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BOSTON 

PUBLIC 

LffiRARY 


2>i  : 

?^      UNITED      STATES      TARIFF      COMMISSION 

SYNTHETIC 
ORGANIC      CHEMICALS 


United  States  Production 
and  Sales,  1966 

TC  Publication  248 


Fiftieth  Annual  Edition 


RECENT  REPORTS  OF  THE  UNITED   STATES  TARIFF  COMMISSION  ON 
SYNTHETIC    ORGANIC   CHEMICALS 


Synthetic  Organic  Chemicals,  United  States  Production  and  Sales,  1961  (TC  Publication  72,  1962), 

$1.25 
Synthetic  Organic  Chemicals,  United   States  Production  and  Sales,  1962  (TC  Publication  114, 

1963),  $1.50 
Synthetic  Organic  Chemicals,  United  States  Production  and  Sales,  1963  (TC  Publication  143, 

1964),  $1.50 
Synthetic  Organic  Chemicals,  United  States  Production  and  Sales,  1964  (TC  Publication  167, 

1965),  $1.25 
Synthetic  Organic  Chemicals,  United  States  Production  and  Sales,  1965  (TC  Publication  206), 

$1.00 


NOTE.— The  reports  listed  above  may  be  purchased  from  the  Superintendent  of  Documents,  U.S.  Government 
Printing  Oflice,  Washington,  D.C.  20402.  See  inside  back  cover  for  additional  reports.  All  U.S.  Tariff  Commission 
reports  reproduced  by  the  Government  Printing  Office  may  be  consulted  in  the  official  depository  libraries  through- 
out the  United  States. 


UNITED  STATES  TARIFF  COMMISSION 


SYNTHETIC 
ORGANIC   CHEMICALS 

United  States  Production 
and  Sales,  1966 


UNDER  THE  PROVISIONS  OF 
SECTION  332  OF  THE  TARIFF 
ACT  OF  1930,  AS  AMENDED 


U.S.  GOVERNMENT  PRINTING  OFFICE 
WASHINGTON  :  1968 


TC  PubUcation  248 


UNITED  STATES  TARIFF  COMMISSION 

Stanley  S.  Metzger,  Chairman 
Glenn  W.  Sutton,  Vice  Chairman 
James  W.  Culliton 
Penelope  H.  Thunberg 
Bruce  E.  Clubb 

DoNN  N.  Bent,  Secretary 


Address    all   communications 

UNITED  STATES  TARIFF  COMMISSION 

Washington,  D.C.     20436 


For  sale  by  the  Superintendent  of  Documents,  U.S.  Government  Printing  Office 
Washington,  D.C.  20402  -  Price  $1.50 


CONTENTS 

Page 

Intr  oduc  tion v 

Summary vii 

PART  I.       PRODUCTION  AND  SALES  OF  TARS,    TAR  CRUDES,   AND  CRUDES 
DERIVED  FROM  PETROLEUM  AND  NATURAL  GAS 

Tars -.- 1 

Tar  crudes 1 

Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion 4 

PART  II.       PRODUCTION  AND  SALES  OF  INTERMEDIATES  AND  FINISHED 
SYNTHETIC  ORGANIC  CHEMICALS,    BY  GROUPS 

General  7 

Cyclic  intermediates 10 

Dyes 15 

Pigments 26 

Medicinal  chemicals 31 

Flavor  and  perfume  materials 36 

Plastics  and  resin  materials    38 

Rubber -processing  chemicals 42 

Elastomers  (synthetic  rubbers) 44 

Plasticizers 45 

Surface-active  agents 47 

Pesticides  and  related  products 53 

Miscellaneous  chemicals 55 

PART  III.       ALPHABETICAL  LIST  OF  INDIVIDUAL  PRODUCTS,    BY  GROUPS, 
AND  NAMES  OF  MANUFACTURERS 

Tar  crudes 63 

Crude  products  from  petroletun  and  natural  gas  for  chemical  conversion 64 

Cyclic  intermediates 66 

Dyes - - -- - 92 

Pigments 113 

Medicinal  chemicals 117 

Flavor  and  perfume  materials 130 

Plastics  and  resin  materials 136 

Rubber -processing  chemicals 140 

Elastomers  (synthetic  rubbers) 143 

Plasticizers 144 

Surface -active  agents 147 

Pesticides  and  related  products 162 

Miscellaneous  chemicals 168 

Directory  of  manufacturers    193 

APPENDIX 

U.S.    imports  of  benzenoid  intermediates  and  finished  benzenoid  products 213 


Introduction 

This  is  the  fiftieth  annual  report  of  the  U.S.    Tariff  Commission  on  domestic  production  and 
sales  of  synthetic  organic  chemicals  and  the  raw  materials  from  which  they  are  made.    The 
report  presents  statistics  for  1966  on  crude  organic  chemicals  derived  from  coal,    natural  gas, 
and  petroleum;  on  intermediates;  and  on  finished  synthetic  organic  chemical  products.    The 
finished  products  are  grouped  according  to  their  principal  use--dyes,    synthetic  organic  pigments, 
medicinal  chemicals,    flavor  and  perfume  materials,    plastics  and  resin  materials,    rubber-proc- 
essing chemicals ,    elastomers,    plasticizers ,    surface-active    agents,    pesticides    and    related 
products,    and    miscellaneous    chemicals.    The    use    classifications    of   finished    synthetic    organic 
chemicals    are   based    principally   on   the   manufacturers'    annual    reports    to   the    Tariff   Commis- 
sion;   other    sources    include   trade   associations,    the    chemical   literature,     chemical  dictionaries, 
encyclopedias,     and    consultants    in  the    chemical    industry.    With   a   few    exceptions,    the    report 
does  not  cover  organic  chemicals   (such  as  wood -distillation  products,    essential  oils,    and  naval 
stores)   that    are    derived    from    natural    (vegetable)    sources    by    simple    extraction    or    distillation. 
The  Commission    has    compiled   the    statistics    given    in   this    report    from    information    supplied 
by  approximately  825  primary  manufacturers,    listed  in  part  III. 

The  first  section  of  the  report  includes  the  statistics  on  all  products  and  groups  of  products 
for  which  information  can  be  published.    The  second  section  lists  all  the  chemicals  and  chemical 
products  on  which  data  are  reported  and  identifies  the  manufacturers  of  each.    Each  reporting 
company  has  been  assigned  an  identification  symbol  consisting  of  a  combination  of  not  more  than 
three  capital  letters,    selected  in  most  instances  with  the  approval  of  the  manufacturer,    and 
usually  bearing  some  relationship  to  the  company  name.    The  identification  symbols  are  perma- 
nent and,    except  for  such  changes  as  may  be  necessary,    will  be  used  in  all  future  reports  in 
this  series.    This  report  includes  data  on  only  those  individual  chemicals  for  which  the  volume 
of  production  or  sales  in  the  year  covered  exceeded  1,000  pounds  or  for  which  the  value  of  sales 
exceeded  $1, 000. 

The  raw  materials  referred  to  in  this  report  are  obtained  from  coal,    crude  petroleum, 
natural  gas,    and  certain  other  natural  materials,    such  as  vegetable  oils,   fats,    rosin,    and  grains. 
Crude  organic  chemicals  are  derived  from  coal  by  thermal  decomposition,    from  petroleum  and 
natural  gas  by  catalytic  cracking  and  by  distillation  or  absorption,    and  from  other  natural 
sources  by  fermentation.    Production  of  these  crude  organic  chemicals  is  the  first  step  in  the 
manufacture  of  synthetic  organic  chemicals.    From  these  crudes,    intermediates  are  obtained  by 
synthesis  or  refining;  most  of  the  intermediates  are  then  converted  into  finished  chemical  prod- 
ucts,   such  as  medicinal  chemicals,    plastics  and  resin  materials,    and  dyes.    More  than  half  of 
the  total  production  of  intermediates   is  not  sold  directly  to  the  ultimate  consunner,    but  is  used 
by  the  producing  companies  themselves  in  their  manufacturing  processes.    The  statistics  given 
in  this  report  include  data  for  all  known  domestic  producers  of  the  items  covered. 

In  this  report  the  statistics  on  production  of  the  individual  chemicals  reported  by  manufac- 
turers include  the  total  output  of  the  companies'  plants,    i.  e.  ,    the  quantities  produced  for  con- 
sumption within  the  producing  plants,    as  well  as  the  quantities  produced  for  domestic  and  foreign 
sale.    The  quantities  reported  as  produced,   therefore,    generally  exceed  the  quantities  rep>orted 
as  sold.    Some  of  these  differences,    however,    are  attributable  to  changes  in  inventories.    As 
specified  in  the  reporting  instructions  that  the  Commission  sends  to  manufacturers,    and  as  used 
in  this  report,    production  and  sales  (unless  otherwise  specifically  indicated)  are  defined  as 
follows : 

Production  is  the  total  quantity  of  a  commodity  made  available  by  original  manufacture  only.  It 
is  the  sum  (expressed  in  terms  of  100-percent  active  ingredient  unless  otherwise  specified)  of 
the  quantities  of  a  commodity- - 

(1)  Produced,    separated,    and  consumed  in  the  same  plant  or  establishment  (a  commodity 

is  considered  to  be  separated  when  it  is  isolated  from  the  reaction  system  and/or 
when  it  is  weighed,    analyzed,    or  otherwise  measured).    Byproducts  and  coproducts 
not  classified  as  waste  materials  are  also  included; 

(2)  Produced  and  transferred  to  other  plants  or  establishments  of  the  same  firm; 

(3)  Produced  and  sold  to  other  firms  (including  production  for  others  under  toll  agree- 

ments   );  and 

(4)  Produced  and  held  in  stock. 


A  toll  agreement  is  an  agreement  between  two  firms,  under  which  one  firm  furnishes  the  raw  materials  and  pays  the  processing  costs 
and  the  other  firm  prepares  the  finished  product  and  returns  it  to  the  first  firm. 


VI  INTRODUCTION 

Production  excludes-- 

(1)  Purification  of  a  commodity  unless  specifically  requested  in  the  reporting  instructions; 

(2)  Intermediate  products  that  are  formed  in  the  manufacturing  process  but  are  not  isolated 

from  the  reaction  system- -that  is,    not  weighed,    analyzed,    or  otherwise  measured; 
and 

(3)  Materials  that  are  used  in  the  process  but  are  recovered  for  reuse  or  sale;  and  waste 

products  that  have  no  economic  significance. 

Sales  are  defined  as  actual  sales  of  commodities  by  original  manufacturers  only.   Sales  include-- 

(1)  Shipments  of  commodities  for  domestic  use  and  for  export,    or  segregation  in  a  ware- 

house when  title  has  passed  to  the  purchaser  in  a  bonafide  sale; 

(2)  Shipments  of  a  commodity  produced    by  others  under  toll  agreements;  and 

(3)  Shipments  to  subsidiary  or  affiliated  companies. 

Sales  exclude-- 

(1)  All  intracompany  transfers  within  a  corporate  entity; 

(2)  All  sales  of  purchased  commodities;  and 

(3)  All  shipments  of  a  commodity  produced   for  others    under  toll  agreements. 

The  value  of  a  sale  is  the  net  selling  price,   f.  o.  b.    plant  or  warehouse,    or  delivered  value, 
whichever  represents  the  normal  industry  practice. 

Data  on  the  chemicals  covered  inthis  report  are  usually  given  in  terms  of  undiluted  mate- 
rials.   Products  of  95  percent  or  more  purity  are  considered  to  be   100  percent  pure.    The  prin- 
cipal exceptions  are  the  statistics  on  dyes  and  a  few  solvents,    which  are  reported  in  terms  of 
commercial  concentrations,    and  the  statistics  on  certain  plastics  and  resins,   which  are  reported 
on  a  dry  basis.  The  report  specifically  notes  those  products  for  which  the  statistics  are  reported 
in  terms  of  commercial  concentrations. 

The  average  unit  values  of  sales  for  groups  of  products  shown  in  the  tables  accompanying 
this  report  are  the  averages  for  products  which  vary  widely  in  unit  values  and  in  the  quantities 
sold. 

In  this  report,    statistics  are  presented  in  as  great  detail  as  is  possible  without  revealing  the 
operations    of  individual    producers.    Statistics  for  an  individual  chemical  or  group  of  chemicals 
are  not  given  unless  there  are  three  or  more  producers  no  one  or  two  of  which  may  be  predomi- 
nant.   Moreover,    even  when  there  are  three  or  more  producers,    statistics  are  not  given  if  there 
is  any  possibility  that  their  publication  would  violate  the  statutory  provisions  relating  to  unlawful 
disclosure  of  information  accepted  in  confidence  by  the  Commission.  ^ 

Statistics  on  tars  and  tar  crudes  include  data  furnished  directly  to  the  Tariff  Commission  by 
distillers  of  coal  tar,  water-gas  tar,  and  oil-gas  tar,  and  data  furnished  to  the  Division  of  Bitu- 
minous Coal,    U.S.    Bureau  of  Mines ,   by  coke-oven  operators. 

Statistics  on  U.S.    general  imports  in  1966  of  benzenoid  intermediates  and  finished  benzenoid 
products  that    entered    under    schedule   4,    parts    IB    and    IC,     of  the    Tariff  Schedules    of  the 
United  States  are  given  in  the  appendix. 

Information  on  synonymous  names  of  organic  chemicals  included  in  this  report  may  be  found 
in  the  SOCMA  Handbook:    Commercial  Organic  Chemical  Names,   recently  published  by  the  Chemical  Abstracts 
Service  of  the  American  Chemical  Society,    or  the   Colour  Index  (2d  edition),    published  in  1956  by  the 
Society  of  Dyers  and  Colourists. 


Sec.  5,  U.S.C.  139b  and  sec.  18,  U.S.C,  1905. 


Summary 

Combined  production  of  all  synthetic  organic  chemicals,    tars,    tar  crudes,    and  crude  products 
from  petroleum  and  natural  gas  in  1966  was    169,  174  million  pounds--an  increase  of  11.6  percent 
over  the  output  in  1965  (see  table   1).    Sales  of  these  materials  in  1966,    which  totaled  90,  175  mil- 
lion pounds,    valued  at  $10,999  million,    were   12.4  percent  larger  than  in  1965  in  terms  of  quan- 
tity and   11.1   percent  larger  in  terms  of  value.    These  figures  include  data  on  production  and  sales 
of  chemicals  measured  at  several  successive  steps  in  the  manufacturing  process,    and  therefore 
they  necessarily  contain  some  duplication. 

In  1966,    production  of  all  synthetic  organic  chemicals,    including  cyclic  intermediates  and 
finished  chemical  products,    totaled   100,627  million  pounds,    or   13.2  percent  more  than  the  output 
in  1965  (see  table  1).    Production  of  plastics  and  resin  materials  (13,  585  million  pounds)  was   16.  3 
percent  larger  in  1966  than  in  1965;  that  of  medicinal  chemicals  (185  million  pounds)  was   16.  3 
percent  larger;  that  of  pesticides  and  related  products   (1,013  million  pounds)  was    15.  5  percent 
larger;  that  of  cyclic  intermediates  (19,467  million  pounds)  was   15.4  percent  larger;  and  that  of 
miscellaneous  organic  chemicals   (57,253  million  pounds)  was    12.  6  percent  larger. 

The  output  of  most  other  groups  of  synthetic  organic  chemicals  also  increased  in  1966  com- 
pared with  1965,   with  rubber-processing  chemicals  and  plasticizer  chemicals  showing  increases 
of  more  than  12  percent.    Production  of  surface-active  agents  (3,321  million  pounds)  showed  the 
smallest  percentage  gain  in  1966  over   1965  (4.  8  percent). 

1ABJ-.1!;  1.  — ^ymnettc  organic  chemicals  and  their  raw  materials :    U.S.  production  and  sales,  1965  and  1966 


decrease 

(-),  1966 
over 
1965^ 


decrease 
(-),  1966 

over 

1965^ 


Grand  total 

Tar 

Tar  crudes 

Crude  products  from  petroleum  and 
natural  gas 

Synthetic  organic  chemicals,  total 

Intermediates 

Dyes 

Synthetic  organic  pigments 

Medicinal  chemicals 

Flavor  and  perfume  materials 

Plastics  and  resin  materials 

Rubber-processing  chemicals 

Elastomers  (synthetic  rubbers) — 

Plasticizers 

Surface-active  agents 

Pesticides  and  related  products- 
Miscellaneous  chemicals 


8,027 
10,205 


8,019 
10,062 


3,662 
6,332 


16,865 

19,467 

207 

219 

48 

51 

160 

185 

99 

111 

11,685 

13,585 

252 

283 

3,592 

3,929 

1,073 

1,209 

3,170 

3,321 

877 

1,013 

50,836 

57,253 

129 

88 

10,053 

194 

3,041 

1,022 

1,698 

764 

22,040 


11,472 
209 
3,411 
1,156 
1,766 
822 
24,549 


17.2 
7.5 
13.9 


12.2 
13.1 
4.0 


13.6 
13.4 
14.9 
10.0 
9.0 


Percentages  calculated  from  figures  rounded  to  thousands. 
Because  of  rounding,  figures  may  not  add  to  the  totals  shown. 


PART  I.   PRODUCTION  AND  SALES  OF  TARS,  TAR  CRUDES,  AND 
CRUDES  DERIVED  FROM  PETROLEUM  AND  NATURAL  GAS 


Coal  tar  is   produced  chiefly  by  the  steel  industry 


byproduct  of  the  manufacture  of  coke 


water-gas  tar  and  oil-gas  tar  are  produced  by  the  fuel-gas  industry.    Production  of  coal  tar, 
therefore,    depends  on  the  demand  for  steel;  production  of  water-gas  tar  and  oil-gas  tar  reflects 
the  consumption  of  manufactured  gas  for  industrial  and  household  use.    Water-gas  and  oil-gas 
tars  have  properties  intermediate  between  those  of  petroleum  asphalts  and  coal  tars.    Petroleum 
asphalts  are  not  usually  considered  to  be  raw  materials  for  chemicals. 

The  quantity  of  tar  produced  from  coal  in  the  United  States  in  1966  was   802  million  gallons, 
or  0.  1  percent  less  than  the  803  million  gallons  produced  in  1965.    U.  S.    production  of  water-gas 
tar  and  oil-gas  tar  was  not  reported  to  the  Commission  for  1965  or  1966;  production  of  these  tars 
amounted  to   19  million  gallons   in  1962,    the  last  year  for  which  production  was   reported  to  the 
Tariff  Commission. 

Total  consumption  of  tar  in  1966  amounted  to  763  million  gallons,  of  which  605  million  gal- 
lons was  consumed  by  distillation,  132  million  gallons  as  fuel,  and  26  million  gallons  in  miscel- 
laneous uses. 


TABLE  2 Tar:    U.S.  production  and  consumption,  1965  and  1966 

[in  thousands  of  gallons] 


PRODUCTION 

Coal  tar  from  coke-oven  byproduct  plants,    total ■"■ 

CONSUMPTION 
Total - - 

Tar  consumed  by  distillation,    total 

Coal  tar  distilled  or  topped  by  coke-oven  operators-"- 

Coal  tar,   water-gas  tar,   distilled  by  producers  and  tar  distillers^ 

Tar  consumed  chiefly  as   fuel^ 

Tar  consumed  otherwise  than  by  distillation  or  as  fuel,    total 

Coal  tar  consumed  at  coke-oven  plants   for  roads  and  upkeep-"- 

Coal  tar,  water-gas  tar,  and  oil-gas  tar  processed  at  tar  refineries,  crude  tar 
consumed  for  upkeep  at  such  refineries,  and  tar  consumed  in  making  gas  and  in 
special -purpose  tar  blends 


312,079 
303,737 


27,169 


131,890 
26,432 


Reported  to  the  U.S.  Bureau  of  Mines. 
^  Reported  to  U.S.  Tariff  Commission.  Represents  tar  purchased  from  companies  operating  coke  ovens  and  gas-retort 
plants  and  distilled  by  companies  operating  tar -distillation  plants. 


Tar  Crudes 


Tar  crudes  are  obtained  from  coke-oven  gas  and  by  distilling  coal  tar,  water-gas  tar,    and 
oil-gas  tar.    The  most  important  tar  crudes  are  benzene,   toluene,   xylene,    naphthalene,    and 
creosote  oil.    Some  of  the  products  produced  from  coal  tar  are  identical  with  those  produced  from 
petroleum.    Data  for  materials  derived  from  petroleum  are  included,    for  the  most  part,    with  the 
statistics  for  materials  derived  from  coal  tar,   which  are  shown  in  tables  3  and  4A.^ 


Iso  table  4B.  pi.  UI,   which  lists  these  products  and  identifies  the 


2  SYNTHETIC  ORGANIC  CHEMICALS,  1966 

Domestic  production  of  industrial  and  specification  grades  of  benzene  reported  by  coke-oven 
operators  and  petroleum  refinery  operatori^   in  1966  amounted  to  955  million  gallons--15.  5  per- 
cent more  than  the  827  million  gallons   reported  for   1965.    These  statistics  include  data  for 
benzene  produced  from  light  oil  and  petroleum.    Sales  of  benzene  by  coke-oven  operators  and 
petroleunn  operators   in   1966  amounted  to  606  million  gallons,    valued  at  $147  million,    compared 
with  511  million  gallons,    valued  at  $123  million,    in  1965.    In  1966  the  output  of  toluene  ^  (including 
material  produced  for  use  in  blending  in  aviation  fuel)  amounted  to  584  million  gallons--6.4  per- 
cent more  than  the  549  million  gallons   reported  for   1965.    Sales  of  toluene  in  1966  were  361  mil- 
lion gallons,   valued  at  $62  million,    compared  with  325  million  gallons,   valued  at  $54  million,    in 
1965.    The  output  of  xylene^  in  1966  (including  that  produced  for  blending  in  motor  fuels)  was  329 
million  gallons,    compared  with  340  million  gallons  in  1965.    About  98  percent  of  the  329  million 
gallons  of  xylene  produced  in  1966  was  obtained  from  petroleum  sources. 

Production  of  crude  naphthalene  in  1966  (including  354  million  pounds  of  petroleum-derived 
naphthalene)  amounted  to  848  million  pounds,    compared  with  811  million  pounds  in  1965.    In  1966 
the  output  of  creosote  oil  for  wood  preservation  was    133  million  gallons   (100-percent  creosote 
basis),    compared  with  124  million  gallons  in  1965.    Production  of  road  tar  and  tar  (crude  and 
refined)  for  other  uses  in  1966  was   68  million  gallons,    compared  with  85  million  gallons  in  1965. 

TABLE  3.  --  Tar  and  tar  crudes:  Summary  of  U.S.  production  of  specified  products,  average  1957-59, 
annual  1965  and  1966 

[Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published 
or  where  no  data  were  reported] 


Unit 

of 

quantity 


1966  over  1966  over 

1957-59  1965 


Tar 

Benzene: 

Tar  distillers^ - 

Coke-oven  operators 

Petroleum  operators 

Total— 

Toluene: 

Tar  distillers 

Coke-oven  operators 

Petrol emn  operators 

Total - - 

Xylene: 

Tar  distillers 

Coke-oven  operators 

Petroleum  operators 

Total 

Naphthalene: 

Crude* - 

Petroleum  naphthalene,   all  grades 

Total 

Creosote  oil   (Dead  oil):' 

Distillate  as  such   (100*  creosote 

basis) 

Creosote  content  of  coal-tar  solution 

(1005t  creosote  basis)   

Total 


1,000  gal-- 

1,000  gal— 
1,000  gal— 
1,000  gal- 
1,000  gal— 

1,000  gal- 
1,000  gal-- 
1,000  gal— 
1,000  gal- 

1,000  gal  — 
1,000  gal  — 
1,000  gal— 
1,000  gal— 

1,000  lb— 
1,000  lb— 
1,000  lb— 


1,000  gal- 
1,000  gal- 


27, 130 
139,121 
155,694 


4,162 
31,007 
204,421 


239,590 

795 

8,908 

180,021 


6,741 
^333,063 


189, 724 
396,882 


463,980 
346, 620 


493,634 
354,068 


90,913 
14, 172 


111,087 
12,515 


114,725 
18, 141 


26.2 
28.0 


105,085 


123,602 


13271 


26.4 


Includes  data  for  oil-gas,   water-gas,    and  gas-retort  tar  reported  to  the  American  Gas  Association  for  1957-59 
only,    and  for  coal   tar  reported  to  the  Division  of  Bituminous   Coal,    U.S.    Bureau  of  Mines. 

^   Includes  data  for  benzene  produced  from  imported  crude  light  oil. 

^  Includes  data  for  material  produced  for  use  in  blending  motor  fuels.  Statistics  are  not  comparable  with .monthly 
figures,   which  included  some  o-xylene  now  shown  on  table  7A. 

*  Naphthalene  solidifying  at  less  than  79°  C.  Figures  include  production  by  tar  distillers  and  coke-oven  operators 
and  represent  combined  data  for  the  commercial  grades  of  naphthalene  to  avoid  disclosure  of  the  operations  of  indi- 
vidual companies.    Because  of  conversion  between  grades,    the  figures  may  include  some  duplication. 

'  Includes  data  for  creosote  oil  produced  by  tar  distillers  and  coke-oven  operators  and  used  only  in  wood  preserv- 
ing. 


Statistics  on  production  and  sal( 
the  operations  of  individual  companies. 


Df  benzene,   toluene,   and  xylene  by  tar  distillers  cannot  be  shown  because  publication  would  reveal 


TAR  CRUDES  3 

TABLE  4A.—  Tar  crudes:  U.S.  production  and  sales,  1966 

[Listed  below  are  all  tar  crudes  for  which  any  reported  data  on  production  or  sales  may  be  published.    (Leaders  are 
used  where  the   reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were  reported.) 
Table  4.B  in  pt.    Ill   lists  separately  all  products   for  which  data  on  production  or  sales  were  reported  and  iden- 
tifies the  manufacturers  reporting  to  the  U.S.   Tariff  Commission] 


Unit 
value ^ 


Crude  light  oil:  Coke-oven  operators 

Intermediate  light  oil:  Coke-oven  operators- - 

Ught-oil  distillates: 
Benzene,  specification  and  industrial  grades, 

total=  ' - 

Coke-oven  operators 

Petroleum  operators 

Toluene,  all  grades,  total^  ^ 

Coke-oven  operators 

Petroleum  operators 

Xylene,  all  grades,  total^  ^ 

Coke-oven  operators 

Petroleum  operators 

Solvent  naphtha:^  Coke-oven  operators 

Other  light-oil  distillates:^  Coke-oven  operators 

Naphthalene,  crude  (tar  distillers  and  coke-oven 

operators),  total* 

Solldifj-ing  at— 

Less  than  74°  C 

74°  C.  to  less  than  7^°   C- 

Crude  tar -acid  olls:^  Coke-oven  operators 

Creosote  oil  (Dead  oil)  (tar  distillers  and  coke- 
oven  operators)  (100*  creosote  basis),  total^--- 

Distillate  as  such  (100*  creosote  basis) 

Creosote  content  of  coal-tar  solution  (100* 
creosote  basis) 

All  other  distillate  products' 

Tar,  road 

Tar  (crude  and  refined)  for  other  uses* 

Pitch  of  tar: 

Hard  (water  softening  point  above  1£0°  F.) 

Other' — — 


1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 
1,000  gal- 


1,000  gal- 
1,000  gal- 


1,000  gal  — 
1,000  gal— 
1,000  gal— 


262,640 
5,978 


955,272 

113,932 

841,340 

583,894 

22,791 

561,103 

328,684 

6,124 

322,560 

3,161 

6,348 


132,866 


114,725 
18,141 


83,274 
3,622 


606,050 

112,095 

493,955 

361,358 

22,622 

338,736 

236,792 

6,410 

230,382 

2,954 

3,076 


147,305 

27,333 

119,972 

62,137 

4,309 

57,828 

42,585 

1,405 

41,180 

547 

272 


96,193 

18,414 

18,143 

'5,013 

14,760 
53,634 
9,492 

2,657 
7,263 
1,986 

732 
435 

28,641 
14,424 

■■•  Unit  value  per  gallon,  or  ton,  as  specified. 

^  Data  reported  by  tar  distillers  are  not  included  because  publication  would  disclose  the  operations  of 
individual  companies.   Production  of  benzene  and  toluene  by  tar  distillers  Increased  in  1966,  compared  with 
1965;  production  of  xylene  decreased.  The  annual  production  statistics  for  petroleum  operators  on  benzene, 
toluene,  and  xylene  are  not  comparable  with  the  combined  monthly  production  figures,  due  to  fiscal  year  revisions. 
Includes  data  for  material  produced  for  use  in  blending  motor  fuels. 

*  Statistics  represent  combined  data  for  the  commercial  grades  of  naphthalene.  Because  of  conversion  of 
naphthalene  from  one  grade  to  another,  the  figures  may  include  sane  duplication. 

Statistics  include  only  data  for  creosote  oil  sold  for,  or  used  in,  wood  preserving.  In  1966,  production  of 
creosote  in  coal-tar  solution  (lOO*  solution  basis)  amounted  to  27,791  thousand  gallons;  sales  were  27,604 
thousand  gallons,  valued  at  5,013  thousand  dollars,  with  a  unit  value  of  $0.18  per  gallon. 

'  Includes  value  of  coal  tar  used  in  preparing  creosote  in  coal-tar  solution. 

'  Includes  data  for  pyridine  crude  bases,  crude  oresylic  acid,  and  neutral  oils  produced  by  tar  distillers, 
and  for  crude  sodium  phenolate  produced  by  coke-oven  operators. 

*  Includes  data  for  tar  used  for  paint,  pipe  covering,  saturating,  and  other  uses. 

'  Includes  soft  and  medium  pitch  of  tar  (water  softening  points  less  than  llfl°  F.,  and  110°  F.  to  160°  F.  ASTM 
D61-24),  pitch  of  tar  coke,  and  pitch  emulsion. 

Note.— Statistics  for  materials  produced  in  coke  and  gas-retort  ovens  are  oon5)iled  by  the  Division  of  Bitumlnoue 
Coal,  U.S.  Bureau  of  Mines,  Department  of  the  Interior.  Statistics  for  materials  produced  in  tar  and  petroleum 
refineries  are  compiled  by  the  U.S.  Tariff  Commission. 


4  SYNTHETIC  ORGANIC  CHEMICALS,  1966 

Some  of  the  products  included  in  the  statistics  in  table  4A  are  derived  from  other  products 
for  which  data  are  also  included  in  the  table..,  The  statistics,    therefore,    involve  considerable 
duplication,    and  for  this  reason  no  group  totals  or  grand  totals  are  given.    It  is  estimated  that, 
after  duplication  has  been  eliminated  insofar  as  possible,   the  net  value  of  the  output  of  these 
products  and  of  tar  burned  as  fuel  was  $552  million  in   1966,    compared  with  $500  million  in  1965 
and  $460  million  in  1964. 

Crude  Products  from  Petroleum  and  Natural  Gas  for  Chemical  Conversion 

Crude  products  that  are  derived  from  petroleum  and  natural  gas  are  related  to  the  intermedi- 
ates and  finished  products  made  from  such  crudes  in  much  the  same  way  that  crude  products 
derived  from  the  distillation  of  coal  tar  are  related  to  their  intermediates  and  finished  products. 
Many  of  the  crude  products  derived  from  petroleum  are  identical  with  those  derived  from  coal 
tar  (e.  g.  ,    benzene,   toluene,    and  xylene).    Considerable  duplication  exists  in  the  statistics  on  the 
production  and  sales  of  petroleum  crudes  because  some  of  these  crude  chemicals  are  converted 
to  other  crude  products  derived  from  petroleum  and  because  data  on  some  production  and  sales 
are  reported  at  successive  stages  in  the  conversion  processes   (see  table  5A-' ).    Notwithstanding 
these  duplications,   the  statistics  are  sufficiently  accurate  to  indicate  trends  in  the  industry  and 
to  serve  as  a  basis  for  general    comparison.     Many  of  the  crude  products  for  which  data  are 
included  in  the  statistics  may  be  used  either  as  fuel  or  as  basic  materials  from  which  to  derive 
other  chemicals,    depending  on  prevailing  economic  conditions;  but  in  this  report  every  effort 
has  been  made  to  exclude  data  on  materials  that  are  used  as  fuel.    However,   data  are  included 
on  toluene  and  xylene  which  are  not  used  directly  as  fuel  but  in  blending  aviation  and  motor- 
grade  gasolines.    Statistics  on  the  production  and  sales  of  crude  products  from  petroleum  and 
natural  gas  for  chemical  conversion  for   1966  are  given  in  table  5A^. 


TABLE  5A.  --Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion:  U.S.  production 

and  sales,  1966 

. Listed  below  are  the  crude  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  any  reported 
data  on  production  or  sales  may  be  published.    (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence 
and  may  not  be  published  or  where  no  data  were  reported. )    Table  5B  in  pt.    Ill  lists  separately  all  products  from 
petroleum  and  natural  gas  for  chemical  conversion  for  which  data  on  production  or  sales  were  reported  and  identi- 
fies the  manufacturer  of  each! 


Grand  total 

ARQMATICS  AND  NAPHTHENES^ 

Total - -. 

Benzene   (1°   and  2°),   total 

Benzene,    1^ 

Benzene,   2° 

Naphthalene,    all  grades 

Naphthenlc  acids,   total 

Acid  number  150-199 — 

All  other 

Sodium  carbolate  and  phenate,  crude 

Toluene,  all  grades,  total 

Nitration  grade,  1° 

Pure  commercial  grade,  2° 

Solvent  grade,  905t 

All  other^ -  - — 

xylenes,  mixed,  total 

3° 

All  other^— - - 

All  other  aromaties  and  naphthenes* 

See  footnotes  at  end  of  table. 


J.  000 
pounds 
50,466,599 


i.OOO 
pounds 
27,494,322 


5,329,209 
879,880 


7,503 
16,525 


,724 
;, 079,217 


279,759 
15,939 


2,580,595 
196,297 


1,301,925 
2,325,658 


1,785,497 


1,661,054 


611,358 
1,049,696 
1,955,610 


11,342 
1,665 


466 
1,199 


See  also  table  5B,  pt.  JH,  which  lists  all  the  products  reported  and  identifies  the  nianufacturers. 


CRUDE  PRODUCTS  FROM  PETROLEUM  AND  NATURAL  GAS 

-Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion.-  U.S.  production 
and  sales,  i 966— Continued 


Production 


ALIPHATIC  HYDROCARBONS 

Total - — — 

C2  hydrocarbons,  total 

Acetylene' 

Ethane - - 

Ethylene - 

Cs  hydrocarbons,  total 

Propane 

Propylene 

C*  hydrocarbons,  total 

1,3-Butadlene,  grade  for  rubbers  (elastomers) 

Butadiene  and  butylene  fractions 

n- Butane 

1-Butene  and  2-butene  mixture* 

leobutane 

Isobutylene 

All  other' 

C5  hydrocarbons,  total 

Isoprene 

All  other^ 

All  other  aliphatic  hydrocarbons  aiid  derivatives,  total- 
Alpha  olefins' 

Diisobutylene  (diisobutene) 

Heptenes,  mixed 

Hexane 

Nonene  ( Tripropylene) 

Polybutene^° 

Tetrapropylene 

Hydrocarbon  derivatives-'-^ 

All  other^^ 


U, 4^9,167 


715,005 
1,493,077 
11,2A1,085 


709,834 
3,276,767 


4,385,234 
4,677,450 


,057,C 


3,612,301 
2,644,017 


4,760,865 


261, 610 


2,921,803 
878,895 
1,302,526 
1,580,592 
517,838 
460,979 
394,455 

599,388 


147,462 
451,926 


4,499,575 


1,865,705 
150,492 
400,661 

1,340,947 
380, 626 
161,280 
461,154 

124,048 


185,621 
5,613 
4,987 
37,655 
5,447 
9,913 
12,374 

4,066 


261,832 
34,034 
301,326 
186,791 
289,284 
153,373 
457,259 
30,285 
2,785,391 


162,535 
27, 178 
231,842 

Ul,202 
157,857 
305,660 
23,334 
1,317,720 


7,935 
2,040 
8,498 


6,842 
45,288 


$0,035 


.055 
.100 
.037 
.012 
.028 
.OU 
.061 
.027 


.049 
.075 
.037 

.062 
.074 
.027 
.293 

.034 


Calculated  from  rounded  figures. 
2  Tie  chemical  raw  materials  designated  as  aronatlos  are  in  some  cases  identical  with  those  obtained  from  the  dis- 
tillation of  coal  tar.  However,  the  statistics  given  in  the  table  above  relate  only  to  such  materials  as  are  derived 
from  petroleum  and  natural  gas.   Statistics  on  aromatic  chemicals  from  all  sources  are  given  in  table  4A,  "Tar  Crudes. " 
'  Includes  toluene  and  xylene  used  as  solvents,  as  well  as  that  which  is  blended  in  aviation  and  motor  gasolines. 
*  Includes  data  for  90-percent  benzene,  crude  cresylic  acid,  sodium  cresylate,  aUsyl  aromatlcs,  distillates,  sol- 
vents, and  miscellaneous  cyclic  hydrocarbons. 

'  Production  figures  on  acetylene  from  calcium  carbide  for  chemical  synthesis  are  collected  by  the  U.S.  Bureau  of  the 
Census. 

'  Hie  statistics  represent  principally  the  butene  content  of  crude  refinery  gases  from  which  butadiene  is  manu- 
factured. 

'  Includes  data  for  1-butene,  2-butene,  mixed  butylenes,  and  mixed  olefins. 
'  Includes  data  for  pentanes,  pentenes,  and  C5  hydrocarbon  mixtures. 

'  Includes  data  for  -the  following  molecular  weight  ranges:  C6-C7;  Cg-Cio;  Cn-Ci,;  C16-C20;  and  Cie-Cjo. 
^°  Includes  compounds  having  a  molecular  weight  of  3,000  or  less. 
^^  Includes  data  for  di-tert-butyldisulfide  and  miscellaneous  mercaptane. 

^^  Includes  data  for  ethane-ethylene  mixture,  heptane,  methane,  propane-propylene  mixture,  octanes,  eicosane,  and 
hydrocarbon  mixtures. 


The  output  of  crude  products  derived  from  petroleum  and  natural  gas  as  a  group  amounted 
to  50,  467  million  pounds  in  1966,    or   13.4  percent  more  than  the  44,  510  million  pounds  reported 
for  1965  (table  1).    The  larger  output  in  1966  is  accounted  for  chiefly  by  increased  production  of 
ethylene,    benzene,    propylene,   toluene,    and  acetylene.   Sales  of  crude  chemicals  from  petroleum 
in  1966  was  27,494  million  pounds,   valued  at  $865  million,    compared  with  23,402  million 
pounds,  valued  at  $705  million,    in  1965. 

The  output  of  all  aromatic  and  naphthenic  products  amounted  to   14,  799  million  pounds  in 
1966,    compared  with  13,763  million  pounds  in  1965.    Sales  in  1966,    which  amounted  to   10,029 
million  pounds,   valued  at  $261  million,    were  1,384  million  pounds  larger,    and  valued  at  $46  mil- 
lion more,   than  those  in  1965.    Naphthalene  was  produced  from  petroleum  sources  in  substan- 
tially greater  quantities  in  1966  than  in  1965.    The  output  of  1°   and  2"   benzene  from  petroleum 


^  SYNTHETIC  ORGANIC  CHEMICALS,  1966 

amounted  to  6,  209  million  pounds  in  1966--19.3  percent  more  than  the  5,  203  million  pounds  pro- 
duced in  1965.    The  output  of  toluene  in  1966  was  4,  079  million  pounds--?.  1  percent  more  than 
the  3,  810  million  pounds  produced  in  1965.    Production  of  xylene  was  2,  326  million  pounds  in 
1966,    compared  with  2,401   million  pounds  in  1965.    These  figures  include  toluene  and  xylene 
used  in  blends  in  aviation  and  motor-grade  gasolines.    The  output  of  naphthenic  acids  amounted 
to  24  million  pounds  in  1966,    about  the  same  as  that  produced  in  1965. 

Production  of  all  aliphatic  hydrocarbons  and  derivatives  from  petroleum  and  natural  gas  waf. 
35,  668  million  pounds  in  1966,    compared  with  30,  746  million  pounds  in   1965.    Sales  of  these 
products  were   17,465  million  pounds,   valued  at  $605  million,    in  1966,    compared  with  14,757 
million  pounds,    valued  at  $490  million,    in   1965.    The  statistics  on  production  of  acetylene  (table 
5A)  include  only  acetylene  produced  from  hydrocarbons  and  used  as  a  raw  material  in  the  pro- 
duction of  other  chemicals.    Total  production  of  acetylene  for  chemical  synthesis  is   reported 
to  the  U.S.    Bureau  of  the  Census.    In   1966,    production  of  acetylene  from  hydrocarbon  sources, 
amounted  to  715  million  pounds.    Production  of  ethylene  was    11,241  million  pounds  in  1966--17.5 
peircent  more  than  the  9,  570  million  pounds  produced  in  1965.    The  output  of  propane  and  propylene 
was  9,  063  million  pounds  in  1966--13.  7  percent  more  than  the  7,  972  million  pounds  produced  in 
1965.    Production  of  1 ,  3-butadiene,    one  of  the  principal  ingredients  of  S-type  synthetic  rubber, 
was  2,922  million  pounds  in  1966,    compared  with  2,685  million  pounds  in  1965.    The  output  of 
1 ,  3-butadiene  in  I966--8.8  percent  more  than  that  in  1965--was  the  largest  on  record. 

The  following  tabulation  shows  the  number  of  companies  that  reported  production  of  organic 
chemical  crudes  in  I966: 

Number 
of 
Chemical    group  companies 

Tar  crudes 13 

Petroleum  crudes 73 


PART  II.      PRODUCTION  AND  SALES  OF  INTERMEDIATES  AND  FINISHED  SYNTHETIC 
ORGANIC  CHEMICALS,   BY  GROUPS 

General 

On  the  basis  of  their  principal  uses,    the   synthetic  organic  chemicals  covered  in  this   report 
are  classified  either  as  intermediates  or  as  finished  products.    Finished  products,    in  turn,    are 
grouped  as  follows:    Dyes,    synthetic  organic  pigments,    medicinal  chemicals,    flavor  and  perfume 
materials,    plastics  and  resin  materials ,    rubber-processing  chemicals,    elastomers  (synthetic 
rubbers),    plasticizers ,    surface-active  agents,    pesticides  and  related  products,    and  miscellane- 
ous  synthetic  organic  chemicals.    Most  of  these  groups  are  further  subdivided,    according  to 
chemical  classes,    into  cyclic  and  acyclic  compounds.    As  most  of  the  intermediates  are  used  in 
the  manufacture  of  finished  products,    aggregate  figures  that  cover  both  intermediates  and  finished 
products  necessarily  include  considerable  duplication. 

Total  production  of  synthetic  organic  chemicals  (intermediates  and  finished  products  com- 
bined) in  1966  was    100,  627  million  pounds,    or   13.  2  percent  more  than  the  output  of  88,  864  mil- 
lion pounds   reported  for   1965  (see  table  6).    Sales  of  synthetic  organic  chemicals  in  1966  amounted 
to  52,  720   million  pounds,    valued  at  $9,  958  million,    compared  with  46,  807  million  pounds,    valued 
at  $9,021  million,    in  1965.    Production  of  all  cyclic  products   (intermediates  and  finished  products 
combined)  in   1966  totaled  32,  133  million  pounds,    or   13.  8  percent  more  than  the  28,229  million 
pounds  produced  in  1965.    The  output  of  acyclic  organic  chemicals  in  1966  amounted  to  68,494 
million  pounds--13.  0  percent  more  than  the  60,  635  million  pounds   reported  for   1965. 


TABLE  6.— Synthetic  organic  chemicals.-  Summary  of  U.S.  production  and  sales  of  intermediates  and  finished 
products,  average  1957-59,  annual  1965  and  1966 

[Production  and  sales  in  thousands  of  pounds;   sales  value  in  thousands  of  dollars] 


Average 
1957-59 

1965 

1966 

Increase,   or  decrease   (-) 

1966  over 
1957-59 

1966  over 
1965 

Organic  chemicals,   cyclic   and   acyclic, 
grand  total: 
Production 

Sales  value 

Cyclic,   total: 

45,598,853 
23,744,812 
5,743,764 

14,381,651 
8,829,037 
2,785,100 

31,217,202 
14,915,775 
2,958,664 

7,343,167 

2,919,264 

481,920 

150,830 
141,731 
182,513 

38,603 
30,218 
58,648 

88,864,092 
46,807,057 
9,020,540 

28,229,128 
16,499,189 
3,855,492 

60,634,964 
30,307,868 
5,165,048 

16,865,164 

7,551,210 

814,383 

207,193 
189,965 
292,284 

48,045 
38,024 
93,635 

100,626,696 
52,719,594 
9,958,383 

32,132,902 
18,867,433 
4,328,963 

68,493,794 
33,852,161 
5,629,420 

19,466,775 

8,852,033 

925,092 

219,194 
204,135 
331,453 

51,128 
43,316 
107,594 

Percent 

120.7 
122.0 
73.4 

123.4 
113.7 
55.4 

119.4 
127.0 
90.3 

165.1 
203.2 
92.0 

45.3 
44.0 
81.6 

32.4 
43.3 
83.5 

Percent 

13.2 
12.6 
10.4 

13.8 
14.4 
12.3 

13.0 
11.7 
9.0 

15.4 
17.2 
13.6 

5.8 
7.5 

13.4 

6.4 
13.9 
14.9 

Sales 

Sales  value 

Acyclic,   total: 

Sales - 

Sales  value 

1.    Intermediates.    Cyclic 

Production 

Sales 

2.    Dyes,    Cyclic 
Production 

Sales 

J.   .Synthetic  Organic  Pigments.    Cyclic 

Sales - 

Sales  value 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 

■  Synthetic  organic  chemicals:  Summary  of  U.S.  production  and  sales  of  intermediates  and  finished 
products,  average  1957-5S,  annual  1965  and  i566— Continued 

[Production  and  sales   in  thousands  of  pounds;   sales  value  in  thousands  of  dollars] 

Increase,   or  decrease  (-) 


^.     Medicinal  Chemicals 

Cyclic: 

Production 70,654  100,040  116,164 

Sales ~  54,151  72,479                  76,842                (^ 

Sales  value 535,297  321,158  356,646               ( ^) 

Acyclic: 

Production 31,592  59,480                 69,305                    119.4 

Sales 28,738  56,569                 59,621               {'■) 

Sales  value 35,660  41,011                  41,762                ( ^) 


5.    Flavor    and  Ptrfumt   Materials 

CycUc: 

Production 27,312  53,223  61,406 

Sales 22,446  44,559  49,597 

Sales  value— - 33,903  56,800  60,915 

Acyclic: 

Production 19,033  46,001  49,264 

Sales— 19,958  43,144  48,717 

Sales  value- —  21,912  28,180  31,719 


124.8 
121.0 
79.7 

158.8 
144.1 
44.8 


6.    Plastics    and  Besin  Materiali 

Cyclic: 

Production 2,278,862  4,452,975  5,066,571 

Sales- —  1,900,032  3,689,722  4,254,211 

Sales  value 518,501  873,501  988,001 

Acyclic: 

Production- - 2,628,779  7,231,900  8,518,301 

Sales 2,438,853  6,363,044  7,217,427 

Sales  value 864,523  1,630,932  1,752, C 


122.3 
123.9 
90.5 

224.0 
195.9 
102.7 


7.   Bubber-Processmg  Chemicals 

Cyclic: 

Production 159,182  211,403  241,248 

Sales— 115,704  166,214  182,790 

Sales  value 74,479  109,204  123,581 

Acyclic 

Production 29,150  40,542  42,087 

Sales 22,127  27,504  26,495 

Sales  value 1A,289  14,189  14,622 


51.6 
58.0 
65.9 

44.4 
19.7 
2.3 


8.    Elastomers    (Synthet 

Cyclic: 

Production 1,938,732  2,300,092  2,482,375 

Sales 1,726,757  1,897,921  2,108,089 

Sales  value 404,897  442,722  463,222 

Acyclic: 

Production 521,811  1,291,562  1,446,812 

Sales - 509,262  1,1A3,242  1,303,169 

Sales  value 199,627  400,726  454,796 


28.0 
22.1 
14.4 

177.3 
155.9 
127.8 


9.   Plasticizers 

Cyclic: 

Production 348,210  798,741  897,249 

Sales 297,423  764,736  873,109 

Sales  value 83,509  133,04^  156,967 

Acyclic: 

Production 118,118  274,456  311,742 

Sales 100,984  256,887  282,577 

Sales  value 38,772  81,348  89,034 

See  footnote  at  end  of  table. 


163.9 
179.8 
129.6 


GENERAL 


TABLE  6.--Synthetic  organic  chemicals:  Summary  of  U.S.  production  and  sales  of  intermediates  and  finished 
products,  average  1957-59,  annual  1965  and  i966~Continued 

[production  and  sales  in  thousands  of  pounds;    sales  value  in  thousands  of  dollars] 


Average 
1957-59 


Increase,   or  decrease  (-) 


1966  over  1966  over 

1957-59  1965 


Cyclic: 

Production- 
Sales 

Sales  value - 

Acyclic: 

Production- 
Sales 

Sales  value - 


11-   Pes 

CycUo: 

Production- 
Sales 

Sales  value- 
Acyclic; 

Production — 

Sales 

Sales  value- 


Cyclic: 

Production- 
Sales 

Sales  value - 

Acyclic : 

Production- 
Sales 

Sales  value- 


852,314 
800,'i32 
127,936 

502,715 
432,135 
113,215 


440,384 
375,627 
150,837 

105,080 
91,938 
49,049 


733,401 
445,252 
132,660 

27,260,924 
11,271,780 
1,621,617 


1,371,320 
877,202 
96,153 

1,799,158 
820,660 
204,035 


682,671 
582,344 
377,858 

194,526 
181,561 
119,208 


1,138,261 
624,813 
244,750 

49,697,339 
21,415,257 
2,645,419 


1,385,217 
879,235 
97,187 

1,936,100 
886,818 
217,726 


776,909 
605,229 
446,946 

236,201 
217,027 
136,856 


1,368,666 
738,847 
271,359 

55,883,982 
23,810,310 
2,890,825 


76.4 
61.1 
196.3 

124.8 
136.1 
179.0 


86.6 
65.9 
104.6 

105.0 
111.2 
78.3 


13.8 
3.9 


21.4 
19.5 
U.8 


20.2 
18.2 
10.9 

12.4 
11.2 
9.3 


Data  for  1966  are  not  comparable  with  those  for  average  1957-59. 

The  following  tabulation  shows,    by  chemical  groups,   the  number  of  companies  that  reported 
production  in  1966  of  one  or  more  of  the  chemicals  included  in  the  groups  listed  in  table  6: 


flumber 
Chemical  group  of 

companies 

Intermediates    219 

Dyes    50 

Synthetic  organic  pigments 36 

Medicinals  chemicals    111 

Flavor  and  perfume  materials 54 

Plastics  and  resin  materials 305 


dumber 
Chemical  group  of 

cojnpanie: 

Rubber-processing  chemicals 32 

Elastomers  (synthetic  rubbers) 29 

Plasticizers 55 

Surface-active  agents     201 

Pesticides  and  related  products 87 

Miscellaneous  chemicals     313 


10  SYNTHETIC  ORGANIC  CHEMICALS,  1966 

Cyclic  Intermediates 

Cyclic  intermediates  are  synthetic  organic  chemicals  derived  principally  from  coal-tar 
crudes  produced  by  destructive  distillation  (pyrolysis)  of  coal  and  from  petroleum  and  natural 
gas.    Most  cyclic  intermediates  are  used  in  the  manufacture  of  more  advanced  synthetic  organic 
chemicals  and  finished  products,    such  as  dyes,    medicinal  chemicals,    elastomers   (synthetic 
rubbers),    pesticides,    and  plastics  and  resin  materials.    Some  intermediates,    however,    are 
sold  as  end  products  without  further  processing.    For  example,    refined  naphthalene  may  be 
used  as  a  raw  material  in  the  manufacture  of  2-naphthol  or  of  other  more  advanced  intermedi- 
ates,   or  it  may  be  packaged  and  sold  as  a  moth  repellent  or  as  a  deodorant.    In  general,   the 
classification  of  a  given  chemical  as  an  intermediate  is  determined  by  the  way  in  which  the 
greater  part  of  its  output  is  consumed.    Since  many  intermediates  represent  successive  steps 
in  production,  the  totals  given  necessarily  include  considerable  duplication.    In  1966,    nearly 
half  of  the  total  output  of  cyclic  intermediates  was  sold;  the  remainder  was  used  by  the  produc- 
ing plants  in  the  manufacture  of  more  advanced  products.    The  statistics  on  cyclic  intermedi- 
ates for  1966  are  given  in  table  lA^. 

Total  production  of  cyclic  intermediates  in  1966--19,467  million  pounds--was  the  largest 
on  record,    and  was    15.4  percent  larger  than  the  output  of  16,865  million  pounds   reported  for 
1965.    The  larger  output  of  cyclic  intermediates  in  1966  was  attributable  to  increased  demand 
by  the  chemical  products  industries,    particularly  those  industries  that  produce  dyes,    pesticides, 
plasticizers ,    and  plastics  and  resin  materials.    Sales  of  cyclic  intermediates  in  1966  amounted 
to  8,  852  million  pounds,    valued  at  $925  million,    compared  with  7,  551  million  pounds,   valued 
at  $814  million,    in  1965.    In  terms  of  quantity,    sales  of  cyclic  intermediates  in  1966  were  17.2 
percent  larger  than  those  in  1965  and  in  terms  of  value,    13.  6  percent  larger. 


TABLE  1  A— Cyclic  intermediates:  U.S.  production  and  sales ,  1966 


[ listed  below  are  all  cyclic   Intermediates  for  which  any  reported  data  on  production  or  sales  may  be  published. 
(Leaders  are  used  where  the  reported  data  are  accepted   in  confidence  and  may  not  be  published  or  where  no 
data  were  reported.)   Table  7B  in  pt.    Ill  lists   alphabetically  all  cyclic  intermediates  for  which  data  on 
production  or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Sale 


Unit 
value^ 


Total - ~ 

Acetanilide,    tech 

Acetophenone,    tech 

Alkylbenzenes^ 

•4'  -Aminoacetanilide   ( Acetyl-p-phenylenediamine) 

5-Amino-2-(p-aminoanilino)benzenesulfonic   acid 

1-Aminoanthraquinone  and  salt 

2-Aminoanthraquinone  and   salt 

6-itaiino-3,4' -azodibenzenesulfonic  acid   (C.I.  Acid  Yellow  9)- 

l-Amino-4-benzamidoanthraquinone 

l-Amino-5-benzamldoanthraquinone 

7-(p-Aminobenzamido)-i-hydroxy-2-naphthalenesulfonic  acid 

2-Aniino-p-benzenedisulfonic   acid   [S03H=1] 

l-Amino-'4-bromo-9,10-dihydro-9,10-dloxo-2-anthraoenesulfonic 

and  sodium  salt 

l-Amino-2-bromo-<t-hydroxyanthraquinone 

l-Amino-2-bromo-4-p-toluidinoanthraquinone 

l-Amlno-5-ohloroanthraquinone 

o-(3-Amino-4-chlorobenzoyl )benzoic  acid 

3-Amino-5-chloro-2-hydroxybenzenesulfonic  acid 


5,438 

965 

714, 901 

696 

7 

1,883 

1,054 


pound 

$0.10 


2,297 

714 

560,076 


See  footnotes   at  end  of  table. 


1-  See  also  table  7B,  pt.  Ill,  which  lists  these  products  alphabeticaUy  and  identifies  the  manufacturers,  and  table  23  in  the  appendix, 
/hich  shows  imports  of  intermediates  and  related  products  during  1965  and  1966. 


CYCLIC  INTERMEDIATES 
TABLE  TA.  — Cyclic  intermediates:  U.S.  production  and  i 


i  966— Continued 


Unit 
valued 


6-Jtaino-A-ohloro-m-toluenesulfonlo  acid   [S03H=l]   

l-Amino-aj-i-dibromoanthraquinone 

l-Amino-9,10-dihydro-9,10-dioxo-4.-p-toluenesulfonamido-2-anthra- 

oenesulfonio  acid,   sodium  salt 

'4-Amino-5-hydroxy-2,7-naphthalenedisulfonic   acid   (H  acid), 

monosodiujL  salt 

<i-Amino-3-hydroxy-l-naphthalenesulfonlc  acid  (1,2,4-acld) 

6-Amino-<i-hydroxy-2-naphthalenesulfonic  acid   (Gamma  acid), 

sodium  salt 

7-Amlno-4-hydroxy-2-naphthalenesulfonic  acid   (j  acid),   sodium  salt- 

N-('V-Amino-3-methoxy-l-anthraquinonyl  )-p-toluenesulf  on  amide 

4' Amino-N-methylacetanillde 

2-Amino-l,5-naphthalenedisulfonic  acid 

6-Amino-l,3-naphthalenedisulfonio   acid   (Jtailno  I  acid) .-- 

7-Aiiilno-l,3-naphthalenedlsulfonlc  acid   (Amino  G  acid) 

4-Amino-l-naphthalenesulfonic  acid   (Naphthionic  acid) 

5-Amino-2-naphthalenesulfonic  acid   (l,6-Cleve's  acid) 

5(and  8)-Amino-2-naphthalenesulfonlo  acid   (Cleve's   acid,   mixed) 

6-Amlno-2-naphthalenesulfonic   acid   (Broenner's   acid) 

8-Amino-l-naphthaleneaulfonio   acid   (Peri  acid) 

8-Amino-2-naphthalenesulfonic   acid   (l,7-Cleve's  acid) 

8-Amino-2-naphthol 

2-Amino-5-nitrobenzenesulfonic  acid   [S03H=1] 

4-Amino-4' nitro-2, 2' -stilbenedisulf onlc   acid 

3'-Aminooxanilic   acid 

p-^(p-Aminophenyl)azo]benzenesulfonic  acid 

4.-Amino-m-toluenes\ilfonic  acid    rS03H=l] 

6-Amino-m-toluenesulfonic  acid    [SOjHil] 

16- Aminoviolan throne 

Aniline   (Aniline  oil) 

7-Anilino-4-hydroxy-2-naphthalenesulfonic  acid   (Rienyl  J  acid) 

Anilinomethanesulfonio   acid  and  salt 

8-Anilino-l-naphthalenesulfonic  acid   (Phenyl  peri   acid) 

o-Anisidine 

o-Anisidinomethanesulfonic   acid 

Anthra[l,9-cd]pyrazol-6(2H)-one   (lyrazoleanthrone) 

Benzaldehyde,    tech 

l-Benzamido-5-chloroanthraquinone 

7H-Benz[de]anthracen-7-one  ( Benzanthrone ) 

Benzidine  hydrochloride  and  sulfate 

Benzoic  acid,    tech 

2-Benzcthiazolethiol   (2-Mercaptobenzothlazole),    sodium  salt 

o-Benzoylbenzoic   acid 

[3,3'-Bianthra[l,9-cd]pyrazole]-6,6'-(2H,2'H)dione   (Pyrazole- 

anthrone  yellow) 

[4,4' -Bi-7H-benz[de] anthracene] -7,7' -dione 

[l,l'-Binaphthalene]-8,8'-dicarboxylic  acid 

1,4-Bis [l-anthraquinonylamino]anthraquinone 

4,4'-Bis  [dimethylamlnojbenzophenone   (Michler's  ketone) 

3-Bromo-7H-benz[de]anthracen-7-one   (3-Broniobenzanthrone) 

l-Bromo-4-(methylamino)anthraquinone 

l-Chloroanthraquinone 

2-Chloroanthraquinone 

Chlorobenzene,   mono-  

o-(p-Chlorobenzoyl) benzoic  acid 

l-Chloro-2,4-dinitrobenzene  (Dlnltrochlorobenzene) 

6-Chlorometanilic  acid 

l-Ghloro-2-methylanthraquinone 

2-Chloro-4-nltroaniline   (o-Chloro-p-nltroaniline) 

4-Chloro-2-nitroanlline   (p-Chloro-o-nitroaniline) 

l-Chloro-5-nltroanthraquinone 

l-Chloro-2-nitrobenzene   ( Chloro-o-nitrobenzene ) 

l-Chloro-3-nitrobenzene   (Chloro-m-nitrobenzene) 

l-Ghloro-4.-nitrobenzene  (Chloro-p-nitrobenzene) 

4-Chloro-3-nitrobenzeneBulf on amide 


16 
116 
1,053 
803 
224 
82 
192 
100 
518 
103 


51 

22 

248 

217 

360 

9 

239,004 

48 

285 

355 

2,024 

447 

28 

5,319 

97 

2,193 

1,251 

20, 511 

25,552 

5,903 

30 
459 

20 


46 

227 

950 

576,749 

1,570 

8,535 

27 

178 

389 

566 


$1.49 
2.36 


,769 
218 
,"637 


153 
,409 


See  footnotes  at  end  of  table 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 
TABLE  TA.— Cyclic  intermediates:  U.S.  production  and  sales ,  i 566— Continued 


Production 


1.000 


4-Chloro-3-nitrobenzenesulfonyl  chloride 

o-(4-Clhloro-3-nitrobenzoyl) benzoic  acid 

"i-Qiloro-S-nitro  toluene 

a-Chlorotoluene  (Benzyl  chloride) 

5-Chloro-o-toluidine  [  NH^^l]  ("i-Chloro-o-toluidine   [CHj^l]) ~ 

N-[(5-Chloro-o-tolyl)azo]saroosine 

[  (<i-Chloro-o-tolyl)thio]acetic  acid 

Cresols,   total^ 

o-Cresol 

(m,p)-Cresol 

All  other* - - 

Cresylic  acid,   refined,   total 

From  coal  tar^ 

From  petroleum 

Cumene 

Cyolohexone 

C^clohexanone 

CJrclohexylamine 

1,4-Diajninoanthraquinone 

2,6-Diaminoanthraquinone 

l,4-Dianiino-2,3-dihydroanthraquinone 

i,4'-Diamino-2,2'-stilbenedisulfonic  acid 

^,5'-Dibenzamido-l,  I'-imlnodianthraqulnone 

1, 5-Dibenzoylnaphthalene 

3,9-Dibromo-7H-benz[de]anthracen-7-one 

2,5-Diohloroanlllne  and  hydrochloride  [HHa^-'-] 

1, 5-Dichloroanthraquinone 

1,8-Dichloroanthraquinone 

o-Dlchlorobenzene 

p-Dichlorobenzene 

3,3'-Dlchlorobenzidine  base  and  salts 

2, 5-Dichloro-4-(3-methyl-5-oxo-2-pyrazolin-l-yl )benzenesulfonio 

acid - - - 

2,6-Dichloro-4-nitroaniline 

l,4-Dichloro-2-nitrobenzene  (Nitro-p-diohlorobenzene) 

Dicyclopentadiene   (includes  cyolopentadlene ) 

p-(Diethylamino)benzaldehyde 

N,  N-Diethylanlllne - - 

9, 10-Dthydro-l,^-dihydroxy-9, lO-dioxo-2-anthraoeneBUlf onio 

acid   (2-Oainizarinsulfonlc   acid) 

9, lO-Dihydro-9, 10-dioxo-l,5-anthraoenedisulfonio  acid  and 

disodium  salt 

9,  lO-Dihydro-9, 10-dioxo-l,  8-anthracenedisxilf onio  acid, 

potassium  salt 

9,10-Dihydro-9, 10-dloxo-2,6-anthracenedleulfonio  acid  and  salt — 
9, lO-Dihydro-9, lO-dioxo-l-anthracenesulT onic  acid  and  salt  (Gold 

salt) - 

9, 10-Dlhydro-5-nitro-9, 10-dioxo-l-anthraceneeulf onic  acid 

l,A-Dlhydroxyanthraqulnone  (Qulnizarln) — 

1,5-Dihydroxyanthraquinone   ( Anthraruf in ) 

1,8-Dihydroxyanthraquinone  (Chrysazln) 

l,5-Dihydroxy-4-,8-dinitroanthraqulnone 

l,8-Dil^roxy-A,5-dinitroanthraquinone  (4,5-Dinitroohrysazin) 

16, 17-W.hydroxyviolanthrone  (Dlhydroxydibenzanthrone) 

3,3'Dimethoxybenzidine  (o-Dianlsidine) 

N,  N-Wmethylaniline 

N,  N-Dimethylbenzylamine 

2,2' -Dimethyl-1 , 1 ' -bianthraquinone 

N,N-Diinethyl-p-nitrosoaniline 

2,4-Dlnitroaniline 

l,5(and  l,8)-Dinitroanthraquinone 

2,4-Dinltrophenol,   tech 


500 

220 

102 

74,994 

35 


16, 586 
35,352 
28,067 


17,665 
36,842 

894,827 

1,900,792 

314,424 

11, 922 

49 

181 

420 

6,510 

162 

288 

502 

206 

173 

64 

51,386 

66,307 

2,790 

347 
607 
793 
49,672 
21 
1,901 


3,501 

83 

2,346 

157 

193 

95 
275 
320 
518 
13,452 

81 
116 

45 
206 
235 
971 


13,000 
35,990 
22,061 


50,726 
65,569 
3,050 


431 

23^008 

970 


26 


1,917 
4,771 
7,801 


5,065 
5,893 
3,923 


1,503 
500 


See  footnotes  at  end  of  table. 


CYCLIC  INTERMEDIATES 
TABLE  7A.  --  Cyclic  intermediates:  U.S.  production  and  sales ,  i566— Continued 


A, A' -Dinitrostilbene-2,2'-disulfonlo  acid 

2,<»-Dlnitrotoluene 

1, S-Diphenoxyanthraqulnone 

Diphenylamine 

1,4-Dl-p-toluidinoanthraquinone 

Divlnylbenzene 

p-Dodeoylphenol 

N-Ethylaniline,    refined 

Ethylbenzene' 

N-Bthyl-N-phenylbenzylamine 

Urdroquinone,    tech 

p-ltydroxybenzenesulfonic   acid 

p-f^droxybenzolo  acid,   methyl  ester 

p-lirdroxybenzoic  acid,   propyl  ester 

i-Hydroxymetanilamide 

4-I^rdroxyiiietanlllc  acid 

3-firdroxy-2,7-naphthalenedisulfoDic   acid,   disodium  salt 

6-Itydroxy-2-naphthalenesulfonic   acid   and  sodium  salt 

3-}trdroxy-2-naphtho-o-toluidide 

N-(7-[fydroxy-l-naphthyl)acetamide 

l,l'-Imlnobis[4-aiDinoanthraquinone] 

7,7'-ImlncbisU-hydroxy-2-naphthalenesulfonic   add] 

l,l'-Iininobis[4-nitroanthraquinone] 

1,1'  -Imlnodianthraquinone   (l,l'-Dianthrimlde) 

Isooyanic   acid  derivatives,    total 

Diphenylmethane  <t,4'-diisocyanate  (MDI) 

Toluene  2,4-   and  2,6-diisocyanate   (80/20  mixture) 

Other  isocyanic  acid  derivatives -.— . 

4.,4'-Isopropylidenediphenol   (Bisphenol  A) 

Isovlolanthrone  ( Isodibenzanthrone) 

Leuco  quinizarin   (1,4, 9, lO-Anthratetrol ) 

2,4-Liitidine 

Melamlne 

dl-p-Mentha-l,8-diene   (Limonene) 

o-Meroaptobenzoic   acid   (Thlosalicylic  acid) 

l-(Methylaniino)anthraquinone 

4,4'-Methylenebis[N,N-dlmethylaniline]   (Methane  base) 

4,4'-Methylenedianillne 

m-(3-Metl^rl-5-oxo-2-pyrazolin-l-yl)benzenesulf  on  amide 

p-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonlc  acid 

4-(3-Methjrl-5-oxo-2-pyrazolin-l-yl)-m-toluenesulfonic  acid 

[S03H=1] 

3-Methyl-l-phenyl-2-pyrazolin-5-one   (Developer  Z) 

a-Methylstyrene 

Naphthalene,    solidifying  at  79°   C.   or  above   (refined  flake) 

(from  domestic  crude) 

2,7-Naphthalenedisulfonio  acid 

1,4, 5,8-Naphthalenetetracarboxylio  acid 

1-Naphthol   (a-Naphthol) — 

Naphthostyril 

Naphth[l,2-dl[l,2,3loxadlazole-5-sulfonic  acid 

p-Nitroaniline 

5-Nitro-o-anisidine  [  NH2=l] 

Nitrobenzene 

m-Nitrobenzenesulfonic   acid   and  sodium  salt 

7(and  8)-Nitronaphth[l,2-d][l,2,3] oxadiazole-5-sulfonic  acld- 

p-Nltrophenol   and  sodium  salt 

3-Nitro-p-toluenesulf onic   acid [sOjH^l] 

5-Nitro-o-toluenesulfonio  acid  [S03H=l] 

2-Nitro-p-toluldine  [nH2=1] 

5-Nltro-o-toluldine  [nH2=1] 

16-Nltroviolan throne 

Nonylphenol 

l-[7-0ico-7H-benz  [de]  anthracen-3-yl  )amlDo]  anthraquinone 


Production 


9,376 

116 

31,615 

195 

2,663 

13,525 

1,505 

,245,000 

692 

13,652 

6,132 


6,135 
173,283 
44,070 


,018 
,750 

250 
,853 
,711 

969 
r025 
87 
,261 
,208 

367 


Qaantity  Value 


pounds 

6,517 
28,569 
1,971 


540 
58,315 
12,727 


dollars 
525 
7,555 
1,519 


190 

14,716 

732 


See  footnotes  at  end  of  table 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 
TABLE  IK. —Cyclic  intermediates:  U.S.  production  and  sales ,  i 966— Continued 


Production 


l,l'.[(7-Oxo-7H-benz[de]anthraoen-3,9-ylene)diimino]di- 

anthraquinone 

5-Oxo-l-phenyl-2-pyTazoline-3-oarboxylio  acid,    ethyl  ester- 
Phenol,   grand  total-' 

Natural,    total 

From  coal  tar 

From  petroleum 

Synthetic ,  total 

From  oumene 

Other  synthetic 


Hienylacetic   acid  and  salts 

Phenylacetonitrile   (ct-Tolunitrlle) 

p-Phenylazoaniline   (C.I.    Solvent  Yellow  1)   and  hydrochloride- 

p-Hienylenediamine 

l-Rienyl-l,2-propanedione,   2-oxime 

Hithalio  anhydride 


Pioolines,   total-" 

2-Picoline   (a-Picoline)- 
Other  picolines 


Piperidine 

Propiophenone 

8,16-iyranthrenedione 

2°  I^idine^ 

Quinaldine 

Salicylaldehyde 

Salicylic  acid,    teoh 

Styrene,    all  grades 

Terephthalic   acid 

Terephthalic   acid,   dimethyl  ester 

1,4,5,8-Tetrachloroanthraquinone 

1,4, 5,8-Tetrahydroxyanthraquinone,    leuco  derivative 

1,4, 5, 8-Tetrakis   ( l-anthraquinonylamino )anthraquinone 

(Pentanthrimide) 

4,4'-Thiodianiline 

Toluene-2,4-diajiiine   (4-m-Tolylenediaiii-i;>  .-1 

o(and  p)-Toluenesulfonic   acid 

o-(p-Toluoyl)benzoic   acid 

4-(o-Tolylazo)-o-toluidine   (C.I.    Solvent  Yel.       3) 

1,3,3-Trimethyl-o^,'  -indolineacetaldehyde 

l,3,3-Trimethyl-2-methyleneindoline   (Trimethyl  base)-- 

7,7'-Ureylenebis[4-hydroxy-2-naphthalenesulfonio  acid]   (J  acid 


urea)- 


Violanthrone   (Dibenzanthrone) — 

o-3Cylene 

p-}^lene 

All  other  cyclic  intermediates- 


1.000 


1,346,621 


57,135 
39,850 
17,285 
1,289,486 
613,435 
676,051 

4,628 


652 

246 

675,180 


2,534 

,191,548 

513,868 

797,470 

131 

120 

236 
13 
68,468 
6,926 
427 
448 
143 
284 

393 

476 

403,211 

518,801 

■369,123 


571,047 


52,272 
37,778 
14,494 
518,775 
280,374 
238,401 


5,034 
3,511 
1,523 


34,617 
1,147 


1,397 
2,023 


457 

5,068 

2,018 

3,915 

1,509,071 


397,224 

459,955 

1,354,505 


Calculated  from  rounded  figures. 

^  Principally  straight-chain  dodecylbenzene,  tridecylbenzene  and  other  straight- 1 
lesser  amounts  of  branohed-chain  compounds. 

•*  Includes  data  for  coke  ovens  and  gas-retort  ovens,  reported  to  the  Division  of 
Mines,  Department  of  the  Interior,  and  for  tar  refineries  and  other  producers,  reported    .hi  I'. 

*  Figures  include  (o,m,p)-cresol  from  tar  and  some  m-cresol  and  p-oresol. 

^  Does  not  include  ethylbenzene  produced  and  consumed  in  continuous -process  styrene  manufacture 


Ikylbenzenes,  but  includes 


DYES  15 

In   1966,    production  of  ethylbenzene  was   3,245  million  pounds,    or  7.4  percent  larger  than 
the  3,023  million  pounds   reported  for   1965.    Output  of  styrene  in  I966  was   3,  192  million  pounds, 
an  increase  of  11.4  percent  over  the  2,864  million  pounds  in  1965.    Other  intermediates  whose 
production  exceeded  one  billion  pounds  in  1966  were  cyclohexane  (1,901  million  pounds),    and 
phenol  (1,347  million  pounds).    The  output  of  other  large-volume  intermediates  in  1966  compared 
with  production   in   1965  was  as  follows:    Cumene,    895  million  pounds   (35.  0  percent  larger  than  in 
1965);  terephthalic  acid,    dimethyl  ester,    797  million  pounds  (46.4  percent  larger);  alkylbenzenes , 
71  5  million  pounds   ( 14.  4  percent  larger );  phthalic  anhydride,    675  million  pounds   (11.0  percent 
larger);  chlorobenzene,    577  million  pounds   (5.  6  percent  larger);  p-xylene,    519  million  pounds 
(30.  9  percent  larger);  o-xylene,    403  million  pounds  (14.  8  percent  larger);  aniline,    239  million 
pounds  (22.2  percent  larger);  and  isocyanates,    223  million  pounds  (21.  3  percent  larger). 

Dyes 

The  synthetic  dyes  produced  in  the  United  States  are  all  derived  in  whole  or  in  part  from 
cyclic  intermediates.    Approximately  two-thirds  of  the  dyes  consumed  in  the  United  States  are 
used  by  the  textile  industry  to  dye  natural  and  synthetic  fibers  or  fabrics;  about  one-sixth  are 
used  for  coloring  paper;  and  the  rest  are  used  chiefly  in  the  production  of  organic  pigments  and 
in  the  dyeing  of  leather  and  plastics.    Of  the  several  thousand  different  synthetic  dyes  that  are 
known,    more  than  one  thousand  five  hundred  are  manufactured  annually  by  one  or  more  domestic 
producers.    The  large  number  of  dyes   results  from  the  many  different  types  of  materials  to  which 
dyes  are  applied,    the  different  conditions  of  service  for  which  dyes  are  required,    and  the  costs 
that  a  particular  use  can  bear.    Dyes  are  sold  as  pastes,    powders,    lumps,    and  solutions;  concen- 
trations vary  from  6  percent  to   100  percent.    The  concentration,    form,    and  purity  of  a  dye  are 
determined  largely  by  the  use  for  which  it  is  intended. 

Table  8A      shows  U.S.    production  and  sales  of  dyes  in  1966,    total  and  by  individual  dyes 
using   Colour   Index    classification  and  terminology. 

Total  domestic  production  of  dyes  in  1966  amounted  to  219  million  pounds,  or  5.  8  percent 
more  than  the  207  million  pounds  produced  in  1965  (table  8A).  Sales  of  dyes  in  1966  amounted 
to  204  million  pounds,  valued  at  $331  million,  compared  with  190  million  pounds,  valued  at 
$292  million,  in  1965.  In  terms  of  quantity  sales  of  dyes  in  1966  were  7.  5  percent  larger  than 
in  1965  and  in  terms  of  value,  13.  4  percent  larger.  The  average  unit  value  of  sales  of  all  dyes 
in  1966  was  $1.  62  a  pound,    or  5.  2  percent  greater  than  the  $1.  54  a  pound  reported  in  1965. 

For  many  important  individual  low-  and  medium-priced  dyes,    for  which  statistics  are 
given  in  table  8A,    production  was  larger  in  1966  than  in  1965.    The  output  of  Vat  Black  27  and 
Acid  Blue  9  more  than  doubled  in  1966  compared  with  1965.    The  output  of  Vat  Black  27  was   1.  5 
million  pounds  in  1966  compared  with  747,  000  pounds  in  1965;  that  of  Acid  Blue     9  was    1.  5  mil- 
lion pounds  in  1966,    compared  with  748,000  pounds  in  1965.    Other  important  dyes  whose  output 
was   substantially  larger  in  1966  than  in  1965  were  Vat  Green  8  (76.  1   percent),    Vat  Yellow  4 
(36.  0  percent),    Vat  Green  3  (35.  2  percent).    Disperse  Yellow  3  (33.  7  percent).  Vat  Black  25 
(31.  5  percent).    Direct  Brown  95  (30.  5  percent),    Basic   Yellow  11   (27.  0  percent),    Basic  Brown  4 
(26.4  percent)  and  Direct  Yellow   106  (17.2  percent). 

On  the  other  hand,    the  output  of  a  few  important  dyes  was   smaller  in  1966  than  in  1965.    Pro- 
duction of  Vat  Blue   18  was  929,  000  pounds  in  1966,    or  35.  2  percent  less  than  the   1.  4  million 
pounds  produced  in  1965;  that  of  Mordant  Black  17  was   656,000  pounds,    or  32.4  percent  less  than 
the  970,000  pounds  produced  in  1965.    The  output  of  Vat  Orange   15  was  27.  5  percent  smaller  in 
1966  than  in  1965;  that  of  Coupling  Component  7  was  21.  5  percent  smaller;  and  that  of  Direct 
Blue  2  was   19.  0  percent  smaller. 


See  also  table  8B,  pt.  IH,  which  lists  these  products  and  identifies  the  manufacturers,  and  the  appendix  (table  23),  which  shows  imports 
of  dye«  during  the  years  1965-66. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE 


-Bemenoid  dyes.-  U.S.  production  and  sales,  1966 


[Listed  below  are  all  benzenoid  dyes  for  which  any  reported  data  on  production  or  sales  may  be  published.  (Leaders 
are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were  re- 
ported. )  Table  8B  in  pt.  Ill  lists  all  dyes  for  which  data  on  production  or  sales  were  reported  and  identifies  the 
manufacturer  of  each] 


Production 


Sales 


Grand  total 

ACID  DYES 

Total — 

Acid  yellow  dyes,  total 

Acid  Yellow  3 - 

Acid  Yellow  11 

Acid  Yellow  17 — 

Acid  Yellow  23 — - 

Acid  Yellow  36— — ■ 

Acid  Yellow  ^0 — 

Acid  Yellow  <i2 ■ 

Acid  Yellow  AA ■ 

Acid  Yellow  5A ■ 

Acid  Yellow  73 

Acid  Yellow  99 

Acid  Yellow  12^ - — ■ 

Acid  Yellow  151— 

All  other— - 

Acid  orange  dyes,  total 

Acid  Orange  1 

Acid  Orange  7 

Acid  Orange  8 

Acid  Orange  10 

Acid  Orange  2A 

Acid  Orange  60 

Acid  Orange  64 

Acid  Orange  116 - 

All  other- - 

Acid  red  dyes,  total 

Acid  Red  1 

Acid  Red  A- - 

Acid  Red  U 

Acid  Red  18— 

Acid  Red  26 

Acid  Red  37— 

Acid  Red  73 

Acid  Red  85 

Acid  Red  87 

Acid  Red  88 

Acid  Red  89 

Acid  Red  llA — 

Acid  Red  137 

Acid  Red  151 - 

Acid  Red  182 

Acid  Red  186 

All  other 

Acid  violet  dyes,  total 

Acid  Violet  1 

Acid  Violet  3 

Acid  Violet  7 - 

Acid  Violet  12 

Acid  Violet  49— - — 

All  other 


i ,  000 
219, 194 


4,100 


635 
414 
404 
643 
69 
54 
297 
610 


137 
59 
256 
200 
678 


J,  000 
ponnds 
204,135 


55 
637 
401 
341 
597 


dollars 
331,453 


,435 


— rnr 

112 
1,187 
805 
379 
462 
99 
109 
160 
185 
206 
239 
469 
3,892 

4,637 
119 
651 
485 
433 
819 
153 


580 
321 
197 
221 


See  footnotes  at  end  of  table. 


DYES 


TABLE  8A.  ~-Bemenoid  dyes :  U.S.  production  and  sales,  i 966- -Continued 


Production 


ACID  DYES— Continued 

Acid  blue  dyes,    total 

Acid  Blue  7— 

Acid  Blue  9 

Acid  Blue  25 - 

Acid  Blue  40— 

Acid  Blue  41 

Acid  Blue  43 

Acid  Blue  45 

Acid  Blue  62- 

Acid  Blue  78 

Acid  Blue  90 

Acid  Blue  113-— - 

Acid  Blue  158  and  158A- 

All  other - 

Acid  green  dyes,  total 

Acid  Green  3 

Acid  Green  9 

Acid  Green  12 

Acid  Green  16 - 

Acid  Green  20 

Acid  Green  25 

All  other 

Acid  brown  dyes,  total 

Acid  Brown  14 

All  other — 

Acid  black  dyes,  total — 

Acid  Black  1 

Acid  Black  24 

Acid  Black  48— - 

Acid  Black  107 

All  other - 

AZOIC  DYES  AND  COMPONENTS 

Total 

Azoic  Yellow  1 

Azoic  Orange  3 

Azoic  red  dyes,  total 

Azoic  Red  1— — - 

Azoic  Red  6 

All  other -  — 

Azoic  Violet  1 - 

Azoic  Blue  2 

Azoic  Blue  3 

Azoic  Brown  9 

Azoic  black  dyes 

All  other  azoic  compositions 


■  Diazo  Component 
(Fast   Color  Base 


Total 

Azoic  Diazo  Component  4,  base- 
Azoic  Diazo  Component  9,  base-- 
Azoic  Diazo  Component  10,  base- 
Azoic  Diazo  Canponent  12,   baee- 


92 
1,514 


255 
1,167 


4,623 


l,2iA 
106 
26 
205 

3,072 


1,920 
168 
263 
156 
749 
405 

5,502 


3,271 


301 

104 

1,025 

1,428 


443 
1,480 


1,298 
177 
149 


354 
517 
321 


See  footnotes  at  end  of  table. 


SYNIHETIC  ORGANIC  CHEMICALS,  1966 
TABLE  8A.  --Benzenoid  dyes.-  U.S.  production  and  sales,  i 966- -Continued 


Eye 


Production 


AZOIC  DYES  AND  COMPONENTS— Continued 


(Fast  Col 


sj— Continued 


Azoic  Dlazo  Component  13,  base 

Azoic  Dlazo  Component  32,  base 

Azoic  Diazo  Component  48,  base 

All  other  azoic  diazo  components,  bases- 


(Fa: 


Color  Sal 


Salt 


Total— 

Azoic  Diazo  Component  1,  salt 

Azoic  Dlazo  Component  2,  salt 

Azoic  Diazo  Component  3,  salt 

Azoic  Diazo  Component  5,  salt 

Azoic  Dlazo  Component  6,  salt 

Azoic  Diazo  Component  8,  salt 

Azoic  Diazo  Component  9,  salt 

Azoic  Dlazo  Component  10,  salt 

Azoic  Dlazo  Component  12,  salt 

Azoic  Dlazo  Component  13,  salt 

Azoic  Diazo  Component  28,  salt 

Azoic  Diazo  Component  36,  salt 

Azoic  Diazo  Coniponent  44,  salt 

Azoic  Diazo  Component  48,  salt 

Azoic  Diazo  Component  49,  salt 

All  other  azoic  diazo  congjonents,  salts- 

Azoic  Coupling  Componen 
(Naphthol   ,4S  and  Deriiati 

Total 

Azoic  Coupling  Component  2 

Azoic  Coupling  Component  3 

Azoic  Coupling  Component  4 

Azoic  Coupling  Component  5 

Azoic  Coupling  Component  7 

Azoic  Coupling  Component  11 

Azoic  Coupling  Component  14 

Azoic  Coupling  Component  17 

Azoic  Coupling  Component  18 

Azoic  Coupling  Component  19 

Azoic  Coupling  Component  20 

Azoic  Coupling  Component  21 

Azoic  Coupling  Component  24 

Azoic  Coupling  Component  29 

Azoic  Coupling  Component  43 

All  other  azoic  coupling  components 

BASIC  DYES 

Total — 

Basic  yellow  dyes,  total 

Basic  Yellow  2 

Basic  Yellow  11 - 

Basic  Yellow  13 - - 

All  other— - 

Basic  orange  dyes,  total 

Basic  Orange  1 

Basic  Orange  2 

See  footnotes  at  end  of  table. 


J,  (AW 

s 

di.llari. 

380 

472 

261 

463 

35 

64 

256 

584 

92 

87 

112 

23 

8 

11 

294 

294 

188 

3U 

331 

381 

40 

51 

58 

117 

132 

135 

267 

251 

163 

88 

82 

117 

80 

67 

74 

257 

298 

220 

344 

344 

404 

41 

69 

8 

13 

10 

13 

70 

55 

175 

453 

342 

543 

6,669 


1,027 

2,184 

603 

2,855 

2.657 


TABLE  8A.  --Benzenoid  dyes :  U.S.  production  and  sales ,  7966- -Continued 


BASIC  DYES— Continued 


Basic  orange  dyes--Continued 

Basic  Orange  21 

All  other— — - 

Basic  red  dyes,  total 

Basic  Red  14 

All  other 

Basic  violet  dyes,  total 

Basic  Violet  1 

Basic  Violet  4 -- 

Basic  Violet  16 

All  other 

Basic  blue  dyes,  total 

Basic  Blue  1 

Basic  Blue  5 

Basic  Blue  7 

Basic  Blue  9 

Basic  Blue  26 

All  other 

Basic  Green  1 

Basic  Green  4 

Basic  Brown  1 

Basic  Brown  4 

All  other  basic  dyes 

DIRECT  DYES 

Total 

Direct  yellow  dyes,  total 

Direct  Yellow  A 

Direct  Yellow  5 - 

Direct  Yellow  6 — — 

Direct  Yellow  11 

Direct  Yellow  12 

Direct  Yellow  26— - 

Direct  Yellow  28 

Direct  Yellow  29 

Direct  Yellow  44 - - 

Direct  Yellow  50 

Direct  Yellow  84 - 

Direct  Yellow  105 

Direct  Yellow  106 

All  other 

Direct  orange  dyes,  total 

Direct  Orange  1 

Direct  Orange  8 

Direct  Orange  15 

Direct  Orange  26 

Direct  Orange  29 

Direct  Orange  34 

Direct  Orange  37 

Direct  Orange  39 

Direct  Orange  72 

Direct  Orange  73 

Direct  Orange  81 

Direct  Orange  102 

All  other 


112 
1,190 


936 
3,036 


8,217 


925 
415 
11 
287 


225 

877 

2,580 

2,206 


1,033 
2,957 

5,922 

1,129 

112 

377 

4,304 

4,428 


259 

1,562 

330 


909 
477 

1,280 
993 

1,047 
24 
537 
UO 
908 
936 
525 
544 

1,482 

3,695 

5,142 


131 
319 
702 
364 
261 
560 
1,662 


See  footnotes  at  end  of  table. 


20 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 
TABLE  BA.--Bemenoid  dyes :  U.S.  production  and  sales ,  i566--Continued 


Production 


DIRECT  DYES— Continued 

Direct  red  dyes,   total 

Direct  Red  1 

Direct  Red  2 

Direct  Red  4 

Direct  Red  10 - - 

Direct  Red  13 - 

Direct  Red  16 - - 

Direct  Red  23 - - 

Direct  Red  2A - 

Direct  Red  26 - 

Direct  Red  28 — 

Direct  Red  31 

Direct  Red  37 — 

Direct  Red  39 - 

Direct  Red  72— - 

Direct  Red  75 

Direct  Red  79— - 

Direct  Red  80 

Direct  Red  81 

Direct  Red  83-~ — 

Direct  Red  84— 

Direct  Red  122 

Direct  Red  149 — 

Direct  Red  153 

All  other— - - 

Direct  violet  dyes,  total 

Direct  Violet  1 

Direct  Violet  9— — 

All  other 

Direct  blue  dyes,  total 

Direct  Blue  1 

Direct  Blue  2 

Direct  Blue  6 

Direct  Blue  8 

Direct  Blue  15 

Direct  Blue  22 

Direct  Blue  24 

Direct  Blue  25 

Direct  Blue  67- - - — 

Direct  Blue  76 

Direct  Blue  78 

Direct  Blue  80 

Direct  Blue  86 

Direct  Blue  98 

Direct  Blue  120  and  120A 

Direct  Blue  126 

All  other 

Direct  green  dyes,  total 

Direct  Green  1 

Direct  Green  6 

Direct  Green  8 

Direct  Green  12 

All  other— 

Direct  brown  dyes,   total 

Direct  Brown  1 

Direct  Brown  lA 

Direct  Brown  2 

Direct  Brown  6 

Direct  Brown  31 

Direct  Brown  74 

Direct  Brown  95 


pounds 

4,406 

221- 

351 
33 


437 

1,821 

555 


595 
1,1A3 
159 
313 
292 
1,882 

1,526 


608 
2,046 


4,376 
221 
379 
33 


21 
193 
130 

7,650 
404 

1,753 
547 
48 


24 


469 
146 
535 

1,054 
162 
268 
233 

1,807 

1,414 


2,061 


9,566 


358 

82 

1,586 


108 
864 
404 
817 

1,608 
283 
580 
691 

3,167 

3,305 
366 
588 

54 


TS7" 
137 
337 
118 
AM 
111 
722 


See  footnotes  at  end  of  table. 


DYES 
TABLE  8A.  --Benzenoid  dyes.-  U.S;  production  and  sales ,  i966- -Continued 


Production 


Quantity  Value 


DIRECT  DYES— Continued 

Direct  brown  dyes--Continued 

Direct  Brown  111 

Direct  Brown  15^ 

All  other - - 

Direct  black  dyes,  total 

Direct  Black  A— - 

Direct  Black  9 - - 

Direct  Black  19 - — 

Direct  Black  22 - 

Direct  Black  38 

Direct  Black  51 — 

Direct  Black  80 — 

All  other - 

DISPERSE  DYES 

Total - 

Disperse  yellow  dyes,  total 

Disperse  Yellow  3 

Disperse  Yellow  5 

Disperse  Yellow  23 

Disperse  Yellow  33— 

Disperse  Yellow  34 

Disperse  Yellow  42 

All  other 

Disperse  orange  dyes,  total 

Disperse  Orange  3 

Disperse  Orange  5 

Disperse  Orange  17 

All  other - 

Disperse  red  dyes,  total 

Disperse  Red  1 

Disperse  Red  5 

Disperse  Red  11 

Disperse  Red  13 

Disperse  Red  15 

Disperse  Red  17 

Disperse  Red  60 

All  other 

Disperse  violet  dyes,  total 

Disperse  Violet  1 

Disperse  Violet  4 

Disperse  Violet  27— 

All  other 

Disperse  blue  dyes,  total 

Disperse  Blue  1 

Disperse  Blue  3 

Disperse  Blue  7 

Disperse  Blue  64 

All  other 

Disperse  black  dyes,  total 

Disperse  Black  1 

Disperse  Black  9 

All  other - 

All  other  disperse  dyes 


375 
(A 

121 

766 
6,215 

101 
1,926 

798 


1,725 


6,768 


2A5 

1,833 

326 

131 

4,233 

1,839 

156 

1,279 

404 


10,501 


5,930 


2or 

1,779 
353 
105 

3,488 


U2 

1,716 

241 


702 
4,813 

252 
1,718 
1,860 


6,452 


2,386 
124 
260 
553 
393 
862 

1,874 

1,983 


193 

320 

170 

1,300 

6,947 


356 
108 
225 
36 
304 
171 
339 
5,408 

939 


18,501 


768 
2,848 
2,473 

302 
12,110 

2,683 
25D1 

2,433 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 
TABLE  8A.  —Bemenoid  dyes.-  U.S.  production  and  sales,  i566--Continued 


Dye 


Production 


FIBER-REACTIVE  OTES 

Fiber-reactive  dyes,  total 

Reactive  blue  dyes 

All  other  reactive  dyes 

FLUORESCENT  BRIGHTENING  AGENTS 
Total 

Fluorescent  Brightening  Agent  28 

All  other  fluorescent  brightening  agents 

FOOD,  DRUG,  AND  COSMETIC  COLORS 
Total 

Food,   Drug,    and  Cosmetic  Dyes 

Total 

rC&C  Blue  No.   1 - - 

FD&C  Blue  No.   2 - 

FDScC  Red  No.   2 - 

FD&C  Red  No.   3 

FDScC  Red  No.   4 - - 

FD&C  Yellow  No.   5 - 

FDSrC  Yellow  No.   6 

All  other  food,  drug,   and  cosmetic  dyes 


Drug  and  Cosme t i 
and  Cos 


and  External  Drag 
eticDyes 


Total - 

nScC  Orange  No.  4 

E&C  Red  No.  7 

E&C  Red  No.  19 

mC  Red  No.  21 

E&C  Red  No.  36 

All  other  drug  and  cosmetic  and  external  drug  and  cosmetic 
dyes 

MDHDANT  DYES 

Total 

Mordant  yellow  dyes,  total 

Mordant  Yellow  8- 

Mordant  Yellow  16 

All  other - 

Mordant  orange  dyes,  total 

Mordant  Orange  1 

All  other 

Mordant  red  dyes,   total 

Mordant  Red  7 

Mordant  Red  9 

All  other 

Mordant  blue  dyes,  total 

Mordant  Blue  1 

All  other 


1 .  000 

1,909 


612 
1,297 


1,240 
21,972 


1.000 
pounds 
1^ 


1,549 
19,280 


3,352 
4,554 


2,364 
38,339 


55 

65 

683 

28 

24 

243 

1,090 

958 

2,543 

138 

125 

1,655 

17 

81 

773 

783 

2,291 

867 

772 

2,024 

181 

115 

585 

See  footnotes  at  end  of  table. 


DYES 
TABLE  8A.  --Beruenoid  dyes:  U.S.  production  and  sales ,  1966 --Continued 


MORDANT  DYES— Continued 


Mardant  brown  dyes,   total 

MDrdant  Brown  1 

Mordant  Brown  33— — - 

Mordant  Brown  40 

All  other 

Mordant  black  dyes,  total 

Ktordant  Black  3 

Mordant  Black  11 

Mordant  Black  13— - 

Mordant  Black  17—- — 

Ifcrdant  Black  38 

All  other - 

All  other  mordant  dyes 

SOLVENT  DYES 

Total 

Solvent  yellow  dyes,  total 

Solvent  Yellow  2 

Solvent  Yellow  3 

Solvent  Yellow  lA 

All  other - - 

Solvent  orange  dyes,  total 

Solvent  Orange  3 

Solvent  Orange  7 

All  other— 

Solvent  red  dyes,  total 

Solvent  Red  24 - 

Solvent  Red  26 

Solvent  Red  49 

All  other 

Solvent  violet  dyes,  total 

Solvent  Violet  8 — 

All  other - — 

Solvent  green  dyes,  total 

Solvent  Green  3 

All  other - - 

Solvent  brown  dyes,  total 

Solvent  Brown  12 

All  other 

All  other  solvent  dyes 

SULFUR  DYES 2 

Total - 

Sulf\ir  Red  6- 

Sulfur  Blue  7 — 

Suli\ir  Blue  11 - — 

Sulfur  Black  1 - 

All  other  sulfur  dyes 


2,112 

41 
656 


62 
6,747 


1,638 

18,180 


2,529 
26 
1,666 
50 
557 
9 
221 


22 


3,180 


590 
1,358 


10 
1,585 
17,503 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 
■  Benzenoid  dyes:  U.S.  production  and  sales,  iS66- -Continued 


Production 


VAT  DYES 

Total 

Vat  yellow  dyes,  total 

Vat  Yellow  2,  8-1/2^6 

Vat  Yellow  4,  12-1/2^- 

Solubllized  Vat  Yellow  A 

All  other 

Vat  orange  dyes,  total 

Vat  Orange  1,  20^6 — 

Solubilized  Vat  Orange  1,  2bf, 

Vat  Orange  2,  12^ 

Vat  Orange  3,  13-1/2^ 

Vat  Orange  5,  lOit- -- 

Solubilized  Vat  Orange  5,  30ifc---- 

Vat  Orange  7,  lilt- 

Vat  Orange  9,  12^6 

Vat  Orange  15,  10^ 

All  other 

Vat  red  dyes,  total 

Vat  Red  1,  13^« 

Vat  Red  10 

Vat  Red  13,  ll^fr- 

Vat  Red  15,  10* 

Vat  Red  32,  20^6- 

All  other 

Vat  violet  dyes,  total--- 

Vat  Violet  1,  lli^ 

Vat  Violet  2,  20*- 

Vat  Violet  9,  12* - 

Vat  Violet  13,  6-1/4* 

Vat  Violet  17 — 

All  other 

Vat  blue  dyes,  total- 

Vat  Blue  6,  8-1/3* 

Vat  Blue  16 — 

Vat  Blue  18,  13*- 

Vat  Blue  20,  lA*- 

All  other --- 

Vat  green  dyes,  total 

Vat  Green  1,  6* 

Vat  Qreen  3,  10*-- 

Solubilized  Vat  Green  3,  26* 

Vat  Green  8,  8-1/2*-- 

Vat  Green  9,  12-1/2* 

All  other --- 

Vat  brown  dyes,  total 

Vat  Brown  1,  11* 

Vat  Brown  3,  11*- - 

Vat  Brown  5,  13*-  — 

All  other 

Vat  black  dyes,  total 

Vat  Black  9,    16*^ 

Vat  Black  25,    12-1/2*- ■ 

Vat  Black  27,    12-1/2*- ■ 

All  other 

All  other  dyes-' 


1 .  000 
57,<i56 


929 
1,088 
12,652 

U,858 


i,052 
5,369 
8 
3,549 
1,371 
509 

4,279 


5,937 
1,523 
3,187 


X516 
807 


16,808 


941 
1,004 
11,645 

13,677 


3,916 

5,002 

11 

2,954 


2,131 
10,526 


402 
1,153 
2,237 


1,207 
1.839 


3,305 


2,586 
3,675 
73 
2,325 
1,267 
379 


1,031 
2,152 


4,431 
1,670 
3,111 


''■  Calculated  from  rounded  figures. 

^  Production  and  sales  quantities  of  C.I.  Leuco  Sulfur  and  C.I.  Solubilized  Sulfur  dyes  are  reported  in  terms  of 
the  usual  commercial  concentration  of  the  C.I.  Sulfur  dyes. 

•'  Includes  oxidation  bases,  ingrain  dyes,  and  miscellaneous  dyes.  Statistics  for  these  groups  of  dyes  may  not  be 
published  separately  because  publication  would  disclose  information  received  in  confidence. 


DYES  25 

Table  9  summarizes  production  and  sales  of  dyes  in  1966,    by  class  of  application.    Four 
application  classes  of  dyes  accounted  for  approximately  two-thirds  of  all  the  dyes   produced.    Vat 
dyes  accounted  for  26.  2  percent  of  the  total;  direct  dyes,    for  17.  0  percent;  and  fluorescent 
brighteners  and  acid  dyes,    each  for   10.  6  percent  of  the  above  classes,    the  output  of  vat  dyes 
remained  about  the  same  in   1966  as  in  1965.    The  output  of  fluorescent  brighteners  was    19.  5  per- 
cent larger  in  1966  than  in   1965;  that  of  acid  dyes  was    13.  7  percent  larger;  and  direct  dyes  was 
3. 5  percent  larger. 

Of  the  remaining  classes,    the  output  of  the  fiber-reactive  dyes  was   1.  9  million  pounds  in 
1966,    or  20.  4  percent  more  than  the   1.  6  million  pounds   produced  in  1965.    Production  of  food, 
drug,    and  cosmetic  colors  was    15.  1  percent  larger  in  1966  than  in   1965;  solvent  dyes,    9.  5  per- 
cent larger;  and  sulfur  dyes,    7.  0  percent  larger.    On  the  other  hand,   the    output  of  mordant  dyes 
was   9.6  percent  smaller  in  1966  than  in  1965;  and  that  of  the  azoic  dyes  and  components,    2.9 
percent  smaller. 

Table  10  shows  production  and  sales  of  dyes,  by  chemical  class.  In  1966,  three  chemical 
classes  of  dyes  accounted  for  two-thirds  of  all  the  dyes  produced:  Azo  dyes  accounted  for  31.8 
percent  of  the  total;  anthraquinone  dyes,  for  24.  7  percent;  and  stilbene  dyes,  for  11.2  percent. 
The  output  of  each  of  these  three  classes  was  larger  in  1966  than  in  1965:  Stilbene  dyes  were 
15. 0  percent  larger;  anthraquinone  dyes,  13. 7  percent  larger;  and  azo  dyes,  4. 8  percent  larger. 
Of  the  remaining  chemical  classes  for  which  statistics  are  published,  the  output  of  sulfur  dyes 
was  7.  0  percent  larger  in  1966  than  in  1965,  and  that  of  triarylmethane  dyes  was  18.  6  percent 
larger.  On  the  other  hand,  the  output  of  phthalocyanine  dyes  was  18.  8  percent  smaller  in  1966 
than  in  1965,    that  of  indigoid  dyes,    8.  5  percent  smaller;  and  azoic  dyes,    3.  7  percent  smaller. 


Benzenoid  dyes:   U.S.  production  and  sales,  by  class  of  application,  1966 


Class  of  application 


Production 


Total— 

Icld - 

^zolo  dyes  and  conjionents: 

Azoic   compositions 

Azoic  dlazo  components,   bases    (Fast  color  bases) 

Azoic  dlazo  components,   salts    (Fast  color  salts) 

Azoic  coupling  components    (Naphthol  AS  and  derivatives )- 

Basic 

Direct 

Fiber-reactive 

Fluorescent  brightening  agents 

Food,   drug,   and  cosmetic  colors 

ilordant 

Solvent 

Sulfur^ 

Vat - - 

Ml  other^— - - - 


i .  000 
pounds 
20^,135 


23, 19"^ 

2,376 
1,^93 

3,071 
11,136 
37,343 
16,696 

1,909 
23,212 

3,363 

4,288 
10,772 
19,959 
57,456 
482 


20,410 

2,204 
1,334 
2,401 
2,478 
10,420 
36,733 
14,849 
1,899 
20,829 
3,109 
3,509 
9,827 
19,236 
54,431 
466 


43,762 

4,473 
2,185 
2,676 
4,978 
26,674 
56,920 
38,060 
7,906 
40,703 
11,474 
5,285 
16,685 
11,034 
57,875 
763 


pound 
$1.62 


2.03 
1.64 
1.11 
2.01 
2.56 
1.55 
2.56 


Calculated  from  rounded  figures. 

^  Production  and  sales  quantities  of  C.I.  Leuoo  Sulfur  and  C.I.  Solubillzed  Sulfur  dyes  are  reported  in  terms  of 
the  usual  commercial  concentration  of  the  C.I.  Sulfur  dyes. 

^  Includes  oxidation  bases,  ingrain  dyes,  and  miscellaneous  dyes.  Statistics  for  these  groups  of  dyes  may  not  be 
published  separately  becauses  publication  would  disclose  information  received  in  confidence. 


26 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 
TABLE  10.  --  Benzenoid  dyes:    U.S.  production  and  sales,  by  chemical  class,  1966 


Chemical  class 


Total 

Anthraqulnone — 

Azo,  total 

Monoazo 

Dlsazo 

Trisazo 

Polyazo 

Not  specified 

Azoic 

Cyanine 

Indigold 

Ketone  tmine 

Me  thine 

Nitro 

Oxazine 

Phthalocyanine- 

Qulnoline 

Stllbene 

Sulfur^ — 

Thiazole 

Triarylmethane- 

Xanthene 

All  other^ 


1 .  000 
pounds 
219,19^ 


69,709 


25, 6U 
20,070 
13,7<19 
2,720 
7,356 

9,39-; 

5U 
5,251 

502 
1,281 
1,^29 

252 
1,783 

523 
24,518 
19,959 

586 
7,936 
1,874 
19,456 


1,000 
dollars 
331,453 


66,277 


23,624 
19,295 
13,341 
2,935 
7,082 

8,430 

505 

5,604 


176 

1,787 

597 

21,760 

19,236 

549 

6,592 

911 

17,564 


121,299 


49,679 
35,284 
15,253 
5,002 
16,081 

14,344 
1,636 
3,590 
1,051 
4,590 
2,519 
789 
4,660 
1,934 

35,143 

11,034 
1,176 

15,037 
4,585 

22,565 


1.83 


2.10 
1.83 
1.14 
1.70 
2.27 

1.70 
3.24 

.64 
2.08 
3.46 
1.83 
4.48 
2.61 
3.24 
1.62 

.57 
2.14 
2.28 
5.03 


Calculated  from  roimded  figures. 

^  Production  and  sales  quantities  of  C.I.  Leuco  Sulfur  and  C.I.  Solubilized  Sulfur  dyes  are  reported  in  terms  of 
the  usual  commercial  concentration  of  the  C.I.  Sulfur  dyes. 

•'  Includes  acrldine,  aminoketone,  azlne,  coumarin,  hydroxyketone ,  nitroso,  oxidation  bases,  thiazine,  vat  sulfur, 
and  miscellaneous  dyes.  Statistics  for  these  groups  of  dyes  may  not  be  published  separately  because  publication  would 
disclose  Information  received  in  confidence. 

Pigments 


As  the  terms  are  used  in  this  report,    synthetic  organic   pigments  are  toners  and  lakes  derived 
in  whole  or  in  part  from  benzenoid  chemicals  and  colors.    They  are  used  in  paints  ancj  related 
products,    in  printing  inks,    and  in  plastics  and  resin  materials. 

Statistics  on  production  and  sales  of  all  benzenoid  pigments  in  1966  are  given  in  table  HA  . 
Statistics  on  sales  of  a  few  selected  pigments  by  commercial  forms  (dry  full-strength  form,  dry 
extended  form,  dry  dispersions,  aqueous  dispersions,  and  flushed  colors)  are  given  in  table  12. 
Prior  to  1961,  statistics  for  toners  included  the  quantities  and  values  of  extenders  and  diluents. 
Beginning  in  1961,  data  were  collected  for  both  the  full-strength  and  extended  toners  on  a  full- 
strength-toner-content  basis.  Individual  toners  and  lakes  are  identified  in  this  report  by  the 
names  used  in  the  second  edition  of  the  Colour  Index. 

Total  production  of  benzenoid  pigments  in  1966  was  51.  1  million  pounds--6.4  percent  more 
than  the  48.  0  million  pounds  produced  in  1965  and  16.  1  percent  more  than  the  44.  1  million  pounds 
produced  in  1964.  Total  sales  of  benzenoid  pigments  in  1966  amounted  to  43.  3  million  pounds, 
valued  at  $107.  6  million,  compared  with  38.  0  million  pounds,  valued  at  $93.  6  million,  in  1965 
and  35.  1  million  pounds,  valued  at  $84.  1  million,  in  1964.  In  terms  of  quantity,  sales  of  ben- 
zenoid pigments  in  1966  were  13.  9  percent  larger  than  in  1965  and  23.  5  percent  larger  than  in 
1964;  in  terms  of  value,  sales  in  1966  were  14.  9  percent  larger  than  in  1965  and  27.  9  percent 
larger  than  in  1964. 

Production  of  toners  in  1966  amounted  to  46.  6  million  pounds--6.  7  percent  more  than  the 
43.  7  million  pounds  reported  for   1965.    Sales  in  1966  were  39.  1  million  pounds,    valued  at  $103.  6 
million,    compared  with  34.  1  million  pounds,    valued  at  $89.9  million,    in  1965.    Sales  in  1966 
were  thus    14.  7  percent  larger  than  those  in  1965  in  terms  of  quantity,    and   15.  3  percent  larger  in 
terms   of  value.    The  individual  toners  listed  in  the  report  which  were  produced  in  the  largest 
quantities  in  1966  were  Pigment  Blue  15,   alpha  form,    5.  0  million  pounds;  Pigment  Green  7,    4.  1 
million  pounds;  Pigment  Yellow  12,   4.  1  million  pounds;  Pigment  Red  49,   barium  toner,    3.5 


-•  See  also  table  IIB,  pt.  in,  which  lists  these  products  i 
of  benzenoid  pigments  during  the  years  1965-66. 


identifies  the  manufacturers,  and  table  23  in  the  appendix,  which  shows  imports 


PIGMENTS 


million  pounds;  Pigment  Blue   19,    2.  7  million  pounds;  Pigment  Blue   15,    beta  form,    2.  7  million 
pounds;  and  Pigment  Red  48,    2.  5  million  pounds. 

Production  of  lakes  totaled  4.  5  million  pounds  in  1966--3.  5  percent  more  than  the  4.  3  mil- 
lion pounds   reported  for   1965.    Sales  of  lakes  in  1966  amounted  to  4.  2  million  pounds,    valued  at 
$4.  0  million,    compared  with  sales  in  1965  of  3.  9  million  pounds,   valued  at  $3.  8  million.    Sales 
in  1966  were  thus   7.  2  percent  larger  than  those  in  1965  in  terms  of  quantity,    and  5.  5  percent 
larger  in  terms  of  value. 

For  each  of  14  selected  pigments,    or  groups  of  pigments,    table  12  gives  data  on  sales  by 
commercial  forms.    Pigment  Yellow   12,    Pigment  Red  90,    and  Pigment  Blue   19  were  sold  princi- 
pally in  the  flushed  form.    The  remaining  11   pigments,    or  groups  of  pigments,    for  which  statistics 
are  published  were  sold  principally  in  the  dry  full-strength  form.    Statistics  on  sales  by  commer- 
cial forms  could  not  be  published  for  Pigment  Red  49,    sodium  toner,    or  for  Pigment  Blue  24 
without  revealing  the  operations   of  individual  companies. 

TABLE  llA.--BenzeTioid  pigments.-  U.S.  production  and  sales ,  1966 

[Listed  below  are  all  toners  and   lakes  for  which  any  reported  data  on  production  or  sales  may  be  published.    (Leaders 
are  used  where  the   reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were  re- 
ported.)   Table  ILB  in  pt.    Ill   lists  all  toners  and   lakes  for  which  data  on  production  or  sales  were  reported  and 
identifies  the  manufacturer  of  each] 


Production 


Grand  total 

TONERS 

Total — 

Yellow  toners,   total 

Hansa  yellows,   total 

Pigment  Yellow  1,  C.I.  11  680—- 
Pigment  Yellow  3,   C.I.    11  710— 

Pigment  Yellow  73 

Pigment  Yellow  7-4,   C.I.   11  741— 

Other  Hansa  yellows 

Benzidine  yellows,   total 

Pigment  Yellow  12,  C.I.  21  090— 
Pigment  Yellow  13,  C.I.  21  100— 
Pigment  Yellow  14,  C.I.  21  095— 
Pigment   Yellow  17,   C.I.    21  105— 

Other  benzidine  yellows 

All  other 

Orange  toners,  total 

Pigment  Orange  2,  C.I.  12  060 

Pigment  Orange  5,  C.I.  12  075 

Pigment  Orange  13,  C.I.  21  110 

Pigment  Orange  16,  C.I.  21  160 

(Vat  Orange  7),  C.I.  71  105 

All  other 

Red  and  violet  toners,  total 

Naphthol  reds,  total 

Pigment  Red  2,  C.I.  12  310 

Pigment  Red  5,  C.I.  12  490 

Pigment  Red  13,  C.I.  12  395 

Pigment  Red  17,  C.I.  12  390 

Pigment  Red  18,  C.I.  12  350 

Pigment  Red  22,  C.I.  12  315 

Pigment  Red  23,  C.I.  12  355 

Other  naphthol  reds 

Pigment  Red  1,  C.I.  12  070,  dark— 
Pigment  Red  1,  C.I.  12  070,  light - 

Pigment  Red  3,  C.I.  12  120 

See  footnotes  at  end  of  table. 


257 

113 

134 

6,357 

4,117 

317 

1,409 

273 

241 

290 

830 
35 
248 
155 
222 


223 

217 

1,843 


2,410 
763 
252 

371 
1,024 
10,450 
5,138 

718 
2,866 

588 
1,140 
1,590 


55 
315 
481 
592 
239 
1,208 

44,621 

2,891 

121 

338 


246 
526 

1,447 
218 
215 

2,325 


pound 

$2.48 


2.76 

-"2752 

1.93 

2.29 

3.44 
2.98 
2.52 
2.16 
3.42 
2.46 
3.34 
5.0; 
12.14 

3.79 
1.49 
1.56 
3.29 
2.77 
21.73 
7.90 

2.37 
4.39 
2.63 
5.04 
5.00 
3.09 

'  2.96 
3.35 
6.05 
1.22 

1.20 
1.52 


28  SYNTHETIC  ORGANIC  CHEMICALS,  1966 

TABLE  UA.  —Bemenoid  pigments.-    U.S.  production  and  sales,  i 966- -Continued 


Pigment 


Production 


Sales 


TONERS— Continued 

Red  and  violet  toners — Continued 

Pigment  Red  4,  C.I.  12  085 - -- 

Pigment  Red  6,  C.I.  12  090 - 

Pigment  Red  38,  C.I.  21  120 - - 

Pigment  Red  48,  C.I.  15  865 

Pigment  Red  49,  C.I.  15  630: 

Barium  toner 

Calcium  toner 

Sodium  toner 

Pigment  Red  52,  C.I.  15  860 - - 

Pigment  Red  53,  C.I.  15  585,  barium  toner 

Pigment  Red  54,  C.I.  14  830,  calcium  toner 

Pigment  Red  57,  C.I.  15  850,  calcium  toner 

Pigment  Red  63,  C.I.  15  880— - 

Pigment  Red  81,  C.I.  45  160,  PMA- 

Pigment  Red  81,  C.I.  45  160,  PTA -- 

Pigment  Red  90,  C.I.  45  380 

Pigment  Violet  1,  C.I.  45  170,  IMA - 

Pigment  Violet  1,  C.I.  45  170,  PTA— 

Pigment  Violet  3,  C.I.  42  535,  fugitive- 

Pigment  Violet  3,  C.I.  42  535,  FMA- — - 

Pigment  Violet  3,  C.I.  42  535,  PTA — - 

Pigment  Violet  23 

All  other 

Blue  toners,  total 

Pigment  Blue  1,  C.I.  42  595,  PUA- 

Pigment  Blue  1,  C.I.  42  595,  PTA- 

Figment  Blue  2,  C.I.  44  045,  fugitive,  MA,  and  PTA- 

Pigment  Blue  9,  C.I.  42  025,  PTA- — 

Pigment  Blue  14,  C.I.  42  600,  BJA- 

Pigment  Blue  15,  C.I.  74  160,  alpha  form 

Pigment  Blue  15,  C.I.  74  160,  beta  form 

Pigment  Blue  19,  C.I.  42  750A - 

Pigment  Blue  22,  C.I.  69  810 

Pigment  Blue  25,  C.I.  21  180 — 

All  other - 

Green  toners,  total 

Pigment  Green  1,  C.I.  42  040,  MA — 

Pigment  Green  1,  C.I.  42  040,  PTA - 

Pigment  Green  2,  C.I.  42  040  and  49  005,  PMA- 

Pigment  Green  2,  C.I.  -42  040  and  49  005,  PTA- 

Pigment  Green  4,  C.I.  42  000,  FMA 

Pigment  Green  4,  C.I.  42  000,  PTA- - 

Pigment  Green  7,  C.I.  74  260 - 

Pigment  Green  8,  C.I.  10  006 

Pigment  Green  36,  C.I.  74  265 

All  other 

Brown  toners,  total 

Pigment  Brown  3,  C.I.  21  010,  IMA- 

Pigment  Brown  5,  C.I.  15  800 

All  other — - - 

Black  toners 

LAKES 

Total 

Yellow  lakes 


3,498 
1,454 
211 
1,309 
2,110 
59 
1,017 


1,507 
99 
63 


4,113 
220 
208 
219 

189 


00 

1,000 

ds 

dollars 

274 

386 

34 

53 

128 

571 

2,443 

4,500 

3,415 

3,331 

1,419 

1,442 

267 

273 

1,226 

1,836 

1,729 

2,223 

67 

153 

867 

1,290 

53 

100 

269 

1,649 

146 

894 

812 

1,508 

99 

293 

57 

379 

560 

815 

355 

1,054 

39 

174 

74 

1,412 

1,956 

14,636 

2,369 

2,637 

37 


35 

566 

11,159 

7,166 

6,196 

684 

'  1,153 


10,634 
240 
706 


See  footnotes  at  end  of  table. 


PIGMENTS 


TABLE  UK.— Bemenoid  pigments:    U.S.  production  and  sales,  i966— Continued 


LAKES— Continued 


Red  lakes: 

Pigment  Red  60,  C.I.  16  105- 
■pigment  Red  83,  C.I.  58  000- 
(Aoid  Red  26),    C.I.    16  150— 


Violet  lakes,  total 

Pigment  Violet  5,  C.I.  58  055- 
All  other 


Blue  lakes:   Pigment  Blue  24,  C.I.  ^2   090- 


$1.76 
3.03 


■^  Calculated  from  rounded  figures. 

^  Includes  all  brown,  green,  and  orange  lakes,  "all  othe 
production  of  Pigment  Blue  24  and  sales  of  yellow  lakes. 


all  other"  black  lakes. 


numbers  shown  in  this  report  are  the  identifying  numbers  given  in  the  second  edition  of 


Note.— The  C.I.  fCVW„„,  Index 
the  Colour   Index. 

The  abbreviations  PMA  and  PTA  stand  for  phosphonclybdic  and  phosphotungstic  (  including  phosphotungstomolybdic) 
acids,  respectively. 


iispersions ,  and  flushed  colors,  1966 


Selected  pigments  by 


Quantity^ 


Pigment  Yellow  12,  C.I.  21  090,  total— - 

Diy  full-strength  toner 

Dry  extended  toner,  dry  dispersions,  aqueous  dispersions-'  and  flushed 
color* 

Pigment  Yellow  13,  C.I.  21  100;  Pigment  Yellow  K,  C.I.  21  095;  Pigment 

Yellow  17,  C.I.  21  105;  and  other  benzidine  yellows,  total 

Dry  full-strength  toner 

Dry  extended  toner  and  dry  dispersions* 

Aqueous  dispersions^ 

Flushed  color 

Pigment  Red  3,  C.I.  12  120,  total — 

Dry  full-strength  toner  and  dry  extended  toner* 

Aqueous  dispersions-' 

Flushed  color 

Pigment  Red  48,  C.I.  15  865,  total 

Dry  full-strength  toner 

Dry  extended  toner  and  dry  dispersions* 

Aqueous  dispersions-* 

Flushed  color 

Pigment  Red  49,  C.I.  15  630,  barium  toner,  total- - 

Dry  full-strength  toner --- 

Dry  extended  toner  and  aqueous  dispersions^  * 

Flushed  color 

Pigment  Red  49,  C.I.  15  630,  calcium  toner,  total - -- 

Dry  full-strength  toner  and  dry  dispersions* 

Aqueous  dispersions-*  and  flushed  color' 

See  footnotes  at  end  of  table. 


pounds 
2,378 
705" 

1,678 


1,230 
40 
315 


3,735 
104 
851 
570 


$2.25 
2.09 

2.31 


3704- 

2.60 
2.70 
3.00 


1.84 

"TTST 

2.09 
2.34 


1.00 
-T97- 
1.18 
1.09 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  12.  —  U.S.  sales  of  selected  dry  full-strength  colors   dry  extended  colors   dry  dispersions ,  aqueous 
dispersions,  and  flushed  colors,  i566— Continued 


Selected  pigments  by 


Quantity      Value 


Pigment  Red  -49,  C.I.  15  630,  sodium  toners- 


Pigment  Red  53,  C.I.  15  585,  barium  toner,  total 

Dry  full-strength  toner,  dry  extended  toner,  and  dry  dispersions* 
Aqueous  dispersions"'  and  flushed  color* 


Pigment  Red  90,  C.I.  45  380,  total 

Dry  full-strength  toner  and  dry  extended  toner* 
Dry  dispersions  and  flushed  color* 


Pigment  Violet  3,  C.I.  A2  535,  fugitive,  total- -- 
Dry  full-strength  toner  and  dry  extended  toner* 
Flushed  color 


Pigment  Violet  3,  C.I.  A2  535,  permanent  (PMA  and  PTA),  total- 
Dry  fuli-strength  toner 

Dry  extended  toner,  dry  dispersions  and  aqueous  dispersions-' 
Flushed  color 


Pigment  Blue  15,  C.I.  7i   160, 

Dry  full-strength  toner 

Dry  extended  toner 

Dry  dispersions 

Aqueous  dispersions^ 

Flushed  color 


alpha  form,  total- 


Pigment  Blue  15,  C.I.  V'i  160,  beta  form,  total 

Dry  full-strength  toner 

Dry  extended  toner,  dry  dispersions  and  aqueous  dispersions-' 
Flushed  color 


Pigment  Blue  19,  C.I.  42  750A,  total 

Dry  full-strength  toner  and  dry  extended  toner*- 
Aqueous  dispersions-'  and  flushed  color* 


Pigment  Blue  24,  C.I.  42  090*- 


Pigment  Green  7,  C.I.  74,  260,  total- 
Dry  full-strength  toner 

Dry  extended  toner 

Dry  dispersions 

Aqueous  dispersions-' • 

Flushed  color 


1.000 
pounds 
267 


1,078 
814 
477 


1,958 
3,440 


1,607 
342 
127 

1,190 

174 


2,260 


1,516 

815 


11.489 


4,429 
2,839 

397 
2,921 

903 


3,391 
2,357 
1,418 


605 
5,591 


2,291 
10,854 


543 


1.98 

2.07 
1.97 


1.46 
1.50 
1.40 


3.14 
3.12 

4.02 


2.78 
2.52 
3.30 
3.68 
2.51 
3.76 


3.02 
3.15 
2.90 
2.97 


2.35 
2.44 
2.34 


3.16 
3.21 
3.75 
4.28 


Quantity  of  the  various  commercial  forms  is  given  in  terms  of  dry  full-strength  toner  (or  dry  lake)  content. 
^  Calculated  from  rounded  figures. 
^  Includes  presscake. 

*  Separate  data  on  these  commercial  forms  may  not  be  published  without  revealing  the  operations  of  Individual 
companies . 

Note. — The  C.I.  {Colour  Index)    numbers  shown  in  this  report  are  the  identifying  numbers  given  In  the  second 
edition  of  the  Colour  Index. 

The  abbreviations  PMA  and  PTA  stand  for  phosphomolybdic  and  phosphotungstio  (including  phosphotungstomolybdic ) 
acids,  respectively. 


MEDICINAl  CHEMICALS  31 

Medicinal  Chemicals 

Medicinal  chemicals  include  the  medicinal  and  feed  grades  of  all  organic  chemicals  having 
therapeutic  value,    whether  obtained  by  chemical  synthesis,    by  fermentation,    by  extraction  from 
naturally  occurring  plant  or  animal  substances,    or  by  refining  a  technical  grade  product.    They 
include  antibiotics  and  other  anti-infective  agents,    antihistamines,    autonomic  drugs,    cardio- 
vascular agents,    central  nervous  system  depressants  and  stimulants,    hormones  and  synthetic 
substitutes,    vitamins,    and  other  therapeutic  agents  for  human  or  veterinary  use  and  for  animal 
feed  supplements.    Statistics  on  production  and  sales  of  medicinal  chemicals  grouped  by  pharma- 
cological class  are  given  in  table   1  3A    . 

The  statistics  shown  are  for  bulk  chemicals  only;  finished  pharmaceutical  preparations  and 
products  put  up  in  pills,    capsules,    tablets,    or  other  measured  doses  are  excluded.^     The  dif- 
ference between  production  and  sales   reflects  inventory  changes,    processing  losses,    and  cap- 
tive consumption  of  medicinal  chemicals  processed  into  ethical  and  proprietary  pharmaceutical 
products  by  the  primary  manufacturer.    In  some  instances,    the  difference  may  also  include 
quantities  of  medicinal  grade  products  used  as  intermediates,    e.g.,    penicillin  G  salts  used  as 
intermediates  in  the  manufacture  of  the  semi-synthetic  penicillins.   All  quantities  are  given  in 
terms  of  100-percent  content  of  the  pure  bulk  drug. 

Sales  of  antibiotics  in  1965  and  1966  cannot  be  compared  with  those  for  earlier  years 
because  the  reporting  instructions  were  changed  in  1965  to  exclude  sales  of  antibiotics  in  mix- 
tures,   formulations,    capsules,    pills,    tablets,    etc.    For  the  years  prior  to  1965,    sales  data  for 
antibiotics  represented  all  sales  by  the  primary  producers,    including  finished  pharmaceutical 
preparations. 

Total  U.S.    production  of  bulk  medicinal  chemicals  in  1966  amounted  to   185  million  pounds, 
or   16.  3  percent  more  than  the   160  million  pounds  produced  in  1965,    and  28.  7  percent  more  than 
the   144  million  pounds  produced  in  1964.    Total  sales  of  bulk  medicinal  chemicals  in  1966 
amounted  to  136  million  pounds,    valued  at  $398  million,    compared  with  sales  in  1965  or   129 
million  pounds,    valued  at  $362  million.    Sales  in  1966  were  thus   5.7  percent  greater  than  in 
1965,    in  terms  of  quantity,    and  10.0  percent  greater,    in  terms  of  value. 

Production  of  the  more  important  groups  of  medicinal  chemicals  in  1966  was  as  follows: 
Antibiotics,    9.7  million  pounds   (29.  5  percent  larger  than  in  1965),    of  which  5.4  million  pounds 
was  for  medicinal  use  and  4.  2  million  pounds  was  for  other  uses;   anti-infective  agents  other 
than  antibiotics,    33.  5  million  pounds  (22.0  percent  larger  than  in  1965);  central  depressants 
and  stimulants,    48.  3  million  pounds  (12.  9  percent  larger);  and  vitamins,    17.6  million  pounds 
(7.  9  percent  larger).    Production  of  some  of  the  more  important  individual  products  listed  in 
the  table  was  as  follows:    Choline  chloride,    36.  2  million  pounds  (16.  2  percent  larger  than  in 
1965);  aspirin,    34.  1  million  pounds  (17.  3  percent  larger);  methionine  and  its  hydroxy  analogue, 
1  3.  9  rnillion  pounds   ( 33.  7  percent  larger);   salicylic  acid,    1 1 .  4  million  pounds   (15.  5  percent 
larger);    piperazine  base  and  salts,    8.7  million  pounds   (33.  3  percent  larger);  ascorbic  acid, 
7.6  million  pounds   (4.2  percent  larger);  anti-infective   sulfonamides,    5.4  million  pounds  (15.3 
percent  larger);  penicillins,    1,676  trillion  units  (24.8  percent  larger);  tetracyclines,    1.7 
million  kilograms   (44.2  percent  larger);  vitamin  A,    944  trillion  units   (57.7  percent  larger); 
and  vitamin  E,    277  billion  units. 


See  also  table  13B,   pt.    111.   which  lists  these  products  and  identifies  the  manufacturers,   and  table  23  in  the  appendix,   which  shows 
imports  of  benzenoid  medicinal  chemicals  and  pharmaceuticals  during  the  years  19b5-66. 

5  Complementary  statistics  on  the  dollar  value  of  manufacturers'    shipments  of  finished  pharmaceutical  preparations,  except  biologicals, 
are  published  annually  by  the  U.S.  Department  of  Commerce,    Bureau  of  the  Census,  in  Current  Industrial  Reporu,- Series  MA-M28G.  Many 
pharmaceutical  manufacturers  who  report  to  the  Bureau  of  the  Census  are  excluded  from  the  Tariff  Commission  report  because  they  are  not 
primary  producers  of  medicinal  chemicals,  that  is,  they  do  not  themselves  produce  the  bulk  drugs  which  go  into  their  pharmaceutical  prod- 
ucts but  purchase  their  drug  requirements  from  domestic  or  foreign  producers. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  13A.  --Medicinal  chemicals:  U.S.  production  and  sales ,  1966 

[Listed  below  are  all  synthetic  organic  medicinal  chemicals  for  which  any  reported  data  on  production  or  sales  may  be 
published.  (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where 
no  data  were  reported. )  Table  13B  in  pt.  Ill  lists  all  medicinal  chemicals  for  which  data  on  production  or  sales 
were  reported  and  identifies  the  manufacturer  of  each] 


Production^ 


Sales ^ 


1.000 
pounds 


Grand  total 

Acyclic 

Benzenoid^ 

Cyclic  nonbenzenoid* 

Antibiotics,  total' 

For  medicinal  use,  total 

Antifungal  and  antitubercular  antibiotics 

Bacitracin 

Penicillins,  total - • 

Penicillin  G,  potassium 

Penicillin  G,  procaine 

All  other— - ■ 

Other  antibiotics  for  medicinal  use 

For  other  uses,  total 

Bacitracin 

Penicillin  G  salts^ - 

All  other - — — 

Anticoagulants,  total 

Sodium  heparin 

All  other - - — — 

Antihistamines,  total 

Antinauseants 

Chlorpheniramine  male ate 

Pheniramine  maleate 

All  other - 

Anti-infective  agents,  total 

Arsenic,  bismuth,  and  mercury  compounds 

Caprylates  and  undeoylenates 

p-Hydroxybenzoic  acid  esters,  total 

Methylparaben 

All  other 

5-Nitrofurane,  -imidazole,  and  -thiazole  derivatives 

Phenolic  antiseptics  and  disinfectants 

Piperazine  base  and  salts,  total 

Piperazine 

All  other 

Quinoline  derivatives,  total 

Diiodohydroxyquln 

Oxyqulnollne  benzoate 

Oxyquinoline  sulfate 

All  other — 

Sulfonamides 

Groups  listed  above  for  which  separate  sales  data  may  not 

be  shown 

Other  anti-infective  agents,  total 

Anthelmintic,  antifungal,  antiprotozoan,  and  antiviral 

agents 

Urinary  antiseptics 

All  other 

Antineoplastic  agents  and  local  anesthetics,   total 

Lidocaine 

All  other- - - - 

See  footnotes  at  end  of  table. 


69,305 
97,891 


9,652 


5,445 
947 
L2 

2,092 
813 
754 
525 

2,394 

4,207 
179 
868 

3,160 

10 


33,532 


4,230 

523 

610 

397 

213 

602 

334 

8,681 

4,033 

4,648 

934 

28 

7 

899 

5,450 


8,677 

722 

2,769 


1,000 
pounds 
136,463 


1.000 
dollars 
398,408 


59,621 
63,666 
13,176 


878 

458 

420 

795 

2,378 


2,762 
9,925 

8,309 
673 
943 


41,762 
269,815 
86,831 
99,263 


62,388 

10,233 

913 

16,078 

4,024 
12,054 
35,164 
36,875 
3,316 
5,688 
27,871 


5,402 


235 

298 

4,869 

82,973 


565 

1,141 

718 

423 

493 
4,855 
1,408 
3,447 

49 


10,701 
58,396 

55,428 
1,189 
1,779 


MEDICINAL  CHEMICALS 
TABLE  \Zk.  —Medicinal  chemicals:  U.S.  production  and  sales ,  7 966 --Continued 


Chemical 


Production-' 


SeleB"- 


Autonomic  drugs,  total 

Parasympatholytic  (anticholinergic)  agents: 

Homatropine  methylbromide 

Oiatemary  ammonium  compounds  (except  tropane 
derivatives) 

Sympathomimetic  (adrenergic)  agents,  total 

Isoproterenol  salts 

Phenylephrine 

Phenylpropanolamine  hydrochloride 

All  other 

Other  autonomic  drugs 

Cardiovascular  agents,  total 

Cardiac  drugs 

Rauwolfia  and  veratrum  alkaloids 

Other  cardiovascular  agents 

Central  depressants  and  stimulants,  total 

Amphetamines,  total 

Dextroamphetamine  sulfate 

Methamphetamine  base  and  hydrochloride 

All  other-- 

Anticonvulsants,  hypnotics,  and  sedatives  (except 

barbiturates)  

Antidepressants 

Barbiturates,  total 

Butabarbital,  sodium 

Phenobarbital,  sodium 

All  other— 

Hydrocodone  bitartrate 

Salicylates,  total 

Aspirin 

All  other - 

Skeletal  muscle  relaxants 

Tranquilizers,  total 

Ifeprobamate 

Phenothiazine  derivatives 

Other  tranquilizers' 

Other  central  depressants  and  stimulants-'--'- 

Dermatologieal  agents,  total 

Allantoin 

Bismuth  subgallate 

Salicylic  acid- -. 

All  other 

Expectorants  and  mucolytic  agents,  total 

Gualacol  and  its  derivatives 

All  other - 

Gastrointestinal  agents,  total 

Choleretics  and  hydrocholeretios 

Choline  salts,  total 

Choline  chloride  (all  grades)— 

All  other- - 

Methionine  and  its  hydroxy  analogue 

Other  gastrointestinal  agents 

Hormones  and  synthetic  substitutes,  total 

Anti-thyroid  agents 

Estrogens 

Prednisone 

Synthetic  hypoglycemic  agents 

Other  hormones  and  synthetic  substitutes 

See  footnotes  at  end  of  table. 


46 

7 

92A 

1 

37,553 

34,114 

3,439 

136 

1,583 

1,206 


12,833 


27 
11,400 
1,384 


52,002 


137 
36,537 
36, 198 
339 
13,904 
1,424 

1,503 


3 

1,298 


468 
32,726 


110 
1,314 
1,244 


1,51A 
1,319 


48, 835 


35,225 
34,955 
270 
:i2,268 
1,342 

369 


1,000 
dollars 

7,813 


21 

245 

1,812 

2,554 

1,923 

14,460 


35 

274 

U,151 

57,891 


"3^5" 


(10) 

643 

5,813 

3,163 

1,694 

956 

48, 622 

4,463 


1,568 
551 


20,049 


5,845 
5,546 
299 
11,164 
3,040 

19,747 


34  SYNTHETIC  ORGANIC  CHFMICALS,  1966 

TABLE  13A.  --Medicinal  chemicals:  U.S.  production  and  sales ,  1966- -Continued 


Production 


Sales ^ 


Renal-acting  and  edema-reducing  agents,  total 

Mercurial  diuretics 

Theobromine  and  theophylline  derivatives,  total 

Aminophylline 

All  other 

Other  renal-acting  and  edema-reducing  agents 

Therapeutic  nutrients,  total 

Amino  acids  and  salts,  total 

Glutamic  acid 

Potassium  glutamate 

All  other — - 

Calcium  gluconate 

Other  therapeutic  nutrients 

Vitamins,  total 

Vitamin  A  alcohol  and  esters,  total-'-^ 

Vitamin  A  palmitate  (feed  grade) 

All  other - 

Vitamin  B-complex,   total 

Cyanocobalamin  (except  U.S.P.    crystalline) ^^- 

Niacin  (all  grades) 

Niacinamide 

Pantothenic  acid  and  derivatives,   total 

Calcium  pantothenate  (racemic)    (feed  grade) 

All  other 

Riboflavin  (all  grades) 

Other  B-complex  vitamins 

Vitamin  C,    total 

Ascorbic   acid 

All  other — 

Vitamin  E'^^ - - — 

Vitamin  K— 

Other  vitamins 

Miscellaneous  medicinal  chemicals'"-^ 


277 
2,609 


2,756 


1,404 
554 
490 


640 

376 

6,276 

2 

2,206 

1,046 

1,523 

1,135 

388 

705 

794 

9,600 

7,581 

2,019 

507 

156 

27 


560 

196 

4,918 

1,787 

952 

940 

607 

333 

590 

649 

5,872 

4,543 

1,329 

406 

72 

18 


11,344 
7,473 
28,584 

2,106 
1,854 
3,251 
1,765 
1,486 
6,176 
15,197 
12,201 
9,163 
3,038 
7,908 
981 
2,261 

5,108 


pound 
$16.66 


49.18 
2.89 


5.£ 


54.8$ 
20.26 
38.13 
5.81 

1.18 
1.95 
3.46 
2.91 
4.46 
10.47 
23.42 
2.08 
2.02 
2.29 
19.48 
13.62 
125.61 

16.27 


^  The  data  on  production  and  sales  are  for  buli  medicinal  chemicals  only;  they  exclude  finished  preparations  and 
dosage-form  products  which  are  manufactured  from  bulk  chemicals.  All  quantities  are  given  in  terms  of  IOO56  active 
ingredient. 

Calculated  from  rounded  figxires  except  as  noted. 

^  The  term  "benzenoid, "  as  used  in  this  report,  describes  any  cyclic  medicinal  chemical  whose  molecule  contains 
either  a  six-membered  carbocycllc  ring  with  conjugated  double  bonds  (e.g.,  the  benzene  ring  or  the  quinone  ring)  or 
a  six-membered  heterocyclic  ring  with  1  or  2  hetero  atoms  and  conjugated  double  bonds,  except  the  pyrimidine  ring 
(e.g.,  the  pyridine  ring  or  the  pyrazine  ring). 

^    Includes  antibiotics  of  unknown  structure. 

'  With  the  exception  of  bacitracin,  the  penicillins,  and  a  few  other  antibiotics  which  were  reported  in  terms  of 
U.S.P.  units,  all  quantities  for  antibiotics  were  reported  as  grams  of  antibiotic  base.  (Thus  production  of  480,900 
grams  of  tetracycline  hydrochloride,  for  example,  would  have  been  reported  aa  444,430  grams  of  tetracycline  base. ) 
For  inclusion  in  the  main  statistical  table  all  quantities  were  converted  from  grams  of  antibiotic  base  to  pounds  of 
antibiotic  base  (453.6  grams  =  1  pound)  or  from  U.S.P.  units  to  pounds  (22.7  million  units  of  bacitracin,  458  mil- 
lion units  of  procaine  penicillin  a,   723  million  units  of  potassium  penicillin  G,  etc.  =  1  pound).  The  following 


MEDICINAL  CHEMICALS 


Footnotes  for  table  i3A--Continuecl 

tabulation  shows  statistics  for  all  individually  publishable  antibiotics  in  terms  of  kHograms  of  antibiotic  base 
(Kg.)   or  billions  of  U.S. P.   units  (BU): 


Ifeit  of 
quantity 


Production 


Bacitracin,   total 

For  medicinal  use 

For  other  uses 

Neomycin,   for  all  uses 

Penicillins,   total 

For  medicinal  use,   total 

Penicillin  G,   potassium 

Penicillin  G,   procaine 

All  other — 

For  other  uses:   Penicillin  G  salts- 
Streptomycin,  for  all  uses 

Tetracyclines,  for  all  uses 


267 
A,0(A 


1,676,281 


"T;2W 

587; 


48,136 
853,571 


209,670 
297,658 
346,243 


2,928 
21,766 


$1,060.96 


60.83 
25.50 


19.19 
40.50 
16.43 


Chiefly  procaine  penicillin  G. 
''   Calculated  from  full  figures. 

*  Sales  of  rauwolfla  and  veratrum  alkaloids  amounted  to  482  pounds. 

'  Includes  2  or  more  of  the  following  6  drugs  which  are  subject  to  Federal  control  under  the  Drug  Abuse 
Control  Act:   Chlordlazepoxlde  hydrochloride,  diazepam,  ethchlorvynol,  ethlnamate,  glutethimide,  and  methylprylon. 
U.S.  production  of  these  6  drugs  amounted  to  508  thousand  pounds  In  1966. 

'■°   Sales  data  for  1965  and  earlier  years  Included  some  sales  of  aspirin  tablets  which  were  inadvertently  reported 
as  bulk  sales.  Statistics  for  sales  of  bulk  aspirin  (excluding  tablets)  in  1966  cannot  be  published  without  dis- 
closing the  operations  of  individual  producers. 

''■■'•  Includes  sales  of  anticonvulsants,  hypnotics,  and  sedatives  (except  barbiturates),  of  antidepressants,  and  of 
salicylates. 

^^   All  quantities  for  vitamins  A,  B12,  D2,  Ds,  and  E  were  reported  in  terms  of  grams  or  units,  but  were  converted 
to  pounds  for  inclusion  in  the  main  statistical  table  (1.317  billion  units  of  vitamin  A  acetate,  0.824  billion  units 
of  vitamin  A  palmltate,  453.6  grams  of  vitamin  B12,  18.14  billion  units  of  vitamins  Dj  and  D3,  617,000  units  of 
d-alpha  tocopheryl  acetate,  454,000  units  of  dl-alpha  tocopheryl  acetate,  etc.  =  1  pound).  The  following  tabulation 
shows  statistics  for  these  vitamins,  except  for  the  D  vitamins,  which  were  not  separately  publishable,  in  terms  of 
kilograms  (Kg.),  millions  of  international  units  (MU),  or  billions  of  U.S. P.  units  (BU): 


Vitamin 

Unit  of 
quantity 

Production 

Sales 

Quantity 

Value 

Unit  value 

Cyanocobalamin   (Vitamin  3^2)    (except 
U.S. P.   crystalline) 

Vitamin  A  alcohol  and  esters,   total 

-—Kg 

BU 

BU 

BU 

MU- 

762 
943,652 

655,512 

!,000 
dollars 

18,817 

$28.70 

Vitamin  A  palmltate   (feed  grade) 

All  other 

Vitamin  E - 

527,584 
416,068 

276,863 

461,755 
193,757 

233,830 

U;344 
7,473 

7,908 

24.57 
38.57 

33.82 

slaxants,  and  mis- 


SYNTHETIC  ORGANIC  CHEMICALS.  1966 


Flavor  and  Perfume  Materials 

Flavor  and  perfume  materials  are  organic  chemicals  used  in  the  manufacture  of  foods,    bev- 
erages,   cosmetics,    and  soaps.   Aromatic  organic  chemicals  are  utilized  to  neutralize  or  to  mask 
unpleasant  odors  in  industrial  processes  and  products  as  well  as  in  consumer  products.    Most  of 
them  have  desirable  flavors  or  odors,    and  some  have  the  ability  to  enhance  natural  flavors  when 
added  to  certain  foods.    This   report  includes  data  on  materials  derived  from  natural  products  by 
actual  chemical  processes  and  from  coal  tar.    These  materials  are  grouped  as  either  cyclic  or 
acyclic  materials,    according  to  their  chemical  structures.    Cyclic  materials  are  further  classi- 
fied as  (1)  benzenoia  and  naphthalenoid,    and  (2)  terpenoid,    heterocyclic,    and  alicyclic.    Not  in- 
cluded are  data  on  purely  natural  products,    such  as  floral  essences,    essential  oils,    and  other 
materials  that  are  obtained  by  simple  extraction  or  by  distillation  from  natural  plant  and  animal 
sources.    Statistics  on  production    and  sales  of  flavor  and  perfume  materials  in  1966  are  given  in 
table   14A.* 

Total  domestic  production  of  flavor  ana  perfume  materials  covered  in  this  report  in  1966 
amounted  to  110.7  million  pounds,    or   11.  5  percent  more  than  the  99.  2  million  pounds  produced  in 
1965.    Sales  of  these  materials  in  1966  amounted  to  98.  3  million  pounds,    valued  at  $92.6  million, 
in  1966. 

Production  of  cyclic  flavor  and  perfume  materials  in  1966  amounted  to  61.4  million  pounds-- 
15.  4  percent  more  than  the   53.  2  million  pounds  produced  in  1965.    Sales  of  cyclic  flavor  and  per- 
fume materials  in  1966  were  49.6  million  pounds,    valued  at  $60.9  million,    compared  with  44.6 
million  pounds,    valued  at  $56.8  million,    in  1965.    The  individual  chemical  in  the  cyclic  group 
that  was  produced  in  the  greatest  volume  in   1966,    supplanting  methyl  salicylate  which  was  the 
leader  for  some  years,   was  benzyl  alcohol  (5.  1  million  pounds).    In  1966,    production  of  synthetic 
sweeteners,    as  a  group,    amounted  to   17.  3  million  pounds,    an  increase  of  35  percent  over  the 
output  of  12.  8  million  pounds  in  1965.    The  average  unit  value  of  sales  of  all  synthetic  sweeteners 
in  1966  was  $0.68  per  pound,    compared  with  $0.89  per  pound  in  1965.    Reflecting  this  lower  unit 
value,   total  value  of  sales  for  synthetic  sweeteners  was  $8.  3  million  in  1966,    compared  with 
$9.0  million  in  1965. 

The  output  of  acyclic  flavor  and  perfume  materials  in  1966  amounted  to  49.  3  million  pounds, 
7.  1  percent  more  than  the  46.  0  million  pounds  produced  in  1965.  Monosodium  glutamate  was  by 
far  the  most  important  of  the  acyclic  chemicals,  and  the  individual  flavor  and  perfume  chemical 
produced  in  the  greatest  volume;  output  of  this  flavor-enhancing  chemical  totaled  45.7  million 
pounds  in  1966,  compared  with  43.  1  million  pounds  in  1965.  Sales  of  acyclic  flavor  and  perfume 
materials  in  1966  amounted  to  48.  7  million  pounds,  valued  at  $31.  7  million,  compared  with  43.  1 
million    pounds,    valued  at  $28.2  million,    in  1965. 


TABLE  lAA.-- Flavor  and  perfume  materials;  U.S.  production  and  sales ,  1966 

[Listed  below  are  all  synthetic  organic   flavor  and  perfume  materials  for  which  any  reported  data  on  production  or 
sales  may  be  published,    (leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  pub- 
lished or  where  no  data  were  reported.)  Table  KB  in  pt.    Ill  lists  all  flavor  and  perfume  materials  for  which 
data  on  production  or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Grand  total 

FLAVOR  AND  PERFUME  MATERIALS,  CYCLIC 
Total - 

Total 

^-Allyl-2-methoxyphenol  (Eugenol) 

Anethole  (p-Propenylanisole) 

p-Anisaldehyde  (p-Methoxybenzaldehyde) 

Benzophenone^ 

Benzyl  acetate  — 

Benzyl  alcohol^ 

Benzyl  butyrate 

Benzyl  cinnamate — 

Benzyl  ether — 

Benzyl  phenylacetate   (Benzyl  a -toluate) 

Benzyl  propionate- - -- - 

See   footnotes  at  end  of  table. 


1,000 
110,670 


table  148.  pt.  m,  which  lists  these  products  and  identifiei  th 
or  and  perfume  materials  during  the  years  1965-66. 


ufacturers,  and  i 


23  in  the  appendix,  whicn  shows  ; 


FLAVOR  AND  PERFUME  MATERIALS  37 

TABLE  lAA.— Flavor  and  perfume  materials:  U.S.  production  and  sales ,  1966— ContinMed 


Material 


Production 


FLAVOR  AND  PERFUME  MATERIALS,    CYCLI C— Continued 

Benzenoid  and  /Vaphthalenoid— Continued 

Benzyl  salicylate 

Cinnamaldehyde 

Cinnamyl  acetate 

Cinnamyl  alcohol 

2-Ethoxynaphthalene 

Isobutyl  phenylacetate  (Isobutyla -toluate) 

Isobutyl  salicylate 

Isopentyl  salicylate  (Isoamyl  salicylate) 

4'-Methoxyacetophenone 

S-Methoxy-'i-propenylphenol  (Isoeugenol) 

p-Methylanlsole   (p-Cresyl  methyl  ether) 

Methyl  anthranilate 

a-Methylcinnamaldehyde 

Methyl  citmamate 

Ifethyl  salicylate   (Synthetic  wintergreen  oil) 

a-Pentylcinnamaldehyde   (ct-Amylcinnamaldehyde) 

Phenethyl  isobutyrate 

Phenethyl  phenylacetate   (Phenethyl a -toluate) 

Phenethyl  propionate 

3-Phenyl-l-propanol  (ffydrooinnamic  alcohol) 

'i-Propenylveratrole   ( Isoeugenyl  methyl  ether) 

p-Tolyl  acetate   (p-Cresyl  acetate) 

a-(TTichloromethyl)benzyl  acetate  (Roeetone) 

All  other  benzenoid  and  naphthalenoid  materials 

Terpenoid,    Heterocyclic,    and  Alicyclic 
Total - — - 

Cedryl  acetate 

Citral  a  (Geranial) - - 

Citronellol-— - 

Citronellyl  acetate 

Citronellyl  formate 

Coumarin 

Essential  oils,  chemically  modified 

Geraniol 

Geranyl  acetate 

Geranyl  formate 

Hydroxyoitronellal 

f^droxycitronellal,   dimethyl  aoetal 

lonones 

Isobomyl  acetate 

Menthol,  synthetic,  tech.  &  U.S.P 

Menthone 

Methylionones 

Nerol — — 

Piperonal  (Heliotropin) 

Rhodinol 

Sweeteners,  synthetic 

Terpineols 

a-Terpinyl  acetate , — 

Vetlvenyl  acetate 

All  other  terpenoid,  heterocyclic  and  alicyclic  materiala- 

FLAVOR  AND  PERFtJME  MATERIAI^,  ACYCLIC 

Total - 

Allyl  hexanoate   (Aiajrl  caproate) 

Ethyl  butyrate 

Ethyl  heptanoate   (Ethyl  enanthate) 

Glutamic   acid,  monosodium  salt   (Itonosodium  glutamate) 

4-Hydroxyundecanoio   acid,  7-lactone   (7-Undecalactone) 

Isopentyl  butyrate   (Isoamyl  butyrate) 

All  other  acyclic  materials 

^  Calculated  from  the  unrounded  figures. 
Includes  some  technical  grade. 


},000 

i,000 

pounds 

pounds 

304 

270 

1,319 

1,207 

15 

3 

2L5 

175 

19 

3,994 

436 

12 


253 

11 

17,346 

3,543 

473 

30 

6,267 


4,001 
485 
10 


263 

8 

12,181 

3,546 

433 

25 

3,064 


1,874 
606 
21 


9 

207 

16,030 


151 

368 

316 

84 

323 

653 

544 

822 

21 

22 

37 

32 

17 

34 

1,031 

1,192 

2,377 

254 

246 

707 

1,U7 

887 

1,159 

91 

91 

156 

U 

11 

24 

513 

51A 

1,973 

15 

9 

54 

340 

305 

998 

978 

997 

378 

574 

551 

2,151 

568 

221 

8,317 

1,132 

269 

457 

9,570 


328 

45,397 


221 
28,662 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


Plastics  and  Resin  Materials 

Plastics  and  resin  materials  are  condensation  and  polymerization  products  of  organic  chem- 
icals,   containing  necessary  plasticizers,    fillers,    extenders,    stabilizers,    and  coloring  agents.    At 
some  stage  in  their  manufacture  they  exist  in  such  physical  condition  that  they  can  be  shaped  or 
otherwise  processed  by  the  application  of  heat  and  pressure.    Some  types  of  plastics  materials 
may  be  molded,    cast,    or  extruded  into  semifinished  or  finished  forms.    Other  types  are  used  as 
adhesives,    for  the  treatment  of  textiles  and  paper,    and  for  protective  coatings.    (Statistics  on 
U.S.    production  and  sales  of  synthetic  plastics  and  resin  materials  for   1966  are  given  in  table 
ISA').  In  general,  the  statistics  follow  the  outline  of  the  Tariff  Commission's  monthly  report  on 
the  production  and  sales  of  synthetic  plastics  and  resin  materials  (S.O.C.    Series   P-66).    How- 
ever,   the  data  given  include  some  companies  which  are  not  covered  in  the  monthly  reports,  and 


TABLE  15A. — Plastics  and  resin  materials :    U.S.  production  and  sales,  by  chemical  classes 
and  uses,  1966 

[Quantities  and  values  are  given  in  terms  of  the  total  weight  of  the  materials  (dry  basis).   Listed  below  are  all 
plastics  and  resin  materials   for  which  any  reported  data  on  production  or  sales  may  be  published.    (Leaders  are 
used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were  reported.) 
Table  15B  in  pt.    Ill   lists  all  plastics  and  resin  materials  for  which  data  on  production  or  sales  were  reported 
and  identifies  the  manufacturer  of  each] 


Production 


Sales 


1.000 
pounds , 


Grand  total 

Plastics  and  resin  materials,   benzenoid 

Plastics  and  resin  materials,   nonbenzenoid 

THERMOSETTING  RESINS 

Total 

Alkyd  resins,  total 

Domestic : 

Phthalio  anhydride  type 

Polybasic  acid  type 

Sales  for  export 

Coumarone-indene  and  petroleum  polymer  resins,  total- 

Floor  tile 

Rubber  compounding 

All  other  uses 

Sales  for  export 

I^oxy  resins: 

Unmodified,  total 

Bonding  and  adhesives 

Protective  coatings 

Reinforced  plastics 

All  other  uses 

Sales  for  export 

Modified - 

Polyester  resins,-'  total 

Reinforced  plastics: 

Sheets,  flat  and  corrugated 

All  other 

Surface  coatings 

All  other  uses 

Sales  for  export 

See  footnotes  at  end  of  table. 


70,2^3 
66,5^7 
197,  566 


4,590 
470,046 


1.000 
pounds. 


4,254,211 
7,217,427 


988,001 
1,752,080 


285, 692 
60, 202 
4,951 

319,741 


70,076 
65,613 
158,272 
25,780 


133,095 
15,144 
54,358 
27, 672 
17,451 
18,470 
4,024 

406,  658 


39,34^ 

253,772 

6,547 

95,192 


73,308 
15,472 
1,273 


4,451 
122,627 


See  also  table  15B,  pt.  Ill  which  lists  these  products  by  chemical  type  and  by  end  uses,  and  identifies  the  manufacturers. 


PLASTICS  AND  RESIN  MATERIALS 

TABLE  15K— Plastics  and  resin  materials:   U.S.  production  and  sales,  by  chemical  classes 
and  uses,  2566— Continued 


39 


Kind  and  use 


Production 


THERM3SETTING  RESINS— Continued 

Phenolic  and  other  tar  acid  resins,  total 

Maiding  materials 

Bonding  and  adhesive  resins  for: 

Laminating 

Coated  and  bonded  abrasives 

Friction  materials 

Thermal  insulation 

Foundry  or  shell  molding 

Plywood 

Fibrous  and  granulated  wood 

Protective  coatings,  unmodified  and  modified 

All  other  uses 

Sales  for  export 

Polyurethane  and  dilsocyanate  resins 

Rosin  ncdifioations,  total 

Rosin  and  rosin  esters,  unmodified  (ester  gvims) 

All  other - — 

Silicone  resins 

Urea  and  melamine  resins,  total 

Textile  treating  and  coating  resins 

Paper  treating  and  coating  resins 

Bonding  and  aiihesive  resins  for: 

Laminating 

Plywood 

Fibrous  and  granulated  wood 

Protective  coatings 

All  other  uses  (including  molding) 

Sales  for  export 

All  other  thermosetting  resins* 

THERMOPLASTIC  RESINS 

Total 

Cellulose  plastics  materials,  total ' 

Sheets,  continuous: 

Under  0.003  gage— 

0.003  gage  and  over 

All  other  sheets,  rods,  and  tubes 

Molding  and  extrusion  materials 

Polyamide  resins,  total 

h^lon  type 

Non-nylon  type 

Polyolefin  plastics  materials: 

Polyethylene,  density  0.940  and  below: 

Production  and  sales 

Dsed  by  reporting  companies  In  processing 

Sales  and  use,  total 

Injection  molding 

Blow  molding 

Film  and  sheet 

Bctrueion  coating  on  paper  and  other  substrates- 
Wire  and  cable 

All  other  extruded  products.  Including  pipe  and 

conduit 

All  other  domestic  uses 

Bcport  sales 

See  footnotes  at  end  of  table. 


307,481 

143,114 
31,544 
43,955 

128,061 
76,854 

156,028 
42,866 
34,291 
82,548 


71,514 
130,796 


186,707 

21,335 

48,734 

5,827 

110, 811 

92,618 
70,300 
22,318 


855,804 


1.000 
dollars 
203, 559 


278, 278 

86,972 
21,958 
38,097 
62,054 
72,671 
146, 138 
36,121 
26,760 
72,987 
13,768 


$0.24 


58,770 
71,139 


12,105 
15,720 


81,221 

73,612 

64,822 

48,624 

59,851 

38,777 

142,490 

121,936 

159,545 

147,482 

63,575 

38,562 

146,818 

125,611 

16,468 

183,462 

22,442 

49,584 

6,432 

105, 004 

82,133 
61,823 
20,310 


2,320,740 
226,745 

2,547,485 
323,464 
42, 503 

1,100,493 
313,164 
275,768 

40,023 
188,490 
263,580 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 

-Plastics  and  resin  materials.-   U.S.  production  and  sales,  by  chemical  classes 
and  uses,  1966 — Continued 


Kind  and  use 


THEEftJOPLASTIC  RESINS— Continued 

i-oiyolefin  plastics  materials — Continued 
Polyethylene,  density  over  0.940: 

Production  and  sales 

Used  by  reporting  conjianies  in  processing 

Sales  and  use,  total 

Injection  molding 

Blow  molding 

Film  and  sheet 

Extrusion  coating  on  paper  and  other  substrates 

Wire  and  cable 

Pipe  and  conduit 

Other  extruded  products 

All  other  domestic  uses 

Export  sales 

Polypropylene : 

Production  and  sales 

Used  by  reporting  companies  in  processing 

Sales  and  use,  total 

Molding 

Extrusion 

All  other  uses  (including  export) 

Styrene  type  plastics  materials,  total 

ABS  and  SAN  resins': 

Production  and  sales 

Sales  and  use,  total 

Molding 

Extrusion 

All  other  domestic  uses 

Export  sales 

Styrene  and  styrene  copolymer  resins: 

Production'  and  sales 

Used  by  reporting  companies  in  processing 

Sales  and  use,  total 

Molding 

Textile  and  paper  treating  and  coating 

Biulsion  paint 

Extrusion 

All  other  domestic  uses 

Export  sales 

Vinyl  resins  (resin  content): 

Polyvinyl  chloride  and  copolymers: 

Production  and  sales,  total 

Suspension  homopolymers 

Suspension  copolymers 

Dispersions  (paste) 

Used  by  reporting  companies  In  processing 

Sales  and  use,  total 

Calendering,  except  flooring 

Flooring : 

Calendered 

Coated 

Paper  and  textile  uses: 

Coating 

Other— - 

Protective  coatings  and  adhesives 

Wire  and  cable 

Extruded  film  and  sheet 

Other  extruded  products 

Sound  records 

Injection  and  blow  molding 

Plastisol  formulating  and  molding 

All  other  domestic  uses 

Bcport  sales 

See  footnotes  at  end  of  table. 


, 163, 561 
,  224, 286 
657,768 
281, 507 


1.000 

pounds, 

dry 


Per 
pound 


178, 800 
346,864 
45,423 
6,715 
30, 193 
39,059 
22,384 
139,068 
82,378 

372,475 
172,009 
544,484 
238, 568 
232,373 
73,543 


362,446 
362,446 
159,988 
111,132 
50,380 
40,946 


245,676 
2,055,575 
1,024,729 
207,337 
42,332 
245,022 
446,047 
90,108 


309, 984 

2,126,4^1 

438,882 


117,217 
15,576 
54,418 

225, 967 
65,956 

281,558 

114,396 
64,608 
91,953 

227,676 
69,232 


PLASTICS  AND  RESIN  MATERIALS 


TABLE  15A, — Plastics  and  resin  materials.-   U.S.  production  and  sales ,  by  chemical  classes 
and  uses,  1966 — Continued 


Kind  and  use 


Production 


THERMOPLASTIC  KESINS— Continued 

Vinyl  resins   (resin  content) — Continued 
Polyvinyl  acetate: 

Production  and  sales,    total 

latexes 

Resins - 

Used  by  reporting  companies  in  prooessing-- 

Sales  and  use,   total 

Bmilsion  paints 

Mhesives 

Paper  treating 

Textile  treating 

All  other  domestic  uses 

Export  sales 

Polyvinyl  alcohol 

Other  vinyl  resins 

All  other  thermoplastic  resins'"'''' 


335,961 
238,442 
97,519 


38,337 
132,098 


dry 

i.mo 

dolla 

231, i29 

66 

354 

73^992 

305,421 

110,090 

105, 44A 

25,702 

10,205 

51,719 

2,261 

'  37,926 

16 

438 

129,424 

67 

784 

380,891 

274 

551 

'■   Calculated  from  rounded  figures. 

^  For  -the  purpose  of  this  report,  "dry  basis"  is  defined  as  the  total  weight  of  the  material,  including  resin, 
plasticizers,  fillers,  extenders,  colors  and  stabilizers,  and  excluding  water,  solvents,  and  other  liquid  diluents. 

^   The  term  "polyester  resins"  includes  unsaturated  aliyds  oopolymerized  with  a  monomer  such  as  styrene,  and 
polyallyl  resins  such  as  diallyl  phthalate  and  allyl  diglycol  carbonate. 

*  Includes  data  for  ace-tone-formnldehyde  resins,  s'tyrene-aUsyd  polyesters,  tolueneeulfonainide  resins,  silicone 
reelns,  and  other  thermosetting  resins  which  were  produced  in  small  quantities.  Also  included  are  saturated  poly- 
esters for  ure'thanee. 

'  Represents  production  of  polye'thylene  by  the  high  pressure  process  and  of  ethylene  copolymers. 

*  Represents  production  of  polyethylene  by  the  low  pressure  process. 

'  ABS  resins  are  polymers  of  acrylonitrile,  styrene,  and  butadiene.  SAN  resins  are  polymers  of  s'tyrene  and 
aorylonitrile. 

*  Data  for  intra-company  consumption  may  not  be  shown  separately,  and  are  Included  with  sales  at  an  estimated 
unit  value. 

'  Includes  straight  polystyrene,  848,429  thousand  pounds;  rubber  modified  polystyrene,  724,413  thousand  poimds; 
styrene-butadiene  copolymers,  306,603  thousand  pounds;  and  all  other,  143,429  thousand  pounds. 

10  Includes  data  for  polyvinyl  butyral,  polyvinyl  formal,  and  polyvinylidene  chloride. 

■''■''  Includes  data  for  aoryllo,  fluorocarbon,  polycarbonate,  polyoxyme'thylene,  polyterpene,  and  o-ther  thermo- 
plastic resins. 


also  some  adjusted  figures  supplied  by  the  original  reporting  companies.    Consequently,    many  of 
the  figures  given  in  table  15A  are  re-vised  from  those  shown  in  the  Connmission's  monthly  release 
dated  April  11,    1967,   which  contained  year-end  cumulative  monthly  totals  for  1966.    The  end  use 
breakdowns  used  were  developed  with  the  ad-vice  of  representatives  of  the  plastics  industry,    and 
the  data  reported  are  the  producers'  determination  of  the  markets  of  their  materials. 

Total  U.S.    production  of  synthetic  plastics  and  resin  nnaterials  in  1966  amounted  to  13,585 
million  pounds,    or   16.3  percent  more  than  the  11,685  million  pounds  reported  for   1965.   Sales  in 
1966  were   11,472  million  pounds,    valued  at  $2,740  million.    Production  of  benzenoid  plastics  and 
resin  materials  in  1966  amounted  to  5,  067  million  pounds  and  that  of  nonbenzenoid  materials  to 
8,  518  million  pounds.    These  figures  compare  with  the  benzenoid  production  in  1965  of  4,453  mil- 
lion pounds,    and  nonbenzenoid  production  of  7,  232  million  pounds. 

The   1966  output  of  all  types  of  thermosetting  resins  totaled  3,647  million  pounds,    compared 
with  3,  237  million  pounds  in  1965.   In  1966  phenolic  and  other  tar  acid  resins  were  produced  in 
the  largest  quantity  in  the  thermosetting  group,    and  exceeded  one  billion  poxinds  for  the  first 
time.    Output  of  phenolic  resins  amounted  to  1,  047  million  pounds  in  1966,    compared  with  922 
million  pounds  in  1965.    Production  of  urea  and  melamine  resins  in  1966  was  718  million  pounds, 
and  that  of  alkyd  resins  was  666  million  poxrnds.    Other  thermosetting  resins  produced  in  signif- 
icant amounts  in  1966  were  polyester  resins  (470  million  pounds);  coumarone-indene  resins  (334 
million  pounds);  epoxy  resins  (140  million  pounds);  and  polyurethane  resins  (72  million  pounds). 

The  total  output  of  thermoplastic  resins  in  1966  amounted  to  9,  938  million  pounds,    com- 
pared with  8,448  million  pound*  in  1965.   In  1966,    as  in  pre-vious  years,    polyethylene,    polysty- 
rene,   and  poly-vinyl  chloride  were  the  resins  produced  in  the  largest  volume.    The  output  of  high- 
pressure  polyethylene  in  1966  was  2,  648  million  pounds,   which  corresponds  to  the  output  of  2,  263 
million  pounds  of  low-density  polyethylene  reported  for   1965.    Production  of  low-pressure  poly- 
ethylene in  1966  was  910  million  pounds,    corresponding  to  the  784  million  pounds  of  high-density 
polyethylene  produced  in  1965. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


The  total  production  of  styrene-type  plastics  materials  in  1966  was    2,385    million  pounds, 
compared  with   2,033    million  pounds  in  1965.   These  totals  include  the  ABS  and  SAN  tyrpes  of 
resins,  for  which  data  are   shown  for  the  first  time  for  1966.  In  1966,  output  of  ABS  and  SAN 
resins  combined  amounted  to  362  million  pounds.  Sales  were  362  million  pounds,  valued  at  $119 
million.  Output  of  other  styrene-type  resins  in  1966,  including  straight  polystyrene,  rubber- 
modified  polystyrene,   styrene-butadiene  copolymer  and  others,  amounted  to   2,023    million 
pounds. 

Polyvinyl  chloride  resin  production  in  1966  amounted  to    2,164   million  pounds,  compared  with 
1,837   million    pounds  in  1965.  Polyvinyl  alcohol  production  in  1966  was  38.3  million  pounds,  and 
that  of  other  vinyl  resins  including  polyvinyl  butyral,  polyvinyl  formal,  and  polyvinylidene  chlo- 
ride amounted  to   132  million  pounds.  All  data  on  vinyl  resins  are  reported  on  a  resin  content 
basis. 

Rubber-Processing  Chemicals 

Rubber-processing  chemicals  are  organic  compounds  that  are  added  to  natural  and  synthetic 
rubbers  to  give  them  qualities  necessary  for  their  conversion  into  finished  rubber  goods.  In  this 
report,   statistics  are  given  for  cyclic  and  acyclic  compounds,  by  use--such  as  accelerators, 
antioxidants,  blowing  agents,  and  peptizers.  Statistics  on  production  and  sales  of  rubber-proc- 
essing chemicals  in  1966  are  given  in  table   16A.8 


TABLE  16A.  --Rubber-processing  chemicals :  U.S.  production  and  sales ,  1966 

'  Listed  below  are  all  rubber-processing  chemicals  for  which  any  reported  data  on  production  or  sales  may  be  pub- 
lished. (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where 
data  were  reported. )  Table  16B  in  pt.  Ill  lists  separately  all  rubber-processing  chemicals  for  which  data  on  pr 
duction  or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Grand  total 

RUBBER-PROCESSING  CHEMICALS,  CYCLIC 

Total 

Accelerators,    activators,    and  vulcanizing  agents,   total- 
Aldehyde-  amine  reaction  products 

Dithiocarbamic   acid  derivatives 

Thiazole  derivatives,    total 

N-Cyclohexyl-2-benzothiazolesulfenamlde 

2,2'-Dithiobls(benzothlazole) 

2-^fercaptobenzo thiazole 

All  other 

All  other  accelerators 

Antioxidants,  antiozonants,  and  stabilizers,  total 

Amino  compounds,  total 

Substituted  p-phenylenediamines,  total 

N, N'-Diphenyl-p-phenylenediamine 

All  other 

Octyldiphenylamine 

N-Phenyl-2-naphthylamine 

All  other  amino  antioxidants,  antiozonants,  and 

stabilizers 

Phenolic  and  phosphite  antioxidants  and  stabilizers, 

total 

Polyphenolics  (including  bisphenols) 

Phenol,  alkylated 

All  other  phenolic  and  phosphite  antioxidants  and 

stabilizers 

Blowing  agents 

Peptizers 

All  other  cyclic  rubber-processing  chemicals,  total 

N-Nitrosodiphenylamine 

All  other^ 

See  footnotes  at  end  of  table. 


K8,668 


115, 79i 

2,283 
47,212 
2,752 
5,31J 

58,234 

32,874 
6,555 
12,406 

13,913 


-S97126" 
37,220 
2,284 


6,236 

11,093 

3,304 
4,913 

3,175 


23,890 
2,738 
5,487 


60,381 
32,790 
2,311 


See  also  table  168,  pt.  in,  which  lists  these  products  and  identifies  the  manufacturer. 


RUBBER-PROCESSING  CHEMICALS 


TABLE  ISA.  --Rubber-processing  chemicals:  U.S.  production  and  sales,  i566--Continued 


Unit 
ifalue^ 


RUBBER-PROCESSING  CHIMICALS,  ACYCLIC 

Total - 

Accelerators,  activators,  and  vulcanizing  agents,  total- 

Dithiocarbamic  acid  derivatives,  total 

Dlbutyldithlocarbamlo  acid,  zinc  salt 

EHethyldithlocarbamlc  acid,  zinc  salt 

Dimethyldithlocarbamlc  acid,  zinc  salt 

All  other 

Thlurams,  total"* 

Bis(diethylthlocarbamoyl)  disulfide 

Bis(dimethylthiocarbamoyl)  disulfide 

Bis(dlmethylthlocarbamDyl)  sulfide 

All  other 

All  other  accelerators,  activators,  and  vulcanizing 

agents 

Dodecyl  mercaptans 

Dimethyldithiocarbamic  acid,    sodium  salt 

All  other  acyclic  rubber-processing  chemicals^ 


1.000 
pounds 


19,925 


7,ig5 
1,741 
1,513 
1,736 
2,495 
11,994 

6,731 
1,338 
3,925 


12,658 
5,663 
3,841 


U,463 


6,082 
1,419 
1,115 
1,461 
2,087 
8,116 
1,087 
5,335 

1,694 

265 

7,860 
2,351 
1,821 


8,919 


4,634 

1,367 

653 

682 

1,932 

3,975 

501 

2,258 


3,629 

1,080 

994 


Calculated  from  rounded  figures. 

^  Includes  tacMfiers  and  physical-property  Improvers. 

■^  Data  on  dithlocarbamates  included  in  this  table  are  for  materials  used  chiefly  in  the  processing  of  natural  and 
synthetic  rubbers.  Data  on  dithlocarbamates  which  are  used  chiefly  as  fungicides  are  reported  in  table  20A  "Pesti- 
cides and  Related  Products."  ' 

*  Includes  data  for  small  amounts  of  tetramethylthluram  sulfides  for  uses  other  than  in  the  processing  of  natural 
and  synthetic  rubbers. 

^  Includes  blowing  agents,  polymerization  regulators,  shortstops,  and  conditioning  and  lubricating  agents. 


Production  of  rubber-processing  chemicals  as  a  group  in  1966  amounted  to  283  million 
pounds,  or  12.5  percent  more  than  the  252  million  pounds  reported  for  1965.  The  larger  total 
output  of  rubber-processing  chemicals  in  1966  is  attributable  principally  to  increased  production 
of  amino  antioxidants  and  thiazole  accelerators.  Sales  of  rubber-processing  chemicals  in  1966 
amounted  to  209  million  pounds,  valued  at  $138  million,  compared  with  194  million  pounds, 
valued  at  $123  million,  in  1965. 

The  output  of  cyclic  rubber-processing  chemicals  in  1966  amounted  to  241  million  pounds, 
or  14.1  percent  more  than  the  211   million  pounds  reported  for  1965.  Sales  in  1966  were   183  mil- 
lion pounds,  valued  at  $124  million,  compared  with  166  million  pounds,  valued  at  $109  million, 
in  1965.  Of  the  total  output  of  cyclic  rubber-processing  chemicals  in  1966,  accelerators  ac- 
counted for  33.0  percent  and  antioxidants  for  61.6  percent.  Production  of  amino  and  phenolic  and 
phosphite  antioxidants,  which  amounted  to   148.7  million  pounds  in  1966,  included   115.8  million 
pounds  of  amino  compounds  and  32.9  million  pounds  of  phenolic  and  phosphite  compounds.  Sales 
of  amino  antioxidants  in  1966  were  89.1  million  pounds,  valued  at  $60.4  million;  sales  of  phe- 
nolic and  phosphite  antioxidants  were  23.9  million  pounds,  valued  at  $18.1   million. 

Production  of  acyclic  rubber-processing  chemicals  in  1966  amounted  to  42.1   million  pounds, 
an  increase  of  3.8  percent  over  the  40.5  million  pounds  reported  for   1965.  Sales  in  1966  totaled 
26.5  million  pounds,  valued  at  $14.6  million,  compared  with  27.5  million  pounds,  valued  at 
$14.2  million,  in  1965.  Accelerators,  principally  dithiocarbamic  acid  derivatives  and  tetra- 
methylthluram sulfides,  accounted  for  47.3  percent  of  the  output  of  acyclic  rubber-processing 
chemicals  for  1966.  Dodecyl  mercaptans  accounted  for  30.1  percent.  Blowing  agents,  peptizers, 
modifiers,  shortstops,  and  lubricating  and  conditioning  agents  accounted  for  the  remainder  of 
the  output  of  acyclic  compounds. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


Elastomers  (Synthetic  Rubbers) 

Elastomers  are  a  group  of  high  polymeric  materials  which  have  properties  similar  to  those 
found  in  natural  rubber.    The  term  "elastomers",    as  used  in  this  report,    is  specifically  defined 
as  substances  in  bale,    crumb,    powder,    latex,    and  other  crude  forms,    which  can  be  vulcanized 
or  similarly  processed  into  materials  that  can  be  stretched  to  at  least  twice  their  original  length 
and,    after  having  been  so  stretched  and  the  stress  removed,  will  return  with  force  to  approxi- 
mately their  original  length. 

Statistics  on  production  and  sales  of  elastomers  are  given  in  table   17A.^    The  total  domestic 
output  of  all  types  of  synthetic  elastomers  in  1966  was  3,  929  million  pounds,    compared  with 
3,  592  million  pounds,    reported  for  1965.   Sales  of  these  elastomers  amounted  to  3,  411  million 
pounds,    valued  at  $918  million  in  1966,    compared  with  3,  041  million  pounds,    valued  at  $843 
million,    in  1965. 

Production  of  cyclic  elastomers  in  1966  amounted  to  2,482  million  pounds,    compared  with 
2,  300  million  pounds  in  1965.    Of  the  total  U.S.    production  of  cyclic  elastomers  in  1966,    the 
polybutadiene-styrene  type  (including  vinylpyridine)  accounted  for  2,470  million  pounds,    and  the 
polyurethane  type  for  12  million  pounds.    Sales  of  cyclic  elastomers  in  1966  were  2,  108  million 
pounds,    valued  at  $463  million,    compared  with  1,  898  million  poxinds,    valued  at  $443  million,    in 
the  previous  year. 

TABLE  n A. --Elastomers  (synthetic  rubbers).-^  U.S.  production  and  sales ,  1966 

[Listed  below  are  all  elastomers   (synthetic  rubbers)  for  which  reported  data  on  production  or  sales  may  be  pub- 
lished.   (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where 
no  data  were  reported.)   Table  17B  in  pt.    Ill  lists  all  elastomers  for  which  data  on  production  or  sales  were 
reported  and  identifies  the  manufacturer  of  each] 


Product 

Production 

Sales 

Quantity 

Value 

Unit  value^ 

Grand  total 

1.000 
pound, 
3,929,187 

1,000 
pounds 
3,411,258 

1.000 
dollars 
918,018 

Per 
pound 

$0.27 

ELASTOMERS,    CYCLIC 

2,482,375 

2,108,089 

463,222 

.22 

2,448,092 
21,  907 
12,376 

1,446,812 

*  2,086,856 
10,955 
10,278 

1,303,169 

446,413 
6,428 
10,381 

454,796 

.21 

1.01 

ELASTOMERS,    ACYCLIC 

.35 

157,122 
230,685 
13,392 

612,689 

131,942 
10^751 
506,148 

58,869 
39,"  307 
107,362 

.45 

Silicone  elastomers 

3.66 
.21 

416,922 
195,767 

432, 924 

342,9'03 
163,245 

654,328 

67,476 
39,886 

249,258 

.20 

All  other  stereo  elastomers 

All  other  acyclic  elastomers^ 

.24 
.38 

The  term    "elastomers"    is  defined  as  substances  in  bale,   crumb,   powder,    latex,    and  other  crude  forms  which  can  be 
vulcanized  or  similarly  processed  into  materials  that  can  be  stretched  at  68°  F.   to  at  least  twice  their  original 
length  and,    after  having  been  so  stretched  and  the  stress  removed,   will  return  with  force  to  approximately  their 
original  length. 

^  Calculated  from  rounded  figures. 

^   Elastomer-content  basis. 

*  Partly  estimated. 

'  Includes  data  for  polyacrylate,   polyalkalene  sulfide,   polychloroprene,   polyisobutylene  elastomers,    and  for  sales 
of  polyisobutylene-isoprene  elastomers. 

Note. — Statistics  on  the  production  of  S-type,    N-type,   Butyl,   neoprene,   and  stereo  elastomers  were  compiled  in 
cooperation  with  the  U.S.    Bureau  of  the   Census. 


See  also  table  17B,  pt.  m,   which  lists  these  products  and  identifies  the  manufacturers. 


The  U.S.    production  of  acyclic  elastomers  in   1966  was   1,447  million  pounds,    compared 
with  1,  292  million  pounds  in  1965.    Sales  of  these  products  in   1966  amounted  to  1,  30  3  million 
pounds,    valued  at  $455  million.    Of  the   1966  production  of  acyclic  elastomers,    stereo  elastomers 
were  produced  in  the  largest  amount  (613  million  pounds),    followed  by  the  polyisobutylene- 
isoprene  type  (^31  million  pounds),    and  the  polybutadiene-acrylonitrile  type   (N-type)  (157  mil- 
lion pounds).    The  stereo  elastomers  are  composed  principally  of  polybutadiene,    polyisoprene, 
and  ethylene-propylene  rubber.    Production  of  silicone  elastomers  in  1966  was   13.4  million 
pounds,    and  of  other  acyclic  elastomers  was  433  million  pounds.    This  latter  figure  includes  data 
for  polyacrylate,    polyalkalene  sulfide,    polychloroprene,    polyisobutylene,    and  other  types  of 
elastomers  of  lesser  importance. 

Plasticizers 

Plasticizers  are  organic  chemicals  that  are  added  to  synthetic   plastics  and  resin  materials 
to  (1)  improve  workability  during  fabrication,    (2)  extend  or  modify  the  natural  properties  of  these 
resins,    or  (3)  develop  new  improved  properties  not  present  in  the  original  resins.    Plasticizers 
reduce  the  viscosity  of  the  resins  and  make  it  easier  to  shape  and  form  them  at  high  temperatures 
and  pressures.    They     also  impart  flexibility  and  other  desirable  properties  to  the  finished  prod- 
uct.   Statistics  on  production  and  sales  of  plasticizers   are  given  in  table   18A.^° 

Total  U.S.    production  of  plasticizers  in  1966  amounted  to  1,209  million  pounds- -represent- 
ing an  increase  of  12.  7  percent  over  the  output  of  1,  073  million  pounds   reported  for   1965.    Sales 
in   1966  of  the  plasticizers  covered  by  this  report  amounted  to  1,  156  million  pounds,    valued  at 
$246  million,    compared  with  1,  022  million  pounds,    valued  at  $214  million,    in   1965--increases 
of  13.  1   percent  in  quantity  and  14.  7  percent  in  value. 

TABLE  16A.— Plasticizers:'-  U.S.  production  and  sales,  1966 

[Listed  below  are  all  plasticizers  for  which  reported  data  may  be  published.  (Leaders  are  used  where  the  reported 
data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were  reported. )  Table  18B  in  pt.  Ill 
lists  all  plasticizers  for  which  data  on  production  or  sales  were  reported  and  identifies  the  manufacturer  of 


Grand  total 

PLASTICIZERS,  CYCLIC 

Total 

Hiosphoric  acid  esters: 

Cresyl  diphenyl  phosphate 

Trlcresyl  phosphate 

Triphenyl  phosphate 

Phthalic  anhydride  esters,    total 

aityl  octyl  phthalates   (including  butyl  2-ethylhexyl 

phthalate) 

Dibutyl  phthalate 

Dicyclohexyl  phthalate 

Diethyl  phthalate 

Whexyl  phthalate - 

Diisodecyl  phthalate 

DKZ-methoxyethyl)  phthalate 

Dimethyl  phthalate 

Dlootyl  phthalates,    total^ 

Di(  2-ethylhexyl )  phthalate— 

Dllso-octyl  phthalate - 

Mixed  dioctyl  phthalates    (including  dicapryl 

phthalate  and  dioctyl  isophthalates ) 

Di-tridecyl  phthalate 

Glyoolate  phthalate  esters 

n-Octyl  n-decyl  phthalate 

All  other  phthalic  anhydride  esters 

Trlmellitie  acid  esters 

All  other  cyclic  plasticizers* 

See  footnotes  at  end  of  table. 


i.OOO 
pounds 
1,155,686 


19, 956 
39, 812 
8,ai7 


17,222 
20,236 
6,739 
21,451 


376,800 
253,000 
103,000 


16,220 
716 
107,  500 
12,340 
4,247 
375,800 
253,000 
103,000 

19,300 
19,350 
4,334 
34,812 
129,763 


54,111 
35,420 
15,450 

3,241 
4,363 
1,736 
6,090 
22,236 

1,080 


and  identifies  the  manufacturen. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  1&A.--Plasticizers :^  U.S.  production  and  sales,  7966- -Continued 


Unit 
value ^ 


PLASTICIZERS,  ACYCLIC 

Total 

Mipio   acid  esters,   total 

Di(2-(2-butoxyethoxy)ethyl)   adipate 

Di(2-etliylhexyl)   adipate 

Diisodeoyl  adipate 

n-Octyl  n-deoyl  adipate 

All  other - 

Azelaic  acid  esters 

Complex  linear  polyesters  and  polymeric  plasticizers' 

Ejpoxidized  esters,  total 

IJjoxidized  soya  oils 

2-Ethylhexyl  epoxytallates 

Octyl  epoxytallates 

All  other- 

Glycerol  monorioinoleate 

Isopropyl  nyristate 

Oleic  acid  esters: 

Butyl  oleate 

Glycerol  trioleate  (Triolein) 

Methyl  oleate 

Propyl  oleates  (including  normal  and  iso) 

Phosphoric  acid  esters 

Sebaoic  acid  esters: 

Dibutyl  sebaoate 

Di(2-ethylhexyl)  sebacate 

Stearic  acid  esters,  total 

n- Butyl  stearate 

All  other— 

Triethylene  glycol  di(caprylate-caprate) 

All  other  acyclic  plasticizers' 


1.000 
pounds 
311,742 


1 .  000 
pounds 
282, 577 


51,797 


50,485 


1,413 
22,278 

6,428 
10,833 
10,845 

15,664 
47,893 


1,322 
20,647 

6,669 
10, 930 
10, 917 

18,129 
45,278 

81, 630 


13,411 


"522" 
4,875 
1,788 
2,665 
3,461 


22,187 


3,172 
2,785 
2,973 

1,500 

13,566 


55,122 
11,056 
11,463 
3,989 

379 


1,847 
2,461 
2,096 
1,362 


15,004 
2,783 
2,929 
1,471 

131 


4,118 
2,925 


^   Does  not  include  data  for  clearly  defined  extenders  or  secondary  plasticizers. 

^  Calculated  from  rounded  figures. 

^   Statistics  for  the  dioctyl  phthalates  are  partly  estimated  because  part  of  the  data  which  were  published  in 
the  preliminary  report  were  erroneously  reported. 

*  Includes  data  for  alkylated  naphthalene,  glycol  dibenzoates,  hydrogenated  terphenyls,  phosphate  esters  (includ- 
ing sales  of  triphenyl  phosphate),  toluenesulfonamides,  tetrahydrofurfuryl  oleate,  and  other  cyclic  plasticizers. 

'  Adiplc  acid  polyesters  account  for  most  of  the  production  of  complex  linear  polyesters  and  polymeric 
plasticizers. 

'  Includes  data  for  citric  and  acetylcitric,  lauric,  myristic,  oleic,  palmitic,  pelargonic,  ricinoleic,  sebacic, 
and  tartaric  acid  esters,  glycerol  and  glycol  esters,  and  other  acyclic  plasticizers. 

Note. — The  total  production  and  sales  statistics  are  included  in  this  report  for  some  items  that  are  not  used 
exclusively  as  plasticizers. 


Production  of  cyclic  plasticizers  in  1966,    which  consisted  chiefly  of  the  esters  of  phthalic 
anhydride  and  phosphoric  acid,    amounted  to    897  million  pounds,    compared  with  799  million 
pounds  in  1965.    Sales  of  cyclic  plasticizers  in  1966  amounted  to  873  million  pounds,    valued  at 
$157  million,    compared  with  765  million  pounds,    valued  at  $133million,  in  the  previous  year. 

Production  of  acyclic  plasticizers  in  1966  amounted  to  312  million  pounds,  compared  with 
274  million  pounds  in  1965.  Sales  of  acyclic  plasticizers  in  1966  amounted  to  283  million  pounds, 
valued  at  $89  million,  compared  with  257  million  pounds,  valued  at  $81  million,  in  1965.  Pro- 
duction of  complex  linear  polyesters  in  1966  amounted  to  48  million  pounds,  and  that  of  epoxi- 
dized  esters,  to  87  million  pounds.  Other  products  included  in  the  acyclic  class  are  the  esters 
of  adipic,    azelaic,    oleic,    sebacic,    and  stearic  acids. 


SURFACE-ACTIVE  AGENTS 


Surface-Active  Agents 

The  surface-active  agents  included  in  this  report  are  organic  chemicals  that  reduce  the  sur- 
face tension  of  water  or  other  solvents  and  are  used  chiefly  as  detergents,    dispersing  agents, 
emulsifiers,    foaming  agents,    or  wetting  agents  in  either  aqueous  or  nonaqueous  systems.    Waxes 
and  products  used  chiefly  as  plasticizers  are  excluded.   Surface-active  agents  are  produced  from 
natural  fats  and  oils;  from  silvichemicals  such  as  lignin,    rosin,   and  tall  oil;  and  from  chemical 
intermediates  derived  from  coal-tar  and  petroleum.   A  major  part  of  the  output  of  the  bulk  chem- 
icals shown  in  this  report  is  consumed  in  the  form  of  packaged  soaps  and  detergents  for  house- 
hold and  industrial  use.    The  remainder  is  used  in  the  processing  of  textiles  and  leather,    in  ore 
flotation  and  oil  drilling  operations,    and  in  the  manufacture  of  agricultural  sprays,    cosmetics, 
elastomers,    foods,    lubricants,    paints,    pharmaceuticals,    and  many  other  products .    Table  19Ai^ 
shows  statistics  for  production  and  sales  of  surface-active  agents  grouped  by  ionic  class  and  by 
chemical  class  and  subclass.   All  quantities  are  reported  in  terms  of  100-percent  organic 
surface-active  ingredient  and  thus  exclude    all    inorganic    salts,   water,    and  other  diluents. 


TABLE  19A.  --Surface-active  agents :  U.S.  production  and  sales.  1966 

[Listed  below  are  all  surface-active   agents  for  which  reported  data  on  production  or  sales  may  be  published. 
(Leaders  are  used  where  the  reported  data  are   accepted  in  confidence   and  may  not  be  published  or  where  no  data 
were  reported.)    Table   19B  in  pt.    Ill  lists  all  surface-active   agents  for  which  data  on  production  or  sales  were 
reported   and  identifies  the  manufacturer  of  each] 


Sales^ 


Quantity'- 


Grand  total 

Benzenoid^ 

Nonbenzenoid^ 

Amphoteric  Surface-Actiie  Agents    

Anionic  Surface-Act  tie  Agents 

Total - 

Carboxylio  acids  (and  salts  thereof),  total 

Amine  salts  of  fatty,  rosin,  and  tall  oil  acids 

Carboxylic  acids  having  amide  or  ester  linkages,  total— 

N-Lauroylsarcosine,  sodium  salt 

All  other - 

Potassium  and  sodium  salts  of  fatty,  rosin,  and  tall 

oil  acids,  total 

Coconut  oil  acids,  potassium  and  sodium  salts,  total- 
Potassium  salt 

Sodium  salt 

Com  oil  acids,  potassium  and  sodium  salts 

Oleic  acid,  potassium  salt 

Oleic  acid,  sodium  salt 

Stearic  acid,  potassium  and  sodium  salts 

Tall  oil  acids,  potassium  and  sodium  salts,  total 

Potassium  salt 

Sodium  salt 

Tallow  acids,  sodium  salt 

All  other 

Phosphoric  and  polyphosphori c  acid  esters  (and  salts 

thereof),  total 

Alcohols  and  phenols,  ethoxylated  and  phosphated,  total- 
Mixed  linear  alcohols,  ethoxylated  and  phosphated 

Nonylphenol,  ethoxylated  and  phosphated 

All  other 

Alcohols,  phosphated  or  polyphosphated,  total 

2-Ethylhexyl  phosphate,  sodium  salt 

All  other 

See  footnotes  at  end  of  table. 


3,321,317 


9'i3,680 

2,377,637 

5,052 


U,138 

92,-130 

617 

3,847 

2,176 

2,258 

28,635 

15,597 

13,038 

493,847 

306,197 


4,124 
5,090 


IMO 

pounds 

1,766,053 


449,685 

1,316,368 

4,852 


5or 

2,678 

901 

1,777 


617 

337 

1,130 

918 

13,796 


2,037 
3,190 
3,569 


1.000 
dollars 
314,913 


81,468 

233,445 

3,225 


2,479 

731 

1,748 

2,201 

27 

2,174 


See  also  table  19B.  pt.  m.  which  lists  these  produ 


Identifies  the  i 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 
TABLE  19 A.  -Surface-active  agents:  U.S.  production  and  sales ,  -ZS66 --Continued 


Anionic  Surface-Act  ive  /Igents- -Continued 

Sulfonic  acids  (and  salts  thereof),  total 

Alkylbenzenesulfonates,  total 

Dodecylbenzenesulfonates,  total 

Dodecylbenzenesulfonic  acid 

Dodecylbenzenesulfonic  acid,  calcium  salt 

Dodecylbenzenesulfonic  acid,  isopropanolamine  salt-- 

Dodeoylbenzenesulfonlc  acid,  isopropylamine  salt 

Dodecylbenzenesulfonic  acid,  sodium  salt 

Dodecylbenzenesulfonic  acid,  triethanolamine  salt 

All  other — 

Other  alkylbenzenesulfonates,  total 

Tridecylbenzenesulfonic  acid 

Tridecylbenzenesulfonic  acid,  sodium  salt 

All  other -  — 

Benzene-,  cumene-,  toluene-,  and  xylenesulfonates,  total 

Xylenesulfonic  acid,  ammonium  salt 

Xylenesulfonlc  acid,  sodium  salt 

All  other 

Ligninsulfonates,  total 

Ligninsulfonic  acid,  calcium  salt 

Ligninsulfonic  acid,  sodium  salt 

All  other 

Naphthalenesulfonates,  total 

Butylnaphthalenesulfonio  acid,  sodium  salt 

All  other-- 

Other  sulfonic   acids,   total 

N-hfethyl-N-oleoyltauTine,    sodium  salt 

Sulfosuccinamic   acid  derivatives 

Sulfosuocinic  acid  esters,   total 

Sulfosuccinic   acid,   bis(2-ethylhexyl)   ester, 

sodlimi  salt 

All  other 

All  other  sulfonic  acids 

Sulfuric  acid  esters  (and  salts  thereof): 

Acids,  amides,  and  esters,  sulfated,  total 

Coconut  oil  acids  -  ethanolamine  condensate,  sulfated, 

potassium  salt 

Esters  of  sulfated  oleic  acid,  total 

Butyl  oleate,  sulfated,  sodium  salt 

Isopropyl  oleate,  sulfated,  sodium  salt 

Propyl  oleate,  sulfated,  sodium  salt 

All  other 

Oleic  acid,  sulfated,  disodium  salt 

Tall  oil,  sulfated,  sodium  salt 

All  other 

Alcohols  and  phenols,  sulfated,  total 

Dodecyl  sulfate  salts,  total 

Dodecyl  sulfate,  magnesium  salt 

Dodecyl  sulfate,  sodium  salt 

Dodecyl  sulfate,  triethanolamine  salt 

All  other -  — - — 

2-Ethylhexyl  sulfate,  sodium  salt 

Ootadecyl  sulfate,  sodium  salt 

Octyl  sulfate,  sodium  salt 

All  other - 

Ethers,  sulfated,  total 

Alkylphenols,  ethoxylated  and  sulfated 

Dodecyl  alcohol,  ethoxylated  and  sulfated,  ammonium 

salt 

Dodecyl  alcohol,   ethoxylated  and  sulfated,    sodium  salt 
Mixed  linear  alcohols,   ethoxylated  and  sulfated, 

sodium  salt 

All  other 

See   footnotes  at  end  of  table. 


1.000 


596,416 

506,544 

92,142 

11,287 

355 

3,780 

391,921 

4,124 

2,935 

89,872 

387 

89,485 

70,922 

16,781 

22,127 

32,014 

4^1,537 

284,018 

54,308 

103,211 

8,277 

834 

7,443 

2,797 
1,714 
7,736 


1.000 
670,985 


137,936 
132,873 


84,634 

4,317 

5,166 

5,063 

387 

787 

3,889 

70,791 

18,780 

20,159 

31,852 

429,550 

272,933 

53,406 

103,211 

6,614 

6,614 
26,094 
2,589 
1,579 
7,275 

4,926 
2,349 
14,651 


22,560 
21,496 
4,500 
2,610 


11,764 

1,066 

1,556 

1,064 

50 

329 

685 

5,117 

1,286 

1,807 

2,024 

15,719 
7,109 
4,097 
4,513 
2,615 

2,615 
14,014 
1,335 
857 
3,903 

2,721 


6,597 

4,806 

1,343 

3,432 

1,772 

401 

357 

355 

133 

512 

489 

153 

2,296 

2,190 

656 

8,699 

768 

734 

179 

5,412 

8,898 

2,795 

28,126 

1^,235 

39,617 

239 

225 

69 

14,862 

11,117 

5,129 

8,493 

16,023 

1,582 

309 

163 

172 

185 

76 



16,290 

6,798 

137,669 

9,601 

8,166 

1,911 

367 

2,718 

2,065 

723 

4,310 

4,531 

670 

120,673 

SURFACE  ACTIVE  AGENTS 
TABLE  19A.  --Surface-active  agents :  U.S.  production  and  sales ,  1966- 


Chemioal 

Production^ 

Sales^ 

Quantity^ 

Value 

Unit 
valued 

Anionic  Surface -Active  .4gents--Contlnued 

Sulfuric  acid  esters   (and  salts  thereof )— Continued 

Natural  fats  and  oils,   sulfated,    total 

Castor  oil,    sulfated,    sodium  salt 

Coconut  oil,    sulfated,    sodium  salt 

1.000 

pounds 

30,-121 

6,504 

2,100 

1,934 

1,469 

962 

238 

247 

5,963 

9,502 

1,502 

133,187 
161,843 

1 .  000 

pounds 

19,520 

3,954 

578 

1,427 

743 

'"    138 
3,535 
7,135 
2,010 

297,800 
126,882 

1.000 

dollars 

3,824 

1,175 

142 

226 

152 

46 
654 
931 
498 

42,866 
50,918 

Per 
pound 

$0.20 
.30 
.25 

Soybean  oil,    sulfated,    sodium  salt — - — 

.33 

Canonic  Surface-Active  Agents 

Amine  oxides  and  oxygen-containing  amines   (except  those 

38,518 

685 
464 
3,384 
1,084 
779 
1,400 
30,722 

17,451 

630 
458 

796 
1,312 

15,364 

257 
210 

'"'    375 
869 

6,992 

.41 

(Mixed   alkyl)  amine,   ethoxylated 

(Tallow  alJsyl) amine,   ethoxylated 

.66 

Amines  and  amine  oxides  having  amide  linkages,    total 

.46 

9,067 

'"    302 
8,765 

7,046 

4,579 

2,286 

181 

1,338 

59,636 

8,759 

75 

202 

8,482 

5,337 

"5,337 
1,268 

3,029 
45 
62 

2,922 

3,607 

3,607 
356 

Coconut  oil  acids  -  diethylenetriamlne  condensate 

Oleic  acid  -  diethylenetriamlne  condensate 

.60 
.31 

Carboxylic  acid  -  diamine  and  polyamine  condensates. 

Oleic  aoid  -   ethylenediamlne  condensate,   mono- 

Stearic  acid  -  ethylenediamlne  condensate,   mono- 

All  other 

Other  amines   and  amine  oxides  having  amide  linkages 

Amines,   not  containing  oxygen  (and  salts  thereof),    total— 

.28 

11,761 
1,839 
1,807 
3,905 
4,210 

32,252 
1,910 
1,605 

11,292 
1,804 

5,670 
9,971 

13,488 
233 

13,255 

10,405 
1,291 
1,716 
3,895 
3,503 

26,083 
1,203 

10,071 

872 

700 

4,179 

9,058 

"    254 
25,146 

697 
3,602 

636 

678 
1,540 

748 
8,292 

657 

"2,267 

379 

324 

1,220 

3,445 

133 
9,157 

.36 

Dodecylamlne — 

Secondary  and  tertiary  monoamines,    total 

N,N-Diniethyloctadecylamine - 

All  other 

.52 

Groups  listed  above  for  which  separate  sales  data  may  not 

See  footnotes  at  end  of  table. 


50  SYNTHETIC  ORGANIC  CHEMICALS,  1966 

TABLE  19A.  —Surface-active  agents.-  U.S.  production  and  sales,  2966- 


Chemioal 


Production^ 


Oxygen- containing  quaternary  annnonium  salts  (except  those 
having  amide  linkages) 

l^atemary  ammonium  salts  having  amide  linkages 

Quaternary  ammonium  salts,  not  containing  oxygen,  total — 
Acyclic,  total 

Bls(  coconut  oil  alkyl)  dime  thy  Ifimmonium  chloride 

Bis(hydrogenated  tallow  alkyl )dlmethylammonium 

chloride 

Dodecyltrimethylamraonium  bromide  and  chloride 

Hexadecyltrimethylaramonium  bromide 

N,N,N',N',N'-Pentamethyl-N-( tallow  alkyl)trimethylene- 

bis-[ ammonium  chloride] 

All  other 

Benzenoid,    total 

Benzyl( coconut  oil  alkyl) dime thylammonium  chloride 

Benzyldimethyl(mixed  alkyl) ammonium  chloride 

Benzyldimethyloctadecylammonium  chloride 

Beuzyldodecyldimethylaramonium  chloride 

(3,'4-Dichlorobenzyl)dodecyldimethylammonium  chloride-- 

(Dodecylbenzyl)trlmethylammonium  chloride 

All  other 

^anionic  Surface-Active  Agents 

Total — — 

Carboxylic  acid  amides,  total 

Carboxylic  acid  -  aUkanolamlne  condensates,  total 

Diethanolamine  condensates  (amlne/acid  ratio  =2/l), 

total - — 

Capric  acid 

Coconut  oil  acids 

Laurie  acid 

Oleic  acid 

Stearic  acid 

Tall  oil  acids 

All  other 

Diethanolamine  condensates  (amine/acid  ratio  =  2/l), 

total 

Coconut  oil  acids 

Laurie  acid 

Oleic  acid 

Stearic  acid 

All  other- — 

Ethanolamlne  condensates  (amine/ acid  ratio  =2/l), 

total 

Coconut  oil  acids 

All  other - 

Ethanolamlne  condensates  (other  amine/acid  ratios) 

Isopropanolamine  condensates,  total 

Laurie  acid 

All  other- 

Other  alkanolamlne  condensates 

Carboxylic  acid  -  alkanolamine  condensates,  ethoxylated- 
Carboxyllo  acid  -  diamine  and  polyamine  condensates 

(nonionic),  total 

Stearic  acid  -  ethylenedlamlne  condensate  (amine/acid 

ratio  =1/2)— 

All  other 

Carboxylic  acid  esters,  total 

Anhydrosorbitol  esters,  total 

Anhydrosorbltol  monoester  of  tall  oil  acids 

Anhydrosorbitol  monolaurate 

See  footnotes  at  end  of  table. 


93,020 


80, 105 

25,555 

110 

13,194 

5,450 

2,113 

864 

574 

3,250 

37,380 
17,826 
17,069 

769 
1,037 

679 


1,156 
1,025 

131 
9,154 
5,842 

866 
4,976 
1,018 


13,787 

435 

2,381 


30,959 
1,620 


63,240 


18,514 
98 
10, 687 
2,730 
2,020 
572 


2,407 


773 
1,035 


1,142 

1,013 

129 


542 
12,238 


1,622 
1,956 
16,756 


77 

59 

51 

11,280 

11,367 

5,169 

7,429 

6,822 

5,735 

346 

346 

287 

3,588 

3,052 

2,551 

413 

396 

356 

553 

521 

374 

43 

35 

25 

303 
3,628 


SURFACE-ACTIVE  AGENTS 
TABLE  19A.  —Surface-active  agents:  U.S.  production  and  sales,  1966- -Continued 


Surface-Active  Agent 


-Continued 


Carboxylio  acid  esters — Continued 
Anhydrosorbltol  esters — Continued 

Anhydrosorbitol  trioleate 

All  other 

Ethoxylated  anhydrosorbitol  esters,  total 

Ethoxylated  anhydrosorbitol  monolaurate 

Ethoxylated  anhydrosorbitol  mono-oleate 

Ethoxylated  anhydrosorbitol  monopalmitate 

Ethoxylated  anhydrosorbitol  monostearate 

Ethoxylated  anhydrosorbitol  trioleate 

Ethoxylated  anhydrosorbitol  tristearate 

All  other 

Ethylene  glycol  and  dietliylene  glycol  esters,  total 

Diethylene  glycol  monolaurate 

Die-thylene  glycol  mono-oleate 

Diethylene  glycol  monostearate 

Ethylene  glycol  distearate 

Ethylene  glycol  monostearate 

All  other - 

Glycerol  esters,  total 

Complex  glycerol  esters 

Glycerol  esters  of  chemically  defined  acids,  total 

Glycerol  monolaurate 

Glycerol  mono-oleate 

Glycerol  monorlcinoleate 

Glycerol  monostearate 

All  other 

Glycerol  esters  of  mixed  acids 

Natural  fats  and  oils,  ethoxylated,  total 

Castor  oil,  ethoxylated 

All  other 

Polyethylene  glycol  esters,  total 

Polyethylene  glycol  esters  of  chemically  defined 

acids,  total 

Polyethylene  glycol  dllaurate 

Polyethylene  glycol  dioleate 

Polyethylene  glycol  distearate 

Polyethylene  glycol  monolaurate 

Polyethylene  glycol  mono-oleate 

Polyethylene  glycol  monostearate 

All  other 

Polyethylene  glycol  esters  of  rosin  and  tall  oil 

acids,  total 

Polyethylene  glycol  sesquiester  of  tall  oil  acids 

All  other 

Polyethylene  glycol  esters  of  other  mixed  acids,  total 
Polyethylene  glycol  sesquiester  of  coconut  oil  acids 

All  other 

Polyglycerol  esters 

Propanediol  esters,  total 

1,2 -Propanediol  monolaurate 

1,2-Propanediol  monostearate 

All  other 

Other  carboxylic  acid  esters 

Ethers,  total - 

Benzenoid  ethers,  total 

Dlnonylphenol,  ethoxylated 

Dodecylphenol,  ethoxylated 

Iso-octylphenol,  ethoxylated 

Nonylphenol,  ethoxylated 

Phenol,  ethoxylated 

All  other 

Nonbenzenoid  ethers,   total 

Dodecyl  alcohol,   ethoxylated 

Hexadecyl  alcohol,   ethoxylated 

See  footnotes  at  end  of  table. 


1.000 
pounds 

7-48 
10,223 
12,3^9 
2,'iOO 
^,753 


761 
1,301 
<i,291 

548 

126 
1,025 

490 
1,016 
1,086 
71,460 
4,259 
23,844 

1,927 

20,974 
943 
43,357 
4,181 
3,611 
570 
24,436 

19,068 
989 
3,042 
361 
5,260 
3,509 
4,835 
1,072 

4,558 

3,771 
787 
810 
258 
552 
428 

3,534 
142 

2,817 

575 

11,904 


2,101 
120,370 

6,507 
105,054 
209,839 


4,650 
340 

2,634 
526 

1,825 

3,892 

528 

120 

825 

437 

854 

1,128 

61,279 

2,976 

22,070 

51 

1,588 

52 

19,929 

450 

36,233 

3,542 


3,542 
16,133 


2,606 

3,960 

763 

3,915 

3,138 
777 
578 
181 
397 
468 

2,079 
145 

1,649 

285 

11,660 

337,431 


205,858 
1,821 
10,359 
1,602 

120,276 

71,800 

131,573 

2,224 

485 


3,384 
5,339 
1,241 
1,920 

157 
1,124 

227 

670 

1,306 

161 

34 

242 

137 

329 

403 

16,860 

1,257 

7,216 

19 

565 

29 

6,401 

202 

8,387 

1,254 


4,441 
263 
279 
IW 
957 
953 

1,545 
330 

984 
740 
244 
189 

50 
139 
230 
591 

69 
444 

78 
5,338 

59,760 


35,905 

410 

1,167 

384 

18,749 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  19A.  —  Surface-active  agents :  U.S.  production  am 

sales,  1966- 

Continued 

Chemical 

Production-'- 

Sales^ 

Quantity^ 

Value 

Unit 
valued 

Nontonic  Surfacr-Aclue    (grnts --font  Ir.ued 

Ethers  —Ctontinued 

Nonbenzenoid  ethers— Continued 

pounds 

104,448 
3,684 
549 
8,329 
92,829 
2,432 

1.000 

81,516 
2,597 

7,367 
37,384 

1,260 

dolUn 
10,299 
1,358 

"  1,614 
9,427 
1,095 

pound 

$0.13 
.52 

9-Octadecenyl  alcohol,   ethoxylated 

rridecyl  alcohol,  ethoxylated — 

All  other 

.22 

.25 

.37 

er  no     o     o  sur  aoe  ac     ve  agen 

sul- 


'  All  quantities  are  given  in  terms  of  100-percent  organic  surface-active  ingredient 

^  Sales  Include  products  sold  as  bulk  surface- active  agents  only. 

^   Calculated  from  rounded  figures. 

^  The  term  "benzenoid, "  as  used  in  this  report,  describes  any  surface- active  age 
whose  molecxilar  structure  includes  1  or  more  6-membered  carbocyclic  or  heterocycli 
bonds  (e.g.,  the  benzene  ring  or  the  pyridine  ring). 

'  Includes  the  lignlnsulfonates,  which  were  classed  as  benzenoid  in  previous  years. 

^  Includes  production  of  "all  other"  sulfonic  acids  and  of  "all  o-ther"  sulfated  alcohols  and  phenols;  also  in- 
cludes sales  of  "all  other"  potassium  and  sodium  salts  of  fatty,  rosin,  and  tall  oil  acids  and  of  "all 
fated  ethers. 

Note:  The  surface- active  agents  included  in  this  report  are  organic  chemicals  that  reduce  the  surface  tension  of 
water  or  o-ther  solvents  and  are  used  chiefly  as  detergents,  dispersing  agents,  emulsifiers,  foaming  agents,  or  wet- 
ting agents  in  either  aqueous  or  non  aqueous  systems.  The  properties  which  make  a  product  useful  as  a  surface- active 
agent  are  due  to  a  molecular  structure  in  which  one  or  more  polar  functional  groups  are  balanced  by  a  large  non- 
polar  group.  Uie  polar,  or  hydrophilic,  groups,  which  may  be  anionic,  cationic,  or  nonionlc,  tend  to  make  the 
product  misclble  with  water  and  other  polar  solvents  and  immiscible  with  oil.  The  nonpolar,  or  hydrophobic,  group, 
which  usually  consists  of  a  long-chain  alkyl  or  aliylphenyl  radical,  tends  to  make  the  product  miscible  with  oil 
and  other  nonpolar  solvent  and  immiscible  with  water.  Because  of  this  balance  between  hydrophilic  and  hydrophobic 
tendencies,  the  molecules  of  surface- active  agent  concentrate  at  the  liquid  phase  boundaries  and  reduce  the  inter- 
facial  tension  of  any  system  in  which  they  are  introduced.  Thus  at  an  oil/water  interface  they  may  promote  the 
formation  of  a  stable  emulsion;  at  an  air/water  interface  they  may  promote  the  formation  of  foam;  and  at  a  liquid/ 
solid  boundary  they  may  act  as  detergents,  dispersing  agents,  or  wetting  agents. 


Total  U.S.    production  of  surface-active  agents  in  1966  amounted  to  3,  321   million  pounds,    or 
4.8  percent  more  than  the  3,  170  million  pounds  reported  for   1965.    These  statistics  include  data 
for  fatty  monoamines,   which  were  previously  reported  in  the   section  on  Miscellaneous  Organic 
Chemicals,    and  for  potassium  and  sodium  salts  of  fatty,    rosin,    and  tall  oil  acids  (soaps),    which 
were  for  the  most  part  not  previously  reported.    Sales  of  bulk  surface-active  agents  in   1966 
amounted  to   1,  766  million  pounds,    valued  at  $315  million,    compared  with  sales  in  1965  of  1,  698 
millionpounds,  valuedat  $300  million.    Sales  in   1966  were  thus  4.  0  percent  larger  than  in   1965  in 
terms  of  quantity  and  4.  9  percent  larger  in  terms  of  value.    Sales  statistics  for   1965  and  1966 
reflect  sales  of  bulk  surface-active  agents  only,    whereas  sales  data  reported  for  earlier  years 
included  surface-active  agents  sold  as  active  ingredients  in  formulated  and  packaged  products, 
as  well  as  strictly  bulk  materials.    Thus  the  statistics  for  1965  and  1966  are  not  strictly  com- 
parable with  those  for  earlier  years. 

Production  of  anionic   surface-active  agents  in   1966  amounted  to  2,  469  million  po-^nds,    or 
74.  3  percent  of  the  total   reported  for   1966  and  4.  7  percent  more  than  the  anionic  output  reported 
for   1965.    Sales  of  anionics  in  1966  amounted  to   1,  112  million  pounds,    valued  at  $141   million.    Of 
the  total  anionic  output,    944  million  pounds  consisted  of  potassium  and  sodium  salts  of  fatty, 
rosin,    and  tall  oil  acids,    of  which  494  million  pounds  was  the  sodium  salt  of  tallow  acids  and  92 
million  pounds  was  the  sodium  salt  of  coconut  oil  acids;   596  million  pounds  consisted  of  alkyl- 
benzenesulfonates,    of  which  392  million  pounds  was  the   sodium  salt  of  dodecylbenzenesulfonic 
acid  and  92  million  pounds  was  the  free  acid;  and  442  million  pounds  consisted  of  ligninsulfonic 
acid  salts,    of  which  284  million  pounds  was  the  calcium  salt  and  54  million  pounds  was  the  sodium 
salt. 

Production  of  nonionic  surface-active  agents  in  1966  amounted  to  686  million  pounds,    or 
20.6  percent  of  the  total   reported  for   1966  and  4.0  percent  more  than  the  nonionic  output  reported 
for   1965.    Sales  of  nonionics  in   1966  amounted  to  523  million  pounds,    valuedat  $119  million.    Of 
the  total  nonionic  output,    234  million  pounds  consisted  of  alkylphenol  ethoxylates  and  other 
benzenoid  ethers,    of  which  120  million  pounds  was  nonylphenol  ethoxylate;  210  million  pounds 
consisted  of  alcohol  ethoxylates  and  other  nonbenzenoid  ethers,    of  which  104  million  pounds  was 
mixed  linear  alcohol  ethoxylate;  80  million  pounds  consisted  of  alkanolamides,    of  which  18  mil- 
lion pounds  was  coco  diethanolamide  (made  with  a   1/1    ratio  of  diethanolamine  to  coconut  oil 
acids),    17  million  pounds  was  lauric  diethanolamide  (1/1   ratio),    and  13  million  pounds  was  coco 


PESTICIDES  AND  RELATE:^  PRODUCTS 


53 


diethanolamide  (2/1   ratio);  and  71  million  pounds  consisted  of  glycerol  esters,    of  which  21  mil- 
lion pounds  was  glycerol  monostearate. 

Production  of  cationic  surface-active  agents  in  1966  amounted  to   162  million  pounds,    or  4.9 
percent  of  the  total  reported  for  1966  and  9.4  percent  more  than  the  cationic  output  reported  for 

1965.  Sales  of  cationics  in  1966  amounted  to  127  million  pounds,    valued  at  $51  million.    Of  the 
total  output  of  cationics,    39  million  pounds  consisted  of  quaternary  ammonium  salts  not  contain- 
ing oxygen,    of  which  18  million  pounds  was  bis  (hydrogenated  tallow  alkyl)dimethylammonium 
chloride;  and  32  million  pounds  consisted  of  primary  monoamines  not  containing  oxygen,    of  which 
11  million  pounds  was  (hydrogenated  tallow  alkyl)amine. 

Production  of  amphoteric  surface-active  agents  in  I966  amounted  to  5.  1  million  pounds,    or 
approximately  0.  2  percent  of  the  total  reported  for  1966  and   1.  2  percent  less  than  the  amphoteric 
output  reported  for   1965.    Sales  in  1966  amounted  to  4.  9  million  pounds,    valued  at  $3.  2  million. 

The  difference  between  production  and  sales    reflects   inventory  changes  and,   for   1965  and 

1966,  captive  consumption  of  soaps  and  surface-active  agents  by  synthetic  rubber  producers  and 
by  manufacturers  of  cosmetics,    packaged  detergents,    bar  soaps,    and  other  formulated  consumer 
products.    In  some  instances  the  difference  may  also  reflect  quantities  of  surface-active  agents 
used  as  chemical  intermediates,    e.g.    nonionic  alcohol  and  alkylphenol  ethoxylates  which  may  be 
converted  to  anionic  surface-active  agents  by  phosphation  or  sulfation. 

Pesticides  and  Related  Products 

This  section  of  the  report  covers  pesticides  (fungicides,    herbicides,    insecticides,    and 
rodenticides)  and  related  products  such  as  plant  hormones,    seed  disinfectants,    soil  conditioners, 
soil  fumigants  and  synergists.    The  data  are  given  in  terms  of  100-percent  active  material;  they 
thus  exclude  such  nnaterials  as  diluents,    emulsifiers,    and  wetting  agents.    Statistics  on  produc- 
tion and  sales  of  pesticides  and  related  products  in  1966  are  given  in  table  20A,''"^ 


TABLE  20A.— Pesticides  and  related  products.-  U.S.  production  and  sales,  1966 

[Listed  below  are  all  pesticides  and  related  products  for  which  any  reported  data  on  production  or  sales  may  be  pub- 
lished. (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no 
data  were  reported. )  Table  20B  in  pt.  Ill  lists  all  pesticides  and  other  organic  agricultural  chemicals  for  which 
data  on  production  or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Sales 


Grand  total 

PESTICIDES  AND  RELATED  PRODUCTS,    CYCLIC 

Total - — 

Fungicides,   total 

3,5-Dijnethyl-l,3,5,2H-tetrahydrothiadlazine-2-thione 

(DMTT) — 

Mercury  fungicides 

Naphthenic  acid,   copper  salt 

Pentaohlorophenol   (PCP) 

S-Qiiinolinol   (8-Itydroxyquinoline),   copper  salt 

2,^,5-Trichlorophenol  and  salts 

All  other^- 

Herbicides  and  plant  hormones,  total 

Dinitrobutylphenol  (DNBP)— - 

Dlnltrobutylphenol,  ammonium  salt 

See  footnotes  at  end  of  table. 


1,110 
1,035 
3,211 
'i3,262 
-426 
17,929 
33,653 

266,  o-;? 


i.mo 

pounds 
822,256 


$0.71 


.^9 

A. 02 

.27 


1.25 
-T32" 

1.57 


■  See  also  table  20B,   pt.  TO,  which  lists  the$e  products  and  Identifies  the  manufacturers. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 
TABLE  20A.— Pesticides  and  related  products .-  U.S.  production  and  sales ,  i 566- -Continued 


PESTICIDES  AND  RELATED  PRODUCTS,    CYCLIC--Conxinued 


Herbicides   and  plant  hormones — Continued 

1-Naphthaleneacetio  acid  and  esters  and  'salts 

Phenoxyacetio  acid  derivatives : 

2,A-Dichlorophenoxyacetic  acid   (2,'4-D) 

2,'i-Dichlorophenoxyaoetic  acid  esteTs  and  salts,    total- 

2,A-Dichlorophenoxyacetic  acid,   n-butyl  ester 

2,'i-Diohlorophenoxyaoetlo  acid,   dimethylamine  salt 

2,<i-Dichlorophenoxyacetic  acid,    iso-ootyl  ester 

2,'4-Dlchlorophenoxyacetio  acid,    isopropyl  ester 

All  other 

2,A,5-Triohlorophenoxyaoetic  acid  (2,'i,5-T) 

2,4,5-Trichlorophenoxyaoetic  acid  esters  and  salts, 

total 

2,'i,5-Trichlorophenoxyacetlc  acid,  n-butyl  ester 

2,'4,5-Trichlorophenoxyaeetio  aold,  iso-octyl  ester 

All  other 

Phenylmercury  acetate  (FMA) 

All  other^ 


72 

522 

17 

966 

T) 

?66 

328 

30,962 

15,^89 

18 

059 

10 

U6 

31 

28,021 
55,281 
20,401 
11,669 
8,181 
2,598 
12,  «2 
5,096 

10,037 


8,785 
22,867 
9,603 
A,  829 
2,979 
880 
A,  576 
'4,705 

8,119 

2,116 

6,003 

2,366 

165,090 


Insecticides  and  rodentioldes,  total 

Aldrin-toxaphene  group'' 

a-Bis(p-chlorophenyl)  |j  ,|:,(i-trichloroe thane  (DDT) 

Hexachlorocyclohexane  (Benzene  hexachloride )  and  lindane- 
Organophosphorus  insecticides,  total 

0, 0-Diethyl  O-p-nitrophenyl  phosphorothloate  (Para- 


0,0-Dimethyl  O-p-nitrophenyl  phosphorothloate  (Methyl 

parathion) 

All  other^ - 

All  other' — 


Wl,349 
73,342 


35,862 

18,036 
65,075 


351,473 
128,161 
101,466 
8,522 
57,084 


26,973 
14,575 
56,240 


16,814 
2,018 
66,426 


18,709 
37,066 
55,143 


PESTICIDES  AND  RELATED  PRODUCTS  ACYCLIC 


Total - 


Fungicides,    total 

Dlmethyldlthiooarbamlc  acid,    ferric  salt   (Ferbam) 

Ethylene  bis(dithiocarbajnic  acid),   disodium  salt   (Nabam) 

Ethylene  bis(dlthiocarbamic   acid),   zinc  salt   (Zineb) 

All  other' - 


1,379 
2,053 
4,721 
28,627 


Herbicides  and  plant  hormones" 

Insecticides,  rodenticides,  and  soil  conditioners  and 

fumigants,  total 

l,2-Dlbromo-3-chloropropane  (DBCP) 

Methyl  bromide  (Bromoethane) 

Organophosphorus  insecticides,  total 

Tetraethyl  pyrophosphate  (TEPP) 

Other  organic  phosphorous  insecticides'' 

All  other  insecticides,  rodenticides,  and  soil  condi 
tioners  and  fumigants -'■° 


1,679 
2,209 
4,326 
27,866 


130,884 


8,722 
16,345 
46,580 

46,580 

70,129 


5,266 
16,324 
39,976 
287 
39,689 

69,318 


66,746 


2,658 
6,652 

48,249 
280 

47,969 

9,187 


^   Calculated  from  rounded  figures. 

^  Includes  captan,  dlchlone,  folpet,  glyodln,  pentachloronitrobenzene,  sodium  pentaohlorophenate,  tri-  and 
tetrachlorophenols,  and  others. 

^   Includes  dimethylurea  compounds,  dinitrophenol  compounds,  endothal,  isopropyl  carbanilates  (IPC  and  CIPC), 
maleic  hydrazide,  propanil,  triazlnes,  uracils,  and  others. 

""   Includes  aldrin,  ohlordan,  dieldrin,  endrln,  heptachlor,  terpene  polychlorinates,  and  toxaphene. 

^  Includes  carbophenothion,  diazlnon,  ronnel,  other  phosphorothioates  and  phosphorodlthioates,  and  others. 

^   Includes  DDD,  4,4-Dlchlorobenzllate,  dlcofol,  endosulfan,  methoxychlor,  and  other  chlorinated  insecticides, 
oarbaryl,  DEET,  small  amounts  of  rodenticides  and  insect  repellents,  hexachlorocyclohexane  and  lindane  (production 
only),  synergists,  and  others. 

Includes  dithiocarbamates  Including  dodine,  maneb,  mercury  compounds,  PETD  and  others. 

^  Includes  CDAA,  methanearsonic  acid's  disodium  salt  and  sodium  salt,  thiocarbamate  and  organophosphorus  herbi- 
cides, sodium  diohloropropionate,  sodium  TCA,  and  others. 

'  Includes  DDVP,  disulfoton,  ethion,  malathion,  naled,  phorate,  TEPP  (production  only),  and  others. 
^°  Includes  soil  conditioners  and  fumigants,  metaldehyde  (which  is  a  molluscioide),  small  quantities  of  rodenti- 
cides, and  others.      . 

Note:  Sale  of  gamma  Isomer  content  in  benzenehexachloride  and  lindane  is  not  publishable  for  1966  because  publics 
tion  would  reveal  the  operations  of  the  individual  producers.  Production  of  ganma  isomer  content  has  not  been 
publishable  since  1963. 


MISCELLANEOUS  CHEMICALS  55 

Production  of  pesticides  and  related  products  in  1966  amounted  to  1,013  million  pounds-- 
about  15  percent  more  than  the  877  million  pounds  reported  for   1965.    Sales  in  1966  were  822 
million  poxmds,    valued  at  $584  million,    compared  with  764  million  pounds,    valued  at  $497  mil- 
lion in  1965. 

The  output  of  cyclic  pesticides  and  related  products  included  in  the  cyclic  group  amounted  to 
777  million  pounds  in  1966--about  14  percent  more  than  the  683  million  pounds  produced  in  1965. 
Sales  in  1966  were  605  million  pounds,  valued  at  $447  million,  connpared  with  582  million  pounds, 
valued  at  $378  million,    in  1965. 

Production  of  acyclic  pesticides  and  related  products  in  1966  amounted  to  236  million  pounds, 
compared  with  the  195  million  pounds  reported  for   1965.    Sales  in  1966  were  217  million  pounds, 
valued  at  $137  million,    compared  with  182  million  pounds,    valued  at  $119  million,    in  1965. 

Miscellaneous  Chemicals 

The  term  miscellaneous  chemicals  comprises  those  synthetic  organic  products  that  are  not 
included  in  the  other  use  groups  covered  by  this  report.    They  include  products  that  are  employed 
in  a  great  variety  of  uses:    The  number  of  chemicals  used  exclusively  for  only  one  purpose  is  not 
large.    Among  the  products  covered  are  those  used  for  gasoline  and  lubricating  oil  additives, 
paint  driers,    photographic  chemicals,    tanning  materials,    flotation  reagents,    refrigerants,    tex- 
tile polymers,    sequestering  agents,    organic  fertilizers,    antifreeze  chemicals,    solvents,    and 
acyclic  intermediates.   Statistics  on  production  and  sales  of  miscellaneous  chemicals  in  1966  are 
given  in  table  21A." 

Production  of  miscellaneous  cyclic  and  acyclic  chemicals  in  1966  totaled  57.  3  billion  pounds 
or  13  percent  more  than  the  output  of  50.  8  billion  pounds  reported  for  1965.   Sales  of  miscellane- 
ous chemicals  in  1966  amounted  to  24.  5  billion  pounds,    valued  at  $3.  2  billion,    compared  with 
22.0  billion  pounds,    valued  at  $2.9  billion,    in  1965. 

The  total  output  of  miscellaneous  cyclic  chemicals  in  1966  was  1.4  billion  pounds,    or  20 
percent  more  than  the  output  of  1 .  1   billion  pounds,    reported  for   1965.   Sales  in  1966  totaled  739 
million  pounds,    valued  at  $271  million,    compared  with  625  million  pounds,    valued  at  $245  mil- 
lion,   in  1965.    In  1966  the  most  important  groups  of  cyclic  compounds  were  the  lubricating  oil 
additives,    the  output  of  which  was  390  million  pounds,    and  synthetic  tanning  materials,    the  output 
of  which  was  36  million  pounds. 

Total  production  of  miscellaneous  acyclic  chemicals  in  1966  was  55.9  billion  pounds  or  12 
percent  more  than  the  output  of  49.  7  billion  pounds  reported  for   1965.    Sales  in  1966  totaled 
23.  8  billion  pounds,    valued  at  $2.  9  billion,    compared  with  21.  4  billion  pounds,    valued  at  $2.  6 
billion,    in  1965.    The  statistics  for  acyclic  chemicals  have  been  regrouped  primarily  by  chemical 
function.    The  order  of  precedence  of  these  functional  groups  is  generally  that  used  in  naming 
and  indexing  chemical  pounds  by    Chemical  Abstracts,   but  other  important  considerations  are  com- 
parability with  statistics  for  earlier  years  and  the  need  for  groupings  that  will  not  reveal  the 
operations  of  individual  producers.    Some  of  the  groupings  by  use  found  in  earlier  reports  have 
been  omitted  for   1966,    as  such  groupings  are  difficult  to  maintain  due  to  the  variety  of  uses  and 
frequent  shifts  in  principal  usage  for  many  important  items. 

In  1966,    the  most  important  groups  of  acyclic  chemicals  were  the  halogenated  hydrocarbons, 
the  nitrogenous  compounds,    iTionohydric  alcohols,    and  aldehydes  and  ketones.    Production  of 
halogenated  hydrocarbons,    which  are  used  as  solvents,    intermediates,    refrigerants,    and  aerosol 
propellants,    totaled  11.6  billion  pounds.    The  most  important  chemicals  in  this  group  were 
dichloroethane  (production  of  3.6  billion  pounds  in  1966  compared  with  2.  5  billion  pounds  in 
1965)  and  vinyl  chloride  (2.  5  billion  pounds  compared  with  2.0  billion  pounds).    Output  of  nitro- 
genous compounds  totaled  8.  9  billion  pounds.    The  most  important  chemical  in  this  group  was 
urea  (used  principally  in  fertilizers  and  as  a  feed  additive),    production  of  which  was  3.4  bil- 
lion pounds  in  1966  compared  with  2.6  billion  pounds  in  1965. 

Monohydric  alcohols,    which  are  used  largely  as  solvents  and  intermediates,   were  the  third 
largest  group  in  1966,    with  production  of  8.8  billion  pounds.    The  most  important  items  in  the 
group  were  synthetic  methanol,    production  of  3.  3  billion  pounds  in  1966  compared  with  2.  9  bil- 
lion pounds  in  1965;  synthetic  ethyl  alcohol,    1.  9  billion  pounds  compared  with  2.  0  billion  pounds, 
and  isopropyl  alcohol,    1.  7  billion  pounds  compared  with  1.  5  billion  pounds.    Aldehydes  and 
ketones,   which  are  also  used  largely  as  solvents  and  intermediates,    were  the  next  largest  group, 
with  production  of  8.  3  billion  pounds.    The  most  important  items  in  the  group  were  formaldehyde, 
production  of  3.  7  billion  pounds  in  1966  compared  with  3.  1  billion  pounds  in  1965;  acetaldehyde, 
1.  3  billion  pounds  compared  with  1.  2  billion  pounds;  and  av.etone,    1.  3  billion  pounds  compared 
with  1.  1   billion  pounds. 


)  uble  21B,  pt.  HI,  which  11m  these  pcoducu  and  identifies  the  aunufacturers. 


56  SYNTHETIC  ORGANIC  CHEMICALS,  1966 

TABLE  21A. — Miscellaneous  chemicals:  U.S.  production  and  sales,  1966 

■  Listed  below  are  all  miscellaneous  chemicals  for  which  any  reported  data  on  production  or  sales  may  be  published. 
(Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data 
were  reported.)   Table  21B  in  pt.    Ill  lists  alphabetically  all  miscellaneous  chemicals  for  which  data  on  production 
or  sales  were  reported  and  identifies  the  manufacturer  of  each  ] 


Production 


Grand  total 

MISCELLANEOUS  CHMICALS,    CYCLIC 

Total - — 

Benzoic  acid  salts:  Sodium  benzoate,  tech.  and  U.S.P 

Benzoyl  peroxide 

Butyl  benzoate 

Cyclopropane 

2j6-Di-tert-butyl-p-cresol: 

Food  grade 

Tech — 

p-Dlmethoxybenzene  (Dimethyl  ether  of  hydroquinone ) 

Flotation  reagents 

Gasoline  additives,  total^ 

N,N'-Di -sec-butyl -p-phenylenediamine 

N,N'-Disalioylidene-l,2-propanediamlne 

All  other- - — — 

Hexamethylenetetramlne ,  tech 

lubricating  oil  and  grease  additives,  total 

Oil-soluble  petroleum  sulfonate,  barium  salt 

Oil-soluble  petroleum  sulfonate,  calcium  salt 

Oil -soluble  petroleum  sulfonate,  sodium  salt 

All  other , 

Morpholine 

Naphthenio  acid  salts,  total^  * 

Calcium  naphthenate 

Cobalt  naphthenate 

Iron  naphthenate 

Lead  naphthenate 

Manganese  naphthenate 

Zinc  naphthenate 

All  other - — 

Photographic  chemicals : 

Benzotriazole 

2,5-Diethoxyi-4-morpholinobenzenediazonium  chlorozincate- 
p-Diethylaminobenzenediazonium  chloride  (p-Diazo-N, N- 
diethylaniline)  -  zinc  chloride 

N,N-Diethyltoluene-2,5-diamine,  monohydrochloride 

Pinene  (a-  and  (i-) 

Propyl  gallate 

Tall  oil  salts,  total^ 

Calcium  tallate 

Cobalt  tallate 

Lead  tallate 

Manganese  tallate 

All  other 

Tanning  materials,  synthetic,  total 

2-Naphthaleneeulfonlc  acid,  formaldehyde  condensate 

and  salts 

All  other 

See  footnotes  at  end  of  table. 


pounds 
57,252,6'i8 


9,'i93 

5,039 

635 

122 

7,310 

14,702 

918 

6,109 


1.000 
pounds 


2,731 

902 

14,954 


389,838 
41,i79 

132,256 
73,177 

142,926 

18,889 

23,317 

17^2" 

3,612 

296 

14,267 

1,652 

1,107 

491 


10,296 
2,792 
2,753 
3,608 
711 
432 
36,343 


61,643 
243,407 


50,084 
193,323 


20,127 
1,353 
3,069 
294 
12,621 
1,253 
1,040 
497 


10,202 
2,797 
2,728 
3,519 
682 
476 

35,702 


31,530 
4,172 


4,862 
8,429 


1,528 
1,455 
7,057 


10,006 
41,422 

8,209 

6,934 
593 

2,038 
100 

2,841 
460 
465 
437 


5,726 
1,957 


MISCELLANEOUS  CHEMICALS 
TABLE  21A.-- Miscellaneous  chemicals.-  U.S.  production  and  sales,  1966 --Continued 


57 


Chemical 

Production 

Sales 

(iiantlty 

Value 

Unit 
value  1 

MISCELLANEOUS  CHHMICALS,    CYCLIC- Continued 

Textile  chemicals,   other  than  surface -active  agents,    total 
l,3-Bi8(hyiJroxymethyl)-2-lJnidazolidone   ( Dljnethylol 

1.000 
pounds 
2,441 

1.000 
pounds 
1,783 

1.000 
dollars 

1,277 

Per 
pound 

$0.72 

92 
2,349 

655,644 
55,883,982 

135 
1,648 

244,976 
23,810,310 

50 
1,227 

141,894 
2,890,825 

.37 
.74 

.58 
.12 

All  other  miscellaneoufl  cyclic  chemicals - — 

MISCELLANEOUS  CHEMICALS,    ACYCLIC 
Total - 

Cellulose  Esters  and  Ethers 

1,026,063 

301,736 

122,596 

.41 

930,130 

211,213 

72,107 

.34 

All  other -  - 

179,826 
95,933 

211,213 
90,523 

72,107 
50,489 

.34 
.56 

48,736 
47,197 

456,986 

48,355 
42,168 

178,369 

20,758 
29,731 

37,582 

.43 
.70 

.21 

Lubricating  Oil  Additives 

100,819 

3,132 

23,073 

329,962 

8,869,388 

49,268 

129,101 

4,323,581 

12,265 
25,317 

420,026 

.25 

Sulfurized  lard  oil 

Nitrogenous  Compounds 

.20 

.10 

716,074 
784,337 

318,169 
197,237 

40,285 
58,130 

.13 
.29 

1,483 

6,356 
25,393 
11,078 
105,216 
634,811 
2,991 
... 

299 

'2,303 
207,794 

881 
1,862 
6,685 
17,636 
10,982 
62,712 
96,479 
2,419 
141,809 

316 

2,854 

1,792 

170,977 

408 
816 
2,526 
4,932 
2,029 
8,351 
39,068 
2,698 
34,997 

376 
1,199 
1,133 
28,477 

.46 
.44 
.38 
.28 
.18 
.13 
.40 
1.12 
.25 

1.19 
.42 
.62 

.17 

Di-n-butylamine 

Dl-n-propylamine 

2-Chloro-N, N-dlmethylethylamine  (Dimethylaminoethyl 

70,262 
79,246 
58,286 
401,128 
44,904 

57,581 
55,831 
57,565 

'29,296 

10' 538 
7,908 
10,031 

'ii,919 

.18 

.14 
.17 

.41 

2-MBthyllactonitrile  (Acetone  oyanohydrin )  — 

Nitriloacida  and  salts,    total 

(Ethylenedinltrilo)tetraacetic  acid,   disodium  salt 

(Ethylenedlnitrilo)tetraacetio  acid,   tetrasodium  salt— 

(Ethylenedinitrilo)tetraaoetic  acid,    trisodlum  salt 

(N-lfydroxyethylethylenedinltrllo)trlaoetic  acid. 

24,773 
473 

4,187 
14,892 
1,001,689 
3,042 
5,249 

685 

15,118 
505 

3,405 
9,583 

3,169 

437 

5,622 
219 

1,612 
4,029 

"2,420 

.64 
.37 
.43 

.47 

.76 

See  footnotes  at  end  of  table. 


58  SYNTHETIC  ORGANIC  CHEMICALS.  1966 

TABLE  21  A. --Miscellaneous  chemicals.-  U.S.  production  and  sales ,  ii'66--Continued 


Chemical 


Production 


Sales 


MISCELLANEOUS  CHE^aCALS,  ACYCLIC— Continued 
/Vi  trogenous   Compounds  -  -Continued 

Sarcosine  and  salt 

Stearamide 

Urea  in  compounds  or  mixtures  (100^  basis),  total 

In  feed  compounds 

In  liquid  fertilizer 

In  solid  fertilizer 

All  other 

All  other  nitrogenous  compounds 

Acids,    Acyl  Halides   and  Anhydrides 

Total— 

Acetic  acid,  synthetic,  1005i^ 

Acetic  anhydride,  100^ 

Acrylic  acid 

Adipic  acid - 

Butyric  acid 

Chloroacetic  acid,  mono-  

Decanoyl  chloride 

Formic  acid,  90^— - 

Fumaric  acid 

Gluconic  acid,  tech 

Lauroyl  chloride 

Maleic  anhydride 

Oxalic  acid— - • 

Balmltoyl  chloride 

Propionic  acid 

All  other  acids,  acyl  halides  and  anhydrides 

Salts   of  Organic  Acids 

Total - 

Acetic  acid  salts,  total 

Ammonium  acetate 

Cfepper  acetate 

Potassium  acetate 

Sodium  acetate 

Zinc  acetate 

Zirconium  acetate 

All  other — ■ 

2-Ethylhexanoio  acid  (a -Ethylcaproio  acid)  salts,  total- 
Calcium  2 -ethylhexanoate 

Cobalt  2 -ethylhexanoate 

l£ad  2 -ethylhexanoate 

Zino  2 -ethylhexanoate 

Zirconium  2 -ethylhexanoate 

All  other— 

Formic  acid,  aluminum  salt 

Gluconic  acid,  sodium  salt,  tech 

linoleic  acid  salts,  total 

Calcium  linoleate 

Cobalt  linoleate 

All  other 

Jferoaptoacetic   (Thioglycolic)   acid,   salts 

Oleic  acid  salts'— - 

Oxalic  acid  salts 

Palmitic  acid  aluminum  salt 

Polyacrylic  acid  salts 

Propionic  acid  salts,  total 

Calcium  propionate 

Sodium  propionate 


pounds 
1,751 
1,327 
3,432,703 


385,961 
1,331,692 
1,387,079 

327,971 
2,263,797 


,596,825 
62,477 
964,457 

66,094 

1,362 

27,208 

46,125 

3,828 

10,756 

168,575 

22,854 

281 

36,989 

687,066 


27,634 


3,351 
17,401 
286 
340 
5,321 
4,262 


701 
241 
413 
814 
2,093 
337 


2,806 
12,311 


12,311 


1 .  000 
pounds 

1,009 

3,263,426 


590 
135,731 


334,053 

1,244,652 

1,415,091 

219,630 

191,108 


11,080 

88,585 

979 


25,880 
37,084 
3,677 


25,391 


610 

186 

3,206 

15,716 

459 

319 

4,895 

3,235 


■33r 


3,955 

455 

5,310 

3,527 
13,991 


$,288 
4,703 


14,570 
51,131 
60,861 
9,169 

102,071 


3,180 
18,803 

200 


3,361 
6,313 
1,233 

15,106 
4,713 


5,612 


228 

135 

710 

2,449 

199 

114 

1,777 

2,474 


149 


6,423 

329 

1,566 


See  footnotes  at  end  of  table. 


MISCELLANEOUS  CHEMICALS 
TABLE  21A.-- Miscellaneous  chemicals.-  U.S.  production  and  sales ,  i 966 --Continued 


59 


KQSCELLANEOUS  CHMICALS,    ACYCLIC— Continued 

Salts   of  Organic  /tclds- -Continued 

Stearic  acid  salts,  total^° - 

Aluminum  stearates,  total 

Aluminum  dlstearate 

Aluminum  monostearate 

Aluminum  tristearate 

Calcium  stearate 

Lead  stearate 

Lithium  stearate 

Magnesium  stearate 

Zinc  stearate -- 

All  other - - - 

All  other  salts  of  organic  acids 

Aldehydes   and  Ketones 

Total- - — 

Acetaldehyde 

Acetone,  total 

From  isopropyl  alcohol 

All  other - 

2-Butanone  (Methyl  ethyl  ketone) 

Chloral  (Trlohloroacetaldehyde) 

Formaldehyde  (37^  by  weight) 

<t-Itydroxy-'i-methyl-2-pentanone  (Diacetone  alcohol) 

4.-Methyl-2-pentanone  (Methyl  isobutyl  ketone) 

All  other  aldehydes  and  ketones 

Alcohols,   Monohydnc,    Unsubstituted 
Total - - - - 

Alcohols,  C9  or  lower,  total 

Butyl  alcohols : 

n-Butyl  alcohol  (n-Propylcarbinol) 

Isobutyl  alcohol  ( Isopropylcarbinol ) 

Ethyl  alcohol,  synthetic^^ 

2-Ethyl-l-hexanol 

Iso-octyl  alcohols 

Isopropyl  alcohol 

Methanol,  synthetic 

All  other,  including  mixtures 

Alcohols,  Cio  or  higher,  total 

Isodecyl  alcohol 

l-Hexadecanol  (Cetyl  alcohol)- 

All  other,  including  mixtures 

Polyhydnc  Alcohols   and  Their  Esters  and  Ethers 

Total - -. 

Polyhydric  alcohols,  total 

Ethylene  glycol 

Pentaerythritol 

Propylene  glycol  (1,2-Propanedlol) 

Sorbitol  —  - - 

All  other 

Polyhydric  alcohol  esters 

Polyhydric  alcohol  ethers,  total 

2-Butoxyethanol  (Ethylene  glycol  monobutyl  ether) 

2-(2-Butoxyethoxy}ethanol  (Diethylene  glycol  monobutyl 

ether) 

Diethylene  glycol 

Dipropylene  glycol 

See  footnotes  at  end  of  table. 


1.000 
pounds 
«,871 


4,2^1 

941 

6A3 

18, 977 

422 

452 

2,458 

11,527 

4,210 

121,808 


1,300,450 
1,330,178 


L,020 

449,158 

399,077 

70,456 

3,712,568 


3,344,716 


396,934 

92,918 

1,881,275 

318,902 

99,994 

1,714,308 

3,268,923 

571,462 

468,571 


122,143 

1,673 

344,755 


2,890,675 


2,081,156 
80,836 
258,826 
65,801 
404,056 
134,187 
1,102,365 


69,333 


181,942 
36,601 


1.000 
40,303 


13,173 


5,606 

4,090 

891 

625 

19,295 

436 

494 

2,399 

10,455 

1,618 

82,660 


242,376 
841,222 


478,  ^U 
362,778 
351,783 

1,359,981 
30,818 
167,977 
226,636 


4,004,199 


234,469 
73,947 
1,175,924 
148,660 
98,721 
695,079 
1,373,497 
203,902 
260,645 


72,476 

1,408 

186.761 


1,886,163 


1,250,384 
65,603 
215,480 
52,097 
302,599 
140,767 
843,941 


6^,738 

12,142 
137,354 
34,146 


2,044 
1,474 
348 
222 
5,236 
182 
261 


3,794 

768 

22,184 


24,943 
15,254 


36,751 
3,877 
20,635 
31,525 


22,111 
5,577 
72,902 
17,027 
11,711 
41,565 
44,776 
26,434 
38,549 


8,798 

455 

29,296 


211,623 


101,888 
15,351 
21,120 
10,339 
62,925 
27,868 

137,356 


11,164 

3,200 
13,649 
3,849 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 
TABLE  21A.— Miscellaneous  chemicals;  U.S.  production  and  sales,  i 566 —Continued 


MISCELLANEOUS  CHBOCALS,    ACYCLIC— Continued 


Mcohols  and  Their  Esters   and  Others- -Continued 


Polyhydrio  alcohol  ethers — Continued 

2-Ethoxyethanol  (Ethylene  glycol  monoethyl  ether) 

2-C2-Ethoxyethoxy)ethanol  (Diethylene  glycol  monoethyl 

ether) • 

2-[2-(2-Ethoxyethoxy)ethoxy]ethanol  (Triethylene  glycol 

monoethyl  ether) 

Glycerol  tri (polyoxypropylene )  ether 

2-Methoxyethanol  (Ethylene  glycol  monomethyl  ether) 

2-(2-Methoxyethoxy)ethanol  (Diethylene  glycol  mono- 
methyl  ether) 

2 - [ 2 - ( 2 -Me thoxyethoxy ) ethoxy  ]ethanol ( Triethylene  glycol 

monomethyl  ether) 

l-Methoxy-2-propanol 

Polyethylene  glycol 

Polypropylene  glycol 

Triethylene  glycol 

All  other  ethers  of  polyhydric  alcohols 

Esters  of  Monohydrlc  Alcohols 

Total - - 

Butyl  acetates,  total 

n-Butyl  acetate 

All  other 

Dibutyl  maleate 

Dllauryl  3,3' -thiodlpropionate 

Ethyl  acetate,  85^ - 

Etl^l  acrylate 

Ethylene  carbonate 

Iso-octyl  mercaptoacetate 

Isopropyl  acetate 

Methyl  acetate 

Phosphorus  acid  esters,  not  elsewhere  specified 

Vinyl  acetate,  monomer ■ 

All  other  esters  of  monohydrlc  alcohols 

Halogenated  Hydrocarbons 

Total 

Carbon  tetrachloride 

Chlorinated  paraffins 

Chlorodifluoromethane 

Chloroethane  (Ethyl  chloride) 

Chloroform 

Chloromethane  (Methyl  chloride) 

Diohlorodifluorome thane 

1,2-Dichloroethaiie  (Ethylene  dichloride) 

Dichloromethane  (Methylene  chloride) 

1,2-Dichloropropane  (Propylene  dichloride) 

Diohlorotetrafluoroe thane 

Tetrachloroethylene  (Perchloroethylene) 

1,1,1-Trichloroethane  (Methylchloroform) 

Triohloroethylene 

Triohlorofluoromethane 

Vinyl  chloride,  monomer  (Chloroethylene) 

All  other  halogenated  hydrocarbons 

See  footnotes  at  end  of  table. 


1.000 
pounds 


173,896 
96,26A 

8,837 

5,245 
10,603 
41,362 

100,558 
59,065 

284,743 


129,543 


84,560 
44,983 
6,233 
1,537 
121,596 
129,995 

"2,369 
47,636 
8,785 
48,461 
605,544 
810,577 


11,564,094 


647,959 
60,051 

676,953 
178,953 
236,889 
286,326 
3,616,599 
267,213 
76,283 

462,678 
242,943 
480,219 
170,350 
2,499,549 
1,661,129 


pounds 
49,437 


3,773 
149,250 
77,260 


36,492 
86,522 
49,894 
118,957 


135,215 
S6,403 
48,812 


1,400 
114,909 

58,656 
1,064 
2,150 

41,964 

30,778 
254,239 
299,997 


615,360 
60,734 
56,472 
274,740 
143,558 
104,224 
266,894 
291,029 
225,833 

17,211 
424,797 
249,683 
462,853 
155,004 
836,172 
343,133 


1.000 
dollars 

7,842 

4,210 

538 
26,760 
12,814 


8,875 
14,147 

8,307 
22,001 


4,518 

1,368 
11,218 
12,159 
407 
1,493 
4,577 

12,790 
27,204 
71,744 


509,409 


42,201 
7,936 
35,640 
18,315 
10,815 
7,473 
75,275 
12,261 
22,494 

9,928 
34,491 
27,853 
39,095 
31,147 
49,552 
84,933 


MISCELLANEOUS  CHEMICALS 
TABLE  21A.  — Miscellaneous  chemicals.-  U.S.  production  and  sales ,  i 566- -Continued 


Chemical 


Production 


Sales 


KQSCELLAtlEOUS  CHIMICALS,    ACYCLIC— Continued 

All  Other  Miscellaneous  Acyclic  Chemcals 

Total— - 

2-Butanone  peroxide 

tert-Butyl  hydroperoxide 

tert-Butyl  peroxide  (Di-tert-butyl  peroxide) 

Carbon  disulfide 

2-Chloroethanol  (Ethylene  ohiorohydrin) 

Deoanoyl  peroxide 

Epoxides,  ethers,  and  acetals,  total 

Ethylene  oxide 

Ethyl  ether,  all  grades 

Isopropyl  ether 

Methyl  ether  (Dimethyl  ether) 

Propylene  oxide 

All  other  epoxides,  ethers,  and  acetals 

Ifluroyl  peroxide 

Phosgene  (Carbonyl  chloride) 

Sodium  formaldehydesulfoxylate 

Sodium  methoxide  (Sodium  methylate) 

Tetraethyllead - — 

Tetramethyllead 

Zinc  formaldehydesulfoxylate 

All  other- - 


1,000 
pounds 
5,480,678 


1.000 
pounds 
1,947,276 


585,070 


176 

1,367 

752,296 

28,446 


179 

1,367 

544,818 


2,782 

311 
1,943 
22,362 

1,259 


2,326,901 
107,222 

11,125 
710,471 
262,043 

1,891 
329,751 

5,224 

5,134 
543,406 
109,328 

1,248 
281,725 


1,791 

5,070 
3,741 

557,740 
95,648 
1,246 

246,712 


29,598 

6,032 

396 


1,137 

1,199 

299,276 

49,865 

577 

157,937 


1.52 

1.74 
1.42 


Calculated  from  rounded  figures. 
^  Statistics  exclude  production  and  sales  of  trlcresyl  phosphate.  Statistics  on  tricresyl  phosphate  are  given  in 
the  section  "Plasticizers." 

'  Quantities  are  given  on  the  basis  of  solid  naphthenate,  tallate,  or  linoleate  content. 

*  Statistics  exclude  production  and  sales  of  copper  napthenate.  Statistics  on  copper  naphthenate  are  given  in  the 
section  "Pesticides  and  Related  Products." 

'  Statistics  exclude  production  and  sales  of  fatty  amines.  Statistics  on  fatty  amines  are  given  in  the  section 
"Surface-Active  Agents." 

*  Production  of  urea  in  primary  solution  totaled  3,543,436  thousand  pounds. 
''   Includes  estimated  values  for  sales  of  urea  in  nitrogen  compounds. 

*  In  addition,  sales  of  recovered  acetic  acid  totaled  75,812  thousand  pounds,  valued  at  4,359  thousand  dollars. 
'  Statistics  exclude  production  and  sales  of  potassium  and  sodium  oleate.  Statistics  on  these  oleates  are 

Included  in  the  section  "Surface-Active  Agents." 

^°   Statistics  exclude  production  and  sales  of  potassium  and  sodium  stearates.  Statistics  on  these  stearates  are 
included  In  the  section  "Surface-Active  Agents." 

•'■■'  Statistics  on  production  of  ethyl  alcohol  from  natural  sources  by  fermentation  are  issued  by  the  Alcohol 
Tax  Unit,  U.S.  Internal  Revenue  Service. 


PART  m.     LIST  OF  INDIVIDUAL  PRODUCTS,   BY  GROUPS,  AND  NAMES  OF 
MANUFACTURERS 

Thi8  section  of  the  report  consists  of  (1)  a  series  of  tables  that  supplement  the  statistical 
information  given  in  parts  I  and  II,    and  (2)  a  Directory  of  Manufacturers.    The  tables  with  num- 
bers that  include  the  letter  "B"  supplement  the  tables  in  part  I  and  II  with  numbers  that  include 
the  letter  "A";  for  example,    table  8B  in  part  III  supplements  table  8A  in  part  II. 

Each  table  in  part  III  lists  the  individual  items  in  each  group  for  which  data  on  production 
or  sales  were  reported  for  1966.    The  tables  include  data  on  only  those  chemicals  for  which 
the  volume    of   production   or    sales    in    1966    exceeded    1,000   pounds    or   for   which  the   value    of 
sales  exceeded  $1,000.    Where  separate  statistics  for  an  item  are  given  in  the  tables  in  part  I  or 
part  II,    an  asterisk  (*)  precedes  the  name  of  the  item  in  the  tables  in  part  III.    The  manufacturers 
of  each  product  are  indicated  by  identification  codes  which  are  listed  in  the  Directory  of  Manu- 
facturers (table  22).   A  few  companies,    however,    have  specifically  requested  that  they  not  be 
identified  as  having  produced  or  sold  certain  items.    These  manufacturers  are  indicated  by  a 
small  letter  "x"  in  the  tables. 

Tar  Crudes 

TABLE  4B.  — Tar  crudes  for  which  U.S.  production  or  sales  were  reported,  identified  by  manufacturer,  1966 

[Tar  crudes  for  which  separate  statistics  are  given  in  table  i,k  are  marked  below  with  an  asterisk  (*);  products  not 
so  marked  do  not  appear  in  table  <iA  because  the  reported  data  are  accepted  in  confidence  and  may  not  be  published. 
Manufacturers'  identification  codes  shown  below  are  taken  from  table  22.  Table  22  identifies  all  U.S.  producers  of 
tar  crudes  (except  producers  that  report  to  the  Division  of  Bituminous  Coal,  U.S.  Bureau  of  Mines)] 


Manufacturers '  identification  codes 
(according  to  list  in  table  22)^ 


»Crude  light  oil 

Light-oil  distillates: 

»Benzene,  specification  and  industrial  grades 

»Toluene,  specification  and  other  grades 

^Xylene,  all  grades 

Solvent  naphtha 

»A11  other  light-oil  distillates -- 

Pyridine  crude  bases 

»Naphthalene ,  crude,  solidifying  at-- 

»Less  than  7<i°  C 

»'li,°   C.  to  less  than  76°  C 

»76°  C.  to  less  than  79°  C 

Crude  tar-acid  oils  having  a  tar-acid  content  of-- 

5«t  to  less  than  24^ 

2^1>   to  51* - 

Cresylic  acid,  crude 

»Creosote  oil  (Dead  oil): 

»Distillate  as  such— 

•Creosote  in  coal-tar  solution 

All  other  distillate  products 

»Tar,  road 

•Tar  for  other  uses: 

Crude 

Refined 

Pitch  of  tar: 

Soft  and  medium  (water  softening  points  less  than 
110°  F.,  and  110°  F.  to  160°  F.). 

»Hard  (water  softening  point  above  160°  F.) 

Pitch-of-tar  coke  and  pitch  emulsion 


CBT.'' 

ACY,  KPP. 

ACY,  KPP. 

ACY,  KPP. 

ACY,  NEV,  PAI. 

ACP,  PAI. 

ACP,  KPT. 

COP. 
KPT. 

ACP,  KPT,  PRD,  RIL. 

ACP,  COP,  KPT,  RIL. 

ACP,  RIL. 

ACP,  KPT,  PRD. 

ACP,  CBT,  COP,  HUS,  KPT,  RIL,  WTC. 

ACP,  JEN,  KPT,  RIL. 

ACP,  KPT,  PAI. 

ACP,  KPT,  RIL,  WTC. 

ACP,  KPT,  RIL. 

KPT,  RIL. 

ACP,  CBT,  COP,  KPT,  RIL. 

ACP,  COP,  HUS,  JEN,  KPT,  RIL. 

JEN,  RIL. 


Does  not  include  manufacturers'  identification  codes  for  producerE_ that  report  to  the  Division  of  Bituminous 
Coal,  U.S.  Bureau  of  Mines.  These  producers  are  listed  in  the  U.S.  Bureau  of  Mines  Mineral  Industry  Survey, 
August  29,  1967,  entitled  "Coke  Producers  in  the  U.S.  in  1966." 

'   Crude  light  oil  production  and  sales  of  this  company  are  not  included  with  the  U.S.  Bureau  of  Mines  figures 
given  in  table  Ak. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 
Crude  Products  From  Petroleum  and  Natural  Gas  for  Chemical  Conversion 


TABLE  5B.  --Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  U.S.  production 
or  sales  were  reported,  identified  by  manufacturer,  1966 

[crude  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  separate  statistics  are  given  in 
table  5A  are  marked  below  with  an  asterisk  (»);  products  not  so  marked  do  not  appear  in  table  5A  because  the 
reported  data  are  accepted  in  confidence  and  may  not  be  published.  Manufacturers'  identification  codes  shown  be- 
low are  taken  from  table  22.  An  x  signifies  that  the  manufacturer  did  not  consent  to  his  identification  with  the 
designated  product] 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


ARQMATICS  AND  NAPHTHENES 

•Benzene  (except  motor  grade): 

•Benzene,  1° 

•Benzene,  2° 

Cresylio  acid,  crude 

•Naphthalene,  all  grades 

•Naphthenic  acids: 

Acid  number  lower  than  150 

•Acid  number  150-199 

Acid  number  200-22'4 

Acid  number  225-2-^9 

•Sodium  carbolate  and  phenate,  crude 

•Toluene : 

•Nitration  grade,  1° 

•Pure  commercial  grade,  2° 

•Solvent  grade 

•All  other - 

•Xylenes,  mixed: 

Aviation  grade 

•3°  — 

5= — - 

All  other 

•All  other  aromatics,  naphthenes,  distillates  and 
solvents 

ALIPHATIC  HYDROCARBONS 

Ci  hydrocarbon:  Methane 

•C2  hydrocarbons: 

•Acetylene 

•Ethane 

•Ethylene 

C2  and  Cj   hydrocarbons,  mixed 

•C3  hydrocarbons; 

•Propane 

•Propylene 

•C4  hydrocarbons : 

•1,3-Butadiene,  grade  for  rubbers  (elastomers)-' 

•Butadiene  and  butylene  fractions 

•n-Butane — 

1-Butene 

2-Butene 

»1-Butene  and  2-butene  mixture 

•Isobutane 

•Isobutylene 

All  other — 

•C5   hydrocarbons: 

Isopentane   (2-Methylbutane ) 

•Ispprene  (2-Methyl-l,3-butadiene) 

n-Pentane 


ACU,  APR,  ASH,  ATR,  CCF,  COR,  CSD,  DLH,  DXS,  ENJ,  GOC, 
GRS,  MOC,  MON,  PLC,  RIG,  SHO,  SKO,  SM,  SNT,  SOG,  SUN, 
TOC,    TX,    UOC,   VEL,    VPT. 

ACC,    CO,   DOW,    SHO,    SOC. 

ATR,    PRD,    RIC,    SHO. 

ASH,    COL,   MON,    SUN,    TID. 

RIC,   SUN,  TX. 

PRD,    RIC,  SM,   SOC,    SUN. 

PRD,    RIC,  SM,    SOC. 

SOC. 

ATR,   GOC,  SIN. 


DOW,   MON,    RIC. 
CO,    FG,   SKO. 

ACC,    COR,    CSD,    CSO,   DXS,    ELP,    GRS,    PLC,    RIC,   SHO,   SM, 
SOC,    TOC,    TX,   VPT. 

CSD,    CSO,    SOG. 

ATR,    COR,   DLH,   MOC,   MON,    SNT,    UOC. 
ASH,    SIN,    SUN,    TX. 

CCP,    COR,    CSD,    CSO,    GRS,    LEN,    RIC,   SHO,    SM,    SOC,    SOG, 
SUN,    TOC. 

ACC,   DUP,    ELP,    ENJ,   FG,    GOC,    JCC,    LEN,   MOC,   MON,    QMC, 
PLC,   SHC,    SM,    SOC,    SOG,   SOI,    USI,    VPT. 


CCP,   MON. 

ACY,   DOW,   DUP,   MNO,   MON,    UCC,   x. 

ACU,    CCP,    CSO,    ENJ,   MON,    PAN,   SHC,    SHO,   SM,    SOI, 

UCC,    USI. 
BFG,    CBN,    CCP,    CSO,    DOW,   DUP,    EKX,    ELP,    ENJ,    GOC,    JCC, 

KPP,   MON,    QMC,    PLC,    RIC,    SHC,   SM,    SNO,    UCC,    USI. 
COR,    GYR,   MON,    PLC. 

AMO,   APR,    ASH,    CCP,    CSD,    CSO,   DXS,    ENJ,   GOC,   GRS,    QMC, 

PAN,    PLC,   SHM,   SHO,   SIN,    £M,   SNT,   SOG,    SOI,    SPI,    UCC, 

UOC,    USI. 
AMO,    ASH,   BFG,    CBN,    CCP,    CSO,   DO*,    EKX,    ELP,    ENJ,   GOC, 

JCC,   MOC,   MON,    PLC,    RIC,    SHC,   SHO,   SIN,    SIO,   SM,   SNT, 

SOG,    SOI,   SPI,   SUN,   UCC,    UOC. 

CBN,    CPY,   DOW,    ELP,    ENJ,    FRS,    GGC,    ILC,   MON,    PLC,    PTT, 

SHC,    SHO,    SM,    SOC,   SPI,    TID,    TUS,    UCC. 
DO*,   GOC,    GYR,   MOC,    PLC,    PTT,    SHC,    SJIO.    31.,,    ".,    SOC, 


SM,    SNT,    SOC,    SOG, 


SPI. 
COR,    CSD,   DXS,    GRS,    OMC,    PAN,    SHO, 

SOI,    UCC,    USI. 
GOC,    PLC,    PTT. 
MON,    PLC,    PTT. 

CSO,    ENJ,    GOC,    PLC,    PTT,    SHO,   SOC,  SPI,    TX,   UOC. 
CCP,    ELP,    ENJ,   GRS,    QMC,    PAN,    PLC,    SHO,    SM,    SDl, 

UCC,    USI. 
DXS,    ENJ,    PTT,    SIN,    UOC. 
APR,   BPG,    ENJ,    JCC,  MON,    PLC,   SM,    SOI,   UCC,   USI. 

PLC,   SM,   SOI,   UCC. 
ENJ,   GYR,   SHC. 
APR,   MON,   PLC. 


CRUDE  PRODUCTS  FROM  PETROLEUM  AND  NATURAL  GAS 


65 


-Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  U.S.  production 
or  sales  were  reported,  identified  by  manufacturer,  1966 — Continued 


Manufacturers '   identification  codes 
(according  to  list  in  table  22) 


ALIPHATIC  HYDROCARBONS--Continued 
K;,  hydrocarbons--Continued 

All  other — 

Cj  hydrocarbons: 

»Hexane 

Neohexane  (2,2-Dimethylbutane) 

All  other— — -- 

C7  hydrocarbons: 

n-Heptane 

»Heptenes,  mixed 

All  other - 

Cg  hydrocarbons: 

»Dlisobutylene  (Diisobutene) 

n-Octane 

2,2,'*-Trimethylpentane  (Iso-octane) 

All  other 

I^rocarbona,  C9  and  above: 

Eioosane 

»Nonene  ( Tripropylene J 

»Polybutene 

»Tetrapropylene 

Tridecene  concentrate 

Trilsobutylene 

All  other 

»A11  other  aliphatic  hydrocarbons  and  derivatives : 
Ifydrocarbons : 
»Alpha  olefins--Molecular  weight  ranges: 

C6-C7 

Cs-Cio 

Cll-Ci5 

All  other 

Ethane -ethylene 

Propane -propylene  mixture 

»%drocarbon  derivatives : 

1-Butanethlol 

tert-Butyl-mercaptan  (2-Methyl-2-propanethiol) 

Di-tert-butyl  disulfide - 

Ethyl  meroaptan  (Ethanethlol) 

Isopropyl  mercaptan 

Methyl  mercaptan  (Methanethiol) 

tert-Octyl  mercaptan 

n-Propyl  mercaptan  (l-Propane thiol) 

All  other 


ATR, 
EN  J, 
GRS, 


ENJ,  GYR,  MON,  PLC,  SHC,  USI. 

PLC,  SOG,  UOC. 

PLC. 


PTT,  IX. 

PLC. 

PLC. 


AMO,  ATR,  ENJ,  GOC,  RIC,  UOC. 

ACC,  CSD,  SOC,  SOI. 

CO,  DXS,  ENJ,  GOC,  MOC,  RIC,  SNT,  SOC,  SUN,  TX,  UOC. 

ENJ. 

ATR. 

CO,  ENJ,  GOC,  HOU,  KEN,  PLC,  SOC,  SUN,  TID,  x. 


GOC,  GYR,  PLC,  SOC. 

GOC,  SOC. 

ENJ,  GOC,  SOC. 

EKX,  GOC,  SOC. 
TX. 


GOC,  TX. 


PLC. 


PLC. 

PAS,  PLC.  SOC. 

PAS,  SOC. 

ACC,  PAS. 

PAS,  PLC. 

PAS,  PLC. 

EKX,  PAS,  PLC,  SOC,  UCC. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


Cyclic  Intermediates 


TABLE  7B.  --Cyclic  intermediates  for  which  U.S.  production  ( 
manufacturer,  1966 


sales  were  reported,  identified  by 


[Cyclic  intermediates  for  which  separate  statistics  are  given  in  table  7A  are  marked  below  with  an  asterisk  (»); 
cyclic   intennediates  not  so  marked  do  not  appear  in  table  7A  because  the  reported  data  are  accepted  in  confidence 
and  may  not  be  published.   Manufacturers'    identification  codes  shown  below  are  taken  from  table  22.   An  x  signifies 
that  the  manufacturer  did  not  consent  to  his   identification  with  the  designated  product] 


Aceanthryleno[2,l-a] aceanthrylene-5,13-dione 

3-Acetaraido-l-{'4-acetamido-2-hydroxy-5-nltrophenylazo)- 

2-naphthol. 

5-Acetamldo-2-aminobenzenesulfonic  acid 

3  -[  ( 2-Acetamido-4  -aminophenyl)  azo  ]  -1, 5  -naphthalenedisul- 

fonic   acid. 

.^-Acetara.do-J-chlcroanthraquinone 

a-Acetamido-p-toluenesulfonamide 

•Acetanilide,   tech 

p-Acetanisidide 

Acetic  acid,  phenyl  ester 

Acetoacetanilide 

o-Acetoacetanisidide 

o-Acetoacetotoluidide 

2  ',4'-Acetoacetoxylidlde 

1' -Acetonaphthone 

Acetone  phenylhydrazone 

p-Acetophenetldide 

•Acetophenone ,  tech 

p-Acetotoluidide 

N-Acetylanthranilic  acid 

p-AcetylbenzenesuUonamide 

p-Acetylbenzenesulfonic  acid,  sodium  salt 

p-Acetylbenzenesulfony lure thane 

l-(N-Acetyl)methylamino-^-bromoanthraquinone 

N-Acetylsulf anilic  acid,  sodium  salt 

N-Acetylsulf anilyl  chloride 

Adenine 

Adenine  bisulfate- — ■ 

»Alkylbenzenes: 

Dodecylbenzene  (including  tridecylbenzene) : 

Straight  chain - ■ 

Other - 

Other  alkylbenzenes :  Straight  chain 

Alkylphenols ,  mixed 

Alkylpiperazines ,  mixed 

Alkylpyridine 

[o-(Allylcarbamoyl)phenoxy] acetic  acid 

6-Allyl-o-cresol 

a-dl-5-Allyl-6-lmino-l-methyl-5-(l-methyl-2-pentynyl)- 

barbituric  acid. 
a-dl-5-Allyl-5-( l-methyl-2-pentynyl) -1-methylbarbituric 

acid. 

N-Allylsalicylamide 

Aminoaceanthryleno[2,l-a]  aceanthrylene-5,13-dlone 

3  '-Aminoacetanilide 

*A  '-Aminoacetanilide   ( Acetyl -p-phenylenediamine) 

3  '-Aminoacetophenone 

»5-Amlno-2-(p-aminoanilino)ben2enesulfonlc  acid 

l-Amino^-(3-aminow;-sulfoanilino)-9,10-dlhydro-9,10- 

dioxo-2-anthracenesulfonic  acid. 
l-Amino^-(A-amino-3-sulfoanilino)-9,10-dlhydro-9,10- 
dioxo-2-anthracenesulfonic  acid. 

5-Amino-2-anilinobenzenesulfonlc  acid 

2-(p-Aminoanilino)  -5-nitrobenzenesulfonlc  acid 

3-Amlno-p-anlsanilide 

5-Amino-2-o-anisidinobenzenesuli'onic  acid 

»l-Aminoanthraquinone  and  salt 

»2-Aminoanthraquinone  and  salt 

N-Cii-Amino-l-anthraquinonyl)  anthranlllc  acid 

N-(5-Amino-l-anthraquinonyl)anthranllic  acid 

N-(8-Amlno-l-anthraquinonyl)  anthranlllc  acid 

•6-Amino-3,4'-azodiben2enesulfonic  acid  (C.I.  Acid 
Yellow  9) . 
8-Amlnobenz[i]acridan-12-one 


SDW. 

CTN,  EKT,  MRK,  SAL,  SW. 

OAF. 

UCC. 

FMP,  UCC. 

FMP,  SDH,  UCC. 

FMP,  UCC. 

FMP. 

GIV. 

DUP. 

AAP. 

ACP,  SKO,  UCC. 

ACY. 

DUP. 

LIL. 

LIL. 

LIL. 

AAP. 

ALL. 

ACY,  CTN,  MRK,  SAL. 


ATR 

CO, 

MON, 

NAC,   PLC 

CO, 

soc. 

CO, 

soc. 

CJiF 

ORO. 

HOU. 

UCC. 

LIL. 

ICO. 

LIL. 

LIL. 

SDW. 

ICI. 

GAF, 

TRC. 

DUP. 

r^, 

NAC 

TRC. 

CTN, 

SDH. 

ere, 

GAF, 

TRC 

YAW. 

TRC. 

AAP,  ACY,  DUP,  GAF,  ICI,  MAY,  NAC,  TRC. 
ACY,  DUP,  GAF,  NAC,  TRC. 


AAP,  ACY,  CM},  DUP,  IHC. 


CYCLIC  INTERMEDIATES 


■Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  J566— Continued 


Manufacturers'   Identification  codes 
(according  to  Ust  in  table  22) 


p-Aminobenzamide 

»l-Amino-4-benzaiiiidoanthraquinone 

»l-Anilno-5-benzamldoanthraquinone 

'i'-[P-(p-A'iiinobenzaiiildo)benzainido]-^-hydroxy-2-naphthalene- 
sulfonic  acid. 

»7-(p-Amlnobenzaniido)  -4-hydroxy-2-naphthalenesulf  onic  acid  — 
7-(p-Aminobenzaiiiido)  -5-hydroxy-3-naphthalenesulfonic  acid  — 

3  '-Aminobenzanilide 

<i'-Aminobenzanilide 

»2-Amino-p-benzenedisulf onic  acid  [SO3H-I] 

o-Aminobenzene thiol 

2-Aminobenziinidazole 

5 -Ami  no-2-benzimidazolinone 

p-Amlnobenzoic  acid,   tech 

p-Amlnobenzoic   acid,  butyl  ester 

p-Aminobenzoic   acid,   2-(dimethylaiiilno)ethyl  ester 

4-Aminobenzophenone 

2-Amino-6-benzothiazoleoarboxylic  acid 

2-(m-Aminobenzoyl)-o-acetanisidide 

p-Amino-N-benzyl-N-ethylbenzenedlazonium  chlorostannate 

p-Amino-N-benzyl-N-ethylbenzenediazonium  chlorozincate 

2-Aiiiino-l-bromo-3-chloroanthraquinone 

»l-Amino-4-bromo-9,10-dihydro-9,10-dioxo-2-anthracene- 
sulfonlc  acid  and  sodium  salt. 

»l-Amino-2-broino-^-hydroxyanthraquinone 

l-Ajnlno-<i-bromo-2-methylanthraquinone 

»l-Amino-2-bromo-A-p-toluidinoanthraquinone 

»l-Aniino-5-ohloroanthraquinone 

l-Amino-S-chloroanthraquinone 

2 -Ami  no-1-chloroanthraquinone 

2-Amino-3-chloroanthraquinone 

4-Amlno-6-chloro-m-benzenedisulf onamide 

<l-Aiiiino-6-ohloro-m-benzenedisulfonamide  hydrochloride 

5-Amlno-2-chlorobenzoic   acid 

2 -Ami  no -5 -chlorobenzophenone 

2-Amlno-6-chlorobenzothlazole  hydrochloride 

»o-(3-Amino-A-chlorobenzoyl) benzoic  acid 

2-Amino-5-ohloro-p-cumenesulfonic  acid 

2-Amino-5-chloro-<i-ethylbenzenesulfonic  acid 

»3-Amino-5-chloro-2-hydroxybenzenesulf onic  acid 

2-Amino-^-chloro-6-nitrophenol 

2-Amino-^-chlorophenol 

2-Aiiiino-6-chloropyrazine 

3-Amino-6-chloropyTidazine 

2-Aiiiino-5-chloro-p-toluenesulfonic  acid  [S03H=1] 

»6-Amino-4-chloro-m-toluenesulfonic  acid  [S03H=1] 

2-Amino-p-cresol 

»l-Amino-2,A-dibromoanthraquinone 

5(and   8) -Aniino-6,8(and  5,7) -dibromo-9,10-dihyd^o-9,10- 
dioxo-l-anthracenesulf  onic   acid. 

2-Aiiiino-4,5-dichlorobenzenesulfonic  acid 

6-Amlno-2,'»-dlchloro-m-cresol 

';'-Aiiiino-2',5'-diethoxybenzaniHde 

l-Amino-9 , lO-dihydro-9 , lO-dioxo-2 -anthracenesulf onic   acid  — 
5(and  8)  -Ainino-9,10-dihydro-9,10-dioxo-l-anthracenesulfonlc 

acid. 
l-Aiiiino-9,10-dihydro-9,10-dioxo-2-anthroic  acid — 

*l-Ajiiino-9,10-dihydro-9,10-dioxo-4-p-toluenesulfonaiiildo-2- 
anthracenesulfonlo  acid,   sodium  salt. 
5-Amiuo-4,5'-dihydroxy-3,'4.'-[(2-methoxy-5-methyl- 

p-phenylene )bis ( azo ) ] -di-2, 7-naphthalenedisulf onic  acid, 
5 ' -benzenesulf onate . 

2-Amino-i-(a,a-dlme thy Ibenzyl) phenol 

2-Amlno-<i,6-dinltrophenol  and  salt 

3-Amino-4-ethoxyacetanilide 

3-Amlno-9-ethylcarbazole 

p-Amino-N-etl^rl-N-hydroxyethyl  benzenediazonlum 
chlorozincate. 

3-Amino-a-ethylhydrocinnamic  acid 

p-Amino-N-ethyl-N-1-naphthy  lbenzaLu.de 

2-Amino-N-ethyl-5-nitrobenzenesulfonanllide 

Aminoethylpiperazine 


SDH. 

ACY,  MAY,  NAC,  TRC. 
GAF,  ICI,  NAC,  TRC. 
CMG,   DUP. 

CM},   DUP,   GAF,    NAC. 

VPC. 

DUP. 

GAF. 

DUP,   GAF,   MAC. 

FMT,   GAM. 

EK. 

DUP. 

DUP,  Lat. 

GAF. 
SDW. 
DUP. 
DUP. 
GAF. 
ESA. 
ESA. 
ICI. 
AAP, 


GAF,    ICI,    NAC,    TRC. 


AAP,   DUP,   GAF,    ICC,    TRC. 

ICI. 

GAF,    ICI,    TRC. 

ACY,   DUP,    ICI,  MAY,    NAC,    TRC. 

DUP. 

DUP,   GAF. 

GAF,    ICI,    TRC. 

ABB. 

ABB. 

TRC. 

COK,    ICI. 

DUP. 

AAP,   GAF,    ICI. 


ACY,   SW. 

CXC,    NAC,    TRC. 

CMi. 

GAF,   MEE,    NAC. 

ACY. 

ACY. 

ACY,   HSC,   SW. 

ACY,    DUP,    HSC,    NAC,   SW. 

mC,   X. 

AAP,   DUP,   GAF,    ICC,    ICI,    NAC,    TRC. 

ICI. 


DUP. 

AAP,    DUP,   GAF. 


AAP. 
ICO,  SDC. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  IB.— Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 — Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


l-Amino-4-hydroxyanthraquinone 

2-Airdno-3-hydroxyanthraquinone 

l-Aniino-4-hydroxy-2-methoxyanthraquinone 

A  -Mlno-5  -hydroxy-2 ,  V-naphthalenedisulf onic  acid , 

benzenesulf onate . 
3 -Aiiiino-5 -hydroxy-2, 7-naphthalenedisulf onic  acid 

(2H  acid),   monosodium  salt. 
4-Amino-5-hydroxy-l,3-naphthalenedisulfonic  acid   (Chicago 

acid),  monoEOdlum  salt. 
•»4-Amlno-5-hydroxy-2,7-naphthalenedisulfonic  acid   (H  acid), 

monosodiujn  salt. 
».;-Amino-3-hydroxy-l-naphthalenesulfonic  acid   (1,2,4.  acid)  — 
•4-Amino-5-hydroxy-l-naphthalenesulfonic  acid   (S  acid), 

sodium  salt. 
»6-Amlno-4-hydroxy-2-naphthalenesulfonlc  acid   (Gamma  acid), 

sodium  salt. 
»7-Amino-4-hydroxy-2-naphthalenesulfonic  acid   (J  acid), 

sodium  salt. 

3'-Amino-2'-hydroxy-5'-nitroacetanilide . 

2-(2-Amino-5-hydroxy-7-sulfo-l-naphthylazo)-5-nltrobenzoic 

acid. 
l-(6-Amino-l-hydroxy-3-sulfo-2-naphthylazo) -6-nitro-2- 

naphthol-i-sulfonic   acid. 

5-Amirioisophthalic  acid 

4-Amino-3-({i  -methanesulf  anamidoethyl)  -N,N-diethylaniline 

hydrochloride. 
»N-(<4-Amino-3-methoxy-l-anthraquinonyl)-p-toluenesulfona- 

mide. 

5-Amino-6-methoxy-2-naphthalenesulfonlc  acid 

m-[('i-Amino-3-methoxyphenyl)azo]  benzenesulf  onic  acid 

8-Amlno-6-methoxyquinoline 

4-[(<i-Amino-5-methoxy-o-tolyl)  azo]  -<i-hydroxy-2,7-, 

naphthalenedisulfonic  acid,  benzenesulf onate . 
3-[('l-Amino-5-methoxy-o-tolyl)azo]-l,5-naphthalene- 

disulfonic  acid. 
7-[('4-Amino-5-metho](y-o-tolyl)azo]  -1,3 -naphthalene- 
disulfonic acid. 

»4'-Amino-N-methylacetanilide 

l-Amino-2-methylanthraquinone 

<i-Amino-<i'-(3-methyl-5-oxo-2-pyrazolin-l-yl)-2,2'- 

stilbenedisulfonic  acid. 

8-Amino-7-methyl-l-phenazinol  (Tolazine  base) 

2-Amino-3-methylpyTidine 

2-Amino-5-methylpyridlne 

2-Amino-6-methylpyridine 

2-Amino-4-methylpyriiiiidine   (2-Amino-4-methyl-l,3-diazine)  — 

2-Amino-i-(methylsulfonyl)  phenol 

2-Amiuo-5-methyl-l,3,A-thiadiazole 

l-Amino-2-methyl-4-p-toluidinoanthraquinone 

l-Aminonaphth[2,3-c]  acrldan-5,8,l<i-trione 

A-Aminonaphth[2,3-c]  acridan-5,8,l<i-trione 

6-Amlnonaphth[2,3-c]  acridan-5,8,l<i-trione 

»2-Amino-l,5-naphthalenedlsulfonic  acid 

3-Amino-l,5-naphthalenedisulfonlc  acid   (C  acid) 

3-Amino-2, 7-naphthalenedisulf onic   acid 

4-Amino-l, 5 -naphthalenedisulfonic  acid 

'i-Amino-l,6-naphthalenedisulfonlc   acid 

«6-Amino-l,3-naphthalenedisulfoiiic   acid   (Amino  I  acid) 

»7-Amino-l,3-naphthalenedisulfonic  acid   (Amino  G  acid) 

6-Amlno-l-naphthalene sulfonamide 

l-Amino-2-naphthalenesulfonic  acid  (o-Naphthionic  acid) 

2-Amino-l-naphthalenesulfonic  acid   (Tobias  acid) 

•"i-Amino-1-naphthalenesulfonic  acid   (Naphthionic  acid) 

4-Amino-l-naphthalenesulfonic  acid,   sodium  salt 

'i(and  5) -Anino-1-naphthalenesulf onic  acid 

5-Amino-l-naphthalenesulfonic  acid   (Laurent's  acid) 

•5-Aiiilno-2-naphthalenesulfonic  acid   (l,6-Cleve's  acid) 

»5(and  8) -Amino-2-naphthalenesulf onic  acid   (Cleve's  acid, 

mixed) . 

•6-Amino-2-naphthaleuesulfonic   acid   (Broenner's  acid) 

6(aiid  7) -Amino-l-naphthalenesulfonic  acid 


GAF. 
GAF, 
TRC. 
TRC. 

NAC. 

DUP, 

NAG. 

DUP, 

NAC. 

DUP, 

MDN, 

NAC. 

ACY, 
MAC. 

GAF, 

NAC, 

TRC, 

VPC 

DUP,   GAF,    NAC,    TRC. 

BKS,    CMG,    DUP,    NAC,    TRC. 

TRC. 
TRC. 

TRC. 


GAF. 

EKT. 

AAP, 

DUP, 

GAF 

NAC, 
DUP, 
SDW. 
TRC. 

TRC. 
TRC. 

cm, 

GAF, 

NAC. 

DUP, 

ICI. 

TRC. 

NAC. 

RIL. 

RIL. 

RIL. 

ACY. 

NAC, 

TRC. 

ACY. 

ICI. 

DUP. 

DUP. 

GAF. 

ACY, 

SDH, 

SW. 

GAF, 

TRC. 

NAC, 

TRC. 

NAC. 

DUP. 

ACY, 

DUP, 

NAC, 

TRC. 

ACY, 

DUP, 

GAF, 

MAC,   TRC 

VPC. 

DUP. 

ACY, 

HSC, 

SW. 

ACY, 

DUP, 

NAC. 

DUP, 
ACY, 
DUP, 

NAC. 
TRC. 
NAC. 

AIJ., 

DUP, 

GAF, 

NAC,    TRC 

ALL, 

DUP, 

MAC, 

TRC. 

NAC, 

SNA, 

TRC. 

DUP, 

VPC. 

CYCLIC  INTERMEDIATES 


69 


TABLE  7B. — Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 — Continued 


Manufacturers'    identification  code 
(according  to  list  in  table  22) 


»8-Amlno-l-naphthalenesulfonic  acid   (Peri  acid) 

»8-Ainino-2-naphthalenesulfonic  acid   (l,7-Cleve's  acid) 

7-Andno-l,3,6-naphthalenetrisulfonic  acid 

8-Aiiiino-l,3,6-naphthalenetrisulfonlc  acid   (Koch's   acid) 

3 -Aniino-2 -naphthoic   acid 

5(and  8)-Amino-2-naphthol 

«8-Amino-2-naphthol 

•2-Aiuino-5-nitrobenzenesulfonic   acid    [SOsH^l] 

2-Aniino-4-nitrophenol 

2-Amino-5-nltrophenol 

<l-Amino-2-nltrophenol 

2-Amino-(p-nitrophenylazo) naphthalene 

2-Amino-l-(p-nitrophenyl) -1,3 -propanediol 

»A-Amino-^'-nitro-2,2'-Etiltienedisulfonic  acid 

2-Amino-5-nitrothiazole 

»3' -Aminooxanllic   acid 

A'-Aminooxanilic  acid 

3-Amino-2-oxazolidinone 

5-Aiiiino-2-[(2-oxo-5-benzimidazolinyl)  amino]  benzenesuLf  onic 
acid. 

p-Aminophenethyl  alcohol 

5-Amino-2-o-phenetidinobenzenesulfonic  acid 

o-Amlnophenol 

p-Aminophenol 

iii-[(p-Aminophenyl)azo]benzenesulfonic   acid 

»p- [(p-Aminophenyl)azo]benzenesulfonlc   acid 

7-[(<i-Amlnophenyl)azo]-l,3-naphthalenedlsulfonic   acid 

5-Amino-8-(phenylazo) -2-naphthol 

8-Ainino-5-(phenylazo)  -2-naphthol 

5-[(p-Amlnophenyl)azo]  salicylic  acid 

2,2'-(m-Amlnophenyllniino)diethanol,   diacetate  ester 

2-(p-Aminophenyl)-6-methylbenzothiazole 

2-(p-Aminophenyl) -6-methyl-7-benzothlazolesulf onic  acid 
and  salt. 

l-(m-Aiiilnophenyl)  -5-oxo-2-pyrazollne-3-carboxyllo  acid 

2-AminopyTidine 

3-AminopyTidine 

4-Aminopyridine 

2-Aminopyrimidine 

5 -Aminosalicylic   acid 

N-(^-Amino-3-sulfo-l-anthraquinonyl)anthranillc  acid 

3'-(3-Aniinow;-sulfophenylsulfaiiioyl)  -3  '  '-sulf  amoyl- 
3-phthalocyanlneBulfonlc   acid,   copper  derivative. 

2-Aminothlazole 

3-itoino-p-toluaiiiide 

a-Amlno-p-toluenesulfonamlde 

5-Amino-o-toluenesulfonanilide 

«>i-Amino-iii-toluenesulfonic   acid   [E03H=l] 

«6-Amlno-m-toluenesulfonic  acid   [S03H=1] 

5-Amino-2-p-toluidinobenzenesulfonic  acid 

m-(i-Ainino-m-tolylazo)benzenesulfonic  acid 

3-[(4-Amino-o-tolyl)azo]  -IjS-naphthalenedisulfonic  acid 

7-[('i-Amino-o-tolyl)azo]  -1,3 -naphthalenedisulf onic  acid 

•16-Aminoviolanthrone 

5-Amino-2,A-xylenesulfonic  acid 

»AnlUne  (AniUne  oil) — 

Aniline  hydrochloride 

l-Anillno-9,10-dihydro-9,10-dioxo-2-anthroio  acid 

1-Anlllno-A-hydroxyanthraquinone 

6-AniUno-4.-hydroxy-2-naphthalenesulfonlc  acid   (Phenyl 
gamma  acid) . 

<<7-Anllino-4-hydroxy-2-naphthalenesulfonic  acid   (Phenyl 
J  acid). 

»Anlllnomethanesulfonlo  acid  and  salt 

»8-Anilino-l-naphthalenesulfonic  acid   (Phenyl  peri  acid) 

o-Anisic   acid 

p-Anisic  acid 

m-Anisidine 

"o-Anlsldlne 

p-Anisidine 

l-p-Anisidino-4-hydroxyanthraqulnone 

*o-Anisidinoiiiethanesulfonlc  acid 


DUP,  NAC, 

SDC 

TRC. 

ALL,  DUP, 

NAC 

TRC 

DUP. 

DUP,  NAC 

RSA. 

GAF. 

CMG,  GAF, 

TRC 

VPC. 

DUP,  GAF, 

NAC 

TRC. 

DUP,  GAF, 

NAC 

TRC. 

NAC. 

ACY. 

AAP. 

PD. 

GAF,  ICI, 

NAC, 

TRC. 

ACY. 

CMG,  DUP, 

TRC. 

DUP. 

NOR. 

DUP, 

EKT. 

NAC. 

SDC. 

ABB,  DUP, 

SDC. 

AAP,  DUP, 

TRC. 

ACY,  CMG, 

DUP, 

CzAF, 

NAC,  TRC 

TRC. 

ALL. 

ALL. 

TRC,  VPC. 

DUP. 

DUP,  NAC. 

DUP,  TRC. 

TRC,  VPC. 

NEP,  RIL. 

RIL. 

NEP. 

ACY. 

AAP,  TRC. 

GAF. 

DUP. 

ACY,  MRK. 

SDH. 

SDW. 

GAF. 

ACY,  DUP, 

GAF. 

DUP,  HSC, 

NAC, 

SNA, 

SW. 

DUP,  NAC, 

TRC. 

TRC. 

TRC. 

TRC. 

ACY,  GAF, 

TRC. 

DUP. 

ACY,  DOW, 

DUP, 

MDB, 

NAC,  RUC 

ACY. 

NAC. 

AAP. 

DUP,  NAC. 

ALT,  CM), 

DUP, 

NAC, 

IRC. 

AAP,  ACY, 

DUP, 

NAC, 

TRC,  VPC. 

CMG,  DUP, 

NAC, 

SDC. 

HN. 

ICO. 

EK. 

AAP,  DUP, 

M3N. 

DUP,  MON. 

AAP. 

AAP,  DUP, 

GAF, 

NAC, 

TRC,  VPC. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


■Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


2-o-Anisldlno-5-nitrobenzenesuironic  acid 

p-Anisoin 

Anisole,  tech 

p-Anisoyl  chloride 

Anthracene,  refined 

Anthranllic  acid  (o-Aminobenzoic  acid)-"- 

»Anthra[l,9-cd]pyrazol-6(2H)-one  ( IVrazoleanthrone ) 

Anthraquinone,  100^ 

l,l'-[l,5(and  l,8)-Anthraquinonylenediamino]bisnaphth 
[2,3-o]acridan-5,8,l'i-trione. 

N,N'-(l,5-Anthraquinonylene)dianthranilic  acid 

N,N'-(l,5-Anthraquinonylene)dioxamic  acid 

(l-Anthraquinonyl) -1,2-hydrazlnedisulfonic  acid,  disodium 
salt. 

Anthrone 

Arsanllic  acid  and  salt,   tech 

Aryldiamines,   mixed 

A',^"  '-Azobis['i-biphenylcarboxylic  acid] 

A-', A"  '-Azobis[ N-( l-chloro-2-anthraquinonyl)  -4- 
biphenylcarboxamide] . 

Barbituric  acid 

Barbituric  acid,   sodium  derivative 

»Benzaldehyde,   tech 

i.[(<i-Benzajiiido-l-anthraquinonyl)amlno]naphth[2,3-c] 
acridan-5 , 8 , lA -trione . 

N-(5-Benzaiiiido-l-anthraqulnonyl)-p-toluenesulfonamide 

1-Benzamido-i-bromoanthraquinone 

l-Benzajnido-^-chloroanthraquinone 

»l-Benzamido-5-chloro anthraquinone 

l_(A.Benza]nido-2,5-diethoxyphenyl)  -3-[methyl-3- 
(2-sulfoethyl)triazene] . 

4-Benzanddo-5 -hydroxy -2, 7-naphthalenedisulfonic   acid 

7-Benzainldo-4-hydroxy-2-naphthalenesulfonic   acid 

N-(4-Benzamido-6-methoxy-m-tolyl) -N-(methylazo) glycine--- 
Benzanilide 

<<7H-Benz  [de]  anthracen-7-one   (Benzanthrone) 

Benzeneboronlc  acid 

m-Benzenedisulf onlc  acid 

m-Benzenedisulfonyl  chloride 

Benzenesulfonamide 

Benzenesulfonlc  acid 

Benzenesulfonic   acid,   2-propyn-l-ol  ester 

Benzenesulfonyl  chloride 

l,2,'i,5-Benzenetetracarboxylic   acid 

l,2,'»,5-Benzenetetracarboxylic-l,2:'i,5-dianhydride 

1,3,5 -Benzenetricarboxy lie  acid 

1,2,'i-Benzenetricarboxylic  acid,  1,2-anhydride 

1,2,'i-Benzenetricarboxylic  acid,  l,2-anhydride-'i-acid 

chloride. 
Benzhydrol  ( Dipheny Imethanol) 

♦Benzidine  hydrochloride  and  sulfate 

Benzil  (Blbenzoyl) 

Benzilic  acid 

2-Benzofuranacetonitrlle 

♦Benzoic  acid,  tech-"- 

Benzoin 

Benzonitrile 

Benzophenonetetraoarboxylic  dianhydride 

»2-Benzothiazolethiol  (2-Meroaptobenzothlazole) ,   sodium 
salt. 

Benzo[b]thlophen-3(2H)-one 

IH-Benzotriazole 

2H-3,l-Benzoxazine-2,'i(lH)-dlone 

Benzoylacetic  acid,  ethyl  ester 

»o-Benzoylbenzoic  acid 

Benzoyl  chloride 

2-Benzoyl-<i-sulfobenzoic  acid 

2-Benzoyl--i'-(p-toluenesulfonamido)aoetanilide 

N-Benzylacetamide 

Benzylandne 

See  footnotes  at  end  of  table. 


TRC. 

CTN. 

DUP,    LIL. 

ICO. 

ACP. 

DUP,    mj,   MEE, 

NAC. 

DUP,   GAF,    TRC. 

ACY,   DUP,   GAF, 

TRC. 

DUP. 

DUP,    ICI. 

GAF,   MEE. 

DUP,   GAF. 

ICI. 

ABB,   FLM. 

DA. 

DUP,    GAF. 

GAF. 

ABB,    KF,    LIL. 

ABB,    KF. 

BPC,    HN,    VEL. 

DUP. 

ICI,    NAC. 

AAP. 

GAF. 

ACY,   DUP,   GAF, 

ICI,  MAY,    NAC,   TRC. 

GAF. 

TRC. 

TRC. 

GAF. 

DUP,  PCW. 

AAP,  ACY,  ATL,  CMC,   DUP,  ICI,  MAY,  NAC,  SDC,  TRC. 

EDC. 


DUP,   X. 

DUP,   X. 

ACC. 

ICO. 

TBK. 

CVra,    LAK, 

NAC,   X. 

LEW. 

BPC,    LEM. 

EK. 

HK,   HN,   MON,   VEL. 

BPC,    LEM. 

VEL. 

GOC. 

ACY,   GYR, 

MDN,    USR 

GAF. 

MEE. 

MEE. 

FMP. 

ACY,   DUP, 

GAF. 

HK,   VEL. 

DUP. 

EK. 

SDW. 

ICO,  ms. 

CYCLIC  INTERMEDIATES 


-Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  iP66- -Continued 


Manufacturers '   identification  codes 
(according  to  list  in  table  22) 


4-(Benzylainino)  -6-chloro-m-benzenedlsulfonic  acid 

2-(Benzylaiiilno)ethanol 

A-Ben2yl-6-chloro-3-keto-2-methyl-7-sulfainyl-l,2,'i- 

benzylthladlazine-1, 1-dloxide . 
'i-Benzyl-6-chloro-3-keto-7-sulfainyl-l,2,'i- 

benzylthiadlazine-1, 1-dloxide. 
l-Benzyl-4,5-dimethyl-6-(p-methoxybenzyl)-l,2,3,6- 

tetrahydropyridine  oxalate. 

Benzyl  disulfide 

Benzyl  ether  (Dlbenzyl  ether) 

5-(Benzylethylaiiilno)  -o-toluenesulf  onic  acid 

N-Benzyl-N-ethyl-m-toluldine 

"ijA'-Benzylidenedi-o-toluidine 

Benzyl  p-nltrophenyl  ether 

p-(Benzyloxy) phenol 

1-Benzyl-A-phenyllsonlpecotio  acid,  benzyl  ester 

l-Benzyl-4-phenylisonlpecotonltrlle 

4-Benzylplperidine 

Benzyl  polysulfide 

Benzyl  sulfide 

Benzyltrimethylaiimonium  chloride 

Benzyltrlmethylammoniuui  hydroxide 

Benzyltrimethylainmoniuni  methoxide 

«[3,3'-Bianthra[l,9-cd]pyrazole]-6,6'(2H,2'H)dione 

(Pyrazoleanthrone  yellow) . 

[3,3^-Bi-7H-benz[de]anthracene] -7,7  '-dione 

»[4,4'-Bl-7H-benz[de]anthracene] -7,7  '-dione 

»[l,l'-Binaphthalene]-8,8'-dicarboxylic  acid 

Biphenyl 

3,3  ' ,^A'  -Biphenyltetramine 

2,2  '^,U,U'  -Biphenyltetrol 

2,2  '-Blqulnollne 

♦Ij'V-Bisfl-anthraquinonylaminoJanthraquinone 

Ij'i-Bls  [l-anthraquinonylamlno]  anthraqulnone  and   1,A-Bis 

[5-chloro-l-anthraq.ulnonylamlno]  anthraquinone  (mixed) . 

1,5-Bis [l-anthraqulnonylamlno] anthraquinone 

Bis  [l-anthraqulnonylamlno Jviolanthrene 

l,<i -Bis  [  ( 5 -benzamido-l-anthraqulnonyl)  amino  ] - 

anthraquinone . 

Bis(chlorosulfonyl)phthalocyaninedisulfonic  acid,   copper 

derivative. 

4.,i'-Bis  [diethylamlno]  benzhydrol 

'i,'4'-Bis[dlethylamino]benzhydrol,   2,6-naphthalene- 

dlsulfonate. 
'>,'i'-Bis  [diethylamino]benzhydrol  salt,   2, 7 -naphthalene - 

disulfonio  acid  mixture. 

i,A'-Bis[dlethylamlno]benzophenone  (Ethyl  ketone  base) 

A-Bls [(p-dlethylamlnophenyl)methyl] -2, 7 -naphthalene - 

dlsulfonic  acid,   leuco  form. 

^,'i' -Bis [dimethylamlno] benzhydrol   (Michler's  hydrol) 

*»i,>4'-Bis[dlmethylamlnojbenzophenone   (Michler's  ketone) 

BiE[p-(dtiiiethylamlno)phenyl]methajiesulfonic   acid  and  salt— 

l,5-Bls[2,4-dlnitrophenoxy]  •^,8-dlnltroanthraqulnone 

l,5(and  1,8) -Bls[2,';-dlnitrophenoxy]wi,3(and  ^,5)- 

dlnltroanthraqulnone . 

Bls(2,3-epoxycyclopentyl) ether  (Epoxide  205) 

3'-[Bis(2-hydroxyethyl)amlno]aoetanllide 

3^-[BiB(2-hydroxyethyl)amino]benzanillde,  dlacetate  ester— 
3 '-[ Bls( 2-l^droxyethyl) amino jmethanesulfouanlllde, 

dlacetate  ester. 
';,<i'-Bls[(p-hydroxyphenyl)azo] -2,2 '-etilbenedisulf  onic 

acid  (C.I.  Direct  Yellow -i) . 

4.,A-Bis[p-hydroxyphenyl] valeric  acid 

iy;-Bis(p-methoxyphenyl)-3-hexanone 

Bls(2-methyl-l-azirldlnyl)phenylphoEphlne  oxide 

2,A-BiB(l-methylbutyl)phenol 

l,'i-Bls[2-(4-methyl-5-phenyloxazolyl)]  benzene  (Mmethyl- 

POPOP). 

Bis(p-nltrophenyl) disulfide 

Bls(o-nltrophenyl) sulfide 


CCW,   FIN. 

BPC. 

NAC. 

DUP,    NAC. 

ACY. 

GAF. 

EK. 

SDW. 

SDW. 

RIL. 

HK. 

BPC. 

MI£. 

MIS. 

MI£. 

DUP,   GAF, 

TRC. 

DUP,   NAC. 

ACY,   DUP, 

GAF, 

ICI 

MAY. 

DUP,   GAF, 

NAC. 

DOW,  MON. 

AAP. 

FMI,    IDC. 

EK. 

ACY,   DUP, 

GAF, 

ICI, 

MAY,    TRC 

TRC. 

DUP,    NAC. 

GAF. 

ICI. 

ACY. 

TRC. 

GAF. 

OAF. 

TRC. 

DSC,   SDH. 

TRC. 

SDH. 

DSC,   DUP, 

NAC, 

SDH. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  IB.— Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  966— Continued 


anuf acturere '   identification  codes 
(according  to  list  in  table  22) 


l,<i-Bis[2-(5-phenyloxazolyl)  ]benzene  (POPOP) 

2-Bromoacetophenone 

o-Bromo aniline 

p-Bromoaniline 

p-Bromoanisole 

»3 -Bromo-7H-benz [ de ] anthracen-7-one  ( 3 -Bromobenzanthrone ) 

Bromobenzene ,  mono-  

p-Bromobenzenesulfonyl  chloride 

o-Bromobenzolc  acid 

Bromochlorobenzene 

6-Bromo-5-chlorobenzoxazolone 

2-Bronio-6-chloro-4-nitroaiiiline 

2-Bromo-4,6-dinltroaniline 

Bromoethylbenzene 

3-(Bromoethyl) thiophene 

2-Bromo-3'-hydroxyacetophenone  benzoate 

l-Bromo-<i-(N-methylacetamido)anthraquinone 

»l-Bromo-4-(inethylaiiiino)anthraquinone 

6-Bromo-3-methyl-7H-dibenz  [f  ,i  j  ]iso<iuinollne-2,7- 
(3H)dione. 

1-Bromonaphthalene 

2-Broiiio-4'-nltroacetophenone 

1-  [(51-Bromo-7-oxo-7H-benz[de]  anthracen-3-yl)  amino]  - 
anthraquinone . 

N-(4-Broinopentyl)phthallmlde 

o-Bromophenol 

p-Bromophenol 

(p-Bromophenyl)acetonitrile 

p-Bromophenylhydrazine  hydrochloride 

2-Bromopyridine 

3-BromopyTidlne 

o-Bromotoluene 

p-Bromotoluene 

a -Bromotoluene 

<;'-Butoxy-3-piperidinoproplophenone 

N-Butylacetanlllde 

p-Butylanlline 

2-tert-Butylanthraquinone 

p-tert-Butylbenzaldehyde 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

p-tert-Butylbenzoio  acid 

o-(p-tert-Butylbenzoyl)benzoic  acid 

6-tert-Butyl-m-cresol 

2-tert-Butyl-p-cresol 

2'-tert-Butyl-4',6'-dimethylacetophenoiie 

4-Butyl-a-(dii!iethylaiiiino)-o-creBOl 

2-tert-Butyl-4-ethylphenol 

N-'-'Butyl-^.-methoxymetanllamlde 

2-tert-Butyl-5-inethylanl80le 

o-seo-Butylphenol 

p-sec-Butylphenol 

o-tert-Butylphenol 

p-tert-Butylphenol 

Butylphenols ,  mixed 

p-tert-Butyltoluene 

5-tert-Butyl-l,2,3-trimethylbenzene 

5-tert-Butyl-m-xylene 

6-tert-Butyl-2,'i-xylenol 

Camphoric  acid 

Camphoric  anhydride 

d-lO-Camphorsulfonic  acid 

Camphosulfonlc  acid 

Carbazole,  refined 

NjN^-Carbonylbisf'i-methojcymetanlUc  acid] — - 

N,N'-CarbonylbiB[4-methO]cy-6-uitroii>etanlllc  acid] 

5 '-(o-Carboxybenzoyl) -2 '-chlorooxanillc  acid 

H-[(3-Carboxy-4-chlorophenyl)  -eulfonyl]anthranillc  acid- 
3-Carboxy-2(and  'i)-hydroxybenzenediazonium  sulfate 


EK. 

DOW. 

MEE. 

AAP. 

AAP,    TRC. 

DOW. 

SDW. 

SDH. 

GAF. 

AAP,   DUP,   GAF, 

AAP,   GAF. 

EK,   RSA. 


RSA. 
BPC. 
EK. 
ICO. 
UCC. 
DUP. 
DUP. 

Grv. 

PLC. 

PLC. 

PLC. 

SHC. 

DUP. 

KPT,   PHD. 

ACY. 

GIV. 

RH. 

ACY. 

PCW. 

GIV. 

DOW,    TNA. 

DOW. 

TMA. 

DOW,    PRD,   UCC. 

DOW. 

GIV,   SHC. 

GIV. 

GIV. 

KPT,   PRD. 

FIN,   OTC. 

FIN. 

OTC. 

PYL. 

SDC. 

OAF. 

GAF. 

GAF. 

TRC. 

GAF,   NAC. 


CYCLIC  INTERMEDIATES 


73 


TABLE  IB. --Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 — Continued 


Manufacturers '   Identification  codes 
(according  to  list  in  table  22) 


o-[(Carboxyinethyl)thio]  benzoic  acid 

[(o-Carboxyphenjrl)thio]  ethylmercury 

Cedrene 

2'-Chloroacetoacetanillde 

2'-Chloroacetophenone 

3'-Chloroacetophenone 

A'-Chloroacetophenone 

4/-(Chloroacetyl) acetanilide 

m-Chloroani  line ■ 

o-Chloro aniline 

p-Chloro  aniline 

2-(o-Chloroanllino)ethanol 

3-(o-Chloroanllino)propionltrile 

5-Chloro-o-anisidine  [NH2=1]  (<i-Chloro-o-anieidine 
[0CH3=1]). 

5-Chloro-o-anisldine  hydrochloride 

<i-Chloroanthranllic  acid 

•1-Chloroanthraquinone 

»2-Chloroanthraquinone 

N-(5-Chloro-l-anthraquinonyl)-p-toluenesulfonamlde 

o-Chlorobenzaldehyde 

p-Chlorobenzaldehyde 

A-(p-Chlorobenzamldo)anthraquinone-l,2-acridone 

Chloro-7H-benz[de]anthracen-7-one  (Chlorobenzanthrone) 

»Chlorobenzene ,  mono-  

p-Chlorobenzenesulf inlc  acid 

p-Chlorobenzenesulfonamide 

p-Chlorobenzenesulfonlc  acid 

p-Chlorobenzenesulfonyl  chloride 

o-Chlorobenzoio  acid 

p-Chlorobenzoic  acid 

p-Chlorobenzonitrlle 

5-Chloro-2-benzoxazolinone 

»o-(p-Chlorobenzoyl) benzoic  acid 

p-Chlorobenzoyl  chloride 

4,^'-(o-ChlorobenzyHdene)di-2,5-xyUdine 

a-(p-Chlorobenzyl) -a-phenyl-l-pyrrolldlne  propanol 

Chloro(p-chloropenyl)phenylinethane 

Chlorooyclohexane 

l-Chloro-2, 5 -diethoxy -4 -nitrobenzene * 

3-Chloro-'i-(diethylaiiilno)benzenediazonluin  chlorozincate 

2-Chloro-N,N-dlethyl^-nitroaniliue 

2-Chloro-3',4'  -dlhydroxyacetophenone 

2-Chloro-l,'i-dihydroxyaiithraquinone 

4  '-Chloro-2  ',  5  '-dimethoxyacetoaoetanllide 

5-Chloro-2,4-di]nethoxyaniline 

5-Chloro^,7-dimethylbenzo[b]thlophen-3(2H)-one 

4.-Chloro-N,N-dimethyl-3-nitrobenzenesulfonaiiilde 

»l-Chloro-2,A-dlnitrobenzene   (Dlnltrochlorobenzene) 

l-Chloro-2,'i-dinltrobenzene  and  2-ohloro-l,3-dinitrobenzene 
mixture. 

3-Chloro-4,6-dinitrobenzene8ulfonlc  acid 

3-Chlorodiphenylamine 

Chlorodiphenylme thane 

N-(2-Chloroethyl)  -4-(2-chloro-4-nitrophenylazo) - 
N-e thy lani line. 

N-(2-Chloroethyl)-N-ethylanillne 

p-[(2-Chlorbethyl)iiiethylaiiiino]  benzaldehyde 

2-Chloro-N-ethyl-5-nltrobenzenesulfonanillde 

Chlorofonalc  acid,   benzyl  ester 

Chloroformic  acid,   phenyl  ester 

4-Chloro-3-hydrazinobenzenesulfonlc   acid 

l-Chloro-4-hydroryanthraquinone 

5'-Chloro-3-hydroxy-2-naphth-o-anisidide 

3-Chloro-<l-hydroxyquinollne-3,4-carbonic   acid 

6-Chloroisatolc  anhydride 

<i-Chloro-N-isopropyl-3-nltrobenzenesulfonainide 

A-Chlorometanlllc   acid 

S-Chlorometanillc  acid 

*6-Chloroinetanillc   acid 

5-Chloro-2-methoxybenzenediazonluin  chloride 


GAF. 

LIL. 

OIV. 

FMP,   UCC. 

EK. 

EX. 

LIL. 

DUP. 

DUP,   GAF. 


EKT. 

BUC,   DUP. 
ALL,   BUC. 


i,   DUP,    GAF,    ICI,   MAI,    NAC,   TRC. 
f,   GAF,   NAC,    TRC. 


DOW,    DVC,    HK,   HKD,   MDN,   MTO,   OMC,    PPG,    WOI. 
NES. 


ACY,   DUP,   GAF,    HN,    ICI,    NAC. 

HN. 

GAF. 

UL. 

OPC. 

ACY. 

ALL,   FWT,   GAF. 

ESA. 

DUP. 

SDW. 

HSH. 

PCW. 

GAF, 


PCW. 

DUP,    NAC,  SDC. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  7B.  — Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  7966— Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


N-[(5-Chloro-2-methoxyphenyl)azo]sarcosine 

p-(Chloromethyl)anlsole 

»l-Chloro-2-methylanthraqulnone 

6-Chloro-4.-methyl-l,3,2-benzothiazathioliuai  chloride 

^-(Chloromethyl)-l,2-dimethylbenzene 

A-(Chloromethyl)-l,3-dimethylbenzene 

l-(Chloromethyl) naphthalene 

^-Chloro-N-methyl-3-nitrobenzenesulfonamide 

"i-Chloro-3-(3-methyl-5-oxo-2-pyrazolin-l-yl)benzene- 
sulfonic   acid. 

2-Chloro-5-(N-methylsulfainoyl)  sulfanilamide — 

5-Chloro-2-(N-methylsulfa]iiyl)  -/i-sulf  amyl-N-benzylaniline 

'i-Chloro-3-(methylsulfonyl)  nitrobenzene 

Chloronaphthalenes 

9-Chloronaphthol  [l,2-b]  thiophen-3(2H)  -one - 

»2-Chloro-';-nitroaniline   (o-Chloro-p-nitroaniline) 

»<i-Chloro-2-nitroaniline   (p-Chloro-o-nitroaniline) 

4-Chloro-2-nitroanisole 

*l-Chloro-5-nitroanthraquinone 

l-Chloro-8-nitroanthraquinone 

»l-Chloro-2-nitrobenzene  (Chloro-o -nitrobenzene) 

l-Chloro-2( and  i) -nitrobenzene   (Chloronitrobenzenes, 
o-  and  P-) . 

»l-Chloro-3 -nitrobenzene  (Chloro-m-nitrobenzene) 

*l-Chloro-'+-nitrobenzene   (Chloro-p -nitrobenzene) 

2-Chloro-5-nitrobenzenesulflnlc  acid 

»'4-Chloro-3-nitrobenzenesulfonainlde 

'i-Chloro-3-nitrobenzenesulfonanllide 

2-Chloro-5-nitrobenzenesulfonic   acid 

2-Chloro-5-nltrobenzenesulfonic   acid,   sodium  salt 

4-Chloro-3-nitrobenzenesulfonio   acid 

2-Chloro-5-nitrobenzenesulfonyl  chloride 

M-Chloro-3-nltrobenzenesulfonyl  chloride 

2-Chloro-4-nitrobenzoic  acid 

2-Chloro-5-nitrobenzoic  acid 

■»o-(4-Chloro-3-nitrobenzoyl)  benzoic  acid 

i-Chloro-2-nitrophenol 

4-Chloro-3-nitrophenyl  methyl  sulfone 

2-Chloro-4-nitrotoluene 

2-Chloro-6-nltrotoluene 

4-Chloro-2-nltro toluene 

«4-Chloro-3-nltrotoluene 

a-Chloro-m-nltrotoluene 

Chloropentafluorobenzene 

m-Chlorophenol 

o-Chlorophenol 

p-Chlorophenol 

2-Chlorophenothiazi 

(p-ChloTOphenyl) acetonitrlle 

4-Chloro-  a^phenyl-o-cresol 

i-Chloro-o-phenylenediamine 

3-(o-Chlorophenyl) -5-methyl-4-lsoxazolecarbonyl  chloride 

3-(o-Chlorophenyl)  -5 -methyl -<i-isoxazolecarboxy lie 

l-(p-Chlorophenyl)  -3-methyl-2-pyrazolln-5-one  — 

p-Chlorophenyl  methyl  sulfone 

2-Chloro-4-phenylphenol 

2-(A -Chloropheny Ithi  o ) benzol 

4-Chlorophthallc  acid 

Chlorophthalic  anhydride. 

(3-Chloropropenyl)benzene  (Cinnamyl  chloride) 

1-  (3-Chloropropyl )-4-methylpipera 

""'-( 6-Chloro-3-pyTidazinyl)  sulfanilamide. 

2-Chloropyridine 

dl-2-[p-Chloro-2-(2-pyridyl) benzyl] oxy-N,N-dimethylethyl 

amine  maleate 
7-Chloro-4-qulnolinol- 
\  -Chlororesorcinol 
2-Chloro-5-sulfamoylbenzolc  acid 
2-Chlorothiaxanthen-9 -one 


DUP,  GAF,  ICI,  NAC,  TRC. 


TRC. 

KPS. 

GAF. 

DOW, 

DUP, 

HSC, 

SDC. 

DOW, 

DUP, 

SDC, 

VPC. 

ALL, 

BUG. 

AGY, 

DUP, 

MAY, 

NAC,    TRC 

DUP, 

MAY. 

AAP, 

DUP, 

MON, 

UPM. 

SDC. 

DUP, 

GAF, 

MON, 

UPM. 

AAP, 

DUP, 

MON, 

UPM. 

TRC. 

AAP, 

CMD, 

DUP, 

EKT,    ICC 

TRC. 

AAP, 

CMG, 

NAC, 

TRC. 

DUP, 

GAF. 

GAF, 

NAC, 

TRC. 

TRC. 

AAP, 

DUP, 

EKT. 

DUP. 

DUP. 

BUG, 

DUP. 

AAP, 

BUG,   DUP 

EK. 

WHC. 

EK. 

DOW, 

GAT,  MON 

DOW, 

MON. 

SK. 

ICO, 

OPC. 

MON. 

FMT. 

ICO, 

OTC. 

ICO. 

DUP, 

TRC. 

TRC. 

DOW. 

MEE. 

DUP, 

SW. 

HK. 

SDW. 

SK. 

ACY. 

FMT. 

X. 

SDW. 

AAP, 

GAF. 

CYCLIC  INTERMEDIATES 


75 


TABLE  IB.— Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1966 — Continued 


Manufacturers '    identification  codes 
(according  to  list  in  table  22) 


and  hydrochloride 

(<i-Chloro-o-toluidin 


2-Chlorothiophene 

m-Chlorotoluene 

p-Chlorotoluene 

»a-Chlorotoluene  (Benzyl  chloride) 
3-Chloro-o-toluidine  [NH2=1 
3-Chloro-p-toluidine  [NH2=1 
4-Chloro-o-toluidlne  [NHj^l 
»5-Chloro-o-toluidine  [NHs^l 
[CH3  =  1]). 

5-Chloro-o-toluidine  hydrochloride  [NH2=1] 

«N-[ (5-Chloro-o-tolyl)azo]sarcosine 

l-(6-Chloro-o-tolyl)-3-methyl-2-pyrazolin-5-one 

»[('i-Chloro-o-tolyl)thio]  acetic   acid 

4-Chloro-a,  a,  a-trif  luoro-3-nitrotoluene 

5-Chloro-a,a,a-trifluoro-2-nitrotoluene 

p-Chloro-O'j^j^-trifluoro  toluene 

6-Chloro-'',*,''-trlf  luoro-m-toluldine 

<;-Chloro-a,a,a-trifluoro-o-toluidine 

2-Chloro-l,3,5-trinitrobenzene 

Chlorotriphenylmethane 

2-Chloro-p-xylene 

<i-Chloro-2,5-xylenesulfonyl  chloride 

.i-Chloro-3,5-xylenol 

[(<;-Chloro-2,5-xylyl)thio]  acetic  acid 

5a-Cholestan-3  p-ol 

ChoUc  acid 

Cinnamoyl  chloride 

»Cresols:^ 

m-Cresol 

«o-Cresol: 

From  coal  tar 

From  petroleum 

p-Cresol 

Cresols,  mixed :^ 
»(m,p)-Cresol: 

From  coal  tar 

From  petroleum 

(o,m,p) -Cresol:  From  coal  tar 

2,3-Cresotic  acid 

»Cresylic   acid,   refined:^ 

»From  coal  tar 

■»From  petroleum 

»Cuinene 


a-Cyano-d-'ja-cyclohexaneacetic  acid,   ethyl  ester- 
a-Cyano-l-cyclohexene-l-acetic   acid,   ethyl  ester- 

i-[(2-Cyanoethyl)ethylaiiiino]-o-tolualdehyde 

P-[(2-Cyanoethyl)methylaiiiino]  benzaldehyde 

8-Cyano-l-naphthalenesuKonic   acid 

•Cyclohexane 


1,2-Cyclohexanedicarboxylio  anhydride 

Cyclohexanol 

«Cyclohexanone 

Cyclohexanone  oxtme 

Cyclohexene 

4-Cyclohexene-l,2-dicarboximide 

i- Cyclohexene-l,2-dicarboxylic  anhydride- 

»Cyclohexylaiiiine 

Cyclohexyl-2-propanone 

N-Cyclohexyltaurine,   sodium  salt 

Cyclopentanepropionic   acid 

Cyclopentanol 

Cyclopentene 

(2-Cyclopenten-l-yl) -2-propanone 

l-Cyclopentyl-2-(methylamlno)propane 

p-Cymene 

Deoxycholic  acid 


BPC,  GRH,  HK,  HN,  MDN,  TBK,  VEL. 

DUP. 

DUP. 

ACY,  PCW. 

ATL,  BUG,  DUP. 

BUG,  SDH. 
ALL,  ATL,  GAF. 


ARA,   EK. 

DUP. 

NAG. 

OTA. 

NAG. 

SDW. 

WIL. 

IGO,    TBK, 

X. 

KPT,    PRD. 

KPT,    PRD. 

ACY,   MER, 

NPG,    PRD,   SW. 

HPG,   SW. 

AGP,    KPT, 

PRD. 

MER,    NPG, 

PIT,   PRD. 

AGP,    KPT. 

DOW. 

AGP,    KPT. 

AIR,   MER, 

NPG,   PIT,   SHO. 

ACC,    AGP, 

CLK,    DOW,   GOG,    HPG,   MON,   SHG,   SKO,   SNT,   SQK. 

TX. 

SDW. 

SDW. 

DUP,   GAF. 

DUP,   GAF. 

DUP. 

ASH,    GO, 

GSD,    DUP,    EKX,    ENJ,   GOC,   GRS,    PLC,   RIG,   SCO 

TX,    UOG 

NAG. 

DUP,  MON, 

NAG. 

DBG,    DUP, 

MON,    NAG. 

NAG,   X. 

EK,    PLG. 

GHO. 

NAG,    PTT. 

ABB,    JGC, 

MON,   PAS,   VGG,   X. 

GIV. 

GAF. 

ARA. 

ARA,    LIL. 

PLC. 

LIL. 

LIL. 

HNW,    HPG, 

NAC. 

WIL. 

AAP. 

SDW. 

See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  7B.  --Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  J966— Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


3'-[Di(2-aoetoxyethyl)amino]-p-acetophenetidlde 

3-(Diallylcarbajiioyl)-l,2,2-triiiiethylcyolopentanecarboxyllc 

acid. 

N^,N^-Diallyljiielamine - 

»l,4-Diaiiiinoanthraquinone 

1,5-Diaminoanthraquinone 

l,5(and   1,8) -Diajninoanthraquinone 

»2,6-Diamlnoanthraquinone 

3,4-Diajiiinobenzanllide 

3','i-Diaminobenzanilide 

2,4-Diaminobenzenesulfonic  acid  [S03H=l] 

2,5-Diaiiiinobenzenesulfonic   acid  [S03H=l] - - 

4-, A  '-Dlamino-2,2  '-biphenyldisulf  onic  acid 

l,5-Diainlno-2,6-dibromo-A,8-di-p-toluidlnoanthraq\iinone 

l,"i-Diamlno-2,3-dichloroanthraquinone 

»l,4-Diamino-2,3-dihydroanthraquinone 

4,8-Diamino-9,10-dihydro-l,5-dihydroxy-9,10-dioxo- 

2,6-anthracenedisulfonic  acid. 
l,A-Diamino-9,10-dihydro-9,10-dioxo-2,3-anthraeene- 

dicarbonitrlle. 
l,4-Diajnino-9,10-dihydro-9,10-dioxo-2,3-anthracene- 

dicarboximide. 

l,5-DiaiBino-4,8-dihydroxyanthraquinone 

l,5(and   l,8)-Diamino-i,8(and  -i.S) -dihydroxyanthraquinone  — 

4.,5-Diamino-l,8-dlhydroxyanthraquinone 

3,6-Diamino-2,7-dimethylacridine 

3,6-0iajnino-2,7-dimethylacridine  sulfate 

4,^'-Diamino-5,5'-diiiiethyl-2,2'-biphenyldisulfonic  acid 

2,'4-Diamino-6-phenyl-s-triazine 

2,6-DiamlnopyTidine 

6,7-DiaiQino-2,3-quinolinediol 

»A,A'  -Dianiino-2,2  '-stilbenedisulfonic  acid 

l,5-Dlamlno-2,4,6,8-tetrabromoanthraquinone 

<i,6-Diamino-m-toluenesulfonic   acid    [S03H=l] 

3,5-Diaiiiino-p-toluenesulfonic  acid    [S03H=l] 

3,5-Diaiiiino-2,'i,6-triiodobenzoic  acid 

l.iiaje-Dianhydroglucitol 

l,5-Dianilino-9,10-dihydro-9,10-dioxo-2,6-anthracene- 

dicarboxylio  acid. 

2,4-Dianilino-l-hydroxyanthraquinone 

6,8-Dianilino-l-naphthalenesulfonic  acid 

2,5-DianillnoterephthaUo  acid - - 

Diarylguanidlne 

p-Dlazo-N,N-diinethylaniline-l-amino-8-naphthol-3- 

sulfonate-6-sulfonic  acid,  sodium  salt. 
5(and  3) -Diazo-6-oxo-l,3(and   1,4) -cyclohexadiene- 

1-carboxylio  acid. 

1,5-Dibenzamidoanthraquinone 

6,ll-Dibenzajnido-16H-dinaphtho[2,3-a,2  ',3  '-i]  -carbazole-5, 

10,15,17-tetrone. 

•4,5'-Dibenzaiiiido-l,l'-iminodianthraqulnone 

Dibenzo[b,def] chrysene-7,14-dione 

»1, 5 -Dibenzoylnaphthalene 

N,N'-Dlbenzylethylenedi amine 

NjN'-Dlbenzylethylenediamlne  diaoetate 

N,N'-Dibenzylidenetoluene-a,a-dia]iilne 

N,N-Dibenzylsulfanllic  acid - 

2,<i'-Dibromoacetophenone 

»3,9-Dibromo-7H-benz[de]anthracen-7-oiie 

p-Dibromobenzene 

ar-Dibronioethylbenzene 

2,6-Dibronio-4-iiitrophenol 

5,13-Dlbroiiio-8,16-pyTanthrenedione 

Dibromoviolanthrone 

p-Dlbutoxybenzene 

l,4-Dibutoxy-2-chloro-5-nltrobenzene 

2,5-Dibutoxy-4-morpholinobenzene  sulfate 

4-(2,5-Dlbutoxy-4-nitrophenyl)morpholine 

2,6-Dl-tert-butyl-4-nonylphenol 

2,4-Dl-tert-butylphenol — - 


ACY. 

CM3, 

GAF, 

AAP, 

AAP, 

DUP. 

VPC. 

DUP, 

TRC. 

AAP, 

ICI. 

CMG,   DUP. 

ACY,   ATL,   DUP,   GAF,    HSH,    ICC,    ICI,   MAY,    TRC. 

TRC. 


DUP,    GAF,    NAC,    TRC. 

TRC. 

ICI,    TRC. 

GAF,    ICI,   NAC,    TRC,   VPC. 


NAC,    TRC. 
ACY,    NAC. 


DUP, 

DUP. 

ICI. 

DUP. 

DUP. 

AAP. 

RH,   \ 

RIL. 

BJL. 

ACY, 

ICI. 

NAC. 

GAF. 

SDW. 

APD. 

GAF, 

GAF. 
NAC. 
MEE. 
DUP. 
IDC. 


GAF,    ICC,   VPC. 


DUP,   GAF,   GGY,    NAC,   SDH,    TRC,   VPC. 


DUP,   GAF,    ICI,   MAY,    NAC,    TRC. 

ICI. 

DUP,   GAF,   HST,    ICI,    TRC,   VPC. 


CYCLIC  INTERMEDIATES 


77 


TABLE  7B.  —Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  566— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


Dibutyltin  biE(cyclohexyl  maleate) 

2,'V-Dichloroaniline 

3, 'i-Dichloro  aniline 

•2,5-Dichloroaniline  and  hydrochloride    [NH2=1]- — 

3-(2,'i-Dichloroanllino)-l-(2,A,6-trichlorophenol) 

»lj5-Dichloroanthraquinone 

l,5(and  1,8) -Diohloroanthraquinone 

»l,8-Dichloroanthraquinone 

2,6-Dichlorobenzaldehyde 

3-(3,<i-Dichlorobenzaiiiido)  -l-phenyl-2-pyrazolin-5-one 

Dichlorobenzanthrone 

m-Dichlorobenzene 

»o-Diohlorobenzene 

o(and  p) -Dichlorobenzene 

•p-Dlchlorobenzene 

4,6-Dichloro-in-benzenedisulfonamide 

'V,6-Dichloro-m-benzenedisulfonyl  chloride 

»3,3'-Dichlorobenzidine  base  and  salts 

2,i-Diohlorobenzoic  acid 

2,6-Diohlorobenzonitrile 

2,'i-Dichlorobenzoyl  chloride 

2,5-Dichlorobenzoyl  chloride 

2,<i-Dichloro-m-cresol 

7,16-Diohloro-6,15-dihydro-5,9,lA,18-anthrazinetetrone— 
<;,8(and  A,5) -Dichloro-9,10-dihydro-9,10-dioxo-l,5(and 

l,8)-anthracenedisulfonic  acid. 
'i,5-Dichloro-3,6-dioxo-l,^-cyclohexadiene-l,2-di- 

carbonitrile . 

Dichlorodiphenylsilane 

2',7'-Dichlorofluorescein 

SjlA-Dichloroisoviolanthrone 

*2 , 5 -Dichloro-4 -( 3-methyl-5-oxo-2-pyrazolin-l-yl) 

benzenesulfonic  acid. 

»2,6-Dlchloro-A-nitroanillne— — 

1, 2 -Dichloro -4 -nitrobenzene 

»l,<V-Dichloro-2-nitrobenzene  ( Nitro-p-dichlorobenzene) 

2,5-Dichloro-3-nitrobenzoic  acid , 

2,5-Dichloro-3-nitrobenzoio  acid,  ammonium  salt 

2,'4-Dichlorophenol 

2-(2,'4-Dichlorophenoxy)ethanol 

N- [ ( 2 , 5-Dichlorophenyl) azo ] -N-ethyl-5 -sulf  oanthranilic 

acid. 
3-(2',6'-Dichlorophenyl)-5-methyl-4-isoxazolecarbonyl 

chloride. 
3-(2',6 '-Dichlorophenyl) -5-methyl-4-isoxazolecarboxylic 

acid. 

2,6-Dichloropyrazine 

3,6-Dichloropyridazine 

4,7-Dichloroquinoline 

3,5-Dichlorosalicylic   acid 

2,5-Dichlorosulfanilic  acid   [SOjH^l] - 

2,5-Dichloro-<;-sulfobenzenediazonium  sulfate 

p,a-Dichlorotoluene 

a,a-Dichlorotoluene   (Benzal  chloride) 

2,6-Diehlorotoluene 

2,<i-Dichloro-3,5-xylenol 

Dicyclohexylamine 

»Dicyolopentadiene   (includes  cyclopentadiene) 

Dicyclopentadiene  dioxide 

2,5-Diethoxyaniline 

2',5'-Diethoxybenzanilide 

p-Diethoxybenzene 

3,4-Diethoxybenzoic  acid 

2,5-Diethoxy-morphoUnobenzenediazoniuin  chloride,   zinc 

chloride. 

'i-(2,5-Diethoxy-i-nitrophenyl)morphollne 

•p-(Diethylamino)benzaldehyde 

2-Diethylaminoethyl-^-acetylamlnophenol 

p-(Diethylamino)benzenediazonlum  chlorozinoate 

a-  [(2-Diethylamino)ethyl]  -  ct-phenylcyclohexanemethanol, 

hydrochloride. 


EK. 

DUP,    ClAF,    ICI,    NAC,    TRC. 

DUP,    NAC. 

DUP,    GAF,    ICI,    TRC. 

DUP. 

EK. 

ACY. 

EK,   GAF. 

ACS,   CPD,   DOW,   DUP,   DVC,   MON,   OMC,   PPG,   SCC,   SVT, 

WOI. 
HKD,   MTO. 
ACS,    CPD,   DOW,   DVC,   HK,   MON,    PPG,   SCC,   SVT,    WOI. 


ALL,    CWN,    LAK,    NAC. 


cm:;,  DUP,  SDH,  trc,  vpc. 

CWN,   DUP,   GAF,  HSH,  MEE,    PCW,   SW,    TRC. 

MON. 

DUP,    NAC,    PCW,  SDC,  VPC. 


ACY. 
ACY. 
PD,   SDW. 


ICO. 

CIG,   DUP,    VPC. 

TRC. 

HN. 

HK,    NAC. 

DUP,   GAF. 

OTA. 

ABB,   MON,    VGC. 

ENJ,   GOC,   UCC,   VEL. 

VEL. 

GAF. 

GAF. 

GAF. 

ICO. 

ALL. 

ALL. 

DUP,   GAF,    NAC. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


■Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  7566- -Continued 


Manxif acturers '   identification  codes 
(according  to  list  in  table  22) 


m-(Diethylamino) phenol  (N,N-Diethyl-3-aminophenol) 

3-f  (p-Diethylamino)phenylazo]-lH-l,2,'4-triazole 

3-(Diethylamlno)proplophenone 

4-(Diethylanilno)  -o-tolualdehyde 

»N,N-Diethylaniline -  — 

N,N-Diethyl-m-anisidine 

Diethylbenzene 

Diethyl-[3,3'-bianthra[l,9-od]pyrazole]  -6,6'-dione 

l,l'-Diethyl-4,4'-carbocyanine  iodide   (Cryptocyanine) 

NjN-Dlethylcyclohexylamine 

a,  a'-Diethyl-'i,<+'  -dlmethoxystllbene 

N.N-Diethylmetanilic  acid 

N  ,N^-Diethyl-^-methoxymetanilamide 

N.N-Diethyl-l-naphthylamine 

N,N-Dlethyl-p-nltrosoanillne 

N,N-DietJ^rl-<i-nitroso-m-anisidine  hydrochloride 

N,N-Diethyl--4-nltroso-m-phenetidine 

N,N-Diethyl-m-phenetldine - 

N,N-Diethyl-m-toluidlne 

ejlS-Dihydro-SjgjKjlS-anthrazinetetrone 

10,ll-Dihydro-5H-dibenzo[a,d]cyclohepten-5-one 

«9,10-Dihydro-l,A-dihydroxy-9,10-dioxo-2-anthraoene- 

sulfonic  acid   (2-Qulnizarinsulfonic   acid). 
N-(5,13-Dlhydro-5,13-dloxoaoeanthryleno[2,l-a]- 

aceanthrylen-7-yl)-9,10-dihydro-l-nitro-9,10-dioxo-2- 

anthr amide. 

»9,10-Dihydro-9,10-dioxo-l,5-anthraoenedisulfonic  acid 

•9, lO-Dilftrdro-9 , 10-dloxo-l, 5 -anthracenedlsulf onic  acid , 

dlsodlum  salt. 
9,10-Dihydro-9,10-dioxo-l,5(and   1,8) -anthracenedlsulf onlc 

acid  and  salt. 

9,10-Dihydro-9,10-dioxo-l,8-anthracenedlsulfonic  acid 

»9,10-Dihydro-9,10-dioxo-l,8-anthracenedisulfonic  acid, 

potassium  salt. 
»9,10-Dihydro-9,10-dioxo-2,6-anthracenedisulfonlc   acid  and 

salt. 
•«9,10-Dlhydro-9,10-dioxo-l-anthraoenesulfonic  acid   and  salt 

(Gold  salt). 
9,10-Dihydro-9,10-dioxo-2-anthracenesulfonlc  acid   and  salt 

(Silver  salt) . 

9,10-Dihydro-9,10-dloxo-2-anthroic   acid 

3,<;-Dihydro-3,'i-dioxo-l-naphthalenesulfonlc  acid,   sodium 

salt. 

[Dihydrogen  3,3  "-phthalocyaninedisulfonato-( 2-)] copper 

10,ll-Dihydro-5-  [3-(methylaminopropyl)]  -5H-dibenzo- 

[a,d] cyclohepten-5-ol. 
«9,10-Dihydro-5-nltro-9,10-dioxo-l-anthracenesulfonio  acid — 
9,10-Dihydro-5(and  8) -nitro-9,10-dioxo-l-anthracene- 

sulfonic  acid. 
9,10-Dihydro-8-nltro-9,10-dioxo-l-anthracenesulfonlc  acid  — 
9,10-Dlhydro-8-nitro-9,10-dloxo-l-anthraoenesulfonlc  acid, 

sodium  salt. 

9,10-Dihydro-l-nitro-9,10-dioxo-2-anthroic  acid 

l,'i-Dlhydro^-oxo-2,6-pyridlnedicarboxylic  acid 

»l,<i-Dihydroxyanthraquinone  (Qulnlzarin) 

»l,5-Dihydroxyanthraquinone  (Anthrarufin) 

l,5(and  1,8) -Dihydroxyanthraquinone 

»l,8-Dihydroxyanthraquinone  (Chrysazln) 

2,6-Dihjfdroxyanthraqulnone  (Anthraflavlc  acid) 

4,5-Dihydroxy-m-benzenedisulfonic  acid,  disodium  salt 

2,'4-Dlhydroxybenzophenone 

»l,5-Dihydroxy-4,8-dlnltroanthraqulnone 

l,5(and  l,8)-Dlhydroxy-4,8(and  <i,5)-dinltroanthraquinone— - 
»l,8-Dihydroxy-A,5-dinitroanthraquinone  (4.,5-Dl- 
nltrochrysazin) . 
l,5-Dihydroxy-A,8-dinitro-2,6-anthraqulnonedisulfonic 

acid. 
17a,21-Dihydroxy-9p,lip-epoxy-16p-methylpregna-l,'i-diene-3, 
20-dlone. 


ACY, 

DUP. 

TRC. 

ACY. 

DUP. 

ACY, 

DSC, 

DUP, 

NAC,   SDH 

DUP. 

r^D, 

DOW, 

KPP. 

GAF. 

EK. 

DUP. 

TIL. 

DUP. 

PCW. 

DUP. 

ESA, 

GAF. 

DUP. 

GAF. 

GAF. 

DUP. 

TRC. 

LIL. 

AAP, 

HSH, 

PAT. 

ICI, 

NAC. 

ACY, 

DUP, 

TRC. 

DUP, 

GAF, 

ICI, 

TRC. 

DUP, 

TRC. 

DUP. 

GAF, 

ICI, 

TRC. 

AAP,  ACY,  GAF,  ICI,  NAC,  TRC,  VPC. 
AAP,  ACY,  DUP,  GAF,  ICI,  MAY,  NAC,  TRC. 
DUP,  NAC. 


NAC. 

EK. 

ICI. 

UL. 

DUP,   MAY, 

NAC,    TRC. 

ICI,    TRC. 

MAY,    NAC. 

DUP. 

DUP,    GAF, 

NAC,    TRC. 

SDW. 

AAP,   ACY, 

CMG,   DUP,    EKT, 

GAF, 

HSH,    ICC, 

ICI,    JTC 

MAY,    NAC,    TRC. 

ACY,   DUP, 

GAF,    NAC. 

CNC,    TRC. 

DUP,   GAF, 

ICI. 

GAF,    TRC. 

SDW. 

DUP,    GAF. 

ICC,    ICI, 

VPC. 

TRC. 

DUP,   GAF, 

ICC,    ICI. 

DUP. 

SCH. 

CYCLIC  INTERMEDIATES 


—Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 — Continued 


Manufacturers'    identification  code 
(according  to  list  in  table  22) 


10,10  '-(Dihydroxyethanedlylldene)dianthrone 

'i,5-Dihydroxy-2,7-naphthalenedisulf onic   acid 
(Chromotropic   acid). 

6,7-Dihydroxy-2-naphthalenesulfonic   acid 

3,5-Dlhydroxy-2-naphthcic  acid 

llB,21-Dihydroxypregna-4,17(20)-cis-dien-3-one 

llP,21-Dlhydrcxypregna-l,'i,17(20)-cis-trien-3-one 

AjS-Dlhydroxy-S-Cp-sulfophenylazo) -2,7-naphthalene- 

disulfonic  acid,  trisodium  salt. 
*16,17-Dihydroxyviolanthrone  (Dlhydroxydibenzanthrone) — 

m-Diiodobenzene 

2,5-Diiodobenzoic  acid,  2-(2-methoxyethoxy)ethyl  ester- 

3,5-Diiodo^-oxo-l(iH)pyridineacetic  acid- 

3,5-Diiodo-L-tyroslne 

Diisopropylbenzene 

N,N'-Diisopropyl-p-phenylenediamine 

2,5-Dimethoxyaniline 

l,5(and  1,8) -Dime thoxyanthraquinone 

2,5-Dimethoxybenzaldehyde 

m-Dimethoxybenzene 

«3,3'-Dimethoxybenzidine  (o-Dianisidine) 

3,3'-Dimethoxybenzidine  hydrochloride 

2,4 -Dime thoxybenzoic  acid 

3,<i-Dimethoxybenzoic  acid 

N,N'-[(3,3'-Dimethoxy-4,4'-biphenylylene)bis-(azo)]bls- 
(N-methyltaurine) . 

2,5 -Dime  thoxy-p! -methyl- p-nitrostyrene 

N-(3,A-Dimethoxy-a-methylphenethyl)-2-('i-ethoxy-3 
methoxyphenyl) acetamide . 

2,5-Dimethoxy^'-nitrostilbene 

3,'4-Dimethoxyphenethylamine  (Homoveratrylamlne) 

'i-(2 ',5 '-Dimethoxyphenethyl)  aniline  hydrochloride 

N-(3,';-Dimethoxyphenethyl)-2-(3,';-dimethoxyphenyl) 
acetamide. 

( 3, 4-Dimethoxyphenyl) acetic   acid 

(Sj-i-Dimethoxyphenyliacetonitrile 

l-(3,4-Dimethoxyphenyl) -2-aminopropane 

l-(3,'i-Dimethoxyphenyl)-2-nitro-l-propene 

2,5-Dimethoxytetrahydrofuran 

16,17-Dimethoxyviolanthrone 

3'-Dimethylaminobenzanilide 

p-(Dimethylamino)benzenediazonium  chlorozincate 

m-(Dtmethylamino) benzoic  acid 

a-(Dimethylamino)-p-creeol 

6-Diinethylamino-2-[2-(2,5-dimethyl-l-phenyl-3- 

pyrryl) vinyl] -1-methyl-l-quinolinium  methyl  sulfate. 

2-  [(2-Dimethylamino)  ethyl]  amlnopyrld  ine — 

2- [[2-( Dijnethylamino)  ethyl] -2-thenylamino]  pyridine 
(uonmedicinal  grade). 

2-  [[2-(Dimethylamino) ethyl] -3-thenylamino] pyridine 

m-(Dimethylaiiiino)  phenol 

N-(p-Dimethylaminophenyl)-l,-4-naphthoquinonelmlne 

»N,N-DlmethylaniUne 

7,12-Dlmethylbenz[a] anthracene 

3,3'-Dimethylbenzidine   (o-Tolidine) 

3,3 ' -Dime thy Ibenzid ine  hydrochloride 

»N,N-Dlmethylbenzylamine 

4.-(a,a-Dijnethylbenzyl)-2-phenylazophenol 

»2,2'-Dimethyl-l,l'-bianthraquinone 

Dimethyl-6,12-ceroxenol  acetate 

5,5-Dimethyl-l,3-cyclohexanedione 

N,N-Dimethylcyclohexylamine 

2',7'-Dimethylfluoran 

5,5-Dimethylhydantoin— - 

2,3-DiiiiethyUndole  — 

2,5-Dtmethyl-<i(2)  -morpholinylmethylphenol  hydrochloride 
N.N-Dimethyl-m-nitro  aniline 

»N,N-Dimethyl-p-nitroEoanillne 

N,N-Dinethyl-p-phenylazoaniline 

N,N-Dlmethyl-p-phenylenediamlne 

N,N-Dinethyl-p-phenylenediamine  hydrochloride 

1,'i-Dimethylpiperazine 


FMT,   GAF,    IDC. 

GAF. 

UP  J. 

UP  J. 

EK. 

ACY,    DUP,   GAF,    ICI,   MAY,    NAC. 


ICO. 

CWN,   DUP,    LAK,   SDH. 


LIL. 

LIL. 

LIL. 

LIL. 

HEX. 

DUP,    GAF,    ICI, 

DUP. 

ESA. 

SDH. 

TKL. 


NAC. 

ACY,   DSC, 

DUP, 

NAC, 

SDH. 

EK. 

CWN,   DUP. 

AAP,   DUP, 

EK. 

ICO,   MLS, 

RH. 

TRC. 

AAP,   ACY, 

CMS, 

DUP, 

GAF, 

TCT, 

NAC, 

TRC 

WIW. 

EKT. 

DUP,   EKT. 

WIW. 

GLY. 

DUP. 

IDC. 

DUP. 

ACY,   DUP, 

ESA, 

NAC. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  2566— Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


N,N-Dimethylsulfanllic  acid 

N,N-Dimethyl-p-toluidlne 

»2,'i-Dinitroanlline 

p-(  2, "i-Dinitroanl  lino)  phenol 

»l,5(and   1,8)-Dinitroanthraqulnone 

N,N'-(2,'i-Dinltro-l,5-anthraqulnonylene)dioxamic  acid 

3',<i-Dlnitrobenzanllide 

m-Dinitrobenzene 

2,A-Dlnitrobenzenesulfonlc  acid 

3,5-Dinitrobenzoic  acid 

3,5-Dinltrobenzoyl  chloride 

10, 10 '-Dlnitro  [3,3 '-bi-7H-benz[de]  anthracene] -7,7 '-dione— 

3,3'-Dinitro-A,^'-biaeetanilide 

Dinitrooaprylphenol 

2,5-Dinltro-p-cresol 

2,4--DlnltrocuiDene 

3  ',5'-Dlnitro-2'-hydroxyacetanllide 

l-(3,5-Dlnitro-2-hydroxyphenylazo)-2-naphthol 

»2,<i-Dlnltrophenol,  tech 

( 2, A-Dinitrophenyl) hydrazine 

3,5-DinitrOEalicyllc  acid 

*A,i,'  -Dlnitrostilbene-2,2  '-disulfonlc  acid 

»2,'i-Dinltrotoluene 

2,'4(9nd  2,6)-Dlnitrotoluene 

3,5-Dinltro-p-toluenesulfonio  acid 

Dlnonylphenol 

2,4--Di-tert-pentylphenol 

2,4-01 -tert-pentylphenoxyacetyl  chloride 

*l,5-Diphenoxyanthraquinone 

l,5(and  l,8)-Diphenoxyanthraqulnone 

1,8-Diphenoxyanthraqulnone 

Dlphenylacetlc  acid 

»Diphenylamine ■» 

2,8-Diphenylanthra[l,2-d:6,5-d']bisthlazole-6,12-dione 

» -d - 1 , 2 -Di pheny 1 -4— d Ime thy lamino -2 -hyd roxy-3 -me thy Ibut ane , 
camphor  sulfonate. 

N,N'-Diphenylethylenedlamlne 

Dlphenylmethane 

2,5-Diphenyloxazole 

l,3-Diphenyl-l,3-propanedione 

1,3-Diphenyltriazene 

1,3-Di^-piperidylpropane 

2,2  '-Dlthiodibenzoic  acid 

*l,4-Di-p-toluidlnoanthraqulnone 

1,5-Di-p-toluidinoanthraquinone 

1,8-Di-p-toluidlnoanthraqulnone 

l,'i-Di(p-toluidino)  -5,8-dihydroxyanthraquinDne 

»Divinylbenzene 

Dlxylylguanidines,  miaed 

Dodeoylbenzene.   (See  Aliylbenzenes . ) 

Dodecylbenzyl  chloride 

Dodecylmethylbenzyl  chloride 

«p-Dodecylphenol 

Eosin  (2', 4', 5  ',7 '-Tetrabromof luorescein) 

Epoxycyclohexyladipate  (Epoxide  289) 

3-(Epoxyethyl)-7-oxabicyolo[-;.1.0]heptane  (Epoxide  206)—- 

o-Ethoxybenzoic  acid 

6-Ethoxy-2-ben20thlazolethlol 

4-Ethoxy-3-methoxybenzaldehyde 

l-(4-Ethoxy-3-methoxybenzyl)-6,7-dimethoxy-3- 
methyllsoquinoline . 

(i-Ethoxy-S-methoxyphenyl) acetic  acid 

2-Ethoxy-l-naphthaldehyde 

2-Ethoxynaphthalene 

2-Ethoxy-l-naphtholc  acid 

2-Ethoxy-l-naphthoyl  chloride 

4-Ethoxy-o-phenylenedlanilne 

(p-Ethoxyphenyl)urea  (Dulcin) 

3-(Ethylaiiiino)  -p-cresol 

3-(Ethylamlno)-p-toluenesulfonlc  acid  [S03H=l] 

»N-Ethylanlllne,   refined 


OAF. 

EK,   SEL. 

AAP,   ACY,   SDC. 

GAF,    NAC,   SDC. 

AAP,    ICC,    ICI,   TRC. 

TRC. 

DUP. 

DUP,    NAC. 

EK,   TRC. 

GAM,  SAL,   SDH. 

EK. 

DUP,  MAY. 

AAP. 

RH. 

DUP. 

DUP. 

TRC. 

TRC. 

AAP,    NAC,  SDC,   X. 

EK. 

EK. 

ACY,   DUP,   OAF,   GGY, 

DUP,    NAC,   RUC. 

DUP,   M3B. 

GAF. 

GAF. 

PAS. 


DUP,   GAF,    ICI,   VPC. 

AAP,   DUP,    ICC. 

EKT. 

AHA,   BPC. 

ACY,   DOW,   DUP,   ORO,   RUC. 

ICI. 

Lli. 


NAC,   SDH,   TRC. 


DOW, 
ARA. 
ARA. 


RFC. 


MEE. 

GAF,    ICI,    NAC,   TRC,   VPC. 


AIL, 

ICI. 

ICI. 

ICI. 

DOW,   FG,   KPP 

ACY. 


GAF,  ICIN,   UCC,   X. 

ICC. 

UCC. 

UCC. 

ACY. 

ARA,   DUP. 

UL. 

LIL. 

LIL. 

ICO. 

ICO. 

ICO. 

ICO,   OPC,    TBK. 

TRC. 

fiSA. 

DUP. 

DUP. 

ACY,   DUP,   NAC,  SDH. 


CYCLIC  INTERMEDIATES 


TABLE  IB.—Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i966— Continued 


Manufacturers '   identification  codes 
(according  to  list  in  table  22) 


2-(N-Ethylanilino)ethanol 

[2-(N-Ethylanilino) ethyl] trimethylammonium  chloride 

3-(N-Ethylanilino)propionitrile 

a-(N-Ethylanilino) -m-toluenesulfonic  acid 

a-(N-Ethylanilino)-p-toluenesulfonic   acid 

N-Ethyl-p-anisidine 

N-Ethylanthranilic  acid 

2-Ethylanthraquinone 

»Ethylbenzene 

o-(p-Ethylbenzoyl) benzoic  acid 

Ethylbenzyl  chloride 

9-Ethylcarbazole 

N-Ethyl-1-oyclohexen-l-ylamine 

N-Ethylcyolohexylamine 

3,3'-Ethylenedioxydiphenol 

Ethylenlmine 

3-Ethyl-2-[3-(3-ethyl-2-benzothiazolinylidene)- 
pentadienyl]  benzothiazollum  iodide. 

l,l'-Ethylidine-di-2-pyTrolidinone 

2-[N-Ethyl-p-[(6-methoxy-2-benzo-thiazolyl)azo]- 
anilino] ethanol. 

N-Ethyl-1-naphthylamine 

9-Ethyl-3-nitrocarbazole 

a-Ethyl-3-nitrociunamic  acid 

p-Ethylphenol 

»N-Ethyl-N-phenylbenzylamine 

Ethylphenylmalonic  acid,   diethyl  eeter 

l-(o-Ethylphenyl)-3-methyl-2-pyrazolin-5-one 

5-Ethyl-2-picoline   (2-Methyl-5-ethylpyridlne)    (MEP) 

l-Ethylpiperldine — 

2-Ethylpyridine 

N-Ethyl-5-sulfoanthranilio  acid 

6-Ethyl-l,2,3,';-tetrahydro-l,l,4,<;-tetramethylnaphthalene- 

N-Ethyl-m-toluidine 

N-Ethyl-o-toluidine 

3-(N-Ethyl-m-toluidino)propionitrile 

1-Ethynyl-l-cyclohexanol 

Fluoren-9-one 

Fluorescein  (3  ',6'-Dihydroxyf luoran) 

l-Fluoro-2,'i-dinitroben2ene 

o-Fluorotoluene 

•i-Fomyl-m-benzenedisulfonic  acid 

o-Fonnylbenzenesulfonlo  acid   (o-Sulfobenzaldehyde) 

Fur  an 

Furfuryl  alcohol 

Furfurylamine 

N-Glycoloylarsanillc  acid,  sodium  salt 

Hexachlorobenzene 

Hexachlorocyclopentadiene 

l,'i,5,6,7,7-Hexachloro-5-norbomene-2,3-dicarboxyliC  acid- 

Hexadecachlorophthalocyanlne 

Hexaf luorobenzene 

Hexa(2-inethyl-l-aziridinyl)-l,3,5-phosphotriazine 

Hippuric  acid 

p-Hydrazinobenzenesulfonic  acid 

3-J^drazino-5-nitro-p-toluenesulfonic  acid    [SOjH'l] 

Hydrindantin 

»Hydroquinone,  tech 

-i'-Hydroxyaoetanllide 

3'-Hydroxyacetophenone 

3'-Hydroxyacetophenone  benzoate 

p-Hydroxybenzaldehyde 

«p-Hydroxybenzenesulfonlc   acid 

2-Jfcnaroxy-llH-benzo[a]carbazole-3-carboxylic  acid 

p-}^roxybenzoic  acid 

p-Hydroxybenzoio  acid,   butyl  ester-'- 

p-Hydroxybenzoic  acid,   ethyl  ester-"- 

p-l^droxybenzoic  acid,  n-heptyl  ester 


EKT. 


DUP, 

DUP. 

EKT. 

GAF,  SDH. 

NAC,  TRC,  WJ. 

EKT. 

SDH. 

NAC. 

CSD,  DOW,  ENJ,  FG,  KPP,  KPT,  MON,  SHC,  SIN,  SKC,  SNT, 

TOG,  UCC. 
NAC. 
BPG. 
ICC. 
UCC,  X. 
ABB. 
IDC. 
DOW. 
GAF. 


DUP. 

ICC. 

SDW. 

ACY. 

DUP,  NAC,  SDH. 

BPC,  MAL. 

TRC. 

UCC. 

RIL. 

RIL. 

SDH. 

GIV. 

DUP,  NAC. 

DUP. 

DUP,  GAF. 

cue,  NAC. 

EK. 

ICC. 

EK,  PIC. 

EK. 

GAF,  SDH. 

GAF,  SDH,  VPC. 

DUP,  OKO. 

QKO. 

MLS. 

SDW. 

DVC. 

HK,  VEL. 

HK,  VEL. 

ICC. 

WHC. 

ICO. 

BPC. 

OAF,  WJ. 

STG. 

HEX. 

CHS,  EKT,  MAN. 

TRC. 

SDH. 

SDH. 

DOW. 

DOW,  MDN,  UPF. 

GAF. 

HN,  WSN. 

HN,  WSN. 

HN,  WSN. 

WSN. 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 — Continued 


Manufacturers '   identification  codes 
(according  to  list  in  table  22) 


■»p-Hydroxybenzoic   acid,  methyl  ester 

»p-Hydroxybenzoic  acid,   propyl  ester-'- 

6'-Hydroxy-in-benzotoluidide 

3'-Hydroxy-2(N-benzyl-N-methylamino)acetophenone 

<i-HydroxycouBiarin 

13b -Hyd roxy -2 , 8 -d  ime thy Inaphtho  [  3 . 2 . 1 -k  1]  xanthen - 

9(13bH)one. 

'i'-(2-i:ydroxyethoxy)acetanilide 

m-Hydroxyethoxyphenol 

3.[N-(2-Hydroxyethyl)anilino]  proplonitrlle 

3.[N-(2-Hydroxyethyl)anllino]propionitrile,   benzoate 

ester. 

N-|3-Hydroxyethyl-2,'i-dihydroxybenzamde 

3-Hydroxy-N-(2-hydroxyethyl)-2-naphthajnide 

N-[ 7-Hydroxy-8- [2-hydroxy-5-(methylsulf amoylphenyl) azo] - 

1-naphthyl]  acetainide. 
6'-Hydroxy-5'-  [(2-hydroxy-5-nitrophenyl)azo]  - 

m-acetotoluidide. 
N-[7-Hydroxy-8-[(2-hydroJcy-5-nitrophenyl)azo]-l- 

naphthyl]  acetamide. 
7-Hydroxy-8-[['i'-[(p-hydroxyphenyl)azo]^-biphenylyl]azo]  - 

1,3-naphthalenedisulfonic  acid. 
7-Hydroxy-8-n  4 '-[  (p-hydroxyphenyl)  azo]  -3,3-diinethyl^- 

blphenylyljazo] -1,3-naphthalenedisulfonic   acid. 

A-Hydroxy-N^-isopropylmetanilamide 

2-Hydroxy-a^,a^-mesitylenediol 

-»4-Hydroxymetanilamlde 

"^-Hydroxymetanilanilide 

»4-Hydroxymetanillc   acid 

N-(/i-Hydroxymetanilyl)anthranilic   acid 

4-Hydroxy-l-methylcarbostyril 

3-Hydroxy-2-methylcinchoninic  acid 

4-Hydroxy-N^-methylnietanllamide 

N-(Hydroxymethyl)phthalamide 

3 -Hydroxy -N-(3-N-morpholinopropyl)  -2-naphthaiidde 

2-hfydroxy-l-naphthaldehyde 

»3-Hydroxy-2,7-naphthalenedlsulfonio  acid,  disodium  salt— 

7-Hydroxy-l,3-naphthalenedisulfonic  acid 

7-Hydroxy-l,3-naphthalenedlsulfonic  acid,   dipotassium 

salt. 
7-Hydroxy-l,3-naphthalenedisulfonic  acid,   disodium  salt— ■ 

4-Hydroxy-2-naphthalenesulfonamide 

l-Hydroxy-2-naphthalenesulfonic  acid,   potassium  salt 

<i-Hydroxy-l-naphthalenesulfonlc   acid 

5-Hydroxy-l-naphthalenesulfonic   acid 

♦6-Hydroxy-2-naphthalenesulfonlc  acid 

»6-f^droxy-2-naphthaleneBulfonlc   acid,   sodium  salt 

7-Hydroxy-2-naphthalenesulfonic   acid   (Cassella's  acid) 

8-Hydroxy-l-naphthalenesulfonic   acid 

8->tydroxy-l-naphthalenesulfonic   acid,Y-sultone 

3-Hydroxy-2-naphthanlUde   (Naphthol  AS) 

l-Hydroxy -2 -naphthoic   acid 

3-Hydroxy-2-naphtholc   acid   (B.O.N.) 

3-Hydroxy-2 -naphthoic  acid,  methyl  ester 

»3-Hydroxy-2-naphtho-o-toluidide 

N-(2-Hydroxy-l-naphthyl) acetamide 

*N-(7-I^droxy-l-naphthyl)acetajiiide 

l-( 2-Hydroxy-l-naphtl^lazo) -6-nitro-2-naphthol-4-sulf onic 

acid. 

N-(7-}fydroxy-l-naphthyl)benz amide 

3  '-  [(7-Hydroxy-l-naphthyl)carbei!ioyl]  acetanillde 

4-Hydroxy-7-[p-(p-nltrobenzamldo)benzamido] -2-naphthalene- 

sulfonic  acid. 
';-Hydroxy-7-(p-nltrobenzamido)-2-naphthalenesulfonlc  acid- 

2-Hydroxy-5-nitrometanilic   acid 

3-Hydroxy-4-( phenylazo) -2 -naphthoic  acid 

llx -Hydroxyprogesterone 

A-Hydroxypropiophenone 

a,  a'-[(a-Hydroxy-p-sulfobenzylidene)bi6[  (3-methyl- 

p-phenylene)(ethyllmlno)]]  di-m-toluenesulfonlc  acid. 

See  footnotes  at  end  of  table. 


HN,    ICO,   LEM,   SEL,   WSN. 
HN,    ICO,    LEM,   WSN. 

TRC. 
SDW. 
ABB. 

wm. 


TRC. 

ACY. 

CM3, 

DUP, 

NAC, 

TRC,   VPC 

TRO. 

CWN, 

DUP, 

NAC, 

TRC. 

TRC. 

ICC. 

DUP. 

TRC. 

ACY. 

IDC. 

ICO. 

ACY, 

GAF, 

NAC, 

TRC,   WJ. 

DUP, 

TRC. 

OAF. 

ACY, 

NAC. 

GAF. 

EK. 

DUP, 

NAC. 

NAC, 

TRC. 

NAC, 

SNA, 

IMS. 

ACY, 

TRC, 

WJ. 

DUP. 

GAF, 

VPC. 

ACY, 

TRC. 

ATL, 

BUC, 

PCW. 

NAC. 

AUG, 

DUP, 

HN, 

PCW. 

PCW. 

ATL, 

BUC, 

PCW. 

ACY. 

CM3, 

GAF, 

TRC. 

TRC. 

TRC. 

TRC. 

DUP. 

DUP, 

GAF. 

TRC. 

ICC. 

UP  J. 

MLS. 

TRC. 

CYCLIC  INTERMEDIATES 


TABLE  7B.  — Cyclic  iTitermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966—  Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


2-Hydroxy-4-sulfo-l-naphthalenediazoniujn  hydroxide,   inner 
salt. 

5-Hydroxy-m-toluenesulfonic  acid : 

l-Hydroxy-4-p-toluidinoanthraquinone 

2-Imidazolidinone  modifications 

»l,l'-Iinlnobls 

l,l'-Iminobis 

l,l'-Iminobls 
»7,7'-Imi nobis 
»l,l'-Iniinobis 


-aminoanthraquinone] 

-benzamidoanthraquinone] 

S-benzamidoanthraquinone] 

-hydroxy-2-naphthalenesulfonic  acid] 

-nitroanthraquinone] 

*l,l'-Iminodianthraquinone  (l,l'-Dianthrimlde) 

1,3-Indandione 

1,2,3-Indantrione  monohydrate  (Ninhydrin) 

Indole -3 -acetic  acid 

Indole-2,3-dione 

5-Iodoanthranllic  acid 

1-Iodonaphthalene 

Isobutylbenzene 

»Isocyanlc  acid  derivatives: 

Bitolylene  diisocyanate  (TODI) 

Cyclohexyl  isocyanate 

Dianisldine  diisocyanate  (DADI) 

3,4-Dichlorophenyl  ester 

•»Diphenylinethane  "ij'l'-diisocyanate  (MDI) 

p-Nitrophenyl  ester 

Phenylisocyanate 

Polyisocyanates  (complex) 

Polymethylene  polypheny lisocyanate 

Toluene  2,<i-dlisocyanate 

Toluene  2,4-  and  2,6-diisocyanate  (65/35  mixture) 

»Toluene  2,4-  and  2,6-diisocyanate  (80/20  mixture) 

p-Tolyl  ester 

Isonicotinic  acid,  methyl  ester 

Isonicotinonitrile 

Isooctylphenol 

Isophthalic  acid  (Benzene-l,3-dicarboxylic  acid) 

Isophthalic  acid,  diallyl  ester 

Isophthalic  acid,  dimethyl  ester 

Isophthalic  acid,  diphenyl  ester 

N-Isopropylaniline 

Isopropylbenzyl  chloride 

4,4'-Isopropylldenebis[2,6-dibromophenol]  (Tetrabromo- 

bisphenol  A) . 
4.,4'-Isopropylidenebis[2,6-dichlorophenol]  (Tetra- 
chlorobisphenol  A) . 

5,5'-Isopropylldenebis(2-hydroxy-m-xylene-a, a'-diol) 

»4,4'-Isopropylidenediphenol  (Bisphenol  A) 

4,4'-IsopropyHdenedlphenol,  ethoxylated 

4,4'-Isopropylldenediphenol,   propoxylated 

o-Isopropylphenol 

4-Isopropyl-m-phenylenediamine 

Isothiocyanic  acid,   phenyl  ester 

«Isoviolanthrone   (Isodibenzanthrone) 

»Leuco  quinizarin  (1,4,9,10-Anthratetrol) 

*2,'i-Lutidlne 

3,4-Lutldine— 

D-Iyserglc  acid 

Malondianilide 

Mandelonitrile 

«Melamine 

»dl-p-Mentha-l,8-diene  (Limonene) 

p-Mentha-l,4(8) -dlene 

»o-Meroaptobenzoic  acid  (Thiosalicylic  acid) 

Metanllamlde 

Metanllanilide 

Metanilic  acid  (m-Aminobenzenesulfonic  acid) 

l-Methoxyanthraquinone 

4-Methoxymetanlllc  acid 

4' -Methoxy-2-(p-methoxyphenyl)acetophenone 

4-Methoxy-N-methylnaphthalimlde 

N-(2-Methoxy-l-naphthyl)acetamide 

6-Methoxy-8-nitroquinoline 


RH. 

ACY,    CMG, 

DUP 

GAF 

ICI 

MAY,    NAC,    TRC 

ACY,   MAY 

GAF,    ICI, 

TRC. 

C^G,    DUP, 

NAC 

TRC. 

ACY,    DUP, 

ICI, 

MAY 

TRC 

ACY,    DUP, 

GAF 

ICI 

MAY 

NAC,    TRC. 

PIC. 

HEX. 

SDW. 

NAC. 

SDW. 

EK. 

PLC. 

UP  J. 

CWN,    OTC. 

CWN,    UPJ. 

DUP. 

DUP,   MOB, 

NAC 

UPJ. 

EK. 

MOB. 

MOB. 

KAI,   MOB, 

UPJ. 

DUP,   MOB. 

DUP,   ICIB. 

DUP,   MOB, 

NAC, 

OMC, 

RUC 

ucc. 

EK. 

RIL. 

RIL. 

PRD. 

ACC,   SOC. 

FMP. 

MTR. 

BJL. 

ACY,    EKT. 

BPC. 

DOW. 

DVC. 

ARK. 

DOW,   MON, 

SHC, 

UCP. 

APD. 

APD. 

TNA. 

DUP. 

TNC. 

ACY,   DUP, 

GAF, 

ICI, 

MAY. 

ACY,   BL, 

5KT, 

•ISH, 

ICC, 

NAC,    TRC. 

AC?,    CFC, 

KPT, 

RIL. 

RIL. 

LIL. 

KF. 

KF. 

ACP,   ACY, 

FIS, 

RCI. 

ARZ,    GIV, 

HNW, 

HPC. 

GIV. 

F/N,    LIL, 

MED. 

CKD,   VPC. 

GAF. 

DUP,    TRC. 

A.y,   GAF. 

CIiCl,   GAF. 

CTN. 

TRC. 

TRC. 

SDW. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  IB.— Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i566~Contlnued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


(p-ftethoxyphenyl) acetic  acid 

'i'-Methoxypropiophenone 

6-lfethoxy-tetralone 

»l-(Methylamlno)anthraquinone 

l-(Methylamino)-A-p-toluldinoanthraquinone- 

N-Methylanlline 

3-(N-Methylanilino)propionitrile 

5-Methyl-o-anisidine   [NH2=1] 

m-Methylanisole 

N-Jtethylanthranilic   acid — 

2-»fethylanthraqulnone 

3-Methylbenzo[f ]quinoline 

2-Mett^rlbenzothiazole 

N-Methylbenzylamine 

Methyl  benzyl  ether 

5 -( 1-Me thy Ibutyl) barbituric  acid 

3-Methylcholanthrene 

Methylcyclohexane 

Methylcyclohexenecarboxaldehyde 

4-Methyl-a,a-dlphenyl-l-piperazineethanol, 
chloride. 

N-Methyleneaniline 

-4, 'i'-Methylenebis[2-chloro  aniline" 


-MethyleneblsfN.N-dimethylanllineJ    (Methane  base) - 
4,4 '-Methylenebis[N,N-dimethyl-3-nitroani line] 
2,2'-l*thylenebis(6-nonyl-p-cresol)- 
5,5'-Methylenebis[toluene-2,4-diaiiiine]  ■ 
«4 ,4 ' -Methylenediani line - 

5,5'-ltethylenedisalicylic  acid - 

5-Kfethylene-2-norbomene 

N-Methylformanilide 

2-ktetlyrlfuran 

Methylhydroquinone 

2-Methylindole-3-carboxaldehyde 

6 -Methyl -2-( 2 -methyl-6-quinolyl) -y-benzothiazolesuOf onic 

acid. 

Methylnaphthalene,   crude 

1-Me  thy Inaphthalene 

N-Methyl-4'-nitroacetanilide 

N-Methyl-p-nitro  aniline 

4-Jfethyl-2-nitroanisole- 

2-Methyl-l-nitroanthraquinone 

2-Methyl-5-nitroimidazole— — — 

N-Methyl-N-nltroso-p-toluenesulfonamlde 

2-Methyl-5-norbornene-2,3-dicarboxylic  anhydride 

Methylnorbomene-2,3-dicarboxylic  anhydride,   isomers 

4-Methyl-7-oxabicyclo[4.1.0]heptane-3-carboxylic  acid, 

(4-methyl-7-oxabicyclo[<;.1.0]  hept-3-yl) -methyl  ester 

(Epoxide  201). 
3'-Methyl-5-  [(7-oxo-7H-benz[de]anthraoen-3-yl)-amino]  - 

1,2 '-iminodianthraquinone . 

»m-(  3-Kfethyl-5 -oxo-2-pyrazolin-l-yl) benzenesulf onamide 

m-(3-Jtethyl-5-oxo-2-pyrazolin-l-yl)ben2enesulfonic  acid 

•p-(3-Methyl-5-oxo-2-pyTazolin-l-yl) benzenesulf onic  acid 

3-(3-Methy 1-5-0X0-2 -pyrazolin-1-yl) -1,5-naphthalene- 

disulfonic  acid. 
6-(3-MBthyl-5-oxo-2-pyrazolin-l-yl)-l,3-naphthalene- 

disulfonic  acid. 
•4-( 3-Methyl-5-oxo-2-pyrazolin-l-yl) -m-toluenesulf onic 

acid    [SOjH^l]. 

2-Methyl-5-phenylbenzoxazole 

l-Methyl-2-phenylindole 

l-Methyl-2-phenylindole-3-carboxaldehyde 

l-Methyl-4-phenylisonlpecotic  acid 

5 -Methyl -3-phenyl-4-isoxazolecarboxy lie  acid 

5-Methyl-3-phenyl-4-isoxazolecarboxylic  acid  hydro- 
chloride. 

»3-Methyl-l-phenyl-2-pyrazolin-5-one  (Developer  Z) 

ktethyl  phenyl  sulfide  (Thioanisole) 

1-Methylpiperazine 

4-Methyl-l-piperazineacetic   acid,  methyl  ester 


CTN,    TBK. 

LIL. 

GAM. 

AAP,   ACY, 

DUP, 

GAF,    ICI,    NAC,   UCC 

GAF,    ICI. 

ACY,   DUP. 

DUP. 

DUP,   SDC. 

GIV. 

GIV,    ICC. 

ACY,   NAC. 

ACY,   DUP, 

GAF. 

FMT. 

ICO,   MIS, 

SDW. 

UCC. 

LIL. 

EK. 

DOW,   PLC. 

UCC. 

ABB. 

DUP. 

DUP. 

ACY,   GAF, 

SDH. 

ACY,   DSC, 

DUP, 

GAF,    NAC,   SDH,   X. 

GAF. 

ACY. 

DUP. 

DOW,   DUP, 

NAC. 

HN. 

DOW. 

MLS. 

QKO. 

EKT. 

GAF. 

DUP. 

KPT. 

HMY. 

GAF,    NAC. 

GAF. 

DUP. 

DUP,   GAF, 

ICI 

NAC. 

RDA. 

ALD,   EK. 

VEL. 

NAC. 

UCC. 

DUP. 

CXC,    TRC,   VPC. 

GAF,    TRC,   VPC. 

AAP,   ACY,   cm,   DUP,   GAF,    TRC,   VPC. 

TRC. 

TRC. 

CVC,   TRC,   VPC. 


GAF. 
GAF. 
SDW. 
ICO. 
ICO. 


ACY,   DOW,    DUP,    NAC,   SDC,   SDH,   SDW,   VPC. 

PIT. 

UCC. 

ABB. 


CYCLIC  INTERMEDIATES 


85 


TABLE  TB.— Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  2966— Continued 


Manufacturers'    Identification  codes 
(according  to  list  in  table  22) 


2-Methyl-l-piperldlnepropanol 

3-Methyl-2-pyrazolin-5-one 

l-Methylpyrrole 

»a-Methylstyrene 

2-(Msthylsulfonyl)^-nltro  aniline 

Methyl  2-thienyl  ketone 

4-(Methylthlo)-iii-cresol 

3-Methylthlophene 

p-(Msthylthio)  phenol - 

6'-Methyl-<i'-p-toluenesulfonaiiiido-m-benzanisldlde 

3-MBthyl-6-p-toluidlno-7H-dlbenz[f ,ij] Isoquinollne- 
2,7(3H)-dione. 

3-Methyl-l-m-tolyl-2-pyrazolin-5-one 

3-Methyl-l-p-tolyl-2-pyrazolin-5-one 

1-Naphthaldehyde - - — 

♦Naphthalene ,  solidifying  at  79"^'  C.  or  above  (refined 
flake)  (from  domestic  crude). 

1,5-Naphthalenediol  (1,5-Dihydroxynaphthalene) 

l,5-Naphthalenedi8ulfonic  acid 

•2,7-Naphthalenedisulfonic  acid 

1-Naphthalenesulfonlc  acid 

l-Naphthalenesulf onlc  acid,  sodium  salt 

2-Naphthalenesulfonic  acid 

2-Naphthalenesulfonlc  acid,  sodium  salt 

2-Naphthalenesulfonyl  chloride 

*l,4,5,8-Naphthalenetetracarboxylic  acid 

1,3,6-Naphthalenetrlsulfonic  acid 

Naphthallc  anhydride 

Naphthalimide 

2H-Naphth[l,8-od] isothiazole-3,5-disulfonlo  acid, 

1,1-dloxlde,  trlsodium  salt. 
1-Naphthoic  acid 

»l-Naphthol  (:<-Naphthol) 

2-Naphthol,   tech.    (p-Naphthol) ^ 

p-Naphtholbenzein 

1,4-Naphthoqulnone 

"Naphthostyril 

»Napth[l,2-d][l,2,3]oxadlazole-5-sulfonic  acid 

1-Naphthylamlne   (c-Naphthylamine) 

2-Naphthylamlne   ( p-Naphthylamine) 

p-(2-Naphthylamino) phenol  (N-(p-Hydroxyphenol) -2- 
naphthylamine) . 

2-(Naphthylthio) acetic   acid 

Niootinonitrile   (3-Cyanopyridine) 

Nitro-aoeanthra[2,l-a]  aoeanthrylene-5,13-dlone 

3'-NltroaoetanlUde 

4'-Nltroacetanillde 

2'-Nltro-p-acetanisidide 

3'-Nltro-p-aoetanisidide 

-i'-Nltro-o-acetanisidide 

2'-Nitro-p-aoetophenetidide 

3'-Nitroaoetophenone 

5'-Nltro-o-acetotoluidlde 

m-Nitro aniline 

o-Nltro aniline 

«p-Nitro aniline 

2-(o-Nltroanilino)ethanol 

2-Nitro-p-anlsidine   [NHj^I] 

A-Nltro-o-anisldine   [NH2=l] - 

»5-Nltro-o-anlsidine   [NHj'll ■ 

o-Nitroanisole 

p-Nitroanlsole 

'V-Nltroanthranilic  acid 

5-Nitroanthranllic  acid 

l-Nitroanthraqulnone 

2-(4-Nitro-2-aiithraqulnonyl)  anthra[  2,3-d] -oxazole- 
5,10-dione. 

m-Nitrobenzaldehyde 

3'-Nitrobenzanlllde 

-i'-Nitrobenzanilide 

See  footnotes  at  end  of  table. 


LIL. 

DUP. 

DUP. 

ACP,   CLK, 

DOW,    HPC,   SKO 

EKT,    TRC. 

SDW. 

CRZ. 

SDW. 

CRZ. 

GAF,    NAC. 

GAF,    ICI. 

DUP. 

VPC. 

COK. 

KPT,    NAC, 

RIL. 

NAC. 

GAF,    NAC. 

DUP,    NAC, 

SDH. 

TRC. 

■mc. 

ACY,    NAC. 

ACY. 

DUP,   GAF. 

GAF,   HST, 

TRC. 

GAF. 

DUP. 

DUP,   GAF, 

NAC. 

DUP. 

COK. 

DUP,   NAC, 

ucc. 

ACY,    NAC, 

SW,   X. 

EK. 

EKT. 

DUP,    GAF, 

NAC. 

CM3,   GAF, 

NAC,    TRC,   VPC 

DUP,    NAC. 

X. 

NAC. 

ACY,   GAF, 

VPC. 

NEP,   RIL. 

ICI. 

GAF,    IHC. 

GAF,    TRC. 

DUP,  SDH. 

GAF. 

DUP. 

AAP. 

SDH. 

DUP. 

ACY,   X. 

AAP,   MDN. 

AAP,   MON, 

SDC,  \jm. 

AAP,   MED. 

DUP,   SDH. 

AAP,   DUP, 

SDH. 

ACY,   ALL, 

BUC,   DUP. 

DUP,  MDN. 

DUP. 

DUP. 

TRC. 

ACY,  MAY. 

GAF,    NAC. 

NAC,   SDH. 

DUP. 

GAF. 

SYNTHETIC  ORGANIC  CHEMICALS  1966 


TABLE  IB. --Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  966- -Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


♦Nitrobenzene 

3  '-Nitrobenzenesulfonanilide 

»m-Nitrobenzenesulfonic  acid 

om-Nitrobenzenesulfonic  acid,   sodium  salt 

m-Nitrobenzenesulfonyl  chloride 

p-Nitrobenzenesulfonyl  chloride 

5-Nitro-2-benzimidazolinone 

m-Nitrobenzoic   acid 

m-Nitrobenzoic   acid,   sodium  salt 

p-Nitrobenzolc  acid 

6-Nitro-2-benzoxazolinone 

2-(m-Nitrobenzoyl)-o-acetanisidide 

m-Nitrobenzoyl  chloride 

p-Nitrobenzoyl  chloride 

p-Nitrobenzyl  alcohol 

4'-Nitro-<;-biphenylcarboxylic  acid 

2-Nitro-p-cresol 

Nitrocyclohexane 

Nitrodiphenylamine 

5-Nitro-2-furaldehydesemioxamazone 

5-Nitro-2-furanmethanediol,   diacetate 

5-Nitroisophthalic   acid 

1-Nitronaphthalene 

3-Nitro-l,5-naphthalenedisulfonic  acid 

4-Nltronaphthalic   anhydride 

»7(and   8) -Nitronaphth[l,2-d]  [1,2,3]  oxadiazole-5-sulfonic 
acid. 

■i'-Nitrooxanilic  acid — 

o-Nitrophenol 

»p-Nitrophenol 

»p-Nitrophenol,   sodium  salt 

'i'-(p-Nitrophenyl)acetophenone 

4-[(p-Nitrophenyl)azo]-o-anisidine 

2-Nitro-p-phenylenediamine 

"i-Nitro-o-phenylenediamine 

(p-Nitrophenyl) hydrazine 

2,2'-(m-Nitrophenylimino)diethanol 

2,2'-(m-Nitrophenylimlno)dlethanol,  diacetate  ester 

2-(p-Nitrophenyl) -2H-naphtho[l,2-d]  triazole-6,8-disulfonlo 

acid. 
2-( p-Nitrophenyl) -l-octadecyl-5-benzimidazolesulfonio 
acid. 

l-(m-Nitrophenyl) -5-oxo-2-pyTazoline-3-carboxylic  acid 

3-Nitrophthalio  acid 

3-Nitrophthallc  anhydride 

4-Nitrophthalimide 

5-Nitrosalicylaldehyde 

3(and  5) -NitrosalicyUc  acid— - 

p-Nitrosophenol 

P -Nitrostyrene 

4-Nitro-4'-(5-suli'o-2H-uaphthol  [1,2-d]  triazol-2-yl)-2,2'- 
stilbenedisulfonic  acid. 

m-Nitrotoluene 

o-Nitrotoluene 

p-Nitrotoluene 

Nitrotoluene  mixtures 

5-Nitro-o-toluenesulfonanilide 

p-Nitrotoluenesulfonlc  acid 

»3-Nitro-p-toluenesulfonic  acid    [SOjH^l] 

»5-Nitro-o-toluenesulfonic  acid    [sOjH^l] 

5-Nitro-o-toluenesulfonyl  chloride 

3-Nitro-p-toluic  acid,  methyl  ester 

»2-Nitro-p-toluidine    [nHj'I] 

4-Nitro-o-toluidine    [NHj'l] 

»5-Nitro-o-toluidine    [nH2=1] 

5-Nitro-2-p-toluidinobenzenesulfonic  acid 

3-Nltrotoluoyl  chloride 

*16-Nitroviolanthrone 

4-Nltro-m-xylene 

Nitroxylenes,   mixed 

Nonyl-dinonylphenol,  mixture 

•Nonylphenol 


DUP,   GAF,   MDN,    NAC,   RUC. 


DUP,    NAC. 
MDN,   MRA,   RBC. 


SDW. 
SDH,    WAY. 


ACY,   MDN. 

NOR. 

NOR. 

GAF,    GAM. 

DUP,    NAC. 

GAF,    NAC,    TRC. 

GAF,    NAC. 

GAF,    NAC,    TRC,   VPC. 

DUP. 

DUP. 

DUP,   KKN,   SDC,   UPM. 

MDN,    U™. 

DUP,   OAF. 

AAP. 

WAY. 

DUP,   FMT. 

EK. 

DUP. 


TRC. 


EK. 

DUP. 

EK. 

EK. 

ACY, 

DUP, 

NAC. 

CWN. 

TRC. 

DUP, 

NAC. 

DUP, 

NAC. 

DUP. 

NAC. 

DUP, 

NAC. 

GAF. 

GGY. 

AAP, 

cm, 

TRC. 

ACY, 

DUP, 

GAF, 

NAC, 

SDH,    TRC 

GAF. 

SDH. 

ACY, 

DUP, 

SW. 

GAF. 

BUG, 

DUP, 

PCW, 

SDH. 

TRC. 

X. 

ACY, 

ATL, 

GAF, 

ICI, 

MAY,    TRC 

DUP. 

NAC. 

.ICC. 

GAF, 

JCC, 

MDN, 

PHD, 

RH,   STP, 

CYCLIC  INTERMEDIATES 


-Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 — Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


5-Norbomene-2,3-dloarboxyllc   anhydride 

Octylphenol 

7-0xabicyclo[4.1.0]heptane   (Cyclohexene  oxide) 

Oxalacetic  acid,   diethyl  ester,   (p-sulfophenyl)hydrazone — 
Oxanllide 

»1-  [( 7-0x0 -7H-benz  [de]  anthracen-3-yl)aiidno]anthraqulnone 

»l,l'-[(7-0xo-7H-benz[de]  anthracen-3,9-ylene) - 
d iimlno ] d i anthraquinone . 

2-Oxocyclohexanecarboxylic  acid,   ethyl  ester 

»5-0xo-l-phenyl-2-pyrazollne-3-carboxyllc  acid,   ethyl 
ester. 
5-0xo-l-(p-sulfophenyl)-2-pyrazoline-3-carboxylic   acid 
(Pyrazolone  T) . 

5-0xo-l-(p-suli'otolyl)  -2-pyrazollne-3-carboxylic  acid 

iji'-Oxydianiline 

Penicillin,   N-ethylpiperidine  salt 

Pentachloronitrobenzene 

Pentylnaphthalenes   (Amylnaphthalenes) 

o-Pentylphenol  (o-Aniylphenol) 

p-tert-Pentylphenol 

3,4,9, lO-Perylenetetracarboxy lie   acid 

3,"i,9,10-Perylenetetracarboxylic  3,<;:9,10-diiiiiide 

Phenethylamine 

Phenethylamine  sulfate 

o-Phenethylbenzoic   acid 

o-Phenetidine 

p-Phenetidine 

Phenetole 

♦Phenol: 
♦Natural: 

»From  coal  tar: ^ 

39°  C,  m.p 

82?J-84* — 

All  other 

♦From  petroleum 

♦Synthetic : 

By  caustic  fusion:  U.S.P 

From  chlorobenzene  by  liquid-phase  hydrolysis:  U.S.P 

From  chlorobenzene  by  vapor-phase  hydrolysis:  U.S.P 

♦From  cumene  by  oxidation:  U.S.P 

PhenolsulXonaphthalein 

Phenolsulfonaphthaleln,  sodium  salt 

Phenothiazln-2-yl-l-propanone 

Phenoxyacetic  acid,  sodium  salt 

2-Phenoxypropanol 

2-Phenoxypropionlc  acid 

2-Phenoxypropionyl  chloride 

♦Phenylacetlc  acid  (a -Toluic  acid) 

Phenylacetlc  acid,  ethyl  ester,  tech 

Phenylacetlc  acid,  methyl  ester 

♦Phenylacetlc  acid,  potassium  salt 

♦Phenylacetlc  acid,  sodium  salt 

♦Phenylacetonitrlle  (a-Tolunitrile) 

ii'-Phenylaoetophenone 

Phenylacetyl  chloride 

2-Phenylanthra[2,3-d]oxazole-5,10-dione 

♦p-Phenylazoanillne  (C.I.  Solvent  Yellow  1)  and  hydro- 
chloride. 

A-(Phenylazo)(Jiphenylamlne 

4-(Phenylazo) -1-naphthylamlne 

4— (Phenylazo) -m-phenylenediamine  (C.I.   Basic  Orange  2) 

5-(Phenylazo) salicylic  acid 

l-Phenyl-l,3-butanedlone 

2-Phenylbutyric  acid 

a-Phenyl-o-cresol 

1-Phenylcyclopentanecarboxylic  acid 

1-Phenyldeoane   (Decylbenzene) 

N,N'-p-PhenylenebisIacetamlde] 

m-Phenylenedl amine 

o-Phenylenedl amine 

See  footnotes  at  end  of  table. 


TRC. 

WRN. 

ACY, 

DUP, 

GAF, 

ACY, 

DUP, 

GAF, 

ARA. 

GAF, 

SDW, 

VPC. 

ICI,  MAY,  TRC. 
ICI,  MAY,  TRC. 


AAP,  GAF,  ICI,  VPC. 


PAS. 

PAS. 

PAS. 

GAF,    NAC. 

DUP,   GAF, 

NAC. 

ms. 

MLS. 

LIL. 

M3N. 

DOW,   MON. 

RSA. 

KPT,   PRD. 

ACP,   KPT. 

ACP,    KPT. 

MER,    NPC, 

PIT, 

PRD, 

SW. 

MAL,   MON, 

RCT. 

DOW. 

HKD,    UCC. 

ACP,    CLK, 

HPC, 

MON, 

SHC, 

SKO,   SOC 

ICO. 

ICO. 

ICO, 

OPC. 

BPC, 

GIV, 

MAL, 

TBK 

BPC. 

BPC. 

BPC, 

OPC, 

TBK. 

BPC, 

OPC. 

BPC, 

OPC, 

SDW, 

TBK 

DUP, 

GAF. 

ICO. 

GAF. 

ACY, 

GAF, 

NAC. 

EK. 

DUP. 

DUP. 

TRC. 

EK. 
BPC. 
RBC. 
SK. 
NAC. 
ACY, 

GAF. 

ACY, 

DUP, 

NAC. 

DUP, 

FMT, 

MEE, 

THC. 

SYNTHETIC  ORGANIC  CHEMICALS.  1966 


-Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  J966— Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


*p-Phenylenediamine 

d-Phenylephrine  base 

dl-Phenylephrine  base 

2-Phenylethenesulfonic  acid,   sodium  salt  (p-Styrene- 
sulfonic   acid,   sodium  salt). 

Phenyl  ether  (Diphenyl  oxide) 

d-(-) -2-Phenylglyclne  and  derivatives 

d-(-)Phenylglycine,   N-carboxy  anhydride 

dl-2-Phenylglycine   (racemic) 

Phenylglycine,   sodium  salt 

d-(  -)Phenylglycyl  hydrochloride 

5-Phenylhydantoin 

Phenylhydrazine 

Phenylhydrazine  hydrochloride 

2,2'-[(Phenyl)imino]dlethanol  (N-Phenyldiethanolamlne) - 

3,3 '-[( Phenyl) imlnojdipropionltrile 

Phenylmagneslum  bromide 

Phenylmalonic  acid,  diethyl  ester 

o-Phenylphenol >- — 

o-Phenylphenol,   chlorinated 

o-Phenylphenol,   sodium  salt 

p-Phenylphenol 

N-Phenyl-p-phenylenediamine 

Phenylphosphinlc  acid 

Phenylphosphonlc  dlchloride 

Phenylphosphonothioic  dlchloride 

Phenylphosphonous  acid 

Phenylphosphonous  acid,   sodium  salt 

Phenylphosphorous  dlchloride 

•l-Phenyl-l,2-propaiiedlone,   2-oxime 

Phenyl-2-propanone 

N-3-Phenylpropyl-p-toluidine 

Phenyl  sulfone 

Phenylundecanoic   acid 

Phloroglucinol 

l(2H)-Phthalazinone - 

Phthallc  acid— 

Phthalic   acid,   diallyl  ester 

Phthalic  acid,   dlsodlum  salt 

»Phthallc  anhydride 


PhthaUde ~ - 

Phthalimlde 

Phthalimide,  potassium  salt 

1Phthalooyaninato(2-)]  copper ' 
Phthalocyanlnato(  2-)]  iron 

Phthalocyaninetetrasulfonyl  chloride,   copper  derivative - 
Phthaloyl  chloride  (Phthalyl  chloride) . 

•Picolines:^ 

»2-Piooline  (a-Picoline) 

3-Picoline  (P-Pioollne) 

■i-Picoline  (y  -Picollne) 

Picoline  (3,4-mixture) 

Plcollnlc  acid 

Plcollnonltrile  (2-Cyanopyrldine) 

3-Picolylamiue 

Picric  acid   (Trlnitrophenol) 

2-Pipeooline 

<i-Pipecollne 

Plperazlne  mixture,   crude-^ 

•Plperldine 

3-Piperldlnopropiophenone  hydrochloride 

Polyohlorobiphenyl 

Poly  (Methylenephenylene)   polyamine 

Primullne  base 

Prlmulinesulfonlo  acid 

lO-Propionylphenothleuslne 

•Propiophenone 

n-Propylbenzeue 

2-Propylpyridlne 

See  footnotes  at  end  of  table. 


ACY,  BFG,  SDC. 

SDW. 

SDW. 

SHL. 

DOW. 

KF. 

OTC. 

KF. 

NAC,  OTC. 

OTC. 

ABB,  X. 

DOW. 

EK,  VPC. 

EKT,  aAF. 

DUP. 

ARA. 

BPC. 

DOW,  RCI. 

DOW. 

DOW. 

DOW. 

DUP,  USR. 

SF. 

SF. 


SF. 

NEP,  ORT,  X. 

ORT,  SK. 

EK. 

NES. 

EK. 

MRT. 

KPT,  NAC,  X. 

EK,  KF,  MEE. 

FMP. 

TNC. 

ACP,  GRH,  HH,  KPS,  MON,  PCC,  PTO,  RCI,  SOC,  STP, 

THC,  UCC,  WTC. 
FMT,  NAC. 
DUP,  MEE,  NAC. 
EK,  SDW. 
ICC,  ICI. 
DUP. 

DUP,  TRC. 
M3N. 

ACP,  KPT,  RIL,  UCC. 

NEP,  RIL. 

RIL,  UCC. 

ACP,  KPT. 


RIL. 

NAC,  SDC,  X. 

LIL. 

RIL. 

JCC,  X. 

ABB,  DUP,  HK,  MRK,  RIL. 

ACY. 

MDN. 

KAI. 

DUP,  NAC. 

ATL. 

ABB. 

IIL,  OPC,  ORT,  TBK. 

EK. 

RIL. 


CYCLIC  INTERMEDIATES 


-Cyclic  iniermediatrs  jor  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


»8,16-PyTanthrenedione 

Pyridine,  refined:^ 
•2°   Pyridine 

Other  grades 

2-Pyridineethanol 

3-Pyridinemethanol 

Pyridine-n-oxide 

Pyridinlum  bromide  perbromide 

3-Pyridinol 

2(  LH)  -Pyridone 

2-Pyrlmidinol 

2-Pyrrolidinone 

3-(l-Pyrrolidinyl)propiophenone  hydrochloride 

lH-Pyrrolo[2, 3-6]  pyridine 

oQuinaldine 

Qulnoline : 

1°  and  2°  QuinoUne 

Other  grades 

2,<;-Quinolinediol - 

8-Quinolinol  (8-Hydroxyquinoline,   tech.) 

Qulnophthalone   ((Juinollne  yellow,   base) 

Resorclnol,   monoacetate  (nonmedicinal  grade)  ■"■ 

Resorcinol,   tech-"- 

p -Resorcylaldehyde 

P -Resorcylio  acid 

p-Resoroylic  acid,   lead  salt 

♦Salicylaldehyde 

•Salicylic  acid,   tech 

Salloyllo   acid,   ammonium  chromium  complex 

Salicylic  acid,   sodium  chromium  complex 

Salicylic   acid,   sodium  salt  (crude) 

Salicylic   acid,   strontium  salt,   tech 

Salicylideneaminoguanidine  oleate 

Sodium  phenoxide 

»Styrene,   all  grades 

5-Sulfamoylanthranilic  acid 

Sulfanllic  acid   (p-Aminobenzenesulfonic  acid)    and  salt- 
<;-Sulfoaiithranlllc  acid 

o-Sulfobenzolc  acid,   cyclic  anhydride 

a, a-  [(p-Sulfobenzylldene)bis[(3-methyl-p-phenylene) 
(ethylimino)]]  di-m-toluenesulfonlc  acid. 

5-Sulfoisophthallc  acid,  1,3-diiiiethyl  ester 

N,5'-SulfonyldianthraniUc  acid 

'i,<i^Sulfonyldiphenol  {^,A  '-Dihydroxydiphenylsulfone)  — 

»Terephthalio   acid 

Terephthallc  acid,   dihydrazide 

»TerephthaUc  acid,  dimethyl  ester 

Terphenyl  ( Phenylbiphenyl) 

l,2,'i,5-Tetraamlnoben2ene  tetrahydrochloride 

[A,A' ,A"  ,A"  '-Tetraaminophthalocyaninato(2-)]copper--- 
3',3",5',5"-Tetrabromophenolphthalein,  ethyl  ester— 

Tetrabromophthalie  anhydride 

TetrabroinD-8,16-pyranthrenedione 

1,3,6,8-Tetrabromopyrene 

•1,4,5,8-Tetrachloroanthraquinone 

1,2,4,5-Tetrachloroben2ene 

l,2,'i,5-Tetrachloro-3-nitrobenzene 

a, a,2,6-Tetrachloro toluene 

Tetrachloroviolanthrone 

Tetrahydrofuran 

Tetrahydro-2-methylfuran 

«l,'i,5,8-Tetrahydroxyanthraquinone,   leuco  derivative 

»1,4.,5,8-Tetrakis(  l-anthraqulnonylamlnD)  anthraqulnone 
(Pentanthrimlde). 

2-(l,l,3,3-Tetramethylbutyl)-p-cresol 

p-(l, 1,3, 3-Tetramethylbutyl) phenol 

N,N,N',N'-Tetramethyl-p-phenylenediamlne 

[-4,4'  ,4",-;  ' '  '-Tetranltrophthalocyaninato(2-) )  copper--- 
2-(2-Thenylami no) pyridine 

See  footnotes  at  end  of  table. 


cm,   ICI,   TRC. 


RIL. 

EK,   RIL. 

RIL. 

AHA. 

NEP. 

FMT. 

GGY. 

GAF. 

LIL. 

SDW. 

ACY,   DUP,    NAC. 

ACP,   KPT. 

EK,  FMT. 

DUP. 

GAM. 

NAC. 

AAP. 

KPT,   UPF. 

OAF. 

ACY,   KPT. 

ACY. 

DOW,   HN,   MTR,   RDA. 

CFC,    DOW,    HN,   MON, 

TRC. 

TRC. 

DOW. 

TNC. 

DUP. 


ACC,   CSD,   DOW,    ELP,   FG,   KPP,   MCB,   MON,   SHC,   SKC,   SNT, 
UCC. 


TRC. 

GAF, 

M3N, 

UPF. 

ACC, 

DUP, 

EKT. 

DUP. 

ACC, 

DUP, 

EKT, 

HPC 

JON. 

BJL. 

DUP. 

EK. 

MCH. 

GAF, 

NAC, 

TRC. 

GAF. 

DUP, 

GAF, 

ICI, 

NAC 

DOW, 

DVC, 

HK. 

SDH. 

DUP. 

GAF, 

ICI. 

DUP, 

QKO. 

DUP, 

OJCO. 

GAF, 

ICC, 

NAC, 

TRC 

GAF, 

ICI, 

NAC. 

ACY. 

GAF. 

EK. 

DUP. 

ABB. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  IB. --Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  966— Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


3,3'-Thiobisr7H-benz[de]anthraoen-7-one] 

l,l'-Thlobis(2-naphthol) — 

»'i,'i'-Thiodianiline 

6,6'-Thiodimetanilic   acid 

Thiopheneaoetic  acid 

2-Thiopheneacetyl  chloride 

2-Thiophenecarboxaldehyde 

eym-Thymol 

■»Toluene-2,<i -diamine   (^-m-Tolylenedlamine) 

Toluene -2, 5-diaiiiine 

Toluene -2, 5 -diamine  sulfate 

Toluene-2,'i-disulfonic  acid 

o-Toluenesulfonamide 

p-Toluenesulfonamide 

«o(and  p) -Toluenesulf onic  acid 

p-Toluenesulfonic  acid 

Toluenesulfonio  acid,   aniline  salt 

p-Toluenesulfonic  acid,   2-chloroethyl  ester 

p-Toluenesulfonic   acid,   ethyl  ester 

p-Toluenesulfonlc  acid,  methyl  ester 

p-Toluenesulfonlc  acid  monohydrate 

p-Toluenesulf onyl  chloride 

m-Toluic  acid— 

o-Toluic  acid 

p-Toluic  acid 

m-Toluidine 

o-Toluidlne 

o-Toluidine  hydrochloride 

p-Toluidlne 

p-Toluidine  hydrochloride 

Toluidines,  mixed 

m-Toluidinomethanesulfonic  acid 

o-Toluidinomethanesulfonic  acid 

8-p-Toluidino-l-naphthalenesulf onl c  acid 

»o-(p-Toluoyl) benzoic  acid 

N-(p-Tolylazo)sarcosine 

»4.(o-Tolylazo)-o-toluidine   (C.I.   Solvent  Yellow  3) 

<i-(o-Tolylazo)  -o-toluidine  hydrochloride 

1-p-Tolyldodecane 

2,2'-(m-Tolylimino)diethanol 

p-Tolylmercuric  chloride 

N,N,N-Tribenzylamine 

l,2,3(and  1,2,4) -Trichlorobenzene 

1,2,4-Trichlorobenzene 

N,2,6-Trichloro-p-benzoquinoneimine 

1, 2, A-Trichloro-S -nitrobenzene 

Trichlorophenylsilane 

a,a,ci-Trlchlorotoluene  ( Benzotrichloride) 

01,2,'4-Trichlorotoluene 

o,2,'i(and  a  ,2,6)-Trichlorotoluene 

ajSj-l-Trichlorotoluene 

2,4,6-Trlchloro-s-triazine  (Cyanurio  chloride) 

1,3,5-Triethylbenzene 

2-(  Trif  luoromethyl)  phenothiazine 

a,a,a-Trifluoro-A-nitro-m-creBol 

a,a,a-Trifluoro-m-nitrotoluene 

a,a,a-Trif luoro-N-phenyl-m-toluidlne   (3-( Trif luoro- 
methyl) diphenylamine)  . 

a,a,a-Trifluorotoluene 

a,a,a-TTifluoro-m-toluidine 

a, a,a-Trifluoro -o-toluidine 

l,2,A-Trihydro3cyanthraquinone 

3,<l,5-Trimethoxybenzoic  acid 

2^,5-Trimethylaniline   (Pseudocumidine) 

l,2,<i-Triinethylbenzene  (Pseudocumene) 

2,3,3-Trlmethyl-3H-indole 

»l,3,3-Trijiiethyl-/!?,a-indolineacetaldehyde 

»l,3,3-Triiiiethyl-2-methyleneindoline  (Trlmethyl  base) 

Trlmethylphenylammonlum  iodide 

a,a',2-Trljiiethyl-l,4--piperazinediethanol 


ACY,   DUP, 

GAF, 

ICI. 

ACY. 

ACY,    DUP, 

NAC. 

NAG. 

BPC. 

LIL. 

ABB. 

GIV. 

ACY,   DUP, 

GAF, 

NAC,   OIC,   RUC, 

WAY. 

EK. 

GAF,   SDH. 

MON. 

MON. 

MDN,   HAC, 

NES, 

SW,   UPF. 

ACY,    TEN, 

UPF. 

NES. 

GAF. 

MAC. 

ICI. 

NES. 

MON. 

CWL. 

CWL. 

CWL. 

DUP,    NAG. 

DUP,   NAG. 

ACY. 

DUP,    NAG. 

EK. 

DUP. 

VPC. 

TRC,  VPC. 

NAC. 

ACY,   DUP, 

NAC. 

BUC,   GAF. 

ACY,   BUC, 

DUP, 

GAF,    NAC,   SDH 

GAF. 

X. 

EKT. 

EK. 

ICO,  ms. 

DVC,   PPG. 

DOW,   DVC, 

HK. 

EK. 

PCW. 

DCC,   UCC. 

HK,  VEL. 

HN. 

BPC. 

HN. 

ACY,   GGY, 

NIL. 

DUP. 

OAF. 

ICO. 

NAC. 

PLC. 

OAF. 

DUP,   GAF,  VPC. 

DUP,  OAF,  NAC,  VPC. 

EK. 

WYN. 


CYCLIC  INTERMEDIATES 


TABLE  IB.— Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i566— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


2,<»,6-Trimethylpyridlne 

1,3,5-Trluitrobenzene 

2,'i,7-Trinltrofluoren-9-one 

Triphenylmethanol 

Triphenylsulfonium  chloride 

a, a', a' '-Tris(dlmethylamino)me6itol 

Tris(2-methyl-l-aziridinyl)phOEphlne  oxide 

m-Ureidoaniline 

«7,7'-Ureylenebis[4-hydroxy-2-naphthalenesulfonlc  acid] 
(J  acid  urea) . 

Veratraldehyde   (aj-i-Dimethoxybenzaldehyde) 

Veratryl  alcohol  (3,'i-Dimethoxybenzyl  alcohol) 

p-Vinylbenzenesulfonlc  acid,   sodium  salt 

4-Vinylcyclohexene 

2,2  '-Vinylenebis [benzimidazole ] 

5-Vinyl-2-picoUne   (MVP) 

2-Vinylpyridine 

A-Vinylpyridlne 

»Violanthrone  (Dibenzanthrone) 

Xanthene-9-carboxylic  acid 

Xanthic  acid,  A-ohloro-o-tolyl  ester 

m-Xylene 

*o-)^lene 

»p-Xylene 

2,5-Xylenesulfonic  acid — 

2,'i-)^lenol 

2,6-)^lenol - 

}5ylenol  crystals 

Xylenols : 

Low  b.p 

Medium  b.p 

Not  classified  as  to  b.p 

Xylidines; 

2,'i-Xylidine  (m-^-Xylidine) 

2,5-Xylidine  (p-Xylidine) 

2,6-Xylldine 

Original  mixture 

'i-(2,';-Xylylazo)-o-toluidine 

4-(2,5-)^lylazo)-o-toluidine 

't-(Xylylazo)xylldine,  mixed 

<i-(2,4-Xylylazo)-2,5-xylidine 

All  other  cyclic  intermediates 


EK. 

GAM. 

RH,  TKL. 

ICO. 

ICI. 

ACY,  ATL,  BKS,  BL,  CMG,  GAF,  NAC,  TRC,  VPC. 

GIV,  LIL,  SLV. 

LIL. 

DUP. 

PLC. 

TRC. 

PLC. 

NEP,  RIL. 

RIL. 

ACY,  ATL,  DUP,  GAF,  ICI,  MAY,  SDC,  TRC. 

MAL. 

GAF. 

SNT,  SOC. 

ASH,  CCP,  COR,  CSD,  CSO,  DLH,  SIN,  SNT,  SOC,  TOC. 

CSD,  ENJ,  HCR,  SIN,  SNT,  SOC,  SOG. 


NPC, 

PIT. 

KPT, 

NPC, 

PIT 

KPT, 

NPC, 

PRD 

DUP, 

NAC. 

DUP. 

Dim. 

DUP, 

NAC. 

NAC. 

ACY. 

GAF. 

FG,  GAF,  GAM,  ICC,  ICO,  LIL,  MON, 


■■■  See  table  13B  for  data  on  medicinal  grade  of  this  item. 

^  Does  not  include  maniif acturers '  identification  codes  for  producers  that  report  to  the  Division  of  Bituminous 
Coal,  U.S.  Bureau  of  Mines.  These  producers  are  listed  in  the  U.S.  Bureau  of  Mines  Mineral  Industry  Survey 

Coke  Producers  in  the  United  States  in  1966.  Aug.   29,  1967. 


92 


SYNTHETIC  ORGANIC  CHEMICALS.  1966 


Dyes 

TABLE  8B.  — Bemenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by  manufacturer,  1966 


[Dyes  for  which  separate  statistics   are  given  in  table  8A  are  marked  below  with  an  asterisk   (»);   dyes  not  so  marked 
do  not  appear  in  table  8A  because  the  reported  data  are  accepted  in  confidence  and  may  not  be  published.   Manu- 
facturers'   identification  codes  shown  below  are  taken  from  table  22.    An  x  signifies   that  the  manufacturer  did  not 
consent  to  his  identification  with  the  designated  product  ] 


Pye 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


ACID  DYES 

»Acid  yellow  dyes: 

Acid  Yellow  1 - - 

Acid  Yellow  2 

»Acid  Yellow  3— 

Acid  Yellow  A— 

Acid  Yellow  7 

Acid  Yellow  9 — 

»Acid  Yellow  11 - 

Acid  Yellow  K 

»Acld  Yellow  17 - 

"Acid  Yellow  23 

Acid  Yellow  25 - - 

Acid  Yellow  29- 

Acid  Yellow  3-;— — 

Acid  Yellow  35— 

»Acid  Yellow  36— 

Acid  Yellow  38 

»Acid  Yellow  40- - 

»Acid  Yellow  A2 - 

«Acid  Yellow  44 - 

Acid  Yellow  49— 

»Acid  Yellow  54 - 

Acid  Yellow  59 

Acid  Yellow  60 

Acid  Yellow  63 

Acid  Yellow  65— 

»Acid  Yellow  73 

Acid  Yellow  76 

Acid  Yellow  79— - 

Acid  Yellow  90 

Acid  Yellow  95 

»Acld  Yellow  99 

Acid  Yellow  114 

Acid  Yellow  121 

*Aoid  Yellow  124— 

Acid  Yellow  127— - 

Acid  Yellow  128- 

Acid  Yellow  129 

»Acld  Yellow  151 - 

Acid  Yellow  152— - 

Acid  Yellow  159— 

Other  acid  yellow  dyes 

»Acid  orange  dyes: 

»Acid  Orange  1 

Acid  Orange  2 

Acid  Orange  5 

Acid  Orange  6 

«Aold  Orange  7 

«Acid  Orange  8 

«Aoid  Orange  10 

Acid  Orange  12 

Acid  Orange  19 

»Acid  Orange  24 

Acid  Orange  28 

Acid  Orange  31 

Acid  Orange  34 

Acid  Orange  45 

Acid  Orange  50 

Acid  Orange  51 

Acid  Orange  52 

Acid  Orange  56 


ACY. 

DUP. 

ACY, 

DUP, 

GAF. 

NAC. 

SDH. 

NAC. 

ACY. 

CMG, 

DUP, 

VPC. 

BDO. 

TMC. 

ACY, 

ATL, 

BDO. 

BKS, 

CMG, 

DUP, 

GAF, 

NAC,    PDC,    SDH,    TRC, 

VPC. 

AAP, 

ACY, 

GAF, 

MRX, 

NAC, 

SDH, 

TRC, 

VPC. 

GAF. 

GAF, 

TRC. 

NAC. 

VPC. 

DUP, 

GAF, 

NAC, 

TRC. 

NAC. 

DUP, 

GAF, 

NAC, 

TRC, 

VPC. 

AAP, 

ACY, 

GAF, 

VPC. 

AAP, 

GAF, 

NAC, 

VPC. 

VPC. 

ACY, 

BKS, 

CMG, 

GAF. 

NAC, 

TRC, 

VPC. 

VPC. 

NAC. 

AAP, 

NAC. 

TRC. 

GAF, 

NAC, 

NYC, 

SDH. 

TRC. 

VPC. 

NAC. 

CMG. 

CMG, 

GAF, 

NAC, 

TRC, 

VPC. 

CMG, 

TRC. 

GAF. 

BKS, 

DUP, 

NAC. 

TRC. 

TRC. 

TRC. 

ACY, 

BKS, 

TRC, 

VPC. 

ACY. 

TRC. 

ACY, 

ALT, 

CMG, 

DUP, 

GAF, 

TRC, 

VPC. 

ALT, 

BKS, 

GAF, 

NAC. 

NAC, 

TRC. 

ACY. 

NAC. 

AAP, 

ACY, 

ATL, 

BKS, 

CPC, 

GAF, 

NAC, 

PDC,    TRC,    YAW. 

ACY, 

ATL, 

BKS, 

DUP, 

GAF, 

NAC, 

TRC. 

ACY, 

BKS, 

DUP, 

GAF, 

NAC, 

TRC, 

VPC, 

YAW. 

NAC. 

GAF. 

ACY, 

DUP, 

GAF, 

NAC, 

TRC, 

YAW. 

NAC. 

AAP. 

ACY. 

NAC, 

TRC. 

AAP. 

cue. 

NAC, 

TRC. 

NAC. 

OAF. 

93 


TABLE  8B.  —  Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i 566— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


ACID  DYES— Continued 


».Acld  orange  dyes — Continued 

»Acid  Orange  60 

Acid  Orange  62 

Acid  Orange  63 

»Acid   Orange  64 

Acid  Orange  69 

Acid  Orange  72- 

Acid  Orange  74 

Acid  Orange  76 

Acid  Orange  85 

Acid  Orange  36 

Acid  Orange  114 

Acid  Orange  116 

Acid  Orange  119 

Other  acid  orange  dyes 

»Acid  red  dyes: 

♦Acid  Red  1 

»Acid  Red  4 — 

»Acid  Red  14- — 

Acid  Red  17 

»Acid  Red  18 

»Aoid  Red  26 

Acid  Red  27 

Acid  Red  32 

Acid  Red  33 

Acid  Red  34 

Acid  Red  35 - — 

»Acid  Red  37 - 

Acid  Red  42 — 

Acid  Red  52 

Acid  Red  57 

Acid  Red  66- 

«Acld  Red  73 

Acid  Red  76 — 

Acid  Red  80 

♦Acid  Red  85 

»Acid  Red  87 
*Aold  Red  88 
»Acid  Red  89 

Acid  Red  94 

Acid  Red  97 

Acid  Red  99 

Acid  Red  lOi 

Acid  Red  10 

Acid  Red  11 
»Acid  Red  11 

Acid  Red  11 

Acid  Red  11 

Acid  Red  13 

Acid  Red  13. 
»Acid  Red  13 
»Acid  Red  15 

Acid  Red  167- 

Acid  Red  175- 

Acid  Red  178- 

Acid  Red  179- 
»Acid  Red  182- 

Acid  Red  183- 
»Aoid  Red  186- 

Acid  Red  190- 

Acid  Red  191. 

Acid  Red  194. 

Acid  Red  201. 

Acid  Red  207. 

Acid  Red  212. 

Acid  Red  213. 

Acid  Red  273. 

Aoid  Red  292 


Acid 
*Acld 

»Acid 

Red 
Red 

Red 

80 - - - 

Acid 

Red 

i06 

Acid  Red 

rr 

Acid 
Acid 
Acid 

Red 
Red 
Red 

»Acid  Red 
«Acid  Red 

GAF,  TRC. 

ACY,  DUP,  NAC. 

ACY. 

GAF. 

CMG,  GAF,  NAC,  TRC. 

NAC,  TRC. 

NAC. 

NAC,  TRC. 

ACY. 

ATL,  BKS,  GAF,  TRC. 

TRC. 

ALT,  DUP,  VPC. 

AAP,  ACY,  BDO,  BKS,  BL,  DUP,  GAF,  NAC,  SDH,  TRC,  VPC, 

YAW. 
ATL,  BDO,  CWG,  DUP,  GAF,  TRC,  VPC,  YAW. 
DUP,  GAF,  NAC,  PDC. 
NAC,  TRC,  YAW. 
ACY,  DUP,  GAF,  NAC,  TRC. 
ACY,  ATL,  CPC,  GAF,  NAC. 
NAC. 

OAF,  NAC. 
NAC,  YAW. 
NAC. 

AAP,  GAF. 

BKS,  CMG,  DUP,  GAF,  NAC,  TRC. 
GAF. 
GAF. 
TRC. 
AAP. 

ACY,  DUP,  GAF,  NAC,  PSC,  TRC. 
NAC. 

GAF,  ICI. 
ACY,  ALT,  ATL,  BKS,  CMG,  DUP,  GAF,  NAC,  PDC,  TRC, 

VPC,  YAW. 
AMS,  NYC,  SDH. 

ACY,  ATL,  DUP,  GAF,  NAC,  SDH,  TRC,  YAW. 
AAP,  GAF,  TRC,  VPC. 
NYC. 
GAF. 

BKS,  CMG,  TRC,  VPC,  YAW. 
VPC. 
YAW. 
DUP. 

ATL,  DUP,  GAF,  NAC. 
GAF,  NAC. 
NAC. 
GAF. 
TRC. 

ATL,  DUP,  GAF,  NAC,  TRC. 
AAP,  ACY,  BKS,  TRC,  YAW. 
NAC,  TRC. 
DUP. 
DUP. 

CMG,  TRC. 

ACY,  BKS,  CMG,  DUP,  GAF,  NAC. 
CWG,  TRC. 

BKS,  CMG,  GAF,  TRC,  VPC. 
ACY. 
TRC. 
TRC. 
TRC. 
NAC. 
TRC. 
TRC. 
OAF. 
ACY. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  8B.  --Beruenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  2  S66— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


ACID  DYES— Continued 

»Acld  red  dyes— Continued 

Acid  Red  299 

Acid  Red  309 — 

Other  acid  red  dyes 

»Acid  violet  dyes: 

»Acid  Violet  1 

»Acid  Violet  3 — 

Acid  Violet  6 - - 

»Acld  Violet  7 

Acid  Violet  9 - 

Acid  Violet  11 - 

»Acld  Violet  12 

Acid  Violet  13 

Acid  Violet  17 

Acid  Violet  29 

Acid  Violet  34 

Acid  Violet  41 

Acid  Violet  43 --- 

»Acid  Violet  49 - 

Acid  Violet  56- — 

Acid  Violet  58 - 

Acid  Violet  76 

Other  acid  violet  dyes 

•»Aoid  blue  dyes : 

Acid  Blue  1 

»Acid  Blue  7— 

»Acid  Blue  9- ■ 

Acid  Blue  10 • 

Acid  Blue  15 

Acid  Blue  20— 

Acid  Blue  22 ■ 

Acid  Blue  23 

»Acid  Blue  25— 

Acid  Blue  26- 

Acid  Blue  27 ■ 

Acid  Blue  29 

Acid  Blue  34— 

»Acid  Blue  40 - 

»Acid  Blue  41 

»Acid  Blue  43 - 

»Aoid  Blue  45— - 

Acid  Blue  47 

Acid  Blue  48 - 

Acid  Blue  55 

Acid  Blue  58 

Acid  Blue  59 

»Acid  Blue  62 - - 

Acid  Blue  63 

Acid  Blue  67 - 

Acid  Blue  69 

Acid  Blue  74 

»Acid  Blue  78- 

Acid  Blue  80 — 

Acid  Blue  81— 

Acid  Blue  83 — 

Acid  Blue  89 

»Acid  Blue  90— — 

Aoid  Blue  92 

Acid  Blue  93— — 

Acid  Blue  102- 

Acid  Blue  104- 

»Aoid  Blue  113 — 

Acid  Blue  118- — 

Acid  Blue  120 

Acid  Blue  122 

Acid  Blue  145 — 

»Aold  Blue  158  and  158A 

Acid  Blue  165— 

Acid  Blue  179 

Acid  Blue  198 


NAC. 
AAP, 
GAF. 
GAF. 
EDO, 
DUP. 
GAF, 
HSH. 
ICl. 
CMG. 
HSH, 
ACY, 
CMG, 
GAF. 
NAC. 
ALT, 

GAF, 
ACY, 
GAF, 
NAC. 
GAF. 
NAC. 
ACY, 
NAC, 
ATL, 
NAC. 
CMG, 
PDC. 
NAC. 
ATL, 
BDO, 
ACY, 
ACY, 
ICI. 
HSC. 
NAC. 
DUP. 
NAC. 


TRC. 

ATL,  DUP,  GAF,  VPC. 


BDO,  CMG,  DUP,  GAF,  NAC,  TRC,  VPC. 
CMG,  DUP,  GAF. 


ICI,  NAC. 
NAC,  TRC. 
GAF. 


NAC,  SDH. 
GAF,  NAC,  SDH. 
NAC,  SDH,  VPC. 


NYC. 
TRC. 
BDO,  CMG,  DUP,  GAF,  NAC,  TRC. 


GAF,  ICI,  NAC,  TRC. 

CMG,  GAF,  NAC. 

GAF,  NAC,  TRC. 

cue,  DUP,  GAF,  NAC,  TRC,  VPC. 


BDO,  GAF,  NAC,  VPC. 


CMG, 

NAC. 

CMG. 
DUP, 
DUP. 

GAF. 
NAO. 

DUP, 

GAF, 

ICI, 

NAC, 

TRC. 

NAC, 

TRC. 

ICI. 

GAP. 

NAC. 

GAF, 

NAC, 

TRC. 

NAC, 

YAW. 

HSC. 

NAC, 

TRC. 

GAF, 

NAC. 

ATL. 

BDO, 

BKS. 

CMG. 

DUP, 

GAF,    NAC 

BKS, 

GAF, 

NAC. 

GAF, 

NAC. 

DUP. 

DUP. 

NAC. 

ACY, 

BKS, 

GAF, 

NAC, 

TRC, 

VPC. 

DUP. 

GAF. 

VPC. 

TABLE  8B.  — Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 — Continued 


Manufacturers'   identification  code 
(according  to  list  in  table  22) 


ACID  DYES— Continued 

»Acid  blue  dyes --Continued 

Acid   Blue  203 

Acid   Blue  230 — - 

Acid  Blue  231 

Other  acid  blue  dyes 

»Acid  green  dyes: 

Acid  Green  1 

»Acid  Green  3 

Acid  Green  5 

»Aoid  Green  9 

»Acid  Green  12 

»Acid  Green  16 

»Acid  Green  20 

Acid  Green  22 

»Acid  Green  25 

Acid  Green  35 - - ■ 

Acid   Green  41 

Acid  Green  44 

Acid  Green  50 - -- • 

Acid  Green  58 

Acid  Green  70 -■ 

Other  acid  green  dyes 

»Acid  brown  dyes: 

Acid   Brown  1 

Acid   Brown  6 

»Acid  Brown  U 

Acid  Brown  19 

Acid  Brown  22 

Acid   Brown  28 

Acid  Brown  29 

Acid  Brown  31 

Acid  Brown  45 

Acid  Brown  96 

Acid  Brown  97 

Acid  Brown  98 

Acid  Brown  152 

Acid  Brown  158 

Acid   Brown  223— - 

Acid  Brown  243 

Other  acid  brown  dyes 

»Acid  black  dyes: 

»Acid  Black  1 

Acid  Black  2 

Acid  Black  12 

Acid  Black  16 

Acid  Black  18 

»Acid  Black  24 

Acid  Black  26,   26A,    and  26B 

Acid  Black  29- 

Acid  Black  41 - 

»Acld  Black  48 - 

Acid   Black  52 — 

Acid  Black  53 

Acid  Black  58— 

Acid  Black  60- 

Acid  Black  92 - 

»Acid  Black  107- 

Acid  Black  108 

Acid  Black  138— 

Other  acid  black  dyes 

AZOIC  DYES  AND  CCMPONENTS 

Azoic  yellow  dyes : 

"Azoic  Yellow  1— 

Azoic  Yellow  2 

Azoic  Yellow  3— - - 


VPC. 

DUP,    TRC. 

TRC. 

ACY,    ALT,    CMG,    DUP,    TRC,    VPC. 


GAF,  NAC. 

NAC,  TRC. 

GAF,  NAC,    SDH,    TRC. 

CMG,  DUP,    GAF,    NAC,    PDC,    TRC. 

NAC. 

GAF,  HSH,    ICI,    NAC,    TRC,    VPC. 

VPC. 

GAF. 


GAF. 

GAF. 

AAP,    ACY,    DUP,    GAF,    NAC,    TRC,    YAW. 

TRC. 

DUP. 

TRC. 

DUP. 

GAF. 

TRC. 

ACY. 

ACY. 

ACY,    TRC. 

GAF. 

GAF. 

GAF. 

GAF. 

ALT,    DUP,    GAF. 


AAP,    ACY,    AIL, 

TRC,    YAW. 
ACY,    NAC. 
NAC. 
NAC. 
NAC. 

CMG,    DUP,    GAF,    NAC. 
DUP,    NAC,    TRC. 
GAF,    NAC,    YAW. 
NAC. 

ACY,    CMG,    DUP,    GAF,    ICI,    NAC,    TRC. 
BKS,    GAF,    NAC,    TRC. 
NAC. 

NAC,  TRC. 
CMG,  TRC. 
ACY. 

GAF,    NAC,    TRC. 
GAF. 
VPC. 
ALT,    DUP,    PDC. 


BKS,    DUP,    FAB,    GAF,    HSH,    NAC,    PDC, 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  8B.  --Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i 566— Continued 


Manufacturers'    identification  code 
(according  to  list  in  table  22) 


AZOIC  DYES  AND  CQMP0N5MTS— Continued 


-Continued 


Azoic  orange  dyes: 

»Azolc  Orange  3 

Azoic  Orange  4 

Other  azoic  orange  dyes 

»Azoic  red  dyes: 

»Azolc  Red  1 

Azoic  Red  2 

»Azoio  Red  6 

Azoic  Red  13 

Azoic  Red  15 

Azoic  Red  16 

Azoic  Red  73 — - 

Azoic  Red  7i, 

Other  azoic  red  dyes 

»Azoic  violet  dyes:  Azoic  Violet  1— 
Azoic  blue  dyes : 

»Azolo  Blue  2 

«Azolc  Blue  3 

Azoic  Blue  4 

Azoic  Blue  6 

Azoic  Blue  7 

Other  azoic  blue  dyes 

Azoic  green  dyes: 

Azoic  Green  1 

Other  azoic  green  dyes 

Azoic  brown  dyes: 

»Azoic  Brown  9 

Azoic  Brown  10 

Azoic  Brown  26 

Other  azoic  brown  dyes 

»Azoic  black  dyes : 

Azoic  Black  1 

Azoic  Black  4 

Azoic  Black  15 

Other  azoic  black  dyes 

Other  azoic  compositions 

Azoic   Diazo   Componeni 
(Fast   Color  Bas 

Azoic  Diazo  Component  2,   base 

Azoic  Diazo  Conqjonent  3,   base 

»Azoic  Diazo  Con?)onent  A,   base 

Azoic  Diazo  Conponent  5,   base 

Azoic  Diazo  Component  8,   base 

»Azolc  Diazo  Component  9,   base 

»Azoic  Diazo  Component  10,   base 

»Azoic  Diazo  Component  12,   baee 

»Azoic  Diazo  Coii?)onent  13,   base 

Azoic  Diazo  Con^ionent  li,   base 

Azoic  Diazo  Component  20,   base 

Azoic  Diazo  Coii5)onent  27,   base 

Azoic  Diazo  Component  28,   base 

»Azoic  Diazo  Component  32,   base 

Azoic  Diazo  Component  34,   base 

Azoic  Diazo  Component  41,   base 

Azoic  Diazo  Conqjonent  42,   base 

Azoic  Diazo  Con^jonent  44,   base 

»Azoio  Diazo  Component  48,   base 

Other  azoic  diazo  components,   bases- 

(Fast   Color  Sal 

»Azoio  Diazo  Coiyonent  1,  salt 

»Azoic  Diazo  Component  2,  salt 

»Azoic  Diazo  Con^ionent  3,  salt 

Azoic  Diazo  Component  4,  salt 


ALL, 

ATL, 

BUC, 

GAF, 

X. 

r,AF. 

VPC. 

ALL, 

ATL, 

BUC, 

GAF, 

HST,    X. 

ATT,, 

HUC, 

GAF, 

X. 

AI,T., 

ATL, 

BUC, 

GAF, 

HST,    VPC,    X 

GAF. 

GAF. 

ATL, 

GAF. 

GAF. 

GAF. 

VPC. 

ALL, 

ATL, 

BUG, 

GAF, 

X. 

ATT,, 

RIIO, 

GAF. 

ALL, 

ATL, 

BUC, 

GAF, 

HST,    X. 

GAF. 

ATL, 

GAF. 

GAF. 

ALL. 

ATL, 

GAF. 

VPC. 

BUC, 

GAF, 

HST, 

VPC, 

X. 

GAF. 

GAF. 

ATL, 

GAF, 

VPC. 

HST. 

ATL, 

BUC, 

GAF. 

GAF. 

ALL, 

ATL, 

GAF, 

VPC. 

ATL, 

BUC. 

BUC. 

ALL, 

BUC, 

GAF, 

SDH. 

GAF, 

SDH. 

DUP, 

SDH. 

AAP, 

DUP, 

VPC. 

ALL, 

AUG, 

BUC, 

GAF. 

ATTG, 

BUC, 

SDH. 

ALL, 

ATL, 

AUG, 

BUC, 

VPC. 

AAP. 

ALL, 

GAF. 

BUC. 

ALL, 

BUC, 

VPC. 

AAP, 

ALL, 

ATL, 

BUC, 

DUP,    SDH 

GAF. 

ALL, 

GAF. 

AT,T,. 

AAP, 

BUC. 

ALL, 

CWN, 

DUP, 

GAF. 

GAF. 

AAP,  ALL,  GAF,  SDH. 

ALL,  AUG,  BUC,  GAF. 

AAP,  ALL,  AUG,  BUC,    GAF,    NAC,    SDH. 

ALL,  AUG,  DUP. 


TABLE  8B.  --Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i 566— Continued 


Manufacturers '   identification  codes 
(according  to  list  in  table  22) 


»A2oic  Dlazo 
»Azoic  Dlazo 
»Azoio  Diazo 
Azoic  Diazo 
»Azoic  Diazo 
»Azoic  Diazo 
Azoic  Diazo 
Azoic  Diazo 
»Azoic  Dlazo 
Azoic  Diazo 
Azoic  Diazo 
Azoic  Diazo 
»Azolc  Diazo 
Azoic  Diazo 
Azoic  Diazo 
Azoic  Diazo 
Azoic  Diazo 
»Azoio  Diazo 
»Azoio  Diazo 
»Azoic  Diazo 
Azoic  Diazo 


AZOIC  DYES  AND  CCMPONSMTS— Continued 

Azoic  Diazo  Components,    Salts 
(Fast  Color  Salts) --Continued 

Coin>onent  5,   salt 

Component  6,    salt 

Component  8,   salt 

Component  9,   salt 

Coiqjonent  10,   salt 

Con5)onent  11,   salt 

Component  12,   salt 

Component  13,    salt 

Component  14,    salt 

Component  20,    salt 

Component  28,   salt 

Component  32,   salt 

Component  34,   salt 

Component  35,   salt 

Component  35,    salt 

Component  37,   salt 

Component  40,   salt 

Component  41,   salt 

Conponent  42,    salt 

Component  44,    salt 

Coii?)onent  48,   salt 

Component  49,   salt 

Component  121,    salt 


AAP, 
AAP, 
AAP, 
AAP, 
AAP, 
AAP, 
AAP, 
AAP, 
AAP. 
ALL, 
ALL, 
ALL, 
GAF. 
GAF. 
AAP, 
ALL, 
BUG. 
BUG, 
ALL, 
ALL, 
AAP, 
AAP, 
GAF. 


ALL,  AUG,  BUG,    GAF,    SDH. 

BUG,  GAF,  SDH. 

ALL,  AUG,  sue,    GAF. 

ALL,  AUG,  BUG,    GAF,    SDH,    VPC. 

ALL,  AUG,  BUG,    GAF,    SDH. 

ALL,  GAF. 

ALL,  AUG,  BUG,    GAF,    SDH. 

ALL,  AUG,  BUG,    GAF,    NAC,    SDH,    VPC. 

GAF. 

AUG,  BUG,  GAF,    NAC,    SDH,    VPC. 

SDH. 


GAF. 

GAF. 

BUG,    GAF,    SDH. 

GAF,    SDH. 

ALL,    BUG,    GAF,    SDH. 


Azoic  Coupling  Compc 
(Naphthol  AS  and  Deni 

»Azoic  Coupling   Component  2 

»Azoic  Coupling   Component  3 

»Azoic  Coupling  Coiqjonent  4 

»Azoic  Coupling  Component  5 

»Azoic  Coupling   Con^ionent  7 

Azoic  Coupling  Component  8 

Azoic  Coupling   Goii5>onent  10 

»Azoic  Coupling  Goinjonent  11 

Azoic  Coupling   Component  12 

Azoic  Coupling   Component  13 

»Azoic  Coupling  Component  14 

Azoic  Coupling   Con^ronent  15 

Azoic  Coupling   Component  16 

»Azoic  Coupling  Component  17 

»Azoic  Coupling  Coiqjonent  18 

»Azoic  Coupling  Conponent  19 

«Azolc  Coupling  Component  20 

*Azoic  Coupling   Component  21 

Azoic  Coupling  Component  23 

»Azolc  Coupling  Component  24 

•Azoic  Coupling   Component  29 

Azoic  Coupling  Component  34 

Azoic  Coupling   Component  35 

Azoic  Coupling  Con^jonent  36 

»Azoic  Coupling   Component  43 

Other  azoic  coupling  con5>onents 

BASIC  DYES 

♦Basic  yellow  dyes: 

Basic  Yellow  1 — 

•Basic  Yellow  2 

Basic  Yellow  5 

•Basic  Yellow  11- 

•Basic  Yellow  13- - 

Basic  Yellow  15 

Basic  Yellow  16— - — 

Basic  Yellow  26 

Basic  Yellow  27 

Basic  Yellow  28 — 


ACY, 

ATL, 

AUG, 

BUG, 

GAF,    NAC,    PCW 

AUG, 

BUG, 

GAF, 

PCW. 

AUG. 

BUG, 

GAF. 

AAP. 

GAF, 

SDH. 

AAP. 

AUG, 

BUG, 

GAF, 

PCW. 

BUG, 

GAF, 

PGW. 

PGW. 

BUG, 

GAF, 

PGW. 

BUG, 

GAF, 

PCW. 

GAF, 

PCW. 

ATL, 

BUG, 

GAF. 

NAG, 

PCW. 

BUG. 

GAF. 

GAF. 

ACY, 

ATL, 

BUG. 

PGW. 

ACY, 

ATL, 

BUG. 

GAF, 

NAC,    PCW. 

BUG, 

GAF, 

PCW. 

AIL, 

BUG, 

DUP, 

GAF, 

PCW. 

ATL, 

AUG, 

BUG, 

GAF, 

PCW. 

GAF, 

PCW. 

BUG, 

GAF, 

PCW. 

ATL, 

AUG, 

BUG, 

GAF, 

PCW. 

BUG, 

GAF, 

PCW. 

GAF, 

PCW. 

OAF. 

ATL, 

BUG, 

GAF. 

ATL, 

GAF, 

VPC. 

DUP. 

ACY,  DUP,  NAC. 

NAC. 

DUP,  GAF,  NAG,  VPC. 

DUP,  GAF,  NAG,  VPC. 

DUP. 

DUP. 

ACY. 

ACY. 

vpn. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Bemenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  566— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


BASIC  DYES— Continued 

»Basic  yellow  dyes --Continued 

Basic  Yellow  37 

Other  basic  yellow  dyes 

♦Basic  orange  dyes: 

»Basic  Orange  1 

*Baslc   Orange  2 

Basic   Orange  lA 

Basic  Orange  17 

»Basic  Orange  21 

Basic   Orange  22 

Basic   Orange  24 

Basic   Orange  25 

Basic   Orange  26 

Basic   Orange  27 

Basic  Orange  31 

»Basic  red  dyes: 

Basic  Red  1 

Basic  Red  2 

Basic  Red  9 — 

Basic  Red  12 

Basic  Red  13 

»Basic  Red  lA 

Basic  Red  15 

Basic  Red  16 

Basic  Red  17 

Basic  Red  18— 

Basic  Red  19 - 

Basic  Red  20 — — 

Basic  Red  22 

Basic  Red  30 - 

Other  basic  red  dyes 

»Basic  violet  dyes: 

*Basic  Violet  1 

Basic  Violet  2 - 

Basic  Violet  3- 

*Basic  Violet  A 

Basic  Violet  7 - 

Basic  Violet  10 

Basic  Violet  13 - 

Basic  Violet  14 

Basic  Violet  15 - — 

*Basic  Violet  16 

Basic  Violet  18 

Other  basic  violet  dyes 

■»Basio  blue  dyes: 

♦Basic  Blue  1 

Basic  Blue  2 

Basic   Blue  3 

Basic  Blue  4 

♦Basic  Blue  5 

Basic  Blue  6 

♦Basic  Blue  7 

♦Basic  Blue  9 

Basic  Blue  11 - 

Basic  Blue  21— — 

Basic  Blue  22 

♦Basic  Blue  26 

Basic  Blue  27 

Basic  Blue  35 

Basic  Blue  38 

Basic  Blue  39 

Basic  Blue  41 

Basic  Blue  47 

Basic   Blue  54— - 

Other  basic  blue  dyes 

Basic  green  dyes: 

♦Basic  Green  1 

Basic  Qreen  3 

•Basic  Green  4 


ACY. 

DUP,    GAF. 

ACY,    DUP, 

GAF, 

NAC, 

TRC. 

ACY,    DSC, 

DUP, 

GAF, 

NAC,    PDC, 

PSC,    TRC, 

GAF. 

NAC. 

DUP,    GAF, 

NAC, 

VPC. 

GAF,    NAC. 

DUP. 

DUP. 

DUP. 

VPC. 

ACY. 

DUP,    GAF. 

DUP,    NAC. 

ACY,    DSC, 

HSC. 

DUP. 

GAF,    NAC. 

ACY,    DUP, 

GAF, 

NAC, 

VPC. 

DUP,    GAF. 

DUP. 

DUP. 

DUP,    VPC. 

DUP. 

DUP. 

ACY,    TRC. 

ACY. 

DUP,    GAF, 

VPC. 

ACY,    DSC, 

GAF, 

HSC, 

NAC. 

DSC,    NYC. 

DSC,    DUP, 

NAC, 

SDH. 

DSC,    DUP, 

GAF, 

NAC. 

GAF,    NAC. 

ACY,    DUP, 

GAF. 

DSC. 

ACY,    DSC. 

DUP. 

DUP,    GAF, 

VPC. 

ACY. 

DUP. 

DSC,    GAF, 

NAC, 

SDH, 

VPC. 

DSC. 

GAF. 

DUP. 

DSC,    SDH, 

VPC. 

ACY,    NAC. 

DSC,    DUP, 

NAC, 

SDH. 

ACY,    GAF, 

NAC, 

SDH. 

DSC,    SDH. 

DUP. 

DUP,    NAC. 

DSC,    DUP, 

NAC, 

SDH. 

GAF. 

DUP. 

ACY,    DUP. 

DUP. 

TRC. 

VPC. 

ACY. 

ACY,    DUP, 

GAF. 

ACY,    DSC, 

DUP, 

NAC, 

SDH. 

DUP. 

ACY,    DSC, 

DUP, 

NAC, 

SDH. 

99 


■  Bemenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i566— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


BASIC  DYES— Continue 

Basic  brown  dyes: 

»Basic   Brown  1 

Basic  Brown  2 

»Basic  Brown  <♦ 

Basic  black  dyes : 

Basic   Black  3 

Other  basic  black  dyes 

DIRECT  DYES 


ACY,  DUP,  GAF,  NAC,  TRC. 

GAF. 

ACY,  DSC,  DUP,  GAF,  NAC,  TRC. 


•Direct  yellow  dyes : 

♦Direct  Yellow  <i 

•Direct  Yellow  5 

•Direct  Yellow  6 

Direct  Yellow  7 

Direct  Yellow  8 - 

Direct  Yellow  9 

•Direct  Yellow  11 

•Direct  Yellow  12 

Direct  Yellow  20 —  - 

Direct  Yellow  23 

•Direct  Yellow  26 

Direct  Yellow  27 

•Direct  Yellow  28 

•Direct  Yellow  29 

Direct  Yellow  39 

•Direct  Yellow  44 

•Direct  Yellow  50 

Direct  Yellow  59 

Direct  Yellow  63 

•Direct  Yellow  84— 

Direct  Yellow  103 

•Direct  Yellow  105 

•Direct  Yellow  106 

Direct  Yellow  107 

Direct  Yellow  114 

Direct  Yellow  117 

Direct  Yellow  118 — - 

Direct  Yellow  120 

Direct  Yellow  121 

Direct  Yellow  125— 

Other  direct  yellow  dyes- 
•Direet  orange  dyes; 

•Direct  Orange  1 

Direct  Orange  6 

•Direct  Orange  8 

Direct  Orange  10 

Direct  Orange  11 

•Direct  Orange  15 

•Direct  Orange  26 

•Direct  Orange  29 

•Direct  Orange  34 

•Direct  Orange  37 

•Direct  Orange  39 

Direct  Grange  40 

Direct  Orange  48 

Direct  Orange  55 

Direct  Orange  59 

Direct  Orange  61 

Direct  Orange  67 

Direct  Orange  70 

•Direct  Orange  72 

•Direct  Orange  73 

Direct  Orange  74 

Direct  Orange  76 

Direct  Orange  78 

Direct  Orange  79 

Direct  Orange  80 

•Direct  Orange  81 

Direct  Orange  83 


DUP,    GAF,    NAC,    TRC. 

GAF,    NAC. 

ATL,    DUP,    GAF,    NAC,    TRC. 


BKS,    DUP,    GAF,    NAC,    TRC. 
DUP,    FAB,    GAF,    NAC,    TRC. 


BKS,    BL,    DUP. 


ATL,    BKS,    BL,    DUP,    FAB,    GAF,    NAC,    TRC,    VPC. 
BKS,    BL,    DUP,    FAB,    GAF,    NAC,    TRC,    VPC. 
DUP,    NAC. 


GAF,    NAC,    TRC. 


BKS,    GAF,    TRC. 
BKS,    FAB,    GAF,    TRC. 


ACY, 
ACY, 
ACY, 
ATL. 
GAF, 
DUP. 
ACY, 
BKS, 
TRC. 
DUP. 
ALT, 
GAF. 
ATL, 
ATL, 
TRC. 
ALT, 
ATL, 
ATL, 
DUP. 
BKS, 
NAC. 
ALT, 
ALT, 
GAF. 
ACY. 
TRC. 
TRC. 
BKS. 
TRC. 
ACY. 
AAP,    ALT,    ATL,    BL,    DUP,    TRC,    VPC. 

AAP,    ATL,    BDO,    CWG,    NAC,    VPC. 

NAC. 

ATL, 

AAP, 

GAF. 

ACY, 

ATL, 

ATL, 

ACY, 

ACY, 

BKS, 

DUP. 

DUP. 

DUP, 

DUP, 

TRC. 

NAC, 

TRC. 

ATL, 

DUP, 

BL, 

DUP. 

DUP, 

DUP. 

DUP, 

DUP, 

GAF, 


DUP,  GAF,  NAC,  TRC. 

DUP,  GAF,  NAC,  TRC. 

BKS,  FAB,  TRC. 

ATL,  CMG,  DUP,  GAF,    NAC. 

CMG,  DUP,  GAF,  TRC. 

CMG,  DUP,  GAF. 


BKS,    FAB,    NAC,    TRC,    VPC. 
GAF,    TRC,    VPC. 
DUP. 


VPC. 

GAF,    NAC,    VPC. 

NAC. 


100 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


■  Bemenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  966— Continued 


Manufacturers'   Identifioatlon  codes 
(according  to  list  in  table  22) 


DIRECT  DYES — Continued 

•Direct  orange  dyes—Continued 

Direct  Orange  88— 

»Dlrect  Orange  102 

Direct  Orange  110 

Other  direct  orange  dyes 

•Direct  red  dyes : 

•Direct  Had  1 - - 

•Direct  Red  2 

•Direct  Red  U— 

Direct  Red  5 

Direct  Red  7 - 

•Direct  Red  10 

•Direct  Red  13— 

•Direct  Red  16- 

Direct  Red  20 

•Direct  Red  23 - 

•Direct  Red  2* 

•Direct  Red  26 — 

•Direct  Red  28— 

•Direct  Red  31 

Direct  Red  32 

•Direct  Red  37— — 

•Direct  Red  39— - — 

Direct  Red  40 

Direct  Red  53- — - 

Direct  Red  62 

•Direct  Red  72 

Direct  Red  73 

•Direct  Red  75 — 

Direct  Red  76 

•Direct  Red  79 

•Direct  Red  80 - — — 

•Direct  Red  81 

•Direct  Red  83 - 

•Direct  Red  8-1— — 

Direct  Red  94 

Direct  Red  95 

Direct  Red  100 

Direct  Red  111 

Qlrect  Red  117 

Direct  Red  120 • 

•Direct  Red  122 

Direct  Red  123— 

Direct  Red  139 

t«irect  Red  U9 - 

Direct  Red  152 

««a.rect  Rod  153— 

Direct  Red  155— - — 

Direct  Red  209 

Other  direct  red  dyes 

fflJlrect  violet  dyes: 

•Direct  Violet  1 

Direct  Violet  7 

•Direct  Violet  9 — 

Direct  Violet  U 

Direct  Violet  22 

Direct  Violet  30- ~ 

Direct  Violet  47 — 

Direct  Violet  48 

Direct  Violet  49 

Direct  Violet  51 

Direct  Violet  62 

Direct  Violet  66 

Direct  Violet  67 

Direct  Violet  68 

Other  direct  rlolet  dyes 

•Direct  blue  dyes: 

•Dlr»ot  Blue  1 


DUP. 

ACT,  DUP,  GAF,  NAC. 

TRC. 

ALT,  ATL,  BL,  DUP,  VPC. 

AAP,  ATL,  DUP,  GAF,  NAC,  TRC,  YAW. 

ATL,  BKS,  DUP,  NAC,  TRC. 

ATL,  NAC,  TRC,  VPC. 

NAC. 

ATL,  YAW. 

AAP,  ACT,  NAC. 

AAP,  ATL,  DUP,  NAC,  TRC,  YAW. 

ATL,  GAF,  NAC,  TRC. 

GAF,  NAC. 

ATL,  BKS,  CMC,  DUP,  FAB,  GAF,  NAC,  TRC. 

AAP,  ATL,  BKS,  BL,  FAB,  TRC,  VPC. 

AAP,  ATL,  DUP,  FAB,  GAF,  NAC,  TRC,  VPC. 

ATL,  BKS,  DUP,  NAC,  TRC. 

ATL,  DUP,  GAF,  NAC. 

DUP,  NAC. 

ATL,  GAF,  NAC,  TRC,  YAW. 

ATL,  GAF,  NAC,  TRC,  YAW. 

VPC. 

NAC. 

TRC. 

GAF,  NAC,  TRC. 

DUP,  NAC. 

ACT,  CMG,  DUP,  GAF. 

GAF,  NAC. 

ATL,  BKS,  CMG,  TRC,  VPC. 

AAP,  ATL,  BDO,  BKS,  BL,  CMG, 

VPC. 

AAP,  ACT,  ALT,  ATL,  BKS,  BL,  CMG,  DUP,  GAF,  NAC,  TRC, 

VPC,  YAW. 


FAB,  NAC,  SDH,  TRC, 


ALT,    ATL, 

BKS, 

BL, 

CMG, 

DUP, 

BKS,    GAF, 

NAC. 

NAC. 

VPC. 

NAC. 

GAF. 

BL,    DUP. 

VPC. 

aiG,    TRC, 

VPC. 

GAF. 

VPC. 

ATL,    CMG, 

DUP, 

GAF. 

CMG,   DUP. 

AAP,    ATL, 

CMG, 

NAC. 

GAF. 

TRC. 

ALT,    BL, 

TRC, 

VPC. 

AAP,    ATL, 

DUP, 

NAC. 

GAF,    NAC. 

ATL,    BKS, 

DUP, 

GAF, 

NAC 

TRC 

NAC. 

DUP. 

AAP. 

DUP,    GAF. 

DUP,    NAC. 

NAC. 

DUP,    NAC. 

ACT. 

ATL,    TRC. 

DUP,    NAC. 

DUP. 

ALT. 

AAP,   ACT, 

ATL, 

BKS, 

BL, 

DUP, 

YAW. 

,  FAB,  OAF,  NAC,  IHC,  VPC, 


TABLE  8B.  —Bemenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i 566— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


DIRECT  DYES— Continued 

»Direct  blue  dyes — Continued 

•Direct  Blue  2 

Direct  Blue  3 - - 

•Direct  Blue  6 

Direct  Blue  8 

•Direct  Blue  14 

•Direct  Blue  15 

Direct  Blue  21 - 

•Direct  Blue  22 

•Direct  Blue  24 

•Direct  Blue  25 

Direct  Blue  26 

Direct  Blue  27 

Direct  Blue  55 - 

Direct  Blue  61 

•Direct  Blue  67— - 

Direct  Blue  71— 

Direct  Blue  74 

Direct  Blue  75 - 

•Direct  Blue  76 

•Direct  Blue  78 

•Direct  Blue  80 

•Direct  Blue  86 

Direct  Blue  87— 

Direct  Blue  91— 

•Direct  Blue  98 

Direct  Blue  100 - - 

Direct  Blue  104 — 

•Direct  Blue  120  and  120A — 

•Direct  Blue  126 

Direct  Blue  130 - 

Direct  Blue  133 - — - 

Direct  Blue  136 

Direct  Blue  143 - 

Direct  Blue  151— - 

Direct  Blue  160— — 

Direct  Blue  189- - 

Direct  Blue  191 - 

Direct  Blue  199— 

Direct  Blue  218 ■ 

Direct  Blue  224 - 

Direct  Blue  238 - 

Other  direct  blue  dyes 

•Direct  green  dyes: 

•Direct  Green  1 

•Direct  Qreen  6 

•Direct  Green  8 

•Direct  Green  12 

Direct  Green  15 

Direct  Green  26 

Direct  Green  27 

Direct  Green  28 

Direct  Green  38 

Direct  Green  39 

Direct  Green  41 

Direct  Green  45 

Direct  Green  47 

Direct  Green  51 

Direct  Green  69 

Other  direct  green  dyes 

•Direct  brown  dyes: 

•Direct  Brown  1 

•Direct  Brown  lA 

•Direct  Brown  2 

•Direct  Brown  6 

Direct  Brown  11 

Direct  Brown  25 

Direct  Brown  27 

•Direct  Brown  31 


AAP,  ATL, 

BKS, 

BL,  DUP,  FAB,  GAF, 

NAC, 

TRC,  VPC, 

NAC. 

AAP,  ACY, 

ATL, 

BKS,  BL,  DUP,  GAF, 

NAC, 

TRC,  YAW. 

ATL,  DUP, 

GAF, 

NAC,  YAW. 

ATL,  BKS, 

NAC, 

TRC. 

ATL,  DUP, 

GAF. 

NAC,  YAW. 

TRC. 

ATL,  CMG, 

DUP, 

NAC. 

ATL,  BKS, 

NAC, 

TRC,  YAW. 

ATL,  DUP, 

GAF, 

NAC,  TRC,  YAW. 

ATL,  NAC. 

DUP. 

NAC. 

YAW. 

DUP,  NAC, 

TRC. 

DUP,  GAF, 

NAC, 

TRC. 

DUP. 

TRC. 

ALT,  ATL, 

BKS, 

BL,  DUP,  FAB,  GAF, 

NAC, 

TRC,  VPC. 

ATL,  CMG, 

DUP, 

GAF,  NAC,  TRC. 

ALT,  ATL, 

BKS, 

BL,  DUP,  FAB,  GAF, 

NAC, 

TRC. 

AAP,  ACY, 

A1.T, 

ATL,  BKS,  DUP,  FAB 

GAF 

ICC,  ICI, 

NAC,  SDH,  TMS,  TRC,  VPC. 

ICI. 

TRC. 

ALT,  ATL, 

GAF, 

NAC,  TRC,  VPC. 

ALT,  BKS. 

DUP. 

BKS,  CMC, 

DUP, 

GAF,  TRC. 

BL,  DUP, 

GAF, 

NAC,  TRC,  VPC. 

NAC. 

GAF. 

GAT. 

DUP. 

ATL,  NAC, 

TRC. 

TRC. 

BKS,  TRC. 

AAP,  GAF. 

GAF. 

BKS,  OAF, 

NAC. 

ATL. 

ACY. 

ALT,  BL, 

DUP, 

FAB,  GAF. 

AAP,  ACY, 

ATL, 

BKS,  DUP,  GAF,  NAC 

TRC 

YAW. 

AAP,  BKS, 

DUP, 

FAB,  GAF,  NAC,  TRC 

YAW 

ATL,  NAC, 

TRC, 

YAW. 

DUP,  NAC, 

TRC. 

DUP. 

TRC. 

NAC,  TRC. 

TRC. 

DUP,  GAF. 

GAF. 

DUP. 

VPC. 

DUP,  GAF. 

TRC. 

TRC. 

ACY,  ALT, 

ATL, 

BL,  DUP. 

ACY,  ATL, 

BKS, 

BL,  DUP,  FAB,  NAC. 

GAF,  TRC, 

YAW. 

AAP,  ACY, 

ATL, 

BKS,  BL,  DUP,  GAF, 

NAC, 

TRC,  YAW. 

DUP,  NAC, 

TRC. 

NAC. 

DUP,  NAC. 

OAF. 

AAP,  ATL, 

DUP, 

GAF,  NAC,  TRC,  YAW 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  iS66~  Continued 


Manufacturers'    Identification  codes 
(according  to  list  in  table  22) 


DIRECT  DYES— Continued 

»Direct  brown  dyes — Continued 

Direct  Brown  32 

Direct  Brown  33 

Direct  Brown  35 

Direct  Brown  4-0 

Direct  Brown  AA 

Direct  Brown  45 

Direct  Brown  48 

Direct  Brown  59 

•Direct  Brown  74 

♦Direct  Brown  95 

Direct  Brown  101 

Direct  Brown  105 

Direct  Brown  106 

♦Direct  Brown  111 

Direct  Brown  112 

Direct  Brown  125 

♦Direct  Brown  154 

Other  direct  brown  dyes 

♦Direct  black  dyes: 

♦Direct  Black  4 

Direct  Black  8 

♦Direct  Black  9 

Direct  Black  17 

♦Direct  Black  19 - - 

♦Direct  Black  22 

Direct  Black  36— 

Direct  Black  37 

♦Direct  Black  38- 

Direct  Black  AA 

Direct  Black  45 — — 

♦Direct  Black  51— 

Direct  Black  55 

Direct  Black  56 

Direct  Black  61 — 

Direct  Black  67 

Direct  Black  71 — 

Direct  Black  74 

Direct  Black  75 

Direct  Black  78 

♦Direct  Black  80 

Direct  Black  109 

Direct  Black  123 

Direct  Black  130 

Direct  Black  190 

Other  direct  black  dyes 

DISPERSE  DYES 

♦Disperse  yellow  dyes: 

Disperse  Yellow  1 

Disperse  Yellow  2 

♦Disperse  Yellow  3 

♦Disperse  Yellow  5 

Disperse  Yellow  8 

Disperse  Yellow  17 

♦Disperse  Yellow  23 

Disperse  Yellow  31 

Disperse  Yellow  32 

♦Disperse  Yellow  33 

♦Disperse  Yellow  34 

Disperse  Yellow  37 

♦Disperse  Yellow  42 

Disperse  Yellow  50 

Disperse  Yellow  54 

Disperse  Yellow  67 

Other  disperse  yellow  dyes 

♦Disperse  orange  dyes: 

♦Disperse  Orange  3 

♦Disperse  Orange  5 


GAF. 
DUP, 
NAC. 
AAP. 
GAP, 
VPC. 
AAP. 
ACY. 
AAP, 
AAP, 
GAP. 
DUP. 
GAP, 
DUP, 
NAC. 
GAP. 
DUP, 
ALT, 

ATI, 
TRC, 
BKS, 
GAP, 
BKS, 
AAP, 
AAP. 
AAP, 
AAP, 
TRC. 
TRC. 
AAP, 
DUP. 
NAC, 
TRC. 
DUP, 
VPC. 
NAC. 
OAF. 
BKS, 
AAP, 
GAP. 
NAC. 
ACY. 


ACY,    ALT,    ATL,    BL,    DUP,    VPC,    YAW. 


GAP,  NAC,  TRC,    YAW. 
BL,    DUP,    NAC,    VPC. 

BKS,  DUP,  GAP,    NAC,    TRC,    YAW. 

DUP,  GAP,  NAC,    TRC. 

TRC. 

GAP,  NAC,  TRC,    VPC. 

ALT,  ATL,  BKS,    CMG,    DUP,    GAP,    NAC,    TRC,    VPC,    YAW. 

DUP. 

ACY,  AIL,  BKS,    BL,    DUP,    PAB,    GAP,    NAC,    TRC,    YAW. 

DUP,  GAP,  NAC,    TRC. 

TRC. 

NAC. 


ATL,    BKS,    BL,    FAB,    NAC,    TRC,    VPC,    YAW. 


DUP, 

GAP. 

AAP, 

BKS, 

BL, 

DUP,    HCT,    GAF, 

HSH, 

ICC, 

NAC, 

SDH, 

TRC 

BKS. 

EKT, 

ICC. 

DUP, 

TRC. 

AAP. 

DUP, 

EKT, 

ICC. 

GAT. 

AAP, 

EKT, 

ICC, 

TRC. 

AAP, 

EKT, 

GAF, 

ICC. 

EKT, 

ICC. 

AAP, 

DUP, 

GAP, 

TRC. 

TRC. 

AAP, 

DUP, 

ICC, 

TRC. 

DW. 

DUP, 

EKT, 

GAF, 

ICC,    VPC. 

AAP,    BKS,    DUP,    EKT,    GAF,    HSH,    ICC,    NAC,    TRC. 
AAP,    HCT,    GAF. 


DYES 


-Bemenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  7966— Continued 


DISPERSE  DYES— Continued 

•Disperse  orange  dyes--C!ontlnued 

Disperse  Orange  16 

•Disperse  Orange  17 

Disperse  Orange  21 

Disperse  Orange  25 

Disperse  Orange  26 

Disperse  Orange  28 

Disperse  Orange  29 

Disperse  Orange  30 

Disperse  Orange  38 

Disperse  Orange  AA 

Other  disperse  orange  dyes 

•Disperse  red  dyes: 

•Disperse  Red  1 

Disperse  Red  i 

•Disperse  Red  5 

Disperse  Red  7 

Disperse  Red  9 

•Disperse  Red  11 

•Disperse  Red  13 

•Disperse  Red  15 

•Disperse  Red  17 

Disperse  Red  20 

Disperse  Red  21 

Disperse  Red  30 

Disperse  Red  31 

Disperse  Red  32 

Disperse  Red  53 

Disperse  Red  55 

Disperse  Red  56 

Disperse  Red  59 

•Disperse  Red  60 

Disperse  Red  61 

Disperse  Red  65 

Disperse  Red  66 

Disperse  Red  73 

Disperse  Red  78 

Disperse  Red  96 

Other  disperse  red  dyes 

•Disperse  violet  dyes: 

•Disperse  Violet  1 

•Disperse  Violet  A- 

Disperse  Violet  8 

Disperse  Violet  11 - - 

Disperse  Violet  14 

Disperse  Violet  18 - - 

Disperse  Violet  22 

Disperse  Violet  26 

•Disperse  Violet  27— 

Other  disperse  violet  dyes 

•Disperse  blue  dyes : 

•lisperse  Blue  1 — 

•Disperse  Blue  3 

ifljisperse  Blue  7 

Disperse  Blue  8 

Disperse  Blue  9 

Disperse  Blue  27 

Disperse  Blue  35 

Disperse  Blue  55 

Disperse  Blue  59 

Disperse  Blue  60 

Disperse  Blue  61 

Disperse  Blue  62 

Disperse  Blue  63 

•Disperse  Blue  6A 

Disperse  Blue  70 

Disperse  Blue  71 

Disperse  Blue  73 

Dlaperse  Blue  79 

Disperse  Blue  116 

Other  disperse  blue  dyes 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


BKS,    EKT,    HSH,    ICC,    NAC. 
TRC. 


BKS,    DUP,    EKT,    GAF,    HSH,    ICC,    NAC,    TRC,    YAW. 

TRC. 

BKS,    EKT,    GAF,    HSH,    ICC. 


DUP,  GAF,  TRC. 

BKS,  DUP,  GAF,  ICC. 

GAF,  HSH,  ICC,  NAC. 

BKS,  DUP,  EKT,  GAF,    HSH,    ICC,    TRC. 


DUP,    VPC. 
TRC. 


BKS,    DUP,    EKT,    GAF,    ICC,    TRC,    VPC. 


GAF,    HSH,    ICC,    TRC. 
GAF,    ICC. 


NAC. 
TRC. 


GAF,    TRC. 

BKS,    EKT,    GAF,    HSH,    ICC,    NAC,    TRC. 

BKS,    EKT,    GAF,    HSH,    ICC,    TRC. 


DUP,    EXT,    OAF,    HSH,    ICC,    VPC. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Bemenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  566— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


DISPERSE  DYES— Continued 

Disperse  green  dyes 

Disperse  brown  dyes: 

Disperse  Brown  1 

Disperse  Brown  2 

Other  disperse  brown  dyes 

^Disperse  black  dyes : 

^Disperse  Black  1 

Disperse  Black  2 

Disperse  Black  6 

Disperse  Black  7 

♦Disperse  Black  9 

Other  disperse  black  dyes 

FIBZR-REACTIVi:  DYES 

Reactive  yellow  dyes: 

Reactive  Yellow  1 

Reactive  Yellow  2 - 

Reactive  Yellow  3 - 

Reactive  Yellow  <♦ 

Reactive  Yellow  6- - 

Reactive  Yellow  7 — 

Reactive  Yellow  11 — 

Reactive  Yellow  13 

Reactive  Yellow  U 

Reactive  Yellow  15 

Reactive  Yellow  16 

Reactive  Yellow  17 - - 

Reactive  Yellow  18 — 

Reactive  Yellow  22 — 

Reactive  Yellow  24 

Other  reactive  yellow  dyes 

Reactive  orange  dyes: 

Reactive  Orange  1 

Reactive  Orange  A 

Reactive  Orange  5 

Reactive  Orange  7 

Reactive  Orange  12 

Reactive  Orange  13 

Reactive  Orange  K 

Reactive  Orange  16 

Other  reactive  orange  dyes 

Reactive  red  dyes: 

Reactive  Red  1 

Reactive  Red  2 

Reactive  Red  3 

Reactive  Red  4 

Reactive  Red  5 

Reactive  Red  8 

Reactive  Red  11 - 

Reactive  Red   13 - 

Reactive  Red  16 

Reactive  Bed  21 

Reactive  Red  29 - ■ 

Reactive  Red  31- • 

Reactive  Red  33- - 

Other  reactive  red  dyes 

Reactive  violet  dyes: 

Reactive  Violet  1 

Reactive  Violet  2 

Reactive  Violet  A 

Reactive  Violet  5- — 

Other  reactive  violet  dyes 

♦Reactive  blue  dyes: 

Reactive  Blue  1 

Reactive   Blue  2 

Reactive  Blue  3 

Reactive  Blue  4 

Reactive  Blue  5 

Reactive  Blue  7 


GAF, 

ICC. 

TRC. 

DUP, 

GAF. 

EKT, 

ICC. 

AAP, 

DUP,    GAF,    TRC. 

DUP, 

TRC. 

AAP. 

YAW. 

AAP, 

BL,    DUP,    OCT,    GAF. 

DUP, 

HCT,    GAF,    ICC,    VPC, 

YAW 

ICI. 

ICI. 

ICI. 

TRC. 

ICI. 

ICI. 

ICI. 

ICI. 

TRC. 

HST. 

ICI. 

HST,  ICI. 

ICI. 

DUP,  GAF. 

ICI. 
TRC. 
HST. 
HST. 


ICI. 
TRC. 
ICI. 
ICI. 
TRC. 
TRC. 


105 


■Bemenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i 566— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


FIBER-REACTIVE  DYES— Continued 

»Reactive  blue  dyes — Continued 

Reactive  Blue  9 

Reactive  Blue  18 

Reactive  Blue  19 

Reactive  Blue  21 -  — 

Reactive  Blue  25 

Reactive  Blue'  27 

Other  reactive  blue  dyes 

Reactive  green  dyes 

Reactive  brown  dyes: 

Reactive  Brown  1 

Reactive  Brown  10 

Reactive  black  dyes : 

Reactive  Black  1 

Reactive  Black  5 

Reactive  Black  9 

FLUORESCENT  BRIGHTINING  AGEMTS 

Fluorescent  Brightening  Agent  1 

Fluorescent  Brightening  Agent  6 

Fluorescent  Brightening  Agent  8 

Fluorescent  Brightening  Agent  9 

Fluorescent  Brightening  Agent  22 

Fluorescent  Brightening  Agent  24 

Fluorescent  Brightening  Agent  25 

»Fluorescent  Brightening  Agent  28 

Fluorescent  Brightening  Agent  30 

Fluorescent  Brightening  Agent  33 

Fluorescent  Brightening  Agent  34 

Fluorescent  Brightening  Agent  37 

Fluorescent  Brightening  Agent  45 

Fluorescent  Brightening  Agent  46 

Fluorescent  Brightening  Agent  49 

Fluorescent  Brightening  Agent  52 

Fluorescent  Brightening  Agent  54 

Fluorescent  Brightening  Agent  59 

Fluorescent  Brightening  Agent  61 

Fluorescent  Brightening  Agent  68 

Fluorescent  Brightening  Agent  71 

Fluorescent  Brightening  Agent  75 

Fluorescent  Brightening  Agent  102 

Fluorescent  Brightening  Agent  108 

Fluorescent  Brightening  Agent  113 

Fluorescent  Brightening  Agent  114 - 

Fluorescent  Brightening  Agent  125 

Fluorescent  Brightening  Agent  126 

Fluorescent  Brightening  Agent  128 

Fluorescent  Brightening  Agent  130 

Fluorescent  Brightening  Agent  134 

Fluorescent  Brightening  Agent  135 - 

Fluorescent  Brightening  Agent  136 

Fluorescent  Brightening  Agent  139 

Fluorescent  Brightening  Agent  155 

Fluorescent  Brightening  Agent  158 

Fluorescent  Brightening  Agent  159 

Fluorescent  Brightening  Agent  161 

Other  fluoreecait  brightening  agents 

FOOD,  DRUG,  AND  COSWETIC  COLORS 

Food,    Drug,    and  Cosmetic  Dyes 

»FD&C  Blue  No.    1— - - 

»FD&C  Blue  No.   2— 

FDtC  Green  No.   3 

•FDStC  Red  No.   2- 

•FDfcC  Red  No.   3 

»FD8tC  Red  No.   4- 

FDfcC  Violet  No.   1 


ICI. 

TRC. 

DUP, 

HST. 

DUP, 

HST. 

ICI. 

HST. 

DUP, 

GAF,    HST 

HST, 

ICI. 

TRC. 

ICI. 

TRC. 

HST. 

GGY. 

ACY. 

ACY. 

ACY,    GAF,    SDH. 

GGY. 

GGY. 

GAF. 

ACY,    CCW,    DUP. 

GAF. 

GAF. 

DUP. 

CIB. 

TRC. 

GGY. 

S. 

S. 

GGY. 

GGY. 

ACY. 

CCW,    GAF. 

ACY,    GAF. 

GAF. 

DUP. 

GAF. 

VPC. 

VPC. 

ACY. 

SDH. 

SDH. 

SDH. 

CIB. 

CIB. 

CIB. 

CIB. 

Wlil. 

ACY. 

ACY. 

ACY. 

ACY,    CCW,    CIB,    DUP,    GGY,    S.    VPC. 


WJ. 

ALT,    KON,    NAC,    SDH,    STG,    WJ. 

ALT,    KON,    NAC,    SDH,    STG. 

KON,    NAC,    SDH,    WJ. 

NAC. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


■Benzenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  566— Continued 


Manuf acturere '   identification  codes 
(according  to  list  in  table  22) 


FOOD,    DRDO,    AND  COSMEnC  COLOBS— Continued 

food.  Drug,   and  Comestic  Dyes --Continued 

«FD8cC  Yellow  No.    5 - 

»FD&C  Yellow  No.   6 

Other  food,   drug,    and  cosmetic  dyes 

Drug  and  Cosmetic  Dyes 

nScC  Blue  No.    6 — 

D6C  Blue  No.    9 

DStC  Brown  No.    1- - 

nStC  Green  No.    5—- — - 

D&C  Green  No.    6 - - 

DScC  Green  No.   8 

»DS:C  Orange  No.   4 

E&C  Orange  No.    5 

E&C  Orange  No.    10 

D&C  Orange  No.    17— 

D&C  Red  No.   3 - 

ntC  Red  No.    6 - 

»I&C  Red  No.    7 - 

D&C  Red  No.   8 — 

nS:C  Red  No.   9 - — 

DSrC  Red  No.    10 

D&C  Red  No.    11— - 

nSiC  Red  No.    12- 

nScC  Red  No.    13 - 

r&C  Red  No.    17— 

*1&.C  Red  No.    19-- 

»E&C  Red  No.   21 - 

E&C  Red  No.    22 — 

D&C  Red  No.   27 

nStC  Red  No.    28— - — 

DScC  Red  No.   30— - - 

ntC  Red  No.   31 — 

D6C  Red  No.   33 - 

D&C  Red  No.   3A 

»Dfi:C  Red  No.   36 

D&C  Red  No.   37 - 

DScC  Red  No.    39- • 

DScC  Violet  No.   2- 

V&C  Yellow  No.    5— - 

DfeC  Yellow  No.   6 

D&C  Yellow  No.   7 

DtC  Yellow  No.    8 

DkC  Yellow  No.    10 

E&C  Yellow  No.    11 

Drug  and  Cosmetic  Dyes,   External 

Bet.  D&C  Green  No.    1 

Ext.  D&C  Orange  No.  3 — 

Btt.  DScC  Red  No.   8 

Bet.  DScC  Violet  No.   2 

Bet.  nScC  Yellow  No.    1 

Bet.  DSrC  Yellow  No.   5 

Bet.  DfeC  Yellow  No.   7 

INGRAIN  DYES 

Ingrain  blue  dyes: 

Ingrain  Blue  1 

Ingrain  Blue  2 

Ingrain  Blue  3 

Ingrain  Blue  6 

UORDANT  DYES 

Mtordant  yellow  dyeo; 

Mordant  Yellow  1 


ALT,    KON, 

NAC, 

SDH,    STG,    WJ 

ALT,    KON, 

NAC, 

SDH,    STG,    WJ 

STG,    WJ. 

KON,    NAC. 

NAG. 

NAC. 

KON,    NAC. 

NAC. 

KON,    SDH. 

KON,    NAC, 

SNA. 

SNA,    IMS. 

TMS. 

KON,    SNA. 

KON. 

KON,    SNA, 

TMS. 

KON,    SNA, 

TMS. 

KON,  ms. 

KON,    SNA, 

TMS. 

KON,    SNA. 

KON,    SNA. 

SNA,    TMS. 

SNA,    TMS. 

KON,    NAC. 

KON,    NAC, 

SNA, 

TMS. 

KON,    SNA, 

TMS. 

KON. 

TMS. 

NAC. 

KON. 

KON. 

NAC. 

KON. 

KON,    SNA, 

TMS. 

NAC. 

SDH. 

NAC. 

KON,    TMS. 

KON. 

KON. 

KON,    NAC, 

TUS. 

KON,    NAC. 

NAC. 

KON,    NAC. 

KON,    NAC. 

SNA. 

KON. 

KON,    NAC. 

SNA. 

KON. 

OAF,    PDC,   TRC. 


DYES 


TABLE  8B.  --Bemenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i 566— Continued 


Manufacturers'    Identification  codes 
(according  to  list  in  table  22) 


MORDANT  DYES— Continued 


"Mordant  yellow  dyes — Continued 

Ktordant  Yellow  3- 

Itordant  Yellow  5 

"Mordant  Yellow  8 

Mordant  Yellow  10 

Itordant  Yellow  14 — - 

•Ktordant  Yellow  16 

MDrdant  Yellow  20 

Mordant  Yellow  26— 

Mordant  Yellow  29 — 

Itordant  Yellow  30 

Jtordant  Yellow  36 

"Mordant  orange  dyes: 

"Mordant  Orange  1 

Mordant  Orange  •i 

ktordant  Orange  6 

Ktordant  Orange  8 

Mordant  Orange  30 

"Mordant  red  dyes: 

Mordant  Red  3 

Ktordant  Red  5 

Mordant  Red  6 

<*tordant  Red  7 

<«Drdant  Red  9—- 

Itordant  Red  11— 

Mordant  Red   19 

Mordant  Red  64 

Mordant  violet  dyes: 

Mordant  Violet  11 - 

Ktordant  Violet  20— 

"Ktordant  blue  dyes: 

<4tordant  Blue  1 

Mordant  Blue  3 

Mordant  Blue  7 

Ktordant  Blue  9 

Ktordant  Blue  13— -. 

Mordant  Blue  19- 

Ktordant  green  dyes: 

Ktordant  Green  11 

Ktordant  Green  36 

Ktordant  Green  47 

"Mordant  brown  dyes: 

ifttordant  Brown  1 

Mordant  Brown  12 

Mordant  Brown  13 

Ktordant  Brown  15 

Ktordant  Brown  17 

Mordant  Brown  18 

Mordant  Brown  19 

Mordant  Brown  21 

"Mordant  Brown  33 


3wn  40 

Mordant  Brown  50 

Itordant  Brown  63 

Ktordant  Brown  70 

"Mordant  black  dyes: 

Ktordant  Black  1 

"Jtordant  Black  3 

"Mordant  Black  5 

Mordant  Black  7 

Mordant  Black  8 

itordant  Black  9' 

"Mordant  Black  11 

♦Mordant  Black  13 

Ktordant  Black  16 

"Ktordant  Black  17 

Mordant  Black  19 

Mordant  Black  26 

"Mordant  Black  38 


ATL,    NAC. 

TRC. 

DUP,    NAG,    VPC. 

DUP,    NAC. 

NAC,    TRC. 

ACY,    DUP,    NAC. 

NAC. 

VPC. 

GAF. 

TRC,    VPC. 

PDC. 

ACY,    GAF,    PDC,    TRC 

GAF. 

ATL,    GAF,    TRC. 

TRC. 

NAC. 

ACY,    NAC. 

PDC. 

GAF. 

ACY,    BDO,    CMG,    GAF, 

NAC,    PDC,    TRC,    VPC. 

GAF,    MRX,    NAC. 

ACY,    NAC. 

PDC. 

PDC. 

GAF. 

GAF. 

DUP,    GAF,    NAC,    TRC. 

GAF. 

TRC. 

GAF,    NAC. 

HSH,    NAC. 

CMG. 

ACY. 

PDC. 

NAC. 

CMG,    DUP,    GAF,    NAC, 

TRC,    YAW. 

PDC. 

NAC. 

GAF. 

CMG. 

DUP,    NAC. 

GAF. 

GAF,    VPC. 

DUP,    GAF,    NAC,    TRC. 

CMG,    DUP,    GAF,    NAC, 

VPC,    YAW. 

TRC. 

TRC. 

DUP,    PDC. 

GAF,    NAC. 

GAF,    NAC,    TRC. 

NAC,    TRC. 

GAF. 

VPC. 

NAC,    VPC. 

GAF,    NAC,    TRC,    VPC. 

GAF,    HSH,    NAC,    TRC. 

NAC,    PDC. 

ACY,    DUP,    GAF,    NAC, 

TRC. 

PDC. 

TRC. 

CWG,    GAF,    NAC. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Bemenotd  dyes  for  which  U.S.  production  or  sal 
manufacturer,  i 966— Continued 


reported,  identified  by 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


OXIDATION  BASES 

CKidation  Base  8  and  8A 

Oxidation  Base  21 

Oxidation   Base  22 

Oxidation  Base  25 

Other  oxidation  bases 

SOLVIHT  DYES 

•Solvent  yellow  dyes : 

Solvent  Yellow  1 

•Solvent  Yellow  2 

•Solvent  Yellow  3 

Solvent  Yellow  13 

•Solvent  Yellow  U--- -- 

Solvent  Yellow  16 --- 

Solvent  Yellow  19 -  — 

Solvent  Yellow  29 

Solvent  Yellow  30 

Solvent  Yellow  33 

Solvent  Yellow  34 

Solvent  Yellow  40 

Solvent  Yellow  42 —  - 

Solvent  Yellow  43 

Solvent  Yellow  44 

Solvent  Yellow  45 

Solvent  Yellow  47 

Solvent  Yellow  56 

Solvent  Yellow  71 

Solvent  Yellow  72  — - 

Other  solvent  yellow  dyes 

•Solvent  orange  dyes : 

Solvent  Orange  1 

Solvent  Orange  2 

•Solvent  Orange  3 

Solvent  Orange  5 

•Solvent  Orange  7 

Solvent  Orange  20 

Solvent  Orange  23 

Solvent  Orange  24 

Solvent  Orange  25 

Solvent  Orange  31 

Solvent  Orange  47 

Solvent  Orange  48 

Solvent  Orange  51 

Other  solvent  orange  dyes 

•Solvent  red  dyes : 

Solvent  Red  8 

Solvent  Red  22 - 

•Solvent  Red  24 

•Solvent  Red  26 — 

Solvent  Red  27 

Solvent  Red  33 —  - — 

Solvent  Red  34 

Solvent  Red  35 

Solvent  Red  36 

Solvent  Red  40 

Solvent  Red  41 - — 

•Solvent  Red  49 

Solvent  Red  52 

Solvent  Red  65 - 

Solvent  Red  68 

Solvent  Red  69 

Solvent  Red  74 

Solvent  Red  75 

Solvent  Red  76 

Solvent  Red  80 

Solvent  Red  105 

Solvent  Red  108 

Solvent  Red  111 

Solvent  Red  115 

Other  solvent  red  dyes 


AAP, 

DUP, 

FH, 

GAF,  PAT, 

PSC. 

DUP, 

FH, 

GAF, 

NAC,  PSC. 

ACY, 

GAF, 

TRC 

AAP, 

ACY, 

DUP 

FH,  GAF, 

NAC,  PAT, 

PSC, 

SDH. 

PAT. 

GAF. 

GAF. 

NAC, 

PSC. 

ACY, 

NAC. 

DUP. 

NAC. 

NAC. 

GAF. 

GAF, 

NAC 

DUP. 

NAG 

ACY, 

DUP, 

GAF 

NAC. 

ACY, 

FH, 

NAC. 

AAP,    ACY,    DSC,    PAT. 


ACY, 

GAF, 

NAC, 

PSC. 

GAF, 

TRC. 

ACY, 

GAF, 

NAC. 

ACY, 

GAF. 

NAC. 

DUP. 

ACY, 

DUP. 

NAC. 

FH. 

ACY. 

ACY. 

AAP, 

ACY, 

DSC, 

DUP, 

PAT 

GAF. 

GAF. 

ACY, 

DUP, 

GAF, 

PAT, 

SDH 

AAP, 

ACY, 

FH, 

HAC, 

PSC. 

NAC. 

DUP, 

GAF. 

DUP. 

GAF. 

NAC. 

GAF. 

asc. 

ACY, 

DSC, 

DUP, 

GAF. 

GAF, 

ICI. 

NAC. 

NAC. 

DUP. 

NAC. 

NAC. 

NAC. 

ACY, 

NAC. 

ACY. 

ACY. 

ACY. 

ACY. 

AAP, 

ACY, 

DSC, 

DUP, 

GAF, 

DYES 


TABLE  8B.  --  Bemenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  566- -ConUnued 


Manufacturers'  identification  code 
(according  to  list  in  table  22) 


SOLVHfT  DYES— Continued 

"Solvent  violet  dyes: 

"Solvent  Violet  8 - 

Solvent  Violet  9 - 

Solvent  Violet  13 - 

Solvent  Violet  U— 

Solvent  Violet  17 - — 

Other  solvent  violet  dyes 

Solvent  blue  dyes: 

Solvent  Blue  3 — 

Solvent  Blue  A 

Solvent  Blue  5 

Solvent  Blue  6 

Solvent  Blue  7 

Solvent  Blue  9— 

Solvent  Blue  11 

Solvent  Blue  12 

Solvait  Blue  16 

Solvent  Blue  32 

Solvent  Blue  36 

Solvent  Blue  37 

Solvent  Blue  38 

Solvent  Blue  39 

Solvent  Blue  43 

Solvent  Blue  58 

Solvent  Blue  59 

Solvent  Blue  60 

Solvent  Blue  74- 

Other  solvent  blue  dyes 

"Solvent  green  dyes; 

Solvent  Green  1 

Solvent  Green  2 

"Solvent  Green  3 

Solvent  Green  10 

Solvent  Green  11 

Other  solvent  green  dyes 

"Solvent  brown  dyes : 

Solvent  Brown  11 

"Solvent  Brown  12 

Solvent  Brown  17 

Solvent  Brown  19 

Solvent  Brown  20 

Solvent  Brown  22 

Solvent  Brown  38 

Other  solvent  brown  dyes 

Solvent  black  dyes: 

Solvent  Black  3 - — 

Solvent  Black  5 — - 

Solvent  Black  7 

Solvent  Black  12 - - 

Solvent  Black  13 

Solvent  Black  17— 

Solvent  Black  26 

Other  solvent  black  dyes 

SULFUR  DYES 

Sulfur  yellow  dyes: 

Sulfur  Yellow  2 

Leueo  Sulfur  Yellow  2 

Sulfur  Yellow  i. 

Leuco  Sulfur  Yellow  4 

Leuco  Sulfur  Yellow  15 

Other  sulfur  yellow  dyes 

Sulfur  orange  dyes: 

Sulfur  Orange  1 

Leuco  Sulfur  Orange  1 

Sulfur  red  dyes: 

Sulfur  Red  1 - 

Leuco  Sulfur  Red  5 

•Sulfur  Red  6- - 


ACY, 

DSC, 

NAC. 

DSC. 

AAP, 

HSH, 

ICI. 

ICI. 

NAC. 
DSC, 

PAT. 

ACY. 

sw. 

DSC, 

DUP, 

SDH. 

DSC. 

DSC. 

ACY, 

NAC. 

GAF. 

GAF. 

ICI. 

DUP, 

NAC. 

NAC. 

AAP. 

DUP, 

NAC. 

DUP. 

ACY, 

DUP, 

NAC. 

NAC. 

NAC. 

ACY. 

ACY. 

ACY. 

NAC. 

AAP, 

ACY, 

DSC,    GAF,    ICI,    PAT, 

ACY, 

DSC, 

SDH. 

GAF. 

AAP, 

ACY, 

ATL,    GAF,    HSH,    NAC 

DUP. 

DUP. 

DSC. 

GAF. 

ACY, 

DSC, 

GAF. 

DUP. 

DUP. 

ACY, 

DUP. 

FH. 

ACY. 

DSC. 

NAC. 

ACY, 

DSC. 

NAC. 

ACY, 

DSC, 

FH,    NAC. 

NAC. 

NAC. 

DUP. 

ACY. 

ACY, 

DSC. 

SDC. 

ACY, 

SDC. 

AUG, 

DUP, 

SDC. 

SDC. 

ACY. 

ACY, 

SDC. 

SDC. 

SDC. 

ACY, 

NAC. 

SDC. 

ACY, 

DUP, 

NAC.    SDC 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Bemenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  966— Continued 


SULFUR  DYiS— Continued 


Sulfur  red  dyee— Continued 

Leuco  Sulfur  Red  6 

Sulfur  Red  8 

Sulfur  blue  dyes: 

»Sulfur  Blue  7 

Leuoo  Sulfur  Blue  7 

Leuco  Sulfur  Blue  8 

Sulfur  Blue  9 — 

Leuco  Sulfur  Blue  9— 

•Sulfur  Blue  11 

Leuoo  Sulfur  Blue  13 

Sulfur  Blue  15— 

Other  sulfur  blue  dyee 

Sulfur  green  dyes: 

Sulfur  Green  1 

Leuoo  Sulfur  (Jreen  1 

Sulfur  Green  2 

Leuco  Sulfur  Green  2 

Sulfur  Green  3 

Sulfur  Green  14 

Sulfur  Green  16 

Leuoo  Sulfur  Green  16 

Sulfur  Green  28 

Other  sulfur  green  dyes 

Sulfur  brown  dyes: 

Sulfur  Brown  3 

Leuoo  Sulfur  Brown  3 

Sulfur  Brown  10 

Leuoo  Sulfur  Brown  10 

Solubillzed  Sulfur  Brown  10- 

Leuoo  Sulfur  Brown  12 

Sulfur  Brown  14 

Leuoo  Sulfur  Brown  14 

Sulfur  Brown  20 

Sulfur  Brown  21 

Sulfur  Brown  26 

Sulfur  Brown  30 

Sulfur  Brown  33 

Sulfur  Brown  37 - 

Leuco  Sulfur  Brown  37 

Sulfur  Brown  39 

Sulfur  Brown  43 

Sulfur  Brown  44 - 

Leuco  Sulfur  Brown  44 

Sulfur  Brown  45 

Sulfur  Brown  50 

Sulfur  Brown  76 

Leuoo  Sulfur  Brown  82 

Other  sulfur  brown  dyes 

Sulfur  black  dyes: 

«Sulfur  Black  1 

Leuoo  Sulfur  Black  1 

Sulfur  Black  2 — 

Leuoo  Sulfur  Black  2- 

Sulfur  Black  6- 

Leuoo  Sulfur  Black  6 

Sulfur  Black  10 

Leuoo  Sulfur  Black  10 

Sulfur  Black  11 

Leuoo  Sulfur  Black  11 

Other  sulfur  black  dyes 


<«Vat  yellow  dyes: 

Vat  Yellow  1,  12-1/251- 

•Vat  Yellow  2,  8-l/2lt- 

Solubllized  Vat  Yellow  2,  255^- 
Vat  Yellow  3,  12-1/2*- 

•Vat  Yellow  4,  12-l/25t- - 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


ACY, 

ACY, 

SDC. 

ACY, 

SDC. 

DUP, 

ACY. 

ACY,  1 

ACY,  i 

NAG. 

NAC. 

NAC,  . 

SDC. 

NAC. 

DUP. 

SDC. 

SDC. 

ACY. 

AUG, 

SDC. 
SDC, 
DUP, 
SDC. 
AUG. 
SDC. 
ACY. 
ACY, 
DUP. 
DUP. 
ACY, 
ACY. 

ACY. 
SDC. 

SDC. 

SDC. 

NAC. 

NAC 

NAC. 

NAC. 

NAC. 

ACY. 

ACY. 

ACY, 

ACY, 
ACY, 
ACY, 
ACY, 
GAF. 
NAC. 
ACY. 
ACY, 


DUP,  NAC,  SDC. 
NAC,  SDC. 


NAC. 
NAC,  SDC. 


AUG,  SDC. 

DUP,  NAC,  SDC. 

AUG,  NAC,  SDC. 

DUP,  NAC,  SDC. 

NAC,  SDC. 


AAP,  DUP,  GAF,  ICI,  NAC,  TRC,  VPC. 

GAF,  ICI. 

DUP. 

ACY,  ATL,  CMG,  GAF,  HST,  ICI,  NAC,  VPC. 


DYES 


■Bemenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  7566— Continued 


Manuf aoturers •   Identification  codes 
(according  to  list  in  table  22) 


VAT  DYES— Continued 

•KVat  yellow  dyes — Continued 

»Solubillzed  Vat  Yellow  A,   37-l/2^t 

Vat  Yellow  10,    10!« 

Vat  Yellow  13,    6-1/256 

Vat  Yellow  U,  12-l/25( 

Vat  Yellow  15,  ll-l/25t— 

Vat  Yellow  22,  lO^J 

Vat  Yellow  27 

Vat  Yellow  33,  IS^t- 

Vat  Yellow  Al,    9<^--- 

Other  vat  yellow  dyes 

»Vat  orange  dyes : 

•Vat  Clrange  1,   205t 

•Solubillzed  Vat  Orange  1,   26* 

»Vat  Orange  2,    125t 

•Vat  Orange  3,    13-l/25t 

Vat  Orange  A,   65t 

•Vat  Orange  5,    IO56 

•Solubillzed  Vat  Orange  5,   30?t 

•Vat  Orange  7,    11*-- 

•Vat  Orange  9,    125t - - 

Vat  Orange  11,    6^6 

•Vat  Orange  15,    10*- 

Vat  Orange  23,    17-1/2*-- 

Vat  Orange  24 

Other  vat  orange  dyes 

•Vat  red  dyes: 

•Vat  Red  1,    13* 

Solubilized  Vat  Red  1,   37*- - - 

•Vat  Red  10,    18*— - 

Solubilized  Vat  Red  10,  31* 

Vat  Red  12,  8-1/2* 

•Vat  Red  13,  11* --- 

Vat  Red  W,  10*-— — - 

•Vat  Red  15,  10*- 

Vat  Red  16,  11* 

Vat  Red  17,  10*- - 

Vat  Red  23- - 

Vat  Red  29,  18* 

•Vat  Red  32,  20*- 

Vat  Red  35,  12-1/2* - - 

Vat  Red  Al,   20* 

Vat  Red  44,  17*- — 

Vat  Red  52,  10*- - 

Vat  Red  53,  12*- — ■ 

Vat  Red  62 - 

Other  vat  red  dyes 

•Vat  violet  dyes: 

•Vat  Violet  1,  11*- - 

Solubilized  Vat  Violet  1,  26*- • 

•Vat  Violet  2,  20* 

Vat  Violet  3,  15*- 

•Vat  Violet  9,  12*- — 

•Vat  Violet  13,  6-1/4* - 

Vat  Violet  14,  12-1/2*- — • 

•Vat  Violet  17,  12-1/2*-— • 

Other  vat  violet  dyes 

•Vat  blue  dyes: 

Vat  Blue  1,  20*- - - 

Solubilized  Vat  Blue  1,  25*- 

Vat  Blue  4,  10* 

Vat  Blue  5,  16* — 

Solubilized  Vat  Blue  5,  38*-— 

*Vat  Blue  6,  8-l/3!t- 

Solubilized  Vat  Blue  6,  17-1/2*- — ■ 

Vat  Blue  7,  12-1/2* 

Solubilized  Vat  Blue  9,   35* - - 

Vat  Blue  12,    6-1/2*—- 

Vat  Blue  14,   8-1/3* 

<*Vat  Blue  16,    16-1/2*- - 


OAF, 

HST, 

ICI. 

GAF. 

ICI. 

TRC. 

ACY. 

DUP, 

GAF. 

VPC. 

TRC. 

ACY. 

MAY, 

NAC, 

VPC. 

CMC, 

GAF, 

HST. 

ICI. 

NAC. 

TRC. 

VPC 

GAF, 

HST, 

ICI. 

ACY, 

CMG. 

DUP, 

GAF, 

ICI, 

NAC, 

TRC 

CMG, 

DUP, 

GAF. 

HST, 

NAC. 

ACY, 

CMG, 

DUP. 

AAP, 

ACY, 

HST. 

QAF, 

HST, 

ICI. 

GAF, 

HST, 

TRC. 

ACY, 

CMG. 

DUP. 

GAF. 

ICI, 

NAC, 

TRC 

DUP, 

NAC. 

AAP, 

GAF, 

ICI. 

MAY. 

NAC. 

TRC. 

VPC 

ACY, 

DUP. 

GAF. 

DUP. 

SDC. 

AAP, 

ACY. 

HST. 

ICI. 

GAF, 

HST, 

ICI. 

GAF, 

NAC. 

TRC. 

GAF. 

DUP. 

DUP, 

GAF, 

TRC. 

GAF, 

HST. 

GAF, 

HST, 

TRC. 

DUP. 

GAF. 

DUP. 

GAF, 

NAC. 

DUP, 

GAF, 

NAC. 

NAC, 

TRC. 

HST. 

TRC. 

DUP. 

DUP. 

DUP. 

DUP, 

GAF, 

TRC, 

VPC. 

ACY, 

DUP. 

GAF. 

ICI. 

MAY. 

NAC, 

TRC. 

GAF. 

ACY, 

GAF, 

HST, 

NAC, 

VPC. 

GAF, 

HST. 

NAC. 

DUP, 

GAF. 

ICI. 

MAY, 

NAC, 

TRC. 

DUP. 

GAF, 

TCI, 

NAC. 

TRC. 

NAC. 

DUP, 

GAF. 

NAC. 

MAY. 

NAC. 

GAF. 

AAP, 

ACY, 

DUP. 

GAF. 

ATL, 

DUP, 

HST. 

NAC. 

VPC 

GAF, 

HST. 

ACY, 

DUP. 

GAF. 

ICI. 

UAY. 

NAC, 

TRC. 

GAF, 

HST. 

TCI. 

NAC. 

GAF. 

DUP. 

DUP, 

GAF, 

NAC, 

TRC. 

ACY, 

DUP, 

ICI, 

NAC. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  8B.  --Bemenoid  dyes  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  966— Continued 


VAT  DYES— Continued 


Manufacturers '    identification  codes 
(according  to  list  in  table  22) 


*Vat  blue  dyes--Continued 

*Vat  Blue  18,    135t 

»Vat  Blue  20,    U,i 

Vat  Blue  26,   24it 

Vat  Blue  29 

Vat  Blue  35,   20^ 

Vat  Blue  39,    12?t- 

Vat  Blue  42 

Vat  Blue  A3 

Vat  Blue  53,   20-l/2']( 

Vat   Blue  60 

Other  vat  blue  dyes 

■»Vat  green  dyes : 

*Vat  Green  1,    6St- 

Solubilized  Vat  Green  1,  12-l/25t— 

»Vat  Green  3,  lO^t 

»Solubilized  Vat  Green  3,  26%- 

»Vat  Green  8,  8-1/2* 

»Vat  Green  9,  12-l/2?6 

Vat  Green  15,  17* 

Vat  Green  18,  8* — 

Vat  Green  20,  6* 

Other  vat  green  dyes 

»Vat  brovm  dyes : 

»Vat  Brown  1,  11* 

Solubilized  Vat  Brorni  1,  17* 

»Vat  Brown  3,  11* 

»Vat  Brown  5,  13* 

Vat  Brown  11,  12* - 

Vat  Brown  12,  12-l/2'> 

Vat  Brown  13,  17* 

Vat  Brown  20,  10-1/2* 

Vat  Brown  25,  11-1/2*- - 

Vat  Brown  28,  22*-— 

Vat  Brown  29,  13* 

Vat  Brown  31,  28*- 

Vat  Brown  38,  20* 

Vat  Brown  40,  14*- 

Vat  Brown  53 

Vat  Brown  57,  15*- 

Other  vat  brown  dyes 

»Vat  black  dyes : 

Vat  Black  1 

Solubilized  Vat  Black  1,  27-1/2*— 

*Vat  Black  9,  16* 

Vat  Black  11,  17-1/2* 

Vat  Black  13,  14* 

Vat  Black  14,  11-1/2* 

Vat  Black  15 — 

Vat  Black  18,  15-1/2* 

Vat  Black  21,  18-1/2* 

Vat  Black  22,  19* 

»Vat  Black  25,  12-1/2* 

»Vat  Black  27,  12-1/2* 

Vat  Black  34,  16*- 

Vat  Black  37 

Vat  Black  38,  20* — 

Vat  Black  52,  18-1/2* 

Other  vat  black  dyes 

All  other  dyes 


AAP, 
AAP, 
GAF. 
GAF. 
HST. 
GAF. 
SDC. 
SDC. 
GAF. 
DUP. 
MAY, 

AAP, 
GAF, 
AAP, 
GAF, 
ATL, 
ACY, 
NAC. 
DUP. 


DUP. 
GAF. 
GAF, 
DUP, 

GAF. 
GAF, 
ATL, 
ACY. 
DUP, 
DUP. 
AAP. 
GAF, 
ACY. 
ACY, 
AAP, 
AAP, 
ICI. 
GAF. 
GAF. 
ACY. 
DUP, 
ACY, 


ACY,  DUP,  GAF,  MAY,  NAC,  TRC. 

ACY,  ATL,  DUP,  GAF,  ICI,  MAY,  NAC,  SDC,  TRC. 


SDC,  VPC,  X. 

ACY,  DUP,  GAF,  ICI,  MAX. 

HST,  ICI. 

ACY,  ATL,  DUP,  GAF,  ICI,  MAY,  NAC,  TRC. 


ATL,  DUP,  GAF,  MAY,  NAC,  SDC,  TRC. 


DUP,  GAF,  ICI,  MAY,  NAC,  TRC. 

ICI. 

ACY,  DUP,  GAF,  ICI,  MAY,  NAC,  TRC,  VPC. 

ACY,  GAF,  HST,  VPC. 

TRC. 

NAC. 


GAF,  NAC. 


ACY,  DUP,  GAF,  ICI,  MAY,  NAC,  TRC. 
ACY,  DUP,  GAF,  ICI,  MAY,  NAC,  TRC,  VPC. 


GAF,  SDC,  TRC. 
PAT,  SDC. 


PIGMENTS 
Pigments 


TABLE  ilB.—Bemenoid  pigments  for  which  U.S.  production  i 
by  manufacturer,  1966 


sales  were  reported,  identified 


[Benzenoid  pigments  for  which  separate  statistics  are  given  in  table  llA  are  marked  below  with  an  asterisk   (»); 
products  not  so  marked  do  not  appear  in  table  llA  because  the  reported  data  are  accepted  in  confidence  and  may 
not  be  published.   Manufacturers'   identification  codes  shown  below  are  taken  from  table  22.   An  x  signifies  that  the 
manufacturer  did  not  consent  to  his  identification  with  the  designated  product] 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


TONERS 

♦Yellow  toners; 
»Hansa  yellows: 

•Pigment  Yellow  1,  C.I.  11  680 

•Pigment  Yellow  3,  C.I.  11  710 

Pigment  Yellow  A,    C.I.  11  665 ■ 

Pigment  Yellow  5,    C.I.  11  660 

Pigment  Yellow  6,  C.I.  11  670 

Pigment  Yellow  9,    C.I.  11  720- 

Pigment  Yellow  49,  C.I.  11  765 

Pigment  Yellow  65,  C.I.  11  740 

•Pigment  Yellow  73 

•Pigment  Yellow  74,  C.I.  11  741 

All  other  Hansa  yellows 

•Benzidine  yellow: 

•Pigment  Yellow  12,  C.I.  21  090 

•Pigment  Yellow  13,  C.I.  21  100 

•Pigment  Yellow  14,  C.I.  21  095 

•Pigment  Yellow  17,  CI.  21  105 

Pigment  Yellow  83 

All  other  benzidine  yellows 

Pigment  Yellow  10,  C.I.  12  710 

Pigment  Yellow  18,  C.I.  49  005 

Pigment  Yellow  60,  C.I.  12  705 

(Basic  Yellow  2),  C.I.  41,000  fugitii 

(Vat  Yellow  1),  C.I.  70  600— — - 

(Vat  Yellow  20),  C.I.  68  420 

All  other 

•Orange  toners: 

Pigment  Orange  1,  C.I.  11  725 — 

•Pigment  Orange  2,  C.I.  12  060 

•Pigment  Orange  5,  C.I.  12  075 

•Pigment  Orange  13,  C.I.  21  110 

Pigment  Orange  15,  C.I.  21  130 

•Pigment  Orange  16,  C.I.  21  160— 

Pigment  Orange  30 

(Vat  Orange  1),  C.I.  59  105 

(Vat  Orange  2),  C.I.  59  705 

(Vat  Orange  3),  C.I.  59  300- 

(Vat  Orange  4),  C.I.  59  710— — 

»(Vat  Orange  7),  C.I.  71  105- — 

All  other - - -- 

•Red  toners: 
•Naphthol  reds: 

•Pigment  Red  2,  C.I.  12  310 

•Pigment  Red  5,  C.I.  12  490 — 

Pigment  Bed  7,  C.I.  12  420 

Pigment  Red  9,  C.I.  12  460 

Pigment  Red  10,  C.I.  12  440- 

•Pigment  Red  13,  C.I.  12  395 

Pigment  Red  14,  C.I.  12  380— 

Pigment  Red  15,  C.I.  12  465 

•Pigment  Red  17,  C.I.  12  390 

•Pigment  Red  18,  C.I.  12  350— 


ACY,  AMS,  DUP,  FCL,  GAF,  HSC,  HSH,  ICI,  IMP,  KON,  NAC, 

PPG,  S,  SDH,  SNA,  SW. 
HSC,  HSH,  HST,  IMP,  KCW,  KON,  NAC,  PPG,  S,  SW. 
NAC,  SNA. 
IMP. 
IMP. 
SNA. 
ICI. 
SW. 

NAC,  SNA,  SW,  X. 
DUP,  SDH,  SW. 
DUP,  HSC,  KCW. 

ACY,  AMS,  CIK,  DUP,  FCL,  GAF,  HSC,  HSH,  ICC,  IMP,  KON, 

LVY,  MRX,  NAC,  S,  SDH,  SNA,  SW. 

BUC,  FCL,  GAF,  HSC,  HSH,  HST,  ICC,  IMP,  ROM,  SDH,  SNA, 

SW. 

ACY,  AMS,  BUC,  CIK,  CPC,  DUP,  FCL,  GAF,  HSC,  HSH,  HST, 

ICC,  IMP,  KON,  MRX,  NAC,  ROM,  S,  SDH,  SNA,  SW,  x. 

ACY,  BUC,  DUP,  FCL,  HSH,  HSC,  HST,  ICC,  IMP,  SDH,  SNA, 


IMP,  ROM,  S,  SW. 


IMP,  S,  SW. 

KCW,  NAC. 

FCL,  IMP,  SDH,  SW. 

ACY,  HSC,  IMP,  SNA,  SW. 

ACY,  AMS,  HSC,  IMP,  KON,  NAC,  SNA,  SW. 

GAF,  NAC. 

BUC,  DUP,  FCL,  GAF,  HSH,  HST,  ICC,  IMP,  NAC,  ROM,  SDH, 

SNA,  SW. 
SNA. 
HST. 
GAF. 

NAC,  TRC. 
NAC. 

GAF,  HST,  NAC. 
BUC,  HSH,  ICC,  KON,  ROM,  SDH. 


GAF,  HSC,  IMP,  KCW,  KON,  MRX,  NAC,  SDH,  SW. 

DUP,  GAF,  HSH,  HST,  ICC,  ICI,  IMP,  NAC,  ROM,  S,  SDH, 


HST, 
AMS, 

NAC. 
HSH, 

ICC 

IMP. 
SW. 

MRX. 
NAC, 
NAC. 
ACY, 

TRC. 
GAF, 

ICC 

IMP. 

KCW. 

IMP,  KCW,  NAC,  SW. 

DUP. 

DUP. 

ACY,  BLN,  FCL,  ICC,  IMP,  S,  SNA,  UHL. 

IMP,  NAC,  SW. 


See  note  at  end  of  table  for  definition  of  abbreviations. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  IIB. 


■Benzenoid  pigments  for  which  U.S.  production  or  sales  were  reported,  identified 
by  manufacturer,  iSfiff— Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


TONERS— Continued 

»Red  toners — Continued 
»Naphtliol  reds--Continued 

Pigment  Red  19,  C.I.  12  -iOO- - ■ 

»Pigment  Red  22,  C.I.  12  315 

♦Pigment  Red  23,  C.I.  12  355 

Pigment  Red  31,  C.I.  12  360 

All  other  naphthol  reds 

♦Pigment  Red  1,  C.I.  12  070,  dark - 

♦Pigment  Red  1,  C.I.  12  070,  light — 

♦Pigment  Red  3,  C.I.  12  120 • 

♦Pigment  Red  A,   G.I.  12  085 - • 

♦Pigment  Red  6,  C.I.  12  090 

♦Pigment  Red  38,  C.I.  21  120 ■ 

Pigment  Red  -H,  C.I.  21  200 

♦Pigment  Red  A8,    C.I.  15  865— — 

Pigment  Red  A9,  C.I.  15  630: 
♦Barium  toner 

♦Calcium  toner 

♦Sodium  toner 

♦Pigment  Red  52,  C.I.  15  860 

♦Pigment  Red  53,  C.I.  15  585,  barium  toner- 
Pigment  Red  53,  C.I.  15  585,  sodium  toner- 

♦Pigment  Red  54,  C.I.  14  830,  calcium  toner- 
Pigment  Red  55,  C.I.  15  820 

♦Pigment  Red  57,  C.I.  15  850,  calcium  toner- 
Pigment  Red  58,  C.I.  15  825 

♦Pigment  Red  63,  C.I.  15  880 

Pigment  Red  64,  C.I.  15  800 — 

Pigment  Red  77,  C.I.  15  826 

Pigment  Red  79,  PMA - 

Pigment  Red  81,  C.I.  45  160,  fugitive - 

♦Pigment  Red  81,  C.I.  45  160,  PMA 

♦Pigment  Red  81,  C.I.  45  160,  PTA— - 

Pigment  Red  87,  C.I.  73  310 - 

Pigment  Red  88 

♦Pigment  Red  90,  C.I.  45  380 - 

Pigment  Red  117,  C.I.  15  603 

Pigment  Red  122 - 

Pigment  Red  123 

(Vat  Red  1),  C.I.  73  360 

(Vat  Red  10),  C.I.  67  000 

(Vat  Red  23),  C.I.  71  130- 

(Vat  Red  29),  C.I.  71  140 

All  other 

♦Violet  toners: 

Pigment  Violet  1,  C.I.  45  170,  fugitive-— 

♦Pigment  Violet  1,  C.I.  45  170,  PMA 

♦Pigment  Violet  1,  C.I.  45  170,  PTA- • 

♦Pigment  Violet  3,  C.I.  42  535,  fugitive 

♦Pigment  Violet  3,  C.I.  42  535,  PMA 

♦Pigment  Violet  3,  C.I.  42  535,  PTA- ■ 

Pigment  Violet  19,  C.I.  46  500— 

♦Pigment  Violet  23— • 

(Vat  Violet  1),  C.I.  60  010 — 

(Vat  Violet  2),  C.I.  73  385 

(Vat  Violet  3),  C.I.  73  395 

All  other 


NAC. 

ACY,  DUP,  FGL,  IMP,  MRX,  NAC,  SNA,  SW. 

ACY,  BUC,  DUP,  FCL,  ICC,  IMP,  NAC,  ROM,  SHi,  SNA,  SW. 

SNA,  SW. 

ICC,  KCW,  ROM,  SDH,  SW,  x. 

ACY,  AMS,  FCL,  HSC,  HSH,  IMP,  KON,  LVY,  NAC,  SDH,  SW. 

ACY,  HSC,  HSH,  IMP,  KON,  PPG,  SDH,  SW. 

ACY,  BLN,  CIK,  DUP,  FCL,  HSC,  HSH,  IMP,  KCW,  KON,  NAC, 

PPG,  SDH,  SNA,  SW,  UHL. 

ACY,  AMS,  FCL,  HSC,  HSH,  IMP,  KON,  MRX,  SDH,  SNA,  SW, 

UHL. 

DUP,  HSC,  HSH,  KCW,  SW. 

DUP,  GAF,  ICG,  NAC,  SNA,  SW. 
GAF,  NAC. 

ACY,  AMS,  BLN,  DUP,  FCL,  G.AF,  HSC,  HSH,  IMP,  KON,  LVY, 

MRX,  NAC,  S,  SNA,  SW. 

ACY,  AMS,  CIK,  FCL,  HSC,  IMP,  KON,  LVY,  SDH,  SNA,  SW, 

UHL. 

ACY,  AMS,  FCL,  HSC,  IMP,  LVY,  PPG,  SDH,  SNA,  SW. 

ACY,  AMS,  FCL,  HSC,  KON,  SDH,  SW. 

AMS,  FCL,  HSC,  HSH,  IMP,  SNA,  SW. 

ACY,  AMS,  GIK,  FCL,  HSC,  IMP,  KON,  LVY,  MGR,  MRX,  SDH, 

SNA,  SW. 
KON. 

HSH,  IMP,  MRX,  SDH. 

DUP,  NAC. 

AMS,  BLN,  CIK,  DUP,  FCL,  HSC,  HSH,  IMP,  KON,  LVY,  ICR, 

NAC,  S,  SDH,  SNA,  SW. 

DUP,  GAF,  IMP. 

FCL,  HSH,  IMP,  KON,  NAC,  SNA,  SW. 
NAC. 
SW. 
GAF. 

BLN,  KCW. 

BLN,  CPC,  DUP,  FCL,  GAF,  IMP,  KON,  LVR,  LVY,  MGR,  MRX, 

NYC,  S,  SNA. 

ACY,  AMS,  BLN,  DUP,  FCL,  OAF,  HSC,  IMP,  KCW,  KON,  MQR, 

MRX,  S,  SDH,  SNA- 
NAC. 

NAC,  SDH. 

AMS,  FCL,  ICC,  IMP,  LVR,  LVY,  NYC,  SDH,  SNA. 
SW. 
NAC. 
NAC. 
HST. 

GAF,  NAC. 
NAC. 

GAF,  HSC,  NAC. 

ACY,  DUP,  GAF,  HAM,  HSC,  SW,  TRC. 

BLN,  UHL. 

GAF,  IMP,  LVR,  M3R,  MRX. 

ACY,  AMS,  DUP,  FCL,  GAF,  HSC,  IMP,  KON,  M3R,  MRX,  S, 

SNA. 

ACY,  AMS,  BLN,  HAM,  HSC,  IMP,  KON,  LVR,  LVY,  ICR,  UHL. 

AMS,  BLN,  CIK,  DUP,  EAK,  GAF,  HSC,  IMP,  KON,  LVY,  ICR, 

MRX,  NYC,  PPG,  SDH,  SNA,  SW,  UHL. 

ACY,  AKE,  BLN,  GAF,  HSC,  IMP,  KON,  MRX,  SNA,  SW. 

DUP,  NAC. 

ACY,  GAF,  HST,  NAC,  TRC. 
DUP. 
NAC. 
NAC 

BUC,  ICC,  IMP,  ROM. 


See  note  at  end  of  table  for  definition  of  abbreviations. 


115 


TABLE  IIB — Bemenoid  pigments  for  which  U.S.  production  or  sales  were  reported,  identified 
by  manufacturer,  i  566— Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


TONERS— Continued 

»Blue  toners: 

•Pigment  Blue  1,  C.I.  «  595,  PMA- 

"Pigment  Blue  1,  C.I.  42  595,  PTA 

"Pigment  Blue  2,  C.I.  44  045,  fugitive 

"Pigment  Blue  2,  C.I.  44  045,  PMA - 

"Pigment  Blue  2,  C.I.  44  045,  PTA 

Pigment  Blue  3,  C.I.  42  140,  PMA 

Pigment  Blue  3,  C.I.  42  140,  PTA - 

Pigment  Blue  5,  C.I.  42  600 

Pigment  Blue  9,  C.I.  42  025,  PMA- — 

"Pigment  Blue  9,  C.I.  42  025,  PTA 

Pigment  Blue  10,  C.I.  44  O40,  PMA - 

Pigment  Blue  10,  C.I.  44  CXO,  PTA— - 

"Pigment  Blue  14,  C.I.  42  600,  PMA 

Pigment  Blue  14,  C.I.  42  600,  PTA - 

"Pigment  Blue  15,  C.I.  74  160,  alpha  form 

•Pigment  Blue  15,  C.I.  74  160,  beta  form 

"Pigment  Blue  19,  C.I.  42  750A 

•Pigment  Blue  22,  C.I.  69  810 — 

"Pigment  Blue  25,  C.I.  21  180 

Pigment  Blue  27,  C.I.  77  510 

(Basic  Blue  7),  C.I.  42  595,  PTA - 

(Vat  Blue  4),  C.I.  69  800 — - 

(Vat  Blue  6),  C.I.  69  825 — 

All  other— - - - 

*Qreea   toners: 

•Pigment  Green  1,  C.I.  42  040,  PMA — 

•Pigment  Green  1,  C.I.  42  040,  PTA- 

•Pigment  Green  2,  C.I.  42  040  and  49  005,  PMA 

•Pigment  Green  2,  C.I.  42  040  and  49  005,  PTA— - 

Pigment  Green  4,  C.I.  42  000,  fugitive 

•Pigment  Green  4,  C.I.  42  000,  PMA 

•Pigment  Green  4,  C.I.  42  000,  PTA 

•Pigment  Green  7,  C.I.  74  260 

•Pigment  Green  8,  C.I.  10  006 

Pigment  Green  10,  C.I.  12  775- 

•Pigment  Green  36,  C.I.  74  265 

Pigment  Green  38— - - 

•Brown  toners: 

Pigment  Brown  1,  C.I.  12  480 - 

Pigment  Brown  2,  C.I.  12  071 

•Pigment  Brown  3,  C.I.  21  010  PMA — 

•Pigment  Brown  5,  C.I.  15  800— - - 

(Vat  Brown  3),  C.I.  69  015— — 

All  other— - 

•Black  toners: 

Pigment  Black  1,  C.I.  50  440 

Pigment  Black  7,  C.I.  77  266 - 

All  other — 

LAKES 

•Ttellow  lakes: 

(Acid  yellow  1),  C.I.  10  316 

(Acid  Yellow  3),  C.I.  47  005- 

(Acid  Yellow  23),  C.I.  19  140 - 

Orange  lakes: 

Pigment  Orange  17,  C.I.  15  510 

All  other — — 

Red  lakes: 

•Pigment  Red  60,  C.I.  16  105 

•Pigment  Red  83,  C.I.  58  000 — - — 

(Acid  Red  17),  C.I.  16  180 

See  note  at  end  of  table  for  definition  of  abbreviations, 


BLN,  DUP,  EAK,  GAF,  HSC,  IMP,  KON,  LVH,  IVY,  M3R,  MRX, 

NYC,  SDH,  SNA,  SW,  UHL. 

AMS,  GAF,  HAM,  IMP,  KON,  MGR,  NAC,  SNA,  SW. 
BLN. 

GAF,  IMP,  LVR. 
HAM. 
MGR. 
MGR. 
GAF. 

LVR,  MRX,  NYC. 

BLN,  GAF,  IMP,  MRX,  SDH. 

IMP,  SDH. 
IMP. 

DUP,  OAF,  IMP,  NYC. 

DUP,  NYC. 

ACY,  DUP,  FCL,  OAF,  HSC,  ICC,  ICI,  IMP,  NAC,  SNA,  SW, 

IMS,  TRC. 

ACY,  AMS,  DUP,  FCL,  HSC,  ICC,  IMP,  LVY,  NAC,  SNA,  SW, 

IMS. 

ACY,  AMS,  HSC,  NYC,  SW. 

DUP,  IMP,  NAC,  TRC. 

DUP,  GAF,  ICC,  NAC,  S. 
GAF. 
DUP. 
GAF. 

ICI,  TRC. 

GAF,  IMP,  SDH. 


BLN,  GAF,  IMP,  MRX,  NYC,  UHL. 

BLN,  IMP,  MGR,  S,  SDH. 

GAF,  IMP,  KON,  LVY,  MGR,  MRX,  SDH,  UHL. 

ACY,  AMS,  DUP,  GAF,  IMP,  KON,  LVY;  MRX,  S,  SDH,  UH 

BLN,  GAF. 

BLN,  GAF,  MGR. 

ACY,  AMS,  HAM,  IMP,  KON,  MGR. 

ACY,  CIK,  DUP,  FCL,  GAF,  HSC,  ICC,  IMP,  NAC,  SNA, 

TMS,  TRC. 

DUP,  HSH,  IMP,  KCW,  SW. 

DUP,  HSC,  IMP,  SW. 

ACY,  GAF,  NAC,  SNA. 
NAC. 


ICI. 

HSH,  SDH. 

BLN,  KCW,  KON. 

BUC,  HSH,  ICC,  NAC,  ROM,  SNA. 

GAF,  NAC,  TRC. 

GAF,  ICC,  SDH,  SW. 

SNA. 
GAF. 

BLN,  DUP,  GAF,  UHL. 


IMP. 
IMP. 
KON,  MGR,  MRX. 


BLN,  HSC,  HSH,  KON,  MRX,  SNA,  SW. 
HSH,  IMP,  KON,  MRX,  PPQ,  SW,  UHL. 
IMP,  KCW. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  IIB. 


-Bemenoid  pigments  for  which  U.S.  production  or  sales  were  reported,  identified 
by  manufacturer,  i566~Continued 


Pigment 

Manufacturers'  identification  codes 
(according  to  list  in  table  22) 

LAKES— Continued 

fled  lakes— Continued 

(Acid  Red  25),  C.I.  16  050 

•(Aold  Red  26),  C.I.  16  150 - - 

KON. 

CPC,  HAM,  IMP,  KCW. 

KON. 

IMP. 

HAM,  IMP. 

BLN,  DUP,  HSH,  IMP,  KON,  NAC. 

SH. 

BLN. 

HAM,  HSC. 

BLN,  CPC,  KCW. 

AMS,  BLN,  KON,  LVY,  SDH. 

LVR. 

CPC,  KCW. 

BLN,  CPC. 

HAM,  KON. 

CPC,  KON,  NYC. 
HAM. 

All  other- - - 

»Vlolet  lakes: 

Pigment  Violet  20,  C.I.  58  225 

(Acid  Violet  17),  C.I.  42  650 

All  other — 

Blue  lakes: 

Black  lakes: 

0  er 

Note. — The  C.I.  (Colour  Index)  numbers  snown  in  this  report  are  the  identifying  codes  given  in  the  second  edition  of 
the  Colour  Inaex. 

When  the  name  of  a  color  is  enclosed  in  parentheses,   it  indicates  that  this  name  is  that  of  the  dye  from  which  the 
pigment  can  be  made  and  that  no  name  for  the  pigment  itself  is  given  in  the  Colour  Iruiex. 

The  abbreviations  PMA  and  PTA  stand  for  phosphomolybdic  and  phosphotungstic  (including  phosphotungstomolybdic) 
acids,   respectively. 


MEDICINAL  CHEMICALS 
Medicinal  Chemicals 


TABLE  IZB.— Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 

[Medicinal  chemicals  for  which  separate  statistics  are  given  in  table  13A  in  pt.    II  are  marked  below  with  an  asterisk 
(»);   medicinal  chemicals  not  so  marked  do  not  appear  in  table   13A  because  the  reported  data  are  accepted  in  con- 
fidence  and  may  not  be  published.   Manufacturers'   identification  codes  shown  below  are  taken  from  table  22.   An  x 
signifies  that  the  manufacturer  did  not  consent  to  his  identification  with  the  designated  product] 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


» Antibiotics: 
»For  medicinal  use: 

^Antifungal  and  antitubercular  antibiotics 
Antifungal  antibiotics: 

Amphotericin  B 

Candlcldin 

Nystatin 

Antitubercular  antibiotics : 

Cycloserine 

Dihydrostreptomyoin 

Streptomycin 

Viomycin 

♦Bacitracin 

♦Penicillins: 

Ampicillin 

Cloxacillin,  sodium 

Dicloxacillin,  sodium 

Hetacillln— ^ - —  • 

Methicillin,  sodium - ■ 

Nafcillin,  sodium • 

Oxacillin,  sodium 

Penicillin  G,  benzathine 

•Penicillin  G,  potassium 

•Penicillin  G,  procaine 

Penicillin  G,  sodium 

Penicillin  0,  sodium 

Phenethicillin,  potassium 

Phenoxymethylpenicillin  (Penicillin  V)-- 

Phenoxymethylpenicillin,  benzathine 

Phenoxymethylpenicillin,  hydrabamlne 

Phenoxymethylpenicillin,  potassium 

•Other  antibiotics  for  medicinal  use: 

Cephaloridine 

Cephalothin 

Chloramphenicol 

Erythromycin 

Fumagillin 

Gentamycin 

Gramicidin 

Kanamycin 

Llncctnycin 

Neomycin 

Novobiocin 

Oleandomycin 

Paromomycin 

Polymyxin  B 

Tetracyclines: 

Chlortetracycline 

Demethylchlortetraoycline 

Methacycline 

Oxytetracycllne 

Tetracycline 

Thiostrepton 

Triacetyloleandomycin 

lyrothricin 

Vancomycin 

•For  other  uses: 

•Bacitracin 

Chlortetracycline 

Cycloheximide 

Hygronycin  B- 

Neomycin 

Novobiocin 

Oxytetracycllne 


OMS. 

PEN. 

OMS. 

COM. 

MHK, 

PFZ. 

LIL, 

MRK, 

OMS. 

PFZ 

PFZ. 

COM, 

PEN, 

PFZ, 

PMP. 

BRS, 

WYT. 

BRS. 

BRS. 

BRS. 

BRS. 

WYT. 

BRS. 

PFZ, 

WYT. 

LIL, 

MRK, 

OMS, 

PFZ, 

LIL, 

MRK, 

OMS, 

PFZ, 

QMS. 

UP  J. 

BRS, 

WYT. 

LIL. 

WYT. 

ABB. 

ABB, 

LIL. 

LIL. 

LIL. 

PD. 

ABB, 

LIL. 

ABB. 

SCH. 

BAX, 

PEN. 

BRS. 

X. 

OMS, 
MRX, 

PEN, 
UP  J. 

PFZ, 

UP  J. 

PFZ. 

PFZ. 

ACY,    BRS,    PFZ,    RI^. 

CftiB. 

PFZ. 

BAX,    PEN. 

LIL. 


UP  J. 
LIL. 
PEN, 
UP  J. 
PFZ. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  13B.— Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i 566— Continued 


Manufacturers'   identification  codes 
( according  to  list  in  table  22 ) 


»Antibiotios--Continued 
»For  other  uses--Continued 
♦Penicillin  G  salts: 

Penicillin  G,   benzathine 

Penicillin  G,   procaine 

Streptomycin 

lyiosin 

►Anticoagulants: 

Ammonium  heparin 

Anlsindione 

Bisliydroxycoumarin 

Phenindione 

Potassium  heparin 

♦Sodium  heparin 

Sodium  warfarin 

» Antihistamines: 
♦Antinauseants: 

Cyclizine  hydrochloride 

Dlmenhydrinate 

Meclizine  hydrochloride 

Trimethobenzamide  hydrochloride 

Bromodiphenhydr amine  hydrochloride 

Brompheniramine  maleate 

Carbinoxamine 

Chlorcyclizine  hydrochloride 

Chlorothen  citrate 

♦Chlorpheniramine  maleate 

Cyproheptadine  hydrochloride 

Dexbrompheniramlne  maleate 

Dexchlorpheniramine  maleate 

Dimethindene  maleate 

Diphenhydramine  hydrochloride 

Doxylamine  succinate 

Methapyrilene  fumarate 

Jfethapyrilene  hydrochloride 

Jfethapyrilene  hydroxybenzoylbenzoate 

Phenindamine  tartrate 

♦Pheniramine  maleate 

Phenyltoloxamine  citrate 

Pyrllamine  maleate 

Pyrrobut amine  phosphate 

Thenyldiamlne  hydrochloride 

Thonzylamlne  hydrochloride 

Tripelennamine 

Tripelennamine  citrate 

Tripelennamine  hydrochloride 

Triprolidlne  hydrochloride 

*Anti-infective  agents  (except  antibiotics): 
♦Arsenic,  bismuth,  and  mercury  compounds: 
Arsenic  and  bismuth  compounds: 

Arsanilic  acid-'- 

Bismu-th  dlpropylacetate 

Bismu-th  sodium  triglycollamate 

Bismuth  subsalicylate 

Carbarsone 

Glycobiarsol 

Nitarsone 

Roxarsone 

Sodium  arsanilate-"- 

Mercury  compounds: 

o-Hydroxyphenylmercuric  chloride 

Merbromin 

Mercuric  salicylate 

Nitromersol 

Phenylmer curie  acetate 

Phenylmercuric  benzoate 

Phenylmerouric  borate 

Phenylmercuric  nitrate 

Thimerosal 

See  footnotes  at  end  of  table. 


LIL. 

MRK. 

QMS,    PFZ 

LIL, 

MRK, 

PFZ. 

LIL. 

WIL. 

SCH. 

ABB, 

FIN. 

CTN, 

GAN. 

WIL. 

ABB, 

RIK, 

WIL. 

EN. 

BUR. 

SRL. 

PFZ. 

HOF. 

PD. 

SCH. 

SCH. 

ABB, 

BUR. 

ACY. 

HFJC, 

LEM, 

SCH,    SK, 

MRK. 

SCH. 

SCH. 

CBP. 

ARA, 

GAN, 

PD. 

BKC. 

ABB. 

ABB. 

LIL. 

HOF. 

HEX, 

LEM, 

SCH,   X. 

BRS. 

HEX, 

MRK, 

fiSA. 

LIL. 

SEW. 

NEP. 

CBP. 

CBP. 

CBP. 

BUR. 

BPC. 

MAL, 

NOR, 

PEN 

LIL, 

PYL, 

WHL 

PYL, 

SDW. 

SAL. 

SAL. 

PYL, 

SAL, 

WHL. 

MRK. 

HYN. 

MAL. 

ABB. 

WRC. 

MRK, 

WRC. 

MRK, 

WRC. 

MRK, 

WRC. 

LIL, 

PYL, 

SEL. 

MEDICINAL  CHEMICALS 


-Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  966— Continued 


Uanvifaoturere '  Identification  codes 
( according  to  list  In  table  22) 


"Antl-lnfectlve  agents  (except  antibiotics) --Continued 

"Caprylatee  and  undecylenates: 

Calcium  undecylenate 

Sodium  caprylate 

Sodium  undecylenate 

Undecylenic  acid 

Zinc  undecylenate 

•p-Hydroxybenzoic  acid  esters: 

Benzylparaben 

Butylparaben'- 

Ethylparaben^ 

"Methylparaben^ 

Propylparaben^ 

»5-Nltrofurane,   -imidazole,   and  -thiazole  derivatives 

Aolnitrazole 

2-Mlno-5-nltrothlazole 

Furazolidone 

Metronidazole 

Nihydrazone 

Nl  thiazide 

Nitrofurantoin 

Nitrofurazone 

•Phenolic  antiseptics  and  disinfectants: 

Betanaphthol^ 

Blthlonol 

Chloro thymol 

Resorcinol'"' 

Reeorclnol  monoacetate-"- 

niymol 

Thymol  iodide 

»Piperazlne  base  and  salts: 

•Plperazlne-"- 

Piperazlne  adipate 

Piperazine  calcium  edetate 

Piperazlne  citrate 

Piperazine  dihydrochloride 

Piperazine  hexahydrate 

Piperazine  hydrochloride 

Piperazine  phosphate 

Piperazine  sulfate 

Piperazlne  tartrate 

»(Jilnollne  derivatives: 

Amodiaquln 

Amodiaquln  hydrochloride 

Chloroqulne  phosphate 

•Diiodohydroxyquin 

Hydroxychloroquine  sulfate 

8-Hydroxy-5-quinollnesulfonic  acid 

lodochlorhydroxyquin 

Qxyqulnollne 

»Qxyquinollne  benzoate 

Qxyquinoline  citrate 

Qxyqulnollne  potassium  sulfate 

»Qxyqulnollne  sulfate 

Primaquine  phosphate 

"Sulfonamides: 

Acetyl  sulfamethoxypyridazine 

Acetyl  sulflsoxazole 

Azosulf amide 

Dinsed - 

Mafenlde  acetate 

Mafenide  hydrochloride 

Para-nitrosulfathiazole 

Phthalylsulfacetamide 

Phthalylsulfathiazole 

Sucolnylsulfathlazole 

Sulfabenz  amide 

Sulfabenzamide,  sodium 

Sulfabromomethazlne,  sodium 

Sulfacetamide 


WTL. 

LEM,    TNC 

BAC. 

BAC. 

BAC,    LEM, 

TNC 

WTL. 

LEM. 

HN,    ICO. 

HN. 

HN,    ICO, 

LEM, 

PYL, 

HN,    ICO, 

LEM, 

WSN. 

ACY. 

ACY. 

NOR. 

RDA. 

NOR. 

MRK. 

NOR. 

NOR. 

ACY,    FIN. 

SDH. 

OPC. 

LEM- 

FIN,    KPT. 

GIV. 

MAL. 

DOW,    FLM, 

JCC, 

UCC. 

JCC,    PYL. 

EN. 

BUR,    JCC. 

DOW,    FLM, 

JCC, 

WHL. 

JCC,    RDA, 

SEL. 

DOW,    JCC. 

BUR,    JCC, 

PYL. 

JCC. 

PYl. 

PD. 

PD. 

SDW. 

CBP,    LEM, 

PYL, 

RSA. 

SDW. 

MRK. 

CBP,    PYL. 

GAM,    LEM, 

MRK. 

QAM,    LEM, 

MRK. 

GAM,   LEM,   MRK,   PYL. 


ACY. 
HOF. 
SOU. 
SAL. 
SEW. 
SDW. 
SIW. 

T.ITM, 

LQI,   MEK,   PYL. 

LEM,   MRK,    PYL 

ACY. 

ACY. 

MRK. 

T.RU. 


See  footnotes  at  eal  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Medicinal  chemicals  for  Which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  2566— Continued 


ManuTaoturers '   identification  codes 
(according  to  list  in  table  22) 


*Anti-infectlve  agents   (except  antlbiotics)--Continued 
♦Sulfonamides — Continued 

Sulfacetamide,    sodium 

Sulfactaoropyrazine,    sodium 

Sulfadiazine 

Sulfadiazine,    sodium 

Sulfadimethoxine 

Sulfaethidole- 

Sulfaguanidine 

Sulfamerazine 

Sulfamerazine,   sodium 

Sulfamethazine 

Sulfamethlzole 

Sulfamethoxazole 

Sulfamethoxypyridazine 

Sulfanilamide 

Sulfanltran 

Sulfapyridine 

Sulfapyridine,    sodium 

Sulfaqulnox aline 

Sulfathiazole 

SulfatMazole,    sodium 

Sulfisoxazole 

»Other  anti-infective  agents: 

♦Anthelmintic,    antifungal,    antiprotozoan,    and 
antivirEil  agents: 
Anthelmintic   agents: 

Cadium  anthranilate 

Diethylcarbamaztne  citrate 

Gentian  violet 

Hexylresorcinol 

Ehenothiazine 

Pyrvinium  pamoate 

Thiabendazole 

Antifungal  agents: 

Benzoic  acid-"- 

Diamthazole  hydrochloride 

Fuchsin,  basic 

Salicylanilide^ 

Antiprotozoan  agents: 

Aklomlde 

Amprolium 

Chlorbetamlde 

Nitrophenlde ■ 

Pyrimethamine 

Antiviral  agent:   Amantadine  hydrochloride 

•Urinary  antiseptics: 

Ammonium  benzoate 

Ammonium  mandelate 

Calcium  mandelate 

Ethoxazene  hydrochloride 

Mandelic  acid - 

Methenamlne 

Methenamine  hippurate 

Methenamlne  mandelate 

Methylene  blue 

Phenazopyridine  hydrochloride 

»A11  other: 

Aorlflavine 

Aminacrine 

Aminacrine  hydrochloride 

Antileprotio  and  antltubercular  agents: 

Aminosalicylic  acid 

Calcium  aminosalicylate 

Dapeone 

Isonlazid 

Potassium  amlnoealioylate 

Pyrazlnamlde 

Sodium  aminosalicylate 

Sodium  sulfoxone 


LEM. 

ACY. 

ACY, 

LEM. 

ACY. 

HOF. 

ACY. 

ACY, 

LEM. 

ACY, 

LEM. 

ACY. 

ACY, 

LEM. 

ACY. 

HOF. 

ACY. 

LEM, 

MRK. 

SAL. 

ACY, 

MRK. 

ACY. 

MRK. 

ACY, 

LEM,   MRK. 

ACY, 

MRK. 

HOF. 

MAL. 

ACY. 

NAC,    SDH. 

HEX,   MRK. 

CLV. 

x. 

MRK. 

MON,    PFZ. 

HOF. 

NAC. 


RSA. 

MAL. 

KON. 

MAL. 

HN. 

RIK. 

ARN,    LEM,    NEP,    PYL,    TNC. 

ACY,    NAC. 

HOF,    KON,    NEP. 

NAC. 


RIL. 
MLS. 
MRK. 
MLS. 
JiBB. 


See  footnotes  at  end  of  table. 


MEDICINAL  CHEMICALS 


TABLE  MB.— Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  566— Continued 


Manufacturers'   Identification  codes 
(according  to  list  in  table  22) 


•Antl- infective   agents  (except  antibiotics) — Continued 
»Other  anti-infective  agents- -Continued 
«A11  other — Continued 

BenzRlkonixim  chloride 

Bromoform 

Camphor,  monobromated 

Cetallconlum  chloride 

Cetylpyridinium  chloride 

Chloramine  T 

Chlorobutanol 

Iodoform^ 

Magnesium  salicylate 

Nalidixic  acid 

Nltromide 

Providone  -  iodine  complex 

♦Antineoplastic  agents  and  local  anesthetics: 
Antineoplastic  agents: 

Mercaptopurlne ^ 

Ure thane 

Vinblastine  sulfate 

Vincristine  sulfate 

Local  anesthetics: 

Butacalne  sulfate 

Butamben  plcrate 

Butyl  amlnobenzoate  (Butamben) 

Dibucalne 

Wbucalne  hydrochloride 

Ethyl  amlnobenzoate  (Benzocalne) 

Isobutyl  amlnobenzoate 

»Lidocalne 

Qxethazalne 

Phenacaine  hydrochloride 

Piperocalne  hydrochloride 

Pramoxine  hydrochloride 

Procaine 

Procaine  hydrochloride 

Proparacaine  hydrochloride 

Propyl  amlnobenzoate 

Pyrrocalne  hydrochloride 

Tetracaine 

Tetracaine  hydrochloride 

♦Autonomic  drugs: 

Ganglionic  blocking  agent:   Hexemethonlum  chloride-- 
Parasyinpatholytic  (anticholinergic)  agents: 
♦Quaternary  ammonium  compounds  (except  tropane 
derivatives) : 

Ambutonlum  bromide 

Dlphemanll  methylsulfate 

Hexocycllum  methylsulfate 

Isopropamlde  iodide 

Mepenzolate  bromide 

Methanthellne  brcmlde 

Plpenzolate  bromide 

Pralldoxlme  chloride 

Propantheline  bromide 

Thlhexinol  methylbromlde 

Trldlhexethyl  iodide — 

Tertiary  amines  (except  tropane  derivatives): 

Adiphenlne  hydrochloride 

Amlnopentamlde  sulfate 

Caramlphen  edisylate 

Dicyclomine  hydrochloride 

Ethopropazine 

Orphenadrlne  citrate 

Orphenadrine  hydrochloride 

Oxyphencycllmlne  hydrochloride 

Piperidolate  hydrochloride 

Thlphenamll  hydrochloride 

Trihexyphenidyl  hydrochloride 


SDH. 

DOW. 

MAL, 

PEN. 

FIN, 

SDW. 

FIN, 

HEX, 

NEP 

MON. 

BPC, 

PD. 

MAL, 

PEN. 

MAL. 

SDH. 

SAL. 

GAF. 

BUR. 

FMP. 

LIL. 

LIL. 

ABB. 

ABB. 

ABB. 

CBP. 

CBP. 

ABB, 

LEM. 

ICO. 

AST, 

LEM, 

SDW. 

WiT. 

GAN, 

SDW. 

LIL. 

ABB. 

ABB. 

ABB, 

I.EM, 

PFZ. 

QMS. 

ICO. 

EN. 

SDW. 

ICO, 

RSA, 

SDW. 

ICO. 

SCH. 

ABB. 

SK. 

LKL. 

SRL. 

LiCL. 

CBP,    NEP. 

SHL. 

SCH. 

ACY. 


SK. 

BKC. 

NEP. 

RIK. 

RIK. 

PFZ. 

LKL. 

BJL,    X. 

ACY,    SDW. 


'^e   footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHtMICALS,  1966 


TABLE  13B. — Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufactu.'er ,  1966 — Continued 


ManuTaoturers '  identification  codes 
(according  to  list  in  table  22) 


»Autonomlc  drugs — Continued 

Parasympatholytic  (anticholinergic)  agents--Continued 
Tropane  derivatives: 

Anisotropine  methylbromide 

Benztropine  mesylate 

Homatropine 

Homatropine  hydrobromide 

»Homatropine  methylbromide 

Parasympathomimetic  (cholinergic)  agents: 

Acetylcholine  chloride 

Methachollne  chloride 

Neostigmine  bromide 

Ehysostigmine  salicylate 

Pyridostigmine  bromide 

Sympatholytic  (antiadrenergic)  agent:   Ergonovine 
maleate 
•Sympathomimetic  (adrenergic)  agents: 

Adrenalone 

Cinnamedrine  (Cinnamylephedrine) 

Cyclopentamine  hydrochloride 

Epinephrine  bitartrate  (levo) 

Epinephrine  hydrochloride  (racemic) 

•Isoproterenol  salts: 

Isoproterenol  hydrochloride 

Isoproterenol  sulfate 

Levarterenol  bitartrate 

dl-Metanephrine  hydrochloride 

Metaraminol  bitartrate 

Methoxyphenamine  hydrochloride 

Naphazoline  hydrochloride 

Nordefrin  hydrochloride 

Nylidrin  hydrochloride 

•Phenylephrine 

Phenylephrine  bitartrate 

Phenylephrine  hydrochloride 

•Phenylpropanolamine  hydrochloride 

Propylhexedrine 

Protoiylol  hydrochloride 

Pseudoephedrine  hydrochloride 

Pseudoephedrine  sulfate 

Tetrahydrozollne  hydrochloride 

♦Cardiovascular  agents: 
•Cardiac  drugs: 

Calcium  camphorsulfonate 

Digitoxin 

Procainamide  hydrochloride 

Quinldine  gluconate 

Quinidine  sulfate 

•Rauwolfia  and  veratrum  alkaloids: 

Aliavervir— - - — 

Alseroxylon 

Deserpidine 

Reserpine 

Syrosingopine 

•Other  cardiovascular  agents: 

Antihypertensive  agents  (except  rauwolfia  and  veratrum 
alkaloids) : 

Hydralazine  hydrochloride 

Methyldopa 

Pargyline  hydrochloride 

Bioflavonoids: 

Hesperidln 

Hesperidin  methyl  chalcone 

Lemon  bioflavonoid 

Naringin 

Rutin — - - - 

Vasodilators: 

Dioxyline  phosphate 

Ethyl  nitrite - 

Glyceryl  trinitrate 

Isosorbide  dinltrate 

Mannltol  hexanltrate 


OTN, 

HEX. 

CTN. 

CTN, 

EN,    HEX 

MRK, 

RSA. 

MRK, 

RSA. 

HEX. 

PEN. 

HOF. 

LIL. 

GAN,  SDW. 
ABB,  GAN. 
SDW. 
SDW. 
SDW. 


CTN, 
GAN. 
CTN, 
BKL, 
HEX, 
LKL. 
BUR, 
GAN. 
PFZ. 


FIN,  PYL. 
BUR. 

LEM,  QMS. 
HEX. 
HEX. 


SKG. 
SKG. 
SKG. 
SKG. 


LIL. 
MAL. 
APD. 
APD. 
APD. 


MEDICINAL  CHEMICALS 


123 


TABLE  13B.  —Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  566— Continued 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


•Cardiovascular  agents— Continued 

*Other  cardiovascular  agents — Continued 
Vasodilators — Continued 

Nlcotlnyl  alcohol  tartrate 

Pentaerythrltol  tetranltrate 

•Central  depressants  and  stimulants: 
•Amphetamines: 

Amphetamine  (racemic) 

Amphetamine  hydrochloride  (racemic) 

Amphetamine  sulfate  (racemic) 

Dextroamphetamine 

Dextroamphetamine  carboxymethylcellulose 

Dextroamphetamine  hydrochloride 

Dextroamphetamine  phosphate 

•Dextroamphetamine  sulfate 

Dextroamphetamine  tannate 

Lev amphetamine  succinate 

•Jfethamphetamlne  base  and  hydrochloride: 

Methamphetamine  ( dextro) 

tfethamphetamine  (levo) 

Methamphetamine  (racemic) 

Methanqjhetamlne  hydrochloride  (dextro) 

Methamphetamine  hydrochloride  (racemic) 

•Anticonvulsants,  hypnotics,  and  sedatives  (except 
barbiturates) : 
Anticonvulsants: 

Aminoglutethlmide 

Diphenylhydantoin 

Diphenylhy'is^'''Oin,  sodium 

EthoEuximlde 

Etbotoln 

Methsuximlde 

Paramethadione 

Phenacemide 

Phensuximlde 

Trimethadione 

Hypnotics  and  sedatives: 

Carbromal 

Ethohlorvynol 

Ethinamate 

Glutethlmide 

Methyprylon 

•Antidepressants: 

Amltrlptyline 

Deslpramine  hydrochloride 

Imlpramlne  hydrochloride 

Isocarboxazid 

Nialamide — 

Nortriptyline 

Phenelzine  sulfate 

•Barbiturates: 

5-Allyl-5-(2-cyclopenten-l-yl)barbituric  acid 

Amobarbltal 

Amobarbital,  sodium 

Barbital- — 

Barbital,  sodium 

Butabarbital- 

•Butabarbital,  sodium 

Butalbltal 

Butalbltal,  sodium 

Butethal— 

Cyclobarbital 

Cyclobarbital,    calcium 

5-Ethyl-5-pentylbarbiturlo  acid 

Hexobarbital 

Hexobarbltal,   sodium 

Ifephobarbital 

Metharbital 

Uethohexltal,    sodium 

Pentobarbital 

Pentobarbital,   sodium 

Ehenobarbltal 


HOF. 

APD. 

HEX, 

ORT. 

ARN, 

HEX, 

AHN, 

HEX. 

HEX. 

AHN. 

ARN, 

HEX. 

ARN, 

HEX. 

ARN, 

HEX, 

SK. 

ARN. 

ARN. 

HEX. 

ABB. 

HEX. 

ABB, 

ARN, 

GAN,    HEX. 

ARN, 

GAN, 

HEX. 

CBP. 

PD. 

PD. 

PD. 

ABB. 

PD. 

ABB. 

ABB. 

PD. 

ABB. 

PD. 

ABB. 

LIL. 

CBP. 

HOF. 

MRK. 

GGY, 

LKL. 

GGY. 

HOF. 

PFZ. 

LIL. 

NEP. 

GAN. 

LIL. 

GAN, 

LIL. 

GAN. 

GAN. 

ABB, 

GAN. 

ABB, 

BPC, 

GAN. 

GAN. 

GAN. 

GAM. 

SDW. 

SDW. 

BPC. 

GAN, 

SDW. 

SD*. 

SDW. 

ABB. 

LIL. 

ABB, 

GAN. 

ABB, 

BPC, 

GAN. 

BPC, 

GAN, 

UAL. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  966— Continued 


•Central  depressants  and  stimulants — Continued 
»Barbitur ates — Continued 

»Phenobarbital,   sodium 

Secobarbital 

Secobarbital,    sodium 

Talbutal 

Thiamylal,  sodium 

Thiopental,  sodium 

Vinbarbital 

»Hydrooodone  bitartrate 

»Salioylates: 

Aluminum  aspirin 

•Aspirin 

Ethyl  salicylate  carbonate 

Phenyl  salicylate 

Potassium  salicylate 

Salioylamide 

Salicylsallcyllo  acid 

Sodium  salicylate 

Strontium  salicylate 

•Skeletal  muscle  relaxants: 

Carisoprodol 

Chlorphenesin  carbamate 

Chlorzoxazone 

Mephenesin 

Phenaglycodol 

Styramate 

Succinylcholine  chloride 

Tubocurarine 

•Tranquilizers: 

*Meprobamate 

•Phenothiazine  derivatives: 

Carphenazine  maleate 

Chlorpromazine  hydrochloride 

Fluphenazine  hydrochloride 

lifepazine  hydrochloride 

Perphenazine 

Prochlorperazine  maleate 

Promazine  hydrochloride 

Promethazine  hydrochloride 

Trifluoperazine  hydrochloride 

Triflupromazine  hydrochloride 

»Other  tranquilizers: 

Azacyolonol  hydrochloride 

Buclizine  hydrochloride 

Chlordiazepoxide  hydrochloride 

Chlormezanone 

Chlorprothixene 

Diazepam 

Ethomoxane  hydrochloride 

Hydroxyphenamate 

Hydroxyzine  hydrochloride 

Hydroxyzine  pamoate 

Mebutamate 

Methaqualone 

Jfethaqualone  hydrochloride 

Oxazepam 

lybamate 

•Other  central  depressants  and  stimulants: 

Analgesics  and  antipyretics  (except  salicylates) 

Acetaminophen 

Acetanllide 

p-Aminobenzoic  acid  and  salts: 

Aminobenzoic  acid 

Calcium  aminobenzoate 

Magnesium  aminobenzoate 

Potassium  aminobenzoate 

Sodium  aminobenzoate 

Anlleridine  hydrochloride 

Aurothlogluoose 

Calcium  succinate 

Colchicine 


CAN,  MAL,  SDW. 

GAN. 

GAN,  LIL. 

SEW. 

PD. 

ABB. 


ABB,  PYL,  SCH. 

CFC,  DOW,  MLS,  HON,  NOR,  SDG. 


DOW, 

MAL. 

HN, 

'EN. 

CFC, 

TNC. 

DOW, 

HN. 

TNC. 

X. 

X. 

OTC. 

HEX, 

OMS. 

LIL. 

ARP. 

ABB, 

BUR,    SDW. 

ABB, 

QMS. 

ABB, 

BKL,    PEN. 

WYT. 

SK. 

QMS. 

SCH. 

NEP. 

SCH. 

SK. 

WYT. 

WYT. 

SK. 

OMS. 

BKC. 

PFZ. 

HOF, 

SOU. 

HOF. 

HOF. 

LIL. 

ARA, 

ARP. 

PFZ. 

PFZ. 

X. 

HEX, 

X. 

BPC. 

WYT. 

PEN, 

X. 

ATP, 

MLS,    NEP, 

CTN. 

LEM. 

GAN, 

LEM. 

LEM. 

GAN, 

LOJ. 

GAN, 

LEU. 

MRK. 

MEDICINAL  CHEMICALS 


TABLE  IZB.— Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufjcturer,  i  566— Continued 


Manufacturers'  identification  codes 
(according  to  list  In  table  22) 


•Central  depressants  and  stimulants — Continued 

•Other  central  depressants  and  stimulants — Continued 
Analgesics  and  antipyretics   (except 
sali  cy lates ) — Continued 

Ethoheptazine  citrate 

Indomethaoin 

Meperidine  hydroctiloride 

Oxycodone  hydrochloride 

Qxymorphone  hydrochloride 

Oxyphenbutazone 

Pentazocine 

Phenacetin 

Phenylbutazone 

Phenyramldol  hydrochloride 

Propoxyphene  hydrochloride 

Propoxyphene  napsylate 

Anesthetics: 

Tribrcmoethanol 

Vinyl  ether 

Antitussives: 

Benzonatate 

Carbetapentane  citrate 

Dextromethorphan  hydrobromide 

Dimethoxanate  hydrochloride 

Ethylmorphlne  hydrochloride 

Stimulants : 

Benzphetamine  hydrochloride 

Caffeine: 

Natural 

Synthetic - — 

Caffeine,  citrated — 

Caffeine  sodium  benzoate 

Chlorphentermine  hydrochloride 

Dlethylpropion  hydrochloride 

Nikethamide — 

Phendimetrazine 

Phenmetrazine  hydrochloride 

Phentermine 

•Dermatological  agents: 

•Allantoin 

Aluminum  phenols\ilfonate 

Ammonium  phenolsulfonate 

•Bismuth  subgallate 

Dipropylene  glycol  salicylate 

Glycol  salicylate 

Homomenthyl  salicylate 

Menthyl  salicylate 

p-Uethoxycinnamlc  acid,  2-ethoxyethyl  ester 

Podophyllum  resin 

•Salicylic  acld^ - 

Scarlet  red 

Sodium  phenolsulfonate 

Zinc  phenolsulfonate 

•Expectorants  and  mucolytic  agents: 

Ethylenedi amine  dihydriodide 

•Gualaool  and  its  derivatives: 

Glyceryl  gualacolate 

Guaiacol 

Potassium  gualacolsulfonate 

lodinated  glycerol 

lodobrassid 

Lobeline  sulfate 

Terpin  hydrate 

Thonzoniujn  bromide 

•Gastrointestinal  agents: 

•Choleretics  and  hydrocholeretios: 

Bile  aoide,  oxidized 

Dehydrooholic  acid 

Florantyrone 

Iron  bile  salts 

See  footnotes  at  end  of  table. 


MRK. 
sun,   WYT. 


GGY. 
SOU. 
MON. 
GGY. 
OTC. 
UL. 
LIL. 

SDW. 

MRK. 

CBP. 
PFZ. 
HOP. 


GNF,  M3fW. 
PFZ. 

MAL,  MRK. 
MAL. 
NEP. 
BKC,  x. 
CBP,  PYL. 


GGY. 


CTN, 

FIN 

HFT. 

MAL. 

SAL. 

BKC, 

MAL, 

PEN. 

SBC. 

RDA. 

ICO. 

CFC. 

GIV. 

ABB, 

PEN. 

DOW, 

HN, 

ffiN,    SDH. 

NAC. 

MAL, 

SAL. 

MAL. 

CLV, 

PYL, 

WHL. 

BKL, 

GAN, 

ICO,    X. 

MON. 

HN. 

X,     X 

CBP. 

ABB. 

LEM, 

PEN. 

NEP. 

SRL, 

WIL. 

WIL. 

SRL. 

LIL. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  13B. — Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i 566— Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


•Gastrointeetinal  agentB--Continued 

•Choleretics  and  hydrocholeretics — Continued 

Ox  bile  extract 

Sodium  dehydrocholate 

Tooair$>hyl 

•Choline  salts: 

Choline  bicarbonate 

Choline  bitartrate 

•Choline  chloride  (all  grades): 

Feed  grade 

Medicinal  grade 

Technical  grade 

Choline  citrate  (Trichollne  citrate) 

Choline  dihydrogen  citrate 

•Methionine  and  its  hydroxy  analogue: 

Methionine  (feed  grade) 

Methionine  (medicinal  grade) 

Methionine,  hydroxy  analogue,  calcium  salt- 
•Other  gastrointestinal  agents: 

Betaine  base 

Betaine  hydrate 

Betaine  hydrochloride 

Calcium  polycarbophil 

Dihydroxy  aluminum  aminoacetate 

Magnesium  citrate 

Pectin— 

Phenolphthalein * 

Fhenolphthalein,  yellow 

Polycarbophil 

Sitosterols 

Sodium  tartrate 

•Hormones  and  synthetic  substitutes: 
•Antithyroid  agents: 

Methimazol 

Propylthiouracil 

Thiouracll 

•Estrogens: 

Chlorotrianisene 

Dienestrol  dlacetate 

Dlethylstilbestrol - 

Diethylstilbestrol  dlproplonate 

Natural  estrogenic  substances 

Piperazine  estrone  sulfate 

•Prednisone 

•Synthetic  hypoglycemic  agents: 

Aoetohexamide 

Chlorpropamide 

Phenformin  hydrochloride 

Tolazamide 

Tolbutamide 

•Other  hormones  and  synthetic  substitutes: 

Androgen:   Fluoxymesterone 

Corticosteroids: 

Betamethasone 

Betamethasone  acetate 

Betamethasone  phosphate 

Cortisone  acetate 

Dexamethasone 

Dexamethasone  acetate 

Dexamethasone  phosphate 

Dichlorisone  acetate 

Fludrocortisone  acetate 

Fluorometholone 

Fluprednlsolone 

Hydrocortisone 

l^drooortisone  acetate 

Hydrocortisone  phosphate 

Methylprednlsolone 

Prednisolone 

Prednisolone  acetate 

Triamcinolone 


ABB. 
WIL. 

COM. 
ACY, 

HFT. 

COM, 
HFT. 
GAF, 
ACY, 
ACY, 

DLI,    HFT,    TMH 

RH. 
HFT. 
HFT. 

DOW, 
DOW, 
DUP, 

LEM- 
MON. 

HFT, 
HFT. 
HFT, 

UAL. 
TNC. 

CHT. 

SKG. 
MON. 

WLI. 
UP  J. 
MAL. 

LIL. 
PYL. 
ACY. 

BKC. 
SCH. 
CTN, 
CTN. 
ORG. 
ABB. 
MRK, 

LIL. 
SCH,    UPJ. 

LIL. 
PFZ. 

SCH. 

MRK, 

SCH,    UPJ 

MRK, 

SCH. 

SCH. 

MRK. 

SCH. 

DPJ. 

UPJ. 

UPJ. 

MRK, 

UPJ. 

MRK, 

UPJ. 

UPJ. 

MRK, 

UPJ. 

SCH, 

UPJ. 

ACY, 

QMS. 

MEDICINAL  CHEMICALS 


TABLE  133. --Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i 966— Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


«Hormones  and  synthetic  substitutes--Continued 

»Other  hormones  and  synthetic  substitutes — Continued 
Progestogens: 

Medroxyprogesterone  acetate 

Progesterone 

All  other: 

Corticotropin  (ACTH)  (pituitary) 

Insulin  (pancreas) 

»Renal- acting  and  edema- reducing  agents: 
•Mercurial  diuretics: 

Meralluride 

Mersalyl  acid—- - - 

Sodium  mercaptomerin 

Sodium  mercurophylline 

•Theobranlne  and  theophylline  derivatives: 

Ambuphylllne 

»Aminophylline 

Aminophylline  sodium  biphosphate 

Oxtriphylline 

Theobromine  sodium  acetate 

Theobromine  sodium  salicylate 

Theophylline  magnesium 

Theophylline  monoethanolamlne 

Theophylline  piperazine  ethanoate 

Theophylline  sodium  glyclnate 

♦Other  renal- acting  and  edema- reducing  agents: 

Acetazolamlde 

Benzothiadiazlne  derivatives: 

Benz thiazide 

Chlorothiazide 

Flume thiazide 

Hydrochlorothiazide 

Hydroflumethiazide 

Methyclothiazide- - - — ■ 

Polythiazlde 

Trichlormethiazide 

Chlorthalidone 

Diohlorphenamide 

Probenecid 

Spironolactone 

Triamterene 

♦Therapeutic  nutrients: 
♦Amino  acids  and  salts: 

Acetyltryptophane 

Aminoacetic  acid  (glycine)^ 

Amino  acid  mixtures 

Arglnine  glutamate 

Aspartlc  acid  and  salts: 

Aspartic  acid 

Magnesium  aspartate 

Potassium  aspartate 

Beta- alanine 

Glutamic  acid  and  salts: 

Ammonium  glutamate 

Calcium  glutamate 

♦Glutamic  acid 

Glutamic  acid  hydrochloride 

♦Potassium  glutamate 

I^ysine  (feed  grade) 

lysine  hydrochloride 

Phenylalanine 

d-Direonine 

Tryptophane 

♦Calcium  gluconate 

♦Other  therapeutic  nutrients: 

Calcium  glucoheptonate 

Calcium  lactophosphate 

Calcium  levultnate 

Calcium  phytate---- 

Copper  gluconate 

See  footnotes  at  end  of  table. 


GAN. 

GAN,  LEM,  SRL. 

GAN. 

NEP. 

MAL. 

CLC. 

MAL. 

LIL. 

SEL. 

CHT. 

ACY. 

PFZ. 
MRK. 


SOU. 

BPC,  DOW. 
ABB,  CUT,  STA. 
ABB. 

HEX,  NAC. 


IMC, 

LEM, 

PFZ 

IMC, 

LEM. 

IMC, 

LEM, 

PFZ 

MRK. 

MRK. 

SEW. 

SIM. 

SDW. 

MAL, 

PFZ, 

WHL 

PFN. 

MAL. 

pn,, 

SEL. 

STA. 

PFZ. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


■  Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  566— Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


^Therapeutic  nutrients — Continued 

»Other  therapeutic  nutrients — Continued 

Ferrous  gluconate 

Fructose 

Lecithin 

Liver  concentrate 

Liver,   desiccated 

Magnesium  gluconate 

Manganese  gluconate 

Potassium  gluconate 

Sodium  glycerophosphate 

» Vitamins: 
»Vitamin  A  alcohol  and  esters: 

Vitamin  A  acetate   (feed  grade) 

Vitamin  A  acetate   (medicinal  grade) 

Vitamin  A  alcohol 

Vitamin  A  natural  esters 

♦Vitamin  A  palmitate   (feed  grade) 

Vitamin  A  palmitate   (medicinal  grade) 

»Vitamin  B-complex: 

*Cyanocobalamln  (except  U.S. P.    crystalline): 

Feed  grade 

Medicinal  grade 

♦Niacin: 

Feed  grade 

Medicinal  grade 

♦Niacinamide 

♦Pantothenic  acid  and  derivatives: 

Calcium  pantothenate  (dextro) 

♦Calcium  pantothenate  (racemic)  (feed  grade) 

Calcium  pantothenate  (racemic)  (medicinal  grade). 
Calcium  pantothenate  (racemic)  -  csilcium 
chloride  complex. 

Dexpanthenol 

Panthenol  (racemic) 

Sodium  pantothenate 

♦Riboflavin: 

Feed  grade 

Medicinal  grade 

♦Other  B-complex  vitamins: 

Biotin - - - 

Cyanocobalamin  (U.S.?.  crystalline) 

Cyanooobalamin  with  intrinsic  factor  concentrate- 

Folic  acid 

Inositol 

Magnesium  nicotinate 

Niacinamide  hydrochloride 

Pyridoxine 

Riboflavin-5-phosphate,  sodium 

Sodiiim  nicotinate 

Thiamine  hydrochloride 

Thiamine  mononitrate 

♦Vitamin  C: 

♦Ascorbic  acid 

Ascorbyl  palmitate 

Calcium  ascorbate 

Sodium  ascorbate 

♦Vitamin  E: 

d- Alpha  tocopherol 

dl -Alpha  tocopherol 

d-Alpha  tocopheryl  acetate 

dl-Alpha  tocopheryl  acetate  (feed  grade) 

dl-Alpha  tocopheryl  acetate  (medicinal  grade) 

d-Alpha  tocopheryl  acid  succinate 

dl-Alpha  tocopheryl  acid  succinate 

♦Vitamin  K: 

Menadione 

Menadione  sodium  bisulfite 

Phytonadione 


PFZ 

SDW 

DLI 

PFN 

ARP. 

WIL. 

WIL. 

PFZ. 

PFZ. 

PFZ. 

SEL. 

HOF. 

HOF 

PFZ 

CW, 

HOF. 

CW. 

EK, 

HOF, 

PFZ. 

EK, 

HOF, 

PFZ. 

GPR, 

MRK 

PMP 

IMC, 

MRK 

ABB,  CKL,  MRK,  NEP,  RIL. 
MRK,  NOP,  RIL,  SCR. 
MRK,  NEP.  PD,  RIL,  SCR. 


MRK,  x. 

CKL,  DLI, 

HFT 

NOP 

NOP. 

CKL,  HFT, 

NOP. 

HOF. 

HOF. 

PD. 

COM,  GPR, 

HOF, 

MRK 

HOF,  MRK. 

HOF. 

MRK. 

WIL. 

ACY. 

STA. 

NEP. 

NEP. 

HOF,  MRK. 

HOF. 

NEP. 

HOF,  MRK. 

HOF,  MRK. 

HOF,  MRK, 

PFZ. 

PFZ. 

PFZ. 

HOF,  MRK, 

PFZ. 

CW,  EK. 

HOF. 

CW,  EK. 

HOF. 

HOF. 

CW,  EK. 

HOF. 

ABB,  HET, 

HFT, 

WHL. 

ABB,  HET, 

HFT, 

WHL. 

MEDICINAL  CHEMICALS 


TABLE  13B.— Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i566~Continued 


Manufacturers'   Identification  codes 
(according  to  list  in  table  22) 


» Vitamins — Continued 
»Other  vitamins: 

Beta-carotene   (Provitamin  A) 

Cholecalciferol   (Vitamin  D3) - 

Ergocalciferol  (Vitamin  Dj) 

•Miscellaneous  medicinal  chemicals: 
Diagnostic  agents: 

Roentgenographic   contrast  media: 

Acetrizoate,    sodium 

Diatrizoate,   meglumine 

Diatrizoate,    sodium 

Diprotrizoate,    sodium 

lodihippurate,    sodium 

lodopyracet 

lopanoic   acid 

lophendylate 

lothalamate,   meglumine 

lothalamate,    sodium 

Methiodal,   sodium 

Other  diagnostic  agents: 

Galactose  (liver  function  test) 

Indocyanine  green  (cardiac  output  test)- 

Metyrapone   (pituitary  function  test) 

Hematological  agents   (except  anticoagulants) 

Aminocaproic  acid 

Cellulose,   oxidized 

Dextran  (plasma  expander) 

anooth  muscle  relaxants: 

Alverlne 

Alverine  citrate 

Alverlne  hydrochloride 

Papaverine  hydrochloride 

Sodium  benzyl  succinate 

Unclassified  medicinal  chemicals: 

Berberine  hydrochloride 

Hydrastine 

Hydrastine  hydrochloride 

Penicillamine  (copper  chelating  agent) 


sm. 

MAL. 
MAL. 
SDW. 
SEW. 


■"■  See  table  7B  for  producers  of  the  technical  grade. 
^  See  table  21B  for  producers  of  the  technical  grade 


130 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


Flavor  and  Perfume  Materials 


TABLE  14B.  --  Flavor  and  perfume  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 

[Flavor  and  perfijme  materials   for  which  separate  statistics  are  given  in  table  14A  are  marked  below  with  an  asterisk 
(»);    those  not  so  marked  do  not  appear  in  table  KA  because  the  reported  data  are  accepted  in  confidence  and  may 
not  be  published.   Manufacturers'   identification  codes  shown  below  are  taken  from  table  22.   An  x  signifies  that  the 
manufacturer  did  not  consent  to  his  identification  with  the  designated  product] 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


FLAVOR  AND  PEHFUME  MATERIALS,    CYCLIC 


Benz 


and  Naphthale 


2'-Acetonaphthone   (Methyl  p-naphthyl  ketone) 

Acetophenone 

7-Acetyl-6-ethyl-l,l,4,^-tetramethyl-l,2,3,<;-tetra- 
hydronaphthalene . 

p-Allylanlsole 

»4-Allyl-2-methoxyphenol  (Eugenol) 

Allyl  phenoxyacetate 

4-Allylveratrole   (Eugenyl  methyl  ether) 

*Anethole  (p-Propenylanisole) 

♦p-Anisaldehyde   (p-Methoxybenzaldehyde) 

Anlsole   (Methyl  phenyl  ether) 

Anisyl  acetate 

Anisyl  alcohol 

*Benzophenone 

»Benzyl  acetate 

"Benzyl  alcohol 

Benzyl  benzoate 

»Benzyl  butyrate 

*Benzyl  clnnamate 

"Benzyl  ether 

Benzyl  formate 

Benzyl  glyceryl  aoetal 

Benzyl  isobutyrate 

Benzyl  isopentyl  ether 

1- ( Benzyloxy ) -2-methoxy-A-propenylbenzene   ( Benzyl 
isoeugenyl  ether). 

"Benzyl  phenylacetate   (Benzyl  a-toluate) 

"Benzyl  propionate 

"Benzyl  salicylate 

a-Bromostyrene 

A  '-tert-Butyl-2  ',  6  '-dimethyl-3  ',  5  '-dinltroaoeto- 

phenone  (Musk  ketone). 
6-tert-Butyl-3-methyl-2,4-dinitroanisole   (Mjsk  ambrette)- 
p-tert-Butyl-a-methylhydrocinnamaldehyde   ( a-Methyl- 

p-  ( p-tert-butylphenyl) proplonaldehyde ) . 
5-tert-Butyl-l,2,3-trljnethyl-'i,6-dinltrobenzene   (5-tert- 
Butyl-A, 6-dinitrohemlmellitene) . 

5-tert-Butyl-2,'4,6-trlnitro-m-xylene   (Miek  xylol) 

Carvacrol  (2-p-Cymenol) 

"Cinn am aldehyde 

Cinnamic  acid 

"Cinnamyl  acetate 

"Cinnamyl  alcohol 

Cinnamyl  anthranilate 

Cinnamyl  cinnamate 

Cinnamyl  formate 

Cinnamyl  isovalerate 

Cinnamyl  propionate 

trans-Decahydro-2-naphthol 

Dihydronordlcyclopentadienyl  acetate 

p,a-Dimethylbenzyl  alcohol  (p-Methylphenylmethyl- 
carbinol) . 

Dimethylhydroquinone 

a,a-Dimethylphenethyl  acetate   (DMBCA) - 

a,a-Dlinethylphenethyl  alcohol  (DMBC) 

4,6-Dinltro-l,l,3,3,5-pentamethylindane 

Diphenylme thane 

l,3-Diphenyl-2-propanone  (Dibenzyl  ketone) 

l-Ethoxy-2-hydroxy-'i-propenylbenzene  ( Propenyl-guaethol; 
6-ethoxy-m-anol) . 


GIV,    TBK. 

GIV,    TBK. 

GIV,    TBK. 

GIV. 

FB,    GIV,    ICO, 

IFF, 

LUE, 

GIV. 

GIV,    TBK. 

MiZ,    FB,    GLD, 

HNW, 

HPC. 

GIV,    OPC,    SHL, 

TBK, 

UNG. 

GIV. 

GIV,    TBK. 

GIV,    TBK. 

QAF,    GIV,    ICO, 

NEO, 

TBK. 

GIV,    IFF,    OPC, 

SHL, 

TBK, 

BPC,    OPC,    SHL, 

TBK, 

VEL. 

MON,    OPC,    TBK, 

VEL. 

FB,    GIV,    TBK. 

FB,    GIV,    ICO, 

TBK. 

OPC,    SHL,    VEL. 

GIV,    TBK. 

GIV. 

TBK. 

GIV. 

GIV,    TBK. 

GIV,    m,    TBK 

FB,    GIV,    TBK. 

GIV,    OPC,    TBK, 

UNG. 

TBK. 

GIV. 

GIV. 

GIV. 

GIV. 

GIV. 

GIV. 

FB,    OPC,    TBK, 

BPC. 

FB,    GIV,    TBK. 

FB,    GIV,    NEC, 

TBK, 

FEL,    RT. 

TBK. 

TBK. 

TBK. 

GIV,    TBK. 

IFF. 

GIV. 

GIV. 

ICO. 

GIV,    IFF,    RDA 

GIV,    IFF. 

GIV. 

ARA,    TBK, 

GIV. 

SHL. 

I,  TBK,  UNG,  VLY. 


FLAVOR  AND  PERFUME  MATERIALS 


-Flavor  and  perfume  materials  for  which  U.S.  productior 
mnnufacturer,  i  566- -Continued 


or  sales  were  reported,  identified  by 


Manufacturers'   Identification  codes 
(according  to  list  in  table  22) 


FUVOR  AND  PERFUME  MATERIALS,    CYCLIC— Continued 

Benzenoid  and  Naphthalenoid- -Continxied 

»2-Ethoxynaphthalene   (Ethyl  |i-naphthyl  ether) 

Ethyl  anthranilate ■ 

Ethyl  benzoate 

Ethyl  cinnamate 

Ethyl  a, P-epoxy-P-methylhydrocinnamate  (Ethyl 
methylphenylglyoidate) . 

Ethyl  eugenol 

2-Ethylhexyl  salicylate 

Ethyl  phenylacetate 

Ethyl  3-phenylglycidate— - -- 

Ethyl  salicylate 

Ethylvanillin - - 

Eugenol  acetate 

a-Hexylcinnamaldehyde 

Ifydratropaldehyde   (a-Phenylproplonaldehyde) 

Hydratropaldehyde,   dimethyl  aoetal 

Hydroxycitronellal  methyl  anthranilate 

2-Hydroxypropyl  p-N,N-bis(2-hydroxypropyl)amino- 
benzoate. 

Isobutyl  cinnamate 

»Isobutyl  phenylacetate   (Isobutyl  a-toluate) 

»Isobutyl  salicylate 

Isoeugenyl  acetate 

»Isopentyl  salicylate   (Isoamyl  salicylate) 

p-Isopropylbenzaldehyde   (Cumaldehyde) 

p-Isopropylcyclohexanol 

p- Isopropyl-a-methylhydrocinnamaldehyde   ( Cyclamen 
aldehyde). 

p-Isopropyl-a-methylhydrocinnamyl  alcohol 

»A '-Jfethoxyacetophenone 

2-Methoxynaphthalene   (Methyl  P-naphthyl  ether)— 

Ifethoxyphenyl  butanone 

l-(p-Jfethoxyphenyl)-l-pentene-3-one 

•2-Jfethoxy-4-propenylphenol  ( Isoeugenol) 

-i'-Methylacetophenone   (Ifethyl  p-tolyl  ketone) 

Jfcthyl  anisate — 

*p-Methylanisole   (p-Cresyl  methyl  ether) 

»Methyl  anthranilate 

Methylanthanilydene  p-isopropyl  methylhydrocinnamal- 
dehyde. 

Methyl  benzoate 

a-Methylbenzyl  acetate   (Styralyl  acetate) 

p-Methylbenzyl  acetate 

a-Methylbenzyl  alcohol 

»a-Methylclnnamaldehyde 

»lfethyl  cinnamate 

Msthyl  eugenol 

p-tfethyl  hydratropic  aldehyde 

Methyl  N-methylanthranilate   (Dimethyl  anthranilate)— 

Methyl  phenylacetate  (Methyl  a-toluate)- 

2-»fcthyl-4-phenyl-2-butanol(a,ix-Dlmethyl-3-phenyl- 
1-propanol) . 

»Methyl  salicylate   (Synthetic  wintergreen  oil) 

»a-Pentyloinnamaldehyde   (a-Amylcinnamaldehyde) 

Phenethyl  acetate 

Phenethyl  alcohol 

Phenethyl  formate 

»Phenethyl  isobutyrate 

Phenethyl  isovalerate 

•Phenethyl  phenylacetate   (Phenethyl  a-toluate) 

»Phenethyl  propionate 

Phenethyl  salicylate 

2-Phenoxyethyl  isobutyrate 

Phenylaoetaldehyde  (a-Tolualdehyde) 

Phenylacetaldehyde,  dimethyl  acetal 

o-Phenylanisole  (2-Methoxybiphenyl) 

4-Phenyl-3-buten-2-one   (Benzylidene  acetone) 

Phenylethyl  acetal 


GIV 

ICO 

TBK 

FB. 

TBK 

GIV 

TBK 

GIV, 

TBK 

ICO 

ICO 

GIV 

GIV 

TBK. 

FB, 

TBK. 

MON 

RDA. 

GIV. 

GIV 

IFF, 

TBK 

GIV 

IFF. 

GIV, 

IFF. 

GIV. 

SHL. 

TBK. 

FB, 

GIV, 

OPC, 

TBK. 

FB, 

GIV, 

TBK. 

TBK. 

FB, 

GIV, 

OPC, 

TBK. 

GIV. 

GIV. 

GIV, 

RDA. 

GIV. 

GIV, 

ICO, 

OPC 

TBK. 

GIV, 

TBK. 

TBK. 

GIV. 

GIV, 

SHL, 

TBK 

VLY. 

OPC, 

TBK. 

ICO. 

GIV, 

TBK, 

VLY 

DOW, 

FB, 

GIV, 

MEE,  OPC,  SHL,  UNO 

HDA. 

HN. 

GIV, 

TBK, 

VLY. 

IFF. 

UCC. 

FB, 

GIV, 

TBK, 

VLY. 

FB, 

ICO, 

TBK. 

ICO. 

GIV. 

GIV, 

OPC. 

GIV, 

TBK. 

IFF. 

CFC, 

DOW, 

HN, 

MON,  PEN. 

FB, 

GIV, 

IFF, 

NEO,  RDA,  TBK,  VLY 

GIV, 

IFF. 

orv. 

IFF, 

OPC 

IFF, 

TBK. 

GIV, 

IFF, 

TBK 

FB, 

GIV. 

FB, 

GIV, 

IFF, 

TBK. 

GIV, 

IFF, 

TBK. 

GIV, 

TBK. 

GIV, 

IFF, 

TBK. 

GIV, 

TBK. 

GIV, 

TBK. 

GIV. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  14B. 


-Flavor  and  perfume  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  7566--Continued 


Manufacturers'   identification  code 
(according  to  list  in  table  22) 


FLAVOR  AND  PERFTME  MATERIALS,   CYCLIC— Continued 
Brnzenoid  and  Naphthalenoid--Continued 


Phenylethyl  tiglate 

«3- Phenyl- 1-propanol  (Hydrocinnamic  alcohol) 

3- Phenyl- l-propyl  acetate  ( Hydrocinnamy 1  acetate) - 
Phenyl  propyl  cinnamate 

»4-Propenylveratrole   (Isoeugenyl  methyl  ether) 

p-Propylanisole 

p-Tolualdehyde  (p-Methylbenzaldehyde) 

p-Tolylacetaldehyde 

»p-Tolyl  acetate  (p-Cresyl  acetate) 

p-Tolyl  isobutyrate   (p-Cresyl  isobutyrate) 

p-Tolyl  phenylacetate   (p-Cresyl  a-toluate) 

«a-(Trichloromethyl) benzyl  acetate   (Rosetone) 

p-a,  a-Trimethylphenethyl  alcohol 

Trimethyltetrahydrobenzylidene  acetone 

Vanillin- — 

All  other — 


Terpenoid.  Heterocyclic,    and  Alicycl 


Allyl  cyclanexyl  propionate 

Allyl  ionone 

p-tert-Amylcyclohexanone 

Amyris  acetate 

Bomyl  acetate 

<;-tert-Butylcyclohexanol 

'i-tert-Butylcyclohexanone 

i-tert-Butyloyolohexyl  acetate 

Cadinene 

Carvone  (Carvol) 

P-Caryophyllene 

Cedarwood  acetate 

Cedranone 

Cedrenol 

Cedrol 

»Cedryl  acetate 

•Citral  a  (Geranial) 

Citral  dimethyl  acetal 

Citronellal 

»Citronellol 

•Citronellyl  acetate 

Citronellyl  butyrate 

»Citronellyl  formate 

Citronellyl  isobutyrate 

Citronellyl  oxyacetaldehyde 

Citronellyl  propionate 

*Couiiiarin-" --_--._-- .......... 

Cyolohexylcyclohexanone 

(^clopentanone 

Dlhydroterpinyl  acetate 

"Essential  oils,  chemically  modified: 

Acetyl  cedrene 

Citronella  oil,  acetylated 

Clove  leaf  oil  terpenes 

Ethyl  oxyhydrate 

Quaiacwood  acetate 

Lavandin,  acetylated 

Oil  clove  stem,  acetylated 

Santalol 

Sassafras  oil,   hydrogeuated 

a-Furfural  mercaptan 

»Geranlol 

Geranoxy  acetaldehyde 

»C3eranyl  acetate 

Geranyl  benzoate 

Geranyl  butyrate 

"Qerauyl  formate 

Geranyl  isobutyrate 


FB. 

FB,    GIV,    TBK. 

FB,    GIV,    TBK. 

FB. 

GIV,    ICO,    TBK. 

GIV. 

GIV,    HN. 

GIV. 

GIV,    ICO,    IFF,    TBK. 

IFF. 

GIV. 

ICO,    NEO,    TBK. 

IFF. 

TBK. 

MON,    SLV. 

FB,    GIV,    IFF,    PFW,    SHL. 

GIV. 

GIV,    IFF. 

IFF. 

GIV. 

FEL. 

IFF. 

DOW. 

DOW,    IFF. 

FB. 

FB,    FRM,    OPC. 

FB,    GIV. 

FB. 

TBK. 

GIV. 

GIV,    IFF,    OPC,    TBK. 

GIV,    IFF,    NEO,    TBK,    UNG 

FB,    FEL,    GIV,    HOF,    LUE, 

NEO,    RT,    TBK. 

GIV. 

FB,    GIV,    IFF,    TBK. 

FB,    GIV,    GLD,    IFF,    NEO, 

TBK,    VLY. 

GIV,    IFF,    TBK,    VLY. 

GIV,    TBK. 

GIV,    IFF,    TBK,    VLY. 

GIV,    TBK. 

IFF. 

IFF. 

DOW,    MON,    NEO,    RDA,    TBK 

GIV. 

ARA. 

GIV. 

GIV,    IFF. 

CP,    RT. 

SHL. 

FEL,    FLO,    LUE,    VND. 

FB,    GIV,    TBK. 

FEL,    GIV,    UNG. 

FB. 

GIV,    IFF,    VLY. 

GIV. 

RT. 

FB,    FEL,    GIV,    GLD,    IFF, 

NEO,    TBK,    UNO 

IFF. 

FEL,    GIV,    IFF,    NEO,    TBK 

VLY. 

QIV. 

GIV,    TBK. 

GIV,    IFF,    TBK,   VLY. 

IFF. 

FLAVOR  AND  PERFUME  MATERIALS 


TABLE  14B. 


-Flavor  and  perfume  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i966--Contmued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


FLAVOR  AND  PERFUME  MATERIALS,   CYCLIC— Continued 

Terpenoid,   Heterocyclic,   and  Alicyclic--Contimied 

Geranyl  isovalerate 

Oeranyl  phenylaoetate  (Geranyl  a-toluate) 

Geranyl  tiglate 

Hexadecanollde 

2-Hexyl-2-cyclopenten-l-one 

Ifydrocoumarin  (Sj-i-Dihydrocoumarin) 

»f^droxycltronellal 

•ffydroxycltronellal,   dimethyl  acetal 

2-Hydroxy-3-methyl-2-cyclopenten-l-nno   (Methyl 

cyclopentenolone) . 
■4-(<C-l^roxy-4-methylpentyl)-3-cyclohexene-l- 
0  arbox  aldehyde . 

3-Hydroxy-2-methyl-"i-pyrone   (Maltol) 

Indole 

»lonones: 

a-Ionone 

P-Ionone 

lonone  (a-  and  P-) 

Isobomeol  (Isobomyl  alcohol) 

»lEobornyl  acetate 

Isobomyl  methoxycyclohexanol 

2-lBObutylquinoUne   (a-Isobutylqulnollne) 

lEcmenthone 

6-Isopropylquinoline  (p-Isopropylquinollne) 

Isopulegol 

Isosafrole 

Laevo  carveol 

d-Limonene 

Linalool  (Linalyl  alcohol) 

Linalyl  acetate 

Linalyl  anthranilate 

Linalyl  isobutyrate 

Linalyl  propionate 

Jfenthadlene-7-carbinol 

1, l-p-Menthen-6-yl-l-propanone 

•Menthol,    synthetic: 

Tech 

U.S.P - 

»Menthone 

Menthyl  acetate 

6-lfethylcoumarln 

•Uethylionones: 

6-Methyl-a-ionone 

6-Mb  thy 1-P-ionone 

Methylionone   (a-   and  P-) 

Methyl  ionone  standard 

4-Methyl-2-(2'-methyl-l-propan-l-yl)-tetrahydropyran-' 

»Nerol 

Neryl  acetate  prime 

Nopyl  acetate 

Onega  decenol  (Hosalva) 

ci-Phellandrene 

•Piperonal  (Hellotropln) 

Piperonal,  sodium  bisulfite  con^lex 

Piperonal  terpenes 

Pseudolinalyl  acetate  (J^cenyl  acetate,  principally)- 

•Hhodinol 

Rhodlnyl  acetate 

Safrole 

«S»eeteners,  synthetic: 

Cyclohexanesulfamio  acid 

Cyolohexanesulfamic  acid,  calcium  salt 

Cyclohexanesulfamic  acid,  sodium  salt 

Saccharin 

Saccharin,  calcium  salt 

Saccharin,  sodium  salt 

All  other — — - 


GIV,  TBK. 

FB. 

IFF. 

IFF. 

GIV,  TBK. 

GIV,  GLD,  IFF,  OPC 

TBK 

VLY. 

FB,  GIV,  IFF,  TBK. 

DOW, 

IFF. 

DOW,  PFZ. 

GIV,  LUE. 

GIV,  IFF,  MYW,  NEO 

TBK 

HOF,  MYW,  TBK. 

GIV,  LUE,  MYW,  TBK 

UNG 

RDA. 

FB,  GIV,  OPC,  RDA, 

TBK, 

UNG. 

IFF. 

IFF. 

GIV,  TBK. 

FMT. 

GIV. 

GIV. 

FB. 

RT,  SKG. 

FB,  FEL,  GIV,  GLD, 

HOF, 

LUE, 

FB,  GIV,  GLD,  HOF, 

LUE, 

NEO, 

FMP. 

HOF,  TBK. 

FB,  GIV,  HOF. 

RT.   ■ 

GIV. 

GIV,  ICO,  NEO. 

GIV,  GLD,  HNW,  NEO 

GIV,  HNW,  NEO,  OPC 

FB,  GIV. 

GIV. 

GIV,  IFF,  im. 

NEO,  TBK. 

GIV,  LUE,  MYW,  TBK 

TBK. 

GIV. 

FB,  GLD,  IFF,  TBK, 

VI-Y. 

GIV. 

SHL,  VLY. 

IFF. 

ICO. 

GIV,  SHL,  TBK. 

SHL. 

SHL. 

IFF. 

FB,  FEL,  GIV,  IFF, 

LUE, 

NEO, 

FB,  GIV,  IFF. 

GIV,  OPC. 

ABB. 

ABB,  CYC,  DRW,  MDN,  NHS,  PBY,  PFZ,  UliS. 

ABB,  DRW,  MON,  NRS,  PBY,  PFZ,  UNS. 

MEE,  UDU,  NRS. 

MEE,  MON,  NRS,  PBY. 

MEE,  KDN,  NRS. 

GIV 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  14B.  --Flavor  and  perfume  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i566- -Continued 


FLAVOR  AMD  PERFUME  MATERIALS,    CYCLIC— Continued 


Terpenoid, 


cycli 


and  Ali 


«Terpineols: 

a-Terpineol 

P-Terpineol 

Terpineol  (a-   and  P-) 

Terpinol  hydrate  (Terpin  hydrate),    teoh- 

»a-Terpinyl  acetate 

a-Terpinyl  propionate 

Tetrahydro  alloocimenol 

Tetramethy lethy lacety Itetralin 

3,5,5-Trimethyloyclohexanol 

Vetlvenol 

»Vetivenyl  acetate 

All  other 


FLAVOR  AND  PERFUME  MATERIALS,  ACYCLIC 


Manuf aoturere '  identification  codes 
(according  to  list  in  table  22) 


HFC. 
MEG. 


RDA,  TBK,  UNO. 


TBK. 
GIV,  IFF,  NEO,  TBK. 
IFF. 


Acetyl  propionyl 

Allyl  heptanoate  (Allyl  enanthate) 

»Allyl  hexanoate  (Allyl  eaproate) 

Allyl  Isothiooyanate  (Synthetic  mustard  oil) 

Allyl  mercaptan 

Allyl  sulfide  (Diallyl  sulfide) 

Amyl  propionate 

Brazinol r 

Butyl  butyrate 

Butyl  butyryl  lactate 

Butyl  isovalerate 

Butyl  undeoylenate 

Decanal  (Capr aldehyde)  (Cio) 

Diethyl  sebacate  (Ethyl  sebaoate) • 

Diethyl  succinate 

2,6-Dlmethyl-5-hepten-l-al 

3,6-Dimethyl-3-octanol 

3,7-Dimethyl-l-octanol 

3,7-Dimethyl-3-ootanol 

Dimethyl  succinate 

Dodecyl  acetate  (Lauiyl  acetate) 

Ethylamyl  ketone 

»Ethyl  butyrate 

Ethyl  caprate 

Ethyl  decanoate 

Ethylene  brassy late 

Ethylene  glycol  tridecandiote 

Ethyl  formate 

»Ethyl  heptanoate   (Ethyl  enanthate) 

Ethyl  hexanoate   (Ethyl  eaproate) 

Ethyl  Isovalerate— 

Ethyl  laurate 

Ethyl  myrlstate 

Ethyl  nonanoate  (Ethyl  pelargonate) 

Ethyl  oetanoate  (Ethyl  caprylate) 

Ethyl  propionate 

•Glutamic  acid,  monosodium  salt  (IfcnoBodlum  glutamate) 

Heptanal  (Enanthaldehyde)    (C7) 

4-Heptaiione  (Butyrone)   (W-n-propyl  ketone) 

Heptyl  alcohol  (1-Heptanol) 

Heptyl  ether  (Enanthio  ether) 

2-Hexenal 

cis-3-Hfixen-l-ol 

Hexyl  oetanoate  (Hexyl  caprylate) 

cis-3-Hexyn-l-ol 

3-Hydroxy-2-butanone  (Acetoin) 

4-Hydroxynonanoio  acid,   y- lactone     (y-Nonalaotone) 

-;-Hydroxyootanoie  acid,   y- lactone     (Y-Octalactone) 

««;-l^droxyundeeaiioie  acid,  y-laotone     (Y-Undeealactone) 

iBoamyl  propionate 

l8obul7l  acetate 


TBK. 

FB,    GIV,    UNG. 

MRT. 

HT. 

RT. 

GIV. 

RDA. 

TBK. 

ICO. 

TBK. 

GIV. 

GIV,    IFF,    OPC,    TBK. 

FEL,    TBK. 

TBK,    UCC. 

GIV. 

cue. 

GIV,    VLY. 

GIV. 

ICO. 

TBK. 

GIV. 

FB,    NW,   RT,   TBK. 

FB. 

TBK. 

VLY. 

RDA- 

FB. 

FB,   FEL,   RT,   TBK. 

NW,   TBK. 
FB. 

TBK. 
GIV,  RT. 
GIV,  TBK. 
FB,  TBK. 
FB. 


GRW,    mC,    MRK. 


COM, 

BAC. 

TBK. 

BAC,    UCC. 

TBK. 

GIV. 

TBK, 

X. 

Fvr. 

GIV,   TBK, 

GIV,   TBK. 

FB,    GIV,    TBK. 

FB. 

FB.    TBK- 


FLAVOR  AND  PERFUME  MATERIALS 


TABLE  14B.  --Flavor  and  perfume  materials  for  which  U.S.  production  or  sales  were 
manufacturer,  2 966 --Continued 


sported,  identified  by 


ManuTacturere '   identification  codes 
(according  to  list  in  table  22) 


FLAVOR  AND  PERFUME  MATERIALS,    ACYCLIC— Continued 

»Isopentyl  butyrate   (Isoamyl  butyrate) 

Isopentyl  formate  (Isoamyl  formate) 

Isopentyl  heptanoate 

Isopentyl  isovalerate   (Amyl  isovalerate) 

Lauraldehyde   (Dodecyl  aldehyde)    (C12) 

Linalyl  butyrate 

Methyl  furoate - — 

6-Ktethyl-5-hepten-2-one 

kfethyl-p-methylthlopropionate 

Methyl-2-nonenoate— 

Methjlolmethylhexyl  ketone 

3-Methylthlopropionaldehyde 

2-Methylundecanal  (2-MethyLnonylacetaldehyde) 

Myristic   aldehyde   (C14) - 

Nonanal  (Pelargonaldehyde)    (C,) 

Nonanedlol  monoacetate 

Nonanol 

Nonyl  acetate 

Octanal   (Caprylaldehyde)    (Cj) 

n-Octyl  formate 

n-Octyl  Isobutyrate 

Tepyl  acetate 

Trimethyl  hexanal,    sodium  bisulfite  complex 

2,6,10-Trimethyl-9-undecen-l-al 

Undecanal   (Hendecanaldehyde)   (Cii) — 

2-Undecanone   (Xtethyl  nonyl  ketone) 

9-Undecenal  (9-Hendecenaldehyde) 

9-Undecen-l-ol  (9-Hendecenol) 

10-tIndecen-l-ol 

Valerolactone 


FB, 

GIV, 

NW,    RT,    TBK 

FEL 

RT, 

TBK. 

FEL. 

FB, 

TBK. 

GIV, 

IFF 

TBK. 

niv. 

FB. 

GIV. 

RT. 

GIV. 

GIV. 

RT. 

GIV, 

TBK. 

GIV, 

IFF. 

GIV, 

TBK. 

GIV. 

TBK. 

GIV. 

GIV, 

IFF. 

FB. 

FB, 

TBK. 

IFF, 

TBK. 

SHL. 

GIV. 

GIV, 

IFF, 

TBK. 

GIV. 

GIV, 

TBK. 

TBK. 

GIV. 

GIV. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


Plastics  and  Resins  Materials 


TABLE  15B. — Plastics  and  resin  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 

[Plastics  and  resin  materials  for  which  separate  statistics  are  given  in  table  15A  are  marked  below  with  an 
asterisk  (*);  chemicals  not  so  marked  do  not  appear  in  table  ISA  because  the  reported  data  are  accepted  in 
confidence  and  may  not  be  published.  Manufacturers'  identification  codes  shown  below  are  taken  from  table  22. 
An  X  signifies  that  the  manufacturer  did  not  consent  to  his  identification  with  the  designated  product  ] 


Manufacturers '  identification  codes 
(according  to  list  in  table  22) 


THERMOSETTING  RESINS 


»AlJ!yd  reeins,  domestic: 
»Phthalio  anhydride  type- 


«Coumarone-indene  and  petroleum  polymer  resins; 

»Floor  tile 

»Rubber  compounding 

»A11  other  uses  (including  ejcport) 

Epoxy  resins: 

»Unmodified: 

»Bonding  and  adhesives 

♦Protective  coatings 

♦Reinforced  plastics 

*A11  other  uses  (including  export) 

♦Modified 


♦Polyester  resins: 

Reinforced  plastics: 
"Sheets,  flat  and  corrugated 

*AU  other 

♦Surface  coatings 

♦All  other  uses  (Including  export)- 

♦Phenolic  and  other  tar  acid  resins: 
♦Molding  materials 

Bonding  and  adhesive  reslne  for: 
♦Laminating 

♦Coated  and  bonded  abrasives 

♦Friction  materials 

♦Thermal  insulation 

♦Foundry  or  shell  molding 

♦Plywood . 

♦Fibrous  and  granulated  wood 


AAI,  ACP,  ACY,  ADM,  AMR,  APV,  BAl,  BEN,  BOY,  BRU,  CEL, 
CIK,  CM,  COM,  CPV,  DAV,  DEC,  DSO,  DUN,  DUP,  EW,  FAR, 
FBR,  FCD,  FLW,  FOC,  FRE,  FSH,  GEI,  GIL,  GLD,  GRG, 
GRV,  HAN,  HPC,  HRS,  ICF,  JOB,  JSC,  JWL,  KEL,  KMC, 
KMP,  KPS,  KYN,  MCC,  MID,  MMM,  MNP,  MR,  NPV,  NCI, 
NTL,  ORO,  QSB,  OXR,  PER,  PFP,  PPG,  PRT,  QCP,  RCI, 
RED,  REL,  RH,  SCF,  SCN,  SED,  SIP,  SM,  SRR,  SVC,  SW, 
SYV,  TV,  VTV,  WAS. 

ACP,  ACY,  ADM,  APT,  APV,  BEN,  BRU,  CGL,  CM,  COM,  CPV, 
DSO,  DUN,  DUP,  EW,  FAR,  FBR,  FCD,  FOC,  GEI,  GIL, 
GLD,  GRV,  HAN,  HPC,  HRS,  HYC,  ICF,  KYN,  MCC,  MID, 
MMM,  NCI,  NON,  NPV,  ORO,  OSB,  PFP,  PPG,  PRT,  RCI, 
RED,  RH,  SCN,  SHA,  SM,  SRR,  SW,  TV,  VTV. 

ACC,  ACP,  NEV,  NSP,  PAI,  RCI,  VEL. 
ACC,  ACP,  KPI,  NEV,  NSP,  PAI,  RCI,  VEL,  WTC. 
ACC,  ACP,  CM,  DSO,  DUP,  ENJ,  MCA,  MID,  NEV,  NSP,  PAI, 
PPG,  RCI,  VEL,  VSV. 


CBA,  CEL,  DOW,  SHC,  UPC. 

CBA,  CEL,  DOW,  RCI,  SHC,  UCP. 

CBA,  CEL,  DOW,  RCI,  SHC,  UCP. 

CBA,  DOW,  RCI,  SHC,  UCP. 

ACP,  ADM,  BEN,  CM,  FMP,  FOM,  GLD,  HAP,  IOC,  LEF,  MID, 

MMM,  MNP,  MRB,  NON,  QSB,  PI£,  PPG,  PYR,  REZ,  SCN, 

SRR,  VTV,  WAS. 


ACY,  APD,  DA,  EW,  GLD,  HKD,  ICF,  LAS,  MFG,  ORO,  PPG, 

RCI,  RH,  SIC,  SW,  USR. 
ACP,  ACY,  ADM,  CPV,  DA,  DSO,  FRE,  GLD,  GNT,  GRV,  HKD, 

ICF,  IPC,  KPS,  LAS,  MFG,  MRO,  PLU,  PPG,  RCI,  SW, 

USR,  UTR,  VAL. 
ACP,  ACY,  APD,  COM,  CPV,  DA,  GLD,  GYH,  ICF,  MCC,  ORO, 

PPG,  SM,  SW. 
ACP,  ACR,  ACY,  AMR,  APD,  DA,  DAV,  DSO,  EKT,  EPC,  EW, 

FMP,  FRE,  GEI,  GLD,  GNT,  GRG,  GYR,  HKD,  LAS,  MMM, 

OCF,  PLU,  PPG,  RCI,  RH,  SCN,  SW,  TXT,  USR,  VAL. 

FRL,  GE,  HER,  HKD,  HVG,  MON,  MRB,  NPI,  PIS,  RCI,  RGC, 
SYR,  UCP,  VAR,  VSV. 

ACP,  AMR,  BOR,  CAT,  CBR,  CD,  EW,  FOM,  GE,  HKD,  IRI, 

MCA,  MON,  NPI,  NPP,  NTC,  NVF,  PGU,  PPL,  PYZ,  RCD, 

RCI,  SCN,  SPL,  SYR,  TKL,  UCP,  VAR. 
AMR,  BME,  BOR,  CAT,  CBM,  CBR,  HKD,  MUM,  MON,  MRB,  PPG, 

PYZ,  SCN,  SYR,  UCP,  VAR. 
ABS,  BME,  BOR,  FRL,  GE,  HKD,  MMM,  MON,  PYZ,  RAB,  SCN, 

SYR,  SYV,  UCP,  VAR,  VSV. 
ACP,  AMR,  CAT,  HKD,  MON,  OCF,  PYZ,  RCI,  SCN,  UCP. 
ACP,  ACR,  AMR,  BOR,  GE,  HKD,  MON,  NPI,  PYZ,  RCI,  SCN, 

SYR,  TXT,  UCP,  UNO,  VAR. 
BOR,  CAT,  CBC,  CBD,  HPC,  MON,  PGU,  PYZ,  RCI,  RH,  SIM, 

WCA,  WHD. 
AMR,  BOR,  CBC,  CBD,  HKD,  MCA,  MON,  NPI,  PYZ,  RCI,  SIM, 

UCP,  UPL. 


PLASTICS  AND  RESIN  MATERIALS 


137 


■Plastics  and  resin  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966- -Continued 


Manufacturers'   Identification  codes 
(according  to  list  in  table  22) 


THERMOSETTING  RESINS— Continued 

»Phenollc   and  other  tar  acid  resins — Continued 
•Protective  coatings,  unmodified  and  modified 

»A11  other  uses   (including  export) 

•Polyurethane  am    dlisocyanate  resi"S 

»Rosin  modifications: 

»Rosin  and  rosin  esters,   unmodified  fester  gums) 

»A11  other 

•Silicone  resins 

Styrene -alkyd  polyesters 

»Urea  and  melamine  resins: 

•Textile  treating  and  coating  resins 

•Paper  treating  and  coating  resins 

Ifolding  materials 

Bonding  and  adhesive  resins  for: 
•Laminating 

•Plywood 

•Fibrous  and  granulated  wood 

•Protective  coatings 

•All  other  uses  (including  export) 

•All  other  thermosetting  resins 


THERMOPLASTIC  RESINS 


Acrylic  resins 

•Cellulose  plastics  materials: 
Sheets,  continuous: 
•Under  0.003  gage 

•0.003  gage  and  over 

•All  other  sheets,  rods,  and  tubes 

•Molding  and  extrusion  materials 

•Polyamide  resins: 

•Nylon  type 

•Non-nylon  type 

Polyolefin  plastics  materials: 
Ethylene  polymers  and  copolymers: 
Production: 

•High  pressure  polyethylene 

•Low  pressure  polyethylene 

•Ethylene  copolymers 

•Polyethylene,  density  0.9^0  and  below: 
•Sales  and  use: 

•Injection  molding 


•Blow  molding 

•Filin  and  sheet- 


ADM,  BOR,  CIK,  CPV,  DSO,  EW,  FCD,  FRE,  GE,  GEI,  GRV, 
HAN,  HER,  HKD,  ICF,  INL,  KMC,  KRM,  KYN,  MID,  MMM, 
MON,  MRB,  NCI,  NPI,  ORG,  OXR,  PYR,  PE,  RCI,  RH, 
SM,  SNC,  SW,  SYR,  TV,  UCP,  VAR,  VTV,  WAS. 

AC?,  AMR,  BME,  BOR,  CAT,  CBM,  CBR,  DSO,  EW,  GE,  GEI, 
GRG,  HER,  HKD,  IOC,  IRC,  IRI,  KND,  KPT,  MMM,  MON, 
MRB,  NPI,  ?IS,   PYR,  PYZ,  RAB,  RCI,  REZ,  RGC,  RH, 
RPC,  SCN,  SHA,  SNC,  SYR,  UCP,  USR,  VAR,  VSV. 

ACB,  ADM,  AFP,  ARK,  BFG,  CBM,  DUP,  GPM,  HAP,  IPI,  JWI, 
KMC,  MCC,  NOP,  NPV,  PEL,  PFP,  QUN,  SCN,  UPJ. 

ADM,  CBY,  DPP,  ECC,  FAR,  FRP,  HPC,  KRM,  MCC,  NCI,  OSB, 

SRR. 
ADM,  CBY,  DPP,  FAR,  FLW,  FRP,  HPC,  JNS,  KRM,  MCC,  NCI, 

OSB,  PPG,  RH,  SCF,  SHA. 
ACP,  BOR,  DCC,  GLD,  SPD,  UCC. 
ADM,  DEG,  PFP. 

ACY,  APX,  BRY,  CAT,  CBR,  GIB,  CRC,  DAN,  DEP,  DUP,  ECC, 
GAF,  GGY,  HNC,  HRT,  JSC,  MON,  MRA,  ONX,  OXR,  PC,  QCP, 
RCI,  RH,  ROC,  RPC,  S,  SBC,  SEY,  SNW,  STC,  SYN,  USO, 
VAL,  WIC. 

ACY,  AMR,  BME,  BOR,  CBC,  CBD,  CBR,  DEP,  DUP,  HPC,  MMM, 
MON,  RCI,  RH,  SIM,  TXT,  x. 

ACP,  ACY,  FMB,  GDN,  PMC,  SFA. 

ACY,  BOR,  CAT,  CBR,  FOM,  GE,  MON,  NPP,  NTC,  OCF,  PGU, 

PMC,  PPL,  STC. 
ACP,  ACY,  BOR,  CAT,  CBC,  CBD,  HPC,  MON,  NPI,  NTC,  PGU, 

RCI,  REN,  RH,  SAC,  SIM,  SOR,  WRD. 
ACY,  AMR,  BOR,  CBD,  IPR,  MON,  PGU,  RCI,  SAC,  SOR,  SYV, 

UPL. 
ACP,  ACY,  CEL,  CPV,  DSO,  DUP,  GLD,  GRV,  HAN,  KPS,  MID, 

MDN,  NON,  OXR,  PPG,  RCI,  REL,  RH,  SCN,  SW,  TV. 
ACP,  ACY,  AMR,  BOR,  CAT,  CMP,  DUP,  EFH,  FMB,  HPC,  MON, 

RCI,  RH,  STC,  UNO,  VAL,  VAR. 
ACP,  ACY,  CIB,  GGY,  HPC,  HVG,  JNS,  MOB,  MON,  NOP,  NPV, 

NTC,  OCF,  PPG,  RPC,  UBS,  UNO,  WTC. 


ACY,  CEL,  CIB,  CM3,  DUP, 
PPG,  QUN,  RH,  RPC,  SAR, 


HCO,  JNS,  JSC, 


CEL,  DUP,  EKT,  NIX. 

CEL,  DOW,  EKT,  MON,  MPP, 

CEL,  MPP,  NIX,  PDJ,  RSB, 

CBN,  CEL,  DOW,  EKT,  MON, 

ALF,  DUP,  FG,  POL,  SPN. 

BCM,  EMR,  GNM,  JNS,  KRM, 


ACP,  DOW,  DUP,  EKX,  KPP, 
ACP,  CEL,  DOW,  DUP,  HPC, 
DUP,  UCP,  USI. 


NIX,  PDJ,  SPY. 

SPY. 

RSB. 


MON,  RCC,  SPN, 
KPP,  MON,  PLC, 


ACP,  CEL,  DOW,  DUP,  EKX, 

UCP,  USI. 

ACP,  DOW,  DUP,  EKX,  KPP, 

USI. 

ACP,  ALO,  CEL,  DOW,  DUP, 

SPN,  UCP,  USI. 

CEL,  DOW,  DUP,  EKX,  KPP, 

CEL,  DOW,  DUP,  EKX,  KPP, 


KPP,  MON,  PLC, 
MDN,  PLC,  RCC, 
EKX,  KPP,  MDN, 


UCP,  USI. 
UCP,  USI. 


RCC,  SHC,  SPN, 
SHC,  SPN,  UCP, 
PLC,  RCC,  SHC, 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  15B.  --Plastics  and  resin  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i966— Continued 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


THERMOPLASTIC  RESINS— Continued 

Polyolefin  plastics  materials— Continued 
♦Polyethylene,  density  0.940  and  be low- -Continued 
»Sales  and  use — Continued 

»Pipe  and  conduit 

*Other  extruded  products 

»A11  other  uses  (including  export) 

•Polyethylene,  density  over  0.940: 
»Sales  and  use: 

•Injection  molding 

•Blow  molding 

•Film  and  sheet 

•Extrusion  coating  on  paper  and  other  substrates- 

•Wire  and  cable 

•Pipe  and  conduit 

•Other  extruded  products 

•All  other  uses  (including  export) 

Polypropylene : 

•Production 

•Sales  and  use: 

•Molding - - — ■ 

•Extrusion 

•All  other  uses  (including  export) 

•Styrene  type  plastics  materials : 
ABS  and  SAN  resins: 
•Production 

•Sales  and  use: 

•Jtolding 

•Extrusion 

•All  other  uses  (including  export) 

Styrene  and  styrene  copolymer  resins: 
•Production: 

StrEiight  polystyrene 

Rubber-modified  polystyrene 

Styrene-butadiene  copolymer 

All  other - 

•Sales  and  use: 

•Molding 

•Textile  and  paper  treating  and  coating 

•Emulsion  paint 

•Extrusion 

Foam  and  foamable  materials 

•All  other  uses  (including  export) 


Vinyl  resins: 

Polyvinyl  chloride  and  copolymers; 
•Production: 

Suspension  homopolymers 

Suspension  copolymers 

Dispersions  (paste) 


DOW,  EKX,  KPP,  PLC,  UCP,  USI. 

ACP,  DOW,  DUP,  EKX,  KPP,  PLC,  UCP,  USI. 

ACP,  CEL,  DOW,  DUP,  EKX,  KPP,  MON,  PLC,  RCC,  SPN,  UCP, 


ACP,  CEL,  DOW,  DUP,  EKX,  HPC,  KPP,  PLC,  RCC,  SHC,  UCP, 

USI. 

ACP,  CEL,  DOW,  DUP,  EKX,  HPC,  KPP,  MON,  PLC,  RCC,  SHC, 

UCP,  USI. 

ACP,  CEL,  DOW,  DUP,  EKX,  HPC,  KPP,  PLC,  SHC,  UCP,  USI. 

DUP,  EKX,  PLC,  UCP,  USI. 

ACP,  CEL,  DUP,  EKX,  HPC,  MON,  PLC,  SHC,  UCP,  USI. 

ACP,  CEL,  DUP,  EKX,  HPC,  KPP,  PLC,  SHC,  UCP,  USI. 

ACP,  CEL,  DOW,  DUP,  EKX,  HPC,  KPP,  PLC,  UCP,  USI. 

ACP,  CEL,  DOW,  DUP,  EKX,  HPC,  KPP,  MDN,  PLC,  UCP,  USI. 

ALO,  AVS,  DOW,  EKX,  EN  J,  HPC,  NVT,  RCC,  SHC. 

ACP,  AVS,  DOW,  EKX,  ENJ,  HPC,  NVT,  ORO,  PLC,  RCC,  SHC, 

UCP,  USI. 

ACP,  ALO,  AVS,  EKX,  ENJ,  HPC,  NVT,  ORO,  PLC,  RCC,  SHC, 

UCP,  USI,  VEL. 

ACP,  ALO,  AVS,  DOW,  EKX,  ENJ,  HPC,  NVT,  ORO,  PLC,  RCC, 

SHC,  UCP,  USI,  VEL. 


BFG,  DOW,  FBF,  MCB,  HON,  UCP,  USR. 

BFG,  DOW,  MCB,  MON,  MPP,  RCC,  UCP,  USR. 

BFG,  DOW,  FIR,  GRD,  MCB,  MDN,  MPP,  RCC,  SW,  UCP,  USR, 
WIC. 


BPL,  CBN,  CSD,  DOW,  FBF,  FG,  KPP,  MON,  ONX,  ?IA,   POL, 

RCC,  SEK,  SOL,  TIC,  UBS,  UCP,  WAS. 
BPL,  CSD,  DOW,  FG,  GOR,  KPP,  MOhJ,  PLA,  RCC,  SHC,  UCP. 
BFG,  BOR,  DOW,  FIR,  GCC,  GNT,  GRD,  GYR,  ILC,  KPP,  SEP, 

USR,  WIC. 
ACC,  BCN,  BKC,  BOR,  DOW,  DSO,  DUP,  FLH,  GAF,  GLD,  GRD, 

IOC,  JNS,  JSC,  MON,  MRT,  PAI,  PVI,  RCC,  RH,  SM,  SPI, 

UNC,  WAS. 

BFG,  BKC,  BPL,  CSD,  DOW,  FBF,  FG,  FIR,  GOR,  GYR,  KPP, 
MDN,  PLA,  RCC,  SHC,  SOL,  TIC,  UCP,  USR. 

BOR,  DOW,  FIR,  FLH,  GNT,  GRD,  GYR,  ILC,  JSC,  KPP,  MON, 
ONX,  SEP,  USR,  WAS,  WIC. 

BOR,  DOW,  DSO,  FIR,  GNT,  GRD,  GYR,  KPP,  MON,  RCC,  USR. 

CBN,  CSD,  DOW,  DSO,  KPP,  MON,  MPP,  RCC,  SHC,  UCP,  X. 

CSD,  DOW,  GYR,  KPP,  MON,  RCC,  SEK,  SHC,  UNC,  USR,  x. 

ACC,  BCN,  BFG,  BOR,  CSD,  DOW,  DSO,  DUP,  FG,  GAF,  GGC, 
GLD,  GNT,  GRD,  GYR,  IOC,  JNS,  JSC,  KPP,  VON,  MPP, 
MRT,  PAI,  POL,  PVI,  RCC,  RH,  SEK,  SEP,  SHC,  SM,  SPI, 
UBS,  UCP,  UNC,  USR,  WAS. 


AME,  ATU,  BFG,  BOR,  CRY,  CUC,  DA,  DOW,  ESC,  FIR,  GNT, 

GRA,  GYR,  MON,  PU,  SFA,  UCP,  USR. 
AME,  BFG,  BOR,  CRY,  CUC,  DA,  FIR,  QNT,  KYS,  MON,  NSC, 

ONX,  PNT,  SFA,  THC,  UCP. 
BFG,  BOR,  CRY,  DA,  FIR,  GYR,  MDN,  UCP,  USR. 


PLASTICS  AND  RESIN  MATERIALS 


139 


TABLE  15B.  --Plastics  and  resin  materials  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  iP66— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


THERM3PLASTIC  RESINS— Continued 

Vinyl  resins— Continued 

Polyvinyl  chloride  and  copoljniiers — Continued 
»Sales  and  use: 

•Calendering ,   except  flooring 

Flooring : 
•Calendered 

•Coated 

Paper  and  textile  uses: 
•Coating 

•Other 

•Protective  coatings  and  adhesives 

•Wire  and  cable 

•Extruded  film  and  sheet 

•Other  extruded  products 

•Sound  records 

•Injection  and  blow  molding 

•Plastisol  formulating  and  molding 

•All  other  uses  (including  export) 

Polyvinyl  acetate: 
•Production: 

•Latexes 

•Resins 

•Sales  and  use: 

•Qnulsion  paints 

•Adhesives 

•Paper  treating 

•Textile  treating 

•All  other  uses  (including  export) 

•Polyvinyl  alcohol 

•Other  vinyl  resins 

•All  other  thenuDplastic  resins 


FIR,  GNT, 

AME,  ATU,  BFG,  BOR,  CRY,  CUC,  DA,  ESC,  FIR,  MON,  THC, 

UCP. 
BFG,  BOR,  CRY,  DA,  FIR,  GNT,  GYR,  XCN,  THC,  UCP,  USR. 

ATU,  BFG,  BOR,  CRY,  DA,  ESC,  FIR,  M3N,  ONX,  THC,  UCP, 

USR. 
BFG,  BOR,  ESC,  FIR,  ONX,  THC,  UCP. 
BFG,  BOR,  DA,  ESC,  FIR,  MON,  NSC,  UCP. 
AME,  BFG,  BOR,  CRY,  CUC,  DA,  DOW,  FIR,  MON,  PNT,  THC, 

UCP,  USR. 
AME,  BFG,  BOR,  CUC,  DA,  DOW,  FIR,  GYR,  ION,  PNT,  SFA, 

THC,  UCP,  USR. 
ACP,  ATU,  BFG,  BOR,  CRY,  CUC,  DA,  DOW,  ESC,  FIR,  GNT, 

GYR,  MON,  PNT,  SFA,  THC,  UCP,  USR. 
BFG,  BOR,  CRY,  CUC,  DA,  KYS,  MON,  PLA,  PNT,  SFA,  THC, 

UCP,  USR. 
ATU,  BFG,  BOR,  CRY,  DA,  DOW,  ESC,  FIR,  GYR,  MON,  THC, 

UCP,  USR. 
BFG,  BOR,  CRY,  CUC,  DA,  ESC,  FIR,  MON,  PYR,  THC,  UCP, 

USR. 
BFG,  BOR,  CRY,  CUC,  DA,  DOW,  ESC,  FIR,  GNT,  GRA,  GYR, 

ION,  PYR,  SFA,  THC,  UCP,  USR. 


AML,  APV,  BOR,  BOY,  GEL,  CUC,  DSO,  DUP,  FC,  FLH,  GLC, 
GLD,  GRD,  HAN,  HNC,  HRT,  JSC,  KMC,  KMP,  UCC,   MMM, 
MR,  MRN,  NCI,  NPV,  NSC,  NTC,  PII,  PPG,  PVI,  QCP,  REL, 
RPC,  SED,  SEY,  SPC,  UCP,  WAS,  WIC. 

AFP,  BEN,  BIS,   BOR,  CAT,  CST,  CUC,  DAN,  DAV,  DUP,  FAR, 
HNC,  JOB,  MON,  NSC,  OCF,  PPG,  RCI,  SCO,  SED,  SH,  UCP. 

AML,  APV,  BEN,  BOR,  CAT,  CEL,  CUC,  DAV,  DSO,  DUP,  FLH, 

GLC,  GLD,  GRD,  HAN,  JOB,  KMC,  KMP,  MCC,  MON,  MR,  NCI, 

NPV,  NSC,  PPG,  RCI,  SED,  SPC,  UCP,  WAS,  WIC. 
AML,  BOR,  CEL,  CUC,  DUP,  FC,  FLH,  GLC,  GRD,  HNC,  JSC, 

MMM,  M3N,  MRN,  NSC,  NTC,  PII,  PPG,  RCI,  SH,  UCP. 
AML,  BOR,  CEL,  CUC,  DUP,  FLH,  GLC,  MMM,  MON,  NSC,  PII, 

SEY,  UCP,  WIC. 
AML,  BOR,  CEL,  CST,  CUC,  DAN,  DUP,  GLC,  GRD,  HRT,  JSC, 

NSC,  PII,  RPC,  SCO,  SEY. 
AFP,  AML,  BLS,  BOR,  CEL,  CUC,  DUP,  FAR,  FLH,  GLC,  GLD, 

GRD,  HRT,  MON,  NSC,  OCF,  PII,  PVI,  QCP,  REL,  RCI, 

UCP,  WAS. 
BOR,  CUC,  DUP,  FC,  MCC,  MON. 
BOR,  DOW,  DUP,  GLD,  GRD,  IOC,  MON,  SW,  UCP. 
ACG,  ACP,  CBY,  CIB,  DEP,  DUP,  ECC,  GE,  GLC,  HPC,  JSC, 

KRM,  MID,  1AM,  MOB,  RH,  RPC,  SBC,  SCN,  SNW,  UCP. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 
Rubber -Processing  Chemicals 


TABLE  16B.- 


■  Rubber-processing  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 


feubber-processing  chemicals  for  which  separate   statistics  are  given  in  table   16A  are  marked  below  with  an  asterisk 
(»);   chemicals  not  so  marked  do  not  appear  in  table  16A  because  the  reported  data  are  accepted  In  confidence  and 
may  not  be  published.   Manufacturers'   identification  codes  shown  below  are  taken  from  table  22.   An  x  signifies  that 
the  manufacturer  did  not  consent  to  his  identification  with  the  designated  product] 


Chemical 


Manufacturers'  identification  code 
(according  to  list  in  table  22) 


RUBBER-PROCESSING  CHEMICALS,  CYCLIC 

»Aocelerators,  activators,  and  vulcanizing  agents: 
*Aldehyde-amlne  reaction  products: 

Aoetaldehyde-aniline  condensate 

n-Butyraldehyde-anlllne  condensate 

Butyraldehyde-butylldeneanillne  condensate 

i-Ethyl-(i-propylacrylanilide-- 

Formaldehyde -p-toluldlne  condensate 

tteptaldehyde-anlline  condensate 

Trlethyltrlmethylenetri  amine - 

"Dithlocarbamlc  acid  derivatives: 

Dlbutyldithlocarbamlc  acid,  N,N-dimethylcyclo- 
hexylamine  salt. 

Dlbutyldithlocarbamlc  acid,  dlphenylguanldlne  salt 

Dlmethylethylene  dlphenyldithlocarbamic  acid,  lead  salt 

2,A-Dinltrophenyl  dimethyldlthiocarbamate-- 

Piperidinecarbodithioic  acid,  plperidlnium-potassium 
salts,  mixed. 
Guanldlnes: 

Dlcatechol  borate,  di-o-tolylguanidine  salt 

1,3-Diphenylguanldine 

Dlphenylguanldlne  phthalate 

1,3-Dl-o-tolylguanldlne 

1,2,3-Triphenylguanldine 

»Thiazole  derivatives: 

2-Benzothlazyl  N,N-diethylthiocarbamoyl  sulfide 

l,3-Bls(2-benzothiazolylmercaptomethyl)urea 

N-tert-Butyl-2-benzothiazolesulfenamlde 

»N-Cyclohexyl-2-benzothiazolesulfenamlde 

N,N-Dllsopropyl-2-benzothiazolesulfenamlde ■ 

N- ( 2 , 6 -Dime thy Imorphollno )  -2 -benzothiazolesulf enamide - ■ 

»2,2'  -Dlthiobls(benzothiazole ) ■ 

•2-Mercaptobenzothlazole 

2-Mercaptobenzothlazole,  zinc  chloride 

2-MBrcaptobenzothlazole,  zinc  salt 

4-Morpholinyl-2-ben2othlazyl  disulfide -- 

N-Oxydlethylene -2 -benzothiazolesulf enamide 

Thlazollne-2-thiol ■ 

All  other  cyclic  accelerators,  activators,  and 
vulcanizing  agents: 

p-Benzoqulnonedioxime 

Bls(p-amlnocyclohexyl)methane  carbamate 

Bis(2,6-dlmethylmorpholinothlocarbonyl)sulflde 

Dlbenzoyl-p-qulnonedioxlme 

Dlbenzylamlne ' 

N, N'-Dlclnnanylldene-l,6-hexanediamlne 

Di-N,N'-pentamethylenethiuram  tetraeulflde 

4,'i'-Dithlodlmorphollne • 

2 -Imidazoline -2 -thiol ■ 

Poly-p-dlnltrosobenzene 

Styrene  polysulflde - ■ 

Tetrahydro-4,A,6-trimethyl-2(lH)-pyrimldlnethlone 

•Antioxidants,  antlozonants,  and  stabilizers: 

"Amino  antioxidants,  antlozonants,  and  stabilizers: 
Aldehyde-  and  acetone-amlne  reaction  products: 

Acetaldehyde-anlllne  hydrochloride  condensate 

Aldol - :i-naphthy lamlne  condensate 

Butyraldehyde-aniline  condensate 

Dlphenylamlne-acetone  condensate 

Phenyl -2-naphthylamine-acetone  condensate 

•Substituted  p-phenylenediamlnes: 

N,N'-Bls(l,'; -dime  thy  lpentyl)-p-phenylenediamine 

N,N'-Bls(l-ethyl-3-me thy lpentyl)-p-pheny lenedi amine- ■ 


MON,  RCD,  USR. 


ceo. 
ceo. 

USR. 
DUP. 


ACY,  BPG,  MON,  USR. 


ACY, 

BPG, 

GYR,   MON, 

USR 

ACY, 

BFG, 

GYR,   MON, 

USR 

DUP. 

ACY, 

GYR, 

USR. 

GYR. 

ACY, 

MON. 

ACY. 

CTA, 

DUP. 

DUP. 

DUP. 

CTA, 
MI.S, 

USR. 
USR. 

DUP. 

DUP, 

VNC. 

MON. 

DUP, 

RBC. 

DUP. 

TKL. 

USR. 

BFX). 

DUP. 

ACY, 

BFG,   DUP,    USR 

USR. 

ILKT, 

USR,   x. 

EKT, 

MON,    UPM. 

RUBBER-PROCESSING  CHEMICALS 

TABLE  l^B. --Rubber-processing  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
maTuifacturer,  i566— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


RUBBER-PROCESSING  CHIMICAI5,    CYCLIC--Continued 

^Antioxidants,   antlozonants ,   and  stabillzers--Continued 
«Amlno  antioxidants,    antlozonants,   and  stabillzers-- 
Continued 
^Substituted  p-phenylenediamlnes — Continued 

N, N'-Bis(l-methylheptyl)-p-phenylenediamlne 

N-sec-Butyl-N' -phenyl -p-phenylenedlamlne 

N-Cyclohexyl-N' -phenyl -p-phenylenediamlne 

Diarylarylenediamlnes,   mixed 

N,N'-Dl-sec-butyl-p-phenylenediamine 

N,N'-Dl-2-naphthyl -p-phenylenediamlne 

»N,N'-Diphenyl-p-phenylenedlainlne 

N-Isopropyl-N' -phenyl -p-phenylenediamine 

All  other  p-phenylenediamines 

Other  amino  antioxidants,   antlozonants,   and  stabi- 
lizers : 

p-Anilinophenol 

l,2-Dlhydro-6-dodecyl-2,2,'i-trimethylquinoline 

l,2-Dihydro-6-ethoxy-2,2,'i-tri]nethylquinoline 

l,2-Dihydro-2,2,<i-trimethylquinoline 

<i,4'-Dlmethoxydiphenylainine 

"tj-i'-Dloctyldlphenylajiilne 

N.N'-Dlphenylethylenedlamine 

N,N'-Diphenyl-l,3-propanedlamine 

NjN'-Di-o-tolylethylenediamlne 

p-Isopropoxydiphenylamlne 

A,A'-Methylenedianiline 

»Octyldiphenylaiiiine 

Octyldlphenylamlne  mixture   (mono-,  nonyl-,   and  di-). 

N-Phenyl-1-naphthylamine 

»N-Phenyl-2-naphthylamlne 

p-(p-Toluenesulfonamido)diphenylamlne 

All  other -. 

»Phenollc  and  phosphite  antioxidants  and  stabilizers: 
Phosphites : 

Nonyl  phenyl  phosphites,  mixed 

Polyphenolic  phosphite,  polyalkylated 

•PolyphenoliCE  (including  bisphenols) : 

Bisphenol,  hindered 

<»,'i'-Butylidenebis(6-tert-butyl-m-cresol) 

2,5-Di-(l,l-dlmethylpropyl)hydroqulnone 

2,2'-Methylenebis(6-tert-butyl-p-cre3ol) 

2,2'-MethylenebiE(6-tert-butyl-^-ethylphenol) 

2,2'-Methylenebis(6-tert-octyl-p-cresol) 

2,2'-Thlobis(<V,6-di-sec-amylphenol) - 

<i,'i'-Thlobis(6-tert-butyl-m-cresol) 

l,l,3-Tri(2-methyl-^-hydroxy-5-tert-butylphenyl) 
butane . 
Other  phenolic  antioxidants  and  stabilizers: 

p-Benzyloxyphenol 

N-Butyroyl-p-aminophenol 

o-Cresol,  alkylated 

N-Ifluroyl-p-amlnophenol 

»Phenol,   alkylated 

Phenol,  hindered 

Phenol,  styrenated 

N-Stearoyl-p-amlnophenol 

Xylenol,  alkylated 

♦Blowing  agents: 

N,N'-Dlmethyl-N,N'-dinitrosoterephthalamlde 

Dlnltrosopentamethylenetetramine 

p,p'-Oxybis( benzene sulfonhydrazlde) 

•Peptizers : 

Alkylated  o-thiocresol 

Alkylated  thlophenol,  zinc  salt 

A17I  mercaptans 

2 -Benznmi  dothlophene ,  zinc  salt 

2', 2'  '  '-Dithiobis(benzanlllde) 

Dixylyl  disulfides,  mixed 

2-Naphthalene  thiol 

Pentachlorobenzene thiol 


BFG,    EKT, 

MON, 

um. 

USR. 

USR. 

am. 

USR. 

BFG. 

BPG,    DUP, 

USR. 

MON,    USR. 

MON. 

BFG. 

HON. 

MON. 

BPG,  MON. 

DUP. 

BPG. 

CCO,    NOP, 

X. 

CCO. 

CCO. 

BPG. 

USR. 

ACY,   NPI, 

FAS, 

USR. 

BFG. 

DUP,    USR. 

BPG,    DUP, 

USR. 

USR. 

DUP. 

USR. 

BFG. 

GYR. 

MON. 

MON. 

ACY,    CAT. 

ACY. 

ACY. 

MON. 

MON. 

ICI. 

BFG. 

MLS. 

PIT. 

MLS. 

ACY,    BPG, 

CCO, 

GYH,    PAS, 

PIT,    USR 

DUP,    GYR, 

PIT. 

BFG,   GYR, 

USR. 

PIT. 

DUP. 

DUP,    NPI. 

USR. 

PIT. 

PIT. 

PIT. 
ACY. 

ACY. 
PIT. 
DUP. 
DUP. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  16B .--  Rubber-processing  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 — Continued 


Manufacturers '   identification  codes 
(according  to  list  in  table  22) 


RUBBER-PROCESSING  CHIMICAI^,    CYCLIC— Continued 

►Peptizers — Continued 

Pentachlorobenzenethiol,   zinc  salt 

Thiocresol 

Thiophenol   (Benzenethiol ) 

Xylene  thiol - 

Other  cyclic  rubber-processing  chemicals: 

p-tert-Amylphenol  sulfide   (tackifler) 

Dioresyl  disulfide - — — 

N,4-Dinltroso-N-methylanlline   (physical-property 
improver). 

Hindered  aromatic  polyamine 

»N-Nitrosodiphenylamine   (retarder) 

RUBBER-PROCESSING  CHIMICAI£,    ACYCLIC 

•Accelerators,   activators,   and  vulcanizing  agents: 
•Dithlocarbamic  acid  derivatives ; 

Dibutyldithiocarbamic  acid,   potassium  salt 

Dlbutyldithiocarbamic  acid,    sodium  salt 

»Dibutyldithlooarbamio  acid,    zinc   salt 

Dlethyldithiocarbamlc  acid,    selenium  salt 

Diethyldithiocarbamio  acid,   sodium  salt 

Dlethyldithiocarbamlc   acid,    tellurium  salt 

»Diethyldithlocarbamic  acid,    zinc   salt 

Dlmethyldlthlocarbaiaic  acid,   bismuth  salt 

Dimethyldlthiocarbamic   acid,   copper  salt 

Dimethyldithlocarbamlc  acid,    lead  salt 

Dimethyldlthiocarbamic  acid,   selenium  salt 

Dimethyldlthiocarbamic   acid,   sodium  salt  and  sodium 
polysulfide. 

•Dimethyldlthiocarbamic   acid,   zinc  salt 

All  other - 

»Thlurams : 

Bis(dibutylthiocarbamoyl)    sulfidei 

»Bis  (diethyl thiocarbamoyl)  disulfide 

•Bis (dimethyl thiocarbamoyl)  disulfide 

Bis (dimethyl thiocarbamoyl)  disulfide  and  2-mercapto- 
benzothiazole,   mixed. 

»Bis (dimethyl thiocarbamoyl)  sulfide 

Bis (ethylmethyl thiocarbamoyl)   sulfide 

Thiuram  blend 

Xanthates  and  sulfides : 

Dl-n-butylxantho  disulfide 

Dlisopropylxantho  disulfide 

Zinc  dlbutyl  xanthate 

Zinc  isopropyl  xanthate 

All  other  acyclic   accelerators,    activators,    and  vulcan- 
izing agents: 

n-Butyraldehyde-butylamlne  condensate 

Dl-n-butylammonlum  oleate 

3-Ethyl-l,l-dimethyl-2-thlourea 

Ethylenedlamlne  carbamate 

Polyoxyalkalenetetrasulfide 

l,l,3-Trlmethyl-2-thlourea 

Blowing  agents: 

Madlfied  urea 

Urea-bluret  mixture 

Conditioning  and  lubricating  agents: 

Methyl  stearyl- 10- sulfonic  acid,    sodium  salt 

Mono-   and  dlaliyl  acid  phosphates,  mixed 

Mono-   and  dlaliyl  phosphate  ammonium  salts,   mixed 


DUP. 
PIT. 
PIT. 
DUP. 

PAS. 
USR. 
CTA,   MON. 


VNC. 

DUP,    PAS,    USR,    VNC. 

ALC,    DUP,    PAS,    USR,    VNC. 

VNC. 

ALC,    PAS. 

VNC. 

ALC,    GYR,    PAS,    USR,    VNC. 

VNC. 

VKC. 

VNC. 

VNC. 

BFG,    GNT. 


USR. 

DUP,  GYR,    PAS. 

BPG,  DUP,    GNT,    GYR,    PAS,    USR,    VNC. 

DUP,  VNC. 

DUP,    GYR,    USR. 

VNC. 

DUP. 


ELASTOMERS  (SYNTHETIC  RUBBERS) 


143 


-Rubber-processing  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer ,  1966 — Continued 


Chemical 

Manufacturers'  Identification  codes 
(according  to  list  in  table  22) 

RUBBER- PROCESSING  CHEMICALS,  ACYCLIC-Continued 

Poljnnerlzatlon  regulators: 

Alkyl  meroaptans,  mixed - 

PAS,  PLC. 
HK,  PAS,  PLC. 

Shortstops: 

Dlmethyldithlooarbamlo  acid,  potassium  salt 

oDlmethyldlthlooarbamlo  acid,  sodium  salt 

Other  acyclic  rubber-processing  chemicals: 

Zinc  laurate  (activator,  physical-property  improver) 

GYR,  PAS,  USR. 

ALC,  BFG,  DUP,  GYR,  PAS,  USR. 

USR. 
USR 

Elastomers  (Synthetic  Rubbers) 


TABLE  ITB.— Elastomers  (synthetic  rubbers)  for  which  U.S.  production  or  , 

manufacturer,  2966 


were  reported,  identified  by 


[Elastomers   (synthetic  rubbers)    for  which  separate  statistics  are  given  in  table   17A  are  marked  below  with  an  as- 
terisk (»);   products  not  so  marked  do  not  appear  in  table   17A  because  the  reported  data  are  accepted  in  confidence 
and  may  not  be  published.  Manufacturers'   identification  codes  shown  below  are   taken  from  table  22.  An  x  signifies 
that  the  manufacturer  did  not  consent  to  his   identification  with  the  designated  product] 


Product 

Manufacturers'  identification  codes 
(according  to  list  in  table  22) 

ELASTC»ilERS,  CYCLIC 

ASY,  BFG,  CPY,  FIR,  FRS,  GGC,  GNT,  GYR,  ILC,  MCB, 

PLC,  RUB,  SHC,  TUS,  URC,  USR,  WIC. 
BFG,  FIR,  FRS,  G^JT,  GYR,  PLC,  USR. 
ACY,  DUP,  GNT,  MOB,  PRC,  RUB,  TKL,  USR. 

ACY,  BFG,  TKL. 

-D  1       +V,      +    ^         ^  py^^  ^"®   yp^ 

ELASTOMERS,  ACYCLIC 

BFG  FRS  GYR  TKL  TUS 

Polychloroprene  type  (Neoprene) 

•Polyisobutylene-isoprene  type  (Butyl) 

Reaction  products  of  natural  rubber 

DUP. 

CBN,  ENJ. 
GYR,  HPC. 
DCC,  SPD,  UCS. 

ASY,  BAR,  DUP,  ENJ,  FRS,  GGC,  GNT,  GYR,  PLC,  SHC,  TUS. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


Plasticizers 

TABLE  18B.  --Plasthizers  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 

[Plasticizers  for  which  separate  statistics  are  given  in  table  ISA  are  marked  below  with  an  asterisk  (»);  products 
not  so  marked  do  not  appear  in  table  ISA  because  the  reported  data  are  accepted  in  confidence  and  may  not  be 
published.  Manuf actiirers'  identification  codes  shown  below  are  taken  from  table  22] 


Manufacturers'  identification  code 
(according  to  list  in  table  22) 


PLASTICIZERS,  CYCLIC 

Coumarone-indene  plasticizer 

N-Cyclohexyl-p-toluenesulfonamide 

Dibenzyl  sebacate 

Diethylene  glycol  dibenzoate 

Di-tert-octyldiphenyl  oxide 

Dipropanediol  dibenzoate 

N-Ethyl-p-toluenesulfonamide 

Isopropylidenedlphenoxypropanol 

Naphthalene,  alkylated ■ 

Phosphoric  acid  esters; 

*Cresyl  diphenyl  phosphate 

Dibutyl  phenyl  phosphate 

Diphenyl  mono-o-xenyl  phosphate 

Diphenyl  oetyl  phosphate 

Methyl  diphenyl  phosphate 

»Tricresyl  phosphate 

»Triphenyl  phosphate 

All  other  phosphoric  acid  esters 

»Phthalic  anhydride  esters: 

Alkyl  benzyl  phthalates 

Bis('4-methyl-2-pentyl)  phthalate 

Butyl  benzyl  phthalate 

Butyl  cyclohexyl  phthalate 

n-Butyl  n-decyl  phthalate 

»Butyl  2-ethylhexyl  phthalate 

n-Butyl  isodecyl  phthalate 

»Butyl  octyl  phthalate 

Di ( 2-butoxyethyl)  Dhthaiate 

»Di butyl  phthalate 

»Dicyolohexyl  phthalate 

^Diethyl  phthalate 

*Dihexyl  phthalate 

»Diisodecyl  phthalate 

■»Di(2-methoxyethyl)  phthalate 

Dimethyl  isophthalate 

»Diniethyl  phthalate 

Dinonyl  phthalate 

»Dioctyl  phthalates: 

Dicapryl  phthalate 

Di( 2-ethylhexyl)  isophthalate 

*Di(  2-ethylhexyl)  phthalate 

«Dliso-octyl  phthalate 

Di-n-octyl  phthalate 

Mixed  dioctyl  phthalates 

Diphenyl  phthalate 

»Ditridecyl  phthalate 

2-Ethylhexyl  Isodecyl  phthalate 

*Glycolate  phthalate  esters: 

Butyl  phthalyl  butyl  glycolate 

Ethyl  (and  methyl)  phthalyl  ethyl  glycolate 

All  other  glycolate  phthalate  esters 

Hexyl  n-decyl  phthalate 

Hydrogenated  castor  oil  phthalate 

Isodecyl  tridecyl  phthalate 

Iso-octyl  isodecyl  phthalate 

»n-Octyl  n-decyl  phthalate 

All  other  phthallc  anhydride  esters 

Polyethylene  glycol  dibenzoate 


MON. 

WTH. 

VEL. 

DOW. 

VEL. 

ON. 

DOW. 

ACC. 

FMP, 

MON, 

MTR, 

SFA, 

X. 

WON. 

DOW. 

MON. 

™p. 

MON. 

FW, 

MON, 

MTR, 

SFA. 

EK, 

MON, 

SFA. 

SKA. 

X. 

GRH. 

GRH, 

MON. 

ACP. 

PCC. 

ACP, 

MON, 

UCC. 

GRH, 

UCC. 

GRH, 

PCC, 

RCI, 

RUB. 

FMP, 

WM. 

ACP, 

COM, 

DUP, 

EKT, 

GRH, 

MON, 

PCC, 

PFZ, 

RCI, 

RUB, 

SW, 

UCC,   WTH. 

ACP, 

DUP, 

FMP, 

MON, 

PFZ. 

Dtrp, 

EKT 

KF, 

WON, 

pn. 

ACP, 

GRH 

THC. 

ACP, 

BFG 

FVT, 

EN  J, 

GRH, 

MON, 

PCC, 

RCI, 

RUB, 

THC, 

UCC 

WTH. 

DUP, 

EKT, 

FMP, 

RCI, 

SFA. 

GRH,  WTH. 

UCC. 

ACP,  BFG,  EKT,  ENJ,  GRH,  MON,  PCC,  PFZ,  RCI,  RUB,  THC, 

UCC,  WTH. 
ACP,  AM,  BFG,  EKT,  ENJ,  GRH,  M3N,  PCC,  PFZ.  RCI,  RUB, 

THC,  UCC. 
ADM. 
ACP. 
MON. 


MON,  NOP. 

MON. 

ARG,  HPC. 

ACP,  UCC. 

DUP. 

THC. 

ACP,  GRH,  RUB. 

ACP,  ENJ,  GRH,  MSN,  PCC,  PFZ,  RCI,  RUB,  THC. 

FMP,  GRH,  kON,  THC,  UCC. 

VEL. 


TABLE  18B.  —Plasticizers  for  which  U.S.  production  or  sales  were  reported   identified  by 
manufacturer,  i566~Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


PLASnCIZERS,   CYCLIC--Continued 

Tetrahydrofurfuryl  oleate 

Toluenesulfonamide,   o-,   p-  mixtures 

Triethylene  glycol  dibenzoate 

»Trimellitio   acid  esters: 

n-Octyl  n-decyl  trimellltate 

Tri(2-ethylhexyl)triinellitate 

Triisodecyl  trimellltate 

Trilso-octyl  trimellltate — 

Trl-n-octyl  trimellltate- 

All  other  trimellitic  acid  esters 

All  other  cyclic  plasticizers 

PLASTICIZERS,   ACYCLIC 

»Adipio  acid  esters: 

*Di{2-(2-butoxyethoxy) ethyl)    adlpate 

•Di(2-ethylhexyl)    adlpate— 

Dlisobutyl  adlpate 

"Diisodecyl  adlpate 

Dilso-octyl  adlpate 

Diisopropyl  adlpate 

Dlnonyl  adlpate 

Di-n-octyl  adlpate 

n-Hexyl  n-decyl  adipate 

Iso-octyl  Isodecyl  adipate 

»n-Octyl  n-decyl  adlpate 

Polyethylene  glycol  adipate 

All  other  adlpic   acid  esters 

»Azelaic  acid  esters: 

Dlcyclohexyl  azelate 

Dl(2-ethylbutyl)    azelate— - - 

Di(2-ethylhexyl)    azelate 

Dlisobutyl  azelate 

Dilso-octyl  azelate 

Dl-n-octyl  azelate 

All  other  azelalc   acid   esters 

Ij-i-Butanediol  dicaprylate 

Butoxyethyl  pelargonate 

Citric  and  acetylcitrlc  acid  esters 

•Complex  linear  polyesters  and  polymeric  plasticizers 

Di(butoxyethoxy-ethoxy) methane 

Dl(2-(2-butoxyethoxy)ethyl)methane 

Dlbutyl  tartrate 

Diethylene  glycol  dlnonanoate 

Dilso-octyl  diglycolate 

»Epoxldlzed  esters: 

Butyl  epoxydioleate 

Butyl  epoxystearate 

Butyl  epoxytallate 

Epoxidized   linseed  oils 

»Epoxldlzed  soya  oils 

Epoxidized   tall  oils 

»2-Ethylhexyl  epoxytallates 

Octyl  epoxystearates 

•Octyl  epoxytallates 

All  other  epoxidized  esters 

Glycerol  pelargonate 

Glyceryl  tributyrate  and  tripropionate 

Glycol  pelargonate 

Isodecyl  nonanoate   (Isodecyl  pelargonate) 

Laurie  acid  esters 

Ityristic  acid  esters: 

Butyl  myrlstate 

»Isopropyl  myrlstate 

Other  myristlc  acid   esters 

»01eic  acid  esters: 

2-Butoxyethyl  oleate 

•Butyl  oleate 

•Glycerol  trioleate   (Triolein)— 

•Isopropyl  oleate 


CCW, 
ACY, 
VEL. 

EMR. 
MON. 

THC. 
PFZ. 
PFZ. 
PFZ, 

RUB. 

PFZ, 
CCW, 

RUB. 
EKT, 

MON, 

NEV 

FMP,  RCI 

TKL,  WTH 

EKT,  GRH, 

MON,  PCC 

RCI 

RH, 

THC 

UCC. 

FMP,  GRH, 

HAL. 

ACP,  EKT, 

GRH,  MON 

PCC 

PFZ 

,  RCI 

,  RH, 

RUB,  THC,  UCC 

PCC,  RCI, 

RH,  RUB, 

WTH. 

SBC,  VND 

THC. 

ACP. 

ACP,  PCC. 

GRH,  NOP, 

RCI. 

ACP,  GRH, 

MON,  PCC, 

ROT 

RH, 

THC, 

TKT, 

UCC. 

PFZ. 

GRH,  PFZ. 

PFZ. 

EMR. 

EKT,  EMR, 

PFZ,  RCI, 

RH, 

RUB, 

UCC. 

HAL. 

EMR. 

PFZ. 

ACP,  EMR. 

RUB. 

HAL. 

PFZ. 

ADM,  EKT, 

EMR,  GLY, 

HAL 

MON 

RH, 

RUB, 

THC,  WTH. 

TKL. 

GRD. 

ARC. 

EMR,  RUB. 

CCA,  FMP. 

AM. 

BAC. 

ADM,  THC. 

Pm,   SWT. 

ADM,  ARG, 

BAC,  RCI, 

RH, 

SWT, 

THC, 

ncc. 

RCI. 

ADM,  BAC, 

UCC. 

ARG. 

ARG,  RH, 

:hc,  UCC. 

EMR,  RH. 

EMR. 

EKT. 

EMR. 

EMR. 

HAL,  SBC. 

ARC. 

ARC,  DRW, 

ICI,  NOP. 

ICI. 

ARC. 

ARC,  CHL, 

HAL,  ICI, 

NOP. 

SWT, 

WM, 

WTH. 

DRW,  EMR, 

SWT,  WM. 

EMR,  ICI, 

WM. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Plasticizers  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  966— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


PLASTICIZERS,   ACYCLIC— Continued 

•Oleic  acid  esterB--Continued 

•Methyl  oleate 

•n-Propyl  oleate 

All  other  oleic  acid  esters 

Palmitic  acid  esters: 

Isobutyl  palmitate 

Iso-octyl  palmitate 

Isopropyl  palmitate 

2 -Methoxyethy 1  palmitate 

•Phosphoric  acid  esters: 

Tri(2-butoxyethyl)    phosphate 

Tri(2-chloroethyl)   phosphate 

Triethyl  phosphate 

Trioctyl  phosphate 

All  other  phosphoric  acid  esters 

Ricinolelc  and   acetylrlcinoleic  acid  esters: 

n-Butyl  acetylrioinoleate 

Butyl  riclnoleate 

•Glycerol  monoricinoleate 

Glyceryl  tri( acetylricinoleate) 

Methyl  riclnoleate 

All  other  ricinolelc   and  acetylrlcinoleic  acid  esters 
Sebaclc  acid  esters: 

•Dibutyl  sebaoate 

»Dl(2-ethylhexyl)   sebacate 

Dliso-octyl  sebecate 

Dimethyl  sebacate 

Dipentyl  sebacate 

All  other  sebacic  acid  esters 

•Stearic  acid  esters: 

Butoxyethyl  stearate 

»n-Butyl  stearate 

Dlmethylajnmonium  stearate 

2-Ethylhexyl  stearate 

Glycerol  triacetyl  stearate 

Isopropyl  stearate 

Methoxyethyl  stearate 

Methyl  dichlorostearate 

Methyl  pentaohlorostearate 

Methyl  stearate 

All  other  stearic  acid  esters 

Sucrose  acetate  isobutyrate 

Tetraethylene  glycol  di(2-ethylhexanoate) 

Triethylene  glycol  dlcaprylate 

•Triethylene  glycol  dl(caprylate-caprate) 

Triethylene  glycol  dl-2-ethylbutyrate 

Triethylene  glycol  di(2-ethylhexanoate) 

Triethylene  glycol  dlpelargonate 

2,2,'i-Triiiiethyl-l,3-pentanediol  diisobutyrate 

All  other  acyclic  plasticizers 


CHL,  EMR,  ICI,  NOP,  SWT. 
CHL,  EMR,  WM. 
HAL,  RH,  VND. 


FMP,  WES. 
UCC. 
EKT. 
FMP,   UCC. 


SF, 


ARC,  BAC,  PFZ,  RH. 

EKT,  GRH,  HAL,  PFZ,  RCI,  RH,  WTH. 

QRD,  GRH,  HAL,  PCC,  RH,  RUB,  WTH. 

NOP. 

GRH. 

RCI. 

NOP. 


CHL,  EMR,  HAL,  ICI,  RUB,  SCP,  SWT,  WTH. 


ARC, 
ARC, 
RH. 
FMP. 
BAC. 
ARC, 


CHL. 
HPC, 
EKT. 
UCC. 


DRW,  FOR,  HAL,  RUB. 

UCC. 

EKT,  NOP,  UCC. 

RUB. 

EKX. 

EMR,  HAL,  HPC,  PFZ,  TKL,  UCC, 


SURFACE-ACTIVE  AGENTS 


147 


Surface -Active  Agents 


-Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 


[Surface-active  agents  for  which  separate  statistics  are  given  in  table  19A  are  marked  below  with  an  asterisk  (»); 
products  not  so  marked  do  not  appear  in  table  19A  because  the  reported  data  are  accepted  in  confidence  and  may  not 
be  published.   Manufacturers'    identification  codes  sho?m  below  are  taken  from  table  22.   An  x  signifies  that  the 
manufacturer  did  not  consent  to  his  identification  with  the  designated  product] 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


Amphoteric  Surface-Active   Agents 

Acyclic : 

(l-Carboxyheptadecyl)trimethylammonium  hydroxide,   inner 

salt   (C-Hexadecylbetaine). 
( Carboxymethyl )( coconut  oil  alkyl )dimethylammonium 

hydroxide,    inner  salt  [N-(Coconut  oil  alkyl )betaine  ]. 
(Carboxymethyl) [3-(ooconut  oil  amldo )propyl] -dimethyl- 
ammonium  chloride,    sodium  salt. 
( Carboxymethyl )dimethyl(9-ootadeoenyl)aramonium  hydroxide 

inner  salt    [N-(9-0ctadecenyl)-betalne] . 
(l-Carboxyundecyl)trimethylammonium  hydroxide,    inner 

salt   (C-Decylbetaine). 

N-( Coconut  oil  alkyl )-p-alanine,  sodium  salt 

N-(2-Coconut  oil  amidoethyl)-N-(2-hydroxyethyl) -glycine, 

sodium  salt. 

N-Dodecyl-3-iminodipropionio  acid,   disodium  salt 

N- ( 2-ftydroxyethyl ) -N- ( 2-lauramidoethyl ) -p -alanine, 

sodium  salt. 
N- ( 2-Hydroxyethyl ) -N- ( 2-stearamidoethyl  )glycine,   sodium 

salt. 
Mixed  acyclic  primary  amines,    ethoxylated  and  sulfated, 

sodium  salt. 

(Mixed  alkyl )sulf obetaine 

Mixed  fatty  betaines 

Oleic  acid   -  ethylenediamlne  condensate,   propoxylated 

and  sulfated,    sodium  salt. 

Polypeptide,    ammonium  salt 

Polypeptide,    sodium  salt 

N-(Tallow  alkyl  )-3-lminodlproplonic  acid,   disodium  salt- 
Gyclic: 

1, 1-Bis ( carboxymethyl ) -2-undeoyl-2-imidazollnium 

hydroxide,   disodium  salt. 
l-Carboxymethyl-2-heptadeoyl-l-(2-hydroxyethyl)- 

Z-imidazolinlum  hydroxide,   sodium  derivative,    sodium 

salt. 
l-Carboxymethyl-l-(2-hydroxyethyl)-2-nonyl-2- 

Imldazolinium  chloride,  sodium  salt. 
l-Carboxymethyl-l-(2-hydroxyethyl)-2-nonyl-2- 

Imidazolinlum  hydroxide,  sodium  derivative,  sodium 

salt. 
l-Carboxymethyl-l-(2-hydroxyethyl)-2-undeoyl-2- 

imldazolinium  chloride. 
1- Carboxymethyl- 1- ( 2-hydroxyethyl ) -2-vmdecyl-2- 

imidazolinium  hydroxide,  sodium  derivative,  sodium 

salt. 
Heptadecylmethylbenzimldazolinesulfonic  acid,  sodium 

salt. 
3-[ 2-(2-Undecyl-2-iinidazolin-l-yl)ethoxy]propionio  acid, 

sodium  salt. 

Anionic  Surface-Active  Agents 

MCarboxylio  acids  (and  salts  thereof): 

»Amine  salts  of  fatty,  rosin,  and  tall  oil  acids: 

Coconut  oil  acids,  trlethanolamine  salt 

Oleic  acid,  butylamine  salt 

Oleic  acid,  diethylamlne  salt 

Oleic  acid,  trlethanolamine  salt 

Saturated  Cia'Cig  acids,  ethanolamine  salt 

Stearic  acid,  morpholine  salt 

Stearic  acid,  N,N,N',N'-tetrakis(2-hydroxyethyl)- 
ethylenediamine  salt. 


DUP. 
CUL. 
JRG. 
DUP. 
DUP. 


DUP,  TXT. 

TXT. 

S. 

MYW. 
MtW. 
GNM. 

MIR. 

MIR. 


PCS,  UVC. 
MIR. 


DYS. 
WTC. 
DCM,  HAL,  TCC. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  966— Continued 


Manufacturers'   identification  cedes 
(according  to  list  in  table  22) 


Sur/a 


Agen 


-Continued 


»Carboxylic   acids   (and  salts  thereof )--Contlnued 
♦Amine  salts  of  fatty,   rosin,    and  tall  oil 
acids — Continued 

Stearic  acid,    triethanolamlne  salt 

Tallow  acids,    triethanolamlne  salt 

«Carboxylic  acids  having  amide  or  ester  linlcages : 

N-(Cooonut  oil  acyl  )polypeptide,    ammonium  salt 

N-(Coconut  oil  acyl ipolypeptide,   potassium  salt 

N-( Coconut  oil  acyl )polypeptide,    sodium  salt 

N-( Coconut  oil  acyl )sarcosine 

N-(Cooonut  oil  acyl)aarcosine,   sodium  salt 

»N-Lauroylsaroosine,   sodium  salt 

N- (Mixed  alkylsulf onyl )glyoine,   sodium  salt 

N-Oleoylpolypeptide,   sodium  salt 

N-Oleoylsarcoelne,   sodium  salt 

Phthalic  acid,   octadeoyl  ester,   potassium  salt 

Stearolactolactic   acid 

Stearolactolaotic  acid,   calcium  salt 

Stearolactolactic  acid,   sodium  salt 

N-Stearoylsaroosine,    sodium  salt 

N-Undecenoylpolypeptide,   potassium  salt 

All  other 

"Potassium  and  sodium  salts  of  fatty,  rosin,  and  tall 
oil  acids: 

Castor  oil  acids,  potassium  salt 

Castor  oil  acids,  sodium  salt 

•Coconut  oil  acids,  potassium  and  sodium  salts: 
•Potassium  salt 


•Sodium  salt 

Coconut  oil  and  tallow  acids,  sodium  salt 

•Com  oil  acids,  potassium  and  sodium  salts: 

Potassium  salt 

Sodium  salt 

Cottonseed  oil  acids,  sodium  salt 

Laurie  acid,  potassium  salt 

Mixed  vegetable  fatty  acids,  potassium  salt- 
•Oleic  acid,  potassium  salt 


•Oleic  acid,  sodium  salt- 


Olive  oil  acids,  sodium  salt 

Palm  oil  acids,  sodium  salt 

Peanut  oil  acids,  potassium  salt 

Hosin  acids,  potassium  salt 

Bosin  acids,  sodium  salt 

Soybean  oil  acids,  potassium  salt 

•Stearic  acid,  potassium  and  sodium  salts: 

Patassium  salt 

Sodium  salt 

•Tall  oil  acids,  potassium  and  sodium  salts: 
•Potassium  salt 


•Sodium  salt 

Tallow  acids,  potassium  salt- 
•Tallow  acids,  sodium  salt 


All  other 

•Ftiosphoric  and  polyphosphoric  acid  esters  (and 
salts  thereof): 
•Alcohols  and  phenols,  ethoxylated  and  phosphated: 

Dlnonylphenol,  ethoxylated  and  phosphated 

Dodecyl  alcohol,  ethoxylated  and  phosphated 

Dodeoyl  alcohol,  ethoxylated  and  phosphated,  barium 
salt. 

Dodecylphenol,  ethoxylated  and  phosphated 

2-Ethylhexanol,  ethoxylated  and  phosphated -- 

Iso-octyl  alcohol,  ethoxylated  and  phosphated 

44CLxed  linear  alcohols,  ethoxylated  and  phosphated 

•Nonylphenol,  ethoxylated  and  phosphated 


AML, 

GLY, 

TCC. 

SBP. 

MfW. 

MYW. 

MYW. 

GGY. 

HMP. 

CP, 

GGY. 

HMP,    ONX. 

GAF. 

TMT. 

MYW. 

GAF, 

GGY. 

CIB. 

GLY. 

GLY. 

GLY. 

GGY. 

MYW. 

HMP. 

ARL. 

BAG, 

SEA. 

HAL, 

MRV, 

WHI. 

ACE,  BSC,  CSB,  DSO,  DYS,  GRL,  HOT,  JHG,  LUR,  mC,  PCH, 

PG,  SWT. 
CON,  CP,  JRG,  LEV,  NPR,  PG,  PRX. 
GRC. 

HOT,  PCH. 

LUR,  NMC. 

WHI. 

DRW,  NOP,  VAL. 

AML,  ARL,  DYS,  GRC,  GRL,  PCH,  SWT. 

AML,  BSC,  BSW,  CCL,  CIB,  CPY,  DAN,  FRS,  GYR,  HOT,  NMC, 

NOP,  QCP,  S,  SHP,  USR,  WBG,  WIC. 

BSW,  FRS,  LEV,  LUR,  MRV,  NOP,  SEA,  SNW,  SWT,  USR,  WBG, 

WTC. 

HOT,  LUR. 
LUR. 

KAL,  SLC. 

ASY,  FRS,  GRC,  X. 

ASY,  CRT,  MRA,  PLC,  PRX,  QCP,  X. 

CON,  DRW,  DYS. 

GYR,  VAL,  WTC. 

OYR,  LEV,  MAL,  NOP,  WTC. 

ACE,  ASY,  BSC,  CON,  CSB,  DRW,  DYS,  EFH,  FRS,  GAF,  GYR, 
HOT,  LUR,  mC,    PNX,  QCP,  USR,  VAL,  WHI,  x. 

CPY,  GYR,  MRV,  PCS,  PRX,  QCP,  TXT,  UNP,  X. 

ASY,  CPY,  NMC,  PG,  SWT. 

ASY,  CON,  CP,  DYS,  FRS,  GYR,  JRG,  LEV,  LUR,  I«C,  NOP, 
NPR,  PG,  PLC,  PRX,  QCP,  SWT. 

NMC. 


TCI. 

TCI,  WAY. 

GAF. 

CRT,  CST,  GAF,  SEY. 

GAF,  NLC,  RTF,  SEY,  TCC,  TXT,  VAC,  WAY,  WSN. 


SURFACE-ACTIVE  AGENTS 


149 


TABLE  19B.  —Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i966— Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


4nionic  Surface-Active  4gen(s - -Continued 

•phosphoric  and  polyphosphorio  acid  esters   (and  salts 
thereof ) — Continued 
•Alcohols  and  phenols,    ethoxylated  and  phosphated— 
Continued 
Nonylphenol,   ethoxylated  and  phosphated,  barium 
salt. 

9-Ootadeoenyl  alcohol,    ethoxylated  and  phosphated 

Octylphenol,    ethoxylated  and  phosphated 

Octylphenol,    ethoxylated  and  phosphated,   magnesium 
salt. 

Phenol,   ethoxylated  and  phosphated 

Trideoyl  alcohol,    ethoxylated  and  phosphated 

All  other 

•Alcohols,  phosphated  or  polyphosphated : 

Deoyl,  dodeoyl,  and  octyl  phosphate,  morpholine  ealt- 

Deoyl  polyphosphate,  triethanolamlne  salt 

2-Ethylhexyl  phosphate 

»2-Ethylhexyl  phosphate,  sodium  salt 

2-Ethylhexyl  polyphosphate 

Hexyl  polyphosphate,  potassium  salt 

Mixed  alkyl  phosphate 

Mixed  alliyl  phosphate,  diethanolamine  salt 

Octadecyl  phosphate,  triethanolamlne  salt 

9-Ootadeoenyl  phosphate 

Octyl  phosphate 

Octyl  phosphate,  alkylamine  salt 

Octyl  phosphate,  potassium  salt 

Octyl  polyphosphate 

Octyl  polyphosphate,  alkylamine  salt 

Octyl  polyphosphate,  potassium  salt 

Octyl  polyphosphate,  sodium  salt 

•Sulfonic  acids  (and  salts  thereof): 
•Alkylbenzenesulf onates : 
•Dodecylbenzenesulf onates : 

•Dodecylbenzenesulfonic  acid 

Dodecylbenzenesulf onic  acid,  ammonium  salt 

Dodecylbenzenesulfonic  acid,  butylamlne  salt 

•Dodecylbenzenesulfonic  acid,  calcium  salt 

Dodecylbenzenesulfonic  acid,  diethanolamine  salt— 

Dodecylbenzenesulfonic  acid,  ethylenediamine  salt — 

•Dodecylbenzenesulfonic  acid,  isopropanolamine  salt- 

•Dodecylbenzenesulfonic  acid,  isopropylamine  salt — 

Dodecylbenzenesulfonic  acid,  (mixed  alkyl ) -amine 
salt. 

Dodecylbenzenesulfonic  acid,  potassium  salt 

Dodecylbenzenesulfonic  acid,  propoxylated 
ethylenediamine  salt. 

•Dodecylbenzenesulfonic  acid,  sodium  salt 

Dodecylbenzenesulfonic  acid,  strontium  salt 

•Dodecylbenzenesulfonic  acid,  triethanolamlne  salt — 

•Other  alky IbenzenesxUf onates : 

DecylbenzenesuJfonic  acid,  sodixim  salt 

Didodecylbenzenesulfonic  acid 

Didodecylbenzenesulfonic  acid,  sodium  salt 

Pentadecylbenzenesulfonio  acid,  potassium  salt 

Pentylbenzenesulfonio  acid,  sodium  salt 

•Tridecylbenzenesulfonic  acid 

•Tridecylbenzenesulfonic  acid,  sodium  salt 

Undecylbenzenesulfonio  acid 

Undecylbenzenesulfonic  acid,  sodium  salt 

•Benzene-,  cumene-,  toluene-,  and  xylenesulf onates : 

Benzenesulfonlc  acid,  sodium  salt 

Cumenesulfonio  acid,  ammonium  salt 

2,4-Dinitrobenezenesulfonic  acid,  sodium  salt 

Toluenesulfonlo  acid 

Toluenesulfonlc  acid,  potassium  salt 


GAF. 

GAF, 

LUR, 

NLC,   WAT. 

NLC. 

DUP. 

MOA. 

RCD. 

WAY. 

SEf, 

UCC, 

UVC. 

live. 

CST. 

DEX. 

BON, 

CST. 

DUP. 

DW. 

RCD. 

DUP. 

DUP. 

SFA- 

DUP. 

DUP. 

DEX. 

TXT. 

TXT. 

ARD,  CO,  CRT,  CTL,  aiK,  HLI,  LEV,  MON,  NAC,  PIL,  RCD, 

RTF,  STP,  TCI,  TDC,  TOI,  TXT,  WTC. 

ARL,  CTL. 
WTC. 

APD,  NLC,  RCD,  RH,  RTF,  STP,  WTC,  X. 
VAL. 

APD,  RTF. 

CTL,  RCD,  X. 

APD,  ARD,  CTL,  RCD  RTF,  SNW,  STP. 

PCS,  STP,  VAL,  WTC. 


AAC,  APX,  ARD,  ARL,  ATR,  BLA,  CO,  CP,  CRT,  CTL,  DEP, 
DSO,  DYS,  EFH,  HLI,  HRT,  LEV,  MON,  NAC,  NOP,  PHC,  PO, 
PIL,  PRX,  RCD,  STP,  SWT,  TO),  UNP,  WIC,  WTC. 

RTF. 

AAC,  AML,  ARD,  ARL,  ATR,  CRT,  CTL,  DSO,  DYS,  HLI,  NAC, 
PCS,  PIL,  RCD,  RTF,  SOS,  STP,  SWT,  TXT,  VAC. 

AEU,  MON. 

CO. 

CO. 

STP. 

MON. 

KON,  NPR,  TXT. 

BLA,  CP,  NPR,  ROD,  WTC. 

TXT. 

TXT. 

NE5. 

STP. 

NE5. 

NES,  RCD. 

NES,  RCD,  STP,  TXN. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


.  —Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 — Continued 


Ghenlcal 

Manufacturers 

identification  codes 

(according  to  list  in  table  22) 

Anionic  Surface-Active  /Igenls- -Continued 

^Sulfonic  acids   (and  salts  thereof )— Continued 

»Benzene-,    oumene-,    toluene-,    and  xylenesulfonates— 

Continued 

CO, 

NES, 

PIL,    RCD, 

STP, 

WTC. 

STP,   TXN,   WTC. 

loluenesuilonic  aclu,   soaluin  salt------------ — ----- 

»Xylenesulfonie  acid,    ammonium  salt 

ATR, 

CO, 

HLI,    NES, 

RCD, 

NES, 

STP. 

^lenesuiionic  aciu,   poxassium  saix-- —.—-.- 

ATR, 

CO, 

HLI,    JRG, 

NES, 

PIL,    RCD,    STP,    TXN,   WTC. 

»Ugninsulfonates: 

Ligninsulfonic  acid,    aluminum  salt 

MAR. 

CRZ. 
CRZ, 
MAR. 

gninsu               ^^J'j'    smmon  um  s 

CWP, 

GLY,    LKY, 

LPC 

MAR,    PSP. 

*Ligninsulionlc  acid,   calcium  salt----— — —-"——--- 
Ligninsulfonic  acid,   chromium  salt 

Ligninsulfonic  acid     iron  salt---— --—-—-- — — — 

CRZ. 
LPC, 
PSP. 
CRZ, 

MAR. 

Ligninsulfonic  acid,   magnesium  salt — --— - 

Ligninsulfonic  acid,   mixed  salts-- -- --- -— 

»Ligninsulfonic  acid,    sodium  salt 

CWP, 

MAR,    WVA 

»Naphthalenesulf onates : 

BenzyLnaphthalenesulXonio  acid 

OAF. 

Butylnaphthalenesulfonic  acid 

SCP. 

*Butylnaphthalenesulfonic  acid     sodium  salt— --------- 

CLD, 
GAF, 
PFZ. 

CMS, 
MRA, 

GGY,    PFZ 
S. 

Dibutylnaphthalenesulf onic  acid - - - --- ---- 

Didodecylnaphthalenesulfonic  acid,    sodium  salt 

Diisopropylnaphthalenesulfonic  acid 

DUP, 

GAF, 

GRD,    NAC 

Diisopropylnaphthalenesulfonio  acid,    sodium  salt 

GAF, 

PFZ. 

Dipentylnaphthalenesulfonlc  acid,    ammonium  salt 

NLC. 

Dipentylnaphthalenesulfonio  acid,    (mixed  aliyl)amine 

salt. 
Dipentylnaphthalenesulfonlc   acid,   sodium  salt 

NLC. 

GGY. 

Isopropylnaphthalenesulfonic  acid 

DUP, 

NOP, 

ONX. 

Methylenebis(2-naphthalenesulfonic  acid)— 

DUP. 

6,6'-Methylenebis(2-naphthalenesuironic  acid),    calcium 

DUP. 

salt. 

Methylnaph'thalenesuLfonic  acid     scxiium  salt----------- 

UDI. 

Methylnonylnaphthalenesulf onic' acid,   sodium  salt 

UDI. 

Tetrahydronaphthalenesulfonic  acid 

DUP. 

»Other  sulfonic  acids: 

»N-Methyl-N-oleoyltaurine,    sodium  salt 

CRC, 

CRT, 

DEP,    OAF, 

HRT 

MRA,    NOP. 

»Sulfosucoinamic  acid  derivatives: 

N- ( 1, 2-Dicarboxyethyl  )-N-octadecylsulf osucclnamic 

ACY. 

acid,    tetrasodium  salt. 

N- ( 2-ltrdroxyethyl ) -N- ( tallow  aliyl  )sulf osucoinamlo 

SCP. 

acid,   dlsodium  salt. 

N-OctadeoylsuLfosucclnamic  acid,  disodium  salt 

ACT. 

N-(01eoyloxyisopropyl)Eulfosucoinamic  acid,   disodium 

OTC. 

salt. 

»Sulfosuccinio  acid  esters: 

Sulfosuccinic  acid,  bis(2,6-dimethyl-4-heptyl)  ester. 

GAF. 

sodium  s6LLt. 

♦Sulfosuccinic  acid,  bls(2-ethylhexyl)  ester,   sodium 

ACT, 

CRC, 

CRT,    CST, 

DAN 

EFH,    EMK,   GQY,    HRT,    ICI, 

MOA, 

salt. 

PC 

,    SBC 

,   TCI. 

Sulfosuccinic  acid,  bis(talloii  monoglyoeride )  ester. 

ACT. 

sodium  salt. 

Sulfosuccinic  acid,  dihexyl  ester,   sodium  salt 

ACT, 

MQA, 

SNW. 

Sulfosuccinic  acid,   dioctyl  ester,   sodium  salt 

RH. 

Sulfosuccinic  acid,   dipentyl  ester,    sodium  salt 

ACT. 

Sulfosuccinic  acid,  ditrideoyl  ester,   sodium  salt — 

ACT, 

MQA. 

•All  other  sulfonic  acids: 

Rn+-wThvd-pr»wl-iHTih*anvT  milf^r^Tiln     Of^-IH                 ....    —    - 

RBC. 

ouLyuiyuroxyDipiienyisuiionic   acia-- ——————-- 

Butylhydroxybiphenylsulfonic  acid,   sodium  salt 

ICO. 

Coconut  oil  acids,    2-sulfoethyl  ester,   sodium  salt 

GAF, 

LEV. 

(Coconut  oil  isethlonate,   sodium  salt). 

Dodeoyldiphenyloxidedisulfonic  acid,  disodium  salt— 

DOW. 

Dodeoyl  sulfoacetate 

MAC. 

(Byoerol  monostearate  sulfoacetate,   sodium  salt 

WTC. 

Laurie  acid,   2-sulfoacetaiiildoethyl  ester,  potassium 

salt. 
2-LauToyloxy-l-propanesulfonic  acid 

WTC. 

SDH. 

\IA-Vf>t\    n1  VBnAQiilf rinln     n/ilrt     .--......    _..„.-..—_...    - 

RET, 
DUP, 

TXT. 
RET, 

nu-xc^u   H  [  KHneaujLL  onic   ucia------- ---— — — — — 

Mixed  alkanesulfonio  acid,   sodium  salt 

VPC. 

SURFACE-ACTIVE  AGENTS 


TABLE  19B.— Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  7966— Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


Anionic   Surfacf-Ac<ivt   /(genf  s  - -Continued 

*Sulfonio   acids   (and  salts  thereof )~ Continued 
"Other  sulfonic   acids — Continued 

»A11  other  sulfonic   acids — Continued 

Octylphenol,    ethoxylated  and  sulfonated,    sodium  salt' 
Petroleumsulf onic   acid,   water  soluble   (acid  layer), 

sodium  salt. 
Taurine  derivatives: 

N-( Coconut  oil  acyl)-N-methyltaurine,    sodium  salt- 

N-Cyclohexyl-N-palmitoyltaurine,    sodium  salt 

N-Methyl-N-palmitoyltaurine,    sodium  salt 

N-Methyl-N-(tall  oil  acyDtaurlne,   sodium  salt 

N-Methyl-N-(tallow  acyl)taurine,    sodium  salt 

All  other 

Sulfuric  acid  esters  (and  salts  thereof): 
»Acids,  amides,  and  esters,  sulfated: 

»Coconut  oil  acids  -  ethanolamine  condensate,  sulfated, 

potassium  salt. 
»Esters  of  sulfated  oleic  acid: 

2-Butaxyethyl  oleate,  sulfated,  sodium  salt 

»Butyl  oleate,  sulfated,  sodium  salt 

Ethyl  oleate,  sulfated,  sodium  salt 

Glycerol  trioleate,  sulfated,  sodium  salt 

»Isopropyl  oleate,  sulfated,  sodium  salt 

Methyl  oleate,  sulfated,  sodium  salt 

»Propyl  oleate,  sulfated,  sodium  salt 

»01eic  acid,  sulfated,  disodium  salt 

»Tall  oil,  sulfated,  sodium  salt 

»Other  acids,  amides,  and  esters,  sulfated: 

Bu-tyl  riclnoleate,  sulfated,  disodium  salt 

Coconut  oil  acids  -  isopropanolamine  condensate, 

sulfated,  sodium  salt. 
Glycerol  monoester  of  coconut  oil  acids,  sulfated, 

ammonium  salt. 
Glycerol  monoester  of  coconut  oil  acids,  sulfated, 
sodium  salt. 

9-Octadecenyl  acetate,  sulfated,  sodium  salt 

Oleic  acid  -  ethanolamine  condensate,  sulfated, 
sodium  salt. 

Oleostearin,  sulfated,  sodium  salt 

Ricinoleic  acid,  sulfated,  disodium  salt 

All  other 

•Alcohols   and  phenols,    sulfated: 
»Dodeoyl  sulfate  salts: 

2-Amlno-2-me-thylpropanol  salt 

Ammonium  salt 

Diethanolamine  salt 

N, N-Dlethylcyclohexylamlne  salt 

Isopropanolamine  salt 

"Magnesium  salt 

Potassium  salt 

"Sodium  salt 

"Triethanolamlne  salt 

*2-Ethylhexyl  sulfate,    sodium  salt 

•Octadeoyl  sulfate,    sodium  salt 

"Ootyl  sulfate,    sodium  salt 

"Other  alcohols  and  phenols,    sulfated: 
Linear  alcohols,    sulfated: 

Coconut  oil  allcyl  sulfate,    triethanolamine  salt 

Coconut  and  sperm  oil  aliyl  sulfate,    sodium  salt— 

Decyl  sulfate,    sodium  salt 

Decyl  sulfate,    triethanolamine  salt 

Hexadeoyl  and  9-ootadecenyl  sulfate,    sodium  salt — 

Hexadeoyl  sulfate,    sodium  salt 

Hexyl  sulfate,   potassium  salt 

Mixed  linear  alcohols,    sulfated,    ammonium  salt 

Mixed  linear  alcohols,    sulfated,   polyamine  salt 

Mixed  linear  alcohols,    sulfated,    sodium  salt 


CRT, 

RH. 

SIN, 

SON 

OAF, 

TNI. 

OAF. 

GAF. 

GAF, 

TXT 

GAF. 

STC. 

DEX,    IMK,    HRT,    ONX. 


I  CI,    NOP,    ONX,    PC. 

GAF,    KAL. 

MRV,    SCP. 

BHY,    CRT,    DEX,    HRT, 

ICI, 

LEA, 

LUR. 

ICI,    NOP. 

ACY,    BSC,    EFH,   MRV. 

ACT,    ACY,    CRT,    DRW, 

am. 

GAF, 

LEA, 

TEN,    WHI,    WHW. 

ACY,    APX,    ICI,    HRV, 

NOP, 

SEA, 

WHI. 

NOP. 

APX. 

DUP. 

SCP. 

SEA. 

NOP. 

EMR, 

SEY. 

DUP. 

AAC, 

CTL, 

DUP, 

ONX, 

STP. 

AAC, 

CTL, 

CUL, 

DUP, 

HLI, 

JEG, 

ONX, 

STP 

DUP. 

JBG. 

AAC, 

CTL, 

HLI, 

STP. 

CTL, 

HLI, 

PG. 

AAC, 

CTL, 

CUL, 

DUP, 

HLI, 

JHG, 

ONX, 

PCI, 

RET. 

AAC, 

CTL, 

CUL, 

DUP, 

HLI, 

ONX, 

PCS, 

PG. 

TXT. 

AAC, 

UCC, 

WTC. 

DUP, 

BflC, 

ONX, 

PG. 

AAC, 

DUP, 

PCS, 

SEY. 

PCS. 

DUP. 

CTL, 

DUP, 

ONX, 

PCS. 

DUP. 

PCS. 

AAC, 

DUP. 

PCS. 

TXT. 

NLC. 

LAK, 

PCS, 

TXT. 

PCS,    PG,    RCD, 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Surface-active  agents  for  which  U.S.  production  or  sales  were 
manufacturer,  1966 — Continued 


iported,  identified  by 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


Ag,n 


-Continued 


Sulfuric  acid  esters  (and  salts  thereof )— Continued 
»Aloohols  and  phenols,  sulfated — Continued 

«Other  alcohols  and  phenols,  sulfated — Continued 
Linear  alcohols,  sulfated — Continued 

Nonyl  sulfate,  sodium  salt 

Octadeoyl  sulfate,  triethanolamlne  salt 

Tetradecyl  sulfate,  sodium  salt 

All  other 

Phenols  and  nonlinear  alcohols,    sulfated: 

Branched  hexadecyl  sulfate,    sodium  salt 

3,9-Diethyl-6-tridecyl  sulfate,    sodium  salt 

7-Ethyl-2-methyl-4-undecyl  sulfate,   sodium  salt 

Trichlorophenol  sulfate,    ethanolamlne  salt 

Tridecyl  sulfate,    sodium  salt 

»Ethers,   sulfated: 

»Aliylphenols,  ethoxylated  and  sulfated: 

Dodecylphenol,  ethoxylated  and  sulfated,  anmonium 

salt. 
(Mixed  aliyl )phenol,  ethoxylated  and  sulfated, 

sodium  salt. 
Nonylphenol,  ethoxylated  and  sulfated,  ammonium 

salt. 
Nonylphenol,  ethoxylated  and  sulfateu,  ethanolamlne 

salt. 
Nonylphenol,  ethoxylated  and  sulfated,  sodium  salt— 
Nonylphenol,  ethoxylated  and  sulfated,  triethanol- 
amlne salt. 
Ootylphenol,  ethoxylated  and  sulfated,  sodium  salt— 
»Dodecyl  alcohol,  ethoxylated  and  sulfated,  ammonium 

salt. 
*Dodeoyl  alcohol,  ethoxylated  and  sulfated,  sodium  salt- 
<«ittxed  linear  alcohols,  ethoxylated  and  sulfated, 

sodium  salt. 
»Other  sulfated  ethers: 

Dodecyl  and  tetradecyl  alcohols,  ethoxylatsd  and 

sulfated,  ammonium  salt. 
Dodecyl  and  tetradecyl  alcohols,  ethoxylated  and 
sulfated,  potassium  salt. 

Hexyloxypropyl  sulfate,  sodium  salt 

Mixed  linear  alcohols,  ethoxylated  and  sulfated, 

ammonium  salt. 
Mixed  linear  alcohols,  ethoxylated  and  sulfated, 

potassium  salt. 
Sperm  oil  alcohol,  ethoxylated  and  sulfated,  sodium 

salt. 
Tridecyl  alcohol,  ethoxylated  and  sulfated,  ammonium 

salt. 
Tridecyl  alcohol,  ethoxylated  and  sulfated,  sodium 
salt. 

All  other 

^Natural  fats  and  oils,  sulfated: 

»Castor  oil,  sulfated,  sodium  salt 

*Cooonut  oil,  sulfated,  sodium  salt 

»Cod  oil,  sulfated,  sodium  salt 

Cottonseed  oil,  sulfated,  sodium  salt 

Grease,  other  than  wool,  sulfated,  sodium  salt 

Herring  oil,  sulfated,  sodium  salt 

Lard,  sulfated,  sodium  salt 

Mixed  fish  oils,  sulfated,  sodium  salt 

Mixed  vegetable  oils,  sulfated,  sodium  salt 

Mustard  seed  oil,  sulfated,  sodium  salt 

»Neat's-foot  oil,  sulfated,  sodium  salt 

•Peanut  oil,  siilfated,  sodium  salt 

Redfish  oil,  sulfated,  sodium  salt 

»Ricebran  oil,  sulfated,  sodium  salt 

•Soybean  oil,  sulfated,  sodium  salt 

oil,  sulfated,  sodium  salt 


TIN. 
DUP. 
ONX. 
PCS. 

APX. 
PCS, 
UCC. 
GAF. 
AAC. 

UCC. 

GAF. 

GAF. 

CIB, 

CTL, 

GAF, 

STP, 

TXT 

GAF. 

CRT, 
ARL. 

CTL, 

GAF. 

RH. 
AAC, 

CTL, 

ONX, 

PG. 

STP. 

S. 

CO,  LAK,  NLC,  PIL,  RCD,  SCP, 

CO,  GAF,  RCD,  SHC,  TXT. 

DUP. 

PCS,  RCD. 


SHC,  STP,  TXT,  UCC. 


AAC,  ARL,  RCD. 


APX,  PCS, 


3,  SEY. 


AAE,  ACT,  ACY,  AML,  APX,  BBJ,  bSC,  BSW,  CRT,  DEX,  DRW, 
DUP,  GAF,  HRT,  I  CI,  KAL,  KNG,  LEA,  LUR,  MRA,  MRD, 
MRV,  NOP,  ONX,  PC,  S,  SCO,  SCP,  SEA,  SLC,  WHI,  WHW. 

ACY,  MRD,  NOP,  RTC,  SEA,  WHW. 

ACT,  CRT,  DRW,  MRD,  NOP,  S,  SEA,  WAW,  WHI,  WHW. 

NOP,  RTC. 

NOP,  SEA,  WHI,  WHW. 

WHI. 

AML,  SCO,  WHI. 
PCI. 

LUR,  NOP. 

ACT,  CRT,  KAL,  LOR,  MRD,  NOP,  PC,  SEA,  WHW. 

ACY,  I  CI,  LUR,  NOP,  SCP,  SLC. 
WHI. 

EFH,  KNG,  LUR,  NOP. 

CRT,  DRW,  HRT,  KAL,  MRD,  NOP,  ONX. 

ACT,  CLD,  CRT,  DRW,  HRT,  KAL,  KNG,  LEA,  MRD,  NOP,  ONX, 

RTC,  S,  SEA,  WHI,  WHW. 


SURFACE-ACTIVE  AGENTS 


TABLE  19B.  —Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  566- -Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


Sulfuric  acid  esters  (and  salts  thereof) — Continued 
^Natural  fats  and  oils,    sulfated— Continued 

»Tallow,   sulfated,    sodium  salt 


Whale  oil,    sulfated,   sodium  salt 

Other  anionic  surface-active  agent:     Trideoyl  alcohol, 
ethoxylated  and  carbonated,    sodium  salt. 

Cationic  Surface-Active   Agents 

»Amlne  oxides  and  oxygen-containing   amines   (except  those 
having  amide  linkages ) : 

*2- ( 8-Heptadecenyl ) -1- ( 2-hydroxyethyl )-2-imidazoline 

*2-Heptadeoyl-l-(2-hydroxyethyl)-2-imidazoline 

»( Mixed  aliyl) amine,    ethoxylated 

»Rosin  amine,    ethoxylated 

»( Soybean  oil  allsyl )  amine,    ethoxylated 

»( Tallow  alkyl)amine,    ethoxylated 

•»Other  amine  oxides  and  oxygen-oontalnlng  amines   (except 
those  having  amide  linkages): 
Acyclic: 

N,N-bis( 2-hydroxyethyl) (coconut  oil  alkyl)amine 
oxide. 

N, N- Bis (2-hydroxyethyl )dodecylamine 

N,  N-Bis(2-hydroxyeti^rl)ootadeoylamine 

N,N-Bls(2-hydroxyethyl)( tallow  alkyl)amlne 

N,N-Bis( 2-hydroxyethyl) (tallow  aliyDamine  acetate 

(Coconut  oil  alkyl)amine,    ethoxylated 

(Coconut  oil  alJ!yl)amine,    ethoxylated,    acetate 

(Coconut  oil  alkyl)amine,    ethoxylated,   maleate 

N, N-Dimethylhexadecylamine  oxide 

( Ifydrogenated  tallow  aU£yl)amlne,    ethoxylated 

N- ( 2-Hydroxyethyl ) -N, N ', N '-trie ( 2-hydroxypropyl ) 

ethylenediamine. 
N-(2-ltsrdroxyethyl)-N,N',N'-tris  (2-hydroxypropyl) 
ethylenediamine  distearate,   methyl  sulfate. 

Octadecylamine,    ethoxylated 

Polyethylenepolyamine,    alioxylated 

N-(Tallow  aliyl)trimethylenediamine,    ethoxylated 

N,N, N', N'-Tetrakis( 2-hydroxyethyl )ethylenediamine 

N,  N,  N ' ,  N ' -Tetr akls ( 2 -hydroxypropy 1 ) ethylenediamine 

dioleate,   methyl  sulfate. 
N, N, N ', N'-Tetrakis( 2-hydroxypropyl )ethylenediamine, 

propoxylated  and  ethoxylated. 
N,  N,  N',  N'-Tetra]d.s(  2-hydroxypropyl)  ethylenediamine 
dioleate,  methyl  sulfate. 

All  other 

Cyclic : 

2-(8-Heptadecenyl)-A,4-bis(hydroxymethyl)-2-oxazoline, 
2- ( 8-Heptadeoenyl )-4-hydroxymethyl-^-methyl-2- 


ACT,  ACT,  HRY,  BSW,  DRW,  EFH,  ICI,  KAL,  LEA,  LUR,  MRA, 
MRD,  NOP,  ONX,  PC,  PCI,  SCP,  SEf,  SID,  SNW,  SOS,  WHI, 
WHW. 

KNG. 


GGY,  NIC,  ONX,  UVC. 

OCT,  HDG,  MQA,  UVC. 

APD,  CIB,  GAP,  NOP,    RH. 

HPC,  NLC,  PCS,  RTF. 

AAC,  ARC,  VAC. 

AAC,  AI*1,  ARC,  CIB,    DUP. 


N-Hexadecylmorpholine 

N-(2-}trdroxyethyl  )-l,  2-diphenylethylenediamlne— 

l-(2-[^droxyethyl)-2-nonyl-2-tntidazoline 

1 -1, 2-HydToxyethyl)-2-nor(  coconut  oil  alkylJ-2- 

imidazoline. 
l-(2-}tydroxyethyl)-2-nor(tall  oil  alkyl)-2- 

imidazoline. 
l-(2-Itrdroxyethyl)-2-trideoyl-2-imidazollne 
hydrochloride. 

l-(2-l^droxyethyl)-2-undecyl-2- imidazoline 

Piperazine,    ethoxylated 

N-(Soybean  oil  aUsyl )morpholine 

Amines  and  amine  oxides  having  amide  linkages: 
■»*Carboxylic  acid  -  diamine  and  polyamine  condensates ; 
Adipic   and  stearic  acids  -  diethylenetriamlne 
condensate. 
»Cooanut  oil  acids  -  diethylenetriamlne  condensate- 


CTL, 

FIN. 

FIN. 

TXT. 

PG. 

AAC, 

APD, 

ARC, 

RPC. 

SDH. 

ONX. 

CIB, 

TCH, 

VAC 

NIC. 

DUP. 

ARC. 

ICI, 

TCH. 

NIC. 

ARC, 

RTF. 

NLC. 

DUP. 

WYN. 

DUP. 

GAF, 

X. 

ecu, 

UVC. 

CCM, 

UVC. 

APD. 

APX, 

PCS. 

PCS, 

UVC. 

MOA, 

UVC. 

NLC, 

UVC. 

GGY, 

UVC. 

GGY, 

UVC. 

GAF. 

APD. 

APX. 

APX, 

NOP, 

■na. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


—Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966— Continued 


Chemioal 

Manuf 

icturers'  identification  codes 

(ac 

wording  to  list  in  table  22) 

Cationic  Surface-Active   4gen(s - -Continued 

»Anines  and  amine  oxides  having  amide  linkages — Continued 

»Carboxylio  acid  -  diamine  and  polyamine  conden- 

sates—Continued 

Coconut  oil  acids  -  N,N-dlmethyltrimethylenediamine 

JRG, 

RCD, 

TXT. 

condensate. 

Mixed  fatty  acids  -  polyalkylenepolyamine  condensate— 

NLC. 

Oleic  acid  -  l-(2-aminoethyl)piperazine  condensate 

TXT. 

»01eic  acid  -  diethylenetriamine  condensate 

APD, 

HDG, 

PCS, 

TXT. 

Oleic  acid  -  diethylenetriamine  condensate,  acetic 

PCS. 

acid  salt. 

Oleic  acid  -  N, N-dimethyltrimethylenedlamine 

CCW, 

SNW. 

condensate. 

Pelargonic  acid  -  tetraethylenepentamine  condensate— 

ICI. 

Stearic  acid  -  diethylenetriamine  condensate 

APX, 

CST, 

DEP, 

HRT,  ONX,  PCS,  S. 

Stearic  acid  -  N,N-diethylethylenediamlne  condensate— 

GBP. 

Stearic  acid  -  dipropylenetriamine  condensate 

JOR. 

Stearic  acid  -  tetraethylenepentamine  condensate 

ICI, 

ONX, 

PCS. 

Tall  oil  acids  -  diethylenetriamine  condensate 

NCW. 

Tall  oil  acids  -  polyalkylenepolyamine  condensate 

TXT, 

UVC. 

All  other 

ajR, 

TOD, 

m. 

»Carboxylio  acid  -  diamine  and  polyamine  condensates. 

ethoxylated: 

Coconut  oil  acids  -  diethylenetriamine  condensate. 

TCC. 

polyethoxylated. 

Coconut  oil  acids  -  ethylenediamine  condensate. 

AKL, 

NOP. 

monoethoxylated . 

♦Oleic  acid  -  ethylenediamine  condensate,  mono- 

CLD, 

DEX, 

NOP, 

SOC,  TNA. 

ethoxylated. 

Palm  oil  acids  -  ethylenediamine  condensate,  mono- 

APX. 

ethoxylated. 

Stearic  acid  -  diethylenetriamine  condensate,  poly- 

TCC. 

ethoxylated. 

♦Stearic  acid  -  ethylenediamine  condensate,  mono- 

AML, 

CLD, 

CMG, 

CST,  DEP,  DEX,  ICI,  MRA,  NOP,  £ 

,  SNW. 

ethoxylated. 

Stearic  acid  -  ethylenediamine  condensate,  poly- 

APD. 

ethoxylated. 

♦Other  amines  and  amine  oxides  having  amide  linkages: 

N, N-Bis (2-hydroxyethyl )-2- (stearamidomethoxy )  - 

CIS. 

ethylamine. 

3-Lauraiiu.do-N,  N-dimethylpropylamlne  oxide 

SNW. 
JffW. 

Polypeptide,  ethyl  ester ——-_-_- __- 

GRD, 

UVC. 

Stearic  acid  -  N-(2-cyanoethyl)diethylene- 

CIB. 

triamine  condensate,  (amine/acid  ratio  =  1/2). 

*itaiines,  not  containing  oxygen  (and  salts  thereof): 

♦Amine  salts: 

AIM, 

ARC, 

FOR. 

N-(  Coconut  oil  alkyDtrimethylenediamine  acetate 

AHC, 

PCS. 

(^jrdrogenated  tallow  aliyDamine  acetate 

ATM, 

ARC. 

(9-0ctadeoenyl)amine  acetate 

GNM. 
ACY, 

ARC. 

Octadecylamine  acetate---— -—--—- 

ARC. 

ARC. 

^coyoean  oij.  aj-jtyx  ^ajnine  acexaxe— -— ------ 

(Tallow  alkyDamine  acetate 

MM, 

AHC, 

FOR. 

]ij_  ( -paj^^Q^  alkyl  )trimethylenediamine  acetate- - 

ARC, 

FOR. 

N- (Tallow  alkyDtrimethylenediamine  naphthenate 

APD, 

FOR. 

N-(Tallow  alkyDtrimethylenediamine  oleate 

FOR. 

All  other 

AEM. 

♦Diamines  and  polyamines: 

1- ( 2-Aminoethyl  )-2- (8-heptadeeenyl )-2-lmidazoline 

NLC. 

1-  ( 2 -Ami  no  ethyl  )-2~hep'tadecyl-2-iEiidazoline------ 

PCS. 

l-(2-Amlnoethyl ) -2- (mixed  alkyl )-2-lmidazollne 

RTF. 

l-(2-Aminoethyl)-2-nor(tall  oil  alkyl )-2-imidazoline— 

NLC. 

ARC, 

FOR, 

GNM, 

HUM. 

♦H-Vuoconux  o±±   a  i  Kyi  jxri mpunyieneuiflimne---------- — 

PCS. 

*:-Vo-nepxaaecenyi )  -^-i  mi  dagoiine — --—--_ 

2-Heptadecyl-2-liiiidazoline 

SCO. 

H-('IjHypH  nlVvl  ^nnT  v*athv1  <iTi^no1  vnm-iTi«a------  - --  — -  — -  — 

CCW. 

n-VMuteu  aj.jiyx  y  poj^e  tny J. enepoiy amine--- ---—--— -—-— 

9  HririTrl  P--{  m-1f^O'7on -Ino       .-..   —   -  -    _   — —  -- 

PCS. 
ARC, 

<i-nonyi-*c-iiitLQazoiine-- — ----- — — — ___——_--_ 

FOR, 

GNM. 

'»rH-^7-ut,xtiaecenyi;xrimexnyieneQiamine ---.. — ._....._ 

N-(Soybean  oil  alkyDtrimethylenediamine 

ARC, 

HUM. 

SURFACE-ACTIVE  AGENTS 


TABLE  IQB.— Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i566— Continued 


Manufacturers'    Identification  codes 
(according  to  list  in  table  22) 


Canonic  Surface-Active   Agents  - -Continued 

^Amines,   not  containing  oxygen   (and  salts  thereof) — 
Continued 
wDianiines   and  polyamines — Continued 

N-( Tallow  aliyDdipropylenetriamine 

»N-( Tallow  aliyZ  )trlmethylenedi«mine 

^Primary  monoamines: 

»( Coconut  oil  alkyl) Amine 

(Cottonseed  oil  aliyl)amine 

»Dodecylamine 

Hexadeoylamine 

*(Hydrogenated  tallow  al]5yl)amine 

(MiJced  aliyl ) amine 

(Mixed  tert-aUjyl) amine 

»9-0otadeoenylamine 

*Octadecylaiiiine 

Octylamine ■•■ 

(Soybean  oil  aliyl ) amine 

(Tall  oil  alkyDamine 

»( Tallow  alkyDamine 

♦Secondary  and  tertiary  monoamines; 

Bis(cooonut  oil  allsyl)amine 

Bis(hydrogenated  tallow  alkyl)amine 

N,N-Dimethyl( coconut  oil  aliyl)amine 

N, N- Dime thy Idodecylamine 

N,  N-Dimethylhexadecylamine 

N, N-Dimethyl(hydrogenated  tallow  aU!yl)amine 

N,N-Dimethyl( mixed  aliyl)amine 

*N, N- Dime thy loctadecylamine 

N,N- Dimethyl (soybean  oil  alkyl)amine 

N, N-Dimethyltetradecylamlne 

N-Methylbis(coconut  oil  all£yl)amine 

N-Methylbis(hydrogenated  tallow  all!yl)amine 

N-Methylbis(mixed  alkyl  )amine 

N-Metl^rldiootadecylamine 

Tridodeoylamine 

Trioctylamine 

Trls(hydrogenated  tallow  aUsyDamlne 

•Oxygen-containing  quaternary  ammonium  salts   (except 
those  having  amide  linkages ) : 

(2-Aiiilnoethyl)ethyl(hydrogenated  tallow  aliyl)- 
(2-hydroxyethyl) ammonium  ethyl  sulfate. 

Benzyl  (coconut  oil  alliyl)bis(2-hydroxyethyl)ammonium 
chloride. 

Benzyl ( coconut  oil  aliyl,   ethoxylated )dimethylammonium 
chloride. 

l-Benzyl-2-heptadecyl-l-(2-hydroxyethyl)-2-imidazolinium 
chloride. 

l-Benzyl-l-(2-hydroxyethyl)-2-nor(tall  oil  aliyl) -2- 
imidazolinium  chloride. 

Bis ( 2-hydroxyethyl,    ethoxylated )methyl( 9-ootadecenyl ) 
ammonixim  chloride. 

Bis  ( 2-hydroxyethyl,   ethcacylated  )me1diyloetadeoylammonium 
chloride. 

(Coconut  oil  alkyl )bis( 2-hydroxyethyl,    ethoxylated ) - 
methylammonium  chloride. 

(Ethoxybenzyl )dlmethyl(ootylphenoxy )aninionlum  chloride 

(Ethoxybenzyl)dimethyl(octyltolyloxy) ammonium  chloride--- 

l-Ethyl-2- ( 8-heptadecenyl ) -1- ( 2-hydroxyethyl )- 
2-imidazolinium  ethyl  sulfate. 

N-Ethyl-N-hexadecylmorpholinlum  ethyl  sulfate 

N-Ett^l-N-(soybean  oil  alkyl )morphollnium  ethyl  sulfate-- 

2-}tydroxytrlmethylenebis  [(coconut  oil  aliyl )dlmethyl- 
ammonium  chloride]. 

( Tridecylbenzyl )diethyl ( 2-hydroxyethyl )ammonium 
chloride. 

Tri ethyl (octadecyloxymethyl) ammonium  chloride 

All  other 


GNM. 

ARC, 

FOR, 

GNM, 

HUM. 

ATM, 

ARC, 

FOR, 

GNM,    HUM. 

FOR. 

ATM, 

ARC, 

FOR, 

GNM. 

ATM. 

ARC, 

FOR. 

pm. 

ARC, 

FOR, 

GNM,    HUM. 

GNM. 

RH. 

ARC, 

FOR, 

GNM. 

ATM, 

ARC, 

FOR, 

GNM. 

ARC, 

RH, 

UCC. 

ARC, 

HUM. 

FOR, 

GNM. 

AEM, 

ARC, 

FOR, 

GNM,    HUM. 

ARC. 

ARC, 

FOR. 

BRD, 

HUM, 

PG. 

BRD. 

ARC, 

BRD. 

ARC. 

PG, 

IH. 

ARC, 

BRD, 

HUM, 

PG. 

ARC. 

ARC, 

BRD. 

FOR, 

GNM. 

ARC, 

FOR, 

GNM. 

PG. 

FOR. 

GNM. 

GNM. 

GNM. 

LUR. 

CIB. 

GAF. 

PCS, 

UVC. 

NIC. 

ARC. 

ARC. 

ARC, 

VAC. 

RH. 

RH. 

APD. 

APD. 

APD. 

CIB. 

SNW. 

DAN. 

TCC. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  19B.  —Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  566— Continued 


Cat 


Surfa 


4ge 


-Continued 


^Quaternary  ajimonlum  salts  having  amide  linkages: 

Benzylbis  ( 2-hydroxyethyl )  ( 2-stearaiiiidomethoxyethyl ) 

ammonivim  chloride. 
2-Heptadeoyl-l-methyl-l-(2-stearaiiddoethyl)  - 

inddazolinlum  methyl  sulfate. 
(2-Hydroxyethyl  )dimethyl(3-stearaiid.dopropyl)  anmoniu 

dihydrogen  phosphate. 
( 2-Hydroxyethyl  )dimethyl ( 3-stearamidopropyl 
nitrate . 

(3-Lauramidopropyl)trimethylammonlum  methyl  sulfate 

Trimethyl(3-oleamldopropyl)anfflionium  methyl  sulfate 

a.1  other 

"Quaternary  ammonium  salts,  not  containing  oxygen: 
»Acyclic: 

«ais( coconut  oil  alkyl )dimethylammonium  chloride 

»Bi3(hydrogenated  tallow  aliyl )dimethylaramonlum 
chloride. 
Bis(hydrogenated  tallow  alkyl )dlmethylammonium 
methyl  sulfate. 

(Coconut  oil  aliyl )trimethylammonium  chloride 

(Cottonseed  oil  alkyl )trlmethylaramonlum  chloride 

Dldodeoyldimethylammonium  bromide 

Dimethy Ibis (mixed  alkyl)-  and  Trimethyl ( mixed  alkyl)- 
ammonluin  chloride. 

Dimethylbls(9-octadeoenyl ) ammonium  chloride 

DlmethylbiE( soybean  oil  alkyl ) ammonium  chloride 

Dimethy Idiootadecylammonlum  chloride 

Dimethyldloctadecylammonium  methyl  sulfate 

»Dodecyltrimethylammonium  bromide  and  chloride: 

Dodecyltrimethylammonlum  bromide 

Dodeoyltrimethylammonlum  chloride 

Ethyldlmethyl( mixed  alkyl )ainmonium  ethyl  sulfate 

Ethyldimethyl(9-ootadeoenyl)ammonium  bromide 

Ethylhexadecyldimethylammonium  bromide 

»Hexadeoyltrimethylainmonlum  bromide 

Hexadeoyltrimethylammonium  chloride 

Hexadeoyltrlmethylammonium  p-toluenesulfonate 

(ftrdrogenated  tallow  alkyl )trimethylamiionium 
chloride. 

Methyl triootylammonlum  chloride 

Methyl tris(mixed  alkyl) ammonium  chloride 

»N,  N,  N ',  N ',  N'-Pentamethyl-N-( tallow  alkyl )trimethylene- 
bis  [amncnlum  chloride] . 

Trlmethyloctadecylammonium  chloride 

Trimethyl ( soybean  oil  alkyl) ammonium  chloride 

Trimethyl (tallow  alkyl) ammonium  chloride 

All  other 

»Benzenoid : 

«Benzyl( coconut  oil  alkyl )dimethylammonium  chloride 

»Benzyldlmethyl( mixed  alkyl ) ammonium  chloride 

»Benzyldimethyloctadecylammonium  chloride 

Benzyldlmethyltetradecylaramonlum  chloride 

»Benzyldodecyldlmethylammonium  chloride 

Benzylhexadecyldimethylammonlum  chloride 

Benzyl(hydrogenated  tallow  alky 1 ) dimethy lammonlum 
chloride 

l-Benzylpyrldinium  chloride 

Benzyl trimethylaramonlum  chloride 

»(3,4-Dichlorobenzyl  )dodeoyldimethylamiionlum  ohloride- 

(Dodecylbenzyl)triethylaramonium  chloride 

»(Dodecylbenzyl)trimethylammonlum  chloride 

2-Dodecylisoqulnolinlum  bromide 

(Dodeoylmethylbenzyl  )trlmethylairanoniuiii  chloride 

1-Dodeeylpyridinium  chloride 

(Ethylbenzyl)dimethyl(mixed  alkyl) ammonium  chlorlde— 
PhenyltrimethylanuDonium  chloride 


Manufacturers'  Identification  codes 
(according  to  list  in  table  22) 


CIB. 
CUL. 


ACY. 
CIB. 
DUP,  NLC,  VAC. 


ARC,  ENJ,  FOR,  GNM,  VAC. 

Am,  ARC,  FOR,  am,   vac. 


ARC,    FOR, 

GNM. 

FOR. 

ONX. 

GNM. 

GNM. 

ARC. 

FOR,    PG. 

ONX. 

DUP. 

ARC,    FOR, 

GNM. 

JOR. 

ONX. 

FIN. 

DUP,    FIN, 

ICI. 

ARC. 

FIN. 

ARC,    FOR, 

HUM. 

GNM. 

AEM,    VAC. 

ARC,    GNM, 

ORO. 

ARC,    GNM. 

ARC,    VAC. 

ARC,    FOR, 

GNM. 

STC. 

CRT,    DEP, 

LUR, 

TXT. 

AAC,    BRD, 

CUL, 

FIN, 

ONX,    PG,    RH,    RTF,    TXT,   VAC, 

CUL,    FIN, 

ONX, 

PCS, 

RET,    WSN. 

SNW,    WSN. 

FIN,    ONX, 

SDH, 

WSN. 

ONX,    RH. 

HUM,    PCS. 

PC. 

CUL,  NLC,  VAC. 

CUL,  ONX. 


SURFACE-ACTIVE  AGENTS 


-Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i966— Continued 


Manufacturers '   Identification  codes 
(according  to  list  in  table  22) 


Non.omc  Surface-Active  Agent. 

»Carboxylio  acid  amides: 

»Carboxylic  acid  -  alkanolamine  condensates: 

»Diethanolainine  condensates  (amine/aoid  ratio  =  2/1): 

*Capric  acid 

Castor  oil  acids 

»Coconut  oil  acids 

Coconut  oil  and  tall  oil  acids 

Coconut  oil  and  tallow  acids 

»Laurio  acid 

Laurie  and  nyristlo  acids 

Llnoleic  acid 

»01eic  acid 

Palmitic  acid 

Pelargonio  acid 

♦Stearic  acid 

*Tall  oil  acids— 

Unspecified  mixed  fatty  acids 

»Dlethanolaiiilne  condensates  (amlne/acid  ratio  =  l/l): 

»Coconut  oil  acids 

»Laurio  acid 

Laurie  and  nyristic  acids 

*01eio  acid 

Palmitic  and  stearic  acids 

♦Stearic  acid 

Tall  oil  acids 

Tallow  acids- 

Itaspeoified  mixed  fatty  acids 

•Bthanolamine  condensates  (amine/acid  ratio  =  2/1): 

♦Coconut  oil  acids 

Hydrogenated  castor  oil  acids 

Hydrogenated  tallow  acids 

Laurie  acid 

Stearic  acid 

♦Bthanolamine  condensates  (other  amine/acid  ratios): 

Coconut  oil  acids  (amlne/acid  ratio  =  l/l) 

Laurie  and  nyristic  acids  (amine/acid  ratio  =  l/l)-' 

Oleic  acid  (amine/acid  ratio  =  l/l) 

Stearic  acid  (amine/acid  ratio  =  l/l) 

Stearic  acid  (amine/acid  ratio  =  1/2) 

♦Isopropanolamine  condensates : 

Coconut  oil  acids 

♦Laurie  acid 

Laurie  and  nyristio  acids 

Oleic  acid 

♦Other  alkanolamlne  condensates: 

Coconut  oil  acids  -  dlethanolamine  condensate 

(amlne/acid  ratio  ==  1.4/1). 
Coconut  oil  acids  -  dlethanolamine  condensate 

(amine/acid  ratio  «  1/2). 
Laurie  acid  -  dlethanolamine  condensate  (amlne/acid 
ratio  =  1.6/1). 

Stearic  acid  -  methanolamlne  condensate 

♦Carboxylle  acid  -  alianolamine  condensates,  ethoxylated 
Coconut  oil  acids  -  ethanolamlne  condensate, 

ethoxylated. 
Urdrogenated  tallow  acids  -  ethanolamlne  condensate, 
ethoxylated. 

Oleic  acid  -  ethanolamlne  condensate,  ethoxylated 

Oleic  acid  -  methanolamlne  condensate,  ethoxylated 

Tall  oil  acids  -  ethanolamlne  condensate,  ethoxylated 
♦Carboxylle  acid  -  diamine  and  polyamine  condensates 
(nonlonlc ) : 
Olelo  acid  -  ethylenediamine  condensate  (amine/acid 
ratio  »  1/2). 


GGY,  PCS,  UVC. 

ONX,  PCS,  VAL. 

ML,  ARD,  BSC,  BSW,  CIB,  CLI,  CRT,  CTL,  DEP,  EFH,  HAL, 
HLI,  HRT,  JOR,  KNP,  LUR,  MOA,  NOP,  PC,  PCS,  PNX,  RCD 
SBC,  SEY,  STP,  SWT,  TCC,  TXC,  UNN,  UVC,  VAC,  VND, 
WIC,  WTC. 

CSB. 

CLI,  PC. 

ARD,  CLI,  DR*,  NOP,  ONX,  PCS,  PG,  RCD,  WTC. 

TXN. 

VND. 

CCW,  CLI,  HLI,  UVC,  VAC,  STP,  WTC. 

CMC. 

Qffi,  PCS. 

AML,  EMR,  JOR,  NOP,  ONX,  SCO,  TXC,  VAL,  WTC. 

EFH,  MRA,  UVC,  WTC. 

BSC,  HLI. 

APX,  ARD,  CCL,  CLI,  CTL,  DRW,  IMK,  GGY,  HLI,  MOA,  MRV, 
NOP,  ONX,  PCS,  PEK,  QCP,  RCD,  RFC,  RTF,  SBC,  SEY, 
STP,  TXT,  UVC,  VAC. 

CTL,  CUL,  DRW,  LEV,  MOA,  ONX,  PCS,  PG,  RTF,  SBC,  STP, 
TXT. 

CLI,  TXT. 

GGY,  NOP,  PCS,  SBC,  SCP,  SWT,  TCC,  TXT,  VAC. 

BSC,  MRA,  PCS. 

BSC,  DEP,  am,  GGY,  GLY,  RPC,  SEY,  UVC. 

MRV,  PCS. 

RPC. 

STP. 

CTL,  PCS,  RTF,  STP,  UVC,  VND,  WTC. 

GLY. 

GLY. 

CTL,  WTC. 

CLI. 

HRT,  MOA,  PG,  STP. 

TXT. 

VPC. 

MOA,  VND. 

GLY,  WTC. 

DSO,  MOA,  STP. 

ARD,  CLI,  MOA,  PCS,  WTC. 

LEV,  TXT. 

WTC. 

JRG. 


WON. 

DUP,  ICI. 

STP. 

ARC,  NOP. 

ARC,  GAF. 

QAF 

JCC. 


CCW,  GLY,  HDG. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  19B Surface -active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 

manufacturer,  i 566— Continued 


Manufacturers'    identification  code 
(according  to  list  in  table  22) 


Sarfa 


Agen 


-Continued 


»Carboxylic  acid  amides— Continued 

»C'xrboxyJ.io  acid  -  diamine  and  polyamine  condensates 
(nonionic )— Continued 
Stearic  acid  -  N>  N'-diethylethylenediamine  condensate 
(amine/acid  ratio  =  1/2). 
♦Stearic  acid  -  ethylenediamine  condensate  (amine/acid 
ratio  =1/2). 

All  other 

»Carboxylic  acid  esters: 
»Anhydrosorbltol  esters: 

Anhydrosorbitol  dioleate 

Anhydrosorbitol  ester  of  mixed  fatty  acids 

»Anhydrosorbitol  monoester  of  tall  oil  acids 

♦Anhydrosorbitol  monolaurate 

Anhydrosorbitol  mono-oleate 

Anhydrosorbitol  monopalmitate 

Anhydrosorbitol  monostearate 

Anhydrosorbitol  sesquioleate 

Anhydrosorbitol  tetrastearate 

Anhydrosorbitol  triester  of  tall  oil  acids 

♦Anhydrosorbitol  trioleate 

Anhydrosorbitol  tristearate 

♦Ethoxylated  anhydrosorbitol  esters : 

Ethoxylated  anhydrosorbitol  monoester  of  tall  oil 
acids. 

♦Ethoxylated  anhydrosorbitol  monolaurate 

♦Ethoxylated  anhydrosorbitol  mono-oleate 

♦Ethoxylated  anhydrosorbitol  monopalmitate 

♦Ethoxylated  anhydrosorbitol  monostearate 

Ethoxylated  anhydrosorbitol  triester  of  castor 

oil  acids. 
Ethoxylated  anhydrosorbitol  triester  of  tail  oil 
acids. 

♦Ethoxylated  anhydrosorbitol  trioleate 

♦Ethoxylated  anhydrosorbitol  tristearate 

♦Ethylene  glycol  and  diethylene  glycol  esters: 

Diethylene  glycol  dioleate 

Dietl^lene  glycol  distearate 

Diethylene  glycol  monoester  of  coconut  oil  acids 

Diethylene  glycol  monoester  of  tall  oil  acids 

♦Diethylene  glycol  monolaurate 

♦Diethylene  glycol  mono-oleate 

Diethylene  glycol  monoricinoleate 

♦Methylene  glycol  monostearate 

Diethylene  glycol  sesquiester  of  tall  oil  acids 

Diethylene  glycol  sesquilaurate 

Diethylene  glycol  sesquistearate 

♦Ethylene  glycol  distearate 

Ethylene  glycol  mono-oleate 

♦Ethylene  glycol  monostearate 

Ethylene  glycol  sesquistearate 

♦Glycerol  esters: 

♦Con?)lex  glycerol  esters: 

Glycerol  diacetyltartrate  monostearate 

Glycerol  lactate  palmitate 

Glycerol  lactate  stearate 

Glycerol  maleate  mono-oleate 

Glycerol  monoester,  aoetylated 

Glycerol  nionoester  of  mixed  fatty  acids,  acetylated- 

Glycerol  mono-oleate,  acetylated 

♦Glycerol  esters  of  chemically  defined  acids: 

Glycerol  dioleate 

Glycerol  distearate 

Glycerol  monocaprylate 

♦Glycerol  monolaurate 

♦Glycerol  mono-oleate 


SNW. 

CCW, 

CTN, 

GLY, 

ICI. 

NOP. 

APD. 

GLY. 

APD, 

GLY, 

HDG, 

RTF, 

TCH. 

APD, 

GLY, 

HDG, 

PCS, 

TCH. 

AAC, 

APD, 

DRW, 

GLY, 

HAL, 

HDG, 

APD. 

GLY, 

PCS. 

AAC, 

APD, 

DRW, 

GLY, 

HDG, 

PCS. 

AAC, 

GLY. 

APD. 

GLY, 

TCH. 

APD, 

GLY, 

HDG, 

PCS, 

TCH. 

APD, 

GLY, 

HDG. 

TCH. 

AAC,  APD,  DRW,  GLY,  HDG,  PCS,  TCH. 

AAC,  APD,  ARC,  DRW,  GLD,  GLY,  HDG,  PCS,  TCH. 

AAC,  APD,  GLY,  PCS,  TCH. 

AAC,  APD,  DRW,  GLY,  HDG,  PCS,  TCH. 

APD. 

APD,  RTF. 

AAC,  AH),  GLY,  TCH. 
AAC,  APD,  GLY,  PCS,  TCH. 

GLY. 

ARC,  GLY. 

MR. 

HDG. 

ARC,  CCW,  GLY,  HAL,  HDG,  KAL,  NOP,  WTC. 

ARC,  HAL,  NOP,  WTC. 

GLY. 

ARC,  CCW,  CLI,  HAL,  NOP,  PCS,  QCP,  SEY,  UVC,  VAL,  VND, 

WTC. 
QCP,  WTC. 
GLY. 
WM. 

ARC,  am,  HAL,  HDG,  PCS. 
HAL. 
ARC,  CCW,  CLI,  EFH,  GLY,  HAL,  HDG,  KNP,  PCS,  VND,  WM. 


DRW,  PCS,  WTC. 
DRW,  GLD. 
APD,  GLD. 
NOP,  WTC. 


ARC,  HAL. 
APX,  ARC. 
ARC,  DRW. 

ARC,  GLY,  HAL,  KNP. 

APD,  ARC,  CCW,  DRW,  EFH,  HC,  EMR,  GLY,  HAL,  HDG,  PCS, 
SWT,  WM. 


SURFACE-ACTIVE  AGENTS 


TABLE  19B.- -Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i566— Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


Agen 


-Continued 


»Carboxylio  acid  esters— Continued 
"Glycerol  esters — Continued 

"Glycerol  esters  of  chemically  defined  acids--Continued 

"Glycerol  monoricinoleate 

"Glycerol  raonostearate 


"Glycerol  esters  of  mixed  acids : 

Glycerol  monoester  of  coconut  oil  acids 

Glycerol  monoester  of  com  oil  acids 

Glycerol  monoester  of  cottonseed  oil  acids 

Gljoerol  monoester  of  hydrogenated  cottonseed  oil 

acids. 
Glycerol  monoester  of  hydrogenated  soybean  oil 
acids. 

Glycerol  monoester  of  lard  acids 

Glycerol  monoester  of  peanut  oil  acids -— 

Glycerol  sesquiester  of  mixed  fatty  acids 

All  other 

"Natural  fats  and  oils,  ethoxylated: 

"Castor  oil,  ethoxylated 


}^rogenated  castor  oil,  ethoxylated 

Lanolin,  ethoxylated 

♦Polyethylene  glycol  esters: 
"Polyethylene  glycol  esters  of  chemically  defined 
acids: 

"Polyethylene  glycol  dilaurate 

"Polyethylene  glycol  dioleate 


"Polyethylene  glycol  distearate 

Polyetlvlene  glycol  methyloarbitol  maleate- 
"Polyethylene  glycol  monolaurate 


♦Polyethylene  glycol  mono-oleate- 


Polyethylene  glycol  monopalmitate 

Polyetlqrlene  glycol  monopelargonate- 
Polyethylene  glycol  monoricinoleate- 
♦Polyethylene  glycol  raonostearate 


Polyethylene  glycol  sesquioleate 

"Polyethylene  glycol  esters  of  rosin  and  tall  oil  acids; 

Polyethylene  glycol  diester  of  tall  oil  acids 

Polyethylene  glycol  monoester  of  rosin  acids 

Polyethylene  glycol  monoester  of  tall  oil  acids 

Polyethylene  glycol  sesquiester  of  rosin  acids 

"Polyethylene  glycol  sesquiester  of  tall  oil  acids 

Polyethylene  glycol  unspecified  ester  of  tall  oil 
acids. 
"Polyethylene  glycol  esters  of  other  mixed  acids: 

Polyethylene  glycol  diester  of  trimerized  castor  oil 

acids. 
Polyethylene  glycol  ester  of  unspecified  mixed  fatty 

acids. 
Polyethylene  glycol  monoester  of  coconut  oil  acids — 
Polyethylene  glycol  monoester  of  soybean  oil  acids — 

Polyethylene  glycol  monoester  of  tallow  acids 

Polyethylene  glycol  sesquiester  of  castor  oil  acids— 
•Polyethylene  glycol  sesquiester  of  coconut  oil 
acids. 

Polyethylene  glycol  sesquiester  of  tallow  acids 

»Polyglycerol  esters: 

Polyglyoerol  distearate 

Polyglyoerol  lactate  oleate 

Polyglycerol  mono-oleate 


BAG,  COW,  HAL. 

ARC,  CCW,  CHL,  CRT,  DRW,  EK,  GLY,  GRO,  HAL,  HDG,  JRG, 

LUR,  MRA,  NOP,  NW,  PCS,  PG,  SNW,  SWT,  TCC,  UVC,  VND, 

WM,  WTC,  X. 

DRW,  GLY,  HDG,  SWT,  WM. 

GLD. 

DRW,  EK,  HDG,  PCS. 

aLD,  LEV,  PCS. 

DRW,  GLD. 

EK,  GLD,  GLY,  PCS. 


APD,  BAG,  DRW,  Uffi,  GAF,  GLY,  ICI,  NLC, 

TCH,  VAC. 

APD,  GAF,  TCH,  VAC. 

AAC,  APD,  DRW,  PCS. 


ARC,  DEX,  EFH,  GLY,  HAL,  HDG,  JOR,  NOP,  UVC,  WM. 

ARC,  CLD,  EFH,  ENJ,  GGY,  GLY,  HAL,  HDG,  NOP,  PCS,  UVC, 

VND,  x. 
ARC,  GLY,  HAL,  HDG,  PCS,  QCP. 
CCA. 
AAC,  ARC,  BSC,  CCA,  GGY,  GLY,  HAL,  HDG,  JOR,  KNP,  NOP, 

SYC,  TCH,  TXT,  UVC. 
ARC,  CCA,  CLD,  CRC,  CRT,  DEX,  DRW,  EMR,  GAF,  GGY,  GLY, 

HAL,  HDG,  ICI,  NOP,  ONX,  PCS,  SWT,  SYC,  TCH,  UVC, 

VAC,  WM,  WTC,  X. 
APD,  GLY. 
IMR. 

AAC,  ARC,  BAC,  HAL,  NOP,  TCH. 
AML,  APD,  ARC,  CRT,  DEP,  DEX,  DRW,  affi,  GAF,  GGY,  GLY, 

HAL,  HDG,  ICI,  KNP,  NOP,  ONX,  PC,  PCS,  PD,  RH,  SEY, 

TCC,  TCH,  VND,  WTC. 
PCS. 


GLY. 
NLC. 
GLY, 
APD, 
AML, 
ARC. 

SOS. 
HFC, 
APD, 

QCP. 
APX, 

DRW, 

HDG, 

MON,    NOI 

GLY. 

mj. 

IMR, 
SYC. 
SOS. 
GGY, 
ARL, 

GLY, 

WTC. 
DRW, 

PCS. 
NOP, 

ONX, 

PCS, 

PG,    VND. 

ONX. 

PCS. 
DRW. 
HDG, 

VND, 

WTC. 

NOP,  CMC,  RTF,  TCH,  WTC. 


160 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 — Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


ive  /Ige 


»CaTboxylic  acid  esters — Ctontinued 
^Propanediol  esters: 

1, 2-Propanediol  distearate 

1, 3-Propanediol  wonoester  of  coconut  oil  acids 

»1, 2- Propanediol  monolaurate 

1, 2-Propanediol  mono-oleate 

»1, 2- Propanediol  monostearate 

All  other 

»Other  oarboxylic  acid  esters: 

Anhydrosorbitol  glycerol  monolaurate 

Coconut  oil  acids,  ethoxylated  methanol  ester 

Di-isobutylene  maleate 

Ethoxylated  glycerol  sesquiester  of  mixed  fatty  acids- 

Ethoxylated  1,2-propanedlol  monostearate 

Ethoxylated  sorbitol  beeswax  ester 

Ethoxylated  sorbitol  hexaester  of  tall  oil  acids 

Ethoxylated  sorbitol  hexaoleate 

Ethoxylated  sorbitol  lanolin  ester 

Ethoxylated  sorbitol  mono-oleate 

Ethoxylated  sorbitol  monostearate 

Ethoxylated  sorbitol  oleate,  acetylated 

Ethoxylated  sorbitol  pentaester  of  tall  oil  acids 

Ethoxylated  sorbitol  pentalaurate 

Ethoxylated  sorbitol  stearate 

Ethoxylated  sorbitol  tetraester  of  laurio  and  oleic 
acids. 

Ethoxylated  sorbitol  tetraester  of  tall  oil  acids 

Methylgluooside  laurate 

Metl^lglucoside  oleate 

Pentaerythrltol  distearate 

Polyaliylene  glycol  adipate 

PolyaUtylene  glycol  diglycolate 

Polyalliylene  glycol  naphthenate 

Sucrose  esters  of  fatty  acids 

All  other 

♦Ethers : 

*Benzenoid  ethers: 

Alkylphenol  -  formaldehyde  condensates,  alkoxylated: 

(Mixed  alkyl)phenol  -  formaldehyde,  alkoxylated 

Nonylphenol  -  formaldehyde,  alkoxylated 

tert-Ootylphenol  -  formaldehyde,  ethoxylated 

Pentylphenol  -  formaldehyde,  alkoxylated 

Diisobutylphenol,  ethoxylated 

»Dlnonylphenol,  ethoxylated 

»Dodeoylphenol,  ethoxylated 

»Iso-octylphenol,  ethoxylated 

(Mixed  aliyl )phenol,  ethoxylated 

(Mixed  alkyl  )phenol,  ethoxylated,  butyl  ether 

(Mixed  alkyl )phenoxypoly(ethyleneoxy)ethyl  chloride— 
♦Nonylphenol,  ethoxylated 

Nonylphenol,  ethoxylated  and  propoxylated 

Nonylphenoxypoly(ethyleneoxy)ethyl  iodide 

Pentylphenol,  ethoxylated 

♦Phenol,  ethoxylated 

Rienol,  propoxylated 

Tetradeoylphenol,  ethoxylated 

Tridecylphenol,  ethoxylated 

}5/lenol,  ethoxylated 

All  other 

♦Nonbenzenoid  ethers: 

Linear  alcohols,  alkoxylated: 

Decyl  alcohol,  ethoxylated 

Decyloxypoly(ethyleneoxy)ethyl  chloride 

Decyl  and  octyl  alcohols,  ethoxylated 

♦Dodecyl  alcohol,  ethoxylated 

♦Hexadeoyl  alcohol,  ethoxylated 

♦Mixed  linear  alcohols,  ethoxylated 


HAL. 

DHW. 

ARC, 

HAL, 

SBC, 

WM. 

ARC, 

HAL. 

APD, 

ARC, 

CCW, 

EK,    OLD,    GLY,    HAL, 

HDG,    JRG,    PCS,    PG. 

PCS. 

APD, 

PCS. 

JOR. 

RH. 

APD. 

APD. 

APD. 

APD, 

TCH. 

APD, 

TCH. 

APD. 

APD. 

SNW. 

APD. 

APD. 

APD. 

APD. 

APD. 

APD. 

HDG. 

HDG. 

VAL. 

PFZ. 

NLC, 

RTF. 

APD. 

SUG. 

CCW, 

STC, 

WM. 

RTF. 

NLC, 

RTF. 

SDW. 

RTF. 

r,AF, 

RH. 

GAF, 

JCC, 

STP. 

GAF, 

MON, 

PCS, 

UCC. 

APX, 

CTB, 

DRW, 

NOP, 

CMC. 

GAF. 

RH. 

GAF. 

APD, 

CIB, 

CLY, 

DOW. 

DRW, 

GAF,    HPC 

JCC,    MON,    NLC,    CMC, 

PCS,    RH 

,    RTF 

,    STP 

,    TCH 

UCC. 

RTF. 

GAF. 

RTF. 

APD, 

GAF, 

JCC, 

NOP, 

TCH, 

UCC. 

NLC. 

ORO, 

PCS. 

PCS. 

NLC. 

RH, 

VPC. 

GAF,  I  CI,  PCS. 
GAF. 
GAF. 

AAC,  APD,  DRW,  DUP,  GAF,  GLY,  JCC,  CMC,  PCS. 

ATM,  APD,  CIB,  I  CI,  NAC. 

ATM,  CO,  GAF,  JCC,  LAK,  MON,  NLC,  PCS,  RH,  SHC,  STP, 
TCH.  UCC. 


SURFACE-ACTIVE  AGENTS 


-Surface-active  agents  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966— Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


Surfa 


Agen 


-Continued 


»Ethers — Continued 

»Nonbenzenoid  ethers— Continued 

Linear  alcohols,    alkoxylated — Continued 

Mixed  linear  alcohols,    ethoxylated  and  propoxylated 

■W-Octadeoenyl  alcohol,    ethoxylated 

*Octadecyl  alcohol,    ethoxylated 

Sperm  oil  alcohol,    ethoxylated 

Tallow  alcohol,    ethoxylated 

Other  ethers  and  thloethers: 

tert-Dodecyl  meroaptan,    ethoxylated 

Glucose,    ethoxylated 

Isodecyl  alcohol,    ethoxylated 

lEo-octyl  alcohol,    ethoxylated 

Poly(mixed  ethylene,   propylene  )glycol 

Polypropylene  glycol,    ethoxylated 

Rosin  alcohol,    ethoxylated 

Sorbitol,    ethoxylated 

Sorbitol,   propoxylated  and  ethoxylated 

Sucrose,   propoxylated 

2,4-,7,9-Tetramethyl-5-decyr.e-4,7-diol,   ethoxylated-- 
»Trideoyl  alcohol,    ethoxylated 

Tridecyl  alcohol,   propoxylated  and  ethoxylated 

Trimethylheptanol,    ethoxylated 

Trimethylolpropane,    alkoxylated 

All  other 

«Other  nonionic  surface-active  agents: 

Bis(octadecenyloxypolyethylene  glycol)  ester  of  1,6- 

hexajnethylenedicarbamic  acid. 
3,5-Dimethyl-l-hexyn-3-ol 

3,6-Dimethyl-'i-octyne-3,6-diol 

Dodecylbenzenesulfonic  acid  -  diethanolamine  condensate, 

fatty  acid  monoester. 

Ethylene  glycol  dibenzenesulfonate 

Glycerol  sesquiester  of  hydrogenated  castor  oil  acids, 

borated  and  ethoxylated. 

Octyl  phosphate,  ethoxylated 

2,4,7,9-Tetrainethyl-5-decyne-4,7-diol 

Tri(castor  oil  alkyl)  phosphate 


RTF, 

STP, 

WYN. 

AAC, 

ADM, 

APD. 

CTB, 

DUP, 

GAF, 

ICI, 

NOP, 

TCH, 

VAC, 

VPC. 

APD, 

CIB, 

DUP. 

HDG. 

DUP. 

AAC, 

ma. 

AAC, 

MON. 

RH. 

PCS. 

GAF. 

NIC, 

UCC. 

NLC, 

PCS, 

RTF, 

vmj. 

CIB, 

HPC. 

APD, 

TCH. 

APD. 

APD. 

cue. 

AAC, 

APD, 

DRW, 

EFH, 

GAF, 

GLY, 

ICI, 

JCC, 

MON, 

NLC, 

CMC 

PCS,    RTF,    TCH,    UCC. 

JCC. 

UCC. 

JCC, 

RTF. 

SNW, 

VAC. 

CIB. 

cue. 

cue. 

MAH. 

DUP,    SFA. 

cue. 

GLY. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 
Pesticides  and  Related  Products 


TABLE  20B. --Pesticides  and  related  products  for  which  U.S.  production  or 
by  manufacturer,  1966 


lies  were  reported,  identified 


[Pesticides  and  related  products   for  which  separate  statistics  are  given  in  table  20A  are  marked  below  with  an 
asterisk  (*);   products  not  so  marked  do  not  appear  in  table  20A  becaxise  the  reported  date  are  accepted  in  confidence 
and  may  not  be  published.  Manufacturers'    identification  codes  shown  below  are  taken  from  table  22.  An  x  signifies 
that  the  manufacturer  did  not  consent  to  his  identification  with  the  designated  product] 


PESTICIDES  AND  RELATED  PRODUCTS,   CYCLIC 

»  Fungicides: 

2,6-Bis(dimethylaininomethyl)c;yclohexanone 

5-Chloro-2-benzothiazolethiol,    laurylpyridium  salt- 

2,'+-Dichloro-6-(o-chloroanilino)-s-triazine 

l,A-Dichloro-2, 5 -diraethoxy benzene 

2,3-Dichloro-l,4-naphthoquinone  (Dichlone) 

2,6-Dichloro-^-nitroanillne  (DCNA) - 

»3 , 5-Dimethyl-l, 3, 5 , 2H-tetrahydrothladiazine-2-thior 
(D»CT). 

Diphenylammonium  propionate 

3,3'-Ethylenebis(tetrahydro-4,6-dimethyl-2H-l,3,5- 
thiadiazine-2-thione ) . 

2-Heptadecyl-2-iraidazoline  (Glyodin) 

2-Mercaptobenzothiazole,  monoethanolamine  salt 

»Mercury  fungicides: 

N-(Ethylmercuri)-p-toluene  sulfonanilide 

Hydroxymerourichlorophenol 

Hydroxymercurinitrophenol 

Mercurial  turf  fungicides 

Methylmercury  quinolinolate- 
2- ( Phenylmercuriamino ) ethyl 

Phenylmercuricajranonium  acetate 

Phenylmercuric  borate 

Phenylmercuric  hydroxide 

Phenylmercuric  lactate 

Phenylmercuric  naphthonate 

Phenylmercuric  oleate 

Phenylmercuric  propionate 

N-Phenylmercuriformamide 

Tris(2-hydroxyethyl)(phenylmercuri)aiiimonium  lactate- 
2- ( 1-Methy  1-n-heptyl) -"i , 6-dlnitrophenyl  crotonate 

(Dinocap) . 
3-(2-Methylpiperldino,lpropyl-3,<;-diohlorobenzoate 
(Piperalin). 

»Naphthenio  acid,  copper  salt 

Pentachloronitrobenzene  (PCNB) 

■»Pentachlorophenol  (PCP) 

Pentachlorophenol,  sodium  salt 

*8-Quinolinol  (8-Hydroxyquinoline),  copper  salt 

Tetrachloro-p-benzoquinone  (Chloranil) 

2,3,'i,6-Tetrachlorophenol  and  sodium  salt 

N-Trlchloromethylthio-'i-cyclohexene-l,2-dicarboximde 
( Captan ) . 

N-Trichloromethylthiophthalimide  (Folpet) 

»2,'i,5-Trichlorophenol 

*2,'4,5-Trichlorophenol,  ethanolamlne  salt 

»2,'i,5-Trichlorophenol,  sodium  salt 

2,<i,6-Trlchlorophenol 

Other  fungicides 

^Herbicides   and  plant  hormones: 

•4-Amino-3,5,6-trichloropicolinic  acid   (Picloram) 

5-Bromo-3-sec-butyl-6-methyluracil   (Bromacil) 

3-tert-Butyl-5-chloro-6-methyluracil 

N-Butyl-N-ethyl-ii,a,:i-trlfluoro-2,6-dinltro-p- 
toluidine   (Benefin). 

2-Butynyl-'i-ohloro-m-chlorocarbanilate  (Barban) 

2-Chloro-'i-ethylamino-6-isopropylamino-s-triazine 
(Atrazine). 

3'-Chloro-2-methyl-p-valerotoluidide  (Solan) 

3-(p-Chlorophenyl)-l,l-dimethylurea  (Monuron) 

3-(p-Chlorophenyl)-l,l-dimethylurea  trichloroacetate-- 
3-Cyclohexyl-5,6-trimethyleneuracll 


USR. 
CWN. 
MRK,  OTC,  SF,  WRC. 


DUP. 
DUP. 
DUP. 
MAL. 

MRK. 
CLY. 
TRO. 
TRO. 
MRK. 
U3K. 
MRK. 
CLY,  HNX,  MRK,  TRO. 


CCA,  FER,  HNX,  MCI,  MLD,  SHP,  SOC,  SRR,  TGL,  TRO,  WTC. 


BXT,    DOW,    FRO,   MON, 
DOW,   MON,    RCI. 
GAM,    HNX,   MRK. 
USR. 

RCI, 

SFD. 

CHO. 

CHO. 

DA,   DOW,   HK,   HPC. 

BKL,   GAF. 

FMN. 
DUP. 
ACN. 
DUP. 


PESTICIDES  AND  RELATED  PRODUCTS 


-Pesticides  and  related  products  for  which  U.S.  production  or  ^ 
by  manufacturer,  1 966— Continued 


lies  were  reported,  identified 


PESTICIDES  AND  RELATED  PRODUCTS,   CYCLIC— Continued 

"Herbicides  and  plant  hormcnes--Continued 

2,6-Di-tert-butyl-p-tolyljnethylcarbamate 

2,5-Dichloro-3-ajninobenzoic  acid,   ammonium  salt 

3,6-Dichloro-o-amsic  acid    (Dicamba) 

2,'*-Dichlorobenzyltributylphosphonium  chloride 

2-{2,'i-Diohlorophenoxy)ethyl  sulfate,    sodium  salt 
(Sesone) . 

2-(2,'*-Dichlorophenoxy)propionic  acid   ( Dichlorprop ) 

3-(3,4-Dichlorophenyl)-l,l-dimethylurea   (Diuron) 

3-(3,'4-Dichlorophenyl)-l-methoxy-l-methylurea   (Linuron) 
3-(3,4-Dichlorophenyl)-l-methyl-l-n-butylurea   (Nebiu-on) 

2,4-Dichlorophenyl-4-nitrophenyl  ether 

3','4'-Diohloropropionanilide  (Propanil) 

l,2-Dihydropyridazine-3,6-dione  (Maleic  hydrazide) (MH)- 
N- ( beta-0, 0-Di  isopropyl-dithiophosphcry lethyl ) -benzene 
sulfonamide  (Bensulide). 

N,N-Dimethyl-2,2-diphenylacetamide  (Diphenamid) 

l,l-Dimethyl-3-phenylurea  (Fenuron) 

l,l-Dimethyl-3-phenylurea  trichloroacetate 

Dimethyl-tetrachloroterephthalate 

»Dinltrobutylphenol  (DNBP) 

»Dinitrobutylphenol,  aramoniim  salt 

Dinitrobutyl  phenol,  triethanolamine  salt 

Dinitrocresol  (DNOC) — - 

Dinitrocresol,  sodium  salt 

Diphenylaoetonitrile  (Diphenatrile) 

2-Ethylamino-'V-isopropylamino-6-methylmercapto-s- 

triazine  (Ametryne). 
S-Ethyl  hexahydro-lH-azepine-l-oarbothioate  (Molinate)- 

Gibberellic  acid — . 

3-(Hexahydro-'l,7-methanoindan-5-yl)-l,l-dimethylurea 
(Norea). 

3-Indolebutyric  acid 

Isopropyl  N-phenylcarbamate  (IPC) 

Isopropyl  N-(3-chlorophenyl) carbamate  (CIPC) 

l-(2-kfethylcyclohe)(yl)-3-phenylurea  (Siduron) 

2-Met;iylniercapto-4. ,  6-bis- ( isopropylamino ) -s-trlazine 

(Prometryne) . 
1-Naphthaleneacetic  acid  and  derivatives: 

1-Naphthaleneacetamlde 

•1-Naphthaleneacetic  acid  (NAA) 

•1-Naphthaleneacetic  acid,  methyl  ester 

•1-Naphthaleneacetic  acid,  sodium  salt 

N-1-Naphthylphthalamic  acid  (NPA)- 

7-0xabicyclo[2.2.1] heptane-2,3-dicarboxylic  acid, 

disodium  salt  (Endothal). 
Phenoxyacetic  acid  derivatives: 

'4-Chloro-2-methylphenoxyacetic  acid  (MCPA) 

4-Chlorophenoxyacetic  acid,  potassium  salt 

•2,^-Dichlorophenoxyacetic  acid  (2,'4-D) 

•2,^-Dichlorophenoxyacetic  acid  esters  and  salts: 

2,'i-Dlchlorophenoxyacetic  acid,  2-butoxyethyl  ester 
2,'i-Dlchlorophenoxyacetic  acid,  butoxypoly- 
propyleneglycol  ester. 

•2,'i-Dichlorophenoxyacetic  acid,  n-butyl  ester 

2,'4-Dichlorophenoxyacetic  acid,  sec-butyl  ester 

•2,'4-Dlchlorophenoxyacetic  acid,  dimethyl  ami ne  salt- 
2,'i-Dichlorophenoxyacetic  acid,  ethanolajnine  and 
isopropanolamine  salt. 

2,4-Dichlorophenoxyacetic  acid,  ethyl  ester 

2,'i-Dichlorophenoxyacetic  acid,  2-ethylhexyl  ester- 

•2,'+-Dichlorophenoxyacetic  acid,  iso-octyl  ester 

•2,A-Dichlorophenoxyacetic  acid,  isopropyl  ester 

2,<l-Dichlorophenoxyacetic  acid,  lithium  salt 

2,<i-Dichlorophenoxyacetic  acid,  sodium  salt 

•2,'i,5-Trichlorophenoxyacetic  acid  (2,^,5-T) 

»2,'i,5-Trichlorophenoxyacetic  acid  esters  and  salts: 

2,4,5-Triohlorophenoxyacetic  acid,  amyl  esters 

2,'i,5-Trichlorophenoxyacetic  acid,  2-butoxyethyl 

ester. 
2,4,5-Triohlorophenoxyacetio  acid,  butoxy- 
polypropyleneglycol  ester. 


HPC. 

DUP. 

DUP. 

DUP. 

RH. 

CIS,  MON,  RH. 

ACY,  USR. 

SF. 

CWN,  LIL,  X. 

DUP. 

ACN. 

DA. 

CIS,  DOW,  FMN. 

CIS,  DOW,  FMN. 

CIS,  DOW,  FMN. 

CIS,  FMN. 

CIS,  FMN. 

LIL. 

GGY. 

SF. 


ARA. 
PPG. 
PPG. 


AMC, 
AMC. 
AMC, 
USR. 
PAS. 

COK,   THM. 
BKL. 

CHC, 
GTH. 
CHC, 

CLY,   RIV. 
DA,   DOW,   HPC, 

MON, 

THM, 

TMH 

DA,  DOW,  HPC,  MR,  MON,  RIV. 

MON. 

AMC,  CHC,  DA,  DOW,  HPC,  RIV,  TMH. 


HPC. 
DOW,  MON,  RIV. 
CHC,  DA,  DOW,  HPC,  MON. 
RIV. 


DOW,  HPC,  MON,  THM. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Pesticides  and  related  products  for  which  U.S.  production  or  sales 
by  manufacturer,  1966 — Continued 


reported,  identified 


Chemical 

Manufacturers'   identification  codes 

(according  to  list 

in  table  22) 

PESTICIDES  AND  RELATED  PRODUCTS,    CYCLIC— Continued 

•Herbicides  and  plant  hormones- -Continued 

Phenoxyacetic  acid  derlvatives--Continued 

»2,'l,5-Trichlorophenoxyacetic  acid  esters  and 

salts— Continued 

»2,4,5-Trichlorophenoxyaoetlo  acid,  ii-butyl  ester— 

DA, 

DOW, 

HPC,  MON,   RIV. 

2,';,5-Trichlorophenoxyacetlo  acid,   2-ethylhexyl 

DA, 

HPC. 

ester. 

»2,'i,5-Triohlorophenoxyacetlc  acid,   iso-octyl  ester- 

DOW, 

MON, 

RIV.TMH. 

2,'i,5-Trichlorophenoxyacetio  acid,   triethyl  amine 

DOW, 

HPC, 

RIV. 

salt. 

itpV,„„„i__T,n,iT^    ftr-fi+n  +  p     CPMA'^ -_-- - 

BKM, 

CLY, 

MRK,   TRO,  WRC. 

■*rnenyjjnercury  ace  Late    v^wm.; — 

Polychloro-tetrahydro-methanoindene   ( Polychlorodi- 

VEL. 

cyclopentadiene)    isomers. 

N  m  Tolyl  phthalamic  acid - -- - 

USR. 

2-(2,'i,5-Trichlorophenoxy)propionic  acid   (Silvex) 

DOW, 

HPC 

2-{2,'i,5-Trichlorophenoxy)propionic  acid,   2-ethylhexyl 

HPC. 

ester. 

2-(2,'l,5-Trichlorophenoxy)propionic  acid,   isooctyl 

RIV. 

ester. 

y. ,  a,o<-Trif  luoro-2 , 6-dinltro-N,  N-dipropyl-p-toluidine 

LIL. 

(Trifluralin). 

Tris-(2,';-dichlorophenoxyethyl)phosphite  (2,4-DEP) 

USR. 

Insect  attractants:     tert-Butyl  4(or  5)-chloro-2- 

TBK. 

methylcyclohexanecarboxylate    (Trimedlure) . 

•Insecticides: 

AT  lii+ViT'T  Ti     (■qTIt/I     hnT«nlr\ff    r\f^    C^T\e>yA-n    T\ 

BPC. 

AJ.iexnrin  vaiiyi  nomoiog  oi   uinerin  i; — 

ore. 

X. 

j-sec-iUnyipnenyi-N-meTinyicarDajnaue ------ 

Benzyl  thiocyanate 

HK. 

2-sec-Butyl-^ ,  6-dinitrophenyl-3 ,3-dijiietliylacrylate 

FMJ, 

fMP 

(Binapacryl) . 

Chlorinated  insecticides: 

•Aldrin-toxaphene  group: 

Heptachloro-tetrahydro-endo-methanoindene 

VEL. 

(Heptachlor). 

Hexachloro-epoxy-octahydro-endo-endo-di- 

SHC, 

VEL 

methanonaphthalene   ( Endrin ) . 

Hexaohloro-epoxy-octahydro-endo-exo-di- 

SHC. 

methanonaphthalene   (Dleldrin) . 

Hexachloro-hexahydro-endo-exo-dimethanonaphthalene- 

SHC. 

(Aldrin). 

Octaohloro-hexahydro-methanoindene  (Chlordan) 

VEL. 
HN. 

Terpene  polychlorlnates — 

Trtvnr\hon»     ^  Phi  (-lT•^  nn+AH     /^ftrnnh^mo  ^ - 

HPC. 

loxapnene    ^uniorinatea  cainpnene  ; 

2,2-Bis(p-chlorophenyl)-l,l-dichloroethane(DDD)   (TDE) 

ACN, 

RH. 

l,l-Bis(p-ohlorophenyl)-2-nitrobutane 

CCM. 

CM. 

»o.-Bls(p-chlorophenyl)  p,  p,p-trlchloroethane   (DDT) 

ACN, 

DA, 

LEB,  MTO,   OMC. 

2-(p-tert-Butylphenoxy)isopropyl-2'-ohloroethyl 

USR. 

sulfite. 

2-(2-{p-tert-Butylphenoxy)-l-methylethoxy)-l- 

USR. 

methylethyl-2-chloroethyl  sulfite. 

Chlorobenzilate - - — 

GGY. 

p-Chlorophenyl  p-chlorobenzenesulfonate   (Ovex) 

AMP, 

CIS 

DOW. 

r\    rhl  m.r.r^hf.nvT     M   mfi+hvl  f^ofhomnt p - 

OTC. 

o-uni-oropnenyi-M-meT/nyxcaruamaut: 

p-Chlorophenyl  2,'i,5-trichlorophenyl  sulfone 

FMN. 

(Tetradifon). 

Deoachlorooctahydro-l,3,4-metheno-2H-cyclobuta   [cd] 

NAC. 

pentalene-2-one . 

l,l-Dlchloro-2,2-bis(p-ethylphenyl)ethane 

RH. 

'l,4'-Dichloro-a-trlohloromethylbenzhydrol  (Dicofol) — 

RH. 

Dodecachlorooctahydro-l,3,'i-metheno-2H-cyclobuta  [  cd  ] 

NAC. 

pentalene   (Mirex). 

»Hexachlorocyolohexane   (Benzene  hexachlorlde)    (BHC)  — 

DA, 

HK,   PPG. 

»Hexachlorocyclohexane,     100*   y-lsomer   (Lindane)- 

HK. 

Hexaohloro-hexahydro-methano-benzodioxathlepine 

HK. 

3-oxide   (Endosulfan) . 

1,1, l-Trichloro-2 , 2-bis ( p-methoxyphenyl ) ethane 

CHT, 

DUP 

(Methoxychlor). 

N,N-Diethyl-iii-toluamide    (DEET) - 

HPC, 

PFZ 

MGK. 
CIS, 

ui-n-propyi  isocxncnomeronate — ---- — ------ 

HPC 

Isobomyl  thiocyanoacetate — —------———--- 

2-Methyl-2- (methyl thlo)proplonaldehyde  0-methyl- 

UCC. 

carbamoyl  oxlme. 

1-Naphthyl  N-methylcarbamate   (Carbaryl) 

ucc. 

PESTICIDES  AND  RELATED  PRODUCTS 


TABLE  20B. --Pesticides  and  related  products  for  which  U.S.  production  or  sales  were  reported,  identified 
by  manufacturer,  i 966— Continued 


Chemical 

Manufacturer^ 

'  identification  codes 

(according 

to  list  in  table  22) 

PESTICIDES  AND  RELATED  PRODUCTS,  CYCLIC-Contlnued 

"Insecticides— Continued 

»Organcphosphorus  insecticides; 

A-tert-Butyl-2-chlorophenyl  methyl  methylphos- 

DOW. 

phoramidite. 

S-[[(p-Chlorophenyl)thio]methyl]  0,0-diethyl 

SF. 

phosphorodithioate  (Carbophenothion) . 

0,0-Diethyl  0-3-chloro-<;-methyl-l-oxo-2H-l- 

CHG. 

benzopyran-7-yl  phosphorothioate  (Coumaphos). 

Diethyl-l-(2,4-dichlorophenyl)-2-chlorovinyl 

SHC. 

phosphate. 

0,0-Diethyl  0-(2-isopropyl-";-methyl-6-pyrimdinyl) 

GGY. 

phosphorothioate  ( Diazlnon ) . 

0,0-Diethyl  0-p-{methylsulfinyl)phenyl  phos- 

CHG. 

phorothioate  . 

»0,0-Diethyl  O-p-nitrophenyl  phosphorothioate 

AMP, 

MDN, 

SF,  SHC. 

(Parathion). 

0,0-Dijiiethyl  S-(p-ohlorophenylthlo)methyl  phos- 

SF. 

phorodithioate. 

0, 0-Dlmethyl  0-  [i-  (methylthio)  -m-tolyl]  phos- 

CHG. 

phorothioate  (Fenthion). 

»0,0-Dijnethyl  0-p-nltrophenyl  phosphorothioate 

AMP, 

MON, 

SF,  SHC. 

(Methyl  parathion) . 

0,0-Dimethyl  S-[4-oxo-l,2,3-benzotriazin-3(4H)- 

CHG. 

ylmethyl]  phosphorodithioate. 

0,0-Dimethyl  S-phthalimidomethyl  phosphorodithioate- 

SF. 

Dimethyl  2,<;,5-triohlorophenyl  phosphorothionate 

DOW. 

(Ronnel). 

2,3-p-Dioxane  S,S-bis(0,0-diethylphosphorodithioate) 

HPC. 

(Dioxathion) . 

O-Ethyl  O-p-nitrophenyl  phenylphosphonothioate  (EPN) 

SF. 

a-Methylbenzyl  3-(dtmethoxyphosphinyloxy)-cis- 

SHC. 

crotonate. 

0,0,0',0'-Tetramethyl  Q,0'-Thiodi-p-phenylene 

ACY. 

phosphorothioate. 

All  other  organophosphorus  insecticides 

SF. 

Nematocides: 

0,0-Diethyl  0-(2,4-diohlorophenyl)  phosphorothioate— 

SM. 

0,0-Diethyl  0-2-pyrazinyl  phosphorothioate  (Thionazin) 

ACY. 

»Rodenticides: 

3-(a-Acetonylben2yl)^-hydroxycoumarin  (Warfarin) 

MOT, 

PEN. 

2-Plvaloyl-l,3-indandione  (Pindone) 

MOT, 

PIC. 

Other  rodenticides— - - - - - --- 

AKC, 

NES. 

Synergists: 

a-[2-(2-n-Butoxyethoxy)-ethoxy]^,5-methylenedioxy-2- 

FMN, 

FMP. 

propyltoluene  (Piperonyl  butoxide) . 

N-(2-Ethylhexyl)bicyclo(2.2.1)-5-heptene-2,3- 

M3K. 

dlcarboximide. 

Other  synergists --- 

CTN. 

PESTICIDES  AND  RELATED  PRODUCTS,  ACYCLIC 

»Fungicides: 

3^g_2^  ^-bromoacetoxy-2-butene— — - -— 

VIN. 
MAL. 

Cadmium  succinate 

l-Chloro-2-nitropropane  (Korax) 

FMN, 

FMP. 

rVfBrvUnm  pvnnnHI  thi  ^^^In^  HnnoT'hnnoto 

BKM. 

L/iHoaium  cyanuQi  LnaoimiaucarDonaT>e — -- 

Dlthiocarbamic  acid  fungicides: 

»Dimethyldithiocarbamio  acid,  ferric  salt  (Ferbam)-- 

DUP, 

FMN, 

RBC,  WRC. 

Dimethyldithiocarbamic  acid,  manganese  salt 

FMN. 

Ethylene  bis( dlthiocarbamic  acid),  dlammonium  salt— 

CIS, 

RBC. 

'Ethylene  bis(dithiocarbamic  acid),  disodium  salt 

CIS, 

DUP, 

FMN,  RH. 

(Nabam). 

Ethylene  bls(dithiocarbainio  acid),  manganese  salt 

CIS, 

DUP, 

RH. 

(Maneb) . 

-Ethylene  bis(dithiocarbamic  acid),  zinc  salt 

CIS, 

DUP, 

FMN,  RH. 

(Zineb). 

Polyethylenethiuram  disulfide  (PETD) 

FMN. 

Other  dlthiocarbamic  acid  fungicides 

VNC. 
ACY. 

n-Dodecyl^uanldine  acetate  (Dodine)— - -_-— 

Mercury  fungicides: 

TRO. 

Ethylmercuric  chloride---------- ----------- .. 

DUP. 
DUP. 

Ethylmercuric  phosphate 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  20B. 


-Pesticides  and  related  products  for  which  U.S.  production  or  sales  were  reported,  identified 
by  manufacturer,  i  566— Continued 


Manufacturers '   identification  codes 
(according  to  list  in  table  22) 


PESTICIDES  AND  RELATED  PRODUCTS,   ACYCLIC— Continued 

»Fungicides--Continued 

Mercury  fungicides — Continued 

3-Methyl(mercurithio)-l,2-propanediol 

Methylmercuric  acetate 

Methylmercuric  hydroxide 

All  other  acyclic   fungicides: 

Dimethyl  thiocarbonyl  disulfide 

2-Propene-l, 1-dlol  diacetate 

Other- - 

^Herbicides  and  plant  hormones: 

Cacodylic  acid 

2-Chloroallyl  diethyldithiocarbamate  (CDEC) 

2-Chloro-N,N-diallylaoetamide  (CDAA) 

2,3-Dlchloroallyl  diisopropylthiolcarbamate  (Diallate) 

2,2-Dichloroproplonic  acid,  sodium  salt  (Dalapon) 

N-Dlmethylamlno  succlnamic  acid 

S-Ethyl  dl-N,N-propylthiocarbamate  (EPTC) 

Ethyl  xanthogen  disulfide 

Methanearsonic  acid,  dlsodium  salt  (DSMA) 

Methanearsonic  acid,  dodecyl-  and  octylaramonium  salts- 
Methane  arsonlc  acid,  sodium  salt  (M3MA) 

S-Propyl  butylethylthiooarbamate  (Pebulate) 

S-Propyl  dipropylthlocarbamate  (Vemolate) 

S,S,S-Trlbutyl  phosphorotrithioate 

Tributyl  phosphorotrithioate 

Trichloroacetic  acid,  sodium  salt  (TCA) 

S-2,3,3-Trichloroallyl  N,N-diisopropylthiolcarbamate 
(Tri-allate). 
"Insecticides: 

2-(2-Butoxyethoxy)ethyl  thiocyanate 

Butoxy  polypropylene  glycol 

Metaldehyde 

»Organophosphorus  insecticides: 

S-[l,2-Bis(ethoxycarbonyl) ethyl]  0,0-dimethyl 
phosphorodlthioate  (Malathion) . 

2-Carbomethoxy-l-propen-2yl  dimethyl  phosphate 

l,2-Dibromo-2,2-dichloroethyl  dimethyl  phosphate 

(Naled). 
0,0-Diethyl  S-2-(ethylthlo) ethyl  phosphorodlthioate 

(Disulfoton) . 
0,0-Diethyl  0-2-(ethylthio)ethyl  phosphorothloate 

(Demeton  0) . 
0,0-Dlethyl  S-2-(ethylthio)ethyl  phosphorothloate 

(Demeton  S). 
0,0-Diethyl  S-(ethylthlo)methyl  phosphorodlthioate 

(Phorate). 
3-(Dimethoxyphosphinyloxy)-N,N-dlmethyl-cis- 

orotonamlde . 
0,0-Dimethy  1-0-2, 2-dichlorovinyl  phosphate  (DDVP)  — 
0,0-Dimethyl  S-(N-methyloarbamDylmethyl)  phos- 
phorodlthioate (Dimethoate). 
Dimethyl  phosphate  of  3-hydroxy-N-methyl-cls- 

crotonamide . 
S-t2-(Ethylsulflnyl)ethyl]  0,0-dimethyl  phos- 
phorodlthioate (Oxydemetonmethyl) . 
0,0,0',0'-Tetraethyl  S,S' -methylene  bls-phos- 
phorodithioate  (Ethion). 

"Tetraethyl  pyrophosphate  (TEPP) 

Tetra-n-propyl  dithlopyrophosphate 

2-Thlocyanoethyl  dodecanoate 

Other  acyclic  insecticides 

»Rodentioldes :  Sodium  fluoracetate 

»Soil  conditioners:  Polyaorylonltrile,  hydrolyzed, 
sodium  salt. 


DUP 
DUP. 

MRT. 

CLY. 
SHC. 
BFG. 

ASL. 

MDN. 

MON. 

MON. 

DOW. 

USR. 

SF. 

RBC. 

ASL,  CLY. 

CLY,  VIN. 

VIN. 

SF. 


CHG. 

CHG. 

CHG. 

ACY. 

SHC. 

SHC. 
ACY. 

SHC. 

CHG. 

FMN,  FMP. 

ALC,  AMP,  OTH. 

SF. 

RH. 

HK,  x. 


PESTICIDES  AND  RELATED  PRODUCTS 


TABLE  20B. 


-Pesticides  and  related  products  for  which  U.S.  production  or  sales  were  reported,  identified 
by  manufacturer,  i 966— Continued 


PESTICIDES  AND  RELATED  PRODUCTS,  ACYCLIC—Continued 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


»Soil  fumigants: 

2-Anilnobutane  carbonate 

»l,2-Dibromo-3-chloropropane  (DBCP) 

1,3-Dichloropropene 

1,3-Diohloropropene,  1,2-dichloropropane 

»Methyl  bromide  ( Bromomethane ) 

N-Methyldithlocarbamic  acid,  sodium  salt  (Metham)- 

Trichloronitromethane  (Chloropiorin) 

All  other  soil  fumigants 


LIL. 

AMP,  EST,  DOW,  SHC. 

DOW. 

DOW,  SHC. 

AMP,  DOW,  FRO,  GIL,  MCH. 

DUP,  SF. 

DOW,  mc. 

SF. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 
Miscellaneous  Chemicals 


TABLE  21B.  --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 

Miscellaneous  chemicals  for  which  separate  statistics  are  given  in  table  21A  are  marked  with  an  asterisk   (»); 
chemicals  not  so  marked  do  not  appear  in  table  21A  because  the  reported  data  are  accepted  in  confidence  and  may  not 
be  published.  Manufacturers'    identification  codes  shown  below  are  taken  from  table  22.   An  x  signifies  that  the 
manufacturer  did  not  consent  to  his  identification  with  the  designated  product] 

Manufacturers'   identification  codes 
(according  to  list  in  table  22) 

MISCELLANEOUS  CHIMICALS,    CYCLIC 


6-Acetoxy-2,4-dimethyl-m-dioxane 

Adenosine  phosphates 

2-Aminobenzothiazole 

S-Amino-'ije-dimeroapto-ljSjS-triazine 

l-(2-Aminoethyl)piperazine 

l-(3-Aminopropyl)morpholine 

Anisaldehyde  bisulfite — 

Arylalkyl  phosphites - 

Barium  octylphenate 

Benzoic  acid  salts: 

Aluminum  benzoate 

Cobalt  benzoate 

»Sodiu]n  benzoate,    tech 

»Sodium  benzoate,   U.S.P 

p-Benzoquinone   (p-(Jiinone) 

Benzothiazole 

*Benzoyl  peroxide 

Biological   stains 

Bis(2,<i-dichlorobenzoyl)  peroxide 

2,'i-Bis(4-hydroxy-3,5-di-tert-butyl-phenoxy)-6-(n-octyl- 
thio)-l,3,5-triazine. 

Bis(2-hydroxypropoxyphenyl)methane 

2,4-Bis(n-octylthio)-6-('i'-hydroxy-3',5'-di-tert-butyl- 
anilino)-l,3,5-trlazine. 

Boron  fluoride -phenol  complex 

*Butyl  benzoate 

p-tert-Butylbenzoic  acid,  barium  bis-salt 

n-Butylferrocene 

2 (and  3)-tert-Butyl-'i-methoxyphenol 

p-tert-Butyl-a-methylcinnamaldehyde 

tert-Butyl  peroxybenzoate 

4-tert-Butylphenyl  salicylate 

4-tert-Butylpyrocatechol 

Camphene 

Cellulose  acetate  phthalate 

Centralite-1  (N,  N'-Diethyl-N,N'-diphenylurea) 

Chemical  indicators 

Chemical  reagents 

Chloramine  B  (Sodium  derivative  of  N-ohlorobenzene  sul- 
fonamide ) . 

Chlorinated  terphenyls 

2-Chloroacetophenone 

l-(3-Chloroallyl)-3,5,7-triaza-l-azon  iaadamantane  chlo- 
ride. 

(o-Chlorobenzylidene)malononltrile 

5-Chloro-2-hydroxybenzophenone 

Chlorophyllin,  sodium -potassium-copper 

Cobalt  phthalocyaninedisulfonic  acid 

Cumene  hydroperoxide 

Cyclohexanone  peroxide 

Cyolohexene-l,2-dlcarboxylic  acid  ( Tetrahydrophthalio 
acid)  disubstituted,  polyester  salts:  Barium  and 
cadmium  salts. 

1,'i-Cyolohexylenedimethanol 

♦Cyclopropane 

Cytldlne  and  derivatives 

Decahydronaphthalene  (Deoalin) 

Decyl  diphenyl  phosphite 

Dehydroacetic  acid,  and  sodium  salt 

2,5-Di-tert-amylhydroquinone 

Dlazodinltrophenol 


ACY. 
JCC. 
JCC. 
GIV. 
WES. 
CCA. 


HK,  HN,  MON,  PFZ,  VEL. 

EKT. 

ACY. 

A2T, 

HLC, 

CAD. 

GGY. 


ACQ. 
FRO, 
CCA. 
ARA. 
EKT. 
GIV. 
WTL. 
DCW. 
BKL, 
GLD, 


OTC, 
EK, 
ACG, 
NES. 

KPS. 

GAM. 
DOW. 


KCH. 


PAS. 
HLC,  LAM,  NAC. 
CLB,  EK,  GFS,  HLC,  LAM,  NAC,  PIC. 


NAC. 

HPG,  RCI. 
CAD,  WTL. 
RCI. 


EKT. 

MAL,  OH,  QMS,  TAE. 

PIB. 

DUP. 


GAN. 
EKT. 
HPC. 


MISCELLANEOUS  CHEMICALS 


TABLE  21B.  --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  7 566 --Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,    CYCUC--Continued 

2,4-Dibenzoylresorcinol 

l,3-Dibromo-5,5-dimethylhydantoin 

2,6-Di-tert-butyl-p-cresol: 

*Food  grade 

»Tech 

Di-n-butylferrocene 

2,5-Di-tert-butylhydroqulnone 

Dl-tert-butyl  peroxyphthalate 

2,^-Dichlorobenzoyl  peroxide 

l,3-Dichloro-5,5-dlmethylhydantoln 

Dichloro-s-triazine-2,<i,6(lH,3H,5H)trione   (Dlchloroiso- 
cyanuric  acid),   potassium  and  sodium  salts. 

Dicyclohexylammoniuni  nitrite 

Didecyl  phenyl  phosphite 

N,  N-Diethyl-p-phenylenediamine 

Digitonin -- 

2,5-Dihydroxybenzenesulfonic  acid 

2,2'-Dlhydroxy-'i,'V'  -dlmethoxybenzophenone 

2,6-Dihydroxylsonlcotinic  acid  (2,6-Dihydroxy-A-carboxy- 
pyridine). 

2,2' -Dihydroxy-A -methoxybenzophenone 

2,2'-Dihydroxy-4-(octadecyloxy)benzophenone 

3,5-Diiodosalicylic  acid 

Diisopropylbenzene  hydroperoxide 

Diisopropyl-m,p-cresols 

»p-Dimethoxybenzene  (Dimethyl  ether  of  hydroquinone ) 

a,a-Dimethylbenzyl  hydroperoxide 

2,5-Dimethyl-2,5-dl(peroxyphenyl)hexane 

2,5-Dlmethylhexane-2,5-diperoxybenzoate 

2,6-Dimethylmorpholine 

4,4^-Dinitrocarbanilide-'4,6-dimethyl-2-pyTimidinol 

Dl-n-ootadecyl  3,5-di-tert-butyl-'i-hydroxyphenyl  phospho 
nate. 

Dioxane  (1,4-Diethylene  oxide) 

2,5-Diphenyl-p-benzoquinone 

Dithioaramilide,  monoethanolamine  salt 

4-(Dodecyloxy)-2-hydroxybenzophenone 

Enzymes : 
Ifydrolytio : 

Amylases 

Proteases 

Other 

Nonhydrolytic 

l,2-Iiioxy-3-phenoxypropane  (Glycidyl  phenyl  ether) 

6-Ethoxy-m-anol  ( Propenylmethylguaethol ) 

Ethyl  cellulose  phthalate 

2-Bthylhexyl  octylphenyl  phosphite 

Ethyl  hydrocaffeate 

<^-Ethylmorpholine 

Ferrocene 

•Flotation  reagents : 

Dicresylphosphorodlthioic  acid  (Dicresylthiophosphorio 
acid). 

Dicresylphosphorodlthioic  acid,  ammonium  salt 

Dicresylphosphorodlthioic  acid,  sodium  salt 

2, 2' -Dimethyl thiocarbanillde  (Dl-o-tolyl thiourea) 

Rosin  amines 

Thiocarbanillde  (Diphenyl thiourea) 

Fluorinated  benzenoid  chemicals 

Furan  derivatives : 

2-F\iTaldehyde  (Furfural) 

Tetrahydrofurfuryl  alcohol 

Gallic  acid - 

•Gasoline  additives : 

N,N'-Bis{l,<l-dimethylpentyl)-p-phenylenediamine 

2,6-Di-tert-butylphenol 

N,N-Di-sec -butyl -o-phenylenedlamine 

»N,N'-Di-sec-butyl-p-phenylenedlamine 

N, N'-Dlisopropyl-p-phenylenediamine 


CAT,    EKT,    HPC,    KPT,    SHC. 

CAT,    EKT,    HPC,    KPT,    PRD,    SHC. 

ARA. 

EKT. 

WTL. 

WTL. 

GLY. 

MON. 


ACY. 

MET. 

HPC. 

GIV. 

ASL, 

EKT,    GAF, 

ICO,    TBK. 

ACP. 

WTL. 

UPR. 

DOW. 

MRK. 

GGY. 

DOW, 

UCC. 

EKT. 

ACY. 

DUP, 

EKT. 

BAX, 

CRN,    QMS, 

PMP,    RH,    WBC 

BAX, 

PFZ,    PMP, 

RH,    WBC. 

MLS, 

RH,    WBC. 

PLB, 

WBC. 

SHC. 

ICO. 

EK. 

X. 

ICO. 

JCC, 

UCC. 

ARA. 

ACY. 

ACY. 

KCU. 

DUP. 

RBC. 

HPC. 

ACY, 

MAC. 

PIC. 

QKO. 

QKO. 

MAL. 

EKT. 

SHC, 

TNA. 

DUP, 

EKT. 

DUP, 

EKT,    UPM. 

DUP, 

EKT. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


■  -Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i 566 --Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


MISCELLANEOUS  CIQMICAI^,    CYCLIC— Continued 

•Gasoline  additives— Continued 

»N,N'-Dlsalicylidene-l,2-propanediamine 

Methylcyclopentadienylmanganese  tricarbonyl 

'i,^'-Methylenebis(2,6-di-tert-butylphenol) ■ 

2,2'-Thiobis[6-tert-butyl-<;-methylphenol] ■ 

Glyceryl  p-aminobenzoate 

Glyceryl  tribenzoate 

Guanosine  phosphates 

5,6,7,8,9,9-Hexachloro-l,2,3,4,Aa,5,8,8a-ootahydro-5,8- 
methano-2,3-naphthalic   anhydride   (Cloran). 

*Hexamethylenetetrainine,    tech 

o-(2-Ifydroxy-p-anisoyl )benzoic   acid 

N-(2-Hydroxyethyl)gentisamlde 

2-Ifydroxy-A-methoxybenzophenone 

2-Ifydroxy-'4-methoxy-5-sulfobenzophenone  trihydrate 

2-(2'-Hydroxy-5'-inethylphenyl)benzotriazole 

2-itfdroxy-^-n-octoxybenzophenone 

Hydroxyphenylbenzotriazole  derivative 

2-(2-ffydroxyphenyl)-<i(3)-qUinazolone 

1-Ifydroxy -2 -pyridine  (Onadine) 

2-Imidazolidinethlone  (1,3 -Ethylene -2 -thiourea)--- --- 

Inosine  and  phosphates 

lEoamyl  p-dimethylaminobenzoate 

Isooyanuric  acid 

Isophorone 

Isopropyl-o-cresol 

p-Isopropyl-a-methylcinnamaldehyde 

Isopropylmorpholine 

Ketene,  dimer 

♦Lubricating  oil  and  grease  additives: 

Chlorosulfurized  and  sulfurized  compounds : 

Liquid  disulfide — 

Tall  oil  ester,  sulfurized 

Terpenes,  sulfurized 

All  other 

Oil-soluble  petroleum  sulfonates: 

Oil-soluble  petroleum  sulfonate,  ammonium  salt 

•Oil-soluble  petroleum  sulfonate,  barium  salt 

•Oil -soluble  petroleum  sulfonate,  calcium  salt 

•Oil-soluble  petroleum  sulfonate,  sodium  salt 

All  other 

Phenol  salts : 

Barium  salt  of  dodecylphenol 

Barium  salt  of  nonylphenol 

Calcium  salt  of  octylphenol-fonnaldehyde 

Calcium  salt  of  polypropylphenol 

All  other  phenol  salts 

All  other - - — 

Waleic  anhydride  half  esters,  vinyl  ether  copolymers 

p-Menthane 

8-p-Menthyl  hydroperoxide 

p-Methoxybenzylldenemalonlc  acid,  dimethyl  ester 

4-Methoxyphenol 

2-Kfethylazlridine 

2,2' -Methylenebis[  i-chlorophenol  ]  (Dlchlorophene  ) 

Methylenebis[5,5-dlmethylhydantoin]--- 

2,2'-Methylenebls  [3,'i,6-trlchlorophenol]  (Hexachlor 
2,2' -Me thylendi -p-cresol  (Bis ( 5 -methyl-2-hydroxyphenyl ) - 
methane ) . 

Methyl  gallate - - -- 

Methylglucoslde- - -- - 

'i-Methylmorpholine 

5-Methyl-5-norbomene-2,3-dlcarboxyllo  anhydride  (Methyl- 
bioyolo(2 .2.1] hept-5-ene-2, 3-dloarboxyllc  anhydride ) . 

Methyl  phenyl  phosphates 

l-Methyl-2-pyrrolldone,  monomer 

Methyl  triphenyl  phosphonium  bromide 

Methyl  vinyl  ether-toluene  polymer 

Methyl  vinyl  ether-xylene  polymer 


DUP,  EKT,  TX,  UFM,  X. 

TNA. 

ENJ,  SHC,  TNA. 

CAT. 

VND. 
VEL. 
PLB. 
WSN. 

BOR,  DUP,  HKD,  HMP,  HN,  PIS,    UCC. 

ACY. 

ICO. 

ACY,  GAF. 

ACY. 

GGY. 

ACY. 

GGY. 

QMC. 
PAS. 
PIB. 
VND. 
MON. 
UCC. 


SIN. 

CO,  LUB,  TX,  X. 

CO,  ENJ,  LUB,  ORO,  SHO,  SON,  TX. 

CO,  ENJ,  MOR,  NOP,  PAH,  SHO,  SOC,  SOI,  SON,  TX. 

CO. 

TX. 
CCA. 
SHC. 
ORO. 


ENJ, 
GAF. 
HPC. 
HNW, 
ACY. 
ASL, 
ICO. 
GIV. 
GLY. 
GIV. 
GIV. 


CRN. 

JCC,  UCC. 
ICO. 

TNA. 
GAF. 
ALD. 
OAF. 
GAF. 


LUB,  MON, 
LUB,  MON, 


MISCELLANEOUS  CHEMICALS 


TABLE  21B.  — Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  966— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


mSCELUmWS  chemicals,   cyclic— continued 

»Morpholine 

Morpholine  salt  of  p-toluenesulfonic  acid 

»Napthenic  acid  salts : 

Aluminum  naphthenate 

Barium  naphthenate 

Cadmium  naphthenate 

*Calcium  naphthenate 

Cobalt  lead  manganese  naphthenate 

♦Cobalt  naphthenate 

»Iron  naphthenate 

Lead  manganese  naphthenate 

»Lead  naphthenate 

Lithium  naphthenate 

♦Manganese  naphthenate 

Nickel  naphthenate 

Rare'  earths  naphthenate 

Sodium  naphthenate 

Strontium  naphthenate 

♦Zinc  naphthenate 

o-Nltrobenzoic  acid  and  sodium  salt 

Norbomane-2-methanol  (Bloyolo(2,2, 1 ) -heptane -2 -methanol ) - 
5-Norbomen-2-ylmethyl  acrylate  ( Bicylo[ 2.2.1  ]-hept-5- 
ene-2-methylol  acrylate). 

l-0ctad€cenyl-2-naphthenyltetrahydropyTimidine 

Octadecyl  3 - ( 3 , 5 -di -tert-butyl -4 -hydroxyphenyl ) -propionate 

Octylphenol  cyclotetrasiloxane 

Organic  mercury  compounds: 

Phenyl  mercuric  borate 

Other - - - 

1,10-Phenanthroline 

p-Phenolsulfonic  acid 

Phenolthiosulfonic  acid 

2-Phenoxyethanol  (Ethylene  glycol  monophenyl  ether) 

2-(2-Rienoxyethoxy)ethanol  (Diethylene  glycol  phenyl 
ether). 

2,2'-(p-Phenylene)diethanol 

Phenyl  hydrogen  phosphate 

5-Phosphonylribose  l-pyrophosphate 

Photographic  chemicals : 

N-(o-Acetamidophenethyl)-l-hydroxy-2-naphthamide 

2-(4.-Amino-N-ethyl-m-toluidino)ethanol 

♦Benzotrlazole 

p-Benzylnmi  nophenol  hydrochloride 

Catechol  ( Pyrooatechln ) 

3-Chloro-A-dlethylamlnobenzenediazonlum  chloride  (p- 
Diazo-2-chloro-N,N-diethylanlline)  -  zinc  chloride. 

Chlorohydroquinone 

2, A-Dinmi nophenol  dihydrochloride  (Amidol) 

2[N-(2,'V-Dl-tert-araylphenoxyaoetyl)  amldo]-^,6-dichloro- 

5-methylphenol . 
2, 5-Dlbutoxy-A-morpholinobenzenedlazonium  chlorozlncate- 

4-Diazo-l-morphollnobenzene 

*2, 5-Dlethoxy-4-morpholinobenzenedlazonlum  ohlorozincate- 
*p-Diethylamlnobenzenediazonlum  chloride  (p-Diazo-N,N- 
dlethylanlline)  -  zinc  chloride. 
p-Dlethylaminobenzenediazonlum  (p-Dlazo-N,N-diethyl- 
aniline)  fluoroborate. 

N,N-Dlethyl-p-phenylenediamlne  hydrochloride 

»N, N-Diethyltoluene-2,5-diamlne,  monohydroohlorlde 

2,5-Dlhydroxybenzenesulfonlc  acid 

2,7-Dlliydroxy-3,6-naphthalene  sulfonate 

p-Wmethylaminobenzenedlazonlum  chloride  (p-Dlazo-N,N- 

dtmethylanlllne )  -  zinc  chloride. 
4- (2 ' , 6 ' -Dlmethylmorphollnyl )benzenediazonium  chloride  - 
zinc  chloride. 


HSH,  WTC. 

CCA. 

CCA. 

CCA,  CCC,  FER,  HNX,  HSH,  MCI,  MID,  SHP,  SOC,  SRR,  SW, 

TRO,  WTC,  X,  X. 
HNX,  HSH. 
CCA,  CCC,  FER,  HNX,  HSH,  MCI,  MID,  MON,  SHP,  SOC,  SRR, 

SW,  TRO,  WTC,  X,  X. 
CCA,  CCC,  HNX,  HSH,  MCI,  MID,  SOC,  WTC. 
CCA. 
CCA,  CCC,  CCW,  FER,  HNX,  HSH,  MCI,  MID,  SHP,  SOC,  SRR, 

SW,  TRO,  WTC,  X,  X. 
CCA. 
CCA,  CCC,  FER,  HNX,  HSH,  MID,  SHP,  SOC,  SRR,  SW,  TRO, 

WTC,  X. 
CCA. 

CCA,  HNX. 
CCA. 
CCA. 
CCA,  CCC,  FER,  HNX,  HSH,  MCI,  MID,  SHP,  SOC,  SRR,  SW, 

TRO,  WTC. 
WAY. 
ICO. 
ICO. 


GAF. 

DOW,  JCC. 
DOW. 


EKT. 

EKT. 

EK, 

FMT, 

UEE, 

MRT. 

EK. 

KPT. 

FMT, 

IDC. 

EK. 

VPC. 

IDC. 

ESA, 

Fwr, 

IDC. 

PMT. 

ESA, 

Fvr, 

GAF, 

IDC 

JMT, 

OAF, 

IDC, 

MRT 

IDC. 

EKT, 

FMT. 

EKT, 

FMT, 

mc. 

EK. 

FMT. 

mr, 

IDC. 

172 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  21B.  --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i  566- -Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


MISCELLANEOUS  CHBGCALS,   CYCLIC— Continued 

Photographic  chemicals— Continued 

p-Diphenylaminediazonium  sulfate 

p-(N-Ethylbenziiiiido)benzenediazonium  chloride   (p-Diazo- 

N-benzyl-N-ethylaniline)   -  zinc  chloride, 
p- rEthyl(2-hydroxyethyl)amlno]benzenediazonium  chloride 
(p-Diazo-N-ethyl-N-hydroxyethylaniline)   -  zinc 
chloride . 

N-Ethyl-N-hydroxyethyl-p-phenylenediamine  sulfate 

N-Ethyl-N-(|J-methanesulfonamidoethyl)toluene-2,5-dlamine 
sulfate. 

Iftrdroquinone   (Hydroquinol) 

p-  [(2-Hyxiroxyethyl)methylamlno]  benzenediazonium  chloride 
(p-Diazo-N-hydroxyethyl-N-methylaniline)   -  zinc 
chloride. 
l-t^roxy-N-(2-hydroxyethyl)-2-naphthamlde  (2,3-Cixynaph- 
thoic -mono-ethanolamlde ) . 

l-(3-Hirdroxyphenyl)urea '■ 

4-Methoxy-l-naphthol 

p-Methylaminophenol  sulfate  (Metol) 

5-Methylbenzotriazole 

2-Methylbenzoxazole 

4-Methyl-l-phenyl-3-pyrazolidinone 

<i-lfcrpholinylbenzenediazonlum  chloride  -  zinc  chloride 
salt. 

4-Morpholinylbenzenediazoniuin  fluoroborate 

6-Nitrobenz imidazole 

Octylphenyl  salicylate 

Phenyl-5-meroaptotetrazole 

l-Phenyl-3-pyrazolidlnone 

<t-Phenylpyrooatechol 

Polyvinyl  olnnamate 

2-Resorcyllo  monoethanolamide 

4,4' -Thiodiresorcinol  (Diresoroyl  sulfide) 

l-(2,4,6-Trichlorophenyl)-3-(4-nitroanilino)-2-pyraz- 
olin-5-one. 

All  other — - 

Phthallo  acid,  lead  salt,  dibasic 

•Plnene  (a-  and  p-) 

Poly-4-(2-acryloxy  ethoxy)-2-hydroxybenzophenone 

Polyethylene  terephthalate 

•Propyl  gallate 

IVrogallol  (Pyrogallic  acid) 

Resorclnol  monobenzoate 

Rosin  acid  salts: 

Aluminum  reslnate 

Calcium  reslnate 

Cobalt  manganese  reslnate 

Copper  reslnate 

Iron  reslnate 

Lead  reslnate 

Manganese  reslnate 

Zinc  reslnate 

Sallcylanillde,  nonmedlclnal 

Salicylic  acid,  lead  sail- 

Silicones 

Sodium  cresoxide  (Cresyllc  acid,  sodium  salt) 

Sodium  ferric  ethylenediamine  dl-o-hydroxyphenylacetate 

Sucrose  benzoate 

Sulfosalicyllc  acid 

Tall  oil  fatty  acid  chloride — 

»Tall  oil  salts  (linolelc -rosin  acid  salts): 

♦Calcium  tallate 

♦Cobalt  tallate 

Copper  tallate 

Iron  tallate 

lead  manganese  tallate 

»Iead  tallate 

«Uanganese  tallate 

Zinc  tallate - 

Tannic  acid 


PMT, 

IDC. 

EK. 

EK. 

FMT. 

IDC. 

IDC. 

EK, 

M. 

EKT. 

CFC, 

fMT. 

GGY, 

WAY. 

X. 

WAY. 

PVT. 

BKC. 

EKT. 

EK, 

EKT,. 

IDC, 

WAY. 

NTL. 

ABZ, 

CBY, 

OID 

HNW,    HPC. 

ACY. 

DUP, 

EK. 

EKT, 

HN, 

HSH. 

HSH, 

MAL. 

EKT. 

JMS, 

MAL. 

JMS. 

SW. 

JMS. 

JMS. 

HSH, 

JMS. 

JMS. 

JMS. 

,TMS, 

SW. 

DUP, 

FIN, 

MEE 

PCW. 

NTL. 

DCC. 

DEX, 

GOC. 

GOY. 

VEL. 

HON, 

MRK. 

OAF. 

CCA,  CCC,  DYS,  HNX,  HSH,  MCI,  MID,  SHR,  TRO,  WTC. 

CCA,  CCC,  FER,  HNX,  MCI,  MID,  SHP,  SRR,  TRO,  WTC. 

CCA,  MID,  SHP. 

CCA,  MCI,  MID,  SRR,  WTC. 

HSH,  MCI. 

CCA,  CCC,  FER,  HHX,  HSH,  MCI,  MID,  SHP,  SRR,  TRO,  WTC, 

CCA^  CCC,  FER,  HNX.  HSH,  MCI,  MID,  SRR,  TRO,  WTC. 

CCA,  HSH,  MCI. 

HSH,  MAL. 


MISCELLANEOUS  CHEMICALS 


TABLE  21B. 


-Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  7566- -Continued 


Manufacturers'    Identification  codes 
(according  to  list  in  table  22) 


MISCELIANEOUS  CHEMICALS,    CYCUC- -Continued 

»Tanning  materials,   synthetic : 

Ifcrdroxytoluenesulfonic  acid,    formaldehyde  condensate 
(Cresol-formaldehyde  sulfonate),   sodium  salt. 
»2-Naphthalenesulfonic  acid,    formaldehyde  condensate 

and  salts. 
l-Phenol-2-sulfonic   acid,   formaldehyde  condensate 
(Phenol-formaldehyde,   sulfonated). 

1-Phenol-^-sulfonic  acid,    formaldehyde  condensate 

Styrene  maleic  anhydride  interpolymer,  partial  sodium 

salt. 
Sulfonyldiphenolsulfonic  acid,  formaldehyde  condensate — 

All  other— 

Tetra(n-butyl)ammonium  picrate 

3,3',<i,4.'-Tetrachlorophenylurea 

Tetrahydrcmethylthiophene-l,l-dioxide 

IjajSjA-Tetral^dronaphthalene  (Tetralin) - - 

Tetrahydrothiophene 

Tetrahydrothiophene-l,l-dioxide  (Sulfolane) 

Tetralds[ methylene-3-(3 ', 5 '-di-tert-butyl-^ ' -hydroxyphenol ) 
propionate]  methane. 

Tetramethylaminoethylpiperazine 

Tetraphenyltin 

•Textile  chemicals,  other  than  surface-active  agents: 
•l,3-Bis(hydroxymethyl  )-2-imidazolidone  (Dimethylol 
ethylene  urea). 

N',N'-Diphenyl-l,2-propanediamine 

l-[(Octadecyloxy)methyl]  pyridinium  chloride 

Phenol,  sulfurated 

Tetrahydro-3,5-bis(methoxymethyl)^H-l,3,5-oxadiazine-^- 
one  (l,3-Bis(methoxymethyl)uron). 

2,2',i,^'-Tetrahydroxybenzophenone 

All  other - — 

2,2'-Thiobls[4-chlorophenol] 

2,2'-Thiobis['V,6-dichlorophenol] 

[2,2'-Thiobis('i-octylphenolate)]-n-butylamine  nickel— 

Thiophene - 

o-Toluidine  formaldehyde  hydrochloride 

o-Tolylblguanide 

Triaryl  phosphites 

3,'i',5-Tribromosalicylanilide 

3,4',5-Tribromosallcylanilide  and  dibromosalicylanilide 
mixtures. 

3,'i,<i'-Triohlorocarbanilide 

Trichloromelamlne 

l,3,5-Trichloro-s-trlazine-2,4,6(lH,3H,5H)trione  (Tri- 
ohlorolsocyanuric  acid). 

Tri-(m,p)-cre8yl  borate 

3-Trifluoromethyl-4.,';'-diohlorooarbonalide 

a,a,a-Trlfluoro-p-toluidlne   (p-Aminobenzotrifluoride) 

2,'i,6-Trinitroresorcinol,   lead  derivative 

s-Trioxane 

Triphenylphosphine ^ 

Trlphenyl  phosphite 

Triphenyltin  acetate 

Triphenyltln  chloride 

Trls(l-aziridinyl)phosphine  oxide 

Uridine  derivatives 

l-Viiiyl-2-pyrrolidlnone,  monomer  and  polymer 

l-Vinyl-2-pyrrolidinone  -  acrylamide  copolymer 

l-Vlnyl-2-pyrrolidinone  -  ethyl  -  acrylamide  copolymer 

l-Vinyl-2-pyrrolidinone  -  vinyl  acetate  copolymer 

MISCELIANEOUS  CHMICALS,  ACYCLIC 


»Cellulo8e  esters: 

•Celluloae  acetate 

Cellulose  acetate  butyrate- 


GGY. 

AKS,  GRD,  NOP,  NYC,  RH. 

NAC,  NOP,  RH. 


ore. 

PLC. 
DUP. 
CRO,  PAS. 


ACY,  AKS,  DEX. 

SNW. 
DUP. 
GAT. 
DEX. 

OAF. 

AKS,  X,  X. 

GIV. 

SDH. 

ACY. 

PAS. 

RBC. 

MON. 


MON. 
WTH. 
MON. 

USB. 
GGY. 
PIC. 


SYNTHETIC  ORGANIC  CHEMICALS  1966 


TABLE  21B.  --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  iP66- -Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


MISCELIANEOUS  CHEMICALS,   ACYCLIC— Continued 


Cellulo 


Est 


and  Ether 


-Continued 


»Cellulose  esters — Continued 

Cellulose  acetate  propionate 

Cellulose  propionate 

Nitrocellulose   (Cellulose  nitrate) 

»Cellulose  ethers: 

Ethylcellulose 

Ethylhydroxyethylcelluloee 

Urdroxyethylcellulose 

Methylcellulose 

»Sodium  carboxjmethyloellulose,   100^ 

Sodium  carboxjmethylhydroxyethylcellulose 

Lubricating  Oil  Additives 

Chlorosulfurlzed  hydrocarbon 

Chlorosulfurlzed  lard  oil 

Chlorosulfurlzed  sperm  oil 

Oxidized  hydrocarbons 

»Pho6phorodlthloates  (Dlthiophospliates) : 

Zinc  di(butylhexyl)  phosphorodithioate 

Zinc  dihexyl  phosphorodithioate 

Zinc  diisopropyl  phosphorodithioate 

All  other - - 

Sulfurized  butenes 

»Sulfurized  lard  oil 

•Sulfurized  sperm  oil 

All  other - 

Nitrogenous  Compounds 

Acetaldehyde,  1,1 -dimethyl  hydrazone 

Acetamlde 

Acetamidine  hydrochloride 

Aoetamidoethanol  (n-Acetyl-ethanolamlne) 

Acetone  semlcarbazone 

Acetonitrile 

•Acrylonitrlle 

Adiponitrile - - - 

Allyl-sec-butylcyanoacetio  acid,  ethyl  ester 

l-Allyl-3-(2-hydroxyethyl) -2 -thiourea 

Allyl  Isocyanate 

Allyl  isothiocyanate,  non-perfume  grade 

Amidinourea  (Granylurea)  phosphate 

•Amines : 

Allylamines 

«n-Butylamine,  mono-  

tert-Butylamine,  mono-  

n-Butylethylamine 

n-Butylmethylamine 

»Di-n-butylamine 

Di-n-butylmethylamine 

Dlethylamine  hydrochloride 

Die thylenetri amine 

N,N-Diethylethylenediamine 

ifi-  ,N^  -Diethyl-l,'i-pentanediamine  ( Novoldiamlne ) ■ 

Diethylaminopropylamine 

Dlhexylamine 

Diisobutylamlne 

Dimethylamine  hydrochloride 

Dimethylamlne  sulfate 

N,N-Dimethyl-l,3-propanediamlne 

Dlmethylamlnopropylamine 

Dlpentylamine  ( Diamylamlne ) 

»Dlpropylamine 

Dipropylenetriamine 

•Ethylamlnee : 

Dlethylamine 

Ethylamlne,  mono-  

Trlethy] 


DOW,  HPC. 

HPC. 

HPC,  UCC. 

DCW. 

BUK,  DUP,  HPC,  KON,  WMP,  WYN. 

HPC. 


EN  J. 
CCW. 

ccw. 

ALX. 


ORO. 

MON. 

SIN. 

ENJ,  LUB,  MON,  SIN,  X. 

LUB. 

ccw,  GOC,  NLC,  SIN,  WBG. 

CCW,  LUB,  QCP,  SIN,  SOI. 

CCW,  ENJ,  HK,  LUB,  MON,  ORO,  SIN,  SOI,  TX. 


DIX. 

ACQ. 

MRK. 

RBC. 

NOR. 

EKX,   SOH, 

UCC. 

ACY,    BPG, 

DUP, 

MON,    SOH,    UCC 

DUP,   MON. 

SDW. 

mr,  IDC. 

CTN. 

ICO. 

ACT. 

SHC. 

EKT,    PAS, 

UCC, 

VGC. 

MON,    RH. 

PAS. 

PAS. 

PAS,    UCC, 

VGC. 

UCC. 

CFC,    X. 

DOW,    JCC, 

UCC. 

CBP,    COK. 

SDH. 

UCC. 

VGC. 

PAS,    VGC. 

EK,    GAM. 

RH. 

JCC. 

UCC. 

PAS,    VGC. 

ENJ,    PAS, 

UCC, 

VGC. 

UCC. 

DUP,    ESC, 

PAS, 

UCC,    VGC. 

ESC,    PAS, 

UCC, 

VGC. 

ESC,    PAS, 

UCC, 

VGC. 

MISCELLANEOUS  CHEMICALS 


TABLE  21B.  --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1 966  - -Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC— Continued 

Nitrogenous  Compounds-~C<)ntirmed 

Amines — Continued 

Ethylenediamlne 

Ethylenediamine  sulfate 

1,6-Hexanediamine   (Hexamethylenediamine) 

3,3'-Iminoblspropylamine 

Isobutylamlne 

»Isopropylamines : 

Diisopropylamine 

Isopropylamlne,   mono-   

»Methylajnines : 

Dimethylamine 

Msthylamlne ,   mono-   

Trimethylamlne-- 

Methylamine  hydrochloride 

Methyltriethylenediamlne 

Pentaethylenehexamine 

Pentylamine   (Monoamylamine) 

1,2-Propanediamine   ( Propylenediamine ) 

1,3-Propanedlamine   (1,3-Diaminopropane) 

Propylamine  mono-   

Tetraethylenepentamine 

N,N,N',N'-Tetramethyl-l,3-butanediamine 

Tetramethylethylenediamine 

Tributylamlne - 

Triethylenetetramine 

Tripentylamine 

Other -- - 

2-Amino-l-butanol 

2-Aminoethanethiol  (2-Meroaptoethylamine)  hydrochloride- - 

1-Amlnoethanol  (Acetaldehyde  ammonia) 

2-Aminoethanol  (Monoethanolamine)  hydrochloride 

2-Aminoethanol  (Monoethanolamine)  sulfite 

Aminoethoxyethanol 

2-(2-Aminoethylamino)ethanol  (Amlnoethylethanolamine) 

2-Amlnoethyl  mercaptoacetate  (Monoethanolamine  thio- 
glycolate). 

2-Amlno-2-ethyl-l,3-propanediol 

2-Aminoethyl  vinyl  ether , 

Aminoguanidlne  bicarbonate 

2-Amlno-2-(hydroxymethyl)-l,3-propanediol  (Trls-(hydroxy- 
methyl ) amlnome thane ) . 

2-Amlno-2-methyl-l,3-propanediol 

2-Amino-2 -methyl -1-propanol 

2-Amino-l-propanol 

3-Amino-l-propanol 

»1,1'  -Azobisformamide 

2,2'-Azobis[2-methylproplonitrile]  (Azobislsobutyronitril( 

l,3-Bis(2-hydroxyethyl)-2-thiourea 

l,3-Bis(hydroxymethyl)urea  ( Dimethylolurea ) 

N,0-Bis(trimethylsilyl)acetamide— — 

Biuret - 

N-Bromoacetamide 

N-Bromosuccinimide  (Suooinibromimlde) 

2,3-Butanedione  monoxlme 

2-Butanone  oxime 

tert-Butyl  carbazate 

n-Butyl  cyanoacetate 

l-Butyl-3-ethyl-2-thiourea 

2,2'-(Butylimino)diethanol  (N,N-Bis(2-hydroxyethyl)-butyl. 
amine). 

Butyl  isoeyanate 

Butyraldehyde  oxime 

n-Butyronitrile 

»Caprolaotam  (2-Qxohexamethylentmlne) 

Chloroaoetamide 

Chloroacetonltrlle 

Chlorocholine  chloride 


ESC,  PAS,  UCC,  VGC. 
ESC,  PAS,  UCC,  VGC. 


CFC, 

CCM, 

DUP, 

ESC 

PAS 

RH. 

COM, 

DUP, 

ESC, 

GAF 

PAS 

RH. 

COM, 

DUP, 

ESC, 

PAS 

RH. 

EK, 

RBC. 

JCC. 

DOW. 

EK, 

PAS. 

JCC, 

UCC. 

UCC. 

PAS, 

UCC. 

DOW, 

UCC. 

UCC. 

RH. 

PAS. 

DOW, 

UCC. 

PAS. 

ALB, 

ALD, 

DUP, 

EK, 

NTfi, 

ONX,    SNW,    VGC 

ACY, 

COM. 

EVN. 

PAS. 

WSN. 

EVN, 

SUM. 

JCC. 

DOW, 

JCC, 

UCC. 

EVN, 

HAB. 

COM. 

MEE. 

TRJ. 

COM. 

COM. 

CCM. 

LIL. 

UCC. 

FWT, 

NPT, 

USH. 

DUP. 

IDC. 

GLY, 

X. 

PIC. 

SW. 

AHA. 

ARA, 

SDW. 

EK. 

ALB, 

CCA, 

MID, 

NAC, 

TRO. 

AID. 

KF. 

PAS. 

PAS. 

CWN, 

UPJ. 

NAC. 

EKX. 

DBC, 

DUP, 

NAC. 

BPC, 

DOW. 

BPC. 

ACY. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 

TABLE  21B  --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i 566 --Continued 


MISCELLANEOUS  CHEMICAI5,  ACYCLIC— Continued 

Nitrogenous  Compounffs- -Continued 

»2-Chloro-N,N-dlinethylethylamine  (Dlmethylaminoethyl  chlO' 
ride)  hydrochloride. 

3-Chloro-N,N-dimethylpropylandne 

a-Chloro-N.N-dimetl^rlpropylamine  hydrochloride 

3-Ghloro-N,N-diinethylpropylamine  hydrochloride — 

2-Chloroethylamine 

fi-Chloroallyl-N-methylamine 

N-Chlorosuooinimide  (Succinichlorimide) 

2-Chlorotriethylamine  hydrochloride 

2-Chloro-N,N-diethylethylamine  hydrochloride — 

Choline  tase 

Coco  nitrile 

Coconut  oil  amide 

Cottonseed  oil  nitrile 

Creatine  &  creatinine 

Crotononitrile 

2-Cyanoacetamide 

2-Cyanoacethydrazide 

Cyanoacetic  acid 

Cyanogen  bromide 

2-Dibutylaminoethanol 

1, 3 -Dibutyl -2 -thiourea 

IjA-Dicyanobutene 

Diethyl  acetamidomalonate 

Dlethylaminoethanethiol  hydrochloride 

»2-DiethylaEinoethanol 

2-(2-Diethylaminoethoxy)ethanol 

2-Diethylaminoethyl  methacrylate 

Dlethylcarbamoyl  chloride 

Diethyldithiocarbamic  acid,  sodium  salt 

N,N-Diethyldodecanamlde 

Diethylhydroxylandne 

l,3-Diethyl-2-thiourea - -— 

2-Diisopropylaminoethanol  ( N-Diisopropylethanolamine ) -- 

Diisopropylannnonium  nitrite 

l,3-Diisopropyl-2-thiourea 

Di ( me thoxye thy 1) amine 

N, N-Dimethylacetamide 

2-Dimethylajiiinoethanethiol  hydrochloride 

»2-Dimetl^laminoethanol 

3-Dimethylajninopropionitrile 

Dlmethylaminoethyl  methacrylate 

2-Dimethylamino-2-methyl-l-propanol 

Dimethylcarbamoyl  chloride 

N-(3-Dimethylaminopropyl)oleamide 

N, N-Dimethylformamide 

1,1 -Dime  tt^rlhydrazine 

Dithiooxamlde 

2,5-Dithiobiurea - 

tert-Dodecyldisuccinamide 

Erucamide 

*Ethanolamines : 

*2-Aminoethanol  (Monoethanolamine) 

»2,2'-Amlnodiethanol  (Diethanolamine) 

<<2,2 '  ,2  "  -Nitrilotriethanol  ( Trlethanolamlne ) 

Ethoxymethylenemalononitrile 

3-Ethoxypropionitrile 

Ethyl  aoetamidocyanoacetate 

Ethyl  allyl(l-methyl-2-pentynyl)cyanoaoetate- — 

2-Ethylaminoethanol  ( Ethylmouoethanolamine ) 

Ethyl  carbamate 

Ethyl  carbodilmide  hydrochloride 

Ethyl  cyanoacetate 

Ethyl  diazoacetate 

2-Ethylhexyl  cyanoacetate 

N-Ethyl-N-hydroxyethyl-l,<i-pentanediamine-* 

5-(N-Ethyl-N-hydroxyethylamino)-2-pentaxione 

Ethyl  isocyanate 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


ABB,  GAM,  HEX,  MCH,  NES,  PAS. 


SK. 

MCH. 

MCH. 

ICI. 

LIL. 

ARA,  RAC. 

HEX,  MCH, 

PAS. 

RH. 

FOR. 

ARC,  PG. 

FOR. 

PFN. 

KF. 

KF. 

KF. 


AAC,    PAS. 

PAS,    RBC. 

X. 

SDW. 

EVN. 

AAC,   PAS, 

UCC. 

PAS. 

DUP. 

GAM. 

EK. 

EK. 

PAS. 

PAS,    RBC. 

PAS,    UCC. 

CMC. 

PAS. 

VGC. 

DUP. 

EVN. 

AAC,    JCC, 

PAS,    RH,    UCC 

ACY. 

AAC. 

COM. 

CTN,  ore. 

DUP. 

DUP. 

FMP. 

MAL. 

ACY. 

X. 

ADM,    FIN 

ACP,  DOW,  JCC,  UCC. 

ACP,  DOW,  JCC,  UCC. 

ACP,  DOW,  JCC,  UCC. 

KF. 

ACY. 

SDW. 

LIL. 

PAS. 

BKL,  FMP. 

OTC. 

KF. 

AID. 

GAF,  KF. 

SDW. 

SDW. 

CTN,  OTC. 


MISCELLANEOUS  CHEMICALS 

TABLE  21B.  --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  7566- -Continued 

Manufacturers'    identification  codes 
(according  to  list  in  table  22) 

MISCELLANEOUS  CHEMICALS,    ACYCLIC— Continued 
Nitrogenous  Compounds— Continued 


Fonnamlde 

Formamidine  disulfide  dihydrochloride 

Glycine  (Aminoacetic  acid),  non-medicinal 

Glycine  ethyl  ester  hydrochloride 

Glycine  salts : 

Cupric  glycinate 

Potassium  glycinate 

Sodium  glycinate 

Glyoolonitrile 

Guanidine  hydrochloride 

Hexamethylenediaramonium  adipate  (Nylon  salt) 

ffydracrylonltrile  (Ethylene  cyanohydrin) 

2-Ifydrazinoethanol  (2-Hydroxyethylhydrazine) 

N-Z-ffydroxyethylaoetamide 

I^roxyethyl  carbamate 

2-(l^droxymethyl) -2 -nitro-l, 3 -propanediol  (Tris-(hydroxy- 
methyl )ni tromethane ) . 

Isobutyronitrile 

Isopropanolamines : 

l-Amino-2-propanol  (Manoisopropanolamine) 

l,l'-Iiid.nodi-2-propanol  (Diisopropanolamine) 

1,1',  1"  -Nitrilotri-2-propanol  (Triisopropanolamine) 

3-Isopropoxyproplonitrile 

3-Isopropoxypropylamine 

2-Isopropylaminoethanol 

Isopropyl  carbamate 

Isopropyl  ethyl thionocarbamate 

Lactonitrile 

Lauronitrile  (Dodecyl  nltrile) 

Malonamlde 

Malononltrlle 

Methacrylamlde 

Methacrylonitrlle - 

Methoxyamine  hydrochloride 

3-Methoxypropionitrile 

3-Methoxypropylamlne 

N-ltethylacetamlde 

2-Methylamlnoethanol  ( N-Methylethanolamlne ) 

Methylamino  dimethyl  acetal 

ifethyl  carbamate 

Methyl  cyanoacetate 

Methyl  a -cyanoacrylate 

N,N'-Methylenebis(acrylamlde) - 

N,N'-Methylenebis(octadecanamlde) 

N-Uethylglucamine 

Methyl  isocyanate 

2,2'-(Methylimino)diethanol  (Methyldiethanolamlne) 

»2-Metliyllactonitrile  (Acetone  cyanohydrin) 

2-Methyl-2-nltro-l,3-propanedlol 

2-Methyl-2-nltro-l-propanol 

Nfethylpolyethanolamine 

N-Methyltaurlne 

N-Methyltaurine,  sodium  salt 

N-lfethylurea 

»Nitriloacids  and  salts: 

(Dlethylenetrinitrllc)pentaaoetio  acid 

(Diethylenetrinitrllo)pentaaoetlc  acid,  monoeodium 

hydrogen  ferric  salt. 
(.Diethylenetrlnltrilo)pentaacetlc  acid,  pentasodium  salt 

(Dlethylenetrinitrilo)pentaacetlc  add,  sodium  salt 

N,N-Dihydroxyethylglyclne,  sodium  salt 

Ethanoldiglycine,  disodlum  salt 

(Ethylenedinltrilo)tetraacetic  acid  (Ethylenediamlne- 

tetraacetic  acid). 
(Ethylenedlnltrilo)tetraaoetio  acid,  oalolum  disodlum 

salt. 
(Ethylenedinltrilo)tetraaoetic  acid,  diammonlum  salt 


DUP. 
WAY. 

BPC,  CHT. 
BPC. 

BPC. 

BPC. 

BPC. 

ACY. 

ACY. 

CEL,  MON. 

UCC. 

NOR. 

USR. 

JCC. 

COM. 

EKX. 

DOW,  UCC. 

DOW,  UCC. 

DOW,  UCC. 

ACY,  DUP. 

DUP. 

PAS. 

BKL. 

DOW. 

MON. 

FOR. 

KF. 

KF. 

BFG,  RH,  X. 

SOH. 

EK. 

DUP. 

DUP,  EKT,  JCC. 

ACI,  EK. 

UCC. 

LIL. 

BKL,  FUP. 

KF. 

EKT. 

ACY. 

ARC. 

DUP. 

CTN,  OTC. 

UCC. 

ACY,  RH,  X. 

COM. 

COM. 

GAF. 

GAF. 

TNA. 

LIL. 


DOW,  GGY,  HMP. 
DCW,  GGY. 
DOW. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  21B.  --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufa  cturer,  1 966  -  -  Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC— Continued 

Nitrogenous  Compounds-'Continued 

»Nitrlloaoids  and  salts— Continued 

»(Ethylenedinitrilo)tetraacetic  acid,  dlsodium  salt 

(Ethylenedinitrilo)tetraacetlo  acid,  disodium  copper 

salt,  dihydrate. 
(Ethylenedinitrilo)tetraacetic  acid,  disodium  zinc  salt, 
dihydrate. 

(Ethylenedinitrilo)tetraacetic  acid,  manganese  salt 

(Ethylenedinitrilo)tetraacetic  acid,  monosodium  iron 

salt. 
(Ethylenedlnitrilo)tetraacetlo  acid,  tetrapotassium  salt 

»(Ethylenedinitrilo)tetraaoetic  acid,  tetrasodium  salt 

»(Ethylenedinitrilo)tetraacetlc  acid,  trisodium  salt 

(N-Hydroxyethylethylenedlnitrllo)trlacetio  acid 

»(N-HjrdroxyethyletlQflenedinitrilo)triacetic  acid,  tri- 
sodium salt. 

Nitrilotriacetic  acid,  trisodium  salt 

Other 

2-Nitro-l-butanol — — 

Nitroethane 

Nitrome thane 

1-Nitropropane 

2-Nitropropane 

»Nylon,  6  and  6/6  polymer  for  fiber 

Ootadecyl  isooyanate 

«01eamlde  (Octadeoene  amide) 

Oleonitrile  (Octodecene  nitrile) 

Oleoylhydroxamic  acid 

Oleoylpalmltamlde 

*Pentaerythrltol  tetranitrate 

Pentyl  nitrate  (Anyl  nitrate) 

Polyaorylamide 

Polyacrylonltrlle 

n-Propyl  carbamate 

Propyl  isooyanate ■ — 

Propyl  nitrate 

Quaternary  ammonium  compounds 

Ricinolamlde 

*Saroosine  (N-Methylamlnoacetic  acid) 

Semlcarbazide  base 

Semicarbazide  hydrochloride 

Semioxamazide 

»Stearamlde  (Octadecane  amide) 

Stearonitrile  (Octadecanenitrile) 

Suoolnlmide 

Tallow  amide,  hydrogenated 

Tall  oil  nitrile - - - 

Tallow  nitrile - 

Tallow  nitrile,  hydrogenated 

N,N,N',N'-Tetrald.s(2-hydroxypropyl)ethylenediamine 

Tetramethylguanidine 

Tetramethylurea 

Thloacetamide 

3,3 '-Thlodlpropionltrlle 

Thiosemicarbazide 

Triallyl  cyanurate 

Triisopropanolamine  borate 

N-Trimethylsllylacetamide 

»Urea  In  compounds  or  mixtures,  100^  basis : 

»In  feed  compounds 

»In  liquid  fertilizer 

»In  solid  fertilizer 

In  plastics 

All  other- - - - 

Urea  peroxide 


GGY. 

CRT,  CWL,  DOW,  GGY,  HMP,  HRT,  RFC,  TCC. 

GGY,  HMP,  NOP. 

GGY. 

CRT,  CWL,  DOW,  GGY,  HMP,  RPC,  TCC. 


GGY, 

HMP. 

EK, 

WP. 

COM. 

COM. 

COM. 

COM. 

COM. 

DUP, 

MON, 

NAC. 

CWN, 

MOB. 

ADM, 

ARC, 

FIN, 

HUM. 

ARC, 

FOR. 

WAY, 

WOB. 

FIN. 

DUP, 

HPC, 

TRJ. 

TNA. 

ACY, 

NLC. 

DUP. 

BKT,. 

CWN, 

OTC. 

TNA. 

EK, 

PAS, 

RSA. 

TKL. 

GAF, 

GGY, 

HMP, 

VPC. 

FMT. 

FMP. 

NOR. 

ADM, 

ARC, 

DUP, 

FIN.    HUM. 

FOR, 

HUM. 

NAC. 

ADM, 

ARC. 

FOR. 

ADM, 

FOR. 

FOR. 

rm. 

ACY. 

OTC. 

BKC. 

ACY, 

HAB. 

ACY, 

FMI. 

ACT. 

USB. 

EK, 

PIC. 

ACN,  ACY,  DUP,  GSC,  JDC,  KET,  MON,  MSC,  SOH,  VLN. 
ACN,  CFC,  CNC,  DUP,  ESC,  FCA,  FTX,  GCC,  GOC,  HKY,  HPC, 

JDC,  KET,  MON,  MSC,  NIT,  CMC,  PLC,  PPC,  SHC,  SNI, 

SOH,  VLN,  WYC,  X. 
ACN,  ACY,  CNC,  DUP,  GCC,  GOC,  HPC,  JDC,  MON,  MSC,  PPC, 

SHC,  SNO,  SOH,  VLN. 
DUP,  MON. 

ACN,  ACY,  DUP,  HPC,  MON,  SHC,  SNO,  SOH,  VLN,  x. 
FBM. 


MISCELLANEOUS  CHEMICALS 

TABLE  21B.  --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i566- -Continued 


Manufaoturere'    identification  codes 
(according  to  list  In  table  22) 


MISCELLANEOUS  CHMICALS,   ACYCLIC— Continued 

Nitrogenous  Compounds--Contliiued 

Urea  -  urethanp  r-opol^raier 

Y-Valeronitrlle — - 

All  other  nitrogenous  compounds 

Acids,  Acid  Anhydrides,   and  Acyl  Halides 

»Acetic  acid,   synthetic,   100^ - 

♦Acetic  anhydride,   100^: 

From  acetaldehyde 

From  acetic  acid,   other  than  recovered,   by  the  vapor- 
phase  process. 
From  acetic   acid,   recovered,   by  the  vapor-phase  process 

From  ethylene 

Acetyl  chloride 

Aconitio  acid 

»Acryllc  acid 

«Adiplc  acid - - 

Adipoyl  chloride 

Azelaic  acid 

Behenic  acid 

:i-Brcmo(lauric-steario)  acid 

Butylstannolc  acid 

•Butyric  acid 

Butyric  anhydride 

Butyiyl  chloride 

Castor  oil  fatty  acids,  dehydrated 

»Chloroaoetic  acid,  mono-  

Chloroacetyl  chloride 

Citric  acid 

Crotonio  acid  (2-Butenoie  acid) 

»Decanoyl  chloride 

Dlglyoolic  acid 

Di-n-propylacetic  acid 

Di-n-propylacetyl  chloride 

Dodecenylsuccinic  anhydride 

Dodecylauccinic  anhydride 

Erucic  acid . 

2-.Ethylbutyrio  acid  (Diethylacetic  acid) 

2-Ethylhexanoic  acid  (a-Ethylcaproic  acid) 

2-Ethylhexanoyl  chloride 

♦Formic  acid,  905t- 

»F\jjiiaric  acid 

♦Gluconic  acid,  tech 

Glutarlc  anhydride 

Glycolio  acid  (Hydroxyicetic  acid) 

n-Hexadecenylsuocinic  anhydride 

Isethlonic  acid  (2 -Hydroxy ethanesulfonic  acid) 

Isoascorbic  acid 

lEobutyric  acid 

Isobutyrlc  anhydride 

Isodecanoic  acid  mixed  IscmerB 

Iso-ootanoic  acid 

Itaoonic  acid  (Methylenesuccinlc  acid) 

Lactic  acid: 

Edible,  100^ 

Technical,  100* 

lauroyl  bromide 

♦lauroyl  chloride 

Levultnlc  acid 

Maleic  acid 

♦Maleic  anhydride - 

Malic  acid 

Molonlc  acid — 

Mercaptoacetic  acid  ( Thloglycollc  acid) 

fl-Mercaptopropionlc  acid 

Mercaptosucclnlc  acid  (Thlcmallc  acid) 

Methacryllc  acid 


DUP. 
SEL. 
ADM,  CFC,  x. 


BOH,  CEL,  EKT,  HPC,  PUB,  UCC. 


HPC. 

CEL,    EKT. 

CEL. 

UCC. 

TBK. 

PCW. 

BFG,    GEL,    DBC,   MM 

UCC. 

CEL,    DUP,    ELP,   MON 

NAC,    RH. 

CFC,    EK. 

EMR. 

ADM,    HUM. 

DUP. 

CCW. 

CEL,    EKT,    UCC. 

EKT. 

HK. 

BAC,    SF. 

BUK,    DA,    DOW,    HPC, 

MON. 

DOW. 

MLS,    PFZ. 

EKT. 

CAD,    TBK,    UPR,    WTL 

DUP. 

X. 

CTN. 

HMY,   MON,    NAC. 

X. 

ARC. 

UCC. 

EKT,    UCC. 

WTL. 

DUP,    HN,    SF,    UCC. 

HN,   MON,    NAC,    PCC, 

PFZ     PTT. 

CWL,    DLI,    IBI,    PFZ. 

UCC. 

DUP. 

HMY. 

GAF. 

BAX,   MRK,    PFZ. 

EKT. 

EKT. 

UCC. 

UCC. 

PFZ. 

CLN,   MON. 

cm,   MON. 

DOW. 

CAD,    GAF,    ONX,    TBK, 

THC,    UPR,    WTL 

CRZ. 

NAC,    PFN,    PFZ. 

HN,    KPS,   MON,    NAC, 

PCC,    PTT,    RCl. 

EK,    NAC,    PFN, 

KF. 

EVN,    HAB,    RETT. 

EVN. 

EVN. 

DUP,    RH. 

180  SYNTHETIC  ORGANIC  CHEMICALS,  1966 

TABLE  21B.— Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 — Continued 


MISCELLANEOUS  CHBGCALS,   ACYCLIC— Continued 

Acids,  Acid  Anhydrides,   and  Acyl  Ha i ides —Continued 

Methanesulfonio  acid 

2-Nfethylvaleric  aold  (2-Methylpentanoio  acid) 

Micoohlorio  acid  (2,3-Diohloro-3-foniiylaorylio  acid)- 

Nonanolc  acid   (Pelargonic  acid) 

Nonenylsuooinic  anhydride 

Ootanoyl  chloride 

Octenylsuocinic  anhydride 

Oleoyl  chloride 

"Oxalic  acid 

»Palmltoyl  chloride 

Pelargonyl  chloride 

Peroxyaoetlc  acid 

Pivaloyl  chloride 

Polyaorylic  acid 

Polygalacturonic  aold 

•Propionic  acid 

Propionic  anhydride 

Propionyl  chloride 

2-Propylvaleric  acid  (Dlpropylacetic  acid) 

Sebaclo  acid 

Sorbic  acid  (2,4-Hexadlenolc  acid) 

Stearyl-2-laotic  acid 

Succinic  acid 

Succinic  anhydride 

Tallow  fatty  acyl  chloride 

d-Tartarlc  acid 

Tetrahydroxysucoinlc  acid  (Dioxytartlo  acid) 

Thioaoetlc  acid 

Thlolactic  acid r 

3,3'-Thlodlpropionlc  acid 

Trichloroacetic  acid 

Trichloroacetyl  chloride 

(Trlohloroiiiethyl)pho8phonlo  acid 

Trlfluoroacetic  anhydride 

Valeric  acid - — - - 

All  other— 

Sails  of  Organic  Acids 

•Acetic  acid  salts: 

Aluminum  acetate 

subacetate 

acetate 

Barium  acetate 

Cadmium  acetate 

Calcium  acetate 

Chrcmlum  acetate — -— — 

Cobalt  acetate 

•Copper  acetate 

Lead  acetate 

lead  subacetate 

Lead  tetraacetate 

Magnesium  acetate 

Manganese  acetate 

Mercuric  acetate 

Methylmeroury  acetate 

motel  acetate 

•Potassium  acetate 

Silver  acetate 

•Sodium  acetate 

Sodium  dlacetate 

Strontium  acetate 

Uranyl  acetate 

•Zinc  acetate 

•Zirconium  acetate 

Chloroacetlo  acid,  sodium  salt 

3-Chloro-2Tbutene-l-sulfonio  aold,  sodium  salt 

Chlorohydroxylaotio  acid,  aluminum,  sodium  salt 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


EK,  PAS. 
UCC. 
EKT. 
EMR,  GIV. 

mx. 

HK. 

HMY. 

DEP,  GAP,  TBK. 

ACG,  HK,  MAL,  PFZ,  SF. 

GAP,  HAL,  OPC,  TBK. 

WTL. 

FMB. 

WRL. 

RH. 

SKG. 

CEL,  CCM,  EKT,  UCC. 

CEL,  EKT,  UCC. 

ABB,  TBK. 

BPC. 

RH,  WTH. 

UCC. 


MAC. 


AIB,  DUP,  EK,  KF,  PIC,  RH,  UCC. 


ACY,    UCC. 

MAL. 

ACG,    BKC, 

MAL, 

WSN. 

ACG,    BKC, 

MAL. 

BKC,    HSH, 

MAL. 

SHP. 

ACG,   BKC, 

MAL. 

ACY. 

BKC,    HSH, 

SHP. 

ACG,   BKC, 

UCC. 

ACG,   BKC, 

MAL, 

SW. 

ACG,   BKC, 

MAL. 

AHA. 

ACG,   BKC. 

HSH,    SHP. 

ACG,   MAL. 

DUP. 

BKC,    HSH, 

SHP. 

ACG,   BKC, 

CWL, 

MAL, 

UCC, 

WSN. 

MAL. 

ACG,    BKC, 

CEL, 

DAN, 

EKT, 

MAL 

UCC. 

BKC. 

BKC. 

ACG,    BKC, 

HSH, 

MAL, 

SNW, 

UCC 

HSH,    NTL, 

SNW, 

TZC. 

D0». 

MISCELLANEOUS  CHEMICALS 


TABLE  21B.  —Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i 566- -Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


MISCELIANEOUS  CHIMICAIS,  ACYCLIC—Continued 
Salts  of  Organic  Acids—Continued 

Citric  acid  salts: 

Ammonium  citrate 

Calcium  citrate 

Ferric  ammonium  citrate 

Ferric  citrate 

Ferrous  calcium  citrate 

Potassium  citrate 

Sodium  citrate 

»2-B^hylhexanoic  acid   (a-Ethylcaproic  acid)   salts: 

Aluminum  2-ethylhexanoate 

Barium  2-ethylhexanoate 

Cadmium  2-ethylhexanoate 

»Calclum  2-ethylhexanoate 

•Cobalt  2-ethylhexanoate 

Copper  2-ethylhexanoate 

Dlbutyltin  di -2-ethylhexanoate 

Iron  2-etbylhexanoate 

»Lead  2-ethylhexanoate 

Lithium  2-ethyIhexanoate 

Manganese  2-ethylhexanoate 

Nickel  2-ethylhexanoate 

Potassium  2-ethylhexanoate 

Rare  earths  2-ethylhexanoate 

Stannous  2-ethylhexanoate 

Strontium  2-ethylhexanoate 

»Zino  2-ethylhexanoate 

•Zirconium  2-ethylhexanoate 

Formic  acid  salts : 

•Aluminum  formate 

Ammonium  formate 

Calcium  formate 

Chromic  formate 

Copper  formate 

Lead  formate 

Nickel  formate 

Potassium  formate 

Sodium  formate,   refined 

Sodium  formate,   tech 

FUmario  acid,    lead  salt 

Gluooheptonlc  acid,  zinc  salt 

Gluconic  acid  salts: 

Ammonium  gluconate 

•Sodium  gluconate 

Glyoolio  acid  salts : 

Aluminum  glycolate 

Sodium  glycolate 

9H-Hexadeoafluorononanolc  acid,  ammonium  salt 

Humlo  acids,  sodium  salts 

Isoascorblc  acid,  sodium  salt 

lactic  acid  salts : 

Aluminum  sodium  lactate 

Calcium  lactate - 

•Llnolelc  acid  salts: 

•Calcium  llnoleate 

•Cobalt  llnoleate 

Copper  llnoleate 

Lead  llnoleate 

Lead  manganese  llnoleate 

Ifanganese  llnoleate 

Maleio  acid,   trlbasic  lead  salt— - 

•Jfercaptoaoetlo  acid  ( Thloglycollc  acid)  salts: 

Ammonium  mercaptoacetate 

Antimony  mercaptoacetate 

Calcium  mercaptoacetate 

Dlbutyltin  bis(iso-octyl  mercaptoacetate) 

Dlbutyltin  mercaptoacetate 

Potassium  mercaptoacetate 

Sodium  mercaptoacetate 


MAL, 

PFZ. 

PFZ. 

MAL, 

PFZ. 

MAL. 

X. 

MLS, 

PFZ. 

MLS, 

PFZ. 

WTC. 

CCA. 

CCA. 

CCA,    FEE,    HNX,    HSH,   MCI,    SRR,    SW,    WTC. 

CCA,    FER,    HNX,    HSH,   MCI,   MID,    SHP,    SRR,    SW,    WTC. 

CCA,    SRR. 

X. 

CCA,   SRR. 

CCA,    HNX,    HSH,   MCI,    SHP,    SRR,    SW,    WTC. 

SRR. 

CCA,    HNX. 

MCI. 

CCA,   SRR. 

CCA. 

WTC. 

CCA. 

CCA,    HNX,    HSH,   MCI,    SRR,   WTC. 

CCA,    HNX,   WTC. 

CFC,    SF,    UCC,   WSN. 

ACG,   WSN. 

TRJ. 

OAF. 

CTN. 


CFC. 

ACG,   BKC. 
HPC,    TRJ. 
NTL. 
PFN. 

PFZ. 


CWL,   DU,    IBI,    PFZ,    Hff. 


CIB. 

CFC, 

MED. 

DUP. 

HW. 

MRK, 

PFZ. 

TZC. 

SHF. 

CCA, 

LET, 

SHP 

HSH, 

SHF, 

SRR. 

WTC. 

SHP, 

SRR. 

SDH, 

SRR. 

SHP. 

NTL. 

EVN, 

HAB. 

TNI 

CCA. 

EVN. 

X. 

CCA. 

EVN. 

EVN, 

MED. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  21B. --MiscelUxTieous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  j 966— Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,   ACTCLIC— Continued 


Salt 


of  Organic  i4cids--Contlnued 


Meroaptopropionlc  acid,  dibutyltin  salt 

Methylsucoinlc  acid,  disodium  salt 

Neodecanonoic  acid  salts 

Octanoic  acid  (Capryllo  acid)  salts: 

Aluminum  octanoate 

Stannous  octanoate 

Zinc  octanoate 

*01eic  acid  salts: 

Aluminum  oleate 

Ammonium  oleate 

Barium  zinc  oleate 

Copper  oleate 

Stannous  oleate 

»Oxalic  acid  salts: 

Ammonium  oxalate 

Calcium  oxalate 

Copper  oxalate 

Ferric  ammonium  oxalate 

Ferric  oxalate 

Ferric  sodium  oxalate 

Ferrous  oxalate 

Potassium  binoxalate 

Sodium  binoxalate 

Other 

Palmitic  acid  salts: 

^Aluminum  palmitate 

Zinc  palmitate 

Phosphorodithioic  acid  salts  ( Dithiophosphates ) : 

Potassium  dihexyl  phosphorodithioate 

Sodium  di-sec -butyl  diethyl  phosphorodithioate 

Sodium  di -sec-butyl  phosphorodithioate 

Sodium  diethyl  phosphorodithioate 

Sodium  dihexyl  phosphorodithioate 

Sodium  diisopropyl  phosphorodithioate 

Other 

»Polyacrylic  acid  salts : 

Ammonium  polyacrylate 

Potassium  polyacrylate 

Sodium  polyacrylate 

Polymethacrylio  acid,  sodium  salt 

♦Propionic  acid  salts: 

*Calcium  propionate 

♦Sodium  propionate 

Zinc  propionate 

Ricinoleic  acid  salts: 

Calcium  ricinoleate 

Lithium  ricinoleate 

Sodium  ethyl  oxalaoetate 

Sodium  polypectate 

Sodium  sorbitol  borate 

Sorblc  acid  salts: 

Potassium  sorbate 

Sodium  sorbate 

♦Stearic  acid  salts : 
♦Aluminum  stearates: 

♦Aluminum  distearate 

♦Aluminum  monostearate 

♦Aluminum  trlstearate 

Ammonium  stearate 

Barium  stearate 

Cadmium  stearate 

♦Calcium  stearate 

Cobalt  stearate 

Copper  stearate 

Ferric  stearate 

Ferrous  stearate 

♦Lead  stearate 


CCA, 

X. 

SDW. 

CCA. 

NOP. 

CCW, 

X. 

BKC. 

MAL, 

vrrc. 

BCN. 

vrrc. 

MID, 

WTC. 

CCW, 

X. 

ACG, 

BKC, 

PFZ. 

SF. 

CFG. 

PFZ. 

PFZ. 

PFZ. 

BKL. 

ACG, 

BKC, 

PFZ. 

ACG, 

BKC, 

MAL,    SF 

DUP. 

ACY, 

NOP, 

WTC. 

ACY, 

NOP, 

WTC. 

ACY. 

ACY. 

ACY. 

ACY. 

ACY. 

ACY. 

ACY. 

BPG. 

BPG. 

ALC, 

BFG, 

JOR,    RH 

GRD. 

CEL,  HFT,  PFZ,  UCC,  WSN. 
CEL,  PFZ,  UCC,  WSN. 
BKC. 

BAC. 
BAG. 
PMP. 
SKO. 
AH). 


JTC,  LEF,  MAL,  NOG,  NOP,  PRP,  SYP,  WTG. 

LEF,  MAL,  NOP,  WTC. 

JTC,  LEF,  MAL,  NOG,  NOP,  PRP,  SYP. 

NOP. 

LEF,  NOG,  NOP,  PRP,  SYP,  WTG. 

PRP,  SYP,  WTG. 

HNX,  JTC,  LEF,  MAL,  NOG,  NOP,  PRP,  SYP,  WTG. 


WTG. 


WTG. 

NOP,  NTL,  PRP,  WTC. 


MISCELLANEOUS  CHEMICALS 


183 


TABLE  21B. — Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966— Continued 


Manufacturers '   identification  codes 
(according  to  list  in  table  22) 


MISCELLANEOUS  CHEKQCALS,    ACYCLIC— Continued 


Salts  of  Organi 


cids-'Contlnued 


Stearic  acid  salts — Continued 

Lead  stearate,  dibasic 

^Lithium  stearate 

^Magnesium  stearate 

Manganese  stearate 

Nickel  stearate 

»Zinc  stearate 

All  other — -  — 

Succinic  acid,  sodium  salt 

Sugar  acids,  sodium  salt 

Tartaric  acid  salts: 

Antimony  potassium  tartrate 

Potassium  bi tartrate 

Potassium  sodium  tartrate 

Sodium  bi tartrate 

Valeric  acid,  ammonium  salt 

Xanthic  acid  salts : 

Potassium  n-butylaanthate 

Potassium  ethylxanthate 

Potassium  hexylxanthate 

Potassium  isopropylxanthate 

Potassium  pentylxanthate 

Potassium  sec -pentylxanthate 

Sodium  n-butyLxanthate 

Sodium  sec-butylxanthate 

Sodium  ethylxanthate 

Sodium  isobutyLxanthate 

Sodium  isopropylxanthate 

All  other  salts  of  organic  acids 

Aldehydes  and  Ketones 

»Acetaldehyde 

»Acetone : 

From  cumene 

♦From  isopropyl  alcohol 

Other - _ — 

Acrolein  (Acrylaldehyde) 

Aldol  (Acetaldol)- 

»2-Butanone  (Methyl  ethyl  ketone) 

Butyraldehyde 

»Chloral  (Triohloroaoetaldehyde) - 

5-Ghloro-2-pentanone 

l-Chloro-l-penten-3-one  ((3 -Chlorovinyl  ethyl  ketone) 

Chloro-2-propanone  (Chloroacetone) 

Crotonaldehyde 

Dihydropseudoionone 

l,3-Dihydroxy-2-propanone  (Dihydroxyacetone) 

2-Ethylbutryaldehyde 

2-Ethyihexanal  (c<  -Ethylcaproaldehyde) 

•Formaldehyde  (375t  by  weight) 

Glutaxaldehyde 

Glyoxal 

2-Ifeptanone  (Methyl  amyl  ketone) 

Hexaldehyde 

2,5-Hexanedione  (Aoetonylacetone) 

«4-I^droxy-^-methyl-2-pentanone  (Dlacetone  alcohol)  — 

Isobutyraldehyde 

Isodeoaldehyde,  mixed  isomers 

iBovalerone  (Dlleobutyl  ketone) 

lactide  (3,6-Dljiiethyl-2,5-p-dioxanedione) 

-i-Methoxy-* -methyl -2 -pentanone 

5 -Methyl -2-hexanone  (Methyl  isoamyl  ketone) 

*4-Methyl-2-pentanone  (Methyl  isobutyl  ketone) 

4-Methyl-3-penten-2-one  (Mesityl  oxide)— 


NTL. 

LEF,    NOP,    PRP,    SYP, 

WTC. 

ACY,    LEF,   MAL,    NOG, 

NOP, 

PRP, 

SYP,    WTC 

NOC. 

WTO. 

ACY,    BCN,    CCA,    HNX, 

,TTC, 

T,EF, 

MAL,    NOC 

WTC. 

APD. 

MAL. 

PFN. 

PFZ. 

ATC. 

PFZ. 

PFZ. 

RSA,    UCC. 

USE. 

ACY,    DOW. 

DOW. 

DOW. 

ACY,    DOW. 

DOW. 

KCC,    USR. 

ACY,    DOW. 

ACY,    DOW. 

DOW. 

ACY,    DOW. 

DUP,    EK,    GLY,    X. 

NOP,  PRP,  SYP, 


CEL,  COM,  DUP,  EKT,  EKX,  HPC,  MON,  PUB,  SHC,  UCC. 

ACP,  CLK,  HPC,  MON,  SHC,  SKO,  SOC. 

EKT,  ENJ,  SHC,  UCC. 

CEL,  DIX,  HPC. 

SHC,  UCC. 

UCC. 

CEL,  DEC,  ENJ,  SHC,  SPI,  UCC. 

CEL,  EKX,  UCC. 

DA,  FMB,  GGY,  MFO. 

SDW. 

ABB. 

EK,  MRK. 

CEL,  EKT,  UCC. 

GIV. 

BAX,  PFZ. 

UCC. 

EKX,  UCC. 

ACP,  BQR,  CBC,  GET ,  CCM,  DUP,  GAF,  GOC,  HKD,  HN,  : 

MON,  RGI,  RH,  TIU,  UCC. 
UCC. 
UCC. 
UCC. 

EKX,  GIV. 
RBG. 

CEL,  SHC,  UCC. 
EKX,  UCC. 
UCC. 

EKT,  UCC. 
GLN. 
SHC. 

EKT,  UCC. 

EKT,  ENJ,  SHC,  UCC. 
SHC,  UCC. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 


■  Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported  identified  0\ 
manufacturer,  i966--Continued 


MISCELLANEOUS  CHEMICAI3,    ACYCLIC— Continued 


ildehydes  and  Ketones- -Continued 


Methylpseudoionone 

2 -Methylvaleraldehyde  ( 2 -Methylpentaldehyde ) 

Ootanal,  tech. 

2-Ctetanone  (Hexyl  methyl  ketone) 

3-Ootanone  (Amyl  ethyl  ketone) 

Paraformaldehyde 

Paraldehyde  (Paracetaldehyde) 

2,4-Pentanedione  (Aoetylacetone) 

2-Pentanone  (Methyl  propyl  ketone) 

3-Pentanone  (Diethyl  ketone) 

Propionaldehyde 

Pseudolonone 

Pyruvaldehyde 

Tetrahydropseudolonone 

2,6,8-Trlmethyl-4-nonanone  (Isobutyl  heptyl  ketone) 
All  other 

Alcohols.   Monohydnc,    Unsubstituted 

»Aloohols  C9  or  lower: 

Allyl  alcohol 

Amyl  alcohols : 
Unmixed : 

2-Methyl-l-butanol 

2-Methyl-2-butanol  (tert-Amyl  alcohol)— 

3-Methylbatanol 

1-Pentanol 

2-Pentanol 

3-Pentanol 

Mixed: 

Fusel  oil,  refined 

Other  than  fusel  oil 

»Butyl  alcohols : 
Primary: 

»Iso  (Isopropylcarbinol) 

»Normal  (n-Propylcarbinol) 

Secondary  (Methylethylcarbinol) 

Tertiary  (Trimethylcarbinol) 

Mixed 

2,6-Dimethyl-4-heptanol  (Dlisobutylcarbinol) 

»Ethyl  alcohol,  synthetic 

2-Ethyl-l-butanol - - 

»2-Ethyl-l-hexanol 

2-Ethyl-4-methyl-l-pentanol 

4-Etlyrl-l-octyn-3-ol 

Heptyl  alcohol 

Hexyl  alcohol 

Hexynol 

»Iso-octyl  alcohols 

«Isopropyl  alcohols 

«Methanol,  synthetic 

2-Methyl-3-buten-2-ol 

2-Methyl-3-butyn-2-ol - 

■i -Methyl -2 -pen tanol  (1-Methylisobutyl  oarbinol)  — 

3 -Methyl -1 -pen tyn-3-ol  (Methylparafynol) 

1-Octanol 

2-Octanol   (sec-Capryl  alcohol) 

Octanols,   other 

Propyl  alcohol   (Propanol) 

2-Propyn-l-ol 

All  other  (Including  mixtures) 

»Aloohole  Cio  or  higher: 

1-Deoanol 

3,9-Diethyl-6-tridecanol 

Dodecyl  alcohol  (Lauryl  alcohol)  (95it) 

7-Ethyl-2-methyl-'i-hendecanol 


IFF. 

TBK,  WTH. 

TBK. 

CEL,  HN,  HPC. 

UCC. 

UCC. 

UCC. 

HEX. 

EKX,  UCC. 

GIV. 

UCC. 

GIV. 

UCC. 

CEL,  EK,  GIV. 


UCC. 
SHC. 
UCC. 
UCC. 
UCC. 
EK. 


DEC,  EKX,  ENJ,  SHC,  UCC. 

CEL,  CO,  DEC,  EKX,  ENJ,  SHC,  UCC. 

ENJ,  SHC. 

SHC. 

DEC,  EKX. 

UCC. 

CEL,  DUP,  EKX,  ENJ,  HPC,  SHC,  UCC,  USI. 

UCC. 

CEL,  EKX,  ENJ,  SHC,  UCC. 

EKX. 

cue. 

EKX. 

EKX,  ENJ,  UCC. 
cue,  LIL. 

ENJ,  GOC,  HOU,  0X0,  TID,  UCC. 

ENJ,  SHC,  UCC. 

ACN,  BOR,  CEL,  COM,  DUP,  ENJ,  ESC,  GOC,  HN,  HPC,  MON, 
RCI,  m,    TCC,  UCC. 

cue. 
cue. 

SHC,  UCC. 

cue. 

DUP. 

HH,  WTH. 

EKX,  PG. 

CEL,  UCC. 

GAF. 

CEL,  CO,  PG,  TNA. 

DUP,  TNA. 

UCC. 

DUP,  PG,  RH. 

UCC. 


MLSCtllANEOUS  CHEMICALS 


185 


TABLE  21B. 


-Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i 966 --Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


kOSCELLANEOUS  CHEMICALS,   ACYCUC— Continued 

Alcohols.    Monohydnc,    Unsubstituted~-Continued 
"Alcohols  Cio  or  higher--Continued 

1-Hexadecanol   (Cetyl  alcohol)   (955t) - 

Hexadeoyl  alcohols 

»l8odeoyl  alcohol 

1-Octadecanol   (Stearyl  alcohol)   (955t) - 

ois-9-Octadecen-l-ol   (Oleyl  alcohol) 

Tetradecyl  alcohols 

Trideoanol  mixed  isomers 

2,6,8-Trimethyl-<l-nonanol 

All  other  (Including  mixtures) 

folyhydric   Alcohols    and  Their   Esters    and  Ethers 

»ft)lyhydrlo  alcohols: 

1,4-Butanediol 

l,2(and  l,3)-Butanediol  (Butylene  glycol) 

2-Butene-l,4-diol 

2-Butyne-l,^-diol — 

3-Chloro-l,2-propanediol  (Glycerol  a-chlorohydrin) 

1,10-Deoanediol - 

2,5-DiJiiethyl-2,5-hexanediol - 

2,5-Dljiiethyl-3-hexyne-2,5-dlol— 

2,2-Dliiiethyl-l,3-propanediol  (Mopentyl  glycol)— 

•Ethylene  glycol 

2-Ethyl-l,3-hexanediol - 

2-Ethyl-2-(hydroxymethyl)-l,3-propanediol   (Trimethylol- 
propane ) . 

Glycerol,   synthetic 

1,6-Hexanedlol - 

1,2,6-Hexanetriol - - - 

2-(I^roxymethyl)-2-methyl-l,3-propanedlol  (Trimethylol- 
ethane). 

Mannltol - — 

3-Mercapto-l,2-propanediol  ( Thioglycerol ) 

Methylglycerol 

2-Methyl-2,'i-pentanediol  (Hexylene  glycol) 

2 -Methyl -2 -propyl -1,3 -propanediol 

1,9-Nonanediol - 

»Pentaerythrltol 

♦Propylene  glycol  (1,2-Propanediol) 

•Sorbitol - 

2,2,4-Trimethyl-l,3-pentanediol - 

•Polyhydrlc  alcohol  esters: 

1,3-Butanediol  dimethacrylate 

2-(2-Butoxyethoxy)ethyl  acetate 

2-Butoxyetliyl  acetate 

Diethylene  glycol  ohloroformate 

2-Ethoxyethyl  acetate 

Ethylene  glycol  diaoetate 

Ethylene  glycol  dimeroaptoaoetate 

Etl^lene  glycol  dimethacrylate 

Ethylene  glycol  hydroxyacetate 

2-Ethyl-l,3-hexanediol  titanate 

2 -Ethyl -2 ( hydroxymethyl ) -1, 3 -propanediol  trijnethacrylate 

Glyceryl  monoacetate  (Ifonoacetin) 

Glyceryl  triacetate  (Trlaoetin) 

Glycol  adipate 

Hexanetriol  octoate 

Hjrdroxyethyl  methacrylate 

I^rdroxypropyl  methacrylate 

Hydroxypivalyl  hydroxypivalate 

2-Methoxyethyl  acetate 

Uethoxytriethyleneglycol  acetate 

Pantaerythrltol  caprylate 

Pentaerythrltol  pelargonate 

Polyethylene  glycol  dimethacrylate 

Propylene  glycol  diaeetate 


ADM,  DUP,  GIV,  RH. 

ENJ,  PG. 

ENJ,  GOC,  HOU,  QXO,  TID,  UCC. 

ADM,  DUP,  PG,  HH. 

ADM,  DUP. 

PG. 

ENJ,  GOC,  HOU,  TID,  UCC. 

UCC. 

ADM,  CO,  EKX,  GYR,  PG,  RH,  SHC,  TNA,  x. 


GAP. 
CEL. 
GAF. 
GAP. 

EVN,  ore. 


cue. 
cue. 

EKX. 

ACP,  APD,  CAU,  CEL,  DCW,  DUP,  EKX,  GAF,  HCH,  JCC,  CMC, 

UCC,  wra. 

UCC. 
CEL. 


APD, 

DOW, 

SHC. 

CEL. 

UCC. 

TRJ. 

APD. 

EVN. 

APD. 

CEL, 

SHC, 

UCC. 

ABB, 

BKL, 

ICO. 

ASM. 

CEL. 

COM, 

HN,   HPC,    RCI,   TRJ 

APD, 

CEL, 

DOW,    DUP,    JCC,    (M 

APD, 

BRD, 

MRK,    PFZ. 

EKX. 

SAR. 

UCC. 

UCC. 

PPG. 

DOW, 

EKT, 

UCC. 

UCC. 

EVN. 

SAR. 

CCA. 

DUP. 

SAR. 

ARC, 

HAL. 

EKT, 

UCC. 

x. 

ARC. 

AAC. 

JCC. 

EKX. 

UCC. 

RBC. 

DRW. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  21B.  --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  1966 — Continued 


Manufacturers '    identification  codes 
(according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICAI5,   ACyCLIC--Continued 

Polyhydnc   Alcohols  and  Their   Esters    and  £t/iers  — Continued 

»ft3lyhydric  alcohol  esters— Continued 

Sucrose  oota -acetate 

Tetraethylene  glycol  dimethacrylate 

Triethylene  glycol  dimethacrylate 

Tri(hexylene  glycol)  biborate 

2,2,'4-Trimethyl-l,3-pentanediol  monoisobutyrate 

All  other — — ■ 

»Polyhydric  alcohol  ethers : 

3-(Allyloxy)-l,2-propanedlol  (Allyl  glyceryl  ether) ■ 

Bis(2-butoxyethyl)  ether  (Diethylene  glycol  di-n-butyl 

ether). 
Bis(2-ethoxyetliyl)  ether  (Diethylene  glycol  diethyl 
ether). 

Bis(hydroxyethyl)  ether  butynediol 

Bis[2-(2-methoxyethoxy)ethyl]  ether  (Tetraethylene 

glycol  dimethyl  ether). 
Bis(2-methoxyethyl)  ether  (Diethylene  glycol  dimethyl 
ether) . 

»2-Butoxyethanol  (Ethylene  glycol  monobutyl  ether) 

*2-(2-Butoxyethoxy)ethanol  (Diethylene  glycol  monobutyl 
ether). 
2-[2-(2-Butoxyethoxy)ethoxy]ethanol  (Triethylene  glycol 
monobutyl  ether). 

l-Butoxyethoxy-2-propanol > 

1,2-Dlbutoxyethane  (Ethylene  glycol  di-n-butyl  ether) — ... 

♦Diethylene  glycol 

Dletl^lene  glycol,  borated 

Dime thoxy ethane  (Ethylene  glycol  dimethyl  ether) 

»Dlpropylene  glycol 

»2-Ethoxyethanol  (Ethylene  glycol  monoethyl  ether) 

»2-(2-Ethoxyethoxy)ethanol  (Diethylene  glycol  monoethyl 
ether). 

<<2-[2-(2-Ethoxyethoxy)ethoxy]ethanol  (Triethylene  glycol 
monoethyl  ether). 
Ethoxypropanol 

•Glycerol  tri(polyoxypropylene)  ether 

2-[2-(Hexyloxy)ethoxy]ethanol 

l-Isobutoxy-2-propanol  (Propylene  glycol  Isobutyl  ether) 
Isobutoxyethanol 

»2-Methoxyethanol  (Ethylene  glycol  monomethyl  ether) 

»2-(2-Methoxyethoxy)ethanol  (Diethylene  glycol  monomethyl 
ether). 

»2-[2-(2-Msthoxyethoxy)ethoxy]ethanol  (Triethylene  glycol 
monomethyl  ether). 
2-(2-Methoxyethoxy)ethyl  2-metho2yethyl  ether  (Triethy- 
lene glycol  dimethyl  ether). 
Methoxypolyethylene  glycol 

»l-Methoxy-2-propanol 

3-(3-Methoxypropoxy)propanol 

3-[3-(3-Methoxypropoxy)propoxy]propanol 

Methyl  butynoxyethanol 

Polyethoxyethylglycerol 

Polyethoxyethylsorbitol 

♦Polyethylene  glycol 

Polypropoxy  ethers 

♦Polypropylene  glycol 

Polytetramethylene  ether  glycol 

Tetraethylene  glycol 

1,1,3,3-Tetramethoxypropane 

2,2'-Thlodlethanol  (Thlodlglycol) 

♦Triethylene  glycol 

Tripropylene  glycol 

All  other 

Esters   of  Monohydric  Alcohols 

Allyl  methacrylate 


PD. 
SAP. 
SAP. 
USB. 
EKX. 
EK,    TNI. 


DOW,    JCC,    CMC,    SHC,    UCC. 
DOW,    JCC,   CMC,    SHC,    UCC. 


DOW, 

OMC, 

UCC. 

UCC. 

UCC. 

ACP, 

CAU, 

DIX, 

DOW, 

EKX, 

GAF, 

HCH, 

JCC, 

GU. 

A.ST,. 

CEL, 

DOW, 

JCC, 

OMC, 

UCC, 

WYN. 

DOW, 

JCC, 

OMC, 

UCC. 

DOW, 

JCC, 

OMC, 

UCC. 

DOW, 

OMC, 

UCC. 

UCC. 

JCC, 

OMC, 

UCC, 

WYN. 

UCC. 

DOW. 

UCC. 

DOW, 

JCC, 

OMC, 

UCC. 

DOW, 

JCC, 

CMC, 

UCC. 

DOW, 

OMC, 

UCC. 

ASL. 

JCC, 

UCC. 

DOW, 

SHC, 

UCC. 

DOW, 

UCC. 

DOW. 

cue. 

GLY. 

au. 

ACP, 

DOW, 

DUP, 

GAF, 

JCC, 

OMC, 

UCC, 

WIN 

ACS, 

DOW, 

WYN. 

DOW, 

JCC, 

NLC, 

OMC, 

UCC, 

WXN. 

QKO, 

X. 

DOW. 

UCC. 

KF. 

PIC, 

UCC. 

ACP, 

CAU, 

DOW, 

GAF, 

HCH, 

JCC, 

CMC, 

UCC. 

DOW, 

UCC. 

DOW, 

UCC, 

WIN. 

MISCELLANEOUS  CHEMICALS 


187 


TABLE  21B.  --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i 566- -Continued 


Manufacturers'   identification  codes 
(according  to  list  in  table  22) 


MISCELUNEOUS  CHaCCALS,  ACYCLIC— Continued 
Esters    of  Monohydric   4 (coho is--Contlnued 

Amyl  acetates,  90^: 

Amyl  acetate  (n-Pentyl  acetate) 

Isopentyl  acetate  (Isoamyl  acetate) 

Mixed - - - - - 

»Butyl  acetates: 

ISO 

»Normal 

Secondary 

Tertiary -- 

Mixed - 

Butyl  acrylate 

Butyl  chloroacetate 

n-Butyl  a-hydroxy-a-methylbutyrate 

Butyl  lactate 

tert-Butyl  peroxyacetate . 

tert-Butyl  peroxy-2-ethylhexanoate 

tert-Butyl  peroxyisobutyrate 

t^rt-Butyl  peroxylsopropyloarbonate 

tert-Butyl  peroxyplvalate 

Cetyl  lactate 

Diallyl  maleate 

Dibutyl  fumarate 

*Dlbutyl  maleate - 

Diethyl  sec-butylethylmalonate 

Diethyl  butylmalonate 

Diethyl  sec -butylmalonate 

Diethyl  carbonate  (Ethyl  carbonate) 

Diethyl  dlethylmalonate  (Diethyl  malonic  ester) 

Diethyl  (ethoxymethylene)malonate 

Diethyl  ethylisopentylmalonate 

Diethyl  ethylmalonate  (Ethyl  malonic  ester) 

Dietl^l  ethyl(l-methylbutyl)malonate  (Ethyl  1-methyl  butyl 
malonic  ester). 

Diethyl  ethyl (l -me thy lpropyl)malonate 

Dl(2-ethyl-l-hexyl)  fumarate 

Di(2-ethyl-l-hexyl)  maleate - — - 

Diethyl  maleate 

Diethyl  malonate  (Malonic  ester) 

Dletl^l  (l-methylbutyl)malonate 

Diethyl  methylmalonate 

Diethyl  (l-methylpropyl)malonate 

Diethyl  oxalate  (Ethyl  oxalate) 

Diethyl  succinate 

Di-iso-nonyl  maleate 

Diiso-octyl  fumarate 

Diisopropyl  peroxydlcarbonate  (Isopropyl  percarbonate) 

*Dllauryl  3,3'-thiodiproplonate— 

Dimethyl  acetylenedlcarboxylate 

Dimethyl  carbonate 

2,5-Diiaethylhexane  2,5-diperoctoate 

Dimethyl  malonate 

Dl(4-methyl-2-pentyl)  maleate 

Dioctyl  maleate 

Distearyl  3,3'-thlodipropionate 

Dlthiobis(stearyl  propionate) 

Ditridecyl  maleate 

Di(tridecyl)  3,3'-thlodipropionate — 

2-(2-Ethoxyethoxy)ethyl  acetate 

»Ethyl  acetate  (85^) — 

Ethyl  acetoacetate 

»Ethyl  acrylate 

Ethyl  chloroacetate 

Ethyl  chlorof ormate 

♦Ethylene  carbonate 

Ethyl  formate 

2-Ethyl-l-hexyl  acetate — 

2-Ethyl-l-hexyl  aciylate 


NW,    TBK. 

CEL,    ENJ, 

UCC. 

EKT,    ENJ, 

UCC. 

CEL,    EKT, 

ENJ, 

PUB,    SHC,    UCC. 

ENJ,    HPC, 

PUB, 

SHC. 

ENJ. 

CEL. 

CEL,    DBC, 

UCC. 

MON. 

BPC. 

COM. 

WTL. 

WTL. 

WTL. 

PPG. 

WTL. 

VND. 

PMP. 

MON,    PFZ, 

RCI, 

RUB. 

cue,    DUP, 

MON, 

RCI,    RUB. 

ABB. 

BPC. 

ABB. 

CTN,    FMP. 

BPC,    LIL. 

KF. 

LIL. 

LIL. 

ABB,   BPC. 

BPC. 

RUB. 

HUB. 

ACY,    UCC. 

ABB,    KF, 

LIL. 

ABB,    LIL. 

BPC. 

BPC. 

MP. 

ICO. 

RUB. 

RUB. 

PPG. 

ACY,    CCW, 

EVN, 

HAB. 

EK. 

CTN. 

UPR. 

KF. 

RUB. 

HET,   MON, 

PCC. 

ACY,    CCW, 

EVN. 

EVN. 

RUB. 

ACY,    EVN. 

UCC. 

CEL,    EKT, 

ENJ, 

HPC,    MON,    PUB,    UCC 

EKT,    UCC. 

CEL,    DBC, 

RH, 

JCC. 

DOW,    KF, 

MON. 

CTN,    FVP. 

DOW,    JCC, 

UCC. 

COM. 

EKT,    UCC. 

CEL,   DBC, 

UCC. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were 
manufacturer,  iS>66— Continued  


eported,  identified  by 


MISCELLANEOUS  CHEMICAI5,  ACYCUC- -Continued 


of  Monohydr 


-Continued 


2-Ethyl-l-hexyl  methacrylate ""■"": 

Ethyl  2-hydroxy-3-methylbutyrate  (Ethyl  hydroxylsovalerate ; 

Ethylidene  diaoetate- - " " 

Ethyl  propionate 

Ethyl  silicate  ( Tetraethoxysilane ) — - 

Ethyl  sulfate  (Diethyl  sulfate) - 

Ethyl  thioglycolate-- -- - 

Fatty  acid  esters,  not  included  with  plastiolzers  or  sur- 
face-active agents: 

Butyl  palmitate 

Dimethyl  brassylate 

Ethyl  stearate 

Hexadecyl  stearate 

Isopropyl  linoleate 

Methyl  esters  of  coconut  oil 

Methyl  esters  of  cottonseed  oil 

Methyl  esters  of  tallow 

Methyl  12 -hydroxys  tearate—- - - ■ 

Methyl  myristate 

All  other - "- ' 

Isobutyl  acrylate 

Isobutyl  isobutyrate 

Isobutyl  undecylenate 

Isodecyl  acrylate 

»Iso-octyl  mercaptoaoetate 

Iso-octyl  3-meroaptopropionate 

»Isopropyl  acetate 

Isopropyl  chloroformate 

Lauryl  lactate 

Methallylidlne  diacetate 

»Methyl  acetate - 

Methyl  acetoacetate 

Methyl  acrylate,  monomer 

Methyl  borate 

Methyl  chloroacetate 

Methyl  chloroformate 

Methyl  dichloroacetate 

Methyl  formate 

Methyl  methacrylate,  monomer 

4-Methyl-2-pentyl  acetate— — 

Methyl  sulfate  (Dimethyl  sulfate) -- 

Methyl  vinyl  acetate 

Myristyl  lactate - 

Octadecyl  3-mercaptopropionate 

*Phosphorus  acid  esters: 

Bis(2-ethylhexyl)  hydrogen  phosphate — - 

Butyl  phosphates 

Chloropropyl  phosphorothioate 

Dibutyl  butylphosphonate 

Dibutyl  hydrogen  phosphate 

Didodecyl  hydrogen  phosphate 

Diethyl  phosphorochloridothionate 

Dimethyl  methylphosphonate 

Dimethyl  phosphorochloridothionate 

Ethyl  phosphates 

Iso-octyl  hydrogen  phosphate 

Isopentyl  octyl  hydrogen  phosphate 

Methyl  phosphates  — - - " 

Pentyl  phosphates  (Amyl  phosphates) 

Tributyl  phosphate 

Tributyl  phosphite 

Tridecyl  phosphite 

Trietl^l  phosphite 

Triiso-octyl  phosphite - " 

Trimethyl  phosphate 

Trimethyl  phosphite 

Tris(2-ohloroethyl)  phosphite 

Trls(2,3-dibromopropyl)  phosphate 


Manufacturers'  identification  codes 
(according  to  list  in  table  22) 


RH. 

GEL. 

NW,  TBK. 

MTR,  SFA,  UCC. 

UCC. 

EVN. 


ICO. 

ARC,  ICI. 

VND. 

HUM,  PG. 

BFR. 

BFR,  CHL,  HUM. 

BAG,  HUM. 

HUM. 

EMR,  GLY,  GRO,  PCS,  RT,  SUG. 

DEC. 

EKX. 

GIV. 

UCC. 

CCW,  EVN,  HAB. 

EVN. 

EKT, 

CTN, 

VND. 

UCC. 

BOR, 

EKT, 

CEL, 

CAL, 

DOW, 

CTN. 

KF, 

DUP. 

ACY,  DUP,  RH. 

PUB,  SHC,  UCC. 

DUP. 

UCC. 

VND. 

EVN. 


ENJ,  HPC,  UCC. 
PPG. 


EK,  MON,  UCC. 
UCC'. 

DEC,  RH. 
MHI,  SFA. 
KF. 

PD. 


HK,  SF,  X 

SF. 

COM,  MP. 


MISCELLANEOUS  CHEMICALS 


TABLE  21B.  --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were 
manufacturer,  i566--Contlnued 


sported,  identified  by 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


MISCELLANEOUS  CHEMCALS,    ACYCLIC— Continued 
filers   of  Monohydric   4  ico/iois--Cont  Inupd 

"Phosphorus  acid  esters — Continued 

Tris(2-ethylhexyl)  phosphite 

Tris(octadecyl )  phosphite 

All  other -  — 

Propyl  acetate 

Propylene  carbonate 

Tetraoctyl  orthosilicate- 

Titanic  acid  esters: 

Tetrabutyl  titanate 

Tetraisopropyl  titanate 

Tetrald.s(2-ethylhexyl)  titanate -- -- 

Other - 

Triethyl  borate 

Triethyl  orthoacetate 

Triethyl  orthoformate- 

Triethyl  orthopropionate 

Triisodeoyl  orthoformate 

Trimethyl  orthoformate 

»Vinyl  acetate  monomer 

All  other— 

Halogenaled  Hydrocarbons 

1-Bromobutane  (n-Butyl  bromide) 

2-Brcniobutane  (sec-Butyl  bromide) 

Bromochloromethane 

l-Bromo-3-chloropropane  (Trimethylenechlorobromlde)  - 

2-Bromo-2-chloro-l,l,l-trifluoroethane 

l-Bromododecane 

Bromoethane  (Ethyl  bromide) 

l-Bromohexane  (n-Hexyl  bromide) 

l-Bromo-3-methylbutane  (Isoamyl  bromide) 

1-Bromo-octadecane 

1-Bromopentane  (n-Amyl  bromide) 

2-Bromopentane  ( 1-Methylbutyl  bromide) 

1-Bromopropane  (n-Propyl  bromide) 

2-Bromopropane  (Isopropyl  bromide) 

3-Bromopropene  (Allyl  bromide) 

Brcmotrichlorome thane 

Brcanotrifluorome  thane 

»Carbon  tetrachloride 

"Chlorinated  paraffins : 

less  than  35^  chlorine 

35^-6^^  chlorine - 

65%  or  more  chlorine 

1-Chlorobutane  (n-Butyl  chloride) 

2-Chlorobutane  (sec-Butyl  chloride) 

l-Chloro-l,l-difluoroethane 

"Chlorodifluorome thane 

»Chloroethane  (Ethyl  chloride) 

"Chloroform 

2-Chloro-3-hexyne 

"Chlorome thane  (Methyl  chloride) 

2-Chloro-2-methylpropane  (tert-Butyl -chloride) 

3-Chloro-2-methylpropene  (Methallyl  chloride)- -- 

Chloropentafluoroethane 

3-Chloropropene  (Allyl  chloride) 

Chlorotrlfluoroethylene  (Trifluorovinyl  chloride) 

Chlorotrifluoroethylene,  polymerized 

Chlorotrlfluorome thane 

l,2-Dibramo-l,l-dichloroe thane 

Dibromodifluorome thane 

1,2-Dibromoethane  (Ethylene  dibromide) 

Dibromoethane  (Methylene  bromide) 

Ij-i-Dibromopentane 

l,2-Dibromo-l,l,2,2-tetrafluoroethane 

Dlchlorobutadiene 

1,^-Dichlorobutene 


DUP,    ENJ, 

MON, 

X. 

CEL,    EKT, 

ENJ, 

PUB, 

ucr, 

DOW,    JCC. 

MON. 

DUP. 

DUP. 

DUP. 

DUP. 

USB. 

EK,    KF. 

KF. 

BOR,  CEL,  cue,  DUP,  MON,  NSC,  UCC. 
DUP,  EK,  HAB,  PCC,  RH,  SAR. 


«PC, 

CIB 

MCH 

ABB 

BPC 

DOW 

DOW 

MCH 

ICI. 

DUP. 

DOW 

MCH 

BPC. 

BPC, 

IJL 

DUP, 

OAF 

BPC, 

CLB 

ABB, 

LIL. 

BPC, 

CIB 

EK. 

BPC. 

CLB, 

DOW. 

MCH. 

DUP. 

ACS, 

DA, 

DOW, 

FMB,    FRO,    PPG,    SF. 

HK. 

CCH, 

DA, 

DVC, 

HK,    HPC,    KEI,    KPS,    WOI. 

DA, 

DVC, 

WOI. 

PUB, 

UCC. 

PLC. 

ACQ, 

DUP. 

ACQ, 

DUP, 

KAI, 

PAS,    UCC. 

AME, 

DOW, 

DUP 

HPC,    PPG,    SHC,    TNA,    USI 

ACS, 

DA, 

DOW, 

DUP,    FRO,    SF. 

LIL. 

ACS, 

Am, 

DCC 

DOW,    DUP,    FRO,    TNA,    UCC 

CLB, 

EK. 

FMP. 

DUP. 

DOW, 

SHC. 

ACQ, 

MMM. 

HK, 

ItM. 

ACO, 

DUP, 

PAS. 

DOW. 

DOW. 

DOW, 

ETD, 

HCH, 

MCH. 

DOW. 

SDW. 

DUP. 

DUP. 

DUP. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Miscellaneous  chemicals  for  which  U.S.  production  or  i 
manufacturer,  i966--Contlnuecl 


were  reported,  identified  by 


Manufacturers'   identifieation  eodes 
(according  to  list  in  table  22) 


MISCELLANEOUS  CHiMICALS,   ACYCUC— Continued 
Halogenated  Hydrocarbons — Continued 

»Dichlorodifluorome  thane 

»l,2-Dichloroethane   (Ethylene  diohlorlde) - 

»Dlohloromethane   (Methylene  chloride) 

»l,2-Dlchloropropane   (Propylene  dichloride) 

2,3-Diohloropropane 

»Dichlorotetrafluoroethane 

1,1-Difluoroe thane 

Wfluorotetrachloroethane 

Diiodomethane   (Methylene  iodide) 

Hexachloroethane 

Hexafluoropropylene,   monomer 

lodoethane   (Ethyl  iodide),   tech 

Iodoform  (Triiodomethane) ,   nonmedioinal 

lodomethane   (Methyl  iodide) 

1-Iodoperfluorohexane 

lAuryl  chlorides 

Ootafluorocyclobutane 

1,1,2,2-Tetrabromoethane   (Acetylene  tetrabromide ) 

Tetrabromoe thane 

1,1,2,2-Tetraohloroethane   (Acetylene  tetrachloride) 

»Tetrachloroethylene   ( Perchloroethylene ) 

Tetrafluoroetf^lene,   monomer 

Tetrafluoroethylene,   polymer 

Tetrafluorcmethane 

»l,l,l-Trichloroethane   (Methyl  chloroform) 

1,1,2-Trlchloroethane   (Vinyl  trichloride) 

»Trichloroethylene 

»Trichlorofluoromethane 

1,2,3-Trichloropropane 

1,2,3-Trichloropropene 

Trichlorotrifluoroe thane 

»Vinyl  chloride,  monomer  ( Chloroethylene ) 

Vinyl  fluoride ■ 

Vinylidene  chloride,  monomer   (1,1-Dlohloroethylene) 

Vinylidene  fluoride 

All  other ■ 

All   Other  Miscellaneous  Acyclic  Chemicals 

Acetyl  peroxide 

Alkyl  sulfides,  mixed 

Aluininum  isopropoxide  (Alunilnum  isopropylate ) 

*2-Butanone  peroxide 

»tert-Butyl  hydroperoxide 

*tert-Butyl  peroxide  (Di-tert-butyl  peroxide) 

Butyrolactone 

Caprolaotone 

»Carbon  disulfide 

Carbonyl  sulfide 

»2-Chloroethanol  (Ethylene  chlorohydrln ) 

l-Chloro-2-propanol 

»Decanoyl  peroxide 

Dextran 

Dlaldehyde  starch 

Diohloropropanol 

Diethylthiophosphoryl  chloride 

2,4-Dlhydroxy-3,3-dlmethylbutyric  acid,   gammalactone 
(Pantolactone). 

2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane 

2,5-Dlmethyl-2,5-di(tert-butylperoxy)hexyne-3 

•I^ioxides,  ethers,  and  acetals: 

Acetone  dimethylacetal   (2,2-Dijnethoxypropane) 

l-(Allyloxy)-2,3-epoxypropane   (Allyl  glycidyl  ether)—- 

Bls(2-chloroethoxy)methane   (Dlchloroethylfonual) 

Bis(2-chloroethyl)   ether  (Dlohlorodiethyl  ether) 


ACG,    DUP,    KAI,    PAS,   UCC. 

AME,   BPG,    DA,    DOW,    DUP,    JCC,   MON,    CMC,    PPG,    TNA,    UCC. 
ACS,    DA,    DOW,   DUP,    FRO,    HK,    SF. 
DOW,    JCC,   UCC. 
DOW,    UCC. 

ACG,   DUP,    PAS,    UCC. 
ACG,   DUP. 
DUP. 

NTB,    SDW. 
NES. 
DUP. 

CLE,    EK,    FMT. 
NTB. 

CI£,  EK,  FMT,  aSA. 
x. 
HK. 
DUP. 
DOW. 
DCW. 
DUP. 

DA,    DOW,    DUP,    FRO,    HK,    PPG,    SF,    TTX. 
DUP. 
DUP. 
DUP. 

DOW,    HK,    PPG,    TNA. 
DOW,    UCC. 

DOW,   DUP,   HK,   PPG,   TTX. 
ACG,    DUP,    KAI,    PAS,    UCC. 
DOW,    SHC. 
DOW. 

ACG,   DUP,    PAS,    UCC. 

ACS,    AME,    BFG,    CUC,   DA,    DOW,    GNT,    GYR,    HN,   MNO,   MON, 
TNA,    UCC. 

DOW,    TNA. 

BFG,    GIB,    DUP,    EK,    KPS. 


WTL. 

ORO. 

CHT. 

AZT, 

CAD, 

NOC, 

RCI, 

UPR, 

WTL. 

AZT, 

CAD, 

UPR, 

WTL. 

AZT, 

CAD, 

RCI, 

SHC, 

UPR, 

WTL. 

GAF. 

UCC. 

BKT, 

BMB, 

PAS, 

PPG, 

SF. 

TKL. 

CMC, 

TKL, 

UCC. 

EK. 

CAD, 

UPR, 

WTL. 

PHR. 

MLS. 

EK, 

ICO. 

ACY. 

CKL. 

WTL. 

WTL. 

DCW. 

DOW, 

SHC. 

TKL. 

DOW, 

UCC. 

MISCELLANEOUS  CHEMICALS 


TABLE  21B.  --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i566- -Continued 


Manufacturers'    identification  codes 
(according  to  list  in  table  22) 


MISCELLANEOUS  CHmiCAlS,   ACYCLIC— Continued 


,llo 


i(s  — Cont 


All   0th. 

•Epoxides,  ethers,  and  acetals — Continued 

Bis(2-ohloro-l-methylethyl)  ether  (Dichloroisopropyl 
ether). 

l-Butoxy-2,3-epoxypropane  (Butyl  glycidyl  ether) 

Butylene  oxide 

Butyl  ether  (Di-n-butyl  ether) 

Butyl  \dnyl  ether 

2-Chloro-l,l-dimethoxyethane  (Dimethyl  ohloracetal)- 

2-Chloroethyl  vinyl  ether 

Chloromethyl  methyl  ether 

2,2-Dichloro-l,l-difluoroethyl  methyl  ether 

Epichlorohydrin 

•Ethylene  oxide 

•Ethyl  ether: 

Absolute 

Tech — 

U.S.P— - 

Ethyl  vinyl  ether 

Olycidol  (2,3-Epoxy-l-propanol) 

Glyoxal  ethylene  glycol  bis  acetal 

Isobutyl  vinyl  ether 

•Isopropyl  ether 

Methylal  ( Dime thoxyme thane) 

•Methyl  ether  (Dimethyl  ether) 

Methyl  vinyl  ether — 

Octadecyl  vinyl  ether 

Polychlorinated  propyl  ether 

•Propylene  oxide 

Other - - -, 

Ethanedithiol — - 

Ethanethiol - - 

2-(Ethylmercapto)ethanol 

Fats  and  oils,   chemically  modified 

Gluoono -delta-lac tone 

Glucoheptonolactone 

Glutaraldehyde  bis(sodiujn  bisulfite) 

Glyoxal,   sodium  bisulfite 

Hexachlorodimethyl  sulfone 

n-Hexadecyl  disulfide 

I^drocarbons : 

1-Butyne   (Ethylacetylene) 

n-Dodecane 

Ethylene,  from  ethyl  alcohol,  medicinal  grade 

Hexadeoane 

J^cene 

n-Octane 

1-Ootadeoene 

Kand  2)-0ctene 

Propyne  (Methylacetylene) 

Other - - 

•Lauroyl  peroxide 

Magnesium  methylate 

Methanesulfanol 

Methyl  disulfide - 

Methyl  sulfide  (Dimethyl  sulfide)- 

Methyl  sulfoxide - - 

n-Ootadecyl  mercaptan 

1-Ootanethiol  (n-Octyl  mercaptan) 

Organo-aluminum  compounds : 

Ethylalumlnum  chlorides 

Isobutylaluminum  chlorides 

Uethylaluminum  chlorides 

Other 

Organo-boron  compounds 

Organo-lead  ccanpounds ; 

•Tetraethyllead - - — 

•Tetraaethyllead - - — - 

Tetra(me  thyl -ethyl  )lead - 


DOW. 

SHC. 

DOW,  UCC. 

UCC. 

UCC. 

LIL. 

UCC. 

HK,  RH. 

DOW. 

CBA,  DOW,  SHC. 

ACP,  CAU,  DOW,  EKX,  GAF, 

MAL. 

ENJ,  HPC,  UCC,  USI. 

MAL,  QMS. 

UCC. 

DEC. 

FIN. 

GAF. 

ENJ,  SHC,  UCC. 

CEL. 

COM,  DUP,  UCC. 

GAF,  UCC. 

GAF. 

JCC. 

CEL,  DOW,  JCC,  CMC,  UCC, 

EK,  EVN,  JCC,  PIC. 

RBC. 

EK. 

PAS. 

ABB,  BCN,  CHL,  DOM,  RT,  ; 

PFZ. 

PEN. 

IDC. 

CFC. 

SFA. 

PAS. 


HCH,  JCC,  OMC,  SNO,  UCC,  WYN. 


HMY. 

WTH. 

cue. 

cue, 

OOC, 

HMY. 

AZT, 

CAD, 

UPR, 

WTL. 

MRT, 

SFA. 

PAS. 

CRZ. 

CBZ, 

PAS. 

cm. 

HMY. 

PAS. 

TNA, 

TSA. 

TNA, 

TSA. 

TNA, 

TSA. 

ISA. 

ACG, 

CAL, 

SFA. 

DUP, 

HCH, 

NI£, 

TNA. 

DUP, 

HCH, 

NLC, 

TNA. 

DUP, 

TNA. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


-Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported,  identified  by 
manufacturer,  i 966- -Continued 


Manufacturers'   identification  codes 

(according  to  list  in  table  22) 


MISCELLANEOUS  CHEMICALS,   ACYCUC— Continued 


U!  Othi 


•Ma 


die   Che 


-Continued 


Organo-lithlum  compounds 

Organo-magnesium  halides 

Organo-meroury  compounds 

Organo-sillcon  compounds 

Organo-tin  compounds : 

Bis(trlbutyltin)  oxide— - 

Dlbutyltin  dichlorlde 

Dibutylmethoxytin  (Dlbutyl  tin  methoxide) 

Other - - 

Organo-zino  ccmpounds 

Perchlorcmethanethiol  ( Perchloromethyl  mercaptan) 
Perlargonyl  peroxide 

*Phosgene  (Carbonyl  chloride) 

Pine  oil,  synthetic 

Polyethylene  polysulfide 

Propanone  peroxide  (Acetone  peroxide) 

Propionyl  peroxide 

Rare  sugars 

Sodium  ethoxide 

Sodium  formaldehyde  bisulfite 

■»Sodium  formaldehyde  sulfoxylate 

»Sodium  methoxide  (Sodium  methylate) 

Sodium  octylate 

Suocinyl  peroxide 

Tetrakis(hydroxymethyl)phosphonlum  chloride 

Tributylphosphine 

Trideoyl  mercaptan 

Trioctylphosphlne  oxide 

»Zino  formaldehydeaulfoxylate 

Other - 


FTE. 

AHA,  x. 

LIL,  NTB. 

Dec,  ORO,  SF,  SPD,  UCS. 

CCW,  X. 

CCW,  X. 

CCA. 

CCW,  X. 

TNA. 

CHO. 

WTL. 

CTN,  DUP,  MOB,  MAC,  CMC,  OTC,  PPG,  RUC,  UCC,  OPJ,  VDM. 

CBY. 

BFG. 

SDH. 

WTL. 


EK,  IDC. 

HSH,  NOP,  RH,  ROY. 

BFR,  DA,  DUP,  HSH,  KF,  QMC,  RBC,  SFA. 

FIN. 

WTL. 


NOP,  RH,  ROY. 

ACY,  AID,  AIX,   AHA,  CCA,  CCW,  CWN,  DCC,  DUP,  EK,  EKX, 

ENJ,  FER,  ICO,  KF,  UL,  PFN,  PRN,  SF,  SNW,  SYP,  TNA, 

UCC,  x',  X,  X,  X. 


DIRECTORY  OF  MANUFACTURERS 


Directory  of  Manufacturers 

The  Directory  of  Manufacturers  lists  the  companies  that  report  their  production  of  synthetic 
organic  chemicals  to  the  U.S.    Tariff  Commission.   The  name  of  each  manufacturer  is  preceded 
by  an  alphabetical  identification  symbol.   These  identification  symbols  consist  of  not  more  than 
three  capital  letters,    and  usually  bear  a  relation  to  the  compamy  name. 

For  1966,  the  Directory  of  Manufacturers  lists  approximately  825  primary  manufacturers 
(see  table  22).  Some  of  the  companies  that  report  production  of  synthetic  organic  chemicals  do 
not  sell  the  materials,    but  consume  their  entire  output  in  further  manufacturing. 

The  Directory  of  Manufacturers  lists  the  reporting  companies  in  two  ways:  Section  1  lists 
them  in  alphabetical  order  by  identification  symbols;  section  2  lists  the  reporting  companies  in 
alphabetical  order  by  company  name,  and  gives  the  corresponding  identification  symbol  and  the 
company  address.    Company  divisions  are  usually  listed  under  the  parent  company's  name. 


TABLE  22. --Synthetic  organic  chemicals.-  Directory  of  manufacturers ,  1966 


SECTION  1.      ALPHABEnCAL  DIRECTORY  BY  CODE 
[Names  of  synthetic  organic  chemical  manufacturers  that  reported  production  or  sales  to  the  U.S.   Tariff  Commission 
for  1966  are   listed  below  In  the  order  of  their   identification  codes  as  used  in  tables   in  pt.    III.   Section  2  of 
this  table   lists  these  manufacturers  alphabetically  and  gives  their  office  addresses.] 


Code 

Code 

Identi- 

Name of  company 

identi- 

Name of  company 

fication 

fication 

AAC 

Alcolac  Chemical  Corp. 

ARC 

Argus  Chemical  Corp. 

AAE 

American  Aniline  &  Extract  Co.,  Inc. 

ARK 

Armstrong  Cork  Co. 

AAI 

American  Aliyd  Industries 

ARL 

Arol  Chemical  Products  Co. 

AAP 

American  Aniline  Products,  Inc. 

ARM 

Armour  Agricultural  Chemical  Co. 

ABB 

Abbott  Laboratories 

ARN 

Arenol  Chemical  Corp. 

ABS 

Abex  Corp.,  American  Brakeblok  Div. 

ARP 

Armour  Pharmaceutical  Co. 

ACB 

Allied  Chemical  Corp.,  Barrett  Div. 

ARZ 

Arizona  Chemical  Co. 

ACC 

Amoco  Chemicals  Corp. 

ASH 

Ashland  Oil  &  Refining  Co. 

ACE 

Acme  Chemical  Co. 

ASL 

Ansul  Chemical  Go. 

ACG 

Allied  Chemical  Corp.,  General  Chemical  Div. 

AST 

ACI 

Aceto  Industrial  Chemical  Corp. 

ASY 

American  Synthetic  Rubber  Corp. 

ACN 

Allied  Chemical  Corp.,  Agricultural  Div. 

ATC 

American  Tartars  Corp. 

AGP 

Allied  Chemical  Corp.,  Plastics  Div. 

ATL 

Atlantic  Chemical  Corp. 

ACR 

Acme  Resin  Corp. 

ATP 

Atco  Chemical-Industrial  Products,  Inc., 

Fine 

ACS 

Allied  Chemical  Corp.,  Solvay  Process  Div. 

Chemicals  Div. 

ACT 

Arthur  C.  Trask  Co. 

ATR 

Atlantic  Richfield  Co.,  ARCO  Chemical  Co 

Div. 

ACU 

Allied  Chemical  Corp.,  Union  Texas  Petroleum 

ATU 

Atlantic  Tubing  &  Rubber  Co. 

Div. 

AUG 

Augusta  Chemical  Go. 

ACY 

American  Cyanamid  Co. 

AV 

FlC  Corp.,  American  Viscose  Div. 

ADM 

ADM  Co. 

AVS 

Avisun  Corp. 

AFP 

Air  Products  &  Chemical,  Inc.,  Apache  Foam 
Products  Div. 

AZT 

Aatec  Chemicals,  Inc. 

AKS 

Arkansas  Co.,  Inc. 

BAC 

Baker  Castor  Oil  Co. 

ALB 

Ames  Laboratories,  Inc. 

BAL 

Baltimore  Paint  &  Chemical  Corp. 

ALC 

Alco  Chemical  Corp. 

BAR 

American  Rubber  &  Chemical  Co. 

AID 

Aldrich  Chemical  Co.,  Inc. 

BAX 

Baxter  Laboratories,  Inc. 

ALF 

Allied  Chemical  Corp.,  Fibers  Div. 

BCM 

Belding  Chemical  Industries 

ALL 

Alliance  Color  &  Chemical  Co. 

BCN 

l£hn  &  Fink  Products  Corp.,  Beacon  Div. 

ALO 

Alamo  Industries,  Inc. 

BDO 

Benzenoid  Organics,  Inc. 

ALT 

Crompton  &  Knowles  Corp.,  Chemicals  Group, 

BEN 

Bennett's 

Althouse  &  Bates  Div. 

BFG 

B.  F.  Goodrich  Co.,  B.  F.  Goodrich  Chemical 

ALX 

Alox  Corp. 

Co.  Div. 

AMB 

American  Bio-Synthetlcs  Corp. 

BFR 

Branohf lower  Co. 

AJC 

Amchem  Products,  Inc. 

BJL 

Burdick  &  Jackson  Laboratories,  Inc. 

AME 

American  Chemical  Corp. 

BKC 

J.  T.  Baker  Chemical  Co. 

AML 

Amalgamated  Chemical  Corp. 

BKL 

Millmaster  Onyx  Corp.,  Berkeley  Chemical  Div. 

AMD 

American  Oil  Go.  (Texas) 

BKM 

Buckman  Laboratories,  Inc. 

AMP 

American  Potash  &  Chemical  Corp. 

BKS 

Tenneco  Chemicals,  Inc.,  Berkshire  Color 

Div. 

AMR 

Pacific  Resins  &  Chemical  Co. 

BKT 

J.  T.  Baker  Chemical  Co.,  Taylor  Div. 

AMS 

Martin-Marietta  Corp.,  Rldgway  Color  & 

BL 

Belle  Chemical  Co.,  Inc. 

Chemical  Div. 

BLA 

Blue  Arrow,  Inc. 

ANM 

Ancon  Chemical  Corp. 

BLN 

Brooklyn  Color  Works,  Inc. 

APD 

Atlas  Chemical  Industries,  Inc. 

BLS 

Beech-Nut  Life  Savers,  Inc. 

APR 

Atlas  Processing  Co. 

BME 

Bendix  Corp.,  Marshall-Eclipse  Div. 

APT 

American  Petrochemical  Corp. 

BOR 

Borden  Co.,  Borden  Chemical  Co.  Div. 

APV 

Armstrong  Paint  &  Varnish  Works,  Inc. 

BOY 

Walter  N.  Boysen  Go. 

APX 

Apex  Chemical  Co.,  Inc. 

BPC 

Cowles  Chemical  Co.,  Benzol  Products  Div 

AHA 

Arapahoe  Chemicals,  Div.  of  Syntex  Corp. 

BPL 

Brand  Plastics  Co. 

ARC 

Armour  Industrial  Chemical  Co. 

BRD 

Baird  Chemical  Industries,  Inc. 

ARD 

Ardmore  Chemical  Co. 

BRS 

Bristol-Meyers  Co.,  Bristol  Uboratories 

Div. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 
TABLE  22. --Synthetic  organic  chemicals.-  Directory  of  manufacturers ,  i 566— Continued 


Code 

Code 

identi- 

Name of  company 

identi- 

Name of  company 

fication 

fication 

BRU 

M.  A.  Bruder  &  Sons,  Inc. 

COR 

Commonwealth  Oil  Refining  Co.,  Inc. 

BRY 

Bryant  Chemical  Corp. 

CP 

Colgate-Palmolive  Co. 

ESC 

Burkart-Sohler  Chemical  Co. 

CPC 

Chi Ids  Pulp  Colors,  Inc. 

BST 

Best  Fertilizers  Co. 

CPD 

Chemical  Products  Corp. 

BSW 

Original  Bradford  Soap  Works,  Inc. 

CPV 

Cook  Paint  &  Varnish  Co. 

BUG 

Blaokman-Uhler  Chemical  Co. 

CPY 

Copolymer  Rubber  &   Chemical  Corp. 

BUX 

Buckeye  Cellulose  Corp. 

CRC 

Crown  Chemical  Corp. 

BUR 

Burroughs -Wellcome  &  Co.  (U.S.A.),  Inc. 

CRN 

Com  Products  Co. 

BXT 

J.  H.  Baxter  &  Co. 

cas 

Carus  Chemical  Co.,  Inc. 

CRT 

Crest  Chemical  Corp. 

CAD 

Cadet  Chemical  Corp. 

CRY 

Tenneco  Manufacturing  Co.,  Tenneco  Plastics 

CAL 

Callery  Chemical  Co. 

Dlv. 

CAT 

Ashland  Oil  &  Refining  Co.,  Catalin  Corp.  Dlv. 

CRZ 

Crown  Zellerbach  Corp.,  Chemical  Products  Div. 

CAU 

Calcasieu  Chemical  Corp. 

CSB 

Chemical  Services  of  Baltimore,  Inc. 

CBA 

Ciba  Corp.,  Clba  Products  Co. 

CSD 

Cosden  Oil  &   Chemical  Co. 

CBC 

Georgia-Pacific  Corp.,  Coos  Bay  Div. 

CSO 

Cities  Service  Oil  Co. 

CBD 

Chembond  Corp. 

CST 

Charles  S.  Tanner  Co. 

CBM 

Carborundum  Co.,  Coated  Abrasives  Dlv. 

CIA 

Conestoga  Chemical  Corp. 

CBN 

Columbian  Carbon  Co.,  Inc.  and  Chemicals  Div. 

CTL 

Continental  Chemical  Co. 

CBP 

Ciba  Corp.,  Clba  Pharmaceutical  Co.  Div. 

CTN 

Chemetron  Corp.,  Chemetron  Chemicals  Dlv., 

CBR 

Colab  Resin  Corp. 

Organic  Chemical  Dept. 

CBT 

Samuel  Cabot,  Inc. 

cue 

Cumberland  Chemical  Corp.,  a  Subsidiary  of 

CBY 

Crosby  Chemicals,  Inc. 

Air  Reduction  Co.,  Inc. 

CCA 

Carlisle  Chemical  Works,  Inc.,  Advance  Div. 

CUL 

Culver  Chemical  Co. 

CCC 

Chase  Chemical  Corp. 

CUT 

Cutter  Laboratories,  Inc. 

CCH 

Pearsall  Chemical  Co. 

CW 

General  Mills,  Inc.,  Chemical  Div. 

CCL 

Charlotte  Chemical  Laboratories 

OWL 

Cowles  Chemical  Co. 

CCO 

Chemlco,  Inc. 

OWN 

Upjohn  Co.,  Carwin  Organic  Chemicals 

CCP 

Crown  Central  Petroleum  Corp. 

CWP 

Consolidated  Papers,  Inc. 

CCW 

Carlisle  Chemical  Works,  Inc. 

CYC 

Cyolamate  Corp.  of  America 

CD 

Budd  Co.,  Polyohem  Dlv. 

CEL 

Celanese  Corp.  of  America: 

DA 

Diamond  Alkali  Co.,  and  Western  Div. 

Celanese  Chemical  Co.  Dlv. 

DAN 

Dan  River  Mills,  Inc. 

Celanese  Coatings  Co. 

DAV 

Conchemco,  Inc.,  H.  B.  Davis  Co.  Dlv. 

Celanese  Plastics  Co. 

DBC 

Dow  Badische  Co. 

Fibers  Co.  Div. 

DCC 

Dow  Coming  Corp. 

CFA 

Cooperative  Farm  Chemicals  Association 

DEG 

Degen  Oil  &  Chemical  Co. 

CFC 

Sun  Chemical  Corp. -Kearny 

DEP 

DePaul  Chemical  Co.,  Inc. 

CGL 

Cargin,  Inc. 

DEX 

Dexter  Chemical  Corp. 

CHC 

Chlpman  Chemical  Co.,  Inc. 

DLX 

Dixie  Chemical  Co. 

CHF 

Chemical  Formulators,  Inc. 

DLH 

Hess  Oil  &   Chemical  Corp. 

CHG 

Chemagro  Corp. 

DLI 

Dawe's  Laboratories,  Inc. 

CHL 

Chemol,  Inc. 

DOM 

Dominion  Products,  Inc. 

CHO 

Stauffer  Chemical  Co.,  Calilo  Chemicals, 

DOW 

Dow  Chemical  Co. 

Inc.  Div. 

DPP 

Dixie  Pine  Products  Co.,  Inc. 

CHT 

Chattem  Drug  &  Chemical  Co.,  Chattem 

DRW 

Drew  Chemical  Corp. 

Chemicals  Dlv. 

DSC 

Dye  Specialties,  Inc. 

CIB 

Clba  Chemical  &  Dye  Co. 

DSO 

DeSoto  Chemical  Coatings,  Inc. 

CIK 

Tenneco  Chemicals,  Inc.,  Cal/Ink  Dlv. 

DUN 

Frank  W.  Dunne  Co. 

CIS 

Chemical  Insecticide  Corp. 

DUP 

E.  I.  duPont  de  Nemours  &  Co.,  Inc. 

CKL 

Chemlek  Laboratories,  Inc. 

DVC 

Dover  Chemical  Corp. 

CLB 

Columbia  Organic  Chemicals  Co.,  Inc. 

nxs 

Sunray  DX  Oil  Co. 

CLC 

Charles  L.  Hulsking  &  Co.,  Inc.,  Cllntbrook 
Chemical  Co.  Dlv. 

DYS 

Davies-Young  Soap  Co. 

CLD 

Colloids,  Inc. 

EAK 

CLI 

Cllntwood  Chemical  Co. 

ECC 

Eastern  Color  &  Chemical  Co. 

CLK 

Clark  Oil  &  Refining  Corp. 

EDC 

Edoan  Laboratories 

CLN 

Standard  Brands,  Inc.,  Clinton  Com  Proces- 

EFH 

E.  F.  Houghton  &   Co. 

sing  Co.  Div. 

EK 

Eastman  Kodak  Co. 

CLV 

Clover  Chemical  Co. 

EKT 

Eastman  Kodak  Co.,  Tennessee  Eastman  Co.  Div. 

CLY 

W.  A.  Cleary  Corp. 

EKX 

Eastman  Kodak  Co.,  Texas  Eastman  Co.  Dlv. 

CM 

Carpenter -Morton  Co. 

ELP 

El  Paso  Products  Co. 

CMG 

Nyanza,  Inc. 

EMK 

Emkay  Chemical  Co. 

CMP 

Commercial  Products  Co.,  Inc. 

EMR 

Emery  Industries,  Inc. 

CNC 

Columbian  Nitrogen  Corp. 

EN 

Endo  Laboratories,  Inc. 

CO 

Continental  Oil  Co. 

ENJ 

Enjay  Chemical  Co. 

COK 

Cockerllle  Chemicals,  Inc. 

EPC 

Epoxyllte  Corp. 

COL 

Collier  Carbon  &  Chemical  Corp. 

ESA 

East  Shore  Chendoal  Co.,  Inc. 

COM 

Commercial  Solvents  Corp. 

ESC 

Escambia  Chemical  Corp. 

CON 

Concord  Chemical  Co.,  Inc. 

ETD 

Ethyl-Dow  Chemical  Co. 

COP 

Coopers  Creek  Chemical  Corp. 

EVN 

Evans  Chemetics,  Inc. 

DIRECTORY  OF  MANUFACTURERS 
TABLE  22. --Synthetic  organic  chemicals.-   Directory  of  manufacturers ,  i 966- -Continued 


195 


Code 

Code 

identi- 
fication 

Name  of  company 

identi- 
fication 

Name  of  company 

EW 

Westlnghouse  Electric  Corp.,  Insulating 

GRC 

W.  R.  Grace  &  Co.,  Dubois  Chemicals  Div. 

Materials  Div.  -  BenoUte 

GRD 

W.  R.  Grace  &  Co.,  Dewey  &  Almy  Chemical  Div. 

ORG 

P.  D.  George  Co. 

FAB 

Fabricolor  Manufacturing  Corp. 

GRH 

W.  R.  Grace  &  Co. ,  Hatco  Chemical  Div. 

FAR 

Famow,  Inc. 

GRL 

W.  R.  Grace  &  Co.,  Vestal  Laboratories  Div. 

FB 

Fritzsche  Bros.,  Inc. 

GRO 

A.  Gross  &  Co.,  Inc. 

FBF 

Rexall  Chemical  Co.,  Fiberfll  Div. 

GRS 

Pontlac  Refining  Corp. 

FBR 

Fibreboard  Corp. 

GRV 

Guardsman  Chemical  Coatings,  Inc. 

FC 

Franklin  Chemical  Co. 

GRW 

Great  Western  Sugar  Co. 

FCA 

Farmers  Chemical  Association,  Inc. 

GTH 

Guth  Chemical  Co. 

FCD 

France,  Campbell  &  Darling,  Inc. 

GTL 

Great  Lakes  Chemical  Corp. 

FCL 

Federal  Color  Laboratories,  Inc. 

GYR 

Goodyear  Tire  &  Rubber  Co. 

FEL 

Felton  Chemical  Co.,  Inc. 

FER 

Ferro  Corp.,  Ferro  Chemical  Div. 

HAB 

Halby  Products  Co.,  Inc. 

FG 

Foster  Grant  Co.,  Inc. 

HAL 

C.  P.  Hall  Co.  of  Illinois 

FH 

Foster-Heaton  Co. 

HAM 

Hampden  Color  &  Chemical  Co. 

FIN 

Fine  Organics,  Inc. 

HAN 

Hanna  Paint  Manufacturing  Co.,  Inc. 

FIR 

Firestone  Tire  &  Rubber  Co.,  Firestone 

HAP 

AppUed  Plastics  Co.,  Inc. 

Plastics  Co.  Div. 

HCH 

Houston  Chemical  Corp. 

FIS 

Fisher  Melamine  Corp. 

HCO 

Nyanza,  Inc.,  Hamilton  Chemical  Div. 

FLH 

H.  B.  Fuller  Co. 

HDG 

Hodag  Chemical  Corp. 

FLM 

Fleming  Laboratories,  Inc. 

HER 

Heresite  &  Chemical  Co. 

FLO 

HET 

Heterochemical  Corp. 

FLW 

W.  P.  PuUer  Paint  Co. 

HEX 

Hexagon  Laboratories,  Inc. 

FMB 

FM:  Corp.,  Inorganic  Chemicals  Div. 

HFT 

Hoffman-Taff,  Inc. 

FMN 

FMC  Corp.,  Niagara  Chemical  Div. 

HK 

Hooker  Chemical  Corp. 

FMP 

FJK  Corp.,  Organic  Chemicals  Div. 

HKD 

Hooker  Chemical  Corp.,  Durez  Plastics  Div. 

FMT 

Fairmount  Chemical  Co.,  Inc. 

HKY 

Hawkeye  Chemical  Co. 

FOC 

Farac  Oil  &  Chemical  Co.,  Div.  of  Handsohy 

HLC 

Hartman-Leddon  Co. 

Chemical  Co. 

HLI 

Haag  Laboratories,  Inc. 

FQM 

Formica  Corp. 

HMP 

W.  R.  Grace  &  Co.,  Hampshire  Chemical  Div. 

FOR 

Foremost  Chemical  Products  Co. 

HMY 

Humphrey  Chemical  Co. 

FRE 

Freeman  Chemical  Corp. 

HN 

Tenneeo  Chemicals,  Inc. 

FRL 

Firestone  Tire  &   Rubber  Co.,  Firestone 

HNC 

H  &  N  Chemical  Co. 

Rubber  &  Latex  Products  Co.  Div. 

HNT 

Huntington  Laboratories,  Inc. 

FRM 

Farmer's  Chemical  Co. 

HNW 

Tenneeo  Chemicals,  Inc.,  Newport  Div. 

FRO 

Vulcan  Materials  Co.,  Chemicals  Div. 

HNX 

Tenneeo  Chemicals,  Inc.,  Nuodex  Div. 

FRP 

Filtered  Rosin  Products  Co. 

HOF 

Hoffmann-LaRoche,  Inc. 

FRS 

Firestone  Tire  &  Rubber  Co.,  Firestone 

HOU 

Air  Products  &  Chemicals,  Inc.,  Houdry 

Synthetic  Rubber  &  Latex  Co.  Div. 

Process  &  Chemical  Div. 

FSH 

Frisoh  &  Co.,  Inc. 

HPC 

Hercules,  Inc. 

FTE 

Foote  Mineral  Co. 

HHS 

Grow  Chemical  Corp.,  Harris  Paint  Co.  Div. 

Fra 

Fel-Tex,  Inc. 

HRT 

Hart  Products  Corp. 

HSC 

HoUand-Suco  Color  Co. 

OAF 

General  Aniline  &  Film  Corp.,  Dyestuff  & 

HSH 

Harshaw  Chemical  Co.,  Div.  of  Kewanee  Oil  Co. 

Chemical  Div. 

HST 

American  Hoechst  Corp. 

GAM 

Gamma  Chemical  Corp. 

HUM 

National  Dairy  Products  Corp;,  Humko  Products 

CAN 

Gane's  Chemical  Works,  Inc. 

Chemical  Div. 

GCC 

W.  R.  Grace  &   Co.,  Agricultural  Products  Div. 

HUS 

Husky  Briquet ting.  Inc. 

GDN 

Lancaster  Chemical  Corp.,  Gordon  Chemicals 

HVG 

Haveg  Industries,  Inc.,  Resin  &  Compound  Div. 

Co.  Div. 

HYC 

Hysol  Corp. 

GE 

General  Electric  Co.,  Chemical  Materials  Dept. 

HYN 

Hynson,  Westcott  &  Dunning,  Inc. 

GEI 

General  Electric  Co.,  Insulating  Materials 

Dept. 

IBI 

Industrial  Blochemicals 

CffS 

G.  Frederick  Smith  Chemical  Co. 

ICC 

Interchemlcal  Corp.,  Color  &  Chemicals  Div. 

GOC 

Goodrich-Gulf  Chemicals,  Inc. 

ICF 

Interchemical  Corp.,  Finishes  Div. 

GGY 

Geigy  Chemical  Corp. 

ICI 

I.  C.  I.  (Organics),  Inc. 

GIL 

Oilman  Paint  &  Varnish  Co. 

ICO 

Interchemical  Corp.,  Organic  Chemicals  Dept. 

GIV 

Givaudan  Corp. 

IDC 

Industrial  Dyestuff  Co. 

GLC 

General  Latex  &  Chemical  Corp. 

IFF 

International  Flavors  &  Fragrances,  Inc. 

GLD 

Glldden  Co.,  and  Durkee  Famous  Foods  Div. 

ILC 

International  Latex  &  Chemical  Corp. 

GDC 

Glasflex,  Inc. 

IMC 

International  Minerals  &  Chemical  Corp. 

GLY 

Glyco  Chemicals,  Inc. 

IMP 

Hercules,  Inc.,  Imperial  Color  &  Chemical  Dept. 
Imperial,  Inc. 

GNF 

General  Foods  Corp.,  Maxwell  House  Div. 

IMR 

GNM 

General  Mills,  Inc. 

INL 

Inland  Steel  Container  Co. 

GNT 

General  Tire  &  Rubber  Co.,  Chemical  Div. 

IOC 

Hitter  Pfaudler  Corp.,  lonac  Chemical  Co.  Div. 

GOC 

Gulf  Oil  Corp. 

IPC 

Interplastic  Corp.,  Commercial  Resins  Div. 

GCfi 

Gordon  Chemical  Co.,  Inc. 

IPI 

Isocyanate  Products,  Inc. 

GPM 

General  Plastics  Manufacturing  Co. 

IPR 

Inter-Pacific  Resins,  Inc. 

GPR 

Grain  Processing  Corp. 

IRC 

IRC,  Inc. 

GRA 

Great  American  Plastics  Co. 

IRI 

Ironsides  Resins,  Inc. 

196  SYNTHETIC  ORGANIC  CHEMICALS,  1966 

TABLE  22. --Synthetic  organic  chemicals.-  Directory  of  manufacturers ,  i566— Continued 


Code 

Code 

identi- 

Name of  company 

identi- 

Name of  company 

fication 

fication 

JCC 

Jefferson  Chemical  Co.,  Inc. 

MEE 

Maumee  Chemical  Co. 

JDC 

Nipak,  Inc. 

MER 

Merichem  Co. 

JEN 

Jennison-Wright  Corp. 

MET 

M  &  T  Chemicals,  Inc. 

JIE 

J.  Meyer  &  Sons,  Inc. 

MFG 

Molded  Fiber  Glass  Body  Co.,  Resin  Div. 

JNS 

S.  C.  Johnson  &  Son,  Inc. 

MIK 

McLaughlin  Gormley  King  Co. 

JOB 

Jones-Blair  Paint  Co. 

JGR 

Magruder  Color  Co.,  Inc. 

JOR 

Jordan  Chemical  Co. 

MHI 

Ventron  Corp.,  Ifetal  Hydrides  Div. 

JRG 

Andrew  Jergens  Co. 

MID 

Midland  Industrial  Finishes  Co. 

JSC 

Jersey  State  Chemical  Co. 

MIR 

Miranol  Chemical  Co.,  Inc. 

JTC 

Joseph  Turner  &  Co. 

MID 

Metalead  Products  Corp. 

JWL 

Jewel  Paint  &  Vamish  Co. 

MLS 

Miles  Laboratories,  Inc.,  Chemicals  Div. 

MMM 

Minnesota  Mining  &  Manufacturing  Co. 

KAI 

Kaiser  Aluminum  &  Chemical  Corp. ,  Kaiser 

MNO 

Monochem,  Inc. 

Chemicals  Div. 

MNP 

Minnesota  Paints,  Inc. 

KAl 

Kali  Manufacturing  Co. 

M3A 

Mona  Industries,  Inc. 

KCC 

Kennecott  Copper  Corp.,  Chino  Mines  Div. 

MOB 

Mobay  Chemical  Co. 

KCH 

Keystone  Chemurgic  Corp. 

MOC 

Marathon  Oil  Co.,  Texas  Refining  Div. 

KCU 

Kennecott  Copper  Corp.,  Utah  Copper  Div. 

MDN 

Monsanto  Co. 

KCW 

Keystone  Color  Works,  Inc. 

MOR 

Mineral  Oil  Refining  Co. 

KEI 

Keil  Chemical  Co. 

MOT 

Motoraco,  Inc. 

KEL 

Kelly-Pickering  Chemical  Corp. 

MPP 

Midwest  Plastic  Products  Co. 

KEN 

Kendall  Refining  Co. 

MR 

Benjamin  Moore  &  Co. 

KET 

Ketona  Chemical  Corp. 

MRA 

Metro-Atlantic,  Inc. 

KF 

Kay-Fries  Chemicals,  Inc. 

MRB 

Marblette  Corp. 

KMC 

Kohler-McUster  Paint  Co. 

MRD 

Marden-Wild  Corp. 

KMP 

Kelly -Ktoore  Paint  Co. 

MRK 

Merck  &  Co.,  Inc. 

KND 

Knoedler  Chemical  Co. 

MRN 

International  Latex  &  Chemical  Corp.,  Paisley 

KNG 

Far -Best  Corp.,  0.  L.  King  Div. 

Products  Div. 

KNP 

Knapp  Products,  Inc. 

MRO 

W.  R.  Grace  &  Co.,  Marco  Chemical  Div. 

KON 

H.  Kohnstamm  &  Co.,  Inc. 

MRT 

Morton  Chemical  Co. 

KPI 

Kenrich  Petrochemicals,  Inc. 

MRV 

Marlowe-Van  Loan  Corp. 

KPP 

Sinclalr-Koppers  Co. 

MRX 

Max  Marx  Color  &  Chemical  Co. 

KPS 

Koppers  Pittsburgh  Co. 

MSC 

Mississippi  Chemical  Corp. 

KPT 

Koppers  Co.,  Inc.,  Tar  &  Chemical  Div. 

MTO 

((tontrose  Chemical  Corp.  of  California 

KRM 

Lawter  Chemicals,  Inc.,  Krumbhaar  Resin  Div. 

MTR 

Baldwin -Ifontrose  Chemical  Co.,  Inc.,  Montrose 

KYN 

Kyanize  Paints,  Inc. 

Chemical  Div. 

KIS 

Keysor  Chemical  Co. 

MYW 

Stepan  Chemical  Co.,  Maywood  Div. 

LAK 

Lakeway  Chemical  Co. 

NAC 

Allied  Chemioal  Corp.,  Industrial  Chemicals 

LAM 

Lalfotte  Chemical  Products  Co. 

Div. 

LAS 

Lasco  Industries,  Inc. 

NCI 

Union  Camp  Corp.,  Chemical  Div. 

LEA 

Leatex  Chemical  Co. 

NCW 

Nostrip  Chemical  Works,  Inc. 

LEB 

Lebanon  Chemical  Corp. 

NEO 

Norda  Essential  Oil  &  Chemical  Co.,  Inc. 

LEF 

Leffingwell  Chemical  Co. 

NEP 

Nepera  Chemical  Co.,  Inc. 

LEM 

B.  L.  Lemke  k   Co.,  Inc. 

NES 

Nease  Chemical  Co.,  Inc. 

LEN 

Leonard  Refineries,  Inc. 

NEV 

Neville  Chemical  Co. 

LEV 

Lever  Brothers  Co. 

NIL 

Nilok  Chemicals,  Inc. 

LIL 

Ell  Ully  &  Co. 

NIT 

Nltrin,  Inc. 

LKL 

Lakeside  Laboratories,  Div.  of  Colgate- 

NIX 

Tenneco  Chemicals,  Inc.,  Nixon-Baldwin  Div. 

PaljDOlive  Co. 

NLC 

Nalco  Chemical  Co. 

DCT 

St.  Regis  Paper  Co.,  Lake  States  Div. 

NMC 

National  Milling  &  Chemioal  Co.,  Inc. 

LMI 

North  American  Chemical  Co. 

NOC 

Norac  Co.,  Inc.  and  subsidiary  Mathe  Chemioal 

LPC 

Lignin  Products  Co. 

Co. 

LUB 

Lubrizol  Corp. 

NGN 

A.  P.  Nonweiler  Co. 

LUE 

George  Lueders  &  Co.,  Inc. 

NOP 

Nopco  Chemical  Co.,  Inc. 

LUR 

Laurel  Products  Corp. 

NOR 

Norwich  Pharmacal  Co. 

LVR 

C.  Lever  Co.,  Inc. 

NPC 

Northwest  Petrochemical  Corp. 

LVY 

Fred'k  H.  Levey  Co.,  Inc. 

NPI 

National  Polychemicals,  Inc. 

NPP 

National  Plastic  Products  Co.,  Inc. 

MAH 

Maher  Color  &  Chemical  Co. 

NPR 

Newport  Products  Co.,  Div.  of  Safeway  Stores, 

MAL 

Mallinckrodt  Chemical  Works 

Inc. 

MAN 

Manganese  Chemical  Co.,  Div.  of  Pickands 

NPV 

Norris  Paint  &  Vamish  Co. 

Mather  &  Co. 

NRS 

Norse  Chemical  Corp. 

MAR 

American  Can  Co. 

NSC 

National  Starch  k   Chemical  Corp. 

MAY 

Otto  B.  May,  Inc. 

NSP 

Alabama  Binder  k   Chemical  Corp. 

MCA 

Masonite  Corp.,  Alpine  Chemical  Div. 

NTB 

National  Biochemical  Co. 

MCB 

Borg -Warner  Corp. ,  Marbon  Chemical  Div. 

NTC 

National  Casein  Co. 

MCC 

McCloskey  Vamish  Co. 

NTL 

National  Lead  Co. 

JCH 

Michigan  Chemioal  Corp. 

NVF 

N.V.F.  Co. 

MCI 

Mooney  Chemicals,  Inc. 

NVT 

Novamont  Corp. 

MED 

Medical  Chemicals  Corp. 

NW 

Northwestem  Chemical  Co. 

DIRECTORY  OF  MANUFACTURERS  197 

TABLE  22.— Synthetic  organic  chemicals:   Directory  of  manufacturers ,  7566- -Continued 


Code 

Code 

identi- 

Name of  company 

identi- 

Name of  company 

fication 

fication 

NYC 

Tenneco  Chemicals,  Inc.,  New  York  Color 

PSP 

Georgia-Pacific  Corp.,  Puget  Sound  Div. 

Dlv. 

PTO 

Puerto  Rico  Chemical  Co.,  Inc. 

PIT 

Petro-Tex  Chemical  Corp. 

OCF 

Owene-Comlng  Fiberglae  Corp. 

PUB 

Publicker  Industries,  Inc. 

OH 

Air  Reduction  Co.,  Inc.,  Ohio  Chemical  & 

PVI 

Polyvinyl  Chemicals,  Inc. 

Surgical  Equipment  Co.  Dlv. 

PYL 

Polychemical  Laboratories,  Inc. 

OMC 

Olin  Mathleson  Chemical  Corp. 

PYR 

Poly  Resins 

QMS 

E.  R.  Squibb  &  Sons,  Inc. 

PYZ 

Polyrez  Co . ,  Inc . 

OhK 

Jilllmaster  Onyx  Corp.,  Onyx  Chemical  Div. 

OPC 

Orbls  Products  Corp. 

QCP 

Quaker  Chemical  Corp. 

ORG 

Oi^anlos,  Inc. 

QKO 

Quaker  Oats  Co. 

ORO 

Chevron  Chemical  Co.,  Additives  Div. 

QUN 

K.  J.  Quinn  &  Co.,  Inc. 

ORT 

Roehr  Chemicals,  Inc. 

ceB 

C.  J.  Osbom  Co. 

RAB 

Raybestos -Manhattan,  Inc.,  Raybestos  Div. 

OTA 

Ottawa  Chemical  Co. 

RBC 

Roberts  Chemicals,  Inc. 

OTC 

Ott  Chemical  Co. 

RCC 

Rexall  Chemical  Co. 

OTH 

Chevron  Chemical  Co.,  Ortho  Dlv. 

RCD 

Richardson  Co. 

0X0 

Oxo  Chemicals  Co. 

RCI 

Relchhold  Chemicals,  Inc. 

OXR 

Onyx  Oils  &  Resins,  Inc. 

RDA 

Rhodia,  Inc. 

RED 

Red  Spot  Paint  &  Varnish  Co.,  Inc. 

PAI 

Pennsylvania  Industrial  Chemical  Corp. 

REH 

Rebels  Chemical  Co.,  Div.  of  Armour 

PAN 

Pan  American  Petroleum  Corp. 

Pharmaceutical  Co. 

PAR 

Pennsylvania  Refining  Co. 

REL 

ReUance  Universal,  Inc. 

PAS 

Pennsalt  Chemicals  Corp. 

REM 

Remington  Arms  Co.,  Inc. 

PAT 

Patent  Chemicals,  Inc. 

REN 

Reni-oh  Resins 

PBY 

Pillsbury  Co.,  Chemical  Div. 

RET 

Rayette-Faberge,  Inc. 

PC 

Proctor  Chemical  Co.,  Inc. 

REZ 

Rezolln,  Inc. 

PCC 

USS  Chemicals,  Div.  of  U.S.  Steel  Corp. 

RGC 

Rogers  Corp. 

PCH 

Peerless  Chemical  Co. 

RH 

Rohm  &  Haas  Co. 

PCI 

Pioneer  Chemical  Works,  Inc. 

RIC 

Atlantic  Richfield  Co.,  Richfield  Div. 

PCS 

Emery  Industries,  Inc.,  Western  Dlv. 

RIK 

Riker  Laboratories,  Div.  of  Rexall  Drug  «■ 

PCW 

Pf ister  Chemical  Works 

Chemical  Co. 

PD 

Parke,  Davis  &  Co. 

RIL 

Rellly  Tar  &  Chemical  Corp. 

PDC 

Bemcolors-Poughkeepsie,  Inc. 

RIV 

Rlverdale  Chemical  Co. 

PDJ 

Joseph  Davis  Plastics  Co. 

RLS 

Rachelle  Laboratories,  Inc. 

PEK 

Peck's  Products  Co. 

ROC 

Rock  Hill  Printing  &  Finishing  Co. 

PEL 

Pelron  Corp. 

ROM 

United  Jferchants  &  Manufacturers,  Inc.,  Roma 

PEN 

S.  B.  Penick  &  Co. 

Chemical  Div. 

PER 

Perry  &  Derrick  Co. 

ROY 

Royce  Chemical  Co. 

PFN 

Pfanstiehl  Laboratories,  Inc. 

RPC 

Refined  Products  Co. 

PFP 

Phelan-Faust  Paint  Manufacturing  Co., 

RSA 

R.S.A.  Corp. 

Phelan's  Resins  &  Plastics  Div. 

RSB 

Rosenberg  Bros.  &  Co. 

PFW 

Polak's  Frutal  Works 

RT 

F.  Ritter  &  Co. 

PFZ 

Chas.  Pfizer  &  Co.,  Inc. 

RTC 

Rltter  Chemical  Co.,  Inc. 

PG 

Procter  &  Gamble  Co. 

RTF 

Retzloff  Chemical  Co. 

PGU 

Gulf  Oil  Corp.,  Chemicals  Dept.,  Perkins  Glue 

RUB 

Hooker  Chemical  Corp.,  Ruco  Div. 

Branch 

RUC 

Rubicon  Chemicals,  Inc. 

PHR 

Pharmachem  Corp. 

PIC 

Pierce  Organlcs,  Inc. 

S 

Sandoz,  Inc. 

PI  I 

Polymer  Industries,  Inc. 

SAC 

Southeastern  Adhesives  Co. 

PIL 

Pilot  Chemical  Co. 

SAL 

Salsbury  Laboratories 

PIT 

Pitt-Consol  Chemical  Co. 

SAR 

Sartomer  Resins,  Inc. 

PLA 

Richardson  Co.,  Richardson  Polymers  Div. 

SBC 

Scher  Bros.,  Inc. 

PLB 

P-L  Biochemloals,  Inc. 

SEP 

Sugar  Beet  Products  Co. 

PLC 

Phillips  Petroleum  Co. 

sec 

Standard  Chlorine  Chemical  Co.,  Inc. 

PLS 

Plastics  Engineering  Co. 

SCF 

Schaefer  Varnish  Co.,  Inc. 

PLU 

Plumb  Chemical  Corp. 

SCH 

Scherlng  Corp. 

PMC 

Plastics  Manufacturing  Co. 

SCN 

Schenectady  Chemicals,  Inc. 

PMP 

Premier  Malt  Products,  Inc. 

SCO 

Scholler  Bros.,  Inc. 

PNT 

Pantasote  Co. 

SCP 

Standard  Chemical  Products,  Inc. 

PNX 

Phoenix  Oil  Co. 

SCR 

R.  P.  Scherer  Corp. 

POL 

Polymer  Corp. 

SDC 

Martin-Marietta  Corp.,  Southern  Dyestuff  Co. 

PPC 

Premier  Petrochemical  Co. 

Div. 

PPG 

Pittsburgh  Plate  Glass  Co. 

SDG 

Sterling  Drug,  Inc.,  Glenbrook  Laboratories 

PPL 

Pioneer  Plastics  Corp.,  Chemical  Dlv. 

Div. 

PRC 

Products  Research  &  Chemical  Corp. 

SDH 

SterUng  Drug,  Inc.,  Rilton-Davis  Chemical 

PRD 

Productol  Chemical  Co.,  Inc. 

Co.  Div. 

PHP 

S.  B.  Penick  &  Co.,  Parsons -Plymouth  Div. 

SDW 

Sterling  Drug,  Inc.,  Winthrop  Laboratories 

PRT 

Pratt  &  Lambert,  Inc. 

Div. 

PRX 

Purex  Corp.,  Ltd. 

SEA 

Seaboard  Chemicals,  Inc. 

PSC 

Passaic  Color  &  Chemical  Co. 

SED 

Seidlitz  Paint  &  Varnish  Co. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 
TABLE  22.— Synthetic  organic  chemicals.-  Directory  of  manufacturers ,  1966— Continued 


Code 

Code 

identi- 

Name of  company 

identi- 

Name of  company 

fication 

fication 

SEK 

Seldsul  Plastics  Corp. 

SVC 

Sullivan  Varnish  Co. 

SEL 

Selney  Go. ,  Inc. 

SVT 

Solvent  Chemical  Co.,  Inc. 

SEP 

Southeast  Polymers,  Inc. 

SW 

Sherwin-Williams  Co. 

SEY 

Seydel-Woolley  &  Co.,  Inc. 

SWT 

Swift  &  Co. 

SF 

Stauffer  Chemical  Co.,  Industrial  Chemical 

SYC 

Synthetic  Chemicals,  Inc. 

Dlv. 

SYN 

Synthron,  Inc. 

SFA 

Stauffer  Chemical  Co.,  Specialty  Chemical  Div. 

SYP 

Synthetic  Products  Co. 

SFD 

Sonford  Chemical  Co. 

SYR 

ADM  Co.,  Synco  Resins 

SH 

Stein,  Hall  &  Co.,  Inc. 

SYV 

Synvar  Corp. 

SHA 

Shanco  Plastics  &  Chemicals,  Inc. 

SHC 

Shell  Oil  Co.,  Shell  Chemical  Co.  Div. 

lAE 

Chemetron  Corp.,  National  Cylinder  Gas  Div. 

SHF 

National  Dairy  Products  Corp.,  Sheffield 

TBK 

Universal  Oil  Products  Co.,  Chemical  Div. 

Chemical  Co.  Div. 

TCC 

Tanatex  Chemical  Corp. 

SHL 

Shulton,  Inc. 

TCH 

Try Ion  Chemical  Corp. 

SHM 

Shamrock  Oil  &  Gas  Corp. 

TCI 

Texize  Chemicals,  Inc. 

SHO 

Shell  Oil  Co. 

TDC 

Diversey  Corp. 

SHP 

Shepherd  Chemical  Co. 

TEN 

Tennessee  Copper  Co. 

SIC 

Vistron  Corp.,  Silmar  Div. 

TGL 

Triangle  Chemical  Co. 

SID 

George  F.  Slddall  Co.,  Inc. 

THC 

Thompson  Apex  Co.,  Div.  of  Continental  Oil  Co. 

SIM 

Simpson  Timber  Co. 

THM 

Thompson  Chemical  Corp. 

SIN 

Sinclair  Refining  Co. 

TIC 

Ticonderoga  Chemical  Corp. 

SIO 

Standard  Oil  Co.  of  Ohio 

TID 

Tidewater  Oil  Co. 

SIP 

James  P.  Sipe  &   Co. 

TKL 

Thiokol  Chemical  Corp. 

SK 

Smith,  Kline  &  French  Laboratories 

TMH 

Thompson-Hayward  Chemical  Co. 

SKC 

Slnclair-Koppers  Chemical  Co. 

lie 

Sterling  Drug,  Inc.,  Thomasset  Colors  Div. 

SKG 

Sunldst  Growers,  Inc. 

TNA 

Ethyl  Corp. 

SKO 

Skelly  Oil  Co. 

TNC 

Sun  Chemical  Corp. 

SLC 

Soluol  Chemical  Co.,  Inc. 

TNI 

Gillette  Chemical  Co. 

SLV 

Sterling  Drug,  Inc.,  Salvo  Chemical  Div. 

TOC 

Tenneco  Oil  Co.,  Refining  6  Marketing 

SU 

Mobil  Chemical  Co.: 

Accoxinting 

Industrial  Chemical  Div. 

TRC 

Toms  River  Chemical  Corp. 

North  Atlantic  Div. 

TRJ 

Trojan  Powder  Co. 

Petrochemical  Div. 

TRO 

Troy  Chemical  Co. 

SM 

Socony  Mabil  Oil  Co.,  Inc.: 

ISA 

Itexas  Alky Is,  Inc. 

MDbll  Chemical  Co.  Dlv.  and 

TTX 

Detrex  Chemical  Industries,  Inc. 

Chemical  Coatings  Div.,  Louisville  Plant 

TOS 

Texas-U.S.  Chemical  Co. 

SMC 

Stamford  Chemical  Co. 

TV 

Sun  Chemical  Corp.,  Industrial  Coatings  Div. 

SNA 

Sun  Chemical  Corp.,  Chemical  Products  Div. 

TX 

Texaco,  Inc. 

SNC 

Sonooo  Products  Co. 

TXC 

Tex  Chem  Co. 

SNI 

Kaiser  Aluminum  &  Chemicals  Corp.,  Kaiser 

TXN 

Textilana-Nease,  Inc. 

Agricultural  Chemicals  Dlv. 

TXT 

Textilana  Corp. 

SNO 

SunOlin  Chemical  Co. 

■EC 

Tizon  Chemical  Corp. 

SNT 

Suntide  Refining  Co. 

SNW 

Sun  Chemical  Corp.,  Chemical  Products  Dlv. 

UBS 

A.  E.  Staley  Manufacturing  Co.,  UBS 

SOC 

Standard  Oil  Co.  of  California,  Chevron 

Chemical  Co.  Div. 

Chemical  Co. 

UCC 

Union  Carbide  Corp.,  Chemicals  Dlv. 

SOG 

Signal  Oil  &  Gas  Co. 

UCP 

Union  Carbide  Corp.,  Plastics  Div. 

SOH 

Sohlo  Chemical  Co.  &  Solar  Nitrogen  Chemicals, 

UCS 

Union  Carbide  Corp.,  Silicones  Dlv. 

Inc. 

UDI 

PetroohemlcalB  Co.,  Inc. 

SOI 

American  Oil  Co.  (Maryland) 

UHL 

Paul  Uhlloh  &   Co.,  Inc. 

SOL 

Solar  Chemical  Corp. 

UNC 

Badisehe  Products  Corp. 

SON 

Wltco  Chemical  Co.,  Inc.,  Sonnebom  Dlv. 

UNG 

Ungerer  &  Co. 

SOR 

ThomaBon  Industries,  Inc.,  Southern  Resin  Div. 

UNN 

United  Chemical  Corp.  of  Norwood 

SOS 

Southern  Sizing  Co. 

UNO 

United  Oil  Manufacturing  Co. 

SPC 

Sinclair  Paint  Co. 

UHP 

United  Chemical  Products  Corp. 

SPD 

General  Electric  Co.,  Silicone  Products  Dept. 

UNS 

Union  Starch  &  Refining  Co.,  Inc. 

SPI 

Sinclair  Petrochemicals,  Inc. 

UOC 

Union  Oil  Co.  of  California 

SPL 

Spaulding  Fibre  Co.,  Inc. 

UPF 

United  States  Pipe  &  Foundry  Co. 

SPN 

Gulf  Oil  Corp.,  Chemicals  Dept. 

UPJ 

Upjohn  Co. 

SPY 

Standard  Pyroxoloid  Corp. 

UPL 

United  States  Plywood  Corp.,  California  Div., 

SHL 

G.  D.  Searle  &  Co. 

Shasta  Operations 

SRR 

Streaen-Reuter  International,  International 

UPM 

Universal  Oil  Products  Co. 

Minerals  &  Chemical  Corp. 

UPR 

U.S.  Peroxygen  Corp. 

STA 

A.  E.  Staley  Manufacturing  Co. 

URC 

United  Carbon  Co. 

STC 

Sou-Tex  Chemical  Co.,  Inc. 

USB 

U.S.  Borax  Research  Corp. 

STG 

Stange  Co. 

USI 

National  Distillers  &  Chemical  Corp. : 

STP 

Stepan  Chemical  Co.,  Industrial  Chemicals 

A-B  Chemleal  Corp.  Div. 

Div.,  milsdale  Works 

National  Petro  Chemical  Corp.  Dlv. 

SDO 

Sucro-Chemlcal,  Div.  of  Colonial  Sugars  Co. 

U.S.  Industrial  Chemicals  Co.  Div. 

SUM 

Summit  Chemical  Products  Corp. 

USO 

U.S.  Oil  Co. 

SUN 

Sun  Oil  Co. 

USR 

Uniroyal,  Inc.,  Unlroyal  Chemloal  Div. 

DIRECTORY  OF  MANUFACTURERS 
TABLE  22. --Synthetic  organic  chemicals:   Directory  of  manufacturers ,  1966 — Continued 


Code 

Code 

identi- 

Name of  compariy 

identi- 

Name of  company 

fication 

fication 

UTR 

Utah  Resin  Co.,  Inc. 

WES 

Weston  Chemical  Corp. 

UVC 

Universal  Chemicals  Corp. 

WHC 

Whittaker  Corp.,  Narmco  Research  & 
Development  Div. 

VAC 

Vamey Chemical  Corp. 

WHI 

White  &  Hodges,  Inc. 

VAL 

Valchem 

WHL 

Whitmoyer  Laboratories,  Inc. 

VAR 

Reichhold  Chemicals,  Inc.,  Varcum  Chemical 

WHW 

Whittemore -Wright  Co.,  Inc. 

Div. 

WIC 

Wica  Chemicals,  Inc. 

VB 

Vermi lye -Bell 

WIL 

Wilson  &  Co.,  Inc.,  Wilson  Laboratories  Div. 

VDM 

Van  De  Mark  Chemical  Co. 

WJ 

Warner- Jenklnson  Manufacturing  Co. 

VEl 

Velsicol  Chemical  Corp.  &  Industrial 

WLI 

White  Laboratories,  Inc. 

Chemicals  Div. 

WLM 

Wilmot  &  Cassidy,  Inc. 

VGC 

Virginia  Chemicals,  Inc. 

WM 

Wilson  &  Co.,  Inc.,  Wilson-Martin  Div. 

VIN 

Vlneland  Chemical  Co. 

WMP 

Warner  Machine  Products,  Inc.,  Warner 

VLN 

Valley  Nitrogen  Producers,  Inc. 

Chemical  Div. 

VLY 

Chem-Fleur,  Inc. 

WOB 

Wobum  Chemical  Corp. 

TOC 

Vanderbilt  Chemical  Corp. 

WOI 

Neville  Chemical  Co. 

VND 

Van  Dyk  &  Co.,  Inc. 

WON 

Woonsocket  Color  &  Chemical  Co. 

VPC 

Verona-Pharma  Chemical  Corp. 

WRC 

Wood  Ridge  Chemical  Corp. 

VPT 

Viokers  Refining  Co.,  Inc. 

WRD 

Weyerhaeuser  Co.,  Wood  Products  Div. 

VSV 

Valentine  Sugars,  Inc.,  Vallte  Div. 

WSN 

Washine  Chemical  Corp. 

VTV 

Vita-Var  Corp.,  Div.  of  Textron  Industries, 

WTC 

Witco  Chemical  Co.,  Inc. 

Inc. 

WTH 

Wallace  &  Tlernan,  Inc.,  Harchem  Div. 

WTL 

Wallace  &  Tlernan,  Inc.,  Lucldol  Div. 

WAS 

Purex  Corp . ,  Ltd . 

WVA 

West  Virginia  Pulp  &  Paper  Co.,  Polyohemioala 

WAW 

W.  A.  Wood  Co. 

Div. 

WAY 

Philip  A.  Hunt  Chemical  Corp.,  Wayland 

WYC 

Wycon 

Chemical  Div. 

WYN 

Wyandotte  Chemicals  Corp. 

WBC 

Worthington  Biochemical  Corp. 

WYT 

American  Home  Products  Corp.,  Wyeth  Labora- 

WBG 

White  &  Bag ley  Co. 

tories,  Inc.  Div. 

WCA 

West  Coast  Adhesives  Co. 

WCC 

Witfield  Chemical  Corp. 

YAW 

Young  AniUne  Works,  Inc. 

SYNTHETIC  ORGANIC  CHEMICALS,  1966 


TABLE  22.  --Synthetic  organic  chemicals:   Directory  of  manufacturers ,  i 566 --Continued 

SECTION  2.    ALPHABETICAL  DIRECTORY  BY  CCMPANY 
[Names  of  synthetic  organic  chemical  manufacturers  that  reported  production  or  sales  to  the  U.S.   Tariff  Commission 
for  1966  are  listed  below  alphabetically,    together  with  their  identification  codes  aa  used  in  tables  in  pt.    III. 
Sec.   1  of  this  table  lists  these  manufacturers  in  the  order  of  their  identification  codes] 


Name  of  oonpany 


Office  address 


MM   Co 

Synco  Resins 

Abbott  Laboratories 

Abex  Corp.,  American  Brakeblok  Div 

Aceto  Industrial  Chemical  Corp 

Acme  Chemical  Co 

Acme  Resin  Corp 

Air  Products  &  Chemicals,  Inc. : 

Apache  Foam  Products  Div 

Houdry  Process  &  Chemical  Div 

Air  Reduction  Co.,  Inc.,  Ohio  Chemical  t 
Surgical  Bjulpment  Co.  Div. 

Alabama  Binder  &  Chemical  Corp 

Alamo  Industries,  Inc 

Alco  Chemical  Corp 

Alcolac  Chemical  Corp 

Aldrioh  Chemical  Co.,  Ino 

Alliance  Color  &  Chemical  Co 

Allied  Chemical  Corp. : 

Agricultural  Div 

Barrett  Div 

Fibers  Div 

General  Chemical  Div 

Industrial  Chemicals  Div 

Plastics  Div 

Solvay  Process  Div 

Union  Texas  Petroleum  Div 

Alox  Corp 

Amalgamated  Chemical  Corp 

Amohem  Products,  Inc 

American  Aliyd  Industries 

American  Aniline  &  Extract  Co.,  Inc 

American  Aniline  Products,  Inc 

American  Bio-Synthetics  Corp 

American  Can  Co 

American  Chemical  Corp 

American  Cyanamid  Co 

American  Hoechst  Corp 

American  Home  Products  Corp.,  \l(sreth 
Laboratories,  Inc.  Div. 

American  Oil  Co.  (Maryland) 

American  Oil  Co.  (Texas) 

American  Petrochemical  Corp 

American  Potash  &  Chemical  Corp 

American  Rubber  &  Chemical  Co 

American  Synthetic  Rubber  Corp 

American  Tartars  Corp 

Ames  Laboratories,  Ino 

Amoco  Chemicals  Corp 

Ancon  Chemical  Corp 

Ansul  Chemical  Co 

Apex  Chemical  Co.,  Inc 

Applied  Plastics  Co.,  Ino 

Arapahoe  Chemicals,  Div.  of  Syntex  Corp 

Ardmore  Chemical  Co- 

Arenol  Chemical  Corp 

Argus  Chemical  Corp 

Arizona  Chemical  Co 

Arkansas  Co.,  Inc 

Armour  Agricultural  Chemiceil  Co 

Armour  Industrial  Chemical  Co 

Armour  Pharmaceutical  Co 

Armstrong  Cork  Co 

Armstrong  Paint  &   Varnish  Works,  Ino 

Arol  Chemical  Products  Co 


500  Investors  Bldg.,  Minneapolis,  MN  55440. 

32  Henry  St.,  Bethel,  CT  06801. 

Wth  St.  and  Sheridan  Rd.,  N.  Chicago,  IL  60664. 

900  W.  Maple  Rd.,  Troy,  MI  48012. 

126-02  Northern  Blvd.,  Flushing,  New  York,  NY  11368. 

2506  N.  32nd  St.,  Milwaukee,  WI  53245. 

1401  Circle  Ave.,  Forest  Park,  IL  60130. 

P.O.  Box  7,  Belvidere,  IL  61008. 

1339  Chestnut  St.,  Philadelphia,  PA  19107. 

1400  E.  Washington  Ave.,  Madison,  WI  53701. 

P.O.  Box  3179,  Tuscaloosa,  AL  35401. 

16th  Fl.,  Daniel  Bldg.,  Oreenville,  SC  29606. 

Trenton  Ave.  and  William  St.,  Philadelphia,  PA  19134. 

3440  Fairfield  Rd.,  Baltimore,  MD  21061. 

2371  N.  30th  St.,  Milwaukee,  WI  53210. 

P.O.  Box  326,  Ridgefield,  NJ  07657. 

P.O.  Drawer  61,  Hopewell,  VA  23860. 

40  Rector  St.,  New  York,  NY  10006. 

1450  Broadway,  New  York,  NY  10018. 

Columbia  Rd.  and  Park  Ave.,  Morristown,  NJ  07960. 

Columbia  Rd.  and  Park  Ave.,  Morristown,  NJ  07960. 

P.O.  Box  365,  Morristown,  NJ  07960. 

P.O.  Box  6,  Solvay,  NY  13209. 

P.O.  Box  2120,  Houston,  TX  77001. 

3943  Buffalo  Ave.,  Niagara  Falls,  NY  14302. 

Chtario  and  Rorer  Sts.,  Philadelphia,  PA  19134. 

Brookside  Ave.,  Ambler,  PA  19002. 

Broad  and  14th  Sts.,  Carlstadt,  NJ  07072. 

Venango  and  F  Sts.,  Riiladelphia,  PA  19134. 

P.O.  Box  3063,  Paterson,  NJ  07509. 

710  W.  National  Ave.,  Milwaukee,  WI  53204. 

100  Park  Ave.,  New  York,  NY  10017. 

P.O.  Box  9247,  Long  Beach,  CA  90810. 

Wayne,  NJ  07470. 

129  Oiidnick  St.,  Coventry,  RI  02816. 
P.O.  Box  8299,  Philadelphia,  PA  19101. 

910  S.  Michigan  Ave.,  Chicago,  IL  60680. 

910  S.  Michigan  Ave.,  Chicago,  IL  60680. 

3134  California  St.,  N.E.,  Minneapolis,  MN  55418. 

3000  W.  6th  St.,  Los  Angeles,  CA  90054. 

P.O.  Box  1034,  Louisville,  KY  40201. 

P.O.  Box  360,  Louisville,  KY  40201. 

420  Lexington  Ave.,  New  York,  NY  10017. 

200  Rock  Lane,  Milford,  CT  06460. 

130  E.  Randolph  Dr.,  Chicago,  IL  60601. 
1  Stanton  St.,  Marinette,  WI  54143. 

1  Stanton  St.,  Marinette,  WI  54143. 

200  S.  1st  St.,  Elizabethport,  NJ  07206. 

130  Penn  St.,  El  Segundo,  CA  90246. 

2855  Walnut  St.,  Boulder,  CO  80302. 

840  Valley  Brook  Ave.,  I^mdhurst,  NJ  07071. 

40-33  23d  St.,  Long  Island  City,  NJ  11101. 

633  Court  St.,  Brooklyn,  NY  11231. 

Wayne,  NJ  07470. 

185  Foundry  St.,  Newark,  NJ  07105. 

P.O.  Box  1685,  Atlanta,  CA  30301. 

401  N.  Wabash  Ave.,  Chicago,  IL  60609. 

P.O.  Box  511,  Kankakee,  IL  60901. 

Liberty  and  Charlotte  Sts.,  Lancaster,  PA  17604. 

1330  S.  Kilboum  Ave.,  Chicago,  IL  60623. 

371  Wayne  St.,  Jersey  City,  NJ  07302. 


DIRECTORY  OF  MANUFACTURERS 
TABLE  22.  —Synthetic  organic  chemicals:  Directory  of  manufacturers ,  i566--Continued 


201 


of  con^jany 


Office  address 


Ashland  Oil  &  Refining  Co 

Catalln  Corp.   Div 

Astra.  Hiarmaceutioal  Products,    Ino 

Atco  Chemical-Industrial  Products,    Inc., 

Fine  Chemioals  Div. 

Atlantic   Chemical  Corp 

Atlantic  Richfield   Co. : 

ARCO  Chemical  Co.   Div -- 

Richfield  Div 

Atlantic  Tablng  &  Rubber  Co 

Atlas  Chemical  Industries,    Ino 

Atlas   Processing   Co 

Augusta  Chemical  Co 

Avisun  Corp 

Aztec  Chemicals,  Inc 

Badische  Products  Corp 

Baird  Chemical  Industries,  Ino 

Baker  Castor  Oil  Co 

J.  T.  Baker  Chemical  Co 

Taylor  Div 

Baldwin-Montrose  Chemical  Co.,  Inc., 

Montrose  Chemical  Div. 

Baltimore  Paint  &  Chemical  Corp 

J.  H.  Baxter  &   Co 

Baxter  Laboratories,  Ino 

Beech-Nut  Life  Savers,  Ino 

Belding  Chemical  Industries 

Belle  Chemical  Co.,  Ino 

Bendix  Corp.,  Marshall-Eclipse  Wv 

Bennett's 

Benzenoid  Organios,  Ino 

Bemcolors-Poughkeepsie,  Inc 

Best  Fertilizers  Co 

Blackman-Uhler  Chemical  Co 

Blue  Arrow,  Inc 

Borden  Co.,  Borden  Chemical  Co.  Div 

Borg-Wamer  Corp.,  Marbon  Chemical  Div 

Walter  N.  Boysen  Co 

Branohf lower  Co 

Brand  Plastics  Co 

Bristol-Meyers  Co.,  Bristol  Laboratories  Div- 

Brooklyn  Color  Works,  Inc 

M.  A.  Bruder  &  Sons,  Ino 

Bryant  Chemical  Corp 

Buckeye  Cellulose  Corp 

Buokman  Laboratories,  Ino 

Budd  Co.,  Polyohem  Div 

Burdick  &   Jackson  Laboratories,  Ino 

Burkart-Schier  Chemical  Co 

Burroughs-Welloome  &  Co.  (U.S.A.),  Ino 


Samuel  Cabot,  Ino — — 

Cadet  Chemical  Corp — - — 

Calcasieu  Chemioal  Corp ~ 

Callery  Chemioal  Co 

Carborundum  Co.,  Coated  Abrasives  Div- 

Cargill,  Ino 

Carlisle  Chemicals  Works,  Inc 

Advance  Div 

Carpenter-Morton  Co 

Carufl  Chemioal  Co.,    Inc 

Celanese  Corp.  of  America: 

Celanese  Chemical  Co.   Div 

Celanese  Coatings  Co 

Celanese  Plastics  Co 

Fibers  Co.   Div 

Charlotte  ChKnioal  Laboratories 


Ch&fi^  Chemical  Corp- 


1401  Winchester  Ave.,  Ashland,  KY  41101. 
1  Park  Ave.,  New  York,  NY  10016. 
7-1/2  Neponset  St.,  Worcester,  MA  01606. 
93  Main  St.,  Franklin,  NJ  07416. 

P.O.  Box  216,  Nutley,  NJ  07110. 

260  S.  Broad  St.,  Philadelphia,  PA  19101. 

&i5  South  Mariposa,  Los  Angeles,  CA  90005. 

Mill  St.,  Cranston,  RI  02905. 

Wilmington,  DE  19899. 

P.O.  Box  1786,  3546  Midway  St.,  Shreveport,  LA  71102. 

P.O.  Box  660,  Augusta,  GA  30903. 

1608  Walnut  St.,  Philadelphia,  PA  19103. 

P.O.  Box  756,  KLyrla,  OH  44035. 

Foot  of  Central  Ave.,  Kearny,  NJ  07032. 

185  Madison  Ave.,  New  York,  NY  10016. 

40  Avenue  A,  Bayonne,  NJ  07002. 

222  Red  School  Lane,  Fhilllpsburg,  NJ  08865. 

222  Red  School  Lane,  Riillipsburg,  NJ  08865. 

100  Lister  Ave.,  Newark,  NJ  07105. 

2325  Hollins  Ferry  Rd.,  Baltimore,  MD  21230. 

120  Ktontgomery  St.,  San  Francisco,  CA  94104. 

6301  N.  Uncoln  Ave.,  Morton  (Jrove,  IL  60053. 

Church  St.,  Canajoharie,  NY  13317. 

1407  Broadway,  New  York,  NY  10018. 

P.O.  Box  848,  Lowell,  NC  28089. 

P.O.  Box  238,  Troy,  NY  12180. 

65  W.  1st  S.,  Salt  Lake  City,  UT  84110. 

P.O.  Box  156,  Bellingham,  MA  02019. 

P.O.  Box  29,  77  N.  Water  St.,  Poughkeepsie,  MY  12602. 

P.O.  Box  198,  Uthrop,  CA  95330. 

P.O.  Box  5627,  Spartanburg,  SC  29301. 

5050  mgewood  Ct.,  Jacksonville,  FL  32203. 

350  Madison  Ave.,  New  York,  NY  10017. 

P.O.  Box  68,  Washington,  WV  26181. 

1001  42d  St.,  Oakland,  CA  94608. 

4501  Shilshole  Ave.,  NW.,  Seattle,  WA  98101. 

130  E.  Randolph  Dr.,  Chicago,  IL  60601. 

P.O.  Box  657,  Syracuse,  NY  13201. 

90  Linden  Blvd.,  Hicksvllle,  NY  11801. 

52d  St.  and  (S-ays  Ave.,  Philadelphia,  PA  191A3. 

6  North  St.,  N.  Oilncy,  MA  02171. 

2899  Jackson  Ave.,  HBmphlB,    TN  38108. 

1256  N.  McLean  Blvd.,  Memphis,  TN  38108. 

70  S.  Chapel  St.,  Newark,  DE  19711. 

1953  S.  Harvey  St.,  Muskegon,  MI  49442. 

1228  Chestnut  St.,  Chattanooga,  TN  37402. 

1  Scarsdale  Rd.,  Tuokahoe,  NY  10707. 


246  Summer  St.,  Boston,  MA  02210. 

2153  Lockport-Olcott  Rd.,  Burt,  NY  U028. 

P.O.  Box  1522,  Lake  Charles,  LA  70601. 

Callery,  PA  16024. 

P.O.  Box  477,  Niagara  Falls,  NY  U302. 

Room  2008,  3  Penn  Center  Plaza,  Fhlladelphla,  PA  19102. 

west  St.,  Reading,  OH  45215. 

500  Jersey  Ave.,  New  Brunswick,  NJ  08903. 

376  W.  3d  St.,  Everett,  MA  02149. 

1375  8th  St.,  LaSalle,  IL  6U01. 

522  5th  Ave.,  New  York,  NY  10036. 

1481  S.  11th  St.,  Louisville,  KY  40208. 

550  Broad  St.,  Newark,  NJ  07102. 

P.O.  Box  1414,  Charlotte,  NC  28201. 

P.O.  Box  948,  5046  Old  Plnevllle  M.,  Charlotte, 

NC  28201. 
3527  .Small man  St.,  Pittsburgh,  PA  15201. 


202  SYNTHETIC  ORGANIC  CHEMICALS,  1966 

TABLE  22.  --Synthetic  organic  chemicals:   Directory  of  manufacturers ,  i 966- -Continued 


of  company 


Office  address 


Chattem  Drug  &  Ghemlcal   Co.,    Qiattem 

Chemicals  Div. 

Chemagro  Corp 

Chembond  Corp 

Ghemetron  Corp. : 

Chemetron  Chemicals  Div.,  Organic  Chemical 
Dept. 

National  Cylinder  Gas  Div 

Ghem-Fleur,  Ino 

Chemical  Formulators,  Inc 

Chemical  Insecticide  Corp 

Chemical  Products  Corp 

Chemical  Services  of  Baltimore,  Inc 

Chemioo,  Inc 

Chemlek  Laboratories,  Ino 

Chevron  Chemical  Co. : 

Additives  Div 

Ortho  Div 

Chllds  Pulp  Colors,  Inc 

Chipman  Chemical  Co.,  Inc 

Ciba  Chemical  &  Dye  Co 

Ciba  Corp. : 

Ciba  Hiarmaoeutical   Co.   Div 

Ciba  Products  Co 

Cities  Service  Oil   Co 

Clark  Oil  &  Refining   Corp 

W.   A.    Cleary  Corp 

Clintwood  Chemical  Co 

Clover  Chemical  Co 

Cockerille  Chemicals,  Inc 

Colab  Resin  Corp 

Colgate- Pal  unlive  Co 

Collier  Carbon  &  Chemical  Corp 

Colloids,  Inc 

Columbia  Organic  Chemicals  Co.,  Inc 

Columbian  Carbon  Co 

Chemicals  Div 

Columbian  Nitrogen  Corp 

Commercial  Products  Co.,  Ino 

Commercial  Solvents  Corp 

Commonwealth  Oil  Refining  Co.,  Ino 

Conchemoo,  Inc.,  H.  B.  Davis  Co.  Div 

Concord  Chemical  Co.,  Inc 

Conestoga  Chemical  Corp 

Consolidated  Papers,  Inc 

Continental  Chemical  Co 

Continental  Oil  Co 

Cook  Paint  &  Varnish  Co 

Cooperative  Farm  Chemicals  Association 

Coopers  Creek  Chemical  Corp 

Copolymer  Rubber  &   Chemical  Corp 

Com  Products  Co 

Cosden  Oil  &  Chemical  Co 

Cowles  Chemical  Co 

Benzol  Products  Div 

Crest  Chemical  Corp 

Crompton  &  Knowles  Corp.,  Chemicals  Group, 

Althouse  &   Bates  Div. 

Crosby  Chemicals,  Inc 

Crown  Central  Petroleum  Corp 

Crown  Chemical  Corp 

Crown  Zellerbaoh  Corp.,  Chemioal  Products  Div 

Culver  Chemical  Co 

Cumberland  Chemioal  Corp.,  Subsidiary  of 

Reduction  Co.,  Ino. 

Cutter  Laboratories,  Ino 

Cjrolamate  Corp.  of  America 


1715  W.  38th  St.,  Chattanooga,  TN  37409. 

P.O.  Box  4913,  Station  "F",  Kansas  City,  MO  64120. 
P.O.  Box  270,  Springfield,  OR  97477. 

201  E.  42d  St.,  New  York,  NY  10017. 

840  N.  Michigan  Ave.,  Chicago,  IL  60611. 

200  Palaski  St.,  Newark,  NJ  07105. 

P.O.  Box  26,  Nitro,  WV  25143. 

20  Whitman  Ave.,  Metuchen,  NJ  08840. 

P.O.  Box  449,  Cartersville,  GA  30120. 

Howard  and  West  Sts.,  Baltimore,  MD  21230. 

2508  E.  Bailey  Rd.,  Cuyahoga  Falls,  OH  44221. 

4040  W.  123d  St.,  Alsip,  IL  60658. 

P.O.  Box  3227,  Greensboro,  NC  27402. 

200  Bush  St.,  San  Francisco,  CA  94120. 

940  Hensley,  Richmond,  CA  94801. 

43  Summit  St.,  Brooklyn,  NY  11231. 

P.O.  Box  2009,  297  Jersey  Ave.,  New  Brunswick,  NJ 

08903. 
Route  208,  Fair  Lawn,  NJ  07410. 

556  Morris  Ave.,  Summit,  NJ  07901. 

556  Morris  Ave.,  Summit,  NJ  07901. 

P.O.  Box  300,  Tulsa,  OK  74101. 

131st  St.  and  Kedzle  Ave.,  Blue  Island,  IL  60406. 

P.O.  Box  749,  New  Brunswick,  NJ  08903. 

1  N.  LaSalle  St.,  Chicago,  IL  60602. 

P.O.  Box  146,  Eighty  Four,  PA  15330. 

Greenwood,  VA  22%3. 

Main  St.,  Tewksbury,  MA  01876. 

300  Park  Ave.,  New  York,  NY  10022. 

714  W.  Olynpic  Blvd.,  Los  Angeles,  CA  90015. 

394  Frelinghuysen  Ave.,  Newark,  NJ  07114. 

912  Drake  St.,  Columbia,  SC  29205. 

380  Madison  Ave.,  New  York,  NY  10017. 

P.O.  Box  1522,  Lake  Charles,  LA  70601. 

P.O.  Box  1483,  Augusta,  GA  30903. 

117  Ethel  Ave.,  Hawthorne,  NJ  07641. 

260  Madison  Ave.,  New  York,  NY  10016. 

P.O.  Box  ^23,  San  Juan,  PR  00905. 

Bayard  and  Severn  Sts.,  Baltimore,  MD  21230. 

205  S.  2d  St.,  Camden,  NJ  08103. 

Wilmington  Industrial  Park,  Wilmington,  DE  19801. 

Wisconsin  Rapids,  WI  54494. 

270  Clifton  Blvd.,  Clifton,  NJ  07015. 

9  Rockefeller  Plaza,  New  York,  NY  10020. 

P.O.  Box  389,  N.  Kansas  City,  MO  64L41. 

P.O.  Box  308,  Lawrence,  KS  66044. 

River  Rd.,  W.  Conshohocken,  PA  19428. 

P.O.  Box  2591,  Baton  Rouge,  LA  70821. 

717  5th  Ave.,  New  York,  NY  10022. 

P.O.  Box  1311,  Big  Spring,  TX  70720. 

12000  Shaker  Blvd.,  Cleveland,  OH  44120. 

237  South  St.,  Newark,  NJ  0711A. 

225  Branet  St.,  Newark,  NJ  07114. 

500  Pear  St.,  Reading,  PA  19603. 

P.O.  Drawer  32,  DeRldder,  LA  70634. 

P.O.  Box  1168,  Baltimore,  MD  21203. 

12  Dudley  St.,  Providence,  RI  02901. 

Camas,  WA  98607. 

1502  N.  25th  St.,  Melrose  Park,  IL  60160. 

150  E.  42d  St.,  New  York,  NY  10017. 

4th  and  Parker  Sts.,  Berkeley,  CA  94710. 
100  Lister  Ave.,  Newark,  NJ  07105. 


DIRECTORY  OF  MANUFACTURERS  203 

TABLE  22.  —Synthetic  organic  chemicals.-  Directory  of  manufacturers ,  i 566 --Continued 


Name  of  company 


Office  address 


Dan  River  Mills,    Ino 

Davles-Youiig  Soap  Co 

Josepli  Davis  Plastics  Co 

Dawe's  Laboratories,   Inc 

Degen  Oil  &  Chemical  Co 

DePaul  Chemical   Co.,    Inc 

DeSoto  Chemical  Coatings,    Inc 

Detrex  Chemical  Industries,    Inc 

Dexter  Chemical   Corp 

Diamond  Alkali   Co 

Western  Div 

Diversey  Corp 

DLxie  Chemical  Co 

Dixie  Pine  Products  Co.,  Inc 

Dominion  Products,  Ino 

Dover  Chemical  Co 

Dow  Badische  Co 

Dow  Chemical  Co 

Dow  Corning  Corp 

Drew  Chemical  Corp 

Frank  W.  Dunne  Co 

E.  I.  duftjnt  de  Nemours  &  Co.,  Ino 

Eye  Specialties,  Inc 

J.   S.   &  W.   R.    EaMns,    Inc 

Intern  Color  &  Chemical  Co 

Eastman  Kodak  Co 

Tennessee  E^tman  Co.   Div 

Texas  Eastman  Co.   Div 

East  Shore  Chemical  Co.,    Ino 

Blcan  Laboratories 

EL  Paso  Products  Co 

Bnery  Industries,    Inc 

Western  Div 

Bukay  Chemical  Co 

Bido  Laboratories,  Inc 

Bijay  Chemical  Co 

:^oxylite  Corp 

Escambia  Chemical  Corp 

Ethyl  Corp 

Ethyl-Dow  Chemical  Co 

Evans  Chemetios,  Ino 

PMC  Corp. : 

JUnerican  Viscose  Div 

Inorganic  Chemicals  Div 

Niagara  Chemical  Div 

Organic  Chemloais  Div 

Fabricolor  Manufacturing  Corp 

Falrmount  Chemical  Co.,   Inc 

Farac   Oil  &  Chemical  Co.,   Div  of  Handschy 

Qiemical  Co. 

Far- Best  Corp.,    0.   L.    King  Div 

Fanners  Chemical  Association,    Inc 

Farmer's  Chemical  Co 

Famow,    Ino 

Federal  Color  Laboratories 

Fel-Tex,    Ino 

Felton  Chemical  Co.,  Inc 

Ferro  Corp.,  Ferro  Chemical  Div- 
Fibreboard  Oorp 
Filtered  Rosin  Products  Co- 
Fine  Organlcs,  Inc 
Firestone  Tire  &  Rubber  Co. 

Firestone  Plastics  Co 

Firestone  Rubber  &  Latex  Products  Co.  Div. 

Firestone  ^mthetic  Rubber  &   Latex  Co.  DlV' 
Flstier  Melamine  Corp' 


Danville,  VA  24540. 

705  Albany  St.,  Dayton,  OH  45401. 

450  Schuyler  Ave.,  Kearny,  NJ  07032. 

4800  S.  Richmond  St.,  Chicago,  IL  60632. 

200  Kellogg  St.,  Jersey  City,  NJ  07305. 

4^-27  Purvis  St.,  Long  Island  City,  NY  11101. 

1700  S.  Mt.  Prospect  Ave.,  Des  Plaines,  IL  60018. 

14331  Woodrow  Wilson,  Detroit,  MI  48232. 

845  fllgewater  Rd.,  Bronx,  MY  10474. 

300  Union  Commerce  Bldg.,  Cleveland,  OH  44114. 

300  Union  Commerce  Bldg.,  Cleveland,  OH  4^114. 

212  W.  Monroe  St.,  Chicago,  IL  60606. 

3635  W.  Dallas  Ave.,  Houston,  TX  77019. 

P.O.  Box  470,  Hattiesburg,  MS  39401. 

882  3d  Ave.,  Brooklyn,  NY  11232. 

15th  and  Davis  Sts.,  Dover,  OH  44622. 

Williamsburg,  VA  23185. 

Midland,  MI  48640. 

P.O.  Box  582,  Midland,  MI  48640. 

416  Division  St.,  Boonton,  NJ  07005. 

1007  41st  St.,  Oakland,  CA  94608. 

DuPont  Bldg.,  Wilmington,  DE  19898. 

26  Journal  Sq.,  Jersey  City,  NJ  07306. 

55  Berry  St.,  Brooklyn,  NY  11211. 

35  Livingston  St.,  Providence,  RI  02904. 

343  State  St.,  Rochester,  NY  14650. 

P.O.  Box  511,  Kingsport,  TN  37662. 

P.O.  Box  2068,  Longview,  TX  75601. 

1180  Michigan  Ave.,  Muskegon,  MI  49440. 

18  Marshall,  S.  Norwalk,  CT  06856. 

P.O.  Box  3986,  Odessa,  TX  79760. 

4300  Carew  Tower,  Cincinnati,  OH  45202. 

8733  S.  Dice  Rd.,  Santa  Fe  Springs,  CA  90670. 

319  2d  St.,  Elizabeth,  NJ  07206. 

1000  Stewart  Ave.,  Garden  City,  NY  11530. 

60  W.  49th  St.,  New  York,  NY  10020. 

1428  N.  T^rler  Ave.,  S.  EL  Monte,  CA  91733. 

P.O.  Box  467,  Pensacola,  FL  32502. 

100  Park  Ave.,  New  York,  NY  10017. 

Midland,  MI  48640. 

250  E.  43d  St.,  New  York,  NY  10017. 


1617  John  F.  Kennedy  Blvd.,  Hiiladelphia,  PA  19103. 
Sawyer  Ave.  and  River  Rd.,  Tonawanda,  NY  14207,  and 

633  3d  Ave.,  New  York,  NY  10017. 
100  Niagara  St.,  Middleport,  NY  14105. 
1701  Patapsco  Dr.,  Baltimore,  MD  21226,  and  P.O.  Box 

547,  Nitro,  WV  25U3. 
24-1/2  Van  Houten  St.,  Paterson,  NJ  07505. 
117  Blanchard  St.,  Newark,  NJ  07105. 
147th  St.  and  Indiana  Ave.,  CJiicago,  IL  60627. 

640  Oilman  St.,  Berkeley,  CA  94710. 

P.O.  Box  67,  TJmer,  TN  37392. 

P.O.  Box  591,  Kalamazoo,  MI  49005. 

77  Jacobus  Ave.,  S.  Kearny,  NJ  07032. 

4526  Chickering  Ave.,  Cincinnati,  OH  45232. 

P.O.  Box  68,  Fremont,  NB  68025. 

599  Johnson  Ave.,  Brooklyn,  NY  11237. 

P.O.  Box  3A9,  Bedford,  OH  440U. 

P.O.  Box  431A,  Oakland,  CA  94623. 

P.O.  Box  349,  Baxley,  GA  31513. 

205  Main  St.,  Lodi,  NJ  0764-;. 


P.O.  Box  699,  Pottatown,  PA  19464. 
P.O.  Box  2290,  Fall  River,  MA  02722. 
381  W.  Wilbeth  Rd.,  Akron,  OH  44301. 
90  Park  Ave.,  New  York,  NY  10016. 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 
TABLE  22.  -Synthetic  organic  chemicals:  Directory  of  manufacturers ,  2 966 --Continued 

Office  address 


Fleming  Laboratories,    Inc 

Florasynth,    Ino 

Foote  Mineral  Co 

ForeniDst  Chemical  Products  Co 

Formica  Corp 

Foster  Grant  Co.,    Ino 

Foster-Heaton  Co 

France,    Can^ibell  &  Darling,    Inc 

Franklin  Chemical  Co 

Freeman  Chemioal  Corp 

Frisch  &  Co.,   Inc 

Fritzsche  Bros.,    Inc 

H.    B.   Fuller  Co 

W.    P.    Fuller  Paint  Co 

Gemma  Chemioal  Corp 

Gane's   Chemical  Iforks,    Inc 

Geigy  Chemioal  Corp 

General  Aniline  &  Film  Corp.,   Eyestuff  & 

Chemical  Div. 
General  Electric  Co. : 

Chemioal  Materials  Dept 

Insulating  Materials  Dept 

Silicone  Products  Dept— 

General  Foods  Corp.,   Maxwell  House  Div 

General  Latex  &  Chemical  Corp 

General  Mills,    Ino 

Chemical  Div 

General  Plastics  Manufacturing   Co 

General  Tire  &  Rubber  Co.,   Chemioal  Div 

P.    D.   George  Co 

Georgia-Pacific  Corp. : 

Coos  Bay  Div 

Puget  Sound  Div 

Gillette  Chemical  Co 

Oilman  Paint  &  Varnish  Co 

Givaudan  Corp 

Glasflex,  Ino 

Glidden  Co 

Durkee  Famous  Foods  Div 

Glyco  Chemicals,  Inc 

B.  F.  Goodrich  Co.,  B.  F.  Goodrich  Chemioal 
Co.  Div. 

Goodrich-Gulf  Chemicals,  Ino 

Goodyear  Tire  &  Rubber  Co 

Gordon  Chemioals  Co.,  Inc 

.  R.  Grace  &  Co. : 

Agricultural  Products  Div 

Dewey  &  Alny  Chemioal  Div 

Dubois  Chemioals  Div 

HaiUJShire  Chemical  Div 

Hatoo  Chemical  Div 

Maroo  Chemical  Div 

Vestal  Laboratories  Div 

Grain  Processing  Corp 

Great  American  Plastics  Co 

Great  Lakes  Chemioal  Corp 

Great  Western  Sugar  Co 

A.  Gross  Sc   Co.,  Inc 

Grow  Chemioal  Corp.,  Harris  Paint  Co.  Div — 

Guardsman  Chemioal  Coatings,  Ino 

Gulf  Oil  Corp 

Chemicals  Dept 

Perkins  Glue  Branch 

Guth  Chemical  Co 

H  &  N  Chemioal  Co 

Haag  Laboratories,  Inc 

Halby  Rroduots  Co.,  Inc 


P.O.  Box  10372,  Charlotte,  NC  28201. 

900  Van  Nest  Ave.,  Bronx,  NY  10^62. 

Route  100,  Bcton,  PA  193A1. 

P.O.  Box  599,  Oakland,  CA  94604. 

Wayne,  NJ  07470. 

289  N.  Main  St.,  Leominster,  MA  01453. 

E.  5th  St.,  Paterson,  NJ  07524. 
N.  Michigan  Ave.,  Kenllworth,  NJ  07033. 
2020  Bruok  St.,  Columbus,  OH  43207. 
222  E.  Main  St.,  Port  Washington,  WI  53074. 

E.  11th  St.,  Paterson,  NJ  07524. 
76  9th  Ave.,  New  York,  NY  10011. 
1150  Bistio  St.,  St.  Paul,  MN  55108. 
450  E.  Grand  Ave.,  S.  San  Francisco,  CA  94080. 

90  Park  Ave.,  New  York,  NY  10016. 
535  5th  Ave.,  New  York,  NY  10017. 
Saw  Mill  River  Rd.,  Ardsley,  NY  10502. 
P.O.  Box  2164,  Greenville,  SC  29602,  and  P.O.  Box  12, 
Unden,  NJ  07036. 

1  Plastics  Ave.,  Coshocton,  OH  43812,  and  1  Plastics 

Ave.,  Plttsfield,  MA  01203. 
1  River  Hd.,  Schenectady,  NY  12305. 
Waterford,  NY  12188. 
1125  Hudson  St.,  Hoboken,  NJ  07030. 
666  Main  St.,  Cambridge,  MA  02139. 
S.  Kensington  Rd.,  Kankakee,  IL  60901. 
Qaimby  St.,  Ossining,  NY  10562. 
3481  S.  35th  St.,  Taooma,  WA  98409. 
1708  Biglewood  Ave.,  Akron,  OH  44309. 
5200  N.  2d  St.,  St.  Louis,  MO  63L47. 

P.O.  Box  869,  Coos  Bay,  OR  97420. 

P.O.  Box  1236,  Bellingham,  WA  98225. 

P.O.  Box  362,  N.  Chicago,  IL  60064. 

W.  8th  and  Fine  Sts.,  Chattanooga,  TN  37401. 

125  Delawanna  Ave.,  Clifton,  NJ  07014. 

Stirling,  NJ  07980. 

900  Union  Commerce  Bldg.,  Cleveland,  OH  44115. 

2333  Logan  Blvd.,  Chicago,  IL  60647. 

417  5th  Ave.,  New  York,  NY  10016. 

3135  Euclid  Ave.,  Cleveland,  OH  44137. 


1717  E.  9th  St. 
lUA  E.  Market 
88  Webster  St., 


Cleveland,  OH  44114. 
5t.,  Akron,  OH  44316. 
Worcester,  MA  01603. 


P.O.  Box  277,  147  Jefferson  Ave.,  Meii?)his,  TN  38101. 

62  Whittemore  Ave.,  Cambridge,  MA  02W0. 

634  Broadway,  Cincinnati,  OH  45202. 

Poiseon  Ave.,  Nashua,  NH  03060. 

629  AniJoy  St.,  Fords,  NJ  08863. 

1711  W.  Elizabeth  Ave.,  Linden,  NJ  07036. 

4963  Manchester  Ave.,  St.  Louis,  MO  63110. 

1600  Oregon  St.,  Muscatine,  LA  52761. 

85  Water  St.,  Fitohburg,  MA  21420. 

P.O.  Box  2200,  west  Lafayette,  IN  47906. 

P.O.  Box  5308,  Terminal  Annex,  Denver,  CO  80217. 

295  Madison  Ave.,  New  York,  NY  10017. 

1010-26  N.  19th  St.,  Tan?)a,FL.  33601. 

1350  Steele  Ave.  SW.,  Grand  Rapids,  MI  49502. 

P.O.  Drawer  2100,  Houston,  TX  77001. 

Dwight  Bldg.,  Kansas  City,  MO  64105. 

632  Cannon  Ave.,  Lansdale,  PA  19446. 

332  S.  Center  St.,  Hillside,  IL  60162. 

90  Maltese  Dr.,  Totowa,  NJ  07512. 
lAOlO  S.  Seeley,  Blue  Island,  IL  60406. 
P.O.  Box  366,  Wilmington,  DE  19899. 


DIRECTORY  OF  MANUFACTURERS  205 

TABLE  22.  --Synthetic  organic  chemicals;  Directory  of  manufacturers ,  i 966— Continued 


Name  of  company 


C.   P.   Hall  Co.   of   Illinois 

Hanfxlen  Color  &  Chemical   Co 

Hanna  Paint  Manufacturing  Co.,    Ino 

Harshaw  Chemical   Co.,   Div.   of  Kewanee  Oil  Co- 

Hartman-Leddon  Co 

Hart  Products   Corp 

Haveg   Industries,    Inc.,    Resin  &  Con^jound  Div- 

Hawkeye  Chemical  Co 

Hercules,    Inc 

Iiqjerial  Color  &  Chemical  Dept 

Heresite  &  Chemical  Co 

Hess  Oil  &  Chemical  Corp 

Heterochemical  Corp 

Hexagon  Laboratories,    Ino 

Hodag   Chemical   Corp 

Hoffmann- Laltoche,    Ino 

Hoffman-Taff,    Ino 

Holland-Suoo  Color   Co 

Hooker  Chemical  Corp 

Durez   Plastics  Div 

Ruoo  ttlv 

E.   F.   Houghton  &  Co 

Houston  Chemical  Corp 

Charles  L.   Huisklng  &  Co.,    Inc.,    Clintbrook 

Chemical  Co.   Div. 

Huii5)hrey  Chemical  Co ; 

Philip  A.   Hunt  Chemical   Corp.,    Wayland 

Chemical  Div. 

Huntington  Laboratories,    Inc 

Husky  Briquetting,    Inc 

fftrason,   Westcott  &  IXmning,    Inc 

Itysol  Corp 

I.C.I.    (Qrganics),    Inc 

IRC,    Ino 

Inperial,    Inc 

Industrial  Bloohemioals 

Industrial  Eyestuff   Co 

Inland  Steel  Container  Co 

Interohemloal  Corp. : 

Color  &  Chemicals  Div 

Finishes  Div 

Organic   Chemicals  Dept 

International  Flavors  &  Frangrances,    Inc 

International  Latex  &  Chemical  Corp 

Paisley  Products  Div 

International  Minerals  &  Chemical  Corp 

Inter-Pacific  Resins,    Inc 

Interplastio   Corp.,    Commercial  Resins  Div 

Ironsides  Resins,    Inc 

Isocyanate  Products,    Inc 

Jefferson  Chemical  Co.,    Inc 

Jennlson-ffright  Corp 

Andrew  Jergens  Co 

Jersey  State  Chemical  Co 

Jewel  Paint  &  Varnish  Co 

S.    C.    Johnson  &  Son,    Inc 

Jones-Blair  Paint  Co 

Jordan  Chemical  Co 

Kaiser  Aluminum  &  Chemical  Corp.: 

Kaiser  Agricultural  Chemicals  Div 

Kaiser  Chemical  Div 

Kali  Manufacturing  Co 

Kay-Fries  Chemicals,  Inc 

Keil  Chemical  Co 

Kelly-Jfoore  Paint  Co ^ 

Kelly-Piokerlng  Chemical  Corp 

Kendall  Refining  Co 


7300  S.  Central  Ave.,  Chicago,  IL  60638. 

5  Albany  St.,  Springfield,  MA  01101. 

P.O.  Box  Wr,    Columbus,  OH  «216. 

1945  E.  97th  St.,  Cleveland,  OH  44106. 

60th  St.  and  Woodland  Ave.,  Philadelphia,  PA  191A3. 

1440  Broadway,  New  York,  NY  10018. 

900  Greenba'-Ji  Rd.,  Wilmington,  DE  19808. 

P.O.  Box  899,  Clinton,  LA  52733. 

Hercules  Tower,  910  Market  St.,  Wilmington,  DE  19899. 

P.O.  Box  231,  Glens  Falls,  NY  12803. 

822  S.  14th  St.,  Manitowoc,  WI  54220. 

280  Park  Ave.,  New  York,  NY  10017. 

Ill  E.  Hawthorne  Ave.,  Valley  Stream,  NY  11582. 

3536  Peartree  Ave.,  Bronx,  NY  10469. 

7247  N.  Central  Park  Ave.,  Skokie,  IL  60076. 

324-424  Klngsland  Rd.,  Nutley,  NJ  07110. 

P.O.  Box  1246  SSS,  Springfield,  MO  65805. 

P.O.  Box  2166,  Huntington,  WV  25722. 

Long  Rd.,  Grand  Island,  NY  14072. 

Walok  Rd.,  N.  Tonawanda,  NY  14121. 

New  South  Rd.,  Hioksville,  L.I.,  NY  11802. 

303  W.  Lehigh  Ave.,  Philadelphia,  PA  19133. 

1  Gateway  Center,  Httsburgh,  PA  15222. 

417  5th  Ave.,  New  York,  NY  10016. 

Devlne  St.,  North  Haven,  CT  06473. 
P.O.  Box  63,  Uncoln,  HI  02865. 

P.O.  Box  710,  Huntington,  IN  46750. 

P.O.  Box  380,  Cody,  WY  82414. 

Charles  and  Chase  Sts.,  Baltimore,  MD  21201. 

1100  Seneca  Ave.,  Olean,  NY  U760. 

55  Canal  St.,  Providence,  RI  02901. 

401  N.  Broad  St.,  Riiladelphia,  PA  19108. 

W.  6th  and  Grass  Sts.,  Shenandoah,  lA  51601. 

U.S.  Highway  1,  Edison,  NJ  08817. 

P.O.  Box  4249,  E.  Providence,  RI  02914. 

6532  S.  Menard  Ave.,  Chicago,  IL  60638. 

150  Wagaraw  Rd.,  Hawthorne,  NJ  07506. 

1255  Broad  St.,  Clifton,  NJ  07015. 

Berry  Ave.  and  13th  St.,  Carlstadt.  NJ  07072. 

521  W.  57th  St.,  New  York,  NY  10019. 

P.O.  Drawer  K,  Playtex  Park,  Dover,  DE  19901. 

1770  Canalport  Ave.,  Chicago,  IL  60616. 

5401  Old  Orchard  Rd.,  Skokie,  IL  60078. 

P.O.  Box  445,  1602  N.  18th  St.,  Sweet  Home,  OR  97386. 

2015  N.E.  Broadway  St.,  Minneapolis,  MN  55413. 

270  W.  Mound  St.,  P.O.  Box  1999,  Columbus,  OH  43216. 

900  Wilmington  Rd.,  New  Castle,  DE  19720. 

P.O.  Box  53300,  Houston,  TX  77052. 

P.O.  Box  691,  Toledo,  OH  43601. 

2535  Spring  Grove  Ave.,  Cincinnati,  OH  45214. 

59  Lee  Ave.,  Haledon,  NJ  07508. 

345  N.  Western  Ave.,  Chicago,  IL  60612. 

1525  Howe  St.,  Racine,  WI  53403. 

6969  Denton  Dr.,  Dallas,  TX  75235. 

Barclay  Bldg.,  1  Belmont  Ave.,  Bala  Qynwyd,  PA  19004. 


P.O.  Box  246,  Savannah,  OA  31402. 
P.O.  Box  337,  Gramercy,  LA  70052. 
427  E.  Itoyer  St.,  Philadelphia,  PA  19125. 
360  Lexington  Ave.,  New  York,  NY  10017. 
3000  Sheffield  Ave.,  Hammond,  IN  46320. 
1015  Commercial  St.,  San  Carlos,  CA  94070. 
956  Bransten  Rd.,  San  Carlos,  CA  94070. 
77  N.  Kendall  Ave.,  Bradford,  PA  16701. 


206  SYNTHETIC  ORGANIC  CHEMICALS.  1966 

TABLE  22. -Synthetic  organic  chemicals:  Directory  of  manufacturers ,  i 566 --Continued 


Name  of  company 


MID 
MRA 
JMB 
MCH 
yrm 
UPP 
ULS 


Keimeoott  Copper  Corp. : 

Chlno  Mines  Div 

Utah  Copper  Div 

Kenrioh  Petrochemioals,    Ino 

Ketona  Chemloal   Corp 

Keysor  Chemical  Co 

Keystone   Chemurglo   Corp 

Keystone  Color  Works,    Inc 

Knapp  Products,    Inc 

Knoedler  Chemical  Co 

Kohler-McLister  Paint  Co 

H.   Kohnstaram  &  Co.,    Inc 

Koppers  Co.,    Inc.,    Tar  &  Chemical 

Koppers   Pittsburgh  Co 

Kyanize  Paints,    Ino 


Lakeside  Laboratories,   Div,   of  Colgate- 
Palmolive  Co. 

Lakeway  Chemical  Co 

LaMotte  Chemloal  Products   Co 

Lancaster  Chemical  Corp.,  Gordon  Chendeals 
Co.   Div. 

Lasoo  Industries,    Inc 

Laurel  Products   Corp 

Lawter  Chemicals,    Inc.,    Krumbhaar  Resin  Div 

Leatex  Chemical  Co 

Lebanon  Chemical   Corp 

Leffingwell  Chemical  Co 

Lehn  &  Fink  Products  Corp.,    Beacon  Div 

B.  L.   Lemke  &  Co.,    Inc 

Leonard  Refineries,  Ino 

Lever  Brothers  Co 

C.  Lever  Co.,  Inc 

Fred'k  H.   Levey  Co.,    Ino 

Lignin  Products  Co 

ELi  Lilly  &  Co 

Lubrlzol  Corp 

George  Lueders  &  Co.,  Inc 


of  Pickands 


M  &  T  Chemicals,    Inc 

Magruder  Color  Co.,    Ino 

Maher  Color  &  Chemical  Co 

Malllnckrodt  Chemical  Works- 
Manganese  Chemical  Co.,    Div. 
Mather  &  Co. 

Marathon  Oil  Co.,   Texas  Refining  Div 

Marblette  Corp 

Marden-Wild   Corp 

Marlowe-Van  Loan  Corp 

Martin-Marietta  Corp. : 

Ridgway  Color  &  Chemical  Div 

Southern  Eyestuff  Co.  Div 

Max  Marx  Color  &  Chemloal  Co 

Masonite  Corp.,   Alpine  Chemical  Div 

Mathe  Chemical  Co 

Maumee  Chemical  Co 

Otto  B.  May,    Ino 

MoCloskey  Varnish  Co 

McLaughlin  Gormley  King  Co 

Medical  Chemicals  Corp 

Merck  &  Co.,  Inc 

Meriohem  Co 

Metalead  Products  Corp 

Metro-Atlantic,  Ino 

J.  Meyer  &  Sons,  Ino 

Michigan  Chemical  Corp 

Midland  Industrial  Finishes  Co 

Midwest  Plastic  Products  Co 

Miles  Laboratories,  Inc.,  CbemioalE  Dlv- 


Hurley,  MM  88043. 

P.O.  Box  11299,  Salt  Lake  City,  UT  84111. 

Foot  of  E.  22d  St.,  Bayonne,  NJ  07002. 

P.O.  Box  6565,  Tarrant  Branch,  Birmingham,  AL  35217. 

26000  Bouquet  Canyon  Rd.,  Saugus,  CA  91350. 

R.D.  2,  Bethlehem,  PA  18017. 

151  W.  Gay  Ave.,  York,  PA  17403. 

180  Hamilton  Ave.,  Lodi,  NJ  07644. 

651  High  St.,  Lancaster,  PA  17604. 

P.O.  Box  546,  1201  Osage  St.,  Denver,  CO  80201. 

161  Avenue  of  the  Americas,  New  York,  NY  10013. 

Koppers  Bldg.,  430  7th  Ave.,  Pittsburgh,  PA  15219. 

Koppers  Bldg.,  430  7th  Ave.,  Pittsburgh,  PA  15219. 

2d  and  Boston  Sts.,  Everett,  MA  02149. 

1707  E.  North  Ave.,  Milwaukee,  WI  53201. 

5025  Evanston  Ave.,  Muskegon,  MI  49443. 

Chestertown,  MD  21620. 

500  A  St.,  Wilmington,  DE  19801. 

1561  Qiapin  Rd.,  Montebello,  CA  90640. 

2600  Tioga  St.,  Hiiladelphia,  PA  19134. 

3550  Touhy  Ave.,  Chicago,  IL  60645. 

2722  N.  Hancock  St.,  Hiiladelphia,  PA  19133. 

P.O.  Box  180,  Lebanon,  PA  17CK2. 

P.O.  Box  185,  Brea,  CA  92621. 

33  Riohdale  Ave.,  Cambridge,  MA  02140. 

199  Main  St.,  Lodi,  NJ  07644. 

E.  Superior  St.,  Alma,  MI  48801. 

390  Park  Ave.,  New  York,  NY  10022. 

Howard  and  Huntington  Sts.,  Philadelphia,  PA  19133. 

380  Madison  Ave.,  New  York,  NY  10017. 

P.O.  Box  960,  Erie,  PA  16512. 

740  S.  Alabama  St.,  Indianapolis,  IN  46206. 

29400  Lakeland  Blvd.,  Wiokliffe,  OH  44117. 

427  Washington  St.,  New  York,  NY  10013. 

Woodbridge  Rd.  and  Randolph  Ave.,  Rahway,  NJ  07065. 

1  Virginia  St.,  Newark,  NJ  071U. 

1700  N.  ELston  Ave.,  Chicago,  IL  60622. 

3600  N.  2nd  St.,  St.  Louis,  MO  63147. 

2000  Union  Commerce  Bldg.,  Cleveland,  OH  44115. 

P.O.  Box  1191,  Texas  City,  TX  77590. 

37-31  30th  St.,  Long  Island  City,  NY  11101. 

500  Columbia  St.,  Somerville,  MA  02143. 

P.O.  Box  1851,  1511  Joshua  Circle,  High  Point,  NO  27261. 

75  Front  St.,  Ridgway,  PA  15853. 

P.O.  Box  10098,  Charlotte,  NC  28201. 

192  Colt  St.,  Irvington,  NJ  07111. 

P.O.  Box  2392,  Gulfport,  MS  39503. 

169  Millbank  St.,  Lodi,  NJ  07644. 

1310  Expressway  Dr.,  Toledo,  OH  43608. 

52  Amsterdam  St.,  Newark,  NJ  07105. 

7600  State  Rd.,  Billadelphia,  PA  19136. 

1715  S.E.  5th  St.,  Minneapolis,  MN  554U. 

4541  W.  CSrand  Ave.,  Chicago,  IL  60639. 

126  E.  Lincoln  Ave.,  Rahway,  NJ  07065. 

19U  Haden  Rd.,  Houston,  TX  77015. 

P.O.  Box  11005,  2901  Park  Blvd.,  Palo  Alto,  CA  94306. 

2027  Smith  St.,  Centerdale,  RI  02911. 

4321  N.  4th  St.,  Riiladelphia,  PA  19140. 

2  N.  Riverside  Plaza,  Chicago,  IL  60606. 

P.O.  Box  620,  E.  Water,  St.,  Waukegan,  IL  60086. 

3251  Chicago  Rd.,  Stager,  IL  64075. 

l^tle  and  McNaughton  Ste.,  Elkhart,  IN  4651A. 


DIRECTORY  OF  MANUFACTURERS 
TABLE  22.  --Synthetic  organic  chemicals:  Directory  of  manufacturers ,  i 566- -Continued 


Identi- 
fication 
code 


Name  of  company 


Office  address 


Mill  master  Onyx  Corp. : 

Berkeley  Chemical  Div 

Onyx  Chemical  Div 

Mineral  Oil  Refining   Co 

Minnesota  Mining  &  Manufacturing   Co 

Minnesota  Paints,    Inc 

Mlranol  Chemical  Co.,    Inc 

sissippi   Chemical  Corp 

Mobay  Chemical  Co 

Mobil   Chemical  Co. : 

Industrial  Chemical  Div 

North  Atlantic  Div 

Petrochemical  Div 

Molded  Fiber  Glass  Body  Co.,    Resin  Div 

Jtona  Industries,    Inc 

Monochem,    Inc 

Monsanto  Co. : 

Bircham  Bend  Plant 

Chocolate  Bayou  Plant 

Gering  Plastics  Dept 

Organic  Chemical  Div 

Plastics  Div 

Textiles  Div 

Western  Div 

Montrose  Chemical  Corp.   of   California 

Mooney  Chemical,    Inc 

Benjamin  Ktoore  &  Co. 

Morton  Chemical  Co 

Motomco,    Inc 

N.V.F.    Co— - _ 

Nalco  Chemical  Co 

National  Biochemical  Co 

National  Casein  Co 

National  Dairy  Products  Corp. : 

Humko  Products  Chemical  Div 

Sheffield  Chemical  Co.  Div 

National  Distillers  &  Chemical  Corp. : 

A-B  Qiemical  Corp.  Div 

National  Petro  Chemical  Corp.  Div 

U.S.  Industrial  Chemicals  Co.  Div 

National  Lead  Co 

National  Milling  &  Chemical  Co.,  Inc 

National  Plastic  Products  Co.,  Inc 

National  Polychemicals,  Inc 

National  Starch  &  Chemical  Corp 

Nease  Chemical  Co.,  Inc 

Nepera  Chemical  Co.,  Inc 

Neville  Chemical  Co 

Newport  Products  Co.,  Div.  of  Safeway  Stores, 

Inc. 
Nilok  Chemicals,  Inc 

Nipak,  Inc 

Nitrin,  Inc — 

A.  P.  Nonweiler  Co 

Nopco  Chemical  Co.,  Inc 

Norac  Co.,  Inc 

Norda  Essential  Oil  &  Chemical  Co.,  Inc 

Norrls  Paint  &   Varnish  Co 

Norse  Chemical  Corp 

North  American  Chemical  Co 

Northwestern  Chemical  Co 

Northwest  Petrochemical  Corp 

Norwich  Riarmaoal  Co 

Nostrip  Chemical  Works,  Inc 

Novamont  Corp 


99  Park  Ave.,  New  York,  NY  10016. 

Warren  and  Morris  Sts.,  Jersey  City,  NJ  07302. 

^01  Park  Ave.,  Dickinson,  TX  77539. 

2501  Hudson  Rd.,  St.  Paul,  MN  55119. 

1101  S.  3d  St.,  Minneapolis,  MN  55415. 

277  Coit  St.,  Irvington,  NJ  07111. 

P.O.  Box  388,  Yazoo  City,  MS  39194. 

Penn  Lincoln  Parkway,  W.  Pittsburgh,  PA  15205. 

401  E.  Main  St.,  Richmond,  VA  23208. 

612  South  Flower  St.,  Los  Angeles,  CA  90054. 

P.O.  Box  3868,  Beaumont,  TX  77704. 

4601  Benefit  Ave.,  Ashtabula,  OH  44004. 

65  E.  23d  St.,  Paterson,  NJ  07524. 

P.O.  Box  488,  Geismar,  LA  70734. 

190  Grochmal  Ave.,  Indian  Orchard,  MA  01051. 

P.O.  Box  711,  Alvin,  TX  77511. 

200  N.  7th  St.,  Kenilworth,  NJ  07033. 

800  N.  Lindbergh  Blvd.,  St.  Louis,  MO  63166. 

730  Worcester  St.,  Springfield,  MA  01101;  5100  W. 
Jefferson  Ave.,  Trenton,  MI  48183;  River  Rd., 
Addyston,  OH  45001,  and  P.O.  Box  1311,  Texas  City, 
TX  77591. 

350  5th  Ave.,  New  York,  NY  10001. 

9229  E.  Marginal  Way  S.,  Seattle,  WA  98108. 

500  S.  Virgil  Ave.,  Los  Angeles,  CA  90005. 

2301  Scranton  Rd.,  Cleveland,  OH  44113. 

548  5th  Ave.,  New  York,  NY  10036. 

110  N.  Wacker  Dr.,  Qiicago,  IL  60606. 

89  Terminal  Ave.,  Clark,  NJ  07066. 

Maryland  Ave.  and  Beech  St.,  Wilmington,  DE  19899. 
180  N.  Michigan  Ave.,  Chicago,  IL  60601. 
3127  W.  Lake  St.,  Chicago,  IL  60612. 
601  W.  80th  St.,  Chicago,  IL  60620. 


99  Park  Ave.,  New  York,  NY  10016. 

99  Park  Ave.,  New  York,  NY  10016. 

99  Park  Ave.,  New  York,  NY  10016. 

Ill  Broadway,  New  York,  NY  10006. 

4601  Flat  Rock  Rd.,  Philadelphia,  PA  19127. 

Odenton,  MD  21113. 

51  Eames  St.,  Wilmington,  MA  01887. 

750  3d  Ave.,  New  York,  NY  10017. 

P.O.  Box  221,  State  College,  PA  16801. 

Route  17  and  Aver ill  Ave.,  Harriman,  NY  10926. 

Neville  Island  P.O.,  Pittsburgh,  PA  15225. 

1501  Mariposa  St.,  San  Francisco,  CA  94107. 

Mill  St.  and  N.  Transit  Rd.,  Lockport,  NY  14094. 

301  S.  Howard  St.,  Dallas,  TX  75221. 

P.O.  Box  233,  Cordova,  IL  61242. 

P.O.  Box  1007,  Oshkosh,  WI  54901. 

60  Park  PI.,  Newark,  NJ  07101. 

405  S.  Motor  Ave.,  Azusa,  CA  91703. 

475  10th  Ave.,  New  York,  NY  10001. 

1675  Commercial  St.,  N.E.,  Salem,  OR  97303. 

2121  Norse  Ave.,  Cudahy,  WI  53110. 

19  S.  Canal  St.,  Lawrence,  MA  01843. 

120  N.  Aurora  St.,  W.  Chicago,  IL  60185. 

P.O.  Box  99,  Anacortes,  WA  98221. 

17  Eaton  Ave.,  Norwich,  NY  13815. 

182  Uberty  Ave.,  Jamaica,  NY  11433. 

P.O.  Box  189,  Kenova,  WV  25530. 


208 


SYNTHETIC  ORGANIC  CHEMICALS,  1966 
■Synthetic  organic  chemicals:  Directory  of  manufacturers ,  2 966 --Continued 


Name  of  con5>any 


Office  address 


Nyanza,  Ino 

Hamilton  Chemical  Div 

Olin  Mathieson  Chenioal  Corp 

Onyx  Oils  &  Resins,  Inc 

Orbis  Products  Corp 

Qrganios,  Ino 

Original  Bradford  Soap  Works,  Inc 

C.  J.  Osbom  Co 

Ottawa  Chemical   Co 

Ott  Chemical  Co 

Owens-Coming  Fiberglas   Corp 

Oxo  Chemicals   Co 

P-L  Biochemioals,    Inc 

Pacific  Kesins  &  Chemical  Co 

Pan  American  Petroleum  Corp 

Pantasote  Co 

Parke,   Davis  &  Co 

saic   Color  &  Chemical  Co 

Patent  Chemicals,    Ino 

Pearsall   Chemical  Co 

Peck's   Products   Co 

Peerless   Chemical   Co 

Pelron  Corp 

S.    B.   Peniok  &  Co 

Parsons-Plymouth  Div 

Pennsalt  Chemicals  Corp 

Pennsylvania  Industrial   Chemical   Corp- 

Pennsylvania  Refining   Co 

Perry  &  Derrick  Co 

Petrochemicals   Co.,    Inc 

Petro-Tex  Chemical   Corp 

Pfanstiehl  Laboratories,    Inc 

Pfister  Chemical  Works 

Chas.    Pfizer  &  Co.,    Ino 

Pharmachem  Corp 

Phelan-Faust  Paint  Manufacturing   Co., 

Phelan's  Resins  &  Flastios  Div. 

Phillips  Petroleum  Co 

Phoenix  Oil   Co 

Pierce  Qrganics,    Inc 

Pillsbury  Co.,    Qiemioal  Div 

Pilot  Chemical   Co 

Pioneer  Chemical  Works,    Ino 

Pioneer  Plastics   Corp.,    Chemical  Div— 

Pitt-Consol   Chemical  Co 

Pittsburgh  Plate  Glass  Co 

Plastics   Bigineering  Co 

Plastics  Manufacturing   Co 

Plumb  Chemical  Corp 

Polak's  Frutal  Works 

Polychemioal  Laboratories,    Ino 

Polymer  Corp 

Polymer  Industries,    Ino 

Poly  Resins 

Polyrez  Co.,    Inc 

Polyvinyl  Chemicals,    Ino 

Pontiac  Refining   Corp 

Pratt  &  Lambert,    Ino 

Premier  Malt  Products,    Inc 

Premier  Petrochemical  Co 

Procter  &  Gamble  Co 

Proctor  Chemical   Co.,    Ino 

Produotol   Chemical  Co.,    Inc 

Products  Research  &  Chemical  Corp 

Publicker  Industries,    Ino 

Puerto  Rico  Chemical   Co.,    Inc 

Purex  Corp.,  Ltd 


P.O.  Box  349,  Ashland,  MA  01721. 
45  Andrews  St.,  Lowell,  MA  01853. 

445  W.  59th  St.,  New  York,  NY  10019. 
95  Broad  St.,  New  York,  NY  10004. 
475  10th  Ave.,  New  York,  NY  10018. 
1724  Greenleaf  Ave.,  Chicago,  IL  60628. 
200  Providence  St.,  W.  Warwick,  HI  02893. 
1301  W.  aianoke  St.,  Linden,  NJ  07036. 
700  N.  Wheeling  St.,  Toledo,  OH  43605. 
500  Agard  Rd.,  Muskegon,  MI  49945. 
P.O.  Box  901,  Toledo,  OH  43614. 
P.O.  Box  127,  Ironton,  OH  45638. 

1037  W.  MoKinley  Ave.,  Milwaukee,  WI  53205. 

3400  13th  Ave.  SW.,  Seattle,  WA  98134. 

P.O.  Box  591,  Tulsa,  OK  74102. 

26  Jefferson  St.,  Passaic,  NJ  07056. 

P.O.  Box  118,  Detroit,  MI  48232. 

28-36  Paterson  St.,  Paterson,  NJ  07501. 

335  McLean  Blvd.,  Paterson,  NJ  07504. 

P.O.  Box  108,  Hiillipsburg,  NJ  08865. 

610  E.  Clarence  Ave.,  St.  Louis,  MO  63147. 

3850  Oakman  Blvd.,  Detroit,  MI  48204. 

7847  W.  47th  St.,  I^rons,  IL  60534. 

100  Church  St.,  New  York,  NY  10008. 

100  Church  St.,  New  York,  NY  10008. 

3  Penn  Center,  Philadelphia,  PA  19102. 

120  State  St.,  Qairton,  PA  15025. 

Union  Bank  Bldg.,  Butler,  PA  16001. 

2510  Highland  Ave.,  Norwood,  OH  45212. 

1825  E.  Spring  St.,  Long  Beach,  CA  90806. 

P.O.  Box  2584,  Houston,  TX  77001. 

1219  CtLen  Rook  Ave.,  Waukegan,  IL  60085. 

P.O.  Box  326,  Ridgefield,  NJ  07657. 

235  E.  42d  St.,  New  York,  NY  10017. 

Broad  and  Wood  Sts.,  Bethlehem,  PA  18018. 

Oak  St.  and  Buff  Hd.,  P.O.  Box  189,  Burlington, 

lA  52602. 
841-A  Adama  Bldg.,  Bartlesville,  OK  74003. 
9505  Caesius  Ave.,  Cleveland,  OH  44105. 
P.O.  Box  98,  Rookford,  IL  61105. 
608  2nd  Ave.  S.,  Minneapolis,  MN  55402. 
11756  Burke  St.,  Santa  Pe  Springs,  CA  90670. 
Route  73,  Maple  Shade,  NJ  08052. 
Pionite  Rd.,  Auburn,  ME  O4210. 
191  Doremus  Ave.,  Newark,  NJ  07105. 
1  Gateway  Center,  Pittsburgh,  PA  15222. 
1607  Geele  Ave.,  Sheboygan,  WI  53082. 
2700  S.  Westmoreland,  Dallas,  TX  75224. 
4837  James  St.,  Philadelphia,  PA  19137. 
33  Sprague  Ave.,  Middletown,  NY  10940. 
490  Hunts  Point  Ave.,  New  York,  NY  10059. 
2120  Fairmont  Ave.,  Reading,  PA  19603. 
Viaduct  Rd.,  Springdale,  CT  06879. 
11655  Wicks  St.,  Sun  Valley,  CA  91352. 
P.O.  Box  320,  Woodbury,  NJ  08096. 
730  Main  St.,  Wilmington,  MA  01887. 
3400  Uwrenoe  Dr.,  Corpus  Christi,  TX  78403. 
75  Tonawanda  St.,  Buffalo,  NY  14207. 
917  W.  Juneau  Ave.,  Milwaukee,  WI  53201. 
P.O.  Box  100,  Pasadena,  TX  77501. 

Ivorydale  Technical  Ctr.,  Rm.  2S25,  Cincinnati,  OH  45217. 
P.O.  Box  399,  Salisbuiy,  NC  28144. 
615  S.  Flower  St.,  Los  Angeles,  CA  90017. 
2919  Bnpire  Ave.,  Burbank,  CA  91504. 
1429  Walnut  St.,  Philadelphia,  PA  19102. 
Rm.  72.2  -  Carr.  No.  2,  Arecibo,  PR  00613. 
5101  dark  Ave.,  Lakewood,  CA  90712,  and  2260  N.  ELston 

Ave.,  Chicago,  IL  60614. 


DIRECTORY  OF  MANUFACTURERS  209 

TABLE  22.  --Synthetic  organic  chemicals :  Directory  of  manufacturers ,  2966- -Continued 


of  company 


Office  addres 


Qiaker  Chemical  Corp 

Qaaier  Oats  Co 

K.  J.  Oalnn  &  Co.,  Ino 

R.S.A.  Corp 

Baohelle  Laboratories,  Ino 

Raybestos-Manhattan,  Inc.,  Raybestos  Div — 

Rayette-Faberge,  Inc 

Red  Spot  Paint  &  Varnish  Co.,  Ino 

Refined  Products  Co 

Reheis  Chemical  Co.,  Div.  of  Armour  Riarma- 

oeutical  Co. 
Reiohhold  Chemicals,  Ino 

Varoum  Chemical  Div 

Reilly  Tar  &  Chemical  Corp 

Reliance  Universal,  Ino 

Remington  Arms  Co.,  Inc 

Renroh  Resins 

Retzloff  Chemical  Co 

Rexall  Chemical  Co 

Fiberfil  Div 

Rezolin,  Ino 

Rhodia,  Ino 

Richardson  Co 

Richardson  Polymers  Div 

Riker  Laboratories,  Div.  of  Rexall  Drug  & 

Chemical  Co. 

F.  Hitter  &  Co 

Ritter  Chemical  Co.,  Inc- 

Ritter  Efaudler  Corp.,  lonao  Chemical  Co.  E 

Riverdale  Chemical  Co 

Roberts  Chemicals,  Ino 

Rook  Hill  Printing  &  Finishing  Co 

Roehr  Chemicals,  Ino 

Rogers  Corp 

Rohm  &   Haas  Co 

Rosenberg  Bros.  &  Co 

Royoe  Chemical  Co 

Rubicon  Chemicals,  Inc 

St.  Regis  Paper  Co.,  Lake  States  Div 

Salsbury  Laboratories 

Sandoz,  Inc 

Sartomer  Resins,    Ino 

Schaefer  Varnish  Co.,    Ino 

Schenectady  Chemicals,    Ino 

Scher  Bros.,    Ino 

R.  P.  Scherer  Corp 

Sobering  Corp 

Scholler  Bros.,  Inc 

Seaboard  Chemicals,  Ino 

G.  D.  Searle  &  Co 

Seidlitz  Paint  &  Varnish  Co 

Sekisul  Plastics  Corp 

Selney  Co.,  Inc 

Seydel-Woolley  &  Co.,    Ino 

Shamrock  Oil  &  Ges   Corp 

Shanoo  Plastics  &  Chemicals,    Inc 

Shell  Oil   Co 

Shell   Chemical  Co.   Div 

aiepherd  Chemical   Co 

Sherwin-Williams   Co 

Shulton,    Inc 

George  F.  Slddall  Co.,  Ino 

Signal  Oil  &  Gas  Co 

Siinpson  Timber  Co 

Slnolair-Kbppers  Chendoal  Co 

Sinolalr-Koppers  Co 


ELm  and  Sandy  Sts.,  Conshohocken,  PA  19428. 
345  Merchandise  Mart  Plaza,  Chicago,  IL  60654. 
195  Canal  St.,  Maiden,  MA  02148. 

690  Saw  Mill  River  Rd.,  Ardsley,  m   10502. 

700  Henry  Ford  Ave.,  Long  Beach,  CA  90810. 

75  E.  Main  St.,  Stratford,  CT  06601. 

261  E.  5th  St.,  St.  Paul,  MN  55101. 

110  Main  St.,  Evansville,  IN  47708. 

624  Schuyler  Ave.,  I^mdhurst,  NJ  07071. 

325  Snyder  Ave.,  Berkeley  Heights,  NJ  07922. 

525  N.  Broadway,  White  Plains,  NY  10602. 

Niagara  Falls,  NY  14302. 

11  S.  Meridan  St.,  Indianapolis,  IN  46204. 

4730  Crittenden  Dr.,  P.O.  Box  21067,  Louisville,  KY 

40221,  and  6901  Cavalcade,  Houston,  TX  77001. 
939  Bamum  Ave.,  Bridgeport,  CT  06602. 
P.O.  Box  1191,  New  Bern,  NO  28560. 
P.O.  Box  45296,  Houston,  TX  77045. 
8480  Beverly  Blvd.,  Los  Angeles,  CA  90048. 
1701  N.  Heidelbaoh  Ave.,  Evansville,  IN  47717. 
1651  18th  St.,  Santa  Monica,  CA  90404. 
600  Madison  Ave.,  New  York,  NY  10022. 
2700  W.  Lake  St.,  Melrose  Park,  IL  60160. 
345  Morgan  Lane,  West  Haven,  CT  06516. 
19901  Nordhoff  St.,  Northridge,  CA  91324. 

4001  Goodwin  Ave.,  Los  Angeles,  CA  90039. 

403  W.  Main  St.,  Amsterdam,  NY  12010. 

Birmingham,  NJ  08011. 

220  E.  17th  St.,  Chicago  Heights,  IL  60411. 

P.O.  Box  546,  Nitro,  WV  25143. 

Rook  Hill,  SC  29730. 

52-20  37th  St.,  Long  Island  City,  NY  11101. 

Rogers,  CT  06263. 

Independence  Mall  West,  Philadelphia,  PA  19105. 

100  Landing  Ave.,  Smithtown,  NY  11787. 
Carlton  Hill  P.O.,  E.  Rutherford,  NJ  07073. 
P.O.  Box  517,  Geismar,  LA  70734. 

603  W.  Davenport  St.,  Rhinelander,  WI  54501. 

500  Gilbert  St.,  Charles  City,  U  50616. 

P.O.  Box  357,  Fair  Lawn,  NJ  07410,  and  Route  10, 

Hanover,  NJ  07936. 
P.O.  Box  56,  Essington,  PA  19029. 
1350  S.  15th  St.,  Louisville,  KY  40210. 
Congress  St.  and  10th  Ave.,  Schenectady,  NY  12301. 
P.O.  Box  538,  Allwood  Station,  Clifton,  NJ  07012. 
9425  Grinnell  Ave.,  Detroit,  MI  48213. 
1011  Morris  Ave.,  Union,  NJ  07083. 

Collins  and  Westmoreland  Sts.,  Philadelphia,  PA  19134. 
30  Foster  St.,  Salem,  MA  01970. 
P.O.  Box  5110,  Chicago,  IL  60680. 
18th  and  Garfield  Sts.,  Kansas  City,  MO  64141. 
666  Dietrich  Ave.,  Hazelton,  PA  18201. 
65  9th  St.,  Brooklyn,  NY  11215. 
748  Rice  St.  NW.,  Atlanta,  GA  30318. 
P.O.  Box  631,  Amarillo,  TX  79105. 
2716  Kenmore  Ave.,  Tonawanda,  NY  14150. 
52  W.  52d  St.,  New  York,  NY  10019. 
113  W.  52d  St.,  New  York,  NY  10019. 
5000  Paplar  St.,  Cincinnati,  OH  45212. 

101  Prospect  Ave.  NW.,  Cleveland,  OH  44101. 
697  Route  46,  Clifton,  NJ  07015. 

P.O.  Box  925,  Spartanburg,  SC  29301. 

P.O.  Box  5008,  Harrisburg  Station,  Houston,  TX  77012. 

2301  N.  Columbia  Blvd.,  Portland,  OR  97217. 

9822  La  Borte  Freeway,  Houston,  TX  77012. 

900  Konners  Bldg.,  Pittsburgh,  PA  15219. 


210  SYNTHETIC  ORGANIC  CHEMICALS,  1966 

TABLE  22.  -Synthetic  organic  chemicals :  Directory  of  manufacturers ,  1966 — Continued 


Sinclair  Paint  Co 

Sinclair  Petroohemcals,    Ino 

Sinclair  Refining   Co 

James   B.    Sipe  &  Co 

Skelly  Oil  Co 

G.   Frederick  Smith   Chemical   Co 

Smith,   Kline  &  French  Laboratories 

Socony  Kkjbil  CtLl  Co.,    Inc.: 

Mobil  Chemical   Co.   Div 

Chemical  Coatings  Div.,    Louisville  Plant 
Sohio  CSiemioal  Co.   &  Solar  Nitrogen  Chemicals, 
Inc. 

Solar  Chemical   Corp 

Soluol  Chemical  Co.,   Inc 

Solvent  Chemical  Co.,    Ino 

Sonford  Chemical  Co 

Sonoco  Products  Co 

Sou-Tex  Chemical  Co.,    Inc 

Southeastern  Mhesives  Co 

Southeast  Polyioers,    Ino 

Southern  Sizing   Co 

Spaulding  Fibre  Co.,    Inc 

E.   R.   Squibb  &  Sons,    Inc 

A.    E.   Staley  Manufacturing   Co 

UBS  Chemical   Co.   Div 

Stamford  Chemical   Co 

Standard  Brands,    Inc.,    Clinton  Com  Processing 
Co.   Div. 

Standard   Chemical  Products,    Inc 

Standard   Chlorine  Chemioal   Co.,    Inc 

Standard  Oil  Co.   of   California,    Chevron 
Chemical   Co. 

Standard   Oil  Co.   of  Ohio 

Standard   jyroxoloid   Corp 

Stange  Co 

Stauf f er  Chemical  Co. : 

Calhio  Chemicals,  Ino.  Div 

Industrial  Chemioal  Div 

Specialty  Chemical  Div 

Stein,  Hall  &  Co.,  Ino 

Stepan  Qiemioal  Co.  : 

Industrial  Chemicals  Div.,  Millsdale  Works—- 

Maywood  Div 

Sterling  Drug,  Inc.: 

Glenbrook  Laboratories  Div 

Hilton-Davis  Chemical  Co.  Div 

Salvo  Chemical  Div 

Thomasset  Colors  Div 

Winthrop  Laboratories  Div 

Stresen-Rfiuter  International,  International 
Minerals  &  Chemioal  Group. 

Sue ro- Chemical  Div.  of  Colonial  Sugars  Co 

Sugar  Beet  Products  Co 

Sullivan  Varnish  Co 

Summit  Chemical  Products  Corp 

Sun  Chemical  Corp 

Chemioal  Products  Div 

Chemical  Products  Div 

Ind\iBtrial  Coatings  Div 

Sun  Chemical  Corp  -  Kearny 

Sunkist  Growers,  Inc 

Sun  Oil  Co 

SunOLln  Chemioal  Co 

Sunray  DX  Oil  Co — 

Suntide  Refining  Co 

Suift  &  Co 

Synthetic.  Chemicals,  Inc 

^mthetio  Products  Co 


3960  E.  Washington  Blvd.,  Los  Angeles,  CA  90023. 

600  5th  Ave.,  New  York,  NY  10020. 

600  5th  Ave.,  New  York,  NY  10020. 

P.O.  Box  13090,  Pittsburgh,  PA  15243. 

Oil  Center  Bldg.,  P.O.  Box  1650,  Tulsa,  OK  74102. 

867  MoKinley  Ave.,  Columbus,  OH  43223. 

1500  Spring  Garden  St.,  Philadelphia,  PA  19101. 

7301  Bessemer  Ave.,  Cleveland,  OH  44127  and  Metuohen, 

NJ  osaio. 

1630  W.  Hill  Street,  Louisville,  KY  40210. 
1434  Midland  Bldg.,  Cleveland,  OH  4^115. 

Fuller  St.,  Leominster,  MA  01453. 

Green  Hill  and  Market  Sts.,  P.O.  Box  112,  W.  Warwick, 
02893. 

341  Commercial  St.,  Maiden,  MA  02148. 
P.O.  Box  127,  Ftort  Neches,  TX  77651. 
Hartsville,  SC  29550. 

E.  Catawba  Ave.,  Mount  Holly,  NC  28120. 

P.O.  Box  791,  Lenoir,  NC  28645. 

P.O.  Box  309,  Chattanooga,  TN  37401. 

P.O.  Box  987,  East  Point,  GA  30aW. 

310  Wheeler  St.,  Tonawanda,  NY  14150. 

745  5th  Ave.,  New  York,  NY  10022. 

22d  and  Eldorado  Sts.,  Lecatur,  IL  62525 

491  Main  St.,  Cambridge,  MA  02U2. 

45  Jefferson  St.,  P.O.  Box  1131,  Stamford,  CT  06940. 

1251  Beaver  Channel  Parkway,  Clinton,  lA  52733. 

1301  Jefferson  St.,  Hoboken,  NJ  07030. 
1025  Belleville  Turnpike,  Kearny,  NJ  07032. 
200  Bush  St.,  San  Francisco,  CA  %120. 

Midland  Bldg.,  Cleveland,  OH  4^115. 
85  Pleasant  St.,  Leominster,  MA  01453. 

342  N.  Western  Ave.,  Chicago,  IL  60612. 

380  Madison  Ave.,  New  York,  NY  10017. 
380  Madison  Ave.,  New  York,  NY  10017. 
380  Madison  Ave.,  New  York,  NY  10017. 
605  3d  Ave.,  New  York,  NY  10016. 

ELwood,  IL  60421. 

100  W.  Hunter  Ave.,  Maywood,  NJ  07607. 

90  Park  Ave.,  New  York,  NY  10018. 

2235  Langdon  Farm  Rd.,  Cincinnati,  OH  45237. 

Military  Rd.,  Rothschild,  WI  54474. 

120  Lister  Ave.,  Newark,  NJ  07105. 

90  Park  Ave.,  New  York,  NY  10016. 

400  W.  Roosevelt  Ave.,  Bensenvllle,  IL  60106. 

P.O.  Drawer  G,  Gramercy,  LA  70052. 

302  Waller  St.,  Saginaw,  MI  48605. 

410  N.  Hart  St.,  Qiioago,  IL  60622. 

11  William  St.,  Belleville,  NJ  07109. 

185  Foundry  St.,  Newark,  NJ  07105. 

441  Tompkins  Ave.,  Staten  Island,  NY  10305. 

Wood  River  Junction,  RI  02894. 

135  W.  Lake  St.,  Northlake,  IL  60164. 

1106  Harrison  Ave.,  Kearny,  NJ  07029. 

720  E.  Sunkist  St.,  Ontario,  CA  91764. 

1608  Walnut  St.,  Riiladelphla,  PA  19103. 

P.O.  Box  F,  Claymont,  DE  19703. 

P.O.  Box  2039,  Tulsa,  OK  74102. 

P.O.  Box  2608,  Corpus  Christi,  TX  78403. 

115  W.  Jackson  Blvd.,  Chicago,  IL  60604. 

335  KfcLean  Blvd.,  Paterson,  NJ  07504. 

1636  Wayside  Rd.,  Cleveland,  OH  44112. 


DIRECTORY  OF  MANUFACTURERS 
TABLE  22.  -Synthetic  organic  chemicals;   Directory  of  manufacturers,  i 566- -Continued 


Name  of  conpany 


SJyiithron,    Ino 

^var  Corp 

Tanatex   Chemical   Corp 

Qiarles  S.   Tanner  Co 

Tenneoo  Chemicals,    Inc 

Berkshire  Color  Div 

Cal/Ink  Div— 

Newport  Div 

New  York  Color  Div 

Nixon-Baldwin  Div 

Nuodex  Div 

Tenneco  Manufacturing  Co.,  Tenneco  Plastics 

Div. 
Tenneco  Oil  Co.,  Refining  &  Marketing 
Accounting. 

Tennessee  Copper  Co 

Texaco,  Ino 

Texas  Alkyls,    Ino 

Texas-U.S.    Chemical  Co 

Tex  Ghem  Co 

Texize  Chemicals,    Ino 

Textilana  Corp 

Textilana-Nease,    Ino 

Thiokol   Chemical  Corp 

Thomason   Industries,    Inc.,    Southern  Resin  Div. 
Thoii5)son  Apex   Co.,   Div.   of   Continental  Oil   Co. 

Thonfison  Chemical   Corp 

Thompson-Hayward   Chemical   Co 

Ticonderoga  Chemical   Corp 

Tidewater  Oil   Co 

Tizon  Chemical  Corp 

Toms  River  Chemical  Corp 

Arthur  C.   Trask  Co 

Triangle  Chemical  Co 

Trojan  Powder  Co 

Troy   Chemical  Co 

Trylon  Chemical   Corp 

Joseph  Turner  &  Co 

USS  Qiemicals  Div.   of  U.S.   Steel   Corp 

Paul  Uhlioh  &   Co.,    Ino 

Ifagerer  &  Co 

Union-Camp   Corp.,    Chemical  Div 

Union  Carbide  Corp. : 

Chemicals  Div 

Plastics  Div 

Silicones  Div 

Union  Oil  Co.   of   California 

Union  Starch  &  Refining  Co.,    Ino 

Uniroyal,    Inc.,    Uhiroyal   Chemical  Div 

United   Carbon  Co 

United   Chemical   Corp.   of  Norwood 

United   Chemical   Products   Corp- 

United  Merchants  &  Mfgrs.,    Inc.,   Roma 
Chemioal  Div. 

United  Oil  Manufacturing   Co 

U.S.    Borax  Research  Corp 

U.S.    Oil   Co 

U.S.    Peroxygen  Corp- 

United  States   Pipe  &  Foundry  Co 

United  States   Plywood   Corp.,    California  Div., 
Shasta  Operations. 

Universal  Chemicals  Corp 

Universal  Oil  Products   Co 

lemical  Div 

Upjohn  Co 

Carwin  Organic   Chemicals 

Utah  Resin  Co.,    Ino 


Office  address 


Ryan  Ave.,   Ashton,   RI  02805. 

917  Washington  St.,   Wilmington,   DE  19899. 

P.O.    Box  388,    lyndhurst,    NJ  07071. 

P.O.    Box  3867,    Park  Place,   Greensville,   SC  29608. 

300   E.   42d  St.,    New  York,    NY  10017. 

12th  and  Bern  Sts.,    Reading,    PA  19604. 

711   Camella  St.,    Berkeley,    CA  94710. 

P.O.   Box  911,   Pensacola,   FL  32502. 

374  Main  St.,    Belleville,    NJ  07109. 

Nixon,    NJ  08818. 

P.O.    Box  2,    Plscataway,    NJ  08854. 

P.O.    Box  2,    Plscataway,    NJ  08854. 


P.O. 


2511,  Houston,  TX  77001. 


Copperhill,  TN  37317. 

1111  Rush  Ave.,  Houston,  TX  77052. 

P.O.  Box  600,  Deer  Park,  TX  77536. 

P.O.  Box  667,  Port  Neches,  TX  77651. 

20-21  Wagaraw  Rd.,  Fair  Lawn,  NJ  07410. 

P.O.  Box  368,  Greenville,  SC  29602. 

12607  Cerise  Ave.,  Hawthorne,  CA  90250. 

1240  S.  88th  St.,  Klwardsville,  KS  66022. 

P.O.  Box  27,  Bristol,  PA  19007. 

P.O.  Drawer  1600,  Fayetteville,  NC  28301. 

505  Central  Ave.,  Pawtucket,  RI  02862. 

3028  Locust  St.,  St.  Louis,  MO  63103. 

5200  Speaker  Rd.,  Kansas  City,  KS  66110. 

Marguerite  Ave.,  Leominster,  MA  01453. 

Delaware  City,  DE  19706. 

Looktown  Rd.,  Flemlngton,  NJ  08822. 

P.O.  Box  71,  Tbms  River,  NJ  08753. 

327  S.  LaSalle  St.,  Qilcago,  IL  60604. 

206  Lower  Elm  St.,  P.O.  Box  4528,  Macon,  GA  312 

17  N.  7th  St.,  Allentown,  PA  18105. 

338  Wilson  Ave.,  Newark,  NJ  07105. 

P.O.  Box  5101,  Station  B,  Greenville,  SC  29606. 

Pleasant  View  Terrace,  Ridgefield,  NJ  07451. 

Grant  Bldg.,  Pittsburgh,  PA  15219. 

90  West  St.,  New  York,  NY  10006. 

161  Avenue  of  the  Americas,  New  York,  NY  10013. 

P.O.  Box  6170,  Jacksonville,  FL  32205. 

270  Park  Ave.,  New  York,  NY  10017. 

270  Park  Ave.,  New  York,  NY  10017. 

270  Park  Ave.,  New  York,  NY  10017. 

461  S.  Boylston  St.,  Los  Angeles,  CA  90017. 

301  Washington  St.,  Columbus,  IN  47201. 

Naugatuck,  CT  06771. 

P.O.  Box  149,  Baytown,  TX  77520. 

P.O.  Box  327,  Endicott  St.,  Norwood,  MA  02062. 

York  and  Colgate  Sts.,  Jersey  City,  NJ  07302. 

749  Quequeohan  St.,  F^n  River,  MA  02721. 

2d  and  Cascade  Sts.,  Erie,  PA  16512. 
3075  Wilshlre  Blvd.,  Los  Angeles,  CA  90005. 
P.O.  Box  4228,  E.  Providence,  RI  02914. 
850  Morton  Ave.,  Richmond,  CA  94804. 
3300  1st  Ave.  N.,  Birmingham,  AL  35202. 
P.O.  Box  2317,  Redding,  CA  96001. 

P.O.  Box  1224,  Ashton,  RI  02865. 
30  Algonquin  Rd.,  Des  Plalnes,  IL  60018. 
State  Highway  17,  E.  Rutherford,  NJ  07073. 
7000  Portage  Rd.,  Kalamazoo,  MI  49001. 
Sackett  Point  Rd.,  North  Haven,  CT  0&;73. 
604-605  Keams  Bldg.,  Salt  Lake  City,  UT  84101. 


212  SYNTHETIC  ORGANIC  CHEMICALS,  1966 

TABLE  22.  -Synthetic  organic  chemicals :   Directory  of  manufacturers ,  1966 — Continued 


Name  of  coirpany 


Office  address 


Valchem 

Valentine  Sugars,  Inc.,  Valite  Div 

Valley  Nitrogen  Producers,  Ino 

Van  De  Mark  Chemical  Co 

Vanderbilt  Chemical  Corp 

Van  Eyk  &  Co.,  Inc 

Varney  Chemical   Corp 

Veliscol  'Chemical  Corp 

Industrial   Chemicals  Div 

Ventron  Corp.,   Metal  Hydrides  mv 

Vermi lye-Bell 

Verona-Pharma  Chemical  Corp 

Vickers  Refining   Co.,    Inc 

Vineland  Chemical   Co 

Virginia  Chemicals,    Inc 

Vistron  Corp.,    Silmar  Div 

Vitra-Var  Corp.,   Div.   of  Textron  Industries, 

Inc. 
Vulcan  Materials   Co.,    Chemical  Div. 

Wallace  &  Herman,    Inc.: 

Harchem  Div 

Lucidol  Div 

Wamer-Jenkinson  Manufacturing   Co 

Warner  Machine  Products,    Inc.,   Warner 
Chemical  Div. 

Washine  Chemical  Corp 

West  Coast  Mhesives  Co 

Westinghouse  Electric   Corp.,    Insulating 
Materials  Div.    -   Benollte. 

Weston  Chemical   Corp 

West  Virginia  Pulp  &  Paper  Co.,    BdIj- 
chemicals  Div. 

Weyerhaeuser  Co.,   Wood  Products  Div 

White  &  Bagley  Co 

White  &  Hodges,    Inc 

White  Laboratories,    Inc 

Whitmoyer  Laboratories,    Inc 

Whittaker  Corp.,    Narmco  Research  &  Develop- 
ment Div. 

Whittemore-Wright  Co.,    Inc 

Wioa  Chemicals,    Inc 

Wilmot  &  Cassidy,    Inc 

Wilson  &  Co.,    Inc. : 

Wilson  Laboratories  Div 

Wilson-Martin  Div 

Witeo  Chemical   Co.,    Inc 

Sonneborn  Div 

Witfield   Chemical   Corp 

Wobum  Chemical  Corp 

W.   A.   Wood   Co 

Wood  Ridge  Chemical  Corp 

Woonsocket  Color  &  Chemical  Co 

Worthington  Biochemical  Corp 

Wyandotte  Chemicals  Corp 

^con 

Young  Jtaillne  Works,  Inc 


1407  Broadway,  New  York,  NY  10018. 

726  Whitney  Bldg.,  New  Orleans,  LA  70130. 

P.O.  Box  128,  Helm,  CA  93627. 

N.  Transit  Rd.,  Lockport,  NY  U09ii. 

33  Winfield  St.,  E.  Norwalk,  CT  06855. 

11  William  St.,  Belleville,  NJ  07109. 

2001  Afton  Ed.,  Janesville,  WI  53545. 

341  E.  Ohio  St.,  Chicago,  IL  60611. 

4902  Central  Ave. ,  Chattanooga,  TN  37410. 

12-24  Congress  St.,  Beverly,  MA  01915. 

21707  Bothell  Way,  Bothell,  WA  98011. 

P.O.  Box  385,  Springfield  Rd.,  Union,  NJ  07083. 

P.O.  Box  2240,  Wichita,  KS  67201- 

W.  Wheat  Rd.,  Vineland,  NJ  08360. 

West  Norfolk,  VA  23703. 

12335  S.  Van  Ness  Ave.,  Hawthorne,  .A  9C250. 

177  Oakwood  Ave.,  Grange,  NJ  07050. 

P.O.  Box  545,  Wichita,  KS  67201. 


25  Main  St.,  Belleville,  NJ  07109. 
1740  Military  Rd.,  Buffalo,  NY  14240. 
2526  Baldwin  St.,  St.  Louis,  MO  63106. 
1200  Rochester  Ave.,  Ifcmcie,  IN  47302. 

165  Main  St.,  Lodl,  NJ  07644. 

11104  NW.  Front  Ave.,  Portland,  OR  97231. 

Manor,  PA  15665. 

104  E.  40th  St.,  New  York,  NY  10016. 
P.O.  Box  5207,  N.  Charleston,  SC  29406. 

118  S.  Palmetto  St.,  Marshfield,  WI  54449. 
P.O.  Box  1171,  Worcester,  MA  01601. 
576  Lawrence  St.,  Lowell,  MA  01852. 
Galloping  Hill  Rd.,  Kenilworth,  NJ  07033. 
19  N.  Railroad  St.,  Myerstown,  PA  17067. 
3540  Aero  Ct.,  San  Diego,  CA  92123. 

62  Alford  St.,  Boston,  MA  02129. 
P.O.  Box  506,  Charlotte,  NC  28201. 
108  Provost  St.,  Brooklyn,  NY  11222. 

4221  S.  Western  Blvd.,  Chicago,  IL  60609. 

Jackson  and  Swanson  Sts.,  Philadelphia,  PA  191A8. 

P.O.  Box  305,  Paramus,  NJ  07652. 

277  Park  Ave.,  New  York,  NY  lOU^  '. 

P.O.  Box  1243,  Wilmington,  CA  90744. 

1200  Harrison  Ave.,  Harrison,  NJ  07029. 

108  Spring  St.,  Everett,  MA  02149. 

Park  PI.  E.,  Wood  Ridge,  NJ  07075. 

176  Sunnyside  Ave.,  Woonsocket,  RI  02895. 

Route  9,  Freehold,  NJ  07728. 

1609  Biddle  Ave.,  Wyandotte,  MI  48192. 

P.O.  Box  1087,  Colorado  Springs,  CO  80901. 

2731  Boston  St.,  Baltimore,  MD  21224. 


APPENDIX 

U.S.  Imports  of  Benzenoid  Intermediates 
and  Finished  Benzenoid  Products 

Table  23  summarizes,    for   1965  and  1966,    U.S.    imports  of  benzenoid  chemicals  and  products 
entered  under  the  Tariff  Schedules  of  the  United  States  (TSUS),    schedule  4,    part  1,    subparts  B 
and  C.    The  data,    which  were  obtained  by  analyzing  invoices  covering  imports  through  U.S. 
customs  districts,    are  given  in  detail  in  a  separate  report  of  the  Tariff  Commission. ■■• 

In  1966,    general  imports  of  benzenoid  intermediates  entered  under  schedule  4,    part  IB,    com- 
prised 665  items  with  a  total  weight  of  68.  9  million  pounds  and  an  invoice  value  of  $31.2  million. 
In  1965,    imports  consisted  of  642  items  with  a  total  weight  of  38,  0  million  pounds  and  an  invoice 
value  of  $19.  5  million.   About  half  of  the  benzenoid  chemicals  and  products  imported  in  1966  were 
declared  to  be  "competitive"  (duty  based  on  "American  selling  price").   In  1966,    imports  of  these 
products  from  Canada  amounted  to  23  percent  of  the  total;  imports  from  that  country  amounted 
to  15.6  million  pounds,    compared  with  13  million  pounds  in  1965.   In  1966,    imports  from  Italy 
amounted  to  5.8  million  pounds,    compared  with  8.  I  million  pounds  in  1965.   Imports  from  West 
Germany  amounted  to  14.  5  million  pounds,    compared  with  7.  2  million  pounds  in  1965.   Imports 
from  Japan  totaled  14.4  million  pounds  in  1966,    compared  with  3.  3  million  pounds  in  1965;  and 
imports  from  the  United  Kingdom  amounted  to  8.  1  million  pounds,    compared  to  2.  2  million 
pounds  in    1965.    Sizable    quantities  of  intermediates  were  also  imported  in  1966  from  Switzer- 
land (2.  0  million  pounds),    France  (3.  5  million  pounds),    and  Sweden  (0.  9  million  pounds). 

The  most  important  intermediates  imported  in  1966  were  phenol,    styrene,    adipic  acid, 
alkylbenzene,    phthalic  anhydride,    Bisphenol  A,    poly  alky  Ibenzene,   ethylbenzene  and  3-hydroxy- 


TABLE  23. 


■  Benzenoid  intermediates  and  finished  benzenoid  products .-  U.S.  general  imports, 
classified  by  use,  1965  and  1966 


Intermediates 

Finished  benzenoid  products,  total 

Dyes,  total 

Acid 

Azoic  dyes 

Azoic  components: 

Fast  color  bases 

Fast  color  salts 

Naphthol  AS  and  its  derivatlves-- 

Basic 

Direct 

Disperse 

Fiber-reactive 

Fluorescent  brightening  agents 

Mordant 

Solvent 

Sulfur 

Vat 

All  other 

Benzenoid  pigments  (toners  and  lakes) 

Medicinals  and  pharmaceuticals 

Flavor  and  perfume  materials 

All  other 


1,000 
pounds 
37,975 


12, 276 

22 

416 
185 

1,093 

1,227 
931 

1,880 
652 
229 
221 
168 
37 

3,374 
233 

797 

3,408 

1,908 

'13,552 


13,715 
2,555 


520 

269 

1,558 

1,136 

1,159 

2,494 

1,249 

247 

362 

265 

45 

1,761 

^81 

1,010 

4,674 

2,564 

'25,912 


1,000 
dollars 

31,217 


1,738 
10,855 

4,033 
U,416 


Includes   small  quantities  of  rubber-processing  chemicals . 
^  Includes   ingrain  dyes. 
^  Includes  organic  pesticides  and  related  products,   plaaticlzers,   surface  active  agents,   and  textile  assistant. 

Source:      Conplled  from  the  records  of  the  U.S.    Bureau  of   Customs. 


als  and  Products,  1966,    TC  Publication  216,   1967  [processed]. 


213 


214  SYNTHETIC  ORGANIC  CHEMICALS,  1966 

2-naphthoic  acid  (B.O.N.  ).   In  1966,    imports  of  phenol  amounted  to  8.6  million  pounds  and 
came  from  the  United  Kingdom,    France  and  West  Germany.    Imports  of  styrene  amounted  to 
8.  5  million  pounds  and  all  came  from  Canada.   Imports  of  adipic  acid  in  1966    totaled  5.  3  million 
pounds,   compared  with  13.7  million  pounds  in  1965  and  all  came  from  Canada.   Imports  of 
alkylbenzene  in  1966  amounted  to  5.  1  million  pounds  and  imports  of  phthalic  anhydride  announted 
to  4.6  million  pounds.   All  of  the  alkylbenzene  and  most  of  the  phthalic  anhydride  came  from 
Japan.   In  1966,    imports  of  4,  4' -Isopropylidenediphenol  (Bisphenol  A),   which  came  principally 
from  the  Netherlands  and  France,    totaled  4.2  million  pounds;  imports  of  polyalkylbenzene,   which 
came  from  Italy,    totaled  3.7  million  pounds;  imports  of  ethylbenzene,   which  came  from  Canada, 
totaled  1.  2  million  pounds;  and  imports  of  B.O.N.  ,   which  came  from  West  Germany,   Italy  and 
Japan,    totaled  917,  000  pounds. 

Imports  in  1966  of  all  finished  benzenoid  chemicals  and  products  that  are  dutiable  under 
part  IC  comprised  2,  401  items,   with  a  total  weight  of  47.  9  million  pounds  and  an  invoice  value 
of  $56.  9  million.   In  1965,    imports  consisted  of  2,  223  items,   with  a  total  weight  of  31.9  million 
pounds  and  an  invoice  value  of  $45.4  million.    The  most  important  group  of  finished  benzenoid 
products  imported  in  1966  was  benzenoid  dyes.   Imports  of  dyes  amounted  to  $25.8  million 
(invoice  value),    or  45.4  percent  of  the  value  of  all  imports  under  part  IC.   In  1965,    imports  of 
dyes  amounted  to  $20.  5  million  (invoice  value),    or  45.  1  percent  of  the  value  of  all  imports  under 
part  IC. 

Imports  of  medicinals  and  pharmaceuticals,    the  next  most  important  group  of  products 
entered  vmder  part  IC  in  1966,    decreased  in  1966,    compared  with  1965.   In  1966,    imports  of 
medicinals  and  pharmaceuticals  were  valued  at  $10.9  million  (invoice  value),    or  19.  1  percent 
of  the  total  value  of  imports  under  part  IC.   In  1965,    imports  of  medicinals  and  pharmaceuticals 
were  valued  at  $12.6  million  or  27.6  percent  of  total  value  of  imports  under  part  IC.   In  1966, 
imports  of  benzenoid  pigments  were  valued  at  $1.  7  million,    compared  with  $1.  5  million  in  1965. 
Imports  of  benzenoid  flavor  and  perfume  materials  in  1966  ($4.0  million)  were  60  percent  more 
than  in  1965  ($2.  5  million).    Imports  of  other  benzenoid  products  in  1966,    entered  under  part  IC 
(chiefly  polyamide  resins  and  pesticides)  were  valued  at  $14.4  million,    compared  with  $8.  3 
million  in  1965. 


O  -  307-771 


REPORTS  OF  THE  UNITED  STATES  TARIFF  COMIVIISSION  ON  THE  OPERATION  OF  THE 
TRADE  AGREEMENTS  PROGRAM 

*Operation  of  the  Trade  Agreements  Program,  June  1934  to  April  1948  (Rept.  No.  160,  2d  ser.,  1949): 
Part  I.       Summary 

Part  II.     History  of  the  Trade  Agreements  Program 
Part  HI.  Trade-Agreement  Concessions  Granted  by  the  United  States 
Part  IV.    Trade- Agreement  Concessions  Obtained  by  the  United  States 
Part  V.      Effects  of  the  Trade  Agreements  Program  on  United  States  Trade 

♦Operation  of  the  Trade  Agreements  Program:  Second  Report,  April  1948- March  1949  (Rept.  No. 

163,  2d  ser.,  1950) 

♦Operation  of  the  Trade  Agreements  Program:  Third  Report,  April  1949- June  1950  (Rept.  No.  172, 

2d  ser.,  1951) 
♦Operation  of  the  Trade  Agreements  Program:  Fourth  Report,  July  1950- June  1951  (Rept.  No.  174, 

2d  ser.,  1952) 
♦Operation  of  the  Trade  Agreements  Program:  Fifth  Report,  July  1951-June  1952  (Rept.  No.  191, 

2d  ser.,  1954) 
♦Operation  of  the  Trade  Agreements  Program :  Sixth  Report,  July  1952- June  1953  (Rept.  No.  193, 

2d  ser.,  1954) 
♦Operation  of  the  Trade  Agreements  Program :  Seventh  Report,  July  1953-June  1954  (Rept.  No.  195, 

2d  ser.,  1955) 
♦Operation  of  the  Trade  Agreements  Program:  Eighth  Report,  July  1954-June  1955  (Rept.  No.  197, 

2d  ser.,  1956) 
♦Operation  of  the  Trade  Agreements  Program:  Ninth  Report,  July  1955-June  1956  (Rept.  No.  199, 

2d  ser.,  1957) 
♦Operation  of  the  Trade  Agreements  Program :  10th  Report,  July  1956-June  1957  (Rept.  No.  202, 

2d  ser.,  1959) 
♦Operation  of  the  Trade  Agreements  Program:  11th  Report,  July  1957- June  1958  (Rept.  No.  204, 

2d  ser.,  1959) 
♦Operation  of  the  Trade  Agreements  Program :  12th  Report,  July  1958-June  1959  (TC  Publication 

9,  1961) 
♦Operation  of  the  Trade  Agreements  Program:  13th  Report,  July  1959- June  1960  (TC  Publication 

51,  1962) 
Operation  of  the  Trade  Agreements  Program:  14th  Report,  July  1960- June  1962  (TC  Publication 

120,  1964),  350 
♦Operation  of  the  Trade  Agreements  Program:  15th  Report,  July  1962-June  1963  (TC  Publication 

147,  1965) 
Operation  of  the  Trade  Agreements  Program:  16th  Report,  July  1963-June  1964  (TC  Publication 

164,  1966),  300 

Operation  of  the  Trade  Agreements  Program:  17th  Report,  July  1964-December  1965  (TC  Pub- 
lication 192),  350 

NOTE. — The  reports  preceded  by  an  asterisk  (*)  are  out  of  print.  Those  followed  by  u  price  n«ay  be  purchased  from 
the  Superintendent  of  Documents,  U.S.  Government  Printing  Office,  Washington,  U.C.  20402.  See  inside  front 
cover  for  additional  reports.  All  U.S.  Tariff  Commission  reports  reproduced  by  the  Government  Printing  Office 
may  be  consulted  in  the  official  depository  libraries  throughout  the  United  States.