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Full text of "Synthetic organic chemicals"

BOSTON 

PUBLIC 

LffiRARY 




2>i : 

?^ UNITED STATES TARIFF COMMISSION 

SYNTHETIC 
ORGANIC CHEMICALS 



United States Production 
and Sales, 1966 

TC Publication 248 




Fiftieth Annual Edition 



RECENT REPORTS OF THE UNITED STATES TARIFF COMMISSION ON 
SYNTHETIC ORGANIC CHEMICALS 



Synthetic Organic Chemicals, United States Production and Sales, 1961 (TC Publication 72, 1962), 

$1.25 
Synthetic Organic Chemicals, United States Production and Sales, 1962 (TC Publication 114, 

1963), $1.50 
Synthetic Organic Chemicals, United States Production and Sales, 1963 (TC Publication 143, 

1964), $1.50 
Synthetic Organic Chemicals, United States Production and Sales, 1964 (TC Publication 167, 

1965), $1.25 
Synthetic Organic Chemicals, United States Production and Sales, 1965 (TC Publication 206), 

$1.00 



NOTE.— The reports listed above may be purchased from the Superintendent of Documents, U.S. Government 
Printing Oflice, Washington, D.C. 20402. See inside back cover for additional reports. All U.S. Tariff Commission 
reports reproduced by the Government Printing Office may be consulted in the official depository libraries through- 
out the United States. 



UNITED STATES TARIFF COMMISSION 



SYNTHETIC 
ORGANIC CHEMICALS 

United States Production 
and Sales, 1966 



UNDER THE PROVISIONS OF 
SECTION 332 OF THE TARIFF 
ACT OF 1930, AS AMENDED 



U.S. GOVERNMENT PRINTING OFFICE 
WASHINGTON : 1968 



TC PubUcation 248 



UNITED STATES TARIFF COMMISSION 

Stanley S. Metzger, Chairman 
Glenn W. Sutton, Vice Chairman 
James W. Culliton 
Penelope H. Thunberg 
Bruce E. Clubb 

DoNN N. Bent, Secretary 



Address all communications 

UNITED STATES TARIFF COMMISSION 

Washington, D.C. 20436 



For sale by the Superintendent of Documents, U.S. Government Printing Office 
Washington, D.C. 20402 - Price $1.50 



CONTENTS 

Page 

Intr oduc tion v 

Summary vii 

PART I. PRODUCTION AND SALES OF TARS, TAR CRUDES, AND CRUDES 
DERIVED FROM PETROLEUM AND NATURAL GAS 

Tars -.- 1 

Tar crudes 1 

Crude products from petroleum and natural gas for chemical conversion 4 

PART II. PRODUCTION AND SALES OF INTERMEDIATES AND FINISHED 
SYNTHETIC ORGANIC CHEMICALS, BY GROUPS 

General 7 

Cyclic intermediates 10 

Dyes 15 

Pigments 26 

Medicinal chemicals 31 

Flavor and perfume materials 36 

Plastics and resin materials 38 

Rubber -processing chemicals 42 

Elastomers (synthetic rubbers) 44 

Plasticizers 45 

Surface-active agents 47 

Pesticides and related products 53 

Miscellaneous chemicals 55 

PART III. ALPHABETICAL LIST OF INDIVIDUAL PRODUCTS, BY GROUPS, 
AND NAMES OF MANUFACTURERS 

Tar crudes 63 

Crude products from petroletun and natural gas for chemical conversion 64 

Cyclic intermediates 66 

Dyes - - -- - 92 

Pigments 113 

Medicinal chemicals 117 

Flavor and perfume materials 130 

Plastics and resin materials 136 

Rubber -processing chemicals 140 

Elastomers (synthetic rubbers) 143 

Plasticizers 144 

Surface -active agents 147 

Pesticides and related products 162 

Miscellaneous chemicals 168 

Directory of manufacturers 193 

APPENDIX 

U.S. imports of benzenoid intermediates and finished benzenoid products 213 



Introduction 

This is the fiftieth annual report of the U.S. Tariff Commission on domestic production and 
sales of synthetic organic chemicals and the raw materials from which they are made. The 
report presents statistics for 1966 on crude organic chemicals derived from coal, natural gas, 
and petroleum; on intermediates; and on finished synthetic organic chemical products. The 
finished products are grouped according to their principal use--dyes, synthetic organic pigments, 
medicinal chemicals, flavor and perfume materials, plastics and resin materials, rubber-proc- 
essing chemicals , elastomers, plasticizers , surface-active agents, pesticides and related 
products, and miscellaneous chemicals. The use classifications of finished synthetic organic 
chemicals are based principally on the manufacturers' annual reports to the Tariff Commis- 
sion; other sources include trade associations, the chemical literature, chemical dictionaries, 
encyclopedias, and consultants in the chemical industry. With a few exceptions, the report 
does not cover organic chemicals (such as wood -distillation products, essential oils, and naval 
stores) that are derived from natural (vegetable) sources by simple extraction or distillation. 
The Commission has compiled the statistics given in this report from information supplied 
by approximately 825 primary manufacturers, listed in part III. 

The first section of the report includes the statistics on all products and groups of products 
for which information can be published. The second section lists all the chemicals and chemical 
products on which data are reported and identifies the manufacturers of each. Each reporting 
company has been assigned an identification symbol consisting of a combination of not more than 
three capital letters, selected in most instances with the approval of the manufacturer, and 
usually bearing some relationship to the company name. The identification symbols are perma- 
nent and, except for such changes as may be necessary, will be used in all future reports in 
this series. This report includes data on only those individual chemicals for which the volume 
of production or sales in the year covered exceeded 1,000 pounds or for which the value of sales 
exceeded $1, 000. 

The raw materials referred to in this report are obtained from coal, crude petroleum, 
natural gas, and certain other natural materials, such as vegetable oils, fats, rosin, and grains. 
Crude organic chemicals are derived from coal by thermal decomposition, from petroleum and 
natural gas by catalytic cracking and by distillation or absorption, and from other natural 
sources by fermentation. Production of these crude organic chemicals is the first step in the 
manufacture of synthetic organic chemicals. From these crudes, intermediates are obtained by 
synthesis or refining; most of the intermediates are then converted into finished chemical prod- 
ucts, such as medicinal chemicals, plastics and resin materials, and dyes. More than half of 
the total production of intermediates is not sold directly to the ultimate consunner, but is used 
by the producing companies themselves in their manufacturing processes. The statistics given 
in this report include data for all known domestic producers of the items covered. 

In this report the statistics on production of the individual chemicals reported by manufac- 
turers include the total output of the companies' plants, i. e. , the quantities produced for con- 
sumption within the producing plants, as well as the quantities produced for domestic and foreign 
sale. The quantities reported as produced, therefore, generally exceed the quantities rep>orted 
as sold. Some of these differences, however, are attributable to changes in inventories. As 
specified in the reporting instructions that the Commission sends to manufacturers, and as used 
in this report, production and sales (unless otherwise specifically indicated) are defined as 
follows : 

Production is the total quantity of a commodity made available by original manufacture only. It 
is the sum (expressed in terms of 100-percent active ingredient unless otherwise specified) of 
the quantities of a commodity- - 

(1) Produced, separated, and consumed in the same plant or establishment (a commodity 

is considered to be separated when it is isolated from the reaction system and/or 
when it is weighed, analyzed, or otherwise measured). Byproducts and coproducts 
not classified as waste materials are also included; 

(2) Produced and transferred to other plants or establishments of the same firm; 

(3) Produced and sold to other firms (including production for others under toll agree- 

ments ); and 

(4) Produced and held in stock. 



A toll agreement is an agreement between two firms, under which one firm furnishes the raw materials and pays the processing costs 
and the other firm prepares the finished product and returns it to the first firm. 



VI INTRODUCTION 

Production excludes-- 

(1) Purification of a commodity unless specifically requested in the reporting instructions; 

(2) Intermediate products that are formed in the manufacturing process but are not isolated 

from the reaction system- -that is, not weighed, analyzed, or otherwise measured; 
and 

(3) Materials that are used in the process but are recovered for reuse or sale; and waste 

products that have no economic significance. 

Sales are defined as actual sales of commodities by original manufacturers only. Sales include-- 

(1) Shipments of commodities for domestic use and for export, or segregation in a ware- 

house when title has passed to the purchaser in a bonafide sale; 

(2) Shipments of a commodity produced by others under toll agreements; and 

(3) Shipments to subsidiary or affiliated companies. 

Sales exclude-- 

(1) All intracompany transfers within a corporate entity; 

(2) All sales of purchased commodities; and 

(3) All shipments of a commodity produced for others under toll agreements. 

The value of a sale is the net selling price, f. o. b. plant or warehouse, or delivered value, 
whichever represents the normal industry practice. 

Data on the chemicals covered inthis report are usually given in terms of undiluted mate- 
rials. Products of 95 percent or more purity are considered to be 100 percent pure. The prin- 
cipal exceptions are the statistics on dyes and a few solvents, which are reported in terms of 
commercial concentrations, and the statistics on certain plastics and resins, which are reported 
on a dry basis. The report specifically notes those products for which the statistics are reported 
in terms of commercial concentrations. 

The average unit values of sales for groups of products shown in the tables accompanying 
this report are the averages for products which vary widely in unit values and in the quantities 
sold. 

In this report, statistics are presented in as great detail as is possible without revealing the 
operations of individual producers. Statistics for an individual chemical or group of chemicals 
are not given unless there are three or more producers no one or two of which may be predomi- 
nant. Moreover, even when there are three or more producers, statistics are not given if there 
is any possibility that their publication would violate the statutory provisions relating to unlawful 
disclosure of information accepted in confidence by the Commission. ^ 

Statistics on tars and tar crudes include data furnished directly to the Tariff Commission by 
distillers of coal tar, water-gas tar, and oil-gas tar, and data furnished to the Division of Bitu- 
minous Coal, U.S. Bureau of Mines , by coke-oven operators. 

Statistics on U.S. general imports in 1966 of benzenoid intermediates and finished benzenoid 
products that entered under schedule 4, parts IB and IC, of the Tariff Schedules of the 
United States are given in the appendix. 

Information on synonymous names of organic chemicals included in this report may be found 
in the SOCMA Handbook: Commercial Organic Chemical Names, recently published by the Chemical Abstracts 
Service of the American Chemical Society, or the Colour Index (2d edition), published in 1956 by the 
Society of Dyers and Colourists. 



Sec. 5, U.S.C. 139b and sec. 18, U.S.C, 1905. 



Summary 

Combined production of all synthetic organic chemicals, tars, tar crudes, and crude products 
from petroleum and natural gas in 1966 was 169, 174 million pounds--an increase of 11.6 percent 
over the output in 1965 (see table 1). Sales of these materials in 1966, which totaled 90, 175 mil- 
lion pounds, valued at $10,999 million, were 12.4 percent larger than in 1965 in terms of quan- 
tity and 11.1 percent larger in terms of value. These figures include data on production and sales 
of chemicals measured at several successive steps in the manufacturing process, and therefore 
they necessarily contain some duplication. 

In 1966, production of all synthetic organic chemicals, including cyclic intermediates and 
finished chemical products, totaled 100,627 million pounds, or 13.2 percent more than the output 
in 1965 (see table 1). Production of plastics and resin materials (13, 585 million pounds) was 16. 3 
percent larger in 1966 than in 1965; that of medicinal chemicals (185 million pounds) was 16. 3 
percent larger; that of pesticides and related products (1,013 million pounds) was 15. 5 percent 
larger; that of cyclic intermediates (19,467 million pounds) was 15.4 percent larger; and that of 
miscellaneous organic chemicals (57,253 million pounds) was 12. 6 percent larger. 

The output of most other groups of synthetic organic chemicals also increased in 1966 com- 
pared with 1965, with rubber-processing chemicals and plasticizer chemicals showing increases 
of more than 12 percent. Production of surface-active agents (3,321 million pounds) showed the 
smallest percentage gain in 1966 over 1965 (4. 8 percent). 

1ABJ-.1!; 1. — ^ymnettc organic chemicals and their raw materials : U.S. production and sales, 1965 and 1966 



decrease 

(-), 1966 
over 
1965^ 



decrease 
(-), 1966 

over 

1965^ 



Grand total 

Tar 

Tar crudes 

Crude products from petroleum and 
natural gas 

Synthetic organic chemicals, total 

Intermediates 

Dyes 

Synthetic organic pigments 

Medicinal chemicals 

Flavor and perfume materials 

Plastics and resin materials 

Rubber-processing chemicals 

Elastomers (synthetic rubbers) — 

Plasticizers 

Surface-active agents 

Pesticides and related products- 
Miscellaneous chemicals 



8,027 
10,205 



8,019 
10,062 



3,662 
6,332 



16,865 


19,467 


207 


219 


48 


51 


160 


185 


99 


111 


11,685 


13,585 


252 


283 


3,592 


3,929 


1,073 


1,209 


3,170 


3,321 


877 


1,013 


50,836 


57,253 



129 

88 

10,053 

194 

3,041 

1,022 

1,698 

764 

22,040 



11,472 
209 
3,411 
1,156 
1,766 
822 
24,549 



17.2 
7.5 
13.9 



12.2 
13.1 
4.0 



13.6 
13.4 
14.9 
10.0 
9.0 



Percentages calculated from figures rounded to thousands. 
Because of rounding, figures may not add to the totals shown. 



PART I. PRODUCTION AND SALES OF TARS, TAR CRUDES, AND 
CRUDES DERIVED FROM PETROLEUM AND NATURAL GAS 



Coal tar is produced chiefly by the steel industry 



byproduct of the manufacture of coke 



water-gas tar and oil-gas tar are produced by the fuel-gas industry. Production of coal tar, 
therefore, depends on the demand for steel; production of water-gas tar and oil-gas tar reflects 
the consumption of manufactured gas for industrial and household use. Water-gas and oil-gas 
tars have properties intermediate between those of petroleum asphalts and coal tars. Petroleum 
asphalts are not usually considered to be raw materials for chemicals. 

The quantity of tar produced from coal in the United States in 1966 was 802 million gallons, 
or 0. 1 percent less than the 803 million gallons produced in 1965. U. S. production of water-gas 
tar and oil-gas tar was not reported to the Commission for 1965 or 1966; production of these tars 
amounted to 19 million gallons in 1962, the last year for which production was reported to the 
Tariff Commission. 

Total consumption of tar in 1966 amounted to 763 million gallons, of which 605 million gal- 
lons was consumed by distillation, 132 million gallons as fuel, and 26 million gallons in miscel- 
laneous uses. 



TABLE 2 Tar: U.S. production and consumption, 1965 and 1966 

[in thousands of gallons] 



PRODUCTION 

Coal tar from coke-oven byproduct plants, total ■"■ 

CONSUMPTION 
Total - - 

Tar consumed by distillation, total 

Coal tar distilled or topped by coke-oven operators-"- 

Coal tar, water-gas tar, distilled by producers and tar distillers^ 

Tar consumed chiefly as fuel^ 

Tar consumed otherwise than by distillation or as fuel, total 

Coal tar consumed at coke-oven plants for roads and upkeep-"- 

Coal tar, water-gas tar, and oil-gas tar processed at tar refineries, crude tar 
consumed for upkeep at such refineries, and tar consumed in making gas and in 
special -purpose tar blends 



312,079 
303,737 



27,169 



131,890 
26,432 



Reported to the U.S. Bureau of Mines. 
^ Reported to U.S. Tariff Commission. Represents tar purchased from companies operating coke ovens and gas-retort 
plants and distilled by companies operating tar -distillation plants. 



Tar Crudes 



Tar crudes are obtained from coke-oven gas and by distilling coal tar, water-gas tar, and 
oil-gas tar. The most important tar crudes are benzene, toluene, xylene, naphthalene, and 
creosote oil. Some of the products produced from coal tar are identical with those produced from 
petroleum. Data for materials derived from petroleum are included, for the most part, with the 
statistics for materials derived from coal tar, which are shown in tables 3 and 4A.^ 



Iso table 4B. pi. UI, which lists these products and identifies the 



2 SYNTHETIC ORGANIC CHEMICALS, 1966 

Domestic production of industrial and specification grades of benzene reported by coke-oven 
operators and petroleum refinery operatori^ in 1966 amounted to 955 million gallons--15. 5 per- 
cent more than the 827 million gallons reported for 1965. These statistics include data for 
benzene produced from light oil and petroleum. Sales of benzene by coke-oven operators and 
petroleunn operators in 1966 amounted to 606 million gallons, valued at $147 million, compared 
with 511 million gallons, valued at $123 million, in 1965. In 1966 the output of toluene ^ (including 
material produced for use in blending in aviation fuel) amounted to 584 million gallons--6.4 per- 
cent more than the 549 million gallons reported for 1965. Sales of toluene in 1966 were 361 mil- 
lion gallons, valued at $62 million, compared with 325 million gallons, valued at $54 million, in 
1965. The output of xylene^ in 1966 (including that produced for blending in motor fuels) was 329 
million gallons, compared with 340 million gallons in 1965. About 98 percent of the 329 million 
gallons of xylene produced in 1966 was obtained from petroleum sources. 

Production of crude naphthalene in 1966 (including 354 million pounds of petroleum-derived 
naphthalene) amounted to 848 million pounds, compared with 811 million pounds in 1965. In 1966 
the output of creosote oil for wood preservation was 133 million gallons (100-percent creosote 
basis), compared with 124 million gallons in 1965. Production of road tar and tar (crude and 
refined) for other uses in 1966 was 68 million gallons, compared with 85 million gallons in 1965. 

TABLE 3. -- Tar and tar crudes: Summary of U.S. production of specified products, average 1957-59, 
annual 1965 and 1966 

[Leaders are used where the reported data are accepted in confidence and may not be published 
or where no data were reported] 



Unit 

of 

quantity 



1966 over 1966 over 

1957-59 1965 



Tar 

Benzene: 

Tar distillers^ - 

Coke-oven operators 

Petroleum operators 

Total— 

Toluene: 

Tar distillers 

Coke-oven operators 

Petrol emn operators 

Total - - 

Xylene: 

Tar distillers 

Coke-oven operators 

Petroleum operators 

Total 

Naphthalene: 

Crude* - 

Petroleum naphthalene, all grades 

Total 

Creosote oil (Dead oil):' 

Distillate as such (100* creosote 

basis) 

Creosote content of coal-tar solution 

(1005t creosote basis) 

Total 



1,000 gal-- 

1,000 gal— 
1,000 gal— 
1,000 gal- 
1,000 gal— 

1,000 gal- 
1,000 gal-- 
1,000 gal— 
1,000 gal- 

1,000 gal — 
1,000 gal — 
1,000 gal— 
1,000 gal— 

1,000 lb— 
1,000 lb— 
1,000 lb— 



1,000 gal- 
1,000 gal- 



27, 130 
139,121 
155,694 



4,162 
31,007 
204,421 



239,590 

795 

8,908 

180,021 



6,741 
^333,063 



189, 724 
396,882 



463,980 
346, 620 



493,634 
354,068 



90,913 
14, 172 



111,087 
12,515 



114,725 
18, 141 



26.2 
28.0 



105,085 



123,602 



13271 



26.4 



Includes data for oil-gas, water-gas, and gas-retort tar reported to the American Gas Association for 1957-59 
only, and for coal tar reported to the Division of Bituminous Coal, U.S. Bureau of Mines. 

^ Includes data for benzene produced from imported crude light oil. 

^ Includes data for material produced for use in blending motor fuels. Statistics are not comparable with .monthly 
figures, which included some o-xylene now shown on table 7A. 

* Naphthalene solidifying at less than 79° C. Figures include production by tar distillers and coke-oven operators 
and represent combined data for the commercial grades of naphthalene to avoid disclosure of the operations of indi- 
vidual companies. Because of conversion between grades, the figures may include some duplication. 

' Includes data for creosote oil produced by tar distillers and coke-oven operators and used only in wood preserv- 
ing. 



Statistics on production and sal( 
the operations of individual companies. 



Df benzene, toluene, and xylene by tar distillers cannot be shown because publication would reveal 



TAR CRUDES 3 

TABLE 4A.— Tar crudes: U.S. production and sales, 1966 

[Listed below are all tar crudes for which any reported data on production or sales may be published. (Leaders are 
used where the reported data are accepted in confidence and may not be published or where no data were reported.) 
Table 4.B in pt. Ill lists separately all products for which data on production or sales were reported and iden- 
tifies the manufacturers reporting to the U.S. Tariff Commission] 



Unit 
value ^ 



Crude light oil: Coke-oven operators 

Intermediate light oil: Coke-oven operators- - 

Ught-oil distillates: 
Benzene, specification and industrial grades, 

total= ' - 

Coke-oven operators 

Petroleum operators 

Toluene, all grades, total^ ^ 

Coke-oven operators 

Petroleum operators 

Xylene, all grades, total^ ^ 

Coke-oven operators 

Petroleum operators 

Solvent naphtha:^ Coke-oven operators 

Other light-oil distillates:^ Coke-oven operators 

Naphthalene, crude (tar distillers and coke-oven 

operators), total* 

Solldifj-ing at— 

Less than 74° C 

74° C. to less than 7^° C- 

Crude tar -acid olls:^ Coke-oven operators 

Creosote oil (Dead oil) (tar distillers and coke- 
oven operators) (100* creosote basis), total^--- 

Distillate as such (100* creosote basis) 

Creosote content of coal-tar solution (100* 
creosote basis) 

All other distillate products' 

Tar, road 

Tar (crude and refined) for other uses* 

Pitch of tar: 

Hard (water softening point above 1£0° F.) 

Other' — — 



1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 



1,000 gal- 
1,000 gal- 



1,000 gal — 
1,000 gal— 
1,000 gal— 



262,640 
5,978 



955,272 

113,932 

841,340 

583,894 

22,791 

561,103 

328,684 

6,124 

322,560 

3,161 

6,348 



132,866 



114,725 
18,141 



83,274 
3,622 



606,050 

112,095 

493,955 

361,358 

22,622 

338,736 

236,792 

6,410 

230,382 

2,954 

3,076 



147,305 

27,333 

119,972 

62,137 

4,309 

57,828 

42,585 

1,405 

41,180 

547 

272 



96,193 


18,414 


18,143 


'5,013 


14,760 
53,634 
9,492 


2,657 
7,263 
1,986 


732 
435 


28,641 
14,424 



■■• Unit value per gallon, or ton, as specified. 

^ Data reported by tar distillers are not included because publication would disclose the operations of 
individual companies. Production of benzene and toluene by tar distillers Increased in 1966, compared with 
1965; production of xylene decreased. The annual production statistics for petroleum operators on benzene, 
toluene, and xylene are not comparable with the combined monthly production figures, due to fiscal year revisions. 
Includes data for material produced for use in blending motor fuels. 

* Statistics represent combined data for the commercial grades of naphthalene. Because of conversion of 
naphthalene from one grade to another, the figures may include sane duplication. 

Statistics include only data for creosote oil sold for, or used in, wood preserving. In 1966, production of 
creosote in coal-tar solution (lOO* solution basis) amounted to 27,791 thousand gallons; sales were 27,604 
thousand gallons, valued at 5,013 thousand dollars, with a unit value of $0.18 per gallon. 

' Includes value of coal tar used in preparing creosote in coal-tar solution. 

' Includes data for pyridine crude bases, crude oresylic acid, and neutral oils produced by tar distillers, 
and for crude sodium phenolate produced by coke-oven operators. 

* Includes data for tar used for paint, pipe covering, saturating, and other uses. 

' Includes soft and medium pitch of tar (water softening points less than llfl° F., and 110° F. to 160° F. ASTM 
D61-24), pitch of tar coke, and pitch emulsion. 

Note.— Statistics for materials produced in coke and gas-retort ovens are oon5)iled by the Division of Bitumlnoue 
Coal, U.S. Bureau of Mines, Department of the Interior. Statistics for materials produced in tar and petroleum 
refineries are compiled by the U.S. Tariff Commission. 



4 SYNTHETIC ORGANIC CHEMICALS, 1966 

Some of the products included in the statistics in table 4A are derived from other products 
for which data are also included in the table.., The statistics, therefore, involve considerable 
duplication, and for this reason no group totals or grand totals are given. It is estimated that, 
after duplication has been eliminated insofar as possible, the net value of the output of these 
products and of tar burned as fuel was $552 million in 1966, compared with $500 million in 1965 
and $460 million in 1964. 

Crude Products from Petroleum and Natural Gas for Chemical Conversion 

Crude products that are derived from petroleum and natural gas are related to the intermedi- 
ates and finished products made from such crudes in much the same way that crude products 
derived from the distillation of coal tar are related to their intermediates and finished products. 
Many of the crude products derived from petroleum are identical with those derived from coal 
tar (e. g. , benzene, toluene, and xylene). Considerable duplication exists in the statistics on the 
production and sales of petroleum crudes because some of these crude chemicals are converted 
to other crude products derived from petroleum and because data on some production and sales 
are reported at successive stages in the conversion processes (see table 5A-' ). Notwithstanding 
these duplications, the statistics are sufficiently accurate to indicate trends in the industry and 
to serve as a basis for general comparison. Many of the crude products for which data are 
included in the statistics may be used either as fuel or as basic materials from which to derive 
other chemicals, depending on prevailing economic conditions; but in this report every effort 
has been made to exclude data on materials that are used as fuel. However, data are included 
on toluene and xylene which are not used directly as fuel but in blending aviation and motor- 
grade gasolines. Statistics on the production and sales of crude products from petroleum and 
natural gas for chemical conversion for 1966 are given in table 5A^. 



TABLE 5A. --Crude products from petroleum and natural gas for chemical conversion: U.S. production 

and sales, 1966 

. Listed below are the crude products from petroleum and natural gas for chemical conversion for which any reported 
data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence 
and may not be published or where no data were reported. ) Table 5B in pt. Ill lists separately all products from 
petroleum and natural gas for chemical conversion for which data on production or sales were reported and identi- 
fies the manufacturer of each! 



Grand total 

ARQMATICS AND NAPHTHENES^ 

Total - -. 

Benzene (1° and 2°), total 

Benzene, 1^ 

Benzene, 2° 

Naphthalene, all grades 

Naphthenlc acids, total 

Acid number 150-199 — 

All other 

Sodium carbolate and phenate, crude 

Toluene, all grades, total 

Nitration grade, 1° 

Pure commercial grade, 2° 

Solvent grade, 905t 

All other^ - - — 

xylenes, mixed, total 

3° 

All other^— - - 

All other aromaties and naphthenes* 

See footnotes at end of table. 



J. 000 
pounds 
50,466,599 



i.OOO 
pounds 
27,494,322 



5,329,209 
879,880 



7,503 
16,525 



,724 
;, 079,217 



279,759 
15,939 



2,580,595 
196,297 



1,301,925 
2,325,658 



1,785,497 



1,661,054 



611,358 
1,049,696 
1,955,610 



11,342 
1,665 



466 
1,199 



See also table 5B, pt. JH, which lists all the products reported and identifies the nianufacturers. 



CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS 

-Crude products from petroleum and natural gas for chemical conversion.- U.S. production 
and sales, i 966— Continued 



Production 



ALIPHATIC HYDROCARBONS 

Total - — — 

C2 hydrocarbons, total 

Acetylene' 

Ethane - - 

Ethylene - 

Cs hydrocarbons, total 

Propane 

Propylene 

C* hydrocarbons, total 

1,3-Butadlene, grade for rubbers (elastomers) 

Butadiene and butylene fractions 

n- Butane 

1-Butene and 2-butene mixture* 

leobutane 

Isobutylene 

All other' 

C5 hydrocarbons, total 

Isoprene 

All other^ 

All other aliphatic hydrocarbons aiid derivatives, total- 
Alpha olefins' 

Diisobutylene (diisobutene) 

Heptenes, mixed 

Hexane 

Nonene ( Tripropylene) 

Polybutene^° 

Tetrapropylene 

Hydrocarbon derivatives-'-^ 

All other^^ 



U, 4^9,167 



715,005 
1,493,077 
11,2A1,085 



709,834 
3,276,767 



4,385,234 
4,677,450 



,057,C 



3,612,301 
2,644,017 



4,760,865 



261, 610 



2,921,803 
878,895 
1,302,526 
1,580,592 
517,838 
460,979 
394,455 

599,388 



147,462 
451,926 



4,499,575 



1,865,705 
150,492 
400,661 

1,340,947 
380, 626 
161,280 
461,154 

124,048 



185,621 
5,613 
4,987 
37,655 
5,447 
9,913 
12,374 

4,066 



261,832 
34,034 
301,326 
186,791 
289,284 
153,373 
457,259 
30,285 
2,785,391 



162,535 
27, 178 
231,842 

Ul,202 
157,857 
305,660 
23,334 
1,317,720 



7,935 
2,040 
8,498 



6,842 
45,288 



$0,035 



.055 
.100 
.037 
.012 
.028 
.OU 
.061 
.027 



.049 
.075 
.037 

.062 
.074 
.027 
.293 

.034 



Calculated from rounded figures. 
2 Tie chemical raw materials designated as aronatlos are in some cases identical with those obtained from the dis- 
tillation of coal tar. However, the statistics given in the table above relate only to such materials as are derived 
from petroleum and natural gas. Statistics on aromatic chemicals from all sources are given in table 4A, "Tar Crudes. " 
' Includes toluene and xylene used as solvents, as well as that which is blended in aviation and motor gasolines. 
* Includes data for 90-percent benzene, crude cresylic acid, sodium cresylate, aUsyl aromatlcs, distillates, sol- 
vents, and miscellaneous cyclic hydrocarbons. 

' Production figures on acetylene from calcium carbide for chemical synthesis are collected by the U.S. Bureau of the 
Census. 

' Hie statistics represent principally the butene content of crude refinery gases from which butadiene is manu- 
factured. 

' Includes data for 1-butene, 2-butene, mixed butylenes, and mixed olefins. 
' Includes data for pentanes, pentenes, and C5 hydrocarbon mixtures. 

' Includes data for -the following molecular weight ranges: C6-C7; Cg-Cio; Cn-Ci,; C16-C20; and Cie-Cjo. 
^° Includes compounds having a molecular weight of 3,000 or less. 
^^ Includes data for di-tert-butyldisulfide and miscellaneous mercaptane. 

^^ Includes data for ethane-ethylene mixture, heptane, methane, propane-propylene mixture, octanes, eicosane, and 
hydrocarbon mixtures. 



The output of crude products derived from petroleum and natural gas as a group amounted 
to 50, 467 million pounds in 1966, or 13.4 percent more than the 44, 510 million pounds reported 
for 1965 (table 1). The larger output in 1966 is accounted for chiefly by increased production of 
ethylene, benzene, propylene, toluene, and acetylene. Sales of crude chemicals from petroleum 
in 1966 was 27,494 million pounds, valued at $865 million, compared with 23,402 million 
pounds, valued at $705 million, in 1965. 

The output of all aromatic and naphthenic products amounted to 14, 799 million pounds in 
1966, compared with 13,763 million pounds in 1965. Sales in 1966, which amounted to 10,029 
million pounds, valued at $261 million, were 1,384 million pounds larger, and valued at $46 mil- 
lion more, than those in 1965. Naphthalene was produced from petroleum sources in substan- 
tially greater quantities in 1966 than in 1965. The output of 1° and 2" benzene from petroleum 



^ SYNTHETIC ORGANIC CHEMICALS, 1966 

amounted to 6, 209 million pounds in 1966--19.3 percent more than the 5, 203 million pounds pro- 
duced in 1965. The output of toluene in 1966 was 4, 079 million pounds--?. 1 percent more than 
the 3, 810 million pounds produced in 1965. Production of xylene was 2, 326 million pounds in 
1966, compared with 2,401 million pounds in 1965. These figures include toluene and xylene 
used in blends in aviation and motor-grade gasolines. The output of naphthenic acids amounted 
to 24 million pounds in 1966, about the same as that produced in 1965. 

Production of all aliphatic hydrocarbons and derivatives from petroleum and natural gas waf. 
35, 668 million pounds in 1966, compared with 30, 746 million pounds in 1965. Sales of these 
products were 17,465 million pounds, valued at $605 million, in 1966, compared with 14,757 
million pounds, valued at $490 million, in 1965. The statistics on production of acetylene (table 
5A) include only acetylene produced from hydrocarbons and used as a raw material in the pro- 
duction of other chemicals. Total production of acetylene for chemical synthesis is reported 
to the U.S. Bureau of the Census. In 1966, production of acetylene from hydrocarbon sources, 
amounted to 715 million pounds. Production of ethylene was 11,241 million pounds in 1966--17.5 
peircent more than the 9, 570 million pounds produced in 1965. The output of propane and propylene 
was 9, 063 million pounds in 1966--13. 7 percent more than the 7, 972 million pounds produced in 
1965. Production of 1 , 3-butadiene, one of the principal ingredients of S-type synthetic rubber, 
was 2,922 million pounds in 1966, compared with 2,685 million pounds in 1965. The output of 
1 , 3-butadiene in I966--8.8 percent more than that in 1965--was the largest on record. 

The following tabulation shows the number of companies that reported production of organic 
chemical crudes in I966: 

Number 
of 
Chemical group companies 

Tar crudes 13 

Petroleum crudes 73 



PART II. PRODUCTION AND SALES OF INTERMEDIATES AND FINISHED SYNTHETIC 
ORGANIC CHEMICALS, BY GROUPS 

General 

On the basis of their principal uses, the synthetic organic chemicals covered in this report 
are classified either as intermediates or as finished products. Finished products, in turn, are 
grouped as follows: Dyes, synthetic organic pigments, medicinal chemicals, flavor and perfume 
materials, plastics and resin materials , rubber-processing chemicals, elastomers (synthetic 
rubbers), plasticizers , surface-active agents, pesticides and related products, and miscellane- 
ous synthetic organic chemicals. Most of these groups are further subdivided, according to 
chemical classes, into cyclic and acyclic compounds. As most of the intermediates are used in 
the manufacture of finished products, aggregate figures that cover both intermediates and finished 
products necessarily include considerable duplication. 

Total production of synthetic organic chemicals (intermediates and finished products com- 
bined) in 1966 was 100, 627 million pounds, or 13. 2 percent more than the output of 88, 864 mil- 
lion pounds reported for 1965 (see table 6). Sales of synthetic organic chemicals in 1966 amounted 
to 52, 720 million pounds, valued at $9, 958 million, compared with 46, 807 million pounds, valued 
at $9,021 million, in 1965. Production of all cyclic products (intermediates and finished products 
combined) in 1966 totaled 32, 133 million pounds, or 13. 8 percent more than the 28,229 million 
pounds produced in 1965. The output of acyclic organic chemicals in 1966 amounted to 68,494 
million pounds--13. percent more than the 60, 635 million pounds reported for 1965. 



TABLE 6.— Synthetic organic chemicals.- Summary of U.S. production and sales of intermediates and finished 
products, average 1957-59, annual 1965 and 1966 

[Production and sales in thousands of pounds; sales value in thousands of dollars] 





Average 
1957-59 


1965 


1966 


Increase, or decrease (-) 




1966 over 
1957-59 


1966 over 
1965 


Organic chemicals, cyclic and acyclic, 
grand total: 
Production 

Sales value 

Cyclic, total: 


45,598,853 
23,744,812 
5,743,764 

14,381,651 
8,829,037 
2,785,100 

31,217,202 
14,915,775 
2,958,664 

7,343,167 

2,919,264 

481,920 

150,830 
141,731 
182,513 

38,603 
30,218 
58,648 


88,864,092 
46,807,057 
9,020,540 

28,229,128 
16,499,189 
3,855,492 

60,634,964 
30,307,868 
5,165,048 

16,865,164 

7,551,210 

814,383 

207,193 
189,965 
292,284 

48,045 
38,024 
93,635 


100,626,696 
52,719,594 
9,958,383 

32,132,902 
18,867,433 
4,328,963 

68,493,794 
33,852,161 
5,629,420 

19,466,775 

8,852,033 

925,092 

219,194 
204,135 
331,453 

51,128 
43,316 
107,594 


Percent 

120.7 
122.0 
73.4 

123.4 
113.7 
55.4 

119.4 
127.0 
90.3 

165.1 
203.2 
92.0 

45.3 
44.0 
81.6 

32.4 
43.3 
83.5 


Percent 

13.2 
12.6 
10.4 

13.8 
14.4 
12.3 

13.0 
11.7 
9.0 

15.4 
17.2 
13.6 

5.8 
7.5 

13.4 

6.4 
13.9 
14.9 


Sales 

Sales value 

Acyclic, total: 


Sales - 

Sales value 

1. Intermediates. Cyclic 

Production 

Sales 




2. Dyes, Cyclic 
Production 


Sales 




J. .Synthetic Organic Pigments. Cyclic 


Sales - 

Sales value 



SYNTHETIC ORGANIC CHEMICALS, 1966 

■ Synthetic organic chemicals: Summary of U.S. production and sales of intermediates and finished 
products, average 1957-5S, annual 1965 and i566— Continued 

[Production and sales in thousands of pounds; sales value in thousands of dollars] 

Increase, or decrease (-) 



^. Medicinal Chemicals 

Cyclic: 

Production 70,654 100,040 116,164 

Sales ~ 54,151 72,479 76,842 (^ 

Sales value 535,297 321,158 356,646 ( ^) 

Acyclic: 

Production 31,592 59,480 69,305 119.4 

Sales 28,738 56,569 59,621 {'■) 

Sales value 35,660 41,011 41,762 ( ^) 



5. Flavor and Ptrfumt Materials 

CycUc: 

Production 27,312 53,223 61,406 

Sales 22,446 44,559 49,597 

Sales value— - 33,903 56,800 60,915 

Acyclic: 

Production 19,033 46,001 49,264 

Sales— 19,958 43,144 48,717 

Sales value- — 21,912 28,180 31,719 



124.8 
121.0 
79.7 

158.8 
144.1 
44.8 



6. Plastics and Besin Materiali 

Cyclic: 

Production 2,278,862 4,452,975 5,066,571 

Sales- — 1,900,032 3,689,722 4,254,211 

Sales value 518,501 873,501 988,001 

Acyclic: 

Production- - 2,628,779 7,231,900 8,518,301 

Sales 2,438,853 6,363,044 7,217,427 

Sales value 864,523 1,630,932 1,752, C 



122.3 
123.9 
90.5 

224.0 
195.9 
102.7 



7. Bubber-Processmg Chemicals 

Cyclic: 

Production 159,182 211,403 241,248 

Sales— 115,704 166,214 182,790 

Sales value 74,479 109,204 123,581 

Acyclic 

Production 29,150 40,542 42,087 

Sales 22,127 27,504 26,495 

Sales value 1A,289 14,189 14,622 



51.6 
58.0 
65.9 

44.4 
19.7 
2.3 



8. Elastomers (Synthet 

Cyclic: 

Production 1,938,732 2,300,092 2,482,375 

Sales 1,726,757 1,897,921 2,108,089 

Sales value 404,897 442,722 463,222 

Acyclic: 

Production 521,811 1,291,562 1,446,812 

Sales - 509,262 1,1A3,242 1,303,169 

Sales value 199,627 400,726 454,796 



28.0 
22.1 
14.4 

177.3 
155.9 
127.8 



9. Plasticizers 

Cyclic: 

Production 348,210 798,741 897,249 

Sales 297,423 764,736 873,109 

Sales value 83,509 133,04^ 156,967 

Acyclic: 

Production 118,118 274,456 311,742 

Sales 100,984 256,887 282,577 

Sales value 38,772 81,348 89,034 

See footnote at end of table. 



163.9 
179.8 
129.6 



GENERAL 



TABLE 6.--Synthetic organic chemicals: Summary of U.S. production and sales of intermediates and finished 
products, average 1957-59, annual 1965 and i966~Continued 

[production and sales in thousands of pounds; sales value in thousands of dollars] 



Average 
1957-59 



Increase, or decrease (-) 



1966 over 1966 over 

1957-59 1965 



Cyclic: 

Production- 
Sales 

Sales value - 

Acyclic: 

Production- 
Sales 

Sales value - 



11- Pes 

CycUo: 

Production- 
Sales 

Sales value- 
Acyclic; 

Production — 

Sales 

Sales value- 



Cyclic: 

Production- 
Sales 

Sales value - 

Acyclic : 

Production- 
Sales 

Sales value- 



852,314 
800,'i32 
127,936 

502,715 
432,135 
113,215 



440,384 
375,627 
150,837 

105,080 
91,938 
49,049 



733,401 
445,252 
132,660 

27,260,924 
11,271,780 
1,621,617 



1,371,320 
877,202 
96,153 

1,799,158 
820,660 
204,035 



682,671 
582,344 
377,858 

194,526 
181,561 
119,208 



1,138,261 
624,813 
244,750 

49,697,339 
21,415,257 
2,645,419 



1,385,217 
879,235 
97,187 

1,936,100 
886,818 
217,726 



776,909 
605,229 
446,946 

236,201 
217,027 
136,856 



1,368,666 
738,847 
271,359 

55,883,982 
23,810,310 
2,890,825 



76.4 
61.1 
196.3 

124.8 
136.1 
179.0 



86.6 
65.9 
104.6 

105.0 
111.2 
78.3 



13.8 
3.9 



21.4 
19.5 
U.8 



20.2 
18.2 
10.9 

12.4 
11.2 
9.3 



Data for 1966 are not comparable with those for average 1957-59. 

The following tabulation shows, by chemical groups, the number of companies that reported 
production in 1966 of one or more of the chemicals included in the groups listed in table 6: 



flumber 
Chemical group of 

companies 

Intermediates 219 

Dyes 50 

Synthetic organic pigments 36 

Medicinals chemicals 111 

Flavor and perfume materials 54 

Plastics and resin materials 305 



dumber 
Chemical group of 

cojnpanie: 

Rubber-processing chemicals 32 

Elastomers (synthetic rubbers) 29 

Plasticizers 55 

Surface-active agents 201 

Pesticides and related products 87 

Miscellaneous chemicals 313 



10 SYNTHETIC ORGANIC CHEMICALS, 1966 

Cyclic Intermediates 

Cyclic intermediates are synthetic organic chemicals derived principally from coal-tar 
crudes produced by destructive distillation (pyrolysis) of coal and from petroleum and natural 
gas. Most cyclic intermediates are used in the manufacture of more advanced synthetic organic 
chemicals and finished products, such as dyes, medicinal chemicals, elastomers (synthetic 
rubbers), pesticides, and plastics and resin materials. Some intermediates, however, are 
sold as end products without further processing. For example, refined naphthalene may be 
used as a raw material in the manufacture of 2-naphthol or of other more advanced intermedi- 
ates, or it may be packaged and sold as a moth repellent or as a deodorant. In general, the 
classification of a given chemical as an intermediate is determined by the way in which the 
greater part of its output is consumed. Since many intermediates represent successive steps 
in production, the totals given necessarily include considerable duplication. In 1966, nearly 
half of the total output of cyclic intermediates was sold; the remainder was used by the produc- 
ing plants in the manufacture of more advanced products. The statistics on cyclic intermedi- 
ates for 1966 are given in table lA^. 

Total production of cyclic intermediates in 1966--19,467 million pounds--was the largest 
on record, and was 15.4 percent larger than the output of 16,865 million pounds reported for 
1965. The larger output of cyclic intermediates in 1966 was attributable to increased demand 
by the chemical products industries, particularly those industries that produce dyes, pesticides, 
plasticizers , and plastics and resin materials. Sales of cyclic intermediates in 1966 amounted 
to 8, 852 million pounds, valued at $925 million, compared with 7, 551 million pounds, valued 
at $814 million, in 1965. In terms of quantity, sales of cyclic intermediates in 1966 were 17.2 
percent larger than those in 1965 and in terms of value, 13. 6 percent larger. 



TABLE 1 A— Cyclic intermediates: U.S. production and sales , 1966 



[ listed below are all cyclic Intermediates for which any reported data on production or sales may be published. 
(Leaders are used where the reported data are accepted in confidence and may not be published or where no 
data were reported.) Table 7B in pt. Ill lists alphabetically all cyclic intermediates for which data on 
production or sales were reported and identifies the manufacturer of each] 



Sale 



Unit 
value^ 



Total - ~ 

Acetanilide, tech 

Acetophenone, tech 

Alkylbenzenes^ 

•4' -Aminoacetanilide ( Acetyl-p-phenylenediamine) 

5-Amino-2-(p-aminoanilino)benzenesulfonic acid 

1-Aminoanthraquinone and salt 

2-Aminoanthraquinone and salt 

6-itaiino-3,4' -azodibenzenesulfonic acid (C.I. Acid Yellow 9)- 

l-Amino-4-benzamidoanthraquinone 

l-Amino-5-benzamldoanthraquinone 

7-(p-Aminobenzamido)-i-hydroxy-2-naphthalenesulfonic acid 

2-Aniino-p-benzenedisulfonic acid [S03H=1] 

l-Amino-'4-bromo-9,10-dihydro-9,10-dloxo-2-anthraoenesulfonic 

and sodium salt 

l-Amino-2-bromo-<t-hydroxyanthraquinone 

l-Amino-2-bromo-4-p-toluidinoanthraquinone 

l-Amlno-5-ohloroanthraquinone 

o-(3-Amino-4-chlorobenzoyl )benzoic acid 

3-Amino-5-chloro-2-hydroxybenzenesulfonic acid 



5,438 

965 

714, 901 

696 

7 

1,883 

1,054 



pound 

$0.10 



2,297 

714 

560,076 



See footnotes at end of table. 



1- See also table 7B, pt. Ill, which lists these products alphabeticaUy and identifies the manufacturers, and table 23 in the appendix, 
/hich shows imports of intermediates and related products during 1965 and 1966. 



CYCLIC INTERMEDIATES 
TABLE TA. — Cyclic intermediates: U.S. production and i 



i 966— Continued 



Unit 
valued 



6-Jtaino-A-ohloro-m-toluenesulfonlo acid [S03H=l] 

l-Amino-aj-i-dibromoanthraquinone 

l-Amino-9,10-dihydro-9,10-dioxo-4.-p-toluenesulfonamido-2-anthra- 

oenesulfonio acid, sodium salt 

'4-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid (H acid), 

monosodiujL salt 

<i-Amino-3-hydroxy-l-naphthalenesulfonlc acid (1,2,4-acld) 

6-Amino-<i-hydroxy-2-naphthalenesulfonic acid (Gamma acid), 

sodium salt 

7-Amlno-4-hydroxy-2-naphthalenesulfonic acid (j acid), sodium salt- 

N-('V-Amino-3-methoxy-l-anthraquinonyl )-p-toluenesulf on amide 

4' Amino-N-methylacetanillde 

2-Amino-l,5-naphthalenedisulfonic acid 

6-Amino-l,3-naphthalenedisulfonio acid (Jtailno I acid) .-- 

7-Aiiilno-l,3-naphthalenedlsulfonlc acid (Amino G acid) 

4-Amino-l-naphthalenesulfonic acid (Naphthionic acid) 

5-Amino-2-naphthalenesulfonic acid (l,6-Cleve's acid) 

5(and 8)-Amino-2-naphthalenesulfonlo acid (Cleve's acid, mixed) 

6-Amlno-2-naphthalenesulfonic acid (Broenner's acid) 

8-Amino-l-naphthaleneaulfonio acid (Peri acid) 

8-Amino-2-naphthalenesulfonic acid (l,7-Cleve's acid) 

8-Amino-2-naphthol 

2-Amino-5-nitrobenzenesulfonic acid [S03H=1] 

4-Amino-4' nitro-2, 2' -stilbenedisulf onlc acid 

3'-Aminooxanilic acid 

p-^(p-Aminophenyl)azo]benzenesulfonic acid 

4.-Amino-m-toluenes\ilfonic acid rS03H=l] 

6-Amino-m-toluenesulfonic acid [SOjHil] 

16- Aminoviolan throne 

Aniline (Aniline oil) 

7-Anilino-4-hydroxy-2-naphthalenesulfonic acid (Rienyl J acid) 

Anilinomethanesulfonio acid and salt 

8-Anilino-l-naphthalenesulfonic acid (Phenyl peri acid) 

o-Anisidine 

o-Anisidinomethanesulfonic acid 

Anthra[l,9-cd]pyrazol-6(2H)-one (lyrazoleanthrone) 

Benzaldehyde, tech 

l-Benzamido-5-chloroanthraquinone 

7H-Benz[de]anthracen-7-one ( Benzanthrone ) 

Benzidine hydrochloride and sulfate 

Benzoic acid, tech 

2-Benzcthiazolethiol (2-Mercaptobenzothlazole), sodium salt 

o-Benzoylbenzoic acid 

[3,3'-Bianthra[l,9-cd]pyrazole]-6,6'-(2H,2'H)dione (Pyrazole- 

anthrone yellow) 

[4,4' -Bi-7H-benz[de] anthracene] -7,7' -dione 

[l,l'-Binaphthalene]-8,8'-dicarboxylic acid 

1,4-Bis [l-anthraquinonylamino]anthraquinone 

4,4'-Bis [dimethylamlnojbenzophenone (Michler's ketone) 

3-Bromo-7H-benz[de]anthracen-7-one (3-Broniobenzanthrone) 

l-Bromo-4-(methylamino)anthraquinone 

l-Chloroanthraquinone 

2-Chloroanthraquinone 

Chlorobenzene, mono- 

o-(p-Chlorobenzoyl) benzoic acid 

l-Chloro-2,4-dinitrobenzene (Dlnltrochlorobenzene) 

6-Chlorometanilic acid 

l-Ghloro-2-methylanthraquinone 

2-Chloro-4-nltroaniline (o-Chloro-p-nltroaniline) 

4-Chloro-2-nitroanlline (p-Chloro-o-nitroaniline) 

l-Chloro-5-nltroanthraquinone 

l-Chloro-2-nitrobenzene ( Chloro-o-nitrobenzene ) 

l-Chloro-3-nitrobenzene (Chloro-m-nitrobenzene) 

l-Ghloro-4.-nitrobenzene (Chloro-p-nitrobenzene) 

4-Chloro-3-nitrobenzeneBulf on amide 



16 
116 
1,053 
803 
224 
82 
192 
100 
518 
103 



51 

22 

248 

217 

360 

9 

239,004 

48 

285 

355 

2,024 

447 

28 

5,319 

97 

2,193 

1,251 

20, 511 

25,552 

5,903 

30 
459 

20 



46 

227 

950 

576,749 

1,570 

8,535 

27 

178 

389 

566 



$1.49 
2.36 



,769 
218 
,"637 



153 
,409 



See footnotes at end of table 



SYNTHETIC ORGANIC CHEMICALS, 1966 
TABLE TA.— Cyclic intermediates: U.S. production and sales , i 566— Continued 



Production 



1.000 



4-Chloro-3-nitrobenzenesulfonyl chloride 

o-(4-Clhloro-3-nitrobenzoyl) benzoic acid 

"i-Qiloro-S-nitro toluene 

a-Chlorotoluene (Benzyl chloride) 

5-Chloro-o-toluidine [ NH^^l] ("i-Chloro-o-toluidine [CHj^l]) ~ 

N-[(5-Chloro-o-tolyl)azo]saroosine 

[ (<i-Chloro-o-tolyl)thio]acetic acid 

Cresols, total^ 

o-Cresol 

(m,p)-Cresol 

All other* - - 

Cresylic acid, refined, total 

From coal tar^ 

From petroleum 

Cumene 

Cyolohexone 

C^clohexanone 

CJrclohexylamine 

1,4-Diajninoanthraquinone 

2,6-Diaminoanthraquinone 

l,4-Dianiino-2,3-dihydroanthraquinone 

i,4'-Diamino-2,2'-stilbenedisulfonic acid 

^,5'-Dibenzamido-l, I'-imlnodianthraqulnone 

1, 5-Dibenzoylnaphthalene 

3,9-Dibromo-7H-benz[de]anthracen-7-one 

2,5-Diohloroanlllne and hydrochloride [HHa^-'-] 

1, 5-Dichloroanthraquinone 

1,8-Dichloroanthraquinone 

o-Dlchlorobenzene 

p-Dichlorobenzene 

3,3'-Dlchlorobenzidine base and salts 

2, 5-Dichloro-4-(3-methyl-5-oxo-2-pyrazolin-l-yl )benzenesulfonio 

acid - - - 

2,6-Dichloro-4-nitroaniline 

l,4-Dichloro-2-nitrobenzene (Nitro-p-diohlorobenzene) 

Dicyclopentadiene (includes cyolopentadlene ) 

p-(Diethylamino)benzaldehyde 

N, N-Diethylanlllne - - 

9, 10-Dthydro-l,^-dihydroxy-9, lO-dioxo-2-anthraoeneBUlf onio 

acid (2-Oainizarinsulfonlc acid) 

9, lO-Dihydro-9, 10-dioxo-l,5-anthraoenedisulfonio acid and 

disodium salt 

9, lO-Dihydro-9, 10-dioxo-l, 8-anthracenedisxilf onio acid, 

potassium salt 

9,10-Dihydro-9, 10-dloxo-2,6-anthracenedleulfonio acid and salt — 
9, lO-Dihydro-9, lO-dioxo-l-anthracenesulT onic acid and salt (Gold 

salt) - 

9, 10-Dlhydro-5-nitro-9, 10-dioxo-l-anthraceneeulf onic acid 

l,A-Dlhydroxyanthraqulnone (Qulnizarln) — 

1,5-Dihydroxyanthraquinone ( Anthraruf in ) 

1,8-Dihydroxyanthraquinone (Chrysazln) 

l,5-Dihydroxy-4-,8-dinitroanthraqulnone 

l,8-Dil^roxy-A,5-dinitroanthraquinone (4,5-Dinitroohrysazin) 

16, 17-W.hydroxyviolanthrone (Dlhydroxydibenzanthrone) 

3,3'Dimethoxybenzidine (o-Dianlsidine) 

N, N-Wmethylaniline 

N, N-Dimethylbenzylamine 

2,2' -Dimethyl-1 , 1 ' -bianthraquinone 

N,N-Diinethyl-p-nitrosoaniline 

2,4-Dlnitroaniline 

l,5(and l,8)-Dinitroanthraquinone 

2,4-Dinltrophenol, tech 



500 

220 

102 

74,994 

35 



16, 586 
35,352 
28,067 



17,665 
36,842 

894,827 

1,900,792 

314,424 

11, 922 

49 

181 

420 

6,510 

162 

288 

502 

206 

173 

64 

51,386 

66,307 

2,790 

347 
607 
793 
49,672 
21 
1,901 



3,501 

83 

2,346 

157 

193 

95 
275 
320 
518 
13,452 

81 
116 

45 
206 
235 
971 



13,000 
35,990 
22,061 



50,726 
65,569 
3,050 



431 

23^008 

970 



26 



1,917 
4,771 
7,801 



5,065 
5,893 
3,923 



1,503 
500 



See footnotes at end of table. 



CYCLIC INTERMEDIATES 
TABLE 7A. -- Cyclic intermediates: U.S. production and sales , i566— Continued 



A, A' -Dinitrostilbene-2,2'-disulfonlo acid 

2,<»-Dlnitrotoluene 

1, S-Diphenoxyanthraqulnone 

Diphenylamine 

1,4-Dl-p-toluidinoanthraquinone 

Divlnylbenzene 

p-Dodeoylphenol 

N-Ethylaniline, refined 

Ethylbenzene' 

N-Bthyl-N-phenylbenzylamine 

Urdroquinone, tech 

p-ltydroxybenzenesulfonic acid 

p-f^droxybenzolo acid, methyl ester 

p-lirdroxybenzoic acid, propyl ester 

i-Hydroxymetanilamide 

4-I^rdroxyiiietanlllc acid 

3-firdroxy-2,7-naphthalenedisulfoDic acid, disodium salt 

6-Itydroxy-2-naphthalenesulfonic acid and sodium salt 

3-}trdroxy-2-naphtho-o-toluidide 

N-(7-[fydroxy-l-naphthyl)acetamide 

l,l'-Imlnobis[4-aiDinoanthraquinone] 

7,7'-ImlncbisU-hydroxy-2-naphthalenesulfonic add] 

l,l'-Iininobis[4-nitroanthraquinone] 

1,1' -Imlnodianthraquinone (l,l'-Dianthrimlde) 

Isooyanic acid derivatives, total 

Diphenylmethane <t,4'-diisocyanate (MDI) 

Toluene 2,4- and 2,6-diisocyanate (80/20 mixture) 

Other isocyanic acid derivatives -.— . 

4.,4'-Isopropylidenediphenol (Bisphenol A) 

Isovlolanthrone ( Isodibenzanthrone) 

Leuco quinizarin (1,4, 9, lO-Anthratetrol ) 

2,4-Liitidine 

Melamlne 

dl-p-Mentha-l,8-diene (Limonene) 

o-Meroaptobenzoic acid (Thlosalicylic acid) 

l-(Methylaniino)anthraquinone 

4,4'-Methylenebis[N,N-dlmethylaniline] (Methane base) 

4,4'-Methylenedianillne 

m-(3-Metl^rl-5-oxo-2-pyrazolin-l-yl)benzenesulf on amide 

p-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonlc acid 

4-(3-Methjrl-5-oxo-2-pyrazolin-l-yl)-m-toluenesulfonic acid 

[S03H=1] 

3-Methyl-l-phenyl-2-pyrazolin-5-one (Developer Z) 

a-Methylstyrene 

Naphthalene, solidifying at 79° C. or above (refined flake) 

(from domestic crude) 

2,7-Naphthalenedisulfonio acid 

1,4, 5,8-Naphthalenetetracarboxylio acid 

1-Naphthol (a-Naphthol) — 

Naphthostyril 

Naphth[l,2-dl[l,2,3loxadlazole-5-sulfonic acid 

p-Nitroaniline 

5-Nitro-o-anisidine [ NH2=l] 

Nitrobenzene 

m-Nitrobenzenesulfonic acid and sodium salt 

7(and 8)-Nitronaphth[l,2-d][l,2,3] oxadiazole-5-sulfonic acld- 

p-Nltrophenol and sodium salt 

3-Nitro-p-toluenesulf onic acid [sOjH^l] 

5-Nitro-o-toluenesulfonio acid [S03H=l] 

2-Nitro-p-toluldine [nH2=1] 

5-Nltro-o-toluldine [nH2=1] 

16-Nltroviolan throne 

Nonylphenol 

l-[7-0ico-7H-benz [de] anthracen-3-yl )amlDo] anthraquinone 



Production 



9,376 

116 

31,615 

195 

2,663 

13,525 

1,505 

,245,000 

692 

13,652 

6,132 



6,135 
173,283 
44,070 



,018 
,750 

250 
,853 
,711 

969 
r025 
87 
,261 
,208 

367 



Qaantity Value 



pounds 

6,517 
28,569 
1,971 



540 
58,315 
12,727 



dollars 
525 
7,555 
1,519 



190 

14,716 

732 



See footnotes at end of table 



SYNTHETIC ORGANIC CHEMICALS, 1966 
TABLE IK. —Cyclic intermediates: U.S. production and sales , i 966— Continued 



Production 



l,l'.[(7-Oxo-7H-benz[de]anthraoen-3,9-ylene)diimino]di- 

anthraquinone 

5-Oxo-l-phenyl-2-pyTazoline-3-oarboxylio acid, ethyl ester- 
Phenol, grand total-' 

Natural, total 

From coal tar 

From petroleum 

Synthetic , total 

From oumene 

Other synthetic 



Hienylacetic acid and salts 

Phenylacetonitrile (ct-Tolunitrlle) 

p-Phenylazoaniline (C.I. Solvent Yellow 1) and hydrochloride- 

p-Hienylenediamine 

l-Rienyl-l,2-propanedione, 2-oxime 

Hithalio anhydride 



Pioolines, total-" 

2-Picoline (a-Picoline)- 
Other picolines 



Piperidine 

Propiophenone 

8,16-iyranthrenedione 

2° I^idine^ 

Quinaldine 

Salicylaldehyde 

Salicylic acid, teoh 

Styrene, all grades 

Terephthalic acid 

Terephthalic acid, dimethyl ester 

1,4,5,8-Tetrachloroanthraquinone 

1,4, 5,8-Tetrahydroxyanthraquinone, leuco derivative 

1,4, 5, 8-Tetrakis ( l-anthraquinonylamino )anthraquinone 

(Pentanthrimide) 

4,4'-Thiodianiline 

Toluene-2,4-diajiiine (4-m-Tolylenediaiii-i;> .-1 

o(and p)-Toluenesulfonic acid 

o-(p-Toluoyl)benzoic acid 

4-(o-Tolylazo)-o-toluidine (C.I. Solvent Yel. 3) 

1,3,3-Trimethyl-o^,' -indolineacetaldehyde 

l,3,3-Trimethyl-2-methyleneindoline (Trimethyl base)-- 

7,7'-Ureylenebis[4-hydroxy-2-naphthalenesulfonio acid] (J acid 



urea)- 



Violanthrone (Dibenzanthrone) — 

o-3Cylene 

p-}^lene 

All other cyclic intermediates- 



1.000 



1,346,621 



57,135 
39,850 
17,285 
1,289,486 
613,435 
676,051 

4,628 



652 

246 

675,180 



2,534 

,191,548 

513,868 

797,470 

131 

120 

236 
13 
68,468 
6,926 
427 
448 
143 
284 

393 

476 

403,211 

518,801 

■369,123 



571,047 



52,272 
37,778 
14,494 
518,775 
280,374 
238,401 



5,034 
3,511 
1,523 



34,617 
1,147 



1,397 
2,023 



457 

5,068 

2,018 

3,915 

1,509,071 



397,224 

459,955 

1,354,505 



Calculated from rounded figures. 

^ Principally straight-chain dodecylbenzene, tridecylbenzene and other straight- 1 
lesser amounts of branohed-chain compounds. 

•* Includes data for coke ovens and gas-retort ovens, reported to the Division of 
Mines, Department of the Interior, and for tar refineries and other producers, reported .hi I'. 

* Figures include (o,m,p)-cresol from tar and some m-cresol and p-oresol. 

^ Does not include ethylbenzene produced and consumed in continuous -process styrene manufacture 



Ikylbenzenes, but includes 



DYES 15 

In 1966, production of ethylbenzene was 3,245 million pounds, or 7.4 percent larger than 
the 3,023 million pounds reported for 1965. Output of styrene in I966 was 3, 192 million pounds, 
an increase of 11.4 percent over the 2,864 million pounds in 1965. Other intermediates whose 
production exceeded one billion pounds in 1966 were cyclohexane (1,901 million pounds), and 
phenol (1,347 million pounds). The output of other large-volume intermediates in 1966 compared 
with production in 1965 was as follows: Cumene, 895 million pounds (35. percent larger than in 
1965); terephthalic acid, dimethyl ester, 797 million pounds (46.4 percent larger); alkylbenzenes , 
71 5 million pounds ( 14. 4 percent larger ); phthalic anhydride, 675 million pounds (11.0 percent 
larger); chlorobenzene, 577 million pounds (5. 6 percent larger); p-xylene, 519 million pounds 
(30. 9 percent larger); o-xylene, 403 million pounds (14. 8 percent larger); aniline, 239 million 
pounds (22.2 percent larger); and isocyanates, 223 million pounds (21. 3 percent larger). 

Dyes 

The synthetic dyes produced in the United States are all derived in whole or in part from 
cyclic intermediates. Approximately two-thirds of the dyes consumed in the United States are 
used by the textile industry to dye natural and synthetic fibers or fabrics; about one-sixth are 
used for coloring paper; and the rest are used chiefly in the production of organic pigments and 
in the dyeing of leather and plastics. Of the several thousand different synthetic dyes that are 
known, more than one thousand five hundred are manufactured annually by one or more domestic 
producers. The large number of dyes results from the many different types of materials to which 
dyes are applied, the different conditions of service for which dyes are required, and the costs 
that a particular use can bear. Dyes are sold as pastes, powders, lumps, and solutions; concen- 
trations vary from 6 percent to 100 percent. The concentration, form, and purity of a dye are 
determined largely by the use for which it is intended. 

Table 8A shows U.S. production and sales of dyes in 1966, total and by individual dyes 
using Colour Index classification and terminology. 

Total domestic production of dyes in 1966 amounted to 219 million pounds, or 5. 8 percent 
more than the 207 million pounds produced in 1965 (table 8A). Sales of dyes in 1966 amounted 
to 204 million pounds, valued at $331 million, compared with 190 million pounds, valued at 
$292 million, in 1965. In terms of quantity sales of dyes in 1966 were 7. 5 percent larger than 
in 1965 and in terms of value, 13. 4 percent larger. The average unit value of sales of all dyes 
in 1966 was $1. 62 a pound, or 5. 2 percent greater than the $1. 54 a pound reported in 1965. 

For many important individual low- and medium-priced dyes, for which statistics are 
given in table 8A, production was larger in 1966 than in 1965. The output of Vat Black 27 and 
Acid Blue 9 more than doubled in 1966 compared with 1965. The output of Vat Black 27 was 1. 5 
million pounds in 1966 compared with 747, 000 pounds in 1965; that of Acid Blue 9 was 1. 5 mil- 
lion pounds in 1966, compared with 748,000 pounds in 1965. Other important dyes whose output 
was substantially larger in 1966 than in 1965 were Vat Green 8 (76. 1 percent), Vat Yellow 4 
(36. percent), Vat Green 3 (35. 2 percent). Disperse Yellow 3 (33. 7 percent). Vat Black 25 
(31. 5 percent). Direct Brown 95 (30. 5 percent), Basic Yellow 11 (27. percent), Basic Brown 4 
(26.4 percent) and Direct Yellow 106 (17.2 percent). 

On the other hand, the output of a few important dyes was smaller in 1966 than in 1965. Pro- 
duction of Vat Blue 18 was 929, 000 pounds in 1966, or 35. 2 percent less than the 1. 4 million 
pounds produced in 1965; that of Mordant Black 17 was 656,000 pounds, or 32.4 percent less than 
the 970,000 pounds produced in 1965. The output of Vat Orange 15 was 27. 5 percent smaller in 
1966 than in 1965; that of Coupling Component 7 was 21. 5 percent smaller; and that of Direct 
Blue 2 was 19. percent smaller. 



See also table 8B, pt. IH, which lists these products and identifies the manufacturers, and the appendix (table 23), which shows imports 
of dye« during the years 1965-66. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 



-Bemenoid dyes.- U.S. production and sales, 1966 



[Listed below are all benzenoid dyes for which any reported data on production or sales may be published. (Leaders 
are used where the reported data are accepted in confidence and may not be published or where no data were re- 
ported. ) Table 8B in pt. Ill lists all dyes for which data on production or sales were reported and identifies the 
manufacturer of each] 



Production 



Sales 



Grand total 

ACID DYES 

Total — 

Acid yellow dyes, total 

Acid Yellow 3 - 

Acid Yellow 11 

Acid Yellow 17 — 

Acid Yellow 23 — - 

Acid Yellow 36— — ■ 

Acid Yellow ^0 — 

Acid Yellow <i2 ■ 

Acid Yellow AA ■ 

Acid Yellow 5A ■ 

Acid Yellow 73 

Acid Yellow 99 

Acid Yellow 12^ - — ■ 

Acid Yellow 151— 

All other— - 

Acid orange dyes, total 

Acid Orange 1 

Acid Orange 7 

Acid Orange 8 

Acid Orange 10 

Acid Orange 2A 

Acid Orange 60 

Acid Orange 64 

Acid Orange 116 - 

All other- - 

Acid red dyes, total 

Acid Red 1 

Acid Red A- - 

Acid Red U 

Acid Red 18— 

Acid Red 26 

Acid Red 37— 

Acid Red 73 

Acid Red 85 

Acid Red 87 

Acid Red 88 

Acid Red 89 

Acid Red llA — 

Acid Red 137 

Acid Red 151 - 

Acid Red 182 

Acid Red 186 

All other 

Acid violet dyes, total 

Acid Violet 1 

Acid Violet 3 

Acid Violet 7 - 

Acid Violet 12 

Acid Violet 49— - — 

All other 



i , 000 
219, 194 



4,100 



635 
414 
404 
643 
69 
54 
297 
610 



137 
59 
256 
200 
678 



J, 000 
ponnds 
204,135 



55 
637 
401 
341 
597 



dollars 
331,453 



,435 



— rnr 

112 
1,187 
805 
379 
462 
99 
109 
160 
185 
206 
239 
469 
3,892 

4,637 
119 
651 
485 
433 
819 
153 



580 
321 
197 
221 



See footnotes at end of table. 



DYES 



TABLE 8A. ~-Bemenoid dyes : U.S. production and sales, i 966- -Continued 



Production 



ACID DYES— Continued 

Acid blue dyes, total 

Acid Blue 7— 

Acid Blue 9 

Acid Blue 25 - 

Acid Blue 40— 

Acid Blue 41 

Acid Blue 43 

Acid Blue 45 

Acid Blue 62- 

Acid Blue 78 

Acid Blue 90 

Acid Blue 113-— - 

Acid Blue 158 and 158A- 

All other - 

Acid green dyes, total 

Acid Green 3 

Acid Green 9 

Acid Green 12 

Acid Green 16 - 

Acid Green 20 

Acid Green 25 

All other 

Acid brown dyes, total 

Acid Brown 14 

All other — 

Acid black dyes, total — 

Acid Black 1 

Acid Black 24 

Acid Black 48— - 

Acid Black 107 

All other - 

AZOIC DYES AND COMPONENTS 

Total 

Azoic Yellow 1 

Azoic Orange 3 

Azoic red dyes, total 

Azoic Red 1— — - 

Azoic Red 6 

All other - — 

Azoic Violet 1 - 

Azoic Blue 2 

Azoic Blue 3 

Azoic Brown 9 

Azoic black dyes 

All other azoic compositions 



■ Diazo Component 
(Fast Color Base 



Total 

Azoic Diazo Component 4, base- 
Azoic Diazo Component 9, base-- 
Azoic Diazo Component 10, base- 
Azoic Diazo Canponent 12, baee- 



92 
1,514 



255 
1,167 



4,623 



l,2iA 
106 
26 
205 

3,072 



1,920 
168 
263 
156 
749 
405 

5,502 



3,271 



301 

104 

1,025 

1,428 



443 
1,480 



1,298 
177 
149 



354 
517 
321 



See footnotes at end of table. 



SYNIHETIC ORGANIC CHEMICALS, 1966 
TABLE 8A. --Benzenoid dyes.- U.S. production and sales, i 966- -Continued 



Eye 



Production 



AZOIC DYES AND COMPONENTS— Continued 



(Fast Col 



sj— Continued 



Azoic Dlazo Component 13, base 

Azoic Dlazo Component 32, base 

Azoic Diazo Component 48, base 

All other azoic diazo components, bases- 



(Fa: 



Color Sal 



Salt 



Total— 

Azoic Diazo Component 1, salt 

Azoic Dlazo Component 2, salt 

Azoic Diazo Component 3, salt 

Azoic Diazo Component 5, salt 

Azoic Dlazo Component 6, salt 

Azoic Diazo Component 8, salt 

Azoic Diazo Component 9, salt 

Azoic Dlazo Component 10, salt 

Azoic Dlazo Component 12, salt 

Azoic Dlazo Component 13, salt 

Azoic Diazo Component 28, salt 

Azoic Diazo Component 36, salt 

Azoic Diazo Coniponent 44, salt 

Azoic Diazo Component 48, salt 

Azoic Diazo Component 49, salt 

All other azoic diazo congjonents, salts- 

Azoic Coupling Componen 
(Naphthol ,4S and Deriiati 

Total 

Azoic Coupling Component 2 

Azoic Coupling Component 3 

Azoic Coupling Component 4 

Azoic Coupling Component 5 

Azoic Coupling Component 7 

Azoic Coupling Component 11 

Azoic Coupling Component 14 

Azoic Coupling Component 17 

Azoic Coupling Component 18 

Azoic Coupling Component 19 

Azoic Coupling Component 20 

Azoic Coupling Component 21 

Azoic Coupling Component 24 

Azoic Coupling Component 29 

Azoic Coupling Component 43 

All other azoic coupling components 

BASIC DYES 

Total — 

Basic yellow dyes, total 

Basic Yellow 2 

Basic Yellow 11 - 

Basic Yellow 13 - - 

All other— - 

Basic orange dyes, total 

Basic Orange 1 

Basic Orange 2 

See footnotes at end of table. 





J, (AW 


s 


di.llari. 


380 


472 


261 


463 


35 


64 


256 


584 



92 


87 


112 


23 


8 


11 


294 


294 


188 


3U 


331 


381 


40 


51 


58 


117 


132 


135 


267 


251 


163 


88 


82 


117 


80 


67 


74 


257 


298 


220 


344 


344 


404 




41 


69 




8 


13 




10 


13 


70 


55 


175 


453 


342 


543 



6,669 



1,027 

2,184 

603 

2,855 

2.657 



TABLE 8A. --Benzenoid dyes : U.S. production and sales , 7966- -Continued 



BASIC DYES— Continued 



Basic orange dyes--Continued 

Basic Orange 21 

All other— — - 

Basic red dyes, total 

Basic Red 14 

All other 

Basic violet dyes, total 

Basic Violet 1 

Basic Violet 4 -- 

Basic Violet 16 

All other 

Basic blue dyes, total 

Basic Blue 1 

Basic Blue 5 

Basic Blue 7 

Basic Blue 9 

Basic Blue 26 

All other 

Basic Green 1 

Basic Green 4 

Basic Brown 1 

Basic Brown 4 

All other basic dyes 

DIRECT DYES 

Total 

Direct yellow dyes, total 

Direct Yellow A 

Direct Yellow 5 - 

Direct Yellow 6 — — 

Direct Yellow 11 

Direct Yellow 12 

Direct Yellow 26— - 

Direct Yellow 28 

Direct Yellow 29 

Direct Yellow 44 - - 

Direct Yellow 50 

Direct Yellow 84 - 

Direct Yellow 105 

Direct Yellow 106 

All other 

Direct orange dyes, total 

Direct Orange 1 

Direct Orange 8 

Direct Orange 15 

Direct Orange 26 

Direct Orange 29 

Direct Orange 34 

Direct Orange 37 

Direct Orange 39 

Direct Orange 72 

Direct Orange 73 

Direct Orange 81 

Direct Orange 102 

All other 



112 
1,190 



936 
3,036 



8,217 



925 
415 
11 
287 



225 

877 

2,580 

2,206 



1,033 
2,957 

5,922 

1,129 

112 

377 

4,304 

4,428 



259 

1,562 

330 



909 
477 

1,280 
993 

1,047 
24 
537 
UO 
908 
936 
525 
544 

1,482 

3,695 

5,142 



131 
319 
702 
364 
261 
560 
1,662 



See footnotes at end of table. 



20 



SYNTHETIC ORGANIC CHEMICALS, 1966 
TABLE BA.--Bemenoid dyes : U.S. production and sales , i566--Continued 



Production 



DIRECT DYES— Continued 

Direct red dyes, total 

Direct Red 1 

Direct Red 2 

Direct Red 4 

Direct Red 10 - - 

Direct Red 13 - 

Direct Red 16 - - 

Direct Red 23 - - 

Direct Red 2A - 

Direct Red 26 - 

Direct Red 28 — 

Direct Red 31 

Direct Red 37 — 

Direct Red 39 - 

Direct Red 72— - 

Direct Red 75 

Direct Red 79— - 

Direct Red 80 

Direct Red 81 

Direct Red 83-~ — 

Direct Red 84— 

Direct Red 122 

Direct Red 149 — 

Direct Red 153 

All other— - - 

Direct violet dyes, total 

Direct Violet 1 

Direct Violet 9— — 

All other 

Direct blue dyes, total 

Direct Blue 1 

Direct Blue 2 

Direct Blue 6 

Direct Blue 8 

Direct Blue 15 

Direct Blue 22 

Direct Blue 24 

Direct Blue 25 

Direct Blue 67- - - — 

Direct Blue 76 

Direct Blue 78 

Direct Blue 80 

Direct Blue 86 

Direct Blue 98 

Direct Blue 120 and 120A 

Direct Blue 126 

All other 

Direct green dyes, total 

Direct Green 1 

Direct Green 6 

Direct Green 8 

Direct Green 12 

All other— 

Direct brown dyes, total 

Direct Brown 1 

Direct Brown lA 

Direct Brown 2 

Direct Brown 6 

Direct Brown 31 

Direct Brown 74 

Direct Brown 95 



pounds 

4,406 

221- 

351 
33 



437 

1,821 

555 



595 
1,1A3 
159 
313 
292 
1,882 

1,526 



608 
2,046 



4,376 
221 
379 
33 



21 
193 
130 

7,650 
404 

1,753 
547 
48 



24 



469 
146 
535 

1,054 
162 
268 
233 

1,807 

1,414 



2,061 



9,566 



358 

82 

1,586 



108 
864 
404 
817 

1,608 
283 
580 
691 

3,167 

3,305 
366 
588 

54 



TS7" 
137 
337 
118 
AM 
111 
722 



See footnotes at end of table. 



DYES 
TABLE 8A. --Benzenoid dyes.- U.S; production and sales , i966- -Continued 



Production 



Quantity Value 



DIRECT DYES— Continued 

Direct brown dyes--Continued 

Direct Brown 111 

Direct Brown 15^ 

All other - - 

Direct black dyes, total 

Direct Black A— - 

Direct Black 9 - - 

Direct Black 19 - — 

Direct Black 22 - 

Direct Black 38 

Direct Black 51 — 

Direct Black 80 — 

All other - 

DISPERSE DYES 

Total - 

Disperse yellow dyes, total 

Disperse Yellow 3 

Disperse Yellow 5 

Disperse Yellow 23 

Disperse Yellow 33— 

Disperse Yellow 34 

Disperse Yellow 42 

All other 

Disperse orange dyes, total 

Disperse Orange 3 

Disperse Orange 5 

Disperse Orange 17 

All other - 

Disperse red dyes, total 

Disperse Red 1 

Disperse Red 5 

Disperse Red 11 

Disperse Red 13 

Disperse Red 15 

Disperse Red 17 

Disperse Red 60 

All other 

Disperse violet dyes, total 

Disperse Violet 1 

Disperse Violet 4 

Disperse Violet 27— 

All other 

Disperse blue dyes, total 

Disperse Blue 1 

Disperse Blue 3 

Disperse Blue 7 

Disperse Blue 64 

All other 

Disperse black dyes, total 

Disperse Black 1 

Disperse Black 9 

All other - 

All other disperse dyes 



375 
(A 

121 

766 
6,215 

101 
1,926 

798 



1,725 



6,768 



2A5 

1,833 

326 

131 

4,233 

1,839 

156 

1,279 

404 



10,501 



5,930 



2or 

1,779 
353 
105 

3,488 



U2 

1,716 

241 



702 
4,813 

252 
1,718 
1,860 



6,452 



2,386 
124 
260 
553 
393 
862 

1,874 

1,983 



193 

320 

170 

1,300 

6,947 



356 
108 
225 
36 
304 
171 
339 
5,408 

939 



18,501 



768 
2,848 
2,473 

302 
12,110 

2,683 
25D1 

2,433 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1966 
TABLE 8A. —Bemenoid dyes.- U.S. production and sales, i566--Continued 



Dye 



Production 



FIBER-REACTIVE OTES 

Fiber-reactive dyes, total 

Reactive blue dyes 

All other reactive dyes 

FLUORESCENT BRIGHTENING AGENTS 
Total 

Fluorescent Brightening Agent 28 

All other fluorescent brightening agents 

FOOD, DRUG, AND COSMETIC COLORS 
Total 

Food, Drug, and Cosmetic Dyes 

Total 

rC&C Blue No. 1 - - 

FD&C Blue No. 2 - 

FDScC Red No. 2 - 

FD&C Red No. 3 

FDScC Red No. 4 - - 

FD&C Yellow No. 5 - 

FDSrC Yellow No. 6 

All other food, drug, and cosmetic dyes 



Drug and Cosme t i 
and Cos 



and External Drag 
eticDyes 



Total - 

nScC Orange No. 4 

E&C Red No. 7 

E&C Red No. 19 

mC Red No. 21 

E&C Red No. 36 

All other drug and cosmetic and external drug and cosmetic 
dyes 

MDHDANT DYES 

Total 

Mordant yellow dyes, total 

Mordant Yellow 8- 

Mordant Yellow 16 

All other - 

Mordant orange dyes, total 

Mordant Orange 1 

All other 

Mordant red dyes, total 

Mordant Red 7 

Mordant Red 9 

All other 

Mordant blue dyes, total 

Mordant Blue 1 

All other 



1 . 000 

1,909 



612 
1,297 



1,240 
21,972 



1.000 
pounds 
1^ 



1,549 
19,280 



3,352 
4,554 



2,364 
38,339 



55 


65 


683 


28 


24 


243 


1,090 


958 


2,543 


138 


125 


1,655 




17 


81 


773 


783 


2,291 


867 


772 


2,024 


181 


115 


585 



See footnotes at end of table. 



DYES 
TABLE 8A. --Beruenoid dyes: U.S. production and sales , 1966 --Continued 



MORDANT DYES— Continued 



Mardant brown dyes, total 

MDrdant Brown 1 

Mordant Brown 33— — - 

Mordant Brown 40 

All other 

Mordant black dyes, total 

Ktordant Black 3 

Mordant Black 11 

Mordant Black 13— - 

Mordant Black 17—- — 

Ifcrdant Black 38 

All other - 

All other mordant dyes 

SOLVENT DYES 

Total 

Solvent yellow dyes, total 

Solvent Yellow 2 

Solvent Yellow 3 

Solvent Yellow lA 

All other - - 

Solvent orange dyes, total 

Solvent Orange 3 

Solvent Orange 7 

All other— 

Solvent red dyes, total 

Solvent Red 24 - 

Solvent Red 26 

Solvent Red 49 

All other 

Solvent violet dyes, total 

Solvent Violet 8 — 

All other - — 

Solvent green dyes, total 

Solvent Green 3 

All other - - 

Solvent brown dyes, total 

Solvent Brown 12 

All other 

All other solvent dyes 

SULFUR DYES 2 

Total - 

Sulf\ir Red 6- 

Sulfur Blue 7 — 

Suli\ir Blue 11 - — 

Sulfur Black 1 - 

All other sulfur dyes 



2,112 

41 
656 



62 
6,747 



1,638 

18,180 



2,529 
26 
1,666 
50 
557 
9 
221 



22 



3,180 



590 
1,358 



10 
1,585 
17,503 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1966 
■ Benzenoid dyes: U.S. production and sales, iS66- -Continued 



Production 



VAT DYES 

Total 

Vat yellow dyes, total 

Vat Yellow 2, 8-1/2^6 

Vat Yellow 4, 12-1/2^- 

Solubllized Vat Yellow A 

All other 

Vat orange dyes, total 

Vat Orange 1, 20^6 — 

Solubilized Vat Orange 1, 2bf, 

Vat Orange 2, 12^ 

Vat Orange 3, 13-1/2^ 

Vat Orange 5, lOit- -- 

Solubilized Vat Orange 5, 30ifc---- 

Vat Orange 7, lilt- 

Vat Orange 9, 12^6 

Vat Orange 15, 10^ 

All other 

Vat red dyes, total 

Vat Red 1, 13^« 

Vat Red 10 

Vat Red 13, ll^fr- 

Vat Red 15, 10* 

Vat Red 32, 20^6- 

All other 

Vat violet dyes, total--- 

Vat Violet 1, lli^ 

Vat Violet 2, 20*- 

Vat Violet 9, 12* - 

Vat Violet 13, 6-1/4* 

Vat Violet 17 — 

All other 

Vat blue dyes, total- 

Vat Blue 6, 8-1/3* 

Vat Blue 16 — 

Vat Blue 18, 13*- 

Vat Blue 20, lA*- 

All other --- 

Vat green dyes, total 

Vat Green 1, 6* 

Vat Qreen 3, 10*-- 

Solubilized Vat Green 3, 26* 

Vat Green 8, 8-1/2*-- 

Vat Green 9, 12-1/2* 

All other --- 

Vat brown dyes, total 

Vat Brown 1, 11* 

Vat Brown 3, 11*- - 

Vat Brown 5, 13*- — 

All other 

Vat black dyes, total 

Vat Black 9, 16*^ 

Vat Black 25, 12-1/2*- ■ 

Vat Black 27, 12-1/2*- ■ 

All other 

All other dyes-' 



1 . 000 
57,<i56 



929 
1,088 
12,652 

U,858 



i,052 
5,369 
8 
3,549 
1,371 
509 

4,279 



5,937 
1,523 
3,187 



X516 
807 



16,808 



941 
1,004 
11,645 

13,677 



3,916 

5,002 

11 

2,954 



2,131 
10,526 



402 
1,153 
2,237 



1,207 
1.839 



3,305 



2,586 
3,675 
73 
2,325 
1,267 
379 



1,031 
2,152 



4,431 
1,670 
3,111 



''■ Calculated from rounded figures. 

^ Production and sales quantities of C.I. Leuco Sulfur and C.I. Solubilized Sulfur dyes are reported in terms of 
the usual commercial concentration of the C.I. Sulfur dyes. 

•' Includes oxidation bases, ingrain dyes, and miscellaneous dyes. Statistics for these groups of dyes may not be 
published separately because publication would disclose information received in confidence. 



DYES 25 

Table 9 summarizes production and sales of dyes in 1966, by class of application. Four 
application classes of dyes accounted for approximately two-thirds of all the dyes produced. Vat 
dyes accounted for 26. 2 percent of the total; direct dyes, for 17. percent; and fluorescent 
brighteners and acid dyes, each for 10. 6 percent of the above classes, the output of vat dyes 
remained about the same in 1966 as in 1965. The output of fluorescent brighteners was 19. 5 per- 
cent larger in 1966 than in 1965; that of acid dyes was 13. 7 percent larger; and direct dyes was 
3. 5 percent larger. 

Of the remaining classes, the output of the fiber-reactive dyes was 1. 9 million pounds in 
1966, or 20. 4 percent more than the 1. 6 million pounds produced in 1965. Production of food, 
drug, and cosmetic colors was 15. 1 percent larger in 1966 than in 1965; solvent dyes, 9. 5 per- 
cent larger; and sulfur dyes, 7. percent larger. On the other hand, the output of mordant dyes 
was 9.6 percent smaller in 1966 than in 1965; and that of the azoic dyes and components, 2.9 
percent smaller. 

Table 10 shows production and sales of dyes, by chemical class. In 1966, three chemical 
classes of dyes accounted for two-thirds of all the dyes produced: Azo dyes accounted for 31.8 
percent of the total; anthraquinone dyes, for 24. 7 percent; and stilbene dyes, for 11.2 percent. 
The output of each of these three classes was larger in 1966 than in 1965: Stilbene dyes were 
15. percent larger; anthraquinone dyes, 13. 7 percent larger; and azo dyes, 4. 8 percent larger. 
Of the remaining chemical classes for which statistics are published, the output of sulfur dyes 
was 7. percent larger in 1966 than in 1965, and that of triarylmethane dyes was 18. 6 percent 
larger. On the other hand, the output of phthalocyanine dyes was 18. 8 percent smaller in 1966 
than in 1965, that of indigoid dyes, 8. 5 percent smaller; and azoic dyes, 3. 7 percent smaller. 



Benzenoid dyes: U.S. production and sales, by class of application, 1966 



Class of application 



Production 



Total— 

Icld - 

^zolo dyes and conjionents: 

Azoic compositions 

Azoic dlazo components, bases (Fast color bases) 

Azoic dlazo components, salts (Fast color salts) 

Azoic coupling components (Naphthol AS and derivatives )- 

Basic 

Direct 

Fiber-reactive 

Fluorescent brightening agents 

Food, drug, and cosmetic colors 

ilordant 

Solvent 

Sulfur^ 

Vat - - 

Ml other^— - - - 



i . 000 
pounds 
20^,135 



23, 19"^ 

2,376 
1,^93 

3,071 
11,136 
37,343 
16,696 

1,909 
23,212 

3,363 

4,288 
10,772 
19,959 
57,456 
482 



20,410 

2,204 
1,334 
2,401 
2,478 
10,420 
36,733 
14,849 
1,899 
20,829 
3,109 
3,509 
9,827 
19,236 
54,431 
466 



43,762 

4,473 
2,185 
2,676 
4,978 
26,674 
56,920 
38,060 
7,906 
40,703 
11,474 
5,285 
16,685 
11,034 
57,875 
763 



pound 
$1.62 



2.03 
1.64 
1.11 
2.01 
2.56 
1.55 
2.56 



Calculated from rounded figures. 

^ Production and sales quantities of C.I. Leuoo Sulfur and C.I. Solubillzed Sulfur dyes are reported in terms of 
the usual commercial concentration of the C.I. Sulfur dyes. 

^ Includes oxidation bases, ingrain dyes, and miscellaneous dyes. Statistics for these groups of dyes may not be 
published separately becauses publication would disclose information received in confidence. 



26 



SYNTHETIC ORGANIC CHEMICALS, 1966 
TABLE 10. -- Benzenoid dyes: U.S. production and sales, by chemical class, 1966 



Chemical class 



Total 

Anthraqulnone — 

Azo, total 

Monoazo 

Dlsazo 

Trisazo 

Polyazo 

Not specified 

Azoic 

Cyanine 

Indigold 

Ketone tmine 

Me thine 

Nitro 

Oxazine 

Phthalocyanine- 

Qulnoline 

Stllbene 

Sulfur^ — 

Thiazole 

Triarylmethane- 

Xanthene 

All other^ 



1 . 000 
pounds 
219,19^ 



69,709 



25, 6U 
20,070 
13,7<19 
2,720 
7,356 

9,39-; 

5U 
5,251 

502 
1,281 
1,^29 

252 
1,783 

523 
24,518 
19,959 

586 
7,936 
1,874 
19,456 



1,000 
dollars 
331,453 



66,277 



23,624 
19,295 
13,341 
2,935 
7,082 

8,430 

505 

5,604 



176 

1,787 

597 

21,760 

19,236 

549 

6,592 

911 

17,564 



121,299 



49,679 
35,284 
15,253 
5,002 
16,081 

14,344 
1,636 
3,590 
1,051 
4,590 
2,519 
789 
4,660 
1,934 

35,143 

11,034 
1,176 

15,037 
4,585 

22,565 



1.83 



2.10 
1.83 
1.14 
1.70 
2.27 

1.70 
3.24 

.64 
2.08 
3.46 
1.83 
4.48 
2.61 
3.24 
1.62 

.57 
2.14 
2.28 
5.03 



Calculated from roimded figures. 

^ Production and sales quantities of C.I. Leuco Sulfur and C.I. Solubilized Sulfur dyes are reported in terms of 
the usual commercial concentration of the C.I. Sulfur dyes. 

•' Includes acrldine, aminoketone, azlne, coumarin, hydroxyketone , nitroso, oxidation bases, thiazine, vat sulfur, 
and miscellaneous dyes. Statistics for these groups of dyes may not be published separately because publication would 
disclose Information received in confidence. 

Pigments 



As the terms are used in this report, synthetic organic pigments are toners and lakes derived 
in whole or in part from benzenoid chemicals and colors. They are used in paints ancj related 
products, in printing inks, and in plastics and resin materials. 

Statistics on production and sales of all benzenoid pigments in 1966 are given in table HA . 
Statistics on sales of a few selected pigments by commercial forms (dry full-strength form, dry 
extended form, dry dispersions, aqueous dispersions, and flushed colors) are given in table 12. 
Prior to 1961, statistics for toners included the quantities and values of extenders and diluents. 
Beginning in 1961, data were collected for both the full-strength and extended toners on a full- 
strength-toner-content basis. Individual toners and lakes are identified in this report by the 
names used in the second edition of the Colour Index. 

Total production of benzenoid pigments in 1966 was 51. 1 million pounds--6.4 percent more 
than the 48. million pounds produced in 1965 and 16. 1 percent more than the 44. 1 million pounds 
produced in 1964. Total sales of benzenoid pigments in 1966 amounted to 43. 3 million pounds, 
valued at $107. 6 million, compared with 38. million pounds, valued at $93. 6 million, in 1965 
and 35. 1 million pounds, valued at $84. 1 million, in 1964. In terms of quantity, sales of ben- 
zenoid pigments in 1966 were 13. 9 percent larger than in 1965 and 23. 5 percent larger than in 
1964; in terms of value, sales in 1966 were 14. 9 percent larger than in 1965 and 27. 9 percent 
larger than in 1964. 

Production of toners in 1966 amounted to 46. 6 million pounds--6. 7 percent more than the 
43. 7 million pounds reported for 1965. Sales in 1966 were 39. 1 million pounds, valued at $103. 6 
million, compared with 34. 1 million pounds, valued at $89.9 million, in 1965. Sales in 1966 
were thus 14. 7 percent larger than those in 1965 in terms of quantity, and 15. 3 percent larger in 
terms of value. The individual toners listed in the report which were produced in the largest 
quantities in 1966 were Pigment Blue 15, alpha form, 5. million pounds; Pigment Green 7, 4. 1 
million pounds; Pigment Yellow 12, 4. 1 million pounds; Pigment Red 49, barium toner, 3.5 



-• See also table IIB, pt. in, which lists these products i 
of benzenoid pigments during the years 1965-66. 



identifies the manufacturers, and table 23 in the appendix, which shows imports 



PIGMENTS 



million pounds; Pigment Blue 19, 2. 7 million pounds; Pigment Blue 15, beta form, 2. 7 million 
pounds; and Pigment Red 48, 2. 5 million pounds. 

Production of lakes totaled 4. 5 million pounds in 1966--3. 5 percent more than the 4. 3 mil- 
lion pounds reported for 1965. Sales of lakes in 1966 amounted to 4. 2 million pounds, valued at 
$4. million, compared with sales in 1965 of 3. 9 million pounds, valued at $3. 8 million. Sales 
in 1966 were thus 7. 2 percent larger than those in 1965 in terms of quantity, and 5. 5 percent 
larger in terms of value. 

For each of 14 selected pigments, or groups of pigments, table 12 gives data on sales by 
commercial forms. Pigment Yellow 12, Pigment Red 90, and Pigment Blue 19 were sold princi- 
pally in the flushed form. The remaining 11 pigments, or groups of pigments, for which statistics 
are published were sold principally in the dry full-strength form. Statistics on sales by commer- 
cial forms could not be published for Pigment Red 49, sodium toner, or for Pigment Blue 24 
without revealing the operations of individual companies. 

TABLE llA.--BenzeTioid pigments.- U.S. production and sales , 1966 

[Listed below are all toners and lakes for which any reported data on production or sales may be published. (Leaders 
are used where the reported data are accepted in confidence and may not be published or where no data were re- 
ported.) Table ILB in pt. Ill lists all toners and lakes for which data on production or sales were reported and 
identifies the manufacturer of each] 



Production 



Grand total 

TONERS 

Total — 

Yellow toners, total 

Hansa yellows, total 

Pigment Yellow 1, C.I. 11 680—- 
Pigment Yellow 3, C.I. 11 710— 

Pigment Yellow 73 

Pigment Yellow 7-4, C.I. 11 741— 

Other Hansa yellows 

Benzidine yellows, total 

Pigment Yellow 12, C.I. 21 090— 
Pigment Yellow 13, C.I. 21 100— 
Pigment Yellow 14, C.I. 21 095— 
Pigment Yellow 17, C.I. 21 105— 

Other benzidine yellows 

All other 

Orange toners, total 

Pigment Orange 2, C.I. 12 060 

Pigment Orange 5, C.I. 12 075 

Pigment Orange 13, C.I. 21 110 

Pigment Orange 16, C.I. 21 160 

(Vat Orange 7), C.I. 71 105 

All other 

Red and violet toners, total 

Naphthol reds, total 

Pigment Red 2, C.I. 12 310 

Pigment Red 5, C.I. 12 490 

Pigment Red 13, C.I. 12 395 

Pigment Red 17, C.I. 12 390 

Pigment Red 18, C.I. 12 350 

Pigment Red 22, C.I. 12 315 

Pigment Red 23, C.I. 12 355 

Other naphthol reds 

Pigment Red 1, C.I. 12 070, dark— 
Pigment Red 1, C.I. 12 070, light - 

Pigment Red 3, C.I. 12 120 

See footnotes at end of table. 



257 

113 

134 

6,357 

4,117 

317 

1,409 

273 

241 

290 

830 
35 
248 
155 
222 



223 

217 

1,843 



2,410 
763 
252 

371 
1,024 
10,450 
5,138 

718 
2,866 

588 
1,140 
1,590 



55 
315 
481 
592 
239 
1,208 

44,621 

2,891 

121 

338 



246 
526 

1,447 
218 
215 

2,325 



pound 

$2.48 



2.76 

-"2752 

1.93 

2.29 

3.44 
2.98 
2.52 
2.16 
3.42 
2.46 
3.34 
5.0; 
12.14 

3.79 
1.49 
1.56 
3.29 
2.77 
21.73 
7.90 

2.37 
4.39 
2.63 
5.04 
5.00 
3.09 

' 2.96 
3.35 
6.05 
1.22 

1.20 
1.52 



28 SYNTHETIC ORGANIC CHEMICALS, 1966 

TABLE UA. —Bemenoid pigments.- U.S. production and sales, i 966- -Continued 



Pigment 



Production 



Sales 



TONERS— Continued 

Red and violet toners — Continued 

Pigment Red 4, C.I. 12 085 - -- 

Pigment Red 6, C.I. 12 090 - 

Pigment Red 38, C.I. 21 120 - - 

Pigment Red 48, C.I. 15 865 

Pigment Red 49, C.I. 15 630: 

Barium toner 

Calcium toner 

Sodium toner 

Pigment Red 52, C.I. 15 860 - - 

Pigment Red 53, C.I. 15 585, barium toner 

Pigment Red 54, C.I. 14 830, calcium toner 

Pigment Red 57, C.I. 15 850, calcium toner 

Pigment Red 63, C.I. 15 880— - 

Pigment Red 81, C.I. 45 160, PMA- 

Pigment Red 81, C.I. 45 160, PTA -- 

Pigment Red 90, C.I. 45 380 

Pigment Violet 1, C.I. 45 170, IMA - 

Pigment Violet 1, C.I. 45 170, PTA— 

Pigment Violet 3, C.I. 42 535, fugitive- 

Pigment Violet 3, C.I. 42 535, FMA- — - 

Pigment Violet 3, C.I. 42 535, PTA — - 

Pigment Violet 23 

All other 

Blue toners, total 

Pigment Blue 1, C.I. 42 595, PUA- 

Pigment Blue 1, C.I. 42 595, PTA- 

Figment Blue 2, C.I. 44 045, fugitive, MA, and PTA- 

Pigment Blue 9, C.I. 42 025, PTA- — 

Pigment Blue 14, C.I. 42 600, BJA- 

Pigment Blue 15, C.I. 74 160, alpha form 

Pigment Blue 15, C.I. 74 160, beta form 

Pigment Blue 19, C.I. 42 750A - 

Pigment Blue 22, C.I. 69 810 

Pigment Blue 25, C.I. 21 180 — 

All other - 

Green toners, total 

Pigment Green 1, C.I. 42 040, MA — 

Pigment Green 1, C.I. 42 040, PTA - 

Pigment Green 2, C.I. 42 040 and 49 005, PMA- 

Pigment Green 2, C.I. -42 040 and 49 005, PTA- 

Pigment Green 4, C.I. 42 000, FMA 

Pigment Green 4, C.I. 42 000, PTA- - 

Pigment Green 7, C.I. 74 260 - 

Pigment Green 8, C.I. 10 006 

Pigment Green 36, C.I. 74 265 

All other 

Brown toners, total 

Pigment Brown 3, C.I. 21 010, IMA- 

Pigment Brown 5, C.I. 15 800 

All other — - - 

Black toners 

LAKES 

Total 

Yellow lakes 



3,498 
1,454 
211 
1,309 
2,110 
59 
1,017 



1,507 
99 
63 



4,113 
220 
208 
219 

189 



00 


1,000 


ds 


dollars 


274 


386 


34 


53 


128 


571 


2,443 


4,500 


3,415 


3,331 


1,419 


1,442 


267 


273 


1,226 


1,836 


1,729 


2,223 


67 


153 


867 


1,290 


53 


100 


269 


1,649 


146 


894 


812 


1,508 


99 


293 


57 


379 


560 


815 


355 


1,054 


39 


174 


74 


1,412 


1,956 


14,636 



2,369 

2,637 

37 



35 

566 

11,159 

7,166 

6,196 

684 

' 1,153 



10,634 
240 
706 



See footnotes at end of table. 



PIGMENTS 



TABLE UK.— Bemenoid pigments: U.S. production and sales, i966— Continued 



LAKES— Continued 



Red lakes: 

Pigment Red 60, C.I. 16 105- 
■pigment Red 83, C.I. 58 000- 
(Aoid Red 26), C.I. 16 150— 



Violet lakes, total 

Pigment Violet 5, C.I. 58 055- 
All other 



Blue lakes: Pigment Blue 24, C.I. ^2 090- 



$1.76 
3.03 



■^ Calculated from rounded figures. 

^ Includes all brown, green, and orange lakes, "all othe 
production of Pigment Blue 24 and sales of yellow lakes. 



all other" black lakes. 



numbers shown in this report are the identifying numbers given in the second edition of 



Note.— The C.I. fCVW„„, Index 
the Colour Index. 

The abbreviations PMA and PTA stand for phosphonclybdic and phosphotungstic ( including phosphotungstomolybdic) 
acids, respectively. 



iispersions , and flushed colors, 1966 



Selected pigments by 



Quantity^ 



Pigment Yellow 12, C.I. 21 090, total— - 

Diy full-strength toner 

Dry extended toner, dry dispersions, aqueous dispersions-' and flushed 
color* 

Pigment Yellow 13, C.I. 21 100; Pigment Yellow K, C.I. 21 095; Pigment 

Yellow 17, C.I. 21 105; and other benzidine yellows, total 

Dry full-strength toner 

Dry extended toner and dry dispersions* 

Aqueous dispersions^ 

Flushed color 

Pigment Red 3, C.I. 12 120, total — 

Dry full-strength toner and dry extended toner* 

Aqueous dispersions-' 

Flushed color 

Pigment Red 48, C.I. 15 865, total 

Dry full-strength toner 

Dry extended toner and dry dispersions* 

Aqueous dispersions-* 

Flushed color 

Pigment Red 49, C.I. 15 630, barium toner, total- - 

Dry full-strength toner --- 

Dry extended toner and aqueous dispersions^ * 

Flushed color 

Pigment Red 49, C.I. 15 630, calcium toner, total - -- 

Dry full-strength toner and dry dispersions* 

Aqueous dispersions-* and flushed color' 

See footnotes at end of table. 



pounds 
2,378 
705" 

1,678 



1,230 
40 
315 



3,735 
104 
851 
570 



$2.25 
2.09 

2.31 



3704- 

2.60 
2.70 
3.00 



1.84 

"TTST 

2.09 
2.34 



1.00 
-T97- 
1.18 
1.09 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 12. — U.S. sales of selected dry full-strength colors dry extended colors dry dispersions , aqueous 
dispersions, and flushed colors, i566— Continued 



Selected pigments by 



Quantity Value 



Pigment Red -49, C.I. 15 630, sodium toners- 



Pigment Red 53, C.I. 15 585, barium toner, total 

Dry full-strength toner, dry extended toner, and dry dispersions* 
Aqueous dispersions"' and flushed color* 



Pigment Red 90, C.I. 45 380, total 

Dry full-strength toner and dry extended toner* 
Dry dispersions and flushed color* 



Pigment Violet 3, C.I. A2 535, fugitive, total- -- 
Dry full-strength toner and dry extended toner* 
Flushed color 



Pigment Violet 3, C.I. A2 535, permanent (PMA and PTA), total- 
Dry fuli-strength toner 

Dry extended toner, dry dispersions and aqueous dispersions-' 
Flushed color 



Pigment Blue 15, C.I. 7i 160, 

Dry full-strength toner 

Dry extended toner 

Dry dispersions 

Aqueous dispersions^ 

Flushed color 



alpha form, total- 



Pigment Blue 15, C.I. V'i 160, beta form, total 

Dry full-strength toner 

Dry extended toner, dry dispersions and aqueous dispersions-' 
Flushed color 



Pigment Blue 19, C.I. 42 750A, total 

Dry full-strength toner and dry extended toner*- 
Aqueous dispersions-' and flushed color* 



Pigment Blue 24, C.I. 42 090*- 



Pigment Green 7, C.I. 74, 260, total- 
Dry full-strength toner 

Dry extended toner 

Dry dispersions 

Aqueous dispersions-' • 

Flushed color 



1.000 
pounds 
267 



1,078 
814 
477 



1,958 
3,440 



1,607 
342 
127 

1,190 

174 



2,260 



1,516 

815 



11.489 



4,429 
2,839 

397 
2,921 

903 



3,391 
2,357 
1,418 



605 
5,591 



2,291 
10,854 



543 



1.98 

2.07 
1.97 



1.46 
1.50 
1.40 



3.14 
3.12 

4.02 



2.78 
2.52 
3.30 
3.68 
2.51 
3.76 



3.02 
3.15 
2.90 
2.97 



2.35 
2.44 
2.34 



3.16 
3.21 
3.75 
4.28 



Quantity of the various commercial forms is given in terms of dry full-strength toner (or dry lake) content. 
^ Calculated from rounded figures. 
^ Includes presscake. 

* Separate data on these commercial forms may not be published without revealing the operations of Individual 
companies . 

Note. — The C.I. {Colour Index) numbers shown in this report are the identifying numbers given In the second 
edition of the Colour Index. 

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstio (including phosphotungstomolybdic ) 
acids, respectively. 



MEDICINAl CHEMICALS 31 

Medicinal Chemicals 

Medicinal chemicals include the medicinal and feed grades of all organic chemicals having 
therapeutic value, whether obtained by chemical synthesis, by fermentation, by extraction from 
naturally occurring plant or animal substances, or by refining a technical grade product. They 
include antibiotics and other anti-infective agents, antihistamines, autonomic drugs, cardio- 
vascular agents, central nervous system depressants and stimulants, hormones and synthetic 
substitutes, vitamins, and other therapeutic agents for human or veterinary use and for animal 
feed supplements. Statistics on production and sales of medicinal chemicals grouped by pharma- 
cological class are given in table 1 3A . 

The statistics shown are for bulk chemicals only; finished pharmaceutical preparations and 
products put up in pills, capsules, tablets, or other measured doses are excluded.^ The dif- 
ference between production and sales reflects inventory changes, processing losses, and cap- 
tive consumption of medicinal chemicals processed into ethical and proprietary pharmaceutical 
products by the primary manufacturer. In some instances, the difference may also include 
quantities of medicinal grade products used as intermediates, e.g., penicillin G salts used as 
intermediates in the manufacture of the semi-synthetic penicillins. All quantities are given in 
terms of 100-percent content of the pure bulk drug. 

Sales of antibiotics in 1965 and 1966 cannot be compared with those for earlier years 
because the reporting instructions were changed in 1965 to exclude sales of antibiotics in mix- 
tures, formulations, capsules, pills, tablets, etc. For the years prior to 1965, sales data for 
antibiotics represented all sales by the primary producers, including finished pharmaceutical 
preparations. 

Total U.S. production of bulk medicinal chemicals in 1966 amounted to 185 million pounds, 
or 16. 3 percent more than the 160 million pounds produced in 1965, and 28. 7 percent more than 
the 144 million pounds produced in 1964. Total sales of bulk medicinal chemicals in 1966 
amounted to 136 million pounds, valued at $398 million, compared with sales in 1965 or 129 
million pounds, valued at $362 million. Sales in 1966 were thus 5.7 percent greater than in 
1965, in terms of quantity, and 10.0 percent greater, in terms of value. 

Production of the more important groups of medicinal chemicals in 1966 was as follows: 
Antibiotics, 9.7 million pounds (29. 5 percent larger than in 1965), of which 5.4 million pounds 
was for medicinal use and 4. 2 million pounds was for other uses; anti-infective agents other 
than antibiotics, 33. 5 million pounds (22.0 percent larger than in 1965); central depressants 
and stimulants, 48. 3 million pounds (12. 9 percent larger); and vitamins, 17.6 million pounds 
(7. 9 percent larger). Production of some of the more important individual products listed in 
the table was as follows: Choline chloride, 36. 2 million pounds (16. 2 percent larger than in 
1965); aspirin, 34. 1 million pounds (17. 3 percent larger); methionine and its hydroxy analogue, 
1 3. 9 rnillion pounds ( 33. 7 percent larger); salicylic acid, 1 1 . 4 million pounds (15. 5 percent 
larger); piperazine base and salts, 8.7 million pounds (33. 3 percent larger); ascorbic acid, 
7.6 million pounds (4.2 percent larger); anti-infective sulfonamides, 5.4 million pounds (15.3 
percent larger); penicillins, 1,676 trillion units (24.8 percent larger); tetracyclines, 1.7 
million kilograms (44.2 percent larger); vitamin A, 944 trillion units (57.7 percent larger); 
and vitamin E, 277 billion units. 



See also table 13B, pt. 111. which lists these products and identifies the manufacturers, and table 23 in the appendix, which shows 
imports of benzenoid medicinal chemicals and pharmaceuticals during the years 19b5-66. 

5 Complementary statistics on the dollar value of manufacturers' shipments of finished pharmaceutical preparations, except biologicals, 
are published annually by the U.S. Department of Commerce, Bureau of the Census, in Current Industrial Reporu,- Series MA-M28G. Many 
pharmaceutical manufacturers who report to the Bureau of the Census are excluded from the Tariff Commission report because they are not 
primary producers of medicinal chemicals, that is, they do not themselves produce the bulk drugs which go into their pharmaceutical prod- 
ucts but purchase their drug requirements from domestic or foreign producers. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 13A. --Medicinal chemicals: U.S. production and sales , 1966 

[Listed below are all synthetic organic medicinal chemicals for which any reported data on production or sales may be 
published. (Leaders are used where the reported data are accepted in confidence and may not be published or where 
no data were reported. ) Table 13B in pt. Ill lists all medicinal chemicals for which data on production or sales 
were reported and identifies the manufacturer of each] 



Production^ 



Sales ^ 



1.000 
pounds 



Grand total 

Acyclic 

Benzenoid^ 

Cyclic nonbenzenoid* 

Antibiotics, total' 

For medicinal use, total 

Antifungal and antitubercular antibiotics 

Bacitracin 

Penicillins, total - • 

Penicillin G, potassium 

Penicillin G, procaine 

All other— - ■ 

Other antibiotics for medicinal use 

For other uses, total 

Bacitracin 

Penicillin G salts^ - 

All other - — — 

Anticoagulants, total 

Sodium heparin 

All other - - — — 

Antihistamines, total 

Antinauseants 

Chlorpheniramine male ate 

Pheniramine maleate 

All other - 

Anti-infective agents, total 

Arsenic, bismuth, and mercury compounds 

Caprylates and undeoylenates 

p-Hydroxybenzoic acid esters, total 

Methylparaben 

All other 

5-Nitrofurane, -imidazole, and -thiazole derivatives 

Phenolic antiseptics and disinfectants 

Piperazine base and salts, total 

Piperazine 

All other 

Quinoline derivatives, total 

Diiodohydroxyquln 

Oxyqulnollne benzoate 

Oxyquinoline sulfate 

All other — 

Sulfonamides 

Groups listed above for which separate sales data may not 

be shown 

Other anti-infective agents, total 

Anthelmintic, antifungal, antiprotozoan, and antiviral 

agents 

Urinary antiseptics 

All other 

Antineoplastic agents and local anesthetics, total 

Lidocaine 

All other- - - - 

See footnotes at end of table. 



69,305 
97,891 



9,652 



5,445 
947 
L2 

2,092 
813 
754 
525 

2,394 

4,207 
179 
868 

3,160 

10 



33,532 



4,230 

523 

610 

397 

213 

602 

334 

8,681 

4,033 

4,648 

934 

28 

7 

899 

5,450 



8,677 

722 

2,769 



1,000 
pounds 
136,463 



1.000 
dollars 
398,408 



59,621 
63,666 
13,176 



878 

458 

420 

795 

2,378 



2,762 
9,925 

8,309 
673 
943 



41,762 
269,815 
86,831 
99,263 



62,388 

10,233 

913 

16,078 

4,024 
12,054 
35,164 
36,875 
3,316 
5,688 
27,871 



5,402 



235 

298 

4,869 

82,973 



565 

1,141 

718 

423 

493 
4,855 
1,408 
3,447 

49 



10,701 
58,396 

55,428 
1,189 
1,779 



MEDICINAL CHEMICALS 
TABLE \Zk. —Medicinal chemicals: U.S. production and sales , 7 966 --Continued 



Chemical 



Production-' 



SeleB"- 



Autonomic drugs, total 

Parasympatholytic (anticholinergic) agents: 

Homatropine methylbromide 

Oiatemary ammonium compounds (except tropane 
derivatives) 

Sympathomimetic (adrenergic) agents, total 

Isoproterenol salts 

Phenylephrine 

Phenylpropanolamine hydrochloride 

All other 

Other autonomic drugs 

Cardiovascular agents, total 

Cardiac drugs 

Rauwolfia and veratrum alkaloids 

Other cardiovascular agents 

Central depressants and stimulants, total 

Amphetamines, total 

Dextroamphetamine sulfate 

Methamphetamine base and hydrochloride 

All other-- 

Anticonvulsants, hypnotics, and sedatives (except 

barbiturates) 

Antidepressants 

Barbiturates, total 

Butabarbital, sodium 

Phenobarbital, sodium 

All other— 

Hydrocodone bitartrate 

Salicylates, total 

Aspirin 

All other - 

Skeletal muscle relaxants 

Tranquilizers, total 

Ifeprobamate 

Phenothiazine derivatives 

Other tranquilizers' 

Other central depressants and stimulants-'--'- 

Dermatologieal agents, total 

Allantoin 

Bismuth subgallate 

Salicylic acid- -. 

All other 

Expectorants and mucolytic agents, total 

Gualacol and its derivatives 

All other - 

Gastrointestinal agents, total 

Choleretics and hydrocholeretios 

Choline salts, total 

Choline chloride (all grades)— 

All other- - 

Methionine and its hydroxy analogue 

Other gastrointestinal agents 

Hormones and synthetic substitutes, total 

Anti-thyroid agents 

Estrogens 

Prednisone 

Synthetic hypoglycemic agents 

Other hormones and synthetic substitutes 

See footnotes at end of table. 



46 

7 

92A 

1 

37,553 

34,114 

3,439 

136 

1,583 

1,206 



12,833 



27 
11,400 
1,384 



52,002 



137 
36,537 
36, 198 
339 
13,904 
1,424 

1,503 



3 

1,298 



468 
32,726 



110 
1,314 
1,244 



1,51A 
1,319 



48, 835 



35,225 
34,955 
270 
:i2,268 
1,342 

369 



1,000 
dollars 

7,813 



21 

245 

1,812 

2,554 

1,923 

14,460 



35 

274 

U,151 

57,891 



"3^5" 



(10) 

643 

5,813 

3,163 

1,694 

956 

48, 622 

4,463 



1,568 
551 



20,049 



5,845 
5,546 
299 
11,164 
3,040 

19,747 



34 SYNTHETIC ORGANIC CHFMICALS, 1966 

TABLE 13A. --Medicinal chemicals: U.S. production and sales , 1966- -Continued 



Production 



Sales ^ 



Renal-acting and edema-reducing agents, total 

Mercurial diuretics 

Theobromine and theophylline derivatives, total 

Aminophylline 

All other 

Other renal-acting and edema-reducing agents 

Therapeutic nutrients, total 

Amino acids and salts, total 

Glutamic acid 

Potassium glutamate 

All other — - 

Calcium gluconate 

Other therapeutic nutrients 

Vitamins, total 

Vitamin A alcohol and esters, total-'-^ 

Vitamin A palmitate (feed grade) 

All other - 

Vitamin B-complex, total 

Cyanocobalamin (except U.S.P. crystalline) ^^- 

Niacin (all grades) 

Niacinamide 

Pantothenic acid and derivatives, total 

Calcium pantothenate (racemic) (feed grade) 

All other 

Riboflavin (all grades) 

Other B-complex vitamins 

Vitamin C, total 

Ascorbic acid 

All other — 

Vitamin E'^^ - - — 

Vitamin K— 

Other vitamins 

Miscellaneous medicinal chemicals'"-^ 



277 
2,609 



2,756 



1,404 
554 
490 



640 

376 

6,276 

2 

2,206 

1,046 

1,523 

1,135 

388 

705 

794 

9,600 

7,581 

2,019 

507 

156 

27 



560 

196 

4,918 

1,787 

952 

940 

607 

333 

590 

649 

5,872 

4,543 

1,329 

406 

72 

18 



11,344 
7,473 
28,584 

2,106 
1,854 
3,251 
1,765 
1,486 
6,176 
15,197 
12,201 
9,163 
3,038 
7,908 
981 
2,261 

5,108 



pound 
$16.66 



49.18 
2.89 



5.£ 



54.8$ 
20.26 
38.13 
5.81 

1.18 
1.95 
3.46 
2.91 
4.46 
10.47 
23.42 
2.08 
2.02 
2.29 
19.48 
13.62 
125.61 

16.27 



^ The data on production and sales are for buli medicinal chemicals only; they exclude finished preparations and 
dosage-form products which are manufactured from bulk chemicals. All quantities are given in terms of IOO56 active 
ingredient. 

Calculated from rounded figxires except as noted. 

^ The term "benzenoid, " as used in this report, describes any cyclic medicinal chemical whose molecule contains 
either a six-membered carbocycllc ring with conjugated double bonds (e.g., the benzene ring or the quinone ring) or 
a six-membered heterocyclic ring with 1 or 2 hetero atoms and conjugated double bonds, except the pyrimidine ring 
(e.g., the pyridine ring or the pyrazine ring). 

^ Includes antibiotics of unknown structure. 

' With the exception of bacitracin, the penicillins, and a few other antibiotics which were reported in terms of 
U.S.P. units, all quantities for antibiotics were reported as grams of antibiotic base. (Thus production of 480,900 
grams of tetracycline hydrochloride, for example, would have been reported aa 444,430 grams of tetracycline base. ) 
For inclusion in the main statistical table all quantities were converted from grams of antibiotic base to pounds of 
antibiotic base (453.6 grams = 1 pound) or from U.S.P. units to pounds (22.7 million units of bacitracin, 458 mil- 
lion units of procaine penicillin a, 723 million units of potassium penicillin G, etc. = 1 pound). The following 



MEDICINAL CHEMICALS 



Footnotes for table i3A--Continuecl 

tabulation shows statistics for all individually publishable antibiotics in terms of kHograms of antibiotic base 
(Kg.) or billions of U.S. P. units (BU): 



Ifeit of 
quantity 



Production 



Bacitracin, total 

For medicinal use 

For other uses 

Neomycin, for all uses 

Penicillins, total 

For medicinal use, total 

Penicillin G, potassium 

Penicillin G, procaine 

All other — 

For other uses: Penicillin G salts- 
Streptomycin, for all uses 

Tetracyclines, for all uses 



267 
A,0(A 



1,676,281 



"T;2W 

587; 



48,136 
853,571 



209,670 
297,658 
346,243 



2,928 
21,766 



$1,060.96 



60.83 
25.50 



19.19 
40.50 
16.43 



Chiefly procaine penicillin G. 
'' Calculated from full figures. 

* Sales of rauwolfla and veratrum alkaloids amounted to 482 pounds. 

' Includes 2 or more of the following 6 drugs which are subject to Federal control under the Drug Abuse 
Control Act: Chlordlazepoxlde hydrochloride, diazepam, ethchlorvynol, ethlnamate, glutethimide, and methylprylon. 
U.S. production of these 6 drugs amounted to 508 thousand pounds In 1966. 

'■° Sales data for 1965 and earlier years Included some sales of aspirin tablets which were inadvertently reported 
as bulk sales. Statistics for sales of bulk aspirin (excluding tablets) in 1966 cannot be published without dis- 
closing the operations of individual producers. 

''■■'• Includes sales of anticonvulsants, hypnotics, and sedatives (except barbiturates), of antidepressants, and of 
salicylates. 

^^ All quantities for vitamins A, B12, D2, Ds, and E were reported in terms of grams or units, but were converted 
to pounds for inclusion in the main statistical table (1.317 billion units of vitamin A acetate, 0.824 billion units 
of vitamin A palmltate, 453.6 grams of vitamin B12, 18.14 billion units of vitamins Dj and D3, 617,000 units of 
d-alpha tocopheryl acetate, 454,000 units of dl-alpha tocopheryl acetate, etc. = 1 pound). The following tabulation 
shows statistics for these vitamins, except for the D vitamins, which were not separately publishable, in terms of 
kilograms (Kg.), millions of international units (MU), or billions of U.S. P. units (BU): 



Vitamin 


Unit of 
quantity 


Production 


Sales 


Quantity 


Value 


Unit value 


Cyanocobalamin (Vitamin 3^2) (except 
U.S. P. crystalline) 

Vitamin A alcohol and esters, total 


-—Kg 

BU 

BU 

BU 

MU- 


762 
943,652 


655,512 


!,000 
dollars 

18,817 


$28.70 


Vitamin A palmltate (feed grade) 

All other 

Vitamin E - 


527,584 
416,068 

276,863 


461,755 
193,757 

233,830 


U;344 
7,473 

7,908 


24.57 
38.57 

33.82 



slaxants, and mis- 



SYNTHETIC ORGANIC CHEMICALS. 1966 



Flavor and Perfume Materials 

Flavor and perfume materials are organic chemicals used in the manufacture of foods, bev- 
erages, cosmetics, and soaps. Aromatic organic chemicals are utilized to neutralize or to mask 
unpleasant odors in industrial processes and products as well as in consumer products. Most of 
them have desirable flavors or odors, and some have the ability to enhance natural flavors when 
added to certain foods. This report includes data on materials derived from natural products by 
actual chemical processes and from coal tar. These materials are grouped as either cyclic or 
acyclic materials, according to their chemical structures. Cyclic materials are further classi- 
fied as (1) benzenoia and naphthalenoid, and (2) terpenoid, heterocyclic, and alicyclic. Not in- 
cluded are data on purely natural products, such as floral essences, essential oils, and other 
materials that are obtained by simple extraction or by distillation from natural plant and animal 
sources. Statistics on production and sales of flavor and perfume materials in 1966 are given in 
table 14A.* 

Total domestic production of flavor ana perfume materials covered in this report in 1966 
amounted to 110.7 million pounds, or 11. 5 percent more than the 99. 2 million pounds produced in 
1965. Sales of these materials in 1966 amounted to 98. 3 million pounds, valued at $92.6 million, 
in 1966. 

Production of cyclic flavor and perfume materials in 1966 amounted to 61.4 million pounds-- 
15. 4 percent more than the 53. 2 million pounds produced in 1965. Sales of cyclic flavor and per- 
fume materials in 1966 were 49.6 million pounds, valued at $60.9 million, compared with 44.6 
million pounds, valued at $56.8 million, in 1965. The individual chemical in the cyclic group 
that was produced in the greatest volume in 1966, supplanting methyl salicylate which was the 
leader for some years, was benzyl alcohol (5. 1 million pounds). In 1966, production of synthetic 
sweeteners, as a group, amounted to 17. 3 million pounds, an increase of 35 percent over the 
output of 12. 8 million pounds in 1965. The average unit value of sales of all synthetic sweeteners 
in 1966 was $0.68 per pound, compared with $0.89 per pound in 1965. Reflecting this lower unit 
value, total value of sales for synthetic sweeteners was $8. 3 million in 1966, compared with 
$9.0 million in 1965. 

The output of acyclic flavor and perfume materials in 1966 amounted to 49. 3 million pounds, 
7. 1 percent more than the 46. million pounds produced in 1965. Monosodium glutamate was by 
far the most important of the acyclic chemicals, and the individual flavor and perfume chemical 
produced in the greatest volume; output of this flavor-enhancing chemical totaled 45.7 million 
pounds in 1966, compared with 43. 1 million pounds in 1965. Sales of acyclic flavor and perfume 
materials in 1966 amounted to 48. 7 million pounds, valued at $31. 7 million, compared with 43. 1 
million pounds, valued at $28.2 million, in 1965. 



TABLE lAA.-- Flavor and perfume materials; U.S. production and sales , 1966 

[Listed below are all synthetic organic flavor and perfume materials for which any reported data on production or 
sales may be published, (leaders are used where the reported data are accepted in confidence and may not be pub- 
lished or where no data were reported.) Table KB in pt. Ill lists all flavor and perfume materials for which 
data on production or sales were reported and identifies the manufacturer of each] 



Grand total 

FLAVOR AND PERFUME MATERIALS, CYCLIC 
Total - 

Total 

^-Allyl-2-methoxyphenol (Eugenol) 

Anethole (p-Propenylanisole) 

p-Anisaldehyde (p-Methoxybenzaldehyde) 

Benzophenone^ 

Benzyl acetate — 

Benzyl alcohol^ 

Benzyl butyrate 

Benzyl cinnamate — 

Benzyl ether — 

Benzyl phenylacetate (Benzyl a -toluate) 

Benzyl propionate- - -- - 

See footnotes at end of table. 



1,000 
110,670 



table 148. pt. m, which lists these products and identifiei th 
or and perfume materials during the years 1965-66. 



ufacturers, and i 



23 in the appendix, whicn shows ; 



FLAVOR AND PERFUME MATERIALS 37 

TABLE lAA.— Flavor and perfume materials: U.S. production and sales , 1966— ContinMed 



Material 



Production 



FLAVOR AND PERFUME MATERIALS, CYCLI C— Continued 

Benzenoid and /Vaphthalenoid— Continued 

Benzyl salicylate 

Cinnamaldehyde 

Cinnamyl acetate 

Cinnamyl alcohol 

2-Ethoxynaphthalene 

Isobutyl phenylacetate (Isobutyla -toluate) 

Isobutyl salicylate 

Isopentyl salicylate (Isoamyl salicylate) 

4'-Methoxyacetophenone 

S-Methoxy-'i-propenylphenol (Isoeugenol) 

p-Methylanlsole (p-Cresyl methyl ether) 

Methyl anthranilate 

a-Methylcinnamaldehyde 

Methyl citmamate 

Ifethyl salicylate (Synthetic wintergreen oil) 

a-Pentylcinnamaldehyde (ct-Amylcinnamaldehyde) 

Phenethyl isobutyrate 

Phenethyl phenylacetate (Phenethyl a -toluate) 

Phenethyl propionate 

3-Phenyl-l-propanol (ffydrooinnamic alcohol) 

'i-Propenylveratrole ( Isoeugenyl methyl ether) 

p-Tolyl acetate (p-Cresyl acetate) 

a-(TTichloromethyl)benzyl acetate (Roeetone) 

All other benzenoid and naphthalenoid materials 

Terpenoid, Heterocyclic, and Alicyclic 
Total - — - 

Cedryl acetate 

Citral a (Geranial) - - 

Citronellol-— - 

Citronellyl acetate 

Citronellyl formate 

Coumarin 

Essential oils, chemically modified 

Geraniol 

Geranyl acetate 

Geranyl formate 

Hydroxyoitronellal 

f^droxycitronellal, dimethyl aoetal 

lonones 

Isobomyl acetate 

Menthol, synthetic, tech. & U.S.P 

Menthone 

Methylionones 

Nerol — — 

Piperonal (Heliotropin) 

Rhodinol 

Sweeteners, synthetic 

Terpineols 

a-Terpinyl acetate , — 

Vetlvenyl acetate 

All other terpenoid, heterocyclic and alicyclic materiala- 

FLAVOR AND PERFtJME MATERIAI^, ACYCLIC 

Total - 

Allyl hexanoate (Aiajrl caproate) 

Ethyl butyrate 

Ethyl heptanoate (Ethyl enanthate) 

Glutamic acid, monosodium salt (Itonosodium glutamate) 

4-Hydroxyundecanoio acid, 7-lactone (7-Undecalactone) 

Isopentyl butyrate (Isoamyl butyrate) 

All other acyclic materials 

^ Calculated from the unrounded figures. 
Includes some technical grade. 



},000 


i,000 


pounds 


pounds 


304 


270 


1,319 


1,207 


15 


3 


2L5 


175 


19 





3,994 

436 

12 



253 

11 

17,346 

3,543 

473 

30 

6,267 



4,001 
485 
10 



263 

8 

12,181 

3,546 

433 

25 

3,064 



1,874 
606 
21 



9 

207 

16,030 





151 


368 


316 


84 


323 


653 


544 


822 


21 


22 


37 


32 


17 


34 


1,031 


1,192 


2,377 


254 


246 


707 


1,U7 


887 


1,159 


91 


91 


156 


U 


11 


24 


513 


51A 


1,973 


15 


9 


54 


340 


305 


998 


978 


997 


378 


574 


551 


2,151 



568 

221 

8,317 

1,132 

269 

457 

9,570 



328 

45,397 



221 
28,662 



SYNTHETIC ORGANIC CHEMICALS, 1966 



Plastics and Resin Materials 

Plastics and resin materials are condensation and polymerization products of organic chem- 
icals, containing necessary plasticizers, fillers, extenders, stabilizers, and coloring agents. At 
some stage in their manufacture they exist in such physical condition that they can be shaped or 
otherwise processed by the application of heat and pressure. Some types of plastics materials 
may be molded, cast, or extruded into semifinished or finished forms. Other types are used as 
adhesives, for the treatment of textiles and paper, and for protective coatings. (Statistics on 
U.S. production and sales of synthetic plastics and resin materials for 1966 are given in table 
ISA'). In general, the statistics follow the outline of the Tariff Commission's monthly report on 
the production and sales of synthetic plastics and resin materials (S.O.C. Series P-66). How- 
ever, the data given include some companies which are not covered in the monthly reports, and 



TABLE 15A. — Plastics and resin materials : U.S. production and sales, by chemical classes 
and uses, 1966 

[Quantities and values are given in terms of the total weight of the materials (dry basis). Listed below are all 
plastics and resin materials for which any reported data on production or sales may be published. (Leaders are 
used where the reported data are accepted in confidence and may not be published or where no data were reported.) 
Table 15B in pt. Ill lists all plastics and resin materials for which data on production or sales were reported 
and identifies the manufacturer of each] 



Production 



Sales 



1.000 
pounds , 



Grand total 

Plastics and resin materials, benzenoid 

Plastics and resin materials, nonbenzenoid 

THERMOSETTING RESINS 

Total 

Alkyd resins, total 

Domestic : 

Phthalio anhydride type 

Polybasic acid type 

Sales for export 

Coumarone-indene and petroleum polymer resins, total- 

Floor tile 

Rubber compounding 

All other uses 

Sales for export 

I^oxy resins: 

Unmodified, total 

Bonding and adhesives 

Protective coatings 

Reinforced plastics 

All other uses 

Sales for export 

Modified - 

Polyester resins,-' total 

Reinforced plastics: 

Sheets, flat and corrugated 

All other 

Surface coatings 

All other uses 

Sales for export 

See footnotes at end of table. 



70,2^3 
66,5^7 
197, 566 



4,590 
470,046 



1.000 
pounds. 



4,254,211 
7,217,427 



988,001 
1,752,080 



285, 692 
60, 202 
4,951 

319,741 



70,076 
65,613 
158,272 
25,780 



133,095 
15,144 
54,358 
27, 672 
17,451 
18,470 
4,024 

406, 658 



39,34^ 

253,772 

6,547 

95,192 



73,308 
15,472 
1,273 



4,451 
122,627 



See also table 15B, pt. Ill which lists these products by chemical type and by end uses, and identifies the manufacturers. 



PLASTICS AND RESIN MATERIALS 

TABLE 15K— Plastics and resin materials: U.S. production and sales, by chemical classes 
and uses, 2566— Continued 



39 



Kind and use 



Production 



THERM3SETTING RESINS— Continued 

Phenolic and other tar acid resins, total 

Maiding materials 

Bonding and adhesive resins for: 

Laminating 

Coated and bonded abrasives 

Friction materials 

Thermal insulation 

Foundry or shell molding 

Plywood 

Fibrous and granulated wood 

Protective coatings, unmodified and modified 

All other uses 

Sales for export 

Polyurethane and dilsocyanate resins 

Rosin ncdifioations, total 

Rosin and rosin esters, unmodified (ester gvims) 

All other - — 

Silicone resins 

Urea and melamine resins, total 

Textile treating and coating resins 

Paper treating and coating resins 

Bonding and aiihesive resins for: 

Laminating 

Plywood 

Fibrous and granulated wood 

Protective coatings 

All other uses (including molding) 

Sales for export 

All other thermosetting resins* 

THERMOPLASTIC RESINS 

Total 

Cellulose plastics materials, total ' 

Sheets, continuous: 

Under 0.003 gage— 

0.003 gage and over 

All other sheets, rods, and tubes 

Molding and extrusion materials 

Polyamide resins, total 

h^lon type 

Non-nylon type 

Polyolefin plastics materials: 

Polyethylene, density 0.940 and below: 

Production and sales 

Dsed by reporting companies In processing 

Sales and use, total 

Injection molding 

Blow molding 

Film and sheet 

Bctrueion coating on paper and other substrates- 
Wire and cable 

All other extruded products. Including pipe and 

conduit 

All other domestic uses 

Bcport sales 

See footnotes at end of table. 



307,481 

143,114 
31,544 
43,955 

128,061 
76,854 

156,028 
42,866 
34,291 
82,548 



71,514 
130,796 



186,707 

21,335 

48,734 

5,827 

110, 811 

92,618 
70,300 
22,318 



855,804 



1.000 
dollars 
203, 559 



278, 278 

86,972 
21,958 
38,097 
62,054 
72,671 
146, 138 
36,121 
26,760 
72,987 
13,768 



$0.24 



58,770 
71,139 



12,105 
15,720 



81,221 


73,612 


64,822 


48,624 


59,851 


38,777 


142,490 


121,936 


159,545 


147,482 


63,575 


38,562 


146,818 


125,611 




16,468 



183,462 

22,442 

49,584 

6,432 

105, 004 

82,133 
61,823 
20,310 



2,320,740 
226,745 

2,547,485 
323,464 
42, 503 

1,100,493 
313,164 
275,768 

40,023 
188,490 
263,580 



SYNTHETIC ORGANIC CHEMICALS, 1966 

-Plastics and resin materials.- U.S. production and sales, by chemical classes 
and uses, 1966 — Continued 



Kind and use 



THEEftJOPLASTIC RESINS— Continued 

i-oiyolefin plastics materials — Continued 
Polyethylene, density over 0.940: 

Production and sales 

Used by reporting conjianies in processing 

Sales and use, total 

Injection molding 

Blow molding 

Film and sheet 

Extrusion coating on paper and other substrates 

Wire and cable 

Pipe and conduit 

Other extruded products 

All other domestic uses 

Export sales 

Polypropylene : 

Production and sales 

Used by reporting companies in processing 

Sales and use, total 

Molding 

Extrusion 

All other uses (including export) 

Styrene type plastics materials, total 

ABS and SAN resins': 

Production and sales 

Sales and use, total 

Molding 

Extrusion 

All other domestic uses 

Export sales 

Styrene and styrene copolymer resins: 

Production' and sales 

Used by reporting companies in processing 

Sales and use, total 

Molding 

Textile and paper treating and coating 

Biulsion paint 

Extrusion 

All other domestic uses 

Export sales 

Vinyl resins (resin content): 

Polyvinyl chloride and copolymers: 

Production and sales, total 

Suspension homopolymers 

Suspension copolymers 

Dispersions (paste) 

Used by reporting companies In processing 

Sales and use, total 

Calendering, except flooring 

Flooring : 

Calendered 

Coated 

Paper and textile uses: 

Coating 

Other— - 

Protective coatings and adhesives 

Wire and cable 

Extruded film and sheet 

Other extruded products 

Sound records 

Injection and blow molding 

Plastisol formulating and molding 

All other domestic uses 

Bcport sales 

See footnotes at end of table. 



, 163, 561 
, 224, 286 
657,768 
281, 507 



1.000 

pounds, 

dry 



Per 
pound 



178, 800 
346,864 
45,423 
6,715 
30, 193 
39,059 
22,384 
139,068 
82,378 

372,475 
172,009 
544,484 
238, 568 
232,373 
73,543 



362,446 
362,446 
159,988 
111,132 
50,380 
40,946 



245,676 
2,055,575 
1,024,729 
207,337 
42,332 
245,022 
446,047 
90,108 



309, 984 

2,126,4^1 

438,882 



117,217 
15,576 
54,418 

225, 967 
65,956 

281,558 

114,396 
64,608 
91,953 

227,676 
69,232 



PLASTICS AND RESIN MATERIALS 



TABLE 15A, — Plastics and resin materials.- U.S. production and sales , by chemical classes 
and uses, 1966 — Continued 



Kind and use 



Production 



THERMOPLASTIC KESINS— Continued 

Vinyl resins (resin content) — Continued 
Polyvinyl acetate: 

Production and sales, total 

latexes 

Resins - 

Used by reporting companies in prooessing-- 

Sales and use, total 

Bmilsion paints 

Mhesives 

Paper treating 

Textile treating 

All other domestic uses 

Export sales 

Polyvinyl alcohol 

Other vinyl resins 

All other thermoplastic resins'"'''' 



335,961 
238,442 
97,519 



38,337 
132,098 



dry 


i.mo 




dolla 




231, i29 


66 


354 


73^992 






305,421 






110,090 






105, 44A 






25,702 






10,205 






51,719 






2,261 






' 37,926 


16 


438 


129,424 


67 


784 


380,891 


274 


551 



'■ Calculated from rounded figures. 

^ For -the purpose of this report, "dry basis" is defined as the total weight of the material, including resin, 
plasticizers, fillers, extenders, colors and stabilizers, and excluding water, solvents, and other liquid diluents. 

^ The term "polyester resins" includes unsaturated aliyds oopolymerized with a monomer such as styrene, and 
polyallyl resins such as diallyl phthalate and allyl diglycol carbonate. 

* Includes data for ace-tone-formnldehyde resins, s'tyrene-aUsyd polyesters, tolueneeulfonainide resins, silicone 
reelns, and other thermosetting resins which were produced in small quantities. Also included are saturated poly- 
esters for ure'thanee. 

' Represents production of polye'thylene by the high pressure process and of ethylene copolymers. 

* Represents production of polyethylene by the low pressure process. 

' ABS resins are polymers of acrylonitrile, styrene, and butadiene. SAN resins are polymers of s'tyrene and 
aorylonitrile. 

* Data for intra-company consumption may not be shown separately, and are Included with sales at an estimated 
unit value. 

' Includes straight polystyrene, 848,429 thousand pounds; rubber modified polystyrene, 724,413 thousand poimds; 
styrene-butadiene copolymers, 306,603 thousand pounds; and all other, 143,429 thousand pounds. 

10 Includes data for polyvinyl butyral, polyvinyl formal, and polyvinylidene chloride. 

■''■'' Includes data for aoryllo, fluorocarbon, polycarbonate, polyoxyme'thylene, polyterpene, and o-ther thermo- 
plastic resins. 



also some adjusted figures supplied by the original reporting companies. Consequently, many of 
the figures given in table 15A are re-vised from those shown in the Connmission's monthly release 
dated April 11, 1967, which contained year-end cumulative monthly totals for 1966. The end use 
breakdowns used were developed with the ad-vice of representatives of the plastics industry, and 
the data reported are the producers' determination of the markets of their materials. 

Total U.S. production of synthetic plastics and resin nnaterials in 1966 amounted to 13,585 
million pounds, or 16.3 percent more than the 11,685 million pounds reported for 1965. Sales in 
1966 were 11,472 million pounds, valued at $2,740 million. Production of benzenoid plastics and 
resin materials in 1966 amounted to 5, 067 million pounds and that of nonbenzenoid materials to 
8, 518 million pounds. These figures compare with the benzenoid production in 1965 of 4,453 mil- 
lion pounds, and nonbenzenoid production of 7, 232 million pounds. 

The 1966 output of all types of thermosetting resins totaled 3,647 million pounds, compared 
with 3, 237 million pounds in 1965. In 1966 phenolic and other tar acid resins were produced in 
the largest quantity in the thermosetting group, and exceeded one billion poxinds for the first 
time. Output of phenolic resins amounted to 1, 047 million pounds in 1966, compared with 922 
million pounds in 1965. Production of urea and melamine resins in 1966 was 718 million pounds, 
and that of alkyd resins was 666 million poxrnds. Other thermosetting resins produced in signif- 
icant amounts in 1966 were polyester resins (470 million pounds); coumarone-indene resins (334 
million pounds); epoxy resins (140 million pounds); and polyurethane resins (72 million pounds). 

The total output of thermoplastic resins in 1966 amounted to 9, 938 million pounds, com- 
pared with 8,448 million pound* in 1965. In 1966, as in pre-vious years, polyethylene, polysty- 
rene, and poly-vinyl chloride were the resins produced in the largest volume. The output of high- 
pressure polyethylene in 1966 was 2, 648 million pounds, which corresponds to the output of 2, 263 
million pounds of low-density polyethylene reported for 1965. Production of low-pressure poly- 
ethylene in 1966 was 910 million pounds, corresponding to the 784 million pounds of high-density 
polyethylene produced in 1965. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



The total production of styrene-type plastics materials in 1966 was 2,385 million pounds, 
compared with 2,033 million pounds in 1965. These totals include the ABS and SAN tyrpes of 
resins, for which data are shown for the first time for 1966. In 1966, output of ABS and SAN 
resins combined amounted to 362 million pounds. Sales were 362 million pounds, valued at $119 
million. Output of other styrene-type resins in 1966, including straight polystyrene, rubber- 
modified polystyrene, styrene-butadiene copolymer and others, amounted to 2,023 million 
pounds. 

Polyvinyl chloride resin production in 1966 amounted to 2,164 million pounds, compared with 
1,837 million pounds in 1965. Polyvinyl alcohol production in 1966 was 38.3 million pounds, and 
that of other vinyl resins including polyvinyl butyral, polyvinyl formal, and polyvinylidene chlo- 
ride amounted to 132 million pounds. All data on vinyl resins are reported on a resin content 
basis. 

Rubber-Processing Chemicals 

Rubber-processing chemicals are organic compounds that are added to natural and synthetic 
rubbers to give them qualities necessary for their conversion into finished rubber goods. In this 
report, statistics are given for cyclic and acyclic compounds, by use--such as accelerators, 
antioxidants, blowing agents, and peptizers. Statistics on production and sales of rubber-proc- 
essing chemicals in 1966 are given in table 16A.8 



TABLE 16A. --Rubber-processing chemicals : U.S. production and sales , 1966 

' Listed below are all rubber-processing chemicals for which any reported data on production or sales may be pub- 
lished. (Leaders are used where the reported data are accepted in confidence and may not be published or where 
data were reported. ) Table 16B in pt. Ill lists separately all rubber-processing chemicals for which data on pr 
duction or sales were reported and identifies the manufacturer of each] 



Grand total 

RUBBER-PROCESSING CHEMICALS, CYCLIC 

Total 

Accelerators, activators, and vulcanizing agents, total- 
Aldehyde- amine reaction products 

Dithiocarbamic acid derivatives 

Thiazole derivatives, total 

N-Cyclohexyl-2-benzothiazolesulfenamlde 

2,2'-Dithiobls(benzothlazole) 

2-^fercaptobenzo thiazole 

All other 

All other accelerators 

Antioxidants, antiozonants, and stabilizers, total 

Amino compounds, total 

Substituted p-phenylenediamines, total 

N, N'-Diphenyl-p-phenylenediamine 

All other 

Octyldiphenylamine 

N-Phenyl-2-naphthylamine 

All other amino antioxidants, antiozonants, and 

stabilizers 

Phenolic and phosphite antioxidants and stabilizers, 

total 

Polyphenolics (including bisphenols) 

Phenol, alkylated 

All other phenolic and phosphite antioxidants and 

stabilizers 

Blowing agents 

Peptizers 

All other cyclic rubber-processing chemicals, total 

N-Nitrosodiphenylamine 

All other^ 

See footnotes at end of table. 



K8,668 



115, 79i 

2,283 
47,212 
2,752 
5,31J 

58,234 

32,874 
6,555 
12,406 

13,913 



-S97126" 
37,220 
2,284 



6,236 

11,093 

3,304 
4,913 

3,175 



23,890 
2,738 
5,487 



60,381 
32,790 
2,311 



See also table 168, pt. in, which lists these products and identifies the manufacturer. 



RUBBER-PROCESSING CHEMICALS 



TABLE ISA. --Rubber-processing chemicals: U.S. production and sales, i566--Continued 



Unit 
ifalue^ 



RUBBER-PROCESSING CHIMICALS, ACYCLIC 

Total - 

Accelerators, activators, and vulcanizing agents, total- 

Dithiocarbamic acid derivatives, total 

Dlbutyldithlocarbamlo acid, zinc salt 

EHethyldithlocarbamlc acid, zinc salt 

Dimethyldithlocarbamlc acid, zinc salt 

All other 

Thlurams, total"* 

Bis(diethylthlocarbamoyl) disulfide 

Bis(dimethylthiocarbamoyl) disulfide 

Bis(dlmethylthlocarbamDyl) sulfide 

All other 

All other accelerators, activators, and vulcanizing 

agents 

Dodecyl mercaptans 

Dimethyldithiocarbamic acid, sodium salt 

All other acyclic rubber-processing chemicals^ 



1.000 
pounds 



19,925 



7,ig5 
1,741 
1,513 
1,736 
2,495 
11,994 

6,731 
1,338 
3,925 



12,658 
5,663 
3,841 



U,463 



6,082 
1,419 
1,115 
1,461 
2,087 
8,116 
1,087 
5,335 

1,694 

265 

7,860 
2,351 
1,821 



8,919 



4,634 

1,367 

653 

682 

1,932 

3,975 

501 

2,258 



3,629 

1,080 

994 



Calculated from rounded figures. 

^ Includes tacMfiers and physical-property Improvers. 

■^ Data on dithlocarbamates included in this table are for materials used chiefly in the processing of natural and 
synthetic rubbers. Data on dithlocarbamates which are used chiefly as fungicides are reported in table 20A "Pesti- 
cides and Related Products." ' 

* Includes data for small amounts of tetramethylthluram sulfides for uses other than in the processing of natural 
and synthetic rubbers. 

^ Includes blowing agents, polymerization regulators, shortstops, and conditioning and lubricating agents. 



Production of rubber-processing chemicals as a group in 1966 amounted to 283 million 
pounds, or 12.5 percent more than the 252 million pounds reported for 1965. The larger total 
output of rubber-processing chemicals in 1966 is attributable principally to increased production 
of amino antioxidants and thiazole accelerators. Sales of rubber-processing chemicals in 1966 
amounted to 209 million pounds, valued at $138 million, compared with 194 million pounds, 
valued at $123 million, in 1965. 

The output of cyclic rubber-processing chemicals in 1966 amounted to 241 million pounds, 
or 14.1 percent more than the 211 million pounds reported for 1965. Sales in 1966 were 183 mil- 
lion pounds, valued at $124 million, compared with 166 million pounds, valued at $109 million, 
in 1965. Of the total output of cyclic rubber-processing chemicals in 1966, accelerators ac- 
counted for 33.0 percent and antioxidants for 61.6 percent. Production of amino and phenolic and 
phosphite antioxidants, which amounted to 148.7 million pounds in 1966, included 115.8 million 
pounds of amino compounds and 32.9 million pounds of phenolic and phosphite compounds. Sales 
of amino antioxidants in 1966 were 89.1 million pounds, valued at $60.4 million; sales of phe- 
nolic and phosphite antioxidants were 23.9 million pounds, valued at $18.1 million. 

Production of acyclic rubber-processing chemicals in 1966 amounted to 42.1 million pounds, 
an increase of 3.8 percent over the 40.5 million pounds reported for 1965. Sales in 1966 totaled 
26.5 million pounds, valued at $14.6 million, compared with 27.5 million pounds, valued at 
$14.2 million, in 1965. Accelerators, principally dithiocarbamic acid derivatives and tetra- 
methylthluram sulfides, accounted for 47.3 percent of the output of acyclic rubber-processing 
chemicals for 1966. Dodecyl mercaptans accounted for 30.1 percent. Blowing agents, peptizers, 
modifiers, shortstops, and lubricating and conditioning agents accounted for the remainder of 
the output of acyclic compounds. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



Elastomers (Synthetic Rubbers) 

Elastomers are a group of high polymeric materials which have properties similar to those 
found in natural rubber. The term "elastomers", as used in this report, is specifically defined 
as substances in bale, crumb, powder, latex, and other crude forms, which can be vulcanized 
or similarly processed into materials that can be stretched to at least twice their original length 
and, after having been so stretched and the stress removed, will return with force to approxi- 
mately their original length. 

Statistics on production and sales of elastomers are given in table 17A.^ The total domestic 
output of all types of synthetic elastomers in 1966 was 3, 929 million pounds, compared with 
3, 592 million pounds, reported for 1965. Sales of these elastomers amounted to 3, 411 million 
pounds, valued at $918 million in 1966, compared with 3, 041 million pounds, valued at $843 
million, in 1965. 

Production of cyclic elastomers in 1966 amounted to 2,482 million pounds, compared with 
2, 300 million pounds in 1965. Of the total U.S. production of cyclic elastomers in 1966, the 
polybutadiene-styrene type (including vinylpyridine) accounted for 2,470 million pounds, and the 
polyurethane type for 12 million pounds. Sales of cyclic elastomers in 1966 were 2, 108 million 
pounds, valued at $463 million, compared with 1, 898 million poxinds, valued at $443 million, in 
the previous year. 

TABLE n A. --Elastomers (synthetic rubbers).-^ U.S. production and sales , 1966 

[Listed below are all elastomers (synthetic rubbers) for which reported data on production or sales may be pub- 
lished. (Leaders are used where the reported data are accepted in confidence and may not be published or where 
no data were reported.) Table 17B in pt. Ill lists all elastomers for which data on production or sales were 
reported and identifies the manufacturer of each] 



Product 


Production 


Sales 


Quantity 


Value 


Unit value^ 


Grand total 


1.000 
pound, 
3,929,187 


1,000 
pounds 
3,411,258 


1.000 
dollars 
918,018 


Per 
pound 

$0.27 


ELASTOMERS, CYCLIC 


2,482,375 


2,108,089 


463,222 


.22 




2,448,092 
21, 907 
12,376 

1,446,812 


* 2,086,856 
10,955 
10,278 

1,303,169 


446,413 
6,428 
10,381 

454,796 


.21 








1.01 


ELASTOMERS, ACYCLIC 


.35 




157,122 
230,685 
13,392 

612,689 


131,942 
10^751 
506,148 


58,869 
39," 307 
107,362 


.45 






Silicone elastomers 


3.66 
.21 




416,922 
195,767 

432, 924 


342,9'03 
163,245 

654,328 


67,476 
39,886 

249,258 


.20 


All other stereo elastomers 

All other acyclic elastomers^ 


.24 
.38 



The term "elastomers" is defined as substances in bale, crumb, powder, latex, and other crude forms which can be 
vulcanized or similarly processed into materials that can be stretched at 68° F. to at least twice their original 
length and, after having been so stretched and the stress removed, will return with force to approximately their 
original length. 

^ Calculated from rounded figures. 

^ Elastomer-content basis. 

* Partly estimated. 

' Includes data for polyacrylate, polyalkalene sulfide, polychloroprene, polyisobutylene elastomers, and for sales 
of polyisobutylene-isoprene elastomers. 

Note. — Statistics on the production of S-type, N-type, Butyl, neoprene, and stereo elastomers were compiled in 
cooperation with the U.S. Bureau of the Census. 



See also table 17B, pt. m, which lists these products and identifies the manufacturers. 



The U.S. production of acyclic elastomers in 1966 was 1,447 million pounds, compared 
with 1, 292 million pounds in 1965. Sales of these products in 1966 amounted to 1, 30 3 million 
pounds, valued at $455 million. Of the 1966 production of acyclic elastomers, stereo elastomers 
were produced in the largest amount (613 million pounds), followed by the polyisobutylene- 
isoprene type (^31 million pounds), and the polybutadiene-acrylonitrile type (N-type) (157 mil- 
lion pounds). The stereo elastomers are composed principally of polybutadiene, polyisoprene, 
and ethylene-propylene rubber. Production of silicone elastomers in 1966 was 13.4 million 
pounds, and of other acyclic elastomers was 433 million pounds. This latter figure includes data 
for polyacrylate, polyalkalene sulfide, polychloroprene, polyisobutylene, and other types of 
elastomers of lesser importance. 

Plasticizers 

Plasticizers are organic chemicals that are added to synthetic plastics and resin materials 
to (1) improve workability during fabrication, (2) extend or modify the natural properties of these 
resins, or (3) develop new improved properties not present in the original resins. Plasticizers 
reduce the viscosity of the resins and make it easier to shape and form them at high temperatures 
and pressures. They also impart flexibility and other desirable properties to the finished prod- 
uct. Statistics on production and sales of plasticizers are given in table 18A.^° 

Total U.S. production of plasticizers in 1966 amounted to 1,209 million pounds- -represent- 
ing an increase of 12. 7 percent over the output of 1, 073 million pounds reported for 1965. Sales 
in 1966 of the plasticizers covered by this report amounted to 1, 156 million pounds, valued at 
$246 million, compared with 1, 022 million pounds, valued at $214 million, in 1965--increases 
of 13. 1 percent in quantity and 14. 7 percent in value. 

TABLE 16A.— Plasticizers:'- U.S. production and sales, 1966 

[Listed below are all plasticizers for which reported data may be published. (Leaders are used where the reported 
data are accepted in confidence and may not be published or where no data were reported. ) Table 18B in pt. Ill 
lists all plasticizers for which data on production or sales were reported and identifies the manufacturer of 



Grand total 

PLASTICIZERS, CYCLIC 

Total 

Hiosphoric acid esters: 

Cresyl diphenyl phosphate 

Trlcresyl phosphate 

Triphenyl phosphate 

Phthalic anhydride esters, total 

aityl octyl phthalates (including butyl 2-ethylhexyl 

phthalate) 

Dibutyl phthalate 

Dicyclohexyl phthalate 

Diethyl phthalate 

Whexyl phthalate - 

Diisodecyl phthalate 

DKZ-methoxyethyl) phthalate 

Dimethyl phthalate 

Dlootyl phthalates, total^ 

Di( 2-ethylhexyl ) phthalate— 

Dllso-octyl phthalate - 

Mixed dioctyl phthalates (including dicapryl 

phthalate and dioctyl isophthalates ) 

Di-tridecyl phthalate 

Glyoolate phthalate esters 

n-Octyl n-decyl phthalate 

All other phthalic anhydride esters 

Trlmellitie acid esters 

All other cyclic plasticizers* 

See footnotes at end of table. 



i.OOO 
pounds 
1,155,686 



19, 956 
39, 812 
8,ai7 



17,222 
20,236 
6,739 
21,451 



376,800 
253,000 
103,000 



16,220 
716 
107, 500 
12,340 
4,247 
375,800 
253,000 
103,000 

19,300 
19,350 
4,334 
34,812 
129,763 



54,111 
35,420 
15,450 

3,241 
4,363 
1,736 
6,090 
22,236 

1,080 



and identifies the manufacturen. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 1&A.--Plasticizers :^ U.S. production and sales, 7966- -Continued 



Unit 
value ^ 



PLASTICIZERS, ACYCLIC 

Total 

Mipio acid esters, total 

Di(2-(2-butoxyethoxy)ethyl) adipate 

Di(2-etliylhexyl) adipate 

Diisodeoyl adipate 

n-Octyl n-deoyl adipate 

All other - 

Azelaic acid esters 

Complex linear polyesters and polymeric plasticizers' 

Ejpoxidized esters, total 

IJjoxidized soya oils 

2-Ethylhexyl epoxytallates 

Octyl epoxytallates 

All other- 

Glycerol monorioinoleate 

Isopropyl nyristate 

Oleic acid esters: 

Butyl oleate 

Glycerol trioleate (Triolein) 

Methyl oleate 

Propyl oleates (including normal and iso) 

Phosphoric acid esters 

Sebaoic acid esters: 

Dibutyl sebaoate 

Di(2-ethylhexyl) sebacate 

Stearic acid esters, total 

n- Butyl stearate 

All other— 

Triethylene glycol di(caprylate-caprate) 

All other acyclic plasticizers' 



1.000 
pounds 
311,742 



1 . 000 
pounds 
282, 577 



51,797 



50,485 



1,413 
22,278 

6,428 
10,833 
10,845 

15,664 
47,893 



1,322 
20,647 

6,669 
10, 930 
10, 917 

18,129 
45,278 

81, 630 



13,411 



"522" 
4,875 
1,788 
2,665 
3,461 



22,187 



3,172 
2,785 
2,973 

1,500 

13,566 



55,122 
11,056 
11,463 
3,989 

379 



1,847 
2,461 
2,096 
1,362 



15,004 
2,783 
2,929 
1,471 

131 



4,118 
2,925 



^ Does not include data for clearly defined extenders or secondary plasticizers. 

^ Calculated from rounded figures. 

^ Statistics for the dioctyl phthalates are partly estimated because part of the data which were published in 
the preliminary report were erroneously reported. 

* Includes data for alkylated naphthalene, glycol dibenzoates, hydrogenated terphenyls, phosphate esters (includ- 
ing sales of triphenyl phosphate), toluenesulfonamides, tetrahydrofurfuryl oleate, and other cyclic plasticizers. 

' Adiplc acid polyesters account for most of the production of complex linear polyesters and polymeric 
plasticizers. 

' Includes data for citric and acetylcitric, lauric, myristic, oleic, palmitic, pelargonic, ricinoleic, sebacic, 
and tartaric acid esters, glycerol and glycol esters, and other acyclic plasticizers. 

Note. — The total production and sales statistics are included in this report for some items that are not used 
exclusively as plasticizers. 



Production of cyclic plasticizers in 1966, which consisted chiefly of the esters of phthalic 
anhydride and phosphoric acid, amounted to 897 million pounds, compared with 799 million 
pounds in 1965. Sales of cyclic plasticizers in 1966 amounted to 873 million pounds, valued at 
$157 million, compared with 765 million pounds, valued at $133million, in the previous year. 

Production of acyclic plasticizers in 1966 amounted to 312 million pounds, compared with 
274 million pounds in 1965. Sales of acyclic plasticizers in 1966 amounted to 283 million pounds, 
valued at $89 million, compared with 257 million pounds, valued at $81 million, in 1965. Pro- 
duction of complex linear polyesters in 1966 amounted to 48 million pounds, and that of epoxi- 
dized esters, to 87 million pounds. Other products included in the acyclic class are the esters 
of adipic, azelaic, oleic, sebacic, and stearic acids. 



SURFACE-ACTIVE AGENTS 



Surface-Active Agents 

The surface-active agents included in this report are organic chemicals that reduce the sur- 
face tension of water or other solvents and are used chiefly as detergents, dispersing agents, 
emulsifiers, foaming agents, or wetting agents in either aqueous or nonaqueous systems. Waxes 
and products used chiefly as plasticizers are excluded. Surface-active agents are produced from 
natural fats and oils; from silvichemicals such as lignin, rosin, and tall oil; and from chemical 
intermediates derived from coal-tar and petroleum. A major part of the output of the bulk chem- 
icals shown in this report is consumed in the form of packaged soaps and detergents for house- 
hold and industrial use. The remainder is used in the processing of textiles and leather, in ore 
flotation and oil drilling operations, and in the manufacture of agricultural sprays, cosmetics, 
elastomers, foods, lubricants, paints, pharmaceuticals, and many other products . Table 19Ai^ 
shows statistics for production and sales of surface-active agents grouped by ionic class and by 
chemical class and subclass. All quantities are reported in terms of 100-percent organic 
surface-active ingredient and thus exclude all inorganic salts, water, and other diluents. 



TABLE 19A. --Surface-active agents : U.S. production and sales. 1966 

[Listed below are all surface-active agents for which reported data on production or sales may be published. 
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data 
were reported.) Table 19B in pt. Ill lists all surface-active agents for which data on production or sales were 
reported and identifies the manufacturer of each] 



Sales^ 



Quantity'- 



Grand total 

Benzenoid^ 

Nonbenzenoid^ 

Amphoteric Surface-Actiie Agents 

Anionic Surface-Act tie Agents 

Total - 

Carboxylio acids (and salts thereof), total 

Amine salts of fatty, rosin, and tall oil acids 

Carboxylic acids having amide or ester linkages, total— 

N-Lauroylsarcosine, sodium salt 

All other - 

Potassium and sodium salts of fatty, rosin, and tall 

oil acids, total 

Coconut oil acids, potassium and sodium salts, total- 
Potassium salt 

Sodium salt 

Com oil acids, potassium and sodium salts 

Oleic acid, potassium salt 

Oleic acid, sodium salt 

Stearic acid, potassium and sodium salts 

Tall oil acids, potassium and sodium salts, total 

Potassium salt 

Sodium salt 

Tallow acids, sodium salt 

All other 

Phosphoric and polyphosphori c acid esters (and salts 

thereof), total 

Alcohols and phenols, ethoxylated and phosphated, total- 
Mixed linear alcohols, ethoxylated and phosphated 

Nonylphenol, ethoxylated and phosphated 

All other 

Alcohols, phosphated or polyphosphated, total 

2-Ethylhexyl phosphate, sodium salt 

All other 

See footnotes at end of table. 



3,321,317 



9'i3,680 

2,377,637 

5,052 



U,138 

92,-130 

617 

3,847 

2,176 

2,258 

28,635 

15,597 

13,038 

493,847 

306,197 



4,124 
5,090 



IMO 

pounds 

1,766,053 



449,685 

1,316,368 

4,852 



5or 

2,678 

901 

1,777 



617 

337 

1,130 

918 

13,796 



2,037 
3,190 
3,569 



1.000 
dollars 
314,913 



81,468 

233,445 

3,225 



2,479 

731 

1,748 

2,201 

27 

2,174 



See also table 19B. pt. m. which lists these produ 



Identifies the i 



SYNTHETIC ORGANIC CHEMICALS, 1966 
TABLE 19 A. -Surface-active agents: U.S. production and sales , -ZS66 --Continued 



Anionic Surface-Act ive /Igents- -Continued 

Sulfonic acids (and salts thereof), total 

Alkylbenzenesulfonates, total 

Dodecylbenzenesulfonates, total 

Dodecylbenzenesulfonic acid 

Dodecylbenzenesulfonic acid, calcium salt 

Dodecylbenzenesulfonic acid, isopropanolamine salt-- 

Dodeoylbenzenesulfonlc acid, isopropylamine salt 

Dodecylbenzenesulfonic acid, sodium salt 

Dodecylbenzenesulfonic acid, triethanolamine salt 

All other — 

Other alkylbenzenesulfonates, total 

Tridecylbenzenesulfonic acid 

Tridecylbenzenesulfonic acid, sodium salt 

All other - — 

Benzene-, cumene-, toluene-, and xylenesulfonates, total 

Xylenesulfonic acid, ammonium salt 

Xylenesulfonlc acid, sodium salt 

All other 

Ligninsulfonates, total 

Ligninsulfonic acid, calcium salt 

Ligninsulfonic acid, sodium salt 

All other 

Naphthalenesulfonates, total 

Butylnaphthalenesulfonio acid, sodium salt 

All other-- 

Other sulfonic acids, total 

N-hfethyl-N-oleoyltauTine, sodium salt 

Sulfosuccinamic acid derivatives 

Sulfosuocinic acid esters, total 

Sulfosuccinic acid, bis(2-ethylhexyl) ester, 

sodlimi salt 

All other 

All other sulfonic acids 

Sulfuric acid esters (and salts thereof): 

Acids, amides, and esters, sulfated, total 

Coconut oil acids - ethanolamine condensate, sulfated, 

potassium salt 

Esters of sulfated oleic acid, total 

Butyl oleate, sulfated, sodium salt 

Isopropyl oleate, sulfated, sodium salt 

Propyl oleate, sulfated, sodium salt 

All other 

Oleic acid, sulfated, disodium salt 

Tall oil, sulfated, sodium salt 

All other 

Alcohols and phenols, sulfated, total 

Dodecyl sulfate salts, total 

Dodecyl sulfate, magnesium salt 

Dodecyl sulfate, sodium salt 

Dodecyl sulfate, triethanolamine salt 

All other - — - — 

2-Ethylhexyl sulfate, sodium salt 

Ootadecyl sulfate, sodium salt 

Octyl sulfate, sodium salt 

All other - 

Ethers, sulfated, total 

Alkylphenols, ethoxylated and sulfated 

Dodecyl alcohol, ethoxylated and sulfated, ammonium 

salt 

Dodecyl alcohol, ethoxylated and sulfated, sodium salt 
Mixed linear alcohols, ethoxylated and sulfated, 

sodium salt 

All other 

See footnotes at end of table. 



1.000 



596,416 

506,544 

92,142 

11,287 

355 

3,780 

391,921 

4,124 

2,935 

89,872 

387 

89,485 

70,922 

16,781 

22,127 

32,014 

4^1,537 

284,018 

54,308 

103,211 

8,277 

834 

7,443 

2,797 
1,714 
7,736 



1.000 
670,985 



137,936 
132,873 



84,634 

4,317 

5,166 

5,063 

387 

787 

3,889 

70,791 

18,780 

20,159 

31,852 

429,550 

272,933 

53,406 

103,211 

6,614 

6,614 
26,094 
2,589 
1,579 
7,275 

4,926 
2,349 
14,651 



22,560 
21,496 
4,500 
2,610 



11,764 

1,066 

1,556 

1,064 

50 

329 

685 

5,117 

1,286 

1,807 

2,024 

15,719 
7,109 
4,097 
4,513 
2,615 

2,615 
14,014 
1,335 
857 
3,903 

2,721 



6,597 


4,806 


1,343 


3,432 


1,772 


401 


357 


355 


133 


512 


489 


153 


2,296 


2,190 


656 


8,699 






768 


734 


179 


5,412 


8,898 


2,795 




28,126 


1^,235 


39,617 






239 


225 


69 


14,862 


11,117 


5,129 


8,493 






16,023 






1,582 








309 


163 


172 


185 


76 





16,290 


6,798 


137,669 






9,601 


8,166 


1,911 


367 






2,718 


2,065 


723 


4,310 


4,531 


670 


120,673 







SURFACE ACTIVE AGENTS 
TABLE 19A. --Surface-active agents : U.S. production and sales , 1966- 



Chemioal 


Production^ 


Sales^ 




Quantity^ 


Value 


Unit 
valued 


Anionic Surface -Active .4gents--Contlnued 

Sulfuric acid esters (and salts thereof )— Continued 

Natural fats and oils, sulfated, total 

Castor oil, sulfated, sodium salt 

Coconut oil, sulfated, sodium salt 


1.000 

pounds 

30,-121 

6,504 

2,100 

1,934 

1,469 

962 

238 

247 

5,963 

9,502 

1,502 

133,187 
161,843 


1 . 000 

pounds 

19,520 

3,954 

578 

1,427 

743 

'" 138 
3,535 
7,135 
2,010 

297,800 
126,882 


1.000 

dollars 

3,824 

1,175 

142 

226 

152 

46 
654 
931 
498 

42,866 
50,918 


Per 
pound 

$0.20 
.30 
.25 














Soybean oil, sulfated, sodium salt — - — 


.33 














Canonic Surface-Active Agents 








Amine oxides and oxygen-containing amines (except those 


38,518 














685 
464 
3,384 
1,084 
779 
1,400 
30,722 

17,451 


630 
458 

796 
1,312 

15,364 


257 
210 

'"' 375 
869 

6,992 


.41 


(Mixed alkyl) amine, ethoxylated 








(Tallow alJsyl) amine, ethoxylated 


.66 


Amines and amine oxides having amide linkages, total 


.46 




9,067 

'" 302 
8,765 

7,046 

4,579 

2,286 

181 

1,338 

59,636 


8,759 

75 

202 

8,482 

5,337 

"5,337 
1,268 


3,029 
45 
62 

2,922 

3,607 

3,607 
356 




Coconut oil acids - diethylenetriamlne condensate 

Oleic acid - diethylenetriamlne condensate 


.60 
.31 


Carboxylic acid - diamine and polyamine condensates. 




Oleic aoid - ethylenediamlne condensate, mono- 




Stearic acid - ethylenediamlne condensate, mono- 




All other 




Other amines and amine oxides having amide linkages 

Amines, not containing oxygen (and salts thereof), total— 


.28 




11,761 
1,839 
1,807 
3,905 
4,210 

32,252 
1,910 
1,605 

11,292 
1,804 

5,670 
9,971 

13,488 
233 

13,255 


10,405 
1,291 
1,716 
3,895 
3,503 

26,083 
1,203 

10,071 

872 

700 

4,179 

9,058 

" 254 
25,146 


697 
3,602 

636 

678 
1,540 

748 
8,292 

657 

"2,267 

379 

324 

1,220 

3,445 

133 
9,157 


.36 


























Dodecylamlne — 




















Secondary and tertiary monoamines, total 

N,N-Diniethyloctadecylamine - 

All other 


.52 


Groups listed above for which separate sales data may not 









See footnotes at end of table. 



50 SYNTHETIC ORGANIC CHEMICALS, 1966 

TABLE 19A. —Surface-active agents.- U.S. production and sales, 2966- 



Chemioal 



Production^ 



Oxygen- containing quaternary annnonium salts (except those 
having amide linkages) 

l^atemary ammonium salts having amide linkages 

Quaternary ammonium salts, not containing oxygen, total — 
Acyclic, total 

Bls( coconut oil alkyl) dime thy Ifimmonium chloride 

Bis(hydrogenated tallow alkyl )dlmethylammonium 

chloride 

Dodecyltrimethylamraonium bromide and chloride 

Hexadecyltrimethylaramonium bromide 

N,N,N',N',N'-Pentamethyl-N-( tallow alkyl)trimethylene- 

bis-[ ammonium chloride] 

All other 

Benzenoid, total 

Benzyl( coconut oil alkyl) dime thylammonium chloride 

Benzyldimethyl(mixed alkyl) ammonium chloride 

Benzyldimethyloctadecylammonium chloride 

Beuzyldodecyldimethylaramonium chloride 

(3,'4-Dichlorobenzyl)dodecyldimethylammonium chloride-- 

(Dodecylbenzyl)trlmethylammonium chloride 

All other 

^anionic Surface-Active Agents 

Total — — 

Carboxylic acid amides, total 

Carboxylic acid - aUkanolamlne condensates, total 

Diethanolamine condensates (amlne/acid ratio =2/l), 

total - — 

Capric acid 

Coconut oil acids 

Laurie acid 

Oleic acid 

Stearic acid 

Tall oil acids 

All other 

Diethanolamine condensates (amine/acid ratio = 2/l), 

total 

Coconut oil acids 

Laurie acid 

Oleic acid 

Stearic acid 

All other- — 

Ethanolamlne condensates (amine/ acid ratio =2/l), 

total 

Coconut oil acids 

All other - 

Ethanolamlne condensates (other amine/acid ratios) 

Isopropanolamine condensates, total 

Laurie acid 

All other- 

Other alkanolamlne condensates 

Carboxylic acid - alkanolamine condensates, ethoxylated- 
Carboxyllo acid - diamine and polyamine condensates 

(nonionic), total 

Stearic acid - ethylenedlamlne condensate (amine/acid 

ratio =1/2)— 

All other 

Carboxylic acid esters, total 

Anhydrosorbitol esters, total 

Anhydrosorbltol monoester of tall oil acids 

Anhydrosorbitol monolaurate 

See footnotes at end of table. 



93,020 



80, 105 

25,555 

110 

13,194 

5,450 

2,113 

864 

574 

3,250 

37,380 
17,826 
17,069 

769 
1,037 

679 



1,156 
1,025 

131 
9,154 
5,842 

866 
4,976 
1,018 



13,787 

435 

2,381 



30,959 
1,620 



63,240 



18,514 
98 
10, 687 
2,730 
2,020 
572 



2,407 



773 
1,035 



1,142 

1,013 

129 



542 
12,238 



1,622 
1,956 
16,756 



77 


59 


51 


11,280 


11,367 


5,169 


7,429 


6,822 


5,735 


346 


346 


287 


3,588 


3,052 


2,551 


413 


396 


356 


553 


521 


374 


43 


35 


25 



303 
3,628 



SURFACE-ACTIVE AGENTS 
TABLE 19A. —Surface-active agents: U.S. production and sales, 1966- -Continued 



Surface-Active Agent 



-Continued 



Carboxylio acid esters — Continued 
Anhydrosorbltol esters — Continued 

Anhydrosorbitol trioleate 

All other 

Ethoxylated anhydrosorbitol esters, total 

Ethoxylated anhydrosorbitol monolaurate 

Ethoxylated anhydrosorbitol mono-oleate 

Ethoxylated anhydrosorbitol monopalmitate 

Ethoxylated anhydrosorbitol monostearate 

Ethoxylated anhydrosorbitol trioleate 

Ethoxylated anhydrosorbitol tristearate 

All other 

Ethylene glycol and dietliylene glycol esters, total 

Diethylene glycol monolaurate 

Die-thylene glycol mono-oleate 

Diethylene glycol monostearate 

Ethylene glycol distearate 

Ethylene glycol monostearate 

All other - 

Glycerol esters, total 

Complex glycerol esters 

Glycerol esters of chemically defined acids, total 

Glycerol monolaurate 

Glycerol mono-oleate 

Glycerol monorlcinoleate 

Glycerol monostearate 

All other 

Glycerol esters of mixed acids 

Natural fats and oils, ethoxylated, total 

Castor oil, ethoxylated 

All other 

Polyethylene glycol esters, total 

Polyethylene glycol esters of chemically defined 

acids, total 

Polyethylene glycol dllaurate 

Polyethylene glycol dioleate 

Polyethylene glycol distearate 

Polyethylene glycol monolaurate 

Polyethylene glycol mono-oleate 

Polyethylene glycol monostearate 

All other 

Polyethylene glycol esters of rosin and tall oil 

acids, total 

Polyethylene glycol sesquiester of tall oil acids 

All other 

Polyethylene glycol esters of other mixed acids, total 
Polyethylene glycol sesquiester of coconut oil acids 

All other 

Polyglycerol esters 

Propanediol esters, total 

1,2 -Propanediol monolaurate 

1,2-Propanediol monostearate 

All other 

Other carboxylic acid esters 

Ethers, total - 

Benzenoid ethers, total 

Dlnonylphenol, ethoxylated 

Dodecylphenol, ethoxylated 

Iso-octylphenol, ethoxylated 

Nonylphenol, ethoxylated 

Phenol, ethoxylated 

All other 

Nonbenzenoid ethers, total 

Dodecyl alcohol, ethoxylated 

Hexadecyl alcohol, ethoxylated 

See footnotes at end of table. 



1.000 
pounds 

7-48 
10,223 
12,3^9 
2,'iOO 
^,753 



761 
1,301 
<i,291 

548 

126 
1,025 

490 
1,016 
1,086 
71,460 
4,259 
23,844 

1,927 

20,974 
943 
43,357 
4,181 
3,611 
570 
24,436 

19,068 
989 
3,042 
361 
5,260 
3,509 
4,835 
1,072 

4,558 

3,771 
787 
810 
258 
552 
428 

3,534 
142 

2,817 

575 

11,904 



2,101 
120,370 

6,507 
105,054 
209,839 



4,650 
340 

2,634 
526 

1,825 

3,892 

528 

120 

825 

437 

854 

1,128 

61,279 

2,976 

22,070 

51 

1,588 

52 

19,929 

450 

36,233 

3,542 



3,542 
16,133 



2,606 

3,960 

763 

3,915 

3,138 
777 
578 
181 
397 
468 

2,079 
145 

1,649 

285 

11,660 

337,431 



205,858 
1,821 
10,359 
1,602 

120,276 

71,800 

131,573 

2,224 

485 



3,384 
5,339 
1,241 
1,920 

157 
1,124 

227 

670 

1,306 

161 

34 

242 

137 

329 

403 

16,860 

1,257 

7,216 

19 

565 

29 

6,401 

202 

8,387 

1,254 



4,441 
263 
279 
IW 
957 
953 

1,545 
330 

984 
740 
244 
189 

50 
139 
230 
591 

69 
444 

78 
5,338 

59,760 



35,905 

410 

1,167 

384 

18,749 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 19A. — Surface-active agents : U.S. production am 


sales, 1966- 


Continued 




Chemical 


Production-'- 


Sales^ 


Quantity^ 


Value 


Unit 
valued 


Nontonic Surfacr-Aclue (grnts --font Ir.ued 

Ethers —Ctontinued 

Nonbenzenoid ethers— Continued 


pounds 

104,448 
3,684 
549 
8,329 
92,829 
2,432 


1.000 

81,516 
2,597 

7,367 
37,384 

1,260 


dolUn 
10,299 
1,358 

" 1,614 
9,427 
1,095 


pound 

$0.13 
.52 


9-Octadecenyl alcohol, ethoxylated 


rridecyl alcohol, ethoxylated — 

All other 


.22 

.25 

.37 


er no o o sur aoe ac ve agen 



sul- 



' All quantities are given in terms of 100-percent organic surface-active ingredient 

^ Sales Include products sold as bulk surface- active agents only. 

^ Calculated from rounded figures. 

^ The term "benzenoid, " as used in this report, describes any surface- active age 
whose molecxilar structure includes 1 or more 6-membered carbocyclic or heterocycli 
bonds (e.g., the benzene ring or the pyridine ring). 

' Includes the lignlnsulfonates, which were classed as benzenoid in previous years. 

^ Includes production of "all other" sulfonic acids and of "all o-ther" sulfated alcohols and phenols; also in- 
cludes sales of "all other" potassium and sodium salts of fatty, rosin, and tall oil acids and of "all 
fated ethers. 

Note: The surface- active agents included in this report are organic chemicals that reduce the surface tension of 
water or o-ther solvents and are used chiefly as detergents, dispersing agents, emulsifiers, foaming agents, or wet- 
ting agents in either aqueous or non aqueous systems. The properties which make a product useful as a surface- active 
agent are due to a molecular structure in which one or more polar functional groups are balanced by a large non- 
polar group. Uie polar, or hydrophilic, groups, which may be anionic, cationic, or nonionlc, tend to make the 
product misclble with water and other polar solvents and immiscible with oil. The nonpolar, or hydrophobic, group, 
which usually consists of a long-chain alkyl or aliylphenyl radical, tends to make the product miscible with oil 
and other nonpolar solvent and immiscible with water. Because of this balance between hydrophilic and hydrophobic 
tendencies, the molecules of surface- active agent concentrate at the liquid phase boundaries and reduce the inter- 
facial tension of any system in which they are introduced. Thus at an oil/water interface they may promote the 
formation of a stable emulsion; at an air/water interface they may promote the formation of foam; and at a liquid/ 
solid boundary they may act as detergents, dispersing agents, or wetting agents. 



Total U.S. production of surface-active agents in 1966 amounted to 3, 321 million pounds, or 
4.8 percent more than the 3, 170 million pounds reported for 1965. These statistics include data 
for fatty monoamines, which were previously reported in the section on Miscellaneous Organic 
Chemicals, and for potassium and sodium salts of fatty, rosin, and tall oil acids (soaps), which 
were for the most part not previously reported. Sales of bulk surface-active agents in 1966 
amounted to 1, 766 million pounds, valued at $315 million, compared with sales in 1965 of 1, 698 
millionpounds, valuedat $300 million. Sales in 1966 were thus 4. percent larger than in 1965 in 
terms of quantity and 4. 9 percent larger in terms of value. Sales statistics for 1965 and 1966 
reflect sales of bulk surface-active agents only, whereas sales data reported for earlier years 
included surface-active agents sold as active ingredients in formulated and packaged products, 
as well as strictly bulk materials. Thus the statistics for 1965 and 1966 are not strictly com- 
parable with those for earlier years. 

Production of anionic surface-active agents in 1966 amounted to 2, 469 million po-^nds, or 
74. 3 percent of the total reported for 1966 and 4. 7 percent more than the anionic output reported 
for 1965. Sales of anionics in 1966 amounted to 1, 112 million pounds, valued at $141 million. Of 
the total anionic output, 944 million pounds consisted of potassium and sodium salts of fatty, 
rosin, and tall oil acids, of which 494 million pounds was the sodium salt of tallow acids and 92 
million pounds was the sodium salt of coconut oil acids; 596 million pounds consisted of alkyl- 
benzenesulfonates, of which 392 million pounds was the sodium salt of dodecylbenzenesulfonic 
acid and 92 million pounds was the free acid; and 442 million pounds consisted of ligninsulfonic 
acid salts, of which 284 million pounds was the calcium salt and 54 million pounds was the sodium 
salt. 

Production of nonionic surface-active agents in 1966 amounted to 686 million pounds, or 
20.6 percent of the total reported for 1966 and 4.0 percent more than the nonionic output reported 
for 1965. Sales of nonionics in 1966 amounted to 523 million pounds, valuedat $119 million. Of 
the total nonionic output, 234 million pounds consisted of alkylphenol ethoxylates and other 
benzenoid ethers, of which 120 million pounds was nonylphenol ethoxylate; 210 million pounds 
consisted of alcohol ethoxylates and other nonbenzenoid ethers, of which 104 million pounds was 
mixed linear alcohol ethoxylate; 80 million pounds consisted of alkanolamides, of which 18 mil- 
lion pounds was coco diethanolamide (made with a 1/1 ratio of diethanolamine to coconut oil 
acids), 17 million pounds was lauric diethanolamide (1/1 ratio), and 13 million pounds was coco 



PESTICIDES AND RELATE:^ PRODUCTS 



53 



diethanolamide (2/1 ratio); and 71 million pounds consisted of glycerol esters, of which 21 mil- 
lion pounds was glycerol monostearate. 

Production of cationic surface-active agents in 1966 amounted to 162 million pounds, or 4.9 
percent of the total reported for 1966 and 9.4 percent more than the cationic output reported for 

1965. Sales of cationics in 1966 amounted to 127 million pounds, valued at $51 million. Of the 
total output of cationics, 39 million pounds consisted of quaternary ammonium salts not contain- 
ing oxygen, of which 18 million pounds was bis (hydrogenated tallow alkyl)dimethylammonium 
chloride; and 32 million pounds consisted of primary monoamines not containing oxygen, of which 
11 million pounds was (hydrogenated tallow alkyl)amine. 

Production of amphoteric surface-active agents in I966 amounted to 5. 1 million pounds, or 
approximately 0. 2 percent of the total reported for 1966 and 1. 2 percent less than the amphoteric 
output reported for 1965. Sales in 1966 amounted to 4. 9 million pounds, valued at $3. 2 million. 

The difference between production and sales reflects inventory changes and, for 1965 and 

1966, captive consumption of soaps and surface-active agents by synthetic rubber producers and 
by manufacturers of cosmetics, packaged detergents, bar soaps, and other formulated consumer 
products. In some instances the difference may also reflect quantities of surface-active agents 
used as chemical intermediates, e.g. nonionic alcohol and alkylphenol ethoxylates which may be 
converted to anionic surface-active agents by phosphation or sulfation. 

Pesticides and Related Products 

This section of the report covers pesticides (fungicides, herbicides, insecticides, and 
rodenticides) and related products such as plant hormones, seed disinfectants, soil conditioners, 
soil fumigants and synergists. The data are given in terms of 100-percent active material; they 
thus exclude such nnaterials as diluents, emulsifiers, and wetting agents. Statistics on produc- 
tion and sales of pesticides and related products in 1966 are given in table 20A,''"^ 



TABLE 20A.— Pesticides and related products.- U.S. production and sales, 1966 

[Listed below are all pesticides and related products for which any reported data on production or sales may be pub- 
lished. (Leaders are used where the reported data are accepted in confidence and may not be published or where no 
data were reported. ) Table 20B in pt. Ill lists all pesticides and other organic agricultural chemicals for which 
data on production or sales were reported and identifies the manufacturer of each] 



Sales 



Grand total 

PESTICIDES AND RELATED PRODUCTS, CYCLIC 

Total - — 

Fungicides, total 

3,5-Dijnethyl-l,3,5,2H-tetrahydrothiadlazine-2-thione 

(DMTT) — 

Mercury fungicides 

Naphthenic acid, copper salt 

Pentaohlorophenol (PCP) 

S-Qiiinolinol (8-Itydroxyquinoline), copper salt 

2,^,5-Trichlorophenol and salts 

All other^- 

Herbicides and plant hormones, total 

Dinitrobutylphenol (DNBP)— - 

Dlnltrobutylphenol, ammonium salt 

See footnotes at end of table. 



1,110 
1,035 
3,211 
'i3,262 
-426 
17,929 
33,653 

266, o-;? 



i.mo 

pounds 
822,256 



$0.71 



.^9 

A. 02 

.27 



1.25 
-T32" 

1.57 



■ See also table 20B, pt. TO, which lists the$e products and Identifies the manufacturers. 



SYNTHETIC ORGANIC CHEMICALS, 1966 
TABLE 20A.— Pesticides and related products .- U.S. production and sales , i 566- -Continued 



PESTICIDES AND RELATED PRODUCTS, CYCLIC--Conxinued 



Herbicides and plant hormones — Continued 

1-Naphthaleneacetio acid and esters and 'salts 

Phenoxyacetio acid derivatives : 

2,A-Dichlorophenoxyacetic acid (2,'4-D) 

2,'i-Dichlorophenoxyaoetic acid esteTs and salts, total- 

2,A-Dichlorophenoxyacetic acid, n-butyl ester 

2,'i-Diohlorophenoxyaoetlo acid, dimethylamine salt 

2,<i-Dichlorophenoxyacetic acid, iso-ootyl ester 

2,'4-Dlchlorophenoxyacetio acid, isopropyl ester 

All other 

2,A,5-Triohlorophenoxyaoetic acid (2,'i,5-T) 

2,4,5-Trichlorophenoxyaoetic acid esters and salts, 

total 

2,'i,5-Trichlorophenoxyacetlc acid, n-butyl ester 

2,'4,5-Trichlorophenoxyaeetio aold, iso-octyl ester 

All other 

Phenylmercury acetate (FMA) 

All other^ 



72 


522 


17 


966 


T) 


?66 




328 


30,962 


15,^89 


18 


059 


10 


U6 



31 

28,021 
55,281 
20,401 
11,669 
8,181 
2,598 
12, «2 
5,096 

10,037 



8,785 
22,867 
9,603 
A, 829 
2,979 
880 
A, 576 
'4,705 

8,119 

2,116 

6,003 

2,366 

165,090 



Insecticides and rodentioldes, total 

Aldrin-toxaphene group'' 

a-Bis(p-chlorophenyl) |j ,|:,(i-trichloroe thane (DDT) 

Hexachlorocyclohexane (Benzene hexachloride ) and lindane- 
Organophosphorus insecticides, total 

0, 0-Diethyl O-p-nitrophenyl phosphorothloate (Para- 



0,0-Dimethyl O-p-nitrophenyl phosphorothloate (Methyl 

parathion) 

All other^ - 

All other' — 



Wl,349 
73,342 



35,862 

18,036 
65,075 



351,473 
128,161 
101,466 
8,522 
57,084 



26,973 
14,575 
56,240 



16,814 
2,018 
66,426 



18,709 
37,066 
55,143 



PESTICIDES AND RELATED PRODUCTS ACYCLIC 



Total - 



Fungicides, total 

Dlmethyldlthiooarbamlc acid, ferric salt (Ferbam) 

Ethylene bis(dithiocarbajnic acid), disodium salt (Nabam) 

Ethylene bis(dlthiocarbamic acid), zinc salt (Zineb) 

All other' - 



1,379 
2,053 
4,721 
28,627 



Herbicides and plant hormones" 

Insecticides, rodenticides, and soil conditioners and 

fumigants, total 

l,2-Dlbromo-3-chloropropane (DBCP) 

Methyl bromide (Bromoethane) 

Organophosphorus insecticides, total 

Tetraethyl pyrophosphate (TEPP) 

Other organic phosphorous insecticides'' 

All other insecticides, rodenticides, and soil condi 
tioners and fumigants -'■° 



1,679 
2,209 
4,326 
27,866 



130,884 



8,722 
16,345 
46,580 

46,580 

70,129 



5,266 
16,324 
39,976 
287 
39,689 

69,318 



66,746 



2,658 
6,652 

48,249 
280 

47,969 

9,187 



^ Calculated from rounded figures. 

^ Includes captan, dlchlone, folpet, glyodln, pentachloronitrobenzene, sodium pentaohlorophenate, tri- and 
tetrachlorophenols, and others. 

^ Includes dimethylurea compounds, dinitrophenol compounds, endothal, isopropyl carbanilates (IPC and CIPC), 
maleic hydrazide, propanil, triazlnes, uracils, and others. 

"" Includes aldrin, ohlordan, dieldrin, endrln, heptachlor, terpene polychlorinates, and toxaphene. 

^ Includes carbophenothion, diazlnon, ronnel, other phosphorothioates and phosphorodlthioates, and others. 

^ Includes DDD, 4,4-Dlchlorobenzllate, dlcofol, endosulfan, methoxychlor, and other chlorinated insecticides, 
oarbaryl, DEET, small amounts of rodenticides and insect repellents, hexachlorocyclohexane and lindane (production 
only), synergists, and others. 

Includes dithiocarbamates Including dodine, maneb, mercury compounds, PETD and others. 

^ Includes CDAA, methanearsonic acid's disodium salt and sodium salt, thiocarbamate and organophosphorus herbi- 
cides, sodium diohloropropionate, sodium TCA, and others. 

' Includes DDVP, disulfoton, ethion, malathion, naled, phorate, TEPP (production only), and others. 
^° Includes soil conditioners and fumigants, metaldehyde (which is a molluscioide), small quantities of rodenti- 
cides, and others. . 

Note: Sale of gamma Isomer content in benzenehexachloride and lindane is not publishable for 1966 because publics 
tion would reveal the operations of the individual producers. Production of ganma isomer content has not been 
publishable since 1963. 



MISCELLANEOUS CHEMICALS 55 

Production of pesticides and related products in 1966 amounted to 1,013 million pounds-- 
about 15 percent more than the 877 million pounds reported for 1965. Sales in 1966 were 822 
million poxmds, valued at $584 million, compared with 764 million pounds, valued at $497 mil- 
lion in 1965. 

The output of cyclic pesticides and related products included in the cyclic group amounted to 
777 million pounds in 1966--about 14 percent more than the 683 million pounds produced in 1965. 
Sales in 1966 were 605 million pounds, valued at $447 million, connpared with 582 million pounds, 
valued at $378 million, in 1965. 

Production of acyclic pesticides and related products in 1966 amounted to 236 million pounds, 
compared with the 195 million pounds reported for 1965. Sales in 1966 were 217 million pounds, 
valued at $137 million, compared with 182 million pounds, valued at $119 million, in 1965. 

Miscellaneous Chemicals 

The term miscellaneous chemicals comprises those synthetic organic products that are not 
included in the other use groups covered by this report. They include products that are employed 
in a great variety of uses: The number of chemicals used exclusively for only one purpose is not 
large. Among the products covered are those used for gasoline and lubricating oil additives, 
paint driers, photographic chemicals, tanning materials, flotation reagents, refrigerants, tex- 
tile polymers, sequestering agents, organic fertilizers, antifreeze chemicals, solvents, and 
acyclic intermediates. Statistics on production and sales of miscellaneous chemicals in 1966 are 
given in table 21A." 

Production of miscellaneous cyclic and acyclic chemicals in 1966 totaled 57. 3 billion pounds 
or 13 percent more than the output of 50. 8 billion pounds reported for 1965. Sales of miscellane- 
ous chemicals in 1966 amounted to 24. 5 billion pounds, valued at $3. 2 billion, compared with 
22.0 billion pounds, valued at $2.9 billion, in 1965. 

The total output of miscellaneous cyclic chemicals in 1966 was 1.4 billion pounds, or 20 
percent more than the output of 1 . 1 billion pounds, reported for 1965. Sales in 1966 totaled 739 
million pounds, valued at $271 million, compared with 625 million pounds, valued at $245 mil- 
lion, in 1965. In 1966 the most important groups of cyclic compounds were the lubricating oil 
additives, the output of which was 390 million pounds, and synthetic tanning materials, the output 
of which was 36 million pounds. 

Total production of miscellaneous acyclic chemicals in 1966 was 55.9 billion pounds or 12 
percent more than the output of 49. 7 billion pounds reported for 1965. Sales in 1966 totaled 
23. 8 billion pounds, valued at $2. 9 billion, compared with 21. 4 billion pounds, valued at $2. 6 
billion, in 1965. The statistics for acyclic chemicals have been regrouped primarily by chemical 
function. The order of precedence of these functional groups is generally that used in naming 
and indexing chemical pounds by Chemical Abstracts, but other important considerations are com- 
parability with statistics for earlier years and the need for groupings that will not reveal the 
operations of individual producers. Some of the groupings by use found in earlier reports have 
been omitted for 1966, as such groupings are difficult to maintain due to the variety of uses and 
frequent shifts in principal usage for many important items. 

In 1966, the most important groups of acyclic chemicals were the halogenated hydrocarbons, 
the nitrogenous compounds, iTionohydric alcohols, and aldehydes and ketones. Production of 
halogenated hydrocarbons, which are used as solvents, intermediates, refrigerants, and aerosol 
propellants, totaled 11.6 billion pounds. The most important chemicals in this group were 
dichloroethane (production of 3.6 billion pounds in 1966 compared with 2. 5 billion pounds in 
1965) and vinyl chloride (2. 5 billion pounds compared with 2.0 billion pounds). Output of nitro- 
genous compounds totaled 8. 9 billion pounds. The most important chemical in this group was 
urea (used principally in fertilizers and as a feed additive), production of which was 3.4 bil- 
lion pounds in 1966 compared with 2.6 billion pounds in 1965. 

Monohydric alcohols, which are used largely as solvents and intermediates, were the third 
largest group in 1966, with production of 8.8 billion pounds. The most important items in the 
group were synthetic methanol, production of 3. 3 billion pounds in 1966 compared with 2. 9 bil- 
lion pounds in 1965; synthetic ethyl alcohol, 1. 9 billion pounds compared with 2. billion pounds, 
and isopropyl alcohol, 1. 7 billion pounds compared with 1. 5 billion pounds. Aldehydes and 
ketones, which are also used largely as solvents and intermediates, were the next largest group, 
with production of 8. 3 billion pounds. The most important items in the group were formaldehyde, 
production of 3. 7 billion pounds in 1966 compared with 3. 1 billion pounds in 1965; acetaldehyde, 
1. 3 billion pounds compared with 1. 2 billion pounds; and av.etone, 1. 3 billion pounds compared 
with 1. 1 billion pounds. 



) uble 21B, pt. HI, which 11m these pcoducu and identifies the aunufacturers. 



56 SYNTHETIC ORGANIC CHEMICALS, 1966 

TABLE 21A. — Miscellaneous chemicals: U.S. production and sales, 1966 

■ Listed below are all miscellaneous chemicals for which any reported data on production or sales may be published. 
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data 
were reported.) Table 21B in pt. Ill lists alphabetically all miscellaneous chemicals for which data on production 
or sales were reported and identifies the manufacturer of each ] 



Production 



Grand total 

MISCELLANEOUS CHMICALS, CYCLIC 

Total - — 

Benzoic acid salts: Sodium benzoate, tech. and U.S.P 

Benzoyl peroxide 

Butyl benzoate 

Cyclopropane 

2j6-Di-tert-butyl-p-cresol: 

Food grade 

Tech — 

p-Dlmethoxybenzene (Dimethyl ether of hydroquinone ) 

Flotation reagents 

Gasoline additives, total^ 

N,N'-Di -sec-butyl -p-phenylenediamine 

N,N'-Disalioylidene-l,2-propanediamlne 

All other- - — — 

Hexamethylenetetramlne , tech 

lubricating oil and grease additives, total 

Oil-soluble petroleum sulfonate, barium salt 

Oil-soluble petroleum sulfonate, calcium salt 

Oil -soluble petroleum sulfonate, sodium salt 

All other , 

Morpholine 

Naphthenio acid salts, total^ * 

Calcium naphthenate 

Cobalt naphthenate 

Iron naphthenate 

Lead naphthenate 

Manganese naphthenate 

Zinc naphthenate 

All other - — 

Photographic chemicals : 

Benzotriazole 

2,5-Diethoxyi-4-morpholinobenzenediazonium chlorozincate- 
p-Diethylaminobenzenediazonium chloride (p-Diazo-N, N- 
diethylaniline) - zinc chloride 

N,N-Diethyltoluene-2,5-diamine, monohydrochloride 

Pinene (a- and (i-) 

Propyl gallate 

Tall oil salts, total^ 

Calcium tallate 

Cobalt tallate 

Lead tallate 

Manganese tallate 

All other 

Tanning materials, synthetic, total 

2-Naphthaleneeulfonlc acid, formaldehyde condensate 

and salts 

All other 

See footnotes at end of table. 



pounds 
57,252,6'i8 



9,'i93 

5,039 

635 

122 

7,310 

14,702 

918 

6,109 



1.000 
pounds 



2,731 

902 

14,954 



389,838 
41,i79 

132,256 
73,177 

142,926 

18,889 

23,317 

17^2" 

3,612 

296 

14,267 

1,652 

1,107 

491 



10,296 
2,792 
2,753 
3,608 
711 
432 
36,343 



61,643 
243,407 



50,084 
193,323 



20,127 
1,353 
3,069 
294 
12,621 
1,253 
1,040 
497 



10,202 
2,797 
2,728 
3,519 
682 
476 

35,702 



31,530 
4,172 



4,862 
8,429 



1,528 
1,455 
7,057 



10,006 
41,422 

8,209 

6,934 
593 

2,038 
100 

2,841 
460 
465 
437 



5,726 
1,957 



MISCELLANEOUS CHEMICALS 
TABLE 21A.-- Miscellaneous chemicals.- U.S. production and sales, 1966 --Continued 



57 



Chemical 


Production 


Sales 




(iiantlty 


Value 


Unit 
value 1 


MISCELLANEOUS CHHMICALS, CYCLIC- Continued 

Textile chemicals, other than surface -active agents, total 
l,3-Bi8(hyiJroxymethyl)-2-lJnidazolidone ( Dljnethylol 


1.000 
pounds 
2,441 


1.000 
pounds 
1,783 


1.000 
dollars 

1,277 


Per 
pound 

$0.72 


92 
2,349 

655,644 
55,883,982 


135 
1,648 

244,976 
23,810,310 


50 
1,227 

141,894 
2,890,825 


.37 
.74 

.58 
.12 




All other miscellaneoufl cyclic chemicals - — 

MISCELLANEOUS CHEMICALS, ACYCLIC 
Total - 




Cellulose Esters and Ethers 


1,026,063 


301,736 


122,596 


.41 






930,130 


211,213 


72,107 


.34 




All other - - 


179,826 
95,933 


211,213 
90,523 


72,107 
50,489 


.34 
.56 








48,736 
47,197 

456,986 


48,355 
42,168 

178,369 


20,758 
29,731 

37,582 


.43 
.70 

.21 


Lubricating Oil Additives 






100,819 

3,132 

23,073 

329,962 

8,869,388 


49,268 

129,101 

4,323,581 


12,265 
25,317 

420,026 


.25 


Sulfurized lard oil 


Nitrogenous Compounds 


.20 

.10 






716,074 
784,337 


318,169 
197,237 


40,285 
58,130 


.13 
.29 








1,483 

6,356 
25,393 
11,078 
105,216 
634,811 
2,991 
... 

299 

'2,303 
207,794 


881 
1,862 
6,685 
17,636 
10,982 
62,712 
96,479 
2,419 
141,809 

316 

2,854 

1,792 

170,977 


408 
816 
2,526 
4,932 
2,029 
8,351 
39,068 
2,698 
34,997 

376 
1,199 
1,133 
28,477 


.46 
.44 
.38 
.28 
.18 
.13 
.40 
1.12 
.25 

1.19 
.42 
.62 

.17 


Di-n-butylamine 

Dl-n-propylamine 












2-Chloro-N, N-dlmethylethylamine (Dimethylaminoethyl 












70,262 
79,246 
58,286 
401,128 
44,904 


57,581 
55,831 
57,565 

'29,296 


10' 538 
7,908 
10,031 

'ii,919 


.18 

.14 
.17 

.41 






2-MBthyllactonitrile (Acetone oyanohydrin ) — 

Nitriloacida and salts, total 

(Ethylenedinltrilo)tetraacetic acid, disodium salt 

(Ethylenedlnitrilo)tetraacetio acid, tetrasodium salt— 

(Ethylenedinitrilo)tetraaoetic acid, trisodlum salt 

(N-lfydroxyethylethylenedinltrllo)trlaoetic acid. 


24,773 
473 

4,187 
14,892 
1,001,689 
3,042 
5,249 


685 

15,118 
505 

3,405 
9,583 

3,169 


437 

5,622 
219 

1,612 
4,029 

"2,420 


.64 
.37 
.43 

.47 














.76 





See footnotes at end of table. 



58 SYNTHETIC ORGANIC CHEMICALS. 1966 

TABLE 21 A. --Miscellaneous chemicals.- U.S. production and sales , ii'66--Continued 



Chemical 



Production 



Sales 



MISCELLANEOUS CHE^aCALS, ACYCLIC— Continued 
/Vi trogenous Compounds - -Continued 

Sarcosine and salt 

Stearamide 

Urea in compounds or mixtures (100^ basis), total 

In feed compounds 

In liquid fertilizer 

In solid fertilizer 

All other 

All other nitrogenous compounds 

Acids, Acyl Halides and Anhydrides 

Total— 

Acetic acid, synthetic, 1005i^ 

Acetic anhydride, 100^ 

Acrylic acid 

Adipic acid - 

Butyric acid 

Chloroacetic acid, mono- 

Decanoyl chloride 

Formic acid, 90^— - 

Fumaric acid 

Gluconic acid, tech 

Lauroyl chloride 

Maleic anhydride 

Oxalic acid— - • 

Balmltoyl chloride 

Propionic acid 

All other acids, acyl halides and anhydrides 

Salts of Organic Acids 

Total - 

Acetic acid salts, total 

Ammonium acetate 

Cfepper acetate 

Potassium acetate 

Sodium acetate 

Zinc acetate 

Zirconium acetate 

All other — ■ 

2-Ethylhexanoio acid (a -Ethylcaproio acid) salts, total- 
Calcium 2 -ethylhexanoate 

Cobalt 2 -ethylhexanoate 

l£ad 2 -ethylhexanoate 

Zino 2 -ethylhexanoate 

Zirconium 2 -ethylhexanoate 

All other— 

Formic acid, aluminum salt 

Gluconic acid, sodium salt, tech 

linoleic acid salts, total 

Calcium linoleate 

Cobalt linoleate 

All other 

Jferoaptoacetic (Thioglycolic) acid, salts 

Oleic acid salts'— - 

Oxalic acid salts 

Palmitic acid aluminum salt 

Polyacrylic acid salts 

Propionic acid salts, total 

Calcium propionate 

Sodium propionate 



pounds 
1,751 
1,327 
3,432,703 



385,961 
1,331,692 
1,387,079 

327,971 
2,263,797 



,596,825 
62,477 
964,457 

66,094 

1,362 

27,208 

46,125 

3,828 

10,756 

168,575 

22,854 

281 

36,989 

687,066 



27,634 



3,351 
17,401 
286 
340 
5,321 
4,262 



701 
241 
413 
814 
2,093 
337 



2,806 
12,311 



12,311 



1 . 000 
pounds 

1,009 

3,263,426 



590 
135,731 



334,053 

1,244,652 

1,415,091 

219,630 

191,108 



11,080 

88,585 

979 



25,880 
37,084 
3,677 



25,391 



610 

186 

3,206 

15,716 

459 

319 

4,895 

3,235 



■33r 



3,955 

455 

5,310 

3,527 
13,991 



$,288 
4,703 



14,570 
51,131 
60,861 
9,169 

102,071 



3,180 
18,803 

200 



3,361 
6,313 
1,233 

15,106 
4,713 



5,612 



228 

135 

710 

2,449 

199 

114 

1,777 

2,474 



149 



6,423 

329 

1,566 



See footnotes at end of table. 



MISCELLANEOUS CHEMICALS 
TABLE 21A.-- Miscellaneous chemicals.- U.S. production and sales , i 966 --Continued 



59 



KQSCELLANEOUS CHMICALS, ACYCLIC— Continued 

Salts of Organic /tclds- -Continued 

Stearic acid salts, total^° - 

Aluminum stearates, total 

Aluminum dlstearate 

Aluminum monostearate 

Aluminum tristearate 

Calcium stearate 

Lead stearate 

Lithium stearate 

Magnesium stearate 

Zinc stearate -- 

All other - - - 

All other salts of organic acids 

Aldehydes and Ketones 

Total- - — 

Acetaldehyde 

Acetone, total 

From isopropyl alcohol 

All other - 

2-Butanone (Methyl ethyl ketone) 

Chloral (Trlohloroacetaldehyde) 

Formaldehyde (37^ by weight) 

<t-Itydroxy-'i-methyl-2-pentanone (Diacetone alcohol) 

4.-Methyl-2-pentanone (Methyl isobutyl ketone) 

All other aldehydes and ketones 

Alcohols, Monohydnc, Unsubstituted 
Total - - - - 

Alcohols, C9 or lower, total 

Butyl alcohols : 

n-Butyl alcohol (n-Propylcarbinol) 

Isobutyl alcohol ( Isopropylcarbinol ) 

Ethyl alcohol, synthetic^^ 

2-Ethyl-l-hexanol 

Iso-octyl alcohols 

Isopropyl alcohol 

Methanol, synthetic 

All other, including mixtures 

Alcohols, Cio or higher, total 

Isodecyl alcohol 

l-Hexadecanol (Cetyl alcohol)- 

All other, including mixtures 

Polyhydnc Alcohols and Their Esters and Ethers 

Total - -. 

Polyhydric alcohols, total 

Ethylene glycol 

Pentaerythritol 

Propylene glycol (1,2-Propanedlol) 

Sorbitol — - - 

All other 

Polyhydric alcohol esters 

Polyhydric alcohol ethers, total 

2-Butoxyethanol (Ethylene glycol monobutyl ether) 

2-(2-Butoxyethoxy}ethanol (Diethylene glycol monobutyl 

ether) 

Diethylene glycol 

Dipropylene glycol 

See footnotes at end of table. 



1.000 
pounds 
«,871 



4,2^1 

941 

6A3 

18, 977 

422 

452 

2,458 

11,527 

4,210 

121,808 



1,300,450 
1,330,178 



L,020 

449,158 

399,077 

70,456 

3,712,568 



3,344,716 



396,934 

92,918 

1,881,275 

318,902 

99,994 

1,714,308 

3,268,923 

571,462 

468,571 



122,143 

1,673 

344,755 



2,890,675 



2,081,156 
80,836 
258,826 
65,801 
404,056 
134,187 
1,102,365 



69,333 



181,942 
36,601 



1.000 
40,303 



13,173 



5,606 

4,090 

891 

625 

19,295 

436 

494 

2,399 

10,455 

1,618 

82,660 



242,376 
841,222 



478, ^U 
362,778 
351,783 

1,359,981 
30,818 
167,977 
226,636 



4,004,199 



234,469 
73,947 
1,175,924 
148,660 
98,721 
695,079 
1,373,497 
203,902 
260,645 



72,476 

1,408 

186.761 



1,886,163 



1,250,384 
65,603 
215,480 
52,097 
302,599 
140,767 
843,941 



6^,738 

12,142 
137,354 
34,146 



2,044 
1,474 
348 
222 
5,236 
182 
261 



3,794 

768 

22,184 



24,943 
15,254 



36,751 
3,877 
20,635 
31,525 



22,111 
5,577 
72,902 
17,027 
11,711 
41,565 
44,776 
26,434 
38,549 



8,798 

455 

29,296 



211,623 



101,888 
15,351 
21,120 
10,339 
62,925 
27,868 

137,356 



11,164 

3,200 
13,649 
3,849 



SYNTHETIC ORGANIC CHEMICALS, 1966 
TABLE 21A.— Miscellaneous chemicals; U.S. production and sales, i 566 —Continued 



MISCELLANEOUS CHBOCALS, ACYCLIC— Continued 






Mcohols and Their Esters and Others- -Continued 



Polyhydrio alcohol ethers — Continued 

2-Ethoxyethanol (Ethylene glycol monoethyl ether) 

2-C2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl 

ether) • 

2-[2-(2-Ethoxyethoxy)ethoxy]ethanol (Triethylene glycol 

monoethyl ether) 

Glycerol tri (polyoxypropylene ) ether 

2-Methoxyethanol (Ethylene glycol monomethyl ether) 

2-(2-Methoxyethoxy)ethanol (Diethylene glycol mono- 
methyl ether) 

2 - [ 2 - ( 2 -Me thoxyethoxy ) ethoxy ]ethanol ( Triethylene glycol 

monomethyl ether) 

l-Methoxy-2-propanol 

Polyethylene glycol 

Polypropylene glycol 

Triethylene glycol 

All other ethers of polyhydric alcohols 

Esters of Monohydrlc Alcohols 

Total - - 

Butyl acetates, total 

n-Butyl acetate 

All other 

Dibutyl maleate 

Dllauryl 3,3' -thiodlpropionate 

Ethyl acetate, 85^ - 

Etl^l acrylate 

Ethylene carbonate 

Iso-octyl mercaptoacetate 

Isopropyl acetate 

Methyl acetate 

Phosphorus acid esters, not elsewhere specified 

Vinyl acetate, monomer ■ 

All other esters of monohydrlc alcohols 

Halogenated Hydrocarbons 

Total 

Carbon tetrachloride 

Chlorinated paraffins 

Chlorodifluoromethane 

Chloroethane (Ethyl chloride) 

Chloroform 

Chloromethane (Methyl chloride) 

Diohlorodifluorome thane 

1,2-Dichloroethaiie (Ethylene dichloride) 

Dichloromethane (Methylene chloride) 

1,2-Dichloropropane (Propylene dichloride) 

Diohlorotetrafluoroe thane 

Tetrachloroethylene (Perchloroethylene) 

1,1,1-Trichloroethane (Methylchloroform) 

Triohloroethylene 

Triohlorofluoromethane 

Vinyl chloride, monomer (Chloroethylene) 

All other halogenated hydrocarbons 

See footnotes at end of table. 



1.000 
pounds 



173,896 
96,26A 

8,837 

5,245 
10,603 
41,362 

100,558 
59,065 

284,743 



129,543 



84,560 
44,983 
6,233 
1,537 
121,596 
129,995 

"2,369 
47,636 
8,785 
48,461 
605,544 
810,577 



11,564,094 



647,959 
60,051 

676,953 
178,953 
236,889 
286,326 
3,616,599 
267,213 
76,283 

462,678 
242,943 
480,219 
170,350 
2,499,549 
1,661,129 



pounds 
49,437 



3,773 
149,250 
77,260 



36,492 
86,522 
49,894 
118,957 



135,215 
S6,403 
48,812 



1,400 
114,909 

58,656 
1,064 
2,150 

41,964 

30,778 
254,239 
299,997 



615,360 
60,734 
56,472 
274,740 
143,558 
104,224 
266,894 
291,029 
225,833 

17,211 
424,797 
249,683 
462,853 
155,004 
836,172 
343,133 



1.000 
dollars 

7,842 

4,210 

538 
26,760 
12,814 



8,875 
14,147 

8,307 
22,001 



4,518 

1,368 
11,218 
12,159 
407 
1,493 
4,577 

12,790 
27,204 
71,744 



509,409 



42,201 
7,936 
35,640 
18,315 
10,815 
7,473 
75,275 
12,261 
22,494 

9,928 
34,491 
27,853 
39,095 
31,147 
49,552 
84,933 



MISCELLANEOUS CHEMICALS 
TABLE 21A. — Miscellaneous chemicals.- U.S. production and sales , i 566- -Continued 



Chemical 



Production 



Sales 



KQSCELLAtlEOUS CHIMICALS, ACYCLIC— Continued 

All Other Miscellaneous Acyclic Chemcals 

Total— - 

2-Butanone peroxide 

tert-Butyl hydroperoxide 

tert-Butyl peroxide (Di-tert-butyl peroxide) 

Carbon disulfide 

2-Chloroethanol (Ethylene ohiorohydrin) 

Deoanoyl peroxide 

Epoxides, ethers, and acetals, total 

Ethylene oxide 

Ethyl ether, all grades 

Isopropyl ether 

Methyl ether (Dimethyl ether) 

Propylene oxide 

All other epoxides, ethers, and acetals 

Ifluroyl peroxide 

Phosgene (Carbonyl chloride) 

Sodium formaldehydesulfoxylate 

Sodium methoxide (Sodium methylate) 

Tetraethyllead - — 

Tetramethyllead 

Zinc formaldehydesulfoxylate 

All other- - 



1,000 
pounds 
5,480,678 



1.000 
pounds 
1,947,276 



585,070 



176 

1,367 

752,296 

28,446 



179 

1,367 

544,818 



2,782 

311 
1,943 
22,362 

1,259 



2,326,901 
107,222 

11,125 
710,471 
262,043 

1,891 
329,751 

5,224 

5,134 
543,406 
109,328 

1,248 
281,725 



1,791 

5,070 
3,741 

557,740 
95,648 
1,246 

246,712 



29,598 

6,032 

396 



1,137 

1,199 

299,276 

49,865 

577 

157,937 



1.52 

1.74 
1.42 



Calculated from rounded figures. 
^ Statistics exclude production and sales of trlcresyl phosphate. Statistics on tricresyl phosphate are given in 
the section "Plasticizers." 

' Quantities are given on the basis of solid naphthenate, tallate, or linoleate content. 

* Statistics exclude production and sales of copper napthenate. Statistics on copper naphthenate are given in the 
section "Pesticides and Related Products." 

' Statistics exclude production and sales of fatty amines. Statistics on fatty amines are given in the section 
"Surface-Active Agents." 

* Production of urea in primary solution totaled 3,543,436 thousand pounds. 
'' Includes estimated values for sales of urea in nitrogen compounds. 

* In addition, sales of recovered acetic acid totaled 75,812 thousand pounds, valued at 4,359 thousand dollars. 
' Statistics exclude production and sales of potassium and sodium oleate. Statistics on these oleates are 

Included in the section "Surface-Active Agents." 

^° Statistics exclude production and sales of potassium and sodium stearates. Statistics on these stearates are 
included In the section "Surface-Active Agents." 

•'■■' Statistics on production of ethyl alcohol from natural sources by fermentation are issued by the Alcohol 
Tax Unit, U.S. Internal Revenue Service. 



PART m. LIST OF INDIVIDUAL PRODUCTS, BY GROUPS, AND NAMES OF 
MANUFACTURERS 

Thi8 section of the report consists of (1) a series of tables that supplement the statistical 
information given in parts I and II, and (2) a Directory of Manufacturers. The tables with num- 
bers that include the letter "B" supplement the tables in part I and II with numbers that include 
the letter "A"; for example, table 8B in part III supplements table 8A in part II. 

Each table in part III lists the individual items in each group for which data on production 
or sales were reported for 1966. The tables include data on only those chemicals for which 
the volume of production or sales in 1966 exceeded 1,000 pounds or for which the value of 
sales exceeded $1,000. Where separate statistics for an item are given in the tables in part I or 
part II, an asterisk (*) precedes the name of the item in the tables in part III. The manufacturers 
of each product are indicated by identification codes which are listed in the Directory of Manu- 
facturers (table 22). A few companies, however, have specifically requested that they not be 
identified as having produced or sold certain items. These manufacturers are indicated by a 
small letter "x" in the tables. 

Tar Crudes 

TABLE 4B. — Tar crudes for which U.S. production or sales were reported, identified by manufacturer, 1966 

[Tar crudes for which separate statistics are given in table i,k are marked below with an asterisk (*); products not 
so marked do not appear in table <iA because the reported data are accepted in confidence and may not be published. 
Manufacturers' identification codes shown below are taken from table 22. Table 22 identifies all U.S. producers of 
tar crudes (except producers that report to the Division of Bituminous Coal, U.S. Bureau of Mines)] 



Manufacturers ' identification codes 
(according to list in table 22)^ 



»Crude light oil 

Light-oil distillates: 

»Benzene, specification and industrial grades 

»Toluene, specification and other grades 

^Xylene, all grades 

Solvent naphtha 

»A11 other light-oil distillates -- 

Pyridine crude bases 

»Naphthalene , crude, solidifying at-- 

»Less than 7<i° C 

»'li,° C. to less than 76° C 

»76° C. to less than 79° C 

Crude tar-acid oils having a tar-acid content of-- 

5«t to less than 24^ 

2^1> to 51* - 

Cresylic acid, crude 

»Creosote oil (Dead oil): 

»Distillate as such— 

•Creosote in coal-tar solution 

All other distillate products 

»Tar, road 

•Tar for other uses: 

Crude 

Refined 

Pitch of tar: 

Soft and medium (water softening points less than 
110° F., and 110° F. to 160° F.). 

»Hard (water softening point above 160° F.) 

Pitch-of-tar coke and pitch emulsion 



CBT.'' 

ACY, KPP. 

ACY, KPP. 

ACY, KPP. 

ACY, NEV, PAI. 

ACP, PAI. 

ACP, KPT. 

COP. 
KPT. 

ACP, KPT, PRD, RIL. 

ACP, COP, KPT, RIL. 

ACP, RIL. 

ACP, KPT, PRD. 

ACP, CBT, COP, HUS, KPT, RIL, WTC. 

ACP, JEN, KPT, RIL. 

ACP, KPT, PAI. 

ACP, KPT, RIL, WTC. 

ACP, KPT, RIL. 

KPT, RIL. 

ACP, CBT, COP, KPT, RIL. 

ACP, COP, HUS, JEN, KPT, RIL. 

JEN, RIL. 



Does not include manufacturers' identification codes for producerE_ that report to the Division of Bituminous 
Coal, U.S. Bureau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey, 
August 29, 1967, entitled "Coke Producers in the U.S. in 1966." 

' Crude light oil production and sales of this company are not included with the U.S. Bureau of Mines figures 
given in table Ak. 



SYNTHETIC ORGANIC CHEMICALS, 1966 
Crude Products From Petroleum and Natural Gas for Chemical Conversion 



TABLE 5B. --Crude products from petroleum and natural gas for chemical conversion for which U.S. production 
or sales were reported, identified by manufacturer, 1966 

[crude products from petroleum and natural gas for chemical conversion for which separate statistics are given in 
table 5A are marked below with an asterisk (»); products not so marked do not appear in table 5A because the 
reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown be- 
low are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the 
designated product] 



Manufacturers' identification codes 
(according to list in table 22) 



ARQMATICS AND NAPHTHENES 

•Benzene (except motor grade): 

•Benzene, 1° 

•Benzene, 2° 

Cresylio acid, crude 

•Naphthalene, all grades 

•Naphthenic acids: 

Acid number lower than 150 

•Acid number 150-199 

Acid number 200-22'4 

Acid number 225-2-^9 

•Sodium carbolate and phenate, crude 

•Toluene : 

•Nitration grade, 1° 

•Pure commercial grade, 2° 

•Solvent grade 

•All other - 

•Xylenes, mixed: 

Aviation grade 

•3° — 

5= — - 

All other 

•All other aromatics, naphthenes, distillates and 
solvents 

ALIPHATIC HYDROCARBONS 

Ci hydrocarbon: Methane 

•C2 hydrocarbons: 

•Acetylene 

•Ethane 

•Ethylene 

C2 and Cj hydrocarbons, mixed 

•C3 hydrocarbons; 

•Propane 

•Propylene 

•C4 hydrocarbons : 

•1,3-Butadiene, grade for rubbers (elastomers)-' 

•Butadiene and butylene fractions 

•n-Butane — 

1-Butene 

2-Butene 

»1-Butene and 2-butene mixture 

•Isobutane 

•Isobutylene 

All other — 

•C5 hydrocarbons: 

Isopentane (2-Methylbutane ) 

•Ispprene (2-Methyl-l,3-butadiene) 

n-Pentane 



ACU, APR, ASH, ATR, CCF, COR, CSD, DLH, DXS, ENJ, GOC, 
GRS, MOC, MON, PLC, RIG, SHO, SKO, SM, SNT, SOG, SUN, 
TOC, TX, UOC, VEL, VPT. 

ACC, CO, DOW, SHO, SOC. 

ATR, PRD, RIC, SHO. 

ASH, COL, MON, SUN, TID. 

RIC, SUN, TX. 

PRD, RIC, SM, SOC, SUN. 

PRD, RIC, SM, SOC. 

SOC. 

ATR, GOC, SIN. 



DOW, MON, RIC. 
CO, FG, SKO. 

ACC, COR, CSD, CSO, DXS, ELP, GRS, PLC, RIC, SHO, SM, 
SOC, TOC, TX, VPT. 

CSD, CSO, SOG. 

ATR, COR, DLH, MOC, MON, SNT, UOC. 
ASH, SIN, SUN, TX. 

CCP, COR, CSD, CSO, GRS, LEN, RIC, SHO, SM, SOC, SOG, 
SUN, TOC. 

ACC, DUP, ELP, ENJ, FG, GOC, JCC, LEN, MOC, MON, QMC, 
PLC, SHC, SM, SOC, SOG, SOI, USI, VPT. 



CCP, MON. 

ACY, DOW, DUP, MNO, MON, UCC, x. 

ACU, CCP, CSO, ENJ, MON, PAN, SHC, SHO, SM, SOI, 

UCC, USI. 
BFG, CBN, CCP, CSO, DOW, DUP, EKX, ELP, ENJ, GOC, JCC, 

KPP, MON, QMC, PLC, RIC, SHC, SM, SNO, UCC, USI. 
COR, GYR, MON, PLC. 

AMO, APR, ASH, CCP, CSD, CSO, DXS, ENJ, GOC, GRS, QMC, 

PAN, PLC, SHM, SHO, SIN, £M, SNT, SOG, SOI, SPI, UCC, 

UOC, USI. 
AMO, ASH, BFG, CBN, CCP, CSO, DO*, EKX, ELP, ENJ, GOC, 

JCC, MOC, MON, PLC, RIC, SHC, SHO, SIN, SIO, SM, SNT, 

SOG, SOI, SPI, SUN, UCC, UOC. 

CBN, CPY, DOW, ELP, ENJ, FRS, GGC, ILC, MON, PLC, PTT, 

SHC, SHO, SM, SOC, SPI, TID, TUS, UCC. 
DO*, GOC, GYR, MOC, PLC, PTT, SHC, SJIO. 31.,, "., SOC, 



SM, SNT, SOC, SOG, 



SPI. 
COR, CSD, DXS, GRS, OMC, PAN, SHO, 

SOI, UCC, USI. 
GOC, PLC, PTT. 
MON, PLC, PTT. 

CSO, ENJ, GOC, PLC, PTT, SHO, SOC, SPI, TX, UOC. 
CCP, ELP, ENJ, GRS, QMC, PAN, PLC, SHO, SM, SDl, 

UCC, USI. 
DXS, ENJ, PTT, SIN, UOC. 
APR, BPG, ENJ, JCC, MON, PLC, SM, SOI, UCC, USI. 

PLC, SM, SOI, UCC. 
ENJ, GYR, SHC. 
APR, MON, PLC. 



CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS 



65 



-Crude products from petroleum and natural gas for chemical conversion for which U.S. production 
or sales were reported, identified by manufacturer, 1966 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



ALIPHATIC HYDROCARBONS--Continued 
K;, hydrocarbons--Continued 

All other — 

Cj hydrocarbons: 

»Hexane 

Neohexane (2,2-Dimethylbutane) 

All other— — -- 

C7 hydrocarbons: 

n-Heptane 

»Heptenes, mixed 

All other - 

Cg hydrocarbons: 

»Dlisobutylene (Diisobutene) 

n-Octane 

2,2,'*-Trimethylpentane (Iso-octane) 

All other 

I^rocarbona, C9 and above: 

Eioosane 

»Nonene ( Tripropylene J 

»Polybutene 

»Tetrapropylene 

Tridecene concentrate 

Trilsobutylene 

All other 

»A11 other aliphatic hydrocarbons and derivatives : 
Ifydrocarbons : 
»Alpha olefins--Molecular weight ranges: 

C6-C7 

Cs-Cio 

Cll-Ci5 

All other 

Ethane -ethylene 

Propane -propylene mixture 

»%drocarbon derivatives : 

1-Butanethlol 

tert-Butyl-mercaptan (2-Methyl-2-propanethiol) 

Di-tert-butyl disulfide - 

Ethyl meroaptan (Ethanethlol) 

Isopropyl mercaptan 

Methyl mercaptan (Methanethiol) 

tert-Octyl mercaptan 

n-Propyl mercaptan (l-Propane thiol) 

All other 



ATR, 
EN J, 
GRS, 



ENJ, GYR, MON, PLC, SHC, USI. 

PLC, SOG, UOC. 

PLC. 



PTT, IX. 

PLC. 

PLC. 



AMO, ATR, ENJ, GOC, RIC, UOC. 

ACC, CSD, SOC, SOI. 

CO, DXS, ENJ, GOC, MOC, RIC, SNT, SOC, SUN, TX, UOC. 

ENJ. 

ATR. 

CO, ENJ, GOC, HOU, KEN, PLC, SOC, SUN, TID, x. 



GOC, GYR, PLC, SOC. 

GOC, SOC. 

ENJ, GOC, SOC. 

EKX, GOC, SOC. 
TX. 



GOC, TX. 



PLC. 



PLC. 

PAS, PLC. SOC. 

PAS, SOC. 

ACC, PAS. 

PAS, PLC. 

PAS, PLC. 

EKX, PAS, PLC, SOC, UCC. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



Cyclic Intermediates 



TABLE 7B. --Cyclic intermediates for which U.S. production ( 
manufacturer, 1966 



sales were reported, identified by 



[Cyclic intermediates for which separate statistics are given in table 7A are marked below with an asterisk (»); 
cyclic intennediates not so marked do not appear in table 7A because the reported data are accepted in confidence 
and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies 
that the manufacturer did not consent to his identification with the designated product] 



Aceanthryleno[2,l-a] aceanthrylene-5,13-dione 

3-Acetaraido-l-{'4-acetamido-2-hydroxy-5-nltrophenylazo)- 

2-naphthol. 

5-Acetamldo-2-aminobenzenesulfonic acid 

3 -[ ( 2-Acetamido-4 -aminophenyl) azo ] -1, 5 -naphthalenedisul- 

fonic acid. 

.^-Acetara.do-J-chlcroanthraquinone 

a-Acetamido-p-toluenesulfonamide 

•Acetanilide, tech 

p-Acetanisidide 

Acetic acid, phenyl ester 

Acetoacetanilide 

o-Acetoacetanisidide 

o-Acetoacetotoluidide 

2 ',4'-Acetoacetoxylidlde 

1' -Acetonaphthone 

Acetone phenylhydrazone 

p-Acetophenetldide 

•Acetophenone , tech 

p-Acetotoluidide 

N-Acetylanthranilic acid 

p-AcetylbenzenesuUonamide 

p-Acetylbenzenesulfonic acid, sodium salt 

p-Acetylbenzenesulfony lure thane 

l-(N-Acetyl)methylamino-^-bromoanthraquinone 

N-Acetylsulf anilic acid, sodium salt 

N-Acetylsulf anilyl chloride 

Adenine 

Adenine bisulfate- — ■ 

»Alkylbenzenes: 

Dodecylbenzene (including tridecylbenzene) : 

Straight chain - ■ 

Other - 

Other alkylbenzenes : Straight chain 

Alkylphenols , mixed 

Alkylpiperazines , mixed 

Alkylpyridine 

[o-(Allylcarbamoyl)phenoxy] acetic acid 

6-Allyl-o-cresol 

a-dl-5-Allyl-6-lmino-l-methyl-5-(l-methyl-2-pentynyl)- 

barbituric acid. 
a-dl-5-Allyl-5-( l-methyl-2-pentynyl) -1-methylbarbituric 

acid. 

N-Allylsalicylamide 

Aminoaceanthryleno[2,l-a] aceanthrylene-5,13-dlone 

3 '-Aminoacetanilide 

*A '-Aminoacetanilide ( Acetyl -p-phenylenediamine) 

3 '-Aminoacetophenone 

»5-Amlno-2-(p-aminoanilino)ben2enesulfonlc acid 

l-Amino^-(3-aminow;-sulfoanilino)-9,10-dlhydro-9,10- 

dioxo-2-anthracenesulfonic acid. 
l-Amino^-(A-amino-3-sulfoanilino)-9,10-dlhydro-9,10- 
dioxo-2-anthracenesulfonic acid. 

5-Amino-2-anilinobenzenesulfonlc acid 

2-(p-Aminoanilino) -5-nitrobenzenesulfonlc acid 

3-Amlno-p-anlsanilide 

5-Amino-2-o-anisidinobenzenesuli'onic acid 

»l-Aminoanthraquinone and salt 

»2-Aminoanthraquinone and salt 

N-Cii-Amino-l-anthraquinonyl) anthranlllc acid 

N-(5-Amino-l-anthraquinonyl)anthranllic acid 

N-(8-Amlno-l-anthraquinonyl) anthranlllc acid 

•6-Amino-3,4'-azodiben2enesulfonic acid (C.I. Acid 
Yellow 9) . 
8-Amlnobenz[i]acridan-12-one 



SDW. 

CTN, EKT, MRK, SAL, SW. 

OAF. 

UCC. 

FMP, UCC. 

FMP, SDH, UCC. 

FMP, UCC. 

FMP. 

GIV. 

DUP. 

AAP. 

ACP, SKO, UCC. 

ACY. 

DUP. 

LIL. 

LIL. 

LIL. 

AAP. 

ALL. 

ACY, CTN, MRK, SAL. 



ATR 


CO, 


MON, 


NAC, PLC 


CO, 


soc. 






CO, 


soc. 






CJiF 


ORO. 






HOU. 








UCC. 








LIL. 








ICO. 








LIL. 








LIL. 








SDW. 








ICI. 








GAF, 


TRC. 






DUP. 


r^, 


NAC 


TRC. 


CTN, 


SDH. 






ere, 


GAF, 


TRC 


YAW. 


TRC. 









AAP, ACY, DUP, GAF, ICI, MAY, NAC, TRC. 
ACY, DUP, GAF, NAC, TRC. 



AAP, ACY, CM}, DUP, IHC. 



CYCLIC INTERMEDIATES 



■Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, J566— Continued 



Manufacturers' Identification codes 
(according to Ust in table 22) 



p-Aminobenzamide 

»l-Amino-4-benzaiiiidoanthraquinone 

»l-Anilno-5-benzamldoanthraquinone 

'i'-[P-(p-A'iiinobenzaiiildo)benzainido]-^-hydroxy-2-naphthalene- 
sulfonic acid. 

»7-(p-Amlnobenzaniido) -4-hydroxy-2-naphthalenesulf onic acid — 
7-(p-Aminobenzaiiiido) -5-hydroxy-3-naphthalenesulfonic acid — 

3 '-Aminobenzanilide 

<i'-Aminobenzanilide 

»2-Amino-p-benzenedisulf onic acid [SO3H-I] 

o-Aminobenzene thiol 

2-Aminobenziinidazole 

5 -Ami no-2-benzimidazolinone 

p-Amlnobenzoic acid, tech 

p-Amlnobenzoic acid, butyl ester 

p-Aminobenzoic acid, 2-(dimethylaiiilno)ethyl ester 

4-Aminobenzophenone 

2-Amino-6-benzothiazoleoarboxylic acid 

2-(m-Aminobenzoyl)-o-acetanisidide 

p-Amino-N-benzyl-N-ethylbenzenedlazonium chlorostannate 

p-Amino-N-benzyl-N-ethylbenzenediazonium chlorozincate 

2-Aiiiino-l-bromo-3-chloroanthraquinone 

»l-Amino-4-bromo-9,10-dihydro-9,10-dioxo-2-anthracene- 
sulfonlc acid and sodium salt. 

»l-Amino-2-broino-^-hydroxyanthraquinone 

l-Ajnlno-<i-bromo-2-methylanthraquinone 

»l-Amino-2-bromo-A-p-toluidinoanthraquinone 

»l-Aniino-5-ohloroanthraquinone 

l-Amino-S-chloroanthraquinone 

2 -Ami no-1-chloroanthraquinone 

2-Amino-3-chloroanthraquinone 

4-Amlno-6-chloro-m-benzenedisulf onamide 

<l-Aiiiino-6-ohloro-m-benzenedisulfonamide hydrochloride 

5-Amlno-2-chlorobenzoic acid 

2 -Ami no -5 -chlorobenzophenone 

2-Amlno-6-chlorobenzothlazole hydrochloride 

»o-(3-Amino-A-chlorobenzoyl) benzoic acid 

2-Amino-5-ohloro-p-cumenesulfonic acid 

2-Amino-5-chloro-<i-ethylbenzenesulfonic acid 

»3-Amino-5-chloro-2-hydroxybenzenesulf onic acid 

2-Amino-^-chloro-6-nitrophenol 

2-Amino-^-chlorophenol 

2-Aiiiino-6-chloropyrazine 

3-Amino-6-chloropyTidazine 

2-Aiiiino-5-chloro-p-toluenesulfonic acid [S03H=1] 

»6-Amino-4-chloro-m-toluenesulfonic acid [S03H=1] 

2-Amino-p-cresol 

»l-Amino-2,A-dibromoanthraquinone 

5(and 8) -Aniino-6,8(and 5,7) -dibromo-9,10-dihyd^o-9,10- 
dioxo-l-anthracenesulf onic acid. 

2-Aiiiino-4,5-dichlorobenzenesulfonic acid 

6-Amlno-2,'»-dlchloro-m-cresol 

';'-Aiiiino-2',5'-diethoxybenzaniHde 

l-Amino-9 , lO-dihydro-9 , lO-dioxo-2 -anthracenesulf onic acid — 
5(and 8) -Ainino-9,10-dihydro-9,10-dioxo-l-anthracenesulfonlc 

acid. 
l-Aiiiino-9,10-dihydro-9,10-dioxo-2-anthroic acid — 

*l-Ajiiino-9,10-dihydro-9,10-dioxo-4-p-toluenesulfonaiiildo-2- 
anthracenesulfonlo acid, sodium salt. 
5-Amiuo-4,5'-dihydroxy-3,'4.'-[(2-methoxy-5-methyl- 

p-phenylene )bis ( azo ) ] -di-2, 7-naphthalenedisulf onic acid, 
5 ' -benzenesulf onate . 

2-Amino-i-(a,a-dlme thy Ibenzyl) phenol 

2-Amlno-<i,6-dinltrophenol and salt 

3-Amino-4-ethoxyacetanilide 

3-Amlno-9-ethylcarbazole 

p-Amino-N-etl^rl-N-hydroxyethyl benzenediazonlum 
chlorozincate. 

3-Amino-a-ethylhydrocinnamic acid 

p-Amino-N-ethyl-N-1-naphthy lbenzaLu.de 

2-Amino-N-ethyl-5-nitrobenzenesulfonanllide 

Aminoethylpiperazine 



SDH. 

ACY, MAY, NAC, TRC. 
GAF, ICI, NAC, TRC. 
CMG, DUP. 

CM}, DUP, GAF, NAC. 

VPC. 

DUP. 

GAF. 

DUP, GAF, MAC. 

FMT, GAM. 

EK. 

DUP. 

DUP, Lat. 

GAF. 
SDW. 
DUP. 
DUP. 
GAF. 
ESA. 
ESA. 
ICI. 
AAP, 



GAF, ICI, NAC, TRC. 



AAP, DUP, GAF, ICC, TRC. 

ICI. 

GAF, ICI, TRC. 

ACY, DUP, ICI, MAY, NAC, TRC. 

DUP. 

DUP, GAF. 

GAF, ICI, TRC. 

ABB. 

ABB. 

TRC. 

COK, ICI. 

DUP. 

AAP, GAF, ICI. 



ACY, SW. 

CXC, NAC, TRC. 

CMi. 

GAF, MEE, NAC. 

ACY. 

ACY. 

ACY, HSC, SW. 

ACY, DUP, HSC, NAC, SW. 

mC, X. 

AAP, DUP, GAF, ICC, ICI, NAC, TRC. 

ICI. 



DUP. 

AAP, DUP, GAF. 



AAP. 
ICO, SDC. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE IB.— Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1966 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



l-Amino-4-hydroxyanthraquinone 

2-Airdno-3-hydroxyanthraquinone 

l-Aniino-4-hydroxy-2-methoxyanthraquinone 

A -Mlno-5 -hydroxy-2 , V-naphthalenedisulf onic acid , 

benzenesulf onate . 
3 -Aiiiino-5 -hydroxy-2, 7-naphthalenedisulf onic acid 

(2H acid), monosodium salt. 
4-Amino-5-hydroxy-l,3-naphthalenedisulfonic acid (Chicago 

acid), monoEOdlum salt. 
•»4-Amlno-5-hydroxy-2,7-naphthalenedisulfonic acid (H acid), 

monosodiujn salt. 
».;-Amino-3-hydroxy-l-naphthalenesulfonic acid (1,2,4. acid) — 
•4-Amino-5-hydroxy-l-naphthalenesulfonic acid (S acid), 

sodium salt. 
»6-Amlno-4-hydroxy-2-naphthalenesulfonlc acid (Gamma acid), 

sodium salt. 
»7-Amino-4-hydroxy-2-naphthalenesulfonic acid (J acid), 

sodium salt. 

3'-Amino-2'-hydroxy-5'-nitroacetanilide . 

2-(2-Amino-5-hydroxy-7-sulfo-l-naphthylazo)-5-nltrobenzoic 

acid. 
l-(6-Amino-l-hydroxy-3-sulfo-2-naphthylazo) -6-nitro-2- 

naphthol-i-sulfonic acid. 

5-Amirioisophthalic acid 

4-Amino-3-({i -methanesulf anamidoethyl) -N,N-diethylaniline 

hydrochloride. 
»N-(<4-Amino-3-methoxy-l-anthraquinonyl)-p-toluenesulfona- 

mide. 

5-Amino-6-methoxy-2-naphthalenesulfonlc acid 

m-[('i-Amino-3-methoxyphenyl)azo] benzenesulf onic acid 

8-Amlno-6-methoxyquinoline 

4-[(<i-Amino-5-methoxy-o-tolyl) azo] -<i-hydroxy-2,7-, 

naphthalenedisulfonic acid, benzenesulf onate . 
3-[('l-Amino-5-methoxy-o-tolyl)azo]-l,5-naphthalene- 

disulfonic acid. 
7-[('4-Amino-5-metho](y-o-tolyl)azo] -1,3 -naphthalene- 
disulfonic acid. 

»4'-Amino-N-methylacetanilide 

l-Amino-2-methylanthraquinone 

<i-Amino-<i'-(3-methyl-5-oxo-2-pyrazolin-l-yl)-2,2'- 

stilbenedisulfonic acid. 

8-Amino-7-methyl-l-phenazinol (Tolazine base) 

2-Amino-3-methylpyTidine 

2-Amino-5-methylpyridlne 

2-Amino-6-methylpyridine 

2-Amino-4-methylpyriiiiidine (2-Amino-4-methyl-l,3-diazine) — 

2-Amino-i-(methylsulfonyl) phenol 

2-Amiuo-5-methyl-l,3,A-thiadiazole 

l-Amino-2-methyl-4-p-toluidinoanthraquinone 

l-Aminonaphth[2,3-c] acrldan-5,8,l<i-trione 

A-Aminonaphth[2,3-c] acridan-5,8,l<i-trione 

6-Amlnonaphth[2,3-c] acridan-5,8,l<i-trione 

»2-Amino-l,5-naphthalenedlsulfonic acid 

3-Amino-l,5-naphthalenedisulfonlc acid (C acid) 

3-Amino-2, 7-naphthalenedisulf onic acid 

4-Amino-l, 5 -naphthalenedisulfonic acid 

'i-Amino-l,6-naphthalenedisulfonlc acid 

«6-Amino-l,3-naphthalenedisulfoiiic acid (Amino I acid) 

»7-Amino-l,3-naphthalenedisulfonic acid (Amino G acid) 

6-Amlno-l-naphthalene sulfonamide 

l-Amino-2-naphthalenesulfonic acid (o-Naphthionic acid) 

2-Amino-l-naphthalenesulfonic acid (Tobias acid) 

•"i-Amino-1-naphthalenesulfonic acid (Naphthionic acid) 

4-Amino-l-naphthalenesulfonic acid, sodium salt 

'i(and 5) -Anino-1-naphthalenesulf onic acid 

5-Amino-l-naphthalenesulfonic acid (Laurent's acid) 

•5-Aiiilno-2-naphthalenesulfonic acid (l,6-Cleve's acid) 

»5(and 8) -Amino-2-naphthalenesulf onic acid (Cleve's acid, 

mixed) . 

•6-Amino-2-naphthaleuesulfonic acid (Broenner's acid) 

6(aiid 7) -Amino-l-naphthalenesulfonic acid 



GAF. 
GAF, 
TRC. 
TRC. 


NAC. 








DUP, 


NAG. 








DUP, 


NAC. 








DUP, 


MDN, 


NAC. 






ACY, 
MAC. 


GAF, 


NAC, 


TRC, 


VPC 



DUP, GAF, NAC, TRC. 

BKS, CMG, DUP, NAC, TRC. 

TRC. 
TRC. 

TRC. 



GAF. 

EKT. 






AAP, 


DUP, 


GAF 


NAC, 
DUP, 
SDW. 
TRC. 


TRC. 
TRC. 





cm, 


GAF, 


NAC. 




DUP, 


ICI. 






TRC. 








NAC. 








RIL. 








RIL. 








RIL. 








ACY. 








NAC, 


TRC. 






ACY. 








ICI. 








DUP. 








DUP. 








GAF. 








ACY, 


SDH, 


SW. 




GAF, 


TRC. 






NAC, 


TRC. 






NAC. 








DUP. 








ACY, 


DUP, 


NAC, 


TRC. 


ACY, 


DUP, 


GAF, 


MAC, TRC 


VPC. 








DUP. 








ACY, 


HSC, 


SW. 




ACY, 


DUP, 


NAC. 




DUP, 
ACY, 
DUP, 


NAC. 
TRC. 
NAC. 






AIJ., 


DUP, 


GAF, 


NAC, TRC 


ALL, 


DUP, 


MAC, 


TRC. 


NAC, 


SNA, 


TRC. 




DUP, 


VPC. 







CYCLIC INTERMEDIATES 



69 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1966 — Continued 



Manufacturers' identification code 
(according to list in table 22) 



»8-Amlno-l-naphthalenesulfonic acid (Peri acid) 

»8-Ainino-2-naphthalenesulfonic acid (l,7-Cleve's acid) 

7-Andno-l,3,6-naphthalenetrisulfonic acid 

8-Aiiiino-l,3,6-naphthalenetrisulfonlc acid (Koch's acid) 

3 -Aniino-2 -naphthoic acid 

5(and 8)-Amino-2-naphthol 

«8-Amino-2-naphthol 

•2-Aiuino-5-nitrobenzenesulfonic acid [SOsH^l] 

2-Aniino-4-nitrophenol 

2-Amino-5-nltrophenol 

<l-Amino-2-nltrophenol 

2-Amino-(p-nitrophenylazo) naphthalene 

2-Amino-l-(p-nitrophenyl) -1,3 -propanediol 

»A-Amino-^'-nitro-2,2'-Etiltienedisulfonic acid 

2-Amino-5-nitrothiazole 

»3' -Aminooxanllic acid 

A'-Aminooxanilic acid 

3-Amino-2-oxazolidinone 

5-Aiiiino-2-[(2-oxo-5-benzimidazolinyl) amino] benzenesuLf onic 
acid. 

p-Aminophenethyl alcohol 

5-Amino-2-o-phenetidinobenzenesulfonic acid 

o-Amlnophenol 

p-Aminophenol 

iii-[(p-Aminophenyl)azo]benzenesulfonic acid 

»p- [(p-Aminophenyl)azo]benzenesulfonlc acid 

7-[(<i-Amlnophenyl)azo]-l,3-naphthalenedlsulfonic acid 

5-Amino-8-(phenylazo) -2-naphthol 

8-Ainino-5-(phenylazo) -2-naphthol 

5-[(p-Amlnophenyl)azo] salicylic acid 

2,2'-(m-Amlnophenyllniino)diethanol, diacetate ester 

2-(p-Aminophenyl)-6-methylbenzothiazole 

2-(p-Aminophenyl) -6-methyl-7-benzothlazolesulf onic acid 
and salt. 

l-(m-Aiiilnophenyl) -5-oxo-2-pyrazollne-3-carboxyllo acid 

2-AminopyTidine 

3-AminopyTidine 

4-Aminopyridine 

2-Aminopyrimidine 

5 -Aminosalicylic acid 

N-(^-Amino-3-sulfo-l-anthraquinonyl)anthranillc acid 

3'-(3-Aniinow;-sulfophenylsulfaiiioyl) -3 ' '-sulf amoyl- 
3-phthalocyanlneBulfonlc acid, copper derivative. 

2-Aminothlazole 

3-itoino-p-toluaiiiide 

a-Amlno-p-toluenesulfonamlde 

5-Amino-o-toluenesulfonanilide 

«>i-Amino-iii-toluenesulfonic acid [E03H=l] 

«6-Amlno-m-toluenesulfonic acid [S03H=1] 

5-Amino-2-p-toluidinobenzenesulfonic acid 

m-(i-Ainino-m-tolylazo)benzenesulfonic acid 

3-[(4-Amino-o-tolyl)azo] -IjS-naphthalenedisulfonic acid 

7-[('i-Amino-o-tolyl)azo] -1,3 -naphthalenedisulf onic acid 

•16-Aminoviolanthrone 

5-Amino-2,A-xylenesulfonic acid 

»AnlUne (AniUne oil) — 

Aniline hydrochloride 

l-Anillno-9,10-dihydro-9,10-dioxo-2-anthroio acid 

1-Anlllno-A-hydroxyanthraquinone 

6-AniUno-4.-hydroxy-2-naphthalenesulfonlc acid (Phenyl 
gamma acid) . 

<<7-Anllino-4-hydroxy-2-naphthalenesulfonic acid (Phenyl 
J acid). 

»Anlllnomethanesulfonlo acid and salt 

»8-Anilino-l-naphthalenesulfonic acid (Phenyl peri acid) 

o-Anisic acid 

p-Anisic acid 

m-Anisidine 

"o-Anlsldlne 

p-Anisidine 

l-p-Anisidino-4-hydroxyanthraqulnone 

*o-Anisidinoiiiethanesulfonlc acid 



DUP, NAC, 


SDC 


TRC. 




ALL, DUP, 


NAC 


TRC 




DUP. 








DUP, NAC 








RSA. 








GAF. 








CMG, GAF, 


TRC 


VPC. 




DUP, GAF, 


NAC 


TRC. 




DUP, GAF, 


NAC 


TRC. 




NAC. 








ACY. 








AAP. 








PD. 








GAF, ICI, 


NAC, 


TRC. 




ACY. 








CMG, DUP, 


TRC. 






DUP. 








NOR. 








DUP, 








EKT. 








NAC. 








SDC. 








ABB, DUP, 


SDC. 






AAP, DUP, 


TRC. 






ACY, CMG, 


DUP, 


CzAF, 


NAC, TRC 


TRC. 








ALL. 








ALL. 








TRC, VPC. 








DUP. 








DUP, NAC. 








DUP, TRC. 








TRC, VPC. 








NEP, RIL. 








RIL. 








NEP. 








ACY. 








AAP, TRC. 








GAF. 








DUP. 








ACY, MRK. 








SDH. 








SDW. 








GAF. 








ACY, DUP, 


GAF. 






DUP, HSC, 


NAC, 


SNA, 


SW. 


DUP, NAC, 


TRC. 






TRC. 








TRC. 








TRC. 








ACY, GAF, 


TRC. 






DUP. 








ACY, DOW, 


DUP, 


MDB, 


NAC, RUC 


ACY. 








NAC. 








AAP. 








DUP, NAC. 








ALT, CM), 


DUP, 


NAC, 


IRC. 


AAP, ACY, 


DUP, 


NAC, 


TRC, VPC. 


CMG, DUP, 


NAC, 


SDC. 




HN. 








ICO. 








EK. 








AAP, DUP, 


M3N. 






DUP, MON. 








AAP. 








AAP, DUP, 


GAF, 


NAC, 


TRC, VPC. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



■Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1966— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



2-o-Anisldlno-5-nitrobenzenesuironic acid 

p-Anisoin 

Anisole, tech 

p-Anisoyl chloride 

Anthracene, refined 

Anthranllic acid (o-Aminobenzoic acid)-"- 

»Anthra[l,9-cd]pyrazol-6(2H)-one ( IVrazoleanthrone ) 

Anthraquinone, 100^ 

l,l'-[l,5(and l,8)-Anthraquinonylenediamino]bisnaphth 
[2,3-o]acridan-5,8,l'i-trione. 

N,N'-(l,5-Anthraquinonylene)dianthranilic acid 

N,N'-(l,5-Anthraquinonylene)dioxamic acid 

(l-Anthraquinonyl) -1,2-hydrazlnedisulfonic acid, disodium 
salt. 

Anthrone 

Arsanllic acid and salt, tech 

Aryldiamines, mixed 

A',^" '-Azobis['i-biphenylcarboxylic acid] 

A-', A" '-Azobis[ N-( l-chloro-2-anthraquinonyl) -4- 
biphenylcarboxamide] . 

Barbituric acid 

Barbituric acid, sodium derivative 

»Benzaldehyde, tech 

i.[(<i-Benzajiiido-l-anthraquinonyl)amlno]naphth[2,3-c] 
acridan-5 , 8 , lA -trione . 

N-(5-Benzaiiiido-l-anthraqulnonyl)-p-toluenesulfonamide 

1-Benzamido-i-bromoanthraquinone 

l-Benzajnido-^-chloroanthraquinone 

»l-Benzamido-5-chloro anthraquinone 

l_(A.Benza]nido-2,5-diethoxyphenyl) -3-[methyl-3- 
(2-sulfoethyl)triazene] . 

4-Benzanddo-5 -hydroxy -2, 7-naphthalenedisulfonic acid 

7-Benzainldo-4-hydroxy-2-naphthalenesulfonic acid 

N-(4-Benzamido-6-methoxy-m-tolyl) -N-(methylazo) glycine--- 
Benzanilide 

<<7H-Benz [de] anthracen-7-one (Benzanthrone) 

Benzeneboronlc acid 

m-Benzenedisulf onlc acid 

m-Benzenedisulfonyl chloride 

Benzenesulfonamide 

Benzenesulfonlc acid 

Benzenesulfonic acid, 2-propyn-l-ol ester 

Benzenesulfonyl chloride 

l,2,'i,5-Benzenetetracarboxylic acid 

l,2,'»,5-Benzenetetracarboxylic-l,2:'i,5-dianhydride 

1,3,5 -Benzenetricarboxy lie acid 

1,2,'i-Benzenetricarboxylic acid, 1,2-anhydride 

1,2,'i-Benzenetricarboxylic acid, l,2-anhydride-'i-acid 

chloride. 
Benzhydrol ( Dipheny Imethanol) 

♦Benzidine hydrochloride and sulfate 

Benzil (Blbenzoyl) 

Benzilic acid 

2-Benzofuranacetonitrlle 

♦Benzoic acid, tech-"- 

Benzoin 

Benzonitrile 

Benzophenonetetraoarboxylic dianhydride 

»2-Benzothiazolethiol (2-Meroaptobenzothlazole) , sodium 
salt. 

Benzo[b]thlophen-3(2H)-one 

IH-Benzotriazole 

2H-3,l-Benzoxazine-2,'i(lH)-dlone 

Benzoylacetic acid, ethyl ester 

»o-Benzoylbenzoic acid 

Benzoyl chloride 

2-Benzoyl-<i-sulfobenzoic acid 

2-Benzoyl--i'-(p-toluenesulfonamido)aoetanilide 

N-Benzylacetamide 

Benzylandne 

See footnotes at end of table. 



TRC. 




CTN. 




DUP, LIL. 




ICO. 




ACP. 




DUP, mj, MEE, 


NAC. 


DUP, GAF, TRC. 




ACY, DUP, GAF, 


TRC. 


DUP. 




DUP, ICI. 




GAF, MEE. 




DUP, GAF. 




ICI. 




ABB, FLM. 




DA. 




DUP, GAF. 




GAF. 




ABB, KF, LIL. 




ABB, KF. 




BPC, HN, VEL. 




DUP. 




ICI, NAC. 




AAP. 




GAF. 




ACY, DUP, GAF, 


ICI, MAY, NAC, TRC. 


GAF. 





TRC. 

TRC. 

GAF. 

DUP, PCW. 

AAP, ACY, ATL, CMC, DUP, ICI, MAY, NAC, SDC, TRC. 

EDC. 



DUP, X. 




DUP, X. 




ACC. 




ICO. 




TBK. 




CVra, LAK, 


NAC, X. 


LEW. 




BPC, LEM. 




EK. 




HK, HN, MON, VEL. 


BPC, LEM. 




VEL. 




GOC. 




ACY, GYR, 


MDN, USR 


GAF. 




MEE. 




MEE. 




FMP. 




ACY, DUP, 


GAF. 


HK, VEL. 




DUP. 




EK. 




SDW. 




ICO, ms. 





CYCLIC INTERMEDIATES 



-Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, iP66- -Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



4-(Benzylainino) -6-chloro-m-benzenedlsulfonic acid 

2-(Benzylaiiilno)ethanol 

A-Ben2yl-6-chloro-3-keto-2-methyl-7-sulfainyl-l,2,'i- 

benzylthladlazine-1, 1-dloxide . 
'i-Benzyl-6-chloro-3-keto-7-sulfainyl-l,2,'i- 

benzylthiadlazine-1, 1-dloxide. 
l-Benzyl-4,5-dimethyl-6-(p-methoxybenzyl)-l,2,3,6- 

tetrahydropyridine oxalate. 

Benzyl disulfide 

Benzyl ether (Dlbenzyl ether) 

5-(Benzylethylaiiilno) -o-toluenesulf onic acid 

N-Benzyl-N-ethyl-m-toluldine 

"ijA'-Benzylidenedi-o-toluidine 

Benzyl p-nltrophenyl ether 

p-(Benzyloxy) phenol 

1-Benzyl-A-phenyllsonlpecotio acid, benzyl ester 

l-Benzyl-4-phenylisonlpecotonltrlle 

4-Benzylplperidine 

Benzyl polysulfide 

Benzyl sulfide 

Benzyltrimethylaiimonium chloride 

Benzyltrlmethylammoniuui hydroxide 

Benzyltrimethylainmoniuni methoxide 

«[3,3'-Bianthra[l,9-cd]pyrazole]-6,6'(2H,2'H)dione 

(Pyrazoleanthrone yellow) . 

[3,3^-Bi-7H-benz[de]anthracene] -7,7 '-dione 

»[4,4'-Bl-7H-benz[de]anthracene] -7,7 '-dione 

»[l,l'-Binaphthalene]-8,8'-dicarboxylic acid 

Biphenyl 

3,3 ' ,^A' -Biphenyltetramine 

2,2 '^,U,U' -Biphenyltetrol 

2,2 '-Blqulnollne 

♦Ij'V-Bisfl-anthraquinonylaminoJanthraquinone 

Ij'i-Bls [l-anthraquinonylamlno] anthraqulnone and 1,A-Bis 

[5-chloro-l-anthraq.ulnonylamlno] anthraquinone (mixed) . 

1,5-Bis [l-anthraqulnonylamlno] anthraquinone 

Bis [l-anthraqulnonylamlno Jviolanthrene 

l,<i -Bis [ ( 5 -benzamido-l-anthraqulnonyl) amino ] - 

anthraquinone . 

Bis(chlorosulfonyl)phthalocyaninedisulfonic acid, copper 

derivative. 

4.,i'-Bis [diethylamlno] benzhydrol 

'i,'4'-Bis[dlethylamino]benzhydrol, 2,6-naphthalene- 

dlsulfonate. 
'>,'i'-Bis [diethylamino]benzhydrol salt, 2, 7 -naphthalene - 

disulfonio acid mixture. 

i,A'-Bis[dlethylamlno]benzophenone (Ethyl ketone base) 

A-Bls [(p-dlethylamlnophenyl)methyl] -2, 7 -naphthalene - 

dlsulfonic acid, leuco form. 

^,'i' -Bis [dimethylamlno] benzhydrol (Michler's hydrol) 

*»i,>4'-Bis[dlmethylamlnojbenzophenone (Michler's ketone) 

BiE[p-(dtiiiethylamlno)phenyl]methajiesulfonic acid and salt— 

l,5-Bls[2,4-dlnitrophenoxy] •^,8-dlnltroanthraqulnone 

l,5(and 1,8) -Bls[2,';-dlnitrophenoxy]wi,3(and ^,5)- 

dlnltroanthraqulnone . 

Bls(2,3-epoxycyclopentyl) ether (Epoxide 205) 

3'-[Bis(2-hydroxyethyl)amlno]aoetanllide 

3^-[BiB(2-hydroxyethyl)amino]benzanillde, dlacetate ester— 
3 '-[ Bls( 2-l^droxyethyl) amino jmethanesulfouanlllde, 

dlacetate ester. 
';,<i'-Bls[(p-hydroxyphenyl)azo] -2,2 '-etilbenedisulf onic 

acid (C.I. Direct Yellow -i) . 

4.,A-Bis[p-hydroxyphenyl] valeric acid 

iy;-Bis(p-methoxyphenyl)-3-hexanone 

Bls(2-methyl-l-azirldlnyl)phenylphoEphlne oxide 

2,A-BiB(l-methylbutyl)phenol 

l,'i-Bls[2-(4-methyl-5-phenyloxazolyl)] benzene (Mmethyl- 

POPOP). 

Bis(p-nltrophenyl) disulfide 

Bls(o-nltrophenyl) sulfide 



CCW, FIN. 








BPC. 








NAC. 








DUP, NAC. 








ACY. 








GAF. 








EK. 








SDW. 








SDW. 








RIL. 








HK. 








BPC. 








MI£. 








MIS. 








MI£. 








DUP, GAF, 


TRC. 






DUP, NAC. 








ACY, DUP, 


GAF, 


ICI 


MAY. 


DUP, GAF, 


NAC. 






DOW, MON. 








AAP. 








FMI, IDC. 








EK. 








ACY, DUP, 


GAF, 


ICI, 


MAY, TRC 


TRC. 








DUP, NAC. 








GAF. 








ICI. 








ACY. 








TRC. 








GAF. 








OAF. 








TRC. 








DSC, SDH. 








TRC. 








SDH. 








DSC, DUP, 


NAC, 


SDH. 





SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE IB.— Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i 966— Continued 



anuf acturere ' identification codes 
(according to list in table 22) 



l,<i-Bis[2-(5-phenyloxazolyl) ]benzene (POPOP) 

2-Bromoacetophenone 

o-Bromo aniline 

p-Bromoaniline 

p-Bromoanisole 

»3 -Bromo-7H-benz [ de ] anthracen-7-one ( 3 -Bromobenzanthrone ) 

Bromobenzene , mono- 

p-Bromobenzenesulfonyl chloride 

o-Bromobenzolc acid 

Bromochlorobenzene 

6-Bromo-5-chlorobenzoxazolone 

2-Bronio-6-chloro-4-nitroaiiiline 

2-Bromo-4,6-dinltroaniline 

Bromoethylbenzene 

3-(Bromoethyl) thiophene 

2-Bromo-3'-hydroxyacetophenone benzoate 

l-Bromo-<i-(N-methylacetamido)anthraquinone 

»l-Bromo-4-(inethylaiiiino)anthraquinone 

6-Bromo-3-methyl-7H-dibenz [f ,i j ]iso<iuinollne-2,7- 
(3H)dione. 

1-Bromonaphthalene 

2-Broiiio-4'-nltroacetophenone 

1- [(51-Bromo-7-oxo-7H-benz[de] anthracen-3-yl) amino] - 
anthraquinone . 

N-(4-Broinopentyl)phthallmlde 

o-Bromophenol 

p-Bromophenol 

(p-Bromophenyl)acetonitrile 

p-Bromophenylhydrazine hydrochloride 

2-Bromopyridine 

3-BromopyTidlne 

o-Bromotoluene 

p-Bromotoluene 

a -Bromotoluene 

<;'-Butoxy-3-piperidinoproplophenone 

N-Butylacetanlllde 

p-Butylanlline 

2-tert-Butylanthraquinone 

p-tert-Butylbenzaldehyde 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

p-tert-Butylbenzoio acid 

o-(p-tert-Butylbenzoyl)benzoic acid 

6-tert-Butyl-m-cresol 

2-tert-Butyl-p-cresol 

2'-tert-Butyl-4',6'-dimethylacetophenoiie 

4-Butyl-a-(dii!iethylaiiiino)-o-creBOl 

2-tert-Butyl-4-ethylphenol 

N-'-'Butyl-^.-methoxymetanllamlde 

2-tert-Butyl-5-inethylanl80le 

o-seo-Butylphenol 

p-sec-Butylphenol 

o-tert-Butylphenol 

p-tert-Butylphenol 

Butylphenols , mixed 

p-tert-Butyltoluene 

5-tert-Butyl-l,2,3-trimethylbenzene 

5-tert-Butyl-m-xylene 

6-tert-Butyl-2,'i-xylenol 

Camphoric acid 

Camphoric anhydride 

d-lO-Camphorsulfonic acid 

Camphosulfonlc acid 

Carbazole, refined 

NjN^-Carbonylbisf'i-methojcymetanlUc acid] — - 

N,N'-CarbonylbiB[4-methO]cy-6-uitroii>etanlllc acid] 

5 '-(o-Carboxybenzoyl) -2 '-chlorooxanillc acid 

H-[(3-Carboxy-4-chlorophenyl) -eulfonyl]anthranillc acid- 
3-Carboxy-2(and 'i)-hydroxybenzenediazonium sulfate 



EK. 

DOW. 

MEE. 

AAP. 

AAP, TRC. 

DOW. 

SDW. 

SDH. 

GAF. 

AAP, DUP, GAF, 

AAP, GAF. 

EK, RSA. 



RSA. 
BPC. 
EK. 
ICO. 
UCC. 
DUP. 
DUP. 

Grv. 

PLC. 

PLC. 

PLC. 

SHC. 

DUP. 

KPT, PHD. 

ACY. 

GIV. 

RH. 

ACY. 

PCW. 

GIV. 

DOW, TNA. 

DOW. 

TMA. 

DOW, PRD, UCC. 

DOW. 

GIV, SHC. 

GIV. 

GIV. 

KPT, PRD. 

FIN, OTC. 

FIN. 

OTC. 

PYL. 

SDC. 

OAF. 

GAF. 

GAF. 

TRC. 

GAF, NAC. 



CYCLIC INTERMEDIATES 



73 



TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1966 — Continued 



Manufacturers ' Identification codes 
(according to list in table 22) 



o-[(Carboxyinethyl)thio] benzoic acid 

[(o-Carboxyphenjrl)thio] ethylmercury 

Cedrene 

2'-Chloroacetoacetanillde 

2'-Chloroacetophenone 

3'-Chloroacetophenone 

A'-Chloroacetophenone 

4/-(Chloroacetyl) acetanilide 

m-Chloroani line ■ 

o-Chloro aniline 

p-Chloro aniline 

2-(o-Chloroanllino)ethanol 

3-(o-Chloroanllino)propionltrile 

5-Chloro-o-anisidine [NH2=1] (<i-Chloro-o-anieidine 
[0CH3=1]). 

5-Chloro-o-anisldine hydrochloride 

<i-Chloroanthranllic acid 

•1-Chloroanthraquinone 

»2-Chloroanthraquinone 

N-(5-Chloro-l-anthraquinonyl)-p-toluenesulfonamlde 

o-Chlorobenzaldehyde 

p-Chlorobenzaldehyde 

A-(p-Chlorobenzamldo)anthraquinone-l,2-acridone 

Chloro-7H-benz[de]anthracen-7-one (Chlorobenzanthrone) 

»Chlorobenzene , mono- 

p-Chlorobenzenesulf inlc acid 

p-Chlorobenzenesulfonamide 

p-Chlorobenzenesulfonlc acid 

p-Chlorobenzenesulfonyl chloride 

o-Chlorobenzoio acid 

p-Chlorobenzoic acid 

p-Chlorobenzonitrlle 

5-Chloro-2-benzoxazolinone 

»o-(p-Chlorobenzoyl) benzoic acid 

p-Chlorobenzoyl chloride 

4,^'-(o-ChlorobenzyHdene)di-2,5-xyUdine 

a-(p-Chlorobenzyl) -a-phenyl-l-pyrrolldlne propanol 

Chloro(p-chloropenyl)phenylinethane 

Chlorooyclohexane 

l-Chloro-2, 5 -diethoxy -4 -nitrobenzene * 

3-Chloro-'i-(diethylaiiilno)benzenediazonluin chlorozincate 

2-Chloro-N,N-dlethyl^-nitroaniliue 

2-Chloro-3',4' -dlhydroxyacetophenone 

2-Chloro-l,'i-dihydroxyaiithraquinone 

4 '-Chloro-2 ', 5 '-dimethoxyacetoaoetanllide 

5-Chloro-2,4-di]nethoxyaniline 

5-Chloro^,7-dimethylbenzo[b]thlophen-3(2H)-one 

4.-Chloro-N,N-dimethyl-3-nitrobenzenesulfonaiiilde 

»l-Chloro-2,A-dlnitrobenzene (Dlnltrochlorobenzene) 

l-Chloro-2,'i-dinltrobenzene and 2-ohloro-l,3-dinitrobenzene 
mixture. 

3-Chloro-4,6-dinitrobenzene8ulfonlc acid 

3-Chlorodiphenylamine 

Chlorodiphenylme thane 

N-(2-Chloroethyl) -4-(2-chloro-4-nitrophenylazo) - 
N-e thy lani line. 

N-(2-Chloroethyl)-N-ethylanillne 

p-[(2-Chlorbethyl)iiiethylaiiiino] benzaldehyde 

2-Chloro-N-ethyl-5-nltrobenzenesulfonanillde 

Chlorofonalc acid, benzyl ester 

Chloroformic acid, phenyl ester 

4-Chloro-3-hydrazinobenzenesulfonlc acid 

l-Chloro-4-hydroryanthraquinone 

5'-Chloro-3-hydroxy-2-naphth-o-anisidide 

3-Chloro-<l-hydroxyquinollne-3,4-carbonic acid 

6-Chloroisatolc anhydride 

<i-Chloro-N-isopropyl-3-nltrobenzenesulfonainide 

A-Chlorometanlllc acid 

S-Chlorometanillc acid 

*6-Chloroinetanillc acid 

5-Chloro-2-methoxybenzenediazonluin chloride 



GAF. 

LIL. 

OIV. 

FMP, UCC. 

EK. 

EX. 

LIL. 

DUP. 

DUP, GAF. 



EKT. 

BUC, DUP. 
ALL, BUC. 



i, DUP, GAF, ICI, MAI, NAC, TRC. 
f, GAF, NAC, TRC. 



DOW, DVC, HK, HKD, MDN, MTO, OMC, PPG, WOI. 
NES. 



ACY, DUP, GAF, HN, ICI, NAC. 

HN. 

GAF. 

UL. 

OPC. 

ACY. 

ALL, FWT, GAF. 

ESA. 

DUP. 

SDW. 

HSH. 

PCW. 

GAF, 



PCW. 

DUP, NAC, SDC. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 7966— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



N-[(5-Chloro-2-methoxyphenyl)azo]sarcosine 

p-(Chloromethyl)anlsole 

»l-Chloro-2-methylanthraqulnone 

6-Chloro-4.-methyl-l,3,2-benzothiazathioliuai chloride 

^-(Chloromethyl)-l,2-dimethylbenzene 

A-(Chloromethyl)-l,3-dimethylbenzene 

l-(Chloromethyl) naphthalene 

^-Chloro-N-methyl-3-nitrobenzenesulfonamide 

"i-Chloro-3-(3-methyl-5-oxo-2-pyrazolin-l-yl)benzene- 
sulfonic acid. 

2-Chloro-5-(N-methylsulfainoyl) sulfanilamide — 

5-Chloro-2-(N-methylsulfa]iiyl) -/i-sulf amyl-N-benzylaniline 

'i-Chloro-3-(methylsulfonyl) nitrobenzene 

Chloronaphthalenes 

9-Chloronaphthol [l,2-b] thiophen-3(2H) -one - 

»2-Chloro-';-nitroaniline (o-Chloro-p-nitroaniline) 

»<i-Chloro-2-nitroaniline (p-Chloro-o-nitroaniline) 

4-Chloro-2-nitroanisole 

*l-Chloro-5-nitroanthraquinone 

l-Chloro-8-nitroanthraquinone 

»l-Chloro-2-nitrobenzene (Chloro-o -nitrobenzene) 

l-Chloro-2( and i) -nitrobenzene (Chloronitrobenzenes, 
o- and P-) . 

»l-Chloro-3 -nitrobenzene (Chloro-m-nitrobenzene) 

*l-Chloro-'+-nitrobenzene (Chloro-p -nitrobenzene) 

2-Chloro-5-nitrobenzenesulflnlc acid 

»'4-Chloro-3-nitrobenzenesulfonainlde 

'i-Chloro-3-nitrobenzenesulfonanllide 

2-Chloro-5-nitrobenzenesulfonic acid 

2-Chloro-5-nltrobenzenesulfonic acid, sodium salt 

4-Chloro-3-nitrobenzenesulfonio acid 

2-Chloro-5-nitrobenzenesulfonyl chloride 

M-Chloro-3-nltrobenzenesulfonyl chloride 

2-Chloro-4-nitrobenzoic acid 

2-Chloro-5-nitrobenzoic acid 

■»o-(4-Chloro-3-nitrobenzoyl) benzoic acid 

i-Chloro-2-nitrophenol 

4-Chloro-3-nitrophenyl methyl sulfone 

2-Chloro-4-nitrotoluene 

2-Chloro-6-nltrotoluene 

4-Chloro-2-nltro toluene 

«4-Chloro-3-nltrotoluene 

a-Chloro-m-nltrotoluene 

Chloropentafluorobenzene 

m-Chlorophenol 

o-Chlorophenol 

p-Chlorophenol 

2-Chlorophenothiazi 

(p-ChloTOphenyl) acetonitrlle 

4-Chloro- a^phenyl-o-cresol 

i-Chloro-o-phenylenediamine 

3-(o-Chlorophenyl) -5-methyl-4-lsoxazolecarbonyl chloride 

3-(o-Chlorophenyl) -5 -methyl -<i-isoxazolecarboxy lie 

l-(p-Chlorophenyl) -3-methyl-2-pyrazolln-5-one — 

p-Chlorophenyl methyl sulfone 

2-Chloro-4-phenylphenol 

2-(A -Chloropheny Ithi o ) benzol 

4-Chlorophthallc acid 

Chlorophthalic anhydride. 

(3-Chloropropenyl)benzene (Cinnamyl chloride) 

1- (3-Chloropropyl )-4-methylpipera 

""'-( 6-Chloro-3-pyTidazinyl) sulfanilamide. 

2-Chloropyridine 

dl-2-[p-Chloro-2-(2-pyridyl) benzyl] oxy-N,N-dimethylethyl 

amine maleate 
7-Chloro-4-qulnolinol- 
\ -Chlororesorcinol 
2-Chloro-5-sulfamoylbenzolc acid 
2-Chlorothiaxanthen-9 -one 



DUP, GAF, ICI, NAC, TRC. 



TRC. 








KPS. 








GAF. 








DOW, 


DUP, 


HSC, 


SDC. 


DOW, 


DUP, 


SDC, 


VPC. 


ALL, 


BUG. 






AGY, 


DUP, 


MAY, 


NAC, TRC 


DUP, 


MAY. 






AAP, 


DUP, 


MON, 


UPM. 


SDC. 








DUP, 


GAF, 


MON, 


UPM. 


AAP, 


DUP, 


MON, 


UPM. 


TRC. 








AAP, 


CMD, 


DUP, 


EKT, ICC 


TRC. 








AAP, 


CMG, 


NAC, 


TRC. 


DUP, 


GAF. 






GAF, 


NAC, 


TRC. 




TRC. 








AAP, 


DUP, 


EKT. 





DUP. 




DUP. 




BUG, 


DUP. 


AAP, 


BUG, DUP 


EK. 




WHC. 




EK. 




DOW, 


GAT, MON 


DOW, 


MON. 


SK. 




ICO, 


OPC. 


MON. 




FMT. 




ICO, 


OTC. 


ICO. 




DUP, 


TRC. 


TRC. 




DOW. 




MEE. 




DUP, 


SW. 


HK. 




SDW. 




SK. 




ACY. 




FMT. 




X. 




SDW. 




AAP, 


GAF. 



CYCLIC INTERMEDIATES 



75 



TABLE IB.— Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer , 1966 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



and hydrochloride 

(<i-Chloro-o-toluidin 



2-Chlorothiophene 

m-Chlorotoluene 

p-Chlorotoluene 

»a-Chlorotoluene (Benzyl chloride) 
3-Chloro-o-toluidine [NH2=1 
3-Chloro-p-toluidine [NH2=1 
4-Chloro-o-toluidlne [NHj^l 
»5-Chloro-o-toluidine [NHs^l 
[CH3 = 1]). 

5-Chloro-o-toluidine hydrochloride [NH2=1] 

«N-[ (5-Chloro-o-tolyl)azo]sarcosine 

l-(6-Chloro-o-tolyl)-3-methyl-2-pyrazolin-5-one 

»[('i-Chloro-o-tolyl)thio] acetic acid 

4-Chloro-a, a, a-trif luoro-3-nitrotoluene 

5-Chloro-a,a,a-trifluoro-2-nitrotoluene 

p-Chloro-O'j^j^-trifluoro toluene 

6-Chloro-'',*,''-trlf luoro-m-toluldine 

<;-Chloro-a,a,a-trifluoro-o-toluidine 

2-Chloro-l,3,5-trinitrobenzene 

Chlorotriphenylmethane 

2-Chloro-p-xylene 

<i-Chloro-2,5-xylenesulfonyl chloride 

.i-Chloro-3,5-xylenol 

[(<;-Chloro-2,5-xylyl)thio] acetic acid 

5a-Cholestan-3 p-ol 

ChoUc acid 

Cinnamoyl chloride 

»Cresols:^ 

m-Cresol 

«o-Cresol: 

From coal tar 

From petroleum 

p-Cresol 

Cresols, mixed :^ 
»(m,p)-Cresol: 

From coal tar 

From petroleum 

(o,m,p) -Cresol: From coal tar 

2,3-Cresotic acid 

»Cresylic acid, refined:^ 

»From coal tar 

■»From petroleum 

»Cuinene 



a-Cyano-d-'ja-cyclohexaneacetic acid, ethyl ester- 
a-Cyano-l-cyclohexene-l-acetic acid, ethyl ester- 

i-[(2-Cyanoethyl)ethylaiiiino]-o-tolualdehyde 

P-[(2-Cyanoethyl)methylaiiiino] benzaldehyde 

8-Cyano-l-naphthalenesuKonic acid 

•Cyclohexane 



1,2-Cyclohexanedicarboxylio anhydride 

Cyclohexanol 

«Cyclohexanone 

Cyclohexanone oxtme 

Cyclohexene 

4-Cyclohexene-l,2-dicarboximide 

i- Cyclohexene-l,2-dicarboxylic anhydride- 

»Cyclohexylaiiiine 

Cyclohexyl-2-propanone 

N-Cyclohexyltaurine, sodium salt 

Cyclopentanepropionic acid 

Cyclopentanol 

Cyclopentene 

(2-Cyclopenten-l-yl) -2-propanone 

l-Cyclopentyl-2-(methylamlno)propane 

p-Cymene 

Deoxycholic acid 



BPC, GRH, HK, HN, MDN, TBK, VEL. 

DUP. 

DUP. 

ACY, PCW. 

ATL, BUG, DUP. 

BUG, SDH. 
ALL, ATL, GAF. 



ARA, EK. 




DUP. 




NAG. 




OTA. 




NAG. 




SDW. 




WIL. 




IGO, TBK, 


X. 


KPT, PRD. 




KPT, PRD. 




ACY, MER, 


NPG, PRD, SW. 


HPG, SW. 




AGP, KPT, 


PRD. 


MER, NPG, 


PIT, PRD. 


AGP, KPT. 




DOW. 




AGP, KPT. 




AIR, MER, 


NPG, PIT, SHO. 


ACC, AGP, 


CLK, DOW, GOG, HPG, MON, SHG, SKO, SNT, SQK. 


TX. 




SDW. 




SDW. 




DUP, GAF. 




DUP, GAF. 




DUP. 




ASH, GO, 


GSD, DUP, EKX, ENJ, GOC, GRS, PLC, RIG, SCO 


TX, UOG 




NAG. 




DUP, MON, 


NAG. 


DBG, DUP, 


MON, NAG. 


NAG, X. 




EK, PLG. 




GHO. 




NAG, PTT. 




ABB, JGC, 


MON, PAS, VGG, X. 


GIV. 




GAF. 




ARA. 




ARA, LIL. 




PLC. 




LIL. 




LIL. 




HNW, HPG, 


NAC. 


WIL. 




AAP. 




SDW. 





See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 7B. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, J966— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



3'-[Di(2-aoetoxyethyl)amino]-p-acetophenetidlde 

3-(Diallylcarbajiioyl)-l,2,2-triiiiethylcyolopentanecarboxyllc 

acid. 

N^,N^-Diallyljiielamine - 

»l,4-Diaiiiinoanthraquinone 

1,5-Diaminoanthraquinone 

l,5(and 1,8) -Diajninoanthraquinone 

»2,6-Diamlnoanthraquinone 

3,4-Diajiiinobenzanllide 

3','i-Diaminobenzanilide 

2,4-Diaminobenzenesulfonic acid [S03H=l] 

2,5-Diaiiiinobenzenesulfonic acid [S03H=l] - - 

4-, A '-Dlamino-2,2 '-biphenyldisulf onic acid 

l,5-Diainlno-2,6-dibromo-A,8-di-p-toluidlnoanthraq\iinone 

l,"i-Diamlno-2,3-dichloroanthraquinone 

»l,4-Diamino-2,3-dihydroanthraquinone 

4,8-Diamino-9,10-dihydro-l,5-dihydroxy-9,10-dioxo- 

2,6-anthracenedisulfonic acid. 
l,A-Diamino-9,10-dihydro-9,10-dioxo-2,3-anthraeene- 

dicarbonitrlle. 
l,4-Diajnino-9,10-dihydro-9,10-dioxo-2,3-anthracene- 

dicarboximide. 

l,5-DiaiBino-4,8-dihydroxyanthraquinone 

l,5(and l,8)-Diamino-i,8(and -i.S) -dihydroxyanthraquinone — 

4.,5-Diamino-l,8-dlhydroxyanthraquinone 

3,6-Diamino-2,7-dimethylacridine 

3,6-0iajnino-2,7-dimethylacridine sulfate 

4,^'-Diamino-5,5'-diiiiethyl-2,2'-biphenyldisulfonic acid 

2,'4-Diamino-6-phenyl-s-triazine 

2,6-DiamlnopyTidine 

6,7-DiaiQino-2,3-quinolinediol 

»A,A' -Dianiino-2,2 '-stilbenedisulfonic acid 

l,5-Dlamlno-2,4,6,8-tetrabromoanthraquinone 

<i,6-Diamino-m-toluenesulfonic acid [S03H=l] 

3,5-Diaiiiino-p-toluenesulfonic acid [S03H=l] 

3,5-Diaiiiino-2,'i,6-triiodobenzoic acid 

l.iiaje-Dianhydroglucitol 

l,5-Dianilino-9,10-dihydro-9,10-dioxo-2,6-anthracene- 

dicarboxylio acid. 

2,4-Dianilino-l-hydroxyanthraquinone 

6,8-Dianilino-l-naphthalenesulfonic acid 

2,5-DianillnoterephthaUo acid - - 

Diarylguanidlne 

p-Dlazo-N,N-diinethylaniline-l-amino-8-naphthol-3- 

sulfonate-6-sulfonic acid, sodium salt. 
5(and 3) -Diazo-6-oxo-l,3(and 1,4) -cyclohexadiene- 

1-carboxylio acid. 

1,5-Dibenzamidoanthraquinone 

6,ll-Dibenzajnido-16H-dinaphtho[2,3-a,2 ',3 '-i] -carbazole-5, 

10,15,17-tetrone. 

•4,5'-Dibenzaiiiido-l,l'-iminodianthraqulnone 

Dibenzo[b,def] chrysene-7,14-dione 

»1, 5 -Dibenzoylnaphthalene 

N,N'-Dlbenzylethylenedi amine 

NjN'-Dlbenzylethylenediamlne diaoetate 

N,N'-Dibenzylidenetoluene-a,a-dia]iilne 

N,N-Dibenzylsulfanllic acid - 

2,<i'-Dibromoacetophenone 

»3,9-Dibromo-7H-benz[de]anthracen-7-oiie 

p-Dibromobenzene 

ar-Dibronioethylbenzene 

2,6-Dibronio-4-iiitrophenol 

5,13-Dlbroiiio-8,16-pyTanthrenedione 

Dibromoviolanthrone 

p-Dlbutoxybenzene 

l,4-Dibutoxy-2-chloro-5-nltrobenzene 

2,5-Dibutoxy-4-morpholinobenzene sulfate 

4-(2,5-Dlbutoxy-4-nitrophenyl)morpholine 

2,6-Dl-tert-butyl-4-nonylphenol 

2,4-Dl-tert-butylphenol — - 



ACY. 

CM3, 

GAF, 

AAP, 

AAP, 

DUP. 

VPC. 

DUP, 

TRC. 

AAP, 

ICI. 

CMG, DUP. 

ACY, ATL, DUP, GAF, HSH, ICC, ICI, MAY, TRC. 

TRC. 



DUP, GAF, NAC, TRC. 

TRC. 

ICI, TRC. 

GAF, ICI, NAC, TRC, VPC. 



NAC, TRC. 
ACY, NAC. 



DUP, 

DUP. 

ICI. 

DUP. 

DUP. 

AAP. 

RH, \ 

RIL. 

BJL. 

ACY, 

ICI. 

NAC. 

GAF. 

SDW. 

APD. 

GAF, 

GAF. 
NAC. 
MEE. 
DUP. 
IDC. 



GAF, ICC, VPC. 



DUP, GAF, GGY, NAC, SDH, TRC, VPC. 



DUP, GAF, ICI, MAY, NAC, TRC. 

ICI. 

DUP, GAF, HST, ICI, TRC, VPC. 



CYCLIC INTERMEDIATES 



77 



TABLE 7B. —Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i 566— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



Dibutyltin biE(cyclohexyl maleate) 

2,'V-Dichloroaniline 

3, 'i-Dichloro aniline 

•2,5-Dichloroaniline and hydrochloride [NH2=1]- — 

3-(2,'i-Dichloroanllino)-l-(2,A,6-trichlorophenol) 

»lj5-Dichloroanthraquinone 

l,5(and 1,8) -Diohloroanthraquinone 

»l,8-Dichloroanthraquinone 

2,6-Dichlorobenzaldehyde 

3-(3,<i-Dichlorobenzaiiiido) -l-phenyl-2-pyrazolin-5-one 

Dichlorobenzanthrone 

m-Dichlorobenzene 

»o-Diohlorobenzene 

o(and p) -Dichlorobenzene 

•p-Dlchlorobenzene 

4,6-Dichloro-in-benzenedisulfonamide 

'V,6-Dichloro-m-benzenedisulfonyl chloride 

»3,3'-Dichlorobenzidine base and salts 

2,i-Diohlorobenzoic acid 

2,6-Diohlorobenzonitrile 

2,'i-Dichlorobenzoyl chloride 

2,5-Dichlorobenzoyl chloride 

2,<i-Dichloro-m-cresol 

7,16-Diohloro-6,15-dihydro-5,9,lA,18-anthrazinetetrone— 
<;,8(and A,5) -Dichloro-9,10-dihydro-9,10-dioxo-l,5(and 

l,8)-anthracenedisulfonic acid. 
'i,5-Dichloro-3,6-dioxo-l,^-cyclohexadiene-l,2-di- 

carbonitrile . 

Dichlorodiphenylsilane 

2',7'-Dichlorofluorescein 

SjlA-Dichloroisoviolanthrone 

*2 , 5 -Dichloro-4 -( 3-methyl-5-oxo-2-pyrazolin-l-yl) 

benzenesulfonic acid. 

»2,6-Dlchloro-A-nitroanillne— — 

1, 2 -Dichloro -4 -nitrobenzene 

»l,<V-Dichloro-2-nitrobenzene ( Nitro-p-dichlorobenzene) 

2,5-Dichloro-3-nitrobenzoic acid , 

2,5-Dichloro-3-nitrobenzoio acid, ammonium salt 

2,'4-Dichlorophenol 

2-(2,'4-Dichlorophenoxy)ethanol 

N- [ ( 2 , 5-Dichlorophenyl) azo ] -N-ethyl-5 -sulf oanthranilic 

acid. 
3-(2',6'-Dichlorophenyl)-5-methyl-4-isoxazolecarbonyl 

chloride. 
3-(2',6 '-Dichlorophenyl) -5-methyl-4-isoxazolecarboxylic 

acid. 

2,6-Dichloropyrazine 

3,6-Dichloropyridazine 

4,7-Dichloroquinoline 

3,5-Dichlorosalicylic acid 

2,5-Dichlorosulfanilic acid [SOjH^l] - 

2,5-Dichloro-<;-sulfobenzenediazonium sulfate 

p,a-Dichlorotoluene 

a,a-Dichlorotoluene (Benzal chloride) 

2,6-Diehlorotoluene 

2,<i-Dichloro-3,5-xylenol 

Dicyclohexylamine 

»Dicyolopentadiene (includes cyclopentadiene) 

Dicyclopentadiene dioxide 

2,5-Diethoxyaniline 

2',5'-Diethoxybenzanilide 

p-Diethoxybenzene 

3,4-Diethoxybenzoic acid 

2,5-Diethoxy-morphoUnobenzenediazoniuin chloride, zinc 

chloride. 

'i-(2,5-Diethoxy-i-nitrophenyl)morphollne 

•p-(Diethylamino)benzaldehyde 

2-Diethylaminoethyl-^-acetylamlnophenol 

p-(Diethylamino)benzenediazonlum chlorozinoate 

a- [(2-Diethylamino)ethyl] - ct-phenylcyclohexanemethanol, 

hydrochloride. 



EK. 

DUP, ClAF, ICI, NAC, TRC. 

DUP, NAC. 

DUP, GAF, ICI, TRC. 

DUP. 

EK. 

ACY. 

EK, GAF. 

ACS, CPD, DOW, DUP, DVC, MON, OMC, PPG, SCC, SVT, 

WOI. 
HKD, MTO. 
ACS, CPD, DOW, DVC, HK, MON, PPG, SCC, SVT, WOI. 



ALL, CWN, LAK, NAC. 



cm:;, DUP, SDH, trc, vpc. 

CWN, DUP, GAF, HSH, MEE, PCW, SW, TRC. 

MON. 

DUP, NAC, PCW, SDC, VPC. 



ACY. 
ACY. 
PD, SDW. 



ICO. 

CIG, DUP, VPC. 

TRC. 

HN. 

HK, NAC. 

DUP, GAF. 

OTA. 

ABB, MON, VGC. 

ENJ, GOC, UCC, VEL. 

VEL. 

GAF. 

GAF. 

GAF. 

ICO. 

ALL. 

ALL. 

DUP, GAF, NAC. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



■Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 7566- -Continued 



Manxif acturers ' identification codes 
(according to list in table 22) 



m-(Diethylamino) phenol (N,N-Diethyl-3-aminophenol) 

3-f (p-Diethylamino)phenylazo]-lH-l,2,'4-triazole 

3-(Diethylamlno)proplophenone 

4-(Diethylanilno) -o-tolualdehyde 

»N,N-Diethylaniline - — 

N,N-Diethyl-m-anisidine 

Diethylbenzene 

Diethyl-[3,3'-bianthra[l,9-od]pyrazole] -6,6'-dione 

l,l'-Diethyl-4,4'-carbocyanine iodide (Cryptocyanine) 

NjN-Dlethylcyclohexylamine 

a, a'-Diethyl-'i,<+' -dlmethoxystllbene 

N.N-Diethylmetanilic acid 

N ,N^-Diethyl-^-methoxymetanilamide 

N.N-Diethyl-l-naphthylamine 

N,N-Dlethyl-p-nltrosoanillne 

N,N-DietJ^rl-<i-nitroso-m-anisidine hydrochloride 

N,N-Diethyl--4-nltroso-m-phenetidine 

N,N-Diethyl-m-phenetldine - 

N,N-Diethyl-m-toluidlne 

ejlS-Dihydro-SjgjKjlS-anthrazinetetrone 

10,ll-Dihydro-5H-dibenzo[a,d]cyclohepten-5-one 

«9,10-Dihydro-l,A-dihydroxy-9,10-dioxo-2-anthraoene- 

sulfonic acid (2-Qulnizarinsulfonic acid). 
N-(5,13-Dlhydro-5,13-dloxoaoeanthryleno[2,l-a]- 

aceanthrylen-7-yl)-9,10-dihydro-l-nitro-9,10-dioxo-2- 

anthr amide. 

»9,10-Dihydro-9,10-dioxo-l,5-anthraoenedisulfonic acid 

•9, lO-Dilftrdro-9 , 10-dloxo-l, 5 -anthracenedlsulf onic acid , 

dlsodlum salt. 
9,10-Dihydro-9,10-dioxo-l,5(and 1,8) -anthracenedlsulf onlc 

acid and salt. 

9,10-Dihydro-9,10-dioxo-l,8-anthracenedlsulfonic acid 

»9,10-Dihydro-9,10-dioxo-l,8-anthracenedisulfonic acid, 

potassium salt. 
»9,10-Dihydro-9,10-dioxo-2,6-anthracenedisulfonlc acid and 

salt. 
•«9,10-Dlhydro-9,10-dioxo-l-anthraoenesulfonic acid and salt 

(Gold salt). 
9,10-Dihydro-9,10-dioxo-2-anthracenesulfonlc acid and salt 

(Silver salt) . 

9,10-Dihydro-9,10-dloxo-2-anthroic acid 

3,<;-Dihydro-3,'i-dioxo-l-naphthalenesulfonlc acid, sodium 

salt. 

[Dihydrogen 3,3 "-phthalocyaninedisulfonato-( 2-)] copper 

10,ll-Dihydro-5- [3-(methylaminopropyl)] -5H-dibenzo- 

[a,d] cyclohepten-5-ol. 
«9,10-Dihydro-5-nltro-9,10-dioxo-l-anthracenesulfonio acid — 
9,10-Dihydro-5(and 8) -nitro-9,10-dioxo-l-anthracene- 

sulfonic acid. 
9,10-Dihydro-8-nltro-9,10-dioxo-l-anthracenesulfonlc acid — 
9,10-Dlhydro-8-nitro-9,10-dloxo-l-anthraoenesulfonlc acid, 

sodium salt. 

9,10-Dihydro-l-nitro-9,10-dioxo-2-anthroic acid 

l,'i-Dlhydro^-oxo-2,6-pyridlnedicarboxylic acid 

»l,<i-Dihydroxyanthraquinone (Qulnlzarin) 

»l,5-Dihydroxyanthraquinone (Anthrarufin) 

l,5(and 1,8) -Dihydroxyanthraquinone 

»l,8-Dihydroxyanthraquinone (Chrysazln) 

2,6-Dihjfdroxyanthraqulnone (Anthraflavlc acid) 

4,5-Dihydroxy-m-benzenedisulfonic acid, disodium salt 

2,'4-Dlhydroxybenzophenone 

»l,5-Dihydroxy-4,8-dlnltroanthraqulnone 

l,5(and l,8)-Dlhydroxy-4,8(and <i,5)-dinltroanthraquinone— - 
»l,8-Dihydroxy-A,5-dinitroanthraquinone (4.,5-Dl- 
nltrochrysazin) . 
l,5-Dihydroxy-A,8-dinitro-2,6-anthraqulnonedisulfonic 

acid. 
17a,21-Dihydroxy-9p,lip-epoxy-16p-methylpregna-l,'i-diene-3, 
20-dlone. 



ACY, 


DUP. 






TRC. 








ACY. 








DUP. 








ACY, 


DSC, 


DUP, 


NAC, SDH 


DUP. 








r^D, 


DOW, 


KPP. 




GAF. 








EK. 








DUP. 








TIL. 








DUP. 








PCW. 








DUP. 








ESA, 


GAF. 






DUP. 








GAF. 








GAF. 








DUP. 








TRC. 








LIL. 








AAP, 


HSH, 


PAT. 




ICI, 


NAC. 






ACY, 


DUP, 


TRC. 




DUP, 


GAF, 


ICI, 


TRC. 


DUP, 


TRC. 






DUP. 








GAF, 


ICI, 


TRC. 





AAP, ACY, GAF, ICI, NAC, TRC, VPC. 
AAP, ACY, DUP, GAF, ICI, MAY, NAC, TRC. 
DUP, NAC. 



NAC. 










EK. 










ICI. 










UL. 










DUP, MAY, 


NAC, TRC. 








ICI, TRC. 










MAY, NAC. 










DUP. 










DUP, GAF, 


NAC, TRC. 








SDW. 










AAP, ACY, 


CMG, DUP, EKT, 


GAF, 


HSH, ICC, 


ICI, JTC 


MAY, NAC, TRC. 








ACY, DUP, 


GAF, NAC. 








CNC, TRC. 










DUP, GAF, 


ICI. 








GAF, TRC. 










SDW. 










DUP, GAF. 










ICC, ICI, 


VPC. 








TRC. 










DUP, GAF, 


ICC, ICI. 








DUP. 










SCH. 











CYCLIC INTERMEDIATES 



—Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1966 — Continued 



Manufacturers' identification code 
(according to list in table 22) 



10,10 '-(Dihydroxyethanedlylldene)dianthrone 

'i,5-Dihydroxy-2,7-naphthalenedisulf onic acid 
(Chromotropic acid). 

6,7-Dihydroxy-2-naphthalenesulfonic acid 

3,5-Dlhydroxy-2-naphthcic acid 

llB,21-Dihydroxypregna-4,17(20)-cis-dien-3-one 

llP,21-Dlhydrcxypregna-l,'i,17(20)-cis-trien-3-one 

AjS-Dlhydroxy-S-Cp-sulfophenylazo) -2,7-naphthalene- 

disulfonic acid, trisodium salt. 
*16,17-Dihydroxyviolanthrone (Dlhydroxydibenzanthrone) — 

m-Diiodobenzene 

2,5-Diiodobenzoic acid, 2-(2-methoxyethoxy)ethyl ester- 

3,5-Diiodo^-oxo-l(iH)pyridineacetic acid- 

3,5-Diiodo-L-tyroslne 

Diisopropylbenzene 

N,N'-Diisopropyl-p-phenylenediamine 

2,5-Dimethoxyaniline 

l,5(and 1,8) -Dime thoxyanthraquinone 

2,5-Dimethoxybenzaldehyde 

m-Dimethoxybenzene 

«3,3'-Dimethoxybenzidine (o-Dianisidine) 

3,3'-Dimethoxybenzidine hydrochloride 

2,4 -Dime thoxybenzoic acid 

3,<i-Dimethoxybenzoic acid 

N,N'-[(3,3'-Dimethoxy-4,4'-biphenylylene)bis-(azo)]bls- 
(N-methyltaurine) . 

2,5 -Dime thoxy-p! -methyl- p-nitrostyrene 

N-(3,A-Dimethoxy-a-methylphenethyl)-2-('i-ethoxy-3 
methoxyphenyl) acetamide . 

2,5-Dimethoxy^'-nitrostilbene 

3,'4-Dimethoxyphenethylamine (Homoveratrylamlne) 

'i-(2 ',5 '-Dimethoxyphenethyl) aniline hydrochloride 

N-(3,';-Dimethoxyphenethyl)-2-(3,';-dimethoxyphenyl) 
acetamide. 

( 3, 4-Dimethoxyphenyl) acetic acid 

(Sj-i-Dimethoxyphenyliacetonitrile 

l-(3,4-Dimethoxyphenyl) -2-aminopropane 

l-(3,'i-Dimethoxyphenyl)-2-nitro-l-propene 

2,5-Dimethoxytetrahydrofuran 

16,17-Dimethoxyviolanthrone 

3'-Dimethylaminobenzanilide 

p-(Dimethylamino)benzenediazonium chlorozincate 

m-(Dtmethylamino) benzoic acid 

a-(Dimethylamino)-p-creeol 

6-Diinethylamino-2-[2-(2,5-dimethyl-l-phenyl-3- 

pyrryl) vinyl] -1-methyl-l-quinolinium methyl sulfate. 

2- [(2-Dimethylamino) ethyl] amlnopyrld ine — 

2- [[2-( Dijnethylamino) ethyl] -2-thenylamino] pyridine 
(uonmedicinal grade). 

2- [[2-(Dimethylamino) ethyl] -3-thenylamino] pyridine 

m-(Dimethylaiiiino) phenol 

N-(p-Dimethylaminophenyl)-l,-4-naphthoquinonelmlne 

»N,N-DlmethylaniUne 

7,12-Dlmethylbenz[a] anthracene 

3,3'-Dimethylbenzidine (o-Tolidine) 

3,3 ' -Dime thy Ibenzid ine hydrochloride 

»N,N-Dlmethylbenzylamine 

4.-(a,a-Dijnethylbenzyl)-2-phenylazophenol 

»2,2'-Dimethyl-l,l'-bianthraquinone 

Dimethyl-6,12-ceroxenol acetate 

5,5-Dimethyl-l,3-cyclohexanedione 

N,N-Dimethylcyclohexylamine 

2',7'-Dimethylfluoran 

5,5-Dimethylhydantoin— - 

2,3-DiiiiethyUndole — 

2,5-Dtmethyl-<i(2) -morpholinylmethylphenol hydrochloride 
N.N-Dimethyl-m-nitro aniline 

»N,N-Dimethyl-p-nitroEoanillne 

N,N-Dinethyl-p-phenylazoaniline 

N,N-Dlmethyl-p-phenylenediamlne 

N,N-Dinethyl-p-phenylenediamine hydrochloride 

1,'i-Dimethylpiperazine 



FMT, GAF, IDC. 

GAF. 

UP J. 

UP J. 

EK. 

ACY, DUP, GAF, ICI, MAY, NAC. 



ICO. 

CWN, DUP, LAK, SDH. 



LIL. 

LIL. 

LIL. 

LIL. 

HEX. 

DUP, GAF, ICI, 

DUP. 

ESA. 

SDH. 

TKL. 



NAC. 














ACY, DSC, 


DUP, 


NAC, 


SDH. 








EK. 














CWN, DUP. 














AAP, DUP, 


EK. 












ICO, MLS, 


RH. 












TRC. 














AAP, ACY, 


CMS, 


DUP, 


GAF, 


TCT, 


NAC, 


TRC 


WIW. 














EKT. 














DUP, EKT. 














WIW. 














GLY. 














DUP. 














IDC. 














DUP. 














ACY, DUP, 


ESA, 


NAC. 











SYNTHETIC ORGANIC CHEMICALS, 1966 



-Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 2566— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



N,N-Dimethylsulfanllic acid 

N,N-Dimethyl-p-toluidlne 

»2,'i-Dinitroanlline 

p-( 2, "i-Dinitroanl lino) phenol 

»l,5(and 1,8)-Dinitroanthraqulnone 

N,N'-(2,'i-Dinltro-l,5-anthraqulnonylene)dioxamic acid 

3',<i-Dlnitrobenzanllide 

m-Dinitrobenzene 

2,A-Dlnitrobenzenesulfonlc acid 

3,5-Dinitrobenzoic acid 

3,5-Dinltrobenzoyl chloride 

10, 10 '-Dlnitro [3,3 '-bi-7H-benz[de] anthracene] -7,7 '-dione— 

3,3'-Dinitro-A,^'-biaeetanilide 

Dinitrooaprylphenol 

2,5-Dinltro-p-cresol 

2,4--DlnltrocuiDene 

3 ',5'-Dlnitro-2'-hydroxyacetanllide 

l-(3,5-Dlnitro-2-hydroxyphenylazo)-2-naphthol 

»2,<i-Dlnltrophenol, tech 

( 2, A-Dinitrophenyl) hydrazine 

3,5-DinitrOEalicyllc acid 

*A,i,' -Dlnitrostilbene-2,2 '-disulfonlc acid 

»2,'i-Dinltrotoluene 

2,'4(9nd 2,6)-Dlnitrotoluene 

3,5-Dinltro-p-toluenesulfonio acid 

Dlnonylphenol 

2,4--Di-tert-pentylphenol 

2,4-01 -tert-pentylphenoxyacetyl chloride 

*l,5-Diphenoxyanthraquinone 

l,5(and l,8)-Diphenoxyanthraqulnone 

1,8-Diphenoxyanthraqulnone 

Dlphenylacetlc acid 

»Diphenylamine ■» 

2,8-Diphenylanthra[l,2-d:6,5-d']bisthlazole-6,12-dione 

» -d - 1 , 2 -Di pheny 1 -4— d Ime thy lamino -2 -hyd roxy-3 -me thy Ibut ane , 
camphor sulfonate. 

N,N'-Diphenylethylenedlamlne 

Dlphenylmethane 

2,5-Diphenyloxazole 

l,3-Diphenyl-l,3-propanedione 

1,3-Diphenyltriazene 

1,3-Di^-piperidylpropane 

2,2 '-Dlthiodibenzoic acid 

*l,4-Di-p-toluidlnoanthraqulnone 

1,5-Di-p-toluidinoanthraquinone 

1,8-Di-p-toluidlnoanthraqulnone 

l,'i-Di(p-toluidino) -5,8-dihydroxyanthraquinDne 

»Divinylbenzene 

Dlxylylguanidines, miaed 

Dodeoylbenzene. (See Aliylbenzenes . ) 

Dodecylbenzyl chloride 

Dodecylmethylbenzyl chloride 

«p-Dodecylphenol 

Eosin (2', 4', 5 ',7 '-Tetrabromof luorescein) 

Epoxycyclohexyladipate (Epoxide 289) 

3-(Epoxyethyl)-7-oxabicyolo[-;.1.0]heptane (Epoxide 206)—- 

o-Ethoxybenzoic acid 

6-Ethoxy-2-ben20thlazolethlol 

4-Ethoxy-3-methoxybenzaldehyde 

l-(4-Ethoxy-3-methoxybenzyl)-6,7-dimethoxy-3- 
methyllsoquinoline . 

(i-Ethoxy-S-methoxyphenyl) acetic acid 

2-Ethoxy-l-naphthaldehyde 

2-Ethoxynaphthalene 

2-Ethoxy-l-naphtholc acid 

2-Ethoxy-l-naphthoyl chloride 

4-Ethoxy-o-phenylenedlanilne 

(p-Ethoxyphenyl)urea (Dulcin) 

3-(Ethylaiiiino) -p-cresol 

3-(Ethylamlno)-p-toluenesulfonlc acid [S03H=l] 

»N-Ethylanlllne, refined 



OAF. 

EK, SEL. 

AAP, ACY, SDC. 

GAF, NAC, SDC. 

AAP, ICC, ICI, TRC. 

TRC. 

DUP. 

DUP, NAC. 

EK, TRC. 

GAM, SAL, SDH. 

EK. 

DUP, MAY. 

AAP. 

RH. 

DUP. 

DUP. 

TRC. 

TRC. 

AAP, NAC, SDC, X. 

EK. 

EK. 

ACY, DUP, OAF, GGY, 

DUP, NAC, RUC. 

DUP, M3B. 

GAF. 

GAF. 

PAS. 



DUP, GAF, ICI, VPC. 

AAP, DUP, ICC. 

EKT. 

AHA, BPC. 

ACY, DOW, DUP, ORO, RUC. 

ICI. 

Lli. 



NAC, SDH, TRC. 



DOW, 
ARA. 
ARA. 



RFC. 



MEE. 

GAF, ICI, NAC, TRC, VPC. 



AIL, 

ICI. 

ICI. 

ICI. 

DOW, FG, KPP 

ACY. 



GAF, ICIN, UCC, X. 

ICC. 

UCC. 

UCC. 

ACY. 

ARA, DUP. 

UL. 

LIL. 

LIL. 

ICO. 

ICO. 

ICO. 

ICO, OPC, TBK. 

TRC. 

fiSA. 

DUP. 

DUP. 

ACY, DUP, NAC, SDH. 



CYCLIC INTERMEDIATES 



TABLE IB.—Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i966— Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



2-(N-Ethylanilino)ethanol 

[2-(N-Ethylanilino) ethyl] trimethylammonium chloride 

3-(N-Ethylanilino)propionitrile 

a-(N-Ethylanilino) -m-toluenesulfonic acid 

a-(N-Ethylanilino)-p-toluenesulfonic acid 

N-Ethyl-p-anisidine 

N-Ethylanthranilic acid 

2-Ethylanthraquinone 

»Ethylbenzene 

o-(p-Ethylbenzoyl) benzoic acid 

Ethylbenzyl chloride 

9-Ethylcarbazole 

N-Ethyl-1-oyclohexen-l-ylamine 

N-Ethylcyolohexylamine 

3,3'-Ethylenedioxydiphenol 

Ethylenlmine 

3-Ethyl-2-[3-(3-ethyl-2-benzothiazolinylidene)- 
pentadienyl] benzothiazollum iodide. 

l,l'-Ethylidine-di-2-pyTrolidinone 

2-[N-Ethyl-p-[(6-methoxy-2-benzo-thiazolyl)azo]- 
anilino] ethanol. 

N-Ethyl-1-naphthylamine 

9-Ethyl-3-nitrocarbazole 

a-Ethyl-3-nitrociunamic acid 

p-Ethylphenol 

»N-Ethyl-N-phenylbenzylamine 

Ethylphenylmalonic acid, diethyl eeter 

l-(o-Ethylphenyl)-3-methyl-2-pyrazolin-5-one 

5-Ethyl-2-picoline (2-Methyl-5-ethylpyridlne) (MEP) 

l-Ethylpiperldine — 

2-Ethylpyridine 

N-Ethyl-5-sulfoanthranilio acid 

6-Ethyl-l,2,3,';-tetrahydro-l,l,4,<;-tetramethylnaphthalene- 

N-Ethyl-m-toluidine 

N-Ethyl-o-toluidine 

3-(N-Ethyl-m-toluidino)propionitrile 

1-Ethynyl-l-cyclohexanol 

Fluoren-9-one 

Fluorescein (3 ',6'-Dihydroxyf luoran) 

l-Fluoro-2,'i-dinitroben2ene 

o-Fluorotoluene 

•i-Fomyl-m-benzenedisulfonic acid 

o-Fonnylbenzenesulfonlo acid (o-Sulfobenzaldehyde) 

Fur an 

Furfuryl alcohol 

Furfurylamine 

N-Glycoloylarsanillc acid, sodium salt 

Hexachlorobenzene 

Hexachlorocyclopentadiene 

l,'i,5,6,7,7-Hexachloro-5-norbomene-2,3-dicarboxyliC acid- 

Hexadecachlorophthalocyanlne 

Hexaf luorobenzene 

Hexa(2-inethyl-l-aziridinyl)-l,3,5-phosphotriazine 

Hippuric acid 

p-Hydrazinobenzenesulfonic acid 

3-J^drazino-5-nitro-p-toluenesulfonic acid [SOjH'l] 

Hydrindantin 

»Hydroquinone, tech 

-i'-Hydroxyaoetanllide 

3'-Hydroxyacetophenone 

3'-Hydroxyacetophenone benzoate 

p-Hydroxybenzaldehyde 

«p-Hydroxybenzenesulfonlc acid 

2-Jfcnaroxy-llH-benzo[a]carbazole-3-carboxylic acid 

p-}^roxybenzoic acid 

p-Hydroxybenzoio acid, butyl ester-'- 

p-Hydroxybenzoic acid, ethyl ester-"- 

p-l^droxybenzoic acid, n-heptyl ester 



EKT. 



DUP, 

DUP. 

EKT. 

GAF, SDH. 

NAC, TRC, WJ. 

EKT. 

SDH. 

NAC. 

CSD, DOW, ENJ, FG, KPP, KPT, MON, SHC, SIN, SKC, SNT, 

TOG, UCC. 
NAC. 
BPG. 
ICC. 
UCC, X. 
ABB. 
IDC. 
DOW. 
GAF. 



DUP. 

ICC. 

SDW. 

ACY. 

DUP, NAC, SDH. 

BPC, MAL. 

TRC. 

UCC. 

RIL. 

RIL. 

SDH. 

GIV. 

DUP, NAC. 

DUP. 

DUP, GAF. 

cue, NAC. 

EK. 

ICC. 

EK, PIC. 

EK. 

GAF, SDH. 

GAF, SDH, VPC. 

DUP, OKO. 

QKO. 

MLS. 

SDW. 

DVC. 

HK, VEL. 

HK, VEL. 

ICC. 

WHC. 

ICO. 

BPC. 

OAF, WJ. 

STG. 

HEX. 

CHS, EKT, MAN. 

TRC. 

SDH. 

SDH. 

DOW. 

DOW, MDN, UPF. 

GAF. 

HN, WSN. 

HN, WSN. 

HN, WSN. 

WSN. 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



-Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1966 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



■»p-Hydroxybenzoic acid, methyl ester 

»p-Hydroxybenzoic acid, propyl ester-'- 

6'-Hydroxy-in-benzotoluidide 

3'-Hydroxy-2(N-benzyl-N-methylamino)acetophenone 

<i-HydroxycouBiarin 

13b -Hyd roxy -2 , 8 -d ime thy Inaphtho [ 3 . 2 . 1 -k 1] xanthen - 

9(13bH)one. 

'i'-(2-i:ydroxyethoxy)acetanilide 

m-Hydroxyethoxyphenol 

3.[N-(2-Hydroxyethyl)anilino] proplonitrlle 

3.[N-(2-Hydroxyethyl)anllino]propionitrile, benzoate 

ester. 

N-|3-Hydroxyethyl-2,'i-dihydroxybenzamde 

3-Hydroxy-N-(2-hydroxyethyl)-2-naphthajnide 

N-[ 7-Hydroxy-8- [2-hydroxy-5-(methylsulf amoylphenyl) azo] - 

1-naphthyl] acetainide. 
6'-Hydroxy-5'- [(2-hydroxy-5-nitrophenyl)azo] - 

m-acetotoluidide. 
N-[7-Hydroxy-8-[(2-hydroJcy-5-nitrophenyl)azo]-l- 

naphthyl] acetamide. 
7-Hydroxy-8-[['i'-[(p-hydroxyphenyl)azo]^-biphenylyl]azo] - 

1,3-naphthalenedisulfonic acid. 
7-Hydroxy-8-n 4 '-[ (p-hydroxyphenyl) azo] -3,3-diinethyl^- 

blphenylyljazo] -1,3-naphthalenedisulfonic acid. 

A-Hydroxy-N^-isopropylmetanilamide 

2-Hydroxy-a^,a^-mesitylenediol 

-»4-Hydroxymetanilamlde 

"^-Hydroxymetanilanilide 

»4-Hydroxymetanillc acid 

N-(/i-Hydroxymetanilyl)anthranilic acid 

4-Hydroxy-l-methylcarbostyril 

3-Hydroxy-2-methylcinchoninic acid 

4-Hydroxy-N^-methylnietanllamide 

N-(Hydroxymethyl)phthalamide 

3 -Hydroxy -N-(3-N-morpholinopropyl) -2-naphthaiidde 

2-hfydroxy-l-naphthaldehyde 

»3-Hydroxy-2,7-naphthalenedlsulfonio acid, disodium salt— 

7-Hydroxy-l,3-naphthalenedisulfonic acid 

7-Hydroxy-l,3-naphthalenedlsulfonic acid, dipotassium 

salt. 
7-Hydroxy-l,3-naphthalenedisulfonic acid, disodium salt— ■ 

4-Hydroxy-2-naphthalenesulfonamide 

l-Hydroxy-2-naphthalenesulfonic acid, potassium salt 

<i-Hydroxy-l-naphthalenesulfonlc acid 

5-Hydroxy-l-naphthalenesulfonic acid 

♦6-Hydroxy-2-naphthalenesulfonlc acid 

»6-f^droxy-2-naphthaleneBulfonlc acid, sodium salt 

7-Hydroxy-2-naphthalenesulfonic acid (Cassella's acid) 

8-Hydroxy-l-naphthalenesulfonic acid 

8->tydroxy-l-naphthalenesulfonic acid,Y-sultone 

3-Hydroxy-2-naphthanlUde (Naphthol AS) 

l-Hydroxy -2 -naphthoic acid 

3-Hydroxy-2-naphtholc acid (B.O.N.) 

3-Hydroxy-2 -naphthoic acid, methyl ester 

»3-Hydroxy-2-naphtho-o-toluidide 

N-(2-Hydroxy-l-naphthyl) acetamide 

*N-(7-I^droxy-l-naphthyl)acetajiiide 

l-( 2-Hydroxy-l-naphtl^lazo) -6-nitro-2-naphthol-4-sulf onic 

acid. 

N-(7-}fydroxy-l-naphthyl)benz amide 

3 '- [(7-Hydroxy-l-naphthyl)carbei!ioyl] acetanillde 

4-Hydroxy-7-[p-(p-nltrobenzamldo)benzamido] -2-naphthalene- 

sulfonic acid. 
';-Hydroxy-7-(p-nltrobenzamido)-2-naphthalenesulfonlc acid- 

2-Hydroxy-5-nitrometanilic acid 

3-Hydroxy-4-( phenylazo) -2 -naphthoic acid 

llx -Hydroxyprogesterone 

A-Hydroxypropiophenone 

a, a'-[(a-Hydroxy-p-sulfobenzylidene)bi6[ (3-methyl- 

p-phenylene)(ethyllmlno)]] di-m-toluenesulfonlc acid. 

See footnotes at end of table. 



HN, ICO, LEM, SEL, WSN. 
HN, ICO, LEM, WSN. 

TRC. 
SDW. 
ABB. 

wm. 



TRC. 








ACY. 








CM3, 


DUP, 


NAC, 


TRC, VPC 


TRO. 








CWN, 


DUP, 


NAC, 


TRC. 


TRC. 








ICC. 








DUP. 








TRC. 








ACY. 








IDC. 








ICO. 








ACY, 


GAF, 


NAC, 


TRC, WJ. 


DUP, 


TRC. 






OAF. 








ACY, 


NAC. 






GAF. 








EK. 








DUP, 


NAC. 






NAC, 


TRC. 






NAC, 


SNA, 


IMS. 




ACY, 


TRC, 


WJ. 




DUP. 








GAF, 


VPC. 






ACY, 


TRC. 






ATL, 


BUC, 


PCW. 




NAC. 








AUG, 


DUP, 


HN, 


PCW. 


PCW. 








ATL, 


BUC, 


PCW. 




ACY. 








CM3, 


GAF, 


TRC. 




TRC. 








TRC. 








TRC. 








DUP. 








DUP, 


GAF. 






TRC. 








ICC. 








UP J. 








MLS. 








TRC. 









CYCLIC INTERMEDIATES 



TABLE 7B. — Cyclic iTitermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1966— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



2-Hydroxy-4-sulfo-l-naphthalenediazoniujn hydroxide, inner 
salt. 

5-Hydroxy-m-toluenesulfonic acid : 

l-Hydroxy-4-p-toluidinoanthraquinone 

2-Imidazolidinone modifications 

»l,l'-Iinlnobls 

l,l'-Iminobis 

l,l'-Iminobls 
»7,7'-Imi nobis 
»l,l'-Iniinobis 



-aminoanthraquinone] 

-benzamidoanthraquinone] 

S-benzamidoanthraquinone] 

-hydroxy-2-naphthalenesulfonic acid] 

-nitroanthraquinone] 

*l,l'-Iminodianthraquinone (l,l'-Dianthrimlde) 

1,3-Indandione 

1,2,3-Indantrione monohydrate (Ninhydrin) 

Indole -3 -acetic acid 

Indole-2,3-dione 

5-Iodoanthranllic acid 

1-Iodonaphthalene 

Isobutylbenzene 

»Isocyanlc acid derivatives: 

Bitolylene diisocyanate (TODI) 

Cyclohexyl isocyanate 

Dianisldine diisocyanate (DADI) 

3,4-Dichlorophenyl ester 

•»Diphenylinethane "ij'l'-diisocyanate (MDI) 

p-Nitrophenyl ester 

Phenylisocyanate 

Polyisocyanates (complex) 

Polymethylene polypheny lisocyanate 

Toluene 2,<i-dlisocyanate 

Toluene 2,4- and 2,6-diisocyanate (65/35 mixture) 

»Toluene 2,4- and 2,6-diisocyanate (80/20 mixture) 

p-Tolyl ester 

Isonicotinic acid, methyl ester 

Isonicotinonitrile 

Isooctylphenol 

Isophthalic acid (Benzene-l,3-dicarboxylic acid) 

Isophthalic acid, diallyl ester 

Isophthalic acid, dimethyl ester 

Isophthalic acid, diphenyl ester 

N-Isopropylaniline 

Isopropylbenzyl chloride 

4,4'-Isopropylldenebis[2,6-dibromophenol] (Tetrabromo- 

bisphenol A) . 
4.,4'-Isopropylidenebis[2,6-dichlorophenol] (Tetra- 
chlorobisphenol A) . 

5,5'-Isopropylldenebis(2-hydroxy-m-xylene-a, a'-diol) 

»4,4'-Isopropylidenediphenol (Bisphenol A) 

4,4'-IsopropyHdenedlphenol, ethoxylated 

4,4'-Isopropylldenediphenol, propoxylated 

o-Isopropylphenol 

4-Isopropyl-m-phenylenediamine 

Isothiocyanic acid, phenyl ester 

«Isoviolanthrone (Isodibenzanthrone) 

»Leuco quinizarin (1,4,9,10-Anthratetrol) 

*2,'i-Lutidlne 

3,4-Lutldine— 

D-Iyserglc acid 

Malondianilide 

Mandelonitrile 

«Melamine 

»dl-p-Mentha-l,8-diene (Limonene) 

p-Mentha-l,4(8) -dlene 

»o-Meroaptobenzoic acid (Thiosalicylic acid) 

Metanllamlde 

Metanllanilide 

Metanilic acid (m-Aminobenzenesulfonic acid) 

l-Methoxyanthraquinone 

4-Methoxymetanlllc acid 

4' -Methoxy-2-(p-methoxyphenyl)acetophenone 

4-Methoxy-N-methylnaphthalimlde 

N-(2-Methoxy-l-naphthyl)acetamide 

6-Methoxy-8-nitroquinoline 



RH. 










ACY, CMG, 


DUP 


GAF 


ICI 


MAY, NAC, TRC 


ACY, MAY 










GAF, ICI, 


TRC. 








C^G, DUP, 


NAC 


TRC. 






ACY, DUP, 


ICI, 


MAY 


TRC 




ACY, DUP, 


GAF 


ICI 


MAY 


NAC, TRC. 


PIC. 










HEX. 










SDW. 










NAC. 










SDW. 










EK. 










PLC. 










UP J. 










CWN, OTC. 










CWN, UPJ. 










DUP. 










DUP, MOB, 


NAC 


UPJ. 






EK. 










MOB. 










MOB. 










KAI, MOB, 


UPJ. 








DUP, MOB. 










DUP, ICIB. 










DUP, MOB, 


NAC, 


OMC, 


RUC 


ucc. 


EK. 










RIL. 










RIL. 










PRD. 










ACC, SOC. 










FMP. 










MTR. 










BJL. 










ACY, EKT. 










BPC. 










DOW. 










DVC. 










ARK. 










DOW, MON, 


SHC, 


UCP. 






APD. 










APD. 










TNA. 










DUP. 










TNC. 










ACY, DUP, 


GAF, 


ICI, 


MAY. 




ACY, BL, 


5KT, 


•ISH, 


ICC, 


NAC, TRC. 


AC?, CFC, 


KPT, 


RIL. 






RIL. 










LIL. 










KF. 










KF. 










ACP, ACY, 


FIS, 


RCI. 






ARZ, GIV, 


HNW, 


HPC. 






GIV. 










F/N, LIL, 


MED. 








CKD, VPC. 










GAF. 










DUP, TRC. 










A.y, GAF. 










CIiCl, GAF. 










CTN. 










TRC. 










TRC. 










SDW. 











SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE IB.— Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i566~Contlnued 



Manufacturers' identification codes 
(according to list in table 22) 



(p-ftethoxyphenyl) acetic acid 

'i'-Methoxypropiophenone 

6-lfethoxy-tetralone 

»l-(Methylamlno)anthraquinone 

l-(Methylamino)-A-p-toluldinoanthraquinone- 

N-Methylanlline 

3-(N-Methylanilino)propionitrile 

5-Methyl-o-anisidine [NH2=1] 

m-Methylanisole 

N-Jtethylanthranilic acid — 

2-»fethylanthraqulnone 

3-Methylbenzo[f ]quinoline 

2-Mett^rlbenzothiazole 

N-Methylbenzylamine 

Methyl benzyl ether 

5 -( 1-Me thy Ibutyl) barbituric acid 

3-Methylcholanthrene 

Methylcyclohexane 

Methylcyclohexenecarboxaldehyde 

4-Methyl-a,a-dlphenyl-l-piperazineethanol, 
chloride. 

N-Methyleneaniline 

-4, 'i'-Methylenebis[2-chloro aniline" 



-MethyleneblsfN.N-dimethylanllineJ (Methane base) - 
4,4 '-Methylenebis[N,N-dimethyl-3-nitroani line] 
2,2'-l*thylenebis(6-nonyl-p-cresol)- 
5,5'-Methylenebis[toluene-2,4-diaiiiine] ■ 
«4 ,4 ' -Methylenediani line - 

5,5'-ltethylenedisalicylic acid - 

5-Kfethylene-2-norbomene 

N-Methylformanilide 

2-ktetlyrlfuran 

Methylhydroquinone 

2-Methylindole-3-carboxaldehyde 

6 -Methyl -2-( 2 -methyl-6-quinolyl) -y-benzothiazolesuOf onic 

acid. 

Methylnaphthalene, crude 

1-Me thy Inaphthalene 

N-Methyl-4'-nitroacetanilide 

N-Methyl-p-nitro aniline 

4-Jfethyl-2-nitroanisole- 

2-Methyl-l-nitroanthraquinone 

2-Methyl-5-nitroimidazole— — — 

N-Methyl-N-nltroso-p-toluenesulfonamlde 

2-Methyl-5-norbornene-2,3-dicarboxylic anhydride 

Methylnorbomene-2,3-dicarboxylic anhydride, isomers 

4-Methyl-7-oxabicyclo[4.1.0]heptane-3-carboxylic acid, 

(4-methyl-7-oxabicyclo[<;.1.0] hept-3-yl) -methyl ester 

(Epoxide 201). 
3'-Methyl-5- [(7-oxo-7H-benz[de]anthraoen-3-yl)-amino] - 

1,2 '-iminodianthraquinone . 

»m-( 3-Kfethyl-5 -oxo-2-pyrazolin-l-yl) benzenesulf onamide 

m-(3-Jtethyl-5-oxo-2-pyrazolin-l-yl)ben2enesulfonic acid 

•p-(3-Methyl-5-oxo-2-pyTazolin-l-yl) benzenesulf onic acid 

3-(3-Methy 1-5-0X0-2 -pyrazolin-1-yl) -1,5-naphthalene- 

disulfonic acid. 
6-(3-MBthyl-5-oxo-2-pyrazolin-l-yl)-l,3-naphthalene- 

disulfonic acid. 
•4-( 3-Methyl-5-oxo-2-pyrazolin-l-yl) -m-toluenesulf onic 

acid [SOjH^l]. 

2-Methyl-5-phenylbenzoxazole 

l-Methyl-2-phenylindole 

l-Methyl-2-phenylindole-3-carboxaldehyde 

l-Methyl-4-phenylisonlpecotic acid 

5 -Methyl -3-phenyl-4-isoxazolecarboxy lie acid 

5-Methyl-3-phenyl-4-isoxazolecarboxylic acid hydro- 
chloride. 

»3-Methyl-l-phenyl-2-pyrazolin-5-one (Developer Z) 

ktethyl phenyl sulfide (Thioanisole) 

1-Methylpiperazine 

4-Methyl-l-piperazineacetic acid, methyl ester 



CTN, TBK. 






LIL. 






GAM. 






AAP, ACY, 


DUP, 


GAF, ICI, NAC, UCC 


GAF, ICI. 






ACY, DUP. 






DUP. 






DUP, SDC. 






GIV. 






GIV, ICC. 






ACY, NAC. 






ACY, DUP, 


GAF. 




FMT. 






ICO, MIS, 


SDW. 




UCC. 






LIL. 






EK. 






DOW, PLC. 






UCC. 






ABB. 






DUP. 






DUP. 






ACY, GAF, 


SDH. 




ACY, DSC, 


DUP, 


GAF, NAC, SDH, X. 


GAF. 






ACY. 






DUP. 






DOW, DUP, 


NAC. 




HN. 






DOW. 






MLS. 






QKO. 






EKT. 






GAF. 






DUP. 






KPT. 






HMY. 






GAF, NAC. 






GAF. 






DUP. 






DUP, GAF, 


ICI 


NAC. 


RDA. 






ALD, EK. 






VEL. 






NAC. 






UCC. 







DUP. 

CXC, TRC, VPC. 

GAF, TRC, VPC. 

AAP, ACY, cm, DUP, GAF, TRC, VPC. 

TRC. 

TRC. 

CVC, TRC, VPC. 



GAF. 
GAF. 
SDW. 
ICO. 
ICO. 



ACY, DOW, DUP, NAC, SDC, SDH, SDW, VPC. 

PIT. 

UCC. 

ABB. 



CYCLIC INTERMEDIATES 



85 



TABLE TB.— Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 2966— Continued 



Manufacturers' Identification codes 
(according to list in table 22) 



2-Methyl-l-piperldlnepropanol 

3-Methyl-2-pyrazolin-5-one 

l-Methylpyrrole 

»a-Methylstyrene 

2-(Msthylsulfonyl)^-nltro aniline 

Methyl 2-thienyl ketone 

4-(Methylthlo)-iii-cresol 

3-Methylthlophene 

p-(Msthylthio) phenol - 

6'-Methyl-<i'-p-toluenesulfonaiiiido-m-benzanisldlde 

3-MBthyl-6-p-toluidlno-7H-dlbenz[f ,ij] Isoquinollne- 
2,7(3H)-dione. 

3-Methyl-l-m-tolyl-2-pyrazolin-5-one 

3-Methyl-l-p-tolyl-2-pyrazolin-5-one 

1-Naphthaldehyde - - — 

♦Naphthalene , solidifying at 79"^' C. or above (refined 
flake) (from domestic crude). 

1,5-Naphthalenediol (1,5-Dihydroxynaphthalene) 

l,5-Naphthalenedi8ulfonic acid 

•2,7-Naphthalenedisulfonic acid 

1-Naphthalenesulfonlc acid 

l-Naphthalenesulf onlc acid, sodium salt 

2-Naphthalenesulfonic acid 

2-Naphthalenesulfonlc acid, sodium salt 

2-Naphthalenesulfonyl chloride 

*l,4,5,8-Naphthalenetetracarboxylic acid 

1,3,6-Naphthalenetrlsulfonic acid 

Naphthallc anhydride 

Naphthalimide 

2H-Naphth[l,8-od] isothiazole-3,5-disulfonlo acid, 

1,1-dloxlde, trlsodium salt. 
1-Naphthoic acid 

»l-Naphthol (:<-Naphthol) 

2-Naphthol, tech. (p-Naphthol) ^ 

p-Naphtholbenzein 

1,4-Naphthoqulnone 

"Naphthostyril 

»Napth[l,2-d][l,2,3]oxadlazole-5-sulfonic acid 

1-Naphthylamlne (c-Naphthylamine) 

2-Naphthylamlne ( p-Naphthylamine) 

p-(2-Naphthylamino) phenol (N-(p-Hydroxyphenol) -2- 
naphthylamine) . 

2-(Naphthylthio) acetic acid 

Niootinonitrile (3-Cyanopyridine) 

Nitro-aoeanthra[2,l-a] aoeanthrylene-5,13-dlone 

3'-NltroaoetanlUde 

4'-Nltroacetanillde 

2'-Nltro-p-acetanisidide 

3'-Nltro-p-aoetanisidide 

-i'-Nltro-o-acetanisidide 

2'-Nitro-p-aoetophenetidide 

3'-Nitroaoetophenone 

5'-Nltro-o-acetotoluidlde 

m-Nitro aniline 

o-Nltro aniline 

«p-Nitro aniline 

2-(o-Nltroanilino)ethanol 

2-Nitro-p-anlsidine [NHj^I] 

A-Nltro-o-anisldine [NH2=l] - 

»5-Nltro-o-anlsidine [NHj'll ■ 

o-Nitroanisole 

p-Nitroanlsole 

'V-Nltroanthranilic acid 

5-Nitroanthranllic acid 

l-Nitroanthraqulnone 

2-(4-Nitro-2-aiithraqulnonyl) anthra[ 2,3-d] -oxazole- 
5,10-dione. 

m-Nitrobenzaldehyde 

3'-Nitrobenzanlllde 

-i'-Nitrobenzanilide 

See footnotes at end of table. 



LIL. 




DUP. 




DUP. 




ACP, CLK, 


DOW, HPC, SKO 


EKT, TRC. 




SDW. 




CRZ. 




SDW. 




CRZ. 




GAF, NAC. 




GAF, ICI. 




DUP. 




VPC. 




COK. 




KPT, NAC, 


RIL. 


NAC. 




GAF, NAC. 




DUP, NAC, 


SDH. 


TRC. 




■mc. 




ACY, NAC. 




ACY. 




DUP, GAF. 




GAF, HST, 


TRC. 


GAF. 




DUP. 




DUP, GAF, 


NAC. 


DUP. 




COK. 




DUP, NAC, 


ucc. 


ACY, NAC, 


SW, X. 


EK. 




EKT. 




DUP, GAF, 


NAC. 


CM3, GAF, 


NAC, TRC, VPC 


DUP, NAC. 




X. 




NAC. 




ACY, GAF, 


VPC. 


NEP, RIL. 




ICI. 




GAF, IHC. 




GAF, TRC. 




DUP, SDH. 




GAF. 




DUP. 




AAP. 




SDH. 




DUP. 




ACY, X. 




AAP, MDN. 




AAP, MON, 


SDC, \jm. 


AAP, MED. 




DUP, SDH. 




AAP, DUP, 


SDH. 


ACY, ALL, 


BUC, DUP. 


DUP, MDN. 




DUP. 




DUP. 




TRC. 




ACY, MAY. 




GAF, NAC. 




NAC, SDH. 




DUP. 




GAF. 





SYNTHETIC ORGANIC CHEMICALS 1966 



TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i 966- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



♦Nitrobenzene 

3 '-Nitrobenzenesulfonanilide 

»m-Nitrobenzenesulfonic acid 

om-Nitrobenzenesulfonic acid, sodium salt 

m-Nitrobenzenesulfonyl chloride 

p-Nitrobenzenesulfonyl chloride 

5-Nitro-2-benzimidazolinone 

m-Nitrobenzoic acid 

m-Nitrobenzoic acid, sodium salt 

p-Nitrobenzolc acid 

6-Nitro-2-benzoxazolinone 

2-(m-Nitrobenzoyl)-o-acetanisidide 

m-Nitrobenzoyl chloride 

p-Nitrobenzoyl chloride 

p-Nitrobenzyl alcohol 

4'-Nitro-<;-biphenylcarboxylic acid 

2-Nitro-p-cresol 

Nitrocyclohexane 

Nitrodiphenylamine 

5-Nitro-2-furaldehydesemioxamazone 

5-Nitro-2-furanmethanediol, diacetate 

5-Nitroisophthalic acid 

1-Nitronaphthalene 

3-Nitro-l,5-naphthalenedisulfonic acid 

4-Nltronaphthalic anhydride 

»7(and 8) -Nitronaphth[l,2-d] [1,2,3] oxadiazole-5-sulfonic 
acid. 

■i'-Nitrooxanilic acid — 

o-Nitrophenol 

»p-Nitrophenol 

»p-Nitrophenol, sodium salt 

'i'-(p-Nitrophenyl)acetophenone 

4-[(p-Nitrophenyl)azo]-o-anisidine 

2-Nitro-p-phenylenediamine 

"i-Nitro-o-phenylenediamine 

(p-Nitrophenyl) hydrazine 

2,2'-(m-Nitrophenylimino)diethanol 

2,2'-(m-Nitrophenylimlno)dlethanol, diacetate ester 

2-(p-Nitrophenyl) -2H-naphtho[l,2-d] triazole-6,8-disulfonlo 

acid. 
2-( p-Nitrophenyl) -l-octadecyl-5-benzimidazolesulfonio 
acid. 

l-(m-Nitrophenyl) -5-oxo-2-pyTazoline-3-carboxylic acid 

3-Nitrophthalio acid 

3-Nitrophthallc anhydride 

4-Nitrophthalimide 

5-Nitrosalicylaldehyde 

3(and 5) -NitrosalicyUc acid— - 

p-Nitrosophenol 

P -Nitrostyrene 

4-Nitro-4'-(5-suli'o-2H-uaphthol [1,2-d] triazol-2-yl)-2,2'- 
stilbenedisulfonic acid. 

m-Nitrotoluene 

o-Nitrotoluene 

p-Nitrotoluene 

Nitrotoluene mixtures 

5-Nitro-o-toluenesulfonanilide 

p-Nitrotoluenesulfonlc acid 

»3-Nitro-p-toluenesulfonic acid [SOjH^l] 

»5-Nitro-o-toluenesulfonic acid [sOjH^l] 

5-Nitro-o-toluenesulfonyl chloride 

3-Nitro-p-toluic acid, methyl ester 

»2-Nitro-p-toluidine [nHj'I] 

4-Nitro-o-toluidine [NHj'l] 

»5-Nitro-o-toluidine [nH2=1] 

5-Nitro-2-p-toluidinobenzenesulfonic acid 

3-Nltrotoluoyl chloride 

*16-Nitroviolanthrone 

4-Nltro-m-xylene 

Nitroxylenes, mixed 

Nonyl-dinonylphenol, mixture 

•Nonylphenol 



DUP, GAF, MDN, NAC, RUC. 



DUP, NAC. 
MDN, MRA, RBC. 



SDW. 
SDH, WAY. 



ACY, MDN. 

NOR. 

NOR. 

GAF, GAM. 

DUP, NAC. 

GAF, NAC, TRC. 

GAF, NAC. 

GAF, NAC, TRC, VPC. 

DUP. 

DUP. 

DUP, KKN, SDC, UPM. 

MDN, U™. 

DUP, OAF. 

AAP. 

WAY. 

DUP, FMT. 

EK. 

DUP. 



TRC. 



EK. 










DUP. 










EK. 










EK. 










ACY, 


DUP, 


NAC. 






CWN. 










TRC. 










DUP, 


NAC. 








DUP, 


NAC. 








DUP. 


NAC. 








DUP, 


NAC. 








GAF. 










GGY. 










AAP, 


cm, 


TRC. 






ACY, 


DUP, 


GAF, 


NAC, 


SDH, TRC 


GAF. 










SDH. 










ACY, 


DUP, 


SW. 






GAF. 










BUG, 


DUP, 


PCW, 


SDH. 




TRC. 










X. 










ACY, 


ATL, 


GAF, 


ICI, 


MAY, TRC 


DUP. 










NAC. 










.ICC. 










GAF, 


JCC, 


MDN, 


PHD, 


RH, STP, 



CYCLIC INTERMEDIATES 



-Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, 1966 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



5-Norbomene-2,3-dloarboxyllc anhydride 

Octylphenol 

7-0xabicyclo[4.1.0]heptane (Cyclohexene oxide) 

Oxalacetic acid, diethyl ester, (p-sulfophenyl)hydrazone — 
Oxanllide 

»1- [( 7-0x0 -7H-benz [de] anthracen-3-yl)aiidno]anthraqulnone 

»l,l'-[(7-0xo-7H-benz[de] anthracen-3,9-ylene) - 
d iimlno ] d i anthraquinone . 

2-Oxocyclohexanecarboxylic acid, ethyl ester 

»5-0xo-l-phenyl-2-pyrazollne-3-carboxyllc acid, ethyl 
ester. 
5-0xo-l-(p-sulfophenyl)-2-pyrazoline-3-carboxylic acid 
(Pyrazolone T) . 

5-0xo-l-(p-suli'otolyl) -2-pyrazollne-3-carboxylic acid 

iji'-Oxydianiline 

Penicillin, N-ethylpiperidine salt 

Pentachloronitrobenzene 

Pentylnaphthalenes (Amylnaphthalenes) 

o-Pentylphenol (o-Aniylphenol) 

p-tert-Pentylphenol 

3,4,9, lO-Perylenetetracarboxy lie acid 

3,"i,9,10-Perylenetetracarboxylic 3,<;:9,10-diiiiiide 

Phenethylamine 

Phenethylamine sulfate 

o-Phenethylbenzoic acid 

o-Phenetidine 

p-Phenetidine 

Phenetole 

♦Phenol: 
♦Natural: 

»From coal tar: ^ 

39° C, m.p 

82?J-84* — 

All other 

♦From petroleum 

♦Synthetic : 

By caustic fusion: U.S.P 

From chlorobenzene by liquid-phase hydrolysis: U.S.P 

From chlorobenzene by vapor-phase hydrolysis: U.S.P 

♦From cumene by oxidation: U.S.P 

PhenolsulXonaphthalein 

Phenolsulfonaphthaleln, sodium salt 

Phenothiazln-2-yl-l-propanone 

Phenoxyacetic acid, sodium salt 

2-Phenoxypropanol 

2-Phenoxypropionlc acid 

2-Phenoxypropionyl chloride 

♦Phenylacetlc acid (a -Toluic acid) 

Phenylacetlc acid, ethyl ester, tech 

Phenylacetlc acid, methyl ester 

♦Phenylacetlc acid, potassium salt 

♦Phenylacetlc acid, sodium salt 

♦Phenylacetonitrlle (a-Tolunitrile) 

ii'-Phenylaoetophenone 

Phenylacetyl chloride 

2-Phenylanthra[2,3-d]oxazole-5,10-dione 

♦p-Phenylazoanillne (C.I. Solvent Yellow 1) and hydro- 
chloride. 

A-(Phenylazo)(Jiphenylamlne 

4-(Phenylazo) -1-naphthylamlne 

4— (Phenylazo) -m-phenylenediamine (C.I. Basic Orange 2) 

5-(Phenylazo) salicylic acid 

l-Phenyl-l,3-butanedlone 

2-Phenylbutyric acid 

a-Phenyl-o-cresol 

1-Phenylcyclopentanecarboxylic acid 

1-Phenyldeoane (Decylbenzene) 

N,N'-p-PhenylenebisIacetamlde] 

m-Phenylenedl amine 

o-Phenylenedl amine 

See footnotes at end of table. 



TRC. 






WRN. 






ACY, 


DUP, 


GAF, 


ACY, 


DUP, 


GAF, 


ARA. 






GAF, 


SDW, 


VPC. 



ICI, MAY, TRC. 
ICI, MAY, TRC. 



AAP, GAF, ICI, VPC. 



PAS. 










PAS. 










PAS. 










GAF, NAC. 










DUP, GAF, 


NAC. 








ms. 










MLS. 










LIL. 










M3N. 










DOW, MON. 










RSA. 










KPT, PRD. 










ACP, KPT. 










ACP, KPT. 










MER, NPC, 


PIT, 


PRD, 


SW. 




MAL, MON, 


RCT. 








DOW. 










HKD, UCC. 










ACP, CLK, 


HPC, 


MON, 


SHC, 


SKO, SOC 



ICO. 








ICO. 








ICO, 


OPC. 






BPC, 


GIV, 


MAL, 


TBK 


BPC. 








BPC. 








BPC, 


OPC, 


TBK. 




BPC, 


OPC. 






BPC, 


OPC, 


SDW, 


TBK 


DUP, 


GAF. 






ICO. 








GAF. 








ACY, 


GAF, 


NAC. 




EK. 








DUP. 








DUP. 








TRC. 








EK. 
BPC. 
RBC. 
SK. 
NAC. 
ACY, 


GAF. 






ACY, 


DUP, 


NAC. 




DUP, 


FMT, 


MEE, 


THC. 



SYNTHETIC ORGANIC CHEMICALS. 1966 



-Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, J966— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



*p-Phenylenediamine 

d-Phenylephrine base 

dl-Phenylephrine base 

2-Phenylethenesulfonic acid, sodium salt (p-Styrene- 
sulfonic acid, sodium salt). 

Phenyl ether (Diphenyl oxide) 

d-(-) -2-Phenylglyclne and derivatives 

d-(-)Phenylglycine, N-carboxy anhydride 

dl-2-Phenylglycine (racemic) 

Phenylglycine, sodium salt 

d-( -)Phenylglycyl hydrochloride 

5-Phenylhydantoin 

Phenylhydrazine 

Phenylhydrazine hydrochloride 

2,2'-[(Phenyl)imino]dlethanol (N-Phenyldiethanolamlne) - 

3,3 '-[( Phenyl) imlnojdipropionltrile 

Phenylmagneslum bromide 

Phenylmalonic acid, diethyl ester 

o-Phenylphenol >- — 

o-Phenylphenol, chlorinated 

o-Phenylphenol, sodium salt 

p-Phenylphenol 

N-Phenyl-p-phenylenediamine 

Phenylphosphinlc acid 

Phenylphosphonlc dlchloride 

Phenylphosphonothioic dlchloride 

Phenylphosphonous acid 

Phenylphosphonous acid, sodium salt 

Phenylphosphorous dlchloride 

•l-Phenyl-l,2-propaiiedlone, 2-oxime 

Phenyl-2-propanone 

N-3-Phenylpropyl-p-toluidine 

Phenyl sulfone 

Phenylundecanoic acid 

Phloroglucinol 

l(2H)-Phthalazinone - 

Phthallc acid— 

Phthalic acid, diallyl ester 

Phthalic acid, dlsodlum salt 

»Phthallc anhydride 



PhthaUde ~ - 

Phthalimlde 

Phthalimide, potassium salt 

1Phthalooyaninato(2-)] copper ' 
Phthalocyanlnato( 2-)] iron 

Phthalocyaninetetrasulfonyl chloride, copper derivative - 
Phthaloyl chloride (Phthalyl chloride) . 

•Picolines:^ 

»2-Piooline (a-Picoline) 

3-Picoline (P-Pioollne) 

■i-Picoline (y -Picollne) 

Picoline (3,4-mixture) 

Plcollnlc acid 

Plcollnonltrile (2-Cyanopyrldine) 

3-Picolylamiue 

Picric acid (Trlnitrophenol) 

2-Pipeooline 

<i-Pipecollne 

Plperazlne mixture, crude-^ 

•Plperldine 

3-Piperldlnopropiophenone hydrochloride 

Polyohlorobiphenyl 

Poly (Methylenephenylene) polyamine 

Primullne base 

Prlmulinesulfonlo acid 

lO-Propionylphenothleuslne 

•Propiophenone 

n-Propylbenzeue 

2-Propylpyridlne 

See footnotes at end of table. 



ACY, BFG, SDC. 

SDW. 

SDW. 

SHL. 

DOW. 

KF. 

OTC. 

KF. 

NAC, OTC. 

OTC. 

ABB, X. 

DOW. 

EK, VPC. 

EKT, aAF. 

DUP. 

ARA. 

BPC. 

DOW, RCI. 

DOW. 

DOW. 

DOW. 

DUP, USR. 

SF. 

SF. 



SF. 

NEP, ORT, X. 

ORT, SK. 

EK. 

NES. 

EK. 

MRT. 

KPT, NAC, X. 

EK, KF, MEE. 

FMP. 

TNC. 

ACP, GRH, HH, KPS, MON, PCC, PTO, RCI, SOC, STP, 

THC, UCC, WTC. 
FMT, NAC. 
DUP, MEE, NAC. 
EK, SDW. 
ICC, ICI. 
DUP. 

DUP, TRC. 
M3N. 

ACP, KPT, RIL, UCC. 

NEP, RIL. 

RIL, UCC. 

ACP, KPT. 



RIL. 

NAC, SDC, X. 

LIL. 

RIL. 

JCC, X. 

ABB, DUP, HK, MRK, RIL. 

ACY. 

MDN. 

KAI. 

DUP, NAC. 

ATL. 

ABB. 

IIL, OPC, ORT, TBK. 

EK. 

RIL. 



CYCLIC INTERMEDIATES 



-Cyclic iniermediatrs jor which U.S. production or sales were reported, identified by 
manufacturer, 1966— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



»8,16-PyTanthrenedione 

Pyridine, refined:^ 
•2° Pyridine 

Other grades 

2-Pyridineethanol 

3-Pyridinemethanol 

Pyridine-n-oxide 

Pyridinlum bromide perbromide 

3-Pyridinol 

2( LH) -Pyridone 

2-Pyrlmidinol 

2-Pyrrolidinone 

3-(l-Pyrrolidinyl)propiophenone hydrochloride 

lH-Pyrrolo[2, 3-6] pyridine 

oQuinaldine 

Qulnoline : 

1° and 2° QuinoUne 

Other grades 

2,<;-Quinolinediol - 

8-Quinolinol (8-Hydroxyquinoline, tech.) 

Qulnophthalone ((Juinollne yellow, base) 

Resorclnol, monoacetate (nonmedicinal grade) ■"■ 

Resorcinol, tech-"- 

p -Resorcylaldehyde 

P -Resorcylio acid 

p-Resoroylic acid, lead salt 

♦Salicylaldehyde 

•Salicylic acid, tech 

Salloyllo acid, ammonium chromium complex 

Salicylic acid, sodium chromium complex 

Salicylic acid, sodium salt (crude) 

Salicylic acid, strontium salt, tech 

Salicylideneaminoguanidine oleate 

Sodium phenoxide 

»Styrene, all grades 

5-Sulfamoylanthranilic acid 

Sulfanllic acid (p-Aminobenzenesulfonic acid) and salt- 
<;-Sulfoaiithranlllc acid 

o-Sulfobenzolc acid, cyclic anhydride 

a, a- [(p-Sulfobenzylldene)bis[(3-methyl-p-phenylene) 
(ethylimino)]] di-m-toluenesulfonlc acid. 

5-Sulfoisophthallc acid, 1,3-diiiiethyl ester 

N,5'-SulfonyldianthraniUc acid 

'i,<i^Sulfonyldiphenol {^,A '-Dihydroxydiphenylsulfone) — 

»Terephthalio acid 

Terephthallc acid, dihydrazide 

»TerephthaUc acid, dimethyl ester 

Terphenyl ( Phenylbiphenyl) 

l,2,'i,5-Tetraamlnoben2ene tetrahydrochloride 

[A,A' ,A" ,A" '-Tetraaminophthalocyaninato(2-)]copper--- 
3',3",5',5"-Tetrabromophenolphthalein, ethyl ester— 

Tetrabromophthalie anhydride 

TetrabroinD-8,16-pyranthrenedione 

1,3,6,8-Tetrabromopyrene 

•1,4,5,8-Tetrachloroanthraquinone 

1,2,4,5-Tetrachloroben2ene 

l,2,'i,5-Tetrachloro-3-nitrobenzene 

a, a,2,6-Tetrachloro toluene 

Tetrachloroviolanthrone 

Tetrahydrofuran 

Tetrahydro-2-methylfuran 

«l,'i,5,8-Tetrahydroxyanthraquinone, leuco derivative 

»1,4.,5,8-Tetrakis( l-anthraqulnonylamlnD) anthraqulnone 
(Pentanthrimlde). 

2-(l,l,3,3-Tetramethylbutyl)-p-cresol 

p-(l, 1,3, 3-Tetramethylbutyl) phenol 

N,N,N',N'-Tetramethyl-p-phenylenediamlne 

[-4,4' ,4",-; ' ' '-Tetranltrophthalocyaninato(2-) ) copper--- 
2-(2-Thenylami no) pyridine 

See footnotes at end of table. 



cm, ICI, TRC. 



RIL. 

EK, RIL. 

RIL. 

AHA. 

NEP. 

FMT. 

GGY. 

GAF. 

LIL. 

SDW. 

ACY, DUP, NAC. 

ACP, KPT. 

EK, FMT. 

DUP. 

GAM. 

NAC. 

AAP. 

KPT, UPF. 

OAF. 

ACY, KPT. 

ACY. 

DOW, HN, MTR, RDA. 

CFC, DOW, HN, MON, 

TRC. 

TRC. 

DOW. 

TNC. 

DUP. 



ACC, CSD, DOW, ELP, FG, KPP, MCB, MON, SHC, SKC, SNT, 
UCC. 



TRC. 








GAF, 


M3N, 


UPF. 




ACC, 


DUP, 


EKT. 




DUP. 








ACC, 


DUP, 


EKT, 


HPC 


JON. 








BJL. 








DUP. 








EK. 








MCH. 








GAF, 


NAC, 


TRC. 




GAF. 








DUP, 


GAF, 


ICI, 


NAC 


DOW, 


DVC, 


HK. 




SDH. 








DUP. 








GAF, 


ICI. 






DUP, 


QKO. 






DUP, 


OJCO. 






GAF, 


ICC, 


NAC, 


TRC 


GAF, 


ICI, 


NAC. 




ACY. 








GAF. 








EK. 








DUP. 








ABB. 









SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i 966— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



3,3'-Thiobisr7H-benz[de]anthraoen-7-one] 

l,l'-Thlobis(2-naphthol) — 

»'i,'i'-Thiodianiline 

6,6'-Thiodimetanilic acid 

Thiopheneaoetic acid 

2-Thiopheneacetyl chloride 

2-Thiophenecarboxaldehyde 

eym-Thymol 

■»Toluene-2,<i -diamine (^-m-Tolylenedlamine) 

Toluene -2, 5-diaiiiine 

Toluene -2, 5 -diamine sulfate 

Toluene-2,'i-disulfonic acid 

o-Toluenesulfonamide 

p-Toluenesulfonamide 

«o(and p) -Toluenesulf onic acid 

p-Toluenesulfonic acid 

Toluenesulfonio acid, aniline salt 

p-Toluenesulfonic acid, 2-chloroethyl ester 

p-Toluenesulfonic acid, ethyl ester 

p-Toluenesulfonlc acid, methyl ester 

p-Toluenesulfonlc acid monohydrate 

p-Toluenesulf onyl chloride 

m-Toluic acid— 

o-Toluic acid 

p-Toluic acid 

m-Toluidine 

o-Toluidlne 

o-Toluidine hydrochloride 

p-Toluidlne 

p-Toluidine hydrochloride 

Toluidines, mixed 

m-Toluidinomethanesulfonic acid 

o-Toluidinomethanesulfonic acid 

8-p-Toluidino-l-naphthalenesulf onl c acid 

»o-(p-Toluoyl) benzoic acid 

N-(p-Tolylazo)sarcosine 

»4.(o-Tolylazo)-o-toluidine (C.I. Solvent Yellow 3) 

<i-(o-Tolylazo) -o-toluidine hydrochloride 

1-p-Tolyldodecane 

2,2'-(m-Tolylimino)diethanol 

p-Tolylmercuric chloride 

N,N,N-Tribenzylamine 

l,2,3(and 1,2,4) -Trichlorobenzene 

1,2,4-Trichlorobenzene 

N,2,6-Trichloro-p-benzoquinoneimine 

1, 2, A-Trichloro-S -nitrobenzene 

Trichlorophenylsilane 

a,a,ci-Trlchlorotoluene ( Benzotrichloride) 

01,2,'4-Trichlorotoluene 

o,2,'i(and a ,2,6)-Trichlorotoluene 

ajSj-l-Trichlorotoluene 

2,4,6-Trlchloro-s-triazine (Cyanurio chloride) 

1,3,5-Triethylbenzene 

2-( Trif luoromethyl) phenothiazine 

a,a,a-Trifluoro-A-nitro-m-creBol 

a,a,a-Trifluoro-m-nitrotoluene 

a,a,a-Trif luoro-N-phenyl-m-toluidlne (3-( Trif luoro- 
methyl) diphenylamine) . 

a,a,a-Trifluorotoluene 

a,a,a-TTifluoro-m-toluidine 

a, a,a-Trifluoro -o-toluidine 

l,2,A-Trihydro3cyanthraquinone 

3,<l,5-Trimethoxybenzoic acid 

2^,5-Trimethylaniline (Pseudocumidine) 

l,2,<i-Triinethylbenzene (Pseudocumene) 

2,3,3-Trlmethyl-3H-indole 

»l,3,3-Trijiiethyl-/!?,a-indolineacetaldehyde 

»l,3,3-Triiiiethyl-2-methyleneindoline (Trlmethyl base) 

Trlmethylphenylammonlum iodide 

a,a',2-Trljiiethyl-l,4--piperazinediethanol 



ACY, DUP, 


GAF, 


ICI. 


ACY. 






ACY, DUP, 


NAC. 




NAG. 






BPC. 






LIL. 






ABB. 






GIV. 






ACY, DUP, 


GAF, 


NAC, OIC, RUC, 


WAY. 






EK. 






GAF, SDH. 






MON. 






MON. 






MDN, HAC, 


NES, 


SW, UPF. 


ACY, TEN, 


UPF. 




NES. 






GAF. 






MAC. 






ICI. 






NES. 






MON. 






CWL. 






CWL. 






CWL. 






DUP, NAG. 






DUP, NAG. 






ACY. 






DUP, NAG. 






EK. 






DUP. 






VPC. 






TRC, VPC. 






NAC. 






ACY, DUP, 


NAC. 




BUC, GAF. 






ACY, BUC, 


DUP, 


GAF, NAC, SDH 


GAF. 






X. 






EKT. 






EK. 






ICO, ms. 






DVC, PPG. 






DOW, DVC, 


HK. 




EK. 






PCW. 






DCC, UCC. 






HK, VEL. 






HN. 






BPC. 






HN. 






ACY, GGY, 


NIL. 




DUP. 







OAF. 

ICO. 

NAC. 

PLC. 

OAF. 

DUP, GAF, VPC. 

DUP, OAF, NAC, VPC. 

EK. 

WYN. 



CYCLIC INTERMEDIATES 



TABLE IB.— Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i566— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



2,<»,6-Trimethylpyridlne 

1,3,5-Trluitrobenzene 

2,'i,7-Trinltrofluoren-9-one 

Triphenylmethanol 

Triphenylsulfonium chloride 

a, a', a' '-Tris(dlmethylamino)me6itol 

Tris(2-methyl-l-aziridinyl)phOEphlne oxide 

m-Ureidoaniline 

«7,7'-Ureylenebis[4-hydroxy-2-naphthalenesulfonlc acid] 
(J acid urea) . 

Veratraldehyde (aj-i-Dimethoxybenzaldehyde) 

Veratryl alcohol (3,'i-Dimethoxybenzyl alcohol) 

p-Vinylbenzenesulfonlc acid, sodium salt 

4-Vinylcyclohexene 

2,2 '-Vinylenebis [benzimidazole ] 

5-Vinyl-2-picoUne (MVP) 

2-Vinylpyridine 

A-Vinylpyridlne 

»Violanthrone (Dibenzanthrone) 

Xanthene-9-carboxylic acid 

Xanthic acid, A-ohloro-o-tolyl ester 

m-Xylene 

*o-)^lene 

»p-Xylene 

2,5-Xylenesulfonic acid — 

2,'i-)^lenol 

2,6-)^lenol - 

}5ylenol crystals 

Xylenols : 

Low b.p 

Medium b.p 

Not classified as to b.p 

Xylidines; 

2,'i-Xylidine (m-^-Xylidine) 

2,5-Xylidine (p-Xylidine) 

2,6-Xylldine 

Original mixture 

'i-(2,';-Xylylazo)-o-toluidine 

4-(2,5-)^lylazo)-o-toluidine 

't-(Xylylazo)xylldine, mixed 

<i-(2,4-Xylylazo)-2,5-xylidine 

All other cyclic intermediates 



EK. 

GAM. 

RH, TKL. 

ICO. 

ICI. 

ACY, ATL, BKS, BL, CMG, GAF, NAC, TRC, VPC. 

GIV, LIL, SLV. 

LIL. 

DUP. 

PLC. 

TRC. 

PLC. 

NEP, RIL. 

RIL. 

ACY, ATL, DUP, GAF, ICI, MAY, SDC, TRC. 

MAL. 

GAF. 

SNT, SOC. 

ASH, CCP, COR, CSD, CSO, DLH, SIN, SNT, SOC, TOC. 

CSD, ENJ, HCR, SIN, SNT, SOC, SOG. 



NPC, 


PIT. 




KPT, 


NPC, 


PIT 


KPT, 


NPC, 


PRD 


DUP, 


NAC. 




DUP. 






Dim. 






DUP, 


NAC. 




NAC. 






ACY. 






GAF. 







FG, GAF, GAM, ICC, ICO, LIL, MON, 



■■■ See table 13B for data on medicinal grade of this item. 

^ Does not include maniif acturers ' identification codes for producers that report to the Division of Bituminous 
Coal, U.S. Bureau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey 

Coke Producers in the United States in 1966. Aug. 29, 1967. 



92 



SYNTHETIC ORGANIC CHEMICALS. 1966 



Dyes 

TABLE 8B. — Bemenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1966 



[Dyes for which separate statistics are given in table 8A are marked below with an asterisk (»); dyes not so marked 
do not appear in table 8A because the reported data are accepted in confidence and may not be published. Manu- 
facturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not 
consent to his identification with the designated product ] 



Pye 



Manufacturers' identification codes 
(according to list in table 22) 



ACID DYES 

»Acid yellow dyes: 

Acid Yellow 1 - - 

Acid Yellow 2 

»Acid Yellow 3— 

Acid Yellow A— 

Acid Yellow 7 

Acid Yellow 9 — 

»Acid Yellow 11 - 

Acid Yellow K 

»Acld Yellow 17 - 

"Acid Yellow 23 

Acid Yellow 25 - - 

Acid Yellow 29- 

Acid Yellow 3-;— — 

Acid Yellow 35— 

»Acid Yellow 36— 

Acid Yellow 38 

»Acid Yellow 40- - 

»Acid Yellow A2 - 

«Acid Yellow 44 - 

Acid Yellow 49— 

»Acid Yellow 54 - 

Acid Yellow 59 

Acid Yellow 60 

Acid Yellow 63 

Acid Yellow 65— 

»Acid Yellow 73 

Acid Yellow 76 

Acid Yellow 79— - 

Acid Yellow 90 

Acid Yellow 95 

»Acld Yellow 99 

Acid Yellow 114 

Acid Yellow 121 

*Aoid Yellow 124— 

Acid Yellow 127— - 

Acid Yellow 128- 

Acid Yellow 129 

»Acld Yellow 151 - 

Acid Yellow 152— - 

Acid Yellow 159— 

Other acid yellow dyes 

»Acid orange dyes: 

»Acid Orange 1 

Acid Orange 2 

Acid Orange 5 

Acid Orange 6 

«Aold Orange 7 

«Acid Orange 8 

«Aoid Orange 10 

Acid Orange 12 

Acid Orange 19 

»Acid Orange 24 

Acid Orange 28 

Acid Orange 31 

Acid Orange 34 

Acid Orange 45 

Acid Orange 50 

Acid Orange 51 

Acid Orange 52 

Acid Orange 56 



ACY. 
















DUP. 
















ACY, 


DUP, 


GAF. 


NAC. 










SDH. 
















NAC. 
















ACY. 
















CMG, 


DUP, 


VPC. 












BDO. 


TMC. 














ACY, 


ATL, 


BDO. 


BKS, 


CMG, 


DUP, 


GAF, 


NAC, PDC, SDH, TRC, 


VPC. 














AAP, 


ACY, 


GAF, 


MRX, 


NAC, 


SDH, 


TRC, 


VPC. 


GAF. 
















GAF, 


TRC. 














NAC. 
















VPC. 
















DUP, 


GAF, 


NAC, 


TRC. 










NAC. 
















DUP, 


GAF, 


NAC, 


TRC, 


VPC. 








AAP, 


ACY, 


GAF, 


VPC. 










AAP, 


GAF, 


NAC, 


VPC. 










VPC. 
















ACY, 


BKS, 


CMG, 


GAF. 


NAC, 


TRC, 


VPC. 




VPC. 
















NAC. 
















AAP, 


NAC. 














TRC. 
















GAF, 


NAC, 


NYC, 


SDH. 










TRC. 
















VPC. 
















NAC. 
















CMG. 
















CMG, 


GAF, 


NAC, 


TRC, 


VPC. 








CMG, 


TRC. 














GAF. 
















BKS, 


DUP, 


NAC. 












TRC. 
















TRC. 
















TRC. 
















ACY, 


BKS, 


TRC, 


VPC. 










ACY. 
















TRC. 
















ACY, 


ALT, 


CMG, 


DUP, 


GAF, 


TRC, 


VPC. 




ALT, 


BKS, 


GAF, 


NAC. 










NAC, 


TRC. 














ACY. 
















NAC. 
















AAP, 


ACY, 


ATL, 


BKS, 


CPC, 


GAF, 


NAC, 


PDC, TRC, YAW. 


ACY, 


ATL, 


BKS, 


DUP, 


GAF, 


NAC, 


TRC. 




ACY, 


BKS, 


DUP, 


GAF, 


NAC, 


TRC, 


VPC, 


YAW. 


NAC. 
















GAF. 
















ACY, 


DUP, 


GAF, 


NAC, 


TRC, 


YAW. 






NAC. 
















AAP. 
















ACY. 
















NAC, 


TRC. 














AAP. 
















cue. 


NAC, 


TRC. 












NAC. 
















OAF. 

















93 



TABLE 8B. — Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 566— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



ACID DYES— Continued 



».Acld orange dyes — Continued 

»Acid Orange 60 

Acid Orange 62 

Acid Orange 63 

»Acid Orange 64 

Acid Orange 69 

Acid Orange 72- 

Acid Orange 74 

Acid Orange 76 

Acid Orange 85 

Acid Orange 36 

Acid Orange 114 

Acid Orange 116 

Acid Orange 119 

Other acid orange dyes 

»Acid red dyes: 

♦Acid Red 1 

»Acid Red 4 — 

»Acid Red 14- — 

Acid Red 17 

»Acid Red 18 

»Aoid Red 26 

Acid Red 27 

Acid Red 32 

Acid Red 33 

Acid Red 34 

Acid Red 35 - — 

»Acid Red 37 - 

Acid Red 42 — 

Acid Red 52 

Acid Red 57 

Acid Red 66- 

«Acld Red 73 

Acid Red 76 — 

Acid Red 80 

♦Acid Red 85 

»Acid Red 87 
*Aold Red 88 
»Acid Red 89 

Acid Red 94 

Acid Red 97 

Acid Red 99 

Acid Red lOi 

Acid Red 10 

Acid Red 11 
»Acid Red 11 

Acid Red 11 

Acid Red 11 

Acid Red 13 

Acid Red 13. 
»Acid Red 13 
»Acid Red 15 

Acid Red 167- 

Acid Red 175- 

Acid Red 178- 

Acid Red 179- 
»Acid Red 182- 

Acid Red 183- 
»Aoid Red 186- 

Acid Red 190- 

Acid Red 191. 

Acid Red 194. 

Acid Red 201. 

Acid Red 207. 

Acid Red 212. 

Acid Red 213. 

Acid Red 273. 

Aoid Red 292 



Acid 
*Acld 

»Acid 


Red 
Red 

Red 


80 - - - 


















Acid 


Red 














i06 


Acid Red 




rr 


Acid 
Acid 
Acid 


Red 
Red 
Red 










»Acid Red 
«Acid Red 







GAF, TRC. 

ACY, DUP, NAC. 

ACY. 

GAF. 

CMG, GAF, NAC, TRC. 

NAC, TRC. 

NAC. 

NAC, TRC. 

ACY. 

ATL, BKS, GAF, TRC. 

TRC. 

ALT, DUP, VPC. 

AAP, ACY, BDO, BKS, BL, DUP, GAF, NAC, SDH, TRC, VPC, 

YAW. 
ATL, BDO, CWG, DUP, GAF, TRC, VPC, YAW. 
DUP, GAF, NAC, PDC. 
NAC, TRC, YAW. 
ACY, DUP, GAF, NAC, TRC. 
ACY, ATL, CPC, GAF, NAC. 
NAC. 

OAF, NAC. 
NAC, YAW. 
NAC. 

AAP, GAF. 

BKS, CMG, DUP, GAF, NAC, TRC. 
GAF. 
GAF. 
TRC. 
AAP. 

ACY, DUP, GAF, NAC, PSC, TRC. 
NAC. 

GAF, ICI. 
ACY, ALT, ATL, BKS, CMG, DUP, GAF, NAC, PDC, TRC, 

VPC, YAW. 
AMS, NYC, SDH. 

ACY, ATL, DUP, GAF, NAC, SDH, TRC, YAW. 
AAP, GAF, TRC, VPC. 
NYC. 
GAF. 

BKS, CMG, TRC, VPC, YAW. 
VPC. 
YAW. 
DUP. 

ATL, DUP, GAF, NAC. 
GAF, NAC. 
NAC. 
GAF. 
TRC. 

ATL, DUP, GAF, NAC, TRC. 
AAP, ACY, BKS, TRC, YAW. 
NAC, TRC. 
DUP. 
DUP. 

CMG, TRC. 

ACY, BKS, CMG, DUP, GAF, NAC. 
CWG, TRC. 

BKS, CMG, GAF, TRC, VPC. 
ACY. 
TRC. 
TRC. 
TRC. 
NAC. 
TRC. 
TRC. 
OAF. 
ACY. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 8B. --Beruenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 2 S66— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



ACID DYES— Continued 

»Acld red dyes— Continued 

Acid Red 299 

Acid Red 309 — 

Other acid red dyes 

»Acid violet dyes: 

»Acid Violet 1 

»Acid Violet 3 — 

Acid Violet 6 - - 

»Acld Violet 7 

Acid Violet 9 - 

Acid Violet 11 - 

»Acld Violet 12 

Acid Violet 13 

Acid Violet 17 

Acid Violet 29 

Acid Violet 34 

Acid Violet 41 

Acid Violet 43 --- 

»Acid Violet 49 - 

Acid Violet 56- — 

Acid Violet 58 - 

Acid Violet 76 

Other acid violet dyes 

•»Aoid blue dyes : 

Acid Blue 1 

»Acid Blue 7— 

»Acid Blue 9- ■ 

Acid Blue 10 • 

Acid Blue 15 

Acid Blue 20— 

Acid Blue 22 ■ 

Acid Blue 23 

»Acid Blue 25— 

Acid Blue 26- 

Acid Blue 27 ■ 

Acid Blue 29 

Acid Blue 34— 

»Acid Blue 40 - 

»Acid Blue 41 

»Acid Blue 43 - 

»Aoid Blue 45— - 

Acid Blue 47 

Acid Blue 48 - 

Acid Blue 55 

Acid Blue 58 

Acid Blue 59 

»Acid Blue 62 - - 

Acid Blue 63 

Acid Blue 67 - 

Acid Blue 69 

Acid Blue 74 

»Acid Blue 78- 

Acid Blue 80 — 

Acid Blue 81— 

Acid Blue 83 — 

Acid Blue 89 

»Acid Blue 90— — 

Aoid Blue 92 

Acid Blue 93— — 

Acid Blue 102- 

Acid Blue 104- 

»Aoid Blue 113 — 

Acid Blue 118- — 

Acid Blue 120 

Acid Blue 122 

Acid Blue 145 — 

»Aold Blue 158 and 158A 

Acid Blue 165— 

Acid Blue 179 

Acid Blue 198 



NAC. 
AAP, 
GAF. 
GAF. 
EDO, 
DUP. 
GAF, 
HSH. 
ICl. 
CMG. 
HSH, 
ACY, 
CMG, 
GAF. 
NAC. 
ALT, 

GAF, 
ACY, 
GAF, 
NAC. 
GAF. 
NAC. 
ACY, 
NAC, 
ATL, 
NAC. 
CMG, 
PDC. 
NAC. 
ATL, 
BDO, 
ACY, 
ACY, 
ICI. 
HSC. 
NAC. 
DUP. 
NAC. 



TRC. 

ATL, DUP, GAF, VPC. 



BDO, CMG, DUP, GAF, NAC, TRC, VPC. 
CMG, DUP, GAF. 



ICI, NAC. 
NAC, TRC. 
GAF. 



NAC, SDH. 
GAF, NAC, SDH. 
NAC, SDH, VPC. 



NYC. 
TRC. 
BDO, CMG, DUP, GAF, NAC, TRC. 



GAF, ICI, NAC, TRC. 

CMG, GAF, NAC. 

GAF, NAC, TRC. 

cue, DUP, GAF, NAC, TRC, VPC. 



BDO, GAF, NAC, VPC. 



CMG, 


NAC. 










CMG. 
DUP, 
DUP. 


GAF. 
NAO. 










DUP, 


GAF, 


ICI, 


NAC, 


TRC. 




NAC, 


TRC. 










ICI. 












GAP. 












NAC. 












GAF, 


NAC, 


TRC. 








NAC, 


YAW. 










HSC. 












NAC, 


TRC. 










GAF, 


NAC. 










ATL. 


BDO, 


BKS. 


CMG. 


DUP, 


GAF, NAC 


BKS, 


GAF, 


NAC. 








GAF, 


NAC. 










DUP. 












DUP. 


NAC. 










ACY, 


BKS, 


GAF, 


NAC, 


TRC, 


VPC. 


DUP. 












GAF. 












VPC. 













TABLE 8B. — Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 1966 — Continued 



Manufacturers' identification code 
(according to list in table 22) 



ACID DYES— Continued 

»Acid blue dyes --Continued 

Acid Blue 203 

Acid Blue 230 — - 

Acid Blue 231 

Other acid blue dyes 

»Acid green dyes: 

Acid Green 1 

»Acid Green 3 

Acid Green 5 

»Aoid Green 9 

»Acid Green 12 

»Acid Green 16 

»Acid Green 20 

Acid Green 22 

»Acid Green 25 

Acid Green 35 - - ■ 

Acid Green 41 

Acid Green 44 

Acid Green 50 - -- • 

Acid Green 58 

Acid Green 70 -■ 

Other acid green dyes 

»Acid brown dyes: 

Acid Brown 1 

Acid Brown 6 

»Acid Brown U 

Acid Brown 19 

Acid Brown 22 

Acid Brown 28 

Acid Brown 29 

Acid Brown 31 

Acid Brown 45 

Acid Brown 96 

Acid Brown 97 

Acid Brown 98 

Acid Brown 152 

Acid Brown 158 

Acid Brown 223— - 

Acid Brown 243 

Other acid brown dyes 

»Acid black dyes: 

»Acid Black 1 

Acid Black 2 

Acid Black 12 

Acid Black 16 

Acid Black 18 

»Acid Black 24 

Acid Black 26, 26A, and 26B 

Acid Black 29- 

Acid Black 41 - 

»Acld Black 48 - 

Acid Black 52 — 

Acid Black 53 

Acid Black 58— 

Acid Black 60- 

Acid Black 92 - 

»Acid Black 107- 

Acid Black 108 

Acid Black 138— 

Other acid black dyes 

AZOIC DYES AND CCMPONENTS 

Azoic yellow dyes : 

"Azoic Yellow 1— 

Azoic Yellow 2 

Azoic Yellow 3— - - 



VPC. 

DUP, TRC. 

TRC. 

ACY, ALT, CMG, DUP, TRC, VPC. 



GAF, NAC. 

NAC, TRC. 

GAF, NAC, SDH, TRC. 

CMG, DUP, GAF, NAC, PDC, TRC. 

NAC. 

GAF, HSH, ICI, NAC, TRC, VPC. 

VPC. 

GAF. 



GAF. 

GAF. 

AAP, ACY, DUP, GAF, NAC, TRC, YAW. 

TRC. 

DUP. 

TRC. 

DUP. 

GAF. 

TRC. 

ACY. 

ACY. 

ACY, TRC. 

GAF. 

GAF. 

GAF. 

GAF. 

ALT, DUP, GAF. 



AAP, ACY, AIL, 

TRC, YAW. 
ACY, NAC. 
NAC. 
NAC. 
NAC. 

CMG, DUP, GAF, NAC. 
DUP, NAC, TRC. 
GAF, NAC, YAW. 
NAC. 

ACY, CMG, DUP, GAF, ICI, NAC, TRC. 
BKS, GAF, NAC, TRC. 
NAC. 

NAC, TRC. 
CMG, TRC. 
ACY. 

GAF, NAC, TRC. 
GAF. 
VPC. 
ALT, DUP, PDC. 



BKS, DUP, FAB, GAF, HSH, NAC, PDC, 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 8B. --Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 566— Continued 



Manufacturers' identification code 
(according to list in table 22) 



AZOIC DYES AND CQMP0N5MTS— Continued 






-Continued 



Azoic orange dyes: 

»Azolc Orange 3 

Azoic Orange 4 

Other azoic orange dyes 

»Azoic red dyes: 

»Azolc Red 1 

Azoic Red 2 

»Azoio Red 6 

Azoic Red 13 

Azoic Red 15 

Azoic Red 16 

Azoic Red 73 — - 

Azoic Red 7i, 

Other azoic red dyes 

»Azoic violet dyes: Azoic Violet 1— 
Azoic blue dyes : 

»Azolo Blue 2 

«Azolc Blue 3 

Azoic Blue 4 

Azoic Blue 6 

Azoic Blue 7 

Other azoic blue dyes 

Azoic green dyes: 

Azoic Green 1 

Other azoic green dyes 

Azoic brown dyes: 

»Azoic Brown 9 

Azoic Brown 10 

Azoic Brown 26 

Other azoic brown dyes 

»Azoic black dyes : 

Azoic Black 1 

Azoic Black 4 

Azoic Black 15 

Other azoic black dyes 

Other azoic compositions 

Azoic Diazo Componeni 
(Fast Color Bas 

Azoic Diazo Component 2, base 

Azoic Diazo Conqjonent 3, base 

»Azoic Diazo Con?)onent A, base 

Azoic Diazo Conponent 5, base 

Azoic Diazo Component 8, base 

»Azolc Diazo Component 9, base 

»Azoic Diazo Component 10, base 

»Azoic Diazo Component 12, baee 

»Azoic Diazo Coii?)onent 13, base 

Azoic Diazo Con^ionent li, base 

Azoic Diazo Component 20, base 

Azoic Diazo Coii5)onent 27, base 

Azoic Diazo Component 28, base 

»Azoic Diazo Component 32, base 

Azoic Diazo Component 34, base 

Azoic Diazo Component 41, base 

Azoic Diazo Conqjonent 42, base 

Azoic Diazo Con^jonent 44, base 

»Azoio Diazo Component 48, base 

Other azoic diazo components, bases- 

(Fast Color Sal 

»Azoio Diazo Coiyonent 1, salt 

»Azoic Diazo Component 2, salt 

»Azoic Diazo Con^ionent 3, salt 

Azoic Diazo Component 4, salt 



ALL, 


ATL, 


BUC, 


GAF, 


X. 


r,AF. 










VPC. 










ALL, 


ATL, 


BUC, 


GAF, 


HST, X. 


ATT,, 


HUC, 


GAF, 


X. 




AI,T., 


ATL, 


BUC, 


GAF, 


HST, VPC, X 


GAF. 










GAF. 










ATL, 


GAF. 








GAF. 










GAF. 










VPC. 










ALL, 


ATL, 


BUG, 


GAF, 


X. 


ATT,, 


RIIO, 


GAF. 






ALL, 


ATL, 


BUC, 


GAF, 


HST, X. 


GAF. 










ATL, 


GAF. 








GAF. 










ALL. 










ATL, 


GAF. 








VPC. 










BUC, 


GAF, 


HST, 


VPC, 


X. 


GAF. 










GAF. 










ATL, 


GAF, 


VPC. 






HST. 










ATL, 


BUC, 


GAF. 






GAF. 










ALL, 


ATL, 


GAF, 


VPC. 





ATL, 


BUC. 








BUC. 










ALL, 


BUC, 


GAF, 


SDH. 




GAF, 


SDH. 








DUP, 


SDH. 








AAP, 


DUP, 


VPC. 






ALL, 


AUG, 


BUC, 


GAF. 




ATTG, 


BUC, 


SDH. 






ALL, 


ATL, 


AUG, 


BUC, 


VPC. 


AAP. 










ALL, 


GAF. 








BUC. 










ALL, 


BUC, 


VPC. 






AAP, 


ALL, 


ATL, 


BUC, 


DUP, SDH 


GAF. 










ALL, 


GAF. 








AT,T,. 










AAP, 


BUC. 








ALL, 


CWN, 


DUP, 


GAF. 




GAF. 











AAP, ALL, GAF, SDH. 

ALL, AUG, BUC, GAF. 

AAP, ALL, AUG, BUC, GAF, NAC, SDH. 

ALL, AUG, DUP. 



TABLE 8B. --Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 566— Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



»A2oic Dlazo 
»Azoic Dlazo 
»Azoio Diazo 
Azoic Diazo 
»Azoic Diazo 
»Azoic Diazo 
Azoic Diazo 
Azoic Diazo 
»Azoic Dlazo 
Azoic Diazo 
Azoic Diazo 
Azoic Diazo 
»Azolc Diazo 
Azoic Diazo 
Azoic Diazo 
Azoic Diazo 
Azoic Diazo 
»Azoio Diazo 
»Azoio Diazo 
»Azoic Diazo 
Azoic Diazo 



AZOIC DYES AND CCMPONSMTS— Continued 

Azoic Diazo Components, Salts 
(Fast Color Salts) --Continued 

Coin>onent 5, salt 

Component 6, salt 

Component 8, salt 

Component 9, salt 

Coiqjonent 10, salt 

Con5)onent 11, salt 

Component 12, salt 

Component 13, salt 

Component 14, salt 

Component 20, salt 

Component 28, salt 

Component 32, salt 

Component 34, salt 

Component 35, salt 

Component 35, salt 

Component 37, salt 

Component 40, salt 

Component 41, salt 

Conponent 42, salt 

Component 44, salt 

Coii?)onent 48, salt 

Component 49, salt 

Component 121, salt 



AAP, 
AAP, 
AAP, 
AAP, 
AAP, 
AAP, 
AAP, 
AAP, 
AAP. 
ALL, 
ALL, 
ALL, 
GAF. 
GAF. 
AAP, 
ALL, 
BUG. 
BUG, 
ALL, 
ALL, 
AAP, 
AAP, 
GAF. 



ALL, AUG, BUG, GAF, SDH. 

BUG, GAF, SDH. 

ALL, AUG, sue, GAF. 

ALL, AUG, BUG, GAF, SDH, VPC. 

ALL, AUG, BUG, GAF, SDH. 

ALL, GAF. 

ALL, AUG, BUG, GAF, SDH. 

ALL, AUG, BUG, GAF, NAC, SDH, VPC. 

GAF. 

AUG, BUG, GAF, NAC, SDH, VPC. 

SDH. 



GAF. 

GAF. 

BUG, GAF, SDH. 

GAF, SDH. 

ALL, BUG, GAF, SDH. 



Azoic Coupling Compc 
(Naphthol AS and Deni 

»Azoic Coupling Component 2 

»Azoic Coupling Component 3 

»Azoic Coupling Coiqjonent 4 

»Azoic Coupling Component 5 

»Azoic Coupling Con^ionent 7 

Azoic Coupling Component 8 

Azoic Coupling Goii5>onent 10 

»Azoic Coupling Goinjonent 11 

Azoic Coupling Component 12 

Azoic Coupling Component 13 

»Azoic Coupling Component 14 

Azoic Coupling Con^ronent 15 

Azoic Coupling Component 16 

»Azoic Coupling Component 17 

»Azoic Coupling Coiqjonent 18 

»Azoic Coupling Conponent 19 

«Azolc Coupling Component 20 

*Azoic Coupling Component 21 

Azoic Coupling Component 23 

»Azolc Coupling Component 24 

•Azoic Coupling Component 29 

Azoic Coupling Component 34 

Azoic Coupling Component 35 

Azoic Coupling Con^jonent 36 

»Azoic Coupling Component 43 

Other azoic coupling con5>onents 

BASIC DYES 

♦Basic yellow dyes: 

Basic Yellow 1 — 

•Basic Yellow 2 

Basic Yellow 5 

•Basic Yellow 11- 

•Basic Yellow 13- - 

Basic Yellow 15 

Basic Yellow 16— - — 

Basic Yellow 26 

Basic Yellow 27 

Basic Yellow 28 — 



ACY, 


ATL, 


AUG, 


BUG, 


GAF, NAC, PCW 


AUG, 


BUG, 


GAF, 


PCW. 




AUG. 


BUG, 


GAF. 






AAP. 


GAF, 


SDH. 






AAP. 


AUG, 


BUG, 


GAF, 


PCW. 


BUG, 


GAF, 


PGW. 






PGW. 










BUG, 


GAF, 


PGW. 






BUG, 


GAF, 


PCW. 






GAF, 


PCW. 








ATL, 


BUG, 


GAF. 


NAG, 


PCW. 


BUG. 


GAF. 








GAF. 










ACY, 


ATL, 


BUG. 


PGW. 




ACY, 


ATL, 


BUG. 


GAF, 


NAC, PCW. 


BUG, 


GAF, 


PCW. 






AIL, 


BUG, 


DUP, 


GAF, 


PCW. 


ATL, 


AUG, 


BUG, 


GAF, 


PCW. 


GAF, 


PCW. 








BUG, 


GAF, 


PCW. 






ATL, 


AUG, 


BUG, 


GAF, 


PCW. 


BUG, 


GAF, 


PCW. 






GAF, 


PCW. 








OAF. 










ATL, 


BUG, 


GAF. 






ATL, 


GAF, 


VPC. 







DUP. 

ACY, DUP, NAC. 

NAC. 

DUP, GAF, NAG, VPC. 

DUP, GAF, NAG, VPC. 

DUP. 

DUP. 

ACY. 

ACY. 

vpn. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



-Bemenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 566— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



BASIC DYES— Continued 

»Basic yellow dyes --Continued 

Basic Yellow 37 

Other basic yellow dyes 

♦Basic orange dyes: 

»Basic Orange 1 

*Baslc Orange 2 

Basic Orange lA 

Basic Orange 17 

»Basic Orange 21 

Basic Orange 22 

Basic Orange 24 

Basic Orange 25 

Basic Orange 26 

Basic Orange 27 

Basic Orange 31 

»Basic red dyes: 

Basic Red 1 

Basic Red 2 

Basic Red 9 — 

Basic Red 12 

Basic Red 13 

»Basic Red lA 

Basic Red 15 

Basic Red 16 

Basic Red 17 

Basic Red 18— 

Basic Red 19 - 

Basic Red 20 — — 

Basic Red 22 

Basic Red 30 - 

Other basic red dyes 

»Basic violet dyes: 

*Basic Violet 1 

Basic Violet 2 - 

Basic Violet 3- 

*Basic Violet A 

Basic Violet 7 - 

Basic Violet 10 

Basic Violet 13 - 

Basic Violet 14 

Basic Violet 15 - — 

*Basic Violet 16 

Basic Violet 18 

Other basic violet dyes 

■»Basio blue dyes: 

♦Basic Blue 1 

Basic Blue 2 

Basic Blue 3 

Basic Blue 4 

♦Basic Blue 5 

Basic Blue 6 

♦Basic Blue 7 

♦Basic Blue 9 

Basic Blue 11 - 

Basic Blue 21— — 

Basic Blue 22 

♦Basic Blue 26 

Basic Blue 27 

Basic Blue 35 

Basic Blue 38 

Basic Blue 39 

Basic Blue 41 

Basic Blue 47 

Basic Blue 54— - 

Other basic blue dyes 

Basic green dyes: 

♦Basic Green 1 

Basic Qreen 3 

•Basic Green 4 



ACY. 










DUP, GAF. 










ACY, DUP, 


GAF, 


NAC, 


TRC. 




ACY, DSC, 


DUP, 


GAF, 


NAC, PDC, 


PSC, TRC, 


GAF. 










NAC. 










DUP, GAF, 


NAC, 


VPC. 






GAF, NAC. 










DUP. 










DUP. 










DUP. 










VPC. 










ACY. 










DUP, GAF. 










DUP, NAC. 










ACY, DSC, 


HSC. 








DUP. 










GAF, NAC. 










ACY, DUP, 


GAF, 


NAC, 


VPC. 




DUP, GAF. 










DUP. 










DUP. 










DUP, VPC. 










DUP. 










DUP. 










ACY, TRC. 










ACY. 










DUP, GAF, 


VPC. 








ACY, DSC, 


GAF, 


HSC, 


NAC. 




DSC, NYC. 










DSC, DUP, 


NAC, 


SDH. 






DSC, DUP, 


GAF, 


NAC. 






GAF, NAC. 










ACY, DUP, 


GAF. 








DSC. 










ACY, DSC. 










DUP. 










DUP, GAF, 


VPC. 








ACY. 










DUP. 










DSC, GAF, 


NAC, 


SDH, 


VPC. 




DSC. 










GAF. 










DUP. 










DSC, SDH, 


VPC. 








ACY, NAC. 










DSC, DUP, 


NAC, 


SDH. 






ACY, GAF, 


NAC, 


SDH. 






DSC, SDH. 










DUP. 










DUP, NAC. 










DSC, DUP, 


NAC, 


SDH. 






GAF. 










DUP. 










ACY, DUP. 










DUP. 










TRC. 










VPC. 










ACY. 










ACY, DUP, 


GAF. 








ACY, DSC, 


DUP, 


NAC, 


SDH. 




DUP. 










ACY, DSC, 


DUP, 


NAC, 


SDH. 





99 



■ Bemenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i566— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



BASIC DYES— Continue 

Basic brown dyes: 

»Basic Brown 1 

Basic Brown 2 

»Basic Brown <♦ 

Basic black dyes : 

Basic Black 3 

Other basic black dyes 

DIRECT DYES 



ACY, DUP, GAF, NAC, TRC. 

GAF. 

ACY, DSC, DUP, GAF, NAC, TRC. 



•Direct yellow dyes : 

♦Direct Yellow <i 

•Direct Yellow 5 

•Direct Yellow 6 

Direct Yellow 7 

Direct Yellow 8 - 

Direct Yellow 9 

•Direct Yellow 11 

•Direct Yellow 12 

Direct Yellow 20 — - 

Direct Yellow 23 

•Direct Yellow 26 

Direct Yellow 27 

•Direct Yellow 28 

•Direct Yellow 29 

Direct Yellow 39 

•Direct Yellow 44 

•Direct Yellow 50 

Direct Yellow 59 

Direct Yellow 63 

•Direct Yellow 84— 

Direct Yellow 103 

•Direct Yellow 105 

•Direct Yellow 106 

Direct Yellow 107 

Direct Yellow 114 

Direct Yellow 117 

Direct Yellow 118 — - 

Direct Yellow 120 

Direct Yellow 121 

Direct Yellow 125— 

Other direct yellow dyes- 
•Direet orange dyes; 

•Direct Orange 1 

Direct Orange 6 

•Direct Orange 8 

Direct Orange 10 

Direct Orange 11 

•Direct Orange 15 

•Direct Orange 26 

•Direct Orange 29 

•Direct Orange 34 

•Direct Orange 37 

•Direct Orange 39 

Direct Grange 40 

Direct Orange 48 

Direct Orange 55 

Direct Orange 59 

Direct Orange 61 

Direct Orange 67 

Direct Orange 70 

•Direct Orange 72 

•Direct Orange 73 

Direct Orange 74 

Direct Orange 76 

Direct Orange 78 

Direct Orange 79 

Direct Orange 80 

•Direct Orange 81 

Direct Orange 83 



DUP, GAF, NAC, TRC. 

GAF, NAC. 

ATL, DUP, GAF, NAC, TRC. 



BKS, DUP, GAF, NAC, TRC. 
DUP, FAB, GAF, NAC, TRC. 



BKS, BL, DUP. 



ATL, BKS, BL, DUP, FAB, GAF, NAC, TRC, VPC. 
BKS, BL, DUP, FAB, GAF, NAC, TRC, VPC. 
DUP, NAC. 



GAF, NAC, TRC. 



BKS, GAF, TRC. 
BKS, FAB, GAF, TRC. 



ACY, 
ACY, 
ACY, 
ATL. 
GAF, 
DUP. 
ACY, 
BKS, 
TRC. 
DUP. 
ALT, 
GAF. 
ATL, 
ATL, 
TRC. 
ALT, 
ATL, 
ATL, 
DUP. 
BKS, 
NAC. 
ALT, 
ALT, 
GAF. 
ACY. 
TRC. 
TRC. 
BKS. 
TRC. 
ACY. 
AAP, ALT, ATL, BL, DUP, TRC, VPC. 

AAP, ATL, BDO, CWG, NAC, VPC. 

NAC. 

ATL, 

AAP, 

GAF. 

ACY, 

ATL, 

ATL, 

ACY, 

ACY, 

BKS, 

DUP. 

DUP. 

DUP, 

DUP, 

TRC. 

NAC, 

TRC. 

ATL, 

DUP, 

BL, 

DUP. 

DUP, 

DUP. 

DUP, 

DUP, 

GAF, 



DUP, GAF, NAC, TRC. 

DUP, GAF, NAC, TRC. 

BKS, FAB, TRC. 

ATL, CMG, DUP, GAF, NAC. 

CMG, DUP, GAF, TRC. 

CMG, DUP, GAF. 



BKS, FAB, NAC, TRC, VPC. 
GAF, TRC, VPC. 
DUP. 



VPC. 

GAF, NAC, VPC. 

NAC. 



100 



SYNTHETIC ORGANIC CHEMICALS, 1966 



■ Bemenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 966— Continued 



Manufacturers' Identifioatlon codes 
(according to list in table 22) 



DIRECT DYES — Continued 

•Direct orange dyes—Continued 

Direct Orange 88— 

»Dlrect Orange 102 

Direct Orange 110 

Other direct orange dyes 

•Direct red dyes : 

•Direct Had 1 - - 

•Direct Red 2 

•Direct Red U— 

Direct Red 5 

Direct Red 7 - 

•Direct Red 10 

•Direct Red 13— 

•Direct Red 16- 

Direct Red 20 

•Direct Red 23 - 

•Direct Red 2* 

•Direct Red 26 — 

•Direct Red 28— 

•Direct Red 31 

Direct Red 32 

•Direct Red 37— — 

•Direct Red 39— - — 

Direct Red 40 

Direct Red 53- — - 

Direct Red 62 

•Direct Red 72 

Direct Red 73 

•Direct Red 75 — 

Direct Red 76 

•Direct Red 79 

•Direct Red 80 - — — 

•Direct Red 81 

•Direct Red 83 - 

•Direct Red 8-1— — 

Direct Red 94 

Direct Red 95 

Direct Red 100 

Direct Red 111 

Qlrect Red 117 

Direct Red 120 • 

•Direct Red 122 

Direct Red 123— 

Direct Red 139 

t«irect Red U9 - 

Direct Red 152 

««a.rect Rod 153— 

Direct Red 155— - — 

Direct Red 209 

Other direct red dyes 

fflJlrect violet dyes: 

•Direct Violet 1 

Direct Violet 7 

•Direct Violet 9 — 

Direct Violet U 

Direct Violet 22 

Direct Violet 30- ~ 

Direct Violet 47 — 

Direct Violet 48 

Direct Violet 49 

Direct Violet 51 

Direct Violet 62 

Direct Violet 66 

Direct Violet 67 

Direct Violet 68 

Other direct rlolet dyes 

•Direct blue dyes: 

•Dlr»ot Blue 1 



DUP. 

ACT, DUP, GAF, NAC. 

TRC. 

ALT, ATL, BL, DUP, VPC. 

AAP, ATL, DUP, GAF, NAC, TRC, YAW. 

ATL, BKS, DUP, NAC, TRC. 

ATL, NAC, TRC, VPC. 

NAC. 

ATL, YAW. 

AAP, ACT, NAC. 

AAP, ATL, DUP, NAC, TRC, YAW. 

ATL, GAF, NAC, TRC. 

GAF, NAC. 

ATL, BKS, CMC, DUP, FAB, GAF, NAC, TRC. 

AAP, ATL, BKS, BL, FAB, TRC, VPC. 

AAP, ATL, DUP, FAB, GAF, NAC, TRC, VPC. 

ATL, BKS, DUP, NAC, TRC. 

ATL, DUP, GAF, NAC. 

DUP, NAC. 

ATL, GAF, NAC, TRC, YAW. 

ATL, GAF, NAC, TRC, YAW. 

VPC. 

NAC. 

TRC. 

GAF, NAC, TRC. 

DUP, NAC. 

ACT, CMG, DUP, GAF. 

GAF, NAC. 

ATL, BKS, CMG, TRC, VPC. 

AAP, ATL, BDO, BKS, BL, CMG, 

VPC. 

AAP, ACT, ALT, ATL, BKS, BL, CMG, DUP, GAF, NAC, TRC, 

VPC, YAW. 



FAB, NAC, SDH, TRC, 



ALT, ATL, 


BKS, 


BL, 


CMG, 


DUP, 


BKS, GAF, 


NAC. 








NAC. 










VPC. 










NAC. 










GAF. 










BL, DUP. 










VPC. 










aiG, TRC, 


VPC. 








GAF. 










VPC. 










ATL, CMG, 


DUP, 


GAF. 






CMG, DUP. 










AAP, ATL, 


CMG, 


NAC. 






GAF. 










TRC. 










ALT, BL, 


TRC, 


VPC. 






AAP, ATL, 


DUP, 


NAC. 






GAF, NAC. 










ATL, BKS, 


DUP, 


GAF, 


NAC 


TRC 


NAC. 










DUP. 










AAP. 










DUP, GAF. 










DUP, NAC. 










NAC. 










DUP, NAC. 










ACT. 










ATL, TRC. 










DUP, NAC. 










DUP. 










ALT. 










AAP, ACT, 


ATL, 


BKS, 


BL, 


DUP, 


YAW. 











, FAB, OAF, NAC, IHC, VPC, 



TABLE 8B. —Bemenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 566— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



DIRECT DYES— Continued 

»Direct blue dyes — Continued 

•Direct Blue 2 

Direct Blue 3 - - 

•Direct Blue 6 

Direct Blue 8 

•Direct Blue 14 

•Direct Blue 15 

Direct Blue 21 - 

•Direct Blue 22 

•Direct Blue 24 

•Direct Blue 25 

Direct Blue 26 

Direct Blue 27 

Direct Blue 55 - 

Direct Blue 61 

•Direct Blue 67— - 

Direct Blue 71— 

Direct Blue 74 

Direct Blue 75 - 

•Direct Blue 76 

•Direct Blue 78 

•Direct Blue 80 

•Direct Blue 86 

Direct Blue 87— 

Direct Blue 91— 

•Direct Blue 98 

Direct Blue 100 - - 

Direct Blue 104 — 

•Direct Blue 120 and 120A — 

•Direct Blue 126 

Direct Blue 130 - 

Direct Blue 133 - — - 

Direct Blue 136 

Direct Blue 143 - 

Direct Blue 151— - 

Direct Blue 160— — 

Direct Blue 189- - 

Direct Blue 191 - 

Direct Blue 199— 

Direct Blue 218 ■ 

Direct Blue 224 - 

Direct Blue 238 - 

Other direct blue dyes 

•Direct green dyes: 

•Direct Green 1 

•Direct Qreen 6 

•Direct Green 8 

•Direct Green 12 

Direct Green 15 

Direct Green 26 

Direct Green 27 

Direct Green 28 

Direct Green 38 

Direct Green 39 

Direct Green 41 

Direct Green 45 

Direct Green 47 

Direct Green 51 

Direct Green 69 

Other direct green dyes 

•Direct brown dyes: 

•Direct Brown 1 

•Direct Brown lA 

•Direct Brown 2 

•Direct Brown 6 

Direct Brown 11 

Direct Brown 25 

Direct Brown 27 

•Direct Brown 31 



AAP, ATL, 


BKS, 


BL, DUP, FAB, GAF, 


NAC, 


TRC, VPC, 


NAC. 










AAP, ACY, 


ATL, 


BKS, BL, DUP, GAF, 


NAC, 


TRC, YAW. 


ATL, DUP, 


GAF, 


NAC, YAW. 






ATL, BKS, 


NAC, 


TRC. 






ATL, DUP, 


GAF. 


NAC, YAW. 






TRC. 










ATL, CMG, 


DUP, 


NAC. 






ATL, BKS, 


NAC, 


TRC, YAW. 






ATL, DUP, 


GAF, 


NAC, TRC, YAW. 






ATL, NAC. 










DUP. 










NAC. 










YAW. 










DUP, NAC, 


TRC. 








DUP, GAF, 


NAC, 


TRC. 






DUP. 










TRC. 










ALT, ATL, 


BKS, 


BL, DUP, FAB, GAF, 


NAC, 


TRC, VPC. 


ATL, CMG, 


DUP, 


GAF, NAC, TRC. 






ALT, ATL, 


BKS, 


BL, DUP, FAB, GAF, 


NAC, 


TRC. 


AAP, ACY, 


A1.T, 


ATL, BKS, DUP, FAB 


GAF 


ICC, ICI, 


NAC, SDH, TMS, TRC, VPC. 






ICI. 










TRC. 










ALT, ATL, 


GAF, 


NAC, TRC, VPC. 






ALT, BKS. 










DUP. 










BKS, CMC, 


DUP, 


GAF, TRC. 






BL, DUP, 


GAF, 


NAC, TRC, VPC. 






NAC. 










GAF. 










GAT. 










DUP. 










ATL, NAC, 


TRC. 








TRC. 










BKS, TRC. 










AAP, GAF. 










GAF. 










BKS, OAF, 


NAC. 








ATL. 










ACY. 










ALT, BL, 


DUP, 


FAB, GAF. 






AAP, ACY, 


ATL, 


BKS, DUP, GAF, NAC 


TRC 


YAW. 


AAP, BKS, 


DUP, 


FAB, GAF, NAC, TRC 


YAW 




ATL, NAC, 


TRC, 


YAW. 






DUP, NAC, 


TRC. 








DUP. 










TRC. 










NAC, TRC. 










TRC. 










DUP, GAF. 










GAF. 










DUP. 










VPC. 










DUP, GAF. 










TRC. 










TRC. 










ACY, ALT, 


ATL, 


BL, DUP. 






ACY, ATL, 


BKS, 


BL, DUP, FAB, NAC. 






GAF, TRC, 


YAW. 








AAP, ACY, 


ATL, 


BKS, BL, DUP, GAF, 


NAC, 


TRC, YAW. 


DUP, NAC, 


TRC. 








NAC. 










DUP, NAC. 










OAF. 










AAP, ATL, 


DUP, 


GAF, NAC, TRC, YAW 







SYNTHETIC ORGANIC CHEMICALS, 1966 



-Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, iS66~ Continued 



Manufacturers' Identification codes 
(according to list in table 22) 



DIRECT DYES— Continued 

»Direct brown dyes — Continued 

Direct Brown 32 

Direct Brown 33 

Direct Brown 35 

Direct Brown 4-0 

Direct Brown AA 

Direct Brown 45 

Direct Brown 48 

Direct Brown 59 

•Direct Brown 74 

♦Direct Brown 95 

Direct Brown 101 

Direct Brown 105 

Direct Brown 106 

♦Direct Brown 111 

Direct Brown 112 

Direct Brown 125 

♦Direct Brown 154 

Other direct brown dyes 

♦Direct black dyes: 

♦Direct Black 4 

Direct Black 8 

♦Direct Black 9 

Direct Black 17 

♦Direct Black 19 - - 

♦Direct Black 22 

Direct Black 36— 

Direct Black 37 

♦Direct Black 38- 

Direct Black AA 

Direct Black 45 — — 

♦Direct Black 51— 

Direct Black 55 

Direct Black 56 

Direct Black 61 — 

Direct Black 67 

Direct Black 71 — 

Direct Black 74 

Direct Black 75 

Direct Black 78 

♦Direct Black 80 

Direct Black 109 

Direct Black 123 

Direct Black 130 

Direct Black 190 

Other direct black dyes 

DISPERSE DYES 

♦Disperse yellow dyes: 

Disperse Yellow 1 

Disperse Yellow 2 

♦Disperse Yellow 3 

♦Disperse Yellow 5 

Disperse Yellow 8 

Disperse Yellow 17 

♦Disperse Yellow 23 

Disperse Yellow 31 

Disperse Yellow 32 

♦Disperse Yellow 33 

♦Disperse Yellow 34 

Disperse Yellow 37 

♦Disperse Yellow 42 

Disperse Yellow 50 

Disperse Yellow 54 

Disperse Yellow 67 

Other disperse yellow dyes 

♦Disperse orange dyes: 

♦Disperse Orange 3 

♦Disperse Orange 5 



GAF. 
DUP, 
NAC. 
AAP. 
GAP, 
VPC. 
AAP. 
ACY. 
AAP, 
AAP, 
GAP. 
DUP. 
GAP, 
DUP, 
NAC. 
GAP. 
DUP, 
ALT, 

ATI, 
TRC, 
BKS, 
GAP, 
BKS, 
AAP, 
AAP. 
AAP, 
AAP, 
TRC. 
TRC. 
AAP, 
DUP. 
NAC, 
TRC. 
DUP, 
VPC. 
NAC. 
OAF. 
BKS, 
AAP, 
GAP. 
NAC. 
ACY. 



ACY, ALT, ATL, BL, DUP, VPC, YAW. 



GAP, NAC, TRC, YAW. 
BL, DUP, NAC, VPC. 

BKS, DUP, GAP, NAC, TRC, YAW. 

DUP, GAP, NAC, TRC. 

TRC. 

GAP, NAC, TRC, VPC. 

ALT, ATL, BKS, CMG, DUP, GAP, NAC, TRC, VPC, YAW. 

DUP. 

ACY, AIL, BKS, BL, DUP, PAB, GAP, NAC, TRC, YAW. 

DUP, GAP, NAC, TRC. 

TRC. 

NAC. 



ATL, BKS, BL, FAB, NAC, TRC, VPC, YAW. 



DUP, 


GAP. 
















AAP, 


BKS, 


BL, 


DUP, HCT, GAF, 


HSH, 


ICC, 


NAC, 


SDH, 


TRC 


BKS. 


EKT, 


ICC. 














DUP, 


TRC. 
















AAP. 


















DUP, 


EKT, 


ICC. 














GAT. 


















AAP, 


EKT, 


ICC, 


TRC. 












AAP, 


EKT, 


GAF, 


ICC. 












EKT, 


ICC. 
















AAP, 


DUP, 


GAP, 


TRC. 












TRC. 


















AAP, 


DUP, 


ICC, 


TRC. 












DW. 


















DUP, 


EKT, 


GAF, 


ICC, VPC. 













AAP, BKS, DUP, EKT, GAF, HSH, ICC, NAC, TRC. 
AAP, HCT, GAF. 



DYES 



-Bemenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 7966— Continued 



DISPERSE DYES— Continued 

•Disperse orange dyes--C!ontlnued 

Disperse Orange 16 

•Disperse Orange 17 

Disperse Orange 21 

Disperse Orange 25 

Disperse Orange 26 

Disperse Orange 28 

Disperse Orange 29 

Disperse Orange 30 

Disperse Orange 38 

Disperse Orange AA 

Other disperse orange dyes 

•Disperse red dyes: 

•Disperse Red 1 

Disperse Red i 

•Disperse Red 5 

Disperse Red 7 

Disperse Red 9 

•Disperse Red 11 

•Disperse Red 13 

•Disperse Red 15 

•Disperse Red 17 

Disperse Red 20 

Disperse Red 21 

Disperse Red 30 

Disperse Red 31 

Disperse Red 32 

Disperse Red 53 

Disperse Red 55 

Disperse Red 56 

Disperse Red 59 

•Disperse Red 60 

Disperse Red 61 

Disperse Red 65 

Disperse Red 66 

Disperse Red 73 

Disperse Red 78 

Disperse Red 96 

Other disperse red dyes 

•Disperse violet dyes: 

•Disperse Violet 1 

•Disperse Violet A- 

Disperse Violet 8 

Disperse Violet 11 - - 

Disperse Violet 14 

Disperse Violet 18 - - 

Disperse Violet 22 

Disperse Violet 26 

•Disperse Violet 27— 

Other disperse violet dyes 

•Disperse blue dyes : 

•lisperse Blue 1 — 

•Disperse Blue 3 

ifljisperse Blue 7 

Disperse Blue 8 

Disperse Blue 9 

Disperse Blue 27 

Disperse Blue 35 

Disperse Blue 55 

Disperse Blue 59 

Disperse Blue 60 

Disperse Blue 61 

Disperse Blue 62 

Disperse Blue 63 

•Disperse Blue 6A 

Disperse Blue 70 

Disperse Blue 71 

Disperse Blue 73 

Dlaperse Blue 79 

Disperse Blue 116 

Other disperse blue dyes 



Manufacturers' identification codes 
(according to list in table 22) 



BKS, EKT, HSH, ICC, NAC. 
TRC. 



BKS, DUP, EKT, GAF, HSH, ICC, NAC, TRC, YAW. 

TRC. 

BKS, EKT, GAF, HSH, ICC. 



DUP, GAF, TRC. 

BKS, DUP, GAF, ICC. 

GAF, HSH, ICC, NAC. 

BKS, DUP, EKT, GAF, HSH, ICC, TRC. 



DUP, VPC. 
TRC. 



BKS, DUP, EKT, GAF, ICC, TRC, VPC. 



GAF, HSH, ICC, TRC. 
GAF, ICC. 



NAC. 
TRC. 



GAF, TRC. 

BKS, EKT, GAF, HSH, ICC, NAC, TRC. 

BKS, EKT, GAF, HSH, ICC, TRC. 



DUP, EXT, OAF, HSH, ICC, VPC. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



-Bemenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 566— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



DISPERSE DYES— Continued 

Disperse green dyes 

Disperse brown dyes: 

Disperse Brown 1 

Disperse Brown 2 

Other disperse brown dyes 

^Disperse black dyes : 

^Disperse Black 1 

Disperse Black 2 

Disperse Black 6 

Disperse Black 7 

♦Disperse Black 9 

Other disperse black dyes 

FIBZR-REACTIVi: DYES 

Reactive yellow dyes: 

Reactive Yellow 1 

Reactive Yellow 2 - 

Reactive Yellow 3 - 

Reactive Yellow <♦ 

Reactive Yellow 6- - 

Reactive Yellow 7 — 

Reactive Yellow 11 — 

Reactive Yellow 13 

Reactive Yellow U 

Reactive Yellow 15 

Reactive Yellow 16 

Reactive Yellow 17 - - 

Reactive Yellow 18 — 

Reactive Yellow 22 — 

Reactive Yellow 24 

Other reactive yellow dyes 

Reactive orange dyes: 

Reactive Orange 1 

Reactive Orange A 

Reactive Orange 5 

Reactive Orange 7 

Reactive Orange 12 

Reactive Orange 13 

Reactive Orange K 

Reactive Orange 16 

Other reactive orange dyes 

Reactive red dyes: 

Reactive Red 1 

Reactive Red 2 

Reactive Red 3 

Reactive Red 4 

Reactive Red 5 

Reactive Red 8 

Reactive Red 11 - 

Reactive Red 13 - 

Reactive Red 16 

Reactive Bed 21 

Reactive Red 29 - ■ 

Reactive Red 31- • 

Reactive Red 33- - 

Other reactive red dyes 

Reactive violet dyes: 

Reactive Violet 1 

Reactive Violet 2 

Reactive Violet A 

Reactive Violet 5- — 

Other reactive violet dyes 

♦Reactive blue dyes: 

Reactive Blue 1 

Reactive Blue 2 

Reactive Blue 3 

Reactive Blue 4 

Reactive Blue 5 

Reactive Blue 7 



GAF, 


ICC. 




TRC. 






DUP, 


GAF. 




EKT, 


ICC. 




AAP, 


DUP, GAF, TRC. 




DUP, 


TRC. 




AAP. 






YAW. 






AAP, 


BL, DUP, OCT, GAF. 




DUP, 


HCT, GAF, ICC, VPC, 


YAW 



ICI. 

ICI. 

ICI. 

TRC. 

ICI. 

ICI. 

ICI. 

ICI. 

TRC. 

HST. 

ICI. 

HST, ICI. 

ICI. 

DUP, GAF. 

ICI. 
TRC. 
HST. 
HST. 



ICI. 
TRC. 
ICI. 
ICI. 
TRC. 
TRC. 



105 



■Bemenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 566— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



FIBER-REACTIVE DYES— Continued 

»Reactive blue dyes — Continued 

Reactive Blue 9 

Reactive Blue 18 

Reactive Blue 19 

Reactive Blue 21 - — 

Reactive Blue 25 

Reactive Blue' 27 

Other reactive blue dyes 

Reactive green dyes 

Reactive brown dyes: 

Reactive Brown 1 

Reactive Brown 10 

Reactive black dyes : 

Reactive Black 1 

Reactive Black 5 

Reactive Black 9 

FLUORESCENT BRIGHTINING AGEMTS 

Fluorescent Brightening Agent 1 

Fluorescent Brightening Agent 6 

Fluorescent Brightening Agent 8 

Fluorescent Brightening Agent 9 

Fluorescent Brightening Agent 22 

Fluorescent Brightening Agent 24 

Fluorescent Brightening Agent 25 

»Fluorescent Brightening Agent 28 

Fluorescent Brightening Agent 30 

Fluorescent Brightening Agent 33 

Fluorescent Brightening Agent 34 

Fluorescent Brightening Agent 37 

Fluorescent Brightening Agent 45 

Fluorescent Brightening Agent 46 

Fluorescent Brightening Agent 49 

Fluorescent Brightening Agent 52 

Fluorescent Brightening Agent 54 

Fluorescent Brightening Agent 59 

Fluorescent Brightening Agent 61 

Fluorescent Brightening Agent 68 

Fluorescent Brightening Agent 71 

Fluorescent Brightening Agent 75 

Fluorescent Brightening Agent 102 

Fluorescent Brightening Agent 108 

Fluorescent Brightening Agent 113 

Fluorescent Brightening Agent 114 - 

Fluorescent Brightening Agent 125 

Fluorescent Brightening Agent 126 

Fluorescent Brightening Agent 128 

Fluorescent Brightening Agent 130 

Fluorescent Brightening Agent 134 

Fluorescent Brightening Agent 135 - 

Fluorescent Brightening Agent 136 

Fluorescent Brightening Agent 139 

Fluorescent Brightening Agent 155 

Fluorescent Brightening Agent 158 

Fluorescent Brightening Agent 159 

Fluorescent Brightening Agent 161 

Other fluoreecait brightening agents 

FOOD, DRUG, AND COSWETIC COLORS 

Food, Drug, and Cosmetic Dyes 

»FD&C Blue No. 1— - - 

»FD&C Blue No. 2— 

FDtC Green No. 3 

•FDStC Red No. 2- 

•FDfcC Red No. 3 

»FD8tC Red No. 4- 

FDfcC Violet No. 1 



ICI. 




TRC. 




DUP, 


HST. 


DUP, 


HST. 


ICI. 




HST. 




DUP, 


GAF, HST 


HST, 


ICI. 


TRC. 




ICI. 




TRC. 




HST. 





GGY. 

ACY. 

ACY. 

ACY, GAF, SDH. 

GGY. 

GGY. 

GAF. 

ACY, CCW, DUP. 

GAF. 

GAF. 

DUP. 

CIB. 

TRC. 

GGY. 

S. 

S. 

GGY. 

GGY. 

ACY. 

CCW, GAF. 

ACY, GAF. 

GAF. 

DUP. 

GAF. 

VPC. 

VPC. 

ACY. 

SDH. 

SDH. 

SDH. 

CIB. 

CIB. 

CIB. 

CIB. 

Wlil. 

ACY. 

ACY. 

ACY. 

ACY, CCW, CIB, DUP, GGY, S. VPC. 



WJ. 

ALT, KON, NAC, SDH, STG, WJ. 

ALT, KON, NAC, SDH, STG. 

KON, NAC, SDH, WJ. 

NAC. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



■Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 566— Continued 



Manuf acturere ' identification codes 
(according to list in table 22) 



FOOD, DRDO, AND COSMEnC COLOBS— Continued 

food. Drug, and Comestic Dyes --Continued 

«FD8cC Yellow No. 5 - 

»FD&C Yellow No. 6 

Other food, drug, and cosmetic dyes 

Drug and Cosmetic Dyes 

nScC Blue No. 6 — 

D6C Blue No. 9 

DStC Brown No. 1- - 

nStC Green No. 5—- — - 

D&C Green No. 6 - - 

DScC Green No. 8 

»DS:C Orange No. 4 

E&C Orange No. 5 

E&C Orange No. 10 

D&C Orange No. 17— 

D&C Red No. 3 - 

ntC Red No. 6 - 

»I&C Red No. 7 - 

D&C Red No. 8 — 

nS:C Red No. 9 - — 

DSrC Red No. 10 

D&C Red No. 11— - 

nSiC Red No. 12- 

nScC Red No. 13 - 

r&C Red No. 17— 

*1&.C Red No. 19-- 

»E&C Red No. 21 - 

E&C Red No. 22 — 

D&C Red No. 27 

nStC Red No. 28— - — 

DScC Red No. 30— - - 

ntC Red No. 31 — 

D6C Red No. 33 - 

D&C Red No. 3A 

»Dfi:C Red No. 36 

D&C Red No. 37 - 

DScC Red No. 39- • 

DScC Violet No. 2- 

V&C Yellow No. 5— - 

DfeC Yellow No. 6 

D&C Yellow No. 7 

DtC Yellow No. 8 

DkC Yellow No. 10 

E&C Yellow No. 11 

Drug and Cosmetic Dyes, External 

Bet. D&C Green No. 1 

Ext. D&C Orange No. 3 — 

Btt. DScC Red No. 8 

Bet. DScC Violet No. 2 

Bet. nScC Yellow No. 1 

Bet. DSrC Yellow No. 5 

Bet. DfeC Yellow No. 7 

INGRAIN DYES 

Ingrain blue dyes: 

Ingrain Blue 1 

Ingrain Blue 2 

Ingrain Blue 3 

Ingrain Blue 6 

UORDANT DYES 

Mtordant yellow dyeo; 

Mordant Yellow 1 



ALT, KON, 


NAC, 


SDH, STG, WJ 


ALT, KON, 


NAC, 


SDH, STG, WJ 


STG, WJ. 






KON, NAC. 






NAG. 






NAC. 






KON, NAC. 






NAC. 






KON, SDH. 






KON, NAC, 


SNA. 




SNA, IMS. 






TMS. 






KON, SNA. 






KON. 






KON, SNA, 


TMS. 




KON, SNA, 


TMS. 




KON, ms. 






KON, SNA, 


TMS. 




KON, SNA. 






KON, SNA. 






SNA, TMS. 






SNA, TMS. 






KON, NAC. 






KON, NAC, 


SNA, 


TMS. 


KON, SNA, 


TMS. 




KON. 






TMS. 






NAC. 






KON. 






KON. 






NAC. 






KON. 






KON, SNA, 


TMS. 




NAC. 






SDH. 






NAC. 






KON, TMS. 






KON. 






KON. 






KON, NAC, 


TUS. 




KON, NAC. 






NAC. 






KON, NAC. 






KON, NAC. 






SNA. 






KON. 






KON, NAC. 






SNA. 






KON. 







OAF, PDC, TRC. 



DYES 



TABLE 8B. --Bemenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 566— Continued 



Manufacturers' Identification codes 
(according to list in table 22) 



MORDANT DYES— Continued 



"Mordant yellow dyes — Continued 

Ktordant Yellow 3- 

Itordant Yellow 5 

"Mordant Yellow 8 

Mordant Yellow 10 

Itordant Yellow 14 — - 

•Ktordant Yellow 16 

MDrdant Yellow 20 

Mordant Yellow 26— 

Mordant Yellow 29 — 

Itordant Yellow 30 

Jtordant Yellow 36 

"Mordant orange dyes: 

"Mordant Orange 1 

Mordant Orange •i 

ktordant Orange 6 

Ktordant Orange 8 

Mordant Orange 30 

"Mordant red dyes: 

Mordant Red 3 

Ktordant Red 5 

Mordant Red 6 

<*tordant Red 7 

<«Drdant Red 9—- 

Itordant Red 11— 

Mordant Red 19 

Mordant Red 64 

Mordant violet dyes: 

Mordant Violet 11 - 

Ktordant Violet 20— 

"Ktordant blue dyes: 

<4tordant Blue 1 

Mordant Blue 3 

Mordant Blue 7 

Ktordant Blue 9 

Ktordant Blue 13— -. 

Mordant Blue 19- 

Ktordant green dyes: 

Ktordant Green 11 

Ktordant Green 36 

Ktordant Green 47 

"Mordant brown dyes: 

ifttordant Brown 1 

Mordant Brown 12 

Mordant Brown 13 

Ktordant Brown 15 

Ktordant Brown 17 

Mordant Brown 18 

Mordant Brown 19 

Mordant Brown 21 

"Mordant Brown 33 



3wn 40 

Mordant Brown 50 

Itordant Brown 63 

Ktordant Brown 70 

"Mordant black dyes: 

Ktordant Black 1 

"Jtordant Black 3 

"Mordant Black 5 

Mordant Black 7 

Mordant Black 8 

itordant Black 9' 

"Mordant Black 11 

♦Mordant Black 13 

Ktordant Black 16 

"Ktordant Black 17 

Mordant Black 19 

Mordant Black 26 

"Mordant Black 38 



ATL, NAC. 






TRC. 






DUP, NAG, VPC. 






DUP, NAC. 






NAC, TRC. 






ACY, DUP, NAC. 






NAC. 






VPC. 






GAF. 






TRC, VPC. 






PDC. 






ACY, GAF, PDC, TRC 






GAF. 






ATL, GAF, TRC. 






TRC. 






NAC. 






ACY, NAC. 






PDC. 






GAF. 






ACY, BDO, CMG, GAF, 


NAC, PDC, TRC, VPC. 


GAF, MRX, NAC. 






ACY, NAC. 






PDC. 






PDC. 






GAF. 






GAF. 






DUP, GAF, NAC, TRC. 






GAF. 






TRC. 






GAF, NAC. 






HSH, NAC. 






CMG. 






ACY. 






PDC. 






NAC. 






CMG, DUP, GAF, NAC, 


TRC, YAW. 




PDC. 






NAC. 






GAF. 






CMG. 






DUP, NAC. 






GAF. 






GAF, VPC. 






DUP, GAF, NAC, TRC. 






CMG, DUP, GAF, NAC, 


VPC, YAW. 




TRC. 






TRC. 






DUP, PDC. 






GAF, NAC. 






GAF, NAC, TRC. 






NAC, TRC. 






GAF. 






VPC. 






NAC, VPC. 






GAF, NAC, TRC, VPC. 






GAF, HSH, NAC, TRC. 






NAC, PDC. 






ACY, DUP, GAF, NAC, 


TRC. 




PDC. 






TRC. 






CWG, GAF, NAC. 







SYNTHETIC ORGANIC CHEMICALS, 1966 



-Bemenotd dyes for which U.S. production or sal 
manufacturer, i 966— Continued 



reported, identified by 



Manufacturers' identification codes 
(according to list in table 22) 



OXIDATION BASES 

CKidation Base 8 and 8A 

Oxidation Base 21 

Oxidation Base 22 

Oxidation Base 25 

Other oxidation bases 

SOLVIHT DYES 

•Solvent yellow dyes : 

Solvent Yellow 1 

•Solvent Yellow 2 

•Solvent Yellow 3 

Solvent Yellow 13 

•Solvent Yellow U--- -- 

Solvent Yellow 16 --- 

Solvent Yellow 19 - — 

Solvent Yellow 29 

Solvent Yellow 30 

Solvent Yellow 33 

Solvent Yellow 34 

Solvent Yellow 40 

Solvent Yellow 42 — - 

Solvent Yellow 43 

Solvent Yellow 44 

Solvent Yellow 45 

Solvent Yellow 47 

Solvent Yellow 56 

Solvent Yellow 71 

Solvent Yellow 72 — - 

Other solvent yellow dyes 

•Solvent orange dyes : 

Solvent Orange 1 

Solvent Orange 2 

•Solvent Orange 3 

Solvent Orange 5 

•Solvent Orange 7 

Solvent Orange 20 

Solvent Orange 23 

Solvent Orange 24 

Solvent Orange 25 

Solvent Orange 31 

Solvent Orange 47 

Solvent Orange 48 

Solvent Orange 51 

Other solvent orange dyes 

•Solvent red dyes : 

Solvent Red 8 

Solvent Red 22 - 

•Solvent Red 24 

•Solvent Red 26 — 

Solvent Red 27 

Solvent Red 33 — - — 

Solvent Red 34 

Solvent Red 35 

Solvent Red 36 

Solvent Red 40 

Solvent Red 41 - — 

•Solvent Red 49 

Solvent Red 52 

Solvent Red 65 - 

Solvent Red 68 

Solvent Red 69 

Solvent Red 74 

Solvent Red 75 

Solvent Red 76 

Solvent Red 80 

Solvent Red 105 

Solvent Red 108 

Solvent Red 111 

Solvent Red 115 

Other solvent red dyes 



AAP, 


DUP, 


FH, 


GAF, PAT, 


PSC. 






DUP, 


FH, 


GAF, 


NAC, PSC. 








ACY, 


GAF, 


TRC 










AAP, 


ACY, 


DUP 


FH, GAF, 


NAC, PAT, 


PSC, 


SDH. 


PAT. 














GAF. 














GAF. 














NAC, 


PSC. 












ACY, 


NAC. 












DUP. 














NAC. 














NAC. 














GAF. 














GAF, 


NAC 












DUP. 


NAG 












ACY, 


DUP, 


GAF 


NAC. 








ACY, 


FH, 


NAC. 











AAP, ACY, DSC, PAT. 



ACY, 


GAF, 


NAC, 


PSC. 




GAF, 


TRC. 








ACY, 


GAF, 


NAC. 






ACY, 


GAF. 








NAC. 










DUP. 










ACY, 


DUP. 








NAC. 










FH. 










ACY. 










ACY. 










AAP, 


ACY, 


DSC, 


DUP, 


PAT 


GAF. 










GAF. 










ACY, 


DUP, 


GAF, 


PAT, 


SDH 


AAP, 


ACY, 


FH, 


HAC, 


PSC. 


NAC. 










DUP, 


GAF. 








DUP. 










GAF. 










NAC. 










GAF. 










asc. 










ACY, 


DSC, 


DUP, 


GAF. 




GAF, 


ICI. 








NAC. 










NAC. 










DUP. 










NAC. 










NAC. 










NAC. 










ACY, 


NAC. 








ACY. 










ACY. 










ACY. 










ACY. 










AAP, 


ACY, 


DSC, 


DUP, 


GAF, 



DYES 



TABLE 8B. -- Bemenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 566- -ConUnued 



Manufacturers' identification code 
(according to list in table 22) 



SOLVHfT DYES— Continued 

"Solvent violet dyes: 

"Solvent Violet 8 - 

Solvent Violet 9 - 

Solvent Violet 13 - 

Solvent Violet U— 

Solvent Violet 17 - — 

Other solvent violet dyes 

Solvent blue dyes: 

Solvent Blue 3 — 

Solvent Blue A 

Solvent Blue 5 

Solvent Blue 6 

Solvent Blue 7 

Solvent Blue 9— 

Solvent Blue 11 

Solvent Blue 12 

Solvait Blue 16 

Solvent Blue 32 

Solvent Blue 36 

Solvent Blue 37 

Solvent Blue 38 

Solvent Blue 39 

Solvent Blue 43 

Solvent Blue 58 

Solvent Blue 59 

Solvent Blue 60 

Solvent Blue 74- 

Other solvent blue dyes 

"Solvent green dyes; 

Solvent Green 1 

Solvent Green 2 

"Solvent Green 3 

Solvent Green 10 

Solvent Green 11 

Other solvent green dyes 

"Solvent brown dyes : 

Solvent Brown 11 

"Solvent Brown 12 

Solvent Brown 17 

Solvent Brown 19 

Solvent Brown 20 

Solvent Brown 22 

Solvent Brown 38 

Other solvent brown dyes 

Solvent black dyes: 

Solvent Black 3 - — 

Solvent Black 5 — - 

Solvent Black 7 

Solvent Black 12 - - 

Solvent Black 13 

Solvent Black 17— 

Solvent Black 26 

Other solvent black dyes 

SULFUR DYES 

Sulfur yellow dyes: 

Sulfur Yellow 2 

Leueo Sulfur Yellow 2 

Sulfur Yellow i. 

Leuco Sulfur Yellow 4 

Leuco Sulfur Yellow 15 

Other sulfur yellow dyes 

Sulfur orange dyes: 

Sulfur Orange 1 

Leuco Sulfur Orange 1 

Sulfur red dyes: 

Sulfur Red 1 - 

Leuco Sulfur Red 5 

•Sulfur Red 6- - 



ACY, 


DSC, 


NAC. 


DSC. 






AAP, 


HSH, 


ICI. 


ICI. 






NAC. 
DSC, 


PAT. 




ACY. 


sw. 




DSC, 


DUP, 


SDH. 


DSC. 






DSC. 






ACY, 


NAC. 




GAF. 






GAF. 


ICI. 




DUP, 


NAC. 




NAC. 






AAP. 






DUP, 


NAC. 




DUP. 






ACY, 


DUP, 


NAC. 


NAC. 






NAC. 






ACY. 






ACY. 






ACY. 






NAC. 






AAP, 


ACY, 


DSC, GAF, ICI, PAT, 


ACY, 


DSC, 


SDH. 


GAF. 






AAP, 


ACY, 


ATL, GAF, HSH, NAC 


DUP. 






DUP. 






DSC. 






GAF. 






ACY, 


DSC, 


GAF. 


DUP. 






DUP. 






ACY, 


DUP. 




FH. 






ACY. 






DSC. 






NAC. 






ACY, 


DSC. 


NAC. 


ACY, 


DSC, 


FH, NAC. 


NAC. 






NAC. 






DUP. 






ACY. 






ACY, 


DSC. 





SDC. 






ACY, 


SDC. 




AUG, 


DUP, 


SDC. 


SDC. 






ACY. 






ACY, 


SDC. 




SDC. 






SDC. 






ACY, 


NAC. 




SDC. 






ACY, 


DUP, 


NAC. SDC 



SYNTHETIC ORGANIC CHEMICALS, 1966 



-Bemenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 966— Continued 



SULFUR DYiS— Continued 



Sulfur red dyee— Continued 

Leuco Sulfur Red 6 

Sulfur Red 8 

Sulfur blue dyes: 

»Sulfur Blue 7 

Leuoo Sulfur Blue 7 

Leuco Sulfur Blue 8 

Sulfur Blue 9 — 

Leuco Sulfur Blue 9— 

•Sulfur Blue 11 

Leuoo Sulfur Blue 13 

Sulfur Blue 15— 

Other sulfur blue dyee 

Sulfur green dyes: 

Sulfur Green 1 

Leuoo Sulfur (Jreen 1 

Sulfur Green 2 

Leuco Sulfur Green 2 

Sulfur Green 3 

Sulfur Green 14 

Sulfur Green 16 

Leuoo Sulfur Green 16 

Sulfur Green 28 

Other sulfur green dyes 

Sulfur brown dyes: 

Sulfur Brown 3 

Leuoo Sulfur Brown 3 

Sulfur Brown 10 

Leuoo Sulfur Brown 10 

Solubillzed Sulfur Brown 10- 

Leuoo Sulfur Brown 12 

Sulfur Brown 14 

Leuoo Sulfur Brown 14 

Sulfur Brown 20 

Sulfur Brown 21 

Sulfur Brown 26 

Sulfur Brown 30 

Sulfur Brown 33 

Sulfur Brown 37 - 

Leuco Sulfur Brown 37 

Sulfur Brown 39 

Sulfur Brown 43 

Sulfur Brown 44 - 

Leuco Sulfur Brown 44 

Sulfur Brown 45 

Sulfur Brown 50 

Sulfur Brown 76 

Leuoo Sulfur Brown 82 

Other sulfur brown dyes 

Sulfur black dyes: 

«Sulfur Black 1 

Leuoo Sulfur Black 1 

Sulfur Black 2 — 

Leuoo Sulfur Black 2- 

Sulfur Black 6- 

Leuoo Sulfur Black 6 

Sulfur Black 10 

Leuoo Sulfur Black 10 

Sulfur Black 11 

Leuoo Sulfur Black 11 

Other sulfur black dyes 



<«Vat yellow dyes: 

Vat Yellow 1, 12-1/251- 

•Vat Yellow 2, 8-l/2lt- 

Solubllized Vat Yellow 2, 255^- 
Vat Yellow 3, 12-1/2*- 

•Vat Yellow 4, 12-l/25t- - 



Manufacturers' identification codes 
(according to list in table 22) 



ACY, 

ACY, 

SDC. 

ACY, 

SDC. 

DUP, 

ACY. 

ACY, 1 

ACY, i 

NAG. 

NAC. 

NAC, . 

SDC. 

NAC. 

DUP. 

SDC. 

SDC. 

ACY. 

AUG, 

SDC. 
SDC, 
DUP, 
SDC. 
AUG. 
SDC. 
ACY. 
ACY, 
DUP. 
DUP. 
ACY, 
ACY. 

ACY. 
SDC. 

SDC. 

SDC. 

NAC. 

NAC 

NAC. 

NAC. 

NAC. 

ACY. 

ACY. 

ACY, 

ACY, 
ACY, 
ACY, 
ACY, 
GAF. 
NAC. 
ACY. 
ACY, 



DUP, NAC, SDC. 
NAC, SDC. 



NAC. 
NAC, SDC. 



AUG, SDC. 

DUP, NAC, SDC. 

AUG, NAC, SDC. 

DUP, NAC, SDC. 

NAC, SDC. 



AAP, DUP, GAF, ICI, NAC, TRC, VPC. 

GAF, ICI. 

DUP. 

ACY, ATL, CMG, GAF, HST, ICI, NAC, VPC. 



DYES 



■Bemenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 7566— Continued 



Manuf aoturers • Identification codes 
(according to list in table 22) 



VAT DYES— Continued 

•KVat yellow dyes — Continued 

»Solubillzed Vat Yellow A, 37-l/2^t 

Vat Yellow 10, 10!« 

Vat Yellow 13, 6-1/256 

Vat Yellow U, 12-l/25( 

Vat Yellow 15, ll-l/25t— 

Vat Yellow 22, lO^J 

Vat Yellow 27 

Vat Yellow 33, IS^t- 

Vat Yellow Al, 9<^--- 

Other vat yellow dyes 

»Vat orange dyes : 

•Vat Clrange 1, 205t 

•Solubillzed Vat Orange 1, 26* 

»Vat Orange 2, 125t 

•Vat Orange 3, 13-l/25t 

Vat Orange A, 65t 

•Vat Orange 5, IO56 

•Solubillzed Vat Orange 5, 30?t 

•Vat Orange 7, 11*-- 

•Vat Orange 9, 125t - - 

Vat Orange 11, 6^6 

•Vat Orange 15, 10*- 

Vat Orange 23, 17-1/2*-- 

Vat Orange 24 

Other vat orange dyes 

•Vat red dyes: 

•Vat Red 1, 13* 

Solubilized Vat Red 1, 37*- - - 

•Vat Red 10, 18*— - 

Solubilized Vat Red 10, 31* 

Vat Red 12, 8-1/2* 

•Vat Red 13, 11* --- 

Vat Red W, 10*-— — - 

•Vat Red 15, 10*- 

Vat Red 16, 11* 

Vat Red 17, 10*- - 

Vat Red 23- - 

Vat Red 29, 18* 

•Vat Red 32, 20*- 

Vat Red 35, 12-1/2* - - 

Vat Red Al, 20* 

Vat Red 44, 17*- — 

Vat Red 52, 10*- - 

Vat Red 53, 12*- — ■ 

Vat Red 62 - 

Other vat red dyes 

•Vat violet dyes: 

•Vat Violet 1, 11*- - 

Solubilized Vat Violet 1, 26*- • 

•Vat Violet 2, 20* 

Vat Violet 3, 15*- 

•Vat Violet 9, 12*- — 

•Vat Violet 13, 6-1/4* - 

Vat Violet 14, 12-1/2*- — • 

•Vat Violet 17, 12-1/2*-— • 

Other vat violet dyes 

•Vat blue dyes: 

Vat Blue 1, 20*- - - 

Solubilized Vat Blue 1, 25*- 

Vat Blue 4, 10* 

Vat Blue 5, 16* — 

Solubilized Vat Blue 5, 38*-— 

*Vat Blue 6, 8-l/3!t- 

Solubilized Vat Blue 6, 17-1/2*- — ■ 

Vat Blue 7, 12-1/2* 

Solubilized Vat Blue 9, 35* - - 

Vat Blue 12, 6-1/2*—- 

Vat Blue 14, 8-1/3* 

<*Vat Blue 16, 16-1/2*- - 



OAF, 


HST, 


ICI. 










GAF. 














ICI. 














TRC. 














ACY. 














DUP, 


GAF. 












VPC. 














TRC. 














ACY. 














MAY, 


NAC, 


VPC. 










CMC, 


GAF, 


HST. 


ICI. 


NAC. 


TRC. 


VPC 


GAF, 


HST, 


ICI. 










ACY, 


CMG. 


DUP, 


GAF, 


ICI, 


NAC, 


TRC 


CMG, 


DUP, 


GAF. 


HST, 


NAC. 






ACY, 


CMG, 


DUP. 










AAP, 


ACY, 


HST. 










QAF, 


HST, 


ICI. 










GAF, 


HST, 


TRC. 










ACY, 


CMG. 


DUP. 


GAF. 


ICI, 


NAC, 


TRC 


DUP, 


NAC. 












AAP, 


GAF, 


ICI. 


MAY. 


NAC. 


TRC. 


VPC 


ACY, 


DUP. 


GAF. 










DUP. 














SDC. 














AAP, 


ACY. 


HST. 


ICI. 








GAF, 


HST, 


ICI. 










GAF, 


NAC. 


TRC. 










GAF. 














DUP. 














DUP, 


GAF, 


TRC. 










GAF, 


HST. 












GAF, 


HST, 


TRC. 










DUP. 














GAF. 














DUP. 














GAF, 


NAC. 












DUP, 


GAF, 


NAC. 










NAC, 


TRC. 












HST. 














TRC. 














DUP. 














DUP. 














DUP. 














DUP, 


GAF, 


TRC, 


VPC. 








ACY, 


DUP. 


GAF. 


ICI. 


MAY. 


NAC, 


TRC. 


GAF. 














ACY, 


GAF, 


HST, 


NAC, 


VPC. 






GAF, 


HST. 


NAC. 










DUP, 


GAF. 


ICI. 


MAY, 


NAC, 


TRC. 




DUP. 


GAF, 


TCI, 


NAC. 


TRC. 






NAC. 














DUP, 


GAF. 


NAC. 










MAY. 














NAC. 














GAF. 














AAP, 


ACY, 


DUP. 


GAF. 








ATL, 


DUP, 


HST. 


NAC. 


VPC 






GAF, 


HST. 












ACY, 


DUP. 


GAF. 


ICI. 


UAY. 


NAC, 


TRC. 


GAF, 


HST. 


TCI. 










NAC. 














GAF. 














DUP. 














DUP, 


GAF, 


NAC, 


TRC. 








ACY, 


DUP, 


ICI, 


NAC. 









SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 8B. --Bemenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i 966— Continued 



VAT DYES— Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



*Vat blue dyes--Continued 

*Vat Blue 18, 135t 

»Vat Blue 20, U,i 

Vat Blue 26, 24it 

Vat Blue 29 

Vat Blue 35, 20^ 

Vat Blue 39, 12?t- 

Vat Blue 42 

Vat Blue A3 

Vat Blue 53, 20-l/2']( 

Vat Blue 60 

Other vat blue dyes 

■»Vat green dyes : 

*Vat Green 1, 6St- 

Solubilized Vat Green 1, 12-l/25t— 

»Vat Green 3, lO^t 

»Solubilized Vat Green 3, 26%- 

»Vat Green 8, 8-1/2* 

»Vat Green 9, 12-l/2?6 

Vat Green 15, 17* 

Vat Green 18, 8* — 

Vat Green 20, 6* 

Other vat green dyes 

»Vat brovm dyes : 

»Vat Brown 1, 11* 

Solubilized Vat Brorni 1, 17* 

»Vat Brown 3, 11* 

»Vat Brown 5, 13* 

Vat Brown 11, 12* - 

Vat Brown 12, 12-l/2'> 

Vat Brown 13, 17* 

Vat Brown 20, 10-1/2* 

Vat Brown 25, 11-1/2*- - 

Vat Brown 28, 22*-— 

Vat Brown 29, 13* 

Vat Brown 31, 28*- 

Vat Brown 38, 20* 

Vat Brown 40, 14*- 

Vat Brown 53 

Vat Brown 57, 15*- 

Other vat brown dyes 

»Vat black dyes : 

Vat Black 1 

Solubilized Vat Black 1, 27-1/2*— 

*Vat Black 9, 16* 

Vat Black 11, 17-1/2* 

Vat Black 13, 14* 

Vat Black 14, 11-1/2* 

Vat Black 15 — 

Vat Black 18, 15-1/2* 

Vat Black 21, 18-1/2* 

Vat Black 22, 19* 

»Vat Black 25, 12-1/2* 

»Vat Black 27, 12-1/2* 

Vat Black 34, 16*- 

Vat Black 37 

Vat Black 38, 20* — 

Vat Black 52, 18-1/2* 

Other vat black dyes 

All other dyes 



AAP, 
AAP, 
GAF. 
GAF. 
HST. 
GAF. 
SDC. 
SDC. 
GAF. 
DUP. 
MAY, 

AAP, 
GAF, 
AAP, 
GAF, 
ATL, 
ACY, 
NAC. 
DUP. 



DUP. 
GAF. 
GAF, 
DUP, 

GAF. 
GAF, 
ATL, 
ACY. 
DUP, 
DUP. 
AAP. 
GAF, 
ACY. 
ACY, 
AAP, 
AAP, 
ICI. 
GAF. 
GAF. 
ACY. 
DUP, 
ACY, 



ACY, DUP, GAF, MAY, NAC, TRC. 

ACY, ATL, DUP, GAF, ICI, MAY, NAC, SDC, TRC. 



SDC, VPC, X. 

ACY, DUP, GAF, ICI, MAX. 

HST, ICI. 

ACY, ATL, DUP, GAF, ICI, MAY, NAC, TRC. 



ATL, DUP, GAF, MAY, NAC, SDC, TRC. 



DUP, GAF, ICI, MAY, NAC, TRC. 

ICI. 

ACY, DUP, GAF, ICI, MAY, NAC, TRC, VPC. 

ACY, GAF, HST, VPC. 

TRC. 

NAC. 



GAF, NAC. 



ACY, DUP, GAF, ICI, MAY, NAC, TRC. 
ACY, DUP, GAF, ICI, MAY, NAC, TRC, VPC. 



GAF, SDC, TRC. 
PAT, SDC. 



PIGMENTS 
Pigments 



TABLE ilB.—Bemenoid pigments for which U.S. production i 
by manufacturer, 1966 



sales were reported, identified 



[Benzenoid pigments for which separate statistics are given in table llA are marked below with an asterisk (»); 
products not so marked do not appear in table llA because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 22) 



TONERS 

♦Yellow toners; 
»Hansa yellows: 

•Pigment Yellow 1, C.I. 11 680 

•Pigment Yellow 3, C.I. 11 710 

Pigment Yellow A, C.I. 11 665 ■ 

Pigment Yellow 5, C.I. 11 660 

Pigment Yellow 6, C.I. 11 670 

Pigment Yellow 9, C.I. 11 720- 

Pigment Yellow 49, C.I. 11 765 

Pigment Yellow 65, C.I. 11 740 

•Pigment Yellow 73 

•Pigment Yellow 74, C.I. 11 741 

All other Hansa yellows 

•Benzidine yellow: 

•Pigment Yellow 12, C.I. 21 090 

•Pigment Yellow 13, C.I. 21 100 

•Pigment Yellow 14, C.I. 21 095 

•Pigment Yellow 17, CI. 21 105 

Pigment Yellow 83 

All other benzidine yellows 

Pigment Yellow 10, C.I. 12 710 

Pigment Yellow 18, C.I. 49 005 

Pigment Yellow 60, C.I. 12 705 

(Basic Yellow 2), C.I. 41,000 fugitii 

(Vat Yellow 1), C.I. 70 600— — - 

(Vat Yellow 20), C.I. 68 420 

All other 

•Orange toners: 

Pigment Orange 1, C.I. 11 725 — 

•Pigment Orange 2, C.I. 12 060 

•Pigment Orange 5, C.I. 12 075 

•Pigment Orange 13, C.I. 21 110 

Pigment Orange 15, C.I. 21 130 

•Pigment Orange 16, C.I. 21 160— 

Pigment Orange 30 

(Vat Orange 1), C.I. 59 105 

(Vat Orange 2), C.I. 59 705 

(Vat Orange 3), C.I. 59 300- 

(Vat Orange 4), C.I. 59 710— — 

»(Vat Orange 7), C.I. 71 105- — 

All other - - -- 

•Red toners: 
•Naphthol reds: 

•Pigment Red 2, C.I. 12 310 

•Pigment Red 5, C.I. 12 490 — 

Pigment Bed 7, C.I. 12 420 

Pigment Red 9, C.I. 12 460 

Pigment Red 10, C.I. 12 440- 

•Pigment Red 13, C.I. 12 395 

Pigment Red 14, C.I. 12 380— 

Pigment Red 15, C.I. 12 465 

•Pigment Red 17, C.I. 12 390 

•Pigment Red 18, C.I. 12 350— 



ACY, AMS, DUP, FCL, GAF, HSC, HSH, ICI, IMP, KON, NAC, 

PPG, S, SDH, SNA, SW. 
HSC, HSH, HST, IMP, KCW, KON, NAC, PPG, S, SW. 
NAC, SNA. 
IMP. 
IMP. 
SNA. 
ICI. 
SW. 

NAC, SNA, SW, X. 
DUP, SDH, SW. 
DUP, HSC, KCW. 

ACY, AMS, CIK, DUP, FCL, GAF, HSC, HSH, ICC, IMP, KON, 

LVY, MRX, NAC, S, SDH, SNA, SW. 

BUC, FCL, GAF, HSC, HSH, HST, ICC, IMP, ROM, SDH, SNA, 

SW. 

ACY, AMS, BUC, CIK, CPC, DUP, FCL, GAF, HSC, HSH, HST, 

ICC, IMP, KON, MRX, NAC, ROM, S, SDH, SNA, SW, x. 

ACY, BUC, DUP, FCL, HSH, HSC, HST, ICC, IMP, SDH, SNA, 



IMP, ROM, S, SW. 



IMP, S, SW. 

KCW, NAC. 

FCL, IMP, SDH, SW. 

ACY, HSC, IMP, SNA, SW. 

ACY, AMS, HSC, IMP, KON, NAC, SNA, SW. 

GAF, NAC. 

BUC, DUP, FCL, GAF, HSH, HST, ICC, IMP, NAC, ROM, SDH, 

SNA, SW. 
SNA. 
HST. 
GAF. 

NAC, TRC. 
NAC. 

GAF, HST, NAC. 
BUC, HSH, ICC, KON, ROM, SDH. 



GAF, HSC, IMP, KCW, KON, MRX, NAC, SDH, SW. 

DUP, GAF, HSH, HST, ICC, ICI, IMP, NAC, ROM, S, SDH, 



HST, 
AMS, 


NAC. 
HSH, 


ICC 


IMP. 
SW. 






MRX. 
NAC, 
NAC. 
ACY, 


TRC. 
GAF, 


ICC 



IMP. 

KCW. 

IMP, KCW, NAC, SW. 

DUP. 

DUP. 

ACY, BLN, FCL, ICC, IMP, S, SNA, UHL. 

IMP, NAC, SW. 



See note at end of table for definition of abbreviations. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE IIB. 



■Benzenoid pigments for which U.S. production or sales were reported, identified 
by manufacturer, iSfiff— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



TONERS— Continued 

»Red toners — Continued 
»Naphtliol reds--Continued 

Pigment Red 19, C.I. 12 -iOO- - ■ 

»Pigment Red 22, C.I. 12 315 

♦Pigment Red 23, C.I. 12 355 

Pigment Red 31, C.I. 12 360 

All other naphthol reds 

♦Pigment Red 1, C.I. 12 070, dark - 

♦Pigment Red 1, C.I. 12 070, light — 

♦Pigment Red 3, C.I. 12 120 • 

♦Pigment Red A, G.I. 12 085 - • 

♦Pigment Red 6, C.I. 12 090 

♦Pigment Red 38, C.I. 21 120 ■ 

Pigment Red -H, C.I. 21 200 

♦Pigment Red A8, C.I. 15 865— — 

Pigment Red A9, C.I. 15 630: 
♦Barium toner 

♦Calcium toner 

♦Sodium toner 

♦Pigment Red 52, C.I. 15 860 

♦Pigment Red 53, C.I. 15 585, barium toner- 
Pigment Red 53, C.I. 15 585, sodium toner- 

♦Pigment Red 54, C.I. 14 830, calcium toner- 
Pigment Red 55, C.I. 15 820 

♦Pigment Red 57, C.I. 15 850, calcium toner- 
Pigment Red 58, C.I. 15 825 

♦Pigment Red 63, C.I. 15 880 

Pigment Red 64, C.I. 15 800 — 

Pigment Red 77, C.I. 15 826 

Pigment Red 79, PMA - 

Pigment Red 81, C.I. 45 160, fugitive - 

♦Pigment Red 81, C.I. 45 160, PMA 

♦Pigment Red 81, C.I. 45 160, PTA— - 

Pigment Red 87, C.I. 73 310 - 

Pigment Red 88 

♦Pigment Red 90, C.I. 45 380 - 

Pigment Red 117, C.I. 15 603 

Pigment Red 122 - 

Pigment Red 123 

(Vat Red 1), C.I. 73 360 

(Vat Red 10), C.I. 67 000 

(Vat Red 23), C.I. 71 130- 

(Vat Red 29), C.I. 71 140 

All other 

♦Violet toners: 

Pigment Violet 1, C.I. 45 170, fugitive-— 

♦Pigment Violet 1, C.I. 45 170, PMA 

♦Pigment Violet 1, C.I. 45 170, PTA- • 

♦Pigment Violet 3, C.I. 42 535, fugitive 

♦Pigment Violet 3, C.I. 42 535, PMA 

♦Pigment Violet 3, C.I. 42 535, PTA- ■ 

Pigment Violet 19, C.I. 46 500— 

♦Pigment Violet 23— • 

(Vat Violet 1), C.I. 60 010 — 

(Vat Violet 2), C.I. 73 385 

(Vat Violet 3), C.I. 73 395 

All other 



NAC. 

ACY, DUP, FGL, IMP, MRX, NAC, SNA, SW. 

ACY, BUC, DUP, FCL, ICC, IMP, NAC, ROM, SHi, SNA, SW. 

SNA, SW. 

ICC, KCW, ROM, SDH, SW, x. 

ACY, AMS, FCL, HSC, HSH, IMP, KON, LVY, NAC, SDH, SW. 

ACY, HSC, HSH, IMP, KON, PPG, SDH, SW. 

ACY, BLN, CIK, DUP, FCL, HSC, HSH, IMP, KCW, KON, NAC, 

PPG, SDH, SNA, SW, UHL. 

ACY, AMS, FCL, HSC, HSH, IMP, KON, MRX, SDH, SNA, SW, 

UHL. 

DUP, HSC, HSH, KCW, SW. 

DUP, GAF, ICG, NAC, SNA, SW. 
GAF, NAC. 

ACY, AMS, BLN, DUP, FCL, G.AF, HSC, HSH, IMP, KON, LVY, 

MRX, NAC, S, SNA, SW. 

ACY, AMS, CIK, FCL, HSC, IMP, KON, LVY, SDH, SNA, SW, 

UHL. 

ACY, AMS, FCL, HSC, IMP, LVY, PPG, SDH, SNA, SW. 

ACY, AMS, FCL, HSC, KON, SDH, SW. 

AMS, FCL, HSC, HSH, IMP, SNA, SW. 

ACY, AMS, GIK, FCL, HSC, IMP, KON, LVY, MGR, MRX, SDH, 

SNA, SW. 
KON. 

HSH, IMP, MRX, SDH. 

DUP, NAC. 

AMS, BLN, CIK, DUP, FCL, HSC, HSH, IMP, KON, LVY, ICR, 

NAC, S, SDH, SNA, SW. 

DUP, GAF, IMP. 

FCL, HSH, IMP, KON, NAC, SNA, SW. 
NAC. 
SW. 
GAF. 

BLN, KCW. 

BLN, CPC, DUP, FCL, GAF, IMP, KON, LVR, LVY, MGR, MRX, 

NYC, S, SNA. 

ACY, AMS, BLN, DUP, FCL, OAF, HSC, IMP, KCW, KON, MQR, 

MRX, S, SDH, SNA- 
NAC. 

NAC, SDH. 

AMS, FCL, ICC, IMP, LVR, LVY, NYC, SDH, SNA. 
SW. 
NAC. 
NAC. 
HST. 

GAF, NAC. 
NAC. 

GAF, HSC, NAC. 

ACY, DUP, GAF, HAM, HSC, SW, TRC. 

BLN, UHL. 

GAF, IMP, LVR, M3R, MRX. 

ACY, AMS, DUP, FCL, GAF, HSC, IMP, KON, M3R, MRX, S, 

SNA. 

ACY, AMS, BLN, HAM, HSC, IMP, KON, LVR, LVY, ICR, UHL. 

AMS, BLN, CIK, DUP, EAK, GAF, HSC, IMP, KON, LVY, ICR, 

MRX, NYC, PPG, SDH, SNA, SW, UHL. 

ACY, AKE, BLN, GAF, HSC, IMP, KON, MRX, SNA, SW. 

DUP, NAC. 

ACY, GAF, HST, NAC, TRC. 
DUP. 
NAC. 
NAC 

BUC, ICC, IMP, ROM. 



See note at end of table for definition of abbreviations. 



115 



TABLE IIB — Bemenoid pigments for which U.S. production or sales were reported, identified 
by manufacturer, i 566— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



TONERS— Continued 

»Blue toners: 

•Pigment Blue 1, C.I. « 595, PMA- 

"Pigment Blue 1, C.I. 42 595, PTA 

"Pigment Blue 2, C.I. 44 045, fugitive 

"Pigment Blue 2, C.I. 44 045, PMA - 

"Pigment Blue 2, C.I. 44 045, PTA 

Pigment Blue 3, C.I. 42 140, PMA 

Pigment Blue 3, C.I. 42 140, PTA - 

Pigment Blue 5, C.I. 42 600 

Pigment Blue 9, C.I. 42 025, PMA- — 

"Pigment Blue 9, C.I. 42 025, PTA 

Pigment Blue 10, C.I. 44 O40, PMA - 

Pigment Blue 10, C.I. 44 CXO, PTA— - 

"Pigment Blue 14, C.I. 42 600, PMA 

Pigment Blue 14, C.I. 42 600, PTA - 

"Pigment Blue 15, C.I. 74 160, alpha form 

•Pigment Blue 15, C.I. 74 160, beta form 

"Pigment Blue 19, C.I. 42 750A 

•Pigment Blue 22, C.I. 69 810 — 

"Pigment Blue 25, C.I. 21 180 

Pigment Blue 27, C.I. 77 510 

(Basic Blue 7), C.I. 42 595, PTA - 

(Vat Blue 4), C.I. 69 800 — - 

(Vat Blue 6), C.I. 69 825 — 

All other— - - - 

*Qreea toners: 

•Pigment Green 1, C.I. 42 040, PMA — 

•Pigment Green 1, C.I. 42 040, PTA- 

•Pigment Green 2, C.I. 42 040 and 49 005, PMA 

•Pigment Green 2, C.I. 42 040 and 49 005, PTA— - 

Pigment Green 4, C.I. 42 000, fugitive 

•Pigment Green 4, C.I. 42 000, PMA 

•Pigment Green 4, C.I. 42 000, PTA 

•Pigment Green 7, C.I. 74 260 

•Pigment Green 8, C.I. 10 006 

Pigment Green 10, C.I. 12 775- 

•Pigment Green 36, C.I. 74 265 

Pigment Green 38— - - 

•Brown toners: 

Pigment Brown 1, C.I. 12 480 - 

Pigment Brown 2, C.I. 12 071 

•Pigment Brown 3, C.I. 21 010 PMA — 

•Pigment Brown 5, C.I. 15 800— - - 

(Vat Brown 3), C.I. 69 015— — 

All other— - 

•Black toners: 

Pigment Black 1, C.I. 50 440 

Pigment Black 7, C.I. 77 266 - 

All other — 

LAKES 

•Ttellow lakes: 

(Acid yellow 1), C.I. 10 316 

(Acid Yellow 3), C.I. 47 005- 

(Acid Yellow 23), C.I. 19 140 - 

Orange lakes: 

Pigment Orange 17, C.I. 15 510 

All other — — 

Red lakes: 

•Pigment Red 60, C.I. 16 105 

•Pigment Red 83, C.I. 58 000 — - — 

(Acid Red 17), C.I. 16 180 

See note at end of table for definition of abbreviations, 



BLN, DUP, EAK, GAF, HSC, IMP, KON, LVH, IVY, M3R, MRX, 

NYC, SDH, SNA, SW, UHL. 

AMS, GAF, HAM, IMP, KON, MGR, NAC, SNA, SW. 
BLN. 

GAF, IMP, LVR. 
HAM. 
MGR. 
MGR. 
GAF. 

LVR, MRX, NYC. 

BLN, GAF, IMP, MRX, SDH. 

IMP, SDH. 
IMP. 

DUP, OAF, IMP, NYC. 

DUP, NYC. 

ACY, DUP, FCL, OAF, HSC, ICC, ICI, IMP, NAC, SNA, SW, 

IMS, TRC. 

ACY, AMS, DUP, FCL, HSC, ICC, IMP, LVY, NAC, SNA, SW, 

IMS. 

ACY, AMS, HSC, NYC, SW. 

DUP, IMP, NAC, TRC. 

DUP, GAF, ICC, NAC, S. 
GAF. 
DUP. 
GAF. 

ICI, TRC. 

GAF, IMP, SDH. 



BLN, GAF, IMP, MRX, NYC, UHL. 

BLN, IMP, MGR, S, SDH. 

GAF, IMP, KON, LVY, MGR, MRX, SDH, UHL. 

ACY, AMS, DUP, GAF, IMP, KON, LVY; MRX, S, SDH, UH 

BLN, GAF. 

BLN, GAF, MGR. 

ACY, AMS, HAM, IMP, KON, MGR. 

ACY, CIK, DUP, FCL, GAF, HSC, ICC, IMP, NAC, SNA, 

TMS, TRC. 

DUP, HSH, IMP, KCW, SW. 

DUP, HSC, IMP, SW. 

ACY, GAF, NAC, SNA. 
NAC. 



ICI. 

HSH, SDH. 

BLN, KCW, KON. 

BUC, HSH, ICC, NAC, ROM, SNA. 

GAF, NAC, TRC. 

GAF, ICC, SDH, SW. 

SNA. 
GAF. 

BLN, DUP, GAF, UHL. 



IMP. 
IMP. 
KON, MGR, MRX. 



BLN, HSC, HSH, KON, MRX, SNA, SW. 
HSH, IMP, KON, MRX, PPQ, SW, UHL. 
IMP, KCW. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE IIB. 



-Bemenoid pigments for which U.S. production or sales were reported, identified 
by manufacturer, i566~Continued 



Pigment 


Manufacturers' identification codes 
(according to list in table 22) 


LAKES— Continued 

fled lakes— Continued 

(Acid Red 25), C.I. 16 050 

•(Aold Red 26), C.I. 16 150 - - 


KON. 

CPC, HAM, IMP, KCW. 

KON. 

IMP. 

HAM, IMP. 

BLN, DUP, HSH, IMP, KON, NAC. 

SH. 

BLN. 

HAM, HSC. 

BLN, CPC, KCW. 

AMS, BLN, KON, LVY, SDH. 

LVR. 

CPC, KCW. 

BLN, CPC. 

HAM, KON. 

CPC, KON, NYC. 
HAM. 




All other- - - 

»Vlolet lakes: 


Pigment Violet 20, C.I. 58 225 

(Acid Violet 17), C.I. 42 650 

All other — 

Blue lakes: 












Black lakes: 




er 



Note. — The C.I. (Colour Index) numbers snown in this report are the identifying codes given in the second edition of 
the Colour Inaex. 

When the name of a color is enclosed in parentheses, it indicates that this name is that of the dye from which the 
pigment can be made and that no name for the pigment itself is given in the Colour Iruiex. 

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic) 
acids, respectively. 



MEDICINAL CHEMICALS 
Medicinal Chemicals 



TABLE IZB.— Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1966 

[Medicinal chemicals for which separate statistics are given in table 13A in pt. II are marked below with an asterisk 
(»); medicinal chemicals not so marked do not appear in table 13A because the reported data are accepted in con- 
fidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x 
signifies that the manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 22) 



» Antibiotics: 
»For medicinal use: 

^Antifungal and antitubercular antibiotics 
Antifungal antibiotics: 

Amphotericin B 

Candlcldin 

Nystatin 

Antitubercular antibiotics : 

Cycloserine 

Dihydrostreptomyoin 

Streptomycin 

Viomycin 

♦Bacitracin 

♦Penicillins: 

Ampicillin 

Cloxacillin, sodium 

Dicloxacillin, sodium 

Hetacillln— ^ - — • 

Methicillin, sodium - ■ 

Nafcillin, sodium • 

Oxacillin, sodium 

Penicillin G, benzathine 

•Penicillin G, potassium 

•Penicillin G, procaine 

Penicillin G, sodium 

Penicillin 0, sodium 

Phenethicillin, potassium 

Phenoxymethylpenicillin (Penicillin V)-- 

Phenoxymethylpenicillin, benzathine 

Phenoxymethylpenicillin, hydrabamlne 

Phenoxymethylpenicillin, potassium 

•Other antibiotics for medicinal use: 

Cephaloridine 

Cephalothin 

Chloramphenicol 

Erythromycin 

Fumagillin 

Gentamycin 

Gramicidin 

Kanamycin 

Llncctnycin 

Neomycin 

Novobiocin 

Oleandomycin 

Paromomycin 

Polymyxin B 

Tetracyclines: 

Chlortetracycline 

Demethylchlortetraoycline 

Methacycline 

Oxytetracycllne 

Tetracycline 

Thiostrepton 

Triacetyloleandomycin 

lyrothricin 

Vancomycin 

•For other uses: 

•Bacitracin 

Chlortetracycline 

Cycloheximide 

Hygronycin B- 

Neomycin 

Novobiocin 

Oxytetracycllne 



OMS. 








PEN. 








OMS. 








COM. 








MHK, 


PFZ. 






LIL, 


MRK, 


OMS. 


PFZ 


PFZ. 








COM, 


PEN, 


PFZ, 


PMP. 


BRS, 


WYT. 






BRS. 








BRS. 








BRS. 








BRS. 








WYT. 








BRS. 








PFZ, 


WYT. 






LIL, 


MRK, 


OMS, 


PFZ, 


LIL, 


MRK, 


OMS, 


PFZ, 


QMS. 








UP J. 








BRS, 


WYT. 






LIL. 








WYT. 








ABB. 








ABB, 


LIL. 






LIL. 








LIL. 








PD. 








ABB, 


LIL. 






ABB. 








SCH. 








BAX, 


PEN. 






BRS. 








X. 








OMS, 
MRX, 


PEN, 
UP J. 


PFZ, 


UP J. 


PFZ. 








PFZ. 









ACY, BRS, PFZ, RI^. 

CftiB. 

PFZ. 

BAX, PEN. 

LIL. 



UP J. 
LIL. 
PEN, 
UP J. 
PFZ. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 13B.— Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 566— Continued 



Manufacturers' identification codes 
( according to list in table 22 ) 



»Antibiotios--Continued 
»For other uses--Continued 
♦Penicillin G salts: 

Penicillin G, benzathine 

Penicillin G, procaine 

Streptomycin 

lyiosin 

►Anticoagulants: 

Ammonium heparin 

Anlsindione 

Bisliydroxycoumarin 

Phenindione 

Potassium heparin 

♦Sodium heparin 

Sodium warfarin 

» Antihistamines: 
♦Antinauseants: 

Cyclizine hydrochloride 

Dlmenhydrinate 

Meclizine hydrochloride 

Trimethobenzamide hydrochloride 

Bromodiphenhydr amine hydrochloride 

Brompheniramine maleate 

Carbinoxamine 

Chlorcyclizine hydrochloride 

Chlorothen citrate 

♦Chlorpheniramine maleate 

Cyproheptadine hydrochloride 

Dexbrompheniramlne maleate 

Dexchlorpheniramine maleate 

Dimethindene maleate 

Diphenhydramine hydrochloride 

Doxylamine succinate 

Methapyrilene fumarate 

Jfethapyrilene hydrochloride 

Jfethapyrilene hydroxybenzoylbenzoate 

Phenindamine tartrate 

♦Pheniramine maleate 

Phenyltoloxamine citrate 

Pyrllamine maleate 

Pyrrobut amine phosphate 

Thenyldiamlne hydrochloride 

Thonzylamlne hydrochloride 

Tripelennamine 

Tripelennamine citrate 

Tripelennamine hydrochloride 

Triprolidlne hydrochloride 

*Anti-infective agents (except antibiotics): 
♦Arsenic, bismuth, and mercury compounds: 
Arsenic and bismuth compounds: 

Arsanilic acid-'- 

Bismu-th dlpropylacetate 

Bismu-th sodium triglycollamate 

Bismuth subsalicylate 

Carbarsone 

Glycobiarsol 

Nitarsone 

Roxarsone 

Sodium arsanilate-"- 

Mercury compounds: 

o-Hydroxyphenylmercuric chloride 

Merbromin 

Mercuric salicylate 

Nitromersol 

Phenylmer curie acetate 

Phenylmercuric benzoate 

Phenylmerouric borate 

Phenylmercuric nitrate 

Thimerosal 

See footnotes at end of table. 



LIL. 


MRK. 


QMS, PFZ 


LIL, 


MRK, 


PFZ. 


LIL. 






WIL. 






SCH. 






ABB, 


FIN. 




CTN, 


GAN. 




WIL. 






ABB, 


RIK, 


WIL. 


EN. 






BUR. 






SRL. 






PFZ. 






HOF. 






PD. 






SCH. 






SCH. 






ABB, 


BUR. 




ACY. 






HFJC, 


LEM, 


SCH, SK, 


MRK. 






SCH. 






SCH. 






CBP. 






ARA, 


GAN, 


PD. 


BKC. 






ABB. 






ABB. 






LIL. 






HOF. 






HEX, 


LEM, 


SCH, X. 


BRS. 






HEX, 


MRK, 


fiSA. 


LIL. 






SEW. 






NEP. 






CBP. 






CBP. 






CBP. 






BUR. 







BPC. 






MAL, 


NOR, 


PEN 


LIL, 


PYL, 


WHL 


PYL, 


SDW. 




SAL. 






SAL. 






PYL, 


SAL, 


WHL. 


MRK. 






HYN. 






MAL. 






ABB. 






WRC. 






MRK, 


WRC. 




MRK, 


WRC. 




MRK, 


WRC. 




LIL, 


PYL, 


SEL. 



MEDICINAL CHEMICALS 



-Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 966— Continued 



Uanvifaoturere ' Identification codes 
( according to list In table 22) 



"Antl-lnfectlve agents (except antibiotics) --Continued 

"Caprylatee and undecylenates: 

Calcium undecylenate 

Sodium caprylate 

Sodium undecylenate 

Undecylenic acid 

Zinc undecylenate 

•p-Hydroxybenzoic acid esters: 

Benzylparaben 

Butylparaben'- 

Ethylparaben^ 

"Methylparaben^ 

Propylparaben^ 

»5-Nltrofurane, -imidazole, and -thiazole derivatives 

Aolnitrazole 

2-Mlno-5-nltrothlazole 

Furazolidone 

Metronidazole 

Nihydrazone 

Nl thiazide 

Nitrofurantoin 

Nitrofurazone 

•Phenolic antiseptics and disinfectants: 

Betanaphthol^ 

Blthlonol 

Chloro thymol 

Resorcinol'"' 

Reeorclnol monoacetate-"- 

niymol 

Thymol iodide 

»Piperazlne base and salts: 

•Plperazlne-"- 

Piperazlne adipate 

Piperazine calcium edetate 

Piperazlne citrate 

Piperazine dihydrochloride 

Piperazine hexahydrate 

Piperazine hydrochloride 

Piperazine phosphate 

Piperazine sulfate 

Piperazlne tartrate 

»(Jilnollne derivatives: 

Amodiaquln 

Amodiaquln hydrochloride 

Chloroqulne phosphate 

•Diiodohydroxyquin 

Hydroxychloroquine sulfate 

8-Hydroxy-5-quinollnesulfonic acid 

lodochlorhydroxyquin 

Qxyqulnollne 

»Qxyquinollne benzoate 

Qxyquinoline citrate 

Qxyqulnollne potassium sulfate 

»Qxyqulnollne sulfate 

Primaquine phosphate 

"Sulfonamides: 

Acetyl sulfamethoxypyridazine 

Acetyl sulflsoxazole 

Azosulf amide 

Dinsed - 

Mafenlde acetate 

Mafenide hydrochloride 

Para-nitrosulfathiazole 

Phthalylsulfacetamide 

Phthalylsulfathiazole 

Sucolnylsulfathlazole 

Sulfabenz amide 

Sulfabenzamide, sodium 

Sulfabromomethazlne, sodium 

Sulfacetamide 



WTL. 






LEM, TNC 






BAC. 






BAC. 






BAC, LEM, 


TNC 


WTL. 


LEM. 






HN, ICO. 






HN. 






HN, ICO, 


LEM, 


PYL, 


HN, ICO, 


LEM, 


WSN. 


ACY. 






ACY. 






NOR. 






RDA. 






NOR. 






MRK. 






NOR. 






NOR. 






ACY, FIN. 






SDH. 






OPC. 






LEM- 






FIN, KPT. 






GIV. 






MAL. 






DOW, FLM, 


JCC, 


UCC. 


JCC, PYL. 






EN. 






BUR, JCC. 






DOW, FLM, 


JCC, 


WHL. 


JCC, RDA, 


SEL. 




DOW, JCC. 






BUR, JCC, 


PYL. 




JCC. 






PYl. 






PD. 






PD. 






SDW. 






CBP, LEM, 


PYL, 


RSA. 


SDW. 






MRK. 






CBP, PYL. 






GAM, LEM, 


MRK. 




QAM, LEM, 


MRK. 





GAM, LEM, MRK, PYL. 



ACY. 
HOF. 
SOU. 
SAL. 
SEW. 
SDW. 
SIW. 

T.ITM, 

LQI, MEK, PYL. 

LEM, MRK, PYL 

ACY. 

ACY. 

MRK. 

T.RU. 



See footnotes at eal of table. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



-Medicinal chemicals for Which U.S. production or sales were reported, identified by 
manufacturer, 2566— Continued 



ManuTaoturers ' identification codes 
(according to list in table 22) 



*Anti-infectlve agents (except antlbiotics)--Continued 
♦Sulfonamides — Continued 

Sulfacetamide, sodium 

Sulfactaoropyrazine, sodium 

Sulfadiazine 

Sulfadiazine, sodium 

Sulfadimethoxine 

Sulfaethidole- 

Sulfaguanidine 

Sulfamerazine 

Sulfamerazine, sodium 

Sulfamethazine 

Sulfamethlzole 

Sulfamethoxazole 

Sulfamethoxypyridazine 

Sulfanilamide 

Sulfanltran 

Sulfapyridine 

Sulfapyridine, sodium 

Sulfaqulnox aline 

Sulfathiazole 

SulfatMazole, sodium 

Sulfisoxazole 

»Other anti-infective agents: 

♦Anthelmintic, antifungal, antiprotozoan, and 
antivirEil agents: 
Anthelmintic agents: 

Cadium anthranilate 

Diethylcarbamaztne citrate 

Gentian violet 

Hexylresorcinol 

Ehenothiazine 

Pyrvinium pamoate 

Thiabendazole 

Antifungal agents: 

Benzoic acid-"- 

Diamthazole hydrochloride 

Fuchsin, basic 

Salicylanilide^ 

Antiprotozoan agents: 

Aklomlde 

Amprolium 

Chlorbetamlde 

Nitrophenlde ■ 

Pyrimethamine 

Antiviral agent: Amantadine hydrochloride 

•Urinary antiseptics: 

Ammonium benzoate 

Ammonium mandelate 

Calcium mandelate 

Ethoxazene hydrochloride 

Mandelic acid - 

Methenamlne 

Methenamine hippurate 

Methenamlne mandelate 

Methylene blue 

Phenazopyridine hydrochloride 

»A11 other: 

Aorlflavine 

Aminacrine 

Aminacrine hydrochloride 

Antileprotio and antltubercular agents: 

Aminosalicylic acid 

Calcium aminosalicylate 

Dapeone 

Isonlazid 

Potassium amlnoealioylate 

Pyrazlnamlde 

Sodium aminosalicylate 

Sodium sulfoxone 



LEM. 




ACY. 




ACY, 


LEM. 


ACY. 




HOF. 




ACY. 




ACY, 


LEM. 


ACY, 


LEM. 


ACY. 




ACY, 


LEM. 


ACY. 




HOF. 




ACY. 




LEM, 


MRK. 


SAL. 




ACY, 


MRK. 


ACY. 




MRK. 




ACY, 


LEM, MRK. 


ACY, 


MRK. 


HOF. 





MAL. 

ACY. 

NAC, SDH. 

HEX, MRK. 

CLV. 

x. 

MRK. 

MON, PFZ. 

HOF. 

NAC. 



RSA. 

MAL. 

KON. 

MAL. 

HN. 

RIK. 

ARN, LEM, NEP, PYL, TNC. 

ACY, NAC. 

HOF, KON, NEP. 

NAC. 



RIL. 
MLS. 
MRK. 
MLS. 
JiBB. 



See footnotes at end of table. 



MEDICINAL CHEMICALS 



TABLE MB.— Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 566— Continued 



Manufacturers' Identification codes 
(according to list in table 22) 



•Antl- infective agents (except antibiotics) — Continued 
»Other anti-infective agents- -Continued 
«A11 other — Continued 

BenzRlkonixim chloride 

Bromoform 

Camphor, monobromated 

Cetallconlum chloride 

Cetylpyridinium chloride 

Chloramine T 

Chlorobutanol 

Iodoform^ 

Magnesium salicylate 

Nalidixic acid 

Nltromide 

Providone - iodine complex 

♦Antineoplastic agents and local anesthetics: 
Antineoplastic agents: 

Mercaptopurlne ^ 

Ure thane 

Vinblastine sulfate 

Vincristine sulfate 

Local anesthetics: 

Butacalne sulfate 

Butamben plcrate 

Butyl amlnobenzoate (Butamben) 

Dibucalne 

Wbucalne hydrochloride 

Ethyl amlnobenzoate (Benzocalne) 

Isobutyl amlnobenzoate 

»Lidocalne 

Qxethazalne 

Phenacaine hydrochloride 

Piperocalne hydrochloride 

Pramoxine hydrochloride 

Procaine 

Procaine hydrochloride 

Proparacaine hydrochloride 

Propyl amlnobenzoate 

Pyrrocalne hydrochloride 

Tetracaine 

Tetracaine hydrochloride 

♦Autonomic drugs: 

Ganglionic blocking agent: Hexemethonlum chloride-- 
Parasyinpatholytic (anticholinergic) agents: 
♦Quaternary ammonium compounds (except tropane 
derivatives) : 

Ambutonlum bromide 

Dlphemanll methylsulfate 

Hexocycllum methylsulfate 

Isopropamlde iodide 

Mepenzolate bromide 

Methanthellne brcmlde 

Plpenzolate bromide 

Pralldoxlme chloride 

Propantheline bromide 

Thlhexinol methylbromlde 

Trldlhexethyl iodide — 

Tertiary amines (except tropane derivatives): 

Adiphenlne hydrochloride 

Amlnopentamlde sulfate 

Caramlphen edisylate 

Dicyclomine hydrochloride 

Ethopropazine 

Orphenadrlne citrate 

Orphenadrine hydrochloride 

Oxyphencycllmlne hydrochloride 

Piperidolate hydrochloride 

Thlphenamll hydrochloride 

Trihexyphenidyl hydrochloride 



SDH. 






DOW. 






MAL, 


PEN. 




FIN, 


SDW. 




FIN, 


HEX, 


NEP 


MON. 






BPC, 


PD. 




MAL, 


PEN. 




MAL. 






SDH. 






SAL. 






GAF. 






BUR. 






FMP. 






LIL. 






LIL. 






ABB. 






ABB. 






ABB. 






CBP. 






CBP. 






ABB, 


LEM. 




ICO. 






AST, 


LEM, 


SDW. 


WiT. 






GAN, 


SDW. 




LIL. 






ABB. 






ABB. 






ABB, 


I.EM, 


PFZ. 


QMS. 






ICO. 






EN. 






SDW. 






ICO, 


RSA, 


SDW. 



ICO. 

SCH. 

ABB. 

SK. 

LKL. 

SRL. 

LiCL. 

CBP, NEP. 

SHL. 

SCH. 

ACY. 



SK. 

BKC. 

NEP. 

RIK. 

RIK. 

PFZ. 

LKL. 

BJL, X. 

ACY, SDW. 



'^e footnotes at end of table. 



SYNTHETIC ORGANIC CHtMICALS, 1966 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufactu.'er , 1966 — Continued 



ManuTaoturers ' identification codes 
(according to list in table 22) 



»Autonomlc drugs — Continued 

Parasympatholytic (anticholinergic) agents--Continued 
Tropane derivatives: 

Anisotropine methylbromide 

Benztropine mesylate 

Homatropine 

Homatropine hydrobromide 

»Homatropine methylbromide 

Parasympathomimetic (cholinergic) agents: 

Acetylcholine chloride 

Methachollne chloride 

Neostigmine bromide 

Ehysostigmine salicylate 

Pyridostigmine bromide 

Sympatholytic (antiadrenergic) agent: Ergonovine 
maleate 
•Sympathomimetic (adrenergic) agents: 

Adrenalone 

Cinnamedrine (Cinnamylephedrine) 

Cyclopentamine hydrochloride 

Epinephrine bitartrate (levo) 

Epinephrine hydrochloride (racemic) 

•Isoproterenol salts: 

Isoproterenol hydrochloride 

Isoproterenol sulfate 

Levarterenol bitartrate 

dl-Metanephrine hydrochloride 

Metaraminol bitartrate 

Methoxyphenamine hydrochloride 

Naphazoline hydrochloride 

Nordefrin hydrochloride 

Nylidrin hydrochloride 

•Phenylephrine 

Phenylephrine bitartrate 

Phenylephrine hydrochloride 

•Phenylpropanolamine hydrochloride 

Propylhexedrine 

Protoiylol hydrochloride 

Pseudoephedrine hydrochloride 

Pseudoephedrine sulfate 

Tetrahydrozollne hydrochloride 

♦Cardiovascular agents: 
•Cardiac drugs: 

Calcium camphorsulfonate 

Digitoxin 

Procainamide hydrochloride 

Quinldine gluconate 

Quinidine sulfate 

•Rauwolfia and veratrum alkaloids: 

Aliavervir— - - — 

Alseroxylon 

Deserpidine 

Reserpine 

Syrosingopine 

•Other cardiovascular agents: 

Antihypertensive agents (except rauwolfia and veratrum 
alkaloids) : 

Hydralazine hydrochloride 

Methyldopa 

Pargyline hydrochloride 

Bioflavonoids: 

Hesperidln 

Hesperidin methyl chalcone 

Lemon bioflavonoid 

Naringin 

Rutin — - - - 

Vasodilators: 

Dioxyline phosphate 

Ethyl nitrite - 

Glyceryl trinitrate 

Isosorbide dinltrate 

Mannltol hexanltrate 



OTN, 


HEX. 


CTN. 




CTN, 


EN, HEX 


MRK, 


RSA. 


MRK, 


RSA. 


HEX. 




PEN. 




HOF. 




LIL. 





GAN, SDW. 
ABB, GAN. 
SDW. 
SDW. 
SDW. 



CTN, 
GAN. 
CTN, 
BKL, 
HEX, 
LKL. 
BUR, 
GAN. 
PFZ. 



FIN, PYL. 
BUR. 

LEM, QMS. 
HEX. 
HEX. 



SKG. 
SKG. 
SKG. 
SKG. 



LIL. 
MAL. 
APD. 
APD. 
APD. 



MEDICINAL CHEMICALS 



123 



TABLE 13B. —Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 566— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



•Cardiovascular agents— Continued 

*Other cardiovascular agents — Continued 
Vasodilators — Continued 

Nlcotlnyl alcohol tartrate 

Pentaerythrltol tetranltrate 

•Central depressants and stimulants: 
•Amphetamines: 

Amphetamine (racemic) 

Amphetamine hydrochloride (racemic) 

Amphetamine sulfate (racemic) 

Dextroamphetamine 

Dextroamphetamine carboxymethylcellulose 

Dextroamphetamine hydrochloride 

Dextroamphetamine phosphate 

•Dextroamphetamine sulfate 

Dextroamphetamine tannate 

Lev amphetamine succinate 

•Jfethamphetamlne base and hydrochloride: 

Methamphetamine ( dextro) 

tfethamphetamine (levo) 

Methamphetamine (racemic) 

Methanqjhetamlne hydrochloride (dextro) 

Methamphetamine hydrochloride (racemic) 

•Anticonvulsants, hypnotics, and sedatives (except 
barbiturates) : 
Anticonvulsants: 

Aminoglutethlmide 

Diphenylhydantoin 

Diphenylhy'is^'''Oin, sodium 

EthoEuximlde 

Etbotoln 

Methsuximlde 

Paramethadione 

Phenacemide 

Phensuximlde 

Trimethadione 

Hypnotics and sedatives: 

Carbromal 

Ethohlorvynol 

Ethinamate 

Glutethlmide 

Methyprylon 

•Antidepressants: 

Amltrlptyline 

Deslpramine hydrochloride 

Imlpramlne hydrochloride 

Isocarboxazid 

Nialamide — 

Nortriptyline 

Phenelzine sulfate 

•Barbiturates: 

5-Allyl-5-(2-cyclopenten-l-yl)barbituric acid 

Amobarbltal 

Amobarbital, sodium 

Barbital- — 

Barbital, sodium 

Butabarbital- 

•Butabarbital, sodium 

Butalbltal 

Butalbltal, sodium 

Butethal— 

Cyclobarbital 

Cyclobarbital, calcium 

5-Ethyl-5-pentylbarbiturlo acid 

Hexobarbital 

Hexobarbltal, sodium 

Ifephobarbital 

Metharbital 

Uethohexltal, sodium 

Pentobarbital 

Pentobarbital, sodium 

Ehenobarbltal 



HOF. 






APD. 






HEX, 


ORT. 




ARN, 


HEX, 




AHN, 


HEX. 




HEX. 






AHN. 






ARN, 


HEX. 




ARN, 


HEX. 




ARN, 


HEX, 


SK. 


ARN. 






ARN. 






HEX. 






ABB. 






HEX. 






ABB, 


ARN, 


GAN, HEX. 


ARN, 


GAN, 


HEX. 


CBP. 






PD. 






PD. 






PD. 






ABB. 






PD. 






ABB. 






ABB. 






PD. 






ABB. 






PD. 






ABB. 






LIL. 






CBP. 






HOF. 






MRK. 






GGY, 


LKL. 




GGY. 






HOF. 






PFZ. 






LIL. 






NEP. 






GAN. 






LIL. 






GAN, 


LIL. 




GAN. 






GAN. 






ABB, 


GAN. 




ABB, 


BPC, 


GAN. 


GAN. 






GAN. 






GAM. 






SDW. 






SDW. 






BPC. 






GAN, 


SDW. 




SD*. 






SDW. 






ABB. 






LIL. 






ABB, 


GAN. 




ABB, 


BPC, 


GAN. 


BPC, 


GAN, 


UAL. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



-Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 966— Continued 



•Central depressants and stimulants — Continued 
»Barbitur ates — Continued 

»Phenobarbital, sodium 

Secobarbital 

Secobarbital, sodium 

Talbutal 

Thiamylal, sodium 

Thiopental, sodium 

Vinbarbital 

»Hydrooodone bitartrate 

»Salioylates: 

Aluminum aspirin 

•Aspirin 

Ethyl salicylate carbonate 

Phenyl salicylate 

Potassium salicylate 

Salioylamide 

Salicylsallcyllo acid 

Sodium salicylate 

Strontium salicylate 

•Skeletal muscle relaxants: 

Carisoprodol 

Chlorphenesin carbamate 

Chlorzoxazone 

Mephenesin 

Phenaglycodol 

Styramate 

Succinylcholine chloride 

Tubocurarine 

•Tranquilizers: 

*Meprobamate 

•Phenothiazine derivatives: 

Carphenazine maleate 

Chlorpromazine hydrochloride 

Fluphenazine hydrochloride 

lifepazine hydrochloride 

Perphenazine 

Prochlorperazine maleate 

Promazine hydrochloride 

Promethazine hydrochloride 

Trifluoperazine hydrochloride 

Triflupromazine hydrochloride 

»Other tranquilizers: 

Azacyolonol hydrochloride 

Buclizine hydrochloride 

Chlordiazepoxide hydrochloride 

Chlormezanone 

Chlorprothixene 

Diazepam 

Ethomoxane hydrochloride 

Hydroxyphenamate 

Hydroxyzine hydrochloride 

Hydroxyzine pamoate 

Mebutamate 

Methaqualone 

Jfethaqualone hydrochloride 

Oxazepam 

lybamate 

•Other central depressants and stimulants: 

Analgesics and antipyretics (except salicylates) 

Acetaminophen 

Acetanllide 

p-Aminobenzoic acid and salts: 

Aminobenzoic acid 

Calcium aminobenzoate 

Magnesium aminobenzoate 

Potassium aminobenzoate 

Sodium aminobenzoate 

Anlleridine hydrochloride 

Aurothlogluoose 

Calcium succinate 

Colchicine 



CAN, MAL, SDW. 

GAN. 

GAN, LIL. 

SEW. 

PD. 

ABB. 



ABB, PYL, SCH. 

CFC, DOW, MLS, HON, NOR, SDG. 



DOW, 


MAL. 


HN, 


'EN. 


CFC, 




TNC. 




DOW, 


HN. 


TNC. 




X. 




X. 




OTC. 




HEX, 


OMS. 


LIL. 




ARP. 




ABB, 


BUR, SDW. 


ABB, 


QMS. 


ABB, 


BKL, PEN. 


WYT. 




SK. 




QMS. 


SCH. 


NEP. 




SCH. 




SK. 




WYT. 




WYT. 




SK. 




OMS. 




BKC. 




PFZ. 




HOF, 




SOU. 




HOF. 




HOF. 




LIL. 




ARA, 


ARP. 


PFZ. 




PFZ. 




X. 




HEX, 


X. 


BPC. 




WYT. 




PEN, 


X. 


ATP, 


MLS, NEP, 


CTN. 




LEM. 




GAN, 


LEM. 


LEM. 




GAN, 


LOJ. 


GAN, 


LEU. 


MRK. 





MEDICINAL CHEMICALS 



TABLE IZB.— Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufjcturer, i 566— Continued 



Manufacturers' identification codes 
(according to list In table 22) 



•Central depressants and stimulants — Continued 

•Other central depressants and stimulants — Continued 
Analgesics and antipyretics (except 
sali cy lates ) — Continued 

Ethoheptazine citrate 

Indomethaoin 

Meperidine hydroctiloride 

Oxycodone hydrochloride 

Qxymorphone hydrochloride 

Oxyphenbutazone 

Pentazocine 

Phenacetin 

Phenylbutazone 

Phenyramldol hydrochloride 

Propoxyphene hydrochloride 

Propoxyphene napsylate 

Anesthetics: 

Tribrcmoethanol 

Vinyl ether 

Antitussives: 

Benzonatate 

Carbetapentane citrate 

Dextromethorphan hydrobromide 

Dimethoxanate hydrochloride 

Ethylmorphlne hydrochloride 

Stimulants : 

Benzphetamine hydrochloride 

Caffeine: 

Natural 

Synthetic - — 

Caffeine, citrated — 

Caffeine sodium benzoate 

Chlorphentermine hydrochloride 

Dlethylpropion hydrochloride 

Nikethamide — 

Phendimetrazine 

Phenmetrazine hydrochloride 

Phentermine 

•Dermatological agents: 

•Allantoin 

Aluminum phenols\ilfonate 

Ammonium phenolsulfonate 

•Bismuth subgallate 

Dipropylene glycol salicylate 

Glycol salicylate 

Homomenthyl salicylate 

Menthyl salicylate 

p-Uethoxycinnamlc acid, 2-ethoxyethyl ester 

Podophyllum resin 

•Salicylic acld^ - 

Scarlet red 

Sodium phenolsulfonate 

Zinc phenolsulfonate 

•Expectorants and mucolytic agents: 

Ethylenedi amine dihydriodide 

•Gualaool and its derivatives: 

Glyceryl gualacolate 

Guaiacol 

Potassium gualacolsulfonate 

lodinated glycerol 

lodobrassid 

Lobeline sulfate 

Terpin hydrate 

Thonzoniujn bromide 

•Gastrointestinal agents: 

•Choleretics and hydrocholeretios: 

Bile aoide, oxidized 

Dehydrooholic acid 

Florantyrone 

Iron bile salts 

See footnotes at end of table. 



MRK. 
sun, WYT. 



GGY. 
SOU. 
MON. 
GGY. 
OTC. 
UL. 
LIL. 

SDW. 

MRK. 

CBP. 
PFZ. 
HOP. 



GNF, M3fW. 
PFZ. 

MAL, MRK. 
MAL. 
NEP. 
BKC, x. 
CBP, PYL. 



GGY. 



CTN, 


FIN 


HFT. 


MAL. 






SAL. 






BKC, 


MAL, 


PEN. 


SBC. 






RDA. 






ICO. 






CFC. 






GIV. 






ABB, 


PEN. 




DOW, 


HN, 


ffiN, SDH. 


NAC. 






MAL, 


SAL. 




MAL. 






CLV, 


PYL, 


WHL. 


BKL, 


GAN, 


ICO, X. 


MON. 






HN. 






X, X 






CBP. 






ABB. 






LEM, 


PEN. 




NEP. 






SRL, 


WIL. 




WIL. 






SRL. 






LIL. 







SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 566— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



•Gastrointeetinal agentB--Continued 

•Choleretics and hydrocholeretics — Continued 

Ox bile extract 

Sodium dehydrocholate 

Tooair$>hyl 

•Choline salts: 

Choline bicarbonate 

Choline bitartrate 

•Choline chloride (all grades): 

Feed grade 

Medicinal grade 

Technical grade 

Choline citrate (Trichollne citrate) 

Choline dihydrogen citrate 

•Methionine and its hydroxy analogue: 

Methionine (feed grade) 

Methionine (medicinal grade) 

Methionine, hydroxy analogue, calcium salt- 
•Other gastrointestinal agents: 

Betaine base 

Betaine hydrate 

Betaine hydrochloride 

Calcium polycarbophil 

Dihydroxy aluminum aminoacetate 

Magnesium citrate 

Pectin— 

Phenolphthalein * 

Fhenolphthalein, yellow 

Polycarbophil 

Sitosterols 

Sodium tartrate 

•Hormones and synthetic substitutes: 
•Antithyroid agents: 

Methimazol 

Propylthiouracil 

Thiouracll 

•Estrogens: 

Chlorotrianisene 

Dienestrol dlacetate 

Dlethylstilbestrol - 

Diethylstilbestrol dlproplonate 

Natural estrogenic substances 

Piperazine estrone sulfate 

•Prednisone 

•Synthetic hypoglycemic agents: 

Aoetohexamide 

Chlorpropamide 

Phenformin hydrochloride 

Tolazamide 

Tolbutamide 

•Other hormones and synthetic substitutes: 

Androgen: Fluoxymesterone 

Corticosteroids: 

Betamethasone 

Betamethasone acetate 

Betamethasone phosphate 

Cortisone acetate 

Dexamethasone 

Dexamethasone acetate 

Dexamethasone phosphate 

Dichlorisone acetate 

Fludrocortisone acetate 

Fluorometholone 

Fluprednlsolone 

Hydrocortisone 

l^drooortisone acetate 

Hydrocortisone phosphate 

Methylprednlsolone 

Prednisolone 

Prednisolone acetate 

Triamcinolone 



ABB. 
WIL. 




COM. 
ACY, 


HFT. 


COM, 
HFT. 
GAF, 
ACY, 
ACY, 


DLI, HFT, TMH 

RH. 
HFT. 
HFT. 


DOW, 
DOW, 
DUP, 


LEM- 
MON. 


HFT, 
HFT. 
HFT, 


UAL. 
TNC. 


CHT. 




SKG. 
MON. 




WLI. 
UP J. 
MAL. 




LIL. 
PYL. 
ACY. 




BKC. 
SCH. 
CTN, 
CTN. 
ORG. 
ABB. 
MRK, 


LIL. 
SCH, UPJ. 


LIL. 
PFZ. 





SCH. 




MRK, 


SCH, UPJ 


MRK, 


SCH. 


SCH. 




MRK. 




SCH. 




DPJ. 




UPJ. 




UPJ. 




MRK, 


UPJ. 


MRK, 


UPJ. 


UPJ. 




MRK, 


UPJ. 


SCH, 


UPJ. 


ACY, 


QMS. 



MEDICINAL CHEMICALS 



TABLE 133. --Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 966— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



«Hormones and synthetic substitutes--Continued 

»Other hormones and synthetic substitutes — Continued 
Progestogens: 

Medroxyprogesterone acetate 

Progesterone 

All other: 

Corticotropin (ACTH) (pituitary) 

Insulin (pancreas) 

»Renal- acting and edema- reducing agents: 
•Mercurial diuretics: 

Meralluride 

Mersalyl acid—- - - 

Sodium mercaptomerin 

Sodium mercurophylline 

•Theobranlne and theophylline derivatives: 

Ambuphylllne 

»Aminophylline 

Aminophylline sodium biphosphate 

Oxtriphylline 

Theobromine sodium acetate 

Theobromine sodium salicylate 

Theophylline magnesium 

Theophylline monoethanolamlne 

Theophylline piperazine ethanoate 

Theophylline sodium glyclnate 

♦Other renal- acting and edema- reducing agents: 

Acetazolamlde 

Benzothiadiazlne derivatives: 

Benz thiazide 

Chlorothiazide 

Flume thiazide 

Hydrochlorothiazide 

Hydroflumethiazide 

Methyclothiazide- - - — ■ 

Polythiazlde 

Trichlormethiazide 

Chlorthalidone 

Diohlorphenamide 

Probenecid 

Spironolactone 

Triamterene 

♦Therapeutic nutrients: 
♦Amino acids and salts: 

Acetyltryptophane 

Aminoacetic acid (glycine)^ 

Amino acid mixtures 

Arglnine glutamate 

Aspartlc acid and salts: 

Aspartic acid 

Magnesium aspartate 

Potassium aspartate 

Beta- alanine 

Glutamic acid and salts: 

Ammonium glutamate 

Calcium glutamate 

♦Glutamic acid 

Glutamic acid hydrochloride 

♦Potassium glutamate 

I^ysine (feed grade) 

lysine hydrochloride 

Phenylalanine 

d-Direonine 

Tryptophane 

♦Calcium gluconate 

♦Other therapeutic nutrients: 

Calcium glucoheptonate 

Calcium lactophosphate 

Calcium levultnate 

Calcium phytate---- 

Copper gluconate 

See footnotes at end of table. 



GAN. 

GAN, LEM, SRL. 

GAN. 

NEP. 

MAL. 

CLC. 

MAL. 

LIL. 

SEL. 

CHT. 

ACY. 

PFZ. 
MRK. 



SOU. 

BPC, DOW. 
ABB, CUT, STA. 
ABB. 

HEX, NAC. 



IMC, 


LEM, 


PFZ 


IMC, 


LEM. 




IMC, 


LEM, 


PFZ 


MRK. 






MRK. 






SEW. 






SIM. 






SDW. 






MAL, 


PFZ, 


WHL 


PFN. 






MAL. 






pn,, 


SEL. 




STA. 






PFZ. 







SYNTHETIC ORGANIC CHEMICALS, 1966 



■ Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 566— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



^Therapeutic nutrients — Continued 

»Other therapeutic nutrients — Continued 

Ferrous gluconate 

Fructose 

Lecithin 

Liver concentrate 

Liver, desiccated 

Magnesium gluconate 

Manganese gluconate 

Potassium gluconate 

Sodium glycerophosphate 

» Vitamins: 
»Vitamin A alcohol and esters: 

Vitamin A acetate (feed grade) 

Vitamin A acetate (medicinal grade) 

Vitamin A alcohol 

Vitamin A natural esters 

♦Vitamin A palmitate (feed grade) 

Vitamin A palmitate (medicinal grade) 

»Vitamin B-complex: 

*Cyanocobalamln (except U.S. P. crystalline): 

Feed grade 

Medicinal grade 

♦Niacin: 

Feed grade 

Medicinal grade 

♦Niacinamide 

♦Pantothenic acid and derivatives: 

Calcium pantothenate (dextro) 

♦Calcium pantothenate (racemic) (feed grade) 

Calcium pantothenate (racemic) (medicinal grade). 
Calcium pantothenate (racemic) - csilcium 
chloride complex. 

Dexpanthenol 

Panthenol (racemic) 

Sodium pantothenate 

♦Riboflavin: 

Feed grade 

Medicinal grade 

♦Other B-complex vitamins: 

Biotin - - - 

Cyanocobalamin (U.S.?. crystalline) 

Cyanooobalamin with intrinsic factor concentrate- 

Folic acid 

Inositol 

Magnesium nicotinate 

Niacinamide hydrochloride 

Pyridoxine 

Riboflavin-5-phosphate, sodium 

Sodiiim nicotinate 

Thiamine hydrochloride 

Thiamine mononitrate 

♦Vitamin C: 

♦Ascorbic acid 

Ascorbyl palmitate 

Calcium ascorbate 

Sodium ascorbate 

♦Vitamin E: 

d- Alpha tocopherol 

dl -Alpha tocopherol 

d-Alpha tocopheryl acetate 

dl-Alpha tocopheryl acetate (feed grade) 

dl-Alpha tocopheryl acetate (medicinal grade) 

d-Alpha tocopheryl acid succinate 

dl-Alpha tocopheryl acid succinate 

♦Vitamin K: 

Menadione 

Menadione sodium bisulfite 

Phytonadione 



PFZ 


SDW 




DLI 


PFN 




ARP. 






WIL. 






WIL. 






PFZ. 






PFZ. 






PFZ. 






SEL. 






HOF. 






HOF 


PFZ 




CW, 


HOF. 




CW. 






EK, 


HOF, 


PFZ. 


EK, 


HOF, 


PFZ. 


GPR, 


MRK 


PMP 


IMC, 


MRK 





ABB, CKL, MRK, NEP, RIL. 
MRK, NOP, RIL, SCR. 
MRK, NEP. PD, RIL, SCR. 



MRK, x. 






CKL, DLI, 


HFT 


NOP 


NOP. 






CKL, HFT, 


NOP. 




HOF. 






HOF. 






PD. 






COM, GPR, 


HOF, 


MRK 


HOF, MRK. 






HOF. 






MRK. 






WIL. 






ACY. 






STA. 






NEP. 






NEP. 






HOF, MRK. 






HOF. 






NEP. 






HOF, MRK. 






HOF, MRK. 






HOF, MRK, 


PFZ. 




PFZ. 






PFZ. 






HOF, MRK, 


PFZ. 




CW, EK. 






HOF. 






CW, EK. 






HOF. 






HOF. 






CW, EK. 






HOF. 






ABB, HET, 


HFT, 


WHL. 


ABB, HET, 


HFT, 


WHL. 



MEDICINAL CHEMICALS 



TABLE 13B.— Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i566~Continued 



Manufacturers' Identification codes 
(according to list in table 22) 



» Vitamins — Continued 
»Other vitamins: 

Beta-carotene (Provitamin A) 

Cholecalciferol (Vitamin D3) - 

Ergocalciferol (Vitamin Dj) 

•Miscellaneous medicinal chemicals: 
Diagnostic agents: 

Roentgenographic contrast media: 

Acetrizoate, sodium 

Diatrizoate, meglumine 

Diatrizoate, sodium 

Diprotrizoate, sodium 

lodihippurate, sodium 

lodopyracet 

lopanoic acid 

lophendylate 

lothalamate, meglumine 

lothalamate, sodium 

Methiodal, sodium 

Other diagnostic agents: 

Galactose (liver function test) 

Indocyanine green (cardiac output test)- 

Metyrapone (pituitary function test) 

Hematological agents (except anticoagulants) 

Aminocaproic acid 

Cellulose, oxidized 

Dextran (plasma expander) 

anooth muscle relaxants: 

Alverlne 

Alverine citrate 

Alverlne hydrochloride 

Papaverine hydrochloride 

Sodium benzyl succinate 

Unclassified medicinal chemicals: 

Berberine hydrochloride 

Hydrastine 

Hydrastine hydrochloride 

Penicillamine (copper chelating agent) 



sm. 

MAL. 
MAL. 
SDW. 
SEW. 



■"■ See table 7B for producers of the technical grade. 
^ See table 21B for producers of the technical grade 



130 



SYNTHETIC ORGANIC CHEMICALS, 1966 



Flavor and Perfume Materials 



TABLE 14B. -- Flavor and perfume materials for which U.S. production or sales were reported, identified by 
manufacturer, 1966 

[Flavor and perfijme materials for which separate statistics are given in table 14A are marked below with an asterisk 
(»); those not so marked do not appear in table KA because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 22) 



FLAVOR AND PEHFUME MATERIALS, CYCLIC 



Benz 



and Naphthale 



2'-Acetonaphthone (Methyl p-naphthyl ketone) 

Acetophenone 

7-Acetyl-6-ethyl-l,l,4,^-tetramethyl-l,2,3,<;-tetra- 
hydronaphthalene . 

p-Allylanlsole 

»4-Allyl-2-methoxyphenol (Eugenol) 

Allyl phenoxyacetate 

4-Allylveratrole (Eugenyl methyl ether) 

*Anethole (p-Propenylanisole) 

♦p-Anisaldehyde (p-Methoxybenzaldehyde) 

Anlsole (Methyl phenyl ether) 

Anisyl acetate 

Anisyl alcohol 

*Benzophenone 

»Benzyl acetate 

"Benzyl alcohol 

Benzyl benzoate 

»Benzyl butyrate 

*Benzyl clnnamate 

"Benzyl ether 

Benzyl formate 

Benzyl glyceryl aoetal 

Benzyl isobutyrate 

Benzyl isopentyl ether 

1- ( Benzyloxy ) -2-methoxy-A-propenylbenzene ( Benzyl 
isoeugenyl ether). 

"Benzyl phenylacetate (Benzyl a-toluate) 

"Benzyl propionate 

"Benzyl salicylate 

a-Bromostyrene 

A '-tert-Butyl-2 ', 6 '-dimethyl-3 ', 5 '-dinltroaoeto- 

phenone (Musk ketone). 
6-tert-Butyl-3-methyl-2,4-dinitroanisole (Mjsk ambrette)- 
p-tert-Butyl-a-methylhydrocinnamaldehyde ( a-Methyl- 

p- ( p-tert-butylphenyl) proplonaldehyde ) . 
5-tert-Butyl-l,2,3-trljnethyl-'i,6-dinltrobenzene (5-tert- 
Butyl-A, 6-dinitrohemlmellitene) . 

5-tert-Butyl-2,'4,6-trlnitro-m-xylene (Miek xylol) 

Carvacrol (2-p-Cymenol) 

"Cinn am aldehyde 

Cinnamic acid 

"Cinnamyl acetate 

"Cinnamyl alcohol 

Cinnamyl anthranilate 

Cinnamyl cinnamate 

Cinnamyl formate 

Cinnamyl isovalerate 

Cinnamyl propionate 

trans-Decahydro-2-naphthol 

Dihydronordlcyclopentadienyl acetate 

p,a-Dimethylbenzyl alcohol (p-Methylphenylmethyl- 
carbinol) . 

Dimethylhydroquinone 

a,a-Dimethylphenethyl acetate (DMBCA) - 

a,a-Dlinethylphenethyl alcohol (DMBC) 

4,6-Dinltro-l,l,3,3,5-pentamethylindane 

Diphenylme thane 

l,3-Diphenyl-2-propanone (Dibenzyl ketone) 

l-Ethoxy-2-hydroxy-'i-propenylbenzene ( Propenyl-guaethol; 
6-ethoxy-m-anol) . 



GIV, TBK. 






GIV, TBK. 






GIV, TBK. 






GIV. 






FB, GIV, ICO, 


IFF, 


LUE, 


GIV. 






GIV, TBK. 






MiZ, FB, GLD, 


HNW, 


HPC. 


GIV, OPC, SHL, 


TBK, 


UNG. 


GIV. 






GIV, TBK. 






GIV, TBK. 






QAF, GIV, ICO, 


NEO, 


TBK. 


GIV, IFF, OPC, 


SHL, 


TBK, 


BPC, OPC, SHL, 


TBK, 


VEL. 


MON, OPC, TBK, 


VEL. 




FB, GIV, TBK. 






FB, GIV, ICO, 


TBK. 




OPC, SHL, VEL. 






GIV, TBK. 






GIV. 






TBK. 






GIV. 






GIV, TBK. 






GIV, m, TBK 






FB, GIV, TBK. 






GIV, OPC, TBK, 


UNG. 




TBK. 






GIV. 






GIV. 






GIV. 






GIV. 






GIV. 






GIV. 






FB, OPC, TBK, 






BPC. 






FB, GIV, TBK. 






FB, GIV, NEC, 


TBK, 




FEL, RT. 






TBK. 






TBK. 






TBK. 






GIV, TBK. 






IFF. 






GIV. 






GIV. 






ICO. 






GIV, IFF, RDA 






GIV, IFF. 






GIV. 






ARA, TBK, 






GIV. 






SHL. 







I, TBK, UNG, VLY. 



FLAVOR AND PERFUME MATERIALS 



-Flavor and perfume materials for which U.S. productior 
mnnufacturer, i 566- -Continued 



or sales were reported, identified by 



Manufacturers' Identification codes 
(according to list in table 22) 



FUVOR AND PERFUME MATERIALS, CYCLIC— Continued 

Benzenoid and Naphthalenoid- -Continxied 

»2-Ethoxynaphthalene (Ethyl |i-naphthyl ether) 

Ethyl anthranilate ■ 

Ethyl benzoate 

Ethyl cinnamate 

Ethyl a, P-epoxy-P-methylhydrocinnamate (Ethyl 
methylphenylglyoidate) . 

Ethyl eugenol 

2-Ethylhexyl salicylate 

Ethyl phenylacetate 

Ethyl 3-phenylglycidate— - -- 

Ethyl salicylate 

Ethylvanillin - - 

Eugenol acetate 

a-Hexylcinnamaldehyde 

Ifydratropaldehyde (a-Phenylproplonaldehyde) 

Hydratropaldehyde, dimethyl aoetal 

Hydroxycitronellal methyl anthranilate 

2-Hydroxypropyl p-N,N-bis(2-hydroxypropyl)amino- 
benzoate. 

Isobutyl cinnamate 

»Isobutyl phenylacetate (Isobutyl a-toluate) 

»Isobutyl salicylate 

Isoeugenyl acetate 

»Isopentyl salicylate (Isoamyl salicylate) 

p-Isopropylbenzaldehyde (Cumaldehyde) 

p-Isopropylcyclohexanol 

p- Isopropyl-a-methylhydrocinnamaldehyde ( Cyclamen 
aldehyde). 

p-Isopropyl-a-methylhydrocinnamyl alcohol 

»A '-Jfethoxyacetophenone 

2-Methoxynaphthalene (Methyl P-naphthyl ether)— 

Ifethoxyphenyl butanone 

l-(p-Jfethoxyphenyl)-l-pentene-3-one 

•2-Jfethoxy-4-propenylphenol ( Isoeugenol) 

-i'-Methylacetophenone (Ifethyl p-tolyl ketone) 

Jfcthyl anisate — 

*p-Methylanisole (p-Cresyl methyl ether) 

»Methyl anthranilate 

Methylanthanilydene p-isopropyl methylhydrocinnamal- 
dehyde. 

Methyl benzoate 

a-Methylbenzyl acetate (Styralyl acetate) 

p-Methylbenzyl acetate 

a-Methylbenzyl alcohol 

»a-Methylclnnamaldehyde 

»lfethyl cinnamate 

Msthyl eugenol 

p-tfethyl hydratropic aldehyde 

Methyl N-methylanthranilate (Dimethyl anthranilate)— 

Methyl phenylacetate (Methyl a-toluate)- 

2-»fcthyl-4-phenyl-2-butanol(a,ix-Dlmethyl-3-phenyl- 
1-propanol) . 

»Methyl salicylate (Synthetic wintergreen oil) 

»a-Pentyloinnamaldehyde (a-Amylcinnamaldehyde) 

Phenethyl acetate 

Phenethyl alcohol 

Phenethyl formate 

»Phenethyl isobutyrate 

Phenethyl isovalerate 

•Phenethyl phenylacetate (Phenethyl a-toluate) 

»Phenethyl propionate 

Phenethyl salicylate 

2-Phenoxyethyl isobutyrate 

Phenylaoetaldehyde (a-Tolualdehyde) 

Phenylacetaldehyde, dimethyl acetal 

o-Phenylanisole (2-Methoxybiphenyl) 

4-Phenyl-3-buten-2-one (Benzylidene acetone) 

Phenylethyl acetal 



GIV 


ICO 


TBK 




FB. 








TBK 








GIV 


TBK 






GIV, 


TBK 






ICO 








ICO 








GIV 








GIV 


TBK. 






FB, 


TBK. 






MON 


RDA. 






GIV. 








GIV 


IFF, 


TBK 




GIV 


IFF. 






GIV, 


IFF. 






GIV. 








SHL. 








TBK. 








FB, 


GIV, 


OPC, 


TBK. 


FB, 


GIV, 


TBK. 




TBK. 








FB, 


GIV, 


OPC, 


TBK. 


GIV. 








GIV. 








GIV, 


RDA. 






GIV. 








GIV, 


ICO, 


OPC 


TBK. 


GIV, 


TBK. 






TBK. 








GIV. 








GIV, 


SHL, 


TBK 


VLY. 


OPC, 


TBK. 






ICO. 








GIV, 


TBK, 


VLY 




DOW, 


FB, 


GIV, 


MEE, OPC, SHL, UNO 


HDA. 








HN. 








GIV, 


TBK, 


VLY. 




IFF. 








UCC. 








FB, 


GIV, 


TBK, 


VLY. 


FB, 


ICO, 


TBK. 




ICO. 








GIV. 








GIV, 


OPC. 






GIV, 


TBK. 






IFF. 








CFC, 


DOW, 


HN, 


MON, PEN. 


FB, 


GIV, 


IFF, 


NEO, RDA, TBK, VLY 


GIV, 


IFF. 






orv. 


IFF, 


OPC 




IFF, 


TBK. 






GIV, 


IFF, 


TBK 




FB, 


GIV. 






FB, 


GIV, 


IFF, 


TBK. 


GIV, 


IFF, 


TBK. 




GIV, 


TBK. 






GIV, 


IFF, 


TBK. 




GIV, 


TBK. 






GIV, 


TBK. 






GIV. 









SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 14B. 



-Flavor and perfume materials for which U.S. production or sales were reported, identified by 
manufacturer, 7566--Continued 



Manufacturers' identification code 
(according to list in table 22) 



FLAVOR AND PERFTME MATERIALS, CYCLIC— Continued 
Brnzenoid and Naphthalenoid--Continued 



Phenylethyl tiglate 

«3- Phenyl- 1-propanol (Hydrocinnamic alcohol) 

3- Phenyl- l-propyl acetate ( Hydrocinnamy 1 acetate) - 
Phenyl propyl cinnamate 

»4-Propenylveratrole (Isoeugenyl methyl ether) 

p-Propylanisole 

p-Tolualdehyde (p-Methylbenzaldehyde) 

p-Tolylacetaldehyde 

»p-Tolyl acetate (p-Cresyl acetate) 

p-Tolyl isobutyrate (p-Cresyl isobutyrate) 

p-Tolyl phenylacetate (p-Cresyl a-toluate) 

«a-(Trichloromethyl) benzyl acetate (Rosetone) 

p-a, a-Trimethylphenethyl alcohol 

Trimethyltetrahydrobenzylidene acetone 

Vanillin- — 

All other — 



Terpenoid. Heterocyclic, and Alicycl 



Allyl cyclanexyl propionate 

Allyl ionone 

p-tert-Amylcyclohexanone 

Amyris acetate 

Bomyl acetate 

<;-tert-Butylcyclohexanol 

'i-tert-Butylcyclohexanone 

i-tert-Butyloyolohexyl acetate 

Cadinene 

Carvone (Carvol) 

P-Caryophyllene 

Cedarwood acetate 

Cedranone 

Cedrenol 

Cedrol 

»Cedryl acetate 

•Citral a (Geranial) 

Citral dimethyl acetal 

Citronellal 

»Citronellol 

•Citronellyl acetate 

Citronellyl butyrate 

»Citronellyl formate 

Citronellyl isobutyrate 

Citronellyl oxyacetaldehyde 

Citronellyl propionate 

*Couiiiarin-" --_--._-- .......... 

Cyolohexylcyclohexanone 

(^clopentanone 

Dlhydroterpinyl acetate 

"Essential oils, chemically modified: 

Acetyl cedrene 

Citronella oil, acetylated 

Clove leaf oil terpenes 

Ethyl oxyhydrate 

Quaiacwood acetate 

Lavandin, acetylated 

Oil clove stem, acetylated 

Santalol 

Sassafras oil, hydrogeuated 

a-Furfural mercaptan 

»Geranlol 

Geranoxy acetaldehyde 

»C3eranyl acetate 

Geranyl benzoate 

Geranyl butyrate 

"Qerauyl formate 

Geranyl isobutyrate 



FB. 




FB, GIV, TBK. 




FB, GIV, TBK. 




FB. 




GIV, ICO, TBK. 




GIV. 




GIV, HN. 




GIV. 




GIV, ICO, IFF, TBK. 




IFF. 




GIV. 




ICO, NEO, TBK. 




IFF. 




TBK. 




MON, SLV. 




FB, GIV, IFF, PFW, SHL. 




GIV. 




GIV, IFF. 




IFF. 




GIV. 




FEL. 




IFF. 




DOW. 




DOW, IFF. 




FB. 




FB, FRM, OPC. 




FB, GIV. 




FB. 




TBK. 




GIV. 




GIV, IFF, OPC, TBK. 




GIV, IFF, NEO, TBK, UNG 




FB, FEL, GIV, HOF, LUE, 


NEO, RT, TBK. 


GIV. 




FB, GIV, IFF, TBK. 




FB, GIV, GLD, IFF, NEO, 


TBK, VLY. 


GIV, IFF, TBK, VLY. 




GIV, TBK. 




GIV, IFF, TBK, VLY. 




GIV, TBK. 




IFF. 




IFF. 




DOW, MON, NEO, RDA, TBK 




GIV. 




ARA. 




GIV. 




GIV, IFF. 




CP, RT. 




SHL. 




FEL, FLO, LUE, VND. 




FB, GIV, TBK. 




FEL, GIV, UNG. 




FB. 




GIV, IFF, VLY. 




GIV. 




RT. 




FB, FEL, GIV, GLD, IFF, 


NEO, TBK, UNO 


IFF. 




FEL, GIV, IFF, NEO, TBK 


VLY. 


QIV. 




GIV, TBK. 




GIV, IFF, TBK, VLY. 




IFF. 





FLAVOR AND PERFUME MATERIALS 



TABLE 14B. 



-Flavor and perfume materials for which U.S. production or sales were reported, identified by 
manufacturer, i966--Contmued 



Manufacturers' identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued 

Terpenoid, Heterocyclic, and Alicyclic--Contimied 

Geranyl isovalerate 

Oeranyl phenylaoetate (Geranyl a-toluate) 

Geranyl tiglate 

Hexadecanollde 

2-Hexyl-2-cyclopenten-l-one 

Ifydrocoumarin (Sj-i-Dihydrocoumarin) 

»f^droxycltronellal 

•ffydroxycltronellal, dimethyl acetal 

2-Hydroxy-3-methyl-2-cyclopenten-l-nno (Methyl 

cyclopentenolone) . 
■4-(<C-l^roxy-4-methylpentyl)-3-cyclohexene-l- 
arbox aldehyde . 

3-Hydroxy-2-methyl-"i-pyrone (Maltol) 

Indole 

»lonones: 

a-Ionone 

P-Ionone 

lonone (a- and P-) 

Isobomeol (Isobomyl alcohol) 

»lEobornyl acetate 

Isobomyl methoxycyclohexanol 

2-lBObutylquinoUne (a-Isobutylqulnollne) 

lEcmenthone 

6-Isopropylquinoline (p-Isopropylquinollne) 

Isopulegol 

Isosafrole 

Laevo carveol 

d-Limonene 

Linalool (Linalyl alcohol) 

Linalyl acetate 

Linalyl anthranilate 

Linalyl isobutyrate 

Linalyl propionate 

Jfenthadlene-7-carbinol 

1, l-p-Menthen-6-yl-l-propanone 

•Menthol, synthetic: 

Tech 

U.S.P - 

»Menthone 

Menthyl acetate 

6-lfethylcoumarln 

•Uethylionones: 

6-Methyl-a-ionone 

6-Mb thy 1-P-ionone 

Methylionone (a- and P-) 

Methyl ionone standard 

4-Methyl-2-(2'-methyl-l-propan-l-yl)-tetrahydropyran-' 

»Nerol 

Neryl acetate prime 

Nopyl acetate 

Onega decenol (Hosalva) 

ci-Phellandrene 

•Piperonal (Hellotropln) 

Piperonal, sodium bisulfite con^lex 

Piperonal terpenes 

Pseudolinalyl acetate (J^cenyl acetate, principally)- 

•Hhodinol 

Rhodlnyl acetate 

Safrole 

«S»eeteners, synthetic: 

Cyclohexanesulfamio acid 

Cyolohexanesulfamic acid, calcium salt 

Cyclohexanesulfamic acid, sodium salt 

Saccharin 

Saccharin, calcium salt 

Saccharin, sodium salt 

All other — — - 



GIV, TBK. 






FB. 






IFF. 






IFF. 






GIV, TBK. 






GIV, GLD, IFF, OPC 


TBK 


VLY. 


FB, GIV, IFF, TBK. 






DOW, 






IFF. 






DOW, PFZ. 






GIV, LUE. 






GIV, IFF, MYW, NEO 


TBK 




HOF, MYW, TBK. 






GIV, LUE, MYW, TBK 


UNG 




RDA. 






FB, GIV, OPC, RDA, 


TBK, 


UNG. 


IFF. 






IFF. 






GIV, TBK. 






FMT. 






GIV. 






GIV. 






FB. 






RT, SKG. 






FB, FEL, GIV, GLD, 


HOF, 


LUE, 


FB, GIV, GLD, HOF, 


LUE, 


NEO, 


FMP. 






HOF, TBK. 






FB, GIV, HOF. 






RT. ■ 






GIV. 






GIV, ICO, NEO. 






GIV, GLD, HNW, NEO 






GIV, HNW, NEO, OPC 






FB, GIV. 






GIV. 






GIV, IFF, im. 






NEO, TBK. 






GIV, LUE, MYW, TBK 






TBK. 






GIV. 






FB, GLD, IFF, TBK, 


VI-Y. 




GIV. 






SHL, VLY. 






IFF. 






ICO. 






GIV, SHL, TBK. 






SHL. 






SHL. 






IFF. 






FB, FEL, GIV, IFF, 


LUE, 


NEO, 


FB, GIV, IFF. 






GIV, OPC. 







ABB. 

ABB, CYC, DRW, MDN, NHS, PBY, PFZ, UliS. 

ABB, DRW, MON, NRS, PBY, PFZ, UNS. 

MEE, UDU, NRS. 

MEE, MON, NRS, PBY. 

MEE, KDN, NRS. 

GIV 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 14B. --Flavor and perfume materials for which U.S. production or sales were reported, identified by 
manufacturer, i566- -Continued 



FLAVOR AMD PERFUME MATERIALS, CYCLIC— Continued 



Terpenoid, 



cycli 



and Ali 



«Terpineols: 

a-Terpineol 

P-Terpineol 

Terpineol (a- and P-) 

Terpinol hydrate (Terpin hydrate), teoh- 

»a-Terpinyl acetate 

a-Terpinyl propionate 

Tetrahydro alloocimenol 

Tetramethy lethy lacety Itetralin 

3,5,5-Trimethyloyclohexanol 

Vetlvenol 

»Vetivenyl acetate 

All other 



FLAVOR AND PERFUME MATERIALS, ACYCLIC 



Manuf aoturere ' identification codes 
(according to list in table 22) 



HFC. 
MEG. 



RDA, TBK, UNO. 



TBK. 
GIV, IFF, NEO, TBK. 
IFF. 



Acetyl propionyl 

Allyl heptanoate (Allyl enanthate) 

»Allyl hexanoate (Allyl eaproate) 

Allyl Isothiooyanate (Synthetic mustard oil) 

Allyl mercaptan 

Allyl sulfide (Diallyl sulfide) 

Amyl propionate 

Brazinol r 

Butyl butyrate 

Butyl butyryl lactate 

Butyl isovalerate 

Butyl undeoylenate 

Decanal (Capr aldehyde) (Cio) 

Diethyl sebacate (Ethyl sebaoate) • 

Diethyl succinate 

2,6-Dlmethyl-5-hepten-l-al 

3,6-Dimethyl-3-octanol 

3,7-Dimethyl-l-octanol 

3,7-Dimethyl-3-ootanol 

Dimethyl succinate 

Dodecyl acetate (Lauiyl acetate) 

Ethylamyl ketone 

»Ethyl butyrate 

Ethyl caprate 

Ethyl decanoate 

Ethylene brassy late 

Ethylene glycol tridecandiote 

Ethyl formate 

»Ethyl heptanoate (Ethyl enanthate) 

Ethyl hexanoate (Ethyl eaproate) 

Ethyl Isovalerate— 

Ethyl laurate 

Ethyl myrlstate 

Ethyl nonanoate (Ethyl pelargonate) 

Ethyl oetanoate (Ethyl caprylate) 

Ethyl propionate 

•Glutamic acid, monosodium salt (IfcnoBodlum glutamate) 

Heptanal (Enanthaldehyde) (C7) 

4-Heptaiione (Butyrone) (W-n-propyl ketone) 

Heptyl alcohol (1-Heptanol) 

Heptyl ether (Enanthio ether) 

2-Hexenal 

cis-3-Hfixen-l-ol 

Hexyl oetanoate (Hexyl caprylate) 

cis-3-Hexyn-l-ol 

3-Hydroxy-2-butanone (Acetoin) 

4-Hydroxynonanoio acid, y- lactone (y-Nonalaotone) 

-;-Hydroxyootanoie acid, y- lactone (Y-Octalactone) 

««;-l^droxyundeeaiioie acid, y-laotone (Y-Undeealactone) 

iBoamyl propionate 

l8obul7l acetate 



TBK. 

FB, GIV, UNG. 

MRT. 

HT. 

RT. 

GIV. 

RDA. 

TBK. 

ICO. 

TBK. 

GIV. 

GIV, IFF, OPC, TBK. 

FEL, TBK. 

TBK, UCC. 

GIV. 

cue. 

GIV, VLY. 

GIV. 

ICO. 

TBK. 

GIV. 

FB, NW, RT, TBK. 

FB. 

TBK. 

VLY. 

RDA- 

FB. 

FB, FEL, RT, TBK. 

NW, TBK. 
FB. 

TBK. 
GIV, RT. 
GIV, TBK. 
FB, TBK. 
FB. 



GRW, mC, MRK. 



COM, 

BAC. 

TBK. 

BAC, UCC. 

TBK. 

GIV. 

TBK, 

X. 

Fvr. 

GIV, TBK, 

GIV, TBK. 

FB, GIV, TBK. 

FB. 

FB. TBK- 



FLAVOR AND PERFUME MATERIALS 



TABLE 14B. --Flavor and perfume materials for which U.S. production or sales were 
manufacturer, 2 966 --Continued 



sported, identified by 



ManuTacturere ' identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIALS, ACYCLIC— Continued 

»Isopentyl butyrate (Isoamyl butyrate) 

Isopentyl formate (Isoamyl formate) 

Isopentyl heptanoate 

Isopentyl isovalerate (Amyl isovalerate) 

Lauraldehyde (Dodecyl aldehyde) (C12) 

Linalyl butyrate 

Methyl furoate - — 

6-Ktethyl-5-hepten-2-one 

kfethyl-p-methylthlopropionate 

Methyl-2-nonenoate— 

Methjlolmethylhexyl ketone 

3-Methylthlopropionaldehyde 

2-Methylundecanal (2-MethyLnonylacetaldehyde) 

Myristic aldehyde (C14) - 

Nonanal (Pelargonaldehyde) (C,) 

Nonanedlol monoacetate 

Nonanol 

Nonyl acetate 

Octanal (Caprylaldehyde) (Cj) 

n-Octyl formate 

n-Octyl Isobutyrate 

Tepyl acetate 

Trimethyl hexanal, sodium bisulfite complex 

2,6,10-Trimethyl-9-undecen-l-al 

Undecanal (Hendecanaldehyde) (Cii) — 

2-Undecanone (Xtethyl nonyl ketone) 

9-Undecenal (9-Hendecenaldehyde) 

9-Undecen-l-ol (9-Hendecenol) 

10-tIndecen-l-ol 

Valerolactone 



FB, 


GIV, 


NW, RT, TBK 


FEL 


RT, 


TBK. 


FEL. 






FB, 


TBK. 




GIV, 


IFF 


TBK. 


niv. 






FB. 






GIV. 






RT. 






GIV. 






GIV. 






RT. 






GIV, 


TBK. 




GIV, 


IFF. 




GIV, 


TBK. 




GIV. 






TBK. 






GIV. 






GIV, 


IFF. 




FB. 






FB, 


TBK. 




IFF, 


TBK. 




SHL. 






GIV. 






GIV, 


IFF, 


TBK. 


GIV. 






GIV, 


TBK. 




TBK. 






GIV. 






GIV. 







SYNTHETIC ORGANIC CHEMICALS, 1966 



Plastics and Resins Materials 



TABLE 15B. — Plastics and resin materials for which U.S. production or sales were reported, identified by 
manufacturer, 1966 

[Plastics and resin materials for which separate statistics are given in table 15A are marked below with an 
asterisk (*); chemicals not so marked do not appear in table ISA because the reported data are accepted in 
confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. 
An X signifies that the manufacturer did not consent to his identification with the designated product ] 



Manufacturers ' identification codes 
(according to list in table 22) 



THERMOSETTING RESINS 



»AlJ!yd reeins, domestic: 
»Phthalio anhydride type- 



«Coumarone-indene and petroleum polymer resins; 

»Floor tile 

»Rubber compounding 

»A11 other uses (including ejcport) 

Epoxy resins: 

»Unmodified: 

»Bonding and adhesives 

♦Protective coatings 

♦Reinforced plastics 

*A11 other uses (including export) 

♦Modified 



♦Polyester resins: 

Reinforced plastics: 
"Sheets, flat and corrugated 

*AU other 

♦Surface coatings 

♦All other uses (Including export)- 

♦Phenolic and other tar acid resins: 
♦Molding materials 

Bonding and adhesive reslne for: 
♦Laminating 

♦Coated and bonded abrasives 

♦Friction materials 

♦Thermal insulation 

♦Foundry or shell molding 

♦Plywood . 

♦Fibrous and granulated wood 



AAI, ACP, ACY, ADM, AMR, APV, BAl, BEN, BOY, BRU, CEL, 
CIK, CM, COM, CPV, DAV, DEC, DSO, DUN, DUP, EW, FAR, 
FBR, FCD, FLW, FOC, FRE, FSH, GEI, GIL, GLD, GRG, 
GRV, HAN, HPC, HRS, ICF, JOB, JSC, JWL, KEL, KMC, 
KMP, KPS, KYN, MCC, MID, MMM, MNP, MR, NPV, NCI, 
NTL, ORO, QSB, OXR, PER, PFP, PPG, PRT, QCP, RCI, 
RED, REL, RH, SCF, SCN, SED, SIP, SM, SRR, SVC, SW, 
SYV, TV, VTV, WAS. 

ACP, ACY, ADM, APT, APV, BEN, BRU, CGL, CM, COM, CPV, 
DSO, DUN, DUP, EW, FAR, FBR, FCD, FOC, GEI, GIL, 
GLD, GRV, HAN, HPC, HRS, HYC, ICF, KYN, MCC, MID, 
MMM, NCI, NON, NPV, ORO, OSB, PFP, PPG, PRT, RCI, 
RED, RH, SCN, SHA, SM, SRR, SW, TV, VTV. 

ACC, ACP, NEV, NSP, PAI, RCI, VEL. 
ACC, ACP, KPI, NEV, NSP, PAI, RCI, VEL, WTC. 
ACC, ACP, CM, DSO, DUP, ENJ, MCA, MID, NEV, NSP, PAI, 
PPG, RCI, VEL, VSV. 



CBA, CEL, DOW, SHC, UPC. 

CBA, CEL, DOW, RCI, SHC, UCP. 

CBA, CEL, DOW, RCI, SHC, UCP. 

CBA, DOW, RCI, SHC, UCP. 

ACP, ADM, BEN, CM, FMP, FOM, GLD, HAP, IOC, LEF, MID, 

MMM, MNP, MRB, NON, QSB, PI£, PPG, PYR, REZ, SCN, 

SRR, VTV, WAS. 



ACY, APD, DA, EW, GLD, HKD, ICF, LAS, MFG, ORO, PPG, 

RCI, RH, SIC, SW, USR. 
ACP, ACY, ADM, CPV, DA, DSO, FRE, GLD, GNT, GRV, HKD, 

ICF, IPC, KPS, LAS, MFG, MRO, PLU, PPG, RCI, SW, 

USR, UTR, VAL. 
ACP, ACY, APD, COM, CPV, DA, GLD, GYH, ICF, MCC, ORO, 

PPG, SM, SW. 
ACP, ACR, ACY, AMR, APD, DA, DAV, DSO, EKT, EPC, EW, 

FMP, FRE, GEI, GLD, GNT, GRG, GYR, HKD, LAS, MMM, 

OCF, PLU, PPG, RCI, RH, SCN, SW, TXT, USR, VAL. 

FRL, GE, HER, HKD, HVG, MON, MRB, NPI, PIS, RCI, RGC, 
SYR, UCP, VAR, VSV. 

ACP, AMR, BOR, CAT, CBR, CD, EW, FOM, GE, HKD, IRI, 

MCA, MON, NPI, NPP, NTC, NVF, PGU, PPL, PYZ, RCD, 

RCI, SCN, SPL, SYR, TKL, UCP, VAR. 
AMR, BME, BOR, CAT, CBM, CBR, HKD, MUM, MON, MRB, PPG, 

PYZ, SCN, SYR, UCP, VAR. 
ABS, BME, BOR, FRL, GE, HKD, MMM, MON, PYZ, RAB, SCN, 

SYR, SYV, UCP, VAR, VSV. 
ACP, AMR, CAT, HKD, MON, OCF, PYZ, RCI, SCN, UCP. 
ACP, ACR, AMR, BOR, GE, HKD, MON, NPI, PYZ, RCI, SCN, 

SYR, TXT, UCP, UNO, VAR. 
BOR, CAT, CBC, CBD, HPC, MON, PGU, PYZ, RCI, RH, SIM, 

WCA, WHD. 
AMR, BOR, CBC, CBD, HKD, MCA, MON, NPI, PYZ, RCI, SIM, 

UCP, UPL. 



PLASTICS AND RESIN MATERIALS 



137 



■Plastics and resin materials for which U.S. production or sales were reported, identified by 
manufacturer, 1966- -Continued 



Manufacturers' Identification codes 
(according to list in table 22) 



THERMOSETTING RESINS— Continued 

»Phenollc and other tar acid resins — Continued 
•Protective coatings, unmodified and modified 

»A11 other uses (including export) 

•Polyurethane am dlisocyanate resi"S 

»Rosin modifications: 

»Rosin and rosin esters, unmodified fester gums) 

»A11 other 

•Silicone resins 

Styrene -alkyd polyesters 

»Urea and melamine resins: 

•Textile treating and coating resins 

•Paper treating and coating resins 

Ifolding materials 

Bonding and adhesive resins for: 
•Laminating 

•Plywood 

•Fibrous and granulated wood 

•Protective coatings 

•All other uses (including export) 

•All other thermosetting resins 



THERMOPLASTIC RESINS 



Acrylic resins 

•Cellulose plastics materials: 
Sheets, continuous: 
•Under 0.003 gage 

•0.003 gage and over 

•All other sheets, rods, and tubes 

•Molding and extrusion materials 

•Polyamide resins: 

•Nylon type 

•Non-nylon type 

Polyolefin plastics materials: 
Ethylene polymers and copolymers: 
Production: 

•High pressure polyethylene 

•Low pressure polyethylene 

•Ethylene copolymers 

•Polyethylene, density 0.9^0 and below: 
•Sales and use: 

•Injection molding 



•Blow molding 

•Filin and sheet- 



ADM, BOR, CIK, CPV, DSO, EW, FCD, FRE, GE, GEI, GRV, 
HAN, HER, HKD, ICF, INL, KMC, KRM, KYN, MID, MMM, 
MON, MRB, NCI, NPI, ORG, OXR, PYR, PE, RCI, RH, 
SM, SNC, SW, SYR, TV, UCP, VAR, VTV, WAS. 

AC?, AMR, BME, BOR, CAT, CBM, CBR, DSO, EW, GE, GEI, 
GRG, HER, HKD, IOC, IRC, IRI, KND, KPT, MMM, MON, 
MRB, NPI, ?IS, PYR, PYZ, RAB, RCI, REZ, RGC, RH, 
RPC, SCN, SHA, SNC, SYR, UCP, USR, VAR, VSV. 

ACB, ADM, AFP, ARK, BFG, CBM, DUP, GPM, HAP, IPI, JWI, 
KMC, MCC, NOP, NPV, PEL, PFP, QUN, SCN, UPJ. 

ADM, CBY, DPP, ECC, FAR, FRP, HPC, KRM, MCC, NCI, OSB, 

SRR. 
ADM, CBY, DPP, FAR, FLW, FRP, HPC, JNS, KRM, MCC, NCI, 

OSB, PPG, RH, SCF, SHA. 
ACP, BOR, DCC, GLD, SPD, UCC. 
ADM, DEG, PFP. 

ACY, APX, BRY, CAT, CBR, GIB, CRC, DAN, DEP, DUP, ECC, 
GAF, GGY, HNC, HRT, JSC, MON, MRA, ONX, OXR, PC, QCP, 
RCI, RH, ROC, RPC, S, SBC, SEY, SNW, STC, SYN, USO, 
VAL, WIC. 

ACY, AMR, BME, BOR, CBC, CBD, CBR, DEP, DUP, HPC, MMM, 
MON, RCI, RH, SIM, TXT, x. 

ACP, ACY, FMB, GDN, PMC, SFA. 

ACY, BOR, CAT, CBR, FOM, GE, MON, NPP, NTC, OCF, PGU, 

PMC, PPL, STC. 
ACP, ACY, BOR, CAT, CBC, CBD, HPC, MON, NPI, NTC, PGU, 

RCI, REN, RH, SAC, SIM, SOR, WRD. 
ACY, AMR, BOR, CBD, IPR, MON, PGU, RCI, SAC, SOR, SYV, 

UPL. 
ACP, ACY, CEL, CPV, DSO, DUP, GLD, GRV, HAN, KPS, MID, 

MDN, NON, OXR, PPG, RCI, REL, RH, SCN, SW, TV. 
ACP, ACY, AMR, BOR, CAT, CMP, DUP, EFH, FMB, HPC, MON, 

RCI, RH, STC, UNO, VAL, VAR. 
ACP, ACY, CIB, GGY, HPC, HVG, JNS, MOB, MON, NOP, NPV, 

NTC, OCF, PPG, RPC, UBS, UNO, WTC. 



ACY, CEL, CIB, CM3, DUP, 
PPG, QUN, RH, RPC, SAR, 



HCO, JNS, JSC, 



CEL, DUP, EKT, NIX. 

CEL, DOW, EKT, MON, MPP, 

CEL, MPP, NIX, PDJ, RSB, 

CBN, CEL, DOW, EKT, MON, 

ALF, DUP, FG, POL, SPN. 

BCM, EMR, GNM, JNS, KRM, 



ACP, DOW, DUP, EKX, KPP, 
ACP, CEL, DOW, DUP, HPC, 
DUP, UCP, USI. 



NIX, PDJ, SPY. 

SPY. 

RSB. 



MON, RCC, SPN, 
KPP, MON, PLC, 



ACP, CEL, DOW, DUP, EKX, 

UCP, USI. 

ACP, DOW, DUP, EKX, KPP, 

USI. 

ACP, ALO, CEL, DOW, DUP, 

SPN, UCP, USI. 

CEL, DOW, DUP, EKX, KPP, 

CEL, DOW, DUP, EKX, KPP, 



KPP, MON, PLC, 
MDN, PLC, RCC, 
EKX, KPP, MDN, 



UCP, USI. 
UCP, USI. 



RCC, SHC, SPN, 
SHC, SPN, UCP, 
PLC, RCC, SHC, 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 15B. --Plastics and resin materials for which U.S. production or sales were reported, identified by 
manufacturer, i966— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



THERMOPLASTIC RESINS— Continued 

Polyolefin plastics materials— Continued 
♦Polyethylene, density 0.940 and be low- -Continued 
»Sales and use — Continued 

»Pipe and conduit 

*Other extruded products 

»A11 other uses (including export) 

•Polyethylene, density over 0.940: 
»Sales and use: 

•Injection molding 

•Blow molding 

•Film and sheet 

•Extrusion coating on paper and other substrates- 

•Wire and cable 

•Pipe and conduit 

•Other extruded products 

•All other uses (including export) 

Polypropylene : 

•Production 

•Sales and use: 

•Molding - - — ■ 

•Extrusion 

•All other uses (including export) 

•Styrene type plastics materials : 
ABS and SAN resins: 
•Production 

•Sales and use: 

•Jtolding 

•Extrusion 

•All other uses (including export) 

Styrene and styrene copolymer resins: 
•Production: 

StrEiight polystyrene 

Rubber-modified polystyrene 

Styrene-butadiene copolymer 

All other - 

•Sales and use: 

•Molding 

•Textile and paper treating and coating 

•Emulsion paint 

•Extrusion 

Foam and foamable materials 

•All other uses (including export) 



Vinyl resins: 

Polyvinyl chloride and copolymers; 
•Production: 

Suspension homopolymers 

Suspension copolymers 

Dispersions (paste) 



DOW, EKX, KPP, PLC, UCP, USI. 

ACP, DOW, DUP, EKX, KPP, PLC, UCP, USI. 

ACP, CEL, DOW, DUP, EKX, KPP, MON, PLC, RCC, SPN, UCP, 



ACP, CEL, DOW, DUP, EKX, HPC, KPP, PLC, RCC, SHC, UCP, 

USI. 

ACP, CEL, DOW, DUP, EKX, HPC, KPP, MON, PLC, RCC, SHC, 

UCP, USI. 

ACP, CEL, DOW, DUP, EKX, HPC, KPP, PLC, SHC, UCP, USI. 

DUP, EKX, PLC, UCP, USI. 

ACP, CEL, DUP, EKX, HPC, MON, PLC, SHC, UCP, USI. 

ACP, CEL, DUP, EKX, HPC, KPP, PLC, SHC, UCP, USI. 

ACP, CEL, DOW, DUP, EKX, HPC, KPP, PLC, UCP, USI. 

ACP, CEL, DOW, DUP, EKX, HPC, KPP, MDN, PLC, UCP, USI. 

ALO, AVS, DOW, EKX, EN J, HPC, NVT, RCC, SHC. 

ACP, AVS, DOW, EKX, ENJ, HPC, NVT, ORO, PLC, RCC, SHC, 

UCP, USI. 

ACP, ALO, AVS, EKX, ENJ, HPC, NVT, ORO, PLC, RCC, SHC, 

UCP, USI, VEL. 

ACP, ALO, AVS, DOW, EKX, ENJ, HPC, NVT, ORO, PLC, RCC, 

SHC, UCP, USI, VEL. 



BFG, DOW, FBF, MCB, HON, UCP, USR. 

BFG, DOW, MCB, MON, MPP, RCC, UCP, USR. 

BFG, DOW, FIR, GRD, MCB, MDN, MPP, RCC, SW, UCP, USR, 
WIC. 



BPL, CBN, CSD, DOW, FBF, FG, KPP, MON, ONX, ?IA, POL, 

RCC, SEK, SOL, TIC, UBS, UCP, WAS. 
BPL, CSD, DOW, FG, GOR, KPP, MOhJ, PLA, RCC, SHC, UCP. 
BFG, BOR, DOW, FIR, GCC, GNT, GRD, GYR, ILC, KPP, SEP, 

USR, WIC. 
ACC, BCN, BKC, BOR, DOW, DSO, DUP, FLH, GAF, GLD, GRD, 

IOC, JNS, JSC, MON, MRT, PAI, PVI, RCC, RH, SM, SPI, 

UNC, WAS. 

BFG, BKC, BPL, CSD, DOW, FBF, FG, FIR, GOR, GYR, KPP, 
MDN, PLA, RCC, SHC, SOL, TIC, UCP, USR. 

BOR, DOW, FIR, FLH, GNT, GRD, GYR, ILC, JSC, KPP, MON, 
ONX, SEP, USR, WAS, WIC. 

BOR, DOW, DSO, FIR, GNT, GRD, GYR, KPP, MON, RCC, USR. 

CBN, CSD, DOW, DSO, KPP, MON, MPP, RCC, SHC, UCP, X. 

CSD, DOW, GYR, KPP, MON, RCC, SEK, SHC, UNC, USR, x. 

ACC, BCN, BFG, BOR, CSD, DOW, DSO, DUP, FG, GAF, GGC, 
GLD, GNT, GRD, GYR, IOC, JNS, JSC, KPP, VON, MPP, 
MRT, PAI, POL, PVI, RCC, RH, SEK, SEP, SHC, SM, SPI, 
UBS, UCP, UNC, USR, WAS. 



AME, ATU, BFG, BOR, CRY, CUC, DA, DOW, ESC, FIR, GNT, 

GRA, GYR, MON, PU, SFA, UCP, USR. 
AME, BFG, BOR, CRY, CUC, DA, FIR, QNT, KYS, MON, NSC, 

ONX, PNT, SFA, THC, UCP. 
BFG, BOR, CRY, DA, FIR, GYR, MDN, UCP, USR. 



PLASTICS AND RESIN MATERIALS 



139 



TABLE 15B. --Plastics and resin materials for which U.S. production or sales were reported, identified by 
manufacturer, iP66— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



THERM3PLASTIC RESINS— Continued 

Vinyl resins— Continued 

Polyvinyl chloride and copoljniiers — Continued 
»Sales and use: 

•Calendering , except flooring 

Flooring : 
•Calendered 

•Coated 

Paper and textile uses: 
•Coating 

•Other 

•Protective coatings and adhesives 

•Wire and cable 

•Extruded film and sheet 

•Other extruded products 

•Sound records 

•Injection and blow molding 

•Plastisol formulating and molding 

•All other uses (including export) 

Polyvinyl acetate: 
•Production: 

•Latexes 

•Resins 

•Sales and use: 

•Qnulsion paints 

•Adhesives 

•Paper treating 

•Textile treating 

•All other uses (including export) 

•Polyvinyl alcohol 

•Other vinyl resins 

•All other thenuDplastic resins 



FIR, GNT, 

AME, ATU, BFG, BOR, CRY, CUC, DA, ESC, FIR, MON, THC, 

UCP. 
BFG, BOR, CRY, DA, FIR, GNT, GYR, XCN, THC, UCP, USR. 

ATU, BFG, BOR, CRY, DA, ESC, FIR, M3N, ONX, THC, UCP, 

USR. 
BFG, BOR, ESC, FIR, ONX, THC, UCP. 
BFG, BOR, DA, ESC, FIR, MON, NSC, UCP. 
AME, BFG, BOR, CRY, CUC, DA, DOW, FIR, MON, PNT, THC, 

UCP, USR. 
AME, BFG, BOR, CUC, DA, DOW, FIR, GYR, ION, PNT, SFA, 

THC, UCP, USR. 
ACP, ATU, BFG, BOR, CRY, CUC, DA, DOW, ESC, FIR, GNT, 

GYR, MON, PNT, SFA, THC, UCP, USR. 
BFG, BOR, CRY, CUC, DA, KYS, MON, PLA, PNT, SFA, THC, 

UCP, USR. 
ATU, BFG, BOR, CRY, DA, DOW, ESC, FIR, GYR, MON, THC, 

UCP, USR. 
BFG, BOR, CRY, CUC, DA, ESC, FIR, MON, PYR, THC, UCP, 

USR. 
BFG, BOR, CRY, CUC, DA, DOW, ESC, FIR, GNT, GRA, GYR, 

ION, PYR, SFA, THC, UCP, USR. 



AML, APV, BOR, BOY, GEL, CUC, DSO, DUP, FC, FLH, GLC, 
GLD, GRD, HAN, HNC, HRT, JSC, KMC, KMP, UCC, MMM, 
MR, MRN, NCI, NPV, NSC, NTC, PII, PPG, PVI, QCP, REL, 
RPC, SED, SEY, SPC, UCP, WAS, WIC. 

AFP, BEN, BIS, BOR, CAT, CST, CUC, DAN, DAV, DUP, FAR, 
HNC, JOB, MON, NSC, OCF, PPG, RCI, SCO, SED, SH, UCP. 

AML, APV, BEN, BOR, CAT, CEL, CUC, DAV, DSO, DUP, FLH, 

GLC, GLD, GRD, HAN, JOB, KMC, KMP, MCC, MON, MR, NCI, 

NPV, NSC, PPG, RCI, SED, SPC, UCP, WAS, WIC. 
AML, BOR, CEL, CUC, DUP, FC, FLH, GLC, GRD, HNC, JSC, 

MMM, M3N, MRN, NSC, NTC, PII, PPG, RCI, SH, UCP. 
AML, BOR, CEL, CUC, DUP, FLH, GLC, MMM, MON, NSC, PII, 

SEY, UCP, WIC. 
AML, BOR, CEL, CST, CUC, DAN, DUP, GLC, GRD, HRT, JSC, 

NSC, PII, RPC, SCO, SEY. 
AFP, AML, BLS, BOR, CEL, CUC, DUP, FAR, FLH, GLC, GLD, 

GRD, HRT, MON, NSC, OCF, PII, PVI, QCP, REL, RCI, 

UCP, WAS. 
BOR, CUC, DUP, FC, MCC, MON. 
BOR, DOW, DUP, GLD, GRD, IOC, MON, SW, UCP. 
ACG, ACP, CBY, CIB, DEP, DUP, ECC, GE, GLC, HPC, JSC, 

KRM, MID, 1AM, MOB, RH, RPC, SBC, SCN, SNW, UCP. 



SYNTHETIC ORGANIC CHEMICALS, 1966 
Rubber -Processing Chemicals 



TABLE 16B.- 



■ Rubber-processing chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1966 



feubber-processing chemicals for which separate statistics are given in table 16A are marked below with an asterisk 
(»); chemicals not so marked do not appear in table 16A because the reported data are accepted In confidence and 
may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that 
the manufacturer did not consent to his identification with the designated product] 



Chemical 



Manufacturers' identification code 
(according to list in table 22) 



RUBBER-PROCESSING CHEMICALS, CYCLIC 

»Aocelerators, activators, and vulcanizing agents: 
*Aldehyde-amlne reaction products: 

Aoetaldehyde-aniline condensate 

n-Butyraldehyde-anlllne condensate 

Butyraldehyde-butylldeneanillne condensate 

i-Ethyl-(i-propylacrylanilide-- 

Formaldehyde -p-toluldlne condensate 

tteptaldehyde-anlline condensate 

Trlethyltrlmethylenetri amine - 

"Dithlocarbamlc acid derivatives: 

Dlbutyldithlocarbamlc acid, N,N-dimethylcyclo- 
hexylamine salt. 

Dlbutyldithlocarbamlc acid, dlphenylguanldlne salt 

Dlmethylethylene dlphenyldithlocarbamic acid, lead salt 

2,A-Dinltrophenyl dimethyldlthiocarbamate-- 

Piperidinecarbodithioic acid, plperidlnium-potassium 
salts, mixed. 
Guanldlnes: 

Dlcatechol borate, di-o-tolylguanidine salt 

1,3-Diphenylguanldine 

Dlphenylguanldlne phthalate 

1,3-Dl-o-tolylguanldlne 

1,2,3-Triphenylguanldine 

»Thiazole derivatives: 

2-Benzothlazyl N,N-diethylthiocarbamoyl sulfide 

l,3-Bls(2-benzothiazolylmercaptomethyl)urea 

N-tert-Butyl-2-benzothiazolesulfenamlde 

»N-Cyclohexyl-2-benzothiazolesulfenamlde 

N,N-Dllsopropyl-2-benzothiazolesulfenamlde ■ 

N- ( 2 , 6 -Dime thy Imorphollno ) -2 -benzothiazolesulf enamide - ■ 

»2,2' -Dlthiobls(benzothiazole ) ■ 

•2-Mercaptobenzothlazole 

2-Mercaptobenzothlazole, zinc chloride 

2-MBrcaptobenzothlazole, zinc salt 

4-Morpholinyl-2-ben2othlazyl disulfide -- 

N-Oxydlethylene -2 -benzothiazolesulf enamide 

Thlazollne-2-thiol ■ 

All other cyclic accelerators, activators, and 
vulcanizing agents: 

p-Benzoqulnonedioxime 

Bls(p-amlnocyclohexyl)methane carbamate 

Bis(2,6-dlmethylmorpholinothlocarbonyl)sulflde 

Dlbenzoyl-p-qulnonedioxlme 

Dlbenzylamlne ' 

N, N'-Dlclnnanylldene-l,6-hexanediamlne 

Di-N,N'-pentamethylenethiuram tetraeulflde 

4,'i'-Dithlodlmorphollne • 

2 -Imidazoline -2 -thiol ■ 

Poly-p-dlnltrosobenzene 

Styrene polysulflde - ■ 

Tetrahydro-4,A,6-trimethyl-2(lH)-pyrimldlnethlone 

•Antioxidants, antlozonants, and stabilizers: 

"Amino antioxidants, antlozonants, and stabilizers: 
Aldehyde- and acetone-amlne reaction products: 

Acetaldehyde-anlllne hydrochloride condensate 

Aldol - :i-naphthy lamlne condensate 

Butyraldehyde-aniline condensate 

Dlphenylamlne-acetone condensate 

Phenyl -2-naphthylamine-acetone condensate 

•Substituted p-phenylenediamlnes: 

N,N'-Bls(l,'; -dime thy lpentyl)-p-phenylenediamine 

N,N'-Bls(l-ethyl-3-me thy lpentyl)-p-pheny lenedi amine- ■ 



MON, RCD, USR. 



ceo. 
ceo. 

USR. 
DUP. 



ACY, BPG, MON, USR. 



ACY, 


BPG, 


GYR, MON, 


USR 


ACY, 


BFG, 


GYR, MON, 


USR 


DUP. 








ACY, 


GYR, 


USR. 




GYR. 








ACY, 


MON. 






ACY. 








CTA, 


DUP. 






DUP. 








DUP. 








CTA, 
MI.S, 


USR. 
USR. 






DUP. 








DUP, 


VNC. 






MON. 








DUP, 


RBC. 






DUP. 








TKL. 









USR. 




BFX). 




DUP. 




ACY, 


BFG, DUP, USR 


USR. 




ILKT, 


USR, x. 


EKT, 


MON, UPM. 



RUBBER-PROCESSING CHEMICALS 

TABLE l^B. --Rubber-processing chemicals for which U.S. production or sales were reported, identified by 
maTuifacturer, i566— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



RUBBER-PROCESSING CHIMICAI5, CYCLIC--Continued 

^Antioxidants, antlozonants , and stabillzers--Continued 
«Amlno antioxidants, antlozonants, and stabillzers-- 
Continued 
^Substituted p-phenylenediamlnes — Continued 

N, N'-Bis(l-methylheptyl)-p-phenylenediamlne 

N-sec-Butyl-N' -phenyl -p-phenylenedlamlne 

N-Cyclohexyl-N' -phenyl -p-phenylenediamlne 

Diarylarylenediamlnes, mixed 

N,N'-Dl-sec-butyl-p-phenylenediamine 

N,N'-Dl-2-naphthyl -p-phenylenediamlne 

»N,N'-Diphenyl-p-phenylenedlainlne 

N-Isopropyl-N' -phenyl -p-phenylenediamine 

All other p-phenylenediamines 

Other amino antioxidants, antlozonants, and stabi- 
lizers : 

p-Anilinophenol 

l,2-Dlhydro-6-dodecyl-2,2,'i-trimethylquinoline 

l,2-Dihydro-6-ethoxy-2,2,'i-tri]nethylquinoline 

l,2-Dihydro-2,2,<i-trimethylquinoline 

<i,4'-Dlmethoxydiphenylainine 

"tj-i'-Dloctyldlphenylajiilne 

N.N'-Dlphenylethylenedlamine 

N,N'-Diphenyl-l,3-propanedlamine 

NjN'-Di-o-tolylethylenediamlne 

p-Isopropoxydiphenylamlne 

A,A'-Methylenedianiline 

»Octyldiphenylaiiiine 

Octyldlphenylamlne mixture (mono-, nonyl-, and di-). 

N-Phenyl-1-naphthylamine 

»N-Phenyl-2-naphthylamlne 

p-(p-Toluenesulfonamido)diphenylamlne 

All other -. 

»Phenollc and phosphite antioxidants and stabilizers: 
Phosphites : 

Nonyl phenyl phosphites, mixed 

Polyphenolic phosphite, polyalkylated 

•PolyphenoliCE (including bisphenols) : 

Bisphenol, hindered 

<»,'i'-Butylidenebis(6-tert-butyl-m-cresol) 

2,5-Di-(l,l-dlmethylpropyl)hydroqulnone 

2,2'-Methylenebis(6-tert-butyl-p-cre3ol) 

2,2'-MethylenebiE(6-tert-butyl-^-ethylphenol) 

2,2'-Methylenebis(6-tert-octyl-p-cresol) 

2,2'-Thlobis(<V,6-di-sec-amylphenol) - 

<i,'i'-Thlobis(6-tert-butyl-m-cresol) 

l,l,3-Tri(2-methyl-^-hydroxy-5-tert-butylphenyl) 
butane . 
Other phenolic antioxidants and stabilizers: 

p-Benzyloxyphenol 

N-Butyroyl-p-aminophenol 

o-Cresol, alkylated 

N-Ifluroyl-p-amlnophenol 

»Phenol, alkylated 

Phenol, hindered 

Phenol, styrenated 

N-Stearoyl-p-amlnophenol 

Xylenol, alkylated 

♦Blowing agents: 

N,N'-Dlmethyl-N,N'-dinitrosoterephthalamlde 

Dlnltrosopentamethylenetetramine 

p,p'-Oxybis( benzene sulfonhydrazlde) 

•Peptizers : 

Alkylated o-thiocresol 

Alkylated thlophenol, zinc salt 

A17I mercaptans 

2 -Benznmi dothlophene , zinc salt 

2', 2' ' '-Dithiobis(benzanlllde) 

Dixylyl disulfides, mixed 

2-Naphthalene thiol 

Pentachlorobenzene thiol 



BFG, EKT, 


MON, 


um. 




USR. 








USR. 








am. 








USR. 








BFG. 








BPG, DUP, 


USR. 






MON, USR. 








MON. 








BFG. 








HON. 








MON. 








BPG, MON. 








DUP. 








BPG. 








CCO, NOP, 


X. 






CCO. 








CCO. 








BPG. 








USR. 








ACY, NPI, 


FAS, 


USR. 




BFG. 








DUP, USR. 








BPG, DUP, 


USR. 






USR. 








DUP. 








USR. 








BFG. 








GYR. 








MON. 








MON. 








ACY, CAT. 








ACY. 








ACY. 








MON. 








MON. 








ICI. 








BFG. 








MLS. 








PIT. 








MLS. 








ACY, BPG, 


CCO, 


GYH, PAS, 


PIT, USR 


DUP, GYR, 


PIT. 






BFG, GYR, 


USR. 






PIT. 








DUP. 








DUP, NPI. 








USR. 








PIT. 








PIT. 








PIT. 
ACY. 








ACY. 
PIT. 
DUP. 
DUP. 









SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 16B .-- Rubber-processing chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1966 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



RUBBER-PROCESSING CHIMICAI^, CYCLIC— Continued 

►Peptizers — Continued 

Pentachlorobenzenethiol, zinc salt 

Thiocresol 

Thiophenol (Benzenethiol ) 

Xylene thiol - 

Other cyclic rubber-processing chemicals: 

p-tert-Amylphenol sulfide (tackifler) 

Dioresyl disulfide - — — 

N,4-Dinltroso-N-methylanlline (physical-property 
improver). 

Hindered aromatic polyamine 

»N-Nitrosodiphenylamine (retarder) 

RUBBER-PROCESSING CHIMICAI£, ACYCLIC 

•Accelerators, activators, and vulcanizing agents: 
•Dithlocarbamic acid derivatives ; 

Dibutyldithiocarbamic acid, potassium salt 

Dlbutyldithiocarbamic acid, sodium salt 

»Dibutyldithlooarbamio acid, zinc salt 

Dlethyldithiocarbamlc acid, selenium salt 

Diethyldithiocarbamio acid, sodium salt 

Dlethyldithiocarbamlc acid, tellurium salt 

»Diethyldithlocarbamic acid, zinc salt 

Dlmethyldlthlocarbaiaic acid, bismuth salt 

Dimethyldlthiocarbamic acid, copper salt 

Dimethyldithlocarbamlc acid, lead salt 

Dimethyldlthiocarbamic acid, selenium salt 

Dimethyldlthiocarbamic acid, sodium salt and sodium 
polysulfide. 

•Dimethyldlthiocarbamic acid, zinc salt 

All other - 

»Thlurams : 

Bis(dibutylthiocarbamoyl) sulfidei 

»Bis (diethyl thiocarbamoyl) disulfide 

•Bis (dimethyl thiocarbamoyl) disulfide 

Bis (dimethyl thiocarbamoyl) disulfide and 2-mercapto- 
benzothiazole, mixed. 

»Bis (dimethyl thiocarbamoyl) sulfide 

Bis (ethylmethyl thiocarbamoyl) sulfide 

Thiuram blend 

Xanthates and sulfides : 

Dl-n-butylxantho disulfide 

Dlisopropylxantho disulfide 

Zinc dlbutyl xanthate 

Zinc isopropyl xanthate 

All other acyclic accelerators, activators, and vulcan- 
izing agents: 

n-Butyraldehyde-butylamlne condensate 

Dl-n-butylammonlum oleate 

3-Ethyl-l,l-dimethyl-2-thlourea 

Ethylenedlamlne carbamate 

Polyoxyalkalenetetrasulfide 

l,l,3-Trlmethyl-2-thlourea 

Blowing agents: 

Madlfied urea 

Urea-bluret mixture 

Conditioning and lubricating agents: 

Methyl stearyl- 10- sulfonic acid, sodium salt 

Mono- and dlaliyl acid phosphates, mixed 

Mono- and dlaliyl phosphate ammonium salts, mixed 



DUP. 
PIT. 
PIT. 
DUP. 

PAS. 
USR. 
CTA, MON. 



VNC. 

DUP, PAS, USR, VNC. 

ALC, DUP, PAS, USR, VNC. 

VNC. 

ALC, PAS. 

VNC. 

ALC, GYR, PAS, USR, VNC. 

VNC. 

VKC. 

VNC. 

VNC. 

BFG, GNT. 



USR. 

DUP, GYR, PAS. 

BPG, DUP, GNT, GYR, PAS, USR, VNC. 

DUP, VNC. 

DUP, GYR, USR. 

VNC. 

DUP. 



ELASTOMERS (SYNTHETIC RUBBERS) 



143 



-Rubber-processing chemicals for which U.S. production or sales were reported, identified by 
manufacturer , 1966 — Continued 



Chemical 


Manufacturers' Identification codes 
(according to list in table 22) 


RUBBER- PROCESSING CHEMICALS, ACYCLIC-Continued 

Poljnnerlzatlon regulators: 

Alkyl meroaptans, mixed - 


PAS, PLC. 
HK, PAS, PLC. 




Shortstops: 

Dlmethyldithlooarbamlo acid, potassium salt 

oDlmethyldlthlooarbamlo acid, sodium salt 

Other acyclic rubber-processing chemicals: 

Zinc laurate (activator, physical-property improver) 


GYR, PAS, USR. 

ALC, BFG, DUP, GYR, PAS, USR. 

USR. 
USR 







Elastomers (Synthetic Rubbers) 



TABLE ITB.— Elastomers (synthetic rubbers) for which U.S. production or , 

manufacturer, 2966 



were reported, identified by 



[Elastomers (synthetic rubbers) for which separate statistics are given in table 17A are marked below with an as- 
terisk (»); products not so marked do not appear in table 17A because the reported data are accepted in confidence 
and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies 
that the manufacturer did not consent to his identification with the designated product] 



Product 


Manufacturers' identification codes 
(according to list in table 22) 


ELASTC»ilERS, CYCLIC 


ASY, BFG, CPY, FIR, FRS, GGC, GNT, GYR, ILC, MCB, 

PLC, RUB, SHC, TUS, URC, USR, WIC. 
BFG, FIR, FRS, G^JT, GYR, PLC, USR. 
ACY, DUP, GNT, MOB, PRC, RUB, TKL, USR. 

ACY, BFG, TKL. 




-D 1 +V, + ^ ^ py^^ ^"® yp^ 


ELASTOMERS, ACYCLIC 






BFG FRS GYR TKL TUS 






Polychloroprene type (Neoprene) 

•Polyisobutylene-isoprene type (Butyl) 

Reaction products of natural rubber 


DUP. 

CBN, ENJ. 
GYR, HPC. 
DCC, SPD, UCS. 




ASY, BAR, DUP, ENJ, FRS, GGC, GNT, GYR, PLC, SHC, TUS. 









SYNTHETIC ORGANIC CHEMICALS, 1966 



Plasticizers 

TABLE 18B. --Plasthizers for which U.S. production or sales were reported, identified by 
manufacturer, 1966 

[Plasticizers for which separate statistics are given in table ISA are marked below with an asterisk (»); products 
not so marked do not appear in table ISA because the reported data are accepted in confidence and may not be 
published. Manuf actiirers' identification codes shown below are taken from table 22] 



Manufacturers' identification code 
(according to list in table 22) 



PLASTICIZERS, CYCLIC 

Coumarone-indene plasticizer 

N-Cyclohexyl-p-toluenesulfonamide 

Dibenzyl sebacate 

Diethylene glycol dibenzoate 

Di-tert-octyldiphenyl oxide 

Dipropanediol dibenzoate 

N-Ethyl-p-toluenesulfonamide 

Isopropylidenedlphenoxypropanol 

Naphthalene, alkylated ■ 

Phosphoric acid esters; 

*Cresyl diphenyl phosphate 

Dibutyl phenyl phosphate 

Diphenyl mono-o-xenyl phosphate 

Diphenyl oetyl phosphate 

Methyl diphenyl phosphate 

»Tricresyl phosphate 

»Triphenyl phosphate 

All other phosphoric acid esters 

»Phthalic anhydride esters: 

Alkyl benzyl phthalates 

Bis('4-methyl-2-pentyl) phthalate 

Butyl benzyl phthalate 

Butyl cyclohexyl phthalate 

n-Butyl n-decyl phthalate 

»Butyl 2-ethylhexyl phthalate 

n-Butyl isodecyl phthalate 

»Butyl octyl phthalate 

Di ( 2-butoxyethyl) Dhthaiate 

»Di butyl phthalate 

»Dicyolohexyl phthalate 

^Diethyl phthalate 

*Dihexyl phthalate 

»Diisodecyl phthalate 

■»Di(2-methoxyethyl) phthalate 

Dimethyl isophthalate 

»Diniethyl phthalate 

Dinonyl phthalate 

»Dioctyl phthalates: 

Dicapryl phthalate 

Di( 2-ethylhexyl) isophthalate 

*Di( 2-ethylhexyl) phthalate 

«Dliso-octyl phthalate 

Di-n-octyl phthalate 

Mixed dioctyl phthalates 

Diphenyl phthalate 

»Ditridecyl phthalate 

2-Ethylhexyl Isodecyl phthalate 

*Glycolate phthalate esters: 

Butyl phthalyl butyl glycolate 

Ethyl (and methyl) phthalyl ethyl glycolate 

All other glycolate phthalate esters 

Hexyl n-decyl phthalate 

Hydrogenated castor oil phthalate 

Isodecyl tridecyl phthalate 

Iso-octyl isodecyl phthalate 

»n-Octyl n-decyl phthalate 

All other phthallc anhydride esters 

Polyethylene glycol dibenzoate 



MON. 






















WTH. 






















VEL. 






















DOW. 






















VEL. 






















ON. 






















DOW. 






















ACC. 






















FMP, 


MON, 


MTR, 


SFA, 


X. 














WON. 






















DOW. 






















MON. 






















™p. 


MON. 




















FW, 


MON, 


MTR, 


SFA. 
















EK, 


MON, 


SFA. 


















SKA. 






















X. 






















GRH. 






















GRH, 


MON. 




















ACP. 






















PCC. 






















ACP, 


MON, 


UCC. 


















GRH, 


UCC. 




















GRH, 


PCC, 


RCI, 


RUB. 
















FMP, 


WM. 




















ACP, 


COM, 


DUP, 


EKT, 


GRH, 


MON, 


PCC, 


PFZ, 


RCI, 


RUB, 


SW, 


UCC, WTH. 


















ACP, 


DUP, 


FMP, 


MON, 


PFZ. 














Dtrp, 


EKT 


KF, 


WON, 


pn. 














ACP, 


GRH 


THC. 


















ACP, 


BFG 


FVT, 


EN J, 


GRH, 


MON, 


PCC, 


RCI, 


RUB, 


THC, 


UCC 


WTH. 




















DUP, 


EKT, 


FMP, 


RCI, 


SFA. 















GRH, WTH. 

UCC. 

ACP, BFG, EKT, ENJ, GRH, MON, PCC, PFZ, RCI, RUB, THC, 

UCC, WTH. 
ACP, AM, BFG, EKT, ENJ, GRH, M3N, PCC, PFZ. RCI, RUB, 

THC, UCC. 
ADM. 
ACP. 
MON. 



MON, NOP. 

MON. 

ARG, HPC. 

ACP, UCC. 

DUP. 

THC. 

ACP, GRH, RUB. 

ACP, ENJ, GRH, MSN, PCC, PFZ, RCI, RUB, THC. 

FMP, GRH, kON, THC, UCC. 

VEL. 



TABLE 18B. —Plasticizers for which U.S. production or sales were reported identified by 
manufacturer, i566~Continued 



Manufacturers' identification codes 
(according to list in table 22) 



PLASnCIZERS, CYCLIC--Continued 

Tetrahydrofurfuryl oleate 

Toluenesulfonamide, o-, p- mixtures 

Triethylene glycol dibenzoate 

»Trimellitio acid esters: 

n-Octyl n-decyl trimellltate 

Tri(2-ethylhexyl)triinellitate 

Triisodecyl trimellltate 

Trilso-octyl trimellltate — 

Trl-n-octyl trimellltate- 

All other trimellitic acid esters 

All other cyclic plasticizers 

PLASTICIZERS, ACYCLIC 

»Adipio acid esters: 

*Di{2-(2-butoxyethoxy) ethyl) adlpate 

•Di(2-ethylhexyl) adlpate— 

Dlisobutyl adlpate 

"Diisodecyl adlpate 

Dilso-octyl adlpate 

Diisopropyl adlpate 

Dlnonyl adlpate 

Di-n-octyl adlpate 

n-Hexyl n-decyl adipate 

Iso-octyl Isodecyl adipate 

»n-Octyl n-decyl adlpate 

Polyethylene glycol adipate 

All other adlpic acid esters 

»Azelaic acid esters: 

Dlcyclohexyl azelate 

Dl(2-ethylbutyl) azelate— - - 

Di(2-ethylhexyl) azelate 

Dlisobutyl azelate 

Dilso-octyl azelate 

Dl-n-octyl azelate 

All other azelalc acid esters 

Ij-i-Butanediol dicaprylate 

Butoxyethyl pelargonate 

Citric and acetylcitrlc acid esters 

•Complex linear polyesters and polymeric plasticizers 

Di(butoxyethoxy-ethoxy) methane 

Dl(2-(2-butoxyethoxy)ethyl)methane 

Dlbutyl tartrate 

Diethylene glycol dlnonanoate 

Dilso-octyl diglycolate 

»Epoxldlzed esters: 

Butyl epoxydioleate 

Butyl epoxystearate 

Butyl epoxytallate 

Epoxidized linseed oils 

»Epoxldlzed soya oils 

Epoxidized tall oils 

»2-Ethylhexyl epoxytallates 

Octyl epoxystearates 

•Octyl epoxytallates 

All other epoxidized esters 

Glycerol pelargonate 

Glyceryl tributyrate and tripropionate 

Glycol pelargonate 

Isodecyl nonanoate (Isodecyl pelargonate) 

Laurie acid esters 

Ityristic acid esters: 

Butyl myrlstate 

»Isopropyl myrlstate 

Other myristlc acid esters 

»01eic acid esters: 

2-Butoxyethyl oleate 

•Butyl oleate 

•Glycerol trioleate (Triolein)— 

•Isopropyl oleate 



CCW, 
ACY, 
VEL. 


EMR. 
MON. 






THC. 
PFZ. 
PFZ. 
PFZ, 


RUB. 






PFZ, 
CCW, 


RUB. 
EKT, 


MON, 


NEV 



FMP, RCI 


TKL, WTH 












EKT, GRH, 


MON, PCC 


RCI 


RH, 


THC 


UCC. 




FMP, GRH, 


HAL. 












ACP, EKT, 


GRH, MON 


PCC 


PFZ 


, RCI 


, RH, 


RUB, THC, UCC 


PCC, RCI, 


RH, RUB, 


WTH. 










SBC, VND 














THC. 














ACP. 














ACP, PCC. 














GRH, NOP, 


RCI. 












ACP, GRH, 


MON, PCC, 


ROT 


RH, 


THC, 


TKT, 


UCC. 


PFZ. 














GRH, PFZ. 














PFZ. 














EMR. 














EKT, EMR, 


PFZ, RCI, 


RH, 


RUB, 


UCC. 






HAL. 














EMR. 














PFZ. 














ACP, EMR. 














RUB. 














HAL. 














PFZ. 














ADM, EKT, 


EMR, GLY, 


HAL 


MON 


RH, 


RUB, 


THC, WTH. 


TKL. 














GRD. 














ARC. 














EMR, RUB. 














CCA, FMP. 














AM. 














BAC. 














ADM, THC. 














Pm, SWT. 














ADM, ARG, 


BAC, RCI, 


RH, 


SWT, 


THC, 


ncc. 




RCI. 














ADM, BAC, 


UCC. 












ARG. 














ARG, RH, 


:hc, UCC. 












EMR, RH. 














EMR. 














EKT. 














EMR. 














EMR. 














HAL, SBC. 














ARC. 














ARC, DRW, 


ICI, NOP. 












ICI. 














ARC. 














ARC, CHL, 


HAL, ICI, 


NOP. 


SWT, 


WM, 


WTH. 




DRW, EMR, 


SWT, WM. 












EMR, ICI, 


WM. 













SYNTHETIC ORGANIC CHEMICALS, 1966 



-Plasticizers for which U.S. production or sales were reported, identified by 
manufacturer, i 966— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



PLASTICIZERS, ACYCLIC— Continued 

•Oleic acid esterB--Continued 

•Methyl oleate 

•n-Propyl oleate 

All other oleic acid esters 

Palmitic acid esters: 

Isobutyl palmitate 

Iso-octyl palmitate 

Isopropyl palmitate 

2 -Methoxyethy 1 palmitate 

•Phosphoric acid esters: 

Tri(2-butoxyethyl) phosphate 

Tri(2-chloroethyl) phosphate 

Triethyl phosphate 

Trioctyl phosphate 

All other phosphoric acid esters 

Ricinolelc and acetylrlcinoleic acid esters: 

n-Butyl acetylrioinoleate 

Butyl riclnoleate 

•Glycerol monoricinoleate 

Glyceryl tri( acetylricinoleate) 

Methyl riclnoleate 

All other ricinolelc and acetylrlcinoleic acid esters 
Sebaclc acid esters: 

•Dibutyl sebaoate 

»Dl(2-ethylhexyl) sebacate 

Dliso-octyl sebecate 

Dimethyl sebacate 

Dipentyl sebacate 

All other sebacic acid esters 

•Stearic acid esters: 

Butoxyethyl stearate 

»n-Butyl stearate 

Dlmethylajnmonium stearate 

2-Ethylhexyl stearate 

Glycerol triacetyl stearate 

Isopropyl stearate 

Methoxyethyl stearate 

Methyl dichlorostearate 

Methyl pentaohlorostearate 

Methyl stearate 

All other stearic acid esters 

Sucrose acetate isobutyrate 

Tetraethylene glycol di(2-ethylhexanoate) 

Triethylene glycol dlcaprylate 

•Triethylene glycol dl(caprylate-caprate) 

Triethylene glycol dl-2-ethylbutyrate 

Triethylene glycol di(2-ethylhexanoate) 

Triethylene glycol dlpelargonate 

2,2,'i-Triiiiethyl-l,3-pentanediol diisobutyrate 

All other acyclic plasticizers 



CHL, EMR, ICI, NOP, SWT. 
CHL, EMR, WM. 
HAL, RH, VND. 



FMP, WES. 
UCC. 
EKT. 
FMP, UCC. 



SF, 



ARC, BAC, PFZ, RH. 

EKT, GRH, HAL, PFZ, RCI, RH, WTH. 

QRD, GRH, HAL, PCC, RH, RUB, WTH. 

NOP. 

GRH. 

RCI. 

NOP. 



CHL, EMR, HAL, ICI, RUB, SCP, SWT, WTH. 



ARC, 
ARC, 
RH. 
FMP. 
BAC. 
ARC, 



CHL. 
HPC, 
EKT. 
UCC. 



DRW, FOR, HAL, RUB. 

UCC. 

EKT, NOP, UCC. 

RUB. 

EKX. 

EMR, HAL, HPC, PFZ, TKL, UCC, 



SURFACE-ACTIVE AGENTS 



147 



Surface -Active Agents 



-Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1966 



[Surface-active agents for which separate statistics are given in table 19A are marked below with an asterisk (»); 
products not so marked do not appear in table 19A because the reported data are accepted in confidence and may not 
be published. Manufacturers' identification codes sho?m below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 22) 



Amphoteric Surface-Active Agents 

Acyclic : 

(l-Carboxyheptadecyl)trimethylammonium hydroxide, inner 

salt (C-Hexadecylbetaine). 
( Carboxymethyl )( coconut oil alkyl )dimethylammonium 

hydroxide, inner salt [N-(Coconut oil alkyl )betaine ]. 
(Carboxymethyl) [3-(ooconut oil amldo )propyl] -dimethyl- 
ammonium chloride, sodium salt. 
( Carboxymethyl )dimethyl(9-ootadeoenyl)aramonium hydroxide 

inner salt [N-(9-0ctadecenyl)-betalne] . 
(l-Carboxyundecyl)trimethylammonium hydroxide, inner 

salt (C-Decylbetaine). 

N-( Coconut oil alkyl )-p-alanine, sodium salt 

N-(2-Coconut oil amidoethyl)-N-(2-hydroxyethyl) -glycine, 

sodium salt. 

N-Dodecyl-3-iminodipropionio acid, disodium salt 

N- ( 2-ftydroxyethyl ) -N- ( 2-lauramidoethyl ) -p -alanine, 

sodium salt. 
N- ( 2-Hydroxyethyl ) -N- ( 2-stearamidoethyl )glycine, sodium 

salt. 
Mixed acyclic primary amines, ethoxylated and sulfated, 

sodium salt. 

(Mixed alkyl )sulf obetaine 

Mixed fatty betaines 

Oleic acid - ethylenediamlne condensate, propoxylated 

and sulfated, sodium salt. 

Polypeptide, ammonium salt 

Polypeptide, sodium salt 

N-(Tallow alkyl )-3-lminodlproplonic acid, disodium salt- 
Gyclic: 

1, 1-Bis ( carboxymethyl ) -2-undeoyl-2-imidazollnium 

hydroxide, disodium salt. 
l-Carboxymethyl-2-heptadeoyl-l-(2-hydroxyethyl)- 

Z-imidazolinlum hydroxide, sodium derivative, sodium 

salt. 
l-Carboxymethyl-l-(2-hydroxyethyl)-2-nonyl-2- 

Imldazolinium chloride, sodium salt. 
l-Carboxymethyl-l-(2-hydroxyethyl)-2-nonyl-2- 

Imidazolinlum hydroxide, sodium derivative, sodium 

salt. 
l-Carboxymethyl-l-(2-hydroxyethyl)-2-undeoyl-2- 

imldazolinium chloride. 
1- Carboxymethyl- 1- ( 2-hydroxyethyl ) -2-vmdecyl-2- 

imidazolinium hydroxide, sodium derivative, sodium 

salt. 
Heptadecylmethylbenzimldazolinesulfonic acid, sodium 

salt. 
3-[ 2-(2-Undecyl-2-iinidazolin-l-yl)ethoxy]propionio acid, 

sodium salt. 

Anionic Surface-Active Agents 

MCarboxylio acids (and salts thereof): 

»Amine salts of fatty, rosin, and tall oil acids: 

Coconut oil acids, trlethanolamine salt 

Oleic acid, butylamine salt 

Oleic acid, diethylamlne salt 

Oleic acid, trlethanolamine salt 

Saturated Cia'Cig acids, ethanolamine salt 

Stearic acid, morpholine salt 

Stearic acid, N,N,N',N'-tetrakis(2-hydroxyethyl)- 
ethylenediamine salt. 



DUP. 
CUL. 
JRG. 
DUP. 
DUP. 



DUP, TXT. 

TXT. 

S. 

MYW. 
MtW. 
GNM. 

MIR. 

MIR. 



PCS, UVC. 
MIR. 



DYS. 
WTC. 
DCM, HAL, TCC. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



-Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, i 966— Continued 



Manufacturers' identification cedes 
(according to list in table 22) 



Sur/a 



Agen 



-Continued 



»Carboxylic acids (and salts thereof )--Contlnued 
♦Amine salts of fatty, rosin, and tall oil 
acids — Continued 

Stearic acid, triethanolamlne salt 

Tallow acids, triethanolamlne salt 

«Carboxylic acids having amide or ester linlcages : 

N-(Cooonut oil acyl )polypeptide, ammonium salt 

N-(Coconut oil acyl ipolypeptide, potassium salt 

N-( Coconut oil acyl )polypeptide, sodium salt 

N-( Coconut oil acyl )sarcosine 

N-(Cooonut oil acyl)aarcosine, sodium salt 

»N-Lauroylsaroosine, sodium salt 

N- (Mixed alkylsulf onyl )glyoine, sodium salt 

N-Oleoylpolypeptide, sodium salt 

N-Oleoylsarcoelne, sodium salt 

Phthalic acid, octadeoyl ester, potassium salt 

Stearolactolactic acid 

Stearolactolaotic acid, calcium salt 

Stearolactolactic acid, sodium salt 

N-Stearoylsaroosine, sodium salt 

N-Undecenoylpolypeptide, potassium salt 

All other 

"Potassium and sodium salts of fatty, rosin, and tall 
oil acids: 

Castor oil acids, potassium salt 

Castor oil acids, sodium salt 

•Coconut oil acids, potassium and sodium salts: 
•Potassium salt 



•Sodium salt 

Coconut oil and tallow acids, sodium salt 

•Com oil acids, potassium and sodium salts: 

Potassium salt 

Sodium salt 

Cottonseed oil acids, sodium salt 

Laurie acid, potassium salt 

Mixed vegetable fatty acids, potassium salt- 
•Oleic acid, potassium salt 



•Oleic acid, sodium salt- 



Olive oil acids, sodium salt 

Palm oil acids, sodium salt 

Peanut oil acids, potassium salt 

Hosin acids, potassium salt 

Bosin acids, sodium salt 

Soybean oil acids, potassium salt 

•Stearic acid, potassium and sodium salts: 

Patassium salt 

Sodium salt 

•Tall oil acids, potassium and sodium salts: 
•Potassium salt 



•Sodium salt 

Tallow acids, potassium salt- 
•Tallow acids, sodium salt 



All other 

•Ftiosphoric and polyphosphoric acid esters (and 
salts thereof): 
•Alcohols and phenols, ethoxylated and phosphated: 

Dlnonylphenol, ethoxylated and phosphated 

Dodecyl alcohol, ethoxylated and phosphated 

Dodeoyl alcohol, ethoxylated and phosphated, barium 
salt. 

Dodecylphenol, ethoxylated and phosphated 

2-Ethylhexanol, ethoxylated and phosphated -- 

Iso-octyl alcohol, ethoxylated and phosphated 

44CLxed linear alcohols, ethoxylated and phosphated 

•Nonylphenol, ethoxylated and phosphated 



AML, 


GLY, 


TCC. 


SBP. 






MfW. 






MYW. 






MYW. 






GGY. 






HMP. 






CP, 


GGY. 


HMP, ONX. 


GAF. 






TMT. 


MYW. 




GAF, 


GGY. 




CIB. 






GLY. 






GLY. 






GLY. 






GGY. 






MYW. 






HMP. 






ARL. 


BAG, 


SEA. 


HAL, 


MRV, 


WHI. 



ACE, BSC, CSB, DSO, DYS, GRL, HOT, JHG, LUR, mC, PCH, 

PG, SWT. 
CON, CP, JRG, LEV, NPR, PG, PRX. 
GRC. 

HOT, PCH. 

LUR, NMC. 

WHI. 

DRW, NOP, VAL. 

AML, ARL, DYS, GRC, GRL, PCH, SWT. 

AML, BSC, BSW, CCL, CIB, CPY, DAN, FRS, GYR, HOT, NMC, 

NOP, QCP, S, SHP, USR, WBG, WIC. 

BSW, FRS, LEV, LUR, MRV, NOP, SEA, SNW, SWT, USR, WBG, 

WTC. 

HOT, LUR. 
LUR. 

KAL, SLC. 

ASY, FRS, GRC, X. 

ASY, CRT, MRA, PLC, PRX, QCP, X. 

CON, DRW, DYS. 

GYR, VAL, WTC. 

OYR, LEV, MAL, NOP, WTC. 

ACE, ASY, BSC, CON, CSB, DRW, DYS, EFH, FRS, GAF, GYR, 
HOT, LUR, mC, PNX, QCP, USR, VAL, WHI, x. 

CPY, GYR, MRV, PCS, PRX, QCP, TXT, UNP, X. 

ASY, CPY, NMC, PG, SWT. 

ASY, CON, CP, DYS, FRS, GYR, JRG, LEV, LUR, I«C, NOP, 
NPR, PG, PLC, PRX, QCP, SWT. 

NMC. 



TCI. 

TCI, WAY. 

GAF. 

CRT, CST, GAF, SEY. 

GAF, NLC, RTF, SEY, TCC, TXT, VAC, WAY, WSN. 



SURFACE-ACTIVE AGENTS 



149 



TABLE 19B. —Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, i966— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



4nionic Surface-Active 4gen(s - -Continued 

•phosphoric and polyphosphorio acid esters (and salts 
thereof ) — Continued 
•Alcohols and phenols, ethoxylated and phosphated— 
Continued 
Nonylphenol, ethoxylated and phosphated, barium 
salt. 

9-Ootadeoenyl alcohol, ethoxylated and phosphated 

Octylphenol, ethoxylated and phosphated 

Octylphenol, ethoxylated and phosphated, magnesium 
salt. 

Phenol, ethoxylated and phosphated 

Trideoyl alcohol, ethoxylated and phosphated 

All other 

•Alcohols, phosphated or polyphosphated : 

Deoyl, dodeoyl, and octyl phosphate, morpholine ealt- 

Deoyl polyphosphate, triethanolamlne salt 

2-Ethylhexyl phosphate 

»2-Ethylhexyl phosphate, sodium salt 

2-Ethylhexyl polyphosphate 

Hexyl polyphosphate, potassium salt 

Mixed alkyl phosphate 

Mixed alliyl phosphate, diethanolamine salt 

Octadecyl phosphate, triethanolamlne salt 

9-Ootadeoenyl phosphate 

Octyl phosphate 

Octyl phosphate, alkylamine salt 

Octyl phosphate, potassium salt 

Octyl polyphosphate 

Octyl polyphosphate, alkylamine salt 

Octyl polyphosphate, potassium salt 

Octyl polyphosphate, sodium salt 

•Sulfonic acids (and salts thereof): 
•Alkylbenzenesulf onates : 
•Dodecylbenzenesulf onates : 

•Dodecylbenzenesulfonic acid 

Dodecylbenzenesulf onic acid, ammonium salt 

Dodecylbenzenesulfonic acid, butylamlne salt 

•Dodecylbenzenesulfonic acid, calcium salt 

Dodecylbenzenesulfonic acid, diethanolamine salt— 

Dodecylbenzenesulfonic acid, ethylenediamine salt — 

•Dodecylbenzenesulfonic acid, isopropanolamine salt- 

•Dodecylbenzenesulfonic acid, isopropylamine salt — 

Dodecylbenzenesulfonic acid, (mixed alkyl ) -amine 
salt. 

Dodecylbenzenesulfonic acid, potassium salt 

Dodecylbenzenesulfonic acid, propoxylated 
ethylenediamine salt. 

•Dodecylbenzenesulfonic acid, sodium salt 

Dodecylbenzenesulfonic acid, strontium salt 

•Dodecylbenzenesulfonic acid, triethanolamlne salt — 

•Other alky IbenzenesxUf onates : 

DecylbenzenesuJfonic acid, sodixim salt 

Didodecylbenzenesulfonic acid 

Didodecylbenzenesulfonic acid, sodium salt 

Pentadecylbenzenesulfonio acid, potassium salt 

Pentylbenzenesulfonio acid, sodium salt 

•Tridecylbenzenesulfonic acid 

•Tridecylbenzenesulfonic acid, sodium salt 

Undecylbenzenesulfonio acid 

Undecylbenzenesulfonic acid, sodium salt 

•Benzene-, cumene-, toluene-, and xylenesulf onates : 

Benzenesulfonlc acid, sodium salt 

Cumenesulfonio acid, ammonium salt 

2,4-Dinitrobenezenesulfonic acid, sodium salt 

Toluenesulfonlo acid 

Toluenesulfonlc acid, potassium salt 



GAF. 






GAF, 


LUR, 


NLC, WAT. 


NLC. 






DUP. 






MOA. 


RCD. 




WAY. 






SEf, 


UCC, 


UVC. 


live. 






CST. 


DEX. 




BON, 


CST. 


DUP. 


DW. 






RCD. 






DUP. 






DUP. 


SFA- 




DUP. 






DUP. 






DEX. 


TXT. 




TXT. 







ARD, CO, CRT, CTL, aiK, HLI, LEV, MON, NAC, PIL, RCD, 

RTF, STP, TCI, TDC, TOI, TXT, WTC. 

ARL, CTL. 
WTC. 

APD, NLC, RCD, RH, RTF, STP, WTC, X. 
VAL. 

APD, RTF. 

CTL, RCD, X. 

APD, ARD, CTL, RCD RTF, SNW, STP. 

PCS, STP, VAL, WTC. 



AAC, APX, ARD, ARL, ATR, BLA, CO, CP, CRT, CTL, DEP, 
DSO, DYS, EFH, HLI, HRT, LEV, MON, NAC, NOP, PHC, PO, 
PIL, PRX, RCD, STP, SWT, TO), UNP, WIC, WTC. 

RTF. 

AAC, AML, ARD, ARL, ATR, CRT, CTL, DSO, DYS, HLI, NAC, 
PCS, PIL, RCD, RTF, SOS, STP, SWT, TXT, VAC. 

AEU, MON. 

CO. 

CO. 

STP. 

MON. 

KON, NPR, TXT. 

BLA, CP, NPR, ROD, WTC. 

TXT. 

TXT. 

NE5. 

STP. 

NE5. 

NES, RCD. 

NES, RCD, STP, TXN. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



. —Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1966 — Continued 



Ghenlcal 






Manufacturers 


identification codes 








(according to list in table 22) 




Anionic Surface-Active /Igenls- -Continued 














^Sulfonic acids (and salts thereof )— Continued 














»Benzene-, oumene-, toluene-, and xylenesulfonates— 














Continued 
















CO, 


NES, 


PIL, RCD, 


STP, 


WTC. 

STP, TXN, WTC. 




loluenesuilonic aclu, soaluin salt------------ — ----- 

»Xylenesulfonie acid, ammonium salt 


ATR, 


CO, 


HLI, NES, 


RCD, 






NES, 


STP. 










^lenesuiionic aciu, poxassium saix-- —.—-.- 






ATR, 


CO, 


HLI, JRG, 


NES, 


PIL, RCD, STP, TXN, WTC. 




»Ugninsulfonates: 




Ligninsulfonic acid, aluminum salt 


MAR. 














CRZ. 
CRZ, 
MAR. 












gninsu ^^J'j' smmon um s 


CWP, 


GLY, LKY, 


LPC 


MAR, PSP. 




*Ligninsulionlc acid, calcium salt----— — —-"——--- 
Ligninsulfonic acid, chromium salt 




Ligninsulfonic acid iron salt---— --—-—-- — — — 


CRZ. 
LPC, 
PSP. 
CRZ, 














MAR. 










Ligninsulfonic acid, magnesium salt — --— - 

Ligninsulfonic acid, mixed salts-- -- --- -— 










»Ligninsulfonic acid, sodium salt 


CWP, 


MAR, WVA 








»Naphthalenesulf onates : 














BenzyLnaphthalenesulXonio acid 


OAF. 












Butylnaphthalenesulfonic acid 


SCP. 












*Butylnaphthalenesulfonic acid sodium salt— --------- 


CLD, 
GAF, 
PFZ. 


CMS, 
MRA, 


GGY, PFZ 
S. 








Dibutylnaphthalenesulf onic acid - - - --- ---- 








Didodecylnaphthalenesulfonic acid, sodium salt 








Diisopropylnaphthalenesulfonic acid 


DUP, 


GAF, 


GRD, NAC 








Diisopropylnaphthalenesulfonio acid, sodium salt 


GAF, 


PFZ. 










Dipentylnaphthalenesulfonlc acid, ammonium salt 


NLC. 












Dipentylnaphthalenesulfonio acid, (mixed aliyl)amine 

salt. 
Dipentylnaphthalenesulfonlc acid, sodium salt 


NLC. 












GGY. 












Isopropylnaphthalenesulfonic acid 


DUP, 


NOP, 


ONX. 








Methylenebis(2-naphthalenesulfonic acid)— 


DUP. 












6,6'-Methylenebis(2-naphthalenesuironic acid), calcium 


DUP. 












salt. 














Methylnaph'thalenesuLfonic acid scxiium salt----------- 


UDI. 
















Methylnonylnaphthalenesulf onic' acid, sodium salt 


UDI. 












Tetrahydronaphthalenesulfonic acid 


DUP. 












»Other sulfonic acids: 














»N-Methyl-N-oleoyltaurine, sodium salt 


CRC, 


CRT, 


DEP, OAF, 


HRT 


MRA, NOP. 




»Sulfosucoinamic acid derivatives: 














N- ( 1, 2-Dicarboxyethyl )-N-octadecylsulf osucclnamic 


ACY. 












acid, tetrasodium salt. 














N- ( 2-ltrdroxyethyl ) -N- ( tallow aliyl )sulf osucoinamlo 


SCP. 












acid, dlsodium salt. 














N-OctadeoylsuLfosucclnamic acid, disodium salt 


ACT. 












N-(01eoyloxyisopropyl)Eulfosucoinamic acid, disodium 


OTC. 












salt. 














»Sulfosuccinio acid esters: 














Sulfosuccinic acid, bis(2,6-dimethyl-4-heptyl) ester. 


GAF. 












sodium s6LLt. 














♦Sulfosuccinic acid, bls(2-ethylhexyl) ester, sodium 


ACT, 


CRC, 


CRT, CST, 


DAN 


EFH, EMK, GQY, HRT, ICI, 


MOA, 


salt. 


PC 


, SBC 


, TCI. 








Sulfosuccinic acid, bis(talloii monoglyoeride ) ester. 


ACT. 












sodium salt. 














Sulfosuccinic acid, dihexyl ester, sodium salt 


ACT, 


MQA, 


SNW. 








Sulfosuccinic acid, dioctyl ester, sodium salt 


RH. 












Sulfosuccinic acid, dipentyl ester, sodium salt 


ACT. 












Sulfosuccinic acid, ditrideoyl ester, sodium salt — 


ACT, 


MQA. 










•All other sulfonic acids: 














Rn+-wThvd-pr»wl-iHTih*anvT milf^r^Tiln Of^-IH .... — - 


RBC. 












ouLyuiyuroxyDipiienyisuiionic acia-- ——————-- 




Butylhydroxybiphenylsulfonic acid, sodium salt 


ICO. 












Coconut oil acids, 2-sulfoethyl ester, sodium salt 


GAF, 


LEV. 










(Coconut oil isethlonate, sodium salt). 














Dodeoyldiphenyloxidedisulfonic acid, disodium salt— 


DOW. 












Dodeoyl sulfoacetate 


MAC. 












(Byoerol monostearate sulfoacetate, sodium salt 


WTC. 












Laurie acid, 2-sulfoacetaiiildoethyl ester, potassium 

salt. 
2-LauToyloxy-l-propanesulfonic acid 


WTC. 












SDH. 












\IA-Vf>t\ n1 VBnAQiilf rinln n/ilrt .--...... _..„.-..—_... - 


RET, 
DUP, 


TXT. 
RET, 










nu-xc^u H [ KHneaujLL onic ucia------- ---— — — — — 

Mixed alkanesulfonio acid, sodium salt 


VPC. 









SURFACE-ACTIVE AGENTS 



TABLE 19B.— Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 7966— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



Anionic Surfacf-Ac<ivt /(genf s - -Continued 

*Sulfonio acids (and salts thereof )~ Continued 
"Other sulfonic acids — Continued 

»A11 other sulfonic acids — Continued 

Octylphenol, ethoxylated and sulfonated, sodium salt' 
Petroleumsulf onic acid, water soluble (acid layer), 

sodium salt. 
Taurine derivatives: 

N-( Coconut oil acyl)-N-methyltaurine, sodium salt- 

N-Cyclohexyl-N-palmitoyltaurine, sodium salt 

N-Methyl-N-palmitoyltaurine, sodium salt 

N-Methyl-N-(tall oil acyDtaurlne, sodium salt 

N-Methyl-N-(tallow acyl)taurine, sodium salt 

All other 

Sulfuric acid esters (and salts thereof): 
»Acids, amides, and esters, sulfated: 

»Coconut oil acids - ethanolamine condensate, sulfated, 

potassium salt. 
»Esters of sulfated oleic acid: 

2-Butaxyethyl oleate, sulfated, sodium salt 

»Butyl oleate, sulfated, sodium salt 

Ethyl oleate, sulfated, sodium salt 

Glycerol trioleate, sulfated, sodium salt 

»Isopropyl oleate, sulfated, sodium salt 

Methyl oleate, sulfated, sodium salt 

»Propyl oleate, sulfated, sodium salt 

»01eic acid, sulfated, disodium salt 

»Tall oil, sulfated, sodium salt 

»Other acids, amides, and esters, sulfated: 

Bu-tyl riclnoleate, sulfated, disodium salt 

Coconut oil acids - isopropanolamine condensate, 

sulfated, sodium salt. 
Glycerol monoester of coconut oil acids, sulfated, 

ammonium salt. 
Glycerol monoester of coconut oil acids, sulfated, 
sodium salt. 

9-Octadecenyl acetate, sulfated, sodium salt 

Oleic acid - ethanolamine condensate, sulfated, 
sodium salt. 

Oleostearin, sulfated, sodium salt 

Ricinoleic acid, sulfated, disodium salt 

All other 

•Alcohols and phenols, sulfated: 
»Dodeoyl sulfate salts: 

2-Amlno-2-me-thylpropanol salt 

Ammonium salt 

Diethanolamine salt 

N, N-Dlethylcyclohexylamlne salt 

Isopropanolamine salt 

"Magnesium salt 

Potassium salt 

"Sodium salt 

"Triethanolamlne salt 

*2-Ethylhexyl sulfate, sodium salt 

•Octadeoyl sulfate, sodium salt 

"Ootyl sulfate, sodium salt 

"Other alcohols and phenols, sulfated: 
Linear alcohols, sulfated: 

Coconut oil allcyl sulfate, triethanolamine salt 

Coconut and sperm oil aliyl sulfate, sodium salt— 

Decyl sulfate, sodium salt 

Decyl sulfate, triethanolamine salt 

Hexadeoyl and 9-ootadecenyl sulfate, sodium salt — 

Hexadeoyl sulfate, sodium salt 

Hexyl sulfate, potassium salt 

Mixed linear alcohols, sulfated, ammonium salt 

Mixed linear alcohols, sulfated, polyamine salt 

Mixed linear alcohols, sulfated, sodium salt 



CRT, 


RH. 


SIN, 


SON 


OAF, 


TNI. 


OAF. 




GAF. 




GAF, 


TXT 


GAF. 




STC. 





DEX, IMK, HRT, ONX. 



I CI, NOP, ONX, PC. 








GAF, KAL. 








MRV, SCP. 








BHY, CRT, DEX, HRT, 


ICI, 


LEA, 


LUR. 


ICI, NOP. 








ACY, BSC, EFH, MRV. 








ACT, ACY, CRT, DRW, 


am. 


GAF, 


LEA, 


TEN, WHI, WHW. 








ACY, APX, ICI, HRV, 


NOP, 


SEA, 


WHI. 


NOP. 








APX. 









DUP. 
















SCP. 
















SEA. 
















NOP. 
















EMR, 


SEY. 














DUP. 
















AAC, 


CTL, 


DUP, 


ONX, 


STP. 








AAC, 


CTL, 


CUL, 


DUP, 


HLI, 


JEG, 


ONX, 


STP 


DUP. 
















JBG. 
















AAC, 


CTL, 


HLI, 


STP. 










CTL, 


HLI, 


PG. 












AAC, 


CTL, 


CUL, 


DUP, 


HLI, 


JHG, 


ONX, 


PCI, 


RET. 














AAC, 


CTL, 


CUL, 


DUP, 


HLI, 


ONX, 


PCS, 


PG. 


TXT. 














AAC, 


UCC, 


WTC. 












DUP, 


BflC, 


ONX, 


PG. 










AAC, 


DUP, 


PCS, 


SEY. 










PCS. 
















DUP. 
















CTL, 


DUP, 


ONX, 


PCS. 










DUP. 
















PCS. 
















AAC, 


DUP. 














PCS. 


TXT. 














NLC. 
















LAK, 


PCS, 


TXT. 













PCS, PG, RCD, 



SYNTHETIC ORGANIC CHEMICALS, 1966 



-Surface-active agents for which U.S. production or sales were 
manufacturer, 1966 — Continued 



iported, identified by 



Manufacturers' identification codes 
(according to list in table 22) 



Ag,n 



-Continued 



Sulfuric acid esters (and salts thereof )— Continued 
»Aloohols and phenols, sulfated — Continued 

«Other alcohols and phenols, sulfated — Continued 
Linear alcohols, sulfated — Continued 

Nonyl sulfate, sodium salt 

Octadeoyl sulfate, triethanolamlne salt 

Tetradecyl sulfate, sodium salt 

All other 

Phenols and nonlinear alcohols, sulfated: 

Branched hexadecyl sulfate, sodium salt 

3,9-Diethyl-6-tridecyl sulfate, sodium salt 

7-Ethyl-2-methyl-4-undecyl sulfate, sodium salt 

Trichlorophenol sulfate, ethanolamlne salt 

Tridecyl sulfate, sodium salt 

»Ethers, sulfated: 

»Aliylphenols, ethoxylated and sulfated: 

Dodecylphenol, ethoxylated and sulfated, anmonium 

salt. 
(Mixed aliyl )phenol, ethoxylated and sulfated, 

sodium salt. 
Nonylphenol, ethoxylated and sulfated, ammonium 

salt. 
Nonylphenol, ethoxylated and sulfateu, ethanolamlne 

salt. 
Nonylphenol, ethoxylated and sulfated, sodium salt— 
Nonylphenol, ethoxylated and sulfated, triethanol- 
amlne salt. 
Ootylphenol, ethoxylated and sulfated, sodium salt— 
»Dodecyl alcohol, ethoxylated and sulfated, ammonium 

salt. 
*Dodeoyl alcohol, ethoxylated and sulfated, sodium salt- 
<«ittxed linear alcohols, ethoxylated and sulfated, 

sodium salt. 
»Other sulfated ethers: 

Dodecyl and tetradecyl alcohols, ethoxylatsd and 

sulfated, ammonium salt. 
Dodecyl and tetradecyl alcohols, ethoxylated and 
sulfated, potassium salt. 

Hexyloxypropyl sulfate, sodium salt 

Mixed linear alcohols, ethoxylated and sulfated, 

ammonium salt. 
Mixed linear alcohols, ethoxylated and sulfated, 

potassium salt. 
Sperm oil alcohol, ethoxylated and sulfated, sodium 

salt. 
Tridecyl alcohol, ethoxylated and sulfated, ammonium 

salt. 
Tridecyl alcohol, ethoxylated and sulfated, sodium 
salt. 

All other 

^Natural fats and oils, sulfated: 

»Castor oil, sulfated, sodium salt 

*Cooonut oil, sulfated, sodium salt 

»Cod oil, sulfated, sodium salt 

Cottonseed oil, sulfated, sodium salt 

Grease, other than wool, sulfated, sodium salt 

Herring oil, sulfated, sodium salt 

Lard, sulfated, sodium salt 

Mixed fish oils, sulfated, sodium salt 

Mixed vegetable oils, sulfated, sodium salt 

Mustard seed oil, sulfated, sodium salt 

»Neat's-foot oil, sulfated, sodium salt 

•Peanut oil, siilfated, sodium salt 

Redfish oil, sulfated, sodium salt 

»Ricebran oil, sulfated, sodium salt 

•Soybean oil, sulfated, sodium salt 

oil, sulfated, sodium salt 



TIN. 
DUP. 
ONX. 
PCS. 










APX. 
PCS, 
UCC. 
GAF. 
AAC. 


UCC. 








GAF. 










GAF. 










CIB, 


CTL, 


GAF, 


STP, 


TXT 


GAF. 










CRT, 
ARL. 


CTL, 


GAF. 






RH. 
AAC, 


CTL, 


ONX, 


PG. 





STP. 

S. 

CO, LAK, NLC, PIL, RCD, SCP, 

CO, GAF, RCD, SHC, TXT. 

DUP. 

PCS, RCD. 



SHC, STP, TXT, UCC. 



AAC, ARL, RCD. 



APX, PCS, 



3, SEY. 



AAE, ACT, ACY, AML, APX, BBJ, bSC, BSW, CRT, DEX, DRW, 
DUP, GAF, HRT, I CI, KAL, KNG, LEA, LUR, MRA, MRD, 
MRV, NOP, ONX, PC, S, SCO, SCP, SEA, SLC, WHI, WHW. 

ACY, MRD, NOP, RTC, SEA, WHW. 

ACT, CRT, DRW, MRD, NOP, S, SEA, WAW, WHI, WHW. 

NOP, RTC. 

NOP, SEA, WHI, WHW. 

WHI. 

AML, SCO, WHI. 
PCI. 

LUR, NOP. 

ACT, CRT, KAL, LOR, MRD, NOP, PC, SEA, WHW. 

ACY, I CI, LUR, NOP, SCP, SLC. 
WHI. 

EFH, KNG, LUR, NOP. 

CRT, DRW, HRT, KAL, MRD, NOP, ONX. 

ACT, CLD, CRT, DRW, HRT, KAL, KNG, LEA, MRD, NOP, ONX, 

RTC, S, SEA, WHI, WHW. 



SURFACE-ACTIVE AGENTS 



TABLE 19B. —Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, i 566- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



Sulfuric acid esters (and salts thereof) — Continued 
^Natural fats and oils, sulfated— Continued 

»Tallow, sulfated, sodium salt 



Whale oil, sulfated, sodium salt 

Other anionic surface-active agent: Trideoyl alcohol, 
ethoxylated and carbonated, sodium salt. 

Cationic Surface-Active Agents 

»Amlne oxides and oxygen-containing amines (except those 
having amide linkages ) : 

*2- ( 8-Heptadecenyl ) -1- ( 2-hydroxyethyl )-2-imidazoline 

*2-Heptadeoyl-l-(2-hydroxyethyl)-2-imidazoline 

»( Mixed aliyl) amine, ethoxylated 

»Rosin amine, ethoxylated 

»( Soybean oil allsyl ) amine, ethoxylated 

»( Tallow alkyl)amine, ethoxylated 

•»Other amine oxides and oxygen-oontalnlng amines (except 
those having amide linkages): 
Acyclic: 

N,N-bis( 2-hydroxyethyl) (coconut oil alkyl)amine 
oxide. 

N, N- Bis (2-hydroxyethyl )dodecylamine 

N, N-Bis(2-hydroxyeti^rl)ootadeoylamine 

N,N-Bls(2-hydroxyethyl)( tallow alkyl)amlne 

N,N-Bis( 2-hydroxyethyl) (tallow aliyDamine acetate 

(Coconut oil alkyl)amine, ethoxylated 

(Coconut oil alJ!yl)amine, ethoxylated, acetate 

(Coconut oil alkyl)amine, ethoxylated, maleate 

N, N-Dimethylhexadecylamine oxide 

( Ifydrogenated tallow aU£yl)amlne, ethoxylated 

N- ( 2-Hydroxyethyl ) -N, N ', N '-trie ( 2-hydroxypropyl ) 

ethylenediamine. 
N-(2-ltsrdroxyethyl)-N,N',N'-tris (2-hydroxypropyl) 
ethylenediamine distearate, methyl sulfate. 

Octadecylamine, ethoxylated 

Polyethylenepolyamine, alioxylated 

N-(Tallow aliyl)trimethylenediamine, ethoxylated 

N,N, N', N'-Tetrakis( 2-hydroxyethyl )ethylenediamine 

N, N, N ' , N ' -Tetr akls ( 2 -hydroxypropy 1 ) ethylenediamine 

dioleate, methyl sulfate. 
N, N, N ', N'-Tetrakis( 2-hydroxypropyl )ethylenediamine, 

propoxylated and ethoxylated. 
N, N, N', N'-Tetra]d.s( 2-hydroxypropyl) ethylenediamine 
dioleate, methyl sulfate. 

All other 

Cyclic : 

2-(8-Heptadecenyl)-A,4-bis(hydroxymethyl)-2-oxazoline, 
2- ( 8-Heptadeoenyl )-4-hydroxymethyl-^-methyl-2- 



ACT, ACT, HRY, BSW, DRW, EFH, ICI, KAL, LEA, LUR, MRA, 
MRD, NOP, ONX, PC, PCI, SCP, SEf, SID, SNW, SOS, WHI, 
WHW. 

KNG. 



GGY, NIC, ONX, UVC. 

OCT, HDG, MQA, UVC. 

APD, CIB, GAP, NOP, RH. 

HPC, NLC, PCS, RTF. 

AAC, ARC, VAC. 

AAC, AI*1, ARC, CIB, DUP. 



N-Hexadecylmorpholine 

N-(2-}trdroxyethyl )-l, 2-diphenylethylenediamlne— 

l-(2-[^droxyethyl)-2-nonyl-2-tntidazoline 

1 -1, 2-HydToxyethyl)-2-nor( coconut oil alkylJ-2- 

imidazoline. 
l-(2-}tydroxyethyl)-2-nor(tall oil alkyl)-2- 

imidazoline. 
l-(2-Itrdroxyethyl)-2-trideoyl-2-imidazollne 
hydrochloride. 

l-(2-l^droxyethyl)-2-undecyl-2- imidazoline 

Piperazine, ethoxylated 

N-(Soybean oil aUsyl )morpholine 

Amines and amine oxides having amide linkages: 
■»*Carboxylic acid - diamine and polyamine condensates ; 
Adipic and stearic acids - diethylenetriamlne 
condensate. 
»Cooanut oil acids - diethylenetriamlne condensate- 



CTL, 


FIN. 




FIN. 






TXT. 






PG. 






AAC, 


APD, 


ARC, 


RPC. 






SDH. 






ONX. 






CIB, 


TCH, 


VAC 


NIC. 






DUP. 






ARC. 


ICI, 


TCH. 


NIC. 






ARC, 


RTF. 




NLC. 






DUP. 






WYN. 






DUP. 






GAF, 


X. 




ecu, 


UVC. 




CCM, 


UVC. 




APD. 






APX, 


PCS. 




PCS, 


UVC. 




MOA, 


UVC. 




NLC, 


UVC. 




GGY, 


UVC. 




GGY, 


UVC. 




GAF. 






APD. 






APX. 






APX, 


NOP, 


■na. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



—Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1966— Continued 



Chemioal 




Manuf 


icturers' identification codes 








(ac 


wording to list in table 22) 




Cationic Surface-Active 4gen(s - -Continued 












»Anines and amine oxides having amide linkages — Continued 












»Carboxylio acid - diamine and polyamine conden- 












sates—Continued 












Coconut oil acids - N,N-dlmethyltrimethylenediamine 


JRG, 


RCD, 


TXT. 






condensate. 












Mixed fatty acids - polyalkylenepolyamine condensate— 


NLC. 










Oleic acid - l-(2-aminoethyl)piperazine condensate 


TXT. 










»01eic acid - diethylenetriamine condensate 


APD, 


HDG, 


PCS, 


TXT. 




Oleic acid - diethylenetriamine condensate, acetic 


PCS. 










acid salt. 












Oleic acid - N, N-dimethyltrimethylenedlamine 


CCW, 


SNW. 








condensate. 












Pelargonic acid - tetraethylenepentamine condensate— 


ICI. 










Stearic acid - diethylenetriamine condensate 


APX, 


CST, 


DEP, 


HRT, ONX, PCS, S. 




Stearic acid - N,N-diethylethylenediamlne condensate— 


GBP. 










Stearic acid - dipropylenetriamine condensate 


JOR. 










Stearic acid - tetraethylenepentamine condensate 


ICI, 


ONX, 


PCS. 






Tall oil acids - diethylenetriamine condensate 


NCW. 










Tall oil acids - polyalkylenepolyamine condensate 


TXT, 


UVC. 








All other 


ajR, 


TOD, 


m. 






»Carboxylio acid - diamine and polyamine condensates. 












ethoxylated: 












Coconut oil acids - diethylenetriamine condensate. 


TCC. 










polyethoxylated. 












Coconut oil acids - ethylenediamine condensate. 


AKL, 


NOP. 








monoethoxylated . 












♦Oleic acid - ethylenediamine condensate, mono- 


CLD, 


DEX, 


NOP, 


SOC, TNA. 




ethoxylated. 












Palm oil acids - ethylenediamine condensate, mono- 


APX. 










ethoxylated. 












Stearic acid - diethylenetriamine condensate, poly- 


TCC. 










ethoxylated. 












♦Stearic acid - ethylenediamine condensate, mono- 


AML, 


CLD, 


CMG, 


CST, DEP, DEX, ICI, MRA, NOP, £ 


, SNW. 


ethoxylated. 












Stearic acid - ethylenediamine condensate, poly- 


APD. 










ethoxylated. 












♦Other amines and amine oxides having amide linkages: 












N, N-Bis (2-hydroxyethyl )-2- (stearamidomethoxy ) - 


CIS. 










ethylamine. 












3-Lauraiiu.do-N, N-dimethylpropylamlne oxide 


SNW. 
JffW. 










Polypeptide, ethyl ester ——-_-_- __- 






GRD, 


UVC. 












Stearic acid - N-(2-cyanoethyl)diethylene- 


CIB. 










triamine condensate, (amine/acid ratio = 1/2). 












*itaiines, not containing oxygen (and salts thereof): 












♦Amine salts: 














AIM, 


ARC, 


FOR. 










N-( Coconut oil alkyDtrimethylenediamine acetate 


AHC, 


PCS. 








(^jrdrogenated tallow aliyDamine acetate 


ATM, 


ARC. 








(9-0ctadeoenyl)amine acetate 


GNM. 
ACY, 


ARC. 








Octadecylamine acetate---— -—--—- 






ARC. 
















ARC. 










^coyoean oij. aj-jtyx ^ajnine acexaxe— -— ------ 




(Tallow alkyDamine acetate 


MM, 


AHC, 


FOR. 






]ij_ ( -paj^^Q^ alkyl )trimethylenediamine acetate- - 


ARC, 


FOR. 












N- (Tallow alkyDtrimethylenediamine naphthenate 


APD, 


FOR. 








N-(Tallow alkyDtrimethylenediamine oleate 


FOR. 










All other 


AEM. 










♦Diamines and polyamines: 












1- ( 2-Aminoethyl )-2- (8-heptadeeenyl )-2-lmidazoline 


NLC. 










1- ( 2 -Ami no ethyl )-2~hep'tadecyl-2-iEiidazoline------ 


PCS. 














l-(2-Amlnoethyl ) -2- (mixed alkyl )-2-lmidazollne 


RTF. 










l-(2-Aminoethyl)-2-nor(tall oil alkyl )-2-imidazoline— 


NLC. 












ARC, 


FOR, 


GNM, 


HUM. 




♦H-Vuoconux o±± a i Kyi jxri mpunyieneuiflimne---------- — 






PCS. 










*:-Vo-nepxaaecenyi ) -^-i mi dagoiine — --—--_ 




2-Heptadecyl-2-liiiidazoline 


SCO. 










H-('IjHypH nlVvl ^nnT v*athv1 <iTi^no1 vnm-iTi«a------ - -- — - — - — 


CCW. 










n-VMuteu aj.jiyx y poj^e tny J. enepoiy amine--- ---—--— -—-— 




9 HririTrl P--{ m-1f^O'7on -Ino .-.. — - - _ — — -- 


PCS. 
ARC, 










<i-nonyi-*c-iiitLQazoiine-- — ----- — — — ___——_--_ 


FOR, 


GNM. 






'»rH-^7-ut,xtiaecenyi;xrimexnyieneQiamine ---.. — ._....._ 




N-(Soybean oil alkyDtrimethylenediamine 


ARC, 


HUM. 









SURFACE-ACTIVE AGENTS 



TABLE IQB.— Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, i566— Continued 



Manufacturers' Identification codes 
(according to list in table 22) 



Canonic Surface-Active Agents - -Continued 

^Amines, not containing oxygen (and salts thereof) — 
Continued 
wDianiines and polyamines — Continued 

N-( Tallow aliyDdipropylenetriamine 

»N-( Tallow aliyZ )trlmethylenedi«mine 

^Primary monoamines: 

»( Coconut oil alkyl) Amine 

(Cottonseed oil aliyl)amine 

»Dodecylamine 

Hexadeoylamine 

*(Hydrogenated tallow al]5yl)amine 

(MiJced aliyl ) amine 

(Mixed tert-aUjyl) amine 

»9-0otadeoenylamine 

*Octadecylaiiiine 

Octylamine ■•■ 

(Soybean oil aliyl ) amine 

(Tall oil alkyDamine 

»( Tallow alkyDamine 

♦Secondary and tertiary monoamines; 

Bis(cooonut oil allsyl)amine 

Bis(hydrogenated tallow alkyl)amine 

N,N-Dimethyl( coconut oil aliyl)amine 

N, N- Dime thy Idodecylamine 

N, N-Dimethylhexadecylamine 

N, N-Dimethyl(hydrogenated tallow aU!yl)amine 

N,N-Dimethyl( mixed aliyl)amine 

*N, N- Dime thy loctadecylamine 

N,N- Dimethyl (soybean oil alkyl)amine 

N, N-Dimethyltetradecylamlne 

N-Methylbis(coconut oil all£yl)amine 

N-Methylbis(hydrogenated tallow all!yl)amine 

N-Methylbis(mixed alkyl )amine 

N-Metl^rldiootadecylamine 

Tridodeoylamine 

Trioctylamine 

Trls(hydrogenated tallow aUsyDamlne 

•Oxygen-containing quaternary ammonium salts (except 
those having amide linkages ) : 

(2-Aiiilnoethyl)ethyl(hydrogenated tallow aliyl)- 
(2-hydroxyethyl) ammonium ethyl sulfate. 

Benzyl (coconut oil alliyl)bis(2-hydroxyethyl)ammonium 
chloride. 

Benzyl ( coconut oil aliyl, ethoxylated )dimethylammonium 
chloride. 

l-Benzyl-2-heptadecyl-l-(2-hydroxyethyl)-2-imidazolinium 
chloride. 

l-Benzyl-l-(2-hydroxyethyl)-2-nor(tall oil aliyl) -2- 
imidazolinium chloride. 

Bis ( 2-hydroxyethyl, ethoxylated )methyl( 9-ootadecenyl ) 
ammonixim chloride. 

Bis ( 2-hydroxyethyl, ethcacylated )me1diyloetadeoylammonium 
chloride. 

(Coconut oil alkyl )bis( 2-hydroxyethyl, ethoxylated ) - 
methylammonium chloride. 

(Ethoxybenzyl )dlmethyl(ootylphenoxy )aninionlum chloride 

(Ethoxybenzyl)dimethyl(octyltolyloxy) ammonium chloride--- 

l-Ethyl-2- ( 8-heptadecenyl ) -1- ( 2-hydroxyethyl )- 
2-imidazolinium ethyl sulfate. 

N-Ethyl-N-hexadecylmorpholinlum ethyl sulfate 

N-Ett^l-N-(soybean oil alkyl )morphollnium ethyl sulfate-- 

2-}tydroxytrlmethylenebis [(coconut oil aliyl )dlmethyl- 
ammonium chloride]. 

( Tridecylbenzyl )diethyl ( 2-hydroxyethyl )ammonium 
chloride. 

Tri ethyl (octadecyloxymethyl) ammonium chloride 

All other 



GNM. 








ARC, 


FOR, 


GNM, 


HUM. 


ATM, 


ARC, 


FOR, 


GNM, HUM. 


FOR. 








ATM, 


ARC, 


FOR, 


GNM. 


ATM. 


ARC, 


FOR. 




pm. 


ARC, 


FOR, 


GNM, HUM. 


GNM. 








RH. 








ARC, 


FOR, 


GNM. 




ATM, 


ARC, 


FOR, 


GNM. 


ARC, 


RH, 


UCC. 




ARC, 


HUM. 






FOR, 


GNM. 






AEM, 


ARC, 


FOR, 


GNM, HUM. 


ARC. 








ARC, 


FOR. 






BRD, 


HUM, 


PG. 




BRD. 








ARC, 


BRD. 






ARC. 








PG, 


IH. 






ARC, 


BRD, 


HUM, 


PG. 


ARC. 








ARC, 


BRD. 






FOR, 


GNM. 






ARC, 


FOR, 


GNM. 




PG. 








FOR. 








GNM. 








GNM. 








GNM. 








LUR. 








CIB. 








GAF. 








PCS, 


UVC. 






NIC. 








ARC. 








ARC. 








ARC, 


VAC. 






RH. 








RH. 








APD. 








APD. 








APD. 








CIB. 








SNW. 








DAN. 








TCC. 









SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 19B. —Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, i 566— Continued 



Cat 



Surfa 



4ge 



-Continued 






^Quaternary ajimonlum salts having amide linkages: 

Benzylbis ( 2-hydroxyethyl ) ( 2-stearaiiiidomethoxyethyl ) 

ammonivim chloride. 
2-Heptadeoyl-l-methyl-l-(2-stearaiiddoethyl) - 

inddazolinlum methyl sulfate. 
(2-Hydroxyethyl )dimethyl(3-stearaiid.dopropyl) anmoniu 

dihydrogen phosphate. 
( 2-Hydroxyethyl )dimethyl ( 3-stearamidopropyl 
nitrate . 

(3-Lauramidopropyl)trimethylammonlum methyl sulfate 

Trimethyl(3-oleamldopropyl)anfflionium methyl sulfate 

a.1 other 

"Quaternary ammonium salts, not containing oxygen: 
»Acyclic: 

«ais( coconut oil alkyl )dimethylammonium chloride 

»Bi3(hydrogenated tallow aliyl )dimethylaramonlum 
chloride. 
Bis(hydrogenated tallow alkyl )dlmethylammonium 
methyl sulfate. 

(Coconut oil aliyl )trimethylammonium chloride 

(Cottonseed oil alkyl )trlmethylaramonlum chloride 

Dldodeoyldimethylammonium bromide 

Dimethy Ibis (mixed alkyl)- and Trimethyl ( mixed alkyl)- 
ammonluin chloride. 

Dimethylbls(9-octadeoenyl ) ammonium chloride 

DlmethylbiE( soybean oil alkyl ) ammonium chloride 

Dimethy Idiootadecylammonlum chloride 

Dimethyldloctadecylammonium methyl sulfate 

»Dodecyltrimethylammonium bromide and chloride: 

Dodecyltrimethylammonlum bromide 

Dodeoyltrimethylammonlum chloride 

Ethyldlmethyl( mixed alkyl )ainmonium ethyl sulfate 

Ethyldimethyl(9-ootadeoenyl)ammonium bromide 

Ethylhexadecyldimethylammonium bromide 

»Hexadeoyltrimethylainmonlum bromide 

Hexadeoyltrimethylammonium chloride 

Hexadeoyltrlmethylammonium p-toluenesulfonate 

(ftrdrogenated tallow alkyl )trimethylamiionium 
chloride. 

Methyl triootylammonlum chloride 

Methyl tris(mixed alkyl) ammonium chloride 

»N, N, N ', N ', N'-Pentamethyl-N-( tallow alkyl )trimethylene- 
bis [amncnlum chloride] . 

Trlmethyloctadecylammonium chloride 

Trimethyl ( soybean oil alkyl) ammonium chloride 

Trimethyl (tallow alkyl) ammonium chloride 

All other 

»Benzenoid : 

«Benzyl( coconut oil alkyl )dimethylammonium chloride 

»Benzyldlmethyl( mixed alkyl ) ammonium chloride 

»Benzyldimethyloctadecylammonium chloride 

Benzyldlmethyltetradecylaramonlum chloride 

»Benzyldodecyldlmethylammonium chloride 

Benzylhexadecyldimethylammonlum chloride 

Benzyl(hydrogenated tallow alky 1 ) dimethy lammonlum 
chloride 

l-Benzylpyrldinium chloride 

Benzyl trimethylaramonlum chloride 

»(3,4-Dichlorobenzyl )dodeoyldimethylamiionlum ohloride- 

(Dodecylbenzyl)triethylaramonium chloride 

»(Dodecylbenzyl)trimethylammonlum chloride 

2-Dodecylisoqulnolinlum bromide 

(Dodeoylmethylbenzyl )trlmethylairanoniuiii chloride 

1-Dodeeylpyridinium chloride 

(Ethylbenzyl)dimethyl(mixed alkyl) ammonium chlorlde— 
PhenyltrimethylanuDonium chloride 



Manufacturers' Identification codes 
(according to list in table 22) 



CIB. 
CUL. 



ACY. 
CIB. 
DUP, NLC, VAC. 



ARC, ENJ, FOR, GNM, VAC. 

Am, ARC, FOR, am, vac. 



ARC, FOR, 


GNM. 






FOR. 








ONX. 








GNM. 








GNM. 








ARC. 








FOR, PG. 








ONX. 








DUP. 








ARC, FOR, 


GNM. 






JOR. 








ONX. 








FIN. 








DUP, FIN, 


ICI. 






ARC. 








FIN. 








ARC, FOR, 


HUM. 






GNM. 








AEM, VAC. 








ARC, GNM, 


ORO. 






ARC, GNM. 








ARC, VAC. 








ARC, FOR, 


GNM. 






STC. 








CRT, DEP, 


LUR, 


TXT. 




AAC, BRD, 


CUL, 


FIN, 


ONX, PG, RH, RTF, TXT, VAC, 


CUL, FIN, 


ONX, 


PCS, 


RET, WSN. 


SNW, WSN. 








FIN, ONX, 


SDH, 


WSN. 




ONX, RH. 








HUM, PCS. 









PC. 

CUL, NLC, VAC. 

CUL, ONX. 



SURFACE-ACTIVE AGENTS 



-Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, i966— Continued 



Manufacturers ' Identification codes 
(according to list in table 22) 



Non.omc Surface-Active Agent. 

»Carboxylio acid amides: 

»Carboxylic acid - alkanolamine condensates: 

»Diethanolainine condensates (amine/aoid ratio = 2/1): 

*Capric acid 

Castor oil acids 

»Coconut oil acids 

Coconut oil and tall oil acids 

Coconut oil and tallow acids 

»Laurio acid 

Laurie and nyristlo acids 

Llnoleic acid 

»01eic acid 

Palmitic acid 

Pelargonio acid 

♦Stearic acid 

*Tall oil acids— 

Unspecified mixed fatty acids 

»Dlethanolaiiilne condensates (amlne/acid ratio = l/l): 

»Coconut oil acids 

»Laurio acid 

Laurie and nyristic acids 

*01eio acid 

Palmitic and stearic acids 

♦Stearic acid 

Tall oil acids 

Tallow acids- 

Itaspeoified mixed fatty acids 

•Bthanolamine condensates (amine/acid ratio = 2/1): 

♦Coconut oil acids 

Hydrogenated castor oil acids 

Hydrogenated tallow acids 

Laurie acid 

Stearic acid 

♦Bthanolamine condensates (other amine/acid ratios): 

Coconut oil acids (amlne/acid ratio = l/l) 

Laurie and nyristic acids (amine/acid ratio = l/l)-' 

Oleic acid (amine/acid ratio = l/l) 

Stearic acid (amine/acid ratio = l/l) 

Stearic acid (amine/acid ratio = 1/2) 

♦Isopropanolamine condensates : 

Coconut oil acids 

♦Laurie acid 

Laurie and nyristio acids 

Oleic acid 

♦Other alkanolamlne condensates: 

Coconut oil acids - dlethanolamine condensate 

(amlne/acid ratio == 1.4/1). 
Coconut oil acids - dlethanolamine condensate 

(amine/acid ratio « 1/2). 
Laurie acid - dlethanolamine condensate (amlne/acid 
ratio = 1.6/1). 

Stearic acid - methanolamlne condensate 

♦Carboxylle acid - alianolamine condensates, ethoxylated 
Coconut oil acids - ethanolamlne condensate, 

ethoxylated. 
Urdrogenated tallow acids - ethanolamlne condensate, 
ethoxylated. 

Oleic acid - ethanolamlne condensate, ethoxylated 

Oleic acid - methanolamlne condensate, ethoxylated 

Tall oil acids - ethanolamlne condensate, ethoxylated 
♦Carboxylle acid - diamine and polyamine condensates 
(nonlonlc ) : 
Olelo acid - ethylenediamine condensate (amine/acid 
ratio » 1/2). 



GGY, PCS, UVC. 

ONX, PCS, VAL. 

ML, ARD, BSC, BSW, CIB, CLI, CRT, CTL, DEP, EFH, HAL, 
HLI, HRT, JOR, KNP, LUR, MOA, NOP, PC, PCS, PNX, RCD 
SBC, SEY, STP, SWT, TCC, TXC, UNN, UVC, VAC, VND, 
WIC, WTC. 

CSB. 

CLI, PC. 

ARD, CLI, DR*, NOP, ONX, PCS, PG, RCD, WTC. 

TXN. 

VND. 

CCW, CLI, HLI, UVC, VAC, STP, WTC. 

CMC. 

Qffi, PCS. 

AML, EMR, JOR, NOP, ONX, SCO, TXC, VAL, WTC. 

EFH, MRA, UVC, WTC. 

BSC, HLI. 

APX, ARD, CCL, CLI, CTL, DRW, IMK, GGY, HLI, MOA, MRV, 
NOP, ONX, PCS, PEK, QCP, RCD, RFC, RTF, SBC, SEY, 
STP, TXT, UVC, VAC. 

CTL, CUL, DRW, LEV, MOA, ONX, PCS, PG, RTF, SBC, STP, 
TXT. 

CLI, TXT. 

GGY, NOP, PCS, SBC, SCP, SWT, TCC, TXT, VAC. 

BSC, MRA, PCS. 

BSC, DEP, am, GGY, GLY, RPC, SEY, UVC. 

MRV, PCS. 

RPC. 

STP. 

CTL, PCS, RTF, STP, UVC, VND, WTC. 

GLY. 

GLY. 

CTL, WTC. 

CLI. 

HRT, MOA, PG, STP. 

TXT. 

VPC. 

MOA, VND. 

GLY, WTC. 

DSO, MOA, STP. 

ARD, CLI, MOA, PCS, WTC. 

LEV, TXT. 

WTC. 

JRG. 



WON. 

DUP, ICI. 

STP. 

ARC, NOP. 

ARC, GAF. 

QAF 

JCC. 



CCW, GLY, HDG. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 19B Surface -active agents for which U.S. production or sales were reported, identified by 

manufacturer, i 566— Continued 



Manufacturers' identification code 
(according to list in table 22) 



Sarfa 



Agen 



-Continued 



»Carboxylic acid amides— Continued 

»C'xrboxyJ.io acid - diamine and polyamine condensates 
(nonionic )— Continued 
Stearic acid - N> N'-diethylethylenediamine condensate 
(amine/acid ratio = 1/2). 
♦Stearic acid - ethylenediamine condensate (amine/acid 
ratio =1/2). 

All other 

»Carboxylic acid esters: 
»Anhydrosorbltol esters: 

Anhydrosorbitol dioleate 

Anhydrosorbitol ester of mixed fatty acids 

»Anhydrosorbitol monoester of tall oil acids 

♦Anhydrosorbitol monolaurate 

Anhydrosorbitol mono-oleate 

Anhydrosorbitol monopalmitate 

Anhydrosorbitol monostearate 

Anhydrosorbitol sesquioleate 

Anhydrosorbitol tetrastearate 

Anhydrosorbitol triester of tall oil acids 

♦Anhydrosorbitol trioleate 

Anhydrosorbitol tristearate 

♦Ethoxylated anhydrosorbitol esters : 

Ethoxylated anhydrosorbitol monoester of tall oil 
acids. 

♦Ethoxylated anhydrosorbitol monolaurate 

♦Ethoxylated anhydrosorbitol mono-oleate 

♦Ethoxylated anhydrosorbitol monopalmitate 

♦Ethoxylated anhydrosorbitol monostearate 

Ethoxylated anhydrosorbitol triester of castor 

oil acids. 
Ethoxylated anhydrosorbitol triester of tail oil 
acids. 

♦Ethoxylated anhydrosorbitol trioleate 

♦Ethoxylated anhydrosorbitol tristearate 

♦Ethylene glycol and diethylene glycol esters: 

Diethylene glycol dioleate 

Dietl^lene glycol distearate 

Diethylene glycol monoester of coconut oil acids 

Diethylene glycol monoester of tall oil acids 

♦Diethylene glycol monolaurate 

♦Diethylene glycol mono-oleate 

Diethylene glycol monoricinoleate 

♦Methylene glycol monostearate 

Diethylene glycol sesquiester of tall oil acids 

Diethylene glycol sesquilaurate 

Diethylene glycol sesquistearate 

♦Ethylene glycol distearate 

Ethylene glycol mono-oleate 

♦Ethylene glycol monostearate 

Ethylene glycol sesquistearate 

♦Glycerol esters: 

♦Con?)lex glycerol esters: 

Glycerol diacetyltartrate monostearate 

Glycerol lactate palmitate 

Glycerol lactate stearate 

Glycerol maleate mono-oleate 

Glycerol monoester, aoetylated 

Glycerol nionoester of mixed fatty acids, acetylated- 

Glycerol mono-oleate, acetylated 

♦Glycerol esters of chemically defined acids: 

Glycerol dioleate 

Glycerol distearate 

Glycerol monocaprylate 

♦Glycerol monolaurate 

♦Glycerol mono-oleate 



SNW. 












CCW, 


CTN, 


GLY, 


ICI. 






NOP. 












APD. 












GLY. 












APD, 


GLY, 


HDG, 


RTF, 


TCH. 




APD, 


GLY, 


HDG, 


PCS, 


TCH. 




AAC, 


APD, 


DRW, 


GLY, 


HAL, 


HDG, 


APD. 


GLY, 


PCS. 








AAC, 


APD, 


DRW, 


GLY, 


HDG, 


PCS. 


AAC, 


GLY. 










APD. 












GLY, 


TCH. 










APD, 


GLY, 


HDG, 


PCS, 


TCH. 




APD, 


GLY, 


HDG. 









TCH. 

AAC, APD, DRW, GLY, HDG, PCS, TCH. 

AAC, APD, ARC, DRW, GLD, GLY, HDG, PCS, TCH. 

AAC, APD, GLY, PCS, TCH. 

AAC, APD, DRW, GLY, HDG, PCS, TCH. 

APD. 

APD, RTF. 

AAC, AH), GLY, TCH. 
AAC, APD, GLY, PCS, TCH. 

GLY. 

ARC, GLY. 

MR. 

HDG. 

ARC, CCW, GLY, HAL, HDG, KAL, NOP, WTC. 

ARC, HAL, NOP, WTC. 

GLY. 

ARC, CCW, CLI, HAL, NOP, PCS, QCP, SEY, UVC, VAL, VND, 

WTC. 
QCP, WTC. 
GLY. 
WM. 

ARC, am, HAL, HDG, PCS. 
HAL. 
ARC, CCW, CLI, EFH, GLY, HAL, HDG, KNP, PCS, VND, WM. 



DRW, PCS, WTC. 
DRW, GLD. 
APD, GLD. 
NOP, WTC. 



ARC, HAL. 
APX, ARC. 
ARC, DRW. 

ARC, GLY, HAL, KNP. 

APD, ARC, CCW, DRW, EFH, HC, EMR, GLY, HAL, HDG, PCS, 
SWT, WM. 



SURFACE-ACTIVE AGENTS 



TABLE 19B.- -Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, i566— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



Agen 



-Continued 



»Carboxylio acid esters— Continued 
"Glycerol esters — Continued 

"Glycerol esters of chemically defined acids--Continued 

"Glycerol monoricinoleate 

"Glycerol raonostearate 



"Glycerol esters of mixed acids : 

Glycerol monoester of coconut oil acids 

Glycerol monoester of com oil acids 

Glycerol monoester of cottonseed oil acids 

Gljoerol monoester of hydrogenated cottonseed oil 

acids. 
Glycerol monoester of hydrogenated soybean oil 
acids. 

Glycerol monoester of lard acids 

Glycerol monoester of peanut oil acids -— 

Glycerol sesquiester of mixed fatty acids 

All other 

"Natural fats and oils, ethoxylated: 

"Castor oil, ethoxylated 



}^rogenated castor oil, ethoxylated 

Lanolin, ethoxylated 

♦Polyethylene glycol esters: 
"Polyethylene glycol esters of chemically defined 
acids: 

"Polyethylene glycol dilaurate 

"Polyethylene glycol dioleate 



"Polyethylene glycol distearate 

Polyetlvlene glycol methyloarbitol maleate- 
"Polyethylene glycol monolaurate 



♦Polyethylene glycol mono-oleate- 



Polyethylene glycol monopalmitate 

Polyetlqrlene glycol monopelargonate- 
Polyethylene glycol monoricinoleate- 
♦Polyethylene glycol raonostearate 



Polyethylene glycol sesquioleate 

"Polyethylene glycol esters of rosin and tall oil acids; 

Polyethylene glycol diester of tall oil acids 

Polyethylene glycol monoester of rosin acids 

Polyethylene glycol monoester of tall oil acids 

Polyethylene glycol sesquiester of rosin acids 

"Polyethylene glycol sesquiester of tall oil acids 

Polyethylene glycol unspecified ester of tall oil 
acids. 
"Polyethylene glycol esters of other mixed acids: 

Polyethylene glycol diester of trimerized castor oil 

acids. 
Polyethylene glycol ester of unspecified mixed fatty 

acids. 
Polyethylene glycol monoester of coconut oil acids — 
Polyethylene glycol monoester of soybean oil acids — 

Polyethylene glycol monoester of tallow acids 

Polyethylene glycol sesquiester of castor oil acids— 
•Polyethylene glycol sesquiester of coconut oil 
acids. 

Polyethylene glycol sesquiester of tallow acids 

»Polyglycerol esters: 

Polyglyoerol distearate 

Polyglyoerol lactate oleate 

Polyglycerol mono-oleate 



BAG, COW, HAL. 

ARC, CCW, CHL, CRT, DRW, EK, GLY, GRO, HAL, HDG, JRG, 

LUR, MRA, NOP, NW, PCS, PG, SNW, SWT, TCC, UVC, VND, 

WM, WTC, X. 

DRW, GLY, HDG, SWT, WM. 

GLD. 

DRW, EK, HDG, PCS. 

aLD, LEV, PCS. 

DRW, GLD. 

EK, GLD, GLY, PCS. 



APD, BAG, DRW, Uffi, GAF, GLY, ICI, NLC, 

TCH, VAC. 

APD, GAF, TCH, VAC. 

AAC, APD, DRW, PCS. 



ARC, DEX, EFH, GLY, HAL, HDG, JOR, NOP, UVC, WM. 

ARC, CLD, EFH, ENJ, GGY, GLY, HAL, HDG, NOP, PCS, UVC, 

VND, x. 
ARC, GLY, HAL, HDG, PCS, QCP. 
CCA. 
AAC, ARC, BSC, CCA, GGY, GLY, HAL, HDG, JOR, KNP, NOP, 

SYC, TCH, TXT, UVC. 
ARC, CCA, CLD, CRC, CRT, DEX, DRW, EMR, GAF, GGY, GLY, 

HAL, HDG, ICI, NOP, ONX, PCS, SWT, SYC, TCH, UVC, 

VAC, WM, WTC, X. 
APD, GLY. 
IMR. 

AAC, ARC, BAC, HAL, NOP, TCH. 
AML, APD, ARC, CRT, DEP, DEX, DRW, affi, GAF, GGY, GLY, 

HAL, HDG, ICI, KNP, NOP, ONX, PC, PCS, PD, RH, SEY, 

TCC, TCH, VND, WTC. 
PCS. 



GLY. 
NLC. 
GLY, 
APD, 
AML, 
ARC. 


SOS. 
HFC, 
APD, 


QCP. 
APX, 


DRW, 


HDG, 


MON, NOI 


GLY. 












mj. 












IMR, 
SYC. 
SOS. 
GGY, 
ARL, 


GLY, 

WTC. 
DRW, 


PCS. 
NOP, 


ONX, 


PCS, 


PG, VND. 


ONX. 












PCS. 
DRW. 
HDG, 


VND, 


WTC. 









NOP, CMC, RTF, TCH, WTC. 



160 



SYNTHETIC ORGANIC CHEMICALS, 1966 



-Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1966 — Continued 



Manufacturers' identification codes 
(according to list in table 22) 



ive /Ige 



»CaTboxylic acid esters — Ctontinued 
^Propanediol esters: 

1, 2-Propanediol distearate 

1, 3-Propanediol wonoester of coconut oil acids 

»1, 2- Propanediol monolaurate 

1, 2-Propanediol mono-oleate 

»1, 2- Propanediol monostearate 

All other 

»Other oarboxylic acid esters: 

Anhydrosorbitol glycerol monolaurate 

Coconut oil acids, ethoxylated methanol ester 

Di-isobutylene maleate 

Ethoxylated glycerol sesquiester of mixed fatty acids- 

Ethoxylated 1,2-propanedlol monostearate 

Ethoxylated sorbitol beeswax ester 

Ethoxylated sorbitol hexaester of tall oil acids 

Ethoxylated sorbitol hexaoleate 

Ethoxylated sorbitol lanolin ester 

Ethoxylated sorbitol mono-oleate 

Ethoxylated sorbitol monostearate 

Ethoxylated sorbitol oleate, acetylated 

Ethoxylated sorbitol pentaester of tall oil acids 

Ethoxylated sorbitol pentalaurate 

Ethoxylated sorbitol stearate 

Ethoxylated sorbitol tetraester of laurio and oleic 
acids. 

Ethoxylated sorbitol tetraester of tall oil acids 

Methylgluooside laurate 

Metl^lglucoside oleate 

Pentaerythrltol distearate 

Polyaliylene glycol adipate 

PolyaUtylene glycol diglycolate 

Polyalliylene glycol naphthenate 

Sucrose esters of fatty acids 

All other 

♦Ethers : 

*Benzenoid ethers: 

Alkylphenol - formaldehyde condensates, alkoxylated: 

(Mixed alkyl)phenol - formaldehyde, alkoxylated 

Nonylphenol - formaldehyde, alkoxylated 

tert-Ootylphenol - formaldehyde, ethoxylated 

Pentylphenol - formaldehyde, alkoxylated 

Diisobutylphenol, ethoxylated 

»Dlnonylphenol, ethoxylated 

»Dodeoylphenol, ethoxylated 

»Iso-octylphenol, ethoxylated 

(Mixed aliyl )phenol, ethoxylated 

(Mixed alkyl )phenol, ethoxylated, butyl ether 

(Mixed alkyl )phenoxypoly(ethyleneoxy)ethyl chloride— 
♦Nonylphenol, ethoxylated 

Nonylphenol, ethoxylated and propoxylated 

Nonylphenoxypoly(ethyleneoxy)ethyl iodide 

Pentylphenol, ethoxylated 

♦Phenol, ethoxylated 

Rienol, propoxylated 

Tetradeoylphenol, ethoxylated 

Tridecylphenol, ethoxylated 

}5/lenol, ethoxylated 

All other 

♦Nonbenzenoid ethers: 

Linear alcohols, alkoxylated: 

Decyl alcohol, ethoxylated 

Decyloxypoly(ethyleneoxy)ethyl chloride 

Decyl and octyl alcohols, ethoxylated 

♦Dodecyl alcohol, ethoxylated 

♦Hexadeoyl alcohol, ethoxylated 

♦Mixed linear alcohols, ethoxylated 



HAL. 














DHW. 














ARC, 


HAL, 


SBC, 


WM. 








ARC, 


HAL. 












APD, 


ARC, 


CCW, 


EK, OLD, GLY, HAL, 


HDG, JRG, PCS, PG. 


PCS. 














APD, 


PCS. 












JOR. 














RH. 














APD. 














APD. 














APD. 














APD, 


TCH. 












APD, 


TCH. 












APD. 














APD. 














SNW. 














APD. 














APD. 














APD. 














APD. 














APD. 














APD. 














HDG. 














HDG. 














VAL. 














PFZ. 














NLC, 


RTF. 












APD. 














SUG. 














CCW, 


STC, 


WM. 










RTF. 














NLC, 


RTF. 












SDW. 














RTF. 














r,AF, 


RH. 












GAF, 


JCC, 


STP. 










GAF, 


MON, 


PCS, 


UCC. 








APX, 


CTB, 


DRW, 


NOP, 


CMC. 






GAF. 














RH. 














GAF. 














APD, 


CIB, 


CLY, 


DOW. 


DRW, 


GAF, HPC 


JCC, MON, NLC, CMC, 


PCS, RH 


, RTF 


, STP 


, TCH 


UCC. 




RTF. 














GAF. 














RTF. 














APD, 


GAF, 


JCC, 


NOP, 


TCH, 


UCC. 




NLC. 














ORO, 


PCS. 












PCS. 














NLC. 














RH, 


VPC. 













GAF, I CI, PCS. 
GAF. 
GAF. 

AAC, APD, DRW, DUP, GAF, GLY, JCC, CMC, PCS. 

ATM, APD, CIB, I CI, NAC. 

ATM, CO, GAF, JCC, LAK, MON, NLC, PCS, RH, SHC, STP, 
TCH. UCC. 



SURFACE-ACTIVE AGENTS 



-Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1966— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



Surfa 



Agen 



-Continued 



»Ethers — Continued 

»Nonbenzenoid ethers— Continued 

Linear alcohols, alkoxylated — Continued 

Mixed linear alcohols, ethoxylated and propoxylated 

■W-Octadeoenyl alcohol, ethoxylated 

*Octadecyl alcohol, ethoxylated 

Sperm oil alcohol, ethoxylated 

Tallow alcohol, ethoxylated 

Other ethers and thloethers: 

tert-Dodecyl meroaptan, ethoxylated 

Glucose, ethoxylated 

Isodecyl alcohol, ethoxylated 

lEo-octyl alcohol, ethoxylated 

Poly(mixed ethylene, propylene )glycol 

Polypropylene glycol, ethoxylated 

Rosin alcohol, ethoxylated 

Sorbitol, ethoxylated 

Sorbitol, propoxylated and ethoxylated 

Sucrose, propoxylated 

2,4-,7,9-Tetramethyl-5-decyr.e-4,7-diol, ethoxylated-- 
»Trideoyl alcohol, ethoxylated 

Tridecyl alcohol, propoxylated and ethoxylated 

Trimethylheptanol, ethoxylated 

Trimethylolpropane, alkoxylated 

All other 

«Other nonionic surface-active agents: 

Bis(octadecenyloxypolyethylene glycol) ester of 1,6- 

hexajnethylenedicarbamic acid. 
3,5-Dimethyl-l-hexyn-3-ol 

3,6-Dimethyl-'i-octyne-3,6-diol 

Dodecylbenzenesulfonic acid - diethanolamine condensate, 

fatty acid monoester. 

Ethylene glycol dibenzenesulfonate 

Glycerol sesquiester of hydrogenated castor oil acids, 

borated and ethoxylated. 

Octyl phosphate, ethoxylated 

2,4,7,9-Tetrainethyl-5-decyne-4,7-diol 

Tri(castor oil alkyl) phosphate 



RTF, 


STP, 


WYN. 


















AAC, 


ADM, 


APD. 


CTB, 


DUP, 


GAF, 


ICI, 


NOP, 


TCH, 


VAC, 


VPC. 


APD, 


CIB, 


DUP. 


HDG. 
















DUP. 






















AAC, 


ma. 




















AAC, 


MON. 




















RH. 






















PCS. 






















GAF. 






















NIC, 


UCC. 




















NLC, 


PCS, 


RTF, 


vmj. 
















CIB, 


HPC. 




















APD, 


TCH. 




















APD. 






















APD. 






















cue. 






















AAC, 


APD, 


DRW, 


EFH, 


GAF, 


GLY, 


ICI, 


JCC, 


MON, 


NLC, 


CMC 


PCS, RTF, TCH, UCC. 














JCC. 






















UCC. 






















JCC, 


RTF. 




















SNW, 


VAC. 




















CIB. 






















cue. 






















cue. 






















MAH. 























DUP, SFA. 

cue. 

GLY. 



SYNTHETIC ORGANIC CHEMICALS, 1966 
Pesticides and Related Products 



TABLE 20B. --Pesticides and related products for which U.S. production or 
by manufacturer, 1966 



lies were reported, identified 



[Pesticides and related products for which separate statistics are given in table 20A are marked below with an 
asterisk (*); products not so marked do not appear in table 20A becaxise the reported date are accepted in confidence 
and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies 
that the manufacturer did not consent to his identification with the designated product] 



PESTICIDES AND RELATED PRODUCTS, CYCLIC 

» Fungicides: 

2,6-Bis(dimethylaininomethyl)c;yclohexanone 

5-Chloro-2-benzothiazolethiol, laurylpyridium salt- 

2,'+-Dichloro-6-(o-chloroanilino)-s-triazine 

l,A-Dichloro-2, 5 -diraethoxy benzene 

2,3-Dichloro-l,4-naphthoquinone (Dichlone) 

2,6-Dichloro-^-nitroanillne (DCNA) - 

»3 , 5-Dimethyl-l, 3, 5 , 2H-tetrahydrothladiazine-2-thior 
(D»CT). 

Diphenylammonium propionate 

3,3'-Ethylenebis(tetrahydro-4,6-dimethyl-2H-l,3,5- 
thiadiazine-2-thione ) . 

2-Heptadecyl-2-iraidazoline (Glyodin) 

2-Mercaptobenzothiazole, monoethanolamine salt 

»Mercury fungicides: 

N-(Ethylmercuri)-p-toluene sulfonanilide 

Hydroxymerourichlorophenol 

Hydroxymercurinitrophenol 

Mercurial turf fungicides 

Methylmercury quinolinolate- 
2- ( Phenylmercuriamino ) ethyl 

Phenylmercuricajranonium acetate 

Phenylmercuric borate 

Phenylmercuric hydroxide 

Phenylmercuric lactate 

Phenylmercuric naphthonate 

Phenylmercuric oleate 

Phenylmercuric propionate 

N-Phenylmercuriformamide 

Tris(2-hydroxyethyl)(phenylmercuri)aiiimonium lactate- 
2- ( 1-Methy 1-n-heptyl) -"i , 6-dlnitrophenyl crotonate 

(Dinocap) . 
3-(2-Methylpiperldino,lpropyl-3,<;-diohlorobenzoate 
(Piperalin). 

»Naphthenio acid, copper salt 

Pentachloronitrobenzene (PCNB) 

■»Pentachlorophenol (PCP) 

Pentachlorophenol, sodium salt 

*8-Quinolinol (8-Hydroxyquinoline), copper salt 

Tetrachloro-p-benzoquinone (Chloranil) 

2,3,'i,6-Tetrachlorophenol and sodium salt 

N-Trlchloromethylthio-'i-cyclohexene-l,2-dicarboximde 
( Captan ) . 

N-Trichloromethylthiophthalimide (Folpet) 

»2,'i,5-Trichlorophenol 

*2,'4,5-Trichlorophenol, ethanolamlne salt 

»2,'i,5-Trichlorophenol, sodium salt 

2,<i,6-Trlchlorophenol 

Other fungicides 

^Herbicides and plant hormones: 

•4-Amino-3,5,6-trichloropicolinic acid (Picloram) 

5-Bromo-3-sec-butyl-6-methyluracil (Bromacil) 

3-tert-Butyl-5-chloro-6-methyluracil 

N-Butyl-N-ethyl-ii,a,:i-trlfluoro-2,6-dinltro-p- 
toluidine (Benefin). 

2-Butynyl-'i-ohloro-m-chlorocarbanilate (Barban) 

2-Chloro-'i-ethylamino-6-isopropylamino-s-triazine 
(Atrazine). 

3'-Chloro-2-methyl-p-valerotoluidide (Solan) 

3-(p-Chlorophenyl)-l,l-dimethylurea (Monuron) 

3-(p-Chlorophenyl)-l,l-dimethylurea trichloroacetate-- 
3-Cyclohexyl-5,6-trimethyleneuracll 



USR. 
CWN. 
MRK, OTC, SF, WRC. 



DUP. 
DUP. 
DUP. 
MAL. 

MRK. 
CLY. 
TRO. 
TRO. 
MRK. 
U3K. 
MRK. 
CLY, HNX, MRK, TRO. 



CCA, FER, HNX, MCI, MLD, SHP, SOC, SRR, TGL, TRO, WTC. 



BXT, DOW, FRO, MON, 
DOW, MON, RCI. 
GAM, HNX, MRK. 
USR. 


RCI, 


SFD. 


CHO. 






CHO. 

DA, DOW, HK, HPC. 

BKL, GAF. 







FMN. 
DUP. 
ACN. 
DUP. 



PESTICIDES AND RELATED PRODUCTS 



-Pesticides and related products for which U.S. production or ^ 
by manufacturer, 1 966— Continued 



lies were reported, identified 



PESTICIDES AND RELATED PRODUCTS, CYCLIC— Continued 

"Herbicides and plant hormcnes--Continued 

2,6-Di-tert-butyl-p-tolyljnethylcarbamate 

2,5-Dichloro-3-ajninobenzoic acid, ammonium salt 

3,6-Dichloro-o-amsic acid (Dicamba) 

2,'*-Dichlorobenzyltributylphosphonium chloride 

2-{2,'i-Diohlorophenoxy)ethyl sulfate, sodium salt 
(Sesone) . 

2-(2,'*-Dichlorophenoxy)propionic acid ( Dichlorprop ) 

3-(3,4-Dichlorophenyl)-l,l-dimethylurea (Diuron) 

3-(3,'4-Dichlorophenyl)-l-methoxy-l-methylurea (Linuron) 
3-(3,4-Dichlorophenyl)-l-methyl-l-n-butylurea (Nebiu-on) 

2,4-Dichlorophenyl-4-nitrophenyl ether 

3','4'-Diohloropropionanilide (Propanil) 

l,2-Dihydropyridazine-3,6-dione (Maleic hydrazide) (MH)- 
N- ( beta-0, 0-Di isopropyl-dithiophosphcry lethyl ) -benzene 
sulfonamide (Bensulide). 

N,N-Dimethyl-2,2-diphenylacetamide (Diphenamid) 

l,l-Dimethyl-3-phenylurea (Fenuron) 

l,l-Dimethyl-3-phenylurea trichloroacetate 

Dimethyl-tetrachloroterephthalate 

»Dinltrobutylphenol (DNBP) 

»Dinitrobutylphenol, aramoniim salt 

Dinitrobutyl phenol, triethanolamine salt 

Dinitrocresol (DNOC) — - 

Dinitrocresol, sodium salt 

Diphenylaoetonitrile (Diphenatrile) 

2-Ethylamino-'V-isopropylamino-6-methylmercapto-s- 

triazine (Ametryne). 
S-Ethyl hexahydro-lH-azepine-l-oarbothioate (Molinate)- 

Gibberellic acid — . 

3-(Hexahydro-'l,7-methanoindan-5-yl)-l,l-dimethylurea 
(Norea). 

3-Indolebutyric acid 

Isopropyl N-phenylcarbamate (IPC) 

Isopropyl N-(3-chlorophenyl) carbamate (CIPC) 

l-(2-kfethylcyclohe)(yl)-3-phenylurea (Siduron) 

2-Met;iylniercapto-4. , 6-bis- ( isopropylamino ) -s-trlazine 

(Prometryne) . 
1-Naphthaleneacetic acid and derivatives: 

1-Naphthaleneacetamlde 

•1-Naphthaleneacetic acid (NAA) 

•1-Naphthaleneacetic acid, methyl ester 

•1-Naphthaleneacetic acid, sodium salt 

N-1-Naphthylphthalamic acid (NPA)- 

7-0xabicyclo[2.2.1] heptane-2,3-dicarboxylic acid, 

disodium salt (Endothal). 
Phenoxyacetic acid derivatives: 

'4-Chloro-2-methylphenoxyacetic acid (MCPA) 

4-Chlorophenoxyacetic acid, potassium salt 

•2,^-Dichlorophenoxyacetic acid (2,'4-D) 

•2,^-Dichlorophenoxyacetic acid esters and salts: 

2,'i-Dlchlorophenoxyacetic acid, 2-butoxyethyl ester 
2,'i-Dlchlorophenoxyacetic acid, butoxypoly- 
propyleneglycol ester. 

•2,'i-Dichlorophenoxyacetic acid, n-butyl ester 

2,'4-Dichlorophenoxyacetic acid, sec-butyl ester 

•2,'4-Dlchlorophenoxyacetic acid, dimethyl ami ne salt- 
2,'i-Dichlorophenoxyacetic acid, ethanolajnine and 
isopropanolamine salt. 

2,4-Dichlorophenoxyacetic acid, ethyl ester 

2,'i-Dichlorophenoxyacetic acid, 2-ethylhexyl ester- 

•2,'+-Dichlorophenoxyacetic acid, iso-octyl ester 

•2,A-Dichlorophenoxyacetic acid, isopropyl ester 

2,<l-Dichlorophenoxyacetic acid, lithium salt 

2,<i-Dichlorophenoxyacetic acid, sodium salt 

•2,'i,5-Trichlorophenoxyacetic acid (2,^,5-T) 

»2,'i,5-Trichlorophenoxyacetic acid esters and salts: 

2,4,5-Triohlorophenoxyacetic acid, amyl esters 

2,'i,5-Trichlorophenoxyacetic acid, 2-butoxyethyl 

ester. 
2,4,5-Triohlorophenoxyacetio acid, butoxy- 
polypropyleneglycol ester. 



HPC. 

DUP. 

DUP. 

DUP. 

RH. 

CIS, MON, RH. 

ACY, USR. 

SF. 

CWN, LIL, X. 

DUP. 

ACN. 

DA. 

CIS, DOW, FMN. 

CIS, DOW, FMN. 

CIS, DOW, FMN. 

CIS, FMN. 

CIS, FMN. 

LIL. 

GGY. 

SF. 



ARA. 
PPG. 
PPG. 



AMC, 
AMC. 
AMC, 
USR. 
PAS. 


COK, THM. 
BKL. 








CHC, 
GTH. 
CHC, 


CLY, RIV. 
DA, DOW, HPC, 


MON, 


THM, 


TMH 



DA, DOW, HPC, MR, MON, RIV. 

MON. 

AMC, CHC, DA, DOW, HPC, RIV, TMH. 



HPC. 
DOW, MON, RIV. 
CHC, DA, DOW, HPC, MON. 
RIV. 



DOW, HPC, MON, THM. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



-Pesticides and related products for which U.S. production or sales 
by manufacturer, 1966 — Continued 



reported, identified 



Chemical 






Manufacturers' identification codes 






(according to list 


in table 22) 


PESTICIDES AND RELATED PRODUCTS, CYCLIC— Continued 










•Herbicides and plant hormones- -Continued 










Phenoxyacetic acid derlvatives--Continued 










»2,'l,5-Trichlorophenoxyacetic acid esters and 










salts— Continued 










»2,4,5-Trichlorophenoxyaoetlo acid, ii-butyl ester— 


DA, 


DOW, 


HPC, MON, RIV. 




2,';,5-Trichlorophenoxyacetlo acid, 2-ethylhexyl 


DA, 


HPC. 






ester. 










»2,'i,5-Triohlorophenoxyacetlc acid, iso-octyl ester- 


DOW, 


MON, 


RIV.TMH. 




2,'i,5-Trichlorophenoxyacetio acid, triethyl amine 


DOW, 


HPC, 


RIV. 




salt. 










itpV,„„„i__T,n,iT^ ftr-fi+n + p CPMA'^ -_-- - 


BKM, 


CLY, 


MRK, TRO, WRC. 




■*rnenyjjnercury ace Late v^wm.; — 




Polychloro-tetrahydro-methanoindene ( Polychlorodi- 


VEL. 








cyclopentadiene) isomers. 










N m Tolyl phthalamic acid - -- - 


USR. 












2-(2,'i,5-Trichlorophenoxy)propionic acid (Silvex) 


DOW, 


HPC 






2-{2,'i,5-Trichlorophenoxy)propionic acid, 2-ethylhexyl 


HPC. 








ester. 










2-(2,'l,5-Trichlorophenoxy)propionic acid, isooctyl 


RIV. 








ester. 










y. , a,o<-Trif luoro-2 , 6-dinltro-N, N-dipropyl-p-toluidine 


LIL. 








(Trifluralin). 










Tris-(2,';-dichlorophenoxyethyl)phosphite (2,4-DEP) 


USR. 








Insect attractants: tert-Butyl 4(or 5)-chloro-2- 


TBK. 








methylcyclohexanecarboxylate (Trimedlure) . 










•Insecticides: 










AT lii+ViT'T Ti (■qTIt/I hnT«nlr\ff r\f^ C^T\e>yA-n T\ 


BPC. 








AJ.iexnrin vaiiyi nomoiog oi uinerin i; — 






ore. 


X. 






j-sec-iUnyipnenyi-N-meTinyicarDajnaue ------ 




Benzyl thiocyanate 


HK. 








2-sec-Butyl-^ , 6-dinitrophenyl-3 ,3-dijiietliylacrylate 


FMJ, 


fMP 






(Binapacryl) . 










Chlorinated insecticides: 










•Aldrin-toxaphene group: 










Heptachloro-tetrahydro-endo-methanoindene 


VEL. 








(Heptachlor). 










Hexachloro-epoxy-octahydro-endo-endo-di- 


SHC, 


VEL 






methanonaphthalene ( Endrin ) . 










Hexaohloro-epoxy-octahydro-endo-exo-di- 


SHC. 








methanonaphthalene (Dleldrin) . 










Hexachloro-hexahydro-endo-exo-dimethanonaphthalene- 


SHC. 








(Aldrin). 










Octaohloro-hexahydro-methanoindene (Chlordan) 


VEL. 
HN. 








Terpene polychlorlnates — 




Trtvnr\hon» ^ Phi (-lT•^ nn+AH /^ftrnnh^mo ^ - 


HPC. 








loxapnene ^uniorinatea cainpnene ; 




2,2-Bis(p-chlorophenyl)-l,l-dichloroethane(DDD) (TDE) 


ACN, 


RH. 






l,l-Bis(p-ohlorophenyl)-2-nitrobutane 


CCM. 










CM. 












»o.-Bls(p-chlorophenyl) p, p,p-trlchloroethane (DDT) 


ACN, 


DA, 


LEB, MTO, OMC. 




2-(p-tert-Butylphenoxy)isopropyl-2'-ohloroethyl 


USR. 








sulfite. 










2-(2-{p-tert-Butylphenoxy)-l-methylethoxy)-l- 


USR. 








methylethyl-2-chloroethyl sulfite. 










Chlorobenzilate - - — 


GGY. 








p-Chlorophenyl p-chlorobenzenesulfonate (Ovex) 


AMP, 


CIS 


DOW. 




r\ rhl m.r.r^hf.nvT M mfi+hvl f^ofhomnt p - 


OTC. 








o-uni-oropnenyi-M-meT/nyxcaruamaut: 




p-Chlorophenyl 2,'i,5-trichlorophenyl sulfone 


FMN. 








(Tetradifon). 










Deoachlorooctahydro-l,3,4-metheno-2H-cyclobuta [cd] 


NAC. 








pentalene-2-one . 










l,l-Dlchloro-2,2-bis(p-ethylphenyl)ethane 


RH. 








'l,4'-Dichloro-a-trlohloromethylbenzhydrol (Dicofol) — 


RH. 








Dodecachlorooctahydro-l,3,'i-metheno-2H-cyclobuta [ cd ] 


NAC. 








pentalene (Mirex). 










»Hexachlorocyolohexane (Benzene hexachlorlde) (BHC) — 


DA, 


HK, PPG. 




»Hexachlorocyclohexane, 100* y-lsomer (Lindane)- 


HK. 








Hexaohloro-hexahydro-methano-benzodioxathlepine 


HK. 








3-oxide (Endosulfan) . 










1,1, l-Trichloro-2 , 2-bis ( p-methoxyphenyl ) ethane 


CHT, 


DUP 






(Methoxychlor). 










N,N-Diethyl-iii-toluamide (DEET) - 


HPC, 


PFZ 








MGK. 
CIS, 








ui-n-propyi isocxncnomeronate — ---- — ------ 


HPC 






Isobomyl thiocyanoacetate — —------———--- 




2-Methyl-2- (methyl thlo)proplonaldehyde 0-methyl- 


UCC. 








carbamoyl oxlme. 










1-Naphthyl N-methylcarbamate (Carbaryl) 


ucc. 









PESTICIDES AND RELATED PRODUCTS 



TABLE 20B. --Pesticides and related products for which U.S. production or sales were reported, identified 
by manufacturer, i 966— Continued 



Chemical 






Manufacturer^ 


' identification codes 






(according 


to list in table 22) 


PESTICIDES AND RELATED PRODUCTS, CYCLIC-Contlnued 










"Insecticides— Continued 










»Organcphosphorus insecticides; 










A-tert-Butyl-2-chlorophenyl methyl methylphos- 


DOW. 








phoramidite. 










S-[[(p-Chlorophenyl)thio]methyl] 0,0-diethyl 


SF. 








phosphorodithioate (Carbophenothion) . 










0,0-Diethyl 0-3-chloro-<;-methyl-l-oxo-2H-l- 


CHG. 








benzopyran-7-yl phosphorothioate (Coumaphos). 










Diethyl-l-(2,4-dichlorophenyl)-2-chlorovinyl 


SHC. 








phosphate. 










0,0-Diethyl 0-(2-isopropyl-";-methyl-6-pyrimdinyl) 


GGY. 








phosphorothioate ( Diazlnon ) . 










0,0-Diethyl 0-p-{methylsulfinyl)phenyl phos- 


CHG. 








phorothioate . 










»0,0-Diethyl O-p-nitrophenyl phosphorothioate 


AMP, 


MDN, 


SF, SHC. 




(Parathion). 










0,0-Dijiiethyl S-(p-ohlorophenylthlo)methyl phos- 


SF. 








phorodithioate. 










0, 0-Dlmethyl 0- [i- (methylthio) -m-tolyl] phos- 


CHG. 








phorothioate (Fenthion). 










»0,0-Dijnethyl 0-p-nltrophenyl phosphorothioate 


AMP, 


MON, 


SF, SHC. 




(Methyl parathion) . 










0,0-Dimethyl S-[4-oxo-l,2,3-benzotriazin-3(4H)- 


CHG. 








ylmethyl] phosphorodithioate. 










0,0-Dimethyl S-phthalimidomethyl phosphorodithioate- 


SF. 








Dimethyl 2,<;,5-triohlorophenyl phosphorothionate 


DOW. 








(Ronnel). 










2,3-p-Dioxane S,S-bis(0,0-diethylphosphorodithioate) 


HPC. 








(Dioxathion) . 










O-Ethyl O-p-nitrophenyl phenylphosphonothioate (EPN) 


SF. 








a-Methylbenzyl 3-(dtmethoxyphosphinyloxy)-cis- 


SHC. 








crotonate. 










0,0,0',0'-Tetramethyl Q,0'-Thiodi-p-phenylene 


ACY. 








phosphorothioate. 










All other organophosphorus insecticides 


SF. 








Nematocides: 










0,0-Diethyl 0-(2,4-diohlorophenyl) phosphorothioate— 


SM. 








0,0-Diethyl 0-2-pyrazinyl phosphorothioate (Thionazin) 


ACY. 








»Rodenticides: 










3-(a-Acetonylben2yl)^-hydroxycoumarin (Warfarin) 


MOT, 


PEN. 






2-Plvaloyl-l,3-indandione (Pindone) 


MOT, 


PIC. 






Other rodenticides— - - - - - --- 


AKC, 


NES. 






Synergists: 










a-[2-(2-n-Butoxyethoxy)-ethoxy]^,5-methylenedioxy-2- 


FMN, 


FMP. 






propyltoluene (Piperonyl butoxide) . 










N-(2-Ethylhexyl)bicyclo(2.2.1)-5-heptene-2,3- 


M3K. 








dlcarboximide. 










Other synergists --- 


CTN. 












PESTICIDES AND RELATED PRODUCTS, ACYCLIC 










»Fungicides: 










3^g_2^ ^-bromoacetoxy-2-butene— — - -— 


VIN. 
MAL. 








Cadmium succinate 








l-Chloro-2-nitropropane (Korax) 


FMN, 


FMP. 






rVfBrvUnm pvnnnHI thi ^^^In^ HnnoT'hnnoto 


BKM. 








L/iHoaium cyanuQi LnaoimiaucarDonaT>e — -- 




Dlthiocarbamic acid fungicides: 










»Dimethyldithiocarbamio acid, ferric salt (Ferbam)-- 


DUP, 


FMN, 


RBC, WRC. 




Dimethyldithiocarbamic acid, manganese salt 


FMN. 








Ethylene bis( dlthiocarbamic acid), dlammonium salt— 


CIS, 


RBC. 






'Ethylene bis(dithiocarbamic acid), disodium salt 


CIS, 


DUP, 


FMN, RH. 




(Nabam). 










Ethylene bls(dithiocarbainio acid), manganese salt 


CIS, 


DUP, 


RH. 




(Maneb) . 










-Ethylene bis(dithiocarbamic acid), zinc salt 


CIS, 


DUP, 


FMN, RH. 




(Zineb). 










Polyethylenethiuram disulfide (PETD) 


FMN. 








Other dlthiocarbamic acid fungicides 


VNC. 
ACY. 








n-Dodecyl^uanldine acetate (Dodine)— - -_-— 








Mercury fungicides: 










TRO. 












Ethylmercuric chloride---------- ----------- .. 


DUP. 
DUP. 








Ethylmercuric phosphate 









SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 20B. 



-Pesticides and related products for which U.S. production or sales were reported, identified 
by manufacturer, i 566— Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



PESTICIDES AND RELATED PRODUCTS, ACYCLIC— Continued 

»Fungicides--Continued 

Mercury fungicides — Continued 

3-Methyl(mercurithio)-l,2-propanediol 

Methylmercuric acetate 

Methylmercuric hydroxide 

All other acyclic fungicides: 

Dimethyl thiocarbonyl disulfide 

2-Propene-l, 1-dlol diacetate 

Other- - 

^Herbicides and plant hormones: 

Cacodylic acid 

2-Chloroallyl diethyldithiocarbamate (CDEC) 

2-Chloro-N,N-diallylaoetamide (CDAA) 

2,3-Dlchloroallyl diisopropylthiolcarbamate (Diallate) 

2,2-Dichloroproplonic acid, sodium salt (Dalapon) 

N-Dlmethylamlno succlnamic acid 

S-Ethyl dl-N,N-propylthiocarbamate (EPTC) 

Ethyl xanthogen disulfide 

Methanearsonic acid, dlsodium salt (DSMA) 

Methanearsonic acid, dodecyl- and octylaramonium salts- 
Methane arsonlc acid, sodium salt (M3MA) 

S-Propyl butylethylthiooarbamate (Pebulate) 

S-Propyl dipropylthlocarbamate (Vemolate) 

S,S,S-Trlbutyl phosphorotrithioate 

Tributyl phosphorotrithioate 

Trichloroacetic acid, sodium salt (TCA) 

S-2,3,3-Trichloroallyl N,N-diisopropylthiolcarbamate 
(Tri-allate). 
"Insecticides: 

2-(2-Butoxyethoxy)ethyl thiocyanate 

Butoxy polypropylene glycol 

Metaldehyde 

»Organophosphorus insecticides: 

S-[l,2-Bis(ethoxycarbonyl) ethyl] 0,0-dimethyl 
phosphorodlthioate (Malathion) . 

2-Carbomethoxy-l-propen-2yl dimethyl phosphate 

l,2-Dibromo-2,2-dichloroethyl dimethyl phosphate 

(Naled). 
0,0-Diethyl S-2-(ethylthlo) ethyl phosphorodlthioate 

(Disulfoton) . 
0,0-Diethyl 0-2-(ethylthio)ethyl phosphorothloate 

(Demeton 0) . 
0,0-Dlethyl S-2-(ethylthio)ethyl phosphorothloate 

(Demeton S). 
0,0-Diethyl S-(ethylthlo)methyl phosphorodlthioate 

(Phorate). 
3-(Dimethoxyphosphinyloxy)-N,N-dlmethyl-cis- 

orotonamlde . 
0,0-Dimethy 1-0-2, 2-dichlorovinyl phosphate (DDVP) — 
0,0-Dimethyl S-(N-methyloarbamDylmethyl) phos- 
phorodlthioate (Dimethoate). 
Dimethyl phosphate of 3-hydroxy-N-methyl-cls- 

crotonamide . 
S-t2-(Ethylsulflnyl)ethyl] 0,0-dimethyl phos- 
phorodlthioate (Oxydemetonmethyl) . 
0,0,0',0'-Tetraethyl S,S' -methylene bls-phos- 
phorodithioate (Ethion). 

"Tetraethyl pyrophosphate (TEPP) 

Tetra-n-propyl dithlopyrophosphate 

2-Thlocyanoethyl dodecanoate 

Other acyclic insecticides 

»Rodentioldes : Sodium fluoracetate 

»Soil conditioners: Polyaorylonltrile, hydrolyzed, 
sodium salt. 



DUP 
DUP. 

MRT. 

CLY. 
SHC. 
BFG. 

ASL. 

MDN. 

MON. 

MON. 

DOW. 

USR. 

SF. 

RBC. 

ASL, CLY. 

CLY, VIN. 

VIN. 

SF. 



CHG. 

CHG. 

CHG. 

ACY. 

SHC. 

SHC. 
ACY. 

SHC. 

CHG. 

FMN, FMP. 

ALC, AMP, OTH. 

SF. 

RH. 

HK, x. 



PESTICIDES AND RELATED PRODUCTS 



TABLE 20B. 



-Pesticides and related products for which U.S. production or sales were reported, identified 
by manufacturer, i 966— Continued 



PESTICIDES AND RELATED PRODUCTS, ACYCLIC—Continued 



Manufacturers' identification codes 
(according to list in table 22) 



»Soil fumigants: 

2-Anilnobutane carbonate 

»l,2-Dibromo-3-chloropropane (DBCP) 

1,3-Dichloropropene 

1,3-Diohloropropene, 1,2-dichloropropane 

»Methyl bromide ( Bromomethane ) 

N-Methyldithlocarbamic acid, sodium salt (Metham)- 

Trichloronitromethane (Chloropiorin) 

All other soil fumigants 



LIL. 

AMP, EST, DOW, SHC. 

DOW. 

DOW, SHC. 

AMP, DOW, FRO, GIL, MCH. 

DUP, SF. 

DOW, mc. 

SF. 



SYNTHETIC ORGANIC CHEMICALS, 1966 
Miscellaneous Chemicals 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1966 

Miscellaneous chemicals for which separate statistics are given in table 21A are marked with an asterisk (»); 
chemicals not so marked do not appear in table 21A because the reported data are accepted in confidence and may not 
be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 

Manufacturers' identification codes 
(according to list in table 22) 

MISCELLANEOUS CHIMICALS, CYCLIC 



6-Acetoxy-2,4-dimethyl-m-dioxane 

Adenosine phosphates 

2-Aminobenzothiazole 

S-Amino-'ije-dimeroapto-ljSjS-triazine 

l-(2-Aminoethyl)piperazine 

l-(3-Aminopropyl)morpholine 

Anisaldehyde bisulfite — 

Arylalkyl phosphites - 

Barium octylphenate 

Benzoic acid salts: 

Aluminum benzoate 

Cobalt benzoate 

»Sodiu]n benzoate, tech 

»Sodium benzoate, U.S.P 

p-Benzoquinone (p-(Jiinone) 

Benzothiazole 

*Benzoyl peroxide 

Biological stains 

Bis(2,<i-dichlorobenzoyl) peroxide 

2,'i-Bis(4-hydroxy-3,5-di-tert-butyl-phenoxy)-6-(n-octyl- 
thio)-l,3,5-triazine. 

Bis(2-hydroxypropoxyphenyl)methane 

2,4-Bis(n-octylthio)-6-('i'-hydroxy-3',5'-di-tert-butyl- 
anilino)-l,3,5-trlazine. 

Boron fluoride -phenol complex 

*Butyl benzoate 

p-tert-Butylbenzoic acid, barium bis-salt 

n-Butylferrocene 

2 (and 3)-tert-Butyl-'i-methoxyphenol 

p-tert-Butyl-a-methylcinnamaldehyde 

tert-Butyl peroxybenzoate 

4-tert-Butylphenyl salicylate 

4-tert-Butylpyrocatechol 

Camphene 

Cellulose acetate phthalate 

Centralite-1 (N, N'-Diethyl-N,N'-diphenylurea) 

Chemical indicators 

Chemical reagents 

Chloramine B (Sodium derivative of N-ohlorobenzene sul- 
fonamide ) . 

Chlorinated terphenyls 

2-Chloroacetophenone 

l-(3-Chloroallyl)-3,5,7-triaza-l-azon iaadamantane chlo- 
ride. 

(o-Chlorobenzylidene)malononltrile 

5-Chloro-2-hydroxybenzophenone 

Chlorophyllin, sodium -potassium-copper 

Cobalt phthalocyaninedisulfonic acid 

Cumene hydroperoxide 

Cyclohexanone peroxide 

Cyolohexene-l,2-dlcarboxylic acid ( Tetrahydrophthalio 
acid) disubstituted, polyester salts: Barium and 
cadmium salts. 

1,'i-Cyolohexylenedimethanol 

♦Cyclopropane 

Cytldlne and derivatives 

Decahydronaphthalene (Deoalin) 

Decyl diphenyl phosphite 

Dehydroacetic acid, and sodium salt 

2,5-Di-tert-amylhydroquinone 

Dlazodinltrophenol 



ACY. 
JCC. 
JCC. 
GIV. 
WES. 
CCA. 



HK, HN, MON, PFZ, VEL. 

EKT. 

ACY. 

A2T, 

HLC, 

CAD. 

GGY. 



ACQ. 
FRO, 
CCA. 
ARA. 
EKT. 
GIV. 
WTL. 
DCW. 
BKL, 
GLD, 



OTC, 
EK, 
ACG, 
NES. 

KPS. 

GAM. 
DOW. 



KCH. 



PAS. 
HLC, LAM, NAC. 
CLB, EK, GFS, HLC, LAM, NAC, PIC. 



NAC. 

HPG, RCI. 
CAD, WTL. 
RCI. 



EKT. 

MAL, OH, QMS, TAE. 

PIB. 

DUP. 



GAN. 
EKT. 
HPC. 



MISCELLANEOUS CHEMICALS 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 7 566 --Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, CYCUC--Continued 

2,4-Dibenzoylresorcinol 

l,3-Dibromo-5,5-dimethylhydantoin 

2,6-Di-tert-butyl-p-cresol: 

*Food grade 

»Tech 

Di-n-butylferrocene 

2,5-Di-tert-butylhydroqulnone 

Dl-tert-butyl peroxyphthalate 

2,^-Dichlorobenzoyl peroxide 

l,3-Dichloro-5,5-dlmethylhydantoln 

Dichloro-s-triazine-2,<i,6(lH,3H,5H)trione (Dlchloroiso- 
cyanuric acid), potassium and sodium salts. 

Dicyclohexylammoniuni nitrite 

Didecyl phenyl phosphite 

N, N-Diethyl-p-phenylenediamine 

Digitonin -- 

2,5-Dihydroxybenzenesulfonic acid 

2,2'-Dlhydroxy-'i,'V' -dlmethoxybenzophenone 

2,6-Dihydroxylsonlcotinic acid (2,6-Dihydroxy-A-carboxy- 
pyridine). 

2,2' -Dihydroxy-A -methoxybenzophenone 

2,2'-Dihydroxy-4-(octadecyloxy)benzophenone 

3,5-Diiodosalicylic acid 

Diisopropylbenzene hydroperoxide 

Diisopropyl-m,p-cresols 

»p-Dimethoxybenzene (Dimethyl ether of hydroquinone ) 

a,a-Dimethylbenzyl hydroperoxide 

2,5-Dimethyl-2,5-dl(peroxyphenyl)hexane 

2,5-Dlmethylhexane-2,5-diperoxybenzoate 

2,6-Dimethylmorpholine 

4,4^-Dinitrocarbanilide-'4,6-dimethyl-2-pyTimidinol 

Dl-n-ootadecyl 3,5-di-tert-butyl-'i-hydroxyphenyl phospho 
nate. 

Dioxane (1,4-Diethylene oxide) 

2,5-Diphenyl-p-benzoquinone 

Dithioaramilide, monoethanolamine salt 

4-(Dodecyloxy)-2-hydroxybenzophenone 

Enzymes : 
Ifydrolytio : 

Amylases 

Proteases 

Other 

Nonhydrolytic 

l,2-Iiioxy-3-phenoxypropane (Glycidyl phenyl ether) 

6-Ethoxy-m-anol ( Propenylmethylguaethol ) 

Ethyl cellulose phthalate 

2-Bthylhexyl octylphenyl phosphite 

Ethyl hydrocaffeate 

<^-Ethylmorpholine 

Ferrocene 

•Flotation reagents : 

Dicresylphosphorodlthioic acid (Dicresylthiophosphorio 
acid). 

Dicresylphosphorodlthioic acid, ammonium salt 

Dicresylphosphorodlthioic acid, sodium salt 

2, 2' -Dimethyl thiocarbanillde (Dl-o-tolyl thiourea) 

Rosin amines 

Thiocarbanillde (Diphenyl thiourea) 

Fluorinated benzenoid chemicals 

Furan derivatives : 

2-F\iTaldehyde (Furfural) 

Tetrahydrofurfuryl alcohol 

Gallic acid - 

•Gasoline additives : 

N,N'-Bis{l,<l-dimethylpentyl)-p-phenylenediamine 

2,6-Di-tert-butylphenol 

N,N-Di-sec -butyl -o-phenylenedlamine 

»N,N'-Di-sec-butyl-p-phenylenedlamine 

N, N'-Dlisopropyl-p-phenylenediamine 



CAT, EKT, HPC, KPT, SHC. 

CAT, EKT, HPC, KPT, PRD, SHC. 

ARA. 

EKT. 

WTL. 

WTL. 

GLY. 

MON. 



ACY. 






MET. 






HPC. 






GIV. 






ASL, 


EKT, GAF, 


ICO, TBK. 


ACP. 






WTL. 






UPR. 






DOW. 






MRK. 






GGY. 






DOW, 


UCC. 




EKT. 






ACY. 






DUP, 


EKT. 




BAX, 


CRN, QMS, 


PMP, RH, WBC 


BAX, 


PFZ, PMP, 


RH, WBC. 


MLS, 


RH, WBC. 




PLB, 


WBC. 




SHC. 






ICO. 






EK. 






X. 






ICO. 






JCC, 


UCC. 




ARA. 






ACY. 






ACY. 






KCU. 






DUP. 


RBC. 




HPC. 






ACY, 


MAC. 




PIC. 






QKO. 






QKO. 






MAL. 






EKT. 






SHC, 


TNA. 




DUP, 


EKT. 




DUP, 


EKT, UPM. 




DUP, 


EKT. 





SYNTHETIC ORGANIC CHEMICALS, 1966 



■ -Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 566 --Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CIQMICAI^, CYCLIC— Continued 

•Gasoline additives— Continued 

»N,N'-Dlsalicylidene-l,2-propanediamine 

Methylcyclopentadienylmanganese tricarbonyl 

'i,^'-Methylenebis(2,6-di-tert-butylphenol) ■ 

2,2'-Thiobis[6-tert-butyl-<;-methylphenol] ■ 

Glyceryl p-aminobenzoate 

Glyceryl tribenzoate 

Guanosine phosphates 

5,6,7,8,9,9-Hexachloro-l,2,3,4,Aa,5,8,8a-ootahydro-5,8- 
methano-2,3-naphthalic anhydride (Cloran). 

*Hexamethylenetetrainine, tech 

o-(2-Ifydroxy-p-anisoyl )benzoic acid 

N-(2-Hydroxyethyl)gentisamlde 

2-Ifydroxy-A-methoxybenzophenone 

2-Ifydroxy-'4-methoxy-5-sulfobenzophenone trihydrate 

2-(2'-Hydroxy-5'-inethylphenyl)benzotriazole 

2-itfdroxy-^-n-octoxybenzophenone 

Hydroxyphenylbenzotriazole derivative 

2-(2-ffydroxyphenyl)-<i(3)-qUinazolone 

1-Ifydroxy -2 -pyridine (Onadine) 

2-Imidazolidinethlone (1,3 -Ethylene -2 -thiourea)--- --- 

Inosine and phosphates 

lEoamyl p-dimethylaminobenzoate 

Isooyanuric acid 

Isophorone 

Isopropyl-o-cresol 

p-Isopropyl-a-methylcinnamaldehyde 

Isopropylmorpholine 

Ketene, dimer 

♦Lubricating oil and grease additives: 

Chlorosulfurized and sulfurized compounds : 

Liquid disulfide — 

Tall oil ester, sulfurized 

Terpenes, sulfurized 

All other 

Oil-soluble petroleum sulfonates: 

Oil-soluble petroleum sulfonate, ammonium salt 

•Oil-soluble petroleum sulfonate, barium salt 

•Oil -soluble petroleum sulfonate, calcium salt 

•Oil-soluble petroleum sulfonate, sodium salt 

All other 

Phenol salts : 

Barium salt of dodecylphenol 

Barium salt of nonylphenol 

Calcium salt of octylphenol-fonnaldehyde 

Calcium salt of polypropylphenol 

All other phenol salts 

All other - - — 

Waleic anhydride half esters, vinyl ether copolymers 

p-Menthane 

8-p-Menthyl hydroperoxide 

p-Methoxybenzylldenemalonlc acid, dimethyl ester 

4-Methoxyphenol 

2-Kfethylazlridine 

2,2' -Methylenebis[ i-chlorophenol ] (Dlchlorophene ) 

Methylenebis[5,5-dlmethylhydantoin]--- 

2,2'-Methylenebls [3,'i,6-trlchlorophenol] (Hexachlor 
2,2' -Me thylendi -p-cresol (Bis ( 5 -methyl-2-hydroxyphenyl ) - 
methane ) . 

Methyl gallate - - -- 

Methylglucoslde- - -- - 

'i-Methylmorpholine 

5-Methyl-5-norbomene-2,3-dlcarboxyllo anhydride (Methyl- 
bioyolo(2 .2.1] hept-5-ene-2, 3-dloarboxyllc anhydride ) . 

Methyl phenyl phosphates 

l-Methyl-2-pyrrolldone, monomer 

Methyl triphenyl phosphonium bromide 

Methyl vinyl ether-toluene polymer 

Methyl vinyl ether-xylene polymer 



DUP, EKT, TX, UFM, X. 

TNA. 

ENJ, SHC, TNA. 

CAT. 

VND. 
VEL. 
PLB. 
WSN. 

BOR, DUP, HKD, HMP, HN, PIS, UCC. 

ACY. 

ICO. 

ACY, GAF. 

ACY. 

GGY. 

ACY. 

GGY. 

QMC. 
PAS. 
PIB. 
VND. 
MON. 
UCC. 



SIN. 

CO, LUB, TX, X. 

CO, ENJ, LUB, ORO, SHO, SON, TX. 

CO, ENJ, MOR, NOP, PAH, SHO, SOC, SOI, SON, TX. 

CO. 

TX. 
CCA. 
SHC. 
ORO. 



ENJ, 
GAF. 
HPC. 
HNW, 
ACY. 
ASL, 
ICO. 
GIV. 
GLY. 
GIV. 
GIV. 



CRN. 

JCC, UCC. 
ICO. 

TNA. 
GAF. 
ALD. 
OAF. 
GAF. 



LUB, MON, 
LUB, MON, 



MISCELLANEOUS CHEMICALS 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 966— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



mSCELUmWS chemicals, cyclic— continued 

»Morpholine 

Morpholine salt of p-toluenesulfonic acid 

»Napthenic acid salts : 

Aluminum naphthenate 

Barium naphthenate 

Cadmium naphthenate 

*Calcium naphthenate 

Cobalt lead manganese naphthenate 

♦Cobalt naphthenate 

»Iron naphthenate 

Lead manganese naphthenate 

»Lead naphthenate 

Lithium naphthenate 

♦Manganese naphthenate 

Nickel naphthenate 

Rare' earths naphthenate 

Sodium naphthenate 

Strontium naphthenate 

♦Zinc naphthenate 

o-Nltrobenzoic acid and sodium salt 

Norbomane-2-methanol (Bloyolo(2,2, 1 ) -heptane -2 -methanol ) - 
5-Norbomen-2-ylmethyl acrylate ( Bicylo[ 2.2.1 ]-hept-5- 
ene-2-methylol acrylate). 

l-0ctad€cenyl-2-naphthenyltetrahydropyTimidine 

Octadecyl 3 - ( 3 , 5 -di -tert-butyl -4 -hydroxyphenyl ) -propionate 

Octylphenol cyclotetrasiloxane 

Organic mercury compounds: 

Phenyl mercuric borate 

Other - - - 

1,10-Phenanthroline 

p-Phenolsulfonic acid 

Phenolthiosulfonic acid 

2-Phenoxyethanol (Ethylene glycol monophenyl ether) 

2-(2-Rienoxyethoxy)ethanol (Diethylene glycol phenyl 
ether). 

2,2'-(p-Phenylene)diethanol 

Phenyl hydrogen phosphate 

5-Phosphonylribose l-pyrophosphate 

Photographic chemicals : 

N-(o-Acetamidophenethyl)-l-hydroxy-2-naphthamide 

2-(4.-Amino-N-ethyl-m-toluidino)ethanol 

♦Benzotrlazole 

p-Benzylnmi nophenol hydrochloride 

Catechol ( Pyrooatechln ) 

3-Chloro-A-dlethylamlnobenzenediazonlum chloride (p- 
Diazo-2-chloro-N,N-diethylanlline) - zinc chloride. 

Chlorohydroquinone 

2, A-Dinmi nophenol dihydrochloride (Amidol) 

2[N-(2,'V-Dl-tert-araylphenoxyaoetyl) amldo]-^,6-dichloro- 

5-methylphenol . 
2, 5-Dlbutoxy-A-morpholinobenzenedlazonium chlorozlncate- 

4-Diazo-l-morphollnobenzene 

*2, 5-Dlethoxy-4-morpholinobenzenedlazonlum ohlorozincate- 
*p-Diethylamlnobenzenediazonlum chloride (p-Diazo-N,N- 
dlethylanlline) - zinc chloride. 
p-Dlethylaminobenzenediazonlum (p-Dlazo-N,N-diethyl- 
aniline) fluoroborate. 

N,N-Dlethyl-p-phenylenediamlne hydrochloride 

»N, N-Diethyltoluene-2,5-diamlne, monohydroohlorlde 

2,5-Dlhydroxybenzenesulfonlc acid 

2,7-Dlliydroxy-3,6-naphthalene sulfonate 

p-Wmethylaminobenzenedlazonlum chloride (p-Dlazo-N,N- 

dtmethylanlllne ) - zinc chloride. 
4- (2 ' , 6 ' -Dlmethylmorphollnyl )benzenediazonium chloride - 
zinc chloride. 



HSH, WTC. 

CCA. 

CCA. 

CCA, CCC, FER, HNX, HSH, MCI, MID, SHP, SOC, SRR, SW, 

TRO, WTC, X, X. 
HNX, HSH. 
CCA, CCC, FER, HNX, HSH, MCI, MID, MON, SHP, SOC, SRR, 

SW, TRO, WTC, X, X. 
CCA, CCC, HNX, HSH, MCI, MID, SOC, WTC. 
CCA. 
CCA, CCC, CCW, FER, HNX, HSH, MCI, MID, SHP, SOC, SRR, 

SW, TRO, WTC, X, X. 
CCA. 
CCA, CCC, FER, HNX, HSH, MID, SHP, SOC, SRR, SW, TRO, 

WTC, X. 
CCA. 

CCA, HNX. 
CCA. 
CCA. 
CCA, CCC, FER, HNX, HSH, MCI, MID, SHP, SOC, SRR, SW, 

TRO, WTC. 
WAY. 
ICO. 
ICO. 



GAF. 

DOW, JCC. 
DOW. 



EKT. 








EKT. 








EK, 


FMT, 


UEE, 


MRT. 


EK. 








KPT. 








FMT, 


IDC. 






EK. 








VPC. 








IDC. 








ESA, 


Fwr, 


IDC. 




PMT. 








ESA, 


Fvr, 


GAF, 


IDC 


JMT, 


OAF, 


IDC, 


MRT 


IDC. 








EKT, 


FMT. 






EKT, 


FMT, 


mc. 




EK. 








FMT. 








mr, 


IDC. 







172 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 566- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHBGCALS, CYCLIC— Continued 

Photographic chemicals— Continued 

p-Diphenylaminediazonium sulfate 

p-(N-Ethylbenziiiiido)benzenediazonium chloride (p-Diazo- 

N-benzyl-N-ethylaniline) - zinc chloride, 
p- rEthyl(2-hydroxyethyl)amlno]benzenediazonium chloride 
(p-Diazo-N-ethyl-N-hydroxyethylaniline) - zinc 
chloride . 

N-Ethyl-N-hydroxyethyl-p-phenylenediamine sulfate 

N-Ethyl-N-(|J-methanesulfonamidoethyl)toluene-2,5-dlamine 
sulfate. 

Iftrdroquinone (Hydroquinol) 

p- [(2-Hyxiroxyethyl)methylamlno] benzenediazonium chloride 
(p-Diazo-N-hydroxyethyl-N-methylaniline) - zinc 
chloride. 
l-t^roxy-N-(2-hydroxyethyl)-2-naphthamlde (2,3-Cixynaph- 
thoic -mono-ethanolamlde ) . 

l-(3-Hirdroxyphenyl)urea '■ 

4-Methoxy-l-naphthol 

p-Methylaminophenol sulfate (Metol) 

5-Methylbenzotriazole 

2-Methylbenzoxazole 

4-Methyl-l-phenyl-3-pyrazolidinone 

<i-lfcrpholinylbenzenediazonlum chloride - zinc chloride 
salt. 

4-Morpholinylbenzenediazoniuin fluoroborate 

6-Nitrobenz imidazole 

Octylphenyl salicylate 

Phenyl-5-meroaptotetrazole 

l-Phenyl-3-pyrazolidlnone 

<t-Phenylpyrooatechol 

Polyvinyl olnnamate 

2-Resorcyllo monoethanolamide 

4,4' -Thiodiresorcinol (Diresoroyl sulfide) 

l-(2,4,6-Trichlorophenyl)-3-(4-nitroanilino)-2-pyraz- 
olin-5-one. 

All other — - 

Phthallo acid, lead salt, dibasic 

•Plnene (a- and p-) 

Poly-4-(2-acryloxy ethoxy)-2-hydroxybenzophenone 

Polyethylene terephthalate 

•Propyl gallate 

IVrogallol (Pyrogallic acid) 

Resorclnol monobenzoate 

Rosin acid salts: 

Aluminum reslnate 

Calcium reslnate 

Cobalt manganese reslnate 

Copper reslnate 

Iron reslnate 

Lead reslnate 

Manganese reslnate 

Zinc reslnate 

Sallcylanillde, nonmedlclnal 

Salicylic acid, lead sail- 

Silicones 

Sodium cresoxide (Cresyllc acid, sodium salt) 

Sodium ferric ethylenediamine dl-o-hydroxyphenylacetate 

Sucrose benzoate 

Sulfosalicyllc acid 

Tall oil fatty acid chloride — 

»Tall oil salts (linolelc -rosin acid salts): 

♦Calcium tallate 

♦Cobalt tallate 

Copper tallate 

Iron tallate 

lead manganese tallate 

»Iead tallate 

«Uanganese tallate 

Zinc tallate - 

Tannic acid 



PMT, 


IDC. 






EK. 








EK. 








FMT. 








IDC. 








IDC. 








EK, 


M. 






EKT. 








CFC, 


fMT. 






GGY, 


WAY. 






X. 








WAY. 








PVT. 








BKC. 








EKT. 








EK, 


EKT,. 


IDC, 


WAY. 


NTL. 








ABZ, 


CBY, 


OID 


HNW, HPC. 


ACY. 








DUP, 


EK. 






EKT, 


HN, 


HSH. 




HSH, 


MAL. 






EKT. 








JMS, 


MAL. 






JMS. 


SW. 






JMS. 








JMS. 








HSH, 


JMS. 






JMS. 








JMS. 








,TMS, 


SW. 






DUP, 


FIN, 


MEE 


PCW. 


NTL. 








DCC. 








DEX, 


GOC. 






GOY. 








VEL. 








HON, 


MRK. 






OAF. 









CCA, CCC, DYS, HNX, HSH, MCI, MID, SHR, TRO, WTC. 

CCA, CCC, FER, HNX, MCI, MID, SHP, SRR, TRO, WTC. 

CCA, MID, SHP. 

CCA, MCI, MID, SRR, WTC. 

HSH, MCI. 

CCA, CCC, FER, HHX, HSH, MCI, MID, SHP, SRR, TRO, WTC, 

CCA^ CCC, FER, HNX. HSH, MCI, MID, SRR, TRO, WTC. 

CCA, HSH, MCI. 

HSH, MAL. 



MISCELLANEOUS CHEMICALS 



TABLE 21B. 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 7566- -Continued 



Manufacturers' Identification codes 
(according to list in table 22) 



MISCELIANEOUS CHEMICALS, CYCUC- -Continued 

»Tanning materials, synthetic : 

Ifcrdroxytoluenesulfonic acid, formaldehyde condensate 
(Cresol-formaldehyde sulfonate), sodium salt. 
»2-Naphthalenesulfonic acid, formaldehyde condensate 

and salts. 
l-Phenol-2-sulfonic acid, formaldehyde condensate 
(Phenol-formaldehyde, sulfonated). 

1-Phenol-^-sulfonic acid, formaldehyde condensate 

Styrene maleic anhydride interpolymer, partial sodium 

salt. 
Sulfonyldiphenolsulfonic acid, formaldehyde condensate — 

All other— 

Tetra(n-butyl)ammonium picrate 

3,3',<i,4.'-Tetrachlorophenylurea 

Tetrahydrcmethylthiophene-l,l-dioxide 

IjajSjA-Tetral^dronaphthalene (Tetralin) - - 

Tetrahydrothiophene 

Tetrahydrothiophene-l,l-dioxide (Sulfolane) 

Tetralds[ methylene-3-(3 ', 5 '-di-tert-butyl-^ ' -hydroxyphenol ) 
propionate] methane. 

Tetramethylaminoethylpiperazine 

Tetraphenyltin 

•Textile chemicals, other than surface-active agents: 
•l,3-Bis(hydroxymethyl )-2-imidazolidone (Dimethylol 
ethylene urea). 

N',N'-Diphenyl-l,2-propanediamine 

l-[(Octadecyloxy)methyl] pyridinium chloride 

Phenol, sulfurated 

Tetrahydro-3,5-bis(methoxymethyl)^H-l,3,5-oxadiazine-^- 
one (l,3-Bis(methoxymethyl)uron). 

2,2',i,^'-Tetrahydroxybenzophenone 

All other - — 

2,2'-Thiobls[4-chlorophenol] 

2,2'-Thiobis['V,6-dichlorophenol] 

[2,2'-Thiobis('i-octylphenolate)]-n-butylamine nickel— 

Thiophene - 

o-Toluidine formaldehyde hydrochloride 

o-Tolylblguanide 

Triaryl phosphites 

3,'i',5-Tribromosalicylanilide 

3,4',5-Tribromosallcylanilide and dibromosalicylanilide 
mixtures. 

3,'i,<i'-Triohlorocarbanilide 

Trichloromelamlne 

l,3,5-Trichloro-s-trlazine-2,4,6(lH,3H,5H)trione (Tri- 
ohlorolsocyanuric acid). 

Tri-(m,p)-cre8yl borate 

3-Trifluoromethyl-4.,';'-diohlorooarbonalide 

a,a,a-Trlfluoro-p-toluidlne (p-Aminobenzotrifluoride) 

2,'i,6-Trinitroresorcinol, lead derivative 

s-Trioxane 

Triphenylphosphine ^ 

Trlphenyl phosphite 

Triphenyltin acetate 

Triphenyltln chloride 

Trls(l-aziridinyl)phosphine oxide 

Uridine derivatives 

l-Viiiyl-2-pyrrolidlnone, monomer and polymer 

l-Vinyl-2-pyrrolidinone - acrylamide copolymer 

l-Vlnyl-2-pyrrolidinone - ethyl - acrylamide copolymer 

l-Vinyl-2-pyrrolidinone - vinyl acetate copolymer 

MISCELIANEOUS CHMICALS, ACYCLIC 



»Cellulo8e esters: 

•Celluloae acetate 

Cellulose acetate butyrate- 



GGY. 

AKS, GRD, NOP, NYC, RH. 

NAC, NOP, RH. 



ore. 

PLC. 
DUP. 
CRO, PAS. 



ACY, AKS, DEX. 

SNW. 
DUP. 
GAT. 
DEX. 

OAF. 

AKS, X, X. 

GIV. 

SDH. 

ACY. 

PAS. 

RBC. 

MON. 



MON. 
WTH. 
MON. 

USB. 
GGY. 
PIC. 



SYNTHETIC ORGANIC CHEMICALS 1966 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, iP66- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELIANEOUS CHEMICALS, ACYCLIC— Continued 



Cellulo 



Est 



and Ether 



-Continued 



»Cellulose esters — Continued 

Cellulose acetate propionate 

Cellulose propionate 

Nitrocellulose (Cellulose nitrate) 

»Cellulose ethers: 

Ethylcellulose 

Ethylhydroxyethylcelluloee 

Urdroxyethylcellulose 

Methylcellulose 

»Sodium carboxjmethyloellulose, 100^ 

Sodium carboxjmethylhydroxyethylcellulose 

Lubricating Oil Additives 

Chlorosulfurlzed hydrocarbon 

Chlorosulfurlzed lard oil 

Chlorosulfurlzed sperm oil 

Oxidized hydrocarbons 

»Pho6phorodlthloates (Dlthiophospliates) : 

Zinc di(butylhexyl) phosphorodithioate 

Zinc dihexyl phosphorodithioate 

Zinc diisopropyl phosphorodithioate 

All other - - 

Sulfurized butenes 

»Sulfurized lard oil 

•Sulfurized sperm oil 

All other - 

Nitrogenous Compounds 

Acetaldehyde, 1,1 -dimethyl hydrazone 

Acetamlde 

Acetamidine hydrochloride 

Aoetamidoethanol (n-Acetyl-ethanolamlne) 

Acetone semlcarbazone 

Acetonitrile 

•Acrylonitrlle 

Adiponitrile - - - 

Allyl-sec-butylcyanoacetio acid, ethyl ester 

l-Allyl-3-(2-hydroxyethyl) -2 -thiourea 

Allyl Isocyanate 

Allyl isothiocyanate, non-perfume grade 

Amidinourea (Granylurea) phosphate 

•Amines : 

Allylamines 

«n-Butylamine, mono- 

tert-Butylamine, mono- 

n-Butylethylamine 

n-Butylmethylamine 

»Di-n-butylamine 

Di-n-butylmethylamine 

Dlethylamine hydrochloride 

Die thylenetri amine 

N,N-Diethylethylenediamine 

ifi- ,N^ -Diethyl-l,'i-pentanediamine ( Novoldiamlne ) ■ 

Diethylaminopropylamine 

Dlhexylamine 

Diisobutylamlne 

Dimethylamine hydrochloride 

Dimethylamlne sulfate 

N,N-Dimethyl-l,3-propanediamlne 

Dlmethylamlnopropylamine 

Dlpentylamine ( Diamylamlne ) 

»Dlpropylamine 

Dipropylenetriamine 

•Ethylamlnee : 

Dlethylamine 

Ethylamlne, mono- 

Trlethy] 



DOW, HPC. 

HPC. 

HPC, UCC. 

DCW. 

BUK, DUP, HPC, KON, WMP, WYN. 

HPC. 



EN J. 
CCW. 

ccw. 

ALX. 



ORO. 

MON. 

SIN. 

ENJ, LUB, MON, SIN, X. 

LUB. 

ccw, GOC, NLC, SIN, WBG. 

CCW, LUB, QCP, SIN, SOI. 

CCW, ENJ, HK, LUB, MON, ORO, SIN, SOI, TX. 



DIX. 






ACQ. 






MRK. 






RBC. 






NOR. 






EKX, SOH, 


UCC. 




ACY, BPG, 


DUP, 


MON, SOH, UCC 


DUP, MON. 






SDW. 






mr, IDC. 






CTN. 






ICO. 






ACT. 






SHC. 






EKT, PAS, 


UCC, 


VGC. 


MON, RH. 






PAS. 






PAS. 






PAS, UCC, 


VGC. 




UCC. 






CFC, X. 






DOW, JCC, 


UCC. 




CBP, COK. 






SDH. 






UCC. 






VGC. 






PAS, VGC. 






EK, GAM. 






RH. 






JCC. 






UCC. 






PAS, VGC. 






ENJ, PAS, 


UCC, 


VGC. 


UCC. 






DUP, ESC, 


PAS, 


UCC, VGC. 


ESC, PAS, 


UCC, 


VGC. 


ESC, PAS, 


UCC, 


VGC. 



MISCELLANEOUS CHEMICALS 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1 966 - -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

Nitrogenous Compounds-~C<)ntirmed 

Amines — Continued 

Ethylenediamlne 

Ethylenediamine sulfate 

1,6-Hexanediamine (Hexamethylenediamine) 

3,3'-Iminoblspropylamine 

Isobutylamlne 

»Isopropylamines : 

Diisopropylamine 

Isopropylamlne, mono- 

»Methylajnines : 

Dimethylamine 

Msthylamlne , mono- 

Trimethylamlne-- 

Methylamine hydrochloride 

Methyltriethylenediamlne 

Pentaethylenehexamine 

Pentylamine (Monoamylamine) 

1,2-Propanediamine ( Propylenediamine ) 

1,3-Propanedlamine (1,3-Diaminopropane) 

Propylamine mono- 

Tetraethylenepentamine 

N,N,N',N'-Tetramethyl-l,3-butanediamine 

Tetramethylethylenediamine 

Tributylamlne - 

Triethylenetetramine 

Tripentylamine 

Other -- - 

2-Amino-l-butanol 

2-Aminoethanethiol (2-Meroaptoethylamine) hydrochloride- - 

1-Amlnoethanol (Acetaldehyde ammonia) 

2-Aminoethanol (Monoethanolamine) hydrochloride 

2-Aminoethanol (Monoethanolamine) sulfite 

Aminoethoxyethanol 

2-(2-Aminoethylamino)ethanol (Amlnoethylethanolamine) 

2-Amlnoethyl mercaptoacetate (Monoethanolamine thio- 
glycolate). 

2-Amlno-2-ethyl-l,3-propanediol 

2-Aminoethyl vinyl ether , 

Aminoguanidlne bicarbonate 

2-Amlno-2-(hydroxymethyl)-l,3-propanediol (Trls-(hydroxy- 
methyl ) amlnome thane ) . 

2-Amlno-2-methyl-l,3-propanediol 

2-Amino-2 -methyl -1-propanol 

2-Amino-l-propanol 

3-Amino-l-propanol 

»1,1' -Azobisformamide 

2,2'-Azobis[2-methylproplonitrile] (Azobislsobutyronitril( 

l,3-Bis(2-hydroxyethyl)-2-thiourea 

l,3-Bis(hydroxymethyl)urea ( Dimethylolurea ) 

N,0-Bis(trimethylsilyl)acetamide— — 

Biuret - 

N-Bromoacetamide 

N-Bromosuccinimide (Suooinibromimlde) 

2,3-Butanedione monoxlme 

2-Butanone oxime 

tert-Butyl carbazate 

n-Butyl cyanoacetate 

l-Butyl-3-ethyl-2-thiourea 

2,2'-(Butylimino)diethanol (N,N-Bis(2-hydroxyethyl)-butyl. 
amine). 

Butyl isoeyanate 

Butyraldehyde oxime 

n-Butyronitrile 

»Caprolaotam (2-Qxohexamethylentmlne) 

Chloroaoetamide 

Chloroacetonltrlle 

Chlorocholine chloride 



ESC, PAS, UCC, VGC. 
ESC, PAS, UCC, VGC. 



CFC, 


CCM, 


DUP, 


ESC 


PAS 


RH. 




COM, 


DUP, 


ESC, 


GAF 


PAS 


RH. 




COM, 


DUP, 


ESC, 


PAS 


RH. 






EK, 


RBC. 












JCC. 














DOW. 














EK, 


PAS. 












JCC, 


UCC. 












UCC. 














PAS, 


UCC. 












DOW, 


UCC. 












UCC. 














RH. 














PAS. 














DOW, 


UCC. 












PAS. 














ALB, 


ALD, 


DUP, 


EK, 


NTfi, 


ONX, SNW, VGC 


ACY, 


COM. 












EVN. 














PAS. 














WSN. 














EVN, 


SUM. 












JCC. 














DOW, 


JCC, 


UCC. 










EVN, 


HAB. 












COM. 














MEE. 














TRJ. 














COM. 














COM. 














CCM. 














LIL. 














UCC. 














FWT, 


NPT, 


USH. 










DUP. 














IDC. 














GLY, 


X. 












PIC. 














SW. 














AHA. 














ARA, 


SDW. 












EK. 














ALB, 


CCA, 


MID, 


NAC, 


TRO. 






AID. 














KF. 














PAS. 














PAS. 














CWN, 


UPJ. 












NAC. 














EKX. 














DBC, 


DUP, 


NAC. 










BPC, 


DOW. 












BPC. 














ACY. 















SYNTHETIC ORGANIC CHEMICALS, 1966 

TABLE 21B --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 566 --Continued 



MISCELLANEOUS CHEMICAI5, ACYCLIC— Continued 

Nitrogenous Compounffs- -Continued 

»2-Chloro-N,N-dlinethylethylamine (Dlmethylaminoethyl chlO' 
ride) hydrochloride. 

3-Chloro-N,N-dimethylpropylandne 

a-Chloro-N.N-dimetl^rlpropylamine hydrochloride 

3-Ghloro-N,N-diinethylpropylamine hydrochloride — 

2-Chloroethylamine 

fi-Chloroallyl-N-methylamine 

N-Chlorosuooinimide (Succinichlorimide) 

2-Chlorotriethylamine hydrochloride 

2-Chloro-N,N-diethylethylamine hydrochloride — 

Choline tase 

Coco nitrile 

Coconut oil amide 

Cottonseed oil nitrile 

Creatine & creatinine 

Crotononitrile 

2-Cyanoacetamide 

2-Cyanoacethydrazide 

Cyanoacetic acid 

Cyanogen bromide 

2-Dibutylaminoethanol 

1, 3 -Dibutyl -2 -thiourea 

IjA-Dicyanobutene 

Diethyl acetamidomalonate 

Dlethylaminoethanethiol hydrochloride 

»2-DiethylaEinoethanol 

2-(2-Diethylaminoethoxy)ethanol 

2-Diethylaminoethyl methacrylate 

Dlethylcarbamoyl chloride 

Diethyldithiocarbamic acid, sodium salt 

N,N-Diethyldodecanamlde 

Diethylhydroxylandne 

l,3-Diethyl-2-thiourea - -— 

2-Diisopropylaminoethanol ( N-Diisopropylethanolamine ) -- 

Diisopropylannnonium nitrite 

l,3-Diisopropyl-2-thiourea 

Di ( me thoxye thy 1) amine 

N, N-Dimethylacetamide 

2-Dimethylajiiinoethanethiol hydrochloride 

»2-Dimetl^laminoethanol 

3-Dimethylajninopropionitrile 

Dlmethylaminoethyl methacrylate 

2-Dimethylamino-2-methyl-l-propanol 

Dimethylcarbamoyl chloride 

N-(3-Dimethylaminopropyl)oleamide 

N, N-Dimethylformamide 

1,1 -Dime tt^rlhydrazine 

Dithiooxamlde 

2,5-Dithiobiurea - 

tert-Dodecyldisuccinamide 

Erucamide 

*Ethanolamines : 

*2-Aminoethanol (Monoethanolamine) 

»2,2'-Amlnodiethanol (Diethanolamine) 

<<2,2 ' ,2 " -Nitrilotriethanol ( Trlethanolamlne ) 

Ethoxymethylenemalononitrile 

3-Ethoxypropionitrile 

Ethyl aoetamidocyanoacetate 

Ethyl allyl(l-methyl-2-pentynyl)cyanoaoetate- — 

2-Ethylaminoethanol ( Ethylmouoethanolamine ) 

Ethyl carbamate 

Ethyl carbodilmide hydrochloride 

Ethyl cyanoacetate 

Ethyl diazoacetate 

2-Ethylhexyl cyanoacetate 

N-Ethyl-N-hydroxyethyl-l,<i-pentanediamine-* 

5-(N-Ethyl-N-hydroxyethylamino)-2-pentaxione 

Ethyl isocyanate 



Manufacturers' identification codes 
(according to list in table 22) 



ABB, GAM, HEX, MCH, NES, PAS. 



SK. 

MCH. 

MCH. 

ICI. 

LIL. 

ARA, RAC. 

HEX, MCH, 

PAS. 

RH. 

FOR. 

ARC, PG. 

FOR. 

PFN. 

KF. 

KF. 

KF. 



AAC, PAS. 




PAS, RBC. 




X. 




SDW. 




EVN. 




AAC, PAS, 


UCC. 


PAS. 




DUP. 




GAM. 




EK. 




EK. 




PAS. 




PAS, RBC. 




PAS, UCC. 




CMC. 




PAS. 




VGC. 




DUP. 




EVN. 




AAC, JCC, 


PAS, RH, UCC 


ACY. 




AAC. 




COM. 




CTN, ore. 




DUP. 




DUP. 




FMP. 




MAL. 




ACY. 




X. 




ADM, FIN 





ACP, DOW, JCC, UCC. 

ACP, DOW, JCC, UCC. 

ACP, DOW, JCC, UCC. 

KF. 

ACY. 

SDW. 

LIL. 

PAS. 

BKL, FMP. 

OTC. 

KF. 

AID. 

GAF, KF. 

SDW. 

SDW. 

CTN, OTC. 



MISCELLANEOUS CHEMICALS 

TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 7566- -Continued 

Manufacturers' identification codes 
(according to list in table 22) 

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 
Nitrogenous Compounds— Continued 



Fonnamlde 

Formamidine disulfide dihydrochloride 

Glycine (Aminoacetic acid), non-medicinal 

Glycine ethyl ester hydrochloride 

Glycine salts : 

Cupric glycinate 

Potassium glycinate 

Sodium glycinate 

Glyoolonitrile 

Guanidine hydrochloride 

Hexamethylenediaramonium adipate (Nylon salt) 

ffydracrylonltrile (Ethylene cyanohydrin) 

2-Ifydrazinoethanol (2-Hydroxyethylhydrazine) 

N-Z-ffydroxyethylaoetamide 

I^roxyethyl carbamate 

2-(l^droxymethyl) -2 -nitro-l, 3 -propanediol (Tris-(hydroxy- 
methyl )ni tromethane ) . 

Isobutyronitrile 

Isopropanolamines : 

l-Amino-2-propanol (Manoisopropanolamine) 

l,l'-Iiid.nodi-2-propanol (Diisopropanolamine) 

1,1', 1" -Nitrilotri-2-propanol (Triisopropanolamine) 

3-Isopropoxyproplonitrile 

3-Isopropoxypropylamine 

2-Isopropylaminoethanol 

Isopropyl carbamate 

Isopropyl ethyl thionocarbamate 

Lactonitrile 

Lauronitrile (Dodecyl nltrile) 

Malonamlde 

Malononltrlle 

Methacrylamlde 

Methacrylonitrlle - 

Methoxyamine hydrochloride 

3-Methoxypropionitrile 

3-Methoxypropylamlne 

N-ltethylacetamlde 

2-Methylamlnoethanol ( N-Methylethanolamlne ) 

Methylamino dimethyl acetal 

ifethyl carbamate 

Methyl cyanoacetate 

Methyl a -cyanoacrylate 

N,N'-Methylenebis(acrylamlde) - 

N,N'-Methylenebis(octadecanamlde) 

N-Uethylglucamine 

Methyl isocyanate 

2,2'-(Methylimino)diethanol (Methyldiethanolamlne) 

»2-Metliyllactonitrile (Acetone cyanohydrin) 

2-Methyl-2-nltro-l,3-propanedlol 

2-Methyl-2-nltro-l-propanol 

Nfethylpolyethanolamine 

N-Methyltaurlne 

N-Methyltaurine, sodium salt 

N-lfethylurea 

»Nitriloacids and salts: 

(Dlethylenetrinitrllc)pentaaoetio acid 

(Diethylenetrinitrllo)pentaaoetlc acid, monoeodium 

hydrogen ferric salt. 
(.Diethylenetrlnltrilo)pentaacetlc acid, pentasodium salt 

(Dlethylenetrinitrilo)pentaacetlc add, sodium salt 

N,N-Dihydroxyethylglyclne, sodium salt 

Ethanoldiglycine, disodlum salt 

(Ethylenedinltrilo)tetraacetic acid (Ethylenediamlne- 

tetraacetic acid). 
(Ethylenedlnltrilo)tetraaoetio acid, oalolum disodlum 

salt. 
(Ethylenedinltrilo)tetraaoetic acid, diammonlum salt 



DUP. 
WAY. 

BPC, CHT. 
BPC. 

BPC. 

BPC. 

BPC. 

ACY. 

ACY. 

CEL, MON. 

UCC. 

NOR. 

USR. 

JCC. 

COM. 

EKX. 

DOW, UCC. 

DOW, UCC. 

DOW, UCC. 

ACY, DUP. 

DUP. 

PAS. 

BKL. 

DOW. 

MON. 

FOR. 

KF. 

KF. 

BFG, RH, X. 

SOH. 

EK. 

DUP. 

DUP, EKT, JCC. 

ACI, EK. 

UCC. 

LIL. 

BKL, FUP. 

KF. 

EKT. 

ACY. 

ARC. 

DUP. 

CTN, OTC. 

UCC. 

ACY, RH, X. 

COM. 

COM. 

GAF. 

GAF. 

TNA. 

LIL. 



DOW, GGY, HMP. 
DCW, GGY. 
DOW. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufa cturer, 1 966 - - Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

Nitrogenous Compounds-'Continued 

»Nitrlloaoids and salts— Continued 

»(Ethylenedinitrilo)tetraacetic acid, dlsodium salt 

(Ethylenedinitrilo)tetraacetlo acid, disodium copper 

salt, dihydrate. 
(Ethylenedinitrilo)tetraacetic acid, disodium zinc salt, 
dihydrate. 

(Ethylenedinitrilo)tetraacetic acid, manganese salt 

(Ethylenedinitrilo)tetraacetic acid, monosodium iron 

salt. 
(Ethylenedlnitrilo)tetraacetlo acid, tetrapotassium salt 

»(Ethylenedinitrilo)tetraaoetic acid, tetrasodium salt 

»(Ethylenedinitrilo)tetraacetlc acid, trisodium salt 

(N-Hydroxyethylethylenedlnitrllo)trlacetio acid 

»(N-HjrdroxyethyletlQflenedinitrilo)triacetic acid, tri- 
sodium salt. 

Nitrilotriacetic acid, trisodium salt 

Other 

2-Nitro-l-butanol — — 

Nitroethane 

Nitrome thane 

1-Nitropropane 

2-Nitropropane 

»Nylon, 6 and 6/6 polymer for fiber 

Ootadecyl isooyanate 

«01eamlde (Octadeoene amide) 

Oleonitrile (Octodecene nitrile) 

Oleoylhydroxamic acid 

Oleoylpalmltamlde 

*Pentaerythrltol tetranitrate 

Pentyl nitrate (Anyl nitrate) 

Polyaorylamide 

Polyacrylonltrlle 

n-Propyl carbamate 

Propyl isooyanate ■ — 

Propyl nitrate 

Quaternary ammonium compounds 

Ricinolamlde 

*Saroosine (N-Methylamlnoacetic acid) 

Semlcarbazide base 

Semicarbazide hydrochloride 

Semioxamazide 

»Stearamlde (Octadecane amide) 

Stearonitrile (Octadecanenitrile) 

Suoolnlmide 

Tallow amide, hydrogenated 

Tall oil nitrile - - - 

Tallow nitrile - 

Tallow nitrile, hydrogenated 

N,N,N',N'-Tetrald.s(2-hydroxypropyl)ethylenediamine 

Tetramethylguanidine 

Tetramethylurea 

Thloacetamide 

3,3 '-Thlodlpropionltrlle 

Thiosemicarbazide 

Triallyl cyanurate 

Triisopropanolamine borate 

N-Trimethylsllylacetamide 

»Urea In compounds or mixtures, 100^ basis : 

»In feed compounds 

»In liquid fertilizer 

»In solid fertilizer 

In plastics 

All other- - - - 

Urea peroxide 



GGY. 

CRT, CWL, DOW, GGY, HMP, HRT, RFC, TCC. 

GGY, HMP, NOP. 

GGY. 

CRT, CWL, DOW, GGY, HMP, RPC, TCC. 



GGY, 


HMP. 






EK, 


WP. 






COM. 








COM. 








COM. 








COM. 








COM. 








DUP, 


MON, 


NAC. 




CWN, 


MOB. 






ADM, 


ARC, 


FIN, 


HUM. 


ARC, 


FOR. 






WAY, 


WOB. 






FIN. 








DUP, 


HPC, 


TRJ. 




TNA. 








ACY, 


NLC. 






DUP. 








BKT,. 








CWN, 


OTC. 






TNA. 








EK, 


PAS, 


RSA. 




TKL. 








GAF, 


GGY, 


HMP, 


VPC. 


FMT. 








FMP. 








NOR. 








ADM, 


ARC, 


DUP, 


FIN. HUM. 


FOR, 


HUM. 






NAC. 








ADM, 


ARC. 






FOR. 








ADM, 


FOR. 






FOR. 








rm. 








ACY. 








OTC. 








BKC. 








ACY, 


HAB. 






ACY, 


FMI. 






ACT. 








USB. 








EK, 


PIC. 







ACN, ACY, DUP, GSC, JDC, KET, MON, MSC, SOH, VLN. 
ACN, CFC, CNC, DUP, ESC, FCA, FTX, GCC, GOC, HKY, HPC, 

JDC, KET, MON, MSC, NIT, CMC, PLC, PPC, SHC, SNI, 

SOH, VLN, WYC, X. 
ACN, ACY, CNC, DUP, GCC, GOC, HPC, JDC, MON, MSC, PPC, 

SHC, SNO, SOH, VLN. 
DUP, MON. 

ACN, ACY, DUP, HPC, MON, SHC, SNO, SOH, VLN, x. 
FBM. 



MISCELLANEOUS CHEMICALS 

TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i566- -Continued 



Manufaoturere' identification codes 
(according to list In table 22) 



MISCELLANEOUS CHMICALS, ACYCLIC— Continued 

Nitrogenous Compounds--Contliiued 

Urea - urethanp r-opol^raier 

Y-Valeronitrlle — - 

All other nitrogenous compounds 

Acids, Acid Anhydrides, and Acyl Halides 

»Acetic acid, synthetic, 100^ - 

♦Acetic anhydride, 100^: 

From acetaldehyde 

From acetic acid, other than recovered, by the vapor- 
phase process. 
From acetic acid, recovered, by the vapor-phase process 

From ethylene 

Acetyl chloride 

Aconitio acid 

»Acryllc acid 

«Adiplc acid - - 

Adipoyl chloride 

Azelaic acid 

Behenic acid 

:i-Brcmo(lauric-steario) acid 

Butylstannolc acid 

•Butyric acid 

Butyric anhydride 

Butyiyl chloride 

Castor oil fatty acids, dehydrated 

»Chloroaoetic acid, mono- 

Chloroacetyl chloride 

Citric acid 

Crotonio acid (2-Butenoie acid) 

»Decanoyl chloride 

Dlglyoolic acid 

Di-n-propylacetic acid 

Di-n-propylacetyl chloride 

Dodecenylsuccinic anhydride 

Dodecylauccinic anhydride 

Erucic acid . 

2-.Ethylbutyrio acid (Diethylacetic acid) 

2-Ethylhexanoic acid (a-Ethylcaproic acid) 

2-Ethylhexanoyl chloride 

♦Formic acid, 905t- 

»F\jjiiaric acid 

♦Gluconic acid, tech 

Glutarlc anhydride 

Glycolio acid (Hydroxyicetic acid) 

n-Hexadecenylsuocinic anhydride 

Isethlonic acid (2 -Hydroxy ethanesulfonic acid) 

Isoascorbic acid 

lEobutyric acid 

Isobutyrlc anhydride 

Isodecanoic acid mixed IscmerB 

Iso-ootanoic acid 

Itaoonic acid (Methylenesuccinlc acid) 

Lactic acid: 

Edible, 100^ 

Technical, 100* 

lauroyl bromide 

♦lauroyl chloride 

Levultnlc acid 

Maleic acid 

♦Maleic anhydride - 

Malic acid 

Molonlc acid — 

Mercaptoacetic acid ( Thloglycollc acid) 

fl-Mercaptopropionlc acid 

Mercaptosucclnlc acid (Thlcmallc acid) 

Methacryllc acid 



DUP. 
SEL. 
ADM, CFC, x. 



BOH, CEL, EKT, HPC, PUB, UCC. 



HPC. 




CEL, EKT. 




CEL. 




UCC. 




TBK. 




PCW. 




BFG, GEL, DBC, MM 


UCC. 


CEL, DUP, ELP, MON 


NAC, RH. 


CFC, EK. 




EMR. 




ADM, HUM. 




DUP. 




CCW. 




CEL, EKT, UCC. 




EKT. 




HK. 




BAC, SF. 




BUK, DA, DOW, HPC, 


MON. 


DOW. 




MLS, PFZ. 




EKT. 




CAD, TBK, UPR, WTL 




DUP. 




X. 




CTN. 




HMY, MON, NAC. 




X. 




ARC. 




UCC. 




EKT, UCC. 




WTL. 




DUP, HN, SF, UCC. 




HN, MON, NAC, PCC, 


PFZ PTT. 


CWL, DLI, IBI, PFZ. 




UCC. 




DUP. 




HMY. 




GAF. 




BAX, MRK, PFZ. 




EKT. 




EKT. 




UCC. 




UCC. 




PFZ. 




CLN, MON. 




cm, MON. 




DOW. 




CAD, GAF, ONX, TBK, 


THC, UPR, WTL 


CRZ. 




NAC, PFN, PFZ. 




HN, KPS, MON, NAC, 


PCC, PTT, RCl. 


EK, NAC, PFN, 




KF. 




EVN, HAB, RETT. 




EVN. 




EVN. 




DUP, RH. 





180 SYNTHETIC ORGANIC CHEMICALS, 1966 

TABLE 21B.— Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1966 — Continued 



MISCELLANEOUS CHBGCALS, ACYCLIC— Continued 

Acids, Acid Anhydrides, and Acyl Ha i ides —Continued 

Methanesulfonio acid 

2-Nfethylvaleric aold (2-Methylpentanoio acid) 

Micoohlorio acid (2,3-Diohloro-3-foniiylaorylio acid)- 

Nonanolc acid (Pelargonic acid) 

Nonenylsuooinic anhydride 

Ootanoyl chloride 

Octenylsuocinic anhydride 

Oleoyl chloride 

"Oxalic acid 

»Palmltoyl chloride 

Pelargonyl chloride 

Peroxyaoetlc acid 

Pivaloyl chloride 

Polyaorylic acid 

Polygalacturonic aold 

•Propionic acid 

Propionic anhydride 

Propionyl chloride 

2-Propylvaleric acid (Dlpropylacetic acid) 

Sebaclo acid 

Sorbic acid (2,4-Hexadlenolc acid) 

Stearyl-2-laotic acid 

Succinic acid 

Succinic anhydride 

Tallow fatty acyl chloride 

d-Tartarlc acid 

Tetrahydroxysucoinlc acid (Dioxytartlo acid) 

Thioaoetlc acid 

Thlolactic acid r 

3,3'-Thlodlpropionlc acid 

Trichloroacetic acid 

Trichloroacetyl chloride 

(Trlohloroiiiethyl)pho8phonlo acid 

Trlfluoroacetic anhydride 

Valeric acid - — - - 

All other— 

Sails of Organic Acids 

•Acetic acid salts: 

Aluminum acetate 

subacetate 

acetate 

Barium acetate 

Cadmium acetate 

Calcium acetate 

Chrcmlum acetate — -— — 

Cobalt acetate 

•Copper acetate 

Lead acetate 

lead subacetate 

Lead tetraacetate 

Magnesium acetate 

Manganese acetate 

Mercuric acetate 

Methylmeroury acetate 

motel acetate 

•Potassium acetate 

Silver acetate 

•Sodium acetate 

Sodium dlacetate 

Strontium acetate 

Uranyl acetate 

•Zinc acetate 

•Zirconium acetate 

Chloroacetlo acid, sodium salt 

3-Chloro-2Tbutene-l-sulfonio aold, sodium salt 

Chlorohydroxylaotio acid, aluminum, sodium salt 



Manufacturers' identification codes 
(according to list in table 22) 



EK, PAS. 
UCC. 
EKT. 
EMR, GIV. 

mx. 

HK. 

HMY. 

DEP, GAP, TBK. 

ACG, HK, MAL, PFZ, SF. 

GAP, HAL, OPC, TBK. 

WTL. 

FMB. 

WRL. 

RH. 

SKG. 

CEL, CCM, EKT, UCC. 

CEL, EKT, UCC. 

ABB, TBK. 

BPC. 

RH, WTH. 

UCC. 



MAC. 



AIB, DUP, EK, KF, PIC, RH, UCC. 



ACY, UCC. 










MAL. 










ACG, BKC, 


MAL, 


WSN. 






ACG, BKC, 


MAL. 








BKC, HSH, 


MAL. 


SHP. 






ACG, BKC, 


MAL. 








ACY. 










BKC, HSH, 


SHP. 








ACG, BKC, 


UCC. 








ACG, BKC, 


MAL, 


SW. 






ACG, BKC, 


MAL. 








AHA. 










ACG, BKC. 










HSH, SHP. 










ACG, MAL. 










DUP. 










BKC, HSH, 


SHP. 








ACG, BKC, 


CWL, 


MAL, 


UCC, 


WSN. 


MAL. 










ACG, BKC, 


CEL, 


DAN, 


EKT, 


MAL 


UCC. 










BKC. 










BKC. 










ACG, BKC, 


HSH, 


MAL, 


SNW, 


UCC 


HSH, NTL, 


SNW, 


TZC. 






D0». 











MISCELLANEOUS CHEMICALS 



TABLE 21B. —Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 566- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELIANEOUS CHIMICAIS, ACYCLIC—Continued 
Salts of Organic Acids—Continued 

Citric acid salts: 

Ammonium citrate 

Calcium citrate 

Ferric ammonium citrate 

Ferric citrate 

Ferrous calcium citrate 

Potassium citrate 

Sodium citrate 

»2-B^hylhexanoic acid (a-Ethylcaproic acid) salts: 

Aluminum 2-ethylhexanoate 

Barium 2-ethylhexanoate 

Cadmium 2-ethylhexanoate 

»Calclum 2-ethylhexanoate 

•Cobalt 2-ethylhexanoate 

Copper 2-ethylhexanoate 

Dlbutyltin di -2-ethylhexanoate 

Iron 2-etbylhexanoate 

»Lead 2-ethylhexanoate 

Lithium 2-ethyIhexanoate 

Manganese 2-ethylhexanoate 

Nickel 2-ethylhexanoate 

Potassium 2-ethylhexanoate 

Rare earths 2-ethylhexanoate 

Stannous 2-ethylhexanoate 

Strontium 2-ethylhexanoate 

»Zino 2-ethylhexanoate 

•Zirconium 2-ethylhexanoate 

Formic acid salts : 

•Aluminum formate 

Ammonium formate 

Calcium formate 

Chromic formate 

Copper formate 

Lead formate 

Nickel formate 

Potassium formate 

Sodium formate, refined 

Sodium formate, tech 

FUmario acid, lead salt 

Gluooheptonlc acid, zinc salt 

Gluconic acid salts: 

Ammonium gluconate 

•Sodium gluconate 

Glyoolio acid salts : 

Aluminum glycolate 

Sodium glycolate 

9H-Hexadeoafluorononanolc acid, ammonium salt 

Humlo acids, sodium salts 

Isoascorblc acid, sodium salt 

lactic acid salts : 

Aluminum sodium lactate 

Calcium lactate - 

•Llnolelc acid salts: 

•Calcium llnoleate 

•Cobalt llnoleate 

Copper llnoleate 

Lead llnoleate 

Lead manganese llnoleate 

Ifanganese llnoleate 

Maleio acid, trlbasic lead salt— - 

•Jfercaptoaoetlo acid ( Thloglycollc acid) salts: 

Ammonium mercaptoacetate 

Antimony mercaptoacetate 

Calcium mercaptoacetate 

Dlbutyltin bis(iso-octyl mercaptoacetate) 

Dlbutyltin mercaptoacetate 

Potassium mercaptoacetate 

Sodium mercaptoacetate 



MAL, 


PFZ. 


PFZ. 




MAL, 


PFZ. 


MAL. 




X. 




MLS, 


PFZ. 


MLS, 


PFZ. 


WTC. 




CCA. 




CCA. 





CCA, FEE, HNX, HSH, MCI, SRR, SW, WTC. 

CCA, FER, HNX, HSH, MCI, MID, SHP, SRR, SW, WTC. 

CCA, SRR. 

X. 

CCA, SRR. 

CCA, HNX, HSH, MCI, SHP, SRR, SW, WTC. 

SRR. 

CCA, HNX. 

MCI. 

CCA, SRR. 

CCA. 

WTC. 

CCA. 

CCA, HNX, HSH, MCI, SRR, WTC. 

CCA, HNX, WTC. 

CFC, SF, UCC, WSN. 

ACG, WSN. 

TRJ. 

OAF. 

CTN. 



CFC. 

ACG, BKC. 
HPC, TRJ. 
NTL. 
PFN. 

PFZ. 



CWL, DU, IBI, PFZ, Hff. 



CIB. 






CFC, 


MED. 




DUP. 






HW. 






MRK, 


PFZ. 




TZC. 






SHF. 






CCA, 


LET, 


SHP 


HSH, 


SHF, 


SRR. 


WTC. 






SHP, 


SRR. 




SDH, 


SRR. 




SHP. 






NTL. 






EVN, 


HAB. 


TNI 


CCA. 






EVN. 






X. 






CCA. 






EVN. 






EVN, 


MED. 





SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 21B. --MiscelUxTieous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, j 966— Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACTCLIC— Continued 



Salt 



of Organic i4cids--Contlnued 



Meroaptopropionlc acid, dibutyltin salt 

Methylsucoinlc acid, disodium salt 

Neodecanonoic acid salts 

Octanoic acid (Capryllo acid) salts: 

Aluminum octanoate 

Stannous octanoate 

Zinc octanoate 

*01eic acid salts: 

Aluminum oleate 

Ammonium oleate 

Barium zinc oleate 

Copper oleate 

Stannous oleate 

»Oxalic acid salts: 

Ammonium oxalate 

Calcium oxalate 

Copper oxalate 

Ferric ammonium oxalate 

Ferric oxalate 

Ferric sodium oxalate 

Ferrous oxalate 

Potassium binoxalate 

Sodium binoxalate 

Other 

Palmitic acid salts: 

^Aluminum palmitate 

Zinc palmitate 

Phosphorodithioic acid salts ( Dithiophosphates ) : 

Potassium dihexyl phosphorodithioate 

Sodium di-sec -butyl diethyl phosphorodithioate 

Sodium di -sec-butyl phosphorodithioate 

Sodium diethyl phosphorodithioate 

Sodium dihexyl phosphorodithioate 

Sodium diisopropyl phosphorodithioate 

Other 

»Polyacrylic acid salts : 

Ammonium polyacrylate 

Potassium polyacrylate 

Sodium polyacrylate 

Polymethacrylio acid, sodium salt 

♦Propionic acid salts: 

*Calcium propionate 

♦Sodium propionate 

Zinc propionate 

Ricinoleic acid salts: 

Calcium ricinoleate 

Lithium ricinoleate 

Sodium ethyl oxalaoetate 

Sodium polypectate 

Sodium sorbitol borate 

Sorblc acid salts: 

Potassium sorbate 

Sodium sorbate 

♦Stearic acid salts : 
♦Aluminum stearates: 

♦Aluminum distearate 

♦Aluminum monostearate 

♦Aluminum trlstearate 

Ammonium stearate 

Barium stearate 

Cadmium stearate 

♦Calcium stearate 

Cobalt stearate 

Copper stearate 

Ferric stearate 

Ferrous stearate 

♦Lead stearate 



CCA, 


X. 




SDW. 






CCA. 






NOP. 






CCW, 


X. 




BKC. 






MAL, 


vrrc. 




BCN. 






vrrc. 






MID, 


WTC. 




CCW, 


X. 




ACG, 


BKC, 


PFZ. 


SF. 






CFG. 






PFZ. 






PFZ. 






PFZ. 






BKL. 






ACG, 


BKC, 


PFZ. 


ACG, 


BKC, 


MAL, SF 


DUP. 






ACY, 


NOP, 


WTC. 


ACY, 


NOP, 


WTC. 


ACY. 






ACY. 






ACY. 






ACY. 






ACY. 






ACY. 






ACY. 






BPG. 






BPG. 






ALC, 


BFG, 


JOR, RH 


GRD. 







CEL, HFT, PFZ, UCC, WSN. 
CEL, PFZ, UCC, WSN. 
BKC. 

BAC. 
BAG. 
PMP. 
SKO. 
AH). 



JTC, LEF, MAL, NOG, NOP, PRP, SYP, WTG. 

LEF, MAL, NOP, WTC. 

JTC, LEF, MAL, NOG, NOP, PRP, SYP. 

NOP. 

LEF, NOG, NOP, PRP, SYP, WTG. 

PRP, SYP, WTG. 

HNX, JTC, LEF, MAL, NOG, NOP, PRP, SYP, WTG. 



WTG. 



WTG. 

NOP, NTL, PRP, WTC. 



MISCELLANEOUS CHEMICALS 



183 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1966— Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEKQCALS, ACYCLIC— Continued 



Salts of Organi 



cids-'Contlnued 



Stearic acid salts — Continued 

Lead stearate, dibasic 

^Lithium stearate 

^Magnesium stearate 

Manganese stearate 

Nickel stearate 

»Zinc stearate 

All other — - — 

Succinic acid, sodium salt 

Sugar acids, sodium salt 

Tartaric acid salts: 

Antimony potassium tartrate 

Potassium bi tartrate 

Potassium sodium tartrate 

Sodium bi tartrate 

Valeric acid, ammonium salt 

Xanthic acid salts : 

Potassium n-butylaanthate 

Potassium ethylxanthate 

Potassium hexylxanthate 

Potassium isopropylxanthate 

Potassium pentylxanthate 

Potassium sec -pentylxanthate 

Sodium n-butyLxanthate 

Sodium sec-butylxanthate 

Sodium ethylxanthate 

Sodium isobutyLxanthate 

Sodium isopropylxanthate 

All other salts of organic acids 

Aldehydes and Ketones 

»Acetaldehyde 

»Acetone : 

From cumene 

♦From isopropyl alcohol 

Other - _ — 

Acrolein (Acrylaldehyde) 

Aldol (Acetaldol)- 

»2-Butanone (Methyl ethyl ketone) 

Butyraldehyde 

»Chloral (Triohloroaoetaldehyde) - 

5-Ghloro-2-pentanone 

l-Chloro-l-penten-3-one ((3 -Chlorovinyl ethyl ketone) 

Chloro-2-propanone (Chloroacetone) 

Crotonaldehyde 

Dihydropseudoionone 

l,3-Dihydroxy-2-propanone (Dihydroxyacetone) 

2-Ethylbutryaldehyde 

2-Ethyihexanal (c< -Ethylcaproaldehyde) 

•Formaldehyde (375t by weight) 

Glutaxaldehyde 

Glyoxal 

2-Ifeptanone (Methyl amyl ketone) 

Hexaldehyde 

2,5-Hexanedione (Aoetonylacetone) 

«4-I^droxy-^-methyl-2-pentanone (Dlacetone alcohol) — 

Isobutyraldehyde 

Isodeoaldehyde, mixed isomers 

iBovalerone (Dlleobutyl ketone) 

lactide (3,6-Dljiiethyl-2,5-p-dioxanedione) 

-i-Methoxy-* -methyl -2 -pentanone 

5 -Methyl -2-hexanone (Methyl isoamyl ketone) 

*4-Methyl-2-pentanone (Methyl isobutyl ketone) 

4-Methyl-3-penten-2-one (Mesityl oxide)— 



NTL. 








LEF, NOP, PRP, SYP, 


WTC. 






ACY, LEF, MAL, NOG, 


NOP, 


PRP, 


SYP, WTC 


NOC. 








WTO. 








ACY, BCN, CCA, HNX, 


,TTC, 


T,EF, 


MAL, NOC 


WTC. 








APD. 








MAL. 








PFN. 








PFZ. 








ATC. 








PFZ. 








PFZ. 








RSA, UCC. 








USE. 








ACY, DOW. 








DOW. 








DOW. 








ACY, DOW. 








DOW. 








KCC, USR. 








ACY, DOW. 








ACY, DOW. 








DOW. 








ACY, DOW. 








DUP, EK, GLY, X. 









NOP, PRP, SYP, 



CEL, COM, DUP, EKT, EKX, HPC, MON, PUB, SHC, UCC. 

ACP, CLK, HPC, MON, SHC, SKO, SOC. 

EKT, ENJ, SHC, UCC. 

CEL, DIX, HPC. 

SHC, UCC. 

UCC. 

CEL, DEC, ENJ, SHC, SPI, UCC. 

CEL, EKX, UCC. 

DA, FMB, GGY, MFO. 

SDW. 

ABB. 

EK, MRK. 

CEL, EKT, UCC. 

GIV. 

BAX, PFZ. 

UCC. 

EKX, UCC. 

ACP, BQR, CBC, GET , CCM, DUP, GAF, GOC, HKD, HN, : 

MON, RGI, RH, TIU, UCC. 
UCC. 
UCC. 
UCC. 

EKX, GIV. 
RBG. 

CEL, SHC, UCC. 
EKX, UCC. 
UCC. 

EKT, UCC. 
GLN. 
SHC. 

EKT, UCC. 

EKT, ENJ, SHC, UCC. 
SHC, UCC. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



■ Miscellaneous chemicals for which U.S. production or sales were reported identified 0\ 
manufacturer, i966--Continued 



MISCELLANEOUS CHEMICAI3, ACYCLIC— Continued 



ildehydes and Ketones- -Continued 



Methylpseudoionone 

2 -Methylvaleraldehyde ( 2 -Methylpentaldehyde ) 

Ootanal, tech. 

2-Ctetanone (Hexyl methyl ketone) 

3-Ootanone (Amyl ethyl ketone) 

Paraformaldehyde 

Paraldehyde (Paracetaldehyde) 

2,4-Pentanedione (Aoetylacetone) 

2-Pentanone (Methyl propyl ketone) 

3-Pentanone (Diethyl ketone) 

Propionaldehyde 

Pseudolonone 

Pyruvaldehyde 

Tetrahydropseudolonone 

2,6,8-Trlmethyl-4-nonanone (Isobutyl heptyl ketone) 
All other 

Alcohols. Monohydnc, Unsubstituted 

»Aloohols C9 or lower: 

Allyl alcohol 

Amyl alcohols : 
Unmixed : 

2-Methyl-l-butanol 

2-Methyl-2-butanol (tert-Amyl alcohol)— 

3-Methylbatanol 

1-Pentanol 

2-Pentanol 

3-Pentanol 

Mixed: 

Fusel oil, refined 

Other than fusel oil 

»Butyl alcohols : 
Primary: 

»Iso (Isopropylcarbinol) 

»Normal (n-Propylcarbinol) 

Secondary (Methylethylcarbinol) 

Tertiary (Trimethylcarbinol) 

Mixed 

2,6-Dimethyl-4-heptanol (Dlisobutylcarbinol) 

»Ethyl alcohol, synthetic 

2-Ethyl-l-butanol - - 

»2-Ethyl-l-hexanol 

2-Ethyl-4-methyl-l-pentanol 

4-Etlyrl-l-octyn-3-ol 

Heptyl alcohol 

Hexyl alcohol 

Hexynol 

»Iso-octyl alcohols 

«Isopropyl alcohols 

«Methanol, synthetic 

2-Methyl-3-buten-2-ol 

2-Methyl-3-butyn-2-ol - 

■i -Methyl -2 -pen tanol (1-Methylisobutyl oarbinol) — 

3 -Methyl -1 -pen tyn-3-ol (Methylparafynol) 

1-Octanol 

2-Octanol (sec-Capryl alcohol) 

Octanols, other 

Propyl alcohol (Propanol) 

2-Propyn-l-ol 

All other (Including mixtures) 

»Aloohole Cio or higher: 

1-Deoanol 

3,9-Diethyl-6-tridecanol 

Dodecyl alcohol (Lauryl alcohol) (95it) 

7-Ethyl-2-methyl-'i-hendecanol 



IFF. 

TBK, WTH. 

TBK. 

CEL, HN, HPC. 

UCC. 

UCC. 

UCC. 

HEX. 

EKX, UCC. 

GIV. 

UCC. 

GIV. 

UCC. 

CEL, EK, GIV. 



UCC. 
SHC. 
UCC. 
UCC. 
UCC. 
EK. 



DEC, EKX, ENJ, SHC, UCC. 

CEL, CO, DEC, EKX, ENJ, SHC, UCC. 

ENJ, SHC. 

SHC. 

DEC, EKX. 

UCC. 

CEL, DUP, EKX, ENJ, HPC, SHC, UCC, USI. 

UCC. 

CEL, EKX, ENJ, SHC, UCC. 

EKX. 

cue. 

EKX. 

EKX, ENJ, UCC. 
cue, LIL. 

ENJ, GOC, HOU, 0X0, TID, UCC. 

ENJ, SHC, UCC. 

ACN, BOR, CEL, COM, DUP, ENJ, ESC, GOC, HN, HPC, MON, 
RCI, m, TCC, UCC. 

cue. 
cue. 

SHC, UCC. 

cue. 

DUP. 

HH, WTH. 

EKX, PG. 

CEL, UCC. 

GAF. 

CEL, CO, PG, TNA. 

DUP, TNA. 

UCC. 

DUP, PG, RH. 

UCC. 



MLSCtllANEOUS CHEMICALS 



185 



TABLE 21B. 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 966 --Continued 



Manufacturers' identification codes 
(according to list in table 22) 



kOSCELLANEOUS CHEMICALS, ACYCUC— Continued 

Alcohols. Monohydnc, Unsubstituted~-Continued 
"Alcohols Cio or higher--Continued 

1-Hexadecanol (Cetyl alcohol) (955t) - 

Hexadeoyl alcohols 

»l8odeoyl alcohol 

1-Octadecanol (Stearyl alcohol) (955t) - 

ois-9-Octadecen-l-ol (Oleyl alcohol) 

Tetradecyl alcohols 

Trideoanol mixed isomers 

2,6,8-Trimethyl-<l-nonanol 

All other (Including mixtures) 

folyhydric Alcohols and Their Esters and Ethers 

»ft)lyhydrlo alcohols: 

1,4-Butanediol 

l,2(and l,3)-Butanediol (Butylene glycol) 

2-Butene-l,4-diol 

2-Butyne-l,^-diol — 

3-Chloro-l,2-propanediol (Glycerol a-chlorohydrin) 

1,10-Deoanediol - 

2,5-DiJiiethyl-2,5-hexanediol - 

2,5-Dljiiethyl-3-hexyne-2,5-dlol— 

2,2-Dliiiethyl-l,3-propanediol (Mopentyl glycol)— 

•Ethylene glycol 

2-Ethyl-l,3-hexanediol - 

2-Ethyl-2-(hydroxymethyl)-l,3-propanediol (Trimethylol- 
propane ) . 

Glycerol, synthetic 

1,6-Hexanedlol - 

1,2,6-Hexanetriol - - - 

2-(I^roxymethyl)-2-methyl-l,3-propanedlol (Trimethylol- 
ethane). 

Mannltol - — 

3-Mercapto-l,2-propanediol ( Thioglycerol ) 

Methylglycerol 

2-Methyl-2,'i-pentanediol (Hexylene glycol) 

2 -Methyl -2 -propyl -1,3 -propanediol 

1,9-Nonanediol - 

»Pentaerythrltol 

♦Propylene glycol (1,2-Propanediol) 

•Sorbitol - 

2,2,4-Trimethyl-l,3-pentanediol - 

•Polyhydrlc alcohol esters: 

1,3-Butanediol dimethacrylate 

2-(2-Butoxyethoxy)ethyl acetate 

2-Butoxyetliyl acetate 

Diethylene glycol ohloroformate 

2-Ethoxyethyl acetate 

Ethylene glycol diaoetate 

Ethylene glycol dimeroaptoaoetate 

Etl^lene glycol dimethacrylate 

Ethylene glycol hydroxyacetate 

2-Ethyl-l,3-hexanediol titanate 

2 -Ethyl -2 ( hydroxymethyl ) -1, 3 -propanediol trijnethacrylate 

Glyceryl monoacetate (Ifonoacetin) 

Glyceryl triacetate (Trlaoetin) 

Glycol adipate 

Hexanetriol octoate 

Hjrdroxyethyl methacrylate 

I^rdroxypropyl methacrylate 

Hydroxypivalyl hydroxypivalate 

2-Methoxyethyl acetate 

Uethoxytriethyleneglycol acetate 

Pantaerythrltol caprylate 

Pentaerythrltol pelargonate 

Polyethylene glycol dimethacrylate 

Propylene glycol diaeetate 



ADM, DUP, GIV, RH. 

ENJ, PG. 

ENJ, GOC, HOU, QXO, TID, UCC. 

ADM, DUP, PG, HH. 

ADM, DUP. 

PG. 

ENJ, GOC, HOU, TID, UCC. 

UCC. 

ADM, CO, EKX, GYR, PG, RH, SHC, TNA, x. 



GAP. 
CEL. 
GAF. 
GAP. 

EVN, ore. 



cue. 
cue. 

EKX. 

ACP, APD, CAU, CEL, DCW, DUP, EKX, GAF, HCH, JCC, CMC, 

UCC, wra. 

UCC. 
CEL. 



APD, 


DOW, 


SHC. 


CEL. 






UCC. 






TRJ. 






APD. 






EVN. 






APD. 






CEL, 


SHC, 


UCC. 


ABB, 


BKL, 


ICO. 


ASM. 






CEL. 


COM, 


HN, HPC, RCI, TRJ 


APD, 


CEL, 


DOW, DUP, JCC, (M 


APD, 


BRD, 


MRK, PFZ. 


EKX. 






SAR. 






UCC. 






UCC. 






PPG. 






DOW, 


EKT, 


UCC. 


UCC. 






EVN. 






SAR. 






CCA. 






DUP. 






SAR. 






ARC, 


HAL. 




EKT, 


UCC. 




x. 






ARC. 






AAC. 






JCC. 






EKX. 






UCC. 






RBC. 






DRW. 







SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1966 — Continued 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAI5, ACyCLIC--Continued 

Polyhydnc Alcohols and Their Esters and £t/iers — Continued 

»ft3lyhydric alcohol esters— Continued 

Sucrose oota -acetate 

Tetraethylene glycol dimethacrylate 

Triethylene glycol dimethacrylate 

Tri(hexylene glycol) biborate 

2,2,'4-Trimethyl-l,3-pentanediol monoisobutyrate 

All other — — ■ 

»Polyhydric alcohol ethers : 

3-(Allyloxy)-l,2-propanedlol (Allyl glyceryl ether) ■ 

Bis(2-butoxyethyl) ether (Diethylene glycol di-n-butyl 

ether). 
Bis(2-ethoxyetliyl) ether (Diethylene glycol diethyl 
ether). 

Bis(hydroxyethyl) ether butynediol 

Bis[2-(2-methoxyethoxy)ethyl] ether (Tetraethylene 

glycol dimethyl ether). 
Bis(2-methoxyethyl) ether (Diethylene glycol dimethyl 
ether) . 

»2-Butoxyethanol (Ethylene glycol monobutyl ether) 

*2-(2-Butoxyethoxy)ethanol (Diethylene glycol monobutyl 
ether). 
2-[2-(2-Butoxyethoxy)ethoxy]ethanol (Triethylene glycol 
monobutyl ether). 

l-Butoxyethoxy-2-propanol > 

1,2-Dlbutoxyethane (Ethylene glycol di-n-butyl ether) — ... 

♦Diethylene glycol 

Dletl^lene glycol, borated 

Dime thoxy ethane (Ethylene glycol dimethyl ether) 

»Dlpropylene glycol 

»2-Ethoxyethanol (Ethylene glycol monoethyl ether) 

»2-(2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl 
ether). 

<<2-[2-(2-Ethoxyethoxy)ethoxy]ethanol (Triethylene glycol 
monoethyl ether). 
Ethoxypropanol 

•Glycerol tri(polyoxypropylene) ether 

2-[2-(Hexyloxy)ethoxy]ethanol 

l-Isobutoxy-2-propanol (Propylene glycol Isobutyl ether) 
Isobutoxyethanol 

»2-Methoxyethanol (Ethylene glycol monomethyl ether) 

»2-(2-Methoxyethoxy)ethanol (Diethylene glycol monomethyl 
ether). 

»2-[2-(2-Msthoxyethoxy)ethoxy]ethanol (Triethylene glycol 
monomethyl ether). 
2-(2-Methoxyethoxy)ethyl 2-metho2yethyl ether (Triethy- 
lene glycol dimethyl ether). 
Methoxypolyethylene glycol 

»l-Methoxy-2-propanol 

3-(3-Methoxypropoxy)propanol 

3-[3-(3-Methoxypropoxy)propoxy]propanol 

Methyl butynoxyethanol 

Polyethoxyethylglycerol 

Polyethoxyethylsorbitol 

♦Polyethylene glycol 

Polypropoxy ethers 

♦Polypropylene glycol 

Polytetramethylene ether glycol 

Tetraethylene glycol 

1,1,3,3-Tetramethoxypropane 

2,2'-Thlodlethanol (Thlodlglycol) 

♦Triethylene glycol 

Tripropylene glycol 

All other 

Esters of Monohydric Alcohols 

Allyl methacrylate 



PD. 
SAP. 
SAP. 
USB. 
EKX. 
EK, TNI. 



DOW, JCC, CMC, SHC, UCC. 
DOW, JCC, CMC, SHC, UCC. 



DOW, 


OMC, 


UCC. 












UCC. 
















UCC. 
















ACP, 


CAU, 


DIX, 


DOW, 


EKX, 


GAF, 


HCH, 


JCC, 


GU. 
















A.ST,. 
















CEL, 


DOW, 


JCC, 


OMC, 


UCC, 


WYN. 






DOW, 


JCC, 


OMC, 


UCC. 










DOW, 


JCC, 


OMC, 


UCC. 










DOW, 


OMC, 


UCC. 












UCC. 
















JCC, 


OMC, 


UCC, 


WYN. 










UCC. 
















DOW. 
















UCC. 
















DOW, 


JCC, 


OMC, 


UCC. 










DOW, 


JCC, 


CMC, 


UCC. 










DOW, 


OMC, 


UCC. 












ASL. 
















JCC, 


UCC. 














DOW, 


SHC, 


UCC. 












DOW, 


UCC. 














DOW. 
















cue. 
















GLY. 
















au. 
















ACP, 


DOW, 


DUP, 


GAF, 


JCC, 


OMC, 


UCC, 


WIN 


ACS, 


DOW, 


WYN. 












DOW, 


JCC, 


NLC, 


OMC, 


UCC, 


WXN. 






QKO, 


X. 














DOW. 


UCC. 














KF. 
















PIC, 


UCC. 














ACP, 


CAU, 


DOW, 


GAF, 


HCH, 


JCC, 


CMC, 


UCC. 


DOW, 


UCC. 














DOW, 


UCC, 


WIN. 













MISCELLANEOUS CHEMICALS 



187 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 566- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELUNEOUS CHaCCALS, ACYCLIC— Continued 
Esters of Monohydric 4 (coho is--Contlnued 

Amyl acetates, 90^: 

Amyl acetate (n-Pentyl acetate) 

Isopentyl acetate (Isoamyl acetate) 

Mixed - - - - - 

»Butyl acetates: 

ISO 

»Normal 

Secondary 

Tertiary -- 

Mixed - 

Butyl acrylate 

Butyl chloroacetate 

n-Butyl a-hydroxy-a-methylbutyrate 

Butyl lactate 

tert-Butyl peroxyacetate . 

tert-Butyl peroxy-2-ethylhexanoate 

tert-Butyl peroxyisobutyrate 

t^rt-Butyl peroxylsopropyloarbonate 

tert-Butyl peroxyplvalate 

Cetyl lactate 

Diallyl maleate 

Dibutyl fumarate 

*Dlbutyl maleate - 

Diethyl sec-butylethylmalonate 

Diethyl butylmalonate 

Diethyl sec -butylmalonate 

Diethyl carbonate (Ethyl carbonate) 

Diethyl dlethylmalonate (Diethyl malonic ester) 

Diethyl (ethoxymethylene)malonate 

Diethyl ethylisopentylmalonate 

Diethyl ethylmalonate (Ethyl malonic ester) 

Dietl^l ethyl(l-methylbutyl)malonate (Ethyl 1-methyl butyl 
malonic ester). 

Diethyl ethyl (l -me thy lpropyl)malonate 

Dl(2-ethyl-l-hexyl) fumarate 

Di(2-ethyl-l-hexyl) maleate - — - 

Diethyl maleate 

Diethyl malonate (Malonic ester) 

Dletl^l (l-methylbutyl)malonate 

Diethyl methylmalonate 

Diethyl (l-methylpropyl)malonate 

Diethyl oxalate (Ethyl oxalate) 

Diethyl succinate 

Di-iso-nonyl maleate 

Diiso-octyl fumarate 

Diisopropyl peroxydlcarbonate (Isopropyl percarbonate) 

*Dllauryl 3,3'-thiodiproplonate— 

Dimethyl acetylenedlcarboxylate 

Dimethyl carbonate 

2,5-Diiaethylhexane 2,5-diperoctoate 

Dimethyl malonate 

Dl(4-methyl-2-pentyl) maleate 

Dioctyl maleate 

Distearyl 3,3'-thlodipropionate 

Dlthiobis(stearyl propionate) 

Ditridecyl maleate 

Di(tridecyl) 3,3'-thlodipropionate — 

2-(2-Ethoxyethoxy)ethyl acetate 

»Ethyl acetate (85^) — 

Ethyl acetoacetate 

»Ethyl acrylate 

Ethyl chloroacetate 

Ethyl chlorof ormate 

♦Ethylene carbonate 

Ethyl formate 

2-Ethyl-l-hexyl acetate — 

2-Ethyl-l-hexyl aciylate 



NW, TBK. 






CEL, ENJ, 


UCC. 




EKT, ENJ, 


UCC. 




CEL, EKT, 


ENJ, 


PUB, SHC, UCC. 


ENJ, HPC, 


PUB, 


SHC. 


ENJ. 






CEL. 






CEL, DBC, 


UCC. 




MON. 






BPC. 






COM. 






WTL. 






WTL. 






WTL. 






PPG. 






WTL. 






VND. 






PMP. 






MON, PFZ, 


RCI, 


RUB. 


cue, DUP, 


MON, 


RCI, RUB. 


ABB. 






BPC. 






ABB. 






CTN, FMP. 






BPC, LIL. 






KF. 






LIL. 






LIL. 






ABB, BPC. 






BPC. 






RUB. 






HUB. 






ACY, UCC. 






ABB, KF, 


LIL. 




ABB, LIL. 






BPC. 






BPC. 






MP. 






ICO. 






RUB. 






RUB. 






PPG. 






ACY, CCW, 


EVN, 


HAB. 


EK. 






CTN. 






UPR. 






KF. 






RUB. 






HET, MON, 


PCC. 




ACY, CCW, 


EVN. 




EVN. 






RUB. 






ACY, EVN. 






UCC. 






CEL, EKT, 


ENJ, 


HPC, MON, PUB, UCC 


EKT, UCC. 






CEL, DBC, 


RH, 


JCC. 


DOW, KF, 


MON. 




CTN, FVP. 






DOW, JCC, 


UCC. 




COM. 






EKT, UCC. 






CEL, DBC, 


UCC. 





SYNTHETIC ORGANIC CHEMICALS, 1966 



-Miscellaneous chemicals for which U.S. production or sales were 
manufacturer, iS>66— Continued 



eported, identified by 



MISCELLANEOUS CHEMICAI5, ACYCUC- -Continued 



of Monohydr 



-Continued 



2-Ethyl-l-hexyl methacrylate ""■"": 

Ethyl 2-hydroxy-3-methylbutyrate (Ethyl hydroxylsovalerate ; 

Ethylidene diaoetate- - " " 

Ethyl propionate 

Ethyl silicate ( Tetraethoxysilane ) — - 

Ethyl sulfate (Diethyl sulfate) - 

Ethyl thioglycolate-- -- - 

Fatty acid esters, not included with plastiolzers or sur- 
face-active agents: 

Butyl palmitate 

Dimethyl brassylate 

Ethyl stearate 

Hexadecyl stearate 

Isopropyl linoleate 

Methyl esters of coconut oil 

Methyl esters of cottonseed oil 

Methyl esters of tallow 

Methyl 12 -hydroxys tearate—- - - ■ 

Methyl myristate 

All other - "- ' 

Isobutyl acrylate 

Isobutyl isobutyrate 

Isobutyl undecylenate 

Isodecyl acrylate 

»Iso-octyl mercaptoaoetate 

Iso-octyl 3-meroaptopropionate 

»Isopropyl acetate 

Isopropyl chloroformate 

Lauryl lactate 

Methallylidlne diacetate 

»Methyl acetate - 

Methyl acetoacetate 

Methyl acrylate, monomer 

Methyl borate 

Methyl chloroacetate 

Methyl chloroformate 

Methyl dichloroacetate 

Methyl formate 

Methyl methacrylate, monomer 

4-Methyl-2-pentyl acetate— — 

Methyl sulfate (Dimethyl sulfate) -- 

Methyl vinyl acetate 

Myristyl lactate - 

Octadecyl 3-mercaptopropionate 

*Phosphorus acid esters: 

Bis(2-ethylhexyl) hydrogen phosphate — - 

Butyl phosphates 

Chloropropyl phosphorothioate 

Dibutyl butylphosphonate 

Dibutyl hydrogen phosphate 

Didodecyl hydrogen phosphate 

Diethyl phosphorochloridothionate 

Dimethyl methylphosphonate 

Dimethyl phosphorochloridothionate 

Ethyl phosphates 

Iso-octyl hydrogen phosphate 

Isopentyl octyl hydrogen phosphate 

Methyl phosphates — - - " 

Pentyl phosphates (Amyl phosphates) 

Tributyl phosphate 

Tributyl phosphite 

Tridecyl phosphite 

Trietl^l phosphite 

Triiso-octyl phosphite - " 

Trimethyl phosphate 

Trimethyl phosphite 

Tris(2-ohloroethyl) phosphite 

Trls(2,3-dibromopropyl) phosphate 



Manufacturers' identification codes 
(according to list in table 22) 



RH. 

GEL. 

NW, TBK. 

MTR, SFA, UCC. 

UCC. 

EVN. 



ICO. 

ARC, ICI. 

VND. 

HUM, PG. 

BFR. 

BFR, CHL, HUM. 

BAG, HUM. 

HUM. 

EMR, GLY, GRO, PCS, RT, SUG. 

DEC. 

EKX. 

GIV. 

UCC. 

CCW, EVN, HAB. 

EVN. 

EKT, 

CTN, 

VND. 

UCC. 

BOR, 

EKT, 

CEL, 

CAL, 

DOW, 

CTN. 

KF, 

DUP. 

ACY, DUP, RH. 

PUB, SHC, UCC. 

DUP. 

UCC. 

VND. 

EVN. 



ENJ, HPC, UCC. 
PPG. 



EK, MON, UCC. 
UCC'. 

DEC, RH. 
MHI, SFA. 
KF. 

PD. 



HK, SF, X 

SF. 

COM, MP. 



MISCELLANEOUS CHEMICALS 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were 
manufacturer, i566--Contlnued 



sported, identified by 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMCALS, ACYCLIC— Continued 
filers of Monohydric 4 ico/iois--Cont Inupd 

"Phosphorus acid esters — Continued 

Tris(2-ethylhexyl) phosphite 

Tris(octadecyl ) phosphite 

All other - — 

Propyl acetate 

Propylene carbonate 

Tetraoctyl orthosilicate- 

Titanic acid esters: 

Tetrabutyl titanate 

Tetraisopropyl titanate 

Tetrald.s(2-ethylhexyl) titanate -- -- 

Other - 

Triethyl borate 

Triethyl orthoacetate 

Triethyl orthoformate- 

Triethyl orthopropionate 

Triisodeoyl orthoformate 

Trimethyl orthoformate 

»Vinyl acetate monomer 

All other— 

Halogenaled Hydrocarbons 

1-Bromobutane (n-Butyl bromide) 

2-Brcniobutane (sec-Butyl bromide) 

Bromochloromethane 

l-Bromo-3-chloropropane (Trimethylenechlorobromlde) - 

2-Bromo-2-chloro-l,l,l-trifluoroethane 

l-Bromododecane 

Bromoethane (Ethyl bromide) 

l-Bromohexane (n-Hexyl bromide) 

l-Bromo-3-methylbutane (Isoamyl bromide) 

1-Bromo-octadecane 

1-Bromopentane (n-Amyl bromide) 

2-Bromopentane ( 1-Methylbutyl bromide) 

1-Bromopropane (n-Propyl bromide) 

2-Bromopropane (Isopropyl bromide) 

3-Bromopropene (Allyl bromide) 

Brcmotrichlorome thane 

Brcanotrifluorome thane 

»Carbon tetrachloride 

"Chlorinated paraffins : 

less than 35^ chlorine 

35^-6^^ chlorine - 

65% or more chlorine 

1-Chlorobutane (n-Butyl chloride) 

2-Chlorobutane (sec-Butyl chloride) 

l-Chloro-l,l-difluoroethane 

"Chlorodifluorome thane 

»Chloroethane (Ethyl chloride) 

"Chloroform 

2-Chloro-3-hexyne 

"Chlorome thane (Methyl chloride) 

2-Chloro-2-methylpropane (tert-Butyl -chloride) 

3-Chloro-2-methylpropene (Methallyl chloride)- -- 

Chloropentafluoroethane 

3-Chloropropene (Allyl chloride) 

Chlorotrlfluoroethylene (Trifluorovinyl chloride) 

Chlorotrifluoroethylene, polymerized 

Chlorotrlfluorome thane 

l,2-Dibramo-l,l-dichloroe thane 

Dibromodifluorome thane 

1,2-Dibromoethane (Ethylene dibromide) 

Dibromoethane (Methylene bromide) 

Ij-i-Dibromopentane 

l,2-Dibromo-l,l,2,2-tetrafluoroethane 

Dlchlorobutadiene 

1,^-Dichlorobutene 



DUP, ENJ, 


MON, 


X. 




CEL, EKT, 


ENJ, 


PUB, 


ucr, 


DOW, JCC. 








MON. 








DUP. 








DUP. 








DUP. 








DUP. 








USB. 








EK, KF. 








KF. 









BOR, CEL, cue, DUP, MON, NSC, UCC. 
DUP, EK, HAB, PCC, RH, SAR. 



«PC, 


CIB 


MCH 




ABB 


BPC 






DOW 








DOW 


MCH 






ICI. 








DUP. 








DOW 


MCH 






BPC. 








BPC, 


IJL 






DUP, 


OAF 






BPC, 


CLB 






ABB, 


LIL. 






BPC, 


CIB 


EK. 




BPC. 








CLB, 


DOW. 






MCH. 








DUP. 








ACS, 


DA, 


DOW, 


FMB, FRO, PPG, SF. 


HK. 








CCH, 


DA, 


DVC, 


HK, HPC, KEI, KPS, WOI. 


DA, 


DVC, 


WOI. 




PUB, 


UCC. 






PLC. 








ACQ, 


DUP. 






ACQ, 


DUP, 


KAI, 


PAS, UCC. 


AME, 


DOW, 


DUP 


HPC, PPG, SHC, TNA, USI 


ACS, 


DA, 


DOW, 


DUP, FRO, SF. 


LIL. 








ACS, 


Am, 


DCC 


DOW, DUP, FRO, TNA, UCC 


CLB, 


EK. 






FMP. 








DUP. 








DOW, 


SHC. 






ACQ, 


MMM. 






HK, 


ItM. 






ACO, 


DUP, 


PAS. 




DOW. 








DOW. 








DOW, 


ETD, 


HCH, 


MCH. 


DOW. 








SDW. 








DUP. 








DUP. 








DUP. 









SYNTHETIC ORGANIC CHEMICALS, 1966 



-Miscellaneous chemicals for which U.S. production or i 
manufacturer, i966--Contlnuecl 



were reported, identified by 



Manufacturers' identifieation eodes 
(according to list in table 22) 



MISCELLANEOUS CHiMICALS, ACYCUC— Continued 
Halogenated Hydrocarbons — Continued 

»Dichlorodifluorome thane 

»l,2-Dichloroethane (Ethylene diohlorlde) - 

»Dlohloromethane (Methylene chloride) 

»l,2-Dlchloropropane (Propylene dichloride) 

2,3-Diohloropropane 

»Dichlorotetrafluoroethane 

1,1-Difluoroe thane 

Wfluorotetrachloroethane 

Diiodomethane (Methylene iodide) 

Hexachloroethane 

Hexafluoropropylene, monomer 

lodoethane (Ethyl iodide), tech 

Iodoform (Triiodomethane) , nonmedioinal 

lodomethane (Methyl iodide) 

1-Iodoperfluorohexane 

lAuryl chlorides 

Ootafluorocyclobutane 

1,1,2,2-Tetrabromoethane (Acetylene tetrabromide ) 

Tetrabromoe thane 

1,1,2,2-Tetraohloroethane (Acetylene tetrachloride) 

»Tetrachloroethylene ( Perchloroethylene ) 

Tetrafluoroetf^lene, monomer 

Tetrafluoroethylene, polymer 

Tetrafluorcmethane 

»l,l,l-Trichloroethane (Methyl chloroform) 

1,1,2-Trlchloroethane (Vinyl trichloride) 

»Trichloroethylene 

»Trichlorofluoromethane 

1,2,3-Trichloropropane 

1,2,3-Trichloropropene 

Trichlorotrifluoroe thane 

»Vinyl chloride, monomer ( Chloroethylene ) 

Vinyl fluoride ■ 

Vinylidene chloride, monomer (1,1-Dlohloroethylene) 

Vinylidene fluoride 

All other ■ 

All Other Miscellaneous Acyclic Chemicals 

Acetyl peroxide 

Alkyl sulfides, mixed 

Aluininum isopropoxide (Alunilnum isopropylate ) 

*2-Butanone peroxide 

»tert-Butyl hydroperoxide 

*tert-Butyl peroxide (Di-tert-butyl peroxide) 

Butyrolactone 

Caprolaotone 

»Carbon disulfide 

Carbonyl sulfide 

»2-Chloroethanol (Ethylene chlorohydrln ) 

l-Chloro-2-propanol 

»Decanoyl peroxide 

Dextran 

Dlaldehyde starch 

Diohloropropanol 

Diethylthiophosphoryl chloride 

2,4-Dlhydroxy-3,3-dlmethylbutyric acid, gammalactone 
(Pantolactone). 

2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane 

2,5-Dlmethyl-2,5-di(tert-butylperoxy)hexyne-3 

•I^ioxides, ethers, and acetals: 

Acetone dimethylacetal (2,2-Dijnethoxypropane) 

l-(Allyloxy)-2,3-epoxypropane (Allyl glycidyl ether)—- 

Bls(2-chloroethoxy)methane (Dlchloroethylfonual) 

Bis(2-chloroethyl) ether (Dlohlorodiethyl ether) 



ACG, DUP, KAI, PAS, UCC. 

AME, BPG, DA, DOW, DUP, JCC, MON, CMC, PPG, TNA, UCC. 
ACS, DA, DOW, DUP, FRO, HK, SF. 
DOW, JCC, UCC. 
DOW, UCC. 

ACG, DUP, PAS, UCC. 
ACG, DUP. 
DUP. 

NTB, SDW. 
NES. 
DUP. 

CLE, EK, FMT. 
NTB. 

CI£, EK, FMT, aSA. 
x. 
HK. 
DUP. 
DOW. 
DCW. 
DUP. 

DA, DOW, DUP, FRO, HK, PPG, SF, TTX. 
DUP. 
DUP. 
DUP. 

DOW, HK, PPG, TNA. 
DOW, UCC. 

DOW, DUP, HK, PPG, TTX. 
ACG, DUP, KAI, PAS, UCC. 
DOW, SHC. 
DOW. 

ACG, DUP, PAS, UCC. 

ACS, AME, BFG, CUC, DA, DOW, GNT, GYR, HN, MNO, MON, 
TNA, UCC. 

DOW, TNA. 

BFG, GIB, DUP, EK, KPS. 



WTL. 












ORO. 












CHT. 












AZT, 


CAD, 


NOC, 


RCI, 


UPR, 


WTL. 


AZT, 


CAD, 


UPR, 


WTL. 






AZT, 


CAD, 


RCI, 


SHC, 


UPR, 


WTL. 


GAF. 












UCC. 












BKT, 


BMB, 


PAS, 


PPG, 


SF. 




TKL. 












CMC, 


TKL, 


UCC. 








EK. 












CAD, 


UPR, 


WTL. 








PHR. 












MLS. 












EK, 


ICO. 










ACY. 












CKL. 












WTL. 












WTL. 












DCW. 












DOW, 


SHC. 










TKL. 












DOW, 


UCC. 











MISCELLANEOUS CHEMICALS 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i566- -Continued 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHmiCAlS, ACYCLIC— Continued 



,llo 



i(s — Cont 



All 0th. 

•Epoxides, ethers, and acetals — Continued 

Bis(2-ohloro-l-methylethyl) ether (Dichloroisopropyl 
ether). 

l-Butoxy-2,3-epoxypropane (Butyl glycidyl ether) 

Butylene oxide 

Butyl ether (Di-n-butyl ether) 

Butyl \dnyl ether 

2-Chloro-l,l-dimethoxyethane (Dimethyl ohloracetal)- 

2-Chloroethyl vinyl ether 

Chloromethyl methyl ether 

2,2-Dichloro-l,l-difluoroethyl methyl ether 

Epichlorohydrin 

•Ethylene oxide 

•Ethyl ether: 

Absolute 

Tech — 

U.S.P— - 

Ethyl vinyl ether 

Olycidol (2,3-Epoxy-l-propanol) 

Glyoxal ethylene glycol bis acetal 

Isobutyl vinyl ether 

•Isopropyl ether 

Methylal ( Dime thoxyme thane) 

•Methyl ether (Dimethyl ether) 

Methyl vinyl ether — 

Octadecyl vinyl ether 

Polychlorinated propyl ether 

•Propylene oxide 

Other - - -, 

Ethanedithiol — - 

Ethanethiol - - 

2-(Ethylmercapto)ethanol 

Fats and oils, chemically modified 

Gluoono -delta-lac tone 

Glucoheptonolactone 

Glutaraldehyde bis(sodiujn bisulfite) 

Glyoxal, sodium bisulfite 

Hexachlorodimethyl sulfone 

n-Hexadecyl disulfide 

I^drocarbons : 

1-Butyne (Ethylacetylene) 

n-Dodecane 

Ethylene, from ethyl alcohol, medicinal grade 

Hexadeoane 

J^cene 

n-Octane 

1-Ootadeoene 

Kand 2)-0ctene 

Propyne (Methylacetylene) 

Other - - 

•Lauroyl peroxide 

Magnesium methylate 

Methanesulfanol 

Methyl disulfide - 

Methyl sulfide (Dimethyl sulfide)- 

Methyl sulfoxide - - 

n-Ootadecyl mercaptan 

1-Ootanethiol (n-Octyl mercaptan) 

Organo-aluminum compounds : 

Ethylalumlnum chlorides 

Isobutylaluminum chlorides 

Uethylaluminum chlorides 

Other 

Organo-boron compounds 

Organo-lead ccanpounds ; 

•Tetraethyllead - - — 

•Tetraaethyllead - - — - 

Tetra(me thyl -ethyl )lead - 



DOW. 

SHC. 

DOW, UCC. 

UCC. 

UCC. 

LIL. 

UCC. 

HK, RH. 

DOW. 

CBA, DOW, SHC. 

ACP, CAU, DOW, EKX, GAF, 

MAL. 

ENJ, HPC, UCC, USI. 

MAL, QMS. 

UCC. 

DEC. 

FIN. 

GAF. 

ENJ, SHC, UCC. 

CEL. 

COM, DUP, UCC. 

GAF, UCC. 

GAF. 

JCC. 

CEL, DOW, JCC, CMC, UCC, 

EK, EVN, JCC, PIC. 

RBC. 

EK. 

PAS. 

ABB, BCN, CHL, DOM, RT, ; 

PFZ. 

PEN. 

IDC. 

CFC. 

SFA. 

PAS. 



HCH, JCC, OMC, SNO, UCC, WYN. 



HMY. 








WTH. 








cue. 








cue, 


OOC, 


HMY. 




AZT, 


CAD, 


UPR, 


WTL. 


MRT, 


SFA. 






PAS. 








CRZ. 








CBZ, 


PAS. 






cm. 








HMY. 








PAS. 








TNA, 


TSA. 






TNA, 


TSA. 






TNA, 


TSA. 






ISA. 








ACG, 


CAL, 


SFA. 




DUP, 


HCH, 


NI£, 


TNA. 


DUP, 


HCH, 


NLC, 


TNA. 


DUP, 


TNA. 







SYNTHETIC ORGANIC CHEMICALS, 1966 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, i 966- -Continued 



Manufacturers' identification codes 

(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCUC— Continued 



U! Othi 



•Ma 



die Che 



-Continued 



Organo-lithlum compounds 

Organo-magnesium halides 

Organo-meroury compounds 

Organo-sillcon compounds 

Organo-tin compounds : 

Bis(trlbutyltin) oxide— - 

Dlbutyltin dichlorlde 

Dibutylmethoxytin (Dlbutyl tin methoxide) 

Other - - 

Organo-zino ccmpounds 

Perchlorcmethanethiol ( Perchloromethyl mercaptan) 
Perlargonyl peroxide 

*Phosgene (Carbonyl chloride) 

Pine oil, synthetic 

Polyethylene polysulfide 

Propanone peroxide (Acetone peroxide) 

Propionyl peroxide 

Rare sugars 

Sodium ethoxide 

Sodium formaldehyde bisulfite 

■»Sodium formaldehyde sulfoxylate 

»Sodium methoxide (Sodium methylate) 

Sodium octylate 

Suocinyl peroxide 

Tetrakis(hydroxymethyl)phosphonlum chloride 

Tributylphosphine 

Trideoyl mercaptan 

Trioctylphosphlne oxide 

»Zino formaldehydeaulfoxylate 

Other - 



FTE. 

AHA, x. 

LIL, NTB. 

Dec, ORO, SF, SPD, UCS. 

CCW, X. 

CCW, X. 

CCA. 

CCW, X. 

TNA. 

CHO. 

WTL. 

CTN, DUP, MOB, MAC, CMC, OTC, PPG, RUC, UCC, OPJ, VDM. 

CBY. 

BFG. 

SDH. 

WTL. 



EK, IDC. 

HSH, NOP, RH, ROY. 

BFR, DA, DUP, HSH, KF, QMC, RBC, SFA. 

FIN. 

WTL. 



NOP, RH, ROY. 

ACY, AID, AIX, AHA, CCA, CCW, CWN, DCC, DUP, EK, EKX, 

ENJ, FER, ICO, KF, UL, PFN, PRN, SF, SNW, SYP, TNA, 

UCC, x', X, X, X. 



DIRECTORY OF MANUFACTURERS 



Directory of Manufacturers 

The Directory of Manufacturers lists the companies that report their production of synthetic 
organic chemicals to the U.S. Tariff Commission. The name of each manufacturer is preceded 
by an alphabetical identification symbol. These identification symbols consist of not more than 
three capital letters, and usually bear a relation to the compamy name. 

For 1966, the Directory of Manufacturers lists approximately 825 primary manufacturers 
(see table 22). Some of the companies that report production of synthetic organic chemicals do 
not sell the materials, but consume their entire output in further manufacturing. 

The Directory of Manufacturers lists the reporting companies in two ways: Section 1 lists 
them in alphabetical order by identification symbols; section 2 lists the reporting companies in 
alphabetical order by company name, and gives the corresponding identification symbol and the 
company address. Company divisions are usually listed under the parent company's name. 



TABLE 22. --Synthetic organic chemicals.- Directory of manufacturers , 1966 



SECTION 1. ALPHABEnCAL DIRECTORY BY CODE 
[Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. Tariff Commission 
for 1966 are listed below In the order of their identification codes as used in tables in pt. III. Section 2 of 
this table lists these manufacturers alphabetically and gives their office addresses.] 



Code 




Code 






Identi- 


Name of company 


identi- 


Name of company 




fication 




fication 






AAC 


Alcolac Chemical Corp. 


ARC 


Argus Chemical Corp. 




AAE 


American Aniline & Extract Co., Inc. 


ARK 


Armstrong Cork Co. 




AAI 


American Aliyd Industries 


ARL 


Arol Chemical Products Co. 




AAP 


American Aniline Products, Inc. 


ARM 


Armour Agricultural Chemical Co. 




ABB 


Abbott Laboratories 


ARN 


Arenol Chemical Corp. 




ABS 


Abex Corp., American Brakeblok Div. 


ARP 


Armour Pharmaceutical Co. 




ACB 


Allied Chemical Corp., Barrett Div. 


ARZ 


Arizona Chemical Co. 




ACC 


Amoco Chemicals Corp. 


ASH 


Ashland Oil & Refining Co. 




ACE 


Acme Chemical Co. 


ASL 


Ansul Chemical Go. 




ACG 


Allied Chemical Corp., General Chemical Div. 


AST 






ACI 


Aceto Industrial Chemical Corp. 


ASY 


American Synthetic Rubber Corp. 




ACN 


Allied Chemical Corp., Agricultural Div. 


ATC 


American Tartars Corp. 




AGP 


Allied Chemical Corp., Plastics Div. 


ATL 


Atlantic Chemical Corp. 




ACR 


Acme Resin Corp. 


ATP 


Atco Chemical-Industrial Products, Inc., 


Fine 


ACS 


Allied Chemical Corp., Solvay Process Div. 




Chemicals Div. 




ACT 


Arthur C. Trask Co. 


ATR 


Atlantic Richfield Co., ARCO Chemical Co 


Div. 


ACU 


Allied Chemical Corp., Union Texas Petroleum 


ATU 


Atlantic Tubing & Rubber Co. 






Div. 


AUG 


Augusta Chemical Go. 




ACY 


American Cyanamid Co. 


AV 


FlC Corp., American Viscose Div. 




ADM 


ADM Co. 


AVS 


Avisun Corp. 




AFP 


Air Products & Chemical, Inc., Apache Foam 
Products Div. 


AZT 


Aatec Chemicals, Inc. 




AKS 


Arkansas Co., Inc. 


BAC 


Baker Castor Oil Co. 




ALB 


Ames Laboratories, Inc. 


BAL 


Baltimore Paint & Chemical Corp. 




ALC 


Alco Chemical Corp. 


BAR 


American Rubber & Chemical Co. 




AID 


Aldrich Chemical Co., Inc. 


BAX 


Baxter Laboratories, Inc. 




ALF 


Allied Chemical Corp., Fibers Div. 


BCM 


Belding Chemical Industries 




ALL 


Alliance Color & Chemical Co. 


BCN 


l£hn & Fink Products Corp., Beacon Div. 




ALO 


Alamo Industries, Inc. 


BDO 


Benzenoid Organics, Inc. 




ALT 


Crompton & Knowles Corp., Chemicals Group, 


BEN 


Bennett's 






Althouse & Bates Div. 


BFG 


B. F. Goodrich Co., B. F. Goodrich Chemical 


ALX 


Alox Corp. 




Co. Div. 




AMB 


American Bio-Synthetlcs Corp. 


BFR 


Branohf lower Co. 




AJC 


Amchem Products, Inc. 


BJL 


Burdick & Jackson Laboratories, Inc. 




AME 


American Chemical Corp. 


BKC 


J. T. Baker Chemical Co. 




AML 


Amalgamated Chemical Corp. 


BKL 


Millmaster Onyx Corp., Berkeley Chemical Div. 


AMD 


American Oil Go. (Texas) 


BKM 


Buckman Laboratories, Inc. 




AMP 


American Potash & Chemical Corp. 


BKS 


Tenneco Chemicals, Inc., Berkshire Color 


Div. 


AMR 


Pacific Resins & Chemical Co. 


BKT 


J. T. Baker Chemical Co., Taylor Div. 




AMS 


Martin-Marietta Corp., Rldgway Color & 


BL 


Belle Chemical Co., Inc. 






Chemical Div. 


BLA 


Blue Arrow, Inc. 




ANM 


Ancon Chemical Corp. 


BLN 


Brooklyn Color Works, Inc. 




APD 


Atlas Chemical Industries, Inc. 


BLS 


Beech-Nut Life Savers, Inc. 




APR 


Atlas Processing Co. 


BME 


Bendix Corp., Marshall-Eclipse Div. 




APT 


American Petrochemical Corp. 


BOR 


Borden Co., Borden Chemical Co. Div. 




APV 


Armstrong Paint & Varnish Works, Inc. 


BOY 


Walter N. Boysen Go. 




APX 


Apex Chemical Co., Inc. 


BPC 


Cowles Chemical Co., Benzol Products Div 




AHA 


Arapahoe Chemicals, Div. of Syntex Corp. 


BPL 


Brand Plastics Co. 




ARC 


Armour Industrial Chemical Co. 


BRD 


Baird Chemical Industries, Inc. 




ARD 


Ardmore Chemical Co. 


BRS 


Bristol-Meyers Co., Bristol Uboratories 


Div. 



SYNTHETIC ORGANIC CHEMICALS, 1966 
TABLE 22. --Synthetic organic chemicals.- Directory of manufacturers , i 566— Continued 



Code 




Code 




identi- 


Name of company 


identi- 


Name of company 


fication 




fication 




BRU 


M. A. Bruder & Sons, Inc. 


COR 


Commonwealth Oil Refining Co., Inc. 


BRY 


Bryant Chemical Corp. 


CP 


Colgate-Palmolive Co. 


ESC 


Burkart-Sohler Chemical Co. 


CPC 


Chi Ids Pulp Colors, Inc. 


BST 


Best Fertilizers Co. 


CPD 


Chemical Products Corp. 


BSW 


Original Bradford Soap Works, Inc. 


CPV 


Cook Paint & Varnish Co. 


BUG 


Blaokman-Uhler Chemical Co. 


CPY 


Copolymer Rubber & Chemical Corp. 


BUX 


Buckeye Cellulose Corp. 


CRC 


Crown Chemical Corp. 


BUR 


Burroughs -Wellcome & Co. (U.S.A.), Inc. 


CRN 


Com Products Co. 


BXT 


J. H. Baxter & Co. 


cas 


Carus Chemical Co., Inc. 






CRT 


Crest Chemical Corp. 


CAD 


Cadet Chemical Corp. 


CRY 


Tenneco Manufacturing Co., Tenneco Plastics 


CAL 


Callery Chemical Co. 




Dlv. 


CAT 


Ashland Oil & Refining Co., Catalin Corp. Dlv. 


CRZ 


Crown Zellerbach Corp., Chemical Products Div. 


CAU 


Calcasieu Chemical Corp. 


CSB 


Chemical Services of Baltimore, Inc. 


CBA 


Ciba Corp., Clba Products Co. 


CSD 


Cosden Oil & Chemical Co. 


CBC 


Georgia-Pacific Corp., Coos Bay Div. 


CSO 


Cities Service Oil Co. 


CBD 


Chembond Corp. 


CST 


Charles S. Tanner Co. 


CBM 


Carborundum Co., Coated Abrasives Dlv. 


CIA 


Conestoga Chemical Corp. 


CBN 


Columbian Carbon Co., Inc. and Chemicals Div. 


CTL 


Continental Chemical Co. 


CBP 


Ciba Corp., Clba Pharmaceutical Co. Div. 


CTN 


Chemetron Corp., Chemetron Chemicals Dlv., 


CBR 


Colab Resin Corp. 




Organic Chemical Dept. 


CBT 


Samuel Cabot, Inc. 


cue 


Cumberland Chemical Corp., a Subsidiary of 


CBY 


Crosby Chemicals, Inc. 




Air Reduction Co., Inc. 


CCA 


Carlisle Chemical Works, Inc., Advance Div. 


CUL 


Culver Chemical Co. 


CCC 


Chase Chemical Corp. 


CUT 


Cutter Laboratories, Inc. 


CCH 


Pearsall Chemical Co. 


CW 


General Mills, Inc., Chemical Div. 


CCL 


Charlotte Chemical Laboratories 


OWL 


Cowles Chemical Co. 


CCO 


Chemlco, Inc. 


OWN 


Upjohn Co., Carwin Organic Chemicals 


CCP 


Crown Central Petroleum Corp. 


CWP 


Consolidated Papers, Inc. 


CCW 


Carlisle Chemical Works, Inc. 


CYC 


Cyolamate Corp. of America 


CD 


Budd Co., Polyohem Dlv. 






CEL 


Celanese Corp. of America: 


DA 


Diamond Alkali Co., and Western Div. 




Celanese Chemical Co. Dlv. 


DAN 


Dan River Mills, Inc. 




Celanese Coatings Co. 


DAV 


Conchemco, Inc., H. B. Davis Co. Dlv. 




Celanese Plastics Co. 


DBC 


Dow Badische Co. 




Fibers Co. Div. 


DCC 


Dow Coming Corp. 


CFA 


Cooperative Farm Chemicals Association 


DEG 


Degen Oil & Chemical Co. 


CFC 


Sun Chemical Corp. -Kearny 


DEP 


DePaul Chemical Co., Inc. 


CGL 


Cargin, Inc. 


DEX 


Dexter Chemical Corp. 


CHC 


Chlpman Chemical Co., Inc. 


DLX 


Dixie Chemical Co. 


CHF 


Chemical Formulators, Inc. 


DLH 


Hess Oil & Chemical Corp. 


CHG 


Chemagro Corp. 


DLI 


Dawe's Laboratories, Inc. 


CHL 


Chemol, Inc. 


DOM 


Dominion Products, Inc. 


CHO 


Stauffer Chemical Co., Calilo Chemicals, 


DOW 


Dow Chemical Co. 




Inc. Div. 


DPP 


Dixie Pine Products Co., Inc. 


CHT 


Chattem Drug & Chemical Co., Chattem 


DRW 


Drew Chemical Corp. 




Chemicals Dlv. 


DSC 


Dye Specialties, Inc. 


CIB 


Clba Chemical & Dye Co. 


DSO 


DeSoto Chemical Coatings, Inc. 


CIK 


Tenneco Chemicals, Inc., Cal/Ink Dlv. 


DUN 


Frank W. Dunne Co. 


CIS 


Chemical Insecticide Corp. 


DUP 


E. I. duPont de Nemours & Co., Inc. 


CKL 


Chemlek Laboratories, Inc. 


DVC 


Dover Chemical Corp. 


CLB 


Columbia Organic Chemicals Co., Inc. 


nxs 


Sunray DX Oil Co. 


CLC 


Charles L. Hulsking & Co., Inc., Cllntbrook 
Chemical Co. Dlv. 


DYS 


Davies-Young Soap Co. 


CLD 


Colloids, Inc. 


EAK 




CLI 


Cllntwood Chemical Co. 


ECC 


Eastern Color & Chemical Co. 


CLK 


Clark Oil & Refining Corp. 


EDC 


Edoan Laboratories 


CLN 


Standard Brands, Inc., Clinton Com Proces- 


EFH 


E. F. Houghton & Co. 




sing Co. Div. 


EK 


Eastman Kodak Co. 


CLV 


Clover Chemical Co. 


EKT 


Eastman Kodak Co., Tennessee Eastman Co. Div. 


CLY 


W. A. Cleary Corp. 


EKX 


Eastman Kodak Co., Texas Eastman Co. Dlv. 


CM 


Carpenter -Morton Co. 


ELP 


El Paso Products Co. 


CMG 


Nyanza, Inc. 


EMK 


Emkay Chemical Co. 


CMP 


Commercial Products Co., Inc. 


EMR 


Emery Industries, Inc. 


CNC 


Columbian Nitrogen Corp. 


EN 


Endo Laboratories, Inc. 


CO 


Continental Oil Co. 


ENJ 


Enjay Chemical Co. 


COK 


Cockerllle Chemicals, Inc. 


EPC 


Epoxyllte Corp. 


COL 


Collier Carbon & Chemical Corp. 


ESA 


East Shore Chendoal Co., Inc. 


COM 


Commercial Solvents Corp. 


ESC 


Escambia Chemical Corp. 


CON 


Concord Chemical Co., Inc. 


ETD 


Ethyl-Dow Chemical Co. 


COP 


Coopers Creek Chemical Corp. 


EVN 


Evans Chemetics, Inc. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. --Synthetic organic chemicals.- Directory of manufacturers , i 966- -Continued 



195 



Code 




Code 




identi- 
fication 


Name of company 


identi- 
fication 


Name of company 


EW 


Westlnghouse Electric Corp., Insulating 


GRC 


W. R. Grace & Co., Dubois Chemicals Div. 




Materials Div. - BenoUte 


GRD 


W. R. Grace & Co., Dewey & Almy Chemical Div. 






ORG 


P. D. George Co. 


FAB 


Fabricolor Manufacturing Corp. 


GRH 


W. R. Grace & Co. , Hatco Chemical Div. 


FAR 


Famow, Inc. 


GRL 


W. R. Grace & Co., Vestal Laboratories Div. 


FB 


Fritzsche Bros., Inc. 


GRO 


A. Gross & Co., Inc. 


FBF 


Rexall Chemical Co., Fiberfll Div. 


GRS 


Pontlac Refining Corp. 


FBR 


Fibreboard Corp. 


GRV 


Guardsman Chemical Coatings, Inc. 


FC 


Franklin Chemical Co. 


GRW 


Great Western Sugar Co. 


FCA 


Farmers Chemical Association, Inc. 


GTH 


Guth Chemical Co. 


FCD 


France, Campbell & Darling, Inc. 


GTL 


Great Lakes Chemical Corp. 


FCL 


Federal Color Laboratories, Inc. 


GYR 


Goodyear Tire & Rubber Co. 


FEL 


Felton Chemical Co., Inc. 






FER 


Ferro Corp., Ferro Chemical Div. 


HAB 


Halby Products Co., Inc. 


FG 


Foster Grant Co., Inc. 


HAL 


C. P. Hall Co. of Illinois 


FH 


Foster-Heaton Co. 


HAM 


Hampden Color & Chemical Co. 


FIN 


Fine Organics, Inc. 


HAN 


Hanna Paint Manufacturing Co., Inc. 


FIR 


Firestone Tire & Rubber Co., Firestone 


HAP 


AppUed Plastics Co., Inc. 




Plastics Co. Div. 


HCH 


Houston Chemical Corp. 


FIS 


Fisher Melamine Corp. 


HCO 


Nyanza, Inc., Hamilton Chemical Div. 


FLH 


H. B. Fuller Co. 


HDG 


Hodag Chemical Corp. 


FLM 


Fleming Laboratories, Inc. 


HER 


Heresite & Chemical Co. 


FLO 




HET 


Heterochemical Corp. 


FLW 


W. P. PuUer Paint Co. 


HEX 


Hexagon Laboratories, Inc. 


FMB 


FM: Corp., Inorganic Chemicals Div. 


HFT 


Hoffman-Taff, Inc. 


FMN 


FMC Corp., Niagara Chemical Div. 


HK 


Hooker Chemical Corp. 


FMP 


FJK Corp., Organic Chemicals Div. 


HKD 


Hooker Chemical Corp., Durez Plastics Div. 


FMT 


Fairmount Chemical Co., Inc. 


HKY 


Hawkeye Chemical Co. 


FOC 


Farac Oil & Chemical Co., Div. of Handsohy 


HLC 


Hartman-Leddon Co. 




Chemical Co. 


HLI 


Haag Laboratories, Inc. 


FQM 


Formica Corp. 


HMP 


W. R. Grace & Co., Hampshire Chemical Div. 


FOR 


Foremost Chemical Products Co. 


HMY 


Humphrey Chemical Co. 


FRE 


Freeman Chemical Corp. 


HN 


Tenneeo Chemicals, Inc. 


FRL 


Firestone Tire & Rubber Co., Firestone 


HNC 


H & N Chemical Co. 




Rubber & Latex Products Co. Div. 


HNT 


Huntington Laboratories, Inc. 


FRM 


Farmer's Chemical Co. 


HNW 


Tenneeo Chemicals, Inc., Newport Div. 


FRO 


Vulcan Materials Co., Chemicals Div. 


HNX 


Tenneeo Chemicals, Inc., Nuodex Div. 


FRP 


Filtered Rosin Products Co. 


HOF 


Hoffmann-LaRoche, Inc. 


FRS 


Firestone Tire & Rubber Co., Firestone 


HOU 


Air Products & Chemicals, Inc., Houdry 




Synthetic Rubber & Latex Co. Div. 




Process & Chemical Div. 


FSH 


Frisoh & Co., Inc. 


HPC 


Hercules, Inc. 


FTE 


Foote Mineral Co. 


HHS 


Grow Chemical Corp., Harris Paint Co. Div. 


Fra 


Fel-Tex, Inc. 


HRT 


Hart Products Corp. 






HSC 


HoUand-Suco Color Co. 


OAF 


General Aniline & Film Corp., Dyestuff & 


HSH 


Harshaw Chemical Co., Div. of Kewanee Oil Co. 




Chemical Div. 


HST 


American Hoechst Corp. 


GAM 


Gamma Chemical Corp. 


HUM 


National Dairy Products Corp;, Humko Products 


CAN 


Gane's Chemical Works, Inc. 




Chemical Div. 


GCC 


W. R. Grace & Co., Agricultural Products Div. 


HUS 


Husky Briquet ting. Inc. 


GDN 


Lancaster Chemical Corp., Gordon Chemicals 


HVG 


Haveg Industries, Inc., Resin & Compound Div. 




Co. Div. 


HYC 


Hysol Corp. 


GE 


General Electric Co., Chemical Materials Dept. 


HYN 


Hynson, Westcott & Dunning, Inc. 


GEI 


General Electric Co., Insulating Materials 








Dept. 


IBI 


Industrial Blochemicals 


CffS 


G. Frederick Smith Chemical Co. 


ICC 


Interchemlcal Corp., Color & Chemicals Div. 


GOC 


Goodrich-Gulf Chemicals, Inc. 


ICF 


Interchemical Corp., Finishes Div. 


GGY 


Geigy Chemical Corp. 


ICI 


I. C. I. (Organics), Inc. 


GIL 


Oilman Paint & Varnish Co. 


ICO 


Interchemical Corp., Organic Chemicals Dept. 


GIV 


Givaudan Corp. 


IDC 


Industrial Dyestuff Co. 


GLC 


General Latex & Chemical Corp. 


IFF 


International Flavors & Fragrances, Inc. 


GLD 


Glldden Co., and Durkee Famous Foods Div. 


ILC 


International Latex & Chemical Corp. 


GDC 


Glasflex, Inc. 


IMC 


International Minerals & Chemical Corp. 


GLY 


Glyco Chemicals, Inc. 


IMP 


Hercules, Inc., Imperial Color & Chemical Dept. 
Imperial, Inc. 


GNF 


General Foods Corp., Maxwell House Div. 


IMR 


GNM 


General Mills, Inc. 


INL 


Inland Steel Container Co. 


GNT 


General Tire & Rubber Co., Chemical Div. 


IOC 


Hitter Pfaudler Corp., lonac Chemical Co. Div. 


GOC 


Gulf Oil Corp. 


IPC 


Interplastic Corp., Commercial Resins Div. 


GCfi 


Gordon Chemical Co., Inc. 


IPI 


Isocyanate Products, Inc. 


GPM 


General Plastics Manufacturing Co. 


IPR 


Inter-Pacific Resins, Inc. 


GPR 


Grain Processing Corp. 


IRC 


IRC, Inc. 


GRA 


Great American Plastics Co. 


IRI 


Ironsides Resins, Inc. 



196 SYNTHETIC ORGANIC CHEMICALS, 1966 

TABLE 22. --Synthetic organic chemicals.- Directory of manufacturers , i566— Continued 



Code 




Code 




identi- 


Name of company 


identi- 


Name of company 


fication 




fication 




JCC 


Jefferson Chemical Co., Inc. 


MEE 


Maumee Chemical Co. 


JDC 


Nipak, Inc. 


MER 


Merichem Co. 


JEN 


Jennison-Wright Corp. 


MET 


M & T Chemicals, Inc. 


JIE 


J. Meyer & Sons, Inc. 


MFG 


Molded Fiber Glass Body Co., Resin Div. 


JNS 


S. C. Johnson & Son, Inc. 


MIK 


McLaughlin Gormley King Co. 


JOB 


Jones-Blair Paint Co. 


JGR 


Magruder Color Co., Inc. 


JOR 


Jordan Chemical Co. 


MHI 


Ventron Corp., Ifetal Hydrides Div. 


JRG 


Andrew Jergens Co. 


MID 


Midland Industrial Finishes Co. 


JSC 


Jersey State Chemical Co. 


MIR 


Miranol Chemical Co., Inc. 


JTC 


Joseph Turner & Co. 


MID 


Metalead Products Corp. 


JWL 


Jewel Paint & Vamish Co. 


MLS 


Miles Laboratories, Inc., Chemicals Div. 






MMM 


Minnesota Mining & Manufacturing Co. 


KAI 


Kaiser Aluminum & Chemical Corp. , Kaiser 


MNO 


Monochem, Inc. 




Chemicals Div. 


MNP 


Minnesota Paints, Inc. 


KAl 


Kali Manufacturing Co. 


M3A 


Mona Industries, Inc. 


KCC 


Kennecott Copper Corp., Chino Mines Div. 


MOB 


Mobay Chemical Co. 


KCH 


Keystone Chemurgic Corp. 


MOC 


Marathon Oil Co., Texas Refining Div. 


KCU 


Kennecott Copper Corp., Utah Copper Div. 


MDN 


Monsanto Co. 


KCW 


Keystone Color Works, Inc. 


MOR 


Mineral Oil Refining Co. 


KEI 


Keil Chemical Co. 


MOT 


Motoraco, Inc. 


KEL 


Kelly-Pickering Chemical Corp. 


MPP 


Midwest Plastic Products Co. 


KEN 


Kendall Refining Co. 


MR 


Benjamin Moore & Co. 


KET 


Ketona Chemical Corp. 


MRA 


Metro-Atlantic, Inc. 


KF 


Kay-Fries Chemicals, Inc. 


MRB 


Marblette Corp. 


KMC 


Kohler-McUster Paint Co. 


MRD 


Marden-Wild Corp. 


KMP 


Kelly -Ktoore Paint Co. 


MRK 


Merck & Co., Inc. 


KND 


Knoedler Chemical Co. 


MRN 


International Latex & Chemical Corp., Paisley 


KNG 


Far -Best Corp., 0. L. King Div. 




Products Div. 


KNP 


Knapp Products, Inc. 


MRO 


W. R. Grace & Co., Marco Chemical Div. 


KON 


H. Kohnstamm & Co., Inc. 


MRT 


Morton Chemical Co. 


KPI 


Kenrich Petrochemicals, Inc. 


MRV 


Marlowe-Van Loan Corp. 


KPP 


Sinclalr-Koppers Co. 


MRX 


Max Marx Color & Chemical Co. 


KPS 


Koppers Pittsburgh Co. 


MSC 


Mississippi Chemical Corp. 


KPT 


Koppers Co., Inc., Tar & Chemical Div. 


MTO 


((tontrose Chemical Corp. of California 


KRM 


Lawter Chemicals, Inc., Krumbhaar Resin Div. 


MTR 


Baldwin -Ifontrose Chemical Co., Inc., Montrose 


KYN 


Kyanize Paints, Inc. 




Chemical Div. 


KIS 


Keysor Chemical Co. 


MYW 


Stepan Chemical Co., Maywood Div. 


LAK 


Lakeway Chemical Co. 


NAC 


Allied Chemioal Corp., Industrial Chemicals 


LAM 


Lalfotte Chemical Products Co. 




Div. 


LAS 


Lasco Industries, Inc. 


NCI 


Union Camp Corp., Chemical Div. 


LEA 


Leatex Chemical Co. 


NCW 


Nostrip Chemical Works, Inc. 


LEB 


Lebanon Chemical Corp. 


NEO 


Norda Essential Oil & Chemical Co., Inc. 


LEF 


Leffingwell Chemical Co. 


NEP 


Nepera Chemical Co., Inc. 


LEM 


B. L. Lemke k Co., Inc. 


NES 


Nease Chemical Co., Inc. 


LEN 


Leonard Refineries, Inc. 


NEV 


Neville Chemical Co. 


LEV 


Lever Brothers Co. 


NIL 


Nilok Chemicals, Inc. 


LIL 


Ell Ully & Co. 


NIT 


Nltrin, Inc. 


LKL 


Lakeside Laboratories, Div. of Colgate- 


NIX 


Tenneco Chemicals, Inc., Nixon-Baldwin Div. 




PaljDOlive Co. 


NLC 


Nalco Chemical Co. 


DCT 


St. Regis Paper Co., Lake States Div. 


NMC 


National Milling & Chemioal Co., Inc. 


LMI 


North American Chemical Co. 


NOC 


Norac Co., Inc. and subsidiary Mathe Chemioal 


LPC 


Lignin Products Co. 




Co. 


LUB 


Lubrizol Corp. 


NGN 


A. P. Nonweiler Co. 


LUE 


George Lueders & Co., Inc. 


NOP 


Nopco Chemical Co., Inc. 


LUR 


Laurel Products Corp. 


NOR 


Norwich Pharmacal Co. 


LVR 


C. Lever Co., Inc. 


NPC 


Northwest Petrochemical Corp. 


LVY 


Fred'k H. Levey Co., Inc. 


NPI 


National Polychemicals, Inc. 






NPP 


National Plastic Products Co., Inc. 


MAH 


Maher Color & Chemical Co. 


NPR 


Newport Products Co., Div. of Safeway Stores, 


MAL 


Mallinckrodt Chemical Works 




Inc. 


MAN 


Manganese Chemical Co., Div. of Pickands 


NPV 


Norris Paint & Vamish Co. 




Mather & Co. 


NRS 


Norse Chemical Corp. 


MAR 


American Can Co. 


NSC 


National Starch k Chemical Corp. 


MAY 


Otto B. May, Inc. 


NSP 


Alabama Binder k Chemical Corp. 


MCA 


Masonite Corp., Alpine Chemical Div. 


NTB 


National Biochemical Co. 


MCB 


Borg -Warner Corp. , Marbon Chemical Div. 


NTC 


National Casein Co. 


MCC 


McCloskey Vamish Co. 


NTL 


National Lead Co. 


JCH 


Michigan Chemioal Corp. 


NVF 


N.V.F. Co. 


MCI 


Mooney Chemicals, Inc. 


NVT 


Novamont Corp. 


MED 


Medical Chemicals Corp. 


NW 


Northwestem Chemical Co. 



DIRECTORY OF MANUFACTURERS 197 

TABLE 22.— Synthetic organic chemicals: Directory of manufacturers , 7566- -Continued 



Code 




Code 




identi- 


Name of company 


identi- 


Name of company 


fication 




fication 




NYC 


Tenneco Chemicals, Inc., New York Color 


PSP 


Georgia-Pacific Corp., Puget Sound Div. 




Dlv. 


PTO 


Puerto Rico Chemical Co., Inc. 






PIT 


Petro-Tex Chemical Corp. 


OCF 


Owene-Comlng Fiberglae Corp. 


PUB 


Publicker Industries, Inc. 


OH 


Air Reduction Co., Inc., Ohio Chemical & 


PVI 


Polyvinyl Chemicals, Inc. 




Surgical Equipment Co. Dlv. 


PYL 


Polychemical Laboratories, Inc. 


OMC 


Olin Mathleson Chemical Corp. 


PYR 


Poly Resins 


QMS 


E. R. Squibb & Sons, Inc. 


PYZ 


Polyrez Co . , Inc . 


OhK 


Jilllmaster Onyx Corp., Onyx Chemical Div. 






OPC 


Orbls Products Corp. 


QCP 


Quaker Chemical Corp. 


ORG 


Oi^anlos, Inc. 


QKO 


Quaker Oats Co. 


ORO 


Chevron Chemical Co., Additives Div. 


QUN 


K. J. Quinn & Co., Inc. 


ORT 


Roehr Chemicals, Inc. 






ceB 


C. J. Osbom Co. 


RAB 


Raybestos -Manhattan, Inc., Raybestos Div. 


OTA 


Ottawa Chemical Co. 


RBC 


Roberts Chemicals, Inc. 


OTC 


Ott Chemical Co. 


RCC 


Rexall Chemical Co. 


OTH 


Chevron Chemical Co., Ortho Dlv. 


RCD 


Richardson Co. 


0X0 


Oxo Chemicals Co. 


RCI 


Relchhold Chemicals, Inc. 


OXR 


Onyx Oils & Resins, Inc. 


RDA 


Rhodia, Inc. 






RED 


Red Spot Paint & Varnish Co., Inc. 


PAI 


Pennsylvania Industrial Chemical Corp. 


REH 


Rebels Chemical Co., Div. of Armour 


PAN 


Pan American Petroleum Corp. 




Pharmaceutical Co. 


PAR 


Pennsylvania Refining Co. 


REL 


ReUance Universal, Inc. 


PAS 


Pennsalt Chemicals Corp. 


REM 


Remington Arms Co., Inc. 


PAT 


Patent Chemicals, Inc. 


REN 


Reni-oh Resins 


PBY 


Pillsbury Co., Chemical Div. 


RET 


Rayette-Faberge, Inc. 


PC 


Proctor Chemical Co., Inc. 


REZ 


Rezolln, Inc. 


PCC 


USS Chemicals, Div. of U.S. Steel Corp. 


RGC 


Rogers Corp. 


PCH 


Peerless Chemical Co. 


RH 


Rohm & Haas Co. 


PCI 


Pioneer Chemical Works, Inc. 


RIC 


Atlantic Richfield Co., Richfield Div. 


PCS 


Emery Industries, Inc., Western Dlv. 


RIK 


Riker Laboratories, Div. of Rexall Drug «■ 


PCW 


Pf ister Chemical Works 




Chemical Co. 


PD 


Parke, Davis & Co. 


RIL 


Rellly Tar & Chemical Corp. 


PDC 


Bemcolors-Poughkeepsie, Inc. 


RIV 


Rlverdale Chemical Co. 


PDJ 


Joseph Davis Plastics Co. 


RLS 


Rachelle Laboratories, Inc. 


PEK 


Peck's Products Co. 


ROC 


Rock Hill Printing & Finishing Co. 


PEL 


Pelron Corp. 


ROM 


United Jferchants & Manufacturers, Inc., Roma 


PEN 


S. B. Penick & Co. 




Chemical Div. 


PER 


Perry & Derrick Co. 


ROY 


Royce Chemical Co. 


PFN 


Pfanstiehl Laboratories, Inc. 


RPC 


Refined Products Co. 


PFP 


Phelan-Faust Paint Manufacturing Co., 


RSA 


R.S.A. Corp. 




Phelan's Resins & Plastics Div. 


RSB 


Rosenberg Bros. & Co. 


PFW 


Polak's Frutal Works 


RT 


F. Ritter & Co. 


PFZ 


Chas. Pfizer & Co., Inc. 


RTC 


Rltter Chemical Co., Inc. 


PG 


Procter & Gamble Co. 


RTF 


Retzloff Chemical Co. 


PGU 


Gulf Oil Corp., Chemicals Dept., Perkins Glue 


RUB 


Hooker Chemical Corp., Ruco Div. 




Branch 


RUC 


Rubicon Chemicals, Inc. 


PHR 


Pharmachem Corp. 






PIC 


Pierce Organlcs, Inc. 


S 


Sandoz, Inc. 


PI I 


Polymer Industries, Inc. 


SAC 


Southeastern Adhesives Co. 


PIL 


Pilot Chemical Co. 


SAL 


Salsbury Laboratories 


PIT 


Pitt-Consol Chemical Co. 


SAR 


Sartomer Resins, Inc. 


PLA 


Richardson Co., Richardson Polymers Div. 


SBC 


Scher Bros., Inc. 


PLB 


P-L Biochemloals, Inc. 


SEP 


Sugar Beet Products Co. 


PLC 


Phillips Petroleum Co. 


sec 


Standard Chlorine Chemical Co., Inc. 


PLS 


Plastics Engineering Co. 


SCF 


Schaefer Varnish Co., Inc. 


PLU 


Plumb Chemical Corp. 


SCH 


Scherlng Corp. 


PMC 


Plastics Manufacturing Co. 


SCN 


Schenectady Chemicals, Inc. 


PMP 


Premier Malt Products, Inc. 


SCO 


Scholler Bros., Inc. 


PNT 


Pantasote Co. 


SCP 


Standard Chemical Products, Inc. 


PNX 


Phoenix Oil Co. 


SCR 


R. P. Scherer Corp. 


POL 


Polymer Corp. 


SDC 


Martin-Marietta Corp., Southern Dyestuff Co. 


PPC 


Premier Petrochemical Co. 




Div. 


PPG 


Pittsburgh Plate Glass Co. 


SDG 


Sterling Drug, Inc., Glenbrook Laboratories 


PPL 


Pioneer Plastics Corp., Chemical Dlv. 




Div. 


PRC 


Products Research & Chemical Corp. 


SDH 


SterUng Drug, Inc., Rilton-Davis Chemical 


PRD 


Productol Chemical Co., Inc. 




Co. Div. 


PHP 


S. B. Penick & Co., Parsons -Plymouth Div. 


SDW 


Sterling Drug, Inc., Winthrop Laboratories 


PRT 


Pratt & Lambert, Inc. 




Div. 


PRX 


Purex Corp., Ltd. 


SEA 


Seaboard Chemicals, Inc. 


PSC 


Passaic Color & Chemical Co. 


SED 


Seidlitz Paint & Varnish Co. 



SYNTHETIC ORGANIC CHEMICALS, 1966 
TABLE 22.— Synthetic organic chemicals.- Directory of manufacturers , 1966— Continued 



Code 




Code 




identi- 


Name of company 


identi- 


Name of company 


fication 




fication 




SEK 


Seldsul Plastics Corp. 


SVC 


Sullivan Varnish Co. 


SEL 


Selney Go. , Inc. 


SVT 


Solvent Chemical Co., Inc. 


SEP 


Southeast Polymers, Inc. 


SW 


Sherwin-Williams Co. 


SEY 


Seydel-Woolley & Co., Inc. 


SWT 


Swift & Co. 


SF 


Stauffer Chemical Co., Industrial Chemical 


SYC 


Synthetic Chemicals, Inc. 




Dlv. 


SYN 


Synthron, Inc. 


SFA 


Stauffer Chemical Co., Specialty Chemical Div. 


SYP 


Synthetic Products Co. 


SFD 


Sonford Chemical Co. 


SYR 


ADM Co., Synco Resins 


SH 


Stein, Hall & Co., Inc. 


SYV 


Synvar Corp. 


SHA 


Shanco Plastics & Chemicals, Inc. 






SHC 


Shell Oil Co., Shell Chemical Co. Div. 


lAE 


Chemetron Corp., National Cylinder Gas Div. 


SHF 


National Dairy Products Corp., Sheffield 


TBK 


Universal Oil Products Co., Chemical Div. 




Chemical Co. Div. 


TCC 


Tanatex Chemical Corp. 


SHL 


Shulton, Inc. 


TCH 


Try Ion Chemical Corp. 


SHM 


Shamrock Oil & Gas Corp. 


TCI 


Texize Chemicals, Inc. 


SHO 


Shell Oil Co. 


TDC 


Diversey Corp. 


SHP 


Shepherd Chemical Co. 


TEN 


Tennessee Copper Co. 


SIC 


Vistron Corp., Silmar Div. 


TGL 


Triangle Chemical Co. 


SID 


George F. Slddall Co., Inc. 


THC 


Thompson Apex Co., Div. of Continental Oil Co. 


SIM 


Simpson Timber Co. 


THM 


Thompson Chemical Corp. 


SIN 


Sinclair Refining Co. 


TIC 


Ticonderoga Chemical Corp. 


SIO 


Standard Oil Co. of Ohio 


TID 


Tidewater Oil Co. 


SIP 


James P. Sipe & Co. 


TKL 


Thiokol Chemical Corp. 


SK 


Smith, Kline & French Laboratories 


TMH 


Thompson-Hayward Chemical Co. 


SKC 


Slnclair-Koppers Chemical Co. 


lie 


Sterling Drug, Inc., Thomasset Colors Div. 


SKG 


Sunldst Growers, Inc. 


TNA 


Ethyl Corp. 


SKO 


Skelly Oil Co. 


TNC 


Sun Chemical Corp. 


SLC 


Soluol Chemical Co., Inc. 


TNI 


Gillette Chemical Co. 


SLV 


Sterling Drug, Inc., Salvo Chemical Div. 


TOC 


Tenneco Oil Co., Refining 6 Marketing 


SU 


Mobil Chemical Co.: 




Accoxinting 




Industrial Chemical Div. 


TRC 


Toms River Chemical Corp. 




North Atlantic Div. 


TRJ 


Trojan Powder Co. 




Petrochemical Div. 


TRO 


Troy Chemical Co. 


SM 


Socony Mabil Oil Co., Inc.: 


ISA 


Itexas Alky Is, Inc. 




MDbll Chemical Co. Dlv. and 


TTX 


Detrex Chemical Industries, Inc. 




Chemical Coatings Div., Louisville Plant 


TOS 


Texas-U.S. Chemical Co. 


SMC 


Stamford Chemical Co. 


TV 


Sun Chemical Corp., Industrial Coatings Div. 


SNA 


Sun Chemical Corp., Chemical Products Div. 


TX 


Texaco, Inc. 


SNC 


Sonooo Products Co. 


TXC 


Tex Chem Co. 


SNI 


Kaiser Aluminum & Chemicals Corp., Kaiser 


TXN 


Textilana-Nease, Inc. 




Agricultural Chemicals Dlv. 


TXT 


Textilana Corp. 


SNO 


SunOlin Chemical Co. 


■EC 


Tizon Chemical Corp. 


SNT 


Suntide Refining Co. 






SNW 


Sun Chemical Corp., Chemical Products Dlv. 


UBS 


A. E. Staley Manufacturing Co., UBS 


SOC 


Standard Oil Co. of California, Chevron 




Chemical Co. Div. 




Chemical Co. 


UCC 


Union Carbide Corp., Chemicals Dlv. 


SOG 


Signal Oil & Gas Co. 


UCP 


Union Carbide Corp., Plastics Div. 


SOH 


Sohlo Chemical Co. & Solar Nitrogen Chemicals, 


UCS 


Union Carbide Corp., Silicones Dlv. 




Inc. 


UDI 


PetroohemlcalB Co., Inc. 


SOI 


American Oil Co. (Maryland) 


UHL 


Paul Uhlloh & Co., Inc. 


SOL 


Solar Chemical Corp. 


UNC 


Badisehe Products Corp. 


SON 


Wltco Chemical Co., Inc., Sonnebom Dlv. 


UNG 


Ungerer & Co. 


SOR 


ThomaBon Industries, Inc., Southern Resin Div. 


UNN 


United Chemical Corp. of Norwood 


SOS 


Southern Sizing Co. 


UNO 


United Oil Manufacturing Co. 


SPC 


Sinclair Paint Co. 


UHP 


United Chemical Products Corp. 


SPD 


General Electric Co., Silicone Products Dept. 


UNS 


Union Starch & Refining Co., Inc. 


SPI 


Sinclair Petrochemicals, Inc. 


UOC 


Union Oil Co. of California 


SPL 


Spaulding Fibre Co., Inc. 


UPF 


United States Pipe & Foundry Co. 


SPN 


Gulf Oil Corp., Chemicals Dept. 


UPJ 


Upjohn Co. 


SPY 


Standard Pyroxoloid Corp. 


UPL 


United States Plywood Corp., California Div., 


SHL 


G. D. Searle & Co. 




Shasta Operations 


SRR 


Streaen-Reuter International, International 


UPM 


Universal Oil Products Co. 




Minerals & Chemical Corp. 


UPR 


U.S. Peroxygen Corp. 


STA 


A. E. Staley Manufacturing Co. 


URC 


United Carbon Co. 


STC 


Sou-Tex Chemical Co., Inc. 


USB 


U.S. Borax Research Corp. 


STG 


Stange Co. 


USI 


National Distillers & Chemical Corp. : 


STP 


Stepan Chemical Co., Industrial Chemicals 




A-B Chemleal Corp. Div. 




Div., milsdale Works 




National Petro Chemical Corp. Dlv. 


SDO 


Sucro-Chemlcal, Div. of Colonial Sugars Co. 




U.S. Industrial Chemicals Co. Div. 


SUM 


Summit Chemical Products Corp. 


USO 


U.S. Oil Co. 


SUN 


Sun Oil Co. 


USR 


Uniroyal, Inc., Unlroyal Chemloal Div. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. --Synthetic organic chemicals: Directory of manufacturers , 1966 — Continued 



Code 




Code 




identi- 


Name of compariy 


identi- 


Name of company 


fication 




fication 




UTR 


Utah Resin Co., Inc. 


WES 


Weston Chemical Corp. 


UVC 


Universal Chemicals Corp. 


WHC 


Whittaker Corp., Narmco Research & 
Development Div. 


VAC 


Vamey Chemical Corp. 


WHI 


White & Hodges, Inc. 


VAL 


Valchem 


WHL 


Whitmoyer Laboratories, Inc. 


VAR 


Reichhold Chemicals, Inc., Varcum Chemical 


WHW 


Whittemore -Wright Co., Inc. 




Div. 


WIC 


Wica Chemicals, Inc. 


VB 


Vermi lye -Bell 


WIL 


Wilson & Co., Inc., Wilson Laboratories Div. 


VDM 


Van De Mark Chemical Co. 


WJ 


Warner- Jenklnson Manufacturing Co. 


VEl 


Velsicol Chemical Corp. & Industrial 


WLI 


White Laboratories, Inc. 




Chemicals Div. 


WLM 


Wilmot & Cassidy, Inc. 


VGC 


Virginia Chemicals, Inc. 


WM 


Wilson & Co., Inc., Wilson-Martin Div. 


VIN 


Vlneland Chemical Co. 


WMP 


Warner Machine Products, Inc., Warner 


VLN 


Valley Nitrogen Producers, Inc. 




Chemical Div. 


VLY 


Chem-Fleur, Inc. 


WOB 


Wobum Chemical Corp. 


TOC 


Vanderbilt Chemical Corp. 


WOI 


Neville Chemical Co. 


VND 


Van Dyk & Co., Inc. 


WON 


Woonsocket Color & Chemical Co. 


VPC 


Verona-Pharma Chemical Corp. 


WRC 


Wood Ridge Chemical Corp. 


VPT 


Viokers Refining Co., Inc. 


WRD 


Weyerhaeuser Co., Wood Products Div. 


VSV 


Valentine Sugars, Inc., Vallte Div. 


WSN 


Washine Chemical Corp. 


VTV 


Vita-Var Corp., Div. of Textron Industries, 


WTC 


Witco Chemical Co., Inc. 




Inc. 


WTH 


Wallace & Tlernan, Inc., Harchem Div. 






WTL 


Wallace & Tlernan, Inc., Lucldol Div. 


WAS 


Purex Corp . , Ltd . 


WVA 


West Virginia Pulp & Paper Co., Polyohemioala 


WAW 


W. A. Wood Co. 




Div. 


WAY 


Philip A. Hunt Chemical Corp., Wayland 


WYC 


Wycon 




Chemical Div. 


WYN 


Wyandotte Chemicals Corp. 


WBC 


Worthington Biochemical Corp. 


WYT 


American Home Products Corp., Wyeth Labora- 


WBG 


White & Bag ley Co. 




tories, Inc. Div. 


WCA 


West Coast Adhesives Co. 






WCC 


Witfield Chemical Corp. 


YAW 


Young AniUne Works, Inc. 



SYNTHETIC ORGANIC CHEMICALS, 1966 



TABLE 22. --Synthetic organic chemicals: Directory of manufacturers , i 566 --Continued 

SECTION 2. ALPHABETICAL DIRECTORY BY CCMPANY 
[Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. Tariff Commission 
for 1966 are listed below alphabetically, together with their identification codes aa used in tables in pt. III. 
Sec. 1 of this table lists these manufacturers in the order of their identification codes] 



Name of oonpany 



Office address 



MM Co 

Synco Resins 

Abbott Laboratories 

Abex Corp., American Brakeblok Div 

Aceto Industrial Chemical Corp 

Acme Chemical Co 

Acme Resin Corp 

Air Products & Chemicals, Inc. : 

Apache Foam Products Div 

Houdry Process & Chemical Div 

Air Reduction Co., Inc., Ohio Chemical t 
Surgical Bjulpment Co. Div. 

Alabama Binder & Chemical Corp 

Alamo Industries, Inc 

Alco Chemical Corp 

Alcolac Chemical Corp 

Aldrioh Chemical Co., Ino 

Alliance Color & Chemical Co 

Allied Chemical Corp. : 

Agricultural Div 

Barrett Div 

Fibers Div 

General Chemical Div 

Industrial Chemicals Div 

Plastics Div 

Solvay Process Div 

Union Texas Petroleum Div 

Alox Corp 

Amalgamated Chemical Corp 

Amohem Products, Inc 

American Aliyd Industries 

American Aniline & Extract Co., Inc 

American Aniline Products, Inc 

American Bio-Synthetics Corp 

American Can Co 

American Chemical Corp 

American Cyanamid Co 

American Hoechst Corp 

American Home Products Corp., \l(sreth 
Laboratories, Inc. Div. 

American Oil Co. (Maryland) 

American Oil Co. (Texas) 

American Petrochemical Corp 

American Potash & Chemical Corp 

American Rubber & Chemical Co 

American Synthetic Rubber Corp 

American Tartars Corp 

Ames Laboratories, Ino 

Amoco Chemicals Corp 

Ancon Chemical Corp 

Ansul Chemical Co 

Apex Chemical Co., Inc 

Applied Plastics Co., Ino 

Arapahoe Chemicals, Div. of Syntex Corp 

Ardmore Chemical Co- 

Arenol Chemical Corp 

Argus Chemical Corp 

Arizona Chemical Co 

Arkansas Co., Inc 

Armour Agricultural Chemiceil Co 

Armour Industrial Chemical Co 

Armour Pharmaceutical Co 

Armstrong Cork Co 

Armstrong Paint & Varnish Works, Ino 

Arol Chemical Products Co 



500 Investors Bldg., Minneapolis, MN 55440. 

32 Henry St., Bethel, CT 06801. 

Wth St. and Sheridan Rd., N. Chicago, IL 60664. 

900 W. Maple Rd., Troy, MI 48012. 

126-02 Northern Blvd., Flushing, New York, NY 11368. 

2506 N. 32nd St., Milwaukee, WI 53245. 

1401 Circle Ave., Forest Park, IL 60130. 

P.O. Box 7, Belvidere, IL 61008. 

1339 Chestnut St., Philadelphia, PA 19107. 

1400 E. Washington Ave., Madison, WI 53701. 

P.O. Box 3179, Tuscaloosa, AL 35401. 

16th Fl., Daniel Bldg., Oreenville, SC 29606. 

Trenton Ave. and William St., Philadelphia, PA 19134. 

3440 Fairfield Rd., Baltimore, MD 21061. 

2371 N. 30th St., Milwaukee, WI 53210. 

P.O. Box 326, Ridgefield, NJ 07657. 

P.O. Drawer 61, Hopewell, VA 23860. 

40 Rector St., New York, NY 10006. 

1450 Broadway, New York, NY 10018. 

Columbia Rd. and Park Ave., Morristown, NJ 07960. 

Columbia Rd. and Park Ave., Morristown, NJ 07960. 

P.O. Box 365, Morristown, NJ 07960. 

P.O. Box 6, Solvay, NY 13209. 

P.O. Box 2120, Houston, TX 77001. 

3943 Buffalo Ave., Niagara Falls, NY 14302. 

Chtario and Rorer Sts., Philadelphia, PA 19134. 

Brookside Ave., Ambler, PA 19002. 

Broad and 14th Sts., Carlstadt, NJ 07072. 

Venango and F Sts., Riiladelphia, PA 19134. 

P.O. Box 3063, Paterson, NJ 07509. 

710 W. National Ave., Milwaukee, WI 53204. 

100 Park Ave., New York, NY 10017. 

P.O. Box 9247, Long Beach, CA 90810. 

Wayne, NJ 07470. 

129 Oiidnick St., Coventry, RI 02816. 
P.O. Box 8299, Philadelphia, PA 19101. 

910 S. Michigan Ave., Chicago, IL 60680. 

910 S. Michigan Ave., Chicago, IL 60680. 

3134 California St., N.E., Minneapolis, MN 55418. 

3000 W. 6th St., Los Angeles, CA 90054. 

P.O. Box 1034, Louisville, KY 40201. 

P.O. Box 360, Louisville, KY 40201. 

420 Lexington Ave., New York, NY 10017. 

200 Rock Lane, Milford, CT 06460. 

130 E. Randolph Dr., Chicago, IL 60601. 
1 Stanton St., Marinette, WI 54143. 

1 Stanton St., Marinette, WI 54143. 

200 S. 1st St., Elizabethport, NJ 07206. 

130 Penn St., El Segundo, CA 90246. 

2855 Walnut St., Boulder, CO 80302. 

840 Valley Brook Ave., I^mdhurst, NJ 07071. 

40-33 23d St., Long Island City, NJ 11101. 

633 Court St., Brooklyn, NY 11231. 

Wayne, NJ 07470. 

185 Foundry St., Newark, NJ 07105. 

P.O. Box 1685, Atlanta, CA 30301. 

401 N. Wabash Ave., Chicago, IL 60609. 

P.O. Box 511, Kankakee, IL 60901. 

Liberty and Charlotte Sts., Lancaster, PA 17604. 

1330 S. Kilboum Ave., Chicago, IL 60623. 

371 Wayne St., Jersey City, NJ 07302. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. —Synthetic organic chemicals: Directory of manufacturers , i566--Continued 



201 



of con^jany 



Office address 



Ashland Oil & Refining Co 

Catalln Corp. Div 

Astra. Hiarmaceutioal Products, Ino 

Atco Chemical-Industrial Products, Inc., 

Fine Chemioals Div. 

Atlantic Chemical Corp 

Atlantic Richfield Co. : 

ARCO Chemical Co. Div -- 

Richfield Div 

Atlantic Tablng & Rubber Co 

Atlas Chemical Industries, Ino 

Atlas Processing Co 

Augusta Chemical Co 

Avisun Corp 

Aztec Chemicals, Inc 

Badische Products Corp 

Baird Chemical Industries, Ino 

Baker Castor Oil Co 

J. T. Baker Chemical Co 

Taylor Div 

Baldwin-Montrose Chemical Co., Inc., 

Montrose Chemical Div. 

Baltimore Paint & Chemical Corp 

J. H. Baxter & Co 

Baxter Laboratories, Ino 

Beech-Nut Life Savers, Ino 

Belding Chemical Industries 

Belle Chemical Co., Ino 

Bendix Corp., Marshall-Eclipse Wv 

Bennett's 

Benzenoid Organios, Ino 

Bemcolors-Poughkeepsie, Inc 

Best Fertilizers Co 

Blackman-Uhler Chemical Co 

Blue Arrow, Inc 

Borden Co., Borden Chemical Co. Div 

Borg-Wamer Corp., Marbon Chemical Div 

Walter N. Boysen Co 

Branohf lower Co 

Brand Plastics Co 

Bristol-Meyers Co., Bristol Laboratories Div- 

Brooklyn Color Works, Inc 

M. A. Bruder & Sons, Ino 

Bryant Chemical Corp 

Buckeye Cellulose Corp 

Buokman Laboratories, Ino 

Budd Co., Polyohem Div 

Burdick & Jackson Laboratories, Ino 

Burkart-Schier Chemical Co 

Burroughs-Welloome & Co. (U.S.A.), Ino 



Samuel Cabot, Ino — — 

Cadet Chemical Corp — - — 

Calcasieu Chemioal Corp ~ 

Callery Chemioal Co 

Carborundum Co., Coated Abrasives Div- 

Cargill, Ino 

Carlisle Chemicals Works, Inc 

Advance Div 

Carpenter-Morton Co 

Carufl Chemioal Co., Inc 

Celanese Corp. of America: 

Celanese Chemical Co. Div 

Celanese Coatings Co 

Celanese Plastics Co 

Fibers Co. Div 

Charlotte ChKnioal Laboratories 



Ch&fi^ Chemical Corp- 



1401 Winchester Ave., Ashland, KY 41101. 
1 Park Ave., New York, NY 10016. 
7-1/2 Neponset St., Worcester, MA 01606. 
93 Main St., Franklin, NJ 07416. 

P.O. Box 216, Nutley, NJ 07110. 

260 S. Broad St., Philadelphia, PA 19101. 

&i5 South Mariposa, Los Angeles, CA 90005. 

Mill St., Cranston, RI 02905. 

Wilmington, DE 19899. 

P.O. Box 1786, 3546 Midway St., Shreveport, LA 71102. 

P.O. Box 660, Augusta, GA 30903. 

1608 Walnut St., Philadelphia, PA 19103. 

P.O. Box 756, KLyrla, OH 44035. 

Foot of Central Ave., Kearny, NJ 07032. 

185 Madison Ave., New York, NY 10016. 

40 Avenue A, Bayonne, NJ 07002. 

222 Red School Lane, Fhilllpsburg, NJ 08865. 

222 Red School Lane, Riillipsburg, NJ 08865. 

100 Lister Ave., Newark, NJ 07105. 

2325 Hollins Ferry Rd., Baltimore, MD 21230. 

120 Ktontgomery St., San Francisco, CA 94104. 

6301 N. Uncoln Ave., Morton (Jrove, IL 60053. 

Church St., Canajoharie, NY 13317. 

1407 Broadway, New York, NY 10018. 

P.O. Box 848, Lowell, NC 28089. 

P.O. Box 238, Troy, NY 12180. 

65 W. 1st S., Salt Lake City, UT 84110. 

P.O. Box 156, Bellingham, MA 02019. 

P.O. Box 29, 77 N. Water St., Poughkeepsie, MY 12602. 

P.O. Box 198, Uthrop, CA 95330. 

P.O. Box 5627, Spartanburg, SC 29301. 

5050 mgewood Ct., Jacksonville, FL 32203. 

350 Madison Ave., New York, NY 10017. 

P.O. Box 68, Washington, WV 26181. 

1001 42d St., Oakland, CA 94608. 

4501 Shilshole Ave., NW., Seattle, WA 98101. 

130 E. Randolph Dr., Chicago, IL 60601. 

P.O. Box 657, Syracuse, NY 13201. 

90 Linden Blvd., Hicksvllle, NY 11801. 

52d St. and (S-ays Ave., Philadelphia, PA 191A3. 

6 North St., N. Oilncy, MA 02171. 

2899 Jackson Ave., HBmphlB, TN 38108. 

1256 N. McLean Blvd., Memphis, TN 38108. 

70 S. Chapel St., Newark, DE 19711. 

1953 S. Harvey St., Muskegon, MI 49442. 

1228 Chestnut St., Chattanooga, TN 37402. 

1 Scarsdale Rd., Tuokahoe, NY 10707. 



246 Summer St., Boston, MA 02210. 

2153 Lockport-Olcott Rd., Burt, NY U028. 

P.O. Box 1522, Lake Charles, LA 70601. 

Callery, PA 16024. 

P.O. Box 477, Niagara Falls, NY U302. 

Room 2008, 3 Penn Center Plaza, Fhlladelphla, PA 19102. 

west St., Reading, OH 45215. 

500 Jersey Ave., New Brunswick, NJ 08903. 

376 W. 3d St., Everett, MA 02149. 

1375 8th St., LaSalle, IL 6U01. 

522 5th Ave., New York, NY 10036. 

1481 S. 11th St., Louisville, KY 40208. 

550 Broad St., Newark, NJ 07102. 

P.O. Box 1414, Charlotte, NC 28201. 

P.O. Box 948, 5046 Old Plnevllle M., Charlotte, 

NC 28201. 
3527 .Small man St., Pittsburgh, PA 15201. 



202 SYNTHETIC ORGANIC CHEMICALS, 1966 

TABLE 22. --Synthetic organic chemicals: Directory of manufacturers , i 966- -Continued 



of company 



Office address 



Chattem Drug & Ghemlcal Co., Qiattem 

Chemicals Div. 

Chemagro Corp 

Chembond Corp 

Ghemetron Corp. : 

Chemetron Chemicals Div., Organic Chemical 
Dept. 

National Cylinder Gas Div 

Ghem-Fleur, Ino 

Chemical Formulators, Inc 

Chemical Insecticide Corp 

Chemical Products Corp 

Chemical Services of Baltimore, Inc 

Chemioo, Inc 

Chemlek Laboratories, Ino 

Chevron Chemical Co. : 

Additives Div 

Ortho Div 

Chllds Pulp Colors, Inc 

Chipman Chemical Co., Inc 

Ciba Chemical & Dye Co 

Ciba Corp. : 

Ciba Hiarmaoeutical Co. Div 

Ciba Products Co 

Cities Service Oil Co 

Clark Oil & Refining Corp 

W. A. Cleary Corp 

Clintwood Chemical Co 

Clover Chemical Co 

Cockerille Chemicals, Inc 

Colab Resin Corp 

Colgate- Pal unlive Co 

Collier Carbon & Chemical Corp 

Colloids, Inc 

Columbia Organic Chemicals Co., Inc 

Columbian Carbon Co 

Chemicals Div 

Columbian Nitrogen Corp 

Commercial Products Co., Ino 

Commercial Solvents Corp 

Commonwealth Oil Refining Co., Ino 

Conchemoo, Inc., H. B. Davis Co. Div 

Concord Chemical Co., Inc 

Conestoga Chemical Corp 

Consolidated Papers, Inc 

Continental Chemical Co 

Continental Oil Co 

Cook Paint & Varnish Co 

Cooperative Farm Chemicals Association 

Coopers Creek Chemical Corp 

Copolymer Rubber & Chemical Corp 

Com Products Co 

Cosden Oil & Chemical Co 

Cowles Chemical Co 

Benzol Products Div 

Crest Chemical Corp 

Crompton & Knowles Corp., Chemicals Group, 

Althouse & Bates Div. 

Crosby Chemicals, Inc 

Crown Central Petroleum Corp 

Crown Chemical Corp 

Crown Zellerbaoh Corp., Chemioal Products Div 

Culver Chemical Co 

Cumberland Chemioal Corp., Subsidiary of 

Reduction Co., Ino. 

Cutter Laboratories, Ino 

Cjrolamate Corp. of America 



1715 W. 38th St., Chattanooga, TN 37409. 

P.O. Box 4913, Station "F", Kansas City, MO 64120. 
P.O. Box 270, Springfield, OR 97477. 

201 E. 42d St., New York, NY 10017. 

840 N. Michigan Ave., Chicago, IL 60611. 

200 Palaski St., Newark, NJ 07105. 

P.O. Box 26, Nitro, WV 25143. 

20 Whitman Ave., Metuchen, NJ 08840. 

P.O. Box 449, Cartersville, GA 30120. 

Howard and West Sts., Baltimore, MD 21230. 

2508 E. Bailey Rd., Cuyahoga Falls, OH 44221. 

4040 W. 123d St., Alsip, IL 60658. 

P.O. Box 3227, Greensboro, NC 27402. 

200 Bush St., San Francisco, CA 94120. 

940 Hensley, Richmond, CA 94801. 

43 Summit St., Brooklyn, NY 11231. 

P.O. Box 2009, 297 Jersey Ave., New Brunswick, NJ 

08903. 
Route 208, Fair Lawn, NJ 07410. 

556 Morris Ave., Summit, NJ 07901. 

556 Morris Ave., Summit, NJ 07901. 

P.O. Box 300, Tulsa, OK 74101. 

131st St. and Kedzle Ave., Blue Island, IL 60406. 

P.O. Box 749, New Brunswick, NJ 08903. 

1 N. LaSalle St., Chicago, IL 60602. 

P.O. Box 146, Eighty Four, PA 15330. 

Greenwood, VA 22%3. 

Main St., Tewksbury, MA 01876. 

300 Park Ave., New York, NY 10022. 

714 W. Olynpic Blvd., Los Angeles, CA 90015. 

394 Frelinghuysen Ave., Newark, NJ 07114. 

912 Drake St., Columbia, SC 29205. 

380 Madison Ave., New York, NY 10017. 

P.O. Box 1522, Lake Charles, LA 70601. 

P.O. Box 1483, Augusta, GA 30903. 

117 Ethel Ave., Hawthorne, NJ 07641. 

260 Madison Ave., New York, NY 10016. 

P.O. Box ^23, San Juan, PR 00905. 

Bayard and Severn Sts., Baltimore, MD 21230. 

205 S. 2d St., Camden, NJ 08103. 

Wilmington Industrial Park, Wilmington, DE 19801. 

Wisconsin Rapids, WI 54494. 

270 Clifton Blvd., Clifton, NJ 07015. 

9 Rockefeller Plaza, New York, NY 10020. 

P.O. Box 389, N. Kansas City, MO 64L41. 

P.O. Box 308, Lawrence, KS 66044. 

River Rd., W. Conshohocken, PA 19428. 

P.O. Box 2591, Baton Rouge, LA 70821. 

717 5th Ave., New York, NY 10022. 

P.O. Box 1311, Big Spring, TX 70720. 

12000 Shaker Blvd., Cleveland, OH 44120. 

237 South St., Newark, NJ 0711A. 

225 Branet St., Newark, NJ 07114. 

500 Pear St., Reading, PA 19603. 

P.O. Drawer 32, DeRldder, LA 70634. 

P.O. Box 1168, Baltimore, MD 21203. 

12 Dudley St., Providence, RI 02901. 

Camas, WA 98607. 

1502 N. 25th St., Melrose Park, IL 60160. 

150 E. 42d St., New York, NY 10017. 

4th and Parker Sts., Berkeley, CA 94710. 
100 Lister Ave., Newark, NJ 07105. 



DIRECTORY OF MANUFACTURERS 203 

TABLE 22. —Synthetic organic chemicals.- Directory of manufacturers , i 566 --Continued 



Name of company 



Office address 



Dan River Mills, Ino 

Davles-Youiig Soap Co 

Josepli Davis Plastics Co 

Dawe's Laboratories, Inc 

Degen Oil & Chemical Co 

DePaul Chemical Co., Inc 

DeSoto Chemical Coatings, Inc 

Detrex Chemical Industries, Inc 

Dexter Chemical Corp 

Diamond Alkali Co 

Western Div 

Diversey Corp 

DLxie Chemical Co 

Dixie Pine Products Co., Inc 

Dominion Products, Ino 

Dover Chemical Co 

Dow Badische Co 

Dow Chemical Co 

Dow Corning Corp 

Drew Chemical Corp 

Frank W. Dunne Co 

E. I. duftjnt de Nemours & Co., Ino 

Eye Specialties, Inc 

J. S. & W. R. EaMns, Inc 

Intern Color & Chemical Co 

Eastman Kodak Co 

Tennessee E^tman Co. Div 

Texas Eastman Co. Div 

East Shore Chemical Co., Ino 

Blcan Laboratories 

EL Paso Products Co 

Bnery Industries, Inc 

Western Div 

Bukay Chemical Co 

Bido Laboratories, Inc 

Bijay Chemical Co 

:^oxylite Corp 

Escambia Chemical Corp 

Ethyl Corp 

Ethyl-Dow Chemical Co 

Evans Chemetios, Ino 

PMC Corp. : 

JUnerican Viscose Div 

Inorganic Chemicals Div 

Niagara Chemical Div 

Organic Chemloais Div 

Fabricolor Manufacturing Corp 

Falrmount Chemical Co., Inc 

Farac Oil & Chemical Co., Div of Handschy 

Qiemical Co. 

Far- Best Corp., 0. L. King Div 

Fanners Chemical Association, Inc 

Farmer's Chemical Co 

Famow, Ino 

Federal Color Laboratories 

Fel-Tex, Ino 

Felton Chemical Co., Inc 

Ferro Corp., Ferro Chemical Div- 
Fibreboard Oorp 
Filtered Rosin Products Co- 
Fine Organlcs, Inc 
Firestone Tire & Rubber Co. 

Firestone Plastics Co 

Firestone Rubber & Latex Products Co. Div. 

Firestone ^mthetic Rubber & Latex Co. DlV' 
Flstier Melamine Corp' 



Danville, VA 24540. 

705 Albany St., Dayton, OH 45401. 

450 Schuyler Ave., Kearny, NJ 07032. 

4800 S. Richmond St., Chicago, IL 60632. 

200 Kellogg St., Jersey City, NJ 07305. 

4^-27 Purvis St., Long Island City, NY 11101. 

1700 S. Mt. Prospect Ave., Des Plaines, IL 60018. 

14331 Woodrow Wilson, Detroit, MI 48232. 

845 fllgewater Rd., Bronx, MY 10474. 

300 Union Commerce Bldg., Cleveland, OH 44114. 

300 Union Commerce Bldg., Cleveland, OH 4^114. 

212 W. Monroe St., Chicago, IL 60606. 

3635 W. Dallas Ave., Houston, TX 77019. 

P.O. Box 470, Hattiesburg, MS 39401. 

882 3d Ave., Brooklyn, NY 11232. 

15th and Davis Sts., Dover, OH 44622. 

Williamsburg, VA 23185. 

Midland, MI 48640. 

P.O. Box 582, Midland, MI 48640. 

416 Division St., Boonton, NJ 07005. 

1007 41st St., Oakland, CA 94608. 

DuPont Bldg., Wilmington, DE 19898. 

26 Journal Sq., Jersey City, NJ 07306. 

55 Berry St., Brooklyn, NY 11211. 

35 Livingston St., Providence, RI 02904. 

343 State St., Rochester, NY 14650. 

P.O. Box 511, Kingsport, TN 37662. 

P.O. Box 2068, Longview, TX 75601. 

1180 Michigan Ave., Muskegon, MI 49440. 

18 Marshall, S. Norwalk, CT 06856. 

P.O. Box 3986, Odessa, TX 79760. 

4300 Carew Tower, Cincinnati, OH 45202. 

8733 S. Dice Rd., Santa Fe Springs, CA 90670. 

319 2d St., Elizabeth, NJ 07206. 

1000 Stewart Ave., Garden City, NY 11530. 

60 W. 49th St., New York, NY 10020. 

1428 N. T^rler Ave., S. EL Monte, CA 91733. 

P.O. Box 467, Pensacola, FL 32502. 

100 Park Ave., New York, NY 10017. 

Midland, MI 48640. 

250 E. 43d St., New York, NY 10017. 



1617 John F. Kennedy Blvd., Hiiladelphia, PA 19103. 
Sawyer Ave. and River Rd., Tonawanda, NY 14207, and 

633 3d Ave., New York, NY 10017. 
100 Niagara St., Middleport, NY 14105. 
1701 Patapsco Dr., Baltimore, MD 21226, and P.O. Box 

547, Nitro, WV 25U3. 
24-1/2 Van Houten St., Paterson, NJ 07505. 
117 Blanchard St., Newark, NJ 07105. 
147th St. and Indiana Ave., CJiicago, IL 60627. 

640 Oilman St., Berkeley, CA 94710. 

P.O. Box 67, TJmer, TN 37392. 

P.O. Box 591, Kalamazoo, MI 49005. 

77 Jacobus Ave., S. Kearny, NJ 07032. 

4526 Chickering Ave., Cincinnati, OH 45232. 

P.O. Box 68, Fremont, NB 68025. 

599 Johnson Ave., Brooklyn, NY 11237. 

P.O. Box 3A9, Bedford, OH 440U. 

P.O. Box 431A, Oakland, CA 94623. 

P.O. Box 349, Baxley, GA 31513. 

205 Main St., Lodi, NJ 0764-;. 



P.O. Box 699, Pottatown, PA 19464. 
P.O. Box 2290, Fall River, MA 02722. 
381 W. Wilbeth Rd., Akron, OH 44301. 
90 Park Ave., New York, NY 10016. 



SYNTHETIC ORGANIC CHEMICALS, 1966 
TABLE 22. -Synthetic organic chemicals: Directory of manufacturers , 2 966 --Continued 

Office address 



Fleming Laboratories, Inc 

Florasynth, Ino 

Foote Mineral Co 

ForeniDst Chemical Products Co 

Formica Corp 

Foster Grant Co., Ino 

Foster-Heaton Co 

France, Can^ibell & Darling, Inc 

Franklin Chemical Co 

Freeman Chemioal Corp 

Frisch & Co., Inc 

Fritzsche Bros., Inc 

H. B. Fuller Co 

W. P. Fuller Paint Co 

Gemma Chemioal Corp 

Gane's Chemical Iforks, Inc 

Geigy Chemioal Corp 

General Aniline & Film Corp., Eyestuff & 

Chemical Div. 
General Electric Co. : 

Chemioal Materials Dept 

Insulating Materials Dept 

Silicone Products Dept— 

General Foods Corp., Maxwell House Div 

General Latex & Chemical Corp 

General Mills, Ino 

Chemical Div 

General Plastics Manufacturing Co 

General Tire & Rubber Co., Chemioal Div 

P. D. George Co 

Georgia-Pacific Corp. : 

Coos Bay Div 

Puget Sound Div 

Gillette Chemical Co 

Oilman Paint & Varnish Co 

Givaudan Corp 

Glasflex, Ino 

Glidden Co 

Durkee Famous Foods Div 

Glyco Chemicals, Inc 

B. F. Goodrich Co., B. F. Goodrich Chemioal 
Co. Div. 

Goodrich-Gulf Chemicals, Ino 

Goodyear Tire & Rubber Co 

Gordon Chemioals Co., Inc 

. R. Grace & Co. : 

Agricultural Products Div 

Dewey & Alny Chemioal Div 

Dubois Chemioals Div 

HaiUJShire Chemical Div 

Hatoo Chemical Div 

Maroo Chemical Div 

Vestal Laboratories Div 

Grain Processing Corp 

Great American Plastics Co 

Great Lakes Chemioal Corp 

Great Western Sugar Co 

A. Gross Sc Co., Inc 

Grow Chemioal Corp., Harris Paint Co. Div — 

Guardsman Chemioal Coatings, Ino 

Gulf Oil Corp 

Chemicals Dept 

Perkins Glue Branch 

Guth Chemical Co 

H & N Chemioal Co 

Haag Laboratories, Inc 

Halby Rroduots Co., Inc 



P.O. Box 10372, Charlotte, NC 28201. 

900 Van Nest Ave., Bronx, NY 10^62. 

Route 100, Bcton, PA 193A1. 

P.O. Box 599, Oakland, CA 94604. 

Wayne, NJ 07470. 

289 N. Main St., Leominster, MA 01453. 

E. 5th St., Paterson, NJ 07524. 
N. Michigan Ave., Kenllworth, NJ 07033. 
2020 Bruok St., Columbus, OH 43207. 
222 E. Main St., Port Washington, WI 53074. 

E. 11th St., Paterson, NJ 07524. 
76 9th Ave., New York, NY 10011. 
1150 Bistio St., St. Paul, MN 55108. 
450 E. Grand Ave., S. San Francisco, CA 94080. 

90 Park Ave., New York, NY 10016. 
535 5th Ave., New York, NY 10017. 
Saw Mill River Rd., Ardsley, NY 10502. 
P.O. Box 2164, Greenville, SC 29602, and P.O. Box 12, 
Unden, NJ 07036. 

1 Plastics Ave., Coshocton, OH 43812, and 1 Plastics 

Ave., Plttsfield, MA 01203. 
1 River Hd., Schenectady, NY 12305. 
Waterford, NY 12188. 
1125 Hudson St., Hoboken, NJ 07030. 
666 Main St., Cambridge, MA 02139. 
S. Kensington Rd., Kankakee, IL 60901. 
Qaimby St., Ossining, NY 10562. 
3481 S. 35th St., Taooma, WA 98409. 
1708 Biglewood Ave., Akron, OH 44309. 
5200 N. 2d St., St. Louis, MO 63L47. 

P.O. Box 869, Coos Bay, OR 97420. 

P.O. Box 1236, Bellingham, WA 98225. 

P.O. Box 362, N. Chicago, IL 60064. 

W. 8th and Fine Sts., Chattanooga, TN 37401. 

125 Delawanna Ave., Clifton, NJ 07014. 

Stirling, NJ 07980. 

900 Union Commerce Bldg., Cleveland, OH 44115. 

2333 Logan Blvd., Chicago, IL 60647. 

417 5th Ave., New York, NY 10016. 

3135 Euclid Ave., Cleveland, OH 44137. 



1717 E. 9th St. 
lUA E. Market 
88 Webster St., 



Cleveland, OH 44114. 
5t., Akron, OH 44316. 
Worcester, MA 01603. 



P.O. Box 277, 147 Jefferson Ave., Meii?)his, TN 38101. 

62 Whittemore Ave., Cambridge, MA 02W0. 

634 Broadway, Cincinnati, OH 45202. 

Poiseon Ave., Nashua, NH 03060. 

629 AniJoy St., Fords, NJ 08863. 

1711 W. Elizabeth Ave., Linden, NJ 07036. 

4963 Manchester Ave., St. Louis, MO 63110. 

1600 Oregon St., Muscatine, LA 52761. 

85 Water St., Fitohburg, MA 21420. 

P.O. Box 2200, west Lafayette, IN 47906. 

P.O. Box 5308, Terminal Annex, Denver, CO 80217. 

295 Madison Ave., New York, NY 10017. 

1010-26 N. 19th St., Tan?)a,FL. 33601. 

1350 Steele Ave. SW., Grand Rapids, MI 49502. 

P.O. Drawer 2100, Houston, TX 77001. 

Dwight Bldg., Kansas City, MO 64105. 

632 Cannon Ave., Lansdale, PA 19446. 

332 S. Center St., Hillside, IL 60162. 

90 Maltese Dr., Totowa, NJ 07512. 
lAOlO S. Seeley, Blue Island, IL 60406. 
P.O. Box 366, Wilmington, DE 19899. 



DIRECTORY OF MANUFACTURERS 205 

TABLE 22. --Synthetic organic chemicals; Directory of manufacturers , i 966— Continued 



Name of company 



C. P. Hall Co. of Illinois 

Hanfxlen Color & Chemical Co 

Hanna Paint Manufacturing Co., Ino 

Harshaw Chemical Co., Div. of Kewanee Oil Co- 

Hartman-Leddon Co 

Hart Products Corp 

Haveg Industries, Inc., Resin & Con^jound Div- 

Hawkeye Chemical Co 

Hercules, Inc 

Iiqjerial Color & Chemical Dept 

Heresite & Chemical Co 

Hess Oil & Chemical Corp 

Heterochemical Corp 

Hexagon Laboratories, Ino 

Hodag Chemical Corp 

Hoffmann- Laltoche, Ino 

Hoffman-Taff, Ino 

Holland-Suoo Color Co 

Hooker Chemical Corp 

Durez Plastics Div 

Ruoo ttlv 

E. F. Houghton & Co 

Houston Chemical Corp 

Charles L. Huisklng & Co., Inc., Clintbrook 

Chemical Co. Div. 

Huii5)hrey Chemical Co ; 

Philip A. Hunt Chemical Corp., Wayland 

Chemical Div. 

Huntington Laboratories, Inc 

Husky Briquetting, Inc 

fftrason, Westcott & IXmning, Inc 

Itysol Corp 

I.C.I. (Qrganics), Inc 

IRC, Ino 

Inperial, Inc 

Industrial Bloohemioals 

Industrial Eyestuff Co 

Inland Steel Container Co 

Interohemloal Corp. : 

Color & Chemicals Div 

Finishes Div 

Organic Chemicals Dept 

International Flavors & Frangrances, Inc 

International Latex & Chemical Corp 

Paisley Products Div 

International Minerals & Chemical Corp 

Inter-Pacific Resins, Inc 

Interplastio Corp., Commercial Resins Div 

Ironsides Resins, Inc 

Isocyanate Products, Inc 

Jefferson Chemical Co., Inc 

Jennlson-ffright Corp 

Andrew Jergens Co 

Jersey State Chemical Co 

Jewel Paint & Varnish Co 

S. C. Johnson & Son, Inc 

Jones-Blair Paint Co 

Jordan Chemical Co 

Kaiser Aluminum & Chemical Corp.: 

Kaiser Agricultural Chemicals Div 

Kaiser Chemical Div 

Kali Manufacturing Co 

Kay-Fries Chemicals, Inc 

Keil Chemical Co 

Kelly-Jfoore Paint Co ^ 

Kelly-Piokerlng Chemical Corp 

Kendall Refining Co 



7300 S. Central Ave., Chicago, IL 60638. 

5 Albany St., Springfield, MA 01101. 

P.O. Box Wr, Columbus, OH «216. 

1945 E. 97th St., Cleveland, OH 44106. 

60th St. and Woodland Ave., Philadelphia, PA 191A3. 

1440 Broadway, New York, NY 10018. 

900 Greenba'-Ji Rd., Wilmington, DE 19808. 

P.O. Box 899, Clinton, LA 52733. 

Hercules Tower, 910 Market St., Wilmington, DE 19899. 

P.O. Box 231, Glens Falls, NY 12803. 

822 S. 14th St., Manitowoc, WI 54220. 

280 Park Ave., New York, NY 10017. 

Ill E. Hawthorne Ave., Valley Stream, NY 11582. 

3536 Peartree Ave., Bronx, NY 10469. 

7247 N. Central Park Ave., Skokie, IL 60076. 

324-424 Klngsland Rd., Nutley, NJ 07110. 

P.O. Box 1246 SSS, Springfield, MO 65805. 

P.O. Box 2166, Huntington, WV 25722. 

Long Rd., Grand Island, NY 14072. 

Walok Rd., N. Tonawanda, NY 14121. 

New South Rd., Hioksville, L.I., NY 11802. 

303 W. Lehigh Ave., Philadelphia, PA 19133. 

1 Gateway Center, Httsburgh, PA 15222. 

417 5th Ave., New York, NY 10016. 

Devlne St., North Haven, CT 06473. 
P.O. Box 63, Uncoln, HI 02865. 

P.O. Box 710, Huntington, IN 46750. 

P.O. Box 380, Cody, WY 82414. 

Charles and Chase Sts., Baltimore, MD 21201. 

1100 Seneca Ave., Olean, NY U760. 

55 Canal St., Providence, RI 02901. 

401 N. Broad St., Riiladelphia, PA 19108. 

W. 6th and Grass Sts., Shenandoah, lA 51601. 

U.S. Highway 1, Edison, NJ 08817. 

P.O. Box 4249, E. Providence, RI 02914. 

6532 S. Menard Ave., Chicago, IL 60638. 

150 Wagaraw Rd., Hawthorne, NJ 07506. 

1255 Broad St., Clifton, NJ 07015. 

Berry Ave. and 13th St., Carlstadt. NJ 07072. 

521 W. 57th St., New York, NY 10019. 

P.O. Drawer K, Playtex Park, Dover, DE 19901. 

1770 Canalport Ave., Chicago, IL 60616. 

5401 Old Orchard Rd., Skokie, IL 60078. 

P.O. Box 445, 1602 N. 18th St., Sweet Home, OR 97386. 

2015 N.E. Broadway St., Minneapolis, MN 55413. 

270 W. Mound St., P.O. Box 1999, Columbus, OH 43216. 

900 Wilmington Rd., New Castle, DE 19720. 

P.O. Box 53300, Houston, TX 77052. 

P.O. Box 691, Toledo, OH 43601. 

2535 Spring Grove Ave., Cincinnati, OH 45214. 

59 Lee Ave., Haledon, NJ 07508. 

345 N. Western Ave., Chicago, IL 60612. 

1525 Howe St., Racine, WI 53403. 

6969 Denton Dr., Dallas, TX 75235. 

Barclay Bldg., 1 Belmont Ave., Bala Qynwyd, PA 19004. 



P.O. Box 246, Savannah, OA 31402. 
P.O. Box 337, Gramercy, LA 70052. 
427 E. Itoyer St., Philadelphia, PA 19125. 
360 Lexington Ave., New York, NY 10017. 
3000 Sheffield Ave., Hammond, IN 46320. 
1015 Commercial St., San Carlos, CA 94070. 
956 Bransten Rd., San Carlos, CA 94070. 
77 N. Kendall Ave., Bradford, PA 16701. 



206 SYNTHETIC ORGANIC CHEMICALS. 1966 

TABLE 22. -Synthetic organic chemicals: Directory of manufacturers , i 566 --Continued 



Name of company 



MID 
MRA 
JMB 
MCH 
yrm 
UPP 
ULS 



Keimeoott Copper Corp. : 

Chlno Mines Div 

Utah Copper Div 

Kenrioh Petrochemioals, Ino 

Ketona Chemloal Corp 

Keysor Chemical Co 

Keystone Chemurglo Corp 

Keystone Color Works, Inc 

Knapp Products, Inc 

Knoedler Chemical Co 

Kohler-McLister Paint Co 

H. Kohnstaram & Co., Inc 

Koppers Co., Inc., Tar & Chemical 

Koppers Pittsburgh Co 

Kyanize Paints, Ino 



Lakeside Laboratories, Div, of Colgate- 
Palmolive Co. 

Lakeway Chemical Co 

LaMotte Chemloal Products Co 

Lancaster Chemical Corp., Gordon Chendeals 
Co. Div. 

Lasoo Industries, Inc 

Laurel Products Corp 

Lawter Chemicals, Inc., Krumbhaar Resin Div 

Leatex Chemical Co 

Lebanon Chemical Corp 

Leffingwell Chemical Co 

Lehn & Fink Products Corp., Beacon Div 

B. L. Lemke & Co., Inc 

Leonard Refineries, Ino 

Lever Brothers Co 

C. Lever Co., Inc 

Fred'k H. Levey Co., Ino 

Lignin Products Co 

ELi Lilly & Co 

Lubrlzol Corp 

George Lueders & Co., Inc 



of Pickands 



M & T Chemicals, Inc 

Magruder Color Co., Ino 

Maher Color & Chemical Co 

Malllnckrodt Chemical Works- 
Manganese Chemical Co., Div. 
Mather & Co. 

Marathon Oil Co., Texas Refining Div 

Marblette Corp 

Marden-Wild Corp 

Marlowe-Van Loan Corp 

Martin-Marietta Corp. : 

Ridgway Color & Chemical Div 

Southern Eyestuff Co. Div 

Max Marx Color & Chemloal Co 

Masonite Corp., Alpine Chemical Div 

Mathe Chemical Co 

Maumee Chemical Co 

Otto B. May, Ino 

MoCloskey Varnish Co 

McLaughlin Gormley King Co 

Medical Chemicals Corp 

Merck & Co., Inc 

Meriohem Co 

Metalead Products Corp 

Metro-Atlantic, Ino 

J. Meyer & Sons, Ino 

Michigan Chemical Corp 

Midland Industrial Finishes Co 

Midwest Plastic Products Co 

Miles Laboratories, Inc., CbemioalE Dlv- 



Hurley, MM 88043. 

P.O. Box 11299, Salt Lake City, UT 84111. 

Foot of E. 22d St., Bayonne, NJ 07002. 

P.O. Box 6565, Tarrant Branch, Birmingham, AL 35217. 

26000 Bouquet Canyon Rd., Saugus, CA 91350. 

R.D. 2, Bethlehem, PA 18017. 

151 W. Gay Ave., York, PA 17403. 

180 Hamilton Ave., Lodi, NJ 07644. 

651 High St., Lancaster, PA 17604. 

P.O. Box 546, 1201 Osage St., Denver, CO 80201. 

161 Avenue of the Americas, New York, NY 10013. 

Koppers Bldg., 430 7th Ave., Pittsburgh, PA 15219. 

Koppers Bldg., 430 7th Ave., Pittsburgh, PA 15219. 

2d and Boston Sts., Everett, MA 02149. 

1707 E. North Ave., Milwaukee, WI 53201. 

5025 Evanston Ave., Muskegon, MI 49443. 

Chestertown, MD 21620. 

500 A St., Wilmington, DE 19801. 

1561 Qiapin Rd., Montebello, CA 90640. 

2600 Tioga St., Hiiladelphia, PA 19134. 

3550 Touhy Ave., Chicago, IL 60645. 

2722 N. Hancock St., Hiiladelphia, PA 19133. 

P.O. Box 180, Lebanon, PA 17CK2. 

P.O. Box 185, Brea, CA 92621. 

33 Riohdale Ave., Cambridge, MA 02140. 

199 Main St., Lodi, NJ 07644. 

E. Superior St., Alma, MI 48801. 

390 Park Ave., New York, NY 10022. 

Howard and Huntington Sts., Philadelphia, PA 19133. 

380 Madison Ave., New York, NY 10017. 

P.O. Box 960, Erie, PA 16512. 

740 S. Alabama St., Indianapolis, IN 46206. 

29400 Lakeland Blvd., Wiokliffe, OH 44117. 

427 Washington St., New York, NY 10013. 

Woodbridge Rd. and Randolph Ave., Rahway, NJ 07065. 

1 Virginia St., Newark, NJ 071U. 

1700 N. ELston Ave., Chicago, IL 60622. 

3600 N. 2nd St., St. Louis, MO 63147. 

2000 Union Commerce Bldg., Cleveland, OH 44115. 

P.O. Box 1191, Texas City, TX 77590. 

37-31 30th St., Long Island City, NY 11101. 

500 Columbia St., Somerville, MA 02143. 

P.O. Box 1851, 1511 Joshua Circle, High Point, NO 27261. 

75 Front St., Ridgway, PA 15853. 

P.O. Box 10098, Charlotte, NC 28201. 

192 Colt St., Irvington, NJ 07111. 

P.O. Box 2392, Gulfport, MS 39503. 

169 Millbank St., Lodi, NJ 07644. 

1310 Expressway Dr., Toledo, OH 43608. 

52 Amsterdam St., Newark, NJ 07105. 

7600 State Rd., Billadelphia, PA 19136. 

1715 S.E. 5th St., Minneapolis, MN 554U. 

4541 W. CSrand Ave., Chicago, IL 60639. 

126 E. Lincoln Ave., Rahway, NJ 07065. 

19U Haden Rd., Houston, TX 77015. 

P.O. Box 11005, 2901 Park Blvd., Palo Alto, CA 94306. 

2027 Smith St., Centerdale, RI 02911. 

4321 N. 4th St., Riiladelphia, PA 19140. 

2 N. Riverside Plaza, Chicago, IL 60606. 

P.O. Box 620, E. Water, St., Waukegan, IL 60086. 

3251 Chicago Rd., Stager, IL 64075. 

l^tle and McNaughton Ste., Elkhart, IN 4651A. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. --Synthetic organic chemicals: Directory of manufacturers , i 566- -Continued 



Identi- 
fication 
code 



Name of company 



Office address 



Mill master Onyx Corp. : 

Berkeley Chemical Div 

Onyx Chemical Div 

Mineral Oil Refining Co 

Minnesota Mining & Manufacturing Co 

Minnesota Paints, Inc 

Mlranol Chemical Co., Inc 

sissippi Chemical Corp 

Mobay Chemical Co 

Mobil Chemical Co. : 

Industrial Chemical Div 

North Atlantic Div 

Petrochemical Div 

Molded Fiber Glass Body Co., Resin Div 

Jtona Industries, Inc 

Monochem, Inc 

Monsanto Co. : 

Bircham Bend Plant 

Chocolate Bayou Plant 

Gering Plastics Dept 

Organic Chemical Div 

Plastics Div 

Textiles Div 

Western Div 

Montrose Chemical Corp. of California 

Mooney Chemical, Inc 

Benjamin Ktoore & Co. 

Morton Chemical Co 

Motomco, Inc 

N.V.F. Co— - _ 

Nalco Chemical Co 

National Biochemical Co 

National Casein Co 

National Dairy Products Corp. : 

Humko Products Chemical Div 

Sheffield Chemical Co. Div 

National Distillers & Chemical Corp. : 

A-B Qiemical Corp. Div 

National Petro Chemical Corp. Div 

U.S. Industrial Chemicals Co. Div 

National Lead Co 

National Milling & Chemical Co., Inc 

National Plastic Products Co., Inc 

National Polychemicals, Inc 

National Starch & Chemical Corp 

Nease Chemical Co., Inc 

Nepera Chemical Co., Inc 

Neville Chemical Co 

Newport Products Co., Div. of Safeway Stores, 

Inc. 
Nilok Chemicals, Inc 

Nipak, Inc 

Nitrin, Inc — 

A. P. Nonweiler Co 

Nopco Chemical Co., Inc 

Norac Co., Inc 

Norda Essential Oil & Chemical Co., Inc 

Norrls Paint & Varnish Co 

Norse Chemical Corp 

North American Chemical Co 

Northwestern Chemical Co 

Northwest Petrochemical Corp 

Norwich Riarmaoal Co 

Nostrip Chemical Works, Inc 

Novamont Corp 



99 Park Ave., New York, NY 10016. 

Warren and Morris Sts., Jersey City, NJ 07302. 

^01 Park Ave., Dickinson, TX 77539. 

2501 Hudson Rd., St. Paul, MN 55119. 

1101 S. 3d St., Minneapolis, MN 55415. 

277 Coit St., Irvington, NJ 07111. 

P.O. Box 388, Yazoo City, MS 39194. 

Penn Lincoln Parkway, W. Pittsburgh, PA 15205. 

401 E. Main St., Richmond, VA 23208. 

612 South Flower St., Los Angeles, CA 90054. 

P.O. Box 3868, Beaumont, TX 77704. 

4601 Benefit Ave., Ashtabula, OH 44004. 

65 E. 23d St., Paterson, NJ 07524. 

P.O. Box 488, Geismar, LA 70734. 

190 Grochmal Ave., Indian Orchard, MA 01051. 

P.O. Box 711, Alvin, TX 77511. 

200 N. 7th St., Kenilworth, NJ 07033. 

800 N. Lindbergh Blvd., St. Louis, MO 63166. 

730 Worcester St., Springfield, MA 01101; 5100 W. 
Jefferson Ave., Trenton, MI 48183; River Rd., 
Addyston, OH 45001, and P.O. Box 1311, Texas City, 
TX 77591. 

350 5th Ave., New York, NY 10001. 

9229 E. Marginal Way S., Seattle, WA 98108. 

500 S. Virgil Ave., Los Angeles, CA 90005. 

2301 Scranton Rd., Cleveland, OH 44113. 

548 5th Ave., New York, NY 10036. 

110 N. Wacker Dr., Qiicago, IL 60606. 

89 Terminal Ave., Clark, NJ 07066. 

Maryland Ave. and Beech St., Wilmington, DE 19899. 
180 N. Michigan Ave., Chicago, IL 60601. 
3127 W. Lake St., Chicago, IL 60612. 
601 W. 80th St., Chicago, IL 60620. 



99 Park Ave., New York, NY 10016. 

99 Park Ave., New York, NY 10016. 

99 Park Ave., New York, NY 10016. 

Ill Broadway, New York, NY 10006. 

4601 Flat Rock Rd., Philadelphia, PA 19127. 

Odenton, MD 21113. 

51 Eames St., Wilmington, MA 01887. 

750 3d Ave., New York, NY 10017. 

P.O. Box 221, State College, PA 16801. 

Route 17 and Aver ill Ave., Harriman, NY 10926. 

Neville Island P.O., Pittsburgh, PA 15225. 

1501 Mariposa St., San Francisco, CA 94107. 

Mill St. and N. Transit Rd., Lockport, NY 14094. 

301 S. Howard St., Dallas, TX 75221. 

P.O. Box 233, Cordova, IL 61242. 

P.O. Box 1007, Oshkosh, WI 54901. 

60 Park PI., Newark, NJ 07101. 

405 S. Motor Ave., Azusa, CA 91703. 

475 10th Ave., New York, NY 10001. 

1675 Commercial St., N.E., Salem, OR 97303. 

2121 Norse Ave., Cudahy, WI 53110. 

19 S. Canal St., Lawrence, MA 01843. 

120 N. Aurora St., W. Chicago, IL 60185. 

P.O. Box 99, Anacortes, WA 98221. 

17 Eaton Ave., Norwich, NY 13815. 

182 Uberty Ave., Jamaica, NY 11433. 

P.O. Box 189, Kenova, WV 25530. 



208 



SYNTHETIC ORGANIC CHEMICALS, 1966 
■Synthetic organic chemicals: Directory of manufacturers , 2 966 --Continued 



Name of con5>any 



Office address 



Nyanza, Ino 

Hamilton Chemical Div 

Olin Mathieson Chenioal Corp 

Onyx Oils & Resins, Inc 

Orbis Products Corp 

Qrganios, Ino 

Original Bradford Soap Works, Inc 

C. J. Osbom Co 

Ottawa Chemical Co 

Ott Chemical Co 

Owens-Coming Fiberglas Corp 

Oxo Chemicals Co 

P-L Biochemioals, Inc 

Pacific Kesins & Chemical Co 

Pan American Petroleum Corp 

Pantasote Co 

Parke, Davis & Co 

saic Color & Chemical Co 

Patent Chemicals, Ino 

Pearsall Chemical Co 

Peck's Products Co 

Peerless Chemical Co 

Pelron Corp 

S. B. Peniok & Co 

Parsons-Plymouth Div 

Pennsalt Chemicals Corp 

Pennsylvania Industrial Chemical Corp- 

Pennsylvania Refining Co 

Perry & Derrick Co 

Petrochemicals Co., Inc 

Petro-Tex Chemical Corp 

Pfanstiehl Laboratories, Inc 

Pfister Chemical Works 

Chas. Pfizer & Co., Ino 

Pharmachem Corp 

Phelan-Faust Paint Manufacturing Co., 

Phelan's Resins & Flastios Div. 

Phillips Petroleum Co 

Phoenix Oil Co 

Pierce Qrganics, Inc 

Pillsbury Co., Qiemioal Div 

Pilot Chemical Co 

Pioneer Chemical Works, Ino 

Pioneer Plastics Corp., Chemical Div— 

Pitt-Consol Chemical Co 

Pittsburgh Plate Glass Co 

Plastics Bigineering Co 

Plastics Manufacturing Co 

Plumb Chemical Corp 

Polak's Frutal Works 

Polychemioal Laboratories, Ino 

Polymer Corp 

Polymer Industries, Ino 

Poly Resins 

Polyrez Co., Inc 

Polyvinyl Chemicals, Ino 

Pontiac Refining Corp 

Pratt & Lambert, Ino 

Premier Malt Products, Inc 

Premier Petrochemical Co 

Procter & Gamble Co 

Proctor Chemical Co., Ino 

Produotol Chemical Co., Inc 

Products Research & Chemical Corp 

Publicker Industries, Ino 

Puerto Rico Chemical Co., Inc 

Purex Corp., Ltd 



P.O. Box 349, Ashland, MA 01721. 
45 Andrews St., Lowell, MA 01853. 

445 W. 59th St., New York, NY 10019. 
95 Broad St., New York, NY 10004. 
475 10th Ave., New York, NY 10018. 
1724 Greenleaf Ave., Chicago, IL 60628. 
200 Providence St., W. Warwick, HI 02893. 
1301 W. aianoke St., Linden, NJ 07036. 
700 N. Wheeling St., Toledo, OH 43605. 
500 Agard Rd., Muskegon, MI 49945. 
P.O. Box 901, Toledo, OH 43614. 
P.O. Box 127, Ironton, OH 45638. 

1037 W. MoKinley Ave., Milwaukee, WI 53205. 

3400 13th Ave. SW., Seattle, WA 98134. 

P.O. Box 591, Tulsa, OK 74102. 

26 Jefferson St., Passaic, NJ 07056. 

P.O. Box 118, Detroit, MI 48232. 

28-36 Paterson St., Paterson, NJ 07501. 

335 McLean Blvd., Paterson, NJ 07504. 

P.O. Box 108, Hiillipsburg, NJ 08865. 

610 E. Clarence Ave., St. Louis, MO 63147. 

3850 Oakman Blvd., Detroit, MI 48204. 

7847 W. 47th St., I^rons, IL 60534. 

100 Church St., New York, NY 10008. 

100 Church St., New York, NY 10008. 

3 Penn Center, Philadelphia, PA 19102. 

120 State St., Qairton, PA 15025. 

Union Bank Bldg., Butler, PA 16001. 

2510 Highland Ave., Norwood, OH 45212. 

1825 E. Spring St., Long Beach, CA 90806. 

P.O. Box 2584, Houston, TX 77001. 

1219 CtLen Rook Ave., Waukegan, IL 60085. 

P.O. Box 326, Ridgefield, NJ 07657. 

235 E. 42d St., New York, NY 10017. 

Broad and Wood Sts., Bethlehem, PA 18018. 

Oak St. and Buff Hd., P.O. Box 189, Burlington, 

lA 52602. 
841-A Adama Bldg., Bartlesville, OK 74003. 
9505 Caesius Ave., Cleveland, OH 44105. 
P.O. Box 98, Rookford, IL 61105. 
608 2nd Ave. S., Minneapolis, MN 55402. 
11756 Burke St., Santa Pe Springs, CA 90670. 
Route 73, Maple Shade, NJ 08052. 
Pionite Rd., Auburn, ME O4210. 
191 Doremus Ave., Newark, NJ 07105. 
1 Gateway Center, Pittsburgh, PA 15222. 
1607 Geele Ave., Sheboygan, WI 53082. 
2700 S. Westmoreland, Dallas, TX 75224. 
4837 James St., Philadelphia, PA 19137. 
33 Sprague Ave., Middletown, NY 10940. 
490 Hunts Point Ave., New York, NY 10059. 
2120 Fairmont Ave., Reading, PA 19603. 
Viaduct Rd., Springdale, CT 06879. 
11655 Wicks St., Sun Valley, CA 91352. 
P.O. Box 320, Woodbury, NJ 08096. 
730 Main St., Wilmington, MA 01887. 
3400 Uwrenoe Dr., Corpus Christi, TX 78403. 
75 Tonawanda St., Buffalo, NY 14207. 
917 W. Juneau Ave., Milwaukee, WI 53201. 
P.O. Box 100, Pasadena, TX 77501. 

Ivorydale Technical Ctr., Rm. 2S25, Cincinnati, OH 45217. 
P.O. Box 399, Salisbuiy, NC 28144. 
615 S. Flower St., Los Angeles, CA 90017. 
2919 Bnpire Ave., Burbank, CA 91504. 
1429 Walnut St., Philadelphia, PA 19102. 
Rm. 72.2 - Carr. No. 2, Arecibo, PR 00613. 
5101 dark Ave., Lakewood, CA 90712, and 2260 N. ELston 

Ave., Chicago, IL 60614. 



DIRECTORY OF MANUFACTURERS 209 

TABLE 22. --Synthetic organic chemicals : Directory of manufacturers , 2966- -Continued 



of company 



Office addres 



Qiaker Chemical Corp 

Qaaier Oats Co 

K. J. Oalnn & Co., Ino 

R.S.A. Corp 

Baohelle Laboratories, Ino 

Raybestos-Manhattan, Inc., Raybestos Div — 

Rayette-Faberge, Inc 

Red Spot Paint & Varnish Co., Ino 

Refined Products Co 

Reheis Chemical Co., Div. of Armour Riarma- 

oeutical Co. 
Reiohhold Chemicals, Ino 

Varoum Chemical Div 

Reilly Tar & Chemical Corp 

Reliance Universal, Ino 

Remington Arms Co., Inc 

Renroh Resins 

Retzloff Chemical Co 

Rexall Chemical Co 

Fiberfil Div 

Rezolin, Ino 

Rhodia, Ino 

Richardson Co 

Richardson Polymers Div 

Riker Laboratories, Div. of Rexall Drug & 

Chemical Co. 

F. Hitter & Co 

Ritter Chemical Co., Inc- 

Ritter Efaudler Corp., lonao Chemical Co. E 

Riverdale Chemical Co 

Roberts Chemicals, Ino 

Rook Hill Printing & Finishing Co 

Roehr Chemicals, Ino 

Rogers Corp 

Rohm & Haas Co 

Rosenberg Bros. & Co 

Royoe Chemical Co 

Rubicon Chemicals, Inc 

St. Regis Paper Co., Lake States Div 

Salsbury Laboratories 

Sandoz, Inc 

Sartomer Resins, Ino 

Schaefer Varnish Co., Ino 

Schenectady Chemicals, Ino 

Scher Bros., Ino 

R. P. Scherer Corp 

Sobering Corp 

Scholler Bros., Inc 

Seaboard Chemicals, Ino 

G. D. Searle & Co 

Seidlitz Paint & Varnish Co 

Sekisul Plastics Corp 

Selney Co., Inc 

Seydel-Woolley & Co., Ino 

Shamrock Oil & Ges Corp 

Shanoo Plastics & Chemicals, Inc 

Shell Oil Co 

Shell Chemical Co. Div 

aiepherd Chemical Co 

Sherwin-Williams Co 

Shulton, Inc 

George F. Slddall Co., Ino 

Signal Oil & Gas Co 

Siinpson Timber Co 

Slnolair-Kbppers Chendoal Co 

Sinolalr-Koppers Co 



ELm and Sandy Sts., Conshohocken, PA 19428. 
345 Merchandise Mart Plaza, Chicago, IL 60654. 
195 Canal St., Maiden, MA 02148. 

690 Saw Mill River Rd., Ardsley, m 10502. 

700 Henry Ford Ave., Long Beach, CA 90810. 

75 E. Main St., Stratford, CT 06601. 

261 E. 5th St., St. Paul, MN 55101. 

110 Main St., Evansville, IN 47708. 

624 Schuyler Ave., I^mdhurst, NJ 07071. 

325 Snyder Ave., Berkeley Heights, NJ 07922. 

525 N. Broadway, White Plains, NY 10602. 

Niagara Falls, NY 14302. 

11 S. Meridan St., Indianapolis, IN 46204. 

4730 Crittenden Dr., P.O. Box 21067, Louisville, KY 

40221, and 6901 Cavalcade, Houston, TX 77001. 
939 Bamum Ave., Bridgeport, CT 06602. 
P.O. Box 1191, New Bern, NO 28560. 
P.O. Box 45296, Houston, TX 77045. 
8480 Beverly Blvd., Los Angeles, CA 90048. 
1701 N. Heidelbaoh Ave., Evansville, IN 47717. 
1651 18th St., Santa Monica, CA 90404. 
600 Madison Ave., New York, NY 10022. 
2700 W. Lake St., Melrose Park, IL 60160. 
345 Morgan Lane, West Haven, CT 06516. 
19901 Nordhoff St., Northridge, CA 91324. 

4001 Goodwin Ave., Los Angeles, CA 90039. 

403 W. Main St., Amsterdam, NY 12010. 

Birmingham, NJ 08011. 

220 E. 17th St., Chicago Heights, IL 60411. 

P.O. Box 546, Nitro, WV 25143. 

Rook Hill, SC 29730. 

52-20 37th St., Long Island City, NY 11101. 

Rogers, CT 06263. 

Independence Mall West, Philadelphia, PA 19105. 

100 Landing Ave., Smithtown, NY 11787. 
Carlton Hill P.O., E. Rutherford, NJ 07073. 
P.O. Box 517, Geismar, LA 70734. 

603 W. Davenport St., Rhinelander, WI 54501. 

500 Gilbert St., Charles City, U 50616. 

P.O. Box 357, Fair Lawn, NJ 07410, and Route 10, 

Hanover, NJ 07936. 
P.O. Box 56, Essington, PA 19029. 
1350 S. 15th St., Louisville, KY 40210. 
Congress St. and 10th Ave., Schenectady, NY 12301. 
P.O. Box 538, Allwood Station, Clifton, NJ 07012. 
9425 Grinnell Ave., Detroit, MI 48213. 
1011 Morris Ave., Union, NJ 07083. 

Collins and Westmoreland Sts., Philadelphia, PA 19134. 
30 Foster St., Salem, MA 01970. 
P.O. Box 5110, Chicago, IL 60680. 
18th and Garfield Sts., Kansas City, MO 64141. 
666 Dietrich Ave., Hazelton, PA 18201. 
65 9th St., Brooklyn, NY 11215. 
748 Rice St. NW., Atlanta, GA 30318. 
P.O. Box 631, Amarillo, TX 79105. 
2716 Kenmore Ave., Tonawanda, NY 14150. 
52 W. 52d St., New York, NY 10019. 
113 W. 52d St., New York, NY 10019. 
5000 Paplar St., Cincinnati, OH 45212. 

101 Prospect Ave. NW., Cleveland, OH 44101. 
697 Route 46, Clifton, NJ 07015. 

P.O. Box 925, Spartanburg, SC 29301. 

P.O. Box 5008, Harrisburg Station, Houston, TX 77012. 

2301 N. Columbia Blvd., Portland, OR 97217. 

9822 La Borte Freeway, Houston, TX 77012. 

900 Konners Bldg., Pittsburgh, PA 15219. 



210 SYNTHETIC ORGANIC CHEMICALS, 1966 

TABLE 22. -Synthetic organic chemicals : Directory of manufacturers , 1966 — Continued 



Sinclair Paint Co 

Sinclair Petroohemcals, Ino 

Sinclair Refining Co 

James B. Sipe & Co 

Skelly Oil Co 

G. Frederick Smith Chemical Co 

Smith, Kline & French Laboratories 

Socony Kkjbil CtLl Co., Inc.: 

Mobil Chemical Co. Div 

Chemical Coatings Div., Louisville Plant 
Sohio CSiemioal Co. & Solar Nitrogen Chemicals, 
Inc. 

Solar Chemical Corp 

Soluol Chemical Co., Inc 

Solvent Chemical Co., Ino 

Sonford Chemical Co 

Sonoco Products Co 

Sou-Tex Chemical Co., Inc 

Southeastern Mhesives Co 

Southeast Polyioers, Ino 

Southern Sizing Co 

Spaulding Fibre Co., Inc 

E. R. Squibb & Sons, Inc 

A. E. Staley Manufacturing Co 

UBS Chemical Co. Div 

Stamford Chemical Co 

Standard Brands, Inc., Clinton Com Processing 
Co. Div. 

Standard Chemical Products, Inc 

Standard Chlorine Chemioal Co., Inc 

Standard Oil Co. of California, Chevron 
Chemical Co. 

Standard Oil Co. of Ohio 

Standard jyroxoloid Corp 

Stange Co 

Stauf f er Chemical Co. : 

Calhio Chemicals, Ino. Div 

Industrial Chemioal Div 

Specialty Chemical Div 

Stein, Hall & Co., Ino 

Stepan Qiemioal Co. : 

Industrial Chemicals Div., Millsdale Works—- 

Maywood Div 

Sterling Drug, Inc.: 

Glenbrook Laboratories Div 

Hilton-Davis Chemical Co. Div 

Salvo Chemical Div 

Thomasset Colors Div 

Winthrop Laboratories Div 

Stresen-Rfiuter International, International 
Minerals & Chemioal Group. 

Sue ro- Chemical Div. of Colonial Sugars Co 

Sugar Beet Products Co 

Sullivan Varnish Co 

Summit Chemical Products Corp 

Sun Chemical Corp 

Chemioal Products Div 

Chemical Products Div 

Ind\iBtrial Coatings Div 

Sun Chemical Corp - Kearny 

Sunkist Growers, Inc 

Sun Oil Co 

SunOLln Chemioal Co 

Sunray DX Oil Co — 

Suntide Refining Co 

Suift & Co 

Synthetic. Chemicals, Inc 

^mthetio Products Co 



3960 E. Washington Blvd., Los Angeles, CA 90023. 

600 5th Ave., New York, NY 10020. 

600 5th Ave., New York, NY 10020. 

P.O. Box 13090, Pittsburgh, PA 15243. 

Oil Center Bldg., P.O. Box 1650, Tulsa, OK 74102. 

867 MoKinley Ave., Columbus, OH 43223. 

1500 Spring Garden St., Philadelphia, PA 19101. 

7301 Bessemer Ave., Cleveland, OH 44127 and Metuohen, 

NJ osaio. 

1630 W. Hill Street, Louisville, KY 40210. 
1434 Midland Bldg., Cleveland, OH 4^115. 

Fuller St., Leominster, MA 01453. 

Green Hill and Market Sts., P.O. Box 112, W. Warwick, 
02893. 

341 Commercial St., Maiden, MA 02148. 
P.O. Box 127, Ftort Neches, TX 77651. 
Hartsville, SC 29550. 

E. Catawba Ave., Mount Holly, NC 28120. 

P.O. Box 791, Lenoir, NC 28645. 

P.O. Box 309, Chattanooga, TN 37401. 

P.O. Box 987, East Point, GA 30aW. 

310 Wheeler St., Tonawanda, NY 14150. 

745 5th Ave., New York, NY 10022. 

22d and Eldorado Sts., Lecatur, IL 62525 

491 Main St., Cambridge, MA 02U2. 

45 Jefferson St., P.O. Box 1131, Stamford, CT 06940. 

1251 Beaver Channel Parkway, Clinton, lA 52733. 

1301 Jefferson St., Hoboken, NJ 07030. 
1025 Belleville Turnpike, Kearny, NJ 07032. 
200 Bush St., San Francisco, CA %120. 

Midland Bldg., Cleveland, OH 4^115. 
85 Pleasant St., Leominster, MA 01453. 

342 N. Western Ave., Chicago, IL 60612. 

380 Madison Ave., New York, NY 10017. 
380 Madison Ave., New York, NY 10017. 
380 Madison Ave., New York, NY 10017. 
605 3d Ave., New York, NY 10016. 

ELwood, IL 60421. 

100 W. Hunter Ave., Maywood, NJ 07607. 

90 Park Ave., New York, NY 10018. 

2235 Langdon Farm Rd., Cincinnati, OH 45237. 

Military Rd., Rothschild, WI 54474. 

120 Lister Ave., Newark, NJ 07105. 

90 Park Ave., New York, NY 10016. 

400 W. Roosevelt Ave., Bensenvllle, IL 60106. 

P.O. Drawer G, Gramercy, LA 70052. 

302 Waller St., Saginaw, MI 48605. 

410 N. Hart St., Qiioago, IL 60622. 

11 William St., Belleville, NJ 07109. 

185 Foundry St., Newark, NJ 07105. 

441 Tompkins Ave., Staten Island, NY 10305. 

Wood River Junction, RI 02894. 

135 W. Lake St., Northlake, IL 60164. 

1106 Harrison Ave., Kearny, NJ 07029. 

720 E. Sunkist St., Ontario, CA 91764. 

1608 Walnut St., Riiladelphla, PA 19103. 

P.O. Box F, Claymont, DE 19703. 

P.O. Box 2039, Tulsa, OK 74102. 

P.O. Box 2608, Corpus Christi, TX 78403. 

115 W. Jackson Blvd., Chicago, IL 60604. 

335 KfcLean Blvd., Paterson, NJ 07504. 

1636 Wayside Rd., Cleveland, OH 44112. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. -Synthetic organic chemicals; Directory of manufacturers, i 566- -Continued 



Name of conpany 



SJyiithron, Ino 

^var Corp 

Tanatex Chemical Corp 

Qiarles S. Tanner Co 

Tenneoo Chemicals, Inc 

Berkshire Color Div 

Cal/Ink Div— 

Newport Div 

New York Color Div 

Nixon-Baldwin Div 

Nuodex Div 

Tenneco Manufacturing Co., Tenneco Plastics 

Div. 
Tenneco Oil Co., Refining & Marketing 
Accounting. 

Tennessee Copper Co 

Texaco, Ino 

Texas Alkyls, Ino 

Texas-U.S. Chemical Co 

Tex Ghem Co 

Texize Chemicals, Ino 

Textilana Corp 

Textilana-Nease, Ino 

Thiokol Chemical Corp 

Thomason Industries, Inc., Southern Resin Div. 
Thoii5)son Apex Co., Div. of Continental Oil Co. 

Thonfison Chemical Corp 

Thompson-Hayward Chemical Co 

Ticonderoga Chemical Corp 

Tidewater Oil Co 

Tizon Chemical Corp 

Toms River Chemical Corp 

Arthur C. Trask Co 

Triangle Chemical Co 

Trojan Powder Co 

Troy Chemical Co 

Trylon Chemical Corp 

Joseph Turner & Co 

USS Qiemicals Div. of U.S. Steel Corp 

Paul Uhlioh & Co., Ino 

Ifagerer & Co 

Union-Camp Corp., Chemical Div 

Union Carbide Corp. : 

Chemicals Div 

Plastics Div 

Silicones Div 

Union Oil Co. of California 

Union Starch & Refining Co., Ino 

Uniroyal, Inc., Uhiroyal Chemical Div 

United Carbon Co 

United Chemical Corp. of Norwood 

United Chemical Products Corp- 

United Merchants & Mfgrs., Inc., Roma 
Chemioal Div. 

United Oil Manufacturing Co 

U.S. Borax Research Corp 

U.S. Oil Co 

U.S. Peroxygen Corp- 

United States Pipe & Foundry Co 

United States Plywood Corp., California Div., 
Shasta Operations. 

Universal Chemicals Corp 

Universal Oil Products Co 

lemical Div 

Upjohn Co 

Carwin Organic Chemicals 

Utah Resin Co., Ino 



Office address 



Ryan Ave., Ashton, RI 02805. 

917 Washington St., Wilmington, DE 19899. 

P.O. Box 388, lyndhurst, NJ 07071. 

P.O. Box 3867, Park Place, Greensville, SC 29608. 

300 E. 42d St., New York, NY 10017. 

12th and Bern Sts., Reading, PA 19604. 

711 Camella St., Berkeley, CA 94710. 

P.O. Box 911, Pensacola, FL 32502. 

374 Main St., Belleville, NJ 07109. 

Nixon, NJ 08818. 

P.O. Box 2, Plscataway, NJ 08854. 

P.O. Box 2, Plscataway, NJ 08854. 



P.O. 



2511, Houston, TX 77001. 



Copperhill, TN 37317. 

1111 Rush Ave., Houston, TX 77052. 

P.O. Box 600, Deer Park, TX 77536. 

P.O. Box 667, Port Neches, TX 77651. 

20-21 Wagaraw Rd., Fair Lawn, NJ 07410. 

P.O. Box 368, Greenville, SC 29602. 

12607 Cerise Ave., Hawthorne, CA 90250. 

1240 S. 88th St., Klwardsville, KS 66022. 

P.O. Box 27, Bristol, PA 19007. 

P.O. Drawer 1600, Fayetteville, NC 28301. 

505 Central Ave., Pawtucket, RI 02862. 

3028 Locust St., St. Louis, MO 63103. 

5200 Speaker Rd., Kansas City, KS 66110. 

Marguerite Ave., Leominster, MA 01453. 

Delaware City, DE 19706. 

Looktown Rd., Flemlngton, NJ 08822. 

P.O. Box 71, Tbms River, NJ 08753. 

327 S. LaSalle St., Qilcago, IL 60604. 

206 Lower Elm St., P.O. Box 4528, Macon, GA 312 

17 N. 7th St., Allentown, PA 18105. 

338 Wilson Ave., Newark, NJ 07105. 

P.O. Box 5101, Station B, Greenville, SC 29606. 

Pleasant View Terrace, Ridgefield, NJ 07451. 

Grant Bldg., Pittsburgh, PA 15219. 

90 West St., New York, NY 10006. 

161 Avenue of the Americas, New York, NY 10013. 

P.O. Box 6170, Jacksonville, FL 32205. 

270 Park Ave., New York, NY 10017. 

270 Park Ave., New York, NY 10017. 

270 Park Ave., New York, NY 10017. 

461 S. Boylston St., Los Angeles, CA 90017. 

301 Washington St., Columbus, IN 47201. 

Naugatuck, CT 06771. 

P.O. Box 149, Baytown, TX 77520. 

P.O. Box 327, Endicott St., Norwood, MA 02062. 

York and Colgate Sts., Jersey City, NJ 07302. 

749 Quequeohan St., F^n River, MA 02721. 

2d and Cascade Sts., Erie, PA 16512. 
3075 Wilshlre Blvd., Los Angeles, CA 90005. 
P.O. Box 4228, E. Providence, RI 02914. 
850 Morton Ave., Richmond, CA 94804. 
3300 1st Ave. N., Birmingham, AL 35202. 
P.O. Box 2317, Redding, CA 96001. 

P.O. Box 1224, Ashton, RI 02865. 
30 Algonquin Rd., Des Plalnes, IL 60018. 
State Highway 17, E. Rutherford, NJ 07073. 
7000 Portage Rd., Kalamazoo, MI 49001. 
Sackett Point Rd., North Haven, CT 0&;73. 
604-605 Keams Bldg., Salt Lake City, UT 84101. 



212 SYNTHETIC ORGANIC CHEMICALS, 1966 

TABLE 22. -Synthetic organic chemicals : Directory of manufacturers , 1966 — Continued 



Name of coirpany 



Office address 



Valchem 

Valentine Sugars, Inc., Valite Div 

Valley Nitrogen Producers, Ino 

Van De Mark Chemical Co 

Vanderbilt Chemical Corp 

Van Eyk & Co., Inc 

Varney Chemical Corp 

Veliscol 'Chemical Corp 

Industrial Chemicals Div 

Ventron Corp., Metal Hydrides mv 

Vermi lye-Bell 

Verona-Pharma Chemical Corp 

Vickers Refining Co., Inc 

Vineland Chemical Co 

Virginia Chemicals, Inc 

Vistron Corp., Silmar Div 

Vitra-Var Corp., Div. of Textron Industries, 

Inc. 
Vulcan Materials Co., Chemical Div. 

Wallace & Herman, Inc.: 

Harchem Div 

Lucidol Div 

Wamer-Jenkinson Manufacturing Co 

Warner Machine Products, Inc., Warner 
Chemical Div. 

Washine Chemical Corp 

West Coast Mhesives Co 

Westinghouse Electric Corp., Insulating 
Materials Div. - Benollte. 

Weston Chemical Corp 

West Virginia Pulp & Paper Co., BdIj- 
chemicals Div. 

Weyerhaeuser Co., Wood Products Div 

White & Bagley Co 

White & Hodges, Inc 

White Laboratories, Inc 

Whitmoyer Laboratories, Inc 

Whittaker Corp., Narmco Research & Develop- 
ment Div. 

Whittemore-Wright Co., Inc 

Wioa Chemicals, Inc 

Wilmot & Cassidy, Inc 

Wilson & Co., Inc. : 

Wilson Laboratories Div 

Wilson-Martin Div 

Witeo Chemical Co., Inc 

Sonneborn Div 

Witfield Chemical Corp 

Wobum Chemical Corp 

W. A. Wood Co 

Wood Ridge Chemical Corp 

Woonsocket Color & Chemical Co 

Worthington Biochemical Corp 

Wyandotte Chemicals Corp 

^con 

Young Jtaillne Works, Inc 



1407 Broadway, New York, NY 10018. 

726 Whitney Bldg., New Orleans, LA 70130. 

P.O. Box 128, Helm, CA 93627. 

N. Transit Rd., Lockport, NY U09ii. 

33 Winfield St., E. Norwalk, CT 06855. 

11 William St., Belleville, NJ 07109. 

2001 Afton Ed., Janesville, WI 53545. 

341 E. Ohio St., Chicago, IL 60611. 

4902 Central Ave. , Chattanooga, TN 37410. 

12-24 Congress St., Beverly, MA 01915. 

21707 Bothell Way, Bothell, WA 98011. 

P.O. Box 385, Springfield Rd., Union, NJ 07083. 

P.O. Box 2240, Wichita, KS 67201- 

W. Wheat Rd., Vineland, NJ 08360. 

West Norfolk, VA 23703. 

12335 S. Van Ness Ave., Hawthorne, .A 9C250. 

177 Oakwood Ave., Grange, NJ 07050. 

P.O. Box 545, Wichita, KS 67201. 



25 Main St., Belleville, NJ 07109. 
1740 Military Rd., Buffalo, NY 14240. 
2526 Baldwin St., St. Louis, MO 63106. 
1200 Rochester Ave., Ifcmcie, IN 47302. 

165 Main St., Lodl, NJ 07644. 

11104 NW. Front Ave., Portland, OR 97231. 

Manor, PA 15665. 

104 E. 40th St., New York, NY 10016. 
P.O. Box 5207, N. Charleston, SC 29406. 

118 S. Palmetto St., Marshfield, WI 54449. 
P.O. Box 1171, Worcester, MA 01601. 
576 Lawrence St., Lowell, MA 01852. 
Galloping Hill Rd., Kenilworth, NJ 07033. 
19 N. Railroad St., Myerstown, PA 17067. 
3540 Aero Ct., San Diego, CA 92123. 

62 Alford St., Boston, MA 02129. 
P.O. Box 506, Charlotte, NC 28201. 
108 Provost St., Brooklyn, NY 11222. 

4221 S. Western Blvd., Chicago, IL 60609. 

Jackson and Swanson Sts., Philadelphia, PA 191A8. 

P.O. Box 305, Paramus, NJ 07652. 

277 Park Ave., New York, NY lOU^ '. 

P.O. Box 1243, Wilmington, CA 90744. 

1200 Harrison Ave., Harrison, NJ 07029. 

108 Spring St., Everett, MA 02149. 

Park PI. E., Wood Ridge, NJ 07075. 

176 Sunnyside Ave., Woonsocket, RI 02895. 

Route 9, Freehold, NJ 07728. 

1609 Biddle Ave., Wyandotte, MI 48192. 

P.O. Box 1087, Colorado Springs, CO 80901. 

2731 Boston St., Baltimore, MD 21224. 



APPENDIX 

U.S. Imports of Benzenoid Intermediates 
and Finished Benzenoid Products 

Table 23 summarizes, for 1965 and 1966, U.S. imports of benzenoid chemicals and products 
entered under the Tariff Schedules of the United States (TSUS), schedule 4, part 1, subparts B 
and C. The data, which were obtained by analyzing invoices covering imports through U.S. 
customs districts, are given in detail in a separate report of the Tariff Commission. ■■• 

In 1966, general imports of benzenoid intermediates entered under schedule 4, part IB, com- 
prised 665 items with a total weight of 68. 9 million pounds and an invoice value of $31.2 million. 
In 1965, imports consisted of 642 items with a total weight of 38, million pounds and an invoice 
value of $19. 5 million. About half of the benzenoid chemicals and products imported in 1966 were 
declared to be "competitive" (duty based on "American selling price"). In 1966, imports of these 
products from Canada amounted to 23 percent of the total; imports from that country amounted 
to 15.6 million pounds, compared with 13 million pounds in 1965. In 1966, imports from Italy 
amounted to 5.8 million pounds, compared with 8. I million pounds in 1965. Imports from West 
Germany amounted to 14. 5 million pounds, compared with 7. 2 million pounds in 1965. Imports 
from Japan totaled 14.4 million pounds in 1966, compared with 3. 3 million pounds in 1965; and 
imports from the United Kingdom amounted to 8. 1 million pounds, compared to 2. 2 million 
pounds in 1965. Sizable quantities of intermediates were also imported in 1966 from Switzer- 
land (2. million pounds), France (3. 5 million pounds), and Sweden (0. 9 million pounds). 

The most important intermediates imported in 1966 were phenol, styrene, adipic acid, 
alkylbenzene, phthalic anhydride, Bisphenol A, poly alky Ibenzene, ethylbenzene and 3-hydroxy- 



TABLE 23. 



■ Benzenoid intermediates and finished benzenoid products .- U.S. general imports, 
classified by use, 1965 and 1966 



Intermediates 

Finished benzenoid products, total 

Dyes, total 

Acid 

Azoic dyes 

Azoic components: 

Fast color bases 

Fast color salts 

Naphthol AS and its derivatlves-- 

Basic 

Direct 

Disperse 

Fiber-reactive 

Fluorescent brightening agents 

Mordant 

Solvent 

Sulfur 

Vat 

All other 

Benzenoid pigments (toners and lakes) 

Medicinals and pharmaceuticals 

Flavor and perfume materials 

All other 



1,000 
pounds 
37,975 



12, 276 

22 

416 
185 

1,093 

1,227 
931 

1,880 
652 
229 
221 
168 
37 

3,374 
233 

797 

3,408 

1,908 

'13,552 



13,715 
2,555 



520 

269 

1,558 

1,136 

1,159 

2,494 

1,249 

247 

362 

265 

45 

1,761 

^81 

1,010 

4,674 

2,564 

'25,912 



1,000 
dollars 

31,217 



1,738 
10,855 

4,033 
U,416 



Includes small quantities of rubber-processing chemicals . 
^ Includes ingrain dyes. 
^ Includes organic pesticides and related products, plaaticlzers, surface active agents, and textile assistant. 

Source: Conplled from the records of the U.S. Bureau of Customs. 



als and Products, 1966, TC Publication 216, 1967 [processed]. 



213 



214 SYNTHETIC ORGANIC CHEMICALS, 1966 

2-naphthoic acid (B.O.N. ). In 1966, imports of phenol amounted to 8.6 million pounds and 
came from the United Kingdom, France and West Germany. Imports of styrene amounted to 
8. 5 million pounds and all came from Canada. Imports of adipic acid in 1966 totaled 5. 3 million 
pounds, compared with 13.7 million pounds in 1965 and all came from Canada. Imports of 
alkylbenzene in 1966 amounted to 5. 1 million pounds and imports of phthalic anhydride announted 
to 4.6 million pounds. All of the alkylbenzene and most of the phthalic anhydride came from 
Japan. In 1966, imports of 4, 4' -Isopropylidenediphenol (Bisphenol A), which came principally 
from the Netherlands and France, totaled 4.2 million pounds; imports of polyalkylbenzene, which 
came from Italy, totaled 3.7 million pounds; imports of ethylbenzene, which came from Canada, 
totaled 1. 2 million pounds; and imports of B.O.N. , which came from West Germany, Italy and 
Japan, totaled 917, 000 pounds. 

Imports in 1966 of all finished benzenoid chemicals and products that are dutiable under 
part IC comprised 2, 401 items, with a total weight of 47. 9 million pounds and an invoice value 
of $56. 9 million. In 1965, imports consisted of 2, 223 items, with a total weight of 31.9 million 
pounds and an invoice value of $45.4 million. The most important group of finished benzenoid 
products imported in 1966 was benzenoid dyes. Imports of dyes amounted to $25.8 million 
(invoice value), or 45.4 percent of the value of all imports under part IC. In 1965, imports of 
dyes amounted to $20. 5 million (invoice value), or 45. 1 percent of the value of all imports under 
part IC. 

Imports of medicinals and pharmaceuticals, the next most important group of products 
entered vmder part IC in 1966, decreased in 1966, compared with 1965. In 1966, imports of 
medicinals and pharmaceuticals were valued at $10.9 million (invoice value), or 19. 1 percent 
of the total value of imports under part IC. In 1965, imports of medicinals and pharmaceuticals 
were valued at $12.6 million or 27.6 percent of total value of imports under part IC. In 1966, 
imports of benzenoid pigments were valued at $1. 7 million, compared with $1. 5 million in 1965. 
Imports of benzenoid flavor and perfume materials in 1966 ($4.0 million) were 60 percent more 
than in 1965 ($2. 5 million). Imports of other benzenoid products in 1966, entered under part IC 
(chiefly polyamide resins and pesticides) were valued at $14.4 million, compared with $8. 3 
million in 1965. 



O - 307-771 



REPORTS OF THE UNITED STATES TARIFF COMIVIISSION ON THE OPERATION OF THE 
TRADE AGREEMENTS PROGRAM 

*Operation of the Trade Agreements Program, June 1934 to April 1948 (Rept. No. 160, 2d ser., 1949): 
Part I. Summary 

Part II. History of the Trade Agreements Program 
Part HI. Trade-Agreement Concessions Granted by the United States 
Part IV. Trade- Agreement Concessions Obtained by the United States 
Part V. Effects of the Trade Agreements Program on United States Trade 

♦Operation of the Trade Agreements Program: Second Report, April 1948- March 1949 (Rept. No. 

163, 2d ser., 1950) 

♦Operation of the Trade Agreements Program: Third Report, April 1949- June 1950 (Rept. No. 172, 

2d ser., 1951) 
♦Operation of the Trade Agreements Program: Fourth Report, July 1950- June 1951 (Rept. No. 174, 

2d ser., 1952) 
♦Operation of the Trade Agreements Program: Fifth Report, July 1951-June 1952 (Rept. No. 191, 

2d ser., 1954) 
♦Operation of the Trade Agreements Program : Sixth Report, July 1952- June 1953 (Rept. No. 193, 

2d ser., 1954) 
♦Operation of the Trade Agreements Program : Seventh Report, July 1953-June 1954 (Rept. No. 195, 

2d ser., 1955) 
♦Operation of the Trade Agreements Program: Eighth Report, July 1954-June 1955 (Rept. No. 197, 

2d ser., 1956) 
♦Operation of the Trade Agreements Program: Ninth Report, July 1955-June 1956 (Rept. No. 199, 

2d ser., 1957) 
♦Operation of the Trade Agreements Program : 10th Report, July 1956-June 1957 (Rept. No. 202, 

2d ser., 1959) 
♦Operation of the Trade Agreements Program: 11th Report, July 1957- June 1958 (Rept. No. 204, 

2d ser., 1959) 
♦Operation of the Trade Agreements Program : 12th Report, July 1958-June 1959 (TC Publication 

9, 1961) 
♦Operation of the Trade Agreements Program: 13th Report, July 1959- June 1960 (TC Publication 

51, 1962) 
Operation of the Trade Agreements Program: 14th Report, July 1960- June 1962 (TC Publication 

120, 1964), 350 
♦Operation of the Trade Agreements Program: 15th Report, July 1962-June 1963 (TC Publication 

147, 1965) 
Operation of the Trade Agreements Program: 16th Report, July 1963-June 1964 (TC Publication 

164, 1966), 300 

Operation of the Trade Agreements Program: 17th Report, July 1964-December 1965 (TC Pub- 
lication 192), 350 

NOTE. — The reports preceded by an asterisk (*) are out of print. Those followed by u price n«ay be purchased from 
the Superintendent of Documents, U.S. Government Printing Office, Washington, U.C. 20402. See inside front 
cover for additional reports. All U.S. Tariff Commission reports reproduced by the Government Printing Office 
may be consulted in the official depository libraries throughout the United States.