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Given  By 

p.  rspct/ct  memoirs 

M3         ^ 


UNITED   STATES  TARIFF  COMMISSION 

SYNTHETIC 
ORGANIC    CHEMICALS 

United  States  Production 
and  Sales,  1965 

TC  Publication  206 

on  Public  Lib 

tntcndent  of  Documents 

JUL  2 11967 

>S!TORY 


RECENT  REPORTS  OF  THE  UNITED  STATES  TARIFF  COMMISSION  ON  SYNTHETIC 

ORGANIC  CHEMICALS 

*Synthetic  Organic  Chemicals,  United  States  Production  and  Sales,  1960  (TC  Publication  34,  1961) 
Synthetic  Organic  Chemicals,  United  States  Production  and  Sales,  1961  (TC  Publication  72,  1962), 

$1.25 
Synthetic  Organic  Chemicals,  United  States  Production  and  Sales,  1962  (TC  Publication   114, 

1963),  $1.50 
Synthetic  Organic  Chemicals,  United  States  Production  and  Sales,  1963  (TC  Publication  143, 

1964),  $1.50 
Synthetic  Organic  Chemicals,  United  States  Production  and  Sales,  1964  (TC  Publication  167, 

1965),  $1.25 


NOTE. — The  report  preceded  by  an  asterisk!*)  is  out  of  print.  The  other  reports  listed  may  be  purchased  from 
the  Superintendent  of  Documents,  U.S.  Government  Printing  Office,  Washington,  D.C.  20402.  See  inside  back 
cover  for  additional  reports.  AH  U.S.  Tariff  Commission  reports  reproduced  by  the  Government  Printing  Office 
may  be  consulted  in  the  official  depository  libraries  throughout  the  United  Stales. 


UNITED  STATES  TARIFF  COMMISSION 


SYNTHETIC 
ORGANIC    CHEMICALS 

United  States  Production 
and  Sales,  1965 


UNDER  THE  PROVISIONS  OF 
SECTION  332  OF  THE  TARIFF 
ACT  OF   1930,  AS  AMENDED 


U.S.  GOVERNMENT  PRINTING  OFFICE 
WASHINGTON  :  1967 


TC  Publication  206 


UNITED  STATES  TARIFF  COMMISSION 

Paul  Kaplowitz,  Chairman 
Glenn  W.  Sutton,  Vice  Chairman 
James  W.  Culliton 
Dan  H.  Fenn,  Jr. 
Penelope  H.  Thunberg 

Donn  N.  Bent,  Secretary 


Address  all  communications 

UNITED  STATES  TARIFF  COMMISSION 

Washington,  D.C.     20436 


For  sale  by  the  Superintendent  of  Documents,  U.S.  Government  Printing  Office 
Washington,  D.C.  20402  -  Price  $1.00 


CONTENTS 

Page 


Introduction- 
Summary  


Vll 


PART  I.        PRODUCTION  AND  SALES  OF  TARS,    TAR  CRUDES,    AND  CRUDES 
DERIVED  FROM  PETROLEUM  AND  NATURAL  GAS 

Tars 

Tar  crudes '■ 

Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion \ 

PART  II.        PRODUCTION  AND  SALES  OF  INTERMEDIATES  AND  FINISHED 
SYNTHETIC  ORGANIC  CHEMICALS,    BY  GROUPS 

General  

Cyclic  intermediates _ 

Dyes """~-'.~."l"l""l""  10 

Pigments ^ 

Medicinal  chemicals , , 

Flavor  and  perfume  materials ,, 

Plastics  and  resin  materials ,□ 

Rubber -processing  chemicals .-, 

Elastomers  (synthetic  rubbers) ., 

P  lasticize  r  s *j? 

Surface -active  agents *i? 

Pesticides  and  other  organic  agricultural  chemicals 52 

Miscellaneous  chemicals ?f 

PART  III.         ALPHABETICAL  LIST  OF  INDIVIDUAL  PRODUCTS,    BY  GROUPS, 
AND  NAMES  OF  MANUFACTURERS 

Tar  crudes ,  , 

Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion 62 

Cyclic  intermediates /. 

Dyes  ::::::::::::::::::::::::  % 

Pigments -- -- 7 

Medicinal  chemicals ,  ,f 

Flavor  and  perfume  materials 12q 

Plastics  and  resin  materials ,-/. 

Rubber -proce s sing  chemicals 13R 

Elastomers  (synthetic  rubbers) _  ,  .-, 

Plasticizers ""1  !?, 

Surface  -active  age nts r*f 

Pesticides  and  other  organic  agricultural  chemicals w  , 

Miscellaneous  chemicals ?f 

Directory  of  manufacturers Jjj^ 

APPENDIX 

U.S.    imports  of  benzenoid  intermediates  and  finished  benzenoid  products 211 


Introduction 

This  is  the  forty-ninth  annual  report  of  the  U.S.   Tariff  Commission  on  domestic  production 
and  sales  of  synthetic  organic  chemicals  and  the  raw  materials  from  which  they  are  made.  The 
report  presents  statistics  for  1965  on  production  and  sales  of  crude  organic  chemicals  derived 
from  coal,  natural  gas,  and  petroleum;  of  intermediates;  and  of  finished  synthetic  organic  chem- 
ical products.  The  finished  products  are  grouped  according  to  their  principal  use--dyes,  syn- 
thetic organic  pigments,  medicinal  chemicals,  flavor  and  perfume  materials,  plastics  and  resin 
materials,  rubber-processing  chemicals,  elastomers,  plasticizers,  surface- active  agents,  pesti- 
cides and  other  organic  agricultural  chemicals,  and  miscellaneous  chemicals.  The  use  classifi- 
cations of  finished  synthetic  organic  chemicals  are  based  principally  on  the  manufacturers' 
annual  reports  to  the  Tariff  Commission;  other  sources  include  trade  associations,  the  chemical 
literature,  chemical  dictionaries,  encyclopedias,  and  consultants  in  the  chemical  industry.  With 
a  few  exceptions,  the  report  does  not  cover  organic  chemicals  (such  as  wood- distillation  products 
essential  oils,  and  naval  stores)  that  are  derived  from  natural  (vegetable)  sources  by  simple  ex- 
traction or  distillation.  The  Commission  has  compiled  the  statistics  given  in  this  report  from 
information  supplied  by  approximately  800  primary  manufacturers,  listed  in  part  III, 

The  first  section  of  the  report  includes  the  statistics  on  all  products  and  groups  of  products 
for  which  such  information  can  be  published.  The  second  section  lists  all  the  chemicals  and 
chemical  products  on  which  data  are  reported  and  identifies  the  manufacturers  of  each.  Each 
reporting    company  has   been  assigned   an  identification   symbol   consisting   of  a    combination 
of  not  more  than  three  capital  letters,  selected  in  most  instances  with  the  approval  of  the  manu- 
facturer, and  usually  bearing  some  relationship  to  the  company  name.  The  identification  symbols 
are  permanent  and,  except  for  such  changes  as  may  be  necessary,  will  be  used  in  all  future  re- 
ports in  this  series.  Like  the  seven  immediately  preceding  reports,  this  report  includes  data  on 
only  those  individual  chemicals  for  which  the  volume  of  production  or  sales  in  the  year  covered 
exceeded  1,000  pounds  or  for  which  the  value  of  sales  exceeded  $1,000. 

The  raw  materials  referred  to  in  this  report  are  obtained  from  coal,  crude  petroleum,  nat- 
ural gas,  and  certain  other  natural  materials,  such  as  vegetable  oils,  fats,  rosin,  and  grains. 
Crude  organic  chemicals  are  derived  from  coal  by  thermal  decomposition,  from  petroleum  and 
natural  gas  by  catalytic  cracking  and  by  distillation  or  absorption,  and  from  other  natural 
sources  by  fermentation.  Production  of  these  crude  organic  chemicals  is  the  first  step  in  the 
manufacture  of  synthetic  organic  chemicals.  From  these  crudes,  intermediates  are  obtained  by 
synthesis  or  refining;  most  of  the  intermediates  are  then  converted  into  finished  chemical  prod- 
ucts, such  as  medicinal  chemicals,  plastics  and  resin  materials,  and  dyes.  More  than  half  of  the 
total  production  of  intermediates  is  not  sold  directly  to  the  ultimate  consumer,  but  is  used  by 
the  producing  companies  themselves  in  their  manufacturing  processes.  The  statistics  given  in 
this  report  include  data  for  all  known  domestic  producers  of  the  items  covered. 

In  this  report  the  statistics  on  production  of  the  individual  chemicals  reported  by  manufac- 
turers include  the  total  output  of  the  companies'  plants,  i.e.,  the  quantities  produced  for  con- 
sumption within  the  producing  plants,  as  well  as  the  quantities  produced  for  domestic  and  foreign 
sale.  The  quantities  reported  as  produced,  therefore,  generally  exceed  the  quantities  reported 
as  sold.  Some  of  these  differences,  however,  are  attributable  to  changes  in  inventories.  As  speci- 
fied in  the  reporting  instructions  that  the  Commission  sends  to  manufacturers,  and  as  used  in 
this  report,  production  and  sales  (unless  otherwise  specifically  indicated)  are  defined  as  follows: 

Production  is  the  total  quantity  of  a  commodity  made  available  by  original  manufacture  only.  It 
is  the  sum  (expressed  in  terms  of  100-percent  active  ingredient  unless  otherwise  specified)  of 
the  quantities  of  a  commodity- - 

(1)  Produced,  separated,  and  consumed  in  the  same  plant  or  establishment    (a  commodity 

is  considered  to  be  separated  when  it  is  isolated  from  the  reaction  system  and/or 
when  it  is  weighed,  analyzed,  or  otherwise  measured).  Byproducts  and  coproducts 
not  classified  as  waste  materials  are  also  included; 

(2)  Produced  and  transferred  to  other  plants  or  establishments  of  the  same  firm; 

(3)  Produced  and  sold  to  other  firms  (including  production  for  others  under  toll  agree- 

ments1); and 

(4)  Produced  and  held  in  stock. 


A  toll  agreement  is  an  agreement  between  two  firms,  under  which  one  firm  furnishes  the  raw  materials  and  pays  the  processing  costs 
and  the  other  firm  prepares  the  finished  product  and  returns  it  to  the  first  firm. 


vi  INTRODUCTION 

Production  excludes- - 

(1)  Purification  of  a  commodity  unless  specifically  requested  in  the  reporting  instructions; 
2)  Intermediate  products  that  are  formed  in  the  manufacturing  process  but  are  not  iso- 
lated from  the  reaction  system- -that  is,  not  weighed,  analyzed,  or  otherwised  meas- 
ured;  and  ,  . 

(3)  Materials  that  are  used  in  the  process  but  are  recovered  for  reuse  or  sale;  and  waste 
products  that  have  no  economic  significance. 

Sales  are  defined  as  actual  sales  of  commodities  by  original  manufacturers  only.  Sales  include-- 

(1)  Shipments  of  commodities  for  domestic  use  and  for  export,  or  segregation  in  a  ware- 

house when  title  has  passed  to  the  purchaser  in  a  bonafide  sale; 

(2)  Shipments  of  a  commodity  produced   by  others  under  toll  agreements;  and 

(3)  Shipments  to  subsidiary  or  affiliated  companies. 

Sales  exclude- - 

(1)  All  intracompany  transfers  within  a  corporate  entity; 

(2)  All  sales  of  purchased  commodities;  and 

(3)  All  shipments  of  a  commodity  produced  for  others  under  toll  agreements. 

The  value  of  a  sale  is  the  net  selling  price,  f.o.b.  plant  or  warehouse,  or  delivered  value, 
whichever  represents  the  normal  industry  practice. 

Data  on  the  chemicals  covered  in  this  report  are  usually  given  in  terms  of  undiluted  mate- 
rials. Products  of  95  percent  or  more  purity  are  considered  to  be  100  percent  pure.  The  prin- 
cipal exceptions  are  the  statistics  on  dyes  and  a  few  solvents,  which  are  reported  in  terms  of 
commercial  concentrations,  and  the  statistics  on  certain  plastics  and  resins,  which  are  reported 
on  a  dry  basis.  The  report  specifically  notes  those  products  for  which  the  statistics  are  reported 
in  terms  of  commercial  concentrations.  .*.,..,  ■    „ 

The  average  unit  values  of  sales  for  groups  of  products  shown  in  the  tables  accompanying 
this  report  are  weighted  averages  for  products  which  vary  widely  in  unit  values  and  in  the  quan- 

tltieinthiS  report,  statistics  are  presented  in  as  great  detail  as  is  possible  without  revealing  the 
operations  of  individual  producers.  Statistics  for  an  individual  chemical  or  group  of  chemicals 
are  not  given  unless  there  are  three  or  more  producers  no  one  or  two  of  which  may  be  predomi- 
nant. Moreover,  even  when  there  are  three  or  more  producers,  statistics  are  not  given  if  there 
is  any  possibility  that  their  publication  would  violate  the  statutory  provisions  relating  to  unlaw- 
ful disclosure  of  information  accepted  in  confidence  by  the  Commission. 

Statistics  on  tars  and  tar  crudes  include  data  furnished  directly  to  the  Tariff  Commission  by 
distillers  of  coal  tar,  water-gas  tar,  and  oil-gas  tar,  and  data  furnished  to  the  Division  of  Bitu- 
minous Coal,   U.S.  Bureau  of  Mines,  by  coke-oven  operators.  ,,..',-„  j 

Statistics  on  U.S.  general  imports  in  1965  of  benzenoid  intermediates  and  finished  benzenoid 
products  that  entered  under  schedule  4,  parts  IB  and  1C,  of  the  Tariff  Schedules  of  the  United 
States  are  given  in  the  appendix.  , 

Information  on  synonymous  names  of  organic  chemicals  included  in  this  report  may  be  found 
in  the  SOCMA  Handbook:    Commercial  Organic  Chemical  Names,     recently  published  by  the  Chemical  AD- 
stracts  Service  of  the  American  Chemical  Society,  or  in  the  Colour  Index  (2d  edition),  published  in 
1956  by  the  Society  of  Dyers  and  Colourists. 


2  Sec.  5,  U.S.C.  139b  and  sec.  18.  U.S.C.  1905. 


Summary 

Combined  production  of  all  synthetic  organic  chemicals,  tars,  tar  crudes,  and  crude  prod- 
ucts from  petroleum  and  natural  gas  in  1965  was  151,606  million  pounds--an  increase  of  11.7 
percent  over  the  output  in  1964  (see  table  1).  Sales  of  these  materials  in  1965,  which  totaled 
80,204  million  pounds,  valued  at  $9,898  million,  were  10.4  percent  larger  than  in  1964  in  terms 
of  quantity  and  7.1  percent  larger  in  terms  of  value.  These  figures  include  data  on  production 
and  sales  of  chemicals  measured  at  several  successive  steps  in  the  manufacturing  process,  and 
therefore  they  necessarily  contain  some  duplication. 

In  1965,  production  of  all  synthetic  organic  chemicals,  including  cyclic  intermediates  and 
finished  chemical  products,  totaled  88,864  million  pounds,  or  12.9  percent  more  than  the  output 
in  1964  (see  table  1).  Production  of  plastics  and  resin  materials  (11,685  million  pounds)  was   15.7 
percent  larger  in  1965  than  in  1964;  that  of  cyclic  intermediates  (16,865  million  pounds)  was   13.2 
percent  larger;  that  of  plasticizers  (1,073  million  pounds)  was  12.8  percent  larger;  that  of  dyes 
(207  million  pounds)  was  12.4  percent  larger;  and  that  of  pesticides  and  other  organic  agricul- 
tural chemicals  (877  million  pounds)  was   12.1  percent  larger. 

The  output  of  most  other  groups  of  synthetic  organic  chemicals  also  increased  in  1965  com- 
pared with  1964,  with  miscellaneous  chemicals  and  medicinal  chemicals  showing  increases  of 
more  than  10  percent.  Production  of  rubber-processing  chemicals  (252  million  pounds)  was  3.3 
percent  less  in  1965  than  in  1964.  Production  and  sales  statistics  for  surface-active  agents  for 
1965  are  not  comparable  with  those  for  previous  years. 

TABLE  1.  --  Synthetic  organic  chemicals  and  their  raw  materials:  U.S.  production  and  sales,  1964  and  1965 


Increase 

or 
decrease 
(-),    1965 

over 
19641 


Increase, 
1965 
over 
19641 


Increase, 
1965 
over 
19641 


Grand  total2 

Tar 

Tar  crudes 

Crude  products  from  petroleum  and 
natural  gas 

Synthetic  organic  chemicals,  total2 

Intermediates 

Eyes 

Synthetic  organic  pigments 

Medicinal  chemicals 

Flavor  and  perfume  materials 

Plastics  and  resin  materials 

Rubber-processing  chemicals 

ELastomers  (synthetic  rubbers) 

Plasticizers 

Surface-active  agents 

Pesticides  and  other  organic 

agricultural  chemicals 

Miscellaneous  chemicals 


Million 
pounds 
135,716 


Million 
dollars 
9,898 


7,629 
9,547 


78, 678 


8,027 
10,205 


88,864 


5.2 
6.9 


12.9 


3,361 
6,076 


20,465 
42,766 


3,662 
6,332 


23,402 
46, 807 


9.0 
4.2 


34 

131 


9,021 


14, 896 

184 

44 

144 

91 

10, 103 

261 

3,421 

951 

2,119 

783 
45,681 


16,865 

207 

48 

160 

99 

11,685 

252 

3,592 

1,073 

3,170 

877 
50,836 


(3) 


13.2 
12.4 

9.1 
10.7 

9.6 
15.7 
-3.3 

5.0 
12.8 


12.1 
11.3 


6,470 

178 
35 

119 

80 

8,727 

184 
2,958 

905 
1,900 

692 
20, 518 


7,551 

190 

38 

129 

88 

10,053 

194 

3,041 

1,022 

1,698 

764 
22,040 


(3) 


(3) 


10.3 
7.4 


711 
264 

84 
646 

84 
2,120 
123 
810 
188 
350 

427 
2,651 


814 

292 

94 

362 

85 

2,504 

123 

843 

214 

300 

497 
2,890 


6.3 
4.1 


(3) 


(3) 


14.5 

10.7 
11.3 

1.5 

18.1 

.3 

4.1 
14.4 


16.4 
9.0 


Percentages  calculated  from  figures  rounded  to  thousands. 

Because  of  rounding,  figures  may  not  add  to  the  totals  shown. 

Data  for  1965  are  not  comparable  with  those  for  1964;  for  details  see  the  appropriate  tables. 


PART  I.  PRODUCTION  AND  SALES  OF  TARS,  TAR  CRUDES,  AND 
CRUDES  DERIVED  FROM  PETROLEUM  AND  NATURAL  GAS 

Tars 

Coal  tar  is  produced  chiefly  by  the  steel  industry  as  a  byproduct  of  the  manufacture  of  coke; 
water-gas  tar  and  oil-gas  tar  are  produced  by  the  fuel-gas  industry.  Production  of  coal  tar, 
therefore,  depends  on  the  demand  for  steel;  production  of  water-gas  tar  and  oil-gas  tar  reflects 
the  consumption  of  manufactured  gas  for  industrial  and  household  use.  Water-gas  and  oil-gas 
tars  have  properties  intermediate  between  those  of  petroleum  asphalts  and  coal  tars.  Petroleum 
asphalts  are  not  usually  considered  to  be  raw  materials  for  chemicals. 

The  quantity  of  tar  produced  from  coal  in  the  United  States  in  1 965  was  803  million  gallons, 
or  5.2  percent  more  than  the  763  million  gallons  produced  in  1964.  U.S.  production  of  water-gas 
tar  and  oil-gas  tar  was  not  reported  to  the  Commission  for  1964  or  1965;  production  of  these 
tars  amounted  to  19  million  gallons  in  1962,  the  last  year  for  which  production  was  reported  to 
the  Tariff  Commission. 

Total  consumption  of  tar  in  1965  amounted  to  766  million  gallons,  of  which  616  million  gal- 
lons  was  consumed  by  distillation,   123  million  gallons  as  fuel,  and  27  million  gallons  in  mis- 
cellaneous uses. 

TABLE  2.  — Tar;   U.S.  production  and  consumption,  1964  and  1965 

[in  thousands  of  gallons] 


PRODUCTION 

Coal  tar  from  coke-oven  byproduct  plants,   total1 

CONSUMPTION 

Total 

Tar  consumed  by  distillation,    total 

Coal  tar  distilled  or  topped  by  coke-oven  operators1 

Coal  tar,   water-gas  tar,    and  oil-gas  tar  distilled  by  producers  and  tar 

distillers2 

Tar  consumed  chiefly  as  fuel1 

Tar  consumed  otherwise  than  by  distillation  or  as  fuel,    total 

Coal  tar  consumed  at  coke-oven  plants  for  roads  and  upkeep1 

Coal  tar,  water-gas  tar,  and  oil-gas  tar  processed  at  tar  refineries,  crude  tar 
consumed  for  upkeep  at  such  refineries,  and  tar  consumed  in  making  gas  and  in 
special- purpose  tar  blends 


762,918 


746, 900 


765,946 


601,753 


615,816 


293,957 

307, 796 

127,872 

17,275 


T7T 


16,904 


312,079 
303,737 
122,961 
27,169 


"371 


26,298 


1  Reported  to  the  U.S.  Bureau  of  Vines. 

2  Reported  to  U.S.  Tariff  Commission.  Represents  tar  purchased  from  companies  operating  coke  ovens  and  gas-retort 
plants  and  distilled  by  companies  operating  tar-distillation  plants. 

Tar  Crudes 

Tar  crudes  are  obtained  from  coke-oven  gas  and  by  distilling  coal  tar,  water-gas  tar,  and 
oil- gas  tar.  The  most  important  tar  crudes  are  benzene,  toluene,  xylene,  naphthalene,  and 
creosote  oil.  Some  of  the  products  produced  from  coal  tar  are  identical  with  those  produced  from 
petroleum  and  natural  gas.  Data  for  materials  derived  from  these  latter  sources  are  included, 
for  the  most  part,  in  or  with  the  statistics  for  materials  derived  from  coal  tar,  which  are  shown 
in  tables  3  and  4A.1 


See  also  table  4B,  pt.  Ill,  which  lists  these  products  alphabetically  and  identifies  the  manufacturers. 


2  SYNTHETIC  ORGANIC  CHEMICALS,  1965 

Domestic  production  of  industrial  and  specification  grades  of  benzene  reported  by  coke-oven 
operators  and  petroleum  operators2  in  1965  amounted  to  827  million  gallons-- 13.2  percent  more 
than  the  730  million  gallons  reported  for  1964.   These  statistics  include  data  for  benzene  pro- 
duced from  light  oil  and  petroleum.  Sales  of  benzene  by  coke-oven  operators  and  petroleum  op- 
erators in  1965  amounted  to  511  million  gallons,  valued  at  $123  million,  compared  with  464  mil- 
lion gallons,  valued  at  $104  million,  in  1964.  In  1965  the  output  of  toluene2  (including  material 
produced  for  use  in  blending  in  aviation  fuel)  amounted  to  549  million  gallons-- 10.9  percent  more 
than  the  495  million  gallons  reported  for  1964.  Sales  of  toluene  in  1965  were  325  million  gallons, 
valued  at  $54  million,  compared  with  261  million  gallons,  valued  at  $44  million,  in  1964.  The 
output  of  xylene2  in  1965  (including  that  produced  for  blending  in  motor  fuels)  was  340  million 
gallons,  compared  with  343  million  gallons  in  1964.  About  98  percent  of  the  340  million  gallons 
of  xylene  produced  in  1965  was  obtained  from  petroleum  sources. 

Production  of  crude  naphthalene  in  1965  (including  347  million  pounds  of  petroleum-derived 
naphthalene)  amounted  to  811  million  pounds,  compared  with  740  million  pounds  in  1964.  In  1965 
the  output  of  creosote  oil  for  wood  preservation  was   124  million  gallons  (100-percent  creosote 
basis),  compared  with  113  million  gallons  in  1964.  Production  of  road  tar  and  tar  (crude  and  re- 
fined) for  other  uses  in  1965  was  85  million  gallons,  compared  with  76  million  gallons  in  1964. 


TABLE  3.  --Tar  and  tar  crudes  .■  Summary  of  U.S.  production  of  specified  products,  average  1950-54, 

annual  1964  and  1965 

[Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published 
or  where  no  data  were  reported] 


quantity 


Average 
1950-54 


Increase,  or 
decrease  (-) 


1965  over 
1950-54 


1965  over 
1964 


Tar1 

Benzene : 2 

Tar  distillers3 

Coke-oven  operators 

Petroleum  operators 

Total - 

Toluene: 

Tar  distillers 

Coke-oven  operators 

Petroleum  operators 

Total 

Xylene: 

Tar  distillers 

Coke-oven  operators 

Petroleum  operators 

Total — 

Naphthalene,  crude: 

Solidifying  at  less  than  79°  C.5  — 
Petroleum  naphthalene,  all  grades- 
Total 


,000  gal- 
,000  gal- 
,000  gal- 
,000  gal- 

,000  gal- 
,000  gal- 
,000  gal- 
,000  gal- 

,000  gal- 
,000  gal- 
,000  gal- 
,000  gal- 

,000  lb— 
,000  lb— 
,000  lb- 


Creosote  oil   (Dead  oil)6 1,000 


876,070 

41,389 
163,356 
46,635 


7,497 
32,981 
80,725 


1,373 

9,028 

78, 188 


8,589 
307,537 


307,537 
109, 946 


118,  944 
611, 294 


802,738 


121,917 
704, 993 


730,238 


25,521 
469,519 


826,910 


24,816 
524,013 


7,119 

'336,079 


343,198 


425,690 
314,664 


548, 829 


6,741 
1 333,063 


463,980 
346, 620 


810, 600 


-25.4 
1,411.7 


-24.8 
549.1 


-25.3 
326.0 


283.6 


163.6 
1.0 


2.5 
15.3 
13.2 


-.9 
-1.0 

9.0 
10.2 
9.5 


Includes  data  for  oil-gas,   water-gas,    and  gas-retort  tar  reported  to  the  American  Gas   Association  for  1950-54 
only,    and  for  coal  tar  reported  to  the  Division  of  Bituminous  Coal,    U.S.    Bureau  of  Mines. 

2  Includes  data  for  motor-grade  benzene  in  1950-54.    Production  in  recent  years  has  been  negligible. 

3  Includes  data  for  benzene  produced  from  imported  crude  light  oil. 

*  Includes  data  for  material  produced  for  use  in  blending  motor  fuels.   Statistics  are  not  comparable  with  monthly 
figures,   which  included  some  o-xylene  now  shown  on  table  7A. 

5  Figures  include  production  by  tar  distillers  and  coke-oven  operators  and  represent  combined  data  for  the  com- 
mercial grades  of  naphthalene  to  avoid  disclosure  of  the  operations  of  individual  companies.  Because  of  conversion 
between  grades,    the  figures  may  include  some  duplication. 

6  Includes  data  for  creosote  oil  produced  by  tar  distillers  and  coke-oven  operators  and  used  only  in  wood  preserv- 
ing.  Data  for  production  of  creosote  oil  in  coal-tar  solution  have  been  excluded  because  the  figures  for  1950-54 
are  not  comparable  with  the  figures  for  1964  and  1965.    Production  figures  for  1950-54  are  for  the  distillate  sold  or 
consumed  as  such,   and  for  1964  and  1965  the  production  of  the  distillate  is  on  a  100-percent-creosote  basis. 


Statistics  on  production  and  sales  of  benzene,  toluene,  and  xylene  by  tar  distillers  cannot  be  shown  because  publication  would  reveal  the 
operations  of  individual  companies. 


TAR  CRUDES 
TABLE  4A. --  Tar  crudes.-  U.S.  production  and  sales,  1965 

[Listed  below  are  all  tar  crudes  for  which  any  reported  data  on  production  or  sales  may  be  published.    (Leaders  are 
used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were  reported.) 
Table  4B  in  pt.    Ill   lists  separately  all  products  for  which  data  on  production  or  sales  were  reported  and  iden- 
tifies the  manufacturers  reporting  to  the  U.S.   Tariff  Commission] 


of 
quantity 


Quantity 


Unit 
value1 


Crude  light  oil:      Coke-oven  operators 

Intermediate   light  oil:      Coke-oven  operators 

Light-oil  distillates: 
Benzene,    specification  and  industrial  grades, 

total2  3 -■ 

Coke-oven  operators 

Petroleum  operators 

Toluene,  all  grades,  total2  3 

Coke-oven  operators 

Petroleum  operators 

Xylene,  total2  3 

Coke-oven  operators 

Petroleum  operators 

Solvent  naphtha,  total 

Tar  distillers 

Coke-oven  operators 

Other  light-oil  distillates:  Coke-oven  operators- 
Naphthalene,  crude  (tar  distillers  and  coke-oven 

operators) ,  total* 

Solidifying  at— 

Less  than  74°  C 

74°  C.  to  less  than  79°  C 

Crude  tar- acid  oils: 

Tar  distillers 

Coke-oven  operators 

Creosote  oil  (Dead  oil)  (tar  distillers  and  coke- 
oven  operators)  (100$  creosote  basis),  total5 — 

Distillate  as  such  ( 100$  creosote  basis) 

Creosote  content  of  coal-tar  solution  (100$ 

creosote  basis) 

All  other  distillate  products7 

Tar,  road,  and  tar  ( crude  and  refined)  for  other 

uses8 

Pitch  of  tar: 

Hard  (water  softening  point  above  160°  F. ) 

Other9 


1,000  gal- 
1,000  gal- 


1,000  gal— 

1,000  gal— 

1,000  gal— 

1,000  gal— 

1,000  gal— 

1,000  gal— 

1,000  gal— 

1,000  gal— 

1,000  gal— 

1,000  gal— 

1,000  gal— 

1,000  gal— 

1,000  gal— 


1,000  lb— 
1,000  lb— 


1,000  gal- 
1,000  gal- 


1,000  gal— 

1,000  gal— 

1,000  gal— 

1,000  gal— 

1,000  gal— 

1,000  tons- 

1,000  tons- 


262,701 
4,939 


826,910 

121,917 

704, 993 

548,829 

24,816 

524,013 

339,804 

6,741 

333,063 

10,016 

4,596 

5,420 

7,995 


463,980 


69,537 
1,815 


510,842 

127,449 

383,393 

324,517 

25,087 

299,430 

201,743 

6,913 

194,830 

7,992 

3,41/4 

4,578 


1,000 
dollars 
9,441 
183 


123,282 

29,652 

93,630 

53,882 

4,622 

49,260 

36,734 

1,523 

35,211 

1,622 

753 

869 

448 


$0.14 
.10 


.24 
.23 
.24 
.17 
.18 
.16 
.18 
.22 
.18 
.20 
.22 
.19 
.09 


81,856 
382, 124 


321 
28,027 


123,602 


111,087 

12,515 

31,445 

84,941 

916 
1,088 


76,963 


317 
28,635 


107,452 


95,927 
11,525 


79,818 


594 
487 


1A3 
4,365 


22,868 


19,268 
3,600 


11,896 


22,638 
16,753 


.20 
.31 


38.11 
34.40 


1  Unit  value  per  gallon,  or  ton,  as  specified. 

2  Data  reported  by  tar  distillers  are  not  included  because  publication  would  disclose  the  operations  of  individual 
companies.  Production  of  toluene  and  xylene  by  tar  distillers  decreased  in  1965,  compared  with  1964;  production  of 
benzene  increased.  The  annual  production  statistics  for  petroleum  operators  on  benzene,  toluene,  and  xylene  are  not 
comparable  with  the  combined  monthly  production  figures,  due  to  fiscal  year  revisions. 

3  Includes  data  for  material  produced  for  use  in  blending  motor  fuels. 

*  Statistics  represent  combined  data  for  the  commercial  grades  of  naphthalene.  Because  of  conversion  of  naphtha- 
lene from  one  grade  to  another,  the  figures  may  include  some  duplication. 

5  Statistics  include  only  data  for  creosote  oil  sold  for,  or  used  in,  wood  preserving.  In  1965,  production  of 
creosote  in  coal-tar  solution  (100$  solution  basis)  amounted  to  21,360  thousand  gallons;  sales  were  19,635  thousand 
gallons,  valued  at  3,600  thousand  dollars,  with  a  unit  value  of  $0.18  per  gallon. 

6  Includes  value  of  coal  tar  used  in  preparing  creosote  in  coal-tar  solution. 

7  Includes  data  for  pyridine  crude  bases,  crude  cresylic  acid,  dry  distilled  tar  acid,  and  neutral  oils  produced 
by  tar  distillers,  and  for  crude  sodium  phenolate  produced  by  coke-oven  operators. 

8  Tar  (crude  and  refined)  for  other  uses  includes  data  on  tar  used  for  paint,  pipe  covering,  saturating,  and 
other  uses. 

9  Includes  soft  and  medium  pitch  of  tar  (water  softening  points  less  than  110°  F. ,  and  110°  F.  to  160°  F.  ASTM 
D61-24),  pitch  of  tar  coke,  and  pitch  emulsion. 

Note. — Statistics  for  materials  produced  in  coke  and  gas- retort  ovens  are  compiled  by  the  Division  of  Bituminous 
Coal,  U.S.  Bureau  of  Mines,  Department  of  the  Interior.  Statistics  for  materials  produced  in  tar  and  petroleum 
refineries  are  compiled  by  the  U.S.  Tariff  Commission. 


4  SYNTHETIC  ORGANIC  CHEMICALS,  1965 

Some  of  the  products  included  in  the  statistics  in  table  4A  are  derived  from  other  products 
for  which  data  are  also  included  in  the  table.  The  statistics,  therefore,  involve  considerable 
duplication,  and  for  this  reason  no  group  totals  or  grand  totals  are  given.  It  is  estimated  that 
after  duplication  has  been  eliminated  insofar  as  possible  the  net  value  of  the  output  of  these 
products  and  of  tar  burned  as  fuel  was  $500  million  in  1965,  compared  with  $460  million  in  1964 
and  $406  million  in  1963. 

Crude  Products  From  Petroleum  and  Natural  Gas  for  Chemical  Conversion 

Crude  products  that  are  derived  from  petroleum  and  natural  gas  are  related  to  the  inter- 
mediates and  finished  products  made  from  such  crudes  in  much  the  same  way  that  crude  prod- 
ucts derived  from  the  distillation  of  coal  tar  are  related  to  their  intermediates  and  finished 
products.  Many  of  the  crude  products  derived  from  petroleum  are  identical  with  those  derived 
from  coal  tar  (e.g.,  benzene,  toluene,  and  xylene).  Considerable  duplication  exists  in  the  statis- 
tics on  the  production  and  sales  of  petroleum  crudes  because  some  of  these  crude  chemicals 
are  converted  to  other  crude  products  derived  from  petroleum  and  because  data  on  some  pro- 
duction and  sales  are  reported  at  successive  stages  in  the  conversion  processes  (see  table  5A3). 
Notwithstanding  these  duplications,  the  statistics  are  sufficiently  accurate  to  indicate  trends  in 
the  industry  and  to  serve  as  a  basis  for  general  comparison.  Many  of  the  crude  products  for 
which  data  are  included  in  the  statistics  may  be  used  either  as  fuel  or  as  basic  materials  from 
which  to  derive  other  chemicals,  depending  on  prevailing  economic  conditions.  In  this  report, 
every  effort  has  been  made  to  exclude  data  on  materials  that  are  used  as  fuel.  However,  data 
are  included  on  toluene  and  xylene  which  are  not  used  directly  as  fuel  but  in  blending  aviation 
and  motor- grade  gasolines. 

TABLE  ^A..— Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion:  U.S.  production 

and  sales,  1965 

[Listed  below  are  the  crude  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  any  reported 
data  on  production  or  sales  may  be  published.    (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence 
and  may  not  be  published  or  where  no  data  were  reported.)   Table  5B  in  pt.    Ill  lists  separately  all  products  from 
petroleum  and  natural  gas  for  chemical  conversion  for  which  data  on  production  or  sales  were  reported   and  identi- 
fies the  manufacturer  of  each  ] 


Production 


Quantity 


Unit 
valued- 


Grand  total 

ARQMATICS  AND  NAPHTHENES2 
Total 

Alkyl  aromatics,   distillates,   and  solvents — 

Benzene  (1°    and  2°),    total 

Benzene,   1° 

Benzene,   2° 

Naphthalene,   all  grades 

Naphthenic  acids 

Toluene,    all  grades,   total 

Nitration  grade,   1° 

Pure  commercial  grade,   2° 

Solvent  grade,   90$ 

All  other3 — 

Xylenes,  mixed,  total 

3° - 

All  other3 

All  other  aromatics  and  naphthenes* 

See  footnotes  at  end  of  table. 


1,000 
pounds 
44,509,671 


1,000 
pounds 
23,402,442 


1,000 
dollar. 


pound 


$0,030 


214,832 


1,878,248 
5,202,849 


4,139,487 
1,063,362 


346, 620 
24,365 


3,809,575 


1,877,189 
2,829,440 


21,873 
93,630 


.025 
.012 
.033 


269, 845 
17,217 


10,643 
1,805 


2,375,829 
177,635 
124,855 

1,131,256 

2,401,383 


.039 
.105 


■  023 
.023 


503, 673 
1,404,723 


444,864 
1,956,519 


100,350 


535J25D 

969,463 


10, 532 
35,211 


11,625 
23,586 


.025 
TTJ2T 
.024 


See  also  table  5B,  pt,  HI,  which  lists  these  products  alphabetically  and  identifies  the  manufacturers. 


CRUDE  PRODUCTS  FROM  PETROLEUM  AND  NATURAL  GAS 


TABLE  5A.  - 


-  Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion.-  U.  S.  production 
and  sales,  i965--Continued 


Unit 
value1 


ALIPHATIC  HYDROCARBONS 

Total 

C2  hydrocarbons,   total 

Acetylene5 

Ethane 

Ethylene 

C3  hydrocarbons,   total 

Propane 

Propylene 

C4  hydrocarbons,    total 

1,3-Butadiene,   grade  for  rubbers   (elastomers) 

Butadiene  and  butylene  fractions 

n-Butane 

1-Butene  and  2-butene  mixture6 

Isobutane 

Isobutylene 

All  other7 

C5  hydrocarbons8 

All  other  aliphatic  hydrocarbons  and  derivatives,  total. 

Alpha  olefins9 

Diisobutylene  (Diisobutene) 

Heptenes,  mixed 

Nonene  (Tripropylene) 

Polybutene1" 

Tetrapropylene-- 

Hydrocarbon  derivatives11 

All  other12 


30,746,281 


14,757,498 


465,208 
1, 546, 660 
9,569,885 


4,231,286 
3,740,835 


7,182,182 


2,685,359 
486, 177 
1,879,011 
1,067,303 
516,726 
270,866 
276,740 

456,523 

3,553,702 


125,536 
33,151 
279, 751 
244, 257 
240,482 
462,255 
32, 847 
2,135,423 


663,130 
2,714,873 


3,135,301 
1, 884, 641 


4,568,676 


1,670,936 
102,213 
1,022,371 
1,080,716 
285,391 
167, 671 
239,378 

95,927 


115,065 
26,689 
172,782 
161, 009 
202, 974 
359,033 
20,405 
636,993 


1,000 

dollars 

489,856 


5,781 

109,816 


29,774 
39, 567 


237, 143 


171,807 
4,251 
12,295 
30,630 
3,962 
8,448 
5,750 

2,938 
64,837 


5,489 
1,942 
6,483 
4,755 

12,892 
9,102 
6,101 

18,073 


$0,033 


.009 
.040 


.014 
.009 
.021 


.103 
.042 
.012 
.028 
.014 
.050 
.024 


.038 
.048 
.073 
.038 
.030 
.064 
.025 
.299 
.028 


Calculated  from  rounded  figures. 

2  The  chemical  raw  materials  designated  as  aromatics  are  in  some  cases  identical  with  those  obtained  from  the  dis- 
tillation of  coal  tar.  However,  the  statistics  given  in  the  table  above  relate  only  to  such  materials  as  are  derived 
from  petroleum  and  natural  gas.  Statistics  on  aromatic  chemicals  from  all  sources  are  given  in  table  4A,  "Tar  Crudes. ' 

3  Includes  toluene  and  xylene  used  as  solvents,  as  well  as  that  which  is  blended  in  aviation  and  motor  gasolines. 
*  Includes  data  for  90-percent  benzene,  crude  cresylic  acid,  sodium  cresylate,  sodium  carbolate  and  phenate,  and 

miscellaneous  cyclic  hydrocarbons. 

5  Production  figures  on  acetylene  from  calcium  carbide  for  chemical  synthesis  are  collected  by  the  U. S.  Bureau  of 
the  Census. 

6  The  statistics  represent  principally  the  butene  content  of  crude  refinery  gases  from  which  butadiene  is  manu- 
factured. 

7  Includes  data  for  1-butene,  2-butene,  mixed  butylenes,  and  mixed  olefins. 

8  Includes  data  for  isoprene,  pentanes,  pentenes,  and  C5  hydrocarbon  mixtures. 

9  Includes  data  for  the  following  molecular  weight  ranges:  C6-C7,  C8-C10,  C1:L-Ci5,  Bn^   Ci6-C2o- 

10  Includes  compounds  having  a  molecular  weight  of  3,000  or  less. 

11  Includes  data  for  di-tert-butyldisulfide  and  miscellaneous  mercaptans. 

12  Includes  data  for  hexane,   heptane,   methane,   propane-propylene  mixture,   octanes,   1-dodecene,   eicosane,   and  hydro- 
carbon mixtures. 


The  output  of  crude  products  derived  from  petroleum  and  natural  gas  as  a  group  amounted 
to  44,510  million  pounds  in  1965,  or  11.7  percent  more  than  the  39,862  million  pounds  reported 
for  1964.  The  larger  output  in  1965  is  accounted  for  chiefly  by  increased  production  of  benzene, 
toluene,  ethylene,  and  propane.  Sales  of  crude  chemicals  from  petroleum  in  1965  were  23,402 
million  pounds,  valued  at  $705  million,  compared  with  20,465  million  pounds,  valued  at  $619 
million,  in  1964. 

The  output  of  all  aromatic  and  naphthenic  products  amounted  to  13,763  million  pounds  in 
1965,  compared  with  12,574  million  pounds  in  1964.  Sales  in  1965,  which  amountedto  8,645 
million  pounds,  valued  at  $215  million,  were  1,066  million  pounds  larger,  and  valued  at  $35  mil- 
lion more,  than  those  in  1964.  Naphthalene  was  produced  from  petroleum  sources  in  substan- 
tially greater  quantities  in  1965  than  in  1964.   The  output  of  lc  and  2°  benzene  from  petroleum 


6  SYNTHETIC  ORGANIC  CHEMICALS,  1965 

amounted  to  5,203  million  pounds  in  1965--15.3  percent  more  than  the  4,511  million  pounds  pro- 
duced in  1964.  The  output  of  toluene  in  1965  was  3,810  million  pounds--  11.6  percent  more  than 
the  3,413  million  pounds  produced  in  1964.  Production  of  xylene  was  2,401  million  pounds  in  1965, 
compared  with  2,423  million  pounds  in  1964.  These  figures  include  toluene  and  xylene  used  in 
blends  in  aviation  and  motor-grade  gasolines.  The  output  of  naphthenic  acids  amounted  to  24 
million  pounds  in  1965,  compared  with  30  million  pounds  produced  in  1964. 

Production  of  all  aliphatic  hydrocarbons  and  derivatives  from  petroleum  and  natural  gas  was 
30,746  million  pounds  in  1965,  compared  with  27,288  million  pounds  in  1964.  Sales  of  these  prod- 
ucts were  14,757  million  pounds,  valued  at  $490  million,  in  1965,  compared  with  12,887  million 
pounds,  valued  at  $439  million,  in  1964.  The  statistics  on  production  of  acetylene  (table  5 A)  in- 
clude only  acetylene  produced  from  natural  gas  and  used  as  a  raw  material  in  the  production  of 
other  chemicals.  Total  production  of  acetylene  for  chemical  synthesis  is  reported  to  the  U.S. 
Bureau  of  the  Census.  In  1965,  production  of  acetylene  from  all  sources  except  that  produced  by 
railroad  shops,  shipyards,  and  small  establishments  using  portable  generators,  amounted  to 
1,141  million  pounds.  Production  of  ethylene  was  9,570  million  pounds  in  1965,  or  10.7  percent 
more  than  the  8,641  million  pounds  produced  in  1964.  The  output  of  propane  and  propylene  was 
7,972  million  pounds  in  1965--10.3  percent  more  than  the  7,227  million  pounds  produced  in  1964. 
Production  of  1,3 -butadiene,  one  of  the  principal  ingredients  of  S-type  synthetic  rubber,  was 
2,685  million  pounds  in  1965,  compared  with  2,491  million  pounds  in  1964.   The  output  of  1,3-buta- 
diene  in  1965--7.8  percent  more  than  that  in  1964--was  the  largest  on  record. 

The  following  tabulation  shows  the  number  of  companies  that  reported  production  of  organic 
chemical  crudes  in  1965: 

Number 

of 
Chemical   group  companies 

Tar  crudes 14 

Petroleum  crudes 72 


PART  II.     PRODUCTION  AND  SALES  OF  INTERMEDIATES  AND 
FINISHED  SYNTHETIC  ORGANIC  CHEMICALS,   BY  GROUPS 


General 


On  the  basis  of  their  principal  uses,  the  synthetic  organic  chemicals  covered  in  this  report 
are  classified  either  as  intermediates  or  as  finished  products.  Finished  products,  in  turn,  are 
grouped  as  follows:  Dyes,   synthetic  organic  pigments,  medicinal  chemicals,  flavor  and  perfume 
materials,  plastics  and  resin  materials,  rubber-processing  chemicals,  elastomers  (synthetic 
rubbers),  plasticizers,  surface-active  agents,  pesticides  and  other  organic  agricultural  chemi- 
cals, and  miscellaneous  synthetic  organic  chemicals.     Most  of  these  groups  are  further  sub- 
divided, according  to  chemical  classes,  into  cyclic  and  acyclic  compounds.  As  most  of  the  in- 
termediates are  used  in  the  manufacture  of  finished  products,  aggregate  figures  that  cover  both 
intermediates  and  finished  products  necessarily  include  considerable  duplication. 

Total  production  of  synthetic  organic  chemicals  (intermediates  and  finished  products  com- 
bined) in  1965  was  88,864  million  pounds,  or  12.9  percent  more  than  the  output  of  78,678  million 
pounds  reported  for  1964  (see  table  6).  Sales  of  synthetic  organic  chemicals  in  1965  amounted  to 
46,807  million  pounds,  valued  at  $9,021  million,  compared  with  42,766  million  pounds,  valued  at 
$8,458  million,  in  1964.  Production  of  all  cyclic  products  (intermediates  and  finished  products 
combined)  in  1965  totaled  28,229  million  pounds,  or  10.7  percent  more  than  the  25,506  million 
pounds  produced  in  1964.  The  output  of  acyclic  organic  chemicals  in  1965  amounted  to  60,635 
million  pounds--14.0  percent  more  than  the  53,172  million  pounds  reported  for  1964. 


: 


TABLE  6. — Synthetic  organic  chemicals.-  Summary  of  U.S.  production  and  sales  of  intermediates  and  finished 
products,  average  1957-59,  annual  1964  and  1965 

[Production  and  sales  in  thousands  of  pounds;    sales  value  in  thousands  of  dollars] 


Average 
1957-59 


Increase,    or  decrease  (-) 


1965  over 
1957-59 


1965   over 
1964 


Organic  chemicals,   cyclic  and  acyclic, 
grand  total: 

Production 

Sales 

Sales  value 


Cyclic,   total: 

Production 

Sales- --- 

Sales  value — 

Acyclic,   total: 

Production 

Sales 

Sales  value--- 


1.    Inte 


Cycli 


Production — 

Sales 

Sales  value - 


2.   Dyes,   Cycli 


Production — 

Sales 

Sales  value- 


3.  Synthetic  Organic  Pigments,  Cycli 


Production- - 

Sales 

Sales  value - 


45,598,853 

23,744,812 

5 , 743 , 764 


14,381,651 
8,829,037 
2,785,100 

31,217,202 
14,915,775 
2,958,664 


7,343,167 

2,919,264 

481,920 


150,830 
141,731 
182,513 


38,603 
30,215 
58,648 


78,677,699 

42,766,420 

8,457.909 


25.505,853 
15,241,685 
3,890,571 


53,171,846 
27,524,735 
4,567,338 


14,895,573 

6,470,072 

711, 119 


184,387 
178,273 
264,023 


44,053 
35,081 
84,131 


88,864,092 

46,807,057 

9,020,540 


28,229,128 
16,499, 1B9 
3,855,492 


60,634,964 

30,307,868 

5,165,048 


16,865,164 

7,551,210 

814,383 


207, 193 
189,965 
292,284 


48,045 
38,024 
93,635 


94.9 
97.1 
57.0 


94.2 
103.2 
74.6 


129.7 
158.7 
69.0 


37.4 
34.0 
60.1 


24.5 
25~8 
59.7 


12.9 
9.4 


10.7 
8.2 
-.9 


12.4 
6.6 
10.7 


9.1 
8.4 
11.3 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  6. — Synthetic  organic  chemicals:  Summary  of  U.S.  production  and  sales  of  intermediates  and  finished 
products,  average  1957-59,  annual  1964  and  1 965- -Continued 

[Production  and  sales  in  thousands  of  pounds;    sales  value  in  thousands  of  dollars] 


Average 
1957-59 


Increase,    or  decrease  (-) 


1965   over 
1957-59 


4.     Medicinal  Chemicals 

Cyclic: 

Production 

Sales 

Sales  value 

Acyclic : 

Production 

Sales 

Sales  value 

5.  Flavor    and  Perfume  Materials 

Cyclic: 

Production 

Sales 

Sales  value 

Acyclic: 

Production 

Sales 

Sales  value 

6.  Plastics   and  Resin  Materials 

Cyclic: 

Production 

Sales 

Sales  value 

Acyclic: 

Production 

Sales 

Sales  value 

7.  Rubber -Processing  Chemicals 

Cyclic: 

Production 

Sales 

Sales  value 

Acyclic : 

Production 

Sales 

Sales  value 

«.  Elastomers    (Synthetic  Rubbers) 

Cyclic : 

Production 

Sales 

Sales  value 

Acyclic: 

Production 

Sales 

Sales  value 

9.  Plasticizers 

Cyclic: 

Production 

Sales 

Sales  value 

Acyclic : 

Production 

Sales 

Sales  value 

See  footnote  at  end  of  table. 


70,654 
54,151 
535,297 

31,592 
28,738 
35,660 


27,312 
22,446 
33,903 

19,033 
19,958 
21.912 


2,278,862 

1,900,032 

518,501 

2,628,779 

2,438,853 

864,523 


159,182 
115,704 
74,479 

29,150 
22,127 
1/4,289 


1,938,732 

1,726,757 

404,897 

521,811 
509,262 
199,627 


348,210 

297,423 

83,509 

118,118 
100,984 
38,772 


97,579 

76,946 

612,233 

46,511 
41,732 
33,459 


49,563 
41,235 
56,571 

41,007 
38,802 
27, 163 


3,915,046 

3,256,105 

777,342 

6,188,018 
5,470,616 
1,342,942 


222,461 
161,660 
108,656 

38,095 
22,567 
14,371 


2,332,436 

1,961,181 

450,913 

1,088,782 
996,403 
358,989 


717,624 
689,647 
119,565 

233,784 

215,240 

67,903 


100,040 

72,479 

321,158 

59,480 
56,569 
41,011 


53,223 
44,559 
56,800 

46,001 
43,144 
28,180 


4,452,975 

3,689,722 

873,501 

7,231,900 
6,363,044 
1,630,932 


211,403 
166,21/4 
109,204 

40,542 
27,504 
1/4,189 


2,300,092 

1,897,921 

442,722 

1,291,562 

1,143,242 

400,726 


798,741 
764,736 
133,044 

274,456 
256,887 
81,348 


i1) 
(x) 


t1) 


1A1.7 

116.2 

28.6 


95.4 
94.2 


175.1 
160.9 


32.8 
43.7 
46.6 

39.1 
24.3 


18.6 
9.9 
9.3 

147. 5 
124.5 
100.7 


129.4 
157.1 
59.3 

132.4 

154.4 
109.8 


GENERAL 

TABLE  6,-Syntketic  organic  chemicals:  Summary  of  U.S.  production  and  sales  of  intermediates  and  finished 
products,  average  1957-59,  annual  1964  and  1965 — Continued 

[Production  and  sales  in  thousands  of  pounds;    sales  value  in  thousands  of  dollars] 


Average 
1957-59 


Increase,  or  decrease  (-) 


1965   over 
1957-59 


1965   over 
1964 


10.    Surface-Acti 


Cyclic: 

Production — 

Sales 

Sales  value- 
Acyclic  : 

Production — 

Sales 

Sales  value - 


Organ 

Cyclic : 

Production — 

Sales 

Sales  value - 

Acyclic : 

Production-- 

Sales 

Sales  value- 


Agricultu 


and  Othe 
il  Chemii 


- 


Cyclic : 

Production- 
Sales 

Sales  value- 
Acyclic: 

Production — 

Sales 

Sales  value- 


852,314 
800,432 
127.936 

502,715 
432,135 
113,215 


440,384 
375,627 
150,837 

105,080 
91,938 
49,049 


733,401 
445,252 
132,660 

27,260,924 

11,271,780 

1,621,617 


1,347,809 

1,245,176 

165,132 

770,879 
654,754 
185,010 


584,698 
522,691 
316,556 

198,051 
169,664 
110,555 


1,114,624 
603,618 
224,330 

44,566,719 
19,914,957 
2,426,946 


1,371,320 

877,202 

96,153 

1,799,158 
820,660 
204,035 


682,671 
582,344 
377,858 

194,526 
181,561 
119,208 


1,138,261 
624,813 
244,750 

49,697,339 

21,415,257 

2,645,419 


55.0 
55.0 
150.5 

85.1 
97.5 
143.0 


55.2 
40.3 
84.5 

82.3 

90.0 


16.8 
11.4 
19.4 

-1.8 
7.0 
7.8 


2.1 
3.5 
9.1 

11.5 
7.5 
9.0 


1  Data  for  1965  are  not  comparable  with  those  for  1964;    for  details  see  the  appropriate  tables. 

The   following    tabulation   shows,   by   chemical  groups,  the  number  of  companies  that  reported 
production  in  1965  of  one  or  more  of  the  chemicals  included  in  the  groups  listed  in  table  6: 


Number 
Chemical  group  oj 

comj'atne 

Intermediates 213 

Dyes 53 

Synthetic  organic  pigments 37 

Medicinal  chemicals 111 

Flavor  and  perfume  materials 55 

Plastics  and  resin  materials 320 


Numbe r 
Chemical  group  of 

cvmpanie 
Rubber-processing  chemicals 31 

Elastomers  (synthetic  rubbers) 29 

Plasticlzers 58 

Surface-active  agents 188 

Pesticides  and  other  organic  agricultural  chemicals  85 

Miscellaneous  chemicals 328 


10 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 
Cyclic  Intermediates 


Cyclic  intermediates  are  synthetic  organic  chemicals  derived  principally  from  coal-tar 
crudes  produced  by  destructive  distillation  (pyrolysis)  of  coal  and  from  petroleum  and  natural 
gas.  Most  cyclic  intermediates  are  used  in  the  manufacture  of  more  advanced  synthetic  organic 
chemicals  and  finished  products,   such  as  dyes,  medicinal  chemicals,   elastomers  (synthetic 
rubbers),  pesticides,  and  plastics  and  resin  materials.  Some  intermediates,  however,  are  sold 
as  end  products  without  further  processing.  For  example,  refined  naphthalene  may  be  used  as  a 
raw  material  in  the  manufacture  of  2-naphthol  or  of  other  more  advanced  intermediates,  or  it 
may  be  packaged  and  sold  as  a  moth  repellent  or  as  a  deodorant.  In  general,  the  way  in  which 
the  greater  part  of  the  output  of  a  given  chemical  is  consumed  determines  its  use  classification 
in  this  report.   Table  7A     gives  statistics  on  production  and  sales  of  cyclic  intermediates  in 
1965.  Individual  statistics  given  in  the  table  represent  more  than  85  percent  of  the  total  quantity 
of  intermediates  produced.  Since  many  of  the  intermediates  included  in  the  statistics  represent 
successive  steps  in  production,  the  totals  necessarily  include  considerable  duplication.  In  1965 
nearly  half  of  the  total  output  of  cyclic  intermediates  was  sold;  the  rest  was  consumed  chiefly 
by  the  producing  plants  in  the  manufacture  of  more  advanced  intermediates  and  finished 
products. 

Total  production  of  cyclic  intermediates  in  1 965  —  1 6,865  million  pounds--was  the  largest  on 
record,  and  was   13.2  percent  larger  than  the  output  of  14,896  million  pounds  reported  for   1964. 
The  larger  output  of  cyclic  intermediates  in  1965  was  attributable  to  increased  demand  by  the 
chemical  products  industries,  particularly  those  industries  that  produce  dyes,  pesticides,  plas- 
ticizers,  and  plastics  and  resin  materials.  Sales  of  cyclic  intermediates  in  1965  amounted  to 
7,551  million  pounds,  valued  at  $814  million,  compared  with  6,470  million  pounds,  valued  at  $711 
million,  in  1964.  In  terms  of  quantity,   sales  of  cyclic  intermediates  in  1965  were  16.7  percent 
larger  than  those  in  1964  and  in  terms  of  value,   14.5  percent  larger. 


TABLE  7A. — Cyclic  intermediates :  U.S.  production  and  sales,  1965 

[Listed  below  are  all  cyclic  intermediates   for  which  any  reported  data  on  production  or  sales  may  be  published. 

(Leaders   are  used  where  the  reported  data  are   accepted  in  confidence  and  may  not  be  published  or  where  no  data  were 
reported.;   Table  7B  in  pt.   Ill  lists  alphabetically  all  cyclic   intermediates  for  which  data  on  production  or  sales 
were  reported  and  identifies  the  manufacturer  of  each  J 


Production 


Quantity 


Unit 
value1 


Total 

Acetanilide,   tech 

H-Acetylsulfanilyl  chloride 

Alkylbenzenes2 

4'  -Aminoacetanilide   (Acetyl-p-phenylenediaraine) 

5-Amino-2-(p-aminoanilino)benzenesulfonic  acid 

2-(p-Aminoanilino)-5-nitrobenzenesulfonic   acid 

1-Aminoanthraquinone  and  salt 

2-Aminoanthraquinone  and  salt 

6-Amino-3,4'-azodibenzenesulfonic  acid 

1 -Amino -4-benzamidoanthraqui none 

l-Amino-5-benzamidoanthraquinone 

7-(p-Aminobenzamido)-4-hydroxy-2-naphthalenesulfonic  acid 

2-Amino-p-benzenedisulfonic  acid  [S03H=l] 

l-Amino-4-bromo-9,10-dihydro-9,10-dioxo-2-anthracenesulfonic  acid 

and  sodium  salt 

l-Amino-2-bromo-4-hydroxyanthraquinone 

l-Amino-2-bromo-4-p-toluidinoanthraquinone 

l-Amino-5-chloroanthraquinone 

o-(3-Amino-4-chlorobenzoyl)benzoic  acid 

See  footnotes  at  end  of  table. 


1.000 
pounds 

16,865,164 


3,672 

3,313 

624,894 

602 

21 

47 

1,547 

1,146 

59 

95 

125 


187 
204 
28 
105 
116 


1.000 

pounds 

7,551,210 


1.000 
dollars 

814,383 


583,634 


55,537 


1  See  also  table  7B,  pt.  Ill,  which  lists  these  products  alphabetically  and  identifies  the  manufacturers,  and  table  23  in  the  appendix,  which 
shows  imports  of  intermediates  and  related  products  during  1964  and  1965. 


CYCLIC  INTERMEDIATES 
TABLE  7A.  —  Cyclic  intermediates ;  U.S.  production  and  sales,  1965 — Continued 


Production 


Unit 
value1 


3-Amino-5-chloro-2-hydroxybenzenesulfonic  acid 

2-Amino-5-chloro-p-toluenesulfonic  acid  [S03H=l] 

6-Amino-4-chloro-m-toluenesulfonic  acid  [S03H>l] 

l-Amino-2,4-dibromoanthraquinone 

l-Amino-9,10-dihydro-9,10-dioxo-4-p-toluenesulfonamido-2- 

anthracenesulfonic  acid,  sodium  salt 

4-Amino-5-hydroxy-2,7-naphthalenedisulfonic  acid  (H  acid), 

monosodium  salt 

4-Amino-3-hydroxy-l-naphthalenesulfonie  acid  (1,2,4-acid) 

6-Amino-4-hydroxy-2-naphthalenesulfonic  acid  (Gamma  acid), 

sodium  salt 

7-Amino-4-hydroxy-2-naphthalenesulfonic  acid  (J  acid),  sodium  salt- 

N-(4-Aiidno-3-methoxy-l-anthraquinonyl)-p-toluene  sulfonamide 

4'-Amino-N-methylacetanilide 

2-Amino-l,5-naphthalenedisulfonic  acid 

3-Amino-l,5-naphthalenedisulfonic  acid  (C  acid) 

6-Amino-l,3-naphthalenedisulfonie  acid  (Amino  I  acid) 

7-Amino-l,3-naphthalenedisulfonic  acid  (Amino  G  acid) 

4-Amino-l-naphthalenesulfonic  acid  (Naphthionic  acid) 

5-Amino-2-naphthalenesulfonic  acid  (1,6-Cleve's  acid) 

5(and  8)-Amino-2-naphthalenesulfonic  acid  (Cleve's  acid,  mixed) 

6-Amino-2-naphthalenesulfonic  acid  (Broenner's  acid) 

8-Amino-l-naphthalenesulfonic  acid  (Peri  acid) 

8-Amino-2-naphthalenesulfonic  acid  (1,7-Cleve's  acid) 

8-Amino-2-naphthol 

2-Amino-5-nitrobenzenesulfonic  acid  [S03H=l] 

2-Amino-4-nitrophenol 

3'-Aminooxanilic  acid 

p-[(p-Aminophenyl)azo]benzenesulfonic  acid 

4-Amino-m-toluenesulfonic  acid  [  S03H=l] 

6-Amino-m-toluenesulfonic  acid  [S03H=1] 

5-Amino-2-p-toluidinobenzenesulfonic  acid 

Aniline  (Aniline  oil) 

7-Anilino-4-hydroxy-2-naphthalenesulfonic  acid  (Phenyl  J  acid) 

Anilinomethanesulfonic  acid  and  salt 

8-Anilino-l-naphthalenesulfonic  acid  (Phenyl  peri  acid) 

o-Anisidine • 

o-Anisidinomethanesulfonic  acid 

Anthranilic  acid   (o-Aminobenzoic  acid) 

Anthra[l,  9-cd]pyrazol-6(2H)-one   (Pyrazoleanthrone) 

N,N'-(l,5-Anthraquinonylene)dianthranilic  acid 

4',4'"-AzobisL4-biphenylcarboxylic  acid] 

Benzaldehyde,  tech 

l-Benzamido-5-chloroanthraquinone 

7H-Benz[de]anthracen-7-one   ( Benzanthrone ) 

Benzidine  hydrochloride  and  sulfate 

Benzoic  acid,  tech 

o-Benzoylbenzoic  acid 

[3,3'-Bianthra[l,9-cd]pyrazole]-6,6'-(2H,2'H)dione   (Pyrazole- 
anthrone yellow) 

[4,4'-Bi-7H-benz[de]anthracen]-7,7'-dione 

l,4-Bis[l-anthraquinonylamino]anthraquinone 

4,4'-Bis[dimethylamino]benzophenone   (Mlchler's  ketone) 

3-Bromo-7H-benz [de] anthracen-7-one   (3-Bromobenzanthrone) 

l-Bromo-4-(methylamino)anthraquinone 

p-tert-Butylphenol 

1-Chloroanthraquinone 

2-Chloroanthraquinone 

Chlorobenzene,  mono-  

o-(p-Chlorobenzoyl)benzoic  acid 

l-Chloro-2,4-dinitrobenzene   (Dinitrochlorobenzene) 

6-Chlorometanilic  acid 

l-Chloro-2-methylanthraquinone 

2-Chloro-4-nitroaniline_  (o-Chloro-p-nitroaniline) 

4-Chloro-2-nitroaniline   (p-Chloro-o-nitroaniline) 


1.000 
pounds 
13 
1,585 

1,047 
370 


4,723 
1,602 


22 

60 

212 

1,187 

1,123 

145 

136 

229 

135 

790 

165 

65 

48 

137 

19 

196 

266 

207 

31 

195,547 

43 

277 

417 

1,585 

347 

712 

16 

26 

36 

3,979 

115 

2,256 

1,610 

16,190 


107 
239 
43 

184 

1,250 

546,292 

1,864 

8,107 

24 

140 

448 

461 


1,000 
pounds 


1,000 
dollars 


$1.19 


2,929 
184 


2,817 


76,277 


4,168 


1,160 
8,461 


15,276 


82,159 

362 

1,659 


.96 

.74 

1.60 


,959 


1,723 


1,183 
1,522 


3,152 


5,071 
232 
277 


1.02 
.18 


.64 
.17 


See  footnotes  at  end  of  table. 


12  SYNTHETIC  ORGANIC  CHEMICALS.  1965 

TABLE  TA.— Cyclic  intermediates.-  U.S.  production  and  sales ,  1965- -Continued 


Production 


l-Chloro-5-nitroanthraquinone 

l-Chloro-8-nitroanthraquinone 

l-Chloro-2-nitrobenzene  (Chloro-o-nitrobenzene ) - 
l-Chloro-4-nitrobenzene  (Chloro-p-nitrobenzene ) - 

4-Chlora-3-nitrobenzenesulfonamide 

2-Chloro-5-nitrobenzenesulfonic  acid 

4-Chloro-3-nitrobenzenesulf onyl  chloride 

o-(4-Chloro-3-nitrobenzoyl)benzoic  acid 

(p-Chlorophenyl)acetonitrile 

K -Chlorotoluene  (Benzyl  chloride) 

4-Chloro-o-toluidine  [NH2=l]  and  hydrochloride-- 
5-Chloro-o-toluidine  [NH2=1]  and  hydrochloride - - 

N-[(5-Chloro-o-tolyl)azo]sarcosine 

[(4-Chloro-o-tolyl)thio] acetic  acid 


Cresols,  total3 

m-,  o-,  and  p-Cresols 

(m,p)-Cresol  (from  coal  tar  and  petroleum) - 
(o,m,p)-Cresol4 

Cresylic  acid,  refined,  total3 

From  coal  tar 

From  petroleum 


Cumene 

Cyclohexane 

Cyclohexanol 

Cyclohexanone 

Cyelohexylamine 

1,4-Diaminoanthraquinone 

1,5-Diaminoanthraquinone 

2,6-Diaminoanthraquinone 

l,4-Diamino-2,3-dihydroanthraquinone 

4,4'-Diamino-2,2'-stilbenedisulfonic  acid 

4,5'-Dibenzamido-l,l'-iminodianthraquinone 

1,5-Dibenzoylnaphthalene 

3,9-Dibromo-7H-benz[de]anthracen-7-one 

2,5-Dichloroaniline  and  hydrochloride  [NH2=l] 

1,5-Dichloroanthraquinone 

o-Dichlorobenzene 

p-Dichlorobenzene 

3,3'-Dichlorobenzidine  base  and  salts 

2 , 5-Dichloro-4- ( 3-methyl-5-oxo-2-pyrazolin-l-yl ) benzenesulf onic 


acid- 


2,6-Dichloro-4-nltroanillne 

l,4-Dichloro-2-nitrobenzene  (Nitro-p-dichlorobenzene) 

2,5-ffl.chlorosulfanilie  acid  [s03H=l] 

p-(Diethylamino)benzaldehyde 

N,N-Diethylaniline 

9,10-Dihydro-l,4-dihydroxy-9,10-dioxo-2-anthracenesulfonic  acid 
(2-Quinizarinsulfonic  acid) 

9,10-Dihydro-9,10-dioxo-l,5-anthracenedisulfonic  acid  and  disodium 
salt 

9,10-Dihydro-9,10-dioxo-l,8-anthracenedisulfonic  acid, 

potassium  salt ; 

9,10-Dihydro-9,10-dioxo-2,6-anthraeenedisulfonic  acid  and  salt 

9,10-Dihydro-9,10-dioxo-l-anthracenesulfonic  acid  and  salt 

9,10-Dihydro-5-nitro-9,10-dioxo-l-anthracenesulfonic   acid 

9,10-Dihydro-l-nltro-9,10-dloxo-2-anthroic  acid 

1,4-Dihydroxyanthraqulnone   (Quinizarin) 

1 , 5-Dihydroxyanthraquinone    (Anthrarufin) 

1,8-Dihydroxyanthraquinone  (Qirysazin) 

2,6-Dihydroxyanthraquinone  (Anthraflavic  acid) 

l,8-Dihydroxy-4,5-dinitroanthraquinone   (4, 5-Dinitrochrysazin ) 

16,17-Dihydroxyviolanthrone  (Dihydroxydibenzanthrone) 


l.nnn 

pounds 

117 

56 

28,290 

109,757 

275 

89 

248 

U5 

34 

62,000 

62 

507 

181 


71,168 


innn 

pounds 


10,536 


32,533 
24,022 
14,613 

50,890 


21,969 
28,921 

663,009 
1,700,245 

321,651 

13,651 

64 

64 

179 

398 

4,784 

142 

231 

330 

123 

199 

41,115 

65,835 

2,677 

292 
259 
705 
110 
30 
1,721 


1,226 

412 
369 

3,066 
135 
29 

1,962 
233 
181 
9 
461 
337 


72,019 


29,268 
27,715 
15,036 

56,966 


21,998 

34,  < 


1,474,742 

2,663 

12,269 

5,528 


37,199 
66,546 
2,331 


159 
1,732 


8,636 
3,032 
1,949 

6,192 


2,587 
3,605 


60,166 

679 

3,152 

1,386 


4,239 
5,789 
2,851 


See  footnotes  at  end  of  table. 


CYCLIC  INTERMEDIATES 
TABLE  1A. --Cyclic  intermediates.-  U.S.  production  and  sales ,  1965--Continued 


m-Dimethoxybenzene 

3,3'-Dimethoxybenzidine 

16,17-Dimethoxyviolanthrone 

N,N-Dimethylaniline 

N,N-Dimethyrbenzylamine 

2,2'-Dlmethyl-l,l'-bianthraquinone 

N,N-Dimethyl-p-nitrosoaniline 

p-(2,4-Dinitroanilino)phenol 

2,4-Dinitrophenol,  tech 

4,4'-Dinitrostirbene-2,2'-disulfonie  acid 

1,4-Di-p-toluidinoanthraquinone 

Divinylbenzene 

p-Dodecylphenol 

N-Ethylaniline,  refined 

Ethylbenzene5 

N-Ethyl-N-phenylbenzylamine 

o-Formylbenzenesulfonic  acid  (o-Sulfobenzaldehyde) 

p-Hydrazinobenzenesulfonic  acid 

p-Hydroxybenzenesulfonic  aoid  (l-Phenol-4-sulfonic  acid) 

p-Hydroxybenzoic  acid,  methyl  ester 

p-Hydroxybenzoic  acid,  propyl  ester 

4-Hydroxymetanilamide 

4-Hydroxymetanilic  acid 

3-Hydroxy-2,7-naphthalenedisulfonic  acid,  disodium  salt- 
6-Hydroxy-2-naphthalenesulfonic  acid  (Schaeffer's  acid) 

sodium  salt 

3-Hydroxy-2-naphthoic  acid  (B.O.N.) 

N-(7-Hydroxy-l-naphthyl)acetamide 

l,l'-Iminobis ,4-aminoanthraquinone] 

1,1'  -Iminobis  . 5-benzamidoanthraquinone] 

7,7'-Iminobis  ;4-hydroxy-2-naphthalenesulfonic  acid]- 

1,1' -Iminobis[4-nitroanthraquinone] 

l,l'-Iminodianthraquinone  (l,l'-Dianthrimide) 


Isocyanic  acid  derivatives,  total 

Diphenylmethane  4,4'-diisocyanate  (MDI) 

Toluene  2,4-  and  2,6-diisocyanate  (80/20  mixture) 
All  other 


4,4'-Isopropylidenediphenol  (Bisphenol  A) 

Isoviolanthrone  ( Isodibenzanthrone ) 

Leuco  quinizarin  (1,4,9,10-Anthratetrol)- 


o-Mercaptobenzoic  acid 

Metanilic  acid  (m-Aminobenzenesulfonic  acid) 

l-(Methylamino)anthraquinone 

4,4'-Methylenebis[N,N-dimethylaniline]  (Methane  base) 

4,4-'-Methylenedianiline 

p-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic  acid 

4-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-m-toluenesulfonic  acid  [so3H=l]  ■ 

3-Methyl-l-phenyl-2-pyrazolin-5-one  (Developer  Z) 

a-Jfethylstyrene 

Naphthalene,  solidifying  at  79°C.  or  above,  refined  from  domestic 


crude- 

1,4,5,8-Naphthalenetetracarboxylic  acid 

1-Naphthol  (a  -Naphthol) 

Naphth[l,2-d] [l,2,3]oxadiazole-5-sulfonic  acid 

p-Nitroaniline 

4-Nitro-o-anisidine  [NH2=l] 

5-Nitro-o-anisidine  [NH2=l] 

Nitrobenzene 

m-Nltrobenzenesulfonic  acid  and  sodium  salt 

3-Nitro-l,5-naphthalenedisulfonic  acid 

7(and  8)-Nitronaphth[l,2-d]  [l,2,3]oxadiazole-5-sulfonic  acid- 
p-Nitrophenol  and  sodium  salt 


Production 


1.000 

567 

133 

11,041 

69 

90 

36 

935 

6,449 

202 

2,748 

11,021 

761 

3,022,730 

838 

271 

175 

6,310 

246 

102 

119 

106 

1,715 

348 
3,951 

24 
138 
45 
21 
103 
145 

184,262 

4,817 

146,578 

32,867 

97,197 

44 

88 

73,201 

17 

917 

175 

1,206 

1,086 

203 

6 

281 

13,553 

4,731 
57 

1,250 

12,478 

103 

108 

280,341 

2,293 

223 

1,084 

19,856 


Quantity 


1.000 
pounds 


6,003 
81 


1,762 


385 
580,332 


6,202 
256 
74 


776 
205 


162,739 


Unit 
value1 


138,152 
24,587 


56,487 


59,285 


190 
536 


216 
8,480 


801 
6,883 


11,506 
2,397 


11,273 


1,000 
dollars 


1,296 

111 


1,403 


189 
23,614 


956 
375 
164 


703 
164 


61,648 


49,024 
12,624 


11,753 
15,064 


425 
303 


353 
941 


484 
2,988 


1,051 
1,023 


4,292 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 
TABLE  7A. — Cyclic  intermediates :  U.S.  production  and  sales ,  1965 — Continued 


Quantity 


Unit 

value1 


5-Nitro-o-toluenesulf  onic  acid  [  S03H=l] ' 

3-Nitro-p-toluenesulfonic   acid  [  S03H=l] 

2-Nitro-p-toluidine  [NH2=l] 

16-Nitroviolanthrone 

Nonylphenol 

l-[(7-0xo-7H-benz[de]  anthracen-3-yl)  amino] anthraquinone 

l,l'-[(7-0xo-7H-benz[de]anthracen-3,9-ylene)diimino]dianthraquinone 

5-0xo-l-phenyl-2-pyrazoline-3-carboxylic  acid,  ethyl  ester 

5-0xo-l-(p-sulfophenyl)-2-pyrazoline-3-carboxylic  acid 

(Pyrazolone  T) 

Phenol,  grand  total3 

Natural,  total 

From  coal  tar 

From  petroleum 

Synthetic,  total 

From  cumene 

Other  synthetic 


Phenylacetic  acid  and  salts 

p-Phenylazoaniline  (p-Aminoazobenzene)  and  hydrochloride 

l-Phenyl-l,2-propanedione,  2-oxime  (Isonitrosopropiophenone)- 
Phthalic  anhydride 

Picolines,  total6 

2-Picoline  (a  -Picoline) 

Other  picolines 


Piperidine 

Propiophenone 

8,16-Pyranthrenedione 

2°-Pyridine6 

Quinaldine 

Salicylaldehyde 

Salicylic  acid,  tech 

Styrene,  all  grades 

Terephthalic  acid,  dimethyl  ester 

1,4,5,8-Tetrachloroanthraquinone 

1,4,5,8-Tetrahydroxyanthraquinone,  leuco  derivative 

Toluene-2,4-diamine  (4-m-Tolylenediamine) 

o(and  p) -Toluenesulfonic  acid 

4-(o-Tolylazo)-o-toluidine 

l,3,3-Trimethyl-A2'a-indolineaeetaldehyde 

l,3,3-Trimethyl-2-methyleneindoline 

7,7 '-Ureylenebis[4-hydroxy-2-naphthalenesulfonic  acid]  (J  acid  urea) 
Violanthrone  (Dibenzanthrone) 


o-Xylene 

p-Xylene 

Xylenols7 

All  other  cyclic  intermediates- 


1,000 

pounds 

8,429 

73 

1,257 

88 

61,001 

375 

637 


1,229,113 


55,672 

41,055 

U,617 

1,173,441 

560,040 

613,401 

4,056 

166 

248 

608,318 

4,779 


1,000 
pounds 


822 

22,190 


532,704 


2,332 
2,447 

434 

533 

19 

6,488 

38 

2,540 

22,763 

2,864,306 

544,578 

89 

127 

54,411 

5,868 

467 

141 

326 

437 

569 

351,369 

396,333 

14,585 

2,321,922 


52,532 

36,241 

16,291 

480,172 

224,040 

256,132 

3,290 


336,289 
2,493 


1,000 
dollars 


2,424 


50,222 


812 
1,681 


5,751 

1,839 

5,138 

1,248,222 

218,991 


5,183 


343,755 

375,248 

12,440 

990,168 


47f 

3,198 

1,690 

45,334 

20,682 

24,652 

1,285 


28,364 
1,011 


~278~ 
733 


3,313 

1,879 

1,786 

95,190 

52,474 


9,121 

32,714 

1,478 

216,479 


.10 
.09 
.10 


.58 
1.02 


.22 


1  Calculated  from  rounded  figures. 

Principally  straight-chain  dodecylbenzene  and  tridecylbenzene,  but  includes  lesser  amounts  of  branched-chain  com- 
pounds and  other  alkylbenzenes. 

3  Includes  data  for  coke  ovens  and  gas-retort  ovens,  reported  to  the  Division  of  Bituminous  Coal,  U.S.  Bureau  of 
Mines,  Department  of  the  Interior,  and  for  tar  and  petroleum  refineries  and  other  producers,  reported  to  the  U.S. 
Tariff  Commission. 

4  Includes  some  mixed  cresols.  Figures  include  (o,m,p)-eresol  from  coal  tar  and  from  petroleum. 

5  Does  not  include  ethylbenzene  produced  and  consumed  in  continuous-process  styrene  manufacture. 

6  Includes  data  for  coke  ovens  and  gas-retort  ovens,  reported  to  the  Division  of  Bituminous  Coal,  U.S.  Bureau  of 
Mines,  Department  of  the  Interior,  and  for  tar  refineries  and  other  producers,  reported  to  the  U.S.  Tariff  Commission. 

7  Includes  low-  and  medium-boiling  xylenols  and  xylenols  unclassified  as  to  boiling  point. 


DYES  15 

In  1965,  production  of  ethylbenzene    exceeded  3  billion  pounds  for  the  first  time,  reaching 
3,023  million  pounds.  Styrene  production  in  1965  was  2,864  million  pounds,  an  11.4-percent  in- 
crease over  the  2,571  million  pounds  reported  for  1964.  Ethylbenzene  is  used  almost  entirely  in 
the  manufacture  of  styrene,  which,  in  turn,  is  used  almost  entirely  in  the  manufacture  of  plastics 
materials  and  synthetic  rubber.  Other  intermediates  whose  production   exceeded   one   billion 
pounds  in  1965  were  cyclohexane  at  1,700  million  pounds,  representing  a  24.4-percent  increase 
over  the  1,367  million  pounds  reported  for  1964,  and  phenol  at  1,229  million  pounds,  represent- 
ing  a    10.4-percent   increase   over   the    1964  production  of  1,113  million  pounds.  The  output  of 
other  large-volume  intermediates  in  1965  compared  with  production  in  1964  was  as  follows: 
Cumene,  663  million  pounds  (20.6  percent  larger);    phthalic  anhydride,  608  million  pounds  (9.1 
percent  larger);  monochlorobenzene,  546  million  pounds,  (1.6  percent  larger);  terephthalic  acid, 
dimethyl  ester,  545  million  pounds  (53.1  percent  larger);  p-xylene,  396  million  pounds  (34.0  per- 
cent larger);  and  isocyanates,  184  million  pounds  (33.6  percent  larger). 

Dyes 

Dyes  produced  in  the  United  States  are  all  derived  in  whole  or  in  part  from  cyclic  inter- 
mediates. Approximately  two-thirds  of  the  dyes  consumed  in  the  United  States  are  used  by  the 
textile  industry  to  dye  natural  and  synthetic  fibers  or  fabrics;  about  one-sixth  are  used  for  color- 
ing paper;  and  the  rest  are  used  chiefly  in  the  production  of  organic  pigments  and  in  the  dyeing  of 
leather  and  plastics.  Of  the  several  thousand  different  synthetic  dyes  that  are  known,  more  than 
two  thousand  are  manufactured  by  one  or  more  domestic  producers.  The  large  number  of  dyes 
results  from  the  many  different  types  of  materials  to  which  dyes  are  applied,  the  different  con- 
ditions of  service  for  which  dyes  are  required,  and  the  costs  that  a  particular  use  can  bear. 
Dyes  are  sold  as  pastes,  powders,  lumps,  and  solutions;  concentrations  vary  from  6  percent  to 
100  percent.  The  concentration,  form,  and  purity  of  a  dye  are  determined  largely  by  the  use  for 
which  it  is  intended. 

Table  8A2   shows  U.S.  production  and  sales  of  dyes  in  1965,  total  and  by  individual  dyes, 
using  the  Colour  Index    classification  and  terminology. 

Total  domestic  production  of  dyes  in  1965  amounted  to  207  million  pounds,  or  12.4  percent 
more  than  the  184  million  pounds  in  1964.  Sales  of  dyes  in  1965  amounted  to  190  million  pounds, 
valued  at  $292  million,  compared  with  178  million  pounds,  valued  at  $264  million,  in    1964.  In 
terms  of  quantity,  sales  of  dyes  in  1965  were  6.6  percent  larger  than  in  1964,  and  in  terms  of 
value,   10.7  percent  larger.  The  average  unit  value  of  sales  of  all  dyes  in  1965  was  $1.54  a  pound, 
compared  with  $1.48  a  pound  in  1964. 

For  many  important  individual  low-  and  medium-priced  dyes  for  which  statistics  are  given 
in  table  8A,  production  was  larger  in  1965  than  in  1964.  The  output  of  Vat  Green  8  was  2.0  mil- 
lion pounds  in  1965,  or  78.8  percent  more  than  the  1.1  million  pounds  produced  in  1964;  that  of 
Vat  Black  25  was  4.5  million  pounds,  or  44.7  percent  more  than  the  3.1  million  pounds  produced 
in  1964.  Other  important  dyes  whose  output  was  substantially  larger  in  1965  than  in  1964  were 
Disperse  Yellow  3  (38.3  percent),  Vat  Green  3  (34.3  percent).  Vat  Yellow  2  (33.0  percent),  Sulfur 
Black  1  (31.9  percent),  Direct  Blue  2  (23.0  percent),  and  Mordant  Black  11  (17.4  percent). 

On  the  other  hand,  the  output  of  a  few  important  dyes  was  smaller  in  1965  than  in  1964.  Pro- 
duction of  Vat  Green  1  was  3.8  million  pounds  in  1965,  or  36.4  percent  less  than  the  5.9  million 
pounds  produced  in  1964;  that  of  Leuco  Sulfur  Black  2  was  2.2  million  pounds,  or  20.5  percent 
less  than  the  2.8  million  pounds  produced  in  1964.  The  output  of  Acid  Black  1  was  9.7  percent 
smaller  in  1965  than  in  1964,  and  that  of  Vat  Blue  6  was  4.4  percent  smaller. 


2  See  also  table  8B,  pt.  Ill,  which  lists  these  products  and  identifies  the  manufacturers,  and  the  appendix  (table  23),  which  shows  imports 
of  dyes  during  the  years  1964-65. 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 
TABLE  8A.  --Benzenoid  dyes.-  U.S.  production  and  sales ,  1965 


[Listed  below  are  all  benzenoid  dyes  for  which  any  reported  data  on  production  or  sales  may  be  published.    (Leaders 
are  used  where  the  reported  data  are  accepted   in  confidence  and  may  not  be  published  or  where  no  data  were 
reported.)   Table  8B  in  pt.    Ill  lists  all  dyes  for  which  data  on  production  or  sales  were  reported  and  identifies 
the  manufacturer  of  each] 


Dye 


Production 


Grand  total 

ACID  DYES 

Total 

Acid  yellow  dyes,  total 

Acid  Yellow  3 

Acid  Yellow  11 

Acid  Yellow  17 ■ 

Acid  Yellow  23 

Acid  Yellow  36— - — 

Acid  Yellow  40 

Acid  Yellow  42 

Acid  Yellow  44 

Acid  Yellow  54 

Acid  Yellow  73 

Acid  Yellow  99 

All  other 

Acid  orange  dyes,  total 

Acid  Orange  1 

Acid  Orange  7 

Acid  Orange  8 

Acid  Orange  ID 

Acid  Orange  24 

Acid  Orange  60 

Acid  Orange  64 

All  other 

Acid  red  dyes,  total 

Acid  Red  1 

Acid  Red  4 

Acid  Red  1A 

Acid  Red  18 

Acid  Red  26 

Acid  Red  37 

Acid  Red  73 

Acid  Red  85 

Acid  Red  87 

Acid  Red  88 • 

Acid  Red  89 

Acid  Red  99 - ■ 

Acid  Red  114 - ~ • 

Acid  Red  115 

Acid  Red  137- — ■ 

Acid  Red  151 • 

Acid  Red  182 

Acid  Red  186 

All  other 

Acid  violet  dyes,  total 

Acid  Violet  1 

Acid  Violet  3— ■ 

Acid  Violet  7 

Acid  Violet  12 

Acid  Violet  49 

All  other 


1,000 
pounds 
207, 193 


20,395 


3,375 


46 
461 
387 
239 
140 


89 

246 


1,633 
2,793 


77 
698 
315 
265 
502 
60 
50 
826 

3,489 


654 
95 
100 
129 
112 
40 
250 
162 


173 
58 


142 
118 


1,171 


67 
71 

104 
73 
77 

102 


1,000 
pounds 
189,965 


1,000 
dollars 
292,284 


18,666 


2,961 


3T 

46 

472 

334 

241 

135 

52 

28 

65 

72 

70 

1,415 

2,789 


T8~ 
717 
354 
294 
516 
47 


2,973 


592 
114 
116 
114 
110 
42 
249 
160 


171 
66 
39 

136 

106 
41 
34 

601 


58 
81 

122 
62 
72 

107 


39,025 


6,743 


111 

96 

1,011 

728 

361 

374 

85 

82 

141 

163 

157 

3,434 

4,271 


100 
672 
404 
384 
693 
120 
168 
1,730 

6,022 


621 

207 
159 
135 
135 
126 
547 
288 
183 
202 

71 
397 
138 

64 
429 
230 
131 
103 
1,856 

944 


83 

1A2 
166 
94 
160 
299 


See  footnotes  at  end  of  table. 


DYES 


TABLE  8A.  --Benzenoid  dyes ;  U.S.  production  and  sales ,  1 965- -Continued 


Eye 


Quantity 


ACID  DYES— Continued 

Acid  blue  dyes,  total 

Acid  Blue  7 

Acid  Blue  9 

Acid  Blue  25 — 

Acid  Blue  40 

Acid  Blue  41 

Acid  Blue  43 

Acid  Blue  45 

Acid  Blue  62 

Acid  Blue  78 

Acid  Blue  90 

Acid  Blue  113 

Acid  Blue  118 

Acid  Blue  158  and  158A — 

All  other 

Acid  green  dyes,  total 

Acid  Green  3 

Acid  Green  9 

Acid  Green  12 

Acid  Green  16 

Acid  Green  20 

Acid  Green  25 

All  other 

Acid  brown  dyes,  total 

Acid  Brown  1A 

All  other 

Acid  black  dyes,  total 

Acid  Black  1 

Acid  Black  24 

Acid  Black  48 — — 

Acid  Black  107— - 

All  other 

AZOIC  DIES  AND  COMPONENTS 

Azoic  Compositions 

Total 

Azoic  Yellow  1 

Azoic  Yellow  3 

Azoic  Orange  3 

Azoic  red  dyes,    total 

Azoic  Red  1 

Azoic  Red  2 

Azoic  Red  6 

Azoic  Red  16 

All  other 

Azoic  Blue  2 

Azoic  Blue  3 

Azoic  Brown  9 

Azoic  black  dyes 

All  other  azoic  compositions 


1,000 
pounds 
3,695 


748 
121 


212 
1,343 


1,075 


206 
25 
15 
81 
38 
364 
346 


306 
489 


4,679 


1,247 

1D1 

12 

289 

3,030 


2,100 


202 

67 

304 


115 
1A9 
823 
218 


1,000 
pounds 
3,275 


1,000 
dollars 


74 
24 

538 

26 

39 

9 

351 

188 
1,812 


179 
23 
13 
65 
38 
260 
312 


270 
467 


4,539 


1,178 
120 
25 
187 

3,029 


2,043 


200 
64 

301 
6 
87 

13 
113 
146 
790 
216 


9,582 


647 

59 
247 
181 
1,722 
166 
257 

91 
529 

424 
5,061 

2,431 


211 
101 

54 
245 

73 
782 
965 

1,683 


385 
1,298 


7,349 


1,436 
210 
130 
522 

5,051 


3,968 


94 
4 
91 

1,159 


348 
124 
500 
17 
170 

26 

185 

479 

1,403 

527 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 
TABLE  8A.  --Benzenoid  dyes.-  U.S.  production  and  sales,  1 965- -Continued 


Production 


Quantity 


AZOIC  DYES  AND  COMPONENTS— Continued 

Azoic  Diazo  Components ,   Bases 
(Fast  Color  Bases) 

Total- - - 

Azoic  Diazo  Component  4,  base 

Azoic  Diazo  Component  9,  base 

Azoic  Diazo  Component  10,  base 

Azoic  Diazo  Component  12,  base 

Azoic  Diazo  Component  13,  base 

Azoic  Diazo  Component  32,  base 

Azoic  Diazo  Component  48,  base 

All  other  azoic  diazo  components,  bases 

Azoic  Diazo  Components ,  Salts 
(Fast  Color  Salts) 

Total - 

Azoic  Diazo  Component  1,  salt 

Azoic  Diazo  Component  2,  salt 

Azoic  Diazo  Component  3,  salt 

Azoic  Diazo  Component  5,  salt 

Azoic  Diazo  Component  6,  salt 

Azoic  Diazo  Component  8,  salt 

Azoic  Diazo  Component  9,  salt 

Azoic  Diazo  Component  ID,  salt 

Azoic  Diazo  Component  11,  salt 

Azoic  Diazo  Component  12,  salt 

Azoic  Diazo  Component  13,  salt -r -. 

Azoic  Diazo  Component  28,  salt 

Azoic  Diazo  Component  48,  salt 

Azoic  Diazo  Component  49,  salt 

All  other  azoic  diazo  components,  salts 

Azoic  Coupling  Components 
(Naphthol  AS  and  Derivatives) 

Total 

Azoic  Coupling  Component  2 

Azoic  Coupling  Component  3 

Azoic  Coupling  Component  4 

Azoic  Coupling  Component  5 

Azoic  Coupling  Component  7 

Azoic  Coupling  Component  8 

Azoic  Coupling  Component  11 

Azoic  Coupling  Component  14 

Azoic  Coupling  Component  17 

Azoic  Coupling  Component  18 

Azoic  Coupling  Component  19 

Azoic  Coupling  Component  20 

Azoic  Coupling  Component  21 

Azoic  Coupling  Component  29 

All  other  azoic  coupling  components 


1,000 
pounds 
1,558 


107 
54 
71 
237 
377 
307 


2,835 


3,172 


1,310 


1,000 
dollars 
2,057 


46 
224 
341 
276 


2,646 


2,429 


151 
266 
429 
427 
79 
623 


2,683 


296 

309 

200 

357 

327 

373 

40 

43 

153 

123 

125 

435 

384 

246 

92 

89 

132 

42 

72 

103 

102 

111 

421 

371 

254 

340 

338 

364 

90 

86 

96 

39 

38 

110 

464 

352 

495 

271 

39 

14 

44 

53 

23 

46 

ID 

28 

791 

715 

1,454 

19 

22 

21 

70 

215 

141 

276 

176 

817 

616 

736 

7 

6 

35 

137 

92 

198 

112 

69 

150 

32 

24 

55 

481 

698 

1,577 

See  footnotes  at  end  of  table. 


DYES 


19 


TABLE  8A.  — Benzenoid  dyes :  U.S.  production  and  sales ,  1965 — Continued 


Eye 


Quantity 


BASIC  DYES 

Total - 

Basic  yellow  dyes,    total 

Basic  Yellow  2 

Basic  Yellow  11 

Basic  Yellow  13 

All  other 

Basic  orange  dyes,  total 

Basic  Orange  1 

Basic  Orange  2 

Basic  Orange  21 

All  other 

Basic  red  dyes,  total 

Basic  Red  14- 

All  other 

Basic  violet  dyes,  total 

Basic  Violet  1 

Basic  Violet  3 

Basic  Violet  4 

Basic  Violet  16 

All  other 

Basic  blue  dyes,  total 

Basic  Blue  1 

Basic  Blue  5 

Basic  Blue  7 

Basic  Blue  9 

Basic  Blue  26 

All  other 

Basic  Green  1 

Basic  Green  4 

Basic  Brown  1 

Basic  Brown  4 

All  other  basic  dyes 

DIRECT  DYES 

Total- - — 

Direct  yellow  dyes,  total 

Direct  Yellow  4 

Direct  Yellow  5~- 

Direct  Yellow  6 

Direct  Yellow  11 

Direct  Yellow  12 

Direct  Yellow  26 

Direct  Yellow  28 

Direct  Yellow  44 

Direct  Yellow  50 

Direct  Yellow  59 

Direct  Yellow  84 

Direct  Yellow  105 

Direct  Yellow  106 

All  other 


1,000 
pounds 
10,573 


1,923 


605 
482 


1,353 


339 

543 
358 
113 

1,213 


436 
777 


2,991 


983 

38 

130 

1,840 

1,569 


25 
22 

474 

65 

983 

87 
594 
254 
541 

48 


36,080 


6,719 


"463" 

75 

752 

974 

388 

'  345 
403 
398 
327 
467 
188 
691 

1,443 


1,000 
pounds 
9,553 


1,794 


614 
431 


333 

549 

341 

94 

1,055 


351 

704 


2,750 


932 
1,129 


109 
549 


128 
299 


95 

584 
195 
505 
48 


33,663 


6,214 


422 
105 
703 
865 
393 
6 
300 
395 
365 
122 
398 
220 
592 
1,328 


1,000 
dollars 
23,907 


5,419 


1, 

1,717 

326 

2,088 

2,416 


355 

646 

1,082 

333 

3,428 


1,097 
2,331 


5,582 


1,198 

2,045 

97 

388 

1,854 

4,154 


105 

396 

699 

173 

2,781 

300 
1,506 
290 
669 
143 


50,970 


10,972 


~§97~ 

302 

1,101 

979 

926 

15 

568 

671 

745 

183 

567 

536 

1,008 

2,474 


See  footnotes  at  end  of  table. 


20  SYNTHETIC  ORGANIC  CHEMICALS,  1965 

TABLE  8A.  --Benzenoid  dyes;  U.S.  production  and  sales,  1965 — Continued 


Dye 


Production 


DIRECT  DYES— Continued 

Direct  orange  dyes,  total 

Direct  Orange  1 

Direct  Orange  8 

Direct  Orange  15 

Direct  Orange  26 

Direct  Orange  34 

Direct  Orange  37 

Direct  Orange  39 

Direct  Orange  72 

Direct  Orange  73 

Direct  Orange  81 

Direct  Orange  102 

All  other 

Direct  red  dyes,  total 

Direct  Red  1 

Direct  Red  2 

Direct  Red  4 

Direct  Red  10 

Direct  Red  13 

Direct  Red  16 

Direct  Red  23 

Direct  Red  24 

Direct  Red  26 

Direct  Red  28 

Direct  Red  31 

Direct  Red  37 

Direct  Red  39 

Direct  Red  75 

Direct  Red  79 

Direct  Red  80 

Direct  Red  81 

Direct  Red  83 

Direct  Red  122 

Direct  Red  127  and  127A 

Direct  Red  149— - -- 

Direct  Red  153 

All  other 

Direct  violet  dyes,  total 

Direct  Violet  1 

Direct  Violet  9 

Direct  Violet  51- 

All  other 

Direct  blue  dyes,  total 

Direct  Blue  1 

Direct  Blue  2 

Direct  Blue  6 

Direct  Blue  8 

Direct  Blue  14 

Direct  Blue  15 

Direct  Blue  22 

Direct  Blue  24 

Direct  Blue  25 

Direct  Blue  71 

Direct  Blue  76 

Direct  Blue  78 

Direct  Blue  80 

Direct  Blue  86 

Direct  Blue  98 

Direct  Blue  120  and  120A 

Direct  Blue  126 

Direct  Blue  151 

All  other 

See  footnotes  at  end  of  table. 


1,901 


164 

201 
68 
137 
63 
132 
344 
34 
57 
165 
500 

4,519 


275 

472 

30 

20 

190 

65 

259 

464 

172 

198 

47 

75 

72 

301 
587 
385 
113 


26 

699 


112 
8,141 


431 

2,248 

571 

30 

129 

62 

24 

43 

39 

80 

574 

124 

438 

1,211 

118 

178 

142 

1,699 


1,000 
pounds 
1,829 


1,000 
dollars 
4,044 


170 
184 


121 
319 
58 
57 
185 
488 

4,198 


~T7S 
463 

17 
165 

64 
227 
412 
178 
203 


28 
284 
513 
344 
115 

36 


84 

7 

60 

7,81/; 


407 

2,177 

527 

43 

113 

65 

22 

38 

54 

86 

583 

108 

404 

1,1D3 

125 

189 

175 

30 

1,565 


36 
228 
222 

87 
272 
153 
250 
685 
231 
178 
474 
1,228 

9,102 


"359" 
803 

28 
264 
124 
553 
810 
451 
277 

95 
219 
158 

99 
684 
901 
872 
179 
178 


1,661 
506 


203 

48 

232 

11,437 


731 

1,928 

267 

80 

102 

111 

40 

53 

146 

252 

1,106 

303 

650 

1,712 

235 

397 

462 

40 

2,822 


DYES 
TABLE  8A. — Benzenoid  dyes  •  U.S.  production  and  sales,  1965 — Continued 


Dye 


Quantity 


DIRECT  DYES— Continued 

Direct  green  dyes,    total 

Direct  Green  1 

Direct  Green  6 

Direct  Green  8 

Direct  Green  12 

Direct  Green  38 

All  other 

Direct  brown  dyes,  total 

Direct  Brown  1  and  1A 

Direct  Brown  2 

Direct  Brown  6 

Direct  Brown  31 

Direct  Brown  74 

Direct  Bro»n  95 

Direct  Brown  111 

Direct  Brown  154 

All  other 

Direct  black  dyes,  total 

Direct  Black  4 

Direct  Black  9 

Direct  Black  19 

Direct  Black  22 

Direct  Black  38 

Direct  Black  51 

Direct  Black  80 

All  other . 

DISPERSE  DYES 

Total 

Disperse  yellow  dyes,  total 

Disperse  Yellow  3 

Disperse  Yellow  5 

Disperse  Yellow  23 

Disperse  Yellow  33 

Disperse  Yellow  34 

Disperse  Yellow  42 

Disperse  Yellow  54 

All  other 

Disperse  orange  dyes,  total 

Disperse  Orange  3 

Disperse  Orange  5 

Disperse  Orange  17- 

All  other 

Disperse  red  dyes,  total 

Disperse  Red  1 

Disperse  Red  5 

Disperse  Red  11 

Disperse  Red  13 

Disperse  Red  17 

Disperse  Red  60 

All  other 

Disperse  Violet  1 

Disperse  Violet  4 

Disperse  Violet  27 


1,396 


275 
456 

37 
29 


1,883 


266 

200 
84 

102 
56 

560 

369 
246 

11,364 


234 

64 

208 

903 

6,297 

56 

2,148 

1,454 


15,514 


2,707 


1,290 
56 

229 
202 
201 
185 
544 


104 

98 

179 

707 

2,178 


273 
112 
42 
36 
127 


1,000 
pounds 
1,1*9 


201 

471 

32 

1A 
431 

1,756 


227 

184 

103 

93 

62 

498 

61 

322 

206 

10,541 


194 

48 

224 

738 

5,833 

65 

2,087 

1,352 


13,522 


2,484 


1,245 
44 
74 
21B 
171 
189 
155 
388 

801 


115 
523 


1,919 


232 
69 
30 
28 

124 

80 

1,356 

33 
20 
161 


1.000 
dollars 
2,610 


267 

559 
41 

50 
1,693 

2,496 


T0B~ 
283 
119 
270 
93 
437 
217 
313 
456 

9,803 


199 
68 

322 

637 
4,487 

207 
1,850 
2,033 


32,878 


4,822 


2,040 
150 
197 
348 
295 
330 
565 
897 

1,503 


159 

170 
178 
996 

5,899 


379 

85 

128 

38 

170 

291 

4,808 

111 

58 

238 


See  footnotes  at  end  of  table. 


22 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 
TABLE  8A.  --Benzenoid  dyes :  U.S.  production  and  sales,  1965- -Continued 


Dye 


Quantity 


DISPERSE  DYES— Continued 

Disperse  "blue  dyes,  total 

Disperse  Blue  1 

Disperse  Blue  3 

Disperse  Blue  7 

Disperse  Blue  64 

All  other 

Disperse  "black  dyes,  total 

Disperse  Black  1 

Disperse  Black  9 

All  other 

All  other  disperse  dyes 

FIBER-REACTIVE  DYES 

Fiber- reactive  dyes,  total 

Reactive  yellow  dyes 

Reactive  red  dyes 

Reactive  blue  dyes 

All  other  reactive  dyes 

FLUORESCENT  BRIGHTENING  AGENTS 

Total- — — 

Fluorescent  Brightening  Agent  9 

Fluorescent  Brightening  Agent  28 

All  other  fluorescent  brightening  agents 

FOOD,  DRUG,  AND  COSMETIC  COLORS 

Total 

Food,   Drug,    and  Cosmetic  Dyes 

Total 

FD&C  Blue  No.    1 

FD&C  Red  No.   2 — 

FDScC  Red  No.  3 - - 

FDScC  Red  No.   4— — 

FDScC  Yellow  No.    5 

FD&C  Yellow  No.   6- 

All  other  food,  drug,  and  cosmetic  dyes 


6,296 


Drug 


nd  Cosmetic 
and  Cosm 


and  Exte 
■tic  Dyes 


jl  Drug 


348 
1,928 

319 

101 

3,600 

2,723 


344 
2,379 

361 

1,586 


631 
679 


19,420 


3,749 
1,515 
W-,  156 


2,923 


2,681 


Total — - 

D&C  Red  No.    12 — - — 

D&C  Red  No.    19 — 

D&C  Red  No.   21 - 

D&C  Red  No.    36 - 

All  other  drug  and  cosmetic  and  external  drug  and 
cosmetic  dyes 


1,000 
pounds 
5,559 


250 

1,576 

301 

1A4 

3,288 

2,266 


275 

1,572 

419 


1,558 


271 
337 
613 
337 


18,284 


3,588 
1,568 
13,128 


2,736 


2,493 


1,000 
dollars 
16,700 


1,024 

2,520 

2,041 

464 

10,651 

2,1 


336 

1,607 

945 


6,744 


1,023 
1,223 
3,320 
1,178 


34,516 


5,675 
2,427 
26,414 


10,238 


8,971 


85 

52 

596 

819 

820 

2,223 

111 

90 

1,278 

21 

56 

241 

770 

682 

2,127 

782 

700 

1,949 

93 

93 

557 

1,267 


130 
31 


1,051 


See  footnotes  at  end  of  table. 


DYES 


23 


TABLE  8A.- -Benzenoid  dyes.-  U.S.  production  and  sales ,  i365--Continued 


Eye 


MORDANT  DYES 

Total— - 

Mordant  yellow  dyes,  total 

Mordant  Yellow  1 

Mordant  Yellow  8 

All  other 

Mordant  orange  dyes,  total 

Mordant  Orange  1 

All  other 

Mordant  red  dyes,  total 

Mordant  Red  7 

All  other 

Mordant  blue  dyes,  total 

Mordant  Blue  1 

All  other 

Mordant  brown  dyes,  total 

Mordant  Brown  1 

Mordant  Brown  40 

All  other 

Mordant  black  dyes,  total 

Mordant  Black  3 

Mordant  Black  5 

Mordant  Black  11 

Mordant  Black  13 

Mordant  Black  17 

Mordant  Black  38 

All  other 

All  other  mordant  dyes 

SOLVENT  DYES 

Total 

Solvent  yellow  dyes,  total 

Solvent  Yellow  2 — 

Solvent  Yellow  3 

Solvent  Yellow  U 

Solvent  Yellow  47 

All  other 

Solvent  orange  dyes,  total 

Solvent  Orange  2 

Solvent  Orange  3 

Solvent  Orange  7 

All  other 

Solvent  red  dyes,  total 

Solvent  Red  24 

Solvent  Red  26 

Solvent  Red  49 

All  other 

Solvent  violet  dyes,  total 

Solvent  Violet  8 

All  other 

Solvent  Blue  38 

See  footnotes  at  end  of  table. 


Quantity 


31 
136 


117 
90 


3,715 


2,412 

61 

970 


9,837 


1,020 


38 
42 

663 
30 

247 


110 
244 


1,478 


362 
290 
46 
780 


323 
161 


4,246 


43 

12 

187 


43 

101 


23 
180 


3,288 


18 

19 

2,303 

25 

672 

17 

234 

16 


43 
42 

548 
42 

220 


4 

21 

116 

228 

1,362 


284 
272 
40 
766 


1,000 
dollars 
5,706 


23 
336 


205 
279 


169 
135 


137 

58 

434 

3,582 


33 
2,311 

72 
675 

52 
4W 


15,351 


543 
198 

1,004 


7 

45 

164 

475 

2,640 


540 

498 

258 

1,344 

982 


24 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 
TABLE  8A. — Benzenoid  dyes.-  U.S.  production  and  sales,  1965 — Continued 


Dye 


Production 


Quantity 


SOLVENT  DYES — Continued 

Solvent  green  dyes,  total 

Solvent  Green  3 

All  other 

Solvent  Drown  dyes 

All  other  solvent  dyes 

SULFUR  DYES2 

Total 

Sulfur  Blue  7 

Sulfur  Blue  11 

Sulfur  Blue  15 

Sulfur  Brown  ID 

Sulfur  Black  1 

Leuco  Sulfur  Black  1 

Leuco  Sulfur  Black  2 

All  other  sulfur  dyes 

VAT  DYES 

Total 

Vat  yellow  dyes,  total 

Vat  Yellow  2,   8-3/2% 

Vat  Yellow  4,    12-1/2% 

All  other 

Vat  orange  dyes,    total 

Vat  Orange  1,   20% 

Solubilized  Vat  Orange  1,  26% 

Vat  Orange  2,    12% 

Vat  Orange  3,    13-1/2% 

Vat  Orange  4,   6% 

Vat  Orange  5,  ]fl% 

Solubilized  Vat  Orange  5,  30% 

Vat  Orange  7,  11% 

Vat  Orange  9,  12% 

Vat  Orange  15,  10% 

All  other 

Vat  red  dyes,    total 

Vat  Red  1,    13% 

Vat  Red  13,    11% 

Vat  Red  15,    10% 

Vat  Red  32,   20% 

All  other : 

Vat  violet  dyes,    total 

Vat  Violet  1,    11% 

Vat  Violet  2,   20% 

Vat  Violet  9,    12% 

Vat  Violet  13,   6-1/4% 

All  other 

Vat  blue  dyes,  total 

Vat  Blue  6,   8-1/3% 

Vat  Blue  18,    13%- 

Vat  Blue  20,    14% 

All  other- 

See  footnotes  at  end  of  table. 


5,900 


18,648 


57,511 


4,090 


2,373 
763 
954 

2,794 


322 

110 

113 
7 
312 
124 
687 
493 

1,412 


651 
125 
286 


310 

34 

133 

421 


21,964 


3,395 

1,433 

1,205 

15,931 


97 

360 

56 

220 

86 

304 

,586 

8,270 

17,471 


52,439 


3,897 


2,417 
675 
805 

2,463 


553 


81 
163 

271 
109 
564 
438 

1,143 


201 
30 
265 


214 

33 


391 
68 


19,924 


3,318 

1,125 

1,073 

14,408 


9,960 


120 

130 

92 

26 

26 

6 

13 

47 

50 

34 

1,419 

1,160 

404 

5,827 

5,871 

2,154 

2,207 

2,030 

800 

9,028 

8,198 

6,437 

48,728 


5,303 


2,126 

865 

2,312 

5,846 


1,506 

53 

509 

242 
232 

795 

269 

1,362 

878 

2,436 


~K2~ 
284 
201 
131 
978 


335 
490 

197 

12,659 


3,527 
1,942 
1,450 
5,740 


DYES 


25 


TABLE  8A.--Bemenoid  dyes.-  U.S.  production  and  sales ,  1965— Continued 


Eye 


Production 


Quantity 


Unit 
value1 


VAT  DYES— Continued 

Vat  green  dyes,   total 

Vat  Green  1,   6$ 

Vat  Green  3,    1A# 

Solubilized  Vat  Green  3,   26$ 

Vat  Green  8,   8- 1/2$ 

Vat  Green  9,    12-1/2$ 

All  other 

Vat  brown  dyes,  total 

Vat  Brown  1,  11$ 

Vat  Brown  3,  11$ 

Vat  Brown  5,  13% 

All  other 

Vat  black  dyes,  total 

Solubilized  Vat  Black  1,  27-1/2$ 

Vat  Black  9,  16$ ■ 

Vat  Black  25,    12-1/2$ 

Vat  Black  27,    12-1/2$ - ■ 

All  other 

All  other  dyes3 


1.000 
11,425 


ID,  574 


3,755 
3,970 
16 
2,015 
1,468 
201 

5,037 


629 
1,049 

106 
3,253 

9,793 


3,690 
3,554 
13 
1,878 
1,297 
142 

4,726 


1,000 
dollars 

7,379 


2,425 
2,209 
80 
1,379 
1,057 
229 

5,618 


559 

970 

115 

3,082 

8,910 


176 
4,51/4 

747 
4,356 

296 


4 
153 

4,151 
653 

3,949 

469 


887 
1,493 

177 
3,061 

7,797 


33 
354 

2,904 
792 

3,71A 

884 


pound 

$0.70 


.66 
.62 

6.15 
.73 
.81 

1.61 

1.19 


1.59 
1.54 
1.54 


8.25 
2.31 

.70 
1.21 

.94 

1.88 


1  Calculated  from  rounded  figures. 

2  Production  and  sales  quantities  of  C.I.  Leuco  Sulfur  and  C.I.  Solubilized  Sulfur  dyes  are  reported  in  terms  of 
the  usual  commercial  concentration  of  the  C.I.  Sulfur  dyes. 

3  Includes  oxidation  bases,  ingrain  dyes,  and  miscellaneous  dyes.  Statistics  for  these  groups  of  dyes  may  not  be 
published  separately  because  publication  would  disclose  information  received  in  confidence. 


Table  9  summarizes  production  and  sales  of  dyes  in  1965,   by  class  of  application.   Six 
classes  of  dyes  grouped  by  class  of  application  accounted  for  more  than  four-fifths  of  all  the 
dyes  produced  in  1965.    Vat  dyes  accounted  for  27.8  percent  of  the  total;  direct  dyes,  for  17.4 
percent;  acid  dyes,    for  9.8  percent;  fluorescent  brightening  agents,   for  9.4  percent;  sulfur 
dyes,   for  9.0  percent;  and  disperse  dyes,    for  7.5  percent.   Of  the  above  six  classes,    the  output 
of  disperse  dyes  was  18.  1  percent  larger  in  1965  than  in  1964;  that  of  fluorescent  brightening 
agents,    16.5  percent  larger;  and  that  of  both  direct  and  acid  dyes,    14.  6  percent  larger. 

Of  the  remaining  classes,    the  output  of  mordant  dyes  was  4.  7  million  pounds  in  1965,    or 
33.  6  percent  more  than  the  3.  6  million  pounds  in  1964.    Production  of  fast  color  salts  was  32.  7 
percent  larger  in  1965  than  in  1964;  basic  dyes,    15.  5  percent;  solvent  dyes,    15.  1  percent;  and 
fast  color  bases,    12.0  percent.    On  the  other  hand,    the  output  of  fiber- reactive  dyes  was  3.  3 
percent  smaller  in  1965  than  in  1964,    and  that  of  azoic  coupling  components,    1.4  percent 
smaller. 

Table  10  shows  production  and  sales  of  dyes  in  1965,   by  chemical  class.   In  1965,    three 
chemical  classes  of  dyes  accounted  for  approximately  two-thirds  of  all  the  dyes  produced:  Azo 
dyes  accounted  for  32.  1  percent  of  the  total;  anthraquinone  dyes,    for  23.  0  percent;  and  stilbene 
dyes,   for  10.  3  percent.   The  output  of  each  of  these  three  classes  was  larger  in  1965  than  in 
1964:  Stilbene  dyes  were  15.4  percent  larger;  azo  dyes,   14.9  percent  larger;  and  anthraquinone 
dyes,    14.4  percent  larger.   Of  the  remaining  chemical  classes  for  which  1964  and  1965  statistics 
are  published,   production  of  most  classes  was  larger  in  1965  than  in  1964.   In  terms  of  value 
of  sales,   the  most  important  classes  of  dyes  in  1965  were  the  azo  dyes  ($107.  1  million),   the 
anthraquinone  dyes  ($72.7  million),   the  stilbene  dyes  ($33.0  million),    and  the  triarylmethane 
dyes  ($13.  3  million). 


26 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 
TABLE  9*--Benzenoid  dyes.-    U.S.  production  and  sales ,  by  class  of  application,  1965 


Class  of  application 


Total 

Acid 

Azoic  dyes  and  components: 

Azoic  compositions 

Azoic  diazo  components,  bases  (Fast  color  bases) 

Azoic  diazo  components,  salts  (Fast  color  salts) 

Azoic  coupling  components  (Naphthol  AS  and  derivatives) 

Basic 

Direct 

Disperse 

Fiber-reactive 

Fluorescent  brightening  agents 

Food,  drug,  and  cosmetic  colors 

Mordant 

Solvent 

Sulfur2 

Vat 

All  other3 


1,000 
pounds 
207,193 


20,395 

2,100 

1,558 

2,835 

3,172 

10,573 

36,080 

15,514 

1,586 

19,420 

2,923 

4,745 

9,837 

18,648 

57,511 

296 


Quantity 


1.000 
pounds 
189,965 


18,666 

2,043 
1,310 
2,646 
2,429 
9,553 
33,663 
13,522 
1,558 
18,284 
2,736 
4,246 
8,930 
17,471 
52,439 
469 


1,000 
dollars 
292,284 


39,025 

3,968 

2,057 

2,683 

4,669 

23,907 

50,970 

32,878 

6,744 

34,516 

10,238 

5,706 

15,351 

9,960 

48,728 

884 


Unit 
value1 


pound 
$1.54 


2.09 

1.94 
1.57 
1.01 
1.92 
2.50 
1.51 
2.43 
4.33 
1.89 
3.74 
1.34 
1.72 
.57 
.93 
1.88 


. I.   Solubilized  Sulfur  dyes  are  reported  in  terms  of 


1  Calculated  from  rounded  figures. 

2  Production  and  sales  quantities  of  C.I.   Leuco  Sulfur  and 
the  usual  commercial  concentration  of  the  C.I.   Sulfur  dyes. 

3  Includes  oxidation  bases,   ingrain  dyes,   and  miscellaneous  dyes.   Statistics  for  these  groups  of  dyes  may  not  be 
published  separately  because  publication  would  disclose  information  received  in  confidence. 


TABLE  10.  —  Benzenoid  dyes.-    U.S.  production  and  sales,  by  chemical  class,  1965 


Chemical  class 


Unit 
value1 


Total 

Anthr  aquinone - - 

Azo,  total 

Monoazo 

Disazo 

Trisazo 

Polyazo 

Not  specified 

Azoic 

Cyanine 

Indigoid 

Ketone  imine — 

Methine 

Nitro 

Oxazine 

Phthalocyanine - 

Quinoline 

Stilbene 

Sulfur2 

Thiazole 

Triarylmethane - 

Xanthene 

All  other3 


1,000 
pounds 
207,193 


1,000 
pounds 
189,965 


1,000 
dollars 
292,284 


47,674 


66,497 


42,774 


61,737 


24,752 

19,807 

12,155 

3,315 

6,468 

9,754 
518 

5,740 
613 

1,343 
913 
173 

2,197 

576 

21,327 

18,648 

625 

6,690 

1,311 
22,594 


22,390 

18,584 

11,350 

2,937 

6,476 

8,441 

442 
5,533 

620 
1,188 

788 

179 
2,002 

507 
19,874 
17,471 

559 
5,992 

787 
21,071 


72,664 
107,091 


43,337 
32,631 
12,157 
4,727 
14,239 

13,405 
1,423 
3,304 
1,313 
4,160 
1,438 
736 
5,0pl 
1,664 

33,029 
9,960 
1,113 

13,252 
3,887 

18,794 


pound 


$1.54 


1.73 


1.94 
1.76 
1.07 
1.61 
2.20 

1.59 
3.22 
.60 
2.12 
3.50 
1.82 
4.11 
2.52 
3.28 


2.21 
4.94 


Calculated  from  rounded  figures. 

2  Production  and  sales  quantities  of  C.I.  Leuco  Sulfur  and  C.I.  Solubilized  Sulfur  dyes  are  reported  in  terms  of 
the  usual  commercial  concentration  of  the  C.I.  Sulfur  dyes. 

3  Includes  acridine,  aminoketone,  azine,  coumarin,  hydroxyketone ,  nitroso,  oxidation  bases,  thiazine,  vat  sulfur, 
and  miscellaneous  dyes.  Statistics  for  these  groups  of  dyes  may  not  be  published  separately  because  publication 
would  disclose  information  received  in  confidence. 


PIGMENTS  27 


Pigments 


As  the  terms  are  used  in  this  report,    synthetic  organic  pigments  are  toners  and  lakes 
derived  in  whole  or  in  part  from  benzenoid  chemicals  and  colors.    They  are  used  in  paints  and 
related  products,   in  printing  inks,    and  in  plastics  and  resin  materials. 

Statistics  on  production  and  sales  of  all  benzenoid  pigments  in  1965  are  given  in  table   11A. 
Statistics  on  sales  of  a  few  selected  pigments  by  commercial  forms  (dry  full- strength  form, 
dry  extended  form,    dry  dispersions,    aqueous  dispersions,    and  flushed  colors)  are  given  in 
table   12.    Prior  to  1961,    statistics  for  toners  included  the  quantities  and  values  of  extenders  and 
diluents.    Beginning  in  1961,    data  were  collected  for  both  the  full-strength  and  extended  toners 
on  a  full-strength-toner-content  basis.   Individual  toners  and  lakes  are  identified  in  this  report 
by  the  names  used  in  the  second  edition  of  the  Colour  Index. 

Total  production  of  benzenoid  pigments  in  1965  was  48.  0  million  pounds--9.  1  percent  more 
than  the  44.  1  million  pounds  produced  in  1964  and  21.9  percent  more  than  the  39.  4  million 
pounds  produced  in  1963.    Total  sales  of  benzenoid  pigments  in  1965  amounted  to  38.0  million 
pounds,    valued  at  $93.  6  million,    compared  with  35.  1  million  pounds,    valued  at  $84.  1  million,   in 

1964  and  33.  5  million  pounds,    valued  at  $79.  6  million,    in  1963.    In  terms  of  quantity,    sales  of 
benzenoid  pigments  in  1965  were  8.4  percent  larger  than  in  1964  and  13.4  percent  larger  than 
in  1963;  in  terms  of  value,    sales  in  1965  were  11.  3  percent  larger  than  in  1964  and  17.  6  percent 
larger  than  in  1963. 

Production  of  toners  in  1965  amounted  to  43.7  million  pounds--9.2  percent  more  than  the 
40.0  million  pounds  reported  for  1964.  Sales  in  1965  were  34.1  million  pounds,  valued  at  $89.9 
million,  compared  with  31.4  million  pounds,  valued  at  $80.9  million,  in  1964.  Sales  in  1965  were 
thus  8.5  percent  larger  than  those  in  1964  in  terms  of  quantity,  and  11.1  percent  larger  in  terms 
of  value.  The  individual  toners  listed  in  the  report  which  were  produced  in  the  largest  quantities 
in  1965  were  Pigment  Blue  15,  alpha  form,  4.5  million  pounds;  Pigment  Green  7,  4.3  million 
pounds;  Pigment  Yellow  12,  3.5  million  pounds;  Pigment  Red  49,  barium  toner,  3.2  million 
pounds;  Pigment  Red  48,  2.6  million  pounds;  Pigment  Blue  19,  2.5  million  pounds;  and  Pigment 
Blue  15,  beta  form,  2.2  million  pounds. 

Production  of  lakes  totaled  4.3  million  pounds  in  1965--8.0  percent  more  than  the  4.0  mil- 
lion pounds  reported  for  1964.  Sales  of  lakes  in  1965  amounted  to  3.9  million  pounds,  valued  at 
$3.8  million,  compared  with  sales  in  1964  of  3.7  million  pounds,  valued  at  $3.3  million.  Sales  in 

1965  were  thus  7.3  percent  larger  than  those  in  1964  in  terms  of  quantity,  and  15.3  percent 
larger  in  terms  of  value.  Pigment  Blue  24,  with  an  output  of  2.2  million  pounds,  was  the  lake 
produced  in  largest  quantity  in  1965. 

For  each  of  14  selected  pigments,  or  groups  of  pigments,  table  12  gives  data  on  sales  by 
commercial  forms.  Pigment   Yellow  12,  Pigment  Red  90,  and  Pigment  Blue  19  were  sold  prin- 
cipally in  the  flushed  form.   The  remaining  11  pigments,  or  groups  of  pigments,  for  which  statis- 
tics are  published  were  sold  principally  in  the  dry  full- strength  form.  Statistics  on  sales  by 
commercial  forms  could  not  be  published  for  Pigment  Red  49,  sodium  toner,  or  for  Pigment 
Blue  24  without  revealing  the  operations  of  individual  companies. 


3  Sec  also  table  11B,  pt.  Ill,  which  lists  these  products  alphabetically  and  identifies  the  manufacturers,  and  table  23  in  the  appendix, 
which  shows  imports  of  benzenoid  pigments  during  the  years  1964-G5. 


28 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 
TABLE  11  A. --Benzenoid  pigments:    U.S.  production  and  sales ,  1965 


[Listed  below  are  all  toners  and  lakes  for  which  any  reported  data  on  production  or  sales  may  be  published.    (Leaders 
are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were 
reported.)   Table  11B  in  pt.   Ill  lists  all  toners  and  lakes  for  which  data  on  production  or  sales  were  reported  and 
identifies  the  manufacturer  of  each] 


Pigment 


Quantity 


Grand  total 

TONERS 
Total 

Yellow  toners,    total 

Hansa  yellows,   total 

Pigment  Yellow  1,    C.I.    11  680 — 

Pigment  Yellow  3,    C.I.    11  710 

Other  Hansa  yellows 

Benzidine  yellows,   total 

Pigment  Yellow  12,    C.I.   21  090 

Pigment  Yellow  13,    C.I.   21  100 

Pigment  Yellow  14,    C.I.   21  095 

Pigment  Yellow  17,    C.I.   21  1£>5 

Other  benzidine  yellows 

All  other 

Orange  toners,  total 

Pigment  Orange  2,  C.I.  12  060 

Pigment  Orange  5,  C.I.  12  075 

Pigment  Orange  13,  C.I.  21  110 

Pigment  Orange  16,  C.I.  21  160 

All  other 

Red  and  violet  toners,  total 

Naphthol  reds,  total 

Pigment  Red  2,  C.I.  12   310 

Pigment  Red  5,  C.I.  12  490 

Pigment  Red  17,  C.I.  12  390 

Pigment  Red  IS,  C.I.  12  350 

Pigment  Red  22,  C.I.  12  315 

Pigment  Red  23,  C.I.  12  355 

Other  naphthol  reds 

Pigment  Red  1,  C.I.  12  070,  dark 

Pigment  Red  1,  C.I.  12  070,  light — 

Pigment  Red  3,  C.I.  12  120 - - 

Pigment  Red  4,  C.I.  12  085 - 

Pigment  Red  6,  C.I.  12  090 

Pigment  Red  38,  C.I.  21  120- 

Pigment  Red  48,  C.I.  15  865 

Pigment  Red  49,  C.I.  15  630: 

Barium  toner 

Calcium  toner 

Sodium  toner , 

Pigment  Red  52,  C.I.  15  860 

Pigment  Red  53,  C.I.  15  585,  barium  toner- 
Pigment  Red  54,  C.I.  14  830,  calcium  toner- 
Pigment  Red  57,  C.I.  15  850,  calcium  toner- 
Pigment  Red  63,  C.I.  15  880 

Pigment  Red  81,  C.I.  45  160,  PMA 

Pigment  Red  81,  C.I.  45  160,  PTA 

Pigment  Red  90,  C.I.  45  380 

Pigment  Violet  1,  C.I.  45  170,  PMA 

Pigment  Violet  1,  C.I.  45  170,  PTA 

Pigment  Violet  3,  C.I.  42  535,  fugitive 

Pigment  Violet  3,  C.I.  42  535,  PMA 

Pigment  Violet  3,  C.I.  42  535,  PTA 

All  other 


1,000 
pounds 
48,045 


6,935 


1,208 
590 
170 
448 

5,509 

3,541 
316 

1,204 
223 
225 
218 

860 


247 
172 
212 
229 


770 

94 

100 

63 

12 

115 

104 

282 

210 

192 

1,593 

388 

73 

157 

2,627 

3,223 

1,544 

241 

1,181 

1,924 

69 

965 

323 

166 

1,291 

78 

44 

432 

429 

40 

2,594 


1,000 
pounds 
38,024 


1,000 
dollars 
93,635 


34,105 


4,523 


386 

85 

397 

3,515 

2,063 

177 

942 

152 

181 

140 

700 


185 

160 
181 
135 

16,720 


601 
54 


97 
109 
221 
152 
162 
1,250 
251 

127 
2,231 

2,941 

1,384 

268 

1,008 

1,590 

52 

853 

38 

223 

133 

667 


385 

378 

36 

1,870 


12,737 


2,316 

728 

196 

1,392 

8,730 

4,503 

566 

2,184 

526 

951 

1,691 

2,745 


55 

290 

520 

536 

1,344 

38,883 


2,759. 
165 
324 
172 

291 
416 

1,391 
189 
199 

1,915 
351 

576 
4,068 

2,870 
1,413 

272 
1,307 
2,038 

115 

1,272 

71 

1,359 

835 
1,239 

227 

264 

578 
1,096 

147 
13,723 


See  footnotes  at  end  of  table. 


PIGMENTS 


29 


TABLE  HA. --Benzenoid  pigments;   U.S.  production  and  sales ,  1965 — Continued 


Pigment 


Unit 
value1 


TON ERS- - Cont inued 

Blue  toners,    total 

Pigment  Blue  1,    C.I.   42  595,    PMA 

Pigment  Blue  1,    C.I.  42  595,   PTA- 

Pigment  Blue  2,    C.I.  44  045,    fugitive,    PMA,    and  PTA- 

Pigment  Blue  9,    C.I.   42  025,    PTA 

Pigment  Blue  IA,    C.I.  42  600,   PMA 

Pigment  Blue  15,    C.I.   74  160,    alpha  form 

Pigment  Blue  15,    C.I.   74  160,    beta  form 

Pigment  Blue  19,    C.I.  42  750A 

Pigment  Blue  22,    C.I.   69  810 

All  other 

Green  toners,  total 

Pigment  Green  1,  C.I.  42  040,  PMA 

Pigment  Green  1,  C.I.  42  040,  PTA 

Pigment  Green  2,  C.I.  42  040  and  49  005,  PMA 

Pigment  Green  2,  C.I.  42  040  and  49  005,  PTA 

Pigment  Green  4,  C.I.  42  000,  PMA 

Pigment  Green  4,  C.I.  42  000,  PTA 

Pigment  Green  7,  C.I.  74  260 

Pigment  Green  8,  C.I.  ID  006 

All  other 

Brown  toners,  total 

Pigment  Brown  5,  C.I.  15  800 

All  other 

Black  toners 

LAKES 

Total- - 

Red  lakes,  total 

Pigment  Red  60,  C.I.  16  105- - 

Pigment  Red  83,  C.I.  58  000 

(Acid  Red  26),  C.I.  16  150 

All  other 

Violet  lakes,  total 

Pigment  Violet  5,  C.I.  58  055— 

All  other 

Blue  lakes,  total 

Pigment  Blue  24,  C.I.  42  090 

All  other 

Black  lakes:      (Natural  Black  3),    C.I.   75  291 

All  other  lakes2 


1,000 

pounds 

9,997 


T7D" 

31 

18 

9 

70 

4,538 

2,239 

2,546 

376 


55 

41 

7 

7 

4,252 

184 

337 

164 


220 

83 

623 


2,214 


2,183 


67 

853 


1,000 
pounds 

8,239 


T50" 
22 


66 

3,464 

1,797 

2,450 

17 

240 

3,557 


2,965 
143 
333 


3,919 


958 


~178~ 

70 

625 

85 


1,960 


1,928 


1,000 
dollars 
23,603 


"750" 

123 

46 

55 

522 

9,497 

5,390 

5,661 

343 

1,216 

11,369 


249 
212 


9,270 

190 

1,301 


157 
123 


1,067 


272 
248 
286 
261 


1,872 


1,852 


$2.86 


"4T69" 
5.59 
3.29 
6.11 
7.91 
2.74 
3.00 
2.31 

20.18 
5.07 

3.20 


5.00 
5.62 
4.88 
6.24 
4.33 
3.50 
3.13 
1.33 
3.91 


1.94 
4.39 


1.11 


1.53 
3.54 

.46 
3.07 

2.1A 


1  Calculated  from  rounded  figures. 

2  Includes  all  brown,   green,   orange,    and  yellow  lakes,    "all  other"  black  lakes,    and  sales  of  Natural  Black  3. 

Note. — The  C.I. (Colour  Index)  numbers  shown  in  this  report  are  the  identifying  numbers  given  in  the  second  edition  of 
the  Colour  Index. 

The  abbreviations  PMA  and  PTA  stand  for  phosphomolybdic  and  phosphotungstic  ( including  phosphotungstomolybdic) 
acids,   respectively. 


30  SYNTHETIC  ORGANIC  CHEMICALS,  1965 

TABLE  12  —  U.S.  sales  of  selected  dry  full-strength  colors,  dry  extended  colors,  dry  dispersions,  aqueous 

dispersions,  and  flushed  colors,  1965 


Selected  pigments  by  commercial  forms 


Pigment  Yellow  12,    C.I.   21  090,   total 

Dry  full-strength  toner 

Dry  extended  toner,   aqueous  dispersions3  and  flushed  color  

Pigment  Yellow  13,    C.I.   21  100;   Pigment  Yellow  14,    C.I.   21  095;   Pigment 

Yellow  17,    C.I.   21  105;   and  other  benzidine  yellows,   total 

Dry  full-strength  toner 

Dry  extended  toner  and  dry  dispersions4 

Aqueous  dispersions3 

Flushed  color 


Pigment  Red  3,    C.I.   12  120,   total 

Dry  full-strength  toner  and  dry  extended  toner4 

Aqueous  dispersions3 

Flushed  color 


Pigment  Red  48,  C.I.  15  865,  total 

Dry  full-strength  toner 

Dry  extended  toner 

Dry  dispersions  and  aqueous  dispersions 
Flushed  color 


Pigment  Red  49,  C.I.  15  630,  barium  toner,  total - 

Dry  full-strength  toner --- — 

Dry  extended  toner  and  aqueous  dispersions 
Flushed  color 


Pigment  Red  49,  C.I.  15  630,  calcium  toner,  total- 
Dry  full-strength  toner  and  dry  dispersions4 

Aqueous  dispersions3  and  flushed  color4 

Pigment  Red  49,  C.I.  15  630,  sodium  toner4 


Pigment  Red  53,  C.I.  15  585,  barium  toner,  total 

Dry  full-strength  toner,  dry  extended  toner,  and  dry  dispersions4 
Aqueous  dispersions3  and  flushed  color4 


Pigment  Red  90,  C.I.  45  380,  total -- 

Dry  full-strength  toner  and  dry  extended  toner4- 
Dry  dispersions  and  flushed  color4 


Pigment  Violet  3,  C.I.  42  535,  fugitive, .  total— - 
Dry  full-strength  toner  and  dry  extended  toner 
Flushed  color 


Pigment  Violet  3,  C.I.  42  535,  permanent  (PMA  and  PTA),  total - 

Dry  full-strength  toner 

Dry  extended  toner,  dry  dispersions  and  aqueous  dispersions 
Flushed  color 


Pigment  Blue  15,  C.I.  74  160,  alpha  form,  total - 

Dry  full-strength  toner 

Dry  extended  toner 

Dry  dispersions 

Aqueous  dispersions3 

Flushed  color 


Pigment  Blue  15,  C.I.  74  160,  beta  form,  total 

Dry  full-strength  toner r- 

Dry  extended  toner,  dry  dispersions  and  flushed  eolor4- 
Aqueous  dispersions 


Pigment  Blue  19,  C.I.  42  750A,  total 

Dry  full-strength  toner  and  dry  extended  toner4 
Aqueous  dispersions3  and  flushed  color4 


See  footnotes  at  end  of  table. 


Qjantity1 


1,000 
pounds 
2,063 


608 
1,455 


1,007 


237 
163 


1,250 


740 

65 

445 


2,062 

41 


2,070 

10 

861 

1,384 


1,110 
274 


1,590 


936 
654 


275 
110 


222 
78 
114 

3,464 


2,036 

497 

34 

721 

176 

1,797 


883 
513 
401 

2,450 


207 
2,243 


1.000 
dollars 

4,734 


1,315 
3,419 


4,302 


3,093 
107 
596 
506 

1,986 


1,126 

108 
752 

4,083 


3,756 
83 

144 
100 

2,981 


2,019 


1,556 


1,131 
425 


1,201 
905 


1,324 


87 
1,237 


418 
162 


693 
226 
338 

9,630 


5,498 
1,618 

153 
1,892 

469 

5,392 


2,760 
1,564 
1,068 


471 
5,190 


MEDICINAL  CHEMICALS 

TABLE  12.  --U.S.  sales  of  selected  dry  full-strength  colors,  dry  extended  colors ,  dry  dispersions,  aqueous 
dispersions ,  and  flushed  colors,  1965 — Continued 


Selected  pigments  by  commercial  forms 


Quantity1 


Unit 
value2 


Pigment  Blue  24,    C.I.   42  090* 

Pigment  Green  7,    C.I.   74  260,    total - 

Dry  full-strength  toner 

Dry  extended  toner 

Dry  dispersions 

Aqueous  dispersions3 

Flushed  color 


pounds 
1,928 

2,965 


pound 


2,392 
9,341 


$1.24 
3.15 


1,345 

244 

67 

985 

324 


4,314 
903 
279 

2,892 
953 


3.21 
3.70 
4.16 
2.94 
2.94 


1  Quantity  of  the  various  commercial  forms  is  given  in  terms  of  dry  full-strength  toner   (or  dry  lake)  content. 

2  Calculated  from  rounded  figures. 

3  Includes  presscake. 

*  Separate  data  on  these  commercial  forms  may  not  be  published  without  revealing  the  operations  of  individual  com- 
panies. 

Note. —The  C.I.  (Colour  Index)   numbers  shown  in  this  report  are  the  identifying  numbers  given  in  the  second  edi- 
tion Of  the  Colour  Index. 

The  abbreviations  FMA  and  PTA  stand  for  phosphomolybdic  and  phosphotungstic  (including  phosphotungstomolybdic ) 
acids,  respectively. 

Medicinal  Chemicals 


Medicinal  chemicals  include  the  medicinal  and  feed  grades  of  all  organic  chemicals  having 
therapeutic  value,  whether  obtained  by  chemical  synthesis,  by  fermentation,  by  extraction  from 
naturally  occurring  plant  or  animal  substances,  or  by  refining  the  technical  grade  material.  They 
include  alkaloids,  antibiotics  and  other  anti-infective  agents,  antihistamines,  autonomic  drugs, 
central-nervous-system  depressants  and  stimulants,  hormones,  vitamins,  and  other  therapeutic 
agents  for  human  or  veterinary  use  and  for  animal  feed  supplements.  Statistics  on  the  production 
of  medicinal  chemicals  are  in  terms  of  100-percent  content  of  the  medicinal  chemical  itself,  ex- 
clusive of  all  diluents  or  other  materials  used  in  mixing  or  compounding  tablets,  solutions,  and 
suspensions  for  consumer  use.  Sales  include  that  part  of  the  original  production  that  was  sold  in 
bulk  and  exclude  all  dosage-form  products  and  other  finished  pharmaceutical  preparations. 

Statistics  on  U.S.  production  and  sales  of  medicinal  chemicals  in  1965  are  given  in  table 
13A.*   Total  production  of  medicinal  chemicals  in  1965  amounted  to  160  million  pounds,  or  10.7 
percent  more  than  the  144  million  pounds  produced  in  1964,  and  14.6  percent  more  than  the  139 
million  pounds  produced  in  1963.  Total  sales  of  medicinal  chemicals  in  1965  amounted  to  129 
million  pounds,  valued  at  $362  million.  These  figures  represent  sales  of  bulk  medicinal  chemi- 
cals only  and  therefore  cannot  be  compared  with  sales  data  for  earlier  years,  which  included 
all  antibiotics  sold  by  the  primary  producers,  whether  they  were  sold  as  medicinal  preparations 
or  as  bulk  materials.  Sales  of  medicinal  chemicals  in  1965,  exclusive  of  antibiotics,  amounted 
to  125  million  pounds,  valued  at  $269  million,  compared  with  sales  in  1964  of  113  million 
pounds,  valued  at  $260  million,  and  sales  in  1963  of  108  million  pounds,  valued  at  $251  million. 
Sales  in  1965  of  medicinal  chemicals  other  than  antibiotics  were  thus   10.6  percent  larger  than 
in  1964  and  15.3  percent  larger  than  in  1963,  in  terms  of  quantity,  and  3.4  percent  larger  than 
in  1964  and  7.1  percent  larger  than  in  1963,  in  terms  of  value. 

Production  of  the  more  important  groups  of  medicinal  chemicals  in  1965  was  as  follows: 
Antibiotics,  7.5  million  pounds  (14.0  percent  larger  than  in  1964),  of  which  4.7  million  pounds  was 
for  medicinal  use  and  2.8  million  pounds  was  for  other  uses;  anti-infective  agents  other  than  an- 
tibiotics, 27.5  million  pounds  (5.9  percent  larger  thanin  1964);  central  depressants  and  stimulants, 
42.8  million  pounds  (5.4  percent  larger);  and  vitamins,  16.3  million  pounds  (15.5  percent  larger). 
Production  of  some  of  the  more  important  individual  products  listed  in  the  report  was  as  follows: 
Aspirin,  29.1  million  pounds  (3.1  percent  larger  than  in  1964);  salicylic  acid,  9.9  million  pounds 
(24.8  percent  smaller  than  in  1964);  choline  chloride,  31.1  million  pounds  (23.6  percent  larger); 
methionine  and  its  hydroxy  analogue,   10.4  million  pounds  (72.0  percent  larger);  ascorbic  acid, 
7.3  million  pounds  (19.6  percent  larger);  piperazine  base  and  salts,  6.5  million  pounds  (6.3  per- 
cent smaller);  anti-infective  sulfonamides,  4.7  million  pounds  (4.8  percent  smaller);  vitamin  A 
alcohol  and  esters,  598  trillion  units  (3.1  percent  smaller);  penicillins,  1,343  trillion  units  (11.7 
percent  larger);  and  tetracyclines,  1,157  million  grams  of  antibiotic  base. 


See  also  table  13B.  pt.  Ill,  which  lists  these  products  alphabetically  and  identifies  the  manufacturers,  and  table  23  in  the  appendix 
which  shows  imports  of  coal-tar  medicinal  chemicals  and  pharmaceuticals  during  the  years  l°64-65. 


32 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 
TABLE  13A.  --Medicinal  chemicals.-    U.S.  production  and  sales ,  19651 


[Listed  below  are  all  synthetic  organic  medicinal  chemicals  for  which  any  reported  data  on  production  or  sales  may  be 
published.  I  Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where 
no  data  were  reported.)  Table  13B  in  pt.  Ill  lists  alphabetically  all  medicinal  chemicals  for  which  data  on  produc- 
tion or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Quantity 


Grand  total 

Acyclic 

Benzenoid3 

Cyclic  nonbenzenoid^ 

Antibiotics,  total5 

For  medicinal  use,  total 

Antifungal  and  antitubercular  antibiotics,  total 

Streptomycin 

All  other 

Bacitracin 

Penicillins,  total 

Penicillin  G,  potassium 

Penicillin  G,  procaine 

All  other 

All  other  antibiotics  for  medicinal  use 

For  other  uses,  total 

Bacitracin 

Penicillin  G,  procaine 

All  other 

Antihistamines,  total 

Antinauseants 

Chlorpheniramine  maleate 

Pheniramine  maleate 

Pyrilamine  maleate 

All  other 

Anti-infective  agents  (except  antibiotics),  total 

Antimony,  arsenic,  and  bismuth  compounds 

Cetylpyridinium  chloride 

Mercury  compounds 

5-Nitrofurane,  -imidazole,  and  -thiazole  derivatives 

Phenolic  antiseptics  and  disinfectants 

Piperazine  base  and  salts,  total 

Piperazine 

All  other 

Quinoline  derivatives,  total 

Diiodohydroxyquin 

All  other 

Sulfonamides,  total 

Sulfathiazole 

All  other 

Other  anti-infective  agents,  total 

Anthelmintic,  antifungal,  antiprotozoan,  and  antiviral 

agents 

Urinary  antiseptics 

All  other 

Antineoplastic  agents  and  local  anesthetics 

Autonomic  drugs,  total 

Parasympatholytic  (anticholinergic)  agents: 
Quaternary  ammonium  compounds  (except  tropane 

derivatives) 

Tertiary  amines  (except  tropane  derivatives) 

Sympathomimetic  (adrenergic)  agents,  total 

Epinephrine  salts 

Isoproterenol  salts 

Phenylephrine  base  and  salts,  total 

Phenylephrine  hydrochloride 

All  other 


1,000 
pounds 
159,520 


59,480 
84,678 
15,362 
7,455 


4,656 

1,134 

470 

664 

7 

1,749 

530 

798 

421 

1,766 

2,799 

127 

707 

1,965 

380 


17 
268 


27,493 


3,035 

31 

35 

502 

279 

6,513 

2,891 

3,622 

536 

19 

517 

4,728 

117 

4,611 

11,834 


696 
2,458 

2,189 

436 


(6) 


1,000 
pounds 
129,048 


1,000 
dollars 
362,169 


56,569 
60,977 
11,502 
4, 


2,397 

846 

389 

457 

7 

328 


1,134 

1,689 

132 

1,557 


182 
16,887 


27 

239 
4,455 

712 
3,743 

152 

152 

1,343 

72 

1,271 

10,644 

7,729 

573 

2,342 

1,522 

302 


I6) 


41,011 

224,159 

96,999 

93,593 


53,713 
11,023 
3,539 
7,484 
897 

3,343 

5,996 
32,454 
39,880 

2,943 

36,937 

4,745 


257 
299 


4,189 
67,581 


82 
348 

428 
3,507 

789 
2,718 

495 

495 

6,265 

186 

6,079 

56,456 

46,718 

997 

8,741 

1,724 

5,791 


810 
1,031 
3,603 


1,767 

1,547 

220 


See  footnotes  at  end  of  table. 


MEDICINAL  CHEMICALS 
TABLE  13A.  —Medicinal  chemicals.-   U.S.  production  and  sales,  19651  --Continued 


33 


Quantity 


Autonomic  drugs — Continued 

Sympathomimetic  (adrenergic)  agents — Continued 

Phenylpropanolamine  hydrochloride 

All  other 

All  other  autonomic  drugs 

Cardiovascular  agents,  total 

Vasodilators 

All  other 

Central  depressants,  total 

Analgesics  and  antipyretics,  total 

Salicylates,  total 

Aspirin 

All  other 

All  other  analgesics  and  antipyretics 

Anticonvulsants,  hypnotics,  and  sedatives,  total 

Barbiturates,  total 

Butabarbital 

Butabarbital,  sodium 

Phenobarbital,  sodium 

All  other 

All  other  anticonvulsants,  hypnotics,  and  sedatives7 — 

Skeletal  muscle  relaxants,  total 

Mephenesin 

Succinylcholine  chloride 

All  other 

Tranquilizers,  total 

Meprobamate 

Phenothiazine  derivatives 

All  other7 

Other  central  depressants,   total8 

Ethyl-aorphine  hydrochloride 

All  o^her 

Central  stimulants,  total 

Amphetamines,  total 

Amphetamine,  dextroamphetamine  and  levamphet amine  base 

and  salts,  total 

Dextroamphetamine  sulfate 

All  other 

Methamphetamine  base  and  hydrochloride,  total 

Methamphetnnri ne  (racemic) 

Methamphetamine  hydrochloride  (dextro) 

All  other 

Antidepressants 

Caffeine  (natural  and  synthetic) 

Other  central  stimulants 

Dermatological  agents,  total 

Allantoin 

Bismuth  subgallate 

Salicylic  acid 

Other  dermatological  agents 

Expectorants  and  mucolytic  agents 

Gastrointestinal  agents,  total 

Choleretics  and  hydrocholeretics 

Choline  chloride  (all  grades) 

Methionine  and  its  hydroxy  analogue 

Other  gastrointestinal  agents 

Hormones  and  synthetic  substitutes,  total 

Corticosteroids,  total 

Hydrocortisone 


1,000 
pounds 


39,904 


36,320 

32,355 

29,089 

3,266 

3,965 

1,759 

971 

31 

42 

9 

889 

788 

223 


162 
1,548 
1,179 

369 
54 


105 
38 


2,662 
11,255 


32 
9,866 
1,335 

1,021 

43,183 


143 

31,146 

10,402 

1,492 

1,381 


1,000 
pounds 


392 

34,998 


32,859 
29,091 
26,169 
2,922 
3,768 


527 


169 
1,361 
1,272 


(9) 


2,938 


2,741 
101 


6,812 


5,579 
1,233 


1,022 
44,627 


32,459 

10,658 

1,510 


1,000 
dollars 
1,233 
552 
347 

11,731 


11,731 
34,739 


21,726 
17,165 
14,380 
2,785 
4,561 


2,128 
289 

1,839 
899 


899 
5,237 
3,344 

762 

1,131 

4,749 

82 

4,667 

10,169 


753 

471 


471 
282 


5,036 
4,380 


3,286 


2,177 
1,109 


1,613 
19,084 


5,423 
10,368 
3,293 

26,893 


21,713 
2,109 


See  footnotes  at  end  of  table. 


34 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 
TABLE  13A. — Medicinal  chemicals;   U.S.  production  and  sales ,  19651 Continued 


Quantity 


Unit 
value  2 


Hormones  and  synthetic  substitutes—Continued 
Corticosteroids-- Continued 

All  other 

Estrogens 

Synthetic  hypoglycemic  agents 

Other  hormones  and  synthetic  substitutes 

Renal-acting  and  edema-reducing  agents,   total 

Mercurial  diuretics 

Theobromine  and  theophylline  derivatives,    total- 

Aminophylline 

All  other 

Other  renal-acting  and  edema-reducing  agents 

Therapeutic  nutrients,  total 

Amino  acids  and  salts,  total 

Glutamic  acid 

All  other 

Calcium  gluconate 

Other  therapeutic  nutrients 

Vitamins,  total 

Ascorbic  acid  and  derivatives,  total 

Ascorbic  acid 

All  other 

B-complex  vitamins: 

Cyanocobalamin  (all  grades)10 

Niacin  (all  grades) 

Niacinamide 

Pantothenic  acid  and  derivatives,  total 

Calcium  pantothenate  (racemic)  (all  grades)- 

All  other 

Riboflavin  (all  grades) 

Cholecalciferol  (Vitamin  D3)  10 

Ergocalciferol  (Vitamin  D2)  10 

Menadione 

Menadione  sodium  bisulfite 

Vitamin  A  alcohol  and  esters,  total10 

Vitamin  A  palmitate  (feed  grade) 

All  other 

Other  vitamins 

Miscellaneous  medicinal  chemicals,  total11 

Anticoagulants 

All  other 


1,000 
pounds 


27 
1,139 

205 

1,284 


101 


1,174 
3,203 


1,927 

75 

1,852 

656 

620 

16,297 


8,629 
7,274 
1,355 


1,828 

889 

1,610 

1,252 

358 

958 


59 

77 

677 

464 

213 

1,569 

463 


10 
453 


1,000 
pounds 


38 

20 

337 


1,000 

dollars 

19,604 

688 

1,189 

3,303 

7,913 


2,374 


1,334 
56 

1,278 
524 
516 

12,028 


6,089 
4,903 
1,186 


1,461 

858 

1,310 

1,055 

255 

599 

2 


73 

613 

419 

194 

1,021 

261 


28 
262 


262 
7,623 


2,842 


1,879 
345 
529 

65,366 


11,978 
9,349 
2,629 

8,324 
1,812 
1,754 
2,967 
1,780 
1,187 
6,214 
520 
180 

578 
17,249 
8,642 
8,607 
13,790 

5,099 


775 
4,324 


Per 

pound 

$515.89 

34.40 

3.53 

1,101.00 

42.77 


28.00 
2.47 


2.47 
97.73 


TT48" 


,324.00 

1.24 

2.04 

2.26 

1.69 

4.65 

10.37 

260.00 

180.00 

7.92 
28.14 
20.63 
44.37 
13.51 

19.54 


155.00 
16.89 


1  The  data  on  production  and  sales  are  for  bulk  medicinal  chemicals;  they  exclude   finished  preparations  and  dosage- 
form  products  which  are  manufactured  from  bulk  chemicals.  All  quantities  are  given  in  terms  of  100$  active  ingredient. 

2  Calculated  from  rounded  figures. 

3  The  term  "benzenoid,"  as  used  in  this  report,  describes  any  cyclic  medicinal  chemical  whose  molecules  contain 
either  a  6-membered  carbocyclic  ring  with  conjugated  double  bonds  (e.g.,  the  benzene  ring  or  the  quinone  ring)  or  a 
6-membered  heterocyclic  ring  with  1  or  2  hetero  atoms  and  conjugated  double  bonds,  except  the  pyrimidine  ring  (e.g., 
the  pyridine  ring  or  the  pyrazine  ring) . 

**  Includes  antibiotics  of  unknown  structure. 


MEDICINAL  CHEMICALS 


35 


Footnotes  for  table  13A — Continued 


5  All  quantities  for  antibiotics  were  reported  in  terms  of  grams  of  antibiotic  base  or  U.S. P.  units,  but  are  shown 
in  the  table  in  pounds.  Statistics  for  all  individually  publishable  antibiotics  are  shown  below  in  terms  of  kilograms 
of  antibiotic  base  (Kg.)  or  billions  of  U.S. P.  units  (BU): 


Quantity 


Bacitracin  (BU),  total 

For  medicinal  use 

For  other  uses 

Neomycin  (Kg.),  for  all  uses 

Penicillins  (BU),  total 

Penicillin  G,  potassium,  for  medicinal  use- 
Penicillin  G,  procaine,  total 

For  medicinal  use 

For  other  uses 

Other  penicillins,  for  medicinal  use 

Streptomycin  (Kg.),  for  medicinal  use 

Tetracyclines  (Kg.),  for  all  uses 


3,054 


169 
2,885 


76,332 
1,343,126 


383,402 
689,433 
365,587 
323,846 
270,291 

213,242 
1,156,705 


3,159 


169 
2,990 


31,783 
773,372 


236,822 
482,669 


53,881 


176,398 
472,551 


1.000 
dollars 
3,840 


897 
2,943 


1,831 
16,444 


3,343 
7,105 


3,539 
29,089 


$1,215.57 


5,307.69 
984.28 


14.12 
14.72 


20.06 
61.56 


6  Production  of  epinephrine  salts  amounted  to  374  pounds;  sales  amounted  to  370  pounds. 

7  Includes  2  or  more  of  the  following  6  drugs  which  are  subject  to  Federal  control  under  the  Drug  Abuse  Control 
Act:  Chlordiazepoxide  hydrochloride,  diazepam,  ethchlorvynol,  ethinamate,  glutethimide,  and  methyprylon.  U.S.  pro- 
duction of  these  6  drugs  amounted  to  524  thousand  pounds  in  1965. 

8  Includes  production  and  sales  of  anesthetics  and  antitussives;  also  includes  sales  of  "all  other"  anticonvul- 
sants, hypnotics,  and  sedatives. 

9  Sales  of  ethylmorphine  hydrochloride  amounted  to  450  pounds. 

10  The  following  tabulation  shows  statistics  for  vitamins  A,  Bi2,  D2,  and  D3  in  terms  of  kilograms  (Kg.)  or  bil- 
lions of  U.S. P.  units  (BU): 


Production 

Sales 

Quantity 

Value 

Unit  value 

Cholecalciferol  (Vitamin  D3)  (BU) 

20,552 
598,264 

29,676 

660 

16,233 

541,147 

1,000 
dollars 

520 

8,324 

180 

17,249 

$17.52 

12,612.12 

11.09 

31.62 

Ergocalciferol  (Vitamin  D2)  (BU) 

Vitamin  A  alcohol  and  esters  (BU),  total 

382,665 
215,599 

345,165 
195,982 

8,642 
8,607 

25.04 
42.96 

Includes  diagnostic  agents,  hematological  agents,  smooth-muscle  relaxants,  and  miscellaneous  unclassified  me- 
dicinal chemicals. 


36 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


Flavor  and  Perfume  Materials 


Flavor  and  perfume  materials  are  organic  chemicals  used  in  the  manufacture  of  foods, 
beverages,  cosmetics,  and  soaps.  Aromatic  organic  chemicals  are  utilized  to  neutralize  or  to 
mask  unpleasant  odors  in  industrial  processes  and  products  as  well  as  in  consumer  products. 
Most  of  them  have  desirable  flavors  or  odors,  and  some  have  the  ability  to  enhance  natural 
flavors  when  added  to  certain  foods.  This  report  includes  data  on  materials  derived  from 
natural  products  by  actual  chemical  processes  and  from  coal  tar;  it  does  not  include  data  on 
purely  natural  products,  such  as  floral  essences,  essential  oils,  and  other  materials  that  are 
obtained  by  simple  extraction  or  by  distillation  from  natural  plant  and  animal  sources. 

The  flavor  and  perfume  materials  covered  in  this  report  are  grouped  as  either  cyclic  or 
acyclic  materials,  according  to  their  chemical  structure.  Cyclic  materials  are  further  classified 
as  (1)  benzenoid  and  naphthalenoid,  and  (2)  terpenoid,  heterocyclic,  and  alicyclic.  Statistics  on 
production  and  sales  of  flavor  and  perfume  materials  in  1965  are  given  in  table  14A.5 

Production  of  flavor  and  perfume  materials  in  1965  amounted  to  99.2  million  pounds--9.6 
percent  more  than  the  output  of  90.6  million  pounds  in  1964.  Sales  in  1965  amounted  to  87.7 
million  pounds,  valued  at  $85.0  million,  compared  with  80.0  million  pounds,  valued  at  $83.7 
million,  in  1964. 

Production  of  cyclic  flavor  and  perfume  materials  in  1965  amounted  to  53.2  million  pounds-- 
7.4  percent  more  than  the  49.6  million  pounds  reported  for  1964.  Sales  of  cyclic  flavor  and  per- 
fume materials  in  1965  were  44.6  million  pounds,  valued  at  $56.8  million,  compared  with  41.2 
million  pounds,  valued  at  $56.6  million,  in  1964.  The  individual  chemical  in  the  cyclic  group  that 
was  produced  in  the  greatest  volume  in  1965  was  methyl  salicylate  (4.7  million  pounds).  In  1965, 
production  of  synthetic  sweeteners,  as  a  group,  amounted  to  12.8  million  pounds,  representing 
an  increase  of  only  5.1  percent  over  production  in  1964,  compared  with  an  increase  in  1964  of 
113.7  percent  over  production  in  1963. 

The  output  of  acyclic  flavor  and  perfume  materials  in  1965  amounted  to  46.0  million  pounds-- 
12.2  percent  more  than  the  41.0  million  pounds  reported  for  1964.  By  far  the  most  important  of 
the  acyclic  materials  in  1965  was  monosodium  glutamate,  a  flavor- enhancing  chemical,  produc- 
tion of  which  totaled  43.1  million  pounds.  Sales  of  acyclic  flavor  and  perfume  materials  in  1965 
amounted  to  43.1  million  pounds,  valued  at  $28.2  million,  compared  with  38.8  million  pounds, 
valued  at  $27.2  million,  in  1964. 

TABLE  14A. — Flavor  and  perfume  materials:  U.S.  production  and  sales ,  1965 

[Listed  below  are  all  synthetic  organic  flavor  and  perfume  materials  for  which  any  reported  data  on  production  or 
sales  may  be  published.    (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  pub- 
lished or  where  no  data  were  reported.)   Table  1AB  in  pt.   Ill  lists  alphabetically  all  flavor  and  perfume  materials 
for  which  data  on  production  or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Production 


Quantity 


Unit 
value1 


Grand  total- 


99,224 


87,703 


1,000 
dollars 
84, 980 


Pur 
pound 


$0.96 


FLAVOR  AND  PERFUME  MATERIALS,    CYCLIC 


53,223 


44,559 


56,800 


id  and  Naphthale 


Total- 


24,087 


22,365 


25,307 


1.13 


4-Allylveratrole  (Eugenyl  methyl  ether)  - 

Anethole  ( p-Propenylanisole) 

p-Anisaldehyde  ( p-Methoxybenzaldehyde) -- 

Benzophenone2 

Benzyl  acetate 

Benzyl  alcohol2 

Benzyl  cinnamate 

Benzyl  propionate 

Benzyl  salicylate 

Cinnamaldehyde 

Cinnamyl  alcohol 


1,904 

963 

179 

1,324 

3,955 

13 
190 
908 
184 


8 

22 

1,489 

1,053 

922 

1,292 

122 

122 

1,325 

534 

3,725 

1,399 

4 

U 

12 

13 

182 

234 

893 

633 

161 

225 

2.97 

.71 

1.40 

1.00 

.40 

.38 

3.78 

1.11 

1.29 

.71 

1.40 


See  footnotes  at  end  of  table. 


5  See  also  table  14B,  pt.  Ill,  which  lists  these  products  alphabetically  and  identifies  the  manufacturers,  and  table  23  in  the  appendix,  which 
shows  imports  of  benzenoid  flavor  and  perfume  materials  during  the  years  1964-65. 


FLAVOR  AND  PERFUME  MATERIALS 


37 


TABLE  14A. -- Flavor  and  perfume  materials;  U.S.  production  and  sales ,  i365--Continued 


FLAVOR  AND  PERFUME  MATERIALS,   CYCLIC— Continued 

Benzenoid  and  Naphthalenoid—  Continued 

Eugenol 

Isobutyl  phenylaoetate  (Isobutyl a-toluate) 

Isobutyl  salicylate 

Isoeugenol 

Isopentyl  salicylate  (Amyl  salicylate) 

p-Isopropyl-a-methylhydrocinnamaldehyde  (Cyclamen  aldehyde) 

Methyl  anthranilate 

a-Methylcinnamaldehyde 

Methyl  cinnamate 

Methyl  salicylate  (Synthetic  wintergreen  oil) 

a-Pentylcinnamaldehyde  (a-Amylcinnamaldehyde) 

Phenethyl  acetate 

Phenethyl  isobutyrate 

Phenethyl  phenylacetate  (Phenethyl  a-toluate) 

3-Phenyl-l-propanol  (Hydrocinnamic  alcohol) 

All  other  benzenoid  and  naphthalenoid  materials 

Terpenoid,    Heterocyclic,    and  Alicyclic 
Total 

Cedryl  acetate 

Citral  (Geranial) 

Citronellol 

Citronellyl  acetate 

Citronellyl  formate 

Coumarin 

Essential  oils,  chemically  modified 

Geraniol 

Geranyl  acetate 

Hydroxycitronellal 

Ionones 

Isobornyl  acetate 

Menthol,  synthetic,  tech.  and  U.S.P 

Methylionones 

Nerol 

Piperonal  (Heliotropin) 

Rhodinol 

Sweeteners,  synthetic 

Terpineols 

Terpinyl  acetate 

Vetivenyl  acetate 

All  other  terpenoid,  heterocyclic,  and  alicyclic  materials- 

FLAVOR  AND  PERFUME  MATERIALS,  ACYCLIC 

Total 

Allyl  hexanoate  (Allyl  caproate) 

Ethyl  butyrate 

Ethyl  nonanoate  (Ethyl  pelargonate) 

Glutamic  acid,  monosodium  salt  (Monosodium  glutamate) 

Isopentyl  butyrate  (Amyl  butyrate) 

Isopentyl  formate  (Amyl  formate) 

Lauraldehyde  (Dodecyl  aldehyde) (C12) 

All  other  acyclic  materials 

1  Calculated  from  the  unrounded  figures. 

2  Includes  some  technical  grade. 


Production 


1,000 
pounds 


4,675 
527 


8,235 


29,136 


46,001 


57 
248 


43,121 
45 


2,528 


Quantity 


1,000 

1,000 

pounds 

dollars 

350 

620 

17 

17 

54 

49 

107 

302 

409 

295 

184 

512 

177 

323 

11 

21 

64 

126 

4,121 

1,850 

451 

624 

73 

74 

6 

14 

12 

39 

18 

33 

7,468 

W,867 

22,194 


125 

122 

252 

171 

80 

286 

555 

460 

737 

29 

29 

51 

25 

21 

53 

1,016 

963 

2,157 

146 

136 

152 

634 

602 

828 

76 

67 

117 

454 

386 

1,553 

262 

248 

830 

942 

910 

346 

381 

384 

1,357 

446 

444 

1,790 

25 

15 

76 

256 

272 

574 

12 

11 

312 

12,841 

10,133 

8,971 

3,418 

3,105 

920 

586 

578 

329 

33 

25 

565 

6,703 

3,203 

9,237 

43,144 


58 

294 


40,366 
58 


19 
2,345 


31,493 


28,180 


216 

201 

7 

25,530 

46 

2 

105 

2,073 


38 


SYNTHETIC  ORGANIC  CHEMICALS.  1965 


Plastics  and  Resin  Materials 


Plastics  and  resin  materials  are  condensation  or  polymerization  products  of  organic  chemi- 
cals containing  necessary  fillers,  plasticizers,  and  extenders.  At  some  stage  in  their  manufac- 
ture they  exist  in  such  physical  condition  that  they  can  be  shaped  or  processed  by  the  application 
of  heat  and  pressure.  Some  types  of  plastics  may  be  molded,  cast,  or  extruded  into  finished  or 
semifinished  forms.  Other  types  are  used  as  adhesives,  for  the  treatment  of  textiles  and  paper, 
and  for  protective  coatings.  Still  other  types  of  plastics  materials  may  be  processed  into  sheets, 
rods,  and  tubes,  which  are  further  manufactured  into  finished  articles.  Except  for  vinyl  resins, 
the  statistics  given  in  the  following  tables  are  based  on  the  total  weight  of  the  materials,  exclud- 
ing liquids.    Statistics  for  vinyl  resins  are  given  on  the  basis  of  resin  content. 

Statistics  on  production  and  sales  of  plastics  and  resins  in  1965  are  given  in  table  15A6 
according  to  chemical  composition  and  broad  end  uses.    In  general,    this  table  follows  the  outline 

TABLE  15A, — Plastics  and  resin  materials ;    U.S.  production  and  sales,  by  chemical  classes 

and  uses,  1965 

[Quantities  and  values  are  given  in  terms  of  the  total  weight  of  the  materials  (dry  basis).  Listed  below  are  all 
plastics  and  resin  materials  for  which  any  reported  data  on  production  or  sales  may  be  published.  (Leaders  are 
used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were  reported.) 
Table  15B  in  pt.  Ill  lists  all  plastics  and  resin  materials  for  which  data  on  production  or  sales  were  reported 
and  identifies  the  manufacturer  of  each] 


Kind  and  use 


Quantity 


Unit 
value1 


Grand  total 

Plastics  and  resin  materials,  benzenoid 

Plastics  and  resin  materials,  nonbenzenoid 

THERMOSETTING  RESINS 

Total 

Alkyd  resins,  total 

Protective  coatings: 

Phthalic  anhydride  type,  total 

Unmodified 

Modified 

Polybasic  acid  type 

All  other  uses3 

Sales  for  export 

Coumarone-indene  and  petroleum  polymer  resins,  total- 
Floor  tile 

Rubber  compounding 

All  other  uses 

Sales  for  export 

Epoxy  resins: 

Unmodified,  total 

Bonding  and  adhesives 

Protective  coatings 

Reinforced  plastics 

All  other  uses 

Sales  for  export 

Modified 

Polyester  resins,*  total 

Reinforced  plastics: 

Sheets,  flat  and  corrugated 

All  other 

Surface  coatings 

All  other  uses 

Sales  for  export 


1,000 
pounds, 

11, 684-,  875 


4,452,975 
7,231,900 


3,236,701 


639,577 


562,618 

412,648 

149,970 

59,365 

17,594 


324,309 


84,727 

65,631 

173,951 


110,663 


8,559 
398,884 


1,000 
pounds, 

10,052,766 


1,000 
dollars 
2,504,433 


3,689,722 
6,363,044 


2,550,863 


873,501 
1,630,932 


662,392 


334,856 


88,679 


273,148 

207,438 

65,710 

46,701 

9,407 

5,600 

309,494 


74,289 

63,271 

144,623 

27,311 


105,681 
10,124 
48,080 
17,499 
19,224 
10,754 
2,935 

343,605 


73,167 
54,578 
18,589 
10,282 
3,536 
1,694 

30,569 


58,180 


3,390 
99,331 


32,841 

219,725 

6,500 

75,641 


pound 


.24 
.26 


See  footnotes  at  end  of  table. 


6  See  also  table  15B,  pt.  Ill,  which  lists  these  products  according  to  chemical  composition,  and  identifies  the  manufacturers. 


PLASTICS  AND  RESIN  MATERIALS 

TABLE  15A.-- Plastics  and  resin  materials .-   U.S.  production  and  sales,  by  chemical  classes 
and  uses,  i 965- -Continued 


39 


Kind  and  use 


THERMOSETTING  RESINS— Continued 

Phenolic  and  other  tar  acid  resins,  total 

Molding  materials 

Bonding  and  adhesive  resins  for— 

Laminating 

Coated  and  bonded  abrasives 

Friction  materials 

Thermal  insulation 

Foundry  or  shell  molding 

Plywood 

Fibrous  and  granulated  wood 

All  other  bonding  and  adhesive  uses 

Protective  coatings,  unmodified  and  modified-- 

All  other  uses 

Sales  for  export 

Polyurethane  and  diisocyanate  resins 

Rosin  modifications,  total 

Rosin  and  rosin  esters,  unmodified  (ester  gums 
All  other 

Urea  and  melamine  resins,  total 

Textile  treating  and  coating  resins 

Paper  treating  and  coating  resins 

Bonding  and  adhesive  resins  for — 

Laminating 

Plywood 

Fibrous  and  granulated  wood 

All  other  bonding  and  adhesive  uses 

Protective  coatings 

All  other  uses  (including  molding) 

Sales  for  export 

All  other  thermosetting  resins6 

THERMOPLASTIC  RESINS 

Total 

Cellulose  plastics  materials,  total 

Sheets ,  continuous : 

Under  0.003  gage 

0.003  gage  and  over 

All  other  sheets,  rods,  and  tubes 

Molding  and  extrusion  materials 

Polyamide  resins,  total ' 

Nylon  type 

Non-nylon  type 

Styrene-type  plastics  materials: 

Production  and  sales 

Used  by  reporting  companies  in  processing 

Sales  and  use,  total 

Molding 

Textile  and  paper  treating  and  coating 

Emulsion  paint 

Extrusion 

All  other  uses 

Sales  for  export 

Vinyl  resins  (resin-content  basis): 
Polyvinyl  acetate  resins: 

Production  and  sales 

Used  by  reporting  companies  in  processing — 

See  footnotes  at  end  of  table. 


921,753 


274,193 

132,732 
27,024 
32,623 

120,626 
68,782 

117,832 
31,815 
32,176 
34, 8H 
49,136 


66,209 
102,962 


Quantity 


62,279 
40,683 


621,179 


65,703 
50,758 

51,764 

135,125 

117,102 

15,138 

58,515 

127,074 


42,606 


8,448,174 


169,476 


24,104 

38,342 

8,316 

98,714 

92,076 


73,415 
18,661 


2,033,147 


313,160 


1,000 
pounds, 

dry 
basis' 

744,657 


246,140 

79,109 
22,013 
28,102 
52,576 
66,651 
110,589 
28,051 
28,580 
24,678 
44,164 
14,004 

55,443 

101,249 


1,000 
dollars 
178,799 


61,735 
39,514 


517,698 


31,226 
20,115 


59,571 
34,698 

34,686 
115,162 
103,054 

15,306 

35,373 
103,103 

16,745 

35,245 


7,501,903 


163,095 


24,350 

35,945 

8,921 

93,879 

73,383 


55,916 
17,467 


1,836,246 

184,245 

2,020,491 

1,063,005 

153,169 

43,062 

310,986 

325,843 

124,426 


220,354 
62,923 


11,321 
8,794 


129,227 


Unit 
value1 


pound 


22,876 


1,842,041 


107,825 


65,376 
54,884 
10,492 


383,318 


67,974 


TABLE  15A.--Plastics  and  resin  materials.-   U.S.  production  and  sales,  by  chemical  classes 
and  uses,  1965 — Continued 


Kind  and  use 


THERMOPLASTIC  RES  INS --Continued 

Vinyl  resins  (resin-content  basis) — Continued 
Polyvinyl  acetate  resins — Continued 

Sales  and  use,  total 

Emulsion  paint 

Adhesives 

Bonding  and  sizing 

All  other  uses 

Sales  for  export 

Polyvinyl  chloride  and  copolymer  resins: 

Production  and  sales 

Used  by  reporting  companies  in  processing 

Sales  and  use,  total 

Calendering: 

Film,  under  6  mils 

Sheet,  6  mils  and  over 

Flooring 

Coating,  bonding,  and  adhesives: 

Paper  and  textile  coating  (including  calendering)- 

Flooring 

Extrusion: 

Wire  and  cable 

Garden  hose 

All  other  extrusions 

Molding: 

Records 

Slush  and  rotational  molding 

All  other  moldings 

All  other  uses 

Sales  for  export 

All  other  vinyl  resins:  Production  and  sales 

Polyolefin  plastics  materials: 

Polyethylene,  density  0.940  and  below: 

Production  and  sales 

Used  by  reporting  companies  in  processing 

Sales  and  use,  total 

Injection  molding 

Blow  molding 

Extrusions: 

Film  and  sheet 

Wire  and  cable  coating 

Extrusion  coating  on  paper  and  other  substrates — 

Pipe 

All  other  extrusions 

All  other  uses 

Sales  for  export 

Polyethylene,  density  over  0.940: 

Production  and  sales 

Used  by  reporting  companies  in  processing 

Sales  and  use,  total 

Injection  molding 

Blow  molding 

Extrusions: 

Film  and  sheet 

Wire  and  cable  coating 

Pipe 

All  other  extrusions  (including  extrusion  coating 

and  filament) 

All  other  uses 

Sales  for  export 


1,837,467 


161,659 


Quantity 


1,000 
pounds , 

basis- 
283,277 
104,641 
111,064 
19,856 
45,074 
2,642 

1,715,321 

140,337 

1,855,658 

83,626 

250,374 
262,282 

180,884 
68,507 

217,214 
11,367 
254,781 

89,552 
43,070 
30,993 
294,913 
68,095 
9   154,936 


262,922 

2,046,006 

236,885 

2,282,891 

291,091 

40,468 

938,193 

215,946 

282,610 

19,381 

12,282 

179,326 

303,594 

784,441 

649,084 

90,835 

739,919 

130,111 

272,769 

37,539 

22,600 

29,759 

26,302 

133,254 

87,585 

1,000 
dollars 


Unit 
value 


$0.17 


78,915 


344,431 


119,861 


See  footnotes  at  end  of  table. 


PLASTICS  AND  RESIN  MATERIALS 

TABLE  15A. — Plastics  and  resin  materials;    U.S.  production  and  sales,  by  chemical  class 
and  uses,  1 965- -Continued 


Kind  and  use 


Quantity 


Unit 
value1 


THERMOPLASTIC  RESINS— Continued 

Polyolefin  plasties  materials — Continued 
Polypropylene : 

Production  and  sales 

Used  by  reporting  companies  in  processing — 

Sales  and  use,  total 

Molding 

Extrusion 

All  other  uses   (including  export) 

All  other  thermoplastic  resins   ° 


1,000 
pounds, 

basis2 
374,067 


419,759 


1,000 
pounds, 

basis2 
300,934 
75,671 
376,605 
182,712 
135,991 
57,902 
342,544 


1,000 
dollars 
64,831 


312,321 


$0.22 


1  Calculated  from  rounded  figures. 

2  For  the  purpose  of  this  report,  "dry  basis"  is  defined  as  the  total  weight  of  the  material,  including  resin, 
plasticizers,  fillers,  extenders,  colors  and  stabilizers,  and  excluding  water,  solvents,  and  other  liquid  diluents. 

3  Includes  saturated  polyesters  for  urethanes. 

The  term  "polyester  resins"  includes  unsaturated  alkyds  copolymerized  with  a  monomer  such  as  styrene,  and 
polyallyl  resins  such  as  diallyl  phthalate  and  allyl  diglycol  carbonate. 

5  Includes  448,650  thousand  pounds  of  urea-formaldehyde  type,  and  172,529  thousand  pounds  of  melamine-formaldehyde 
type. 

6  Includes  data  for  acetone -formaldehyde  resins,  styrene-alkyd  polyesters,  toluenesulfonamide  resins,  silicone 
resins,  and  other  thermosetting  resins,  which  were  produced  in  small  quantities. 

Includes  straight  polystyrene,  728,435  thousand  pounds;  rubber  modified  polystyrene,  641,884  thousand  pounds; 
styrene-butadiene  copolymers,  253,146  thousand  pounds;  and  all  other,  including  ABS  and  SAN,  409,682  thousand 
pounds . 

8  Includes  37,373  thousand  pounds  of  polyvinyl  alcohol. 

Data  for  intra-company  consumption  may  not  be  shown  separately,  and  are  included  with  sales  at  an  estimated  unit 
value . 

10  Includes  data  for  acrylic,  fluorocarbon,  polycarbonate,  polyoxymethylene,  polyterpene,  and  other  thermoplastic 
resins. 


of  the  Tariff  Commission's  monthly  report  on  the  production  and  sales  of  synthetic  plastics  and 
resin  materials  (S.  O.  C.   Series  P-65).    However,   data  are  included  for  plastics  materials  which 
are  not  covered  in  the  monthly  report  and  for  a  number  of  smaller  producers  that  do  not  report 
monthly.    The  monthly  data  for  1965,   moreover,   were  returned  to  the  reporting  companies  for 
verification  or  correction.   In  consequence,   many  of  the  figures  in  the  following  table  are  revised 
from  those  shown  in  the  monthly  release  of  March  23,    1966,   which  contained  yearend  cumulative 
totals  for  1965.    The  figures  in  the  thermoplastics  section  of  the  table  under  "Used  by  reporting 
companies  in  processing"  represent  captive  use  of  the  materials.    The  quantities  reported  under 
"Sales  and  use"  in  this  section  include  data  for  captive  consumption,   and  for  outside  sales  as 
defined  in  the  introduction  to  this  volume. 

In  1965,    total  U.S.    production  of  synthetic  plastics  and  resin  materials,   including  cellu- 
losics,   amounted  to  11,  685  million  pounds,    or  15.  7  percent  more  than  the  10,  103  million 
pounds  reported  for  1964.   Sales  of  synthetic  plastics  and  resin  materials  in  1965  amounted  to 
10,  053  million  pounds,   valued  at  $2,  504  million.    Production  of  benzenoid  plastics  and  resin 
materials  in  1965  amounted  to  4,453  million  pounds,   and  that  of  nonbenzenoid  materials,    to 
7,  232  million  pounds.    These  figures  compare  with  production  in  1964  of  3,  915  million  pounds, 
and  6,  188  million  pounds,    respectively.    Production  of  all  thermosetting  resins  in  1965  was 
3,237  million  pounds,   and  that  of  thermoplastic  resins  was  8,448  million  pounds. 

In  1965,   polyethylene,   polystyrene,   and  polyvinyl  chloride  resins  were  the  materials 
produced  in  the  largest  volume.    The  total  output  of  high-density  and  low-density  polyethylene 
resins  in  1965  amounted  to  3,  047  million  pounds,    compared  with  2,  613  million  pounds  in  1964. 
Sales  of  polyethylene  resins  in  1965  were  2,  695  million  pounds,   valued  at  $464  million.    Produc- 
tion of  styrene-type  plastics  materials  in  1965  was  2,  033  million  pounds,   compared  with  1,  728 
million  pounds  in  1964.   Sales  of  such  materials  in  1965  were  1,  836  million  pounds,   valued  at 
$383  million.    The  output  of  polyvinyl  chloride  and  copolymer  resins  in  1965  amounted  to  1,  837 
million  pounds,    compared  with  1,  637  million  pounds  in  1964.    Sales  of  polyvinyl  chloride  resins 
in  1965  totaled  1,  715  million  pounds,   valued  at  $297  million.    Other  synthetic  plastics  and  resin 
materials  produced  in  1965  in  large  volume  were  phenolic  and  other  tar  acid  resins  (922  million 
pounds),   alkyd  resins  (640  million  pounds),   urea  and  melamine  resins  (621  million  pounds), 
polyester  resins  (399  million  pounds),   coumarone-indene  and  petroleum  polymer  resins  (324 
million  pounds),   and  polyvinyl  acetate  resins  (313  million  pounds). 


42 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


Rubber-Processing  Chemicals 

Rubber-processing  chemicals  are  organic  compounds  that  are  added  to  natural  and  synthetic 
rubbers  to  give  them  qualities  necessary  for  their  conversion  into  finished  rubber  goods.    In  this 
report,    statistics  are  given  for  cyclic  and  acyclic  compounds,   by  use--such  as  accelerators, 
antioxidants,   and  peptizers.   Statistics  on  production  and  sales  of  rubber-processing  chemicals 
in  1965  are  given  in  table   16A.7 

Production  of  rubber-processing  chemicals  as  a  group  in  1965  amounted  to  252  million 
pounds,   compared  with  the  261  million  pounds  reported  for  1964.    This  apparent  decrease  in  1965 
production  was  due  principally  to  the  reclassification  of  sodium  2-mercaptobenzothiazole  (2- 
benzothiazolethiol,    sodium  salt)  from  rubber-processing  chemicals  to  cyclic  intermediates. 
Sales  of  rubber-processing  chemicals  in  1965  amounted  to  194  million  pounds,    valued  at  $123 
million,    compared  with  184  million  pounds,    valued  at  $123  million,    in  1964. 

TABLE  16A. — Rubber-processing  chemicals.-  U.S.  production  and  sales ,  1965 

[Listed  below  are  all  rubber-processing  chemicals  for  which  any  reported  data  on  production  or  sales  may  be  pub- 
lished.   (Leaders  are  used  where  the  reported  data  are  accepted   in  confidence  and  may  not  be  published  or  where 
no  data  were  reported. )  Table  16B  in  pt.    Ill  lists  separately  all  rubber-processing  chemicals  for  which  data  on 
production  or  sales  were  reported   and  identifies  the  manufacturer  of  each] 


Quantity 


Unit 
value1 


Grand  total 

RUBBER-PROCESSING  CHEMICALS,    CYCLIC 
Total 

Accelerators,   activators,   and  vulcanizing  agents,   total 

Aldehyde-amine   reaction  products 

Dithiocarbamic  acid  derivatives 

Thiazole  derivatives,  total 

N-Cyclohexyl-2-benzothiazolesulfenamide 

2,2'-Dithiobis(benzothiazole) 

All  other 

All  other  accelerators 

Antioxidants,  antiozonants,  and  stabilizers,  total 

Amino  antioxidants,  antiozonants,  and  stabilizers,  total 
Aldehyde-  and  acetone-amine  reaction  products ,  total — 

Diphenylamine -ace tone  condensate 

All  other 

Substituted  p-phenylenediamines,  total 

NjN'-Diphenyl-p-phenylenediamine 

All  other 

Octyldiphenylamine 

All  other  amino  antioxidants,  antiozonants,  and 

stabilizers 

Phenolic  and  phosphite  antioxidants  and  stabilizers, 

total 

Phenol,  alkylated 

All  other  phenolic  and  phosphite  antioxidants  and 

stabilizers 

Blowing  agents 

Peptizers 

All  other  cyclic  rubber-processing  chemicals,  total 

N-Nitrosodiphenylamine  (retarder) 

All  other3 

See  footnotes  at  end  of  table. 


251,945 


193,718 


1,000 
dollars 
123,393 


211,403 


166,214 


109,204 


71,279 


55,841 


32,529 


239 
59,439 
7,228 
21,307 
30,904 
11,601 

127,537 


97,928 

9,374 

8,601 

773 

41,496 
1,732 

39,764 
2,189 

44,869 

29,609 
11,522 

18,087 

3,425 
4,950 

4,212 


1,086 

207 

44,077 

6,232 
10,805 
27,040 
10,471 

99,421 


3,224 


77,166 

7,991 

7,414 

577 

29,538 
1,479 

28,059 
1,982 

37,655 

22,255 
6,693 

15,562 

3,340 
4,404 

3,208 


971 
354 
22,907 
3,501 
5,386 
14,020 
8,297 

67,045 


2,254 
954 


50,380 

4,041 

3,594 

447 

27,249 
1,335 

25,914 
1,044 

18,046 

16,665 
3,508 

13,157 

4,698 
2,842 

2,090 


1,239 
851 


1.71 
.52 
.56 
.50 
.52 
.79 


.48 
.77 
.92 
.90 
.92 
.53 


.52 
.85 


1.41 
.65 


7  See  also  table  16B,  pt.  Ill,  which  lists  these  products  alphabetically  and  Identifies  the  manufacturers. 


ELASTOMERS  (SYNTHETIC  RUBBERS) 
TABLE  16A.  — Rubber-processing  chemicals .-  U.S.  production  and  sales,  1965 — Continued 


43 


Quantity 


Unit 
value1 


RUBBER-PROCESSING  CHEMICALS,   ACYCLIC 

Total 

Accelerators,  activators,  and  vulcanizing  agents,  total 

Dithiocarbamic  acid  derivatives,  total* 

Dibutyldithiocarbamic  acid,  zinc  salt 

Diethyldithiocarbamic  acid,  zinc  salt 

Dimethyldithiocarbamic  acid,  zinc  salt 

All  other 

Thiurams,  total5 

Bis(dimethylthiocarbamoyl)  disulfide 

Bis(dimethylthiocarbamoyl)  sulfide 

All  other 

All  other  accelerators,   activators,   and  vulcanizing 
agents 


1.000 
pounds 
40,542 


27,504 


1.000 
dollars 
14,189 


21,340 


Dodecyl  mercaptans" 

Dimethyldithiocarbamic  acid,  sodium  salt 

All  other  acyclic  rubber-processing  chemicals7 


8,575 
1,522 
1,262 
1,478 
4,313 
12,379 
7,045 
1,561 
3,773 

386 

12,551 
3,469 
3,182 


14,144 


6,557 
1,559 
861 
1,288 
2,849 
7,324 
4,708 
1,338 
1,278 

263 

10,748 

2,612 


8,834 


4,802 

1,468 

523 

570 

2,241 

3,746 

2,036 

1,088 

622 

286 

4,218 
1,137 


.44 
.79 
.51 
.43 
.81 


.44 


1  Calculated  from  rounded  figures. 

2  Not  comparable  with  data  for  previous  years  owing  to  reclassification  of  certain  products  previously  considered 
to  be  rubber-processing  chemicals. 

3  Includes  tackifiers  and  physical-property  improvers. 

4  Data  on  dithiocarbamates  included  in  this  table  are  for  materials  used  chiefly  in  the  processing  of  natural  and 
synthetic  rubbers.  Data  on  dithiocarbamates  which  are  used  chiefly  as  fungicides  are  reported  in  table  20A,  "Pesti- 
cides and  Other  Organic  Agricultural  Chemicals . " 

5  Includes  data  for  small  amounts  of  tetramethylthiuram  sulfides  for  uses  other  than  in  the  processing  of  natural 
and  synthetic  rubbers. 

6  Includes  some  detergent -grade  dodecyl  mercaptans. 

7  Includes  blowing  agents,  polymerization  regulators,  shortstops,  and  conditioning  and  lubricating  agents. 


The  output  of  cyclic  rubber-processing  chemicals  in  1965  amounted  to  211  million  pounds. 
Sales  in  1965  were  166  million  pounds,   valued  at  $109  million,    compared  with  162  million 
pounds,   valued  at  $109  million,   in  1964.    Of  the  total  output  of  cyclic  rubber-processing  chem- 
icals in  1965,   accelerators  accounted  for  33.7  percent  and  antioxidants  for  60.3  percent.    Pro- 
duction of  amino  and  phenolic  and  phosphite  antioxidants,   which  amounted  to  127.  5  million 
pounds  in  1965,   included  97.  9  million  pounds  of  amino  compounds  and  29.  6  million  pounds  of 
phenolic  and  phosphite  compounds.   Sales  of  amino  antioxidants  in  1965  were  77.2  million  pounds, 
valued  at  $50.4  million;  sales  of  phenolic  and  phosphite  antioxidants  were  22.  3  million  pounds, 
valued  at  $16.  7  million. 

Production  of  acyclic  rubber-processing  chemicals  in  1965  amounted  to  40.  5  million 
pounds,   compared  with  the  38.  1  million  pounds  reported  for  1964.   Sales  in  1965  totaled  27.  5 
million  pounds,   valued  at  $14.  2  million,    compared  with  22.  6  million  pounds,   valued  at  $14.4 
million,   in  1964.  Accelerators,   principally  dithiocarbamic  acid  derivatives  and  tetramethyl- 
thiuram sulfides,   accounted  for  52.6  percent  of  the  output  of  acyclic  rubber-processing  chemi- 
cals in  1965.  Dodecyl  mercaptans  accounted  for  31.0  percent.    Blowing  agents,   peptizers, 
modifiers,    shortstops,   and  lubricating  and  conditioning  agents  accounted  for  the  remainder  of 
the  output  in  the  acyclic  group. 


Elastomers  (Synthetic  Rubbers) 

The  synthetic  rubber  industry  in  the  United  States  continued  to  operate  at  a  high  level  of 
capacity  in  1965.    The  styrene-butadiene,   or  S-type,    rubber  is  a  general-purpose  material  used 
in  the  manufacture  of  tires  and  other  rubber  goods,   and  is  the  most  important  type  of  synthetic 
rubber,   in  terms  of  quantity  produced.   Several  other  types  of  synthetic  rubbers  are  also  pro- 
duced in  large  volume;  among  them  are  the  polybutadiene-acrylonitrile  type,  or  N-type,    the 
polybutadiene-isoprene  type,    or  Butyl-type,   neoprene,   and  stereo  elastomers. 


44  SYNTHETIC  ORGANIC  CHEMICALS,  1965 

The  total  output  of  all  types  of  elastomers  in  the  United  States  in  1965  amounted  to  3,  592  mil- 
lion pounds --somewhat  more  than  the  3,421  million  pounds  reported  for  1964.   Sales  of  elastomers 
covered  in  this  report  amounted  to  3,  041  million  pounds,    valued  at  $843  million,    in  1965,    com- 
pared with  2,  958  million  pounds,   valued  at  $810  million,    in  1964.    Statistics  on  the  production  and 
sales  of  elastomers  are  given  in  table  17A.8 

Production  of  cyclic  elastomers,    which  consisted  chiefly  of  the  polybutadiene-styrene  type 
(S-type),   amounted  to  2,300  million  pounds  in  1965,    compared  with  2,332  million  pounds  in  1964. 
Sales  of  these  elastomers  amounted  to  1,  898  million  pounds,   valued  at  $443  million,   in  1965,    com- 
pared with  1,961  million  pounds,   valued  at  $451  million,   in  1964.    Production  of  polyurethane  type 
elastomers  in  1965  amounted  to  9.  0  million  pounds. 

The  output  of  acyclic  elastomers,  including  N-type,  neoprene,  Butyl,  silicone,  and  stereo 
elastomers,  amounted  to  1,292  million  pounds  in  1965,  compared  with  the  1,  089  million  pounds 
reported  for  1964.  Sales  of  these  elastomers  amounted  to  1,  143  million  pounds,  valued  at  $401 
million,  in  1965,  compared  with  996  million  pounds,  valued  at  $359  million,  in  1964.  The  output  of 
silicone  elastomers  in  1965  amounted  to  10.  9  million  pounds,  and  that  of  stereo  elastomers,  to 
502  million  pounds. 


TABLE  17A.  — Elastomers  (synthetic  rubbers)  :x  U.S.  production  and  sales,  1965 

[Listed  below  are  all  elastomers   (synthetic  rubbers)  for  which  reported  data  on  production  or  sales  may  be  pub- 
lished.   (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where 
no  data  were  reported.)  Table  17B  in  pt.    Ill  lists  alphabetically  all  elastomers  for  which  data  on  production  or 
sales  were  reported  and  identifies  the  manufacturer  of  each] 


Qjjantity 


Unit  value2 


Grand  total 

ELASTOMERS,    CYCLIC 

Total 

Polybutadiene-styrene  type  (S-type) 

Polybutadiene-styrene-vinylpyridine  type-- 
Polyurethane  type 

ELASTOMERS,    ACYCLIC 

Total 

Polybutadiene-acrylonitrile  type  (N-type)- 

Polyisobutylene-isoprene  type  (Butyl) 

Silicone  elastomers 

Stereo  elastomers,  total 

Stereo  polybutadiene 

All  other  stereo  elastomers 

All  other  acyclic  elastomers 


3,591,654 


3,041,163 


1,000 
dollars 
843,448 


2,271,647 
19,402 
9,043 


4  1,879,568 
10,432 
7,921 


1,143,242 


427,741 
6,650 
8,331 


400,726 


149, 858 
225,392 
10, 913 


111,695 
8,535 

410,508 


52,812 
30,425 
91,314 


362,278 
139,878 


287, 090 
123,418 


62,158 
29, 156 


$0.28 


.23 

.64 

1.05 


The  term  "elastomers"  is  defined  as  substances  in  bale,  crumb,  powder,  latex,  and  other  crude  forms  which  can  be 
vulcanized  or  similarly  processed  into  materials  that  can  be  stretched  at  68°  F.  to  at  least  twice  their  original 
length  and,  after  having  been  so  stretched  and  the  stress  removed,  will  return  with  force  to  approximately  their 
original  length. 

2  Calculated  from  rounded  figures. 

3  Elastomer-content  basis. 

4  Partly  estimated. 


Note. — Statistics  on  the  production  of  S-type, 
cooperation  with  the  U.S.   Bureau  of  the  Census. 


N-type,    Butyl,   neoprene,    and   stereo  elastomers  were  compiled  in 


8  see  also  table  17B,  pt.  m,  which  lists  these  products  alphabetically  and  identifies  the  manufacturers. 


PLASTICIZERS 


45 


Plasticizers 

Plasticizers  are  organic  chemicals  that  are  added  to  synthetic  plastics  and  resin  materials  to 
(1)  improve  workability  during  fabrication,    (2)  extend  or  modify  the  natural  properties  of  these 
resins,    or  (3)  develop  new  improved  properties  not  present  in  the  original  resins.    Plasticizers  re- 
duce the  viscosity  of  the  resins  and  make  it  easier  to  shape  and  form  them  at  high  temperatures 
and  pressures.    They  also  impart  flexibility  and  other  desirable  properties  to  the  finished  product. 
Statistics  on  production  and  sales  of  plasticizers  are  given  in  table  18A.9 

TABLE  18A.  --Plasticizers:1  U.S.  production  and  sales,  1965 


[Listed  below  are  all  plasticizers  for  which  reported  data  may  be  published.    (Leaders  are  used  where  the  reported 
data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were  reported.)   Table  18B  in  pt.    Ill 
lists  all  plasticizers  for  which  data  on  production  or  sales  were  reported   and   identifies  the  manufacturer  of 
each] 


Production 


Quantity 


Unit 
value3 


Grand  total 

PLASTICIZERS,    CYCLIC 

Total 

Phosphoric  acid  esters: 

Cresyl  diphenyl  phosphate 

Tricresyl  phosphate 

Phthalic  anhydride  esters,  total 

Butyl  octyl  phthalates  ( including  butyl  2-ethyLhexyl 

phthalate) 

Dibutyl  phthalates  (including  diisobutyl  phthalate) — 

Dicyclohexyl  phthalate 

Diethyl  phthalate 

Dihexyl  phthalate 

Diisodecyl  phthalate 

Di(2-methoxyethyl)  phthalate 

Dimethyl  phthalate 

Dioctyl  phthalates,  total 

Di( 2-ethyLhexyl)  phthalate 

Diiso-octyl  phthalate 

Mixed  dioctyl  phthalates  (including  dioctyl  iso- 

phthalates) 

Ditrideeyl  phthalate 

Octyl  decyl  phthalates  (including  iso-octyl  isodecyl 

phthalate) 

All  other  phthalic  anhydride  esters 

Trimellitic  acid  esters 

All  other  cyclic  plasticizers3 

PLASTICIZERS,  ACYCLIC* 

Total- - 

Adipic  acid  esters,    total 

Di(  2- ethylhexyl)    adipate 

Diisodecyl  adipate 

Diiso-octyl  adipate  ( including  di-n-octyl  adipate) 

Octyl  decyl  adipate  ( including  iso-octyl  isodecyl 

adipate) 

All  other 

See  footnotes  at  end  of  table. 


1  000 
pounds 
1,073,197 


798,741 


19, 697 
34, 834 


678, 679 


15,052 

20,012 

7,719 

17,999 

1,702 

89, 552 

10,976 

4,408 

353, 108 

212,360 

121,589 

19,159 


25,416 
119,  847 


65,531 


274,456 


47,760 


1A,704 
9,582 
10,912 

10,065 
2,497 


1,000 

pounds 

1,021,623 


764,736 


17, 103 
37, 627 


646,366 


14, 934 
16,773 

12,035 

1,489 

89,112 

8,107 

3,937 

343,016 

211,466 

115,945 

15,605 
13,145 

25,856 
117,962 

1,981 
61,659 


256,887 


42, 950 


13,205 
8,162 


9,978 
11, 605 


214,392 


133,044 


4,447 
11,338 


97,772 


1,973 
3,1A0 

2,181 

231 

12,523 

1,669 

786 

47, 084 

28, 438 

16, 255 

2,391 
2,662 

4,41A 
21, 109 

801 
18,686 


81,348 


11,  K5 


2,989 
2,181 


2,335 
3,640 


See  also  table  18B,   pt.  Ill,   which  lists  these  products  alphabetically  and  identifies  the  manufacturers. 


SYNTHETIC  ORGANIC  CHEMICALS.  1965 


TABLE  18A.  --plasticizers.-1  U.S.  production  and  sales ,  1965  --Continued 


Production 


Quantity 


Unit 
value2 


PLASTICIZERS,   ACYCLIC— Continued 

Azelaic  aeid  esters ' 

Complex  linear  polyesters  and  polymeric  plasticizers- 

Epoxidized  esters,    total 

Epoxidized  soya  oils 

2-Ethylhexyl  epoxytallates 

Octyl  epoxytallates 

All  other5 - 

Glycerol  monoricinoleate 

Isopropyl  myristate 

Isopropyl  pa Imitate 

Oleic  acid  esters,  total 

Butyl  oleate 

Glycerol  trioleate  (Triolein) 

Isopropyl  oleate 

Methyl  oleate 

n-Propyl  oleate 

All  other6 

Phosphoric  acid  esters 

Sebacic  acid  esters: 

Dibutyl  sebacate 

Di(2-ethylhexyl)  sebacate 

Stearic  acid  esters,  total 

n- Butyl  stearate 

All  other 

Triethylene  glycol  di(caprylate-caprate) 

All  other  acyclic  plasticizers7 


13,167 
40,  265 

75,905 


49,484 


10,642 
15,779 


1,473 
1,008 

9,470 


3,106 

2,666 

168 

2,631 

698 

201 

13,851 

4,692 
5,711 


3,848 
3,848 


1,844 
51,614 


1,000 

pounds 
15,092 
37,759 

81,322 


54,158 
11,362 
9,788 
6,014 
258 
1,397 
942 

6,689 


1,681 

2,174 

139 

1,850 

664 

181 

12,197 

3,137 
5,509 

7,318 


3,540 
3,778 


1,536 
40,781 


1.000 
dollars 
4,435 
14,746 

21,450 


14,395 
2,420 
2,467 
2,168 

92 
626 

348 

1,443 


361 
475 


379 
136 


5,323 


1,908 
2,780 


1,749 


839 
910 


503 
14, 800 


.61 
.50 


.33 
.36 


1  Does  not  include  data  for  clearly  defined  extenders  or  secondary  plasticizers. 

2  Calculated  from  rounded  figures. 

3  Includes  data  for  glycol  dibenzoates,  phosphate  esters  (including  triphenyl  phosphate),  toluenesulfonamides, 
tetrahydrofurfuryl  oleate,  trimellitic  acid  esters  (production  only),  and  other  cyclic  plasticizers. 

4  Dibutyl  maleate  is  now  published  in  table  21A,  "Miscellaneous  Chemicals." 

5  Includes  several  items  that  were  included  in  earlier  reports  in  "All  other"  oleic  acid  esters. 

6  Several  items  that  were  included  here  in  earlier  reports  are  now  included  in  "All  other"  epoxidized  esters. 

7  Includes  data  for  citric  and  acetylcitric,  lauric,  myristic,  palmitic,  ricinoleic,  sebacic,  and  tartaric  acid 
esters,  glycerol  and  glycol  esters  of  certain  fatty  acids,  glycerol  tripropionate,  and  other  acyclic  plasticizers. 

Note. — The  total  production  and  sales  statistics  are  included  in  this  report  for  some  items  that  are  not  used 
exclusively  as  plasticizers. 


Total  U.S.    production  of  plasticizers  in  1965  amounted  to  1,  073  million  pounds  —  representing 
an  increase  of  12.8  percent  over  the  output  of  951  million  pounds  reported  for  1964.   Sales  in  1965 
of  the  plasticizers  covered  by  this  report  amounted  to  1,  022  million  pounds,    valued  at  $214  mil- 
lion,   compared  with  905  million  pounds,    valued  at  $187  million,   in  1964. 

Production  of  cyclic  plasticizers  in  1965,   which  consisted  chiefly  of  the  esters  of  phthalic 
anhydride  and  phosphoric  acid,   amounted  to  799  million  pounds,    compared  with  718  million  pounds 
in  1964.    Sales  of  cyclic  plasticizers  in  1965  amounted  to  765  million  pounds,    valued  at  $133  mil- 
lion,   compared  with  690  million  pounds,    valued  at  $120  million,    in  the  previous  year. 

Production  of  acyclic  plasticizers  in  1965  amounted  to  274  million  pounds,    compared  with  234 
million  pounds  in  1964.    Sales  of  acyclic  plasticizers  in  1965  amounted  to  257  million  pounds, 
valued  at  $81  million,    compared  with  215  million  pounds,    valued  at  $68  million,    in  1964.    Produc- 
tion of  complex  linear  polyesters  in  1965  amounted  to  40  million  pounds,    and  that  of  epoxidized 
esters,    to  76  million  pounds.    Other  products  included  in  the  acyclic  class  are  the  esters  of 
adipic,   azelaic,    oleic,    sebacic,   and  stearic  acids. 


SURFACE-ACTIVE  AGENTS 


47 


Surface-Active  Agents 

The  surface-active  agents  covered  in  this   report  include  anhydrous  potassium  and  sodium 
soaps,    synthetic  organic  detergents,    and  dispersing,  emulsifying,    and  wetting  agents   that  function 
in  either  aqueous  or  nonaqueous  systems.   Waxes  and  plasticizers  are  not  included.    The  data  are 
reported  in  terms  of  100-percent  organic,    surface-active  ingredient,    and  thus    exclude  all  inor- 
ganic salts,   water,   and  other  diluents.   A  major  part  of  the  output  of  surface-active  agents  is  con- 
sumed in  the  form  of  packaged  soaps  and  detergents  for  household  and  industrial  use.    The  re- 
mainder is  used  as  dispersing,    emulsifying,    foaming,    penetrating,    and  wetting  agents  in  the  proc- 
essing of  textiles  and  leather,   in  ore  flotation  and  oil-drilling  operations,    and  in  the  manufacture 
of  agricultural  sprays,   cosmetics,    elastomers,   foods,    lubricants,   paints,   pharmaceuticals,   and 
many  other  products. 

Statistics  on  U.S.    production  and  sales  of  surface-active  agents  in  1965  are  given  in  table 
19A.10  Total  production  of  surface-active  agents  in  1965  amounted  to  3,  170  million  pounds.    This 


TABLE  19A. — Surface-active  agents ;  U.S.  production  and  sales,  1965 

[Listed  below  are  all  surface-active  agents  for  which  reported  data  on  production  or  sales  may  be  published. 
(Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were 
reported.)  Table  19B  in  pt.    Ill  lists  all  surface-active  agents   for  which  data  on  production  or  sales  were  reported 
and  identifies  the  manufacturer  of  each] 


Production1 


Sales" 


Quantity1 


Unit 
value3 


Grand  total 

Amphoteric 

Anionic 

Cationic 

Nonionic 

BENZENOID  SURFACE-ACTIVE  AGENTS 

Total - 

Not  Sulfated  or  Sulfonated 
Total 

Amides,  amines,  and  quaternary  ammonium  salts,  total — 

Benzyldimethyl(  mixed  alky 1) ammonium  chloride 

Benzyldimethyloctadecylammonium  chloride 

Benzyldodecyldimethylammonium  chloride 

(3,4-Dichlorobenzyl)  dodecyldimethylammonium  chloride- 

( Dodecylbenzyl) trimethylammonium  chloride 

Heterocyclic  compounds,  total 

l-Benzyl-2-heptadecyl-l-(2-hydroxyethyl)-2-imidazo- 
linium  chloride-; 

All  other 

Oxygen- containing  compounds  (except  heterocyclic) 

All  other 

Carboxylic  acid  esters  and  ethers,  total 

Dinonylphenol,  ethoxylated 

Dodecylphenol,  ethoxylated 

Iso-octylphenol,  ethoxylated 

Nonylphenol,  ethoxylated 

Phenol,  ethoxylated 

Other  carboxylic  acid  esters  and  ethers 

Phosphoric  and  polyphosphorie  acid  esters,  total 

Nonylphenol,  ethoxylated  and  phosphated 

All  other 

See  footnotes  at  end  of  table. 


1,000 

pounds 

3,170,478 


5,112 

2,358,173 

148, 001 

659, 192 

1,371,320 


246,024 


8,127 


3,859 
378 
662 
46 
187 
637 

53 
584 
710 


232, 610 


3, 
19,645 
1,940 
129,394 
6,504 
71,322 

5,287 


4,264 
1,023 


1,000 

pounds 

1, 697, 862 


4,899 

1,077,582 

123,213 

492, 168 

877,202 


211,969 


7,760 


3,684 
359 
662 
44 
201 
608 

62 

546 

651 

1,551 

200,950 


2,613 
12,598 

120,243 

65,496 

3,259 


2,502 
757 


1,000 
dollars 
300, 188 


2,940 
133,393 
50, 542 
113,313 

96,153 


43,327 


6,796 


2,967 
312 
533 
28 
129 
654 

24 

630 

869 

1,304 

35,374 


551 
1,932 

18,887 

14,004 

1,157 


297 


.60 
.12 
.41 
.23 


1.15 

1.33 

.84 


.21 
.36 


10  See  also  table  19B,  pt.  in,  which  lists  these  products  alphabetically  and  identifies  the  manufacturers. 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 
TABLE  19A. — Surface-active  agents.-  U.S.  production  and  sales ,  1965 — Continued 


Chemical 


Sales2 


Production1 


Quantity1  Value 


BENZENOID  SUHFACE-ACTIVE  AGENTS— Continued 

Sulfated  and  Sulfonated 

Total 

Aliylphenols,  ethoxylated  and  sulfated,  total 

Nonylphenol,  ethoxylated  and  sulfated,  and  salts 

All  other 

Benzenesulfonates,  total 

Benzene-,  cumene-,  toluene-,  and  xylenesulfonates,  total 

Xylenesulfonic  acid,  ammonium  salt 

Xylenesulfonic  acid,  sodium  salt 

All  other 

Branched  chain  alkylbenzenesulf onates ,  total 

Dodecylbenzenesulfonic  acid 

Dodecylbenzenesulfonic  acid,  calcium  salt 

Dodecylbenzenesulfonic  acid,  isopropylamine  salt 

Dodecylbenzenesulfonic  acid  ( mixed  alkyl) amine  salt 

Dodecylbenzenesulfonic  acid,  sodium  salt 

Dodecylbenzenesulfonic  acid,  triethanolamine  salt 

All  other 

Straight  chain  alkylbenzenesulfonates,  total 

Dodecylbenzenesulfonic  acid 

Dodecylbenzenesulfonic  acid,  sodium  salt 

Dodecylbenzenesulfonic  acid,  triethanolamine  salt 

All  other . 

Lignosulfonates,  total 

Lignosulfonic  acid,  calcium  salt 

Lignosulfonic  acid,  sodium  salt 

All  other 

Naphthalenesulfonates,  total 

Butylnaphthalenesulfonic  acid,  sodium  salt 

Diisopropylnaphthalenesulfonic  acid 

All  other 

Other  benzenoid  surface- active  agents,  sulfated  and 

sulfonated* 

NONBENZENOID  SUHFACE-ACTIVE  AGENTS 

Total - - 

Not  Sulfated  or  Sulfonated 

Total5— - — 

Amides,  amines,  and  quaternary  ammonium  salts,  total 

Amines,  amine  oxides,  and  amine  salts  (except  hetero- 
cyclic), total 

Amine  salts  of  fatty  acids  (anionic) 

Amines,  not  containing  oxygen,  and  salts  thereof, 

total 

Amine  salts  (  cationic) 

Diamines  and  polyamines,    total 

N-( 9-0ctadecenyl) trimethylenediamine 

N-(  Tallow  alkyl)  trimethylenediamine • 

All  other 

Primary  monoamines,  total6 

(Coconut  oil  alkyl) amine 

Dodecylamine 

( Hydrogenated  tallow  alkyl) amine 

Octadecylamine 

(Tallow  alkyl) amine 

All  other 


1,125,296 


16,729 


4,329 
12,400 


643,179 


78,458 

24,043 

21,558 

32,857 

174, 650 

47,441 

11, 296 

3,722 

670 

88,424 

2,718 

20,379 

390,071 

261,264 

1,113 

127, 694 


288, 165 
44,015 
115,027 

9,626 


943 

481 

8,202 


8,555 


1,799,158 


1,440,633 


944 

48,478 
1,914 
8,839 
1,201 
4,  K)l 
3,537 

24,273 
1,544 
1,934 

13,063 

727 

4,736 

2,269 


1,000 
pounds 
665,233 


210,208 


74,093 
23,456 
18, 276 
32,361 
83, 170 
14, 382 
8,800 
3,814 
279 
49,069 
2,754 
4,072 
52,945 
12,606 
37,300 

3,039 

428,055 


269,728 
43, 902 
114,425 

6,780 


6,780 
20, 190 

820, 660 


423,098 


171,396 


59,452 
812 

43,291 
1,861 
8,413 
1,280 
4,003 
3,130 

21,958 
1,299 
1,427 

13,098 

660 

3,620 

1,854 


1,000 
dollars 
52,826 


27, 670 


5,153 
1,573 
1,599 
1,981 
1/4,645 
2,152 
2,318 
1, 1/42 
93 
7,409 
629 
902 
7,872 
1,799 
5,484 

589 

14,985 


6,020 
3,391 
5,574 

2,664 


2,664 


7,507 


204, 035 


125,616 


61,527 


20,300 
561 

1A,  105 

626 
2,795 

518 
1,408 

869 
6,61/4 

610 

778 
2,992 

303 
1,065 

866 


See  footnotes  at  end  of  table. 


SURFACE-ACTIVE  AGENTS 
TABLE  19A.  —  Surface-active  agents;  U.S.  production  and  sales ,  1 965 --Continued 


49 


NONBENZENOID  SURFACE-ACTIVE  AGENTS— Continued 

Not  Sulfated  or  Sulfonated—  Continued 

Amides,  amines,  and  quaternary  ammonium  salts — Continued 
Amines,  amine  oxides,  and  amine  salts  ( except 
heterocyclic) — Continued 

Amines,  not  containing  oxygen,  and  salts 
thereof — Continued 
Secondary  and  tertiary  monoamines6 

Oxygen-containing  amines  and  amine  oxides,  total 

(Mixed  alkyl)  amine,  ethoxylated 

(Tallow  aliyl) amine,  ethoxylated 

All  other 

Fatty  acid  -  alianolamine  condensates,  total- 

Diethanolamine  condensates,  total 

Capric  acid 

Coconut  oil  acids  (amine/acid  ratio=2/l) 

Coconut  oil  acids  (amine/acid  ratio=]/l) 

Laurie  acid 

Oleic  acid  (amine/acid  ratio^2/l) 

Oleic  acid  (amine/acid  ratio=l/l) 

Stearic  acid 

Tall  oil  acids 

All  other 

Other  alianolamine  condensates,  total 

Coconut  oil  acids  -  ethanolamine  condensate 

Laurie  acid  -  ethanolamine  condensate 

Laurie  acid  -  isopropanolamine  condensate 

Stearic  acid  -  ethanolamine  condensate  ( amine/acid 

ratio=l/l) 

All  other 

Fatty  acid  -  diamine  and  polyamine  condensates,  total 

Oleic  acid  -  diethylenetriamine  condensate 

Oleic  acid  -  ethylenediamine  condensate  ( amine/acid 
ratio=l/2) 

All  other 

Fatty  acid  -  diamine  and  polyamine  condensates, 

alioxylated,  total 

Oleic  acid  -  ethylenediamine  condensate, 

monoethoxylated 

Stearic  acid  -  ethylenediamine  condensate, 

monoethoxylated 

All  other 

Heterocyclic  amines  and  quaternary  ammonium  salts,  total 

Imidazoline  derivatives,  total 

2-HeptadecyI-l-(2-hydroxyethyl) -2- imidazoline 

All  other 

Morpholine,  oxazoline,  and  piperazine  derivatives 

Quaternary  ammonium  salts  (except  heterocyclic),  total — 

Bis( coconut  oil  alkyl) dimethylammonium  chloride 

Bis(hydrogenated  tallow  a llsyl)  dimethylammonium 

chloride 

Dimethyldioctadecylammonium  chloride 

Dodecyltrimethylammonium  chloride 

Oxygen- containing  compounds 

Other  quaternary  ammonium  salts 

N-Substituted  amino  acids  and  polypeptides,  total 

N-Lauroylsarcosine,  sodium  salt 

All  other 

Other  amides,  amines,  and  quaternary  ammonium  salts, 

total 

Hydrogenated  tallow  acids  -  ethanolamine  condensate, 
ethoxylated 

Oleic  acid  -  ethanolamine  condensate,  ethoxylated 

All  other 


Production1 


13,452 

2,782 

1,086 

(7) 

85,912 

68,  U7 

96 

17, 194 

21,526 

20,654 

1,652 

1,262 

1,877 

470 

3,416 

17, 765 


Quantity1 


1,000 

pounds 

11,059 

15,349 

2,593 

1,051 

11,705 

58,531 

52,493 


21,109 

1,328 
1,231 
1,609 
204 
27,012 
6,038 
2,312 


498 

662 

672 

223 

113 

113 

41 

16,492 

2,941 

1,018 

17, 837 

17,  IK) 

6,461 

912 

767 

222 

96 

98 

33 

16, 829 

16,245 

6,206 

8,531 

5,519 

4,597 

4,261 

3,913 

2,476 

2,405 

357 

3,043 

2,192 

9,173 

7,866 

3,553 

7,112 

6,470 

2,762 

481 

473 

212 

6,631 

5,997 

2,550 

2,061 

1,396 

791 

17, 890 

18, 169 

6,476 

1,334 

1,228 

695 

12,894 

13,349 

3,106 

164 

157 

86 

100 

124 

143 

1,361 

1,298 

933 

2,037 

2,013 

1,513 

5,840 

3,569 

1,662 

2,663 

3,177 

3,569 

1,662 

1,180 

647 

250 

277 

100 

103 

108 

74 

7) 

795 

473 

1,000 

dollars 

4,070 

5,634 

1,150 

746 

3,738 

17,831 

15,997 


5,850 


424 

415 

759 

43 

8,506 

1,834 

552 


See  footnotes  at  end  of  table. 


50 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 
TABLE  19A.  -Surface-active  agents;  U.S.  production  and  sales,  1 965 --Continued 


Production1 


Sales2 


Quantity1  Value 


NONBENZENOID  SURFACE-ACTIVE  AGENTS--Continued 

Not  Sulfated  or  Sulfonated--Continued 

Carboxylic  acid  esters,  total 

Ethylene  glycol  and  diethylene  glycol  esters,  total— 

Diethylene  glycol  monolaurate 

Diethylene  glycol  mono-oleate 

Diethylene  glycol  monostearate 

Ethylene  glycol  distearate 

Ethylene  glycol  monostearate 

All  other 

Glycerol  esters,  total 

Complex  glycerol  esters 

Glycerol  esters  of  chemically  defined  acids,  total- 

Glycerol  monolaurate 

Glycerol  mono-oleate 

Glycerol  monostearate 

All  other 

Glycerol  esters  of  mixed  acids 

Polyethylene  glycol  esters,  total 

Polyethylene  glycol  esters  of  chemically  defined 

acids,  total 

Polyethylene  glycol  dilaurate 

Polyethylene  glycol  dioleate 

Polyethylene  glycol  distearate 

Polyethylene  glycol  monolaurate 

Polyethylene  glycol  mono-oleate 

Polyethylene  glycol  monostearate 

All  other 

Polyethylene  glycol  esters  of  mixed  acids,  total — 

Polyethylene  glycol  ester  of  castor  oil  acids 

Polyethylene  glycol  ester  of  coconut  oil  acids — 

Polyethylene  glycol  ester  of  rosin  acids 

Polyethylene  glycol  ester  of  tall  oil  acids 

Polyethylene  glycol  ester  of  tallow  acids 

All  other 

Polyglycerol  esters 

Other  carboxylic  acid  esters,  total 

Anhydrosorbitol  tall  oil  ester 

Anhydrosorbitol  trioleate 

Anhydrosorbitol  tristearate 

Ethoxylated  anhydrosorbitol  monolaurate 

Ethoxylated  anhydrosorbitol  mono-oleate 

Ethoxylated  anhydrosorbitol  monopalmitate 

Ethoxylated  anhydrosorbitol  monostearate 

Ethoxylated  anhydrosorbitol  trioleate 

Ethoxylated  anhydrosorbitol  tristearate 

1, 2-Propanediol  monolaurate 

1, 2-Propanediol  monostearate 

All  other 

Ethers,  total 

Castor  oil,  ethoxylated ■ 

n-Dodecyl  alcohol,  ethoxylated 

Lanolin,  ethoxylated 

Mixed  linear  alcohols,  ethoxylated 

9-0ctadecenyl  alcohol,  ethoxylated 

n-Octadecyl  alcohol,  ethoxylated 

Tridecyl  alcohol,  ethoxylated 

All  other 


1,000 
pounds 
146,815 


5,179 
519 
77 
911 


2,868 
68, 233 

4,006 

29,399 

81 

3,481 
24,524 

1,313 
34, 828 
24,344 

18,464 

1,067 

3,219 

327 

4,762 

3,205 

4,693 

1,191 

5,880 

999 

461 

435 

3,686 

140 

159 

956 

48, 103 

468 

563 

375 

3,007 

4,316 

320 

2,496 

407 

775 

144 

1,122 

34, 110 

189,975 


3,087 

631 

101, 877 

3,438 

514 

8,029 

72,399 


1,000 
pounds 
112,226 


1,000 
dollars 
37,053 


4,531 

509 

58 

561 

255 

653 

2,495 

59,252 

3,012 

27,956 

57 

3,043 

23,076 

1,780 

28,284 

15,845 

10,567 

818 

651 

282 

2,058 

2,283 

3,686 

789 

5,278 

"   354 

"3,243 

W-9 

1,532 

885 

31,713 

390 

64 

2,526 

3,724 

2,238 
393 

151 

1,047 

21, 180 

117,226 


2,619 

1,937 

268 

75,580 

2,404 

398 

7,293 

26,727 


1,485 

156 

16 

171 

76 

251 

815 

15,912 

1,325 

7,769 

21 

726 

6,495 

527 

6,818 

5,702 

4,187 
283 
242 
100 
821 
888 

1,406 
447 

1,515 


594 

413 

13,541 

152 

23 

1,085 

1,592 

982 
176 

61 

628 

8,842 

21,154 


SgT 

859 

87 

9,407 

1,128 

185 

1,638 

6,969 


See  footnotes  at  end  of  table. 


SURFACE-ACTIVE  AGENTS 
TABLE  19A. — Surface-active  agents ;   U.S.  production  and  sales,  1965- 


Chemical 


Production-1- 


Quantity1 


NONBENZENOID  SURFACE- ACTIVE  AGENTS— Continued 
Not  Sulfated  or  Sulfonated— Continued 

Fatty,  rosin,  and  tall  oil  acids,  potassium  and  sodium 

salts,  total8 

Coconut  oil  acids,  potassium  and  sodium  salts 

Oleic  acid,  potassium  salt 

Oleic  acid,  sodium  salt 

Stearic  acid,  potassium  and  sodium  salts 

Tall  oil  acids,  potassium  and  sodium  salts,  total 

Potassium  salt 

Sodium  salt 

Tallow  acids,  sodium  salt 

All  other 

Phosphoric  and  polyphosphoric  acid  esters,  total 

2-Ethylhexyl  phosphate,  sodium  salt 

2-Ethylhexyl  polyphosphate 

All  other 

Sulfated  and  Sulfonated 

Total5 

Alcohols,  sulfated,  total 

n-Dodecyl  sulfate  salts,  total 

n-Dodecyl  sulfate,  ammonium  salt 

n-Dodecyl  sulfate,  sodium  salt 

n-Dodecyl  sulfate,  triethanolamine  salt 

n-Dodecyl  sulfate,  all  other  salts 

All  other  sulfated  alcohols 

Amides,  amines,  and  quaternary  ammonium  salts,  sulfated 

and  sulfonated,  total 

Coconut  oil  acids  -  ethanolamine  condensate,  sulfated, 

potassium  salt 

N-Methyl-N-oleoyltaurine 

Quaternary  ammonium  sulfates 

Sulfosuccinamie  acid  derivatives 

All  other 

Carboxylic  acid  esters  (except  natural  fats  and  oils), 

sulfated  and  sulfonated,  total 

Esters  of  sulfated  oleic  acid,  total 

Isopropyl  oleate,  sulfated 

Propyl  oleate,  sulfated 

All  other 

Sulfosuccinic  acid  esters,  total 

Sulfosuccinic  acid,  bis (2-ethylhexyl) ester 

Sulfosuccinic  acid,  dihexyl  ester 

Sulfosuccinic  acid,  ditridecyl  ester,  sodium  salt 

All  other 

Other  carboxylic  acid  esters,  sulfated  and  sulfonated 

Ethers,  sulfated  and  sulfonated,  total 

n-Dodecyl  alcohol,  ethoxylated  and  sulfated,  sodium  salt 
All  other 

Natural  fats  and  oils,  sulfated,  total 

Castor  oil,  sulfated 

Coconut  oil,  sulfated 

Cod  oil,  sulfated 

Grease,  other  than  wool,  sulfated 

Neat's- foot  oil,  sulfated 

Peanut  oil,  sulfated 

Soybean  oil,  sulfated 

Sperm  oil,  sulfated 

Tallow,  sulfated 

All  other 


1,000 


3,361 


101,505 
2,845 
2,035 
2,265 
29, 775 
1/4,460 
15,315 
473,326 
286,  610 

6,656 


249 

380 

6,027 


106, 986 


41,899 
1,961 

15,889 
9,712 

1A,337 
(7) 

15,042 


30 
3,021 
8,767 
1,760 
1,464 


3,701 
1,094 
508 
2,099 
6,817 
4,774 


(7) 


298 
757 


2,120 
(7) 


29,507 


5,518 
2,758 
2,224 

659 
1,253 
1,121 

279 
6,490 
8,272 

933 


1,000 
pounds 


1,000 
dollars 


312 
948 


14, 916 


(7) 


5,186 


232 

380 

4,574 


116,471 


29,644 


1,930 
12,459 
5,467 

9,788 
14,559 


30 
2,943 
8,559 
1,707 
1,320 


11,343 

3,147 

550 

750 

1,847 

6,291 

4,347 

955 

305 

684 

1,905 


42,531 


1,542 
40,989 

18,394 


3,851 

805 

1,625 

589 

1,007 
150 
3,278 
6,061 
1,028 


154 

312 

2,117 


(7) 
3,244 


72 

105 

3,067 


35,297 


12,922 


825 
6,233 
1,755 

4,109 


6,727 


31 

1,458 

3,112 

986 

1,140 

5,812 


1,013 
211 
186 
616 

3,381 

2,464 
328 
187 
402 

1,418 

5,859 


499 
5,360 

3,977 


1,228 
163 
275 

136 
281 

sa 

630 
947 
259 


See  footnotes  at  end  of  table. 


52 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 
TABLE  19A.  --Surface-active  agents;  U.S.  production  and  sales ,  1965  --Continued 


Sales  2 

Chemical 

Production1 

Quantity1 

Value 

Unit 
value3 

NONBENZENOID  SURFACE-ACTIVE  AGENTS— Continued 

Sulfated  and  Sulfonated- -Continued 

Other  nonbenzenoid  surface- active  agents,    sulfated  and 
sulfonated: 

1.000 

7,206 
694 

1,000 
pounds 

(7) 

(7) 

1,000 

dollars 

C) 

(7) 

Per 

Nonbenzenoid  surface-active  agents 
for  which  separate  data  cannot   be   shown 

Total9— - - 

251,539 

281,091 

43,122 

$0.15 

All  quantities  are  given  in  terms  of  100-percent  organic  surface-active  ingredient. 

2  Sales  include  products  sold  as  bulk  surface-active  agents  only. 

3  Calculated  from  rounded  figures. 

4  Includes  sales  of  alkylphenols,  ethoxylated  and  sulfated. 

5  Total  shown  includes  only  those  products  and  groups  for  which  separate  data  are  published  below. 

6  These  products  were  included  in  the  "Miscellaneous  Chemicals"  section  in  previous  years. 

7  Data  are  not  separately  publishable  but  are  included  in  the  total  shown  below  for  "Nonbenzenoid  surface- active 
agents  for  which  separate  data  cannot  be  shown." 

8  Includes  production  of  approximately  884-  million  pounds  not  previously  reported. 

9  Includes  production  of  "all  other"  oxygen-containing  amines  and  amine  oxides,  "all  other"  amides,  amines,  and 
quaternary  ammonium  salts,  and  "all  other"  sulfated  and  sulfonated  alcohols,  carboxylic  acid  esters,  and  ethers; 
includes  sales  of  "all  other"  potassium  and  sodium  salts  of  fatty,  rosin,  and  tall  oil  acids,  and  of  sulfated  oleic 
acid  and  sulfated  tall  oil;  also  includes  production  and  sales  of  "all  other"  nonbenzenoid  surface- active  agents, 
not  sulfated  or  sulfonated,  and  of  "all  other"  nonbenzenoid  surface-active  agents,  sulfated  and  sulfonated. 

total  includes  data  for  fatty  monoamines,    which  in  previous  years  were  reported  in  the  section  on 
miscellaneous  organic  chemicals,    and  for  potassium  and  sodium  salts  of  fatty,    rosin,    and  tall  oil 
acids    (soaps),   which  were  for  the  most  part  not  reported  in  previous  years.    U.S.    production  in 
1965,    exclusive  of  materials  reported  for  the  first  time,   amounted  to  approximately  2,248  mil- 
lion pounds--6.  1  percent  more  than  the  2,  119  million  pounds  reported  for  1964,    and  13.  5  percent 
more  than  the  1,  981  million  pounds  reported  for   1963.    Sales  of  bulk  surface-active  agents  in  1965 
amounted  to  1,  698  million  pounds,    valued  at  $300  million.    These  figures  reflect  sales  of  bulk 
surface-active  agents  only  and  cannot  be  compared  with  sales  data  for  previous  years,    which 
included  surface-active  agents  sold  as  active  ingredients  in  formulated  and  packaged  products,  as 
well  as  strictly  bulk  materials. 

Production  of  anionic  surface- active  agents  in  1965  amounted  to  2,  358  million  pounds,    or 
74.4  percent  of  the  total;  sales  amounted  to  1,  078  million  pounds,    valued  at  $133  million.   Of  the 
anionic  products  for  which  individual  statistics  are  shown  in  the  table,    those  produced  inlargest 
quantity  were  tallow  acids,    sodium  salt,    473  million  pounds;  lignosulfonic  acid,    calcium  salt,  288 
million  pounds;  straight  chain  dodecylbenzenesulfonic  acid,    sodium  salt,    261  million  pounds; 
coconut  oil  acids,    potassium  and  sodium  salts,    102  million  pounds;  and  branched  chain  dodecyl- 
benzenesulfonic acid,    sodium  salt,    88  million  pounds. 

Production  of  those  surface-active  agents  which  are  generally  considered  to  be  nonionic 
amounted  to  659  million  pounds,    or  20.8  percent  of  the  total  output  for  1965;  sales  amounted  to 
492  million  pounds,    valued  at  $113  million.    The  most  important  nonionic  products,    in  terms  of 
quantity,   were  nonylphenol,    ethoxylated,    129  million  pounds,    and  mixed  linear  alcohols,  ethoxy- 
lated,   102  million  pounds. 

Production  of  cationic  materials  totaled  148  million  pounds,    or  4.  7  percent  of  the  total; 
sales  amounted  to  123  million  pounds,   valued  at  $51  million.    Production  of  amphoteric  materials 
amounted  to  5  million  pounds,   or  approximately  0.  2  percent  of  the  total;   sales  amounted  to  5 
million  pounds,    valued  at  $3  million. 


Pesticides  and  Other  Organic  Agricultural  Chemicals 

This  section  of  the  report  covers  pesticides  (fungicides,    herbicides,   insecticides,    and 
rodenticides)  and  other  organic  agricultural  chemicals,    such  as  plant  hormones,    seed  disinfec- 
tants,   soil  conditioners,    and  soil  fumigants.   The  data  are  given  in  terms  of  100-percent  active 
material;    they   thus    exclude  such  materials  as  diluents,    emulsifiers,    synergists,    and  wetting 


PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL  CHEMICALS 


53 


agents.   Statistics  on  production  and  sales  of  pesticides  and  other  organic  agricultural  chemicals 
in  1965  are  given  in  table  20A. 

Production  of  pesticides  and  other  organic  agricultural  chemicals  in  1965  amounted  to  877 
million  pounds—about  12  percent  more  than  the  783  million  pounds  reported  for  1964.    Sales  in 
1965  were  764  million  pounds,    valued  at  $497  million,    compared  with  692  million  pounds,    valued 
at  $427  million  in  1964. 

The  output  of  cyclic  pesticides  and  other  chemicals  included  in  the  cyclic  group  amounted  to 
683  million  pounds  in  1965--about  17  percent  more  than  the  585  million  pounds  produced  in  1964. 
Sales  in  1965  were  582  million  pounds,    valued  at  $378  million,    compared  with  523  million 
pounds,    valued  at  $317  million,    in  1964. 

Production  of  acyclic  pesticides  and  other  acyclic  organic  agricultural  chemicals  in  1965 
amounted  to  195  million  pounds,    compared  with  the   198  million  pounds  reported  for  1964.    Sales 
in  1965  were  182  million  pounds,    valued  at  $119  million,    compared  with  170  million  pounds, 
valued  at  $111  million,    in  1964.    The  apparent  decrease  in  production  was  caused  by  the  transfer 
of  several  chlorothiophosphates  used  as  intermediates,    to  the  acyclic  miscellaneous  chemicals 
section. 

TABLE  20A. — Pesticides  and  other  organic  agricultural  chemicals  .•  U.S.  production  and  sales ,  1965 

[Listed  below  are  all  pesticides  and  other  organic  agricultural  chemicals  for  which  any  reported  data  on  production 
or  sales  may  be  published.    (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be 
published  or  where  no  data  were  reported.)   Table  20B  in  pt.    Ill  lists  all  pesticides  and  other  organic  agricul- 
tural chemicals  for  which  data  on  production  or  sales  were  reported  and  identifies  the  manufacturer  of  each  ] 


Quantity 


Unit 
value1 


Grand  total 

PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL 
CHEMICALS,    CYCLIC 

Total- — 

Fungicides,  total 

Mercury  fungicides 

Naphthenic  acid,   copper  salt 

Pentachlorophenol  (PCP) 

Pentachlorophenol,    sodium  salt 

2,4, 5-Trichlorophenol  and  salts 

All  other2 - - 

Herbicides  and  plant  hormones,  total 

2-sec-Butyl-4, 6-dinitrophenol,  ammonium  salt 

Phenoxyacetic  acid  derivatives: 

(2, 4-Dichlorophenoxy) acetic  acid  (2,4-D) 

( 2, 4-Dichlorophenoxy) acetic  acid  esters  and  salts, 

total 

(2, 4-Dichlorophenoxy) acetic  acid,  n-butyl  ester 

(2, 4-Dichlorophenoxy) acetic  acid,  dimethylamine  salt 

(2, 4-Dichlorophenoxy) acetic  acid,  ethyl  ester 

(2, 4-Dichlorophenoxy) acetic  acid,  iso-octyl  ester 

(2, 4-Dichlorophenoxy) acetic  acid,  isopropyl  ester 

All  other 

(2,4, 5-Trichlorophenoxy) acetic  acid  (2,4,5-T) 

(2, 4, 5-Trichlorophenoxy)  acetic  acid  esters  and  salts, 

total 

(2,4,5-Trichlorophenoxy)acetic  acid,  n-butyl  ester — 
(2,4, 5-Trichlorophenoxy) acetic  acid,  iso-octyl  ester 

All  other : 

Phenylmereury  acetate  (PMA) 

All  other3 - - — 

Insecticides  and  rodenticides,  total 

Aldrin-toxaphene  group4 

Hexachlorocyclohexane  (Benzene  hexachloride)  and 

lindane5 

See  footnotes  at  end  of  table. 


1,000 
pounds 
877, 197 


1,000 
pounds 
763, 905 


1,000 
dollars 
497,066 


682,671 


582,344 


377, 858 


87,378 


1,602 
3,268 
39,965 
11,113 
12,969 
18,461 

215,307 


73,328 


1,367 
3,101 
33,320 
12,646 

22,894 

142,123 


24,208 


4,265 

902 

4,625 

2,661 

11,755 

169,478 


63,320 

63,360 

12,084 
13,872 

9,580 

27, 824 
11,601 

13,516 
6,485 
2,292 
4,739 
588 

62, 863 

379,986 


118, 832 


26,049 

47,299 
10,925 
11,435 
628 
7,948 
3,053 
13,310 


13,176 
5,820 
2,401 
4,955 
375 

55,168 

366,893 


110,794 
6,948 


7,664 

21, 179 
4,51A 
4,743 
158 
3,007 
955 
7,802 


9,674 
3,449 
1,831 
4,394 
2,615 
128,275 

184, 172 


49,644 
1,440 


■  33 

3.12 

.29 


.25 
.38 


.73 
.59 
.76 
.89 
6.97 
2.33 

.50 


11 


See  also  table  20B,  pt.  Ill,   which  lists  these  products  alphabetically  and  identifies  the  manufacturers. 


54 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  20A.  --Pesticides  and  other  organic  agricultural  chemicals ;  U.S.  production  and  sales,  1965 — Continued 


Production 


Quantity 


Unit 

value1 


PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL 
CHEMICALS,    CYCLIC— Continued 
Insecticides  and  rodenticides,    total — Continued 

Organophosphorus  insecticides ,    total 

0, O-Diethyl  O-(p-nitrophenyl)  phosphorothioate 

(Parathion) 

0, O-Dimethyl  O-(p-nitrophenyl)  phosphorothioate 

(Methyl  parathion) 

All  other6 

l,l,l-Trichloro-2,2-bis(p-ehlorophenyl) -ethane  (DDT) 

All  other7 

PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL 
CHEMICALS,  ACYCLIC 
Total 

Fungicides,  total 

Dime thyldithiocarb ami c  acid,  ferric  salt  (Ferbam) 

Ethylene  bis(dithiocarbamic  acid),   disodium  salt  (Nabam) 

Ethylene  bis(dithiocarbamic  acid),   zinc  salt   (Zineb) 

All  other8 

Herbicides  and  plant  hormones,  total9 

Insecticides,  rodenticides,  and  soil  conditioners  and 

fumigants,  total 

Bromome thane  (Methyl  bromide) 

l,2-Dibromo-3-chloropropane 

Organophosphorus  insecticides10 

All  other  insecticides,  rodenticides,  and  soil 

conditioners  and  fumigants11 


1,000 
pounds 
62,029 

16,607 

29,111 

16,311 

140,785 

58,340 


194,526 


55,186 

14,198 

27,440 
13,548 
141,451 
52,514 


181,561 


1.000 
dollars 
63,778 

10,427 

20,662 
32,689 
20,458 
48,852 


119,208 


36,456 


33,014 


25,943 


2,384 
2,489 
5,075 
26,508 

47,617 
110,453 


14,303 
3,433 
33,299 

59,418 


1,745 

2,141 

4,468 

24,660 

40,746 
107,801 


15,127 
3,893 
30,557 

58,224 


675 

813 

2,012 

22,443 

37,798 
55,467 


6,605 
2,013 
39,051 

7,798 


pound 


$1.16 

.73 

.75 

2.41 

.14 

.93 


■  66 
.79 


.38 
.45 


.52 
1.28 


1  Calculated  from  rounded  figures. 

2  Includes  captan,  dichlone,  glyodin,  sodium  pentaehlorophenate,  tri-  and  tetrachlorophenols,  and  others. 

3  Includes  dimethylurea  compounds,  dinitrophenol  compounds,  endothal,  isopropyl  carbanilates  (IPC  and  CIPC), 
maleic  hydrazide,  triazines,  and  others. 

*  Includes  aldrin,  chlordane,  dieldrin,  endrin,  heptachlor,  terpene  polyehlorinates,  and  toxaphene. 

5  Production  of  gamma  isomer  content  is  not  publishable  because  publication  would  reveal  the  operations  of  the 
individual  producers.  Sales  of  gamma  isomer  content  in  benzenehexachloride  and  lindane  totaled  2.0  million  pounds. 

6  Includes  carbophenothion,  diazinon,  other  phosphorothioates  and  phosphorodithioates,  and  others. 

7  Includes  DDD,  endosulfan,  methoxychlor,  tetradifon  and  other  chlorinated  insecticides,  1-naphtnyl  methylcar- 
bamate,  small  amounts  of  rodenticides  and  insect  repellents,  hexachlorocyclohexane  and  lindane  (production  only), 
and  others. 

8  Includes  dodine,  mercury  compounds,  maneb,  and  others. 

9  Includes  CDAA,  methanearsonic  acid,  disodium  salt,  thiocarbamate  and  organophosphorus  herbicides,  sodium 
dichloropropionate,  sodium  TCA,  and  others. 

10  Includes  DDVP,  ethion,  malathion,  naled,  phorate,  TEPP,  and  others. 

11  Includes  soil  conditioners  and  fumigants,  small  quantities  of  rodenticides,  and  others. 


Miscellaneous  Chemicals 


As  used  in  this  report,    the  term  "miscellaneous  chemicals"  refers  to  those  synthetic  organic 
products  that  are  not  included  in  the  use  groups  covered  in  the  preceding  sections  of  the  report. 
These  miscellaneous  chemicals,    which  account  for  about  three- fifths  of  the  output  of  all  synthetic 
organic  chemicals,    include  products  that  are  employed  in  a  great  variety  of  uses;  the  number  of 
chemicals  used  exclusively  for  only  one  purpose  is  not  large.    Among  the  products  covered  are 
those  used  for  gasoline  and  lubricating  oil  additives,    paint  driers,    photographic  chemicals, 
tanning  materials,    flotation  reagents,    refrigerants,    textile  polymers,    sequestering  agents,    or- 
ganic fertilizers,   antifreeze  chemicals,    solvents,   and  acyclic  intermediates. 

Production  of  miscellaneous  chemicals  in  1965  amounted  to  50.8  billion  pounds,    or   11.3 
percent  more  than  the  output  of  45.  7  billion  pounds  reported  for   1964.    Sales  of  miscellaneous 
chemicals  in  1965  amounted  to  22.  0  billion  pounds,    valued  at  $2.  9  billion,    compared  with  20.  5 
billion  pounds,   valued  at  $2.  7  billion,    in  1964.   Statistics  on  production  and  sales  of  miscellane- 
ous chemicals  in  1965  are  given  in  table  21A.12 


"  See  also  table  21B,  pt.  Ill,   which  lists  these  products  alphabetically  and  identifies  the  manufacturers. 


MISCELLANEOUS  CHEMICALS  55 

TABLE  21A.  —  Miscellaneous  chemicals;  U.S.  production  and  sales,  1965 

[Listed  below  are  all  miscellaneous  chemicals  for  which  any  reported  data  on  production  or  sales  may  be  published. 
(Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data 
were  reported. )  Table  21B  in  pt.    Ill  lists  alphabetically  all  miscellaneous  chemicals  for  which  data  on  produc- 
tion or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Quantity 


Grand  total 

MISCELLANEOUS  CHEMICALS,    CYCLIC 

Total 

Benzoic  acid  salts:  Sodium  benzoate,  tech.  and  U.S.P- 

Benzoyl  peroxide 

Cyclopropane 

2, 6-Di-tert- butyl- p-cresol: 

Food  grade 

Tech 

4- Ethylmorpholine 

Flotation  reagents 

Gasoline  additives,  total2 

N,  N'-Di-sec-butyl-p-phenylenediamine 

N, N'-Disalicylidene-l,  2-propanediamine 

All  other 

Hexamethylenetetramine,  tech 

Lubricating  oil  and  grease  additives,  total 

Oil-soluble  petroleum  sulfonate,  barium  salt 

Oil- soluble  petroleum  sulfonate,  calcium  salt 

Oil-soluble  petroleum  sulfonate,  sodium  salt 

All  other 

Morpholine 

Naphthenic  acid  salts,  total3  4 

Calcium  naphthenate 

Cobalt  naphthenate 

Iron  naphthenate 

Lead  naphthenate 

Manganese  naphthenate 

Zinc  naphthenate 

All  other 

Photographic  chemicals: 

Benzotriazole 

p-Diethylaminobenzenediazonium  chloride  (p-Diazo-N, 

N-diethylaniline)  -  zinc  chloride 

N, N-Diethyltoluene-2, 5- diamine,  monohydrochlori.de 

Pinene 

Propyl  gallate 

Tall  oil  salts,  total3 

Calcium  tallate 

Cobalt  tallate 

Iron  tallate 

Lead  tallate 

Manganese  tallate 

Zinc  tallate 

All  other 

Tanning  materials,    synthetic,    total 

2-Naphthalenesulfonic  acid,    formaldehyde  condensate 

and  salts . 

All  other 

See  footnotes  at  end  of  table. 


pounds 
50, 835, 600 


22,040,070 


1,000 
dollars 
2, 890, 169 


1,138,261 


9,111 

4,835 

126 

7,298 
15,150 
1,086 
5,828 

10,905 
2,064 


8,841 
49,344 
354,1 


45,963 
110, 801 

73, 678 
124,247 

15,831 

21,493 


1,887 
3,364 

381 
12,796 
1,474 
1,049 

542 


127 
156 


29,852 
77 


8,679 


"785" 

2,400 

596 

3,847 

851 

26 

174 

34,225 


29,779 
4,446 


624, 813 


7,474 

4,734 

126 

6,761 

12,147 
974 


6,540 


2,169 

853 

3,518 

34,318 

210, 198 


11, 604 

47,422 
151, 172 

W,248 

18,756 


1,399 
2,780 

252 
11,014 
1,159 

992 
1,160 


103 
162 


23,612 


8,153 


639 
2,441 

445 
3,609 

800 
32 

187 

33,376 


28, 902 
4,474 


244,750 


2,216 
4,580 
1,726 

3,836 
6,687 
1,120 


5,697 


1,915 
1,241 
2,541 

6,064 

50,280 


2,820 


9,467 
37,  993 


6,673 
6,61A 


599 

1,909 

90 

2,602 

435 

362 

617 


254 
452 


3,000 
237 


2,814 


207 
1,287 
134 
893 
227 
9 
57 

7, 666 


5,392 
2,274 


56 


SYNTHETIC  ORGANIC  CHEMICALS.  1965 
TABLE  21A.  —  Miscellaneous  chemicals;  U.S.  production  and  sales ,  1965- 


Qaantity 


MISCELLANEOUS  CHEMICALS,  CYCLIC— Continued 

Textile  chemicals,  other  than  surface-active  agents — 
All  other  miscellaneous  cyclic  chemicals 

MISCELLANEOUS  CHEMICALS,  ACYCLIC 

Total 

Acetaldehyde 

Acetic  acid,  synthetic,  IWf,5 

Acetic  acid  salts,  total 

Copper  acetate 

Potassium  acetate 

Sodium  acetate 

Zinc  acetate 

Zirconium  acetate 

All  other 

Acetic  anhydride,  100$,  from  all  sources 

Acetone,  total 

From  cumene 

From  isopropyl  alcohol 

All  other 

Acrylic  acid 

Acrylonitrile 

Adipic  acid 

Alcohols,  monohydrie,  unsubstituted,  total 

Alcohols  C9  or  lower,  total 

Butyl  alcohols,  total 

Iso  ( Isopropylcarbinol) 

Normal  ( n-Propylcarbinol) 

All  other 

Ethyl  alcohol,  synthetic6 

2-Ethyl-l-hexanol 

Hexyl  alcohol 

Iso-octyl  alcohols 

Isopropyl  alcohol 

Methanol,  synthetic 

All  other 

Alcohols  C10  or  higher,  total 

Decyl  alcohols 

1-Hexadecanol  (Cetyl  alcohol)  (95$) 

1-Octadecanol  (Stearyl  alcohol)  (95$) 

All  other - 

Amines,  total7 

Butylamine 

Dihutylamine 

Diethylamine 

Dimethylamine 

Ethylamine 

Isopropylamine 

Methylamine,  mono- - 

Trimethylamine 

All  other- 

Bis(2-chloroethyl)  ether  ( Dichlorodiethyl  ether) ,  all 

grades 

2-Butanone  (Methyl  ethyl  ketone) 

2-Butanone  oxime 

2-Butanone  peroxide 

Butyl  acetates,    total 

Normal 

All  other 

See  footnotes  at  end  of  table. 


1,000 
pounds 

2,820 
566,587 


49,697,339 


1,230,310 
1,346,683 


25,412 


200 

3,138 

16,331 

524 

182 

5,037 

1,531,738 

1, 124, 097 


746, 879 
377,218 

40, 938 
771,622 
865,719 

8, 295, 247 


7,926,726 
827,568 

428, 807 

398,761 

2,039,211 

293,203 

8,335 

126, 742 

1,537,988 

2,868,578 

225, 101 

368,521 

105,942 

2,678 

259,901 

694, 809 


1,206 
2,409 
7,006 
50,005 
8,329 

30,532 

14,085 

581,237 


317,500 
2,735 
1,676 

131,511 


86, 116 
45,395 


1,956 
241,070 


21,415,257 


1,000 
dollars 
1,923 
132,741 


2,645,419 


101,920 
294,468 


23,799 


206 

3,045 

15,662 

323 

4,563 

179,  672 


296,305 

417,691 

27,  669 

7,594 

303,339 

69,991 

4, 241, 634 


4,095,746 

391,484 

67, 962 

291,711 

31,811 

1,315,353 

149,410 

2,183 

112, 668 

581,509 

1,395,137 

148,002 

145,888 

68, 280 

2,752 

6,912 

67,944 

163,652 


1,805 
22,918 

6,789 
26,574 

6,316 
99,250 


1,981 

301, 161 

2,807 

1,622 

123,274 


80,430 
42,844 


6,617 
19, 883 


5,017 


127 

596 

2,398 

183 

1,713 


11,  908 

20,964 

1,127 

2,162 

48,354 
16,446 

266, 120 


242, 869 
36,041 

5,087 
27,383 

3,571 
76, 688 
16,337 
366 
12,852 
35, 982 
43,881 
20,722 
23,251 

8,024 
742 

1,202 
13,283 

49,440 


4,080 

1,177 

3,848 

846 

38, 6  M 


175 

32,376 
1,704 
2,541 

11, 817 


7,781 

4,036 


MISCELLANEOUS  CHEMICALS 
TABLE  21A.  -- Miscellaneous  chemicals.-  U.S.  production  and  sales ,  1965—  Continued 


57 


Production 


Quantity 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

tert- Butyl  hydroperoxide 

tert- Butyl  peroxide  (Di-tert-butyl  peroxide) 

Butyric  acid 

Caprolactam  (Hexahydro-2H-azepin-2-one) 

Carbon  disulfide 

Cellulose  esters  and  ethers,  total 

Cellulose  esters,  total 

Cellulose  acetate 

All  other 

Cellulose  ethers,  total 

Sodium  carboxymethylcellulose,  100$ 

All  other 

Chloral  (Trichloroaeetaldehyde) 

Chloroacetic  acid,  mono-  

Chloroacetic  acid,  methyl  ester 

2-Chloro-N,  N-dimethylethylamine  ( Dimethylaminoethyl 

chloride)  hydrochloride 

Decanoyl  peroxide 

Dibutyl  fumarate 

Dibutyl  maleate 

2-Diethylaminoethanol 

Diethylene  glycol 

Dilauryl  3,3'-thiodipropionate 

2-Dimethylaminoethanol 

Dioctyl  maleate 

Dipropylene  glycol 

Erucamide 

Ethanolamines,    total 

2-Aminoethanol  (Monoethanolamine) 

2,2'-Iminodiethanol  (Diethanolamine) 

2, 2 ', 2 " -Nitrilotriethanol  ( Triethanolamine) 

2- Ethoxyethanol  (Ethylene  glycol  monoethyl  ether) 

2-(2-Ethoxyethoxy)ethanol  (Diethylene  glycol  monoethyl 

ether) ; 

2-[2-(2-Ethoxyethoxy)ethoxy]ethanol  (Triethylene  glycol 

monoethyl  ether) 

Ethyl  acetate,    85$ 

Ethyl  acrylate 

Ethylene  glycol 

Ethylene  oxide 

Ethyl  ether,  all  grades 

2-Ethylhexanoic  acid  (a-Ethylcaproic  acid)  salts,  total- 
Calcium  2-ethylhexanoate 

Cobalt  2-ethylhexanoate 

Lead  2-ethylhexanoate 

Manganese  2- ethylhexanoate 

Zinc  2-ethylhexanoate 

All  other 

2-Ethyl-l-hexyl  acetate 

2-Ethyl-l-hexyl  acrylate 

Formaldehyde,  37$  by  weight 

Formic  acid,  90$- 

Formic  acid  salts 

Fu marie  acid 

Gluconic  acid,  tech 

Gluconic  acid,  sodium  salt,  tech 

Halogenated  hydrocarbons,  total 

1-Bromobutane  (n- Butyl  bromide) 

Carbon  tetrachloride 

Chlorinated  paraffins 

Chlorodifluoromethane 

Chloroethane  (Ethyl  chloride) 

Chloroform 

Chloromethane  (Methyl  chloride) 

See  footnotes  at  end  of  table. 


1,000 
pounds 

145 
1,011 

290,005 
756,512 

930, 700 


839,392 
669, 112 
170, 280 
91,308 
48, 770 
42, 538 

73,502 

71,063 

585 

353 

667 

6,120 

7,513 

3,159 

158, 746 

1,180 

1,794 

494 

33, 904 

451 

200, 836 


67,474 
77, 500 
55,862 


33,733 

6,933 

114,013 

116,796 

1, 797, 935 

2,189,798 

93,164 

4,404 


604 

227 

59 

276 

3,238 

25, 200 
3, 106, 572 
23,  657 
30,518 
33,749 
3,891 
8.01A 

9,362,119 


593, 636 
43,750 

685,768 
152,510 
187,549 


1,000 
pounds 

VA 

1,020 

478 

133,612 

541, 605 

278,425 


193,324 

193,324 
85,101 
45,242 
39, 859 


532 

239 
651 
5,494 
5,419 
2,589 
134, 994 
1,168 
1,458 

30,602 
429 

155,038 


54,108 
52,413 
48,517 

.  46,560 

25,467 

3,310 

100, 197 

47,407 

1,197,846 

255,952 

85, 174 

3,261 


~27T~ 
503 
178 
56 
259 
1,991 

608 
20,529 
1,189,434 
23,241 
25,023 
31,615 
3,501 
7,559 

4,042,963 


1,000 
dollars 

286 

1,672 

144 

41,900 

'21,691 

113,408 


66,528 

66, 528 
46,880 
19,057 
27,823 


190 

301 

897 

1,098 

1,054 

1,122 

13,675 

1,152 

981 

3,652 
51A 

27,708 


10,667 
8,176 
8,865 

7,716 

4,446 

543 
10,425 
10,901 
104,237 
25,994 
5,429 

3,173 


A3 

509,439 
43,635 
49,815 
273,944 
123,320 
94,791 


110 

549 

68 

27 

129 

2,290 

169 
5,752 
30, 199 
2,993 
1,233 
5,181 
1,135 
2,270 

458,045 


32 
37,486 
5,698 
30, 193 
18,576 
9,871 
6,437 


58  SYNTHETIC  ORGANIC  CHEMICALS,  1965 

TABLE  21A. — Miscellaneous  chemicals;  U.S.  production  and  sales ,  1965- 


Chemical 


Production 


Quantity 


MISCELLANEOUS  CHEMICALS,    ACYCLIC--Continued 

Halogenated  hydrocarbons — Continued 

Dichlorodifluorome thane 

1, 2-Dichloroethane  (Ethylene  dichloride) 

Dichloromethane  (Methylene  chloride) 

1, 2-Dichloropropane  (Propylene  dichloride) 

Dichlorotetrafluoroethane 

Iodomethane  (Methyl  iodide) 

Lauryl  chlorides 

Tetrachloroethylene  (Perchloroethylene) 

Trichloroethylene 

Trichlorofluoromethane 

Vinyl  chloride,  monomer  ( Chloroethylene) 

All  other 

4-Hydroxy-4-methyl-2-pentanone  (Diacetone  alcohol) 

Isoascorbie  acid,  sodium  salt 

Isopropyl  acetate 

Isopropyl  ether 

Lauroyl  chloride 

Lauroyl  peroxide 

Linoleic  acid  salts,  total3 

Calcium  linoleate 

Cobalt  linoleate 

All  other 

Lubricating  oil  additives,  total 

Phosphorodithioates  ( Dithiophosphates) 

Sulfurized  lard  oil 

Sulfurized  sperm  oil 

All  other 

Maleic  anhydride 

Mercaptoacetic  acid  ( Thioglycolic  acid) 

Mercaptoacetic  (Thioglycolic)  acid  derivatives,  total 

2-Aminoethyl  mercaptoacetate  (Monoethanolamine 

thioglycolate) 

Ammonium  mercaptoacetate 

Iso-oetyl  mercaptoacetate 

All  other 

2-Methoxyethanol  (Ethylene  glycol  monomethyl  ether) 

2-(2-Methoxyethoxy) ethanol  (Diethylene  glycol  monomethyl 

ether) 

2- [2-(2-Methoxyethoxy)  ethoxy] ethanol  (Triethylene  glycol 

monomethyl  ether) 

Methyl  acetate 

Methyl  ether  (Dimethyl  ether) 

4-Methyl-2-pentanone  (Methyl  isobutyl  ketone) 

Nylon,  6  and  6/6  polymer  for  fiber- 

Oleic  acid  salts,  total8 

Copper  oleate 

All  other 

Oxalic  acid 

Oxalic  acid  salts 

Palmitic  acid  salts 

Pal ml toy 1  chloride 

Pentaerythritol 

Pentaerythritol  tetranitrate 

Phosgene  (Carbonyl  chloride) 

Phosphorus  acid  esters,  not  elsewhere  specified,  total — 

Tributyl  phosphate 

All  other 

See  footnotes  at  end  of  table. 


271,408 

2,455,907 

210,830 

61,013 

21,762 

14 

911 

429,354 

434,510 

170,461 

2,000,000 

1, 642, 667 


2,835 
45,483 


9,526 
1,333 


138 

197 
124 

417, 817 


102, 269 

2,562 

23,668 

289,318 

128,226 


5,904 


272 
1,599 

4,033 

73,801 

11,416 

3,128 

8,887 

10,393 

168, 874 

980, 596 

282 


247 

19,573 

6,664 

758 

225 

69,338 

4,959 

284,671 

26,988 


4,702 
22,286 


1,000 


poi 


nds 


254, 202 

309, 033 

194,504 

31,122 

18,812 
9 

384, 978 
428, 120 
153, 953 
687,817 
485,426 

28,004 
2,386 

38,033 
4,199 

1,345 

467 


138 

329 

184, 798 


48, 146 


136, 652 


94,411 
558 


5,394 


1,729 
3,431 


66,  W7 


151,027 


20,752 
6,803 


69,396 
2,767 


23,445 


4,753 
18,  692 


1,000 

dollars 

72, 191 

13,932 

17, 207 

729 

10, 947 

26 

32,447 
36, 068 
31,318 
42, 178 
92,709 

3,574 

3,288 

4,018 

346 

1,401 

151 


26 

125 

39, 937 


11,  968 


27, 969 


10,976 
525 


6,982 


181 


1,254 
5,547 


11,233 


17,944 


3,782 
1,542 


15,415 
2,111 


9,943 


1,883 
8,060 


59 


TABLE  21A.  —  Miscellaneous  chemicals.-  U.S.  production  and  sales ,  1965—  Continued 


Quantity 


MISCELLANEOUS  CHEMICALS,  ACXCLIC--Continued 

Polyacrylic  acid  salts 

Polyethylene  glycol 

Polypropoxy  ethers,  total 

Glycerol  tri(polyoxypropylene)  ether 

All  other 

Polypropylene  glycol 

Propionic  acid 

Propionic  acid  salts: 

Calcium  propionate 

Sodium  propionate 

Propylene  glycol  ( 1, 2-Propanediol) 

Propylene  oxide 

Sarcosine  and  salt 

Sequestering  agents,  total 

(Wethylenetrinitrilo)pentaacetic  acid,  sodium  salt-- 
( Ethylenedinitrilo) tetraacetic  acid  (  Ethylenediamine- 

tetraacetic  acid) 

( Ethylenedinitrilo) tetraacetic  acid,  tetrasodium  salt- 
( Ethylenedinitrilo) tetraacetic  acid,  monohydrogen 

trisodium  salt 

(N-Hydroxyethylethylenedinitrilo) triacetic  acid, 

trisodium  salt 

All  other 

Sodium  formaldehydesulfoxylate 

Sodium  methoxide  (Sodium  methylate) 

Sorbitol 

Stearand.de  ( Octadecanamide) 

Stearic  acid  salts,  total9 

Aluminum  stearates,  total 

Aluminum  distearate 

Aluminum  monostearate 

Aluminum  tristearate 

Calcium  stearate 

Lead  stearate 

Lithium  stearate 

Magnesium  stearate 

Zinc  stearate 

All  other 

Tallow  amide,  hydrogenated 

Tetraethyllead 

Tetramethyllead  and  tetra(methyl  and  ethyl) leads 

Triethylene  glycol 

Urea  in  compounds  or  mixtures  (100$  basis),  total 

In  feed  compounds 

In  liquid  fertilizer 

In  solid  fertilizer 

All  other 

See  footnotes  at  end  of  table. 


1,000 
pounds 
2,492 
39, 698 

220, 923 


161,250 
59, 673 

94,059 
31,870 

12,248 
4,369 

212,756 

604, 559 

1,698 

35,764 


Ijf 


3,528 
19, 985 


3,721 
6,057 

5,466 

4,891 

62,471 

764 

37,546 


5,469 

3,913 
895 
661 
12,674 
421 
593 

2,370 
12,020 

3,999 

686 
549, 176 
137,  609 
50,  667 

2,572,923 


300, 865 

943,218 

1,092,818 

236, 022 


1,000 
pounds 
3,326 
35,129 

190,858 


134,476 
56,382 

80,416 
16,801 

10,398 
5,168 

188, 933 
69, 254 


26,  662 


1,734 


1,914 
13,736 


3,266 
5,430 

5,253 
4,267 
45,525 


34,433 


5,306 

3,797 

883 

626 

12,324 

372 

522 

2,323 

12,000 

1,586 


548, 177 
136,038 
41, 733 

2,466,882 


1.000 
dollars 
4,030 
8,571 

36,896 


25,767 
11,129 

Li,  085 
1,806 

1,930 

960 

19,709 

8,298 


10, 668 


557 
999 


1,468 
2,408 

1,266 
1,386 
10, 001 


12,588 


305,309 

915,203 

1,085,567 

160,  803 


1,931 

1,366 
341 
224 

4,188 
146 
264 
888 

4,424 
747 


297,480 
78,001 
7,024 

1  99,587 


12,410 

36,791 

43,399 

6,987 


60 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  21A. — Miscellaneous  chemicals:  U.S.  production  and  sales ,  1965 — Continued 


Quantity 


Unit 
value1 


MISCELLANEOUS  CHMICALS,    ACYCLIC— Continued 

Vinyl  acetate,    monomer 

Zinc  formaldehydesulfoxylate 

All  other  miscellaneous  acyclic  chemicals 


1,000 
pounds 
511,951 
1,490 
6,349,894 


1,000 
pounds 
259,099 
1,454 
1,582,690 


1,000 
dollars 
27, 837 
657 
443,025 


pound 

$0.11 
.45 
.28 


1  Calculated  from  rounded  figures. 

2  Statistics  exclude  production  and  sales  of  tricresyl  phosphate.  Statistics  on  tricresyl  phosphate  are  given  in 
the  section  "Plasticizers." 

3  Quantities  are  given  on  the  basis  of  solid  naphthenate,  tallate,  or  linoleate  content. 

*  Statistics  exclude  production  and  sales  of  copper  naphthenate.  Statistics  on  copper  naphthenate  are  given  in 
the  section  "Pesticides  and  Other  Organic  Agricultural  Chemicals." 

5  In  addition,  sales  of  recovered  acetic  acid  totaled  76,641  thousand  pounds,  valued  at  4,466  thousand  dollars. 

6  Statistics  on  production  of  ethyl  alcohol  from  natural  sources  by  fermentation  are  issued  by  the  Alcohol  Tax 
Unit,  U.S.  Internal  Revenue  Service. 

7  Statistics  exclude  production  and  sales  of  fatty  amines.  Statistics  on  fatty  amines  are  given  in  the  section 
"Surface- Active  Agents. " 

8  Statistics  exclude  production  and  sales  of  potassium  and  sodium  oleates.  Statistics  on  these  oleates  are  in- 
cluded in  the  section  "Surface- Active  Agents." 

5  Statistics  exclude  production  and  sales  of  potassium  and  sodium  stearates.  Statistics  on  these  stearates  are 
included  in  the  section  "Surf ace- Active  Agents." 

10  Production  of  urea  in  primary  solution  totaled  2,789,089  thousand  pounds. 

11  Includes  estimated  values  for  sales  of  urea  in  nitrogen  compounds. 


The  total  output  of  miscellaneous  cyclic  chemicals  in  1965  was  1.  14  billion  pounds,    or  2.  1 
percent  more  than  the  output  of  1.  11  billion  pounds  reported  for  1964.    Sales  in  1965  totaled  625 
million  pounds,    valued  at  $245  million,    compared  with  604  million  pounds,    valued  at  $224  million, 
in  1964.    The  most  important  subgroup  of  cyclic  compounds  was  the  lubricating  oil  additives,    the 
output  of  which  was  355  million  pounds  in  1965. 

Total  production  of  miscellaneous  acyclic  chemicals  in  1965  was  49.  7  billion  pounds--ll.  5 
percent  more  than  the  output  of  44.  6  billion  pounds  reported  for  1964.    Sales  in  1965  totaled  21.4 
billion  pounds,   valued  at  $2.  6  billion,    compared  with  19.  9  billion  pounds,   valued  at  $2.  4  billion, 
in  1964. 

Production  of  alcohols  and  halogenated  hydrocarbons  in  1965  each  exceeded  that  of  any  of  the 
use  groups  of  synthetic  organic  chemicals  except  cyclic  intermediates  and  plastics  and  resin 
materials.    Production  of  monohydric,   unsubstituted  alcohols  totaled  8.3  billion  pounds  in  1965, 
or  4.  5  percent  more  than  in  1964.   Alcohols  are  used  as  solvents,   intermediates,    and  antifreeze 
materials,    and  for  other  purposes.    Production  of  halogenated  hydrocarbons  totaled  9.4  billion 
pounds  in  1965,    or   15.4  percent  more  than  the  8.  1  billion  pounds  reported  for   1964.    Halogenated 
hydrocarbons  are  used  as  solvents,    intermediates,    refrigerants,    and  aerosol  propellants,    and 
for  other  purposes. 

Individual  chemicals  the  output  of  which  exceeded  1  billion  pounds  in  1965  were  formaldehyde 
(3.  1  billion  pounds,    compared  with  2.  8  billion  pounds  in  1964);  synthetic  methanol  (2.  9  billion 
pounds,    compared  with  2.  6  billion  pounds  in  1964);  urea  (2.6  billion  pounds,    compared  with  2.4 
billion  pounds);  dichloroethane  (2.  5  billion  pounds,    compared  with  2.  2  billion  pounds);  ethylene 
oxide  (2.  2  billion  pounds,    in  each  year);  ethyl  alcohol  (2.  04  billion  pounds,    compared  with  2.  07 
billion  pounds);  vinyl  chloride  (2.0  billion  pounds,    compared  with  1.6  billion  pounds);  ethylene 
glycol  (1.8  billion  pounds,    in  each  year);  isopropyl  alcohol  (1.5  billion  pounds,    in  each  year); 
and  acetic  anhydride  (1.  5  billion  pounds,    compared  with  1.4  billion  pounds). 


PART  IE.  ALPHABETICAL  LIST  OF  INDIVIDUAL  PRODUCTS,   BY  GROUPS, 
AND  NAMES  OF  MANUFACTURERS 


This  section  of  the  report  consists  of  (1)  a  series  of  tables  that  supplement  the  statistical 
information  given  in  parts  I  and  II,  and  (2)  a  Directory  of  Manufacturers.  The  tables  with  num- 
bers that  include  the  letter  "B"  supplement  the  tables  in  part  I  or  part  II  with  numbers  that  in- 
clude the  letter  "A";  for  example,  table  8B  in  part  III  supplements  table  8A  in  part  II. 

Each  table  in  part  III  lists  alphabetically  the  individual  items  in  each  group  for  which  data 
on  production  or  sales  were  reported  for  1965.  The  tables  include  data  on  only  those  chemicals 
for  which  the  volume  of  production  or  sales  in  1965  exceeded  1,000  pounds  or  for  which  the  value 
of  sales  exceeded  $1,000.  Where  separate  statistics  for  an  item  are  given  in  the  tables  in  part  I 
or  part  II,  an  asterisk  (*)  precedes  the  name  of  the  item  in  the  tables  in  part  III.  The  manufac- 
turers of  each  product  are  indicated  by  identification  codes  which  are  listed  in  the  Directory  of 
Manufacturers  (table  22).  A  few  companies,  however,  have  specifically  requested  that  they  not 
be  identified  as  having  produced  or  sold  certain  items.  These  manufacturers  are  indicated  by  a 
small  letter  "x"  in  the  tables. 


Tar  Crudes 
TABLE  4B.  — Tar  crudes  for  which  U.S.  production  or  sales  were  reported,  identified  by  manufacturer ,  1965 

[Tar  crudes   for  which  separate  statistics  are  given  in  table  4A  are  marked  below  with  an  asterisk  (*);   products  not 
so  marked  do  not  appear  in  table  4A  because  the  reported  data  are  accepted  in  confidence  and  may  not  be  published. 
Manufacturers'   identification  codes  shown  below  are  taken  from  table  22.   Table  22  identifies   all  U.S.  producers   of 
tar  crudes   (except  producers  that  report  to  the  Division  of  Bituminous  Coal,   U.S.   Bureau  of  Mines)] 


Manufacturers '   identification  codes 
(according  to  list   in  table  22  J1 


*Crude  light  oil 

Light-oil  distillates: 

*Benzene,   specification  and  industrial  grades 

*Toluene,   specification  and  other  grades 

*Xylene,   all  grades 

^Solvent  naphtha 

*A11  other  light-oil  distillates 

Pyridine  crude  bases 

*Naphthalene ,  crude,  solidifying  at — 

*Less  than  74°  C 

*74°  C.  to  less  than  76°  C 

*76°  C.  to  less  than  79°  C 

Crude  tar-acid  oils  having  a  tar-acid  content  of — 

5<f>  to  less  than  24$ 

24$  to  51$ 

Cresylic  acid,  crude 

*Creosote  oil  (Dead  oil): 

^Distillate  as  such 

^Creosote  in  coal-tar  solution 

All  other  distillate  products 

*Tar,  road 

*Tar  for  other  uses: 

Crude 

Refined 

Pitch  of  tar: 

Soft  and  medium  (water  softening  points  less  than 
110°  F.,  and  110°  F.  to  160°  F.).. 

*Hard  (water  softening  point  above  160°  F.) 

Pitch-of-tar  coke  and  pitch  emulsion 


ACY, 

KPP. 

ACY, 

KPP. 

ACY, 

KPP. 

ACY, 

KPT, 

NEV, 

PAI. 

ACP, 

PAI. 

ACP, 

KPT. 

COP. 

KPT. 

ACP, 

KPT, 

PRD, 

RIL. 

ACP, 

RIL. 

ACP, 

KPT, 

RIL. 

ACP, 

KPT, 

PRD. 

ACP, 

CBT, 

COP, 

HUS, 

KPT, 

RIL,   WTC 

ACP, 

JEN, 

KPT, 

RIL. 

ACP, 

KPT, 

PAI. 

ACP, 

KPT, 

RIL, 

WTC. 

KPT, 

RIL. 

ACP, 

KPT, 

RIL, 

RUR. 

ACP, 

CBT, 

COP, 

JEN, 

KPT, 

RIL. 

ACP, 

COP, 

HUS, 

KPT, 

RIL. 

JEN, 

RIL. 

1  Does  not  include  manufacturers '  identification  codes  for  producers  that  report  to  the  Division  of  Bituminous 
Coal,  U.S.  Bureau  of  Mines.  These  producers  are  listed  in  the  U.S.  Bureau  of  Mines  Mineral  Industry  Survey,  Aug.  10, 
1966,  entitled  "Coke  Producers  in  the  U.S.  in  1965." 

2  Crude  light  oil  production  and  sales  of  this  company  are  not  included  with  the  U.S.  Bureau  of  Mines  figures 
given  in  table  4A. 

61 


62 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


Crude  Products  From  Petroleum  and  Natural  Gas  for  Chemical  Conversion 


TABLE  5B. — Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  U.S.  production 
or  sales  were  reported,  identified  by  manufacturer,  1965 

[Crude  products   from  petroleum  and  natural  gas   for  chemical  conversion  for  which  separate  statistics  are  given  in 
table  5A  are  marked  below  with  an  asterisk  (*);   products  not  so  marked  do  not  appear  in  table  5A  because  the 
reported  data  are  accepted  in  confidence  and  may  not  be  published.  Manufacturers'   identification  codes  shown  be- 
low are  taken  from  table  22.  An  x  signifies  that  the  manufacturer  did  not  consent  to  his  identification  with  the 
designated  product] 


Manufacturers '   identification  codes 
(according  to  list  in  table  22) 


AROMATICS  AND  NAPHTHENES 

*Alkyl  aromatics,   distillates,   and  solvents 

^Benzene   (except  motor  grade): 

*Benzene,   1° 

*Benzene,   2° 

Cresylic  acid,  crude 

*Naphthalene,  all  grades 

*Naphthenic  acids: 

Acid  number  lower  than  150 

Acid  number  150-199 

Acid  number  200-224 

Acid  number  225-249 

Sodium  carbolate  and  phenate,  crude 

*Toluene : 

^Nitration  grade,  1° 

*Pure  commercial  grade,  2° 

Solvent  grade 

All  other 

*Xylenes,  mixed: 

Aviation  grade 

*3°~ — 

5° 

All  other 

All  other  aromatics  and  naphthenes 

ALIPHATIC  HYDROCARBONS 

Ci  hydrocarbon:  Methane 

*C2  hydrocarbons: 

^Acetylene 

*Ethane 

^Ethylene 

C2  and  C3  hydrocarbons,  mixed 

*C3  hydrocarbons: 

*Propane 

Propane -propylene  mixture 

*Propylene 

*Ci,   hydrocarbons: 

*1,3-Butadiene,  grade  for  rubbers  (elastomers)' 

*Butadiene  and  butylene  fractions 


ACC,  DUP,  EN J,  FG,  GOC,  JCC,  MOC,  MON,  CMC,  PLC,  SHC, 
SM,  SOC,  SOG,  USI,  VPT. 

ACU,  APR,  ASH,  ATR,  CCP,  COR,  CSD,  DLH,  DXS,  ENJ,  GOC, 
GRS,  MOC,  MON,  PLC,  PRO,  RIC,  SHO,  SKO,  SM,  SNT,  SUN, 
TOC,  TX,  VPT. 

ACC,  AMO,  CO,  DOW,  SHO,  SOC,  UCC. 

ATR,  PRD,  RIC,  SHO. 

ASH,  COL,  MON,  SUN,  TID. 

RIC,  SUN,  TX. 
PRD,  RIC,  SM,  SOC,  SUN. 
PRD,  RIC,  SM,  SOC. 
PRD,  RIC,  SM,  SOC. 
ATR,  GOC,  SIN. 

ASH,  ATR,  COR,  CSD,  DLH,  ENJ,  GOC,  LEN,  MOC,  MON,  PLC, 
PRO,  SHC,  SHO,  SIN,  SNT,  SOG,  SUN,  TOC,  TX,  UCC,  VPT. 

DOW,  MON,  RIC. 

CO,  FG,  SKO. 

ACC,  CSD,  CSO,  DXS,  ELP,  GRS,  RIC,  SHO,  SM,  SOC,  TOC, 
TX,  VPT. 

CSD,  CSO,  SOG. 

ASH,  ATR,  COR,  DLH,  MON,  PRO,  SNT. 

SIN,  SUN,  TX. 

AMO,  CCP,  CSD,  ENJ,  GRS,  LEN,  MOC,  RIC,  SHO,  SM,  SOC, 

SOG,  SUN,  TOC,  VEL,  VPT. 
COR,  ELP,  ENJ,  JCC,  LEN,  PAS,  PLC,  SM,  SOI. 


CCP,  MOC,  MON,  PAN. 

ACY,  DOW,  DUP,  MNO,  MON,  UCC,  x. 

ACU,  CCP,  ENJ,  MOC,  MON,  PAN,  PLC,  SHC,  SHO,  SM,  SOI, 

TX,  UCC,  USI. 
CCP,  DOW,  DUP,  EKX,  ELP,  ENJ,  GOC,  JCC,  KPP,  MOC,  MON, 

OMC,  PET,  PLC,  RIC,  SHC,  SM,  SNO,  TX,  UCC,  USI. 
COR,  GYR,  MON,  PLC. 


AMO,  ASH,  CCP,  CSD,  DXS,  ENJ,  GRS, 
SHM,  SHO,  SIN,  SM,  SNT,  SOG,  SOI, 

GOC,  TX. 

AMO,  ASH,  CCP,  DOW,  EKX,  ELP,  ENJ, 
PET,  PLC,  RIC,  SHC,  SHO,  SIN,  SM, 
UCC,  UOC. 

CPY,  DOW,  ELP,  ENJ,  FRS,  GGC,  ILC, 

SHC,  SM,  SOC,  SPI,  TID,  TUS,  UCC. 

DOW,  GYR,  PLC,  PTT,  SHC,  SHO,  SIN, 


MOC,  OMC, 
SPI,  UCC, 


GOC,  JCC, 
SOG,  SOI.. 


PAN,  PLC, 
UOC,  USI. 


MOC,  MON, 
SPI,  SUN, 


MON,  PET,  PLC,  PTT, 
SOC. 


CRUDE  PRODUCTS  FROM  PETROLEUM  AND  NATURAL  GAS 


63 


TABLE  5B.  —Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  U.S.  production 
or  sales  were  reported,  identified  by  manufacturer,  1965 — Continued 


Manufacturers '   identification  codes 
(according  to  list  in  table  22) 


ALIPHATIC  HYDROCARBONS— Continued 

*C*  hydrocarbons — Continued 

*n-Butane 

1-Butene 

2-Butene 

*1-Butene  and  2-butene  mixture 

*Isobutane 

*Isobutylene 

All  other 

*d   hydrocarbons: 

Isopentane  ( 2-Methylbutane ) ; 

Isoprene  (2-Methyl-l,3-butadiene) 

n-Pentane 

All  other : 

C6  hydrocarbons: 

Diisopropyl  (2,3-Dimethylbutane) 

Hexane 

Neohexane  (2,2-Dimethylbutane) 

All  other 

C7  hydrocarbons: 

n-Heptane 

*Heptenes,  mixed 

All  other 

Cs  hydrocarbons: 

*Diisobutylene  (Diisobutene) 

n-Octane 

2,2,4-Trimethylpentane  (Iso-octane) 

All  other 

Hydrocarbons,  C9  and  above: 

Eicosane 

*Nonene  ( Tripropylene ) 

Pentadecene 

*Polybutene 

*Tetrapropylene 

Tridecene  concentrate 

Triisobutylene 

All  other 

*Hydrocarbon  derivatives : 

1-Butanethiol 

tert-Butyl  mercaptan  (2-Methyl-2-propanethiol) 

Di-tert-butyl  disulfide 

Ethyl  mercaptan  (Ethanethiol) 

Isopropyl  mercaptan 

Methyl  mercaptan  (Methanethiol) 

tert-Octyl  mercaptan 

n-Propyl  mercaptan  (1-Propanethiol) 

All  other '■ 

*A11  other  aliphatic  hydrocarbons:  Alpha  olefins,  molecular 
weight  ranges: 

C6"C7 

C8-C10 

C11-C15 

Cl6_C20 

All  other 


COR,  CSD,  DXS,  ELP,  GRS,  MOC,  OMC,  PAN,  PLC,  SHO, 

SM,  SNT,  SOC,  SOG,  SOI,  UCC,  USI. 
PLC,  PTT. 
MON,  PLC,  PTT. 

AMD,  ENJ,  GOC,  PLC,  PRO,  PTT,  SHO,  SOC,  SPI,  TX. 
CCP,  DXS,  ELP,  ENJ,  GRS,  MOC,  OMC,  PAN,  PLC,  SHO, 

SOI,  UCC,  USI. 
CCP,  ENJ,  PLC,  PRO,  PTT,  SIN. 
APR,  JCC,  MOC,  MON,  PLC,  SM,  SOI,  UCC,  USI. 

CCP,  CSD,  PLC,  SHO,  SM,  SOI,  UCC. 

ENJ,  GYR,  SHC. 

APR,  PLC. 

ENJ,  GYR,  MOC,  MON,  PAS,  PET,  PLC,  USI. 


PLC. 
ENJ, 
PLC. 
APR, 

EKX, 
CSD, 
PLC. 

ATR, 
ENJ, 
ENJ. 
PLC. 

ATR. 
AMO, 


PLC,  PRO. 
PLC,  SOG. 


ENJ,  PLC,  PRO. 

ENJ,  GOC,  HOU,  SIN,  SOG,  SOI,  TID. 


ENJ,  PTT,  TX. 
PLC. 


ATR,  CO,  ENJ,  GOC,  PAS,  PRO,  RIC. 


CSD,  SOC,  SOI. 
DXS,  ENJ,  GOC,  MOC,  PRO,  RIC,  SNT,  SOC,  SUN,  TX. 


ACC 

CO, 

ENJ. 

ATR. 

CO,  ENJ,  GOC,  HOU,  KEN,  PLC,  SOC,  SUN,  TID,  UCC,  x 


PAS. 
PAS, 
PAS, 
CSD, 
PAS, 
ACC, 
PAS, 
PAS, 
EKX, 


PLC. 

PLC. 

PAS,  SOC,  x. 

SOC. 

PAS. 

PLC. 

PLC. 

PAS,  PLC,  SOC. 


GOC,  GYR,  PLC,  SOC. 

ENJ,  GOC,  SOC. 

ENJ,  GOC,  SOC. 
GOC. 

EKX,  SOC. 


64 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


Cyclic  Intermediates 

TABLE  7B.  —  Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 


[Cyclic  intermediates  for  which  separate  statistics  are  given  in  table  7A  are  marked  below  with  an  asterisk  (*); 
cyclic  intermediates  not  so  marked  do  not  appear  in  table  7A  because  the  reported  data  are  accepted  in  confidence 
and  may  not  be  published.   Manufacturers'   identification  codes  shown  below  are  taken  from  table  22.    An  x  signifies 
that  the  manufacturer  did  not  consent  to  his  identification  with  the  designated  product] 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


Aceanthryleno[2, 1-a] aceanthrylene-5, 13-dione 

8-Aeetamido-l-(4-acetamido-2-hydroxy-5-nitrophenylazo)- 
2-naphthol. 

4-Acetamido-2-aminobenzenesulfonic  acid 

p-Acetamidobenzoic  acid 

2-Acetamido-3-chloroanthraquinone 

*Acetanilide,   tech 

Acetic  acid,   phenyl  ester 

Acetoacetanilide 

o-Aeetoacetanisidide 

o-Acetoacetotoluidide 

2',4'-Acetoacetoxylidide 

p-Acetoanisidide 

1' -Acetonaphthone 

Acetone  phenylhydrazone 

p-Aeetophenetidide 

Acetophenone,   tech 

p-Acetotoluidide 

N-Acetylanthranilic  acid 

p-Acetylbenzenesulfonamide 

p-Acetylbenzenesulfonic  acid,    sodium  salt 

p-Acetylbenzenesulfonylurethane 

1-(N-  Acetyl )methylamino-4-bromo an thraquinone 

N-Acetylsulfanilic  acid,   sodium  salt 

*N-Acetylsulfanilyl  chloride 

Adenine 

*Alkylbenzenes : 

Dodecylbenzene   (including  tridecylbenzene) : 

Straight  chain 

Other 

Other  alkylbenzenes: 

Straight  chain 

Other 

Alkylphenols,  mixed 

Alkylpiperazines,  mixed 

Alkylpyridine 

a-dl-5-Allyl-6-imino-l-methyl-5-(l-methyl-2-pentynyl)- 

barbituric  acid. 
a-dl-5-Allyl-5-(l-methyl-2-pentynyl)-l-methyl  barbi- 
turic acid. 
Aminoaceanthryleno [2, 1-a] aceanthrylene-5, 13-dione 

*4-'-Aminoacetanilide   (Acetyl-p-phenylenediamine) 

3'-Aminoacetophenone 

*5-Amino-2-(p-aminoanilino)benzenesulfonic  acid 

l-Amino-4—  (3-amino-<t-sulfoanilino)-9, 10-dihydro-9, 10- 

dioxo-2-anthracenesulfonic  acid. 
1- Amino-4- (4-amino-3-sulf oanilino ) -9, 10-dihydro-9, 10- 

dioxo-2-anthracenesulfonic  acid. 
5-Amino-2-anilinobenzenesulfonic  acid 

*2-(p-Aminoanilino)-5-nitrobenzenesulfonic  acid 

3-Amino-p-anisanilide 

5-Amino-2-o-anisidinobenzenesulfonic  acid 

*l-Aminoanthraquinone  and  salt 

*2-Aminoanthraquinone  and  salt 

N-(4-Amino-l-anthraquinonyl)anthranilic  acid 

N-(5-Amino-l-anthraquinonyl)anthranilic  acid 

N-(8-Amino-l-anthraquinonyl)anthranilic  acid 

4-Aminoantipyrine 

*6-Amino-3,4'-azodibenzenesulfonie  acid   (C.I.    Acid 
Yellow  9). 

8-Aminobenz  [a]  acridan-12-one 

p-Aminobenzamide 

*l-Amino-4-benzamidoan thraquinone 

*l-Amino-5-benzamidoan thraquinone 


ICI. 
TRC. 

G. 

DUP. 

G. 

CTN, 

UCC. 

FMP, 

FMP, 

FMP, 

FMP, 

AAP. 

GIV. 

DUP. 

AAP. 

ACP, 

ACY. 

DUP. 

LIL. 

LIL. 

LIL. 

AAP. 

ALL. 

ACY, 

AHA. 


EKT,    MRK,    SAL,    SW. 

UCC. 
UCC. 
UCC. 
UCC. 


CTN,   MRK,    SAL. 


CO,    MON,    NAC,    PLC,    SOC,    UCC,    WCC. 
ATR,    CO,    NAC. 

CO,    SOC. 

ATR. 

G,    0R0. 

HOU. 

UCC. 

LIL. 

LIL. 

ICI. 

DUP,    G,    NAC,    TRC. 

CTN,    SDH,    SDW. 

AAP,    CMG,    DUP,    G,    TRC,    YAW. 

TRC. 

TRC. 


NAC. 

CMG, 

PCW. 

TRC. 

AAP, 

ACY, 

G. 

DUP. 

DUP. 

SDW. 

AAP, 


DUP,    NAC,    TRC. 


ACY,    DUP,    G,    ICI,    MAY,    NAC,    TRC. 
DUP,    G,    NAC,    TRC. 


CMG,    DUP,    NAC,    TRC. 


NAC. 

SDH. 

ACY,    MAY,    NAC,    TRC. 

G,    ICI,    NAC,    TEC. 


CYCLIC  INTERMEDIATES 


65 


TABLE  7B. 


-Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965  — Continued 


7-[p-(p-Aminobenzamido)benzamido]  -4-hydroxy-2-naphthalene- 

sulfonic  acid. 
7-(m-Aminobenzamido )-4-hydroxy-2-naphthalenesulf onic  acid- 
*7-(p-Aminobenzamido )-4-hydroxy-2-naphthalenesulfonic  acid- 
7-(p-Aminobenzamido )-5-hydroxy-3-naphthalenesulf onic  acid- 
s'- Aminobenzanilide 

4'-Aminobenzanilide 

*2-Amino-p-benzenedisulfonic  acid  [S03H  =  l] 

o-Aminobenzenethiol 

2-Aminobenzimidazole 

5-Amino-2-benzimidazolinone 

p-Aminobenzoic  acid,   tech 

p-Aminobenzoic  acid,    2-(diethylamino)ethyl  ester   (Procaine 

p-Aminobenzoic  acid,    2-(dimethylamino)ethyl  ester 

2-Amino-6-benzothiazolecarboxylic  acid 

2-(m-Aminobenzoyl)-o-acetanisidide 

l-Amino-4-bromo-2-chloroanthraquinone 

2-Amino-l-bromo-3-chloroanthraquinone 

5(and  8)-Amino-8(and  5)-bromo-9, 10-dihydro-9, 10-dioxo- 
l,6(and  l,7)-anthracenedisulfonic  acid. 
*l-Amino-4-bromo-9, 10-dihydro-9, 10-dioxo-2-anthracene- 
sulfonic  acid  and  sodium  salt. 

*l-Amino-2-bromo-4-hydroxyanthraquinone 

l-Amino-4-bromo-2-methylanthraquinone 

*l-Amino-2-bromo-4- p-toluidinoanthraquinone 

l-Amino-2-chloroanthraquinone 

*l-Amino-5-chloroanthraquinone 

l-Amino-8-chloroanthraquinone 

2-Amino-l-chloroanthraquinone 

2-Amino-3-chloroanthraquinone 

4- Amino-6-chloro-m-benzen  edisulfonami.de 

4-  Amino-6-chloro-m-benzenedisulfonamide  hydrochloride 

5-Amino-2-chlorobenzoic  acid 

2-Amino-5-chlorobenzophenone 

2-Amino-6-chlorobenzothiazole  hydrochloride 

*o-(3-Amino-4-chlorobenzoyl)benzoic  acid 

2-Amino-5-chloro-p-cumenesulfonic  acid 

2-Amino-5-chloro-4-ethylbenzenesulfonic  acid 

l-Amino-2-chloro-4-hydroxyanthraquinone 

*3-Amino-5-chloro-2-hydroxybenzenesulfonic  acid 

2-Amino-4— chlorophenol 

2-Amino-6-chloropyrazine 

3-Amino-6-chloropyridazine 

*2-Amino-5-chloro-p-toluenesulfonic  acid   [S03H=1] 

*6-Amino-4-chloro-m-toluenesulfonic  acid   [S03H=1] 

2-Amino-p-cresol 

*l-Amino-2,4-dibromoanthraquinone 

5(and  8)-Amino-6,8(and  5,7)-dibromo-9,10-dihydro-9,10- 
dioxo-1-anthracenesulfonic  acid. 

l-Amino-5, 8-dichloroanthraquinone 

4'-Amino-2',5/-diethoxybenzanilide 

3-Amino-7-(diethylamino)-5-phenylphenazinium  chloride 

l-Amino-9, 10-dihydro-9, 10-dioxo-2-anthracenesulf onic  acid— 
5(and  8 )-Amino-9, 10-dihydro-9, 10-dioxo-l-anthracenesulfonic 
acid. 
*l-Amino-9, 10-dihydro-9, 10-dioxo-4-p-toluenesulf onamido- 
2-anthracenesulfonic  acid,   sodium  salt. 

4-Amino-l,3-dihydroxyanthraquinone 

5-Amino-4, 5/-dihydroxy-3,4'-[(2-methoxy-5-methyl-p- 
phenylene)bis(azo)] -di-2,7-naphthalenedisulfonic  acid, 
5' -benzenesulf onate. 

2-Amino-4-(a,a-dimethylbenzyl)phenol 

2-Amino-N, N-dimethyl-p-toluenesulfonamide 

2-Amino-4, 6-dinitrophenol  and  salt 

3-Amino-4-ethoxyacetanilide 

3-Amino-9-ethylcarbazole 

p-Amino-N-ethyl-N-1-naphthylbenzamide 

Aminoethylpiperazine 

l-Amino-4-hydroxyanthraquinone 1 

2-Amino-3-hydroxyanthraquinone 

5-Amino-4-hydroxy-m-benzenedisulfonic  acid 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


CMG, 

DUP. 

TRC. 

CMG, 

DUP, 

G,    NAC. 

VPC. 

DUP. 

G,    TRC. 

DUP, 

G,    NAC,    TRC. 

FMT. 

EK. 

DUP. 

DUP, 

G. 

LM. 

SDW. 

DUP. 

G. 

AAP. 

ICI, 

MAY. 

TRC. 

AAP, 

DUP, 

G,    ICI,    NAC,    TRC. 

AAP, 

DUP, 

ICC,    TRC. 

ICI. 

G,    ICI,    TRC. 

AAP. 

ACT, 

DUP, 

ICI,    MAY,    NAC,    TRC 

DUP, 

NAC. 

DUP, 

G. 

G,    ICI. 

ABB. 

ABB. 

TRC. 

COK, 

ICI, 

TBK. 

DUP. 

AAP, 

G,    ICI. 

SW. 

ACY, 

SW. 

AAP. 

CMG, 

NAC, 

TRC. 

G,   MEE. 

ACY. 

ACY. 

ACY, 

HSC, 

SW. 

ACY, 

DUP, 

HSC,    NAC,    SW. 

TRC, 

X. 

AAP, 

DUP, 

ICC,    ICI,    NAC,    TRC. 

ICI. 

TRC. 

ALL. 

DUP. 

G. 

ICI, 

TRC. 

AAP, 

DUP, 

G. 

DUP,    G. 

AAP. 

AAP. 

G. 

UCC. 

G. 

G,    NAC. 

TRC. 


66 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  IB.-- Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i965--Continued 


l-Amino-4-  [(m-2-hydroxyethylsulf onyl  )anilino]  -9, 10-  dihydro- 
9, 10-dioxo-2-anthracenesulf onic  acid. 

l-Amino-4-hydroxy-2-methoxyanthraquinone 

4-Amino-5-hydroxy-2,7-naphthalenedisulfonic  acid,  benzene- 

sulfonate. 
3-Amino-5-hydroxy-2,7-naphthalenedisulfonic  acid    (2R  acid), 

monosodium  salt. 
4-Amino-5-hydroxy-l,3-naphthalenedisulfonic  acid   (Chicago 

acid),   monosodium  salt. 
*4-Amino-5-hydroxy-2,7-naphthalenedisulfonic  acid   (H  acid), 

monosodium  salt. 
*4-Amino-3-hydroxy-l-naphthalenesulfonic  acid   (1,2,4-  acid) — 
4-Amino-5-hydroxy-l-naphthalenesulfonie  acid  (S  acid), 

sodium  salt. 
*6-Amino-4-hydroxy-2-naphthalenesulfonic  acid   (Gamma  acid), 

sodium  salt. 
*7-Amino-4-hydroxy-2-naphthalenesulf  onic  acid   ( J  acid  ), 

sodium  salt. 

3-Amino-l-hydroxy-2-naphthanilide 

3'-Amino-2'-hydroxy-5'-nitroacetanilide 

6-Amiiio-5-[  (2-hydroxy-4-nitrophenyl)azo]  -2-naphthalene- 

sulfonic   acid. 
2-(2-Amino-5-hydroxy-7-sulfo-l-naphthylazo)-5-nitrobenzoic 

acid. 
l-(6-Anuno-l-hydroxy-3-sulfo-2-naphthylazo)-6-nitro-2- 

naphthol-4-sulfonic  acid. 

5-Aminoisophthalic  acid 

4-Amino-3-  ((3  -methanesulf  anamidoethyl  )-N,  N-diethylaniline 

hydrochloride. 

3-Amino-4-  methoxyacetanilide 

*N-(4-Amino-3-methoxy-l-anthraquinonyl)-p-toluenesulfon- 

amide. 

5-Amino-6-methoxy-2-naphthalenesulfonie  acid 

m- [(4-Amino-3-methoxyphenyl )azo]benzenesulf onic  acid 

8-Amino-6-methoxyquinoline 

4-[(4-Amino-5-methoxy-o-tolyl)azo]-4-hydroxy-2,7- 

naphthalenedisulfonie  acid,   benzenesulfonate. 
3- [(4- Amino-5-rnethoxy-o-tolyl)azo]-l,  5-naphthalenedi- 
sulf onic  acid. 
7-[(4-Amino-5-methoxy-o-tolyl)azo] -1,3-naphthalenedi- 
sulfonic  acid. 

*4'-Amino-N-methylacetanilide 

l-Amino-2-methylanthraquinone 

2-Amino-5-(6-methyl-2-benzothiazolyl)benzenesulfonicacid — 
4-Amino-4'-(3-methyl-5-oxo-2-pyrazolin-l-yl)-2,2'-stil- 
benedisulfonic  acid. 

8-Amino-7-methyl-l-phenazinol  (Tolazine  base) 

8-Amino-7-methyl-2-phenazinol 

2-Amino-3-methylpyridine 

2-Amino-5-methylpyridine 

2-Amino-6-methylpyridine — - — 

2-Amino-4-methylpyrimidine  (2-Amino-4-methyl-l,3-diazine) — 

2-Amino-4-(methylsulfonyl)phenol 

2-Amino-5-methyl-l,3,4-thiadiazole 

l-Amino-2-methyl-4-p-toluidinoanthraquinone 

l-Aminonaphth[2,3-c]acridan-5,8,14-trione 

l(and  4)-Aminonaphth[2,3-c]  acridan-5,8,14-trione 

4-Aminonaphth[2,3-e]acridan-5,8, 14-trione 

6-Aminonaphth[  2, 3-c]acridan-5, 8, 14-trione 

*2-Amino-l, 5-naphthalenedisulf onic  acid 

*3-Amino-l, 5-naphthalenedisulf onic  acid  (C  acid) 

3-Andno-2,7-naphthalenedisulfonic  acid 

4- Amino-1, 5-naphthalenedisulf onic  acid 

4-Amino-l,6-naphthalenedisulfonic  acid 

*6-Anri.no-l,3-naphthalenedisulfonic  acid   (Amino  I  acid) 

*7- Amino-1, 3-naphthalenedisulf onic  acid   (Amino  G  acid) 

6-Amino-l-naphthalenesulfonamide 

l-Amino-2-naphthalenesulfonic  acid   (o-Naphthionic  acid) 

2-Amino-l-naphthalenesulfonic  acid   (Tobias  acid) 

*4-Amino-l-naphthalenesulfonic  acid   (Naphthionic  acid) 

4-Amino-l-naphthalenesulfonic  acid,   sodium  salt 


Manufacturers '    identification  codes 
(according  to  list  in  table  22) 


TRC. 

TRC. 

DUP,  NAC. 

DUP,  NAC. 

DUP,  MON,    NAC. 

ACY,  G,    NAC,    TRC,    VPC. 
NAC. 

DUP,  G,    NAC,    TRC. 

BKS,  CMG,    DUP,    G,    NAC,    TRC. 


TRC. 
TRC. 


AAP. 

AAP,    DUP,    G. 

NAC,  TRC. 
DUP,  TRC. 
SDW. 

TRC. 

TRC. 


CMG, 

G,    NAC. 

DUP, 

ICI. 

G. 

TRC. 

NAC. 

DUP. 

RIL. 

RIL. 

NEP, 

RIL. 

ACY. 

NAC, 

TRC. 

ACY. 

ICI. 

DUP. 

NAC. 

DUP. 

G. 

ACY, 

SDH, 

SW. 

G,    NAC,    TRC. 

TRC. 

NAC. 

DUP. 

ACY, 

DUP, 

G,    NAC, 

ACY, 

DUP, 

G,    NAC, 

VPC. 

DUP. 

ACY, 

HSC, 

IMP,    SW. 

ACY, 

DUP, 

NAC. 

DUP, 

NAC. 

67 


TABLE  7B. 


-  Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


4(and   5)-Amino-l-naphthalenesulfonic  acid 

5-Amino-l-naphthalenesulfonic   acid   (Laurent's   acid) 

*5-Amino-2-naphthalenesulfonic  acid   (l,6-Cleve's   acid) 

*5(and  8)-Amino-2-naphthalenesulfonic  acid   (Cleve's  acid, 
mixed). 

*6-Amino-2-naphthalenesulfonic  acid   (Broenner's  acid) 

6(and  7)-Amino-l-naphthalenesulf onic  acid 

*8-Amino-l-naphthalenesulfonic  acid   (Peri  acid) 

*8-Amino-2-naphthalenesulfonic  acid   (1,7-Cleve's  acid) 

7-Amino-l,3,6-naphthalenetrisulfonic  acid 

8-Amino-l,3,6-naphthalenetrisulfonic  acid   (Koch's  acid) 

5 (and  8)-Amino-2-naphthol 

*8-Amino-2-naphthol 

3-Amino-5-(m-nitrobenzamido)-p-toluenesulfonic  acid 

*2-Amino-5-nitrobenzenesulfonic   acid  [S03H=l] 

4-Amino-3-nitrobenzoic   acid 

*2-Amino-4-nitrophenol 

2-Amino-5-nitrophenol 

4-Amino-2-nitrophenol 

2-Amino-l-(p-nitrophenyl)-l,3-propanediol 

4-Amino-4'-nitro-2,2'-stilbenedisulfonic  acid 

2-Amino-5-nitrothiazole 

*3' -Amlnooxanilic  acid 

4' -Aminooxanilic  acid 

3-Amino-2-oxazolidinone 

5-Anuno-2-[(2-oxo-5-benzimidazolinyl)amino]benzenesulfonic 
acid. 

p-Aminophenethyl  alcohol 

5-Amino-2-o-phenetidinobenzenesulfonie  acid 

o-Aminophenol 

p-Aminophenol 

m-[  (p-Aminophenyl)azo]  benzenesulfonic  acid 

*p-[ (p-Aminophenyl )azo] benzenesulf onic  acid 

7-[  (4-Aminophenyl)azo]  -1,3-naphthalenedisulfonic  acid 

5-Anino-8-(phenylazo)-2-naphthol 

8-Amino-5-(phenylazo)-2-naphthol 

5-[ (p-Aminophenyl )azo] salicylic  acid 

2-(p-itainophenyl)-6-methylbenzothiazole 

2-(p-Jtoiinophenyl )-6-methyl-7-benzothiazolesulf onic  acid 
and  salt. 

l-(m-Aninophenyl)-5-oxo-2-pyrazoline-3-carboxylic  acid 

2-JSminopyridine 

4-Aminopyridine 

2-Aminopyrimidine 

5-Jtadnosalicylic  acid 

N-(4-Amino-3-sulfo-l-anthraquinonyl)anthranilic  acid 

3 '  -  (3-Am.no-4-sulf  ophenylsulf  amoyl )  -3  "  -sulf  amoyl-3- 

phthalocyaninesulfonic  acid,    copper  derivative. 
l-Jtaiino-2,3, 6, 7-tetr ahydro-4, 5, 8-trihydroxyanthraquinone--- 

2-Aminothiazole • 

3-itad.no-p-toluamide 

5-Amino-o-toluenesulfonanilide 

*4-Anino-ni-toluenesulfonic  acid  [S03HJ.] 

*6-Amino-m-toluenesulfonie  acid  [S03H=1] 

*5-Amino-2-p-toluidinobenzenesulfonic  acid 

3- [(4-Amino-o-tolyl )azo] -1, 5-naphthalenedisulf onic  acid 

7- [(4-Amino-o-tolyl)azo] -1,3-naphthalenedisulfonic  acid 

16-Aminoviolan throne 

2-Jimino-3,5-xylenesulfonic  acid    [S03H=1] 

5-Anino-2,4-xylenesulfonic  acid 

*Aniline   (Aniline  oil) 

Aniline  hydrochloride 

l-Anilino-9, 10-dihydro-9, 10-dioxo-2-anthroic  acid 

l-Anilino-4-hydroxyanthraquinone 

6-Anilino-4-hydroxy-2-naphthalenesulfonic  acid   (Phenyl 
gamma  acid). 
*7-Anilino-4-hydroxy-2-naphthalenesulfonic  acid   (Phenyl 
J  acid). 

*Anilinomethanesulfonic  acid   and  salt 

*8-Anilino-l-naphthalenesulfonic  acid   (Phenyl  peri  acid) 

m-Anilinophenol 

p- Anisic  acid 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


ACY 

TRC. 

DUP 

NAC. 

DUP 

G,  NAC,  TRC. 

ALL, 

DUP,  G,  NAC. 

ALL, 

KLS,  NAC,  SNA,  TRC. 

VPC 

DUP, 

NAC,  SDC,  TRC. 

DUP, 

G,  NAC,  TRC. 

DUP. 

DUP, 

NAC. 

G. 

CMG, 

G,  TRC,  VPC. 

G. 

ACY, 

DUP,  G,  NAC,  TRC. 

DUP. 

DUP, 

G,  NAC,  TRC. 

NAC. 

ACY, 

VPC. 

PD. 

G,  NAC,  TRC. 

ACY. 

CMG, 

DUP,  TRC,  VPC. 

DUP. 

NOR. 

DUP. 

EKT. 

NAC. 

FMT. 

ABB, 

DUP,  SDC. 

AAP, 

DUP,  TRC. 

ACY, 

CMG,  DUP,  G,  NAC,  TRC 

TRC. 

ALL. 

ALL. 

TRC, 

VPC. 

DUP, 

NAC. 

DUP, 

TRC. 

TRC, 

VPC. 

NEP, 

RIL. 

RIL. 

ACY. 

AAP, 

TRC. 

G. 

DUP. 

DUP. 

ACY, 

MRK. 

SDH. 

G. 

ACY, 

DUP,  G,  SNA. 

DUP, 

HSC,  NAC,  SW. 

DUP, 

NAC,  TRC. 

TRC. 

TRC. 

ACY, 

G. 

DUP. 

DUP. 

ACY, 

DOW,  DUP,  NAC. 

ACY. 

NAC. 

AAP. 

DUP, 

NAC. 

ALT,  CMG,  DUP,  NAC,  TRC. 


AAP,  ACY,  DUP,  NAC,  TRC,  VPC. 
CMG,  DUP,  NAC,  SDC. 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  7B. 


■Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965  --Continued 


Manufacturers'    identification  cedes 
(according  to  list  in  table  22) 


m-Anisidine 

*o-Anisidine '—■ 

p-Anisidine 

l-p-Anisidino-4-hydroxyanthraquinone 

*o-Anisidinomethanesulfonic  acid 

2-o-Anisidino-5-nitrobenzenesulfonic  acid 

p-Anisoin 

Anisole,  tech 

4-  (o-Anisylazo)-o-anisidine 

Anthracene,   refined 

*Anthranilic  acid   (o-Aminobenzoic  acid) 

*Anthra[l,9-cd]pyrazol-6(2H)-one   (Pyrazoleanthrone) 

Anthraquinone,    100$ 

1,1'  -[l,5  (and  1, 8)-Anthraquinonylenediamino]bisnaphth- 
[  2,3-c]acridan-5,8, 14-trione. 

*N, N'-(l,5-Anthraquinonylene)dianthranilic  acid 

N, N'-(l,5-Anthraquinonylene)dioxamic  acid 

N,N'-l,5(and  l,8)-Anthraquinonylene  dioxamic  acid 

(l-Anthraquinonyl)-l,2-hydrazinedisulfonic  acid,   disodium 
salt. 

Anthrone 

Arsanilic  acid  and  salt,   tech 

Aryldiamines,   mixed 

*4',4'"-Azobis[4-biphenylearboxylic  acid] 

4' , 4' " - Azobis [ N- ( l-ehloro-2-anthraquinonyl )-4-biphenyl- 
carboxamide] . 

Barbituric  acid 

Barbituric  acid,   sodium  derivative 

*Benzaldehyde,   tech 

4-  [(4— Benzamido-l-anthraquinonyl)amino]naphth[2,3-c]- 
acridan-5, 8, 14-trione. 

N-(5-Benzamido-l-anthraquinonyl)-p-toluenesulfonamide 

l-Benzamido-4-bromo anthraquinone 

l-Benzamido-4- chloroanthraquinone 

*l-Benzamido-5-chloroanthraquinone 

l-Benzamido-5, 8-dichloroanthraquinone 

4-Benzamido-5-hydroxy-2, 7-naphthalenedisulfonic  acid 

7-Benzamido-4-hydroxy-2-naphthalenesulfonie  acid 

N-(4-Benzamido-6-methoxy-m-tolyl)-N-(methylazo)glycine 

Benzanilide 

*7H-Benz[de]anthracen-7-one   (Benzanthrone) 

Benzeneboronic  acid 

m-Benzenedisulfonic  acid 

Benzenesulfonand.de 

Benzenesulfonic  acid 

Benzenesulfonyl  chloride 

1,2,4, 5-Benzenetetracarboxylic  acid 

1, 2,4, 5-Benzenetetracarboxylic-l, 2 :4, 5-dianhydride 

1,3,5-Benzenetricarboxylic  acid 

1,2,4-Benzenetricarboxylic  acid,    1, 2-anhydride 

Benzhydrol   ( Diphenylmethanol ) 

^Benzidine  hydrochloride  and  sulfate 

Benzil   (Bibenzoyl) ■ 

Benzilic   acid 

2-Benzofuranacetonitrile 

^Benzoic  acid,   tech 

Benzoic  anhydride 

Benzoin 

Benzonitrile 

Benzophenonetetracarboxylic  dianhydride 

2-Benzothiazolethiol   (2-Mercaptobenzothiazole),    sodium 
salt. 

Benzo[b]thiophen-3(2H)-one 

lH-Benzotriazole 

2H-3,l-Benzoxazine-2,4(lH)-dione 

2-Benzoxazolinone 

Benzoylacetic  acid,  ethyl  ester 

*o-Benzoylbenzoic  acid 

Benzoyl  chloride 

4-Benzoyl-3-hydroxyphenyl  methacrylate 

2-Benzoyl-4-sulfobenzoic  acid 


EK. 

AAP, 

DUP, 

AAP. 

AAP, 

TRC. 

CTN. 

DUP, 

AAP. 

ACP. 

DUP, 

DUP, 

ACY, 

DUP. 


ALL,    DUP,    KLS,    MON. 
MON. 


DUP,    G,    NAC,    TRC,    VPC. 
GIV,    LIL. 


LB/1,    MEE,    NAC. 
G,    TRC. 
DUP,    G,    TRC. 


DUP,    ICI,    TRC. 
G,    MEE. 
G. 
DUP,    G. 

ICI. 

ABB,    FLM. 

DA. 

DUP,    G,    TRC. 


KF,    LIL. 
ABB,    KF. 
BPC,    HN,    VEL. 
DUP. 


ICI, 

AAP. 

DUP, 

ACY, 

TRC. 

TRC. 

AAP, 

G. 

DUP, 

AAP, 

EDC. 

KPT. 

NES. 

NES, 

NES. 

DUP. 

DUP, 

ACC. 

ACC. 

TBK. 

CWN, 

LEM. 

BPC, 

EK. 

FRO, 

EK. 

BPC, 

VEL. 

GOC. 

ACY, 


MEE. 
MEE. 


NAC. 


DUP,    G,    ICI,    MAY,    NAC,    TRC. 


ACY,    ATL,    CMG,    DUP,    G,    ICI,    MAY,    NAC,    SDC,    TRC. 


FIN,    LAK,    NAC,    x. 

LEM. 

HK,    HN,    MON,    VEL. 

LEM. 

GYR,    MON. 


FMP. 

ACY,    DUP,    G,    NAC. 

HK,    HN,    VEL. 


CYCLIC  INTERMEDIATES 


69 


TABLE  7B.  --Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965  --Continued 


2-Benzoyl-4'-(p-toluenesulfonamido)acetanilide 

Benzylamine 

4-(Benzylamino)-6-chloro-m-benzenedisulfonic   acid 

2-(Benzylamino)ethanol 

4-Benzyl-6-chloro-3-keto-2-methyl-7-sulf  amyl-1, 2,  4-benzyl- 

thiadiazine-1, 1-dioxide. 
4-Benzyl-6-chloro-3-keto-7-sulf amyl-1,  2, 4-benzylthia- 
diazine-1, 1-dioxide. 

Benzyl  disulfide 

Benzyl  ether  (Dibenzyl  ether) 

5-(Benzylethylamino)-o-toluenesulfonic  acid 

N-Benzyl-N-ethyl-m-toluidine 

4- ( Benzylideneamino ) antipyr ine 

4,4'-Benzylidenedi-o-toluidine 

Benzylidene  phthalide 

p-(Benzyloxy)phenol 

4- Benzylpiperidine 

Benzjl  polysulfide 

4-Berizylpyridine 

Benzyl  sulfide 

Benzyl trimethylammonium  chloride 

Benzyltrimethylammonium  hydroxide 

Benzyl trimethylammonium  methoxide 

4',4'"-Biacetophenone 

M>,3'-Bianthra[l,9-cd]pyrazole]-6,6'-(2H,2'H)dione 
( Pyrazoleanthrone  yellow). 

[3,3'-Bi-7H-benz[de]  anthracene]  -7,7'-dione 

*[4,4'-Bi-7H-benz[de]  anthracene] -7, 7 '-dione 

[l,l'-Binaphthalene]-8,8'-dicarboxylic   acid 

Biphenyl 

3,3',4,4'-Biphenyltetramine . 

2,2',4,4'-Biphenyltetrol 

2,2'-Biqiinoline 

*1,4-Bis[ 1-anthraquinonylamino]  anthraquinone 

l,4-Bis[i-anthraquinonylamino]  anthraquinone  and  1,4-Bis- 
[ 5-chloro-l-anthraquinonylamino] anthraquinone   (mixed ) . 

It  5-Bis  [1-anthraquinonylamino]  anthraquinone > 

l,4-Bis(anthraquinonylamino)anthraquinone  carbazole 

Bis[l-anthraquinonylamino]violanthrene 

l,4-Bis[(5-benzamido-l-anthraquinonyl)amino]anthraquinone-— 

a2,a6-Bis[5-tert-butyl-6-hydroxy-m-tolyl]mesitol 

Bis(chlorosulfonyl)phthalocyaninedisulfonic  acid,    copper 
derivative. 

4,4'-Bisrdiethylamino]benzhydrol 

4,4'-Bis[diethylamino]benzhydrol,   2,6-naphthalenedi- 

sulfonate. 
4,4'-Bis[diethylamino]benzhydrol  salt,   2,7-naphthalenedi- 
sulfonic  acid  mixture. 

4,4'-Bis[diethylamino]benzophenone   (Ethyl  ketone  base) 

4-Bis[ (p-diethylaminophenyl )methyl] -2, 7-naphthalenedi- 
sulfonic  acid,   leuco  form. 

4,4'TBis[dimethylamino]benzhydrol   (Michler's  hydrol) 

*4,4'-Bis[dimethylamino]benzophenone   (Michler's  ketone) 

Bis[p-(dimethylamino)phenyl]methanesulfonic  acid  and  salt — 

1, 5-Bis[2,4-dinitrophenoxy]-4,8-dinitroanthraquinone 

l,5(and  l,8)-Bis[2,4-dinitrophenoxy]-4,8(and  4,5)-dinitro- 
anthraquinone . 

Bis(2,3-epoxycyclopentyl)ether  (Epoxide  205) 

4,4'-Bis[(p-hydroxyphenyl)azo]-2,2'-stilbenedisulfonic  acid 
(C.I.   Direct  Yellow  4). 

4,4-Bis[p-hydroxyphenyli valeric  acid 

4,4-Bis(p-methoxyphenyl)-3-hexanone 

Bis(2-methyl-l-aziridinyl )phenylphosphine  oxide 

2,4-Bis(l-methylbutyl)phenol 

l,4-Bis[2-(4-methyl-5-phenyloxazolyl)l  benzene   (Dimethyl- 
P0P0P). 

Bis(o-nitrophenyl)sulfide 

m-Bis(m-phenoxyphenoxy)benzene 

l,4-Bis[2-(5-phenyloxazolyl)]benzene   (P0P0P) 

2-Brcanoacetophenone 

p-Bromoaniline 

p-Bromoanisole~ 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


EK. 

ICO,    MLS. 

ABB. 

MLS.. 

ABB. 

ABB. 

CCW. 

BPC,    TBK. 

NAC. 

DUP,    NAC. 

SDW. 

ACY. 

LIL. 

EK,    ICO. 

RIL. 

HK. 

RIL. 

BPC. 

MLS. 

MLS. 

MLS. 

DUP. 

DUP,    G,    TRC. 

DUP,  NAC. 

ACY,  DUP,    ICI,    MAY,    NAC. 

DUP,  NAC. 

DOW,  MON. 

AAP. 

FMT,  IDC. 

EK. 

ACY,  DUP,    G,    ICI,    MAY,    NAC. 

TRC. 

DUP,    NAC. 

ICI. 

G. 

ICI. 

ACY. 

TRC. 


DSC,    SDH. 
TRC. 

SDH. 

DSC,    DUP,    G,    NAC,    SDH. 

NAC. 

DUP. 

DUP. 

UCC. 
TRC. 

JNS. 
LIL. 
ICO. 
PAS. 
ARA. 


EK. 
ARA. 


EK. 

EK,    ICO. 


70 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  7B  —Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1 965—  Continued 


*3-Bromo-7H-benz[de]anthracen-7-one  (3-Bromobenzanthrone) 

Bromobenzene,   mono-  

p-Bromobenzenesulfonyl  chloride 

4-Bromobenzophenone 

Bromochlorobenzene 

o-Bromochlorobenzene 

6-Bromo-5-chlorobenzoxazolone 

2-Bromo-6-chloro-4-nitroaniline 

2-Bromodibenzofuran 

2-Bromo-4,6-dinitroaniline 

Bromoethylbenzene 

2-Bromo-3' -hydroxyacetophenone  benzoate 

*l-Bromo-4-(methylamino)anthraquinone 

6-Bronc-3-methyl-7H-dibenz[f,ij],isoquinoline-2,7(3H)dione-- 

1-Bromonaphthalene 

2-Bromo— 4'-nitroacetophenone 

l-[ (9-Bromo-7-oxo-7H-benz [de]  anthracen-3-yl )amino] anthra- 
quinone. 

m-Bromophenol 

o-Bromophenol 

(p-Bromophenyl)acetonitrile 

p-Bromophenylhydrazine  hydrochloride 

2-Broraopyridine 

o-Bromotoluene 

p- Br omo toluene 

a-Bromo toluene 

2-Bromo-l,3,5-triethylbenzene 

p-Butoxyphenol 

4-[3-(p-Butoxyphenoxy)propyl]  morpholine 

4' -Butoxy-2-piperidinopropiophenone  hydrochloride 

N-Butylacetanilide 

l-(Butylamino)anthraquinone 

p-(Butylamino)benzoie  acid,   ethyl  ester 

p-Butylaniline 

2-tert-Butylanthraquinone 

p-tert-Butylbenzaldehyde 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

p-tert-Butylbenzoic  acid 

o-(p-tert-Butylbenzoyl)benzoic  acid 

6-tert-Butyl-m-cresol 

2-tert-Butyl-p-cresol 

2'-tert-Butyl-4',6'-dimethylacetophenone 

4-Butyl-a-(dimethylamino)-o-cresol 

2-tert- Butyl -4-ethylphenol 

^-Butyl-i-methoxymetanilamide 

2-tert-Butyl-5-methylanisole 

o-sec-Butylphenol 

p-sec-Butylphenol 

o-tert-Butylphenol 

*p-tert-Butylphenol ■ 

Butylphenols,  mixed 

p-tert-Butyltoluene 

5-tert-Butyl-l,2,3-trimethylbenzene 

5-tert-Butyl-m-xylene 

6-tert-Butyl-2,4-xylenol 

Camphoric  acid 

Camphoric  anhydride 

Camphosulfonic  acid 

Carbamic  acid,  2-hydroxy-2-phenylbutyl  ester  (Hydroxy- 
phenamate ) . 

Carbazole,  refined 

N, N'-Carbonylbis[4-methoxymetanilic  acid] 

N,  N'-Carbonylbis[4-methoxy-6-nitrometanilic  acid] 

2,4'-Carbonyldibenzoic  acid 

5'_(o-Carboxybenzoyl)-2'-chlorooxanilic  acid 

N- [ (3-Carboxy-4-chlorophenyl )-sulf onyl] anthranilic  acid 

3-Carboxy-2(and  4)-hydroxybenzenediazonium  sulfate 

o-[(Carboxymethyl)thio]  benzoic  acid 

[ (o-Carboxyphenyl )thio] ethylmercury 

Cedrene 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


ACY,  DUP,  G,  ICI,  MAY,  NAC. 

DCW. 

EK. 

ICO. 

DOW. 

PIC. 

MEE. 

AAP. 

G. 

AAP,  TRC. 

DOW. 

SDH. 

AAP,  DUP,  G,  ICI. 

AAP. 

EK. 

G. 


BPC. 

EK. 

FMT,  NEP, 

EK,  RSA. 

BPC,  PIC. 

BPC,  EK. 

DUP. 


ICO. 

UCC. 

AAP. 

ICO. 

DUP,  UCC. 

DUP. 

GIV. 

PLC. 

PLC. 

PLC. 

SHC. 

DUP. 

KPT,  PED. 

ACY. 

GIV. 

EH. 

ACY. 

ALL,  KLS,  PCW. 

GIV. 

DOW,  TNA,  UCC. 

DOW. 

TNA. 

DOW,  PRD,  UCP. 

DOW. 

GIV,  SHC. 

GIV. 

GIV. 

KPT. 

FIN,  OTC. 

FIN. 

OTC,  FYL. 

AHA. 

SDC. 
G. 


TRC. 
NAC- 


LIL. 
GIV. 


CYCLIC  INTERMEDIATES 


TABLE  7B.  —Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


2'-Chloroacetoacetanilide 

2'-Chloroacetophenone 

4'-Chloroacetophenone 

4'-(Chloroacetyl)acetanilide 

m-Chloroaniline 

o-Chloroaniline 

p-Chloroaniline 

2-(o-Chloroanilino)ethanol 

3-(o-Chloroanilino)propionitrile 

5-Chloro-o-anisidine  [NH2  =  !]    (4-Chloro-o-anisidine 
[0CH3=1]). 

5-Chloro-o-anisidine  hydrochloride 

4— Chloroanthranilic  acid 

*l-Chloroanthraquinone 

*2-Chloroanthraquinone 

N-(5-Chloro-l-anthraquinonyl)-p-toluenesulfonamide 

o-Chlorobenzaldehyde 

p-Chlorobenzaldehyde 

4-(p-Chlorobenzamido)anthraquinone-l, 2-acridone : 

Chloro-7H-benz [de] anthracen-7-one   ( Chlorobenzanthrone ) 

*Chlorobenzene,   mono-  

p-Chlorobenzenesulfinic  acid 

p-Chlorobenzenesulf on amide 

p-Chlorobenzenesulfonic  acid 

o-Chlorobenzoic  acid 

p-Chlorobenzoic  acid 

p-Chlorobenzonitrile 

*o-(p-Chlorobenzoyl)benzoie  acid 

o(and  p)-Chlorobenzoyl  chloride 

p-Chlorobenzoyl  chloride 

4,4'-(o-Chlorobenzylidene)di-2,5-xylidine 

a-(p-Chlorobenzyl)-ct-phenyl-l-pyrrolidine  propanol 

Chloro(p-chlorophenyl)phenylmethane 

Chlorocyclohexane 

l-Chloro-2,5-diethoxy-4-nitrobenzene 

2-Chloro-N, N-diethyl-4-nitroaniline 

2-Chloro-3',4'-dihydroxyacetophenone 

2-Chloro-l,4-dihydroxyanthraquinone 

N-(3-Chloro-9,10-dihydroxy-2-anthryl)acetamidebis [hydrogen 
sulfate  ]. 

4'-Chloro-2',5'-dimethoxyacetoaeetanillde 

4-Chloro-2, 5-dimethoxy aniline 

5-Chloro-2,4-dimethoxy aniline 

5-Chloro-4, 7-dimethylbenzo [b]  thiophen-3(2H)-one 

4-Chloro-N,N-dimethyl-3-ni  trobenzenesulfonanti.de 

*l-Chloro-2,4-dinitrobenzene  (Dinitrochlorobenzene) 

l-Chloro-2,4-dinitrobenzene  and  2-chloro-l,3-dinitrobenzene 
mixture. 

3-Chloro-4,  6-dinitrobenzenesulf onic  acid 

4-Chloro-3, 5-dinitrobenzoic  acid 

3-Chlorodiphenylamine 

Chlorodiphenylmethane 

a- Chloro-o( and/or  p )-dodeeyltoluene  [CH3=1] 

p-[ (2-Chloroethyl )methylamino]benzaldehyde 

Chloroformic  acid,   benzyl  ester 

Chloroformic  acid,   phenyl  ester 

l-Chloro-4-hydroxyanthraquinone 

4-Chloro-5-hydroxy-l, 7-naphthalenedisulf onic  acid 

5'-Chloro-3-hydroxy-2-naphth-o-anisidide 

3-Chloro-4-hydroxyquinoline-3,4-carbonic  acid 

6-Chloroisatoic  anhydride 

4-Chloro-N-isopropyl-3-nitrobenzenesulf on amide 

4-Chlorometanilic  acid 

5-Chlorometanilic  acid 

*6-Chlorometanilic  acid 

5-Chloro-2-methoxybenzenediazonium  chloride 

N-[ (5-Chloro-2-methoxyphenyl)azo] sarcosine 

*l-Chloro-2-methylanthraquinone 

4-(Chloromethyl)-l,2-dimethylbenzene 

4-(Chloromethyl)-l,3-dimethylbenzene 

l-(Chloromethyl)naphthalene 

4-Chloro-N-methyl-3-nitrobenzenesulf on amide 


FMP,    UCC. 

EK. 

LIL,    NES. 

DUP. 

DUP,    G. 

DUP,    MON,    NAC. 

DUP,    MON. 

EKT. 

DUP. 

ALL,    BUC,    KLS. 


BUC, 

DUP. 

ACY, 

ACY, 

ICI. 

HN. 

HN. 

G. 

ACY, 

ACS, 

TRC. 

ACY, 

G. 

HN. 

HN. 

EK. 

ACY, 

HN. 

HN. 

G. 

LIL. 

OPC, 

ACY. 

ALL, 

DUP. 

AAP, 

NAC. 


G. 


DUP,    G,    ICI,    MAY,    NAC. 
G,    NAC,    TRC. 


DOW,  DUP,   DVC,    GGY,   HK,  HKD,  MON,  MTO,  OMC,  PPG,  WOI. 
NES. 


DUP,    G,    ICI,    NAC. 

TBK. 
KMT,    G. 
SDW. 


PCW. 

PCW. 

G,    PCW. 

NAC. 

EKT,    G. 

AAP,    DUP,    NAC,    SDC. 

DUP. 

TRC. 

G. 

SK. 

TBK. 

0R0. 

G,    NAC. 

RSA. 

EK. 

ICI. 

G. 

PCW. 

SDH. 

MEE. 

TRC. 

DUP. 

NAC. 

AAP,   DUP,   G,   SW. 

G. 

ATL. 

AAP,    ACY,    CMG,    G,    ICI,    NAC,    TRC. 

BPC. 

BPC. 

BPC. 

TRC. 


72 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


-Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


2- Chloro-5-(N-methylsulfamoyl) sulfanilamide 

5-Chloro-2-(N-methylsulfamyl)-<4-sulfamyl-N-benzylaniline 

Chloronaphthalen.es 

*2-Chloro-<i-nitroaniline   (o-Chloro-p-nitroaniline) 

*4-Chloro-2-nitroaniline   (p-Chloro-o-nitroaniline) 

"i-Chloro-2-nitroanisole 

*l-Chloro-5-nitroanthraquinone 

*l-Chloro-8-nitroanthraquinone 

*l-Chloro-2-nitrobenzene   (Chloro-o-nitrobenzene) 

l-Chloro-2(and  4)-nitrobenzene  (Chloronitrobenzenes, 

o-  and  p-). 
l-Chloro-3-nitrobenzene  (Chloro-m-nitrobenzene) 

*l-Chloro-4-nitrobenzene  (Chloro-p-nitrobenzene) 

*4-Chloro-3-nitrobenzenesulfonamide 

4-Chloro-3-nitrobenzenesulfonanilide 

*2-Chloro-5-nitrobenzenesulfonic  acid 

2-Chloro-5-nitrobenzenesulfonic  acid,   sodium  salt 

4-Chloro-3-nitrobenzenesulfonic   acid 

*4-Chloro-3-nitrobenzenesulfonyl  chloride 

2-Chloro-4- nitrobenzoic  acid 

2-Chloro-5-nitrobenzoic  acid 

*o-(4--Chloro-3-nitrobenzoyl  )benzoic  acid 

4-Chloro-2-nitrophenol 

4-Chloro-3-nitrophenyl  methyl  sulfone 

2-Chloro-<i-  nitrotoluene 

2-Chloro-6-nitrotoluene 

4-Chloro-2-nitrotoluene 

4-  Chloro-3 -nitrotoluene 

m- Chlorophenol 

o-Chlorophenol 

p- Chlorophenol 

2-Chlorophenothiazine 

(m-Chlorophenyl)acetonitrile 

*(p-Chlorophenyl)acetonitrile 

l-(p-Chloro-a-phenylbenzyl)-4-methylpiperazine 

4-Chloro-a-phenyl-o-cresol 

4-Chlqro-o-phenylenediamine 

3-(o-fihlorophenyl)-5-methyl-<i-isoxazolecarbonyl  chloride 

3-(o-Chlorophenyl  )-5-methyl-4- isoxazolecarboxylic  acid- 

l-(m-phlorophenyl)-3-methyl-2-pyrazolin-5-one 

p-Chlprophenyl  methyl  sulfone 

2-Chloro-<4-phenylphenol 

1- [4-(p-Chlorophenyl )-3-phenyl-3-butenyl]pyrrolidine  hydro- 
bromide. 

4-Chlorophthalic  acid 

Chlorophthalic  anhydride 

l-(3-Chloropropyl)-4-methylpiperazine 

^-(e-Chloro-S-pyridazinylJsulfanilamide 

2-Chloropyridine 

dl-2-[p-Chloro-d-(2-pyridyl )benzyl]oxy-N, N-dimethylethyl- 
amine  maleate. 

7-Chloro-4-quinolinol 

2-(6-Chloro-2-quinoyl)-l,3-indandione 

4-Chlororesorcinol 

8-Chlorotheophylline 

2-Chlorothiaxanthen-9-one 

2-Chlorothiophene 

m- Chlorotoluene 

o-Chlorotoluene 

p-Chloro toluene 

*a- Chlorotoluene   (Benzyl  chloride) 

Chlorotoluenes,   mixed 

6-Chloro-m-toluidine 

6-Chloro-m-toluidine  hydrochloride 

3-Chloro-o-toluidine  [  NH2  =  1] 

*4-Chloro-o-toluidine  [  NH2  =  1]    and  hydrochloride 

*5-Chloro-o-toluidine  [  NH2  =  1]    (4-Chloro-o-toluidine 
[CH3  =  1]). 

*5-Chloro-o-toluidine  hydrochloride  [  NH2  =  1] 

3-Chloro-p-toluidine  [NH2=  1] 

*N-[(5-Chloro-o-tolyl)azo]sarcosine 


G,    KPS,    KPT. 

ACY, 

DOW,    DUP, 

HSC. 

AAP, 

DOWr  DUP, 

VPC. 

ALL. 

ACY, 

DUP,    MAY, 

NAC,    TRC. 

DUP, 

MAY,    NAC. 

AAP, 

DUP,    MON, 

UPM. 

SDC. 

DUP, 

G,    UPM. 

AAP, 

DUP,    MON, 

UPM. 

AAP, 

CMG,    DUP, 

EKT,    ICC,    TRC 

TRC. 

AAP, 

CMG,    NAC, 

TRC. 

DUP. 

G,    NAC,    TRC. 

AAP, 

DUP,    EKT. 

SAL. 

TRC. 

AAP, 

G,    ICI,    NAC. 

DUP. 

TRC. 

DUP. 

DUP. 

BUC, 

DUP. 

AAP, 

BUC. 

EK. 

DOW, 

MON. 

DOW, 

MON. 

SK. 

BPC. 

ICO, 

OPC,    TBK. 

ABB. 

MON. 

FMT. 

ICO, 

OTC. 

ICO. 

TRC. 

TRC. 

DOW. 

LIL. 

SW. 

HK. 

SK. 

ACY. 

FMT. 

X. 

SDW. 

DUP. 

AAP, 

G. 

MAL. 

KF. 

GAM. 

BPC, 

GRH, 

HK,    HN, 

BPC. 

BUC. 

BUC. 

AAP, 

ACY, 

PCW. 

ATL, 
DUP, 

BUC, 
SDH. 

DUP. 

ALL, 

ATL, 

BUC,    G. 

CYCLIC  INTERMEDIATES 


73 


TABLE  7B. — Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965  --Continued 


l-(6-Chloro-o-tolyl)-3-methyl-2-pyrazolin-5-one 

*[(4-Chloro-o-tolyl)thio]acetic  acid 

4-Chloro-a,<x,a-trifluoro-3-nitrotoluene 

5-Chloro-a,x,a-trifluoro-2-nitrotoluene 

p-Chloro-a,a,a-trif  luorotoluene 

6-Chloro-oc,  a,ct-trifluoro-m-toluidine 

2-Chloro-l,3,5-trinitrobenzene 

Chlorotriphenylmethane 

2-Chloro-p-xylene 

4-Chloro-2, 5-xylenesulf onyl  chloride 

4-Chloro-3,5-xylenol 

[ (4-Chloro-2,5-xylyl)thio]acetic  acid 

5<x-Cholestan-3/S-ol 

Cholic  acid 

Cinnamoyl  chloride 

*Cresols : 1 

m-Cresol 

o-Cresol: 

From  coal  tar 

From  petroleum 

p-Cresol 

Cresols,   mixed  i1 
*(m,p)-Cresol: 

From  coal  tar 

From  petroleum 

*(o,m,p)-Cresol: 

From  coal  tar 

From  petroleum 

2,3-Cresotic  acid 

*Cresylic  acid,   refined:1 

*From  coal  tar 

*From  petroleum 

*Cumene 

N-(0-Cyanoethyl)-N-(/3-acetoxyethyl)aniline 

4-[(2-Cyanoethyl)ethylamino]-o-tolualdehyde 

p-[(2-Cyanoethyl)methylamino]benzaldehyde 

8-Cyano-l-naphthalenesulfonic  acid 

*Cyclohexane 

1,2-Cyclohexanedicarboxylic  acid,   diallyl  ester 

1,4-Cyclohexanedicarboxylic  acid,   dimethyl  ester 

1,2-Cyclohexanedicarboxylic  anhydride 

*Qyclohexanol 

*Cyelohexanone 

Cyclohexanone  oxime 

Cyclohexene 

4-Cyclohexene-l,2-dicarboximide 

4-Cyclohexene-l,2-dicarboxylie  anhydride 

*Cyclohexylamine 

Cyclohexyl-2-propanone 

N-Qyclohexyltaurine,   sodium  salt 

Qyclopentanepropionic  acid 

Cyclopentanol 

Qyclopentanone 

Qyclopentene 

Cyclopentylphenylglycolic  acid,   methyl  ester 

Cyclopropylcarbox amide 

Cyclopropylcarboxylic  acid 

p-Cymene 

Deoxycholic  acid 

1,5 (and  l,8)-Diacetamidoanthraquinone 

3'-[Di(2-acetoxyethyl)amino]-p-acetophenetidide 

N, N-Diacetyl-4,4'  -diaminobiphenyl 

3- (Diallylcarbamoyl )-l, 2, 2-trimethylcyclopentanecarboxylic 
acid. 

N2,  N2-W.allylmelamine 

*l,4-Diaminoanthraquinone 

*1, 5-Diaminoanthraquinone 

1,5 (and  l,8)-Diaminoanthraquinone 

*2, 6-Waminoanthraquinone 

3,4-Diaminobenzanilide 

2,4-Diaminobenzenesulfonic  acid  [S03H=l] 

See  footnote  at  end  of  table. 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


TRC. 

ACY, 

ALL, 

NAC, 

POT 

AAP, 

G,    MEE. 

MEE. 

HK. 

AAP. 

EK, 

PIC. 

ARA, 

EK. 

DUP. 

G,    NAC. 

OTA. 

G,    NAC. 

SDW. 

SRL, 

WIL. 

BPC, 

TBK, 

X. 

KPT, 

PRD. 

KPT, 

PRD. 

MER, 

NPC, 

PRD, 

SW. 

ACY, 

HPC, 

SW. 

ACP, 

KPT, 

PRD. 

MER, 

NPC, 

PIT, 

PRD. 

ACP, 

KPT. 

NPC, 
DOW. 

PIT, 

PRD. 

ACP,  KPT. 

MER,  NPC,    PIT,    PRD,    SHO. 

ACC,  CLK,    DOW,    GOC,    HPC,    MON,    SHC,    SKO,    SOC,    TX. 

EKT. 

DUP,  G. 

DUP,  G. 

DUP,  G. 

ASH,  CO,    CSD,    DUP,    EK,    EKX,    ENJ,    GOC,    GRS,    PLC,    PRO, 

RIC,    SOG. 
ICO. 


NAC. 

DUP, 

MON, 

NAC. 

DBC, 

DUP, 

MON,    NAC. 

NAC, 

X. 

KF, 

PLC. 

CHO. 

NAC, 

PTT. 

ABB, 

JCC, 

MON,    PAS,    VGC,    x. 

GIV. 

G. 

ARA. 

ARA, 

LIL. 

ARA. 

PLC. 

ARA. 

ABB. 

ABB. 

HNW, 

HPC, 

NAC. 

MRK, 

WIL. 

AAP. 

TRC. 

AAP. 

WYT. 

ACY. 

CMG, 

DUP, 

G,    NAC,    TRC. 

DUP, 

MEE, 

TRC. 

AAP, 

G,    ICI,    TRC. 

AAP, 

DUP, 

G,    ICI,    NAC,    TRC,    VPC. 

AAP, 

DUP. 

DUP, 

NAC, 

TRC. 

74 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  7B. Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 — Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


2,5-Diaminobenzenesulfonic  acid    [S03H=1] 

4,4'-Diamino-2,2'-biphenyldisulfonic  acid 

3,7-Diamino-4, 6-dibenzothiophenedisulfonic  acid,    5,5- 

dioxide,  disodium  salt. 

1, 5-Diamino-2,6-dibromo-4,8-di-p-toluidinoanthraquinone 

l,4-Diamino-2,3-dichloroanthraquinone ■■ 

*l,4-Diamino-2,3-dihydroanthraquinone 

4, 8-Diamino-9, 10-dihydro-l, 5-dihydroxy-9, 10-dioxo-2, 6- 

anthracenedisulfonic  acid. 
l,4-Diamino-9, 10-dihydro-9, 10-dioxo-2,3-anthracenedi- 

carbonitrile. 
1, 4-Diamino-9, 10-dihydro-9, 10-dioxo-2, 3-anthracenedicar- 

boximide. 

l,5-Diamino-4,8-dihydroxyanthraquinone 

l,5(and  l,8)-Diamino-4, 8(and  4, 5 )-dihydroxyanthraquinone 

4, 5-Diamino-l,8-dihydroxyanthraquinone 

3, 6-Diamino-2, 7-dimethylacridine 

3, 6-Diamino-2, 7-dimethylacridine  sulfate 

4,4'-Diaraino-5,5'-dimethyl-2,2'  -biphenyldisulfonic  acid 

l,4-Diamino-5-nitroanthraquinone 

4,6-Diamino-5-nitroso-2-phenylpyrimidine 

2,4-Diamino-6-phenyl-s-triazine 

2, 6-Diaminopyridine 

*4,4'-Diamino-2,2'-stilbenedisulfonic  acid 

l,5-Diamino-2,4,6,8-tetrabromoanthraquinone 

2, 5-Diandnotoluene  sulfate 

4,6-Diamino-m-toluenesulfonic  acid    [S03H=l] 

N-(4,6-Diamino-m-tolyl)-p-benzoquinoneimine 

1, 5-Dianilino-9, 10-dihydro-9, 10-dioxo-2, 6-anthraeenedi- 

carboxylic  acid. 

2,4-Dianilino-l-hydroxyanthraquinone 

6, 8-Dianilino-l-naphthalenesulf onic  acid 

Diary lguanidine 

p-Diazo-N,  N-dimethylaniline-l-amino-8-naphthol-3-sulfonate- 

6-sulfonic  acid,    sodium  salt. 
5(and  3)-Diazo-6-oxo-l,3(and  l,4)-cyclohexadiene-l-car- 

boxylic  acid. 

1,5-Dibenzamidoanthraquinone 

6,ll-Dibenzamido-16H-dinaphtho[2,3-aJ2  ',3'-l]  -carbazole- 

5, 10, 15, 17-tetrone. 

*4, 5' -Dibenzamido-1, 1' -iminodianthraquinone 

Dibenzo[b,def]  chrysene-7, 14-dione 

*1, 5-Dibenzoylnaphthalene 

N,  N'-Dibenzylethylenediamine 

N, N'-Dibenzylethylenediamine  diacetate 

N, N-Dibenzylsulf anilic  acid 

2,4'  -Dibromoacetophenone 

*3,9-Dibromo-7H-benz[de]anthracen-7-one 

m-Dibromobenzene 

p-Dibromobenzene 

2, 2'  -Dibromobiphenyl 

Dibromodibenzo[b,def] chrysene-7, 14-dione 

ar-Dibromoethylbenzene 

2,6-Dibromo-l, 5-naphthalenediol 

2,6-Dibromo-4-nitrophenol 

5, 13-Dibromo-8, 16-pyranthrenedione 

Dibromoviolan throne 

2, 5-Dibutoxy aniline 

p-Dibutoxybenzene 

l,4-Dibutoxy-2-chloro-5-nitrobenzene 

2, 5-Dibutoxy-4-morpholinobenzenediazonium  sulfate 

4-(2,5-Dibutoxy-4-nitrophenyl)morpholine 

2,4-Di-tert-butylphenol 

Dibutyltin  bis(cyclohexyl  maleate) 

3,4-Dichloroaniline 

*2,5-Dichloroaniline  and  hydrochloride  [NH2"l] 

3,4-Dichloroaniline-6-sulfonic  acid 

3- ( 2, 4-Dichloroanilino )-l- ( 2, 4, 6-trichlorophenyl ) -2- 

pyr azolin- 5-one . 

*1, 5-Dichloroanthraquinone 

1,5 (and  1, 8)-Dichloroanthraquinone 

1, 8-Dichloroanthraquinone 


TRC. 

AAP,  ACY, 
ACY. 

ICI. 

CMG,  DUP. 
ACY,  ATL, 
TRC. 

DUP. 

DUP. 


DUP,  G,  ICC,  VPC. 

DUP. 

ICI. 

DUP. 

DUP. 

AAP. 


ARA. 

RH,  VEL. 
NEP,  RIL. 
ACY,  DUP, 
ICI. 
EK. 
NAC. 
DUP. 
G,  NAC. 


DUP,  G,  HSH,  ICC,  ICI,  MAY,  TRC. 


G,  GGY,  NAC,  SDH,  TRC,  VPC. 


NAC. 
DUP. 
IDC. 


G,    TRC. 

ICI. 

ACY,    DUP, 

G,    ICI, 

MAY, 

NAC, 

TRC 

ATL,    ICI. 

ACY,    DUP, 

G,    HST, 

ICI, 

TRC, 

VPC 

ICO,    WYT. 

WYT. 

ICI. 

DUP,  G,  MAY,  NAC,  TRC. 


DOW. 

EDC. 

ICI. 

DOW. 

EK. 

MEE. 

DUP, 

ICI. 

G. 

EKT. 

ALL. 

ALL. 

ALL. 

ALL. 

DOW, 

KPT. 

X. 

DUP, 

MON. 

AAP, 

DUP,    KLS,    NAC,    SDH 

SW. 

EK. 

DUP, 

G,    ICI,    NAC. 

DUP, 

NAC. 

ICI, 

TRC. 

CYCLIC  INTERMEDIATES 


75 


TABLE  IB. --Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965  --Continued 


Manufacturers1   identification  codes 
(according  to  list  in  table  22) 


4, 5-Dichloro-l,  8-anthraquinonedisulfonic  acid 

2, 6-Dichlorobenzaldehyde 

2, 6-Dichlorobenzaldehyde  oxime 

3-(3,4-Dichlorobenzamido)-l-phenyl-2-pyrazolin-5-one 

Dichlorobenzan throne 

m-Dichlorobenzene 

*o-Dichlorobenzene 

o(and  p)-Diehlorobenzene 

*p-Dichlorobenzene 

4,  6-Dichloro-m-benzenedisulf  on  amide 

4,6-Dichloro-m-benzenedisulfonyl  chloride 

*3,3'-Dichlorobenzidine  base  and  salts 

2, A— Diehlorobenzoic  acid 

2, 6-Dichlorobenzonitrile 

2,4-Dichlorobenzoyl  chloride 

2, 5-Dichlorobenzoyl  chloride 1 

8,18-Dichloro-5,15-diethyl-5,15-dihydrodiindolo-(3,2-b: 
3  ',2'-m)triphenodioxazine. 

7 ',  16-Dichloro-6, 15-dihydro-5, 9, 14, 18-anthrazinetetrone 

4, 8 ( and  4, 5 )-Dichloro-9, 10-dihydro-9, 10-dioxo-l, 5 ( and 
l,8)-anthracenedisulfonic  acid. 

1, 5-Dichloro-4,8-dihydroxyanthraquinone 

l,5(and  l,8)-Dichloro-4, 8(and  4, 5)-dihydroxyanthraquinone — 

6,6'-Diehloro-2,2'-dimethoxybenzidine 

4, 5-Dichloro-3,6-dioxo-l,4-cyclohexadiene-l, 2-dicarboni- 
trile. 

Dichlorodiphenylsilane 

2',7'-Dichlorofluorescein 

2,5-Dichloro-4-hydrazinobenzenesulfonic  acid 

2- ( 5, 8-Dichloro-l-hydroxy-2-naphthylazo ) -l-phenol-4-sulf on- 

amide. 
N- ( 6, 8-Dichloro-5-hydroxy-l-naphthyl )-p-toluenesulf on amide- 
s' 14-Dichloroisoviolan  throne 

*2,5-Dichloro-4-(3-methyl-5-oxo-2-pyrazolin-l-yl)benzene- 
sulfonic  acid. 
2,3-Dichloro-6-methylquinoxaline 

*2,6-Dichloro-4-nitroaniline 

1, 2-Dichloro-4-nitrobenzene 

*l,4-Dichloro-2-nitrobenzene  (Nitro-p-dichlorobenzene) 

2,4-Dichlorophenol 

N-[  (2,5-Dichlorophenyl)azo]-N-ethyl-5-sulfoanthranilie  acid 
3-(2',6'-Dichlorophenyl)-5-methyl-4-isoxazolecarbonyl 

chloride. 
3-(2',6'-Dichlorophenyl)-5-methyl-4-isoxazolecarboxylic 
acid. 

l-(2,5-Dichlorophenyl)-3-triazenecarbonitrile 

2,6-Dichloropyrazine 

2,5-Dichloro-3,6-di(l-pyrenamino)-p-benzoquinone 

3,6-Dichloropyridazine 

4,7-Dichloroquinoline' 

3, 5-Dichlorosalicylic  acid 

*2, 5-Dichlorosulf anilic  acid  [S03H=1] 

2, 5-Dichloro-4-sulf obenzenediazonium  sulfate 

p,oc-Dichlorotoluene 

2, 6-Dichlorotoluene 

a,a'-Dichloroxylene 

2,4-Dichloro-3,5-xylenol 

Dicyclodiepoxycarboxylate  (l^ioxide  221) 

Dicyclohexylamine 

Dicyclohexylcarbodiimide 

Dicyclopentadiene  (includes  cyclopentadiene) 

Dicyelopentadiene  dioxide 

2, 5-Diethoxyaniline 

2',5'-Diethoxybenzanilide 

p-Diethoxybenzene 

2, 5-Diethoxy-morpholinobenzenediazonium  chloride,    zinc 
chloride. 

2',5'-Diethoxy-4'-nitrobenzanilide 

l,4-Diethoxy-2-nitrobenzene 

4-(2, 5-Diethoxy-4-nitrophenyl )morpholine 

«p-(Diethylamino)benzaldehyde 


0. 

DUP. 

OTC. 

EK. 

ACY. 

CPD, 

ACS, 

GGY, 

ACS, 

ABB. 


EK,  G. 

CPD,  DOW,  DUP,  DVC,  MON,  CMC,  PPG,  SCC,  SVT,  WOI. 

HKD,  MTO. 

CPD,  DOW,  DUP,  DVC,  HK,  MON,  PPG,  SCC,  SVT,  WOI. 


ALL,  CWN,  IMP,  LAK,  NAC,  UPJ. 


AAP, 

TRC. 

ICI. 

G. 

DUP. 

DUP. 

ALL. 

ARA. 

DCC, 

UCS. 

EK. 

G. 

TRC. 

EK. 

ICI. 

ACY, 

CMG,    DUP,    G,    KLS,    PCW, 

X. 

AAP, 

DUP,    EKT,    G,    MEE,    TRC 

DUP, 

MON. 

AAP, 

DUP,    NAC,    PCW,    VPC. 

DOW, 

MON. 

G. 

ICO, 

OTC. 

ICO. 

G. 

ACY. 

TRC. 

ACY. 

SDW. 

ICO. 

CMG, 

DUP,    G,    VPC. 

TRC. 

HN. 

DUP, 

G. 

BPC. 

OTA. 

UCC. 

ABB, 

MON,    VGC. 

G. 

ENJ, 

GOC,    UCC. 

UCC. 

ALL. 

ALL. 

ALL, 

G. 

ALL. 

ALL. 

ALL, 

G. 

ALL. 

DUP, 

G,    NAC. 

76 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  7B.  -Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965  --Continued 


a_ [(2-Diethylamino) ethyl] -cc-phenylcyclohexanemethanol, 
hydrochloride . 

m- (Diethylamino )phenol  ( N, N-Diethyl-3-aminophenol ) 

3-[(p-Diethylamino)phenylazo]-lH-l,2,4-triazole 

3-(Diethylamino)propiophenqne 

4-(Diethylamino)-o-tolualdehyde 

*N,  N-Diethylaniline 

N, N-Diethyl-m-anisidine 

Diethylbenzene 

Diethyl-[3,3'-biantnra[l,9-cd]pyrazole]-6,6  -dione 

1, l' -Diethyl-4, 4'  -carbocyanine  iodide   ( Cryptocyanine ) 

N, N-Diethylcyclohexylamine 

a,a'-Diethyl-4,4'-dimethoxystilbene 

Nj  N-Diethylmetanillc  acid 

N:L,N1-Diethyl-4-methoxymetanilamide 

Diethyl-N-methyl-N-piperazine  acetate 

N, N-Diethyl-p-nitrosoaniline 

N, N-Diethyl-4-nitroso-m-anisidine  hydrochloride 

N, N-Diethyl-4-nitroso-m-phenetidine 

N,  N-Di ethyl -p-phenylenediamine 

N, N-Diethyl-m-toluidine 

6, 15-Dihydro-5, 9, 14, 18-anthrazinetetrone 

10,ll-Dihydro-5H-dibenzo[a,d]cyclohepten-5-one 

2,3-Dihydro-l,8-dihydroxyanthraquinone 

9, 10-Dihydro-l, 5-dihydroxy-4, 8-dinitro-9, 10-dioxo-2, 6- 

anthracenedisulfonic  acid. 
*9, 10-Dihydro-l, 4-dihydroxy-9, 10-dioxo-2-anthracenesulfonic 

acid  (2-Qainizarinsulfonic  acid). 
N-( 5, 13-Dihydro-5, 13-dioxoaceanthryleno[ 2, 1-a] -aceanthry- 

len_7-yl)-9,10-dihydro-l-nitro-9,10-dioxo-2-anthr amide. 

«9, 10-Dihydro-9, 10-dioxo-l,  5-anthracenedisulf onic  acid 

*9, 10-Dihydro-9, 10-dioxo-l,  5-ar.thracenedisulf onic  acid, 

disodium  salt. 
9, 10-Dihydro-9, 10-dioxo-l, 5 (and  1, 8 )-anthracenedisulf onic 

acid  and  salt. 

9, 10-Dihydro-9, 10-dioxo-l, 8-anthracenedisulf onic  acid 

*9, lO-Dihydro-9, 10-dioxo-l, 8-anthracenedisulf onic  acid, 

potassium  salt. 
*9, 10-Dihydro-9,10-dioxo-2,6-anthracenedisulfonic  acid  and 

salt. 
*9, 10-Dihydro-9, 10-dioxo-l-anthracenesulf onic  acid  and  salt 

(Gold  salt). 
9, 10-Dihydro-9, 10-dioxo-2-anthracenesulfonic  acid  and  salt 

(Silver  salt). 

9, 10-Dihydro-9,10-dioxo-2-anthroic  acid 

3,4-Dihydro-3,4-dioxo-l-naphthalenesulfonic  acid,   sodium 

salt. 
10, ll-Dihydro-5-[3-(methylaminopropyl )  J -5H-dibenzol a,d J- 
cyclohepten-5-ol. 
*9, 10-Dihydro-5-nitro-9, 10-dioxo-l-anthracenesulf  onic  acid— 
9,10-Dihydro-5(and  8 )-nitro-9, 10-dioxo-l-anthracenesulf onic 

acid. 
9, 10-Dihydro-8-nitro-9, 10-dioxo-l-anthracenesulf  onic  acid— 
9, 10-Dihydro-8-nitro-9, 10-dioxo-l-anthracenesulf onic  acid, 
sodium  salt. 

*9, 10-Dihydro-l-nitro-9, 10-dioxo-2-anthroic  acid 

l,4-Dihydro-4-oxo-2, 6-pyridinecarboxylic  acid 

2,3-Dihydro-4H-pyran 

*l,4-Dihydroxyanthraquinone  (Ouinizarin) 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


*1, 5-Dihydroxyanthraquinone   (Anthraimfin) 

1,5 (and  1, 8)-Dihydroxyanthraquinone 

*l,8-Dihydroxyanthraquinone   (Chrysazin) 

*2,6-Dihydroxyanthraquinone   (Anthraflavic  acid) 

2, 5-Dihydroxybenzenesulf onic  acid   ( tfydroquinone  sulfonic 
acid ) . 

2,4-Dihydroxybenzophenone 

1, 5-Dihydroxy-4,8-dinitroanthraquinone 

l,5(and  l,8)-Dihydroxy-4,8(and  4,5)-dinitroanthraquinone- 

*l,8-Dihydroxy-4,5-dinitroanthraquinone   (4,5-Dinitro- 
chrysazin). 


ACY, 

DUP,    MON. 

TRC. 

ACY. 

DUP. 

ACY, 

DSC,    DUP,    NAC,    SDH 

DUP. 

DOW, 

KPP. 

G. 

EK. 

DUP. 

LIL. 

DUP. 

PCW. 

ABB. 

G. 

DUP. 

G. 

FMT. 

DUP. 

TRC. 

LIL. 

DUP. 

VPC. 

AAP, 

HSH,    PAT. 

ICI, 

NAC. 

ACY, 

DUP,    TRC. 

DUP, 

G,    ICI,    TRC. 

DUP, 

TRC. 

DUP. 

G,    ICI,    NAC,    TRC. 

AAP,  DUP,    G,    ICI,    NAC,    TRC,    VPC. 

AAR,  ACY,    DUP,    G,    ICI,    MAY,    NAC,    TRC. 

DUP,  NAC. 

ACY,  NAC. 

EK. 


DUP,  MAY,    NAC,    TRC. 

ICI,  TRC. 

MAY,  NAC. 
DUP. 

DUP,  G,    NAC,    TRC. 

SDW. 

QKO. 

AAP,  ACY,    CMG,    DUP,    EKT,    G,    HSH,    ICC,    ICI,    JTC,    MAY, 

NAC,    TRC. 

ACY,  CMG,    DUP,    G,    NAC,    TRC. 

AAP,  DUP,    TRC. 

DUP,  G,    ICI. 

DUP,  G,    NAC,    TRC. 
NES. 

DUP,  G. 

AAP,  ICC,    ICI,    VPC. 

TRC. 

DUP,  EKT,   G,    ICC,    ICI. 


CYCLIC  INTERMEDIATES 


77 


--Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


10, 10'- (Dihydroxyethanediylidene)dian  throne 

4,  5-Dihydroxy-2,7-naphthalenedisulfonic  acid   ( Chronotropic 
acid). 

6, 7-Dihydroxy-2-naphthalenesulf onic  acid 

3, 5-Dihydroxy-2-naphthoic  acid 

lip .21-Dihydroxypregna-4, 17(20 )-cis-dien-3-one 

llp,21-Dihydroxypregna-l,4,17(20)-cis-trien-3-one 

4,  5-Dihydroxy-3-(p-sulfophenylazo)-2,7-naphthalenedisul- 
fonic  acid,  trisodium  salt. 

*16,17-Dlhydroxyviolanthrone  (Dihydroxydibenzanthrone) 

m-Diiodobenzene 

2, 5-Diiodobenzoic  acid,  2-(2-methoxyethoxy)ethyl  ester 

3, 5-Diiodo-4-oxo-l(4H)pyridineacetic  acid 

3, 5-Diiodo-L- tyrosine 

N, N  '-Diisopropyl-p-phenylenediamine 

2, 5-Dimethoxy aniline 

l,5(and  l,8)-Dimethoxyanthraquinone 

2, 5-Dimethoxybenzaldehyde 

*m-Dimethoxybenzene 

*3,3'-Dimethoxybenzidine 

3,3  -Dimethoxybenzidine  hydrochloride 

2, 4-Dimethoxybenzoie  acid 

2, 6-Dimethoxybenzoyl  chloride 

N,  N'-[(3,3'-Dimethoxy-4,4'-biphenylylene)bis-(azo)]bis- 
( N-methyltaurine ) . 

2,5-Dimethoxy-P-methyl-|3-nitrostyrene 

N-(3,4-Dimethoxy-a-methylphenethyl)-2-(4-ethoxy-3-methoxy- 
phenyl )acetamide. 

2,5-Dimethoxy-a-methylphenylamine 

1,4—  Dimethoxy-2-nitrobenzene 

2, 5-Dimethoxy-4' -nitrostilbene 

3,4-Dimethoxyphenethylamine  (Homoveratrylamine) 

4-(2',5'-Dimethoxyphenethyl)aniline  hydrochloride 

N-(3,4-Dimethoxyphenethyl)-2-(3,4-dimethoxyphenyl)-acetamide 

3,4-Dimethoxyphenisopropylamine 

(3,4-Dimethoxyphenyl)acetic  acid 

(3,4-Dimethoxyphenyl)acetonitrile 

l-(3,4-Dimethoxyphenyl)-2-nitro-l-propene 

*16,17-Dimethoxyviolan throne 

1, 5-(Dimethylamiho)anthraquinone 

m-(Dimethylamino)benzoic  acid 

a-(Dimethylaraino)-p-cresol 

6-Dimethylamino-2- [2-(2, 5-dimethyl-l-phenyl-3-pyrryl)- 
vinyl]-l-methyl-l-quinolinium  methyl  sulfate. 

6-(Dimethylaminoethyl)-2-methoxy-4-nitrophenol 

2-[[  2-(Dimethylamino)ethyl] -2-thenylamino]-pyridine   (non- 
medicinal  grade). 

m-(Dimethylamino)phenol 

l-(Dimethylamino)phenylbutyTonitrile 

N-(p-Dimethylaminophenyl)-l,4-naphthoquinoneimine 

*N,  N-Dimethylaniline 

7, 12-Dimethylbenz[ a] anthracene 

3,3'-Dimethylbenzidine  (o-Tolidine) 

3,3'-Dimethylbenzidine  hydrochloride 

*N,  N-Dimethylbenzylamine 

a,a-Dimethylbenzyl  hydroperoxide 

4-(a,a-Dimethylbenzyl)-2-phenylazophenol 

*2, 2'-Dimethyl-l,l'-bianthraquinone 

Dimethyl-6, 12-ceroxenol  acetate 

5,5-Dimethyl-l,3-cyclohexanedione 

N, N-Dimethylcyclohexylamine 

N,a-Dimethylcyclopentaneethylamine 

N, N-Dimethyl-2, 2-diphenylacetamide 

2 '  ,T  -Dime  thy  If  luor  an 

5,5-Dimethylhydantoin 

2,3-Dimethjrlindole- 

2, 5-Dimethyl-4(2 )-morpholinylmethylphenol  hydrochloride 

*N, N-Dimethyl-p-nitrosoaniline 

N, N-Dimethyl-3-nitro-p-toluenesulf on amide 

N, N-Dimethyl-p-phenylenediamine 

N, N-Dimethyl-p-phenylenediamine  hydrochloride 

1, 4-Dimethylpiper azine 


ICI. 

HSH, 

NAG. 

FMT, 

-G,    IDC,    NAC. 

G. 

UPJ. 

UP  J. 

EK. 

ACY, 

DUP, 

G,    ICI,    MAY,    NAC. 

EK. 

SDW. 

SDW. 

EK. 

DUP. 

ALL, 

EKT, 

KLS. 

TRC. 

CWN. 

ACY, 

ICO, 

TBK. 

ALL, 

BUC, 

CWN,    DUP,    LAK,    SDH 

ALL, 

CWN. 

ACY. 

ICO. 

ALL, 

BUC, 

G. 

LIL. 

x. 

LIL. 

LIL. 

LIL. 

LIL. 

LIL. 

G,    ICI,   MAY. 

AAP. 

SDH. 

TKL. 


MEE. 
ABB. 

ACY, 

ICO. 

NAC. 

ACY, 

EK. 

CWN, 

AAP, 

ICO, 

ACP. 

TRC. 

AAP, 

WLM. 

EKT. 

DUP, 

LIL. 

ARA, 

WLM. 

GLY. 

DUP. 

IDC. 

ACY, 

G. 


EKT, 

EK. 

COK, 


DSC,  DUP,    NAC,    SDH. 

DUP. 

DUP,  EK. 

MLS,  RH. 


ACY,    CMG,    DUP,    G,    ICI,    TRC. 

EKT. 
UPJ. 


DUP,    NAC. 
NAC. 
JCC,    SEL. 


78 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  IB. --Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965  —  Continued 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


N-[[  4- (Dimethylsulf amoyl) -o-tolyl] azo] -N-methyl-5-sulfo- 
anthranilic  acid. 

N, N-Dimethylsulf anilic  acid 

N, N-Dimethyl-p-toluidine 

2,4-Dinitroaniline 

*p-(2,4-Dinitroanilino)phenol 

1, 5(and  l,8)-Dinitroanthraquinone 

N, N'-(2,4-Dinitro-l,5-anthraquinonylene)dioxamic  acid 

3',4-Dinitrobenzanilide 

m-Dinitrobenzene 

2,4-Dinitrobenzenesulfonic  acid 

3, 5-Dinitrobenzoic  acid 

3, 5-Dinitrobenzoyl  chloride 

10,10'-Dinitro[3,3'-bi-7H-benz[de]  anthracene] -7, 7 '-dione 

Dinitrocaprylphenol 

2,4-Dinitrocumene 

3,3'-Dinitro-N, N'-diacetylbenzidine 

3', 5' -Dinitro-2' -hydroxyacetanilide 

l-(3,5-Dinitro-2-hydroxyphenylazo)-2-naphthol 

*2,4-Dinitrophenol,  tech 

(2,4-Dinitrophenyl)hydrazine 

3, 5-Dinitrosalicylic  acid 

*4,4'-Dinitrostilbene-2,2'-disulfonic  acid 

2,4-Dinitrotoluene 

2, 4 (and  2,6)-Dinitrotoluene 

3, 5-Dinitro-p-toluenesulf onic  acid 

2,4-Di-tert-pentylphenol 

1, 5-Diphenoxyanthraquinone 

1,5 (and  1, 8 ) -Diphenoxyanthr aquinone 

1,8-Diphenoxyanthraquinone 

Diphenylacetaldehyde 

Diphenylacetic  acid 

Diphenylamine 

2, 8-Diphenylanthra [l,2-d: 6, 5-d']  bisthiazole-6, 12-dione 

a-d-l,2-Diphenyl-4-dimethylamino-2-hydroxy-3-methylbutane, 
camphor  sulfonate. 

N, N'-Diphenylethylenediamine 

Diphenylme thane 

2-(Diphenylmethoxy)-N, N-dimethylethylamine  (Diphenhydra- 
mine base). 

2,  5-Diphenyloxazole 

l,3-Diphenyl-l,3-propanedione 

1, 3-Diphenyltriazene 

2,2'-Dithiodibenzoic  acid 

*l,4-Di-p-toluidinoanthraquinone 

1, 5-Di-p-toluidinoanthr aquinone 

1,8-Di-p-toluidinoanthr aquinone 

l,4-Di(p-toluidine )-5;8-dihydroxy an thr aquinone 

*Divinylbenzene 

Dixylylguanidines,   mixed 

Dodecylbenzene.    (See  Aliylbenzenes. ) 

Dodecylbenzyl  chloride 

Dodecylmethylbenzyl  chloride 

*p-Dodecylphenol 

Bosin   (2',4',5',7'-Tetrabromofluorescein) 

Epoxycyelohexyladipate   (Ipoxide  289) 

3-(lpoxyethyl)-7-oxabicyclo[4.1.0]heptane  (Epoxide  206) 

o-Ethoxybenzoic  acid 

6-Ethoxy-2-benzothiazolethiol 

4- Ethoxy-3-methoxybenzaldehyde 

4-Ethoxy-3-methoxybenzyl  alcohol 

1- (4-  Ethoxy-3-methoxybenzyl )-6, 7-dimethoxy-3-methyl- 
isoquinoline. 

(4-Ethoxy-3-methoxyphenyl )acetic  acid 

2-Ethoxy-l-naphthaldehyde 

2-Ethoxynaphthalene 

2-Ethoxy-l-naphthoic  acid 

2-Ethoxy-l-naphthoyl  chloride 

4-Ethoxy-o-phenylenediamine 

3-(Ethylamino)-p-cresol 

3-(Ethylamino)-p-toluenesulfonic  acid  [S03H=1] 

*N-Ethylaniline,   refined 


G. 

EK,    RSA, 

SEL. 

AAP,    ACT. 

DUP,    G,    NAC. 

AAP,    ICI, 

TRC. 

TRC. 

DUP. 

DUP,    NAC. 

TRC. 

DUP,    GAM, 

SAL. 

EK. 

DUP,    MAY. 

RH. 

DUP. 

AAP. 

TRC. 

TRC. 

AAP,    DUP, 

NAC,    SDC,    VPC. 

EK. 

EK. 

ACT,    DUP, 

G,    GGY,    NAC,    SDH,    TRC 

DUP,    NAC. 

DUP,    MOB. 

NAC. 

PAS. 

DUP,    ICI, 

VPC. 

AAP,    DUP. 

EKT,    ICI. 

ARA. 

ARA,    BPC. 

ACY,    DOW, 

DUP,    0R0. 

ICI. 

LIL. 

DOW,    RPC. 

ARA. 

ARA. 

ARA. 

EK. 

NAC. 

LIL,    MEE. 

ATL,    CMG, 

G,    ICI,    NAC,    TRC,    VPC 

ICI. 

ICI. 

ICI. 

DOW,    FG, 

KPP. 

ACT. 

CO. 

x. 

G,    MON,    UCC,   x. 

ICC. 

UCC. 

UCC. 

ACT. 

ARA,    DUP. 

LIL. 

LIL. 

LIL. 

LIL. 

ICO. 

ICO,    NAC. 

ICO. 

ICO,    OPC. 

TRC. 

DUP. 

DUP. 

ACY,    DUP, 

NAC,    SDH. 

CYCLIC  INTERMEDIATES 


79 


TABLE  7B. 


-Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


2-(N-Ethylanilino)ethanol 

[ 2-( N-Ethylanilino )ethyl] trimethylammonium  chloride 

3-(N-Ethylanilino)propionitrile 

a-(N-Ethylanilino)-m-toluenesulfonic  acid 

<x-(N-Ethylanilino)-p-toluenesulfonic  acid 

N-Ethyl-p-anisidine 

2-Ethylanthraquinone 

*Ethylbenzene 

o-(p-Ethylbenzoyl)benzoic  acid 

Ethylbenzyl  chloride 

9-EthylcarbazQle 

N-Ethyl-N-(2-chloroethyl)aniline 

N-Ethyl-1-cyclohexen-l-ylamine 

3,3'-Ethylenedioxydiphenol 

Ethylenimine 

2-[  N-Ethyl-p- [(6-methoxy-2-benzo-thiazolyl)azo]anilino  ]- 
ethanol. 

N-Ethyl-1-naphthylamine 

9-Ethyl-3-nitrocarbazole 

p-Ethylphenol 

*N-Ethyl-N-phenylbenzylamine 

N-Ethyl-N-phenylbenzylamine  sulfonic  acid 

Ethylphenylmalonic  acid,   diethyl  ester 

l-(o-Ethylphenyl)-3-methyl-2-pyrazolin-5-one 

5-Ethyl-2-picoline  (2-Methyl-5-ethylpyridine)  (MKP) 

1-Ethylpiperidine 

2-Ethylpyridine 

N-Ethyl-5-sulfoanthranilic  acid 

6-Ethyl-l, 2, 3, 4-tetrahydro-l, 1, 4, 4-tetramethylnaphthalene- 

N- Ethyl -m-toluidine 

N-Ethyl-o-toluidine 

2-(N-Ethyl-m-toluidino)ethanol 

3-(N-Ethyl-m-toluidino)-l, 2-propanediol 

3-(N-Ethyl-m-toluidino)propionitrile 

1-Ethynyl-l-eyclohexanol 

Fluorescein  (3',6'-Dihydroxyfluoran) 

l-Fluoro-2, 4-dinitrobenzene 

o-Fluorotoluene 

4-Formyl-m-benzenedisulfonic  acid 

m-Formylbenzenesulfonic  acid,   sodium  salt 

*o-Formylbenzenesulfonic  acid   (o-Sulfobenzaldehyde) 

Fur an 

Furfuryl  alcohol 

Furfurylamine 

Gentisic  acid   (2,5-Dimethoxybenzoic  acid),   methyl  ester— 

Hexachlorobenzene 

Hexachlorocyclopentadiene 

1, 4, 5, 6, 7, 7-Hexachloro-5-norbornene-2, 3-dicarboxylic  acid 

Hexachlorophenyl  ether 

Hexadecachlorophthaloeyanine 

Hexa(2-methyl-l-aziridinyl )-l,3, 5-phosphotriazine 

Hippuric  acid 

*p-Hydrazinobenzenesulfonic  acid 

4-Hydrazino-m-toluenesulfonic  acid 

Hydroquinone,   tech 

2'-Hydroxyacetophenone 

3'-Hydroxyacetophenone 

4'-Hydroxyacetophenone 

3 ' -Hydroxyacetophenone  benzoate 

6'-Hydroxy-m-acetotoluidide 

p-Hydroxybenzaldehyde 

*p-Hydroxybenzenesulfonic  acid 

2-Hydroxy-llH-benzo [a]carbazole-3-carboxylic  acid 

p-Hydroxybenzoic  acid 

p-Hydroxybenzoic  acid,   butyl  ester 

p-Hydroxybenzoic  acid,   ethyl  ester 

p-Hydroxybenzoic  acid,   n-heptyl  ester 

*p-Hydroxybenzoic  acid,   methyl  ester 

*p-Hydroxybenzoic  acid,   propyl  ester 

4-Hydroxycoumarin 

13b-Hydroxy-2, 8-dimethylnaphtho[3 . 2. 1-kl] xanthen-9(l3bH)- 
one. 


Manufacturers '   identification  codes 
(according  to  list  in  table  22) 


DUP, 

EKT. 

DUP. 

EKT. 

G. 

NAC, 

SDH,  TRC,  WJ. 

EKT. 

G,  NAC. 

DOW, 

ENJ,  FG,  KPP,  KPT 

G,  NAC. 

BPC. 

AAP, 

ICC. 

DUP. 

UCC, 

x. 

IDC. 

DOW. 

TRC. 

DSC, 

DUP. 

AAP, 

ICI. 

ACY. 

DOT, 

NAC,  SDH. 

VPC. 

BPC, 

MAL. 

TRC. 

UCC. 

RIL. 

RIL. 

G. 

GIV. 

DUP. 

DUP. 

G. 

EKT. 

DUP, 

EKT,  G. 

cue, 

EKT,  NAC. 

ICC. 

EK. 

EK, 

PIC. 

G,  SDH. 

G. 

G,  NAC,  SDH,  VPC. 

DUP. 

QKO. 

MLS. 

ICO. 

KPS, 

KPT,  SCC. 

HK, 

VEL. 

HK. 

DOW. 

ICC. 

ICO. 

BPC. 

G,  STG,  WJ. 

G. 

CRS, 

EKT,  MAN. 

OTC. 

SDH. 

OTC. 

SDH 

TRC 

DOW 

DOW 

MON,  UPF. 

G. 

HN, 

WSN. 

UN, 

WSN. 

HN, 

WSN. 

WSN 

HN, 

ICO,  SEL,  WSN. 

HN, 

ICO,  WSN. 

MON,    SHC,    SIN,    SNT,    TOC,    UCC. 


80 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  7B.  — Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1 965  --Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


3-[N-(2-Hydroxyethyl)anilino]propionitrile 

N-|3-Ifydroxyethyl-2,4-d  ihydroxybenzanri.de 

3-Hydroxy-N-(2-hydroxyetnyl)-2-naphthanride 

N-t  7-Ifydroxy-8-  [2-hydroxy-5-(methylsulf  amoylphenyl  )azo]  - 

1-naphthyl]  acetanri.de. 
N-L~7-Hydroxy-8-[(2-hydroxy-5-nitrophenyl)azo]-l-naphthyl]- 

acetanride. 
7-Hydroxy-8-  [[<+'-[  (p-hydroxyphenyl  )azo]  -4-biphenylyl]  azo]  - 

1, 3-naphthalenedisulfonic  acid. 
7-Hyd roxy-8-[[  4' -[ (p-hydroxyphenyl )azo] -3, 3-dime  thyl-4- 
biphenylyl]azo]-l, 3-naphthalenedisulfonic  acid. 

4-Hydroxy-N1-isopropy  lmetanilanri.de 

2-Hydroxy-a1,  cc3-mesitylenediol 

*4-Hydroxymetanilanride 

4-ffydroxymetanilanilide 

*4-Hydroxymetanilic  acid 

N-(4-Hydroxymetanilyl)anthranilic  acid 

4-Hydroxy-l-methycarbostyril 

3-Rydroxy-2-methylcinchoninic  acid 

4-Ifydroxy-N1-methy  lmetanilanri.de 

N-(Hydroxymethyl)phthalamide 

Ifydroxynaphthaldehyde 

7-Hydroxy-l-naphthalenecarbamic  acid,   methyl  ester 

3-Hydroxy-2,7-naphthalenedisulfonic  acid 

*3-Hydroxy-2, 7-naphthalenedisulfonic  acid,   disodium  salt 

7-Hydroxy-l, 3-naphthalenedisulfonic  acid 

7-ffydroxy-l, 3-naphthalenedisulfonic  acid,   dipotassium  salt — 

7-Rydroxy-l,3-naphthalenedisulfonic  acid,   disodium  salt 

4-ifydroxy-2-naphthalenesulfonanri.de 

l-Hydroxy-2-naphthalenesulfonic  acid,   potassium  salt 

4-Ifydroxy-l-naphthalenesulfonic  acid 

5-Hydroxy-l-naphthalenesulfonic  acid 

*6-Ifydroxy-2-naphthalenesulfonic  acid 

*6-Rydroxy-2-naphthalenesulfonic  acid,   sodium  salt 

7-Ifydroxy-2-naphthalenesulfonic  acid   (Cassella's  acid) 

8-Hydroxy-l-naphthalenesulfonic  acid 

8-Hydroxy-l-naphthalenesulfonic  acid,  Y-sultone 

4-Ifydroxy-2-naphthalenesulfonie  acid  benzenesulfonate, 
sodium  salt. 

3-Hydroxy-2-naphthanilide  (Naphthol  AS) 

l-Rydroxy-2-naphthoic  acid 

l-lfydroxy-2-naphthoic  acid,   phenyl  ester 

*3-Ifydroxy-2-naphthoic  acid   (B.O.N.) 

3-lfydroxy-2-naphthoie  acid,   methyl  ester 

3-Ifydroxy-2-naphtho-o-toluidide 

N-( 2-Ifydroxy- 1-naphthyl Jacetanride 

*N-(7-Rydroxy-l-naphthyl)acetamide 

l-(2-Ifydroxy-l-naphthylazo)-6-nitro-2 -naphthol -4-sulfonic 
acid. 

N-(7-Ifydroxy-l-naphthyl)benzamide 

3'-[(7-Hydroxy-l-naphthyl)carbamoyl]acetanilide 

4-Ifydroxy-7-[  p-(p-nitrobenzanri.do  )benzamido  ]-2-naphthalene- 

sulfonic  acid. 
4-hydroxy-7-(p-nitrobenzamido)-2-naphthalenesulfonic  acid — 

2-Ifydroxy-5-nitrometanilic  acid 

l-(2-Hydroxy-4-nitrophenylazo)-2-naphthol 

3-Ifydroxy-4-(phenylazo)-2-naphthoic  acid 

lla-Hydroxypregn-4-ene-3,20-dione 

4-Hydroxypropiophenone 

a>  <x'-[  (a-Hydroxy-p-sulf  obenzylidene)bis[  (3-methyl-p- 
phenylene)(ethylimino)]]  di-m-toluenesulfonic  acid. 
2-Hydroxy-4-sulfo-l-naphthalenediazonium  hydroxide,   inner 
salt. 

l-Hydroxy-4-p-toluidinoanthraquinone 

2-Inridazolidinone  modifications 

*1,  l'-Iminobis[4-aminoan'thraquinone] 

1, l'-Iminobis[4-benzamidoanthraquinone] 

*1, l'-Iminobis[5-benzamidoanthraquinone] 

*7,7'-Iminobis[4-hydroxy-2-naphthalenesulfonic  acid] 

*1, l/-Iminobis[4-nitroanthraquinone] 

*l,l'-Iminodiaiithraquinone  (l,l'-Dianthrimide) 


DUP,    ICC. 
IDC. 
IDC. 
TRC. 

TRC. 


TRC. 

ACY. 

CMC, 

DUP, 

NAC,    TRC,    VPC. 

TRC. 

CWN, 

DUP, 

NAC,    TRC. 

TRC. 

ICC. 

DUP, 

ICC, 

TRC. 

TRC. 

ACY. 

ICO. 

TRC. 

ATL. 

ACY, 

G,    NAC,    TRC,    WJ. 

DUP, 

TRC. 

G. 

ACY, 

NAC. 

G. 

EK. 

DUP, 

NAC. 

NAC, 

TRC. 

NAC, 

SNA, 

TMS. 

ACY, 

TRC, 

WJ. 

DUP. 

G,    VPC. 

ACY, 

TRC. 

G. 

ATL, 

PCW. 

NAC. 

EK. 

AUG, 

DUP, 

HN,    PCW. 

PCW. 

ATL, 

PCW. 

ACY. 

CMG, 

G,    TRC. 

TRC. 

TRC. 

TRC. 

DUP. 

DUP, 

G. 

ALL, 

G,    TRC. 

TRC. 

ICC. 

UPJ. 

MLS. 

TRC. 

ACY. 

G,    ICI. 

RH. 

ACY, 

CMG, 

DUP,    G,    ICI,   MAY,    NAC,    TRC 

ACY, 

MAY. 

G,    ICI,    TRC. 

CMG, 

DUP, 

NAC,    TRC. 

ACY, 

DUP, 

ICI,    MAY,    TRC. 

ACY, 

DUP, 

G,    ICI,    MAY,    NAC,    TRC. 

CYCLIC  INTERMEDIATES 

TABLE  7B.  —Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


1,3-Indandione 

Indole-3-acetic  acid- 

Indole-2,3-dione 

1-Iodonaphthalene 

Isobutylbenzene 

*Isocyanic  acid  derivatives : 

Bitolylene  diisocyanate  (TODI) 

Cyclohexyl  isocyanate 

Dianisidine  diisocyanate   (DADI) 

3,4-Dichlorophenyl  ester 

*Diphenylmethane  4,4'-diisocyanate   (MDI) 

Phenylisocyanate 

Polymethylene  polypheny lisocyanate 

Toluene  2,4-diisocyanate 

Toluene  2,4-  and  2,6-diisocyanate   (65/35  mixture) 

*Toluene  2,4-  and  2,6-diisocyanate  (80/20  mixture) 

Other  isocyanic  acid  derivatives 

Isonicotinic  acid,   methyl  ester 

Isonicotinonitrile 

Isooctylphenol 

Isophthalic  acid   (Benzene-l,3-dicarboxylic  acid) 

Isophthalic  acid,   diallyl  ester 

Isophthalic  acid,   dimethyl  ester 

Isophthalic  acid,   diphenyl  ester 

N-Isopropylaniline 

Isopropylbenzyl  chloride 

4,4'-Isopropylidenebis[2, 6-dibromophenol]  (Tetrabromobis- 

phenol  A). 
4,4'-Isopropylidenebis[2,6-dichlorophenol]  ( Tetrachloro- 
bisphenol  A). 

5,5'-Isopropylidenebis(2-hydroxy-m-xylene-a, a'-diol) 

*4,4'-Isopropylidenediphenol  (Bisphenol  A) 

4,4'-Isopropylidenediphenol,  ethoxylated 

4,4'-Isopropylidenediphenol,  propoxylated 

o-Isopropylphenol 

4-Isopropyl-m-phenylenediamine ■ 

Isothiocyanic  acid,  phenyl  ester 

*Isoviolanthrone  (isodibenzanthrone) 

*Leuco  quinizarin  (1,4, 9,10- Anthratetrol) 

2,4-Lutidine ■ 

3,4-Lutidine 

Mandelonitrile 

*Melamine 

dl-p-Mentha-1, 8-diene  (Limonene) 

p-Mentha-l,4(8)-diene 

*o-Mercaptobenzoic  acid 

Metanilamide 

*Metanilic  acid  (m-Aminobenzenesulfonic  acid) 

1-Methoxyanthraquinone 

4-Methoxymetanilic  acid 

6-Methoxymetanilic  acid 

4'-Methoxy-2-(p-methoxyphenyl)acetophenone 

4-Methoxy-l-naphthol 

N-(2-Methoxy-l-naphthyl)aeetamide 

2-Methoxy-4-nitrophenol 

6-Methoxy-8-nitroquinoline 

m-Methoxyphenol 

Methoxyphenylacetic  acid 

4' -Methoxypropiophenone 

6-Methoxytetralone 

*1- ( Methylanri  no ) anthraquinone 

l-(Methylamino)-4-p-toluidinoanthraquinone 

N-Methylaniline 

2-(N-Methylanilino)ethanol 

3-(N-Methylanilino)propionitrile 

5-Methyl-o-anisidine  [ NH2=l] 

m-Methylanisole 

N-Methylanthranilic  acid 

2-Methylanthraquinone 

3-Methylbenzo'[f]quinoline 

2-Methylbenzothiazole 

a-Methylbenzyl  alcohol 


PIC. 

SDW. 

NAC. 

EK. 

PLC. 

UPJ. 

CWN, 

OTC. 

CWN, 

UPJ. 

DUP. 

DuT?, 

MOB, 

NAC,   UPJ. 

CWN, 

MOB, 

OTC. 

MOB, 

UPJ. 

DUP, 

MOB. 

DUP, 

MOB, 

NAC. 

DUP, 

MOB, 

NAC,    CMC,    UCC. 

DUP, 

EK, 

MOB,    OTC. 

RIL. 

RIL. 

G,    PRD. 

ACC, 

SOC. 

FMP. 

MTR. 

BJL. 

ACY, 

EKT. 

BPC. 

DOW. 

DVC. 

ARK. 

DOW, 

MON, 

SHC,    UCP. 

APD. 

APD. 

TNA. 

DUP. 

TNC. 

DUP, 

G,   MAY. 

AAP, 

ACY, 

BL,    EKT,    HSH,    ICC,    NAC,    TRC 

ACP, 

KPT. 

RIL. 

KF. 

ACN, 

ACY, 

FIS,    RCI. 

GIV, 

HNW. 

GIV. 

EVN, 

LIL, 

MED. 

CMG, 

VPC. 

DUP, 

NAC, 

TRC. 

AAP, 

G. 

ACY, 

CMG. 

G. 

CTN. 

SDH. 

TRC. 

MEE. 

GAM. 

EK. 

SDW. 

LIL. 

GAM. 

AAP, 

ACY, 

DUP,    G,    NAC,    TRC. 

G. 

ACY, 

DUP. 

G. 

DUP. 

DUP. 

GIV. 

ICC. 

ACY, 

NAC. 

ACY, 

G. 

FMT. 

UCC. 

82 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  7B.  —  Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1 965  --Continued 


N-Methylbenzylamine 

Methyl  benzyl  ether 

5-(l-Methylbutyl)barbituric  acid 

3-Methylcholanthrene 

Methylcyclohexane 

Methylcyclohexenecarboxaldehyde 

N-Methylcyclohexylamine 

4-Methyl-a,a-diphenyl-l-piperazineethanol  dihydrochloride — 

N-Methyleneaniline 

4,4'-Methylenebis[2-chloroaniline] 

4,4'-Methylenebis[N, N-diethylaniline] 

*4,4'-Methylenebis[N,  N-dimethylaniline]   (Methane  base) 

4,4'-Methylenebis[N,  N-dimethyl-3-nitroaniline] 

5,5'-Methylenebis[toluene-2,4-diamine] 

*4, 4'-Methylenedianiline 

5,5'-Methylenedisalicylic   acid 

5-Methylene-2-norbornene 

Methylhydroquinone 

6-Methyl-2-(2-methyl-6-quinolyl)-7-benzothiazolesulfonic 

acid. 

Methylnaphthalene,  crude 

N-Methyl-4'-nitroacetanilide 

N-Methyl-p-nitroaniline 

5-Methyl-4-nitro-o-anisidine 

4-Methyl-2-nitroanisole 

2-Methyl-l-nitroanthraquinone 

2-Methyl-5-nitroimidazole 

N-Methyl-N-nitroso-p-toluenesulfonamide 

Methylnorbornene-2,3-dicarboxylic  anhydride,    isomers 

4-Methyl-7-oxabicyclo[4.1.0]heptane-3-carboxylic  acid, 

(4-methyl-7-oxabicyclo [4 . 1 . 0] hept-3-yl )methyl  ester 

(Epoxide  201). 

m-(3-Methyl-5-oxo-2-pyrazolin-l-yl)beneenesulfonamide 

m-(3-Methyl-5-oxo-2-pyrazolin-l-yl  )benzenesulfonic  acid 

*p-(3-Methyl-5-oxo-2-pyrazolin-l-yl  )benzenesulfonic  acid 

3-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-l,5-naphthalenedi- 

sulf onic  acid . 
*4-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-m-toluenesulfonic  acid 

[S03H=1]. 

2-Methyl-5-phenylbenzoxazole 

1-Methyl-l-phenylhydrazine 

5-Methyl-3-phenyl-4-isoxazolecarboxylic  acid 

5-Methyl-3-phenyl-4-isoxazolecarboxylic  acid  hydrochloride — 

*3-Methyl-l-phenyl-2-pyrazolin-5-one  (Developer  Z) 

Methyl  phenyl  sulfide  (Thioanisole) 

1-Methylpiperazine 

2-Methyl-l-piperidinepropanol 

l-Methyl-4-piperidinol 

1-Methylpyrrole 

*<x-Methylstyrene 

N-Methyl-5-sulfoanthranilic  acid 

2-(Methylsulfonyl)-4-nitroaniline 

p-(Methylthio)aniline  hydrochloride— 

4-(Methylthio)-m-cresol 

3-Methylthiophene 

p-(Methylthio)phenol 

3-Methyl-6-p-toluidino-7H-dibenz[f,ij]isoquinoline-2,7(3H)- 

dione. 

3-Methyl-l-p-tolyl-2-pyrazolin-5-one 

1-Naphthaldehyde 

^Naphthalene,  solidifying  at  79°  C.  or  above  (refined  flake) 

(from  domestic  crude). 

1, 5-Naphthalenediol  ( 1, 5-Dihydroxynaphthalene ) 

1, 5-Naphthalenedisulf onic  acid 

2,7-Naphthalenedisulfonic  acid 

1-Naphthalenesulfonic  acid 

1-Naphthalenesulfonic  acid,  sodium  salt 

2-Naphthalenesulfonic  acid 

2-Naphthalenesulfonic  acid,  sodium  salt 

2-Naphthalenesulfonyl  chloride 

*1, 4, 5,8-Naphthalenetetracarboxylie  acid 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


ICO,  MLS. 

UCC. 

LIL. 

EK. 

PLC. 

UCC. 

DUP. 

ABB. 

DUP. 

DUP. 

ACY,  G. 

ACY,  DSC,  DUP,  G,  NAC,  SDH, 

G. 

DUP,  NAC. 

DOW,  DUP,  NAC. 

HN. 

DOW. 

EKT. 

DUP. 

KPT,  VEL. 

G,  NAC. 

G. 

PCW. 

DUP. 

DUP,  G,  ICI,  TRC. 

PDA. 

EK. 

NAC. 

UCC. 


CMG,  VPC. 

G,  TRC,  VPC. 

AAP,  ACY,  CMG,  DUP,  G,  TRC,  VPC. 

TRC. 


CMG,  G,  VPC. 


EK. 


EK. 

ICO. 

ICO. 

DOW,  DUP,  NAC,  SDH,  SDW,  VPC. 

PIT. 

UCC. 

LIL. 

ARA. 

DUP. 

ACP,  CLK,  DOW,  HPC,  SKL. 

G. 

EKT. 

evn. 

CRZ. 
SDW. 
CRZ. 


VPC. 
COK. 
KPT,  NAC,  RIL. 

NAC. 

AUG,  DUP,  NAC. 

DUP,  TRC. 

TRC. 

ICO,  TRC. 

ACY,  FIN,  NAC. 

ACY. 

DUP. 

AAP,  G,  HST,  TRC. 


CYCLIC  INTERMEDIATES 


83 


TABLE  7B. 


■  Cyclic  intermediates  for  which  U.  S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


1,3,6-Naphthalenetrisulfonic  acid 

Naphthalic  anhydride 

Naphthalimide 

2H-Naphth[l,8-cd]isothiazole-3,5-disulfonic  acid,   1,1- 

dioxide,   trisodium  salt. 
1-Naphthoic  acid 

*l-Naphthol  (cc-Naphthol) 

2-Naphthol,  tech.  (8-Naphthol) 

p-Naphtholbenzein 

1,4-Naphthoquinone 

Naphthostyril 

*Naphth[l, 2-d] [l,2,3]oxadiazole-5-sulfonic  acid 

1-Naphthylamine  (a-Naphthylamine) 

2-Naphthylamine  (B-Naphthylamine) 

p- ( 2-Naphthylamino )phenol  ( N-  (p-Hydroxyphenol ) -2-naphthyl- 
amine). 

cc-Naphthylphenyloxazole 

2- ( Naphthylthio ) acetic  acid 

Nicotinonitrile  (3-Cyanopyridine) 

Nitro-aceanthra [2, 1-a] aceanthrylene-5, 13-dione 

4'-Nitroacetanilide 

2'-Nitro-p-acetanisidide 

3 ' -Nitro-p-acetanisidide 

4'-Nitro-o-acetanisidide 

2'-Nitro-p-acetophenetidide 

3'-Nitroacetophenone 

5'-Nitro-o-aeetotoluidide 

m-Nitroaniline 

o-Nitroaniline 

*p-Nitroaniline 

2-Nitro-p-anisidine  [NH2=1] 

*4-Nitro-o-anisidine  [NH2=l]- 

*5-Nitro-o-anisidine  [NH2=l]- 

o-Nitroanisole 

p-Nitroaaisole 

4-Nitroanthranilic  acid 

4(and  5)-Nitroarithranilic  acid '■ 

5-Nitroanthranilic  acid 

1-Nitroanthraquinone 

2- (4-Nitro-2-anthraquinonyl )anthra[ 2, 3-d] -oxazole-5, 10- 
dione. 

m-Nitrobenzaldehyde 

3'-Nitrobenzanilide 

4'-Nitrobenzanilide 

*Nitrobenzene 

■xm-Nitrobenzenesulfonic  acid 

*m-Nitrobenzenesulfonic  acid,    sodium  salt 

5'-Nitrobenzenesulfono-o-toluidide 

m-Nitrobenzenesulfonyl  chloride 

p-Nitrobehzenesulfonyl  chloride 

5-Nitro-2-benzimidazolinone 

m-Nitrobenzoic  acid 

m-Nitrobenzoic  acid,  sodium  salt 

p-Nitrobenzoic  acid 

2-(m-Nitrobenzoyl)-o-acetanisidide 

m-Nitrobenzoyl  chloride 

p-Nitrobenzoyl  chloride 

4' -Nitro-4-biphenylcarboxylie  acid 

2-Nitro-p-cresol 

Nitrocyclohexane 

5-Nitro-4,6-diaminopyrimidine 

Nitrodiphenylamine 

5-Nitro-2-furaldehydesemioxamazone 

5-Nitro-2-furanmethanediol,  diacetate 

5-Nitroisatoic  anhydride 

5-Nitroisophthalic  acid »- 

1-Nitronaphthalene ' 

*3-Nitro-l,5-naphthalenedisulfonic  acid 

8(and  5)-Nitro-l(and  2)-naphthalenesulfonic  acid 

4-Nitronaphthalic  anhydride 

*7(and  8)-Nitronaphth[l,2-d]  [l,2,3]oxadiazole-5-sulfonic  acid 


DUP. 

DUP, 

G,    NAC. 

DUP. 

COK. 

DUP, 

NAC, 

UCC. 

ACY, 

NAC, 

SW. 

EK. 

EKT. 

DUP, 

NAC. 

CMG, 

G,   NAC,    TRC,    VPC. 

DUP, 

NAC. 

X. 

G. 

ARA. 

ACY. 

NEP, 

RIL. 

ICI. 

G,    TRC. 

DUP, 

SDH. 

AAP. 

DUP. 

AAP. 

SDH. 

DUP. 

ACY, 

DUP, 

TRC. 

AAP, 

MON. 

AAP, 

MON, 

SDC,    UPM. 

DUP, 

SDH. 

AAP, 

DUP, 

SDH. 

ACY, 

ALL, 

DUP,    KLS. 

AAP, 

DUP, 

MON. 

DUP. 

DUP. 

DUP. 

MEE, 

TRC. 

ACY. 

G. 

NAC, 

SDH. 

DUP. 

G. 

ACY, 

DUP, 

MON,    NAC. 

ACY, 

DUP, 

NAC. 

AAP, 

G,   MAY,   MON,    MRA 

RBC. 

G. 

EK. 

DUP. 

SDH, 

WAY. 

WAY. 

DUP. 

G. 

HK. 

DUP, 

HK. 

DUP, 

TRC. 

SW. 

DUP. 

KF. 

ACY. 

NOR. 

NOR. 

MEE. 

G,    GAM. 

DUP, 

NAC. 

G,    NAC,    TRC. 

G. 

G,    NAC. 

G,    NAC,    TRC,    VPC. 

SYNTHETIC  ORGANIC  CHEMICALS,  1965 

—Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965—  Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


4'-Nitrooxanilic  acid 

o-Nitrophenol 

*p-Nitrophenol ■ 

*p-Nitrophenol,    sodium  salt 

4' -(p-Nitrophenyl )acetophenone 

4-[ (p-Nitrophenyl )azo]-o-anisidine 

2-Nitro-p-phenylenediamine 

4- Nitro-o-phenylenediamine 

(p-Nitrophenyl )hydrazine 

(p-Nitrophenyl )hydrazine  hydrochloride 

2-(p-Nitrophenyl)-2H-naphtho[l,2-d] triazole-6, 8-disulfonic 
acid. 

l-(m-Nitrophenyl)-5-oxo-2-pyrazoline-3-carboxylic  acid 

3-Nitrophthalic  acid 

4-  Nitrophthalic  acid 

3-Nitrophthalic  anhydride 

4-Nitrophthalimide 

5-Nitrosalicylaldehyde 

3(and  5)-Nitrosalicylic  acid 

p-Nitrosophenol 

[3-Nitrostyrene 

4-Nitro-4'-(5-sulfo-2H-naphthol[l,2-d]triazol-2-yl)-2,2'- 
stilbenedisulfonic  acid. 

m-Nitrotoluene 

o-Nitrotoluene 

p-Nitrotoluene 

Nitrotoluene  mixtures 

p-Nitrotoluenesulfonic  acid 

*3-Nitro-p-toluenesulfonie  acid  [S03H=l] 

*5-Nitro-o-toluenesulfonic  acid  [S03H=l] 

4'-Nitro-p-toluenesulfono-o-toluidide 

3-Nitrotoluic  acid  chloride 

3-Nitro-p-toluic  acid,   methyl  ester 

*2-Nitro-p-toluidine  [NH2=l] 

4-Nitro-o-toluidine  [NH2=l] 

5-Nitro-o-toluidine  [NH2=l] 

5-Nitro-2-p-toluidinobenzenesulfonic  acid 

*16-Nitroviolan throne 

4-Nitro-m-xylene 

Nitroxylenes,  mixed 

2-tert-Nonyl-p-cresol 

Nonyl-dinonylphenol,  mixture 

*Nonylphenol 

5-Norbornene-2,3-dicarboxylic  anhydride 

Octylphenol 

7-0xabicyclo[4.1.0]heptane 

Qxalacetic  acid,   diethyl  ester,    (p-sulf ophenyl )hydrazone 

Oxanilide 

*l-[ (7-0xo-7H-benz[de]anthracen-3-yl)amino]  anthraquinone 

*1,  l'-[(7-Oxo-7H-benz[de]anthracen-3,9-ylene)diimino]di- 
anthr aquinone . 

2-Qxocyclohexanecarboxylic  acid,  ethyl  ester 

2-0xocyclopentanecarboxylic  acid,  ethyl  ester 

5-Qxo-l-phenyl-2-pyrazoline-3-carboxylic  acid 

*5-0xo-l-phenyl-2-pyrazoline-3-carboxylic  acid,  ethyl  ester — 
*5-Qxo-l- (p-sulf ophenyl )-2-pyrazoline-3-carboxylic  acid 
( Pyrazolone  T ) . 

5-Qxo-l-(p-sulfotolyl)-2-pyrazoline-3-carboxylic  acid 

4,4'-0xydianiline 

4,4'-0xydiphenol 

Penicillin,    N-ethylpiperidine  salt 

1, 1, 3,3,5-Pentamethylindan 

Pentylnaphthalenes   ( Amy lnaph thai enes ) 

o-Pentylphenol   (o-Amylphenol ) 

p-tert-Pentylphenol 

3,4, 9, 10-Perylenetetracarboxylic  acid 

3,4, 9,10- Perylenetetracarboxylic  3,4:9, 10-diimide 

Phenethylamine 

Phenethylamine  sulfate 

o-Phenethylbenzoic  acid 

o-Phenetidine 

p-Phenetidine 


DUP. 

DUP. 

DUP,    MON,    SDC,    UPM. 

MON,    UPM. 

DUP,    G. 

AAP. 

WAT. 

DUP,    FMT. 

EK. 

EK. 


ACY, 

DUP, 

NAC. 

OWN, 

UPJ. 

TRC 

DUP, 

NAC. 

DUP, 

NAC. 

DUP, 

NAC. 

DUP, 

NAC. 

GGY. 

AAP, 

CMG, 

G,    TRC. 

ACY, 

DUP, 

G,    NAC,    SDH,    TRC. 

G. 

X. 

SDH. 

ACY, 

DUP, 

NAC,    SDH,    SW. 

ABB, 

G. 

BUC, 

DUP, 

KLS,    PCW. 

TRC. 

ACY, 

ATL, 

G,    ICI,    MAY. 

DUP. 

DUP, 

NAC. 

USR. 

JCC. 

G,    JCC,    MON,    PRD,    RH,    STP,    UCP,    USR 

NAC. 

G,    RH. 

ARA. 

TRC. 

WSN. 

ACY, 

DUP, 

G,    ICI,   MAY,    TRC. 

ACY, 

DUP, 

G,    ICI,    MAY,    NAC,    TRC. 

ARA. 

ARA. 

NAC. 

G,    SDW,    VPC. 

AAP, 

G,    ICI,    VPC. 

VPC. 

OTC, 

X. 

EK. 

MRK. 

GIV. 

PAS. 

PAS. 

PAS, 

UCP. 

DUP, 

G,    NAC. 

DUP, 

G,    NAC. 

ICO, 

MLS. 

MLS. 

LIL. 

MON. 

DOW, 

MON. 

CYCLIC  INTERMEDIATES 


85 


TABLE  7B. 


■Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965  — Continued 


•Phenol: 
•Natural : 

•From  coal  tar:1 

39°  C,  m.p 

82^-84% 

All  other 

•From  petroleum 

•Synthetic: 

By  caustic  fusion:  U.S.P 

From  chlorobenzene  by  liquid -phase  hydrolysis:  U.S.P 

From  chlorobenzene  by  vapor-phase  hydrolysis:  U.S.P 

•From  cumene  by  oxidation:  U.S.P 

Phenolsulfonaphthalein,  sodium  salt — 

Phenothiazin-2-yl-l-propanone 

Fhenoxyacetic  acid,  sodium  salt 

2-Phenoxypropanol 

2-Phenoxypropionic  acid 

2-Phenoxypropionyl  chloride 

•Phenylacetic  acid   (a-Toluic  acid) 

Phenylacetic  acid,    ethyl  ester,   tech 

Phenylacetic  acid,   methyl  ester 

•Phenylacetic  acid,   potassium  salt 

•Phenylacetic  acid,    sodium  salt 

Phenylacetonitrile  (a-Tolunitrile) 

4'-Phenylacetophenone 

Phenylacetyl  chloride 

2-Phenylanthra[2,3-d]  oxazole-5, 10-dione 

»p-Phenylazoaniline   (C. I.   Solvent  Yellow  1)  and  hydrochloride 

p-Phenylazoaniline  sulfate 

4- ( Phenylazo  )diphenylamine 

4- ( Phenylazo ) -1-naphthylamine 

4- ( Phenylazo  )-m-phenylenediamine   (C.I.    Basic  Orange  2) 

5- ( Phenylazo )salicylic  acid 

^-Phenyl-l,  2,4-benzenetriamine 

l-Phenyl-l,3-butanedione 

2-Phenylbutyric  acid 

a-Phenyl-o-cresol 

1-Phenyldecane  ( Decylbenzene ) 

N,  N'-p-Phenylenebis[acetamide] 

m-Phenylenediamine 

o-Phenylenediamine 

p-Phenylenediamine 

Phenyl  ether   (Diphenyl  oxide) 

d-2-Phenylglycine 

d-(-)-2-Phenylglycine  and  derivatives 

dl-2-Phenylglycine  (racemic ) 

Phenylglycine,   sodium  salt 

d-(-)-2-Phenylglycyl  hydrochloride 

5-Phenylhydantoin-- 

Phenylhydrazine 

Phenylhydrazine  hydrochloride 

2,2'-[(Phenyl)imino]diethanol   (N-Phenyldiethanolamine) 

3,3'-[(Phenyl)imino]dipropionitrile 

Phenylmagnesium  bromide 

Phenylmalonic  acid,   diethyl  ester 

o-Phenylphenol 

o-Phenylphenol,    chlorinated 

o-Phenylphenol,    sodium  salt 

p-Phenylphenol 

N-Phenyl-p-phenylenediamine 

Phenylphosphinic  acid 

Phenylphosphonic  dichloride 

Phenylphosphonothioic  dichloride 

Phenylphosphonous  acid 

Phenylphosphonous  acid,   sodium  salt 

Phenylphosphorous  dichloride 

1-Phenylpiperazine " 

«1-Phenyl-1, 2-propanedione,   2-oxime 

Phenyl-2-propanone 

N-3-Phenylpropyl-p-toluidine 

See  footnote  at  end  of  table. 


Manufacturers '    identification  codes 
(according  to  list  in  table  22) 


KPT,  PRD. 

ACP,  KPT. 

ACP,  KPT. 

MER,  NPC,    PIT,    PRD,    SW. 


MAL, 

DOW. 

HKD, 

ACP, 

EK. 

WYT. 

BPC. 

ICO. 

ICO. 

ICO, 

BPC, 

BPC. 

BPC. 

BPC, 

BPC, 

BPC, 

DUP, 

ICO. 

G. 

AAP, 

DUP. 

EK. 

DUP. 

DUP. 

TRC. 

RBC. 

EK. 

BPC. 

RBC. 

NAC. 

ACY. 

ACY, 

FMT, 

ACY, 

DOW. 

BPC. 

KF. 

KF. 

NAC, 

OTC. 

ABB, 

DOW. 

EK, 

AAP, 

DUP. 

ARA. 

BPC. 

DOW, 

DOW. 

DOW. 

DOW. 

DUP, 

SF. 

SF. 

SF. 


RSA. 
ICC, 
ORT, 


MON,    RCI. 


CLK,    HPC,    MON,    SHC,    SKO,    SOC. 


OPC. 

GIV,    MAL,    TBK. 


OPC,    TBK. 
OPC. 

OPC,    SDW. 
G,    NES. 


ACY,    DUP,    G,    NAC. 


DUP,    G.    NAC. 
MEE,    TRC. 
BFG. 


VPC. 
DUP,    EKT. 


NEP,    ORT,   x. 
SK. 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  7B. 


-Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  2365--Continued 


Phenyl  2-pyridyl  ketone 

Phenyl  4- pyridyl  ketone 

Ehenyl  sulfone 

l-Fhenyl-2-thiourea 

Phloroglueinol 

l(2H)-Fhthalazinone 

Ehthalic  acid 

Ehthalic  acid,   diallyl  ester 

Ehthalic  acid,   disodium  salt 

*Fhthalic  anhydride 

Ehthalide 

Ehthalimide 

Ehthalimide,  potassium  salt 

IEhthalocyaninatoC 2-)] copper 
Ehthalocyaninato(2-)]iron 

Ehthalocyaninetetrasulfonyl  chloride,  copper  derivative 
Ehthaloyl  chloride  (Ehthalyl  chloride) 

♦Ficolines:1 

*2-Picoline  (a-Picoline) 

3-Picoline   (fi  -Picoline) 

4-Pieoline   (y-Picoline) 

Ficoline   (3,4-mixture) 

Picolinic  acid 

Picolinonitrile   (2-Cyanopyridine) 

3-Picolylamine 

Picric  acid   (Trinitrophenol) 

2-Pipecoline 

4-Pipecoline 

Piperazine  mixture,   crude 

*Piperidine 

3-Piperidinopropiophenone  hydrochloride 

Polychlorobiphenyl 

Primuline  base ■ 

Primulinesulfonic  acid 

*Propiophenone 

2-Propylpyridine 

*8, 16-Pyranthrenedione 

Pyridine,   refined  z1 

*2°   Pyridine 

Other  grades 

Pyridine  hydrochloride 

2-Pyridineethanol 

3-Pyridinemethanol 

Pyridinium  bromide  perbrond.de 

3-Pyridinol 

2(lH)-Pyridone 

2-Pyrimidinol 

2-Pyrrolidinone 

3-(l-Pyrrolidinyl)propiophenone  hydrochloride 

lH-Pyrrolo [2, 3-6] pyridine 

*Quinaldine 

Quinoline : 

1°  and  2°  Quinoline 

Other  grades 

2,4-Quinolinediol 

8-Quinolinol  (8-Hydroxyquinoline,  tech. ) 

Quinophthalone  (Quinoline  yellow,  base) 

Resorcinol,  monoacetate  (nonmedicinal  grade) 

Resorcinol,  tech 

Resorcinol,  mono-fi-hydroxyethyl  ether 

p-Resorcylaldehyde— 

(3-Resorcylic  acid 

(3-Resorcylic  acid,  lead  salt 

*Salicylaldehyde 

*Salicylic  acid,  tech 

Salicylic  acid,  ammonium  chromium  complex 

Salicylic  acid,  sodium  chromium  complex 

Salicylic  acid,  sodium  salt  (crude) 

Salicylideneaminoguanidine  oleate 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


NEP,  RIL. 

RIL. 

NES. 

ICO. 

MRT. 

KPT,  NAC,  SDH. 

EK,  KF. 

FMP. 

INC. 

ACP,  GRH,  HN,  KPS,  MON,  PCC,  RCI,  SOC,  STP,  SW,  THC, 

UCC,  WTC. 
FMT,  NAC. 
DUP,  MEE,  NAC. 
EK. 

ICC,  ICI. 
DUP. 
DUP. 
MON. 

ACP,  KPT,  RIL,  UCC. 

NEP,  RIL. 

RIL,  UCC. 

ACP,  KPT. 

NEP. 

NEP,  RIL. 

RIL. 

DUP,  NAC,  SDC. 

LIL. 

RIL. 

FLM,  JCC,  x. 

ABB,  DUP,  RIL. 

ACY. 

MON. 

DUP,  NAC. 

ATL. 

LIL,  OPC,  TBK. 

RIL. 

CMG,  ICI,  TRC. 

ACP,  KPT,  NEP,  RIL. 

KPT. 

EK. 

RIL. 

RIL. 

ARA. 

NEP. 

FMT. 

GGY. 

G. 

LIL. 

SDW. 

ACY,  DUP,  NAC. 

ACP,  KPT. 

EK. 

DUP. 

GAM. 

DUP,  NAC. 

AAP. 

KPT. 

BJL. 


ACY, 
ACY. 
DOW, 
CFC, 
TRC. 
TRC. 
DOW. 
DUP. 


HN,  MTR,  RDA. 
DOW,  HN,  MON,  SDH. 


See  footnote  at  end  of  table. 


CYCLIC  INTERMEDIATES 


87 


TABLE  7B.  --Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


Manufacturers'   identification  cede 
(according  to  list  in  table  22) 


Sitosterols,   nonmedicinal 

Sodium  phenoxide 

*Styrene,    all  grades 

(3-Styrenesulfonic  acid,  sodium  salt 

4'-Sulfamoylacetanilide 

Sulfanilic  acid  (p-Aminobenzenesulfonic  acid)  and  salt 

4-Sulfoanthranilic  acid 

«>a-[(p-Sulfobenzylidene)bis[(3-methyl-p-phenylene) (ethyl 
imino)]]  di-m-toluenesulfonic  acid. 

5-Sulfoisophthalic  acid,  1,3-dimethyl  ester 

3,3'-Sulfonyldianiline 

4,4'-Sulfonyldianiline 

N,  5'-Sulfonyldianthranilic  acid 

3,3'-Sulfonyldinitrobenzene 

4,4'-Sulf onyldiphenol  (4,4  '-Dihydroxydiphenylsulfone) 

4-Sulfophthalic  acid 

Terephthalic  acid 

Terephthalic  acid,  dihydrazide 

*Terephthalic  acid,  dimethyl  ester 

Terephthalic  acid,  diphenyl  ester 

Terephthaloyldiacetic  acid,  diethyl  ester 

Terphenyl  ( Phenylbiphenyl ) 

1,2,4, 5-Tetraaminobenzene 

[4,4', 4",  4'"  -Tetr  aaminophthalocyaninato  ( 2- )  ]  copper 

3',3",5',5"  -Tetrabromophenolphthalein,  ethyl  ester 

Tetrabromophthalic  anhydride 

Tetrabromo-8, 16-pyranthrenedione 

1,3,6, 8-Tetrabromopyrene 

*1, 4, 5, 8-Tetrachloroanthraquinone 

1,2,4, 5-Tetrachlorobenzene 

1, 2, 4, 5-Tetrachloro-3-nitrobenzene 

a,a,2,6-Tetrachlorotoluene 

Tetrachloroviolan throne 

Tetrahydrofuran 

Tetrahydro-2-methylfuran 

*1,4, 5,8-Tetrahydroxyanthraquinone,  leuco  derivative 

1,4, 5,8-Tetrakis(l-anthraquinonylamino)anthraquinone 
( Pentanthr imid  e ) . 

2-(l,l,3,3-Tetramethylbutyl)-p-cresol 

p-(l, l,3,3-Tetramethylbutyl)phenol 

3,3 ', 5, 5' -Tetramethyldiphenoquinone 

N, N, N', N'-Tetramethyl-p-phenylenediamine  dihydrochloride- 

[4,4',4",4'"-Tetranitrophthalocyaninato(2-)]copper 

1, 1,4,4-Tetraphenylbutadiene 

2-(2-Thenylamino)pyridine 

3,3'-Thiobis[7H-benz[de]anthracen-7-one] 

4,4'-Thiodianiline 

6, 6'-Thiodimetanilic  acid 

2-Thiopheneacetyl  chloride ■ 

2-Thiophenecarbox aldehyde 

sym- Thymol 

*Toluene-2,4-diamine  (4-m-Tolylenediamine) 

Toluene-2,4-disulfonic  acid 

o-Toluenesulfonamide 

p-Toluenesulfonamide 

*o(and  p)-Toluenesulfonic  acid 

p-Toluenesulfonic  acid 

Toluenesulfonic  acid,  aniline  salt 

p-Toluenesulfonic  acid,  2-chloroethyl  ester 

p-Toluenesulfonic  acid,  ethyl  ester 

p-Toluenesulfonic  acid,  methyl  ester 

p-Toluenesulfonic  acid  monohydrate 

p-Toluenesulfono-o-toluidide 

p-Toluenesulfonyl  chloride 

m-Toluic  acid 

o-Toluic  acid 

p-Toluic  acid 

m-Toluidine 

o-Toluidine 

o-Toluidine  hydrochloride 


UPJ. 

DUP. 

ACC,  CSD,  DOW,  ELP,  FG,  KPP,  MCB,  MON,  SHC,  SKC,  SNT, 

UCC. 
BKL. 

ACY,  CTN. 
ACY,  CTN,  NAC. 
CMG,  TRC. 
TRC. 


RSA. 
TRC. 


G,  MON,  UPF. 

CWN,  UPJ. 

ACC,  DUP,  EKT,  SOC. 

DUP. 

ACC,  DUP,  EKT,  HPC. 

BJL. 

G,  PCW. 

ARA,  MON. 

BJL. 

DUP. 

EK. 

MCH. 

G,  NAC. 

G. 

DUP,  G,  ICI,  NAC. 

DOW,  HK. 

SDH. 

DUP. 

G,  ICI. 

DUP,  OKO. 

DUP,  QKO. 

G,  ICC,  NAC,  TRC. 

ICI,  NAC. 


ACY. 

G. 

DUP. 

EK. 

DUP. 

ARA. 

ABB. 

DUP, 

ACY, 

NAC. 

LIL. 

ABB. 

GIV. 

ACY, 

G. 


G,  ICI. 
NAC. 


DUP,  G,  NAC,  CMC,  SDC,  TRC,  UCC. 


MON. 

MON. 

MON, 

ACY, 

NES. 

G. 

NAC. 

ICI. 

NES, 

G. 

MON. 

CWL. 

CWL. 

CWL, 

DUP, 

DUP, 

ACY. 


NAC,  NES,  SW,  UPF. 
TEN. 


EK. 

NAC. 

NAC. 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 

TABLE  IB.  — Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1 965  --Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


p-Toluidine 

p-Toluidine  hydrochloride 

N-(p-Toluidine)methyl taurine 

Toluidines,   mixed 

m-Toluidinomethanesulfonie  acid 

8-p-Toluidino-l-naphthalenesulfonic  acid 

o-(p-Toluoyl)benzoic  acid 

N-(p-Tolylazo)sarcosine 

*4-(o-Tolylazo)-o-toluidine   (C.I.   Solvent  Yellow  3) 

4-(o-Tolylazo)-o-toluidine  hydrochloride 

1-p-Tolyldodecane 

2,2'-(m-Tolylimino)diethanol 

N,  N,  N-Tribenzylamine 

1, 2, 3( and  1, 2,4  )-Trichlorobenzene 

1, 2,4-Trichlorobenzene 

N, 2, 6-Trichloro-p-benzoquinoneimine 

1, 2,4-Trichloro-5-nitrobenzene 

Trichlorophenylsilane 

<x,a,a-Trichlorotoluene  (Benzotrichloride) 

<x,2,4-Trichlorotoluene 

a,2,4(anda,2, 6)-Trichlorotoluene 

2,4, 6-Trichloro-s-triazine 

1,3,5-Triethylbenzene 

N,  N,  N'-Triethyl-N'-phenylethylenediamine 

2-(Trifluoromethyl)phenothiazine 

a,a,a_Trifluoro-4-nitro-m-cresol 

a,a,a-Trifluoro-m-nitrotoluene 

a,a,a-Trifluoro-N-phenyl-m-toluidine  (3-(Trifluoromethyl) 
diphenylamine ) . 

<x,a,«-Trifluorotoluene 

a,a,a_Trifluoro-m-toluidine 

1, 2,4-Trihydroxyanthraquinone 

3,4, 5-Trimethoxybenzoic  acid 

2,4, 5-Trimethylaniline   (Pseudocumidine) 

1, 2,4-Trimethylbenzene  (Pseudocumene) 

2,3,3-Trimethyl-3H-indole 

*l,3,3-Trimethyl-A2»a-indolineacetaldehyde 

*l,3,3-Trimethyl-2-methyleneindoline  (Trimethyl  base) 

Trimethylphenylammonium  iodide 

«,«',  2-Trimethyl-l,4-piperazinediethanol 

2,4, 6-Trimethylpyridine 

1,3, 5-Trinitrobenzene 

2,4,7-Trinitrofluoren-9-one 

2,4, 6-Trinltroresoreinol,  lead  derivative 

Triphenylmethanol 

Triphenylsulfonium  chloride 

a., a.', a."  -Tris(dimethylamino)mesitol 

Tris(2-methyl-l-aziridinyl)phosphine  oxide 

2,4,6-Tris(2-methyl-l-aziridinyl)-s-triazine 

Tropine 

m-Ureidoaniline 

*7, 7'-Ureylenebis[4-hydroxy-2-naphthalenesulfonic  acid] 
(J  acid  urea). 

Veratraldehyde   (3,4-Dimethoxybenzaldehyde) 

Veratryl  alcohol  (3,4-Dimethoxybenzyl  alcohol) 

p-Vinylbenzenesulfonic  acid,   sodium  salt 

2-Vinylcyclohexene 

4-Vinylcyclohexene 

2,2  -Vinylenebis[benzimidazole] 

5-Vinyl-2-picoline   (MVP) 

2-Vinylpyridine 

4-Vinylpyridine 

*Violanthrone   (Dibenzanthrone) 

Xanthene-9-carboxylic  acid 

m-}iylene 

*o-Xylene 

*p-Xylene 

Xylenesulfonic  acid 

2, 5-Xylenesulf onic  acid 

2,4-Xylenol 

Xylenol  crystals 


DUP, 

NAC. 

EK. 

BUC. 

DUP. 

TRC, 

VPC. 

NAC. 

ACY, 

NAC. 

G. 

ACY, 

ALL, 

DUP,    G,    KLS,    NAC,    SDH. 

G. 

X. 

EKT. 

MLS. 

PPG. 

DOW, 

HK, 

SVT. 

EK. 

PCW. 

DCC, 

UCS. 

HK, 

VEL. 

HN. 

BPC. 

ACY, 

GGY, 

NIL. 

DUP. 

DUP. 

SK. 

MEE. 

SK. 

HK. 

MEE. 

G. 

ICO, 

KF. 

NAC. 

ENJ. 

G. 

DUP, 

G,    VPC. 

DUP, 

G,    NAC,    VPC. 

EK. 

WYN. 

KPT, 

RIL. 

EK. 

EK. 

REM. 

EK. 

GAM. 

RH, 

TKL. 

ICO. 

ICO. 

CTN. 

ICI. 

ACY, 

ATL, 

BKS,    BL,    CMG,    G,    NAC,    TRC,    VPC. 

GIV, 

LIL, 

SLV. 

LIL. 

DUP. 

UCC. 

PLC. 

TRC. 

PLC. 

RIL. 

RIL. 

ACY, 

ATL, 

DUP,    G,    ICI,   MAY,    TRC. 

PLC, 

SNT, 

SOC. 

ASH, 

CCP, 

COR,    CSD,    CSO,    DLH,    ENJ,    SIN,    SNT,    SOC 

TOC. 

CSD, 

ENJ, 

SIN,    SNT,    SOC. 

NE3. 

EK. 

EK. 

ACP, 

KPT. 

CYCLIC  INTERMEDIATES 


TABLE  7B. — Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965  — Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


#Jtylenols : 

Low  b.p 

Medium  b.p 

Not  classified  as  to  b.p 

)iylidines : 

2,4-)fylidine   (m-4-Xylidine)- 

2, 5-Xylidine   (p-Xylidine ) 

2, 6-Xylidine 

Original  mixture 

4-  (2, 4-J!ylylazo )  -o-toluidine— ■ 
4- (2, 5-)fylylazo )-o-toluidine-— 

4-(Xylylazo)xylidine 

4-  ( 2, 4-Jiylylazo )  -2, 5-xylidine- 
All  other  cyclic  intermediates' 


NPC, 

PIT, 

PRD. 

KPT, 

NPC, 

PIT. 

KPT, 

NPC, 

PRD. 

DUP, 

NAC. 

DUP, 

NAC. 

DUP. 

DUP, 

NAC. 

NAC. 

ACY. 

ARA,  G,  HPC,  ICC,  IDC,  LIL,  UPJ,  VPC,  x,  x,  x. 


1  Does  not  include  manufacturers '  identification  codes  for  producers  that  report  to  the  Division  of  Bituminous 
Coal,  U.S.  Bureau  of  Mines.  These  producers  are  listed  in  the  U.S.  Bureau  of  Mines  Mineral  Industry  Survey  Coke 
Producers   in   the  United  States  in  1964,   May  17,  1965. 


90 


SYNTHETIC  ORGANIC  CHEMICALS.  1965 


Dyes 

TABLE  8B.  —  Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported, 
identified  by  manufacturer,  1965 


[Dyes  for  which  separate  statistics  are  given  in  table  8A  are  marked  below  with  an  asterisk  (*);  dyes  not  so  marked 
do  not  appear  in  table  8A  because  the  reported  data  are  accepted  in  confidence  and  may  not  be  published.  Manufac- 
turers' identification  codes  shown  below  are  taken  from  table  22.  An  x  signifies  that  the  manufacturer  did  not 
consent  to  his  identification  with  the  designated  product] 


Dye 


Manufacturers ■  identification  codes 
(according  to  list  in  table  22) 


ACID  DYES 

*Acid  yellow  dyes: 

Acid  Yellow  1 

Acid  Yellow  2 

*Acid  Yellow  3 

Acid  Yellow  4 

Acid  Yellow  7 

Acid  Yellow  9 

*Acid  Yellow  11 

Acid  Yellow  14 

*Acid  Yellow  17 

*Acid  Yellow  23 

Acid  Yellow  25 — 

Acid  Yellow  29 

Acid  Yellow  34 

Acid  Yellow  35 

*Acid  Yellow  36 

Acid  Yellow  38 

*Acid  Yellow  40 

*Acid  Yellow  42 

Acid  Yellow  43- 

*Acid  Yellow  44 

*Acid  Yellow  54 

Acid  Yellow  59 

Acid  Yellow  60 

Acid  Yellow  63 

Acid  Yellow  65 

*Acid  Yellow  73 

Acid  Yellow  76 

Acid  Yellow  79 

Acid  Yellow  90 

Acid  Yellow  95 

*Acid  Yellow  99 

Acid  Yellow  113 

Acid  Yellow  114— 

Acid  Yellow  121 

Acid  Yellow  124 

Acid  Yellow  127— ■ 

Acid  Yellow  128 ■ 

Acid  Yellow  129 

Acid  Yellow  151 

Acid  Yellow  152 - ■ 

Acid  Yellow  159 

Other  acid  yellow  dyes 

*Acid  orange  dyes: 

*Acid  Orange  1 

Acid  Orange  2 

Acid  Orange  5 

Acid  Orange  6 

*Acid  Orange  7 

*Acid  Orange  8 

*Aeid  Orange  10 

Acid  Orange  12 

Acid  Orange  19 

*Acid  Orange  24 

Acid  Orange  28 

Acid  Orange  31 

Acid  Orange  34 

Acid  Orange  45 

Acid  Orange  49 

Acid  Orange  50 

Acid  Orange  51 

Acid  Orange  52 

Acid  Orange  56 

*Acid  Orange  60- 


ACY. 

DUP. 

ACY, 

DUP, 

NAC. 

SDH. 

NAC. 

ACY. 

CMG, 

DUP, 

VPC. 

BDO, 

TRC. 

ACY, 

ATL, 

BDO,    BKS,    CMG,    DUP,    G, 

NAC,    PDC,    SDH,    TRC 

VPC. 

AAP, 

ACY, 

G,   MRX,    NAC,    SDH,    TRC, 

VPC. 

G. 

G,    TRC. 

NAC. 

VPC. 

DUP, 

G,    NAC,    TRC. 

NAC. 

ACY, 

DUP, 

G,    NAC,    TRC,    VPC. 

AAP, 

ACY, 

G,   VPC. 

NAC. 

AAP, 

G,    NAC,    VPC. 

ACY, 

BKS, 

CMG,    G,    NAC,    TRC,    VPC. 

VPC. 

NAC. 

AAP, 

NAC. 

TRC. 

G,    NAC,    NYC,    SDH. 

TRC. 

VPC. 

NAC. 

CMG. 

CMG, 

G,    NAC,    TRC,    VPC. 

TRC. 

CMG, 

TRC. 

G. 

BKS, 

DUP, 

NAC. 

TRC. 

TRC. 

TRC. 

ACY, 

BKS. 

ACY. 

TRC. 

ACY, 

ALT, 

CMG,   DUP,    G,    VPC. 

ALT, 

BKS, 

G,    NAC. 

NAC. 

ACY. 

NAC. 

AAP, 

ACY, 

ATL,    BKS,    CPC,    G,    NAC, 

PDC,    TRC,   YAW. 

ACY, 

ATL, 

BKS,    DUP,    G,    NAC,    TRC. 

ACY, 

ATL, 

DUP,    G,    NAC,    TRC,    YAW. 

NAC. 

G. 

ACY, 

DUP, 

G,    NAC,    TRC,    YAW. 

NAC. 

AAP. 

ACY. 

NAC, 

TRC. 

TRC. 

AAP. 

CMG, 

NAC, 

TRC. 

NAC. 

G. 

BKS, 

CMG, 

DUP,   G. 

DYES 


TABLE  8B.  — Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


Dye 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


ACID  DYES- -Continued 

*Acid  orange  dyes — Continued 

Acid  Orange  62 

Acid  Orange  63 

*Acid  Orange  64 

Acid  Orange  69 

Acid  Orange  72 

Acid  Orange  74 

Acid  Orange  76 

Acid  Orange  85 

Acid  Orange  86 

Acid  Orange  114 

Acid  Orange  116 

Acid  Orange  119 

Other  acid  orange  dyes 

*Aeid  red  dyes: 

*Aeid  Red  1 

*Acid  Red  4 

Acid  Red  12 

*Acid  Red  14 

Acid  Red  17 

*Acid  Red  18 

*Aeid  Red  26 

Acid  Red  27 

Acid  Red  29 

Acid  Red  32 

Acid  Red  33 

Acid  Red  34 

Acid  Red  35 

*Acid  Red  37 

Acid  Red  42 

Acid  Red  52 

Acid  Red  57 

Acid  Red  60 

Acid  Red  66 

*Acid  Red  73 

Acid  Red  76 

Acid  Red  80 

*Acid  Red  85 

*Acid  Red  87 

*Acid  Red  88 

*Acid  Red  89 

Acid  Red  94 

Acid  Red  97 

*Acid  Red  99 

Acid  Red  100 

Acid  Red  106 — 

Acid  Red  113 

*Acid  Red  114 

*Acid  Red  115 

Acid  Red  119 

Acid  Red  133— — 

Acid  Red  134 

*Acid  Red  137 

*Acid  Red  151 

Acid  Red  153 

Acid  Red  167 

Acid  Red  172 

Acid  Red  175 

Acid  Red  178 

Acid  Red  179 

*Acid  Red  182 

Acid  Red  183 

Acid  Red  184 

*Acid  Red  186 

Acid  Red  190 

Acid  Red  191 

Acid  Red  194 

Acid  Red  207 


TRC. 

G,  TRC. 

ACY,  DUP,  NAC. 

ACY. 

a. 

CMG,  G,  NAC,  TRC. 

NAC,  TRC. 

NAC. 

NAC,  TRC. 

ACY. 

ATL,  TRC. 

TRC. 

ALT,  G,  VPC. 

AAP,  ACY,  BDO,  BKS,  BL,  DUP,  G,  NAC,  SDH,  TRC,  VPC, 

YAW. 
ATL,  BDO,  CMG,  DUP,  G,  TRC,  VPC,  YAW. 
G,  NAC. 

ATL,  BDO,  DUP,  G,  NAC,  PDC. 
ATL,  NAC,  TRC. 
ACY,  ATL,  BDO,  G,  NAC,  TRC. 
ACY,  ATL,  CPC,  G,  NAC. 
NAC. 
NAC. 
G,  NAC. 
NAC,  YAW. 
NAC. 
AAP,  G. 

CMG,  DUP,  G,  NAC,  TRC. 
G. 
G. 

TRC. 
TRC. 

AAP,  NAC. 

ACY,  DUP,  G,  NAC,  PSC,  TRC. 
NAC. 
G,  ICI. 
ACY,  ALT,  ATL,  BKS,  CMG,  DUP,  G,  NAC,  PDC,  TRC,  VPC, 

YAW. 
AMS,  NYC,  SDH. 

ACY,  ATL,  DUP,  G,  NAC,  SDH,  TRC,  YAW. 
AAP,  G,  TRC,  VPC. 
NYC. 
ATL,  G. 

BKS,  CMG,  NAC,  TRC,  VPC. 
VPC. 
YAW. 
DUP. 

ATL,  DUP,  G. 
G,  NAC,  TRC. 
NAC. 
G. 

TRC. 

ATL,  DUP,  G,  NAC,  TRC. 
AAP,  ACY,  BKS,  TRC,  YAW. 
YAW. 

NAC,  TRC. 
VPC. 
DUP. 
DUP. 

CMG,  TRC. 

ACY,  BKS,  CMG,  DUP,  G,  NAC. 
CMG,  TRC. 
TRC. 

ACY,  BKS,  CMG,  DUP,  G,  TRC,  VPC. 
ACY. 
TRC. 
TRC. 
NAC. 


92 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  8B.  — Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


Dye 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


ACID  DYES— Continued 

*Acid  red  dyes — Continued 

Acid  Red  212 

Acid  Red  213 

Acid  Red  218— 

Acid  Red  273 

Acid  Red  292 

Acid  Red  299 — 

Acid  Red  309 

Other  acid  red  dyes 

*Acid  violet  dyes: 

*Aeid  Violet  1 

*Acid  Violet  3 

Acid  Violet  6 

*Acid  Violet  7 

Acid  Violet  11 

*Acid  Violet  12 

Acid  Violet  13 — 

Acid  Violet  17 - 

Acid  Violet  29 

Acid  Violet  34 

Acid  Violet  41 

Acid  Violet  43 

*Acid  Violet  49 

Acid  Violet  56 

Acid  Violet  76 

Acid  Violet  78 

Other  acid  violet  dyes 

*Acid  blue  dyes: 

Acid  Blue  1 

*Acid  Blue  7 

*Aeid  Blue  9 

Acid  Blue  10 

Acid  Blue  13 

Acid  Blue  15 

Acid  Blue  20 

Acid  Blue  22 

Acid  Blue  23 

*Acid  Blue  25 

Acid  Blue  26 

Acid  Blue  27 

Acid  Blue  29 

Acid  Blue  34 

Acid  Blue  35 

*Acid  Blue  40 

*Acid  Blue  41 

*Acid  Blue  43 

*Acid  Blue  45 

Acid  Blue  47 

Acid  Blue  48 

Acid  Blue  58 

Acid  Blue  59 

*Acid  Blue  62 

Acid  Blue  63 

Acid  Blue  67 

Acid  Blue  69 

Acid  Blue  74 

*Acid  Blue  78 

Acid  Blud  80 

Acid  Blue  81 

Acid  Blue  83 

Acid  Blue  89— - — 

*Acid  Blue  90 

Acid  Blue  92 

Acid  Blue  93 

Acid  Blue  102 

Acid  Blue  104 

*Acid  Blue  113 

*Acid  Blue  118 

Acid  Blue  120 - 


TRC. 

ALT,  ATL,  G,  TRC,  VPC. 

G,  NAC. 

DUP,  NAC,  TRC,  YAW. 

BD0,  CMG,  DUP,  G,  NAC,  TRC,  VPC. 

DUP,  G. 

G,  SDH. 


ICI,  NAC. 
NAC,  TRC. 
G. 


DUP,  TRC. 

NAC,  SDH. 

G,  NAC,  SDH. 
NAC,  SDH,  VPC. 

NAC. 


NAC. 
NYC. 
TRC. 
BD0,  CMG,  DUP,  G,  NAC,  TRC. 


G,  ICI,  NAC. 
CMG,  G,  NAC. 
G,  NAC,  TRC. 
CMG,  DUP,  G,  NAC,  TRC,  VPC. 


G,  VPC. 

NAC. 

NAC. 

G. 

NAC. 

G,  ICI,  NAC,  TRC. 

TRC. 


NAC. 

G,  NAC,  TRC. 

NAC, 

HSC 
NAC 


TRC. 
NAC. 

BKS,  CMG,  DUP,  G. 

G,  NAC. 
NAC. 


DYES 


93 


TABLE  8B.  --Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


Dye 


ACID  DYES— Continued 

*Acid  blue  dyes — Continued 

Acid  Blue  122— -. 

Acid  Blue  137- - 

Acid  Blue  145 

*Acid  Blue  158  and  158A 

Acid  Blue  165 

Acid  Blue  179 

Acid  Blue  203 

Acid  Blue  230 - 

Acid  Blue  231 

Other  acid  blue  dyes 

*Acid  green  dyes: 

Acid  Green  1 

*Acid  Green  3 

Acid  Green  5 

*Aeid  Green  9 

*Aci'l  Green  12 

*Acid  Green  16 

*Acid  Green  20 

Acid  Green  22 

*Acid  Green  25 

Acid  Green  35 

Acid  Green  4-1 

Acid  Green  44 

Acid  Green  50 

Acid  Green  58 

Other  acid  green  dyes 

*Acid  brown  dyes: 

Acid  Brown  1 

Acid  Brown  6 

*Acid  Brown  14 

Acid  Blown  19 

Acid  Brown  22 

Acid  Brown  28 

Acid  Brown  29 

Acid  Brown  31 

Acid  Brown  45 

Acid  Brown  96 

Acid  Brown  97 

Acid  Brown  98 

Acid  Brown  152 

Acid  Brown  158 

Acid  Brown  223 

Acid  Brown  243 

Other  acid  brown  dyes 

*Acid  black  dyes: 

*Acid  Black  1 

Acid  Black  2 

Acid  Black  12 

Acid  Black  16 

Acid  Black  18 

*Acid  Black  24 

Acid  Black  26,  26A,  and  26B 

Acid  Black  29 

Acid  Black  41 

*Acid  Black  48 

Acid  Black  52 

Acid  Black  53 

Acid  Black  58 

Acid  Black  60 

Acid  Black  92 

*Acid  Black  107 

Acid  Black  138 — *• 

Other  acid  black  dyes 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


DUP. 

NAC. 

DUP. 

ACY,    BKS, 

G,    NAC, 

TRC,    VPC. 

DUP. 

G. 

VPC. 

DUP,    THC. 

TRC. 

ACY,   ALT, 

CMG,    DUP,    TRC,    VPC. 

ACY,    NAC. 

ACY,    DUP, 

G,    NAC, 

TRC. 

G,    NAC. 

ACY,    DUP, 

G,    NAC, 

VPC. 

G,    NAC,    TRC. 

DUP,    G,    NAC,    SDH, 

TRC. 

ATL,    CMG, 

DUP,    G, 

NAC,    TRC. 

G,    NAC. 

ATL,    CMG, 

G,   HSH, 

ICI,    NAC,    TRC,    VPC 

THC. 

ICI,    VPC. 

VPC. 

ACY,    G. 

TRC. 

ALT,    TRC, 

VPC. 

G. 

G. 

AAP,   ACY, 

DUP,    G, 

NAC,    TRC,    YAW. 

TRC. 

DUP. 

TRC. 

DUP,    NAC. 

G. 

NAC,    TRC. 

ACY. 

ACY. 

ACY,    TRC. 

G. 

G. 

G. 

G. 

ALT,    DUP, 

G,    VPC. 

AAP,  ACY,  ATL,  BDO,  BKS,  DUP,  FAB,  G,  NAC,  PDC,  TRC 
YAW.  ' 

ACY,  NAC. 
NAC. 
NAC. 
NAC. 

CMG,  DUP,  G,  NAC. 
DUP,  NAC,  TRC. 
G,  NAC. 
NAC. 

ACY,  CMG,  DUP,  G,  ICI,  NAC,  TRC. 
G,  NAC,  TRC. 
NAC. 

NAC,  TRC. 
CMG,  TRC. 
ACY. 

G,  NAC,  TRC. 
VPC. 
ALT,  DUP,  PDC. 


94 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


-Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


AZOIC  DYES  AND  COMPONENTS 


Azoic  yellow  dyes: 
*Azoic  Yellow  1 

Azoic  Yellow  2 

*Azoic  Yellow  3 

Other  azoic  yellow  dyes 

Azoic  orange  dyes: 

*Azoic  Orange  3 

Azoic  Orange  4 

Other  azoic  orange  dyes 

* Azoic  red  dyes: 

*Azoic  Red  1 

*Azoie  Eed  2 

*Azoic  Bed  6 

Azoic  Red  13 

Azoic  Red  14 

Azoic  Red  15 

•*Azoic  Red  16 

Azoic  Red  73 

Azoic  Red  74 

Other  azoic  red  dyes 

Azoic  violet  dyes: 

Azoic  Violet  1 

Other  azoic  violet  dyes 

Azoic  blue  dyes: 

*Azoic  Blue  2 

*Azoic  Blue  3 

Azoic  Blue  4 

Azoic  Blue  6 

Azoic  Blue  7 

Other  azoic  blue  dyes 

Azoic  green  dyes: 

Azoic  Green  1 

Other  azoic  green  dyes 

Azoic  brown  dyes: 

*Azoic  Brown  9 

Azoic  Brown  10 

Azoic  Brown  26 

Other  azoic  brown  dyes 

* Azoic  black  dyes: 

Azoic  Black  1 

Azoic  Black  2 

Azoic  Black  3 

Azoic  Black  4 

Azoic  Black  15 

Other  azoic  black  dyes 

Other  azoic  compositions 

Azoic  Diazo   Compo 
(Fast   Color 


Azoic 

Azoic 

Azoic 

♦Azoic 

Azoic 

Azoic 

*Azoic 

*Azoic 

*Azoic 

*Azoic 

Azoic 

Azoic 

Azoic 

Azoic 

*Azoic 

Azoic 

Azoic 

Azoic 


Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 


Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 
Component 


1,  base — 

2,  base — 

3,  base — 

4,  base — 

5,  base — 

8,  base — 

9,  base — 

10,  base- 

12,  base- 

13,  base- 

14,  base- 
20,  base- 
24,  base- 
28,  base- 
32,  base- 
34,  base- 
41,  base- 
46,  base- 


ALL,  ATL,  BUC,  G. 

BUC,  G,  HST,  X. 

ATL,  G,  HST. 
BUC. 

ALL,  ATL,  BUC,  G,  x. 


VPC. 

ALL, 

ATL, 
ALL, 
G. 


ATL,  BUC,  G,  HST,  x. 

BUC,  G,  x. 

ATL,  BUC,  G,  HST,  NAC,  VPC,  x. 


ATL,  BUC,  G. 


ATL,  BUC,  G. 
ATL,  G,  x. 


ATL,  BUC,  G. 

ALL,  ATL,  BUC,  G,  HST,  x. 


ATL,  G. 
G. 


ATL,    G. 

VPC. 

ATL,    BUC, 

Qt 

HST,    VPC 

ATL,    BUC. 

BUC,    G. 

ATL,    BUC, 

G> 

VPC. 

G,    HST. 

ATL. 

ATL. 

ALL,   ATL, 

G. 

G,    NAC. 

ALL,   ATL, 

Gj 

VPC. 

SDH. 
ATL. 
KLS. 

ALL,  G,  KLS,  SDH. 
G,  SDH. 
DUP. 

AAP,  DUP,  VPC. 
ALL,  AUG,  BUC,  G,  KLS. 
AUG,  KLS,  SDH. 
ALL,  AUG,  BUC,  KLS. 
AAP. 
ALL,  G. 
KLS. 

ALL,  BUC,  KLS. 

AAP,  ATL,  BUC,  DUP,  KLS,  SDH. 
G. 
G. 
I  ATL. 


DYES 


95 


TABLE  8B.  —Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1 965-  -Continued 


Dye 


AZOIC  DYES  AND  COMPONENTS- -Continued 


Azoic  Diazo  Components,    Bases 
(Fast  Color  Bases)— Continued 


*Azoic  Diazo  Component  48,  base- 
Azoic  Diazo  Component  49,  base- 


Diazo   Components 
(Fast  Color  Salt 


*Azoic 

* Azoic 

*Azoic 

Azoic 

*Azoic 

*Azoic 

*Azoic 

*Azoic 

*Azoic 

*Azoic 

*Azoie 

*Azoic 

Azoic 

Azoic 

Azoic 

*Azoic 

Azoic 

Azoic 

Azoic 

Azoic 

Azoic 

Azoic 

Azoic 

Azoic 

*Azoic 

*Azoic 

Azoic 

Other 


Azoic 

*Azoic 

*Azoic 

*Azoic 

*Azoie 

*Azoic 

* Azoic 

Azoic 

*Azoic 

Azoic 

Azoic 

*Azoic 

Azoic 

Azoic 

*Azoic 

*Azoic 

*Azoic 

*Azolc 

*Azoic 

Azoic 

Azoic 

*Azoic 

Azoic 

Azoic 

Azoic 

Azoic 

Other 


Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
azoic 


Component  1,  salt 

Component  2,  salt 

Component  3,  salt 

Component  4,  salt 

Component  5,  salt 

Component  6,  salt 

Component  8,  salt 

Component  9,  salt 

Component  10,  salt 

Component  11,  salt 

Component  12,  salt 

Component  13,  salt 

Component  14,  salt 

Component  20,  salt 

Component  24,  salt 

Component  28,  salt 

Component  32,  salt 

Component  34,  salt 

Component  35,  salt 

Component  36,  salt 

Component  37,  salt 

Component  41,  salt 

Component  42,  salt 

Component  44,  salt 

Component  48,  salt 

Component  49,  salt 

Component  51,  salt 

diazo  components,  salts- 


Azoic  Coupling  Components 
(Naphthol  AS  and  Derivatives) 

Coupling  Component  1 

Coupling  Component  2 

Coupling  Component  3 

Coupling  Component  4 

Coupling  Component  5 

Coupling  Component  7 

Coupling  Component  8 

Coupling  Component  10 

Coupling  Component  11 

Coupling  Component  12 

Coupling  Component  13 

Coupling  Component  14 

Coupling  Component  15 

Coupling  Component  16 

Coupling  Component  17 

Coupling  Component  18 

Coupling  Component  19 

Coupling  Component  20 

Coupling  Component  21 

Coupling  Component  23 

Coupling  Component  24 

Coupling  Component  29 

Coupling  Component  34 

Coupling  Component  35 

Coupling  Component  36 

Coupling  Component  43 

azoic  coupling  components 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


ALL,  OWN,  DUP,  G. 
KLS. 


AAP,  ALL,  G,  SDH. 

AUG,  BUC,  G,  KLS. 

AAP,  ALL,  AUG,  BUC,  G,  KLS,  SDH,  VPC. 

ALL. 

AAP,  ALL,  AUG,  BUC,  G,  KLS,  SDH,  VPC. 

AAP,  BUC,  G,  KLS,  SDH. 

AAP,  ALL,  AUG,  BUC,  G,  KLS. 

AAP,  ALL,  AUG,  BUC,  G,  KLS,  SDH,  VPC. 

AAP,  ALL,  BUC,  G,  KLS,  SDH. 

AAP,  ALL,  G,  KLS. 

AAP,  ALL,  BUC,  G,  KLS,  SDH. 

AAP,  ALL,  AUG,  BUC,  G,  KLS,  SDH,  VPC. 

AAP. 

ALL,  G. 

BUC. 

ALL,  AUG,  BUC,  G,  KLS,  SDH,  VPC. 

ALL,  BUC,  SDH. 

G. 

G. 

AAP,  G. 

G. 

G. 

ALL,  G,  KLS. 

G,  SDH. 

AAP,  ALL,  G,  NAC,  SDH. 

AAP,  BUC,  G,  KLS. 

BUC. 


AUG. 

AAP,  ACY,  ATL,  BUC,  DUP,  G,  PCW. 

AUG,  BUC,  G,  PCW. 

ATL,  AUG,  BUC,  G,  PCW. 

AAP,  G,  PCW,  SDH. 

AAP,  AUG,  BUC,  G,  PCW. 

ATL,  G,  PCW. 

PCW,  SDH. 

BUC,  G,  PCW. 

BUC,  G,  PCW. 

G. 

ATL,  BUC,  G,  NAC,  PCW. 


ACY,  ATL,  BUC,  PCW. 

ACY,  ATL,  BUC,  DUP,  G,  PCW. 

BUC,  G,  PCW. 

ATL,  BUC,  DUP,  G,  PCW. 

ATL,  AUG,  BUC,  G,  PCW. 

G,  PCW. 

G,  PCW. 

ATL,  AUG,  BUC,  G,  PCW. 

BUC,  G,  PCW. 

ALL,  G,  PCW. 

G. 

ATL,  G. 

ATL,  G,  VPC. 


96 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  8B.  — Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


Dye 


Manufacturers1  identification  codes 
(according  to  list  in  table  22) 


BASIC  DYES 

*Basic  yellow  dyes: 

Basic  Yellow  1 

*Basic  Yellow  2 

Basic  Yellow  5 

*Basic  Yellow  11 

*Basic  Yellow  13 

Basic  Yellow  15 

Basic  Yellow  16 

Basic  Yellow  26 

Basic  Yellow  27 

Basic  Yellow  28 

Basic  Yellow  37 

Other  Basic  yellow  dyes 

*Basic  orange  dyes: 

*Basic  Orange  1 

*Basic  Orange  2 

Basic  Orange  10 

Basic  Orange  14 

Basic  Orange  17 

*Basic  Orange  21 

Basic  Orange  22 

Basic  Orange  24 

Basic  Orange  25 

Basic  Orange  26 

Basic  Orange  31 

Other  basic  orange  dyes 

*Basic  red  dyes: 

Basic  Red  1 

Basic  Red  2 

Basic  Red  9 

Basic  Red  12 

Basic  Red  13 

*Basie  Red  14 

Basic  Red  15 

Basic  Red  16 

Basic  Red  17 

Basic  Red  18 

Basic  Red  19 

Basic  Red  20 

Basic  Red  22 

Basic  Red  30 

Other  basic  red  dyes 

*Basic  violet  dyes: 

*Basic  Violet  1 

Basic  Violet  2 

*Basic  Violet  3 

*Basie  Violet  4 

Basic  Violet  7 

Basic  Violet  10 

Basic  Violet  13 

Basic  Violet  14 

Basic  Violet  15 

*Basic  Violet  16 

Basic  Violet  18 

Other  basic  violet  dyes 

*Basic  blue  dyes: 

*Basic  Blue  1 

Basic  Blue  2 

Basic  Blue  3 

Basic  Blue  4 

*Basic  Blue  5 

Basic  Blue  6 

*Basie  Blue  7 

*Basic  Blue  9 

Basic  Blue  11 

Basic  Blue  21 

Basic  Blue  22 

*Basic  Blue  26 

Basic  Blue  27 


DUP. 

ACY,  DUP,  NAC. 

NAC. 

DUP,  G,  NAC,  VPC. 

DUP,  G,  NAC,  VPC. 

DUP. 

DUP. 

ACY. 

ACY. 

VPC. 

ACY. 

G,  DUP. 

ACY,  DUP,  G,  NAC. 

ACY,  DSC,  DUP,  G,  NAC,  PDC,  PSC,  TRC. 

VPC. 

G. 

NAC. 

DUP,  G,  NAC,  VPC. 

G,  NAC. 

DUP. 

DUP. 

DUP. 

ACY. 

VPC. 


DUP, 

G. 

DUP, 

NAC. 

DSC, 

HSC. 

DUP. 

G,    NAC. 

ACY, 

DUP, 

G, 

NAC,    VPC. 

DUP, 

G. 

DUP. 

DUP. 

DUP, 

VPC. 

DUP. 

DUP. 

ACY, 

TRC. 

ACY. 

DUP. 

ACY, 

DSC, 

HSC,    NAC. 

DSC, 

NYC. 

DSC, 

DUP, 

G, 

NAC,    SDH. 

DSC, 

DUP, 

G, 

NAC. 

G,    NAC. 

ACY, 

DUP, 

G. 

DSC. 

ACY, 

DSC. 

DUP. 

DUP, 

G,   VPC. 

ACY. 

DUP. 

DSC, 

G,    NAC, 

SDH,    VPC. 

DSC. 

G. 

DUP. 

DSC, 

SDH, 

VPC. 

ACY, 

NAC. 

DSC, 

DUP, 

Gi 

SDH. 

ACY, 

G,    NAC, 

SDH. 

DSC, 

DUP, 

SDH. 

DUP. 

DUP, 

NAC. 

DSC, 

DUP, 

G, 

SDH. 

G. 

DYES 


97 


TABLE  8B  —Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


Dye 


BASIC  DYES- -Continued 

♦Basic  blue  dyes—Continued 

Basic  Blue  35 

Basic  Blue  36 

Basic  Blue  38 

Basic  Blue  39 

Basic  Blue  4-1 

Basic  Blue  54 

Other  basic  blue  dyes 

Basic  green  dyes: 

♦Basic  Green  1 

Basic  Green  3 

♦Basic  Green  4 

Basic  Green  5 

Basic  brown  dyes: 

♦Basic  Brown  1 — • 

Basic  Brown  2 

*Basic  Brown  4 

Basic  black  dyes: 

Basic  Black  3 

Other  basic  black  dyes 

DIRECT  DYES 

♦Direct  yellow  dyes: 

*Direct  Yellow  4 

*Direct  Yellow  5 

*Direct  Yellow  6 

Direct  Yellow  7 

Direct  Yellow  8 

Direct  Yellow  9 

*Direct  Yellow  11 

*Direet  Yellow  12 

Direct  Yellow  20 

Direct  Yellow  23 

♦Direct  Yellow  26 

Direct  Yellow  27 

*Direct  Yellow  28 

Direct  Yellow  29 

Direct  Yellow  39 

*Direct  Yellow  44 

*Direct  Yellow  50 

♦Direct  Yellow  59 

Direct  Yellow  62 

Direct  Yellow  63 

♦Direct  Yellow  84 

Direct  Yellow  103 

♦Direct  Yellow  105 

♦Direct  Yellow  106 

Direct  Yellow  107 

Direct  Yellow  114 

Direct  Yellow  117 

Direct  Yellow  118 

Direct  Yellow  121 

Direct  Yellow  125 

Other  direct  yellow  dyes 

♦Direct  orange  dyes: 

♦Direct  Orange  1 

Direct  Orange  6 

♦Direct  Orange  8 

Direct  Orange  10 

Direct  Orange  11 

♦Direct  Orange  15 

♦Direct  Orange  26 

Direct  Orange  29 

♦Direct  Orange  34 

♦Direct  Orange  37 

Direct  Orange  38 

♦Direct  Orange  39 

Direct  Orange  40 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


DUP. 

DUP. 

ACY,    DUP. 

DUP. 

TRC. 

ACY. 

ACY,    DUP, 

G. 

ACY,   DSC, 

DUP,    NAC,    SDH. 

DUP. 

ACY,    DSC, 

DUP,    NAC,    SDH. 

ACY. 

ACY,   DUP, 

G,    NAC,    TRC. 

G,    NAC. 

ACY,    DSC, 

DUP,    G,    NAC,    TRC 

DSC,  DUP. 


ACY,  DUP,  G,  NAC,  TRC. 

ACY,  G,  NAC. 

ACY,  DUP,  G,  NAC,  TRC. 

ATL. 

G,  NAC. 

DUP. 

ACY,  DUP,  G,  NAC,  TRC. 

BKS,  DUP,  G,  NAC,  TRC. 

TRC. 

DUP. 

BKS,  BL,  DUP. 

G. 

ATL,  DUP,  G,  NAC,  TRC. 

DUP,  G. 

TRC. 

ALT,  ATL,  BKS,  BL,  DUP,  G,  NAC,  TRC,  VPC. 

ATL,  BKS,  BL,  DUP,  FAB,  G,  NAC,  TRC,  VPC. 

ATL,  DUP,  NAC. 

NAC. 

DUP. 

BKS,  G,  NAC,  TRC. 

NAC. 

ALT,  BKS,  TRC. 

ALT,  BKS,  G,  TRC. 

G. 

ACY. 

TRC. 

ACY,  TRC. 

TRC. 

ACY. 

AAP,  ALT,  ATL,  BL,  DUP,  FAB,  VPC. 

AAP,  BDO,  CMG,  NAC,  VPC. 

NAC. 

ATL,  DUP,  G,  NAC,  TRC. 

AAP,  NAC. 

G. 

ACY,  DUP,  G,  NAC,  TRC. 

ATL,  BL,  DUP,  G,  NAC,  TRC. 

ATL,  BKS,  TRC. 

ACY,  CMG,  DUP,  G,  NAC. 

ACY,  CMG,  DUP,  G,  TRC. 

NAC. 

ATL,  BKS,  CMG,  DUP,  G. 

DUP. 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  8B.  ■ 


-Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


Dye 


DIRECT  DYES--Continued 

*Direct  orange  dyes — Continued 

Direct  Orange  48 

Direct  Orange  55 

Direct  Orange  59 

Direct  Orange  61 

Direct  Orange  67 

Direct  Orange  70 

^Direct  Orange  72 

*Direct  Orange  73 

Direct  Orange  74 

Direct  Orange  76 

Direct  Orange  78 

Direct  Orange  79 

Direct  Orange  80 

*Direct  Orange  81 

Direct  Orange  83 

Direct  Orange  88 

*Direct  Orange  102 

Direct  Orange  110 

Other  direct  orange  dyes 

*Direct  red  dyes: 

*Direct  Red  1 

-"-Direct  Red  2 

*Direct  Red  4 

Direct  Red  5 

*Direct  Red  10 

*Direct  Red  13 

*Direet  Red  16 

Direct  Red  20 

*Direct  Red  23 

^Direct  Red  24 

*Direct  Red  26 

*Direct  Red  28 

Direct  Red  30 

*Direct  Red  31 

Direct  Red  32 

*Direct  Red  37 

*Direct  Red  39 

Direct  Red  46 

Direct  Red  53 

Direct  Red  62 

Direct  Red  72 

Direct  Red  73 — 

*Direet  Red  75 

Direct  Red  76 

*Direct  Red  79 

*Direct  Red  80 

*Direct  Red  81 

*Direet  Red  83 

Direct  Red  84 

Direct  Red  94 

Direct  Red  95 

Direct  Red  100 

Direct  Red  111 

Direct  Red  117 

Direct  Red  120 

^Direct  Red  122 

Direct  Red  123 — 

*Direct  Red  127  and  127A 

Direct  Red  139 

Direct  Red  148 

*Direct  Red  149 

Direct  Red  152 

*Direct  Red  153 

Direct  Red  155 

Direct  Red  209 

Other  direct  red  dyes 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


DUP. 

DUP,  NAC. 

DUP,  G. 

TRC. 

NAC,  VPC. 

TRC. 

ATL,  BKS,  BL,  FAB,  NAC,  TRC,  VPC. 

DUP,  G,  TRC,  VPC. 

DUP. 

DUP. 

DUP,  VPC. 

DUP. 

DUP,  VPC. 

DUP,  G,  NAC,  VPC. 

G,  NAC. 

DUP. 

ACT,  DUP,  G,  NAC. 

TRC. 

ALT,  ATL,  BL,  DUP,  G,  VPC. 

AAP,  ATL,  DUP,  G,  NAC,  TRC,  IAW. 

ATL,  BKS,  DUP,  NAC,  TRC. 

NAC,  TRC,  VPC. 

NAC. 

AAP,  ACY,  ATL,  NAC. 

AAP,  ATL,  DUP,  G,  NAC,  TRC,  YAW. 

AAP,  ATL,  DUP,  G,  NAC,  TRC. 

G,  NAC. 

ATL,  BKS,  DUP,  FAB,  G,  NAC,  TRC. 

AAP,  ATL,  BKS,  BL,  FAB,  NAC,  TRC,  VPC. 

AAP,  ATL,  BKS,  DUP,  G,  NAC,  TRC,  VPC. 

ATL,  DUP,  NAC,  TRC. 

VPC. 

ATL,  DUP,  G,  NAC,  TRC. 

DUP,  NAC. 

ACY,  ATL,  G,  NAC,  TRC,  YAW. 

ATL,  G,  NAC,  TRC,  YAW. 

ATL,  TRC. 

NAC. 

TRC. 

G,  TRC. 

DUP,  NAC. 

ACY,  CMG,  DUP,  G,  NAC,  VPC. 

G,  NAC. 

ATL,  BKS,  CMG,  TRC,  VPC. 

AAP,  ATL,  BDO,  BKS,  BL,  CMG,  DUP,  FAB,  G,  NAC,  TRC, 

VPC. 
AAP,  ACY,  ATL,  BDO,  BKS,  BL,  CMG,  DUP,  G,  NAC,  TRC, 

VPC,  YAW. 
ALT,  ATL,  BKS,  BL,  CMG,  DUP,  FAB,  G,  NAC,  TRC. 
G,  NAC. 
NAC. 
VPC. 
NAC. 
G,  VPC. 
BL,  DUP. 
VPC. 
CMG,  NAC,  TRC,  VPC. 


DUP, 

NAC, 

TRC. 

VPC. 

DUP. 

ATL, 

CMG, 

DUP,    G, 

NAC 

CMG, 

DUP, 

NAC. 

ATL, 

CMG, 

NAC. 

G. 

TRC. 

ALT, 

BL. 

DYES 


99 


TABLE  8B.  —Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


Dye 


DIRECT  DYES- -Continued 

*Direct  violet  dyes: 

♦Direct  Violet  1 

Direct  Violet  7 

♦Direct  Violet  9 

Direct  Violet  14 

Direct  Violet  22 

Direct  Violet  30 

Direct  Violet  47 

Direct  Violet  48 

Direct  Violet  49 

♦Direct  Violet  51 

Direct  Violet  60 

Direct  Violet  62 

Direct  Violet  66 

Direct  Violet  67 

Direct  Violet  68 — 

Other  direct  violet  dyes 

*Direct  blue  dyes: 

*Direct  Blue  1 

*Direct  Blue  2 

Direct  Blue  3 

♦Direct  Blue  6 

♦Direct  Blue  8 

Direct  Blue  10 

*Direct  Blue  14- 

♦Direct  Blue  15 

Direct  Blue  21 - 

♦Direct  Blue  22 

♦Direct  Blue  24 

♦Direct  Blue  25 

Direct  Blue  26 

Direct  Blue  27 

Direct  Blue  55 

Direct  Blue  67 

♦Direct  Blue  71 

Direct  Blue  74 

Direct  Blue  75 

♦Direct  Blue  76 

♦Direct  Blue  78 

Direct  Blue  79 

♦Direct  Blue  80 

Direct  Blue  84 

♦Direct  Blue  86 

Direct  Blue  87 

Direct  Blue  91 

♦Direct  Blue  98— 

Direct  Blue  100 

Direct  Blue  104 

♦Direct  Blue  120  and  120A 

♦Direct  Blue  126 

Direct  Blue  130 

Direct  Blue  133 

Direct  Blue  136 

Direct  Blue  1A3 

♦Direct  Blue  151 

Direct  Blue  160 

Direct  Blue  189 

Direct  Blue  191 

Direct  Blue  199 

Direct  Blue  218 

Direct  Blue  238 

Other  direct  blue  dyes 

♦Direct  green  dyes: 

♦Direct  Green  1 

♦Direct  Green  6 

♦Direct  Green  8 

♦Direct  Green  12 — ■ 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


AAP,  ATL,  DUP,  NAC. 

G,  NAC. 

ATL,  BKS,  DUP,  G,  NAC,  TRC. 

ATL,  NAC. 

DUP. 

AAP. 

DUP,  G. 

DUP,  NAC. 

NAC. 

ATL,  DUP,  NAC. 

NAC. 

ACY. 

ATL,  TRC. 

DUP,  NAC. 

DUP. 

ALT. 

AAP,  ACY,  ATL,  BKS,  BL,  DUP,  FAB,  G,  NAC,  TRC,  VPC, 

YAW. 
AAP,  ATL,  BKS,  BL,  DUP,  FAB,  G,  NAC,  TRC,  VPC,  YAW. 
NAC. 

AAP,  ACY,  ATL,  BKS,  BL,  DUP,  G,  NAC,  TRC,  YAW. 
ATL,  BKS,  DUP,  G,  NAC,  TRC,  YAW. 
DUP. 

ATL,  DUP,  NAC,  TRC. 
ATL,  DUP,  G,  NAC,  YAW. 
TRC. 

ATL,  CMG,  DUP,  NAC. 
ATL,  BKS,  NAC,  TRC,  YAW. 
DUP,  G,  NAC,  TRC,  YAW. 
ATL,  NAC. 
DUP. 
NAC. 

ATL,  DUP,  NAC,  TRC. 
ATL,  DUP,  G,  NAC,  TRC. 
DUP. 

TRC. 

ALT,  ATL,  BKS,  BL,  DUP,  G,  NAC,  TRC,  VPC. 

ATL,  CMG,  DUP,  G,  NAC,  TRC. 

TRC. 

ALT,  ATL,  BKS,  BL,  DUP,  FAB,  G,  NAC,  TRC. 

DUP. 

AAP,  ACY,  ATL,  BKS,  DUP,  FAB,  G,  ICC,  ICI,  NAC,  SDH, 
TMS,  TRC,  VPC. 

ICI. 

TRC. 

ALT,  ATL,  G,  TRC,  VPC. 

ALT,  NAC. 

DUP. 

ATL,  BKS,  CMG,  DUP,  G,  NAC,  TRC. 

BL,  DUP,  G,  NAC,  TRC,  VPC. 

NAC. 

G. 

G. 

DUP. 

ATL,  NAC,  TRC. 

TRC. 

TRC. 

G. 

G. 

BKS. 

ACY. 

AAP,  ACY,  ALT,  ATL,  BL,  DUP,  FAB,  G,  NAC,  VPC,  YAW. 

AAP,  ACY,  ATL,  BKS,  DUP,  G,  NAC,  TRC,  YAW. 

AAP,  ATL,  BKS,  BL,  DUP,  FAB,  G,  NAC,  TRC,  YAW. 

ATL,  NAC,  TRC. 

DUP,  NAC,  TRC. 


100 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  8B.  —Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1 965— Continued 


Dye 


DIRECT  DYES— Continued 


*Direet  green  dyes — Continued 

Direct  Green  14 

Direct  Green  15 

Direct  Green  26 

Direct  Green  27 

Direct  Green  28 

^Direct  Green  38 

Direct  Green  39 

Direct  Green  41 

Direct  Green  45 

Direct  Green  47 

Direct  Green  51 

Direct  Green  69 

Other  direct  green  dyes 

*Direct  brown  dyes: 

^Direct  Brown  1 

*Direet  Brown  1A 

*Direct  Brown  2 

*Direct  Brown  6 

Direct  Brown  11 

Direct  Brown  25 

Direct  Brown  27 

Direct  Brown  29 

*Direct  Brown  31 

Direct  Brown  32 

Direct  Brown  33 

Direct  Brown  35 

Direct  Brown  40 

Direct  Brown  44- 

Direct  Brown  48 

Direct  Brown  59 

*Direct  Brown  74 

*Direet  Brown  95 

Direct  Brown  101 

Direct  Brown  105 

Direct  Brown  106 

*Direct  Brown  111 

Direct  Brown  112 

Direct  Brown  125 

*Direct  Brown  154 

Other  direct  brown  dyes 

*Direct  black  dyes: 

Direct  Black  3 

*Direct  Black  4 

Direct  Black  8 

^Direct  Black  9 

Direct  Black  17 

*Direct  Black  19 

*Direct  Black  22 

Direct  Black  29 

Direct  Black  36 

Direct  Black  37 

*Direct  Black  38 

Direct  Black  44 

*Direct  Black  51 

Direct  Black  55 

Direct  Black  56 

Direct  Black  67 

Direct  Black  71 

Direct  Black  74 

Direct  Black  75 

Direct  Black  78 

*Direct  Black  80 

Direct  Black  109 

Direct  Black  123 

Direct  Black  130 

Direct  Black  190 

Other  direct  black  dyes 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


MAC. 

DUP. 

TRC. 

NAC,  TRC. 

TRC. 

DUP,  G,  NAC. 

G. 

DUP. 

VPC. 

DUP,  G. 

TRC. 

TRC. 

ACY,  ALT,  ATL,  BL,  DUP. 

ACY,  ATL,  BKS,  BL,  DUP,  FAB,  NAC. 

G,  TRC,  YAW. 

AAP,  ACY,  ATL,  BKS,  BL,  DUP,  G,  NAC,  TRC,  YAW. 

DUP,  G,  NAC,  TRC. 

NAC. 

DUP,  NAC. 

G. 

NAC. 

AAP,  ATL,  DUP,  G,  NAC,  YAW. 

G. 

DUP,  NAC. 

NAC. 
AAP,  DUP. 

G,  YAW. 

AAP. 

ACY. 

AAP,  DUP,  NAC. 

AAP,  ALT,  ATL,  BKS,  BL,  DUP,  FAB,  G,  NAC,  TRC,  YAW. 

G. 

DUP. 

G,  NAC. 

DUP,  G,  TRC,  VPC. 

ATL,  NAC. 

G. 

DUP,  G,  NAC,  TRC,  YAW. 

ALT,  ATL,  BL,  NAC,  TRC,  VPC,  YAW. 

DUP. 

ATL,  BKS,  DUP,  G,  NAC,  TRC,  YAW. 

TRC,  YAW. 

BKS,  DUP,  G,  NAC,  TRC. 

G. 

ATL,  BKS,  G,  NAC,  TRC,  VPC. 

AAP,  ALT,  ATL,  BKS,  CMG,  DUP,  G,  NAC,  TRC,  VPC,  YAW. 

ATL. 

AAP. 

AAP,  DUP. 

AAP,  ACY,  ATL,  BKS,  BL,  DUP,  FAB,  G,  NAC,  TRC,  YAW. 

TRC. 

AAP,  ATL,  DUP,  G,  NAC,  TRC. 

DUP. 

NAC,  TRC. 

DUP,  NAC,  VPC. 

ATL,  BKS,  VPC. 

NAC. 

G. 

BKS,  NAC. 

AAP,  ATL,  BKS,  BL,  FAB,  G,  NAC,  TRC,  VPC,  YAW. 

G. 

NAC. 

ACY. 

BKS. 

ACY,  ALT,  ATL,  BL,  TRC,  YAW. 


DYES 


101 


TABLE  8B.— Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


Dye 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


DISPERSE  DYES 

•Disperse  yellow  dyes: 

Disperse  Yellow  1 

Disperse  Yellow  2 

•Disperse  Yellow  3 

•Disperse  Yellow  5 

Disperse  Yellow  8 

Disperse  Yellow  17 

•Disperse  Yellow  23 

Disperse  Yellow  31 

Disperse  Yellow  32 

•Disperse  Yellow  33 

•Disperse  Yellow  34 

Disperse  Yellow  37 

•Disperse  Yellow  42 

Disperse  Yellow  50 

•Disperse  Yellow  54 

Disperse  Yellow  67 

Other  disperse  yellow  dyes 

•Disperse  orange  dyes: 

•Disperse  Orange  3 

•Disperse  Orange  5 

Disperse  Orange  16 

•Disperse  Orange  17 

Disperse  Orange  21 

Disperse  Orange  25 

Disperse  Orange  26 

Disperse  Orange  29 

Disperse  Orange  30 

Disperse  Orange  38 

Disperse  Orange  44 

Other  disperse  orange  dyes 

•Disperse  red  dyes: 

•Disperse  Red  1 

Disperse  Red  4 

•Disperse  Red  5 

Disperse  Red  9 

•Disperse  Red  11 

•Disperse  Red  13 

Disperse  Red  15 

•Disperse  Red  17 

Disperse  Red  20 

Disperse  Red  21 

Disperse  Red  30 

Disperse  Red  31 

Disperse  Red  32 

Disperse  Red  55 

Disperse  Red  56 

Disperse  Red  59— 

•Disperse  Red  60 

Disperse  Red  61 

Disperse  Red  65 

Disperse  Red  66 

Disperse  Red  73 

Disperse  Red  78 

Disperse  Red  96 

Other  disperse  red  dyes 

Disperse  violet  dyes: 
■  *Disperse  Violet  1 

•Disperse  Violet  4 

Disperse  Violet  8 

Disperse  Violet  11 

Disperse  Violet  14 

Disperse  Violet  18 

Disperse  Violet  22 

Disperse  Violet  26 

•Disperse  Violet  27 

Other  disperse  violet  dyes 

•Disperse  blue  dyes: 

•Disperse  Blue  1 

•Disperse  Blue  3 


BKS,  BL,  DUP,  EKT,  G,  HSH,  ICC,  NAC,  SDH,  TRC. 

EKT,  G,  ICC. 

TRC. 


EKT,  ICC,  NAC,  TRC. 

EKT,  ICC,  G. 
ICC. 

DUP.  TRC. 


DUP,  G,  ICC,  TRC. 
EKT,  G,  ICC. 


BKS,  BL,  DUP,  EKT,  G,  HSH,  ICC,  NAC,  TRC. 
EKT,  G. 


BKS,  EKT,  G,  HSH,  ICC,  NAC. 

TRC. 


EKT,  G,  ICC. 

BKS,  BL,  DUP,  EKT,  G,  HSH,  ICC,  NAC,  TRC,  YAW. 
TRC. 

BKS,  EKT,  G,  HSH,  ICC. 

DUP,  G,  TRC. 
G,  ICC. 
HSH,  ICC,  NAC. 

BKS,  DUP,  EKT,  G,  HSH,  ICC,  TRC. 


DUP,  VPC. 
TRC. 


DUP,  EKT,  G,  ICC,  VPC. 


BKS,  G,  HSH,  ICC,  TRC. 
G,  ICC. 


ACY,  BL,  DUP. 
G,  ICC. 


G,  TRC. 

BKS,  EKT,  G,  HSH,  ICC,  TRC. 


102 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  8B. Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 — Continued 


Dye 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


DISPERSE  DYES — Continued 

^Disperse  blue  dyes — Continued 

■^Disperse  Blue  7 

Disperse  Blue  9 

Disperse  Blue  27 

Disperse  Blue  35 

Disperse  Blue  51 

Disperse  Blue  55 

Disperse  Blue  59 

Disperse  Blue  60 

Disperse  Blue  61 

Disperse  Blue  62 

Disperse  Blue  63 

^Disperse  Blue  64- 

Disperse  Blue  70 

Disperse  Blue  71 

Disperse  Blue  73 

Disperse  Blue  79 

Other  disperse  blue  dyes 

Disperse  brown  dyes: 

Disperse  Brown  2 

Other  disperse  brown  dyes 

^Disperse  black  dyes: 

^Disperse  Black  1 

Disperse  Black  2 

Disperse  Black  6 

Disperse  Black  7 

^Disperse  Black  9 

Other  disperse  black  dyes 

FIBER-REACTIVE  DYES 

*Reactive  yellow  dyes: 

Reactive  Yellow  1 

Reactive  Yellow  2 

Reactive  Yellow  3 

Reactive  Yellow  4 

Reactive  Yellow  6 

Reactive  Yellow  7 

Reactive  Yellow  11 

Reactive  Yellow  13 <- 

Reactive  Yellow  14 

Reactive  Yellow  15 

Reactive  Yellow  16 

Reactive  Yellow  17 

Reactive  Yellow  18 — 
Reactive  Yellow  22- 
Reactive  Yellow  24- 

Other  reactive  yellow  dyes 

Reactive  orange  dyeer 
Reactive  Orange  1- 

Reactive  Orange  2 

Reactive  Orange  4 

Reactive  Orange  5- 
Reactive  Orange  7- 
Reactive  Orange  12- 

Reactive  Orange  13 

Reactive  Orange  14 

Reactive  Orange  16 

*Reactive  red  dyes: 

Reactive  Red  1 

Reactive  Red  2 

Reactive  Red  3 

Reactive  Red  4- 

Reactive  Red  5 

Reactive  Red  6 

Reactive  Red  8 

Reactive  Red  11 

Reactive  Red  13 

Reactive  Red  16 


AAP, 

EKT,    G,    ICC,    TRC. 

G,    ICC. 

EKT. 

ICI. 

G. 

TRC. 

DUP. 

DUP. 

DUP. 

DUP. 

DUP. 

DUP, 

G,    TRC. 

AAP. 

VPC. 

TRC. 

TRC. 

AAP, 

BKS,    DUP,    EKT,    G,   HSH,    ICC,    STD,    VPC 

DUP. 

EKT, 

G,    ICC. 

AAP, 

BL,    DUP,    G,    TRC. 

DUP, 

TRC. 

AAP, 

DUP. 

YAW. 

AAP, 

BL,   DUP,   EKT,    G,    NAC. 

DUP, 

EKT,    G,    ICC,    YAW. 

ICI. 

TRC. 

TRC. 

ICI. 

TRC. 

ICI. 

TRC. 

HST. 

HST. 

DUP,  HST. 

HST., 

HST.. 

ICI. 

ICI. 

HST. 

DUP,  G„  USE. 

ICI. 
TEC. 
ICI. 
TRC. 
DUP. 
ICI. 
ICI. 
ICI. 
HST. 

ICI. 
ICI. 
ICI. 
TRC. 
ICI. 
ICI. 
ICI. 
ICI. 
ICI. 
TRC. 


DYES 


103 


TABLE  8B.  - 


■Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


Dye 


FIBER- REACTIVE  DYES— Continued 

*Reactive  red  dyes — Continued 

Reactive  Red  21 

Reactive  Red  29 

Reactive  Red  31 

Reactive  Red  33 

Reactive  Red  35 

Other  reactive  red  dyes 

Reactive  violet  dyes: 

Reactive  Violet  1 

Reactive  Violet  2 

Reactive  Violet  4 

Reactive  Violet  5 

Other  reactive  violet  dyes 

*Re active  blue  dyes: 

Reactive  Blue  1 

Reactive  Blue  2 

Reactive  Blue  3 

Reactive  Blue  4 

Reactive  Blue  5 

Reactive  Blue  7 

Reactive  Blue  9 

Reactive  Blue  19 

Reactive  Blue  21 

Reactive  Blue  25 

Reactive  Blue  27 

Other  reactive  blue  dyes 

Reactive  green  dyes 

Reactive  brown  dyes: 

Reactive  Brown  1 

Reactive  Brown  10 

Reactive  black  dyes: 

Reactive  Black  1 

Reactive  Black  5 

Reactive  Black  9 

FLUORESCENT  BRIGHTENING  AGENTS 

Fluorescent  Brightening  Agent  1 

Fluorescent  Brightening  Agent  6 

Fluorescent  Brightening  Agent  8 

♦Fluorescent  Brightening  Agent  9 

Fluorescent  Brightening  Agent  22 

Fluorescent  Brightening  Agent  24 

Fluorescent  Brightening  Agent  25 

♦Fluorescent  Brightening  Agent  28 

Fluorescent  Brightening  Agent  30 

Fluorescent  Brightening  Agent  33 

Fluorescent  Brightening  Agent  34- 

Fluorescent  Brightening  Agent  37 

Fluorescent  Brightening  Agent  45 

Fluorescent  Brightening  Agent  46 

Fluorescent  Brightening  Agent  49 

Fluorescent  Brightening  Agent  52 

Fluorescent  Brightening  Agent  54 

Fluorescent  Brightening  Agent  59 

Fluorescent  Brightening  Agent  61 

Fluorescent  Brightening  Agent  68 

Fluorescent  Brightening  Agent  71 

Fluorescent  Brightening  Agent  75 

Fluorescent  Brightening  Agent  102 

Fluorescent  Brightening  Agent  108 

Fluorescent  Brightening  Agent  113 

Fluorescent  Brightening  Agent  114 

Fluorescent  Brightening  Agent  125 

Fluorescent  Brightening  Agent  126 

Fluorescent  Brightening  Agent  128 

Fluorescent  Brightening  Agent  130 

Fluorescent  Brightening  Agent  134 

Fluorescent  Brightening  Agent  135 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


HST. 
ICI. 
ICI. 
ICI. 
HST. 
DUP,  G. 

ICI. 
TRC. 
HST. 
HST. 
HST. 

ICI. 

TRC. 

ICI. 

ICI. 

TRC. 

TRC. 

ICI. 

DUP,  HST. 

DUP,  HST. 

ICI. 

HST. 

DUP,  G,  HST. 

HST. 

TRC. 
ICI. 

TRC. 
HST. 
ICI. 


GGY. 

ACT. 

ACT. 

ACY,  G,  SDH. 

GGY. 

GGY. 

G. 

ACY,  CCW,  DUP,  SDH. 

G. 

G. 

DUP. 

CIB. 

TRC. 

GGY. 

S. 

S. 

GGY. 

GGY. 

ACY. 

CCW,  G. 

ACY,  G. 

G. 

DUP. 

G. 

VPC. 

VPC. 

ACY. 

SDH. 

SDH. 

SDH. 

CIB. 

CIB. 


104 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  8B.  — Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1 965- -Continued 


Dye 


Manufacturers '   identification  codes 
(according  to  list  in  table  22) 


FLUORESCENT  BRIGHTENING  AGENTS— Continued 

Fluorescent  Brightening  Agent  136 

Fluorescent  Brightening  Agent  139 

Fluorescent  Brightening  Agent  155 

Fluorescent  Brightening  Agent  158 

Fluorescent  Brightening  Agent  159 

Fluorescent  Brightening  Agent  161 

Other  fluorescent  brightening  agents 

FOOD,   DRUG,   AND  COSMETIC  COLORS 

Food,   Drug,    and  Cosmetic  Dyes 

*FD&C  Blue  No.    1 

FD&C  Blue  No.    2 

FD&C  Green  No.   3 

*FD&C  Red  No.   2 

*FD&C  Red  No.   3 

*FD&C  Red  No.  4 

FD&C  Violet  No.   1 

*FD&C  Yellow  No.   5 

*FD&C  Yellow  No.   6 

Other  food,   drug,   and  cosmetic  dyes 

Drug  and  Cosmetic  Dyes 

D&C  Black  No.   1 

D&C  Blue  No.   1 

D&C  Blue  No.  4 

D&C  Blue  No.   6 

DM)  Blue  No.   9 

D&C  Brown  No.   1 

D&C  Green  No.   5 

D&C  Green  No.   6 

D&C  Green  No.   8 

D&C  Orange  No.  4 

D&C  Orange  No.   5 

D&C  Orange  No.   10 

D&C  Orange  No.   17 

D&C  Red  No.  2 

D&C  Red  No.  3 

D&C  Red  No.   6 

D&C  Red  No.   7 

D&C  Red  No.   8 

D&C  Red  No.    9 

D&C  Red  No.   10 

D&C  Red  No.    11 

*D&C  Red  No.   12 — 

D&C  Red  No.   13 

D&C  Red  No.    17 

*D&C  Red  No.   19 

*D&C  Red  No.   21 

D&C  Red  No.   22 

D&C  Red  No.   27 

D&C  Red  No.   28 

D&C  Red  No.  30 

D&C  Red  No.   31 - 

D&C  Red  No.   33 

D&C  Red  No.   34 

*D&C  Red  No.   36 

D&C  Red  No.  37 

D&C  Red  No.   39 

D&C  Violet  No.   2 

D&C  Yellow  No.    5 

D&C  Yellow  No.   6 

D&C  Yellow  No.   8 

D&C  Yellow  No.   10 

D&C  Yellow  No.    11 


CIB. 
CIB. 
WLM. 
ACY. 
ACY. 
ACY. 
ACY,    CCW,    CIB,    DUP,    G,    GGY,    S,    VPC. 


BAT, 

KON, 

NAC, 

SDH, 

WJ. 

K0N, 

NAC, 

SDH. 

WJ. 

BAT, 

KON, 

NAC, 

SDH, 

STG,   WJ 

BAT, 

KON, 

NAC, 

SDH, 

STG. 

BAT, 

KON, 

NAC, 

SDH, 

STG. 

BAT, 

NAC. 

BAT, 

KON, 

NAC, 

SDH, 

STG,   WJ 

BAT, 

KON, 

NAC, 

SDH, 

STG,    WJ 

WJ. 

K0N, 

YAW. 

K0N. 

SNA. 

K0N, 

NAC. 

NAC. 

NAC. 

K0N, 

NAC. 

NAC. 

K0N, 

SDH. 

K0N, 

SNA. 

SNA, 

TMS. 

TMS. 

K0N, 

SNA. 

K0N. 

K0N, 

TMS. 

K0N, 

TMS. 

K0N, 

SNA, 

TMS. 

K0N, 

TMS. 

K0N, 

SNA, 

TMS. 

K0N, 

SNA. 

K0N, 

SNA. 

K0N, 

SNA, 

TMS. 

SNA, 

TMS. 

KON, 

NAC. 

KON, 

SNA, 

TMS. 

KON, 

SNA, 

TMS. 

KON. 

TMS. 

NAC. 

KON. 

KON. 

KON, 

NAC. 

KON, 

SNA, 

TMS. 

KON, 

SNA, 

TMS. 

NAC. 

SDH. 

NAC. 

KON, 

TMS. 

KON. 

KON, 

NAC, 

TMS. 

KON, 

NAC. 

NAC. 

DYES 


105 


TABLE  8B.  —Benzenoid  dyes  for  which  U.S.  production  or  sales  were  re, 
manufacturer,  1 965-  -Continued 


ported,  identified  by 


Dye 


FOOD,   DRUG,   AND  COSMETIC  COLORS— Continued 
Drug  and  Cosmetic  Dyes,    External 


Ext.  D&C  Green  No.    1~ 

Ext.  DM  Orange  No.   3- 

Ext.  DScC  Red  No.   8 

Ext.  DScC  Red  No.  15— 

Ext.  DScC  Violet  No.  2- 

Ext.  DScC  Yellow  No.  1- 

Ext.  DScC  Yellow  No.  5- 

Ext.  DScC  Yellow  No.  7- 


Ingrain  blue  dyes: 
Ingrain  Blue  1— 
Ingrain  Blue  3— 
Ingrain  Blue  4 — 
Ingrain  Blue  8 — 


*Mordant  yellow  dyes: 

*Mordant  Yellow  1 

Mordant  Yellow  3 

Mordant  Yellow  5 

*Mordant  Yellow  8— 
Mordant  Yellow  10— 
Mordant  Yellow  14 — 
Mordant  Yellow  16 — 
Mordant  Yellow  20— 
Mordant  Yellow  26— 
Mordant  Yellow  29— 
Mordant  Yellow  30— 
Mordant  Yellow  36— 
n-Mordant  orange  dyes: 

*Mordant  Orange  1 — 
Mordant  Orange  4 — 
Mordant  Orange  6 — 
Mordant  Orange  8 — 
Mordant  Orange  30— 
*Mordant  red  dyes: 

Mordant  Red  3 

Mordant  Red  5 

Mordant  Red  6 

*Mordant  Red  7 

Mordant  Red  9 

Mordant  Red  11 

Mordant  Red  19—— 

Mordant  Red  59 

Mordant  Red  64 

Mordant  violet  dyes: 

Mordant  Violet  5— 

Mordant  Violet  11- 

Mordant  Violet  26- 

*Mordant  blue  dyes: 

*Mordant  Blue  1 

Mordant  Blue  3 

Mordant  Blue  7 

Mordant  Blue  9 

Mordant  Blue  13 

Mordant  Blue  19 

Mordant  green  dyes: 
Mordant  Green  11— 
Mordant  Green  36— 
*Mordant  brown  dyes: 

*Mordant  Brown  1 

Mordant  Brown  12 — 
Mordant  Brown  13 — 
Mordant  Brown  15 — 
Mordant  Brown  17— 


INGRAIN  DYES 


MORDANT  DYES 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


K0N,  NAC. 
K0N,  NAC. 
SNA. 
K0N. 
K0N. 

K0N,  NAC. 
SNA. 
K0N. 


ICI. 
ICI. 
ICI. 

ICI. 


ATL,    G,    PDC,    TRC. 

ATL,    NAC. 

NAC,    TRC. 

DUP,    NAC,   VPC. 

DUP. 

NAC,    TRC. 

ACY,    NAC. 

NAC. 

VPC. 

G. 

TRC,   VPC. 

PDC. 

ACY,    G,    PDC,    TRC. 

G,   VPC. 

ATL,    G,    TRC. 

TRC. 

NAC. 

ACY,    ICI,    NAC. 

PDC. 

G. 

ACY,    BD0,    CMG,    G, 

NAC, 

PDC,    TRC,    VPC 

G,    HSH,   MRX,    NAC. 

ACY,    NAC. 

PDC. 

TRC. 

PDC. 

NAC. 

G. 

G. 

DUP,    G,    NAC,    TRC. 

G. 

NAC,    TRC. 

G,    NAC. 

HSH,    NAC. 

CMG. 

ACY. 

NAC,    PDC. 

CMG,    DUP,    G,   NAC, 

TRC, 

YAW. 

PDC. 

NAC. 

G. 

106 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  8B. Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 — Continued 


Dye 


MORDANT  DYES— Continued 

*Mordant  brown  dyes — Continued 

Mordant  Brown  18 

Mordant  Brown  19 

Mordant  Brown  21 

Mordant  Brown  33 

*Mordant  Brown  4-0 

Mordant  Brown  43 

Mordant  Brown  50 

Mordant  Brown  63 

Mordant  Brown  70 

*Mordant  black  dyes: 

Mordant  Black  1 

^Mordant  Black  3 

^Mordant  Black  5 

Mordant  Black  7 

Mordant  Black  8 

Mordant  Black  9 

*Mordant  Black  11 

*Mordant  Black  13 

Mordant  Black  16 

*Mordant  Black  17 

Mordant  Black  19 

Mordant  Black  26 

*Mordant  Black  38 

OXIDATION  BASES 

Oxidation  Base  8  and  8A 

Oxidation  Base  21 

Oxidation  Base  22 

Oxidation  Base  25 

Other  oxidation  bases 

SOLVENT  DYES 

^Solvent  yellow  dyes: 

Solvent  Yellow  1 

*Solvent  Yellow  2 

^Solvent  Yellow  3 

Solvent  Yellow  13 

^Solvent  Yellow  14 

Solvent  Yellow  16 

Solvent  Yellow  19 

Solvent  Yellow  29 

Solvent  Yellow  30 

Solvent  Yellow  33 

Solvent  Yellow  34 

Solvent  Yellow  40 

Solvent  Yellow  42 

Solvent  Yellow  43 

Solvent  Yellow  44 

Solvent  Yellow  45 — 

^Solvent  Yellow  47 

Solvent  Yellow  53 

Solvent  Yellow  56 

Solvent  Yellow  66 

Solvent  Yellow  71 

Solvent  Yellow  72 

Other  solvent  yellow  dyes 

* Solvent  orange  dyes: 

^Solvent  Orange  2 

*Solvent  Orange  3 

Solvent  Orange  5 

^Solvent  Orange  7 

Solvent  Orange  20 

Solvent  Orange  23 

Solvent  Orange  24 

Solvent  Orange  25 

Solvent  Orange  31 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


DUP,  NAC. 

G. 

G,  VPC. 

DUP,  NAC,  TRC. 

CMG,  DUP,  G,  NAC,  VPC,  YAW. 

G. 

TRC. 

TRC. 

DUP,  PDC. 

G,  NAC,  TRC. 

G,  NAC,  TRC. 

G,  NAC,  TRC. 

G. 

NAC,  VPC. 

NAC,  VPC. 

G,  NAC,  TRC,  VPC. 

G,  HSH,  NAC,  TRC. 

NAC. 

ACY,  DUP,  G,  NAC,  TRC. 

PDC. 

TRC. 

CMG,  G,  NAC,  VPC. 


ACY. 
PDC. 
ACY. 
ACY. 
ACY. 


ACY. 

AAP,  DUP,  FH,  G,  PAT,  PSC. 

DUP,  FH,  G,  NAC,  PSC. 

ACY,  G,  TRC. 

AAP,  ACY,  DUP,  FH,  G,  NAC,  PAT,  PSC,  SDH. 

PAT. 

G. 

G,  NAC. 

PSC. 

ACY,  NAC. 

DUP. 

NAC. 

NAC. 

G. 

G,  NAC. 

DUP,  NAC. 

ACY,  DUP,  G,  NAC. 

NAC. 

ACY,  FH. 

NAC. 

ACY. 

ACY. 

ACY,  DSC,  PAT. 

AAP,  NAC,  PSC. 

ACY,  DSC,  G,  NAC. 

G. 

ACY,  ATL,  FH,  G,  NAC,  PSC. 

ACY,  G,  NAC. 

NAC. 

DUP. 

ACY,  DUP. 

NAC. 


DYES 


107 


TABLE  8B  -Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
lAtsi^  ob.  j      manufacturer,  1965  —Continued 


Dye 


SOLVENT  DYES— Continued 


•Solvent  orange  dyes— Continued 

Solvent  Orange  47 

Solvent  Orange  48 

Solvent  Orange  51 

Other  solvent  orange  dyes 

•Solvent  red  dyes: 

Solvent  Red  8 

Solvent  Red  22 

•Solvent  Red  24 

•Solvent  Red  26 

Solvent  Red  27 

Solvent  Red  33 

Solvent  Red  34 

Solvent  Red  35 

Solvent  Red  36 

Solvent  Red  40 

Solvent  Red  41 

•Solvent  Red  49 

Solvent  Red  52 

Solvent  Red  65 

Solvent  Red  68 

Solvent  Red  69 

Solvent  Red  74 

Solvent  Red  76 

Solvent  Red  80 

Solvent  Red  105 

Solvent  Red  106 

Solvent  Red  108 

Solvent  Red  111 

Solvent  Red  115 

Other  solvent  red  dyes 

•Solvent  violet  dyes: 

*Solvent  Violet  8 

Solvent  Violet  9 

Solvent  Violet  13 

Solvent  Violet  14 

Solvent  Violet  17 

Other  solvent  violet  dyes- 
Solvent  "blue  dyes: 

Solvent  Blue  3 

Solvent  Blue  4 

Solvent  Blue  5 

Solvent  Blue  6 

Solvent  Blue  7 

Solvent  Blue  9 

Solvent  Blue  11 

Solvent  Blue  12 

Solvent  Blue  13 

Solvent  Blue  16 

Solvent  Blue  30 

Solvent  Blue  31 

Solvent  Blue  32 

Solvent  Blue  36 

Solvent  Blue  37 

•Solvent  Blue  38 

Solvent  Blue  39 

Solvent  Blue  43 

Solvent  Blue  58 

Solvent  Blue  59 

Solvent  Blue  60 

Other  solvent  blue  dyes — 
•Solvent  green  dyes: 

Solvent  Green  1 

Solvent  Green  2 

•Solvent  Green  3 

Solvent  Green  10 

Solvent  Green  11 

Other  solvent  green  dyes- 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


ACY. 
ACY. 
DSC,  DUP,  PAT. 

G. 

G. 

ACY,  DUP,  G,  PAT,  SDH. 

AAP,  ACY,  FH,  NAC,  PSC. 

NAC. 

DUP,  G. 

DUP. 

G. 

NAC. 

G. 

DSC. 

ACY,  DSC,  DUP,  G. 

G,  ICI. 

NAC. 

NAC. 

DUP. 

NAC. 

NAC. 

NAC. 

ACY. 

ACY. 

ACY. 

ACY. 

ACY. 

ACY,  BKS,  DSC,  DUP,  G,  ICI,  PAT. 

ACY,  DSC,  NAC. 

DSC. 

AAP,  HSH,  ICI. 

ICI. 

NAC. 

DSC,  PAT. 

SW. 

DSC,  DUP,  SDH. 

DSC. 

DSC. 

ACY,  NAC. 

G. 

G,  ICI. 

DUP,  NAC 

ICI. 

NAC. 

NAC. 

NAC. 

AAP. 

DUP,  NAC. 

DUP. 

ACY,  DUP,  NAC. 

NAC. 

NAC. 

ACY. 

ACY. 

ACY. 

AAP,  ACY,  DSC,  G,  ICI,  PAT,  SDH. 


ACY,  DSC,  SDH. 

AAP,  ACY,  ATL,  CMG,  G,  HSH,  ICI,  NAC. 

DUP. 

DUP. 

DSC. 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  8B.  --Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1 965-  -Continued 


Dye 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


SOLVENT  DYES--Continued 

^Solvent  brown  dyes: 

Solvent  Brown  11 

Solvent  Brown  12 

Solvent  Brown  17 

Solvent  Brown  19 

Solvent  Brown  20 

Solvent  Brown  21 ■ 

Solvent  Brown  22 

Solvent  Brown  38 

Other  solvent  brown  dyes 

Solvent  black  dyes: 

Solvent  Black  3 

Solvent  Black  5 

Solvent  Black  7 

Solvent  Black  12 

Solvent  Black  13 

Solvent  Black  17 

Solvent  Black  19 

Solvent  Black  20 

Solvent  Black  26 

Other  solvent  black  dyes 

SULFUR  DYES 

Sulfur  yellow  dyes : 

Sulfur  Yellow  2 

Leuco  Sulfur  Yellow  2 

Sulfur  Yellow  4 

Leuco  Sulfur  Yellow  4 

Leuco  Sulfur  Yellow  15 

Other  sulfur  yellow  dyes 

Sulfur  red  dyes: 

Sulfur  Red  1 

Sulfur  Red  6 

Sulfur  Red  8 

Sulfur  blue  dyes: 

*Sulfur  Blue  7 

Leuco  Sulfur  Blue  7 

Leuco  Sulfur  Blue  8 

Sulfur  Blue  9 

Leuco  Sulfur  Blue  9 

*Sulfur  Blue  11 

Leuco  Sulfur  Blue  11 

Sulfur  Blue  13 

Leuco  Sulfur  Blue  13 

*Sulfur  Blue  15 

Sulfur  Blue  16 

Other  sulfur  blue  dyes 

Sulfur  green  dyes: 

Sulfur  Green  1 

Leuco  Sulfur  Green  1 ; — 

Sulfur  Green  2 

Leuco  Sulfur  Green  2 

Sulfur  Green  3 

Leuco  Sulfur  Green  3 

Sulfur  Green  14 

Leuco  Sulfur  Green  16 

Sulfur  Green  28 

Other  sulfur  green  dyes 

Sulfur  brown  dyes: 

Sulfur  Brown  3 

Leuco  Sulfur  Brown  3 

*Sulfur  Brown  10 

Leuco  Sulfur  Brown  10 

Sulfur  Brown  14 

Leuco  Sulfur  Brown  Li 

Sulfur  Brown  20 

Sulfur  Brown  21 

Sulfur  Brown  30 


ACY, 

DSC, 

G. 

DUP. 

DUP. 
ACY, 

DUP. 

NAC. 

FH. 

DSC. 

NAC. 

ACY, 

DSC, 

NAC. 

ACY, 

DSC, 

FH,    NAC 

NAC. 

NAC. 

DUP. 

G. 

NAC. 

ACY. 

DSC, 

DUP. 

NAC. 
ACY, 
SDC. 
SDC. 
ACY. 
ACY, 

ACY, 

ACY, 
DUP. 

ACY, 
ACY, 
SDC. 
ACY, 
SDC. 
DUP, 
SDC. 
NAC. 
ACY. 
ACY, 
ACY. 
ACY, 

NAC. 
NAC. 
NAC, 
SDC. 
NAC, 
SDC. 
DUP. 
SDC. 
ACY. 
AUG, 

SDC. 
SDC. 
DUP, 
SDC. 
ACY. 
ACY. 
DUP. 
DUP. 
ACY. 


AUG,  SDC. 


NAC. 
DUP,  NAC. 


NAC,  SDC. 
NAC,  SDC. 


NAC. 
NAC,  SDC. 


DUP,  NAC. 
SDC. 


SDC. 
SDC. 


NAC,  SDC. 


DYES 


109 


TABLE  8B. 


■  Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965-  -Continued 


Dye 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


SULFUR  DYES— Continued 

Sulfur  brown  dyes — Continued 

Sulfur  Brown  33 

Leuco  Sulfur  Brown  37 

Sulfur  Brown  39 

Sulfur  Brown  4-3 

Leuco  Sulfur  Brown  43 

Sulfur  Brown  44 

Leuco  Sulfur  Brown  44 

Sulfur  Brown  45 

Sulfur  Brown  50 

Other  sulfur  brown  dyes 

Sulfur  black  dyes: 

*Sulfur  Black  1 — 

*Leuco  Sulfur  Black  1 

Sulfur  Black  2 

*Leuco  Sulfur  Black  2 

Sulfur  Black  6 

Leuco  Sulfur  Black  6 

Sulfur  Black  10 

Leuco  Sulfur  Black  10 

Sulfur  Black  11 

Leuco  Sulfur  Black  11 

Other  sulfur  black  dyes 

VAT  DYES 

*Vat  yellow  dyes: 

Vat  Yellow  1,  12-1/2$ ■ 

*Vat  Yellow  2,  8-l/2$- 

Solubilized  Vat  Yellow  2,  25$ 

Vat  Yellow  3,  12-1/2$- 

*Vat  Yellow  4,    12-1/2$ 

Solubilized  Vat  Yellow  4,   37-1/2$ 

Vat  Yellow  10,   10$ 

Vat  Yellow  13,   6-1/2$ 

Vat  Yellow  1A,   12-1/2$ -— 

Vat  Yellow  15,    11-1/2$ 

Vat  Yellow  16,    16-2/3$- 

Vat  Yellow  21,   9-1/2$ - 

Vat  Yellow  22,    10$ 

Vat  Yellow  27 

Vat  Yellow  33 - 

Vat  Yellow  41,   9$ 

Other  vat  yellow  dyes 

*Vat  orange  dyes: 

*Vat  Orange  1,   20$ 

*Solubilized  Vat  Orange  1,   26$ 

*Vat  Orange  2,    12$ 

*Vat  Orange  3,   13-1/2$- 

*Vat  Orange  4,   6$ 

*Vat  Orange  5,    10$ 

*Solubilized  Vat  Orange  5,   30$ 

*Vat  Orange  7,   11$ 

*Vat  Orange  9,   12$ 

Vat  Orange  11,   6$ 

*Vat  Orange  15,   10$ 

Vat  Orange  23,    17-1/2$ 

Vat  Orange  24 

Other  vat  orange  dyes 

*Vat  red  dyes: 

*Vat  Red  1,  13$ 

Solubilized  Vat  Bed  1,  37$ 

Vat  Red  10,  18$ 

Solubilized  Vat  Red  10,   31$ 

Vat  Red  12,   8-1/2$ 

*Vat  Red  13,   11$ 

Vat  Red  14,   10$ 

*Vat  Red  15,   10$ 

Vat  Red  16,   11$ 


ACY. 
SDC. 
SDC. 
NAC. 
NAC. 
NAC. 
NAC. 
NAC. 
NAC. 
ACY,   AUG,    NAC,    SDC. 

ACY,    DUP,    NAC,    SDC. 

ACY,   AUG,    NAC,    SDC. 

ACY,    DUP,    NAC. 

ACY,    NAC,    SDC. 

G. 

NAC. 

ACY. 

ACY,    NAC. 

SDC. 

SDC. 

SDC. 


NAC. 

AAP,    DUP,    G,    ICI,    NAC,    TRC,    VPC. 

G,    ICI. 

DUP. 

AAP,    ACY,    ATL,    CMG,    G,    HST,    ICI,    VPC. 

G,    HST,    ICI. 

G. 

ICI. 

TRC. 

ACY. 

DUP. 

ATL. 

DUP,    G. 

VPC. 

TRC,    VPC. 

ACY. 

MAY,    NAC,    VPC. 

CMG,    G,   HST,    ICI,    NAC,    TRC,    VPC. 

G,    HST,    ICI. 

AAP,    ACY,    CMG,    DUP,    G,    ICI,    NAC,    TRC. 

CMG,    DUP,    G,   HST. 

ACY,    CMG,    DUP. 

AAP,   ACY,    HST. 

G,   HST,    ICI. 

G,    HST,    TRC. 

ACY,    CMG,    DUP,    G,    ICI,    NAC,    TRC. 

DUP,    NAC. 

AAP,    G,    ICI,    NAC,    TRC,   VPC. 

ACY,    DUP,    G. 

DUP. 

SDC. 

AAP,   ACY,   DUP,    HST,    ICI. 

G,    HST,    ICI. 

G,    NAC,    TRC. 

G. 

DUP. 

DUP,    G,    TRC. 

G,   HST. 

G,    HST,    TRC. 

DUP. 


no 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  8B.  —Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


Dye 


VAT  DYES— Continued 

*Vat  red  dyes — Continued 

Vat  Red  17,  10$ 

Vat  Red  23 - 

Vat  Red  29,  18$ 

*Vat  Red  32,  20$ 

Vat  Red  35,  12-1/2$ 

Vat  Red  41,  20$- 

Vat  Red  44,  17$ — 

Vat  Red  52,  10$- - - 

Vat  Red  53,  12$ — 

Vat  Red  56 

Vat  Red  62 

Other  vat  red  dyes 

*Vat  violet  dyes: 

*Vat  Violet  1,  11$ 

Solubilized  Vat  Violet  1,  26$ 

*Vat  Violet  2,  20$ 

Vat  Violet  3,   15$ 

*Vat  Violet  9,   12$ 

Vat  Violet  12,   10$ 

*Vat  Violet  13,   6-l/*$ 

Vat  Violet  1A,   12-1/2$ 

Vat  Violet  17,    12-1/2$ 

Other  vat  violet  dyes 

*Vat  blue  dyes: 

Vat  Blue  1,  20$ 

Solubilized  Vat  Blue  1,  25$ 

Vat  Blue  3,  16$ 

Vat  Blue  4,  10$ 

Vat  Blue  5,  16$ - 

Solubilized  Vat  Blue  5,  38$ 

*Vat  Blue  6,  8-1/3$ 

Solubilized  Vat  Blue  6,  17-1/2$- 

Vat  Blue  7,   12-1/2$ - 

Solubilized  Vat  Blue  9,   35$ 

Vat  Blue  12,   6-l/2$- 

Vat  Blue  14,   8-1/3$ 

Vat  Blue  16,    16$-- 

*Vat  Blue  18,   13$ 

*Vat  Blue  20,    14$ 

Vat  Blue  29— - 

Vat  Blue  39,   12$ 

Vat  Blue  43 

Vat  Blue  53 

Vat  Blue  60 

Vat  Blue  61,   16$ 

Other  vat  blue  dyes 

*Vat  green  dyes: 

*Vat  Green  1,   6$ 

Solubilized  Vat  Green  1,   12-3/2$ - 

*Vat  Green  3,   10$ 

*Solubilized  Vat  Green  3,   26$ 

*Vat  Green  8,   8-1/2$ 

*Vat  Green  9,   12-1/2$— 

Vat  Green  15,   17$ ■ 

Vat  Green  18,   8$- 

Vat  Green  19,   13$ 

Vat  Green  20,   6$- 

Other  vat  green  dyes 

*Vat  brown  dyes: 

*Vat  Brown  1,   11$ 

Solubilized  Vat  Brown  1,    17$ 

*Vat  Brown  3,    11$ 

*Vat  Brown  5,   13$- ■ 

Vat  Brown  6,    17-1/2$ 

Vat  Brown  11,   12$ 

Vat  Brown  12,   12-1/2$ 

Vat  Brown  13,   17$ 

Vat  Brown  14,    12$ 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


G. 

DUP. 

G,    NAC. 

DUP,    G,    NAC. 

NAC,    TRC. 

HST. 

TRC. 

DUP. 

DUP. 

ACY. 

DUP. 

DUP,    G,    TRC,    VPC. 

ACY,    DUP,    G,    ICI,   MAY,    NAC,    TRC. 

G,    ICI. 

ACY,    G,   HST,    NAC,   VPC. 

G,   HST,    NAC. 

DUP,    G,    ICI,   MAY,    NAC,    TRC. 

DUP. 

DUP,    G,    ICI,    NAC,    TRC. 

NAC. 

DUP,    G,    NAC. 

NAC. 

NAC. 

G. 

HST. 

ACY,   DUP,    G. 

ATL,    DUP,    HST,    NAC,   VPC. 

AAP,   ACY,   DUP,    G,    ICI,   MAY,    NAC,    TRC. 

G,    HST,    ICI. 

NAC. 

G. 

DUP. 

DUP,    G,    NAC,    TRC. 

ACY,    DUP,    NAC. 

AAP,    ACY,   DUP,    G,    ICI,   MAY,    NAC,    TRC. 

AAP,   ACY,   ATL,   DUP,    G,    ICI,   MAY,    NAC,    TRC. 

G. 

G. 

SDC. 

G. 

DUP. 

DUP. 

SDC,    x. 

AAP,    ACY,   ATL,    DUP,    G,    ICI,   MAY,    NAC. 

G,   HST,    ICI. 

AAP,   ACY,   ATL,    DUP,    G,    ICI,   MAY,    NAC,    TRC. 

G,    HST,    ICI. 

ATL,    DUP,    G,    ICI,    NAC. 

ACY,   ATL,    DUP,    G,   MAY,    NAC,    SDC,    TRC. 

NAC. 

DUP. 

DUP. 

DUP. 

G,    SDG. 

ACY,  DUP,    G,    ICI,   MAY,    NAC,    TRC. 

G,    ICI. 

AAP,  ACY,   DUP,    G,    ICI,   MAY,    NAC,    TRC,   VPC. 

AAP,  ACY,    G,    HST,    VPC. 

TRC. 

MAY,  TRC. 

DUP,  NAC. 

MAY. 

HST. 


DYES 


TABLE  8B.  --Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


Dye 

Manufacturers'  identification  codes 
(according  to  list  in  table  22) 

VAT  DYES— Continued 
*Vat  brown  dyes — Continued 

G. 

ACT. 

AAP. 

ICI. 

DUP. 

G. 

TRC. 

*Vat  black  dyes: 

ACY. 

G. 

112 


SYNTHETIC  ORGANIC  CHEMICALS.  1965 


Pigments 

TABLE  11B.  —  Benzenoid  pigments  for  which  U.S.  production  or  sales  were  reported,  identified 

by  manufacturer ,  1965 

[Benzenoid  pigments  for  which  separate  statistics  are  given  in  table  11A  are  marked  below  with  an  asterisk  (♦); 
products  not  po  marked  do  not  appear  in  table  11A  because  the  reported  data  are  accepted  in  confidence  and  may 
not  be  published.  Manufacturers'   identification  codes  shown  below  are  taken  from  table  22.  An  x  signifies  that 
the  manufacturer  did  not  consent  to  his  identification  with  the  designated  product ] 


Pigment 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


TONERS 
♦Yellow  toners: 
♦Hans a  yellows: 

♦Pigment  Yellow  1,  C.I.  11  680 

♦Pigment  Yellow  3,  C.I.  11  710 

Pigment  Yellow  4,  C.I.  11  665 

Pigment  Yellow  5, 'C.I.  11  660 

Pigment  Yellow  6,  C.I.  11  670 

Pigment  Yellow  9,  C.I.  11  720 

Pigment  Yellow  49,  C.I.  11  765 

Pigment  Yellow  65,  C.I.  11  74-0 

Pigment  Yellow  73 

Pigment  Yellow  74 

All  other  Hansa  yellows 

♦Benzidine  yellows: 

♦Pigment  Yellow  12,  C.I.  21  090 

♦Pigment  Yellow  13,  C.I.  21  100 

♦Pigment  Yellow  14,  C.I.  21  095 

♦Pigment  Yellow  17,  C.I.  21  105 

Pigment  Yellow  83 

All  other  benzidine  yellows 

Pigment  Yellow  10,  C.I.  12  710 

Pigment  Yellow  18,  C.I.  49  005 

Pigment  Yellow  19 

Pigment  Yellow  60,  C.I.  12  705 

Pigment  Yellow  62 

(Basic  Yellow  2),  C.I.  41  000,  fugitive- 

(Vat  Yellow  1),  C.I.  70  600 

(Vat  Yellow  20),  C.I.  68  420 

All  other 

♦Orange  toners: 

Pigment  Orange  1,  C.I.  11  725 

♦Pigment  Orange  2,  C.I.  12  060 

♦Pigment  Orange  5,  C.I.  12  075 

Pigment  Orange  9 

♦Pigment  Orange  13,  C.I.  21  110 

Pigment  Orange  15,  C.I.  21  130 

♦Pigment  Orange  16,  C.I.  21  160 

Pigment  Orange  30 

(Vat  Orange  2),  C.I.  59  705 

(Vat  Orange  3),  C.I.  59  300 

(Vat  Orange  4),  C.I.  59  710 

(Vat  Orange  5),  C.I.  73  335 

(Vat  Orange  7),  C.I.  71  105 

(Vat  Orange  15),  C.I.  69  025 

All  other 

♦Red  toners: 
♦Naphthol  reds: 

♦Pigment  Red  2,  C.I.  12  310 

♦Pigment  Red  5,  C.I.  12  490 

Pigment  Red  7,  C.I.  12  420 

Pigment  Red  9,  C.I.  12  460 

Pigment  Red  10,  C.I.  12  440 

Pigment  Red  13,  C.I.  12  395 

Pigment  Red  14,  C.I.  12  380 

Pigment  Red  15,  C.I.  12  465 


ACY,  AMS,  DUP,  FCL,  G,  HSC,  HSH,  ICI,  IMP,  K0N,  NAC, 

PPG,  S,  SDH,  SNA,  SW. 
HSC,  HSH,  HST,  IMP,  KCW,  K0N,  NAC,  PPG,  S,  SNA,  SW. 
NAC,  SNA. 
IMP. 

CIK,  IMP. 
SNA. 
ICI. 
SW. 

NAC,  SW. 
DUP,  SW. 
DUP,  HSC,  HSH,  IMP,  KCW,  SDH,  SNA. 

ACY,  AMS,  DUP,  FCL,  G,  HSC,  HSH,  ICC,  IMP,  KON,  LVY, 

MRX,  NAC,  S,  SDH,  SNA,  SW. 
BUC,  FCL,  G,  HSH,  HST,  ICC,  IMP,  NAC,  ROM,  SNA,  SW. 
ACY,  AMS,  BUC,  CPC,  DUP,  FCL,  G,  HSC,  HSH,  HST,  ICC, 

IMP,  KON,  MRX,  NAC,  ROM,  S,  SDH,  SNA,  SW,  x. 
ACY,  AMS,  DUP,  FCL,  HSC,  HSH,  HST,  ICC,  IMP,  S,  SDH, 

SNA,  SW. 
HST,  NAC. 

BUC,  HSH,  ICC,  IMP,  ROM,  S,  SW. 
SW. 
IMP. 
G. 
SW. 
S. 

MRX. 

NAC,  TRC. 
NAC,  TRC. 
ACY,  ICC,  IMP,  SW. 

KCW,  NAC. 

FCL,  IMP,  SDH,  SW. 

ACY,  EAK,  HSC,  IMP,  SNA,  SW. 

DUP. 

ACY,  AMS,  BUC,  DUP,  G,  ICC,  IMP,  KON,  NAC,  SNA,  SW. 

G,  NAC. 

BUC,  DUP,  FCL,  G,  HSH,  HST,  ICC,  IMP,  NAC,  ROM,  SDH, 

SNA,  SW. 
SNA,  SW. 
G. 

NAC,  TRC. 
NAC. 
TRO. 
G,  NAC. 
NAC. 
HSH,  ICC,  KON,  ROM,  SDH. 


BUC,  EAK,  G,  HSC,  HSH,  IMP,  KCW,  KON,  MRX,  NAC,  S,  SDH, 

SW. 
DUP,  G,  HSH,  HST,  ICC,  ICI,  IMP,  NAC,  ROM,  SDH,  SNA,  SW. 
ICI,  S. 
IMP. 
KCW. 

IMP,  KCW. 
DUP,  NAC. 
DUP. 


See  note  at  end  of  table  for  definition  of  abbreviations. 


PIGMENTS 

TABLE  WB.—Benzenoid  pigments  for  which  U.S.  production  or  sales  were  reported,  identified 
by  manufacturer,  1 965—  Continued 


113 


Pigment 


TONERS— Continued 

♦Red  toners — Continued 
*Naphthol  reds --Continued 

*Pigment  Red  17,  C.I.  12  390 

♦Pigment  Red  18,  C.I.  12  350 

Pigment  Red  19,  C.I.  12  400 

♦Pigment  Red  22,  C.I.  12  315 

♦Pigment  Red  23,  C.I.  12  355 

Pigment  Red  31,  C.I.  12  360 

All  other  naphthol  reds 

♦Pigment  Red  1,  C.I.  12  070,  dark 

♦Pigment  Red  1,  C.I.  12  070,  light 

*Pigment  Red  3,  C.I.  12  120 

♦Pigment  Red  4,  C.I.  12  085 

Pigment  Red  5 

♦Pigment  Red  6,  C.I.  12  090 

♦Pigment  Red  38,  C.I.  21  120 

Pigment  Red  41,  C.I.  21  200 

♦Pigment  Red  48,  C.I.  15  865 

Pigment  Red  49,  C.I.  15  630: 
*Barium  toner 

♦Calcium  toner 

♦Sodium  toner 

♦Pigment  Red  52,  C.I.  15  860 

♦Pigment  Red  53,  C.I.  15  585,  barium  toner- - 

Pigment  Red  53,  C.I.  15  585,  sodium  toner-- 

♦Pigment  Red  54,  C.I.  14  830,  calcium  toner- 
Pigment  Red  55,  C.I.  15  820 

♦Pigment  Red  57,  C.I.  15  850,  calcium  toner- 
Pigment  Red  58,  C.I.  15  825 

♦Pigment  Red  63,  C.I.  15  880 

Pigment  Red  64,  C.I.  15  800 

Pigment  Red  77,  C.I.  15  826 

Pigment  Red  78 

Pigment  Red  79,  PMA 

Pigment  Red  81,  C.I.  45  160,  fugitive 

♦Pigment  Red  81,  C.I.  45  160,  PMA. 

♦Pigment  Red  81,  C.I.  45  160,  PTA 

Pigment  Red  87,  C.I.  73  310 

Pigment  Red  88 

♦Pigment  Red  90,  C.I.  45  380 

Pigment  Red  117,  C.I.  15  603 

Pigment  Red  122 

Pigment  Red  123 

(Vat  Red  10),  C.I.  67  000 

(Vat  Red  23) 

(Vat  Red  29),  C.I.  71  140 

All  other 

♦Violet  toners: 

Pigment  Violet  1,  C.I.  45  170,  fugitive 

♦Pigment  Violet  1,  C.I.  45  170,  PMA 

♦Pigment  Violet  1,  C.I.  45  170,  PTA 

♦Pigment  Violet  3,  C.I.  42  535,  fugitive 

♦Pigment  Violet  3,  C.I.  42  535,  PMA 

♦Pigment  Violet  3,  C.I.  42  535,  PTA 

Pigment  Violet  19 

Pigment  Violet  23 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


ACY,  BLN,  FCL,  ICC,  IMP,  S,  SNA,  SW. 

IMP,  NAC,  SW. 

NAC. 

ACY,  DUP,  FCL,  IMP,  MRX,  NAC,  SNA,  SW. 

ACY,  BUC,  DUP,  FCL,  HSC,  HSH,  ICC,  IMP,  NAC,  ROM,  SDH, 

SNA. 
ICC,  SNA. 

BUC,  ICC,  IMP,  KCW,  ROM,  SDH,  SW,  x. 
ACY,  AMS,  APC,  FCL,  HSC,  HSH,  IMP,  K0N,  LVY,  NAC, 

PPG,  SDH,  SW. 
ACY,  EAK,  FCL,  HSC,  HSH,  IMP,  KON,  PPG,  SDH,  SW. 
ACY,  APC,  BLN,  CIK,  DUP,  EAK,  FCL,  HSC,  HSH,  IMP,  KCW, 

KON,  NAC,  PPG,  SDH,  SNA,  SW. 
ACY,  AMS,  FCL,  HSC,  HSH,  IMP,  KON,  MRX,  SDH,  SNA,  SW, 

UHL. 
IMP. 

DUP,  HSC,  HSH,  KCW,  SW. 
DUP,  G,  NAC,  SNA,  SW. 
G,  NAC. 
ACY,  AMS,  BLN,  DUP,  FCL,  G,  HSC,  HSH,  ICC,  IMP,  KON, 

LVY,  MRX,  NAC,  S,  SNA,  SW. 

ACY,  AMS,  CIK,  FCL,  HSC,  HSH,  IMP,  KON,  LVY,  PPG,  SDH, 

SNA,  SW,  UHL. 
ACY,  AMS,  FCL,  HSC,  IMP,  LVY,  PPG,  SDH,  SNA,  SW. 
ACY,  AMS,  CIK,  FCL,  HSC,  SDH,  SW. 
AMS,  FCL,  HSC,  HSH,  IMP,  SNA,  SW. 
ACY,  AMS,  CIK,  FCL,  HSC,  HSH,  IMP,  KON,  LVY,  MGR,  MRX, 

SDH,  SNA,  SW. 
KCN. 

HSH,  IMP,  MRX,  SDH. 
DUP,  NAC. 
AMS,  BLN,  CIK,  DUP,  FCL,  HSC,  HSH,  IMP,  KON,  LVY,  MGR, 

NAC,  S,  SDH,  SNA,  SW. 
DUP,  G,  IMP. 

FCL,  HSH,  IMP,  NAC,  SNA,  SW. 
NAC. 
SW. 
DUP. 
G. 

BLN,  KCW. 
BLN,  CPC,  DUP,  FCL,  G,  IMP,  KON,  LVR,  LVY,  MGR,  MRX, 

NYC,  S,  SNA,  SW. 
ACY,  AMS,  BLN,  DUP,  FCL,  G,  HSC,  IMP,  KCW,  KON,  MGR, 

MRX,  S,  SDH,  SNA. 
NAC. 

NAC,  SDH. 

AMS,  FCL,  ICC,  IMP,  LVR,  LVY,  NYC,  SDH,  SNA. 
SW. 
NAC. 
NAC. 
G,  NAC. 
NAC. 
NAC. 
ACY,  DUP,  G,  HAM,  HSC,  S,  SW,  TRC. 

BLN,  UHL. 

BLN,  G,  IMP,  LVR,  MRX. 

ACY,  AMS,  BLN,  DUP,  FCL,  G,  HSC,  IMP,  KON,  MRX,  SNA. 

ACY,  AMS,  BLN,  HAM,  HSC,  IMP,  LVY,  MGE,  SDH,  UHL. 

AMS,  BLN,  CIK,  DUP,  EAK,  G,  HSC,  IMP,  KON,  LVR,  LVY, 

MGR,  MRX,  NYC,  PPG,  SDH,  SNA,  SW,  UHL. 
ACY,  AMS,  G,  HSC,  HSH,  IMP,  KON,  MRX,  SNA,  SW. 
DUP,  NAC. 
G,  HST,  TRC. 


See  note  at  end  of  table  for  definition  of  abbreviations. 


TABLE  11B. 


SYNTHETIC  ORGANIC  CHEMICALS.  1965 

-Benzenoid  pigments  for  which  U.S.  production  or  sales  were  reported,  identified 
by  manufacturer,  1 965- -Continued 


Pigment 


TONERS--Ccmtinued 

*Violet  toners — Continued 

(Vat  Violet  1),  C.I.  60  010 

(Vat  Violet  2),  C.I.  73  385 

(Vat  Violet  3),  C.I.  73  395 

All  other 

♦Blue  toners: 

♦Pigment  Blue  1,  C.I.  42  595,  PMA 

♦Pigment  Blue  1,  C.I.  42  595,  PTA 

♦Pigment  Blue  2,  C.I.  44  045,  fugitive 

♦Pigment  Blue  2,  C.I.  44  045,  PMA 

♦Pigment  Blue  2,  C.I.  44  045,  PTA 

Pigment  Blue  3,  C.I.  42  140,  PTA 

Pigment  Blue  5,  C.I.  42  600 

Pigment  Blue  9,  C.I.  42  025,  PMA 

♦Pigment  Blue  9,  C.I.  42  025,  PTA 

Pigment  Blue  10,  C.I.  44  040,  PMA 

Pigment  Blue  10,  C.I.  44  040,  PTA 

♦Pigment  Blue  14,  C.I.  42  600,  PMA 

Pigment  Blue  14,  C.I.  42  600,  PTA 

♦Pigment  Blue  15,  C.I.  74  160,  alpha  form 

♦Pigment  Blue  15,  C.I.  74  160,  beta  form 

♦Pigment  Blue  19,  C.I.  42  750A 

♦Pigment  Blue  22,  C.I.  69  810 

Pigment  Blue  25,  C.I.  21  180 

(Basic  Blue  7),  C.I.  42  595,  PTA 

(Vat  Blue  4),  C.I.  69  800 

(Vat  Blue  6),  C.I.  69  825 

(Vat  Blue  14),  C.I.  69  810 

All  other 

♦Green  toners: 

Pigment  Green  1,  C.I.  42  040,  fugitive 

♦Pigment  Green  1,  C.I.  42  040,  PMA 

♦Pigment  Green  1,  C.I.  42  040,  PTA 

♦Pigment  Green  2,  C.I.  42  040  and  49  005,  PMA- 
♦Pigment  Green  2,  C.I.  42  040  and  49  005,  PTA- 

Pigment  Green  4,  C.I.  42  000,  fugitive 

♦Pigment  Green  4,  C.I.  42  000,  PMA 

♦Pigment  Green  4,  C.I.  42  000,  PTA 

♦Pigment  Green  7,  C.I.  74  260 

♦Pigment  Green  8,  C.I.  10  006 

Pigment  Green  10,  C.I.  12  775 

Pigment  Green  36 

Pigment  Green  38 

All  other 

♦Brown  toners : 

Pigment  Brown  1,  C.I.  12  480 

Pigment  Brown  2,  C.I.  12  071 

Pigment  Brown  3,  C.I.  21  010,  PMA 

♦Pigment  Brown  5,  C.I.  15  800 

(Vat  Brown  3),  C.I.  69  015 

All  other 

♦Black  toners: 

Pigment  Black  1 

Pigment  Black  7,  C.I.  77  266 

All  other 

LAKES 

Yellow  lakes: 

(Acid  Yellow  1),  C.I.  10  316 

(Acid  Yellow  3),  C.I.  47  005 

(Acid  Yellow  11),  C.I.  18  820 

(Acid  Yellow  23),  C.I.  19  140 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


DUP,  ICI,  NAC. 

NAC. 

NAC. 

ACY,  G,  ICC,  IMP,  ROM. 

BLN,  DUP,  EAK,  FCL,  G,  HSC,  IMP,  K0N,  LVR,  LVY,  MGR, 

MRX,  NYC,  SDH,  SNA,  SW,  UHL. 
AMS,  G,  HAM,  IMP,  MGR,  NAC,  SNA,  SW,  UHL. 
BLN. 

G,  IMP,  LVR. 
G,  HAM. 
MGR. 
G. 

MRX,  NYC,  UHL. 
BLN,  G,  IMP,  MGR,  MRX,  SDH. 
IMP,  SDH. 
IMP. 

DUP,  G,  IMP,  NYC. 
DUP,  G,  NYC. 
ACY,  DUP,  FCL,  G,  HSC,  ICC,  ICI,  IMP,  NAC,  SNA,  SW, 

TMS,  TRC. 
ACY,  AMS,  DUP,  FCL,  HSC,  IMP,  LVY,  NAC,  SNA,  SW,  TMS. 
ACY,  AMS,  HSC,  NYC,  SW. 
DUP,  IMP,  TRC. 
DUP,  G,  ICC,  NAC. 
DUP. 
G. 

ICI,  TRC. 
NAC. 
G,  IMP,  MGR,  SDH. 


BLN,  G,  IMP,  MGR,  MRX,  NYC,  UHL. 

BLN,  IMP,  K0N,  S,  SDH,  SNA. 

G,  IMP,  LVY,  MGR,  MRX,  SDH,  UHL. 

ACY,  AMS,  BLN,  DUP,  IMP,  K0N,  LVY,  MGR,  MRX,  S,  SDH, 

UHL. 
BLN,  G,  MGR. 
BLN,  G,  MGR. 
ACY,  AMS,  HAM,  IMP. 
ACY,  DUP,  FCL,  G,  HSC,  ICC,  IMP,  NAC,  SNA,  SW,  TMS, 

TRC. 
DUP,  G,  HSH,  IMP,  KCW,  LVY,  SW. 
DUP,  HSC,  IMP,  SW. 
ACY,  G. 
NAC. 
ACY,  G,  SNA. 

ICI. 

SDH. 

BLN,  KCW. 

BUC,  HSH,  ICC,  NAC,  ROM,  SNA. 

G,  NAC,  TRC. 

G,  ICC,  SDH,  SW. 

SNA. 
G. 


BLN,  DUP,  G,  MGR,  UHL. 


IMP. 
IMP. 
KON. 
KON,  MRX. 


See  note  at  end  of  table  for  definition  of  abbreviations. 


PIGMENTS 


115 


TABLE  11B. 


■  Benzenoid  pigments  for  which  U.S.  production  or  sales  were  reported,  identified 
by  manufacturer ,  1965 — Continued 


Pigment 

Manufacturers '  identification  codes 
(according  to  list  in  table  22) 

LAKES— Continued 

Orange  lakes: 

Pigment  Orange  17,  C.I.  15  510 

All  other 

*Red  lakes: 

♦Pigment  Red  60,  C.I.  16  105 

♦Pigment  Red  83,  C.I.  58  000 

(Acid  Red  17),  C.I.  16  180 

(Acid  Red  25),  C.I.  16  050 

♦  (Acid  Red  26),  C.I.  16  150 

(Acid  Red  27) 

(Natural  Red  4),  C.I.  75  470 

All  other 

*Violet  lakes: 

♦Pigment  Violet  5,  C.I.  58  055 

Pigment  Violet  20,  C.I.  58  225 

(Acid  Violet  17),  C.I.  42  650 

♦Blue  lakes: 

Pigment  Blue  17,  C.I.  74  180 

♦Pigment  Blue  24,  C.I.  42  090 

(Acid  Blue  93),  C.I.  42  780 

(Acid  Blue  104),  C.I.  42  735 

Green  lakes:   (Acid  Green  3),  C.I.  42  085 

Brown  lakes 

Black  lakes: 
♦(Natural  Black  3),  C.I.  75  291 

CIK,  CPC,  IMP,  KCW,  MGR. 
APC,  HAM. 

BLN,  DUP,  HSC,  HSH,  K0N,  MRX,  SNA,  SW. 

HSH,  IMP,  KON,  MRX,  SW,  UHL. 

IMP,  KCW. 

KON. 

CPC,  EAK,  HAM,  IMP,  KCW. 

KON. 

KON. 

APC,  G,  HAM,  IMP. 

BLN,  DUP,  HSH,  IMP,  NAC. 

SW. 

BLN. 

HAM,  HSC. 

BLN,  CPC. 

AMS,  BLN,  ICC,  KON,  LVY,  MGR,  SDH. 

LVR. 

CPC,  KCW. 

BLN,  CPC. 

HAM,  KON. 

CPC,  KON,  NYC. 
HAM. 

Note. — The  C.I.   (Colour  Index)  numbers  shown  in  this  report  are  the  identifying  codes  given  in  the  second  edition 
of  the  Colour  Index. 

When  the  name  of  a  color  is  enclosed  in  parentheses,   it  indicates  that  this  name  is  that  of  the  dye  from  which  the 
pigment  can  be  made  and  that  no  name  for  the  pigment  itself  is  given  in  the  Colour  Index. 

The  abbreviations  PMA  and  PTA  stand  for  phosphomolybdic  and  phosphotungstic   (including  phosphotungstomolybdic ) 
acids,  respectively. 


116 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


Medicinal  Chemicals 

TABLE  13B.  —Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 

[Medicinal  chemicals  for  which  separate  statistics  are  given  in  table  13A  in  pt.  II  are  marked  below  with  an  asterisk 
(*);  medicinal  chemicals  not  so  marked  do  not  appear  in  table  13A  because  the  reported  data  are  accepted  in  con- 
fidence and  may  not  be  published.  Manufacturers '  identification  codes  shown  below  are  taken  from  table  22.  An  x 
signifies  that  the  manufacturer  did  not  consent  to  his  identification  with  the  designated  product] 


Chemical 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


* Antibiotics : 

*For  medicinal  use: 

*Antifungal  and  antitubercular  antibiotics 
Antifungal  antibiotics : 

Amphotericin  B 

Candicidin 

Nystatin 

Antitubercular  antibiotics : 

Cycloserine 

Dihydrostreptomycin 

^Streptomycin 

Viomycin 

*Bacitracin 

*Penicillins : 

Ampicillin 

Cloxacillln,  sodium 

Methicillin,  sodium 

Nafcillin,  sodium 

Oxacillin,  sodium 

Penicillin  G,  benzathine 

^Penicillin  G,  potassium 

*Penicillin  G,  procaine 

Penicillin  G,  sodium 

Phenethicillln,  potassium 

Phenoxymethylpenicill in  (Penicillin  V)  — 

Phenoxymethylpenicil 1  in,  benzathine 

Phenoxymethylpenicillln,  hydrabamine 

Phenoxymethylpenicillin,  potassium 

*Other  antibiotics  for  medicinal  use: 

Cephalothin 

Chloramphenicol 

Erythromycin 

Fumagillin 

Gentamycin 

Gramicidin 

Kanamycin 

Lincomycin 

Neomycin 

Novobiocin 

Oleandomycin 

Paromomycin 

Polymyxin  B 

Ristocetin 

Tetracyclines : 

Chlortetracycline 

Demethylchlortetracycline 

Oxytetracycline 

Tetracycline 

Thiostrepton 

Triacetyloleandomyciii 

Tyrothricin 

*For  other  uses: 

^Bacitracin 

Chlortetracycline 

Cycloheximide 

Ifygromycin  B 

Neomycin 

Novobiocin 

Oxytetracycline 

^Penicillin  G,  procaine, 

Streptomycin 1 

Tylosin 


PEN. 

OMS. 

COM. 

MRK, 

OMS, 

PFZ. 

LIL, 

MRK, 

OMS, 

PFZ. 

PFZ. 

COM, 

PEN, 

PFZ, 

PMP. 

BRS. 

BRS. 

WYT. 

BRS. 

PFZ, 

WYT. 

LIL, 

MRK, 

OMS, 

PFZ, 

WYT 

LIL, 

MRK, 

OMS, 

PFZ, 

WYT 

MRK, 

OMS, 

PFZ. 

BRS, 

PFZ, 

WYT. 

LIL. 

WYT. 

ABB. 

ABB, 

LIL. 

SCH. 

BAX, 

BRS. 

x. 

OMS, 

MRK, 

PFZ. 

MRK. 

PFZ. 

ABB. 

ACY. 
ACY. 
PFZ. 
ACY, 
OMS. 
PFZ. 
BAX, 

COM, 
ACY. 
UP  J. 
LIL. 
PFZ. 
UP  J. 
PFZ. 
LIL, 
MRK, 
LIL. 


PEN,  PFZ,  UP J. 
UP  J. 


BRS,  PFZ,  RLS. 

PEN. 

GPR,  PEN,  PMP. 


MRK,  OMS,  PFZ,  WYT. 
PFZ. 


MEDICINAL  CHEMICALS 


117 


TABLE  13B. — Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 — Continued 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


♦Antihistamines : 
*Antinauseants : 

Cyclizine  hydrochloride 

Dimehhydrinate 

Meclizine  hydrochloride 

Trimethobenzamide  hydrochloride 

Bromodiphenhydramine  hydrochloride 

Brompheniramine  maleate 

Carbinoxamine  maleate 

Chlorcyclizine  hydrochloride 

♦Chlorpheniramine  maleate 

Cyproheptadine  hydrochloride 

Dexbrompheniramine  maleate 

Dexchlorpheniramine  maleate 

Dimethindene  maleate 

Diphenhydramine  hydrochloride 

Doxylamine  succinate 

Methapyrilene  fumarate 

Methapyrilene  hydrochloride 

Methapyrilene  hydroxybenzoylbenzoate 

Phenindamine  tartrate 

♦Pheniramine  maleate 

Phenyltoloxamine  citrate 

♦Pyrilamine  maleate 

Pyrrobutamine  phosphate 

Eotoxamine  (levo- Carbinoxamine)  tartrate 

Thenyldiamine  hydrochloride 

Thonzylamine  hydrochloride 

Tripelennamine 

Tripelennamine  citrate 

Tripelennamine  hydrochloride 

Triprolidine  hydrochloride 

♦Anti-infective  agents  (except  antibiotics): 
♦Antimony,  arsenic,  and  bismuth  compounds: 

Arsanilic  acid 

Bismuth  dipropylacetate 

Bismuth  sodium  triglycollamate 

Bismuth  subsalicylate 

Carbarsone 

Glycobiarsol 

Ni tars one 

Roxarsone 

Roxarsone,  sodium 

Sodium  arsanilate 

*Cetylpyridinium  chloride 

♦Mercury  compounds : 

o-Hydroxyphenylmercuric  chloride 

Merbromin 

Mercuric  salicylate 

Nitromersol 

Phenylmereuric  acetate 

Phenylmercuric  benzoate 

Phenylmereuric  borate 

Phenylmercuric  chloride 

Phenylmercuric  nitrate 

Thimerosal 

♦5-Nitrofurane,  -imidazole,  and  -thiazole  derivatives: 

Acinitrazole 

2-Amino-5-nitrothiazole 

Furazolidone 

Metronidazole 

Nihydrazone 

Ni thiazide 

Nitrofurantoin 

Nitrofura thiazide 

Nitrofurazone 

♦Phenolic  antiseptics  and  disinfectants: 

Betanaphthol 

Bithionol 

Resorcinol 

Thymol 

Thymol  iodide 


BUR. 

SRL. 

PFZ. 

HOF. 

PD. 

SCH. 

SCH. 

ABB, 

HEX, 

MRK. 

SCH. 

SCH. 

CBP. 

ARA, 

BKC. 

ABB. 

ABB. 

LIL. 

HOF. 

HEX, 

BRS. 

BKL, 

LIL. 

SCH. 

SDW. 

NEP. 

CBP. 

CBP. 

CBP. 

BUR. 


BUR. 

LEM,  SCH,  SK,  x. 


GAN,  PD. 


LEM,  SCH,  x. 

HEX,  MRK,  PYL,  RSA. 


MAL, 

NOR, 

PEN. 

LIL, 

PYL, 

RSA, 

WHL. 

SDW. 

SAL. 

SAL. 

SAL. 

SAL, 

WHL. 

BKL, 

FIN, 

GAN, 

HEX,    NEP 

MRK. 

HYN. 

MAL, 

MRK. 

ABB. 

WRC. 

MRK, 

WRC. 

MRK, 

WRC. 

MRK. 

MRK, 

WRC. 

LIL, 

PYL, 

SEL. 

ACY. 

ACY. 

NOR. 

RDA. 

NOR. 

MRK. 

NOR. 

SCH. 

NOR. 

ACY, 

FIN. 

SDH. 

KPT, 

LEM. 

GIV. 

MAL. 

118 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  13B. 


■  Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


*Anti-infective  agents  (except  antibiotics)  —  Continued 
*Piperazine  base  and  salts : 

*Piperazine 

Piperazine  adipate 

Piperazine  calcium  edetate 

Piperazine  citrate 

Piperazine  dihydrochloride 

Piperazine  hexabydrate 

Piperazine  hydrochloride 

Piperazine  phosphate 

Piperazine  sulfate 

Piperazine  tartrate 

*Quinoline  derivatives: 

Amodiaquin 

Amodiaquin  hydrochloride 

Chloroquine  phosphate 

*Diiodohydroxyquin 

Hydroxychloroquine  sulfate 

8-Hydroxy-5-quinolinesulfonic  acid 

Iodochlorhydroxyquin 

Qxyquinoline 

Oxyquinoline  benzoate 

Qxyquinoline  citrate 

Qxyquinoline  potassium  sulfate 

Qxyquinoline  sulfate 

Primaquine  phosphate 

^Sulfonamides : 

Acetyl  sulfamethoxypyridazine ' 

Acetyl  sulfisoxazole 

Azosulf  amide . 

Dinsed 

Mafenide  hydrochloride 

Phthalylsulfacetamide 

Phthalylsulfathiazole 

Succinylsulfathiazole 

Sulfabenz 

Sulfabenzamide 

Sulfabenzamide,  sodium 

Sulfabromomethazine,  sodium 

Sulfacetamide 

Sulfacetamide,  sodium 

Sulfadiazine 

Sulfadiazine,  sodium 

Sulfadimethoxine 

Sulfaethidole 

Sulfaguanidine 

Sulfamerazine 

Sulfamerazine,  sodium 

Sulfamethazine 

Sulfamethizole 

Sulfamethoxazole 

Sulfamethoxypyridazine 

Sulfanilamide 

Sulfanitran • 

Sulfapyridine 

Sulf apy ridine ,  sodium 

Sulfaquinoxaline 

*Sulfathiazole 

Sulfathiazole,  sodium 

Sulfisoxazole 

*Other  anti-infective  agents : 

*Anthelmintic,  antifungal,  antiprotozoan,  and 
antiviral  agents : 
Anthelmintic  agents : 

Cadium  anthranilate 

Diethylcarbamazine  citrate 

Gentian  violet 

Hexylresorcinol 

Phenothiazine 

Pyrvinium  pamoate 

Thiabendazole 


DOW, 

JCC, 

UCC. 

JCC, 

PYL, 

RDA. 

EN. 

BUR, 

JCC, 

RDA. 

DOW, 

JCC, 

RDA, 

WHL. 

JCC, 

RDA. 

DOW, 

JCC, 

RDA. 

BUR, 

JCC, 

PYL, 

RDA,   WHL 

JCC, 

RDA. 

RDA. 

PD. 

PD. 

SDW. 

LEM, 

PYL, 

RSA, 

SRL. 

SDW. 

GAM, 

MRK. 

CBP, 

PYL. 

GAM, 

LEM, 

MRK. 

GAM, 

LEM, 

MRK. 

GAM. 

LEM. 

GAM, 

LEM, 

MRK, 

PYL. 

PD, 

SDW. 

ACY. 

HOF. 

SDW. 

SAL. 

SDW. 

LEM. 

MRK. 

LEM, 

MRK. 

SAL. 

ACY. 

ACY. 

MRK. 

LEM. 

LEM, 

SCH. 

ACY, 

LEM. 

ACY. 

HOF. 

ACY. 

ACY, 

LEM. 

ACY, 

LEM. 

ACY. 

ACY, 

LEM. 

ACY. 

HOF. 

ACY. 

LEM, 

MRK. 

SAL. 

ACY, 

MRK. 

ACY. 

MRK. 

ACY, 

LEM, 

MRK. 

ACY, 

MRK. 

HOF. 

MAL. 

ACY. 

NAC,  SDH. 

HEX,  MRK. 

CLV. 

x. 

MRK. 


MEDICINAL  CHEMICALS 

TABLE  13B.-- Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


1)9 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


*Anti-ihfective  agents  (except  antibiotics) --Continued 
*Other  anti-infective  agents — Continued 

*Anthelmintic ,  antifungal,  antiprotozoal  and 
antiviral  agents — Continued 
Antifungal  agents : 

Benzoic  acid 

Calcium  undecylenate 

Diamthazole  hydrochloride 

Fuchsin,  basic 

p-Hydroxybenzoic  acid  esters : 

Butylparaben 

Ethylparaben 

Methylparaben 

Propylparaben 

Salicylanilide 

Sodium  eaprylate 

Sodium  undecylenate 

Undecylenic  acid 

Zinc  undecylenate 

Antiprotozoan  agents : 

Aklomide 

Amprolium 

Nitrophenide 

Pyrimethamine 

Antiviral  agent:  Amantadine  hydrochloride 

*Urinary  antiseptics : 

Ammonium  benzoate 

Calcium  mandelate 

Ethoxazene  hydrochloride 

Mandelic  acid 

Methenamine 

Methenamine  acetamidosalicylate 

Mathenamine  mandelate 

Methylene  blue 

Phenazopyridine  hydrochloride 

*A11  other: 

Acriflavine ^ 

Acriviolet 

Aminacrine 

Aminacrine  hydrochloride 

Antileprotic  and  antitubercular  agents : 

Aminosalicylic  acid 

Calcium  aminosalicylate 

Isoniazid 

Potassium  aminosalicylate 

Pyrazinamide 

Sodium  aminosalicylate 

Sodium  sulfoxone 

Benzalkonium  chloride 

Bromoform 

Camphor,  monobromated 

Cetalkonium  chloride 

Chloramine  T 

Chlorobutanol 

Iodoform 

Magnesium  salicylate 

Nalidixic  acid 

Nitromide 

Povidone  -  iodine  complex 

*Antineoplastic  agents  and  local  anesthetics : 
Antineoplastic  agents : 

Mercaptopurine 

Ure thane 

Vinblastine  sulfate 

Vincristine  sulfate 

Local  anesthetics : 

Butacaine  sulfate 

Butamben  picrate 

Butyl  aminobenzoate  (Butamben) 

Dibucaine 

Dibucaine  hydrochloride 


MON, 

PFZ. 

WTL. 

HOF. 

NAC. 

HN, 

ICO. 

HN. 

HN, 

ECO,    LEM,    PYL. 

HN, 

ICO,    LEM,    PYL. 

LEM. 

LEM, 

TNC. 

BAC. 

BAC. 

BAC, 

LEM,    TNC,    WTL. 

SAL. 

MRK. 

ACY. 

BUR. 

x. 

GAM, 

PEN. 

MAL. 

KON. 

MAL. 

HN. 

ABB. 

LEM, 

NEP,    PYL,    TNC 

ACY, 

NAC. 

HOF, 

KON,    NEP. 

NAC. 

NAC. 

SDW. 

SDW. 

MLS. 

MLS. 

RIL. 

MLS. 

MRK. 

MLS. 

ABB. 

SDH. 

DOW. 

MAL, 

PEN. 

FIN, 

SDW. 

MON. 

BPC, 

PD. 

MAL, 

PEN. 

MAL. 

SDH, 

SDW. 

SAL. 

C-. 

BUR. 

BKL, 

FMP. 

LIL. 

LIL. 

ABB. 

ABB. 

ABB, 

ICO. 

CBP. 

CBP. 

SYNIHkllC  ORGANIC  CHEMICALS,  1965 


TABLE  13B.  —Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported   identified  bv 

manufacturer,  1 965— Continued 


"Antineoplastic  agents  and  local  anesthetics— Continued 
Local  anesthetics — Continued 

Ethyl  aminobenzoate   (Benzocaine) 

Isobutyl  aminohenzoate 

Lidocaine 

Oxethazaine 

Phenacaine  hydrochloride 

Piperocaine  hydrochloride 

Pramoxine  hydrochloride 

Procaine 

Procaine  hydrochloride 

Proparacaine  hydrochloride 

Propyl  aminohenzoate 

Pyrrocaine  hydrochloride 

Tetracaine 

Tetracaine  hydrochloride 

"Autonomic  drugs : 

Ganglionic  blocking  agent:  Tetraethylammonium  chloride— 
Parasympatholytic  (anticholinergic)  agents: 
"Quaternary  ammonium  compounds  (except  tropane 
derivatives) : 

Ambutonium  bromide 

Diphemanil  methylsulfate 

Hexocyclium  methylsulfate 

Isopropamide  iodide 

Mepenzolate  bromide 

Methantheline  bromide 

Pipenzolate  bromide 

Pralidoxime  chloride 

Propantheline  bromide 

Thihexinol  methylbromide 

Tridihexethyl  iodide • 

"Tertiary  amines  (except  tropane  derivatives): 

Adiphenine  hydrochloride 

Caramiphen  edisylate 

Cycrimine  hydrochloride 

Dicyclomine  hydrochloride 

Ethopropazine 

Orphenadrine  citrate 

Orphenadrine  hydrochloride 

Oxyphencyclimine  hydrochloride 

Piperidolate  hydrochloride 

Thiphenamil  hydrochloride 

Trihexyphenidyl  hydrochloride 

Tropane  derivatives : 

Anisotropine  methylbromide 

Benztropine  mesylate 

Homatropine 

Homatropine  hydrobromide 

Homatropine  methylbromide 

Parasympathomimetic  (cholinergic)  agents: 

Acetylcholine  chloride 

Methacholine  chloride 

Neostigmine  bromide 

Physostigmine  salicylate ; 

Pyridostigmine  bromide 

Sympatholytic  (antiadrenergic)  agents: 

Ergonovine  maleate 

Hydralazine  hydrochloride 

Tolazoline  hydrochloride 

"Sympathomimetic  (adrenergic)  agents: 

Adrenalone 

Arterenol  hydrochloride  (racemic) 

Cinnamylephedrine 

Cyclopentamine  hydrochloride 

"Epinephrine  salts : 

Epinephrine  bitartrate  (levo) 

Epinephrine  hydrochloride  (racemic) 

"Isoproterenol  salts : 

Isoproterenol  hydrochloride 

Isoproterenol  sulfate 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


ABB,  LEM. 

ICO. 

AST,  LEM. 

WYT. 

CAN,  SDW. 

LIL. 

ABB. 

ABB. 

ABB,  LEM. 

QMS. 

ICO. 

EN. 

SDW. 

ICO,  SDW. 


ICO. 

SCH. 

ABB. 

SK. 

LKL. 

SRL. 

LKL. 

NEP. 

SRL. 

SCH. 

ACY. 

CBP. 

SK. 

LIL. 

BKC. 

NEP. 

RIK. 

RIK. 

PFZ. 

LKL. 

x. 

ACY,  SDW. 


CTN,  HEX. 

CTN. 

CTN,  EN,  HEX. 

MRK. 

MRK,  RSA. 
HEX. 
PEN. 
HOF. 

LIL. 
CBP. 

CTN. 

SDW. 
SDW. 
SDW. 
LIL. 

SDW. 
DOD,  VB. 

GAN,  SDW. 
ABB,  GAN,  SDW. 


MEDICINAL  CHEMICALS 


121 


TABLE  13B — Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i565--Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


"Autonomic  drugs — Continued 

"Sympathomimetic  (adrenergic)   agents — Continued 

Levarterenol  bi tartrate 

dl-Metanephrine  hydrochloride 

Metaraminol  bitartrate 

Methoxyphenamine  hydrochloride 

Naphazoline  hydrochloride 

dl-Nonnetanephrine  hydrochloride 

Nylidrin  hydrochloride 

"Phenylephrine  base  and  salts : 

Phenylephrine 

Phenylephrine  bitartrate 

"Phenylephrine  hydrochloride 

Phenylephrine  tannate 

"Phenylpropanolamine  hydrochloride 

Propylhexedrine 

Protokylol  hydrochloride 

Pseudoephedrine  hydrochloride 

Pseudoephedrine  sulfate 

Tetrahydrozoline  hydrochloride 

"Cardiovascular  agents : 
Antihypertensive  agents : 

Alkavervir 

Alseroxylon 

Deserpidine 

Methyldopa 

Pargyline  hydrochloride 

Reserpine 

Bioflavonoids : 

Hesperidin 

Hesperidin  methyl  chalcone 

Lemon  bioflavonoid 

Naringin 

Rutin 

Cardiac  drugs: 

Calcium  camphor sulfonate 

Digi toxin 

Procainamide  hydrochloride 

Quinidine  gluconate 

"Vasodilators : 

Clonitrate 

Dioxyline  phosphate 

Ethyl  nitrite 

Isosorbide  dinitrate 

Mannitol  hexanitrate 

Nicotinyl  alcohol  tartrate 

Nitroglycerin 

Pentaerythritol  tetranitrate 

"Central  depressants : 

"Analgesics  and  antipyretics: 
"Salicylates : 

Aluminum  aspirin 

"Aspirin 

Ethyl  salicylate  carbonate 

Phenyl  salicylate 

Potassium  salicylate 

Salicylamide 

Salicylsalicylic  acid 

Sodium  salicylate 

Strontium  salicylate 

"Other  analgesics  and  antipyretics : 

Acetaminophen 

Acetanilide 

p-Aminobenzoic  acid  and  salts: 

Aminobenzoic  acid 

Calcium  aminobenzoate 

Magnesium  aminobenzoate 

Potassium  aminobenzoate 

Sodium  aminobenzoate 

Anileridine  hydrochloride 

Calcium  succinate 

Colchicine 


SDW. 

SDW. 

SDW. 

X. 

CBP,    SDW. 

SDW. 

X. 

CTN,    GAN, 

SDW. 

GAN. 

CTN,    GAN, 

HEX, 

SDW. 

CTN. 

BKL,    GAM, 

GAN, 

ICO,    NEP,    ORT 

HEX,    SK. 

LKL. 

BUR,    GAN. 

GAN. 

PFZ. 

PEN,    RIK. 

RIK. 

PEN. 

MRK. 

ABB. 

PEN. 

SKG. 

SKG. 

SKG. 

SKG. 

PEN. 

FIN,    PYL. 

BUR. 

OMS. 

HEX. 

APD. 

LIL. 

MAL. 

APD. 

APD. 

HOF. 

APD. 

APD. 

ABB,    SCH. 

CFC,    DOW, 

MLS, 

MON,    NOR,    SDG. 

PD. 

DOW,   MAL. 

HN,    PEN. 

CFC,   x. 

TNC. 

DOW,    HN. 

MAL,    TNC. 

ATP,   MLS, 

NEP, 

X. 

CTN. 

LEM. 

LEM,   x. 

LEM. 

GAN,    LEM. 

GAN,    LEM. 

MRK. 

LEM. 

PEN. 

122 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  13B. 


-Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


Manuf aoturers '  identification  codes 
(according  to  list  in  table  22) 


^Central  depressants — Continued 
^Analgesics  and  antipyretics — Continued 

Other  analgesics  and  antipyretics — Continued 

Dipyrone 

Ethoheptazine  citrate 

Meperidine  hydrochloride 

Oxycodone  hydrochloride 

Oxymorphone  hydrochloride 

Oxyphenbutazone 

Phenacetin 

Phenylbutazone 

1-Phenylsemicarbazide 

Phenyramidol  hydrochloride 

Propoxyphene  hydrochloride 

Propoxyphene  napsylate 

* Anticonvulsants ,  hypnotics,  and  sedatives: 
Anticonvulsants  (except  barbiturates) : 

Aminoglutethimide 

Diphenylhydantoin 

Diphenylhydantoin,  sodium 

Ethosuximide 

Ethotoin 

Methsuximide 

Paramethadione 

Phenacemide 

Phensuximide 

Trimethadione 

*Barbiturates : 

5-Allyl-5-(2-cyclopenten-l-yl)barbituric  acid 

Amobarbital 

Amobarbital,  sodium 

Barbital 

Barbital,  sodium 

*Butabarbital 

*Butabarbital,  sodium 

Butalbital 

Butalbital,  sodium 

Cyclobarbital,  calcium 

Hexobarbital 

Mephobarbital 

Methohexital,  sodium 

Pentobarbital 

Pentobarbital,  sodium 

Phenobarbital 

*Phenobarbital,  sodium 

Secobarbital 

Secobarbital,  sodium 

Talbutal 

Thiamylal,  sodium 

Thiopental,  sodium 

Vinbarbital 

Hypnotics  and  sedatives  (except  barbiturates): 

Acetylcarbromal 

Carbromal 

Ethchlorvynol 

Ethinamate 

Glutethimide 

Methyprylon 

*Skeletal  muscle  relaxants : 

Carisoprodol 

Chlorphenesin  carbamate 

Chlorzoxazone 

*Mephenesin 

Mephenesin  carbamate 

Phenaglycodol 

Styramate 

*Succinylcholine  chloride 

Tubocurarine 

^Tranquilizers : 

Azacyclonol  hydrochloride 

Buclizine  hydrochloride 

Chlordiazepoxide  hydrochloride 


SDW. 

WYT. 

SDW, 

EN. 

EN. 

GGY. 

DOW, 

GGY. 

RSA. 

OTC. 

LIL. 

LIL. 


CBP. 
PD. 


ABB. 

PD. 

ABB. 


GAN. 

LIL. 

GAN, 

GAN. 

GAN. 

ABB, 

ABB, 

GAN. 

GAN. 

SDW. 

GAN, 

SDW. 

LIL. 

ABB, 

ABB, 

BPC, 

BPC, 

GAN. 

GAN, 

SDW. 

PD. 

ABB. 


MLS. 
MLS, 
ABB. 
LIL. 
CBP. 
HOF. 


UPJ. 
OTC. 
BKL, 
OMS. 
LIL. 
AEP. 
ABB, 
ABB, 

BKC. 
PFZ. 
HOF. 


BPC,  GAN. 
BPC,  GAN. 


BPC,  GAN. 
BPC,  GAN. 
GAN,  MAL. 
GAN,  MAL,  SDW. 

LIL. 


HEX,  OMS. 


BUR,  SDW. 
OMS. 


MEDICINAL  CHEMICALS 


123 


TABLE  13B. 


-Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1 965-  -Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


♦Central  depressants — Continued 
♦Tranquilizers — Continued 

Chlormezanone 

Chlorprothixene 

Diazepam 

Ethoxybutamoxane  hydrochloride 

Hydroxyphenamate 

Hydroxyzine  hydrochloride 

Hydroxyzine  pamoate 

Mebutamate 

Mephenoxalone 

♦Meprobamate 

Methaqualone 

Oxazepam 

*Phenothiazine  derivatives : 

Carphenazine  maleate 

Chlorpromazine  hydrochloride 

Fluphenazine  hydrochloride 

Mepazine  hydrochloride 

Perphenazine 

Prochlorperazine  maleate 

Promazine  hydrochloride 

Promethazine  hydrochloride 

Trifluoperazine  hydrochloride 

Triflupromazine  hydrochloride 

Tybamate 

*Other  central  depressants : 
Anesthetics : 

Tribromoethanol 

Vinyl  ether 

Antitussives: 

Benzonatate 

Carbetapentane  citrate 

Dextromethorphan  hydrobromide 

Dimethoxanate  hydrochloride 

*Ethylmorphine  hydrochloride 

Hydrocodone  bitartrate 

♦Central  stimulants : 
* Amphetamines : 

♦Amphetamine,  dextroamphetamine  and  levamphetamine 
base  and  salts : 

Amphetamine  (racemic) 

Amphetamine  hydrochloride  (racemic) 

Amphetamine  sulfate  (racemic) 

Dextroamphetamine 

Dextroamphetamine  carboxymethylcellulose 

Dextroamphetamine  hydrochloride 

♦Dextroamphetamine  sulfate 

Dextroamphetamine  tannate 

Levamphetamine  succinate 

♦Methamphetamine  base  and  hydrochloride: 

Methamphetamine  (dextro) 

Methamphetamine  (levo) 

♦Methamphetamine  (racemic) 

♦Methamphetamine  hydrochloride  (dextro) 

Methamphetamine  hydrochloride  (racemic) 

♦Antidepressants : 

Amitriptyline 

Desipramine  hydrochloride 

Isocarboxazid 

Nialamide 

Nortriptyline 

Phenelzine  sulfate 

♦Caffeine : 

Natural 

Synthetic 

♦Other  central  stimulants: 

Benzphetamine  hydrochloride 

Caffeine,  citrated 

Caffeine  sodium  benzoate 

Chlorphentermine  hydrochloride 

Diethylpropion  hydrochloride 


SDW. 

HOF. 

HOF. 

LIL. 

ARP. 

PFZ. 

PFZ. 

x. 

ACY. 

ABB,  BKL,  PEN,  TBK. 

HEX,  x. 

WYT. 

WYT. 

SK. 

0M3,  SCH. 

NEP. 

SCH. 

SK. 

WYT. 

WYT. 

SK. 

CMS. 

PEN,  x. 


SDW. 
MRK. 

CBP. 
PFZ. 
HOF. 
x. 

MAL,  MRK,  PEN. 
EN,  MAL,  MRK. 


HEX, 

ORT. 

HEX. 

AM, 

HEX, 

SK. 

HEX. 

ARN. 

ARN, 

HEX. 

ARN, 

HEX, 

SK. 

ARN. 

ARN. 

HEX. 

ABB. 

ARN, 

HEX, 

OTC. 

ABB, 

ARN, 

GAN,   HEX 

ARN, 

CAN, 

HEX. 

MRK. 

GGY, 

LKL. 

HOF. 

PFZ. 

LIL. 

NEP. 

GNF, 

MYW. 

MON, 

PFZ. 

x. 

MAL, 

MRK. 

MAL. 

NEP. 

BKC, 

x. 

124 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  13B.  — Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer ,  1965 — Continued 


Manuf aeturers '  identification  codes 
(according  to  list  in  table  22) 


*Central  stimulants — Continued 

"Other  central  stimulants — Continued 

Nikethamide 

Phendimetrazine  tartrate 

Phenmetrazine  hydrochloride 

Phentermine 

Sodium  succinate 

"Dermatological  agents : 

"Allantoin 

"Bismuth  subgallate 

*Salicylic  acid 

■"Other  dermatological  agents : 

Aluminum  phenolsulfonate 

Ammonium  phenolsulfonate 

Dipropylene  glycol  salicylate 

Glycol  salicylate 

Homomenthyl  salicylate 

p-Methoxycinnamie  acid,  2-ethoxyethyl  ester 

Podophyllum  resin 

Scarlet  red 

Sodium  phenolsulfonate 

Zinc  phenolsulfonate 

■"■Expectorants  and  mucolytic  agents: 

Ethylenediamine  dihydriodide 

Glyceryl  guaiacolate 

Guaiacol 

Iodinated  glycerol 

Lobeline  sulfate 

Terpin  hydrate 

Thonzonium  bromide 

"Gastrointestinal  agents : 

"Choleretics  and  hydrocholeretics : 

Bile  acids,  oxidized 

Dehydrocholic  acid 

Florantyrone 

Iron  bile  salts 

Qx  bile  extract 

Sodium  dehydrocholate 

Tocamphyl 

"Choline  chloride  (all  grades): 

Feed  grade 

Medicinal  grade 

Technical  grade 

"Methionine  and  its  hydroxy  analogue : 

Methionine  (feed  grade) 

Methionine  (medicinal  grade) 

Methionine,  hydroxy  analogue,  calcium  salt-- 
"Other  gastrointestinal  agents : 

Betaine  base 

Betaine  hydrate 

Betaine  hydrochloride 

Calcium  polycarbophil 

Choline  bicarbonate 

Choline  bi tartrate 

Choline  citrate  (Tricholine  citrate) 

Choline  dihydrogen  citrate 

Dihydroxy  aluminum  aminoacetate 

Magnesium  citrate 

Pectin 

Phenolphthalein 

Phenolphthalein,  yellow 

Sitosterols 

Sodium  carboxymethylcellulose 

Sodium  tartrate 

"Hormones  and  synthetic  substitutes : 
"Corticosteroids : 

Betamethasone 

Betamethasone  acetate 

Betamethasone  phosphate 

Cortisone 

Cortisone  acetate 

Dexamethasone 


GGY. 

HEX. 

MAL. 

CTN, 

FIN,    HFT. 

BKC, 

MAL,    PEN. 

DOW, 

HN,  M)N,    SDH. 

MAL. 

SAL. 

SBC. 

RDA. 

ICO. 

GIV. 

ABB, 

PEN. 

NAC. 

MAL, 

SAL. 

MAL. 

BKC, 

PYL,    WHL. 

BKL, 

GAM,    ICO,    OTC,   x 

HN, 

M)N. 

X,    X 

ABB. 

LEM, 

PEN. 

NEP. 

SRL, 

WIL. 

WIL. 

SRL. 

LIL. 

COM, 

DLI, 

HFT,    TMH 

CFC, 

HFT. 

G,    RH. 

DOW. 

DOW, 

LEM. 

DUP, 

MON. 

HFT, 

MAL. 

HFT. 

HFT. 

WLI. 

COM. 

ACY, 

CFC, 

HFT. 

ACY, 

CFC, 

HFT. 

ACY, 

CFC, 

HFT. 

CHT. 

MAL. 

SKG- 

MON. 

WLI. 

UPJ. 

CBP. 

MAL. 

SCH. 

SCH. 

SCH. 

MRK. 

MRK, 

SCH, 

UPJ. 

MRK, 

SCH. 

MEDICINAL  CHEMICALS 


125 


TABLE  13B. — Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 — Continued 


Hormones  and  synthetic  substitutes — Continued 
* Corticosteroids — Continued 

Dexamethasone  acetate 

Dexamethasone  phosphate 

Dichlorisone  acetate 

Fludrocortisone  acetate 

Fluorometholone 

Fluprednisolone 

Hydrocortamate  hydrochloride 

^Hydrocortisone 

Hydrocortisone  acetate 

Hydrocortisone  phosphate 

Indomethacin 

Methylprednisolone 

Prednisolone 

Prednisolone  acetate 

Prednisone 

Triamcinolone 

*Estr:>gens: 

ChLorotrianisene 

Dienestrol  diacetate 

Diethylstilbestrol 

Natural  estrogenic  substances 

Piperazine  estrone  sulfate 

*Synthetic  hypoglycemic  agents : 

Aeetohexamide 

Chlorpropamide 

Phenformin  hydrochloride 

Tolazamide 

Tolbutamide 

«Othef  hormones  and  synthetic  substitutes: 
Androgens : 

Fluoxymesterone 

Testosterone  cypionate 

Antithyroid  agents : 

Jfetliimazole 

Propylthiouracil 

Thiouracil 

Progestogens : 

Medroxyprogesterone  acetate 

Norethynodrel 

Progesterone 

All  other: 

Corticotropin  (ACTH)  (pituitary) 

Insulin  (pancreas) 

*Renal-acting  and  edema-reducing  agents : 
*Mercurial  diuretics: 

Meralluride 

Mersalyl  acid 

Sodium  mercaptomerin 

Sodium  mercurophylline 

^Theobromine  and  theophylline  derivatives : 

Ambuphylline 

*Aminophylline 

Aminophylline  sodium  biphosphate 

Oxtriphylline 

Theobromine  sodium  salicylate 

Theophylline  magnesium 

Theophylline  monoethanolamine 

Theophylline  sodium  acetate 

*Other  renal-acting  and  edema-reducing  agents : 

Acetazolamide 

Benzothiadiazine  derivatives : 

Bendroflumethiazide 

Benzthiazide 

Chlorothiazide 

Cyclothiazide 

Flumethiazide 

Hydrochlorothiazide 

Hydroflumethiazide 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


SCH. 
MRK. 
SCH. 
UP  J. 
UP  J. 
UP  J. 
PFZ. 
MRK, 
MRK, 
MRK. 
MRK. 
UPJ. 
MRK, 
SCH, 
MRK, 
ACY, 

BKC. 
SCH. 
CTN, 
ORG. 
ABB. 

LIL. 
PEZ. 


HST,  x. 


PFZ,  UPJ. 
PFZ,  UPJ. 


SCH,  UPJ. 
UPJ. 

SCH,  UPJ. 
OMS. 


UPJ. 
UPJ. 

LIL. 
PYL. 
ACY. 


ARP, 
ARP, 


LKL. 
SDW. 
WYT. 
FIN. 

GAN. 
GAN, 
GAN. 
NEP. 
CLC. 
MAL. 
LIL. 
MAL. 

ACY. 

OMS. 
PFZ. 
MRK. 
LIL. 
OMS. 
ABB, 
OMS. 


ORG,  WIL. 
LIL. 


LEM,  SRL. 


CBP,  MRK. 


126 


SYNTHETIC  ORGANIC  CHEMICALS.  1965 


TABLE  13B. 


-Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


*Renal-acting  and  edema-reducing  agents — Continued 

*Other  renal-acting  and  edema-reducing  agents — Continued 
Benzothiadiazine  derivatives — Continued 

Polythiazide 

Trichlorme thiazide 

Chlorthalidone 

Dichlorphenamide 

Probenecid 

Spironolactone 

Triamterene 

*Therapeutic  nutrients : 
*Amino  acids  and  salts : 

Acetyltryptophane 

Aminoacetic  acid  (glycine) 

Amino  acid  mixtures 

Arginine  glutamate 

Aspartic  acid  and  salts : 

Aspartic  acid 

Magnesium  aspartate 

Potassium  aspartate 

Beta-alanine 

Glutamic  acid  and  salts : 

Ammonium  glutamate 

Calcium  gluxamate 

^Glutamic  acid 

Glutamic  acid  hydrochloride 

Potassium  glutamate 

lysine  (feed  grade) 

lysine  hydrochloride 

dl- Phenylalanine 

dl- Tryptophane 

*Caleium  gluconate 

«Other  therapeutic  nutrients : 

Calcium  glucoheptonate 

Calcium  lactophosphate 

Calcium  levulinate 

Calcium  phytate 

Copper  gluconate 

Ferrous  gluconate 

Fructose 

Lecithin 

Liver  concentrate 

Liver,  desiccated 

Magnesium  gluconate 

Manganese  gluconate 

Potassium  gluconate 

Sodium  glycerophosphate 

*Vitamins : 

*Ascorbic  acid  and  derivatives : 

* Ascorbic  acid 

Ascorbyl  palmitate 

Calcium  ascorbate 

Sodium  ascorbate 

B-complex  vitamins : 
*Cyanocobalamin  (all  grades): 

Feed  grade 

Medicinal  grade 

U.S. P.  crystalline 

*Niacin  (all  grades): 

Feed  grade 

Medicinal  grade 

^Niacinamide 

*Pantothenic  acid  and  derivatives: 

Calcium  pantothenate  (dextro) 

*Calcium  pantothenate  (racemic)  (all  grades): 

Feed  grade 

Medicinal  grade 

Calcium  pantothenate  (racemic)  -  calcium  chloride 

complex. 
Dexpanthenol 


PFZ. 

SCH. 

GGY. 
MRK. 

MRK. 
SRL. 

SK. 

SDW. 

BPC, 

DOW. 

ABB, 

CUT, 

STA. 

ABB. 

HEX, 

NAC. 

WIT. 

WYT. 

BFG, 

NOP. 

IMC. 

LEM. 

IMC, 

LEM, 

PFZ. 

IMC, 

LEM. 

IMC, 

LEM, 

PFZ. 

MRK. 

MRK. 

SDW. 

SDW. 

MAL, 

PFZ, 

WHL. 

PFN. 

MAL. 

SEL. 

STA. 

PFZ. 

PFZ, 

SDW. 

DLL 

ARP. 

WIL. 

WIL. 

PFZ. 

PFZ. 

PFZ. 

SEL. 

HOF, 

MRK, 

PFZ. 

PFZ. 

PFZ. 

HOF, 

MRK, 

PFZ. 

GPR, 

MRK, 

PMP. 

IMC, 

MRK. 

MRK. 

ABB, 

CKL, 

MRK,    NEP,    RIL 

MRK, 

NOP, 

RIL,   SCR. 

MRK, 

NEP, 

PD,    RIL,    SCR. 

DLI,  MRK,  x. 

CKL,  FLM,  HFT,  NOP. 

NOP. 

NOP. 


MEDICINAL  CHEMICALS 


127 


TABLE  13B.  —Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 — Continued 


*Vitamins — Continued 

B-ooraplex  vitamins — Continued 
•Pantothenic  acid  and  derivatives — Continued 

Panthenol  (racemic) 

Sodium  pantothenate 

*Ribof lavin  ( all  grades ) : 

Feed  grade 

Medicinal  grade 

•Cholecalciferol  (Vitamin  D3) 

•Ergocalciferol  (Vitamin  D2) 

*Menadione 

•Menadione  sodium  bisulfite 

•Vitamin  A  alcohol  and  esters : 

Vitamin  A  acetate  (feed  grade) 

Vitamin  A  acetate  (medicinal  grade) 

Vitamin  A  alcohol 

Vitamin  A  natural  esters 

•Vitamin  A  palmitate  (feed  grade) 

Vitamin  A  palmitate  (medicinal  grade) 

Other  vitamins : 

d-Alpha  tocopherol 

dl-Alpha  tocopherol 

d-Alpha  tocopheryl  acetate 

dl-Alpha  tocopheryl  acetate 

d-Alpha  tocopheryl  acid  succinate 

Beta-carotene  (Provitamin  A) 

Biotin 

Cyanocobalamin  with  intrinsic  factor  concentrate- 

Folic  acid 

Inositol 

Magnesium  nicotinate 

Niacinamide  hydrochloride 

Phytonadione 

Pyridoxine 

Riboflavin-5-phosphate,  sodium 

Sodium  nicotinate 

Thiamine  hydrochloride 

Thiamine  mononitrate 

•Miscellaneous  medicinal  chemicals : 
Diagnostic  agents : 

Roentgenographs  contrast  media: 

Acetrizoate,  sodium 

Diatrizoate,  meglumine 

Diatrizoate,  sodium 

Diprotrizoate,  sodium 

Iodihippurate,  sodium 

Iodopyracet 

Iopanoic  acid 

Iophendylate 

Iothalamate,  meglumine 

Iothalamate,  sodium 

Methiodal,  sodium 

Other  diagnostic  agents : 

Galactose  (liver  function  test) 

Indocyanine  green  (cardiac  output  test) 

Metyrapone  (pituitary  function  test) 

Hematological  agents: 
•Anticoagulants : 

Ammonium  heparin 

Anisindione 

Bishydroxycoumarin 

Phenindione 

Potassium  heparin 

Sodium  heparin 

Sodium  warfarin 

Other  hematological  agents : 

Aminocaproic  acid 

Cellulose,  oxidized 

Dextran  (plasma  expander) 

Smooth  muscle  relaxants : 

Alverine 

Alverine  citrate 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


HOF. 
PD. 

COM,  GPR,  HOF,  MRK,  PMP. 

HOF,  MRK. 

CW,  DLI,  NOP,  VTM. 

CW,  DLI,  SCR,  VTM. 

ABB,  HET,  HFT,  WHL. 

ABB,  HET,  HFT,  WHL. 

HOF. 

CW,  HOF,  PFZ. 

CW,  HOF. 

CW. 

EK,  HOF,  PFZ. 

EK,  HOF,  PFZ. 

CW,  EK. 

HOF. 

CW,  EK. 

HOF. 

CW,  EK,  HOF. 

HOF. 

HOF. 

WIL. 

ACT. 

STA. 

NEP. 

NEP. 

MRK. 

HOF,  MRK. 

HOF. 

MRK,  NEP. 

HOF,  MRK. 

HOF,  MRK. 


MAL. 

SDW. 

SDW. 

MAL. 

MAL. 

SDW. 

SDW. 

x. 

MAL. 

MAL. 

SDW. 


WIL. 

SCH. 

ABB,  FIN. 

CTN,  GAN,  WIL. 

WIL. 

ABB,  RIK. 

EN. 

ACT. 
EKT. 
PHR. 

CTN. 
CTN. 


128 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  13B.—  Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer ,  1965 — Continued 


Chemical 

Manufacturers '  identification  codes 
(according  to  list  in  table  22) 

^Miscellaneous  medicinal  chemicals—Continued 
anooth  muscle  relaxants — Continued 

era. 

LIL. 

ICO. 
ABB,  PEN. 

Other  miscellaneous  medicinal  chemicals : 

PEN. 

ttydrastme  hydrocnior  de 

FLAVOR  AND  PERFUME  MATERIALS 


129 


Flavor  and  Perfume  Materials 

TABLE  14B.  — Flavor  and  perfume  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 

[  Flavor  and  perfume  materials  for  which  separate  statistics  are  given  in  table  14A  are  marked  below  with  an  asterisk 
(*);   those  not  so  marked  do  not  appear  in  table  14A  because  the  reported  data  are  accepted  in  confidence  and  may 
not  be  published.  Manufacturers'   identification  codes  shown  below  are  taken  from  table  22.  An  x  signifies  that  the 
manufacturer  did  not  consent  to  his  identification  with  the  designated  product] 


Material 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


FLAVOR  AND  PERFUME  MATERIALS,  CYCLIC 

Benzenoid  and  Naphthalenoid 

2 '-Acetonaphthone  (Methyl  fi-naphthyl  ketone) 

Aeetophenone 

7-Acetyl-6-ethyl-l,l,4,4-tetramethyl-l,2,3,4-tetrahydro- 
naphthalene . 

p-Allylanisole 

Allyl  phenoxyacetate 

*4-Allylveratrole  (Eugenyl  methyl  ether) 

p-tert-Amylcyclohexanone 

*Anethole  (p-Propenylanisole) 

p-Anisaldehyde  (p-Methoxybenzaldehyde) ■ 

Anisole  (Methyl  phenyl  ether) 

Anisyl  acetate 

Anisyl  alcohol 

*Benzophenone 

*Benzyl  acetate 

*Benzyl  alcohol 

Benzyl  behzoate 

Benzyl  butyrate 

*Benzyl  cinnamate 

Benzyl  ether 

Benzyl  formate 

Benzyl  glyceryl  acetal 

Benzyl  isobutyrate 

Benzyl  isoeugenyl  ether 

Benzyl  isopentyl  ether 

Benzyl  phenylacetate  (Benzyl  a-toluate) 

*Benzyl  propionate 

*Benzyl  salicylate 

a -Bromostyrene 

4' -tert-Butyl-2 ', 6' -dimethyl-3 ' , 5 '-dinitroacetophenone 

(Musk  ketone ) . 
6-tert-Butyl-3-methyl-2,4-dinitroanisole  (Musk  ambrette)-- 
p-tert -Butyl-a -methylhydrocinnamaldehyde  ( a-Methyl-f! -  ( p- 

tert -butylpheny 1 ) propionaldehyde ) . 
5-tert-Butyl-l,2,3-trimethyl-4.,6-dinitrobenzene  (5-tert- 
Butyl-4, 6-dinitrohemi mellitene ) . 

5-tert-Butyl-2,4,6-trinitro-m-xylene  (Musk  xylol) 

Carvacrol  (2-p-Cymenol) 

*Cinnamaldehyde 

Cinnamic  acid 

Cinnamyl  acetate 

*Cinnamyl  alcohol 

Cinnamyl  anthranilate 

Cinnamyl  cinnamate 

Cinnamyl  formate 

Cinnamyl  isovalerate 

Cinnamyl  propionate 

trans-Decahydro-2-naphthol 

p ,<*  -Dimethylbenzyl  alcohol  (p-Methylphenylmethylcarbinol)- 

ajx -Dimethylphenethyl  acetate 

<x,a  -Dimethylphenethyl  alcohol 

ccyx  -Dimethyl  -3-phenyl-l-propanol 

4,6-Dinitro-l,l,3,3,5-pentamethylindan 

Diphenylmethane 

l,3-Diphenyl-2-propanone  (Dibenzyl  ketone) 

l-Ethoxy-2-hydroxy-4-propenylbenzene 

2-Ethoxynaphthalene  (Ethyl  p-naphthyl  ether) 

Ethyl  anisate 

Ethyl  anthranilate 

Ethyl  benzoate 


FB,  GIV,  TBK. 
GIV,  TBK. 
GIV. 

GIV. 

GIV. 

FB,  GIV,  ICO. 

IFF. 

ARZ,  GLD,  HNW,  HPC. 

GIV,  OPC,  SHL,  TBK,  UNG. 

GIV. 

GIV,  TBK. 

GIV,  TBK. 

G,  GIV,  ICO,  NEO,  TBK. 

GIV,  OPC,  SHL,  TBK,  TNP. 

BPC,  GIV,  OPC,  SHL,  TBK,  TNP. 

MON,  TBK,  TNP. 

FB,  GIV,  TBK. 

FB,  GIV,  ICO,  TBK. 

OPC,  SHL,  TNP. 

TBK. 

GIV. 

TBK. 

GIV,  TBK. 

GIV. 

GIV,  TBK. 

FB,  GIV,  TBK. 

GIV,  ICO,  OPC,  TBK,  UNG. 

TBK. 

GIV,  TBK. 

GIV. 
GIV. 

GIV. 

GIV. 

GIV. 

FB,  OPC,  TBK. 

BPC,  ICC. 

FB,  GIV,  TBK. 

FB,  GIV,  NEO,  TBK. 

FEL,  GIV,  RT. 

TBK. 

TBK. 

TBK. 

GIV,  TBK. 

IFF. 

GIV,  TBK. 

GIV,  IFF. 

GIV,  IFF. 

IFF. 

GIV. 

TBK. 

GIV,  TBK. 

SHL. 

GIV. 

ICO. 

FB. 

TBK. 


130 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  14B. 


-Flavor  and  perfume  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1 965-  -Continued 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


FLAVOR  AND  PERFUME  MATERIALS,  CYCLIC--Continued 


Pen 


id  and  haphthalenoid--Continued 


Ethyl  cinnamate 

Ethyl  a,|3-epoxy-(j-methylhydrocinnamate 

Ethyl  eugenol 

2-Ethylhexyl  salicylate 

Ethyl  phenylacetate 

Ethyl  3-phenylglycidate 

Ethyl  salicylate 

Ethylvanillin 

*Eugenol 

Eugenol  acetate 

Hexylcinnamaldehyde 

Hydratropaldehyde  (x -Phenylpropionaldehyde ) 

Hydratropaldehyde,  dimethyl  acetal 

Hydrocinnamaldehyde  (p -Phenylpropionaldehyde) 

Hydroxycitronellal  methyl  anthranilate 

2-Hydroxypropyl  p -N , N -bis ( 2 -hydroxypropyl ) aminobenzoate • 

Isobutyl  cinnamate 

*Isobutyl  phenylacetate  (Isobutyl  a-toluate) 

*Isobutyl  salicylate 

*Isoeugenol 

Isoeugenyl  acetate 

*Isopentyl  salicylate  (Amyl  salicylate) 

p-Isopropylbenzaldehyde  ( Cumaldehyde ) 

p-Isopropylcyclohexanol 

*p-Isopropyl-a-methylhydrocinnamaldehyde  ( Cyclamen 
aldehyde ) . 

4' -Methoxyacetophenone 

2-Methoxynaphthalene  (Methyl  p -naphthyl  ether) 

4-(a-Methoxyphenyl)butanone 

l-(p-Methoxyphenyl)-l-pentene-3-one 

4'  -Methylacetophenone  (Methyl  p-tolyl  ketone) 

Methyl  anisate 

p-Methylanisole  (p-Cresyl  methyl  ether) 

*Methyl  anthranilate 

Methyl  benzoate 

p-Methylbenzyl  acetate 

a-Methylbenzyl  acetate 

a-Methylbenzyl  alcohol  (Methylphenyl  carbinol) 

*a-Methylcinnamaldehyde 

*Methyl  cinnamate 

4-Methyl-7-ethoxy  coumarin 

p-Methyl  hydratropic  aldehyde 

Methyl  N-methylanthranilate  (Dimethyl  anthranilate) 

Methyl  phenylacetate  (Methyl  o-toluate) 

*Methyl  salicylate  (Synthetic  wintergreen  oil) 

*a-Pentylcinnamaldehyde   (a  -Amylcinnamaldehyde) 

*Phenethyl  acetate 

Phenethyl  alcohol 

Phenethyl  formate 

*Phenethyl  isobutyrate 

Phenethyl  isovalerate 

*Phenethyl  phenylacetate  (Phenethyl  a-toluate) 

Phenethyl  propionate 

Phenethyl  salicylate 

2-Phenoxyethyl  isobutyrate 

Phenylacetaldehyde  (a-Tolualdehyde) 

Phenylacetaldehyde,  dimethyl  acetal 

Phenylacetaldehyde,  ethylene  acetal 

o-Phenylanisole  (2-Methoxybiphenyl) 

4-Phenyl-3-buten-2-one 

Phenyl  ethyl  acetal 

Phenylethyl  tiglate 

*3-Phenyl-l-propanol  (Hydrocinnamic  alcohol) 

3-Phenyl-l-propyl  acetate 

5-Propenyl-2-ethoxyphenol  (Propenylguaethol) 

4- Propenylveratrole  (Isoeugenyl  methyl  ether) 

p-Propylanisole 


TBK. 
TBK. 


ICO. 
TBK. 


GIV, 

GIV, 

ICO. 

FEL, 

GIV. 

GIV, 

TBK. 

MON,  RDA. 

FB,  GIV,  ICO,  LUE,  NEO,  PEN,  RT,  TBK,  UNG,  VLY. 

GIV. 

GIV, 

GIV, 

GIV, 

GIV. 

GIV. 

SHL. 

TBK. 

FB, 

FB, 

GIV, 

TBK. 

FB, 

GIV. 

GIV. 

GIV, 


IFF,  TBK. 

IFF. 

IFF. 


GIV,  TBK. 
GIV,  TBK. 
SHL,  TBK,  VLY. 

GIV,  ICO,  OPC,  SHL,  TBK. 
OPC,  RDA. 


GIV,  ICO. 

GIV. 

TBK. 

GIV. 

TBK. 

ICO. 

GIV; 

FB, 

HN. 

ICO. 

FB,  GIV,  VLY. 

TBK. 

FB, 

FB, 

GIV, 

GIV, 

GIV. 

GIV. 

CFC 

FB, 

GIV. 

GIV. 

IFF 

GIV, 

FB, 

FB, 

GIV, 

NEO, 

GIV. 

GIVj 

GIV, 

GIV. 

GIV. 

FB. 

GIV. 

FB. 

FB, 

FB, 

ICO. 

GIV, 

GIV. 


OPC. 
GIV,  MEE,  OPC,  SHL,  UNG. 


GIV,  TBK,  VLY. 
ICO,  TBK. 


OPC, 
TBK, 
D0W; 

GIV, 
IFF. 
IFF, 
TBK. 
IFF, 

GIV. 

GIV, 

TBK. 
TBK. 
TBK. 
TBK. 


HN,  MON,  PEN. 
IFF,  NEO,  RDA,  TBK,  VLY. 
NEO. 
OPC. 

TBK. 

IFF,  TBK. 


GIV,  TBK. 
GIV. 


ICO,  TBK. 


FLAVOR  AND  PERFUME  MATERIALS 


131 


TABLE  14B.  --Flavor  and  perfume  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer ,  2965--Continued 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


FLAVOR  AND  PERFUME  MATERIALS,  CYCLIC— Continued 
Benzenoid  and  Naphthalenoid— Continued 

n-Propyl  phenethyl  acetal 

p-Tolualdehyde  (p-Methylbenzaldehyde) 

p-Tolyl  acetate  (p-Cresyl  acetate) 

p-Tolyl  phenylacetate  (p-Cresyl  a-toluate) 

a-(Trichloromethyl)benzyl  acetate  (Rosetone) 

Trimethyltetrahydrobenzylidene  acetone 

Vanillin 

All  other 

Terpenoid,   Heterocyclic,   and  Alicyclic 

Allyl  eyclohexyl  propionate 

Allyl  ionone 

Amyris  acetate 

Bornyl  acetate 

4-tert-Butyleyclohexanol 

4-tert-Butylcyclohexyl  acetate 

Cadinene 

Carvone  (Carvol) 

Caryophyllene 

Cedranone 

Cedrenol 

Cedrol 

*Cedryl  acetate 

*Citral  (Geranial) 

Citral  dimethyl  acetal 

Citronellal 

*Citronellol 

*Citronellyl  acetate 

Citronellyl  butyrate 

*Citronellyl  formate 

Citronellyl  isobutyrate 

Citronellyl  oxyacetaldehyde 

Citronellyl  propionate 

*Coumarin 

Cyclohexadecanolide 

Cyclohexylcyclohexanone : 

Cyclopentanone 

Dihydrogeraniol 

Dihydroterpinyl  acetate 

^Essential  oils,  chemically  modified: 

Citronella  oil,  acetylated 

Clove  leaf  oil  terpenes 

Ethyl  oxyhydrate 

Gualacwood  acetate 

Lavandin,  acetylated 

Oil  clove  stem,  acetylated 

Sassafras  oil,  hydrogenated 

Other 

a-Furfural  mercaptan 

*Geraniol 

Geranoxy  acetaldehyde 

*Geranyl  acetate 

Geranyl  benzoate 

Geranyl  butyrate 

Geranyl  formate 

Geranyl  isobutyrate 

Geranyl  isovalerate 

Geranyl  phenylacetate  (Geranyl  a-toluate) 

2-Hexyl-2-cyclopenten-l-one 

Hydrocoumarin  (3,4— Dihydrocoumarin) 

*Hydroxyeitronellal 

Hydroxycitronellal,  dimethyl  acetal 

4-(4-Hydroxy-4-methylpentyl)-3-eyelohexene-l-carboxalde- 

hyde. 
Indole 


GIV. 

HN. 

GIV,  IFF. 

GIV. 

ICO,  TBK. 

TBK. 

MON,  SLV. 

FB,  GIV,  IFF,  PFW,  FDA,  SHL. 


GIV. 

GIV, 

GIV, 

FEL. 

IFF. 

DOW, 

FB. 

FB, 

FB, 

TBK 

GIV 

GIV 

GIV 

FB, 

GIV 

FB, 

FB, 

GIV 

GIV 

FB, 

GIV, 

IFF. 

GIV, 

DOW, 

IFF. 

GIV. 

AHA. 

ICO. 

GIV. 

CP, 

SHL. 

FEL, 

FB, 

FEL. 

FB. 

GIV. 

BPC. 

RT. 

FB, 

IFF. 

FEL. 

GIV, 

GIV, 

GIVl 

IFF. 

FB. 

GIV. 

IFF. 

GIV. 

giv! 

GIV! 

iff! 


IFF. 
TBK. 


FRM,  OPC. 
GIV. 


IFF,  TBK. 

IFF,  NEO,  TBK,  UNG. 
FEL,  GIV,  LUE,  MYW,  NEO,  RT,  TBK. 

GIV,  IFF,  TBK. 

GIV,  GLD,  IFF,  NEO,  TBK,  VLY. 
IFF,  TBK,  VLY. 

GIV,  IFF,  TBK,  VLY. 
IFF,  TBK. 


i,   NEO,  RDA,  TBK. 


FLO,  LUE,  VND. 
GIV,  TBK. 
GIV,  UNG. 


FEL,  GIV,  GLD,  IFF,  NEO,  TBK,  UNG,  VLY. 
GIV,  IFF,  TBK,  VLY. 


TBK. 

IFF,  TBK,  VLY. 


ICO. 

GLD,  IFF,  OPC,  TBK,  VLY. 

OPC,  TBK. 


DOW,  GIV. 


132 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  14B.  --Flavor  and  perfume  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer ,  1 965  --Continued 


Material 


FLAVOR  AND  PERFUME  MATERIALS,   CYCLIC--Continued 
Terpenoid,   Heterocyclic,   and  Alicyclic--Continued 


*Ionones : 

a-Ionone 

(3-Ionone 

Ionone   (a-  andp-) 

Isoborneol  (Isobornyl  alcohol) 

*Isobornyl  acetate 

Isobutylquinoline 

Isomenthone 

Isopropylquinoline 

Isopulegol 

Isosafrole 

Laevo  carveol 

d-Limonene 

Llnalool 

Linalyl  acetate 

Linalyl  anthranllate 

Linalyl  isobutyrate 

Linalyl  propionate 

l,l-p-Menthen-6-yl-l-propanone 

*Menthol,   synthetic: 

Tech 

U.S.P 

Menthone 

Menthyl  acetate 

6-Methylcoumarin 

*Methylionones : 

Methyl-a-ionone 

Methyl-fJ-ionone 

Methylionone   (a-  and  fj-) 

Methyl-Y -ionone 

Methyl-5-ionone 

*Nerol 

Nerol,  acetate 

Nopyl  acetate 

Phellandrene 

*Piperonal  (Heliotropin) 

Piperonal,  sodium  bisulfite  complex 

Piperonal  terpenes 

Pseudolinalyl  acetate  (Myrcenyl  acetate,  principally) - 

*Rhodinol 

Rhodinyl  acetate 

Safrole 

Santalol 

Santalyl  acetate 

♦Sweeteners ,  synthetic : 

Cyclohexanesulfamic  acid 

Cyclohexanesulfamic  acid,  calcium  salt 

Cyclohexanesulfamic  acid,  sodium  salt 

Saccharin 

Saccharin,  calcium  salt 

Saccharin,  sodium  salt 

All  other 

*Terpineols: 

a-Terpineol 

P-Terpineol 

Terpineol  (a-  andg-) 

Terpinol  hydrate  (Terpin  hydrate ) ,  tech 

*Terpinyl  acetate 

Terpinyl  propionate 

Tetrahydro  alloocimenol 

3,5,5-Trimethylcyclohexanol 

Vertofix  (Acetyl  cedrene,  principally) 

Vetivenol 

*Vetivenyl  acetate 

All  other 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


GIV,  IFF,  LUE,  MYW,  TBK. 

MYW,  TBK. 

GIV,  LUE,  MYW,  NEO. 

RDA. 

FB,  GIV,  OPC,  RDA. 

IFF. 

FB,  GIV,  TBK. 

FMT. 

GIV,  TBK. 

GIV. 

FB. 

RT,  SKG. 

FB,  FEL,  GIV,  GLD,  HOF,  LUE,  NEO,  SHL,  TBK,  UNG. 

DOW,  FB,  GIV,  GLD,  HOF,  LUE,  SHL,  UNG. 

FMT. 

GIV,  TBK. 

FB,  GIV. 

GIV. 

GIV,  ICO,  NEO. 
GIV,  HNW,  NEO. 
GIV,  HNW,  NEO. 
FB,  GIV. 
GIV. 

GIV,  IFF,  MYW. 

IFF,  NEO. 

GIV,  LUE,  MYW,  VLY. 

TBK. 

TBK. 

FB,  GIV,  GLD,  IFF,  TBK,  VLY. 

FB,  GIV. 

MYW,  SHL,  TBK,  VLY. 

GIV,  ICO. 

GIV,  SHL,  TBK. 

SHL. 

SHL. 

IFF. 

FB,  FEL,  GIV,  IFF,  LUE,  NEO,  SHL. 

FB,  GIV,  IFF. 

GIV. 

GIV,  IFF. 

GIV. 

ABB,  NRS. 

ABB,  CYC,  DRW,  MDN,  NRS,  PBY,  PFZ,  UNS. 

ABB,  DRW,  MON,  NRS,  PBY,  PFZ,  UNS. 

MEE,  M3N,  NRS. 

MEE,  MON,  NRS,  PBY. 

MEE,  MON,  NRS. 

VLY. 

GLD,  HNW,  HPC. 

HNW. 

GIV,  NEO. 

HPC. 

GIV,  NEO,  OPC,  RDA,  TBK,  UNG. 

GIV,  TBK. 

IFF. 

ICO. 

IFF. 

GIV,  TBK. 

FB,  GIV,  IFF,  NEO,  TBK. 

FB,  GIV,  IFF,  OPC,  RDA,  TBK. 


FLAVOR  AND  PERFUME  MATERIALS  133 

TABLE  14B.  --  Flavor  and  perfume  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 — Continued 


FLAVOR  AND  PERFUME  MATERIALS,  ACYCLIC 

Acetyl  butyryl 

Acetyl  isovaleryl 

Acetyl  propionyl 

Allyl  heptanoate   (Allyl  enanthate) 

*Allyl  hexanoate   (Allyl  caproate) 

Allyl  isothiocyanate   (Synthetic  mustard  oil) 

Allyl  sulfide   (Diallyl  sulfide) 

Amyl  propionate 

Butyl  butyrate 

Butyl  isovalerate 

Butyroyl  butyl  lactate 

Decanal  ( Capraldehyde )    (C10) 

Diallyl  disulfide 

Diethyl  sebacate   (Ethyl  sebacate) 

Diethyl  succinate 

Diethyl  tridecanedioate   (Ethylene  brassylate) 

2,6-Dimethyl-5-hepten-l-al 

3,6-Dimethyl-3-oetanol 

3,7-Dimethyl-l-octanol 

3,7-Dimethyl-3-octanol 

Dimethyl  succinate 

Ethylamyl  ketone 

Ethyl  butyrate 

Ethyl  decanoate 

Ethylene  brassylate 

Ethyl  heptanoate  (Ethyl  enanthate) 

Ethyl  hexanoate  (Ethyl  caproate) 

Ethyl  isovalerate 

Ethyl  laurate 

Ethyl  levulinate 

*Ethyl  nonanoate  (Ethyl  pelargonate) 

Ethyl  octanoate  (Ethyl  caprylate) 

^Glutamic  acid,  monosodium  salt  (Monosodium  glutamate 

Heptanal  (Enanthaldehyde)  (C7) 

Heptyl  alcohol  (Heptanol) 

cis-3-Hexen-l-ol 

cis-3-Hexyn-l-ol 

3-Hydroxy-2-butanone  (Acetoin) 

4-Hydroxynonanoic  acid,  y-lactone  (y-Nonalactone) — 

4-Hydroxyoctanoic  acid,  y-lactone  (y -Octalactone ) 

4-Hydroxyundecanoic  acid,  y-lactone  (y -Undecalactone 

*Isopentyl  butyrate  (Amyl  butyrate) 

*Isopentyl  formate  (Amyl  formate) 

Isopentyl  heptanoate  (Amyl  caproate) 

Isopentyl  isovalerate  (Amyl  isovalerate) 

*Lauraldehyde  (Dodecyl  aldehyde)  (Ci2) 

6-Methyl-5-hepten-2-one 

Methyl  isovalerate- 

Methyl-p -methylthiopropionate 

Methyl -2-nonenoate 

Methylolmethylhexyl  ketone 

2-Methylundecanal  ( 2-Methylnonylacetaldehyde ) 

Myristic  aldehyde 

Nonanal  (Pelargonaldehyde)  (C9) 

Nonanediol  monoacetate 

Nonyl  acetate 

Nonynol  acetate,  isomeric  (Tepyl  acetate) 

Octanal  (Caprylaldehyde)  (Cb) 

n-Octyl  acetate 

n-Octyl  formate ■ 

n-Octyl  isobutyrate 

Omega  decenol 

2,6,10-Trimethyl-9-undeeen-l-ol 

Undecanal  (Hendecanaldehyde)  (Cn) 

2-Undecanone  (Methyl  nonyl  ketone) 

Undecenal  (Hendecenaldehyde) 

10-Undecen-l-ol 

Valerolactone 

All  other 


Manufacturers'  identific<.ion  codes 
(according  to  list  in  table  22) 


FB, 

rBK. 

DOW, 

FB, 

GIV,  UNG. 

ICO, 

MRT. 

RT. 

GIV. 

OPC, 

TBK. 

TBK. 

ICO. 

GIV, 

IFF, 

TBK. 

RT. 

FEL, 

TBK. 

ICO, 

TBK, 

UCC. 

RDA. 

GIV. 

cue. 

GIV, 

TBK. 

GIV. 

ICO. 

GIV. 

FB, 

NW,  RT,  TBK. 

TBK. 

VLY. 

FB, 

FEL, 

TBK. 

FB, 

NW. 

FB, 

TBK. 

FB, 

TBK. 

FMT. 

FB, 

FEL, 

GIV,  TBK. 

FB, 

TBK. 

COM, 

GRW 

ITC,  IMC,  MRK. 

BAC. 

BAC 

UCC 

X. 

X. 

FMT. 

GIV 

TBK 

GIV 

TBK 

FB, 

GIV. 

FB, 

GIV, 

NW,  RT,  TBK. 

FEL 

RT, 

TBK. 

FEL 

TBK 

FB, 

TBK. 

GIV 

IFF 

TBK. 

GIV. 

FB. 

RT. 

GIV 

GIV 

GIV 

TBK 

GIV 

GIV 

GIV 

TBK 

IFF 

GIV 

IFF 

FB, 

TBK. 

FB. 

FB, 

TBK. 

IFF 

GIV 

GIV 

IFF 

,  TBK. 

GIV 

GIV 

GIV 

GIV 

FB, 

GIV, 

IFF,  OPC,  RT,  SHL 

SYNTHETIC  ORGANIC  CHEMICALS,  1965 


Plastics  and  Resin  Materials 

TABLE  15B.—  plastics  and  resin  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer ,  1965 

[Plastics  and  resin  materials  for  which  separate  statistics  are  given  in  table  15A  are  marked  below  with  an  asterisk 
(*);  chemicals  not  so  marked  do  not  appear  in  table  15A  because  the  reported  data  are  accepted  in  confidence  and 
may  not  be  published.  Manufacturers'  identification  codes  shown  below  are  taken  from  table  22.  An  x  signifies 
that  the  manufacturer  did  not  consent  to  his  identification  with  the  designated  product] 


Material  and  use 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


THERMOSETTING  RESINS 


*Alkyd  resins: 

Protective  coatings: 
*Phthalic  anhydride  type- 


*Polybasic  acid  type 

*A11  other  uses 

*Coumarone-indene  and  petroleum  polymer  resins 

*Floor  tile 

*Rubber  compounding 

*A11  other  uses 

Epoxy  resins: 

Unmodified: 

^Bonding  and  adhesives 

^Protective  coatings 

^Reinforced  plastics 

*A11  other  uses 

*Modified 


*Polyester  resins: 

Reinforced  plastics: 
*Sheets,  flat  and  corrugated 

*A11  other 

^Surface  coatings 

*A11  other  uses 

Silicone  resins 

*Phenolic  and  other  tar  acid  resins 
^Molding  materials 

Bonding  and  adhesive  resins  for- 
*Laminating 

*Coated  and  bonded  abrasives  — 

*Friction  materials 

^Thermal  insulation 

^Foundry  or  shell  molding 

*Plywood 

*Fibrous  and  granulated  wood — 


AAI,  ACP,  ACY,  ADM,  APT,  APV,  BAL,  BEN,  BOY,  BRU,  CEL, 
CIK,  CM,  COM,  CPV,  DAV,  DEG,  DSO,  DUN,  DUP,  EW,  FAR, 
FBR,  FCD,  FLW,  FOC,  FRE,  FSH,  GEI,  GIL,  GLD,  GRG, 
GRV,  HAN,  HPC,  HRS,  ICF,  JOB,  JWL,  KEL,  KMC,  KMP, 
KPS,  KYN,  MCC,  MID,  NCI,  NPV,  NTL,  0R0,  OSB,  PER, 
PFP,  PPG,  PRT,  RCI,  RED,  REL,  RH,  RMC,  SCF,  SCN,  SED, 
SIP,  SM,  SRR,  SVC,  SW,  SYV,  TV,  VTV,  WAS,  WPC,  x. 

ACP,  ACY,  APV,  BEN,  BRU,  CGL,  CM,  COM,  CPV,  DSO,  DUN, 
DUP,  EW,  FBR,  FCD,  FOC,  GEI,  GLD,  GRV,  HPC,  ICF,  KPS, 
MCC,  MID,  NCI,  NON,  NPV,  OBS,  0R0,  OSB,  PPG,  PRT, 
RED,  REL,  RH,  RMC,  SCN,  SHA,  SM,  SRR,  TV,  VTV. 

ACP,  ACY,  AMR,  CGL,  CIK,  DUP,  GLD,  HPC,  HYC,  JSC,  KMP, 
MMM,  MOB,  NOP,  ORO,  QCP,  RCI,  RH,  SCN,  SIP,  SM. 

ACC,  ACP,  NEV,  NSP,  PAI,  VEL. 
ACC,  ACP,  KPI,  NEV,  NSP,  PAI,  VEL,  WTC. 
ACC,  ACP,  ADM,  CM,  DSO,  DUP,  ENJ,  ICF,  MCA,  NEV,  NPV, 
NSP,  PAI,  PPG,  RCM,  VEL,  VTV. 


CBA,  CEL,  DOW,  SHC,  UCP. 

CBA,  CEL,  DOW,  RCI,  SHC,  UCP. 

CBA,  CEL,  DOW,  RCI,  SHC,  UCP. 

CBA,  CEL,  DOW,  RCI,  SHC,  UCP. 

ACP,  ADM,  BEN,  CM,  DSO,  FAR,  FMC,  GLD,  HAN,  HAP,  ICF, 

IOC,  KPT,  MID,  MNP,  MRB,  NON,  ORO,  OSB,  PPG,  PYR, 

REZ,  RMC,  SCN,  SM,  VTV,  WAS. 


ACY,  ADM,  APD,  DA,  EW,  FRE,  GLD,  HKD,  ICF,  LAS,  MFG, 

ORO,  PPG,  RCI,  RH,  SIC,  USR. 
AAI,  ACP,  ACY,  ADM,  CAP,  CPV,  DA,  DSO,  FRE,  GLD,  GRV, 

HKD,  ICF,  IPC,  KPS,  LAS,  MFG,  MRO,  PLU,  PPG,  RCI, 

SW,  USR. 
ACP,  ACY,  APD,  COM,  CPV,  DA,  FCD,  GLD,  GYR,  ICF,  MCC, 

ORO,  PPG,  SW,  USR. 
ACP,  ACR,  ACY,  AMR,  APD,  DA,  DAV,  DSO,  EKT,  EPC,  EW, 

FMC,  FRE,  GEI,  GLD,  GNT,  GRG,  GYR,  HKD,  LAS,  OCF, 

PLU,  PPG,  RCI,  RH,  SCN,  SW,  USR,  UTR,  VAL. 
ACP,  BOR,  DCC,  GLD,  SPD,  UCS. 

FRL,  GE,  HER,  HKD,  HVG,  IRC,  MON,  MRB,  PLS,  RCI,  RGC, 
SYR,  UCP,  VAR,  VSV. 

ACP,  AMR,  BOR,  CAT,  CBR,  CD,  DRL,  EW,  FOM,  GE,  HKD, 

IRI,  MCA,  MON,  NPI,  NPP,  NTC,  NVF,  PGU,  PYZ,  RCD, 

RCI,  SCN,  SPL,  SYR,  TAY,  TKL,  UCP,  VAR. 
AMR,  EME,  BOR,  CAT,  CBM,  CBR,  HKD,  MMM,  MON,  PYZ,  SCN, 

SYR,  UCP,  VAR. 
ABS,  BME,  BOR,  FRL,  GE,  HKD,  PYZ,  SCN,  SYR,  SYV,  UCP, 

VAR,  VSV,  x. 
ACP,  AMR,  CAT,  GE,  HKD,  ICF,  MON,  NPI,  OCF,  PYZ,  RCI, 

SYV,  UCP. 
ACP,  ACR,  ARM,  BOR,  GE,  HKD,  MON,  NPI,  PYZ,  RCI,  SCN, 

UCP,  UNO,  VAR,  WOD. 
AMR,  BOR,  CAT,  CBC,  CBD,  HPC,  MON,  PGU,  PYZ,  RCI,  RH, 

SIM,  WCA,  WOD,  WRD. 
AMR,  BOR,  CBC,  CBD,  HKD,  ICF,  MCA,  MON,  NPI,  PYZ,  RCI, 

SIM,  UCP. 


PLASTICS  AND  RESIN  MATERIALS 


135 


TABLE  15B.  --Plastics  and  resin  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965-  -Continued 


Material  and  use 


THERMOSETTING  KESINS--Continued 

*Phenolic  and  other  tar  acid  resins— Continued 
Bonding  and  adhesive  resins  for — Continued 
*A11  other  bonding  and  adhesive  uses 

*Proteotive  coatings 

*A11  other  uses 

*Polyurethane  and  diisocyanate  resins 

♦Rosin  modifications: 

♦Rosin  and  rosin  esters,  unmodified  (ester  gums, 
♦All  other 

Styrene  and  alkyd  polyesters 

♦Urea  and  melamine  resins: 

*Textile  treating  and  coating  resins 

♦Paper  treating  and  coating  resins 

Molding  materials 

Bonding  and  adhesive  resins  for— 

♦Laminating 

♦Plywood 

♦Fibrous  and  granulated  wood 

♦All  other  bonding  and  adhesive  uses 

♦Protective  coatings 

All  other  uses 

All  other  thermosetting  resins 


THERMOPLASTIC  RESINS 
Acrylic  resins 

♦Cellulose  plastics  materials: 
Sheets ,  continuous : 
♦Under  0.003  gage 

♦0.003  gage  and  over 

♦All  other  sheets,  rods,  and  tubes 

♦Molding  and  extrusion  materials 

♦Polyamide  resins: 

♦Nylon  type 

♦Non-nylon  type 

♦Styrene  type  plastics  materials: 

♦Molding 

♦Textile  and  paper  treating  and  coating- 

♦Emulsion  paint 

♦Extrusion 

♦All  other  uses 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


ACP,  AMR,  BME,  B0R,  CAT,  GE,  HKD,  IRI,  KPT,  M0N,  MRB, 
PYZ,  RPC,  SCN,  SHA,  SNC,  SYR,  UCP,  USR,  VAR. 

ADM,  AMR,  BOR,  CIK,  CPV,  DS0,  EW,  FAR,  FCD,  FRE,  GE, 
GEI,  GLD,  GRG,  GRV,  HAN,  HER,  HKD,  ICF,  INL,  KRM, 
MID,  M0N,  NCI,  NPI,  0R0,  PFP,  PYZ,  RCI,  RH,  RMC,  SCN, 
SHA,  SM,  SNC,  SW,  SYR,  UCP,  VAR,  VTV,  WAS. 

ACP,  ACR,  AMR,  BOR,  CAT,  EW,  GEN,  HER,  HKD,  IOC,  IRC, 
KND,  MMM,  MON,  MRB,  PLS,  PYR,  PYZ,  RCI,  REZ,  RGC,  RH, 
SCN,  SNC,  UCP,  USR,  VAR,  VSV,  x. 

ACB,  ADM,  ARK,  BFG,  BKL,  CDM,  DUP,  FAR,  GPM,  HAP,  HOU, 
IPI,  MCC,  MID,  NOP,  NPV,  PEL,  PFP,  PYR,  QUN,  SCN, 
TRN,  UPC,  UPJ. 

ADM,  APV,  CBY,  DPP,  FAR,  FCD,  FRP,  HPC,  KRM,  MCC,  SRR. 
ADM,  APV,  CBY,  DPP,  FAR,  FCD,  FLW,  FRP,  HPC,  KRM,  MCC, 

RH,  SCF,  SRR. 
ADM,  DEG,  MCC. 

ACY,  APX,  BOR,  BPY,  CAT,  CCT,  CIB,  CRC,  DAN,  DEP,  DUP, 
ECC,  HNC,  HRT,  JSC,  MON,  MRA,  ONX,  PC,  QCP,  RCI,  RH, 
ROC,  RPC,  S,  SBC,  SEY,  SNW,  STC,  SYN,  TV,  USO,  WON. 

ACY,  AMR,  BME,  BOR,  CBD,  CBR,  DEP,  DUP,  HPC,  MMM,  MON, 
RCI,  RH,  SIM,  x. 

ACP,  ACY,  AV,  BOR,  CAP,  EFH,  GDN,  PMC. 

ACY,  BOR,  CAT,  FOM,  GE,  MON,  NPP,  NTC,  PGU,  PPL. 

ACY,  BGC,  BOR,  CAT,  CBC,  CBD,  HPC,  MON,  NPI,  NTC,  PGU, 

RCI,  REN,  RH,  SAC,  SIM,  SOR,  WOD,  WRD. 
ACY,  AMR,  BOR,  CED,  IPR,  MON,  NTC,  PGU,  RCI,  SOR,  SWP, 

SYV,  UPL. 
ACP,  ACY,  BOR,  GLD,  MON,  OCF,  RCI,  UNO. 
ACP,  ACY,  AMR,  BOR,  CEL,  CPV,  DUP,  GRV,  HAN,  KPS,  MID, 

MON,  OXR,  PPG,  RCI,  REL,  RH,  SCN,  SW. 
ACP,  ACY,  AMR,  AV,  BOR,  CAT,  CMP,  DUP,  ECC,  FRP,  GEO, 

HPC,  MMM,  MON,  RCI,  RH,  VAL,  VAR,  WIC. 
ACP,  ACY,  ADM,  DEG,  GGY,  HPC,  HVG,  JNS,  MCC,  MON,  NPV, 

OCF,  RCD,  SNW,  UBS,  UNO,  WTC. 


AGO,  ACY,  CAT,  CEL,  CIB,  CMG,  DUP,  FLH,  GLC,  GLX,  HCO, 
JNS,  JSC,  PII,  PPG,  QUN,  RH,  RPC,  SAR,  SEY,  USP,  VPC, 
WIC. 


CEL,  DUP,  EKT,  MON. 

CEL,  DOW,  EKT,  MPP,  NIX,  PDJ,  SPY. 

CEL,  MPP,  NIX,  PDJ,  RPI,  RSB,  SPY. 

CEL,  DOW,  EKT,  MON,  PMA,  RSB. 

ALF,  DUP,  FG,  POL,  SPN. 

AMR,  BCM,  EMR,  GNM,  HN,  JNS,  KRM,  SNW. 

ACP,  BFG,  BKC,  BPL,  CSD,  DOW,  DSO,  FBF,  FG,  FIR,  GOR, 

GRP,  GYR,  KPP,  MCB,  MON,  MPL,  PLA,  RCC,  SHC,  SOL, 

TIC,  UCP,  USR. 
BOR,  DOW,  FIR,  GNT,  GRD,  GYR,  ILC,  KPP,  MON,  MRT,  USR, 

WAS,  WIC. 
BOR,  DOW,  DSO,  DUP,  FIR,  GLD,  GNT,  GRD,  GYR,  KPP,  JSC, 

MON,  USR. 
ASP,  BFG,  CSD,  DOW,  KPP,  MCB,  MON,  PMA,  RCC,  UCP,  USR. 
ACC,  ACP,  BCN,  BFG,  BKC,  BOR,  CSD,  DOW,  DSO,  DUP,  FIR, 

G,  GNT,  GRD,  GYR,  IOC,  JNS,  JSC,  KPP,  MCB,  MON,  MRT, 

ONX,  PAI,  POL,  PVI,  RCC,  RH,  SEK,  SEP,  SHC,  SPI,  UBS, 

UCP,  UNC,  USR,  WAS,  WIC. 


136 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE    15B Plastics  and  resin  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 — Continued 


Material  and  use 


Manufacturers '   identification  codes 
(according  to  list  in  table  22) 


THERM3PLASTIC  RESINS--Continued 

Vinyl  resins: 
♦Polyvinyl  acetate  resins: 

♦Emulsion  paint 

♦Adhesives 

♦Bonding  and  sizing 

♦All  other  uses 

♦Polyvinyl  chloride  and  copolymer  resins: 

♦Film,  under  6  mils 

♦Sheet,   6  mils  and  over 

♦Flooring 

♦Paper  and  textile  coating 

Extrusion: 
♦Wire  and  cable 

♦Garden  hose 

♦All  other  extrusions 

Molding: 
♦Records 

♦Slush  and  rotational  molding 

♦All  other  moldings 

♦All  other  uses 

♦All  other  vinyl  resins 

Polyolefin  plastics  materials: 
♦Polyethylene,  density  0.940  and  below: 

♦Injection  molding 

♦Blow  molding 

Extrusion: 
♦Film  and  sheet 

♦Wire  and  cable  coating 

♦Extrusion  coating  on  paper  and  other  substrates- 

♦Pipe 

♦All  other  extrusions 

♦All  other  uses ■ 

♦Polyethylene,  density  over  0.940: 

♦Injection  molding 

♦Blow  molding 

Extrusion: 
♦Film  and  sheet 

♦Wire  and  cable  coating 

♦Pipe 

♦All  other  extrusions 

♦All  other  uses 


ACP,  AIR,  AML,  APV,  BOR,  BOY,  CAT,  CEL,  COM,  DAV,  DSO, 
DUP,  FAR,  FLH,  GLC,  GLD,  GRD,  HAM,  JNT,  KMC,  KMP, 
MCC,  MON,  NPV,  NSC,  RCI,  REL,  SED,  SPC,  UCP,  WAS,  x. 

ACP,  AML,  AIR,  BOR,  CAT,  CEL,  DUP,  FC,  FLH,  GLC,  GRD, 
HNC,  JNT,  JSC,  MON,  MRN,  NSC,  NTC,  PII,  PPG,  RCI, 
SEY,  SH,  SYR,  UCP,  WIC. 

AIR,  AML,  CEL,  .CST,  DUP,  GLC,  GRD,  MON,  PII,  QCP,  RPC, 
SEY,  WIC. 

AIR,  AML,  BOR,  CEL,  CIK,  DAN,  DUP,  FLH,  GLC,  GRD,  HRT, 
JSC,  MON,  NSC,  OCF,  PPG,  PVI,  RCI,  RPC,  SCO,  UCP,  x. 

ATU,  BFG,  BOR,  CRY,  DOW,  FIR,  GNT,  GYR,  MON,  PNT,  THC, 

UCP,  x. 
AME,  ATU,  BFG,  BOR,  CRY,  DA,  DOW,  ESC,  FIR,  GNT,  GYR, 

MON,  PNT,  THC,  UCP,  USR,  x. 
AME,  BFG,  BOR,  CRY,  CUC,  DA,  ESC,  FIR,  GNT,  GYR,  MON, 

THC,  UCP,  USR,  x. 
ATU,  BFG,  BOR,  CRY,  DA,  ESC,  MON,  ONX,  THC,  UCP,  USR,  x. 

ATU,  BFG,  BOR,  CRY,  DA,  DOW,  FIR,  MON,  PNT,  THC,  UCP, 

USR. 
ATU,  BFG,  BOR,  DA,  DOW,  FIR,  MON. 
BFG,  BOR,  CRY,  DA,  DOW,  ESC,  FIR,  GNT,  GYR,  LAS,  MON, 

THC,  UCP,  USR. 

BFG,  BOR,  CRY,  CUC,  DA,  KYS,  MON,  PLA,  PNT,  THC,  UCP, 

USR. 
BFG,  BOR,  CRY,  DA,  ESC,  FIR,  MON,  UCP,  USR. 
ATU,  BFG,  BOR,  CRY,  DA,  DOW,  ESC,  FIR,  GYR,  LAS,  MON, 

PYR,  THE,  UCP. 
ATU,  BFG,  BOR,  CBR,  CMG,  CRY,  CUC,  DA,  DOW,  ESC,  FIR, 

GNT,  GRA,  GYR,  MON,  NSC,  PNT,  PYR,  THC,  UCP,  USR,  x. 
ADM,  AIR,  BEN,  BOR,  DOW,  DUP,  FC,  FCD,  G,  GLD,  GRD, 

HOU,  MCC,  MON,  NSC,  RMC,  RPC,  SW,  UCP. 


ACP,  CEL,  DOW,  DUP,  EKX,  KPP,  MON, 

UCP,  USI. 
ACP,  DOW,  DUP,  EKX,  KPP,  MON,  PLC, 

ACP,  ALO,  CEL,  DOW,  DUP,  EKX,  KPP, 

SPN,  UCP,  USI. 
DOW,  DUP,  EKX,  KPP,  MON,  PLC,  SHC, 
ACP,  CEL,  DOW,  DUP,  EKX,  KPP,  MON, 

UCP,  USI. 
CEL,  DUP,  EKX,  KPP,  PLC,  SPN,  UCP, 
ACP,  DOW,  DUP,  EKX,  GRP,  KPP,  PLC, 
ACP,  CEL,  DOW,  DUP,  EKX,  KPP,  MON, 

UCP,  USI. 

ACP,  CEL,  DOW,  DUP,  EKX,  HPC,  KPP, 

USI. 
ACP,  CEL,  DOW,  DUP,  EKX,  GGC,  HPC, 

UCP,  USI. 

ACP,  CEL,  DOW,  DUP,  EKX,  GGC,  HPC, 

USI. 
ACP,  CEL,  DUP,  EKX,  HPC,  PLC,  UCP. 
ACP,  CEL,  DUP,  EKX,  GGC,  HPC,  KPP, 
ACP,  CEL,  DOW,  DUP,  EKX,  GGC,  HPC, 

USI. 
ACP,  CEL,  DOW,  DUP,  EKX,  GGC,  HPC, 

UCP,  USI. 


PLC,  RCC,  SHC,  SPN, 

RCC,  SHC,  UCP,  USI. 

MON,  PLC,  RCC,  SHC, 

SPN,  UCP,  USI. 

PLC,  RCC,  SHC,  SPN, 

USI. 

UCP,  USI. 

PLC,  RCC,  SHC,  SPN, 

PLC,  RCC,  SHC,  UCP, 

KPP,  MON,  PLC,  SHC, 

KPP,  PLC,  SHC,  UCP, 


PLC,  SHC,  UCP. 
KPP,  PLC,  SHC,  UCP, 


KPP,  MON,  PLC,  RCC, 


PLASTICS  AND  RESIN  MATERIALS 


137 


TABLE  15B.  —Plastics  and  resin  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 — Continued 


Material  and  use 

Manufacturers1  identification  codes 
(according  to  list  in  table  22) 

THERMOPLASTIC  RESINS— Continued 

Polyolefin  plastics  materials—Continued 
^Polypropylene : 

UCP,  USI. 
ACP,  ALO,  AVS,  EKX,  ENJ,  HPC,  PLC,  UCP. 

UCP,  USI. 
ACG,  ACP,  CBY,  CIB,  DEP,  DUP,  GE,  HPC,  JSC,  KRM,  MID, 
MMM,  MOB,  MRA,  RPC,  SBC,  SCN,  SEY,  SNW,  VSV,  WIC. 

SYNTHETIC  ORGANIC  CHEMICALS,  1965 


Rubber- Processing  Chemicals 

TABLE  16B.  --Rubber- processing  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 

[Rubber-processing  chemicals  for  which  separate  statistics  are  given  in  table  16A  are  marked  below  with  an  asterisk 
(*);    chemicals  not  so  marked  do  not  appear  in  table  16A  because  the  reported  data  are  accepted  in  confidence  and 
may  not  be  published.   Manufacturers'    identification  codes  shown  below  are  taken  from  table  22.   An  x  signifies  that 
the  manufacturer  did  not  consent  to  his  identification  with  the  designated  product] 


Manufacturers'    identification  codes 
( according  to  list  in  table  22) 


RUBBER-PROCESSING  CHEMICALS,    CYCLIC 

^Accelerators,  activators,  and  vulcanizing  agents: 
*Aldehyde-amine  reaction  products: 

Acetaldehyde- aniline  condensate 

n-Butyraldehyde- aniline  condensate 

Butyraldehyde-butylideneaniline  condensate 

a-Ethyl-fS-propylacrylanilide 

Heptaldehyde- aniline  condensate 

Triethyltrimethylenetriamine 

*Dithiocarbamic  acid  derivatives: 

Dibenzyldithiocarbamic  acid,  sodium  salt 

Dibenzyldithiocarbamic  acid,  zinc  salt 

Dibutyldithiocarbamic  acid,  N,N-dimethylcyclohexylamine 

salt. 

Dibutyldithiocarbamic  acid,  diphenylguanidine  salt 

Dimethylethylene  diphenyldithiocarbamic  acid,  lead  salt 

2,4-Dinixrophenyl  dimethyldithiocarbamate 

Piperidinecarbodithioic  acid,  piperidinium- potassium 

salts,  mixed. 
Guanidines: 

Dicatechol  borate,  di-o-tolylguanidine  salt 

1, 3-Diphenylguanidine 

Diphenylguanidine  phthalate 

1, 3-Di-o-tolylguanidine 

1, 2,3-Triphenylguanidine 

*Thiazole  derivatives: 

2-Benzothiazyl  N,N-diethylthiocarbamoyl  sulfide 

1, 3-Eis(2-benzothiazolylmercaptomethyl)urea 

N-tert-Buty 1-2- benzothiazolesulf enamide 

*N-Cyelohexyl-2-benzothiazolesulf enamide 

N,  N-Diisopropyl-2-be  nzothiazolesulfenand.de 

N-(2, 6-Dimethy-lmorpholino)  -2-ben£othiazolesulf  enamide — 

*2,2'-Dithiobis(benzothiazole) 

2-Mercaptobenzothiazole 

2-Mercaptobenzothiazole,  zinc  chloride 

2-Mercaptobenzothiazole,  zinc  salt 

4-Morpholi  nyl-2-benzothiazyl  disulfide 

N-0xydiethylene-2-benzothiazolesulf enamide 

Thiazoline-2- thiol 

All  other  cyclic  accelerators,  activators,  and  vulcanizing 

agents: 

p-Benzoquinonedioxime 

Bis(  p- aminocyclohexyl) methane  carbamate 

Bis( 2, 6-dimethylmorpholinothiocarbonyl) sulfide 

Dibenzoyl-p-quinonedioxime • 

Dibenzylamine 

N, N'-Dicinnamylidene-l,  6-hexanediamine 

Di-N,N'-pentamethylenethiuram  tetrasulfide 

^■i'-Dithiodimorpholine 

2-Imidazoline-2-thiol 

m-Phenylenebismaleimide 

Poly-p-dinitrosobenzene 

Styrene  polysulfide 

Tetrahydro-4,4,6-trimethyl-2(  lH)-pyrimidinethione 

*Antioxidants,  antiozonants,  and  stabilizers: 

*Amino  antioxidants,  antiozonants,  and  stabilizers: 
*Aldehyde-  and  acetone-amine  reaction  products: 

Acetaldehyde- aniline  hydrochloride  condensate 

Aldol-cc-naphthylamine  condensate 

Butyraldehyde- aniline  condensate 

*Diphenylamine- acetone  condensate 

Phenyl-2-naphthylamine-acetone  condensate 


USR. 

DUP,  MAN,  RCD,  USR. 

MON. 

CCO. 

USR. 

USR. 

USR. 
USR. 
MON. 

CCO. 
CCO. 
USR. 
DUP. 


DUP. 
ACY. 
MON. 

ACY,  DUP. 
NAC. 


PAS. 
MON. 
MON. 
ACY, 
ACY. 
MON. 
ACY, 
ACY, 
DUP. 
ACY, 
GYR. 
ACY, 
ACY. 


BFG,  MON,  USR. 


BFG,  GYR,  MON,  USR. 
BFG,  GYR,  MON,  USR. 


GYR,  USR. 
MON. 


CTA,  DUP. 

DUP. 

DUP. 

CTA,  USR. 

MLS,  USR. 

DUP. 

DUP,  VNC. 

MON. 

DUP,  RBC. 

DUP. 

DUP. 

TKL. 

VNC. 


USR. 

BFG. 

DUP. 

ACY,  BFG,  DUP,  USR. 

USR. 


RUBBER-PROCESSING  CHEMICALS 


139 


TABLE  16B.—  Rubber-processing  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965—  Continued 


Manufacturers1  identification  codes 
(according  to  list  in  table  22) 


RUBBER-PROCESSING  CHEMICALS,  CYCLIC— Continued 

•Antioxidants,  antlozonants,  and  stabilizers — Continued 
•Amino  antioxidants,  antiozonants,  and  stabilizers — 
Continued 
•Substituted  p-phenylenediamines: 

N,  N'-Bis(  l-ethyl-3-methylpentyl)  -p-phenylenediamine- 

N,  N'-Bis(  l-methyljtieptyl)  -p-phenylenediamine 

N-see-Butyl-N'-phenyl-p-phenylenedlamine 

N-Cyclohexyl-N '-phenyl- p-phenylenediamine 

Diary larylenediamines,  mixed 

N,N'-Di-2-naphthyl- p-phenylenediamine 

•N,N'-Diphenyl- p-phenylenediamine 

N-Isopropyl-N '-phenyl- p-phenylenediamine 

N-(l-MethyLheptyl)-N' -phenyl- p-phenylenediamine 

All  other  p-phenylenediamines 

Other  amino  antioxidants,  antiozonants,  and  stabi- 
lizers: 

p-Anilinophenol 

l,2-Dihydro-6-dodecyl-2,2,4-trimethylquinoline 

l,2-Dihydro-6-ethoxy-2,2,4-trimethylquinoline 

l,2-Dihydro-2, 2,4- trimethylquino line 

4,4'-Dimethoxydiphenylamine 

4,4'-Dioetyldiphenylamine 

N,N'-Diphenylethylenediamine 

N, N'-Diphenyl-l,3-propanediamine 

N, N'-Di-o-tolylethylenediamine 

p- Isopropoxydiphenylamine 

4,4'-Methylenedianiline 

*Octyldiphenylamine 

Octyldiphenylamine  mixture  (mono-,  nonyl-,  and  di-)> 

N-Phenyl-1-naphthylamine 

N-Phenyl-2-naphthylamine 

Tetramethyldiphenylethylenediamine 

p-(p-Toluenesulfonamido)diphenylamine 

•Phenolic  and  phosphite  antioxidants  and  stabilizers: 
Phosphites: 

Nonyl  phenyl  phosphites,  mixed 

Polyphenolie  phosphite,  polyaliylated 

Polyphenolics  ( including  bisphenols) : 

4,4'-Butylidenebis(6-tert-butyl-m-cresol) 

2,5-Di-(l,l-dimethylpropyl)hydroquinone 

2, 2'-Methylenebis(6-tert-butyl-p-cresol) 

2,2'-Methylenebis(6-tert-butyl-4-ethylphenol) 

2,2'-Methylenebis(6-tert-octyl-p-cresol) 

2,2'-Thiobis(4, 6-di-sec-amylphenol) 

4,4'-Thiobis(6-tert-butyl-m-cresol) 

1,  l,3-Tri(2-methyl-4-hydroxy-5-tert-butylphenyl)- 
butane. 
Other  phenolic  antioxidants  and  stabilizers: 

p-Benzyloxyphenol 

N-Butyroyl-p-aminophenol 

o-Cresol,  alkylated 

N-Lauroyl-p-aminophenol 

•Phenol,  alkylated 

Phenol,  hindered 

Phenol,  styrenated 

N-Stearoyl-p-aminophenol 

Xylenol,    alkylated 

•Blowing  agents: 

N,N'-Dimethyl-N,N'-dinitrosoterephthalamide 

Dinitrosopentamethylenetetramine 

p,p'-Oxybis(benzenesulfonhydrazide) 

•Peptizers: 

Alkylated  o-thiocresol 

Alkylated  thiophenol,  zinc  salt 

Aryl  mercaptans 

2-Benzamidothiophene,  zinc  salt 

2',2'"-Dithiobis(benzanilide) 

Dixylyl  disulfides,  mixed 

2-Naphthalene thiol 


EKT, 

MON, 

UPM. 

BFG, 

EKT, 

MON, 

UPM. 

USR. 

USR. 

GYR. 

BFG. 

BFG, 

DUP, 

USR. 

MON, 

USR. 

UPM. 

EKT, 

MON. 

BFG. 

MON. 

MON. 

BFG, 

MON. 

DUP. 

BFG. 

CCO, 

X,    X 

CCO. 

CCO. 

BFG. 

USR. 

ACY, 

NPI, 

PAS, 

USR. 

BFG. 

DUP. 

BFG, 

DUP. 

USR. 
BFG. 

MON. 

MON. 

ACY,  CAT. 

ACY. 

ACY. 

MON. 

MON. 

ICI. 


BFG. 

MLS. 

PIT. 

MLS. 

ACY,  BFG,  CCO,  GYR,  PAS,  PIT,  USR. 

DUP,  GYR,  PIT. 

BFG,  GYR. 

MLS. 

PIT. 

DUP. 

DUP,  NPI. 
USR. 

PIT. 

PIT. 

PIT. 

ACY. 

ACY. 

DUP,  PIT. 

DUP. 


140 


TABLE  16B. 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 

—Rubber-processing  chemicals  for  which  U.S.  production  or  sales  were  reported   identified  by 
manufacturer,  1 965-  -Continued 


RUBBER-PROCESSING  CHEMICALS,    CYCLIC— Continued 

♦Peptizers — Continued 

Pentachlorobenzene thiol 

Pentachlorobenzenethiol,    zinc  salt 

Thioeresol 

Thiophenol  ( Benzenethiol) 

Xylenethiol 

Other  cyclic  rubber-processing  chemicals: 

p-tert-Amylphenol  sulfide  ( taclcifier) 

Dicresyl  disulfide 

N,4-Dinitroso-N-methylaniline  ( physical- property 
improver) . 
♦N-Nitrosodiphenylamine  ( retarder) 

RUBBER-PROCESSING  CHEMICALS,  ACYCLIC 

♦Accelerators,  activators,  and  vulcanizing  agents: 
♦Dithiocarbamic  acid  derivatives: 

Dibutyldithiocarbamic  acid,  potassium  salt 

Dibutyldithiocarbamic  acid,  sodium  salt 

♦Dibutyldithiocarbamic  acid,  zinc  salt 

Diethyldithiocarbamic  acid,  cadmium  salt 

Diethyldithiocarbamic  acid,  selenium  salt 

Diethyldithiocarbamic  acid,  sodium  salt 

Diethyldithiocarbamic  acid, 

♦Diethyldithiocarbamic  acid, 
Dimethyldithiocarbamic  acid, 
Dimethyldithiocarbamic  acid, 
Dimethyldithiocarbamic  acid, 
Dimethyldithiocarbamic  acid, 
Dimethyldithiocarbamic  acid,  sodium  salt  and  sodium 
polysulfide. 

♦Dimethyldithiocarbamic  acid,  zinc  salt 

All  other 

♦Thiurams : 

Bis( dibutylthiocarbamoyl)  sulfide 

Bis( diethylthiocarbamoyl)  disulfide 

♦Bis(  dimethylthiocarbamoyl)  disulfide 

Bis(  dimethylthiocarbamoyl)  disulfide  and  2-mercapto- 
benzothiazole,  mixed. 

*Bis( dimethylthiocarbamoyl)  sulfide 

Bis( ethylmethylthiocarbamoyl)  sulfide 

Thiuram  blend 

Xanthates  and  sulfides: 

Di-n-butylxantho  disulfide 

Diisopropylxantho  disulfide 

Zinc  dibutyl  xanthate 

All  other  acyclic  accelerators,  activators,  and  vulcan- 
izing agents: 

n-Butyraldehyde-butylamine  condensate 

Pi- n- butyls mmonium  oleate 

N,  N'-Dibutyldithioadipamide 

3- Ethyl- 1, 1-dimethy  1-2- thiourea 

Ethylenediamine  carbamate 

Polyoxyalkalenetetrasulfide 

1,1,3-Trimethy  1-2-  thiourea- 


tellurium  salt- 
zinc  salt 

bismuth  salt- 
copper  salt 

lead  salt 

selenium  salt- 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


DUP. 
DUP. 
PIT. 
PIT. 
DUP. 

PAS. 
USR. 
CTA,  MON. 

BFG,  CTA,  GYR,  USR. 


PAS,  USR,  VNC. 

DUP,  PAS,  REC,  USR,  VNC. 


PAS,  USR. 

GYR,  PAS,  RBC,  USR,  VNC. 


VNC. 
DUP, 
ALC, 
VNC. 
VNC. 
ALC, 
VNC. 
ALC, 
VNC. 
VNC. 
VNC. 
VNC. 
BFG, 


ALC,  DUP,  FMN,  GYR,  PAS,  RBC,  USR,  WRC. 
PAS. 

USR. 

DUP,  GYR,  PAS,  VNC. 

BFG,  DUP,  GNT,  GYR,  PAS,  RBC,  USR,  VNC. 

VNC. 

DUP,  GYR,  USR. 

VNC. 

DUP. 

USR. 
BFG. 
USR. 


DUP. 
DUP. 
DUP. 
VNC. 
DUP. 
TKL. 
VNC. 


RUBBER-PROCESSING  CHEMICALS 


141 


TABLE  16B. — Rubber-processing  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  2S65--Contlnued 


Chemical 

Manufacturers'  identification  codes 
( according  to  list  in  table  22) 

RUBBER-PROCESSING  CHEMICALS,  ACYCLIC— Continued 
Blowing  agents: 

SW. 

DUP. 
DUP. 
DUP. 

PAS,  PLC. 

Conditioning  and  lubricating  agents: 

Methyl  stearyl-10-sulfonic  acid,  sodium  salt 

Mono-  and  dialkyl  phosphate  ammonium  salts,  mixed 

Polymerization  regulators: 

Shortstops: 

Dimethyldithiocarbamic  acid,  potassium  salt 

Other  acyclic  rubber-processing  chemicals: 

Zinc  laurate  (activator,  physical- property  improver) 

GYR,  PAS,  USR. 

ALC,  BFG,  DUP,  GYR,  PAS. 

USR. 

SYNTHETIC  ORGANIC  CHEMICALS,  1965 


Elastomers  (Synthetic  Rubbers) 


TABLE  17B.-- Elastomers  (synthetic  rubbers)  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer ,  1965 


[Elastomers   (synthetic  rubbers)   for  which  separate  statistics  are  given  in  table  17A  are  marked  below  with  an  as- 
terisk (*);   products  not  so  marked  do  not  appear  in  table  17A  because  the  reported  data  are  accepted  in  confidence 
and  may  not  be  published.  Manufacturers'   identification  codes  shown  below  are  taken  from  table  22.  An  x  signifies 
that  the  manufacturer  did  not  consent  to  his   identification  with  the  designated  product] 


Product 

Manufacturers '  identification  codes 
(according  to  list  in  table  22) 

ELASTOMERS,  CYCLIC 

ASY,  BFG,  CPY,  FIR,  FRS,  GGC,  GNT,  GYR,  ILC,  MCB,  PLC, 

RUB,  SHC,  TUS,  URC,  USR,  WIC. 
ASY,  BFG,  FIR,  FRS,  GNT,  GYR,  PLC,  USR,  WIC. 
ACY,  BFG,  DUP,  GNT,  MOB,  PRC,  TKL,  USR. 

ACY,  BFG,  TKL. 

TKL. 

BFG,  FRS,  GYR,  TKL,  TUS. 

BFG,  FRS,  GYR,  ILC,  MCB,  USR. 

DUP. 

CBN,  ENJ. 

GYR,  HPC. 

DCC,  SPD,  UCS. 

ASY,  BAR,  DUP,  ENJ,  FRS,  GGC,  GNT,  GYR,  PLC,  SHC,  TUS. 

DUP,  x. 

ELASTOMERS,  ACYCLIC 

*Polyisobutylene-isoprene  type  (Butyl) 

<3+ 

Plasticizers 

TABLE  18B. — Plasticizers  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 

[Plasticizers  for  which  separate  statistics  are  given  in  table  18A  are  marked  below  with  an  asterisk  (*);  products 
not  so  marked  do  not  appear  in  table  18A  because  the  reported  data  are  accepted  in  confidence  and  may  not  be  pub- 
lished. Manufacturers'  identification  codes  shown  below  are  taken  from  table  22] 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


PLASTICIZERS,  CYCLIC 

Coumarone-indene  plasticizer 

N-Cyclohexyl-p-toluenesulfonamide 

Diethylene  glycol  dibenzoate 

Di-tert-octyldiphenyl  oxide 

Dipropanediol  dibenzoate 

N-Ethyl-p-toluenesulfonamide 

Isopropylidenediphenoxypropanol 

Naphthalene,  alkylated 

Phosphoric  acid  esters: 

*Cresyl  diphenyl  phosphate 

Dibutyl  phenyl  phosphate 

Diphenyl  mono-o-xenyl  phosphate 

Diphenyl  octyl  phosphate 

Methyl  diphenyl  phosphate 

*Tricresyl  phosphate 

Triphenyl  phosphate 

All  other  phosphoric  acid  esters 

*Phthalic  anhydride  esters: 

Alkyl  benzyl  phthalates 

Butyl  benzyl  phthalate 

Butyl  cyclohexyl  phthalate 

Butyl  decyl  phthalate 

*Butyl  2-ethylhexyl  phthalate 

n-Butyl  isodecyl  phthalate 

*Butyl  octyl  phthalate 

Butyl  phthalyl  butyl  glycolate 

Di(2-butoxyethyl)  phthalate 

*Dibutyl  phthalate 

*Dicyelohexyl  phthalate 

*Diethyl  phthalate 

*Dihexyl  phthalate 

Diisobutyl  phthalate 

*Diisodecyl  phthalate 

»Di(2-methoxyethyl)  phthalate 

Dimethyl  cyclohexyl  phthalate 

Dimethyl  isophthalate 

*Dimethyl  phthalate 

Dinonyl  phthalate 

*Dioctyl  phthalates: 

Dicapryl  phthalate 

Di(ethylhexyl)isophthalate 

*Di(2-ethyLhexyl)  phthalate 

*Diiso-octyl  phthalate 

Di-n-octyl  phthalate 

*Mixed  dioctyl  phthalates 

Diphenyl  phthalate 

*Ditridecyl  phthalate 

2-EthyLhexyl  isodecyl  phthalate 

Ethyl  (and  methyl)  phthalyl  ethyl  glycolate 

Glycol  phthalic  esters 

Hexyl  n-decyl  phthalate 

Hexyl  isodecyl  phthalate 

Hydrogenated  castor  oil  phthalate 

Isodecyl  tridecyl  phthalate 

*0ctyl  decyl  phthalates: 

Iso-octyl  isodecyl  phthalate 

n-Octyl  n-decyl  phthalate 

All  other  phthalic  anhydride  esters 


NEV. 

MON. 

VEL. 

DOW. 

VEL. 

MON. 

DOW. 

ACC. 

FMP, 

MON,   MTR,   SF,   SM. 

MON. 

DOW. 

MON. 

FMP, 

MON. 

FMP, 

MON,  MTR,   SF. 

DOW, 

EK,   MON,   SF. 

SF. 

MON. 

GRH, 

MON. 

ACP. 

ACP, 

PCC. 

ACP, 

MON,    UCC. 

GRH, 

UCC. 

GRH, 

PCC,   RCI,   RUB. 

MON. 

FMP, 

WM. 

ACP, 

COM,   DUP,   EKT,   ENJ,    GRH, 

HAL, 

LAS, 

MON, 

PCC, 

PFZ 

RCI,   RUB,   SW,   UCC,  WTH. 

ACP, 

DUP,    FMP,  MON,   PFZ. 

DUP, 

EKT,    KF,  MON,   PFZ. 

ACP, 

ENJ,   GRH,    LEH,   THC. 

EKT, 

UCC. 

ACP, 

BFG,   EKT,   ENJ,    GRH,  MON, 

PCC, 

PFZ, 

RCI, 

RUB, 

THC 

UCC,   WTH. 

DUP, 

EKT,    FMP,   RCI,   SF. 

DUP. 

PFZ. 

ACP, 

EKT,    KF,  MON,   PFZ. 

RCI. 

ACP,  GRH,  WTH. 

UCC. 

ACP,  BFG,  EKT,  ENJ,  GRH,  LEH,  MON,  PCC,  PFZ,  RCI,  RUB, 

THC,  UCC,  WTH. 
ACP,  BFG,  EKT,  ENJ,  GRH,  LEH,  MON,  PCC,  PFZ,  RCI,  RUB, 

THC,  UCC. 
ADM. 

ACP,  GRH,  UCC,  WTH. 
MON. 

ACP,  ENJ,  GRH,  MON,  PCC,  PFZ,  RCI,  RUB,  THC,  UCC. 
UCC. 
MON. 

ARG,  HPC. 
ACP,  UCC. 
PFZ. 
DUP. 
THC.  , 

ACP,  PCC. 

ACP,  GRH,  HPC,  MON,  PCC,  PFZ,  RCI,  RUB,  THC,  UCC. 

FMP,  LEH,  MON,  PCC,  UCC. 


144 


SYNTHETIC  ORGANIC  CHEMICALS.  1965 


TABLE  18B. — Plasticizers  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


PLASTICIZERS,  CYCLIC— Continued 

Polyethylene  glycol  dibenzoate 

Tetrahydrofurfuryl  oleate 

Toluenesulfonamide,  o-,  p-  mixtures 

Triethylene  glycol  dibenzoate 

*Trimellitic  acid  esters 

All  other  cyclic  plasticizers 

PLASTICIZERS,  ACYCLIC 

*Adipic  acid  esters: 

Di(2-(2-butoxyethoxy)ethyl)  adipate 

*Di ( 2-ethylhexyl )  adipate 

Diisobutyl  adipate 

*Diisodecyl  adipate 

*Diiso-octyl  adipate 

Dinonyl  adipate 

Di-n-octyl  adipate 

Di-tridecyl  adipate 

Iso-octyl  isodecyl  adipate 

*Octyl  decyl  adipate 

Polyethylene  glycol  adipate 

All  other  adipic  acid  esters 

*Azelaic  acid  esters: 

Di ( 2-ethyLhexyl )  azelate 

Di-n-hexyl  azelate 

Diisobutyl  azelate 

Diiso-octyl  azelate 

Dioctyl  azelate 

All  other  azelaic  acid  esters 

Citric  and  acetylcitric  acid  esters 

^Complex  linear  polyesters  and  polymeric  plasticizers- 

Di(2-(2-butoxyethoxy)ethyl)methane 

Diethylene  glycol  dinonanoate 

Diiso-octyl  diglycolate 

*Epoxidized  esters: 

Butyl  epoxydioleate 

Butyl  epoxytallate 

Epoxidized  linseed  oils 

*Epoxidized  soya  oils 

*2-Ethylhexyl  epoxytallates 

Octyl  epoxystearates 

*Octyl  epoxytallates 

All  other  epoxidized  esters 

Glycerol  pelargonate 

Glyceryl  tributyrate  and  tripropionate 

Glycol  pelargonate 

Isodecyl  maleate 

Isodecyl  nonanoate  (Isodecyl  pelargonate) 

Laurie  acid  esters 

Myristic  acid  esters: 

Butyl  myristate 

*Isopropyl  myristate 

*01eic  acid  esters: 

*Butyl  oleate 

^Glycerol  trioleate  (Triolein) 

*Isopropyl  oleate 

*Methyl  oleate 

*n-Propyl  oleate 

*A11  other  oleic  acid  esters 

Palmitic  acid  esters: 

Isobutyl  palmitate 

*Isopropyl  palmitate 

2-Methoxyethyl  palmitate 

All  other  palmitic  acid  esters 

^Phosphoric  acid  esters: 

Tri(2-butoxyethyl)  phosphate 

Tri(2-chloroethyl)  phosphate 

Triethyl  phosphate 


VEL. 

CCW,  EMR. 

ACY,  MON. 

VEL. 

PCC,  PFZ,  RUB. 

CCW,  EKT,  MON,  NEV,  WTH. 


TKL. 


FMP, 
EKT, 
FMP, 
ACP, 
GRH, 
THC. 
ACP. 
LEH. 
BFG, 
ACP, 
PFZ. 
ACP,  ARC,  EKX,  PCC,  PFZ,  VND. 


LEH,  MON,  PCC,  RCI,  RH,  RUB,  THC,  UCC,  WTH. 
GRH,  HAL,  RCI. 

EKT,  GRH,  LEH,  MON,  PCG,  RCI,  RH,  RUB,  THC,  UCC,  WTH. 
LEH,  PCC,  RCI,  RH,  RUB,  WTH. 


NOP,  RCI. 

GRH,  MON,  PCC,  RCI,  RH,  RUB,  THC,  TKL,  UCC. 


DUP,  EKT,  EMR,  PFZ,  RCI,  RH,  RUB,  THC,  UCC. 

UCC. 

HAL,  RCI. 

EMR,  PFZ. 

PFZ. 

ACP,  EMR,  PFZ. 

PFZ. 

ADM,  EKT,  EMR,  GLY,  HAL,  LEH,  MON,  PFZ,  RH,  RUB,  WM, 

WTH. 
GRD. 

EMR,  RUB. 
CCA,  FMP. 


THC. 

SWT. 

ARG,  BAC,  RCI,  RH,  SWT,  THC,  UCC. 

BAC,  UCC. 

RH,  THC,  UCC. 
RH. 


ADM. 
ADM, 
ADM, 
ADM, 
ADM, 
ARG. 
ARG, 
EMR, 
EMR. 
EKT. 
EMR. 
LEH. 
EMR. 
HAL. 


ARC,  ICI. 

ARC,  ICI,  NOP,  PRP. 

ARC,  HAL,  ICI,  LAS,  NOP,  SWT,  WM,  WTH. 

DRW,  EMR,  SWT,  WM. 

ARC,  ICI,  WM. 

CHL,  EMR,  ICI,  NOP,  SWT. 

CHL,  EMR,  WM. 

ARC,  DRW,  HAL. 

ARC,  EKT. 

ARC,  EMR,  ICI,  PRP,  WM. 

EKT. 

EKT,  RUB. 

FMP,  MON,  SF,  WES. 

UCC. 

EKT. 


PLASTICIZERS 


145 


TABLE  18B.  --Plasticizers  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


PLASTICIZERS,  ACYCLIC— Continued 

•Phosphoric  acid  esters — Continued 

Trioctyl  phosphate 

All  other  phosphoric  acid  esters 

Ricinoleic  and  acetylricinoleic  acid  esters: 

n-Butyl  acetylricinoleate 

Butyl  ricinoleate 

•Glycerol  monorieinoleate 

Glyceryl  tri( acetylricinoleate) 

Methyl  ricinoleate 

All  other  ricinoleic  and  acetylricinoleic  acid  esters 

Sebacic  acid  esters: 

Dibutoxyethyl  sebacate 

*Dibutyl  sebacate 

*Di(2-ethylhexyl)  sebacate 

All  other  sebacic  acid  esters 

•Stearic  acid  esters: 

Butoxyethyl  stearate 

*n-Butyl  stearate 

Glycerol  triacetyl  stearate 

Glycerol  tristearate 

Methoxyethyl  stearate 

Methyl  diohlorostearate 

Methyl  pentachlorostearate 

Methyl  stearate 

All  other  stearic  acid  esters 

Sucrose  acetate  isobutyrate 

Tetraethylene  glycol  di(2-ethylhexanoate) 

*Triethylene  glycol  di(caprylate-caprate) 

Triethylene  glycol  di-2-ethylbutyrate 

Methylene  glycol  di(2-ethylisohexoate) 

Trimethyl  pentanediol  diisobutyrate 

All  other  acyclic  plasticizers 


Manufacturers '  identification  codes 
(according  to  List  in  table  22) 


FMP,  UCC. 

SM. 

BAC,  WTH. 

BAC,  RCI. 

BAC,  GLY,  HAL,  NOP. 

BAC. 

BAC. 

ARC,  BAC,  RCI. 

RCI. 

EKT,  GRH,  HAL,  PFZ,  RCI,  RH,  WTH. 

GRD,  GRH,  HAL,  PCC,  RCI,  RH,  HUB,  WTH. 

ARC,  LEH,  NOP,  PCC,  RCI,  RH,  HOB. 


ARC. 

ARC, 

BAC. 

DRW. 

ARC. 

HK. 

HK. 

CHL. 

ARC, 

EKT. 

UCC. 

DRW, 

UCC. 

EKT. 

EKX. 

ARC, 


CHL,  EMR,  HAL,  ICI,  LAS,  SCP,  SWT,  WTH. 

FMP,  HPC,  PRP,  RCI,  RH,  Hi. 
FOR,  HAL,  RUB. 

EMR,  HAL,  HPC,  LEH,  PFZ,  RH,  RUB,  TKL,  UCC,  WM. 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


Surface-Active  Agents 


TABLE  19B. — Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 

[Surface-active  agents  for  which  separate  statistics  are  given  in  table  19A  are  marked  below  with  an  asterisk  (*); 
products  not  so  marked  do  not  appear  in  table  19A  because  the  reported  data  are  accepted  in  confidence  and  may  not 
be  published.  Manufacturers '  identification  codes  shown  below  are  taken  from  table  22.  An  x  signifies  that  the 
manufacturer  did  not  consent  to  his  identification  with  the  designated  product] 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


BENZENOID  SURFACE-ACTIVE  AGENTS 

Not  Sulfated  or  Sulfonated 

*Amides,  amines,  and  quaternary  ammonium  salts: 

*Benzyldimethyl(mixed  alkyl) ammonium  chloride 

*Benzyldimethyloctadeey lammonium  chloride 

*Benzyldodeeyldimethylammonium  chloride 

*( 3, 4^  Dichlorobenzyl)dodecyldimethy lammonium  chloride 

*(Dodecylbenzyl)trimethylammonium  chloride 

^Heterocyclic  compounds : 

l-Benzyl-2-( coconut  oil  alkyl)-l-(2-hydroxyethyl)-2- 
imidazolinium  chloride. 
*l-Benzyl-2-heptadecyl-l-( 2-hydroxyethyl) -2-imidazo- 
linium  chloride. 
l-Benzyl-l-(2-hydroxyethyl)-2-nor(tall  oil  alkyl)-2- 
imidazolinium  chloride. 

l-Benzyl-2-picolinium  bromide 

1-Benzylpyridinium  chloride 

2-Dodecylisoquinolinium  bromide 

1-Dodecylpyridinium  chloride 

2-(2-Lauroyloxyethyl)carbamoyl-l-methylpyridinium 

chloride. 
l-Methyl-2- ( 2-stearoyloxyethyl) carbamoylpyridinium 
chloride. 
*Oxygen- containing  compounds  (except  heterocyclic): 
Benzylbis ( 2-hydroxyethyl ) ( 2-stearamidomethoxyethyl) - 

ammonium  chloride. 
Benzyl(  coconut  oil  alkyl )bis ( 2-hydroxyethyl )a,mmonium 

chloride . 
Benzyl( coconut  oil  amidopropyl ) dime thy lammonium 

chloride. 
Benzyl( ethoxylated  coconut  oil  alkyl )dimethy lammonium 

chloride. 
( Ethoxybenzyl ) dimethyl ( oc tylphenoxy ) ammonium  chloride — 
(Ethoxybenzyl) dime thyl(octyltolyloxy) ammonium  chloride- 

N-  ( 2-Hydroxyethyl )  -1, 2-diphenylethylenediami  ne 

o-Isopropoxyphenyl  N-methylcarbamate 

(Tridecylbenzyl)diethyl( 2-hydroxyethyl) ammonium 
chloride. 
*A11  other: 

Benzylbis (hydrogenated  tallow  alkyl )methy lammonium 
chloride. 

Benzyl( coconut  oil  alkyl) dime thy lammonium  chloride 

Benzyldimethyltetradecy lammonium  chloride 

Benzylhexadecyldimethy lammonium  chloride 

Benzyl( hydrogenated  tallow  alkyl ) dime thy lammonium 
chloride. 

Benzyl( soybean  oil  alkyl) dimethy lammonium  chloride 

Benzyltrimethy lammonium  chloride 

(Dodecylbenzyl) dimethy loctadecy lammonium  chloride 

(Dodecylbenzyl)triethylammonium  chloride 

( Dodecylmethylbenzy 1 ) trimethy lammonium  chloride 

(Ethylbenzyl)dimethyl(mixed  alkyl) ammonium  chloride 

*Carboxylic  acid  esters  and  ethers : 

*Dinonylphenol,  ethoxylated 

*Dodecylphenol,  ethoxylated 

*Iso-octylphenol,  ethoxylated 

*Nonylphenol,  ethoxylated 

*Phenol,  ethoxylated 


AAC,  BC,  BRD,  CUL,  FIN,  ONX,  PCS,  PG,  RH,  RTF,  TXT, 

VAC,  WSN. 
APX,  ONX,  PCS,  RET,  WSN. 
DEP,  FIN,  ONX,  SDH,  WSN. 
CUL,  FIN,  ONX,  VAC,  WSN. 
BC,  CUL,  NLC,  RCD,  WTC. 


NLC. 


PCS,    TXT, 

UVC 

NLC. 

FIN. 

DEP. 

CUL,    ONX. 

BC,   HK. 

WTC. 

WTC. 

CIB. 

CIB. 

TXT. 

G. 

RH. 
RH. 
APX. 


TXT. 


BC,  CRT. 
SNW,  WSN. 
ONX,  RH. 
TXT. 

TXT. 

COM. 

AML. 

PC. 

RH. 

ONX. 

G,  JCC,  STP. 

G,  MON,  PCS,  UCC. 

APX,  CIB,  DRW,  NOP,  CMC. 

APD,  CIB,  CLY,  DOW,  DRW,  G,  HFC,  JCC,  MON,  NLC,  CMC, 

PCS,  RH,  RTF,  STP,  UCC. 
APD,  G,  JCC,  NOP,  UCC. 


SURFACE-ACTIVE  AGENTS 


147 


TABLE  19B. — Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


BENZENOID  SURFACE- ACTIVE  AGENTS— Continued 

Not  Sulfated  or  Sulfonated--Continucd 

*Carboxylic  acid  esters  and  ethers — Continued 
*Other  earboxylic  acid  esters  and  ethers : 
Alkylphenol  -  formaldehyde,  alkoxylated : 

(Mixed  aliyl) phenol  -  formaldehyde,  aLkoxylated 

Nonylphenol  -  formaldehyde,  alkoxylated 

tert-Octylphenol  -  formaldehyde,  ethoxylated 

Pentylphenol  -  formaldehyde,  alkoxylated 

Diisobutylphenol,  ethoxylated 

(Mixed  alkyl)phenol,  ethoxylated 

(Mixed  alkyljphenol,  ethoxylated,  butyl  ether 

(Mixed  aliyl)phenoxypoly(ethyleneoxy) ethyl  chloride 

Nonylphenol,  ethoxylated  and  propoxylated 

Nonylphenoxypoly(ethyleneoxy) ethyl  iodide 

n-Octylphenol,  ethoxylated 

Pentylphenol,  ethoxylated 

Phthalic  acid,  octadecyl  ester,  potassium  salt 

Tetradecylphenol,  ethoxylated 

Tridecylphenol,  ethoxylated 

Xylenol,  ethoxylated 

All  other 

*Phosphoric  and  polyphosphoric  acid  esters : 

Dinonylphenol,  ethoxylated  and  phosphated 

Hexylphenol,  ethoxylated  and  phosphated 

*Nonylphenol,  ethoxylated  and  phosphated 

Nonylphenol,  ethoxylated  and  phosphated,  barium  salt 

Octylphenol,  ethoxylated  and  phosphated 

Octylphenol,  ethoxylated  and  phosphated,  magnesium  salt- 
Phenol,  ethoxylated  and  phosphated 

Sulfated  and  Sulfonated 

*ALkylphenols,  ethoxylated  and  sulfated: 

Dodecylphenol,  ethoxylated  and  sulfated 

Dodecylphenol,  ethoxylated  and  sulfated,  potassium  salt- 

(Mixed  alkyl)phenol,  ethoxylated  and  sulfated 

»Nonylphenol,  ethoxylated  and  sulfated,  and  salts: 

Nonylphenol,  ethoxylated  and  sulfated 

Nonylphenol,  ethoxylated  and  sulfated,  ammonium  salt — 

Nonylphenol,  ethoxylated  and  sulfated,  sodium  salt 

Nonylphenol,  ethoxylated  and  sulfated,  triethanolamine 
salt. 

n-Octylphenol,  ethoxylated  and  sulfated 

*Benzenesulfonates : 

*Benzene-,  cumene-,  toluene-,  and  xylenesulfonates : 

Benzenesulfonic  acid,  sodium  salt 

Cumenesulfonic  acid,  ammonium  salt 

2,4- Dinitrobenzenesulfonic  acid,  sodium  salt 

Ethylene  glycol  dibenzenesulfonate 

Toluenesulfonic  acid 

p-Toluenesulfonic  acid,  hexadecyltrimethylammonium 
salt. 

Toluenesolfonic  acid,  potassium  salt 

Toluenesulfonic  acid,  sodium  salt 

*Xylenesulfonic  acid,  ammonium  salt 

Xylenesulfonie  acid,  potassium  salt 

*Xylenesulfonic  acid,  sodium  salt 

^Branched  chain  alkylbenzenesulf onates : 

Decylbenzenesulfonic  acid,  sodium  salt 

Didodecylbenzenesulfonic  acid 

Didodecylbenzenesulfonic  acid,  sodium  salt 

*Dodecylbenzenesulfonic  acid 

Dodecylbenzenesulfonic  acid,  ammonium  salt 

Dodecylbenzenesulfonie  acid,  butylamine  salt 

^Dodecylbenzenesulfonic  acid,  calcium  salt 

Dodecylbenzenesulfonic  acid,  diethanolamine  con- 
densate, fatty  acid  monoester. 
Dodecylbenzenesulfonic  acid,  diethanolamine  salt 


NLC,  RTF. 

RTF. 

SDW. 

RTF. 

G,  RH. 

G,  PCS. 

RH. 

G. 

STP. 

G. 

ICI. 

RTF. 

CIB. 

0R0. 

PCS. 

NLC. 

RH. 


RZL. 


G,  NLC,  RTF,  RZL,  SEY,  TCC,  TCI,  TXT,  WAY,  WSN,  WTC. 

G. 

RH. 


G,  LEV,  TCI. 

STP. 

G. 

CRT,  G,  OMC,  WTC. 

CIB,  MYW,  RCD,  STP,  TXT. 

STP. 


RH,  TXT. 


NES,  UPF. 

STP. 

NES. 

NES. 

RCD. 

FIN. 

MTW,  NES,  RCD,  STP,  WTC. 

CO,  NES,  PIL,  RCD,  STP,  WTC. 

ATR,  CO,  NES,  RCD,  STP,  WTC. 

MTW,  NES,  STP. 

ATR,  CO,  MYW,  NES,  PIL,  RCD,  STP,  WTC. 

MON. 

CO. 
CO. 
ARD,  CO,  CRT,  LEV,  MON,  NAC,  PIL,  RCD,  RTF,  SEY,  STP, 

TCI,  TDC,  TEN,  TXT,  WTC. 
ARL. 
WTC. 

APD,  CO,  NLC,  RCD,  RH,  RTF,  SMC,  STP,  WTC. 
MAH. 

PCS,  VAL,  WON. 


148 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  19B.  —Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


Chemical 


BENZENOID  SURFACE- ACTIVE  AGENTS- -Continued 

Sulfated  and  Sulfonated--Continuei 

*Benzenesulf onates — Continued 

*Branehed  chain  aliylbenzenesulfonates--Continued 

Dodecylbenzenesulfonie  acid,  ethylenediamine  salt 

Dodecylbenzenesulfonic  acid,  isopropanolamine  salt 

*Dodeeylbenzenesulfonic  acid,  isopropylamine  salt 

*Dodeeylbenzenesulfonic  acid,  (mixed  aliyl) amine  salt 

Dodecylbenzenesulfonie  acid,  potassium  salt 

Dodecylbenzenesulfonic  acid,  propoxylated  ethylene- 
diamine  salt. 

^Dodecylbenzenesulfonic  acid,  sodium  salt 

Dodecylbenzenesulfonie  acid,  strontium  salt 

^Dodecylbenzenesulfonic  acid,  triethanolamine  salt 

Nonylbenzenesulfonic  acid,  sodium  salt 

Pentadeeylbenzenesulfonic  acid,  potassium  salt 

Pentadecylbenzenesulfonic  acid,  sodium  salt 

Pentylbenzenesulfonic  acid,  sodium  salt 

Tridecylbenzenesulfonie  acid 

Tridecylbenzenesulfonic  acid,  ammonium  salt 

Tridecylbenzenesulfonie  acid,  sodium  salt 

*Straight  chain  alkylbenzenesulfonates : 

^Dodecylbenzenesulfonie  acid 

Dodecylbenzenesulfonie  acid,  ammonium  salt 

Dodecylbenzenesulfonic  acid,  isopropylamine  salt 

*Dodecylbenzenesulfonie  acid,  sodium  salt 

^Dodecylbenzenesulfonic  acid,  triethanolamine  salt 

Tridecylbenzenesulfonic  acid 

Tridecylbenzenesulfonic  acid,  sodium  salt 

*Lignosulf onates : 

Lignosulfonic  acid,  aluminum  salt 

Lignosulfonic  acid,  ammonium  salt 

*Lignosulfonie  acid,  calcium  salt 

Lignosulfonic  acid,  chromium  salt 

Lignosulfonic  acid,  iron  salt 

Lignosulfonic  acid,  magnesium  salt 

^Lignosulfonic  acid,  sodium  salt 

*Naphthalenesulf onates : 

Benzylnaphthalenesulfonic  acid 

Butylnaphthalenesulfonic  acid 

*Butylnaphthalenesulfonic  acid,  sodium  salt 

DibutyLnaphthalenesulfonic  acid 

Didodecylnaphthalenesul fonic  acid,  sodium  salt 

*Diisopropylnaphthalenesn1 fonie  acid 

Diisopropylnaphthalenesulfonic  acid,  sodium  salt 

Dipentylnaphthalenesulfonic  acid 

Dipentylnaphthalenesulfonic  acid,  ammonium  salt 

Dipentylnaphthalenesulfonic  acid,  (mixed  aliyl) amine  salt 

Isopropylnaphthalenesul fonic  acid 

Methylenebis(2-naphthalenesulfonic  acid) 

6,6'-Methylenebis(2-naphthalenesulfonic  acid),  calcium 
salt. 

MethyLnaphthalenesulfonic  acid,  sodium  salt 

JfethylnonyLnaphthalenesulfonic  acid,  sodium  salt 

Tetrahydronaphthalenesulfonic  acid,  sodium  salt 

Other  benzenoid  surface-active  agents,  sulfated  and 
sulfonated : 

ButyLhydroxybiphenylsulfonic  acid 

Dodecyldiphenyloxidedisulfonic  acid,  sodium  salt 

HpptnHppyliTigt.hylbgngiiiririg'an'liTipgiilfnrnp    acid,    Sodium 

salt. 
n-Octylphenol,  ethoxylated  and  sulfonated 

Petroleumsulfonic  acid,  water  soluble  (acid  layer), 
sodium  salt. 

5-Sulfophthalic  acid,  diaDsyl  ester,  potassium  salt 

Trichlorophenol  sulfate,  ethanolamine  salt 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


APD. 

SMC. 

APD,  AHD,  RCD,  RTF,  SNW,  STP,  WTC. 

PCS,  RTF,  STP,  WTC. 

VAL. 

PCS. 

AAC,  APX,  ARD,  ARL,  ATR,  CO,  CP,  CRT,  DEP,  EFH,  EMK, 
HLI,  HRT,  ICI,  LEV,  MON,  NAC,  NOP,  PG,  PIL,  RCD, 
SEY,  STP,  SWT,  TEN,  TXT,  WIC,  WON,  WTC. 

RTF. 

AML,  ARD,  ARL,  ATR,  CRT,  HLI,  NAC,  PCS,  PEK,  PIL,  RCD, 
RTF,  SOS,  STP,  SWT,  TXT,  VAC,  WON,  WTC. 

WTC. 

STP. 

CP. 

MON. 

RCD. 

RCD. 

CP,  TXT,  WTC. 

ARD,  CO,  HLI,  LEV,  NAC,  PIL,  PRX,  RCD,  RTF,  RZL,  STP, 

TCI,  TXT. 
CTL,  TXT. 
CTL,  RCD. 
ARD,  ATR,  CO,  CP,  CTL,  LEV,  NAC,  PG,  PIL,  PRX,  RCD, 

STP,  SWT,  TXT,  UNP. 
ARD,  ATR,  CTL,  NAC,  RCD,  RZL,  STP,  SWT,  TXT. 
RCD. 
BLA,  CP,  PRX,  RCD,  TXT,  UCC. 


MAR. 

CRZ. 

CRZ, 

CWP,    LKY, 

LPC,   MAR,    PSP 

MAR, 

PSP. 

CRZ, 

PSP. 

LPC, 

MAR. 

CRZ, 

CWP,   MAR, 

WVA. 

G. 

SCP. 

CLD, 

CMG,   GGY, 

PFZ. 

G,   MRA,    S. 

PFZ. 

DUP, 

G,    GRD,    NAC. 

G,    PFZ. 

GGY. 

NLC. 

NLC. 

DUP, 

NOP,    ONX. 

DUP. 

DUP. 

UDI. 

UDI. 

DUP. 

ICO, 

RBC. 

DOW. 

CIB. 

SIN,  SON. 


SURFACE-ACTIVE  AGENTS 


149 


TABLE  19B. — Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1 965-  -Continued 


Manufacturers '    identification  codes 
(according  to  list  in  table  22) 


NONBENZENOID  SURFACE-ACTIVE  AGENTS 
Not  Sulfated  or  Sulfonated 

*Amides,   amines,   and  quaternary  ammonium  salts: 

*Amines,   amine  oxides,   and  amine  salts   (except  hetero- 
cyclic) : 
*Amine  salts  of  fatty  acids   (anionic): 

Coconut  oil  acids,   triethanolamine  salt 

Oleic  acid,   diethylamine  salt 

Oleic  acid,   N-(tallow  allsyl ) trimethylenedianri ne 
salt. 

Oleic  acid,   triethanolamine  salt 

Stearic  acid,   N,N,N',N'-tetrakis(2-hydroxyethyl)- 
ethylenediamine  salt. 

Stearic  acid,   triethanolamine  salt 

^Amines,   not  containing  oxygen,   and  salts  thereof: 
"Amine  salts   ( cationic ) : 

(Coconut  oil  allsyl) amine  acetate 

N-( Coconut  oil  allsyl)  trimethylenediamine  acetate--- 

( Hydrogenated  tallow  aliyl)amine  acetate 

(9-0ctadecenyl) amine  acetate 

Octadecylamine  acetate 

Octylamine  acetate 

(Soybean  oil  allsyl) amine  acetate 

(Tallow  aliyl)amine  acetate 

N-(Tallow  alkyl) trimethylenedianri ne  acetate 

N-(Tallow  aliyl)trimethylenediamine  naphthenate 

"Diamines  and  polyamines : 

N-(  Coconut  oil  alliyl ) trimethylenedianri ne 

N-(Mixed  allsyl) polyethylenepolyamine 

*N-(9-0ctadecenyl)trimethylenediamine 

N-(Soybean  oil  allsyl)  trimethylenediamine 

N-( Tallow  allsyl  )dipropylenetriamine 

*N-( Tallow  allsyl)  trimethylenediamine 

"Primary  monoamines : 

*(  Coconut  oil  aliyl)amine 

(Cottonseed  oil  allsyl)  amine 

"Dodecylamine 7 

Hexadecylamine 

*( Hydrogenated  tallow  aliyl)amine 

(Mixed  allsyl) amine 

9-0ctadecenylami  ne 

Octadecylamine 

Octylamine 

(Soybean  oil  alkyl) amine 

(Tall  oil  aliyl)amine 

*( Tallow  allsyl) amine 

"Secondary  and  tertiary  monoamines : 

Bis(coconut  oil  allsyl)amine 

Bis ( hydrogenated  tallow  allsyl)amine 

N, N-Dimethyl( coconut  oil  aliyl)amine 

N, N-Dimethyldodecylamine 

N, N- Dime thy  lhexadecylamine 

N,N-Dimethyl(hydrogenated  tallow  aliyl)amine 

N,N-Dimethyl(inixed  alily)amine 

N,  N-Dimethyloctadecylami  ne 

N,N-Dimethyl( soybean  oil  allsyl) amine 

N,  N-Dimethyltetradecylami  ne 

N-Methylbis( coconut  oil  alkyl)amine 

N-Methy Ibis ( hydrogenated  tallow  allsyl) amine 

N-Methyldioctadecylamine 

Tridodeeylami  ne 

Trioctylamine 

Tris( hydrogenated  tallow  alkyl)amine 

"Oxygen- containing  amines  and  ami  ne  oxides : 

N, N-Bis ( 2-hydroxyethyl ) dodecylami  ne 

N,N-Bis(2-hydroxyethyl)octadecylamine 

N, N-Bis (2-hydroxyethyl) octylamine 

N, N-Bis (2-hydroxyethyl) (tallow  aliyl)amine 

N,N-Bis(2-hydroxyethyl)(tallow  allsyl) amine  acetate— 


WTC. 

FOR. 

DOM, 

HAL, 

TCC, 

TXT. 

ICI. 

AML, 

GLY, 

TCC. 

ADM, 

ARC, 

FOR. 

ARC. 

ADM, 

ARC. 

GNM. 

ACY, 

ARC. 

ARC. 

ARC. 

ADM, 

ARC, 

FOR, 

GNM. 

ARC, 

FOR. 

APD, 

FOR. 

ARC, 

FOR, 

GNM. 

CCW. 

ARC, 

FOR, 

GNM. 

ARC. 

GNM. 

ARC, 

FOR, 

GNM. 

ADM, 

ARC, 

CGL, 

FOR,    GNM. 

FOR. 

ADM, 

ARC, 

FOR, 

GNM. 

ADM, 

ARC, 

FOR. 

ADM, 

ARC, 

CGL, 

FOR,    GNM,    HUM,    VGC 

GNM. 

ARC, 

FOR, 

GNM. 

ADM, 

ARC, 

FOR, 

GNM. 

ARC, 

RH, 

UCC. 

ARC, 

CGL. 

FOR, 

GNM. 

ADM, 

ARC, 

CGL, 

FOR,    GNM,    HUM. 

ARC, 

FOR. 

ARC. 

PG. 

BC. 

ARC, 

BC. 

ARC. 

BRD, 

PG, 

SDH, 

X. 

ARC, 

BC, 

PG. 

ARC. 

ARC, 

BC. 

FOR, 

GNM. 

ARC, 

FOR, 

GNM. 

FOR. 

GNM. 

GNM. 

GNM. 

FIN. 

FIN. 

FIN. 

FIN. 

PG. 

150 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 

TABLE  19B  -Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
lAtf^c  i»d.  j  manufacturer,  1 965— Continued 


NONBENZENOID  SURFACE-ACTIVE  AGENTS— Continued 
Not  Sulfated  or  Sulfonated- -Continued 

*Amides,  amines,  and  quaternaiy  ammonium  salts— Continued 
*Amines,  amine  oxides,  and  amine  salts  (except  hetero- 
cyclic)— Continued 
*Oxygen-containing  amines  and  amine  oxides— Continued 

(Coconut  oil  alkyl)amine,  ethoxylated 

(Coconut  oil  alkyl)amine,  ethoxylated,  acetate 

Hexadecyldimethylamine  oxide 

( Hydrogenated  tallow  alkyl)amine,  ethoxylated—--— 
N-(2-Hydroxyethyl)-N,N',N'-tris(2-hydroxypropyl)- 
ethylenediamine . 

3-Lauramido-N, N-dimethylpropylamine  oxide 

*(Mixed  alkyl)amine,  ethoxylated 

Octadecylamine,  ethoxylated 

Poly ethy lenepolyamine ,  alkoxylated 

Rosin  amine,  ethoxylated 

(Soybean  oil  aliyl) amine,  ethoxylated 

*(Tallow  alkyl)amine,  ethoxylated 

N-(Tallow  aliyljtrimethylenediamine,  ethoxylated— - 
N, N, N', N '-Tetrakis( 2-hydroxyethyl)ethylenediamine-- 
N,  N,  N ' ,  N '-Tetrakis ( 2-hydroxypropyl) ethylene- 
diamine,  propoxylated  and  ethoxylated. 

Triethanolamine,  ethoxylated 

All  other 

*Fatty  acid  -  alkanolamine  condensates : 
*Diethanolamine  condensates : 

*Capric  acid 

Castor  oil  acids 

*Coconut  oil  acids  (amine/acid  ratio=2/l) 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


*Coconut  oil  acids  (amine/acid  ratio=l/l)- 


Coconut  oil  acids  (all  other  ratios) 

Coconut  oil  and  tallow  acids  (amine/acid  ratio=2/l)  — 
*Laurie  acid 


Laurie  and  myristic  acids 

Linoleic  acid 

Mixed  fatty  acids 

*01eic  acid  (amine/acid  ratio=2/l)- 
*01eic  acid  (amine/acid  ratio=l/l)- 

Palmitic  acid 

Pelargonic  acid 

♦Stearic  acid 


*Tall  oil  acids 

Tallow  acids 

♦Other  alkanolamine  condensates : 

*Coeonut  oil  acids  -  ethanolamine  condensate 

Coconut  oil  acids  -  isopropanolamine  condensate 

♦Laurie  acid  -  ethanolamine  condensate 

♦Laurie  acid  -  isopropanolamine  condensate 

Laurie  and  myristic  acids  -  isopropanolamine 
condensate . 

Myristic  acid  -  ethanolamine  condensate 

Myristic  acid  -  isopropanolamine  condensate 

Oleic  acid  -  ethanolamine  condensate 

isopropanolamine  condensate 

ethanolamine  condensate  (amine/acid 


Oleic  acid 
♦Stearic  acid 

ratio=l/l) . 
Stearic  acid 

ratio=l/2). 
All  other 


APD,  ARC,  NLC,  VAC. 

RPC. 

ONX. 

CIB,  TCH,  VAC. 

NLC. 

SNW. 

APD,  CIB,  G,  NOP,  RH. 

ARC,  ICI. 

NLC. 

HPC,  PCS,  RTF. 

ARC,  VAC. 

ADM,  ARC,  CIB,  DUP. 

ARC. 

NLC. 

WYN. 

JCC. 


GGY,  PCS,  RZL. 

PCS,  VAL. 

AML,  ARD,  BSC,  CIB,  CLI,  CRT,  CTL,  DEP,  DRW,  EFH,  HLI, 

HRT,  JOR,  KNP,  LEV,  LUR,  MOA,  NOP,  ONX,  PC,  PCS,  PNX, 

RCD,  RZL,  SBC,  SEY,  STP,  SWT,  TCC,  TXC,  UNN,  UVC, 

VAC,  VND,  WIC,  WTC. 
APX,  ARD,  ARL,  CLI,  CTL,  DRW,  EMK,  GGY,  HLI,  MOA,  MRV, 

NOP,  ONX,  PCS,  PEK,  QCP,  RCD,  RTF,  RZL,  SBC,  SEY, 

STP,  TXT,  VAC. 
JRG,  PCS. 
PG. 
ARD,  CLI,  CTL,  HLI,  MOA,  ONX,  PCS,  PG,  RCD,  RTF,  RZL, 

SBC,  STP,  TXT,  WON,  WTC. 
CLI. 
VND. 

BSC,  HLI,  STP,  WTC. 

CCW,  CLI,  HLI,  MRA,  ONX,  SEY,  STP,  UVC,  VAC,  WTC. 
CUL,  GGY,  NOP,  PCS,  SBC,  SCP,  SEY,  SWT,  TCC,  TXT,  VAC. 
CMG. 
EMR. 
AML,  BSC,  CLI,  DEP,  EMR,  GGY,  GLY,  JOR,  MRA,  NOP,  ONX, 

RPC,  SCO,  SEY,  TXC,  UVC,  VAL,  WTC. 
EFH,  MRA,  MRV,  UVC,  WTC. 
PCS,  RPC. 


ethanolamine  condensate  (amine/acid 


APX,  CCL,  CTL,  HRT,  MOA, 

LEV,  STP. 

CTL,  PCS,  TXT,  WTC. 

ARD,  CLI,  MOA,  PCS,  WTC. 

TXT. 

WTC. 
ARD. 
ARD. 
WTC. 
ARC,  ARD,  MOA,  VND,  WTC. 

GLY,  WTC. 

CLI,  GLY. 


PCS,  PG,  STP,  TXT,  UVC,  VND. 


SURFACE-ACTIVE  AGENTS 


151 


TABLE  19B. — Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


NONBENZENOID  SURFACE-ACTIVE  AGENTS— Continued 

Not  Sulfated  or  Sulfonated— Continued 

*Amides,  amines,  and  quaternary  ammonium  salts — Continued 
*Fatty  acid  -  diamine  and  polyamine  condensates : 
Adipic  and  stearic  acids  -  diethylenetriamine 
condensate. 

Coconut  oil  acids  -  diethylenetriamine  condensate 

Coconut  oil  acids  -  N, N-dimethyltrimethylenediamine 
condensate. 

Mixed  fatty  acid  -  polyaliylenepolyamine  condensate 

Oleic  acid  -  (2-aminoethyl)piperazine  condensate 

*01eie  acid  -  diethylenetriamine  condensate 

Oleic  acid  -  diethylenetriamine  condensate,  acetic 

acid  salt. 
Oleic  acid  -  N, N-dimethyltrimethylenediamine  conden- 
sate. 
Oleic  acid  -  N, N-dimethyltrimethylenediamine  conden- 
sate, caproic  acid  salt. 
*01eie  acid  -  ethylenediamine  condensate  (amine/acid 
ratio=l/2). 

Pelargonic  acid  -  tetraethylenepentamine  condensate 

Stearic  acid  -  diethylenetriamine  condensate 

Stearic  acid  -  N,N-diethylethylenediamine  condensate 

Stearic  acid  -  N,N'-diethylethylenediamine  condensate 
( amine/acid  ratio=l/2 ) . 

Stearic  acid  -  dipropylenetriamine  condensate 

Stearic  acid  -  ethylenediamine  condensate  (amine/acid 
ratio=l/2). 

Stearic  acid  -  tetraethylenepentamine  condensate 

Tall  oil  acids  -  diethylenetriamine  condensate 

All  other 

*Fatty  acid  -  diamine  and  polyamine  condensates,  alkoxy- 
lated: 
Coconut  oil  acids  -  diethylenetriamine  condensate, 

polyethoxylated . 
Coconut  oil  acids  -  ethylenediamine  condensate,  mono- 

ethoxylated. 
Mixed  fatty  acids  -  alkylenediamine  condensate,  poly- 
ethoxylated. 
*01eic  acid  -  ethylenediamine  condensate,  monoethoxy- 
lated. 
Palm  oil  acids  -  ethylenediamine  condensate,  mono- 

ethoxylated. 
Stearic  acid  -  diethylenetriamine  condensate,  poly- 
ethoxylated . 
*Stearic  acid  -  ethylenediamine  condensate,  mono- 
ethoxylated . 
Stearic  acid  -  ethylenediamine  condensate,  poly- 
ethoxylated. 
^Heterocyclic  amines  and  quaternary  ammonium  salts : 
* Imidazoline  derivatives : 

l-(2-Aminoethyl)-2-heptadecyl-2-imidazoline 

l-(2-Aminoethyl)-2-(mixed  al)syl)-2-imidazoline 

l-(2-Aminoethyl)-2-nor(tall  oil  aliyl)-2-imidazoline- 
l,l-Bis(carboxymethyl)-2-undecyl-2-imidazolinium 

chloride,  disodium  salt. 
1, 1-Bis( carboxymethyl) -2-undecyl-2-imidazolinium 

hydroxide,  disodium  salt. 
1- Carboxymethyl-2-heptadecyl-l- ( 2-hydroxyethyl) -2- 
imidazolinium  hydroxide,  sodium  derivative,  sodium 
salt. 
l-Carboxymethyl-l-( 2-hydroxyethyl) -2-nonyl-2- 

imidazolinium  chloride,  sodium  salt. 
l-Carboxymethyl-l-( 2-hydroxyethyl) -2-nonyl-2- 

imidazolinium  hydroxide,  sodium  derivative,  sodium 
salt. 
l-Carboxymethyl-l-( 2-hydroxyethyl) -2-undecyl-2- 

imidazolinium  hydroxide,  sodium  derivative,  sodium 
salt. 


APX, 
JRG, 

NOP. 
TXT. 

NLC. 
PCS. 
APD, 
PCS. 

HDG, 

PCS, 

TXT. 

CCW, 

SNW. 

RCD. 

CCW, 

GLY, 

HDG. 

ICI. 
APX, 
CBP. 
SNW. 

CRT, 

DEP, 

HRT, 

ONX, 

QCP,    S. 

JOR. 
CCW, 

CTN, 

GLY, 

ICI, 

NOP. 

ICI, 
NCW. 
EMR, 

ONX. 
TXT, 

VAL, 

VND, 

WM. 

TCC. 

NOP, 

RFC. 

NLC. 

CLD, 

DEX, 

NOP, 

SOC, 

TNA. 

APX. 

TCC. 

AML, 

CLD, 

CMG, 

CST, 

DEP, 

DEX,    ICI,    MRA,    NOP,    S,    SNW 

APD, 

TCC. 

TXT. 
RTF. 
NLC. 
PCS. 

PCS. 
MIR. 


152 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  19B.  —Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


Chemical 


NONBENZENOID  SURFACE- ACTIVE  AGENTS— Continued 

Not  Sulfated   or  Sulfonated--Continued 
*Amides,  amines,  and  quaternary  ammonium  salts — Continued 
heterocyclic  amines  and  quaternary  ammonium  salts — Con. 
"Imidazoline  derivatives — Continued 

l-Ethyl-2-(8-heptadecenyl)-l-(2-hydroxyethyl)-2- 

imidazolinium  bromide. 
2-(8-Heptadeeenyl)-l-(2-hydroxyethyl)-2-imidazoline- 

2-(8-Heptadecenyl)-2-imidazoline 

*2-Heptadecyl-l-(2-bydroxyethyl)-2-imidazoline 

2-Heptadecyl-2-imidazoline 

l-(2-Hjrdroxyetnyl)-2-nonyl-2-imidazoline 

l-(2-Ifydroxyetnyl)-2-nor(  coconut  oil  alkyl ^-imid- 
azoline. 
l_(2-[tydroxyethyl)-2-nor(tall  oil  aliyl) -2-imid- 

azoline. 
l-(2-Ifydroxyethyl)-2-tridecyl-2-imidazolinium  chlo- 
ride. 

l-(2-Ifydroxyetbyl)-2-undecyl-2-imidazoline 

2-(ll-Ifydroxy-8-heptadecenyl)-2-imidazoline 

Rosinpolyamidoimidazoline 

3- [2- (2-Undecyl-2-imidazolin-l-yl)ethoxy] propionic 
acid. 
*Mbrpholine,  oxazoline,  and  piperazine  derivatives: 

N-Dodeeylmorpholine 

2-(  8-Heptadecenyl )  -4,4-bis  ( hydroxymethyl) -2-oxazo- 

line. 
2-(8-Heptadecenyl)-4-hydroxymethyl-4-methyl-2-oxazo 

line. 

N-Hexadecylmorpholine 

Mixed  fatty  piperazines 

N-(Soybean  oil  aliy 1 )morpholine 

"Quaternary  ammonium  salts  (except  heterocyclic): 

*Bis(coconut  oil  alkyljdimethylammonium  chloride 

*Bis(hydrogenated  tallow  alkyl)dimethylammonium  chlo- 
ride. 

*Dimethyldioctadecylammonium  chloride 

*Dodecyltrimethylammonium  chloride 

"Oxygen-containing  compounds: 

Bis(2-hydroxyethyl,  ethoxylated)methyl(9-octa- 

decenyl)ammonium  chloride. 
Bis( 2-hydroxyethyl,  ethoxylated)methyloctadecyl- 

ammonium  chloride. 

N-(3-Coconut  oil  amidopropyl)betaine 

(Coconut  oil  alkyl)betaine 

(Coconut  oil  alkyl)bis(2-hydroxyethyl,  ethoxylated) 

methylammonium  chloride. 

C-Decylbetaine 

C-Dodecylbetaine 

N-Dodecylbetaine 

C-Hexadecylbetaine 

(2-Ifydroxyethyl)dimethyl(stearamidopropyl) ammonium 

dihydrogen  phosphate. 
( 2-Hydroxyethyl) dimethyl( stearamidopropyl) ammonium 

nitrate. 
2-}fydroxytrimethylenebis[( coconut  oil  aHsyl)di- 

methylammonium  chloride] . 

Mixed  fatty  betaines 

C-Octadecylbetaine . 

Triethyl(octadecyloxymethyl) ammonium  chloride 

Other  quaternary  ammonium  salts : 

(Coconut  oil  aliyl)trimethylammonium  chloride 

Didodecyldimethylammonium  bromide 

Dimethylbis( soybean  oil  aliyl) ammonium  chloride 

Dodecyltrimethylammonium  bromide 

Ethyldimethyl(9-octadecenyl) ammonium  bromide 

Ethyldimethyl( soybean  oil  alkyl) ammonium  bromide — 
Ethylhexadecyldimethylammonium  bromide 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


NLC,  PCS,  UVC. 

HDG,  MOA,  ONX,  RZL,  TXT. 


GGY, 

PCS, 

UVC. 

GRD. 

UVC. 

UVC. 

BC. 

COM, 

UVC. 

COM, 

UVC. 

APD. 

TXT. 

APD. 

ARC, 

FOR, 

GNM, 

VAC. 

ADM, 

ARC, 

FOR, 

GNM,    VAC 

FOR, 

GNM, 

PC. 

ARC, 

FOR, 

GNM. 

RCD. 
CUL. 
ARC,  VAC. 

DUP. 
DUP. 
RCD. 
DUP. 
ACY. 

ACY. 


TXT. 
DUP. 
DAN. 

ARC,  GNM. 

ONX. 

ARC. 

DUP. 

ONX. 

BC. 

FIN. 


SURFACE-ACTIVE  AGENTS 


153 


TABLE  19B.  —Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


NONBENZENOID  SURFACE- ACTIVE  AGENTS— Continued 

Not   Sulfated   or  Sulfonated— Continued 

•Amides,  amines,  and  quaternary  ammonium  salts — Continued 
•Quaternary  ammonium  salts  (except  heterocyclic)  —  Con. 
•Other  quaternary  ammonium  salts — Continued 

Hexadecyltrimethylammonium  bromide 

Hexadecyltrimethylammonium  chloride 

Hexadecyltrimethylammonium  stearate 

( Hydrogenated  tallow  aliyl )trime thy lammonium  chlo- 
ride. 

Methyltriocty lammonium  chloride 

lfethyltris( mixed  aliyl) ammonium  chloride 

N,  N,  N ' ,  N' ,  N' -Pentamethyl-N- ( tallow  aliyl) trimethyl- 
enebis [ammonium  chloride]. 

Trimethyl(mixed  aliyl) ammonium  chloride 

Trimetbyloctadecylammonium  chloride 

Trimethyl( soybean  oil  aliyl) ammonium  chloride 

Trimethyl( tallow  aliyl) ammonium  chloride 

All  other 

•N-Substituted  amino  acids  and  polypeptides : 

N-[ 2-( Carboxymethylamino) ethyl] -N-( 2-hydroxyethyl) - 
coconut  oil  amide,  sodium  salt. 

N-( Coconut  oil  acyl)sarcosine 

N-( Coconut  oil  acyl)sarcosine,  sodium  salt 

N-( Coconut  oil  aliyl) -|3 -alanine 

N-Dodecyl-3-iminodipropionic  acid 

N-Dodecyl-3- inn nodipropionic  acid,  sodium  salt 

N-(2-Hydroxyethyl)-N-(2-lauramidoethyl)-|3-alanine 

N-(2-Hydroxyethyl)-N-(2-stearamidoethyl)glycine 

N-Lauroylpolypeptide 

*N-Iauroylsarcosine,  sodium  salt 

N-Oleoylpolypeptide 

N-Oleoylpolypeptide,  sodium  salt 

N-Oleoylsarcosine,  sodium  salt 

Polypeptide 

N-Stearoylsarcosine,  sodium  salt 

N-(  Tallow  aliyl) -3-i"  mi  nodipropionic  acid,  sodium  salt 
•Other  amides,  amines,  and  quaternary  ammonium  salts: 
N, N-Bis( 2-hydroxyethyl) -2- ( stearamidomethoxy ) ethyl- 

amine. 
N, N-Bis( 2-hydroxyethyl) -2-( stearamidomethoxy ) ethyl- 

amine  -  melamine  ether  condensate. 
Bis [octadecenyloxypolyethylene  glycol] ester  of  1,6- 

hexamethylenedicarbamic  acid. 
Coconut  oil  acids  -  ethanolamine  condensate,  ethoxy- 

lated. 
Coconut  oil  acids  -  isopropanolamine  condensate, 
ethoxylated  and  propoxylated. 
•Hydrogenated  tallow  acids  -  ethanolamine  condensate, 
ethoxylated. 

•Oleic  acid  -  ethanolamine  condensate,  ethoxylated 

Oleic  acid  -  methanolamine  condensate,  ethoxylated 

Stearic  acid  -  N- ( 2-eyanoethyl ) diethylenetriami  ne 

condensate  (amine/acid  ratio=l/2). 
Tall  oil  acids  -  ethanolamine  condensate,  ethoxylated- 
•Carboxylic  acid  esters : 

•Ethylene  glycol  and  diethylene  glycol  esters : 

Diethylene  glycol  distearate 

methylene  glycol  monoester  of  coconut  oil  acids 

Diethylene  glycol  monoester  of  tallow  acids 

•Diethylene  glycol  monolaurate 

•Diethylene  glycol  mono-oleate 

Diethylene  glycol  monoricinoleate 

•Diethylene  glycol  monostearate 

Diethylene  glycol  sesquilaurate 

Diethylene  glycol  sesquioleate 

Diethylene  glycol  sesquistearate 

Diethylene  glycol  tall  oil  ester 


DUP, 

FIN,    I CI. 

ARC. 

FIN. 

ARC, 

FOR. 

GNM. 

VAC. 

ARC, 

GNM. 

GNM. 

ARC, 

GNM. 

ARC, 

FOR. 

ARC, 

FOR,    GNM. 

CGL. 

TCC. 

GGY. 

HMP. 

GNM. 

GNM. 

GNM. 

UVC. 

G. 

MYW. 

CP, 

GGY,    HMP,    ONX. 

MYW. 

I1C. 

G,   GGY. 

MYW. 

GGY. 

GNM. 

CIB. 

CIB. 

CIB. 

DRW, 

STP. 

STP. 

ARC, 

DRW,    NOP. 

ARC, 

DRW,    G. 

G. 

CIB. 

JCC. 

ARC. 

DRW. 

DRW. 

ARC, 

CCW,    DRW,    EMR, 

GLY, 

HAL, 

HDG, 

KAL, 

NOP, 

WTC 

ARC, 

HAL,    WTC. 

GLY. 

AML, 

ARC,    CCW,    CLI, 

HAL, 

NOP, 

PCS, 

QCP, 

SEY, 

UVC 

VAL,   VND,   WTC. 

GLY. 

^ 

GLY. 

GLY, 

WM. 

HDG, 

QCP,   WTC. 

154 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  19B. — Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


NONBENZENOID  SURFACE- ACTIVE  AGENTS— Continued 

Not   Sulfated  or  Sulfonated--Continued 

♦Carboxylic  acid  esters — Continued 
♦Ethylene  glycol  and  diethylene  glycol  esters — Continued 

♦Ethylene  glycol  distearate 

Ethylene  glycol  mono-oleate 

♦Ethylene  glycol  monostearate 

Ethylene  glycol  sesquistearate 

♦Glycerol  esters : 

♦Complex  glycerol  esters : 

Glycerol  diacetyl  tartrate  monostearate 

Glycerol  lactate  palmitate 

Glycerol  lactate  stearate 

Glycerol  maleate  mono-oleate 

Glycerol  monoester,  acetylated 

Glycerol  mono-oleate,  acetylated 

♦Glycerol  esters  of  chemically  defined  acids : 

Glycerol  dioleate 

Glycerol  distearate 

Glycerol  monocaprylate 

♦Glycerol  monolaurate 

♦Glycerol  mono-oleate 

Glycerol  monoricinoleate 

♦Glycerol  monostearate 

♦Glycerol  esters  of  mixed  acids : 

Glycerol  diester  of  lard  acids 

Glycerol  monoester  of  coconut  oil  acids 

Glycerol  monoester  of  cottonseed  oil  acids 

Glycerol  monoester  of  hydrogenated  cottonseed  oil 

acids. 
Glycerol  monoester  of  hydrogenated  soybean  oil  acids 

Glycerol  monoester  of  lard  acids 

Glycerol  monoester  of  mixed  fatty  acids 

Glycerol  monoester  of  peanut  oil  acids 

Glycerol  sesquiester  of  mixed  fatty  acids 

♦Polyethylene  glycol  esters : 

♦Polyethylene  glycol  esters  of  chemically  defined 
acids : 

♦Polyethylene  glycol  dilaurate 

♦Polyethylene  glycol  dioleate 

♦Polyethylene  glycol  distearate 

Polyethylene  glycol  methylcarbitol  maleate 

♦Polyethylene  glycol  monolaurate 

♦Polyethylene  glycol  mono-oleate 

Polyethylene  glycol  monopalmitate 

Polyethylene  glycol  monoricinoleate 

♦Polyethylene  glycol  monostearate r 

Polyethylene  glycol  pelargonate 

Polyethylene  glycol  sesquioleate 

♦Polyethylene  glycol  esters  of  mixed  acids : 

♦Polyethylene  glycol  ester  of  castor  oil  acids 

♦Polyethylene  glycol  ester  of  coconut  oil  acids 

♦Polyethylene  glycol  ester  of  rosin  acids 

♦Polyethylene  glycol  ester  of  tall  oil  acids 

♦Polyethylene  glycol  ester  of  tallow  acids 

Polyethylene  glycol  monoester  of  soybean  oil  acids- 
All  other 


ARC,  EMR,  HAL,  HDG. 

PCS. 

ARC,  CCW,  CLI,  EFH,  GLY,  HAL,  HDG,  KNP,  VND,  WM. 

WM. 


DRW,  PCS,  WTC. 
DRW,  GLD. 
APD,  GLD. 
NOP,  WTC. 


EK. 


ARC,  HAL. 

APX,  ARC,  PCS. 

ARC. 

ARC,  GLX,  HAL,  KNP. 

APD,  ARC,  CCW,  DRW,  EFH,  EK,  EMR,  GLY,  HAL,  HDG,  SWT, 

WM. 
CCW. 
ARC,  CCW,  CHL,  CRT,  DRW,  EK,  EMR,  GLY,  HAL,  HDG,  JRG. 

LUR,  MRA,  NOP,  NW,  PCS,  PG,  SNW,  SWT,  TCC,  UVC,  VND. 

WM,  WTC,  x. 

PCS. 

DRW,  GLY,  HDG,  SWT,  WM. 

DRW,  EK,  PCS. 

LEV. 

DRW. 

EK,  GLD,  PCS. 

EFH,  EK,  GLD,  HDG,  LEV,  SWT,  WTC. 

DRW. 

APD. 


ARC,  DEX,  EFH,  GLY,  HAL,  HDG,  JOR,  NOP,  PCS,  WM. 
ARC,  CLD,  EFH,  GGY,  GLY,  HAL,  HDG,  NOP,  PCS,  RZL,  SM, 

UVC,  VND. 
ARC,  GLY,  HAL,  HDG,  PCS,  QCP. 
CCA. 
AAC,  ARC,  BSC,  CCA,  DEX,  DRW,  GGY,  GLY,  HAL,  HDG,  JOR, 

KNP,  NOP,  PCS,  SYC,  TCH,  TXT,  UVC,  WM. 
AAC,  ARC,  CCA,  CLD,  CRC,  CRT,  DEX,  DRW,  EMR,  G,  GGY, 

GLY,  HAL,  HDG,  I  CI,  NOP,  ONX,  PCS,  SM,  SWT,  SYC,  TCH, 

UVC,  VAC,  WM,  WTC. 
APD. 

AAC,  ARC,  BAC,  NOP. 
AML,  APD,  ARC,  CRT,  DEP,  DEX,  DRW,  EMR,  G,  GGY,  GLY, 

HAL,  HDG,  ICI,  KNP,  NOP,  ONX,  PC,  PCS,  PD,  RH,  TCC, 

TCH,  VND,  WTC. 
EMR. 
PCS. 

G,  GGY,  GLY,  HAL,  NOP,  WTC. 

ARC,  ARL,  DRW,  EMR,  GLY,  NOP,  ONX,  PG,  VND. 

APD,  HPC,  NLC,  CJCP. 

AML,  APD,  APX,  ARC,  DRW,  GLY,  HDG,  MON,  NOP,  RTF,  SOS, 

TCH,  WTC. 
DRW,  ONX,  SOS. 
DRW. 
GLY,  PCS,  SYC. 


SURFACE-ACTIVE  AGENTS 


155 


TABLE  19B  —Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


NONBENZENOID  SURFACE-ACTIVE  AGENTS- -Continued 
Not  Sulfated  or  Sulfonated--Co.nti.nued 

*Carboxylic  acid  esters — Continued 
*Polyglycerol  esters : 

Polyglyeerol  distearate 

Polyglyeerol  lactate  oleate 

Polyglyeerol  monoester  of  cottonseed  oil  acids 

Polyglyeerol  oleate 

Other  carboxylic  acid  esters: 
Anhydrosorbitol  esters : 

Arihydrosorbitol  dioleate 

Anhydrosorbitol  mixed  fatty  acid  ester 

Arihydrosorbitol  monolaurate 

Anhydrosorbitol  mono-oleate 

Anhydrosorbitol  monopalmitate 

Anhydrosorbitol  monostearate 

Anhydrosorbitol  sesquioleate 

^Anhydrosorbitol  tall  oil  ester 

Anhydrosorbitol  tetrastearate 

^Anhydrosorbitol  trioleate 

Anhydrosorbitol  triricinoleate 

*Anhydrosorbitol  tristearate 

Ethoxylated  anhydrosorbitol  esters : 

Ethoxylated  anhydrosorbitol  castor  oil  ester 

*Ethoxylated  anhydrosorbitol  monolaurate 

*Ethoxylated  anhydrosorbitol  mono-oleate 

*Ethoxylated  anhydrosorbitol  monopalmitate 

*Ethoxylated  anhydrosorbitol  monostearate 

Ethoxylated  anhydrosorbitol  tall  oil  ester 

*Ethoxylated  anhydrosorbitol  trioleate 

^■Ethoxylated  anhydrosorbitol  tristearate 

Ethoxylated  sorbitol  esters : 

Ethoxylated  sorbitol  beeswax  ester 

Ethoxylated  sorbitol  distearate 

Ethoxylated  sorbitol  hexaoleate 

Ethoxylated  sorbitol  hexa(tall  oil)  ester 

Ethoxylated  sorbitol  lanolin  ester 

Ethoxylated  sorbitol  mono-oleate 

Ethoxylated  sorbitol  oleate  stearate 

Ethoxylated  sorbitol  pentalaurate 

Ethoxylated  sorbitol  pentaoleate,  acetylated 

Ethoxylated  sorbitol  penta(tall  oil)  ester 

Ethoxylated  sorbitol  tetra(laurate,  oleate) 

Ethoxylated  sorbitol  tetra(tall  oil)  ester 

All  other: 

Anhydrosorbitol  glycerol  monolaurate 

Calcium  stearolactate 

Coconut  oil  acids,  ethoxylated  methanol  ester 

Diisobutylene  maleate 

Ethoxylated  glucose  oleate 

Ethoxylated  glycerol  mono-  and  diester  of  mixed 
fatty  acid. 

Ethoxylated  1,2-propanediol  stearate 

Methyl  glucoside  laurate 

Methyl  glucoside  oleate 

Pentaerythritol  distearate 

Polyalkylene  glycol  diglycolate 

Polyalkylene  glycol  dimaleate 

Polyaliylene  glycol  naphthenate 

1,2-Propanediol  distearate 

1,3-Propanediol  monoester  of  coconut  oil  acids-- 

*l,2-Propanediol  monolaurate 

1,2-Propanediol  mono-oleate 

»l,2-Propanediol  monostearate 

Propylene  glycol  monoesters 

Sucrose  esters  of  fatty  acids 

*Ethers : 

*Castor  oil,  ethoxylated 

n-Decyl  alcohol,  ethoxylated 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


PCS. 
DEW. 
DRW. 
DRW,  HDG,  VND,  WTC. 


APD. 

GLY. 

AAC,  APD,  GLY,  HDG,  PCS. 

AAC,  APD,  DRW,  GLY,  HDG,  PCS. 

APD,  GLY,  PCS. 

AAC,  APD,  DRW,  GLY,  HDG,  PCS. 

GLY. 

APD,  GLY,  HDG,  RTF. 

APD. 

AAC,  APD,  GLY,  HDG,  PCS. 

APD. 

APD,  DRW,  GLY,  HDG,  PCS. 

APD. 

AAC,  APD,  DRW,  GLY,  HDG,  PCS,  TCH. 

AAC,  APD,  ARC,  DRW,  GLY,  HDG,  PCS,  TCH. 

AAC,  APD,  GLY,  TCH. 

AAC,  APD,  DRW,  GLY,  HDG,  PCS,  TCH. 

APD,  RTF,  TCH. 

AAC,  APD,  GLY,  TCH. 

AAC,  APD,  DRW,  GLY,  PCS,  TCH. 

APD. 
APD. 
APD. 
APD. 
APD. 
APD. 
APD. 
APD. 
APD. 
APD. 
APD. 
APD. 

APD. 

GLY. 

DRW,  JOR. 

RH. 

APD. 

APD. 


APD. 

HDG. 

HDG. 

VAL. 

NLC,  RTF. 

NLC. 

APD. 

HAL,  PCS. 

DRW. 

ARC,  HAL,  SBC,  WM. 

ARC,  HAL. 

APD,  ARC,  CCW,  EK,  GLY,  HAL,  HDG, 

GLD. 

SUG. 


JRG,  PCS,  PG,  WTC. 


AAC,  APD,  BAC,  DRW,  ICI, 
G,  ICI,  PCS. 


NLC,  NOP,  PCS,  RTF,  TCH,  VAC. 


156 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  19B. 


-Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


NONBENZENOID  SURFACE-ACTIVE  AGENTS- -Continued 

Not   Sulfated  or  Sulfonated--Cor\tinued 

*Ethers —  Continued 

n-Decyl  and  n-octyl  alcohols,  ethoxylated 

Deoyloxypoly(ethyleneoxy) ethyl  chloride 

*n-Dodecyl  alcohol,  ethoxylated 

Glucose,  ethoxylated 

n-Hexadecyl  alcohol,  ethoxylated 

Hydrogenated  castor  oil,  ethoxylated 

*Lanolin,  ethoxylated 

»Mixed  linear  alcohols,  ethoxylated 

Mixed  linear  alcohols,  ethoxylated  and  propoxylated— 

*9-0ctadecenyl  alcohol,  ethoxylated 

*n-Octadecyl  alcohol,  ethoxylated 

Polyethylene  glycol  tert-dodecyl  thioether 

Poly(mixed  ethylene,  propylene)  glycol 

Polypropylene  glycol,  ethoxylated 

Ricinoleyl  alcohol,  propoxylated  and  ethoxylated 

Rosin  alcohol,  ethoxylated 

Sorbitol,  ethoxylated 

Sperm  oil  alcohol,  ethoxylated 

Tallow  alcohol,  ethoxylated 

*Tridecyl  alcohol,  ethoxylated 

Tridecyl  alcohol,  propoxylated  and  ethoxylated 

Trimethylheptanol,  ethoxylated 

Trimethylnonyl  alcohol,  ethoxylated 

Trimethylolpropane,  alioxylated 

All  other 

*Fatty,  rosin,  and  tall  oil  acids,  potassium  and  sodium 
salts : 

Castor  oil  acids,  potassium  salt 

Castor  oil  acids,  sodium  salt 

*Coconut  oil  acids,  potassium  and  sodium  salts: 

Potassium  salt 

Sodium  salt 

Corn  oil  acids,  potassium  salt 

Corn  oil  acids,  sodium  salt 

Laurie  acid,  potassium  salt 

Mixed  vegetable  fatty  acids,  potassium  salt 

Oleic  acid,  potassium  salt 

*01eic  acid,  sodium  salt 

Olive  oil  acids,  sodium  salt 

Palm  oil  acids,  sodium  salt 

Peanut  oil  acids,  potassium  salt 

Rosin  acids,  potassium  salt 

Rosin  acids,  sodium  salt 

Soybean  oil  acids,  potassium  salt 

♦Stearic  acid,  potassium  and  sodium  salts: 

Potassium  salt 

Sodium  salt 

*Tall  oil  acids,  potassium  and  sodium  salts: 

*Tall  oil  acids,  potassium  salt 

*Tall  oil  acids,  sodium  salt 

Tallow  acids,  potassium  salt 

*Tallow  acids,  sodium  salt 

All  other 

♦Phosphoric  and  polyphosphoric  acid  esters : 

Decyl,  dodecyl,  and  octyl  phosphate,  morpholine  salt 

Decyl  and  octyl  phosphate 

Decyl  polyphosphate,  triethanolamine  salt 

Dodecyl  alcohol,  ethoxylated  and  phosphated 

2-Ethylhexanol,  ethoxylated  and  phosphated 

*2-EtnyLhexyl  phosphate,  sodium  salt 

*2-Ethylhexyl  polyphosphate 

2-Ethylhexyl  polyphosphate,  sodium  salt 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


G. 

AAC,  APD,  DRW,  DUP,  GLY,  JCC,  NAC,  OMC,  PCS,  UCC. 

RH. 

ADM,  APD,  CIB,  ICI. 

APD,  VAC. 

AAC,  APD,  DRW,  VAC. 

CO,  G,  JCC,  MON,  NLC,  RH,  RTF,  SHC,  STP,  TCH,  UCC, 

WYN. 
STP. 

AAC,  ADM,  APD,  CIB,  DUP,  G,  ICI,  NOP,  TCH,  VAC. 
AAC,  APD,  CIB,  DUP,  HDG. 
MON. 

nic,  ucc,  vac. 

nlc,  wyn. 

PCS. 
HPC. 
VAC. 
DUP. 
ADM. 
AAC,  APD,  DRW,  EFH,  G,  ICI,  JCC,  MON,  NLC,  CMC,  PCS, 

RTF,  TCH,  UCC. 
JCC,  PCS. 
PCS. 
UCC. 
RTF. 
JCC,  UCC,  VAC,  VPC. 


BAC,  SEA. 
MRV. 

CP,  JRG,  LUR,  PCH,  PG,  SWT. 

CON,  CP,  JRG,  LEV,  PG,  PRX. 

ARL,  PCH. 

LUR. 

BSC,  DRW,  NOP,  USR,  VAL. 

AML,  ARL,  PCH,  SWT. 

AML,  BSC,  CCL,  CIB,  CPY,  DAN,  GYR,  NOP,  QCP,  S,  SHP, 

USR,  WIC,  WTC,  x. 

LEV,  LUR,  MRV,  NOP,  SEA,  SWT,  USR,  WTC,  x. 
LUR. 
LUR. 

KAL,  SLC. 

ASY,  FRS,  HPC. 

ASY,  CRT,  HPC,  MRA,  PLC,  PRX,  QCP. 

CON,  DRW. 

GYR,  WTC. 

GYR,  LEV,  MAL,  NOP,  WTC. 

ASY,  BSC,  CON,  DRW,  FRS,  GYR,  HPC,  LUR,  PNX,  QCP,  TXT, 

USR,  VAL. 

CPY,  GYR,  HPC,  PCS,  PRX,  QCP,  UNP. 

ASY,  CPY,  GYR,  PG,  SWT. 

ASP,  CON,  CP,  FRS,  GYR,  JRG,  LEV,  LUR,  NOP,  PG,  PLC, 

PRX,  QCP,  SWT. 
SLC. 

DUP. 

UVC. 

RCD. 

G. 

WAY. 

RZL,  SEY,  UCC,  UVC. 

SEY,  TCI,  UVC. 

SF. 


SURFACE-ACTIVE  AGENTS 


157 


TABLE   19B. 


-Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


NONBENZENOID  SURFACE- ACTIVE  AGENTS— Continued 

Not  Sulfated  or  Su(/onated--Continued 

*Phosphoric  and  poljrphosphoric  acid  esters — Continued 

Hexyl  polyphosphate,  potassium  salt 

Mixed  aliyl  phosphate,  diethanolamine  salt 

Mixed  linear  alcohols,  ethoxylated  and  phosphated 

Mixed  mono-  and  dialiyl  phosphate 

Mixed  mono-  and  dioctyl  phosphate 

Mixed  mono-  and  dioctyl  phosphate,  potassium  salt 

9-0ctadecenyl  alcohol,  ethoxylated  and  phospnated 

9-0etadecenyl  phosphate 

Octadecyl  phosphate,  triethanolamine  salt 

Octyl  phosphate,  allsylamine  salt 

Octyl  phosphate,  ethoxylated 

Oct;,!  polyphosphate 

Octyl  polyphosphate,  potassium  salt 

Odyl  polyphosphate,  sodium  salt 

Trideeyl  alcohol,  ethoxylated  and  phosphated 

Tris(castor  oil  alkyl)  phosphate 

All  other 

Other  nonbenzenoid  surface-active  agents,  not  sulfated  or 

sulfonated : 

n-Decyl  alcohol,  ethoxylated  and  carbonated 

3,5-Dimethyl-l-hexyn-3-ol 

3,6-Dimethyl-4-octyne-3,6-diol 

2,4.,7,9-Tetramethyl-5-decyne-4,7-diol 

Trideeyl  alcohol,  ethoxylated  and  carbonated,  sodium 

salt. 
All  other 


Sulfated  and  Sulfonated 

*Alcohols ,  sulfated : 

*n-Dodecyl  sulfate  salts : 

n-Dodecyl  sulfate,  2-amino-2-methylpropanol  salt 

*n-Dodeeyl  sulfate,  ammonium  salt 

n-Dodecyl  sulfate,  diethanolamine  salt 

n-Dodecyl  sulfate,  N,N-diethylcyclohexylamine  salt 

n-Dodecyl  sulfate,  isopropanolamine  salt 

n-Dodecyl  sulfate,  magnesium  salt 

n-Dodecyl  sulfate,  potassium  salt 

*n-Dodecyl  sulfate,  sodium  salt 

*n-Dodecyl  sulfate,  triethanolamine  salt 

*A11  other  sulfated  alcohols : 

sec-Aliyl  sulfate,  ammonium  salt 

Branched  hexadecyl  sulfate,  sodium  salt 

Coconut  oil  and  sperm  oil  aliyl  sulfate,  sodium  salt- 

Decyl  and  octyl  sulfate,  sodium  salt 

n-Decyl  sulfate,  sodium  salt 

n-Deeyl  sulfate,  triethanolamine  salt 

3, 9-Diethyl-6- trideeyl  sulfate 

2-Ethylhexyl  sulfate,  sodium  salt 

7-Ethyl-2-methyl-4-undecyl  sulfate 

n-Hexadecyl  sulfate 

Hexyl  sulfate,  potassium  salt 

Nonyl  sulfate 

n-Oetadecyl  sulfate 

n-Octadecyl  sulfate,  sodium  salt 

n-Octadecyl  sulfate,  triethanolamine  salt 

n-Octyl  sulfate,  sodium  salt 

n-Tetradeeyl  sulfate,  sodium  salt 

Trideeyl  sulfate,  sodium  salt 

»Amides,  amines,  and  quaternary  ammonium  salts,  sulfated 
and  sulfonated: 
Fatty  aeid  -  alkanolamine  condensates,  sulfated: 
*Coeonut  oil  acids  -  ethanolamine  condensate,  sulfated. 

potassium  salt. 
Coconut  oil  acids  -  isopropanolamine  condensate, 

sulfated,  sodium  salt. 


CST,  DEX. 

DUP. 

G. 

CST,  DUP. 

DUP. 

DUP. 

G. 

DUP. 

RCD. 

DUP,  TXT. 

DUP. 

BCN,  DEX,  TXT. 

x. 

SF. 

G,  LUR. 

GLY. 

NLC,  SF,  WTC. 


G. 

cue. 
cue. 
cue. 
s. 

G,  GLY,  STC. 


DUP. 

AAC,  CTL,  DUP,  ONX,  PCS,  RCD,  STP,  TXT. 

AAC,  CUL,  DUP,  HLI,  JRG,  ONX,  RCD,  STP. 

DUP. 

JRG,  PCS. 

AAC,  HLI,  STP. 

HLI,  PG,  RCD. 

AAC,  CUL,  DUP,  HLI,  JRG,  LAK,  MYW,  ONX,  PCI,  PCS,  PG, 

RCD,  RET,  STP,  TXT. 
AAC,  CTL,  CUL,  DUP,  HLI,  MYW,  ONX,  PCS,  PG,  RCD,  RET, 

STP,  TXT. 


ucc. 

APX. 

DUP. 

PCS. 

CTL, 

DUP, 

ONX,    PCS. 

DUP. 

UCC. 

AAC, 

UCC, 

WTC. 

UCC. 

AAC, 

DUP. 

DEX. 

TEN. 

DUP, 

EMK. 

ONX, 

PG. 

DUP. 

DUP, 

PCS. 

ONX, 

AAC, 

DUP. 

DEX, 
APX. 

EMK, 

HRT,    ONX. 

158 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 

TABLE  19B  -Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
1AJJL  manufacturer,  1965— Continued 


Chemical 


NONBENZENOID  SURFACE-ACTIVE  AGENTS— Continued 

Sulfated  and  Sulfonated— Continued 
*Amides,  amines,  and  quaternary  ammonium  salts,  sulfated 
and  sulfonated— Continued 
Fatty  acid  -  alkanolamine  condensates,  sulfated— Con. 

Oleic  acid  -  ethanolamine  condensate,  sulfated 

Stearic  acid,  diethanolamine  condensate,  methyl 

sulfate . 
♦Quaternary  ammonium  sulfates : 

(2-Aminoethyl)ethyl(hydrogenated  tallow  alkyl)(2- 

hydroxyethy 1 ) ammonium  ethyl  sulfate. 
Bis(hydrogenated  tallow  alkyl)dimethylammonium 

methyl  sulfate. 

Dimethyldioctadecylammonium  methyl  sulfate 

Ethyldimethyl(mixed  aliyl) ammonium  ethyl  sulfate 

l-Ethyl-2-(8-heptadecenyl)-l-(2-hydroxyethyl)-2- 

imidazolinium  ethyl  sulfate. 

N-Ethyl-N-hexadecylmorpholinium  ethyl  sulfate 

N-Ethyl-N-( soybean  oil  al!syl)morpholinium  ethyl 

sulfate . 
2-Heptadecyl-l-(2-stearamidoethyl)-2-imidazolinium 

methyl  sulfate. 
(3-Lauramidopropyl)trimethylammonium  methyl  sulfate — 

Mixed  fatty  sulfobetaines 

Trimethyl(3-oleamidopropyl)ammonium  methyl  sulfate 

*Sulfosuccinamic  acid  derivatives : 

N-(l,2-Dicarboxyethyl)-N-octadecylsulfosuecinamic 

acid,  tetrasodium  salt. 
N- ( 2-Hydroxyethyl) -N- ( tallow  allsyl) sulf  osuccinamide— 

N-Octadecylsulfosuccinamide,  disodium  salt 

N-(Oleoyloxyisopropyl) sulf osuccinamide 

Taurine  derivatives : 

N-Cyclohexyl-N-palmitoyltaurine 

N-Methyl-N-( coconut  oil  acyl)taurine 

*N-Methyl-N-oleoyltaurine 

N-Methyl-N-paljnitoyltaurine 

N-Methyl-N-(tall  oil  acyl)taurine,  sodium  salt 

N-Methyl-N-( tallow  acyl) taurine 

Other  amides,  amines,  and  quaternary  ammonium  salts, 
sulfated  and  sulfonated: 
N-( 2-Hydroxyethyl) -N,N',N'-tris(2-hydroxypropyl)- 

ethylenediamine,  distearate  methyl  sulfate. 
Laurie  acid,  2-sulfoacetamidoethyl  ester,  potassium 
salt. 

N-(Mixed  alkyl  sulfonyl)glycine,  sodium  salt 

Mixed  primary  amines,  ethoxylated  and  sulfated 

Oleic  acid  -  ethylenediamine  condensate,  propoxylated 

and  sulfated,  sodium  salt. 
Stearic  acid  -  ethylenediamine  condensate,  mono- 

ethoxylated,  ethyl  sulfate. 
Tall  oil  acids  -  polyallsylenepolyamine  condensate, 

sulfated. 
N, N, N' , N ' - Tetrakis ( 2-hydroxypropyl ) ethylenediamine 
dioleate  methyl  sulfate. 
♦Carboxylic  acid  esters  (except  natural  fats  and  oils), 
sulfated  and  sulfonated: 
♦Esters  of  sulfated  oleic  acid: 

2-Butoxyethyl  oleate,  sulfated 

Butyl  oleate,  sulfated 

Ethyl  oleate,  sulfated 

Glycerol  trioleate,  sulfated 

*Isopropyl  oleate,  sulfated 

Methyl  oleate,  sulfated 

♦Propyl  oleate,  sulfated 

♦Sulfosuccinic  acid  esters: 

Sulfosuccinic  acid,  bis(2,6-dimethyl-4-heptyl)ester, 
sodium  salt. 
♦Sulfosuccinic  acid,  bis (2-ethylhexyl) ester 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


SCP. 
DUP. 


ONX. 
JOR. 
APD. 

APD. 

APD. 


ACY. 
TXT. 
CIB. 


SCP. 
ACY. 
WTC. 


CRC,  CRT,  DEP,  DRW,  G,  HRT,  MRA,  NOP,  PCI. 
G. 


S. 

ICI,  ONX,  PC. 

G,  KAL. 

MRV,  SCP. 

BRY,  DEX,  EMR,  HRT,  ICI,  LEA,  LUR. 

ICI. 

ACY,  BSC,  EFH,  MRV. 

G. 

ACY,  CRC,  CRT,  CST,  DAN,  EFH,  EMK,  GGY,  HRT,  ICI, 
MRA,  PC,  SBC. 


SURFACE-ACTIVE  AGENTS 


159 


TABLE  19B  —Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965—  Continued 


Chemical 


NONBENZENOID  SURFACE-ACTIVE  AGENTS— Continued 


Sulfated   and  Sulfo 


ed--Conlinued 


*Carboxylic  acid  esters  (except  natural  fats  and  oils), 
sulfated  and  sulfonated— Continued 
*Sulfosuccinie  acid  esters— Continued 

Sulfosuccinic  acid,  bis(tallow  monoglyceride)ester 

*Sulfosuccinic  acid,  dihexyl  ester 

Sulfosuccinic  acid,  dioctyl  ester,  sodium  salt 

Sulfosuccinic  acid,  dipentyl  ester,  sodium  salt 

*Sulfosuccinic  acid,  ditridecyl  ester,  sodium  salt 

Other  carboxylic  acid  esters,  sulfated  and  sulfonated: 

Coconut  oil  isethionate 

Coconut  oil  isethionate,  sodium  salt 

Dodecyl  sulfoacetate 

Glycerol  mono( coconut  oil)ester,  sulfated,  ammonium 

salt. 
Glycerol  mono(coconut  oil)ester,  sulfated,  sodium 
salt. 

Glycerol  monostearate  sulfoacetate 

2-Lauroyloxy-l-propanesulfonic  acid 

All  other 

*Ethers,  sulfated  and  sulfonated: 

n-Dodecyl  alcohol,  ethoxylated  and  sulfated,  ammonium 
salt. 
*n-Dodecyl  alcohol,  ethoxylated  and  sulfated,  sodium 
salt. 
n-Dodecyl  alcohol,  ethoxylated  and  sulfated,  tri- 

ethanolamine  salt. 
Dodecyl  and  tetradecyl  alcohols,  ethoxylated  and 

sulfated,  ammonium  salt. 
Dodecyl  and  tetradecyl  alcohols,  ethoxylated  and 
sulfated,  potassium  salt. 

2-Hexyloxypropyl  sulfate,  sodium  salt 

Mixed  linear  alcohols,  ethoxylated  and  sulfated 

Mixed  linear  alcohols,  ethoxylated  and  sulfated, 

ammonium  salt. 
Mixed  linear  alcohols,  ethoxylated  and  sulfated, 

potassium  salt. 
Mixed  linear  alcohols,  ethoxylated  and  sulfated, 
sodium  salt. 

Sperm  oil  alcohol,  ethoxylated  and  sulfated 

Tridecyl  alcohol,  ethoxylated  and  sulfated,  sodium  salt- 
All  other 

^Natural  fats  and  oils,  sulfated: 

*Castor  oil,  sulfated 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


*Coconut  oil,  sulfated 

*Cod  oil,  sulfated 

Cottonseed  oil,  sulfated 

*Grease,  other  than  wool,  sulfated- 

Herring  oil,  sulfated 

Lard,  sulfated 

Mixed  fish  oils,  sulfated 

Mixed  vegetable  oils,  sulfated 

Mustard  seed  oil,  sulfated 

*Neat's-foot  oil,  sulfated 

*Peanut  oil,  sulfated 

Rice-bran  oil,  sulfated 

^Soybean  oil,  sulfated 

*Sperm  oil,  sulfated 


ACY. 

ACY,  MOA,  SNW,  TCI. 


ACT. 

ACY,  MOA,  WTC. 


DRW. 
G,  LEV. 
NAC. 
CP. 

AAC,  CP. 

WTC. 
SDH. 
EMR. 

AAC,  LAK,  ONX,  RCD. 

AAC,  DUP,  ONX,  PCS,  RCD,  RET,  STP. 

PG. 

LEV,  TXT. 


CO,  G,  SHC. 
NLC,  STP. 


*Tallow,  sulfated- 


Whale  oil,  sulfated- 


DUP. 

AAC,  ARL,  RCD. 

APX,  PG. 

AAE,  ACT,  ACY, 
G,  HRT,  ICI, 
ONX,  PC,  PCI, 

ACY,  MRD,  NOP, 

ACT,  CRT,  DRW, 

NOP,  RTC. 

CRT,  NOP,  SEA, 

WHI. 

WAW. 

AML,  SCO. 

LEA. 

LUR,  NOP. 

ACT,  CRT,  KAL, 

ACY,  CRT,  ICI, 

EFH,  KNG,  LUR, 

APX,  CRT,  DRW, 

ACT,  CLD,  CRT, 
RTC,  S,  SEA, 

ACT,  ACY,  BRY, 
NOP,  ONX,  PC 

KNG. 


AML,  APX,  BRY,  BSC,  CRT,  DEX,  DRW,  DUP, 
KAL,  KNG,  LEA,  LUR,  MRA,  MRD,  MRV,  NOP, 

S,  SCO,  SCP,  SEA,  SLC,  WHI,  WHW. 
RTC,  SEA,  WHW. 
MRD,  NOP,  S,  SEA,  WAW,  WHI,  WHW. 

WHI,  WHW. 


LUR,  MRD,  NOP,  PC,  SEA,  WHI,  WHW. 

LEA,  LUR,  NOP,  SCP,  SLC,  SOS. 
NOP. 

HRT,  KAL,  LEA,  MRD,  NOP,  ONX. 

DRW,  HRT,  KAL,  KNG,  LEA,  MRD,  NOP,  ONX, 

WAW,  WHI,  WHW. 

DRW,  EFH,  ICI,  KAL,  LEA,  LUR,  MRA,  MRD, 
PCI,  SCP,  SEY,  SID,  SNW,  SOS,  WHI. 


160 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  19B. — Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


NONBENZENOID  SURFACE- ACTIVE  AGENTS— Continued 

Sulfated  and   Su!/onated--Continued 

Other  nonbenzenoid  surface-active  agents,  sulfated  and 
sulfonated : 

Acetyloleic  acid,  sulfated 

Mixed  alkanesulfonic  acids 

Mixed  alkanesulfonic  acids,  sodium  salt 

*01eic  acid,  sulfated 

Oleostearin,  sulfated 

Ricinoleic  acid,  sulfated 

a-Sulfostearic  acid 

*Tall  oil,  sulfated 


DUP. 
VPC. 
DUP. 
ACT,  ACT,  CRT,  DEX,  DRW,  EMR,  G,  LEA,  LUR,  MRV,  NOP, 

PCI,  SCO,  TEN,  WHI,  WHW. 
SEA. 
NOP. 
RCD. 
ACT,  APX,  CRT,  ICI,  NOP,  SEA,  WHI,  WHW. 


PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL  CHEMICALS 

Pesticides  and  Other  Organic  Agricultural  Chemicals 

TABLE  20B.  --Pesticides  and  other  organic  agricultural  chemicals  for  which  U.S.  production  or  sales  were 
reported,  identified  by  manufacturer,  1965 


[Pesticides  and  other  organic  agricultural  chemicals  for  which  separate  statistics  are  given  in  table  20A  are  marked 
below  with  an  asterisk  (*);   products  not  so  marked  do  not  appear  in  table  20A  because  the  reported  data  are  ac- 
cepted in  confidence  and  may  not  be  published.   Manufacturers'   identification  codes  shown  below  are  taken  from 
table  22.   An  x  signifies  that  the  manufacturer  did  not  consent  to  his  identification  with  the  designated  product] 


Chemical 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL 
CHEMICALS,  CYCLIC 

^Fungicides: 

2,6-Bis(dimethylaminomethyl)eyclohexanone 

2-sec-Butyl-4, 6-dinitrophenyl-3, 3-dimethylacrylate 
( Binapacryl) . 

5-Chloro-2-mereaptobenzothiazole,  laurylpyridium  salt 

2,4-Dichloro-6-o-ehloroanilino-s-triazine 

l,4-Dichloro-2,5-dimethoxybenzene 

2,3-Dichloro-l,4- naphthoquinone  (Diehlone) 

Diphenylammonium  propionate 

3,3'-Ethylenebis(tetrahydro-4,6-dimethyl-2H-l,3,5,5- 
thiadiazine-2-thione) . 

2-Heptadecyl-2-imidazoline  acetate  (Glyodin) 

2-Mereaptobenzothiazole,  monoethanolamine  salt 

*Mereury  fungicides: 

2-Chloro-4-(hydroxymercuri)phenol 

Chloromethoxypropylmercuric  acetate 

N-(Ethylmercuri)-p-toluenesulfonanilide 

4-(Hydroxymercuri)-2-nitrophenol 

8-(Methylmercurioxy)quinoline 

2-(Phenylmercuriamino) ethyl  acetate 

Phenylmercurlammonium  acetate 

N-Phenylmereuriformamide 

Phenylmercury  hydroxide 

Phenylmercury  lactate 

Phenylmercury  naphthenate 

Phenylmercury  oleate 

Phenylmercury  propionate 

Tris(2-hydroxyethyl) (phenylmercuri) ammonium  lactate 

2-( 1-Methylheptyl) -4, 6-dinitrophenyl  crotonate 

*Naphthenic  acid,  copper  salt 

Pentachloronitrobenzene 

*Pentachlorophenol  (PCP) 

*Pentachlorophenol,  sodium  salt 

8-Quinolinol  (8-Hydroxyquinoline),  copper  salt 

Tetrachloro-p-benzoquinone  (Chloranil) 

2,3,4,6-Tetrachlorophenol 

Tetrahydro-3,5-dimethyl-2H,l,3,5-thiadiazine-2-thione 

N- ( Trichloromethylthio) -4-cyclohexene-l, 2-dicarboximide 
( Captan) . 

N-( Trichloromethylthio) phthalimide  (Folpet) 

*2,4,5-Trichlorophenol 

*2,4,5-Triehlorophenol,  ethanolamine  salt 

*2,4,5-Triehlorophenol,  sodium  salt 

2,4,6-Trichlorophenol 

All  other  cyclic  fungicides 

*Herbicides  and  plant  hormones: 

5-Bromo-3-sec-butyl-7-methyluracil 

l-Butyl-3-(3,4-dichlorophenyl) -1-methylurea  ( Neburon) 

2-sec-Butyl-4,6-dinitrophenol  (DNBP) 

*2-sec-Butyl-4, 6-dinitrophenol,  ammonium  salt 

2-sec-Butyl-4,6-dinitrophenol,  triethanolamine  salt 

N-Butyl-N-ethyl-a,a,a,-trifluoro-2,6-dinitro-p-toluidine 
(Benefin). 

2-Chloro-4,6-bis(ethylamino)-s-triazine  (Simazine) 

2-Chloro-4,6-bis(isopropylamino)-s-triazine  (Propazine)- 

4-Chloro-2-butynyl  m-chlorocarbanilate  (Barban) 

2-Chloro-4-ethylamino-6-isopropylamino-s-triazine 

( Atrazine) . 
N-(3-Chloro-4-methylphenyl) -2-methylpentanamide  ( Solan) - 
3-(p-Chlorophenyl) -1, 1-dimethylurea  (Monuron) 


MRK. 
FMN,  FMP. 

VNC. 
CHG. 

DUP. 
USR. 
MRK. 
DUP. 

UCC. 
VNC. 

DUP. 

TRO. 

DUP. 

DUP. 

MRK. 

CLY. 

TRO. 

VIN. 

MRK. 

WRC. 

MRK. 

CLY,  HNX,  MRK,  TRO. 

MRK. 

CLY. 

RH. 

CCA,  FER,  HNX,  MCI,  MLD,  SHP,  SM,  SOC,  SRR,  TGL,  TRO, 

WTC. 
MON,  OMC. 

BXT,  DOW,  FRO,  MON,  RCI,  SFD. 
DOW,  MON,  RCI,  SFD. 
GAM,  HNX,  MRK. 
USR. 
DOW. 

CLY,  MRK,  SF,  WRC. 
CHO. 

CHO. 

DA,  DOW,  HK. 

G. 

DA,  DOW. 

DOW. 

CWN,  DUP. 

DUP. 

DUP. 

CIS,  DOW,  FMN,  TNA. 

CIS,  DOW,  FMN. 

CIS,  DOW,  FMN. 

LIL. 


GGY. 
GGY. 
SPN. 
GGY. 

FMN. 
DUP. 


162 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  20B.  • 


-Pesticides  and  other  organic  agricultural  chemicals  for  which  U.S.  production  or  sales  were 
reported,  identified  by  manufacturer ,  1965 — Continued 


PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL  CHEMICALS, 
CYCLIC--Continued 

^Herbicides  and  plant  hormones — Continued 

3-(p-Chlorophenyl)-l, 1-dimethylurea  trichloroacetate 

2,5-Dichloro-3-aminobenzoic  acid,  ammonium  salt 

3,6-Diehloro-2-anisic  acid 

2-(2,4-Dichlorophenoxy)ethanol  sulfate,  sodium  salt 

3-(3,4-Dichlorophenyl)-l, 1-dimethylurea  (Diuron) 

3-(3,4-Dichlorophenyl) -1-methoxy-l-methylurea  ( Linuron) - 

2,4-Dichlorophenyl-4-nitrophenyl  ether 

3,4-Dichloropropionanilide 

l,2-Dihydro-3,6-pyridazinedione  (Maleic  hydrazide) 

N,N-Dimethyl-2,2-diphenylacetamide  (Diphenamide) 

l,l-Dimethyl-3-phenylurea  (Fenuron) 

l,l-Dimethyl-3-phenylurea  trichloroacetate 

Dimethyl  tetrachloroterephthalate 

4,6-Dinitro-o-eresol  (DNOC) 

4,6-Dinitro-o-cresol,  sodium  salt 

2, 6-Dinitro-N, N-di-n-propyl-ct,a, a-trif luoro-p- 
toluidine  ( Trif luralin) . 

Diphenylacetonitrile 

Gibberellic  acid 

3-(Hexahydro-4,7-methanoindan-5-yl)-l, 1-dimethylurea 
( Norea) . 

Indolebutyric  acid 

Isopropyl  carbanilate   (Isopropyl  N-phenylearbamate) 

(IPC). 
Isopropyl  3-chlorocarbanilate  (Isopropyl  N-(3-chloro- 

phenyl) carbamate)    (CIPC). 
N-( 2-Mercaptoethyl) benzenesulf onamide  S- ( 0, 0-diisopropyl 
phosphorodithioate)    (Betasan). 

l-(2-Methyl-cyclohexyl)-3-phenylurea  (Siduron) 

1-Naphthaleneacetic  acid  and  derivatives: 

1-Naphthaleneacetamide 

1-Naphthaleneacetic  acid 

1-Naphthaleneacetic  acid,  methyl  ester 

1-Naphthaleneacetic  acid,  sodium  salt 

N-1-Naphthylphthalamic  acid  (NPA) 

7-0xabicyclo[2.2.1]heptane-2,3-dicarboxylic  acid, 

disodium  salt  (Endothal). 
Phenoxyacetic  acid  derivatives: 

(4-Chloro-o-tolyloxy) acetic  acid  (MCPA) 

(4-Chloro-o-tolyloxy) acetic  acid,  potassium  salt 

♦(2, 4-Dichlorophenoxy) acetic  acid  (2,4-D) 

*( 2, 4-Dichlorophenoxy) acetic  acid  esters  and  salts: 
( 2, 4-Dichlorophenoxy) acetic  acid,  2-butoxyethyl 

ester. 
(2, 4-Dichlorophenoxy) acetic  acid,  butoxypolypropyl- 
eneglycol  ester. 

*(2, 4-Dichlorophenoxy) acetic  acid,  n-butyl  ester 

(2, 4-Dichlorophenoxy) acetic  acid,  sec-butyl  ester 

*(2,4-Dichlorophenoxy)acetic  acid,  dimethylamine  salt 
(2, 4-Diehlorophenoxy) acetic  acid,  ethanolamine  and 
isopropanolamine  salt. 

*(2, 4-Dichlorophenoxy) acetic  acid,  ethyl  ester 

(2, 4-Dichlorophenoxy) acetic  acid,  2-ethylhexyl  ester 

*(2, 4-Dichlorophenoxy) acetic  acid,  iso-octyl  ester 

*( 2, 4-Dichlorophenoxy) acetic  acid,  isopropyl  ester 

(2, 4-Dichlorophenoxy) acetic  acid,  lithium  salt 

(2,4-Diehlorophenoxy)acetic  acid,  sodium  salt 

All  other  (2, 4-Dichlorophenoxy) acetic  acid  esters 
and  salts. 

*(2, 4, 5-Triehlorophenoxy) acetic  acid  (2,4,5-T) 

*(2, 4, 5-Trichlorophenoxy) acetic  acid  esters  and  salts: 

(2,4,5-Trichlorophenoxy)acetic  acid,  amyl  ester 

(2,4,5-Triehlorophenoxy)aeetic  acid,  2-butoxyethyl 

ester. 
(2,4,5-Trichlorophenoxy) acetic  acid,  butoxypoly- 
propyleneglycol  ester. 
*(2, 4, 5-Trichlorophenoxy) acetic  acid,  n-butyl  ester— 
(2,4,5-Trichlorophenoxy)acetie  acid,  sec-butyl  ester 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


ACG. 

G. 

VEL. 

G. 

DUP. 

DUP. 

RH. 

MON,  RH. 

ACY,  USR. 

LIL,  x. 

DUP. 

ACG. 

DA. 

CIS,  FMN. 

CIS,  FMN. 

LIL. 

LIL. 

ABB,  MRK. 
HPC. 

ARA. 
PPG. 

PPG. 

SF. 

DUP. 

AMC. 

AMC,  COK. 
AMC. 

AMC,  BKL. 
USR. 
PAS. 


CHC,  CLY,  DOW,  RIV. 

GTH. 

CHC,  DA,  DOW,  HPC,  MON. 

AMC. 

DOW. 


AMC,  DA,  DOW,  HPC,  IMR,  MON,  RIV,  TMH. 

CHC,  MON. 

ALC,  AMC,  CHC,  DA,  DOW,  HPC,  RIV,  TMH. 

DOW. 


AMC,    DOW, 

MON. 

DA,   HPC. 

CHC,    DOW, 

MON,   RIV,    TMH. 

AMC,    CHC, 

DA,    DOW,   HPC,   MON, 

RIV 

GTH. 

DOW. 

CWN,   HPC. 

DA,   DOW, 

HPC,   MON. 

HPC. 

AMC. 

DOW. 

DA,    DOW, 

HPC,   MON,    RIV. 

MON. 

PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL  CHEMICALS 

TABLE  20B. — Pesticides  and  other  organic  agricultural  chemicals  for  which  U.S.  production  or  sales  were 
reported,  identified  by  manufacturer,  1965 — Continued 


Manufacturers '   identification  codes 
(according  to  list  in  table  22) 


PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL  CHEMICALS, 
CYCLIC— Continued 

^Herbicides  and  plant  hormones — Continued 
Phenoxyacetic  acid  derivatives — Continued 
*(2,4,5-Trichlorophenoxy)acetic  acid  esters  and  salts — 
Continued 
(2,4,5-Trichlorophenoxy)acetie  acid,   2-ethyLhexyl 
ester. 
*(2, 4, 5-Trichlorophenoxy) acetic  acid,   iso-octyl  ester 
(2,4,5-Triehlorophenoxy)acetic  acid,   isopropyl  ester 
(2, 4, 5-Trichlorophenoxy) acetic  acid,   triethylamine 
salt. 

*Phenylmercury  acetate  (PMA) 

Polychloro-tetrahydro-methanoindene  ( Polychlorodicyclo- 
pentadiene)   isomers. 

N-Tolylphthalamic  acid 

Tributyl(2,4-dichlorobenzyl)phosphonium  chloride 

2-(2,4,5-Trichlorophenoxy)proplonic  acid  (Silvex) '■ 

2-(2,4,5-Trichlorophenoxy)propionic  acid,   2-ethyLhexyl 
ester. 

Tris [2- ( 2, 4-dichlorophenoxy) ethyl] phosphite   (2,4-DEP) 

All  other  cyclic  herbicides  and  plant  hormones 

Insect  attractants: 
2,4-Bis( isopropylamino) -6-methoxy-s-triazine 

( Prometone ) . 
tert-Butyl  4(and  5)-chloro-2-methylcyclohexane- 

carboxylate. 
2-Ethylamino-4-isopropylamino-6-methylmercapto-s- 
triazine  (Ametryne). 
^-Insecticides: 

Allethrin  (Allyl  homolog  of  Cinerin  I) 

Benzyl  thiocyanate 

Chlorinated  insecticides: 
*Aldrin-toxaphene  group: 

Heptachloro-tetrahydro-methanoindene  ( Heptachlor ) 

Hexachloro-epoxy-octahydro-endo,   endo-dimethano- 

naphthalene  ( Endrin) . 
Hexachloro-epoxy-octahydro-endo,   exo-dimethano- 

naphthalene  (Dieldrin). 
Hexachloro-hexahydro- endo,   exo-dimethanonaphthalene 
(Aldrin) . 

Octachloro-tetrahydro-methanoindan  (Chlordan) 

Terpene  polychlorinates 

Toxaphene  (Chlorinated  camphene) 

l,l-Bis(p-chlorophenyl)-2-nitrobutane 

1, l-Bis(p-chlorophenyl)-2-nitropropane 

2-(p-tert-Butylphenoxy)isopropyl-2'-chloroethyl 

sulfite  . 
2-(p-tert-Butylphenoxy)-l-methyletnyl  2- ehloroethyl 
sulfite. 

p-Chlorophenyl  p-chlorobenzenesulfonate  (Ovex) 

p-Chlorophenyl  2,4,5-trichlorophenyl  sulfone 

4,4'-Dichlorobenzilate 

l,l-Dichloro-2,2-bis(p-chlorophenyl)ethane  (DDD)  (TDE) 

1, l-Dichloro-2,2-bis(p-ethylphenyl) ethane 

4,4'-Dichloro-a-(trichloromethyl)benzhydrol 

*Hexachlorocyelohexane  (Benzene  hexachloride) 

*Hexachlorocyclohexane,    100$  y-isomer  (Lindane) 

Hexachloro-hexahydro-methano-benzodioxathiepinoxide 
(Endosulfan). 

*1, l,l-Trichloro-2,2-bis(p-chlorophenyl)ethane  (DDT) 

1, 1, l-Trichloro-2, 2-bis (p-methoxyphenyl) ethane 
(Methoxychlor) . 

All  other  chlorinated  insecticides 

N,  N-Diethyltoluanu.de 

Isobornyl  thiocyanatoacetate 

1-Naphthyl  methylcarbamate 

*Organophosphorus  insecticides: 

4-tert-Butyl-2-chlorophenyl  methyl  methylphosphor- 

amidate. 
3-Chloro-7-hydroxy-4-methylcoumarin  0, 0-diethyl  phos- 
phorothioate . 


DA, 

HPC. 

CIS, 

DOW,    MON,    HIV,    TMH. 

DA. 

DOW, 

HPC,    RIV. 

BKM, 

CLY,   MRK,    TRO,   WRC. 

VEL. 

USR. 

SM. 

DOW, 

HPC,    RIV. 

HPC. 

USR. 

HPC, 

LIL. 

GGY. 

TBK. 

GGY. 

BPC. 

HK. 

VEL. 

SHC, 

VEL. 

SHC. 

SHC. 

VEL. 

HN. 

HPC. 

COM. 

COM. 

USR. 

USR. 

AMP, 

CIS,    DOW. 

FMN, 

FMP. 

GGY. 

ACG, 

RH. 

RH. 

RH. 

DA, 

fRO,   HK,    PPG. 

HK. 

HK. 

ACG, 

DA,    GGY,    LEB,   MTO,    OMC 

CHF, 

DUP. 

LIL, 

SHC. 

HPC, 

PFZ. 

CIS, 

HPC. 

UCC. 

DOW. 

CHG. 

164 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  20B. 


-Pesticides  and  other  organic  agricultural  chemicals  for  which  U.S.  production  or  sales  were 
reported,  identified  by  manufacturer ,  1965 — Continued 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


PESTICIDES  AMD  OTHER  ORGANIC  AGRICULTURAL  CHEMICALS, 
CYCLIC— Continued 

^Insecticides- -Continued 

*Organophosphorus  insecticides — Continued 

S-(p-Chlorophenylthio)methyl  0, O-diethyl  phosphoro- 

dithioate  ( Carbophenothion) . 
0, 0-Diethyl  0-(2-isopropyl-4-methyl-6-pyrimidinyl) 
phosphorothioate  (Diazinon). 
*0, 0-Diethyl  O-(p-nitrophenyl)  phosphorothioate 
( Parathion) . 
0,0-Dimethyl  0- [4-(methylthio)-m-tolyl]  phosphoro- 
thioate. 
*0, 0-Dimethyl  0- ( p-nitrophenyl)  phosphorothioate 
(Methyl  parathion) . 
0, 0-Dimethyl  S-(4-oxo-l,2,3-benzotriazin-3(4H) - 

ylmethyl)  phosphorodithioate. 
0, 0-Dimethyl  0-(2,4,5-trichlorophenyl)  phosphoro- 
thioate (Ronnel). 

p-Dioxane-2,3-diyl  ethyl  phosphorodithioate 

0-Ethyl  0-(p-nitrophenyl)phenyl  phosphonothioate 

a-Methylbenzyl  3-hydroxy-cis-crotonate,  dimethyl  phos 
phate  ester. 

All  other  organophosphorus  insecticides 

Nematocides: 

0-2,4-Dichlorophenyl  0, 0-diethyl  phosphorothioate 

0, 0-Diethyl  0-2-pyrazinyl  phosphorothioate  (Thionozin)— 
*Rodenticides: 

3-(Acetonylbenzyl)-4-hydroxycoumarin 

2-Isovaleryl-l,3-indandione,  calcium  salt 

2-Pivaloyl-l,3-indandione 

PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL 
CHEMICALS,  ACYCLIC 

*Fungicides: 

Bis-1,4— bromoacetoxy-2-butene 

Cadmium  succinate 

l-Chloro-2-nitropropane   (Korax) 

Disodium  cyanodithioimidocarbonate 

Dithiocarbamic  acid  fungicides: 

*Dimethyldithiocarbamic  acid,  ferric  salt  (Ferbam) 

Dimethyldithiocarbamic  acid,  manganese  salt 

Ethylene  bis(dithiocarbamic  acid),  diammonium  salt 

^Ethylene  bis(dithiocarbamic  acid),  disodium  salt 
( Nabam) . 
Ethylene  bis( dithiocarbamic  acid),  manganese  salt 
(Maneb). 
^Ethylene  bis( dithiocarbamic  acid),  zinc  salt  (Zineb)-- 

Polyethylenethiuram  disulfide  (PETD) 

All  other  dithiocarbamic  acid  fungicides 

Dodecylguanidine  acetate  (Dodine) 

Mercury  fungicides: 

3-Ethyl(mercuritnio)-l,2-propanediol 

Ethylmercury  acetate 

Ethylmercury  chloride 

Ethylmercury  phosphate 

3-Methyl(mercurithio)-l,2-propanediol 

Methylmercury  acetate 

Methylmercury  hydroxide 

Methylmercury  nitrile 

All  other  mercury  fungicides 

All  other  acyclic  fungicides 

*Herbicides  and  plant  hormones: 

Cacodylic  acid 

2-Chloroallyl  diethyldithiocarbamate  (CDEC) 

N,N-Diallyl-2-chloroacetamide  (CDAA) 

2,3-Dichloroallyl  diisopropylthiocarbamate 

2,2-Dichloropropionic  acid,  sodium  salt 

Diethyl  dithiobis(thionoformate) 

S-Ethyl  dipropylthiocarbamate  (EPTC) 

Hexachloroacetone 


SF. 

GGY. 

ACY,  AMP,  M0N,  SF,  SHC. 

CHG. 

AMP,  M0N,  SF,  SHC. 

CHG. 

DOW. 

HPC. 

SF. 

SHC. 

SF. 

SM. 
ACY. 

PEN. 
MOT. 
MOT,  PIC. 


VI N. 

MAL. 

FMN,  FMP. 
BKM. 

DUP,  FMN,  RBC,  WRC. 

FMN. 

CIS,  RBC. 

CIS,  DUP,  FMN,  RBC,  RH. 

CIS,  DUP,  RH. 

CIS,  DUP,  FMN,  RH. 

FMN. 

VNC. 

ACY. 

DUP. 
DUP. 
DUP. 
DUP. 
DUP. 
DUP. 
MRT. 
WRC. 
MAL. 
LIL,  MLD,  SHC. 

ASL. 

M0N. 

M0N. 

M0N. 

DOW. 

RBC. 

SF. 

ACG. 


PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL  CHEMICALS 


165 


TABLE  20B.  ■ 


-Pesticides  and  other  organic  agricultural  chemicals  for  which  U.S.  production  or  sales  were 
reported,  identified  by  manufacturer,  1965 — Continued  -^ 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


PESTICIDES  AND  OTHER  ORGANIC  AGRICULTURAL  CHEMICALS, 
ACYCLIC- - Continued 

*Herbicides  and  plant  hormones — Continued 

Methanearsonic  acid,   disodium  salt 

Methanearsonic  acid,   dodecyl-   and  oetylammonium  salts — 

S- Propyl  butylethylthiocarbamate 

S,S,S-Tributyl  phosphorotrithioate 

Tributyl  phosphorotrithioite 

Trichloroacetic  acid,   sodium  salt  (TCA) 

2,3,3-Trichloroallyl  diisopropylthiocarbamate 

All  other  acyclic  herbicides  and  plant  hormones 

^Insecticides: 

2-(2-Butoxyethoxy) ethyl  thiocyanate 

Butoxypolypropylene  glycol  (Fly  repellent) 

Metaldehyde 

*Organophosphorus  insecticides: 

Bis(dialkoxyphosphinothioyl)   disulfides 

S-[l,2-Bis(ethoxycarbonyl)ethyl]   0,0-dimethyl  phos- 

phorodithioate  (Malathion). 
l,2-Dibromo-2,2-dichloroethyl  dimethyl  phosphate 
(Naled). 

2,2-Dichlorovinyl  dimethyl  phosphate  (DDVP) 

0,0- Diethyl  S-[2-(ethylthio)ethyl]  phosphorodithioate- 
0,0-Diethyl  0-[2-(ethylthio)ethyl]  phosphorothioate--- 
0,0-Diethyl  S-[2-(ethylthio)  ethyl]  phosphorothioate— 
0,0-Diethyl  S-[  (ethylthio)methyl]  phosphorodithioate— 
Dimethyl  3-hydroxycrotonate,  dimethyl  phosphate  ester- 
0,0- Dimethyl  S-(N-methylcarbamoy Methyl)  phosphorodi- 
thioate (Dimethoate) . 

Ethyl  methylene  phosphorodithioate  (Ethion) 

Ethyl  pyrophosphate   (Tetraethyl  pyrophosphate)    (TEPP)- 
S-2-(Ethylsulfinyl) ethyl  0,0-dimethyl  phosphoro- 
dithioate. 
Methyl  3-hydroxycrotonate,   dimethyl  phosphate  ester—- 

All  other  organophosphorus  insecticides 

2-Thiocyanatoethyl  laurate 

*Rodenticides:      Sodium  fluoroacetate 

*Soil  conditioners: 

Polyacrylonitrile,   hydrolyzed,   sodium  salt 

All  other  soil  conditioners 

*Soil  fumigants: 

*Bromomethane   (Methyl  bromide) 

Chloropicrin  (Trichloronitromethane) 

*l,2-Dibromo-3-chloropropane 

1,3-Dichloropropene 

1,3-Dichloropropene,    1, 2-dichloropropane 

N-Methyldithiocarbamic  acid,   sodium  salt 

All  other  soil  fumigants 


ASL, 

CLY,    VI N 

CLY, 

VIN. 

SF. 

CHG. 

SM. 

DOW. 

MON. 

SF, 

USR. 

RH. 

UCC. 

COM. 

FMN. 

ACY. 

SHC. 

SHC. 

CHG. 

CHG. 

CHG. 

ACY. 

SHC. 

ACY. 

FMN, 

FMP. 

ALC, 

AMP,    OTH. 

CHG. 

SHC. 

AMP, 

SHC. 

AMP, 

DOW,    FRO, 

GTL, 

MCH 

DOW, 
AMP, 

IMC. 
DOW,    SHC. 

DOW. 

DOW, 

SHC. 

DUP, 

RH,    SF. 

SYNTHETIC  ORGANIC  CHEMICALS.  1963 


Miscellaneous  Chemicals 

TABLE  21B. — Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 

[Miscellaneous  chemicals  for  which  separate  statistics  are  given  in  table  21A  are  marked  with  an  asterisk  (*); 
chemicals  not  so  marked  do  not  appear  in  table  21A  because  the  reported  data  are  accepted  in  confidence  and  may  not 
be  published.   Manufacturers'    identification  codes  shown  below  are  taken  from  table  22.   An  x  signifies  that  the 
manufacturer  did  not  consent  to  his   identification  with  the  designated  product] 


Chemical 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,  CYCLIC 

6-Aeetoxy-2, 4- dimethyl- m-dioxane 

Adenosine  phosphates 

2-Aminobenzothiazole 

3-Amino-4-bromobenzotrifluoride 

l-(2-Aminoethyl)piperazine 

l-(3-Aminopropyl)morpholine 

Anisaldehyde  bisulfite 

Arylalkyl  phosphites 

Aziranephosphine  oxide 

Barium  octylphenate 

Benzoic  acid  salts: 

Barium  benzoate 

Cadmium  benzoate 

Cobalt  benzoate 

*Sodium  benzoate,  tech 

*Sodium  benzoate,  U.S.P 

Zinc  benzoate 

p-Benzoquinone  (p-Quinone) 

Benzothiazole 

* Benzoyl  peroxide 

Biological  stains 

Bis(2,4-dichlorobenzoyl)    peroxide 

Boron  fluoride-phenol  complex 

3-Bromo-4-chlorobenzotrifluoride 

a- [2-(2-Butoxyethoxy) ethoxy] -4,5-methylenedioxy-2-propyl- 

toluene  (Piperonyl  but  oxide). 

Butyl  benzoate 

p-tert-Butylbenzoic  acid,  barium  bis-salt 

2(  and  3)-tert-Butyl-4— methoxyphenol 

p-tert-Butyl-ci-methylcinnamaldehyde 

tert-Butyl  peroxybenzoate 

4-tert-Butylphenyl  salicylate 

4-tert-Butylpyrocatechol 

Camphene 

Catecholdisulfonic  acid,  disodium  salt 

Catecholdisulfonic  acid,  sodium  salt 

Centralite- 1  ( N,  N '-Diethyl-N,  N'-diphenylurea) 

Chemical  indicators 

Chemical  reagents 

Chloramine  B  (Sodium  derivative  of  N-chlorobenzenesulfon- 

amide) . 

Chlorinated  terphenyls 

l-(3-Chloroallyl)-3,5,7-triaza-l-azon  iaadamantane 

chloride. 

4-Chloro-3-cyanobenzotrifluoride 

5-Chloro-2-hydroxybenzophenone 

Chlorophyllin,  sodium- potassium- copper 

Cobalt  phthalocyaninedisulfonic  acid 

Cumene  hydroperoxide 

Cyanuric  acid 

Cyclohexanone  peroxide 

Cyclohexene-1, 2-dicarboxylic  acid  ( Tetrahydrophthalic 

acid)  disubstituted,  polyester  salts:   Barium  and 

cadmium  salts. 

1,4-Cyclohexylenedimethanol 

^Cyclopropane 

Cytidine  and  derivatives 

Decahydronaphthalene  ( Decalin) 

Decyl  diphenyl  phosphite 

Dehydroacetic  acid,  sodium  salt 

2,5-Di-tert-amylhydroquinone 


GIV. 
PLB. 

FMT. 
PIC. 
JCC. 
JCC. 
GIV. 
WES. 
CEM. 
CCA. 

CCW. 

CCW. 

SHP. 

HN. 

HK,  HN,  MON,  PFZ,  VEL. 

CCW. 

EKT. 

ACY. 

AZT, 

HLC, 

CAD. 

ACG. 

PIC. 

FMN, 


FRO, 

CCA. 

EKT. 

GIV. 

WTL. 

DOW. 

BKL, 

GLD, 

ICO. 

SDW. 

OTC, 

EK, 

ACG, 

NES. 


CAD,  NOC,  OXY,  RCI,  SDH,  UPR,  WTL. 
NAC. 


DOW. 
HPC. 


PAS. 
HLC,  LAM,  NAC. 
CLB,  EK,  GFS,  HLC,  NAC,  PIC. 


KPS,  KPT. 
DOW. 

PIC. 

DOW. 

KCH. 

NAC. 

HPC. 

FMB. 

NOC,  WTL. 

RCI. 


EKT. 

MAL,  OH,  OMS,  TAE. 

PLB. 

DUP. 

HK. 


GAN. 

EKT. 


MISCELLANEOUS  CHEMICALS 


167 


TABLE  21B. 


-Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1 965-  -Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,    CYCLIC— Continued 

l,4-Diazabicyclo[2.2.2]oetane  (Triethylenediajnine) 

Diazodinitrophenol 

2,4-Dibenzoylresorcinol 

2,4-Di-tert-butyl-p-cresol 

2,6-Di-tert-butyl-p-cresol: 

*Food  grade 

*Tech 

2,5-Di-tert-butylhydroquinone 

1,  l-Diehloro-2-(  o- chlorophenyl)  -2-(  p- chloropheny  1)  ethane— 

l,3-Dichloro-5,5-dimethylhydantoin 

Dichloro-s-triazine-2,4, 6(  1H,3H,5H) trione  (Dichloroiso- 

cyanuric  acid) . 
Dichloro-s- triazine-2, 4, 6(  LH,3H,5H)  trione,  potassium  salt- 

Diehloro-s- triazine-2, 4, 6(  1H,3H,5H)  trione,  sodium  salt 

Dicyclohexylammonium  nitrite 

Dicyclopentadienyliron 

Didecyl  phenyl  phosphite 

Digitonin 

2,2'-Dihydroxy-4, 4'-dimethoxybenzophenone 

2, 6-Dihydroxyisonicotinic  acid  (2,6-Dihydroxy-4-carboxy- 
pyridine) . 

2, 2'-Dihydroxy—4- methoxybenzophenone 

2,2'-Dihydroxy-4-(octadecyloxy)benzophenone 

3, 5-Diiodosalicylie  acid 

Diisopropylbenzene  hydroperoxide,  mixed  isomers 

Diisopropyl-m,  p-cresols 

Diisopropyl-m,  p-cresols,  mixed 

p-Dimethoxybenzene  (Dimethyl  ether  of  hydroquinone) 

2, 5-Dimethyl-2, 5-di(  peroxyphenyl)  hexane 

2,5-DimethyLhexane-2,5-diperoxybenzoate 

2,6-Dimethylmorpholine 

4,4-Dinitrocarbanilide-4,6-dimethyl-2-pyrimidinol 

Dioxane  ( 1, 4-Diethylene  oxide) 

2,5-Diphenyl-p-benzoquinone 

Diphenyl  phosphite 

4-(Dodecyloxy)-2-hydroxybenzophenone 

Enzymes: 
Hydro lytic: 

Amylases-- 

Proteases 

Other 

Nonhydro lytic 

Other 

1, 2-Epoxy-3-phenoxypropane  (Glycidyl  phenyl  ether) 

6-Ethoxy-m-anol  (Propenylmethylguaethol) 

Ethylglucosyl  p- aminobenzoate 

2-EthyLhexyl  octylphenyl  phosphite 

Ethyl  hydrocaffeate 

*4-Ethylmorpholine 

Fenchone 

*Flotation  reagents: 

Dicresylphosphorodithioic  acid  ( Dicresylthiophosphoric 
acid) . 

Dicresylphosphorodithioic  acid,  ammonium  salt 

Dicresylphosphorodithioic  acid,  sodium  salt 

2,2'-Dimethylthiocarbanilide  (Di-o-tolylthiourea) 

Rosin  amines 

Thiocarbanilide  ( Diphenylthiourea) 

Fluorinated  benzenoid  chemicals 

o-Fluorobenzoic  acid 

4-Fluoro-2-methylaniline 

5-Fluoro-2-nitrotoluene 

Furan  derivatives: 

2-Furaldehyde  (Furfural) 

Tetrahydrofurfuryl  alcohol 

Gallic  acid,  all  grades 

*Gasoline  additives: 

N,  N'-Bis(  1, 4-dimethylpentyl)-p-phenylenediamine 

2, 6-Di-tert-butylphenol 

*N, N'-Di-sec- butyl- p-phenylenedlamine 


HOU. 
HPC. 
DOW. 
PRD. 

CAT,  EKT,  HPC,  KPT,  SHC. 

CAT,  EKT,  HPC,  KPT,  SHC. 

EKT. 

ALD,  EDC. 

GLY. 

MON. 

FMB,  MON. 

FMB,  WON. 

CMC. 

TNA. 

HK. 

PEN. 

G. 

EK. 

ACY. 

ACY. 

MRT. 

HPC. 

GIV. 

GIV. 

ASL,  EKT,  G,  ICO. 

WTL. 

UPR. 

DOW. 

MRK. 

DOW,  UCC. 

EKT. 

HK. 

DUP,  EKT. 


CRN,  OMS,  PMP,  RH,  WBC. 

PMP,  RH,  WBC. 
WBC. 

MLS,  WBC. 


BAX, 

BAX, 

RH, 

FMO, 

PLB. 

SHC. 

ICO. 

VND. 

SM. 

ICO. 

BC,  C 

HNW. 

ACY. 


ACY. 

KCU. 

DUP,  RBC. 
HPC. 

ACY,  NAC. 
PIC. 
PIC. 
PIC. 
PIC. 

QKO. 
CjKO. 

MAL. 

EKT. 
TNA. 
DUP,  EKT,  UPM. 


168 


SYNTHETIC  ORGANIC  CHEMICALS.  1965 


TABLE  21B  -Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965— Continued 


Manufacturers'  identification  codes 
( according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,  CYCLIC— Continued 

Gasoline  additives — Continued 

N,N'-Diisopropyl-p-phenylenediamine 

*N,N'-Disalicylidene-l,2-propanediamine 

Methylcyelopentadienylmanganese  triearbonyl 

2,2'-Thiobis[6-tert-butyl-4-methylphenol] 

All  other 

Glyceryl  p- aminobenzoate 

Guanosine  phosphates 

Heterocyclic  compounds 

5, 6,7, 8, 9, 9-Hexachloro-l,  2,3, 4, 4a,  5, 8, 8a-oetahydro- 
5,8-methano-2,3-naphthalic  anhydride  (Cloran). 

Hexa(2-methylaziridinyl)-l,3,5-phosphotriazine 

*Hexamethylenetetramine,  tech 

Hydrocinnamic  acid 

o-(2-Hydroxy-p-anisoyl) benzoic  acid 

N-(2-Hydroxyethyl)gentisamide 

Hydroxyethylpiperazine 

2-Hydroxy-4-methoxybenzophenone 

2-Hydroxy-4-methoxy-5-sulfobenzophenone  trihydrate- 

Hydroxymethyl-5,5-dimethylhydantoin 

2-Hydroxymethyl-5-norbornene 

2-(2'-Hydroxy-5'-methylphenyl)benzotriazole 

2-Hydroxy-4-n-octoxybenzophenone 

Hydroxyphenylbenzotriazole  derivative 

2-(2-Hydroxyphenyl) -4(3) -quinazo lone 

l-Hydroxy-2-pyridine  (Omadine) 

2-Imidazolidinethione  ( l,3-Ethylene-2-thiourea) 

Inosine  and  phosphates 

Isoamyl  p-dimethylaminobenzoate 

Isocyanurie  acid 

Isocyanuric  acid,  sodium  salt  (Sodium  isocyanurate) 

Isophorone 

Isopropyl-o-cresol 
p-Isopropyl-a- methylc  innamaldehyde- 
Isosorbid 
Ketene,  dimer- 
*Lubricating  oil  and  grease  additives: 

Chlorosulfurized  and  sulfurized  compounds: 
Alicyclic  compounds,  sulfurized- 
Heterocyclic  compounds,  sulfurized 
Liquid  disulfide- 

Tall  oil  ester,  sulfurized 

Terpenes,  sulfurized 

Oil- soluble  petroleum  sulfonates: 

Oil-soluble  petroleum  sulfonate,  ammonium  salt 

Oil-soluble  petroleum  sulfonate,  barium  salt 

*Oil-soluble  petroleum  sulfonate,  calcium  salt 

xOil-soluble  petroleum  sulfonate,  sodium  salt 

All  other 

Phenol  salts: 

Barium  salt  of  dodecylphenol 

Barium  salt  of  nonylphenol 

Calcium  salt  of  octylphenol- formaldehyde 

Calcium  salt  of  polypropylphenol 

All  other  phenol  salts 

All  other 

p-Menthane 

8-p-Menthyl  hydroperoxide 

4-Methallylbenzenesulfonic  acid 

Methoxybenzyl  alcohol 

p-Methoxybenzylidenemalonic  acid,  dimethyl  ester 

4-Methoxyphenol 

N-Methylanthranilic  acid 

2-Methylaziridine 

2,2'-Methylenebis[4-chlorophenol]  ( Dichlorophene) 

4,4'-Methylenebis[2,6-di-tert-butylpheno]] 

Methylenebis[5,5-dimethylhydantoin] 

2,2'-Methylenebis[3,4,6-trichlorophenol]  ( Hexachlorophene) 
2,2'-Methylenedi-p-cresol  ( Bis( 5-methyl-2-hydroxyphenyl) 
methane) . 


DUP,    EKT. 

D0P,    EKT,    SM,    TX,    UPM. 

TNA. 

CAT. 

EKT,    TNA,    UPM. 

TOD. 

PLB. 

ALD. 

WSN. 

ICO. 

BOR,    DUP,    HKD,    HMP,    HN,    FLS,    UCP. 

ICO. 

ACY. 

ICO. 

JCC. 

ACY,    G. 

ACY. 

GLY. 

ICO. 

GGY. 

ACY. 

GGY. 


LUB,    MON,    0R0,    SIN,    x. 

LUB,    MON,    0R0,    SIN,    SM,    TNA,    TX,    X. 


SIN. 

CO,    LUB,    SON,    TX,    X. 

CO,    LUB,    0R0,    SHO,    SON,    X. 

ENJ,    MOR,    NOP,    PAR,    SHO,    SOC,    SOI,    SON,    TX. 

CO. 


TX. 

CCA. 

SHC. 

0R0. 

ENJ, 

ENJ, 

HPC. 

HNW, 

CCW. 

ICO. 

ACY. 

ASL, 

GIV. 

ICO. 

GIV. 

SHC. 

GLY. 

GIV. 

GIV. 


MISCELLANEOUS  CHEMICALS 


169 


TABLE  21B.-- Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer ,  1965 — Continued 


MISCELLANEOUS  CHEMICALS,    CYCLIC— Continued 

Methyl  gallate 

Methylglucoside 

■i-Methylmorpholine 

5-Methyl-5-norbornene-2,3-dicarboxylic  anhydride  (Methyl- 
bicyclo[2.2.l]hept-5-ene-2,3-dicarboxylic  anhydride). 

Methyl  phenyl  phosphates 

l-Methyl-2-pyrrolidone,    monomer 

*Morpholine 

Morpholine  salt  of  p- toluenesulf onic  acid 

*Naphthenic  acid  salts: 

Aluminum  naphthenate 

Barium  naphthenate 

Cadmium  naphthenate 

*Calcium  naphthenate 

Cobalt  lead  manganese  naphthenate 

*Cobalt  naphthenate 

*Iron  naphthenate 

Lead  manganese  naphthenate 

*Lead  naphthenate 

Lithium  naphthenate 

^Manganese  naphthenate 

Nickel  naphthenate 

Rare  earths  naphthenate 

Sodium  naphthenate 

Strontium  naphthenate 

*Zinc  naphthenate 

o-Nitrobenzoic  acid  and  sodium  salt 

5-Norbornene-2-methylacrylate  ( Bicyclo[2.2.  l]hept-5-ene- 
2-aerylate) . 

l-0ctadecenyl-2-naphthenyltetrahydropyrimidine 

Octylphenyl  acid  phosphate 

Organic  mercury  compounds: 

Phenyl  mercuric  borate 

Pyridyl  mercuric  acetate 

1, 10-Phenanthroline 

Phenolthiosulfonic  acid 

2-Phenoxyethanol  (Ethylene  glycol  monophenyl  ether) 

2-(2-Phenoxyethoxy)ethanol  (Diethylene  glycol  phenyl 
ether) . 

2,2'-(p-Phenylene)diethanol 

m-Phenyleneisophthalamide 

Phenyl  hydrogen  phosphate - 

Phenyltrimethylammonium  chloride 

Photographic  chemicals: 

N-(o-Acetamidophenethyl)-l- hydroxy- 2- naphthamide 

2-(4-Amino-N-ethyl-m-toluidino) ethyl  sulfate 

4-Amino-6-methylguaiacol  (2-Methyl-6-methoxy-4-amino- 
phenol  hydrochloride) . 

3-Amino-l,2,4-triazole  (5-Amino-l,3,4-triazole) 

*Benzotriazole 

p-Benzylaminophenol  hydrochloride 

Catechol  (Pyrocatechin) 

3-Chloro-4-diethylaminobenzenediazonium  chloride  ( p- 
Diazo-2-ehlpro-N,  N-diethylaniline)  -  zinc  chloride. 
2-Chloro-N,  N- diethyl- p-phenylenediamine  hydrochloride— 

2,4-Diaminophenol  dihydrochloride  (Amidol) 

N-(4-Diazo-2,5-dibutoxyphenyl)  morpholine,  zinc  chloride 

salt. 
N-(4-Diazo-2, 5-diethoxyphenyl) morpholine,  zinc  chloride 
salt. 

4—  Diazo-1-morpholine  benzene 

2,5-Diethoxy-4-morphinyldiazonium  chloride  -  zinc 
chloride  double  salt. 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


HSH. 
CRN. 
JCC,  UCC. 

ICO. 

TNA. 

G. 

DOW,  JCC,  UCC. 

AMB. 

HSH,  WIC. 

CCA,  QCP. 

CCA. 

CCA,  FER,  HNX,  HSH,  MCI,  MLD,  MR,  SHP,  SM,  SOC,  SRR, 

SW,  TRO,  WTC. 
HNX,  HSH,  SW. 
CCA,  CCC,  FER,  HNX,  HSH,  MCI,  MLD,  MON,  MR,  SHP,  SM, 

SOC,  SRR,  SW,  TRO,  WTC. 
CCA,  HNX,  HSH,  MCI,  MLD,  SOC,  TRO,  WTC. 
CCA. 
CCA,  CCC,  CCW,  FER,  HNX,  HSH,  MCI,  MLD,  MR,  SHP,  SM, 

SOC,  SRR,  SW,  TRO,  WTC. 
CCA. 
CCA,  CCC,  FER,  HNX,  HSH,  MLD,  SHP,  SM,  SOC,  SRR,  SW, 

TRO,  WTC. 
CCA. 

CCA,  HNX. 
CCA. 
CCA. 
CCA,  CCC,  FER,  HNX,  HSH,  MCI,  MLD,  SHP,  SOC,  SRR,  SW, 

TRO,  WTC. 
WAY. 
ICO. 

SM. 
SM. 

WRC. 

MAL. 

COK. 

G. 

DOW,  JCC. 

DOW. 


SM. 
BKL. 


EKT. 
EKT. 


FMT. 

EK,  FMT,  MEE,  MRT. 

EK. 

KPT. 


IDC. 
VPC. 
IDC. 


FMT. 
G. 


170 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  21B. —Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer ,  iS65--Continued 


MISCELLANEOUS  CHMICALS,    CYCLIC--Continued 

Photographic  chemicals — Continued 
*p-Diethylaminobenzenediazonium  chloride  (p-Diazo-N,  N- 
diethylaniline)  -  zinc  chloride. 
p-Diethylaminobenzenediazonium  ( p-Diazo-N, N- diethy lani- 
line)  fluoroborate. 

N,  N-Diethyl-p-phenylenediamine  hydrochloride 

*N, N-Diethyltoluene-2. 5- diamine,  monohydrochloride 

2.5-Dihydroxy-p-benzenedisulfonic  acid,  dipotassium  salt 

2,5-Dihydroxybenzenesulfonic  acid 

2, 7-Dihydroxy-3, 6- naphthalene  sulfonate 

p-Dimethylaminobenzenediazonium  chloride  ( p-Diazo-N,  N- 

dimethylaniline)  -  zinc  chloride. 
<i-(2',6'-Dimethylmorpholinyl)benzenediazonium  chloride  - 
zinc  chloride. 

p-Diphenylaminediazonium  sulfate 

p-(N-Ethylbenzimido)benzenediazonium  chloride  (p-Diazo- 

N-henzyl-N-ethylaniline)  -  zinc  chloride. 
p-[ Ethyl(  2-hydroxyethyl) amino] benzenediazonium  chloride 
(p-Diazo-N-ethyl-N-hydroxyethylaniline)  -  zinc  chlo- 
ride. 

N-Ethyl-N-hydroxyethyl-p-phenylenediamine  sulfate 

N-Ethyl-N-(p-methanesulfonamidoethyl)toluene-2,5-diamine 
sulfate. 

Hydroquinone  ( Hydroquinol) 

p-[( 2-Hydroxyethyl) methylamino]benzenediazonium  chloride 
( p-Diazo-N- hydroxyethyl-N-methylaniline)  -  zinc 
chloride. 
1- Hydroxy- N-( 2-hydroxyethyl) -2-naphthamide  (2,3-Oxynaph- 
thoic-mono-ethanolamide) . 

l-(3-Hydroxyphenyl)urea 

4-Methoxy-l-naphthol 

p-Methylaminophenol  sulfate  (Metol) 

5-Methylbenzotriazole 

2-Methylbenzoxazole 

4-Methyl-l-phenyl-3-pyrazolidinone 

4-Morpholinylbenzenediazonium  chloride  -  zinc  chloride 
salt. 

4-Morpholinylbenzenediazonium  fluoroborate 

6-Nitrobenzimidazole 

Octylphenyl  salicylate 

Phenylmercaptotetrazole 

Phenyl-5-mercaptotetrazole 

l-Phenyl-3-pyrazolidinone 

4-Phenylpyrocatechol 

2-Eesorcylic  monoethanolamide 

4,4'-Thiodiresorcinol  (Diresorcyl  sulfide) 

l-(  2, 4, 6-Trichlorophenyl)  -3-(  4-nitroanilino)  -2-pyraz- 
olin-5-one. 

All  other 

Phthalic  acid,  lead  salt,  dibasic 

*Pinene 

Poly-4-(  2-acryloxy  ethoxy) -2-hydroxybenzophenone 

Polyethylene  terephthalate 

Poly-2-hydroxy-4-methacryloxybenzophenone 

Polyvinyl  phthalate 

*Propyl  gallate 

Pyrogallol  (Pyrogallic  acid) 

Resorcinol  monobenzoate 

Rosin  acid  salts: 

Aluminum  resinate 

Calcium  resinate 

Copper  resinate 

Iron  resinate 

Lead  resinate 

Manganese  resinate 

Zinc  resinate 

All  other 

Salicylanilide 

Salicyclic  acid,  lead  salt 

Silicones 


Manufacturers'  identification  codes 
( according  to  list  in  table  22) 


FMT,  G,  IDC,  MRT. 
IDC. 


EKT,  PMT. 
HCT,  FMT,  IDC. 


FMT. 
FMT,  IDC. 


FMT. 
FMT,  MRT. 


FMT,  IDC. 


IDC. 
EKT. 


EKT. 
FMT,  IDC. 


FMT,  IDC. 
x. 

IK. 
EK. 

FMT. 
WAY. 
IDC. 

IDC. 

EK,  FMT. 

EKT. 

TNC. 

FMT. 

GGY,  WAY. 

x. 

FMT. 

HCC. 

EKT. 

EK,  EKT,  FMT. 

NTL. 

CBY,  GLD,  HNW,  HPC. 

ACY. 

DUP,  EK. 

DUP. 

EK. 

EKT,  HN,  HSH. 

MAL. 

HCT. 

JMS. 

JMS,  SW. 

JMS. 

HSH,  JMS. 

JMS,  MCI. 

JMS. 

JMS,  SW. 

JMS. 

DUP,  FIN,  MEE,  PCW. 

NTL. 

DCC. 


MISCELLANEOUS  CHEMICALS 


171 


TABLE  21B. — Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer ,  1965 — Continued 


Manufacturers'    identification  codes 
( according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,    CYCLIC— Continued 

Sodium  cresoxide  (Cresylic  acid,    sodium  salt) 

Sodium  ferric  ethylenediamine  di-o-hydroxyphenylacetate — 

Sucrose  benzoate 

Sulfosalicylic  acid 

Tall  oil  fatty  acid  chloride 

*Tall  oil  salts  (Linoleic- rosin  acid  salts): 

Barium  zinc  tallate 

*Calcium  tallate 

*Cobalt  tallate 

Copper  tallate 

*Iron  tallate 

Lead  manganese  tallate 

*Lead  tallate 

^Manganese  tallate 

*Zine  tallate 

Tannic  acid 

*Tanning  materials,  synthetic: 

Hydroxytoluenesulfonlc  acid,  formaldehyde  condensate 
( Cresol- formaldehyde  sulfonate),  sodium  salt. 
*2-Naphthalenesulfonie  acid,  formaldehyde  condensate  and 
salts. 
1-Pheno 1-2- sulfonic  acid,  formaldehyde  condensate 
(Phenol- formaldehyde,  sulfonated) . 

1-Pheno 1-4- sulfonic  acid,  formaldehyde  condensate 

Styrene  maleic  anhydride  interpolymer,  partial  sodium 

salt. 
Sulfonyldiphenolsulfonic  acid,  formaldehyde  condensate-- 

All  other 

Tetra(n- butyl)  ammonium  picrate 

3,3',4,4'-Tetrachlorophenylurea 

1,2,3,4-Tetrahydronaphthalene  (Tetralin) 

Tetrahydrothiophene 

Tetramethylaminoethylpiperazine 

Tetraphenyltin 

*Textile  chemicals,  other  than  surface-active  agents: 
1, 3-Bis(  hydroxymethyl) -2- imidazolidone  ( Dimethylol 
ethylene  urea) . 

N',N'-Diphenyl-l,2-propanediamine 

l-[  ( Octadecyloxy)  methyl]  pyridinium  chloride 

Phenol,  sulfurated 

Tetrahydro-3, 5-bis(  methoxymethyl) -4H- 1, 3, 5-oxadiazin-4- 
one  ( 1, 3-  Bis(  methoxymethyl)  uron) . 

2,2',4,4'-Tetrahydroxybenzophenone 

All  other 

2,2'-Thiobis[4-ehlorophenol] 

2,2'-Thiobis[4, 6-dichlorophenol] 

[  2,2'-Thiobis(4-octylphenolate)]  -n-butylamine  nickel 

o-Toluidine  formaldehyde  hydrochloride 

Triallyl  cyanurate 

Triaryl  phosphites 

3,4',5-Tribromosalieylanilide 

3,4',5-Tribromosalicylanilide  and  dibromosalicylanilide 
mixtures. 

3,4,4'-Triehlorocarbanilide _ — 

Trichloromelamine 

l,3,5-Triehloro-s-triazine-2,4,6(lH,3H,5H)trione  (Tri- 
chloroisocyanuric  acid) . 

Tri-(m,  p)-cresyl  borate 

p-Trifluoromethylbenzonitrile 

s-Trioxane 

Triphenyl  phosphite 

Triphenylphosphorus 

Triphenyltin  acetate 

Triphenyltin  chloride 

Tris(  1-aziridinyl)  phospnine  oxide 

2, 4, 6-Tris( 2-hydroxy-4-octyloxyphenyl) -s-triazine 

Uridine  derivatives 

l-Vinyl-2-pyrrolidinone,  monomer  and  polymer 

l-Vinyl-2-pyrrolidinone  -  vinyl  acetate  copolymer 


DEX,  GOC. 
GGY. 
VEL. 

MON,  MRK. 
G. 

HSH. 

CCA,  HNX,  HSH,  MCI,  MLD,  TRO,  VITC. 

CCA,  CCC,  FER,  HNX,  MCI,  MLD,  SHP,  SRR,  TRO,  WTC. 

MCI,  MLD,  SHP,  SRR. 

CCA,  MCA,  MCI,  MLD,  SRR,  WTC. 

HSH,  MCI. 

CCA,  CCC,  FER,  HNX,  HSH,  MCI,  MLD,  SHP,  SM,  SRR,  TRO, 

WTC. 

CCA,  CCC,  FER,  HNX,  HSH,  MCI,  MLD,  SHP,  SRR,  TRO,  WTC. 

CCA,  HSH,  MCI. 

HSH,  MAL. 

GGY. 

AKS,  GRD,  NOP,  NYC,  RH. 

NAC,  NOP,  RH. 


AKS. 
DUP. 

G. 

GGY. 

MED. 

OTC. 

DUP. 

0R0,  PAS. 

JCC. 

x. 

ACY,  AKS. 

SNW. 
DUP. 


AKS, 

x,    x. 

GIV. 

MON, 

SDH. 

ACY. 

RBC. 

ACY. 

WES. 

DOW, 

FIN,    MEE,    TRO 

FIN. 

MON. 

WTH. 

FMB, 

MON. 

USB. 

PIC. 

CEL. 

HK, 

MON. 

PLB. 
G. 

G. 


172 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  21B. 


-Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


Manufacturers1  identification  codes 
( according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC 

*Acetaldehyde 

Acetamide 

Acetamidine  hydrochloride 

Aeetamidoethanol  ( N-Acetylethanolamine) 

*Acetic  acid,  synthetic,  100$ 

*Acetic  acid  salts: 

Aluminum  acetate 

Aluminum  subacetate 

Ammonium  acetate 

Barium  acetate 

Cadmium  acetate 

Calcium  acetate 

Chromium  acetate 

Cobalt  acetate 

*Copper  acetate 

Lead  acetate 

Lead  subacetate 

Lead  tetraacetate 

Magnesium  acetate 

Manganese  acetate 

Mercuric  acetate 

Methylmercury  acetate 

Nickel  acetate 

*Potassium  acetate 

Silver  acetate 

*Sodium  acetate 

Sodium  diacetate 

Strontium  acetate 

Uranyl  acetate 

*Zine  acetate 

* Zirconium  acetate 

*Acetie  anhydride,  100$: 

From  acetaldehyde 

From  acetic  aeid_,  other  than  recovered,  by  the  vapor- 
phase  process. 
From  acetic  acid,  recovered,  by  the  vapor-phase  process- 

From  ethylene 

Acetin: 

Mono- 

Tri - 

Acetoacetamidoacetamide 

*Acetone: 

*From  cumene 

*From  isopropyl  alcohol 

*A11  other 

Acetone,  dimethyl  acetal  (2,2-Dimethoxypropane) 

Acetone  semicarbazone 

Acetonitrile 

Acetyl  chloride 

Acetyl  peroxide 

Aconitic  acid 

Acrolein  ( Acrylaldehyde) 

*Acrylic  acid 

Acrylic  monomers 

*Aerylonitrile 

*Adipic  acid 

Adiponitrile 

*Alcohols,  monohydric,  unsubstituted: 
*Alcohols  C9  or  lower: 

Allyl  alcohol 

Amyl  alcohols: 
Unmixed: 

2»Methyl-2-butanol  (tert-Amyl  alcohol) 

3-Methylbutanol 

1-Pentanol 

2-Pentanol 

3-Pentanol 

Mixed: 

Fusel  oil,  refined 

Other  than  fusel  oil 


CEL, 

COM, 

DIX, 

DUP, 

EKT, 

HPC,    MON,    PUB,    SHC,    UCC 

ACG. 

MRK. 

RBC. 

CEL, 

EKT, 

HPC, 

PUB, 

SNC, 

UCC. 

ACY, 

UCC. 

MAL. 

ACG, 

BKC, 

MAL, 

WSN. 

ACG, 

BKC, 

MAL. 

MAL, 

SHP. 

ACG, 

BKC, 

MAL, 

WSN. 

ACY. 

BKC, 

HSH, 

SHP. 

ACG, 

BKC, 

UCC 

ACG, 

BKC, 

MAL, 

SRR, 

sw. 

ACG, 

BKC, 

MAL. 

ABA. 

ACG, 

BKC. 

HSH, 

SHP. 

BKC, 

MAL. 

DUP. 

BKC, 

HSH, 

SHP. 

ACG, 

BKC, 

CWL, 

MAL, 

UCC, 

WSN. 

MAL. 

ACG, 

BKC, 

CEL, 

DAN, 

EKT, 

MAL,    UCC,   WSN. 

UCC. 

BKC. 

BKC. 

ACG, 

BKC, 

HSH, 

MAL, 

SNW, 

UCC. 

HSH, 

NTL, 

SNW. 

HPC. 

CEL, 

EST. 

CEL. 

UCC. 

ARC, 

HAL. 

EKT, 

WM. 

RBC. 

ACP, 

CLK, 

HPC, 

MON, 

SHC, 

SKO,    SOC. 

EKT, 

EN  J, 

SHC, 

UCC. 

CEL, 

DIX, 

HPC, 

TBK. 

DOW. 

NOR. 

EKX, 

SOH, 

UCC. 

TBK. 

WTL. 

PCW. 

SHC, 

UCC. 

BFG, 

CEL, 

DBC, 

MMM, 

UCC. 

BH. 

ACY, 

BFG, 

DUP, 

MON, 

SOH, 

UCC. 

CEL, 

DUP, 

MON, 

NAC, 

RH. 

DUP, 

MON. 

DOW, 

OMC, 

SHC. 

PAS, 

UCC. 

UCC. 

TBK, 

UCC. 

UCC. 

EK. 

PUB. 

CEL, 

PAS, 

UCC. 

MISCELLANEOUS  CHEMICALS 


173 


TABLE  21B. —Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965—  Continued 


MISCELLANEOUS  CHEMICALS,    ACYCLIC— Continued 

*Aleohols,    monohydric,    unsubstituted — Continued 
*Alcohols  C9  or  lower — Continued 
*Butyl  alcohols: 
Primary: 

*Iso  ( Isopropylcarbinol) 

*Normal  ( n-Propylcarbinol) 

Secondary  (Methylethylcarbinol) 

Tertiary  (Triinethylcarbinol) 

Mixed 

*Ethyl  alcohol,    synthetic 

2-Ethyl-l-butanol  (sec-Hexyl  alcohol) 

*2-  Ethyl-  1-hexanol 

2-Ethyl-4-methyl-l-pentanol 

4-  Ethyl-  l-octyn-3-ol 

Heptyl  alcohol 

*Hexyl  alcohol 

3-Hexyne-2-ol 

*Iso-octyl  alcohols 

*Isopropyl  alcohol 

^Methanol,  synthetic 

2-Methyl-3-buten-2-ol 

2-Methyl-3-butyn-2-ol 

4~Methyl-2-pentanol  ( 1-Methylisobutylcarbinol) 

3-Methyl-l-pentyn-3-ol  (Methylparafynol) 

1-Octanol ■ 

2-0ctanol 

Octanols,    other 

Propyl  alcohol  (Propanol) 

2-Propyn-l-ol 

All  other 

*Alcohols  C10  or  higher: 

*Deeyl  alcohols 

3,9-Diethyl-6-tridecanol 

Dodecyl  alcohol  (Lauryl  alcohol)  (95$) 

7-Ethyl-2-methyl-4-hendecanol 

*l-Hexadeeanol  (Cetyl  alcohol)  (95<f) 

*l-0ctadecanol  (Stearyl  alcohol)  (95%) 

cis-9-0ctadecen-l-ol  (Oleyl  alcohol) 

Tallow  alcohol 

Tetradecanol 

1-Tridecanol 

Tridecanol  mixed  isomers 

2, 6, 8-Trimethyl-4-nonanol 

All  other 

Aldol  (Acetaldol) 

ALkane  and  aliene  hydrocarbons 

Aliyl  and  aliylene  hydrocarbons 

Aliyl  sulfides,    mixed 

l-Allyl-3-(  2-hydroxyethyl) -2-thiourea  ( N-p-Hydroxyethyl- 
N'-allylthiourea) . 

Allyl  isocyanate 

Allyl  isothiocyanate,    nonflavoring  grade 

Allyl  methacrylate 

Allyl  nitrile  (Allyl  cyanide) 

l-(Allyloxy)-2,3-epoxypropane  (Allyl  glycidyl  ether) 

3-(Allyloxy)-l,2-propanediol  (AlLyl  glyceryl  ether) 

Aluminum  isopropoxide  (Aluminum  isopropylate) 

Amidinourea  (Guanylurea)    phosphate  and  sulfate 

*Amines: 

*Butylamine 

tert-Butylamine 

n-Butylethylamine 

Butylmethylamine 

Diallylamine 

*Dibutylamine 

Dibutylmethylamine  (Methylbutylbutylamine) 

*Diethylamine ■ 

Diethylamine  hydrochloride 

Diethylaminopropylamine 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


CEL,    DBC 

EKX, 

ENJ,    SHC,    UCC. 

CEL,    CO, 

DBC, 

EKX,    ENJ,    SHC,    UCC. 

ENJ,    SHC 

SHC. 

CEL,    DBC, 

EKX. 

CEL,    DUP, 

EKX, 

ENJ,    HPC,    PSP,    SHC,    UCC,    USI. 

UCC. 

CEL,    EKX, 

ENJ, 

SHC,    UCC. 

EKX. 

cue. 

EKX. 

EKX,    ENJ, 

UCC. 

LIL. 

EKX,    ENJ, 

GOC, 

HOU,    0X0,    TID,    UCC. 

ENJ,    SHC, 

TBK, 

UCC. 

ACN,    BOR, 

CEL, 

COM,    DUP,    ESC,    GYR,    HPC,    WON,    RH,    SPN 

UCC. 

cue. 

cue. 

SHC,    UCC. 

cue. 

DUP. 

PG,    RH,    WTH. 

IFF. 

CEL,    UCC. 

G. 

CEL,    CO, 

PG,    TNA. 

DUP,    ENJ, 

GOC, 

HOU,    0X0,    PG,    TBK,    TID,    TNK,    UCC. 

UCC. 

DUP,    PG, 

RH. 

UCC. 

ADM,    DUP, 

ENJ, 

GIV,    PG,    RH. 

ADM,    DUP, 

PG, 

RH. 

ADM,    DUP. 

ADM. 

PG. 

ENJ,    GOC. 

UCC. 

UCC. 

ADM,    CO, 

EKX, 

PG,    RH,    SHC,    TNA. 

UCC. 

HMY. 

ADM,    GOC. 

OHO. 

FMT,    IDC. 

CTN. 

ICO. 

SAR. 

KF. 

SHC. 

SHC. 

CHT,    SFA. 

ACY. 

EKT,    PAS, 

UCC, 

VGC. 

»N,    RH. 

PAS. 

PAS. 

SHC. 

'AS,    UCC, 

VGC. 

UCC. 

DUP,    PAS, 

UCC, 

VGC. 

174 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  21B. 


--Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1965 — Continued 


MISCELLANEOUS  CHEMICALS,    ACYCLIC— Continued 

*Amines —  Continued 

Diethylenetriamine 

N, N-Diethylethylenediamine 

N  jN1 -Diethyl- 1, 4-  pentanediamine  (Novoldiamine) 

N, N-Diethyl-l,3-propanediamine 

Diisobutylamine 

Diisopropylamine 

*Dimethy lamine 

Dimethylamine  hydrochloride 

Dimethylamine  sulfate 

Dime thy land  nopropy lamine 

Dipentylamine  (Diamylamine) 

Dipropy lamine 

Dipropylenetriamine 

*Ethy  lamine 

Ethylenediamine 

Ethylenediamine  sulfate 

n-Heptylamine 

1, 6-Hexanediamine  ( Hexamethylenediamine) 

N-Hexylamine 

3,3'-Iminobispropylamine 

Isobuty lamine 

*Isopropy lamine 

Methy lamine  hydrochloride 

*Methylamine,  mono-  

N-Methylethylenediamine 

N-Methyl-l,3-propanediamine 

Methyltriethylenediamine 

Pentaethylenehexamine 

Pentylamine  (Mono amy lamine) 

1, 2-Propanediamine  (Propylenediamine) 

1, 3-Propanediamine 

Propylamine 

Tetraethylenepentamine 

N,N,N',N'-Tetramethyl-l,3-butanediamine 

Tetramethylethylenediamine 

Tributy lamine 

Triethylamine 

Triethylenetetramine 

*Trimethy lamine 

Tripenty lamine 

All  other 

2-Amino-l-butanol 

1-Aminoethanol  (Acetaldehyde  ammonia) 

Aminoethoxyethanol 

2-(  2-Aminoethylamino) ethanol  ( Aminoethylethanolamine) 

2-Aminoethyl  vinyl  ether 

Aminoguanidine  bicarbonate 

2- Amino-2-  ( hydroxymethyl) - 1, 3-propanediol  ( Tris(  hydroxy- 
methyl)  aminomethane) . 

2-Amino-2-methyl-l-propanol  hydrochloride — — 

2-Amino-l-propanol 

3-Amino-l-propanol 

Amyl  acetates,  90$: 

Amyl  acetate  (n-Pentyl  acetate) 

Isopentyl  acetate  ( Isoamyl  acetate) 

Mixed 

Azelaic  acid 

1,  l'-Azobisformamide  ( Azodicarbonamide) 

2,2'-Azobis(2-methylpropionamidine)  hydrochloride 

Behenamide  (Docosanamide) 

Behenic  acid 

Bis(2-butoxyethyl)  ether  (Diethylene  glycol  di-n- butyl 
ether) . 

Bis(  2-chloroethoxy) methane  ( Dichloroetnylformal) 

*Bis(2-chloroethyl)  ether  ( Dichlorodiethyl  ether) 

Bis(2-ehloroethyl)  and  bis(2-chloro-l-methylethyl)  ethers 

mixed. 
Bis(  chloromethyl)  ether 


Manufacturers'  identification  codes 
( according  to  list  in  table  22) 


DOW, 

JCC, 

UCC. 

ALB, 

COK. 

SDH. 

JCC. 

PAS. 

PAS, 

UCC, 

VGC. 

COM, 

DUP, 

PAS,    RH. 

GAM, 

TNC. 

RH. 

UCC. 

PAS, 

VGC. 

PAS, 

UCC. 

UCC. 

ESC, 

PAS, 

UCC,    VGC. 

DOW, 

JCC, 

UCC. 

EK. 

ALB. 

CEL, 

DUP, 

MON. 

VGC. 

JCC, 

UCC. 

PAS, 

VGC. 

ESC, 

PAS, 

UCC. 

RBC. 

COM, 

DUP, 

ESC,  g,  p; 

ALB. 

ALB. 

JCC. 

DOW. 

EK, 

3AS. 

JCC, 

UCC. 

UCC. 

PAS, 

UCC. 

DOW, 

UCC. 

UCC. 

RH. 

PAS, 

VGC. 

PAS, 

UCC. 

ccw, 

DOW, 

UCC. 

COM, 

DUP, 

PAS,    RH. 

PAS. 

ALB, 

DUP, 

ONX,    UCC. 

COM. 

PAS. 

JCC. 

DOW, 

JCC, 

UCC. 

MEE, 

RH. 

TBJ. 

COM. 

SNW. 

LIL. 

UCC. 

PUB, 

TBK. 

FB, 

NW. 

CEL, 

PAS, 

UCC. 

EMR. 

FMT, 

NPI, 

USR. 

X. 

HUM. 

ADM. 

DOW, 

UCC. 

TKL. 

DOW 

JCC 

CMC,    UCC. 

WYN. 

MISCELLANEOUS  CHEMICALS 


175 


TABLE  21B.- 


-Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965-  -Continued 


Manufacturers'    identification  codes 
( according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC— Continued 

Bis(2-chloro-l-methylethyl)    ether  ( Dichloroisopropyl 

ether) . 
Bis(2-ethoxyethyl)    ether  (Di ethylene  glycol  diethyl  ether) 
Bis(hydroxyethyl)    ether  butynediol 

1, 3-Bis(  hydroxymethyl)  urea  ( Dimethylolurea) 

Bis[2-(2-methoxyethoxy)ethyl]   ether  ( Tetraethylene  glycol 

dimethyl  ether) . 
Bis(2-methoxyethyl)    ether  (Diethylene  glycol  dimethyl 
ether) . 

Bis(  tributyltin)    oxide 

Biuret 

Boron  organic  compounds: 

Boron  fluoride  ethyl  ether  complex 

Boron  trifluoride  monoethylamine  complex 

tert-Butylaminoborane 

Triethylborane 

Triethyl  borate 

Trimethoxyboroxine 

Trimethylaminoborane 

All  other 

N-Bromoaeetamide 

fj-Bromopropionic  acid 

1, 2(and  l,3)-Butanediol  (Butylene  glycol) 

1,4-Butanediol 

2,3-Butanediol  (2,3-Butylene  glycol) 

2,3-Butanedione  2-oxime 

1,2,4-Butanetriol 

*2-Butanone  (Methyl  ethyl  ketone) 

Butanone  mixture 

*2-Butanone  oxime 

*2-Butanone  peroxide 

2-Butene-l,4-diol 

l-Butoxy-2,3-epoxypropane  (Butyl  glycidyl  ether) 

2-Butoxyethanol  (Ethylene  glycol  monobutyl  ether) 

2-(2-Butoxyethoxy)ethanol  (Diethylene  glycol  monobutyl 

ether) . 
2-[2-(2-Butoxyethoxy)ethoxy] ethanol  (Triethylene  glycol 
monobutyl  ether) . 

2-(2-Butoxyethoxy) ethyl  acetate 

l-Butoxyethoxy-2-propanol 

2-Butoxyethyl  acetate 

*Butyl  acetates: 

Iso 

*Normal 

Secondary 

Tertiary 

Mixed 

Butyl  aery late 

Butylene  oxide 

Butyl  ether  (Di-n-butyl  ether) 

Butylethylthiourea 

*tert- Butyl  hydroperoxide 

2,2'-(Butylimino)diethanol  (N,N-Bis(2-hydroxyethyl)butyl- 
amine) . 

Butyl  isocyanate * 

Butyl  lactate 

n-Butyllithium 

sec-Butyllithium 

Butyl  maleate,  mono- 

Butyl  oxalate  partial  ester 

*tert-Butyl  peroxide  (Di-tert- butyl  peroxide) 

tert- Butyl  peroxyacetate 

tert- Butyl  peroxyisobutyrate 

tert-Butyl  peroxyisopropyl  carbonate 

tert- Butyl  peroxypivalate 

Butyl  vinyl  ether 

1-Butyne  ( Ethylacetylene) 

2-Butyne-l,4-diol 

Butyraldehyde 

Butyraldehyde  oxime 


DOW. 

ucc. 

G. 

DEC,  GLY,  x. 

ASL. 

ASL,  OMC. 

CCW,  x. 
SW. 

ACG. 

ACG. 

CAL. 

CAL,  TNA. 

USB. 

CAL. 

CAL. 

CAL,  SFA,  USB. 

ARA. 

ABB. 

CEL. 


EK. 

G. 

CEL, 

CEL. 

ALB, 

AZT, 

G. 

DOW, 

JCC, 

JCC, 


DIX,  ENJ,  SHC,  SPI,  UCC. 


CCA,  MID,  NAC,  TED. 
CAD,  NOC,  RIC,  UPR,  WTL. 


SHC. 

OMC,  SHC,  UCC. 

OMC,  SHC,  UCC. 


DOW,  OMC,  UCC. 

UCC. 
UCC. 
UCC. 


CEL, 

CEL, 

EK, 

ENJ. 

CEL. 

CEL, 

DOW, 

UCC. 

PAS. 

AZT, 

PAS. 

CTN, 
COM, 
FTE. 
FIE. 
RUB. 
DUP. 
AZT, 
WTL. 
WTL. 
PPG. 
WTL. 
UCC. 

cue. 

G. 

CEL, 
NAC. 


EKT,  UCC. 

EKT,  ENJ,  PUB,  UCC. 
ENJ,  HPC,  PUB,  SHC. 


DBC,  UCC. 
UCC. 


CAD,  UPR,  WTL. 


UPJ. 
CWN,  UPC. 


CAD,  SHC,  UPR,  WTL. 


HOC,  UCC. 


176 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  21B  -Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 — Continued 


Chemical 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 


*Butyric  acid 

Butyric  anhydride 

Butyrolactone 

Butyronitrile 

Butyryl  chloride 

*Caprolactam  (Hexahydro-2H-azepin-2-one) 

Capro lactone 

*Carbon  disulfide 

^Cellulose  esters: 

^Cellulose  acetate 

Cellulose  acetate  butyrate 

Cellulose  acetate  propionate 

Cellulose  propionate 

Nitrocellulose  (Cellulose  nitrate) 

^Cellulose  ethers: 

Ethylcellulose 

Ethylhydroxyethylcellulose 

Hydroxyethylcellulose 

Methylcellulose 

*Sodium  carboxymethylcellulose,  100% 

Sodium  carboxymethylhydroxyethylcellulose 

Cetyl  chloride 

Cetyl  lactate 

*Chloral  ( Trichloroacetaldehyde) 

Chloroacetamide 

*Chloroacetic  acid,  mono-  

Chloroacetic  acid,  mono-,  derivatives: 

Butyl  chloroacetate 

Ethyl  chloroacetate 

2-Ethylhexyl  chloroacetate 

*Methyl  chloroacetate 

Sodium  chloroacetate 

Chloroacetonitrile 

Chloroacetyl  chloride 

P-Chloroallyl-N-methylamine 

Chlorocholine  chloride ~~ 

2-Chloro-l,  1-dimethoxyethane  (Dimethyl  chloroacetal) - 
*2-Chloro-N, N-dimethylethylamine  ( Dimethylaminoethyl 
chloride)  hydrochloride. 

2-Chloro-N,N-dimethylpropylamine 

3-Chloro-N, N-dimethylpropylamine  hydrochloride 

2-Chloroethanol  (Ethylene  chlorohydrin) 

2-Chloroethylamine 

2-Chloroethyl  chloroformate 

2-Chloroethyl  vinyl  ether 

Chloromethyl  methyl  ether -■ 

l-Chloro-l-penten-3-one  (p-Chloro vinyl  ethyl  ketone)- 
3-Chloro-l,2-propanediol  (Glycerol  a-chlorohydrin)--- 

l-Chloro-2-propanone  ( Chloroacetone) 

N-Chlorosuccinimide  ( Succinichlorimide) 

2-Chlorotriethylamine  hydrochloride 

Chlorotrlmethylsilane 

Choline  base 

Citric  acid 

Citric  acid  salts: 

Ammonium  citrate 

Calcium  citrate 

Ferric  ammonium  citrate 

Ferric  citrate 

Ferrous  calcium  citrate 

Potassium  citrate 

Sodium  citrate 

All  other 

Coconitrile 

Coconut  oil  amide 

Cottonseed  oil  acids,  ammonium  salt 

Cottonseed  oil  nitrile 

Creatine  and  creatinine 

Crotonaldehyde 


Manufacturers'  identification  codes 
( according  to  list  in  table  22) 


CEL,  EKT,  UCC. 
EKT,  UCC. 


DBC,  DUP,  NAC. 

UCC. 

ACG,  BKT,  FMB,  PAS,  PPG,  SF. 

AV,  CEL,  DUP,  EKT. 

EKT. 

EKT. 

CEL. 

DUP,  HPC. 


DOW, 

HPC. 

HPC. 

HPC, 

UCC. 

DOW. 

BUK, 

DUP,    HPC,    KON,    WYM. 

HPC. 

BC. 

VND. 

DA,    FMB,    GGY,    MTO. 

BPC, 

DOW. 

BUK, 

DA,    DOW,    HPC,   MON. 

MON. 

DOW, 

KF,   WON. 

MON. 

BPC, 

DOW,    KF. 

DOW. 

BPC. 

DOW, 

DUP. 

LIL. 

ACY. 

LIL. 

ABB, 

GAM,    HEX,   MCH,    NES,    PAS 

SK. 

MCH. 

CMC, 

UCC. 

ICI. 

CTN. 

UCC. 

HK, 

X. 

ABB. 

EVN, 

ICO,    OTC. 

EK, 

MRK. 

ARA, 

NAC. 

MCH, 

PAS,    X. 

DCC. 

EH. 

MLS, 

PFZ. 

MAL, 

PFZ. 

PFZ. 

MAL, 

PFZ. 

MAL. 

X. 

MLS 

PFZ. 

MLS 

PFZ. 

MLS 

FOR, 

ARC 

CRT,   PG. 

GLY 

FOR 

PFN 

CEL 

EKT,    UCC. 

MISCELLANEOUS  CHEMICALS 


177 


TABLE  21B.  --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 — Continued 


Chemical 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 


Crotonic  acid  (2-Butenoic  acid) 

Crotononitrile 

2-Cyanoacetamide 

Cyanoacethydrazide 

Cyanoacetic  acid 

Cyanogen  bromide 

3-Cyanopropylamine 

1, 10-Decanediol 

Decanoyl  chloride 

*Decanoyl  peroxide 

Dialdehyde  starch 

Diallylcyanamide 

Diallyl  maleate 

1, 2-Dibutoxyethane  (Ethylene  glycol  di-n- butyl  ether)  - 

2-Dibutylaminoethanol 

*Dibutyl  fumarate 

*Dibutyl  maleate 

1, 3-Dibuty 1-2- thiourea 

Dibutyltin  compounds: 

Dibutylmethoxytin  (Dibutyltin  methoxide) 

Dibutyltin  bis(  lauryl  mercaptide) 

Dibutyltin  dichloride 

Dibutyltin  dilaurate 

Dibutyltin  maleate 

Dibutyltin  mercaptopropionate 

Dibutyltin  oxide 

All  other 

Dichloroacetaldehyde 

Dichloroacetic  acid 

2,2-Dichloro-l,  1-difluoroethyl  methyl  ether 

Dichlorodimethylsilane 

Dichloromethylsilane 

Dichloromethylvinylsilane 

l,3-Dichloro-2-propanol 

Dicyanobutene 

Diethyl  allyl( 1-methylbutyl) malonate 

Diethylaluminum  chloride 

Diethylaluminum  iodide 

Diethylaminoethanethiol 

*2-Diethylaminoethanol 

2-(2-Diethylaminoethoxy)  ethanol 

2-Diethylaminoethyl  methacrylate 

Diethylaminopropionamide 

Diethyl  sec-butylethylmalonate 

Diethyl  butylmalonate 

Diethyl  sec- butylmalonate 

Diethylcarbamoyl  chloride 

Diethyl  carbonate  (Ethyl  carbonate) 

Diethyl  diethylmalonate  (Diethyl  malonic  ester) 

*Diethylene  glycol 

Diethylene  glycol,  borated 

Diethylene  glycol  chloroformate 

Diethyl  ( ethoxymethylene) malonate 

Diethyl  ethylisopentylmalonate 

Diethyl  ethylmalonate  (Ethyl  malonic  ester) 

Diethyl  ethyl(  1-methylbutyl)  malonate 

Diethyl  ethyl(3-methylbutyl)  malonate 

Diethyl  ethyl(  1-methylpropyl)  malonate 

Di-2- ethyl- 1-hexyl  fumarate 

Di-2- ethyl- 1-hexyl  maleate 

Diethylhydroxylamine 

N,  N-Diethylhydroxylamine  sulfate 

Diethyl  maleate 

Diethyl  malonate  (Malonic  ester) 

Diethyl  ( 1-methylbutyl) malonate 

Diethyl  (3-methylbutyl)  malonate 

Diethyl  ( 1-methylpropyl) malonate 

Diethyl  oxalate  (Ethyl  oxalate) 

Diethyl  phosphorochloridothioate — 


EEC. 

KF. 

KF. 

KF. 

KF. 

ffl. 

EKT. 

NEP. 

TBK,  UCC. 

CAD,  UPR,  WTL. 

MLS. 

ACY. 

FMP. 

DOW. 

AAC,  PAS. 

MON,  PCC,  PFZ,  RCI,  RUB. 

CUC,  DUP,  GRH,  MON,  PCC,  RCI,  RUB. 

PAS,  RBC. 

CCA. 
x. 

CCW,  x. 

CCA,  x. 

CCA,  x. 

CCA,  x. 


PAS,  UCC. 


FMP. 


CAU,  DIX,  DOW,  G,  HCH,  JCC,  CMC,  UCC,  WYN. 


ABB, 

GAM 

CTN 

BPC 

ACN 

GLY. 

PPG, 

KF. 

LIL. 

BPC,  LIL. 

ABB,  BPC. 

BPC. 

BPC. 

RUB. 

RUB. 

PAS. 

EK. 

ACY,  ICO,  UCC. 

ABB,  KF,  LIL. 

ABB,  BPC,  LIL. 

BPC. 

BPC. 

FMP. 

MON,  SF. 


l,3-Diethyl-2- thiourea |  pas,  RBC 


178 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  21B  —Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965—  Continued 


Chemical 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

Diethylzinc 

Diglycolio  acid 

Dihexyl  fumarate 

Dihydropseudoionone 

2,4-Dihydroxy-3,3-dimethylbutyric  acid,  Y- lactone  (Panto- 
lactone) . 

l,3-Dihydroxy-2-propanone  (Dihydroxy  acetone) 

Diisobutylaluminum  chloride 

Diisobutylaluminum  hydride 

Diisononyl  maleate 

Diiso-octyl  fumarate 

2-Diisopropylaminoethanol  ( N,  N-Diisopropylethanolamine)  — 

Diisopropylammonium  nitrite 

Diisopropylcarbodiimide 

Diisopropyl  peroxydicarbonate  ( Isopropyl  percarbonate) 

1,3-Diisopropy 1-2- thiourea 

*Dilauryl  3,3'-thiodipropionate  (Didodecyl  thiodipropio- 
nate) . 

Dimethoxyethane  ( Ethylene  glycol  dimethyl  ether) 

N,N-Dimethylacetamide 

N,  N-Dimethylacetoaeetamide 

*2-Dimethylaminoethanol 

Dimethylaminoethyl  methaerylate 

Dime thy lamino-2-propanol 

3-Dimethylaminopropionitrile 

N-(3-Dimethylaniinopropyl)oleamide 

Dimethylcarbamoyl  chloride 

Dimethyl  carbonate 

2, 5-Dimethyl-2, 5-di(  tert-butylperoxy) hexane 

2,5-Dimethyl-2,5-di(tert-butylperoxy)hexyne-3 

N,  N-Dimethylformamide 

2, 6-Dimethyl-4-heptanol  ( Diisobutylcarbinol) 

2,5-Dimethyl-2,5-hexanediol 

2,5-Dimethylhexane-2,5-diperoctoate 

2, 5-Dimethyl-3-hexyne-2, 5-diol 

1, 1-Dimethylhydrazine 

Dimethyl  malonate 

Di(4-methyl-2-pentyl)  maleate 

0, 0-Dimethyl  phosphorochloridothioate 

2,2-Dimethyl-l,3-propanediol  (Neopentyl  glycol) 

Dimethylthiophosphoryl  chloride 

Dioctanoyl  peroxide  (Capryloyl  peroxide) 

Dioctyl  fumarate 

*Dioctyl  maleate 

*Dipropylene  glycol 

Distearyl  3,3'-thiodipropionate 

Dithiobis(  stearylpropionate)  (Distearyl  dithiodipropio- 
nate) . 

2,5-Dithiobiurea 

Dithiooxamide 

Ditridecyl  maleate 

n-Dodecane 

Dodecenylsuccinie  anhydride 

tert-Dodecyldisuccinamide 

n-Eicosane 

Epichlorohydrin 

*Erucamide 

Ethanedithiol 

*  Ethanolamines : 

*2-Aminoethanol  (Monoethanolamine) 

*2,2'-Iminodiethanol  (Diethanolamine) 

*2,2',2"-Nitrilotriethanol  (Triethanolamine) 

Ethanolamine  hydrochloride 

Ethanolamine  sulfate 

Ethanolamine  sulfite 

Ethanolamine  trihydrochloride 

*2-Ethoxyethanol  (Ethylene  glycol  monoethyl  ether) 

*2-(2-Ethoxyethoxy)ethanol  (Diethylene  glycol  monoethyl 
ether) . 


Manufacturers'    identification  codes 
( according  to  list  in  table  22) 


TNA. 

DUP. 
FB. 
GIV. 
CKL. 

BAX,    PFZ. 

TSA. 

TSA. 

RUB. 

HUB. 

PAS,    UCC. 

CMC. 

G. 

PPG. 

G. 

ACY,    CCW,    EVN,    HAB. 


ASL. 
DUP, 
EKT. 
AAC, 
AAC. 
COM, 
ACY. 
DUP. 
OTC. 
CTN. 
WTL. 
WTL. 
DUP. 
UCC. 

cue. 

UPR. 
CUC. 
FMP. 
KF. 


MON. 

JCC,    PAS,    RH,    UCC. 

UCC. 


RUB. 

MON, 

SF. 

EKX. 

TBK. 

CEM. 

MON. 

CRT, 

MON, 

PCC, 

RCI. 

CEL, 

DOW, 

JCC, 

OMC,    UCC,    WYN 

ACY, 

CCW, 

EVN. 

EVM. 

ACY. 

MAL. 

RUB. 

HMY. 

HMY, 

MON, 

NAC. 

SM. 

HMY. 

DOW, 

SHC, 

UCC. 

ADM, 

ARC, 

FIN, 

HUM. 

RBC. 

ACN, 

DOW, 

JCC, 

UCC. 

ACN, 

DOW, 

JCC, 

UCC. 

ACN, 

DOW, 

JCC, 

UCC. 

WSN. 

EVN. 

SUM. 

TNC. 

DOW, 

JCC, 

OMC, 

UCC. 

DOW, 

JCC, 

OMC, 

UCC. 

MISCELLANEOUS  CHEMICALS 


179 


TABLE  21B. — Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 — Continued 


Manufacturers'    identification  codes 
( according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC— Continued 

*2-[2-(2-Ethoxyethoxy) ethoxy] ethanol  (Triethylene  glycol 
monoethyl  ether) . 

2-(2-Ethoxyethoxy) ethyl  acetate 

2-Ethoxyethyl  acetate 

Ethoxymethylene  malononitrile 

Ethoxypropanol 

3-Ethoxypropionitrile 

1- Ethoxy- 1,3, 3- trimethoxypropane 

Ethyl  acetamidocyanoacetate 

Ethyl  acetamidomalonate 

*Ethyl  acetate,    85$ 

Ethyl  acetoacetate 

*Ethyl  aery late 

Ethyl  allyl-(  l-methyl-2-pentyl)    cyanoacetate 

Ethylaluminum  dichloride 

Ethylaluminum  sesquichloride 

2-Ethylaminoethanol  ( Ethylmonoethanolamine) 

2-Ethylbutyraldehyde 

2- Ethylbutyric  acid  (Diethylacetic  acid) 

Ethyl  carbamate 

Ethyl  carbodiimide 

Ethyl  chloroformate 

Ethyl  3-( ehloroformyl) propionate  (fj-Carbethoxypropionyl 
chloride) . 

Ethyl  cyanoacetate 

Ethylene,    from  ethyl  alcohol 

Ethylene  carbonate 

Ethylenediamine,    propoxylated 

*  Ethylene  glycol 

Ethylene  glycol  diacetate 

Ethylene  glycol  dimethacrylate 

* Ethylene  oxide 

Ethylene  trithiocarbonate 

*Ethyl  ether: 

Absolute 

Tech 

U.S.P, - — 

Ethylethoxymethylene  cyanoacetate 

Ethyl  formate 

2- Ethylhexanal  (a-Ethylcaproaldehyde) 

2-Ethyl-l,3-hexanediol 

2- Ethylhexanoic  acid  (x-Ethylcaproic  acid) 

*2- Ethylhexanoic  acid  (a-Ethylcaproic  acid)  salts: 

Aluminum  2-ethylhexanoate 

Barium  2-ethylhexanoate 

Cadmium  2-ethylhexanoate 

^Calcium  2-ethylliexanoate 

*Cobalt  2-ethylhexanoate 

Copper  2-ethylhexanoate 

Dibutyltin  di-2-ethylhexanoate 

Iron  2-ethylhexanoate 

*Lead  2-ethylhexanoate 

*Manganese  2-ethylhexanoate 

Nickel  2-ethylhexanoate 

Potassium  2-ethylhexanoate 

Rare  earths  2-ethylhexanoate 

Stannous  2-ethylhexanoate 

Strontium  2-ethylhexanoate 

*Zinc  2-ethylhexanoate 

Zirconium  2-ethylhexanoate 

*2-Ethyl-l-hexyl  acetate 

*2-Ethyl-l-hexyl  acrylate 

2-Ethylhexyl  cyanoacetate 

2-Ethylhexyl  methaerylate 

Ethyl  2-hydroxy-3-methylbutyrate  (  Ethyl  a-hydroxyiso- 

valerate) . 
2- Ethyl-2- ( hydroxymethyl) - 1, 3- propanediol  ( Trimethylol- 

propane) . 
2-  Ethyl-2- ( hydroxymethyl)  - 1, 3-propanediol  allyl  ethers— 


DOW, 

OMC, 

UCC. 

UCC. 

DOW, 

EKT, 

UCC. 

KF. 

UCC. 

ACY. 

KF. 

SDW. 

SDW. 

CEL, 

EKT, 

ENJ,    HPC,   MON,    PUB,    UCC 

EXT, 

FMP, 

UCC. 

CEL, 

DBC, 

RH,    UCC. 

LIL. 

TNA, 

TSA. 

TNA, 

TSA. 

PAS. 

UCC. 

UCC. 

EKL, 

FMP. 

OTC. 

CTN, 

FMP. 

ABB. 

KF. 

OH. 

DOW,  JCC,  UCC. 

PCS. 

ACN,  APD,  CAU,  CEL,  DOW,  DUP,  G,  HCH,  JCC,  OMC,  UCC, 

WYN. 
UCC. 
SAR. 

ACN,  CAU,  DOW,  G,  HCH,  JCC,  OMC,  SNO,  UCC,  WYN. 
EVN. 

MAL. 

ENJ,  HPC,  UCC,  USI. 

MAL,  OMS. 

KF. 

COM,  FB. 

EKX,  UCC. 

UCC. 

EKT,  UCC. 


WTC. 

CCA. 

CCA, 

CCA, 

CCA, 

CCA, 

x. 

CCA. 

CCA, 

CCA, 

MCI. 

CCA. 

CCA. 

WTC, 

CCA. 

CCA, 

CCA, 

CEL, 

CEL, 

G. 


CEL. 
CEL. 


FER,  HNX,  HSH,  MCI,  MLD,  SRR,  SW,  WTC. 
FES,  HNX,  HSH,  MCI,  MLD,  SHP,  SRR,  SW,  WTC. 
MLD,  SRR. 


HNX,  HSH,  MCI,  MLD,  SHP,  SRR,  SW,  WTC. 
HNX,  MCI,  MLD,  SHP,  SRR. 


HNX,  HSH,  MCI,  SRR,  SYP,  WTC. 

HNX,  WTC. 

EKT,  UCC. 

DBC,  UCC. 


180 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  21B. — Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 — Continued 


Manufacturers'    identification  codes 
( according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,   ACYCLIC— Continued 

Ethylidine  diacetate 

2, 2 '-( Ethylindno) diethanol  ( N-Ethyldiethanolamine)  — 

2-(  Ethylmercapto) ethanol 

Ethylmereuric  chloride 

Ethyl  ( l-methyl-2-pentyl) eyanoacetate 

Ethyl  propionate 

Ethyl  silicate  (Tetraethoxysilane) 

Ethyl  sulfate  (Diethyl  sulfate) 

Ethyl  vinyl  ether 

Fats  and  oils,    chemically  modified: 

Lard  oil,   nitrated 

Vegetable  oils,    brominated 

Other 

Fatty  acids,  chemically  modified: 

cc-Bromo(  lauric-stearic)  acids 

Castor  oil  fatty  acids,  dehydrated- 

All  other 

Fatty  acid  esters,  not  included  with  plasticizers  or 
surface- active  agents: 

Ethyl  stearate 

Hexadecyl  stearate 

Isopropyl  linoleate 

Isopropyl  myristate 

Isopropyl  oleate 

Methyl  ester  of  coconut  oil 

Methyl  esters  of  tallow 

Methyl  12-hydroxystearat*-~— 

Methyl  stearate 

All  other 

Fish  oil  fatty  acid  amide 

Flotation  reagents: 
Phosphorodithioates  ( Dithiophosphates) : 

Potassium  dihexyl  phosphorodithioate 

Sodium  di-sec-butyl  diethyl  phosphorodithioate — 

Sodium  di-see-butyl  phosphorodithioate 

Sodium  diethyl  phosphorodithioate 

Sodium  dihexyl  phosphorodithioate 

Sodium  diisopropyl  phosphorodithioate 

Other 

Xanthates: 

Potassium  n-butylxanthate 

Potassium  ethylxanthate 

Potassium  hexylxanthate 

Potassium  isopropylxanthate 

Potassium  pentylxanthates 

Potassium  sec-pentylxanthate 

Sodium  n-butylxanthate 

Sodium  sec-butyLxanthate 

Sodium  ethylxanthate 

Sodium  isobutylxanthate ; 

Sodium  isopropylxanthate 

All  other 

^Formaldehyde,  37$  by  weight 

Formajrd.de 

Formamidine  disulfide  dihydrochloride 

*Formic  acid,  90$ 

*Formic  acid  salts: 

Aluminum  formate 

Ammonium  formate 

Calcium  formate 

Chromic  formate 

Chromium  formate 

Copper  formate 

Lead  formate 

Nickel  formate 

Potassium  formate 

Sodium  formate,  refined 

Sodium  formate,  tech 

Thallous  formate — - — 


CEL. 

ucc. 

PAS. 

LIL. 

LIL. 

FB,  NW,  TBK. 

MTR,  SFA,  UCC 

UCC. 

UCC. 

SM. 
DOM. 
CHL,  x. 

DUP. 
BAC. 
ABB,  RH,  RT,  x. 


ICO. 
ARC, 
VND. 
TBK. 
CRT. 
STP. 
BFR, 
BAC. 
ICO. 
DRW, 
ADM. 


EWR,  ICI,  PCS,  PG,  RT. 


ACY. 
ACY. 
ACY. 
ACY. 
ACY. 
ACY. 
ACY. 


USR. 

ACY,  DOW. 

DOW. 

DOW. 

ACY,  DOW. 

DOW. 

KCC,  USR. 

ACY,  DOW. 

ACY,  DOW. 

DOW. 

ACY,  DOW. 

ACY,  DOW. 

ACN,  BOR,  CBC,  CEL,  COM,  DUP,  G,  HKD,  HN,  HPC,  ICI, 

MON,  RCI,  RH,  SPN,  TRJ,  UCP. 
DUP. 
WAY. 
DUP,  HN,  SF,  SNC,  UCC. 

SF,  SNW,  UCC. 

ACG,  WSN. 

TRJ. 

G. 

NAC. 

CTN. 

NTL. 

HSH. 

TNC. 

ACG,  BKC,  SF. 

HN,  HPC. 

EK. 


MISCELLANEOUS  CHEMICALS 


131 


TABLE  21B. --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  iS65--Continued 


Manufacturers'    identification  codes 
( according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC— Continued 

*Fumaric  acid 

Fumaric  acid,    lead  salt 

Geranyl  crotonate 

Glucoheptono lactone 

^Gluconic  acid,    tech 

Gluconic  acid,    ammonium  salt 

^Gluconic  acid,    sodium  salt,    tech 

Glucono-delta- lactone 

Glutaraldehyde 

Glutaraldehyde  bis[ sodium  bisulfite] 

Glutaric  anhydride 

Glycerol,    synthetic 

Glycidol  (2,3-Epoxy-l-propanol) 

Glycine  (Aminoacetic  acid),  tech 

Glycine,  cupric  salt 

Glycine  ethyl  ester  hydrochloride 

Glycine,  potassium  and  sodium  salts 

Glycol  adipate 

Glycolic  acid  ( Hydroxyacetic  acid) 

Glycolic  acid  salts: 

Aluminum  glycolate 

Sodium  glycolate 

Glycolonitrile 

Glyoxal 

Guanidine  hydrochloride 

4-Guanyl-l-isonitrosoguanyl-l-tetrazene 

*Halogenated  hydrocarbons: 

*l-Bromobutane  (n-Butyl  bromide) 

2-Bromobutane  (sec-Butyl  bromide) 

Bromochlorome thane 

l-Bromo-3-ehloropropane  (Trimethylenechloro bromide) 

2-Bromo-2-chloro-l,  1, 1-trifluoroethane 

1-Bromodecane 

1-Bromododecane 

Bromoethane  (Ethyl  bromide) 

1-Bromohexadecane  (Cetyl  bromide) 

1-Bromohexane  (n-Hexyl  bromide) 

l-Bromo-2-methylbutane 

l-Bromo-3-methyTbutane 

1-Bromo-octadecane 

1-Bromopentane  (n-Amyl  bromide) 

2-Bromopentane  ( 1-Methylbutyl  bromide) 

1- Bromopropane  (n-Propyl  bromide) 

2- Bromopropane  (isopropyl  bromide) 

2-Bromopropene 

3-Bromopropene  (Allyl  bromide) 

3-Bromopropyne 

Bromotrifluoromethane 

*Carbon  tetrachloride 

^Chlorinated  paraffins: 

Less  than  35$  chlorine 

355&-64#  chlorine 

6556  or  more  chlorine 

1-Chloro butane  (n- Butyl  chloride) 

2-Chlorobutane  (sec-Butyl  chloride) 

1-Chloro-l,  1-difluoroethane 

*Chlorodifluoromethane 

*Chloroethane  (Ethyl  chloride): 

Tech 

U.S.P 

*Chloroform: 

Tech 

U.S.P 

2-Chloro-3-hexyne 

*Chloromethane  (Methyl  chloride): 

Crude 

Refined  (refrigerant  grade) 

2-Chloro-2-methylpropane  ( tert- Butyl  chloride) 

3-Chloro-2-methylpropene  (Methallyl  chloride) 

Chloropentafluoroethane 


HN,  MON,  NAC,  PCC,  PFZ,  PTT,  SOC,  STP. 

NTL. 

FB. 

PFN. 

CWL,  DLI,  IBI,  PFZ. 

PFZ. 

CWL, 

DLI, 

UCC. 

IDC,  RZL. 

UCC. 

APD,  DOW,  SHC. 

DIX,  OTC. 

BPC,  CHT. 


DLI,  IBI,  PFZ,  PMP. 
PFZ. 


CIB. 

MED, 

TNC. 

ACY. 

UCC. 

ACY. 

REM. 

ABB, 

BPC,    DOW,   MCH 

ABB, 

BPC. 

DOW. 

DOW, 

MCH. 

ICI. 

G. 

DUP. 

DOW, 

MCH. 

EK. 

BPC. 

LIL. 

BPC, 

LIL. 

DUP, 

G. 

BPC, 

EK,    OPC. 

ABB, 

BPC,    LIL. 

DOW, 

EK. 

BPC. 

CLB. 

DOW. 

DUP. 

ACG,  ACS,  DA,  DOW,  FMB,  FRO,  PPG,  SF. 

HK. 

CCH,  DA,  DVC,  HK,  HPC,  KPS,  KPT,  WOI. 

DA,  DVC,  WOI. 

PUB,  UCC. 

ICO,  PLC. 

ACG,  DUP. 

ACG,  DUP,  KAI,  PAS,  UCC. 

AME,  DOW,  DUP,  HPC,  TNA,  USI. 

DOW,  SHC. 

ACS,  DA,  DOW,  DUP,  FRO,  SF. 

ACS,  DA,  DOW. 

LIL. 

DCC,  DOW,  TNA. 

ACS,  ANM,  DOW,  DUP,  FRO. 

EK. 

FMP. 

DUP. 


182 


SYNTHETIC  ORGANIC  CHEMICALS.  1965 

TABLE  21B  -Miscellaneous  chemicals  for  which  US  production  or  sales  were  reported,  identified  by 
1Abbfi  'S1B•  manufacturer,  1965—  Continued 


Chemical 


MISCELLANEOUS  CHIMICALS,  ACYCLIC— Continued 


*Halogenated  hydrocarbons—Continued 

2-Chloropropane  (Isopropyl  chloride) ----- 

3-Chloropropene  (Allyl  chloride) 

Chlorotrifluoroethylene  (Trifluorovinyl  chloride)-— 

Chlorotrif luoroethylene,    polymerized 

Chlorotrifluoromethane "' 

1, 2-Dibromo-l,  1-dichloroethane 

Dibromodifluoromethane 

1, 2-Dibromoethane  (Ethylene  dibromide) 

Dibromomethane  (Methylene  bromide) ■- 

1, 2-Dibromo-l,  1, 2, 2-tetrafluoroethane— 

Dichlorobutadiene " 

1,4-Dichlorobutene 

*Dichlorodifluoromethane ■ 

*1, 2-Dichloroethane  (Ethylene  dichloride) 

*Dichloromethane  (Methylene  chloride) 

Dichloropentanes,  mixed  isomers 

*1, 2-Dichloropropane  (Propylene  dichloride) 

2,3-Dichloropropane 

*Dichlorotetrafluoroethane 

1, 1-Dif  luoroethane 

Difluorotetrachloroethane 

Diiodomethane  (Methylene  iodide) 

Hexachloroethane 

Hexafluoro-2-propane 

Hexafluoropropylene,   monomer—'- 

Hexamethylene  dibronn.de " 

Iodoethane  (Ethyl  iodide),    tech 

Iodoform  (Triiodomethane) 

*Iodomethane  (Methyl  iodide) 

1-Iodoperfluorohexane 

*Lauryl  chlorides ""' 

Octafluorocyclobutane """""" 

1, 1,2,2-Tetrabromoethane  (Acetylene  tetrabromide) — 

Tetrabromomethane "  "" 

1,1,2,2-Tetrachloroethane  (Acetylene  tetrachloride) - 

*Tetrachloroethylene  (Perchloroethylene) 

Tetrafluoroethylene,  monomer 

Tetrafluoroethylene,  polymer 

Tetrafluoromethane 

Xt  i,  l-Trichloroethane  (Methyl  chloroform) 

l' 1, 2-Trichloroethane  (Vinyl  trichloride) 

*Trichloroethylene "     ""' 

*Trichlorofluoromethane 

1,2,3-Trichloropropane 

1, 2, 3-Triehloropropene 

Trichlorotrif  luoroethane 

*Vinyl  chloride,  monomer  ( Chloroethylene) 


Vinyl  fluoride "~   T" 

Vinylidene  chloride,  monomer  ( 1, 1-Dichloroethylene)  - 


VInylidene  fluoride- 
All  other- 

2-Heptanone  (Methyl  amyl  ketone) 

Hexadecane 

n-Hexadecenyl  succinic  anhydride 

n-Hexadecyl  disulfide 

Hexadecyl  nitrile 

Hexamethylenediammonium  adipate 

1,6-Hexanediol 

Hexanediol  bischloroformate 

2, 5-Hexanedione  ( Acetonylacetone) 

1, 2, 6-Hexanetriol 

1,2,6-Hexanetriol  octoate 

Hexanoic  acid  (Caproic  acid) 

2-[ 2- ( Hexyloxy)  ethoxy] ethanol 

Hydracrylonitrile  (Ethylene  cyanohydrin) - 

Hydrazine  and  salts 

2-Hydrazinoethanol 

Hydroxyethyl  carbamate 

Hydroxyethyl  methacrylate 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


DOW. 

DOW,  SHC. 

ACG,  MMM. 

HK,  MM. 

ACG,  DUP,  PAS. 

DOW. 

DOW. 

DOW,  ETD,  HCH,  MCH. 

DOW. 

DUP. 

DUP. 

DUP. 

ACG  DUP,  KAI,  PAS,  UCC. 

m^,    DA,  DOW,  DUP,  JCC,  MON,  OMC,  PPG,  TNA,  UCC,  WYN. 

ACS,  DA,  DOW,  DUP,  FRO,  SF. 

PAS. 

DOW,  JCC,  UCC. 

DOW,  UCC,  WYN. 

ACG,  DUP,  PAS,  UCC. 

ACG,  DUP. 

DUP. 

NTB,  SDW. 

NES. 

DUP. 

DUP. 

CLB. 

EK,  FMT. 

NTB. 

CLB,  EK,  FMT,  RSA. 

x. 

BC,  HK,  SDH. 

DUP. 

DOW. 

DOW. 

DUP,  PPG. 

DA,  DOW,  DUP,  FRO)  HK,  PPG,  SF,  TTX. 

DUP. 

DUP. 

DUP. 

DOW,  PPG,  TNA. 

DOW,  UCC. 

DOW,  DUP,  HK,  PPG,  TTX. 

ACG,  DUP,  KAI,  PAS,  UCC. 

DOW,  SHC. 

DOW. 

ACS^  AME^  BFG'  CUCJ  DA,  DOW,  GNT,  GYR,  MNO,  MON,  TNA, 

UCC. 
x. 

DOW,  TMC,  TNA. 
x. 

DUP,  EK,  KPS,  KPT. 
UCC. 
HMY. 
HMY. 
PAS. 
FOR. 

CEL,  MON. 
CEL. 
PPG. 

ACI,  RBC. 
UCC. 
ARC. 
FB. 
UCC. 
UCC. 

FMT,  OMC. 
NOR. 
JCC. 
AAC,  JCC. 


MISCELLANEOUS  CHEMICALS 


183 


TABLE  21B.— Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer ,  1 965-  -Continued 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

2-(  Hydroxymethyl) -2-methyl-l, 3-propanediol  ( Trimethylol 

ethane) . 
2-( Hydroxymethyl)  -2-nitro-l,  3-propanediol  ( Tris(  hydroxy- 
methyl) nitromethane) . 
N-( Hydroxymethyl) octadecanamide  ( N-Hydroxyroethylsteara- 
mide) . 

*4-Hydroxy-4-methyl-2-pentanone  (Diaoetone  alcohol) 

Hydroxyneopentyl  hydroxypivalate 

Hydroxypropyl  methacrylate 

Iodoaoetio  acid,  sodium  salt 

Iodomethylmercury  iodide 

Isethionic  acid  (2-Hydroxyethanesulfonic  acid) 

Isoascorbic  acid 

*Isoascorbic  acid,  sodium  salt 

Isobutoxyethanol 

l-Isobutoxy-2-propanol  (Propylene  glycol  isobutyl  ether) - 

Isobutyl  acrylate 

Isobutyl  isobutyrate 

Isobutyraldehyde 

Isobutyric  acid  and  anhydride 

Isobutyronitrile 

Isodecaldehyde,  mixed  isomers 

Isodecanoic  acid,  mixed  isomers 

Isodecyl  acrylate • 

Iso-octanoic  acid 

Isopentyl  ether  (Isoamyl  ether) 

Isoprenylaluminum 

Isopropanolamines: 

l-Amino-2-propanol  ( Monoisopropanolamine) 

1,  l/-Iminodi-2-propanol  ( Diisopropanolamine) 

1, 1',  1"  -Nitrilotri-2-propanol  ( Triisopropanolamine) 

*Isopropyl  acetate 

2-Isopropylaminoethanol 

Isopropyl  chloroformate 

*Isopropyl  ether 

Isovaleric  anhydride 

Isovalerone  (Diisobutyl  ketone) 

Itaconic  acid  (Methylenesuecinic  acid) 

Lactic  acid,  K)0#: 

Edible 

Technical 

Lactic  acid  salts: 

Aluminum  lactate 

Aluminum  sodium  chlorohydroxylactate 

Aluminum  sodium  lactate 

Calcium  lactate 

Sodium  lactate 

Lactic  anhydride 

Lactide  (3,6-Dimethyl-2,5-p-dioxanedione) 

Lactonitrile 

Laurie  acid  salts 

Lauronitrile 

Lauroyl  bromide 

*Lauroyl  chloride 

*Lauroyl  peroxide 

Lauryl  lactate 

Levulinic  acid 

*Linoleic  acid  salts: 

*Calcium  linoleate 

»Cobalt  linoleate 

Copper  linoleate 

Iron  linoleate 

Lead  linoleate- 

Lead  manganese  linoleate 

Manganese  linoleate 


Manufacturers'  identification  codes 
( according  to  list  in  table  22) 


CEL,    SHC,    UCC. 

EKT. 

JCC. 

BSA. 

NTB. 

G. 

MRK,    PFZ. 

BAX,   MRK,    PFZ. 

UCC. 

DOW. 

DBC. 

EKX. 

EKX,    UCC. 

EKT,    UCC. 

ESX. 

UCC. 

UCC. 

UCC. 

UCC. 

GIV. 

TSA. 

DOW,    UCC. 

DOW,    UCC. 

DOW,    UCC. 

EKT,    ENJ,    HPC,    UCC. 

PAS. 

CTN,    PPG. 

ENJ,    SHC,    UCC. 

ICO. 

EKT,    UCC. 

PFZ. 

CLN,    DUP,    MON. 

CLN,   MON. 

TNC. 

REH. 

REH. 

SHF. 

PFN. 

FB. 

CLN. 

MON. 

BCN,    CCW,    SYP. 

FOR. 

DOW. 

CAD,    G,    ONX,    TBK,    THC,    UPR,    WTL 

AZT,    CAD,    UPR,    WTL. 

VND. 

CRZ. 

CCA,    LEF,    SHP,    SRR. 

HSH,    SHP,    SRR. 

WTC. 

HSH. 

SHP,    SRR. 

SDH,    SRR. 

SHP,    SRR. 

184 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  21B-— Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1965 — Continued 


MISCELLANEOUS  CHEMICALS,    ACYCLIC--Continued 

^Lubricating  oil  additives: 

Chloronaphtha  xanthate 

Chlorosulfurized  hydrocarbon 

Chlorosulfurized  lard  oil-- 

Chlorosulfurized  sperm  oil 

Oxidized  hydrocarbons 

*Phosphorodithioates  ( Dithiophosphates) : 

2-Pinene  phosphorodithioate 

Zinc  di(  butylhexyl)    phosphorodithioate 

Zinc  dihexyl  phosphorodithioate 

Zinc  diisopropylhexyl  phosphorodithioate 

Zinc  diisopropyl  phosphorodithioate 

All  other 

Sulfurized  butenes 

*Sulfurized  lard  oil 

Sulfurized  methyl  oleate 

*Sulfurized  sperm  oil 

All  other 

Magnesium  methylate 

Maleic  acid 

Maleic  acid,  tribasic  lead  salt 

*Maleic  anhydride 

Malic  acid 

Malonic  acid 

Malonic  acid  salts 

Malononitrile 

Maltol  (Hydroxy  methyl  pyrone) 

Mannitol 

*Mercaptoacetic  acid  ( Thioglycolic  acid) 

*Mercaptoacetie  acid  (Thioglycolic  acid)  derivatives: 
*2-Aminoethyl  mercaptoacetate  (Monoethanolamine  thio- 
glycolate) . 

*.jr-jonium  mercaptoacetate  (Ammonium  thioglycolate) 

Antimony  mercaptoacetate 

Calcium  mercaptoacetate 

Dibutyltin  bis(  iso-octylmercaptoacetate) 

Dibutyltin  mercaptoacetate 

*Iso-octyl  mercaptoacetate 

Potassium  mercaptoacetate 

Sodium  mercaptoacetate 

3-Mercapto-l,  2-propanediol  ( Thioglycerol) 

|3-Mercaptopropionic  acid 

Mercaptosuccinic  acid  (Thiomalic  acid) 

Metal  soaps  of  oxidized  hydrocarbons 

Methacrylamide 

Methacrylate  copolymers 

Methacrylate  monomers,  above  methyl 

Methacrylic  acid ; 

Methacrylic  acid  esters,  other 

MethalLylidene  diacetate 

Methanesulfanol 

Methanesulfonic  acid 

*2-Methoxyethanol  ( Ethylene  glycol  monomethyl  ether) 

*2-(2-Methoxyethoxy)ethanol  (Diethylene  glycol  monomethyl 

ether) . 
*2-[2-(2-Methoxyethoxy)ethoxy]ethanol  (Triethylene  glycol 
monomethyl  ether) . 
2-(2-Methoxyethoxy)ethyl  2-methoxyethyl  ether  (Triethylene 
glycol  dimethyl  ether) . 

2-Methoxyethyl  acetate 

4-Methoxy-4-methyl-2-pentanol 

4-Methoxy-4-methyl-2-pentanone 

Methoxypolyethylene  glycol 

l-Methoxy-2-propanol 

3-Methoxypropanol 

3-(3-Methoxypropoxy)propanol  (Dipropylene  glycol  methyl 

ether) . 
3-[3-(3-Methoxypropoxy)propoxy]  propanol  (Tripropylene 

glycol  methyl  ether) . 
3-Methoxypropylamine 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


MON. 
EN  J. 
CCW. 

ccw. 

ALX. 

TX. 

0R0. 

MON. 

TX. 

SIN. 

ENJ, 

LUB. 

CCW, 

SIN. 

CCW, 

CCW, 

MKT, 

NAC, 

NTL. 

HN, 

EX, 

KF. 


LUB,  MON,  SIN. 

GOC,  NLC,  SIN. 

LUB,  QCP,  SIN,  SOI,  x. 

ENJ,  HK,  LUB,  MON,  0R0,  SIN,  SOI,  x. 

SFA. 

PFN. 

KPS,  MON,  NAC,  PCC,  PTT,  RCI. 
NAC,  PFN. 


EK,    GIV. 

KF. 

APD. 

EVN, 

HAB, 

RET. 

EVN, 

HAB, 

RET. 

EVN, 

HAB, 

RET, 

TNI. 

CCA. 

EVN. 

X. 

CCA. 

CCW, 

EVN, 

HAB. 

EVN. 

EVN. 

EVN. 

EVN. 

EVN. 

ALX. 

RH, 

X. 

X. 

DUP. 

DUP, 

RH. 

SAR. 

UCC. 

PAS. 

PAS. 

DOW, 

JCC, 

OMC, 

UCC. 

DOW, 

JCC, 

OMC, 

UCC. 

DOW, 

CMC, 

UCC. 

ASL. 

UCC. 

SHC. 

SHC. 

UCC. 

DOW, 

SHC. 

UCC. 

DOW, 

UCC. 

EXT,  JCC. 


MISCELLANEOUS  CHEMICALS 


185 


TABLE  21B.- -Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported   identified  by 

manufacturer,  1 965-  -Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,   ACYCLIC— Continued 

Methoxytriethyleneglycol  acetate 

*Methyl  acetate 

Methyl  acetoacetate 

Methyl  acrylate,   monomer 

Methylal  ( Dimethoxymethane) 

Methylaluminum  sesquichloride 

2-Methylaminoethanol  ( N-Methylethanolamine) 

Methyl  borate 

3-Methyl-2-butenoic  acid 

2-Methyl-l-buten-3-yne  ( Isopropenylacetylene) 

Methyl  butynoxyethanol 

Methyl  carbamate 

Methyl  chloroformate 

Methyl  cyanoacetate 

Methyl  2-cyanoacrylate 

Methyl  dichloroacetate 

Methyl  disulfide  (Dimethyl  disulfide) 

N, N'-Methylenebisacrylamide 

N,N '-Methylenebisoctadecanand.de ■ 

*Metnyl  ether  (Dimethyl  ether) 

Methyl  formate 

N-Methylglucamine 

Methylglycerol 

5-Methyl-2-hexanone  (Methyl  isoamyl  ketone) 

2,2'-(Methylimino)diethanol  (Methyl  diethanolamine) - 

Methyl  isocyanate 

2-Methyllactie  acid  (a-Hydroxyisobutyric  acid) 

2-Methyllactonitrile  (Acetone  cyanohydrin) 

Methylmagnesium  bromide 

Methylmagnesium  chloride 

Methyl  methacrylate,  monomer 

2-Methyl-2-nitro-l,3-propanediol 

2-Methyl-2-nitro-l-propanol 

2-Methyl-2,4-pentanediol  (Hexylene  glycol) 

*4-Methyl-2-pentanone  (Methyl  isobutyl  ketone) 

4-Methyl-2-pentanone  oxime  ( Methylisobutyl  ketoxime) 

4-Methyl-3-penten-2-one  (Mesityl  oxide) 

4-Methyl-2-pentyl  acetate 

Methylpolyethanolamine 

2-Methyl-2-propyl- 1, 3-propanediol 

Methylpseudoionone 

Methyl  sulfate  (Dimethyl  sulfate) 

Methyl  sulfide  (Dimethyl  sulfide) 

Methyl  sulfone 

Methyl  sulfoxide  (Dimethyl  sulfoxide) 

N-Methyltaurine 

N-Methyltaurine,  sodium  salt 

N-Methylurea 

2-Methylvaleraldehyde  ( 2-Methylpentaldehyde) 

2-Methylvaleric  acid 

Methyl  vinyl  acetate 

Methyl  vinyl  ether 

Mucochloric  acid  (2,3-Diehloro-3-formylacrylie  acid) 

Myrcene  (7-Methyl-3-methylene-l,  6-octadiene) 

Myristoyl  chloride 

Myristyl  lactate 

2-Nitro-l-butanol 

Nitroethane 

Nitromethane 

1-Nitropropane 

2-Nitropropane 

1, 9-Nonanediol 

Nonanoic  acid  (Pelargonic  acid) 

Nonanoic  acids,  cobalt  salts 

Nonenylsuceinic  anhydride 

Nylon,  heteropolyamide  polymer 

*Nylon,  6  and  6/6  polymer  for  fiber 

Nylon,  sebacamide  polymer 

1-Octadecene 


RBC. 

BOH,  EK,  MON,  UCC. 

EKT,  UCC. 

CEL,  DBC,  RH. 

CEL. 

TNA. 

UCC. 

MHI,  SFA. 

UCC. 

CUC. 

cue. 

BKL,  MP. 

CTN. 

KF. 

EKT. 

KF,  PD. 

CRZ. 

ACY. 

ARC. 

COM,  DUP,  UCC. 

DUP. 

DUP. 

APD. 

EKT,  UCC. 

UCC. 

CTN,  OTC. 

EK. 

ACY,  x,  x. 

ARA. 

ARA,  x. 

ACY,  DUP,  RH. 

COM. 

COM. 

CEL,  EKT,  SHC,  UCC. 

EKT,  ENJ,  SHC,  UCC. 

ALB. 

SHC. 

PUB,  SHC,  UCC. 

G. 

ABB,  DUP,  ICO. 

GIV. 

DUP. 

CRZ,  PAS. 

CRZ. 

CRZ. 

G. 

TNA. 

LIL. 

UCC. 

UCC. 

UCC. 

G,  UCC. 

EKT. 

IFF. 

BC. 

VND. 

COM. 

COM. 

COM. 

COM. 

COM. 

ADM. 

EMR. 

MID. 

HMY. 

DUP. 

DUP,  MON,  NAC. 

DUP. 

HMY. 


186 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  21B. — Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1 965-  -Continued 


Manufacturers'  identification  code 
( according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,  AC YCLIC-- Continued 

Octadecyl  isocyanate 

n-Octadecyl  mereaptan 

Octadecyl  mercaptopropionate 

1-Octanethiol  (n-Octyl  mereaptan) 

Octanoic  acid  (Caprylic  acid)  salts: 

Aluminum  octanoate 

Barium  octanoate 

Cadmium  octanoate 

Stannous  octanoate 

Zinc  octanoate 

2-0etanone  (Hexyl  methyl  ketone) 

3-0ctanone  (Amyl  ethyl  ketone) 

Octanoyl  chloride 

l-Octene 

l(and  2)-0ctene 

2-0ctene 

Octenylsuccinic  anhydride 

Octyltins 

Oleamide  (Oetadecene  amide) 

Oleamides,  mixed 

*01eie  acid  salts: 

Aluminum  oleate 

Ammonium  oleate - 

Barium  zinc  oleate 

*Copper  oleate 

Lead  oleate 

Stannous  oleate 

Oleonitrile 

Oleoyl  chloride 

Oleoylhydroxamic  acid 

Oleylpalmitamide 

*0xalic  acid 

*Oxalic  acid  salts: 

Ammonium  oxalate 

Calcium  oxalate 

Ferric  ammonium  oxalate 

Ferric  oxalate 

Ferric  sodium  oxalate 

Ferrous  oxalate 

Potassium  binoxalate 

Potassium  oxalate 

Sodium  binoxalate 

Sodium  oxalate 

Oxidized  hydrocarbon  mixtures,  other  than  lubricating  oil 
additives. 
*Palmitic  acid  salts: 

Aluminum  palmitate 

Zinc  palmitate 

*Pa1nritoyl  chloride 

Paraformaldehyde 

Paraldehyde  (Paracetaldehyde) 

*Pentaerythritol 

Pentaerythritol  caprylate 

Pentaerythritol  pelargonate 

*Pentaerythritol  tetranitrate 

2,  4-Pentanedione  ( Acetylacetone) 

2,4-Pentanedione,  metallic  complexes: 

Ferric 

Other 

2-Pentanone  (Methyl  propyl  ketone) 

3-Pentanone  (Diethyl  ketone) 

Pentyl  nitrate  (Amyl  nitrate) 

Peroxyacetic  acid 

^Phosgene  (Carbonyl  chloride) 

•^Phosphorus  acid  esters,  not  elsewhere  specified  (See  also 
Plasticizers,  Surface-active  agents,  Pesticides,  Flo- 
tation reagents,  and  Lubricating  oil  additives) : 

Bis(2-ethylhexyl)  hydrogen  phosphate- 

Bis(2-ethylhexyl)  hydrogen  phosphite 


CWN, 

ICO 

MOB. 

HMY. 

EVN. 

PAS. 

NOP. 

CCW. 

CCW. 

CCW. 

BKC. 

EKT, 

TBK, 

WTH. 

AHA. 

HK, 

UPR. 

ADM. 

WTH. 

mix. 

HMY. 

x. 

ADM, 

ARC, 

FIN,    HUM. 

FIN. 

WTC. 

BCN, 

MCI. 

WTC. 

MLD, 

SHP, 

WTC. 

SHP. 

CCW, 

X. 

ARC, 

FOR. 

DEP, 

G,    TBK. 

WAY. 

FIN. 

ACG, 

MAL, 

PFZ,    SF. 

ACG, 

BKC, 

PFZ. 

SF. 

PFZ. 

PFZ. 

PFZ. 

BKL. 

BKC. 

ACG, 

BKC, 

PFZ. 

SF. 

ACG, 

BKC, 

MAL,    SF. 

ALX. 

ACY, 

NOP, 

WTC. 

ACY, 

NOP, 

WTC. 

G,    HAL,    OPC,    THK. 

CEL, 

HN, 

3PC. 

UCC. 

CEL, 

COM, 

DCI,    HN,    HPC,    RCI,    TRJ. 

DEW. 

DRW. 

DUP, 

HPC, 

TRJ. 

UCC. 

MAK. 

MAK. 

UCC. 

DUP, 

HEX. 

TNA. 

FMB. 

CTN, 

DUP, 

MOB,    NAC,    CMC,    OTC,   PPG,    UCC, 

UPJ,   VDM. 

MISCELLANEOUS  CHEMICALS 


187 


TABLE  21B. --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1 965-  -Continued 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

^Phosphorus  acid  esters,  not  elsewhere  specified  (See  also 
Plastieizers,  Surface-active  agents,  Pesticides,  Flo- 
tation reagents,  and  Lubricating  oil  additives)  — 
Continued 

Butyl  phosphates  (mono-  and  di-) 

Chloropropyl  phosphorothioate 

Dibutyl  butylphosphonate 

Dibutyl  hydrogen  phosphite 

Didodecyl  hydrogen  phosphate 

Diethyl  ethylphosphonate 

Diethyl  hydrogen  phosphite 

Diisopropyl  hydrogen  phosphite 

Dimethyl  hydrogen  phosphite 

Dimethyl  methylphosphonate 

Dioctyl  hydrogen  phosphate 

Dioctyl  hydrogen  phosphite 

Dipentaerythritol  phosphite 

.  2-Ethylhexyl  phosphates  (mono-  and  di-) 

Ethyl  phosphates  (mono-  and  di-) 

Iso-octyl  hydrogen  phosphate 

Isopentyl  octyl  hydrogen  phosphate 

Methyl  dihydrogen  phosphate 

Methyl  phosphates  (mono-  and  di-) 

Pentyl  phosphates  (Mono-  and  diamyl  phosphates) 

*Tributyl  phosphate 

Tributyl  phosphite 

Tridecyl  phosphite 

Triethyl  phosphite 

Triiso-octyl  phosphite 

Triisopropyl  phosphite 

Trimethyl  phosphate 

Trimethyl  phosphite 

Tris(2-chloroethyl)  phosphite 

Tris(2,3-dibromopropyl)  phosphate 

Tris(2-ethylhexyl)  phosphite 

Tris( octadecyl)  phosphite 

All  other 

Pine  oil,  synthetic 

Polyaerylamide 

Polyacrylic  acid 

*Polyacrylic  acid  salts: 

Ammonium  polyacrylate 

Sodium  polyacrylate 

All  other 

Polyacrylonitrile 

Polybutylene  glycol 

Polychlorinated  propyl  ether 

Polyethoxyethylglycerol 

Polyethoxyethylsorbitol 

■^Polyethylene  glycol 

Polyethylene  glycol  dimethacrylate 

Polyethylene  imine 

Polyethylene  polysulfide 

Polyglycerol "     "_ 

Polyglycols,  ethylene  glycol  and  glycol  ethers,  mixtures- 

Polymethacrylic  acid  esters 

*Polypropoxy  ethers: 

*Glycerol  tri(  polyoxypropylene)  ether 

Polypropoxysorbitol 

Other 

^Polypropylene  glycol 

Polytetramethylene  glycol  ether 

Propanone  peroxide  (Acetone  peroxide) 

|3-Propiolactone 

Propionaldehyde 

^Propionic  acid 

Propionic  acid  salts: 

*Calcium  propionate 

*Sodium  propionate 

Zinc  propionate 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


SF,  SM. 

TNA. 

SM. 

SM. 

DUP. 

SM. 

SM. 

SM. 

SM. 

SM. 

DUP,  SF. 

HK. 

HK. 

SF. 

SF,  SM. 

SM. 

SM. 

HK. 

SF,  SM. 

SF. 

COM,  FMP,  SF,  TXT. 

SM. 

HK. 

SM. 

SM. 

SM. 

TNA. 

SM. 

SM. 

MCH. 

HK. 

SM. 

DUP,  MON,  SF,  SM,  x. 

CBY. 

ACY. 

BFG,  NOP,  RH. 

BFG. 

ALC,  BFG,  JOR,  RH. 

BFG. 

DUP. 

NIC. 

JCC. 

GLY. 

APD,  GLY,  TCH. 

ACN,  DOW,  DUP,  G,  JCC,  CMC,  UCC,  WYN. 

SAR. 

cm. 

BFG. 
DRW. 
DOW. 
DUP. 

JCC,  OMC,  UCC,  WYN. 

APD. 

ACS,  APD,  WYN. 

DOW,  JCC,  NLC,  OMC,  UCC,  WYN. 

x. 

SDH. 

CEL. 

EKX,  UCC. 

CEL,  COM,  EKT,  UCC. 

CEL,  HFT,  PFZ,  UCC,  WSN. 
CEL,  PFZ,  UCC,  WSN. 
BKC. 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  21B.—  Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer ,  1 965— Continued 


MISCELLANEOUS  CHMICALS,    ACYCLIC— Continued 


Propionic  anhydride 

Propionyl  chloride 

Propionyl  peroxide 

Propyl  acetate 

Propylene  carbonate 

^Propylene  glycol  ( 1,2-Propanediol) 

Propylene  glycol,   mixed  ethers 

^Propylene  oxide 

n-Propyl  isocyanate 

Propyl  nitrate 

Propyne  (Methylacetylene) 

Pseudoionone 

Pyruvaldehyde 

Quaternary  ammonium  compounds  (butyl  and  lower) 

Rare  sugars 

Ricinolamide 

Ricinoleic  acid  salts: 

Calcium  ricinoleate 

Lithium  ricinoleate 

*Sarcosine  ( N-Methylaminoacetic  acid) 

*Sarcosine,  sodium  salt 

Sebacic  acid 

Semicarbazide  base  and  hydrochloride 

^Sequestering  agents: 

(Diethylenetrinitrilo)pentaacetic  acid 

(Diethylenetrinitrilo)pentaacetic  acid,  monosodium 
hydrogen  ferric  salt. 

*(Diethylenetrinitrilo)pentaaeetie  acid,  sodium  salt 

N, N-Dihydroxyethylglycine,  sodium  salt 

*(  Ethylenedinitrilo)  tetraacetic  acid  ( Ethylenediamine- 
tetraacetic  acid) . 

( Ethylenedinitrilo) tetraacetic  acid,  diammonium  salt 

( Ethylenedinitrilo)  tetraacetic  acid,  dipotassium  salt 

( Ethylenedinitrilo)  tetraacetic  acid,  disodium  salt 

(  Ethylenedinitrilo) tetraacetic  acid,  disodium  calcium 

salt. 
(  Ethylenedinitrilo)  tetraacetic  acid,  disodium  copper 

salt. 
( Ethylenedinitrilo)  tetraacetic  acid,  disodium  zinc  salt, 
diiydrate. 

(  Ethylenedinitrilo) tetraacetic  acid,  manganese  salt 

*(  Ethylenedinitrilo) tetraacetic  acid,  monohydrogen  tri- 
sodium  salt. 
(  Ethylenedinitrilo) tetraacetic  acid,  monosodium  iron 

salt. 
(  Ethylenedinitrilo) tetraacetic  acid,  tetrapotassium  salt 

*( Ethylenedinitrilo) tetraacetic  acid,  tetrasodium  salt 

Hexahydroxyheptanoic  acid,  s6dium  salt 

(N-Hydroxyethylethylenedinitrilo)triacetic  acid 

(N-Hydroxyethylethylenedinitrilo) triacetic  acid,  iron 
sodium  salt. 
*(N-Hydroxyethylethylenedinitrilo) triacetic  acid,  tri- 
sodium  salt. 
( N-Hydroxyethylethylenedinitrilo) triacetic  acid,  other 
salts. 

Nitrilotriacetic  acid,  trisodium  salt 

Sodium  salt  of  sugar  acids 

Silicones 

Sodium  ethoxide 

Sodium  ethyl  oxalacetate * 

Sodium  formaldehydebisulfite 

*Sodium  formaldehydesulfoxylate 

*Sodium  methoxide  (Sodium  methylate) 

Sodium  polypectate 

Sodium  sorbitol  borate 

Sorbic  acid  (2,4-Hexadienoic  acid),  and  potassium  and 
sodium  salts. 

^Sorbitol 

Soya  nitrile 

*Stearamide  ( Octadecanamide) 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


CEL, 
ABB, 
WTL. 
CEL, 
DOW, 
APD, 
DOW. 
CEL, 
CWN, 
TNA. 

cue. 

GIV. 
UCC. 
EDC, 
PFN. 
TKL. 

BAC. 
BAC. 
ATL, 
GGY. 

WTH, 
FMT. 

HMP. 
GGY. 

CWL, 
CWL, 

DOW, 

DOW. 
EK. 
DOW, 
DOW, 

GGY. 


GGY. 
GGY, 

GGY, 

GGY. 
CRT, 
PCW. 
GGY. 
DOW. 


EKT,  UCC. 
EK,  TBK. 

EKT,  PUB,  UCC. 

JCC. 

CEL,  DOW,  DUP,  JCC,  OMC,  UCC,  WYN. 

DOW,  JCC,  OMC,  UCC,  WYN. 
OTC. 


EK,  PAS,  RSA. 


G,  HMP,  VPC. 


DOW,  GGY,  HMP,  RPC,  TCC. 
DOW,  HMP,  MOA. 
GGY,  HMP,  MOA. 


EK,  GGY,  HMP,  RPC. 
GGY. 


HMP,  NOP. 
HMP,  RPC. 

CWL,  DOW,  GGY,  HMP,  HRT,  IBI,  RPC,  TCC. 


CRT,  CWL,  DOW,  HMP,  IBI,  MOA,  RPC,  TCC. 


HMP. 


GGY,    HMP. 

PFN. 

DCC,    ORO,    UCS. 

FMP. 

FMP. 

EK,    IDC. 

HSH,    NOP,    RH,    ROY. 

BFR,    DA,    DUP,    HSH,    KF,    OMC, 

RBC, 

SFA. 

SKG. 

APD. 

UCC. 

APD,    BRD,  MRK,    PFZ. 

CGI. 

ADM,    ARC,    DUP,    FIN,    HUM. 

MISCELLANEOUS  CHEMICALS 


189 


TABLE  21B. —Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  1 965-  -Continued 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 

♦Stearic  acid  salts: 
♦Aluminum  stearates: 

♦Aluminum  distearate 

♦Aluminum  monostearate 

♦Aluminum  tristearate 

Ammonium  stearate 

Barium  stearate 

Cadmium  stearate 

♦Calcium  stearate 

Cobalt  stearate 

Copper  stearate 

Ferric  and  ferrous  stearates 

♦Lead  stearate 

Lead  stearate,  dibasic 

♦Lithium  stearate 

♦Magnesium  stearate 

Ma  nganese  stearate 

Nickel  stearate 

♦Zinc  stearate 

All  other 

Stearonitrile  (Octadecanenitrile) 

Stearoyl  chloride 

Stearyl-2- lactic  acid 

Succinic  acid 

Succinic  anhydride 

Succinimide 

Succinonitrile 

Succinyl  peroxide 

Sucrose  octaacetate 

♦Tallow  umide,  hydrogenated 

Tallow  fatty  acyl  chloride 

Tallow  litrile 

Tallow  nitrile,  hydrogenated 

Tartaric  acid  salts: 

Antimony  potassium  tartrate 

Potassium  bitartrate 

Potassium  sodium  tartrate 

Sodium  bitartrate 

All  other 

Tetrabutyltin 

Tetrabutyl  titanate 

n-Tetradecane 

1, 1,3,3-Tetraethoxypropane 

Tetraethylene  glycol 

Tetraethylene  glycol  dimethacrylate 

♦Tetraethyllead 

Tetrahydropseudoionone 

Tetrahydroxysuccinic  acid  ( Dioxytartaric  acid) 

Tetrakis( hydroxymethyl)  phosphonium  chloride 

N,  N,  N', N'-Tetrakis(  2-hydroxypropyl) ethylenediamine- 

1, 1,3,3-Tetramethoxypropane- 

♦Tetramethyl(  and  ethyl)  lead 

Tetramethylguanidine 

♦Tetramethyllead 

Tetramethylurea 

Tetraoctyl  orthosilicate 

Tetrapropenylsuccinic  acid 

Thioacetamide 

Thioacetic  acid 

2,2'-Thiodiethanol  ( Thiodiethylene  glycol) 

3,3'-Thiodipropionates,  other 

3,3'-Thiodipropionic  acid 

Thiodipropionic  acid,  cobalt  salt 

3,3'-Thiodipropionitrile 

Thiolactic  acid 

Thiosemicarbazide 

Titanic  acid  esters 

Tributylphosphine 


ACY,  JTC,  LEF,  MAL,  NOC,  NOP,  PHP,  SYP,  WTC. 

LEF,  MAL,  NOC,  NOP,  SYP,  WTC. 

ACY,  LEF,  MAL,  NOC,  NOP,  PBP,  SYP. 

LEF,  NOP,  WTC. 

LEF,  NOC,  NOP,  PHP,  SYP,  WTC. 

NOP,  PHP,  SYP,  WTC. 

ACY,  HNX,  JTC,  LEF,  MAL,  NOC,  NOP,  PHP,  SYP,  WTC. 

WTC. 

NOC. 

MCI,  WTC. 

HSH,  LEF,  NOP,  NTL,  PRP,  WTC. 

NOC,  NOP,  NTL. 

FTE,  LEF,  NOP,  PRP,  SYP,  WTC. 

ACY,  JTC,  LEF,  MAL,  NOC,  NOP,  PRP,  SYP,  WTC. 

NOC. 

WTC. 

ACY,  BCN,  CCA,  HNX,  JTC,  LEF,  MAL,  NOC,  NOP,  PRP,  SYP, 

TNC,  WTC. 
APD. 
FOR. 
G,  TBK. 


RKC,    NAC. 

NAC. 

NAC. 

NAC,    RSA. 

WTL. 

PD,    UCC. 

ADM,    ARC, 

CGL,    CRT,    HUM. 

G. 

FOR. 

FOR. 

PF2. 

ATC. 

PFZ. 

PFZ. 

BKC. 

X. 

DUP. 

HMY. 

KF. 

DOW,    UCC. 

SAR. 

DUP,    HCH, 

TNA. 

GIV. 

ACY. 

HK. 

WYN. 

KF. 

DUP,    TNA. 

ACY. 

DUP,    HCH, 

NLC,    TNA. 

OTC. 

MON. 

X. 

BKC,    EK. 

EVN. 

UCC. 

ttAB. 

CCW,    EVN. 

CCW. 

ACY,    HAB. 

EVN. 

ACY,    FMT. 

DUP. 

CCW. 

190 


SYNTHETIC  ORGANIC  CHEMICALS,  1965 


TABLE  21B.- 


-  Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1965 — Continued 


Manufacturers'    identification  codes 
( according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,   ACYCLIC--Continued 

Tributyltin  chloride 

Trichloroacetic  acid 

Trichloroacetyl  chloride 

(Trichloromethyl)phosphonic  acid 

Trichloropropylsilane 

Trichlorovinylsilane 

Tridecyl  mercaptan 

Triethylaluminum 

*Triethylene  glycol 

Triethylene  glycol  dimethacrylate 

Triethyl  orthoacetate 

Triethyl  orthofonnate 

Triethyl  orthopropionate 

Trifluoroaeetic  anhydride 

Tri(hexylene  glycol)  biborate 

Triisobutylaluminum 

Triisodecyl  orthofonnate » 

Trimethoxyboroxine 

T rime thy laluminum 

2, 6, 8-Trimethyl-4-nonanone 

Trimethyl  orthoformate 

2,2,4-Trimethyl-l,3-pentanediol 

2,2,4-Trimethyl-l,3-pentanediol  monoisobutyrate 

Tri-n-octyl  phosphine  oxide 

Tri-n-propy  laluminum 

Tripropylene  glycol 

*Urea  in  compounds  or  mixtures,  100$  basis: 

*In  feed  compounds 

*In  liquid  fertilizer 

*In  solid  fertilizer 

In  plastics 

All  other 

Urea  peroxide 

Urea  urethane  copolymer 

Valeraldehyde 

Valeric  acid 

*Vinyl  acetate,  monomer 

*Zine  formaldenydesulfoxylate 


DOW. 

EK. 

DCC. 

DCC. 

DCC. 

PAS. 

TNA, 

ACN, 

SAH. 

EK, 

KF. 

KF. 

EK. 

USB. 

TNA, 

KF. 

SFA. 

TNA. 

UCC. 

KF. 

EKX. 

EKX. 

EK. 

TNA, 

DOW, 


CAU,  DOW,  G,  HCH,  JCC,  OMC,  UCC. 
KF. 


TSA. 
UCC. 


ACN,  DUP,  GCC,  JDC,  MON,  MSC,  SHC,  SOH. 

ACN,  CFA,  DUP,  ESC,  FCA,  GCC,  HKY,  HPC,  KET,  MON, 

NIT,  SHC,  SNI,  SOH,  SPN,  x. 

ACN,  DUP,  GCC,  HPC,  JDC,  MON,  MSC,  SHC,  SNO,  SOH, 

DUP,  MON. 

ACN,  DUP,  HPC,  MON,  SNO,  SOH. 
FMB. 
DUP. 
UCC. 
UCC. 

BOR,  CEL,  CUC,  DUP,  MON,  NSC,  UCC. 

NOP,  RH,  ROY. 


MSC, 
SPN. 


DIRECTORY  OF  MANUFACTURERS 


Directory  of  Manufacturers 

The  Directory  of  Manufacturers  lists  the  companies  that  report  their  production  of  synthetic 
organic  chemicals  to  the  U.S.   Tariff  Commission.   The  name  of  each  manufacturer  is  preceded 
by  an  alphabetical  identification  symbol.   These  identification  symbols  consist  of  not  more  than 
three  capital  letters,   and  usually  bear  a  relation  to  the  company  name. 

For  1965,  the  Directory  of  Manufacturers  lists  approximately  800  primary  manufacturers 
(see  table  22).  Some  of  the  companies  that  report  production  of  synthetic  organic  chemicals  do 
not  sell  the  materials,   but  consume  their  entire  output  in  further  manufacturing. 

The  Directory  of  Manufacturers  lists  the  reporting  companies  in  two  ways:  Section  1  lists 
them  in  alphabetical  order  by  identification  symbols;  section  2  lists  the  reporting  companies  in 
alphabetical  order  by  company  name,  and  gives  the  corresponding  identification  symbol  and  the 
company  address.   Company  divisions  are  usually  listed  under  the  parent  company's  name. 

TABLE  22.-- Synthetic  organic  chemicals;  Directory  of  manufacturers ,  1965 

SECTION  1.      ALPHABETICAL  DIRECTORY  BY  CODE 
[Names  of  synthetic  organic  chemical  manufacturers  that  reported  production  or  sales  to  the  U.S.   Tariff  Commission 
for  1965   are  listed  below  in  the  order  of  their  identification  codes  as  used  in  tables  m  pt.    III.   Sec.   2  of  this 
table  lists  these  manufacturers  alphabetically  and  gives  their  office  addresses  J 


Name  of  company 


AAC 
AAE 
AAI 
AAP 
ABB 
ABS 

ACB 
ACC 
ACG 
ACI 
ACN 
ACO 
ACP 
ACR 
ACS 
ACT 
ACU 

ACY 
ADM 
AKS 
ALB 
ALC 
ALD 
ALF 
ALL 
ALO 
ALT 

ALX 
AMB 
AMC 
AME 
AML 
AMD 
AMP 
AMR 
AMS 

ANM 
APC 
APD 
APR 
APT 
APV 
APX 
ARA 
ARC 


Alcolac  Chemical  Corp. 

American  Aniline  &  Extract  Co.,    Inc. 

American  Alkyd  Industries 

American  Aniline  Products,    Inc. 

Abbott  Laboratories 

American  Brake  Shoe  Co.,    American  Brakeblok 

Div. 
Allied  Chemical  Corp.,    Barrett  Div. 
Amoco  Chemicals  Corp. 

Allied  Chemical  Corp.,    General  Chemical  Div. 
Aceto  Industrial  Chemical  Corp. 
Allied  Chemical  Corp.,   Nitrogen  Div. 
Acralite  Co.,    Inc. 

Allied  Chemical  Corp.,   Plastics  Div. 
Acme  Resin  Corp. 

Allied  Chemical  Corp.,    Solvay  Process  Div. 
Arthur  C.   Trask  Co. 
Allied  Chemical  Corp.,   Union  Texas  Petroleum 

Div. 
American  Cyanamid  Co. 
Archer-Daniels-Midland  Co. 
Arkansas  Co.,    Inc. 
Ames  Laboratories,    Inc. 
Alco  Chemical  Corp. 
Aldrich  Chemical  Co.,    Inc. 

Allied  Chemical  Corp.,    Fibers  Div. 

Alliance  Color  &  Chemical  Co. 

Alamo  Industries,    Inc. 

Crompton  &  Knowles  Corp.,   Althouse  Chemical  Co. 
Div. 

Alox  Corp. 

American  Bio-Synthetics  Corp. 

Amchem  Products,  Inc. 

American  Chemical  Corp. 

Amalgamated  Chemical  Corp. 

American  Oil  Co.  (Texas) 

American  Potash  Sc   Chemical  Corp. 

Pacific  Resins  &  Chemical  Co. 

Martin-Marietta  Corp. ,  Ridgway  Color  & 
Chemical  Div. 

Ancon  Chemical  Co. 

Appleton  Coated  Paper  Co. 

Atlas  Chemical  Industries,  Inc.,  Chemicals  Div, 

Atlas  Processing  Co. 

American  Petrochemical  Corp. 

Armstrong  Paint  &  Varnish  Works,  Inc. 

Apex  Chemical  Co.,  Inc. 

Syntex  Corp.,  Arapahoe  Chemicals  Div. 

Armour  Industrial  Chemical  Co. 


Name  of  company 


ARD 

ARG 

ARK 

ARL 

ARM 

ARN 

ARP 

ARZ 

ASH 

ASL 

AST 

ASY 

ATC 

ATL 

ATP 

ATR 

ATU 

AUG 

AV 

AVS 

AZT 

BAC 

BAL 

BAR 

BAT 

BAX 

BC 

BCM 

BCN 

BDO 

BEN 

BFG 

BFR 

BJL 

BKC 

BKL 

BKM 

BKS 

BKT 

BL 

BLA 

BLN 

BLS 

BME 

BOR 

BOY 

BPC 


Ardmore  Chemical  Co. 

Argus  Chemical  Corp. 

Armstrong  Cork  Co. 

Arol  Chemical  Products  Co. 

Armour  Agricultural  Chemical  Co. 

Arenol  Chemical  Corp. 

Armour  Pharmaceutical  Co. 

Arizona  Chemical  Co. 

Ashland  Oil  &  Refining  Co. 

Ansul  Chemical  Co. 

Astra  Pharmaceutical  Products,  Inc. 

American  Synthetic  Rubber  Corp. 

American  Tartars  Corp. 

Atlantic  Chemical  Corp. 

Atco  Chemical- Industrial  Products,  Inc. 

Atlantic  Refining  Co. 

Atlantic  Tubing  &   Rubber  Co. 

Augusta  Chemical  Co. 

FMC  Corp.,  American  Viscose  Div. 

Avisun  Corp. 

Aztec  Chemicals,  Inc. 

Baker  Castor  Oil  Co. 

Baltimore  Paint  &  Chemical  Corp. 

American  Rubber  &  Chemical  Co. 

Crompton  &  Knowles  Corp.,  Bates  Div. 

Baxter  Laboratories,  Inc. 

Barlow  Chemical  Corp. 

Belding  Chemical  Industries 

Lehn  &  Fink  Products  Corp.,  Beacon  Div. 

Benzenoid  Organics,  Inc. 

Bennett ' s 

B.  F.  Goodrich  Co.,  B.  F.  Goodrich  Chemical  Co.  Div. 

Branehflower  Co. 

Burdick  &  Jackson  Laboratories,  Inc. 

J.  T.  Baker  Chemical  Co. 

Millmaster  Onyx  Corp.,  Millmaster  Chemical  Div., 

Berkeley  Chemical  Dept. 
Buckman  Laboratories,  Inc. 

Tenneco  Chemicals,  Inc. ,  Berkshire  Color  Div. 
J.  T.  Baker  Chemical  Co.,  Taylor  Div. 
Belle  Chemical  Co.,  Inc. 
Winn-Dixie  Stores,  Inc. 
Brooklyn  Color  Works,  Inc. 
Beech-Nut  Life  Savers,  Inc. 
Bendix  Corp.,  Marshall- Eclipse  Div. 
Borden  Co.,  Borden  Chemical  Co.  Div. 
Walter  N.  Boysen  Co. 
Benzol  Products  Co. 


192  SYNTHETIC  ORGANIC  CHEMICALS,  1965 

TABLE  22..-- Synthetic  organic  chemicals.-  Directory  of  manufacturers ,  1965 — Continued 


Code 

Name  of  company 

Code 

Name  of  company 

BPL 

Brand  Plastics  Co. 

COR 

Commonwealth  Oil  Refining  Co.,  Inc. 

BRD 

Baird  Chemical  Industries,  Inc. 

CP 

Colgate-Palmolive  Co. 

BRS 

Bristol-Meyers  Co.,  Bristol  Laboratories  Div. 

CPC 

Childs  Pulp  Colors,  Inc. 

BRU 

M.  A.  Bruder  &  Sons,  Inc. 

CPD 

Chemical  Products  Corp. 

BRY 

Bryant  Chemical  Corp. 

CPV 

■  Cook  Paint  &  Varnish  Co. 

BSC 

Burkart-Schier  Chemical  Co. 

CPY 

Copolymer  Rubber  &  Chemical  Corp. 

BUC 

Blackman-Uhler  Chemical  Co. 

CRC 

Crown  Chemical  Corp. 

BUK 

Buckeye  Cellulose  Corp. 

CRN 

Corn  Products  Co. 

BUR 

Burroughs- Wellcome  &   Co.  (U.S.A.),  Inc. 

CRS 

Carus  Chemical  Co.,  Inc. 

BXT 

J.  H.  Baxter  &   Co. 

CRT 
CRY 

Crest  Chemical  Corp. 

Tenneco  Manufacturing  Co. ,  Tenneco  Plastics  Div. 

CAD 

Cadet  Chemical  Corp. 

CRZ 

Crown  Zellerbach  Corp.,  Chemical  Products  Div. 

CAL 

Callery  Chemical  Co. 

CSD 

Cosden  Oil  &  Chemical  Co. 

CAP 

Cap- Roc,  Inc.,  Capital  Plastics  Div. 

CSO 

Cities  Service  Oil  Co. 

CAT 

Catalin  Corp.  of  America 

CST 

Charles  S.  Tanner  Co. 

CAU 

Calcasieu  Chemical  Corp. 

CTA 

Conestoga  Chemical  Corp. 

CBA 

Ciba  Corp.,  Ciba  Products  Co. 

CTL 

Continental  Chemical  Co. 

CBC 

Georgia-Pacific  Corp.,  Coos  Bay  Div. 

CTN 

Chemetron  Corp.,  Chemetron  Chemicals,  Organic 

CBD 

Chembond  Corp. 

Chemical  Dept. 

CBM 

Carborundum  Co. ,  Coated  Abrasives  Div. 

cue 

Cumberland  Chemical  Corp.,  Subsidiary  of  Air 

CBN 

Columbian  Carbon  Co. 

Reduction  Co.,  Inc. 

CBP 

Ciba  Corp.,  Ciba  Pharmaceutical  Co.  Div. 

CUL 

Culver  Chemical  Co. 

CBR 

Colab  Resin  Corp. 

CUT 

Cutter  Laboratories,  Inc. 

CBT 

Samuel  Cabot,  Inc. 

CW 

General  Mills,  Inc.,  Chemical  Div. 

CBY 

Crosby  Chemicals,  Inc. 

CWL 

Cowles  Chemical  Co. 

CCA 

Carlisle  Chemical  Works,  Inc.,  Advance  Div. 

OWN 

Upjohn  Co.,  Carwin  Organic  Chemicals 

CCC 

Chase  Chemical  Corp. 

CWP 

Consolidated  Papers,  Inc. 

CCH 

Pearsall  Chemical  Co. 

CYC 

Cyclamate  Corp.  of  America 

• 

CCI 

Checkmate  Chemicals,  Inc. 

CCL 

Charlotte  Chemical  Laboratories 

DA 

Diamond  Alkali  Co.,  and  Western  Div. 

CCO 

Chemico,  Inc. 

DAN 

Dan  River  Mills,  Inc. 

CCP 

Crown  Central  Petroleum  Corp. 

DAV 

Conchemco,  Inc.,  H.  B.  Davis  Co.  Div. 

CCW 

Carlisle  Chemical  Works,  Inc. 

DBC 

Dow  Badische  Chemical  Co. 

CD 

Budd  Co.,  Polychem  Div. 

DCC 

Dow  Corning  Corp. 

CEL 

Celanese  Corp.  of  America: 

DCI 

Delaware  Chemicals,  Inc. 

Celanese  Chemical  Co.  Div. 

DEG 

Degen  Oil  &  Chemical  Co. 

Celanese  Coatings  Co. 

DEP 

DePaul  Chemical  Co.,  Inc. 

Celanese  Plastics  Co. 
Fibers  Co.  Div. 

DEX 
DIX 

Dexter  Chemical  Corp. 
Dixie  Chemical  Co. 

CEM 

Chemirad  Corp. 

DLH 

Hess  Oil  &  Chemical  Corp. 

CFA 

Cooperative  Farm  Chemicals  Association 

DLI 

Dawe's  Laboratories,  Inc. 

CFC 

Rexall  Chemical  Co.  -  Kearny 

DOD 

Donald  A.  Dodd 

CGL 

Cargill,  Inc. 

DOM 

Dominion  Products,  Inc. 

CHC 

Chipman  Chemical  Co. ,  Inc. 

DOW 

Dow  Chemical  Co. 

CHF 

Chemical  Formulators,  Inc. 

DPP 

Dixie  Pine  Products  Co.,  Inc. 

CHG 

Chemagro  Corp. 

DRL 

Caradco,  Inc.,  Durel  Div. 

CHL 

Chemol,  Inc. 

DRW 

Drew  Chemical  Corp. 

Dye  Specialties,  Inc. 

DeSoto  Chemical  Coatings,  Inc. 

CHO 
CHT 

Stauf fer  Chemical  Co. ,  Calhio  Chemicals  Div. 
Chattanooga  Medicine  Co. ,  Chattem  Chemicals 
Div. 

DSC 
DSO 

DUN 

Frank  W.  Dunne  Co. 

CIB 

Ciba  Chemical  &  Dye  Co. 

DUP 

E.  I.  duPont  de  Nemours  &  Co.,  Inc. 

CIK 

Tenneco  Chemicals,  Inc.,  Ca]/lnk  Div. 

DVC 

Dover  Chemical  Co. 

CIS 
CKL 

Chemical  Insecticide  Corp. 
Chemlek  Laboratories,  Inc. 

DXS 

Sunray  DX  Oil  Co. 

CLB 

Columbia  Organic  Chemicals  Co.,  Inc. 

CLC 

Charles  L.  Huisking  &   Co.,  Inc.,  Clintbrook 

EAK 

J.  S.  &  W.  R.  EaMns,  Inc. 

Chemical  Co.  Div. 

ECC 

Eastern  Color  &  Chemical  Co. 

CLD 

Colloids,  Inc. 

EDO 

Edcan  Laboratories 

CLI 

Clintwood  Chemical  Co. 

EFH 

E.  F.  Houghton  &  Co. 

CLK 

Clark  Oil  &  Refining  Corp. 

EK 

Eastman  Kodak  Co. 

CLN 

Standard  Brands,  Inc.,  Clinton  Corn  Processing 

EKT 

Eastman  Kodak  Co.,  Tennessee  Eastman  Co.  Div. 

Co.  Div. 

EKX 

Eastman  Kodak  Co.,  Texas  Eastman  Co.  Div. 

CLV 

Clover  Chemical  Co. 

ELP 

El  Paso  Natural  Gas  Products  Co. 

CLY 

W.  A.  Cleary  Corp. 

EMK 

Emkay  Chemical  Co. 

CM 

Carpenter-Morton  Co. 

EMR 

Emery  Industries,  Inc. 

CMG 

Nyanza,  Inc. 

EN 

Endo  Laboratories,  Inc. 

CMP 

Commercial  Products  Co.,  Inc. 

ENJ 

Enjay  Chemical  Co. 

CO 

Continental  Oil  Co. 

EPC 

Epoxylite  Corp. 

COK 

Cockerille  Chemicals,  Inc. 

ESC 

Escambia  Chemical  Corp. 

COL 

Collier  Carbon  &  Chemical  Corp. 

ETD 

Ethyl-Dow  Chemical  Co. 

COM 

Commercial  Solvents  Corp. 

EVN 

Evans  Chemetics,  Inc. 

CON 

Concord  Chemical  Co.,  Inc. 

EW 

Westinghouse  Electric  Corp.,  Insulating  Materials 

COP 

Coopers  Creek  Chemical  Corp. 

Div. 

DIRECTORY  OF  MANUFACTURERS 
TABLE  22, — Synthetic  organic  chemicals:   Directory  of  manufacturers ,  1965 — Continued 


193 


Code 

Name  of  company 

Code 

Name  of  company 

FAB 

Fabricolor  Manufacturing  Corp. 

GRV 

Guardsman  Chemical  Coatings,  Inc. 

FAR 

Fa  mow,  Inc. 

GRW 

Great  Western  Sugar  Co. 

FB 

Frltzsche  Bros.,  Inc. 

GTH 

Guth  Chemical  Co. 

FBF 

Fiberfil,  Inc. 

GTL 

Great  Lakes  Chemical  Corp. 

FBR 

Fibreboard  Paper  Products  Corp. 

GYR 

Goodyear  Tire  &  Rubber  Co. 

FC 

Franklin  Chemical  Co. 

FCA 

Farmers  Chemical  Association,  Inc. 

HAB 

Halby  Products  Co.,  Inc. 

FCD 

France,  Campbell  &  Darling,  Inc. 

HAL 

C.  P.  Hall  Co.  of  Illinois 

FCL 

Federal  Color  Laboratories,  Inc. 

HAM 

Hampden  Color  &  Chemical  Co. 

FEL 

Felton  Chemical  Co.,  Inc. 

HAN 

Hanna  Paint  Manufacturing  Co.,  Inc. 

FER 

Ferro  Corp.,  Ferro  Chemical  Div. 

HAP 

Applied  Plastics  Co.,  Inc. 

FG 

Foster  Grant  Co.,  Inc. 

HCH 

Houston  Chemical  Corp. 

FH 

Foster-Heaton  Co. 

HCO 

Hamilton  Chemical  Corp. 

FIN 

Fine  Organics,  Inc. 

HDG 

Hodag  Chemical  Corp. 

FIR 

Firestone  Tire  &  Rubber  Co.,  Firestone 

HER 

Heresite  &  Chemical  Corp. 

Plastics  Co.  Div. 

HET 

Heterochemical  Corp. 

FIS 

Fisher  Melamine  Corp. 

HEX 

Hexagon  Laboratories,  Inc. 

FLH 

H.  B.  Fuller  Co. 

HFT 

Hoffman-Taff,  Inc. 

FLM 

Fleming  Laboratories,  Inc. 

HK 

Hooker  Chemical  Corp. 

FLO 

Florasynth  Laboratories,  Inc. 

HKD 

Hooker  Chemical  Corp.,  Durez  Plastics  Div. 

FLW 

W.  P.  Fuller  Paint  Co. 

HKY 

Hawkeye  Chemical  Co. 

FMB 

FMC  Corp.,  Inorganic  Chemicals  Div. 

HLC 

Hartman-Leddon  Co. 

FMN 

FMC  Corp.,  Niagara  Chemical  Div. 

HLI 

Haag  Laboratories,  Inc. 

FMO 

Fermco  Laboratories,  Inc. 

HMP 

W.  R.  Grace  &  Co.,  Hampshire  Chemical  Div. 

FMP 

FMC  Corp.,  Organic  Chemicals  Div. 

HMY 

Humphrey  Chemical  Corp. 

FMT 

Fairmount  Chemical  Co.,  Inc. 

HN 

Tenneco  Chemicals,  Inc. 

FOC 

Farac  Oil  &  Chemical  Co. 

HNC 

H  &   N  Chemical  Co. 

POM 

Formica  Corp. 

HNW 

Tenneco  Chemicals,  Inc.,  Newport  Div. 

FOR 

Foremost  Chemical  Products  Co. 

HNX 

Tenneco  Chemicals,  Inc.,  Nuodex  Div. 

FRE 

Freeman  Chemical  Corp. 

HOF 

Hoffmann-LaRoche,  Inc. 

FRL 

Firestone  Tire  &  Rubber  Co.,  Firestone  Rubber 

HOU 

Air  Products  &  Chemicals,  Inc.,  Houdry  Process 

&  Latex  Products  Co.  Div. 

&   Chemical  Co.  Div. 

FRM 

Farmer's  Chemical  Co. 

HPC 

Hercules  Powder  Co . ,  Inc . 

FRO 

Vulcan  Materials  Co.,  Frontier  Chemical  Co. 

HRS 

Grow  Chemical  Corp.,  Harris  Paint  Co.  Div. 

Div. 

HRT 

Hart  Products  Corp. 

FRP 

Filtered  Rosin  Products  Co. 

HSC 

Holland-Suco  Color  Co. 

FRS 

Firestone  Tire  &  Rubber  Co.,  Firestone 

HSH 

Harshaw  Chemical  Co. 

Synthetic  Rubber  &  Latex  Co.  Div. 

HST 

American  Hoechst  Corp. 

FSH 

Frisch  &  Co. ,  Inc. 

HUM 

National  Dairy  Products  Corp.,  Humko  Products 

FTE 

Foote  Mineral  Co. 

Chemical  Div. 

HUS 

Husky-Dominion  Briquets 

G 

General  Aniline  &  Film  Corp. ,  Dyestuff  & 

HVG 

Haveg  Industries,  Inc.,  Resin  &   Compound  Div. 

Chemical  Div. 

HYC 

Hysol  Corp. 

GAM 

Gamma  Chemical  Corp. 

HYN 

Hynson,  Westcott  &  Dunning,  Inc. 

GAN 

Gane's  Chemical  Works,  Inc. 

GCC 

W.  R.  Grace  &  Co. ,  Nitrogen  Products  Div. 

IBI 

Industrial  Biochemicals 

GDN 

Lancaster  Chemical  Corp.,  Gordon  Chemicals 

ICC 

Interchemical  Corp.,  Color  &  Chemicals  Div. 

Co.  Div. 

ICF 

Interchemical  Corp.,  Finishes  Div. 

GE 

General  Electric  Co.,  Chemical  Materials  Dept. 

ICI 

I.C.I.  (Organics),  Inc. 

GEI 

General  Electric  Co.,  Insulating  Materials 

ICO 

Interchemical  Corp.,  Organic  Chemicals  Dept. 

Dept. 

IDC 

Industrial  Dyestuff  Co. 

GEO 

Geolina  Business,  Inc. 

IFF 

International  Flavors  &  Fragrances,  Inc. 

GFS 

G.  Frederick  Smith  Chemical  Co. 

ILC 

International  Latex  Corp. 

GGC 

Goodrich-Gulf  Chemicals,  Inc. 

IMC 

International  Minerals  &  Chemical  Corp. 

GGY 

Geigy  Chemical  Corp. 

IMP 

Hercules  Powder  Co.,  Inc.,  Imperial  Color  & 

GIL 

Gilman  Paint  &  Varnish  Co. 

Chemical  Dept. 

GIV 

Givaudan  Corp. 

LMR 

Imperial  Chemical  Co.,  Inc. 

GLC 

General  Latex  &   Chemical  Corp. 

INL 

Inland  Steel  Container  Co. 

GLD 

Glidden  Co.,  Durkee  Famous  Foods  Div. 

IOC 

Ritter-Pfaudler  Corp.,  Ionac  Chemical  Co.  Div. 

GLX 

Glasflex,  Inc. 

IPC 

Interplastic  Corp.,  Commercial  Resins  Div. 

GLY 

Glyco  Chemicals,  Inc. 

IPI 

Isocyanate  Products,  Inc. 

GNF 

General  Foods  Corp.,  Maxwell  House  Div. 

IPR 

Inter-Pacific  Resins,  Inc. 

GNM 

General  Mills,  Inc. 

IRC 

IRC,  Inc. 

GNT 

General  Tire  &  Rubber  Co.,  Chemical  Div. 

IRI 

Ironsides  Resins,  Inc. 

GOC 

Gulf  Oil  Corp. 

GOR 

Gordon  Chemical  Co.,  Inc. 

JCC 

Jefferson  Chemical  Co.,  Inc. 

GPM 

General  Plastics  Manufacturing  Co. 

JDC 

Nipak,  Inc. 

GPR 

Grain  Processing  Corp. 

JEN 

Jennison-Wright  Corp. 

GRA 

Great  American  Plastics  Co. 

JMS 

J.  Meyer  &   Sons,  Inc. 

GRD 

W.  R.  Grace  &  Co.,  Dewey  &  Almy  Chemical  Div. 

JNS 

S.  C.  Johnson  &  Son,  Inc. 

GRG 

P.  D.  George  Co. 

JNT 

Jennat  Corp. 

GRH 

W.  R.  Grace  &  Co.,  Hatco  Chemical  Div. 

JOB 

Jones-Blair  Paint  Co. 

GRS 

Pontiac  Refining  Corp. 

JOR 

Jordan  Chemical  Co. 

194  SYNTHETIC  ORGANIC  CHEMICALS,  1965 

TABLE  22.- -Synthetic  organic  chemicals:   Directory  of  manufacturers ,  i365--Continued 


Code 

Name  of  company 

Code 

Name  of  company 

JRG 

Andrew  Jergens  Co. 

MLS 

Miles  Laboratories,  Inc.,  Miles  Chemical  Co.  Div. 

JSC 

Jersey  State  Chemical  Co. 

MMM 

Minnesota  Mining  &  Manufacturing  Co. 

JTC 

Joseph  Turner  &  Co. 

MNO 

Monochem,  Inc. 

JWL 

Jewel  Paint  &  Varnish  Co. 

MNP 

Minnesota  Paints,  Inc. 

MOA 

Mona  Industries,  Inc. 

KAI 

Kaiser  Aluminum  &   Chemical  Corp. 

MOB 

Mobay  Chemical  Co. 

KAL 

Kali  Manufacturing  Co. 

MOC 

Marathon  Oil  Co.,  Texas  Refining  Div. 

KCC 

Kennecott  Copper  Corp.,  Chino  Mines  Div. 

MON 

Monsanto  Co. 

KCH 

Keystone  Chemurgic  Corp. 

MOR 

Mineral  Oil  Refining  Co. 

KCU 

Kennecott  Copper  Corp.,  Utah  Copper  Div. 

MOT 

Motomco,  Inc. 

KCW 

Keystone  Color  Works,  Inc. 

MPL 

Massachusetts  Plastics,  Div.  of  Rexall  Chemical  Group 

KEL 

Kelly-Pickering  Chemical  Corp. 

MPP 

Midwest  Plastic  Products  Co. 

KM 

Kendall  Refining  Co. 

MR 

Benjamin  Moore  &  Co. 

KET 

Ketona  Chemical  Corp. 

MRA 

Metro-Atlantic,  Inc. 

KF 

Kay- Fries  Chemicals,  Inc. 

MRB 

Marblette  Corp. 

KLS 

Kilsdonk  Chemical  Corp. 

MRD 

Marden-Wild  Corp. 

KMC 

Kohler-McLister  Paint  Co. 

MRK 

Merck  &  Co.,  Inc.,  and  Metalsalts  Corp. 

KMP 

Kelly-Moore  Paint  Co. 

MRN 

International  Latex  &  Chemical  Corp,  Paisley 

KND 

Knoedler  Chemical  Co. 

Products  Div. 

KNG 

Far- Best  Corp.,  0.  L.  King  Div. 

MRO 

W.  R.  Grace  &  Co.,  Marco  Chemical  Div. 

KNP 

Knapp  Products,  Inc. 

MRT 

Morton  Salt  Co.,  Morton  Chemical  Co.  Div. 

KON 

H.  Kohnstamm  &  Co.,  Inc. 

MRV 

Marlowe-Van  Loan  Corp. 

KPI 

Kenrich  Petrochemicals,  Inc. 

MRX 

Max  Marx  Color  &   Chemical  Co. 

KPP 

Sinclair-Koppers  Co. 

MSC 

Mississippi  Chemical  Corp. 

KPS 

Koppers  Pittsburgh  Co. 

MTO 

Montrose  Chemical  Corp.  of  California 

KPT 

Koppers  Co.,  Inc.,  Tar  &   Chemical  Div. 

MTR 

Baldwin-Montrose  Chemical  Co.,  Inc.,  Montrose 

KRM 

Lawter  Chemicals,  Inc.,  Krumbhaar  Resin  Div. 

Chemical  Div. 

KYN 

Kyanize  Paints,  Inc. 

MYW 

Stepan  Chemical  Co.,  Maywood  Div. 

KYS 

Keysor  Chemical  Co. 

NAC 

Allied  Chemical  Corp. ,  National  Aniline  Div. 

LAK 

Lakeway  Chemical  Co. 

NCI 

Union  Bag-Camp  Paper  Corp.,  Nelio  Chemical  Div. 

LAM 

LaMotte  Chemical  Products  Co. 

NCW 

Nostrip  Chemical  Works,  Inc. 

LAS 

Lasco  Industries,  Inc. 

NEO 

Norda  Essential  Oil  &  Chemical  Co.,  Inc. 

LEA 

Leatex  Chemical  Co. 

NEP 

Nepera  Chemical  Co.,  Inc. 

LEB 

Lebanon  Chemical  Corp. 

NES 

Nease  Chemical  Co.,  Inc. 

LEF 

Leffingwell  Chemical  Co. 

NEV 

Neville  Chemical  Co. 

LEH 

Lehigh  Chemical  Co. 

NIL 

Nilok  Chemicals,  Inc. 

LEM 

B.  L.  Lemke  &  Co.,  Inc. 

NIT 

Nitrin,  Inc. 

LEN 

Leonard  Refineries,  Inc. 

NIX 

Tenneco  Chemicals,  Inc.,  Nixon- Baldwin  Div. 

LEV 

Lever  Brothers  Co. 

NLC 

Nalco  Chemical  Co. 

LIL 

Eli  Lilly  &   Co. 

NOC 

Norac  Co.,  Inc. 

LKL 

Lakeside  Laboratories,  Div.  of  Colgate- 

NON 

A.  P.  Nonweiler  Co. 

Palmolive  Co. 

NOP 

Nopco  Chemical  Co.,  Inc. 

LKY 

St.  Regis  Paper  Co.,  Lake  States  Yeast  & 

NOR 

Norwich  Pharmacal  Co. 

Chemical  Div. 

NPC 

Northwest  Petrochemical  Corp. 

LMI 

North  American  Chemical  Co. 

NPI 

National  PoLychemicals,  Inc. 

LPC 

Lignin  Products  Co. 

NPP 

National  Plastic  Products  Co.,  Inc. 

LUB 

Lubrizol  Corp. 

NPV 

Norris  Paint  &  Varnish  Co. 

LUE 

George  Lueders  &  Co. 

NRS 

Norse  Chemical  Corp. 

LUR 

Laurel  Soap  Manufacturing  Co. 

NSC 

National  Starch  &   Chemical  Corp. 

LVR 

C.  Lever  Co.,  Inc. 

NSP 

Alabama  Binder  &  Chemical  Corp. 

LVY 

Fred'k  H.  Levey  Co.,  Inc. 

NTB 

National  Biochemical  Co. 

NTC 

National  Casein  Co. 

MAH 

Maher  Color  &  Chemical  Co. 

NTL 

National  Lead  Co. 

MAK 

MacKenzie  Chemical  Works,  Inc. 

NVF 

N.V.F.  Co. 

MAL 

Mallinckrodt  Chemical  Works 

NVT 

Novamont  Corp. 

MAN 

Manganese  Chemical  Corp. 

NW 

Northwestern  Chemical  Co. 

MAR 

American  Can  Co.,  Marathon  Div. 

NYC 

New  York  Color  &  Chemical  Corp.,  Subsidiary  of 

MAY 

Otto  B.  May,  Inc. 

Tenneco  Chemicals,  Inc. 

MCA 

Masonite  Corp. ,  Alpine  Chemical  Div. 

MCB 

Borg- Warner  Corp.,  Maroon  Chemical  Div. 

OCF 

Owens- Corning  Fiberglas  Corp. 

MCC 

McCloskey  Varnish  Co. 

OH 

Air  Reduction  Co.,  Inc.,  Ohio  Chemical  &  Surgical 

MCH 

Michigan  Chemical  Corp. 

Equipment  Co.  Div. 

MCI 

Mooney  Chemical  Corp. 

OMC 

Olin  Mathieson  Chemical  Corp.  and  Agricultural  Div. 

MED 

Medical  Chemicals  Corp. 

OMS 

E.  R.  Squibb  &   Sons  Div.  of  Olin  Mathieson  Chemical 

MEE 

Maumee  Chemical  Co. 

Corp. 

MER 

Jefferson  Lake  Sulphur  Co. ,  Chemical  Div. 

ONX 

Millmaster  Onyx  Corp. ,  Onyx  Chemical  Co.  Div. 

MET 

M  &.  T  Chemicals,  Inc. 

OPC 

Orbis  Products  Corp. 

MFG 

Molded  Fiber  Glass  Body  Co.,  Resin  Div. 

ORG 

Organics,  Inc. 

MGR 

Magruder  Color  Co.,  Inc. 

0R0 

Chevron  Chemical  Co.,  Oronite  Div. 

MHI 

Ventron  Corp.,  Metal  Hydrides  Div. 

ORT 

Roehr  Chemicals,  Inc. 

MID 

Midland  Industrial  Finishes  Co. 

OSB 

C.  J.  Osborn  Co. 

MIR 

Miranol  Chemical  Co.,  Inc. 

OTA 

Ottawa  Chemical  Co. 

MLD 

Metalead  Products  Corp.                   1 

OTC 

Ott  Chemical  Co. 

DIRECTORY  OF  MANUFACTURERS 
TABLE  22, — Synthetic  organic  chemicals.-   Directory  of  manufacturers ,   1965 — Continued 


195 


Code 

Name  of  company 

Code 

Name  of  company 

OTH 

Chevron  Chemical  Co. ,  Ortho  Div. 

RCD 

Richardson  Co. 

0X0 

Oxo  Chemicals  Co. 

RCI 

Reichhold  Chemicals,  Inc. 

OXR 

Onyx  Oils  &  Resins,  Inc. 

RDA 

Rhodia,  Inc. 

OXY 

Millmaster  Onyx  Corp. ,  Oxy  Chemical  Div. 

RED 

Red  Spot  Paint  &  Varnish  Co.,  Inc. 

REH 

Reheis  Chemical  Co. ,  Div.  of  Armour  Pharmaceutical  Co. 

PAI 

Pennsylvania  Industrial  Chemical  Corp. 

REL 

Reliance  Universal,  Inc. 

PAN 

Pan  American  Petroleum  Corp. 

REM 

Remington  Arms  Co.,  Inc. 

PAR 

Pennsylvania  Refining  Co. 

REN 

Renroh  Resins 

PAS 

Pennsalt  Chemicals  Corp. 

RET 

Rayette,  Inc. 

PAT 

Patent  Chemicals,  Inc. 

REZ 

Rezolin,  Inc. 

PBY 

Pillsbury  Co.,  Chemical  Div. 

RGC 

Rogers  Corp. 

PC 

Proctor  Chemical  Co.,  Inc. 

RH 

Rohm  &  Haas  Co. 

PCC 

USS  Chemicals  Div.  of  U.S.  Steel  Corp. 

RIC 

Richfield  Oil  Corp. 

PCH 

Peerless  Chemical  Co. 

RIK 

Riker  Laboratories  Div.  of  Rexall  Drug  &   Chemical  Co. 

PCI 

Pioneer  Chemical  Works,  Inc. 

RIL 

Reilly  Tar  &  Chemical  Corp. 

PCS 

Emery  Industries,  Inc.,  Western  Div. 

RIV 

Riverdale  Chemical  Co. 

PCW 

Pfister  Chemical  Works 

RLS 

Rachelle  Laboratories,  Inc. 

PD 

Parke,  Davis  &  Co. 

RMC 

Rinshed-Mason  Co. 

PDC 

Berncolors-Poughkeepsie,  Inc. 

ROC 

Rock  Hill  Printing  &  Finishing  Co. 

PDJ 

Joseph  Davis  Plastics  Co. 

ROM 

Roma  Chemical  Corp. 

PEK 

Peck's  Products  Co. 

ROY 

Royce  Chemical  Co. 

PEL 

Pelron  Corp. 

RPC 

Refined  Products  Co. 

PEN 

S.  B.  Penick  &  Co. 

RPI 

Rowland  Products,  Inc. 

PER 

Perry  &  Derrick  Co. 

RSA 

R.S.A.  Corp. 

PET 

Petroleum  Chemicals,  Inc. 

RSB 

Rosenberg  Bros.  &  Co. 

PFN 

Pfanstiehl  Laboratories,  Inc. 

RT 

F.  Ritter  &  Co. 

PFP 

Phe Ian- Faust  Paint  Manufacturing  Co., 

RTC 

Ritter  Chemical  Co.,  Inc. 

Phelan's  Resins  &  Plastics  Div. 

RTF 

Retzloff  Chemical  Co. 

PFW 

Polak's  Frutal  Works 

RUB 

Hooker  Chemical  Corp.,  RC  Div. 

PFZ 

Chas.  Pfizer  &  Co.,  Inc. 

RUR 

Ruberoid  Co. 

PG 

Procter  &  Gamble  Co.,  Procter  &  Gamble 
Manufacturing  Co.  Div. 

RZL 

Rozilda  Laboratories,  Inc. 

PGU 

Gulf  Oil  Corp.,  Chemical  Div.,  Perkins  Glue 

S 

Sandoz,  Inc.,  Dyestuff  Div.,  Pigments  Dept. 

Branch 

SAC 

Southeastern  Adhesives  Co. 

PHR 

Pharmachem  Corp. 

SAL 

Salsbury  Laboratories 

PIC 

Pierce  Organics,  Inc. 

SAR 

Sartomer  Resins,  Inc. 

PII 

Polymer  Industries,  Inc. 

SBC 

Scher  Bros.,  Inc. 

PIL 

Pilot  Chemical  Co. 

sec 

Standard  Chlorine  Chemical  Co.,  Inc. 

PIT 

Pitt-Consol  Chemical  Co. 

SCF 

Schaefer  Varnish  Co.,  Inc. 

PLA 

Richardson  Co.,  Richardson  Polymers  Div. 

SCH 

Schering  Corp. 

PLB 

P-L  Biochemicals,  Inc. 

SCN 

Schenectady  Chemicals,  Inc. 

PLC 

Phillips  Petroleum  Co. 

SCO 

Scholler  Bros.,  Inc. 

PLS 

Plastics  Engineering  Co. 

SCP 

Standard  Chemical  Products,  Inc. 

PLU 

Plumb  Chemical  Corp. 

SCR 

R.  P.  Scherer  Corp. 

PMA 

Plastics  Materials,  Inc. 

SDC 

Martin-Marietta  Corp.,  Southern  Dyestuff  Co.  Div. 

PMC 

Plastics  Manufacturing  Co. 

SDG 

Sterling  Drug,  Inc.,  Glenbrook  Laboratories  Div. 

PMP 

Premier  Malt  Products,  Inc. 

SDH 

Sterling  Drug,  Inc.,  Hilton-Davis  Chemical  Co.  Div. 

PNT 

Pantasote  Co. 

SDW 

Sterling  Drug,  Inc.,  Winthrop  Laboratories  Div. 

PNX 

Phoenix  Oil  Co. 

SEA 

Seaboard  Chemicals,  Inc. 

POL 

Polymer  Corp. 

SED 

Seidlitz  Paint  &  Varnish  Co. 

PPG 

Pittsburgh  Plate  Glass  Co. 

SEK 

Sekisui  Plastics  Corp. 

PPL 

Pioneer  Plastics  Corp.,  Chemical  Div. 

SEL 

Selney  Co.,  Inc. 

PRO 

Products  Research  &  Chemical  Corp. 

SEP 

Southeast  Polymers,  Inc. 

PRD 

Productol  Chemical  Co.,  Inc. 

SEY 

Seydel-Woolley  &  Co. ,  Inc. 

PRO 

Pure  Oil  Co. 

SF 

Stauffer  Chemical  Co.,  Industrial  Chemical  Div. 

PRP 

S.  B.  Penick  &  Co.,  Parsons-Plymouth  Div. 

SFA 

Stauffer  Chemical  Co.,  Specialty  Chemical  Div. 

PRT 

Pratt  &   Lambert,  Inc. 

SFD 

Sonford  Chemical  Co. 

PRX 

Purex  Corp.,  Ltd. 

SH 

Stein,  Hall  &  Co.,  Inc. 

PSC 

Passaic  Color  &   Chemical  Co. 

SHA 

Shanco  Plastics  &  Chemicals,  Inc. 

PSP 

Georgia-Pacific  Corp.,  Puget  Sound  Div. 

SHC 

Shell  Oil  Co.,  Shell  Chemical  Co.  Div. 

PTT 

Petro-Tex  Chemical  Corp. 

SHF 

National  Dairy  Products  Corp.,  Sheffield  Chemical 

PUB 

Publicker  Industries,  Inc. 

Co.  Div. 

PVI 

Polyvinyl  Chemicals,  Inc. 

SHL 

Shulton,  Inc. 

PYL 

Polychemical  Laboratories,  Inc. 

SHM 

Shamrock  Oil  &   Gas  Corp. 

PYR 

Poly  Resins 

SHO 

Shell  Oil  Co. 

PYZ 

Polyrez  Co.,  Inc. 

SHP 

Shepherd  Chemical  Co. 

SIC 

Vistron  Corp.,  Silmar  Div. 

QCP 

Quaker  Chemical  Corp. 

SID 

George  F.  Siddall  Co.,  Inc. 

QKO 

Quaker  Oats  Co. 

SIM 

Simpson  Timber  Co. 

QUN 

K.  J.  Quinn  &  Co.,  Inc. 

SIN 

Sinclair  Refining  Co. 

SIO 

Standard  Oil  Co.  of  Ohio 

RAB 

Raybestos-Manhattan,  Inc.,  Raybestos  Div. 

SIP 

James  P.  Sipe  &  Co. 

RBC 

Roberts  Chemicals,  Inc. 

SK 

Smith,  Kline  &   French  Laboratories 

RCC 

Rexall  Chemical  Co. 

SKC 

Sinclair  Koppers  Chemical  Co. 

196  SYNTHETIC  ORGANIC  CHEMICALS,  1965 

TABLE  22. — Synthetic  organic  chemicals.-  Directory  of  manufacturers,  1965 — Continued 


Code 

Name  of  company 

Code 

Name  of  company 

SKG 

Sunkist  Growers,  Inc. 

TRN 

Trancoa  Chemical  Corp. 

SKO 

Skelly  Oil  Co. 

TRO 

Troy  Chemical  Co. 

SLC 

Soluol  Chemical  Co.,  Inc. 

TSA 

Texas  ALkyls,  Inc. 

SLV 

Sterling  Drug,  Inc.,  Salvo  Chemical  Div. 

TTX 

Detrex  Chemical  Industries,  Inc. 

SM 

Socony  Mobil  Oil  Co.,  Inc.: 

TUS 

Texas-U.S.  Chemical  Co. 

Mobil  Chemical  Co.  Div. 

TV 

Tousey  Varnish  Co. 

Mobil  Oil  Co.  Div. 

TX 

Texaco,  Inc. 

SMC 

Stamford  Chemical  Co. 

TXC 

Tex  Chem  Co. 

SNA 

Sun  Chemical  Corp.,  Pigments  Div. 

TXT 

Textilana  Corp. 

SNC 

Sonoco  Products  Co. 

SNI 

Southern  Nitrogen  Co.,  Inc. 

UBS 

A.  E.  Staley  Manufacturing  Co.,  UBS  Chemical 

SNO 

SunOlin  Chemical  Co. 

Co.  Div. 

SNT 

Suntide  Refining  Co. 

UCC 

Union  Carbide  Corp.,  Chemicals  Div. 

SNW 

Sun  Chemical  Corp.,  Chemical  Products  Div. 

UCP 

Union  Carbide  Corp.,  Plastics  Div. 

SOC 

Standard  Oil  Co.  of  California,  Chevron 

ucs 

Union  Carbide  Corp.,  Silicones  Div. 

Chemical  Co. 

UDI 

Universal  Detergents,  Inc.  &  Petrochemicals 

Co. 

SOG 

Signal  Oil  &  Gas  Co. ,  Houston  Div. 

UHL 

Paul  Uhlich  &  Co.,  Inc. 

SOH 

Sohio  Chemical  Co.  &  Solar  Nitrogen 

UNC 

United  Cork  Companies 

Chemicals,  Inc. 

UNG 

Ungerer  &   Co. 

SOI 

American  Oil  Co.  (Maryland) 

UNN 

United  Chemical  Corp.  of  Norwood 

SOL 

Solar  Chemical  Corp. 

UNO 

United  Oil  Manufacturing  Co. 

SON 

Witco  Chemical  Co.,  Inc.,  Sonneborn  Div. 

UNP 

United  Chemical  Products  Corp. 

SOR 

Thomason  Industries,  Inc.,  Southern  Resin  Div. 

UNS 

Union  Starch  &   Refining  Co.,  Inc. 

SOS 

Southern  Sizing  Co. 

UOC 

Union  Oil  Co.  of  California 

SPC 

Sinclair  Paint  Co. 

UPF 

United  States  Pipe  &   Foundry  Co. 

SPD 

General  Electric  Co.,  Silicone  Products  Dept. 

UPJ 

Upjohn  Co. 

SPI 

Sinclair  Petrochemicals,  Inc. 

UPL 

United  States  Plywood  Corp.,  California  Div 

, 

SPL 

Spaulding  Fibre  Co.,  Inc. 

Shasta  Operations 

SPN 

Gulf  Oil  Corp.,  Chemicals  Dept. 

UPM 

Universal  Oil  Products  Co. 

SPY 

Standard  Pyroxoloid  Corp. 

UPR 

U.S.  Peroxygen  Corp. 

SRL 

G.  D.  Searle  &  Co. 

URC 

United  Carbon  Co. 

SRR 

Stresen-Reuter,  Inc. 

USB 

U.S.  Borax  Research  Corp. 

STA 

A.  E.  Staley  Manufacturing  Co. 

USI 

National  Distillers  &  Chemical  Corp. : 

STC 

Sou-Tex  Chemical  Co.,  Inc. 

A-B  Chemical  Corp.  Div. 

STG 

Stange  Co. 

National  Petro  Chemical  Corp.  Div. 

STP 

Stepan  Chemical  Co.,  Industrial  Chemicals 

U.S.  Industrial  Chemicals  Co.  Div. 

Div.,  Millsdale  Works 

USO 

U.S.  Oil  Co. 

SUG 

Sucro-Chemical  Div.  of  Colonial  Sugars  Co. 

USP 

U.S.  Plastic  &   Chemical  Corp. 

SUM 

Summit  Chemical  Products  Corp. 

USR 

United  States  Rubber  Co.,  Chemical  Div. 

SUN 

Sun  Oil  Co. 

UTR 

Utah  Resin  Co.,  Inc. 

SVC 

Sullivan  Varnish  Co. 

UVC 

Universal  Chemicals  Corp. 

SVT 

Solvent  Chemical  Co.,  Inc. 

SW 

Sherwin-Williams  Co. 

VAC 

Varney  Chemical  Corp. 

SWP 

Souhegan  Wood  Products,  Inc. 

VAL 

Valchem 

swr 

Swift  &  Co. 

VAR 

Reichhold  Chemicals,  Inc.,  Varcum  Chemical  Div. 

SYC 

Synthetic  Chemicals,  Inc. 

VB 

Vermi  lye- Bell 

SYN 

Synthron,  Inc. 

VDM 

Van  De  Mark  Chemical  Co. 

SYP 

Synthetic  Products  Co. 

VEL 

Velsicol  Chemical  Corp. 

SYR 

Syneo  Resins,  Inc. 

VGC 

Virginia  Chemicals,  Inc. 

SYV 

Synvar  Corp. 

VIN 
VLY 

Vineland  Chemical  Co. 
Chem-Fleur,  Inc. 

TAE 

Chemtron  Corp. ,  National  Cylinder  Gas  Div. 

VNC 

Vanderbllt  Chemical  Corp. 

TAY 

Taylor  Corp. 

VND 

Van  Dyk  &   Co.,  Inc. 

TBK 

Universal  Oil  Products  Co.,  Chemical  Div. 

VPC 

Verona-Pharma  Chemical  Corp. 

TCC 

Tanatex  Chemical  Corp. 

VPT 

Viekers  Refining  Co.,  Inc. 

TCH 

Trylon  Chemical  Corp. 

VSV 

Valentine  Sugars,  Inc.,  Valite  Div. 

TCI 

Texize  Chemicals,  Inc. 

VTM 

Vitamins,  Inc. 

TDC 

Diversey  Corp. 

VTV 

Vita-Var  Corp.,  Div.  of  Textron  Industries, 

Inc. 

TEN 

Tennessee  Copper  Co. 

TGL 

Triangle  Chemical  Co. 

WAS 

Washburn-Purex  Co. 

THC 

Thompson  Chemical  Co. 

WAW 

W.  A.  Wood  Co. 

TIC 

Ticonderoga  Chemical  Corp. 

WAY 

Philip  A.  Hunt  Chemical  Corp.,  Way land  Chemical  Div. 

TID 

Tidewater  Oil  Co. 

WBC 

Worthington  Biochemical  Corp. 

TKL 

Thiokol  Chemical  Corp. 

WBG 

White  &  Bagley  Co. 

TMC 

Tenneco  Manufacturing  Co. 

WCA 

West  Coast  Adhesives  Co. 

TMH 

Thompson- Hayward  Chemical  Co. 

WCC 

Witfield  Chemical  Corp. 

TMS 

Sterling  Drug,  Inc.,  Thomasset  Colors  Div. 

WES 

Weston  Chemical  Corp. 

TNA 

Ethyl  Corp. 

WHI 

White  8c   Hodges,  Inc. 

TNC 

Tennant  Development  Corp.,  Chemical  Div. 

WHL 

Whitmoyer  Laboratories,  Inc. 

TNI 

Gillette  Chemical  Co. 

WHW 

Whittemore- Wright  Co.,  Inc. 

TOC 

Tenneco  Oil  Co. 

WIC 

Wica  Chemicals,  Inc. 

TRC 

Toms  River  Chemical  Corp. 

WIL 

Wilson  8c   Co.,  Inc.,  Wilson  Laboratories  Div 

TRJ 

Trojan  Powder  Co. 

WJ 

Warner-Jenkinson  Manufacturing  Co. 

DIRECTORY  OF  MANUFACTURERS 
TABLE  11. — Synthetic  organic  chemicals;   Directory  of  manufacturers,  1965 — Continued 


197 


Code 

Name  of  company 

Code 

Name  of  company 

WLI 

White  Laboratories,  Inc. 

WTC 

Witco  Chemical  Co. ,  Inc. 

WLM 

Wilmot  8c   Cassidy,  Inc. 

WTH 

Wallace  &  Tiernan,  Inc.,  Harchejn  Div. 

WM 

Wilson  &  Co.,  Inc.,  Wilson-Martin  Di v. 

WTL 

Wallace  8c   Tiernan,  Inc.,  Lucidol  Div. 

TOD 

Wood  Chemicals,  Inc. 

WVA 

West  Virginia  Pulp  8c  Paper  Co., 

TOI 

Neville  Chemical  Co.,  Chlorinated 

Polychemicals  Div. 

Products  Div. 

WYN 

Wyandotte  Chemicals  Corp. 

TON 

Woonsocket  Color  &  Chemical  Co. 

WYT 

American  Home  Products  Corp.,  lyeth  Laboratories, 

WRC 

Wood  Ridge  Chemical  Corp. 

Inc.  Div. 

WRD 

Weyerhaeuser  Co.,  Wood  Products  Div. 

WSN 

Washine  Chemical  Corp. 

YAW 

Young  Aniline  Works,  Inc. 

198 


SYNTHETIC  ORGANIC  CHEMICALS.  1965 


TABLE  22. — Synthetic  organic  chemicals.-  Directory  of  manufacturers ,  1965 — Continued 

SECTION  2.  ALPHABETICAL  DIRECTORY  BY  COMPANY 

[Names  of  synthetic  organic  chemical  manufacturers  that  reported  production  or  sales  to  the  U.S.  Tariff  Commission 
for  1965  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  tables  in  pt.  III. 
Sec.  1  of  this  table  lists  these  manufacturers  in  the  order  of  their  identification  codes] 


Name  of  company 


Office  address 


Abbott  Laboratories 

Aceto  Industrial  Chemical  Corp 

Acme  Resin  Corp 

Acralite. Co. ,  Inc 

Air  Products  &  Chemicals,  Inc.,  Houdry  Process 

&  Chemical  Co.  Div. 
Air  Reduction  Co.,  Inc.,  Ohio  Chemical  &  Surgical 
Equipment  Co.  Div. 

Alabama  Binder  &  Chemical  Corp 

Alamo  Industries,  Inc 

Alco  Chemical  Corp 

Alcolac  Chemical  Corp 

Aldrich  Chemical  Co.,  Inc 

Alliance  Color  &  Chemical  Co 

Allied  Chemical  Corp.: 

Barrett  Div 

Fibers  Div 

General  Chemical  Div 

National  Aniline  Div 

Nitrogen  Div 


Solvay  Process  Div 

Union  Texas  Petroleum  Div 

Alox  Corp 

Amalgamated  Chemical  Corp 

Amchem  Products,  Inc 

American  Alkyd  Industries 

American  Aniline  &  Extract  Co.,  Inc 

American  Aniline  Products,  Inc 

American  Bio-Synthetics  Corp 

American  Brake  Shoe  Co.,  American  Brakeblok  Div — 

American  Can  Co.,  Marathon  Div — 

American  Chemical  Corp 

American  Cyanamid  Co 

American  Hoechst  Corp 

American  Home  Products  Corp.,  Wyeth  Laboratories, 
Inc.  Div. 

American  Oil  Co.  (Maryland) 

American  Oil  Co.  (Texas) ; 

American  Petrochemical  Corp 

American  Potash  &  Chemical  Corp 

American  Synthetic  Rubber  Corp 

American  Rubber  &  Chemical  Co 

American  Tartars  Corp 

Ames  Laboratories,  Inc 

Amoco  Chemicals  Corp 

Ancon  Chemical  Co 

Ansul  Chemical  Co 

Apex  Chemical  Co.,  Inc 

Appleton  Coated  Paper  Co 

Applied  Plastics  Co.,  Inc ■ 

Archer-Daniels-Midland  Co 

Ardmore  Chemical  Co 

Arenol  Chemical  Corp 

Argus  Chemical  Corp 

Arizona  Chemical  Co 

Arkansas  Co.,  Inc 

Armour  Agricultural  Chemical  Co 

Armour  Industrial  Chemical  Co 

Armour  Pharmaceutical  Co ■ 

Armstrong  Cork  Co 

Armstrong  Paint  &  Varnish  Works,  Inc 

Arol  Chemical  Products  Co 

Ashland  Oil  &  Refining  Co 

Astra  Pharmaceutical  Products,  Inc 

Atco  Chemical- Industrial  Products,  Inc 


14th  St.  and  Sheridan  Rd.,  N.  Chicago,  IL  60664. 

126-02  Northern  Blvd.,  Flushing,  New  York,  NY  11363. 

1401  Circle  Ave.,  Forest  Park,  IL  60130. 

59  Kent  St.,  Brooklyn,  NY  11222. 

Widener  Bldg.,  1339  Chestnut  St.,  Philadelphia,  PA  19107. 

1400  E.  Washington  Ave.,  Madison,  WI  53701. 

P.O.  Box  3179,  Tuscaloosa,  AL  35401. 

Ervin  Bldg.,  4037  Independence  Blvd.,  Charlotte,  NC  28205. 

Trenton  Ave.  and  William  St.,  Philadelphia,  PA  19134. 

3440  Fairfield  Rd.,  Baltimore,  MD  21226. 

2371  N.  30th  St.,  Milwaukee,  WI  53210. 

P.O.  Box  326,  Ridgefield,  NJ  07657. 

40  Rector  St.,  New  York,  NY  10006. 

1450  Broadway,  New  York,  NY  10018. 

P.0'.  Box  70,  Morristown,  NJ  07960. 

40  Rector  St.,  New  York,  NY  10006. 

P.O.  Drawer  61,  Hopewell,  VA  23860. 

P.O.  Box  365,  Morristown,  NJ  07960,  and  225  Allwood  Rd., 

Clifton,  NJ  07015. 
P.O.  Box  271,  Syracuse,  NY  13201. 
P.O.  Box  2120,  Houston,  TX  77001. 
3943  Buffalo  Ave.,  Niagara  Falls,  NY  14302. 
Ontario  and  Rorer  Sts.,  Philadelphia,  PA  19134. 
Brookside  Ave.,  Ambler,  PA  19002. 
Broad  and  14th  Sts.,  Carlstadt,  NJ  07072. 
Venango  and  F  Sts.,  Philadelphia,  PA  19134. 
P.O.  Box  2086,  Paterson,  NJ  07509. 
710  W.  National  Ave.,  Milwaukee,  WI  53204. 
900  W.  Maple  Rd.,  Troy,  MI  48012. 
Neenah,  WI  54957. 

P.O.  Box  9247,  Long  Beach,  CA  90810. 
Berdan  Ave.,  Wayne,  NJ  07470. 

129  Quidnick  St.,  W.  Warwick,  NJ  02893. 
P.O.  Box  8299,  Philadelphia,  PA  19101. 

910  S.  Michigan  Ave.,  Chicago,  IL  60680. 

910  S.  Michigan  Ave.,  Chicago,  IL  60680. 

3134  California  St.,  N.E.,  Minneapolis,  MN  55418. 

3000  W.  6th  St.,  Los  Angeles,  CA  90054. 

P.O.  Box  360,  Louisville,  KY  40201. 

P.O.  Box  1034,  Louisville,  KY  40201. 

420  Lexington  Ave . ,  New  York,  NY  10017. 

200  Rock  Lane,  Milford,  CT  06460. 

130  E.  Randolph  Dr.,  Chicago,  IL  60601. 
1  Stanton  St.,  Marinette,  WI  54143. 

1  Stanton  St.,  Marinette,  WI  54143. 

200  S.  1st  St.,  Elizabethport,  NJ  07206. 

825  E.  Wisconsin  Ave.,  Appleton,  WI  54910. 

130  Perm  St.,  El  Segundo,  CA  90246. 

500  Investors  Bldg.,  Minneapolis,  MN  55440. 

840  Valley  Brook  Ave.,  Lyndhurst,  NJ  07071. 

40-33  23d  St.,  Long  Island  City,  NY  11101. 

633  Court  St.,  Brooklyn,  NY  11231. 

Ill  W.  50th  St.,  New  York,  NY  10020. 

185  Foundry  St.,  P.O.  Box  210,  Newark,  NJ  07101. 

P.O.  Box  1685,  Atlanta,  GA  30301. 

P.O.  Box  1805,  Chicago,  IL  60609. 

P.O.  Box  511,  Kankakee,  IL  60901. 

W.  Liberty  St.,  Lancaster,  PA  17604. 

1330  S.  Kilbourn  Ave.,  Chicago,  IL  60623. 

371  Wayne  St.,  Jersey  City,  NJ  07302. 

1401  Winchester  Ave.,  Ashland,  KY  41101. 
7  Neponset  St.,  Worcester,  MA  01606. 

93  Main  St.,  Franklin,  NJ  07416. 


DIRECTORY  OF  MANUFACTURERS 
TABLE  22.-- Synthetic  organic  chemicals :  Directory  of  manufacturers ,  1 965— Continued 


199 


ATL 
ATR 
ATU 
APD 
APR 
AUG 
AVS 
AZT 

BRD 
BAC 
BKC 
BKT 
MTR 

BAL 

BC 

BXT 

BAX 

BLS 

BCM 

BL 

BME 

BEN 

BDO 

BPC 

PDC 

BUC 

BOR 

MCB 

BOY 

BFR 

BPL 

BBS 

BLN 

BRU 

BRY 

BUK 

BKM 

CD 

BJL 

BSC 

BUR 

CBT 
CAD 
CAU 
CAL 
CAP 
DRL 
CBM 
CGL 

CCW 

CCA 

CM 

CRS 

CAT 

CEL 


CCL 
CCC 
CHT 
CCI 
CHG 
CBD 

CTN 
TAE 
VLY 


Name  of  company 


Atlantic  Chemical  Corp 

Atlantic  Refining  Co 

Atlantic  Tubing  &   Rubber  Co 

Atlas  Chemical  Industries,  Inc. 

Atlas  Processing  Co 

Augusta  Chemical  Co 

Avisun  Corp 

Aztec  Chemicals,  Inc 


Chemicals  Div — 


Baird  Chemical  Industries,  Inc 

Baker  Castor  Oil  Co 

J.  T.  Baker  Chemical  Co 

Taylor  Div 

Baldwin-Montrose  Chemical  Co.,  Inc.,  Montros 
Chemical  Div. 

Baltimore  Paint  &  Chemical  Corp 

Barlow  Chemical  Corp 

J.  H.  Baxter  &  Co 

Baxter  Laboratories,  Inc 

Beech-Nut  Life  Savers,  Inc 

Belding  Chemical  Industries 

Belle  Chemical  Co.,  Inc 

Bendix  Corp.,  Marshall-Eclipse  Div 

Bennett's 

Benzenoid  Organics,  Inc 

Benzol  Products  Co 

Berncolors-Poughkeepsie,  Inc 

Blackman-Uhler  Chemical  Co 

Borden  Co.,  Borden  Chemical  Co.  Div 

Borg-Warner  Corp.,  Marbon  Chemical  Div 

Walter  N.  Boysen  Co 

Branchf lower  Co 

Brand  Plastics  Co 

Bristol-Meyers  Co.,  Bristol  Laboratories  Div 

Brooklyn  Color  Works,  Inc 

M.  A.  Bruder  &  Sons,  Inc 

Bryant  Chemical  Corp 

Buckeye  Cellulose  Corp 

Buckman  Laboratories,  Inc 

Budd  Co.,  Polychem  Div 

Burdick  &  Jackson  Laboratories,  Inc 

Burkart-Schier  Chemical  Co- 

Burroughs-Wellcome  &  Co.  (U.S.A.),  Inc 


Samuel  Cabot,  Inc 

Cadet  Chemical  Corp 

Calcasieu  Chemical  Corp 

Callery  Chemical  Co 

Cap-Roc,  Inc.,  Capital  Plastics  Div 

Caradco,  Inc.,  Durel  Div 

Carborundum  Co.,  Coated  Abrasives  Div- 
Cargill,  Inc 


Carlisle  Chemical  Works,  Inc 

Advance  Div 

Carpenter-Morton  Co 

Carus  Chemical  Co.,  Inc 

Catalin  Corp.  of  America 

Celanese  Corp.  of  America: 

Celanese  Chemical  Co.  Div 

Celanese  Coatings  Co 

Celanese  Plastics  Co 

Fibers  Co.  Div 

Charlotte  Chemical  Laboratories 

Chase  Chemical  Corp 

Chattanooga  Medicine  Co.,  Chattem  Chemicals  Div- 

Checkmate  Chemicals,  Inc 

Chemagro  Corp 

Chembond  Corp 

Chemetron  Corp.: 

Chemetron  Chemicals,  Organic  Chemical  Dept 

National  Cylinder  Gas  Div 

Chem-Fleur,  Inc 


Office  address 


P.O.  Box  216,  Nutley,  NJ  07110. 

260  S.  Broad  St.,  Philadelphia,  PA  19101. 

Mill  St.,  Cranston,  RI  02905. 

New  Murphy  Rd.  and  Concord  Pike,  Wilmington,  DE  19899. 

P.O.  Box  1786,  3546  Midway  St.,  Shreveport,  LA  71102. 

P.O.  Box  660,  Augusta,  GA  30903. 

P.O.  Box  312,  New  Castle,  DE  19720. 

P.O.  Box  756,  Elyria,  OH  44035. 

185  Madison  Ave.,  New  York,  NY  10016. 
40  Avenue  A,  Bayonne,  NJ  07002. 
600  N.  Broad  St.,  Phillipsburg,  NJ  08865. 
600  N.  Broad  St.,  Phillipsburg,  NJ  08865. 
100  Lister  Ave.,  Newark,  NJ  07105. 

2325  Hollins  Ferry  Rd.,  Baltimore,  MD  21230. 

Barlow  Lane,  Ossining,  NY  10562. 

120  Montgomery  St.,  San  Francisco,  CA  94104. 

6301  N.  Lincoln  Ave.,  Morton  Grove,-  IL  60053. 

Canajoharie,  NY  13317. 

1407  Broadway,  New  York,  NY  10018. 

P.O.  Box  848,  Lowell,  NC  28089. 

P.O.  Box  238,  Troy,  NY  12180. 

65  W.  1st  S.,  Salt  Lake  City,  UT  84110. 

P.O.  Box  177,  Attleboro,  MA  02703. 

237  South  St.,  Newark,  NJ  07114. 

77  N.  Water  St.,  Poughkeepsie,  NY  12602. 

P.O.  Box  1869,  Spartanburg,  SC  29301. 

350  Madison  Ave.,  New  York,  NY  10017. 
P.O.  Box  68,  Washington,  WV  26181. 

1001  42d  St.,  Oakland,  CA  94608. 

4501  Shilshole  St.  NW.,  Seattle,  WA  98103. 

130  E.  Randolph  Dr.,  Chicago,  IL  60601. 

P.O.  Box  657,  Syracuse,  NY  13201. 

681  Morgan  Ave.,  Brooklyn,  NY  11222. 

52d  St..  and  Grays  Ave.,  Philadelphia,  PA  19143. 

6  North  St.,  N.  Quincy,  MA  02171. 

2899  Jackson  Ave.,  Memphis,  TN  38108. 

1256  N.  McLean  Blvd.,  Memphis,  TN  38108. 

70  S.  Chapel  St.,  Newark,  DE  19711. 

1953  S.  Harvey  St.,  Muskegon,  MI  49442. 

1228  Chestnut  St.,  Chattanooga,  TN  37402. 

1  Scarsdale  Rd.,  Tuckahoe,  NY  10707. 

246  Summer  St.,  Boston,  MA  02210. 

2153  Lockport-Olcott  Rd.,  Burt,  NY  14028. 

P.O.  Box  1522,  Lake  Charles,  LA  70601. 

Callery,  PA  16024. 

250  Mill  St.,  Rochester,  NY  14614. 

1098  Jackson  St.,  Dubuque,  IA  52000. 

P.O.  Box  477,  Niagara  Falls,  NY  14302. 

Room  2008,  3  Penn  Center  Plaza,  Philadelphia,  PA  19102, 

and  Cargill  Bldg.,  Minneapolis,  MN  55402. 
West  St.,  Reading,  OH  45215. 
500  Jersey  Ave.,  New  Brunswick,  NJ  08903. 
376  W.  3d  St.,  Everett,  MA  02149. 
1375  8th  St.,  LaSalle,  IL  61301. 
1  Park  Ave.,  New  York,  NY  10016. 

522  5th  Ave.,  New  York,  NY  10036. 

1481  S.  11th  St.,  Louisville,  KY  40208. 

744  Broad  St.,  Newark,  NJ  07102. 

P.O.  Box  1414,  Charlotte,  NC  28201. 

P.O.  Box  948,  5046  Old  Pineville  Rd.,  Charlotte,  NC  28201. 

3527  Smallman  St.,  Pittsburgh,  PA  15201. 

1717  W.  38th  St.,  Chattanooga,  TN  37409. 

P.O.  Box  2164,  Greenville,  SC  29602. 

P.O.  Box  4913,  Station  "F",  Kansas  City,  M0  64120. 

P.O.  Box  270,  Springfield,  OR  97477. 

201  E.  42d  St.,  New  York,  NY  10017. 

840  N.  Michigan  Ave.,  Chicago,  IL  60611. 

200  Pulaski  St.,  Newark,  NJ  07105. 


20o  SYNTHETIC  ORGANIC  CHEMICALS.  1965 

TABLE  22.—  Synthetic  organic  chemicals.-  Directory  of  manufacturers ,  1 965— Continued 


Name  of  company 


Chemical  Formulators,  Inc 

Chemical  Insecticide  Corp 

Chemical  Products  Corp 

Chemico,  Inc 

Chemirad  Corp 

Chemlek  Laboratories,  Inc 

Chemol,  Inc 

Chevron  Chemical  Co.: 

Oronite  Div 

Ortho  Div 

Childs  Pulp  Colors,  Inc 

Chipman  Chemical  Co.,  Inc 

Ciba  Chemical  &  Dye  Co 

Ciba  Corp.: 

Ciba  Pharmaceutical  Co.  Div 

Ciba  Products  Co 

Cities  Service  Oil  Co 

Clark  Oil  &  Refining  Corp 

W.  A.  Cleary  Corp 

Clintwood  Chemical  Co 

Clover  Chemical  Co 

Cockerille  Chemicals,  Inc 

Colab  Resin  Corp 

Colgate-Palmolive  Co 

Collier  Carbon  &  Chemical  Corp 

Colloids,  Inc 

Columbian  Carbon  Co 

Columbia  Organic  Chemicals  Co.,  Inc 

Commercial  Products  Co.,  Inc 

Commercial  Solvents  Corp 

Commonwealth  Oil  Refining  Co.,  Inc 

Conchemco,  Inc.,  H.  B.  Davis  Co.  Div 

Concord  Chemical  Co.,  Inc 

Conestoga  Chemical  Corp 

Consolidated  Papers,  Inc 

Continental  Chemical  Co 

Continental  Oil  Co 

Cook  Paint  &  Varnish  Co 

Cooperative  Farm  Chemicals  Association 

Coopers  Creek  Chemical  Corp 

Copolymer  Rubber  &  Chemical  Corp 

Corn  Products  Co 

Cosden  Oil  &  Chemical  Co 

Cowles  Chemical  Co 

Crest  Chemical  Corp 

Crompton  &  Knowles  Corp . : 

Althouse  Chemical  Co.  Div 

Bates  Div 

Crosby  Chemicals,  Inc 

Crown  Central  Petroleum  Corp 

Crown  Chemical  Corp 

Crown  Zellerbaeh  Corp.,  Chemical  Products  Div 

Culver  Chemical  Co 

Cumberland  Chemical  Corp.,  Subsidiary  of  Air 
Reduction  Co.,  Inc. 

Cutter  Laboratories,  Inc 

Cyclamate  Corp.  of  America 


Office  address 


Dan  River  Mills,  Inc 

Joseph  Davis  Plastics  Co 

Dawe's  Laboratories,  Inc 

Degen  Oil  &  Chemical  Co 

Delaware  Chemicals,  Inc 

DePaul  Chemical  Co.,  Inc 

DeSoto  Chemical  Coatings,  Inc — 
Detrex  Chemical  Industries,  Inc- 

Dexter  Chemical  Corp 

Diamond  Alkali  Co 

Western  Div 

Diversey  Corp 

Dixie  Chemical  Co- 

Dixie  Pine  Products  Co.,  Inc 

Donald  A.  Dodd 


P.O.  Box  26,  Nitro,  WV  25143. 

20  Whitman  Ave.,  Metuchen,  NJ  08840. 

P.O.  Box  449,  Cartersville,  GA  30120. 

2508  E.  Bailey  Rd.,  Cuyahoga  Falls,  OH  44221. 

P.O.  Box  187  (Ryders  Lane),  E.  Brunswick.  NJ  08816. 

4040  W.  123d  St.,  Alsip,  IL  60658. 

P.O.  Box  3227,  Greensboro,  NC  27402. 

200  Bush  St.,  San  Francisco,  CA  94120. 

940  Hensley,  Richmond,  CA  94800. 

43  Summit  St.,  Brooklyn,  NY  11231. 

P.O.  Box  2009,  297  Jersey  Ave.,  New  Brunswick,  NJ  08903. 

Route  208,  Fair  Lawn,  NJ  07410. 

556  Morris  Ave.,  Summit,  NJ  07901. 

556  Morris  Ave.,  Summit,  NJ  07901. 

P.O.  Box  300,  Tulsa,  OK  74102. 

131st  St.  and  Kedzie  Ave.,  Blue  Island,  IL  60406. 

P.O.  Box  749,  New  Brunswick,  NJ  08903. 

1  N.  LaSalle  St.,  Chicago,  IL  60602. 

360  Regis  Ave.,  Pittsburgh,  PA  15236. 

Greenwood,  VA  22943. 

Main  St.,  Tewksbury,  MA  01876. 

300  Park  Ave.,  New  York,  NY  10022. 

714  W.  Olympic  Blvd.,  Los  Angeles,  CA  90015. 

394  Frelinghuysen  Ave.,  Newark,  NJ  07114. 

380  Madison  Ave.,  New  York,  NY  10017. 

912  Drake  St.,  Columbia,  SC  29205. 

117  Ethel  Ave.,  Hawthorne,  NJ  07641. 

260  Madison  Ave.,  New  York,  NY  10016. 

P.O.  Box  4423,  San  Juan,  PR  00905. 

Bayard  and  Severn  Sts . ,  Baltimore,  MD  21230. 

205  S.  2d  St.,  Camden,  NJ  08103. 

Wilmington  Industrial  Park,  Wilmington,  DE  19801. 

Wisconsin  Rapids,  WI  54494. 

270  Clifton  Blvd.,  Clifton,  NJ  07015. 

9  Rockefeller  Plaza,  New  York,  NY  10020. 

P.O.  Box  389,  N.  Kansas  City,  M0  64141. 

P.O.  Box  308,  Lawrence,  KS  66044. 

River  Rd.,  W.  Conshohocken,  PA  19428. 

P.O.  Box  2591,  Baton  Rouge,  LA  70821. 

717  5th  Ave.,  New  York,  NY  10022. 

P.O.  Box  1311,  Big  Spring,  TX  70721. 

12000  Shaker  Blvd.,  Cleveland,  OH  44120. 

225  Emmet  St.,  Newark,  NJ  07114. 

500  Pear  St.,  Reading,  PA  19603. 
Scottdale  Rd.,  Lansdowne,  PA  19050. 
P.O.  Drawer  460,  Picayune,  MS  39466. 
P.O.  Box  1168.  Baltimore,  MD  21203. 
12  Dudley  St.,  Providence,  RI  02901. 
Camas,  WA  98607. 

1502  N.  25th  St.,  Melrose  Park,  IL  60160. 
150  E.  42d  St.,  New  York,  NY  10017. 

4th  and  Parker  Sts.,  Berkeley,  CA  94710. 
100  Lister  Ave.,  Newark,  NJ  07105. 

Danville,  VA  24540. 

450  Schuyler  Ave.,  Kearny,  NJ  07032. 

4800  S.  Richmond  St.,  Chicago,  IL  60632. 

200  Kellogg  St.,  Jersey  City,  NJ  07305. 

726  King  St.,  Wilmington,  DE  19801. 

44-27  Purvis  St.,  Long  Island  City,  NY  11101. 

1700  S.  Mt.  Prospect  Ave.,  Des  Plaines,  IL  60018. 

14331  Woodrow  Wilson,  Detroit,  MI  48232. 

845  Edgewater  Rd.,  Bronx,  NY  10474. 

300  Union  Commerce  Bldg.,  Cleveland,  OH  44114. 

300  Union  Commerce  Bldg.,  Cleveland,  OH  44114. 

212  W.  Monroe  St.,  Chicago,  IL  60606. 

P.O.  Box  13410,  Houston,  TX  77019. 

P.O.  Box  470,  Hattiesburg,  MS  39401. 

8002  53d  Ave.  W.,  Everett,  WA  98202. 


DOM 
DVC 
DBC 
DOW 
DCC 
DRW 
DUN 
DUP 
DSC 


DIRECTORY  OF  MANUFACTURERS  201 

TABLE  22.-- Synthetic  organic  chemicals.-  Directory  of  manufacturers ,  1965 --Continued 


Name  of  company 


Inc- 


Dominion  Products, 

Dover  Chemical  Co 

Dow  Badische  Chemical  Co 

Dow  Chemical  Co 

Dow  Corning  Corp 

Drew  Chemical  Corp- 

Frank  W.  Dunne  Co 

E.  I.  duPont  de  Nemours  &  Co.,  Inc- 
Dye  Specialties,  Inc 


J.  S.  &  W.  R.  Eakins,  Inc 

Eastern  Color  &  Chemical  Co 

Eastman  Kodak  Co 

Tennessee  Eastman  Co.  Div 

Texas  Eastman  Co.  Div 

Edcan  Laboratories 

El  Paso  Natural  Gas  Products  Co- 
Emery  Industries,  Inc 

Western  Div 

Emkay  Chemical  Co 

Endo  Laboratories,  Inc 

Enjay  Chemical  Co 

Epoxylite  Corp 

Escambia  Chemical  Corp 

Ethyl  Corp 

Ethyl-Dow  Chemical  Co 

Evans  Chemetics,  Inc 


FMC  Corp . : 

American  Viscose  Div 

Inorganic  Chemicals  Div- 


Niagara  Chemical  Div— 
Organic  Chemicals  Div- 


Fabrieolor  Manufacturing  Corp 

Fairmount  Chemical  Co.,  Inc 

Farac  Oil  &  Chemical  Co 

Far-Best  Corp.,  0.  L.  King  Div 

Farmers  Chemical  Association,  Inc 

Farmer's  Chemical  Co 

Farnow,  Inc 

Federal  Color  Laboratories 

Felton  Chemical  Co.,, Inc 

Fermco  Laboratories,  Inc 

Ferro  Corp.,  Ferro  Chemical  Div 

Fiberfil,  Inc 

Fibreboard  Paper  Products  Corp 

Filtered  Rosin  Products  Co 

Fine  Organics,  Inc 

Firestone  Tire  &  Rubber  Co.: 

Firestone  Plastics  Co.  Div 

Firestone  Rubber  &  Latex  Products  Co.  Div— 
Firestone  Synthetic  Rubber  &  Latex  Co.  Div- 

Fisher  Melamine  Corp 

Fleming  Laboratories,  Inc 

Florasynth  Laboratories,  Inc 

Foote  Mineral  Co 

Foremost  Chemical  Products  Co 

Formica  Corp 

Foster  Grant  Co.,  Inc 

Foster-Heaton  Co 

France,  Campbell  &  Darling,  Inc 

Franklin  Chemical  Co 

Freeman  Chemical  Corp 

Frisch  &  Co.,  Inc 

Fritzsche  Bros.,  Inc 

H.  B.  Fuller  Co 

W.  P.  Fuller  Paint  Co 


Office  address 


882  3d  Ave.,  Brooklyn,  NY  11232. 
15th  and  Davis  Sts.,  Dover,  OH  44622. 
P.O.  Box  875,  Freeport,  TX  77541. 
Main  St.,  Midland,  MI  48640. 
P.O.  Box  592,  Midland,  MI  48641. 
416  Division  St.,  Boonton,  NJ  07005. 
1007  41st  St.,  Oakland,  CA  94608. 
DuPont  Bldg.,  Wilmington,  DE  19898. 
26  Journal  Sq.,  Jersey  City,  N J  07306. 

55  Berry  St.,  Brooklyn,  NY  11211. 

35  Livingston  St.,  Providence,  RI  02904. 

343  State  St.,  Rochester,  NY  14650. 

P.O.  Box  511,  Kingsport,  TN  37662. 

P.O.  Box  2068,  Longview,  TX  75603. 

10  Pine  St.,  S.  Norwalk,  CT  06856. 

P.O.  Box  3986,  Odessa,  TX  79760. 

4300  Carew  Tower,  Cincinnati,  OH  45202. 

8733  S.  Dice  Rd.,  Santa  Fe  Springs,  CA  90670. 

319  2d  St.,  Elizabeth,  NJ  07206. 

1000  Stewart  Ave.,  Garden  City,  NY  11533. 

60  W.  49th  St.,  New  York,  NY  10020. 

P.O.  Box  3397,  1428  N.  Tyler  Ave.,  S.  El  Monte,  CA  91733. 

P.O.  Box  467,  Pensacola,  FL  32502. 

100  Park  Ave.,  New  York,  NY  10017. 

Midland,  MI  48640. 

250  E.  43d  St.,  New  York,  NY  10017. 


1617  John  F.  Kennedy  Blvd.,  Philadelphia,  PA  19103. 
Sawyer  Ave.  and  River  Rd.,  Tonawanda,  NY  14207,  and  633 

3d  Ave.,  New  York,  NY  10017. 
100  Niagara  St.,  Middleport,  NY  14105. 
1701  Patapsco  Dr.,  Baltimore,  MD  21226,  and  633  3d  Ave. 

New  York,  NY  10017. 
24-1/2  Van  Houten  St.,  Paterson,  NJ  07505. 
117  Blanchard  St.,  Newark,  NJ  07105. 
147th  St.  and  Indiana  Ave.,  Chicago,  IL  60627. 
640  Gilman  St.,  Berkeley,  CA  94710. 
P.O.  Box  67,  Tyner,  TN  37392. 
P.O.  Box  591,  Kalamazoo,  MI  49005. 
77  Jacobus  Ave.,  S.  Kearny,  NJ  07032. 
4526  Chickering  Ave . ,  Cincinnati,  OH  45232. 
599  Johnson  Ave.,  Brooklyn,  NY  11237. 
4941  S.  Racine  Ave.,  Chicago,  IL  60609. 
P.O.  Box  349,  Bedford,  OH  44014. 
1701  N.  Heidelbach  Ave.,  Evansville,  IN  47717. 
1550  Powell  St.,  Emeryville,  CA  94608. 
P.O.  Box  349,  Baxley,  GA  31513. 
205  Main  St.,  Lodi,  NJ  07644. 

P.O.  Box  699,  Pottstown,  PA  19464. 

1  Firestone  Ave.,  Fall  River,  MA  02722. 

381  W.  Wilbeth  Rd.,  Akron,  OH  44301. 

90  Park  Ave.,  New  York,  NY  10016. 

P.O.  Box  10372,  2205  Thrift  Rd.,  charlotte,  NC  28201. 

900  Van  Nest  Ave.,  Bronx,  NY  10462. 

Route  100,  Exton,  PA  19341. 

P.O.  Box  599,  Oakland,  CA  94604. 

Berdan  Ave.,  Wayne,  NJ  07470. 

289  N.  Main  St.,  Leominster,  MA  01453. 

16  E.  5th  St.,  Paterson,  NJ  07524. 

N.  Michigan  Ave.,  Kenilworth,  NJ  07033. 

2020  Bruck  St.,  Columbus,  OH  43207. 

222  E.  Main  St.,  Port  Washington,  WI  53074. 

88  E.  11th  St.,  Paterson,  NJ  07524. 

76  9th  Ave.,  New  York,  NY  10011. 

1150  Eustis  St.,  St.  Paul,  MN  55108. 

450  E.  Grand  Ave.,  S.  San  Francisco,  CA  94080. 


Gamma  Chemical  Corp 355  Lexingtorl  Ave-)  New  York  m   10017. 

Cane  s  Chemical  Works,  Inc 535  5th  Ave.,  New  York,  NY  10017 

Geigy  Chemical  Corp |  p.0.  box  430,  Yonkers,  NY  10704. 


202  SYNTHETIC  ORGANIC  CHEMICALS,  1965 

TABLE  22. Synthetic  organic  chemicals.-  Directory  of  manufacturers ,  1965 — Continued 


Name  of  company 


Office  address 


General  Aniline  &  Film  Corp.,  Dyestuff  & 

Chemical  Div. 
General  Electric  Co.: 

Chemical  Materials  Dept 

Insulating  Materials  Dept 

Silicone  Products  Dept 

General  Foods  Corp.,  Maxwell  House  Div 

General  Latex  &  Chemical  Corp 

General  Mills,  Inc 

Chemical  Div 

General  Plastics  Manufacturing  Co 

General  Tire  &  Rubber  Co.,  Chemical  Div 

Geolina  Business,  Inc 

P.  D.  George  Co 

Georgia-Pacific  Corp.: 

Coos  Bay  Div 

Puget  Sound  Div 

Gillette  Chemical  Co 

Gilman  Paint  &  Varnish  Co 

Givaudan  Corp 

Glasflex,  Inc-r 

Glidden  Co 

Durkee  Famous  Foods  Div 

Glyco  Chemicals,  Inc 

B.  F.  Goodrich  Co.,  B.  F.  Goodrich  Chemical  Co 
Div. 

Goodrich-Gulf  Chemicals,  Inc 

Goodyear  Tire  &  Rubber  Co 

Gordon  Chemical  Co.,  Inc 

W.  R.  Grace  &  Co.: 

Dewey  &  Almy  Chemical  Div 

Hampshire  Chemical  Div 

Hatco  Chemical  Div 

Marco  Chemical  Div 

Nitrogen  Products  Div 

Grain  Processing  Corp 

Great  American  Plastics  Co 

Great  Lakes  Chemical  Corp 

Great  Western  Sugar  Co 

Grow  Chemical  Corp.,  Harris  Paint  Co.  Div 

Guardsman  Chemical  Coatings,  Inc 

Gulf  Oil  Corp 

Chemicals  Dept 

Perkins  Glue  Branch 

Guth  Chemical  Co 

H  &  N  Chemical  Co 

Haag  Laboratories,  Inc 

Halby  Products  Co.,  Inc 

C.  P.  Hall  Co.  of  Illinois 

Hamilton  Chemical  Corp 

Hampden  Color  &  Chemical  Co 

Hanna  Paint  Manufacturing  Co.,  Inc 

Harshaw  Chemical  Co 

Hartman-Leddon  Co 

Hart  Products  Corp 

Haveg  Industries,  Inc.,  Kesin  &   Compound  Div— ■ 

Hawkeye  Chemical  Co 

Hercules  Powder  Co.,  Inc 

Imperial  Color  &  Chemical  Dept 

Heresite  &  Chemical  Co 

Hess  Oil  &  Chemical  Corp 

Heterochemical  Corp 

Hexagon  Laboratories,  Inc 

Hodag  Chemical  Corp 

Hoffmann-LaRoche,  Inc 

Hoffman-Taff,  Inc 

Holland-Suco  Color  Co 

Hooker  Chemical  Corp 

Durez  Plastics  Div 

RC  Div 

E.  F.  Houghton  &  Co 


P.O.  Box  12,  Linden,  NJ  07036. 


1  Plastics  Ave.,  Pittsfield,  MA  01203. 
1  Campbell  Rd.,  Schenectady,  NY  12306. 
Waterford,  NY  12188. 
1125  Hudson  St.,  Hoboken,  NJ  07030. 
666  Main  St.,  Cambridge,  MA  02139. 
S.  Kensington  Rd.,  Kankakee,  IL  60901. 
Quimby  St.,  Ossining,  NY  10562. 
3481  S.  35th  St.,  Tacoma,  WA  98409. 
1708  Englewood  Ave.,  Akron,  OH  44309. 
P.O.  Box  1557,  Savannah,  GA  31402. 
5200  N.  2d  St.,  St.  Louis,  M0  63147. 

P.O.  Box  869,  Coos  Bay,  OR  97420. 

300  Laurel  St.,  Bellingham,  WA  98225. 

P.O.  Box  362,  N.  Chicago,  IL  60064. 

W.  8th  and  Pine  Sts.,  Chattanooga,  TN  37401. 

125  Delawanna  Ave.,  Delawanna,  NJ  07014. 

Stirling,  NJ  07980. 

900  Union  Commerce  Bldg.,  Cleveland,  OH  44115. 

2333  Logan  Blvd.,  Chicago,  IL  60647. 

417  5th  Ave.,  New  York,  NY  10016. 

3135  Euclid  Ave.,  Cleveland,  OH  44137. 

1717  E.  9th  St.,  Cleveland,  OH  44114. 
1144  E.  Market  St.,  Akron,  OH  44316. 
88  Webster  St.,  Worcester,  MA  01603. 

62  Whittemore  Ave.,  Cambridge,  MA  02140. 

Poisson  Ave.,  Nashua,  NH  03060. 

King  George  Post  Rd.,  P.O.  Box  27,  Fords,  NJ  08863. 

1711  W.  Elizabeth  Ave.,  Linden,  NJ  07036. 

P.O.  Box  277,  147  Jefferson  Ave.,  Memphis,  TN  38101. 

1600  Oregon  St.,  Muscatine,  IA  52761. 

85  Water  St.,  Fitchburg,  MA  21420. 

P.O.  Box  2200,  Highway  52  N.W.,  West  Lafayette,  IN  47906. 

P.O.  Box  5308,  Terminal  Annex,  Denver,  CO  80217. 

1010-26  N.  19th  St.,  Tampa,  FA  33601. 

1350  Steele  Ave.  SW.,  Grand  Rapids,  MI  49502. 

P.O.  Drawer  2100,  Houston,  TX  77001. 

610  Dwight  Bldg.,  Kansas  City,  M0  64105. 

632  Cannon  Ave.,  Lansdale,  PA  19446. 

332  S.  Center  St.,  Hillside,  IL  60162. 

Maltese  Dr.,  Totowa,  NJ  07512. 

14010  S.  Seeley,  Blue  Island,  IL  60406. 

P.O.  Box  366,  Wilmington,  DE  19899. 

5245  W.  73d  St.,  Chicago,  IL  60638. 

45  Andrews  St.,  Lowell,  MA  01853. 

5  Albany  St.,  Springfield,  MA  01101. 

1313  Windsor  Ave.,  Columbus,  OH  43216. 

1945  E.  97th  St.,  Cleveland,  OH  44106. 

60th  St.  and  Woodland  Ave.,  Philadelphia,  PA  19143. 

1440  Broadway,  New  York,  NY  10018. 

900  Greenbank  Rd.,  Wilmington,  DE  19808. 

P.O.  Box  899,  Clinton,  IA  52733. 

Hercules  Tower,  910  Market  St.,  Wilmington,  DE  19899. 

P.O.  "Box  231,  Glens  Falls,  NY  12803. 

822  S.  14th  St.,  Manitowoc,  WI  54220. 

State  St.,  Perth  Amboy,  NJ  08861. 

Ill  E.  Hawthorne  Ave.,  Valley  Stream,  NY  11582. 

3536  Peartree  Ave.,  Bronx,  NY  10469. 

7247  N.  Central  Park  Ave.,  Skokie,  IL  60076. 

324  Kingsland  Rd.,  Nutley,  NJ  07110. 

P.O.  Box  1246  SSS,  Springfield,  M0  65805. 

P.O.  Box  2166,  24th  St.  and  5th  Ave.,  Huntington, 

WV  25722. 
Buffalo  Ave.  and  47th  St.,  Niagara  Falls,  NY  14302. 
Walck  Rd.,  N.  Tonawanda,  NY  14121. 
New  South  Rd.,  Hicksville,  L.I.,  NY  11802. 
303  W.  Lehigh  Ave.,  Philadelphia,  PA  19133. 


DIRECTORY  OF  MANUFACTURERS 
TABLE  22.—  Synthetic  organic  chemicals.-  Directory  of  manufacturers,  1965— Continued 


203 


Name  of  company 


Houston  Chemical  Corp 

Charles  L.  Huisking  &  Co.,  Inc.,  Clintbrook 

Chemical  Co.  Div. 

Humphrey  Chemical  Co 

Philip  A.  Hunt  Chemical  Corp.,  Wayland  Chemical 

Div. 

Husky-Dominion  Briquets 

Hynson,   Westcott  &  Dunning,    Inc 

Hysol  Corp 


LAK 
LAM 
GDN 

LAS 
LUR 


I.C.I.    (Organics),    Inc 

IRC,    Inc 

Imperial  Chemical  Co.,    Inc 

Industrial  Biochemicals 

Industrial  Dyestuff  Co 

Inland  Steel  Container  Co 

Interchemical  Corp. : 

Color  &  Chemicals  Div 

Finishes  Div 

Organic  Chemicals  Dept 

International  Flavors  &  Fragrances,  Inc 

International  Latex  Corp 

International  Latex  &  Chemical  Corp.,  Paisley 
Products  Div. 

International  Minerals  &  Chemical  Corp 

Inter-Pacific  Resins,  Inc 

Interplastic  Corp.,  Commercial  Resins  Div 

Ironsides  Resins,  Inc 

Isocyanate  Products,  Inc 


Jefferson  Chemical  Co.,  Inc 

Jefferson  Lake  Sulphur  Co.,  Chemical  Div- 

Jennat  Corp 

Jennison-Wright  Corp 

Andrew  Jergens  Co 

Jersey  State  Chemical  Co 

Jewel  Paint  &  Varnish  Co 

S.  C.  Johnson  &  Son,  Inc 

Jones-Blair  Paint  Co 

Jordan  Chemical  Co 


Kaiser  Aluminum  &  Chemical  Corp- 

Kali  Manufacturing   Co 

Kay-Fries   Chemicals,    Inc 

Kelly-Moore  Paint  Co 

Kelly-Pickering  Chemical  Corp— 

Kendall  Refining  Co 

Kennecott  Copper  Corp. : 

Chino  Mines  Div 

Utah  Copper  Div 

Kenrich  Petrochemicals,    Inc 

Ketona  Chemical  Corp 

Keysor  Chemical  Co 

Keystone  Chemurgic  Corp 

Keystone  Color  Works,    Inc 

Kilsdonk  Chemical  Corp 


Office  address 


Knapp  Products,    Inc 

Knoedler  Chemical  Co 

Kohler-McLister  Paint  Co 

H.   Kohnstamm  &  Co.,    Inc 

Koppers  Co.,    Inc.,   Tar  &  Chemical  Div- 

Koppers  Pittsburgh  Co 

Kyanize  Paints,    Inc 


Lakeside  Laboratories,   Div.   of   Colgate-Palmolive 

Co. 

Lakeway  Chemical  Co 

LaMotte  Chemical  Products  Co 

Lancaster  Chemical  Corp.,  Gordon  Chemicals  Co. 

Div. 

Lasco  Industries,  Inc 

Laurel  Soap  Manufacturing  Co 

Lawter  Chemicals,  Inc.,  Krumbhaar  Resin  Div 


200  Madison  Ave.,  New  York,  NY  10016. 
417  5th  Ave.,  New  York,  NY  10016. 

Devine  St.,  North  Haven,  CT  06473. 
P.O.  Box  63,  Lincoln,  RI  02865. 

P.O.  Box  380,  Cody,  WY  82414. 

Charles  and  Chase  Sts.,  Baltimore,  MD  21201. 

1100  Seneca  Ave.,  Olean,  NY  14760. 

55  Canal  St.,  Providence,  RI  02901. 

401  N.  Broad  St.,  Philadelphia,  PA  19108. 

W.  6th  and  Grass  Sts.,  Shenandoah,  IA  51601. 

Edison  Industrial  Center,  Edison,  NJ  08817. 

P.O.  Box  4249,  Massasoit  Ave.,  E.  Providence,  RI  02914. 

6532  S.  Menard  Ave.,  Chicago,  IL  60638. 

150  Wagaraw  Rd.,  Hawthorne,  NJ  07506. 

1255  Broad  St.,  Clifton,  NJ  07015. 

P.O.  Box  8,  Route  17,  Carlstadt,  NJ  07072. 

521  W.  57th  St.,  New  York,  NY  10019. 

Playtex  Park,  Dover,  DE  19901. 

1770  Canalport  Ave.,  Chicago,  IL  60616. 

5401  Old  Orchard  Rd.,  Skokie,  IL  60078. 

P.O.  Box  445,  1602  N.  18th  St.,  Sweet  Home,  OR  97386. 

2015  N.E.  Broadway  St.,  Minneapolis,  MN  55413. 

270  W.  Mound  St.,  P.O.  Box  1999,  Columbus,  OH  43216. 

900  Wilmington  Rd.,  New  Castle,  DE  19720.. 

P.O.  Box  53300,  Houston,  TX  77052. 

1914  Haden  Rd.,  Houston,  TX  77015. 

137  W.  168th  St.,  Gardena,  CA  90247. 

P.O.  Box  4187,  Station  E,  Toledo,  OH  43609. 

2535  Spring  Grove  Ave.,  Cincinnati,  OH  45214. 

59  Lee  Ave.,  Haledon,  NJ  07508. 

345  N.  Western  Ave.,  Chicago,  IL  60612. 

1525  Howe  St.,  Racine,  WI  53403. 

6969  Denton  Dr.,  Dallas,  TX  75235. 

Barclay  Bldg.,  1  Belmont  Ave.,  Bala  Cynwyd,  PA  19004. 

P.O.  Box  337,  Gramercy,  LA  70052. 
427  E.  Mayer  St.,  Philadelphia,  PA  19125. 
360  Lexington  Ave.,  New  York,  NY  10017. 
1015  Commercial  St.,  San  Carlos,  CA  94070. 
956  Bransten  Rd.,  San  Carlos,  CA  94070. 
77  N.  Kendall  Ave.,  Bradford,  PA  16701. 

Hurley,  NM  88043. 

P.O.  Box  11299,  Salt  Lake  City,  UT  84111. 

Foot  of  E.  22d  St.,  Bayonne,  NJ  07002. 

P.O.  Box  6565,  Tarrant  Branch,  Birmingham,  AL  35217. 

26000  Bouquet  Canyon  Rd.,  Saugus,  CA  91350. 

R.D.  2,  Bethlehem,  PA  18017. 

151  W.  Gay  Ave.,  York,  PA  17403. 

c/o  Pfister  Chemical  Works,  P.O.  Box  326,  Ridgefield,  NJ 

07657. 
180  Hamilton  Ave.,  Lodi,  NJ  07644. 
651  High  St.,  Lancaster,  PA  17604. 
P.O.  Box  546,  1201  Osage  St.,  Denver,  CO  80201. 
161  Avenue  of  the  Americas,  New  York,  NY  10013. 
Koppers  Bldg.,  430  7th  Ave.,  Pittsburgh,  PA  15219. 
Koppers  Bldg.,  430  7th  Ave.,  Pittsburgh,  PA  15219. 
2d  and  Boston  Sts.,  Everett,  MA  02149. 

1707  E.  North  Ave.,  Milwaukee,  WI  53201. 

5025  Evanston  Ave.,  Muskegon,  MI  49443. 

Chestertown,  MD  21620. 

500  A  St.,  Wilmington,  DE  19801. 

1561  Chapin  Rd.,  Montebello,  CA  90640. 

Thompson  and  Tioga  Sts.,  Philadelphia,  PA  19134. 

3550  Touhy  Ave.,  Chicago,  IL  60645. 


204  SYNTHETIC  ORGANIC  CHEMICALS,  1965 

TABLE  22. —  Synthetic  organic  chemicals ;  Directory  of  manufacturers ,  1965 — Continued 


Name  of  company 


Leatex  Chemical  Co 

Lebanon  Chemical  Corp 

Leffingwell  Chemical  Co 

Lehigh  Chemical  Co 

Lehn  &  Fink  Products  Corp.,  Beacon  Div 

B.  L.  Lemke  &  Co.,  Inc 

Leonard  Refineries,  Inc 

Lever  Brothers  Co 

C.  Lever  Co.,  Inc 

Fred'k  H.    Levey  Co.,    Inc 

Lignin  Products   Co 

ELi  Lilly  &  Co 

Lubrizol  Corp 

George  Lueders  &  Co 

M  &  T  Chemicals,    Inc 

MacKenzie  Chemical  Works,    Inc 

Magruder  Color  Co.,    Inc 

Maher  Color  &  Chemical  Co 

Mallinckrodt  Chemical  Works 

Manganese  Chemical  Corp 

Marathon  Oil  Co.,   Texas  Refining  Div 

Marblette  Corp 

Marden-Wild   Corp 

Marlowe-Van  Loan  Corp 

Martin-Marietta  Corp. : 

Ridgway  Color  &  Chemical  Div 

Southern  Dyestuff  Co.   Div 

Max  Marx  Color  &  Chemical  Co 

Masonite  Corp.,  Alpine  Chemical  Div 

Massachusetts  Plastics,  Div.  of  Rexall  Chemical 
Group. 

Maumee  Chemical  Co 

Otto  B.  May,  Inc 

McCloskey  Varnish  Co 

Medical  Chemicals  Corp 

Merck  &  Co.,  Inc 

Metalsalts  Corp 

Metalead  Products  Corp 

Metro- Atlantic,  Inc 

J.  Meyer  &  Sons,  Inc 

Michigan  Chemical  Corp 

Midland  Industrial  Finishes  Co 

Midwest  Plastic  Products  Co 

Miles  Laboratories,  Inc.,  Miles  Chemical  Co.  Div 
Millmaster  Onyx  Corp. : 

Millmaster  Chemical  Div.,  Berkeley  Chemical 
Dept. 

Onyx  Chemical  Co.  Div 

Oxy  Chemical  Div 

Mineral  Oil  Refining  Co 

Minnesota  Mining  &  Manufacturing  Co 

Minnesota  Paints,  Inc 

Miranol  Chemical  Co.,  Inc 

Mississippi  Chemical  Corp 

Mobay  Chemical  Co 

Molded  Fiber  Glass  Body  Co.,  Resin  Div 

Mona  Industries,  Inc 

Monochem,  Inc 

Monsanto  Co. : 

Bircham  Bend  Plant ■ 

Chemstrand  Co.  Div 

Chocolate  Bayou  Plant 

Gering  Plastics  Dept 

Organic  Chemical  Div 

Plastics  Div 

Western  Div 

Montrose  Chemical  Corp.  of  California 

Mooney  Chemical  Corp 

Benjamin  Moore  &  Co 

Morton  Salt  Co.,  Morton  Chemical  Co.  Div 

Motomco,  Inc 


Office  address 


2722  N.  Hancock  St.,  Philadelphia,  PA  19133. 

P.O.  Box  180,  Lebanon,  PA  17042. 

P.O.  Box  1187,  Perry  Annex,  Whittier,  CA  90604. 

P.O.  Box  120,  Chestertown,  MD  21620. 

33  Richdale  Ave.,  Cambridge,  MA  02140. 

199  Main  St.,  Lodi,  NJ  07644. 

E.  Superior  St.,  Alma,  MI  48801. 

390  Park  Ave.,  New  York,  NY  10022. 

Howard  and  Huntington  Sts.,  Philadelphia,  PA  19133. 

380  Madison  Ave.,  New  York  NY  10017. 

P.O.  Box  960,  Erie,  PA  16512. 

740  S.  Alabama  St.,  Indianapolis,  IN  46206. 

29400  Lakeland  Blvd.,  Wickliffe,  OH  44092. 

427  Washington  St.,  New  York,  NY  10013. 

Woodbridge  Rd.  and  Randolph  Ave.,  Rahway,  NJ  07065. 

1  Cordello  Ave.,  Central  Islip,  L. I.,  NY  11722. 

2385  Richmond  Terrace,  Staten  Island,  NY  10302. 

1700  N.  ELston  Ave.,  Chicago,  IL  60622. 

P.O.  Box  5439,  St.  Louis,  M0  63160. 

711  Pittman  Rd.,  Baltimore,  MD  21236. 

P.O.  Box  1191,  Texas  City,  TX  77591. 

37-31  30th  St.,  Long  Island  City,  NY  11101. 

500  Columbia  St.,  Somerville,  MA  02143. 

1508  Joshua  Circle,  High  Point,  NC  27261. 

75  Front  St.,  Ridgway,  PA  15853. 
P.O.  Box  10098,  Charlotte,  NC  28201. 
192  Coit  St.,  Irvington,  NJ  07111. 
P.O.  Box  2392,  Gulf  port,  MS  39503. 
West  Ave.,  Ludlow,  MA  01056. 

1310  Expressway  Dr.,  Toledo,  OH  43608. 
52  Amsterdam  St.,  Newark,  NJ  07105. 
7600  State  Rd.,  Philadelphia,  PA  19136. 
4541  W.  Grand  Ave.,  Chicago,  IL  60639. 
126  E.  Lincoln  Ave.,  Rahway,  NJ  07065. 

200  Wagaraw  Rd.,  Hawthorne,  NJ  07507- 

P.O.  Box  11005,  2901  Park  Blvd.,  Palo  Alto,  CA  94306. 

1027  Smith  St.,  Centerdale,  RI  02911. 

4321  N.  4th  St.,  Philadelphia,  PA  19140. 

500  N.  Bankson  St.,  St.  Louis,  MI  48880. 

P.O.  Box  620,  E.  Water  St.,  Waukegan,  IL  60086. 

3251  Chicago  Rd.,  Steger,  IL  64075. 

1127  Myrtle  St.,  Elkhart,  IN  46514. 

99  Park  Ave.,  New  York,  NY  10016. 

Warren  and  Morris  Sts.,  Jersey  City,  NJ  07302. 

P.O.  Box  28,  Hackettstown,  NJ  07840. 

4401  Park  Ave.,  Dickinson,  TX  77539. 

2501  Hudson  Rd.,  St.  Paul,  MN  55119. 

1101  S.  3d  St.,  Minneapolis,  MN  55415. 

277  Coit  St.,  Irvington,  NJ  07111- 

P.O.  Box  388,  Yazoo  City,  MS  39194. 

Penn  Lincoln  Parkway,  W.  Pittsburgh,  PA  15205. 

4601  Benefit  Ave.,  Ashtabula,  OH  44004. 

65  E.  23d  St.,  Paterson,  NJ  07524. 

P.O.  Box  433,  Geismar,  LA  70734. 

190  Grochmal  Ave.,  Indian  Orchard,  MA  01051. 

350  5th  Ave.,  New  York,  NY  10001. 

P.O.  Box  711,  Alvin,  TX  77511. 

200  N.  7th  St.,  Kenilworth,  NJ  07033. 

800  N.  Lindbergh  Blvd.,  St.  Louis,  M0  63166. 

730  Worcester  St.,  Springfield,  MA  01101;  P.O.  Box  1311, 

Texas  City,  TX  77591;  and  River  Rd.,  Addyston,  OH  45001. 
9229  E.  Marginal  Way  S.,  Seattle,  WA  98108. 
500  S.  Virgil  Ave.,  Los  Angeles,  CA  90005. 
2301  Scranton  Rd.,  Cleveland,  OH  44113. 
548  5th  Ave.,  New  York,  NY  10036. 
110  N.  Wacker  Dr.,  Chicago,  IL  60606. 
89  Terminal  Ave.,  Clark,  NJ  07066. 


DIRECTORY  OF  MANUFACTURERS 
TABLE  22. -Synthetic  organic  chemicals.-  Directory  of  manufacturers ,  1 965 --Continued 


205 


NVF 
NLC 
NTB 
NTC 

HUM 
SHF 
USI 


NTL 
NPP 
NPI 
NSC 
NES 
NEP 
NOT 
WOI 
NYC 

NIL 
JDC 
NIT 
NON 
NOP 
NOC 

NEC- 

NPV 

NRS 

LMI 

NW 

NPC 

NOR 

NCW 

NVT 

CMG 


OXR 
OPC 
ORG 
OSB 
OTA 
OTC 
OCF 
0X0 

PLB 

AMR 

PAN 

PNT 

PD 

PSC 

PAT 

CCH 

PEK 

PCH 

PEL 

PEN 

PRP 

PAS 

PAI 

PAR 

PER 

PET 

PTT 

PFN 

PCW 

PFZ 

PHR 


Name  of  company 


N.V.F.  Co 

Nalco  Chemical  Co 

National  Biochemical  Co 

National  Casein  Co 

National  Dairy  Products  Corp.: 

Humko  Products  Chemical  Div 

Sheffield  Chemical  Co.  Div 

National  Distillers  &  Chemical  Corp. : 

A-B  Chemical  Corp.  Div 

National  Petro  Chemical  Corp.  Div 

U.S.  Industrial  Chemicals  Co.  Div 

National  Lead  Co 

National  Plastic  Products  Co.,  Inc 

National  Polychemicals,  Inc 

National  Starch  &  Chemical  Corp 

Nease  Chemical  Co.,  Inc 

Nepera  Chemical  Co.,  Inc 

Neville  Chemical  Co 

Chlorinated  Products  Div 

New  York  Color  &  Chemical  Corp.,  Subsidiary  of 
Tenneco  Chemicals,  Inc.. 

Nilok  Chemicals,  Inc 

Nipak,  Inc 

Nitrin,  Inc 

A.  P.  Nonweiler  Co 

Nopco  Chemical  Co.,  Inc 

Norac  Co.,  Inc 


Norda  Essential  Oil  &   Chemical  Co. 

Norris  Paint  &  Varnish  Co 

Norse  Chemical  Corp 

North  American  Chemical  Co 

Northwestern  Chemical  Co 

Northwest  Petrochemical  Corp 

Norwich  Pharmacal  Co 

Nostrip  Chemical  Works,  Inc 

Novamont  Corp 

Nyanza,  Inc 


Inc- 


Olin  Mathieson  Chemical  Corp- 

Agricultural  Div 

Onyx  Oils  &   Resins,  Inc 

Orbis  Products  Corp 

Organics,  Inc 

C.  J.  Osborn  Co 

Ottawa  Chemical  Co 

Ott  Chemical  Co 

Owens-Corning  Fiberglas   Corp- 
Oxo  Chemicals   Co 


P-L  Biochemioals,    Inc 

Pacific  Resins  &  Chemical  Co 

Pan  American  Petroleum  Corp 

Pantasote  Co 

Parke,   Davis  &  Co 

Passaic   Color  &  Chemical  Co 

Patent  Chemicals,    Inc 

Pearsall  Chemical  Co 

Peck's  Products   Co 

Peerless   Chemical  Co ; 

Pelron  Corp 

S.    B.    Penick  &  Co 

Parsons-Plymouth  Div 

Pennsalt  Chemicals   Corp 

Pennsylvania  Industrial  Chemical  Corp- 

Pennsylvania  Refining  Co 

Perry  &  Derrick  Co 

Petroleum  Chemicals,    Inc 

Petro-Tex  Chemical  Corp 

Pfanstiehl  Laboratories,    Inc 

Pfister  Chemical  Works 

Chas.   Pfizer  &  Co.,    Inc 

Pharmachem  Corp 


Office  address 


Maryland  Ave.   and  Beech  St.,   Wilmington,   DE  19899. 
6216  W.   66th  PI.,    Chicago,    IL  60638. 
3127  W.    Lake  St.,    Chicago,    IL  60612. 
601  W.   80th  St.,    Chicago,    IL  60620. 


P.O. 
P.O. 


Box  398,  Memphis,  TN  38101. 
Box  630,  Norwich,  NY  13815. 


99  Park  Ave.,  New  York,  NY  10016. 

99  Park  Ave.,  New  York,  NY  10016. 

99  Park  Ave.,  New  York,  NY  10016. 

Ill  Broadway,  New  York,  NY  10006. 

Odenton,  MD  21113. 

51  Eames  St.,  Wilmington,  MA  01887. 

750  3d  Ave.,  New  York,  NY  10017. 

P.O.  Box  221,  State  College,  PA  16801. 

Route  17  and  Averill  Ave.,  Harriman,  NY  10926. 

Neville  Island  P.O.,  Pittsburgh,  PA  15225. 

Neville  Island  P.O.,  Pittsburgh,  PA  15225. 

374  Main  St.,  Belleville,  NJ  07109. 

Mill  St.  and  N.  Transit,  Lockport,  NY  14094. 

301  S.  Howard  St.,  Dallas,  TX  75221. 

P.O.  Box  233,  Cordova,  IL  61242. 

P.O.  Box  1007,  Oshkosh,  WI  54901. 

60  Park  PI.,  Newark,  NJ  07101. 

405  S.  Motor  Ave.,  Azusa,  CA  91703,  and  169  Millbank  St. 

Lodi,  NJ  07644. 
475  10th  Ave.,  New  York,  NY  10001. 
1710  Front  St.  NE.,  Salem,  OR  97303. 
2121  Norse  Ave.,  Cudahy,  WI  53110. 
19  S.  Canal  St.,  Lawrence,  MA  01843. 
120  N.  Aurora  St.,  W.  Chicago,  IL  60185. 
P.O.  Box  99,  Anacortes,  WA  98221. 
17  Eaton  Ave.,  Norwich,  NY  13815. 
182  Liberty  Ave.,  Jamaica,  NY  11433. 
P.O.  Box  189,  Kenova,  WV  25530. 
Magunco  Rd.,  P.O.  Box  349,  Ashland,  MA  01721. 

445  W.  59th  St.,  New  York,  NY  10019. 
P.O.  Box  991,  Little  Rock,  AR  72203. 
95  Broad  St.,  New  York,  NY  10004. 
475  10th  Ave.,  New  York,  NY  10018. 
1724  Greenleaf  Ave.,  Chicago,  IL  60628. 
1301  W.  Blancke  St.,  Linden,  NJ  07036. 
700  N.  Wheeling  St.,  Toledo,  OH  43605. 
500  Agard  Rd.,  Muskegon,  MI  49945. 
National  Bank  Bldg.,  Toledo,  OH  43614. 
2100  Grant  Bldg.,  Pittsburgh,  PA  15219. 

1037  W.  McKinley  Ave.,  Milwaukee,  WI  53205. 

3400  13th  Ave.  SW.,  Seattle,  WA  98134. 

P.O.  Box  591,  Tulsa,  OK  74102. 

26  Jefferson  St.,  Passaic,  NJ  07056. 

Foot  of  Jos.  Campau,  Detroit,  MI  48232. 

28-36  Paterson  St.,  Paterson,  NJ  07501. 

335  McLean  Blvd.,  Paterson,  NJ  07504. 

P.O.  Box  108,  Phillipsburg,  NJ  08865. 

P.O.  Box  14508,  St.  Louis,  M0  63178. 

3850  Oakman  Blvd.,  Detroit,  MI  48204. 

7847  W.  47th  St.,  Lyons,  IL  60534. 

100  Church  St.,  New  York,  NY  10008. 

100  Church  St.,  New  York,  NY  10008. 

3  Penn  Center,  Philadelphia,  PA  19102. 

120  State  St.,  P.O.  Box  240,  Clairton,  PA  15025. 

Union  Bank  Bldg.,  Butler,  PA  16001. 

2510  Highland  Ave.,  Norwood,  OH  45212. 

P.O.  Box  1522,  Lake  Charles,  LA  70601. 

P.O.  Box  2584,  Houston,  TX  77001. 

1219  Glen  Rock  Ave.,  Waukegan,  IL  60086. 

P.O.  Box  326,  Ridgefield,  NJ  07657. 

235  E.  42d  St.,  New  York,  NY  10017. 

Broad  and  Wood  Sts.,  Bethlehem,  PA  18015. 


206  SYNTHETIC  ORGANIC  CHEMICALS,  1965 

TABLE  22. — Synthetic  organic  chemicals;  Directory  of  manufacturers ,  1965 — Continued 


Name  of  company 


Office  address 


RGC 
RH 


Phelan-Faust  Paint  Manufacturing  Co.,  Phelan's 
Resins  &  Plastics  Div. 

Phillips  Petroleum  Co 

Phoenix  Oil  Co 

Pierce  Organies,  Inc 

Pillsbury  Co.,  Chemical  Div 

Pilot  Chemical  Co 

Pioneer  Chemical  Works,  Inc 

Pioneer  Plastics  Corp.,  Chemical  Div 

Pitt-Consol  Chemical  Co 

Pittsburgh  Plate  Glass  Co 

Plastics  Engineering  Co 

Plastics  Manufacturing  Co 

Plastics  Materials,  Inc 

Plumb  Chemical  Corp 

Polak's  Frutal  Works 

Polychemical  Laboratories,  Inc 

Polymer  Corp 

Polymer  Industries,  Inc 

Poly  Resins 

Polyrez  Co.,  Inc 

Polyvinyl  Chemicals,  Inc 

Pontiac  Refining  Corp 

Pratt  &  Lambert,  Inc 

Premier  Malt  Products,  Inc 

Procter  &  Gamble  Co.,  Procter  &  Gamble  Manufac- 
turing Co.  Div. 

Proctor  Chemical  Co.,  Inc 

Productol  Chemical  Co.,  Inc 

Products  Research  &   Chemical  Corp 

Publicker  Industries,  Inc 

Pure  Oil  Co 

Purex  Corp.,  Ltd 

Quaker  Chemical  Corp 

Quaker  Oats  Co 

K.  J.  Quinn&Co.,  Inc 

R.S.A.  Corp 

Rachelle  Laboratories,  Inc 

Raybestos-Manhattan,  Inc.,  Raybestos  Div 

Rayette,  Inc 

Red  Spot  Paint  &  Varnish  Co.,  Inc 

Refined  Products  Co ■ 

Reheis  Chemical  Co.,  Div.  of  Armour  Pharma- 
ceutical Co. 

Reichhold  Chemicals,  Inc 

Varcum  Chemical  Div 

Reilly  Tar  &  Chemical  Corp 

Reliance  Universal,  Inc 

Remington  Arms  Co.,  Inc 

Renroh  Resins 

Retzloff  Chemical  Co 

Rexall  Chemical  Co 

Rexall  Chemical  Co.  -  Kearny 

Rezolin,  Inc 

Rhodia,  Inc 

Richardson  Co 

Richardson  Polymers  Div 

Richfield  Oil  Corp 

Riker  Laboratories,  Div.  of  Rexall  Drug  & 

Chemical  Co. 

Rinshed-Mason  Co 

F.  Ritter  &  Co 

Ritter  Chemical  Co.,  Inc 

Ritter  Pfaudler  Corp.,  Ionac  Chemical  Co.  Div-- 

Riverdale  Chemical  Co 

Roberts  Chemicals,  Inc 

Rock  Hill  Printing  &  Finishing  Co 

Roehr  Chemicals,  Inc 

Rogers  Corp 

Rohm  &  Haas  Co 


Oak  St.  and  Buff  Rd.,  P.O.  Box  189,  Burlington,  IA  52602. 

Bartlesville,  OK  74003. 

9505  Cassius  Ave.,  Cleveland,  OH  44-105. 

P.O.  Box  98,  Rockford,  IL  61105. 

1152  Pillsbury  Bldg.,  Minneapolis,  MN  55402. 

11756  Burke  St.,  Santa  Fe  Springs,  CA  90670. 

940  N.  Delaware  Ave.,  Philadelphia,  PA  19123. 

Pionite  Rd.,  Auburn,  ME  04210. 

191  Doremus  Ave.,  Newark,  NJ  07105. 

I  Gateway  Center,  Pittsburgh,  PA  15222. 
1607  Geele  Ave.,  Sheboygan,  WT  53082. 
2700  S.  Westmoreland,  Dallas,  TX  75224. 
New  South  Rd.,  Hicksville,  NY  11801. 
4837  James  St.,  Philadelphia,  PA  19137. 
33  Sprague  Ave.,  Middletown,  NY  10940. 
490  Hunts  Point  Ave.,  New  York,  NY  10059. 
2120  Fairmont  Ave.,  Reading,  PA  19603. 
Viaduct  Rd.,  Springdale,  CT  06879. 
11655  Wicks  St.,  Sun  Valley,  CA  91352. 
P.O.  Box  320,  Woodbury,  NJ  08096. 

26  Howley  St.,  Peabody,  MA  01960. 

P.O.  Box  1581,  Corpus  Christi,  TX  78403. 

75  Tonawanda  St.,  Buffalo,  NY  14207. 

917  W.  Juneau  Ave.,  Milwaukee,  WI  53201. 

Ivorydale  Technical  Center,  Rm.  2S25,  Cincinnati, 

OH  45217. 
P.O.  Box  399,  Salisbury,  NC  28144. 
615  S.  Flower  St.,  Los  Angeles,  CA  90017. 
2919  Empire  Ave.,  Burbank,  CA  91504. 
1429  Walnut  St.,  Philadelphia,  PA  19102. 
200  E.  Gulf  Rd.,  Palatine,  IL  60067. 
5101  Clark  Ave.,  Lakewood,  CA  90712. 

Elm,  Lime,  and  Sandy  Sts.,  Conshohocken,  PA  19428. 
Merchandise  Mart  Plaza,  Chicago,  IL  60654. 
195  Canal  St.,  Maiden,  MA  02148. 

690  Saw  Mill  River  Rd.,  Ardsley,  NY  10502. 

P.O.  Box  9095,  700  Henry  Ford  Ave.,  Long  Beach,  CA  90810. 

75  E.  Main  St.,  Stratford,  CT  06601. 

261  E.  5th  St.,  St.  Paul,  MN  55101. 

110  Main  St.,  Evansville,  IN  47708. 

624  Schuyler  Ave.,  Lyndhurst,  NJ  07071. 

325  Snyder  Ave.,  Berkeley  Heights,  NJ  07922. 

525  N.  Broadway,  White  Plains,  NY  10602. 
Niagara  Falls,  NY  14302. 

II  S.  Meridan  St.,  Indianapolis,  IN  46204. 

4730  Crittenden  Dr.,  P.O.  Box  21067,  Louisville,  KY 

40221,  and  6901  Cavalcade,  Houston,  TX  77001. 
939  Barnum  Ave.,  Bridgeport,  CT  06602. 
P.O.  Box  1191,  New  Bern,  NC  28560. 
P.O.  Box  45296,  Houston,  TX  77045. 
8480  Beverly  Blvd.,  Los  Angeles,  CA  90048. 
1106  Harrison  Ave.,  Kearny,  NJ  07029. 
1651  18th  St.,  Santa  Monica,  CA  90404. 
600  Madison  Ave.,  New  York,  NY  10022. 
27th  Ave.  and  Lake  St.,  Melrose  Park,  IL  60160. 
345  Morgan  Lane,  West  Haven,  CT  06516. 
555  S.  Flower  St.,  Los  Angeles,  CA  90054. 
19901  Nordhoff  St.,  Northridge,  CA  91326. 

5935  Milford  Ave.,  Detroit,  MI  48210. 

4001  Goodwin  Ave.,  Los  Angeles,  CA  90039. 

403  W.  Main  St.,  Amsterdam,  NY  12010. 

Birmingham,  NJ  08011. 

220  E.  17th  St.,  Chicago  Heights,  IL  60411. 

P.O.  Box  546,  Nitro,  WV  25143. 

Rock  Hill,  SC  29730. 

52-20  37th  St.,  Long  Island  City,  NY  11101. 

Main  St.,  Rogers,  CT  06263. 

222  W.  Washington  Sq.,  Philadelphia,  PA  19105. 


DIRECTORY  OF  MANUFACTURERS 
TABLE  22.  —  Synthetic  organic  chemicals.-  Directory  of  manufacturers ,  1965—  Continued 


207 


Name  of  company 


Roma  Chemical  Corp 

Rosenberg  Bros.  &  Co 

Rowland  Products,  Inc 

Royce  Chemical  Co 

Rozilda  Laboratories,  Inc 

Ruberoid  Co 

St.  Regis  Paper  Co.,  Lake  States  Yeast  & 
Chemical  Div. 

Salsbury  Laboratories 

Sandoz,  Inc 

Dyestuff  Div.,  Pigment  Dept 

Sartomer  Resins,  Inc 

Schaefer  Varnish  Co.,  Inc 

Schenectady  Chemicals,  Inc 

Scher  Bros.,  Inc 

R.  P.  Scherer  Corp 

Schering  Corp 

Scholler  Bros.,  Inc 

Seaboard  Chemicals,  Inc 

G.  D.  Searle  &   Co 

Seidlitz  Paint  &  Varnish  Co 

Sekisui  Plastics  Corp 

Selney  Co.,  Inc 

Seydel-Woolley  &  Co.,  Inc 

Shamrock  Oil  &  Gas  Corp 

Shanco  Plastics  &   Chemicals,  Inc 

Shell  Oil  Co 

Shell  Chemical  Co.  Div 

Shepherd  Chemical  Co 

Sherwin-Williams  Co 

Shulton,  Inc 

George  F.  Siddall  Co.,  Inc 

Signal  Oil  &  Gas  Co.,  Houston  Div 

Simpson  Timber  Co 

Sinclair  Koppers  Chemical  Co 

Sinclair-Koppers  Co 

Sinclair  Paint  Co 

Sinclair  Petrochemicals,  Inc 

Sinclair  Refining  Co 

James  B.  Sipe  &  Co 

Skelly  Oil  Co 

G.  Frederick  Smith  Chemical  Co 

Smith,  Kline  &  French  Laboratories 

Socony  Mobil  Oil  Co.,  Inc.: 

Mobil  Chemical  Co.  Div 

Mobil  Oil  Co.  Div 

Sohio  Chemical  Co.  &  Solar  Nitrogen  Chemicals, 

Inc. 

Solar  Chemical  Corp 

Soluol  Chemical  Co.,  Inc 

Solvent  Chemical  Co.,  Inc 

Sonford  Chemical  Co 

Sonoco  Products  Co 

Souhegan  Wood  Products,  Inc 

Sou-Tex  Chemical  Co.,  Inc 

Southeastern  Mhesives  Co 

Southeast  Polymers,  Inc 

Southern  Nitrogen  Co,,  Inc 

Southern  Sizing  Co 

Spaulding  Fibre  Co.,  Inc 

E.  R.  Squibb  &  Sons  Div.  of  Olin  Mathieson 

Chemical  Corp. 
A.  E.  Staley  Manufacturing  Co 

UBS  Chemical  Co.  Div 

Stamford  Chemical  Co 

Standard  Brands,  Inc.,  Clinton  Corn  Processing 

Co.  Div. 

Standard  Chemical  Products,  Inc 

Standard  Chlorine  Chemical  Co.,  Inc 

Standard  Oil  Co.  of  California,  Chevron 

Chemical  Co. 


Office  address 


900  Passaic  Ave.,  E.  Newark,  NJ  07029. 
100  Landing  Ave.,  Smithtown,  NY  11787. 
34  Fairview  Lane,  Kensington,  CT  06037. 
Carlton  Hill  P.O.,  E.  Rutherford,  NJ  07073. 
814  Madison  St.,  Hoboken,  NJ  07030. 
S.  Bound  Brook,  NJ  08880. 

603  W.  Davenport  St.,  Rhinelander,  WI  54501. 

500  Gilbert  St.,  Charles  City,  IA  50616. 

P.O.  Box  357,  Fair  Lawn,  NJ  07410. 

61-63  Van  Dam  St.,  New  York,  NY  10013. 

P.O.  Box  56,  Essington,  PA  19029. 

1350  S.  15th  St.,  Louisville,  KY  40210. 

Congress  St.  and  10th  Ave.,  Schenectady,  NY  12301. 

P.O.  Box  538,  Allwood  Station,  Clifton,  NJ  07012. 

9425  Grinnell  Ave.,  Detroit,  MI  48213. 

1011  Morris  Ave.,  Union,  NJ  07083. 

Collins  and  Westmoreland  Sts.,  Philadelphia,  PA  19134. 

30  Foster  St.,  Salem,  MA  01970. 

P.O.  Box  5110,  Chicago,  IL  60680. 

18th  and  Garfield  Sts.,  Kansas  City,  M0  64141. 

666  Dietrich  Ave.,  Hazelton,  PA  18201. 

65  9th  St.,  Bldg.  15,  Brooklyn,  NY  11215. 

748  Rice  St.  NW.,  Atlanta,  GA  30318. 

P.O.  Box  631,  Amarillo,  TX  79105. 

2716  Kenmore  Ave.,  Tonawanda,  NY  14150. 

113  W.  52d  St.,  New  York,  NY  10019. 

113  W.  52d  St.,  New  York,  NY  10019. 

2803  Highland  Ave.,  Cincinnati,  OH  45212. 

101  Prospect  Ave.  NW.,  Cleveland,  OH  44101. 

697  Route  46,  Clifton,  NJ  07015. 

P.O.  Box  925,  Spartanburg,  SC  29301. 

P.O.  Box  5008,  Harrisburg  Station,  Houston,  TX  77012. 

2301  N.  Columbia  Blvd.,  Portland,  OR  97217. 

P.O.  Box  5536,  Houston,  TX  77012. 

900  Koppers  Bldg.,  Pittsburgh,  PA  15219. 

3960  E.  Washington  Blvd.,  Los  Angeles,  CA  90023. 

600  5th  Ave.,  New  York,  NY  10020. 

600  5th  Ave.,  New  York,  NY  10020. 

P.O.  Box  8010,  Pittsburgh,  PA  15216. 

P.O.  Box  1650,  Tulsa,  OK  74102. 

867  McKinley  Ave . ,  Columbus ,  OH  43223 . 

1500  Spring  Garden  St.,  Philadelphia,  PA  19101. 

150  E.  42d  St.,  New  York,  NY  10017. 

612  S.  Flower  St.,  Los  Angeles,  CA  90054,  and  P.O. 

Box  3311,  Beaumont,  TX  77704. 
621  Republic  Bldg.,  Cleveland,  OH  44115. 

Solar  Park,  Leominster,  MA  01453. 

Green  Hill  and  Market  Sts.,  W.  Warwick,  RI  02893. 

341  Commercial  St.,  Maiden,  MA  02148. 

412  Main  St.,  Houston,  TX  77002. 

Harts ville,  SC  29550. 

Wilton,  NH  03086. 

E.  Catawba  Ave.,  Mount  Holly,  NC  28120. 

P.O.  Box  791,  Lenoir,  NC  28645. 

P.O.  Box  309,  Chattanooga,  TN  37401. 

P.O.  Box  246,  Savannah,  GA  31402. 

P.O.  Box  391,  East  Point,  GA  30044. 

310  Wheeler  St.,  Tonawanda,  NY  14150. 

745  5th  Ave.,  New  York,  NY  10022. 

N.  22d  and  Eldorado  Sts.,  Decatur,  IL  62525. 

491  Main  St.,  Cambridge,  MA  02142. 

45  Jefferson  St.,  P.O.  Box  1131,  Stamford,  CT  06940. 

1251  Beaver  Channel  Parkway,  Clinton,  IA  52733. 

1301  Jefferson  St.,  Hoboken,  NJ  07030. 
1015  Belleville  Turnpike,  Kearny,  NJ  07032. 
200  Bush  St.,  San  Francisco,  CA  94120. 


208  SYNTHETIC  ORGANIC  CHEMICALS,  1965 

TABLE  22. — Synthetic  organic  chemicals .-  Directory  of  manufacturers ,  1 965 --Continued 


Name  of  company 


Standard  Oil  Co.  of  Ohio 

Standard  Pyroxoloid  Corp 

Stange  Co 

Stauf f er  Chemical  Co . : 

Calhio  Chemicals  Div 

Industrial  Chemical  Div 

Specialty  Chemical  Div 

Stein,  Hall  &  Co.,  Inc 

Stepan  Chemical  Co.: 

Industrial  Chemicals  Div. ,  Millsdale  Works— 

Maywood  Div 

Sterling  Drug,  Inc.: 

Glenbrook  Laboratories  Div 

Hilton-Davis  Chemical  Co.  Div 

Salvo  Chemical  Div 

Thomasset  Colors  Div 

Winthrop  Laboratories  Div 

Stresen-Reuter,  Inc 

Sucro-Chemical  Div.  of  Colonial  Sugars  Co 

Sullivan  Varnish  Co 

Summit  Chemical  Products  Corp 

Sun  Chemical  Corp.,  Chemical  Products  Div 

Sun  Chemical  Corp-,  Pigments  Div 

Sunkist  Growers,  Inc ' — 

Sun  Oil  Co 

SunOlin  Chemical  Co 

Sunray  DX  Oil  Co 

Suntide  Refining  Co 

Swift  &  Co 

Synco  Resins,  Inc 

Syntex  Corp.,  Arapahoe  Chemicals  Div 

Synthetic  Chemicals,  Inc 

Synthetic  Products  Co 

Synthron,  Inc 

Synvar  Corp 

Tanatex  Chemical  Corp 

Charles  S.  Tanner  Co 

Taylor  Corp 

Tennant  Development  Corp.,  Chemical  Div 

Tenneco  Chemicals,  Inc 

Berkshire  Color  Div 

Cal/Ink  Div 

Newport  Div 

Nixon-Baldwin  Div 

Nuodex  Div 

Tenneco  Manufacturing  Co 

Tenneco  Plastics  Div 

Tenneco  Oil  Co 

Tennessee  Copper  Co 

Texaco,  Inc • 

Texas  Alkyls,  Inc 

Texas-U.S.  Chemical  Co 

Tex  Chem  Co 

Texize  Chemicals,  Inc 

Textilana  Corp 

Thiokol  Chemical  Corp 

Thomason  Industries,  Inc.,  Southern  Resin  Div 

Thompson  Chemical  Co 

Thompson-Hayward  Chemical  Co -- 

Ticonderoga  Chemical  Corp 

Tidewater  Oil  Co 

Toms  River  Chemical  Corp 

Tousey  Varnish  Co 

Trancoa  Chemical  Corp 

Arthur  C.  Trask  Co 

Triangle  Chemical  Co 

Trojan  Powder  Co 

Troy  Chemical  Co 

Trylon  Chemical  Corp 

Joseph  Turner  &  Co 


Office  address 


Midland  Bldg.,  Cleveland,  OH  44115. 
85  Pleasant  St.,  Leominster,  MA  01453. 
342  N.  Western  Ave.,  Chicago,  IL  60612. 

380  Madison  Ave.,  New  York,  NY  10017. 
380  Madison  Ave.,  New  York,  NY  10017. 
380  Madison  Ave.,  New  York,  NY  10017. 
605  3d  Ave.,  New  York,  NY  10016. 


Elwood,  IL  60421. 
100  W.  Hunter  Ave. 


Maywood,  NJ  07607. 


90  Park  Ave.,  New  York,  NY  10016. 

2235  Langdon  Farm  Rd.,  Cincinnati,  OH  45237. 

Military  Rd.,  Rothschild,  WI  54474. 

120  Lister  Ave.,  Newark,  NJ  07105. 

90  Park  Ave.,  New  York,  NY  10016. 

400  W.  Roosevelt  Ave.,  Bensenville,  IL  60106. 

P.O.  Drawer  G,  Gramercy,  LA  70052. 

410  N.  Hart  St.,  Chicago,  IL  60622. 

11  William  St.,  Belleville,  NJ  07109. 

Wood  River  Junction,  RI  02894. 

441  Tompkins  Ave.,  Staten  Island,  NY  10305. 

720  E.  Sunkist  St.,  Ontario,  CA  91764. 

1608  Walnut  St.,  Philadelphia,  PA  19103. 

P.O.  Box  F,  Claymont,  DE  19703. 

P.O.  Box  2039,  Tulsa,  OK  74102. 

P.O.  Box  2608,  Corpus  Christi,  TX  78403. 

115  W.  Jackson  Blvd.,  Chicago,  IL  60604. 

32  Henry  St.,  Bethel,  CT  06801. 

2855  Walnut  St.,  Boulder,  CO  80301. 

335  McLean  Blvd.,  Paterson,  NJ  07504. 

1636  Wayside  Rd.,  Cleveland,  OH  44112. 

Ryan  Ave.,  Ashton,  RI  02805. 

726  King  St.,  Wilmington,  DE  19801. 

P.O.  Box  388,  Lyndhurst,  NJ  07071. 

450  Furman  Hall  Rd.,  Greensville,  SC  29608. 

Valley  Forge,  PA  19481. 

100  Park  Ave.,  New  York,  NY  10017. 

300  E.  42d  St.,  New  York,  NY  10017. 

12th  and  Bern  Sts.,  Reading,  PA  19604. 

711  Camelia  St.,  Berkeley,  CA  94710. 

P.O.  Box  911,  Pensacola,  FA  32502. 

Nixon,  NJ  08818. 

1  Virginia  St.,  Newark,  NJ  07207. 

P.O.  Box  2511,  Houston,  TX  77001. 

P.O.  Box  38,  East  Brunswick,  NJ  08816. 

P.O.  Box  2511,  Houston,  TX  77001. 

Copperhill,  TN  37317. 

P.O.  Box  52332,  Houston,  TX  77052. 

P.O.  Box  600,  Deer  Park,  TX  77536. 

P.O.  Box  667,  Port  Neches,  TX  77651. 

20-21  Wagaraw  Rd.,  Fair  Lawn,  NJ  07410. 

P.O.  Box  368,  Greenville,  SC  29602. 

12607  Cerise  Ave.,  Hawthorne,  CA  90250. 

P.O.  Box  27,  Bristol,  PA  19007. 

P.O.  Drawer  1600,  Fayetteville,  NC  28301. 

90  Mendor  Ave.,  Pawtucket,  RI  02862. 

5200  Speaker  Rd.,  Kansas  City,  KA  66106. 

Marguerite  Ave.,  Leominster,  MA  01453. 

Delaware  City,  DE  19706. 

Route  37,  P.O.  Box  71,  Toms  River,  NJ  08753. 

135  W.  Lake  St.,  North  Lake,  IL  60164. 

312-326  Ash  St.,  Reading,  MA  01867. 

327  S.  LaSalle  St.,  Chicago,  IL  60604. 

206  Lower  Elm  St.,  P.O.  Box  4528,  Macon,  GA  31208. 

17  N.  7th  St.,  Allentown,  PA  18105. 

338  Wilson  Ave.,  Newark,  NJ  07105. 

P.O.  Box  5101,  Station  B,  Greenville,  SC  29606. 

P.O.  Box  88,  Ridgefield,  NJ  07451. 


DIRECTORY  OF  MANUFACTURERS 
TABLE  22. -Synthetic  organic  chemicals.-  Directory  of  manufacturers ,  1965— Continued 


209 


Name  of  company 


Office  address 


USS  Chemicals  Div.  of  U.S.  Steel  Corp 

Paul  Uhlich  &  Co.,  Inc 

Ungerer  &  Co 

Union  Bag-Camp  Paper  Corp.,  Nelio  Chemical  Div-- 
Union  Carbide  Corp.: 

Chemicals  Div 

Plastics  Div 

Silicones  Div 

Union  Oil  Co.  of  California 

Union  Starch  &  Refining  Co.,  Inc 

United  Carbon  Co 

United  Chemical  Corp.  of  Norwood 

United  Chemical  Products  Corp 

United  Cork  Companies 

United  Oil  Manufacturing  Co 

U.S.  Borax  Research  Corp 

U.S.  Oil  Co 

U.S.  Peroxygen  Corp 

United  States  Pipe  &  Foundry  Co 

U.S.  Plastic  &  Chemical  Corp 

United  States  Plywood  Corp.,  California  Div., 
Shasta  Operations. 

United  States  Rubber  Co.,  Chemical  Div 

Universal  Chemicals  Corp 

Universal  Detergents,  Inc.  &  Petrochemicals  Co-- 

Universal  Oil  Products  Co 

Chemical  Div 

Upjohn  Co 

Carwin  Organic  Chemicals 

Utah  Resin  Co.,  Inc 


Valchem 

Valentine  Sugars,  Inc.,  Valite  Div- 

Van  De  Mark  Chemical  Co 

Vanderbilt  Chemical  Corp 

Van  Dyk  &  Co.,  Inc 

Varney  Chemical  Corp 

Velsicol  Chemical  Corp 


Ventron  Corp.,  Metal  Hydrides  Div 

Vermi lye-Bell 

Verona-Pharma  Chemical  Corp 

Vickers  Refining  Co.,  Inc 

Vineland  Chemical  Co 

Virginia  Chemicals,  Inc 

Vistron  Corp.,  Silmar  Div 

Vitamins,  Inc 

Vita-Var  Corp.,  Div.  of  Textron  Industries,  Inc- 
Vulcan  Materials  Co.,  Frontier  Chemical  Co.  Div- 

Wallace  &  Tiernan,  Inc.: 

Harchem  Div 

Lucidol  Div 

Warner-Jenkinson  Manufacturing  Co 

Washburn-Purex  Co 

Washine  Chemical  Corp 

West  Coast  Adhesives  Co 

Westinghouse  Electric  Corp.,  Insulating 

Materials  Div. 

Weston  Chemical  Corp 

West  Virginia  Pulp  &  Paper  Co.,  Polychemicals 

Div. 

Weyerhaeuser  Co.,  Wood  Products  Div 

White  &  Bagley  Co 

White  &  Hodges,  Inc 

White  Laboratories,  Inc 

Whitmoyer  Laboratories,  Inc 

Whittemore -Wright  Co.,  Inc 

Wica  Chemicals,  Inc 

Wilmot  &  Cassidy,  Inc 


Rm.  2104,  Grant  Bldg.,  Pittsburgh,  PA  15219. 
90  West  St.,  New  York,  NY  10006. 
161  Avenue  of  the  Americas,  New  York,  NY  10013. 
P.O.  Box  6170,  Jacksonville,  FA  32205. 

270  Park  Ave.,  New  York,  NY  10017. 

270  Park  Ave . ,  New  York,  NY  10017. 

270  Park  Ave.,  New  York,  NY  10017. 

461  S.  Boylston  St.,  Los  Angeles,  CA  90017. 

301  Washington  St.,  Columbus,  IK  47201. 

P.O.  Box  149,  Baytown,  TX  77520. 

P.O.  Box  327,  Endicott  St.,  Norwood,  MA  02062. 

York  and  Colgate  Sts . ,  Jersey  City,  NJ  07302 . 

50  Central  Ave.,  Kearny,  NJ  07032. 

2d  and  Cascade  Sts.,  Erie,  PA  16512. 

3075  Wilshire  Blvd.,  Los  Angeles,  CA  90005. 

P.O.  Box  4228,  E.  Providence,  RI  02914. 

850  Morton  Ave.,  Richmond,  CA  94804. 

3300  1st  Ave.  N.,  Birmingham,  AL  35202. 

122  E.  Railroad  Ave.,  W.  Haverstraw,  NY  10993. 

P.O.  Box  1688,  Redding,  CA  96002. 

Naugatuck,  CT  06771. 

1224  Mundon  Rd.,  P.O.  Box  1224,  Ashtos,  RI  02865. 

1825  E.  Spring  St.,  Long  Beach,  CA  90806. 

30  Algonquin  Rd.,  Des  Plaines,  IL  60018. 

State  Highway  17,  E.  Rutherford,  NJ  07073. 

7000  Portage  Rd.,  Kalamazoo,  MI  49001. 

Sackett  Point  Rd.,  North  Haven,  CT  06473. 

604-605  Kearns  Bldg.,  Salt  Lake  City,  UT  84101. 

1407  Broadway,  New  York,  NY  10018. 

726  Whitney  Bldg.,  New  Orleans,  LA  70130. 

N.  Transit  Rd.,  Lockport,  NY  14094. 

33  Winfield  St.,  E.  Norwalk,  CT  06855. 

11  William  St.,  Belleville,  NJ  07109. 

2001  Afton  Rd.,  Janesville,  WI  53545. 

330  E.  Ohio  St.,  Chicago,  IL  60611  and  4902  Central  Ave. 

Chattanooga,  TN  37410. 
12-24  Congress  St.,  Beverly,  MA  01915. 
21707  Bothell  Way,  Bothell,  WA  98011. 
P.O.  Box  385,  Union,  NJ  07083. 
P.O.  Box  2240,  Wichita,  KS  67201. 
W.  Wheat  Rd.,  Vineland,  NJ  08360. 
West  Norfolk,  VA  23703. 

12335  S.  Van  Ness  Ave.,  Hawthorne,  CA  90250. 
809  W.  58th  St.,  Chicago,  IL  60621. 
177  Oakwood  Ave.,  Orange,  NJ  07050. 
P.O.  Box  545,  Wichita,  KS  67201. 


25  Main  St.,  Belleville,  NJ  07109. 
1740  Military  Rd.,  Buffalo,  NY  14240. 
2526  Baldwin  St.,  St.  Louis,  113  63106. 
2244  Elston  Ave.,  Chicago,  IL  60614. 
165  Main  St.,  Lodi,  NJ  07644. 
11104  NW.  Front  Ave.,  Portland,  OR  97231. 
Trafford,  PA  15085. 

104  E.  40th  St.,  Suite  107,  New  York,  NY  10016. 
P.O.  Box  5207,  N.  Charleston,  SC  29406. 

118  S.  Palmetto  St.,  MarshfieM,  WI  54449. 
P.O.  Box  1171,  Worcester,  MA  01601. 
576  Lawrence  St.,  Lowell,  MA  01852. 
Galloping  Hill  Rd.,  Kenilworth,  NJ  07033. 
P.O.  Box  97,  Myerstown,  PA  17067. 
62  Alford  St.,  Boston,  MA  02129. 
P.O.  Box  506,  Charlotte,  NC  28201. 
108  Provost  St.,  Brooklyn,  NY  11222. 


210  SYNTHETIC  ORGANIC  CHEMICALS,  1965 

TABLE  22. — Synthetic  organic  chemicals:  Directory  of  manufacturers ,  1965 — Continued 


Code 

Name  of  company 

Office  address 

WIL 

WM 

BLA 

WTC 

SON 

WCC 

WAW 

WOD 

WRC 

WON 

WBC 

WYN 

YAW 

Wilson  &  Co.,  Inc. : 

4-221  S.  Western  Blvd.,  Chicago,  IL  60609. 

Snyder  Ave.  and  Swanson  St.,  Philadelphia,  PA  19148. 

5050  Edgewood  Ct.,  P.O.  Box  B,  Jacksonville,  FA  52203. 

P.O.  Box  305,  Paramus,  NJ  07652. 

277  Park  Ave.,  New  York,  NY  10017. 

555  S.  Flower  St.,  Los  Angeles,  CA  90017. 

108  Spring  St.,  Everett,  MA  02149. 

P.O.  Box  3545,  Eugene,  OR  97402. 

Park  PI.  E.,  Wood  Ridge,  NJ  07075. 

176  Sunnyside  Ave.,  Woonsocket,  RI  02895. 

Route  9,  Freehold,  NJ  07728. 

1609  Biddle  Ave.,  Wyandotte,  MI  48192. 

2731  Boston  St.,  Baltimore,  MD  21224. 

Witco  Chemical  Co.,  Inc 

w.^°nn^,°™  j 

W.  A.  Wood  Co 

00   .^naCp,S;'.  n° 

Woonsocket  Color  &  Chemical  Co 

or  i^g  °n  1°c   emica   orp 

Young  Aniline  Works,  Inc 

APPENDIX 

U.S.  Imports  of  Benzenoid  Intermediates 
and  Finished  Benzenoid  Products 

Table  23  summarizes,  for  1964  and  1965,  U.S.  imports  of  benzenoid  chemicals  and  products 
entered  under  the  Tariff  Schedules  of  the  United  States  (TSUS),  schedule  4,  part  1,  subparts  B 
and  C.  The  data,  which  were  obtained  by  analyzing  invoices  covering  imports  through  all  U.S. 
customs  districts,  are  given  in  detail  in  a  separate  report  of  the  Tariff  Commission.1 

In  1965,  general  imports  of  benzenoid  intermediates  entered  under  schedule  4,  part  IB, 
comprised  642  items  with  a  total  weight  of  38.0  million  pounds  and  an  invoice  value  of  $19.5 
million.  In  1964,  imports  consisted  of  651  items  with  a  total  weight  of  18.8  million  pounds  and 
an  invoice  value  of  $14.4  million.  About  half  of  the  benzenoid  chemicals  and  products  imported 
in  1965  were  declared  to  be  "competitive"  (duty  based  on  "American  selling  price").  In  1965, 
imports  of  these  products  from  Canada  amounted  to  34  percent  of  the  total;  imports  from  that 
country  amounted  to  13  million  pounds,  compared  with  2.0  million  pounds  in  1964.  In  1965,  im- 
ports from  Italy  amounted  to  8.1  million  pounds,  compared  with  1.6  million  pounds  in  1964.  Im- 
ports from  West  Germany  amounted  to  7.2  million  pounds,  compared  with  7.6  million  pounds  in 
1964.  Imports  from  Japan  totaled  3.3  million  pounds  in  1965,  compared  with  2.2  million  pounds 
in  1964;  and  imports  from  the  United  Kingdom  amounted  to  2.2  million  pounds  in  both  1965  and 
1964.  In  1965,  sizable  quantities  of  intermediates  were  also  imported  from  Switzerland  (1.6  mil- 
lion pounds),  France  (1.2  million  pounds),  and  Sweden  (0.8  million  pounds). 

TABLE  23. — Benzenoid  intermediates  and  finished  benzenoid  products ;  U.S.  general  imports, 

classified  by  use,  1964  and  1965 


Quantity 


Invoice 
value 


Invoice 

value 


Intermediates1 

Finished  benzenoid  products,  total 

Dyes,  total 

Acid 

Azoic  dyes 

Azoic  components: 

Fast  color  bases 

Fast  color  salts 

Naphthol  AS  and  its  derivatives- 
Basic 

Direct 

Disperse 

Fiber-reactive 

Fluorescent  brightening  agents 

Mordant 

Solvent ■. 

Sulfur 

Vat 

All  other 

Benzenoid  pigments  (toners  and  lakes) 

Medicinals  and  pharmaceuticals 

Flavor  and  perfume  materials 

All  other 


1,000 
pounds 
18,789 

23,682 


10,096 

2,093 

14 

311 

113 

901 

1,018 

1,015 

900 

416 

151 

292 

128 

11 


1.000 
dollars 
14,410 

34,670 


16,261 


1,000 
pounds 
37,975 

31,941 


2,713 
2  20 
684 
3,127 
1,613 
8,162 


1,128 
9,764 
2,311 
5,206 


12,276 

1,808 

22 

416 

185 

1,093 

1,227 

931 

1,880 

652 

229 

221 

168 

37 

3,374 

2   33 

797 

3,408 

1,908 

13,552 


1,000 
dollars 

19,483 

45,425 


20,505 


1,510 

12,551 

2,522 

8,337 


1  Includes  small  quantities  of  rubber-processing  chemicals. 

2  Includes  ingrain  dyes. 

3  Includes  organic  pesticides  and  agricultural  chemicals,  plasticizers,   surface -active  agents,   and  textile 
assistants. 

Source:     Compiled  from  the  records  of  the  U.S.   Bureau  of  Customs. 


1  Imports  of  Benzenoid  Chemicals  and  Products,  1965,  TC  Publication  183,  1966  [processed]. 


211 


212  SYNTHETIC  ORGANIC  CHEMICALS,  1965 

The  most  important  intermediates  imported  in  1965  were  adipic  acid,    polyalkylbenzene, 
p-nitrotoluene,    3-hydroxy- 2-naphthoic  acid  (B.  O.  N.  )>    cyclohexanone,    acetoacetanilide,    Gamma 
acid,    anthraquinone,    2-(morpholinothio)benzothiazole,    and  sodium  naphthionate.    In  1965,    imports 
of  adipic  acid  amounted  to  13.  7  million  pounds,    compared  with  1.  9  million  pounds  in  1964,    and 
came  almost  entirely  from  Canada.    Imports  of  polyalkylbenzene   in    1965   totaled  6.  1  million 
pounds,    compared  with  725,000  pounds  in  1964,    and  all  came  from  Italy.   In  1965,    imports  of 
p-nitrotoluene,   which  came  principally  from  Sweden  and  Germany,    totaled  922,  000  pounds;  im- 
ports of  B.O.N. ,   which  came  from  Italy,    West  Germany,    and  Japan,   totaled  873,000  pounds; 
imports  of  cyclohexanone  (699,  000  pounds)  all  came  from  Italy;  imports  of  acetoacetanilide 
(679,  000  pounds)  came  principally  from  Switzerland;  imports  of  Gamma  acid  (595,  000  pounds) 
came  from  Japan,    West  Germany,    and  Italy;  imports  of  anthraquinone  (468,000  pounds)  came 
from  the  United  Kingdom,   Japan,    and  West  Germany;  imports  of  2-(morpholinothio)benzothiazole 
(415,  000  pounds)  all  came  from  the  United  Kingdom;  and  imports  of  sodium  naphthionate  (326,  000 
pounds)  all  came  from  Japan. 

Imports  in  1965  of  all  finished  benzenoid  chemicals  and  products  that  are  dutiable  under 
part  1C  comprised  Z,  223  items,   with  a  total  weight  of  31.9  million  pounds  and  an  invoice  value 
of  $45.4  million.   In  1964,   imports  consisted  of  2,  292  items,   with  a  total  weight  of  23.  7  million 
pounds  and  an  invoice  value  of  $34.  7  million.    In  1965,    benzenoid  dyes  were  the  most  important 
group  of  finished  benzenoid  products  imported.    Imports  of  dyes  amounted  to  $20.  5  million 
(invoice  value),   or  45.2  percent  of  the  value  of  all  imports  under  part  1C.  In  1964,   imports  of 
dyes  amounted  to  $16.  3  million  (invoice  value),    or  47.  0  percent  of  the  value  of  all  imports  under 
part  1C. 

Imports  of  medicinals  and  pharmaceuticals  were  the  next  most  important  group  of  products 
entered  under  part  1C  in  1965.   In  1965,   imports  of  medicinals  and  pharmaceuticals  were  valued 
at  $12.  6  million  (invoice  value),    or  27.  8  percent  of  total  imports  under  part  1C.   In  1964,    imports 
of  medicinals  and  pharmaceuticals  were  valued  at  $9.  8  million,  or  28.  2  percent  of  total  imports 
under  part  1C.   In  1965,   imports  of  benzenoid  pigments  (toners  and  lakes)  were  valued  at  $1.  5 
million,    compared  with  $1.  1  million  in  1964.   Imports  of  benzenoid  flavor  and  perfume  materials 
in  1965  ($2.  5  million)  we re  8  percent  more  than  in  1964.   Imports  in  1965  of  other  benzenoid 
products  entered  under  part  1C  (chiefly  synthetic  resins  and  pesticides)  were  valued  at  $8.  3 
million,    compared  with  $5.  2  million  in  1964. 


REPORTS  OF  THE  UNITED  STATES  TARIFF  COMMISSION  ON  THE  OPERATION  OF  THE 
TRADE  AGREEMENTS  PROGRAM 

*Operation  of  the  Trade  Agreements  Program,  June  1934  to  April  1948  (Rept.  No.  160,  2d  ser.,  1949) : 
Part  I.       Summary 

Part  II.     History  of  the  Trade  Agreements  Program 
Part  III.  Trade-Agreement  Concessions  Granted  by  the  United  States 
Part  IV.    Trade- Agreement  Concessions  Obtained  by  the  United  States 
Part  V.      Effects  of  the  Trade  Agreements  Program  on  United  States  Trade 

*Operation  of  the  Trade  Agreements  Program :  Second  Report,  April  1948-March  1949  (Rept.  No. 

163,  2d  ser.,  1950) 

*Operation  of  the  Trade  Agreements  Program :  Third  Report,  April  1949-June  1950  (Rept.  No.  172, 

2d  ser.,  1951) 
*Operation  of  the  Trade  Agreements  Program :  Fourth  Report,  July  1950-June  1951  (Rept.  No.  174, 

2d  ser.,  1952) 
*Operation  of  the  Trade  Agreements  Program:  Fifth  Report,  July  1951-June  1952  (Rept.  No.  191, 

2d  ser.,  1954) 
*Operation  of  the  Trade  Agreements  Program:  Sixth  Report,  July  1952- June  1953  (Rept.  No.  193, 

2d  ser.,  1954) 
*Operation  of  the  Trade  Agreements  Program :  Seventh  Report,  July  1953- June  1954  (Rept.  No.  195, 

2d  ser.,  1955) 
*Operation  of  the  Trade  Agreements  Program:  Eighth  Report,  July  1954-June  1955  (Rept.  No.  197, 

2d  ser.,  1956) 
*Operation  of  the  Trade  Agreements  Program :  Ninth  Report,  July  1955-June  1956  (Rept.  No.  199, 

2d  ser.,  1957) 
♦Operation  of  the  Trade  Agreements  Program:  10th  Report,  July  1956-June  1957  (Rept.  No.  202, 

2d  ser.,  1959) 
♦Operation  of  the  Trade  Agreements  Program:  11th  Report,  July  1957- June  1958  (Rept.  No.  204, 

2d  ser.,  1959) 
♦Operation  of  the  Trade  Agreements  Program :  12th  Report,  July  1958-June  1959  (TC  Publication 

9,  1961) 
♦Operation  of  the  Trade  Agreements  Program :  13th  Report,  July  1959-June  1960  (TC  Publication 

51,  1962) 
Operation  of  the  Trade  Agreements  Program:  14th  Report,  July  1960-June  1962  (TC  Publication 

120,  1964),  350 
Operation  of  the  Trade  Agreements  Program :  15th  Report,  July  1962-June  1963  (TC  Publication 

147,  1965),  350 
Operation  of  the  Trade  Agreements  Program :  16th  Report,  July  1963-June  1964  (TC  Publication 

164,  1966),  300 

NOTE.— The  reports  preceded  by  an  asterisk  (*)  are  out  of  print.  Those  followed  by  a  price  may  be  purchased  from 
the  Superintendent  of  Documents,  U.S.  Government  Printing  Office,  Washington,  D.C.  20402.  See  inside  front 
cover  for  additional  reports.  All  U.S.  Tariff  Commission  reports  reproduced  by  the  Government  Printing  Office 
may  be  consulted  in  the  official  depository  libraries  throughout  the  United  States. 


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