 
NAC. 

BKS, CMG, DUP, G. 

G, NAC. 
NAC. 



DYES 



93 



TABLE 8B. --Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Dye 



ACID DYES— Continued 

*Acid blue dyes — Continued 

Acid Blue 122— -. 

Acid Blue 137- - 

Acid Blue 145 

*Acid Blue 158 and 158A 

Acid Blue 165 

Acid Blue 179 

Acid Blue 203 

Acid Blue 230 - 

Acid Blue 231 

Other acid blue dyes 

*Acid green dyes: 

Acid Green 1 

*Acid Green 3 

Acid Green 5 

*Aeid Green 9 

*Aci'l Green 12 

*Acid Green 16 

*Acid Green 20 

Acid Green 22 

*Acid Green 25 

Acid Green 35 

Acid Green 4-1 

Acid Green 44 

Acid Green 50 

Acid Green 58 

Other acid green dyes 

*Acid brown dyes: 

Acid Brown 1 

Acid Brown 6 

*Acid Brown 14 

Acid Blown 19 

Acid Brown 22 

Acid Brown 28 

Acid Brown 29 

Acid Brown 31 

Acid Brown 45 

Acid Brown 96 

Acid Brown 97 

Acid Brown 98 

Acid Brown 152 

Acid Brown 158 

Acid Brown 223 

Acid Brown 243 

Other acid brown dyes 

*Acid black dyes: 

*Acid Black 1 

Acid Black 2 

Acid Black 12 

Acid Black 16 

Acid Black 18 

*Acid Black 24 

Acid Black 26, 26A, and 26B 

Acid Black 29 

Acid Black 41 

*Acid Black 48 

Acid Black 52 

Acid Black 53 

Acid Black 58 

Acid Black 60 

Acid Black 92 

*Acid Black 107 

Acid Black 138 — *• 

Other acid black dyes 



Manufacturers' identification codes 
(according to list in table 22) 



DUP. 






NAC. 






DUP. 






ACY, BKS, 


G, NAC, 


TRC, VPC. 


DUP. 






G. 






VPC. 






DUP, THC. 






TRC. 






ACY, ALT, 


CMG, DUP, TRC, VPC. 


ACY, NAC. 






ACY, DUP, 


G, NAC, 


TRC. 


G, NAC. 






ACY, DUP, 


G, NAC, 


VPC. 


G, NAC, TRC. 




DUP, G, NAC, SDH, 


TRC. 


ATL, CMG, 


DUP, G, 


NAC, TRC. 


G, NAC. 






ATL, CMG, 


G, HSH, 


ICI, NAC, TRC, VPC 


THC. 






ICI, VPC. 






VPC. 






ACY, G. 






TRC. 






ALT, TRC, 


VPC. 




G. 






G. 






AAP, ACY, 


DUP, G, 


NAC, TRC, YAW. 


TRC. 






DUP. 






TRC. 






DUP, NAC. 






G. 






NAC, TRC. 






ACY. 






ACY. 






ACY, TRC. 






G. 






G. 






G. 






G. 






ALT, DUP, 


G, VPC. 





AAP, ACY, ATL, BDO, BKS, DUP, FAB, G, NAC, PDC, TRC 
YAW. ' 

ACY, NAC. 
NAC. 
NAC. 
NAC. 

CMG, DUP, G, NAC. 
DUP, NAC, TRC. 
G, NAC. 
NAC. 

ACY, CMG, DUP, G, ICI, NAC, TRC. 
G, NAC, TRC. 
NAC. 

NAC, TRC. 
CMG, TRC. 
ACY. 

G, NAC, TRC. 
VPC. 
ALT, DUP, PDC. 



94 



SYNTHETIC ORGANIC CHEMICALS, 1965 



-Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



AZOIC DYES AND COMPONENTS 



Azoic yellow dyes: 
*Azoic Yellow 1 

Azoic Yellow 2 

*Azoic Yellow 3 

Other azoic yellow dyes 

Azoic orange dyes: 

*Azoic Orange 3 

Azoic Orange 4 

Other azoic orange dyes 

* Azoic red dyes: 

*Azoic Red 1 

*Azoie Eed 2 

*Azoic Bed 6 

Azoic Red 13 

Azoic Red 14 

Azoic Red 15 

•*Azoic Red 16 

Azoic Red 73 

Azoic Red 74 

Other azoic red dyes 

Azoic violet dyes: 

Azoic Violet 1 

Other azoic violet dyes 

Azoic blue dyes: 

*Azoic Blue 2 

*Azoic Blue 3 

Azoic Blue 4 

Azoic Blue 6 

Azoic Blue 7 

Other azoic blue dyes 

Azoic green dyes: 

Azoic Green 1 

Other azoic green dyes 

Azoic brown dyes: 

*Azoic Brown 9 

Azoic Brown 10 

Azoic Brown 26 

Other azoic brown dyes 

* Azoic black dyes: 

Azoic Black 1 

Azoic Black 2 

Azoic Black 3 

Azoic Black 4 

Azoic Black 15 

Other azoic black dyes 

Other azoic compositions 

Azoic Diazo Compo 
(Fast Color 



Azoic 

Azoic 

Azoic 

♦Azoic 

Azoic 

Azoic 

*Azoic 

*Azoic 

*Azoic 

*Azoic 

Azoic 

Azoic 

Azoic 

Azoic 

*Azoic 

Azoic 

Azoic 

Azoic 



Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 



Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 



1, base — 

2, base — 

3, base — 

4, base — 

5, base — 

8, base — 

9, base — 

10, base- 

12, base- 

13, base- 

14, base- 
20, base- 
24, base- 
28, base- 
32, base- 
34, base- 
41, base- 
46, base- 



ALL, ATL, BUC, G. 

BUC, G, HST, X. 

ATL, G, HST. 
BUC. 

ALL, ATL, BUC, G, x. 



VPC. 

ALL, 

ATL, 
ALL, 
G. 



ATL, BUC, G, HST, x. 

BUC, G, x. 

ATL, BUC, G, HST, NAC, VPC, x. 



ATL, BUC, G. 



ATL, BUC, G. 
ATL, G, x. 



ATL, BUC, G. 

ALL, ATL, BUC, G, HST, x. 



ATL, G. 
G. 



ATL, G. 






VPC. 






ATL, BUC, 


Qt 


HST, VPC 


ATL, BUC. 






BUC, G. 






ATL, BUC, 


G> 


VPC. 


G, HST. 






ATL. 






ATL. 






ALL, ATL, 


G. 




G, NAC. 






ALL, ATL, 


Gj 


VPC. 



SDH. 
ATL. 
KLS. 

ALL, G, KLS, SDH. 
G, SDH. 
DUP. 

AAP, DUP, VPC. 
ALL, AUG, BUC, G, KLS. 
AUG, KLS, SDH. 
ALL, AUG, BUC, KLS. 
AAP. 
ALL, G. 
KLS. 

ALL, BUC, KLS. 

AAP, ATL, BUC, DUP, KLS, SDH. 
G. 
G. 
I ATL. 



DYES 



95 



TABLE 8B. —Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1 965- -Continued 



Dye 



AZOIC DYES AND COMPONENTS- -Continued 



Azoic Diazo Components, Bases 
(Fast Color Bases)— Continued 



*Azoic Diazo Component 48, base- 
Azoic Diazo Component 49, base- 



Diazo Components 
(Fast Color Salt 



*Azoic 

* Azoic 

*Azoic 

Azoic 

*Azoic 

*Azoic 

*Azoic 

*Azoic 

*Azoic 

*Azoic 

*Azoie 

*Azoic 

Azoic 

Azoic 

Azoic 

*Azoic 

Azoic 

Azoic 

Azoic 

Azoic 

Azoic 

Azoic 

Azoic 

Azoic 

*Azoic 

*Azoic 

Azoic 

Other 



Azoic 

*Azoic 

*Azoic 

*Azoic 

*Azoie 

*Azoic 

* Azoic 

Azoic 

*Azoic 

Azoic 

Azoic 

*Azoic 

Azoic 

Azoic 

*Azoic 

*Azoic 

*Azoic 

*Azolc 

*Azoic 

Azoic 

Azoic 

*Azoic 

Azoic 

Azoic 

Azoic 

Azoic 

Other 



Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
azoic 



Component 1, salt 

Component 2, salt 

Component 3, salt 

Component 4, salt 

Component 5, salt 

Component 6, salt 

Component 8, salt 

Component 9, salt 

Component 10, salt 

Component 11, salt 

Component 12, salt 

Component 13, salt 

Component 14, salt 

Component 20, salt 

Component 24, salt 

Component 28, salt 

Component 32, salt 

Component 34, salt 

Component 35, salt 

Component 36, salt 

Component 37, salt 

Component 41, salt 

Component 42, salt 

Component 44, salt 

Component 48, salt 

Component 49, salt 

Component 51, salt 

diazo components, salts- 



Azoic Coupling Components 
(Naphthol AS and Derivatives) 

Coupling Component 1 

Coupling Component 2 

Coupling Component 3 

Coupling Component 4 

Coupling Component 5 

Coupling Component 7 

Coupling Component 8 

Coupling Component 10 

Coupling Component 11 

Coupling Component 12 

Coupling Component 13 

Coupling Component 14 

Coupling Component 15 

Coupling Component 16 

Coupling Component 17 

Coupling Component 18 

Coupling Component 19 

Coupling Component 20 

Coupling Component 21 

Coupling Component 23 

Coupling Component 24 

Coupling Component 29 

Coupling Component 34 

Coupling Component 35 

Coupling Component 36 

Coupling Component 43 

azoic coupling components 



Manufacturers' identification codes 
(according to list in table 22) 



ALL, OWN, DUP, G. 
KLS. 



AAP, ALL, G, SDH. 

AUG, BUC, G, KLS. 

AAP, ALL, AUG, BUC, G, KLS, SDH, VPC. 

ALL. 

AAP, ALL, AUG, BUC, G, KLS, SDH, VPC. 

AAP, BUC, G, KLS, SDH. 

AAP, ALL, AUG, BUC, G, KLS. 

AAP, ALL, AUG, BUC, G, KLS, SDH, VPC. 

AAP, ALL, BUC, G, KLS, SDH. 

AAP, ALL, G, KLS. 

AAP, ALL, BUC, G, KLS, SDH. 

AAP, ALL, AUG, BUC, G, KLS, SDH, VPC. 

AAP. 

ALL, G. 

BUC. 

ALL, AUG, BUC, G, KLS, SDH, VPC. 

ALL, BUC, SDH. 

G. 

G. 

AAP, G. 

G. 

G. 

ALL, G, KLS. 

G, SDH. 

AAP, ALL, G, NAC, SDH. 

AAP, BUC, G, KLS. 

BUC. 



AUG. 

AAP, ACY, ATL, BUC, DUP, G, PCW. 

AUG, BUC, G, PCW. 

ATL, AUG, BUC, G, PCW. 

AAP, G, PCW, SDH. 

AAP, AUG, BUC, G, PCW. 

ATL, G, PCW. 

PCW, SDH. 

BUC, G, PCW. 

BUC, G, PCW. 

G. 

ATL, BUC, G, NAC, PCW. 



ACY, ATL, BUC, PCW. 

ACY, ATL, BUC, DUP, G, PCW. 

BUC, G, PCW. 

ATL, BUC, DUP, G, PCW. 

ATL, AUG, BUC, G, PCW. 

G, PCW. 

G, PCW. 

ATL, AUG, BUC, G, PCW. 

BUC, G, PCW. 

ALL, G, PCW. 

G. 

ATL, G. 

ATL, G, VPC. 



96 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 8B. — Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Dye 



Manufacturers 1 identification codes 
(according to list in table 22) 



BASIC DYES 

*Basic yellow dyes: 

Basic Yellow 1 

*Basic Yellow 2 

Basic Yellow 5 

*Basic Yellow 11 

*Basic Yellow 13 

Basic Yellow 15 

Basic Yellow 16 

Basic Yellow 26 

Basic Yellow 27 

Basic Yellow 28 

Basic Yellow 37 

Other Basic yellow dyes 

*Basic orange dyes: 

*Basic Orange 1 

*Basic Orange 2 

Basic Orange 10 

Basic Orange 14 

Basic Orange 17 

*Basic Orange 21 

Basic Orange 22 

Basic Orange 24 

Basic Orange 25 

Basic Orange 26 

Basic Orange 31 

Other basic orange dyes 

*Basic red dyes: 

Basic Red 1 

Basic Red 2 

Basic Red 9 

Basic Red 12 

Basic Red 13 

*Basie Red 14 

Basic Red 15 

Basic Red 16 

Basic Red 17 

Basic Red 18 

Basic Red 19 

Basic Red 20 

Basic Red 22 

Basic Red 30 

Other basic red dyes 

*Basic violet dyes: 

*Basic Violet 1 

Basic Violet 2 

*Basic Violet 3 

*Basie Violet 4 

Basic Violet 7 

Basic Violet 10 

Basic Violet 13 

Basic Violet 14 

Basic Violet 15 

*Basic Violet 16 

Basic Violet 18 

Other basic violet dyes 

*Basic blue dyes: 

*Basic Blue 1 

Basic Blue 2 

Basic Blue 3 

Basic Blue 4 

*Basic Blue 5 

Basic Blue 6 

*Basie Blue 7 

*Basic Blue 9 

Basic Blue 11 

Basic Blue 21 

Basic Blue 22 

*Basic Blue 26 

Basic Blue 27 



DUP. 

ACY, DUP, NAC. 

NAC. 

DUP, G, NAC, VPC. 

DUP, G, NAC, VPC. 

DUP. 

DUP. 

ACY. 

ACY. 

VPC. 

ACY. 

G, DUP. 

ACY, DUP, G, NAC. 

ACY, DSC, DUP, G, NAC, PDC, PSC, TRC. 

VPC. 

G. 

NAC. 

DUP, G, NAC, VPC. 

G, NAC. 

DUP. 

DUP. 

DUP. 

ACY. 

VPC. 



DUP, 


G. 






DUP, 


NAC. 






DSC, 


HSC. 






DUP. 








G, NAC. 






ACY, 


DUP, 


G, 


NAC, VPC. 


DUP, 


G. 






DUP. 








DUP. 








DUP, 


VPC. 






DUP. 








DUP. 








ACY, 


TRC. 






ACY. 








DUP. 








ACY, 


DSC, 


HSC, NAC. 


DSC, 


NYC. 






DSC, 


DUP, 


G, 


NAC, SDH. 


DSC, 


DUP, 


G, 


NAC. 


G, NAC. 






ACY, 


DUP, 


G. 




DSC. 








ACY, 


DSC. 






DUP. 








DUP, 


G, VPC. 




ACY. 








DUP. 








DSC, 


G, NAC, 


SDH, VPC. 


DSC. 








G. 








DUP. 








DSC, 


SDH, 


VPC. 


ACY, 


NAC. 






DSC, 


DUP, 


Gi 


SDH. 


ACY, 


G, NAC, 


SDH. 


DSC, 


DUP, 


SDH. 


DUP. 








DUP, 


NAC. 






DSC, 


DUP, 


G, 


SDH. 


G. 









DYES 



97 



TABLE 8B —Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



Dye 



BASIC DYES- -Continued 

♦Basic blue dyes—Continued 

Basic Blue 35 

Basic Blue 36 

Basic Blue 38 

Basic Blue 39 

Basic Blue 4-1 

Basic Blue 54 

Other basic blue dyes 

Basic green dyes: 

♦Basic Green 1 

Basic Green 3 

♦Basic Green 4 

Basic Green 5 

Basic brown dyes: 

♦Basic Brown 1 — • 

Basic Brown 2 

*Basic Brown 4 

Basic black dyes: 

Basic Black 3 

Other basic black dyes 

DIRECT DYES 

♦Direct yellow dyes: 

*Direct Yellow 4 

*Direct Yellow 5 

*Direct Yellow 6 

Direct Yellow 7 

Direct Yellow 8 

Direct Yellow 9 

*Direct Yellow 11 

*Direet Yellow 12 

Direct Yellow 20 

Direct Yellow 23 

♦Direct Yellow 26 

Direct Yellow 27 

*Direct Yellow 28 

Direct Yellow 29 

Direct Yellow 39 

*Direct Yellow 44 

*Direct Yellow 50 

♦Direct Yellow 59 

Direct Yellow 62 

Direct Yellow 63 

♦Direct Yellow 84 

Direct Yellow 103 

♦Direct Yellow 105 

♦Direct Yellow 106 

Direct Yellow 107 

Direct Yellow 114 

Direct Yellow 117 

Direct Yellow 118 

Direct Yellow 121 

Direct Yellow 125 

Other direct yellow dyes 

♦Direct orange dyes: 

♦Direct Orange 1 

Direct Orange 6 

♦Direct Orange 8 

Direct Orange 10 

Direct Orange 11 

♦Direct Orange 15 

♦Direct Orange 26 

Direct Orange 29 

♦Direct Orange 34 

♦Direct Orange 37 

Direct Orange 38 

♦Direct Orange 39 

Direct Orange 40 



Manufacturers' identification codes 
(according to list in table 22) 



DUP. 




DUP. 




ACY, DUP. 




DUP. 




TRC. 




ACY. 




ACY, DUP, 


G. 


ACY, DSC, 


DUP, NAC, SDH. 


DUP. 




ACY, DSC, 


DUP, NAC, SDH. 


ACY. 




ACY, DUP, 


G, NAC, TRC. 


G, NAC. 




ACY, DSC, 


DUP, G, NAC, TRC 



DSC, DUP. 



ACY, DUP, G, NAC, TRC. 

ACY, G, NAC. 

ACY, DUP, G, NAC, TRC. 

ATL. 

G, NAC. 

DUP. 

ACY, DUP, G, NAC, TRC. 

BKS, DUP, G, NAC, TRC. 

TRC. 

DUP. 

BKS, BL, DUP. 

G. 

ATL, DUP, G, NAC, TRC. 

DUP, G. 

TRC. 

ALT, ATL, BKS, BL, DUP, G, NAC, TRC, VPC. 

ATL, BKS, BL, DUP, FAB, G, NAC, TRC, VPC. 

ATL, DUP, NAC. 

NAC. 

DUP. 

BKS, G, NAC, TRC. 

NAC. 

ALT, BKS, TRC. 

ALT, BKS, G, TRC. 

G. 

ACY. 

TRC. 

ACY, TRC. 

TRC. 

ACY. 

AAP, ALT, ATL, BL, DUP, FAB, VPC. 

AAP, BDO, CMG, NAC, VPC. 

NAC. 

ATL, DUP, G, NAC, TRC. 

AAP, NAC. 

G. 

ACY, DUP, G, NAC, TRC. 

ATL, BL, DUP, G, NAC, TRC. 

ATL, BKS, TRC. 

ACY, CMG, DUP, G, NAC. 

ACY, CMG, DUP, G, TRC. 

NAC. 

ATL, BKS, CMG, DUP, G. 

DUP. 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 8B. ■ 



-Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



Dye 



DIRECT DYES--Continued 

*Direct orange dyes — Continued 

Direct Orange 48 

Direct Orange 55 

Direct Orange 59 

Direct Orange 61 

Direct Orange 67 

Direct Orange 70 

^Direct Orange 72 

*Direct Orange 73 

Direct Orange 74 

Direct Orange 76 

Direct Orange 78 

Direct Orange 79 

Direct Orange 80 

*Direct Orange 81 

Direct Orange 83 

Direct Orange 88 

*Direct Orange 102 

Direct Orange 110 

Other direct orange dyes 

*Direct red dyes: 

*Direct Red 1 

-"-Direct Red 2 

*Direct Red 4 

Direct Red 5 

*Direct Red 10 

*Direct Red 13 

*Direet Red 16 

Direct Red 20 

*Direct Red 23 

^Direct Red 24 

*Direct Red 26 

*Direct Red 28 

Direct Red 30 

*Direct Red 31 

Direct Red 32 

*Direct Red 37 

*Direct Red 39 

Direct Red 46 

Direct Red 53 

Direct Red 62 

Direct Red 72 

Direct Red 73 — 

*Direet Red 75 

Direct Red 76 

*Direct Red 79 

*Direct Red 80 

*Direct Red 81 

*Direet Red 83 

Direct Red 84 

Direct Red 94 

Direct Red 95 

Direct Red 100 

Direct Red 111 

Direct Red 117 

Direct Red 120 

^Direct Red 122 

Direct Red 123 — 

*Direct Red 127 and 127A 

Direct Red 139 

Direct Red 148 

*Direct Red 149 

Direct Red 152 

*Direct Red 153 

Direct Red 155 

Direct Red 209 

Other direct red dyes 



Manufacturers' identification codes 
(according to list in table 22) 



DUP. 

DUP, NAC. 

DUP, G. 

TRC. 

NAC, VPC. 

TRC. 

ATL, BKS, BL, FAB, NAC, TRC, VPC. 

DUP, G, TRC, VPC. 

DUP. 

DUP. 

DUP, VPC. 

DUP. 

DUP, VPC. 

DUP, G, NAC, VPC. 

G, NAC. 

DUP. 

ACT, DUP, G, NAC. 

TRC. 

ALT, ATL, BL, DUP, G, VPC. 

AAP, ATL, DUP, G, NAC, TRC, IAW. 

ATL, BKS, DUP, NAC, TRC. 

NAC, TRC, VPC. 

NAC. 

AAP, ACY, ATL, NAC. 

AAP, ATL, DUP, G, NAC, TRC, YAW. 

AAP, ATL, DUP, G, NAC, TRC. 

G, NAC. 

ATL, BKS, DUP, FAB, G, NAC, TRC. 

AAP, ATL, BKS, BL, FAB, NAC, TRC, VPC. 

AAP, ATL, BKS, DUP, G, NAC, TRC, VPC. 

ATL, DUP, NAC, TRC. 

VPC. 

ATL, DUP, G, NAC, TRC. 

DUP, NAC. 

ACY, ATL, G, NAC, TRC, YAW. 

ATL, G, NAC, TRC, YAW. 

ATL, TRC. 

NAC. 

TRC. 

G, TRC. 

DUP, NAC. 

ACY, CMG, DUP, G, NAC, VPC. 

G, NAC. 

ATL, BKS, CMG, TRC, VPC. 

AAP, ATL, BDO, BKS, BL, CMG, DUP, FAB, G, NAC, TRC, 

VPC. 
AAP, ACY, ATL, BDO, BKS, BL, CMG, DUP, G, NAC, TRC, 

VPC, YAW. 
ALT, ATL, BKS, BL, CMG, DUP, FAB, G, NAC, TRC. 
G, NAC. 
NAC. 
VPC. 
NAC. 
G, VPC. 
BL, DUP. 
VPC. 
CMG, NAC, TRC, VPC. 



DUP, 


NAC, 


TRC. 




VPC. 








DUP. 








ATL, 


CMG, 


DUP, G, 


NAC 


CMG, 


DUP, 


NAC. 




ATL, 


CMG, 


NAC. 




G. 








TRC. 








ALT, 


BL. 







DYES 



99 



TABLE 8B. —Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Dye 



DIRECT DYES- -Continued 

*Direct violet dyes: 

♦Direct Violet 1 

Direct Violet 7 

♦Direct Violet 9 

Direct Violet 14 

Direct Violet 22 

Direct Violet 30 

Direct Violet 47 

Direct Violet 48 

Direct Violet 49 

♦Direct Violet 51 

Direct Violet 60 

Direct Violet 62 

Direct Violet 66 

Direct Violet 67 

Direct Violet 68 — 

Other direct violet dyes 

*Direct blue dyes: 

*Direct Blue 1 

*Direct Blue 2 

Direct Blue 3 

♦Direct Blue 6 

♦Direct Blue 8 

Direct Blue 10 

*Direct Blue 14- 

♦Direct Blue 15 

Direct Blue 21 - 

♦Direct Blue 22 

♦Direct Blue 24 

♦Direct Blue 25 

Direct Blue 26 

Direct Blue 27 

Direct Blue 55 

Direct Blue 67 

♦Direct Blue 71 

Direct Blue 74 

Direct Blue 75 

♦Direct Blue 76 

♦Direct Blue 78 

Direct Blue 79 

♦Direct Blue 80 

Direct Blue 84 

♦Direct Blue 86 

Direct Blue 87 

Direct Blue 91 

♦Direct Blue 98— 

Direct Blue 100 

Direct Blue 104 

♦Direct Blue 120 and 120A 

♦Direct Blue 126 

Direct Blue 130 

Direct Blue 133 

Direct Blue 136 

Direct Blue 1A3 

♦Direct Blue 151 

Direct Blue 160 

Direct Blue 189 

Direct Blue 191 

Direct Blue 199 

Direct Blue 218 

Direct Blue 238 

Other direct blue dyes 

♦Direct green dyes: 

♦Direct Green 1 

♦Direct Green 6 

♦Direct Green 8 

♦Direct Green 12 — ■ 



Manufacturers' identification codes 
(according to list in table 22) 



AAP, ATL, DUP, NAC. 

G, NAC. 

ATL, BKS, DUP, G, NAC, TRC. 

ATL, NAC. 

DUP. 

AAP. 

DUP, G. 

DUP, NAC. 

NAC. 

ATL, DUP, NAC. 

NAC. 

ACY. 

ATL, TRC. 

DUP, NAC. 

DUP. 

ALT. 

AAP, ACY, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, VPC, 

YAW. 
AAP, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, VPC, YAW. 
NAC. 

AAP, ACY, ATL, BKS, BL, DUP, G, NAC, TRC, YAW. 
ATL, BKS, DUP, G, NAC, TRC, YAW. 
DUP. 

ATL, DUP, NAC, TRC. 
ATL, DUP, G, NAC, YAW. 
TRC. 

ATL, CMG, DUP, NAC. 
ATL, BKS, NAC, TRC, YAW. 
DUP, G, NAC, TRC, YAW. 
ATL, NAC. 
DUP. 
NAC. 

ATL, DUP, NAC, TRC. 
ATL, DUP, G, NAC, TRC. 
DUP. 

TRC. 

ALT, ATL, BKS, BL, DUP, G, NAC, TRC, VPC. 

ATL, CMG, DUP, G, NAC, TRC. 

TRC. 

ALT, ATL, BKS, BL, DUP, FAB, G, NAC, TRC. 

DUP. 

AAP, ACY, ATL, BKS, DUP, FAB, G, ICC, ICI, NAC, SDH, 
TMS, TRC, VPC. 

ICI. 

TRC. 

ALT, ATL, G, TRC, VPC. 

ALT, NAC. 

DUP. 

ATL, BKS, CMG, DUP, G, NAC, TRC. 

BL, DUP, G, NAC, TRC, VPC. 

NAC. 

G. 

G. 

DUP. 

ATL, NAC, TRC. 

TRC. 

TRC. 

G. 

G. 

BKS. 

ACY. 

AAP, ACY, ALT, ATL, BL, DUP, FAB, G, NAC, VPC, YAW. 

AAP, ACY, ATL, BKS, DUP, G, NAC, TRC, YAW. 

AAP, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, YAW. 

ATL, NAC, TRC. 

DUP, NAC, TRC. 



100 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 8B. —Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1 965— Continued 



Dye 



DIRECT DYES— Continued 



*Direet green dyes — Continued 

Direct Green 14 

Direct Green 15 

Direct Green 26 

Direct Green 27 

Direct Green 28 

^Direct Green 38 

Direct Green 39 

Direct Green 41 

Direct Green 45 

Direct Green 47 

Direct Green 51 

Direct Green 69 

Other direct green dyes 

*Direct brown dyes: 

^Direct Brown 1 

*Direet Brown 1A 

*Direct Brown 2 

*Direct Brown 6 

Direct Brown 11 

Direct Brown 25 

Direct Brown 27 

Direct Brown 29 

*Direct Brown 31 

Direct Brown 32 

Direct Brown 33 

Direct Brown 35 

Direct Brown 40 

Direct Brown 44- 

Direct Brown 48 

Direct Brown 59 

*Direct Brown 74 

*Direet Brown 95 

Direct Brown 101 

Direct Brown 105 

Direct Brown 106 

*Direct Brown 111 

Direct Brown 112 

Direct Brown 125 

*Direct Brown 154 

Other direct brown dyes 

*Direct black dyes: 

Direct Black 3 

*Direct Black 4 

Direct Black 8 

^Direct Black 9 

Direct Black 17 

*Direct Black 19 

*Direct Black 22 

Direct Black 29 

Direct Black 36 

Direct Black 37 

*Direct Black 38 

Direct Black 44 

*Direct Black 51 

Direct Black 55 

Direct Black 56 

Direct Black 67 

Direct Black 71 

Direct Black 74 

Direct Black 75 

Direct Black 78 

*Direct Black 80 

Direct Black 109 

Direct Black 123 

Direct Black 130 

Direct Black 190 

Other direct black dyes 



Manufacturers' identification codes 
(according to list in table 22) 



MAC. 

DUP. 

TRC. 

NAC, TRC. 

TRC. 

DUP, G, NAC. 

G. 

DUP. 

VPC. 

DUP, G. 

TRC. 

TRC. 

ACY, ALT, ATL, BL, DUP. 

ACY, ATL, BKS, BL, DUP, FAB, NAC. 

G, TRC, YAW. 

AAP, ACY, ATL, BKS, BL, DUP, G, NAC, TRC, YAW. 

DUP, G, NAC, TRC. 

NAC. 

DUP, NAC. 

G. 

NAC. 

AAP, ATL, DUP, G, NAC, YAW. 

G. 

DUP, NAC. 

NAC. 
AAP, DUP. 

G, YAW. 

AAP. 

ACY. 

AAP, DUP, NAC. 

AAP, ALT, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, YAW. 

G. 

DUP. 

G, NAC. 

DUP, G, TRC, VPC. 

ATL, NAC. 

G. 

DUP, G, NAC, TRC, YAW. 

ALT, ATL, BL, NAC, TRC, VPC, YAW. 

DUP. 

ATL, BKS, DUP, G, NAC, TRC, YAW. 

TRC, YAW. 

BKS, DUP, G, NAC, TRC. 

G. 

ATL, BKS, G, NAC, TRC, VPC. 

AAP, ALT, ATL, BKS, CMG, DUP, G, NAC, TRC, VPC, YAW. 

ATL. 

AAP. 

AAP, DUP. 

AAP, ACY, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, YAW. 

TRC. 

AAP, ATL, DUP, G, NAC, TRC. 

DUP. 

NAC, TRC. 

DUP, NAC, VPC. 

ATL, BKS, VPC. 

NAC. 

G. 

BKS, NAC. 

AAP, ATL, BKS, BL, FAB, G, NAC, TRC, VPC, YAW. 

G. 

NAC. 

ACY. 

BKS. 

ACY, ALT, ATL, BL, TRC, YAW. 



DYES 



101 



TABLE 8B.— Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



DISPERSE DYES 

•Disperse yellow dyes: 

Disperse Yellow 1 

Disperse Yellow 2 

•Disperse Yellow 3 

•Disperse Yellow 5 

Disperse Yellow 8 

Disperse Yellow 17 

•Disperse Yellow 23 

Disperse Yellow 31 

Disperse Yellow 32 

•Disperse Yellow 33 

•Disperse Yellow 34 

Disperse Yellow 37 

•Disperse Yellow 42 

Disperse Yellow 50 

•Disperse Yellow 54 

Disperse Yellow 67 

Other disperse yellow dyes 

•Disperse orange dyes: 

•Disperse Orange 3 

•Disperse Orange 5 

Disperse Orange 16 

•Disperse Orange 17 

Disperse Orange 21 

Disperse Orange 25 

Disperse Orange 26 

Disperse Orange 29 

Disperse Orange 30 

Disperse Orange 38 

Disperse Orange 44 

Other disperse orange dyes 

•Disperse red dyes: 

•Disperse Red 1 

Disperse Red 4 

•Disperse Red 5 

Disperse Red 9 

•Disperse Red 11 

•Disperse Red 13 

Disperse Red 15 

•Disperse Red 17 

Disperse Red 20 

Disperse Red 21 

Disperse Red 30 

Disperse Red 31 

Disperse Red 32 

Disperse Red 55 

Disperse Red 56 

Disperse Red 59— 

•Disperse Red 60 

Disperse Red 61 

Disperse Red 65 

Disperse Red 66 

Disperse Red 73 

Disperse Red 78 

Disperse Red 96 

Other disperse red dyes 

Disperse violet dyes: 
■ *Disperse Violet 1 

•Disperse Violet 4 

Disperse Violet 8 

Disperse Violet 11 

Disperse Violet 14 

Disperse Violet 18 

Disperse Violet 22 

Disperse Violet 26 

•Disperse Violet 27 

Other disperse violet dyes 

•Disperse blue dyes: 

•Disperse Blue 1 

•Disperse Blue 3 



BKS, BL, DUP, EKT, G, HSH, ICC, NAC, SDH, TRC. 

EKT, G, ICC. 

TRC. 



EKT, ICC, NAC, TRC. 

EKT, ICC, G. 
ICC. 

DUP. TRC. 



DUP, G, ICC, TRC. 
EKT, G, ICC. 



BKS, BL, DUP, EKT, G, HSH, ICC, NAC, TRC. 
EKT, G. 



BKS, EKT, G, HSH, ICC, NAC. 

TRC. 



EKT, G, ICC. 

BKS, BL, DUP, EKT, G, HSH, ICC, NAC, TRC, YAW. 
TRC. 

BKS, EKT, G, HSH, ICC. 

DUP, G, TRC. 
G, ICC. 
HSH, ICC, NAC. 

BKS, DUP, EKT, G, HSH, ICC, TRC. 



DUP, VPC. 
TRC. 



DUP, EKT, G, ICC, VPC. 



BKS, G, HSH, ICC, TRC. 
G, ICC. 



ACY, BL, DUP. 
G, ICC. 



G, TRC. 

BKS, EKT, G, HSH, ICC, TRC. 



102 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 8B. Benzenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer, 1965 — Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



DISPERSE DYES — Continued 

^Disperse blue dyes — Continued 

■^Disperse Blue 7 

Disperse Blue 9 

Disperse Blue 27 

Disperse Blue 35 

Disperse Blue 51 

Disperse Blue 55 

Disperse Blue 59 

Disperse Blue 60 

Disperse Blue 61 

Disperse Blue 62 

Disperse Blue 63 

^Disperse Blue 64- 

Disperse Blue 70 

Disperse Blue 71 

Disperse Blue 73 

Disperse Blue 79 

Other disperse blue dyes 

Disperse brown dyes: 

Disperse Brown 2 

Other disperse brown dyes 

^Disperse black dyes: 

^Disperse Black 1 

Disperse Black 2 

Disperse Black 6 

Disperse Black 7 

^Disperse Black 9 

Other disperse black dyes 

FIBER-REACTIVE DYES 

*Reactive yellow dyes: 

Reactive Yellow 1 

Reactive Yellow 2 

Reactive Yellow 3 

Reactive Yellow 4 

Reactive Yellow 6 

Reactive Yellow 7 

Reactive Yellow 11 

Reactive Yellow 13 <- 

Reactive Yellow 14 

Reactive Yellow 15 

Reactive Yellow 16 

Reactive Yellow 17 

Reactive Yellow 18 — 
Reactive Yellow 22- 
Reactive Yellow 24- 

Other reactive yellow dyes 

Reactive orange dyeer 
Reactive Orange 1- 

Reactive Orange 2 

Reactive Orange 4 

Reactive Orange 5- 
Reactive Orange 7- 
Reactive Orange 12- 

Reactive Orange 13 

Reactive Orange 14 

Reactive Orange 16 

*Reactive red dyes: 

Reactive Red 1 

Reactive Red 2 

Reactive Red 3 

Reactive Red 4- 

Reactive Red 5 

Reactive Red 6 

Reactive Red 8 

Reactive Red 11 

Reactive Red 13 

Reactive Red 16 



AAP, 


EKT, G, ICC, TRC. 


G, ICC. 


EKT. 




ICI. 




G. 




TRC. 




DUP. 




DUP. 




DUP. 




DUP. 




DUP. 




DUP, 


G, TRC. 


AAP. 




VPC. 




TRC. 




TRC. 




AAP, 


BKS, DUP, EKT, G, HSH, ICC, STD, VPC 


DUP. 




EKT, 


G, ICC. 


AAP, 


BL, DUP, G, TRC. 


DUP, 


TRC. 


AAP, 


DUP. 


YAW. 




AAP, 


BL, DUP, EKT, G, NAC. 


DUP, 


EKT, G, ICC, YAW. 



ICI. 

TRC. 

TRC. 

ICI. 

TRC. 

ICI. 

TRC. 

HST. 

HST. 

DUP, HST. 

HST., 

HST.. 

ICI. 

ICI. 

HST. 

DUP, G„ USE. 

ICI. 
TEC. 
ICI. 
TRC. 
DUP. 
ICI. 
ICI. 
ICI. 
HST. 

ICI. 
ICI. 
ICI. 
TRC. 
ICI. 
ICI. 
ICI. 
ICI. 
ICI. 
TRC. 



DYES 



103 



TABLE 8B. - 



■Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



Dye 



FIBER- REACTIVE DYES— Continued 

*Reactive red dyes — Continued 

Reactive Red 21 

Reactive Red 29 

Reactive Red 31 

Reactive Red 33 

Reactive Red 35 

Other reactive red dyes 

Reactive violet dyes: 

Reactive Violet 1 

Reactive Violet 2 

Reactive Violet 4 

Reactive Violet 5 

Other reactive violet dyes 

*Re active blue dyes: 

Reactive Blue 1 

Reactive Blue 2 

Reactive Blue 3 

Reactive Blue 4 

Reactive Blue 5 

Reactive Blue 7 

Reactive Blue 9 

Reactive Blue 19 

Reactive Blue 21 

Reactive Blue 25 

Reactive Blue 27 

Other reactive blue dyes 

Reactive green dyes 

Reactive brown dyes: 

Reactive Brown 1 

Reactive Brown 10 

Reactive black dyes: 

Reactive Black 1 

Reactive Black 5 

Reactive Black 9 

FLUORESCENT BRIGHTENING AGENTS 

Fluorescent Brightening Agent 1 

Fluorescent Brightening Agent 6 

Fluorescent Brightening Agent 8 

♦Fluorescent Brightening Agent 9 

Fluorescent Brightening Agent 22 

Fluorescent Brightening Agent 24 

Fluorescent Brightening Agent 25 

♦Fluorescent Brightening Agent 28 

Fluorescent Brightening Agent 30 

Fluorescent Brightening Agent 33 

Fluorescent Brightening Agent 34- 

Fluorescent Brightening Agent 37 

Fluorescent Brightening Agent 45 

Fluorescent Brightening Agent 46 

Fluorescent Brightening Agent 49 

Fluorescent Brightening Agent 52 

Fluorescent Brightening Agent 54 

Fluorescent Brightening Agent 59 

Fluorescent Brightening Agent 61 

Fluorescent Brightening Agent 68 

Fluorescent Brightening Agent 71 

Fluorescent Brightening Agent 75 

Fluorescent Brightening Agent 102 

Fluorescent Brightening Agent 108 

Fluorescent Brightening Agent 113 

Fluorescent Brightening Agent 114 

Fluorescent Brightening Agent 125 

Fluorescent Brightening Agent 126 

Fluorescent Brightening Agent 128 

Fluorescent Brightening Agent 130 

Fluorescent Brightening Agent 134 

Fluorescent Brightening Agent 135 



Manufacturers' identification codes 
(according to list in table 22) 



HST. 
ICI. 
ICI. 
ICI. 
HST. 
DUP, G. 

ICI. 
TRC. 
HST. 
HST. 
HST. 

ICI. 

TRC. 

ICI. 

ICI. 

TRC. 

TRC. 

ICI. 

DUP, HST. 

DUP, HST. 

ICI. 

HST. 

DUP, G, HST. 

HST. 

TRC. 
ICI. 

TRC. 
HST. 
ICI. 



GGY. 

ACT. 

ACT. 

ACY, G, SDH. 

GGY. 

GGY. 

G. 

ACY, CCW, DUP, SDH. 

G. 

G. 

DUP. 

CIB. 

TRC. 

GGY. 

S. 

S. 

GGY. 

GGY. 

ACY. 

CCW, G. 

ACY, G. 

G. 

DUP. 

G. 

VPC. 

VPC. 

ACY. 

SDH. 

SDH. 

SDH. 

CIB. 

CIB. 



104 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 8B. — Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1 965- -Continued 



Dye 



Manufacturers ' identification codes 
(according to list in table 22) 



FLUORESCENT BRIGHTENING AGENTS— Continued 

Fluorescent Brightening Agent 136 

Fluorescent Brightening Agent 139 

Fluorescent Brightening Agent 155 

Fluorescent Brightening Agent 158 

Fluorescent Brightening Agent 159 

Fluorescent Brightening Agent 161 

Other fluorescent brightening agents 

FOOD, DRUG, AND COSMETIC COLORS 

Food, Drug, and Cosmetic Dyes 

*FD&C Blue No. 1 

FD&C Blue No. 2 

FD&C Green No. 3 

*FD&C Red No. 2 

*FD&C Red No. 3 

*FD&C Red No. 4 

FD&C Violet No. 1 

*FD&C Yellow No. 5 

*FD&C Yellow No. 6 

Other food, drug, and cosmetic dyes 

Drug and Cosmetic Dyes 

D&C Black No. 1 

D&C Blue No. 1 

D&C Blue No. 4 

D&C Blue No. 6 

DM) Blue No. 9 

D&C Brown No. 1 

D&C Green No. 5 

D&C Green No. 6 

D&C Green No. 8 

D&C Orange No. 4 

D&C Orange No. 5 

D&C Orange No. 10 

D&C Orange No. 17 

D&C Red No. 2 

D&C Red No. 3 

D&C Red No. 6 

D&C Red No. 7 

D&C Red No. 8 

D&C Red No. 9 

D&C Red No. 10 

D&C Red No. 11 

*D&C Red No. 12 — 

D&C Red No. 13 

D&C Red No. 17 

*D&C Red No. 19 

*D&C Red No. 21 

D&C Red No. 22 

D&C Red No. 27 

D&C Red No. 28 

D&C Red No. 30 

D&C Red No. 31 - 

D&C Red No. 33 

D&C Red No. 34 

*D&C Red No. 36 

D&C Red No. 37 

D&C Red No. 39 

D&C Violet No. 2 

D&C Yellow No. 5 

D&C Yellow No. 6 

D&C Yellow No. 8 

D&C Yellow No. 10 

D&C Yellow No. 11 



CIB. 
CIB. 
WLM. 
ACY. 
ACY. 
ACY. 
ACY, CCW, CIB, DUP, G, GGY, S, VPC. 



BAT, 


KON, 


NAC, 


SDH, 


WJ. 


K0N, 


NAC, 


SDH. 






WJ. 










BAT, 


KON, 


NAC, 


SDH, 


STG, WJ 


BAT, 


KON, 


NAC, 


SDH, 


STG. 


BAT, 


KON, 


NAC, 


SDH, 


STG. 


BAT, 


NAC. 








BAT, 


KON, 


NAC, 


SDH, 


STG, WJ 


BAT, 


KON, 


NAC, 


SDH, 


STG, WJ 


WJ. 










K0N, 


YAW. 








K0N. 










SNA. 










K0N, 


NAC. 








NAC. 










NAC. 










K0N, 


NAC. 








NAC. 










K0N, 


SDH. 








K0N, 


SNA. 








SNA, 


TMS. 








TMS. 










K0N, 


SNA. 








K0N. 










K0N, 


TMS. 








K0N, 


TMS. 








K0N, 


SNA, 


TMS. 






K0N, 


TMS. 








K0N, 


SNA, 


TMS. 






K0N, 


SNA. 








K0N, 


SNA. 








K0N, 


SNA, 


TMS. 






SNA, 


TMS. 








KON, 


NAC. 








KON, 


SNA, 


TMS. 






KON, 


SNA, 


TMS. 






KON. 










TMS. 










NAC. 










KON. 










KON. 










KON, 


NAC. 








KON, 


SNA, 


TMS. 






KON, 


SNA, 


TMS. 






NAC. 










SDH. 










NAC. 










KON, 


TMS. 








KON. 










KON, 


NAC, 


TMS. 






KON, 


NAC. 








NAC. 











DYES 



105 



TABLE 8B. —Benzenoid dyes for which U.S. production or sales were re, 
manufacturer, 1 965- -Continued 



ported, identified by 



Dye 



FOOD, DRUG, AND COSMETIC COLORS— Continued 
Drug and Cosmetic Dyes, External 



Ext. D&C Green No. 1~ 

Ext. DM Orange No. 3- 

Ext. DScC Red No. 8 

Ext. DScC Red No. 15— 

Ext. DScC Violet No. 2- 

Ext. DScC Yellow No. 1- 

Ext. DScC Yellow No. 5- 

Ext. DScC Yellow No. 7- 



Ingrain blue dyes: 
Ingrain Blue 1— 
Ingrain Blue 3— 
Ingrain Blue 4 — 
Ingrain Blue 8 — 



*Mordant yellow dyes: 

*Mordant Yellow 1 

Mordant Yellow 3 

Mordant Yellow 5 

*Mordant Yellow 8— 
Mordant Yellow 10— 
Mordant Yellow 14 — 
Mordant Yellow 16 — 
Mordant Yellow 20— 
Mordant Yellow 26— 
Mordant Yellow 29— 
Mordant Yellow 30— 
Mordant Yellow 36— 
n-Mordant orange dyes: 

*Mordant Orange 1 — 
Mordant Orange 4 — 
Mordant Orange 6 — 
Mordant Orange 8 — 
Mordant Orange 30— 
*Mordant red dyes: 

Mordant Red 3 

Mordant Red 5 

Mordant Red 6 

*Mordant Red 7 

Mordant Red 9 

Mordant Red 11 

Mordant Red 19—— 

Mordant Red 59 

Mordant Red 64 

Mordant violet dyes: 

Mordant Violet 5— 

Mordant Violet 11- 

Mordant Violet 26- 

*Mordant blue dyes: 

*Mordant Blue 1 

Mordant Blue 3 

Mordant Blue 7 

Mordant Blue 9 

Mordant Blue 13 

Mordant Blue 19 

Mordant green dyes: 
Mordant Green 11— 
Mordant Green 36— 
*Mordant brown dyes: 

*Mordant Brown 1 

Mordant Brown 12 — 
Mordant Brown 13 — 
Mordant Brown 15 — 
Mordant Brown 17— 



INGRAIN DYES 



MORDANT DYES 



Manufacturers' identification codes 
(according to list in table 22) 



K0N, NAC. 
K0N, NAC. 
SNA. 
K0N. 
K0N. 

K0N, NAC. 
SNA. 
K0N. 



ICI. 
ICI. 
ICI. 

ICI. 



ATL, G, PDC, TRC. 






ATL, NAC. 






NAC, TRC. 






DUP, NAC, VPC. 






DUP. 






NAC, TRC. 






ACY, NAC. 






NAC. 






VPC. 






G. 






TRC, VPC. 






PDC. 






ACY, G, PDC, TRC. 






G, VPC. 






ATL, G, TRC. 






TRC. 






NAC. 






ACY, ICI, NAC. 






PDC. 






G. 






ACY, BD0, CMG, G, 


NAC, 


PDC, TRC, VPC 


G, HSH, MRX, NAC. 






ACY, NAC. 






PDC. 






TRC. 






PDC. 






NAC. 






G. 






G. 






DUP, G, NAC, TRC. 






G. 






NAC, TRC. 






G, NAC. 






HSH, NAC. 






CMG. 






ACY. 






NAC, PDC. 






CMG, DUP, G, NAC, 


TRC, 


YAW. 


PDC. 






NAC. 






G. 







106 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 8B. Benzenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer, 1965 — Continued 



Dye 



MORDANT DYES— Continued 

*Mordant brown dyes — Continued 

Mordant Brown 18 

Mordant Brown 19 

Mordant Brown 21 

Mordant Brown 33 

*Mordant Brown 4-0 

Mordant Brown 43 

Mordant Brown 50 

Mordant Brown 63 

Mordant Brown 70 

*Mordant black dyes: 

Mordant Black 1 

^Mordant Black 3 

^Mordant Black 5 

Mordant Black 7 

Mordant Black 8 

Mordant Black 9 

*Mordant Black 11 

*Mordant Black 13 

Mordant Black 16 

*Mordant Black 17 

Mordant Black 19 

Mordant Black 26 

*Mordant Black 38 

OXIDATION BASES 

Oxidation Base 8 and 8A 

Oxidation Base 21 

Oxidation Base 22 

Oxidation Base 25 

Other oxidation bases 

SOLVENT DYES 

^Solvent yellow dyes: 

Solvent Yellow 1 

*Solvent Yellow 2 

^Solvent Yellow 3 

Solvent Yellow 13 

^Solvent Yellow 14 

Solvent Yellow 16 

Solvent Yellow 19 

Solvent Yellow 29 

Solvent Yellow 30 

Solvent Yellow 33 

Solvent Yellow 34 

Solvent Yellow 40 

Solvent Yellow 42 

Solvent Yellow 43 

Solvent Yellow 44 

Solvent Yellow 45 — 

^Solvent Yellow 47 

Solvent Yellow 53 

Solvent Yellow 56 

Solvent Yellow 66 

Solvent Yellow 71 

Solvent Yellow 72 

Other solvent yellow dyes 

* Solvent orange dyes: 

^Solvent Orange 2 

*Solvent Orange 3 

Solvent Orange 5 

^Solvent Orange 7 

Solvent Orange 20 

Solvent Orange 23 

Solvent Orange 24 

Solvent Orange 25 

Solvent Orange 31 



Manufacturers' identification codes 
(according to list in table 22) 



DUP, NAC. 

G. 

G, VPC. 

DUP, NAC, TRC. 

CMG, DUP, G, NAC, VPC, YAW. 

G. 

TRC. 

TRC. 

DUP, PDC. 

G, NAC, TRC. 

G, NAC, TRC. 

G, NAC, TRC. 

G. 

NAC, VPC. 

NAC, VPC. 

G, NAC, TRC, VPC. 

G, HSH, NAC, TRC. 

NAC. 

ACY, DUP, G, NAC, TRC. 

PDC. 

TRC. 

CMG, G, NAC, VPC. 



ACY. 
PDC. 
ACY. 
ACY. 
ACY. 



ACY. 

AAP, DUP, FH, G, PAT, PSC. 

DUP, FH, G, NAC, PSC. 

ACY, G, TRC. 

AAP, ACY, DUP, FH, G, NAC, PAT, PSC, SDH. 

PAT. 

G. 

G, NAC. 

PSC. 

ACY, NAC. 

DUP. 

NAC. 

NAC. 

G. 

G, NAC. 

DUP, NAC. 

ACY, DUP, G, NAC. 

NAC. 

ACY, FH. 

NAC. 

ACY. 

ACY. 

ACY, DSC, PAT. 

AAP, NAC, PSC. 

ACY, DSC, G, NAC. 

G. 

ACY, ATL, FH, G, NAC, PSC. 

ACY, G, NAC. 

NAC. 

DUP. 

ACY, DUP. 

NAC. 



DYES 



107 



TABLE 8B -Benzenoid dyes for which U.S. production or sales were reported, identified by 
lAtsi^ ob. j manufacturer, 1965 —Continued 



Dye 



SOLVENT DYES— Continued 



•Solvent orange dyes— Continued 

Solvent Orange 47 

Solvent Orange 48 

Solvent Orange 51 

Other solvent orange dyes 

•Solvent red dyes: 

Solvent Red 8 

Solvent Red 22 

•Solvent Red 24 

•Solvent Red 26 

Solvent Red 27 

Solvent Red 33 

Solvent Red 34 

Solvent Red 35 

Solvent Red 36 

Solvent Red 40 

Solvent Red 41 

•Solvent Red 49 

Solvent Red 52 

Solvent Red 65 

Solvent Red 68 

Solvent Red 69 

Solvent Red 74 

Solvent Red 76 

Solvent Red 80 

Solvent Red 105 

Solvent Red 106 

Solvent Red 108 

Solvent Red 111 

Solvent Red 115 

Other solvent red dyes 

•Solvent violet dyes: 

*Solvent Violet 8 

Solvent Violet 9 

Solvent Violet 13 

Solvent Violet 14 

Solvent Violet 17 

Other solvent violet dyes- 
Solvent "blue dyes: 

Solvent Blue 3 

Solvent Blue 4 

Solvent Blue 5 

Solvent Blue 6 

Solvent Blue 7 

Solvent Blue 9 

Solvent Blue 11 

Solvent Blue 12 

Solvent Blue 13 

Solvent Blue 16 

Solvent Blue 30 

Solvent Blue 31 

Solvent Blue 32 

Solvent Blue 36 

Solvent Blue 37 

•Solvent Blue 38 

Solvent Blue 39 

Solvent Blue 43 

Solvent Blue 58 

Solvent Blue 59 

Solvent Blue 60 

Other solvent blue dyes — 
•Solvent green dyes: 

Solvent Green 1 

Solvent Green 2 

•Solvent Green 3 

Solvent Green 10 

Solvent Green 11 

Other solvent green dyes- 



Manufacturers' identification codes 
(according to list in table 22) 



ACY. 
ACY. 
DSC, DUP, PAT. 

G. 

G. 

ACY, DUP, G, PAT, SDH. 

AAP, ACY, FH, NAC, PSC. 

NAC. 

DUP, G. 

DUP. 

G. 

NAC. 

G. 

DSC. 

ACY, DSC, DUP, G. 

G, ICI. 

NAC. 

NAC. 

DUP. 

NAC. 

NAC. 

NAC. 

ACY. 

ACY. 

ACY. 

ACY. 

ACY. 

ACY, BKS, DSC, DUP, G, ICI, PAT. 

ACY, DSC, NAC. 

DSC. 

AAP, HSH, ICI. 

ICI. 

NAC. 

DSC, PAT. 

SW. 

DSC, DUP, SDH. 

DSC. 

DSC. 

ACY, NAC. 

G. 

G, ICI. 

DUP, NAC 

ICI. 

NAC. 

NAC. 

NAC. 

AAP. 

DUP, NAC. 

DUP. 

ACY, DUP, NAC. 

NAC. 

NAC. 

ACY. 

ACY. 

ACY. 

AAP, ACY, DSC, G, ICI, PAT, SDH. 



ACY, DSC, SDH. 

AAP, ACY, ATL, CMG, G, HSH, ICI, NAC. 

DUP. 

DUP. 

DSC. 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 8B. --Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer , 1 965- -Continued 



Dye 



Manufacturers ' identification codes 
(according to list in table 22) 



SOLVENT DYES--Continued 

^Solvent brown dyes: 

Solvent Brown 11 

Solvent Brown 12 

Solvent Brown 17 

Solvent Brown 19 

Solvent Brown 20 

Solvent Brown 21 ■ 

Solvent Brown 22 

Solvent Brown 38 

Other solvent brown dyes 

Solvent black dyes: 

Solvent Black 3 

Solvent Black 5 

Solvent Black 7 

Solvent Black 12 

Solvent Black 13 

Solvent Black 17 

Solvent Black 19 

Solvent Black 20 

Solvent Black 26 

Other solvent black dyes 

SULFUR DYES 

Sulfur yellow dyes : 

Sulfur Yellow 2 

Leuco Sulfur Yellow 2 

Sulfur Yellow 4 

Leuco Sulfur Yellow 4 

Leuco Sulfur Yellow 15 

Other sulfur yellow dyes 

Sulfur red dyes: 

Sulfur Red 1 

Sulfur Red 6 

Sulfur Red 8 

Sulfur blue dyes: 

*Sulfur Blue 7 

Leuco Sulfur Blue 7 

Leuco Sulfur Blue 8 

Sulfur Blue 9 

Leuco Sulfur Blue 9 

*Sulfur Blue 11 

Leuco Sulfur Blue 11 

Sulfur Blue 13 

Leuco Sulfur Blue 13 

*Sulfur Blue 15 

Sulfur Blue 16 

Other sulfur blue dyes 

Sulfur green dyes: 

Sulfur Green 1 

Leuco Sulfur Green 1 ; — 

Sulfur Green 2 

Leuco Sulfur Green 2 

Sulfur Green 3 

Leuco Sulfur Green 3 

Sulfur Green 14 

Leuco Sulfur Green 16 

Sulfur Green 28 

Other sulfur green dyes 

Sulfur brown dyes: 

Sulfur Brown 3 

Leuco Sulfur Brown 3 

*Sulfur Brown 10 

Leuco Sulfur Brown 10 

Sulfur Brown 14 

Leuco Sulfur Brown Li 

Sulfur Brown 20 

Sulfur Brown 21 

Sulfur Brown 30 



ACY, 


DSC, 


G. 


DUP. 






DUP. 
ACY, 


DUP. 




NAC. 






FH. 






DSC. 






NAC. 






ACY, 


DSC, 


NAC. 


ACY, 


DSC, 


FH, NAC 


NAC. 






NAC. 






DUP. 






G. 






NAC. 






ACY. 






DSC, 


DUP. 





NAC. 
ACY, 
SDC. 
SDC. 
ACY. 
ACY, 

ACY, 

ACY, 
DUP. 

ACY, 
ACY, 
SDC. 
ACY, 
SDC. 
DUP, 
SDC. 
NAC. 
ACY. 
ACY, 
ACY. 
ACY, 

NAC. 
NAC. 
NAC, 
SDC. 
NAC, 
SDC. 
DUP. 
SDC. 
ACY. 
AUG, 

SDC. 
SDC. 
DUP, 
SDC. 
ACY. 
ACY. 
DUP. 
DUP. 
ACY. 



AUG, SDC. 



NAC. 
DUP, NAC. 



NAC, SDC. 
NAC, SDC. 



NAC. 
NAC, SDC. 



DUP, NAC. 
SDC. 



SDC. 
SDC. 



NAC, SDC. 



DYES 



109 



TABLE 8B. 



■ Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1965- -Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



SULFUR DYES— Continued 

Sulfur brown dyes — Continued 

Sulfur Brown 33 

Leuco Sulfur Brown 37 

Sulfur Brown 39 

Sulfur Brown 4-3 

Leuco Sulfur Brown 43 

Sulfur Brown 44 

Leuco Sulfur Brown 44 

Sulfur Brown 45 

Sulfur Brown 50 

Other sulfur brown dyes 

Sulfur black dyes: 

*Sulfur Black 1 — 

*Leuco Sulfur Black 1 

Sulfur Black 2 

*Leuco Sulfur Black 2 

Sulfur Black 6 

Leuco Sulfur Black 6 

Sulfur Black 10 

Leuco Sulfur Black 10 

Sulfur Black 11 

Leuco Sulfur Black 11 

Other sulfur black dyes 

VAT DYES 

*Vat yellow dyes: 

Vat Yellow 1, 12-1/2$ ■ 

*Vat Yellow 2, 8-l/2$- 

Solubilized Vat Yellow 2, 25$ 

Vat Yellow 3, 12-1/2$- 

*Vat Yellow 4, 12-1/2$ 

Solubilized Vat Yellow 4, 37-1/2$ 

Vat Yellow 10, 10$ 

Vat Yellow 13, 6-1/2$ 

Vat Yellow 1A, 12-1/2$ -— 

Vat Yellow 15, 11-1/2$ 

Vat Yellow 16, 16-2/3$- 

Vat Yellow 21, 9-1/2$ - 

Vat Yellow 22, 10$ 

Vat Yellow 27 

Vat Yellow 33 - 

Vat Yellow 41, 9$ 

Other vat yellow dyes 

*Vat orange dyes: 

*Vat Orange 1, 20$ 

*Solubilized Vat Orange 1, 26$ 

*Vat Orange 2, 12$ 

*Vat Orange 3, 13-1/2$- 

*Vat Orange 4, 6$ 

*Vat Orange 5, 10$ 

*Solubilized Vat Orange 5, 30$ 

*Vat Orange 7, 11$ 

*Vat Orange 9, 12$ 

Vat Orange 11, 6$ 

*Vat Orange 15, 10$ 

Vat Orange 23, 17-1/2$ 

Vat Orange 24 

Other vat orange dyes 

*Vat red dyes: 

*Vat Red 1, 13$ 

Solubilized Vat Bed 1, 37$ 

Vat Red 10, 18$ 

Solubilized Vat Red 10, 31$ 

Vat Red 12, 8-1/2$ 

*Vat Red 13, 11$ 

Vat Red 14, 10$ 

*Vat Red 15, 10$ 

Vat Red 16, 11$ 



ACY. 
SDC. 
SDC. 
NAC. 
NAC. 
NAC. 
NAC. 
NAC. 
NAC. 
ACY, AUG, NAC, SDC. 

ACY, DUP, NAC, SDC. 

ACY, AUG, NAC, SDC. 

ACY, DUP, NAC. 

ACY, NAC, SDC. 

G. 

NAC. 

ACY. 

ACY, NAC. 

SDC. 

SDC. 

SDC. 



NAC. 

AAP, DUP, G, ICI, NAC, TRC, VPC. 

G, ICI. 

DUP. 

AAP, ACY, ATL, CMG, G, HST, ICI, VPC. 

G, HST, ICI. 

G. 

ICI. 

TRC. 

ACY. 

DUP. 

ATL. 

DUP, G. 

VPC. 

TRC, VPC. 

ACY. 

MAY, NAC, VPC. 

CMG, G, HST, ICI, NAC, TRC, VPC. 

G, HST, ICI. 

AAP, ACY, CMG, DUP, G, ICI, NAC, TRC. 

CMG, DUP, G, HST. 

ACY, CMG, DUP. 

AAP, ACY, HST. 

G, HST, ICI. 

G, HST, TRC. 

ACY, CMG, DUP, G, ICI, NAC, TRC. 

DUP, NAC. 

AAP, G, ICI, NAC, TRC, VPC. 

ACY, DUP, G. 

DUP. 

SDC. 

AAP, ACY, DUP, HST, ICI. 

G, HST, ICI. 

G, NAC, TRC. 

G. 

DUP. 

DUP, G, TRC. 

G, HST. 

G, HST, TRC. 

DUP. 



no 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 8B. —Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



Dye 



VAT DYES— Continued 

*Vat red dyes — Continued 

Vat Red 17, 10$ 

Vat Red 23 - 

Vat Red 29, 18$ 

*Vat Red 32, 20$ 

Vat Red 35, 12-1/2$ 

Vat Red 41, 20$- 

Vat Red 44, 17$ — 

Vat Red 52, 10$- - - 

Vat Red 53, 12$ — 

Vat Red 56 

Vat Red 62 

Other vat red dyes 

*Vat violet dyes: 

*Vat Violet 1, 11$ 

Solubilized Vat Violet 1, 26$ 

*Vat Violet 2, 20$ 

Vat Violet 3, 15$ 

*Vat Violet 9, 12$ 

Vat Violet 12, 10$ 

*Vat Violet 13, 6-l/*$ 

Vat Violet 1A, 12-1/2$ 

Vat Violet 17, 12-1/2$ 

Other vat violet dyes 

*Vat blue dyes: 

Vat Blue 1, 20$ 

Solubilized Vat Blue 1, 25$ 

Vat Blue 3, 16$ 

Vat Blue 4, 10$ 

Vat Blue 5, 16$ - 

Solubilized Vat Blue 5, 38$ 

*Vat Blue 6, 8-1/3$ 

Solubilized Vat Blue 6, 17-1/2$- 

Vat Blue 7, 12-1/2$ - 

Solubilized Vat Blue 9, 35$ 

Vat Blue 12, 6-l/2$- 

Vat Blue 14, 8-1/3$ 

Vat Blue 16, 16$-- 

*Vat Blue 18, 13$ 

*Vat Blue 20, 14$ 

Vat Blue 29— - 

Vat Blue 39, 12$ 

Vat Blue 43 

Vat Blue 53 

Vat Blue 60 

Vat Blue 61, 16$ 

Other vat blue dyes 

*Vat green dyes: 

*Vat Green 1, 6$ 

Solubilized Vat Green 1, 12-3/2$ - 

*Vat Green 3, 10$ 

*Solubilized Vat Green 3, 26$ 

*Vat Green 8, 8-1/2$ 

*Vat Green 9, 12-1/2$— 

Vat Green 15, 17$ ■ 

Vat Green 18, 8$- 

Vat Green 19, 13$ 

Vat Green 20, 6$- 

Other vat green dyes 

*Vat brown dyes: 

*Vat Brown 1, 11$ 

Solubilized Vat Brown 1, 17$ 

*Vat Brown 3, 11$ 

*Vat Brown 5, 13$- ■ 

Vat Brown 6, 17-1/2$ 

Vat Brown 11, 12$ 

Vat Brown 12, 12-1/2$ 

Vat Brown 13, 17$ 

Vat Brown 14, 12$ 



Manufacturers' identification codes 
(according to list in table 22) 



G. 

DUP. 

G, NAC. 

DUP, G, NAC. 

NAC, TRC. 

HST. 

TRC. 

DUP. 

DUP. 

ACY. 

DUP. 

DUP, G, TRC, VPC. 

ACY, DUP, G, ICI, MAY, NAC, TRC. 

G, ICI. 

ACY, G, HST, NAC, VPC. 

G, HST, NAC. 

DUP, G, ICI, MAY, NAC, TRC. 

DUP. 

DUP, G, ICI, NAC, TRC. 

NAC. 

DUP, G, NAC. 

NAC. 

NAC. 

G. 

HST. 

ACY, DUP, G. 

ATL, DUP, HST, NAC, VPC. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC. 

G, HST, ICI. 

NAC. 

G. 

DUP. 

DUP, G, NAC, TRC. 

ACY, DUP, NAC. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC. 

AAP, ACY, ATL, DUP, G, ICI, MAY, NAC, TRC. 

G. 

G. 

SDC. 

G. 

DUP. 

DUP. 

SDC, x. 

AAP, ACY, ATL, DUP, G, ICI, MAY, NAC. 

G, HST, ICI. 

AAP, ACY, ATL, DUP, G, ICI, MAY, NAC, TRC. 

G, HST, ICI. 

ATL, DUP, G, ICI, NAC. 

ACY, ATL, DUP, G, MAY, NAC, SDC, TRC. 

NAC. 

DUP. 

DUP. 

DUP. 

G, SDG. 

ACY, DUP, G, ICI, MAY, NAC, TRC. 

G, ICI. 

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC, VPC. 

AAP, ACY, G, HST, VPC. 

TRC. 

MAY, TRC. 

DUP, NAC. 

MAY. 

HST. 



DYES 



TABLE 8B. --Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



Dye 


Manufacturers' identification codes 
(according to list in table 22) 


VAT DYES— Continued 
*Vat brown dyes — Continued 






G. 




ACT. 

AAP. 

ICI. 

DUP. 

G. 

TRC. 


*Vat black dyes: 






























ACY. 




















G. 



















112 



SYNTHETIC ORGANIC CHEMICALS. 1965 



Pigments 

TABLE 11B. — Benzenoid pigments for which U.S. production or sales were reported, identified 

by manufacturer , 1965 

[Benzenoid pigments for which separate statistics are given in table 11A are marked below with an asterisk (♦); 
products not po marked do not appear in table 11A because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that 
the manufacturer did not consent to his identification with the designated product ] 



Pigment 



Manufacturers' identification codes 
(according to list in table 22) 



TONERS 
♦Yellow toners: 
♦Hans a yellows: 

♦Pigment Yellow 1, C.I. 11 680 

♦Pigment Yellow 3, C.I. 11 710 

Pigment Yellow 4, C.I. 11 665 

Pigment Yellow 5, 'C.I. 11 660 

Pigment Yellow 6, C.I. 11 670 

Pigment Yellow 9, C.I. 11 720 

Pigment Yellow 49, C.I. 11 765 

Pigment Yellow 65, C.I. 11 74-0 

Pigment Yellow 73 

Pigment Yellow 74 

All other Hansa yellows 

♦Benzidine yellows: 

♦Pigment Yellow 12, C.I. 21 090 

♦Pigment Yellow 13, C.I. 21 100 

♦Pigment Yellow 14, C.I. 21 095 

♦Pigment Yellow 17, C.I. 21 105 

Pigment Yellow 83 

All other benzidine yellows 

Pigment Yellow 10, C.I. 12 710 

Pigment Yellow 18, C.I. 49 005 

Pigment Yellow 19 

Pigment Yellow 60, C.I. 12 705 

Pigment Yellow 62 

(Basic Yellow 2), C.I. 41 000, fugitive- 

(Vat Yellow 1), C.I. 70 600 

(Vat Yellow 20), C.I. 68 420 

All other 

♦Orange toners: 

Pigment Orange 1, C.I. 11 725 

♦Pigment Orange 2, C.I. 12 060 

♦Pigment Orange 5, C.I. 12 075 

Pigment Orange 9 

♦Pigment Orange 13, C.I. 21 110 

Pigment Orange 15, C.I. 21 130 

♦Pigment Orange 16, C.I. 21 160 

Pigment Orange 30 

(Vat Orange 2), C.I. 59 705 

(Vat Orange 3), C.I. 59 300 

(Vat Orange 4), C.I. 59 710 

(Vat Orange 5), C.I. 73 335 

(Vat Orange 7), C.I. 71 105 

(Vat Orange 15), C.I. 69 025 

All other 

♦Red toners: 
♦Naphthol reds: 

♦Pigment Red 2, C.I. 12 310 

♦Pigment Red 5, C.I. 12 490 

Pigment Red 7, C.I. 12 420 

Pigment Red 9, C.I. 12 460 

Pigment Red 10, C.I. 12 440 

Pigment Red 13, C.I. 12 395 

Pigment Red 14, C.I. 12 380 

Pigment Red 15, C.I. 12 465 



ACY, AMS, DUP, FCL, G, HSC, HSH, ICI, IMP, K0N, NAC, 

PPG, S, SDH, SNA, SW. 
HSC, HSH, HST, IMP, KCW, K0N, NAC, PPG, S, SNA, SW. 
NAC, SNA. 
IMP. 

CIK, IMP. 
SNA. 
ICI. 
SW. 

NAC, SW. 
DUP, SW. 
DUP, HSC, HSH, IMP, KCW, SDH, SNA. 

ACY, AMS, DUP, FCL, G, HSC, HSH, ICC, IMP, KON, LVY, 

MRX, NAC, S, SDH, SNA, SW. 
BUC, FCL, G, HSH, HST, ICC, IMP, NAC, ROM, SNA, SW. 
ACY, AMS, BUC, CPC, DUP, FCL, G, HSC, HSH, HST, ICC, 

IMP, KON, MRX, NAC, ROM, S, SDH, SNA, SW, x. 
ACY, AMS, DUP, FCL, HSC, HSH, HST, ICC, IMP, S, SDH, 

SNA, SW. 
HST, NAC. 

BUC, HSH, ICC, IMP, ROM, S, SW. 
SW. 
IMP. 
G. 
SW. 
S. 

MRX. 

NAC, TRC. 
NAC, TRC. 
ACY, ICC, IMP, SW. 

KCW, NAC. 

FCL, IMP, SDH, SW. 

ACY, EAK, HSC, IMP, SNA, SW. 

DUP. 

ACY, AMS, BUC, DUP, G, ICC, IMP, KON, NAC, SNA, SW. 

G, NAC. 

BUC, DUP, FCL, G, HSH, HST, ICC, IMP, NAC, ROM, SDH, 

SNA, SW. 
SNA, SW. 
G. 

NAC, TRC. 
NAC. 
TRO. 
G, NAC. 
NAC. 
HSH, ICC, KON, ROM, SDH. 



BUC, EAK, G, HSC, HSH, IMP, KCW, KON, MRX, NAC, S, SDH, 

SW. 
DUP, G, HSH, HST, ICC, ICI, IMP, NAC, ROM, SDH, SNA, SW. 
ICI, S. 
IMP. 
KCW. 

IMP, KCW. 
DUP, NAC. 
DUP. 



See note at end of table for definition of abbreviations. 



PIGMENTS 

TABLE WB.—Benzenoid pigments for which U.S. production or sales were reported, identified 
by manufacturer, 1 965— Continued 



113 



Pigment 



TONERS— Continued 

♦Red toners — Continued 
*Naphthol reds --Continued 

*Pigment Red 17, C.I. 12 390 

♦Pigment Red 18, C.I. 12 350 

Pigment Red 19, C.I. 12 400 

♦Pigment Red 22, C.I. 12 315 

♦Pigment Red 23, C.I. 12 355 

Pigment Red 31, C.I. 12 360 

All other naphthol reds 

♦Pigment Red 1, C.I. 12 070, dark 

♦Pigment Red 1, C.I. 12 070, light 

*Pigment Red 3, C.I. 12 120 

♦Pigment Red 4, C.I. 12 085 

Pigment Red 5 

♦Pigment Red 6, C.I. 12 090 

♦Pigment Red 38, C.I. 21 120 

Pigment Red 41, C.I. 21 200 

♦Pigment Red 48, C.I. 15 865 

Pigment Red 49, C.I. 15 630: 
*Barium toner 

♦Calcium toner 

♦Sodium toner 

♦Pigment Red 52, C.I. 15 860 

♦Pigment Red 53, C.I. 15 585, barium toner- - 

Pigment Red 53, C.I. 15 585, sodium toner-- 

♦Pigment Red 54, C.I. 14 830, calcium toner- 
Pigment Red 55, C.I. 15 820 

♦Pigment Red 57, C.I. 15 850, calcium toner- 
Pigment Red 58, C.I. 15 825 

♦Pigment Red 63, C.I. 15 880 

Pigment Red 64, C.I. 15 800 

Pigment Red 77, C.I. 15 826 

Pigment Red 78 

Pigment Red 79, PMA 

Pigment Red 81, C.I. 45 160, fugitive 

♦Pigment Red 81, C.I. 45 160, PMA. 

♦Pigment Red 81, C.I. 45 160, PTA 

Pigment Red 87, C.I. 73 310 

Pigment Red 88 

♦Pigment Red 90, C.I. 45 380 

Pigment Red 117, C.I. 15 603 

Pigment Red 122 

Pigment Red 123 

(Vat Red 10), C.I. 67 000 

(Vat Red 23) 

(Vat Red 29), C.I. 71 140 

All other 

♦Violet toners: 

Pigment Violet 1, C.I. 45 170, fugitive 

♦Pigment Violet 1, C.I. 45 170, PMA 

♦Pigment Violet 1, C.I. 45 170, PTA 

♦Pigment Violet 3, C.I. 42 535, fugitive 

♦Pigment Violet 3, C.I. 42 535, PMA 

♦Pigment Violet 3, C.I. 42 535, PTA 

Pigment Violet 19 

Pigment Violet 23 



Manufacturers ' identification codes 
(according to list in table 22) 



ACY, BLN, FCL, ICC, IMP, S, SNA, SW. 

IMP, NAC, SW. 

NAC. 

ACY, DUP, FCL, IMP, MRX, NAC, SNA, SW. 

ACY, BUC, DUP, FCL, HSC, HSH, ICC, IMP, NAC, ROM, SDH, 

SNA. 
ICC, SNA. 

BUC, ICC, IMP, KCW, ROM, SDH, SW, x. 
ACY, AMS, APC, FCL, HSC, HSH, IMP, K0N, LVY, NAC, 

PPG, SDH, SW. 
ACY, EAK, FCL, HSC, HSH, IMP, KON, PPG, SDH, SW. 
ACY, APC, BLN, CIK, DUP, EAK, FCL, HSC, HSH, IMP, KCW, 

KON, NAC, PPG, SDH, SNA, SW. 
ACY, AMS, FCL, HSC, HSH, IMP, KON, MRX, SDH, SNA, SW, 

UHL. 
IMP. 

DUP, HSC, HSH, KCW, SW. 
DUP, G, NAC, SNA, SW. 
G, NAC. 
ACY, AMS, BLN, DUP, FCL, G, HSC, HSH, ICC, IMP, KON, 

LVY, MRX, NAC, S, SNA, SW. 

ACY, AMS, CIK, FCL, HSC, HSH, IMP, KON, LVY, PPG, SDH, 

SNA, SW, UHL. 
ACY, AMS, FCL, HSC, IMP, LVY, PPG, SDH, SNA, SW. 
ACY, AMS, CIK, FCL, HSC, SDH, SW. 
AMS, FCL, HSC, HSH, IMP, SNA, SW. 
ACY, AMS, CIK, FCL, HSC, HSH, IMP, KON, LVY, MGR, MRX, 

SDH, SNA, SW. 
KCN. 

HSH, IMP, MRX, SDH. 
DUP, NAC. 
AMS, BLN, CIK, DUP, FCL, HSC, HSH, IMP, KON, LVY, MGR, 

NAC, S, SDH, SNA, SW. 
DUP, G, IMP. 

FCL, HSH, IMP, NAC, SNA, SW. 
NAC. 
SW. 
DUP. 
G. 

BLN, KCW. 
BLN, CPC, DUP, FCL, G, IMP, KON, LVR, LVY, MGR, MRX, 

NYC, S, SNA, SW. 
ACY, AMS, BLN, DUP, FCL, G, HSC, IMP, KCW, KON, MGR, 

MRX, S, SDH, SNA. 
NAC. 

NAC, SDH. 

AMS, FCL, ICC, IMP, LVR, LVY, NYC, SDH, SNA. 
SW. 
NAC. 
NAC. 
G, NAC. 
NAC. 
NAC. 
ACY, DUP, G, HAM, HSC, S, SW, TRC. 

BLN, UHL. 

BLN, G, IMP, LVR, MRX. 

ACY, AMS, BLN, DUP, FCL, G, HSC, IMP, KON, MRX, SNA. 

ACY, AMS, BLN, HAM, HSC, IMP, LVY, MGE, SDH, UHL. 

AMS, BLN, CIK, DUP, EAK, G, HSC, IMP, KON, LVR, LVY, 

MGR, MRX, NYC, PPG, SDH, SNA, SW, UHL. 
ACY, AMS, G, HSC, HSH, IMP, KON, MRX, SNA, SW. 
DUP, NAC. 
G, HST, TRC. 



See note at end of table for definition of abbreviations. 



TABLE 11B. 



SYNTHETIC ORGANIC CHEMICALS. 1965 

-Benzenoid pigments for which U.S. production or sales were reported, identified 
by manufacturer, 1 965- -Continued 



Pigment 



TONERS--Ccmtinued 

*Violet toners — Continued 

(Vat Violet 1), C.I. 60 010 

(Vat Violet 2), C.I. 73 385 

(Vat Violet 3), C.I. 73 395 

All other 

♦Blue toners: 

♦Pigment Blue 1, C.I. 42 595, PMA 

♦Pigment Blue 1, C.I. 42 595, PTA 

♦Pigment Blue 2, C.I. 44 045, fugitive 

♦Pigment Blue 2, C.I. 44 045, PMA 

♦Pigment Blue 2, C.I. 44 045, PTA 

Pigment Blue 3, C.I. 42 140, PTA 

Pigment Blue 5, C.I. 42 600 

Pigment Blue 9, C.I. 42 025, PMA 

♦Pigment Blue 9, C.I. 42 025, PTA 

Pigment Blue 10, C.I. 44 040, PMA 

Pigment Blue 10, C.I. 44 040, PTA 

♦Pigment Blue 14, C.I. 42 600, PMA 

Pigment Blue 14, C.I. 42 600, PTA 

♦Pigment Blue 15, C.I. 74 160, alpha form 

♦Pigment Blue 15, C.I. 74 160, beta form 

♦Pigment Blue 19, C.I. 42 750A 

♦Pigment Blue 22, C.I. 69 810 

Pigment Blue 25, C.I. 21 180 

(Basic Blue 7), C.I. 42 595, PTA 

(Vat Blue 4), C.I. 69 800 

(Vat Blue 6), C.I. 69 825 

(Vat Blue 14), C.I. 69 810 

All other 

♦Green toners: 

Pigment Green 1, C.I. 42 040, fugitive 

♦Pigment Green 1, C.I. 42 040, PMA 

♦Pigment Green 1, C.I. 42 040, PTA 

♦Pigment Green 2, C.I. 42 040 and 49 005, PMA- 
♦Pigment Green 2, C.I. 42 040 and 49 005, PTA- 

Pigment Green 4, C.I. 42 000, fugitive 

♦Pigment Green 4, C.I. 42 000, PMA 

♦Pigment Green 4, C.I. 42 000, PTA 

♦Pigment Green 7, C.I. 74 260 

♦Pigment Green 8, C.I. 10 006 

Pigment Green 10, C.I. 12 775 

Pigment Green 36 

Pigment Green 38 

All other 

♦Brown toners : 

Pigment Brown 1, C.I. 12 480 

Pigment Brown 2, C.I. 12 071 

Pigment Brown 3, C.I. 21 010, PMA 

♦Pigment Brown 5, C.I. 15 800 

(Vat Brown 3), C.I. 69 015 

All other 

♦Black toners: 

Pigment Black 1 

Pigment Black 7, C.I. 77 266 

All other 

LAKES 

Yellow lakes: 

(Acid Yellow 1), C.I. 10 316 

(Acid Yellow 3), C.I. 47 005 

(Acid Yellow 11), C.I. 18 820 

(Acid Yellow 23), C.I. 19 140 



Manufacturers ' identification codes 
(according to list in table 22) 



DUP, ICI, NAC. 

NAC. 

NAC. 

ACY, G, ICC, IMP, ROM. 

BLN, DUP, EAK, FCL, G, HSC, IMP, K0N, LVR, LVY, MGR, 

MRX, NYC, SDH, SNA, SW, UHL. 
AMS, G, HAM, IMP, MGR, NAC, SNA, SW, UHL. 
BLN. 

G, IMP, LVR. 
G, HAM. 
MGR. 
G. 

MRX, NYC, UHL. 
BLN, G, IMP, MGR, MRX, SDH. 
IMP, SDH. 
IMP. 

DUP, G, IMP, NYC. 
DUP, G, NYC. 
ACY, DUP, FCL, G, HSC, ICC, ICI, IMP, NAC, SNA, SW, 

TMS, TRC. 
ACY, AMS, DUP, FCL, HSC, IMP, LVY, NAC, SNA, SW, TMS. 
ACY, AMS, HSC, NYC, SW. 
DUP, IMP, TRC. 
DUP, G, ICC, NAC. 
DUP. 
G. 

ICI, TRC. 
NAC. 
G, IMP, MGR, SDH. 



BLN, G, IMP, MGR, MRX, NYC, UHL. 

BLN, IMP, K0N, S, SDH, SNA. 

G, IMP, LVY, MGR, MRX, SDH, UHL. 

ACY, AMS, BLN, DUP, IMP, K0N, LVY, MGR, MRX, S, SDH, 

UHL. 
BLN, G, MGR. 
BLN, G, MGR. 
ACY, AMS, HAM, IMP. 
ACY, DUP, FCL, G, HSC, ICC, IMP, NAC, SNA, SW, TMS, 

TRC. 
DUP, G, HSH, IMP, KCW, LVY, SW. 
DUP, HSC, IMP, SW. 
ACY, G. 
NAC. 
ACY, G, SNA. 

ICI. 

SDH. 

BLN, KCW. 

BUC, HSH, ICC, NAC, ROM, SNA. 

G, NAC, TRC. 

G, ICC, SDH, SW. 

SNA. 
G. 



BLN, DUP, G, MGR, UHL. 



IMP. 
IMP. 
KON. 
KON, MRX. 



See note at end of table for definition of abbreviations. 



PIGMENTS 



115 



TABLE 11B. 



■ Benzenoid pigments for which U.S. production or sales were reported, identified 
by manufacturer , 1965 — Continued 



Pigment 


Manufacturers ' identification codes 
(according to list in table 22) 


LAKES— Continued 

Orange lakes: 

Pigment Orange 17, C.I. 15 510 

All other 

*Red lakes: 

♦Pigment Red 60, C.I. 16 105 

♦Pigment Red 83, C.I. 58 000 

(Acid Red 17), C.I. 16 180 

(Acid Red 25), C.I. 16 050 

♦ (Acid Red 26), C.I. 16 150 

(Acid Red 27) 

(Natural Red 4), C.I. 75 470 

All other 

*Violet lakes: 

♦Pigment Violet 5, C.I. 58 055 

Pigment Violet 20, C.I. 58 225 

(Acid Violet 17), C.I. 42 650 

♦Blue lakes: 

Pigment Blue 17, C.I. 74 180 

♦Pigment Blue 24, C.I. 42 090 

(Acid Blue 93), C.I. 42 780 

(Acid Blue 104), C.I. 42 735 

Green lakes: (Acid Green 3), C.I. 42 085 

Brown lakes 

Black lakes: 
♦(Natural Black 3), C.I. 75 291 


CIK, CPC, IMP, KCW, MGR. 
APC, HAM. 

BLN, DUP, HSC, HSH, K0N, MRX, SNA, SW. 

HSH, IMP, KON, MRX, SW, UHL. 

IMP, KCW. 

KON. 

CPC, EAK, HAM, IMP, KCW. 

KON. 

KON. 

APC, G, HAM, IMP. 

BLN, DUP, HSH, IMP, NAC. 

SW. 

BLN. 

HAM, HSC. 

BLN, CPC. 

AMS, BLN, ICC, KON, LVY, MGR, SDH. 

LVR. 

CPC, KCW. 

BLN, CPC. 

HAM, KON. 

CPC, KON, NYC. 
HAM. 



Note. — The C.I. (Colour Index) numbers shown in this report are the identifying codes given in the second edition 
of the Colour Index. 

When the name of a color is enclosed in parentheses, it indicates that this name is that of the dye from which the 
pigment can be made and that no name for the pigment itself is given in the Colour Index. 

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic ) 
acids, respectively. 



116 



SYNTHETIC ORGANIC CHEMICALS, 1965 



Medicinal Chemicals 

TABLE 13B. —Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1965 

[Medicinal chemicals for which separate statistics are given in table 13A in pt. II are marked below with an asterisk 
(*); medicinal chemicals not so marked do not appear in table 13A because the reported data are accepted in con- 
fidence and may not be published. Manufacturers ' identification codes shown below are taken from table 22. An x 
signifies that the man ufacturer did not consent to his identification with the designated product] 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



* Antibiotics : 

*For medicinal use: 

*Antifungal and antitubercular antibiotics 
Antifungal antibiotics : 

Amphotericin B 

Candicidin 

Nystatin 

Antitubercular antibiotics : 

Cycloserine 

Dihydrostreptomycin 

^Streptomycin 

Viomycin 

*Bacitracin 

*Penicillins : 

Ampicillin 

Cloxacillln, sodium 

Methicillin, sodium 

Nafcillin, sodium 

Oxacillin, sodium 

Penicillin G, benzathine 

^Penicillin G, potassium 

*Penicillin G, procaine 

Penicillin G, sodium 

Phenethicillln, potassium 

Phenoxymethylpenicill in (Penicillin V) — 

Phenoxymethylpenicil 1 in, benzathine 

Phenoxymethylpenicillln, hydrabamine 

Phenoxymethylpenicillin, potassium 

*Other antibiotics for medicinal use: 

Cephalothin 

Chloramphenicol 

Erythromycin 

Fumagillin 

Gentamycin 

Gramicidin 

Kanamycin 

Lincomycin 

Neomycin 

Novobiocin 

Oleandomycin 

Paromomycin 

Polymyxin B 

Ristocetin 

Tetracyclines : 

Chlortetracycline 

Demethylchlortetracycline 

Oxytetracycline 

Tetracycline 

Thiostrepton 

Triacetyloleandomyciii 

Tyrothricin 

*For other uses: 

^Bacitracin 

Chlortetracycline 

Cycloheximide 

Ifygromycin B 

Neomycin 

Novobiocin 

Oxytetracycline 

^Penicillin G, procaine, 

Streptomycin 1 

Tylosin 



PEN. 










OMS. 










COM. 










MRK, 


OMS, 


PFZ. 






LIL, 


MRK, 


OMS, 


PFZ. 




PFZ. 










COM, 


PEN, 


PFZ, 


PMP. 




BRS. 










BRS. 










WYT. 










BRS. 










PFZ, 


WYT. 








LIL, 


MRK, 


OMS, 


PFZ, 


WYT 


LIL, 


MRK, 


OMS, 


PFZ, 


WYT 


MRK, 


OMS, 


PFZ. 






BRS, 


PFZ, 


WYT. 






LIL. 










WYT. 










ABB. 










ABB, 


LIL. 









SCH. 

BAX, 

BRS. 

x. 

OMS, 

MRK, 

PFZ. 

MRK. 

PFZ. 

ABB. 

ACY. 
ACY. 
PFZ. 
ACY, 
OMS. 
PFZ. 
BAX, 

COM, 
ACY. 
UP J. 
LIL. 
PFZ. 
UP J. 
PFZ. 
LIL, 
MRK, 
LIL. 



PEN, PFZ, UP J. 
UP J. 



BRS, PFZ, RLS. 

PEN. 

GPR, PEN, PMP. 



MRK, OMS, PFZ, WYT. 
PFZ. 



MEDICINAL CHEMICALS 



117 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1965 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



♦Antihistamines : 
*Antinauseants : 

Cyclizine hydrochloride 

Dimehhydrinate 

Meclizine hydrochloride 

Trimethobenzamide hydrochloride 

Bromodiphenhydramine hydrochloride 

Brompheniramine maleate 

Carbinoxamine maleate 

Chlorcyclizine hydrochloride 

♦Chlorpheniramine maleate 

Cyproheptadine hydrochloride 

Dexbrompheniramine maleate 

Dexchlorpheniramine maleate 

Dimethindene maleate 

Diphenhydramine hydrochloride 

Doxylamine succinate 

Methapyrilene fumarate 

Methapyrilene hydrochloride 

Methapyrilene hydroxybenzoylbenzoate 

Phenindamine tartrate 

♦Pheniramine maleate 

Phenyltoloxamine citrate 

♦Pyrilamine maleate 

Pyrrobutamine phosphate 

Eotoxamine (levo- Carbinoxamine) tartrate 

Thenyldiamine hydrochloride 

Thonzylamine hydrochloride 

Tripelennamine 

Tripelennamine citrate 

Tripelennamine hydrochloride 

Triprolidine hydrochloride 

♦Anti-infective agents (except antibiotics): 
♦Antimony, arsenic, and bismuth compounds: 

Arsanilic acid 

Bismuth dipropylacetate 

Bismuth sodium triglycollamate 

Bismuth subsalicylate 

Carbarsone 

Glycobiarsol 

Ni tars one 

Roxarsone 

Roxarsone, sodium 

Sodium arsanilate 

*Cetylpyridinium chloride 

♦Mercury compounds : 

o-Hydroxyphenylmercuric chloride 

Merbromin 

Mercuric salicylate 

Nitromersol 

Phenylmereuric acetate 

Phenylmercuric benzoate 

Phenylmereuric borate 

Phenylmercuric chloride 

Phenylmercuric nitrate 

Thimerosal 

♦5-Nitrofurane, -imidazole, and -thiazole derivatives: 

Acinitrazole 

2-Amino-5-nitrothiazole 

Furazolidone 

Metronidazole 

Nihydrazone 

Ni thiazide 

Nitrofurantoin 

Nitrofura thiazide 

Nitrofurazone 

♦Phenolic antiseptics and disinfectants: 

Betanaphthol 

Bithionol 

Resorcinol 

Thymol 

Thymol iodide 



BUR. 

SRL. 

PFZ. 

HOF. 

PD. 

SCH. 

SCH. 

ABB, 

HEX, 

MRK. 

SCH. 

SCH. 

CBP. 

ARA, 

BKC. 

ABB. 

ABB. 

LIL. 

HOF. 

HEX, 

BRS. 

BKL, 

LIL. 

SCH. 

SDW. 

NEP. 

CBP. 

CBP. 

CBP. 

BUR. 



BUR. 

LEM, SCH, SK, x. 



GAN, PD. 



LEM, SCH, x. 

HEX, MRK, PYL, RSA. 



MAL, 


NOR, 


PEN. 




LIL, 


PYL, 


RSA, 


WHL. 


SDW. 








SAL. 








SAL. 








SAL. 








SAL, 


WHL. 






BKL, 


FIN, 


GAN, 


HEX, NEP 


MRK. 








HYN. 








MAL, 


MRK. 






ABB. 








WRC. 








MRK, 


WRC. 






MRK, 


WRC. 






MRK. 








MRK, 


WRC. 






LIL, 


PYL, 


SEL. 




ACY. 








ACY. 








NOR. 








RDA. 








NOR. 








MRK. 








NOR. 








SCH. 








NOR. 








ACY, 


FIN. 






SDH. 








KPT, 


LEM. 






GIV. 








MAL. 









118 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 13B. 



■ Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



*Anti-infective agents (except antibiotics) — Continued 
*Piperazine base and salts : 

*Piperazine 

Piperazine adipate 

Piperazine calcium edetate 

Piperazine citrate 

Piperazine dihydrochloride 

Piperazine hexabydrate 

Piperazine hydrochloride 

Piperazine phosphate 

Piperazine sulfate 

Piperazine tartrate 

*Quinoline derivatives: 

Amodiaquin 

Amodiaquin hydrochloride 

Chloroquine phosphate 

*Diiodohydroxyquin 

Hydroxychloroquine sulfate 

8-Hydroxy-5-quinolinesulfonic acid 

Iodochlorhydroxyquin 

Qxyquinoline 

Oxyquinoline benzoate 

Qxyquinoline citrate 

Qxyquinoline potassium sulfate 

Qxyquinoline sulfate 

Primaquine phosphate 

^Sulfonamides : 

Acetyl sulfamethoxypyridazine ' 

Acetyl sulfisoxazole 

Azosulf amide . 

Dinsed 

Mafenide hydrochloride 

Phthalylsulfacetamide 

Phthalylsulfathiazole 

Succinylsulfathiazole 

Sulfabenz 

Sulfabenzamide 

Sulfabenzamide, sodium 

Sulfabromomethazine, sodium 

Sulfacetamide 

Sulfacetamide, sodium 

Sulfadiazine 

Sulfadiazine, sodium 

Sulfadimethoxine 

Sulfaethidole 

Sulfaguanidine 

Sulfamerazine 

Sulfamerazine, sodium 

Sulfamethazine 

Sulfamethizole 

Sulfamethoxazole 

Sulfamethoxypyridazine 

Sulfanilamide 

Sulfanitran • 

Sulfapyridine 

Sulf apy ridine , sodium 

Sulfaquinoxaline 

*Sulfathiazole 

Sulfathiazole, sodium 

Sulfisoxazole 

*Other anti-infective agents : 

*Anthelmintic, antifungal, antiprotozoan, and 
antiviral agents : 
Anthelmintic agents : 

Cadium anthranilate 

Diethylcarbamazine citrate 

Gentian violet 

Hexylresorcinol 

Phenothiazine 

Pyrvinium pamoate 

Thiabendazole 



DOW, 


JCC, 


UCC. 




JCC, 


PYL, 


RDA. 




EN. 








BUR, 


JCC, 


RDA. 




DOW, 


JCC, 


RDA, 


WHL. 


JCC, 


RDA. 






DOW, 


JCC, 


RDA. 




BUR, 


JCC, 


PYL, 


RDA, WHL 


JCC, 


RDA. 






RDA. 








PD. 








PD. 








SDW. 








LEM, 


PYL, 


RSA, 


SRL. 


SDW. 








GAM, 


MRK. 






CBP, 


PYL. 






GAM, 


LEM, 


MRK. 




GAM, 


LEM, 


MRK. 




GAM. 








LEM. 








GAM, 


LEM, 


MRK, 


PYL. 


PD, 


SDW. 






ACY. 








HOF. 








SDW. 








SAL. 








SDW. 








LEM. 








MRK. 








LEM, 


MRK. 






SAL. 








ACY. 








ACY. 








MRK. 








LEM. 








LEM, 


SCH. 






ACY, 


LEM. 






ACY. 








HOF. 








ACY. 








ACY, 


LEM. 






ACY, 


LEM. 






ACY. 








ACY, 


LEM. 






ACY. 








HOF. 








ACY. 








LEM, 


MRK. 






SAL. 








ACY, 


MRK. 






ACY. 








MRK. 








ACY, 


LEM, 


MRK. 




ACY, 


MRK. 






HOF. 









MAL. 

ACY. 

NAC, SDH. 

HEX, MRK. 

CLV. 

x. 

MRK. 



MEDICINAL CHEMICALS 

TABLE 13B.-- Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



1)9 



Manufacturers ' identification codes 
(according to list in table 22) 



*Anti-ihfective agents (except antibiotics) --Continued 
*Other anti-infective agents — Continued 

*Anthelmintic , antifungal, antiprotozoal and 
antiviral agents — Continued 
Antifungal agents : 

Benzoic acid 

Calcium undecylenate 

Diamthazole hydrochloride 

Fuchsin, basic 

p-Hydroxybenzoic acid esters : 

Butylparaben 

Ethylparaben 

Methylparaben 

Propylparaben 

Salicylanilide 

Sodium eaprylate 

Sodium undecylenate 

Undecylenic acid 

Zinc undecylenate 

Antiprotozoan agents : 

Aklomide 

Amprolium 

Nitrophenide 

Pyrimethamine 

Antiviral agent: Amantadine hydrochloride 

*Urinary antiseptics : 

Ammonium benzoate 

Calcium mandelate 

Ethoxazene hydrochloride 

Mandelic acid 

Methenamine 

Methenamine acetamidosalicylate 

Mathenamine mandelate 

Methylene blue 

Phenazopyridine hydrochloride 

*A11 other: 

Acriflavine ^ 

Acriviolet 

Aminacrine 

Aminacrine hydrochloride 

Antileprotic and antitubercular agents : 

Aminosalicylic acid 

Calcium aminosalicylate 

Isoniazid 

Potassium aminosalicylate 

Pyrazinamide 

Sodium aminosalicylate 

Sodium sulfoxone 

Benzalkonium chloride 

Bromoform 

Camphor, monobromated 

Cetalkonium chloride 

Chloramine T 

Chlorobutanol 

Iodoform 

Magnesium salicylate 

Nalidixic acid 

Nitromide 

Povidone - iodine complex 

*Antineoplastic agents and local anesthetics : 
Antineoplastic agents : 

Mercaptopurine 

Ure thane 

Vinblastine sulfate 

Vincristine sulfate 

Local anesthetics : 

Butacaine sulfate 

Butamben picrate 

Butyl aminobenzoate (Butamben) 

Dibucaine 

Dibucaine hydrochloride 



MON, 


PFZ. 


WTL. 




HOF. 




NAC. 




HN, 


ICO. 


HN. 




HN, 


ECO, LEM, PYL. 


HN, 


ICO, LEM, PYL. 


LEM. 




LEM, 


TNC. 


BAC. 




BAC. 




BAC, 


LEM, TNC, WTL. 


SAL. 




MRK. 




ACY. 




BUR. 




x. 




GAM, 


PEN. 


MAL. 




KON. 




MAL. 




HN. 




ABB. 




LEM, 


NEP, PYL, TNC 


ACY, 


NAC. 


HOF, 


KON, NEP. 


NAC. 




NAC. 




SDW. 




SDW. 




MLS. 




MLS. 




RIL. 




MLS. 




MRK. 




MLS. 




ABB. 




SDH. 




DOW. 




MAL, 


PEN. 


FIN, 


SDW. 


MON. 




BPC, 


PD. 


MAL, 


PEN. 


MAL. 




SDH, 


SDW. 


SAL. 




C-. 




BUR. 




BKL, 


FMP. 


LIL. 




LIL. 




ABB. 




ABB. 




ABB, 


ICO. 


CBP. 




CBP. 





SYNIHkllC ORGANIC CHEMICALS, 1965 



TABLE 13B. —Medicinal chemicals for which U.S. production or sales were reported identified bv 

manufacturer, 1 965— Continued 



"Antineoplastic agents and local anesthetics— Continued 
Local anesthetics — Continued 

Ethyl aminobenzoate (Benzocaine) 

Isobutyl aminohenzoate 

Lidocaine 

Oxethazaine 

Phenacaine hydrochloride 

Piperocaine hydrochloride 

Pramoxine hydrochloride 

Procaine 

Procaine hydrochloride 

Proparacaine hydrochloride 

Propyl aminohenzoate 

Pyrrocaine hydrochloride 

Tetracaine 

Tetracaine hydrochloride 

"Autonomic drugs : 

Ganglionic blocking agent: Tetraethylammonium chloride— 
Parasympatholytic (anticholinergic) agents: 
"Quaternary ammonium compounds (except tropane 
derivatives) : 

Ambutonium bromide 

Diphemanil methylsulfate 

Hexocyclium methylsulfate 

Isopropamide iodide 

Mepenzolate bromide 

Methantheline bromide 

Pipenzolate bromide 

Pralidoxime chloride 

Propantheline bromide 

Thihexinol methylbromide 

Tridihexethyl iodide • 

"Tertiary amines (except tropane derivatives): 

Adiphenine hydrochloride 

Caramiphen edisylate 

Cycrimine hydrochloride 

Dicyclomine hydrochloride 

Ethopropazine 

Orphenadrine citrate 

Orphenadrine hydrochloride 

Oxyphencyclimine hydrochloride 

Piperidolate hydrochloride 

Thiphenamil hydrochloride 

Trihexyphenidyl hydrochloride 

Tropane derivatives : 

Anisotropine methylbromide 

Benztropine mesylate 

Homatropine 

Homatropine hydrobromide 

Homatropine methylbromide 

Parasympathomimetic (cholinergic) agents: 

Acetylcholine chloride 

Methacholine chloride 

Neostigmine bromide 

Physostigmine salicylate ; 

Pyridostigmine bromide 

Sympatholytic (antiadrenergic) agents: 

Ergonovine maleate 

Hydralazine hydrochloride 

Tolazoline hydrochloride 

"Sympathomimetic (adrenergic) agents: 

Adrenalone 

Arterenol hydrochloride (racemic) 

Cinnamylephedrine 

Cyclopentamine hydrochloride 

"Epinephrine salts : 

Epinephrine bitartrate (levo) 

Epinephrine hydrochloride (racemic) 

"Isoproterenol salts : 

Isoproterenol hydrochloride 

Isoproterenol sulfate 



Manufacturers ' identification codes 
(according to list in table 22) 



ABB, LEM. 

ICO. 

AST, LEM. 

WYT. 

CAN, SDW. 

LIL. 

ABB. 

ABB. 

ABB, LEM. 

QMS. 

ICO. 

EN. 

SDW. 

ICO, SDW. 



ICO. 

SCH. 

ABB. 

SK. 

LKL. 

SRL. 

LKL. 

NEP. 

SRL. 

SCH. 

ACY. 

CBP. 

SK. 

LIL. 

BKC. 

NEP. 

RIK. 

RIK. 

PFZ. 

LKL. 

x. 

ACY, SDW. 



CTN, HEX. 

CTN. 

CTN, EN, HEX. 

MRK. 

MRK, RSA. 
HEX. 
PEN. 
HOF. 

LIL. 
CBP. 

CTN. 

SDW. 
SDW. 
SDW. 
LIL. 

SDW. 
DOD, VB. 

GAN, SDW. 
ABB, GAN, SDW. 



MEDICINAL CHEMICALS 



121 



TABLE 13B — Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i565--Continued 



Manufacturers' identification codes 
(according to list in table 22) 



"Autonomic drugs — Continued 

"Sympathomimetic (adrenergic) agents — Continued 

Levarterenol bi tartrate 

dl-Metanephrine hydrochloride 

Metaraminol bitartrate 

Methoxyphenamine hydrochloride 

Naphazoline hydrochloride 

dl-Nonnetanephrine hydrochloride 

Nylidrin hydrochloride 

"Phenylephrine base and salts : 

Phenylephrine 

Phenylephrine bitartrate 

"Phenylephrine hydrochloride 

Phenylephrine tannate 

"Phenylpropanolamine hydrochloride 

Propylhexedrine 

Protokylol hydrochloride 

Pseudoephedrine hydrochloride 

Pseudoephedrine sulfate 

Tetrahydrozoline hydrochloride 

"Cardiovascular agents : 
Antihypertensive agents : 

Alkavervir 

Alseroxylon 

Deserpidine 

Methyldopa 

Pargyline hydrochloride 

Reserpine 

Bioflavonoids : 

Hesperidin 

Hesperidin methyl chalcone 

Lemon bioflavonoid 

Naringin 

Rutin 

Cardiac drugs: 

Calcium camphor sulfonate 

Digi toxin 

Procainamide hydrochloride 

Quinidine gluconate 

"Vasodilators : 

Clonitrate 

Dioxyline phosphate 

Ethyl nitrite 

Isosorbide dinitrate 

Mannitol hexanitrate 

Nicotinyl alcohol tartrate 

Nitroglycerin 

Pentaerythritol tetranitrate 

"Central depressants : 

"Analgesics and antipyretics: 
"Salicylates : 

Aluminum aspirin 

"Aspirin 

Ethyl salicylate carbonate 

Phenyl salicylate 

Potassium salicylate 

Salicylamide 

Salicylsalicylic acid 

Sodium salicylate 

Strontium salicylate 

"Other analgesics and antipyretics : 

Acetaminophen 

Acetanilide 

p-Aminobenzoic acid and salts: 

Aminobenzoic acid 

Calcium aminobenzoate 

Magnesium aminobenzoate 

Potassium aminobenzoate 

Sodium aminobenzoate 

Anileridine hydrochloride 

Calcium succinate 

Colchicine 



SDW. 






SDW. 






SDW. 






X. 






CBP, SDW. 






SDW. 






X. 






CTN, GAN, 


SDW. 




GAN. 






CTN, GAN, 


HEX, 


SDW. 


CTN. 






BKL, GAM, 


GAN, 


ICO, NEP, ORT 


HEX, SK. 






LKL. 






BUR, GAN. 






GAN. 






PFZ. 






PEN, RIK. 






RIK. 






PEN. 






MRK. 






ABB. 






PEN. 






SKG. 






SKG. 






SKG. 






SKG. 






PEN. 






FIN, PYL. 






BUR. 






OMS. 






HEX. 






APD. 






LIL. 






MAL. 






APD. 






APD. 






HOF. 






APD. 






APD. 






ABB, SCH. 






CFC, DOW, 


MLS, 


MON, NOR, SDG. 


PD. 






DOW, MAL. 






HN, PEN. 






CFC, x. 






TNC. 






DOW, HN. 






MAL, TNC. 






ATP, MLS, 


NEP, 


X. 


CTN. 






LEM. 






LEM, x. 






LEM. 






GAN, LEM. 






GAN, LEM. 






MRK. 






LEM. 






PEN. 







122 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 13B. 



-Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



Manuf aoturers ' identification codes 
(according to list in table 22) 



^Central depressants — Continued 
^Analgesics and antipyretics — Continued 

Other analgesics and antipyretics — Continued 

Dipyrone 

Ethoheptazine citrate 

Meperidine hydrochloride 

Oxycodone hydrochloride 

Oxymorphone hydrochloride 

Oxyphenbutazone 

Phenacetin 

Phenylbutazone 

1-Phenylsemicarbazide 

Phenyramidol hydrochloride 

Propoxyphene hydrochloride 

Propoxyphene napsylate 

* Anticonvulsants , hypnotics, and sedatives: 
Anticonvulsants (except barbiturates) : 

Aminoglutethimide 

Diphenylhydantoin 

Diphenylhydantoin, sodium 

Ethosuximide 

Ethotoin 

Methsuximide 

Paramethadione 

Phenacemide 

Phensuximide 

Trimethadione 

*Barbiturates : 

5-Allyl-5-(2-cyclopenten-l-yl)barbituric acid 

Amobarbital 

Amobarbital, sodium 

Barbital 

Barbital, sodium 

*Butabarbital 

*Butabarbital, sodium 

Butalbital 

Butalbital, sodium 

Cyclobarbital, calcium 

Hexobarbital 

Mephobarbital 

Methohexital, sodium 

Pentobarbital 

Pentobarbital, sodium 

Phenobarbital 

*Phenobarbital, sodium 

Secobarbital 

Secobarbital, sodium 

Talbutal 

Thiamylal, sodium 

Thiopental, sodium 

Vinbarbital 

Hypnotics and sedatives (except barbiturates): 

Acetylcarbromal 

Carbromal 

Ethchlorvynol 

Ethinamate 

Glutethimide 

Methyprylon 

*Skeletal muscle relaxants : 

Carisoprodol 

Chlorphenesin carbamate 

Chlorzoxazone 

*Mephenesin 

Mephenesin carbamate 

Phenaglycodol 

Styramate 

*Succinylcholine chloride 

Tubocurarine 

^Tranquilizers : 

Azacyclonol hydrochloride 

Buclizine hydrochloride 

Chlordiazepoxide hydrochloride 



SDW. 

WYT. 

SDW, 

EN. 

EN. 

GGY. 

DOW, 

GGY. 

RSA. 

OTC. 

LIL. 

LIL. 



CBP. 
PD. 



ABB. 

PD. 

ABB. 



GAN. 

LIL. 

GAN, 

GAN. 

GAN. 

ABB, 

ABB, 

GAN. 

GAN. 

SDW. 

GAN, 

SDW. 

LIL. 

ABB, 

ABB, 

BPC, 

BPC, 

GAN. 

GAN, 

SDW. 

PD. 

ABB. 



MLS. 
MLS, 
ABB. 
LIL. 
CBP. 
HOF. 



UPJ. 
OTC. 
BKL, 
OMS. 
LIL. 
AEP. 
ABB, 
ABB, 

BKC. 
PFZ. 
HOF. 



BPC, GAN. 
BPC, GAN. 



BPC, GAN. 
BPC, GAN. 
GAN, MAL. 
GAN, MAL, SDW. 

LIL. 



HEX, OMS. 



BUR, SDW. 
OMS. 



MEDICINAL CHEMICALS 



123 



TABLE 13B. 



-Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1 965- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



♦Central depressants — Continued 
♦Tranquilizers — Continued 

Chlormezanone 

Chlorprothixene 

Diazepam 

Ethoxybutamoxane hydrochloride 

Hydroxyphenamate 

Hydroxyzine hydrochloride 

Hydroxyzine pamoate 

Mebutamate 

Mephenoxalone 

♦Meprobamate 

Methaqualone 

Oxazepam 

*Phenothiazine derivatives : 

Carphenazine maleate 

Chlorpromazine hydrochloride 

Fluphenazine hydrochloride 

Mepazine hydrochloride 

Perphenazine 

Prochlorperazine maleate 

Promazine hydrochloride 

Promethazine hydrochloride 

Trifluoperazine hydrochloride 

Triflupromazine hydrochloride 

Tybamate 

*Other central depressants : 
Anesthetics : 

Tribromoethanol 

Vinyl ether 

Antitussives: 

Benzonatate 

Carbetapentane citrate 

Dextromethorphan hydrobromide 

Dimethoxanate hydrochloride 

*Ethylmorphine hydrochloride 

Hydrocodone bitartrate 

♦Central stimulants : 
* Amphetamines : 

♦Amphetamine, dextroamphetamine and levamphetamine 
base and salts : 

Amphetamine (racemic) 

Amphetamine hydrochloride (racemic) 

Amphetamine sulfate (racemic) 

Dextroamphetamine 

Dextroamphetamine carboxymethylcellulose 

Dextroamphetamine hydrochloride 

♦Dextroamphetamine sulfate 

Dextroamphetamine tannate 

Levamphetamine succinate 

♦Methamphetamine base and hydrochloride: 

Methamphetamine (dextro) 

Methamphetamine (levo) 

♦Methamphetamine (racemic) 

♦Methamphetamine hydrochloride (dextro) 

Methamphetamine hydrochloride (racemic) 

♦Antidepressants : 

Amitriptyline 

Desipramine hydrochloride 

Isocarboxazid 

Nialamide 

Nortriptyline 

Phenelzine sulfate 

♦Caffeine : 

Natural 

Synthetic 

♦Other central stimulants: 

Benzphetamine hydrochloride 

Caffeine, citrated 

Caffeine sodium benzoate 

Chlorphentermine hydrochloride 

Diethylpropion hydrochloride 



SDW. 

HOF. 

HOF. 

LIL. 

ARP. 

PFZ. 

PFZ. 

x. 

ACY. 

ABB, BKL, PEN, TBK. 

HEX, x. 

WYT. 

WYT. 

SK. 

0M3, SCH. 

NEP. 

SCH. 

SK. 

WYT. 

WYT. 

SK. 

CMS. 

PEN, x. 



SDW. 
MRK. 

CBP. 
PFZ. 
HOF. 
x. 

MAL, MRK, PEN. 
EN, MAL, MRK. 



HEX, 


ORT. 




HEX. 






AM, 


HEX, 


SK. 


HEX. 






ARN. 






ARN, 


HEX. 




ARN, 


HEX, 


SK. 


ARN. 






ARN. 






HEX. 






ABB. 






ARN, 


HEX, 


OTC. 


ABB, 


ARN, 


GAN, HEX 


ARN, 


CAN, 


HEX. 


MRK. 






GGY, 


LKL. 




HOF. 






PFZ. 






LIL. 






NEP. 






GNF, 


MYW. 




MON, 


PFZ. 




x. 






MAL, 


MRK. 




MAL. 






NEP. 






BKC, 


x. 





124 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer , 1965 — Continued 



Manuf aeturers ' identification codes 
(according to list in table 22) 



*Central stimulants — Continued 

"Other central stimulants — Continued 

Nikethamide 

Phendimetrazine tartrate 

Phenmetrazine hydrochloride 

Phentermine 

Sodium succinate 

"Dermatological agents : 

"Allantoin 

"Bismuth subgallate 

*Salicylic acid 

■"Other dermatological agents : 

Aluminum phenolsulfonate 

Ammonium phenolsulfonate 

Dipropylene glycol salicylate 

Glycol salicylate 

Homomenthyl salicylate 

p-Methoxycinnamie acid, 2-ethoxyethyl ester 

Podophyllum resin 

Scarlet red 

Sodium phenolsulfonate 

Zinc phenolsulfonate 

■"■Expectorants and mucolytic agents: 

Ethylenediamine dihydriodide 

Glyceryl guaiacolate 

Guaiacol 

Iodinated glycerol 

Lobeline sulfate 

Terpin hydrate 

Thonzonium bromide 

"Gastrointestinal agents : 

"Choleretics and hydrocholeretics : 

Bile acids, oxidized 

Dehydrocholic acid 

Florantyrone 

Iron bile salts 

Qx bile extract 

Sodium dehydrocholate 

Tocamphyl 

"Choline chloride (all grades): 

Feed grade 

Medicinal grade 

Technical grade 

"Methionine and its hydroxy analogue : 

Methionine (feed grade) 

Methionine (medicinal grade) 

Methionine, hydroxy analogue, calcium salt-- 
"Other gastrointestinal agents : 

Betaine base 

Betaine hydrate 

Betaine hydrochloride 

Calcium polycarbophil 

Choline bicarbonate 

Choline bi tartrate 

Choline citrate (Tricholine citrate) 

Choline dihydrogen citrate 

Dihydroxy aluminum aminoacetate 

Magnesium citrate 

Pectin 

Phenolphthalein 

Phenolphthalein, yellow 

Sitosterols 

Sodium carboxymethylcellulose 

Sodium tartrate 

"Hormones and synthetic substitutes : 
"Corticosteroids : 

Betamethasone 

Betamethasone acetate 

Betamethasone phosphate 

Cortisone 

Cortisone acetate 

Dexamethasone 



GGY. 




HEX. 




MAL. 




CTN, 


FIN, HFT. 


BKC, 


MAL, PEN. 


DOW, 


HN, M)N, SDH. 


MAL. 




SAL. 




SBC. 




RDA. 




ICO. 




GIV. 




ABB, 


PEN. 


NAC. 




MAL, 


SAL. 


MAL. 




BKC, 


PYL, WHL. 


BKL, 


GAM, ICO, OTC, x 


HN, 


M)N. 


X, X 




ABB. 




LEM, 


PEN. 


NEP. 




SRL, 


WIL. 


WIL. 




SRL. 




LIL. 





COM, 


DLI, 


HFT, TMH 


CFC, 


HFT. 




G, RH. 




DOW. 






DOW, 


LEM. 




DUP, 


MON. 




HFT, 


MAL. 




HFT. 






HFT. 






WLI. 






COM. 






ACY, 


CFC, 


HFT. 


ACY, 


CFC, 


HFT. 


ACY, 


CFC, 


HFT. 


CHT. 






MAL. 






SKG- 






MON. 






WLI. 






UPJ. 






CBP. 






MAL. 






SCH. 






SCH. 






SCH. 






MRK. 






MRK, 


SCH, 


UPJ. 


MRK, 


SCH. 





MEDICINAL CHEMICALS 



125 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1965 — Continued 






Hormones and synthetic substitutes — Continued 
* Corticosteroids — Continued 

Dexamethasone acetate 

Dexamethasone phosphate 

Dichlorisone acetate 

Fludrocortisone acetate 

Fluorometholone 

Fluprednisolone 

Hydrocortamate hydrochloride 

^Hydrocortisone 

Hydrocortisone acetate 

Hydrocortisone phosphate 

Indomethacin 

Methylprednisolone 

Prednisolone 

Prednisolone acetate 

Prednisone 

Triamcinolone 

*Estr:>gens: 

ChLorotrianisene 

Dienestrol diacetate 

Diethylstilbestrol 

Natural estrogenic substances 

Piperazine estrone sulfate 

*Synthetic hypoglycemic agents : 

Aeetohexamide 

Chlorpropamide 

Phenformin hydrochloride 

Tolazamide 

Tolbutamide 

«Othef hormones and synthetic substitutes: 
Androgens : 

Fluoxymesterone 

Testosterone cypionate 

Antithyroid agents : 

Jfetliimazole 

Propylthiouracil 

Thiouracil 

Progestogens : 

Medroxyprogesterone acetate 

Norethynodrel 

Progesterone 

All other: 

Corticotropin (ACTH) (pituitary) 

Insulin (pancreas) 

*Renal-acting and edema-reducing agents : 
*Mercurial diuretics: 

Meralluride 

Mersalyl acid 

Sodium mercaptomerin 

Sodium mercurophylline 

^Theobromine and theophylline derivatives : 

Ambuphylline 

*Aminophylline 

Aminophylline sodium biphosphate 

Oxtriphylline 

Theobromine sodium salicylate 

Theophylline magnesium 

Theophylline monoethanolamine 

Theophylline sodium acetate 

*Other renal-acting and edema-reducing agents : 

Acetazolamide 

Benzothiadiazine derivatives : 

Bendroflumethiazide 

Benzthiazide 

Chlorothiazide 

Cyclothiazide 

Flumethiazide 

Hydrochlorothiazide 

Hydroflumethiazide 



Manufacturers ' identification codes 
(according to list in table 22) 



SCH. 
MRK. 
SCH. 
UP J. 
UP J. 
UP J. 
PFZ. 
MRK, 
MRK, 
MRK. 
MRK. 
UPJ. 
MRK, 
SCH, 
MRK, 
ACY, 

BKC. 
SCH. 
CTN, 
ORG. 
ABB. 

LIL. 
PEZ. 



HST, x. 



PFZ, UPJ. 
PFZ, UPJ. 



SCH, UPJ. 
UPJ. 

SCH, UPJ. 
OMS. 



UPJ. 
UPJ. 

LIL. 
PYL. 
ACY. 



ARP, 
ARP, 



LKL. 
SDW. 
WYT. 
FIN. 

GAN. 
GAN, 
GAN. 
NEP. 
CLC. 
MAL. 
LIL. 
MAL. 

ACY. 

OMS. 
PFZ. 
MRK. 
LIL. 
OMS. 
ABB, 
OMS. 



ORG, WIL. 
LIL. 



LEM, SRL. 



CBP, MRK. 



126 



SYNTHETIC ORGANIC CHEMICALS. 1965 



TABLE 13B. 



-Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



*Renal-acting and edema-reducing agents — Continued 

*Other renal-acting and edema-reducing agents — Continued 
Benzothiadiazine derivatives — Continued 

Polythiazide 

Trichlorme thiazide 

Chlorthalidone 

Dichlorphenamide 

Probenecid 

Spironolactone 

Triamterene 

*Therapeutic nutrients : 
*Amino acids and salts : 

Acetyltryptophane 

Aminoacetic acid (glycine) 

Amino acid mixtures 

Arginine glutamate 

Aspartic acid and salts : 

Aspartic acid 

Magnesium aspartate 

Potassium aspartate 

Beta-alanine 

Glutamic acid and salts : 

Ammonium glutamate 

Calcium gluxamate 

^Glutamic acid 

Glutamic acid hydrochloride 

Potassium glutamate 

lysine (feed grade) 

lysine hydrochloride 

dl- Phenylalanine 

dl- Tryptophane 

*Caleium gluconate 

«Other therapeutic nutrients : 

Calcium glucoheptonate 

Calcium lactophosphate 

Calcium levulinate 

Calcium phytate 

Copper gluconate 

Ferrous gluconate 

Fructose 

Lecithin 

Liver concentrate 

Liver, desiccated 

Magnesium gluconate 

Manganese gluconate 

Potassium gluconate 

Sodium glycerophosphate 

*Vitamins : 

*Ascorbic acid and derivatives : 

* Ascorbic acid 

Ascorbyl pa lmi tate 

Calcium ascorbate 

Sodium ascorbate 

B-complex vitamins : 
*Cyanocobalamin (all grades): 

Feed grade 

Medicinal grade 

U.S. P. crystalline 

*Niacin (all grades): 

Feed grade 

Medicinal grade 

^Niacinamide 

*Pantothenic acid and derivatives: 

Calcium pantothenate (dextro) 

*Calcium pantothenate (racemic) (all grades): 

Feed grade 

Medicinal grade 

Calcium pantothenate (racemic) - calcium chloride 

complex. 
Dexpanthenol 



PFZ. 






SCH. 






GGY. 
MRK. 






MRK. 
SRL. 






SK. 






SDW. 






BPC, 


DOW. 




ABB, 


CUT, 


STA. 


ABB. 






HEX, 


NAC. 




WIT. 






WYT. 






BFG, 


NOP. 




IMC. 






LEM. 






IMC, 


LEM, 


PFZ. 


IMC, 


LEM. 




IMC, 


LEM, 


PFZ. 


MRK. 






MRK. 






SDW. 






SDW. 






MAL, 


PFZ, 


WHL. 


PFN. 






MAL. 






SEL. 






STA. 






PFZ. 






PFZ, 


SDW. 




DLL 






ARP. 






WIL. 






WIL. 






PFZ. 






PFZ. 






PFZ. 






SEL. 






HOF, 


MRK, 


PFZ. 


PFZ. 






PFZ. 






HOF, 


MRK, 


PFZ. 


GPR, 


MRK, 


PMP. 


IMC, 


MRK. 




MRK. 






ABB, 


CKL, 


MRK, NEP, RIL 


MRK, 


NOP, 


RIL, SCR. 


MRK, 


NEP, 


PD, RIL, SCR. 



DLI, MRK, x. 

CKL, FLM, HFT, NOP. 

NOP. 

NOP. 



MEDICINAL CHEMICALS 



127 



TABLE 13B. —Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1965 — Continued 



*Vitamins — Continued 

B-ooraplex vitamins — Continued 
•Pantothenic acid and derivatives — Continued 

Panthenol (racemic) 

Sodium pantothenate 

*Ribof lavin ( all grades ) : 

Feed grade 

Medicinal grade 

•Cholecalciferol (Vitamin D 3 ) 

•Ergocalciferol (Vitamin D 2 ) 

*Menadione 

•Menadione sodium bisulfite 

•Vitamin A alcohol and esters : 

Vitamin A acetate (feed grade) 

Vitamin A acetate (medicinal grade) 

Vitamin A alcohol 

Vitamin A natural esters 

•Vitamin A palmitate (feed grade) 

Vitamin A palmitate (medicinal grade) 

Other vitamins : 

d-Alpha tocopherol 

dl-Alpha tocopherol 

d-Alpha tocopheryl acetate 

dl-Alpha tocopheryl acetate 

d-Alpha tocopheryl acid succinate 

Beta-carotene (Provitamin A) 

Biotin 

Cyanocobalamin with intrinsic factor concentrate- 

Folic acid 

Inositol 

Magnesium nicotinate 

Niacinamide hydrochloride 

Phytonadione 

Pyridoxine 

Riboflavin-5-phosphate, sodium 

Sodium nicotinate 

Thiamine hydrochloride 

Thiamine mononitrate 

•Miscellaneous medicinal chemicals : 
Diagnostic agents : 

Roentgenographs contrast media: 

Acetrizoate, sodium 

Diatrizoate, meglumine 

Diatrizoate, sodium 

Diprotrizoate, sodium 

Iodihippurate, sodium 

Iodopyracet 

Iopanoic acid 

Iophendylate 

Iothalamate, meglumine 

Iothalamate, sodium 

Methiodal, sodium 

Other diagnostic agents : 

Galactose (liver function test) 

Indocyanine green (cardiac output test) 

Metyrapone (pituitary function test) 

Hematological agents: 
•Anticoagulants : 

Ammonium heparin 

Anisindione 

Bishydroxycoumarin 

Phenindione 

Potassium heparin 

Sodium heparin 

Sodium warfarin 

Other hematological agents : 

Aminocaproic acid 

Cellulose, oxidized 

Dextran (plasma expander) 

Smooth muscle relaxants : 

Alverine 

Alverine citrate 



Manufacturers ' identification codes 
(according to list in table 22) 



HOF. 
PD. 

COM, GPR, HOF, MRK, PMP. 

HOF, MRK. 

CW, DLI, NOP, VTM. 

CW, DLI, SCR, VTM. 

ABB, HET, HFT, WHL. 

ABB, HET, HFT, WHL. 

HOF. 

CW, HOF, PFZ. 

CW, HOF. 

CW. 

EK, HOF, PFZ. 

EK, HOF, PFZ. 

CW, EK. 

HOF. 

CW, EK. 

HOF. 

CW, EK, HOF. 

HOF. 

HOF. 

WIL. 

ACT. 

STA. 

NEP. 

NEP. 

MRK. 

HOF, MRK. 

HOF. 

MRK, NEP. 

HOF, MRK. 

HOF, MRK. 



MAL. 

SDW. 

SDW. 

MAL. 

MAL. 

SDW. 

SDW. 

x. 

MAL. 

MAL. 

SDW. 



WIL. 

SCH. 

ABB, FIN. 

CTN, GAN, WIL. 

WIL. 

ABB, RIK. 

EN. 

ACT. 
EKT. 
PHR. 

CTN. 
CTN. 



128 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 13B.— Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer , 1965 — Continued 



Chemical 


Manufacturers ' identification codes 
(according to list in table 22) 


^Miscellaneous medicinal chemicals—Continued 
anooth muscle relaxants — Continued 


era. 

LIL. 

ICO. 
ABB, PEN. 




Other miscellaneous medicinal chemicals : 








PEN. 


ttydrastme hydrocnior de 



FLAVOR AND PERFUME MATERIALS 



129 



Flavor and Perfume Materials 

TABLE 14B. — Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer, 1965 

[ Flavor and perfume materials for which separate statistics are given in table 14A are marked below with an asterisk 
(*); those not so marked do not appear in table 14A because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Material 



Manufacturers' identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIALS, CYCLIC 

Benzenoid and Naphthalenoid 

2 '-Acetonaphthone (Methyl fi-naphthyl ketone) 

Aeetophenone 

7-Acetyl-6-ethyl-l,l,4,4-tetramethyl-l,2,3,4-tetrahydro- 
naphthalene . 

p-Allylanisole 

Allyl phenoxyacetate 

*4-Allylveratrole (Eugenyl methyl ether) 

p-tert-Amylcyclohexanone 

*Anethole (p-Propenylanisole) 

p-Anisaldehyde (p-Methoxybenzaldehyde) ■ 

Anisole (Methyl phenyl ether) 

Anisyl acetate 

Anisyl alcohol 

*Benzophenone 

*Benzyl acetate 

*Benzyl alcohol 

Benzyl behzoate 

Benzyl butyrate 

*Benzyl cinnamate 

Benzyl ether 

Benzyl formate 

Benzyl glyceryl acetal 

Benzyl isobutyrate 

Benzyl isoeugenyl ether 

Benzyl isopentyl ether 

Benzyl phenylacetate (Benzyl a-toluate) 

*Benzyl propionate 

*Benzyl salicylate 

a -Bromostyrene 

4' -tert-Butyl-2 ', 6' -dimethyl-3 ' , 5 '-dinitroacetophenone 

(Musk ketone ) . 
6-tert-Butyl-3-methyl-2,4-dinitroanisole (Musk ambrette)-- 
p-tert -Butyl-a -methylhydrocinnamaldehyde ( a-Methyl-f! - ( p- 

tert -butylpheny 1 ) propionaldehyde ) . 
5-tert-Butyl-l,2,3-trimethyl-4.,6-dinitrobenzene (5-tert- 
Butyl-4, 6-dinitrohemi mellitene ) . 

5-tert-Butyl-2,4,6-trinitro-m-xylene (Musk xylol) 

Carvacrol (2-p-Cymenol) 

*Cinnamaldehyde 

Cinnamic acid 

Cinnamyl acetate 

*Cinnamyl alcohol 

Cinnamyl anthranilate 

Cinnamyl cinnamate 

Cinnamyl formate 

Cinnamyl isovalerate 

Cinnamyl propionate 

trans-Decahydro-2-naphthol 

p ,<* -Dimethylbenzyl alcohol (p-Methylphenylmethylcarbinol)- 

ajx -Dimethylphenethyl acetate 

<x,a -Dimethylphenethyl alcohol 

ccyx -Dimethyl -3-phenyl-l-propanol 

4,6-Dinitro-l,l,3,3,5-pentamethylindan 

Diphenylmethane 

l,3-Diphenyl-2-propanone (Dibenzyl ketone) 

l-Ethoxy-2-hydroxy-4-propenylbenzene 

2-Ethoxynaphthalene (Ethyl p-naphthyl ether) 

Ethyl anisate 

Ethyl anthranilate 

Ethyl benzoate 



FB, GIV, TBK. 
GIV, TBK. 
GIV. 

GIV. 

GIV. 

FB, GIV, ICO. 

IFF. 

ARZ, GLD, HNW, HPC. 

GIV, OPC, SHL, TBK, UNG. 

GIV. 

GIV, TBK. 

GIV, TBK. 

G, GIV, ICO, NEO, TBK. 

GIV, OPC, SHL, TBK, TNP. 

BPC, GIV, OPC, SHL, TBK, TNP. 

MON, TBK, TNP. 

FB, GIV, TBK. 

FB, GIV, ICO, TBK. 

OPC, SHL, TNP. 

TBK. 

GIV. 

TBK. 

GIV, TBK. 

GIV. 

GIV, TBK. 

FB, GIV, TBK. 

GIV, ICO, OPC, TBK, UNG. 

TBK. 

GIV, TBK. 

GIV. 
GIV. 

GIV. 

GIV. 

GIV. 

FB, OPC, TBK. 

BPC, ICC. 

FB, GIV, TBK. 

FB, GIV, NEO, TBK. 

FEL, GIV, RT. 

TBK. 

TBK. 

TBK. 

GIV, TBK. 

IFF. 

GIV, TBK. 

GIV, IFF. 

GIV, IFF. 

IFF. 

GIV. 

TBK. 

GIV, TBK. 

SHL. 

GIV. 

ICO. 

FB. 

TBK. 



130 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 14B. 



-Flavor and perfume materials for which U.S. production or sales were reported, identified by 
manufacturer, 1 965- -Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued 



Pen 



id and haphthalenoid--Continued 



Ethyl cinnamate 

Ethyl a,|3-epoxy-(j-methylhydrocinnamate 

Ethyl eugenol 

2-Ethylhexyl salicylate 

Ethyl phenylacetate 

Ethyl 3-phenylglycidate 

Ethyl salicylate 

Ethylvanillin 

*Eugenol 

Eugenol acetate 

Hexylcinnamaldehyde 

Hydratropaldehyde (x -Phenylpropionaldehyde ) 

Hydratropaldehyde, dimethyl acetal 

Hydrocinnamaldehyde (p -Phenylpropionaldehyde) 

Hydroxycitronellal methyl anthranilate 

2-Hydroxypropyl p -N , N -bis ( 2 -hydroxypropyl ) aminobenzoate • 

Isobutyl cinnamate 

*Isobutyl phenylacetate (Isobutyl a-toluate) 

*Isobutyl salicylate 

*Isoeugenol 

Isoeugenyl acetate 

*Isopentyl salicylate (Amyl salicylate) 

p-Isopropylbenzaldehyde ( Cumaldehyde ) 

p-Isopropylcyclohexanol 

*p-Isopropyl-a-methylhydrocinnamaldehyde ( Cyclamen 
aldehyde ) . 

4' -Methoxyacetophenone 

2-Methoxynaphthalene (Methyl p -naphthyl ether) 

4-(a-Methoxyphenyl)butanone 

l-(p-Methoxyphenyl)-l-pentene-3-one 

4' -Methylacetophenone (Methyl p-tolyl ketone) 

Methyl anisate 

p-Methylanisole (p-Cresyl methyl ether) 

*Methyl anthranilate 

Methyl benzoate 

p-Methylbenzyl acetate 

a-Methylbenzyl acetate 

a-Methylbenzyl alcohol (Methylphenyl carbinol) 

*a-Methylcinnamaldehyde 

*Methyl cinnamate 

4-Methyl-7-ethoxy coumarin 

p-Methyl hydratropic aldehyde 

Methyl N-methylanthranilate (Dimethyl anthranilate) 

Methyl phenylacetate (Methyl o-toluate) 

*Methyl salicylate (Synthetic wintergreen oil) 

*a-Pentylcinnamaldehyde (a -Amylcinnamaldehyde) 

*Phenethyl acetate 

Phenethyl alcohol 

Phenethyl formate 

*Phenethyl isobutyrate 

Phenethyl isovalerate 

*Phenethyl phenylacetate (Phenethyl a-toluate) 

Phenethyl propionate 

Phenethyl salicylate 

2-Phenoxyethyl isobutyrate 

Phenylacetaldehyde (a-Tolualdehyde) 

Phenylacetaldehyde, dimethyl acetal 

Phenylacetaldehyde, ethylene acetal 

o-Phenylanisole (2-Methoxybiphenyl) 

4-Phenyl-3-buten-2-one 

Phenyl ethyl acetal 

Phenylethyl tiglate 

*3-Phenyl-l-propanol (Hydrocinnamic alcohol) 

3-Phenyl-l-propyl acetate 

5-Propenyl-2-ethoxyphenol (Propenylguaethol) 

4- Propenylveratrole (Isoeugenyl methyl ether) 

p-Propylanisole 



TBK. 
TBK. 



ICO. 
TBK. 



GIV, 

GIV, 

ICO. 

FEL, 

GIV. 

GIV, 

TBK. 

MON, RDA. 

FB, GIV, ICO, LUE, NEO, PEN, RT, TBK, UNG, VLY. 

GIV. 

GIV, 

GIV, 

GIV, 

GIV. 

GIV. 

SHL. 

TBK. 

FB, 

FB, 

GIV, 

TBK. 

FB, 

GIV. 

GIV. 

GIV, 



IFF, TBK. 

IFF. 

IFF. 



GIV, TBK. 
GIV, TBK. 
SHL, TBK, VLY. 

GIV, ICO, OPC, SHL, TBK. 
OPC, RDA. 



GIV, ICO. 

GIV. 

TBK. 

GIV. 

TBK. 

ICO. 

GIV; 

FB, 

HN. 

ICO. 

FB, GIV, VLY. 

TBK. 

FB, 

FB, 

GIV, 

GIV, 

GIV. 

GIV. 

CFC 

FB, 

GIV. 

GIV. 

IFF 

GIV, 

FB, 

FB, 

GIV, 

NEO, 

GIV. 

GIVj 

GIV, 

GIV. 

GIV. 

FB. 

GIV. 

FB. 

FB, 

FB, 

ICO. 

GIV, 

GIV. 



OPC. 
GIV, MEE, OPC, SHL, UNG. 



GIV, TBK, VLY. 
ICO, TBK. 



OPC, 
TBK, 
D0W ; 

GIV, 
IFF. 
IFF, 
TBK. 
IFF, 

GIV. 

GIV, 

TBK. 
TBK. 
TBK. 
TBK. 



HN, MON, PEN. 
IFF, NEO, RDA, TBK, VLY. 
NEO. 
OPC. 

TBK. 

IFF, TBK. 



GIV, TBK. 
GIV. 



ICO, TBK. 



FLAVOR AND PERFUME MATERIALS 



131 



TABLE 14B. --Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer , 2965--Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued 
Benzenoid and Naphthalenoid— Continued 

n-Propyl phenethyl acetal 

p-Tolualdehyde (p-Methylbenzaldehyde) 

p-Tolyl acetate (p-Cresyl acetate) 

p-Tolyl phenylacetate (p-Cresyl a-toluate) 

a-(Trichloromethyl)benzyl acetate (Rosetone) 

Trimethyltetrahydrobenzylidene acetone 

Vanillin 

All other 

Terpenoid, Heterocyclic, and Alicyclic 

Allyl eyclohexyl propionate 

Allyl ionone 

Amyris acetate 

Bornyl acetate 

4-tert-Butyleyclohexanol 

4-tert-Butylcyclohexyl acetate 

Cadinene 

Carvone (Carvol) 

Caryophyllene 

Cedranone 

Cedrenol 

Cedrol 

*Cedryl acetate 

*Citral (Geranial) 

Citral dimethyl acetal 

Citronellal 

*Citronellol 

*Citronellyl acetate 

Citronellyl butyrate 

*Citronellyl formate 

Citronellyl isobutyrate 

Citronellyl oxyacetaldehyde 

Citronellyl propionate 

*Coumarin 

Cyclohexadecanolide 

Cyclohexylcyclohexanone : 

Cyclopentanone 

Dihydrogeraniol 

Dihydroterpinyl acetate 

^Essential oils, chemically modified: 

Citronella oil, acetylated 

Clove leaf oil terpenes 

Ethyl oxyhydrate 

Gualacwood acetate 

Lavandin, acetylated 

Oil clove stem, acetylated 

Sassafras oil, hydrogenated 

Other 

a-Furfural mercaptan 

*Geraniol 

Geranoxy acetaldehyde 

*Geranyl acetate 

Geranyl benzoate 

Geranyl butyrate 

Geranyl formate 

Geranyl isobutyrate 

Geranyl isovalerate 

Geranyl phenylacetate (Geranyl a-toluate) 

2-Hexyl-2-cyclopenten-l-one 

Hydrocoumarin (3,4— Dihydrocoumarin) 

*Hydroxyeitronellal 

Hydroxycitronellal, dimethyl acetal 

4-(4-Hydroxy-4-methylpentyl)-3-eyelohexene-l-carboxalde- 

hyde. 
Indole 



GIV. 

HN. 

GIV, IFF. 

GIV. 

ICO, TBK. 

TBK. 

MON, SLV. 

FB, GIV, IFF, PFW, FDA, SHL. 



GIV. 

GIV, 

GIV, 

FEL. 

IFF. 

DOW, 

FB. 

FB, 

FB, 

TBK 

GIV 

GIV 

GIV 

FB, 

GIV 

FB, 

FB, 

GIV 

GIV 

FB, 

GIV, 

IFF. 

GIV, 

DOW, 

IFF. 

GIV. 

AHA. 

ICO. 

GIV. 

CP, 

SHL. 

FEL, 

FB, 

FEL. 

FB. 

GIV. 

BPC. 

RT. 

FB, 

IFF. 

FEL. 

GIV, 

GIV, 

GIVl 

IFF. 

FB. 

GIV. 

IFF. 

GIV. 

giv! 

GIV! 

iff! 



IFF. 
TBK. 



FRM, OPC. 
GIV. 



IFF, TBK. 

IFF, NEO, TBK, UNG. 
FEL, GIV, LUE, MYW, NEO, RT, TBK. 

GIV, IFF, TBK. 

GIV, GLD, IFF, NEO, TBK, VLY. 
IFF, TBK, VLY. 

GIV, IFF, TBK, VLY. 
IFF, TBK. 



i, NEO, RDA, TBK. 



FLO, LUE, VND. 
GIV, TBK. 
GIV, UNG. 



FEL, GIV, GLD, IFF, NEO, TBK, UNG, VLY. 
GIV, IFF, TBK, VLY. 



TBK. 

IFF, TBK, VLY. 



ICO. 

GLD, IFF, OPC, TBK, VLY. 

OPC, TBK. 



DOW, GIV. 



132 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 14B. --Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer , 1 965 --Continued 



Material 



FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued 
Terpenoid, Heterocyclic, and Alicyclic--Continued 



*Ionones : 

a-Ionone 

(3-Ionone 

Ionone (a- andp-) 

Isoborneol (Isobornyl alcohol) 

*Isobornyl acetate 

Isobutylquinoline 

Isomenthone 

Isopropylquinoline 

Isopulegol 

Isosafrole 

Laevo carveol 

d-Limonene 

Llnalool 

Linalyl acetate 

Linalyl anthranllate 

Linalyl isobutyrate 

Linalyl propionate 

l,l-p-Menthen-6-yl-l-propanone 

*Menthol, synthetic: 

Tech 

U.S.P 

Menthone 

Menthyl acetate 

6-Methylcoumarin 

*Methylionones : 

Methyl-a-ionone 

Methyl-fJ-ionone 

Methylionone (a- and fj-) 

Methyl-Y -ionone 

Methyl-5-ionone 

*Nerol 

Nerol, acetate 

Nopyl acetate 

Phellandrene 

*Piperonal (Heliotropin) 

Piperonal, sodium bisulfite complex 

Piperonal terpenes 

Pseudolinalyl acetate (Myrcenyl acetate, principally) - 

*Rhodinol 

Rhodinyl acetate 

Safrole 

Santalol 

Santalyl acetate 

♦Sweeteners , synthetic : 

Cyclohexanesulfamic acid 

Cyclohexanesulfamic acid, calcium salt 

Cyclohexanesulfamic acid, sodium salt 

Saccharin 

Saccharin, calcium salt 

Saccharin, sodium salt 

All other 

*Terpineols: 

a-Terpineol 

P-Terpineol 

Terpineol (a- andg-) 

Terpinol hydrate (Terpin hydrate ) , tech 

*Terpinyl acetate 

Terpinyl propionate 

Tetrahydro alloocimenol 

3,5,5-Trimethylcyclohexanol 

Vertofix (Acetyl cedrene, principally) 

Vetivenol 

*Vetivenyl acetate 

All other 



Manufacturers ' identification codes 
(according to list in table 22) 



GIV, IFF, LUE, MYW, TBK. 

MYW, TBK. 

GIV, LUE, MYW, NEO. 

RDA. 

FB, GIV, OPC, RDA. 

IFF. 

FB, GIV, TBK. 

FMT. 

GIV, TBK. 

GIV. 

FB. 

RT, SKG. 

FB, FEL, GIV, GLD, HOF, LUE, NEO, SHL, TBK, UNG. 

DOW, FB, GIV, GLD, HOF, LUE, SHL, UNG. 

FMT. 

GIV, TBK. 

FB, GIV. 

GIV. 

GIV, ICO, NEO. 
GIV, HNW, NEO. 
GIV, HNW, NEO. 
FB, GIV. 
GIV. 

GIV, IFF, MYW. 

IFF, NEO. 

GIV, LUE, MYW, VLY. 

TBK. 

TBK. 

FB, GIV, GLD, IFF, TBK, VLY. 

FB, GIV. 

MYW, SHL, TBK, VLY. 

GIV, ICO. 

GIV, SHL, TBK. 

SHL. 

SHL. 

IFF. 

FB, FEL, GIV, IFF, LUE, NEO, SHL. 

FB, GIV, IFF. 

GIV. 

GIV, IFF. 

GIV. 

ABB, NRS. 

ABB, CYC, DRW, MDN, NRS, PBY, PFZ, UNS. 

ABB, DRW, MON, NRS, PBY, PFZ, UNS. 

MEE, M3N, NRS. 

MEE, MON, NRS, PBY. 

MEE, MON, NRS. 

VLY. 

GLD, HNW, HPC. 

HNW. 

GIV, NEO. 

HPC. 

GIV, NEO, OPC, RDA, TBK, UNG. 

GIV, TBK. 

IFF. 

ICO. 

IFF. 

GIV, TBK. 

FB, GIV, IFF, NEO, TBK. 

FB, GIV, IFF, OPC, RDA, TBK. 



FLAVOR AND PERFUME MATERIALS 133 

TABLE 14B. -- Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer, 1965 — Continued 



FLAVOR AND PERFUME MATERIALS, ACYCLIC 

Acetyl butyryl 

Acetyl isovaleryl 

Acetyl propionyl 

Allyl heptanoate (Allyl enanthate) 

*Allyl hexanoate (Allyl caproate) 

Allyl isothiocyanate (Synthetic mustard oil) 

Allyl sulfide (Diallyl sulfide) 

Amyl propionate 

Butyl butyrate 

Butyl isovalerate 

Butyroyl butyl lactate 

Decanal ( Capraldehyde ) (C 10 ) 

Diallyl disulfide 

Diethyl sebacate (Ethyl sebacate) 

Diethyl succinate 

Diethyl tridecanedioate (Ethylene brassylate) 

2,6-Dimethyl-5-hepten-l-al 

3,6-Dimethyl-3-oetanol 

3,7-Dimethyl-l-octanol 

3,7-Dimethyl-3-octanol 

Dimethyl succinate 

Ethylamyl ketone 

Ethyl butyrate 

Ethyl decanoate 

Ethylene brassylate 

Ethyl heptanoate (Ethyl enanthate) 

Ethyl hexanoate (Ethyl caproate) 

Ethyl isovalerate 

Ethyl laurate 

Ethyl levulinate 

*Ethyl nonanoate (Ethyl pelargonate) 

Ethyl octanoate (Ethyl caprylate) 

^Glutamic acid, monosodium salt (Monosodium glutamate 

Heptanal (Enanthaldehyde) (C 7 ) 

Heptyl alcohol (Heptanol) 

cis-3-Hexen-l-ol 

cis-3-Hexyn-l-ol 

3-Hydroxy-2-butanone (Acetoin) 

4-Hydroxynonanoic acid, y-lactone (y-Nonalactone) — 

4-Hydroxyoctanoic acid, y-lactone (y -Octalactone ) 

4-Hydroxyundecanoic acid, y-lactone (y -Undecalactone 

*Isopentyl butyrate (Amyl butyrate) 

*Isopentyl formate (Amyl formate) 

Isopentyl heptanoate (Amyl caproate) 

Isopentyl isovalerate (Amyl isovalerate) 

*Lauraldehyde (Dodecyl aldehyde) (Ci 2 ) 

6-Methyl-5-hepten-2-one 

Methyl isovalerate- 

Methyl-p -methylthiopropionate 

Methyl -2-nonenoate 

Methylolmethylhexyl ketone 

2-Methylundecanal ( 2-Methylnonylacetaldehyde ) 

Myristic aldehyde 

Nonanal (Pelargonaldehyde) (C 9 ) 

Nonanediol monoacetate 

Nonyl acetate 

Nonynol acetate, isomeric (Tepyl acetate) 

Octanal (Caprylaldehyde) (Cb) 

n-Octyl acetate 

n-Octyl formate ■ 

n-Octyl isobutyrate 

Omega decenol 

2,6,10-Trimethyl-9-undeeen-l-ol 

Undecanal (Hendecanaldehyde) (Cn) 

2-Undecanone (Methyl nonyl ketone) 

Undecenal (Hendecenaldehyde) 

10-Undecen-l-ol 

Valerolactone 

All other 



Manufacturers' identific<.ion codes 
(according to list in table 22) 



FB, 


rBK. 




DOW, 


FB, 


GIV, UNG. 


ICO, 


MRT. 




RT. 






GIV. 






OPC, 


TBK. 




TBK. 






ICO. 






GIV, 


IFF, 


TBK. 


RT. 






FEL, 


TBK. 




ICO, 


TBK, 


UCC. 


RDA. 






GIV. 






cue. 






GIV, 


TBK. 




GIV. 






ICO. 






GIV. 






FB, 


NW, RT, TBK. 


TBK. 






VLY. 






FB, 


FEL, 


TBK. 


FB, 


NW. 




FB, 


TBK. 




FB, 


TBK. 




FMT. 






FB, 


FEL, 


GIV, TBK. 


FB, 


TBK. 




COM, 


GRW 


ITC, IMC, MRK. 


BAC. 






BAC 


UCC 




X. 






X. 






FMT. 






GIV 


TBK 




GIV 


TBK 




FB, 


GIV. 




FB, 


GIV, 


NW, RT, TBK. 


FEL 


RT, 


TBK. 


FEL 


TBK 




FB, 


TBK. 




GIV 


IFF 


TBK. 


GIV. 






FB. 






RT. 






GIV 






GIV 






GIV 


TBK 




GIV 






GIV 






GIV 






TBK 






IFF 






GIV 


IFF 




FB, 


TBK. 




FB. 






FB, 


TBK. 




IFF 






GIV 






GIV 


IFF 


, TBK. 


GIV 






GIV 






GIV 






GIV 






FB, 


GIV, 


IFF, OPC, RT, SHL 



SYNTHETIC ORGANIC CHEMICALS, 1965 



Plastics and Resin Materials 

TABLE 15B.— plastics and resin materials for which U.S. production or sales were reported, identified by 

manufacturer , 1965 

[Plastics and resin materials for which separate statistics are given in table 15A are marked below with an asterisk 
(*); chemicals not so marked do not appear in table 15A because the reported data are accepted in confidence and 
may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies 
that the manufacturer did not consent to his identification with the designated product] 



Material and use 



Manufacturers' identification codes 
(according to list in table 22) 



THERMOSETTING RESINS 



*Alkyd resins: 

Protective coatings: 
*Phthalic anhydride type- 



*Polybasic acid type 

*A11 other uses 

*Coumarone-indene and petroleum polymer resins 

*Floor tile 

*Rubber compounding 

*A11 other uses 

Epoxy resins: 

Unmodified: 

^Bonding and adhesives 

^Protective coatings 

^Reinforced plastics 

*A11 other uses 

*Modified 



*Polyester resins: 

Reinforced plastics: 
*Sheets, flat and corrugated 

*A11 other 

^Surface coatings 

*A11 other uses 

Silicone resins 

*Phenolic and other tar acid resins 
^Molding materials 

Bonding and adhesive resins for- 
*Laminating 

*Coated and bonded abrasives — 

*Friction materials 

^Thermal insulation 

^Foundry or shell molding 

*Plywood 

*Fibrous and granulated wood — 



AAI, ACP, ACY, ADM, APT, APV, BAL, BEN, BOY, BRU, CEL, 
CIK, CM, COM, CPV, DAV, DEG, DSO, DUN, DUP, EW, FAR, 
FBR, FCD, FLW, FOC, FRE, FSH, GEI, GIL, GLD, GRG, 
GRV, HAN, HPC, HRS, ICF, JOB, JWL, KEL, KMC, KMP, 
KPS, KYN, MCC, MID, NCI, NPV, NTL, 0R0, OSB, PER, 
PFP, PPG, PRT, RCI, RED, REL, RH, RMC, SCF, SCN, SED, 
SIP, SM, SRR, SVC, SW, SYV, TV, VTV, WAS, WPC, x. 

ACP, ACY, APV, BEN, BRU, CGL, CM, COM, CPV, DSO, DUN, 
DUP, EW, FBR, FCD, FOC, GEI, GLD, GRV, HPC, ICF, KPS, 
MCC, MID, NCI, NON, NPV, OBS, 0R0, OSB, PPG, PRT, 
RED, REL, RH, RMC, SCN, SHA, SM, SRR, TV, VTV. 

ACP, ACY, AMR, CGL, CIK, DUP, GLD, HPC, HYC, JSC, KMP, 
MMM, MOB, NOP, ORO, QCP, RCI, RH, SCN, SIP, SM. 

ACC, ACP, NEV, NSP, PAI, VEL. 
ACC, ACP, KPI, NEV, NSP, PAI, VEL, WTC. 
ACC, ACP, ADM, CM, DSO, DUP, ENJ, ICF, MCA, NEV, NPV, 
NSP, PAI, PPG, RCM, VEL, VTV. 



CBA, CEL, DOW, SHC, UCP. 

CBA, CEL, DOW, RCI, SHC, UCP. 

CBA, CEL, DOW, RCI, SHC, UCP. 

CBA, CEL, DOW, RCI, SHC, UCP. 

ACP, ADM, BEN, CM, DSO, FAR, FMC, GLD, HAN, HAP, ICF, 

IOC, KPT, MID, MNP, MRB, NON, ORO, OSB, PPG, PYR, 

REZ, RMC, SCN, SM, VTV, WAS. 



ACY, ADM, APD, DA, EW, FRE, GLD, HKD, ICF, LAS, MFG, 

ORO, PPG, RCI, RH, SIC, USR. 
AAI, ACP, ACY, ADM, CAP, CPV, DA, DSO, FRE, GLD, GRV, 

HKD, ICF, IPC, KPS, LAS, MFG, MRO, PLU, PPG, RCI, 

SW, USR. 
ACP, ACY, APD, COM, CPV, DA, FCD, GLD, GYR, ICF, MCC, 

ORO, PPG, SW, USR. 
ACP, ACR, ACY, AMR, APD, DA, DAV, DSO, EKT, EPC, EW, 

FMC, FRE, GEI, GLD, GNT, GRG, GYR, HKD, LAS, OCF, 

PLU, PPG, RCI, RH, SCN, SW, USR, UTR, VAL. 
ACP, BOR, DCC, GLD, SPD, UCS. 

FRL, GE, HER, HKD, HVG, IRC, MON, MRB, PLS, RCI, RGC, 
SYR, UCP, VAR, VSV. 

ACP, AMR, BOR, CAT, CBR, CD, DRL, EW, FOM, GE, HKD, 

IRI, MCA, MON, NPI, NPP, NTC, NVF, PGU, PYZ, RCD, 

RCI, SCN, SPL, SYR, TAY, TKL, UCP, VAR. 
AMR, EME, BOR, CAT, CBM, CBR, HKD, MMM, MON, PYZ, SCN, 

SYR, UCP, VAR. 
ABS, BME, BOR, FRL, GE, HKD, PYZ, SCN, SYR, SYV, UCP, 

VAR, VSV, x. 
ACP, AMR, CAT, GE, HKD, ICF, MON, NPI, OCF, PYZ, RCI, 

SYV, UCP. 
ACP, ACR, ARM, BOR, GE, HKD, MON, NPI, PYZ, RCI, SCN, 

UCP, UNO, VAR, WOD. 
AMR, BOR, CAT, CBC, CBD, HPC, MON, PGU, PYZ, RCI, RH, 

SIM, WCA, WOD, WRD. 
AMR, BOR, CBC, CBD, HKD, ICF, MCA, MON, NPI, PYZ, RCI, 

SIM, UCP. 



PLASTICS AND RESIN MATERIALS 



135 



TABLE 15B. --Plastics and resin materials for which U.S. production or sales were reported, identified by 

manufacturer, 1965- -Continued 



Material and use 



THERMOSETTING KESINS--Continued 

*Phenolic and other tar acid resins— Continued 
Bonding and adhesive resins for — Continued 
*A11 other bonding and adhesive uses 

*Proteotive coatings 

*A11 other uses 

*Polyurethane and diisocyanate resins 

♦Rosin modifications: 

♦Rosin and rosin esters, unmodified (ester gums, 
♦All other 

Styrene and alkyd polyesters 

♦Urea and melamine resins: 

*Textile treating and coating resins 

♦Paper treating and coating resins 

Molding materials 

Bonding and adhesive resins for— 

♦Laminating 

♦Plywood 

♦Fibrous and granulated wood 

♦All other bonding and adhesive uses 

♦Protective coatings 

All other uses 

All other thermosetting resins 



THERMOPLASTIC RESINS 
Acrylic resins 

♦Cellulose plastics materials: 
Sheets , continuous : 
♦Under 0.003 gage 

♦0.003 gage and over 

♦All other sheets, rods, and tubes 

♦Molding and extrusion materials 

♦Polyamide resins: 

♦Nylon type 

♦Non-nylon type 

♦Styrene type plastics materials: 

♦Molding 

♦Textile and paper treating and coating- 

♦Emulsion paint 

♦Extrusion 

♦All other uses 



Manufacturers' identification codes 
(according to list in table 22) 



ACP, AMR, BME, B0R, CAT, GE, HKD, IRI, KPT, M0N, MRB, 
PYZ, RPC, SCN, SHA, SNC, SYR, UCP, USR, VAR. 

ADM, AMR, BOR, CIK, CPV, DS0, EW, FAR, FCD, FRE, GE, 
GEI, GLD, GRG, GRV, HAN, HER, HKD, ICF, INL, KRM, 
MID, M0N, NCI, NPI, 0R0, PFP, PYZ, RCI, RH, RMC, SCN, 
SHA, SM, SNC, SW, SYR, UCP, VAR, VTV, WAS. 

ACP, ACR, AMR, BOR, CAT, EW, GEN, HER, HKD, IOC, IRC, 
KND, MMM, MON, MRB, PLS, PYR, PYZ, RCI, REZ, RGC, RH, 
SCN, SNC, UCP, USR, VAR, VSV, x. 

ACB, ADM, ARK, BFG, BKL, CDM, DUP, FAR, GPM, HAP, HOU, 
IPI, MCC, MID, NOP, NPV, PEL, PFP, PYR, QUN, SCN, 
TRN, UPC, UPJ. 

ADM, APV, CBY, DPP, FAR, FCD, FRP, HPC, KRM, MCC, SRR. 
ADM, APV, CBY, DPP, FAR, FCD, FLW, FRP, HPC, KRM, MCC, 

RH, SCF, SRR. 
ADM, DEG, MCC. 

ACY, APX, BOR, BPY, CAT, CCT, CIB, CRC, DAN, DEP, DUP, 
ECC, HNC, HRT, JSC, MON, MRA, ONX, PC, QCP, RCI, RH, 
ROC, RPC, S, SBC, SEY, SNW, STC, SYN, TV, USO, WON. 

ACY, AMR, BME, BOR, CBD, CBR, DEP, DUP, HPC, MMM, MON, 
RCI, RH, SIM, x. 

ACP, ACY, AV, BOR, CAP, EFH, GDN, PMC. 

ACY, BOR, CAT, FOM, GE, MON, NPP, NTC, PGU, PPL. 

ACY, BGC, BOR, CAT, CBC, CBD, HPC, MON, NPI, NTC, PGU, 

RCI, REN, RH, SAC, SIM, SOR, WOD, WRD. 
ACY, AMR, BOR, CED, IPR, MON, NTC, PGU, RCI, SOR, SWP, 

SYV, UPL. 
ACP, ACY, BOR, GLD, MON, OCF, RCI, UNO. 
ACP, ACY, AMR, BOR, CEL, CPV, DUP, GRV, HAN, KPS, MID, 

MON, OXR, PPG, RCI, REL, RH, SCN, SW. 
ACP, ACY, AMR, AV, BOR, CAT, CMP, DUP, ECC, FRP, GEO, 

HPC, MMM, MON, RCI, RH, VAL, VAR, WIC. 
ACP, ACY, ADM, DEG, GGY, HPC, HVG, JNS, MCC, MON, NPV, 

OCF, RCD, SNW, UBS, UNO, WTC. 



AGO, ACY, CAT, CEL, CIB, CMG, DUP, FLH, GLC, GLX, HCO, 
JNS, JSC, PII, PPG, QUN, RH, RPC, SAR, SEY, USP, VPC, 
WIC. 



CEL, DUP, EKT, MON. 

CEL, DOW, EKT, MPP, NIX, PDJ, SPY. 

CEL, MPP, NIX, PDJ, RPI, RSB, SPY. 

CEL, DOW, EKT, MON, PMA, RSB. 

ALF, DUP, FG, POL, SPN. 

AMR, BCM, EMR, GNM, HN, JNS, KRM, SNW. 

ACP, BFG, BKC, BPL, CSD, DOW, DSO, FBF, FG, FIR, GOR, 

GRP, GYR, KPP, MCB, MON, MPL, PLA, RCC, SHC, SOL, 

TIC, UCP, USR. 
BOR, DOW, FIR, GNT, GRD, GYR, ILC, KPP, MON, MRT, USR, 

WAS, WIC. 
BOR, DOW, DSO, DUP, FIR, GLD, GNT, GRD, GYR, KPP, JSC, 

MON, USR. 
ASP, BFG, CSD, DOW, KPP, MCB, MON, PMA, RCC, UCP, USR. 
ACC, ACP, BCN, BFG, BKC, BOR, CSD, DOW, DSO, DUP, FIR, 

G, GNT, GRD, GYR, IOC, JNS, JSC, KPP, MCB, MON, MRT, 

ONX, PAI, POL, PVI, RCC, RH, SEK, SEP, SHC, SPI, UBS, 

UCP, UNC, USR, WAS, WIC. 



136 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 15B Plastics and resin materials for which U.S. production or sales were reported, identified by 

manufacturer, 1965 — Continued 



Material and use 



Manufacturers ' identification codes 
(according to list in table 22) 



THERM3PLASTIC RESINS--Continued 

Vinyl resins: 
♦Polyvinyl acetate resins: 

♦Emulsion paint 

♦Adhesives 

♦Bonding and sizing 

♦All other uses 

♦Polyvinyl chloride and copolymer resins: 

♦Film, under 6 mils 

♦Sheet, 6 mils and over 

♦Flooring 

♦Paper and textile coating 

Extrusion: 
♦Wire and cable 

♦Garden hose 

♦All other extrusions 

Molding: 
♦Records 

♦Slush and rotational molding 

♦All other moldings 

♦All other uses 

♦All other vinyl resins 

Polyolefin plastics materials: 
♦Polyethylene, density 0.940 and below: 

♦Injection molding 

♦Blow molding 

Extrusion: 
♦Film and sheet 

♦Wire and cable coating 

♦Extrusion coating on paper and other substrates- 

♦Pipe 

♦All other extrusions 

♦All other uses ■ 

♦Polyethylene, density over 0.940: 

♦Injection molding 

♦Blow molding 

Extrusion: 
♦Film and sheet 

♦Wire and cable coating 

♦Pipe 

♦All other extrusions 

♦All other uses 



ACP, AIR, AML, APV, BOR, BOY, CAT, CEL, COM, DAV, DSO, 
DUP, FAR, FLH, GLC, GLD, GRD, HAM, JNT, KMC, KMP, 
MCC, MON, NPV, NSC, RCI, REL, SED, SPC, UCP, WAS, x. 

ACP, AML, AIR, BOR, CAT, CEL, DUP, FC, FLH, GLC, GRD, 
HNC, JNT, JSC, MON, MRN, NSC, NTC, PII, PPG, RCI, 
SEY, SH, SYR, UCP, WIC. 

AIR, AML, CEL, .CST, DUP, GLC, GRD, MON, PII, QCP, RPC, 
SEY, WIC. 

AIR, AML, BOR, CEL, CIK, DAN, DUP, FLH, GLC, GRD, HRT, 
JSC, MON, NSC, OCF, PPG, PVI, RCI, RPC, SCO, UCP, x. 

ATU, BFG, BOR, CRY, DOW, FIR, GNT, GYR, MON, PNT, THC, 

UCP, x. 
AME, ATU, BFG, BOR, CRY, DA, DOW, ESC, FIR, GNT, GYR, 

MON, PNT, THC, UCP, USR, x. 
AME, BFG, BOR, CRY, CUC, DA, ESC, FIR, GNT, GYR, MON, 

THC, UCP, USR, x. 
ATU, BFG, BOR, CRY, DA, ESC, MON, ONX, THC, UCP, USR, x. 

ATU, BFG, BOR, CRY, DA, DOW, FIR, MON, PNT, THC, UCP, 

USR. 
ATU, BFG, BOR, DA, DOW, FIR, MON. 
BFG, BOR, CRY, DA, DOW, ESC, FIR, GNT, GYR, LAS, MON, 

THC, UCP, USR. 

BFG, BOR, CRY, CUC, DA, KYS, MON, PLA, PNT, THC, UCP, 

USR. 
BFG, BOR, CRY, DA, ESC, FIR, MON, UCP, USR. 
ATU, BFG, BOR, CRY, DA, DOW, ESC, FIR, GYR, LAS, MON, 

PYR, THE, UCP. 
ATU, BFG, BOR, CBR, CMG, CRY, CUC, DA, DOW, ESC, FIR, 

GNT, GRA, GYR, MON, NSC, PNT, PYR, THC, UCP, USR, x. 
ADM, AIR, BEN, BOR, DOW, DUP, FC, FCD, G, GLD, GRD, 

HOU, MCC, MON, NSC, RMC, RPC, SW, UCP. 



ACP, CEL, DOW, DUP, EKX, KPP, MON, 

UCP, USI. 
ACP, DOW, DUP, EKX, KPP, MON, PLC, 

ACP, ALO, CEL, DOW, DUP, EKX, KPP, 

SPN, UCP, USI. 
DOW, DUP, EKX, KPP, MON, PLC, SHC, 
ACP, CEL, DOW, DUP, EKX, KPP, MON, 

UCP, USI. 
CEL, DUP, EKX, KPP, PLC, SPN, UCP, 
ACP, DOW, DUP, EKX, GRP, KPP, PLC, 
ACP, CEL, DOW, DUP, EKX, KPP, MON, 

UCP, USI. 

ACP, CEL, DOW, DUP, EKX, HPC, KPP, 

USI. 
ACP, CEL, DOW, DUP, EKX, GGC, HPC, 

UCP, USI. 

ACP, CEL, DOW, DUP, EKX, GGC, HPC, 

USI. 
ACP, CEL, DUP, EKX, HPC, PLC, UCP. 
ACP, CEL, DUP, EKX, GGC, HPC, KPP, 
ACP, CEL, DOW, DUP, EKX, GGC, HPC, 

USI. 
ACP, CEL, DOW, DUP, EKX, GGC, HPC, 

UCP, USI. 



PLC, RCC, SHC, SPN, 

RCC, SHC, UCP, USI. 

MON, PLC, RCC, SHC, 

SPN, UCP, USI. 

PLC, RCC, SHC, SPN, 

USI. 

UCP, USI. 

PLC, RCC, SHC, SPN, 

PLC, RCC, SHC, UCP, 

KPP, MON, PLC, SHC, 

KPP, PLC, SHC, UCP, 



PLC, SHC, UCP. 
KPP, PLC, SHC, UCP, 



KPP, MON, PLC, RCC, 



PLASTICS AND RESIN MATERIALS 



137 



TABLE 15B. —Plastics and resin materials for which U.S. production or sales were reported, identified by 

manufacturer, 1965 — Continued 



Material and use 


Manufacturers 1 identification codes 
(according to list in table 22) 


THERMOPLASTIC RESINS— Continued 

Polyolefin plastics materials—Continued 
^Polypropylene : 






UCP, USI. 
ACP, ALO, AVS, EKX, ENJ, HPC, PLC, UCP. 






UCP, USI. 
ACG, ACP, CBY, CIB, DEP, DUP, GE, HPC, JSC, KRM, MID, 
MMM, MOB, MRA, RPC, SBC, SCN, SEY, SNW, VSV, WIC. 





SYNTHETIC ORGANIC CHEMICALS, 1965 



Rubber- Processing Chemicals 

TABLE 16B. --Rubber- processing chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1965 

[Rubber-processing chemicals for which separate statistics are given in table 16A are marked below with an asterisk 
(*); chemicals not so marked do not appear in table 16A because the reported data are accepted in confidence and 
may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that 
the manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
( according to list in table 22) 



RUBBER-PROCESSING CHEMICALS, CYCLIC 

^Accelerators, activators, and vulcanizing agents: 
*Aldehyde-amine reaction products: 

Acetaldehyde- aniline condensate 

n-Butyraldehyde- aniline condensate 

Butyraldehyde-butylideneaniline condensate 

a-Ethyl-fS-propylacrylanilide 

Heptaldehyde- aniline condensate 

Triethyltrimethylenetriamine 

*Dithiocarbamic acid derivatives: 

Dibenzyldithiocarbamic acid, sodium salt 

Dibenzyldithiocarbamic acid, zinc salt 

Dibutyldithiocarbamic acid, N,N-dimethylcyclohexylamine 

salt. 

Dibutyldithiocarbamic acid, diphenylguanidine salt 

Dimethylethylene diphenyldithiocarbamic acid, lead salt 

2,4-Dinixrophenyl dimethyldithiocarbamate 

Piperidinecarbodithioic acid, piperidinium- potassium 

salts, mixed. 
Guanidines: 

Dicatechol borate, di-o-tolylguanidine salt 

1, 3-Diphenylguanidine 

Diphenylguanidine phthalate 

1, 3-Di-o-tolylguanidine 

1, 2,3-Triphenylguanidine 

*Thiazole derivatives: 

2-Benzothiazyl N,N-diethylthiocarbamoyl sulfide 

1, 3-Eis(2-benzothiazolylmercaptomethyl)urea 

N-tert-Buty 1-2- benzothiazolesulf enamide 

*N-Cyelohexyl-2-benzothiazolesulf enamide 

N, N-Diisopropyl-2-be nzothiazolesulfenand.de 

N-(2, 6-Dimethy-lmorpholino) -2-ben£othiazolesulf enamide — 

*2,2'-Dithiobis(benzothiazole) 

2-Mercaptobenzothiazole 

2-Mercaptobenzothiazole, zinc chloride 

2-Mercaptobenzothiazole, zinc salt 

4-Morpholi nyl-2-benzothiazyl disulfide 

N-0xydiethylene-2-benzothiazolesulf enamide 

Thiazoline-2- thiol 

All other cyclic accelerators, activators, and vulcanizing 

agents: 

p-Benzoquinonedioxime 

Bis( p- aminocyclohexyl) methane carbamate 

Bis( 2, 6-dimethylmorpholinothiocarbonyl) sulfide 

Dibenzoyl-p-quinonedioxime • 

Dibenzylamine 

N, N'-Dicinnamylidene-l, 6-hexanediamine 

Di-N,N'-pentamethylenethiuram tetrasulfide 

^■i'-Dithiodimorpholine 

2-Imidazoline-2-thiol 

m-Phenylenebismaleimide 

Poly-p-dinitrosobenzene 

Styrene polysulfide 

Tetrahydro-4,4,6-trimethyl-2( lH)-pyrimidinethione 

*Antioxidants, antiozonants, and stabilizers: 

*Amino antioxidants, antiozonants, and stabilizers: 
*Aldehyde- and acetone-amine reaction products: 

Acetaldehyde- aniline hydrochloride condensate 

Aldol-cc-naphthylamine condensate 

Butyraldehyde- aniline condensate 

*Diphenylamine- acetone condensate 

Phenyl-2-naphthylamine-acetone condensate 



USR. 

DUP, MAN, RCD, USR. 

MON. 

CCO. 

USR. 

USR. 

USR. 
USR. 
MON. 

CCO. 
CCO. 
USR. 
DUP. 



DUP. 
ACY. 
MON. 

ACY, DUP. 
NAC. 



PAS. 
MON. 
MON. 
ACY, 
ACY. 
MON. 
ACY, 
ACY, 
DUP. 
ACY, 
GYR. 
ACY, 
ACY. 



BFG, MON, USR. 



BFG, GYR, MON, USR. 
BFG, GYR, MON, USR. 



GYR, USR. 
MON. 



CTA, DUP. 

DUP. 

DUP. 

CTA, USR. 

MLS, USR. 

DUP. 

DUP, VNC. 

MON. 

DUP, RBC. 

DUP. 

DUP. 

TKL. 

VNC. 



USR. 

BFG. 

DUP. 

ACY, BFG, DUP, USR. 

USR. 



RUBBER-PROCESSING CHEMICALS 



139 



TABLE 16B.— Rubber-processing chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1965— Continued 



Manufacturers 1 identification codes 
(according to list in table 22) 



RUBBER-PROCESSING CHEMICALS, CYCLIC— Continued 

•Antioxidants, antlozonants, and stabilizers — Continued 
•Amino antioxidants, antiozonants, and stabilizers — 
Continued 
•Substituted p-phenylenediamines: 

N, N'-Bis( l-ethyl-3-methylpentyl) -p-phenylenediamine- 

N, N'-Bis( l-methyljtieptyl) -p-phenylenediamine 

N-see-Butyl-N'-phenyl-p-phenylenedlamine 

N-Cyclohexyl-N '-phenyl- p-phenylenediamine 

Diary larylenediamines, mixed 

N,N'-Di-2-naphthyl- p-phenylenediamine 

•N,N'-Diphenyl- p-phenylenediamine 

N-Isopropyl-N '-phenyl- p-phenylenediamine 

N-(l-MethyLheptyl)-N' -phenyl- p-phenylenediamine 

All other p-phenylenediamines 

Other amino antioxidants, antiozonants, and stabi- 
lizers: 

p-Anilinophenol 

l,2-Dihydro-6-dodecyl-2,2,4-trimethylquinoline 

l,2-Dihydro-6-ethoxy-2,2,4-trimethylquinoline 

l,2-Dihydro-2, 2,4- trimethylquino line 

4,4'-Dimethoxydiphenylamine 

4,4'-Dioetyldiphenylamine 

N,N'-Diphenylethylenediamine 

N, N'-Diphenyl-l,3-propanediamine 

N, N'-Di-o-tolylethylenediamine 

p- Isopropoxydiphenylamine 

4,4'-Methylenedianiline 

*Octyldiphenylamine 

Octyldiphenylamine mixture (mono-, nonyl-, and di-)> 

N-Phenyl-1-naphthylamine 

N-Phenyl-2-naphthylamine 

Tetramethyldiphenylethylenediamine 

p-(p-Toluenesulfonamido)diphenylamine 

•Phenolic and phosphite antioxidants and stabilizers: 
Phosphites: 

Nonyl phenyl phosphites, mixed 

Polyphenolie phosphite, polyaliylated 

Polyphenolics ( including bisphenols) : 

4,4'-Butylidenebis(6-tert-butyl-m-cresol) 

2,5-Di-(l,l-dimethylpropyl)hydroquinone 

2, 2'-Methylenebis(6-tert-butyl-p-cresol) 

2,2'-Methylenebis(6-tert-butyl-4-ethylphenol) 

2,2'-Methylenebis(6-tert-octyl-p-cresol) 

2,2'-Thiobis(4, 6-di-sec-amylphenol) 

4,4'-Thiobis(6-tert-butyl-m-cresol) 

1, l,3-Tri(2-methyl-4-hydroxy-5-tert-butylphenyl)- 
butane. 
Other phenolic antioxidants and stabilizers: 

p-Benzyloxyphenol 

N-Butyroyl-p-aminophenol 

o-Cresol, alkylated 

N-Lauroyl-p-aminophenol 

•Phenol, alkylated 

Phenol, hindered 

Phenol, styrenated 

N-Stearoyl-p-aminophenol 

Xylenol, alkylated 

•Blowing agents: 

N,N'-Dimethyl-N,N'-dinitrosoterephthalamide 

Dinitrosopentamethylenetetramine 

p,p'-Oxybis(benzenesulfonhydrazide) 

•Peptizers: 

Alkylated o-thiocresol 

Alkylated thiophenol, zinc salt 

Aryl mercaptans 

2-Benzamidothiophene, zinc salt 

2',2'"-Dithiobis(benzanilide) 

Dixylyl disulfides, mixed 

2-Naphthalene thiol 



EKT, 


MON, 


UPM. 




BFG, 


EKT, 


MON, 


UPM. 


USR. 








USR. 








GYR. 








BFG. 








BFG, 


DUP, 


USR. 




MON, 


USR. 






UPM. 








EKT, 


MON. 






BFG. 








MON. 








MON. 








BFG, 


MON. 






DUP. 








BFG. 








CCO, 


X, X 






CCO. 








CCO. 








BFG. 








USR. 








ACY, 


NPI, 


PAS, 


USR. 


BFG. 








DUP. 








BFG, 


DUP. 







USR. 
BFG. 

MON. 

MON. 

ACY, CAT. 

ACY. 

ACY. 

MON. 

MON. 

ICI. 



BFG. 

MLS. 

PIT. 

MLS. 

ACY, BFG, CCO, GYR, PAS, PIT, USR. 

DUP, GYR, PIT. 

BFG, GYR. 

MLS. 

PIT. 

DUP. 

DUP, NPI. 
USR. 

PIT. 

PIT. 

PIT. 

ACY. 

ACY. 

DUP, PIT. 

DUP. 



140 



TABLE 16B. 



SYNTHETIC ORGANIC CHEMICALS, 1965 

—Rubber-processing chemicals for which U.S. production or sales were reported identified by 
manufacturer, 1 965- -Continued 



RUBBER-PROCESSING CHEMICALS, CYCLIC— Continued 

♦Peptizers — Continued 

Pentachlorobenzene thiol 

Pentachlorobenzenethiol, zinc salt 

Thioeresol 

Thiophenol ( Benzenethiol) 

Xylenethiol 

Other cyclic rubber-processing chemicals: 

p-tert-Amylphenol sulfide ( taclcifier) 

Dicresyl disulfide 

N,4-Dinitroso-N-methylaniline ( physical- property 
improver) . 
♦N-Nitrosodiphenylamine ( retarder) 

RUBBER-PROCESSING CHEMICALS, ACYCLIC 

♦Accelerators, activators, and vulcanizing agents: 
♦Dithiocarbamic acid derivatives: 

Dibutyldithiocarbamic acid, potassium salt 

Dibutyldithiocarbamic acid, sodium salt 

♦Dibutyldithiocarbamic acid, zinc salt 

Diethyldithiocarbamic acid, cadmium salt 

Diethyldithiocarbamic acid, selenium salt 

Diethyldithiocarbamic acid, sodium salt 

Diethyldithiocarbamic acid, 

♦Diethyldithiocarbamic acid, 
Dimethyldithiocarbamic acid, 
Dimethyldithiocarbamic acid, 
Dimethyldithiocarbamic acid, 
Dimethyldithiocarbamic acid, 
Dimethyldithiocarbamic acid, sodium salt and sodium 
polysulfide. 

♦Dimethyldithiocarbamic acid, zinc salt 

All other 

♦Thiurams : 

Bis( dibutylthiocarbamoyl) sulfide 

Bis( diethylthiocarbamoyl) disulfide 

♦Bis( dimethylthiocarbamoyl) disulfide 

Bis( dimethylthiocarbamoyl) disulfide and 2-mercapto- 
benzothiazole, mixed. 

*Bis( dimethylthiocarbamoyl) sulfide 

Bis( ethylmethylthiocarbamoyl) sulfide 

Thiuram blend 

Xanthates and sulfides: 

Di-n-butylxantho disulfide 

Diisopropylxantho disulfide 

Zinc dibutyl xanthate 

All other acyclic accelerators, activators, and vulcan- 
izing agents: 

n-Butyraldehyde-butylamine condensate 

Pi- n- butyls mmonium oleate 

N, N'-Dibutyldithioadipamide 

3- Ethyl- 1, 1-dimethy 1-2- thiourea 

Ethylenediamine carbamate 

Polyoxyalkalenetetrasulfide 

1,1,3-Trimethy 1-2- thiourea- 



tellurium salt- 
zinc salt 

bismuth salt- 
copper salt 

lead salt 

selenium salt- 



Manufacturers' identification codes 
(according to list in table 22) 



DUP. 
DUP. 
PIT. 
PIT. 
DUP. 

PAS. 
USR. 
CTA, MON. 

BFG, CTA, GYR, USR. 



PAS, USR, VNC. 

DUP, PAS, REC, USR, VNC. 



PAS, USR. 

GYR, PAS, RBC, USR, VNC. 



VNC. 
DUP, 
ALC, 
VNC. 
VNC. 
ALC, 
VNC. 
ALC, 
VNC. 
VNC. 
VNC. 
VNC. 
BFG, 



ALC, DUP, FMN, GYR, PAS, RBC, USR, WRC. 
PAS. 

USR. 

DUP, GYR, PAS, VNC. 

BFG, DUP, GNT, GYR, PAS, RBC, USR, VNC. 

VNC. 

DUP, GYR, USR. 

VNC. 

DUP. 

USR. 
BFG. 
USR. 



DUP. 
DUP. 
DUP. 
VNC. 
DUP. 
TKL. 
VNC. 



RUBBER-PROCESSING CHEMICALS 



141 



TABLE 16B. — Rubber-processing chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 2S65--Contlnued 



Chemical 


Manufacturers' identification codes 
( according to list in table 22) 


RUBBER-PROCESSING CHEMICALS, ACYCLIC— Continued 
Blowing agents: 






SW. 

DUP. 
DUP. 
DUP. 

PAS, PLC. 


Conditioning and lubricating agents: 

Methyl stearyl-10-sulfonic acid, sodium salt 

Mono- and dialkyl phosphate ammonium salts, mixed 

Polymerization regulators: 


Shortstops: 

Dimethyldithiocarbamic acid, potassium salt 

Other acyclic rubber-processing chemicals: 

Zinc laurate (activator, physical- property improver) 


GYR, PAS, USR. 

ALC, BFG, DUP, GYR, PAS. 

USR. 







SYNTHETIC ORGANIC CHEMICALS, 1965 



Elastomers (Synthetic Rubbers) 



TABLE 17B.-- Elastomers (synthetic rubbers) for which U.S. production or sales were reported, identified by 

manufacturer , 1965 



[Elastomers (synthetic rubbers) for which separate statistics are given in table 17A are marked below with an as- 
terisk (*); products not so marked do not appear in table 17A because the reported data are accepted in confidence 
and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies 
that the manufacturer did not consent to his identification with the designated product] 



Product 


Manufacturers ' identification codes 
(according to list in table 22) 


ELASTOMERS, CYCLIC 


ASY, BFG, CPY, FIR, FRS, GGC, GNT, GYR, ILC, MCB, PLC, 

RUB, SHC, TUS, URC, USR, WIC. 
ASY, BFG, FIR, FRS, GNT, GYR, PLC, USR, WIC. 
ACY, BFG, DUP, GNT, MOB, PRC, TKL, USR. 

ACY, BFG, TKL. 

TKL. 

BFG, FRS, GYR, TKL, TUS. 

BFG, FRS, GYR, ILC, MCB, USR. 

DUP. 

CBN, ENJ. 

GYR, HPC. 

DCC, SPD, UCS. 

ASY, BAR, DUP, ENJ, FRS, GGC, GNT, GYR, PLC, SHC, TUS. 

DUP, x. 






ELASTOMERS, ACYCLIC 










*Polyisobutylene-isoprene type (Butyl) 


<3+ 





Plasticizers 

TABLE 18B. — Plasticizers for which U.S. production or sales were reported, identified by 

manufacturer, 1965 

[Plasticizers for which separate statistics are given in table 18A are marked below with an asterisk (*); products 
not so marked do not appear in table 18A because the reported data are accepted in confidence and may not be pub- 
lished. Manufacturers' identification codes shown below are taken from table 22] 



Manufacturers' identification codes 
(according to list in table 22) 



PLASTICIZERS, CYCLIC 

Coumarone-indene plasticizer 

N-Cyclohexyl-p-toluenesulfonamide 

Diethylene glycol dibenzoate 

Di-tert-octyldiphenyl oxide 

Dipropanediol dibenzoate 

N-Ethyl-p-toluenesulfonamide 

Isopropylidenediphenoxypropanol 

Naphthalene, alkylated 

Phosphoric acid esters: 

*Cresyl diphenyl phosphate 

Dibutyl phenyl phosphate 

Diphenyl mono-o-xenyl phosphate 

Diphenyl octyl phosphate 

Methyl diphenyl phosphate 

*Tricresyl phosphate 

Triphenyl phosphate 

All other phosphoric acid esters 

*Phthalic anhydride esters: 

Alkyl benzyl phthalates 

Butyl benzyl phthalate 

Butyl cyclohexyl phthalate 

Butyl decyl phthalate 

*Butyl 2-ethylhexyl phthalate 

n-Butyl isodecyl phthalate 

*Butyl octyl phthalate 

Butyl phthalyl butyl glycolate 

Di(2-butoxyethyl) phthalate 

*Dibutyl phthalate 

*Dicyelohexyl phthalate 

*Diethyl phthalate 

*Dihexyl phthalate 

Diisobutyl phthalate 

*Diisodecyl phthalate 

»Di(2-methoxyethyl) phthalate 

Dimethyl cyclohexyl phthalate 

Dimethyl isophthalate 

*Dimethyl phthalate 

Dinonyl phthalate 

*Dioctyl phthalates: 

Dicapryl phthalate 

Di(ethylhexyl)isophthalate 

*Di(2-ethyLhexyl) phthalate 

*Diiso-octyl phthalate 

Di-n-octyl phthalate 

*Mixed dioctyl phthalates 

Diphenyl phthalate 

*Ditridecyl phthalate 

2-EthyLhexyl isodecyl phthalate 

Ethyl (and methyl) phthalyl ethyl glycolate 

Glycol phthalic esters 

Hexyl n-decyl phthalate 

Hexyl isodecyl phthalate 

Hydrogenated castor oil phthalate 

Isodecyl tridecyl phthalate 

*0ctyl decyl phthalates: 

Iso-octyl isodecyl phthalate 

n-Octyl n-decyl phthalate 

All other phthalic anhydride esters 



NEV. 














MON. 














VEL. 














DOW. 














VEL. 














MON. 














DOW. 














ACC. 














FMP, 


MON, MTR, SF, SM. 












MON. 














DOW. 














MON. 














FMP, 


MON. 












FMP, 


MON, MTR, SF. 












DOW, 


EK, MON, SF. 












SF. 














MON. 














GRH, 


MON. 












ACP. 














ACP, 


PCC. 












ACP, 


MON, UCC. 












GRH, 


UCC. 












GRH, 


PCC, RCI, RUB. 












MON. 














FMP, 


WM. 












ACP, 


COM, DUP, EKT, ENJ, GRH, 


HAL, 


LAS, 


MON, 


PCC, 


PFZ 


RCI, RUB, SW, UCC, WTH. 












ACP, 


DUP, FMP, MON, PFZ. 












DUP, 


EKT, KF, MON, PFZ. 












ACP, 


ENJ, GRH, LEH, THC. 












EKT, 


UCC. 












ACP, 


BFG, EKT, ENJ, GRH, MON, 


PCC, 


PFZ, 


RCI, 


RUB, 


THC 


UCC, WTH. 












DUP, 


EKT, FMP, RCI, SF. 












DUP. 














PFZ. 














ACP, 


EKT, KF, MON, PFZ. 












RCI. 















ACP, GRH, WTH. 

UCC. 

ACP, BFG, EKT, ENJ, GRH, LEH, MON, PCC, PFZ, RCI, RUB, 

THC, UCC, WTH. 
ACP, BFG, EKT, ENJ, GRH, LEH, MON, PCC, PFZ, RCI, RUB, 

THC, UCC. 
ADM. 

ACP, GRH, UCC, WTH. 
MON. 

ACP, ENJ, GRH, MON, PCC, PFZ, RCI, RUB, THC, UCC. 
UCC. 
MON. 

ARG, HPC. 
ACP, UCC. 
PFZ. 
DUP. 
THC. , 

ACP, PCC. 

ACP, GRH, HPC, MON, PCC, PFZ, RCI, RUB, THC, UCC. 

FMP, LEH, MON, PCC, UCC. 



144 



SYNTHETIC ORGANIC CHEMICALS. 1965 



TABLE 18B. — Plasticizers for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



PLASTICIZERS, CYCLIC— Continued 

Polyethylene glycol dibenzoate 

Tetrahydrofurfuryl oleate 

Toluenesulfonamide, o-, p- mixtures 

Triethylene glycol dibenzoate 

*Trimellitic acid esters 

All other cyclic plasticizers 

PLASTICIZERS, ACYCLIC 

*Adipic acid esters: 

Di(2-(2-butoxyethoxy)ethyl) adipate 

*Di ( 2-ethylhexyl ) adipate 

Diisobutyl adipate 

*Diisodecyl adipate 

*Diiso-octyl adipate 

Dinonyl adipate 

Di-n-octyl adipate 

Di-tridecyl adipate 

Iso-octyl isodecyl adipate 

*Octyl decyl adipate 

Polyethylene glycol adipate 

All other adipic acid esters 

*Azelaic acid esters: 

Di ( 2-ethyLhexyl ) azelate 

Di-n-hexyl azelate 

Diisobutyl azelate 

Diiso-octyl azelate 

Dioctyl azelate 

All other azelaic acid esters 

Citric and acetylcitric acid esters 

^Complex linear polyesters and polymeric plasticizers- 

Di(2-(2-butoxyethoxy)ethyl)methane 

Diethylene glycol dinonanoate 

Diiso-octyl diglycolate 

*Epoxidized esters: 

Butyl epoxydioleate 

Butyl epoxytallate 

Epoxidized linseed oils 

*Epoxidized soya oils 

*2-Ethylhexyl epoxytallates 

Octyl epoxystearates 

*Octyl epoxytallates 

All other epoxidized esters 

Glycerol pelargonate 

Glyceryl tributyrate and tripropionate 

Glycol pelargonate 

Isodecyl maleate 

Isodecyl nonanoate (Isodecyl pelargonate) 

Laurie acid esters 

Myristic acid esters: 

Butyl myristate 

*Isopropyl myristate 

*01eic acid esters: 

*Butyl oleate 

^Glycerol trioleate (Triolein) 

*Isopropyl oleate 

*Methyl oleate 

*n-Propyl oleate 

*A11 other oleic acid esters 

Palmitic acid esters: 

Isobutyl palmitate 

*Isopropyl palmitate 

2-Methoxyethyl palmitate 

All other palmitic acid esters 

^Phosphoric acid esters: 

Tri(2-butoxyethyl) phosphate 

Tri(2-chloroethyl) phosphate 

Triethyl phosphate 



VEL. 

CCW, EMR. 

ACY, MON. 

VEL. 

PCC, PFZ, RUB. 

CCW, EKT, MON, NEV, WTH. 



TKL. 



FMP, 
EKT, 
FMP, 
ACP, 
GRH, 
THC. 
ACP. 
LEH. 
BFG, 
ACP, 
PFZ. 
ACP, ARC, EKX, PCC, PFZ, VND. 



LEH, MON, PCC, RCI, RH, RUB, THC, UCC, WTH. 
GRH, HAL, RCI. 

EKT, GRH, LEH, MON, PCG, RCI, RH, RUB, THC, UCC, WTH. 
LEH, PCC, RCI, RH, RUB, WTH. 



NOP, RCI. 

GRH, MON, PCC, RCI, RH, RUB, THC, TKL, UCC. 



DUP, EKT, EMR, PFZ, RCI, RH, RUB, THC, UCC. 

UCC. 

HAL, RCI. 

EMR, PFZ. 

PFZ. 

ACP, EMR, PFZ. 

PFZ. 

ADM, EKT, EMR, GLY, HAL, LEH, MON, PFZ, RH, RUB, WM, 

WTH. 
GRD. 

EMR, RUB. 
CCA, FMP. 



THC. 

SWT. 

ARG, BAC, RCI, RH, SWT, THC, UCC. 

BAC, UCC. 

RH, THC, UCC. 
RH. 



ADM. 
ADM, 
ADM, 
ADM, 
ADM, 
ARG. 
ARG, 
EMR, 
EMR. 
EKT. 
EMR. 
LEH. 
EMR. 
HAL. 



ARC, ICI. 

ARC, ICI, NOP, PRP. 

ARC, HAL, ICI, LAS, NOP, SWT, WM, WTH. 

DRW, EMR, SWT, WM. 

ARC, ICI, WM. 

CHL, EMR, ICI, NOP, SWT. 

CHL, EMR, WM. 

ARC, DRW, HAL. 

ARC, EKT. 

ARC, EMR, ICI, PRP, WM. 

EKT. 

EKT, RUB. 

FMP, MON, SF, WES. 

UCC. 

EKT. 



PLASTICIZERS 



145 



TABLE 18B. --Plasticizers for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



PLASTICIZERS, ACYCLIC— Continued 

•Phosphoric acid esters — Continued 

Trioctyl phosphate 

All other phosphoric acid esters 

Ricinoleic and acetylricinoleic acid esters: 

n-Butyl acetylricinoleate 

Butyl ricinoleate 

•Glycerol monorieinoleate 

Glyceryl tri( acetylricinoleate) 

Methyl ricinoleate 

All other ricinoleic and acetylricinoleic acid esters 

Sebacic acid esters: 

Dibutoxyethyl sebacate 

*Dibutyl sebacate 

*Di(2-ethylhexyl) sebacate 

All other sebacic acid esters 

•Stearic acid esters: 

Butoxyethyl stearate 

*n-Butyl stearate 

Glycerol triacetyl stearate 

Glycerol tristearate 

Methoxyethyl stearate 

Methyl diohlorostearate 

Methyl pentachlorostearate 

Methyl stearate 

All other stearic acid esters 

Sucrose acetate isobutyrate 

Tetraethylene glycol di(2-ethylhexanoate) 

*Triethylene glycol di(caprylate-caprate) 

Triethylene glycol di-2-ethylbutyrate 

Methylene glycol di(2-ethylisohexoate) 

Trimethyl pentanediol diisobutyrate 

All other acyclic plasticizers 



Manufacturers ' identification codes 
(according to List in table 22) 



FMP, UCC. 

SM. 

BAC, WTH. 

BAC, RCI. 

BAC, GLY, HAL, NOP. 

BAC. 

BAC. 

ARC, BAC, RCI. 

RCI. 

EKT, GRH, HAL, PFZ, RCI, RH, WTH. 

GRD, GRH, HAL, PCC, RCI, RH, HUB, WTH. 

ARC, LEH, NOP, PCC, RCI, RH, HOB. 



ARC. 

ARC, 

BAC. 

DRW. 

ARC. 

HK. 

HK. 

CHL. 

ARC, 

EKT. 

UCC. 

DRW, 

UCC. 

EKT. 

EKX. 

ARC, 



CHL, EMR, HAL, ICI, LAS, SCP, SWT, WTH. 

FMP, HPC, PRP, RCI, RH, Hi. 
FOR, HAL, RUB. 

EMR, HAL, HPC, LEH, PFZ, RH, RUB, TKL, UCC, WM. 



SYNTHETIC ORGANIC CHEMICALS, 1965 



Surface-Active Agents 



TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer, 1965 

[Surface-active agents for which separate statistics are given in table 19A are marked below with an asterisk (*); 
products not so marked do not appear in table 19A because the reported data are accepted in confidence and may not 
be published. Manufacturers ' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Manufacturers ' identification codes 
(according to list in table 22) 



BENZENOID SURFACE-ACTIVE AGENTS 

Not Sulfated or Sulfonated 

*Amides, amines, and quaternary ammonium salts: 

*Benzyldimethyl(mixed alkyl) ammonium chloride 

*Benzyldimethyloctadeey lammonium chloride 

*Benzyldodeeyldimethylammonium chloride 

*( 3, 4^ Dichlorobenzyl)dodecyldimethy lammonium chloride 

*(Dodecylbenzyl)trimethylammonium chloride 

^Heterocyclic compounds : 

l-Benzyl-2-( coconut oil alkyl)-l-(2-hydroxyethyl)-2- 
imidazolinium chloride. 
*l-Benzyl-2-heptadecyl-l-( 2-hydroxyethyl) -2-imidazo- 
linium chloride. 
l-Benzyl-l-(2-hydroxyethyl)-2-nor(tall oil alkyl)-2- 
imidazolinium chloride. 

l-Benzyl-2-picolinium bromide 

1-Benzylpyridinium chloride 

2-Dodecylisoquinolinium bromide 

1-Dodecylpyridinium chloride 

2-(2-Lauroyloxyethyl)carbamoyl-l-methylpyridinium 

chloride. 
l-Methyl-2- ( 2-stearoyloxyethyl) carbamoylpyridinium 
chloride. 
*Oxygen- containing compounds (except heterocyclic): 
Benzylbis ( 2-hydroxyethyl ) ( 2-stearamidomethoxyethyl) - 

ammonium chloride. 
Benzyl( coconut oil alkyl )bis ( 2-hydroxyethyl )a,mmonium 

chloride . 
Benzyl( coconut oil amidopropyl ) dime thy lammonium 

chloride. 
Benzyl( ethoxylated coconut oil alkyl )dimethy lammonium 

chloride. 
( Ethoxybenzyl ) dimethyl ( oc tylphenoxy ) ammonium chloride — 
(Ethoxybenzyl) dime thyl(octyltolyloxy) ammonium chloride- 

N- ( 2-Hydroxyethyl ) -1, 2-diphenylethylenediami ne 

o-Isopropoxyphenyl N-methylcarbamate 

(Tridecylbenzyl)diethyl( 2-hydroxyethyl) ammonium 
chloride. 
*A11 other: 

Benzylbis (hydrogenated tallow alkyl )methy lammonium 
chloride. 

Benzyl( coconut oil alkyl) dime thy lammonium chloride 

Benzyldimethyltetradecy lammonium chloride 

Benzylhexadecyldimethy lammonium chloride 

Benzyl( hydrogenated tallow alkyl ) dime thy lammonium 
chloride. 

Benzyl( soybean oil alkyl) dimethy lammonium chloride 

Benzyltrimethy lammonium chloride 

(Dodecylbenzyl) dimethy loctadecy lammonium chloride 

(Dodecylbenzyl)triethylammonium chloride 

( Dodecylmethylbenzy 1 ) trimethy lammonium chloride 

(Ethylbenzyl)dimethyl(mixed alkyl) ammonium chloride 

*Carboxylic acid esters and ethers : 

*Dinonylphenol, ethoxylated 

*Dodecylphenol, ethoxylated 

*Iso-octylphenol, ethoxylated 

*Nonylphenol, ethoxylated 

*Phenol, ethoxylated 



AAC, BC, BRD, CUL, FIN, ONX, PCS, PG, RH, RTF, TXT, 

VAC, WSN. 
APX, ONX, PCS, RET, WSN. 
DEP, FIN, ONX, SDH, WSN. 
CUL, FIN, ONX, VAC, WSN. 
BC, CUL, NLC, RCD, WTC. 



NLC. 



PCS, TXT, 


UVC 


NLC. 




FIN. 




DEP. 




CUL, ONX. 




BC, HK. 




WTC. 





WTC. 

CIB. 

CIB. 

TXT. 

G. 

RH. 
RH. 
APX. 



TXT. 



BC, CRT. 
SNW, WSN. 
ONX, RH. 
TXT. 

TXT. 

COM. 

AML. 

PC. 

RH. 

ONX. 

G, JCC, STP. 

G, MON, PCS, UCC. 

APX, CIB, DRW, NOP, CMC. 

APD, CIB, CLY, DOW, DRW, G, HFC, JCC, MON, NLC, CMC, 

PCS, RH, RTF, STP, UCC. 
APD, G, JCC, NOP, UCC. 



SURFACE-ACTIVE AGENTS 



147 



TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



BENZENOID SURFACE- ACTIVE AGENTS— Continued 

Not Sulfated or Sulfonated--Continucd 

*Carboxylic acid esters and ethers — Continued 
*Other earboxylic acid esters and ethers : 
Alkylphenol - formaldehyde, alkoxylated : 

(Mixed aliyl) phenol - formaldehyde, aLkoxylated 

Nonylphenol - formaldehyde, alkoxylated 

tert-Octylphenol - formaldehyde, ethoxylated 

Pentylphenol - formaldehyde, alkoxylated 

Diisobutylphenol, ethoxylated 

(Mixed alkyl)phenol, ethoxylated 

(Mixed alkyljphenol, ethoxylated, butyl ether 

(Mixed aliyl)phenoxypoly(ethyleneoxy) ethyl chloride 

Nonylphenol, ethoxylated and propoxylated 

Nonylphenoxypoly(ethyleneoxy) ethyl iodide 

n-Octylphenol, ethoxylated 

Pentylphenol, ethoxylated 

Phthalic acid, octadecyl ester, potassium salt 

Tetradecylphenol, ethoxylated 

Tridecylphenol, ethoxylated 

Xylenol, ethoxylated 

All other 

*Phosphoric and polyphosphoric acid esters : 

Dinonylphenol, ethoxylated and phosphated 

Hexylphenol, ethoxylated and phosphated 

*Nonylphenol, ethoxylated and phosphated 

Nonylphenol, ethoxylated and phosphated, barium salt 

Octylphenol, ethoxylated and phosphated 

Octylphenol, ethoxylated and phosphated, magnesium salt- 
Phenol, ethoxylated and phosphated 

Sulfated and Sulfonated 

*ALkylphenols, ethoxylated and sulfated: 

Dodecylphenol, ethoxylated and sulfated 

Dodecylphenol, ethoxylated and sulfated, potassium salt- 

(Mixed alkyl)phenol, ethoxylated and sulfated 

»Nonylphenol, ethoxylated and sulfated, and salts: 

Nonylphenol, ethoxylated and sulfated 

Nonylphenol, ethoxylated and sulfated, ammonium salt — 

Nonylphenol, ethoxylated and sulfated, sodium salt 

Nonylphenol, ethoxylated and sulfated, triethanolamine 
salt. 

n-Octylphenol, ethoxylated and sulfated 

*Benzenesulfonates : 

*Benzene-, cumene-, toluene-, and xylenesulfonates : 

Benzenesulfonic acid, sodium salt 

Cumenesulfonic acid, ammonium salt 

2,4- Dinitrobenzenesulfonic acid, sodium salt 

Ethylene glycol dibenzenesulfonate 

Toluenesulfonic acid 

p-Toluenesulfonic acid, hexadecyltrimethylammonium 
salt. 

Toluenesolfonic acid, potassium salt 

Toluenesulfonic acid, sodium salt 

*Xylenesulfonic acid, ammonium salt 

Xylenesulfonie acid, potassium salt 

*Xylenesulfonic acid, sodium salt 

^Branched chain alkylbenzenesulf onates : 

Decylbenzenesulfonic acid, sodium salt 

Didodecylbenzenesulfonic acid 

Didodecylbenzenesulfonic acid, sodium salt 

*Dodecylbenzenesulfonic acid 

Dodecylbenzenesulfonic acid, ammonium salt 

Dodecylbenzenesulfonie acid, butylamine salt 

^Dodecylbenzenesulfonic acid, calcium salt 

Dodecylbenzenesulfonic acid, diethanolamine con- 
densate, fatty acid monoester. 
Dodecylbenzenesulfonic acid, diethanolamine salt 



NLC, RTF. 

RTF. 

SDW. 

RTF. 

G, RH. 

G, PCS. 

RH. 

G. 

STP. 

G. 

ICI. 

RTF. 

CIB. 

0R0. 

PCS. 

NLC. 

RH. 



RZL. 



G, NLC, RTF, RZL, SEY, TCC, TCI, TXT, WAY, WSN, WTC. 

G. 

RH. 



G, LEV, TCI. 

STP. 

G. 

CRT, G, OMC, WTC. 

CIB, MYW, RCD, STP, TXT. 

STP. 



RH, TXT. 



NES, UPF. 

STP. 

NES. 

NES. 

RCD. 

FIN. 

MTW, NES, RCD, STP, WTC. 

CO, NES, PIL, RCD, STP, WTC. 

ATR, CO, NES, RCD, STP, WTC. 

MTW, NES, STP. 

ATR, CO, MYW, NES, PIL, RCD, STP, WTC. 

MON. 

CO. 
CO. 
ARD, CO, CRT, LEV, MON, NAC, PIL, RCD, RTF, SEY, STP, 

TCI, TDC, TEN, TXT, WTC. 
ARL. 
WTC. 

APD, CO, NLC, RCD, RH, RTF, SMC, STP, WTC. 
MAH. 

PCS, VAL, WON. 



148 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 19B. —Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Chemical 



BENZENOID SURFACE- ACTIVE AGENTS- -Continued 

Sulfated and Sulfonated--Continuei 

*Benzenesulf onates — Continued 

*Branehed chain aliylbenzenesulfonates--Continued 

Dodecylbenzenesulfonie acid, ethylenediamine salt 

Dodecylbenzenesulfonic acid, isopropanolamine salt 

*Dodeeylbenzenesulfonic acid, isopropylamine salt 

*Dodeeylbenzenesulfonic acid, (mixed aliyl) amine salt 

Dodecylbenzenesulfonie acid, potassium salt 

Dodecylbenzenesulfonic acid, propoxylated ethylene- 
diamine salt. 

^Dodecylbenzenesulfonic acid, sodium salt 

Dodecylbenzenesulfonie acid, strontium salt 

^Dodecylbenzenesulfonic acid, triethanolamine salt 

Nonylbenzenesulfonic acid, sodium salt 

Pentadeeylbenzenesulfonic acid, potassium salt 

Pentadecylbenzenesulfonic acid, sodium salt 

Pentylbenzenesulfonic acid, sodium salt 

Tridecylbenzenesulfonie acid 

Tridecylbenzenesulfonic acid, ammo nium salt 

Tridecylbenzenesulfonie acid, sodium salt 

*Straight chain alkylbenzenesulfonates : 

^Dodecylbenzenesulfonie acid 

Dodecylbenzenesulfonie acid, ammonium salt 

Dodecylbenzenesulfonic acid, isopropylamine salt 

*Dodecylbenzenesulfonie acid, sodium salt 

^Dodecylbenzenesulfonic acid, triethanolamine salt 

Tridecylbenzenesulfonic acid 

Tridecylbenzenesulfonic acid, sodium salt 

*Lignosulf onates : 

Lignosulfonic acid, aluminum salt 

Lignosulfonic acid, ammonium salt 

*Lignosulfonie acid, calcium salt 

Lignosulfonic acid, chromium salt 

Lignosulfonic acid, iron salt 

Lignosulfonic acid, magnesium salt 

^Lignosulfonic acid, sodium salt 

*Naphthalenesulf onates : 

Benzylnaphthalenesulfonic acid 

Butylnaphthalenesulfonic acid 

*Butylnaphthalenesulfonic acid, sodium salt 

DibutyLnaphthalenesulfonic acid 

Didodecylnaphthalenesul fonic acid, sodium salt 

*Diisopropylnaphthalenesn1 fonie acid 

Diisopropylnaphthalenesulfonic acid, sodium salt 

Dipentylnaphthalenesulfonic acid 

Dipentylnaphthalenesulfonic acid, ammonium salt 

Dipentylnaphthalenesulfonic acid, (mixed aliyl) amine salt 

Isopropylnaphthalenesul fonic acid 

Methylenebis(2-naphthalenesulfonic acid) 

6,6'-Methylenebis(2-naphthalenesulfonic acid), calcium 
salt. 

MethyLnaphthalenesulfonic acid, sodium salt 

JfethylnonyLnaphthalenesulfonic acid, sodium salt 

Tetrahydronaphthalenesulfonic acid, sodium salt 

Other benzenoid surface-active agents, sulfated and 
sulfonated : 

ButyLhydroxybiphenylsulfonic acid 

Dodecyldiphenyloxidedisulfonic acid, sodium salt 

HpptnHppyliTigt.hylbgngiiiririg'an'liTipgiilfnrnp acid, Sodium 

salt. 
n-Octylphenol, ethoxylated and sulfonated 

Petroleumsulfonic acid, water soluble (acid layer), 
sodium salt. 

5-Sulfophthalic acid, diaDsyl ester, potassium salt 

Trichlorophenol sulfate, ethanolamine salt 



Manufacturers ' identification codes 
(according to list in table 22) 



APD. 

SMC. 

APD, AHD, RCD, RTF, SNW, STP, WTC. 

PCS, RTF, STP, WTC. 

VAL. 

PCS. 

AAC, APX, ARD, ARL, ATR, CO, CP, CRT, DEP, EFH, EMK, 
HLI, HRT, ICI, LEV, MON, NAC, NOP, PG, PIL, RCD, 
SEY, STP, SWT, TEN, TXT, WIC, WON, WTC. 

RTF. 

AML, ARD, ARL, ATR, CRT, HLI, NAC, PCS, PEK, PIL, RCD, 
RTF, SOS, STP, SWT, TXT, VAC, WON, WTC. 

WTC. 

STP. 

CP. 

MON. 

RCD. 

RCD. 

CP, TXT, WTC. 

ARD, CO, HLI, LEV, NAC, PIL, PRX, RCD, RTF, RZL, STP, 

TCI, TXT. 
CTL, TXT. 
CTL, RCD. 
ARD, ATR, CO, CP, CTL, LEV, NAC, PG, PIL, PRX, RCD, 

STP, SWT, TXT, UNP. 
ARD, ATR, CTL, NAC, RCD, RZL, STP, SWT, TXT. 
RCD. 
BLA, CP, PRX, RCD, TXT, UCC. 



MAR. 






CRZ. 






CRZ, 


CWP, LKY, 


LPC, MAR, PSP 


MAR, 


PSP. 




CRZ, 


PSP. 




LPC, 


MAR. 




CRZ, 


CWP, MAR, 


WVA. 


G. 






SCP. 






CLD, 


CMG, GGY, 


PFZ. 


G, MRA, S. 




PFZ. 






DUP, 


G, GRD, NAC. 


G, PFZ. 




GGY. 






NLC. 






NLC. 






DUP, 


NOP, ONX. 




DUP. 






DUP. 






UDI. 






UDI. 






DUP. 






ICO, 


RBC. 




DOW. 






CIB. 







SIN, SON. 



SURFACE-ACTIVE AGENTS 



149 



TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1 965- -Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



NONBENZENOID SURFACE-ACTIVE AGENTS 
Not Sulfated or Sulfonated 

*Amides, amines, and quaternary ammonium salts: 

*Amines, amine oxides, and amine salts (except hetero- 
cyclic) : 
*Amine salts of fatty acids (anionic): 

Coconut oil acids, triethanolamine salt 

Oleic acid, diethylamine salt 

Oleic acid, N-(tallow allsyl ) trimethylenedianri ne 
salt. 

Oleic acid, triethanolamine salt 

Stearic acid, N,N,N',N'-tetrakis(2-hydroxyethyl)- 
ethylenediamine salt. 

Stearic acid, triethanolamine salt 

^Amines, not containing oxygen, and salts thereof: 
"Amine salts ( cationic ) : 

(Coconut oil allsyl) amine acetate 

N-( Coconut oil allsyl) trimethylenediamine acetate--- 

( Hydrogenated tallow aliyl)amine acetate 

(9-0ctadecenyl) amine acetate 

Octadecylamine acetate 

Octylamine acetate 

(Soybean oil allsyl) amine acetate 

(Tallow aliyl)amine acetate 

N-(Tallow alkyl) trimethylenedianri ne acetate 

N-(Tallow aliyl)trimethylenediamine naphthenate 

"Diamines and polyamines : 

N-( Coconut oil alliyl ) trimethylenedianri ne 

N-(Mixed allsyl) polyethylenepolyamine 

*N-(9-0ctadecenyl)trimethylenediamine 

N-(Soybean oil allsyl) trimethylenediamine 

N-( Tallow allsyl )dipropylenetriamine 

*N-( Tallow allsyl) trimethylenediamine 

"Primary monoamines : 

*( Coconut oil aliyl)amine 

(Cottonseed oil allsyl) amine 

"Dodecylamine 7 

Hexadecylamine 

*( Hydrogenated tallow aliyl)amine 

(Mixed allsyl) amine 

9-0ctadecenylami ne 

Octadecylamine 

Octylamine 

(Soybean oil alkyl) amine 

(Tall oil aliyl)amine 

*( Tallow allsyl) amine 

"Secondary and tertiary monoamines : 

Bis(coconut oil allsyl)amine 

Bis ( hydrogenated tallow allsyl)amine 

N, N-Dimethyl( coconut oil aliyl)amine 

N, N-Dimethyldodecylamine 

N, N- Dime thy lhexadecylamine 

N,N-Dimethyl(hydrogenated tallow aliyl)amine 

N,N-Dimethyl(inixed alily)amine 

N, N-Dimethyloctadecylami ne 

N,N-Dimethyl( soybean oil allsyl) amine 

N, N-Dimethyltetradecylami ne 

N-Methylbis( coconut oil alkyl)amine 

N-Methy Ibis ( hydrogenated tallow allsyl) amine 

N-Methyldioctadecylamine 

Tridodeeylami ne 

Trioctylamine 

Tris( hydrogenated tallow alkyl)amine 

"Oxygen- containing amines and ami ne oxides : 

N, N-Bis ( 2-hydroxyethyl ) dodecylami ne 

N,N-Bis(2-hydroxyethyl)octadecylamine 

N, N-Bis (2-hydroxyethyl) octylamine 

N, N-Bis (2-hydroxyethyl) (tallow aliyl)amine 

N,N-Bis(2-hydroxyethyl)(tallow allsyl) amine acetate— 



WTC. 








FOR. 








DOM, 


HAL, 


TCC, 


TXT. 


ICI. 








AML, 


GLY, 


TCC. 




ADM, 


ARC, 


FOR. 




ARC. 








ADM, 


ARC. 






GNM. 








ACY, 


ARC. 






ARC. 








ARC. 








ADM, 


ARC, 


FOR, 


GNM. 


ARC, 


FOR. 






APD, 


FOR. 






ARC, 


FOR, 


GNM. 




CCW. 








ARC, 


FOR, 


GNM. 




ARC. 








GNM. 








ARC, 


FOR, 


GNM. 




ADM, 


ARC, 


CGL, 


FOR, GNM. 


FOR. 








ADM, 


ARC, 


FOR, 


GNM. 


ADM, 


ARC, 


FOR. 




ADM, 


ARC, 


CGL, 


FOR, GNM, HUM, VGC 


GNM. 








ARC, 


FOR, 


GNM. 




ADM, 


ARC, 


FOR, 


GNM. 


ARC, 


RH, 


UCC. 




ARC, 


CGL. 






FOR, 


GNM. 






ADM, 


ARC, 


CGL, 


FOR, GNM, HUM. 


ARC, 


FOR. 






ARC. 








PG. 








BC. 








ARC, 


BC. 






ARC. 








BRD, 


PG, 


SDH, 


X. 


ARC, 


BC, 


PG. 




ARC. 








ARC, 


BC. 






FOR, 


GNM. 






ARC, 


FOR, 


GNM. 




FOR. 








GNM. 








GNM. 








GNM. 








FIN. 








FIN. 








FIN. 








FIN. 








PG. 









150 



SYNTHETIC ORGANIC CHEMICALS, 1965 

TABLE 19B -Surface-active agents for which U.S. production or sales were reported, identified by 
lAtf^c i»d. j manufacturer, 1 965— Continued 



NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 
Not Sulfated or Sulfonated- -Continued 

*Amides, amines, and quaternaiy ammonium salts— Continued 
*Amines, amine oxides, and amine salts (except hetero- 
cyclic) — Continued 
*Oxygen-containing amines and amine oxides— Continued 

(Coconut oil alkyl)amine, ethoxylated 

(Coconut oil alkyl)amine, ethoxylated, acetate 

Hexadecyldimethylamine oxide 

( Hydrogenated tallow alkyl)amine, ethoxylated—--— 
N-(2-Hydroxyethyl)-N,N',N'-tris(2-hydroxypropyl)- 
ethylenediamine . 

3-Lauramido-N, N-dimethylpropylamine oxide 

*(Mixed alkyl)amine, ethoxylated 

Octadecylamine, ethoxylated 

Poly ethy lenepolyamine , alkoxylated 

Rosin amine, ethoxylated 

(Soybean oil aliyl) amine, ethoxylated 

*(Tallow alkyl)amine, ethoxylated 

N-(Tallow aliyljtrimethylenediamine, ethoxylated— - 
N, N, N', N '-Tetrakis( 2-hydroxyethyl)ethylenediamine-- 
N, N, N ' , N '-Tetrakis ( 2-hydroxypropyl) ethylene- 
diamine, propoxylated and ethoxylated. 

Triethanolamine, ethoxylated 

All other 

*Fatty acid - alkanolamine condensates : 
*Diethanolamine condensates : 

*Capric acid 

Castor oil acids 

*Coconut oil acids (amine/acid ratio=2/l) 



Manufacturers' identification codes 
(according to list in table 22) 



*Coconut oil acids (amine/acid ratio=l/l)- 



Coconut oil acids (all other ratios) 

Coconut oil and tallow acids (amine/acid ratio=2/l) — 
*Laurie acid 



Laurie and myristic acids 

Linoleic acid 

Mixed fatty acids 

*01eic acid (amine/acid ratio=2/l)- 
*01eic acid (amine/acid ratio=l/l)- 

Palmitic acid 

Pelargonic acid 

♦Stearic acid 



*Tall oil acids 

Tallow acids 

♦Other alkanolamine condensates : 

*Coeonut oil acids - ethanolamine condensate 

Coconut oil acids - isopropanolamine condensate 

♦Laurie acid - ethanolamine condensate 

♦Laurie acid - isopropanolamine condensate 

Laurie and myristic acids - isopropanolamine 
condensate . 

Myristic acid - ethanolamine condensate 

Myristic acid - isopropanolamine condensate 

Oleic acid - ethanolamine condensate 

isopropanolamine condensate 

ethanolamine condensate (amine/acid 



Oleic acid 
♦Stearic acid 

ratio=l/l) . 
Stearic acid 

ratio=l/2). 
All other 



APD, ARC, NLC, VAC. 

RPC. 

ONX. 

CIB, TCH, VAC. 

NLC. 

SNW. 

APD, CIB, G, NOP, RH. 

ARC, ICI. 

NLC. 

HPC, PCS, RTF. 

ARC, VAC. 

ADM, ARC, CIB, DUP. 

ARC. 

NLC. 

WYN. 

JCC. 



GGY, PCS, RZL. 

PCS, VAL. 

AML, ARD, BSC, CIB, CLI, CRT, CTL, DEP, DRW, EFH, HLI, 

HRT, JOR, KNP, LEV, LUR, MOA, NOP, ONX, PC, PCS, PNX, 

RCD, RZL, SBC, SEY, STP, SWT, TCC, TXC, UNN, UVC, 

VAC, VND, WIC, WTC. 
APX, ARD, ARL, CLI, CTL, DRW, EMK, GGY, HLI, MOA, MRV, 

NOP, ONX, PCS, PEK, QCP, RCD, RTF, RZL, SBC, SEY, 

STP, TXT, VAC. 
JRG, PCS. 
PG. 
ARD, CLI, CTL, HLI, MOA, ONX, PCS, PG, RCD, RTF, RZL, 

SBC, STP, TXT, WON, WTC. 
CLI. 
VND. 

BSC, HLI, STP, WTC. 

CCW, CLI, HLI, MRA, ONX, SEY, STP, UVC, VAC, WTC. 
CUL, GGY, NOP, PCS, SBC, SCP, SEY, SWT, TCC, TXT, VAC. 
CMG. 
EMR. 
AML, BSC, CLI, DEP, EMR, GGY, GLY, JOR, MRA, NOP, ONX, 

RPC, SCO, SEY, TXC, UVC, VAL, WTC. 
EFH, MRA, MRV, UVC, WTC. 
PCS, RPC. 



ethanolamine condensate (amine/acid 



APX, CCL, CTL, HRT, MOA, 

LEV, STP. 

CTL, PCS, TXT, WTC. 

ARD, CLI, MOA, PCS, WTC. 

TXT. 

WTC. 
ARD. 
ARD. 
WTC. 
ARC, ARD, MOA, VND, WTC. 

GLY, WTC. 

CLI, GLY. 



PCS, PG, STP, TXT, UVC, VND. 



SURFACE-ACTIVE AGENTS 



151 



TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 

Not Sulfated or Sulfonated— Continued 

*Amides, amines, and quaternary ammonium salts — Continued 
*Fatty acid - diamine and polyamine condensates : 
Adipic and stearic acids - diethylenetriamine 
condensate. 

Coconut oil acids - diethylenetriamine condensate 

Coconut oil acids - N, N-dimethyltrimethylenediamine 
condensate. 

Mixed fatty acid - polyaliylenepolyamine condensate 

Oleic acid - (2-aminoethyl)piperazine condensate 

*01eie acid - diethylenetriamine condensate 

Oleic acid - diethylenetriamine condensate, acetic 

acid salt. 
Oleic acid - N, N-dimethyltrimethylenediamine conden- 
sate. 
Oleic acid - N, N-dimethyltrimethylenediamine conden- 
sate, caproic acid salt. 
*01eie acid - ethylenediamine condensate (amine/acid 
ratio=l/2). 

Pelargonic acid - tetraethylenepentamine condensate 

Stearic acid - diethylenetriamine condensate 

Stearic acid - N,N-diethylethylenediamine condensate 

Stearic acid - N,N'-diethylethylenediamine condensate 
( amine/acid ratio=l/2 ) . 

Stearic acid - dipropylenetriamine condensate 

Stearic acid - ethylenediamine condensate (amine/acid 
ratio=l/2). 

Stearic acid - tetraethylenepentamine condensate 

Tall oil acids - diethylenetriamine condensate 

All other 

*Fatty acid - diamine and polyamine condensates, alkoxy- 
lated: 
Coconut oil acids - diethylenetriamine condensate, 

polyethoxylated . 
Coconut oil acids - ethylenediamine condensate, mono- 

ethoxylated. 
Mixed fatty acids - alkylenediamine condensate, poly- 
ethoxylated. 
*01eic acid - ethylenediamine condensate, monoethoxy- 
lated. 
Palm oil acids - ethylenediamine condensate, mono- 

ethoxylated. 
Stearic acid - diethylenetriamine condensate, poly- 
ethoxylated . 
*Stearic acid - ethylenediamine condensate, mono- 
ethoxylated . 
Stearic acid - ethylenediamine condensate, poly- 
ethoxylated. 
^Heterocyclic amines and quaternary ammonium salts : 
* Imidazoline derivatives : 

l-(2-Aminoethyl)-2-heptadecyl-2-imidazoline 

l-(2-Aminoethyl)-2-(mixed al)syl)-2-imidazoline 

l-(2-Aminoethyl)-2-nor(tall oil aliyl)-2-imidazoline- 
l,l-Bis(carboxymethyl)-2-undecyl-2-imidazolinium 

chloride, disodium salt. 
1, 1-Bis( carboxymethyl) -2-undecyl-2-imidazolinium 

hydroxide, disodium salt. 
1- Carboxymethyl-2-heptadecyl-l- ( 2-hydroxyethyl) -2- 
imidazolinium hydroxide, sodium derivative, sodium 
salt. 
l-Carboxymethyl-l-( 2-hydroxyethyl) -2-nonyl-2- 

imidazolinium chloride, sodium salt. 
l-Carboxymethyl-l-( 2-hydroxyethyl) -2-nonyl-2- 

imidazolinium hydroxide, sodium derivative, sodium 
salt. 
l-Carboxymethyl-l-( 2-hydroxyethyl) -2-undecyl-2- 

imidazolinium hydroxide, sodium derivative, sodium 
salt. 



APX, 
JRG, 


NOP. 
TXT. 










NLC. 
PCS. 
APD, 
PCS. 


HDG, 


PCS, 


TXT. 






CCW, 


SNW. 










RCD. 












CCW, 


GLY, 


HDG. 








ICI. 
APX, 
CBP. 
SNW. 


CRT, 


DEP, 


HRT, 


ONX, 


QCP, S. 


JOR. 
CCW, 


CTN, 


GLY, 


ICI, 


NOP. 




ICI, 
NCW. 
EMR, 


ONX. 
TXT, 


VAL, 


VND, 


WM. 




TCC. 












NOP, 


RFC. 










NLC. 












CLD, 


DEX, 


NOP, 


SOC, 


TNA. 




APX. 












TCC. 












AML, 


CLD, 


CMG, 


CST, 


DEP, 


DEX, ICI, MRA, NOP, S, SNW 


APD, 


TCC. 










TXT. 
RTF. 
NLC. 
PCS. 













PCS. 
MIR. 



152 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 19B. —Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



Chemical 



NONBENZENOID SURFACE- ACTIVE AGENTS— Continued 

Not Sulfated or Sulfonated--Continued 
*Amides, amines, and quaternary ammonium salts — Continued 
heterocyclic amines and quaternary ammonium salts — Con. 
"Imidazoline derivatives — Continued 

l-Ethyl-2-(8-heptadecenyl)-l-(2-hydroxyethyl)-2- 

imidazolinium bromide. 
2-(8-Heptadeeenyl)-l-(2-hydroxyethyl)-2-imidazoline- 

2-(8-Heptadecenyl)-2-imidazoline 

*2-Heptadecyl-l-(2-bydroxyethyl)-2-imidazoline 

2-Heptadecyl-2-imidazoline 

l-(2-Hjrdroxyetnyl)-2-nonyl-2-imidazoline 

l-(2-Ifydroxyetnyl)-2-nor( coconut oil alkyl ^-imid- 
azoline. 
l_(2-[tydroxyethyl)-2-nor(tall oil aliyl) -2-imid- 

azoline. 
l-(2-Ifydroxyethyl)-2-tridecyl-2-imidazolinium chlo- 
ride. 

l-(2-Ifydroxyetbyl)-2-undecyl-2-imidazoline 

2-(ll-Ifydroxy-8-heptadecenyl)-2-imidazoline 

Rosinpolyamidoimidazoline 

3- [2- (2-Undecyl-2-imidazolin-l-yl)ethoxy] propionic 
acid. 
*Mbrpholine, oxazoline, and piperazine derivatives: 

N-Dodeeylmorpholine 

2-( 8-Heptadecenyl ) -4,4-bis ( hydroxymethyl) -2-oxazo- 

line. 
2-(8-Heptadecenyl)-4-hydroxymethyl-4-methyl-2-oxazo 

line. 

N-Hexadecylmorpholine 

Mixed fatty piperazines 

N-(Soybean oil aliy 1 )morpholine 

"Quaternary ammonium salts (except heterocyclic): 

*Bis(coconut oil alkyljdimethylammonium chloride 

*Bis(hydrogenated tallow alkyl)dimethylammonium chlo- 
ride. 

*Dimethyldioctadecylammonium chloride 

*Dodecyltrimethylammonium chloride 

"Oxygen-containing compounds: 

Bis(2-hydroxyethyl, ethoxylated)methyl(9-octa- 

decenyl)ammonium chloride. 
Bis( 2-hydroxyethyl, ethoxylated)methyloctadecyl- 

ammonium chloride. 

N-(3-Coconut oil amidopropyl)betaine 

(Coconut oil alkyl)betaine 

(Coconut oil alkyl)bis(2-hydroxyethyl, ethoxylated) 

methylammonium chloride. 

C-Decylbetaine 

C-Dodecylbetaine 

N-Dodecylbetaine 

C-Hexadecylbetaine 

(2-Ifydroxyethyl)dimethyl(stearamidopropyl) ammonium 

dihydrogen phosphate. 
( 2-Hydroxyethyl) dimethyl( stearamidopropyl) ammonium 

nitrate. 
2-}fydroxytrimethylenebis[( coconut oil aHsyl)di- 

methylammonium chloride] . 

Mixed fatty betaines 

C-Octadecylbetaine . 

Triethyl(octadecyloxymethyl) ammonium chloride 

Other quaternary ammonium salts : 

(Coconut oil aliyl)trimethylammonium chloride 

Didodecyldimethylammonium bromide 

Dimethylbis( soybean oil aliyl) ammonium chloride 

Dodecyltrimethylammonium bromide 

Ethyldimethyl(9-octadecenyl) ammonium bromide 

Ethyldimethyl( soybean oil alkyl) ammonium bromide — 
Ethylhexadecyldimethylammonium bromide 



Manufacturers' identification codes 
(according to list in table 22) 



NLC, PCS, UVC. 

HDG, MOA, ONX, RZL, TXT. 



GGY, 


PCS, 


UVC. 




GRD. 








UVC. 








UVC. 








BC. 








COM, 


UVC. 






COM, 


UVC. 






APD. 








TXT. 








APD. 








ARC, 


FOR, 


GNM, 


VAC. 


ADM, 


ARC, 


FOR, 


GNM, VAC 


FOR, 


GNM, 


PC. 




ARC, 


FOR, 


GNM. 





RCD. 
CUL. 
ARC, VAC. 

DUP. 
DUP. 
RCD. 
DUP. 
ACY. 

ACY. 



TXT. 
DUP. 
DAN. 

ARC, GNM. 

ONX. 

ARC. 

DUP. 

ONX. 

BC. 

FIN. 



SURFACE-ACTIVE AGENTS 



153 



TABLE 19B. —Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1965— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



NONBENZENOID SURFACE- ACTIVE AGENTS— Continued 

Not Sulfated or Sulfonated— Continued 

•Amides, amines, and quaternary ammonium salts — Continued 
•Quaternary ammonium salts (except heterocyclic) — Con. 
•Other quaternary ammonium salts — Continued 

Hexadecyltrimethylammonium bromide 

Hexadecyltrimethylammonium chloride 

Hexadecyltrimethylammonium stearate 

( Hydrogenated tallow aliyl )trime thy lammonium chlo- 
ride. 

Methyltriocty lammonium chloride 

lfethyltris( mixed aliyl) ammonium chloride 

N, N, N ' , N' , N' -Pentamethyl-N- ( tallow aliyl) trimethyl- 
enebis [ammonium chloride]. 

Trimethyl(mixed aliyl) ammonium chloride 

Trimetbyloctadecylammonium chloride 

Trimethyl( soybean oil aliyl) ammonium chloride 

Trimethyl( tallow aliyl) ammonium chloride 

All other 

•N-Substituted amino acids and polypeptides : 

N-[ 2-( Carboxymethylamino) ethyl] -N-( 2-hydroxyethyl) - 
coconut oil amide, sodium salt. 

N-( Coconut oil acyl)sarcosine 

N-( Coconut oil acyl)sarcosine, sodium salt 

N-( Coconut oil aliyl) -|3 -alanine 

N-Dodecyl-3-iminodipropionic acid 

N-Dodecyl-3- inn nodipropionic acid, sodium salt 

N-(2-Hydroxyethyl)-N-(2-lauramidoethyl)-|3-alanine 

N-(2-Hydroxyethyl)-N-(2-stearamidoethyl)glycine 

N-Lauroylpolypeptide 

*N-Iauroylsarcosine, sodium salt 

N-Oleoylpolypeptide 

N-Oleoylpolypeptide, sodium salt 

N-Oleoylsarcosine, sodium salt 

Polypeptide 

N-Stearoylsarcosine, sodium salt 

N-( Tallow aliyl) -3-i" mi nodipropionic acid, sodium salt 
•Other amides, amines, and quaternary ammonium salts: 
N, N-Bis( 2-hydroxyethyl) -2- ( stearamidomethoxy ) ethyl- 

amine. 
N, N-Bis( 2-hydroxyethyl) -2-( stearamidomethoxy ) ethyl- 

amine - melamine ether condensate. 
Bis [octadecenyloxypolyethylene glycol] ester of 1,6- 

hexamethylenedicarbamic acid. 
Coconut oil acids - ethanolamine condensate, ethoxy- 

lated. 
Coconut oil acids - isopropanolamine condensate, 
ethoxylated and propoxylated. 
•Hydrogenated tallow acids - ethanolamine condensate, 
ethoxylated. 

•Oleic acid - ethanolamine condensate, ethoxylated 

Oleic acid - methanolamine condensate, ethoxylated 

Stearic acid - N- ( 2-eyanoethyl ) diethylenetriami ne 

condensate (amine/acid ratio=l/2). 
Tall oil acids - ethanol ami ne condensate, ethoxylated- 
•Carboxylic acid esters : 

•Ethylene glycol and diethylene glycol esters : 

Diethylene glycol distearate 

methylene glycol monoester of coconut oil acids 

Diethylene glycol monoester of tallow acids 

•Diethylene glycol monolaurate 

•Diethylene glycol mono-oleate 

Diethylene glycol monoricinoleate 

•Diethylene glycol monostearate 

Diethylene glycol sesquilaurate 

Diethylene glycol sesquioleate 

Diethylene glycol sesquistearate 

Diethylene glycol tall oil ester 



DUP, 


FIN, I CI. 














ARC. 
















FIN. 
















ARC, 


FOR. 














GNM. 
















VAC. 
















ARC, 


GNM. 














GNM. 
















ARC, 


GNM. 














ARC, 


FOR. 














ARC, 


FOR, GNM. 














CGL. 
















TCC. 
















GGY. 
















HMP. 
















GNM. 
















GNM. 
















GNM. 
















UVC. 
















G. 
















MYW. 
















CP, 


GGY, HMP, ONX. 














MYW. 
















I1C. 
















G, GGY. 














MYW. 
















GGY. 
















GNM. 
















CIB. 
















CIB. 
















CIB. 
















DRW, 


STP. 














STP. 
















ARC, 


DRW, NOP. 














ARC, 


DRW, G. 














G. 
















CIB. 
















JCC. 
















ARC. 
















DRW. 
















DRW. 
















ARC, 


CCW, DRW, EMR, 


GLY, 


HAL, 


HDG, 


KAL, 


NOP, 


WTC 


ARC, 


HAL, WTC. 














GLY. 
















AML, 


ARC, CCW, CLI, 


HAL, 


NOP, 


PCS, 


QCP, 


SEY, 


UVC 


VAL, VND, WTC. 














GLY. 












^ 




GLY. 
















GLY, 


WM. 














HDG, 


QCP, WTC. 















154 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



NONBENZENOID SURFACE- ACTIVE AGENTS— Continued 

Not Sulfated or Sulfonated--Continued 

♦Carboxylic acid esters — Continued 
♦Ethylene glycol and diethylene glycol esters — Continued 

♦Ethylene glycol distearate 

Ethylene glycol mono-oleate 

♦Ethylene glycol monostearate 

Ethylene glycol sesquistearate 

♦Glycerol esters : 

♦Complex glycerol esters : 

Glycerol diacetyl tartrate monostearate 

Glycerol lactate palmitate 

Glycerol lactate stearate 

Glycerol maleate mono-oleate 

Glycerol monoester, acetylated 

Glycerol mono-oleate, acetylated 

♦Glycerol esters of chemically defined acids : 

Glycerol dioleate 

Glycerol distearate 

Glycerol monocaprylate 

♦Glycerol monolaurate 

♦Glycerol mono-oleate 

Glycerol monoricinoleate 

♦Glycerol monostearate 

♦Glycerol esters of mixed acids : 

Glycerol diester of lard acids 

Glycerol monoester of coconut oil acids 

Glycerol monoester of cottonseed oil acids 

Glycerol monoester of hydrogenated cottonseed oil 

acids. 
Glycerol monoester of hydrogenated soybean oil acids 

Glycerol monoester of lard acids 

Glycerol monoester of mixed fatty acids 

Glycerol monoester of peanut oil acids 

Glycerol sesquiester of mixed fatty acids 

♦Polyethylene glycol esters : 

♦Polyethylene glycol esters of chemically defined 
acids : 

♦Polyethylene glycol dilaurate 

♦Polyethylene glycol dioleate 

♦Polyethylene glycol distearate 

Polyethylene glycol methylcarbitol maleate 

♦Polyethylene glycol monolaurate 

♦Polyethylene glycol mono-oleate 

Polyethylene glycol monopalmitate 

Polyethylene glycol monoricinoleate 

♦Polyethylene glycol monostearate r 

Polyethylene glycol pelargonate 

Polyethylene glycol sesquioleate 

♦Polyethylene glycol esters of mixed acids : 

♦Polyethylene glycol ester of castor oil acids 

♦Polyethylene glycol ester of coconut oil acids 

♦Polyethylene glycol ester of rosin acids 

♦Polyethylene glycol ester of tall oil acids 

♦Polyethylene glycol ester of tallow acids 

Polyethylene glycol monoester of soybean oil acids- 
All other 



ARC, EMR, HAL, HDG. 

PCS. 

ARC, CCW, CLI, EFH, GLY, HAL, HDG, KNP, VND, WM. 

WM. 



DRW, PCS, WTC. 
DRW, GLD. 
APD, GLD. 
NOP, WTC. 



EK. 



ARC, HAL. 

APX, ARC, PCS. 

ARC. 

ARC, GLX, HAL, KNP. 

APD, ARC, CCW, DRW, EFH, EK, EMR, GLY, HAL, HDG, SWT, 

WM. 
CCW. 
ARC, CCW, CHL, CRT, DRW, EK, EMR, GLY, HAL, HDG, JRG. 

LUR, MRA, NOP, NW, PCS, PG, SNW, SWT, TCC, UVC, VND. 

WM, WTC, x. 

PCS. 

DRW, GLY, HDG, SWT, WM. 

DRW, EK, PCS. 

LEV. 

DRW. 

EK, GLD, PCS. 

EFH, EK, GLD, HDG, LEV, SWT, WTC. 

DRW. 

APD. 



ARC, DEX, EFH, GLY, HAL, HDG, JOR, NOP, PCS, WM. 
ARC, CLD, EFH, GGY, GLY, HAL, HDG, NOP, PCS, RZL, SM, 

UVC, VND. 
ARC, GLY, HAL, HDG, PCS, QCP. 
CCA. 
AAC, ARC, BSC, CCA, DEX, DRW, GGY, GLY, HAL, HDG, JOR, 

KNP, NOP, PCS, SYC, TCH, TXT, UVC, WM. 
AAC, ARC, CCA, CLD, CRC, CRT, DEX, DRW, EMR, G, GGY, 

GLY, HAL, HDG, I CI, NOP, ONX, PCS, SM, SWT, SYC, TCH, 

UVC, VAC, WM, WTC. 
APD. 

AAC, ARC, BAC, NOP. 
AML, APD, ARC, CRT, DEP, DEX, DRW, EMR, G, GGY, GLY, 

HAL, HDG, ICI, KNP, NOP, ONX, PC, PCS, PD, RH, TCC, 

TCH, VND, WTC. 
EMR. 
PCS. 

G, GGY, GLY, HAL, NOP, WTC. 

ARC, ARL, DRW, EMR, GLY, NOP, ONX, PG, VND. 

APD, HPC, NLC, CJCP. 

AML, APD, APX, ARC, DRW, GLY, HDG, MON, NOP, RTF, SOS, 

TCH, WTC. 
DRW, ONX, SOS. 
DRW. 
GLY, PCS, SYC. 



SURFACE-ACTIVE AGENTS 



155 



TABLE 19B —Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



NONBENZENOID SURFACE-ACTIVE AGENTS- -Continued 
Not Sulfated or Sulfonated--Co.nti.nued 

*Carboxylic acid esters — Continued 
*Polyglycerol esters : 

Polyglyeerol distearate 

Polyglyeerol lactate oleate 

Polyglyeerol monoester of cottonseed oil acids 

Polyglyeerol oleate 

Other carboxylic acid esters: 
Anhydrosorbitol esters : 

Arihydrosorbitol dioleate 

Anhydrosorbitol mixed fatty acid ester 

Arihydrosorbitol monolaurate 

Anhydrosorbitol mono-oleate 

Anhydrosorbitol monopalmitate 

Anhydrosorbitol monostearate 

Anhydrosorbitol sesquioleate 

^Anhydrosorbitol tall oil ester 

Anhydrosorbitol tetrastearate 

^Anhydrosorbitol trioleate 

Anhydrosorbitol triricinoleate 

*Anhydrosorbitol tristearate 

Ethoxylated anhydrosorbitol esters : 

Ethoxylated anhydrosorbitol castor oil ester 

*Ethoxylated anhydrosorbitol monolaurate 

*Ethoxylated anhydrosorbitol mono-oleate 

*Ethoxylated anhydrosorbitol monopalmitate 

*Ethoxylated anhydrosorbitol monostearate 

Ethoxylated anhydrosorbitol tall oil ester 

*Ethoxylated anhydrosorbitol trioleate 

^■Ethoxylated anhydrosorbitol tristearate 

Ethoxylated sorbitol esters : 

Ethoxylated sorbitol beeswax ester 

Ethoxylated sorbitol distearate 

Ethoxylated sorbitol hexaoleate 

Ethoxylated sorbitol hexa(tall oil) ester 

Ethoxylated sorbitol lanolin ester 

Ethoxylated sorbitol mono-oleate 

Ethoxylated sorbitol oleate stearate 

Ethoxylated sorbitol pentalaurate 

Ethoxylated sorbitol pentaoleate, acetylated 

Ethoxylated sorbitol penta(tall oil) ester 

Ethoxylated sorbitol tetra(laurate, oleate) 

Ethoxylated sorbitol tetra(tall oil) ester 

All other: 

Anhydrosorbitol glycerol monolaurate 

Calcium stearolactate 

Coconut oil acids, ethoxylated methanol ester 

Diisobutylene maleate 

Ethoxylated glucose oleate 

Ethoxylated glycerol mono- and diester of mixed 
fatty acid. 

Ethoxylated 1,2-propanediol stearate 

Methyl glucoside laurate 

Methyl glucoside oleate 

Pentaerythritol distearate 

Polyalkylene glycol diglycolate 

Polyalkylene glycol dimaleate 

Polyaliylene glycol naphthenate 

1,2-Propanediol distearate 

1,3-Propanediol monoester of coconut oil acids-- 

*l,2-Propanediol monolaurate 

1,2-Propanediol mono-oleate 

»l,2-Propanediol monostearate 

Propylene glycol monoesters 

Sucrose esters of fatty acids 

*Ethers : 

*Castor oil, ethoxylated 

n-Decyl alcohol, ethoxylated 



Manufacturers ' identification codes 
(according to list in table 22) 



PCS. 
DEW. 
DRW. 
DRW, HDG, VND, WTC. 



APD. 

GLY. 

AAC, APD, GLY, HDG, PCS. 

AAC, APD, DRW, GLY, HDG, PCS. 

APD, GLY, PCS. 

AAC, APD, DRW, GLY, HDG, PCS. 

GLY. 

APD, GLY, HDG, RTF. 

APD. 

AAC, APD, GLY, HDG, PCS. 

APD. 

APD, DRW, GLY, HDG, PCS. 

APD. 

AAC, APD, DRW, GLY, HDG, PCS, TCH. 

AAC, APD, ARC, DRW, GLY, HDG, PCS, TCH. 

AAC, APD, GLY, TCH. 

AAC, APD, DRW, GLY, HDG, PCS, TCH. 

APD, RTF, TCH. 

AAC, APD, GLY, TCH. 

AAC, APD, DRW, GLY, PCS, TCH. 

APD. 
APD. 
APD. 
APD. 
APD. 
APD. 
APD. 
APD. 
APD. 
APD. 
APD. 
APD. 

APD. 

GLY. 

DRW, JOR. 

RH. 

APD. 

APD. 



APD. 

HDG. 

HDG. 

VAL. 

NLC, RTF. 

NLC. 

APD. 

HAL, PCS. 

DRW. 

ARC, HAL, SBC, WM. 

ARC, HAL. 

APD, ARC, CCW, EK, GLY, HAL, HDG, 

GLD. 

SUG. 



JRG, PCS, PG, WTC. 



AAC, APD, BAC, DRW, ICI, 
G, ICI, PCS. 



NLC, NOP, PCS, RTF, TCH, VAC. 



156 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 19B. 



-Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



NONBENZENOID SURFACE-ACTIVE AGENTS- -Continued 

Not Sulfated or Sulfonated--Cor\tinued 

*Ethers — Continued 

n-Decyl and n-octyl alcohols, ethoxylated 

Deoyloxypoly(ethyleneoxy) ethyl chloride 

*n-Dodecyl alcohol, ethoxylated 

Glucose, ethoxylated 

n-Hexadecyl alcohol, ethoxylated 

Hydrogenated castor oil, ethoxylated 

*Lanolin, ethoxylated 

»Mixed linear alcohols, ethoxylated 

Mixed linear alcohols, ethoxylated and propoxylated— 

*9-0ctadecenyl alcohol, ethoxylated 

*n-Octadecyl alcohol, ethoxylated 

Polyethylene glycol tert-dodecyl thioether 

Poly(mixed ethylene, propylene) glycol 

Polypropylene glycol, ethoxylated 

Ricinoleyl alcohol, propoxylated and ethoxylated 

Rosin alcohol, ethoxylated 

Sorbitol, ethoxylated 

Sperm oil alcohol, ethoxylated 

Tallow alcohol, ethoxylated 

*Tridecyl alcohol, ethoxylated 

Tridecyl alcohol, propoxylated and ethoxylated 

Trimethylheptanol, ethoxylated 

Trimethylnonyl alcohol, ethoxylated 

Trimethylolpropane, alioxylated 

All other 

*Fatty, rosin, and tall oil acids, potassium and sodium 
salts : 

Castor oil acids, potassium salt 

Castor oil acids, sodium salt 

*Coconut oil acids, potassium and sodium salts: 

Potassium salt 

Sodium salt 

Corn oil acids, potassium salt 

Corn oil acids, sodium salt 

Laurie acid, potassium salt 

Mixed vegetable fatty acids, potassium salt 

Oleic acid, potassium salt 

*01eic acid, sodium salt 

Olive oil acids, sodium salt 

Palm oil acids, sodium salt 

Peanut oil acids, potassium salt 

Rosin acids, potassium salt 

Rosin acids, sodium salt 

Soybean oil acids, potassium salt 

♦Stearic acid, potassium and sodium salts: 

Potassium salt 

Sodium salt 

*Tall oil acids, potassium and sodium salts: 

*Tall oil acids, potassium salt 

*Tall oil acids, sodium salt 

Tallow acids, potassium salt 

*Tallow acids, sodium salt 

All other 

♦Phosphoric and polyphosphoric acid esters : 

Decyl, dodecyl, and octyl phosphate, morpholine salt 

Decyl and octyl phosphate 

Decyl polyphosphate, triethanolamine salt 

Dodecyl alcohol, ethoxylated and phosphated 

2-Ethylhexanol, ethoxylated and phosphated 

*2-EtnyLhexyl phosphate, sodium salt 

*2-Ethylhexyl polyphosphate 

2-Ethylhexyl polyphosphate, sodium salt 



Manufacturers ' identification codes 
(according to list in table 22) 



G. 

AAC, APD, DRW, DUP, GLY, JCC, NAC, OMC, PCS, UCC. 

RH. 

ADM, APD, CIB, ICI. 

APD, VAC. 

AAC, APD, DRW, VAC. 

CO, G, JCC, MON, NLC, RH, RTF, SHC, STP, TCH, UCC, 

WYN. 
STP. 

AAC, ADM, APD, CIB, DUP, G, ICI, NOP, TCH, VAC. 
AAC, APD, CIB, DUP, HDG. 
MON. 

nic, ucc, vac. 

nlc, wyn. 

PCS. 
HPC. 
VAC. 
DUP. 
ADM. 
AAC, APD, DRW, EFH, G, ICI, JCC, MON, NLC, CMC, PCS, 

RTF, TCH, UCC. 
JCC, PCS. 
PCS. 
UCC. 
RTF. 
JCC, UCC, VAC, VPC. 



BAC, SEA. 
MRV. 

CP, JRG, LUR, PCH, PG, SWT. 

CON, CP, JRG, LEV, PG, PRX. 

ARL, PCH. 

LUR. 

BSC, DRW, NOP, USR, VAL. 

AML, ARL, PCH, SWT. 

AML, BSC, CCL, CIB, CPY, DAN, GYR, NOP, QCP, S, SHP, 

USR, WIC, WTC, x. 

LEV, LUR, MRV, NOP, SEA, SWT, USR, WTC, x. 
LUR. 
LUR. 

KAL, SLC. 

ASY, FRS, HPC. 

ASY, CRT, HPC, MRA, PLC, PRX, QCP. 

CON, DRW. 

GYR, WTC. 

GYR, LEV, MAL, NOP, WTC. 

ASY, BSC, CON, DRW, FRS, GYR, HPC, LUR, PNX, QCP, TXT, 

USR, VAL. 

CPY, GYR, HPC, PCS, PRX, QCP, UNP. 

ASY, CPY, GYR, PG, SWT. 

ASP, CON, CP, FRS, GYR, JRG, LEV, LUR, NOP, PG, PLC, 

PRX, QCP, SWT. 
SLC. 

DUP. 

UVC. 

RCD. 

G. 

WAY. 

RZL, SEY, UCC, UVC. 

SEY, TCI, UVC. 

SF. 



SURFACE-ACTIVE AGENTS 



157 



TABLE 19B. 



-Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



NONBENZENOID SURFACE- ACTIVE AGENTS— Continued 

Not Sulfated or Su(/onated--Continued 

*Phosphoric and poljrphosphoric acid esters — Continued 

Hexyl polyphosphate, potassium salt 

Mixed aliyl phosphate, diethanolamine salt 

Mixed linear alcohols, ethoxylated and phosphated 

Mixed mono- and dialiyl phosphate 

Mixed mono- and dioctyl phosphate 

Mixed mono- and dioctyl phosphate, potassium salt 

9-0ctadecenyl alcohol, ethoxylated and phospnated 

9-0etadecenyl phosphate 

Octadecyl phosphate, triethanolamine salt 

Octyl phosphate, allsylamine salt 

Octyl phosphate, ethoxylated 

Oct;,! polyphosphate 

Octyl polyphosphate, potassium salt 

Odyl polyphosphate, sodium salt 

Trideeyl alcohol, ethoxylated and phosphated 

Tris(castor oil alkyl) phosphate 

All other 

Other nonbenzenoid surface-active agents, not sulfated or 

sulfonated : 

n-Decyl alcohol, ethoxylated and carbonated 

3,5-Dimethyl-l-hexyn-3-ol 

3,6-Dimethyl-4-octyne-3,6-diol 

2,4.,7,9-Tetramethyl-5-decyne-4,7-diol 

Trideeyl alcohol, ethoxylated and carbonated, sodium 

salt. 
All other 



Sulfated and Sulfonated 

*Alcohols , sulfated : 

*n-Dodecyl sulfate salts : 

n-Dodecyl sulfate, 2-amino-2-methylpropanol salt 

*n-Dodeeyl sulfate, ammonium salt 

n-Dodecyl sulfate, diethanolamine salt 

n-Dodecyl sulfate, N,N-diethylcyclohexylamine salt 

n-Dodecyl sulfate, isopropanolamine salt 

n-Dodecyl sulfate, magnesium salt 

n-Dodecyl sulfate, potassium salt 

*n-Dodecyl sulfate, sodium salt 

*n-Dodecyl sulfate, triethanolamine salt 

*A11 other sulfated alcohols : 

sec-Aliyl sulfate, ammonium salt 

Branched hexadecyl sulfate, sodium salt 

Coconut oil and sperm oil aliyl sulfate, sodium salt- 

Decyl and octyl sulfate, sodium salt 

n-Decyl sulfate, sodium salt 

n-Deeyl sulfate, triethanolamine salt 

3, 9-Diethyl-6- trideeyl sulfate 

2-Ethylhexyl sulfate, sodium salt 

7-Ethyl-2-methyl-4-undecyl sulfate 

n-Hexadecyl sulfate 

Hexyl sulfate, potassium salt 

Nonyl sulfate 

n-Oetadecyl sulfate 

n-Octadecyl sulfate, sodium salt 

n-Octadecyl sulfate, triethanolamine salt 

n-Octyl sulfate, sodium salt 

n-Tetradeeyl sulfate, sodium salt 

Trideeyl sulfate, sodium salt 

»Amides, amines, and quaternary ammonium salts, sulfated 
and sulfonated: 
Fatty aeid - alkanolamine condensates, sulfated: 
*Coeonut oil acids - ethanolamine condensate, sulfated. 

potassium salt. 
Coconut oil acids - isopropanolamine condensate, 

sulfated, sodium salt. 



CST, DEX. 

DUP. 

G. 

CST, DUP. 

DUP. 

DUP. 

G. 

DUP. 

RCD. 

DUP, TXT. 

DUP. 

BCN, DEX, TXT. 

x. 

SF. 

G, LUR. 

GLY. 

NLC, SF, WTC. 



G. 

cue. 
cue. 
cue. 
s. 

G, GLY, STC. 



DUP. 

AAC, CTL, DUP, ONX, PCS, RCD, STP, TXT. 

AAC, CUL, DUP, HLI, JRG, ONX, RCD, STP. 

DUP. 

JRG, PCS. 

AAC, HLI, STP. 

HLI, PG, RCD. 

AAC, CUL, DUP, HLI, JRG, LAK, MYW, ONX, PCI, PCS, PG, 

RCD, RET, STP, TXT. 
AAC, CTL, CUL, DUP, HLI, MYW, ONX, PCS, PG, RCD, RET, 

STP, TXT. 



ucc. 






APX. 






DUP. 






PCS. 






CTL, 


DUP, 


ONX, PCS. 


DUP. 






UCC. 






AAC, 


UCC, 


WTC. 


UCC. 






AAC, 


DUP. 




DEX. 






TEN. 






DUP, 


EMK. 




ONX, 


PG. 




DUP. 






DUP, 


PCS. 




ONX, 






AAC, 


DUP. 




DEX, 
APX. 


EMK, 


HRT, ONX. 



158 



SYNTHETIC ORGANIC CHEMICALS, 1965 

TABLE 19B -Surface-active agents for which U.S. production or sales were reported, identified by 
1AJJL manufacturer, 1965— Continued 



Chemical 



NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 

Sulfated and Sulfonated— Continued 
*Amides, amines, and quaternary ammonium salts, sulfated 
and sulfonated— Continued 
Fatty acid - alkanolamine condensates, sulfated— Con. 

Oleic acid - ethanolamine condensate, sulfated 

Stearic acid, diethanolamine condensate, methyl 

sulfate . 
♦Quaternary ammonium sulfates : 

(2-Aminoethyl)ethyl(hydrogenated tallow alkyl)(2- 

hydroxyethy 1 ) ammonium ethyl sulfate. 
Bis(hydrogenated tallow alkyl)dimethylammonium 

methyl sulfate. 

Dimethyldioctadecylammonium methyl sulfate 

Ethyldimethyl(mixed aliyl) ammonium ethyl sulfate 

l-Ethyl-2-(8-heptadecenyl)-l-(2-hydroxyethyl)-2- 

imidazolinium ethyl sulfate. 

N-Ethyl-N-hexadecylmorpholinium ethyl sulfate 

N-Ethyl-N-( soybean oil al!syl)morpholinium ethyl 

sulfate . 
2-Heptadecyl-l-(2-stearamidoethyl)-2-imidazolinium 

methyl sulfate. 
(3-Lauramidopropyl)trimethylammonium methyl sulfate — 

Mixed fatty sulfobetaines 

Trimethyl(3-oleamidopropyl)ammonium methyl sulfate 

*Sulfosuccinamic acid derivatives : 

N-(l,2-Dicarboxyethyl)-N-octadecylsulfosuecinamic 

acid, tetrasodium salt. 
N- ( 2-Hydroxyethyl) -N- ( tallow allsyl) sulf osuccinamide— 

N-Octadecylsulfosuccinamide, disodium salt 

N-(Oleoyloxyisopropyl) sulf osuccinamide 

Taurine derivatives : 

N-Cyclohexyl-N-palmitoyltaurine 

N-Methyl-N-( coconut oil acyl)taurine 

*N-Methyl-N-oleoyltaurine 

N-Methyl-N-paljnitoyltaurine 

N-Methyl-N-(tall oil acyl)taurine, sodium salt 

N-Methyl-N-( tallow acyl) taurine 

Other amides, amines, and quaternary ammonium salts, 
sulfated and sulfonated: 
N-( 2-Hydroxyethyl) -N,N',N'-tris(2-hydroxypropyl)- 

ethylenediamine, distearate methyl sulfate. 
Laurie acid, 2-sulfoacetamidoethyl ester, potassium 
salt. 

N-(Mixed alkyl sulfonyl)glycine, sodium salt 

Mixed primary amines, ethoxylated and sulfated 

Oleic acid - ethylenediamine condensate, propoxylated 

and sulfated, sodium salt. 
Stearic acid - ethylenediamine condensate, mono- 

ethoxylated, ethyl sulfate. 
Tall oil acids - polyallsylenepolyamine condensate, 

sulfated. 
N, N, N' , N ' - Tetrakis ( 2-hydroxypropyl ) ethylenediamine 
dioleate methyl sulfate. 
♦Carboxylic acid esters (except natural fats and oils), 
sulfated and sulfonated: 
♦Esters of sulfated oleic acid: 

2-Butoxyethyl oleate, sulfated 

Butyl oleate, sulfated 

Ethyl oleate, sulfated 

Glycerol trioleate, sulfated 

*Isopropyl oleate, sulfated 

Methyl oleate, sulfated 

♦Propyl oleate, sulfated 

♦Sulfosuccinic acid esters: 

Sulfosuccinic acid, bis(2,6-dimethyl-4-heptyl)ester, 
sodium salt. 
♦Sulfosuccinic acid, bis (2-ethylhexyl) ester 



Manufacturers ' identification codes 
(according to list in table 22) 



SCP. 
DUP. 



ONX. 
JOR. 
APD. 

APD. 

APD. 



ACY. 
TXT. 
CIB. 



SCP. 
ACY. 
WTC. 



CRC, CRT, DEP, DRW, G, HRT, MRA, NOP, PCI. 
G. 



S. 

ICI, ONX, PC. 

G, KAL. 

MRV, SCP. 

BRY, DEX, EMR, HRT, ICI, LEA, LUR. 

ICI. 

ACY, BSC, EFH, MRV. 

G. 

ACY, CRC, CRT, CST, DAN, EFH, EMK, GGY, HRT, ICI, 
MRA, PC, SBC. 



SURFACE-ACTIVE AGENTS 



159 



TABLE 19B —Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1965— Continued 



Chemical 



NONBENZENOID SURFACE-ACTIVE AGENTS— Continued 



Sulfated and Sulfo 



ed--Conlinued 



*Carboxylic acid esters (except natural fats and oils), 
sulfated and sulfonated— Continued 
*Sulfosuccinie acid esters— Continued 

Sulfosuccinic acid, bis(tallow monoglyceride)ester 

*Sulfosuccinic acid, dihexyl ester 

Sulfosuccinic acid, dioctyl ester, sodium salt 

Sulfosuccinic acid, dipentyl ester, sodium salt 

*Sulfosuccinic acid, ditridecyl ester, sodium salt 

Other carboxylic acid esters, sulfated and sulfonated: 

Coconut oil isethionate 

Coconut oil isethionate, sodium salt 

Dodecyl sulfoacetate 

Glycerol mono( coconut oil)ester, sulfated, ammonium 

salt. 
Glycerol mono(coconut oil)ester, sulfated, sodium 
salt. 

Glycerol monostearate sulfoacetate 

2-Lauroyloxy-l-propanesulfonic acid 

All other 

*Ethers, sulfated and sulfonated: 

n-Dodecyl alcohol, ethoxylated and sulfated, ammonium 
salt. 
*n-Dodecyl alcohol, ethoxylated and sulfated, sodium 
salt. 
n-Dodecyl alcohol, ethoxylated and sulfated, tri- 

ethanolamine salt. 
Dodecyl and tetradecyl alcohols, ethoxylated and 

sulfated, ammonium salt. 
Dodecyl and tetradecyl alcohols, ethoxylated and 
sulfated, potassium salt. 

2-Hexyloxypropyl sulfate, sodium salt 

Mixed linear alcohols, ethoxylated and sulfated 

Mixed linear alcohols, ethoxylated and sulfated, 

ammonium salt. 
Mixed linear alcohols, ethoxylated and sulfated, 

potassium salt. 
Mixed linear alcohols, ethoxylated and sulfated, 
sodium salt. 

Sperm oil alcohol, ethoxylated and sulfated 

Tridecyl alcohol, ethoxylated and sulfated, sodium salt- 
All other 

^Natural fats and oils, sulfated: 

*Castor oil, sulfated 



Manufacturers ' identification codes 
(according to list in table 22) 



*Coconut oil, sulfated 

*Cod oil, sulfated 

Cottonseed oil, sulfated 

*Grease, other than wool, sulfated- 

Herring oil, sulfated 

Lard, sulfated 

Mixed fish oils, sulfated 

Mixed vegetable oils, sulfated 

Mustard seed oil, sulfated 

*Neat's-foot oil, sulfated 

*Peanut oil, sulfated 

Rice-bran oil, sulfated 

^Soybean oil, sulfated 

*Sperm oil, sulfated 



ACY. 

ACY, MOA, SNW, TCI. 



ACT. 

ACY, MOA, WTC. 



DRW. 
G, LEV. 
NAC. 
CP. 

AAC, CP. 

WTC. 
SDH. 
EMR. 

AAC, LAK, ONX, RCD. 

AAC, DUP, ONX, PCS, RCD, RET, STP. 

PG. 

LEV, TXT. 



CO, G, SHC. 
NLC, STP. 



*Tallow, sulfated- 



Whale oil, sulfated- 



DUP. 

AAC, ARL, RCD. 

APX, PG. 

AAE, ACT, ACY, 
G, HRT, ICI, 
ONX, PC, PCI, 

ACY, MRD, NOP, 

ACT, CRT, DRW, 

NOP, RTC. 

CRT, NOP, SEA, 

WHI. 

WAW. 

AML, SCO. 

LEA. 

LUR, NOP. 

ACT, CRT, KAL, 

ACY, CRT, ICI, 

EFH, KNG, LUR, 

APX, CRT, DRW, 

ACT, CLD, CRT, 
RTC, S, SEA, 

ACT, ACY, BRY, 
NOP, ONX, PC 

KNG. 



AML, APX, BRY, BSC, CRT, DEX, DRW, DUP, 
KAL, KNG, LEA, LUR, MRA, MRD, MRV, NOP, 

S, SCO, SCP, SEA, SLC, WHI, WHW. 
RTC, SEA, WHW. 
MRD, NOP, S, SEA, WAW, WHI, WHW. 

WHI, WHW. 



LUR, MRD, NOP, PC, SEA, WHI, WHW. 

LEA, LUR, NOP, SCP, SLC, SOS. 
NOP. 

HRT, KAL, LEA, MRD, NOP, ONX. 

DRW, HRT, KAL, KNG, LEA, MRD, NOP, ONX, 

WAW, WHI, WHW. 

DRW, EFH, ICI, KAL, LEA, LUR, MRA, MRD, 
PCI, SCP, SEY, SID, SNW, SOS, WHI. 



160 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



NONBENZENOID SURFACE- ACTIVE AGENTS— Continued 

Sulfated and Su!/onated--Continued 

Other nonbenzenoid surface-active agents, sulfated and 
sulfonated : 

Acetyloleic acid, sulfated 

Mixed alkanesulfonic acids 

Mixed alkanesulfonic acids, sodium salt 

*01eic acid, sulfated 

Oleostearin, sulfated 

Ricinoleic acid, sulfated 

a-Sulfostearic acid 

*Tall oil, sulfated 



DUP. 
VPC. 
DUP. 
ACT, ACT, CRT, DEX, DRW, EMR, G, LEA, LUR, MRV, NOP, 

PCI, SCO, TEN, WHI, WHW. 
SEA. 
NOP. 
RCD. 
ACT, APX, CRT, ICI, NOP, SEA, WHI, WHW. 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS 

Pesticides and Other Organic Agricultural Chemicals 

TABLE 20B. --Pesticides and other organic agricultural chemicals for which U.S. production or sales were 
reported, identified by manufacturer, 1965 



[Pesticides and other organic agricultural chemicals for which separate statistics are given in table 20A are marked 
below with an asterisk (*); products not so marked do not appear in table 20A because the reported data are ac- 
cepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from 
table 22. An x signifies that the manufacturer did not consent to his identification with the designated product] 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICALS, CYCLIC 

^Fungicides: 

2,6-Bis(dimethylaminomethyl)eyclohexanone 

2-sec-Butyl-4, 6-dinitrophenyl-3, 3-dimethylacrylate 
( Binapacryl) . 

5-Chloro-2-mereaptobenzothiazole, laurylpyridium salt 

2,4-Dichloro-6-o-ehloroanilino-s-triazine 

l,4-Dichloro-2,5-dimethoxybenzene 

2,3-Dichloro-l,4- naphthoquinone (Diehlone) 

Diphenylammonium propionate 

3,3'-Ethylenebis(tetrahydro-4,6-dimethyl-2H-l,3,5,5- 
thiadiazine-2-thione) . 

2-Heptadecyl-2-imidazoline acetate (Glyodin) 

2-Mereaptobenzothiazole, monoethanolamine salt 

*Mereury fungicides: 

2-Chloro-4-(hydroxymercuri)phenol 

Chloromethoxypropylmercuric acetate 

N-(Ethylmercuri)-p-toluenesulfonanilide 

4-(Hydroxymercuri)-2-nitrophenol 

8-(Methylmercurioxy)quinoline 

2-(Phenylmercuriamino) ethyl acetate 

Phenylmercurlammonium acetate 

N-Phenylmereuriformamide 

Phenylmercury hydroxide 

Phenylmercury lactate 

Phenylmercury naphthenate 

Phenylmercury oleate 

Phenylmercury propionate 

Tris(2-hydroxyethyl) (phenylmercuri) ammonium lactate 

2-( 1-Methylheptyl) -4, 6-dinitrophenyl crotonate 

*Naphthenic acid, copper salt 

Pentachloronitrobenzene 

*Pentachlorophenol (PCP) 

*Pentachlorophenol, sodium salt 

8-Quinolinol (8-Hydroxyquinoline), copper salt 

Tetrachloro-p-benzoquinone (Chloranil) 

2,3,4,6-Tetrachlorophenol 

Tetrahydro-3,5-dimethyl-2H,l,3,5-thiadiazine-2-thione 

N- ( Trichloromethylthio) -4-cyclohexene-l, 2-dicarboximide 
( Captan) . 

N-( Trichloromethylthio) phthalimide (Folpet) 

*2,4,5-Trichlorophenol 

*2,4,5-Triehlorophenol, ethanolamine salt 

*2,4,5-Triehlorophenol, sodium salt 

2,4,6-Trichlorophenol 

All other cyclic fungicides 

*Herbicides and plant hormones: 

5-Bromo-3-sec-butyl-7-methyluracil 

l-Butyl-3-(3,4-dichlorophenyl) -1-methylurea ( Neburon) 

2-sec-Butyl-4,6-dinitrophenol (DNBP) 

*2-sec-Butyl-4, 6-dinitrophenol, ammonium salt 

2-sec-Butyl-4,6-dinitrophenol, triethanolamine salt 

N-Butyl-N-ethyl-a,a,a,-trifluoro-2,6-dinitro-p-toluidine 
(Benefin). 

2-Chloro-4,6-bis(ethylamino)-s-triazine (Simazine) 

2-Chloro-4,6-bis(isopropylamino)-s-triazine (Propazine)- 

4-Chloro-2-butynyl m-chlorocarbanilate (Barban) 

2-Chloro-4-ethylamino-6-isopropylamino-s-triazine 

( Atrazine) . 
N-(3-Chloro-4-methylphenyl) -2-methylpentanamide ( Solan) - 
3-(p-Chlorophenyl) -1, 1-dimethylurea (Monuron) 



MRK. 
FMN, FMP. 

VNC. 
CHG. 

DUP. 
USR. 
MRK. 
DUP. 

UCC. 
VNC. 

DUP. 

TRO. 

DUP. 

DUP. 

MRK. 

CLY. 

TRO. 

VIN. 

MRK. 

WRC. 

MRK. 

CLY, HNX, MRK, TRO. 

MRK. 

CLY. 

RH. 

CCA, FER, HNX, MCI, MLD, SHP, SM, SOC, SRR, TGL, TRO, 

WTC. 
MON, OMC. 

BXT, DOW, FRO, MON, RCI, SFD. 
DOW, MON, RCI, SFD. 
GAM, HNX, MRK. 
USR. 
DOW. 

CLY, MRK, SF, WRC. 
CHO. 

CHO. 

DA, DOW, HK. 

G. 

DA, DOW. 

DOW. 

CWN, DUP. 

DUP. 

DUP. 

CIS, DOW, FMN, TNA. 

CIS, DOW, FMN. 

CIS, DOW, FMN. 

LIL. 



GGY. 
GGY. 
SPN. 
GGY. 

FMN. 
DUP. 



162 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 20B. • 



-Pesticides and other organic agricultural chemicals for which U.S. production or sales were 
reported, identified by manufacturer , 1965 — Continued 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, 
CYCLIC--Continued 

^Herbicides and plant hormones — Continued 

3-(p-Chlorophenyl)-l, 1-dimethylurea trichloroacetate 

2,5-Dichloro-3-aminobenzoic acid, ammonium salt 

3,6-Diehloro-2-anisic acid 

2-(2,4-Dichlorophenoxy)ethanol sulfate, sodium salt 

3-(3,4-Dichlorophenyl)-l, 1-dimethylurea (Diuron) 

3-(3,4-Dichlorophenyl) -1-methoxy-l-methylurea ( Linuron) - 

2,4-Dichlorophenyl-4-nitrophenyl ether 

3,4-Dichloropropionanilide 

l,2-Dihydro-3,6-pyridazinedione (Maleic hydrazide) 

N,N-Dimethyl-2,2-diphenylacetamide (Diphenamide) 

l,l-Dimethyl-3-phenylurea (Fenuron) 

l,l-Dimethyl-3-phenylurea trichloroacetate 

Dimethyl tetrachloroterephthalate 

4,6-Dinitro-o-eresol (DNOC) 

4,6-Dinitro-o-cresol, sodium salt 

2, 6-Dinitro-N, N-di-n-propyl-ct,a, a-trif luoro-p- 
toluidine ( Trif luralin) . 

Diphenylacetonitrile 

Gibberellic acid 

3-(Hexahydro-4,7-methanoindan-5-yl)-l, 1-dimethylurea 
( Norea) . 

Indolebutyric acid 

Isopropyl carbanilate (Isopropyl N-phenylearbamate) 

(IPC). 
Isopropyl 3-chlorocarbanilate (Isopropyl N-(3-chloro- 

phenyl) carbamate) (CIPC). 
N-( 2-Mercaptoethyl) benzenesulf onamide S- ( 0, 0-diisopropyl 
phosphorodithioate) (Betasan). 

l-(2-Methyl-cyclohexyl)-3-phenylurea (Siduron) 

1-Naphthaleneacetic acid and derivatives: 

1-Naphthaleneacetamide 

1-Naphthaleneacetic acid 

1-Naphthaleneacetic acid, methyl ester 

1-Naphthaleneacetic acid, sodium salt 

N-1-Naphthylphthalamic acid (NPA) 

7-0xabicyclo[2.2.1]heptane-2,3-dicarboxylic acid, 

disodium salt (Endothal). 
Phenoxyacetic acid derivatives: 

(4-Chloro-o-tolyloxy) acetic acid (MCPA) 

(4-Chloro-o-tolyloxy) acetic acid, potassium salt 

♦(2, 4-Dichlorophenoxy) acetic acid (2,4-D) 

*( 2, 4-Dichlorophenoxy) acetic acid esters and salts: 
( 2, 4-Dichlorophenoxy) acetic acid, 2-butoxyethyl 

ester. 
(2, 4-Dichlorophenoxy) acetic acid, butoxypolypropyl- 
eneglycol ester. 

*(2, 4-Dichlorophenoxy) acetic acid, n-butyl ester 

(2, 4-Dichlorophenoxy) acetic acid, sec-butyl ester 

*(2,4-Dichlorophenoxy)acetic acid, dimethylamine salt 
(2, 4-Diehlorophenoxy) acetic acid, ethanolamine and 
isopropanolamine salt. 

*(2, 4-Dichlorophenoxy) acetic acid, ethyl ester 

(2, 4-Dichlorophenoxy) acetic acid, 2-ethylhexyl ester 

*(2, 4-Dichlorophenoxy) acetic acid, iso-octyl ester 

*( 2, 4-Dichlorophenoxy) acetic acid, isopropyl ester 

(2, 4-Dichlorophenoxy) acetic acid, lithium salt 

(2,4-Diehlorophenoxy)acetic acid, sodium salt 

All other (2, 4-Dichlorophenoxy) acetic acid esters 
and salts. 

*(2, 4, 5-Triehlorophenoxy) acetic acid (2,4,5-T) 

*(2, 4, 5-Trichlorophenoxy) acetic acid esters and salts: 

(2,4,5-Trichlorophenoxy)acetic acid, amyl ester 

(2,4,5-Triehlorophenoxy)aeetic acid, 2-butoxyethyl 

ester. 
(2,4,5-Trichlorophenoxy) acetic acid, butoxypoly- 
propyleneglycol ester. 
*(2, 4, 5-Trichlorophenoxy) acetic acid, n-butyl ester— 
(2,4,5-Trichlorophenoxy)acetie acid, sec-butyl ester 



Manufacturers' identification codes 
(according to list in table 22) 



ACG. 

G. 

VEL. 

G. 

DUP. 

DUP. 

RH. 

MON, RH. 

ACY, USR. 

LIL, x. 

DUP. 

ACG. 

DA. 

CIS, FMN. 

CIS, FMN. 

LIL. 

LIL. 

ABB, MRK. 
HPC. 

ARA. 
PPG. 

PPG. 

SF. 

DUP. 

AMC. 

AMC, COK. 
AMC. 

AMC, BKL. 
USR. 
PAS. 



CHC, CLY, DOW, RIV. 

GTH. 

CHC, DA, DOW, HPC, MON. 

AMC. 

DOW. 



AMC, DA, DOW, HPC, IMR, MON, RIV, TMH. 

CHC, MON. 

ALC, AMC, CHC, DA, DOW, HPC, RIV, TMH. 

DOW. 



AMC, DOW, 


MON. 




DA, HPC. 






CHC, DOW, 


MON, RIV, TMH. 




AMC, CHC, 


DA, DOW, HPC, MON, 


RIV 


GTH. 






DOW. 






CWN, HPC. 






DA, DOW, 


HPC, MON. 




HPC. 






AMC. 






DOW. 






DA, DOW, 


HPC, MON, RIV. 




MON. 







PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS 

TABLE 20B. — Pesticides and other organic agricultural chemicals for which U.S. production or sales were 
reported, identified by manufacturer, 1965 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, 
CYCLIC— Continued 

^Herbicides and plant hormones — Continued 
Phenoxyacetic acid derivatives — Continued 
*(2,4,5-Trichlorophenoxy)acetic acid esters and salts — 
Continued 
(2,4,5-Trichlorophenoxy)acetie acid, 2-ethyLhexyl 
ester. 
*(2, 4, 5-Trichlorophenoxy) acetic acid, iso-octyl ester 
(2,4,5-Triehlorophenoxy)acetic acid, isopropyl ester 
(2, 4, 5-Trichlorophenoxy) acetic acid, triethylamine 
salt. 

*Phenylmercury acetate (PMA) 

Polychloro-tetrahydro-methanoindene ( Polychlorodicyclo- 
pentadiene) isomers. 

N-Tolylphthalamic acid 

Tributyl(2,4-dichlorobenzyl)phosphonium chloride 

2-(2,4,5-Trichlorophenoxy)proplonic acid (Silvex) '■ 

2-(2,4,5-Trichlorophenoxy)propionic acid, 2-ethyLhexyl 
ester. 

Tris [2- ( 2, 4-dichlorophenoxy) ethyl] phosphite (2,4-DEP) 

All other cyclic herbicides and plant hormones 

Insect attractants: 
2,4-Bis( isopropylamino) -6-methoxy-s-triazine 

( Prometone ) . 
tert-Butyl 4(and 5)-chloro-2-methylcyclohexane- 

carboxylate. 
2-Ethylamino-4-isopropylamino-6-methylmercapto-s- 
triazine (Ametryne). 
^-Insecticides: 

Allethrin (Allyl homolog of Cinerin I) 

Benzyl thiocyanate 

Chlorinated insecticides: 
*Aldrin-toxaphene group: 

Heptachloro-tetrahydro-methanoindene ( Heptachlor ) 

Hexachloro-epoxy-octahydro-endo, endo-dimethano- 

naphthalene ( Endrin) . 
Hexachloro-epoxy-octahydro-endo, exo-dimethano- 

naphthalene (Dieldrin). 
Hexachloro-hexahydro- endo, exo-dimethanonaphthalene 
(Aldrin) . 

Octachloro-tetrahydro-methanoindan (Chlordan) 

Terpene polychlorinates 

Toxaphene (Chlorinated camphene) 

l,l-Bis(p-chlorophenyl)-2-nitrobutane 

1, l-Bis(p-chlorophenyl)-2-nitropropane 

2-(p-tert-Butylphenoxy)isopropyl-2'-chloroethyl 

sulfite . 
2-(p-tert-Butylphenoxy)-l-methyletnyl 2- ehloroethyl 
sulfite. 

p-Chlorophenyl p-chlorobenzenesulfonate (Ovex) 

p-Chlorophenyl 2,4,5-trichlorophenyl sulfone 

4,4'-Dichlorobenzilate 

l,l-Dichloro-2,2-bis(p-chlorophenyl)ethane (DDD) (TDE) 

1, l-Dichloro-2,2-bis(p-ethylphenyl) ethane 

4,4'-Dichloro-a-(trichloromethyl)benzhydrol 

*Hexachlorocyelohexane (Benzene hexachloride) 

*Hexachlorocyclohexane, 100$ y-isomer (Lindane) 

Hexachloro-hexahydro-methano-benzodioxathiepinoxide 
(Endosulfan). 

*1, l,l-Trichloro-2,2-bis(p-chlorophenyl)ethane (DDT) 

1, 1, l-Trichloro-2, 2-bis (p-methoxyphenyl) ethane 
(Methoxychlor) . 

All other chlorinated insecticides 

N, N-Diethyltoluanu.de 

Isobornyl thiocyanatoacetate 

1-Naphthyl methylcarbamate 

*Organophosphorus insecticides: 

4-tert-Butyl-2-chlorophenyl methyl methylphosphor- 

amidate. 
3-Chloro-7-hydroxy-4-methylcoumarin 0, 0-diethyl phos- 
phorothioate . 



DA, 


HPC. 


CIS, 


DOW, MON, HIV, TMH. 


DA. 




DOW, 


HPC, RIV. 


BKM, 


CLY, MRK, TRO, WRC. 


VEL. 




USR. 




SM. 




DOW, 


HPC, RIV. 


HPC. 




USR. 




HPC, 


LIL. 


GGY. 




TBK. 




GGY. 




BPC. 




HK. 




VEL. 




SHC, 


VEL. 


SHC. 




SHC. 




VEL. 




HN. 




HPC. 




COM. 




COM. 




USR. 




USR. 




AMP, 


CIS, DOW. 


FMN, 


FMP. 


GGY. 




ACG, 


RH. 


RH. 




RH. 




DA, 


fRO, HK, PPG. 


HK. 




HK. 




ACG, 


DA, GGY, LEB, MTO, OMC 


CHF, 


DUP. 


LIL, 


SHC. 


HPC, 


PFZ. 


CIS, 


HPC. 


UCC. 




DOW. 




CHG. 





164 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 20B. 



-Pesticides and other organic agricultural chemicals for which U.S. production or sales were 
reported, identified by manufacturer , 1965 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



PESTICIDES AMD OTHER ORGANIC AGRICULTURAL CHEMICALS, 
CYCLIC— Continued 

^Insecticides- -Continued 

*Organophosphorus insecticides — Continued 

S-(p-Chlorophenylthio)methyl 0, O-diethyl phosphoro- 

dithioate ( Carbophenothion) . 
0, 0-Diethyl 0-(2-isopropyl-4-methyl-6-pyrimidinyl) 
phosphorothioate (Diazinon). 
*0, 0-Diethyl O-(p-nitrophenyl) phosphorothioate 
( Parathion) . 
0,0-Dimethyl 0- [4-(methylthio)-m-tolyl] phosphoro- 
thioate. 
*0, 0-Dimethyl 0- ( p-nitrophenyl) phosphorothioate 
(Methyl parathion) . 
0, 0-Dimethyl S-(4-oxo-l,2,3-benzotriazin-3(4H) - 

ylmethyl) phosphorodithioate. 
0, 0-Dimethyl 0-(2,4,5-trichlorophenyl) phosphoro- 
thioate (Ronnel). 

p-Dioxane-2,3-diyl ethyl phosphorodithioate 

0-Ethyl 0-(p-nitrophenyl)phenyl phosphonothioate 

a-Methylbenzyl 3-hydroxy-cis-crotonate, dimethyl phos 
phate ester. 

All other organophosphorus insecticides 

Nematocides: 

0-2,4-Dichlorophenyl 0, 0-diethyl phosphorothioate 

0, 0-Diethyl 0-2-pyrazinyl phosphorothioate (Thionozin)— 
*Rodenticides: 

3-(Acetonylbenzyl)-4-hydroxycoumarin 

2-Isovaleryl-l,3-indandione, calcium salt 

2-Pivaloyl-l,3-indandione 

PESTICIDES AND OTHER ORGANIC AGRICULTURAL 
CHEMICALS, ACYCLIC 

*Fungicides: 

Bis-1,4— bromoacetoxy-2-butene 

Cadmium succinate 

l-Chloro-2-nitropropane (Korax) 

Disodium cyanodithioimidocarbonate 

Dithiocarbamic acid fungicides: 

*Dimethyldithiocarbamic acid, ferric salt (Ferbam) 

Dimethyldithiocarbamic acid, manganese salt 

Ethylene bis(dithiocarbamic acid), diammonium salt 

^Ethylene bis(dithiocarbamic acid), disodium salt 
( Nabam) . 
Ethylene bis( dithiocarbamic acid), manganese salt 
(Maneb). 
^Ethylene bis( dithiocarbamic acid), zinc salt (Zineb)-- 

Polyethylenethiuram disulfide (PETD) 

All other dithiocarbamic acid fungicides 

Dodecylguanidine acetate (Dodine) 

Mercury fungicides: 

3-Ethyl(mercuritnio)-l,2-propanediol 

Ethylmercury acetate 

Ethylmercury chloride 

Ethylmercury phosphate 

3-Methyl(mercurithio)-l,2-propanediol 

Methylmercury acetate 

Methylmercury hydroxide 

Methylmercury nitrile 

All other mercury fungicides 

All other acyclic fungicides 

*Herbicides and plant hormones: 

Cacodylic acid 

2-Chloroallyl diethyldithiocarbamate (CDEC) 

N,N-Diallyl-2-chloroacetamide (CDAA) 

2,3-Dichloroallyl diisopropylthiocarbamate 

2,2-Dichloropropionic acid, sodium salt 

Diethyl dithiobis(thionoformate) 

S-Ethyl dipropylthiocarbamate (EPTC) 

Hexachloroacetone 



SF. 

GGY. 

ACY, AMP, M0N, SF, SHC. 

CHG. 

AMP, M0N, SF, SHC. 

CHG. 

DOW. 

HPC. 

SF. 

SHC. 

SF. 

SM. 
ACY. 

PEN. 
MOT. 
MOT, PIC. 



VI N. 

MAL. 

FMN, FMP. 
BKM. 

DUP, FMN, RBC, WRC. 

FMN. 

CIS, RBC. 

CIS, DUP, FMN, RBC, RH. 

CIS, DUP, RH. 

CIS, DUP, FMN, RH. 

FMN. 

VNC. 

ACY. 

DUP. 
DUP. 
DUP. 
DUP. 
DUP. 
DUP. 
MRT. 
WRC. 
MAL. 
LIL, MLD, SHC. 

ASL. 

M0N. 

M0N. 

M0N. 

DOW. 

RBC. 

SF. 

ACG. 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS 



165 



TABLE 20B. ■ 



-Pesticides and other organic agricultural chemicals for which U.S. production or sales were 
reported, identified by manufacturer, 1965 — Continued -^ 



Manufacturers' identification codes 
(according to list in table 22) 



PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, 
ACYCLIC- - Continued 

*Herbicides and plant hormones — Continued 

Methanearsonic acid, disodium salt 

Methanearsonic acid, dodecyl- and oetylammonium salts — 

S- Propyl butylethylthiocarbamate 

S,S,S-Tributyl phosphorotrithioate 

Tributyl phosphorotrithioite 

Trichloroacetic acid, sodium salt (TCA) 

2,3,3-Trichloroallyl diisopropylthiocarbamate 

All other acyclic herbicides and plant hormones 

^Insecticides: 

2-(2-Butoxyethoxy) ethyl thiocyanate 

Butoxypolypropylene glycol (Fly repellent) 

Metaldehyde 

*Organophosphorus insecticides: 

Bis(dialkoxyphosphinothioyl) disulfides 

S-[l,2-Bis(ethoxycarbonyl)ethyl] 0,0-dimethyl phos- 

phorodithioate (Malathion). 
l,2-Dibromo-2,2-dichloroethyl dimethyl phosphate 
(Naled). 

2,2-Dichlorovinyl dimethyl phosphate (DDVP) 

0,0- Diethyl S-[2-(ethylthio)ethyl] phosphorodithioate- 
0,0-Diethyl 0-[2-(ethylthio)ethyl] phosphorothioate--- 
0,0-Diethyl S-[2-(ethylthio) ethyl] phosphorothioate— 
0,0-Diethyl S-[ (ethylthio)methyl] phosphorodithioate— 
Dimethyl 3-hydroxycrotonate, dimethyl phosphate ester- 
0,0- Dimethyl S-(N-methylcarbamoy Methyl) phosphorodi- 
thioate (Dimethoate) . 

Ethyl methylene phosphorodithioate (Ethion) 

Ethyl pyrophosphate (Tetraethyl pyrophosphate) (TEPP)- 
S-2-(Ethylsulfinyl) ethyl 0,0-dimethyl phosphoro- 
dithioate. 
Methyl 3-hydroxycrotonate, dimethyl phosphate ester—- 

All other organophosphorus insecticides 

2-Thiocyanatoethyl laurate 

*Rodenticides: Sodium fluoroacetate 

*Soil conditioners: 

Polyacrylonitrile, hydrolyzed, sodium salt 

All other soil conditioners 

*Soil fumigants: 

*Bromomethane (Methyl bromide) 

Chloropicrin (Trichloronitromethane) 

*l,2-Dibromo-3-chloropropane 

1,3-Dichloropropene 

1,3-Dichloropropene, 1, 2-dichloropropane 

N-Methyldithiocarbamic acid, sodium salt 

All other soil fumigants 



ASL, 


CLY, VI N 


CLY, 


VIN. 


SF. 




CHG. 




SM. 




DOW. 




MON. 




SF, 


USR. 


RH. 




UCC. 




COM. 




FMN. 




ACY. 




SHC. 




SHC. 




CHG. 




CHG. 




CHG. 




ACY. 




SHC. 




ACY. 




FMN, 


FMP. 


ALC, 


AMP, OTH. 


CHG. 




SHC. 




AMP, 


SHC. 



AMP, 


DOW, FRO, 


GTL, 


MCH 


DOW, 
AMP, 


IMC. 
DOW, SHC. 






DOW. 








DOW, 


SHC. 






DUP, 


RH, SF. 







SYNTHETIC ORGANIC CHEMICALS. 1963 



Miscellaneous Chemicals 

TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1965 

[Miscellaneous chemicals for which separate statistics are given in table 21A are marked with an asterisk (*); 
chemicals not so marked do not appear in table 21A because the reported data are accepted in confidence and may not 
be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, CYCLIC 

6-Aeetoxy-2, 4- dimethyl- m-dioxane 

Adenosine phosphates 

2-Aminobenzothiazole 

3-Amino-4-bromobenzotrifluoride 

l-(2-Aminoethyl)piperazine 

l-(3-Aminopropyl)morpholine 

Anisaldehyde bisulfite 

Arylalkyl phosphites 

Aziranephosphine oxide 

Barium octylphenate 

Benzoic acid salts: 

Barium benzoate 

Cadmium benzoate 

Cobalt benzoate 

*Sodium benzoate, tech 

*Sodium benzoate, U.S.P 

Zinc benzoate 

p-Benzoquinone (p-Quinone) 

Benzothiazole 

* Benzoyl peroxide 

Biological stains 

Bis(2,4-dichlorobenzoyl) peroxide 

Boron fluoride-phenol complex 

3-Bromo-4-chlorobenzotrifluoride 

a- [2-(2-Butoxyethoxy) ethoxy] -4,5-methylenedioxy-2-propyl- 

toluene (Piperonyl but oxide). 

Butyl benzoate 

p-tert-Butylbenzoic acid, barium bis-salt 

2( and 3)-tert-Butyl-4— methoxyphenol 

p-tert-Butyl-ci-methylcinnamaldehyde 

tert-Butyl peroxybenzoate 

4-tert-Butylphenyl salicylate 

4-tert-Butylpyrocatechol 

Camphene 

Catecholdisulfonic acid, disodium salt 

Catecholdisulfonic acid, sodium salt 

Centralite- 1 ( N, N '-Diethyl-N, N'-diphenylurea) 

Chemical indicators 

Chemical reagents 

Chloramine B (Sodium derivative of N-chlorobenzenesulfon- 

amide) . 

Chlorinated terphenyls 

l-(3-Chloroallyl)-3,5,7-triaza-l-azon iaadamantane 

chloride. 

4-Chloro-3-cyanobenzotrifluoride 

5-Chloro-2-hydroxybenzophenone 

Chlorophyllin, sodium- potassium- copper 

Cobalt phthalocyaninedisulfonic acid 

Cumene hydroperoxide 

Cyanuric acid 

Cyclohexanone peroxide 

Cyclohexene-1, 2-dicarboxylic acid ( Tetrahydrophthalic 

acid) disubstituted, polyester salts: Barium and 

cadmium salts. 

1,4-Cyclohexylenedimethanol 

^Cyclopropane 

Cytidine and derivatives 

Decahydronaphthalene ( Decalin) 

Decyl diphenyl phosphite 

Dehydroacetic acid, sodium salt 

2,5-Di-tert-amylhydroquinone 



GIV. 
PLB. 

FMT. 
PIC. 
JCC. 
JCC. 
GIV. 
WES. 
CEM. 
CCA. 

CCW. 

CCW. 

SHP. 

HN. 

HK, HN, MON, PFZ, VEL. 

CCW. 

EKT. 

ACY. 

AZT, 

HLC, 

CAD. 

ACG. 

PIC. 

FMN, 



FRO, 

CCA. 

EKT. 

GIV. 

WTL. 

DOW. 

BKL, 

GLD, 

ICO. 

SDW. 

OTC, 

EK, 

ACG, 

NES. 



CAD, NOC, OXY, RCI, SDH, UPR, WTL. 
NAC. 



DOW. 
HPC. 



PAS. 
HLC, LAM, NAC. 
CLB, EK, GFS, HLC, NAC, PIC. 



KPS, KPT. 
DOW. 

PIC. 

DOW. 

KCH. 

NAC. 

HPC. 

FMB. 

NOC, WTL. 

RCI. 



EKT. 

MAL, OH, OMS, TAE. 

PLB. 

DUP. 

HK. 



GAN. 

EKT. 



MISCELLANEOUS CHEMICALS 



167 



TABLE 21B. 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1 965- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, CYCLIC— Continued 

l,4-Diazabicyclo[2.2.2]oetane (Triethylenediajnine) 

Diazodinitrophenol 

2,4-Dibenzoylresorcinol 

2,4-Di-tert-butyl-p-cresol 

2,6-Di-tert-butyl-p-cresol: 

*Food grade 

*Tech 

2,5-Di-tert-butylhydroquinone 

1, l-Diehloro-2-( o- chlorophenyl) -2-( p- chloropheny 1) ethane— 

l,3-Dichloro-5,5-dimethylhydantoin 

Dichloro-s-triazine-2,4, 6( 1H,3H,5H) trione (Dichloroiso- 

cyanuric acid) . 
Dichloro-s- triazine-2, 4, 6( LH,3H,5H) trione, potassium salt- 

Diehloro-s- triazine-2, 4, 6( 1H,3H,5H) trione, sodium salt 

Dicyclohexylammonium nitrite 

Dicyclopentadienyliron 

Didecyl phenyl phosphite 

Digitonin 

2,2'-Dihydroxy-4, 4'-dimethoxybenzophenone 

2, 6-Dihydroxyisonicotinic acid (2,6-Dihydroxy-4-carboxy- 
pyridine) . 

2, 2'-Dihydroxy—4- methoxybenzophenone 

2,2'-Dihydroxy-4-(octadecyloxy)benzophenone 

3, 5-Diiodosalicylie acid 

Diisopropylbenzene hydroperoxide, mixed isomers 

Diisopropyl-m, p-cresols 

Diisopropyl-m, p-cresols, mixed 

p-Dimethoxybenzene (Dimethyl ether of hydroquinone) 

2, 5-Dimethyl-2, 5-di( peroxyphenyl) hexane 

2,5-DimethyLhexane-2,5-diperoxybenzoate 

2,6-Dimethylmorpholine 

4,4-Dinitrocarbanilide-4,6-dimethyl-2-pyrimidinol 

Dioxane ( 1, 4-Diethylene oxide) 

2,5-Diphenyl-p-benzoquinone 

Diphenyl phosphite 

4-(Dodecyloxy)-2-hydroxybenzophenone 

Enzymes: 
Hydro lytic: 

Amylases-- 

Proteases 

Other 

Nonhydro lytic 

Other 

1, 2-Epoxy-3-phenoxypropane (Glycidyl phenyl ether) 

6-Ethoxy-m-anol (Propenylmethylguaethol) 

Ethylglucosyl p- aminobenzoate 

2-EthyLhexyl octylphenyl phosphite 

Ethyl hydrocaffeate 

*4-Ethylmorpholine 

Fenchone 

*Flotation reagents: 

Dicresylphosphorodithioic acid ( Dicresylthiophosphoric 
acid) . 

Dicresylphosphorodithioic acid, ammonium salt 

Dicresylphosphorodithioic acid, sodium salt 

2,2'-Dimethylthiocarbanilide (Di-o-tolylthiourea) 

Rosin amines 

Thiocarbanilide ( Diphenylthiourea) 

Fluorinated benzenoid chemicals 

o-Fluorobenzoic acid 

4-Fluoro-2-methylaniline 

5-Fluoro-2-nitrotoluene 

Furan derivatives: 

2-Furaldehyde (Furfural) 

Tetrahydrofurfuryl alcohol 

Gallic acid, all grades 

*Gasoline additives: 

N, N'-Bis( 1, 4-dimethylpentyl)-p-phenylenediamine 

2, 6-Di-tert-butylphenol 

*N, N'-Di-sec- butyl- p-phenylenedlamine 



HOU. 
HPC. 
DOW. 
PRD. 

CAT, EKT, HPC, KPT, SHC. 

CAT, EKT, HPC, KPT, SHC. 

EKT. 

ALD, EDC. 

GLY. 

MON. 

FMB, MON. 

FMB, WON. 

CMC. 

TNA. 

HK. 

PEN. 

G. 

EK. 

ACY. 

ACY. 

MRT. 

HPC. 

GIV. 

GIV. 

ASL, EKT, G, ICO. 

WTL. 

UPR. 

DOW. 

MRK. 

DOW, UCC. 

EKT. 

HK. 

DUP, EKT. 



CRN, OMS, PMP, RH, WBC. 

PMP, RH, WBC. 
WBC. 

MLS, WBC. 



BAX, 

BAX, 

RH, 

FMO, 

PLB. 

SHC. 

ICO. 

VND. 

SM. 

ICO. 

BC, C 

HNW. 

ACY. 



ACY. 

KCU. 

DUP, RBC. 
HPC. 

ACY, NAC. 
PIC. 
PIC. 
PIC. 
PIC. 

QKO. 
CjKO. 

MAL. 

EKT. 
TNA. 
DUP, EKT, UPM. 



168 



SYNTHETIC ORGANIC CHEMICALS. 1965 



TABLE 21B -Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1965— Continued 



Manufacturers' identification codes 
( according to list in table 22) 



MISCELLANEOUS CHEMICALS, CYCLIC— Continued 

Gasoline additives — Continued 

N,N'-Diisopropyl-p-phenylenediamine 

*N,N'-Disalicylidene-l,2-propanediamine 

Methylcyelopentadienylmanganese triearbonyl 

2,2'-Thiobis[6-tert-butyl-4-methylphenol] 

All other 

Glyceryl p- aminobenzoate 

Guanosine phosphates 

Heterocyclic compounds 

5, 6,7, 8, 9, 9-Hexachloro-l, 2,3, 4, 4a, 5, 8, 8a-oetahydro- 
5,8-methano-2,3-naphthalic anhydride (Cloran). 

Hexa(2-methylaziridinyl)-l,3,5-phosphotriazine 

*Hexamethylenetetramine, tech 

Hydrocinnamic acid 

o-(2-Hydroxy-p-anisoyl) benzoic acid 

N-(2-Hydroxyethyl)gentisamide 

Hydroxyethylpiperazine 

2-Hydroxy-4-methoxybenzophenone 

2-Hydroxy-4-methoxy-5-sulfobenzophenone trihydrate- 

Hydroxymethyl-5,5-dimethylhydantoin 

2-Hydroxymethyl-5-norbornene 

2-(2'-Hydroxy-5'-methylphenyl)benzotriazole 

2-Hydroxy-4-n-octoxybenzophenone 

Hydroxyphenylbenzotriazole derivative 

2-(2-Hydroxyphenyl) -4(3) -quinazo lone 

l-Hydroxy-2-pyridine (Omadine) 

2-Imidazolidinethione ( l,3-Ethylene-2-thiourea) 

Inosine and phosphates 

Isoamyl p-dimethylaminobenzoate 

Isocyanurie acid 

Isocyanuric acid, sodium salt (Sodium isocyanurate) 

Isophorone 

Isopropyl-o-cresol 
p-Isopropyl-a- methylc innamaldehyde- 
Isosorbid 
Ketene, dimer- 
*Lubricating oil and grease additives: 

Chlorosulfurized and sulfurized compounds: 
Alicyclic compounds, sulfurized- 
Heterocyclic compounds, sulfurized 
Liquid disulfide- 

Tall oil ester, sulfurized 

Terpenes, sulfurized 

Oil- soluble petroleum sulfonates: 

Oil-soluble petroleum sulfonate, ammonium salt 

Oil-soluble petroleum sulfonate, barium salt 

*Oil-soluble petroleum sulfonate, calcium salt 

xOil-soluble petroleum sulfonate, sodium salt 

All other 

Phenol salts: 

Barium salt of dodecylphenol 

Barium salt of nonylphenol 

Calcium salt of octylphenol- formaldehyde 

Calcium salt of polypropylphenol 

All other phenol salts 

All other 

p-Menthane 

8-p-Menthyl hydroperoxide 

4-Methallylbenzenesulfonic acid 

Methoxybenzyl alcohol 

p-Methoxybenzylidenemalonic acid, dimethyl ester 

4-Methoxyphenol 

N-Methylanthranilic acid 

2-Methylaziridine 

2,2'-Methylenebis[4-chlorophenol] ( Dichlorophene) 

4,4'-Methylenebis[2,6-di-tert-butylpheno]] 

Methylenebis[5,5-dimethylhydantoin] 

2,2'-Methylenebis[3,4,6-trichlorophenol] ( Hexachlorophene) 
2,2'-Methylenedi-p-cresol ( Bis( 5-methyl-2-hydroxyphenyl) 
methane) . 



DUP, EKT. 

D0P, EKT, SM, TX, UPM. 

TNA. 

CAT. 

EKT, TNA, UPM. 

TOD. 

PLB. 

ALD. 

WSN. 

ICO. 

BOR, DUP, HKD, HMP, HN, FLS, UCP. 

ICO. 

ACY. 

ICO. 

JCC. 

ACY, G. 

ACY. 

GLY. 

ICO. 

GGY. 

ACY. 

GGY. 



LUB, MON, 0R0, SIN, x. 

LUB, MON, 0R0, SIN, SM, TNA, TX, X. 



SIN. 

CO, LUB, SON, TX, X. 

CO, LUB, 0R0, SHO, SON, X. 

ENJ, MOR, NOP, PAR, SHO, SOC, SOI, SON, TX. 

CO. 



TX. 

CCA. 

SHC. 

0R0. 

ENJ, 

ENJ, 

HPC. 

HNW, 

CCW. 

ICO. 

ACY. 

ASL, 

GIV. 

ICO. 

GIV. 

SHC. 

GLY. 

GIV. 

GIV. 



MISCELLANEOUS CHEMICALS 



169 



TABLE 21B.-- Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer , 1965 — Continued 



MISCELLANEOUS CHEMICALS, CYCLIC— Continued 

Methyl gallate 

Methylglucoside 

■i-Methylmorpholine 

5-Methyl-5-norbornene-2,3-dicarboxylic anhydride (Methyl- 
bicyclo[2.2.l]hept-5-ene-2,3-dicarboxylic anhydride). 

Methyl phenyl phosphates 

l-Methyl-2-pyrrolidone, monomer 

*Morpholine 

Morpholine salt of p- toluenesulf onic acid 

*Naphthenic acid salts: 

Aluminum naphthenate 

Barium naphthenate 

Cadmium naphthenate 

*Calcium naphthenate 

Cobalt lead manganese naphthenate 

*Cobalt naphthenate 

*Iron naphthenate 

Lead manganese naphthenate 

*Lead naphthenate 

Lithium naphthenate 

^Manganese naphthenate 

Nickel naphthenate 

Rare earths naphthenate 

Sodium naphthenate 

Strontium naphthenate 

*Zinc naphthenate 

o-Nitrobenzoic acid and sodium salt 

5-Norbornene-2-methylacrylate ( Bicyclo[2.2. l]hept-5-ene- 
2-aerylate) . 

l-0ctadecenyl-2-naphthenyltetrahydropyrimidine 

Octylphenyl acid phosphate 

Organic mercury compounds: 

Phenyl mercuric borate 

Pyridyl mercuric acetate 

1, 10-Phenanthroline 

Phenolthiosulfonic acid 

2-Phenoxyethanol (Ethylene glycol monophenyl ether) 

2-(2-Phenoxyethoxy)ethanol (Diethylene glycol phenyl 
ether) . 

2,2'-(p-Phenylene)diethanol 

m-Phenyleneisophthalamide 

Phenyl hydrogen phosphate - 

Phenyltrimethylammonium chloride 

Photographic chemicals: 

N-(o-Acetamidophenethyl)-l- hydroxy- 2- naphthamide 

2-(4-Amino-N-ethyl-m-toluidino) ethyl sulfate 

4-Amino-6-methylguaiacol (2-Methyl-6-methoxy-4-amino- 
phenol hydrochloride) . 

3-Amino-l,2,4-triazole (5-Amino-l,3,4-triazole) 

*Benzotriazole 

p-Benzylaminophenol hydrochloride 

Catechol (Pyrocatechin) 

3-Chloro-4-diethylaminobenzenediazonium chloride ( p- 
Diazo-2-ehlpro-N, N-diethylaniline) - zinc chloride. 
2-Chloro-N, N- diethyl- p-phenylenediamine hydrochloride— 

2,4-Diaminophenol dihydrochloride (Amidol) 

N-(4-Diazo-2,5-dibutoxyphenyl) morpholine, zinc chloride 

salt. 
N-(4-Diazo-2, 5-diethoxyphenyl) morpholine, zinc chloride 
salt. 

4— Diazo-1-morpholine benzene 

2,5-Diethoxy-4-morphinyldiazonium chloride - zinc 
chloride double salt. 



Manufacturers' identification codes 
(according to list in table 22) 



HSH. 
CRN. 
JCC, UCC. 

ICO. 

TNA. 

G. 

DOW, JCC, UCC. 

AMB. 

HSH, WIC. 

CCA, QCP. 

CCA. 

CCA, FER, HNX, HSH, MCI, MLD, MR, SHP, SM, SOC, SRR, 

SW, TRO, WTC. 
HNX, HSH, SW. 
CCA, CCC, FER, HNX, HSH, MCI, MLD, MON, MR, SHP, SM, 

SOC, SRR, SW, TRO, WTC. 
CCA, HNX, HSH, MCI, MLD, SOC, TRO, WTC. 
CCA. 
CCA, CCC, CCW, FER, HNX, HSH, MCI, MLD, MR, SHP, SM, 

SOC, SRR, SW, TRO, WTC. 
CCA. 
CCA, CCC, FER, HNX, HSH, MLD, SHP, SM, SOC, SRR, SW, 

TRO, WTC. 
CCA. 

CCA, HNX. 
CCA. 
CCA. 
CCA, CCC, FER, HNX, HSH, MCI, MLD, SHP, SOC, SRR, SW, 

TRO, WTC. 
WAY. 
ICO. 

SM. 
SM. 

WRC. 

MAL. 

COK. 

G. 

DOW, JCC. 

DOW. 



SM. 
BKL. 



EKT. 
EKT. 



FMT. 

EK, FMT, MEE, MRT. 

EK. 

KPT. 



IDC. 
VPC. 
IDC. 



FMT. 
G. 



170 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 21B. —Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer , iS65--Continued 



MISCELLANEOUS CHMICALS, CYCLIC--Continued 

Photographic chemicals — Continued 
*p-Diethylaminobenzenediazonium chloride (p-Diazo-N, N- 
diethylaniline) - zinc chloride. 
p-Diethylaminobenzenediazonium ( p-Diazo-N, N- diethy lani- 
line) fluoroborate. 

N, N-Diethyl-p-phenylenediamine hydrochloride 

*N, N-Diethyltoluene-2. 5- diamine, monohydrochloride 

2.5-Dihydroxy-p-benzenedisulfonic acid, dipotassium salt 

2,5-Dihydroxybenzenesulfonic acid 

2, 7-Dihydroxy-3, 6- naphthalene sulfonate 

p-Dimethylaminobenzenediazonium chloride ( p-Diazo-N, N- 

dimethylaniline) - zinc chloride. 
<i-(2',6'-Dimethylmorpholinyl)benzenediazonium chloride - 
zinc chloride. 

p-Diphenylaminediazonium sulfate 

p-(N-Ethylbenzimido)benzenediazonium chloride (p-Diazo- 

N-henzyl-N-ethylaniline) - zinc chloride. 
p-[ Ethyl( 2-hydroxyethyl) amino] benzenediazonium chloride 
(p-Diazo-N-ethyl-N-hydroxyethylaniline) - zinc chlo- 
ride. 

N-Ethyl-N-hydroxyethyl-p-phenylenediamine sulfate 

N-Ethyl-N-(p-methanesulfonamidoethyl)toluene-2,5-diamine 
sulfate. 

Hydroquinone ( Hydroquinol) 

p-[( 2-Hydroxyethyl) methylamino]benzenediazonium chloride 
( p-Diazo-N- hydroxyethyl-N-methylaniline) - zinc 
chloride. 
1- Hydroxy- N-( 2-hydroxyethyl) -2-naphthamide (2,3-Oxynaph- 
thoic-mono-ethanolamide) . 

l-(3-Hydroxyphenyl)urea 

4-Methoxy-l-naphthol 

p-Methylaminophenol sulfate (Metol) 

5-Methylbenzotriazole 

2-Methylbenzoxazole 

4-Methyl-l-phenyl-3-pyrazolidinone 

4-Morpholinylbenzenediazonium chloride - zinc chloride 
salt. 

4-Morpholinylbenzenediazonium fluoroborate 

6-Nitrobenzimidazole 

Octylphenyl salicylate 

Phenylmercaptotetrazole 

Phenyl-5-mercaptotetrazole 

l-Phenyl-3-pyrazolidinone 

4-Phenylpyrocatechol 

2-Eesorcylic monoethanolamide 

4,4'-Thiodiresorcinol (Diresorcyl sulfide) 

l-( 2, 4, 6-Trichlorophenyl) -3-( 4-nitroanilino) -2-pyraz- 
olin-5-one. 

All other 

Phthalic acid, lead salt, dibasic 

*Pinene 

Poly-4-( 2-acryloxy ethoxy) -2-hydroxybenzophenone 

Polyethylene terephthalate 

Poly-2-hydroxy-4-methacryloxybenzophenone 

Polyvinyl phthalate 

*Propyl gallate 

Pyrogallol (Pyrogallic acid) 

Resorcinol monobenzoate 

Rosin acid salts: 

Aluminum resinate 

Calcium resinate 

Copper resinate 

Iron resinate 

Lead resinate 

Manganese resinate 

Zinc resinate 

All other 

Salicylanilide 

Salicyclic acid, lead salt 

Silicones 



Manufacturers' identification codes 
( according to list in table 22) 



FMT, G, IDC, MRT. 
IDC. 



EKT, PMT. 
HCT, FMT, IDC. 



FMT. 
FMT, IDC. 



FMT. 
FMT, MRT. 



FMT, IDC. 



IDC. 
EKT. 



EKT. 
FMT, IDC. 



FMT, IDC. 
x. 

IK. 
EK. 

FMT. 
WAY. 
IDC. 

IDC. 

EK, FMT. 

EKT. 

TNC. 

FMT. 

GGY, WAY. 

x. 

FMT. 

HCC. 

EKT. 

EK, EKT, FMT. 

NTL. 

CBY, GLD, HNW, HPC. 

ACY. 

DUP, EK. 

DUP. 

EK. 

EKT, HN, HSH. 

MAL. 

HCT. 

JMS. 

JMS, SW. 

JMS. 

HSH, JMS. 

JMS, MCI. 

JMS. 

JMS, SW. 

JMS. 

DUP, FIN, MEE, PCW. 

NTL. 

DCC. 



MISCELLANEOUS CHEMICALS 



171 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer , 1965 — Continued 



Manufacturers' identification codes 
( according to list in table 22) 



MISCELLANEOUS CHEMICALS, CYCLIC— Continued 

Sodium cresoxide (Cresylic acid, sodium salt) 

Sodium ferric ethylenediamine di-o-hydroxyphenylacetate — 

Sucrose benzoate 

Sulfosalicylic acid 

Tall oil fatty acid chloride 

*Tall oil salts (Linoleic- rosin acid salts): 

Barium zinc tallate 

*Calcium tallate 

*Cobalt tallate 

Copper tallate 

*Iron tallate 

Lead manganese tallate 

*Lead tallate 

^Manganese tallate 

*Zine tallate 

Tannic acid 

*Tanning materials, synthetic: 

Hydroxytoluenesulfonlc acid, formaldehyde condensate 
( Cresol- formaldehyde sulfonate), sodium salt. 
*2-Naphthalenesulfonie acid, formaldehyde condensate and 
salts. 
1-Pheno 1-2- sulfonic acid, formaldehyde condensate 
(Phenol- formaldehyde, sulfonated) . 

1-Pheno 1-4- sulfonic acid, formaldehyde condensate 

Styrene maleic anhydride interpolymer, partial sodium 

salt. 
Sulfonyldiphenolsulfonic acid, formaldehyde condensate-- 

All other 

Tetra(n- butyl) ammonium picrate 

3,3',4,4'-Tetrachlorophenylurea 

1,2,3,4-Tetrahydronaphthalene (Tetralin) 

Tetrahydrothiophene 

Tetramethylaminoethylpiperazine 

Tetraphenyltin 

*Textile chemicals, other than surface-active agents: 
1, 3-Bis( hydroxymethyl) -2- imidazolidone ( Dimethylol 
ethylene urea) . 

N',N'-Diphenyl-l,2-propanediamine 

l-[ ( Octadecyloxy) methyl] pyridinium chloride 

Phenol, sulfurated 

Tetrahydro-3, 5-bis( methoxymethyl) -4H- 1, 3, 5-oxadiazin-4- 
one ( 1, 3- Bis( methoxymethyl) uron) . 

2,2',4,4'-Tetrahydroxybenzophenone 

All other 

2,2'-Thiobis[4-ehlorophenol] 

2,2'-Thiobis[4, 6-dichlorophenol] 

[ 2,2'-Thiobis(4-octylphenolate)] -n-butylamine nickel 

o-Toluidine formaldehyde hydrochloride 

Triallyl cyanurate 

Triaryl phosphites 

3,4',5-Tribromosalieylanilide 

3,4',5-Tribromosalicylanilide and dibromosalicylanilide 
mixtures. 

3,4,4'-Triehlorocarbanilide _ — 

Trichloromelamine 

l,3,5-Triehloro-s-triazine-2,4,6(lH,3H,5H)trione (Tri- 
chloroisocyanuric acid) . 

Tri-(m, p)-cresyl borate 

p-Trifluoromethylbenzonitrile 

s-Trioxane 

Triphenyl phosphite 

Triphenylphosphorus 

Triphenyltin acetate 

Triphenyltin chloride 

Tris( 1-aziridinyl) phospnine oxide 

2, 4, 6-Tris( 2-hydroxy-4-octyloxyphenyl) -s-triazine 

Uridine derivatives 

l-Vinyl-2-pyrrolidinone, monomer and polymer 

l-Vinyl-2-pyrrolidinone - vinyl acetate copolymer 



DEX, GOC. 
GGY. 
VEL. 

MON, MRK. 
G. 

HSH. 

CCA, HNX, HSH, MCI, MLD, TRO, VITC. 

CCA, CCC, FER, HNX, MCI, MLD, SHP, SRR, TRO, WTC. 

MCI, MLD, SHP, SRR. 

CCA, MCA, MCI, MLD, SRR, WTC. 

HSH, MCI. 

CCA, CCC, FER, HNX, HSH, MCI, MLD, SHP, SM, SRR, TRO, 

WTC. 

CCA, CCC, FER, HNX, HSH, MCI, MLD, SHP, SRR, TRO, WTC. 

CCA, HSH, MCI. 

HSH, MAL. 

GGY. 

AKS, GRD, NOP, NYC, RH. 

NAC, NOP, RH. 



AKS. 
DUP. 

G. 

GGY. 

MED. 

OTC. 

DUP. 

0R0, PAS. 

JCC. 

x. 

ACY, AKS. 

SNW. 
DUP. 



AKS, 


x, x. 


GIV. 




MON, 


SDH. 


ACY. 




RBC. 




ACY. 




WES. 




DOW, 


FIN, MEE, TRO 


FIN. 




MON. 




WTH. 




FMB, 


MON. 


USB. 




PIC. 




CEL. 




HK, 


MON. 



PLB. 
G. 

G. 



172 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 21B. 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



Manufacturers 1 identification codes 
( according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC 

*Acetaldehyde 

Acetamide 

Acetamidine hydrochloride 

Aeetamidoethanol ( N-Acetylethanolamine) 

*Acetic acid, synthetic, 100$ 

*Acetic acid salts: 

Aluminum acetate 

Aluminum subacetate 

Ammonium acetate 

Barium acetate 

Cadmium acetate 

Calcium acetate 

Chromium acetate 

Cobalt acetate 

*Copper acetate 

Lead acetate 

Lead subacetate 

Lead tetraacetate 

Magnesium acetate 

Manganese acetate 

Mercuric acetate 

Methylmercury acetate 

Nickel acetate 

*Potassium acetate 

Silver acetate 

*Sodium acetate 

Sodium diacetate 

Strontium acetate 

Uranyl acetate 

*Zine acetate 

* Zirconium acetate 

*Acetie anhydride, 100$: 

From acetaldehyde 

From acetic aeid_, other than recovered, by the vapor- 
phase process. 
From acetic acid, recovered, by the vapor-phase process- 

From ethylene 

Acetin: 

Mono- 

Tri - 

Acetoacetamidoacetamide 

*Acetone: 

*From cumene 

*From isopropyl alcohol 

*A11 other 

Acetone, dimethyl acetal (2,2-Dimethoxypropane) 

Acetone semicarbazone 

Acetonitrile 

Acetyl chloride 

Acetyl peroxide 

Aconitic acid 

Acrolein ( Acrylaldehyde) 

*Acrylic acid 

Acrylic monomers 

*Aerylonitrile 

*Adipic acid 

Adiponitrile 

*Alcohols, monohydric, unsubstituted: 
*Alcohols C9 or lower: 

Allyl alcohol 

Amyl alcohols: 
Unmixed: 

2»Methyl-2-butanol (tert-Amyl alcohol) 

3-Methylbutanol 

1-Pentanol 

2-Pentanol 

3-Pentanol 

Mixed: 

Fusel oil, refined 

Other than fusel oil 



CEL, 


COM, 


DIX, 


DUP, 


EKT, 


HPC, MON, PUB, SHC, UCC 


ACG. 














MRK. 














RBC. 














CEL, 


EKT, 


HPC, 


PUB, 


SNC, 


UCC. 




ACY, 


UCC. 












MAL. 














ACG, 


BKC, 


MAL, 


WSN. 








ACG, 


BKC, 


MAL. 










MAL, 


SHP. 












ACG, 


BKC, 


MAL, 


WSN. 








ACY. 














BKC, 


HSH, 


SHP. 










ACG, 


BKC, 


UCC 










ACG, 


BKC, 


MAL, 


SRR, 


sw. 






ACG, 


BKC, 


MAL. 










ABA. 














ACG, 


BKC. 












HSH, 


SHP. 












BKC, 


MAL. 












DUP. 














BKC, 


HSH, 


SHP. 










ACG, 


BKC, 


CWL, 


MAL, 


UCC, 


WSN. 




MAL. 














ACG, 


BKC, 


CEL, 


DAN, 


EKT, 


MAL, UCC, WSN. 




UCC. 














BKC. 














BKC. 














ACG, 


BKC, 


HSH, 


MAL, 


SNW, 


UCC. 




HSH, 


NTL, 


SNW. 










HPC. 














CEL, 


EST. 












CEL. 














UCC. 














ARC, 


HAL. 












EKT, 


WM. 












RBC. 














ACP, 


CLK, 


HPC, 


MON, 


SHC, 


SKO, SOC. 




EKT, 


EN J, 


SHC, 


UCC. 








CEL, 


DIX, 


HPC, 


TBK. 








DOW. 














NOR. 














EKX, 


SOH, 


UCC. 










TBK. 














WTL. 














PCW. 














SHC, 


UCC. 












BFG, 


CEL, 


DBC, 


MMM, 


UCC. 






BH. 














ACY, 


BFG, 


DUP, 


MON, 


SOH, 


UCC. 




CEL, 


DUP, 


MON, 


NAC, 


RH. 






DUP, 


MON. 












DOW, 


OMC, 


SHC. 










PAS, 


UCC. 












UCC. 














TBK, 


UCC. 












UCC. 














EK. 














PUB. 














CEL, 


PAS, 


UCC. 











MISCELLANEOUS CHEMICALS 



173 



TABLE 21B. —Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1965— Continued 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

*Aleohols, monohydric, unsubstituted — Continued 
*Alcohols C9 or lower — Continued 
*Butyl alcohols: 
Primary: 

*Iso ( Isopropylcarbinol) 

*Normal ( n-Propylcarbinol) 

Secondary (Methylethylcarbinol) 

Tertiary (Triinethylcarbinol) 

Mixed 

*Ethyl alcohol, synthetic 

2-Ethyl-l-butanol (sec-Hexyl alcohol) 

*2- Ethyl- 1-hexanol 

2-Ethyl-4-methyl-l-pentanol 

4- Ethyl- l-octyn-3-ol 

Heptyl alcohol 

*Hexyl alcohol 

3-Hexyne-2-ol 

*Iso-octyl alcohols 

*Isopropyl alcohol 

^Methanol, synthetic 

2-Methyl-3-buten-2-ol 

2-Methyl-3-butyn-2-ol 

4~Methyl-2-pentanol ( 1-Methylisobutylcarbinol) 

3-Methyl-l-pentyn-3-ol (Methylparafynol) 

1-Octanol ■ 

2-0ctanol 

Octanols, other 

Propyl alcohol (Propanol) 

2-Propyn-l-ol 

All other 

*Alcohols C10 or higher: 

*Deeyl alcohols 

3,9-Diethyl-6-tridecanol 

Dodecyl alcohol (Lauryl alcohol) (95$) 

7-Ethyl-2-methyl-4-hendecanol 

*l-Hexadeeanol (Cetyl alcohol) (95<f) 

*l-0ctadecanol (Stearyl alcohol) (95%) 

cis-9-0ctadecen-l-ol (Oleyl alcohol) 

Tallow alcohol 

Tetradecanol 

1-Tridecanol 

Tridecanol mixed isomers 

2, 6, 8-Trimethyl-4-nonanol 

All other 

Aldol (Acetaldol) 

ALkane and aliene hydrocarbons 

Aliyl and aliylene hydrocarbons 

Aliyl sulfides, mixed 

l-Allyl-3-( 2-hydroxyethyl) -2-thiourea ( N-p-Hydroxyethyl- 
N'-allylthiourea) . 

Allyl isocyanate 

Allyl isothiocyanate, nonflavoring grade 

Allyl methacrylate 

Allyl nitrile (Allyl cyanide) 

l-(Allyloxy)-2,3-epoxypropane (Allyl glycidyl ether) 

3-(Allyloxy)-l,2-propanediol (AlLyl glyceryl ether) 

Aluminum isopropoxide (Aluminum isopropylate) 

Amidinourea (Guanylurea) phosphate and sulfate 

*Amines: 

*Butylamine 

tert-Butylamine 

n-Butylethylamine 

Butylmethylamine 

Diallylamine 

*Dibutylamine 

Dibutylmethylamine (Methylbutylbutylamine) 

*Diethylamine ■ 

Diethylamine hydrochloride 

Diethylaminopropylamine 



Manufacturers' identification codes 
(according to list in table 22) 



CEL, DBC 


EKX, 


ENJ, SHC, UCC. 


CEL, CO, 


DBC, 


EKX, ENJ, SHC, UCC. 


ENJ, SHC 






SHC. 






CEL, DBC, 


EKX. 




CEL, DUP, 


EKX, 


ENJ, HPC, PSP, SHC, UCC, USI. 


UCC. 






CEL, EKX, 


ENJ, 


SHC, UCC. 


EKX. 






cue. 






EKX. 






EKX, ENJ, 


UCC. 




LIL. 






EKX, ENJ, 


GOC, 


HOU, 0X0, TID, UCC. 


ENJ, SHC, 


TBK, 


UCC. 


ACN, BOR, 


CEL, 


COM, DUP, ESC, GYR, HPC, WON, RH, SPN 


UCC. 






cue. 






cue. 






SHC, UCC. 






cue. 






DUP. 






PG, RH, WTH. 




IFF. 






CEL, UCC. 






G. 






CEL, CO, 


PG, TNA. 


DUP, ENJ, 


GOC, 


HOU, 0X0, PG, TBK, TID, TNK, UCC. 


UCC. 






DUP, PG, 


RH. 




UCC. 






ADM, DUP, 


ENJ, 


GIV, PG, RH. 


ADM, DUP, 


PG, 


RH. 


ADM, DUP. 






ADM. 






PG. 






ENJ, GOC. 






UCC. 






UCC. 






ADM, CO, 


EKX, 


PG, RH, SHC, TNA. 


UCC. 






HMY. 






ADM, GOC. 






OHO. 






FMT, IDC. 






CTN. 






ICO. 






SAR. 






KF. 






SHC. 






SHC. 






CHT, SFA. 






ACY. 






EKT, PAS, 


UCC, 


VGC. 


»N, RH. 






PAS. 






PAS. 






SHC. 






'AS, UCC, 


VGC. 




UCC. 






DUP, PAS, 


UCC, 


VGC. 



174 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 21B. 



--Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1965 — Continued 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

*Amines — Continued 

Diethylenetriamine 

N, N-Diethylethylenediamine 

N jN 1 -Diethyl- 1, 4- pentanediamine (Novoldiamine) 

N, N-Diethyl-l,3-propanediamine 

Diisobutylamine 

Diisopropylamine 

*Dimethy lamine 

Dimethylamine hydrochloride 

Dimethylamine sulfate 

Dime thy land nopropy lamine 

Dipentylamine (Diamylamine) 

Dipropy lamine 

Dipropylenetriamine 

*Ethy lamine 

Ethylenediamine 

Ethylenediamine sulfate 

n-Heptylamine 

1, 6-Hexanediamine ( Hexamethylenediamine) 

N-Hexylamine 

3,3'-Iminobispropylamine 

Isobuty lamine 

*Isopropy lamine 

Methy lamine hydrochloride 

*Methylamine, mono- 

N-Methylethylenediamine 

N-Methyl-l,3-propanediamine 

Methyltriethylenediamine 

Pentaethylenehexamine 

Pentylamine (Mono amy lamine) 

1, 2-Propanediamine (Propylenediamine) 

1, 3-Propanediamine 

Propylamine 

Tetraethylenepentamine 

N,N,N',N'-Tetramethyl-l,3-butanediamine 

Tetramethylethylenediamine 

Tributy lamine 

Triethylamine 

Triethylenetetramine 

*Trimethy lamine 

Tripenty lamine 

All other 

2-Amino-l-butanol 

1-Aminoethanol (Acetaldehyde ammonia) 

Aminoethoxyethanol 

2-( 2-Aminoethylamino) ethanol ( Aminoethylethanolamine) 

2-Aminoethyl vinyl ether 

Aminoguanidine bicarbonate 

2- Amino-2- ( hydroxymethyl) - 1, 3-propanediol ( Tris( hydroxy- 
methyl) aminomethane) . 

2-Amino-2-methyl-l-propanol hydrochloride — — 

2-Amino-l-propanol 

3-Amino-l-propanol 

Amyl acetates, 90$: 

Amyl acetate (n-Pentyl acetate) 

Isopentyl acetate ( Isoamyl acetate) 

Mixed 

Azelaic acid 

1, l'-Azobisformamide ( Azodicarbonamide) 

2,2'-Azobis(2-methylpropionamidine) hydrochloride 

Behenamide (Docosanamide) 

Behenic acid 

Bis(2-butoxyethyl) ether (Diethylene glycol di-n- butyl 
ether) . 

Bis( 2-chloroethoxy) methane ( Dichloroetnylformal) 

*Bis(2-chloroethyl) ether ( Dichlorodiethyl ether) 

Bis(2-ehloroethyl) and bis(2-chloro-l-methylethyl) ethers 

mixed. 
Bis( chloromethyl) ether 



Manufacturers' identification codes 
( according to list in table 22) 



DOW, 


JCC, 


UCC. 


ALB, 


COK. 




SDH. 






JCC. 






PAS. 






PAS, 


UCC, 


VGC. 


COM, 


DUP, 


PAS, RH. 


GAM, 


TNC. 




RH. 






UCC. 






PAS, 


VGC. 




PAS, 


UCC. 




UCC. 






ESC, 


PAS, 


UCC, VGC. 


DOW, 


JCC, 


UCC. 


EK. 






ALB. 






CEL, 


DUP, 


MON. 


VGC. 






JCC, 


UCC. 




PAS, 


VGC. 




ESC, 


PAS, 


UCC. 


RBC. 






COM, 


DUP, 


ESC, g, p; 


ALB. 






ALB. 






JCC. 






DOW. 






EK, 


3 AS. 




JCC, 


UCC. 




UCC. 






PAS, 


UCC. 




DOW, 


UCC. 




UCC. 






RH. 






PAS, 


VGC. 




PAS, 


UCC. 




ccw, 


DOW, 


UCC. 


COM, 


DUP, 


PAS, RH. 


PAS. 






ALB, 


DUP, 


ONX, UCC. 


COM. 






PAS. 






JCC. 






DOW, 


JCC, 


UCC. 


MEE, 


RH. 




TBJ. 






COM. 






SNW. 






LIL. 






UCC. 






PUB, 


TBK. 




FB, 


NW. 




CEL, 


PAS, 


UCC. 


EMR. 






FMT, 


NPI, 


USR. 


X. 






HUM. 






ADM. 






DOW, 


UCC. 




TKL. 






DOW 


JCC 


CMC, UCC. 


WYN. 







MISCELLANEOUS CHEMICALS 



175 



TABLE 21B.- 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer , 1965- -Continued 



Manufacturers' identification codes 
( according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

Bis(2-chloro-l-methylethyl) ether ( Dichloroisopropyl 

ether) . 
Bis(2-ethoxyethyl) ether (Di ethylene glycol diethyl ether) 
Bis(hydroxyethyl) ether butynediol 

1, 3-Bis( hydroxymethyl) urea ( Dimethylolurea) 

Bis[2-(2-methoxyethoxy)ethyl] ether ( Tetraethylene glycol 

dimethyl ether) . 
Bis(2-methoxyethyl) ether (Diethylene glycol dimethyl 
ether) . 

Bis( tributyltin) oxide 

Biuret 

Boron organic compounds: 

Boron fluoride ethyl ether complex 

Boron trifluoride monoethylamine complex 

tert-Butylaminoborane 

Triethylborane 

Triethyl borate 

Trimethoxyboroxine 

Trimethylaminoborane 

All other 

N-Bromoaeetamide 

fj-Bromopropionic acid 

1, 2(and l,3)-Butanediol (Butylene glycol) 

1,4-Butanediol 

2,3-Butanediol (2,3-Butylene glycol) 

2,3-Butanedione 2-oxime 

1,2,4-Butanetriol 

*2-Butanone (Methyl ethyl ketone) 

Butanone mixture 

*2-Butanone oxime 

*2-Butanone peroxide 

2-Butene-l,4-diol 

l-Butoxy-2,3-epoxypropane (Butyl glycidyl ether) 

2-Butoxyethanol (Ethylene glycol monobutyl ether) 

2-(2-Butoxyethoxy)ethanol (Diethylene glycol monobutyl 

ether) . 
2-[2-(2-Butoxyethoxy)ethoxy] ethanol (Triethylene glycol 
monobutyl ether) . 

2-(2-Butoxyethoxy) ethyl acetate 

l-Butoxyethoxy-2-propanol 

2-Butoxyethyl acetate 

*Butyl acetates: 

Iso 

*Normal 

Secondary 

Tertiary 

Mixed 

Butyl aery late 

Butylene oxide 

Butyl ether (Di-n-butyl ether) 

Butylethylthiourea 

*tert- Butyl hydroperoxide 

2,2'-(Butylimino)diethanol (N,N-Bis(2-hydroxyethyl)butyl- 
amine) . 

Butyl isocyanate * 

Butyl lactate 

n-Butyllithium 

sec-Butyllithium 

Butyl maleate, mono- 

Butyl oxalate partial ester 

*tert-Butyl peroxide (Di-tert- butyl peroxide) 

tert- Butyl peroxyacetate 

tert- Butyl peroxyisobutyrate 

tert-Butyl peroxyisopropyl carbonate 

tert- Butyl peroxypivalate 

Butyl vinyl ether 

1-Butyne ( Ethylacetylene) 

2-Butyne-l,4-diol 

Butyraldehyde 

Butyraldehyde oxime 



DOW. 

ucc. 

G. 

DEC, GLY, x. 

ASL. 

ASL, OMC. 

CCW, x. 
SW. 

ACG. 

ACG. 

CAL. 

CAL, TNA. 

USB. 

CAL. 

CAL. 

CAL, SFA, USB. 

ARA. 

ABB. 

CEL. 



EK. 

G. 

CEL, 

CEL. 

ALB, 

AZT, 

G. 

DOW, 

JCC, 

JCC, 



DIX, ENJ, SHC, SPI, UCC. 



CCA, MID, NAC, TED. 
CAD, NOC, RIC, UPR, WTL. 



SHC. 

OMC, SHC, UCC. 

OMC, SHC, UCC. 



DOW, OMC, UCC. 

UCC. 
UCC. 
UCC. 



CEL, 

CEL, 

EK, 

ENJ. 

CEL. 

CEL, 

DOW, 

UCC. 

PAS. 

AZT, 

PAS. 

CTN, 
COM, 
FTE. 
FIE. 
RUB. 
DUP. 
AZT, 
WTL. 
WTL. 
PPG. 
WTL. 
UCC. 

cue. 

G. 

CEL, 
NAC. 



EKT, UCC. 

EKT, ENJ, PUB, UCC. 
ENJ, HPC, PUB, SHC. 



DBC, UCC. 
UCC. 



CAD, UPR, WTL. 



UPJ. 
CWN, UPC. 



CAD, SHC, UPR, WTL. 



HOC, UCC. 



176 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 21B -Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1965 — Continued 



Chemical 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 



*Butyric acid 

Butyric anhydride 

Butyrolactone 

Butyronitrile 

Butyryl chloride 

*Caprolactam (Hexahydro-2H-azepin-2-one) 

Capro lactone 

*Carbon disulfide 

^Cellulose esters: 

^Cellulose acetate 

Cellulose acetate butyrate 

Cellulose acetate propionate 

Cellulose propionate 

Nitrocellulose (Cellulose nitrate) 

^Cellulose ethers: 

Ethylcellulose 

Ethylhydroxyethylcellulose 

Hydroxyethylcellulose 

Methylcellulose 

*Sodium carboxymethylcellulose, 100% 

Sodium carboxymethylhydroxyethylcellulose 

Cetyl chloride 

Cetyl lactate 

*Chloral ( Trichloroacetaldehyde) 

Chloroacetamide 

*Chloroacetic acid, mono- 

Chloroacetic acid, mono-, derivatives: 

Butyl chloroacetate 

Ethyl chloroacetate 

2-Ethylhexyl chloroacetate 

*Methyl chloroacetate 

Sodium chloroacetate 

Chloroacetonitrile 

Chloroacetyl chloride 

P-Chloroallyl-N-methylamine 

Chlorocholine chloride ~~ 

2-Chloro-l, 1-dimethoxyethane (Dimethyl chloroacetal) - 
*2-Chloro-N, N-dimethylethylamine ( Dimethylaminoethyl 
chloride) hydrochloride. 

2-Chloro-N,N-dimethylpropylamine 

3-Chloro-N, N-dimethylpropylamine hydrochloride 

2-Chloroethanol (Ethylene chlorohydrin) 

2-Chloroethylamine 

2-Chloroethyl chloroformate 

2-Chloroethyl vinyl ether 

Chloromethyl methyl ether -■ 

l-Chloro-l-penten-3-one (p-Chloro vinyl ethyl ketone)- 
3-Chloro-l,2-propanediol (Glycerol a-chlorohydrin)--- 

l-Chloro-2-propanone ( Chloroacetone) 

N-Chlorosuccinimide ( Succinichlorimide) 

2-Chlorotriethylamine hydrochloride 

Chlorotrlmethylsilane 

Choline base 

Citric acid 

Citric acid salts: 

Ammonium citrate 

Calcium citrate 

Ferric ammonium citrate 

Ferric citrate 

Ferrous calcium citrate 

Potassium citrate 

Sodium citrate 

All other 

Coconitrile 

Coconut oil amide 

Cottonseed oil acids, ammonium salt 

Cottonseed oil nitrile 

Creatine and creatinine 

Crotonaldehyde 



Manufacturers' identification codes 
( according to list in table 22) 



CEL, EKT, UCC. 
EKT, UCC. 



DBC, DUP, NAC. 

UCC. 

ACG, BKT, FMB, PAS, PPG, SF. 

AV, CEL, DUP, EKT. 

EKT. 

EKT. 

CEL. 

DUP, HPC. 



DOW, 


HPC. 


HPC. 




HPC, 


UCC. 


DOW. 




BUK, 


DUP, HPC, KON, WYM. 


HPC. 




BC. 




VND. 




DA, FMB, GGY, MTO. 


BPC, 


DOW. 


BUK, 


DA, DOW, HPC, MON. 


MON. 




DOW, 


KF, WON. 


MON. 




BPC, 


DOW, KF. 


DOW. 




BPC. 




DOW, 


DUP. 


LIL. 




ACY. 




LIL. 




ABB, 


GAM, HEX, MCH, NES, PAS 


SK. 




MCH. 




CMC, 


UCC. 


ICI. 




CTN. 




UCC. 




HK, 


X. 


ABB. 




EVN, 


ICO, OTC. 


EK, 


MRK. 


ARA, 


NAC. 


MCH, 


PAS, X. 


DCC. 




EH. 




MLS, 


PFZ. 


MAL, 


PFZ. 


PFZ. 




MAL, 


PFZ. 


MAL. 




X. 




MLS 


PFZ. 


MLS 


PFZ. 


MLS 




FOR, 




ARC 


CRT, PG. 


GLY 




FOR 




PFN 




CEL 


EKT, UCC. 



MISCELLANEOUS CHEMICALS 



177 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1965 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 



Crotonic acid (2-Butenoic acid) 

Crotononitrile 

2-Cyanoacetamide 

Cyanoacethydrazide 

Cyanoacetic acid 

Cyanogen bromide 

3-Cyanopropylamine 

1, 10-Decanediol 

Decanoyl chloride 

*Decanoyl peroxide 

Dialdehyde starch 

Diallylcyanamide 

Diallyl maleate 

1, 2-Dibutoxyethane (Ethylene glycol di-n- butyl ether) - 

2-Dibutylaminoethanol 

*Dibutyl fumarate 

*Dibutyl maleate 

1, 3-Dibuty 1-2- thiourea 

Dibutyltin compounds: 

Dibutylmethoxytin (Dibutyltin methoxide) 

Dibutyltin bis( lauryl mercaptide) 

Dibutyltin dichloride 

Dibutyltin dilaurate 

Dibutyltin maleate 

Dibutyltin mercaptopropionate 

Dibutyltin oxide 

All other 

Dichloroacetaldehyde 

Dichloroacetic acid 

2,2-Dichloro-l, 1-difluoroethyl methyl ether 

Dichlorodimethylsilane 

Dichloromethylsilane 

Dichloromethylvinylsilane 

l,3-Dichloro-2-propanol 

Dicyanobutene 

Diethyl allyl( 1-methylbutyl) malonate 

Diethylaluminum chloride 

Diethylaluminum iodide 

Diethylaminoethanethiol 

*2-Diethylaminoethanol 

2-(2-Diethylaminoethoxy) ethanol 

2-Diethylaminoethyl methacrylate 

Diethylaminopropionamide 

Diethyl sec-butylethylmalonate 

Diethyl butylmalonate 

Diethyl sec- butylmalonate 

Diethylcarbamoyl chloride 

Diethyl carbonate (Ethyl carbonate) 

Diethyl diethylmalonate (Diethyl malonic ester) 

*Diethylene glycol 

Diethylene glycol, borated 

Diethylene glycol chloroformate 

Diethyl ( ethoxymethylene) malonate 

Diethyl ethylisopentylmalonate 

Diethyl ethylmalonate (Ethyl malonic ester) 

Diethyl ethyl( 1-methylbutyl) malonate 

Diethyl ethyl(3-methylbutyl) malonate 

Diethyl ethyl( 1-methylpropyl) malonate 

Di-2- ethyl- 1-hexyl fumarate 

Di-2- ethyl- 1-hexyl maleate 

Diethylhydroxylamine 

N, N-Diethylhydroxylamine sulfate 

Diethyl maleate 

Diethyl malonate (Malonic ester) 

Diethyl ( 1-methylbutyl) malonate 

Diethyl (3-methylbutyl) malonate 

Diethyl ( 1-methylpropyl) malonate 

Diethyl oxalate (Ethyl oxalate) 

Diethyl phosphorochloridothioate — 



EEC. 

KF. 

KF. 

KF. 

KF. 

ffl. 

EKT. 

NEP. 

TBK, UCC. 

CAD, UPR, WTL. 

MLS. 

ACY. 

FMP. 

DOW. 

AAC, PAS. 

MON, PCC, PFZ, RCI, RUB. 

CUC, DUP, GRH, MON, PCC, RCI, RUB. 

PAS, RBC. 

CCA. 
x. 

CCW, x. 

CCA, x. 

CCA, x. 

CCA, x. 



PAS, UCC. 



FMP. 



CAU, DIX, DOW, G, HCH, JCC, CMC, UCC, WYN. 



ABB, 

GAM 

CTN 

BPC 

ACN 

GLY. 

PPG, 

KF. 

LIL. 

BPC, LIL. 

ABB, BPC. 

BPC. 

BPC. 

RUB. 

RUB. 

PAS. 

EK. 

ACY, ICO, UCC. 

ABB, KF, LIL. 

ABB, BPC, LIL. 

BPC. 

BPC. 

FMP. 

MON, SF. 



l,3-Diethyl-2- thiourea | pas, RBC 



178 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 21B —Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1965— Continued 



Chemical 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

Diethylzinc 

Diglycolio acid 

Dihexyl fumarate 

Dihydropseudoionone 

2,4-Dihydroxy-3,3-dimethylbutyric acid, Y- lactone (Panto- 
lactone) . 

l,3-Dihydroxy-2-propanone (Dihydroxy acetone) 

Diisobutylaluminum chloride 

Diisobutylaluminum hydride 

Diisononyl maleate 

Diiso-octyl fumarate 

2-Diisopropylaminoethanol ( N, N-Diisopropylethanolamine) — 

Diisopropylammonium nitrite 

Diisopropylcarbodiimide 

Diisopropyl peroxydicarbonate ( Isopropyl percarbonate) 

1,3-Diisopropy 1-2- thiourea 

*Dilauryl 3,3'-thiodipropionate (Didodecyl thiodipropio- 
nate) . 

Dimethoxyethane ( Ethylene glycol dimethyl ether) 

N,N-Dimethylacetamide 

N, N-Dimethylacetoaeetamide 

*2-Dimethylaminoethanol 

Dimethylaminoethyl methaerylate 

Dime thy lamino-2-propanol 

3-Dimethylaminopropionitrile 

N-(3-Dimethylaniinopropyl)oleamide 

Dimethylcarbamoyl chloride 

Dimethyl carbonate 

2, 5-Dimethyl-2, 5-di( tert-butylperoxy) hexane 

2,5-Dimethyl-2,5-di(tert-butylperoxy)hexyne-3 

N, N-Dimethylformamide 

2, 6-Dimethyl-4-heptanol ( Diisobutylcarbinol) 

2,5-Dimethyl-2,5-hexanediol 

2,5-Dimethylhexane-2,5-diperoctoate 

2, 5-Dimethyl-3-hexyne-2, 5-diol 

1, 1-Dimethylhydrazine 

Dimethyl malonate 

Di(4-methyl-2-pentyl) maleate 

0, 0-Dimethyl phosphorochloridothioate 

2,2-Dimethyl-l,3-propanediol (Neopentyl glycol) 

Dimethylthiophosphoryl chloride 

Dioctanoyl peroxide (Capryloyl peroxide) 

Dioctyl fumarate 

*Dioctyl maleate 

*Dipropylene glycol 

Distearyl 3,3'-thiodipropionate 

Dithiobis( stearylpropionate) (Distearyl dithiodipropio- 
nate) . 

2,5-Dithiobiurea 

Dithiooxamide 

Ditridecyl maleate 

n-Dodecane 

Dodecenylsuccinie anhydride 

tert-Dodecyldisuccinamide 

n-Eicosane 

Epichlorohydrin 

*Erucamide 

Ethanedithiol 

* Ethanolamines : 

*2-Aminoethanol (Monoethanolamine) 

*2,2'-Iminodiethanol (Diethanolamine) 

*2,2',2"-Nitrilotriethanol (Triethanolamine) 

Ethanolamine hydrochloride 

Ethanolamine sulfate 

Ethanolamine sulfite 

Ethanolamine trihydrochloride 

*2-Ethoxyethanol (Ethylene glycol monoethyl ether) 

*2-(2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl 
ether) . 



Manufacturers' identification codes 
( according to list in table 22) 



TNA. 

DUP. 
FB. 
GIV. 
CKL. 

BAX, PFZ. 

TSA. 

TSA. 

RUB. 

HUB. 

PAS, UCC. 

CMC. 

G. 

PPG. 

G. 

ACY, CCW, EVN, HAB. 



ASL. 
DUP, 
EKT. 
AAC, 
AAC. 
COM, 
ACY. 
DUP. 
OTC. 
CTN. 
WTL. 
WTL. 
DUP. 
UCC. 

cue. 

UPR. 
CUC. 
FMP. 
KF. 



MON. 

JCC, PAS, RH, UCC. 

UCC. 



RUB. 










MON, 


SF. 








EKX. 










TBK. 










CEM. 










MON. 










CRT, 


MON, 


PCC, 


RCI. 




CEL, 


DOW, 


JCC, 


OMC, UCC, WYN 


ACY, 


CCW, 


EVN. 






EVM. 










ACY. 










MAL. 










RUB. 










HMY. 










HMY, 


MON, 


NAC. 






SM. 










HMY. 










DOW, 


SHC, 


UCC. 






ADM, 


ARC, 


FIN, 


HUM. 




RBC. 










ACN, 


DOW, 


JCC, 


UCC. 




ACN, 


DOW, 


JCC, 


UCC. 




ACN, 


DOW, 


JCC, 


UCC. 




WSN. 










EVN. 










SUM. 










TNC. 










DOW, 


JCC, 


OMC, 


UCC. 




DOW, 


JCC, 


OMC, 


UCC. 





MISCELLANEOUS CHEMICALS 



179 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1965 — Continued 



Manufacturers' identification codes 
( according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

*2-[2-(2-Ethoxyethoxy) ethoxy] ethanol (Triethylene glycol 
monoethyl ether) . 

2-(2-Ethoxyethoxy) ethyl acetate 

2-Ethoxyethyl acetate 

Ethoxymethylene malononitrile 

Ethoxypropanol 

3-Ethoxypropionitrile 

1- Ethoxy- 1,3, 3- trimethoxypropane 

Ethyl acetamidocyanoacetate 

Ethyl acetamidomalonate 

*Ethyl acetate, 85$ 

Ethyl acetoacetate 

*Ethyl aery late 

Ethyl allyl-( l-methyl-2-pentyl) cyanoacetate 

Ethylaluminum dichloride 

Ethylaluminum sesquichloride 

2-Ethylaminoethanol ( Ethylmonoethanolamine) 

2-Ethylbutyraldehyde 

2- Ethylbutyric acid (Diethylacetic acid) 

Ethyl carbamate 

Ethyl carbodiimide 

Ethyl chloroformate 

Ethyl 3-( ehloroformyl) propionate (fj-Carbethoxypropionyl 
chloride) . 

Ethyl cyanoacetate 

Ethylene, from ethyl alcohol 

Ethylene carbonate 

Ethylenediamine, propoxylated 

* Ethylene glycol 

Ethylene glycol diacetate 

Ethylene glycol dimethacrylate 

* Ethylene oxide 

Ethylene trithiocarbonate 

*Ethyl ether: 

Absolute 

Tech 

U.S.P, - — 

Ethylethoxymethylene cyanoacetate 

Ethyl formate 

2- Ethylhexanal (a-Ethylcaproaldehyde) 

2-Ethyl-l,3-hexanediol 

2- Ethylhexanoic acid (x-Ethylcaproic acid) 

*2- Ethylhexanoic acid (a-Ethylcaproic acid) salts: 

Aluminum 2-ethylhexanoate 

Barium 2-ethylhexanoate 

Cadmium 2-ethylhexanoate 

^Calcium 2-ethylliexanoate 

*Cobalt 2-ethylhexanoate 

Copper 2-ethylhexanoate 

Dibutyltin di-2-ethylhexanoate 

Iron 2-ethylhexanoate 

*Lead 2-ethylhexanoate 

*Manganese 2-ethylhexanoate 

Nickel 2-ethylhexanoate 

Potassium 2-ethylhexanoate 

Rare earths 2-ethylhexanoate 

Stannous 2-ethylhexanoate 

Strontium 2-ethylhexanoate 

*Zinc 2-ethylhexanoate 

Zirconium 2-ethylhexanoate 

*2-Ethyl-l-hexyl acetate 

*2-Ethyl-l-hexyl acrylate 

2-Ethylhexyl cyanoacetate 

2-Ethylhexyl methaerylate 

Ethyl 2-hydroxy-3-methylbutyrate ( Ethyl a-hydroxyiso- 

valerate) . 
2- Ethyl-2- ( hydroxymethyl) - 1, 3- propanediol ( Trimethylol- 

propane) . 
2- Ethyl-2- ( hydroxymethyl) - 1, 3-propanediol allyl ethers— 



DOW, 


OMC, 


UCC. 


UCC. 






DOW, 


EKT, 


UCC. 


KF. 






UCC. 






ACY. 






KF. 






SDW. 






SDW. 






CEL, 


EKT, 


ENJ, HPC, MON, PUB, UCC 


EXT, 


FMP, 


UCC. 


CEL, 


DBC, 


RH, UCC. 


LIL. 






TNA, 


TSA. 




TNA, 


TSA. 




PAS. 






UCC. 






UCC. 






EKL, 


FMP. 




OTC. 






CTN, 


FMP. 




ABB. 







KF. 

OH. 

DOW, JCC, UCC. 

PCS. 

ACN, APD, CAU, CEL, DOW, DUP, G, HCH, JCC, OMC, UCC, 

WYN. 
UCC. 
SAR. 

ACN, CAU, DOW, G, HCH, JCC, OMC, SNO, UCC, WYN. 
EVN. 

MAL. 

ENJ, HPC, UCC, USI. 

MAL, OMS. 

KF. 

COM, FB. 

EKX, UCC. 

UCC. 

EKT, UCC. 



WTC. 

CCA. 

CCA, 

CCA, 

CCA, 

CCA, 

x. 

CCA. 

CCA, 

CCA, 

MCI. 

CCA. 

CCA. 

WTC, 

CCA. 

CCA, 

CCA, 

CEL, 

CEL, 

G. 



CEL. 
CEL. 



FER, HNX, HSH, MCI, MLD, SRR, SW, WTC. 
FES, HNX, HSH, MCI, MLD, SHP, SRR, SW, WTC. 
MLD, SRR. 



HNX, HSH, MCI, MLD, SHP, SRR, SW, WTC. 
HNX, MCI, MLD, SHP, SRR. 



HNX, HSH, MCI, SRR, SYP, WTC. 

HNX, WTC. 

EKT, UCC. 

DBC, UCC. 



180 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1965 — Continued 



Manufacturers' identification codes 
( according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

Ethylidine diacetate 

2, 2 '-( Ethylindno) diethanol ( N-Ethyldiethanolamine) — 

2-( Ethylmercapto) ethanol 

Ethylmereuric chloride 

Ethyl ( l-methyl-2-pentyl) eyanoacetate 

Ethyl propionate 

Ethyl silicate (Tetraethoxysilane) 

Ethyl sulfate (Diethyl sulfate) 

Ethyl vinyl ether 

Fats and oils, chemically modified: 

Lard oil, nitrated 

Vegetable oils, brominated 

Other 

Fatty acids, chemically modified: 

cc-Bromo( lauric-stearic) acids 

Castor oil fatty acids, dehydrated- 

All other 

Fatty acid esters, not included with plasticizers or 
surface- active agents: 

Ethyl stearate 

Hexadecyl stearate 

Isopropyl linoleate 

Isopropyl myristate 

Isopropyl oleate 

Methyl ester of coconut oil 

Methyl esters of tallow 

Methyl 12-hydroxystearat*-~— 

Methyl stearate 

All other 

Fish oil fatty acid amide 

Flotation reagents: 
Phosphorodithioates ( Dithiophosphates) : 

Potassium dihexyl phosphorodithioate 

Sodium di-sec-butyl diethyl phosphorodithioate — 

Sodium di-see-butyl phosphorodithioate 

Sodium diethyl phosphorodithioate 

Sodium dihexyl phosphorodithioate 

Sodium diisopropyl phosphorodithioate 

Other 

Xanthates: 

Potassium n-butylxanthate 

Potassium ethylxanthate 

Potassium hexylxanthate 

Potassium isopropylxanthate 

Potassium pentylxanthates 

Potassium sec-pentylxanthate 

Sodium n-butylxanthate 

Sodium sec-butyLxanthate 

Sodium ethylxanthate 

Sodium isobutylxanthate ; 

Sodium isopropylxanthate 

All other 

^Formaldehyde, 37$ by weight 

Formajrd.de 

Formamidine disulfide dihydrochloride 

*Formic acid, 90$ 

*Formic acid salts: 

Aluminum formate 

Ammonium formate 

Calcium formate 

Chromic formate 

Chromium formate 

Copper formate 

Lead formate 

Nickel formate 

Potassium formate 

Sodium formate, refined 

Sodium formate, tech 

Thallous formate — - — 



CEL. 

ucc. 

PAS. 

LIL. 

LIL. 

FB, NW, TBK. 

MTR, SFA, UCC 

UCC. 

UCC. 

SM. 
DOM. 
CHL, x. 

DUP. 
BAC. 
ABB, RH, RT, x. 



ICO. 
ARC, 
VND. 
TBK. 
CRT. 
STP. 
BFR, 
BAC. 
ICO. 
DRW, 
ADM. 



EWR, ICI, PCS, PG, RT. 



ACY. 
ACY. 
ACY. 
ACY. 
ACY. 
ACY. 
ACY. 



USR. 

ACY, DOW. 

DOW. 

DOW. 

ACY, DOW. 

DOW. 

KCC, USR. 

ACY, DOW. 

ACY, DOW. 

DOW. 

ACY, DOW. 

ACY, DOW. 

ACN, BOR, CBC, CEL, COM, DUP, G, HKD, HN, HPC, ICI, 

MON, RCI, RH, SPN, TRJ, UCP. 
DUP. 
WAY. 
DUP, HN, SF, SNC, UCC. 

SF, SNW, UCC. 

ACG, WSN. 

TRJ. 

G. 

NAC. 

CTN. 

NTL. 

HSH. 

TNC. 

ACG, BKC, SF. 

HN, HPC. 

EK. 



MISCELLANEOUS CHEMICALS 



131 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, iS65--Continued 



Manufacturers' identification codes 
( according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

*Fumaric acid 

Fumaric acid, lead salt 

Geranyl crotonate 

Glucoheptono lactone 

^Gluconic acid, tech 

Gluconic acid, ammonium salt 

^Gluconic acid, sodium salt, tech 

Glucono-delta- lactone 

Glutaraldehyde 

Glutaraldehyde bis[ sodium bisulfite] 

Glutaric anhydride 

Glycerol, synthetic 

Glycidol (2,3-Epoxy-l-propanol) 

Glycine (Aminoacetic acid), tech 

Glycine, cupric salt 

Glycine ethyl ester hydrochloride 

Glycine, potassium and sodium salts 

Glycol adipate 

Glycolic acid ( Hydroxyacetic acid) 

Glycolic acid salts: 

Aluminum glycolate 

Sodium glycolate 

Glycolonitrile 

Glyoxal 

Guanidine hydrochloride 

4-Guanyl-l-isonitrosoguanyl-l-tetrazene 

*Halogenated hydrocarbons: 

*l-Bromobutane (n-Butyl bromide) 

2-Bromobutane (sec-Butyl bromide) 

Bromochlorome thane 

l-Bromo-3-ehloropropane (Trimethylenechloro bromide) 

2-Bromo-2-chloro-l, 1, 1-trifluoroethane 

1-Bromodecane 

1-Bromododecane 

Bromoethane (Ethyl bromide) 

1-Bromohexadecane (Cetyl bromide) 

1-Bromohexane (n-Hexyl bromide) 

l-Bromo-2-methylbutane 

l-Bromo-3-methyTbutane 

1-Bromo-octadecane 

1-Bromopentane (n-Amyl bromide) 

2-Bromopentane ( 1-Methylbutyl bromide) 

1- Bromopropane (n-Propyl bromide) 

2- Bromopropane (isopropyl bromide) 

2-Bromopropene 

3-Bromopropene (Allyl bromide) 

3-Bromopropyne 

Bromotrifluoromethane 

*Carbon tetrachloride 

^Chlorinated paraffins: 

Less than 35$ chlorine 

355&-64# chlorine 

6556 or more chlorine 

1-Chloro butane (n- Butyl chloride) 

2-Chlorobutane (sec-Butyl chloride) 

1-Chloro-l, 1-difluoroethane 

*Chlorodifluoromethane 

*Chloroethane (Ethyl chloride): 

Tech 

U.S.P 

*Chloroform: 

Tech 

U.S.P 

2-Chloro-3-hexyne 

*Chloromethane (Methyl chloride): 

Crude 

Refined (refrigerant grade) 

2-Chloro-2-methylpropane ( tert- Butyl chloride) 

3-Chloro-2-methylpropene (Methallyl chloride) 

Chloropentafluoroethane 



HN, MON, NAC, PCC, PFZ, PTT, SOC, STP. 

NTL. 

FB. 

PFN. 

CWL, DLI, IBI, PFZ. 

PFZ. 

CWL, 

DLI, 

UCC. 

IDC, RZL. 

UCC. 

APD, DOW, SHC. 

DIX, OTC. 

BPC, CHT. 



DLI, IBI, PFZ, PMP. 
PFZ. 



CIB. 




MED, 


TNC. 


ACY. 




UCC. 




ACY. 




REM. 




ABB, 


BPC, DOW, MCH 


ABB, 


BPC. 


DOW. 




DOW, 


MCH. 


ICI. 




G. 




DUP. 




DOW, 


MCH. 


EK. 




BPC. 




LIL. 




BPC, 


LIL. 


DUP, 


G. 


BPC, 


EK, OPC. 


ABB, 


BPC, LIL. 


DOW, 


EK. 


BPC. 




CLB. 




DOW. 





DUP. 

ACG, ACS, DA, DOW, FMB, FRO, PPG, SF. 

HK. 

CCH, DA, DVC, HK, HPC, KPS, KPT, WOI. 

DA, DVC, WOI. 

PUB, UCC. 

ICO, PLC. 

ACG, DUP. 

ACG, DUP, KAI, PAS, UCC. 

AME, DOW, DUP, HPC, TNA, USI. 

DOW, SHC. 

ACS, DA, DOW, DUP, FRO, SF. 

ACS, DA, DOW. 

LIL. 

DCC, DOW, TNA. 

ACS, ANM, DOW, DUP, FRO. 

EK. 

FMP. 

DUP. 



182 



SYNTHETIC ORGANIC CHEMICALS. 1965 

TABLE 21B -Miscellaneous chemicals for which US production or sales were reported, identified by 
1Abbfi ' S1B • manufacturer, 1965— Continued 



Chemical 



MISCELLANEOUS CHIMICALS, ACYCLIC— Continued 



*Halogenated hydrocarbons—Continued 

2-Chloropropane (Isopropyl chloride) ----- 

3-Chloropropene (Allyl chloride) 

Chlorotrifluoroethylene (Trifluorovinyl chloride)-— 

Chlorotrif luoroethylene, polymerized 

Chlorotrifluoromethane "' 

1, 2-Dibromo-l, 1-dichloroethane 

Dibromodifluoromethane 

1, 2-Dibromoethane (Ethylene dibromide) 

Dibromomethane (Methylene bromide) ■- 

1, 2-Dibromo-l, 1, 2, 2-tetrafluoroethane— 

Dichlorobutadiene " 

1,4-Dichlorobutene 

*Dichlorodifluoromethane ■ 

*1, 2-Dichloroethane (Ethylene dichloride) 

*Dichloromethane (Methylene chloride) 

Dichloropentanes, mixed isomers 

*1, 2-Dichloropropane (Propylene dichloride) 

2,3-Dichloropropane 

*Dichlorotetrafluoroethane 

1, 1-Dif luoroethane 

Difluorotetrachloroethane 

Diiodomethane (Methylene iodide) 

Hexachloroethane 

Hexafluoro-2-propane 

Hexafluoropropylene, monomer—'- 

Hexamethylene dibronn.de " 

Iodoethane (Ethyl iodide), tech 

Iodoform (Triiodomethane) 

*Iodomethane (Methyl iodide) 

1-Iodoperfluorohexane 

*Lauryl chlorides ""' 

Octafluorocyclobutane """""" 

1, 1,2,2-Tetrabromoethane (Acetylene tetrabromide) — 

Tetrabromomethane " "" 

1,1,2,2-Tetrachloroethane (Acetylene tetrachloride) - 

*Tetrachloroethylene (Perchloroethylene) 

Tetrafluoroethylene, monomer 

Tetrafluoroethylene, polymer 

Tetrafluoromethane 

X t i, l-Trichloroethane (Methyl chloroform) 

l' 1, 2-Trichloroethane (Vinyl trichloride) 

*Trichloroethylene " ""' 

*Trichlorofluoromethane 

1,2,3-Trichloropropane 

1, 2, 3-Triehloropropene 

Trichlorotrif luoroethane 

*Vinyl chloride, monomer ( Chloroethylene) 



Vinyl fluoride "~ T" 

Vinylidene chloride, monomer ( 1, 1-Dichloroethylene) - 



VInylidene fluoride- 
All other- 

2-Heptanone (Methyl amyl ketone) 

Hexadecane 

n-Hexadecenyl succinic anhydride 

n-Hexadecyl disulfide 

Hexadecyl nitrile 

Hexamethylenediammonium adipate 

1,6-Hexanediol 

Hexanediol bischloroformate 

2, 5-Hexanedione ( Acetonylacetone) 

1, 2, 6-Hexanetriol 

1,2,6-Hexanetriol octoate 

Hexanoic acid (Caproic acid) 

2-[ 2- ( Hexyloxy) ethoxy] ethanol 

Hydracrylonitrile (Ethylene cyanohydrin) - 

Hydrazine and salts 

2-Hydrazinoethanol 

Hydroxyethyl carbamate 

Hydroxyethyl methacrylate 



Manufacturers' identification codes 
(according to list in table 22) 



DOW. 

DOW, SHC. 

ACG, MMM. 

HK, MM. 

ACG, DUP, PAS. 

DOW. 

DOW. 

DOW, ETD, HCH, MCH. 

DOW. 

DUP. 

DUP. 

DUP. 

ACG DUP, KAI, PAS, UCC. 

m^, DA, DOW, DUP, JCC, MON, OMC, PPG, TNA, UCC, WYN. 

ACS, DA, DOW, DUP, FRO, SF. 

PAS. 

DOW, JCC, UCC. 

DOW, UCC, WYN. 

ACG, DUP, PAS, UCC. 

ACG, DUP. 

DUP. 

NTB, SDW. 

NES. 

DUP. 

DUP. 

CLB. 

EK, FMT. 

NTB. 

CLB, EK, FMT, RSA. 

x. 

BC, HK, SDH. 

DUP. 

DOW. 

DOW. 

DUP, PPG. 

DA, DOW, DUP, FRO) HK, PPG, SF, TTX. 

DUP. 

DUP. 

DUP. 

DOW, PPG, TNA. 

DOW, UCC. 

DOW, DUP, HK, PPG, TTX. 

ACG, DUP, KAI, PAS, UCC. 

DOW, SHC. 

DOW. 

ACS^ AME^ BFG' CUCJ DA, DOW, GNT, GYR, MNO, MON, TNA, 

UCC. 
x. 

DOW, TMC, TNA. 
x. 

DUP, EK, KPS, KPT. 
UCC. 
HMY. 
HMY. 
PAS. 
FOR. 

CEL, MON. 
CEL. 
PPG. 

ACI, RBC. 
UCC. 
ARC. 
FB. 
UCC. 
UCC. 

FMT, OMC. 
NOR. 
JCC. 
AAC, JCC. 



MISCELLANEOUS CHEMICALS 



183 



TABLE 21B.— Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer , 1 965- -Continued 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

2-( Hydroxymethyl) -2-methyl-l, 3-propanediol ( Trimethylol 

ethane) . 
2-( Hydroxymethyl) -2-nitro-l, 3-propanediol ( Tris( hydroxy- 
methyl) nitromethane) . 
N-( Hydroxymethyl) octadecanamide ( N-Hydroxyroethylsteara- 
mide) . 

*4-Hydroxy-4-methyl-2-pentanone (Diaoetone alcohol) 

Hydroxyneopentyl hydroxypivalate 

Hydroxypropyl methacrylate 

Iodoaoetio acid, sodium salt 

Iodomethylmercury iodide 

Isethionic acid (2-Hydroxyethanesulfonic acid) 

Isoascorbic acid 

*Isoascorbic acid, sodium salt 

Isobutoxyethanol 

l-Isobutoxy-2-propanol (Propylene glycol isobutyl ether) - 

Isobutyl acrylate 

Isobutyl isobutyrate 

Isobutyraldehyde 

Isobutyric acid and anhydride 

Isobutyronitrile 

Isodecaldehyde, mixed isomers 

Isodecanoic acid, mixed isomers 

Isodecyl acrylate • 

Iso-octanoic acid 

Isopentyl ether (Isoamyl ether) 

Isoprenylaluminum 

Isopropanolamines: 

l-Amino-2-propanol ( Monoisopropanolamine) 

1, l / -Iminodi-2-propanol ( Diisopropanolamine) 

1, 1', 1" -Nitrilotri-2-propanol ( Triisopropanolamine) 

*Isopropyl acetate 

2-Isopropylaminoethanol 

Isopropyl chloroformate 

*Isopropyl ether 

Isovaleric anhydride 

Isovalerone (Diisobutyl ketone) 

Itaconic acid (Methylenesuecinic acid) 

Lactic acid, K)0#: 

Edible 

Technical 

Lactic acid salts: 

Aluminum lactate 

Aluminum sodium chlorohydroxylactate 

Aluminum sodium lactate 

Calcium lactate 

Sodium lactate 

Lactic anhydride 

Lactide (3,6-Dimethyl-2,5-p-dioxanedione) 

Lactonitrile 

Laurie acid salts 

Lauronitrile 

Lauroyl bromide 

*Lauroyl chloride 

*Lauroyl peroxide 

Lauryl lactate 

Levulinic acid 

*Linoleic acid salts: 

*Calcium linoleate 

»Cobalt linoleate 

Copper linoleate 

Iron linoleate 

Lead linoleate- 

Lead manganese linoleate 

Manganese linoleate 



Manufacturers' identification codes 
( according to list in table 22) 



CEL, SHC, UCC. 




EKT. 




JCC. 




BSA. 




NTB. 




G. 




MRK, PFZ. 




BAX, MRK, PFZ. 




UCC. 




DOW. 




DBC. 




EKX. 




EKX, UCC. 




EKT, UCC. 




ESX. 




UCC. 




UCC. 




UCC. 




UCC. 




GIV. 




TSA. 




DOW, UCC. 




DOW, UCC. 




DOW, UCC. 




EKT, ENJ, HPC, UCC. 




PAS. 




CTN, PPG. 




ENJ, SHC, UCC. 




ICO. 




EKT, UCC. 




PFZ. 




CLN, DUP, MON. 




CLN, MON. 




TNC. 




REH. 




REH. 




SHF. 




PFN. 




FB. 




CLN. 




MON. 




BCN, CCW, SYP. 




FOR. 




DOW. 




CAD, G, ONX, TBK, THC, UPR, WTL 


AZT, CAD, UPR, WTL. 




VND. 




CRZ. 




CCA, LEF, SHP, SRR. 




HSH, SHP, SRR. 




WTC. 




HSH. 




SHP, SRR. 




SDH, SRR. 




SHP, SRR. 





184 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 21B-— Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1965 — Continued 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

^Lubricating oil additives: 

Chloronaphtha xanthate 

Chlorosulfurized hydrocarbon 

Chlorosulfurized lard oil-- 

Chlorosulfurized sperm oil 

Oxidized hydrocarbons 

*Phosphorodithioates ( Dithiophosphates) : 

2-Pinene phosphorodithioate 

Zinc di( butylhexyl) phosphorodithioate 

Zinc dihexyl phosphorodithioate 

Zinc diisopropylhexyl phosphorodithioate 

Zinc diisopropyl phosphorodithioate 

All other 

Sulfurized butenes 

*Sulfurized lard oil 

Sulfurized methyl oleate 

*Sulfurized sperm oil 

All other 

Magnesium methylate 

Maleic acid 

Maleic acid, tribasic lead salt 

*Maleic anhydride 

Malic acid 

Malonic acid 

Malonic acid salts 

Malononitrile 

Maltol (Hydroxy methyl pyrone) 

Mannitol 

*Mercaptoacetic acid ( Thioglycolic acid) 

*Mercaptoacetie acid (Thioglycolic acid) derivatives: 
*2-Aminoethyl mercaptoacetate (Monoethanolamine thio- 
glycolate) . 

*.jr-jonium mercaptoacetate (Ammonium thioglycolate) 

Antimony mercaptoacetate 

Calcium mercaptoacetate 

Dibutyltin bis( iso-octylmercaptoacetate) 

Dibutyltin mercaptoacetate 

*Iso-octyl mercaptoacetate 

Potassium mercaptoacetate 

Sodium mercaptoacetate 

3-Mercapto-l, 2-propanediol ( Thioglycerol) 

|3-Mercaptopropionic acid 

Mercaptosuccinic acid (Thiomalic acid) 

Metal soaps of oxidized hydrocarbons 

Methacrylamide 

Methacrylate copolymers 

Methacrylate monomers, above methyl 

Methacrylic acid ; 

Methacrylic acid esters, other 

MethalLylidene diacetate 

Methanesulfanol 

Methanesulfonic acid 

*2-Methoxyethanol ( Ethylene glycol monomethyl ether) 

*2-(2-Methoxyethoxy)ethanol (Diethylene glycol monomethyl 

ether) . 
*2-[2-(2-Methoxyethoxy)ethoxy]ethanol (Triethylene glycol 
monomethyl ether) . 
2-(2-Methoxyethoxy)ethyl 2-methoxyethyl ether (Triethylene 
glycol dimethyl ether) . 

2-Methoxyethyl acetate 

4-Methoxy-4-methyl-2-pentanol 

4-Methoxy-4-methyl-2-pentanone 

Methoxypolyethylene glycol 

l-Methoxy-2-propanol 

3-Methoxypropanol 

3-(3-Methoxypropoxy)propanol (Dipropylene glycol methyl 

ether) . 
3-[3-(3-Methoxypropoxy)propoxy] propanol (Tripropylene 

glycol methyl ether) . 
3-Methoxypropylamine 



Manufacturers' identification codes 
(according to list in table 22) 



MON. 
EN J. 
CCW. 

ccw. 

ALX. 

TX. 

0R0. 

MON. 

TX. 

SIN. 

ENJ, 

LUB. 

CCW, 

SIN. 

CCW, 

CCW, 

MKT, 

NAC, 

NTL. 

HN, 

EX, 

KF. 



LUB, MON, SIN. 

GOC, NLC, SIN. 

LUB, QCP, SIN, SOI, x. 

ENJ, HK, LUB, MON, 0R0, SIN, SOI, x. 

SFA. 

PFN. 

KPS, MON, NAC, PCC, PTT, RCI. 
NAC, PFN. 



EK, GIV. 






KF. 








APD. 








EVN, 


HAB, 


RET. 




EVN, 


HAB, 


RET. 




EVN, 


HAB, 


RET, 


TNI. 


CCA. 








EVN. 








X. 








CCA. 








CCW, 


EVN, 


HAB. 




EVN. 








EVN. 








EVN. 








EVN. 








EVN. 








ALX. 








RH, 


X. 






X. 








DUP. 








DUP, 


RH. 






SAR. 








UCC. 








PAS. 








PAS. 








DOW, 


JCC, 


OMC, 


UCC. 


DOW, 


JCC, 


OMC, 


UCC. 


DOW, 


CMC, 


UCC. 




ASL. 








UCC. 








SHC. 








SHC. 








UCC. 








DOW, 


SHC. 






UCC. 








DOW, 


UCC. 







EXT, JCC. 



MISCELLANEOUS CHEMICALS 



185 



TABLE 21B.- -Miscellaneous chemicals for which U.S. production or sales were reported identified by 

manufacturer, 1 965- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

Methoxytriethyleneglycol acetate 

*Methyl acetate 

Methyl acetoacetate 

Methyl acrylate, monomer 

Methylal ( Dimethoxymethane) 

Methylaluminum sesquichloride 

2-Methylaminoethanol ( N-Methylethanolamine) 

Methyl borate 

3-Methyl-2-butenoic acid 

2-Methyl-l-buten-3-yne ( Isopropenylacetylene) 

Methyl butynoxyethanol 

Methyl carbamate 

Methyl chloroformate 

Methyl cyanoacetate 

Methyl 2-cyanoacrylate 

Methyl dichloroacetate 

Methyl disulfide (Dimethyl disulfide) 

N, N'-Methylenebisacrylamide 

N,N '-Methylenebisoctadecanand.de ■ 

*Metnyl ether (Dimethyl ether) 

Methyl formate 

N-Methylglucamine 

Methylglycerol 

5-Methyl-2-hexanone (Methyl isoamyl ketone) 

2,2'-(Methylimino)diethanol (Methyl diethanolamine) - 

Methyl isocyanate 

2-Methyllactie acid (a-Hydroxyisobutyric acid) 

2-Methyllactonitrile (Acetone cyanohydrin) 

Methylmagnesium bromide 

Methylmagnesium chloride 

Methyl methacrylate, monomer 

2-Methyl-2-nitro-l,3-propanediol 

2-Methyl-2-nitro-l-propanol 

2-Methyl-2,4-pentanediol (Hexylene glycol) 

*4-Methyl-2-pentanone (Methyl isobutyl ketone) 

4-Methyl-2-pentanone oxime ( Methylisobutyl ketoxime) 

4-Methyl-3-penten-2-one (Mesityl oxide) 

4-Methyl-2-pentyl acetate 

Methylpolyethanolamine 

2-Methyl-2-propyl- 1, 3-propanediol 

Methylpseudoionone 

Methyl sulfate (Dimethyl sulfate) 

Methyl sulfide (Dimethyl sulfide) 

Methyl sulfone 

Methyl sulfoxide (Dimethyl sulfoxide) 

N-Methyltaurine 

N-Methyltaurine, sodium salt 

N-Methylurea 

2-Methylvaleraldehyde ( 2-Methylpentaldehyde) 

2-Methylvaleric acid 

Methyl vinyl acetate 

Methyl vinyl ether 

Mucochloric acid (2,3-Diehloro-3-formylacrylie acid) 

Myrcene (7-Methyl-3-methylene-l, 6-octadiene) 

Myristoyl chloride 

Myristyl lactate 

2-Nitro-l-butanol 

Nitroethane 

Nitromethane 

1-Nitropropane 

2-Nitropropane 

1, 9-Nonanediol 

Nonanoic acid (Pelargonic acid) 

Nonanoic acids, cobalt salts 

Nonenylsuceinic anhydride 

Nylon, heteropolyamide polymer 

*Nylon, 6 and 6/6 polymer for fiber 

Nylon, sebacamide polymer 

1-Octadecene 



RBC. 

BOH, EK, MON, UCC. 

EKT, UCC. 

CEL, DBC, RH. 

CEL. 

TNA. 

UCC. 

MHI, SFA. 

UCC. 

CUC. 

cue. 

BKL, MP. 

CTN. 

KF. 

EKT. 

KF, PD. 

CRZ. 

ACY. 

ARC. 

COM, DUP, UCC. 

DUP. 

DUP. 

APD. 

EKT, UCC. 

UCC. 

CTN, OTC. 

EK. 

ACY, x, x. 

ARA. 

ARA, x. 

ACY, DUP, RH. 

COM. 

COM. 

CEL, EKT, SHC, UCC. 

EKT, ENJ, SHC, UCC. 

ALB. 

SHC. 

PUB, SHC, UCC. 

G. 

ABB, DUP, ICO. 

GIV. 

DUP. 

CRZ, PAS. 

CRZ. 

CRZ. 

G. 

TNA. 

LIL. 

UCC. 

UCC. 

UCC. 

G, UCC. 

EKT. 

IFF. 

BC. 

VND. 

COM. 

COM. 

COM. 

COM. 

COM. 

ADM. 

EMR. 

MID. 

HMY. 

DUP. 

DUP, MON, NAC. 

DUP. 

HMY. 



186 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1 965- -Continued 



Manufacturers' identification code 
( according to list in table 22) 



MISCELLANEOUS CHEMICALS, AC YCLIC-- Continued 

Octadecyl isocyanate 

n-Octadecyl mereaptan 

Octadecyl mercaptopropionate 

1-Octanethiol (n-Octyl mereaptan) 

Octanoic acid (Caprylic acid) salts: 

Aluminum octanoate 

Barium octanoate 

Cadmium octanoate 

Stannous octanoate 

Zinc octanoate 

2-0etanone (Hexyl methyl ketone) 

3-0ctanone (Amyl ethyl ketone) 

Octanoyl chloride 

l-Octene 

l(and 2)-0ctene 

2-0ctene 

Octenylsuccinic anhydride 

Octyltins 

Oleamide (Oetadecene amide) 

Oleamides, mixed 

*01eie acid salts: 

Aluminum oleate 

Ammonium oleate - 

Barium zinc oleate 

*Copper oleate 

Lead oleate 

Stannous oleate 

Oleonitrile 

Oleoyl chloride 

Oleoylhydroxamic acid 

Oleylpalmitamide 

*0xalic acid 

*Oxalic acid salts: 

Ammonium oxalate 

Calcium oxalate 

Ferric ammonium oxalate 

Ferric oxalate 

Ferric sodium oxalate 

Ferrous oxalate 

Potassium binoxalate 

Potassium oxalate 

Sodium binoxalate 

Sodium oxalate 

Oxidized hydrocarbon mixtures, other than lubricating oil 
additives. 
*Palmitic acid salts: 

Aluminum palmitate 

Zinc palmitate 

*Pa1nritoyl chloride 

Paraformaldehyde 

Paraldehyde (Paracetaldehyde) 

*Pentaerythritol 

Pentaerythritol caprylate 

Pentaerythritol pelargonate 

*Pentaerythritol tetranitrate 

2, 4-Pentanedione ( Acetylacetone) 

2,4-Pentanedione, metallic complexes: 

Ferric 

Other 

2-Pentanone (Methyl propyl ketone) 

3-Pentanone (Diethyl ketone) 

Pentyl nitrate (Amyl nitrate) 

Peroxyacetic acid 

^Phosgene (Carbonyl chloride) 

•^Phosphorus acid esters, not elsewhere specified (See also 
Plasticizers, Surface-active agents, Pesticides, Flo- 
tation reagents, and Lubricating oil additives) : 

Bis(2-ethylhexyl) hydrogen phosphate- 

Bis(2-ethylhexyl) hydrogen phosphite 



CWN, 


ICO 


MOB. 




HMY. 








EVN. 








PAS. 








NOP. 








CCW. 








CCW. 








CCW. 








BKC. 








EKT, 


TBK, 


WTH. 




AHA. 








HK, 


UPR. 






ADM. 








WTH. 








mix. 








HMY. 








x. 








ADM, 


ARC, 


FIN, HUM. 




FIN. 








WTC. 








BCN, 


MCI. 






WTC. 








MLD, 


SHP, 


WTC. 




SHP. 








CCW, 


X. 






ARC, 


FOR. 






DEP, 


G, TBK. 




WAY. 








FIN. 








ACG, 


MAL, 


PFZ, SF. 




ACG, 


BKC, 


PFZ. 




SF. 








PFZ. 








PFZ. 








PFZ. 








BKL. 








BKC. 








ACG, 


BKC, 


PFZ. 




SF. 








ACG, 


BKC, 


MAL, SF. 




ALX. 








ACY, 


NOP, 


WTC. 




ACY, 


NOP, 


WTC. 




G, HAL, OPC, THK. 




CEL, 


HN, 


3PC. 




UCC. 








CEL, 


COM, 


DCI, HN, HPC, RCI, TRJ. 




DEW. 








DRW. 








DUP, 


HPC, 


TRJ. 




UCC. 








MAK. 








MAK. 








UCC. 








DUP, 


HEX. 






TNA. 








FMB. 








CTN, 


DUP, 


MOB, NAC, CMC, OTC, PPG, UCC, 


UPJ, VDM. 



MISCELLANEOUS CHEMICALS 



187 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1 965- -Continued 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

^Phosphorus acid esters, not elsewhere specified (See also 
Plastieizers, Surface-active agents, Pesticides, Flo- 
tation reagents, and Lubricating oil additives) — 
Continued 

Butyl phosphates (mono- and di-) 

Chloropropyl phosphorothioate 

Dibutyl butylphosphonate 

Dibutyl hydrogen phosphite 

Didodecyl hydrogen phosphate 

Diethyl ethylphosphonate 

Diethyl hydrogen phosphite 

Diisopropyl hydrogen phosphite 

Dimethyl hydrogen phosphite 

Dimethyl methylphosphonate 

Dioctyl hydrogen phosphate 

Dioctyl hydrogen phosphite 

Dipentaerythritol phosphite 

. 2-Ethylhexyl phosphates (mono- and di-) 

Ethyl phosphates (mono- and di-) 

Iso-octyl hydrogen phosphate 

Isopentyl octyl hydrogen phosphate 

Methyl dihydrogen phosphate 

Methyl phosphates (mono- and di-) 

Pentyl phosphates (Mono- and diamyl phosphates) 

*Tributyl phosphate 

Tributyl phosphite 

Tridecyl phosphite 

Triethyl phosphite 

Triiso-octyl phosphite 

Triisopropyl phosphite 

Trimethyl phosphate 

Trimethyl phosphite 

Tris(2-chloroethyl) phosphite 

Tris(2,3-dibromopropyl) phosphate 

Tris(2-ethylhexyl) phosphite 

Tris( octadecyl) phosphite 

All other 

Pine oil, synthetic 

Polyaerylamide 

Polyacrylic acid 

*Polyacrylic acid salts: 

Ammonium polyacrylate 

Sodium polyacrylate 

All other 

Polyacrylonitrile 

Polybutylene glycol 

Polychlorinated propyl ether 

Polyethoxyethylglycerol 

Polyethoxyethylsorbitol 

■^Polyethylene glycol 

Polyethylene glycol dimethacrylate 

Polyethylene imine 

Polyethylene polysulfide 

Polyglycerol " " _ 

Polyglycols, ethylene glycol and glycol ethers, mixtures- 

Polymethacrylic acid esters 

*Polypropoxy ethers: 

*Glycerol tri( polyoxypropylene) ether 

Polypropoxysorbitol 

Other 

^Polypropylene glycol 

Polytetramethylene glycol ether 

Propanone peroxide (Acetone peroxide) 

|3-Propiolactone 

Propionaldehyde 

^Propionic acid 

Propionic acid salts: 

*Calcium propionate 

*Sodium propionate 

Zinc propionate 



Manufacturers' identification codes 
(according to list in table 22) 



SF, SM. 

TNA. 

SM. 

SM. 

DUP. 

SM. 

SM. 

SM. 

SM. 

SM. 

DUP, SF. 

HK. 

HK. 

SF. 

SF, SM. 

SM. 

SM. 

HK. 

SF, SM. 

SF. 

COM, FMP, SF, TXT. 

SM. 

HK. 

SM. 

SM. 

SM. 

TNA. 

SM. 

SM. 

MCH. 

HK. 

SM. 

DUP, MON, SF, SM, x. 

CBY. 

ACY. 

BFG, NOP, RH. 

BFG. 

ALC, BFG, JOR, RH. 

BFG. 

DUP. 

NIC. 

JCC. 

GLY. 

APD, GLY, TCH. 

ACN, DOW, DUP, G, JCC, CMC, UCC, WYN. 

SAR. 

cm. 

BFG. 
DRW. 
DOW. 
DUP. 

JCC, OMC, UCC, WYN. 

APD. 

ACS, APD, WYN. 

DOW, JCC, NLC, OMC, UCC, WYN. 

x. 

SDH. 

CEL. 

EKX, UCC. 

CEL, COM, EKT, UCC. 

CEL, HFT, PFZ, UCC, WSN. 
CEL, PFZ, UCC, WSN. 
BKC. 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 21B.— Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer , 1 965— Continued 



MISCELLANEOUS CHMICALS, ACYCLIC— Continued 



Propionic anhydride 

Propionyl chloride 

Propionyl peroxide 

Propyl acetate 

Propylene carbonate 

^Propylene glycol ( 1,2-Propanediol) 

Propylene glycol, mixed ethers 

^Propylene oxide 

n-Propyl isocyanate 

Propyl nitrate 

Propyne (Methylacetylene) 

Pseudoionone 

Pyruvaldehyde 

Quaternary ammonium compounds (butyl and lower) 

Rare sugars 

Ricinolamide 

Ricinoleic acid salts: 

Calcium ricinoleate 

Lithium ricinoleate 

*Sarcosine ( N-Methylaminoacetic acid) 

*Sarcosine, sodium salt 

Sebacic acid 

Semicarbazide base and hydrochloride 

^Sequestering agents: 

(Diethylenetrinitrilo)pentaacetic acid 

(Diethylenetrinitrilo)pentaacetic acid, monosodium 
hydrogen ferric salt. 

*(Diethylenetrinitrilo)pentaaeetie acid, sodium salt 

N, N-Dihydroxyethylglycine, sodium salt 

*( Ethylenedinitrilo) tetraacetic acid ( Ethylenediamine- 
tetraacetic acid) . 

( Ethylenedinitrilo) tetraacetic acid, diammonium salt 

( Ethylenedinitrilo) tetraacetic acid, dipotassium salt 

( Ethylenedinitrilo) tetraacetic acid, disodium salt 

( Ethylenedinitrilo) tetraacetic acid, disodium calcium 

salt. 
( Ethylenedinitrilo) tetraacetic acid, disodium copper 

salt. 
( Ethylenedinitrilo) tetraacetic acid, disodium zinc salt, 
diiydrate. 

( Ethylenedinitrilo) tetraacetic acid, manganese salt 

*( Ethylenedinitrilo) tetraacetic acid, monohydrogen tri- 
sodium salt. 
( Ethylenedinitrilo) tetraacetic acid, monosodium iron 

salt. 
( Ethylenedinitrilo) tetraacetic acid, tetrapotassium salt 

*( Ethylenedinitrilo) tetraacetic acid, tetrasodium salt 

Hexahydroxyheptanoic acid, s6dium salt 

(N-Hydroxyethylethylenedinitrilo)triacetic acid 

(N-Hydroxyethylethylenedinitrilo) triacetic acid, iron 
sodium salt. 
*(N-Hydroxyethylethylenedinitrilo) triacetic acid, tri- 
sodium salt. 
( N-Hydroxyethylethylenedinitrilo) triacetic acid, other 
salts. 

Nitrilotriacetic acid, trisodium salt 

Sodium salt of sugar acids 

Silicones 

Sodium ethoxide 

Sodium ethyl oxalacetate * 

Sodium formaldehydebisulfite 

*Sodium formaldehydesulfoxylate 

*Sodium methoxide (Sodium methylate) 

Sodium polypectate 

Sodium sorbitol borate 

Sorbic acid (2,4-Hexadienoic acid), and potassium and 
sodium salts. 

^Sorbitol 

Soya nitrile 

*Stearamide ( Octadecanamide) 



Manufacturers' identification codes 
(according to list in table 22) 



CEL, 
ABB, 
WTL. 
CEL, 
DOW, 
APD, 
DOW. 
CEL, 
CWN, 
TNA. 

cue. 

GIV. 
UCC. 
EDC, 
PFN. 
TKL. 

BAC. 
BAC. 
ATL, 
GGY. 

WTH, 
FMT. 

HMP. 
GGY. 

CWL, 
CWL, 

DOW, 

DOW. 
EK. 
DOW, 
DOW, 

GGY. 



GGY. 
GGY, 

GGY, 

GGY. 
CRT, 
PCW. 
GGY. 
DOW. 



EKT, UCC. 
EK, TBK. 

EKT, PUB, UCC. 

JCC. 

CEL, DOW, DUP, JCC, OMC, UCC, WYN. 

DOW, JCC, OMC, UCC, WYN. 
OTC. 



EK, PAS, RSA. 



G, HMP, VPC. 



DOW, GGY, HMP, RPC, TCC. 
DOW, HMP, MOA. 
GGY, HMP, MOA. 



EK, GGY, HMP, RPC. 
GGY. 



HMP, NOP. 
HMP, RPC. 

CWL, DOW, GGY, HMP, HRT, IBI, RPC, TCC. 



CRT, CWL, DOW, HMP, IBI, MOA, RPC, TCC. 



HMP. 



GGY, HMP. 






PFN. 






DCC, ORO, UCS. 






FMP. 






FMP. 






EK, IDC. 






HSH, NOP, RH, ROY. 






BFR, DA, DUP, HSH, KF, OMC, 


RBC, 


SFA. 


SKG. 






APD. 






UCC. 






APD, BRD, MRK, PFZ. 






CGI. 






ADM, ARC, DUP, FIN, HUM. 







MISCELLANEOUS CHEMICALS 



189 



TABLE 21B. —Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1 965- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

♦Stearic acid salts: 
♦Aluminum stearates: 

♦Aluminum distearate 

♦Aluminum monostearate 

♦Aluminum tristearate 

Ammonium stearate 

Barium stearate 

Cadmium stearate 

♦Calcium stearate 

Cobalt stearate 

Copper stearate 

Ferric and ferrous stearates 

♦Lead stearate 

Lead stearate, dibasic 

♦Lithium stearate 

♦Magnesium stearate 

Ma nganese stearate 

Nickel stearate 

♦Zinc stearate 

All other 

Stearonitrile (Octadecanenitrile) 

Stearoyl chloride 

Stearyl-2- lactic acid 

Succinic acid 

Succinic anhydride 

Succinimide 

Succinonitrile 

Succinyl peroxide 

Sucrose octaacetate 

♦Tallow umide, hydrogenated 

Tallow fatty acyl chloride 

Tallow litrile 

Tallow nitrile, hydrogenated 

Tartaric acid salts: 

Antimony potassium tartrate 

Potassium bitartrate 

Potassium sodium tartrate 

Sodium bitartrate 

All other 

Tetrabutyltin 

Tetrabutyl titanate 

n-Tetradecane 

1, 1,3,3-Tetraethoxypropane 

Tetraethylene glycol 

Tetraethylene glycol dimethacrylate 

♦Tetraethyllead 

Tetrahydropseudoionone 

Tetrahydroxysuccinic acid ( Dioxytartaric acid) 

Tetrakis( hydroxymethyl) phosphonium chloride 

N, N, N', N'-Tetrakis( 2-hydroxypropyl) ethylenediamine- 

1, 1,3,3-Tetramethoxypropane- 

♦Tetramethyl( and ethyl) lead 

Tetramethylguanidine 

♦Tetramethyllead 

Tetramethylurea 

Tetraoctyl orthosilicate 

Tetrapropenylsuccinic acid 

Thioacetamide 

Thioacetic acid 

2,2'-Thiodiethanol ( Thiodiethylene glycol) 

3,3'-Thiodipropionates, other 

3,3'-Thiodipropionic acid 

Thiodipropionic acid, cobalt salt 

3,3'-Thiodipropionitrile 

Thiolactic acid 

Thiosemicarbazide 

Titanic acid esters 

Tributylphosphine 



ACY, JTC, LEF, MAL, NOC, NOP, PHP, SYP, WTC. 

LEF, MAL, NOC, NOP, SYP, WTC. 

ACY, LEF, MAL, NOC, NOP, PBP, SYP. 

LEF, NOP, WTC. 

LEF, NOC, NOP, PHP, SYP, WTC. 

NOP, PHP, SYP, WTC. 

ACY, HNX, JTC, LEF, MAL, NOC, NOP, PHP, SYP, WTC. 

WTC. 

NOC. 

MCI, WTC. 

HSH, LEF, NOP, NTL, PRP, WTC. 

NOC, NOP, NTL. 

FTE, LEF, NOP, PRP, SYP, WTC. 

ACY, JTC, LEF, MAL, NOC, NOP, PRP, SYP, WTC. 

NOC. 

WTC. 

ACY, BCN, CCA, HNX, JTC, LEF, MAL, NOC, NOP, PRP, SYP, 

TNC, WTC. 
APD. 
FOR. 
G, TBK. 



RKC, NAC. 




NAC. 




NAC. 




NAC, RSA. 




WTL. 




PD, UCC. 




ADM, ARC, 


CGL, CRT, HUM. 


G. 




FOR. 




FOR. 




PF2. 




ATC. 




PFZ. 




PFZ. 




BKC. 




X. 




DUP. 




HMY. 




KF. 




DOW, UCC. 




SAR. 




DUP, HCH, 


TNA. 


GIV. 




ACY. 




HK. 




WYN. 




KF. 




DUP, TNA. 




ACY. 




DUP, HCH, 


NLC, TNA. 


OTC. 




MON. 




X. 




BKC, EK. 




EVN. 




UCC. 




ttAB. 




CCW, EVN. 




CCW. 




ACY, HAB. 




EVN. 




ACY, FMT. 




DUP. 




CCW. 





190 



SYNTHETIC ORGANIC CHEMICALS, 1965 



TABLE 21B.- 



- Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer , 1965 — Continued 



Manufacturers' identification codes 
( according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Tributyltin chloride 

Trichloroacetic acid 

Trichloroacetyl chloride 

(Trichloromethyl)phosphonic acid 

Trichloropropylsilane 

Trichlorovinylsilane 

Tridecyl mercaptan 

Triethylaluminum 

*Triethylene glycol 

Triethylene glycol dimethacrylate 

Triethyl orthoacetate 

Triethyl orthofonnate 

Triethyl orthopropionate 

Trifluoroaeetic anhydride 

Tri(hexylene glycol) biborate 

Triisobutylaluminum 

Triisodecyl orthofonnate » 

Trimethoxyboroxine 

T rime thy laluminum 

2, 6, 8-Trimethyl-4-nonanone 

Trimethyl orthoformate 

2,2,4-Trimethyl-l,3-pentanediol 

2,2,4-Trimethyl-l,3-pentanediol monoisobutyrate 

Tri-n-octyl phosphine oxide 

Tri-n-propy laluminum 

Tripropylene glycol 

*Urea in compounds or mixtures, 100$ basis: 

*In feed compounds 

*In liquid fertilizer 

*In solid fertilizer 

In plastics 

All other 

Urea peroxide 

Urea urethane copolymer 

Valeraldehyde 

Valeric acid 

*Vinyl acetate, monomer 

*Zine formaldenydesulfoxylate 



DOW. 

EK. 

DCC. 

DCC. 

DCC. 

PAS. 

TNA, 

ACN, 

SAH. 

EK, 

KF. 

KF. 

EK. 

USB. 

TNA, 

KF. 

SFA. 

TNA. 

UCC. 

KF. 

EKX. 

EKX. 

EK. 

TNA, 

DOW, 



CAU, DOW, G, HCH, JCC, OMC, UCC. 
KF. 



TSA. 
UCC. 



ACN, DUP, GCC, JDC, MON, MSC, SHC, SOH. 

ACN, CFA, DUP, ESC, FCA, GCC, HKY, HPC, KET, MON, 

NIT, SHC, SNI, SOH, SPN, x. 

ACN, DUP, GCC, HPC, JDC, MON, MSC, SHC, SNO, SOH, 

DUP, MON. 

ACN, DUP, HPC, MON, SNO, SOH. 
FMB. 
DUP. 
UCC. 
UCC. 

BOR, CEL, CUC, DUP, MON, NSC, UCC. 

NOP, RH, ROY. 



MSC, 
SPN. 



DIRECTORY OF MANUFACTURERS 



Directory of Manufacturers 

The Directory of Manufacturers lists the companies that report their production of synthetic 
organic chemicals to the U.S. Tariff Commission. The name of each manufacturer is preceded 
by an alphabetical identification symbol. These identification symbols consist of not more than 
three capital letters, and usually bear a relation to the company name. 

For 1965, the Directory of Manufacturers lists approximately 800 primary manufacturers 
(see table 22). Some of the companies that report production of synthetic organic chemicals do 
not sell the materials, but consume their entire output in further manufacturing. 

The Directory of Manufacturers lists the reporting companies in two ways: Section 1 lists 
them in alphabetical order by identification symbols; section 2 lists the reporting companies in 
alphabetical order by company name, and gives the corresponding identification symbol and the 
company address. Company divisions are usually listed under the parent company's name. 

TABLE 22.-- Synthetic organic chemicals; Directory of manufacturers , 1965 

SECTION 1. ALPHABETICAL DIRECTORY BY CODE 
[Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. Tariff Commission 
for 1965 are listed below in the order of their identification codes as used in tables m pt. III. Sec. 2 of this 
table lists these manufacturers alphabetically and gives their office addresses J 



Name of company 



AAC 
AAE 
AAI 
AAP 
ABB 
ABS 

ACB 
ACC 
ACG 
ACI 
ACN 
ACO 
ACP 
ACR 
ACS 
ACT 
ACU 

ACY 
ADM 
AKS 
ALB 
ALC 
ALD 
ALF 
ALL 
ALO 
ALT 

ALX 
AMB 
AMC 
AME 
AML 
AMD 
AMP 
AMR 
AMS 

ANM 
APC 
APD 
APR 
APT 
APV 
APX 
ARA 
ARC 



Alcolac Chemical Corp. 

American Aniline & Extract Co., Inc. 

American Alkyd Industries 

American Aniline Products, Inc. 

Abbott Laboratories 

American Brake Shoe Co., American Brakeblok 

Div. 
Allied Chemical Corp., Barrett Div. 
Amoco Chemicals Corp. 

Allied Chemical Corp., General Chemical Div. 
Aceto Industrial Chemical Corp. 
Allied Chemical Corp., Nitrogen Div. 
Acralite Co., Inc. 

Allied Chemical Corp., Plastics Div. 
Acme Resin Corp. 

Allied Chemical Corp., Solvay Process Div. 
Arthur C. Trask Co. 
Allied Chemical Corp., Union Texas Petroleum 

Div. 
American Cyanamid Co. 
Archer-Daniels-Midland Co. 
Arkansas Co., Inc. 
Ames Laboratories, Inc. 
Alco Chemical Corp. 
Aldrich Chemical Co., Inc. 

Allied Chemical Corp., Fibers Div. 

Alliance Color & Chemical Co. 

Alamo Industries, Inc. 

Crompton & Knowles Corp., Althouse Chemical Co. 
Div. 

Alox Corp. 

American Bio-Synthetics Corp. 

Amchem Products, Inc. 

American Chemical Corp. 

Amalgamated Chemical Corp. 

American Oil Co. (Texas) 

American Potash Sc Chemical Corp. 

Pacific Resins & Chemical Co. 

Martin-Marietta Corp. , Ridgway Color & 
Chemical Div. 

Ancon Chemical Co. 

Appleton Coated Paper Co. 

Atlas Chemical Industries, Inc., Chemicals Div, 

Atlas Processing Co. 

American Petrochemical Corp. 

Armstrong Paint & Varnish Works, Inc. 

Apex Chemical Co., Inc. 

Syntex Corp., Arapahoe Chemicals Div. 

Armour Industrial Chemical Co. 



Name of company 



ARD 

ARG 

ARK 

ARL 

ARM 

ARN 

ARP 

ARZ 

ASH 

ASL 

AST 

ASY 

ATC 

ATL 

ATP 

ATR 

ATU 

AUG 

AV 

AVS 

AZT 

BAC 

BAL 

BAR 

BAT 

BAX 

BC 

BCM 

BCN 

BDO 

BEN 

BFG 

BFR 

BJL 

BKC 

BKL 

BKM 

BKS 

BKT 

BL 

BLA 

BLN 

BLS 

BME 

BOR 

BOY 

BPC 



Ardmore Chemical Co. 

Argus Chemical Corp. 

Armstrong Cork Co. 

Arol Chemical Products Co. 

Armour Agricultural Chemical Co. 

Arenol Chemical Corp. 

Armour Pharmaceutical Co. 

Arizona Chemical Co. 

Ashland Oil & Refining Co. 

Ansul Chemical Co. 

Astra Pharmaceutical Products, Inc. 

American Synthetic Rubber Corp. 

American Tartars Corp. 

Atlantic Chemical Corp. 

Atco Chemical- Industrial Products, Inc. 

Atlantic Refining Co. 

Atlantic Tubing & Rubber Co. 

Augusta Chemical Co. 

FMC Corp., American Viscose Div. 

Avisun Corp. 

Aztec Chemicals, Inc. 

Baker Castor Oil Co. 

Baltimore Paint & Chemical Corp. 

American Rubber & Chemical Co. 

Crompton & Knowles Corp., Bates Div. 

Baxter Laboratories, Inc. 

Barlow Chemical Corp. 

Belding Chemical Industries 

Lehn & Fink Products Corp., Beacon Div. 

Benzenoid Organics, Inc. 

Bennett ' s 

B. F. Goodrich Co., B. F. Goodrich Chemical Co. Div. 

Branehflower Co. 

Burdick & Jackson Laboratories, Inc. 

J. T. Baker Chemical Co. 

Millmaster Onyx Corp., Millmaster Chemical Div., 

Berkeley Chemical Dept. 
Buckman Laboratories, Inc. 

Tenneco Chemicals, Inc. , Berkshire Color Div. 
J. T. Baker Chemical Co., Taylor Div. 
Belle Chemical Co., Inc. 
Winn-Dixie Stores, Inc. 
Brooklyn Color Works, Inc. 
Beech-Nut Life Savers, Inc. 
Bendix Corp., Marshall- Eclipse Div. 
Borden Co., Borden Chemical Co. Div. 
Walter N. Boysen Co. 
Benzol Products Co. 



192 SYNTHETIC ORGANIC CHEMICALS, 1965 

TABLE 22..-- Synthetic organic chemicals.- Directory of manufacturers , 1965 — Continued 



Code 


Name of company 


Code 


Name of company 


BPL 


Brand Plastics Co. 


COR 


Commonwealth Oil Refining Co., Inc. 




BRD 


Baird Chemical Industries, Inc. 


CP 


Colgate-Palmolive Co. 




BRS 


Bristol-Meyers Co., Bristol Laboratories Div. 


CPC 


Childs Pulp Colors, Inc. 




BRU 


M. A. Bruder & Sons, Inc. 


CPD 


Chemical Products Corp. 




BRY 


Bryant Chemical Corp. 


CPV 


■ Cook Paint & Varnish Co. 




BSC 


Burkart-Schier Chemical Co. 


CPY 


Copolymer Rubber & Chemical Corp. 




BUC 


Blackman-Uhler Chemical Co. 


CRC 


Crown Chemical Corp. 




BUK 


Buckeye Cellulose Corp. 


CRN 


Corn Products Co. 




BUR 


Burroughs- Wellcome & Co. (U.S.A.), Inc. 


CRS 


Carus Chemical Co., Inc. 




BXT 


J. H. Baxter & Co. 


CRT 
CRY 


Crest Chemical Corp. 

Tenneco Manufacturing Co. , Tenneco Plastics Div. 




CAD 


Cadet Chemical Corp. 


CRZ 


Crown Zellerbach Corp., Chemical Products Div. 




CAL 


Callery Chemical Co. 


CSD 


Cosden Oil & Chemical Co. 




CAP 


Cap- Roc, Inc., Capital Plastics Div. 


CSO 


Cities Service Oil Co. 




CAT 


Catalin Corp. of America 


CST 


Charles S. Tanner Co. 




CAU 


Calcasieu Chemical Corp. 


CTA 


Conestoga Chemical Corp. 




CBA 


Ciba Corp., Ciba Products Co. 


CTL 


Continental Chemical Co. 




CBC 


Georgia-Pacific Corp., Coos Bay Div. 


CTN 


Chemetron Corp., Chemetron Chemicals, Organic 




CBD 


Chembond Corp. 




Chemical Dept. 




CBM 


Carborundum Co. , Coated Abrasives Div. 


cue 


Cumberland Chemical Corp., Subsidiary of Air 




CBN 


Columbian Carbon Co. 




Reduction Co., Inc. 




CBP 


Ciba Corp., Ciba Pharmaceutical Co. Div. 


CUL 


Culver Chemical Co. 




CBR 


Colab Resin Corp. 


CUT 


Cutter Laboratories, Inc. 




CBT 


Samuel Cabot, Inc. 


CW 


General Mills, Inc., Chemical Div. 




CBY 


Crosby Chemicals, Inc. 


CWL 


Cowles Chemical Co. 




CCA 


Carlisle Chemical Works, Inc., Advance Div. 


OWN 


Upjohn Co., Carwin Organic Chemicals 




CCC 


Chase Chemical Corp. 


CWP 


Consolidated Papers, Inc. 




CCH 


Pearsall Chemical Co. 


CYC 


Cyclamate Corp. of America 


• 


CCI 


Checkmate Chemicals, Inc. 








CCL 


Charlotte Chemical Laboratories 


DA 


Diamond Alkali Co., and Western Div. 




CCO 


Chemico, Inc. 


DAN 


Dan River Mills, Inc. 




CCP 


Crown Central Petroleum Corp. 


DAV 


Conchemco, Inc., H. B. Davis Co. Div. 




CCW 


Carlisle Chemical Works, Inc. 


DBC 


Dow Badische Chemical Co. 




CD 


Budd Co., Polychem Div. 


DCC 


Dow Corning Corp. 




CEL 


Celanese Corp. of America: 


DCI 


Delaware Chemicals, Inc. 






Celanese Chemical Co. Div. 


DEG 


Degen Oil & Chemical Co. 






Celanese Coatings Co. 


DEP 


DePaul Chemical Co., Inc. 






Celanese Plastics Co. 
Fibers Co. Div. 


DEX 
DIX 


Dexter Chemical Corp. 
Dixie Chemical Co. 




CEM 


Chemirad Corp. 


DLH 


Hess Oil & Chemical Corp. 




CFA 


Cooperative Farm Chemicals Association 


DLI 


Dawe's Laboratories, Inc. 




CFC 


Rexall Chemical Co. - Kearny 


DOD 


Donald A. Dodd 




CGL 


Cargill, Inc. 


DOM 


Dominion Products, Inc. 




CHC 


Chipman Chemical Co. , Inc. 


DOW 


Dow Chemical Co. 




CHF 


Chemical Formulators, Inc. 


DPP 


Dixie Pine Products Co., Inc. 




CHG 


Chemagro Corp. 


DRL 


Caradco, Inc., Durel Div. 




CHL 


Chemol, Inc. 


DRW 


Drew Chemical Corp. 

Dye Specialties, Inc. 

DeSoto Chemical Coatings, Inc. 




CHO 
CHT 


Stauf fer Chemical Co. , Calhio Chemicals Div. 
Chattanooga Medicine Co. , Chattem Chemicals 
Div. 


DSC 
DSO 






DUN 


Frank W. Dunne Co. 




CIB 


Ciba Chemical & Dye Co. 


DUP 


E. I. duPont de Nemours & Co., Inc. 




CIK 


Tenneco Chemicals, Inc., Ca]/lnk Div. 


DVC 


Dover Chemical Co. 




CIS 
CKL 


Chemical Insecticide Corp. 
Chemlek Laboratories, Inc. 


DXS 


Sunray DX Oil Co. 




CLB 


Columbia Organic Chemicals Co., Inc. 








CLC 


Charles L. Huisking & Co., Inc., Clintbrook 


EAK 


J. S. & W. R. EaMns, Inc. 






Chemical Co. Div. 


ECC 


Eastern Color & Chemical Co. 




CLD 


Colloids, Inc. 


EDO 


Edcan Laboratories 




CLI 


Clintwood Chemical Co. 


EFH 


E. F. Houghton & Co. 




CLK 


Clark Oil & Refining Corp. 


EK 


Eastman Kodak Co. 




CLN 


Standard Brands, Inc., Clinton Corn Processing 


EKT 


Eastman Kodak Co., Tennessee Eastman Co. Div. 






Co. Div. 


EKX 


Eastman Kodak Co., Texas Eastman Co. Div. 




CLV 


Clover Chemical Co. 


ELP 


El Paso Natural Gas Products Co. 




CLY 


W. A. Cleary Corp. 


EMK 


Emkay Chemical Co. 




CM 


Carpenter-Morton Co. 


EMR 


Emery Industries, Inc. 




CMG 


Nyanza, Inc. 


EN 


Endo Laboratories, Inc. 




CMP 


Commercial Products Co., Inc. 


ENJ 


Enjay Chemical Co. 




CO 


Continental Oil Co. 


EPC 


Epoxylite Corp. 




COK 


Cockerille Chemicals, Inc. 


ESC 


Escambia Chemical Corp. 




COL 


Collier Carbon & Chemical Corp. 


ETD 


Ethyl-Dow Chemical Co. 




COM 


Commercial Solvents Corp. 


EVN 


Evans Chemetics, Inc. 




CON 


Concord Chemical Co., Inc. 


EW 


Westinghouse Electric Corp., Insulating Materials 




COP 


Coopers Creek Chemical Corp. 




Div. 





DIRECTORY OF MANUFACTURERS 
TABLE 22, — Synthetic organic chemicals: Directory of manufacturers , 1965 — Continued 



193 



Code 


Name of company 


Code 


Name of company 


FAB 


Fabricolor Manufacturing Corp. 


GRV 


Guardsman Chemical Coatings, Inc. 


FAR 


Fa mow, Inc. 


GRW 


Great Western Sugar Co. 


FB 


Frltzsche Bros., Inc. 


GTH 


Guth Chemical Co. 


FBF 


Fiberfil, Inc. 


GTL 


Great Lakes Chemical Corp. 


FBR 


Fibreboard Paper Products Corp. 


GYR 


Goodyear Tire & Rubber Co. 


FC 


Franklin Chemical Co. 






FCA 


Farmers Chemical Association, Inc. 


HAB 


Halby Products Co., Inc. 


FCD 


France, Campbell & Darling, Inc. 


HAL 


C. P. Hall Co. of Illinois 


FCL 


Federal Color Laboratories, Inc. 


HAM 


Hampden Color & Chemical Co. 


FEL 


Felton Chemical Co., Inc. 


HAN 


Hanna Paint Manufacturing Co., Inc. 


FER 


Ferro Corp., Ferro Chemical Div. 


HAP 


Applied Plastics Co., Inc. 


FG 


Foster Grant Co., Inc. 


HCH 


Houston Chemical Corp. 


FH 


Foster-Heaton Co. 


HCO 


Hamilton Chemical Corp. 


FIN 


Fine Organics, Inc. 


HDG 


Hodag Chemical Corp. 


FIR 


Firestone Tire & Rubber Co., Firestone 


HER 


Heresite & Chemical Corp. 




Plastics Co. Div. 


HET 


Heterochemical Corp. 


FIS 


Fisher Melamine Corp. 


HEX 


Hexagon Laboratories, Inc. 


FLH 


H. B. Fuller Co. 


HFT 


Hoffman-Taff, Inc. 


FLM 


Fleming Laboratories, Inc. 


HK 


Hooker Chemical Corp. 


FLO 


Florasynth Laboratories, Inc. 


HKD 


Hooker Chemical Corp., Durez Plastics Div. 


FLW 


W. P. Fuller Paint Co. 


HKY 


Hawkeye Chemical Co. 


FMB 


FMC Corp., Inorganic Chemicals Div. 


HLC 


Hartman-Leddon Co. 


FMN 


FMC Corp., Niagara Chemical Div. 


HLI 


Haag Laboratories, Inc. 


FMO 


Fermco Laboratories, Inc. 


HMP 


W. R. Grace & Co., Hampshire Chemical Div. 


FMP 


FMC Corp., Organic Chemicals Div. 


HMY 


Humphrey Chemical Corp. 


FMT 


Fairmount Chemical Co., Inc. 


HN 


Tenneco Chemicals, Inc. 


FOC 


Farac Oil & Chemical Co. 


HNC 


H & N Chemical Co. 


POM 


Formica Corp. 


HNW 


Tenneco Chemicals, Inc., Newport Div. 


FOR 


Foremost Chemical Products Co. 


HNX 


Tenneco Chemicals, Inc., Nuodex Div. 


FRE 


Freeman Chemical Corp. 


HOF 


Hoffmann-LaRoche, Inc. 


FRL 


Firestone Tire & Rubber Co., Firestone Rubber 


HOU 


Air Products & Chemicals, Inc., Houdry Process 




& Latex Products Co. Div. 




& Chemical Co. Div. 


FRM 


Farmer's Chemical Co. 


HPC 


Hercules Powder Co . , Inc . 


FRO 


Vulcan Materials Co., Frontier Chemical Co. 


HRS 


Grow Chemical Corp., Harris Paint Co. Div. 




Div. 


HRT 


Hart Products Corp. 


FRP 


Filtered Rosin Products Co. 


HSC 


Holland-Suco Color Co. 


FRS 


Firestone Tire & Rubber Co., Firestone 


HSH 


Harshaw Chemical Co. 




Synthetic Rubber & Latex Co. Div. 


HST 


American Hoechst Corp. 


FSH 


Frisch & Co. , Inc. 


HUM 


National Dairy Products Corp., Humko Products 


FTE 


Foote Mineral Co. 




Chemical Div. 






HUS 


Husky-Dominion Briquets 


G 


General Aniline & Film Corp. , Dyestuff & 


HVG 


Haveg Industries, Inc., Resin & Compound Div. 




Chemical Div. 


HYC 


Hysol Corp. 


GAM 


Gamma Chemical Corp. 


HYN 


Hynson, Westcott & Dunning, Inc. 


GAN 


Gane's Chemical Works, Inc. 






GCC 


W. R. Grace & Co. , Nitrogen Products Div. 


IBI 


Industrial Biochemicals 


GDN 


Lancaster Chemical Corp., Gordon Chemicals 


ICC 


Interchemical Corp., Color & Chemicals Div. 




Co. Div. 


ICF 


Interchemical Corp., Finishes Div. 


GE 


General Electric Co., Chemical Materials Dept. 


ICI 


I.C.I. (Organics), Inc. 


GEI 


General Electric Co., Insulating Materials 


ICO 


Interchemical Corp., Organic Chemicals Dept. 




Dept. 


IDC 


Industrial Dyestuff Co. 


GEO 


Geolina Business, Inc. 


IFF 


International Flavors & Fragrances, Inc. 


GFS 


G. Frederick Smith Chemical Co. 


ILC 


International Latex Corp. 


GGC 


Goodrich-Gulf Chemicals, Inc. 


IMC 


International Minerals & Chemical Corp. 


GGY 


Geigy Chemical Corp. 


IMP 


Hercules Powder Co., Inc., Imperial Color & 


GIL 


Gilman Paint & Varnish Co. 




Chemical Dept. 


GIV 


Givaudan Corp. 


LMR 


Imperial Chemical Co., Inc. 


GLC 


General Latex & Chemical Corp. 


INL 


Inland Steel Container Co. 


GLD 


Glidden Co., Durkee Famous Foods Div. 


IOC 


Ritter-Pfaudler Corp., Ionac Chemical Co. Div. 


GLX 


Glasflex, Inc. 


IPC 


Interplastic Corp., Commercial Resins Div. 


GLY 


Glyco Chemicals, Inc. 


IPI 


Isocyanate Products, Inc. 


GNF 


General Foods Corp., Maxwell House Div. 


IPR 


Inter-Pacific Resins, Inc. 


GNM 


General Mills, Inc. 


IRC 


IRC, Inc. 


GNT 


General Tire & Rubber Co., Chemical Div. 


IRI 


Ironsides Resins, Inc. 


GOC 


Gulf Oil Corp. 






GOR 


Gordon Chemical Co., Inc. 


JCC 


Jefferson Chemical Co., Inc. 


GPM 


General Plastics Manufacturing Co. 


JDC 


Nipak, Inc. 


GPR 


Grain Processing Corp. 


JEN 


Jennison-Wright Corp. 


GRA 


Great American Plastics Co. 


JMS 


J. Meyer & Sons, Inc. 


GRD 


W. R. Grace & Co., Dewey & Almy Chemical Div. 


JNS 


S. C. Johnson & Son, Inc. 


GRG 


P. D. George Co. 


JNT 


Jennat Corp. 


GRH 


W. R. Grace & Co., Hatco Chemical Div. 


JOB 


Jones-Blair Paint Co. 


GRS 


Pontiac Refining Corp. 


JOR 


Jordan Chemical Co. 



194 SYNTHETIC ORGANIC CHEMICALS, 1965 

TABLE 22.- -Synthetic organic chemicals: Directory of manufacturers , i365--Continued 



Code 


Name of company 


Code 


Name of company 


JRG 


Andrew Jergens Co. 


MLS 


Miles Laboratories, Inc., Miles Chemical Co. Div. 


JSC 


Jersey State Chemical Co. 


MMM 


Minnesota Mining & Manufacturing Co. 


JTC 


Joseph Turner & Co. 


MNO 


Monochem, Inc. 


JWL 


Jewel Paint & Varnish Co. 


MNP 


Minnesota Paints, Inc. 






MOA 


Mona Industries, Inc. 


KAI 


Kaiser Aluminum & Chemical Corp. 


MOB 


Mobay Chemical Co. 


KAL 


Kali Manufacturing Co. 


MOC 


Marathon Oil Co., Texas Refining Div. 


KCC 


Kennecott Copper Corp., Chino Mines Div. 


MON 


Monsanto Co. 


KCH 


Keystone Chemurgic Corp. 


MOR 


Mineral Oil Refining Co. 


KCU 


Kennecott Copper Corp., Utah Copper Div. 


MOT 


Motomco, Inc. 


KCW 


Keystone Color Works, Inc. 


MPL 


Massachusetts Plastics, Div. of Rexall Chemical Group 


KEL 


Kelly-Pickering Chemical Corp. 


MPP 


Midwest Plastic Products Co. 


KM 


Kendall Refining Co. 


MR 


Benjamin Moore & Co. 


KET 


Ketona Chemical Corp. 


MRA 


Metro-Atlantic, Inc. 


KF 


Kay- Fries Chemicals, Inc. 


MRB 


Marblette Corp. 


KLS 


Kilsdonk Chemical Corp. 


MRD 


Marden-Wild Corp. 


KMC 


Kohler-McLister Paint Co. 


MRK 


Merck & Co., Inc., and Metalsalts Corp. 


KMP 


Kelly-Moore Paint Co. 


MRN 


International Latex & Chemical Corp, Paisley 


KND 


Knoedler Chemical Co. 




Products Div. 


KNG 


Far- Best Corp., 0. L. King Div. 


MRO 


W. R. Grace & Co., Marco Chemical Div. 


KNP 


Knapp Products, Inc. 


MRT 


Morton Salt Co., Morton Chemical Co. Div. 


KON 


H. Kohnstamm & Co., Inc. 


MRV 


Marlowe-Van Loan Corp. 


KPI 


Kenrich Petrochemicals, Inc. 


MRX 


Max Marx Color & Chemical Co. 


KPP 


Sinclair-Koppers Co. 


MSC 


Mississippi Chemical Corp. 


KPS 


Koppers Pittsburgh Co. 


MTO 


Montrose Chemical Corp. of California 


KPT 


Koppers Co., Inc., Tar & Chemical Div. 


MTR 


Baldwin-Montrose Chemical Co., Inc., Montrose 


KRM 


Lawter Chemicals, Inc., Krumbhaar Resin Div. 




Chemical Div. 


KYN 


Kyanize Paints, Inc. 


MYW 


Stepan Chemical Co., Maywood Div. 


KYS 


Keysor Chemical Co. 










NAC 


Allied Chemical Corp. , National Aniline Div. 


LAK 


Lakeway Chemical Co. 


NCI 


Union Bag-Camp Paper Corp., Nelio Chemical Div. 


LAM 


LaMotte Chemical Products Co. 


NCW 


Nostrip Chemical Works, Inc. 


LAS 


Lasco Industries, Inc. 


NEO 


Norda Essential Oil & Chemical Co., Inc. 


LEA 


Leatex Chemical Co. 


NEP 


Nepera Chemical Co., Inc. 


LEB 


Lebanon Chemical Corp. 


NES 


Nease Chemical Co., Inc. 


LEF 


Leffingwell Chemical Co. 


NEV 


Neville Chemical Co. 


LEH 


Lehigh Chemical Co. 


NIL 


Nilok Chemicals, Inc. 


LEM 


B. L. Lemke & Co., Inc. 


NIT 


Nitrin, Inc. 


LEN 


Leonard Refineries, Inc. 


NIX 


Tenneco Chemicals, Inc., Nixon- Baldwin Div. 


LEV 


Lever Brothers Co. 


NLC 


Nalco Chemical Co. 


LIL 


Eli Lilly & Co. 


NOC 


Norac Co., Inc. 


LKL 


Lakeside Laboratories, Div. of Colgate- 


NON 


A. P. Nonweiler Co. 




Palmolive Co. 


NOP 


Nopco Chemical Co., Inc. 


LKY 


St. Regis Paper Co., Lake States Yeast & 


NOR 


Norwich Pharmacal Co. 




Chemical Div. 


NPC 


Northwest Petrochemical Corp. 


LMI 


North American Chemical Co. 


NPI 


National PoLychemicals, Inc. 


LPC 


Lignin Products Co. 


NPP 


National Plastic Products Co., Inc. 


LUB 


Lubrizol Corp. 


NPV 


Norris Paint & Varnish Co. 


LUE 


George Lueders & Co. 


NRS 


Norse Chemical Corp. 


LUR 


Laurel Soap Manufacturing Co. 


NSC 


National Starch & Chemical Corp. 


LVR 


C. Lever Co., Inc. 


NSP 


Alabama Binder & Chemical Corp. 


LVY 


Fred'k H. Levey Co., Inc. 


NTB 


National Biochemical Co. 






NTC 


National Casein Co. 


MAH 


Maher Color & Chemical Co. 


NTL 


National Lead Co. 


MAK 


MacKenzie Chemical Works, Inc. 


NVF 


N.V.F. Co. 


MAL 


Mallinckrodt Chemical Works 


NVT 


Novamont Corp. 


MAN 


Manganese Chemical Corp. 


NW 


Northwestern Chemical Co. 


MAR 


American Can Co., Marathon Div. 


NYC 


New York Color & Chemical Corp., Subsidiary of 


MAY 


Otto B. May, Inc. 




Tenneco Chemicals, Inc. 


MCA 


Masonite Corp. , Alpine Chemical Div. 






MCB 


Borg- Warner Corp., Maroon Chemical Div. 


OCF 


Owens- Corning Fiberglas Corp. 


MCC 


McCloskey Varnish Co. 


OH 


Air Reduction Co., Inc., Ohio Chemical & Surgical 


MCH 


Michigan Chemical Corp. 




Equipment Co. Div. 


MCI 


Mooney Chemical Corp. 


OMC 


Olin Mathieson Chemical Corp. and Agricultural Div. 


MED 


Medical Chemicals Corp. 


OMS 


E. R. Squibb & Sons Div. of Olin Mathieson Chemical 


MEE 


Maumee Chemical Co. 




Corp. 


MER 


Jefferson Lake Sulphur Co. , Chemical Div. 


ONX 


Millmaster Onyx Corp. , Onyx Chemical Co. Div. 


MET 


M &. T Chemicals, Inc. 


OPC 


Orbis Products Corp. 


MFG 


Molded Fiber Glass Body Co., Resin Div. 


ORG 


Organics, Inc. 


MGR 


Magruder Color Co., Inc. 


0R0 


Chevron Chemical Co., Oronite Div. 


MHI 


Ventron Corp., Metal Hydrides Div. 


ORT 


Roehr Chemicals, Inc. 


MID 


Midland Industrial Finishes Co. 


OSB 


C. J. Osborn Co. 


MIR 


Miranol Chemical Co., Inc. 


OTA 


Ottawa Chemical Co. 


MLD 


Metalead Products Corp. 1 


OTC 


Ott Chemical Co. 



DIRECTORY OF MANUFACTURERS 
TABLE 22, — Synthetic organic chemicals.- Directory of manufacturers , 1965 — Continued 



195 



Code 


Name of company 


Code 


Name of company 


OTH 


Chevron Chemical Co. , Ortho Div. 


RCD 


Richardson Co. 


0X0 


Oxo Chemicals Co. 


RCI 


Reichhold Chemicals, Inc. 


OXR 


Onyx Oils & Resins, Inc. 


RDA 


Rhodia, Inc. 


OXY 


Millmaster Onyx Corp. , Oxy Chemical Div. 


RED 


Red Spot Paint & Varnish Co., Inc. 






REH 


Reheis Chemical Co. , Div. of Armour Pharmaceutical Co. 


PAI 


Pennsylvania Industrial Chemical Corp. 


REL 


Reliance Universal, Inc. 


PAN 


Pan American Petroleum Corp. 


REM 


Remington Arms Co., Inc. 


PAR 


Pennsylvania Refining Co. 


REN 


Renroh Resins 


PAS 


Pennsalt Chemicals Corp. 


RET 


Rayette, Inc. 


PAT 


Patent Chemicals, Inc. 


REZ 


Rezolin, Inc. 


PBY 


Pillsbury Co., Chemical Div. 


RGC 


Rogers Corp. 


PC 


Proctor Chemical Co., Inc. 


RH 


Rohm & Haas Co. 


PCC 


USS Chemicals Div. of U.S. Steel Corp. 


RIC 


Richfield Oil Corp. 


PCH 


Peerless Chemical Co. 


RIK 


Riker Laboratories Div. of Rexall Drug & Chemical Co. 


PCI 


Pioneer Chemical Works, Inc. 


RIL 


Reilly Tar & Chemical Corp. 


PCS 


Emery Industries, Inc., Western Div. 


RIV 


Riverdale Chemical Co. 


PCW 


Pfister Chemical Works 


RLS 


Rachelle Laboratories, Inc. 


PD 


Parke, Davis & Co. 


RMC 


Rinshed-Mason Co. 


PDC 


Berncolors-Poughkeepsie, Inc. 


ROC 


Rock Hill Printing & Finishing Co. 


PDJ 


Joseph Davis Plastics Co. 


ROM 


Roma Chemical Corp. 


PEK 


Peck's Products Co. 


ROY 


Royce Chemical Co. 


PEL 


Pelron Corp. 


RPC 


Refined Products Co. 


PEN 


S. B. Penick & Co. 


RPI 


Rowland Products, Inc. 


PER 


Perry & Derrick Co. 


RSA 


R.S.A. Corp. 


PET 


Petroleum Chemicals, Inc. 


RSB 


Rosenberg Bros. & Co. 


PFN 


Pfanstiehl Laboratories, Inc. 


RT 


F. Ritter & Co. 


PFP 


Phe Ian- Faust Paint Manufacturing Co., 


RTC 


Ritter Chemical Co., Inc. 




Phelan's Resins & Plastics Div. 


RTF 


Retzloff Chemical Co. 


PFW 


Polak's Frutal Works 


RUB 


Hooker Chemical Corp., RC Div. 


PFZ 


Chas. Pfizer & Co., Inc. 


RUR 


Ruberoid Co. 


PG 


Procter & Gamble Co., Procter & Gamble 
Manufacturing Co. Div. 


RZL 


Rozilda Laboratories, Inc. 


PGU 


Gulf Oil Corp., Chemical Div., Perkins Glue 


S 


Sandoz, Inc., Dyestuff Div., Pigments Dept. 




Branch 


SAC 


Southeastern Adhesives Co. 


PHR 


Pharmachem Corp. 


SAL 


Salsbury Laboratories 


PIC 


Pierce Organics, Inc. 


SAR 


Sartomer Resins, Inc. 


PII 


Polymer Industries, Inc. 


SBC 


Scher Bros., Inc. 


PIL 


Pilot Chemical Co. 


sec 


Standard Chlorine Chemical Co., Inc. 


PIT 


Pitt-Consol Chemical Co. 


SCF 


Schaefer Varnish Co., Inc. 


PLA 


Richardson Co., Richardson Polymers Div. 


SCH 


Schering Corp. 


PLB 


P-L Biochemicals, Inc. 


SCN 


Schenectady Chemicals, Inc. 


PLC 


Phillips Petroleum Co. 


SCO 


Scholler Bros., Inc. 


PLS 


Plastics Engineering Co. 


SCP 


Standard Chemical Products, Inc. 


PLU 


Plumb Chemical Corp. 


SCR 


R. P. Scherer Corp. 


PMA 


Plastics Materials, Inc. 


SDC 


Martin-Marietta Corp., Southern Dyestuff Co. Div. 


PMC 


Plastics Manufacturing Co. 


SDG 


Sterling Drug, Inc., Glenbrook Laboratories Div. 


PMP 


Premier Malt Products, Inc. 


SDH 


Sterling Drug, Inc., Hilton-Davis Chemical Co. Div. 


PNT 


Pantasote Co. 


SDW 


Sterling Drug, Inc., Winthrop Laboratories Div. 


PNX 


Phoenix Oil Co. 


SEA 


Seaboard Chemicals, Inc. 


POL 


Polymer Corp. 


SED 


Seidlitz Paint & Varnish Co. 


PPG 


Pittsburgh Plate Glass Co. 


SEK 


Sekisui Plastics Corp. 


PPL 


Pioneer Plastics Corp., Chemical Div. 


SEL 


Selney Co., Inc. 


PRO 


Products Research & Chemical Corp. 


SEP 


Southeast Polymers, Inc. 


PRD 


Productol Chemical Co., Inc. 


SEY 


Seydel-Woolley & Co. , Inc. 


PRO 


Pure Oil Co. 


SF 


Stauffer Chemical Co., Industrial Chemical Div. 


PRP 


S. B. Penick & Co., Parsons-Plymouth Div. 


SFA 


Stauffer Chemical Co., Specialty Chemical Div. 


PRT 


Pratt & Lambert, Inc. 


SFD 


Sonford Chemical Co. 


PRX 


Purex Corp., Ltd. 


SH 


Stein, Hall & Co., Inc. 


PSC 


Passaic Color & Chemical Co. 


SHA 


Shanco Plastics & Chemicals, Inc. 


PSP 


Georgia-Pacific Corp., Puget Sound Div. 


SHC 


Shell Oil Co., Shell Chemical Co. Div. 


PTT 


Petro-Tex Chemical Corp. 


SHF 


National Dairy Products Corp., Sheffield Chemical 


PUB 


Publicker Industries, Inc. 




Co. Div. 


PVI 


Polyvinyl Chemicals, Inc. 


SHL 


Shulton, Inc. 


PYL 


Polychemical Laboratories, Inc. 


SHM 


Shamrock Oil & Gas Corp. 


PYR 


Poly Resins 


SHO 


Shell Oil Co. 


PYZ 


Polyrez Co., Inc. 


SHP 


Shepherd Chemical Co. 






SIC 


Vistron Corp., Silmar Div. 


QCP 


Quaker Chemical Corp. 


SID 


George F. Siddall Co., Inc. 


QKO 


Quaker Oats Co. 


SIM 


Simpson Timber Co. 


QUN 


K. J. Quinn & Co., Inc. 


SIN 


Sinclair Refining Co. 






SIO 


Standard Oil Co. of Ohio 


RAB 


Raybestos-Manhattan, Inc., Raybestos Div. 


SIP 


James P. Sipe & Co. 


RBC 


Roberts Chemicals, Inc. 


SK 


Smith, Kline & French Laboratories 


RCC 


Rexall Chemical Co. 


SKC 


Sinclair Koppers Chemical Co. 



196 SYNTHETIC ORGANIC CHEMICALS, 1965 

TABLE 22. — Synthetic organic chemicals.- Directory of manufacturers, 1965 — Continued 



Code 


Name of company 


Code 


Name of company 


SKG 


Sunkist Growers, Inc. 


TRN 


Trancoa Chemical Corp. 




SKO 


Skelly Oil Co. 


TRO 


Troy Chemical Co. 




SLC 


Soluol Chemical Co., Inc. 


TSA 


Texas ALkyls, Inc. 




SLV 


Sterling Drug, Inc., Salvo Chemical Div. 


TTX 


Detrex Chemical Industries, Inc. 




SM 


Socony Mobil Oil Co., Inc.: 


TUS 


Texas-U.S. Chemical Co. 






Mobil Chemical Co. Div. 


TV 


Tousey Varnish Co. 






Mobil Oil Co. Div. 


TX 


Texaco, Inc. 




SMC 


Stamford Chemical Co. 


TXC 


Tex Chem Co. 




SNA 


Sun Chemical Corp., Pigments Div. 


TXT 


Textilana Corp. 




SNC 


Sonoco Products Co. 








SNI 


Southern Nitrogen Co., Inc. 


UBS 


A. E. Staley Manufacturing Co., UBS Chemical 


SNO 


SunOlin Chemical Co. 




Co. Div. 




SNT 


Suntide Refining Co. 


UCC 


Union Carbide Corp., Chemicals Div. 




SNW 


Sun Chemical Corp., Chemical Products Div. 


UCP 


Union Carbide Corp., Plastics Div. 




SOC 


Standard Oil Co. of California, Chevron 


ucs 


Union Carbide Corp., Silicones Div. 






Chemical Co. 


UDI 


Universal Detergents, Inc. & Petrochemicals 


Co. 


SOG 


Signal Oil & Gas Co. , Houston Div. 


UHL 


Paul Uhlich & Co., Inc. 




SOH 


Sohio Chemical Co. & Solar Nitrogen 


UNC 


United Cork Companies 






Chemicals, Inc. 


UNG 


Ungerer & Co. 




SOI 


American Oil Co. (Maryland) 


UNN 


United Chemical Corp. of Norwood 




SOL 


Solar Chemical Corp. 


UNO 


United Oil Manufacturing Co. 




SON 


Witco Chemical Co., Inc., Sonneborn Div. 


UNP 


United Chemical Products Corp. 




SOR 


Thomason Industries, Inc., Southern Resin Div. 


UNS 


Union Starch & Refining Co., Inc. 




SOS 


Southern Sizing Co. 


UOC 


Union Oil Co. of California 




SPC 


Sinclair Paint Co. 


UPF 


United States Pipe & Foundry Co. 




SPD 


General Electric Co., Silicone Products Dept. 


UPJ 


Upjohn Co. 




SPI 


Sinclair Petrochemicals, Inc. 


UPL 


United States Plywood Corp., California Div 


, 


SPL 


Spaulding Fibre Co., Inc. 




Shasta Operations 




SPN 


Gulf Oil Corp., Chemicals Dept. 


UPM 


Universal Oil Products Co. 




SPY 


Standard Pyroxoloid Corp. 


UPR 


U.S. Peroxygen Corp. 




SRL 


G. D. Searle & Co. 


URC 


United Carbon Co. 




SRR 


Stresen-Reuter, Inc. 


USB 


U.S. Borax Research Corp. 




STA 


A. E. Staley Manufacturing Co. 


USI 


National Distillers & Chemical Corp. : 




STC 


Sou-Tex Chemical Co., Inc. 




A-B Chemical Corp. Div. 




STG 


Stange Co. 




National Petro Chemical Corp. Div. 




STP 


Stepan Chemical Co., Industrial Chemicals 




U.S. Industrial Chemicals Co. Div. 






Div., Millsdale Works 


USO 


U.S. Oil Co. 




SUG 


Sucro-Chemical Div. of Colonial Sugars Co. 


USP 


U.S. Plastic & Chemical Corp. 




SUM 


Summit Chemical Products Corp. 


USR 


United States Rubber Co., Chemical Div. 




SUN 


Sun Oil Co. 


UTR 


Utah Resin Co., Inc. 




SVC 


Sullivan Varnish Co. 


UVC 


Universal Chemicals Corp. 




SVT 


Solvent Chemical Co., Inc. 








SW 


Sherwin-Williams Co. 


VAC 


Varney Chemical Corp. 




SWP 


Souhegan Wood Products, Inc. 


VAL 


Valchem 




swr 


Swift & Co. 


VAR 


Reichhold Chemicals, Inc., Varcum Chemical Div. 


SYC 


Synthetic Chemicals, Inc. 


VB 


Vermi lye- Bell 




SYN 


Synthron, Inc. 


VDM 


Van De Mark Chemical Co. 




SYP 


Synthetic Products Co. 


VEL 


Velsicol Chemical Corp. 




SYR 


Syneo Resins, Inc. 


VGC 


Virginia Chemicals, Inc. 




SYV 


Synvar Corp. 


VIN 
VLY 


Vineland Chemical Co. 
Chem-Fleur, Inc. 




TAE 


Chemtron Corp. , National Cylinder Gas Div. 


VNC 


Vanderbllt Chemical Corp. 




TAY 


Taylor Corp. 


VND 


Van Dyk & Co., Inc. 




TBK 


Universal Oil Products Co., Chemical Div. 


VPC 


Verona-Pharma Chemical Corp. 




TCC 


Tanatex Chemical Corp. 


VPT 


Viekers Refining Co., Inc. 




TCH 


Trylon Chemical Corp. 


VSV 


Valentine Sugars, Inc., Valite Div. 




TCI 


Texize Chemicals, Inc. 


VTM 


Vitamins, Inc. 




TDC 


Diversey Corp. 


VTV 


Vita-Var Corp., Div. of Textron Industries, 


Inc. 


TEN 


Tennessee Copper Co. 








TGL 


Triangle Chemical Co. 


WAS 


Washburn-Purex Co. 




THC 


Thompson Chemical Co. 


WAW 


W. A. Wood Co. 




TIC 


Ticonderoga Chemical Corp. 


WAY 


Philip A. Hunt Chemical Corp., Way land Chemical Div. 


TID 


Tidewater Oil Co. 


WBC 


Worthington Biochemical Corp. 




TKL 


Thiokol Chemical Corp. 


WBG 


White & Bagley Co. 




TMC 


Tenneco Manufacturing Co. 


WCA 


West Coast Adhesives Co. 




TMH 


Thompson- Hayward Chemical Co. 


WCC 


Witfield Chemical Corp. 




TMS 


Sterling Drug, Inc., Thomasset Colors Div. 


WES 


Weston Chemical Corp. 




TNA 


Ethyl Corp. 


WHI 


White 8c Hodges, Inc. 




TNC 


Tennant Development Corp., Chemical Div. 


WHL 


Whitmoyer Laboratories, Inc. 




TNI 


Gillette Chemical Co. 


WHW 


Whittemore- Wright Co., Inc. 




TOC 


Tenneco Oil Co. 


WIC 


Wica Chemicals, Inc. 




TRC 


Toms River Chemical Corp. 


WIL 


Wilson 8c Co., Inc., Wilson Laboratories Div 




TRJ 


Trojan Powder Co. 


WJ 


Warner-Jenkinson Manufacturing Co. 





DIRECTORY OF MANUFACTURERS 
TABLE 11. — Synthetic organic chemicals; Directory of manufacturers, 1965 — Continued 



197 



Code 


Name of company 


Code 


Name of company 


WLI 


White Laboratories, Inc. 


WTC 


Witco Chemical Co. , Inc. 


WLM 


Wilmot 8c Cassidy, Inc. 


WTH 


Wallace & Tiernan, Inc., Harchejn Div. 


WM 


Wilson & Co., Inc., Wilson-Martin Di v. 


WTL 


Wallace 8c Tiernan, Inc., Lucidol Div. 


TOD 


Wood Chemicals, Inc. 


WVA 


West Virginia Pulp 8c Paper Co., 


TOI 


Neville Chemical Co., Chlorinated 




Polychemicals Div. 




Products Div. 


WYN 


Wyandotte Chemicals Corp. 


TON 


Woonsocket Color & Chemical Co. 


WYT 


American Home Products Corp., lyeth Laboratories, 


WRC 


Wood Ridge Chemical Corp. 




Inc. Div. 


WRD 


Weyerhaeuser Co., Wood Products Div. 






WSN 


Washine Chemical Corp. 


YAW 


Young Aniline Works, Inc. 



198 



SYNTHETIC ORGANIC CHEMICALS. 1965 



TABLE 22. — Synthetic organic chemicals.- Directory of manufacturers , 1965 — Continued 

SECTION 2. ALPHABETICAL DIRECTORY BY COMPANY 

[Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. Tariff Commission 
for 1965 are listed below alphabetically, together with their identification codes as used in tables in pt. III. 
Sec. 1 of this table lists these manufacturers in the order of their identification codes] 



Name of company 



Office address 



Abbott Laboratories 

Aceto Industrial Chemical Corp 

Acme Resin Corp 

Acralite. Co. , Inc 

Air Products & Chemicals, Inc., Houdry Process 

& Chemical Co. Div. 
Air Reduction Co., Inc., Ohio Chemical & Surgical 
Equipment Co. Div. 

Alabama Binder & Chemical Corp 

Alamo Industries, Inc 

Alco Chemical Corp 

Alcolac Chemical Corp 

Aldrich Chemical Co., Inc 

Alliance Color & Chemical Co 

Allied Chemical Corp.: 

Barrett Div 

Fibers Div 

General Chemical Div 

National Aniline Div 

Nitrogen Div 



Solvay Process Div 

Union Texas Petroleum Div 

Alox Corp 

Amalgamated Chemical Corp 

Amchem Products, Inc 

American Alkyd Industries 

American Aniline & Extract Co., Inc 

American Aniline Products, Inc 

American Bio-Synthetics Corp 

American Brake Shoe Co., American Brakeblok Div — 

American Can Co., Marathon Div — 

American Chemical Corp 

American Cyanamid Co 

American Hoechst Corp 

American Home Products Corp., Wyeth Laboratories, 
Inc. Div. 

American Oil Co. (Maryland) 

American Oil Co. (Texas) ; 

American Petrochemical Corp 

American Potash & Chemical Corp 

American Synthetic Rubber Corp 

American Rubber & Chemical Co 

American Tartars Corp 

Ames Laboratories, Inc 

Amoco Chemicals Corp 

Ancon Chemical Co 

Ansul Chemical Co 

Apex Chemical Co., Inc 

Appleton Coated Paper Co 

Applied Plastics Co., Inc ■ 

Archer-Daniels-Midland Co 

Ardmore Chemical Co 

Arenol Chemical Corp 

Argus Chemical Corp 

Arizona Chemical Co 

Arkansas Co., Inc 

Armour Agricultural Chemical Co 

Armour Industrial Chemical Co 

Armour Pharmaceutical Co ■ 

Armstrong Cork Co 

Armstrong Paint & Varnish Works, Inc 

Arol Chemical Products Co 

Ashland Oil & Refining Co 

Astra Pharmaceutical Products, Inc 

Atco Chemical- Industrial Products, Inc 



14th St. and Sheridan Rd., N. Chicago, IL 60664. 

126-02 Northern Blvd., Flushing, New York, NY 11363. 

1401 Circle Ave., Forest Park, IL 60130. 

59 Kent St., Brooklyn, NY 11222. 

Widener Bldg., 1339 Chestnut St., Philadelphia, PA 19107. 

1400 E. Washington Ave., Madison, WI 53701. 

P.O. Box 3179, Tuscaloosa, AL 35401. 

Ervin Bldg., 4037 Independence Blvd., Charlotte, NC 28205. 

Trenton Ave. and William St., Philadelphia, PA 19134. 

3440 Fairfield Rd., Baltimore, MD 21226. 

2371 N. 30th St., Milwaukee, WI 53210. 

P.O. Box 326, Ridgefield, NJ 07657. 

40 Rector St., New York, NY 10006. 

1450 Broadway, New York, NY 10018. 

P.0'. Box 70, Morristown, NJ 07960. 

40 Rector St., New York, NY 10006. 

P.O. Drawer 61, Hopewell, VA 23860. 

P.O. Box 365, Morristown, NJ 07960, and 225 Allwood Rd., 

Clifton, NJ 07015. 
P.O. Box 271, Syracuse, NY 13201. 
P.O. Box 2120, Houston, TX 77001. 
3943 Buffalo Ave., Niagara Falls, NY 14302. 
Ontario and Rorer Sts., Philadelphia, PA 19134. 
Brookside Ave., Ambler, PA 19002. 
Broad and 14th Sts., Carlstadt, NJ 07072. 
Venango and F Sts., Philadelphia, PA 19134. 
P.O. Box 2086, Paterson, NJ 07509. 
710 W. National Ave., Milwaukee, WI 53204. 
900 W. Maple Rd., Troy, MI 48012. 
Neenah, WI 54957. 

P.O. Box 9247, Long Beach, CA 90810. 
Berdan Ave., Wayne, NJ 07470. 

129 Quidnick St., W. Warwick, NJ 02893. 
P.O. Box 8299, Philadelphia, PA 19101. 

910 S. Michigan Ave., Chicago, IL 60680. 

910 S. Michigan Ave., Chicago, IL 60680. 

3134 California St., N.E., Minneapolis, MN 55418. 

3000 W. 6th St., Los Angeles, CA 90054. 

P.O. Box 360, Louisville, KY 40201. 

P.O. Box 1034, Louisville, KY 40201. 

420 Lexington Ave . , New York, NY 10017. 

200 Rock Lane, Milford, CT 06460. 

130 E. Randolph Dr., Chicago, IL 60601. 
1 Stanton St., Marinette, WI 54143. 

1 Stanton St., Marinette, WI 54143. 

200 S. 1st St., Elizabethport, NJ 07206. 

825 E. Wisconsin Ave., Appleton, WI 54910. 

130 Perm St., El Segundo, CA 90246. 

500 Investors Bldg., Minneapolis, MN 55440. 

840 Valley Brook Ave., Lyndhurst, NJ 07071. 

40-33 23d St., Long Island City, NY 11101. 

633 Court St., Brooklyn, NY 11231. 

Ill W. 50th St., New York, NY 10020. 

185 Foundry St., P.O. Box 210, Newark, NJ 07101. 

P.O. Box 1685, Atlanta, GA 30301. 

P.O. Box 1805, Chicago, IL 60609. 

P.O. Box 511, Kankakee, IL 60901. 

W. Liberty St., Lancaster, PA 17604. 

1330 S. Kilbourn Ave., Chicago, IL 60623. 

371 Wayne St., Jersey City, NJ 07302. 

1401 Winchester Ave., Ashland, KY 41101. 
7 Neponset St., Worcester, MA 01606. 

93 Main St., Franklin, NJ 07416. 



DIRECTORY OF MANUFACTURERS 
TABLE 22.-- Synthetic organic chemicals : Directory of manufacturers , 1 965— Continued 



199 



ATL 
ATR 
ATU 
APD 
APR 
AUG 
AVS 
AZT 

BRD 
BAC 
BKC 
BKT 
MTR 

BAL 

BC 

BXT 

BAX 

BLS 

BCM 

BL 

BME 

BEN 

BDO 

BPC 

PDC 

BUC 

BOR 

MCB 

BOY 

BFR 

BPL 

BBS 

BLN 

BRU 

BRY 

BUK 

BKM 

CD 

BJL 

BSC 

BUR 

CBT 
CAD 
CAU 
CAL 
CAP 
DRL 
CBM 
CGL 

CCW 

CCA 

CM 

CRS 

CAT 

CEL 



CCL 
CCC 
CHT 
CCI 
CHG 
CBD 

CTN 
TAE 
VLY 



Name of company 



Atlantic Chemical Corp 

Atlantic Refining Co 

Atlantic Tubing & Rubber Co 

Atlas Chemical Industries, Inc. 

Atlas Processing Co 

Augusta Chemical Co 

Avisun Corp 

Aztec Chemicals, Inc 



Chemicals Div — 



Baird Chemical Industries, Inc 

Baker Castor Oil Co 

J. T. Baker Chemical Co 

Taylor Div 

Baldwin-Montrose Chemical Co., Inc., Montros 
Chemical Div. 

Baltimore Paint & Chemical Corp 

Barlow Chemical Corp 

J. H. Baxter & Co 

Baxter Laboratories, Inc 

Beech-Nut Life Savers, Inc 

Belding Chemical Industries 

Belle Chemical Co., Inc 

Bendix Corp., Marshall-Eclipse Div 

Bennett's 

Benzenoid Organics, Inc 

Benzol Products Co 

Berncolors-Poughkeepsie, Inc 

Blackman-Uhler Chemical Co 

Borden Co., Borden Chemical Co. Div 

Borg-Warner Corp., Marbon Chemical Div 

Walter N. Boysen Co 

Branchf lower Co 

Brand Plastics Co 

Bristol-Meyers Co., Bristol Laboratories Div 

Brooklyn Color Works, Inc 

M. A. Bruder & Sons, Inc 

Bryant Chemical Corp 

Buckeye Cellulose Corp 

Buckman Laboratories, Inc 

Budd Co., Polychem Div 

Burdick & Jackson Laboratories, Inc 

Burkart-Schier Chemical Co- 

Burroughs-Wellcome & Co. (U.S.A.), Inc 



Samuel Cabot, Inc 

Cadet Chemical Corp 

Calcasieu Chemical Corp 

Callery Chemical Co 

Cap-Roc, Inc., Capital Plastics Div 

Caradco, Inc., Durel Div 

Carborundum Co., Coated Abrasives Div- 
Cargill, Inc 



Carlisle Chemical Works, Inc 

Advance Div 

Carpenter-Morton Co 

Carus Chemical Co., Inc 

Catalin Corp. of America 

Celanese Corp. of America: 

Celanese Chemical Co. Div 

Celanese Coatings Co 

Celanese Plastics Co 

Fibers Co. Div 

Charlotte Chemical Laboratories 

Chase Chemical Corp 

Chattanooga Medicine Co., Chattem Chemicals Div- 

Checkmate Chemicals, Inc 

Chemagro Corp 

Chembond Corp 

Chemetron Corp.: 

Chemetron Chemicals, Organic Chemical Dept 

National Cylinder Gas Div 

Chem-Fleur, Inc 



Office address 



P.O. Box 216, Nutley, NJ 07110. 

260 S. Broad St., Philadelphia, PA 19101. 

Mill St., Cranston, RI 02905. 

New Murphy Rd. and Concord Pike, Wilmington, DE 19899. 

P.O. Box 1786, 3546 Midway St., Shreveport, LA 71102. 

P.O. Box 660, Augusta, GA 30903. 

P.O. Box 312, New Castle, DE 19720. 

P.O. Box 756, Elyria, OH 44035. 

185 Madison Ave., New York, NY 10016. 
40 Avenue A, Bayonne, NJ 07002. 
600 N. Broad St., Phillipsburg, NJ 08865. 
600 N. Broad St., Phillipsburg, NJ 08865. 
100 Lister Ave., Newark, NJ 07105. 

2325 Hollins Ferry Rd., Baltimore, MD 21230. 

Barlow Lane, Ossining, NY 10562. 

120 Montgomery St., San Francisco, CA 94104. 

6301 N. Lincoln Ave., Morton Grove,- IL 60053. 

Canajoharie, NY 13317. 

1407 Broadway, New York, NY 10018. 

P.O. Box 848, Lowell, NC 28089. 

P.O. Box 238, Troy, NY 12180. 

65 W. 1st S., Salt Lake City, UT 84110. 

P.O. Box 177, Attleboro, MA 02703. 

237 South St., Newark, NJ 07114. 

77 N. Water St., Poughkeepsie, NY 12602. 

P.O. Box 1869, Spartanburg, SC 29301. 

350 Madison Ave., New York, NY 10017. 
P.O. Box 68, Washington, WV 26181. 

1001 42d St., Oakland, CA 94608. 

4501 Shilshole St. NW., Seattle, WA 98103. 

130 E. Randolph Dr., Chicago, IL 60601. 

P.O. Box 657, Syracuse, NY 13201. 

681 Morgan Ave., Brooklyn, NY 11222. 

52d St.. and Grays Ave., Philadelphia, PA 19143. 

6 North St., N. Quincy, MA 02171. 

2899 Jackson Ave., Memphis, TN 38108. 

1256 N. McLean Blvd., Memphis, TN 38108. 

70 S. Chapel St., Newark, DE 19711. 

1953 S. Harvey St., Muskegon, MI 49442. 

1228 Chestnut St., Chattanooga, TN 37402. 

1 Scarsdale Rd., Tuckahoe, NY 10707. 

246 Summer St., Boston, MA 02210. 

2153 Lockport-Olcott Rd., Burt, NY 14028. 

P.O. Box 1522, Lake Charles, LA 70601. 

Callery, PA 16024. 

250 Mill St., Rochester, NY 14614. 

1098 Jackson St., Dubuque, IA 52000. 

P.O. Box 477, Niagara Falls, NY 14302. 

Room 2008, 3 Penn Center Plaza, Philadelphia, PA 19102, 

and Cargill Bldg., Minneapolis, MN 55402. 
West St., Reading, OH 45215. 
500 Jersey Ave., New Brunswick, NJ 08903. 
376 W. 3d St., Everett, MA 02149. 
1375 8th St., LaSalle, IL 61301. 
1 Park Ave., New York, NY 10016. 

522 5th Ave., New York, NY 10036. 

1481 S. 11th St., Louisville, KY 40208. 

744 Broad St., Newark, NJ 07102. 

P.O. Box 1414, Charlotte, NC 28201. 

P.O. Box 948, 5046 Old Pineville Rd., Charlotte, NC 28201. 

3527 Smallman St., Pittsburgh, PA 15201. 

1717 W. 38th St., Chattanooga, TN 37409. 

P.O. Box 2164, Greenville, SC 29602. 

P.O. Box 4913, Station "F", Kansas City, M0 64120. 

P.O. Box 270, Springfield, OR 97477. 

201 E. 42d St., New York, NY 10017. 

840 N. Michigan Ave., Chicago, IL 60611. 

200 Pulaski St., Newark, NJ 07105. 



2 o SYNTHETIC ORGANIC CHEMICALS. 1965 

TABLE 22.— Synthetic organic chemicals.- Directory of manufacturers , 1 965— Continued 



Name of company 



Chemical Formulators, Inc 

Chemical Insecticide Corp 

Chemical Products Corp 

Chemico, Inc 

Chemirad Corp 

Chemlek Laboratories, Inc 

Chemol, Inc 

Chevron Chemical Co.: 

Oronite Div 

Ortho Div 

Childs Pulp Colors, Inc 

Chipman Chemical Co., Inc 

Ciba Chemical & Dye Co 

Ciba Corp.: 

Ciba Pharmaceutical Co. Div 

Ciba Products Co 

Cities Service Oil Co 

Clark Oil & Refining Corp 

W. A. Cleary Corp 

Clintwood Chemical Co 

Clover Chemical Co 

Cockerille Chemicals, Inc 

Colab Resin Corp 

Colgate-Palmolive Co 

Collier Carbon & Chemical Corp 

Colloids, Inc 

Columbian Carbon Co 

Columbia Organic Chemicals Co., Inc 

Commercial Products Co., Inc 

Commercial Solvents Corp 

Commonwealth Oil Refining Co., Inc 

Conchemco, Inc., H. B. Davis Co. Div 

Concord Chemical Co., Inc 

Conestoga Chemical Corp 

Consolidated Papers, Inc 

Continental Chemical Co 

Continental Oil Co 

Cook Paint & Varnish Co 

Cooperative Farm Chemicals Association 

Coopers Creek Chemical Corp 

Copolymer Rubber & Chemical Corp 

Corn Products Co 

Cosden Oil & Chemical Co 

Cowles Chemical Co 

Crest Chemical Corp 

Crompton & Knowles Corp . : 

Althouse Chemical Co. Div 

Bates Div 

Crosby Chemicals, Inc 

Crown Central Petroleum Corp 

Crown Chemical Corp 

Crown Zellerbaeh Corp., Chemical Products Div 

Culver Chemical Co 

Cumberland Chemical Corp., Subsidiary of Air 
Reduction Co., Inc. 

Cutter Laboratories, Inc 

Cyclamate Corp. of America 



Office address 



Dan River Mills, Inc 

Joseph Davis Plastics Co 

Dawe's Laboratories, Inc 

Degen Oil & Chemical Co 

Delaware Chemicals, Inc 

DePaul Chemical Co., Inc 

DeSoto Chemical Coatings, Inc — 
Detrex Chemical Industries, Inc- 

Dexter Chemical Corp 

Diamond Alkali Co 

Western Div 

Diversey Corp 

Dixie Chemical Co- 

Dixie Pine Products Co., Inc 

Donald A. Dodd 



P.O. Box 26, Nitro, WV 25143. 

20 Whitman Ave., Metuchen, NJ 08840. 

P.O. Box 449, Cartersville, GA 30120. 

2508 E. Bailey Rd., Cuyahoga Falls, OH 44221. 

P.O. Box 187 (Ryders Lane), E. Brunswick. NJ 08816. 

4040 W. 123d St., Alsip, IL 60658. 

P.O. Box 3227, Greensboro, NC 27402. 

200 Bush St., San Francisco, CA 94120. 

940 Hensley, Richmond, CA 94800. 

43 Summit St., Brooklyn, NY 11231. 

P.O. Box 2009, 297 Jersey Ave., New Brunswick, NJ 08903. 

Route 208, Fair Lawn, NJ 07410. 

556 Morris Ave., Summit, NJ 07901. 

556 Morris Ave., Summit, NJ 07901. 

P.O. Box 300, Tulsa, OK 74102. 

131st St. and Kedzie Ave., Blue Island, IL 60406. 

P.O. Box 749, New Brunswick, NJ 08903. 

1 N. LaSalle St., Chicago, IL 60602. 

360 Regis Ave., Pittsburgh, PA 15236. 

Greenwood, VA 22943. 

Main St., Tewksbury, MA 01876. 

300 Park Ave., New York, NY 10022. 

714 W. Olympic Blvd., Los Angeles, CA 90015. 

394 Frelinghuysen Ave., Newark, NJ 07114. 

380 Madison Ave., New York, NY 10017. 

912 Drake St., Columbia, SC 29205. 

117 Ethel Ave., Hawthorne, NJ 07641. 

260 Madison Ave., New York, NY 10016. 

P.O. Box 4423, San Juan, PR 00905. 

Bayard and Severn Sts . , Baltimore, MD 21230. 

205 S. 2d St., Camden, NJ 08103. 

Wilmington Industrial Park, Wilmington, DE 19801. 

Wisconsin Rapids, WI 54494. 

270 Clifton Blvd., Clifton, NJ 07015. 

9 Rockefeller Plaza, New York, NY 10020. 

P.O. Box 389, N. Kansas City, M0 64141. 

P.O. Box 308, Lawrence, KS 66044. 

River Rd., W. Conshohocken, PA 19428. 

P.O. Box 2591, Baton Rouge, LA 70821. 

717 5th Ave., New York, NY 10022. 

P.O. Box 1311, Big Spring, TX 70721. 

12000 Shaker Blvd., Cleveland, OH 44120. 

225 Emmet St., Newark, NJ 07114. 

500 Pear St., Reading, PA 19603. 
Scottdale Rd., Lansdowne, PA 19050. 
P.O. Drawer 460, Picayune, MS 39466. 
P.O. Box 1168. Baltimore, MD 21203. 
12 Dudley St., Providence, RI 02901. 
Camas, WA 98607. 

1502 N. 25th St., Melrose Park, IL 60160. 
150 E. 42d St., New York, NY 10017. 

4th and Parker Sts., Berkeley, CA 94710. 
100 Lister Ave., Newark, NJ 07105. 

Danville, VA 24540. 

450 Schuyler Ave., Kearny, NJ 07032. 

4800 S. Richmond St., Chicago, IL 60632. 

200 Kellogg St., Jersey City, NJ 07305. 

726 King St., Wilmington, DE 19801. 

44-27 Purvis St., Long Island City, NY 11101. 

1700 S. Mt. Prospect Ave., Des Plaines, IL 60018. 

14331 Woodrow Wilson, Detroit, MI 48232. 

845 Edgewater Rd., Bronx, NY 10474. 

300 Union Commerce Bldg., Cleveland, OH 44114. 

300 Union Commerce Bldg., Cleveland, OH 44114. 

212 W. Monroe St., Chicago, IL 60606. 

P.O. Box 13410, Houston, TX 77019. 

P.O. Box 470, Hattiesburg, MS 39401. 

8002 53d Ave. W., Everett, WA 98202. 



DOM 
DVC 
DBC 
DOW 
DCC 
DRW 
DUN 
DUP 
DSC 



DIRECTORY OF MANUFACTURERS 201 

TABLE 22.-- Synthetic organic chemicals.- Directory of manufacturers , 1965 --Continued 



Name of company 



Inc- 



Dominion Products, 

Dover Chemical Co 

Dow Badische Chemical Co 

Dow Chemical Co 

Dow Corning Corp 

Drew Chemical Corp- 

Frank W. Dunne Co 

E. I. duPont de Nemours & Co., Inc- 
Dye Specialties, Inc 



J. S. & W. R. Eakins, Inc 

Eastern Color & Chemical Co 

Eastman Kodak Co 

Tennessee Eastman Co. Div 

Texas Eastman Co. Div 

Edcan Laboratories 

El Paso Natural Gas Products Co- 
Emery Industries, Inc 

Western Div 

Emkay Chemical Co 

Endo Laboratories, Inc 

Enjay Chemical Co 

Epoxylite Corp 

Escambia Chemical Corp 

Ethyl Corp 

Ethyl-Dow Chemical Co 

Evans Chemetics, Inc 



FMC Corp . : 

American Viscose Div 

Inorganic Chemicals Div- 



Niagara Chemical Div— 
Organic Chemicals Div- 



Fabrieolor Manufacturing Corp 

Fairmount Chemical Co., Inc 

Farac Oil & Chemical Co 

Far-Best Corp., 0. L. King Div 

Farmers Chemical Association, Inc 

Farmer's Chemical Co 

Farnow, Inc 

Federal Color Laboratories 

Felton Chemical Co.,, Inc 

Fermco Laboratories, Inc 

Ferro Corp., Ferro Chemical Div 

Fiberfil, Inc 

Fibreboard Paper Products Corp 

Filtered Rosin Products Co 

Fine Organics, Inc 

Firestone Tire & Rubber Co.: 

Firestone Plastics Co. Div 

Firestone Rubber & Latex Products Co. Div— 
Firestone Synthetic Rubber & Latex Co. Div- 

Fisher Melamine Corp 

Fleming Laboratories, Inc 

Florasynth Laboratories, Inc 

Foote Mineral Co 

Foremost Chemical Products Co 

Formica Corp 

Foster Grant Co., Inc 

Foster-Heaton Co 

France, Campbell & Darling, Inc 

Franklin Chemical Co 

Freeman Chemical Corp 

Frisch & Co., Inc 

Fritzsche Bros., Inc 

H. B. Fuller Co 

W. P. Fuller Paint Co 



Office address 



882 3d Ave., Brooklyn, NY 11232. 
15th and Davis Sts., Dover, OH 44622. 
P.O. Box 875, Freeport, TX 77541. 
Main St., Midland, MI 48640. 
P.O. Box 592, Midland, MI 48641. 
416 Division St., Boonton, NJ 07005. 
1007 41st St., Oakland, CA 94608. 
DuPont Bldg., Wilmington, DE 19898. 
26 Journal Sq., Jersey City, N J 07306. 

55 Berry St., Brooklyn, NY 11211. 

35 Livingston St., Providence, RI 02904. 

343 State St., Rochester, NY 14650. 

P.O. Box 511, Kingsport, TN 37662. 

P.O. Box 2068, Longview, TX 75603. 

10 Pine St., S. Norwalk, CT 06856. 

P.O. Box 3986, Odessa, TX 79760. 

4300 Carew Tower, Cincinnati, OH 45202. 

8733 S. Dice Rd., Santa Fe Springs, CA 90670. 

319 2d St., Elizabeth, NJ 07206. 

1000 Stewart Ave., Garden City, NY 11533. 

60 W. 49th St., New York, NY 10020. 

P.O. Box 3397, 1428 N. Tyler Ave., S. El Monte, CA 91733. 

P.O. Box 467, Pensacola, FL 32502. 

100 Park Ave., New York, NY 10017. 

Midland, MI 48640. 

250 E. 43d St., New York, NY 10017. 



1617 John F. Kennedy Blvd., Philadelphia, PA 19103. 
Sawyer Ave. and River Rd., Tonawanda, NY 14207, and 633 

3d Ave., New York, NY 10017. 
100 Niagara St., Middleport, NY 14105. 
1701 Patapsco Dr., Baltimore, MD 21226, and 633 3d Ave. 

New York, NY 10017. 
24-1/2 Van Houten St., Paterson, NJ 07505. 
117 Blanchard St., Newark, NJ 07105. 
147th St. and Indiana Ave., Chicago, IL 60627. 
640 Gilman St., Berkeley, CA 94710. 
P.O. Box 67, Tyner, TN 37392. 
P.O. Box 591, Kalamazoo, MI 49005. 
77 Jacobus Ave., S. Kearny, NJ 07032. 
4526 Chickering Ave . , Cincinnati, OH 45232. 
599 Johnson Ave., Brooklyn, NY 11237. 
4941 S. Racine Ave., Chicago, IL 60609. 
P.O. Box 349, Bedford, OH 44014. 
1701 N. Heidelbach Ave., Evansville, IN 47717. 
1550 Powell St., Emeryville, CA 94608. 
P.O. Box 349, Baxley, GA 31513. 
205 Main St., Lodi, NJ 07644. 

P.O. Box 699, Pottstown, PA 19464. 

1 Firestone Ave., Fall River, MA 02722. 

381 W. Wilbeth Rd., Akron, OH 44301. 

90 Park Ave., New York, NY 10016. 

P.O. Box 10372, 2205 Thrift Rd., charlotte, NC 28201. 

900 Van Nest Ave., Bronx, NY 10462. 

Route 100, Exton, PA 19341. 

P.O. Box 599, Oakland, CA 94604. 

Berdan Ave., Wayne, NJ 07470. 

289 N. Main St., Leominster, MA 01453. 

16 E. 5th St., Paterson, NJ 07524. 

N. Michigan Ave., Kenilworth, NJ 07033. 

2020 Bruck St., Columbus, OH 43207. 

222 E. Main St., Port Washington, WI 53074. 

88 E. 11th St., Paterson, NJ 07524. 

76 9th Ave., New York, NY 10011. 

1150 Eustis St., St. Paul, MN 55108. 

450 E. Grand Ave., S. San Francisco, CA 94080. 



Gamma Chemical Corp 355 Lexingtorl Ave-) New York m 10017 . 

Cane s Chemical Works, Inc 535 5t h Ave., New York, NY 10017 

Geigy Chemical Corp | p. . box 430, Yonkers, NY 10704. 



202 SYNTHETIC ORGANIC CHEMICALS, 1965 

TABLE 22. Synthetic organic chemicals.- Directory of manufacturers , 1965 — Continued 



Name of company 



Office address 



General Aniline & Film Corp., Dyestuff & 

Chemical Div. 
General Electric Co.: 

Chemical Materials Dept 

Insulating Materials Dept 

Silicone Products Dept 

General Foods Corp., Maxwell House Div 

General Latex & Chemical Corp 

General Mills, Inc 

Chemical Div 

General Plastics Manufacturing Co 

General Tire & Rubber Co., Chemical Div 

Geolina Business, Inc 

P. D. George Co 

Georgia-Pacific Corp.: 

Coos Bay Div 

Puget Sound Div 

Gillette Chemical Co 

Gilman Paint & Varnish Co 

Givaudan Corp 

Glasflex, Inc-r 

Glidden Co 

Durkee Famous Foods Div 

Glyco Chemicals, Inc 

B. F. Goodrich Co., B. F. Goodrich Chemical Co 
Div. 

Goodrich-Gulf Chemicals, Inc 

Goodyear Tire & Rubber Co 

Gordon Chemical Co., Inc 

W. R. Grace & Co.: 

Dewey & Almy Chemical Div 

Hampshire Chemical Div 

Hatco Chemical Div 

Marco Chemical Div 

Nitrogen Products Div 

Grain Processing Corp 

Great American Plastics Co 

Great Lakes Chemical Corp 

Great Western Sugar Co 

Grow Chemical Corp., Harris Paint Co. Div 

Guardsman Chemical Coatings, Inc 

Gulf Oil Corp 

Chemicals Dept 

Perkins Glue Branch 

Guth Chemical Co 

H & N Chemical Co 

Haag Laboratories, Inc 

Halby Products Co., Inc 

C. P. Hall Co. of Illinois 

Hamilton Chemical Corp 

Hampden Color & Chemical Co 

Hanna Paint Manufacturing Co., Inc 

Harshaw Chemical Co 

Hartman-Leddon Co 

Hart Products Corp 

Haveg Industries, Inc., Kesin & Compound Div— ■ 

Hawkeye Chemical Co 

Hercules Powder Co., Inc 

Imperial Color & Chemical Dept 

Heresite & Chemical Co 

Hess Oil & Chemical Corp 

Heterochemical Corp 

Hexagon Laboratories, Inc 

Hodag Chemical Corp 

Hoffmann-LaRoche, Inc 

Hoffman-Taff, Inc 

Holland-Suco Color Co 

Hooker Chemical Corp 

Durez Plastics Div 

RC Div 

E. F. Houghton & Co 



P.O. Box 12, Linden, NJ 07036. 



1 Plastics Ave., Pittsfield, MA 01203. 
1 Campbell Rd., Schenectady, NY 12306. 
Waterford, NY 12188. 
1125 Hudson St., Hoboken, NJ 07030. 
666 Main St., Cambridge, MA 02139. 
S. Kensington Rd., Kankakee, IL 60901. 
Quimby St., Ossining, NY 10562. 
3481 S. 35th St., Tacoma, WA 98409. 
1708 Englewood Ave., Akron, OH 44309. 
P.O. Box 1557, Savannah, GA 31402. 
5200 N. 2d St., St. Louis, M0 63147. 

P.O. Box 869, Coos Bay, OR 97420. 

300 Laurel St., Bellingham, WA 98225. 

P.O. Box 362, N. Chicago, IL 60064. 

W. 8th and Pine Sts., Chattanooga, TN 37401. 

125 Delawanna Ave., Delawanna, NJ 07014. 

Stirling, NJ 07980. 

900 Union Commerce Bldg., Cleveland, OH 44115. 

2333 Logan Blvd., Chicago, IL 60647. 

417 5th Ave., New York, NY 10016. 

3135 Euclid Ave., Cleveland, OH 44137. 

1717 E. 9th St., Cleveland, OH 44114. 
1144 E. Market St., Akron, OH 44316. 
88 Webster St., Worcester, MA 01603. 

62 Whittemore Ave., Cambridge, MA 02140. 

Poisson Ave., Nashua, NH 03060. 

King George Post Rd., P.O. Box 27, Fords, NJ 08863. 

1711 W. Elizabeth Ave., Linden, NJ 07036. 

P.O. Box 277, 147 Jefferson Ave., Memphis, TN 38101. 

1600 Oregon St., Muscatine, IA 52761. 

85 Water St., Fitchburg, MA 21420. 

P.O. Box 2200, Highway 52 N.W., West Lafayette, IN 47906. 

P.O. Box 5308, Terminal Annex, Denver, CO 80217. 

1010-26 N. 19th St., Tampa, FA 33601. 

1350 Steele Ave. SW., Grand Rapids, MI 49502. 

P.O. Drawer 2100, Houston, TX 77001. 

610 Dwight Bldg., Kansas City, M0 64105. 

632 Cannon Ave., Lansdale, PA 19446. 

332 S. Center St., Hillside, IL 60162. 

Maltese Dr., Totowa, NJ 07512. 

14010 S. Seeley, Blue Island, IL 60406. 

P.O. Box 366, Wilmington, DE 19899. 

5245 W. 73d St., Chicago, IL 60638. 

45 Andrews St., Lowell, MA 01853. 

5 Albany St., Springfield, MA 01101. 

1313 Windsor Ave., Columbus, OH 43216. 

1945 E. 97th St., Cleveland, OH 44106. 

60th St. and Woodland Ave., Philadelphia, PA 19143. 

1440 Broadway, New York, NY 10018. 

900 Greenbank Rd., Wilmington, DE 19808. 

P.O. Box 899, Clinton, IA 52733. 

Hercules Tower, 910 Market St., Wilmington, DE 19899. 

P.O. "Box 231, Glens Falls, NY 12803. 

822 S. 14th St., Manitowoc, WI 54220. 

State St., Perth Amboy, NJ 08861. 

Ill E. Hawthorne Ave., Valley Stream, NY 11582. 

3536 Peartree Ave., Bronx, NY 10469. 

7247 N. Central Park Ave., Skokie, IL 60076. 

324 Kingsland Rd., Nutley, NJ 07110. 

P.O. Box 1246 SSS, Springfield, M0 65805. 

P.O. Box 2166, 24th St. and 5th Ave., Huntington, 

WV 25722. 
Buffalo Ave. and 47th St., Niagara Falls, NY 14302. 
Walck Rd., N. Tonawanda, NY 14121. 
New South Rd., Hicksville, L.I., NY 11802. 
303 W. Lehigh Ave., Philadelphia, PA 19133. 



DIRECTORY OF MANUFACTURERS 
TABLE 22.— Synthetic organic chemicals.- Directory of manufacturers, 1965— Continued 



203 



Name of company 



Houston Chemical Corp 

Charles L. Huisking & Co., Inc., Clintbrook 

Chemical Co. Div. 

Humphrey Chemical Co 

Philip A. Hunt Chemical Corp., Wayland Chemical 

Div. 

Husky-Dominion Briquets 

Hynson, Westcott & Dunning, Inc 

Hysol Corp 



LAK 
LAM 
GDN 

LAS 
LUR 



I.C.I. (Organics), Inc 

IRC, Inc 

Imperial Chemical Co., Inc 

Industrial Biochemicals 

Industrial Dyestuff Co 

Inland Steel Container Co 

Interchemical Corp. : 

Color & Chemicals Div 

Finishes Div 

Organic Chemicals Dept 

International Flavors & Fragrances, Inc 

International Latex Corp 

International Latex & Chemical Corp., Paisley 
Products Div. 

International Minerals & Chemical Corp 

Inter-Pacific Resins, Inc 

Interplastic Corp., Commercial Resins Div 

Ironsides Resins, Inc 

Isocyanate Products, Inc 



Jefferson Chemical Co., Inc 

Jefferson Lake Sulphur Co., Chemical Div- 

Jennat Corp 

Jennison-Wright Corp 

Andrew Jergens Co 

Jersey State Chemical Co 

Jewel Paint & Varnish Co 

S. C. Johnson & Son, Inc 

Jones-Blair Paint Co 

Jordan Chemical Co 



Kaiser Aluminum & Chemical Corp- 

Kali Manufacturing Co 

Kay-Fries Chemicals, Inc 

Kelly-Moore Paint Co 

Kelly-Pickering Chemical Corp— 

Kendall Refining Co 

Kennecott Copper Corp. : 

Chino Mines Div 

Utah Copper Div 

Kenrich Petrochemicals, Inc 

Ketona Chemical Corp 

Keysor Chemical Co 

Keystone Chemurgic Corp 

Keystone Color Works, Inc 

Kilsdonk Chemical Corp 



Office address 



Knapp Products, Inc 

Knoedler Chemical Co 

Kohler-McLister Paint Co 

H. Kohnstamm & Co., Inc 

Koppers Co., Inc., Tar & Chemical Div- 

Koppers Pittsburgh Co 

Kyanize Paints, Inc 



Lakeside Laboratories, Div. of Colgate-Palmolive 

Co. 

Lakeway Chemical Co 

LaMotte Chemical Products Co 

Lancaster Chemical Corp., Gordon Chemicals Co. 

Div. 

Lasco Industries, Inc 

Laurel Soap Manufacturing Co 

Lawter Chemicals, Inc., Krumbhaar Resin Div 



200 Madison Ave., New York, NY 10016. 
417 5th Ave., New York, NY 10016. 

Devine St., North Haven, CT 06473. 
P.O. Box 63, Lincoln, RI 02865. 

P.O. Box 380, Cody, WY 82414. 

Charles and Chase Sts., Baltimore, MD 21201. 

1100 Seneca Ave., Olean, NY 14760. 

55 Canal St., Providence, RI 02901. 

401 N. Broad St., Philadelphia, PA 19108. 

W. 6th and Grass Sts., Shenandoah, IA 51601. 

Edison Industrial Center, Edison, NJ 08817. 

P.O. Box 4249, Massasoit Ave., E. Providence, RI 02914. 

6532 S. Menard Ave., Chicago, IL 60638. 

150 Wagaraw Rd., Hawthorne, NJ 07506. 

1255 Broad St., Clifton, NJ 07015. 

P.O. Box 8, Route 17, Carlstadt, NJ 07072. 

521 W. 57th St., New York, NY 10019. 

Playtex Park, Dover, DE 19901. 

1770 Canalport Ave., Chicago, IL 60616. 

5401 Old Orchard Rd., Skokie, IL 60078. 

P.O. Box 445, 1602 N. 18th St., Sweet Home, OR 97386. 

2015 N.E. Broadway St., Minneapolis, MN 55413. 

270 W. Mound St., P.O. Box 1999, Columbus, OH 43216. 

900 Wilmington Rd., New Castle, DE 19720.. 

P.O. Box 53300, Houston, TX 77052. 

1914 Haden Rd., Houston, TX 77015. 

137 W. 168th St., Gardena, CA 90247. 

P.O. Box 4187, Station E, Toledo, OH 43609. 

2535 Spring Grove Ave., Cincinnati, OH 45214. 

59 Lee Ave., Haledon, NJ 07508. 

345 N. Western Ave., Chicago, IL 60612. 

1525 Howe St., Racine, WI 53403. 

6969 Denton Dr., Dallas, TX 75235. 

Barclay Bldg., 1 Belmont Ave., Bala Cynwyd, PA 19004. 

P.O. Box 337, Gramercy, LA 70052. 
427 E. Mayer St., Philadelphia, PA 19125. 
360 Lexington Ave., New York, NY 10017. 
1015 Commercial St., San Carlos, CA 94070. 
956 Bransten Rd., San Carlos, CA 94070. 
77 N. Kendall Ave., Bradford, PA 16701. 

Hurley, NM 88043. 

P.O. Box 11299, Salt Lake City, UT 84111. 

Foot of E. 22d St., Bayonne, NJ 07002. 

P.O. Box 6565, Tarrant Branch, Birmingham, AL 35217. 

26000 Bouquet Canyon Rd., Saugus, CA 91350. 

R.D. 2, Bethlehem, PA 18017. 

151 W. Gay Ave., York, PA 17403. 

c/o Pfister Chemical Works, P.O. Box 326, Ridgefield, NJ 

07657. 
180 Hamilton Ave., Lodi, NJ 07644. 
651 High St., Lancaster, PA 17604. 
P.O. Box 546, 1201 Osage St., Denver, CO 80201. 
161 Avenue of the Americas, New York, NY 10013. 
Koppers Bldg., 430 7th Ave., Pittsburgh, PA 15219. 
Koppers Bldg., 430 7th Ave., Pittsburgh, PA 15219. 
2d and Boston Sts., Everett, MA 02149. 

1707 E. North Ave., Milwaukee, WI 53201. 

5025 Evanston Ave., Muskegon, MI 49443. 

Chestertown, MD 21620. 

500 A St., Wilmington, DE 19801. 

1561 Chapin Rd., Montebello, CA 90640. 

Thompson and Tioga Sts., Philadelphia, PA 19134. 

3550 Touhy Ave., Chicago, IL 60645. 



204 SYNTHETIC ORGANIC CHEMICALS, 1965 

TABLE 22. — Synthetic organic chemicals ; Directory of manufacturers , 1965 — Continued 



Name of company 



Leatex Chemical Co 

Lebanon Chemical Corp 

Leffingwell Chemical Co 

Lehigh Chemical Co 

Lehn & Fink Products Corp., Beacon Div 

B. L. Lemke & Co., Inc 

Leonard Refineries, Inc 

Lever Brothers Co 

C. Lever Co., Inc 

Fred'k H. Levey Co., Inc 

Lignin Products Co 

ELi Lilly & Co 

Lubrizol Corp 

George Lueders & Co 

M & T Chemicals, Inc 

MacKenzie Chemical Works, Inc 

Magruder Color Co., Inc 

Maher Color & Chemical Co 

Mallinckrodt Chemical Works 

Manganese Chemical Corp 

Marathon Oil Co., Texas Refining Div 

Marblette Corp 

Marden-Wild Corp 

Marlowe-Van Loan Corp 

Martin-Marietta Corp. : 

Ridgway Color & Chemical Div 

Southern Dyestuff Co. Div 

Max Marx Color & Chemical Co 

Masonite Corp., Alpine Chemical Div 

Massachusetts Plastics, Div. of Rexall Chemical 
Group. 

Maumee Chemical Co 

Otto B. May, Inc 

McCloskey Varnish Co 

Medical Chemicals Corp 

Merck & Co., Inc 

Metalsalts Corp 

Metalead Products Corp 

Metro- Atlantic, Inc 

J. Meyer & Sons, Inc 

Michigan Chemical Corp 

Midland Industrial Finishes Co 

Midwest Plastic Products Co 

Miles Laboratories, Inc., Miles Chemical Co. Div 
Millmaster Onyx Corp. : 

Millmaster Chemical Div., Berkeley Chemical 
Dept. 

Onyx Chemical Co. Div 

Oxy Chemical Div 

Mineral Oil Refining Co 

Minnesota Mining & Manufacturing Co 

Minnesota Paints, Inc 

Miranol Chemical Co., Inc 

Mississippi Chemical Corp 

Mobay Chemical Co 

Molded Fiber Glass Body Co., Resin Div 

Mona Industries, Inc 

Monochem, Inc 

Monsanto Co. : 

Bircham Bend Plant ■ 

Chemstrand Co. Div 

Chocolate Bayou Plant 

Gering Plastics Dept 

Organic Chemical Div 

Plastics Div 

Western Div 

Montrose Chemical Corp. of California 

Mooney Chemical Corp 

Benjamin Moore & Co 

Morton Salt Co., Morton Chemical Co. Div 

Motomco, Inc 



Office address 



2722 N. Hancock St., Philadelphia, PA 19133. 

P.O. Box 180, Lebanon, PA 17042. 

P.O. Box 1187, Perry Annex, Whittier, CA 90604. 

P.O. Box 120, Chestertown, MD 21620. 

33 Richdale Ave., Cambridge, MA 02140. 

199 Main St., Lodi, NJ 07644. 

E. Superior St., Alma, MI 48801. 

390 Park Ave., New York, NY 10022. 

Howard and Huntington Sts., Philadelphia, PA 19133. 

380 Madison Ave., New York NY 10017. 

P.O. Box 960, Erie, PA 16512. 

740 S. Alabama St., Indianapolis, IN 46206. 

29400 Lakeland Blvd., Wickliffe, OH 44092. 

427 Washington St., New York, NY 10013. 

Woodbridge Rd. and Randolph Ave., Rahway, NJ 07065. 

1 Cordello Ave., Central Islip, L. I., NY 11722. 

2385 Richmond Terrace, Staten Island, NY 10302. 

1700 N. ELston Ave., Chicago, IL 60622. 

P.O. Box 5439, St. Louis, M0 63160. 

711 Pittman Rd., Baltimore, MD 21236. 

P.O. Box 1191, Texas City, TX 77591. 

37-31 30th St., Long Island City, NY 11101. 

500 Columbia St., Somerville, MA 02143. 

1508 Joshua Circle, High Point, NC 27261. 

75 Front St., Ridgway, PA 15853. 
P.O. Box 10098, Charlotte, NC 28201. 
192 Coit St., Irvington, NJ 07111. 
P.O. Box 2392, Gulf port, MS 39503. 
West Ave., Ludlow, MA 01056. 

1310 Expressway Dr., Toledo, OH 43608. 
52 Amsterdam St., Newark, NJ 07105. 
7600 State Rd., Philadelphia, PA 19136. 
4541 W. Grand Ave., Chicago, IL 60639. 
126 E. Lincoln Ave., Rahway, NJ 07065. 

200 Wagaraw Rd., Hawthorne, NJ 07507- 

P.O. Box 11005, 2901 Park Blvd., Palo Alto, CA 94306. 

1027 Smith St., Centerdale, RI 02911. 

4321 N. 4th St., Philadelphia, PA 19140. 

500 N. Bankson St., St. Louis, MI 48880. 

P.O. Box 620, E. Water St., Waukegan, IL 60086. 

3251 Chicago Rd., Steger, IL 64075. 

1127 Myrtle St., Elkhart, IN 46514. 

99 Park Ave., New York, NY 10016. 

Warren and Morris Sts., Jersey City, NJ 07302. 

P.O. Box 28, Hackettstown, NJ 07840. 

4401 Park Ave., Dickinson, TX 77539. 

2501 Hudson Rd., St. Paul, MN 55119. 

1101 S. 3d St., Minneapolis, MN 55415. 

277 Coit St., Irvington, NJ 07111- 

P.O. Box 388, Yazoo City, MS 39194. 

Penn Lincoln Parkway, W. Pittsburgh, PA 15205. 

4601 Benefit Ave., Ashtabula, OH 44004. 

65 E. 23d St., Paterson, NJ 07524. 

P.O. Box 433, Geismar, LA 70734. 

190 Grochmal Ave., Indian Orchard, MA 01051. 

350 5th Ave., New York, NY 10001. 

P.O. Box 711, Alvin, TX 77511. 

200 N. 7th St., Kenilworth, NJ 07033. 

800 N. Lindbergh Blvd., St. Louis, M0 63166. 

730 Worcester St., Springfield, MA 01101; P.O. Box 1311, 

Texas City, TX 77591; and River Rd., Addyston, OH 45001. 
9229 E. Marginal Way S., Seattle, WA 98108. 
500 S. Virgil Ave., Los Angeles, CA 90005. 
2301 Scranton Rd., Cleveland, OH 44113. 
548 5th Ave., New York, NY 10036. 
110 N. Wacker Dr., Chicago, IL 60606. 
89 Terminal Ave., Clark, NJ 07066. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. -Synthetic organic chemicals.- Directory of manufacturers , 1 965 --Continued 



205 



NVF 
NLC 
NTB 
NTC 

HUM 
SHF 
USI 



NTL 
NPP 
NPI 
NSC 
NES 
NEP 
NOT 
WOI 
NYC 

NIL 
JDC 
NIT 
NON 
NOP 
NOC 

NEC- 

NPV 

NRS 

LMI 

NW 

NPC 

NOR 

NCW 

NVT 

CMG 



OXR 
OPC 
ORG 
OSB 
OTA 
OTC 
OCF 
0X0 

PLB 

AMR 

PAN 

PNT 

PD 

PSC 

PAT 

CCH 

PEK 

PCH 

PEL 

PEN 

PRP 

PAS 

PAI 

PAR 

PER 

PET 

PTT 

PFN 

PCW 

PFZ 

PHR 



Name of company 



N.V.F. Co 

Nalco Chemical Co 

National Biochemical Co 

National Casein Co 

National Dairy Products Corp.: 

Humko Products Chemical Div 

Sheffield Chemical Co. Div 

National Distillers & Chemical Corp. : 

A-B Chemical Corp. Div 

National Petro Chemical Corp. Div 

U.S. Industrial Chemicals Co. Div 

National Lead Co 

National Plastic Products Co., Inc 

National Polychemicals, Inc 

National Starch & Chemical Corp 

Nease Chemical Co., Inc 

Nepera Chemical Co., Inc 

Neville Chemical Co 

Chlorinated Products Div 

New York Color & Chemical Corp., Subsidiary of 
Tenneco Chemicals, Inc.. 

Nilok Chemicals, Inc 

Nipak, Inc 

Nitrin, Inc 

A. P. Nonweiler Co 

Nopco Chemical Co., Inc 

Norac Co., Inc 



Norda Essential Oil & Chemical Co. 

Norris Paint & Varnish Co 

Norse Chemical Corp 

North American Chemical Co 

Northwestern Chemical Co 

Northwest Petrochemical Corp 

Norwich Pharmacal Co 

Nostrip Chemical Works, Inc 

Novamont Corp 

Nyanza, Inc 



Inc- 



Olin Mathieson Chemical Corp- 

Agricultural Div 

Onyx Oils & Resins, Inc 

Orbis Products Corp 

Organics, Inc 

C. J. Osborn Co 

Ottawa Chemical Co 

Ott Chemical Co 

Owens-Corning Fiberglas Corp- 
Oxo Chemicals Co 



P-L Biochemioals, Inc 

Pacific Resins & Chemical Co 

Pan American Petroleum Corp 

Pantasote Co 

Parke, Davis & Co 

Passaic Color & Chemical Co 

Patent Chemicals, Inc 

Pearsall Chemical Co 

Peck's Products Co 

Peerless Chemical Co ; 

Pelron Corp 

S. B. Penick & Co 

Parsons-Plymouth Div 

Pennsalt Chemicals Corp 

Pennsylvania Industrial Chemical Corp- 

Pennsylvania Refining Co 

Perry & Derrick Co 

Petroleum Chemicals, Inc 

Petro-Tex Chemical Corp 

Pfanstiehl Laboratories, Inc 

Pfister Chemical Works 

Chas. Pfizer & Co., Inc 

Pharmachem Corp 



Office address 



Maryland Ave. and Beech St., Wilmington, DE 19899. 
6216 W. 66th PI., Chicago, IL 60638. 
3127 W. Lake St., Chicago, IL 60612. 
601 W. 80th St., Chicago, IL 60620. 



P.O. 
P.O. 



Box 398, Memphis, TN 38101. 
Box 630, Norwich, NY 13815. 



99 Park Ave., New York, NY 10016. 

99 Park Ave., New York, NY 10016. 

99 Park Ave., New York, NY 10016. 

Ill Broadway, New York, NY 10006. 

Odenton, MD 21113. 

51 Eames St., Wilmington, MA 01887. 

750 3d Ave., New York, NY 10017. 

P.O. Box 221, State College, PA 16801. 

Route 17 and Averill Ave., Harriman, NY 10926. 

Neville Island P.O., Pittsburgh, PA 15225. 

Neville Island P.O., Pittsburgh, PA 15225. 

374 Main St., Belleville, NJ 07109. 

Mill St. and N. Transit, Lockport, NY 14094. 

301 S. Howard St., Dallas, TX 75221. 

P.O. Box 233, Cordova, IL 61242. 

P.O. Box 1007, Oshkosh, WI 54901. 

60 Park PI., Newark, NJ 07101. 

405 S. Motor Ave., Azusa, CA 91703, and 169 Millbank St. 

Lodi, NJ 07644. 
475 10th Ave., New York, NY 10001. 
1710 Front St. NE., Salem, OR 97303. 
2121 Norse Ave., Cudahy, WI 53110. 
19 S. Canal St., Lawrence, MA 01843. 
120 N. Aurora St., W. Chicago, IL 60185. 
P.O. Box 99, Anacortes, WA 98221. 
17 Eaton Ave., Norwich, NY 13815. 
182 Liberty Ave., Jamaica, NY 11433. 
P.O. Box 189, Kenova, WV 25530. 
Magunco Rd., P.O. Box 349, Ashland, MA 01721. 

445 W. 59th St., New York, NY 10019. 
P.O. Box 991, Little Rock, AR 72203. 
95 Broad St., New York, NY 10004. 
475 10th Ave., New York, NY 10018. 
1724 Greenleaf Ave., Chicago, IL 60628. 
1301 W. Blancke St., Linden, NJ 07036. 
700 N. Wheeling St., Toledo, OH 43605. 
500 Agard Rd., Muskegon, MI 49945. 
National Bank Bldg., Toledo, OH 43614. 
2100 Grant Bldg., Pittsburgh, PA 15219. 

1037 W. McKinley Ave., Milwaukee, WI 53205. 

3400 13th Ave. SW., Seattle, WA 98134. 

P.O. Box 591, Tulsa, OK 74102. 

26 Jefferson St., Passaic, NJ 07056. 

Foot of Jos. Campau, Detroit, MI 48232. 

28-36 Paterson St., Paterson, NJ 07501. 

335 McLean Blvd., Paterson, NJ 07504. 

P.O. Box 108, Phillipsburg, NJ 08865. 

P.O. Box 14508, St. Louis, M0 63178. 

3850 Oakman Blvd., Detroit, MI 48204. 

7847 W. 47th St., Lyons, IL 60534. 

100 Church St., New York, NY 10008. 

100 Church St., New York, NY 10008. 

3 Penn Center, Philadelphia, PA 19102. 

120 State St., P.O. Box 240, Clairton, PA 15025. 

Union Bank Bldg., Butler, PA 16001. 

2510 Highland Ave., Norwood, OH 45212. 

P.O. Box 1522, Lake Charles, LA 70601. 

P.O. Box 2584, Houston, TX 77001. 

1219 Glen Rock Ave., Waukegan, IL 60086. 

P.O. Box 326, Ridgefield, NJ 07657. 

235 E. 42d St., New York, NY 10017. 

Broad and Wood Sts., Bethlehem, PA 18015. 



206 SYNTHETIC ORGANIC CHEMICALS, 1965 

TABLE 22. — Synthetic organic chemicals; Directory of manufacturers , 1965 — Continued 



Name of company 



Office address 



RGC 
RH 



Phelan-Faust Paint Manufacturing Co., Phelan's 
Resins & Plastics Div. 

Phillips Petroleum Co 

Phoenix Oil Co 

Pierce Organies, Inc 

Pillsbury Co., Chemical Div 

Pilot Chemical Co 

Pioneer Chemical Works, Inc 

Pioneer Plastics Corp., Chemical Div 

Pitt-Consol Chemical Co 

Pittsburgh Plate Glass Co 

Plastics Engineering Co 

Plastics Manufacturing Co 

Plastics Materials, Inc 

Plumb Chemical Corp 

Polak's Frutal Works 

Polychemical Laboratories, Inc 

Polymer Corp 

Polymer Industries, Inc 

Poly Resins 

Polyrez Co., Inc 

Polyvinyl Chemicals, Inc 

Pontiac Refining Corp 

Pratt & Lambert, Inc 

Premier Malt Products, Inc 

Procter & Gamble Co., Procter & Gamble Manufac- 
turing Co. Div. 

Proctor Chemical Co., Inc 

Productol Chemical Co., Inc 

Products Research & Chemical Corp 

Publicker Industries, Inc 

Pure Oil Co 

Purex Corp., Ltd 

Quaker Chemical Corp 

Quaker Oats Co 

K. J. Quinn&Co., Inc 

R.S.A. Corp 

Rachelle Laboratories, Inc 

Raybestos-Manhattan, Inc., Raybestos Div 

Rayette, Inc 

Red Spot Paint & Varnish Co., Inc 

Refined Products Co ■ 

Reheis Chemical Co., Div. of Armour Pharma- 
ceutical Co. 

Reichhold Chemicals, Inc 

Varcum Chemical Div 

Reilly Tar & Chemical Corp 

Reliance Universal, Inc 

Remington Arms Co., Inc 

Renroh Resins 

Retzloff Chemical Co 

Rexall Chemical Co 

Rexall Chemical Co. - Kearny 

Rezolin, Inc 

Rhodia, Inc 

Richardson Co 

Richardson Polymers Div 

Richfield Oil Corp 

Riker Laboratories, Div. of Rexall Drug & 

Chemical Co. 

Rinshed-Mason Co 

F. Ritter & Co 

Ritter Chemical Co., Inc 

Ritter Pfaudler Corp., Ionac Chemical Co. Div-- 

Riverdale Chemical Co 

Roberts Chemicals, Inc 

Rock Hill Printing & Finishing Co 

Roehr Chemicals, Inc 

Rogers Corp 

Rohm & Haas Co 



Oak St. and Buff Rd., P.O. Box 189, Burlington, IA 52602. 

Bartlesville, OK 74003. 

9505 Cassius Ave., Cleveland, OH 44-105. 

P.O. Box 98, Rockford, IL 61105. 

1152 Pillsbury Bldg., Minneapolis, MN 55402. 

11756 Burke St., Santa Fe Springs, CA 90670. 

940 N. Delaware Ave., Philadelphia, PA 19123. 

Pionite Rd., Auburn, ME 04210. 

191 Doremus Ave., Newark, NJ 07105. 

I Gateway Center, Pittsburgh, PA 15222. 
1607 Geele Ave., Sheboygan, WT 53082. 
2700 S. Westmoreland, Dallas, TX 75224. 
New South Rd., Hicksville, NY 11801. 
4837 James St., Philadelphia, PA 19137. 
33 Sprague Ave., Middletown, NY 10940. 
490 Hunts Point Ave., New York, NY 10059. 
2120 Fairmont Ave., Reading, PA 19603. 
Viaduct Rd., Springdale, CT 06879. 
11655 Wicks St., Sun Valley, CA 91352. 
P.O. Box 320, Woodbury, NJ 08096. 

26 Howley St., Peabody, MA 01960. 

P.O. Box 1581, Corpus Christi, TX 78403. 

75 Tonawanda St., Buffalo, NY 14207. 

917 W. Juneau Ave., Milwaukee, WI 53201. 

Ivorydale Technical Center, Rm. 2S25, Cincinnati, 

OH 45217. 
P.O. Box 399, Salisbury, NC 28144. 
615 S. Flower St., Los Angeles, CA 90017. 
2919 Empire Ave., Burbank, CA 91504. 
1429 Walnut St., Philadelphia, PA 19102. 
200 E. Gulf Rd., Palatine, IL 60067. 
5101 Clark Ave., Lakewood, CA 90712. 

Elm, Lime, and Sandy Sts., Conshohocken, PA 19428. 
Merchandise Mart Plaza, Chicago, IL 60654. 
195 Canal St., Maiden, MA 02148. 

690 Saw Mill River Rd., Ardsley, NY 10502. 

P.O. Box 9095, 700 Henry Ford Ave., Long Beach, CA 90810. 

75 E. Main St., Stratford, CT 06601. 

261 E. 5th St., St. Paul, MN 55101. 

110 Main St., Evansville, IN 47708. 

624 Schuyler Ave., Lyndhurst, NJ 07071. 

325 Snyder Ave., Berkeley Heights, NJ 07922. 

525 N. Broadway, White Plains, NY 10602. 
Niagara Falls, NY 14302. 

II S. Meridan St., Indianapolis, IN 46204. 

4730 Crittenden Dr., P.O. Box 21067, Louisville, KY 

40221, and 6901 Cavalcade, Houston, TX 77001. 
939 Barnum Ave., Bridgeport, CT 06602. 
P.O. Box 1191, New Bern, NC 28560. 
P.O. Box 45296, Houston, TX 77045. 
8480 Beverly Blvd., Los Angeles, CA 90048. 
1106 Harrison Ave., Kearny, NJ 07029. 
1651 18th St., Santa Monica, CA 90404. 
600 Madison Ave., New York, NY 10022. 
27th Ave. and Lake St., Melrose Park, IL 60160. 
345 Morgan Lane, West Haven, CT 06516. 
555 S. Flower St., Los Angeles, CA 90054. 
19901 Nordhoff St., Northridge, CA 91326. 

5935 Milford Ave., Detroit, MI 48210. 

4001 Goodwin Ave., Los Angeles, CA 90039. 

403 W. Main St., Amsterdam, NY 12010. 

Birmingham, NJ 08011. 

220 E. 17th St., Chicago Heights, IL 60411. 

P.O. Box 546, Nitro, WV 25143. 

Rock Hill, SC 29730. 

52-20 37th St., Long Island City, NY 11101. 

Main St., Rogers, CT 06263. 

222 W. Washington Sq., Philadelphia, PA 19105. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. — Synthetic organic chemicals.- Directory of manufacturers , 1965— Continued 



207 



Name of company 



Roma Chemical Corp 

Rosenberg Bros. & Co 

Rowland Products, Inc 

Royce Chemical Co 

Rozilda Laboratories, Inc 

Ruberoid Co 

St. Regis Paper Co., Lake States Yeast & 
Chemical Div. 

Salsbury Laboratories 

Sandoz, Inc 

Dyestuff Div., Pigment Dept 

Sartomer Resins, Inc 

Schaefer Varnish Co., Inc 

Schenectady Chemicals, Inc 

Scher Bros., Inc 

R. P. Scherer Corp 

Schering Corp 

Scholler Bros., Inc 

Seaboard Chemicals, Inc 

G. D. Searle & Co 

Seidlitz Paint & Varnish Co 

Sekisui Plastics Corp 

Selney Co., Inc 

Seydel-Woolley & Co., Inc 

Shamrock Oil & Gas Corp 

Shanco Plastics & Chemicals, Inc 

Shell Oil Co 

Shell Chemical Co. Div 

Shepherd Chemical Co 

Sherwin-Williams Co 

Shulton, Inc 

George F. Siddall Co., Inc 

Signal Oil & Gas Co., Houston Div 

Simpson Timber Co 

Sinclair Koppers Chemical Co 

Sinclair-Koppers Co 

Sinclair Paint Co 

Sinclair Petrochemicals, Inc 

Sinclair Refining Co 

James B. Sipe & Co 

Skelly Oil Co 

G. Frederick Smith Chemical Co 

Smith, Kline & French Laboratories 

Socony Mobil Oil Co., Inc.: 

Mobil Chemical Co. Div 

Mobil Oil Co. Div 

Sohio Chemical Co. & Solar Nitrogen Chemicals, 

Inc. 

Solar Chemical Corp 

Soluol Chemical Co., Inc 

Solvent Chemical Co., Inc 

Sonford Chemical Co 

Sonoco Products Co 

Souhegan Wood Products, Inc 

Sou-Tex Chemical Co., Inc 

Southeastern Mhesives Co 

Southeast Polymers, Inc 

Southern Nitrogen Co,, Inc 

Southern Sizing Co 

Spaulding Fibre Co., Inc 

E. R. Squibb & Sons Div. of Olin Mathieson 

Chemical Corp. 
A. E. Staley Manufacturing Co 

UBS Chemical Co. Div 

Stamford Chemical Co 

Standard Brands, Inc., Clinton Corn Processing 

Co. Div. 

Standard Chemical Products, Inc 

Standard Chlorine Chemical Co., Inc 

Standard Oil Co. of California, Chevron 

Chemical Co. 



Office address 



900 Passaic Ave., E. Newark, NJ 07029. 
100 Landing Ave., Smithtown, NY 11787. 
34 Fairview Lane, Kensington, CT 06037. 
Carlton Hill P.O., E. Rutherford, NJ 07073. 
814 Madison St., Hoboken, NJ 07030. 
S. Bound Brook, NJ 08880. 

603 W. Davenport St., Rhinelander, WI 54501. 

500 Gilbert St., Charles City, IA 50616. 

P.O. Box 357, Fair Lawn, NJ 07410. 

61-63 Van Dam St., New York, NY 10013. 

P.O. Box 56, Essington, PA 19029. 

1350 S. 15th St., Louisville, KY 40210. 

Congress St. and 10th Ave., Schenectady, NY 12301. 

P.O. Box 538, Allwood Station, Clifton, NJ 07012. 

9425 Grinnell Ave., Detroit, MI 48213. 

1011 Morris Ave., Union, NJ 07083. 

Collins and Westmoreland Sts., Philadelphia, PA 19134. 

30 Foster St., Salem, MA 01970. 

P.O. Box 5110, Chicago, IL 60680. 

18th and Garfield Sts., Kansas City, M0 64141. 

666 Dietrich Ave., Hazelton, PA 18201. 

65 9th St., Bldg. 15, Brooklyn, NY 11215. 

748 Rice St. NW., Atlanta, GA 30318. 

P.O. Box 631, Amarillo, TX 79105. 

2716 Kenmore Ave., Tonawanda, NY 14150. 

113 W. 52d St., New York, NY 10019. 

113 W. 52d St., New York, NY 10019. 

2803 Highland Ave., Cincinnati, OH 45212. 

101 Prospect Ave. NW., Cleveland, OH 44101. 

697 Route 46, Clifton, NJ 07015. 

P.O. Box 925, Spartanburg, SC 29301. 

P.O. Box 5008, Harrisburg Station, Houston, TX 77012. 

2301 N. Columbia Blvd., Portland, OR 97217. 

P.O. Box 5536, Houston, TX 77012. 

900 Koppers Bldg., Pittsburgh, PA 15219. 

3960 E. Washington Blvd., Los Angeles, CA 90023. 

600 5th Ave., New York, NY 10020. 

600 5th Ave., New York, NY 10020. 

P.O. Box 8010, Pittsburgh, PA 15216. 

P.O. Box 1650, Tulsa, OK 74102. 

867 McKinley Ave . , Columbus , OH 43223 . 

1500 Spring Garden St., Philadelphia, PA 19101. 

150 E. 42d St., New York, NY 10017. 

612 S. Flower St., Los Angeles, CA 90054, and P.O. 

Box 3311, Beaumont, TX 77704. 
621 Republic Bldg., Cleveland, OH 44115. 

Solar Park, Leominster, MA 01453. 

Green Hill and Market Sts., W. Warwick, RI 02893. 

341 Commercial St., Maiden, MA 02148. 

412 Main St., Houston, TX 77002. 

Harts ville, SC 29550. 

Wilton, NH 03086. 

E. Catawba Ave., Mount Holly, NC 28120. 

P.O. Box 791, Lenoir, NC 28645. 

P.O. Box 309, Chattanooga, TN 37401. 

P.O. Box 246, Savannah, GA 31402. 

P.O. Box 391, East Point, GA 30044. 

310 Wheeler St., Tonawanda, NY 14150. 

745 5th Ave., New York, NY 10022. 

N. 22d and Eldorado Sts., Decatur, IL 62525. 

491 Main St., Cambridge, MA 02142. 

45 Jefferson St., P.O. Box 1131, Stamford, CT 06940. 

1251 Beaver Channel Parkway, Clinton, IA 52733. 

1301 Jefferson St., Hoboken, NJ 07030. 
1015 Belleville Turnpike, Kearny, NJ 07032. 
200 Bush St., San Francisco, CA 94120. 



208 SYNTHETIC ORGANIC CHEMICALS, 1965 

TABLE 22. — Synthetic organic chemicals .- Directory of manufacturers , 1 965 --Continued 



Name of company 



Standard Oil Co. of Ohio 

Standard Pyroxoloid Corp 

Stange Co 

Stauf f er Chemical Co . : 

Calhio Chemicals Div 

Industrial Chemical Div 

Specialty Chemical Div 

Stein, Hall & Co., Inc 

Stepan Chemical Co.: 

Industrial Chemicals Div. , Millsdale Works— 

Maywood Div 

Sterling Drug, Inc.: 

Glenbrook Laboratories Div 

Hilton-Davis Chemical Co. Div 

Salvo Chemical Div 

Thomasset Colors Div 

Winthrop Laboratories Div 

Stresen-Reuter, Inc 

Sucro-Chemical Div. of Colonial Sugars Co 

Sullivan Varnish Co 

Summit Chemical Products Corp 

Sun Chemical Corp., Chemical Products Div 

Sun Chemical Corp-, Pigments Div 

Sunkist Growers, Inc ' — 

Sun Oil Co 

SunOlin Chemical Co 

Sunray DX Oil Co 

Suntide Refining Co 

Swift & Co 

Synco Resins, Inc 

Syntex Corp., Arapahoe Chemicals Div 

Synthetic Chemicals, Inc 

Synthetic Products Co 

Synthron, Inc 

Synvar Corp 

Tanatex Chemical Corp 

Charles S. Tanner Co 

Taylor Corp 

Tennant Development Corp., Chemical Div 

Tenneco Chemicals, Inc 

Berkshire Color Div 

Cal/Ink Div 

Newport Div 

Nixon-Baldwin Div 

Nuodex Div 

Tenneco Manufacturing Co 

Tenneco Plastics Div 

Tenneco Oil Co 

Tennessee Copper Co 

Texaco, Inc • 

Texas Alkyls, Inc 

Texas-U.S. Chemical Co 

Tex Chem Co 

Texize Chemicals, Inc 

Textilana Corp 

Thiokol Chemical Corp 

Thomason Industries, Inc., Southern Resin Div 

Thompson Chemical Co 

Thompson-Hayward Chemical Co -- 

Ticonderoga Chemical Corp 

Tidewater Oil Co 

Toms River Chemical Corp 

Tousey Varnish Co 

Trancoa Chemical Corp 

Arthur C. Trask Co 

Triangle Chemical Co 

Trojan Powder Co 

Troy Chemical Co 

Trylon Chemical Corp 

Joseph Turner & Co 



Office address 



Midland Bldg., Cleveland, OH 44115. 
85 Pleasant St., Leominster, MA 01453. 
342 N. Western Ave., Chicago, IL 60612. 

380 Madison Ave., New York, NY 10017. 
380 Madison Ave., New York, NY 10017. 
380 Madison Ave., New York, NY 10017. 
605 3d Ave., New York, NY 10016. 



Elwood, IL 60421. 
100 W. Hunter Ave. 



Maywood, NJ 07607. 



90 Park Ave., New York, NY 10016. 

2235 Langdon Farm Rd., Cincinnati, OH 45237. 

Military Rd., Rothschild, WI 54474. 

120 Lister Ave., Newark, NJ 07105. 

90 Park Ave., New York, NY 10016. 

400 W. Roosevelt Ave., Bensenville, IL 60106. 

P.O. Drawer G, Gramercy, LA 70052. 

410 N. Hart St., Chicago, IL 60622. 

11 William St., Belleville, NJ 07109. 

Wood River Junction, RI 02894. 

441 Tompkins Ave., Staten Island, NY 10305. 

720 E. Sunkist St., Ontario, CA 91764. 

1608 Walnut St., Philadelphia, PA 19103. 

P.O. Box F, Claymont, DE 19703. 

P.O. Box 2039, Tulsa, OK 74102. 

P.O. Box 2608, Corpus Christi, TX 78403. 

115 W. Jackson Blvd., Chicago, IL 60604. 

32 Henry St., Bethel, CT 06801. 

2855 Walnut St., Boulder, CO 80301. 

335 McLean Blvd., Paterson, NJ 07504. 

1636 Wayside Rd., Cleveland, OH 44112. 

Ryan Ave., Ashton, RI 02805. 

726 King St., Wilmington, DE 19801. 

P.O. Box 388, Lyndhurst, NJ 07071. 

450 Furman Hall Rd., Greensville, SC 29608. 

Valley Forge, PA 19481. 

100 Park Ave., New York, NY 10017. 

300 E. 42d St., New York, NY 10017. 

12th and Bern Sts., Reading, PA 19604. 

711 Camelia St., Berkeley, CA 94710. 

P.O. Box 911, Pensacola, FA 32502. 

Nixon, NJ 08818. 

1 Virginia St., Newark, NJ 07207. 

P.O. Box 2511, Houston, TX 77001. 

P.O. Box 38, East Brunswick, NJ 08816. 

P.O. Box 2511, Houston, TX 77001. 

Copperhill, TN 37317. 

P.O. Box 52332, Houston, TX 77052. 

P.O. Box 600, Deer Park, TX 77536. 

P.O. Box 667, Port Neches, TX 77651. 

20-21 Wagaraw Rd., Fair Lawn, NJ 07410. 

P.O. Box 368, Greenville, SC 29602. 

12607 Cerise Ave., Hawthorne, CA 90250. 

P.O. Box 27, Bristol, PA 19007. 

P.O. Drawer 1600, Fayetteville, NC 28301. 

90 Mendor Ave., Pawtucket, RI 02862. 

5200 Speaker Rd., Kansas City, KA 66106. 

Marguerite Ave., Leominster, MA 01453. 

Delaware City, DE 19706. 

Route 37, P.O. Box 71, Toms River, NJ 08753. 

135 W. Lake St., North Lake, IL 60164. 

312-326 Ash St., Reading, MA 01867. 

327 S. LaSalle St., Chicago, IL 60604. 

206 Lower Elm St., P.O. Box 4528, Macon, GA 31208. 

17 N. 7th St., Allentown, PA 18105. 

338 Wilson Ave., Newark, NJ 07105. 

P.O. Box 5101, Station B, Greenville, SC 29606. 

P.O. Box 88, Ridgefield, NJ 07451. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. -Synthetic organic chemicals.- Directory of manufacturers , 1965— Continued 



209 



Name of company 



Office address 



USS Chemicals Div. of U.S. Steel Corp 

Paul Uhlich & Co., Inc 

Ungerer & Co 

Union Bag-Camp Paper Corp., Nelio Chemical Div-- 
Union Carbide Corp.: 

Chemicals Div 

Plastics Div 

Silicones Div 

Union Oil Co. of California 

Union Starch & Refining Co., Inc 

United Carbon Co 

United Chemical Corp. of Norwood 

United Chemical Products Corp 

United Cork Companies 

United Oil Manufacturing Co 

U.S. Borax Research Corp 

U.S. Oil Co 

U.S. Peroxygen Corp 

United States Pipe & Foundry Co 

U.S. Plastic & Chemical Corp 

United States Plywood Corp., California Div., 
Shasta Operations. 

United States Rubber Co., Chemical Div 

Universal Chemicals Corp 

Universal Detergents, Inc. & Petrochemicals Co-- 

Universal Oil Products Co 

Chemical Div 

Upjohn Co 

Carwin Organic Chemicals 

Utah Resin Co., Inc 



Valchem 

Valentine Sugars, Inc., Valite Div- 

Van De Mark Chemical Co 

Vanderbilt Chemical Corp 

Van Dyk & Co., Inc 

Varney Chemical Corp 

Velsicol Chemical Corp 



Ventron Corp., Metal Hydrides Div 

Vermi lye-Bell 

Verona-Pharma Chemical Corp 

Vickers Refining Co., Inc 

Vineland Chemical Co 

Virginia Chemicals, Inc 

Vistron Corp., Silmar Div 

Vitamins, Inc 

Vita-Var Corp., Div. of Textron Industries, Inc- 
Vulcan Materials Co., Frontier Chemical Co. Div- 

Wallace & Tiernan, Inc.: 

Harchem Div 

Lucidol Div 

Warner-Jenkinson Manufacturing Co 

Washburn-Purex Co 

Washine Chemical Corp 

West Coast Adhesives Co 

Westinghouse Electric Corp., Insulating 

Materials Div. 

Weston Chemical Corp 

West Virginia Pulp & Paper Co., Polychemicals 

Div. 

Weyerhaeuser Co., Wood Products Div 

White & Bagley Co 

White & Hodges, Inc 

White Laboratories, Inc 

Whitmoyer Laboratories, Inc 

Whittemore -Wright Co., Inc 

Wica Chemicals, Inc 

Wilmot & Cassidy, Inc 



Rm. 2104, Grant Bldg., Pittsburgh, PA 15219. 
90 West St., New York, NY 10006. 
161 Avenue of the Americas, New York, NY 10013. 
P.O. Box 6170, Jacksonville, FA 32205. 

270 Park Ave., New York, NY 10017. 

270 Park Ave . , New York, NY 10017. 

270 Park Ave., New York, NY 10017. 

461 S. Boylston St., Los Angeles, CA 90017. 

301 Washington St., Columbus, IK 47201. 

P.O. Box 149, Baytown, TX 77520. 

P.O. Box 327, Endicott St., Norwood, MA 02062. 

York and Colgate Sts . , Jersey City, NJ 07302 . 

50 Central Ave., Kearny, NJ 07032. 

2d and Cascade Sts., Erie, PA 16512. 

3075 Wilshire Blvd., Los Angeles, CA 90005. 

P.O. Box 4228, E. Providence, RI 02914. 

850 Morton Ave., Richmond, CA 94804. 

3300 1st Ave. N., Birmingham, AL 35202. 

122 E. Railroad Ave., W. Haverstraw, NY 10993. 

P.O. Box 1688, Redding, CA 96002. 

Naugatuck, CT 06771. 

1224 Mundon Rd., P.O. Box 1224, Ashtos, RI 02865. 

1825 E. Spring St., Long Beach, CA 90806. 

30 Algonquin Rd., Des Plaines, IL 60018. 

State Highway 17, E. Rutherford, NJ 07073. 

7000 Portage Rd., Kalamazoo, MI 49001. 

Sackett Point Rd., North Haven, CT 06473. 

604-605 Kearns Bldg., Salt Lake City, UT 84101. 

1407 Broadway, New York, NY 10018. 

726 Whitney Bldg., New Orleans, LA 70130. 

N. Transit Rd., Lockport, NY 14094. 

33 Winfield St., E. Norwalk, CT 06855. 

11 William St., Belleville, NJ 07109. 

2001 Afton Rd., Janesville, WI 53545. 

330 E. Ohio St., Chicago, IL 60611 and 4902 Central Ave. 

Chattanooga, TN 37410. 
12-24 Congress St., Beverly, MA 01915. 
21707 Bothell Way, Bothell, WA 98011. 
P.O. Box 385, Union, NJ 07083. 
P.O. Box 2240, Wichita, KS 67201. 
W. Wheat Rd., Vineland, NJ 08360. 
West Norfolk, VA 23703. 

12335 S. Van Ness Ave., Hawthorne, CA 90250. 
809 W. 58th St., Chicago, IL 60621. 
177 Oakwood Ave., Orange, NJ 07050. 
P.O. Box 545, Wichita, KS 67201. 



25 Main St., Belleville, NJ 07109. 
1740 Military Rd., Buffalo, NY 14240. 
2526 Baldwin St., St. Louis, 113 63106. 
2244 Elston Ave., Chicago, IL 60614. 
165 Main St., Lodi, NJ 07644. 
11104 NW. Front Ave., Portland, OR 97231. 
Trafford, PA 15085. 

104 E. 40th St., Suite 107, New York, NY 10016. 
P.O. Box 5207, N. Charleston, SC 29406. 

118 S. Palmetto St., MarshfieM, WI 54449. 
P.O. Box 1171, Worcester, MA 01601. 
576 Lawrence St., Lowell, MA 01852. 
Galloping Hill Rd., Kenilworth, NJ 07033. 
P.O. Box 97, Myerstown, PA 17067. 
62 Alford St., Boston, MA 02129. 
P.O. Box 506, Charlotte, NC 28201. 
108 Provost St., Brooklyn, NY 11222. 



210 SYNTHETIC ORGANIC CHEMICALS, 1965 

TABLE 22. — Synthetic organic chemicals: Directory of manufacturers , 1965 — Continued 



Code 


Name of company 


Office address 


WIL 

WM 

BLA 

WTC 

SON 

WCC 

WAW 

WOD 

WRC 

WON 

WBC 

WYN 

YAW 


Wilson & Co., Inc. : 


4-221 S. Western Blvd., Chicago, IL 60609. 

Snyder Ave. and Swanson St., Philadelphia, PA 19148. 

5050 Edgewood Ct., P.O. Box B, Jacksonville, FA 52203. 

P.O. Box 305, Paramus, NJ 07652. 

277 Park Ave., New York, NY 10017. 

555 S. Flower St., Los Angeles, CA 90017. 

108 Spring St., Everett, MA 02149. 

P.O. Box 3545, Eugene, OR 97402. 

Park PI. E., Wood Ridge, NJ 07075. 

176 Sunnyside Ave., Woonsocket, RI 02895. 

Route 9, Freehold, NJ 07728. 

1609 Biddle Ave., Wyandotte, MI 48192. 

2731 Boston St., Baltimore, MD 21224. 




Witco Chemical Co., Inc 


w .^° nn ^,°™ j 


W. A. Wood Co 


00 .^ naC p, S; '. n ° 


Woonsocket Color & Chemical Co 


or i^g °n 1 ° c emica orp 


Young Aniline Works, Inc 



APPENDIX 

U.S. Imports of Benzenoid Intermediates 
and Finished Benzenoid Products 

Table 23 summarizes, for 1964 and 1965, U.S. imports of benzenoid chemicals and products 
entered under the Tariff Schedules of the United States (TSUS), schedule 4, part 1, subparts B 
and C. The data, which were obtained by analyzing invoices covering imports through all U.S. 
customs districts, are given in detail in a separate report of the Tariff Commission. 1 

In 1965, general imports of benzenoid intermediates entered under schedule 4, part IB, 
comprised 642 items with a total weight of 38.0 million pounds and an invoice value of $19.5 
million. In 1964, imports consisted of 651 items with a total weight of 18.8 million pounds and 
an invoice value of $14.4 million. About half of the benzenoid chemicals and products imported 
in 1965 were declared to be "competitive" (duty based on "American selling price"). In 1965, 
imports of these products from Canada amounted to 34 percent of the total; imports from that 
country amounted to 13 million pounds, compared with 2.0 million pounds in 1964. In 1965, im- 
ports from Italy amounted to 8.1 million pounds, compared with 1.6 million pounds in 1964. Im- 
ports from West Germany amounted to 7.2 million pounds, compared with 7.6 million pounds in 
1964. Imports from Japan totaled 3.3 million pounds in 1965, compared with 2.2 million pounds 
in 1964; and imports from the United Kingdom amounted to 2.2 million pounds in both 1965 and 
1964. In 1965, sizable quantities of intermediates were also imported from Switzerland (1.6 mil- 
lion pounds), France (1.2 million pounds), and Sweden (0.8 million pounds). 

TABLE 23. — Benzenoid intermediates and finished benzenoid products ; U.S. general imports, 

classified by use, 1964 and 1965 



Quantity 



Invoice 
value 



Invoice 

value 



Intermediates 1 

Finished benzenoid products, total 

Dyes, total 

Acid 

Azoic dyes 

Azoic components: 

Fast color bases 

Fast color salts 

Naphthol AS and its derivatives- 
Basic 

Direct 

Disperse 

Fiber-reactive 

Fluorescent brightening agents 

Mordant 

Solvent ■. 

Sulfur 

Vat 

All other 

Benzenoid pigments (toners and lakes) 

Medicinals and pharmaceuticals 

Flavor and perfume materials 

All other 



1,000 
pounds 
18,789 

23,682 



10,096 

2,093 

14 

311 

113 

901 

1,018 

1,015 

900 

416 

151 

292 

128 

11 



1.000 
dollars 
14,410 

34,670 



16,261 



1,000 
pounds 
37,975 

31,941 



2,713 
2 20 
684 
3,127 
1,613 
8,162 



1,128 
9,764 
2,311 
5,206 



12,276 

1,808 

22 

416 

185 

1,093 

1,227 

931 

1,880 

652 

229 

221 

168 

37 

3,374 

2 33 

797 

3,408 

1,908 

13,552 



1,000 
dollars 

19,483 

45,425 



20,505 



1,510 

12,551 

2,522 

8,337 



1 Includes small quantities of rubber-processing chemicals. 

2 Includes ingrain dyes. 

3 Includes organic pesticides and agricultural chemicals, plasticizers, surface -active agents, and textile 
assistants. 

Source: Compiled from the records of the U.S. Bureau of Customs. 



1 Imports of Benzenoid Chemicals and Products, 1965, TC Publication 183, 1966 [processed]. 



211 



212 SYNTHETIC ORGANIC CHEMICALS, 1965 

The most important intermediates imported in 1965 were adipic acid, polyalkylbenzene, 
p-nitrotoluene, 3-hydroxy- 2-naphthoic acid (B. O. N. )> cyclohexanone, acetoacetanilide, Gamma 
acid, anthraquinone, 2-(morpholinothio)benzothiazole, and sodium naphthionate. In 1965, imports 
of adipic acid amounted to 13. 7 million pounds, compared with 1. 9 million pounds in 1964, and 
came almost entirely from Canada. Imports of polyalkylbenzene in 1965 totaled 6. 1 million 
pounds, compared with 725,000 pounds in 1964, and all came from Italy. In 1965, imports of 
p-nitrotoluene, which came principally from Sweden and Germany, totaled 922, 000 pounds; im- 
ports of B.O.N. , which came from Italy, West Germany, and Japan, totaled 873,000 pounds; 
imports of cyclohexanone (699, 000 pounds) all came from Italy; imports of acetoacetanilide 
(679, 000 pounds) came principally from Switzerland; imports of Gamma acid (595, 000 pounds) 
came from Japan, West Germany, and Italy; imports of anthraquinone (468,000 pounds) came 
from the United Kingdom, Japan, and West Germany; imports of 2-(morpholinothio)benzothiazole 
(415, 000 pounds) all came from the United Kingdom; and imports of sodium naphthionate (326, 000 
pounds) all came from Japan. 

Imports in 1965 of all finished benzenoid chemicals and products that are dutiable under 
part 1C comprised Z, 223 items, with a total weight of 31.9 million pounds and an invoice value 
of $45.4 million. In 1964, imports consisted of 2, 292 items, with a total weight of 23. 7 million 
pounds and an invoice value of $34. 7 million. In 1965, benzenoid dyes were the most important 
group of finished benzenoid products imported. Imports of dyes amounted to $20. 5 million 
(invoice value), or 45.2 percent of the value of all imports under part 1C. In 1964, imports of 
dyes amounted to $16. 3 million (invoice value), or 47. percent of the value of all imports under 
part 1C. 

Imports of medicinals and pharmaceuticals were the next most important group of products 
entered under part 1C in 1965. In 1965, imports of medicinals and pharmaceuticals were valued 
at $12. 6 million (invoice value), or 27. 8 percent of total imports under part 1C. In 1964, imports 
of medicinals and pharmaceuticals were valued at $9. 8 million, or 28. 2 percent of total imports 
under part 1C. In 1965, imports of benzenoid pigments (toners and lakes) were valued at $1. 5 
million, compared with $1. 1 million in 1964. Imports of benzenoid flavor and perfume materials 
in 1965 ($2. 5 million) we re 8 percent more than in 1964. Imports in 1965 of other benzenoid 
products entered under part 1C (chiefly synthetic resins and pesticides) were valued at $8. 3 
million, compared with $5. 2 million in 1964. 



REPORTS OF THE UNITED STATES TARIFF COMMISSION ON THE OPERATION OF THE 
TRADE AGREEMENTS PROGRAM 

*Operation of the Trade Agreements Program, June 1934 to April 1948 (Rept. No. 160, 2d ser., 1949) : 
Part I. Summary 

Part II. History of the Trade Agreements Program 
Part III. Trade-Agreement Concessions Granted by the United States 
Part IV. Trade- Agreement Concessions Obtained by the United States 
Part V. Effects of the Trade Agreements Program on United States Trade 

*Operation of the Trade Agreements Program : Second Report, April 1948-March 1949 (Rept. No. 

163, 2d ser., 1950) 

*Operation of the Trade Agreements Program : Third Report, April 1949-June 1950 (Rept. No. 172, 

2d ser., 1951) 
*Operation of the Trade Agreements Program : Fourth Report, July 1950-June 1951 (Rept. No. 174, 

2d ser., 1952) 
*Operation of the Trade Agreements Program: Fifth Report, July 1951-June 1952 (Rept. No. 191, 

2d ser., 1954) 
*Operation of the Trade Agreements Program: Sixth Report, July 1952- June 1953 (Rept. No. 193, 

2d ser., 1954) 
*Operation of the Trade Agreements Program : Seventh Report, July 1953- June 1954 (Rept. No. 195, 

2d ser., 1955) 
*Operation of the Trade Agreements Program: Eighth Report, July 1954-June 1955 (Rept. No. 197, 

2d ser., 1956) 
*Operation of the Trade Agreements Program : Ninth Report, July 1955-June 1956 (Rept. No. 199, 

2d ser., 1957) 
♦Operation of the Trade Agreements Program: 10th Report, July 1956-June 1957 (Rept. No. 202, 

2d ser., 1959) 
♦Operation of the Trade Agreements Program: 11th Report, July 1957- June 1958 (Rept. No. 204, 

2d ser., 1959) 
♦Operation of the Trade Agreements Program : 12th Report, July 1958-June 1959 (TC Publication 

9, 1961) 
♦Operation of the Trade Agreements Program : 13th Report, July 1959-June 1960 (TC Publication 

51, 1962) 
Operation of the Trade Agreements Program: 14th Report, July 1960-June 1962 (TC Publication 

120, 1964), 350 
Operation of the Trade Agreements Program : 15th Report, July 1962-June 1963 (TC Publication 

147, 1965), 350 
Operation of the Trade Agreements Program : 16th Report, July 1963-June 1964 (TC Publication 

164, 1966), 300 

NOTE.— The reports preceded by an asterisk (*) are out of print. Those followed by a price may be purchased from 
the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402. See inside front 
cover for additional reports. All U.S. Tariff Commission reports reproduced by the Government Printing Office 
may be consulted in the official depository libraries throughout the United States. 



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