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Full text of "Synthetic organic chemicals"

BOSTON 

PUBLIC 

LIBRARY 




eovT 



mr:.. 



UNITED STATES TARIFF COMMISSION 



SYNTHETIC 
ORGANIC CHEMICALS 

United States Production 
and Sales, 1967 



TC Publication 295 




Boston Public Library 
Superintendent of Documents 

DEPOSITORY 



RECENT REPORTS OF THE UNITED STATES TARIFF COMMISSION ON 
SYNTHETIC ORGANIC CHEMICALS 

Synthetic Organic Chemicals, United States Production and Sales, 1962 (TC Publication 114, 

1963), $1.50 
Synthetic Organic Chemicals, United States Production and Sales, 1963 (TC Publication 143, 

1964), $1.50 
^Synthetic Organic Chemicals, United States Production and Sales, 1964 (TC Publication 167, 

1965) 
Synthetic Organic Chemicals, United States Production and Sales, 1965 (TC Publication 206, 

1967), $1.00 
Synthetic Organic Chemicals, United States Production and Sales, 1966 (TC Publication 248, 

1968), $1.50 



NOTE.-The report preceded by an asterisk (*) is out of print. The other reports listed above may be purchased from the 
Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402. All U.S. Tariff Commission reports 
reproduced by the Government Printing Office may be consulted in the official depository libraries throughout the United States. 



UNITED STATES TARIFF COMMISSION 



SYNTHETIC 
ORGANIC CHEMICALS 



United States Production 
and Sales, 1967 



UNDER THE PROVISIONS OF 
SECTION 332 OF THE TARIFF 
ACT OF 1930, AS AMENDED 



U.S. GOVERNMENT PRINTING OFFICE 
WASHINGTON : 1969 



TC Publication 295 



UNITED STATES TARIFF COMMISSION 

Glenn W. Sutton, Chairman 
Penelope H. Thunberg 
Bruce E. Clubb 
Will E.Leonard, Jr. 
Herschel D. Newsom 
George M. Moore 

WILLARD W. Kane, Acting Secretary 



Address all communications 

UNITED STATES TARIFF COMMISSION 

Washington, D.C. 20436 



For sale by the Superintendent of Documents, U.S. Government Printing Office 
Washington, D.C. 20402 - Price $2.00 



CONTENTS 



Tar crudes 



General 

Cyclic intermediates 

Dyes 

Pigments 

Medicinal chemicals 

Flavor and perfume materials - 

Plastics and resin materials 

Rubber-processing chemicals-- 
Elastomers (synthetic rubbers) 

Plasticizers 

Surface -active agents 

Pesticides and related products 
Miscellaneous chemicals 



Page 



Introduction X 

Summa ry 



Vll 



PART I. PRODUCTION AND SALES OF TARS, TAR CRUDES, AND CRUDES 
DERIVED FROM PETROLEUM AND NATURAL GAS 

Tars 1 



1 



Crude products from petroleum and natural gas for chemical conversion * 

PART II. PRODUCTION AND SALES OF INTERMEDIATES AND FINISHED 
SYNTHETIC ORGANIC CHEMICALS, BY GROUPS 



7 
10 
15 
26 
30 
34 
36 
40 
42 
43 
45 
51 
53 



PART III. LIST OF INDIVIDUAL PRODUCTS, BY GROUPS, 
AND NAMES OF MANUFACTURERS 

Tar crudes °1 

Crude products from petroleum and natural gas for chemical conversion 62 

Cyclic intermediates °^ 

Dyes 89 

Pigments 11'^ 

Medicinal chemicals ll'^ 

Flavor and perfume materials ^^' 

Plastics and resin materials ^^^ 

Rubber -processing chemicals '' 

Elastomers (synthetic rubbers) '■'*^ 

Pla sticizers l'*l 

Surface -active agents ^'^'* 

Pesticides and related products ^°^ 

Miscellaneous chemicals 1"" 

Directory of manufacturers ^°' 

APPENDIX 

U.S. imports of benzenoid intermediates and finished benzenoid products ''^'^ 



Introduction 

This is the fifty-first annual report of the U.S. Tariff Commission on domestic production 
and sales of synthetic organic chemicals and the raw materials from which they arc made. The 
report presents statistics for 1967 on crude organic chemicals derived from coal, natural gas, 
and petroleum; on intermediates; and on finished synthetic organic chemical products. The 
finished products are grouped according to their principal u8e--dye8, synthetic organic pigments, 
medicinal chemicals, flavor and perfume materials, plastics and resin materials, rubber-proc- 
essing chemicals, elastomers, plasticizers, surface-active agents, pesticides and related prod- 
ucts, and miscellaneous chemicals. The use classifications of finished synthetic organic chemi- 
cals are based principally on the manufacturers' annual reports to the Tariff Commission; other 
sources include trade associations, the chemical literature, chemical dictionaries, encyclo- 
pedias, and consultants in the chemical industry. With a few exceptions, the report does not 
cover organic chemicals (such as wood-distillation products, essential oils, and naval stores) 
that are derived from natural (vegetable) sources by simple extraction or distillation. The 
Commission has compiled the statistics given in this report from information supplied by the 
819 prin-iary n-ianufacturers listed in part 111. 

The first section of the report includes the statistics on all products and groups of products 
for which information can be published. The second section lists all the chemicals and chemical 
products on which data are reported and identifies the manufacturers of each. Each reporting 
company has been assigned an identification symbol consisting of a combination of not more than 
three capital letters, selected in most instances with the approval of the manufacturer, and 
usually bearing some relationship to the company name. The identification symbols are perma- 
nent and, except for such changes as may be necessary, will be used in all future reports in 
this series. This report includes data on only those individual chemicals for which the volume of 
production or sales in the year covered exceeded 1,000 pounds or for which the value of sales 
exceeded $1, 000. 

The raw materials referred to in this report are obtained from coal, crude petroleum, 
natural gas, and certain other natural materials, such as vegetable oils, fats, rosin, and grains. 
Crude organic chemicals are derived from coal by thernaal decomposition, from petroleum and 
natural gas by catalytic cracking and by distillation or absorption, and from other natural sources 
by fermentation. Production of these crude organic chemicals is the first step in the manufacture 
of synthetic organic chen-iicals. From these crudes, intermediates are obtained by synthesis or 
refining; most of the intermediates are then converted into finished chemical products, such as 
medicinal chemicals, plastics and resin materials, and dyes. More than half of the total produc- 
tion of intermediates is not sold directly to the ultimate consumer, but is used by the producing 
companies themselves in their manufacturing processes. The statistics given in this report in- 
clude data for all known domestic producers of the items covered. 

In this report the statistics on production of the individual chemicals rep>orted by manxifac- 
turers include the total output of the comjjanies' plants, i.e. , the quantities produced for con- 
sumption within the producing plants, as well as the quantities produced for domestic and foreign 
sale. The quantities reported as produced, therefore, generaUy exceed the quantities reported 
as sold. Some of these differences, however, are attributable to changes in inventories. As 
specified in the reporting instructions that the Comnnission sends to nnanufacturers, and as used 
in this report, production and sales (unless otherwise specifically indicated) are defined as 
follows: 

Production is the total quantity of a commodity made available by original manrjfaclMtr only. 
It is the sum (expressed in terms of 100-percent active ingredient unless otherwise specified) of 
the quantities of a commodity-- 

(1) Produced, separated, and consumed in the same plant or establishment (a commodity 

is considered to be separated when it is isolated from the reaction system and/or 
when it is weighed, analyzed, or otherwise measured). Byproducts and coproducts 
not classified as waste materials are also included; 

(2) Produced and transferred to other plants or establishments of the same firm; 

(3) Produced and sold to other firms (including production for others under toll agree- 

ments' ); and 

(4) Produced and held in stock. 



A loU agreement Is an agreemem b eto e e n two firms, under •hid) one tirm furnishes the raw materials and pays the processing costs 
and the other firm prepares the finished product and returns It to the first firm. 



INTRODUCTION 



Production excludes- 



(1) Purification of a comnnodity unless specifically requested in the reporting instructions; 

(2) Intermediate products that are formed in the manufacturing process but are not iso- 

lated from the reaction system--that is, not weighed, analyzed, or otherwise meas- 
ured; and 

(3) Materials that are used in the process but are recovered for reuse or sale; and waste 

products that have no economic significance. 

Sales are defined as actual sales of commodities by original manufacturers only. Sales include-- 

(1) Shipments of commodities for domestic use and for export, or segregation in a ware- 

house when title has passed to the purchaser in a bonafide sale; 

(2) Shipnnents of a commodity produced by others under toll agreements; and 

(3) Shipments to subsidiary or affiliated companies. 

Sales exclude -- 

(1) All intracompany transfers within a corporate entity; 

(2) All sales of purchased connmodities; and 

(3) All shipments of a commodity produced for others under toll agreements. 

The value of a sale is the net selling price, f. o.b. plant or warehouse, or delivered value, 
whichever represents the normal industry practice. 

Data on the chemicals covered in this report are usually given in terms of undiluted mate- 
rials. Products of 95 percent or more purity are considered to be 100 percent pure. The prin- 
cipal exceptions are the statistics on dyes and a few solvents, which are reported in terms of 
commercial concentrations, and the statistics on certain plastics and resins, which are reported 
on a dry basis. The report specifically notes those products for which the statistics are reported 
in terms of commercial concentrations. 

The average unit values of sales for groups of products shown in the tables accompanying 
this report are the averages for products which vary widely in unit values and in the quantities 
sold. 

Statistics are presented in as great detail as is possible without revealing the operations of 
individual producers. Statistics for an individual chemical or group of chemicals are given only 
where there are three or more producers no one or two of which may be predominant. Moreover, 
even when there are three or more producers, statistics are not given if there is any possibility 
that their publication would violate the statutory provisions relating to unlawful disclosure of in- 
formation accepted in confidence by the Commission. ^ 

Statistics on tars and tar crudes include data furnished directly to the Tariff Commission by 
distillers of coal tar, water-gas tar, and oil-gas tar, and data furnished to the Division of Bitu- 
minous Coal, U.S. Bureau of Mines, by coke-oven operators. 

Statistics on U.S. general imports in 1967 of benzenoid intermediates and finished benzenoid 
products that entered under schedule 4, parts IB and IC, of the Tariff Schedules of the United 
States are given in the appendix. 

Information on synonymous names of organic chemicals included in this report may be found 
in the SOCMA Handbook: Commercial Organic Chemical Names, recently published by the Chemical Abstracts 
Service of the American Chemical Society, or the Colour Index (2d edition), published in 1956 by the 
Society of Dyers and Colourists. 



^ Sec. 5, U.S.C. 139b and sec. 18, U.S.C. 1905. 



Summary 

Combined production of all synthetic organic chemicals, tars, tar crudes, and crude prod- 
ucts from petroleum and natural gas in 1967 was 176,541 million pounds--an increase of 4.4 
percent over the output in 1966 (see table 1), Sales of these materials in 1967, which totaled 
94,309 million pounds, valued at $11,466 million, were 4.6 percent larger than in 1966 in terms 
of quantity and 4. 2 percent larger in terms of value. These figures include data on production 
and sales of chemicals measured at several successive steps in the manufacturing process, and 
therefore they necessarily reflect some duplication. 

In 1967, production of all synthetic organic chennicals, including cyclic intermediates and 
finished chemical products, totaled 104, 711 million pounds, or 4. 1 percent more than the output 
in 1966 (see table 1). Production of cyclic intermediates (20, 793 million pounds) was 6.8 percent 
larger in 1967 than in 1966; that of surface-active agents (3,479 million pounds) was 4.8 percent 
larger; that of plasticizer chemicals (1, 263 million pounds) was 4. 4 percent larger. 

The output of other groups of synthetic organic chemicals which increased in 1967 compared 
to 1966 were nniscellaneous chemicals and synthetic organic pigments (both 4. 3 percent) and 
pesticides and related products (3.6 percent). Plastics and resin materials increased by 1.5 
percent while flavor and perfume materials showed the smallest percentage gain in 1966 over 
1967 (.8 percent). 



TABLE I. --Synthetic organic chemicals and their raw materials : U.S. production and sales. 1966 and 1967 



Chemical 



Production 



1966 



1967 



Increase 
or 

decrease 

(-), 1967 

over 

1966^ 



Sales 



Quantity 



1966 



1967 



Increase 

or 

decrease 

(-),1967 

over 

1966^ 



1966 



1967 



Increase 

or 

decrease 

(-), 1967 

over 

1966^ 



Grand total^ 

Tar 

Tar crudes 

Crude products from petroleum and 
natural gas 

Synthetic organic chemicals, total^ 

Intermediates 

Dyes 

Synthetic organic pigments 

Medicinal chemicals 

Flavor and perfume materials 

Plastics and resin materials 

Rubber-processing chemicals 

Elastomers isynthetic rubbers) — 

Plasticizers 

Surface-active agents 

Pesticides and related products — 
Miscellaneous chemicals 



Ml I i ion 
pounds 
169,174 



Ml 1 1 ion 
pounds 
176,541 



Percent 
4.4 



Ml 1 1 ion 
pounds 
90,175 



Mill ion 
pounds 
94,309 



Percent 
4.6 



Mil lion 
dol lars 
10,999 



Ml I I ion 
dol lars 
11,466 



8,019 
10,062 

50,467 

100,627 



7,803 
9,588 

54,438 

104,711 



-2.7 
-4.7 



7.9 
4.1 



3,613 
6,348 

27,494 

52,720 



3,547 
6,132 

29,453 

55,177 



-1.8 
-3.4 



7.1 



4.7 



35 
140 



865 



9,958 



34 
136 



858 



10,438 



19,467 

219 

51 

185 

111 

13,585 

283 

3,929 

1,209 

3,321 

1,013 

57,253 



20,793 

206 

53 

180 

112 

13,793 

264 

3,823 

1,263 

3,479 

1,050 

59,696 



6.8 

-5.9 

4.3 

-2.9 

.8 

1.5 

-6.8 

-2.7 

4.4 

4.8 

3.6 

4.3 



8,852 

204 

43 

136 

98 

11,472 

209 

3,411 

1,156 

1,766 

822 

24,549 



9,461 

199 

43 

127 

97 

11,977 

201 

3,262 

1,162 

1,750 

897 

26,001 



6.9 

-2.7 

-1.0 

-7.0 

-1.8 

4.4 

-4.0 

-4.4 

.5 

-.9 

9.1 

5.9 



925 
331 
108 
398 
93 

2,740 
138 
918 
246 
315 
584 

3,162 



1,000 

332 

108 

385 

93 

2,673 
132 
874 
261 
317 
787 

3,476 



Percen I 

4.2 



-2.6 
-3.1 



.1 

.6 

34.8 

9.9 



Percentages calculated from figures rounded to thousands. 
Because of rounding, figures may not add to the totals shown. 



PART I. PRODUCTION AND SALES OF TARS, TAR CRUDES, AND 
CRUDES DERIVED FROM PETROLEUM AND NATURAL GAS 



Tars 

Coal tar is produced chiefly by the steel industry as a byproduct of the manufacture of coke; 
water-gas tar and oil-gas tar are produced by the fuel-gas industry. Production of coal tar, 
therefore, depends on the demand for steel; production of water-gas tar and oil-gas tar reflects 
the consumption of manufactured gas for industrial and household use. Water-gas and oil-gas tars 
have properties intermediate between those of petroleum asphalts and coal tars. Petroleum 
asphalts are not usually considered to be raw materials for chemicals. 

The quantity of tar produced from coal in the United States in 1967 was 780 million gallons, 
or 2. 7 percent less than the 802 million gallons produced in 1966. U. S. production of water-gas 
and oil-gas tar was not reported to the Commission for 1966 or 1967; production of these tars 
amounted to 1 9 million gallons in 1962, the last year for which production was reported to the 
Tariff Commission. 

Total consumption of tar in 1967 amounted to 747 million gallons, of which 595 million gal- 
lons was consumed by distillation, 129 million gallons as fuel, and 23 million gallons in mis- 
cellaneous uses (table 2). 



TABLE 2. --Tar.- U.S. production and consumption, 1966 and 1967 

[in thousands of gallons] 



Product 



1966 



1967 



PRODUCTION 

Coal tar from coke-oven byproduct plants, total^ 

CONSUMPTION 
Total 

Tar consumed by distillation, total 

Coal tar distilled or topped by coke-oven operators"'" 

Coal tar and water-gas tar distilled by producers and tar distillers^ 

Tar consumed chiefly as fuel^ 

Tar consumed otherwise than by distillation or as fuel, total 

Coal tar consumed at coke-oven plants for roads and upkeep"*" 

Coal tar, water-gas tar, and oil-gas tar processed at tar refineries, crude tar 
consumed for upkeep at such refineries, and tar consumed in making gas and in 
special-purpose tar blends 



801,867 



762,904 



780,334 



746,590 



604,582 



594,621 



302,873 
301,709 

131,890 

26,432 



2,192 



24,240 



291,624 
302,997 

129,009 

22,960 



2,468 



20,492 



'■ Reported to the U.S. Bureau of Mines. 

Reported to U.S. Tariff Commission. Represents tar purchased from companies operating coke ovens and gas-retort 
plants and distilled by companies operating tar-distillation plants. 



Tar Crudes 

Tar crudes are obtained from coke-oven gas and by distilling coal tar, water-gas tar, and 
oil-gas tar. The most important tar crudes are benzene, toluene, xylene, naphthalene, creosote 
oil, and pitch of tar. Some of the products produced from coal tar are identical with those pro- 
duced from petroleum. Data for materials derived from petroleum are included, for the most 
part, with the statistics for materials derived from coal tar, which are shown in tables 3 and 
4A.^ 



See also table 4B, pt. 111, which lists these products and Identifies the manufacturers. 



2 SYNTHETIC ORGANIC CHEMICALS, 1967 

Domestic production of industrial and specification grades of benzene reported by coke-oven 
operators and petroleum refinery operators^ in 1967 amoionted to 969 million gallons--1.5 per- 
cent more than the 955 million gallons reported for 1966. These statistics include data for 
benzene produced from light oil and petroleum. Sales of benzene by coke-oven operators and 
petroleum operators in 1967 amounted to 564 million gallons, valued at $135 million, compared 
with 606 million gallons, valued at $147 naillion, in 1966. In 1967 the output of toluene^ (including 
material produced for use in blending in aviation fuel) amounted to 644 million gallons-- 10. 3 
percent more than the 584 million gallons reported for 1966. Sales of toluene in 1967 were 385 
million gallons, valued at $72 million, compared with 361 million gallons, valued at $62 million, 
in 1966. The output of xylene^ in 1967 (including that produced for blending in nnotor fuels) was 
455 million gallons, compared with 329 million gallons in 1966. About 99 percent of the 455 mil- 
lion gallons of xylene produced in 1967 was obtained from petroleunn sources. 

Production of crude naphthalene in 1967 (including 377 million pounds of petroleum-de- 
rived naphthalene) amounted to 898 million pounds, compared with 848 million pounds in 1966. 
In 1967 the output of creosote oil for wood preservation was 126 million gallons (100-percent 
creosote basis), compared with 133 million gallons in 1966. Production of road tar in 1967 was 
50 million gallons, compared with 55 million gallons in 1966. 

Some of the products included in the statistics in table 4A are derived from other products 
for which data are also included in the table. The statistics, therefore, involve considerable 
duplication, and for this reason no group totals or grand totals are given. It is estimated that, 
after duplication has been eliminated insofar as possible, the net value of the output of these 
products and of tar burned as fuel was $597 million in 1967, compared with $552 million in 1966 
and $500 million in 1965. 

TABLE 3. --Tar and tar crudes.- Summary of U.S. production of specified products, average 1957-59, 

annual 1966 and 1967 

[Leaders are used where the reported data are accepted in confidence and may not be published 

or where no data were reported] 



Chemical 



Unit 

of 
quantity 



Average 
1957-59 



1966 



1967 



Increase, or decrease (-) 



1976 over 
1957-59 



1967 over 
1966 



Percent 



Percent 



Tar^ 

Benzene: 

Tar distillers^ 

Coke-oven operators 

Petroleum operators 

Total 

Toluene : 

Tar distillers 

Coke-oven operators 

Petroleum operators 

Total 

Xylene : 

Tar distillers 

Coke-oven operators 

Petroleum operators 

Total 

Naphthalene : 

Crude* 

Petroleum naphthalene, all grades — 

Total 

Creosote oil fDead oil):^ 

Distillate as such (1005^ creosote 

basis) 

Creosote content of coal-tar 

solution (lOOjii creosote basis) 

Total 



1,000 gal-- 

1,000 gal-- 
1,000 gal— 
1,000 gal-- 
1,000 gal-- 

1,000 gal-- 
1,000 gal-- 
1,000 gal-- 
1,000 gal — 

1,000 gal-- 
1,000 gal— 
1,000 gal— 
1,000 gal-- 



760,816 

27,130 
139,121 
155,694 



301,867 



113,932 

841,340 



780,334 



90,642 
878,704 



2.6 



-34.8 
464.4 



-2.7 



-20.4 
4.4 



321,945 

4,162 

31,007 

204,421 



955,272 



22,791 
561,103 



239,590 

795 

8,908 

180,021 



583,894 



6,124 
^322,560 



969,346 



19,357 
624,454 



201.1 



-37.6 
205.5 



1.5 



-15.1 
11.3 



643,811 



5,488 
^449,349 



168.7 



-38.4 
149.6 



10.3 



-10.4 
39.3 



1,000 
1,000 
1,000 



lb- 
lb— 
lb— 



189,724 
396,882 



1,000 gal- 

1,000 gal- 
1,000 gal- 



396,882 

90,913 
14,172 



328,684 

493,634 
354,068 



454,837 

520,991 
376,679 



139.7 
31.3 



38.4 



5.5 
6.4 



105,085 



847,702 

114,725 
18,141 



132,866 



897,670 



108,832 



17,402 



126.2 

19.7 
22.8 



5.9 

-5.1 
-4.1 



126,234 



20.1 



-5.0 



^ Includes data for oil-gas, water-gas, and gas-retort tar reported to the American Gas Association for 1957-59 
only, and for coal tar reported to the Division of Bituminous Coal, U.S. Bureau of Mines. 

^ Includes data for benzene produced from imported crude light oil. 

^ Includes data for material produced for use in blending motor fuels. Statistics are not comparable with monthly 
figures, which included some o-xylene (see table 7A) . 

* Naphthalene solidifying at less than 79°C. Figures include production by tar distillers and coke-oven operators 
and represent combined data for the commercial grades of naphthalene to avoid disclosure of the operations of indi- 
vidual companies. Because of conversion between grades, the figures may include some duplication. 

^ Includes data for creosote oil produced by tar distillers and coke-oven operators and used only in wood preserv- 
ing. 



Statistics on production and sales of benzene, toluene, and xylene by tar distillers cannot be shown because publication would reveal 
the operations of individual companies. 



TAR CRUDES 



TABLE 4A. --Tar crudes: U.S. production and sales , 1967 



[Listed below are all tar crudes for which any reported data on production or sales may be published. (Leaders are 
used where the reported data are accepted in confidence and may not be published or where no data were reported.) 
Table <VB in pt. Ill lists separately all products for which data on production or sales were reported and iden- 
tifies the manufacturers reporting to the U.S. Tariff Commission] 



Product 



Unit 

of 

quantity 



Production 



Sales 



Quantity 



Value 



Unit 
value-"- 



Crude light oil: Coke-oven operators 

Intermediate light oil: Coke-oven operators 

Light-oil distillates: 

Benzene, specification and industrial grades, 

total^ ^ 

Coke-oven operators 

Petroleum operators 

Toluene, all grades, total^ ^ 

Coke-oven operators 

Petroleum operators 

Xylene, all grades, total^ ^ 

Coke-oven operators 

Petroleum operators 

Solvent naphtha:^ Coke-oven operators 

All other light-oil distillates, total 

Coke-oven operators 

Tar distillers^ 

Naphthalene, crude (tar distillers and coke-oven 

operators), total' 

Solidifying at-- 

Less than 11,° C 

1^° C. to less than 79° C 

Crude tar-acid oils:^ Coke-oven operators 

Creosote oil (Dead oil) (tar distillers and coke- 
oven operators) (100/t creosote basis), total*^- 

Distillate as such (lOOjt creosote basis) 

Creosote content of coal-tar solution (100^ 
creosote basis ) 

All other distillate products, total' 

Coke-oven operators 

Tar distillers 

Tar, road 

Tar (crude and refined) for other uses"""" 

Pitch of tar (coke-oven operators and tar distil- 
lers ) : 

Hard ^water softening point above 160° F. ) 

Other^^ 



,000 gal- 
,000 gal- 



,000 gal- 

000 gal- 

,000 gal- 

,000 gal- 

,000 gal- 

,000 gal- 

,000 gal- 

,000 gal- 

,000 gal- 

,000 gal- 

000 gal- 

,000 gal- 

,000 gal- 



1,000 lb— 

1,000 lb— 
1,000 lb— 

1,000 gal-- 



1,000 gal- 
1,000 gal- 

1,000 gal- 

1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 
1,000 gal- 



1,000 tons 
1,000 tons 



252,138 
5,558 



969,3<;6 

90,642 

878,704 

643,811 

19,357 

624,454 

454,837 

5,488 

449,349 

3,633 

10,681 

8,397 

2,284 



520,991 



94,504 
1,566 



563,867 

88,169 

475,698 

384,550 

18,619 

365,931 

274,419 

5,763 

268,656 

2,558 

4,327 

2,068 

2,259 



302,593 



1.000 
dol lars 
13,229 
127 



135,240 

20,941 

114,299 

71,897 

3,693 

68,204 

49,887 

■'1,239 

48,648 

411 

763 

239 

524 



13,081 



84,202 
436,789 

28,089 



126,234 



108,832 
17,402 



27,565 



116,184 



4,514 



'24,788 



3,241 

50,059 
9,408 



98,824 

17,360 
14,229 



941 
935 



3,192 
11,037 
50,688 

9,406 



701 
427 



19,766 

'5,022 

2,531 



323 
2,208 
6,887 
2,048 



26,800 
14,160 



.14 
.08 



.24 
.24 
.24 
.19 
.20 
.19 
.18 
.21 
.18 
.16 
.18 
.12 
.23 



.04 



.16 



■ 21 
.20 



.29 
.18 



.10 
.20 
.14 
.22 



38.23 
33.16 



■'■ Unit value per gallon, or ton, as specified. 

^ Data reported by tar distillers are not included because publication would disclose the operations of individual 
companies. Production of benzene and toluene by tar distillers decreased in 1967, compared with 1966; production 
of xylene increased. The annual production statistics for petroleum operators on benzene, toluene, and xylene are not 
comparable with the combined monthly production figures, due to fiscal year revisions. 

^ Includes data for material produced for use in blending motor fuels . 

* Revised. 

^ Includes solvent naphtha and rubber-reclaiming oils. 

' Statistics represent combined data for the commercial grades of naphthalene. Because of conversion of naphtha- 
lene from one grade to another, the figures may include some duplication. 

'' Statistics include only data for creosote oil sold for, or used in, wood preserving. In 1967, production of 
creosote in coal-tar solution (100^ solution basis) amounted to 27,420 thousand gallons; sales were 27,355 thousand 
gallons, valued at 5,022 thousand dollars, with a unit value of $0.18 per gallon. 

' Includes value of coal tar used in preparing creosote in coal-tar solution. 

Includes data for pyridine crude bases, crude cresylic acid, and neutral oil produced by tar distillers, and for 
crude sodium phenolate produced by coke-oven operators. 
''° Includes data for tar used for paint, pipe covering, saturating, and other uses. 

"■^ Includes soft and medium pitch of tar (water softening points less than 110° F., and 110° F. to 160° F.), pitch 
of tar coke, and pitch emulsion. 

Note. — Statistics for materials produced in coke and gas-retort ovens are compiled by the Division of Bituminous 
Coal, U.S. Bureau of Mines, Department of the Interior. Statistics for materials produced in tar and petroleum re- 
fineries are compiled by the U.S. Tariff Commission. 



4 SYNTHETIC ORGANIC CHEMICALS, 1967 

Crude Products from Petroleum and Natural Gas for Chemical Conversion 

Crude products that are derived from petroleum and natural gas^ are related to the interme- 
diates and finished products nnade from such crudes in much the same way that crude products 
derived fronn the distillation of coal tar are related to their intermediates and finished products. 
Many of the crude products derived from petroleum are identical with those derived fronn coal 
tar (e. g. , benzene, toluene, and xylene). Considerable duplication exists in the statistics on the 
production and sales of petroleum crudes because some of these crude chemicals are converted 
to other crude products derived from petroleum and because data on some production and sales 
are reported at successive stages in the conversion processes (table 5A ). Notwithstanding these 
duplications, the statistics are sufficiently accurate to indicate trends in the industry and to serve 
as a basis for general comparison. Many of the crude products for which data are included in the 
statistics may be used either as fuel or as basic materials from which to derive other chemicals, 
depending on prevailing economic conditions; but in this report every effort has been made to 
exclude data on materials that are used as fuel. However, data are included on toluene and xylene 
which are not used directly as fuel but in blending aviation and motor-grade gasolines. 

The output of crude products derived from petroleum and natural gas as a group amounted to 
54,438 million pounds in 1967, or 7.9 percent more than the 50,467 million pounds reported for 
1966, The larger output in 1967 is accounted for chiefly by increased production of propylene, 
xylenes, ethylene, toluene, and benzene. Sales of crude chemicals from petroleum in 1967 
amounted to 29,453 million pounds, valued at $858 million, compared with 27,494 million pounds, 
valued at $865 million, in 1966. 

The output of aromatic and naphthenic products from petroleum amounted to 16,455 million 
pounds in 1967, compared with 14, 799 million pounds in 1966. Sales in 1967, which amounted to 



TABLE 5A.- 



■Crude products from petroleum and natural gas for chemical conversion; U.S. production 

and sales, 1967 



[Listed below are the crude products from petroleum and natural gas for chemical conversion for which any reported 
data on production or sales may be published, (Leaders are used where the reported data are accepted in confidence 
and may not be published or where no data were reported.) Table 5B in pt. Ill lists separately all products from 
petroleum and natural gas for chemical conversion for which data on production or sales were reported and identi- 
fies the manufacturer of each] 



Product 



Production 



Sales 



Quantity 



Sales 



Unit 
value ■"■ 



Grand total 

AROMATICS AND NAPHTHENES^ 

Total 

Benzene (1° and 2° ) , total 

Benzene, 1° 

Benzene, 2° 

Naphthalene, all grades 

Naphthenic acids, total 

Acid number 150-199 

All other 

Toluene, all grades, total 

Nitration grade, 1° 

Pure commercial grade, 2 

Solvent grade, 90?S 

All other^ 

Xylenes, mixed, total 

Xylene, -f 

All other^ 

All other aromatics and naphthenes* 

See footnotes at end of table. 



1 , QUO 
pound s 
5^,438,232 



16,-;55,333 



6,';84,836 



5,597,280 
887,556 

376,679 

2-^,498 



6,355 
18,143 

■4,539,781 



2,846,896 
600,400 
131,013 
961,472 

3,239,807 



934,106 
2,305,701 

1,789,732 



1 . UOO 

pound s 

29,453,233 



9,952,387 



3,510,651 



280,920 
12,771 



2,660,318 



1,794,876 

272,712 

79,897 

512,833 

1,937,010 



895,648 
1,041,362 

1,550,717 



1 , 000 
dollars 
858,071 



266,556 



114,299 



13,772 
1,330 



68,204 



48,093 
6,311 
1,851 

11,949 

48,648 
21,478 
27,170 

20,303 



Pe 

pound 



$0,029 



.027 



.033 



.049 
.104 



.026 



.027 
.023 
.023 
.023 

.025 



.024 
.026 



.013 



Statistics on aromatic chemicals from coal tar are given in table 4A, (Tar Crudes: U.S. production and sales, 1967). 
See also table 5B, pt. 111, which lists these products and identifies the manufacturers. 



CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS 



TABLK 5A.— Crude products from petroleum and natural gas for chemical conversion: U.S. production 

and sales, 1967 — Continued 



Product 



ALIPHATIC HYDROCARBONS 



Total- 



C2 hydrocarbons, total- 
Acetylene' 

Ethane 

Ethylene 



C3 hydrocarbons, total 

Propane 

Propane -propylene mixture - 
Propylene 



C4 hydrocarbons, total 

1,3-Butadiene, grade for rubbers (elastomers) 



Butadiene and butylene fractions- 

n-Butane 

1-Butene 

1-Butene and 2-butene mixture ''- 

Isobutane 

Isobuty lene 

All other^ 



C5 hydrocarbons, total- 

Isoprene 

n-Pentane 

All other' 



All other aliphatic hydrocarbons and derivatives, 

Alpha olefins^" 

Dilsobutylene (Diisobatene) 

Heptenes, mixed 

Hexane 

Nonene (Tripropylene) 

Polybutene^ 

Te t rapropy lene 

Hydrocarbon derivatives'"'^ 

All other^^ 



total — 



Production 



Sales 



Quantity 



1 . 000 

pounds 

37,982,899 



13,SA1,36A- 



<l29,<i6<i 

1,557,385 

11,85^,515 

10,512,7-;3 



i, 123, 574 

617,35-i 

5,771,815 

8,226,160 



2,660,273 
89<;,218 

2,031,069 
^11,053 

1,391,717 
6<;8,569 

559,261 

78i,<i29 



196,302 

"4,989 

583,138 

■4,618,203 



328,83<i 

288,158 
212,187 
286,278 
176,176 
'433,903 
34,140 
2,858,527 



1 . 000 
pounds 
19,500,846 



848,799 
3,353,371 

7,129,438 



3,903,796 

^3,225,642 

5,156,664 



1,620,806 
238,578 

1,384,780 
36,060 

1,125,019 
300,286 
168,816 
282,319 

158,778 



27,605 

4,960 

126,213 

2,853,796 



Value 



1 . 000 
dollar s 
591,515 



7,013 
132,560 

115,428 



49,431 
'65,997 
231,759 



154,266 

6,997 
15,149 

1,918 
31,856 

4,078 
11,481 

6,014 

6,194 



234,156 

35,033 

195,828 

203,439 

158,861 

251,887 

21,674 

1,752,918 



3,884 

223 

2,087 

98,561 



Unit 
value'' 



Pe 
pound 



$0,030 



.008 
.040 



.016 



.013 



.020 



.045 



12,120 
1,837 
7,665 

7,010 

12,534 

8,326 

5,717 

43,352 



.095 
.029 
.011 
.053 
.028 
.014 
.068 
.021 

■ 039 
.141 
.045 
.016 

.034 



.052 
.052 
.039 

.034 
.079 
.033 
.264 
.025 



^ Calculated from rounded figures. 

^ The chemical raw materials designated as aromatics are in some cases identical with those obtained from the dis- 
tillation of coal tar; however, the statistics given in the table above relate only to such materials as are derived 
from petroleum and natural gas. Statistics on aromatic chemicals from all sources are given in table 4A, "Tar Crudes." 
^ Includes toluene and xylene used as solvents, as well as that which is blended in aviation and motor gasolines. 
* Includes data for 90-percent benzene, crude cresylic acid, crude sodium carbolate and phenate, alkyl aromatics, 
distillates, solvents, and miscellaneous cyclic hydrocarbons. 

' Production figures on acetylene from calcium carbide for chemical synthesis are collected by the U.S. Bureau of 
the Census. 

'' Includes data for a small amount of propane -propylene mixture. 

' The statistics represent principally the butene content of crude refinery gases from which butadiene is manu- 
factured. 

' Includes data for 2-butene, mixed butylenes, and mixed olefins. 
' Includes data for pentanes, pentenes, and C5 hydrocarbon mixtures. 
''•° Includes data for the following molecular weight ranges; C6-C7; Cj-Cio; C11-C15; C16-C20; and C16-C30. 
■'''' Includes compounds having a molecular weight of 3,000 or less. 

Includes data for tert-butylene mercaptan, di-tert-butyldisulfide and miscellaneous mercaptans. 
^^ Includes data for ethane-ethylene mixture, heptane, methane, octanes, n-paraffins, and hydrocarbon mixtures. 

9, 952 million pounds, valued at $267 nnillion, were 77 million pounds smaller, cind valued at $6 
million more, than those in 1966. Naphthalene was produced from petroleum sources in sub- 
stantially greater quantities in 1967 than in 1966. The output of 1° and 2° benzene from petroleum 
amounted to 6,485 million pounds in 1967--4,4 percent more tham the 6,209 million pounds pro- 
duced in 1966. The output of toluene in 1967 was 4, 540 million pounds--11.3 percent more than 
the 4, 079 million pounds produced in 1966. Production of xylene was 3,240 million pounds in 
1967, compared with 2,326 million pounds in 1966, These figures include toluene and xylene used 
in blends in aviation and motor-grade gasolines. The output of naphthenic acids amounted to 24.5 
million pounds in 1967, about the same as that produced in 1966. 



^ SYNTHETIC ORGANIC CHEMICALS, 1967 

Production of all aliphatic hydrocarbons and derivatives from petroleunn and natural gas was 
37,983 million pounds in 1967, compared with 35,668 million pounds in 1966. Sales of these pro- 
ducts were 19,501 million pounds, valued at $592 million, in 1967, compared withl7,465 
million pounds, valued at $605 million, in 1966, The statistics on production of acetylene (table 
5A) include only acetylene produced fronn hydrocarbons and used as a raw material in the pro- 
duction of other chemicals. Total production of acetylene for chemical synthesis is reported to 
the U.S. Bureau of the Census. In 1967, production of acetylene from hydrocarbon sources, 
announted to 429 million pounds. Production of ethylene was 11,855 million pounds in 1967--5.5 
percent more than the 11,241 million pounds produced in 1966. The output of propylene was 
5,772 million pounds in 1967--23.4 percent more than the 4,677 million pounds produced in 
1966. Production of 1 , 3-butadiene, one of the principal ingredients of S-type synthetic rubber, 
was 2, 660 million pounds in 1967, compared with 2, 922 million pounds in 1966. The output of 
1, 3-butadiene in 1966 was the largest on record. 

The following tabulation shows the number of companies that reported production of organic 
chemical crudes in 1967: 

Number of companies 
and 
Chemical group company divisions 

Tar crudes 13 

Petroleum crudes 71 



PART II. PRODUCTION AND SALES OF INTERMEDIATES AND FINISHED SYNTHETIC 

ORGANIC CHEMICALS, BY GROUPS 

General 

On the basis of their principal uses, the synthetic organic chemicals covered in this report 
are classified either as intermediates or as finished products. Finished products, in turn, are 
grouped as follows: Dyes, synthetic organic pigments, medicinal chemicals, flavor and perfume 
materials, plastics and resin materials, rubber-processing chemicals, elastomers (synthetic 
rubbers), plasticizer s, surface-active agents, pesticides and related products, and miscellane- 
ous synthetic organic chemicals. Most of these groups are further subdivided, according to 
chemical classes, into cyclic and acyclic compounds. As most of the inter nnediates are used in 
the manufacture of finished products, aggregate figures that cover both intermediates and finished 
products necessarily include considerable duplication. 

Total production of synthetic organic chemicals (intermediates and finished products com- 
bined) in 1967 was 104,711 million pounds, or 4,1 percent more than the output of 100,627 mil- 
lion pounds reported for 1966 (see table 6). Sales of synthetic organic chemicals in 1967 amounted 
to 55, 177 million pounds, valued at $10,438 million, compared with 52,720 million pounds, 
valued at $9, 958 million, in 1966. Production of all cyclic products (intermediates and finished 
products combined) in 1967 totaled 33,479 million pounds, or 4.2 percent more than the 32, 133 
nnillion pounds produced in 1966. The output of acyclic orgcinic chemicals in 1967 amounted to 
71,232 million pounds-- 4.0 percent more than the 68,494 million pounds reported for 1966. 



TABLE 6. — Synthetic organic chemicals : Summary of U.S. production and sales 0/ intermediates and finished 

products, average 1957-59, annual 1966 and 1967 

[Production and sales in thousands of pounds; sales value in thousands of dollars] 



Chemical 



Average 
1957-59 



1966 



1967 



Increase, or decrease (-) 



1967 over 
1957-59 



1967 over 
1966 



Organic chemicals, cyclic and acyclic, 
grand total: 

Production 

Sales 

Sales value 

Qyclic, total : 

Production 

Sales 

Sales value 

Acyclic, total: 

Production 

Sales 

Sales value 

1. Intermediates, Cyclic 

Production 

Sales 

Sales value 

2. Dyes, Cyclic 

Production 

Sales 

Sales value 

3. Synthetic Organic Pigments, Cyclic 

Production 

Sales 

Sales value 



45,598,853 

23,7^,812 

5,743,76-4 



14,381,651 
8,829,037 
2,785,100 



31,217,202 

14,915,775 

2,958,664 



7,343,167 

2,919,264 

481, 920 



150,830 
141,731 
182, 513 



38,603 
30,218 
58,648 



100, 626, 696 

52,719,594 

9,958,383 



32,132,902 

18,867,433 

4,328,963 



68,493,794 

33,852,161 

5,629,420 



19,466,775 

8,852,033 

925,092 



219,194 
204,135 
331,453 



51,128 

43,316 

107, 594 



104,711,357 
55,176,823 
10,438,453 



33,479,469 

19,328,628 

4,610,293 



71,231,888 

35,848,195 

5,828,160 



20,793,132 
9,461,180 
1,000,359 



206,240 
198, 592 
332,049 



53,322 

42,867 

108,354 



Percent 

129.6 

132.4 

81.7 



132.8 

118.9 

65.5 



128.2 

140.3 

97.0 



183.2 
224.1 
107.6 



36.7 
40.1 
81.9 



38.1 
41.8 
84.8 



Percent 



4.1 
4.7 
4.8 



4.2 
2.4 
6.5 



4.0 
5.9 
3.5 



6.8 
6.9 
8.1 



-5.9 

-2.7 

.2 



4.3 

-1.0 

.7 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 6. Synthetic organic chemicals.- Summary of U.S. production and sales of intermediates and finished 

products, average 1957-59, annual 1966 and 1967 — Continued 

[Production and sales in thousands of pounds; sales value in thousands of dollars] 



Chemical 



Average 
1957-59 



1966 



1967 



Increase, or decrease (-) 



1967 over 
1957-59 



1967 over 
1966 



'i. Medicinal Chemicals 
Cyclic: 

Production 

Sales 

Sales value 

Acyclic; 

Production 

Sales 

Sales value 

5. Flavor and Perfume Materials 

(Cyclic: 

Production 

Sales 

Sales value 

Acyclic : 

Production 

Sales 

Sales value 

6. Plastics and Resin Materials 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic : 

Production 

Sales 

Sales value 

7. Rubber-Processing Chemicals 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 

8. Elastomers (Synthetic Rubbers) 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 

9. Plasticizers 

Cyclic: 

Production 

Sales i 

Sales value 

Acyclic : 

Production 

Sales 

Sales value 



70,654 

54,151 

535,297 

31,592 
28,738 
35,660 



27,312 
22,446 
33,903 

19,033 
19,958 

21,912 



2,278,862 

1,900,032 
518, 501 

2,628,779 

2,438,853 

864, 523 



159, 182 

115,704 

74,479 

29,150 
22,127 
14,289 



1,938,732 

1,726,757 

404,897 

521,811 
509,262 
199, 627 



348,210 

297,423 

83,509 

118,118 

100, 984 

38,772 



116,164 

76,842 

356,646 

69,305 
59,621 
41,762 



61,406 
49, 597 
60,915 

49,264 
48,717 
31,719 



5,066,571 

4,254,211 

988,001 

8,518,301 
7,217,427 
1,752,080 



241,248 
182,790 
123,581 

42,087 
26,495 
14,622 



2,482,375 

2,108,089 

463,222 

1,446,812 

1,303,169 

454,796 



897,249 
873,109 
156, 967 

311,742 

282,577 

89, 034 



110,129 

70,120 

348,873 

69,941 
56,804 
36,402 



57, 978 
47,285 
52,866 

53,558 
49,311 
40,495 



5,033,497 
4,224,121 
1,036,940 

8,759,452 
7,753,242 
1,635,690 



220,139 
169, 970 
116,318 

43,994 
30,878 
15,477 



2,297,637 

1,940,099 

439,580 

1,524,908 

1,321,945 

434,657 



929, 871 
865,084 
167,827 

332,908 

296,767 

93,142 



Percent 

55.9 

(^) 

121.4 



112.3 

110.7 

55.9 

181.4 

147.1 

84.8 



120.9 
122.3 
100.0 

233.2 

217.9 

89.2 



38.3 
46.9 
56.2 

50.9 

39.5 

8.3 



18.5 

12.4 

8.6 

192.2 

159.6 

117.7 



167.0 
190.8 
101.0 

181.8 
193.9 
140.2 



See footnote at end of table. 



GENERAL 9 

TABLE G.—Synthetic organic chemicals: Summary of U.S. production ami sales of intermediates and finished 
products, average 1957-59, annual 1966 and 1967 — Continued 

[Production and sales In thousands of pounds; sales value in thousands of dollars] 



Chemical 



Average 
1957-59 



1966 



1967 



Increase, or decrease (-) 



1967 over 
1957-59 



1967 over 
1966 



10, Surface-Active Agents 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic; 

Production 

Sales 

Sales value 



11. Pesticides anil related products 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 



12. Miscellaneous 



Cyclic: 

Production- - 

Sales 

Sales value- 
Acyclic : 

Production-- 

Sales 

Sales value- 



852, 3 U 
800, 432 
127,936 

502,715 
432,135 
113,215 



440,384 
375,627 
150,837 

105,080 
91,938 
49,049 



733,401 
445,252 
132,660 

27,260,924 

11,271,780 

1,621,617 



1,385,217 

879,235 

97, 187 

1,936,100 
886,818 
217,726 



776, 909 
605,229 
446,946 

236,201 
217,027 
136,856 



1,368,666 
738,847 
271,359 

55,883,982 

23,810,310 

2,890,825 



1,418,444 

852,238 

95,810 

2,060,851 
897,786 
220,877 



823,158 
681,532 
627,742 

226,505 
215,831 
159,301 



1,535,922 
775, 540 
283,575 

58,159,771 

25,225,631 

3,192,119 



Percent 

66.4 



86.9 

81.4 

316.2 

115.6 
134.8 
224.8 



109.4 

74.2 

113.8 

113.3 

123.8 

96.8 



Percent 



2 


4 


-3 


1 


-1 


4 


6 


4 


1 


2 


1 


4 



6.0 
12.6 
40.4 

-4.1 

-.6 

16.4 



12.2 
5.0 
4.5 

4.1 
5.9 

10.4 



■■■Data for 1967 are not comparable with those for average 1957-59. 

The following tabulation shows, by chemical groups, the number of companies that reported 
production in 1967 of one or more of the chemicals included in the groups listed in table 6: 



Number 
Chemical group of 

companies 

Intermediates 220 



Number 

Chemical group of 

companies 

Rubber-processing chemicals 32 



Dyes 50 

Synthetic organic pigments 34 

Medicinal chemicals 108 

Flavor and perfume materials 54 

Plastics and resin materials 291 



Elastomers (synthetic rubbers) 

Plastlcizers 

Surface-active agents 



31 

57 

213 



Pesticides and related products 90 

Miscellaneous chemicals 330 



10 



SYNTHETIC ORGANIC CHEMICALS, 1967 



Cyclic Intermediates 

Cyclic intermediates are synthetic organic chemicals derived principally from coal-tar 
crudes produced by destructive distillation (pyrolysis) of coal and from petroleum and natural 
gas. Most cyclic intermediates are used in the manufacture of more advanced synthetic organic 
chemicals andfinished products, such as dyes, medicinal chemicals, elastomers (synthetic 
rubbers), pesticides, and plastics and resin materials. Some intermediates, however, are sold 
as end products without further processing. For example, refined naphthalene may be used as a 
raw material in the manufacture of 2-naphthol or of other more advanced intermediates, or it may 
be packaged and sold as a moth repellent or as a deodorant. In 1967 nearly half of the total out- 
put of cyclic intermediates was sold; the rest was consumed chiefly by the producing plants in the 
manufacture of more advanced intermediates and finished products. 

Total production of cyclic intermediates in 1967--20, 793 million pounds--was the largest on 
record, and was 6. 8 percent larger than the output of 19, 467 million pounds reported for 1966. 
The larger output of cyclic intermediates in 1967 was attributable to increased demand by the 
chemical products industries, particularly those industries that produce pesticides, pigments, 
and plasticizers , and to an increase in exports. Sales of cyclic intermediates in 1967 amounted to 
9,461 million pounds, valued at $1,000 million, compared with 8,852 million pounds, valued at 
$925 nnillion, in 1966. In terms of quantity, sales of cyclic intermediates in 1967 were 6. 9 per- 
cent larger than those in 1966 and in terms of value, 8. 1 percent larger. 

Production of ethylbenzene was 3, 347 million pounds in 1967, or 3.2 percent larger than the 
3, 245 million pounds reported for 1966. Output of styrene in 1967 was 3, 278 million pounds, an 
increase of 2. 7 percent over the 3, 192 million pounds in 1966. Other intermediates whose pro- 
duction exceeded 1 billion pounds in 1967 were cyclohexane (1, 777 million pounds), phenol 
(1, 356 million pounds), and cumene (1, 134 million pounds). The output of other large-volume 
intermediates in 1967 compared with production in 1966 was as follows: Terephthalic acid, 
dimethyl ester, 936 million pounds (17.4 percent larger than in 1966); p-xylene, 757 nnillion 
pounds (46. percent larger); phthalic anhydride, 727 million pounds (7. 7 percent larger); 
terephthalic acid, 694 million pounds (35.0 percent larger); alkylbenzenes, 684 million pounds 
(4. 3 percent smaller); o-xylene, 493 million pounds (22. 3 percent larger); and chlorobenzene, 
483 million pounds (16.2 percent smaller). Production of isocyanates amounted to 257 million 
pounds (15.0 percent larger than in 1966), and production of aniline was 226 million pounds, a 
decrease of 5. 6 percent from 1966. 

TABLE 7A. — Cyclic intermediates: U.S. production and sales , 1967 

[Listed below are all cyclic intermediates for which any reported data on production or sales may be published. 
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data were 
reported.) Table 7B in pt. Ill lists alphabetically all cyclic intennediates for which data on production or sales 
were reported and identifies the manufacturer of each] 



Chemical 



Production 



Sales 



Quantity 



Value 



Unit 
value ^ 



Total 

Acetanilide, tech 

o-Acetoacetanisidide 

Acetophenone, tech 

Alkylbenzenes^ 

■i'-Aminoacetanilide (Acetyl -p-phenylenediamine) 

5-Amino-2-(p-ajiiinoanilino)benzenesulfonic acid 

2-(p-Aminoanilino)-5-nitrobenzenesulfonic acid 

l-Aminoanthraquinone and salt 

2-Aininoanthraquinone and salt 

6-Amino-3,<i'-azodibenzenesulfonic acid (C.I. Acid Yellow 9) 

l-Amlno-4-benzamidoanthraquinone 

l-Amino-5-benzamidoanthraquinone 

2-Aniino-p-benzenedisulfonlc acid [S03H=1] 

l-Amino-4-brorao-9, 10-dlhydro-9,10-dioxo-2-anthracenesulfonic acid 

and sodium salt 

l-Amino-2-bromo-4-hydroxyanthraquinone 

l-Amino-2-bromo-'i-p-toluidinoanthraquinone 

See footnotes at end of table. 



i.mo 

pounds 
20,793, U2 



1.000 
pounds 

9,461,180 



1 .000 
dollars 

1,000,359 



5,540 

523 

1,773 

684,416 

590 

4 

18 

1,289 

738 

22 

37 

112 

26 

144 

208 

10 



1,191 
641,895 



287 
59,238 



Per 
pound 



.11 



.24 

.09 



CYCUC INTERMEDIATES I, 

TABLE 1A.--Cyclic intermediates: U.S. production and sales, i 56 7- -Continued 



Chemical 



l-Amino-5-chloroanthraquinone 

6-Amino-4-chloro-m-toluenesulfonlc acid [S03H=1] 

l-Amino-2,<i-dibronioanthraquinone 

i-Aniino-3-hydroxy-l-naphthalenesulfonio acid (1,2,'i-aoid) 

6-Amino-4-hydroxy-2-naphthalenesulfonio acid (Gamma acid), sodium 

salt 

7-Amino-4--hydroxy-2-naphthalenesulfonio acid (J acid), sodium 

salt 

N-('+-Amino-3-methoxy-l-anthraquinonyl)-p-toluenesulfonamide 

'i'-Amino-N-methylaoetanilide 

5-Amino-l,3-naphthalenedisulfonic acid (Amino I acid) 

7-Amino-l,3-naphthalenedisulfonic acid (Amino G acid) 

'*-Amino-l-naphthalenesulfonic acid (Naphthionic acid) 

5-Amino-2-naphthalenesulfonic acid (l,6-Cleve's acid) 

5(and 8)-Amino-2-naphthalenesulfonic acid (Cleve's acid, mixed) 

6-Amino-2-naphthalenesulfonic acid (Broenner's acid) 

8-Amino-l-naphthalenesulfonic acid (Peri acid) 

8-Amino-2-naphthalenesulfonic acid (l,7-Cleve's acid) 

2-Amino-5-nitrobenzenesulfonic acid [S03H=l] 

2-Amino-'i-nitrQphenol 

'i-Amino-'i'-nitro-2,2'-stilbenedisulfonie acid 

p-[(p-Aminophenyl)azo]benzenesulfonic acid 

^-Amino-m-toluenesulfonic acid [S03H=l] 

6-Amino-m-toluenesulfonio acid [SOjH^l] 

Aniline (Aniline oil) 

7-Anilino-'i-hydroxy-2-naphthalenesulfonic acid (Phenyl J acid) 

Anilinomethanesulfonic acid and salt 

8-Anilino-l-naphthalenesulfonic acid (Phenyl peri acid) 

o-Anisidine 

o-Anisidinomethanesulfonic acid 

Anthra [l,9-cd]pyrazol-6(2H)-one ( jyrazoleanthrone ) 

N, N'-(l,5-Anthraquinonylene)dianthraniliG acid 

Benzaldehyde, tech 

l-Benzamido-5-chloroanthraquinone 

7H-Benz[de]anthracen-7-one (Benzanthrone) 

l,2,'i,5-Benzenetetracarboxylic-l,2:<i,5-dianhydride 

Benzoic acid, tech 

2-Benzothiazolethiol (2-Mercaptobenzothiazole), sodium salt 

o-Benzoylbenzoic acid 

[3,3'-Bianthra[l,9-cd]pyrazole]-6,6'-(2H,2'H)dione (Pyrazole- 

anthrone yellow) 

I 4,4' -Bi-7H-benz [de] anthracene ]-7, 7' -dione 

l,'i-Bis[l-anthraquinonylamino] anthraquinone 

4,'>'-Bis[dijnethylamino]benzophenone (Michler's ketone) 

3-Bromo-7H-benz[de] anthracen-7-one (3-Broraobenzanthrone) 

l-Brono -4- (me thylamino) anthraquinone 

6-Brano-3-methyl-7H-dibenz[f,ij]isoquinoline-2,7-(3H)-dione 

1-Chloroanthraquinone 

2-Chloroanthraquinone 

Chlorobenzene, mono- 

o-(p-Chlorobenzoyl)benzoic acid 

1 -Chloro-2 , 4 -dini trobenzene ( Dini trochlorobenzene ) 

6-Chlorometanilic acid 

l-Chloro-2-methylanthraquinone 

2-Chloro-'i-nitroaniline (o-Chloro-p-nitroaniline) 

'V-Chloro-2-nitroaniline (p-Chloro-o-nitroaniline) 

l-Chloro-5-nitroanthraquinone 

l-Ghloro-2 -nitrobenzene (Chloro-o-ni trobenzene) 

l-Chloro-'V-ni trobenzene (Chloro-p-nitrobenzene) 

'i-Chloro-3-nitrobenzenesulfonamide 

2-Chloro-5-nitrobenzenesulfonic acid and sodium salt 

'4-Chloro-3-nitrobenzenesulfonyl chloride 

o-('4-Chloro-3-nitrobenzoyl)benzoic acid 

a-Chlorotoluene (Benzyl chloride) 

[ (<i-Chloro-o-tolyl)thio]acetic acid 

Cinnamoyl chloride 

See footnotes at end of table. 



Production 



l.nnn 

pounds 

78 

1,081 

333 

459 

278 

488 

20 

21 

807 

637 

141 

65 

53 

115 

134 

98 

33 

102 

145 

217 

239 

399 

225,556 

58 

321 

225 

2,279 

442 

32 

22 

4,475 

112 

1,754 

22,339 

23,160 

5,107 

24 

523 

99 

75 

163 

53 

5 

184 

793 

483,294 

933 

6,257 

17 

225 

275 

503 

84 

34,226 

101,508 

420 

368 

553 

147 

66,390 

58 

86 



Sales 



Quantity 




1 /m 

pounds 



263 



l.non 

dollars 



313 



Unit 
value ^ 



Per 
pound 



$1.19 



209 
117,627 



755 



338 

56 

10,173 



67,857 
1,768 



221 
463 

12,402 



10,789 



192 
12,799 



549 



450 

239 

1,762 



4,145 
272 



206 
379 



951 



1,927 



.92 
.11 



.73 



1.33 

4.27 

.17 



.06 
.15 



.93 
.82 

.08 



.18 



12 



SYNTHETIC ORGANIC CHEMICALS, 1967 
TABLE 7A. — Cyclic intermediates: U.S. production and sales , i567--Continued 



Chemical 



Production 



Sales 



Quantity 



Value 



Unit 
value -■■ 



Cresols, total-' 

o-Cresol 

(m,p)-Cresol 

All other* 

Cresylic acid, refined-' 

Cumene 

Cyolohexane 

Cyclohexanol 

Cyclohexanone 

Cyclohexylamine 

1,'i-Dlaininoanthraquinone 

2,6-Diaminoanthraquinone 

l,<i-Diajnino-2,3-dihydroanthraquinone 

'i,<4'-Diamino-2,2'-stilbenedisulfonic acid 

^,5'-Dibenzamido-l,l'-iminodianthraquinone 

1,5-Dibenzoylnaphthalene ■• 

3,9-Dibrcmo-7H-benz[de]anthracen-7-one 

1,5-Dichloroanthraquinone 

o-Dichlorobenzene 

p-Dichlorobenzene 

3,3'-Dichlorobenzidine base and salts 

2,5-Dichloro-'i-(3-methyl-5-oxo-2-pyTazolin-l-yl)benzenesulfonic 

acid 

l,'i-Dichloro-2 -nitrobenzene (Nitro-p-diohlorobenzene) 

2,5-Dichlorosulfanilio acid [S03H=l] 

Dicyclopentadiene (includes cyclopentadiene) 

p-(Diethylamino)benzaldehyde 

N,N-Diethylaniline 

9,10-Dihydro-9,10-dioxo-l,8-anthracenedisulfonio acid, potassium 

salt 

9,10-Dihydro-9,10-dioxo-2,6-anthracenedisulfonic acid and salt — 
9,10-Dihydro-9,10-dioxo-l-anthracenesulfonic acid and salt 

(Gold salt) — 

9,10-Dihydro-5-nitro-9,10-dioxo-l-anthracenesulfonic acid 

Ij'l-Dihydroxyanthraquinone (Quinizarin) 

1,5-Dihydroxyanthraquinone (Anthrarufin) 

2,6-Dihydroxyanthraquinone (Anthraflavic acid) 

l,5-Dihydroxy-<+,8-dinitroanthraquinone 

l,8-Dil^droxy-A,5-dinitroanthraquinone ('i,5-Dinitrochrysazin) 

16,17-Dihydroxyviolanthrone (Dihydroxydibenzanthrone) 

3,3'-Dimethoxybenzidine (o-Dianisidine) 

N,N-Dimethylaniline 

N,N-Dimethylbenzylamine 

2,4-Dinitroaniline 

2,'l-Dinltrophenol, tech 

'i,"i'-Dinitrostilbene-2,2'-disulfonic acid 

Diphenylamine 

1,'4-Di-p-toluidinoanthraquinone 

Divinylbenzene 

p-Dodecylphenol 

N-Ethylaniline, refined 

a-(N-Ethylanilino) -p-toluenesulfonio acid 

Ethylbenzene^ 

N-Ethyl-N-phenylbenzylamlne 

3-(N-Ethyl-m-toluidino)propionitrile 

Hydroquinone, tech 

p-}^droxybenzenesulfonic acid 

4-Hydroxymetanilamide 

-i-Itydroxymetanilio acid 

3-Hydroxy-2,7-naphthalenedisulfonic acid, disodium salt 

6-Ifydroxy-2-naphthalenesulfonic acid and sodium salt 

N-(7-lfydroxy-l-naphthyl)acetamlde 

1,1' -Iminobis[/+-aminoanthraquinone] 

1,1' -Iminobis[ 5-benzamidoanthraquinone] 



1.000 

pounds 

78,068 



16, 9« 
35,972 
25,151 

«,386 
l,13<i,334 
1,776,620 

i29,'i57 

11,571 

47 

193 

500 

8,523 

149 

330 

367 

106 

50,366 

66,482 

3,025 

389 

623 

96 

66,562 

28 

1,617 

282 
421 

3,253 

108 

2,068 

172 

7 

76 

247 

405 

370 

15,145 

93 

187 

775 

11,443 

28,244 

145 

2,661 

13,610 

1,185 

116 

3,347,308 

427 

71 

14,206 

5,088 

78 

64 

1,301 

447 

22 

129 

24 



t.non 

pounds 
70,456 



1.000 
dollars 



17,860 
31,685 
20,911 

51,808 

1,801,949 

3,384 

17,422 

5,148 



14,041 



45,970 

64,719 

2,783 

25 
32 

40,801 

959 



216 



343 



87 
94 



498 

977 



469 



781 



516 
034 



217 



2,393 
4,715 
6,933 

7,376 

69,014 

803 

3,088 

1,358 



4,721 
5,782 
3,454 

59 

7 

2,285 
491 



257 



578 



108 
69 



5,327 
1,523 

18,800 



7,450 
729 



172 



See footnotes at end of table. 



CYCLIC INTERMEDIATES 
TABLE TA. --Cyclic intermediates.- U.S. production and sales , 7567- -Continued 



13 



Chemical 



Production 



Sales 



Quantity 



Value 



7,7 '-IminobisrA-hydroxy-2-naphthalenesulf onio acid] 

1,1' -Iniinobis[4-nitroanthraquinone] 

l,l'-Iminodianthraquinone (1,1' -Dianthrimide ) 

Isocyanic acid derivatives, total 

Diphenylme thane i,'4'-diisocyanate (MDI) 

Toluene 2,^- and 2,6-diisocyanate (80/20 mixture) 

Other isocyanic acid derivatives 

4,'i'-Isopropylidenediphenol (Bisphenol A) 

Isoviolanthrone (Isodibenzanthrone) 

Leuco quinizarin (1,4,9, 10-Anthratetrol) 

Melamine 

dl-p-Mentha-l,8-diene (limonene) 

o-Mercaptobenzoic acid (Thiosalicylic acid) 

Metanllic acid(ni-Aiiiinobenzenesulfonio acid) 

l-(Methylamino)anthraquinone 

4,'4'-Methylenebis [N,N-dlmethylaniline] (Methane base) 

2-Methyl-l-nitroanthraquinone 

p-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic acid 

4-(3-Methyl-5-oxo-2-pyrazolin-l-yl) -m-toluenesulfonic acid 

[S03H=1] - 

3 -Methyl -1 -phenyl -2 -pyrazolin-5 -one (Developer Z) 

a-Methylstyrene 

Naphthalene, solidifying at 79° C. or above (refined flake) 

(from domestic crude) 

2,7-Naphthalenedisulfonic acid 

1,'4,5,8-Naphthalenetetracarboxylio acid 

Naphth[l,2-d] [l,2,3]oxadiazole-5-sulfonic acid 

p-Nitroaniline 

5-Nitro-o-anisidine [NH2=i] 

Nitrobenzene 

m-Nitrobenizenesulfonic acid and sodium salt 

7(and 8)-Nitronaphth[l,2-d] [l,2,3]oxadiazole-5-sulfonio acid- 

p-Nitrophenol and sodium salt 

3-Nltro-p-toluenesulfonic acid [S03H=l] 

5-Nitro-o-toluenesulfonic acid [S03H=1] 

2-Nitro-p-toluidine [NH2=l] 

5-Nitro-o-toluidine [NH2=l] 

Nonylphenol 

l-[(7-0xo-7H-benz[de]anthracen-3-yl) amino ]anthraquinone 

l,l'-[(7-0xo-7H-benz[de]anthraoen-3,9-ylene)diimino]dianthra- 

quinone 

3,4,9,10-Perylenetetracarboxylic-3,4:9,10-diimide 

Phenol, grand total-' 

Natural, total 

From coal tar 

Fran petroleum 

Synthetic, total 

Fran cumene 

Other synthetic 

Phenylacetonitrile (a-Tolunitrile) 

p-Phenylazoaniline (C.I. Solvent Yellow 1) and hydrocliloride- 

p-Phenylenediamine 

l-Phenyl-l,2-propanedione, 2-oxime 

Phthalic anhydride 

Picollnes, total' 

2-Picoline (a-Picoline) 

Other picolines 

Piperidine 

Primuline base 



i.nnn 

fwunds 

10 
116 

114 

257,096 



5,578 
199,695 
51,823 

130,352 

41 

172 

78,082 

7,920 

22 

1,124 

639 

992 

77 

126 

12 

127 

15,941 

2,280 

38 

72 

328 

9,001 

119 

347,700 

3,090 

278 

15,370 

67 

10,419 

864 

156 

55,681 

391 

578 
202 

1,356,331 



59,108 

40,823 

18,285 

1,297,223 

721,339 

575,884 



271 

642 

266 

727,472 

4,540 



3,221 
1,319 

382 

31 



i.nno 
fjounds 



217,260 



I pno 

dollars 



3,228 

183,206 

30,826 

50,555 



49,981 
7,042 



432 



95 
10,468 



12,623 
2,551 

15,145 



192 
26,445 



547,352 



53,858 

40,261 

13,597 

493,494 

3U,150 

180,344 

349 



403,455 
4,144 



3,172 
972 



69,371 



3,255 
53,832 
12,284 

10,410 



12,233 
448 



247 



153 
904 



1,136 
919 

5,868 



269 
2,944 



48,774 



5,140 

3,735 

1,405 

43,634 

27,209 

16,425 

178 



48,180 
1,864 



1,5W 
271 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE Ik. — Cyclic intermediates: U.S. production and sales , i 96 7- -Continued 



Chemical 



Production 



Sales 



Quantity 



Value 



Unit 
value ■■■ 



Propiophenone 

8,16-,'Pyranthrenedione 

2° Pyridine^ 

Salioylaldehyde 

Salicyclic acid, tech 

Styrene, all grades 

Terephthalic acid 

Terephthallo acid, dimethyl ester 

Ij'ijSjS-Tetraohloroanthraquinone 

IjAjSjS-Tetrahydroxyanthraquinone, leuco derivative 

3,3'-Thiobis[7H-benz[de]anthracen-7-one] 

Toluene -2, -i-diajiiine (■4-m-Tolylenediamine) 

o-(p-Toluoyl)benzoic acid 

4-(o-Tolylazo)-o-toluidine (C.I. Solvent Yellow 3) 

2,^,6-Trichloro-s-triazine (Cyanuric chloride) 

l,3,3-Trimethyl-A^,C(-indolineacetaldehyde 

l,3,3-Triraethyl-2-methyleneindoline (Trimethyl base) 

7,7'-Ureylenebis['i-hydroxy-2-naphthalenesulfonic acid] (j acid 

urea) 

Violanthrone (Dibenzanthrone) 

o-Xylene 

p-Xylene 

All other cyclic intermediates 



1,000 
pounds 

342 

29 

5,363 

3,444 

30,149 

3,278,137 

693,981 

936,152 

107 

167 

54 

62,792 

240 

306 

172 
393 

342 

254 

493,219 

757,347 

2,694,055 



1.000 
pounds 



5,126 

2,166 

5,333 

1,551,343 

353,470 



26 

5,091 



464, 947 

635,229 

1,606,134 



1,000 

dol lars 



3,049 

2,137 

1,852 

119,543 

69,365 



32 
1,620 



13,909 

51,966 

301,698 



Per 
pound 



.59 
.99 
.35 

.08 

.20 



1.23 
.32 



.03 
.08 
.19 



■■■ Calculated from rounded figures. 

^ Principally straight-chain dodecylbenzene, tridecylbenzene and other straight-chain alkylbenzenes , but includes 
lesser amounts of branched -chain compounds, 

^ Includes data for coke ovens and gas-retort ovens, reported to the Division of Bituminous Coal, U.S. Bureau of 
Mines, Department of the Interior, and for tar refineries and other producers, reported to the U.S. Tariff Commission. 

* Figures include (o,m,p)-oresol from coal tar and some m-cresol and p-cresol. 

' Does not include ethylbenzene produced and consumed in continuous -process styrene manufacture. 



Table 7A gives statistics on production and sales of cyclic intermediates in 1967. In general, 
the classification of a given chemical as an intermediate is determined by the way in which the 
greater part of its output is consumed. Individual statistics given in the table represent more 
than 87 percent of the total quantity of intermediates produced. Since many of the intermediates 
included in the statistics represent successive steps in production, the totals necessarily include 
considerable duplication. 



See also table 7B, pt. 111, which lists these products alphabetically and Identifies the manufacturers, and (table 23) in the appendix, which 
shows imports of intermediates and related products during 1966-67, 



DYES 15 

Dyes 

This report covers domestic production and sales of synthetic dyes (table 8A ), all of which 
are derived in whole or in part from cyclic intermediates. Approximately two-thirds of the dyes 
consumed in the United States are used by the textile industry to dye natural and synthetic fibers 
or fabrics; about one-sixth are used for coloring paper; and the rest are used chiefly in the pro- 
duction of organic pigments and in the dyeing of leather and plastics. Of the several thousand 
different synthetic dyes that are known; more than one thousand are manufactured by one or more 
domestic producers. The large number of dyes results from the many different types of materials 
to which dyes are applied, the different conditions of service for which dyes are required, and 
costs that a particular use can bear. Dyes are sold as pastes, powders, lumps, and solutions; 
concentrations vary from 6 percent to 100 percent. The concentration, form, and purity of a dye 
are determined largely by the use for which it is intended. 

Total domestic production of dyes in 1967 amounted to 206 million pounds, or 5. 9 percent 
less than the 219 million pounds produced in 1966. Sales of dyes in 1967 amounted to 199 million 
pounds, valued at $332 million, compared with 204 million pounds, valued at $331 million, in 
1966. In terms of quantity, sales of dyes in 1967 were 2. 7 percent smaller than in 1966 and in 
terms of value, 0.2 percent larger. The average unit value of sales of all dyes in 1967 was $1.67 
a pound, or 3. 1 percent greater than the $1.62 a pound reported in 1966. 

Although the output and sales of dyes declined slightly in 1967 compared with 1966, the output 
of nnany individual dyes was cut back substantially during 1967. The output of a number of im- 
portant medium- and low-priced dyes was much snnaller in 1967 than in 1966. Production of 
Mordant Black 11 was 359,000 pounds in 1967, or 83.0 percent less than the 2 . 1 million pounds 
produced in 1 966; that of Mordant Black 1 7 was 1 78, 000 pounds , or 72. 9 percent less than the 
656, 000 pounds produced in 1966; and that of Acid Blue 9 was 426, 000 pounds, or 71. 9 percent 
less than the 1. 5 million pounds produced in 1966. Other important dyes whose output was sub- 
stantially smaller in 1967 than in 1966 were Direct Black 80 (44.0 percent), Direct Blue 2 (43.2 
percent). Acid Black 1 (42.7 percent). Vat Green 9 (32.5 percent), Vat Blue 20 (32.6 percent). 
Vat Green 8 (29.9 percent). Vat Black 27 (25.8 percent), and Vat Green 3 (21.7 percent). 

Conversely, the output of a number of important dyes was larger in 1967 than in 1966. Pro- 
duction of Vat Yellow 2 was 2. 9 million pounds, or 22. 3 percent more than the 2. 4 million pounds 
produced in 1966; that of Vat Green 1 was 4. 7 million pounds, or 16. 1 percent more than the 
4. 1 million pounds produced in 1966. Other important dyes whose output was larger in 1967 than 
in 1966 were Basic Orange 21 (110.8 percent), Basic Yellow 11 (41. 3 percent), Direct Yellow 
106 (40.4 percent), Vat Orange 1 (33. 1 percent). Vat Orange 15 (28. 3 percent), and Direct Yel- 
low 11 (16.1 percent). 



See also table 8B, pt, IH, which lists these products and identifies the manufacturers, and the appendix (tai)le 23), which shows imports of 
dyes during the years 1966-67, 



16 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLK 8A. --Bemenoid dyes.- U.S. production and sales, 1967 



[Listed below are all benzenoid dyes for which any reported data on production or sales may be published. (Leaders 
are used where the reported data are accepted in confidence and may not be published or where no data were re- 
ported.) Table 8B in pt. Ill lists all dyes for which data on production or sales were reported and identifies the 
manufacturer of each] 



Eye 



Production 



Sales 



Quantity 



Value 



Unit 
value-^ 



Grand total- 



1 , Ono 

pounds 

206,240 



ACID DYES 



Total- 



Acid yellow dyes, total- 
Acid Yellow 3 

Acid Yellow 11 

Acid Yellow 17 

Acid Yellow 23 

Acid Yellow 36 

Acid Yellow 40 

Acid Yellow 42 

Acid Yellow 44 

Acid Yellow 54 

Acid Yellow 73 

Acid Yellow 99 

Acid Yellow 124 

Acid Yellow 151 

All other 



Acid orange dyes, total- 
Acid Orange 1 

Acid Orange 7 

Acid Orange 8 

Acid Orange 10 

Acid Orange 24 

Acid Orange 60 

Acid Orange 74 

Acid Orange 116 

All other 



Acid red dyes, total- 
Acid Red 1 

Acid Red 4 

Acid Red 14 

Acid Red 18 

Acid Red 26 

Acid Red 37 

Acid Red 73 

Acid Red 85 

Acid Red 87 

Acid Red 88 

Acid Red 89 

Acid Red 99 



Acid Red 114 

Acid Red 137 

Acid Red 151 

Acid Red 182 

Acid Red 186 

All other 



Acid violet dyes, total- 
Acid Violet 1 

Acid Violet 3 

Acid Violet 7 



Acid Violet 12 

Acid Violet 49 

All other ■ — 



17,546 



3,912 



40 

58 

506 

452 

213 

257 

62 

39 

82 

51 

116 

259 

1,777 

2,677 



59 
556 
417 
284 
383 
90 
56 
282 
550 

3,080 



381 

100 

95 

77 

111 

33 

285 

141 

646 

91 

26 

70 

94 

139 

169 

54 

22 

546 

303 



39 
38 
38 

77 
111 



1 , 000 
pounds 

198,592 



17,495 



3,586 



37 

53 

539 

332 

208 

231 

56 

42 

77 

78 

78 

110 

278 

1,467 

2,828 



59 
570 
393 
319 
498 

85 

307 
597 

2,582 



463 

100 

88 

94 

114 

43 

241 

152 

120 

22 

63 

102 

140 

174 

51 

19 

596 

387 



49 
78 
53 
22 
63 
122 



1.000 
dot lars 

332,049 



38,641 



8,607 



123 
126 

1,127 
771 
322 
650 
97 
130 
163 
174 
178 
268 
674 

3,804 

4,641 



152 
600 
473 
405 
689 
208 

689 
1,425 

5,062 



422 
179 
123 
106 
139 
124 
561 
271 

162 

30 

134 

230 

424 

364 

153 

54 

1,586 

846 



77 

158 

72 

39 

161 

339 



See footnotes at end of table. 



TABLE 8A. —Bemenoid dyes: 



DYES 
U.S. production and sales, i 567— Continued 



17 



Tiye 



Production 



Sales 



Quantity 



Value 



ACID DYES — Continued 



Acid blue dyes, total 

Acid Blue 7 

Acid Blue 9 

Acid Blue 25 

Acid Blue 40 

Acid Blue 41 

Acid Blue 43 

Acid Blue 45 

Acid Blue 62 

Acid Blue 78 

Acid Blue 90 

Acid Blue 113 

Acid Blue 158 and 158A- 
All other— 



i.OOO 
pounds 
3,105 



Acid green dyes, total- 
Acid Green 3 

Acid Green 9 

Acid Green 16 

Acid Green 20 

Acid Green 25 

All other 



^A9 

426 

169 

43 

63 

637 
25 
29 

532 
133 
999 

800 



Acid brovm dyes, total- 
Acid Brown 14 

All other 



102 

102 

42 

305 

249 

693 



Acid black dyes, total - 

Acid Black 1 

Acid Black 24 

Acid Black 48 

Acid Black 52 

Acid Black 60 



337 
356 

2,976 



Acid Black 107- 
All other 



AZOIC DYES AND COMPONENTS 



Azoic Compositions 



Total- 



722 
61 
15 

697 
74 

179 
1,228 



1,740 



Azoic Yellow 1- 
Azoic Orange 3- 

Azolc Red 1 

Azoic Red 2 

Azoic Red 6 

Azoic Blue 3 

Azoic Brown 9 — 



Azoic black dyes 

All other azoic compositions 

Azoic Diazo Components , Bases 
(Fast Color Bases) 



Total- 



797 



Azoic Diazo Component 4, base--—- — — — 
Azoic Diazo Component 5, base — —. 

Azoic Diazo Component 10, base 

A^oic Diazo Component 12, base — .^ 

Azoic Diazo Component 32, base—— — — 

All other azoic diazo components, bases- 



11 



124 
207 
455 



/ , 000 
pounds 
3,289 



70 

598 

153 

46 

59 

17 

528 

29 

36 

9 

533 

158 

1,053 

914 



149 

20 

98 

37 

316 

294 

742 



330 
412 

3,167 



815 
95 
22 

728 
85 

159 
1,263 



1,887 



752 



6 

8 
127 
203 
408 



1,000 
Jo I tars 
10,151 



237" 

842 

842 

197 

210 

139 

1,621 
186 
270 
114 
938 
350 

4,205 

2,690 



204 
84 

411 
64 

927 
1,000 

1,604 



466 
1,138 

5,040 



1,047 
165 
127 

1,207 
297 
423 

1,774 



3,381 



28 


24 


39 


72 


82 


lAA 


149 


147 


270 


79 


79 


134 


179 


177 


298 


131 


119 


246 


181 


181 


567 


595 


777 


1,115 


326 


301 


568 



1,104 



17 

21 

127 

286 

653 



See footnotes at end of table. 



18 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 8A. — Benzenoid dyes.- U.S. production and sales, i567--Continued 



Qye 



Production 



Sales 



Quantity 



Value 



Unit 
value ^ 



AZOIC DYES AND COMPONENTS— Continued 

Azoic Diazo Components , Salts 
(Fast Color Salts) 

Total 

Azoic Diazo Component 1, salt 

Azoic Diazo Component 3, salt 

Azoic Diazo Component 5, salt 

Azoic Diazo Component 6, salt 

Azoic Diazo Component 8, salt 

Azoic Diazo Component 9, salt 

Azoic Diazo Component 10, salt 

Azoic Diazo Component 11, salt 

Azoic Diazo Component 12, salt — — 

Azoic Diazo Component 13, salt — — 

Azoic Diazo Component 28, salt — 

Azoic Diazo Component 44, salt 

Azoic Diazo Component 4-8, salt — 

Azoic Diazo Component 4-9, salt 

All other azoic diazo components, salts 

Azoic Coupling Components 
(I^aphthol AS and Derivatives) 



Total - 



Azoic Coupling Component 2 

Azoic Coupling Component 3 

Azoic Coupling Component 4 

Azoic Coupling Component 5 

Azoic Coupling Component 7 

Azoic Coupling Component 14 

Azoic Coupling Component 17 

Azoic Coupling Component 18 

Azoic Coupling Component 19 — 

Azoic Coupling Component 20-—— — 

Azoic Coupling Component 21 ~ — - 

Azoic Coupling Component 29 

Azoic Coupling Component 43 

All other azoic coupling components- 



BASIC DYES 



Total- 



Basic yellow dyes, total- 
Basic Yellow 2 



Basic Yellow 11- 
Basio Yellow 13- 
All other-- 



Basic orange dyes, total- 
Basic Orange 1— 

Basic Orange 2 



Basic Orange 21 

All other— — 



Basic red dyes, total 

Basic Red 9 

Basic Red 14 

All other 



Basic violet dyes, total 

Basic Violet 1 

Basic Violet 4 

Basic Violet 10 

Basic Violet 16 

All other 



i.noo 

pounds 

1,814 



570 
41 
66 
39 

123 
30 
30 
53 

226 

255 
17 

102 
262 



1,945 



11,896 



2,701 



357 
865 

273 
1,166 

1,563 



352 
477 
565 
169 

1,584 



385 
1,199 

3,103 



971 

33 

330 

136 

1,633 



1,000 
pounds 

1,890 



1.000 
dollars 



13 

544 

58 

67 

50 

150 

37 

23 

57 

257 

278 

10 
104 
242 



1,617 



11,623 



2,701 



757 

257 

1,254 

1,643 



370 
591 
508 
174 

1,383 



395 
980 

2,889 



29 
310 
119 

1,573 



1,717 



14 

284 

60 

68 

48 

95 

40 

29 

58 

177 

241 

13 

271 
319 



2,707 



348 


. • • 




11 


12 


34 


8 


8 


16 




10 


27 


303 


311 


523 


186 


147 


268 


87 




. . . 


482 


415 


460 


10 


9 


43 


62 


41 


75 


71 


56 


103 




8 


17 


17 


16 


44 


360 


584 


1,097 



30,123 



8,295 



940 
2,917 

914 
3,524 

3,251 



395 

747 

1,480 

629 

4,370 



27 
1,189 
3,154 

6,022 



1,102 

98 

1),130 

402 

3,290 



See footnotes at end of table. 



DYES 



19 



TABLE 8A. — Bemenoid dyes.- U.S. production and sales, 1967 — Continued 



Rye 



Production 



Sales 



Quantity 



Value 



Unit 
value-"- 



BASIC DYES—Continued 



Basic blue dyes, total- 
Basic Blue 1 

Basic Blue 5 

Basic Blue 9 

Basic Blue 26 

All other 



Basic Green 1 

Basic Green 4 

Basic Brown 1 

Basic Brown 4 

All o-ther basic dyes- 



DIRECT DYES 



Total- 



Direct yellow dyes, total- 
Direct Yellow 4 

Direct Yellow 5 

Direct Yellow 6 

Direct Yellow 11 

Direct Yellow 12 

Direct Yellow 26 

Direct Yellow 28 

Direct Yellow 44 

Direct Yellow 50 



Direct Yellow 105- 
Direct Yellow 106- 
All o-ther 



Direct orange dyes, total- 
Direct Orange 1— — 

Direct Orange 8-— — 

Direct Orange 15 

Direct Orange 26 

Direct Orange 29 

Direct Orange 34 

Direct Orange 37 

Direct Orange 39 

Direct Orange 72 

Direct Orange 73 — 

Direct Orange 81 

Direct Orange 102 

All other 



Direct red dyes, total 

Direct Red 1 

Direct Red 2 

Direct Red 4 

Direct Red 10 

Direct Red 13 

Direct Red 16 

Direct Red 23 

Direct Red 24 

Direct Red 26 



Direct Red 28- 
Direct Red 31- 
Direct Red 37- 
Direct Red 39- 
Direct Red 72- 
Direct Red 75- 
Direct Red 79- 
Direct Red 80- 
Direct Red 81- 



1,000 
pounds 
1,588 



77 
34 

53 
1,424 

89 
503 
171 
525 

69 



32,264 



9,383 



457 
138 
514 
1,074 
327 

239 
697 
309 
244 
1,137 
4,247 

2,201 



IS 
142 
226 

54 
125 
Ul 

48 
217 
412 
114 

76 
246 
412 

3,572 



lS6 

245 

37 

20 

72 

77 

217 

182 

317 

249 

23 

97 

43 

319 

22 

139 

354 

429 



1,000 

pounds 

1,503 



56 
23 

386 
53 

985 

86 
605 
189 
558 

66 



32, 549 



9,116 



434 

174 

564 

984 

300 

6 

270 

646 

347 

241 

1,089 

4,061 

2,169 



23 
145 
204 

60 
119 
105 

50 
222 
402 
104 

80 
238 
417 

3,130 



169 

248 

24 

18 

75 

61 

219 

184 

126 

212 

17 

87 

50 

283 

17 

130 

379 

368 



dul [at s 
5,166 



135 
109 
846 
172 
3,854 

285 

1,516 

309 

722 

187 



49,138 



14,150 



887 

511 

822 

978 

785 

18 

540 

1,155 

772 

565 

1,863 

5,254 

5,110 



49 
225 
220 
129 
289 
241 
132 
445 
886 
405 
242 
639 
1,208 

6,672 



296 
450 

67 

29 
124 
117 
534 
377 
297 
297 

77 
236 
142 
566 

60 
326 
667 
916 



See foo-tnotes at end of table. 



20 



SYNTHETIC ORGANIC CHEMICALS 1967 



TABLE 8A. — Bemenoid dyes : U.S. production and sales, 1967 — Continued 



Eye 



Production 



Sales 



CJuantity 



Value 



Unit 
value ^ 



DIRECT DYES — Continued 



Direct red dyes — Continued 

Direct Red 83 

Direct Red 122 

Direct Red 1A9 

All other 



l.nno 

pounds 



Direct violet dyes, total- 
Direct Violet 9 

All other 



Direct blue dyes, total- 
Direct Blue 1 — — 

Direct Blue 2 

Direct Blue 6 

Direct Blue 8 

Direct Blue 15 



Direct Blue 22- 
Direot Blue 24- 
Direct Blue 25- 
Direct Blue 67- 
Direct Blue 71- 
Direct Blue 76- 



Direct Blue 78 

Direct Blue 30 

Direct Blue 86 

Direct Blue 98 

Direct Blue 120 and 

Direct Blue 126 

Direct Blue 151 

Direct Blue 218 

All other — 



120A- 



Direct green dyes, total 

Direct Green 1 — — — — - — 
Direct Green 6 — — — — 



Direct Green 8- 
All other 



Direct brovm dyes, total- 
Direct Brown 1 — — 

Direct Brovm lA 

Direct Brown 2 

Direct Brown 6 



Direct Brown 31 — 
Direct Brown 7'i — 
Direct Brown 95 — 
Direct Brown Ill- 
Direct Brown 154- 
All other — — 



Direct black dyes, total- 
Direct Black 4 

Direct Black 9 



Direct Black 19 — 
Direct Black 22 — 
Direct Black 38— 
Direct Black 51 — 
Direct Black 80 — 
All other 



DISPERSE DYES 



Total- 



Disperse yellow dyes, total- 
Disperse Yellow 3 — — ——. 



106 



438 



224 



131 
93 

6,316 



369 

1,035 

518 

32 

20 

16 

48 

35 

35 

176 

118 

537 

1,111 

115 

111 

130 

911 
999 

1,115 



1W 

417 

31 

353 

1,660 



91 

95 
190 

77 
UO 

69 
573 

277 
178 

7,793 



147 

26 

74 

312 

5,304 

71 

1,079 

780 



18,309 



4,814 



1 . noo 

fiounds 



l.unn 

dxit lars 



97 

7 

20 

339 

178 



100 
78 

6,249 



363 

1,148 

439 

47 

20 

22 

13 

41 

32 

52 

179 

113 

529 

1,107 

125 

121 

156 

15 

828 

899 

1,125 



290 

387 

37 

411 

1,751 



93 
172 

89 
115 

65 
628 

41 
331 
128 

8,831 



143 

41 

93 

481 

6,101 

79 

1,105 

788 



16, 577 



4,500 



168 
30 
55 

841 

509 



239 
270 

9,736 



737 

1,036 

271 

95 

20 

40 

15 

105 

132 

135 

269 

331 

794 

1,723 

236 

265 

439 

21 

1,560 

1,512 

2,411 



365 

544 

51 

1,451 

2,377 



121 
132 
270 
99 
352 
103 
599 
146 
306 
249 

8,173 



153 
61 

148 

472 
4,802 

256 
1,008 
1,273 



40,981 



1,959 



1,840 



2,720 



See footnotes at end of table. 



DYES 



21 



TABLE 8A.—Bemenoid dyes: U.S. production and sales, i567--Continued 



Eye 



Sales 



Production 



Quantity 



Value 



Unit 
value^ 



DISPERSE DTES—Continued 



Disperse yellow dyes — Continued 

Disperse Yellow 5 — -— ^ 

Disperse Yellow 8- 



Disperse Yellow 23 — 
Disperse Yellow 33 — 
Disperse Yellow 3A — 
Disperse Yellow 42 — 
Disperse Yellow 54 — 
All other 



Disperse orange dyes, total 

Disperse Orange 3 — — 

Disperse Orange 5 — — 



Disperse Orange 17- 
Disperse Orange 25- 
All other 



Disperse red dyes, total- 
Disperse Red 1 — 

Disperse Red 5 — — 



Disperse Red 11 

Disperse Red 13— 

Disperse Red 15-—— — 

Disperse Red 17 

Disperse Red 60 

Disperse Red 55 

All other 



Disperse violet dyes, total- 
Disperse Violet 1 — 

Disperse Violet 4- 



Disperse Violet 27 — 
All other 



Disperse blue dyes, total- 
Disperse Blue 1 — — 

Disperse Blue 3 — - — 

Disprese Blue 7 — 

Disperse Blue 64 — 

All other — ■— 



Disperse black dyes, total 

Disperse Black l— ^ 

All other 



All other disperse dyes- 



FIBER-REACTIVE DYES 



Fiber-reactive dyes, total- 
Reactive blue dyes- 



All other reactive dyes— — 

FLUORESCENT BRIGHTENING AGENTS 
Total 



Fluorescent Brightening Agent 9 

Fluorescent Brightening Agent 28 

All other fluorescent brightening agents 



FOOD, DRUG, AND COSMETIC COLORS 



1.000 
pounds 



140 

368 
353 
335 
650 
172 
837 

1,765 



157 
148 
192 

1,268 

2,232 



227 

71 



62 
138 
220 

39 

1,475 

259 



42 
44 
65 

108 

7,143 



330 
1,892 

549 

80 

4,292 

1,777 



102 
1,675 

319 



2,033 



707 
1,326 



27,622 



Total- 



318 

1,410 

25,894 



3.234 



i.oon 

pounds 



70 
31 
296 
278 
246 
747 
224 
768 

1,486 



114 

126 

146 

49 

1,051 

1,993 

217" 

74 

45 

16 

65 

136 

167 

42 

1,234 

240 



42 
18 
69 

111 

6,337 



243 
1,495 

510 

46 

4,043 

1,772 



115 
1,657 

249 



2,067 



"672r 
1,393 



24,944 



343 

1,396 

23,205 



1,000 
dot lars 

247 
113 
602 
436 
423 

1,122 
861 

1,774 

2,720 



195 

291 

235 

92 

1,907 



361 
131 
286 

23 
202 
146 
578 

86 
4,762 

839 



145 

65 

114 

515 



971 

2,475 

3,196 

105 

12,646 

2,321 



16?" 
2,157 

835 



8,967 



"17532" 
5,485 



51,991 



448 

2,178 

49,365 



11,750 



See footnotes at end of table. 



22 



SYNTHETIC ORGANIC CHEMICALS, 1967 
TABLE 8A. --Benzenoz'rf dyes; U.S. production and sales, J 567— Continued 



Eye 



Production 



Sales 



Quantity 



Value 



value 



FOOD, DRUG, AND COSMETIC COLOES — Continued 



Food, Drug, and Cosmetic Dyes 



Total- 



FD&C Blue No. 1 

FD«C Blue No. 2 

FD&C Red No. 2 

FD&C Red No. 3 

FD&C Yellow No. 5- 
FD&C Yellow No. 6- 



All other food, drug, and cosmetic dyes- 



Drug and Cosmetic and External Drag 
and Cosmetic Dyes 



Total- 



D&C Orange No. •i 

DScC Red No. 7 

D&C Red No. 19 

D&C Red No. 21 

D&C Red No. 36 

D&C Yellow No. 5 

All other drug and cosmetic and external drug and cosmetic 
dyes 



MORDANT DYES 

Mordant yellow dyes, total — 

Mordant Yellow 1-- 

Mordant Yellow 8 

Mordant orange dyes, total 

Mordant Orange 1 — — 

Mordant Orange 5 

All other 

Mordant red dyes — 

Mordant blue dyes--— 

Mordant brown dyes, total— 

Mordant Brown 1 

Mordant Brown 33 

Mordant Brown ■40 

All other ~ — 

Mordant black dyes, total 

Mordant Black 3 

Mordant Black 11 — -— — 

Mordant Black 13 

Mordant Black 17 

All other 

All other mordant dyes 

SOLVENT DYES 

Total 

Solvent yellow dyes, total 

Solvent Yellow 2 

Solvent Yellow 3 



1,000 
pounds 

2,959 



65 

969 

98 

922 

761 



275 



33 

9 

22 

198 



1,465 



208 



10 
198 

93 



54 
39 



122 

58 



211 



137 
760 



359 



178 
223 



13 



11,049 



1,100 



25 

27 



1,000 
pounds 

2,998 



59 
29 
970 
119 
839 
817 
165 



226 



3 
11 
12 
26 
10 
16 

148 



2,095 



223 



35 

13 
175 

127 



20 
78 
29 

112 
62 

213 



37 

34 

13 

129 

1,342 



32 
807 

26 
293 
184 

16 



10,652 



1,005 



30 
41 



1.000 
dot lars 

10,437 



666 
278 
2,599 
1,525 
2,478 
2,118 
773 



1,313 



18 
40 
64 
89 
35 
39 

1,028 



3,379 



393 



52 

25 

316 

210 



30 
94 
86 

309 
168 

522 



86 

68 

35 

333 

1,732 



48 
972 

60 
305 
347 

45 



18,130 



2,238 



54 
63 



See footnotes at end of table. 



TABLE 8A.--Benzenoid dyes: 



DYES 
U.S. production and sales, i967--Continued 



23 



Eye 



Production 



Sales 



Quantity 



Value 



Unit 
value ■'■ 



SOLVENT DnS— Continued 



Solvent yellow dyes — Continued 

Solvent Yellow 14 

All otlier-- — 



1 . 000 
pounds 



Solvent orange dyes, total- 
Solvent Orange 3 

Solvent Orange 7 — 

All other 



Solvent red dyes, total 

Solvent Red 24 

Solvent Red 26 

Solvent Red 33 

Solvent Red 49 

All other 

Solvent violet dyes, total- 
Solvent Violet 8 

All other — 



Solvent blue dyes, total — 

Solvent Blue 38 

All other 

Solvent brown dyes, total- 
Solvent Brown 12 

All other 



All other solvent dyes- 



Sulfur dyes- 



SULFUR DYES^ 



VAT DYES 



Total 



Vat yellow dyes, total 

Vat Yellow 2, 8-1/2% 

Solubilized Vat Yellow 4- 
All other 



Vat orange dyes, total- 



Vat Orange 1, 20 jt 

Solubilized Vat Orange 1, 26 5t- 

Vat Orange 2, 12% 

Vat Orange 3, 13-1/2% 

Vat Orange 4,6% 

Vat Orange 5, 10 %- 



Solubilized Vat Orange 5, 30 % - 

Vat Orange 9, 12 % 

Vat Orange 15, 10% 

All other — — — — 



Vat red dyes, total- 
Vat Red 1, 13%- 



Solubilized Vat Red 1, 37%- 

Vat Red 13, 11% 

Vat Red 15, 10% 

Vat Red 32, 20% 

All other 



Vat violet dyes, total- 
Vat Violet 1, 11 % ~ 



Vat Violet 2, 20% 

See footnotes at end of table. 



737 
311 



524 



41 

483 

1,549 



312 
301 

17 

919 

713 



428 
285 



1,407 
58 



14 
44 

5,698 



56,805 



2,941 
2,456 
3,854 



1,290 

8 

423 

72 
74 

4 

239 

639 

1,105 

2,150 



352 

154 

101 
1,543 

689 



213 
36 



i , 01)0 
pounds 



638 
296 

468 



20 
115 
333 

1,482 



291 
292 

47 
852 

733 



458 
275 

1,322 



124 
1,198 

59 



10 
49 

5,583 



16,892 



53,849 



5,696 



3,007 

6 

2,683 

3,342 



1,035 

8 

388 

50 

82 

82 

5 

184 

655 

853 

1,04^ 



370 
4 
100 
187 
69 
314 

669 



234 



1,00(1 
dollars 

621 
1,500 

899 



41 

148 
710 

3,272 



563 
569 

301 
1,839 

1,050 



563 

487 

5,338 



693 
4,645 

214 



29 

185 

5,119 



10,737 



58,025 



8,136 



2,678 

55 

5,403 

8,429 



2,899 

74 

790 

132 

259 

136 

53 

382 

1,329 

2,375 

2,535 



639 
35 
297 
210 
263 
1,091 

1,497 



619 



24 



SYNTHETIC ORGANIC CHEMICALS, 1967 
TABLE 8A. --Bemenoid dyes : U.S. production and sales, i 967- -Continued 



Dye 



Production 



Sales 



Quantity 



Value 



Unit 
value ^ 



VAT DYES— Continued 



Vat violet dyes --Continued 
Vat Violet 9, 12% 



Vat Violet 13, 6-lA^ 
All other 



Vat blue dyes, total- 
Vat Blue 6, 8-1/3* 
Vat Blue 20, lAi — 
All other 



1.000 
pounds 

110 

266 

64 

18, 777 



Vat green dyes, total — 

Vat Green 1, 6$ 

Vat Green 3, 10<( 

Vat Green 8, 8-l/2<t - 
Vat Green 9, 12-1/2* 
All other -— 



2,852 
733 
15,192 

12,764 



Vat brovm dyes, total- 
Vat Brown 1, 11* 

Vat Brown 3, 11* 

Vat Brown 5, 13* 

All other 



4,706 

4,206 

2,489 

926 

437 

3,825 



1,000 
pounds 

248 
187 

18,458 

2,897 

631 

14,930 

12,205 



1.000 
do I lars 



Per 
pound 



338 
540 



11,397 



$1.36 
2.89 

.62 



Vat black dyes, total- 



Solubllized Vat Black 1, 27-1/2* ■ 

Vat Black 9, 16* 

Vat Black 25, 12-1/2* 

Vat Black 27, 12-1/2"^ 

All other — . 



763 

1,181 

87 

1,794 

9,349 



4,950 
3,673 
2,092 
1,057 
433 

3,937 



3,153 

856 

7,388 

9,348 



1.09 

1.36 

.49 

.77 



706 

1,263 

93 

1,875 



3,062 

2,802 

1,897 

943 

644 

7,072 



.62 

.76 

.91 

.89 

1.49 



All other dyes-" 



169 
5,249 
1,130 
2,801 

17,721 



3 

178 

4,642 

1,087 

2,588 

479 



1,153 

2,296 

147 

3,476 

9,611 



1.63 
1.82 
1.58 
1.85 

1.13 



24 

442 

3,185 

3,340 

2,620 

1,278 



8.00 
2.48 
.69 
3.07 
1.01 



2.67 



^ Calculated from rounded figures. 

^ Production and sales quantities of C.I. Leuco Sulfur and C.I. Solubilized Sulfur dyes are reported in terms of 
the usual connnercial concentration of the C.I. Sulfur dyes. 

^ Includes oxidation bases, ingrain dyes, miscellaneous dyes, and production data for sulfur dyes. 
Statistics for these groups of dyes may not be published separately because publication would disclose information 
received in confidence. 

Table 9 summarizes production and sales of dyes in 1967, by class of application. Four ap- 
plication classes of dyes accounted for approximately two-thirds of all the dyes produced. Vat 
dyes accounted for 27. 5 percent of the total; direct dyes, for 15. 6 percent; fluorescent bright- 
eners, for 1 3. 4 percent; and acid dyes, for 8. 5 percent. Of these four classes of dyes , the 
output of fluorescent brighteners was 19. percent larger in 1967 than in 1966, but the output of 
acid dyes was 24.4 percent smaller in 1967 than in 1966; direct dyes, 13. 6 percent smaller; 
and vat dyes, 1.1 percent smaller. 

Of the remaining classes, the output of the disperse dyes was 18. 3 million pounds in 1967, 
or 9. 7 percent more than the 16. 7 million pounds produced in 1966. Production of basic dyes was 
6. 8 percent larger in 1967 than in 1966; fiber-reactive dyes, 6. 5 percent larger; and solvent dyes, 
2. 6 percent larger. On the other hand, the output of mordant dyes was 65. 8 percent smaller in 
1967 than in 1966; azoic dyes and components, 32. 9 percent smaller, and food, drug, and cos- 
metic colors, 3.8 percent smaller. 

Table 10 shows production and sales of dyes, by chemical class. In 1967, three chemical 
classes of dyes accounted for more than two-thirds of all the dyes produced: Azo dyes accounted 
for 28. 7 percent of the total; anthraquinone dyes, for 25. 1 percent; and stilbene dyes, for 13. 9 
percent. The output of the stilbene dyes was 16.8 percent larger in 1967 than in 1966, but that of 
azo dyes was 14. 9 percent smaller and anthraquinone dyes, 4. 7 percent smaller. Of the re- 
maining chemical classes for which statistics are published, the output of methine dyes was 67. 5 
percent larger in 1967 than in 1966; quinoline dyes, 48. 8 percent larger; cyanine dyes, 28. 8 
percent larger; nitro dyes, 25. 1 percent larger; and phthalocyanine dyes, 16.3 percent larger. 
On the other hand, the output of thiazole dyes was 24. 1 percent smaller in 1967 than in 1966; 
triarylmethane dyes, 13. 6 percent smaller; and ketone imine dyes, 11. 8 percent smaller. 



DYES 



25 



TABLE 9. — Bemenoid dyes : U.S. production and sales , by class of application, 1967 



Class of application 



Production 



Sales 



Quantity 



Value 



Unit 
value ^ 



Total 

Acid 

Azoic dyes and components: 

Azoic compositions 

Azoic diazo components, bases (Fast color bases) 

Azoic diazo components, salts (Fast color salts) 

Azoic coupling components (Naphthol AS and derivatives 1- 

Baslc 

Direct 

Disperse 

Fiber-reactive 

Fluorescent brightening agents 

Food, drug, and cosmetic colors 

Mordant 

Solvent 

Sulfur^ 

Vat 

All other^ 



1 . ono 

pounds 
206,240 



1 . oon 
pounds 

198, 592 



l.lllXl 
dot Ian 

332,049 



Per 

pound 



$1.67 



17,546 

1,740 

797 

1,814 

1,945 

11,896 

32,264 

18,309 

2,033 

27,622 

3,234 

1,465 

11,049 

56,805 
17,721 



17,495 

1,887 

752 

1,890 

1,617 

11,623 

32,549 

16, 577 

2,067 

24,944 

3,224 

2,095 

10,652 

16,892 

53,849 

479 



38,641 

3,381 

1,104 

1,717 

2,707 

30,123 

49,138 

40,981 

8,967 

51,991 

11,750 

3,379 

18, 130 

10,737 

58,025 

1,278 



2.21 

1.79 
1.47 
.91 
1.67 
2.59 
1.51 
2.47 
4.34 



2.08 
3.64 
1.61 
1.70 
.64 
1.08 
2.67 



Calculated from rounded figures. 

^ Production and sales quantities of C.I.Leuco Sulfur and C.I. Solubilized Sulfur dyes are reported in terms of the 
usual commercial concentration of the C.I. Sulfur dyes. 

^ Includes oxidation bases, ingrain dyes, and miscellaneous dyes, and production data for sulphur dyes. Statistics 
for these groups of dyes may not be published separately because publication would disclose information received in 
confidence. 

TABLE 10. — Bemenoid dyes.- U.S. production and sales, by chemical class, 1967 



Chemical class 



Production 



Sales 



Quantity 



Value 



Unit 
value ^ 



Total- 



1,000 
pounds 
206,240 



1.000 
pounds 
198, 592 



1 . 000 

dollars 

332,049 



Per 
pound 

$1.67 



Acridine 

Anthraquinone- 



Azo, total 

Monoazo 

Disazo 

Trisazo 

Polyazo 

Not specified- 



51,704 
59,304 



Azoic 

Cyanine 

Ketone imine — 

Me thine 

Nitro 

Oxazine 

Phthalocyanine- 

Quinoline 

Stilbene 

Sulfur^ 

Thiazine 

Thiazole 

Tri ary Imethane- 

Xanthene 

All other^ 



23,576 

18,639 

9,963 

1,854 

5,272 

6,296 

662 

443 

2,146 

1,788 

2,073 

778 

28,648 



445 

6,855 

1,770 

43,328 



9 
48,486 

59,648 



23,357 

18,148 

10,878 

2,121 

5,144 

6,146 
657 
510 

1,831 

1,729 
239 

1,966 

799 

25,944 

16,892 

386 

478 

6,740 

885 

25,247 



26 

86,671 

111,181 



2.89 
1.79 



1.86 



49, 537 
33,534 
11,835 
3,729 
12,546 

8,909 
2,119 
1,149 
6,103 
2,891 
1,009 
5,236 
2,539 

44,780 

10,737 

847 

1,071 

14,942 
4,502 

27,337 



2.12 
1.85 
1.09 
1.76 
2.44 

1.45 
3.23 
2.25 
3.33 
1.67 
4.22 
2.66 
3.18 
1.73 
.64 
2.19 
2.24 
2.22 
5.09 
1.08 



Calculated from rounded figures. 
^ Production and sales quantities of C.I. Leuco Sulfur and C.I. Solubilized Sulfur dyes are reported in terms of 
the usual commercial concentration of the C.I. Sulfur dyes. 

Includes production and sales of aminoketone, azine, coumarin, hydroxyketone, indigoid, nitroso, oxidation bases, 
vat sulfur, and miscellaneous dyes; and production of acridine, oxazine, sulfur, and thiazine dyes. Statistics for 
these groups of dyes may not be published separately because publication would disclose information received in 
confidence. 



26 SYNTHETIC ORGANIC CHEMICALS, 1967 

Pigments 

As the terms are used in this report, synthetic organic pigments are toners and lakes de- 
rived in whole or in part from benzenoid chemicals and colors. They are used in paints and 
related products, in printing inks, and in plastics and resin materials. 

Statistics on production and sales of all benzenoid pigments in 1967 are given in table 1 lA-' . 
Statistics on sales of a few selected pigments by commercial fornas (dry full-strength form, dry 
extended form, dry dispersions, aqueous dispersions, and flushed colors) are given in table 12. 
Prior to 1961, statistics for toners included the quantities and values of extenders and diluents. 
Beginning in 1961, data were collected for both the full-strength and extended toners on a full- 
strength-toner-content basis. Individual toners and lakes are identified in this report by the names 
used in the second edition of the Colour Index . 

Total production of benzenoid pigments in 1967 was 53. 3 million pounds--4. 3 percent more 
than the 51. 1 million pounds produced in 1966 and 11.0 percent more than the 48.0 million pounds 
produced in 1965. Total sales of benzenoid pigments in 1967 amounted to 42. 9 million pounds, 
valued at $108. 4 million, compared with 43. 3 million pounds, valued at $107. 6 million, in 1966 
and 38. million pounds', valued at $93. 6 million, in 1965. In terms of quantity, sales of benze- 
noid pigments in 1967 were 1. percent smaller than in 1966 and 12. 7 percent larger than in 1965; 
in terms of value, sales in 1967 were 0. 7 percent larger than in 1966 and 15.7 percent larger 
than in 1965. 

Production of toners in 1967 amounted to 49. 2 million po\inds--5. 4 percent nnore than the 
46.6 million pounds reported for 1966. Sales in 1967 were 39.0 million pounds, valued at 
$104. 7 million, compared with 39. 1 million pounds, valued at $103.6 million, in 1966. Sales 
in 1967 were thus 0.3 percent smaller than those in 1966 in terms of quantity, and 1.0 percent 
larger in terms of value. The individual toners listed in the report which were produced in the 
largest quantities in 1967 were Pigment Blue 15, alpha form, 5. million pounds; Pigment 
Green 7, 4.5 million pounds; Pigment Yellow 12, 4.4 million pounds; Pigment Red 49, barium 
toner, 3. 7 million pounds; Pigment Blue 15, beta form, 3.2 million pounds; Pigment Blue 19, 
2. 9 million pounds; and Pigment Red 48, 2. 5 million pounds. 

Production of lakes totaled 4.2 million pounds in 1967--7. 7 percent less than the 4. 5 mil- 
lion pounds reported for 1966. Sales of lakes in 1967 amounted to 3.9 million pounds, valued 
at $3. 7 million, compared with sales in 1966 of 4.2 million pounds, valued at $4.0 million. 
Sales in 1967 were thus 8.0 percent smaller than those in 1966 in terms of quantity, and 7.4 per- 
cent smaller in ternns of value. 

For each of 15 selected pigments, or groups of pigments, table 12 gives data on sales by 
commercial forms. Pigment Yellow 12, Pigment Red 90, and Pigment Blue 19 were sold prin- 
cipally in the flushed form. The remaining 12 pigments, or groups of pigments, for which sta- 
tistics are published were sold principally in the dry full- strength form. Statistics on sales by 
commercial forms could not be published for Pigment Red 49, sodium toner, without revealing 
the operations of individual companies. 



See also table 1 1 B, pt. Ill, which lists these products and identifies the manufacturers, and (table 23) in the appendix, which shows imports 
of benzenoid pigments during the years 1966-67, 



PIGMENTS 



27 



TABLE llA.—Benzenoid pigments : U.S. production and sales , 1967 

[Listed below are all toners and lakes for which any reported data on production or sales may be published. (Leaders 
are used where the reported data are accepted in confidence and may not be published or where no data were re- 
ported.) Table IIB in pt. Ill lists all toners and lakes for which data on production or sales were reported and 
identifies the manufacturer of each] 



Pigment 



Production 



Sales 



CJuantity 



Value 



Unit 
value-"- 



Grand total 

TONERS 

Total 

Yellow toners, total 

Hansa yellows, total 

Pigment Yellow 1, C.I. 11 680 

Pigment Yellow 3, C.I. 11 710 - 

Pigment Yellow 73 

Pigment Yellow 74, C.I. 11 741 

Other Hansa yellows 

Benzidine yellows, total 

Pigment Yellow 12, C.I. 21 090 

Pigment Yellow 13, C.I. 21 100 

Pigment Yellow U, C.I. 21 095 - 

Pigment Yellow 17, C.I. 21 105 

Other benzidine yellows 

All other 

Orange toners, total 

Pigment Orange 2, C.I. 12 060 

Pigment Orange 5, C.I. 12 075 

Pigment Orange 13, C.I. 21 110 

Pigment Orange 16, C.I. 21 160 

All other 

Red and violet toners, total 

Naphthol reds, total 

Pigment Red 2, C.I. 12 310 

Pigment Red 5, C.I. 12 490 

Pigment Red 13, C.I. 12 395 

Pigment Red 17, C;I. 12 390 

Pigment Red 18, C.I. 12 350 

Pigment Red 22, C.I. 12 315 

Pigment Red 23, C.I. 12 355 

Other naphthol reds 

Pigment Red 1, C.I. 12 070, dark 

Pigment Red 1, C.I. 12 070, light 

Pigment Red 3, C.I. 12 120 

Pigment Red 4, C.I. 12 085 

Pigment Red 6, C.I. 12 090 

Pigment Red 38, C.I. 21 120 

Pigment Red 48, C.I. 15 865 

Pigment Red 49, C.I. 15 630: 

Barium toner 

Calciujn toner 

Sodium toner 

Pigment Red 52, C.I. 15 860 

Pigment Red 53, C.I. 15 585, barium toner- 
Pigment Red 54, C.I. 14 830, calcium toner- 
Pigment Red 57, C.I. 15 850, calcium toner- 
Pigment Red 63, C.I. 15 880 

Pigment Red 81, C.I. 45 160, PMA 

Pigment Red 81, C.I. 45 160, PTA 

Pigment Red 90, C.I. 45 380 

(Vat Red 29), C.I. 71 140 

Pigment Violet 1, C.I. 45 170, PMA 

Pigment Violet 1, C.I. 45 170, PTA 

Pigment Violet 3, C.I. 42 535, fugitive 

Pigment Violet 3, C.I. 42 535, PMA 



1.000 
pounds 
53,322 



49, 168 



8,790 



1,334 
655 
153 
292 
142 
92 

7,145 

4,430 
291 

1,749 
326 
349 
311 

997 



59 
263 
152 
307 
216 

21,886 



776 

60 

81 

5 

100 

11 

90 

155 

274 

153 

212 

1,724 

270 

38 

218 

2,525 

3,674 

1,467 

220 

1,477 

2,183 

72 

1,051 

56 

363 

135 

1,770 

31 

100 

75 

542 

433 



1,000 
pounds 



42,867 



1.000 
dol Lars 
108,354 



39,000 



104,680 



5,909 



1,046 

465 

87 

127 

367 

4,731 

2,605 

190 

1,412 

239 

285 

132 

861 



52 
230 
147 
252 
180 

18,285 



522 

29 

56 

4 

84 

68 
141 
140 
117 
173 

1,545 

209 

26 

166 

2,283 

3,085 

1,354 

265 

1,434 

1,773 

61 

873 

52 

316 

119 

930 

95 

66 

537 

359 



16,110 



2,586 
874 
194 

438 

1,080 

12,085 

5,756 

601 
3,469 

728 
1,531 
1,439 

3,006 



79 

367 

478 

669 

1,413 

43,628 



2,128 

75 

285 

17 

256 

204 
478 
813 
145 
214 

2,344 

305 

41 

735 

4,275 

3,161 
1,450 

284 
2,175 
2,372 

141 

1,313 

97 

1,917 

784 
1,731 

302 

442 

762 

1,050 



See footnotes at end of table. 



28 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE llA. --Benzenoid pigments: U.S. production and sales, 7567- -Continued 



Kgment 



Production 



Sales 



Quantity 



Value 



Unit 
value-"- 



TONmS- - Continued 



Red and violet toners — Continued 

Pigment Violet 3, C.I. 42 535, PTA 

Pigment Violet 23 

All other 

Blue toners, total 

Pigment Blue 1, C.I. 42 595, FMA 

Pigment Blue 1, C.I. 42 595, PTA 

Pigment Blue 9, C.I. 42 025, PTA 

Pigment Blue 14, C.I. 42 600, PMA 

Pigment Blue 15, C.I. 74 160, alpha form 

Pigment Blue 15, C.I. 74 160, beta form 

Pigment Blue 19, C.I. 42 750A 

Pigment Blue 22, C.I. 69 810 

Pigment Blue 25, C.I. 21 180 

All other 

Green toners, total 

Pigment Green 1, C.I. 42 040, PTA 

Pigment Green 2, C.I. 42 040 and 49 005, PMA- 
Plgment Green 2, C.I. 42 040 and 49 005, PTA- 

Plgment Green 4, C.I. 42 000, PTA 

Pigment Green 7, C.I. 74 260 

Pigment Green 8, C.I. 10 006 

Pigment Green 36, C.I. 74 265 

All other 

Brown toners, total 

Pigment Brown 5, C.I. 15 800 

All other 

Black toners 

LAKES 

Total 

Red lakes : 

Pigment Red 60, C.I. 16 105 

Pigment Red 83, C.I. 58 000 

(Acid Red 26), C.I. 16 150 

Violet lakes: Pigment Violet 5, C.I. 58 055 

All other lakes^ 



1.000 
pounds 

43 

85 

2,193 

11,819 



172 
25 

56 

5,049 

3,166 

2,899 

26 

218 

208 

5,251 



9 

75 

57 

7 

4,483 

193 

196 

231 

181 



119 
62 



244 



4,154 



189 

82 

565 

201 

3,117 



1,000 
pounds 

37 

66 

1,822 

9,595 



146 

16 

6 

60 

3,692 

2,510 

2,867 

27 

106 

165 

3,980 



7 

68 

50 

8 

3,353 

166 

167 

161 

149 



96 
53 



221 



3,867 



210 

61 

580 

143 

2,873 



1,000 
do I lars 

164 

1,205 

14,091 

28, 196 



746 
92 
32 

523 

10,474 

7,903 

6,748 

464 

322 

892 

13,083 



45 
359 
214 
31 
10,792 
196 
576 
870 

428 



152 
276 



229 



3,674 



319 
223 
268 

320 

2,544 



Per 
pound 

$4.43 

18.26 

7.73 

2.94 



5.11 
5.75 
5.33 
8.72 
2.84 
3.15 
2.35 
17.19 
3.04 
5.41 

3.29 



6.43 
5.28 
4.28 
3.88 
3.22 
1.18 
3.45 
5.40 

2.87 



1.58 
5.21 



1.04 



.95 



1.52 

3.66 

.46 

2.24 

.89 



■"■ Calculated from rounded figures. 

Includes all black, blue, brown, orange, and yellow lakes, " all other" red, and "all other" violet lakes. 

Note. — The C.l. (Colour Index) nxmbers shown in this report are the identifying numbers given in the second edition 
of Colour Index. 

The abbreviation FMA and PTA stand for phosphoraolybdic and phosphotungstic (including phosphotungstomolybdic ) acids, 
respectively. 



PIGMENTS 



29 



TABLE 12. --U.S. sales of selected dry full-strength colors, dry extended colors , dry dispersions, aqueous 

dispersions , and flushed colors, 1967 



Selected pigments by oommeroial forms 



Sales 



Quantity-'^ 



Value 



Pigment Yellow 12, C.I. 21 090, total 

Dry full-strength toner 

Dry extended toner, dry dispersions, and aqueous dispersions-' ^ 

Flushed color 

Pigment Yellow 13, C.I. 21 100; Pigment Yellow U, C.I. 21 095; Pigment 

Yellow 17, C.I. 21 105; and other benzidine yellows, total 

Dry full-strength toner 

Dry extended toner and dry dispersions* 

Aqueous dispersions ■* 

Flushed color 

Pigment Red 3, C.I. 12 120, total 

Dry full-strength toner and dry extended toner* 

Aqueous dispersions-' 

Flushed color 

Pigment Red ^8, C.I. 15 865, total 

Dry full-strength toner 

Dry extended toner and dry dispersions* 

Aqueous dispersions^ 

Flushed color 

Pigment Red 49, C.I. 15 630, barium toner, total 

Dry full-strength toner 

Dry extended toner and aqueous dispersions^ * 

Flushed color 

Pigment Red 49, C.I. 15 630, calcium toner, total 

Dry full-strength toner and dry dispersions* 

Aqueous dispersions-' and flushed color* 

Pigment Red 49, C.I. 15 630, sodium toner* 

Pigment Red 53, C.I. 15 585, barium toner, total 

Dry full-strength toner, dry extended toner, and dry dispersions* 

Aqueous dispersions^ and flushed color* 

Pigment Red 90, C.I. 45 380, total 

Dry full-strength toner 

Dry extended, toner, dry dispersions, and aqueous dispersions-' * 

Flushed color 

Pigment Violet 3, C.I. 42 535, fugitive, total 

Dry full-strength toner and dry extended toner*-T 

Flushed color 

Pigment Violet 3, C.I. 42 535, permanent (PMA and PTA), total 

Dry full-strength toner 

Dry extended toner, dry dispersions and aqueous dispersions-' * 

Flushed color 

Pigment Blue 15, C.I. 74 160, alpha form, total 

Dry full-strength toner 

Di^ extended toner 

Diy dispersions 

Aqueous dispersions-' 

Flushed color 



; . iHH) 

puunds 
2,605 



569 

180 

1,856 



2,126 



1,395 

71 

423 

237 

1,545 



984 
101 
460 

2,283 



2,110 
78 
31 
64 

3,085 



2,280 
90 

715 



1,354 



1,123 
231 

265 

1,773 



1,089 
684 

930 



16 
13 

901 

537 



270 
267 



396 



277 
34 

85 
3,692 



1,441 
719 
184 

1,138 
210 



1.00(1 
dot lars 



5,857 



1,197 

384 

4,276 



6,374 



4,362 
196 

1,109 
707 

2,399 



1,477 
130 
792 

4,275 



3,931 

146 

81 

117 

3,261 



2,346 

91 

824 

1,574 



1,204 
370 

298 

2,422 



1,446 
976 

1,845 



34 

25 

1,786 

762 



398 
364 



1,253 



827 
166 
260 

10,495 



4,039 
2,389 

507 
2,902 

658 



See footnotes at end of table. 



30 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 12. — U.S. sales of selected dry full-strength colors, dry extended colors dry dispersions, aqueous 

dispersions, and flushed colors, 1967 — Continued 



Selected pigments by commercial forms 



Sales 



Quantity^ 



Value 



Unit 
value^ 



Pigment Blue 15, C.I. 74 160, beta form, total - 

Dry full-strength toner 

Dry extended toner and dry dispersions'' 

Aqueous dispersions^ 

Flushed color 



1,000 
pounds 

2,510 



1,000 
dot lars 

7,907 



Pigment Blue 19, C.I. 42 750A, total 

Dry full-strength toner and dry extended toners- 
Aqueous dispersions^ and flushed color* 



1,027 
334 
499 
650 

2,867 



3,345 
1,162 
1,373 
2,027 

6,748 



Pigment Green 7, C.I. 74 260, total - 

Dry full-strength toner 

Dry extended toner 

Dry dispersions 

Aqueous dispersions^ 

Flushed color 



212 
2,655 



3,353 



525 
6,223 

10,792 



1,342 
440 
323 
988 
260 



4,337 
1,660 
1,009 
2,872 
914 



Per 
pound 

$3.15 



3.26 
3.48 
2.75 
3.12 

2.35 



2.48 
2.34 

3.22 



3.23 
3.77 
3.12 
2.91 
3.52 



■"■ Quantity of the various commercial forms is given in terms of dry full-strength toner (or dry lake) content. 
^ Calculated from rounded figures. 
^ Includes pressoake. 

^ Separate data on these commercial forms may not be published without revealing the operations of individual 
companies. 

Note. — The C.I. {Colour Index) numbers shown in this report are the identifying numbers given in the second 
edition of the Colour Index. 

The abbreviations PMA and PTA stand for phosphomolybdio and phosphotungstic (including phosphotungstomolybdic ) 
acids, respectively. 

Medicinal Chemicals 



Medicinal chemicals include the medicinal and feed grades of all organic chemicals having 
therapeutic value, whether obtained by chemical synthesis, by fermentation, by extraction from 
naturally occurring plant or animal substances, or by refining a technical grade product. They 
include antibiotics and other anti-infective agents, antihistamines, autonomic drugs, cardiovas- 
cular agents, central nervous system depressants and stimulants, hormones and synthetic sub- 
stitutes, vitamins, and other therapeutic agents for human or veterinary use and for animal feed 
supplements. 

Table 13A shows statistics for production and sales of medicinal chemicals grouped by 
pharmacological class. 4 The statistics are for bulk chemicals only; finished pharmaceutical 
preparations and products put up in pills, capsules, tablets, or other measured doses are ex- 
cluded. ' The difference between production and sales reflects inventory changes, processing 
losses, and captive consumption of medicinal chemicals processed into ethical and proprietary 
pharmaceutical products by the primary manufacturer. In some instances, the difference may 
also include quantities of medicinal grade products used as intermediates, e.g. , penicillin G 
salts used as intermediates in the manufacture of semisynthetic penicillins. All quantities are 
given in terms of 100-percent content of the pure bulk drug. 

Sales of antibiotics for the years 1965-67 cannot be compared with those for earlier years 
because the reporting instructions were changed in 1965 to exclude sales of antibiotics in mix- 
tures, formulations, capsules, pills, tablets, etc. For the years prior to 1965, sales data for 
antibiotics represented all sales by the primary producers, including finished pharmaceutical 
preparations. 



* See also table 13B, pt. Ill, which lists these products and identifies the manufacturers, and table 23 in die appendix, which shows imports of 
benzenoid medicinal chemicals and pharmaceuticals during the years 1966-67, 

' Complementary statistics on the dollar value of manufacturers' shipments of finished pharmaceutical preparations, except biologlcals, are 
published annually by the U.S. Department of Commerce, Bureau of the Census, in Current Industrial Reports, Series MA-M28G. Many pharma- 
ceutical manufacturers who report to the Bureau of the Census are excluded from the Tariff Commission report because they are not primary 
producers of medicinal chemicals, that Is, they do not themselves produce the bulk drugs which go into their pharmaceutical products but purchase 
their drug requirements from domestic or foreign producers. 



MEDICINAL CHEMICALS 31 

TABLE \Z A. --Medicinal chemicals-. U.S. production and sales , 1967 

[Listed below are all synthetic organic medicinal chemicals for which any reported data on production or sales may 
be published. (Leaders are used where the reported data are accepted in confidence and may not be published or 
where no data were reported. ) Table 13B in pt. Ill lists all medicinal chemicals for which data on production or 
sales were reported and identifies the manufacturer of each] 



Chemical 



Sales -^ 



Production-'- 



Quantity 



Value 



Unit 
value ^ 



Grand total 

Acyclic 

Benzenoid-' 

Cyclic nonbenzenoid*^ 

Antibiotics, total ^ 

For medicinal use, total 

Antifungal and anti tubercular antibiotics 

Bacitracin 

Penicillin G, potassium* 

Other antibiotics for medicinal use 

For other uses, total 

Bacitracin 

All other 

Anticoagulants, total 

Sodium heparin 

All other 

Antihistamines, total 

Antinauseants 

Chlorpheniramine maleate 

Pheniramine maleate 

All other 

Anti -infective agents, total 

Arsenic and bismuth compounds 

Caprylates and undecylenates 

Mercury compounds, total 

Thimerosal 

All other 

Rienolic antiseptics and disinfectants 

Piperazine base and salts, total 

Piperazine 

All other 

Qiinoline derivatives, total 

Diiodohydroxyquin 

Qxyquinoline sulfate 

All other 

Sulfonamides 

Groups listed above for which separate sales data may not 

be shown 

Other anti-infective agents, total 

Anthelmintic and antifungal agents 

Antiprotozoan and antiviral agents 

Urinary antiseptics 

All other 

Antineoplastic agents and local anesthetics, total 

Lldocaine 

All other 

See footnotes at end of table. 



1,000 
pounds 
180,070 



69,941 

91,651 
18,478 

9,464 



5,223 

1,034 

20 

569 
3,600 
4,241 

241 
4,000 



391 



50 

37 

20 

284 

31,399 



3,970 

397 

55 

55 

320 

8,913 

4,017 

4,896 

805 

29 

776 
5,046 



11,893 

5,412 

3,595 

798 

2,088 

899 



899 



1,000 
pounds 
126, 924 



56,804 
58,305 
11,815 

4,744 



2,390 
718 

20 

1,652 

2,354 

187 

2,167 



199 



13 
23 

163 

20, 501 



379 

4 

210 

5,393 

994 

4,399 

396 

23 

8 

365 



4,000 
10, 119 



722 
9,397 



1,000 
dol lars 

385,275 



36,402 

263,656 

85, 217 

96,586 



65,056 

10,754 

969 

53,333 

31, 530 

2,571 

28,959 

1,092 



1,008 
84 

4,847 



219 

340 

4,288 

84,263 



454 

184 

384 

3,917 

904 

3,013 

1,785 

99 

30 

1,656 



11,412 
66, 127 



1,376 
64,751 



161 



32 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 13A. --Medicinal chemicals : U.S. production and sales , i967--Continued 



Chemical 



Sales -^ 



Production^ 



(Juantity 



Value 



Unit 
value ^ 



1,000 
pounds 



Autonomic drugs, total 

Parasympatholytic (anticholinergic) agents (except 

tropane derivatives), total 

(^aternary ammonium compounds 

Tertiary amines 

Sympathomimetic (adrenergic) agents, total 

Isoproterenol salts 

Phenylpropanolamine hydrochloride 

All other 

Other autonomic drugs 

Cardiovascular agents, total 

Cardiac drugs 

Rauwolfia and veratrum alkaloids 

Vasodilators 

Other cardiovascular agents 

Central depressants and stimulants, total 

Anphetamines, total 

Amphetamine base and sulfate (racemic) 

Dextroamphetamine sulfate 

All other 

Analgesics and antipyretics, total 

Salicylates, total 

Aspirin 

All other 

Other analgesics and antipyretics 

Antidepressants 

Barbiturates, total 

Butabarbital, sodium 

Phenobarbital, sodium 

All other 

I^notics and sedatives (except barbiturates)^ 

Skeletal muscle relaxants, total 

Sucoinyloholine chloride 

All other 

Tranquilizers, total 

Meprobamate 

Other tranquilizers'^ 

Other central depressants and stimulants 

Dermatological agents, total 

Bismuth subgallate 

Salicylic acid 

All other 

Expectorants and mucolytic agents, total 

Guaiaool and its derivatives 

All other 

Gastrointestinal agents, total 

Betaine base, hydrate, and hydrochloride 

Choleretics and hydrocholeretics 

Choline chloride (all grades) 

Methionine and its hydroxy analogue 

Other gastrointestinal agents 

Hormones and synthetic substitutes, total 

Synthetic hypoglycemic agents 

Other hormones and synthetic substitutes 

Renal-acting and edema-reducing agents, total 

Mercurial diuretics 

Theobromine and theophylline derivatives, total — 

Amlnophylline 

All other 

Other renal-acting and edema-reducing agents 

Sa^ footnotes at end of table. 



546 



91 

41 

50 

446 

198 

248 

9 

723 



(«) 

54 
669 

43,477 



86 

39 

25 

22 

37,669 

33,105 

30,383 

2,722 

4,564 

116 

668 

5 

663 

481 

268 

7 

261 

1,704 

1,260 

444 

2,485 

12, 996 



23 

11,479 
1,494 

2,231 



2,231 



52,237 



53 

116 

38,649 

10, 998 

2,421 

1,783 



1,538 
245 

1,390 



10 

104 

32 

72 

1,276 



1.000 
pounds 



1,000 
dol lars 



344 



C) 



52 
24 

28 
287 

203 
84 

5 

519 



11 

508 
27, 701 



74 
35 

39 
23,746 
20,300 

20,300 
3,446 

456 
44 

412 

117 

117 

998 

913 

85 

2,310 

9,388 



8,057 
1,331 

1,345 



855 
490 

48, 014 



39 

34,404 

12,150 

1,421 

328 



241 
87 



168 



79 



6,665 



2,486 
1,014 
1,472 
3,954 
15 
1,322 
2,617 
225 

16,291 



189 

16, 102 
56, 710 



581 
150 

431 
34,302 
12,381 

12,381 
21,921 

2,078 
319 

1,759 

634 

634 

4,658 

2,329 

2,329 

14,457 

4,167 



3,093 
1,074 

2,254 



1,450 
804 

17, 661 



66 

5,232 
9,245 
3,118 

17,205 



848 
16,357 

4,2a; 



38 
259 



259 
3,907 



MEDICINAL CHEMICALS 



33 



TABLE 13A. --Medicinal chemicals: U.S. production and sales , i 567.. Continued 



Chemicals 



Production^ 



Sales ^ 



Quantity 



Value 



Unit 
value' 



Therapeutic nutrients, total — 

Andno acids and salts 

Calcium gluconate 

Other therapeutic nutrients- 



1,000 
pounds 

3,W2 



1,000 
pounds 

1,470 



1.000 

dot lars 



Per 
pound 



Vitamins, total 

Vitamin A alcohol and esters, total''-" 

Vitamin A palmitate (feed grade) 

All other 

Vitamin B-complex, total 

Niacin (all grades) 

Niacinamide 

Pantothenic acid and derivatives, total 

Calcium pantothenate (racemio) (feed grade )- 

All other 

Riboflavin (all grades) 

Other B-complex vitamins 

Vitamin C, total 

Ascorbic acid 

All other 

Vitamin D? (Ergocaloiferol)-'-° 

Vitamin E*° 

Vitamin K: 

Menadione 

Menadione sodium bisulfite 

Other vitamins 



Miscellaneous medicinal chemicals-'-'''- 



1,301 

1,8-^1 

17, 568 

1,053 

667 

386 

6,504 

2,306 

867 

1,820 

1,256 

564 

878 

633 

9,160 

7,379 

1,781 

1 

638 

85 
99 
28 

1,815 



"gl9" 
332 
319 

11, 108 



1,832 



1,157 
211 
464 

65,847 



$1.25 



1.41 

.64 

1.45 

5.93 



716 

527 

189 

4,469 

742 
926 
511 
415 
776 
2,025 
5,282 

5,282 

1 

547 



56 
37 

1,086 



16,720 

10,410 

6,310 

24,586 

1,505 
3,014 
1,546 
1,468 
6,071 
13,996 
11,350 

11,350 

124 

9,742 



517 
2,808 

5,490 



23.35 
19.75 
33.39 

5.50 



03 
25 
03 
54 
82 
91 
15 



2.15 

124.00 

17.81 



9.23 
75.89 



5.06 



■'■ The data on production and sales are for bulk medicinal chemicals only; they exclude finished preparations and 
dosage-form products which are manufactured from bulk chemicals. All quantities are given in terms of 100^ active 
ingredient, 

^ Calculated from rounded figures. 

^ The term "benzenoid", as used in this report, describes any cyclic medicinal chemical whose molecule contains 
either a six-membered carbocyclic ring with conjugated double bonds (e.g., the benzene ring or the quinone ring) or a 
six-membered heterocyclic ring with 1 or 2 hetero atoms and conjugated double bonds, except the pyrimidine ring (e.g., 
the pyridine ring or the pyrazine ring). 

* Includes antibiotics of unknown structure. 

' With the exception of bacitracin, the penicillins, and a few other antibiotics which were reported in terms of 
U.S. P. units, all quantities for antibiotics were reported as grams of antibiotic base. (Thus production of 480,900 
grams of tetracycline hydrochloride, for example, would have been reported as 444,430 grams of tetracycline base. ) For 
inclusion in the main statistical table all quantities were converted from grams of antibiotic base to pounds of anti- 
biotic base (453.6 grams = 1 pound) or from U.S. P. units to pounds (22.7 million units of bacitracin, 458 million 
units of procaine penicillin G, 723 million units of potassium penicillin G, etc. = 1 pound). The following tabula- 
tion shows statistics for all individually publishable antibiotics in terms of kilograms of antibiotic base (Kg.) or 
billions of U.S. P. iinits (BU): 



Antibiotic 



Unit of 
quantity 



Production 



Sales 



Quantity 



Value 



Unit 
value 



Bacitracin, total 

For medicinal use- 
For other uses 



-BU- 
-BU- 



5.922 



-BU- 



Neomycin, for all uses- 



-Kg- 



Penicillins, for all uses, total 

Penicillin G, potassium, for medicinal 

use — 

Penicillin G, procaine for all uses 

All other, for all uses 



-BU- 



5,476 

151,668 

1,424,566 



4.707 



45?" 
4,253 

52, 286 

851,778 



1,000 

dol lars 

3.540 



^59" 
2,571 

2,498 

25,175 



$752.07 

2,134.36 

604.51 

47.78 

29.56 



-BU- 
-BU- 
-BU- 



Tetracyollnes, for all uses- 



Kg 



411,613 
727,972 
284,981 

1,522,767 



541,744 
310,034 

616,780 



9,918 
15,257 

32,019 



18.31 
49.21 



51.91 



34 



SYNTHETIC ORGANIC CHEMICALS, 1967 

Footnotes for table i54- -Continued 



^ Production of all penicillins, for all uses, amounted to 2,57<i thousand pounds; sales amounted to 1,618 
thousand pounds, valued at 25,175 thousand dollars. 

' Sales of isoproterenol salts amounted to 369 pounds. 

^ Production of rauwolfia and veratrum alkaloids amounted to 225 pounds. 

' Includes 2 or more of the following 6 drugs which are subject to Federal control under the Drug Abuse 
Control Act: Chlordiazepoxide hydrochloride, diazepam, ethchlorvynol, ethinamate, glutethimlde, and methyl- 
prylon. U.S. production of these 6 drugs amounted to 474 thousand pounds in 1967. 

^° All quantities for vitamins A, ^2> ^> ^3> ^^^ ^ were reported in terms of grams or units, but were con- 
verted to pounds for inclusion in the main statistical table (1.317 billion units of vitamin A acetate, 0.824 
billion units of vitamin A palmitate, 453.6 grams of vitamin B12, 18.14 billion units of vitamins D2 and D3, 
617, OCX) units of d-alpha tocopheryl acetate, 454,000 units of dl-alpha tocopheryl acetate, etc. = 1 pound). 
The following tabulation shows statistics for these vitamins, except for 6^2 and D3, which were not separately 
publishable, in terms of millions of international imits (MU), or billions of U.S. P. units (BU) : 



Vitamin 



Vitamin A alcohol and esters, total- 
Vitamin A palmitate (feed grade) — 
All other 



Vitamin Dj (Ergocalciferol). 
Vitamin E 



Unit of 
quantity 



-BU- 
-BU- 
-BU- 



-BU- 

-MU- 



Production 



970,254 



550,153 
420, 101 

20,433 

343,974 



Sales 



Quantity 



622,048 
434, 128 
187,920 

18,451 

301,123 



Value 



l.OUO 
dollars 
16,720 



10,410 
6,310 

124 

9,742 



Unit value 



$26.88 



23.98 
33.58 



6.72 
32.35 



^■"^ Includes production and sales of diagnostic agents, hematological agents (except anticoagulants), smooth- 
muscle relaxants, and miscellaneous unclassified medicinal chemicals; also includes sales of all other anti- 
neoplastic agents and local anesthetics. 

Total U.S. production of bulk medicinal chemicals in 19^7 amounted to 180 million pounds, 
or 2. 9 percent less than the 185 million pounds produced in 1966, and 12. 9 percent miore than 
the 160 million pounds produced in 1965. Total sales of bulk medicinal chemicals in 1967 
amounted to 127 million poiinds, valued at $385 million, compared with sales in 1966 of 136 
million pounds, valued at $398 million. Sales in 1967 were thus 7. percent smaller thanin 1966, 
in terms of quantity, and 3.3 percent smaller, in terms of value. 

Production of the more important groups of medicinal chemicals in 1967 was as follows: 
Antibiotics, 9.5 million pounds (2 percent smaller than in 1966), of which 5.2 million pounds 
was for medicinal use and 4.2 million pounds was for other uses; anti-infective agents other 
than antibiotics, 31.4 million pounds (6 percent smaller than in 1966); central depressants and 
stimulants, 43.5 nnillion pounds (10 percent smaller); and vitamins, 17.6 million pounds (0.1 
percent larger). Production of some of the more important individual products listed in the 
table was as follows: Choline chloride, 38.6 million pounds (7 percent larger than in 1966); 
aspirin, 30. 4 million pounds (11 percent smaller); salicylic acid, 1 1. 5 million pounds (0. 1 per- 
cent larger); methionine and its hydroxy analogue, 11 million pounds (21 percent smaller); 
piperazine base and salts, 8. 9 nnilUon pounds (3 percent larger); ascorbic acid, 7.4 million 
pounds (3 percent smaller); anti-infective sulfonannides, 5.0 million pounds (7 percent smaller); 
penicillins, 1,425 trillion units (15 percent smaller); tetracyclines, 1.5 million kilogranns (9 
percent smaller); vitamin A, 970 trillion units (3 percent larger); and vitamin E, 344 billion 
units (24 percent larger). 



Flavor and Perfume Materials 

This report covers domestic production and sales of organic chemicals used to impart 
flavors and odors to foods, beverages, cosmetics, and soaps (table 14A).* These aromatic 
chemicals are also utilized to neutralize or mask unpleasant odors in industrial processes 
and products as well as in consumer products. 

Total domestic production of flavor and perfume materials in 1967 amounted to 111.5 
million pounds, or 0.8 percent more than the 110.7 million pounds produced in 1966. Sales of 
these materials in 1967 announted to 96. 6 million pounds, valued at $93.4 million, compared 
with 98. 3 million pounds valued at $92. 6 million, in 1966. 



' See also table 14B, pt. Ill, which lists these products and Identifies the manufacturers, and (table 23) in the appendix, which shows Imports 
of benzenold flavor and perfume materials during the years 1966-67, 



FLAVOR AND PERFUME MATERIALS 



35 



TABLE 14A. --Flavor and perfume materials.- U.S. production and sales, 1967 

[Listed below are all synthetic organic flavor and perfume materials for which any reported data on production or 
sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be pub- 
lished or where no data were reported.) Table 1-46 in pt. Ill lists all flavor and perfume materials for which data 
on production or sales were reported and identifies the manufacturer of each] 



Material 



Production 



Sales 



Quantity 



Value 



Unit 
value ^ 



Grand total 

FLAVOR AND PERFUME MATERIALS, CYCLIC 
Total 

Benzenoid and .\aphthalenoid 

Total 

'i-Allyl-2-methoxyphenol (Eugenol) 

■i-Allyl-l, 2- (methylenedioxy) -benzene (Safrole) 

p-Anisaldehyde 

Anisyl acetate 

Benzophenone^ 

Benzyl acetate 

Benzyl alcohol^ 

Benzyl butyrate 

Benzyl glyceryl acetal 

Benzyl phenylacetate 

Benzyl propionate 

Benzyl salicylate 

Cinnamyl acetate 

Cinnamyl alcohol 

Cinnamyl anthranilate 

Cinnamyl propionate 

Coumarin 

Ethyl phenylglycidate 

Hydratropaldehyde, dimethyl acetal 

ftydrocoumarin 

Isobutyl phenylacetate 

Isobutyl salicylate 

Isopentyl salicylate 

^'-Methoxyacetophenone (Acetanisole) 

2-Methoxy-<i-propenylphenol (Isoeugenol) 

Methyl anthranilate 

oc-Methylbenzyl acetate (Styralyl acetate) 

a-Methyloinnamaldehyde 

Methyl salicylate 

ci-Pentylcinnamaldehyde 

Phenethyl acetate 

Phenethyl isobutyrate 

2 -Phenethyl phenylacetate 

2-Phenoxyethyl isobutyrate 

3-Phenyl-l-propanol (Hydrocinnamio alcohol) 

Piperonal (Heliotropin) 

p-Propenylanisole (Ane thole) 

Sweeteners, synthetic 

p-Tolyl acetate (p-Cresyl acetate) 

All other benzenoid and naphthalenoid materials — 

Terpenoid, Heterocyclic, and .Alicyclic 

Total 

Cedryl acetate 

lonones 

Isobomyl acetate 

p-Menthan-3-one (Menthone) 

Menthol, synthetic, tech. & U.S.P 

Methylionones 

Terpineols 

See footnotes at end of table. 



1.000 
pounds 
111,536 



57,978 



<i8,068 



9,910 



1.000 
pounds 
96,596 



■47,285 



39,231 



8,05^ 



1 . 000 
dollari, 
93,361 



52,866 



36,993 



30^ 


309 


598 




66 


57 


805 


844 


1,176 




4 


14 


261 


132 


141 


1,411 


1,184 


530 


6,123 


5,098 


2,083 




6 


8 


3 


4 


10 


2 


3 


7 


12 


13 


14 


"iOS 


372 


468 




3 


9 


208 


180 


248 


1 


1 


5 




1 


4 


1,U6 


1,125 


2,221 




2 


9 




1 


8 


39 


35 


142 


27 


27 


25 


57 


62 


52 


466 


484 


332 


13 


13 


29 


133 


142 


388 




209 


351 




45 


40 


7 






4,612 


4,595 


2,211 


432 


440 


553 


112 


90 


91 


6 


7 


16 




23 


62 




2 


7 


33 


21 


40 


222 


182 


436 


2,280 


2,307 


1,121 


17,501 


12,669 


8,152 


7 


4 


16 


11,437 


8,526 


15,319 



15,873 



158 


158 


434 


342 






1,002 


939 


355 


8 


9 


30 


652 


557 


2,147 


482 


500 


1,971 


3,140 


3,060 


996 



36 SYNTHETIC ORGANIC CHEMICALS, 1967 

TABLE 14A. — Flavor and perfume materials.- U.S. production and sales , i 967- -Continued 



Material 



Sales 



Production 



(Jiantity 



Value 



Unit 
value ■'■ 



FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued 
Terpenoid, Heterocyclic, and Alicyclic--Continued 

a-Terpinyl acetate 

Vetivenyl acetate 

All other terpenoid, heterocyclic and alicyclic materials- 

FLAVOR AND PERFUME MATERIALS, ACYCLIC 

Total 

Allyl hexanoate 

Citral (Geranial and Neral) 

Citronellyl acetate 

Citronellyl formate 

Citronellyl isobutyrate 

3,7-Dimethyl-trans-2,6-octadien-l-ol (Geraniol) 

3,7-Dimethyl-6-octen-l-ol (Citronellol) 

Ethyl butyrate 

Ethyl hexanoate (Ethyl caproate) 

Ethyl nonanoate 

Geranyl acetate 

Geranyl formate 

Glutamic acid, monosodium salt (Monoscdium glutamate) 

Hydroxycitronellal 

Hydroxycitronellal, dimethyl aoetal 

Isopentyl butyrate 

Isopentyl formate 

Rhodinol ^- — 

All other acyclic materials 

^ Calculated from the unrounded figures. 
^ Includes some technical grade. 



1.000 
pounds 

524 

26 

3,576 



53,558 



18 

308 

28 

7 

A. 

1,310 

590 

371 

W 

92 

<i5,211 

531 

5 

54 

2 

17 

4,996 



1 , 000 
pounds 

530 

25 

2,276 



49,311 



71 
29 
19 

1,113 
554 
352 

3 

81 

9 

42,175 

522 

7 

64 

4 

14 

4,294 



1 . 000 

dollars 

324 

599 

9,017 



40,495 



263 
48 
37 

1,221 
811 
237 

9 
136 

21 

29,589 

2,001 

32 

51 

5 

390 

5,644 



Per 
pound 



$0.61 

23.64 

3.96 



.82 



3 


71 


1 


68 


1 


95 


1 


10 


1 


46 




67 


3 


11 


1 


68 


2 


34 




70 


3 


83 


4 


81 




80 


1 


.45 


28 


22 


1 


31 



Production of cyclic flavor and perfume materials in 1967 amounted to 58. million pounds; 
sales amounted to 47. 3 million pounds, valued at $52. 9 million. The individual chemical in the 
cyclic group produced in the greatest volume in 1967 again was benzyl alcohol (6. 1 million 
pounds). Production of synthetic sweeteners amounted to 17.5 million pounds in 1967, compared 
with 17.3 million pounds in 1966. 

U.S. output of acyclic flavor and perfume materials in 1967 amounted to 53.6 million 
pounds; sales of these materials amounted to 49. 3 million pounds, valued at $40. 5 million. 
Monosodium glutamate was by far the most important of the acyclic chemicals, and the indivi- 
dual flavor and perfume chemical produced in the greatest volume; output of this chemical 
totaled 45.2 million pounds in 1967, slightly less than the 45. 7 million pounds reported in 1966. 

In 1967, many of the flavor and perfume materials were reclassified; as a result, 1967 
production and sales totals for individual groups are not comparable with totals for groups in 
previous years. 

Plastics and Resin Materials 

Plastics and resin materials are condensation and polymerization products of organic 
chemicals, containing necessary plasticizers, fillers, extenders, stabilizers, and coloring 
agents. At sonne stage in their manufacture they exist in such physical condition that they can 
be shaped or otherwise processed by the application of heat and pressure. Some types of plastics 
materials may be molded, cast, or extruded into semifinished or finished forms. Other types 
are used as adhesives, for the treatnient of textiles and paper, and for protective coatings. 
Statistics on U.S. production and sales of synthetic plastics and resin materials for 1967 are 
given in table 15A.7 In general, the statistics follow the outline of the Tariff Commission's 
nnonthly report on the production and sales of synthetic plastics and resin materials (S. O. C. 
Series P-67). However, the data given include some companies which are not covered in the 



See also table 15B, pt. III, which lists these products by chemical types and by end uses, and identifies the manufacturers. 



PLASTICS AND RESIN MATERIALS 



37 



TABLE 15A.- 



-Flastics and resin materials : U.S. production and sales, by chemical classes 
and uses, 1967 



[Quantities and values are given in terms of the total weight of the materials (dry basis). Listed below are all 
plastics and resin materials for which any reported data on production or sales may be published. (Leaders are 
used where the reported data are accepted in confidence and may not be published or where no data were reported. ) 
Table 15B in pt. Ill lists all plastics and resin materials for which data on production or sales were reported and 
identifies the manufacturer of each] 



Kind and use 



Production 



Sales 



Quantity 



Value 



Unit 
value -^ 



Grand total 

Plastics and resin materials, benzenoid 

Plastics and resin materials, nonbenzenoid 

THEIWOSETTING RESINS 

Total 

Alkyd resins, total 

Domestic : 

Phthalio anhydride type 

Polybasic acid type 

Coumarone-indene and petroleum polymer resins, total 

Floor tile 

Rubber compounding 

All other uses 

Sales for export 

Epoxy resin: 

Unmodified, total 

Bonding and adhesives 

Protective coatings 

Reinforced plastics 

All other uses 

Sales for export 

Modified 

Polyester resins,* total 

Reinforced plastics; 

Sheets, flat and corrugated 

All other 

Surface coatings 

All other uses 

Sales for export 

Phenolic and other tar acid resins, total 

Molding materials 

Bonding and adhesive resins for: 

laminating 

Coated and bonded abrasives 

Friction materials 

Thermal insulation 

Foundry or shell molding 

Plywood 

Fibrous and granulated wood 

Protective coatings, unmodified and modified 

All other uses 

Sales for export 

Polyurethane and dlisocyanate resins 

Rosin modifications, total 

Rosin and rosin esters, unmodified (ester gums) 

All other 

See footnotes at end of table. 



1,000 

pounds, 

dry basis' 

13,792,949 



5,033,497 
8,759,452 



3,514,928 



638,478 



549,775 

88,703 

284,162 



47,268 

66,899 

169,995 



131,424 



5,868 
513,492 



983,413 



275,967 

119,738 
27,336 
35,837 

116,546 
65,749 

175,235 
35,330 
36,387 
95,288 



88,604 
133,889 



27,313 
106,576 



i,ono 

pounds, 
dry 6asis' 
11,977,363 



1 , 000 
do! lars 
2,672,630 



4,224,121 
7,753,242 



2,791,537 



^313,293 



262,429 
50,864 

286,601 



45,993 

65,119 

148,881 

26,608 



130,349 
16,488 
54, 996 
26,256 
17,922 
14,687 
4,484 

449,183 



45,817 
278,943 

5,839 
108,702 

9,882 

789,661 



244,683 

68,112 
19,281 
33,231 
55,068 
62,020 
157,179 
27,654 
26,600 
79,406 
16,427 

65,944 

122,002 



25,901 
96,101 



1,036,940 
1,635,690 



716,338 



86,130 



72,172 
13,958 

31,413 



65,867 



3,552 
125,139 



186,230 



35,294 
22,337 



5,331 
17,006 



38 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 15A,--Plastics and resin materials: U.S. production and sales, by chemical classes 

and uses, 7567— Continued 



Kind and use 



Production 



Sales 



Quantity 



Value 



Unit 
value ■"• 



THERMOSETTING RESINS-- Continued 



Urea and melamine resins, total 

Textile treating and coating resins 

Paper treating and coating resins 

Bonding and adhesive resins for: 

Laminating 

Plywood 

Fibrous and granulated wood 

Protective coatings 

All other uses (including molding) 

Sales for export 

All other thermosetting resins^ 

THERMOPLASTIC RESINS 

Total 

Cellulose plastics materials, total 

Sheets, continuous: 

Under 0.003 gage 

0.003 gage and over 

All other sheets, rods, and tubes 

Molding and extrusion materials 

Polyamide resins: Nylon type 

Polyolef in plastics materials : 

Polyethylene, density 0.9A-C1 and below:^ 

Production and sales 

Sales and use, total 

Injection molding 

Blow molding 

Film and sheet 

Extrusion coating on paper and other substrates- 
Wire and cable 

All other extruded products, including pipe 

and conduit 

All other domestic uses 

Export sales 

Polyethylene, density over 0.940: 

■production and sales 

Sales and use, total 

Injection molding 

Blow molding 

Film and sheet 

Extrusion coating on paper and other substrates- 
Wire and cable 

Pipe and conduit 

Other extruded products 

All other domestic uses 

Export sales 

Polypropylene : 

■ Production and sales 

Sales and use, total 

Injection and blow molding^ 

Film and sheet 

Fibers and filaments 

Other extruded products^ 

All other uses 

Export sales 

See footnotes at end of table. 



1.000 
pounds, 

dry 
basL^~ 

690,062 



74,633 
60,007 

57,856 
128,471 
190,043 

55,962 
123,090 



45,536 



10,278,021 



171,380 



16,632 

43,184 

5,067 

106,497 

63,089 



. 2,716,380 



'1,082,176 



662,276 



1,000 
pounds, 

dry 
basis^ 

585,236 



1 . 000 
dollars 
135,769 



per 
pound 



$0.23 



66,295 
39,780 

35,313 
115,157 
176,370 

37,020 
101,546 

13,755 

44,784 



9,185,826 



24, 607 



1,956,292 



167,185 



109,237 



.55 



.21 
.65 



16,778 

44,175 

6,213 

100,019 

53,782 



2,538,688 

2,572,780 

352,669 

44,689 

1,094,354 

307,430 

264,950 

37,258 
214,264 
257,166 

919,960 

976,411 

217,172 

402,619 

38,485 

6,506 

34,561 

38,236 

20,685 

130,220 

87,927 

599,035 

650,146 

281,598 

56,139 

159,912 

39,763 

39,026 

73,708 



51,636 



373,897 



155,465 



128,086 



.96 



.15 



.17 



.21 



PLASTICS AND RESIN MATERIALS 



39 



TABLE 15A.- 



-Plastics ami resin materials ,■ U.S. production and sales, by chemical classes 
and uses, 1967 — Continued 



Kind and use 



Production 



Sales 



(Jiantity 



Value 



Unit 
value ■"■ 



THERMOPLASTIC RESINS— Continued 

Styrene type plastics materials, total 

ABS and SAN resins : ^° 

Production and sales 

Sales and use, total 

Molding 

Extrusion 

All other domestic uses 

Export sales 

Styrene and styrene copolymer resins: 

Production^^ and sales 

Sales and use, total 

Molding 

Textile and paper treating and coating 

Bnulsion paint 

Extrusion 

All other domestic uses (including foam and 

foamable materials) 

Export sales 

Vinyl resins (resin content): 

Polyvinyl chloride and copolymers: 

Production and sales, total 

Suspension homopolymers 

Suspension copolymers 

Dispersions (paste) 

Sales and use, total 

Calendering, except flooring 

Flooring : 

Calendered 

Coated 

Paper and textile coating, and other paper and 

textile uses 

Protective coatings and adhesives 

Wire and cable 

Extruded film and sheet 

Other extruded products 

Sound records 

Injection and blow molding 

Plastisol formulating and molding 

All other domestic uses 

Export sales 

Polyvinyl acetate : 

Production and sales, total 

Latexes 

Resins 

Sales and use, total 

Bnulsion paints 

Adhesives 

Paper treating 

Textile treating 

All other domestic uses 

Export sales 

Polyvinyl alcohol 

Other vinyl resins^^ 

All other thermoplastic resins-'--' 



1 , otm 

pounds ^ 

dry 
basts' 

2,391,103 



371,203 



2,019,900 



,1-42,438 

,303,<i59 

550,139 

288,840 



342,370 
223,375 
118,995 



43,484 
143,635 

519,690 



l.nno 

pounds, 

dry 
basis'^ 
2,161,466 



347,572 

367,030 

184,204 

99, 180 

51,973 

31,673 

1,813,894 
2,000,325 
1,003,361 

214,091 
37,196 

250,781 

420,103 
74,793 



1,927,942 



2,112,276 
394,952 

265,229 
52,294 

101,341 
72,445 

195,801 

102,502 

297,014 

105,247 

71,782 

77,770 

305,149 

70,750 

251,200 



310,525 

95,461 

116,971 

24,661 

7,695 

63,270 

2,467 

37,008 

95,788 

433,772 



1 , 000 
dot tars 
447,760 



Per 
pound 



$0.21 



114,072 



333,688 



.33 



.18 



302,110 



.16 



73,369 



16,236 
44,494 

254,002 



.29 



.44 
.46 



.59 



^ Calculated from rounded figures. 

^ For the purpose of this report, "dry basis" is defined as the total weight of the material, including resin, 
plasticizers, fillers, extenders, colors and stabilizers, and excluding water, solvents, and other liquid diluents. 

^ Includes 3,532 thousand pounds sold for export. 

* The term "polyester resins" includes unsaturated alkyds copolymerized with a monomer such as styrene, and 
polyallyl resins such as diallyl phthalate and allyl diglycol carbonate. 



40 SYNTHETIC ORGANIC CHEMICALS, 1967 

Footnotes for table iSA- -Continued 

^ Includes data for acetone -formaldehyde resins, stjrrene-alkyd polyesters, toluenesulfonamide resins, silicone 
resins, and other thermosetting resins which were produced in small quantities. Also included are saturated poly- 
esters for urethanes. 

^ Represents data for polyethylene produced by the high-pressure process and for ethylene copolymers. 

'^ Represents production of polyethylene by the low-pressure process. 

* Principally for injection molding. 

^ Includes data for extrusion coating, wire and cable coating, pipe and conduit, and other extruded products. 

^° ABS resins are polymers of acrylonitrile, styrene, and butadiene. SAN resins are polymers of styrene and 
acrylonitrile. 

^^ Includes straight polystyrene, 850 m-.lion pounds; rubber-modified polystyrene, 746 million pounds; styrene- 
butadiene copolymers, 289 million pounds; and all other, 135 million pounds. 

^.^ Includes data for polyvinyl butyral, polyvinyl formal, and polyvinylidene chloride. 

'■^ Includes data for acrylic, fluorocarbon, non-nylon type polyamide, polycarbonate, polyoxymethylene, polyterpene, 
and other thermoplastic resins. 

monthly reports, and also some adjusted figures supplied by the original reporting companies. 
Consequently, many of the figures given in table 15A are revised from those shown in the Conn- 
mission's monthly release dated March 15, 1968, which contained year-end cumulative monthly 
totals for 1967. The end use breakdowns shown were developed with the advice of representatives 
of the plastics industry, and the data reported are the producers' determination of the use 
categories for their materials. 

Total U.S. production of synthetic plastics and resin materials in 1967 amounted to 
13, 793 million pounds- -slightly more than the 13, 585 million poiinds reported for 1966. Sales 
in 1967 were 11,977 million pounds, valued at $2,673 million. Production of benzenoid plastics 
and resin materials in 1967 amounted to 5,033 million pounds and that of nonbenzenoid materials 
to 8, 759 million pounds. These figures compare with the benzenoid production in 1966 of 5, 067 
million pounds, and nonbenzenoid production of 8, 518 million pounds. 

The 1967 output of all types of thermosetting resins totaled 3,515 million pounds, compared 
with 3, 647 million pounds in 1966. In 1967 phenolic and other tar acid resins were produced in 
the largest quantity in the thermosetting group. Output of phenolic resins amounted to 983 mil- 
lion pounds in 1967, compared with 1,047 million pounds in 1966. Production of urea and 
melamine resins in 1967 was 690 million pounds, and that of alkyd resins was 638 million 
pounds. Other thermosetting resins produced in significant amounts in 1967 were polyester 
resins (513 million pounds); coumarone-indene resins (284 million pounds); epoxy resins (131 
million pounds); and polyurethane resins (89 million pounds). 

The total output of thermoplastic resins in 1967 amounted to 10,278 million pounds, com- 
pared with 9,938 million pounds in 1966. In 1967, as in previous years, polyethylene, polysty- 
rene, and polyvinyl chloride were the resins produced in the largest volume. The output of high- 
pressure polyethylene in 1967 was 2, 716 million pounds, which corresponds to the output of 
2,648 million pounds reported for 1966. Production of low-pressure polyethylene in 1967 was 
1,082 million pounds, corresponding to the 910 million pounds produced in 1966. 

Rubber -Processing Chemicals 

Rubber-processing chemicals are organic compounds that are added to natural and synthetic 
rubbers to give them qualities necessary for their conversion into finished rubber goods. In this 
report, statistics are given for cyclic and acyclic compounds, by use--such as accelerators, 
antioxidants, blowing agents, and peptizers. Statistics on production and sales of rubber-pro- 
cessing chemicals in 1967 are given in table 16A.^ 

Production of rubber-processing chemicals as a group in 1967 amounted to 264 million 
pounds, or 6.8 percent less than the 283 million pounds reported for 1966, The decreased out- 
put of rubber-processing chemicals in 1967 is attributable principally to a lengthy strike in the 
rubber industry during the year. Sales of rubber-processing chemicals in 1967 amounted to 201 
million pounds, valued at $132 million, compared with 209 million pounds, valued at $138 
million, in 1966. 

The output of cyclic rubber-processing chemicals in 1967 amounted to 220 million pounds, 
8.8 percent less than the 241 million pounds reported for 1966. Sales in 1967 were 170 mil- 
lion pounds, valued at $116 million, compared with 183 million pounds, valued at $124 mil- 
lion, in 1966. Of the total output of cyclic rubber-processing chemicals in 1967, accelerators 
accounted for 31.4 percent and antioxidants for 63.2 percent. Production of antioxidants, which 
amounted to 139. 1 million pounds in 1967, included 108.0 million pounds of amino compounds 
and 31. 1 million pounds of phenolic and phosphite compounds. Sales of amino antioxidants in 1967 



See also table 16B, pt. Ill, which lists these products and Identifies the manufacturers. 



RUBBER-PROCESSING CHEMICALS 



41 



TABLE 16A. - - Rubber-process ing chemicals: U.S. production and sales, 1967 

[Listed below are all rubber-processing chemicals for which any reported data on production or sales may be pub- 
lished. (Leaders are used where the reported data are accepted in confidence and may not be published or where no 
data were reported. ) Table 16B in pt. Ill lists separately all rubber-processing chemicals for which data on pro- 
duction or sales were reported and identifies the manufacturer of each] 



Chemical 



Production 



Sales 



Quantity 



Value 



Grajid total 

RUBBER- PROCESSING CHa^.ICALS, CYCLIC 



Total- 



Accelerators, activators, and vulcanizing agents, total- 

Aldehyde-amine reaction products 

Dithiocarbamic acid derivatives 

Thiazole derivatives, total 

N-Cyolohexyl-2-benzothiazolesulfenamide 

2, 2 '-Dithiobis(benzo thiazole ) 

2-Mercaptobenzo thiazole 

All other thiazole derivatives 

All other accelerators 



Antioxidants, antiozonants, and stabilizers, total 

Amino compounds, total 

Octyldiphenylamine 

N-Phenyl-2-naphthylajrd.ne 

Substituted p-phenylenediamines, total 

N, N'-Diphenyl-p-phenylenedi amine 

All other substituted p-phenylenediamines 

All other amino antioxidiants, antiozonants, and 

stabilizers 

Rienolic and phosphite antioxidants and stabilizers, 

total 

Phenol, alkylated 

Polyphenolics (including bisphenols) 

All other phenolic and phosphite antioxidants and 

stabilizers 



Blowing agents- 
Peptizers 



All other cyclic rubber-processing chemicals 

RUBBER- PROCESSING CHEMICALS, ACYCLIC 



Total- 



Accelerators, activators, and vulcanizing agents, total- 

Dithiocarbamic acid derivatives, total-' 

Dibutyldithiocarbamic acid, sodium salt 

Dibutyldithiocarbamic acid, zinc salt 

Diethyldithiocarbamic acid, zinc salt 

Dimethyldithiocarbamic acid, zinc salt 

All other dithiocarbamic acid derivatives 

Thiurams, total* 

Bis(diethylthiocarbamoyl) disulfide 

Bis(dimethylthiocarbamoyl) disulfide 

Bis(dlmethylthiocarbamoyl) sulfide 

All other thiurams 

All other accelerators, activators, and vulcanizing 
agents 



Dimethyldithiocarbamic acid, sodium salt 

Dodecyl mercaptans 

All other acyclic rubber-processing chemicals '- 



1.000 
pounds 

264,133 



220, 139 



69, 161 



1,217 

238 

56, 674 

4,686 
21, 934 

4,665 
25,389 
11,032 

139,083 



108, 017 
2,844 
5,478 

47,711 
3,151 

44,560 

51, 984 

31,066 
9,953 

8,188 

12, 925 

3,237 
5,731 

2,927 
43,994 



21,493 



6,796 

919 

1,555 

1,135 

1,644 

1,543 

14,310 

3,157 

8,681 

2,251 

221 

387 

5,483 

12,659 

4,359 



1 . oon 

pounds 
200, 848 



169, 970 



55,619 



1,014 

199 

43,427 

3,446 
10,571 

29,410 
10, 979 

103,374 



80,351 
2,775 

33,794 

1,308 

32,486 

43,782 

23,023 
6,282 
7,095 

9,ey46 

3,364 
5,309 

2,304 
30,878 



15,316 



5,880 

1,417 

913 

1,588 

1,962 

9,184 

685 

6,704 

1,571 

224 

252 

1,651 

11,248 

2,663 



1,000 
dol lars 
131,795 



116,318 



34,035 



919 

455 

24, 100 

2,134 

5,967 

15,999 
8,561 

72,461 



55,613 
1,463 

30,944 

1,413 

29, 531 

23,206 

16,848 
3,402 
8,273 

5,173 

5,156 
3,236 

1,430 
15,477 



9,285 



4,508 

1,392 

537 

752 

1,827 

4,474 

405 

2,736 

1,220 

113 

303 

784 
4,205 
1,203 



^ Calculated from rounded figures. 

Includes retarders, tacklfiers, and physical-property improvers. 

Data on dithiocarbamates included in this table are for materials used chiefly in the processing of natural and 
synthetic rubbers. Data on dithiocarbamates which are used chiefly as fungicides are included in table 20A, "Pesti- 
cides and Related Products". 

Includes data for small amounts of tetramethylthiuram sulfides for uses other than in the processing of natural 
and synthetic rubbers. 

Includes blowing agents, polymerization regulators, shortstops, and conditioning and lubricating agents. 



42 



SYNTHETIC ORGANIC CHEMICALS, 1967 



were 80. 4 million pounds, valued at $55. 6 million; sales of phenolic and phosphite antioxidants 
were 23. million pounds, valued at $16. 8 million. 

Production of acyclic rubber-processing chemicals in 1967 amounted to 44. million pounds, 
an increase of 4. 5 percent over the 42. 1 million pounds reported for 1966. Sales in 1967 totaled 
30. 9 million pounds, valued at $15. 5 million, compared with 26. 5 million pounds, valued at 
$14. 6 million, in 1966. Accelerators, principally dithiocarbamic acid derivatives and tetrame- 
thylthiuram sulfides, accounted for 48. 9 percent of the output of acyclic rubber-processing 
chemicals for 1967. Dodecyl mercaptans accounted for 28. 8 percent. Blowing agents, modifiers, 
shortstops, and lubricating and conditioning agents accounted for the remainder of the output of 
acyclic compounds. 

Elastomers (Synthetic Rubbers) 



Elastomers are a group of high polymeric materials which have properties similar to those 
found in natural rubber. The term "elastomers", as used in this report, is specifically defined 
as substances in bale, crumb, powder, latex, and other crude forms, which can be vulcanized or 
similarly processed into materials that can be stretched to at least twice their original length 
and, after having been so stretched and the stress removed, will return with force to approxi- 
mately their original length. Statistics on production and sales of elastomers are given in table 
HA." 

The total domestic output of all types of synthetic elastomers in 1967 was 3, 823, million 
pounds, compared with 3, 929 nnillion pounds reported for 1966. Sales of these elastomers 
amounted to 3, 262 million pounds, valued at $874 million, in 1967, compared with 3,411 mil- 
lion pounds, valued at $918 million, in 1966. 

Production of cyclic elastomers in 1967 amounted to 2, 298 million pounds, connpared with 
2,482 million pounds in 1966. Sales of cyclic elastomers in 1967 were 1,940 million pounds, 
valued at $440 million, compared with 2, 108 million pounds, valued at $463 million, in the 

TABLE n A, --Elastomers (synthetic rubbers).-^ U.S. production and sales , 1967 

[Listed below are all elastomers (synthetic rubbers) for which reported data on production or sales may be pub- 
lished, (Leaders are used where the reported data are accepted in confidence and may not be published or where 
no data were reported. ) Table 17B in pt. Ill lists all elastomers for which data on production or sales were 
reported and identifies the manufacturer of each] 



Product 



Production 



Sales 



Quantity 



Value 



Unit value ^ 



Grand total 

ELASTOMERS, CYCLIC 
Total 

Polybutadiene-styrene type (S-type)-* 

Polybutadiene-styrene-vinylpyridine type-- 
Polyurethane type 

ELASTOMERS, ACYCLIC 
Total 

Polybutadiene-acrylonitrile type (N-type)- 

Polyisobutylene-isoprene type (Butyl) 

Silicone elastomers 

Stereo elastomers, total 

Stereo polybutadiene 

All other stereo elastomers 

All other acyclic elastomers^ 



1,000 

pounds 

3,g22, 5.^5 



1.000 

pounds 

3,262,0^^ 



1,000 
dol lars 

57i,237 



Per 
pound 



.27 



2,297,637 



1,9^0,099 



439,580 



.23 



2,253,337 
21,185 
13,115 



1,524,908 



•1,918,267 
10,353 
11,479 



1,321,945 



422,065 

6,040 

11,475 



434,657 



.22 

.58 

1.00 



.33 



138,290 

255,117 

9,518 

688,609 



128,953 

8,447 
533,004 



59,789 

28,384 
109, 535 



.46 

3.36 
.21 



451,503 
237, 106 

433,374 



354, 544 
178,460 



651,541 



68,067 
41,468 

236,949 



.19 
.23 



.36 



The term elastomers Is defined as substances in bale, crumb, powder, latex, and other crude forms which can be 
vulcanized or similarly processed into materials that can be stretched at 68° F. to at least twice their original 
length and, after having been so stretched and the stress removed, will return with force to approximately their 
original length. ^ Calculated from rounded figures. ^ Elastomer-content basis. * Partly estimated. ' Includes 
data for polyacirylate, polyalkalene sulfide, polychloroprene, polyisobutylene and other elastomers, and for sales of 
polyisobutylene-isoprene elastomers. 



Note. — Statistics on the production of S-type, 
cooperation with the U.S. Bureau of the Census. 



N-type, Butyl, neoprene, and stereo elastomers were compiled in 



'See also table 17B, pt. Ill, which lists these products and identifies the manufacturers. 



PLASTICIZERS 



43 



previous year. Of the total U.S. production of cyclic elastomers in 1967, the polybutadiene- 
styrene type (including vinylpyridine) accoixnted for 2, 285 million pounds, and the polyurethane 
type for 13 million pounds. 

The U.S. production of acyclic elastomers in 196>7 was 1, 525 million pounds, compared with 
1,447 million pounds in 1966. Sales of these products in 1967 amounted to 1,322 million pounds, 
valued at $435 million. Of the 1967 production of acyclic elastomers, stereo elastomers were 
produced in the largest amount (689 million pounds), followed by the polyisobutylene-isoprene 
type (255 million pounds), and the polybutadiene-acrylonitrile type (N-type) (138 million pounds). 
The stereo elastomers are composed principally of poly butadiene, polyisoprene, and ethylene- 
propylene rubber. Production of silicone elastomers in 1967 was 9. 5 million pounds and of 
other acyclic elastomers was 433 nnillion pounds. The latter figure includes polyacrylate, poly- 
alkalene sulfide, polychloroprene, polyisobutylene, and types of other elastomers of lesser im- 
portance. 

Plasticizers 

Plasticizers are organic chemicals that are added to synthetic plastics and resin materials 
to (1) improve workability during fabrication, (2) extend or modify the natural properties of 
these resins, or (3) develop new improved properties not present in the original resins. Plas- 
ticizers reduce the viscosity of the resins and make it easier to shape and form them at high 

TABLE 18A.-- Plasticizers:^ U.S. production arui sales, 1967 

[Listed below are all plasticizers for which reported data may be published. (Leaders are used where the reported 
data are accepted in confidence and may not be published or where no data were reported. ) Table 18B in pt. Ill 
lists all plasticizers for which data on production or sales were reported and identifies the manufacturer of 
each] 



Chemical 



Production 



Sales 



Quantity 



Value 



Unit 
value^ 



Grand total 

PLASTICIZERS, CYCLIC 

Total 

Phosphoric acid esters: 

Cresyl diphenyl phosphate 

Tricresyl phosphate 

Triphenyl phosphate 

Phthalic aihydride esters, total 

Butyl ootyl phthalates (including butyl 2-ethylhexyl 

phthalate) 

Dibutyl phthalate 

Dicyclohexyl phthalate 

Diethyl phthalate 

Dilsodeoyl phthalate 

Di(2-methoxyethyl) phthalate 

Dimethyl phthalate 

Diootyl phthalates, total 

Di( 2-ethylhexyl) phthalate 

Diiso-octyl phthalate 

Mixed dioctyl phthalates (including dioapryl phthalate 

and dioctyl isophthalates ) 

Di-tridecyl phthalate 

Glycolate phthalate esters 

n-Octyl n-decyl phthalate 

All other phthalic anhydride esters 

Trimellitio acid esters, total 

Trioctyl trimellitate 

All other trimellitio acid esters 

All other cyclic plasticizers"^ 

See footnotes at end of table. 



1.000 
pounds 

1, 262, 779 



929,871 



18,229 

42,885 

8,741 

783,876 



16,482 

25,238 

4,981 

20,830 

123,133 

6,754 

4,549 

405,414 

293,243 

98,066 

14, 105 

18,209 

4,939 

40,721 

112,626 

6,252 



2,180 
4,072 

69,888 



1.000 

pounds 

1,161,851 



1 . mo 

dot tars 
260, 969 



865,084 



18,483 
40,335 

733,620 



15, 678 
22,801 

16, 262 

109,852 

5,50; 

4,059 

387,059 

277,741 

97,308 

12,010 

18,399 

4,637 

33,229 

116, 140 

5,693 



2,050 
3,643 

66,953 



167,827 



5,190 
12,679 

125,240 



2,761 
4,310 

3,033 
18,011 

1,495 

829 

60, 843 

43,107 

15,646 

2,090 
4,333 
1,819 
6,190 
21, 616 

2,544 



860 
1,684 

22, 174 



per 
fioand 



$0.22 



.19 



.28 

.31 



.17 



.18 
.19 

.19 
.16 
.27 
.20 
.16 
.16 
.16 

.17 
.24 
.39 

.19 
.19 

.45 
.42 
.46 

.33 



44 



SYNTHETIC ORGANIC CHEMICALS, 1967 
TABLE 18A.--Plasticizers :^ U.S. production and sales, i 96 7- -Continued 



Chemical 



Production 



Sales 



Quantity 



Value 



Unit 
value ^ 



PLASTICIZERS, ACYCLIC 

Total 

Adipic acid esters, total 

Di{2-(2-butoxyethoxy )ethyl) adipate 

Di(2-ethylhexyl ) adipate 

Diisodeoyl adipate 

n-Octyl n-decyl adipate 

All other 

Azelaio acid esters 

Complex linear polyesters and polymeric plastioizer*- 

Epoxidized esters, total 

IJjoxidized soya oils 

2-Ethylhexyl epoxytallates 

Octyl epoxytallates 

All other 

Isopropyl iHyTistate 

Isopropyl palmitate 

Oleic acid esters, total 

Butyl oleate 

Glyceryl trioleate (Triolein) 

Methyl oleate 

Propyl oleates (including normal and iso) 

All other 

Phosphoric acid esters 

Ricinoleic acid esters: 

Butyl ricinoleate 

Glyceryl monorioinoleate 

Sebaoic acid esters: 

Di butyl sebacate 

Di(2-ethylhexyl) sebacate 

Stearic acid esters, total 

n-Butyl stearate 

All other 

Triethylene glycol di(oaprylate-caprate) 

All other acyclic plasticizers^ 



1,000 
pounds 

332,908 



65, 694 



1,610 
31,496 
10, 871 

8,911 
12,806 

17,543 
44,954 

91,517 



62,164 

15, 074 
14,279 

1,051 
720 

11,008 



2,716 

"2,410 
1,189 
4,693 

18,069 



987 

214 



4,684 
6,914 

7,313 



3,893 
3,420 

1,14^ 
61,096 



1.000 
pounds 

296,767 



1 . 000 
dol iars 



57, 628 



1,554 

24, 834 

9,879 

9,002 

12,359 

17,419 
43,256 

83,247 



56,422 
9,666 

14,010 
3,149 

1,400 
811 

8,414 



1,801 
2,797 

852 
2,964 

15,446 



209 



3,306 
6,299 

6,603 



3,337 
3,266 

1,149 

51, 580 



93,142 



15,812 



734 
6,054 
2,670 
2,193 

4,161 

4,966 
16,386 

22,261 



14,960 
2,369 
3,631 
1,301 

606 
305 

2,063 



389 
668 

183 
823 

6,558 



84 



1,959 
3,124 

1,662 



793 
869 



415 
16,941 



Per 
pound 



$0.31 



.27 



.47 
.24 
.27 
.24 
.34 

.29 
.38 

.27 
.26 
.24, 
.26 

.41 

.43 
.38 

.25 
.22 
.24 

.21 
.28 

.42 



.40 



.59 
.50 

.25 
.24 
.27 



.36 
.33 



Does not include data, for clearly defined extenders or secondary plasticizers, 

^ Calculated from rounded figures. 

^ Includes data for alkylated naphthalene, glycol dibenzoates, hydrogenated terphenyls, phosphate esters (includ- 
ing sales of triphenyl phosphate), toluenesulfonamides, tetrahydrofurfuryl oleate, and other cyclic plasticizers. 

* Adipic acid polyesters account for most of the production of complex linear polyesters and polymeric 
plasticizers. 

' Includes data for citric and acetyloitrio, laurio, norristic, palmitic, pelargonio, ricinoleic, sebacic, and 
tartaric acid esters, glyceryl and glycol esters, and other acyclic plasticizers. 

Note. — The total production and sales statistics are included in this report for some items that are not used 
exclusively as plasticizers. 



temperatures and pressures. They also impart flexibility and other desirable properties to the 
finished product. Statistics on production and sales of plasticizers are given in table 18A"''°. 

Total U.S. production of plasticizers in 1967 amounted to 1,263 million pounds- -represent- 
ing an increase of 4.4 percent over the output of 1,209 million pounds reported for 1966. Sales 
in 1967 of the plasticizers covered by this report amounted to 1, 162 million pounds, valued at 
$261 million, compared with 1, 156 million pounds, valued at $246 million in 1 966- -increases 
of 0. 5 percent in quantity and 6. 1 percent in value. 

Production of cyclic plasticizers in 1967, which consisted chiefly of the esters of phthalic anhy- 
dride and phosphoric acid, amounted to 930 million pounds, compared with 897 million pounds in 1 966. 



SURFACE-ACTIVE AGENTS 



45 



Sales of cyclic plasticizers in 1967 amounted to 865 million pounds, valued at $168 million, compared 
with 873 million pounds, valued at $157 million, in the previous year. This represents a decrease in 
salesquantityofO. 9percent, andanincreasein sales value of 7.0 percent. 

Production of acyclic plasticizers in 1967 amounted 333 million pounds, compared with 
31Z million pounds in 1966. Sales of acyclic plasticizers in 1967 amounted to 297 million 
pounds, valued at $93 million, compared with 283 million pounds, valued at $89 million, in 
1966. Production of complex linear polyesters in 1967 amounted to 45 million pounds, and that 
of epoxidized esters, to 92 million pounds. Among the other products included in the acyclic 
class are the esters of adipic, azelaic, oleic, sebacic, and stearic acids. 

Surface -Active Agents 

The surface-active agents included in this report are organic chemicals that reduce the sur- 
face tension of water or other solvents and are used chiefly as detergents, dispersing agents, 
emulsifiers, foaming agents, or wetting agents in either aqueous or nonaqueous systems. Waxes 
and products used chiefly as plasticizers are excluded. Surface-active agents are produced from 
natural fats and oils; from silvichemicals such as lignin, rosin, and tall oil; and from chemical 
intermediates derived from coal-tar and petroleum. A major part of the output of the bulk 
chemicals shown in this report is consumed in the form of packaged soaps and detergents for 
household and industrial use. The remainder is used in the processing of textiles and leather, in 
ore flotation and oil-drilling operations, and in the manufacture of agricultural sprays, cosmetics, 
elastomers, foods, lubricants, paints, pharmaceuticals, and many other products. 

TABLE 19A. --Surface-active agents.- U.S. production and sales, 1967 

[Listed below are all surface-active agents for which reported data on production or sales may be published. 
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data 
were reported. ) Table 19B in pt. Ill lists all surface-active agents for which data on production or sales were 
reported and identifies the manuf actxirer of each] 



Chemical 



Production"'' 



Sales ^ 



Quantity 



Value 



Unit value^ 



Grand total- 

Benzenoid* 

Nonbenzenoid' 



1,000 
pnunds 
3,479,295 



1 . 0(10 
pounds 

1,750,024 



1 . 000 
dol I ars 
316,687 



Per 

found 

$0.18 



Amphoteric Surface -Active Agents - 
Anionic Surface-Act lie Agents 



Total- 



964,779 
2,514,516 

6,639 
2,614,456 



414,179 
1,335,845 

6,510 

1,087,783 



79, 144 
237, 543 

4,014 
148,950 



.19 

.18 



.62 



.14 



Carboxylic acids (and salts thereof), total 

Amine salts of fatty, rosin, and tall oil acids 

Carboxylic acids having amide, ester, or ether link- 
ages, total 

N-Lauroylsarcosine, sodium salt 

All other 

Potassium and sodium salts of fatty, rosin, and tall 

oil acids, total 

Coconut oil acids, potassium and sodium salts 

Corn oil acids, potassium salt 

Corn oil acids, sodium salt 

Mixed vegetable fatty acids, potassium salt 

Oleic acid, potassium salt 

Oleic acid, sodium salt 

Stearic acid, potassium and sodium salts 

Tall oil acids, potassium and sodium salts, total — 

Potassium salt 

Sodium salt 

Tallow acids, potassium salt 

Tallow acids, sodium salt 

All other 

See footnotes at end of table. 



1,044,035 



923 

22,476 

3,079 

19,397 

1,020,636 

127,098 

452 

725 

2,859 

1,149 

1,806 

3,183 

21,700 

11, 734 

9,966 

45,174 

533,126 

283,364 



346 
6,283 
6,283 



2,804 
456 
720 

2,702 
476 

1,535 

681 

13,327 



27,095 



147 
4,006 
4,006 



1,146 
151 
214 

2,077 
110 
303 
245 

2,754 



3,606 



.42 
.64 
.64 



.41 
.33 
.30 
.77 
.23 
.20 
.36 
.21 



.13 



See also table 18B, pt. III, which lists these products and identifies the manufacturers. 



46 



SYNTHETIC ORGANIC CHEMICALS, 1967 
TABLE I'ih. --Surface-active agents : U.S. production and sales , ^567-. Continued 



Chemical 



Produotion-"- 



Sales'^ 



Quantity ■'■ 



Value 



Anionic Surface -Ac t lie .4genfs--Continuod 

Phosphoric and polyphosphorio acid esters (and salts 

thereof ), total 

Alcohols and phenols, ethoxylated and phosphated, total 

Mixed linear alcohols, ethoxylated and phosphated 

Nonylphenol, ethoxylated and phosphated 

Tridecyl alcohol, ethoxylated and phosphated 

All other 

Alcohols, phosphated or polyphosphated, total 

2-Ethylhexyl phosphate, sodiiiin salt 

Octyl phosphates 

All other 

Sulfonic acids (and salts thereof), total 

Alkylbenzenesulfonates, total 

Dodecylbenzenesulfonates, total 

Dodecylbenzenesulfonic acid 

Dodecylbenzenesulfonic acid, calcium salt 

Dodecylbenzenesulfonic acid, isopropanolaraine salt — 

Dodecylbenzenesulfonic acid, isopropylamlne salt 

Dodecylbenzenesulfonic acid, sodium salt 

Dodecylbenzenesulfonic acid, triethanolamine salt 

All other 

Other alkylbenzenesulfonates, total 

Tridecylbenzenesulfonic acid 

All other 

Benzene-, cumene-, toluene-, and xylenesulfonates, total 

Xylenesulfonic acid, ammonium salt 

)!ylenesulfonic acid, sodium salt 

All other 

Ligninsulfonates, total 

Ligninsulfonio acid, calcium salt 

Ligninsulfonic acid, chromium salt 

Ligninsulfonic acid, sodium salt 

All other 

Naphthalenesulfonates, total 

Butylnaphthalenesulfonic acid, sodium salt 

Diisopropylnaphthalenesulfonic acid and sodium salt 

All other 

Sulfonic acids having amide linkages, total 

N-Methyl-N-oleoyltaurine, sodium salt 

Sulfosuccinamio acid derivatives 

All other 

Sulfosuccinic acid esters, total 

Sulfosuccinic acid, bis(2-ethjlhexyl) ester, sodium 

salt 

All other 

All other sulfonic acids 

Sulfuric acid esters (and salts thereof): 

Acids, amides, and esters, sulfated, total 

Coconut oil acids - ethanolamine condensate, sulfated, 

potassium salt 

Esters of sulfated oleic acid, total 

Butyl oleate, sulfated, sodium salt 

Isopropyl oleate, sulfated, sodium salt 

Propyl oleate, sulfated, sodium salt 

All other 

Oleic acid, sulfated, disodium salt 

Tall oil, sulfated, sodium salt 

All other 

See footnotes at end of table. 



1.000 

pounds 
15,110 



9,183 

<W9 

3,418 

392 

<1,924 

5,927 

164 

2,720 

3,043 



651, i92 

537, 541 

101,877 

9,724 

423 

2,507 

416,982 

3,568 

2,460 

113,951 

703 

113,248 

59,096 

11,325 

26,841 

20,930 

453,665 

284,246 

19,975 

45,378 

104,066 

10,615 

201 

482 

9,932 

4,762 

2,587 

1,030 

1,145 

8,035 

5,350 
2,685 



23,469 



1,000 
pounds 

12,306 



1.000 

dol lars 



6,446 



7,854 

386 

2,442 

368 

4,658 

4,452 

124 

2,607 

1,721 

664, 117 



139,229 

128,218 

31, 994 

6,840 

2,985 

81,781 

3,038 

1,580 

11,011 

444 

10, 567 

53,462 

13,277 

15,522 

24,663 

438,059 

268,713 

20, 267 

45,417 

103,662 

7,027 

176 

441 

6,410 

3,953 

2,675 

775 

503 

7,641 

5,1?4 

2,517 

14,746 



15,768 





20 


23 


7,861 


4,960 


1,394 


4,164 


2,658 


646 


391 


348 


125 


538 


524 


188 


2,768 


1,430 


435 


9,712 


> < . 


• . . 


841 


772 


183 


5,055 


10,016 


2,747 



3,725 

116 

850 

157 

2,602 

2,721 

37 

1,494 

1,190 

63, 174 



23,809 

22,229 

4,426 

2,572 

901 

13,044 

825 

461 

1,580 

56 

1,524 

4,765 

1,017 

1,512 

2,236 

16, 666 

6,661 

1,850 

3,604 

4,551 

2,729 

43 

256 

2,430 

2,393 

1,449 

642 

302 

4,092 

2,845 
1,247 
8,720 



4,347 



SURFACE ACTIVE AGENTS 



47 



TABLE 19A. --Surface-active agents: U.S. production and sales, i5(57--Continued 



Chemical 



Production-'- 



Sales'^ 



Quantity-'- 



Value 



Unit 
value^ 



Anionic Surface-Active Agcn(s--ContinLed 

Sulfuric aold esters (and salts thereof) — Continued 

Alcohols and phenols, sulfated, total 

Coconut and sperm oil alkyl sulfate, sodium salt 

Dodeoyl sulfate salts, total 

Dodecyl sulfate, ammonium salt 

Dodecyl sulfate, magnesium salt 

Dodecyl sulfate, sodium salt 

Dodecyl sulfate, triethanolamine salt 

All other 

Hexadecyl sulfate, sodium salt 

Mixed linear alcohol sulfate salts 

Octadecyl sulfate salts 

All other 

Ethers, sulfated, total 

Alkylphenols, ethoxylated and sulfated 

Dodecyl alcohol, ethoxylated and sulfated, ammonium 

salt 

Dodecyl alcohol, ethoxylated and sulfated, sodium 

salt 

Mixed linear alcohols, ethoxylated and sulfated, 

sodium salt 

Tridecyl alcohol, ethoxylated and sulfated, sodium 

salt 

All other 

Natural fats and oils, sulfated, total 

Animal (including fish) oils, sulfated, total 

Cod oil, sulfated, sodium salt 

Neat's-foot oil, sulfated, sodium salt 

Sperm oil, sulfated, sodium salt 

Tallow, sulfated, sodium salt 

All other 

Vegetable oils, sulfated, total 

Castor oil, sulfated, sodium salt 

Coconut oil, sulfated, sodium salt 

Rlcebran oil, sulfated, sodium salt 

Soybean oil, sulfated, sodium salt 

All other 

Other anionic surface-active agents* 

Cationic'Surf ace-Active Agents 
Total 

Amine oxides and oxygen-containing amines (except those 
having amide linkages), total 

Acyclic, total 

(Coconut oil alkyl )amine, ethoxylated 

(Mixed alkyl )amine, ethoxylated 

(Soybean oil alkyl )amine, ethoxylated 

(Tallow alkyl )amine, ethoxylated 

All other 

Imidazoline and oxazoline derivatives, total 

2-(8-Heptadecenyl)-l-(2-hydroxyethyl)-2-imldazoline- 

2-Heptadeoyl-l-(2-hydroxyethyl)-2-imidazoline 

All other 

Cyclic products (except imidazoline and oxazoline 

derivatives ), total 

Rosin amine, ethoxylated 

All other 

See footnotes at end of table. 



1,000 
pounds 

908 

42,048 

2,407 

246 

16,410 

8,931 

14,054 

117 

967 



132,758 
3,696 

1,139 

3,423 

2,770 

832 

120,898 

32,296 

20, 669 

1,940 

1,172 

6,510 

10,004 

l,Oi3 

11,627 

6,998 

2,350 

151 

257 

1,871 

135,083 



154,021 



39,445 



1 , nor) 

pounds 
29, 990 
821 



122 

986 

264 

27,797 

3,416 



1,304 

2,407 

832 

19, 928 

14,678 

1,592 

473 
4,065 
7,566 

982 
5,250 
4,079 

708 

136 
327 

281,290 



122,672 



17, 690 



I'er 

pound 

12,981 
426 



68 

189 

173 

12,125 

1,133 



669 

504 

287 

3,857 

2,186 

215 

97 

672 

990 

212 

1,671 

1,351 

167 

49 
104 

40, 793 



48,017 



7,445 



32,700 


12, 571 


5,391 


2,734 


2,720 


932 


3,741 


. . . 


> . < 


936 


989 


366 


1,342 


1,415 


785 


23,947 


7,447 


3,308 


4,040 


3,091 


1,513 


175 






155 


> • • 


< • < 


3,700 


3,091 


1,513 


2,705 


2,028 


541 


1,037 


• • > 




1,668 


2,028 


541 



48 SYNTHETIC ORGANIC CHEMICALS, 1967 

TABLE 19A. -Surface-active agents : U.S. production and sales, 1967 --Contimjed 



Chemical 



Prcduction"^ 



Sales'^ 



Quantity-"- 



Value 



Cationic Surface-Active 4genf 5 --Continued 

Amines and amine oxides having ajnide linkages, total 

Carboxylic acid - diamine and polyajnine condensates, 

total 

Coconut oil acids - diethylenetriamine condensate 

Coconut oil acids - N, N-dimethyltrimethylenediamine 

condensate 

Stearic acid - diethylenetriamine condensate 

All other 

Stearic acid - ethylenediamne condensate, mono- 

ethoxylated 

Other amines and amine oxides having amide linkages 

Amines, not containing oxygen (and salts thereof), total— 

Amine salts 

Diamines and polyamines, total 

N-( Coconut oil alkyl)trimethylenediamine 

N-C9-Ciotadecenyl)trimethylenediamine 

N-( Tallow alkyl)trimethylenediainine 

All other 

Primary monoamines, total 

(Coconut oil alkyl)ainine 

(Ifydrogenated tallow alkyDamine'' 

9-Octadecenylamine 

Ootadecylamine 

(Tall oil alkyl)amine 

(Tallow alkyl)amine 

All other 

Secondary and tertiary monoamines, total 

N,N- Dimethyl (coconut oil alkyl )amine 

N, N-Dimethyloctadecylamine 

N-Methylbis(hydrogenated tallow alkyl )amine 

All other 

Oxygen-containing quaternary ammonium salts (except those 

having amide linkages), total 

Acyclic 

Cyclic 

Quaternary ammonium salts having amide linkages 

Quaternary ammonium salts, not containing oxygen, total — 

Acyclic, total 

Bis(coconut oil alkyl )dimethylammoniiim chloride 

Bis(hydrogenated tallow alkyl )dimethylamironium 

chloride 

(Coconut oil alkyl ) trlmethylammonium chloride 

Hexadecyltrimethylammonium salts 

All other 

Benzenoid, total 

Benzyl ( coconut oil alkyl )dimethylammoniujn chloride 

Benzyldimethyl (mixed alkyl )ammonium chloride 

Benzyldodecyldimethylammonium chloride 

(3,4-Dichlorobenzyl )dodecyldimethylaramonium chloride — 
All other 

l^onionic Surface-Active Agents 

Total 

Carboxylic acid amides, total^ 

Carboxylic acid - alkanolamine condensates, total 

Diethanolamine condensates (amine/acid ratio=2/l), 

total 

Capric acid 

Coconut oil acids 



1 . nno 

pounds 
13,975 



8,092 



92 

7,606 

2,081 
3,802 

A8, 509 
2,907 

11,689 
1,105 
1,611 
3,625 
5,348 

21,633 

1,687 

2,583 

1,588 

695 



5,165 

9,915 

12,280 

2,045 

300 

9,935 



2,792 



1,196 
1,596 

4,726 

44,574 



34,885 
1,149 

20, 675 

668 

12,393 

9,689 

288 

4,078 

568 

42 

4,713 



704, 179 



91,545 



91,151 

26,945 

106 

12,821 



1 . 000 
pounds 

12,776 



9,211 
95 

78 

9,038 

1,112 
2,453 

42,422 



2,959 
10,241 
1,134 
1,525 
3,324 
4,258 
19, 601 
1,432 
2,727 

731 

47 

4,625 

10,039 

9,621 

2,072 

301 

2,762 

4,486 



2,172 



947 
1,225 

4,383 

43,229 



1.000 
dol lars 

5,912 



34, 565 
1,178 

20, 577 

96 

554 

12,160 

8,664 

290 

4,040 

546 

29 

3,759 



533,059 



58,036 



57,669 

19, 199 

9,905 



3,079 
50 

35 

2,994 

1,004 
1,829 

14,418 



1,192 

3,069 
525 
569 

1,010 
965 

6,443 
667 
766 

319 

19 

1,127 

3,545 

3,714 

835 

157 

743 

1,979 



1,992 



571 
1,421 

1,939 

16,311 



10,347 
414 

4,879 
64 

380 
4,610 
5,964 

254 
2,939 

366 

21 

2,384 



115, 706 



14,843 



14, 663 
5,522 
3,056 



See footnotes at end of table. 



SURFACE ACTIVE AGENTS 
TABLE 19A. --Surface-active agents: U.S. production and sales, i 967- -Continued 



49 



Chemical 



Production ■"■ 



Sales'^ 



Quantity-^ 



Value 



Unit 
value^ 



Nonionic Surface-Active 4gents--Continued 

Carboxj-lic acid amides — Continued 

Carboxylic acid - alkanolamine condensates- -Continued 

Dlethanolainine condensates (amine/aoid ratio = 
2/1) — Continued 

Coconut oil and tallow acids 

Laurie acid 

Oleic acid 

Stearic acid 

Tall oil acids 

All other 

Diethanolamine condensates (other airdne/aoid ratios), 

total 

Coconut oil acids (amine/aoid ratio=l/l) 

Laurie acid (amine/acid ratio = 1/1) 

Oleic acid (amine/acid ratio=l/l ) 

Stearic acid (amine/acid ratio=l/l) 

All other 

Bthanolamine condensates, total 

Laurie acid (amine/acid ratio=2/l ) 

All other 

Isopropanolamine condensates, total 

Laurie acid 

All other 

Groups listed above for which separate sales data may 

not be shown 

Carboxylic acid - alkanolamine condensates, ethoxylated- 

irboxylie acid esters, total 

Anhydrosorbitol esters, total 

Anhydrosorbitol monoester of tall oil acids 

Anhydrosorbitol mono-oleate 

Anhydrosorbitol monos tear ate 

Anhydrosorbitol trioleate 

Anhydrosorbitol tristearate 

All other 

Ethoxylated anhydrosorbitol esters, total 

Ethoxylated anhydrosorbitol raonolaurate 

Ethoxylated anhydrosorbitol mono-oleate 

Ethoxylated anhydrosorbitol monopalmitate 

Ethoxylated anhydrosorbitol monostearate 

Ethoxylated anhydrosorbitol trioleate 

Ethoxylated anhydrosorbitol tristearate 

All other 

Ethylene glycol and diethylene glycol esters, total 

Diethylene glycol monolaurate 

Diethylene glycol mono-oleate 

Diethylene glycol monostearate 

Ethylene glycol monostearate 

All other 

Glycerol esters, total 

Complex glycerol esters 

Glycerol esters of chemically defined acids, total 

Glycerol monolaurate 

Glycerol mono-oleate 

Glycerol monostearate' 

All other 

Glycerol esters of mixed acids, total 

Glycerol monoester of hydrogenated soybean oil acid: 

All other 

Natural fats and oils, ethoxylated, total 

Castor oil, ethoxylated 

Lanolin, ethoxylated 

All other 



i.OOO 


1 , 000 


1 , (100 


pounds 


pounds 


doi lars 


• • • 


1,622 


195 


6,926 


4,340 


1,205 


1,465 


1,237 


372 


692 


509 


200 


423 


• • • 




4,512 


1,586 


494 


38,116 


... 




18,384 


17, 015 


4,240 


15,315 






525 


455 


294 


788 


763 


325 


3,104 






21,838 






37 


23 


9 


21,801 


• > < 




4,252 







4,252 

394 
163, 863 



15,892 
562 

3,798 



11,532 

17, 688 

6,679 

3,689 

814 

6,506 

4,780 

289 

109 

756 

965 

2,661 

73,750 

4,306 

17,013 

66 

2,523 

13,287 

1,137 

52,431 

7,644 

44,787 

4,836 

4,319 

207 

310 



194 



20,020 
367 

126,498 



10,594 

3,848 

2,713 
596 
111 

3,326 
14,365 

3,380 

382 

3,033 

578 

1,278 

5,714 

4,477 

310 

108 

579 

853 

2,627 

59,543 

3,273 

12,092 

62 

2,319 

8,713 

998 

44,178 

5,977 

38,201 

3,775 

3,498 

277 



64 



4,209 
180 

40,232 



3,950 

1,465 

918 

234 

39 

1,294 

5,928 

1,412 

171 

1,261 

239 

522 

2,323 

1,379 

107 

31 

161 

329 

751 

17,209 

1,360 

4,689 

21 

842 

3,341 

485 

11,160 

1,521 

9,639 

1,291 

1,169 

122 



See footnotes at end of table. 



50 



SYNTHETIC ORGANIC CHEMICALS, 1967 
TABLE 19A. --Surface-active agents: U.S. production and sales, 1967. -Continued 



Chemical 



Production 



Sales "^ 



Cuantity-"- 



Value 



Unit 
value ^ 



Nonionic Surface-Active 4gf'nf s--Cont inuefl 

Carboxylic acid esters — Continued 

Pol^fethylene glycol esters, total 

Polyethylene glycol esters of chemically defined 

acids, total 

Polyethylene glycol dilaurate 

Polyethylene glycol dioleate 

Polyethylene glycol distearate 

Polyethylene glycol monolaurate 

Polyethylene glycol inono-oleate 

Polyethylene glycol monostearate 

All other 

Polyethylene glycol esters of rosin and tall oil 

acids, total 

Polyethylene glycol sesquiester of tall oil acids 

All other 

Polyethylene glycol esters of other mixed acids, total- 
Polyethylene glycol sesquiester of coconut oil acids- 
All other 

Polyglycerol esters 

Propanediol esters, total 

1,2- Propanediol monostearate 

All other 

Other carboxylic acid esters 

Ethers, total 

Benzenoid ethers, total 

Dodecylphenol, ethoxylated 

Iso-ootylphenol, ethoxylated 

Nonylphenol, ethoxylated 

Phenol, ethoxylated 

All other 

Nonbenzenoid ethers, total 

Linear alcohols, alkoxylated, total 

Decyl alcohol, ethoxylated 

Dodecyl alcohol, ethoxylated 

Hexadecyl alcohol, ethoxylated 

Mixed linear alcohols, ethoxylated 

Mixed linear alcohols, ethoxylated and propoxylated-- 

9-Octadecenyl alcohol, ethoxylated 

Octadecyl alcohol, ethoxylated 

All other 

Other ethers and thioethers, total 

Tridecyl alcohol, ethoxylated 

All other 

Other nonionic surface-active agents 



1 . mo 

pounds 

22, 980 

23,039 

752 

3,104 

300 

5,134 

3,713 

9,308 

728 

8,517 

8,107 

-ilO 

1,424 

474 

950 

631 

5,039 

3,836 

1,203 

8,267 

443,741 



1.000 
pounds. 

22,238 

13,002 

692 

819 

292 

2,373 

2,906 

5,801 

119 

8,073 

7,681 

392 

1,163 

407 

756 

312 

3,474 

2,280 

1,194 

7,720 

343,767 



210,912 

13,609 

1,584 

111,680 

8,042 

75,997 

232,829 

186,887 

1,046 

378 
124,281 

3,607 

431 

57, 144 

45,942 

6,851 
39,091 

5,030 



185,759 

13,320 

1,001 

99,337 

72,101 
158,008 

118,684 

2,041 

389 

109,051 

2,494 

2,560 

207 

1,942 

39,324 

5,943 

33,381 

4,758 



1 . 000 
dollars 
6,659 

4,845 

231 

273 

102 

931 

1,010 

2,246 

52 

1,362 

1,229 

133 

452 

86 

366 

149 

951 

549 

402 

2,716 

58,432 



31,631 

1,943 

241 

14, 579 

14,868 
26,801 
17,235 

883 

219 

13,325 

453 

1,336 

194 

825 

9,566 

1,354 

8,212 

2,199 



Per 
pound 
$0.30 

.37 
.33 
.33 
.35 
.39 
.35 
.39 
.44 

.17 
.16 
.34 
.39 
.21 
.48 
.48 
.27 
.24 
.34 
.35 

.17 
.17 
.15 
.24 
.15 

.21 
.17 
.15 

.43 
.56 
.12 
.18 
.52 
.94 
.42 
.24 
.23 
.25 

.46 



^ All quantities are given in terms of 100-percent organic surface-active ingredient. 

^ Sales include products sold as bulk surface-active agents only. 

^ Calculated from rounded figures. 

* The term "benzenoid, " as used in this report, describes any surface-active agent, except lignin derivatives, 
whose molecular structure includes 1 or more 6-membered carbocylic or heterocyclic rings with conjugated double 
bonds (e.g., the benzene ring or the pyridine ring). 

^ Includes the ligninsulfonates, which were classed as benzenoid in 1965 and earlier years. 

' Includes production of 'all other" sulfonic acids and of "all other" sulfated alcohols and phenols; also includes 
sales of 'all other" potassium and sodium salts of fatty, rosin, and tall oil acids and of "all other" sulfated 
ethers. 

'' Production and sales of (hydrogenated tallow alkyl)amine were overstated in 1965 and 1966 because of erroneous 
reporting by one producer. 

The nonionic carboxylic acid - diamine and polyamine condensates, formerly reported under this heading, have 
been transferred to the section on Miscellaneous Chemicals, 

Some products previously reported as glycerol monostearate are now reported as glycerol esters of mixed acids. 



PESTICIDES AND RELATED PRODUCTS 51 

Table 1 9A shows statistics for production and sales of surface-active agents grouped by ionic 
class and by chemical class and subclass. ■'■-'■ All quantities are reported in terms of lOO-percent 
organic surface-active ingredient and thus exclude all inorganic salts, water, and other diluents. 
Sales statistics reflect sales of bulk surface-active agents only; sales of formulated products are 
excluded. 

Total U.S. production of surface-active agents in 1967 amounted to 3,479 million pounds, or 
4. 8 percent more than the 3, 321 million pounds reported for 1966 and 9. 7 percent more than the 
3, 170 million pounds reported for 1965. Sales of bulk surface-active agents in 1967 amounted to 
1, 750 million pounds, valued at $317 million, compared with sales in 1966 of 1, 766 million pounds, 
valued at $315 million. Sales in 1967 were thus 0. 9 percent smaller than in 1966 in terms of 
quantity but were 0. 6 percent larger in terms of value. 

Production of anionic surface-active agents in 1967 amounted to 2,614 million pounds, or 
75. 1 percent of the total reported for 1967 and 5. 9 percent more than the anionic output reported 
for 1966. Sales of anionics in 1967 amounted to 1,088 million pounds, valued at $149 million. Of 
the total anionic output, 1 , 02 1 million pounds consisted of potassium and sodium salts of fatty, 
rosin, and tall oil acids, of which 533 million pounds was the sodium salt of tallow acids; 651 
million pounds consisted of alkylbenzenesulfonates , of which 417 million pounds was the sodium 
salt of dodecylbenzenesulfonic acid and 102 million pounds was the free acid; and 454 million 
pounds consisted of ligninsulfonic acid salts, of which 284 million pounds was the calcium salt and 
45 million pounds was the sodium salt. 

Production of nonionic surface-active agents in 1967 amounted to 704 million pounds, or 
20. 2 percent of the total reported for 1967 and 2. 7 percent more than the nonionic output reported 
for 1966. Sales of nonionics in 1967 amounted to 533 million pounds, valued at $116 million. Of 
the total nonionic output, 211 million pounds consisted of alkylphenol ethoxylates and other benze- 
noid ethers, of which 112 million pounds was nonylphenol ethoxylate; 233 million pounds consisted 
of alcohol ethoxylates and other nonbenzenoid ethers, of which 124 million pounds was mixed linear 
alcohol ethoxylate; 91 million pounds consisted of alkanolamides , of which 18 million pounds was 
coco diethanolamide (made with a 1/1 ratio of diethanolamine to coconut oil acids); 15 million 
pounds was lauric diethanolamide (1/1 ratio); and 13 million pounds was coco diethanolamide (2/1 
ratio); and 74 million pounds consisted of glycerol esters, of which 13 million pounds was glycerol 
monostearate. 

Production of cationic surface-active agents in 1967 amounted to 154 million pounds, or 4.4 
percent of the total reported for 1967 and 4. 8 percent less than the cationic output reported for 
1966. Sales of cationics in 1967 amounted to 123 million pounds, valued at $48 million. Of the total 
output of cationics, 45 million pounds consisted of quaternary ammonium salts not containing 
oxygen, of which 21 million pounds was bis(hydrogenated tallow alkyl)dimethylammonium chloride; 
and 22 million pounds consisted of primary monoamines not containing oxygen. 

Production of amphoteric surface-active agents in 1967 amounted to 6. 6 million pounds, or ap- 
proximately 0.2 percent of the total reported for 1967 and 31.4 percent more than the amphoteric 
output reported for 1966. Sales in 1967 amounted to 6. 5 million pounds, valued at $4, million. 

The difference between production and sales reflects inventory changes and captive consump- 
tion of soaps and surface-active agents by synthetic rubber producers, and by manufacturers of 
cosmetics, packaged detergents, bar soaps, and other formulated consumer products. In some 
instances the difference may also reflect quantities of surface-active agents used as chemical 
intermediates, e. g. , nonionic alcohol and alkylphenol ethoxylates which may be converted to 
anionic surface-active agents by phosphation or sulfation. 

Pesticides and Related Products 

This section of the report covers pesticides (fungicides, herbicides, insecticides, and rodenti- 
cides) and related products such as plant hormones, seed disinfectants, soil conditioners, soil 
fumigants and synergists. The data are given in terms of lOO-percent active material; they thus 
exclude such materials as diluents, emulsifiers, and wetting agents. Statistics on production and 
sales of pesticides and related products in 1967 are given in table 20A. ^2 



' ' See also uble 19B, pt, lH, which lists these products »nd identifies the manufacturers. 
*^See also uble 2QB, pt. lU, which lists these piodicts and identifies the manufacturers. 



52 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 2QA..--Pesticides and related products; U.S. production and sales, 1967 

[Listed below are all pesticides and related products for which any reported data on production or sales may be 
published. (Leaders are used where the reported data are accepted in confidence and may not be published or where 
no data were reported. ) Table 20B in pt. Ill lists all pesticides and related products for which data on produc- 
tion or sales were reported and Identifies the manufacturer of each] 



Product 



Production 



Sales 



Quantity 



Value 



Grand total 

PESTICIDES AND RELATED PRODUCTS, CYCLIC 

Total 

Fungicides, total 

3,5-Diraethyl-l,3,5-2H-tetrahydrothiadiazine-2-thione 

(DMTT) 

Mercury fungicides, total 

Phenylmercuric acetate (PMA) 

Other mercury fungicides 

Naphthenic acid, copper salt 

Pentaohlorophenol (PCP) 

8-Quinolinol (8-Hydroxyquinoline), copper salt 

2,4,5-Trichlorophenol and salts 

All other cyclic fungicides^ 

Herbicides and plant hormones, total 

Dinitrobutylphenol, ammonium salt 

1-Naphthaleneaoetlc acid and esters and salts 

Phenoxyacetic acid derivatives ; 

2,'i-Diohlorophenoxyacetic acid (2,4-0) 

2,4-Dichlorophenoxyacetic acid esters and salts, total- 

2,'i-Dichlorophenoxyacetic acid, n-butyl ester 

2,<i-Diohlorophenoxyaoetic acid, dimethylamine salt 

2,'4-Diohlorophenoxyaeetio acid, iso-ootyl ester 

2,'i-Diohlorophenoxyacetic acid, isopropyl ester 

All other (2,<4-D) esters and salts 

2,4, 5-Trichlorophenoxyaoetic acid (2,4, 5-T) 

2,4,5-Triohlorophenoxyaoetic acid esters and salts, 

total 

2,4,5-Triohlorophenoxyaoetio acid, n-butyl ester 

2,4,5-Triohlorophenoxyacetic acid, iso-octyl ester 

All other (2,4, 5-T) esters and salts 

All other cyclic herbicides and plant hormones-* 

Insecticides and rodentioides, total 

Aldrin-toxaphene group* 

a-Bis(p-chlorophenyl)-p,J3,fj-trichloroethane (DDT) 

Hexachlorocyclohexane (.Benzene hexachloride) 

Organophosphorus insecticides, total 

0,0-Diethyl 0-p-nitrophenyl phosphorothioate (Parathion 
0, 0-Dimethyl O-p-nitrophenyl phosphorothioate (Methyl 

parathion) 

All other organophosphorus insecticides' 

All other insecticides and rodenticides^ 

PESTICIDES AND RELATED PRODUCTS ACYCLIC 

Total 

Fungicides, total 

Dimethyldithiocarbamic acid, ferric salt (Ferbam) 

Ethylene bis(dithiocarbamio acid), disodium salt (Nabam)- 

Ethylene bis(dithiooarbaraic acid), zinc salt (Zineb) 

All other acyclic fungicides'' 

Herbicides and plant hormones' 



1 , 000 
pounda 

1,049,663 



823,158 



103,891 



1,046 

1,430 

518 

912 

3,473 

44,239 

193 

25,254 

28,256 

366,298 



58 
28 

77,139 
83,750 
25,402 
19, 139 
9,804 
3,836 
25,569 
14,552 

27,189 

19,422 

4,653 

3,114 

163,582 

352,969 



120, 183 
103,411 

63,924 
11,361 

33,344 
19,219 
65,451 



226, 505 



40, 521 



2,331 

1,361 

3,055 

33,774 

43, 149 



1.000 
pounds 

897,363 



681,532 



80,885 



1,035 

1,196 

341 

855 

3,385 

37,959 

194 

37,116 

243, 892 



66 

30 

34,021 
64,595 
19,559 
15,631 
10,065 

3,070 
16,270 

1,670 

25,699 

19,021 

4,759 

1,919 

122,811 

351,755 



134,318 

88,701 

6,042 

62,730 

14, 573 

31,919 
16,238 
59,964 



215,831 



39,528 



2,002 

2,196 

3,528 

31,802 

38,690 



1 . 000 
dot lars 

787,043 



627,742 



29,651 



548 
6,098 
2,477 
3,621 

996 
6,430 

472 

15,107 
385,523 



119 
128 

10, 854 
28,824 
11,292 
6,534 
3,905 
1,098 
5,995 
2,095 

20,565 

12,937 

5,532 

2,096 

322,938 

212,568 



71,492 
13,696 

1,148 
71,190 

8,217 

19, 803 
43,170 
55,042 



159,301 



26,682 



882 

921 

1,527 

23,352 

44,457 



See footnotes at end of table. 



MISCELLANEOUS CHEMICALS 



53 



TABLE 20A. — Pesticides and related products ; U.S. production and sales , 1967 — Continued 



Product 



PESTICIDES AND REUCTED PRODUCTS, ACYCLIC— Continued 

Insecticides, rodentioides, and soil conditioners and 

furoigants, total 

l,2-Dibromo-3-chloropropane (DBCP) 

Methyl brondde ( Bromoethane ) 

All other acyclic insecticides (including acyclic organo- 
phosphorus insecticides), rodentioides, and soil con- 
ditioners and fumigants' ^° 



Production 



i.om 

pounds 
1-42,835 



5,240 
19,665 



117,930 



Sales 



Quantity 



1,000 
pounds 

137,613 



<i,358 
17,206 



116,049 



Value 



J . 000 
do I lays 



3,162 



2,122 
6,766 



79, 274 



Unit 
value-"- 



Per 
pound 



$0.64 



.49 
.39 



.68 



^ Calculated from rounded figures. 

^ Includes captan, dinooap, folpet, glyodin, pentachloronitrobenzene, sodium pentachlorophenate, tri- and tetra- 
chlorophenols, and others. 

^ Includes barban, 2-ohloro-N-isopropyl acetanilide, dicamba, dimethylurea compounds, dinitrophenol compounds, 
endothal, isopropyl phenylcarbamates (IPC and CIPC), maleio hydrazide, picloram, propanil, triazines, trifluralin, 
uracils, and others. 

* Includes aldrin, chlordan, dieldrin, endrin, heptachlor, terpene polychlorinates, and toxaphene. 

' Includes carbophenothion, couraaphos, diazinon, dioxathion, ronnel, and other phosphorothioates and phosphoro- 
dithioates, and others. 

' Includes chlorobenzilate, DDD, dicofol, endosulfan, methoxychlor, and other chlorinated insecticides, carbaryl, 
insect attractants, DEEP and other insect repellents, hexachlorocyclohexane (production only), lindane (production 
and sales), small amounts of rodenticides, synergists, and others. 

"^ Includes dithiocarbamates, including dodine, maneb, mercury compounds, PETD, and others. 

^ Includes CDAA, dalapon, methanearsonic acid's disodium salt and sodium salt, thiocarbamate, thioloarbamate, and 
organophosphorus herbicides, sodium TCA, and others. 

Includes DDVP, disulfoton, ethion, malathion, naled, phorate, TEPP, and other organophosphorus insecticides, soil 
conditioners and fumigants, metaldehyde (which is a mollusicide), small quantities of rodenticides, and others. 

^° Acyclic oranophosphorus insecticides are included with "All other acyclic insectides" in order to establish an 
all o-ther acyclic insecticide total without disclosing the operations of individual companies. 

Production of pesticides and related products in 1967 amounted to 1, 050 million pounds--about 
4 percent more than the 1,013 million pounds reported for 1966. Sales in 1967 were 897 million 
pounds, valued at $787 million, compared with 822 million pounds, valued at $584 million, in 1966. 

The output of cyclic pesticides and related products included in the cyclic group amounted to 
823 million pounds in 1967--about 6 percent more than the 777 million pounds produced in 1966. 
Sales in 1967 were 682 million pounds, valued at $628 million, compared with 605 million pounds, 
valued at $447 million, in 1966. 




Miscellaneous Chemicals 

The term miscellaneous chemicals comprises those synthetic organic products that are not in- 
cluded in the use groups covered in the preceding sections of the report. They include products 
that are employed in a great variety of uses, the number of chemicals used exclusively for only 
one purpose is not large. Among the products covered are those used for gasoline and lubricating 
oil additives, paintdriers, photographic chemicals, tanning materials, flotation reagents, re- 
frigerants, textile pol-ymers, sequestering agents, organic fertilizers, antifreeze chemicals, 
solvents, and acyclic intermediates. Statistics on production and sales of miscellaneous chemicals 
in 1967 are given in table 21A.^3 

Production of miscellaneous cyclic and acyclic chemicals in 1967 totaled 59. 7 billion pounds, 
or 4 percent more than the output of 57. 3 billion pounds reported for 1966. Sales of miscellaneous 
chemicals in 1967 amounted to 26. billion pounds, valued at $3. 5 billion, con-ipared with 24. 5 
billion pounds, valued at $3.2 billion, in 1966. 

See also table 21B, pt. Ill, which lists these products and identifies the manufacturers. 



54 



SYNTHETIC ORGANIC CHEMICALS, 1967 



Table 21 A... Miscellaneous chemicals.- U.S. production and sales , 1967 

[Listed below are all miscellaneous chemicals for which any reported data on production or sales may be published. 
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data 
were reported.) Table 21B in pt. Ill lists alphabetically all miscellaneous chemicals for which data on production 
or sales were reported and identifies the manufacturer of each] 



Chemical 



Production 



Sales 



Quantity 



Value 



Grand total 

MISCELLANEOUS CHiMICAIS, CYCLIC 

Total 

"Benzoic acid salts; Sodium benzoate, tech. and U.S. P. 

Benzoyl peroxide 

Butyl benzoate 

4--tert-Butylpyrooatechol 

Cyclohexanone peroxide 

2,6-Di-tert-butyl-p-cresol: 

Food grade 

Tech 

p-Dimethoxybenzene (Dimethyl ether of hydroquinone ) 

Flotation reagents 

Gasoline additives, total^ 

N, N'-Di-sec-butyl-p-phenylenediamine 

N, N'-Disalioylidene-l,2-propanediamine 

All other 

Hexamethylenetetramine, tech 

p-I^droxybenzoic acid esters: 

Methyl p-hydroxybenzoate 

Propyl p-hydroxybenzoate 

Lubricating oil and grease additives, total 

Oil-soluble petroleum sulfonate, barium salt 

Oil-soluble petroleum sulfonate, calcium salt 

Oil-soluble petroleum sulfonate, sodium salt 

All other 

Morpholine 

Naphthenic acid salts, total-' * 

Calcium naphthenate 

Cobalt naphthenate 

Iron naphthenate 

Lead naphthenate 

Manganese naphthenate 

Zinc naphthenate 

All other 

Photographic chemicals: 

3-Chloro-4-diethylaminobenzenediazonium salts 

2, 5-Dibutoxy-4-morpholinobenzenediazonium salts 

2,5-Diethoxy-4-morpholinobenzenediazonium salts 

p-Diethylajninobenzenediazonium (p-Diazo-N, N-diethylani- 

line) salts 

N, N-Diethyltoluene-2, 5-diamine, monohydrochloride 

Pinene (a- and p-) 

Propyl gallate 

Rosin acid salts 



1.000 
pounds 

59,695,693 



1,535,922 



15, 923 
5,929 
l,a42 

2A- 

^,152 

K, 508 

5.45 

5,282 

12,499 



1,902 
1,218 
9,379 

84,255 



693 
202 

406,655 



25,335 
147,347 

96,501 
137,472 

22,913 

21,085 



1,174 

3,300 

223 

13,370 

1,357 

980 

681 



19 

96 
307 

114,157 
105 
452 



1.000 
pounds 

26,001,171 



l.OOi'i 
dol lars 

3,475,694 



775,540 



283,575 



12,649 

5,700 

1,313 

539 

24 

4,961 

14,506 

547 



7,734 



1,489 

6,245 

69, 150 



620 
200 

250,091 



65,438 

60,497 

124,156 

17,641 

18, 967 



1,220 

2,757 

115 

12,239 

1,146 

930 

560 



7 

3 

19 

91 
254 

55,896 



3,869 

5,726 

357 

958 

32 

3,032 

8,106 

673 



7,783 



1,372 

6,411 
11,470 



1,000 
425 

55,774 



16, 006 

11,100 
28,668 

7,546 

6,498 



508 

1,845 

39 

2,876 

415 

305 

510 



36 

35 

198 

218 
667 

6,492 



See footnotes at end of table. 



MISCELLANEOUS CHEMICALS 
TABLE 21A. — Miscellaneous chemicals: U.S. production and sales, 1967 — Continued 



55 



Chemicals 



Production 



Sales 



Quantity 



Value 



Unit 
value^ 



MISCELLANEOUS CHEMICALS, CYCLIC— Continued 

Tall oil salts, total-' 

Calcium tallate 

Cobalt tallate 

Lead tallate 

Manganese tallate 

All other 

Tanning materials, synthetic, total 

2-Naphthalenesulfonic acid, formaldehyde condensate and 

salts 

l-Phenol-2-sulfonic acid, formaldehyde condensate 

All other 

Textile chemicals, other than surface-active agents 

All other miscellaneous cyclic chemicals 

MISCELLANEOUS CHEMICAIS, ACYCLIC 

Total 

Cellulose Esters and Ethers 
Total - 

Cellulose esters, total 

Cellulose acetate 

All other 

Cellulose ethers, total 

Sodium oarboxymethylcellulose, lOO^t 

All other 

Lubricating Oil Additives 

Total - - — 

Phosphorodithioates (Dithlophosphates ) 

Sulfurized lard oil 

All other 

Nitrogenous Compounds 

Total' — 

Aorylonitrile 

Amines, total 

Butylamines: 
n-Butylamine, mono- 

Di-n-butylamine 

Ethylamines: 

Diethylamine 

Ethylamines, mono- and tri- 

1, 6-Hexanediamine (Hexamethylenediamine) 

Methylamines : 

Dimethylamine 

Monomethylamine 

Trimethylamlne 

Eropylamines : 

Diisopropylamine 

Di-n-propylamine 

Msnoisopropylamine 

All other 

See footnotes at end of table. 



1,000 

pounds 

7,836 



~7m~ 

2,268 

3,583 

746 

530 

33,820 



30,469 

3,351 

1,810 
780,813 

58,159,771 



1, 030, 138 



926, 222 



743,160 
183,062 

103,916 



54,750 
49, 166 



417, 514 



102,001 

3,635 

311,878 



9,424,828 



670, 764 
785,135 



1,142 
2,785 

11,759 

22,798 

497, 900 

71,259 
17, 200 
20,407 

1,968 

7,254 

17,837 

112,826 



) , noo 
pounds 

7,872 



1.000 
dollars 



2,251 

3,545 

826 

572 

33,673 



2,485 



T2Cr 
1,080 
825 
216 

144 

7,544 



30,228 
2,168 
1,277 

768 
272,315 



25,225,631 



5,806 
721 

1,017 



151,763 



3,192,119 



300,366 



120,489 



207, 879 



69,087 



207, 879 
92,487 



69,087 
51,402 



50,816 
41,671 



160,848 



21,290 
30,112 



33,550 



37,411 

2,869 

120, 568 



5,091,940 



10,312 

446 

22,792 



604, 199 



270,454 
226, 140 



31,875 
61,213 



805 
2,038 

4,721 
18,862 



35,894 
13,640 
12,784 

1,074 

6,595 

17, 170 

112, 557 



373 
845 

1,342 
4,019 



4,763 
1,665 
1,427 

286 

2,231 

2,880 

41,382 






56 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 21A.-- Miscellaneous chemicals.- U.S. production and sales, -Z 56 7- -Continued 



Qiemioals 



Production 



Sales 



Quantity 



Value 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 
Nitrogenous Compounds- -Continued 

1, l'-A2obisforniamide 

Caprolactam (2-Qxohexamethyleniniine) 

2-Dimethylami noethanol 

Eruoamide 

Ethanolamines, total 

2-Ajidnoethanol (Monoethanolandne) 

2,2'-Iminodiethanol (Diethanolamine ) 

2, 2' ,2" -Nitrilotriethanol (Triethanolamine ) 

2-Methyllaotonitrile (Acetone cyanohydrin) 

Nitriloacids and salts, total 

( Ethylenedinltrilo)tetraacetio acid 

(Ethylenedinitrilo)tetraacetiG acid, tetrasodium salt- 
(Ethylenedinitrilo)tetraaoetic acid, trlsodium salt — 
(N-Hydroxyethyletl"iylenedinitrilo)triacetic acid, 

trisodium salt 

All other 

Hylon polymer for fiber 

Pentaerythritol tetranitrate 

Saroosine and salt 

Stearandde 

Urea in compounds or mixtures (100^ basis), total 

In feed compounds 

In liquid fertilizer ■ 

In solid fertilizer 

All other 

All other nitrogenous compounds 

Acids, Acyl Halides and Anhydrides 

Total — - 

Acetic acid, synthetic, 100^6 

Acetic anhydride, 1005t- 

Acrylic acid 

Adiplc acid 

Butyric acid 

Chloroacetio acid, mono- 

Decanoyl chloride 

Formic acid, 9O5S 

Fumaric acid 

Gluconic acid, tech 

Lauroyl chloride 

Maleic anhydride 

Palmitoyl chloride 

Propionic acid 

All other acids, acyl halides and anhydrides 

Salts of Organic Acids 
Total 

Acetic acid salts, total 

Ammonium acetate 

Sodium acetate 

Zinc acetate 

Zirconium acetate 

All other 



1,000 
pounds 

3,505 

328,564 

1,789 

1,125 

226,818 



74,585 
85,878 
66,355 

364,137 

58, 698 



27,529 
652 

3,960 
26,557 

1,092,159 

2,035 
821 

' 4,182,447 



461,807 
1,649,577 
1,751,132 

319,931 

1,706,831 



5,209,604 



1,559,991 

1,556,148 

64,710 

970, 927 

66,359 

1,439 

26,840 

48,015 

4,641 

4,418 

168, 207 

360 

43,916 

693,633 



237,713 



27,689 



400 

W,476 

553 

189 

12,071 



1,000 

pounds 

2,584 

164,689 

1,771 

866 

176,346 



1,000 

do II or ^ 

2,973 

33,677 

1,109 

1,085 

27, 527 



59,259 
57,978 
59,109 



39,282 



9,903 

7,517 

10, 107 



12,326 



1,581 

14,541 

600 

3,669 
18,891 



3,025 
1,569 



3,792,606 



795 

4,739 

253 

1,410 
5,129 



2,341 
721 



•^ 138,282 



465,725 
1,500,032 
1,592,491 

234,358 

412,608 



1,028,648 



16,237 

54,652 

58,673 

8,720 

291,070 



157,051 



341, 146 

134,416 

14,035 

93,530 

935 



23,142 

36,984 

4,083 

114, 117 

22,479 
243,781 



188,811 



23,209 

13,589 

3,771 

17,545 

228 



2,514 
4,690 
1,214 

15,116 

2,311 
72,864 



68,206 



26,695 



6,517 



493 

13,695 

609 

180 

11,718 



IS9" 

2,280 

212 

104 

3,732 



See footnotes at end of table. 



MISCEllANEOUS CHEMICALS 



57 



TABLE 21A. --Miscellaneous chemicals: U.S. production and sales , i967-- Continued 



Chemioals 



Production 



Sales 



(Jjantity 



Value 



Unit 
value"'" 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 
Salts of Organic ;lcids--Contiiiuod 

2-EthyIhexanoio acid (a-Ethyloaproio acid) salts, total - 

Calcium 2-ethylhexanoate 

Cobalt 2-ethylhexanoate 

Lead 2-ethylhexanoate 

Manganese 2-ethylhexanoate 

Zinc 2-ethylhexanoate 

All other 

Formic acid salts 

Gluconic acid, sodium salt, tech 

Linoleic acid salts: Cobalt linoleate 

Mercaptoacetic (Thioglyoolic) acid, salts 

Oleic acid salts^ 

Palmitic acid, aluminum salt 

Polyaciylic acid salts 

Propionic acid salts: 

Calcium propionate 

Sodium propionate 

Stearic acid salts, total' 

Alujiiinum stearates, total 

Aluminum distearate 

Aluminum monostearate 

Aluminum tristearate 

Calcium stearate 

Lithium stearate 

Magnesium stearate 

Zinc stearate 

All other 

All other salts of organic acids 

Aldehydes and Ketones 

Total— 

Acetaldehyde 

Acetone, total 

From isopropyl alcohol 

All other 

2-Butanone (Methyl ethyl ketone) 

Chloral (Trichloroaoetaldehyde) 

Formaldehyde (37^ by weight) 

4-Hydroxy-'4-methyl-2-pentanone (Diacetone alcohol) 

4-Me'thyl-2-pentanone (Methyl isobutyl ketone) 

All other aldehydes and ketones 

Alcohols, Monohydric, Unsubstituted 

Total 

Alcohols, C9 or lower, unmixed, total 

Butyl alcohols: 

n-Butyl alcohol (n- Propylcarbinol) 

Isobutyl alcohol (isopropyloarbinol) 

Ethyl alcohol, synthetic-"-" 

2-Ethyl-l-hexanol 

Hexyl alcohol 

Hexynol 

Iso-octyl alcohols 

Isopropyl alcohol 

See footnotes at end of table. 



1.0(X) 
pounds 

4,234 



858 

187 

99 

285 

2,805 

22, 508 

12,603 

28 

2,469 

464 

101 

2,379 

13,521 
7,463 

43,902 



5,123 

3,793 

791 

539 

20,805 

2,519 

10, 148 

5,307 

100,352 



8,507,842 



1,408,596 
1,283,978 



792, 168 
491,810 

400,424 

54,401 

3,707,093 

199, 274 
1,454,076 



9,418,590 



8,819,204 



424, 64A 

93,078 

1,918,558 

351,976 

15,612 

35 

122,189 

2,069,215 



) . 000 
pounds 
3,117 



1.000 
do I lars 



"596 

735 

221 

69 

297 

1,399 

21, 980 

13,249 

30 

2,259 

435 

3,324 

9,121 

37,716 



4,478 

3,300 

670 

508 

19,429 

482 

2,212 

9,476 

1,639 

70,885 



3,268,392 



827,739 



414,598 
413,141 

381,782 

1,289,720 

31,643 

155,294 

582,214 



4,410,569 



4,010,461 



257,522 

73,718 

1,135,482 

156, 674 

3,728 

108, 620 
739, 176 



2,390 



733 

85 

32 

153 

1,223 

1,160 

3,488 

17 

3,139 

338 

3,851 

1,789 

11,926 



1,637 

1,192 
266 
179 

5,080 
235 
829 

3,415 
730 

33,591 



192,275 



42,858 



22,491 
20,367 

40,608 

33,633 

3,970 

19,662 

51, 544 



293,073 



242,352 



27, 225 

5,455 

69,025 

20,258 

527 

13,290 
45,238 



58 SYNTHETIC ORGANIC CHEMICAIS. 1967 

TABLE 21A. — Miscellaneous chemicals.- U.S. production and sales, i.967--Continued 



Chemicals 



Rroduotion 



Sales 



Qaantity 



Value 



Unit 
value-"- 



IMSCELUNEOUS CfflMICAlS, ACYCUC— Continued 
Alcohols , Monohydric , t/nsu6s 1 1 tuted- -Continued 

Alcohols, C9 or lower, unmixed — Continued 

Methanol, synthetic 

l-(and 2- )Ootanol 

All other 

Alcohols, Cio ^^^ higher, unmixed, total 

Deoyl alcohols 

1-Hexadecanol (Cetyl alcohol) 

All other 

Mixtures of alcohols, total 

Cg and lower, only 

Cio ^^^ higher, only 

Cg to C12 aJ^d others 

Polyhydric Alcohols and Their Esters and Ethers 

Total 

Polyhydric alcohols, total 

Ethylene glycol 

Pentaerythritol 

Propylene glycol (1,2-Propanediol) 

Sorbitol 

All other 

Polyhydric alcohol esters 

Polyhydric alcohol ethers, total 

2-Butoxyethanol (Ethylene glycol monobutyl ether) 

Die-thylene glycol 

Dipropylene glycol 

2-Ethoxye-thanol (Etliylene glycol monoethyl e-ther) 

2-(2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl 

e-ther) 

2-[2-(2-Ethoxyethoxy)ethoxy]e-thanol (Triethylene glycol 

monoe-thyl ether ) 

2-Methoxye-thanol (Ethylene glycol monome-thyl ether) 

2-(2-Methoxyethoxy)ethanol (Diethylene glycol monome- 
thyl ether) 

Polyethylene glycol 

Polypropoxy ethers, total 

Glycerol tri(polyoxypropylene) ether 

All other 

Polypropylene glycol 

Triethylene glycol 

All other ethers of polyhydric alcohols 

Esters of Monohydric Alcohols 
Total— - — 

Butyl acetates, total 

n-Butyl acetate, unmixed 

All other 

Butyl aciylate 

Dibutyl fumarate 

Dibutyl maleate 

Dilauryl 3,3' -thiodipropionate 

Dioctyl maleate 

See footnotes at end of table. 



1.000 
pounds 
3,432,078 
14,629 
377, 190 

205,358 



137,411 

1,414 

66, 533 

394,028 



61,248 
230,953 
101,827 



4,313,541 



2,889,029 



1,988,769 

85,717 

302,528 

74,642 

437,373 

154, 903 

1,269,609 

79,062 

180,353 

31,276 



39,216 



109, 932 

18,043 
38,401 
328, 517 
184,002 
144,515 
135,060 
65,121 
243,728 



1,877,551 



119,559 



64,647 
54,912 

31,945 
4,327 

10,493 
1,160 
2,221 



1.000 
pounds 
1,393,984 
6,040 
135,517 

123,017 



77,354 

1,696 

43,967 

277,091 



3,105,423 



2,037,761 



1,305,151 
70,950 

276, 143 
63,295 

322,222 

155,181 
912,481 



71,923 

121,713 

27, 611 

51,401 

24,399 

4,271 
82,890 

7,387 

35,477 

242,414 

146,324 

96,090 

118,475 

53,232 

71, 288 



910,741 



115,329 



66,158 
49,171 

21,820 
3,716 
5,876 
1,167 
1,961 



1.000 
dollars 
43,589 
1,189 
16, 556 

19, 560 



9,456 

438 

9,666 

31,161 



399,387 



224,607 



98,345 
15,964 
26,529 
12,567 
71,202 

33,037 

141,743 



12,245 

11,496 

3,218 

8,264 

4,167 

508 
13,500 

1,148 
8,636 
36,659 
21,203 
15,456 
17, 924 
9,362 
14, 616 



157,756 



12,126 



7,344 
4,782 

4,721 

702 

1,125 

1,145 
409 



Per 
pound 



MISCELLANEOUS CHEMICALS 
TABLE 21A. — Miscellaneous chemicals; U.S. production and sales, i567-- Continued 



59 



Chemicals 



Production 



Sales 



Quantity 



Value 



Unit 
value^ 



MISCEUANEOUS CHIMICALS, ACYCLIC— Continued 
Estt^rs of Monohydric Alcohols — Continued 

Distearyl 3,3 '-thiodipropionate 

Ethyl acetate, 855^- 

Ethyl acrylate 

Ethyl chloroaoetate 

Isobutyl acrylate 

Iso-octyl mercaptoacetate 

Isopropyl acetate 

Methyl esters of tallow 

Methyl methacrylate 

Phosphorus acid esters, not elsewhere specified 

Vinyl acetate 

All other 

Halo^enat t^<l Hydrocarbons 

Total — 

2-Broniopentarie (1-Methylbutyl bromide) 

Carbon tetrachloride 

Chlorinated paraffins 

Chlorodifluorome thane 

Chloroethane (Ethyl chloride) 

Chloroform 

Chloromethane (Methyl chloride) 

Dichlorodifluororae thane 

1, 2-Dichloroethane (Ethylene diohloride) 

Diohloromethane (Methylene chloride) 

1,2-Diohloropropane (Propylene dichloride) 

Dichlorotetrafluoroethane 

lodomethane (Methyl iodide) 

Tetraohloroethylene ( Perchloroethylene ) 

1,1,1-Trichloroethane (Methylchloroform) 

Trichloroethylene 

Trichlorofluorome thane 

Vinyl chloride, monomer (Chloroethylene) 

ALl other halogenated hydrocarbons 

All Other Misce I laneous Acyclic Chemicals 

Total 

2-Butanone peroxide 

tert-Butyl peroxide (Di-tert-butyl peroxide) 

Carbon disulfide 

Decanoyl peroxide 

Epoxides, ethers, and acetals: 

Ethylene oxide 

Ethyl ether, all grades 

Isopropyl ether 

Methyl ether (Dimethyl ether) 

Propylene oxide 

Lauroyl peroxide 

Organo-silicon polymers 

Phosgene (Carbonyl chloride) 

Sodium formaldehyde sulfoxylate 

Sodium methoxide (Sodium methylate) 

Tetraethyllead 

Tetramethyllead'--'- 

Tetra(raethyl-ethyl)leads 

Zinc formaldehyde sulfoxylate 

ALl other 



1.000 

pounds 

137,026 
UO, 937 

2,229 

2,608 

41,929 

627 

302, 277 

52,437 

602,765 

424,606 



12,019,632 



259 

713,599 

56, 693 

618, 183 
190,886 
275,617 
309,668 
3,970,756 
262,285 
86,275 

11 
532,980 

489,964 

182,216 

2,423,572 

1,906,668 



5,702,818 



1,921 

1,436 

693,638 

928 

2,307,831 
90,081 

12,714 

813,967 

2,195 

32,329 

372,043 

4,277 

4,917 

554,759 

94,971 

203,706 

1,166 

509,939 



1,000 
pounds 

438 

131,393 

49,761 

163 

2,331 

41,433 

623 

35,391 
230,827 
268,512 



4,748,895 



605, 563 

54,596 

58, 506 

284,644 

135,771 

118,031 

289, 905 

324,031 

226,913 

28,843 

21,965 

9 

468, 663 

269,702 

472,723 

155,233 

951,695 

282, 102 



2,010,998 



1,860 

1,270 

519, 974 

940 

301,705 

75,967 

5,411 

75,847 

2,375 

28,818 

12,357 

4,397 

4,304 

528, 568 

97, 587 

197,923 

1,170 

150,525 



l.oon 

dot lars 

490 

12, 527 

10,494 

71 

1,492 
4,538 

80 

13,948 
25,776 
68,112 



555,600 



37,256 

6,787 

35,989 

19, 166 

10, 108 

7,970 

78,901 

12,636 

20,037 

740 

11,981 

30 

35,864 

30,614 

38,762 

29,433 

50, 172 

129,154 



610, 533 



2,746 

1,427 

20,414 

1,208 

26,931 

5,901 

468 

7,247 

2,317 

63,271 

1,387 

1,052 

1,321 

278,671 

44,420 

103,270 

577 

47,905 



See footnotes on following page. 



60 SYNTHETIC ORGANIC CHEMICALS, 1967 

Footnotes for table 21A 

^ Calculated from rounded figures. 

^ Statistics exclude production and sales of tricresyl phosphate. Statistics on tricresyl phosphate are given 
in the section "Plasticizers. " 

■' Quantities are given on the basis of solid naphthenate, tallate, or linoleate content. 

* Statistics exclude production and sales of copper naphthenate. Statistics on copper naphthenate are given in 
the section "Pesticides and Related Products." 

^ Statistics exclude production and sales of fatty amines. Statistics on fatty amines are given in the section 
"Surface-Active Agents." 

* Production of urea in primary solution totaled 4,359,500 thousand pounds. 
' Includes estimated values for sales of urea in nitrogen compounds. 

^ Statistics exclude production and sales of potassium and sodium oleate. Statistics on these oleates are included 
in the section "Surface-Active Agents," 

^ Statistics exclude production and sales of potassium and sodium stearates. Statistics on these stearates are 
included in the section "Surface-Active Agents." 

^° Statistics on production of ethyl alcohol from natural sources by fermentation are issued by the Alcohol Tax 
Unit, U.S. Internal Revenue Service. 

'■^ Includes production and sales for use in synthesis of tetra(methyl-ethyl)leads. 



The total output of miscellaneous cyclic chemicals in 1967 was 1. 5 billion pounds, or 12 
percent more than the output of 1.4 billion pounds reported for 1966. Sales in 1967 totaled 776 
million pounds, valued at $284 million, compared with 739 million pounds, valued at $271 mil- 
lion, in 1966. In 1967 the most important groups of cyclic compounds were the lubricating oil 
additives, the output of which was 407 million pounds, and synthetic tanning materials, the output 
of which was 34 million pounds. 

Total production of miscellaneous acyclic chemicals in 1967 was 58.2 billion pounds, or 4 
percent more than the output of 55. 9 billion pounds reported for 1966. Sales in 1967 totaled 25.2 
billion pounds, valued at $3. 2 billion, compared with 23. 8 billion pounds, valued at $2. 9 bil- 
lion, in 1966. The statistics for acyclic chemicals were regrouped in 1966 primarily by chemical 
function. The order of precedence of these functional groups is generally that used in naming and 
indexing chemical compounds by Chemical Abstracts, but other important considerations are compara- 
bility with statistics for earlier years and the need for groupings that will not reveal the opera- 
tions of individual producers. Some of the groupings, by use, found in earlier reports have been 
omitted for 1967, as such groupings are difficult to maintain due to the variety of uses and frequent 
shifts in principal usage for many important items. 

In 1967, the most important groups of acyclic chemicals were the halogenated hydrocarbons, 
the nitrogenous compounds, monohydric alcohols, and aldehydes and ketones. Production of 
halogenated hydrocarbons, which are used as solvents, intermediates, refrigerants, and aerosol 
propellants, totaled 12.0 billion pounds. The most important chemicals in this group were 
dichloroethane (production of 4. billion pounds in 1967 compared with 3. 6 billion pounds in 
1966) and vinyl chloride (2.4 billion pounds compared with 2.5 billion pounds). Output of nitro- 
genous compounds totaled 9.4 billion pounds. The most important chennical in this group was urea 
(used principally in fertilizers and as a feed additive), production of which was 4. 2 billion pounds 
in 1967 compared with 3.4 billion pounds in 1966. 

Monohydric alcohols, which are used largely as solvents and intermediates, were the third 
largest group in 1967, with production of 9.4 billion pounds. The most important items in this 
group, in terms of production were synthetic methanol (3.4 billion pounds in 1967 compared with 
3. 3 billion pounds in 1966), synthetic ethyl alcohol (1. 9 billion pounds in 1967, the same as in 
1966), and isopropyl alcohol (2. 1 billion pounds in 1967, compared with 1.7 billion pounds in 
1966). Aldehydes and ketones, which are also used largely as solvents and intermediates, were the 
next largest group, with production of 8. 5 billion pounds. The most innportant items in this group 
in 1967 were formaldehyde (3.7 billion pounds), acetaldehyde (1.4 billion pounds), and acetone 
(1.3 billion pounds). 



PART in. LIST OF INDIVIDUAL PRODUCTS, BY GROUPS, AND NAMES OF 

MANUFACTURERS 

This section of the report consists of (1) a series of tables that supplement the statistical 
information given in parts I and II, and (2) a Directory of Manufacturers. The tables with num- 
bers that include the letter "B" supplement the tables in part I and II with numbers that include 
the letter "A"; for example, table 8B in part HI supplements table 8A in part II. 

Each table in part III lists the individual items in each group for which data on production 
or sales were reported for 1967. The tables include data on only those chemicals for which 
the volume of production or sales in 1967 exceeded 1,000 pounds or for which the value of 
sales exceeded $1,000. Where separate statistics for an item are given in the tables in part I or 
part II, an asterisk (*) precedes the name of the itenn in the tables in part III. The maniifacturers 
of each product are indicated by identification codes which are listed in the Directory of Manu- 
facturers (table 22). A few companies, however, have specifically requested that they not be 
identified as having produced or sold certain items. These manufacturers are indicated by a 
small letter "x" in the tables. 

Tar Crudes 

TABLE 4B. — Tar crudes for which U.S. production or sales were reported, identified by manufacturer, 1967 

[Tar crudes for which separate statistics are given in table ^k are marked below with an asterisk (*); products not 
so marked do not appear in table 4A because the reported data are accepted in confidence and may not be published. 
Manufacturers' identification codes shown below are taken from table 22. Table 22 identifies all U.S. producers of 
tar crudes (except producers that report to the Division of Bituminous Coal, U.S. Bureau of Mines)] 



Product 



Manufacturers ' identification codes 
(according to list in table 22) 



»Crude light oil-"- 

Light-oil distillates; 
*Benzene, specification and industrial grades ■"■ ■'-• 

»Toluene, specification and other grades^ ■' 

»}(ylene, all grades-"^ ^ 

"Solvent naphtha-*^ 

»A11 other light-oil distillates-"- 

pyridine crude bases^ 

•Naphthalene, crude, solidifying at — 

»Less than 74" c^ 

«74° C. to less than 79° C:^ 

74° C. to less than 76° C 

76° C. to less than 79° C 

•Crude tar-acid oils;-'- 

Tar-acid content 5!t to less than 24^^ 

Tar-acid content 24!t to 515t-' 

Cresylio acid, crude 

•Creosote oil (Dead oil): 

•Distillate as such-"- 

•Creosote in coal-tar solution-"^ 

•All other distillate products-*^ 

•Tar, road 

•Tar for other uses: 

Crude 

Refined 

Ktoh of tar; 

Soft and medium (water softening points less than 
110° F., and 110° F. to 160° F. ).^ 

•Hard (water softening point above 160° F. )■"■ 

Ritoh-of-tar coke and pitch emulsion 



CBT. 



ACY, 


KPP. 






ACY, 


KPP. 






ACY, 


KPP. 






ACY, 


NEV, 


PAI. 




ACP, 


PAX. 






ACP, 


KPT. 






COP. 








KPT. 








ACP, 


KPT, 


PRD, 


RIL. 


ACP, 


COP, 


KPT, 


RIL. 


ACP, 


RIL. 






ACP, 


KPT, 


PHD. 




ACP, 


CBT, 


COP, 


HUS, KPT, RIL, WTC 


ACP, 


JEN, 


KPT, 


RIL. 


ACP, 


KPT, 


PAI. 




ACP, 


KPT, 


RIL, 


OTC. 


KPT, 


RIL. 






ACP, 


KPT, 


RIL. 





ACP, CBT, COP, KPT, RIL. 



ACP, 
JEN, 



HUS, JEN, KPT, RIL. 
RIL. 



Does not include manufacturers' identification codes for producers that report to the Division of Bituminous 
Coal, U.S. Bureau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey, 
February 4, 1969, entitled "Coke Producers in the U.S. in 1967." 

Crude light oil production and sales of this company are not included with the U.S. Bureau of Mines figures 
given in table 4A. 

Statistics on production or sales of these items by tar distillers could not be published separately or in 
any meaningful combination without disclosing the operations of individual companies. 



61 



62 



SYNTHETIC ORGANIC CHEMICALS, 1967 
Crude Products From Petroleum and Natural Gas for Chemical Conversion 



TABLE 5B, --Crude products from petroleum and natural gas for chemical conversion for which U.S. production 

or sales were reported, identified by manufacturer, 1967 

[Crade products from petroleum and natural gas for chemical conversion for which separate statistics are given in 
table 5A are marked below with an asterisk (»); products not so marked do not appear in table 5A because the 
reported data are accepted in confidence and ma^^ not be published. Manufacturers' identification codes shown be- 
low are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the 
designated product] 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



ARCMATICS AND NAPHTHENES 

^Benzene (except motor grade): 

^Benzene, 1° 

■x-Benzene, 2° 

Cresylic acid, crude 

»Naphthalene, all grades 

^Naphthenic acids: 

Acid number lower than 150 

*Aoid number 150-199 

Acid number 200-224 

Acid number 225-249 

Sodium carbolate and phenate, crude 

»Toluene : 

«Nitratlon grade, 1° 

*Pure commercial grade, 2*^ 

^Solvent grade, 90^6 

All other 

»)^lenes, mixed: 

Aviation grade 

*3° grade 

5 grade 

All other 

»A11 other aromatics, naphthenes, distillates and 
solvents. 



ALIPHATIC HYDROCARBONS 

C-^ hydrocarbon: Methane 

*C2 hydrocarbons : 

»Acetylene 

»Ethane 

»Ethylene 

0,2 and C3 hydrocarbons, mixed 

*C3 hydrocarbons: 

*Propane 

*Propane-propylene mixture 

■"Propylene 

*0i, hydrocarbons : 

»1, 3-Butadiene, grade for rubbers (elastomers 

"Butadiene and butylene fractions 



ACU, APR, ASH, ATR, CCP, CO, COR, CSD, CSP, DLH, DXS, 
ENJ, GOC, GRS, MOC, MON, PLC, SHO, SKO, SM, SNT, SOG, 
SUN, TOO, TX, UOC, VEL, VPT. 

ACC, DOW, SHO, SOC, UCC. 

PRD, SHO. 

ASH, COL, MON, SUN, TID. 

ATR, SUN. 

ATR, PRD, SOC, SUN. 

ATR, PRD, SOC. 

PRD, SOC, TX. 

ATR, GOC, SIN. 

ASH, ATR, COR, CSD, DLH, DXS, ENJ, GOC, MOC, MON, PLC, 
SHO, SIN, SNT, SOG, SUN, TOC, TX, UCC, UOC, VEL, VPT. 

ATR, CSP, DOW, ENJ, LEN, MON. 

CO, FG, SKO. 

ACC, ATR, COR, CSO, DXS, ELP, GRS, PLC, SHO, SM, SOC, 
TOC, TX, VPT. 

CSD, CSO, SOG. 

ATR, COR, DLH, ENJ, MOC, MON, SNT, UOC. 

ASH, SIN, TX. 

ATR, CCP, CSD, CSO, CSP, ENJ, GRS, LEN, MON, SHO, SM, 

SOC, SUN, TOC. 
ACC, DUP, ELP, ENJ, FG, GOC, JCC, LEN, MOC, MON, PLC, 

SHC, SOC, SOI, TX, USI, VPT. 



CCP, MON, UCC. 

DOW, DUP, MNO, MON, UCC, x. 

ACU, CCP, ENJ, MON, PAN, PLC, SHO, SM, SOI, TX, UCC, 

USI. 
ATR, BPG, CBN, CCP, DOW, DUP, EKX, ELP, ENJ, GOC, JCC, 

KPP, MON, CMC, PLC, SHC, SM, SNO, TX, UCC, USI. 
COR, CSO, GYR, MON, PLC, SM. 

AMO, APR, ASH, CCP, CSD, CSO, DXS, ENJ, GOC, GRS, MOC, 

CMC, PAN, PLC, SHO, SIN, SM, SNT, SOG, SOI, SPI, UCC, 

UOC, USI. 
GOC, MOC, TX. 
AMO, ASH, ATR, BFG, CBN, CCP, CSO, DOW, EKX, ELP, ENJ, 

GOC, JCC, KPP, MOC, MON, PLC, SHC, SHO, SIN, SIO, SM, 

SNT, SOG, SOI, SPI, SUN, UCC, UOC. 

CBN, CPY, DOW, DUP, ELP, ENJ, FRS, GGC, ILC, MON, PLC, 
PTT, SHC, SHO, SM, SOC, SPI, TID, TUS, UCC. 

DOW, GOC, GXR, KPP, MOC, PLC, PTT, SHO, SIN, SM, SOC, 
SPI 



CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS 



63 



TABLE 5B. --Crude products from petroleum and natural gas for chemical conversion for which U.S. production 
or sales were reported, identified by manufacturer, i567--Continued 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



ALIPHATIC HYDROCARBONS— Continued 

*Ci, hydrocarbons — Continued 

»n-Butane 

»1-Butene 

2-Butene 

»1-Butene and 2-butene mixture 

^^Isobutane 

*Isobutylene 

All other 

»C5 hydrocarbons: 

Isopentane (2-Methylbutane) 

»Isoprene (2-Methyl-l,3-butadiene ) 

»ii-Pentane ^ 

All other 

C(, hydrocarbons : 

*Hexane 

Neohexane (2,2-Dimethylbutaiie) 

All other 

C7 hydrocarbons : 

n-Heptane 

^Heptanes, mixed 

All other 

Ce hydrocarbons : 

»Diisobutylene (Diisobutene) 

n-Ootane 

2, 2,4-Trimethylpentane ( Iso-octane) 

All other 

[tydrocarbons, C9 and above: 

»Nonene (Tripropylene) 

*Polybutene 

*Tetrapropylene 

Tridecene concentrate 

Triisobutylene 

All other 

*A11 other aliphatic hydrocarbons and derivatives: 
l^drocarbons : 
*Alpha olef ins--^tolecular weight ranges: 

C5-C7 

Cff-Cio 

C11-C15 

All other 

*Hydrocarbon derivatives: 

1-Butanethiol 

tert-Butyl-raercaptan (2-Methyl-2-propaiiethiol ) 

Di-tert-butyl disulfide 

Ethyl mercaptan ( Ethanethiol ) 

Isopropyl mercaptan 

Methyl mercaptan (Methanethiol) 

tert-Octyl mercaptan 

n-Propyl mercaptan (l-Propanethiol) 

All other 



COR, CSD, DXS, GRS, CMC, PAN, PLC, SHO, SM, SNT, SOC, 

SOG, UCC, USI. 

GDC, PLC, PTT. 

MON, PLC, PTT. 

CSC, ENJ, GOC, PLC, PTT, SHO, SOC, SPI, TX, UOC. 

DXS, ELP, GRS, CMC, PAN, PLC, SHO, SOI, UCC, USI, X. 

ENJ, PTT, SHC, SIN, UOC. 

APR, BFG, JCC, MON, PLC, UCC, USI. 

PAN, PLC, SHO, SM. 

ENJ, GYR, MON, SHC. 

APR, ASH, MOC, PLC. 

ENJ, GYR, MON, PLC, SHC, UCC, USI. 

ATR, ENJ, PLC, SOG, UOC. 

PLC. 

APR, PLC. 

EKX, PLC, UOC. 

CSD, ENJ, GOC, HOU, SIN, SOI, TID. 

PLC. 

ATR, PTT, TX. 

PLC. 

ENJ, GRS, PLC. 

PLC. 

ATR, ENJ, GOC, UOC. 

ACC, CSD, SOC, SOI. 

ATR, CO, DXS, ENJ, GOC, MOC, SOC, SUN, TX, UOC. 
ENJ. 
ATR. 

CO, COR, ENJ, GOC, HOU, KEN, PLC, SHC, SOC, SPI, SUN, TID, 
UCC, X. 



GOC, GYR, PLC, SOC. 

GOC, SOC. 

ENJ, GOC, SOC. 

EKX, GOC, KPP, SOC. 

PAS. 

PAS, PLC. 

PAS, PLC. 

PAS, SOC. 

PAS, SOC. 

ACC, PAS. 

PAS. 

PAS. 

EKX, PAS, PLC, SOC. 



64 



SYNTHETIC ORGANIC CHEMICALS, 1967 
Cyclic Intermediates 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, 1967 

[Cyclic Intermediates for which separate statistics are given in table 7A are marked with an asterisk (*); cyclic 
intermediates not so marked do not appear in table 7A because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



Aceanthryleno[2,l-a]aceanthrylene-5,13-dione 

8-Acetamido-l-(i-acetamido-2-hydroxy-5-nitrophenylazo)- 
2-naphthol. 

5-Acetamido-2-amlnobenzenesulfonic acid 

3-[(2-Acetamido-<i-aminophenyl)azo]-l,5-naphthalenedisul- 
fonic acid. 

l-Acetamido-'4-bromoanthraquinone 

2-Acetamido-3-chloroanthraquinone 

«-Acetamido-p-toluenesulfonamide 

2,2'-[(5-Acetamido-2-ethoxyphenyl)imino] diethanol 

*Acetanilide, tech 

Acetic acid, phenyl ester 

Acetoacetanilide 

**-o-Acetoacetanisidide 

o-Acetoacetotoluidide 

2 ',"4 '-Acetoaoetoxylidide 

I'-Acetonaphthone 

Acetone phenylhydrazone 

*Acetophenone, tech 

p-Acetotoluidide 

N-Aoetylanthranilic acid 

p-Aoetylbenzenesulfonamide 

p-Acetylbenzenesulfonic acid, sodium salt 

p -Ac etylbenzenesulfony lure thane 

N-.Acetylsulfanilic acid, sodium salt 

N-Acetylsulfanilyl chloride 

Adenine 

Adrenostrone 

*Alkylbenzenes ; 

Dodecylbenzene (including trideoylbenzene) : 

Straight chain 

Other 

Other alkylbenzenes : Straight chain 

Alky Iphenols , mixed 

Alkylpiperazines, mixed 

Alkylpyridine 

[o-(Allylcarbamoyl)phenoxy] acetic acid 

6-Allyl-o-cresol 

a-dl-5-Allyl-6-imino-l-methyl-5-(l-methyl-2-pentynyl)- 

barbituric acid. 
Aminoaceanthryleno [2,1-a] aceanthrylene-5,13-dione 

3 '-Aminoacetanilide 

*<+' -Aminoacetanilide (Acetyl-p-phenylenediamine) 

3 ' -Aminoacetophenone 

*5-Amino-2-(p-aminoanilino)benzenesulfonic acid 

l-Amino-'i-(3-amino-'t-sulfoanilino)-9,10-dihydro-9,10- 

dioxo-2-anthracenesulfonlc acid. 
l-Amino-4-('i-amino-3-sulfoanilino)-9,10-dihydro-9,10- 
dioxo-2-anthracenesulfonic acid. 

*2-(p-Aminoanilino)-5-nitrobenzenesulfonic acid 

3-Amino-p-anisanilide 

»l-Aminoanthraquinone and salt 

*2-Aminoanthraquinone and salt 

5(and 8)-Amino-l-anthraquinonesUlfonio acid 

N-('i-Amino-l-anthraquinonyl)anthranilic acid 

N-(5-Amino-l-anthraquinonyl)anthranilic acid 

N-(8-Amino-l-anthraquinonyl)anthranilic acid 

i-Aminoantlpyrine 

*6-Amino-3,i'-azodibenzenesulfonic acid (C.I. Acid 
Yellow 9). 

p-Aminobenzamide 

*l-Amino-4--benzamidoanthraquinone 

*l-Amino-5-benzamidoanthraquinone 

7-[p-(p-Aminobenzamido)benzamido]-'i-hydroxy-2-naphtha- 
lenesulfonic acid. 



ICI. 
TRC. 

GAF. 
TRC. 

AAP. 

ICI. 

SDW. 

AAP. 

CTN, 

UCC. 

FMP, 

MP, 

FMP, 

PMP, 

GIV. 

DUP. 

ACP, 

ACY. 

DUP. 

LIL. 

LIL. 

LIL. 

ALL. 

ACY, 

KF. 

UPJ. 



EKT, MRK, SAL, SW. 

UCC. 

SDH, UCC. 
UCC. 
UCC. 



SKO, UCC, UOP. 



CTN, MRK, SAL. 



ACS, ATR, CO, MON, PLC, UCC, WCC. 

ACS, CO, SOC. 

SOC. 

GAF, ORO. 

HOU. 

UCC. 

SDW. 

ICO. 

LIL. 

ICI. 

AAP. 

AAP, ACS, DUP, GAF, TRC. 

CTN, SDH. 

CMC, GAF, YAW. 

TRC. 

TRC. 

ACS, CMG, TRC. 

PCW. 

AAP, ACS, ACY, DUP, GAF, ICI, MAY, TRC. 

ACS, ACY, DUP, GAF, TRC. 

ICI. 

GAF. 

DUP. 

DUP. 

SDW. 

ACS, ACY, CMG, TRC. 

SDH. 

ACY, MAY, TRC. 

ACS, GAF, ICI, TRC. 

DUP. 



CYCLIC INTERMEDIATES 



65 



TABLE 1B.--Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



7-(m-Aminobenzamido) -^-hydroxy-2-naphthalenesulf onic acid 

7-(p-Aininobenzamido)-'i-hydroxy-2-naphthalenesulfonic acid 

7-(p-Arainobenzaiiiido)-5-hydrQxy-3-naphthalenesulfonio acid — 
3 '-Aminobenzanilide-'i' -sulfonic acid 

*2-Amino-p-benzenedisulfonic acid [S03H=1) 

o-Aminobenzenesulfonio acid 

o-Aminobenzene thiol 

2-Ajiiinobenzimidazole 

5-Amino-2-benziraidazolinone 

p-Aminobenzoic acid, tech 

p-Aminobenzoic acid, 2-(dimethylamino)ethyl ester 

2-Aniino-6-benzothiazolecarboxylic acid 

p-Araino-N-benzyl-N-ethylbenzenediazonium ohlorostannate 

p-Amlno-N-benzyl-N-ethylbenzenediazonium chlorozincate 

N-(4-Ajiiino-3-brcmo-l-anthraquinonyl)anthranilic acid 

N-(4-Ainino-3-bromo-l-anthraquinonyl) -p-toluidine sulfonic 

acid. 
2-Amino-l-bromo-3-chloroanthraquinone 

»l-Ainino-'i-bronio-9,10-dihydro-9,10-dioxo-2-anthraoenesulfonic 
acid and sodium salt. 

*l-Amino-2-bromo-'i-hydroxyanthraquinone 

l-Ainino-4-brorao-2-methylanthraquinone 

6-Amino-7-bromonaphth[2,3-clacridan-5,8,W-trione 

*l-Amino-2-bramo-4-p-toluidinoanthraquinone 

**l-Amino-5-chloroanthraquinone 

l-Amino-8-chloroanthraquinone 

2-Ainino-l-chloroanthraquinone 

2-Amino-3-chloroanthraquinone 

4--Ainino-6-chloro-ni-ben2enedisulf onamide 

4-Amino-6-chloro-m-benzenedisulfonamide hydrochloride 

2-Amino-5-chlorobenzophenone 

2-Amino-6-chlorobenzothiazole hydrochloride 

o-(3-Aniino-'+-chlorobenzoyl)benzoic acid 

2-Ainino-5-Ghloro-p-cumenesulfonic acid 

2-Amino-5-ohloro-^-ethylbenzenesulfonic acid 

3-Amino-5-chloro-2-hydroxybenzenesulfonic acid 

2-Amino-'i-chlorophenol 

2-Amino-6-chloropyrazine 

3-Amlno-6-chloropyridazine 

2-Amino-5-chloro-p-toluenesulfonic acid [S03H=1] 

»6-Amlno-4-chloro-m-toluenesulfonio acid [S03H=l] 

2-Amino-p-cresol 

*l-Amino-2,4-dibromoanthraquinone 

5(and 8)-Amlno-6,8(and 5,7)-dibromo-9,10-dihydro-9,10-dioxo- 
1-anthracenesulfonio acid. 

2-Amlno-A,5-dichlorobenzenesulfonlc acid 

'+'-A]nino-2 ',5 '-diethoxybenzanilide 

l-Amino-9,10-dihydro-9,10-dloxo-2-anthroic acid 

l-Amlno-9, lO-dlhydro-9, lO-dioxo-'i-p-toluenesulf onamido-2- 

anthracenesulfonic acid, sodium salt. 
S-Amino-^.S '-dihydroxy-3,<i'-[(2-methoxy-5-methyl-p-phenyl- 
ene)bis(azo) ]-dl-2,7-naphthalenedlsulfonlc acid, 
5 ' -benzenesulf onate. 

2-Amino-'4-(a,a-dimethylbenzyl)phenol 

3-Aiiiino-^-ethoxyacetanilide 

3-Amino-9-etliylcarbazole 

3-Amino-^''--ethylhydrocinnajnic acid 

p-Amlno-N-ethyl-N-hydroxyethyl benzenedlazonium chloro- 
zincate. 

p-Amino-N-ethyl-N-1-naphthylbenz amide 

l-Amino-'V-hydroxyanthraqulnone 

2-Ainino-3-hydroxyanthraqulnone 

l-Amlno-'4-hydroxy-2-methoxyanthraqulnone 

4-Amlno-5-hydroxy-2,7-naphthalenedisulfonic acid, benzene- 
sulf onate. 
3-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid (2R acid), 

monosodlum salt. 
4.-Amlno-5-hydroxy-l,3-naphthalenedisulfonio acid (Chicago 

acid), monosodlum salt, 
4-Amino-5-hydroxy-2,7-naphthalenedisulfonlc acid (H acid), 
monosodium salt. 

*4-Amlno-3-hydroxy-l-naphthalenesulfonic acid (1,2,4 acid) — 



TRC. 

CMC, 

VPC. 

TRC. 

ACS, 

DUP. 

FIS. 

EK. 

DUP. 

DUP, 

SDW. 

DUP. 

ESA. 

ESA. 

TRC. 

TRC. 

ICI. 
DUP, 

AAP, 

ICI. 

TRC. 

GAP, 

ACS, 

DUP. 

DUP. 

GAF, 

ABB. 

ABB. 

LIL. 

DUP. 

AAP, 

SW. 

ACY. 

CMC, 

ACS, 

ACY. 

ACY. 

ACY, 

ACY, 

TRC. 

AAP, 

ICI. 

SW. 

OAF. 
DUP. 
DUP, 

TRC. 



DUP, GAF. 
DUP, ICC, TRC. 

LEM. 



ICI, TRC. 

DUP, GAF, ICC, TRC. 



ICI, TRC. 

ACY, ICI, MAY, TRC. 



ICI. 



OAF, ICI. 



TRC. 
GAF, MEE. 



HSC, SW. 

DUP, HSC, SDH, SW. 

ACS, DUP, OAF, ICC, ICI, TRC. 



GAF. 



TRC. 
AAP. 
SDC. 
SDW. 
ESA. 










GAF. 
DUP, 
ACS, 
TRC. 
TRC. 


GAF. 
GAF. 








ACS, 


DUP. 








ACS, 


DUP. 








ACS, 


DUP, 


MON. 






ACS, 


ACY, 


GAF, 


TRC, 


VPC 



66 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 7B.- 



-Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer, i967--Contmued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



*6 

*7 

3 
6 

2 

1 

5 
4 

1 



8 

3 

7 

*A 
1 
4 

2 

2 

2 

2. 

2. 

2 

1. 

1-. 

6-. 

2 

3-. 

3-, 

4-. 

4-. 
^<€-. 
*7 

6 

1-. 

2 
»4-. 

4- 

4( 

5 
»5-. 
*5C 

*6 

»8-. 

*8 

7-. 

8 

5( 

8-. 

3 
»2-. 
»2 

2 

4 

d 



-Amlno-5-hydroxy-l-naphthalenesulfonic acid (S acid), 
sodium salt. 

-Amino-4-hydroxy-2-naphthalenesulfonic acid (Gamma acid), 
sodium salt. 

-Amlno-4-hydroxy-2-naphthalenesulfonlc acid (J acid), 
sodium salt. 

'-Amino-2 '-hydroxy-5 '-nitroacetanilide 

-Ainino-5-[(2-hydroxy-4-nitrophenyl)azo] -2-naphthalenesul- 
fonic acid. 

■(2-Amino-5-hydroxy-7-sulfo-l-naphthylazo)-5-nitrobenzoic 
acid. 

•(6-Amino-l-hydroxy-3-sulfo-2-naphthylazo)-6-nitro-2- 
naphthol-4-sulfonic acid. 

■Aminoisophthalic acid 

■itaino-3-(p -methanesulf anamidoethyl ) -N, N-diethylaniline 
hydrochloride. 

■Amino-4-methoxyanthraquinone 

■(4-toiino-3-methoxy-l-anthraquinonyl)-p-toluene sulfon- 
amide. 

■[ (4-Amino-3-methoxyphenyl)azo]benzenesulfonic acid 

■Amino-6-methoxyquinoline 

■ [(4-Amino-5-methoxy-o-tolyl)azo]-4-hydroxy-2,7-naphtha- 
lenedisulfonio- acid, benzenesulfonate. 

■ [(4-Amino-5-methoxy-o-tolyl)azo]-l,5-naphthalenedisul- 
fonic acid. 

■ [(4-Amino-5-methoxy-o-tolyl)azo]-l,3-naphthalenedisul- 
fonio acid. 
-Amino-N-methylacetanilide 

•Amino-2-methylantftraquinone 

■Amino-4'-(3-methyl-5-oxo-2-pyrazolin-l-yl)-2,2 '-stil- 
benedisulfonic acid. 

■Anino-3-methylpyridine 

■Amino-5-jnethylpyridine 

■Amino-6-methylpyTidine 

■Amino-4-methylpyrimidine (2-Amino-4-methyl-l,3-diazine)-- 

■Amino-4-(methylsulfonyl)phenol 

■Amino-5-methyl-l,3,4-thiadiazole 

■Amino-2 -methyl -4-p-toluidinoanthraquinone 

Aminonaphth[2,3-c]acridan-5,8,14-trione 

■Aminonaphth[2,3-c]acridan-5,8,14-trione 

Amino-l,5-naphthalenediEUlfonic acid 

Amino-l,5-naphthalenedisulfonic acid (C acid) 

Amino-2, 7-naphthalenedisulfonio acid 

Amino-l,5-naphthalenedisulfonic acid 

Amino-l,6-naphthalenedisulfonic acid 

J\mino-l,3-naphthalenedisulfonic acid (Amino I acid) 

Amino-l,3-naphthalenedisulfonic acid (Amino G acid) 

Amlno-1-naphthalenesulfonamide 

Amino-2 -naphthalenesulfonic acid (o-Naphthlonic acid) 

Amino-1-naphthalenesulfonic acid (Tobias acid) 

Amino-1-naphthalenesulfonio acid (Naphthionic acid) 

Amino-1-naphthalenesulfonic acid, sodium salt 

and 5)-Amino-l-naphthalenesulfonic acid 

Amino-1-naphthalenesulfonic acid (Laurent's acid) 

Amino-2 -naphthalenesulfonic acid (1,6-Cleve's acid) 

and 8) -Amino-2 -naphthalenesulfonic acid (Cleve's acid, 
mixed) . 

Ainino-2 -naphthalenesulfonic acid (Broenner's acid) 

Amino-1-naphthalenesulfonic acid (Peri acid) 

A.Tiino-2 -naphthalenesulfonic acid (l,7-Cleve's acid) 

Amino-l,3,6-naphthalenetrisulfonic acid 

Amino-l,3,6-naphthalenetrisulfonio acid (Koch's acid) 

and 8) -Amino-2 -naphthol 

■Amino-2 -naphthol 

Amino-5-(m-nitrobenzamide)-p-toluenesulfonic acid 

Amino-5-nitrobenzenesulfonic acid [S03H=l] 

Amino-4-nitrophenol 

■Amlno-5-nltrophenol 

■Amino-2 -nitrophenol 

■2 -Amlno-l-(p-nitrophenyl) -1,3 -propanediol 

■2-Amino-l-(p-nitrophenyl) -1,3-propanediol 

■Amino-4'-nitro-2,2 '-stilbenedisulfonic acid 



ACS. 

ACS, DUP, TRC. 

ACS, BKS, DUP, TRC. 

TRC. 
TRC. 

TRC. 

TRC. 



GAF. 








EKT. 








DUP. 








AAP, 


DUP, 


GAF. 




DUP, 


TRC. 






SDW. 








TRC. 








TRC. 








TRC. 








ACS, 


CMG, 


GAF. 




DUP, 


ICI. 






TRC. 








RIL. 








RIL. 








NEP, 


RIL. 






ACT. 








ACS, 


TRC. 






ACY. 








ICI. 








DUP. 








GAF. 








ACT, 


SDH. 






GAT, 


TRC. 






TRC. 








ACS. 








DUP. 








ACS, 


ACY, 


BKS, 


DUP, TRC 


ACS, 


DUP, 


TRC. 




VPC. 








DUP. 








ACY, 


sw. 






ACS, 


ACT, 


DUP. 




ACS, 


DUP. 






ACT, 


TRC. 






ACS, 


DUP. 






ACS, 


ALL, 


DUP, 


TRC. 


ACS, 


ALL, 


TRC. 




ACS, 


SNA, 


TRC. 




ACS, 


DUP, 


SDC, 


TRC. 


ACS, 


ALL, 


DUP, 


TRC. 


DUP. 








ACS, 


DUP. 






GAF. 








CMG, 


TRC, 


VPC. 




GAF. 








ACS, 


DUP, 


GAF, 


TRC. 


ACS, 


DUP, 


TRC. 




ACY. 








PD. 








PD. 








ACS, 


GAF, 


ICI, 


TRC. 



CYCLIC INTERMEDIATES 



67 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, 796"--Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



2-Aniino-5-nitrothiazole 

3 '-Aminooxanilic acid 

"i'-Aminooxanilio acid 

5-Amino-2- [(2-oxo-5-benzijnidazolinyl)amino] benzenesulfonic 
acid. 

p-Aminophenethyl alcohol 

5-Amino-2-o-phenetidinobenzenesulfonic acid 

o-Aminophenol 

p-Aminophenol 

m-[(p-Aniinophenyl)azo] benzenesulfonic acid 

*p-[(p-Aininophenyl)azo] benzenesulfonic acid 

7-[('i-Aminophenyl)azo] -1,3-naphthalenedisulfonic acid 

8-Amino-5-(phenylazo)-2-naphthol 

5- [(p-Ainlnophenyl)azo] salicylic acid 

2,2 '-(m-Aminophenylijiiino)diethanol, diacetate ester 

2-(p-Aminophenyl)-6-niethylbenzothiazole 

2-(p-Aiiiinophenyl)-6-methyl-7-benzothiazolesulfonic acid and 
salt. 

l-(m-Ajninophenyl)-5-oxo-2-pyrazoline-3-carboxylic acid 

/ -2 -Amino-l-phenyl-1, 3 -propanediol 

3-Aminopyrazole-4-carboxamide sulfate 

2-AminopyTidine 

3-Aminopyridine 

i-Aminopyridine 

2-Aminopyrimldine 

3-Aniinoquinoline 

5-Aminosalicyclio acid 

N-(<i-Aiiiino-3-sulfo-l-anthraquinonyl)anthranilic acid 

3 '-(3-Amino-A-Eulfophenylsulfamoyl) -3 ' '-sulfamoyl- 
3-phthalocyaninesulfonic acid, copper derivative. 
l-Amino-2,3,6,7-tetrahydro-4,5,8-trihydroxyanthraquinone — 

2-Aminothiazole 

3-Ainino-p-toluajnide 

a-Amino-p-toluenesulfonamide 

5-Aioino-o-toluenesulfonanilide 

»4-Amino-m-toluenesulfonic acid [S03H=1] 

»6-Amino-m-toluenesulfonic acid [S03H=1] 

5-Ainino-2-p-toluidinobenzenesulfonic acid 

m-('V-Amino-m-tolylazo)benzenesulfonic acid 

3- [(<i-Amino-o-tolyl)azo] -1,5-naphthalenedisulfonic acid 

7- [('i-Ainino-o-tolyl)azo] -1,3-naphthalenedisulfonic acid 

16-Aininoviolan throne 

2-Amino-3,5-xylenesulfonio acid [S03H=1] 

5-Amino-2,'V-xylenesulfonic acid 

t-Amylcyclopentadienyloyclopentadienyliron 

"Aniline (Aniline oil) 

Aniline hydrochloride 

l-Anilino-9,10-dihydro-9,10-dioxo-2-anthroic acid 

l-Anllino-A-hydroxyanthraquinone 

6-Anilino-'4-hydroxy-2-naphthal'enesulfonic acid (Phenyl 
gamna acid). 

»7-Anllino-'»-hydroxy-2-naphthalenesulfonic acid (Phenyl J 
acid ) . 

*Anilinomethanesulfonio acid and salt 

*8-Anilino-l-naphthalenesulfonic acid (Phenyl peri acid) 

m-Anilinophenol 

p-Anilinophenol 

3-Anilinopropionitrile 

•o-Anisidine 

p-Anlsidine 

l-p-Anisidino-4-hydroxyanthraquinone 

*o-Anisidincmethanesulfonic acid 

Anisole, tech 

p-Anisoyl chloride 

4-(o-Anisylazo)-o-anisidine 

Anthracene, refined 

Anthranilic acid (o-Aminobenzolc aoid)^ 

*Anthra[l,9-cd)pyrazol-6(2H)-one ( Pyrazoleanthrone ) 

Anthraquinone, 100^ 

l>l'-[l,5(and 1,8)-Anthraquinonylenediamino]bisnaphth[2,3- 
c]acTidan-5,8,li-tTione. 

»N,N '-(l,5-Anthraquinonylene)dianthranilic acid 



ACY. 
CMC. 
DUP. 
DUP. 

EKT. 
ACS. 
SDC. 
DUP, 
DUP, 
ACS, 
TRC. 
ALL. 
TRC, 
DUP. 
ACS, 
DUP, 



SDC. 
TRC. 
ACY, CMG, DUP, GAF, TRC. 

VPC. 

DUP. 
TRC. 



TRC, VPC. 

PD. 

x. 

NEP, RIL. 

RIL. 

NEP, RIL. 

ACY. 

EK. 

AAP. 

GAF. 

DUP. 



MRK. 



DUP, GAF. 
HSC, SNA, SW. 
TRC. 



DUP. 
ACY, 
SDH. 
SDW. 
GAF. 
ACY, 
DUP, 
DUP, 
TRC. 
TRC. 
TRC. 
GAF. 
SDH. 
DUP. 
ARA. 
ACS, 
ACY. 
ACS. 
AAP. 
DUP. 



ACS, ALT, CMG, DUP, GAF, TRC. 



ACY, DUP, FST, MOB, RUC. 



AAP, 


ACS, 


ACY, 


ATL, 


DUP, TRC, 


ACS, 


CMG, 


DUP, 


SDC. 




GAF. 










SDC. 










GAF. 










AAP, 


DUP, 


MON. 






DUP, 


MON. 








AAP. 










ACS, 


ATL, 


DUP, 


GAF, 


TRC, VPC. 


DUP, 


LIL. 








ICO. 










AAP. 










ACP. 










ACS, 


DUP, 


LEU, 


MEE. 




DUP, 


GAF, 


TRC. 






ACY, 


DUP, 


GAF, 


TRC. 




DUP. 










GAF, 


ICI, 


TRC. 







See footnotes at end of table. 



68 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE ^B.--Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



N,N '-(l,5-Anthraquinonylene)dioxamic acid 

(l-Anthraquinonyl)-l,2-hydrazinedisulfonic acid, disodium 
salt. 

Arsanilio acid and salt, tech 

Aryldiamines, mixed 

4' ,4 ' ' '-Azobis [<V-biphenylcarboxylio acid] 

3,3 '-Azoxydianiline 

Barbituric acid 

Barbituric acid, sodium derivative 

*Benzaldehyde, tech 

N-(5-Benzaraido-l-anthraquinonyl)-p-toluenesulfonamide 

l-Benzamido-4-bromoanthraquinone 

l-Benzamido-A-chloroanthraquinone 

*l-Benzamido-5-ohloroanthraquinone 

l-(<i-Benzamldo-2,5-diethoxyphenyl)-3-[methyl-3-(2-sulfo- 
ethyl ) triazene]. 

'i-Benzamido-5-hydroxy-2,7-naphthalenedisulfonic acid 

7-Benzamido-'4-hydroxy-2-naphthalenesulfonic acid 

N-(4-Benzamido-6-methoxy-m-tolyl) -N-(melthylazo) glycine 

Benzanilide 

<f7H-Benz [de] anthracen-7-one (Benzanthrone) 

m-Benzenedisulfonic acid 

Benzenesulfonamide 

Benzenesulfonic acid 

Benzenesulfonyl chloride 

l,2,'i,5-Benzenetetracarboxylio acid 

»l,2,'i,5-Benzenetetracarboxylic-l,2:'i,5-dianhydride 

1,3,5-Benzenetrioarboxylic acid 

1,2,'i-Benzenetricarboxylic acid, 1,2-anhydride (Trimel- 

lltic anhydride). 
1,2,4-Benzenetrioarboxylic acid, l,2-anhydride-4-acid 

chloride. 

Benzhydrol (Diphenylmethanol) 

Benzidine hydrochloride and sulfate 

Benzil (Bibenzoyl) 

Benzilic acid 

2-Benzofuranacetonitrile 

*Berizoic acid, tech-"- 

Benzoic acid, hydrazide 

Benzoic anhydride 

Benzoin 

Benzonitrile 

Benzophenonetetracarboxylic dianhydride 

*2-Benzothiazolethiol (2-Mercaptobenzothiazole), sodium 

salt. 

IH-Benzotriazole 

2H-3,l-Ben2oxazine-2,'i(lH)-dione 

2-Benzoxazolinone 

Benzoylacetic acid, ethyl ester 

»o-Benzoylbenzoic acid 

Benzoyl chloride 

2-Benzoyl-<i-sulfobenzoic acid 

2-Benzoyl-4'-(p-toluenesulfonamido)acetanilide 

N-Benzylacetamide 

Benzylamine 

4-(Benzylamino)-6-chloro-m-benzenedisulfonlc acid 

2-(Benzylamino)ethanol 

'i-Benzyl-6-chloro-3-keto-2 -methyl -V-sulfamyl-l, 2, li-benzyl- 

thiadiazine-l,l-dioxide. 
'i-Benzyl-6-chloro-3-keto-7-sulfamyl-l,2,4-benzyl- 

thiadiazine-1, 1-dioxide. 
1-Benzyl -4, 5 -dimethyl -6-(p-methoxybenzyl) -1,2, 3,6- 

tetrahydropyridine oxalate. 

Benzyl disulfide 

Benzyl ether (Dibenzyl ether) 

5-(Benzylethylamino) -o-toluenesulf onic acid 

N-Benzyl-N-ethyl-m-toluidine 

3-Benzyl-l,2,3,4, 5,6-hexahyd^o-8-hyd^oxy-cis-6,ll-dimethyl- 
2,6-methano-3-benzazocine hydrobromide. 

Benzylidene phthalide 

p-(Benzyloxy)phenol 

l-Benzyl-4-phenylisonipecotic acid 



OAF, 


MEE. 












DUP, 


GAF. 












ABB, 


FIM. 












DA. 














DUP, 


GAF, 


TRC. 










VPC. 














ABB, 


LIL. 












ABB, 


KF. 












BPC, 


HN, 


VEL. 










ACS, 


ICI. 












AAP. 














DUP, 


GAF, 


TRC. 










ACS, 


AGY, 


DUP, 


GAF, 


ICI, 


MAY, 


TRC. 


GAF. 














TRC. 














TRC. 














GAF. 














DUP. 














AAP, 


ACS, 


ACY, 


ATL, 


CMG, 


DUP, 


GAF, ICI, MAY, SDC, 


TRC. 












KPT, 


UPF. 












NES. 














NES, 


UPF. 












NES. 














DUP, 


X. 












DUP, 


PCR, 


X. 










ACC. 














ACC. 















ICO. 



PD, 


UOP. 


ACS, 


LAK, X. 


Lm. 




BPC, 


LEM. 


EK. 




HK, 


HN, MON, PFZ, VEL 


UP J. 




EK. 




BPC, 


LEM. 


VEL. 




GOC. 




ACY, 


GYR, MON, USR. 


MEE. 
SDC. 




FMP. 




ACY, 


DUP, GAF. 


HK, 


VEL. 


DUP. 




EK. 




SDW. 




ICO, 


MLS. 


ABB. 




ABB. 




ABB. 




SDW. 




CCW. 




BPC, 


UOP. 


ACS, 


DUP. 


SDW. 




LIL. 




EK. 




SDW. 





CYCLIC INTERMEDIATES 



69 



TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



l-Bensyl-4-phenylisonipeootonitrile 

Benzyl polysulfide 

Benzyl sulfide 

Benzyltrlmethylammonium hydroxide 

Benzyltrimethylaramonium methoxide 

»[3,3'-Blanthra[l,9-cd]pyrazole]-6,6'-(2H,2' H)dione 
(pyrazoleanthrone yellow). 
[3,3 '-Bi-7H-benz [de anthracene] -7, 7 '-dione 

*[^,^' -Bi-7H-benz[de anthracene]-7,7'-dione 

[l,l'-Binaphthalene -8,8'-dioarboxylic acid 

Biphenyl 

2-Biphenylainine 

3,3',4,<i'-Biphenyltetramine 

2,2'-Biquinoline 

*1,4-Bis [l-anthraquinonylainino]anthraquinone 

1,'i-Bis (l-anthraqulnonylaminolanthraquinone and 1,4.-Bis [5- 
ohloro-1-anthraquinonylamino] anthraquinone (mixed) . 

1,5-Bis [1-anthraquinonylamino] anthraquinone 

Bis [1-anthraquinonylamino] violanthrene 

1,4-Bis[ ( 5 -benzamido-1-anthraquinonyl) amino] anthraquinone — 

a^,ci*-Bls [5-tert-butyl-6-hydroxy-m-tolyl] mesitol 

Bis(chlorosulfonyl)phthalocyaninedisulfonic acid, copper 

derivative. 
4, 4 ' -Bis [diethylamino] benzhydrol, 2, 6-naphthalenedisul- 
fonate. 

'V.'i' -Bis [diethylamino] benzophenone (Ethyl ketone base) 

4-Bis [(p-diethylaminophenyl)methyl] -2,7-naphthalenedisul- 

fonlc acid, leuco form. 
4-,'i'-Bis[dimethylamino]benzhydrol (Mlchler's hydrol) 

^i^,"*' -Bis[dimethyla]nino]benzophenone (Michler's ketone) 

l,5-Bis[2,4-dinitrophenoxy J-AjS-dinitroanthraquinone 

l,5(and l,8)-Bis[2,'i-dinitrophenoxy ]-4,8(and 'ijS)- 

dinitroanthraqulnone, 
3'- [Bis(2-hydroxyethyl)amino]benzanilide, diacetate ester — 
3 ' - [Bis ( 2-hydroxyethyl ) amino] methanesulf onanilide, 

diacetate ester. 
■4,4' -Bis [ (p-hydroxyphenyl ) azo ] -2, 2 ' -stilbenedisulf onic acid 
(C.I. Direct Yellow A). 

<t,4'-Bis(p-methoxyphenyl)-3-hexanone 

Bls(2-methyl-l-aziridinyl)phenylphosphine oxide 

2,'i-Bis(l-methylbutyl)phenol 

l,<i-Bis[2-(4-methyl-5-phenyloxazolyl) ]benzene (Dimethyl- 
POPOP) . 

Bis (o-nitrophenyl) sulfide 

1,A-Bis[ 2- (5-phenyloxazolyl)] benzene (POPOP) 

2-Bromoacetophenone 

m-Bromoaniline 

o-Bromoaniline 

p-Bromoaniline 

m-Bromoanisole 

p-Branoanisole 

»3-BraQo-7H-benz [de] anthracen-7-one ( 3 -Bromobenzan throne) — 

Bromobenzene, mono- 

p-Broraobenzenesulfonyl chloride 

'4-Bromobenzophenone 

Bromochlorobenzene 

2-Bromo-6-chloro-4-nitroaniline 

Broraocyclopentane 

2-Bromo-'4,6-dinitroaniline 

Bromoethylbenzene 

2-Bromo-3 '-hydroxyacetophenone benzoate 

l-Bromo-'+-(N-methylacetamido) anthraquinone 

*l-Bromo-<+- (me thy lamino) anthraquinone 

«6-Bromo-3-methyl-7H-dibenz[f,ij]isoquinoline-2,7-(3H)dione- 

3-(Bromcimethyl)thiophene 

1-Bromonaphthalene 

2-Bromo-4'-nitroacetophenone 

N-(4-Bromopentyl)phthalimlde 

o-Brcmophenol 

p-Bromophenol 

(p-Bromophenyl)acetonitrile 

p-Bromophenylhydrazine hydrochloride 



SDW. 

HK. 

BPC. 

MLS. 

MLS. 

DUP, 

DUP. 

AGS, 

ACS, 

DOW, 

NES. 

AAP. 

EK. 

ACY, 

TRC. 

DUP. 
OAF. 
ICI. 
ACY. 
TRC. 

GAP. 

DSC. 
TRC. 

SDH. 
ACS, 
DUP. 
DUP. 

DUP. 
DUP. 

TRC. 

LIL. 
ICO. 
PAS. 
ARA. 

X. 

ARA. 

EK. 

EK. 

EK, 

EK. 

PIC 

EK, 

ACY, 

DOW. 

EK. 

ICO. 

DOW. 

MEE. 

LIL. 

AAP, 

DOW. 

SDH. 

GAF. 

AAP, 

AAP, 

SDW. 

EK, 

GAF. 

SDW. 

EK. 

EK. 

BPC. 

EK. 



GAF, TRC. 



ACY, DUP, GAF, ICI, MAY. 

GAF. 

MON. 



DUP, GAF, MAY, TRC. 



DSC, DUP, SDH. 



PIC. 



OPC. 



ATL, DUP, GAF, ICI, MAY, TRC. 



SDC, TRC. 



DUP, GAF, ICI. 
GAF, ICI. 

RSA. 



70 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 1B.--Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



2-Broraopyridine 

a-Bromoresorcylic acid 

a -Bromotoluene 

o-Bromotoluene 

p-Bromotoluene 

2-Bromo-l,3,5-triethylbenzene 

p-Butoxyphenol 

i- [3-(p-Butoxyphenoxy)propyl]morpholine 

4' -Butoxy-3-piperidinopropiophenone 

N-Butylacetanilide 

l-(Butylamino)anthraquinone 

p-Butylaniline 

2-tert-Butylanthraquinone 

p-tert-Butylbenzaldehyde 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

p-tert-Butylbenzoic acid 

o-(p-tert-Butylbenzoyl)benzoic acid 

6-tert-Butyl-m-cresol 

2-tert-Butyl-p-cresol 

(n-Butylcyclopentadienyl)oyolopentadienyliron 

2 '-tert-Butyl-'i' ,6 '-dimethylacetophenone 

'4-Butyl-«-(dimethylamino)-o-oresol 

2-tert-Butyl-'4-ethylphenol 

2-tert-Butyl-5-methylanisole 

o-sec-Butylphenol 

p-sec-ButylphenoI 

o-tert-Butylphenol 

p-tert-Butylphenol 

Butylphenols , mixed 

<+ -Butyl -o-phenylenediamine hemisulfate 

p-tert-Butyl toluene 

5-tert-Butyl-l,2,3-trimethylbenzene 

5-tert-Butyl-m-xylene 

e-tert-Butyl-aji-xylenol 

Camphoric acid 

Camphoric anhydride 

d-10-Camphorsulfonic acid 

Camphosulfonic acid 

Carbazole, refined 

5 '-(o-Carboxybenzoyl)-2'-chlorooxanilic acid 

N- [(3-Carboxy-<i-chlorophenyl)-sulfonyl]anthranilic acid-- 

3-Carboxy-2(and 4)-hydroxybenzenediazonlum sulfate 

[ (o-Carboxyphenyl)thio]ethylmercury 

3-(2-Carboxy-A-Eulfophenyl)-3-ethyl-l-(5-nitro-o-anisyl)- 
triazine. 

a-Carboxy-o-toluic acid 

Cedrene 

2 '-Chloroacetoacetanilide 

2'-Chloroaoetophenone 

3'-Chloroacetophenone 

4 '-Chloroacetophenone 

2-Chloro-2 ',6 '-acetoxylidide 

4'-(Chloroacetyl)aoetanilide 

m-Chloroaniline 

o-Chloroaniline 

p-Chloroaniline 

2-(o-CM.oroanillno)ethanol 

3-(o-Chloroanilino)propionltrile 

5-Chloro-o-anisidine [NH2-I] (4-Chloro-o-anisidine 
[0CH3=1]). 

5-Chloro-o-anisidine hydrochloride 

4-Chloroanthranilic acid 

»1-Chloroanthraquinone 

*2 -Chloroanthraquinone 

N-(5-Chloro-l-anthraquinonyl)-p-toluenesulfonamide 

o-Chlorobenzaldehyde 

p-Chlorobenzaldehyde 

Chloro-7H-benz [de] anthracen-7-one (Chlorobenzanthrone ) — 

*Chloroben2ene, mono- 

p-Chlorobenzenesulfinic acid 



HEP. 

ALL. 

EK. 

EK. 

BPC, EK. 

DUP. 

ABB. 

ABB. 

ICO. 

UCC. 

AAP. 

DUP, UCC. 

DUP. 

GIV. 

PLC. 

PLC. 

CTA, PLC. 

SHC. 

DUP. 

KPT, PRD. 

ACY. 

ARA. 

GIV. 

RH. 

ACY. 

GIV. 

DOW, TNA. 

DOW. 

TNA. 

DOW, PRD, UCC. 

DOW. 

WAY. 

GIV, SHC. 

GIV. 

GIV. 

X. 

FIN. 

FIN. 

OTC. 

LIL. 

SDC. 

GAF. 

TRC. 

ACS, GAF. 

LIL. 

GAF. 

DUP. 

GIV. 

FMP, UCC. 

EK. 

EK. 

UL. 

SDW. 

DUP. 

DUP, GAF. 

DUP, MON. 

DUP, MON. 

EKT. 

DUP, ICC. 

BUG. 



BUG. 

DUP. 

ACY, 

ACS, 

ICI. 

HN. 

HN. 

ACY, 

ACS, 

TRC. 



DUP, GAF, ICI, MAY, TRC. 
ACY, GAF, TRC. 



sec, TRC. 

DOW, DVC, HK, HKD, MON, WTO, NEV, OMC, PPG. 



CYCLIC INTERMEDIATES 



71 



TABLE 7B. Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, ii'67--Continueci 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



p-Chlorobenzenesulfonamide 

p-Chlorobenzenesulfonic acid 

o-Chlorobenzoic acid 

5-Chloro-2-ben2oxazolinone 

*o-(p-Chlorobenzoyl)benzoic acid 

p-Chlorobenzoyl chloride 

A,'^ '-(o-Chlorobenzylidene)di-2,5-xylidine 

a-(p-Chlorobenzyl) -a-phenyl-l-pyrrolidinepropanol hydro- 
chloride. 

Chloro(p-chlorophenyl)phenylme thane 

Chlorocyclohexane 

l-Chloro-2,5-diethoxy-<i-nitrobenzene 

2-Chloro-N,N-diethyl-'i-nitroanlline 

2-Chloro-3','4'-dihydroxyacetophenone 

2-Chloro-l,4-dihydroxyanthraquinone 

<i'-Chloro-2 ' ,5 '-dimethoxyacetoacetanilide 

5-Chloro-2,'i-dimethoxyaniline 

5-Chloro-A,7-dimethylbenzo[b]thiophen-3(2H)-one 

A-Chloro-N, N-dimethyl-3-nitrobenzenesulfonamide 

2-Chloro-<V, 6-dinitroaniline 

»l-Chloro-2,'i-dinitrobenzene (Dinitroohlorobenzene) 

l-Chloro-2,'i-dinitrobenzene and 2-chloro-l,3-dinitrobenzene 
mixture. 

3-Chloro-4,6-dinitrobenzenesulfonic acid 

3-Chlorodiphenylamine ■ 

Chlorodiphenylme thane 

2-Chloroethanol, p-toluenesulfonate 

N-(2-Chloroethyl)-'i-(2-Chloro-'i-nitrophenylazo)-N-ethyl- 
aniline. 

4- [(2-Chloroethyl)ethylamlnol -o-tolualdehyde 

N-(2-Chloroethyl)-N-ethylanillne 

p-[ (2-Chloroethyl)methylamlno] benzaldehyde 

Chloroformic acid, benzyl ester 

Chloroformio acid, phenyl ester 

4-Chloro-5-hydroxy-2,7-naphthalene disulfonic acid 

5'-Chloro-3-hydroxy-2-naphth-o-anisidide 

3-Chloro-4.-hydroxyquinoline-3,<*-carbonic acid 

6-Chloroisatoic anhydride 

4-Chlorometanilic acid 

5-Chlorometanilic acid 

*6-Chlorometanilic acid 

5-Chloro-2-methoxybenzenedlazonium chloride 

N-[(5-Chloro-2-methoxyphenyl)azo] sarcosine 

p-(Chloromethyl)anisole 

*l-Chloro-2-methylanthraquinone 

6-Chloro-4-methyl-l,3,2-benzothlazathiolium chloride 

6-Chloro-<i-methylbenzo[b] thiophene-2-ol 

-i-CChloromethyl) -1,2 -dime thy Ibenzene 

'i-(Chloromethyl)-l,3-dimetl^lbenzene ^ 

l-(Chloromethyl)naphthalerie 

'i-Chloro-N-methyl-3-nltrobenzenesulfonajnlde 

'4-Chloro-3-(3-methyl-5-oxo-2-pyrazolin-l-yl)benzenesul- 
fonlc acid. 

2-Chloro-5-(N-methylsulfamoyl) sulfanilamide 

5 -Chloro-2 - ( N-me tJ^lsulf amy 1 ) -A -sulf amyl -N-benzy laniline - - - 

'»-Chloro-3-(methylsulfonyl)nitrobenzene 

Chloronaphthalenes 

•2-Chloro-A-nitroaniline (o-Chloro-p-nitroaniline) 

*4-Chloro-2-nltroaniline (p-Chloro-o-nitroaniline) 

»l-Chloro-5-nltroanthraquinone 

l-Chloro-8-nltroanthraquinone 

*l-Chloro-2 -nitrobenzene (Chloro-o-nitrobenzene) 

l-Chloro-3 -nitrobenzene (Chloro-m-nitrobenzene) 

*l-Chloro-'4-nitrobenzene (Chloro-p-nitrobenzene) 

2-Chloro-5-nitrobenzenesulfinic acid 

2-Chloro-5-nltrobenzenesulfonamide 

*^-Chloro-3-nitrobenzenesulfonamide 

A-Chloro-3-nitrobenzenesulfonanilide 

*2-Chloro-5-nitrobenzenesulfonio acid 

»2-Chloro-5-nltrobenzenesulfonic acid, sodium salt 

'*-Chloro-3-nitrobenzenesulfonic acid 

2-Chloro-5-nitrobenzenesulfonyl chloride 



ACY. 
GAF. 
HN. 

X. 

ACS, ACY, DUP, GAF, HN, ICI. 

HN. 

GAF. 

LIL. 

OPC. 

ACY. 

ALL, GAF. 

DUP. 

SDW. 

HSH. 

PCW. 

PCW. 

ACS. 

EKT, GAF. 

GAF. 

AAP, ACS, DUP, SDC. 

DUP. 

TRC. 

SK. 

OPC. 

GAF. 

GAF. 



GAF. 

GAF. 

ACS, 

PIC, 

EK. 

GAF. 

PCW. 

SDH. 

MEE. 

DUP. 

ACS. 

AAP, 

GAF. 

ATL. 

SDW. 

ACS, 

AAP. 

ACY. 

BPC. 

BPC. 

BPC. 

TRC. 

DUP. 

ABB. 
ABB. 
TRC. 
KPS. 
DOW, 
DOW, 
ACS, 
DUP. 
AAP, 
DUP, 
AAP, 
TRC. 
AAP. 
AAP, 
TRC. 
AAP, 
DUP, 
ACS, 
TRC. 



GAF. 
RSA. 



DUP, GAF, SW. 



ACY, CMG, DUP, GAF, Id, TRC. 



DUP, SDC. 
DUP, SDC, VPC. 
ACY, DUP, MAY, TRC. 

DUP, MON, UFM. 

GAF. 

DUP, MON, u™. 



CMG, DUP, EKT, GAF, ICC, TRC. 

ACS, CM}, TRC. 

GAF. 

TRC. 



72 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 7B. Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, i967--Continued 



Chemical 



Manufacturers ' Identification codes 
(according to list in table 22) 



*4-Chloro-3-nitrobenzenesulfonyl chloride 

2-Chloro-'i-nitrobenzoic acid 

2-Chloro-5-nitrobenzoio acid 

*o-('4-Chloro-3-nltrobenzoyl)benzolc acid 

'+-Chloro-2-nltrophenol 

'i-Chloro-3-nitrophenyl methyl sulfone 

2-Chloro-4-nitrotoluene 

2 -Chloro-6-nitro toluene 

4-Chloro-2-nitro toluene 

•i-Chloro-3-nitrotoluene 

a-Chloro-m-nitrotoluene 

m-Chlorophenol 

o-Chlorophenol 

p-Chlorophenol 

2-Chlorophenothiazine 

■4 -(p-Chlorophenoxy) aniline 

4-(p-Chlorophenoxy)nltrobenzene 

(p-Chlorophenyl)acetonltrlle 

■i-Chloro-ci-phenyl-o-cresol 

A-Chloro-o-phenylenediamine 

3-(o-Chlorophenyl) -5-methyl-A-isoxazolecarbonyl chloride 

3-(o-Chlorophenyl) -5-methyl-'4-isoxazolecarboxylio acid 

l-(m-Chlorophenyl)-3-methyl-2-pyrazolin-5-one 

l-(p-Chlorophenyl)-3-methyl-2-pyrazolin-5-one 

p-Chlorophenyl methyl sulfone 

2-Chloro-4-phenylphenol 

l-[i-(p-Chlorophenyl)-3-phenyl-2-butenyl] pyrrolidine hydro- 
broraide. 

[(o-Chlorophenyl)thio] acetic acid 

4-Chlorophthalic acid and sodium salt 

C3-Chloropropenyl)benzene (Clnnamyl chloride) 

l-C3-Chloropropyl)-'i-methylpiperazine 

Ni-(6-Chloro-3-pyridazinly) sulfanilamide 

2-Chloropyridine 

6-Chloroquinaldine 

V-Chloro-A-quinolinol 

2-(6-Chloro-2-quinonyl)-l,3-indandione 

4-Chlororesorcinol 

2-Chloro-5-sulfamoylbenzoic acid 

2-Chlorothiophene 

m-Chloro toluene 

o-Chloro toluene 

p-Chloro toluene 

*o-Chlorotoluene (Benzyl chloride) 

3-Chloro-o-toluidine [NH2=l] - 

3-Chloro-p-toluidine [NH2=l] 

A-Chloro-o-toluidine [NH2=l] and hydrochloride 

5-Ghloro-o-toluidine [NH2=l] (-i-Chloro-o-toluidine [CH3=l] ) 

5-Chloro-o-toluldine hydrochloride [NH2=l] 

N- [(5-Chloro-o-tolyl)azo]sarcosine 

l-(6-Chloro-o-tolyl)-3-methyl-2-pyrazolin-5-one 

l-(5-Chloro-o-tolyl)-l-tetrazene 

*[('i-Chloro-o-tolyl)thio] acetic acid 

"i-Chloro-a, a, a-trifluoro-3-nltrotoluene 

5-Chloro-a,a,a-trifluoro-2-nitro toluene 

p-Chloro-^.^j^-trifluorotoluene 

■4-Chloro-*,*,"-trifluoro-o-toluldine 

6-Chloro-*,*,ci-trifluoro-m-toluidlne 

Chlorotriphenylme thane 

c-Chloro-p-xylene 

2-Chloro-p-xylene 

■4-Chloro-2,5-xylenesulfonyl chloride 

4-Chloro-3,5-xylenol 

[ ('i-Chloro-2,5-xylyl)thio]acetic acid 

Cholic acid 

»Clnnamoyl chloride 

»Cresols:^ 

m-Cresol 

*o-Cresol : 

From coal tar 

From petroleum 

p-Cresol 

See footnotes at end of table. 



AAP, 


DUP, 


EKT. 


SAX. 






TRC. 






AAP, 


ACS, 


GAF, ICI. 


DUP, 


MEE. 




TRC. 






DUP. 






DUP. 






DUP. 






AAP, 


DUP. 




EK. 






EK. 






DOW, 


MON. 




DOW, 


MON. 




SK. 






NES. 






NES. 






ICO, 


OPC. 




MON. 






FMT. 






ICO, 


OTC. 




ICO. 






TRC. 






DUP. 






TRC. 






DOW. 






LIL. 






PCW. 






DUP, 


HK, 


UEE, SW. 


SDW. 






SK. 






ACY. 






FMT. 






DUP. 






SDW. 






DUP. 






AAP, 


OAF. 




TRC. 






FIS. 






HK. 






HN. 






HN. 






BPC, 


GRH, 


HK, HN, MON, 


DUP. 






BUG, 


DUP. 




ACY, 


BUC, 


PCW. 


DUP, 


SDH. 




ATL, 


SDH. 




ALL, 


ATL. 




TRC. 






GAF. 






ACS, 


ACY, 


GAF, PCW. 


AAP, 


OAF, 


MEE. 


USE. 






HK. 






MEE. 






AAP. 






EK. 






BPC. 






DUP. 






ACS. 






OTA. 






ACS. 






WIL. 






ICO, 


UOP, 


X. 


KPT, 


PRD. 




KPT, 


PRD. 




KPT, 


MER, 


NPC, PRD, SW. 


ACY, 


HPC, 


SW. 



CYCLIC INTERMEDIATES 



73 



TABLE 7B.- 



-Cyclic intermediates for which U.S. production or sales were reported, identified by 
manufacturer , 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



Cresols, mixed :^ 
»(m,p)-Cresol: 

From coal tar 

From petroleum 

(o,m,p)-Cresol 

»Cresylic acid, refined:^ 

From coal tar 

From petroleum 

*Cumene 

2-[p-(Cyanoacetamido)phenyl] -6-methyl-7-benzothiazolesul- 
fonic acid. 

j.-Cyano-d'^,a-cyclohexaneacetic acid, ethyl ester 

a-Cyano-1-cyclohexene-l-acetic acid, ethyl ester 

N-p-Cyanoethyl-N-CfJ -ace toxyethyl) aniline 

4- [(2-Cyanoethyl)ethylamlno]-o-tolualdehyde 

p- [(2-Cyanoethyl)methylamino]benzaldehyde 

Cycloaliphatic epoxides 

^*-Cyclohexane 

1,2-Cyolohexanedioarboxylic anhydride 

1,3-Cyclohexanedione 

»Cyclohexanol 

*Cyclohexanone 

Cyclohexanone oxime 

Cyclohexene 

i-Cyclohexene-l-carboxaldehyde 

4-C)yclohexene-l,2-dioarboximide 

i-Cyolohexene-l,2-dioarboxylic anhydride 

»Cyclohexylamine 

Cyclohexyl-2-propanone 

N-Cyclohexyltaurine, sodium salt 

Cyolopentamine base 

Cyclopentanepropionic acid 

Cyclopentanol 

Cyclopentanonecarboxylic acid 

Cyolopentene 

Cyclopropaneoarboxylio acid 

p-Cymene 

Decachlorodicyclopentadiene 

Deoxycholic acid 

1,5 (and l,8)-Diacetamidoanthraquinone 

3,5-Diacetamido-2,'i,5-triiodobenzoio acid 

3'-[Di(2-aoetoxyethyl)amino] -p-aoetophenetidide 

3-(Diallylcarbamoyl)-l,2,2-trimethylcyolopentanecarboxylic 

acid. 
N^jN^-Diallylmelamine 

*l,^-Diaminoanthraquinone 

1,5-Diaminoanthraquinone 

l,5(and l,8)-Diaminoanthraquinone 

«2,6-Diaminoanthraquinone 

3,4--Diaminobenzanilide 

3',4-DiajTdnobenzanilide 

2,^-Diaminobenzenesulfonic acid [S03H=l] 

2,5-Diamlnobenzenesulfonic acid [SOsH = l ] 

'*,'*'-Diamino-2,2'-biphenyldisulfonic acid 

l,5-Diamino-2,6-dibromo-'i,8-di-p-toluidinoanthraquinone 

l,'4-Diamino-2,3-dichloroanthraquinone 

*l,^-Diamino-2,3-dihydroanthraquinone 

4,8-Diamino-9,10-dihydro-l,5-dihydroxy-9,10-dioxo-2,6- 

anthracenedisulfonic acid. 
l,4-Diamino-9,10-dihydro-9,10-dioxo-2,3-anthracenedicar- 
bonitrile. 

l,4-Diamino-9,10-dihydro-9,10-dioxo-2,3-anthracenedicar- 
boximide. 

l,5-Diamino-<4,8-dihydroxyanthraquinone 

l,5(and l,8)-Diamino-4,8(and 4,5)-dihydroxyanthraquinone— 

'>,5-Diamino-l,8-dihydroxyanthraquinone 

'i,<i'-Diamino-5,5'-dimethyl-2,2'-blphenyldisulfonic acid 

l,4-Diamino-5-nitroanthraquinone 

2,4-Diamino-6-phenyl-s-triazine 

2,6-Diaminopyridine 

See footnotes at end of table. 



ACP, KPT, PRD. 
MER, NPC, PIT, PRD. 
ACP, KPT, NPC. 

ACP, KPT. 

MER, NPC, PIT, SHO. 

CLK, CSP, DOW, GOC, HPC, MOC, MON, SHC, SKO, SNT, 

SOC, TX. 
DUP. 

SDW. 

SDW. 

EKT. 

DUP, GAF. 

DUP, GAF. 

UCC. 

ASH, ATR, CO, COR, CSD, DUP, EKX, ENJ, GOC, GRS, PLC, 

SOG, TX, UOC. 
ACS. 
PD. 
ACS, 
ACS, 
ACS, 
PLC. 
UCC. 
CHO. 
ACS, 
ABB, 
GIV. 
GAF. 
LIL. 
ARA. 
LIL. 
ARA. 
ARA, 
HEX. 
ACS, 
NES. 
WIL. 
AAP. 
SDW. 
TRC. 
WYT. 



DBC, DUP, MON. 
CEL, DBC, DUP, MON. 



PTT. 

MON, VGC, x. 



PLC. 
HNW, HPC. 



ACY. 
CMG, 
DUP, 
AAP, 
AAP, 
TRC. 
VPC. 
DUP, 
TRC. 
AAP, 
ICI. 
CMG, 
ACY, 
TRC. 

DUP. 

DUP. 



DUP, ICC, VPC. 

DUP. 

ICI. 

AAP. 

GAF. 

RH, VEL. 

NEP, RIL. 



DUP, GAF, TRC. 

GAF, TRC. 

ICI, TRC. 

ACS, ACY, GAF, ICI, TRC, VPC. 



TRC. 

ACS, ACY. 

DUP. 

DUP, GAF, HSH, ICC, ICI, MAY, TRC. 



74 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 7B. Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer , 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



6,7-Diamino-2,3-quinoxalinediol hydrochloride 

»4j4'-Diamlno-2,2 '-stilbenedisulfonic acid 

l,5-Diainino-2,i,6,8-tetrabromoanthraquinone 

4,6-Diainino-m-toluenesulfonic acid [S03H=l) 

3,5-Diamino-p-toluenesulfonic acid [S03H=l] 

3,5-Diainino-2,'i,6-triiodobenzoic acid 

l,'i:3,5-Dlanhydroglucitol 

l,5-Dianilino-9,10-dihydro-9,10-dioxo-2,6-anthracenedicar- 
boxylic acid. 

2,'i-Dianilino-l-hydroxyanthraquinone 

6,8-Dianilino-l-naphthalenesulfonic acid 

Diary Iguanidine 

p-Dlazo-N,N-dimethylaniline-l-ajnino-8-naphthol -3 -sulfonate - 

6-sulfonio acid, sodium salt. 
5(and 3)-Diazo-6-oxo-l,3(and l,'V)-cyclohexadiene-l-car- 
boxylic acid. 

1,5-Dibenzamidoanthraquinone 

6,ll-Dibenzamido-16H-dinaphtho[2,3-a,2 ',3 ' -i] -oarbazole- 
5, 10, 15, 17-tetrone . 

*4,5'-Dibenzamido-l,l'-iminodianthraquinone 

Dibenzo[b,def ]chrysene-7,14-dione 

Dibenzothiophene 

*l,5-Dibenzoylnaphthalene 

N,N'-Dibenzylethylenediamine 

N,N'-Dibenzylethylenediamine diacetate 

N,N '-Dibenzylidene toluene-;/., j, -diamine 

N,N-Dibenzylsulfanilic acid 

2,4' -Dibromoacetophenone 

*3,9-Dibromo-7H-benz[de) anthracen-7-one 

ar-Dibromobenzene 

p-Dibromobenzene 

ar-Dibromodibenzo [b,def ] chrysene-7,l'i-dione 

2,6-Dibromo-l,5-naphthalenediol 

2,6-Dibromo-4-nitroaniline 

2,6-Dibromo-'i-nitrophenol 

5,13-Dibra]io-8,16-pyranthrenedione 

Dibromoviolanthrone 

2,5-Dibutoxyaniline 

p-Dibutoxybenzene 

l,4-Dibutoxy-2-chloro-5-nitrobenzene 

2,5-Dibutoxy-4-morpholinobenzene sulfate diazoniumsulfate 
salt. 

4-(2,5-Dibutoxy-'4-nltrophenyl)morpholine 

l,l'-Di-n-butyldicyclopentadienyliron 

2,<i-Di-tert-butylphenol 

Dibutyltin bis(oyclohexyl maleate) 

3,4-Dichloroaniline 

2,5-Dichloroauiline and hydrochloride [NH2=1] 

3-(2,'4-Dichloroanilino)-l-(2,'i,6-trichlorophenol) 

*l,5-Diehloroanthraquinone 

1,8-Dichloroanthraquinone 

2,6-Diohlorobenzaldehyde 

3-(3,4-Dlchlorobenzamido)-l-phenyl-2-pyrazolin-5-one 

Dichlorobenzanthrone 

m-Dichlorobenzene 

»o-Dichlorobenzene 

o(and p)-Diohlorobenzene 

*p-Dichlorobenzene 

4,6-Diohloro-m-benzenedisulfonamide 

^jS-Dichloro-m-benzenedisulfonyl chloride 

*3,3'-Dichlorobenzidine base and salts 

Dichlorobenzil 

2,4-Dichlorobenzoic acid 

2,6-Dichlorobenzonitrile 

2,4-Dichlorobenzoyl chloride 

Dichlorobenzyl alcohol 

Diohlorobenzyl chloride 

2,'i-Dichloro-m-cresol 

7,16-Dichloro-6,15-dihydro-5,9,l'i,l8-anthrazinetetrone 

4,5-Diohloro-3,6-dioxo-l,4-cyolohexadiene-l,2-dicarboni- 

trile. 
Dichlorodiphenylsilane 



BJL. 

ACS, ACY, DUP, GAF, GGY, SDH, TRC, VPC. 

ICI. 

ACS. 

GAF. 

SDW. 

APD. 

ACS. 

GAF. 
ACS. 
DUP. 
IDC. 

DUP. 

GAF, TRC. 
ICI. 

ACS, ACY, DUP, GAF, ICI, MAY, TRC. 

ATL, ICI, TRC. 

EVN. 

ACY, CMG, DUP, GAF, PCW, TRC, VPC. 

WYT. 

WYT. 

SDH. 

ICI. 

EK. 

DUP, GAF, MAY, TRC. 

DOW. 

DOW. 

ICI. 

EK. 

SDC. 

MEE. 

DUP, ICI. 

GAF. 

BJL. 

ALL. 

ALL, BJL. 

ALL. 

ALL. 
AHA. 
DOW. 

X. 

DUP, MON. 

ACS, BUC, DUP. 

EK. 

ACS, DUP, GAF, ICI, TRC. 

GAF, ICI, TRC. 

DUP. 

EK. 

ACY. 

EK, CMC. 

ACS, CPD, DOW, DUP, DVC, MON, NEV, PPG, SCC, SVT. 

HKD, MTO. 

ACS, CPD, DOW, DVC, MON, NEV, PPG, SCC, SVT. 

ABB. 

ABB. 

ACS, ALL, CWN, LAK. 

MTO. 

HN. 



HN. 

UCC. 

UCC. 

EKT. 

ICI. 

ARA. 

DCC. 



CYCLIC INTERMEDIATES 



75 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer , 7567--Continued 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



2 ',7 '-Dichlorofluorescein 

1,2-Dichlorohexafltiorocyclopentene 

2,5-Dichloro-^-hydrazinobenzenesulfonic acid 

N-(6,8-Diohloro-5-hydroxy-l-naphthyl)-p-toluenesulfonamide- 
SjlA-Dichloroisoviolanthrone 

*2,5-Dichloro-4-(3-methyl-5-oxo-2-pyrazolin-l-yl)benzene- 
sulfonic acid. 

Diohloromethylphenylsilane 

2,'4-Dichloro-l-naphthol 

2,6-Dichloro-4-nitroaniline 

l,2-Dichloro-4-nitrobenzene 

*l,i-Dichloro-2 -ni trobenzene ( Nitro-p-dichlorobenzene ) 

2,4-Dichlorophenol 

2,'i-Dichlorophenol, benzene sulfonate 

3 -( 2 ' , 6 '-Diohlorophenyl ) -5 -methyl-"4-isoxazolecarbonyl 

chloride. 
3 -( 2 ', 6' -Diohlorophenyl ) -5 -me thyl-'i -isoxazolecarboxylic 

acid. 

l-( 2, 5 -Diohlorophenyl) -3 -triazenecarbonitrile 

2,6-DichloropyTazine 

3,6-Dichloropyridazine 

4,7-DichloroquinQline 

2,3-Dichloro-6-quinoxalineoarbonyl chloride 

3,5-Dichlorosalicylic acid 

»2,5-Dichlorosulfanilio acid [S03H=1 ] 

2,5-Diohloro-/4-sulfobenzenediazonium sulfate 

p,a-Dichloro toluene 

a,a-Dichlorotoluene (Benzal chloride) 

2, 6-Dichloro toluene 

Dichloroxylene 

2,4--Dichloro-3,5-xylenol 

Dicyolohexylamine 

»Dicyclopentadiene (includes cyclopentadiene) 

Dicyclopentadiene dioxide 

Didodeoylbenzene 

2,5-Diethoxyaniline 

2',5'-Diethoxybenzanilide 

p-Diethoxybenzene 

3,4-Diethoxybenzoic acid 

2,5-Diethoxy-4-morphollnobenzenediazoniuin chloride, zinc 

chloride. 

2 ',5 '-Diethoxy-4'-nitrobenzanilide 

l,i-Diethoxy-2 -nitrobenzene 

4-(2,5-Diethoxy-4-nitrophenyl)morpholine 

*p-(Diethylamino)benzaldehyde 

3 ' - [2 - ( Diethylamino ) ethyl] -A ' -hydroxyacetanilide 

a-[2-(Diethylainino)ethyl] -a-phenylcyclohexanemethanol 

hydrochloride. 

m-(Diethylamino)phenql (N,N-Diethyl-3-aminophenol) 

3- [(<i-N,N-Diethylamino)phenylazo] -lH-l,2,'i-triazole 

3-(Dlethylaniino)propiophenone 

4-(Diethylamino)-o-tolualdehyde 

»N,N-Diethylanillne 

N,N-Diethyl-m-anlsldine 

Diethylbenzene 

Ijl'-Diethyl-'ij^'-carbocyanine iodide ( Cryptocyanine ) 

N,N-Diethylcyolohexylamlne 

a,a'-Diethyl-4,4'-dliiiethoxystllbene 

N^,N^-Diethyl-4-methoxymetanllaniide 

N,N-Diethyl-p-nitrosoaniline 

NjN-Diethyl-A-nitroso-m-anlsidine hydrochloride 

N,N-Diethyl-<i-nitroso-m-phenetidine 

N,N-Diethyl-m-toluidine 

2,'i-Difluoroaniline 

6,15-Dihydro-5,9,14,18-anthrazinetetrone 

10,ll-Dihydro-5H-dibenzo[a,d]cyclohepten-5-one 

9,10-Dihydro-l,8-dihydroxy-4,5-dinitro-9,10-dioxo- 

2,6-anthraoenedisulfonic acid. 
9,10-Dihydro-l,'i-dihydroxy-9,10-dloxo-2-anthraoenesulfonic 

acid (2-Quinizarinsulfonic acid). 
N-(5,13-Dihydro-5,13-dioxoaceanthryleno[2,l-a]- 

aoeanthrylen-7-yl)-9,10-dihydro-l-nitro-9,10-dioxo-2- 

anthramide. 



EK. 

PIC. 

GAF. 

EK. 

ICI. 

ACY, CMG, DUP, GAP, PCW, TRC, VPC. 

DCC. 

AAP. 

AAP, CWN, DUP, HSH, PCW. 

DUP, MON, SDC. 

ACS, ALL, DUP, PCW, SDC, VPC. 

DOW, MON. 

NES. 

ICO, KF, OTC. 

ICO. 

GAF. 

ACY. 

ACY. 

PD, SDW. 

DUP. 

ICO. 

CMG, DUP, VPC. 

TRC. 

HN. 

ACS, HK. 

DUP. 

BPC. 

OTA. 

ABB, MON, VGC. 

ENJ, GOC, UCC, VEL. 

VEL. 

CO. 

ALL. 

ALL. 

ALL, GAF. 

SDW. 

ALL. 



ALL. 

ALL. 

ALL. 

ACS, DUP, GAF. 

PD. 

ACY. 



ACY, 

TRC. 

ACY. 

DUP. 

ACS, 

DUP. 

DOW, 

EK. 

DUP. 

LIL. 

PCW. 

ESA, 

DUP. 

GAF. 

DUP. 

PIC. 

TRC. 

LIL. 

DUP. 



AAP, HSH, PAT. 
ACS, ICI. 



DUP. 

ACY, DSC, DUP, SDH. 
KPP. 

GAF. 



76 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, iS67- -Continued 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



9,10-Dihydro-9,10-dioxo-l,5-anthracenedisulfonic acid 

9,10-Dihjfdro-9,10-dioxo-l,5-anthracenedisulfonic acid, 

disodium salt. 
9,10-Dihydro-9,10-dioxo-l, 5(and l,8)-anthraoenedlsulfonic 
acid and salt, 
»9,10-Dihydro-9,10-dioxo-l,8-anthraoenedisulfonic acid, 

potassium salt. 
»9, 10-Dihydro-9,10-dioxo-2,5-anthracenedisulfonic acid and 

salt. 
»9,10-Dihydro-9,10-dioxo-l-anthracenesulfonic acid and salt 
(Gold salt). 
9, 10-Dihydro-9,10-dioxo-2-anthracenesulfonio acid and salt 
(Silver salt). 

9,10-Dihydro-9,10-dioxo-2-anthroic acid 

3,'i-Dihydro-3,i-dioxo-l-naphthalenesulfonic acid, sodium 
salt. 

[Dihydrogen 3,3 ' '-phthalocyaninedisulfonato-( 2-)] copper 

10,ll-Dihydro-5-[3-(raethylaminopropyl)] -5H-dlbenzo[a,d] - 
eye lohep ten-5 -ol . 
*9,10-Dihydro-5-nitro-9, 10-dioxo-l-anthracenesulfonic acid — 
9,10-Dihydro-5(and 8)-nitro-9,10-dioxo-l-anthracenesulfonic 
acid. 

9,10-Dihydro-l-nitro-9,10-dioxo-2-anthroio acid 

»l,i-Dihydroxyanthraquinone (Quinizarin) 

»1,5-Dihydroxyanthraquinone (Anthrarufin) 

1,5 (and l,8)-Dihydroxyanthraquinone 

1,8-Dihydroxyanthraquinone (Chrysazin) 

*2, 6-Dihydroxyanthraquinone (Anthraflavlc acid) 

4-,5-Dihydroxy-in-benzenedisulfonic acid, disodium salt 

2,5-Dihydroxybenzenesulfonio acid, potassium salt 

2,'i-Dihydroxybenzophenone 

*l,5-Dihydroxy-<i,8-dinitroanthraquinone 

*l,8-Dihydroxy-'4, 5-dini troanthraquinone (4,5-Dinitro- 
ohrysazin ). 
l,5-Dihydroxy-'4,8-dinitro-2,6-anthraquinonedisulfonic acid- 
17o,21-Dihydroxy-9(i,llfJ-epoxy-16(i-methylpregna-l,'4-diene- 
3,20-dione. 

10,10 '-(Dihydroxyethanediylidene)dianthrone 

3,i-Dihydroxyhydrocinnamic acid (Hydrocaffeic acid) 

4.,5-Dil^rdroxy-2,7-naphthalenedisulfonic acid ( Chromo tropic 
acid) . 

6,7-Dihydroxy-2-naphthalenesulfonic acid 

llB,21-Dlhydroxypregna-4,17(20)-cis-dien-3-one 

llp,21-Dihydroxypregna-l,'i,17(20)-cis-trien-3-one 

4,5 -Dihydroxy-3 -( p -sulf ophenylazo ) -2 , 7-naphthalenedisul- 
fonic acid, trisodium salt. 

*16,17-Dihydroxyviolanthrone (Dihydroxydibenzanthrone) 

m-Diiodobenzene 

3,5-Diiodo-'i-oxo-l('iH)pyridineacetio acid 

3, 5-Diiodo-L- tyrosine 

Diisopropylbenzene 

N,N'-Dlisopropyl-p-phenylenediamine 

2,5-Dimethoxyaniline 

1,5 (and 1,8) -Dime thoxyanthraquinone 

2,5-Dimethoxybenzaldehyde 

m-Dimethoxybenzene 

*3,3'-Dimethoxybenzidine (o-Dianisldine) 

3,3' -Dimethoxybenzidine hydrochloride 

2,'i-Dimethoxybenzoic acid 

3,5-Dlmethoxybenzoic acid 

N,N'-[(3,3'-Dimethoxy-<i,4'-biphenylylene)bis-(azo)] bis- 
(N-methyltaurine) . 

2,5-Dimethoxy-3-methyl-P-nitrostyrene 

2,5-Dimethoxy.,;,._methylphenethylajnine hydrobromide 

N-(3,4-Dimethoxy-a-methylphenethyl)-2-('i-ethoxy-3-methoxy- 
phenyl ) acetamide . 

2,5-Dimethoxy-4'-nitrostilbene 

3,4-Dimethoxyphenethylamine ( Homoveratrylamine ) 

N-(3,'4-Dimethoxyphenethyl)-2-(3,'4-dimethoxyphenyl)acetamide 

(Sji-DimethoxyphenyDacetonitrlle 

l-(3',4'-Dijnethoxyphenyl)-2-amlnopropane 



ACY, 
GAF, 


TRC. 
ICI, 


TRC. 










TRG. 














GAF, 


ICI, 


TRC. 










AAP, 


ACS, 


ACY, 


GAF, ICI, 


TRC, 


VPC. 




AAP, 


ACS, 


ACY, 


DUP, GAF, 


ICI, 


MAY, 


TRC 


DUP. 














ACS. 
EK. 














ICI. 
LIL. 














ACS, 
ICI. 


DUP, 


MAY, 


TRC. 









DUP, GAF, TRC. 

AAP, ACS, ACY, CMG, DUP, EKT, GAF, HSH, ICC, ICI, 

JTC, MAY, TRC. 

ACS, ACY, DUP, GAF, TRC. 
CMG, TRC. 

GAF, ICI, TRC. 

ACS, DUP, GAF, TRC. 
SDC, SDW. 
NES. 

DUP, DVC, GAF. 

ICC, ICI, TRC, VPC. 

DUP, EKT, GAF, ICC, TRC. 

DUP. 
SCH. 

ICI. 
BJL. 
ACS, HSH. 

GAF, IDC. 
UPJ. 
UPJ. 
EK. 

ACS, ACY, DUP, GAF, ICI, MAY. 

EK. 

SDW. 

EK. 

DOW. 

DUP, USR. 

ALL, DUP, EKT. 

TRC. 

CWN. 

ACY, ICO. 

ALL, CWN, DUP, LAK, SDH. 

ALL, CWN. 

ACY. 

AID, ICO. 

ALL, GAF. 



X, 

LIL. 



LIL. 
UL. 
LIL. 
LIL. 



CYCLIC INTERMEDIATES 



n 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, 196 7 --Continued 



Chemical 



Manufacturers ' identification cedes 
(according to list in table 22) 



2,5-Diinethoxy-tetrahydrofuran 

16, 17 -Dimethoxyviolan throne 

p-Dimethylaminobenzanilide 

m-(Dimethylaraino)benzoic acid 

a-(Dimethylamino)-p-cresol 

6-Diniethylaniino-2-[2-(2,5-dimethyl-l-phenyl-3-pyrryl)- 
vinyl] -1-methyl-l-quinolinium methyl sulfate. 

2-[(2-Dijnethylainino)ethyl]arainopyridine 

2 - [ [ 2 - ( Dime thylamino ) ethyl ] -2 - thenylamino] pyridine 
(nonmedicinal grade). 

2-[[ 2 -(Dime thylamino) ethyl] -3 -thenylamino] pyridine 

m-(Dimethylamino)phenol 

N-(p-Dimethylaminophenyl)-l,<4-naphthoquinoneimine 

»N,N-Diraethylaniline — 

7, 12 -Dimethylbenz [a] anthracene 

3,3 -Dimethylbenzidine (o-Tolidine) 

3,3 '-Dime thy Ibenzidine hydrochloride 

*N, N-Dimethylbenzylamine 

a,a-DIjnethylbenzylhydroperoxide 

'4-(a,a-Dimethylbenzyl)-2-phenylazophenol 

2,2'-Dimethyl-l,l'-bianthraquinone 

5,5-Dimethyl-l,3-cyolohexanedione 

N,N-Dimethylcyclohexylamine 

2',7'-Dlmethylfluoran-- 

5,5-Dimethylhydantoin 

2,3-Dimethylindole 

2, 5 -Dimethyl -4(2 )-morpholinylmethylphenol hydrochloride 

N, N-Dimethyl-p-nitrosoaniline 

N,N-Dimethyl-3-nitro-p-toluenesulfonamide 

6,6-Dimethyl-2-norpinene-2-ethanol 

N,N-Dimethyl-p-phenylenediamine 

N,N-Dimethyl-p-phenylenediamine hydrochloride 

1,'t-Dimethylpiperazine 

N-[[4-( Dime thy lsulfamoyl)-o-tolyl]azo] -N-methyl-5- 
sulfoanthranilic acid. 

N,N-Dimethylsulfanilic acid 

N,N-Dimethyl-p-toluidine 

*2,'4-Dinitroaniline 

p-(2,'4-Dinitroanilino)phenol 

l,5(and l,8)-Dinitroanthraquinone 

N,N '-(2,'i-Dinitro-l,5-anthraquinonylene)dioxamic acid 

3 ',4-Dinitrobenzanilide 

m-Dinitrobenzene 

2,4-Dinitrobenzenesulfonic acid 

3,5-Dinitrobenzoic acid 

3,5-Dinitrobenzoyl chloride 

10,10'-Dinitro[3,3'-bi-7H-benz[de] anthracene] -7,7 '-dione— 

3,3 '-Dinitro-4, 4' -biacetanilide 

Dinitrooaprylphenol 

3 ',5 '-Dinitro-2 '-hydroxyacetanilide 

l-(3,5-Dinitro-2-l^<lroxyphenylazo)-2-naphthol 

*2,'*-Dinitrophenol, tech 

(2,i-Dinitrophenyl)hydrazine 

3,5-Dinitrosalicylic acid 

»4,4'-Dinitrostilbene-2,2'-disulfonic acid 

2,'i-Dinitrotoluene 

2,4(and 2,6)-Dinitrotoluene 

3,5-Dinitro-p-toluenesulfonic acid 

2,4-Di-tert-pentylphenol 

2,4-Di-tert-pentylphenoxyacetyl chloride 

1,5-Diphenoxyanthraquinone 

1,5 (and l,8)-Diphenoxyanthraquinone 

1,8-Diphenoxyanthraquinone 

Diphenylacetic acid 

*Diphenylamine 

2,8-Diphenylanthra[l,2-d:6,5-d' ]bisthiazole-6, 12 -dione 

Diphenylcarbamyl chloride 

a-d-l,2-Diphenyl-4-dimethylamino-2-hydroxy-3-methylbutane, 
camphor sulfonate. 

1,1-Diphenylethylene 

N,N'-Diphenylethylenediamine 

2,5-Diphenyloxazole 



HEX. 








GAF, 


ICI, MAY. 






GAF. 








SDH. 








TKL. 








X. 








SDW. 








ABB. 








SDW. 








ACY. 








ACS. 








ACS, 


ACY, DSC, 


DUP, 


SDH. 


EK. 








ALL, 


CWN, DUP. 






CWN, 


DUP, EK. 






ICO, 


MLS, RH. 






ACP, 


CLK. 






TRC. 








AAP, 


ACS, ACY, 


CMC, 


DUP, GAF, ICI, TRC 


EKT. 








DUP, 


EKT. 






WIM. 








GLY. 








DUP. 








IDC. 








ACY, 


ESA. 






GAF. 








RDA. 








EKT. 








EK. 








JCC, 


SEL. 






GAF. 








GAF. 








EK, 


RSA, SEL. 






AAP, 


ACY, SDC. 






DUP, 


GAF. 






AAP, 


ICC, ICI, 


TRC. 




TRC. 








AAP, 


TRC. 






ACS, 


DUP. 






EK, 


TRC. 






FIS, 


SAL. 






EK. 








DUP, 


MAY. 






AAP. 








RH. 








TRC. 








TRC. 








AAP, 


ACS, SDC. 






EK. 








EK. 








ACS, 


ACY, DUP, 


GAF, 


GGY, SDH, TRC. 


ACS, 


DUP, RUC. 






DUP, 


MOB. 






GAF. 








PAS. 








X. 








GAF, 


VPC. 






DUP, 


ICC. 






EKT. 








ARA. 








ACY, 


DOW, DUP, 


FST, 


ORO, RUC. 


ICI. 








EK. 








HL. 








EK. 








DOW, 


RFC. 






ARA. 









78 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



l,3-Diphenyl-l,3-propanedione 

Diphenyl -2 -propanone 

2,2'-Dlthiodlbenzolc acid 

■*l,4--Di-p-toluidinoanthraquinone 

1,8-Di-p-toluidinoanthraquinone 

l,4-Di(p-toluidlno)-5,8-dihydroxyanthraquinone 

*Divinylbenzene 

Dodecylbenzene. (See Alkylbenzenes . ) 

Dodecylbenzyl chloride 

Dcdecylmethylbenzyl chloride 

*p-Dodecylphenol 

Eos in (2 ',i',5 ',7' -Tetrabromofluorescein) 

l,2-Epoxy-3-(2-biphenylyl)propane 

(Epoxyethyl)benzene 

o-Ethoxybenzoic acid 

6-Ethoxy-2-benzothiazolethiol 

<i-Ethoxy-3-methoxybenzyl alcohol 

l-('i-Ethoxy-3-methoxybenzyl)-6,7-dimethoxy-3-methyliso- 
quinone . 

('4-Ethoxy-3-methoxyphenyl) acetic acid 

2-Ethoxy-l-naphtholc acid 

2 -Ethoxy-1 -naphthoyl chloride 

'i-Ethoxy-3-nitroacetanilide 

(p-Ethoxyphenol)urea (Dulcin) 

3-(Ethylamlno)-p-cresol 

3-(EthylaiDino)-p-toluenesulfonic acid [S03H=1] 

*N- Ethyl aniline, refined 

2-(N-Ethylanillno)ethanol 

[2-(N-Bthylanilino)ethyl] trimethylanmonium chloride 

3-(N-Ethylaiiilino)propionitrile 

a-(N-Ethylanilino)-ni-tolueneEulfonic acid 

*«-(N-Ethylanillno)-p-toluenesulfonic acid 

N-Ethyl-p-anisldine 

N-Ethylanthranilic acid 

2 -Ethylanthraquinone 

»Ethylbenzene 

o-(p-Ethylbenzoyl)benzoic acid 

Ethylbenzyl chloride 

9-Ethylcarbazole 

N-Ethyl-1-cyclohexen-l-ylamlne 

N-Ethylcyclohexylamine 

3,3'-Ethylenedioxydiphenol 

Ethyl eniiDlne 

3-Ethyl-2-[3-(3-ethyl-2-benzothiazolinylidene)- 

pentadienyl] benzothlazolium iodide. 
2- [N-Ethyl-p-[(6-methoxy-2-benzothiazolyl)azo]anilino] - 
ethanol . 

N-Ethyl-N-(2-methylsulfonaiiiidoethyl)-m-toluidine 

N-Ethyl-1-naphthylamine 

a-Ethyl-3-nitroclnnamio acid 

p-Ethylphenol 

*N-Ethyl-N-phenylbenzylajiiine 

Ethylphenylmalonic acid, diethyl ester 

l-(o-Ethylphenyl)-3-methyl-2-pyrazolin-5-one 

5-Ethyl-2-picoline (2-Methyl-5-ethylpyridine) (MEP) 

1-Ethylplperidlne 

2-Ethylpyridine 

6-Ethyl-l,2,3,'»-tetrahydro-l,l,4,4-tetrainethylnaphthalene- 

N-Ethyl-m-toluidine 

N-Ethyl-o-toluidine 

3 -(N-Ethyl-m-toluldino) -1,2 -propanediol 

»3-(N-Ethyl-m-toluidino)propionitrile 

1-Ethynyl-l-cyclohexanol 

Fluoren-9-one 

Fluorescein (3',6'-Dihydroxyfluoran) 

l-Fluoro-2,'1— dinitrobenzene 

^-Fonnyl-m-benzenedisulfonio acid 

o-Formylbenzenesulfonlc acid (o-Sulfobenzaldehyde) 

Furan 

Furfuryl alcohol 

Furfurylamine 



AID, 


EK. 








BPC. 










LIL, 


MEE. 








ACS, 


ATL, 


GAF, 


ICI, TRC, VPC. 




ICI. 










ICI. 










DOW, 


FG, 


KPP. 






CO. 










X. 










GAF, 


MON, 


UCC, 


X. 




ICC. 










NES. 










UCC. 










ACY. 










FMT. 










LIL. 










LIJ,. 










LIL. 










ICO. 










ICO, 


WYT. 








AAP. 










RSA. 










DUP. 










DUP. 










ACS, 


ACY, 


DUP, 


SDH. 




DUP, 


EKT. 








DUP. 










EKT. 










GAF, 


SDH. 








ACS, 


TRC, 


WJ. 






EKT. 










SDH. 










ACS, 


DUP. 








CSD, 


DOW, 


ENJ, 


FG, KPP, KPT, MON, SHC, SIN, SKC, SNT 


TOC, UCC. 






DUP. 










BPC. 










SDC. 










UCC, 


X. 








ABB. 










IDC. 










DOW. 










GAF. 










TRC. 










WAY. 










DSC, 


DUP. 








SDW. 










ACY. 










ACS, 


DUP, 


SDH. 






BPC, 


MAL. 








TRC. 










UCC. 










RIL, 










RIL. 










GIV. 










DUP. 










DUP. 










EKT. 










DUP, 


EKT, 


GAF, 


ICC. 




ACS, 


cue. 


EKT. 






EK. 










ICC. 










EK, 


PIC. 








GAF, 


SDH. 








GAF, 


SDH. 








DUP, 


QKO. 








QKO. 
MLS. 











CYCLIC INTERMEDIATES 



79 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, 196 7 --Continued 



Chemical 



Manufacturers' Identification codes 
(according to list in table 22) 



2-Furylinethylketone 

N-Glycoloylarsanilio acid, sodium salt 

Hexachlorocyclopentadiene 

l,'4,5,6,7,7-Hexaohloro-5-norbomene-2,3-dicarboxylic acid — 

Hexadeoachlorophthalocyanine 

Hexafluorobenzene 

1,2,3,4, 5,6-Hexahyd^o-8-hydroxy-cis-6,ll-diIIlethyl- 
2,6-methano-2-benzazooine. 

Hexa(2-methyl-l-aziridinyl)-l,3,5-phosphotriazine 

Hippuric acid 

p-Hydrazinobenzenesulfonio acid 

3-H>'drazino-5-nitro-p-toluenesulfonic acid [S03H=l] 

'i-H/'drazino-m-toluenesulfonic acid 

J^drazobenzene 

•i^droquinone , tech 

<i'-Hydroxyacetaniline 

3'-Hydroxyacetophenone 

3'-}^droxyacetophenone benzoate 

p-ffcrdroxybenzaldehyde 

*p-Hydroxybenzenesulfonic acid 

p-Hydroxybenzoic acid 

6'-}tydroxy-m-benzotoluidide 

o-(p-Hrdroxybenzoyl)benzoic acid 

3'-I^droxy-2(N-benzyl-N-methylamino)acetophenone 

4-H/droxycoumarin 

3-[N-(2-Hydroxyethyl)anilino]propionitrile 

3-f N-(2-Hydroxyethyl)anilino]propionitrile, benzoate ester- 

N-(2-l^droxyethyl)cyclohexylajnine 

N-p-Ifydroxyethyl-2,'i-dihydroxybenzamide 

3-Hydroxy-N-(2-hydroxyethyl)-2-naphthamide 

N-[7-{tydroxy-8-[2-hydroxy-5-(methylsulfamoylphenyl)azo]-l- 

naphthyl] acetamlde. 
5'-It'droxy-5'-[(2-hydroxy-5-nitrophenyl)azo] -m-aceto- 

toluidide. 
N-[7-Hydroxy-8-[(2-hydroxy-5-nitrophenyl)azol-l-naphthyl]- 

aoetamide. 
7-Hydroxy-8-[[ <+'-[( i>hydroxyphenyl) azo] -4-biphenylyl] azo] - 

1,3-naphthalenedisulfonic acid. 
7-Hydroxy-8-[[ 4' 4 (p-hydroxyphenyl)azo]-3,3 '-dimethyl-i- 
biphenylyl] azo] -1,3-naphthalenedisulfonic acid. 
2-Hydroxy-a^,-i3-mesitylenediol 

M-l^droxymetanilamide 

t-A-ffydroxymetanilic acid 

N-C-t-tfydroxymetanilyljanthranilic acid 

4-I^droxy-l-methylcarbostyril 

3-Itydraxy-2-methylcinchoninic acid 

'i-Hydroxy-N^-methylmetanilamide 

N-(Hydroxymethyl)phthallmide 

3-Hydroxy-N-(3-N-morpholinopropyl)-2-naphthamide 

3-l^droxy-2,7-naphthalenedisulfonic acid 

»3-Hydroxy-2,7-naphthaleitedisulfonic acid, disodium salt 

7-Hydroxy-l,3-naphthalenedisulfonic acid 

7-Hydroxy-l,3-naphthalenedisulfonic acid, disodium salt 

'i-lfydroxy-2-naphthalenesulfonamide 

l-ftydroxy-2-naphthalenesulfonic acid, potassium salt 

"i-I^fdroxy-l-naphthalenesulfonic acid 

5-Hydroxy-l-naphthalenesulfonic acid 

t<6-l^droxy-2-naphthalenesulfonic acid 

*6-I6'droxy-2-naphthalenesulfonic acid, sodium salt 

7-l^droxy-2-naphthalenesulfonic acid (Cassella's acid) 

S-l^rdroxy-l-naphthalenesulfonlc acid 

'i-Hydroxy-2-naphthalenesulfonic acid, benzene sulfonate, 
sodium salt. 

3-[trdroxy-2-naphthanilide (Naphthol AS) 

l-}^droxy-2-naphthoic acid 

3-I^rdroxy-2-naphthoic acid (B.O.N.) 

3-Hydroxy-2-naphthoio acid, methyl ester 

l-Hydroxy-2-naphthoic acid, phenyl ester 

3-}tydroxy-2-naphtho-o-toluidide 

N-(2-Hydroxy-l-naphthyl)acetamide 

*N-(7-Hydroxy-l-naphthyl)acetamide 



EK. 




SDW. 




HK, VEL. 




HK, VEL. 




ICC. 




WHC. 




SDW. 




ICO. 




BPC. 




GAF, WJ. 




STG. 




GAF. 




HEX. 




CRS, EKT, 


MAN. 


TRC. 




SDH. 




SDH. 




DOW. 




DOW, MON, 


UPF. 


HN, WSN. 




TRC. 




LIL. 




SDW. 




ABB. 




DUP, ICC. 




DUP. 




ABB. 




IDC. 




IDC. 




TRC. 




TRC. 




TRC. 




TRC. 




TRC. 




ACY. 




ACS, cm, 


DUP, TRC, VPC 


AAP, ACS, 


CWN, DUP, TRC 


TRC. 




ICC. 




DUP, ICC. 




TRC. 




ACY. 




IDC. 




ATL. 




ACS, ACY, 


GAF, TRC, WJ. 


DUP, TRC. 




ACS, ACY. 




GAF. 




EK. 




ACS, DUP. 




ACS. 




ACS, SNA, 


TMS. 


ACY, TRC, 


WJ. 


DUP. 




GAF, VPC. 




GAF. 




ATL, BUG, 


PCW. 


ACS. 




BUG, DUP, 


GAF, HN, PCW. 


PCW. 




EK. 




ATL, BUC, 


PCW. 


ACY. 




CMG, GAF, 


TRC. 



80 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer , i567--Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



l-(2-I^droxy-l-naphthylazo)-6-nitro-2-naphthol-'i -sulfonic 

acid. 

N-(7-lfy'droxy-l-naphthyl)'benzamide 

3'- [(7-Ifydroxy-l-naphthyl)carbamoyl] acetanilide 

4-[^droxy-7- [p-(p-nitrobenzamido)benzamido] -2-naphthalene- 

sulfonic acid, 
'4-Hydroxy-7-(p-nitrobenzamido)-2-naphthalenesulfonio acid — 

2-I^droxy-5-nitrometanilio acid 

l-(2-Hydroxy-<i-nitrophenylazo)-2-naphthol 

2-(m-ffydroxyphenoxy) ethanol 

o- [(p-Hydroxyphenyl)azo]benzoio acid 

3-['i-('>'-[^droxyphenylazo)-2,5-dimethoxyphenylazo] - 

benzenesulfonic acid. 

3-}fydroxy-A-(phenylazo) -2 -naphthoic acid 

lla-I^droxyprogesterone 

<t-Hjrdroxypropiophenone 

o, a'-[(a-Hydroxy-p-sulfobenzylidene)bis [(3-methyl-p- 

phenylene)(ethyliinino) ]]di-m-toluenesulfonio acid. 

l-^ydroxy-4-p-toluidinoanthraquinone 

2-Imidazolidinone modifications 

»1,1' 
1,1' 



-Iminobis 
-Iminobis 



■i-aminoanthraquinone] 

i-benzamidoanthraquinone] 

*l,l' -Iminobis [5-benzamidoanthraquinone] 

«7,7'-Iniinobis ['i-hydroxy-2-naphthalenesulfonic acid] 

*l,l'-Iminobis [■i-nitroanthraquinone ] 

*l,l'-Iminodianthraquinone (1,1' -Dianthrimide) 

l,3_Indandione 

Indanone 

Indole-2,3-dione 

5-Iodoanthranilio acid 

Isobutylbenzene 

»Isocyanic acid derivatives : 

Bitolylene diisocyanate (TODI) 

p-Chlorophenyl isocyanate 

Cyclohexyl isocyanate 

Dianisidine diisocyanate (DADI) 

3,4-Dichlorophenyl ester 

Dioyclohexylme thane 4, 4 '-diisocyanate 

*Diphenyljiiethane 4,4 '-diisocyanate (MDI) 

Phenyllsocyanate 

Polyisooyanates (complex) 

Polymethylene polyphenylisocyanate 

Toluene 2, 4-di isocyanate 

Toluene 2,4- and 2,6-dlisocyanate (55/35 mixture) 

■»Toluene 2,4- and 2,6-diisooyanate (80/20 mixture) 

p-Tolyl ester 

Other 

Isonicotinio acid, methyl ester 

Isonicotinonitrile 

Isoootylphenol 

Isophthalic acid (Benzene-l,3-dicarboxylic acid) 

Isophthalic acid, diallyl ester 

Isophthalic acid, dimethyl ester 

Isophthalic acid, diphenyl ester 

Isophthaloyl chloride 

N-Isopropylaniline 

4,4 '-Isopropylidenebis[2,6-dibromophenol] (Tetrabromobis- 

phenol A) . 
4,4 '-Isopropylidenebis[2,6-diohlorophenol] (Tetrachlorobis- 
phenol A) . 

5,5'-lEopropylidenebis(2-hydroxy-m-xylene-a,a' -diol) 

»4,4'-Isopropylidenediphenol (Bisphenol A) 

'+>4' -Isopropylidenediphenol, ethoxylated 

4,4 -Isopropylidenediphenol, propoxylated 

o-Isopropylphenol 

4-Isopropyl-m-phenylenediamine 

1,3-Isoqulnolinediol 

Isothiocyanio acid, phenyl ester 

*Isoviolanthrone (Isodibenzanthrone) 

»Leuco quinizarin (1,4,9,10-Anthratetrol) 

2,4-Iutidine 

3,4-Lutidlne 



TRC. 

TRC. 
TRC. 
DUP. 

DUP, GAF. 

TRC. 

TRC. 

BJL. 

PIC. 

TRC. 

ICC. 
UPJ. 
MLS. 

TRC. 



ICI. 

RH. 

ACS, 

ACY, 

GAF, 

ATL, 

ACY, 

ACY, 

PIC. 

EK. 

ACS. 

SDW. 

PLC. 

UPJ. 

MOB. 

CWN, 

CWN, 

DUP. 

DUP. 

ACS, 

CWN, 

MOB. 

KAI, 

DUP, 

DUP, 

ACS, 

EK. 

DUP, 

RIL. 

RIL. 

PRD. 

ACC, 

FMP. 

MTR. 

BJL. 

DUP. 

ACY, 

DOW. 

DVC. 

ARK. 
DOW, 
APD. 
APD. 
TNA. 
DUP. 
DUP. 
CFC. 
ACY, 
AAP, 
ACP, 
RIL. 



ACY, CMG, DUP, GAF, ICI, MAY, TRC. 

MAY. 

ICI, TRC. 

DUP, TRC. 

DUP, ICI, MAY, TRC. 

GAF, ICI, MAY, TRC. 



ore. 

UPJ. 



DUP, MOB, UPJ. 
MOB. 

MOB, UPJ. 

MOB. 

MOB. 

DUP, MOB, OMC, RUC, UCC. 

EK, MOB, ore. 



SOC. 



EKT. 



GE, MON, SHC, UCC. 



DUP, GAF, ICI, MAY, TRC. 
ACS, ACY, EKT, HSH, ICC, TRC. 
KPT. 



CYCLIC INTERMEDIATES 



81 



TABLE IB. --Cyclic intermediates foy which U.S. production or sales were reported, identified by 

manufacturer, i567--Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



Malondianilide 

Mandelonitrile 

*Melamine 

»»dl-p-Mentha-l,8-diene (Limonene) 

p-Mentha-l,'»(8)-diene 

O-Mercaptobenzoio acid (Thiosalioylic acid) 

Metanilamide 

Metanilanilide 

JtMetanilic acid (m-Aminobenzenesulfonic aoid) 

1-Methoxyanthraquinone 

4--Methoxymetanilic acid 

l-Methoxy-'i-nitroanthraquinone 

6-Methoxy-8-nitroquinoline 

(m-Methoxyphenyl)acetic acid 

(p-Methoxyphenyl)acetio acid 

i-Methoxy-m-phenylenediamine sulfate 

<i' -Methoxypropiophenone 

*l-(Methylainino)anthraquinone 

l-(Methylaniino)-4-p-toluidinoanthraquinone 

N-Methylaniline 

3-CN-Methylanilino)propionitrile 

5-Methyl-o-anisidine [ NH2=1 ] 

m-Methylanisole 

N-Methylanthranilic acid 

2-Methylanthraquinone 

3-Methylbenzo[f] quinoline 

2-Methylbenzo[f] quinoline-8,10-disulfonio aoid 

2-Methylbenzothiazole 

A-Methylbenzyl alcohol 

N-Methylbenzylamine 

Methyl benzyl ether 

5-(l-Methylbutyl)barbituric acid 

3-Methyloholanthrene 

Methylcyclohexane 

Methyloyclohexenecarboxaldehyder 

Methylcyclohexene-l,2-dicarboxylic anhydride 

Methylcyclohexene methanol 

A-Uethyl-o., a-diphenyl-1-piperazineethanol, dlhydrochlorlde- 

N-Methyleneaniline 

'i,<i'-Methylenebis[ 2-chloroaniline] 

4,4'-Methylenebis[N, N-diethylaniline] 

*';, 4 ' -Methylenebis 
4,<i ' -Methylenebis 



N,N-dimethylaniline] (Methane base) 

[N, N-dimethyl-3-nltroaniline] 

'4,4'-Methylenebis[3-hydroxy-2-naphthoio aoid], disodlum 

salt. 

2,2 ' -Methylenebis (6-nonyl-p-cresol) 

'4,4 '-Methylenedianiline 

5,5 '-Methylenedisalioylic aoid 

5-Methylene-2-norbomene 

N-Methyiformanillde 

Methylhydroquinone 

2-Methylindole-3-oarboxaldehyde 

6-Methyl-2-(2-methyl-6-quinolyl)-7-benzothiazolesulfonio 

aoid. 

Methylnaphthalene, crude 

N-Methyl-4'-nitroaoetanilide 

N-Methyl-p-nltroaniline 

5-Methyl-4-nitro-o-anisidlne 

»2-Methyl-l-nitroanthraquinone 

2-Methyl-5-nltroiiiiidazole 

N-Methyl-N-nitroso-p-toluenesulfonamide 

2-Methyl-5-norbomene-2,3-dioarboxylio anhydride 

Methylnorbomene-2,3-dicarboxylic anhydride, isomers 

3'-Methyl-5-[(7-oxo-7H-benz [de] anthraoen-3-yl) -amino] -1,2'- 

iminodianthraquinone . 

m-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonamide 

m-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonio aoid 

*p-(3-Methyl-5 -0X0-2 -pyrazolin-l-yl)benzenesulfonio acid 

3-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-l,5-naphthalenedisul- 

fonic aoid. 
*4-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-m-toluenesulfonic acid 

[S03H=l]. 



KF. 




KF. 




ACP, ACY, PIS, 


RCI. 


ARZ, GIV, HNW, 


NCI. 


GIV. 




EVN, LIL, MED. 




CMG, VPC. 




GAF. 




ACY, DUP, TRC. 




DUP, GAF. 




ACY, CMG, GAF. 




DUP. 




SDW. 




SDW. 




CTN, UOP. 




WAY. 




LIL. 




AAP, ACS, ACY, 


DUP, GAF, ICI. 


GAF, I CI. 




ACY, DUP. 




DUP. 




DUP, SDC. 




GIV. 




GIV, ICC. 




ACS, ACY. 




ACY. 




DUP. 




FMT. 




UCC. 




ABB, MLS, SDW. 




UCC. 




LIL. 




EK. 




PLC. 




UCC. 




UCC. 




UCC. 




ABB. 




DUP. 




DUP. 




ACY, GAF, SDH, 


TRC. 


ACS, ACY, DSC, 


DUP, GAF, SDH, x. 


GAF. 




PD. 




ACY. 




ACS, DOW, DUP, 


MOB. 


HN. 




DOW. 




MLS. 




EKT. 




GAF. 




DUP. 




KPT. 




ACS, GAF. 




ACY, GAF. 




PCW. 




ACS, DUP, GAF, 


ICI. 


RDA. 




ALD, EK. 




VEL. 




ACS. 




DUP. 




CMG, VPC. 




TRC. 




AAP, ACY, CMG, 


DUP, GAF, TRC, VPC 


TRC. 




(Mi, GAF, TRC, 


VPC. 



82 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer , i967--Continued 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



2-Methyl-5-phenylbenzoxazole 

l-Methyl-2-phenylindole-3-oarboxaldehyde 

l-Methyl-'i-phenylisonipeootio acid 

5-Methyl-3 -phenyl -4-isoxazoleoarboxylic acid 

5-Methyl-3-phenyl-'i-isoxazolecarboxylic acid hydrochloride- 

»3-Metl^l-l-phenyl-2-pyrazolin-5-one (Developer Z) 

Methylphenylsiloxane tetramer 

Methyl phenyl sulfide (Thioanisole) 

l-Methylpiperazine 

<i-Methyl-l-piperazineaoetic acid, methyl ester 

2-Methyl-l-piperidinepropanol 

3-Methyl-2-pyrazolin-5-one 

*a-Methylstyrene 

ar-Methylstyrene (Vinyltoluene) 

N-Methyl-5-sulfoanthranilic acid 

2-(Methylsulfonyl)-'4-nitroaniline 

•i-(Methylthio)-m-cresol 

3-Methylthiophene 

p-(Methylthio)phenol 

3-Methyl-6-p-toluidino-7H-dibenz[f,ij]isoquinoline- 

2,7(3H)-dione. 
3-Methyl-l-p-tolyl-2-pyrazolin-5-one 

*Naphthalene, solidifying at 79° C. or above (refined flake) 
(from domestic crude). 

2,5-Naphthalenedicarboxylio acid 

1,5-Naphthalenedlsulfonio acid 

*2,7-Naphthalenedisulfonic acid 

1-Naphthalenesulfonic acid 

1-Naphthalenesulfonic acid, sodium salt 

2-Naphthalenesulfonic acid 

2-Naphthalenesulfonic acid, sodium salt 

2-Naphthalenesulfonyl chloride 

*l,4,5,8-Naphthalenetetracarboxylic acid 

1,3,6-Naphthalenetrlsulfonio acid 

Naphthalio anhydride 

Naphthalimide 

2H-Naphth[l,8-cd] isothiazole-3,5-disulfonio acid, 
1,1-dioxide, trlsodium salt. 

1-Naphthol (a-Naphthol) -- 

2-Naphthol, tech. (fj-Naphthol)^ 

p-Naphtholbenzein 

Naphthostyril 

»Naphth[l,2-d] [l,2,3]oxadiazole-5-sulfonio acid 

1-Naphthylamine (a-Naphthylamine) 

1-Naphthylamine hydrochloride 

p - ( 2 -Naphthylamino ) phenol ( N- ( p -Itydroxyphenol ) -2 - 
naphthylaim" ne ) . 

2-(Naphthylthio) acetic acid 

Nicotinonitrile (3-CyanopyTldine) 

Nitro-aceanthra [2,l-a]aceanthrylene-5,13-dione 

3 '-Nitroacetanilide 

"i'-Nitroacetanillde 

2 '-Nitro-p-acetanisidlde 

"4 '-Nitro-o-acetanisidide 

3 -Nitroacetophenone 

5 '-Nitro-o-acetotoluidide 

m-Nitroaniline 

o-Nitroaniline 

*p-NitroaniHne 

2-Nitro-p-anisidine [NH2=l] 

'i-Nitro-o-anisidine [NH2=1] 

»5-Nitro-o-anisidine [NHjil] 

o-Nitroanisole 

p-Nitroanisole 

"i-Nitroanthranilic acid 

5-Nltroanthranilic acid 

l-Nitroanthraqulnone 

2-(4-Nitro-2-anthraquinonyl)anthra [2, 3-d] -oxazole- 
5,10-dione. 

m-Nitrobenzaldehyde 

■i'-Nitrobenzanilide 

»Nitrobenzene 



EK. 

GAF 

SDW 

ICO 

ICO 

ACS 

DCC 

PIT, 

WTC 

ABB 

LIL, 

DUP, 

ACP 

DOW, 

GAF 

EKT 

CRZ 

SDW 

CRZ 

DUP, 

VPC 
ACS 

NEP, 
ACS 
ACS 
TRC 
TRC 
ACS 
ACY 
DUP 
GAF 
GAF 
DUP 
ACS 
DUP 

ACS 
ACS 

EK. 
ACS 
ACS 
ACS 
GAF 
ACS, 

ACY 
NEP 
ICI 
AAP 
AAP 
DUP, 
DUP 
CTN 
DUP 
ACY 
AAP 
AAP 
DUP 
DUP 
ACY 
DUP 
DUP 
DUP 
TRC 
ACY 
ACS, 

ACS 
GAF 
ACS 



ACY, DUP, GAF, SDH, SDW, VPC. 

CLK, DOW, HPC, SKO, WTC. 
TRC. 

GAF, ICI. 
KPT, RIL. 



TRC. 
DUP, TRC. 



ACY. 

HST, TRC. 
DUP, GAF. 



DUP, UCC. 
ACY, SW. 

GAF. 

CMC, GAF, TRC, VPC. 

DUP. 

GAF, SDC. 



RIL. 



GAF, TRC. 
SDH. 

SDH. 

x. 

MON. 

MON, UPM. 

SDH. 

SDH. 

ALL, BUC, DUP. 

MON. 



ICC. 
GAF. 



SDH. 



ACY, DUP, FST, MOB, MON, RUC. 



See footnotes at end of table. 



CYCLIC INTERMEDIATES 



83 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, J 967 --Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



3 '-Nitrobenzenesulfonanilide 

■"m-Nitrobenzenesulfonio acid 

*m-Nitrobenzenesulfonic acid, sodium salt 

m-Nitrobenzenesulfonyl chloride 

p-Nitrobenzenesulfonyl chloride 

5-Nitro-2-benzimidazolinone 

m-Nitrobenzoic acid 

m-Nitrobenzoic acid, sodium salt 

p-Nitrobenzoic acid 

m-Nitrobenzoyl chloride 

p-Nitrobenzoyl chloride 

p-Nitrobenzyl alcohol 

■4'-Nitro-^-biphenylcarboxylic acid 

■4-Nitro-sec-butylbenzene 

2-Nitro-p-cresol 

Nitrocyclohexane 

Nitrodiphenylamine 

5-Nitrofuraldehyde diacetate 

5-Nltro-2-furfuraldehyde diacetate 

5-Nitroisophthalic acid 

1-Nitronaphthalene 

3-Nitro-l,5-naphthalenedisulfonic acid 

^-Nitronaphthalic anhydride 

»7(and 8)-Nitronaphth[l,2-d] [l,2,3]oxadiazole-5-sulfonic 
acid. 

o-Nltrophenol 

*p-Nitrophenol 

»p-Nitrophenol, sodium salt 

(p-Nitrophenyl) acetic acid 

4' -(p-Nitrophenyl)acetophenone 

i- [( p-Nitrophenyl )azo]-o-anisidine 

2-Nitro-p-phenylenediamine 

"i-Nitro-o-phenylenediamine 

(p-Nitrophenyl )hydrazine 

2,2'-(m-Nitrophenylimino)diethanol 

2,2'-(m-Nitrophenylimino)diethanol, diacetate ester 

2-(p-Nitrophenyl)-2H-naphtho[l,2-d] triazole-6,8-disulfonic 
acid. 

l-(m-Nitrophenyl)-5-oxo-2-pyrazoline-3-carboxylic acid 

3-Nitrophthalic acid 

3-Nitrophthalic anhydride 

5-Nitrosalicylaldehj'de 

3(and 5)-Nitrosalicylic acid 

p-Nitrosophenol 

-i-Nitrostilbene 

(3-Nitrostyrene 

4-Nitro-'i'-(5-sulfo-2H-naphthol[l,2-d] triazol-2-yl)-2, 
2'-stilbenedisulfonic acid. 

m-Nitrotoluene 

o-Nitrotoluene 

p-Nitrotoluene 

Nitrotoluene mixtures 

5-Nitro-o-toluenesulfonanllide 

p-Nitrotoluenesulfonic acid 

*3-Nitro-p-toluenesulfonic acid [SOsHsl] 

»5-Nitro-o-toluenesulfonic acid [S03H=l] 

4'-Nitro-p-toluenesulfono-o-toluidide 

3-Nitro-p-tolulc acid, methyl ester 

»2-Nitro-p-toluldine [NH2=1 ] 

4-Nitro-o-toluidine [NH2=1 ] 

»5-Nitro-o-toluidine [NH2=1 ] 

5-Nitro-2-p-toluidinobenzenesulfonic acid 

3-Nitrotoluoyl chloride 

16-Nltrovlolanthrone 

"♦-Nltro-m-xylene 

Nltroxylenes, mixed 

Nonyl-dinonylphenol, mixture 

*Nonylphenol 

5-Norbomene-2,3-dicarboxylio anhydride 

Ootylphenol 

Octylphenyl acid phosphate 

7-Clxabicyclo['i. 1.0] heptane (Cyclohexene oxide) 



GAF. 

ACS, ACY, DUP, TRC. 

GAF, MON, MRA. 

GAF. 

EK. 

DUP. 

SDH, WAX. 

WAY. 

DUP. 

HK. 

HK. 

EK. 

TRC. 

WAY. 

SW. 

X. 

ACY, MON. 

NOR. 

NOR. 

FIS, GAF. 

ACS, DUP. 

OAF, TRC. 

ACS, GAF. 

ACS, GAF, TRC, VPC. 

DUP. 

DUP, MON, SDC, Um. 

MON, UPM. 

BPC. 

DUP. 

AAP. 

FIS, WAY. 

DUP, FMT. 

EK. 

DUP. 

DUP. 

TRC. 

DUP, VPC. 

EK. 

EK. 

EK. 

GAF. 

ACS, ACY, DUP, SDC. 

GAF. 

CWN. 

TRC. 



ACS, 
ACS, 
ACS, 
ACS, 
GAF. 
GGY. 
AAP, 
ACS, 
GAF. 
SDH. 
ABB, 
GAF. 
BUG, 
TRC. 

X. 

ATL, 
DUP. 
ACS. 
JCC. 
GAF, 
VEL. 
RH. 

ai. 

AHA. 



DUP. 

DUP, FST. 
DUP, FST. 
DUP, FST. 



CMG, TRC. 

ACY, DUP, GAF, SDH, TRC. 



ACY, DUP, SDH, SW. 

DUP, PCW, SDH. 

GAF, ICI. 

JCC, MON, PRD, RH, STP. 



84 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer , i567--Continued 



Chemical 



Manufacturers' identification codes 
(according to list in tatle 22) 



Oxalacetic acid, diethyl ester, (p-sulfophenyl)hydrazone- 
Oxanilide 

*l-[(7-0xo-7H-benz [de] anthraoen-3-yl)aminc] anthraquinone 

*1,1' -[(7-0xo-7H-benz[de] anthracen-3,9-ylene)diiiiiino]di- 
anthraquinone . 

5-0xo-l-phenyl-2-pyrazoline-3-carboxylic acid 

5-Oxo-l-phenyl-2-pyrazoline-3-carboxylic acid, ethyl ester- 
5-0xo-l-(p-sulfophenyl)-2-pyrazoline-3-carboxylic acid 
(pyrazolone T). 

5-0xo-l-(p-sulfotolyl)-2-pyrazoline-3-carboxylic acid 

4,'>'-0xydianiline 

4,4'-0xydiphenol 

Penicillin, N-ethylpiperidine salt 

1,1,3,3,5-Pentamethylindan 

Pentylnaphthalenes ( Amylnaphthalenes ) 

o-Pentylphenol (o-Aniylphenol) 

p-tert-Pentylphenol 

3,'+,9,10-Perylenetetracarboxylic acid 

»3,4,9,10-Perylenetetracarboxylic-3,<i:9, 10-diimide 

Phenethylamine 

Phenethylamine sulfate 

o-Phenethylbenzoic acid 

o-Phenetidine 

p-Phenetidine 

*Phenol : 
*Natural : 

*Froin coal tar:^ 

39^ C, m.p 

825^-84^ 

All other 

*From petroleum 

^-Synthetic ; 

By caustic fusion: U.S.P 

From chlorobenzene by liquid -phase hydrolysis: U.S.P- 
From chlorobenzene by vapor-phase hydrolysis: U.S.P-- 

*From oumene by oxidation: U.S.P 

Phenolsulfonaphthalein 

Phenolsulfonaphthalein, sodium salt 

Phenothiazin-2-yl-l-propanone 

Phenoxyacetic acid, sodium salt 

2-Phenoxypropanol 

2-Phenoxypropionyl chloride 

Phenylacetic acid (a-Toluic acid) 

Phenylacetic acid, ethyl ester, tech 

Phenylacetic acid, methyl ester 

Phenylacetic acid, potassium salt 

Phenylacetic acid, sodium salt 

*Phenylacetonitrile (a-Tolunitrile) 

4-' -Phenylacetophenone 

N-Phenylanthranilio acid 

2-Phenylanthra[2,3-d] oxazole-5,10-dione 

*p-Phenylazoaniline (C.I. Solvent Yellow 1) and hydrochlo- 
ride. 

'4-(phenylazo)diphenylamine 

4-(Phenylazo)-l-naphthylamine 

4-(Phenylazo)-m-phenylenediamine (C.I. Basic Orange 2) 

l-Phenyl-l,3-butanedione 

2-Phenylbutyric acid 

a-Phenyl-o-cresol 

1-Phenylcyclopentanecarboxylic acid 

1-Phenyldecane (Decylbenzene) 

N'N'-p-Phenylenebis[acetamide] 

ra-Phenylenediamine 

o-Phenylenediamine 

ifp-Phenylenediamine 

d -Phenylephrine base 

dl-Phenylephrine base 

Phenyl-l,2-ethanediol 

2-Phenylethenesulfonic acid, sodium salt (|i-Styrenesulfonic 
acid, sodium salt). 

Phenyl ether ( Diphenyloxide ) 

d-Phenylglycine 

See footnotes at end of table. 



TRC. 

WSN. 

ACY, DUP, GAF, ICI, MAY, TRC. 

ACY, DUP, GAF, ICI, MAY, TRC. 

ACS. 

GAF, SDW, VPC. 

AAP, GAT, VPC. 

VPC. 

X, X. 

EK. 

MRK. 

GIV. 

PAS. 

PAS. 

X, 

ACS, GAF. 

ACS, DUP, GAF. 

MLS. 

MLS. 

LIL. 

MON. 

MON. 



KPT, 


PRD. 






ACP, 


KPT. 






ACP, 


KPT. 






MER, 


NPC, 


PIT, 


PRD, SW. 


MAL, 


MON, 


fiCI. 




DOW. 








HKD, 


UCC. 






ACP, 


CLK, 


HPC, 


MON, SHC 


EK. 








EK. 








WYT. 








BPC. 








ICO. 








ICO, 


OPC. 






BPC, 


GIV, 


MAL. 




BPC, 


UOP. 






BPC. 








BPC, 


OPC, 


UOP. 




BPC, 


OPC, 


UOP. 




BPC, 


OPC, 


SDW, 


UOP. 


DUP. 








SDW. 








GAF. 








ACS, 


ACY, 


DUP, 


GAF. 


EK. 








DUP. 








DUP. 








EK. 








BPC. 








RBC. 








SK. 








ACS. 








ACY. 








ACS, 


ACY, 


DUP, 


GAF. 


AAP, 


DUP, 


FMT, 


MEE. 


ACY, 


BFG, 


SDC. 




SDW. 








SDW. 








AHA. 








DUP, 


SHL. 






DOW. 








ore. 









CYCLIC INTERMEDIATES 



85 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, i567--Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



d-( -)-2-Phenylglycine and derivatives 

d-(-)Phenylglycine, N-carboxy anhydride 

dl-2-Phenylglyoine (racemic) 

Phenylglyclne, sodium salt 

Phenylglycol ethers 

d-( -)Phenylglycyl hydrochloride 

5 -Phenylhydantoin 

Phenylhydrazine 

Phenylhydrazine hydrochloride 

2,2'- [( Phenyl )imino]diethanol (N-Phenyldiethanolamine) 

3,3 '- [( Phenyl )imino]dipropionitrile 

Phenyljnagnesium bromide 

Phenylmalonio acid, diethyl ester 

o-Phenylphenol 

o-Phenylphenol, chlorinated 

o-Phenylphenol, sodium salt 

p-Phenylphenol 

N-Phenyl-p-phenylenediamine 

Phenylphosphinic acid 

Phenylphosphonic dichloride 

Phenylphosphonothioic dichloride 

Phenylphosphonous acid 

Phenylphosphonous acid, sodium salt 

Phenylphosphorous dichloride 

1-Phenylpiperazine 

»l-Phenyl-l,2-propanedione, 2-oxime 

Phenyl -2 -propanone 

Phenylsiloxane tetramer 

Phenylsuccinic acid 

Phenyl sulfone 

1-Phenyl -2 -thiourea 

Phenylundecanoic acid 

Phenylurea 

Phloroglucinol 

l(2H)-Phthalazinone 

Phthalic acid 

Phthalic acid, disodium salt 

«Phthalic anliydride 

Phthalide 

Phthalimide 

Phthalimide, potassium salt 

[phthalocyaninato( 2- )1 copper 

[ Phthalocyaninato( 2-) ] iron 

Phthalocyaninetetrasulfonyl chloride, copper derivative 

Phthaloyl chloride (Phthalyl chloride) 

3-Picoline-N-oxide 

*Picolines:^ 

«2-Picoline (:t-Picoline) 

3-Picoline (P-Plcoline) 

"i-Picoline (y-Picoline) 

Picollne (3,<V-mixture) 

Picolinic acid 

Picolinonitrile ( 2 -Cyanopyridine ) 

3-Picolylamine 

Picric acid (Trinitrophenol) 

2-Pipecoline 

2,5-Piperazinedione 

Piperazine mixture, crude^ 

*Piperldine 

3-Piperidinopropiophenone hydrochloride 

Polychlorobiphenyl 

Poly (Methylenephenylene) polyamine 

»Prtmuline base 

Primulinesulfonic acid 

»Propiophenone 

n-Propylbenzene 

*8,16-Pyranthrenedione 

Pyrazole 

FJrrid ine , refined : ^ 

»2° Pyridine 

Other grades 

See footnotes at end of table. 



KT. 








OTC. 








KF. 








ACS. 








UCC. 








OTC. 








ABB. 








DOW. 








EK, VPC. 








EKT, GAP. 








DUP. 








ARA. 








BPC. 








DOW, RCI, 


RSA. 






DOW. 








DOW. 








DOW, 








DUP, USR. 








SFI. 








SFI. 








SFI. 








SFI. 








SFI. 








SFI. 








RSA. 








ICO, NEP, 


ORT. 






ORT, SK. 








DCC. 








PD. 








NES. 








EK. 








EK. 








RSA. 








MRT. 








ACS, X. 








EK, FMP, 


KF, MEE. 






CFC. 








ACP, GRH, 


KPS, MON, PCC, PTO, RCI, SOC, 


STP, SW, THC 


UCC, WTC. 






ACS, FMT. 








DUP, MEE. 








EK, SDW. 








ICC, ICI. 








DUP. 








DUP, TRC. 








MON. 








RIL. 








ACP, KPT, 


RIL, UCC. 






NEP, RIL. 








RIL, UCC. 








ACP, KPT. 








NEP. 








NEP. 








RIL. 








ACS, SDC. 








LIL. 








EK. 








FIM, JCC, 


X. 






ABB, DUP, 


MRK, RIL. 






ACY. 








MON. 








KAI. 








ACS, ATL, 


DUP. 






ATL. 








LIL, OPC, 


ORT, UOP. 






EK, HMY. 








am, ICI, 


TRC. 






LIL. 








ACP, KPT, 


NEP, RIL. 






KPT. 









86 



SYNTHETIC ORGANIC CHEMICALS 1967 



TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



pyridine hydrochloride 

3-Pyridinemethanol 

Pyridine-N-oxide 

3-Pyridinol 

2(lH)-pyridone 

2-ryrimidinol 

2-Pyrrolidinone 

3-(l-iyrrolidinyl)propiophenone hydrochloride 

Quinaldlne 

Quinoline : 

1° and 2" Quinoline 

Other grades 

2,'i-Quinolinediol 

8-Quinolinol (8-Hydroxyquinoline, tech.) 

Quinophthalone (Quinoline yellow, base) 

2-Quinoxalinol 

Resorcinol, monoacetate (nonmedicinal grade) ^ 

Resoroinol, tech-"^ 

p-Resoroylio acid 

p-Resorcylic acid, lead salt 

*Salicylaldehyde 

*<-Salicylic acid, tech 

Salicylic acid, ammonium chromium complex 

Salicylic acid, sodium chromium complex 

Salicylic acid, sodium salt (crude) 

Salioylideneaminoguanidine oleate 

Sodium phenoxide 

*Styrene, all grades 

5-Sulfamoylanthranilio acid 

Sulfanilic acid (p-Aminobenzenesulfonic acid) and salt- 

Sulfapyridine, tech-* 

-l-Sulfoanthranilio acid 

5-Sulfoanthranilic acid 

a, a- [(p-Sulfobenzylidene)bis[ (3-methyl-p-phenylene)- 
(ethylimino)]] di-m-toluenesulfonic acid. 

5-Sulfoisophthalic acid, 1,3-dimethyl ester 

it,^ '-Sulfonyldianiline 

N,5'-Sulfonyldianthranilic acid 

4,4' -Sulf onyldiphenol (4,4' -Dihydroxyd iphenylsulf one ) - - 

»Terephthalic acid 

«Terephthalic acid, dimethyl ester 

Terphenyl (Phenylbiphenyl) 

1,2,4,5-Tetraaminobenzene tetrahydrochloride 

[4, 4', 4' ' ,4" '-Tetraaminophthalocyaninato(2-)] copper — 
3',3",5',5' '-Tetrabromophenolphthalein, ethyl ester — 

Tetrabromophthalic anhydride 

Tetrabromo-8,16-pyranthrenedione 

1,3,5,8-Tetrabromopyrene 

»l,4,5,8-Tetraehloroanthraquinone 

1,2,4,5-Tetrachlorobenzene 

1,2, 4, 5-Tetrachloro-3 -nitrobenzene 

a,a,2,6-Tetrachlorotoluene 

Tetraohloroviolan throne 

Tetrahydrofuran 

Tetrahydrofurfuryl methacrylate 

*l,4,5,8-Tetrahydroxyanthraquinone, leuco derivative 

l,4,5,8-Tetrakis(l-anthraquinonylamino)anthraqulnone 
( Pentanthrimide ) . 

p-(l,l,3,3-Tetramethylbutyl)phenol 

3,3 ',5, 5 '-Tetramethyldiphenoquinone 

N, N,N', N'-Tetramethyl-p-phenylenediamine 

[4,4' ,4' ',4 ' ' '-Tetranitrophthalocyaninato(2) ] copper 

2-(2-Thenylamino)pyridine 

2,4-Thiazolldinedione 

»3,3'-Thiobis[7H-benz[de] anthracen-7-one] 

l,l'-Thiobis(2-naphthol) — - 

2,2'-Thiobis[ 5-nitrobenzenesulfonic acid] 

4,4'-Thiodianiline 

6,5' -Thiodimetanilio acid 

2-Thiohydantoin 

Thiopheneacetic acid 



EK. 

RIL. 

RIL. 

NEP. 

FMT. 

GGY. 

GAP. 

LIL. 

ACS, ACY. 

ACP, KPT. 

EK. 

DUP, OAF. 

FIS. 

ACS, DUP. 

EK. 

AAP. 

KPT, UPF. 

ACY, KPT. 

ACY. 

DOW, HN, MTR, RDA. 

CFC, DOW, HN, WON, SDH. 

TRC. 

TRC. 

DOW, SDH. 

DUP. 

CFC, DUP. 

ACC, CSD, DOW, ELP, FG, KPP, MCB, MON, SHC, SKC, SNT, 

UCC. 
TRC. 

ACS, ACY, CTN, DUP. 
AAC. 

CMC, TRC. 
ICI. 
TRC. 



RSA. 

TRC. 

MON, 

ACC, 

ACC, 

MON. 

BJL. 

DUP. 

EK. 

MCH. 

ACS. 

GAF. 

ACS, 

DOW, 

SDH. 

DUP. 

GAF, 

DUP, 

SAfi. 

AAP, 

ACS, 

GAF. 

DUP. 

EK. 

DUP. 

ABB. 

EK. 

ACY, 

ACY. 

GAF. 

ACS, 

ACS, 

BPC. 

BPC. 



UPF. 

DUP, EKT. 
DUP, EKT, HPC. 



DUP, GAF. 
DVC, HK. 



ICI. 
QKO. 



ACS, OAF, ICC, TRC. 
ICI. 



DUP, GAF, ICI, MAY, TRC. 



ACY. 
GAF. 



See footnotes at end of table. 



CYCLIC INTERMEDIATES 



87 



TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer , iS67- -Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



2-Thiopheneacetyl chloride 

2-Thiopheneoarboxaldehyde 

sym-Thymol 

«Toluene-2, ^-diamine (<i-m-Tolylenediamine) 

Toluene-2,5-diamine sulfate 

Toluene -2, "i-disulfonic acid 

o-Toluenesulfonamide 

p-Toluenesulfonamide 

o(and p ) -Toluenesulf onic acid 

p-Toluenesulfonic acid 

p -Toluenesulf onic acid, ethyl ester 

p-Toluenesulfonic acid, methyl ester 

p-Toluenesulfono-o-toluidide 

p-Toluenesulfonyl chloride 

m-Toluic acid 

o-Toluic acid 

p-Toluio acid 

m-Toluidine 

o-Toluidine 

o-Toluidine hydrochloride 

p-Toluidine 

p-Toluidine hydrochloride 

Toluidines, mixed 

2-o-Toluidinoethanol 

m-Toluidinomethanesulfonic acid 

o-Toluidinomethanesulfonlc acid 

8-p-Toluidino-l-naphthalenesulfonic acid 

*o-(p-Toluoyl)benzoic acid 

N-(p-Tolyazo)sarcosine 

■>f4-(o-Tolylazo)-o-toluidine (C.I. Solvent Yellow 3) — 

4-(o-Tol^lazo)-o-toluidine hydrochloride 

1-p-Tolyldodecane 

2,2'-(m-Tolylimino)diethanol 

p-Tolylmercuric chloride 

N, N, N-Tribenzylamine 

l,2,3(and l,2,';)-Trichlorobenzene 

1,2,'V-Trichlorobenzene 

N,2,6-Trichloro-p-benzoquinoneimine 

l,2,'4-Trichloro-5-nitrobenzene 

Trichlorophenylsilane 

a,a,a-Trichlorotoluene (Benzotrichloride) 

01,2,4-Trichlorotoluene 

a,2,4-(and a ,2,6)-Trichlorotoluene 

*2,'i,6-Trichloro-s-triazine (Cyanuric chloride) 

1,3,5-Triethylbenzene 

2-(Trifluoromethyl)phenothiazine 

a,a,a-Trifluoro-m-nitrotoluene 

a,a,a-Trifluoro-N-phenyl-m-toluidine (3-(Trifluoro- 
methyDdiphenylamlne) . 

a,a,a-Trifluorotoluene 

a,a,a-Trifluoro-m-taluidine 

a,a,a-Trifluoro-o-toluidine 

1,2,4-Trihydroxyanthraquinone 

2,3,5-Triiodobenzoic acid 

2,'i,5-Tri]iiethylaniline (Pseudocumidine) 

2,3,3-Trimethyl-3H-indole 

«l,3,3-Trimetl^l-ii^,'-indolineacetaldehyde 

*l,3,3-Trimethyl-2-methyleneindoline (Trimethyl base). 

Trimethylphenylanimonium chloride 

Trimethylphenylammonium iodide 

a,a',2-Trimethyl-l,4-plperazinediethanol 

2,4,6-Trimethylpyridine 

1,3,5-Trinitrobenzene 

2,A,6-Trinitrobenzenesulfonic acid 

2,<i,7-Trinitrofluoren-9-one 

Triphenylamine 

Triphenylmethanol 

Triphenylsulfonium chloride 

a, a',a"-Tris(dimethylamino)mesitol 

Tris(2-methyl-l-azirldinyl)phosphine oxide 

Trls(2-methyl-l-aziridinyl)phosphine sulfide 

m-Ureidoanillne 



LIL. 
ABB. 
GIV. 

ACS, ACY, 
EK, WAY. 
GAF, SDH. 
MON. 
MON. 

ACS, MON, 
NES, TEN, 
ACS, ACY, 
ICI. 
GAF. 
MON. 
CWL. 
CWL. 
CWL. 

ACS, DUP. 
ACS, DUP, 
AAP, ACY. 



DUP, GAF, RUC, TRC, UCC. 



SW, UPF. 

UPF. 

ATL. 



FST. 



ACS, 

EK. 

DUP. 

EKT. 

VPC. 

TRC. 

ACS. 

ACS, 

BUC, 



DUP. 



DUP. 



ACY, 

OAF. 

ACS, ACY, BUC, DUP, SDH. 
GAF. 



PPG. 
HK, SVT. 



UCC. 
VEL. 



NIL. 



EKT. 

EK. 

MLS. 

DVC, 

DOW, 

EK. 

PCW. 

DCC, 

HK, 

HN. 

BPC. 

ACY, GGY, 

DUP. 

SK. 

MEE. 

SK. 



HK. 

MEE. 

MEE. 

GAF. 

OAF. 

ACS. 

GAF. 

DUP, GAF, VPC. 

ACS, DUP, GAF, 

BKL. 

EK. 

WYN. 

KPT. 

EK. 

EK. 

EK. 

EK. 

EK. 

FIS. 

RH, 

ICO. 

ICO. 

ICI. 



VPC. 



TKL. 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by 

manufacturer, i 96 7 --Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



*7,7 '-Ureylenebis[<i-hydroxy-2-naphthalenesulfonic acid] 
(j acid urea) . 

Veratraldehyde (SjA-Dimethoxybenzaldehyde) 

Veratryl alcohol C3,4-Dlmethoxybenzyl alcohol) 

2-Vlnyloyclohexene 

-i-Vinylcyclohexene 

2,2 '-Vlnylenebis [benzimidazole] 

5-Vinyl-2-picoline (MVP) 

2-Vinylpyrldine 

4-Vinylpyridine 

*Violan throne (Dlbenzanthrone) 

Xanthene-9-carboxylic acid 

m-Xylene 

»o-Xylene 

«p. Xylene 

2,5-Xylenesulfonic acid 

2,<i-Xylenol 

2,6-Xylenol 

Xylenol crystals 

Xylenols : 

Low b.p 

Medium b.p 

Not classified as to b.p 

Xylidines; 

2,4-Xylidine (m-4-Xylidine) 

2,5-Xylidine (p-Xylidine) 

2,6-Xyiidine 

Original mixture 

4_(2,^-Xylylazo)-o-toluidine 

<l-(2,5-Xylylazo)-o-toluidine 

"♦-(Xylylazojxylidine 

4-(2,4-Xylylazo)-2,5-xylidine 

All other cyclic intermediates 



ACS, AGY, ATL, BKS, CMC, GAF, TRC, VPC. 

LIL, SLV. 

LIL. 

UCC. 

PLC. 

TRC. 

PLC. 

NEP, RIL. 

RIL. 

ATL, DUP, GAF, ICI, MAY, SDC, TRC. 

MAL. 

SNT, SOC. 

ASH, CCP, COR, CSD, CSO, CSP, DLH, ENJ, GRS, MON, 

SIN, SNT, SOC, TOG. 
CSD, ENJ, HGH, SIN, SNT, SOC, SOG. 
EK. 
EK. 
KPT. 
AGP. 

NPC, PIT. 
NPC, PIT, PRD. 
GE, PRD. 

ACS, DUP. 
ACS, DUP. 
DUP. 

ACS, DUP. 
ACS. 
ACY. 
GAF. 
ACS. 

ARA, CWN, DUP, EK, FG, FIS, HPC, ICC, LIL, MON, NRS, 
PAS, PCW, SW, X. 



^ See table 13B for data on medicinal grade of this item. 

^ Does not include manufacturers' identification codes for producers that report to the Division of Bituminous 
Goal, U.S. Bureau of Mines. These producers are listed in the U.S. Bureau of Mines, Mineral Industry Survey Cofee 
Producers in the United States in J 967, Feb. <i, 1969. 



DYES 
Dyes 



89 



TABLE 8B. --Bemenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1967 



[Dyes for which separate statistics are given in table 8A are marked below with an asterisk (*); dyes not so marked 
do not appear in table 8A because the reported data are accepted in confidence and may not be published. Manu- 
facturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not 
consent to his identification with the designated product] 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



ACID DYES 

»Acid yellow dyes: 

Acid Yellow 1 

Acid Yellow 2 

»Acid Yellow 3 

Acid Yellow i, 

»Acid Yellow 11 

Acid Yellow 14 

»Acid Yellow 17 

»Acid Yellow 23 

Acid Yellow 25 

Acid Yellow 29 

Acid Yellow 2A 

■»Acid Yellow 36 

Acid Yellow 38 

»Acid Yellow 40 

*Acid Yellow 42 

»Acid Yellow 44 

Acid Yellow 49 

»Acid Yellow 54 

Acid Yellow 59 

Acid Yellow 63 

Acid Yellow 65 

»Acid Yellow 73 

Acid Yellow 76 

Acid Yellow 79 

Acid Yellow 95 

»Acid Yellow 99 

Acid Yellow 114 

Acid Yellow 121 

»Acid Yellow 124 

Acid Yellow 127 

Acid Yellow 128 

Acid Yellow 129 

»Acid Yellow 151 

Acid Yellow 152 

Acid Yellow 159 

Acid Yellow 174 

Acid Yellow 175 

Other acid yellow dyes 

»Acid orange dyes: 

»Acld Orange 1 

Acid Orange 2 

Acid Orange 5 

Acid Orange 6 

*Acid Orange 7 

*Acid Orange 8 

»Acid Orange 10 

Acid Orange 12 

Acid Orange 19 

»Aoid Orange 24 

Acid Orange 28 

Acid Orange 31 

Acid Orange 34 

Acid Orange 45 

Acid Orange 50 

Acid Orange 51 

Acid Orange 52 

Acid Orange 56 

»Acid Orange 60 

Acid Orange 62 

Acid Orange 63 

Acid Orange 64 

Acid Orange 69 



ACY 
DUP 
ACS 
SDH 
CMC 
EDO 
ACS 



VPC. 



AAP, 
GAF 
GAF 
ACS 
ACS 
ACS 
ACS 
AAP 
AAP 
VPC 
ACS 
VPC 
AAP 
ALT 
ACS 
TRC 
VPC 
CMG 
ACS 
CMG 
GAF, 
ACS 
TRC 
TRC 
TRC 
ACY 
ACY 
ALT 
DUP 
DUP 
ACY 

ACS 
ACS 
ACY 
ACS 
AAP, 
ACS 
ACS 
ACS, 
GAF, 
ACS 
ACS 
AAP, 
ACY 
ACS 
AAP 
CMG 
ACS, 
GAF, 
BKS 
TRC 
GAF, 
ACS 
ACY 



ACY, 

DUP, 
TMC. 
ACY, 



ACS, 

TRC. 

DUP, 
GAF. 
ALT, 
ACY, 
ACS, 



DUP. 

VPC. 

ATL, BDO, BKS, CMG, DUP, GAF, PDC, SDH, TRC, 

ACY, GAF, MRX, SDH, TRC, VPC. 

TRC. 

ATL, DUP, GAF, TRC, VPC. 
GAF, VPC. 
GAF, VPC. 



ACY, BKS, CMG, GAF, TRC, VPC. 



TRC. 
GAF, 



CMG, 

TRC. 



MYC, SDH. 



GAF, TRC, VPC. 



BKS, DUP. 



BKS, DUP, TRC, VPC. 



TRC. 



ALT, 

ATL, 
TRC. 



ACS, 
ACY, 
ACY, 



ATL, CMG, DUP, GAF, TRC, VPC. 
BKS, GAF. 



ACY, ATL, BKS, CPC, GAF, PDC, TRC, YAW. 
ATL, BKS, DUP, GAF, TRC. 
DUP, GAF, PDC, TRC, VPC, YAW. 



ACY, DUP, GAF, TRC, YAW. 



TRC. 



TRC. 



CMG, 

TRC. 
ACY, 



DUP, GAF, TRC. 
DUP. 



90 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 8B. -- Bemenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer, 7567 --Continued 



Dye 



Manufacturers' Identification codes 
(according to list in table 22) 



ACID DYES--Continued 

»Acid orange dyes — Continued 

Acid Orange 72 

*Acid Orange 74 

Acid Orange 76 

Acid Orange 85 

Acid Orange 86 

Acid Orange ll'^ 

»Acid Orange 116 

Acid Orange 119 

Acid Orange 128 

Other acid orange dyes 

»Ac id red dyes ; 

»Acid Red 1 

»Acid Red i 

*Acid Red W 

Acid Red 17 

»Acid Red 18 

»Acid Red 26 

Acid Red 27 

Acid Red 32 

Acid Red 33 

Acid Red 34 

Acid Red 35 

»Acid Red 37 

Acid Red 42 

Acid Red 52 

Acid Red 57 

Acid Red 60 

Acid Red 66 

*Acid Red 73 

Acid Red 76 

Acid Red 80 

*Acid Red 85 

*Acid Red 87 

*Aoid Red 88 

■K-Acid Red 89 

Acid Red 94 

Acid Red 97 

*Acid Red 99 

Acid Red 100 

Acid Red 106 

Acid Red 113 

■»Acid Red 114 

Acid Red 115 

Acid Red 119 

Acid Red 133 

Acid Red 134 

*Acid Red 137 

Acid Red 138 

»Acid Red 151 

Acid Red 167 

Acid Red 175 - 

Acid Red 178 

Acid Red 179 

■»Acid Red 182 

Acid Red 183 

♦Acid Red 186 

Acid Red 190 

Acid Red 191 

Acid Red 194 

Acid Red 201 

Acid Red 207 

Acid Red 212 

Acid Red 213 

Acid Red 292 

Acid Red 299 

Acid Red 309 



GAF 
ACS 
ACS 
ACS 
ACS 
ACY 
ALT 
TRC 
DUP 
ALT 



AAP 



YAW. 



ATL 
ACS 
ACS 
ACS 
ACS 
ACS 
GAF 
ACS 
ACS 
AAP 
ACS 
GAF 
GAF 
TRC 
BKS 
AAP 
ACS 
ACS 
GAF 
ACS 



YAW. 



AMS 
ACS 
AAP 
NYC 
GAF 
ATL, 
VPC 
YAW 
DUP 
ACS 
ACS 
ACS 
GAF 
TRC 
ACS 
ALT 
AAP. 
ACS 
DUP, 
DUP, 
CMG 
ACS 
CMG 
BKS 
ACY 
TRC 
TRC 
TRC 
ACS 
TRC 
TRC 
ACY 
ALT 
TRC 



CMG, 
TRC. 

TRC. 



GAF, TRC. 



BKS, GAF, TRC. 



ATL, 



ACS, 



EDO, 
DUP, 
TRC, 
ACY, 
ACY, 



YAW. 



GAF. 
BKS, 



YAW. 

ACY, 

ICI. 
ACY, 



TRC, VPC. 

ACY, BDO, BKS, BL, DUP, GAF, SDH, TRC, VPC, 

CMG, DUP, GAF, PDC, TRC, VPC, YAW. 

GAF, PDC, YAW. 

YAW. 

ATL, BDO, DUP, GAF, TRC. 

ATL, CPC, GAF. 



CMG, DUP, GAF, TRC. 



NYC, 
ACY, 
BDO, 



ATL, DUP, GAF, PSC, TRC. 



ALT, ATL, BKS, CMG, DUP, GAF, PDC, TRC, VPC, 

SDH. 

ATL, DUP, GAF, SDH, TRC, YAW. 

GAF, VPC. 



BKS, CMG, TRC, VPC, YAW. 



ATL, 
GAF. 
ALT. 



ATL, 

ACY, 
TRC. 



ACY, 

TRC. 
CMG, 



DUP, GAF, PDC, TRC. 



DUP, GAF, TRC. 

ATL, BKS, DUP, TRC, YAW. 



BKS, CMG, DUP, GAF. 
GAF, VPC. 



GAF, TRC. 



DYES 



91 



TABLE 8B. ■ 



■ Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, 2967 --Continued 



Dye 



Manufacturers' Identification codes 
(according to list in table 22) 



ACID DYES— Continued 

»Acid red dyes — Continued 

Acid Red 337 

Other acid red dyes 

«Aoid violet dyes: 

»Acid Violet 1 

•Acid Violet 3 

Acid Violet 6 

»Acid Violet 7 

Acid Violet 11 

»Aoid Violet 12 

Acid Violet 17 

Acid Violet 29 

Acid Violet S-i 

Acid Violet 41 

Acid Violet 43 

»Acid Violet <V9 

Acid Violet 56 

Acid Violet 58 

Acid Violet 76 

Other acid violet dyes 

*Acid blue dyes: 

Acid Blue 1 

wAcid Blue 7 

»Acid Blue 9 

Acid Blue 10 

Acid Blue 15 

Acid Blue 20 

Acid Blue 22 

Acid Blue 23 

»Acid Blue 25 

Acid Blue 27 

Acid Blue 29 

Acid Blue 34 

»Acid Blue 40 

»Acid Blue 41 

»Acid Blue 43 

»Acid Blue 45 

Acid Blue 47 

Acid Blue 48 

Acid Blue 55 

Acid Blue 58 

Acid Blue 59 

*Acid Blue 62 

Acid Blue 63 

Acid Blue 67 

Acid Blue 69 

Acid Blue 74 

»Acid Blue 78 

Acid Blue 80 

Acid Blue 81 

Acid Blue 83 

Acid Blue 89 

»Acid Blue 90 

Acid Blue 92 

Acid Blue 93 

Acid Blue 102 

Acid Blue 104 

»Acld Blue 113 

Acid Blue 118 

Acid Blue 120 

Acid Blue 122 

Acid Blue 145 

»Aold Blue 158 and 158A 

Acid Blue 165 

Acid Blue 179 

Acid Blue 198 

Acid Blue 203 

Acid Blue 230 

Acid Blue 231- 



DUP 
ACY 

ACS 
ACS 
ACS 
AAP 
OAF, 
BDO 
DUP 
HSH 
ICI 
CMG 
HSH 
ACS 
CMG 
GAF 
ACS, 
DUP, 

ACS 
ACS 
ACS 
ACS 
DUP 
ACS 
NYC 
ACS 
ACS 
CMG 
YAW 
ACS 
ACS 
ACS 
ACS 
ACS 
ICI 
HSC 
ACS 
DUP, 
ACS 
ACS 
ACS 
CMG 
DUP 
ACS 
ACS 
ACS 
ICI 
GAF, 
ACS 
ACS 
ACS 
ACY 
ACS 
ACS 
ACS 
ACS 
ACS 
DUP, 
ACS 
ACS 
DUP, 
GAF, 
VPC 
VPC 

DUP; 

TRC 



ALT, ATL, BKS, DUP, GAF, TRC, VPC. 

BDO, CMG, GAF. 

ACY, DUP, TRC, YAW. 

ACS, BDO, CMG, DUP, GAF, TRC, VPC. 

CMG, DUP, GAF. 

GAF, SDH. 



ICI. 

ACY, TRC. 
GAF. 



GAF, TRC. 

GAF, SDH. 
ACY, GAF, SDH. 
GAF, SDH, VPC. 

GAF. 
ACY. 

TRC. 

ATL, BDO, CMG, DUP, GAF, TRC, VPC. 

GAF. 



ALT, ATL, GAF, ICI, TRC. 

BDO, CMG, GAF. 

ACY, GAF, TRC. 

ACY, CMG, DUP, GAF, TRC, VPC. 



ALT, BDO, GAF, VPC. 
CMG. 

GAF. 

DUP. 

DUP, GAF, ICI, TRC. 

TRC. 



GAF, TRC. 

YAW. 

HSC. 

TRC. 

GAF. 

ALT, ATL, BDO, BKS, CMG, DUP, GTIF, TRC. 

BKS, GAF. 

GAF. 

DUP. 

ACY, BDO, BKS, GAF, TRC, VPC. 



TRC. 



92 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 8B. -- Bemenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer, 7567-- Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



ACID DYES--Continued 

»Acid blue dyes — Continued 

Acid Blue 255 

Other acid blue dyes 

»Acid green dyes: 

Acid Green 1 

»Acid Green 3 

Acid Green 5 

»Acid Green 9 

Acid Green 12 

»Acid Green 16 

■»Aoid Green 20 

Acid Green 22 

«Acid Green 25 

Acid Green 35 

Acid Green 41 

Acid Green 44 

Acid Green 50 

Acid Green 58 

Acid Green 70 

Other acid green dyes 

*Acid brown dyes: 

Acid Brown 1 

Acid Brown 6 

*Acid Brown 14 

Acid Brown 19 

Acid Brown 22 

Acid Brown 28 

Acid Brown 29 

Acid Brown 31 

Acid Brown 45 

Acid Brown 96 

Acid Brown 97 

Acid Brown 98 

Acid Brown 152 

Acid Brown 158 

Acid Brown 223 

Acid Brown 243 

Other acid brown dyes 

*Acid black dyes: 

»Acid Black 1 

Acid Black 2 

Acid Black 12 

Acid Black 16 

»Acid Black 24 

Acid Black 26, 26A, and 263 

Acid Black 29 

Acid Black 41 

»Acid Black 48 

*Acid Black 52 

Acid Black 53 

Acid Black 58 

»Acid Black 60 

Acid Black 92 

»Acid Black 107 

Acid Black 108 

Acid Black 138 

Other acid black dyes 

AZOIC DYES AND CCMPONENTS 

Azoic Compositions 

Azoic yellow dyes: 

»Azoic Yellow 1 

Azoic Yellow 2 

Azoic orange dyes : 

*A2oic Orange 3 

Azoic Orange 4 

Other azoic orange dyes 



DUP 
ACY 

ACS 
ACS 
GAF 
ACS 
ACS 
ACS 
ACS 
GAF 
ACS 
TRC 
ICI 
VPC 
ACY 
TRC 
TRC 
ALT 

GAF, 
GAF, 
AAP 
TRC 
DUP 
TRC 
DUP 
GAF 
TRC 
ACY 
ACY 
ACY 
GAF 
GAF 
GAF 
GAF 
ALT 



AAP 



ACS 
ACS 
ACS 
ACS 
ACS 
ACS 
ACS 
ACY 
ACS 
ACS 
TRC 
EDO 
ACY 
ACS 
GAF 
VPC 
DUP 



ALT, ATL, CMG, DUP, GAF, TRC, VPC. 

ACY. 

ACY, DUP, GAF, TRC. 

ACY, DUP, GAF. 

GAF, TRC. 

DUP, GAF, SDH, TRC. 

ATL, EDO, DUP, GAF, PDC, TRC. 

ATL, CMG, GAF, HSH, ICI, TRC, VPC. 

VPC. 

GAF. 



VPC. 



ACS, ACY, DUP, GAF, TRC, YAW. 



TRC. 



DUP, GAF, VPC. 



ACS, ACY, ATL, BDO, BKS, DUP, FAB, GAF, HSH, PDC, 



TRC, YAW. 



ACY. 



CMG, DUP, GAF. 

DUP, TRC. 
GAF. 

CMG, DUP, GAF, ICI, TRC. 

BKS, GAF, TRC. 



CMG, TRC. 
ALT, GAF, TRC. 

GAF, PDC. 



ALL, ATL, BUC. 
BUC, GAF, X. 

ALL, ATL, BUC, GAF, x. 

GAF. 

VPC. 



DYES 



93 



TABLE 8B. -- Bemenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer, i 567 --Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



AZOIC DYES AND CCMPONENTS— Continued 

Azote Compositions—Continued 

»Azoio red dyes : 

»Azoic Red 1 

•Azoic Red 2 

»Azoio Red 6 

Azoic Red 13 

Azoic Red 15 

Azoic Red 16 

Azoic Reef 73 

Azoic Red 7A. 

Crther azoic red dyes 

Azoic violet dyes: Azoic Violet 1 

Azoic blue dyes; 

Azoic Blue 2 

»Azoic Blue 3 

Azoic Blue <» 

Azoic Blue 6 

Azoic Blue 7 

Other azoic blue dyes 

Azoic green dyes : 

Azoic Green 1 

Other azoic green dyes 

Azoic brown dyes: 

»Azoic Brown 9 

Azoic Brown 26 

Other azoic brown dyes 

*Azoio black dyes: 

Azoic Black 1 

Azoic Black A 

Azoic Black 15 

Other azoic black dyes 

Other azoic compositions 



Azoic Diazo Component s , Bases 
(Fast Color Bases} 

Component 2, base 

Component 3, base 

Component "i, base 

Component 5, base 

Component 8, base 

Component 9, base 

Component 10, base 

Component 11, base 

Component 12, base 

Component 13, base 

Component 1^, base 

Component 20, base 

Component 27, base 

Component 28, base 

Component 32, base 

Component 3^, base 

Component 41, base 

Component A2, base 

Component 44, base 

Component 48, base 

diazo components, bases 

Azoic Diazo Components, Salts 
(Fast Color Sal ts) 



Azoic 


Diazo 


Azoic 


Diazo 


♦Azoic 


Diazo 


*Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


»Azoic 


Diazo 


Azoic 


Diazo 


»Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


♦Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Other 


azoic 



♦Azoic Diazo Component 1, 
Azoic Diazo Component 2, 
♦Azoic Diazo Component 3, 
Azoic Diazo Component 4, 
♦Azoic Diazo Component 5, 
♦Azoic Diazo Component 6, 
♦Azoic Diazo Component 8, 
♦Azoic Diazo Component 9, 



ALL, 


ATL, 


BUC, 


GAF, 


HST, X 


ALL, 


ATL, 


BUC, 


GAF, 


X. 


ALL, 


ATL, 


BUC, 


GAF, 


X. 


GAT. 










GAF. 










ATL. 










GAF. 










GAF. 










ALL. 










ATL, 


BUC, 


GAF. 






ATL, 


GAF. 








ALL, 


ATL, 


BUC, 


GAF, 


HST, X 


GAF. 










ATL, 


GAF. 








GAF. 










ALL. 










ATL, 


GAF, 


VPC. 






VPC. 










ALL, 


BUC, 


GAF, 


HST, 


VPC, X 


GAF. 










ATL, 


GAF, 


VPC. 






GAF, 


HST. 








ATL, 


BUC, 


GAF. 






GAF. 










ALL, 


GAF, 


PCW, 


VPC. 





ATL, 


BUC. 






BUC. 








ALL, 


BUC, 


GAF, 


SDH. 


DUP, 


GAF, 


SDH. 




DUP, 


SDH. 






AAP, 


DUP. 






ALL, 


BUC, 


GAF. 




PCW. 








BUC, 


PCW, 


SDH. 




ALL, 


BUC, 


SDH. 




AAP. 








ALL, 


GAF. 






ALL. 








ALL, 


BUC. 






AAP, 


ATL, 


BUC, 


DUP, PCW, SDH 


GAF. 








GAF. 








ALL, 


PCW. 






AAP, 


BUC. 






CWN, 


DUP, 


GAF. 




GAF. 









salt- 
salt- 
salt- 
salt- 
salt- 
salt- 
salt- 
salt- 



AAP, ALL, GAF, SDH. 

GAF. 

AAP, ALL, BUC, GAF, SDH. 

ALL. 

AAP, ALL, BUC, GAF, SDH. 

AAP, BUC, GAF, SDH. 

AAP, ALL, BUC, GAF. 

AAP, ALL, BUC, GAF, SDH, VPC. 



94 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 8B. 



. Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, i567 --Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



»Azoic 


Diazo 


»A2oic 


Diazo 


*Azoic 


Diazo 


*Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


•Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


Azoic 


Diazo 


*Azoic 


Diazo 


*Azoic 


Diazo 


»Azoio 


Diazo 


Azoic 


Diazo 


Other 


azoic 



*Azoic 

»Azolc 

*Azoic 

*Azoic 

*Azoic 

Azoic 

Azoic 

Azoic 

Azoic 

Azoic 

»Azoic 

Azoic 

Azoic 

*Azoic 

*Azoic 

•Azoic 

•Azoic 

•Azoic 

Azoic 

Azoic 

•Azoic 

Azoic 

Azoic 

Azoic 

•Azoic 

Other 



AZOIC DYES AND CCMPONENTS--Continued 

Azoic Diazo Components, Salts 
(Fast Color Sal ts)--Cont.inued 

Component 10, salt 

Component 11, salt 

Component 12, salt 

Component 13, salt 

Component 14, salt 

Component 20, salt 

Component 28, salt 

Component 32, salt 

Component 34, salt 

Component 35, salt 

Component 36, salt 

Component 37, salt 

Component 41, salt 

Component 42, salt 

Component 44, salt 

Component 48, salt 

Component 49, salt 

Component 51, salt 

diazo components, salts 



Azoic Coupling Components 
(Naphthol AS and Derivatives) 

Coupling Component 2 

Coupling Component 3 

Coupling Component 4 

Coupling Component 5 

Coupling Component 7 

Coupling Component 8 

Coupling Component 10 

Coupling Component 11 

Coupling Component 12 

Coupling Component 13 

Coupling Component 14 

Coupling Component 15 

Coupling Component 16 

Coupling Component 17 

Coupling Component 18 

Coupling Component 19 

Coupling Component 20 

Coupling Component 21 

Coupling Component 23 

Coupling Component 24 

Coupling Component 29 

Coupling Component 34 

Coupling Component 35 

Coupling Component 36 

Coupling Component 43 

azoic coupling components 

BASIC DYES 



ALL, BUC, GAF, SDH. 



AAP, 
AAP, 
AAP, 
AAP. 
ALL, 
ALL, 
ALL, 
ALL, 
GAF. 
AAP, 
GAF. 
GAF. 
ALL, 
ALL, 
AAP, 
AAP, 
GAF. 
ALL, 



ALL, 
ALL, 
ALL, 

GAF. 
BUC, 
SDH. 
GAF. 

GAF. 



GAF. 
BUC, 
GAF, 

ALL, 



GAF. 
BUC, 
BUC, 



GAF, 
GAF, 



SDH. 
SDH, 



VPC. 



GAF, SDH, VPC. 



GAF. 
SDH. 
BUC, 



GAF, SDH. 



GAF, SDH. 



•Basic yellow dyes: 

Basic Yellow 1 

•Basic Yellow 2 

•Basic Yellow 11 

•Basic Yellow 13 

Basic Yellow 15 

Basic Yellow 21 

Basic Yellow 24 

Basic Yellow 25 

Basic Yellow 26 

Basic Yellow 28 

Basic Yellow 29 

Basic Yellow 31 

Basic Yellow 37 

Basic Yellow 41 

Other basic yellow dyes- 



ACY, 


ATL, 


BUC, 


DUP, 


GAF, PCW 


BUC, 


GAF, 


PCW. 






ATL, 


BUC, 


GAF, 


PCW. 




AAP, 


GAF, 


PCW, 


SDH. 




AAP, 


BUC, 


PCW. 






ATL, 


BUC, 


GAF, 


PCW. 




ATL, 


PCW. 








BUC, 


GAF, 


PCW. 






ATL, 


BUC, 


GAF, 


PCW. 




GAF. 










ACS, 


ATL, 


BUC, 


GAF, 


PCW. 


BUC, 


GAF. 








BUC, 


GAF. 








ACY, 


ATL, 


BUC, 


PCW. 




ACY, 


ATL, 


BUC, 


GAF, 


PCW. 


BUC, 


GAF, 


PCW. 






ATL, 


BUC, 


DUP, 


GAF, 


PCW. 


ATL, 


BUC, 


PCW. 






GAF, 


PCW. 








GAF, 


PCW. 








BUC, 


GAF, 


PCW. 






ATL, 


BUC, 


GAF, 


PCW. 




GAF, 


PCW. 








GAF. 










ATL, 


BUC, 


GAF. 






ATL, 


GAF. 









DUP. 
ACS, 
ACS, 
ACS, 
DUP. 
VPC. 
BAS. 
BAS. 
ACY. 
VPC. 
VPC. 
DUP. 
ACY, 
ACY. 
DUP, 



ACY, DUP. 

ACY, DUP, GAF, VPC. 

DUP, GAF, VPC. 



DUP. 
VPC. 



DYES 



95 



TABLE 8B. — Bemenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer, i 967 --Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



BASIC DYES--Contlnued 

»Baslc orange dyes: 

»Basic Orange 1 

»Basic Orange 2 

Basic Orange 10 

Basic Orange 14 

Basic Orange 17 

»Basic Orange 21 

Basic Orange 22 

Basic Orange 2<i 

Basic Orange 25 

Basic Orange 26 

Basic Orange 27 

Basic Orange 31 

*Basic red dyes : 

Basic Red 1 

Basic Red 2- 

■Kfiasic Red 9 

Basic Red 12 

Basic Red 13 

*Basic Red 14 

Basic Red 15 

Basic Red 16 

Basic Red 17 

Basic Red 18 

Basic Red 19 

Basic Red 22 

Basic Red 29 

Basic Red 30 

Other basic red dyes 

*Baslc violet dyes: 

»Basic Violet 1 

Basic Violet 2 

Basic Violet 3 

«Basic Violet 4 

Basic Violet 7 

«Basio Violet 10 

Basic Violet 13 

Basic Violet 14 

Basic Violet 15 

»Basic Violet 16 

Basic Violet 18 

Basic Violet 24 

»Basic blue dyes; 

»Basic Blue 1 

Basic Blue 2 

Basic Blue 3 

Basic Blue 4 

»Basic Blue 5 

Basic Blue 6 

Basic Blue 7 

»Basic Blue 9 

Basic Blue 11 

Basic Blue 21 

Basic Blue 22 

»Basic Blue 26 

Basic Blue 35 

Basic Blue 38 

Basic Blue 39 

Basic Blue 41 

Basic Blue 45 

Basic Blue 47 

Basic Blue 54 

Basic Blue 76 

Other basic blue dyes 

Basic green dyes: 

»Basic Green 1 

Basic Green 3 

*Basic Green 4 

Basic Green 5 

Basic Green 7 



ACS 


ACY, 


DUP, 


GAF, 


TRC 


ACS 


ACY, 


DSC, 


DUP, 


GAF 


VPC 










GAF 










ACS 










ACS 


DUP, 


GAF, 


VPC. 




ACS 


GAF. 








DUP 










DUP 










DUP 










VPC 










ACY 










BAS 


DUP, 


GAF. 






ACS 


DUP. 








ACY 


DSC, 


HSC. 






ACY 


DUP. 








ACS 


GAF. 








ACS 


ACY, 


DUP, 


GAF, 


VPC 


DUP 


GAF. 








DUP 










DUP 










DUP 


VPC. 








DUP 










ACY 


TRC. 








BAS 










ACY 










DUP 


GAF, 


VPC. 






ACS 


ACY, 


DSC. 






BKS 


DSC, 


NYC. 






ACS 


DSC, 


DUP, 


GAF, 


SDH 


ACS 


DSC, 


DUP, 


GAF. 




GAF 










ACY 


DUP, 


GAF. 






DSC 










ACY 


DSC. 








DUP 










DUP 


GAF, 


VPC. 






ACY 










DUP 










DSC 


GAF, 


SDH, 


VPC. 




DSC 










GAF 










DUP 










DSC 


GAF, 


SDH, 


VPC. 




ACS 


ACY. 








DSC 


DUP, 


SDH. 






ACS 


ACY, 


SDH. 






DSC 


SDH. 








DUP 










ACS 


DUP. 








ACS 


DSC, 


DUP, 


SDH. 




DUP 










ACY 


DUP. 








DUP 










TRC 










VPC 










VPC 










ACY 


BAS. 








ACY 










DUP 


CAF, 


VPC. 






ACS 


ACY, 


DSC, 


DUP, 


SDH 


DUP 










ACS 


ACY, 


DSC, 


DUP, 


SDH 


ACY 










DSC 











96 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 8B. 



- Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer, iS67 --Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



BASIC DYES— Continued 

Basic brown dyes: 

*Basic Brown 1 

Basic Brown 2 

»Basic Brown 4 

Basic Black dyes: 

Basic Black 3 

Other basic black dyes 

DIRECT DYES 

*Direct yellow dyes; 

*Direct Yellow i. 

*Direcl Yellow 5 

^Direct Yellow 6 

Direct Yellow 7 

Direct Yellow 8 

Direct Yellow 9 

*Direct Yellow 11 

*Direct Yellow 12 

Direct Yellow 20 

Direct Yellow 23 

»Direct Yellow 26 

Direct Yellow 27 

»Direct Yellow 28 

Direct Yellow 29 

Direct Yellow 39 

♦Direct Yellow <W 

Direct Yellow "49 

»Direct Yellow 50 

Direct Yellow 59 

Direct Yellow 8A 

Direct Yellow 103 

♦Direct Yellow 105 

♦Direct Yellow 106 

Direct Yellow 107 

Direct Yellow 11*1 

Direct Yellow 117 

Direct Yellow 118 

Direct Yellow 119 

Direct Yellow 120 

Direct Yellow 121 

Direct Yellow 123 

Direct Yellow 125 

Direct Yellow 128 

Other direct yellow dyes 

♦Direct orange dyes: 

♦Direct Orange 1 

Direct Orange 6 

♦Direct Orange 8 

Direct Orange 10 

Direct Orange 11 

♦Direct Orange 15 

♦Direct Orange 26 

♦Direct Orange 29 

♦Direct Orange 3A. 

♦Direct Orange 37 

♦Direct Orange 39 

Direct Orange <i2 

Direct Orange ■48 

Direct Orange 55 

Direct Orange 59 

Direct Orange 61 

Direct Orange 67 

Direct Orange 70 

♦Direct Orange 72 

♦Direct Orange 73 

Direct Orange 7<i 

Direct Orange 76 

Direct Orange 78 

Direct Orange 79 



ACS, ACY, DUP, OAF, TRC. 

OAF. 

ACS, ACY, DSC, DUP, GAF, TRC. 

GAF. 

DSC, DUP, VPC. 



ACS 


ACY, 


DUP, 


GAF, 


TRC. 






ACS 


ACY, 


GAF. 










ACS 


ACY, 


ATL, 


DUP, 


GAF, 


TRC. 




ATL 














ACS 


GAF. 












DUP 














ACS 


ACY, 


BKS, 


DUP, 


GAF, 


TRC. 




ACS 


ATL, 


BKS, 


DUP, 


FAB, 


GAF, 


TRC 


TRC 














DUP 














ALT 


BKS, 


DUP. 










GAF 














ACS 


ATL, 


DUP, 


GAF, 


TRC. 






ATL 


DUP, 


GAF. 










TRC 














ACS 


ATL, 


BKS, 


DUP, 


FAB, 


GAF, 


TRC, VPC 


VPC 














ACS 


ATL, 


BKS, 


DUP, 


FAB, 


GAF, 


TRC, VPC 


ACS 


ATL, 


DUP. 










BKS 


TRC. 












ACS 














ALT 


BKS, 


GAF, 


TRC. 








ALT 


BKS, 


FAB, 


GAF, 


TRC. 






GAF 














ACY 














TRC 














TRC 














DUP 














BKS 














TRC 














DUP 














ACY 














DUP 














AAP 


ALT, 


ATL, 


DUP, 


GAF, 


TRC, 


VPC. 


AAP 


ATL, 


BDO, 


CMG, 


VPC. 






ACS 


ATL, 


DUP, 


GAF, 


TRC. 






AAP 


ACS. 












GAF 














ACS 


ACY, 


DUP, 


GAF, 


TRC. 






ACS 
ATL 


ATL, 
BKS, 


DUP, 
FAB, 


GAF, 
TRC. 


TRC. 






ACS 


ATL, 


CMG, 


DUP, 


GAF. 






ACY 


CMG, 


DUP, 


GAF, 


TRC. 






ACY 


ALT, 


ATL, 


BKS, 


DUP, 


GAF. 




ATL 
DUP 
DUP 
DUP 


GAF. 












TRC 
ACS 


VPC. 












TRC 














ACS 


ALT, 


ATL, 


BKS, 


FAB, 


TRC, 


VPC. 


DUP 
DUP 


GAF, 


TRC, 


VPC. 








DUP 
VPC 
DUP 















DYES 



97 



TABLE 8B. --Benzenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer, i96?'--Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



DIRECT DYES- -Continued 

»Direct orange dyes — Continued 

Direct Orange 80 

»Direot Orange 81 

Direct Orange 83 

Direct Orange 88 

»Direct Orange 102 

Direct Orange 110 

Other direct orange dyes 

»Direct red dyes: 

^Direct Red 1 

»Direct Red 2 

»Direct Red ^ 

Direct Red 5 

Direct Red 7 

♦Direct Red 10 

♦Direct Red 13 

♦Direct Red 16 

Direct Red 20 

♦Direct Red 23 

♦Direct Red 2A 

♦Direct Red 26 

♦Direct Red 28 

♦Direct Red 31 

Direct Red 32 

♦Direct Red 37 

♦Direct Red 39 

Direct Red -45 

Direct Red i.b 

Direct Red 62 

♦Direct Red 72 

Direct Red 73 

♦Direct Red 75 

Direct Red 76 

♦Direct Red 79 

♦Direct Red 80 

♦Direct Red 81 

♦Direct Red 83 

Direct Red 84 

Direct Red 95 

Direct Red 111 

Direct Red 117 

♦Direct Red 122 

Direct Red 123 

Direct Red 139 

♦Direct Red 14-9 

Direct Red 152 

Direct Red 153 

Direct Red 155 

Direct Red 209 

Direct Red 212 

Other direct red dyes 

♦Direct violet dyes: 

Direct Violet 1 

Direct Violet 7 

♦Direct Violet 9 

Direct Violet 14 

Direct Violet 22 

Direct Violet 47 

Direct Violet 48 

Direct Violet 49 

Direct Violet 51 

Direct Violet 62 

Direct Violet 66 

Direct Violet 67 

Other direct violet dyes 

♦Direct blue dyes: 

♦Direct Blue 1 



DUP, VPC. 

ACS, DUP, 
GAT. 
DUP. 

ACS, ACY, 
TRC. 

ALT, ATL, 

AAP, ACS, 

ACS, ATL, 

ACS, ATL, 
ACS. 
ATL. 

AAP, ACS, 

AAP, ACS, 

ACS, ATL, 

ACS, OAF. 

ACS, ATL, 

ATL, BKS, 

AAP, ACS, 

ACS, ATL, 

ACS, ATL, 

ACS, DUP. 

ACS, ACY, 

ACS, ATL, 
ATL. 
ATL. 

ATL, TRC. 

ACS, OAF, 

ACS, DUP. 

ACS, CMC, 

ACS, GAF. 

ATL, BKS, 

AAP, ACS, 

VPC. 

AAP, ACS, 

YAW. 

ACS, ALT, 

BKS, GAF. 
VPC. 
GAF. 
DUP. 

CMC, TRC, 
GAF. 
VPC. 

ATL, CMG, 

CMC, DUP. 

AAP, ATL. 
GAF. 
TRC. 
VPC. 

ALT, ATL, 

AAP, ACS, 

ACS, GAF. 

ACS, ATL, 

ACS, ATL. 
DUP. 

DUP, GAF. 

ACS, DUP. 
ACS. 

ACS, DUP. 
ACY. 

ATL, TRC. 
DUP. 
ALT. 

AAP, ACS, 
YAW. 



GAF, VPC. 

DUP, GAF. 

DUP, VPC. 

ATL, DUP, GAF, TRC, YAW. 
BKS, DUP, TRC. 
TRC, VPC. 



ACY, ATL. 

ATL, DUP, GAF, TRC, YAW. 

GAF, TRC. 

BKS, CMG, DUP, GAF, TRC. 

FAB, TRC, VPC. 

ATL, BKS, DUP, GAF, TRC, VPC. 

DUP, TRC. 

DUP, GAF. 

ATL, GAF, TRC, YAW. 
GAF, TRC, YAW. 



TRC. 

DUP, GAF. 

CKKJ, TRC, VPC. 

ATL, EDO, BKS, BL, CMG, DUP, FAB, SDH, TRC, 

ACY, ATL, BDO, BKS, BL, DUP, GAF, TRC, VPC, 

ATL, BKS, BL, CMG, DUP, GAF, TRC, VPC. 



VPC. 
DUP, GAF. 



BL, GAF, TRC. 

ATL, DUP. 

BKS, DUP, GAF, TRC. 



ACY, ATL, BKS, BL, DUP, FAB, GAF, TRC, VPC, 



98 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 8B, 



• Benzenoid dyes for which U.S. production or sales were reported, identified by 
manufacturer , 1967 — Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



DIRECT DYES--Contlnued 

♦Direct blue dyes --Continued 

♦Direct Blue 2 

♦Direct Blue 6 

♦Direct Blue 8 

Direct Blue !<« 

♦Direct Blue 15 

Direct Blue 18 

♦Direct Blue 22 

♦Direct Blue 2A 

♦Direct Blue 25 

Direct Blue 26 

Direct Blue 27 

♦Direct Blue 67 

♦Direct Blue 71 

Direct Blue 7<4 

Direct Blue 75 

♦Direct Blue 76 

♦Direct Blue 78 

♦Direct Blue 80 

♦Direct Blue 86 

Direct Blue 87 

Direct Blue 91 

♦Direct Blue 98 

Direct Blue 100 

Direct Blue 104 

♦Direct Blue 120 and 120A 

♦Direct Blue 126 

Direct Blue 133--- 

Direct Blue 136 

Direct Blue l<i3 

♦Direct Blue 151 

Direct Blue 160 

Direct Blue 189-- 

Direct Blue 191 

Direct Blue 199 

♦Direct Blue 218 

Direct Blue 22<i 

Direct Blue 238 

Other direct blue dyes 

♦Direct green dyes: 

♦Direct Green 1 

♦Direct Green 6 

♦Direct Green 8 

Direct Green 12 

Direct Green 15 

Direct Green 26 

Direct Green 27 

Direct Green 28 

Direct Green 38 

Direct Green 39 

Direct Green 41 

Direct Green 45 

Direct Green 47 

Direct Green 51 

Direct Green 69 

Other direct green dyes 

♦Direct brown dyes: 

♦Direct Brown 1 

♦Direct Brown lA 

♦Direct Brown 2 

♦Direct Brown 6 

Direct Brown 25 

Direct Brown 27 

♦Direct Brown 31 

Direct Brown 32 

Direct Brown 33 

Direct Brown 40 

Direct Brown 44 

Direct Brown 48 



AAP 
AAP 
ACS 
ACS 
DUP 
TRC 
TRC 
TRC 
DUP 
GAP 
DUP 
VPC 
DUP 
TRC 
TRC 
ACY 

ACY 
GAP 

AAP; 

ACS 
DUP, 
GAF 
AAP 
GAF. 
DUP, 
AAP 
GAF 
AAP 



ACS, ATL, BKS, BL, DUP, FAB, GAF, TRC, VPC, YAW. 

ACS, ACY, ATL, BKS, BL, DUP, GAF, TRC, YAW. 

ACS, ATL, DUP, GAF, YAW. 

ATL, BKS, TRC. 

ATL, DUP. 

ATL, CMG, DUP. 

ATL, BKS, YAW. 

ATL, DUP, GAF, TRC, YAW. 



ATL, DUP, TRC. 
DUP, GAF, TRC. 



AAP 

AAP 

AAP 

ACS 

ACS 

YAW 

ACS 

ACS 

ACS 

ATL 

DUP 

ACS 

ACS 

DUP 

TRC 

ACS, ALT, ATL, BKS, BL, DUP, FAB, GAF, TRC, VPC. 

ACS, ATL, CMG, DUP, GAF, TRC. 

ACS, ALT, ATL, BKS, BL, DUP, FAB, GAF, TRC. 

AAP, ACS, ACY, ALT, ATL, BKS, DUP, FAB, GAF, ICC, ICI, 

SDH, IMS, TRC, VPC. 
ICI. 
TRC 
ALT 
ALT 
DUP 
BKS 
ACS 
GAF 
GAF 
DUP 
ACS 
TRC 
BKS 
AAP 
GAF 
ACS 
ALT 
ACY 
ALT 



ATL, TRC, VPC. 
BKS. 

DUP, GAF, TRC. 

BL, DUP, GAF, TRC, VPC. 



ATL, TRC. 



TRC. 
ALT, GAF. 



BKS, 

ATL. 



DUP, GAF, TRC. 



BL, DUP, GAF. 

ACS, ACY, ATL, BKS, DUP, GAF, TRC, YAW. 

ACS, BKS, DUP, GAF, TRC, YAW. 

ATL, TRC. 

DUP, TRC. 



GAF. 



GAF. 



ALT, ATL, BL, DUP. 

ATL, BKS, DUP. 

TRC, YAW. 

ACS, ACY, ATL, BKS, BL, DUP, GAF, TRC, YAW. 

DUP, FAB, GAF, TRC. 



ACS, ATL, DUP, GAF, TRC, YAW. 



YAW. 



DYES 



99 



TABLE 8B. — Benzenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer , i 567 --Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



DIRECT DYES— Continued 

»Direct brown dyes — Continued 

Direct Brovm 59 

«Direct Brown lA 

»Direct Brown 95 

Direct Brown 105 

Direct Brown 106 

*Direct Brown 111 

Direct Brown 112 

Direct Brown 125 

»Direct Brown 154 

Other direct brown dyes 

•Direct black dyes; 

•Direct Black 4 

Direct Black 8 

•Direct Black 9 

Direct Black 17 

•Direct Black 19 

•Direct Black 22 

Direct Black 36 

Direct Black 37 

•Direct Black 38 

Direct Black <i4 

Direct Black \5 

•Direct Black 51 

Direct Black 55 

Direct Black 56 

Direct Black 61 

Direct Black 67 

Direct Black 71 

Direct Black 75 

Direct Black 78 

•Direct Black 80 

Direct Black 109 

Direct Black 131 

Direct Black 190 

Other direct black dyes 

DISPERSE DYES 

•Disperse yellow dyes: 

Disperse Yellow 1 

Disperse Yellow 2 

•Disperse Yellow 3 

•Disperse Yellow 5 

•Disperse Yellow 8 

•Disperse Yellow 23 

Disperse Yellow 31 

Disperse Yellow 32 

•Disperse Yellow 33 

•Disperse Yellow 3^ 

Disperse Yellow 37 

•Disperse Yellow AZ 

Disperse Yellow 50 

•Disperse Yellow 5-4 

Disperse Yellow 67 

Other disperse yellow dyes 

•Disperse orange dyes ; 

•Disperse Orange 3 

•Disperse Orange 5 

Disperse Orange 16 

•Disperse Orange 17 

Disperse Orange 21 

•Disperse Orange 25 

Disperse Orange 26 

Disperse Orange 28 

Disperse Orange 29 

Disperse Orange 30 

Disperse Orange 38 

Disperse Orange 41 



ACY. 

AAP, ACS, 
AAP, ACS, 
DUP. 

ACS, GAF. 
DUP, GAF, 
ATL. 
GAF. 

ACS, DUP, 
ACS, AIT, 

ACS, ATL, 
TRC, YAW. 
ACS, BKS, 
GAF. 

ATL, BKS, 
AAP, ACS, 

YAW. 
AAP, ATL. 
AAP, DUP. 
AAP, ACS, 
TRC. 
TRC. 

AAP, ACS, 
DUP. 

ACS, TRC. 
TRC. 
DUP. 

ATL, VPC. 
GAF. 

ACS, BKS, 
AAP, ACS, 
GAF. 
ACS. 
BKS. 
ACY, ALT, 



DUP. 

AIT, ATL, BKS, DUP, GAF, TRC, YAW. 

TRC, VPC. 

FAB, GAF, TRC, YAW. 
ATL, DUP, VPC. 

BKS, DUP, GAF, TRC, YAW.' 

DUP, GAF. 

GAF, TRC. 

ALT, ATL, BKS, CMG, DUP, GAF, TRC, VPC, 

ACY, ATL, BKS, BL, DUP, FAB, GAF, TRC, YAW. 
ATL, DUP, GAF. 

DUP. 

ATL, BKS, BL, FAB, TRC, VPC, YAW. 

ATL, BL, YAW. 



DUP, 
DUP. 
AAP, 
AAP, 
DUP, 
AAP, 
GAF. 
DUP. 
AAP, 
AAP, 
ICC. 
AAP, 
TRC. 
AAP, 
DUP. 
BKS, 

AAP, 
AAP, 
AAP. 
AAP, 
TRC. 
DUP, 
DUP. 
AAP. 
AAP. 
TRC. 
TRC. 
DUP. 



GAF. 

ACS, BKS, BL, DUP, EKT, GAF, HSH, ICC, TRC. 

BKS, EKT, GAF, ICC. 

EKT, TRC. 

DUP, EKT, GAF, ICC. 



EKT, GAF, ICC, TRC. 

EKT, GAF, ICC. 

DUP, EKT, GAF, SDC, TRC. 

DUP, OAF, ICC, TRC. 

DUP, EKT, GAF, ICC, MAY, TRC, VPC. 

BKS, DUP, EKT, GAF, HSH, ICC, TRC. 
EKT, GAF. 

ACS, BKS, EKT, GAF, HSH, ICC. 

EKT, TRC. 



100 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 8B. -- Benzenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



DISPERSE DYES--Continued 

■^Disperse orange dyes--Continued 

Disperse Orange 44 

Disperse Orange 62 

Other disperse orange dyes 

♦Disperse red dyes : 

♦Disperse Red 1 

Disperse Red 4 

♦Disperse Red 5 

Disperse Red 7 

♦Disperse Red 11 

♦Disperse Red 13 

♦Disperse Red 15 

♦Disperse. Red 17 

Disperse Red 20 

Disperse Red 21 

Disperse Red 30 

Disperse Red 31 

Disperse Red 35 

Disperse Red 55 

Disperse Red 56 

Disperse Red 59 

♦Disperse Red 60 

Disperse Red 61 

Disperse Red 62 

♦Disperse Red 65 

Disperse Red 66 

Disperse Red 73 

Disperse Red 78 

Disperse Red 96 

Disperse Red 140 

Other disperse red dyes 

♦Disperse violet dyes; 

♦Disperse Violet 1 

♦Disperse Violet 4 

Disperse Violet 8 

Disperse Violet 14 

Disperse Violet 18 

Disperse Violet 26 

♦Disperse Violet 27 

Other disperse violet dyes 

♦Disperse blue dyes: 

♦Disperse Blue 1 

♦Disperse Blue 3 

♦Disperse Blue 7 

Disperse Blue 9 

Disperse Blue 27 

Disperse Blue 35 

Disperse Blue 55 

Disperse Blue 59 

Disperse Blue 60 

Disperse Blue 61 

Disperse Blue 62 

Disperse Blue 63 

♦Disperse Blue 64 

Disperse Blue 70 

Disperse Blue 71 

Disperse Blue 73 

Disperse Blue 79 

Disperse Blue 109 

Disperse Blue 116 

Disperse Blue 133 

Other disperse blue dyes 

Disperse green dyes 

Disperse brown dyes: 

Disperse Brown 1 

Disperse Brown 2 

Other disperse brown dyes 

♦Disperse black dyes: 

♦Disperse Black 1 

Disperse Black 2 



DUP, 
DUP 
AAP. 

AAP 
GAf 
AAP 
AAP 
AAP, 
AAP 
AAP 
AAP 
ACS 
EKT 
EKT 
ICC, 
EKT 
AAP 
DUP 
ACY 
AAP 
DUP 
DUP, 
DUP 
AAP 
TRC 
TRC 
ACY 
DUP, 

AAP; 

AAP 
AAP 
GAF, 
DUP, 
DUP 
DUP 
AAP 
EKT 

AAP 
AAP 
AAP 
ACS 
EKT 
ICI 
TRC 
DUP 
DUP 
DUP 
DUP 
DUP 
DUP 
AAP 
VPC 
TRC 
AAP 
DUP 
ACY 
DUP 
BKS 
OAF 

TRC 
DUP 
EKT 

AAP 
DUP 



EKT, GAF, ICC, MAY. 

ACS, BKS, DUP, EKT, GAF, HSH, ICC, TRC. 

TRC. 

EKT, GAF, HSH, ICC. 

DUP, GAF, TRC. 

DUP, GAF, ICC. 

GAF, HSH, ICC. 

BKS, DUP, EKT, GAF, HSH, ICC, TRC. 



TRC. 



DUP, TRC. 

DUP, GAF. 
DUP, EKT, VPC. 



EKT, ICC, TRC. 



BKS, DUP, EKT, GAF, ICC, MAY, SDC, TRC. 

EKT, GAF, HSH, ICC, TRC. 
GAF, ICC. 



TRC. 

ACY, BL, DUP, EKT, GAF, ICC. 
GAF. 

GAF, TRC. 

ACS, BKS, EKT, GAF, HSH, ICC, TRC. 

EDO, BKS, DUP, EKT, GAF, ICC, TRC. 

GAF, ICC. 



EKT. 

EKT, GAF, TRC. 

TRC. 



DUP, EKT, GAF, HSH, ICC, MAY, VPC. 
ICC, TRC. 



GAF. 

GAF, ICC, SDC. 

DUP, GAF, TRC. 
TRC. 



DYES 



101 



TABLE 8B. -- Benzenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer, i 967- -Continued 



Dye 



DISPERSE DYES --Continued 

^Disperse black dyes — Continued 

Disperse Black 6 

Disperse Black 7 

Disperse Black 9 

Other disperse black dyes 

FIBER-REACTIVE DYES 

Reactive yellow dyes: 

Reactive Yellow 1 

Reactive Yellow 2 

Reactive Yellow 3 

Reactive Yellow A 

Reactive Yellow 6 

Reactive Yellow 7 

Reactive Yellow 13 

Reactive Yellow lA 

Reactive Yellow 15 

Reactive Yellow 16 

Reactive Yellow 17 

Reactive Yellow 18 

Reactive Yellow 22 

Reactive Yellow 2'i 

Reactive Yellow 37 

Other reactive yellow dyes 

Reactive orange dyes : 

Reactive Orange 1 

Reactive Orange A- 

Reactive Orange 5 

Reactive Orange 7 

Reactive Orange 12 

Reactive Orange 13 

Reactive Orange lA 

Reactive Orange 16 

Other reactive orange dyes 

Reactive red dyes : 

Reactive Red 1 

Reactive Red 2 

Reactive Red 3 

Reactive Red A 

Reactive Red 5 

Reactive Red 8 

Reactive Red 11 

Reactive Red 13 

Reactive Red 16 

Reactive Red 21 

Reactive Red 29 

Reactive Red 31 

Reactive Red 33 

Other reactive red dyes 

Reactive violet dyes: 

Reactive Violet 1 

Reactive Violet 2 

Reactive Violet <i 

Reactive Violet 5 

Other reactive violet dyes 

♦Reactive blue dyes: 

Reactive Blue 1 

Reactive Blue 2 

Reactive Blue 3 

Reactive Blue 4 

Reactive Blue 5 

Reactive Blue 7 

Reactive Blue 9 

Reactive Blue 18 

Reactive Blue 19 

Reactive Blue 21 

Reactive Blue 25 

Reactive Blue 27 

Other reactive blue dyes 



Manufacturers' identification codes 
(according to list in table 22) 



AAP, DUP. 

YAW. 

AAP, BL, DUP, EKT, GAF. 

BKS, DUP, EKT, GAF, ICC, VPC, YAW. 



ICI. 

TRC. 

TRC. 

ICI. 

TRC. 

ICI. 

HST. 

HST. 

DUP, HST. 

HST. 

HST. 

ICI. 

ICI. 

HST. 

HST. 

ACY, DUP, HST, VPC. 

ICI. 
ICI. 
TRC. 
DUP. 
ICI. 
ICI. 
ICI. 
HST. 
HST. 

ICI. 

ICI. 

ICI. 

TRC. 

ICI. 

ICI. 

ICI. 

ICI. 

TRC. 

HST. 

ICI. 

HST, ICI. 

ICI. 

ACY, GAF. 

ICI. 
TRC. 
HST. 
HST. 
HST. 

ICI. 

TRC. 

ICI. 

ICI. 

TRC. 

TRC. 

ICI. 

TRC. 

DUP, HST. 

DUP, HST. 

ICI. 

HST. 

ACY, DUP, GAF, HST. 



102 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE SB. -- Bemenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer, i567--Continued 



riye 



Manufacturers' identification codes 
(according to list in table 22) 



FIBER-REACTIVE DYES— Continued 

Reactive green dyes 

Reactive brown dyes: 

Reactive Brown 1 

Reactive Brown 10 

Reactive black dyes: 

Reactive Black 5 

Reactive Black 9 

FLUORESCENT BRIGHTENING AGENTS 

Fluorescent Brightening Agent 1 

Fluorescent Brightening Agent 6 

Fluorescent Brightening Agent 8 

»Fluorescent Brightening Agent 9 

Fluorescent Brightening Agent 22 

Fluorescent Brightening Agent 2-^ 

Fluorescent Brightening Agent 25 

♦Fluorescent Brightening Agent 28 

Fluorescent Brightening Agent 30 

Fluorescent Brightening Agent 33 

Fluorescent Brightening Agent 3^ 

Fluorescent Brightening Agent 37 

Fluorescent Brightening Agent ^5 

Fluorescent Brightening Agent 46 

Fluorescent Brightening Agent A9 

Fluorescent Brightening Agent 52 

Fluorescent Brightening Agent 54 

Fluorescent Brightening Agent 59 

Fluorescent Brightening Agent 61 

Fluorescent Brightening Agent 68 

Fluorescent Brightening Agent 71 

Fluorescent Brightening Agent 75 

Fluorescent Brightening Agent 102 

Fluorescent Brightening Agent 108 

Fluorescent Brightening Agent 109 

Fluorescent Brightening Agent 113 

Fluorescent Brightening Agent 114 

Fluorescent Brightening Agent 125 

Fluorescent Brightening Agent 126 

Fluorescent Brightening Agent 128 

Fluorescent Brightening Agent 130 

Fluorescent Brightening Agent 134 

Fluorescent Brightening Agent 135 

Fluorescent Brightening Agent 136 

Fluorescent Brightening Agent 139 

Fluorescent Brightening Agent 155 

Fluorescent Brightening Agent 158 

Fluorescent Brightening Agent 159 

Fluorescent Brightening Agent 161 

Other fluorescent brightening agents 

FOOD, DRUG, AND COSMETIC COLORS 

Food. Drug, and Cosmet ic Dyes 

«-FDS:C Blue No. 1 

»FD&C Blue No. 2 

FD&C Green No. 3 

*FD&C Red No. 2 

»FD&:C Red No. 3 

FD&C Red No. 4 

FD&C Violet No. 1 

»FD&C Yellow No. 5 

*FD&C Yellow No. 6 

Other food, drug, and cosmetic dyes 

Drug and Cosmetic Dyes 

D&C Blue No. 6 

D&C Blue No. 9 



HST, ICI. 

TRC. 
ICI. 

HST. 
ICI. 



GGY. 

ACY. 

ACY. 

ACY, 

GGY. 

GGY. 

GAF. 

ACY, 

GAF. 

GAF. 

DUP. 

CIB. 

TRC. 

GGY. 

S. 

S. 

GGY. 

GGY. 

ACY. 

CCW, 

ACY, 

GAF. 

DUP, 

GAF. 

GAF. 

VPC. 

VPC. 

ACY. 

SDH. 

SDH. 

SDH. 

CIB. 

CIB. 

CIB. 

CIB. 

WIM. 

ACY. 

ACY. 

ACY. 

ACY, 



GAF, SDH. 



CCW, DUP, GAF. 



GAF. 
GAF. 



VPC. 



CCW, CIB, DUP, GGY, S, TRC. 



ACS, KON, SDH, WJ. 

ACS, KON, SDH. 

WJ. 

ACS, ALT, KON, SDH, STG, WJ. 

ACS, ALT, KON, SDH, STG. 

ACS, ALT, KON, SDH, WJ. 

ACS. 

ACS, ALT, KON, SDH, STG, WJ. 

ACS, ALT, KON, SDH, STG, WJ. 

STG, WJ. 



ACS. 
ACS. 



DYES 



103 



TABLE 8B. -- Benzenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer. 1967 — Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



FOOD, DRUG, AND COSMETIC COLORS— Continued 
Drug and Cosmetic Dyes--Continued 

D&C Brown No. 1 

D&C Green No. 5 

D&C Green No. 6- 

D5:C Green No. 8 

»DS:C Orange No. 4 

D&C Orange No. 5 

D&C Orange No. 10-- 

D&C Orange No. 17 

D&C Red No. 3 

D&C Red No. 6 

♦D&C Red No. 7 

D&C Red No. 8 

D&C Red No. 9 

DSeC Red No. 10 

D&C Red No. 11 

D&C Red No. 12 

D&C Red No. 13 

E&C Red No. 17 

»D&C Red No. 19 

*D&C Red No. 21 

DScC Red No. 22 

D&C Red No. 27 

D&C Red No. 28 

D&C Red No. 30 

D&C Red No. 31 

D&C Red No. 33 

D&C Red No. 3-; 

»D&C Red No. 36 

D&C Red No. 37 

n&C Violet No. 2 

»D&C Yellow No. 5 

D&C Yellow No. 6 

E&C Yellow No. 7 

D&C Yellow No. 8 

D&C Yellow No. 10 

C&C Yellow No. 11 

Drug and Cosmetic Dyes, External 

Ext. D&C Green No. 1-- 

Ext. D&C Orange No. 3 

Ext. D&C Violet No. 2 

Ext. E&C Yellow No. 1 

Ext. E&C Yellow No. 7 

INGRAIN DYES 

Ingrain blue dyes : 

Ingrain Blue 1 

Ingrain Blue 2 

Ingrain Blue 3 

Ingrain Blue 6 

MORDANT DYES 

♦Mordant yellow dyes : 

♦Mordant Yellow 1 

Mordant Yellow 3 

Mordant Yellow 5 

♦Mordant Yellow 8 

Mordant Yellow 10 

Mordant Yellow 14 

Mordant Yellow 16 

Mordant Yellow 20 

Mordant Yellow 26 

Mordant Yellow 29 

Mordant Yellow 30 

Mordant Yellow 36 



ACS. 






ACS, 


KON. 




ACS, 


KON. 




KON, 


SDH. 




ACS, 


KON, 


SNA, TMS 


SNA, 


TMS. 




TMS. 






KON, 


SNA. 




KON, 


TMS. 




SNA, 


TMS. 




KON, 


SNA, 


TMS. 


KON, 


SNA. 




KON, 


SNA, 


TMS. 


KON, 


SNA. 




SNA. 






SNA, 


TMS. 




SNA. 






ACS, 


KON. 




ACS, 


KON, 


SNA, TMS 


KON, 


SNA, 


TMS. 


KON. 






TMS. 






ACS. 






KON. 






KON. 






ACS. 






KON. 






ALT, 


KON, 


SNA, TMS 


ACS. 






ACS. 






KON, 


SNA, 


TMS. 


KON. 






KON. 






KON, 


TMS. 




ACS, 


KON. 




ACS, 


KON. 





ACS, KON. 
ACS. 
KON. 

ACS, KON. 
KON. 



ICI. 
VPC. 
ICI. 
VPC. 



ATL, GAF, PDC, TRC. 

ACS, ATL. 

TRC. 

ACS, DUP, VPC. 

DUP. 

ACS. 

ACS, ACY. 

ACS. 

VPC. 

GAF. 

TRC, VPC. 

PDC. 



104 SYNTHETIC ORGANIC CHEMICALS, 1967 

TABLE 8B. -- Benzenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



MORDANT DYIS--Continued 

»Mordant orange dyes : 

»Mordant Orange 1 

Mordant Orange "4 

*Mordant Orange 6 

Mordant Orange 8 

Mordant Orange 30 

♦Mordant red dyes: 

Mordant Red 3 

Mordant Red 5 

Mordant Red 6 

Mordant Red 7 

Mordant Red 9 

Mordant Red 11 

Mordant Red 19 

Mordant Red 64 

Mordant violet dyes: 

Mordant Violet 11 

Mordant Violet 20 

»Mordant blue dyes : 

Mordant Blue 1 

Mordant Blue 3 

Mordant Blue 7 

Mordant Blue 9 

Mordant Blue 13 

Mordant Blue 19 

Mordant green dyes : 

Mordant Green 11 

Mordant Green 36 

♦Mordant brovm dyes: 

♦Mordant Brown 1 

Mordant Brown 12 

Mordant Brown 13 

Mordant Brown 15 

Mordant Brown 18 

Mordant Brown 19 

Mordant Brown 21 

♦Mordant Brown 33 

♦Mordant Brown 40 

Mordant Brown 50 

Mordant Brown 63 

Mordant Brown 70 

♦Mordant black dyes : 

Mordant Black 1 

♦Mordant Black 3 

Mordant Black 5 

Mordant Black 7 

Mordant Black 8 

Mordant Black 9 

♦Mordant Black 11 

♦Mordant Black 13 

♦Mordant Black 17 

Mordant Black 19 

Mordant Black 26 

♦Mordant Black 38 

Other mordant black dyes 

OXIDATION BASES 

Oxidation Base 8 and 8A 

Oxidation Base 21 

Oxidation Base 22 

Oxidation Base 25 

Other oxidation bases 

SOLVENT DYES 

♦Solvent yellow dyes: 

Solvent Yellow 1 

♦Solvent Yellow 2 

♦Solvent Yellow 3 

Solvent Yellow 13 



AGY, GAP, 


PDC, 


TRC. 






GAF, VPC. 










ATL, GAF, 


PDC, 


TRC. 






TRC. 










ACS. 










ACS, ACY. 










PDC. 










GAF. 










ACS, ACY, 


BDO, 


CMG, 


GAF, PDC, TRC, VPC 


ACS, GAF, 


MRX. 








ACY. 










PDC. 










PDC. 










GAF. 










GAF. 










ACS, DUP, 


GAF, 


TRC. 






GAF. 










TRC. 










ACS, GAF. 










ACS, HSH. 










CMG. 










ACY. 










PDC. 










ACS, CMG, 


DUP, 


GAF, 


TRC, YAW. 




PDC. 










AGS. 










GAF. 










ACS, DUP. 










GAF. 










GAF, VPC. 










ACS, DUP, 


GAF, 


TRC. 






ACS, CMG, 


GAF, 


YAW. 






TRC. 










TRC. 










DUP, PDC. 










ACS. 










ACS, GAF, 


TRC. 








ACS, TRC. 










GAF. 










VPC. 










ACS, VPC. 










ACS, GAF, 


TRC, 


VPC. 






ACS, GAF, 


HSH. 








ACS, ACY, 


DUP, 


GAF, 


TRC. 




PDC. 










TRC. 










ACS, CMG. 










PDC. 











ACY. 
PDC. 
ACY. 
ACY. 
ACY, CMG. 



AAP, ACY. 

AAP, DUP, FH, GAF, PAT, PSC. 

ACS, DUP, GAF, PSC. 

ACY, OAF, TRC. 



DYES 



105 



TABLE 8B. -- Benzenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer, i567--Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



SOLVENT DYES — Continued 

•Solvent yellow dyes — Continued 

•Solvent Yellow 14 

Solvent Yellow 16 

Solvent Yellow 19 

Solvent Yellow 29 

Solvent Yellow 30 

Solvent Yellow 33 

Solvent Yellow 3A 

Solvent Yellow iO 

Solvent Yellow 42 

Solvent Yellow 44 

Solvent Yellow 45 

Solvent Yellow 47 

Solvent Yellow 53 

Solvent Yellow 56 

Solvent Yellow 71 

Solvent Yellow 72 

Solvent Yellow 87 

Other solvent yellow dyes 

•Solvent orange dyes : 

Solvent Orange 2 

•Solvent Orange 3 

Solvent Orange 5 

•Solvent Orange 7 

Solvent Orange 20 

Solvent Orange 23 

Solvent Orange 24 

Solvent Orange 25 

Solvent Orange 31 

Solvent Orange 48 

Solvent Orange 51 

Other solvent orange dyes 

•Solvent red dyes : 

Solvent Red 8 

Solvent Red 22 

•Solvent Red 24 

•Solvent Red 26 

Solvent Red 27 

•Solvent Red 33 

Solvent Red 34 

Solvent Red 35 

Solvent Red 40 

Solvent Red 41 

•Solvent Red 49 

Solvent Red 52 

Solvent Red 65 

Solvent Red 68 

Solvent Red 69 

Solvent Red 74 

Solvent Red 75 

Solvent Red 76 

Solvent Red 80 

Solvent Red 105 

Solvent Red 108 

Solvent Red 111 

Solvent Red 115 - 

Solvent Red 126 

Other solvent red dyes 

•Solvent violet dyes: 

•Solvent Violet 8 

Solvent Violet 9 

Solvent Violet 13 

Solvent Violet 14 

Solvent Violet 17 

Other solvent violet dyes 

Solvent blue dyes : 

Solvent Blue 3 

Solvent Blue 4 

Solvent Blue 5 

Solvent Blue 6 






AAP 
PAT, 
GAF, 
GAF 
ACS 
ACS 
DUP 
ACS 
ACS, 
ACS 
ACS 
ACS 
ACS 
ACY, 
ACY 
ACY, 
ACY 
AAP 

AAP 
ACS 
GAF 
ACS 
ACY 
ACS 
DUP 
ACY 
ACS 
ACY 
ACY 
AAP 

GAF 
GAF 
ACY 
AAP 
ACS 
ACS 
DUP 
GAF 
GAF 
DSC 
ACY 
GAF 
ACS 
ACS 
DSC 
ACS 
ACS 
ACS 
ACS 
ACY 
ACY 
ACY 
ACY 
ACY 
AAP 

ACS 

DSC 
AAP 
ICI 
ACS 
AAP 

ACY 
DSC 
DSC 
DSC 



ACS, ACY, DUP, FH, GAF, PAT, PSC, SDH. 



PSC. 
ACY. 



GAF. 
DUP. 
ACY, DUP, GAF. 



DSC, PAT, X. 

PSC. 

ACY, DSC, GAF, PSC. 

TRC. 

ACY, FH, GAF. 

GAF. 



DUP. 



ACY, DSC, DUP, PAT. 



DUP, FH, GAF, PAT, SDH. 
ACS, ACY, PSC. 



DUP, GAF. 



DSC, DUP, GAF. 
ICI. 



DUP. 



ACY. 



ACY, DSC, DUP, GAF, ICI, PAT. 

ACY, DSC, DUP, NYC. 

HSH, ICI. 

ACY, DSC, NYC, PAT. 

SW. 

DUP, SDH. 



106 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 8B. -- Benzenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer , 1967 — Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



SOLVENT DYES— Continued 

Solvent blue dyes — Continued 

Solvent Blue 7 

Solvent Blue 9 

Solvent Blue 11 

Solvent Blue 12 

Solvent Blue 16 

Solvent Blue 32 

Solvent Blue 36 

Solvent Blue 37 

♦Solvent Blue 38 

Solvent Blue A3> 

Solvent Blue 58 

Solvent Blue 59 

Solvent Blue 60 

Solvent Blue 74 

Other solvent blue dyes 

Solvent green dyes : 

Solvent Green 1 

Solvent Green 2 

Solvent Green 3 

Solvent Green 10 

Solvent Green 11 

Other solvent green dyes 

^^Solvent brown dyes : 

Solvent Brown 11 

♦Solvent Brown 12 

Solvent Brown 17 

Solvent Brown 19 

Solvent Brown 20 

Solvent Brown 22 

Solvent Brown 38 

Other solvent brown dyes 

Solvent black dyes : 

Solvent Black 3 

Solvent Black 5 

Solvent Black 7 

Solvent Black 12 

Solvent Black 13 

Solvent Black 17 

Solvent Black 26 

Other solvent black dyes 

SULFUR DYES 

Sulfur yellow dyes: 

Leuco Sulfur Yellow 1 

Leuco Sulfur Yellow 2 

Sulfur Yellow A 

Leuco Sulfur Yellow 4 

Leuco Sulfur Yellow 15 

Other sulfur yellow dyes 

Sulfur red dyes ; 

Sulfur Red 1 

Leuco Sulfur Red 5 

Sulfur Red 6 

Leuco Sulfur Red 6 

Sulfur Red 8 

Sulfur blue dyes : 

Sulfur Blue 7 

Leuco Sulfur Blue 7 

Solubilized Sulfur Blue 7 

Sulfur Blue 8 

Leuco Sulfur Blue 8 

Sulfur Blue 9 

Sulfur Blue 11 

Leuco Sulfur Blue 11 

Leuco Sulfur Blue 13 

Sulfur Blue 15 

Other sulfur blue dyes 

Sulfur green dyes : 

Sulfur Green 1 



ACS, 
GAF. 
GAP, 
ACS, 
ACS. 
AAP. 
ACS, 
DUP. 
ACS, 
ACS. 
ACY. 
ACY. 
ACY. 
ACS. 
AAP, 

ACY, 
GAF. 
AAP, 
DUP. 
DUP. 
DSC. 



ACY. 



ICI. 

DUP. 



DUP. 
ACY, DUP. 



ACY, DSC, GAF, ICI, NYC, PAT, SDH. 

DSC, SDH. 

ACS, ACY, ATL, GAF, HSH, ICI. 



GAF. 








ACY, 


DSC, 


GAF. 




DUP. 








ACY, 


DUP. 






FH. 








ACY. 
DSC. 








ACS. 








ACS, 


ACY, 


DSC. 




ACS, 


ACY, 


DSC, FH, 


NYC 


ACS, 


NYC. 






ACS. 








DUP. 








ACY. 








DSC, 


NYC. 







SDC. 






ACY, 


SDC. 




DUP, 


SDC. 




SDC. 






ACY. 






ACY, 


SDC. 




ACS, 


ACY. 




SDC. 






ACS, 


ACY, 


DUP, SDC 


SDC. 






DUP. 






ACS, 


ACY, 


SDC. 


ACS, 


ACY, 


SDC. 


SDC. 






SDC. 






SDC. 






ACS, 


ACY. 




ACS, 


DUP, 


SDC. 


SDC. 






ACY. 






DUP. 






ACY, 


SDC. 





ACS. 



DYES 



107 



TABLE 8B. — Benzenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



SULFUR DYES— Continued 

Sulfur green dyes — Continued 

Sulfur Green 2 

Leuco Sulfur Green 2 

Sulfur Green 3 

Leuco Sulfur Green 3 

Sulfur Green 14 

Leuco Sulfur Green 16 

Solubilized Sulfur Green 16 

Sulfur Green 28 

Other sulfur green dyes 

Sulfur brown dyes: 

Sulfur Brovm 3 

Leuco Sulfur Brown 3 

Solubilized Sulfur Brown 3 

Sulfur Brown 10 

Leuco Sulfur Brown 10 

Solubilized Sulfur Brown 10 

Sulfur Brown 1<> 

Leuco Sulfur Brown 14 

Solubilized Sulfur Brown 14 

Sulfur Brown 20 

Sulfur Brown 21 

Sulfur Brown 26 

Sulfur Brown 30 

Sulfur Brown 33- 

Sulfur Brown 37 

Leuco Sulfur Brown 3'7 

Sulfur Brown 44 

Sulfur Brown 45 

Sulfur Brown 50 

Leuco Sulfur Brown 82 

Other sulfur brown dyes 

Sulfur black dyes; 

Sulfur Black 1 

Leuco Sulfur Black 1 

Solubilized Sulfur Black 1 

Sulfur Black 2 

Leuco Sulfur Black 2 

Solubilized Sulfur Black 2 

Leuco Sulfur Black 6 

Sulfur Black 10 

Leuco Sulfur Black 10 

Sulfur Black 11— 

Leuco Sulfur Black 11 

Other sulfur black dyes 

VAT DYES 

*Vat yellow dyes: 

Vat Yellow 1, 12-l/2!(i 

«Vat Yellow 2, 8-l/2^ 

Solubilized Vat Yellow 2, 255fe 

Vat Yellow 3, 12-1/2$ 

Vat Yellow 4, 12-1/2$ 

^Solubilized Vat Yellow 4, 37-1/2$ 

Vat Yellow 10, 10$ 

Vat Yellow 13, 6-1/2$ 

Vat Yellow 14, 12-1/2,4 

Vat Yellow 15, 11-1/2$ 

Vat Yellow 21, 9-l/2$ 

Vat Yellow 22, 10$ 

Vat Yellow 27 

Vat Yellow 33, 15$ 

Vat Yellow 41, 9$ 

Other vat yellow dyes 

*Vat orange dyes: 

»Vat Orange 1, 20$ 

*Solubllized Vat Orange 1, 26$ 

»Vat Orange 2, 12$ 

•Vat Orange 3, 13-l/2$— 



SDC. 
SDC. 
ACS. 
SDC. 
DUP. 
SDC. 
SDC. 
ACY. 
ACY, SDC. 

SDC. 

SDC, SDH. 

SDC. 

ACS, DUP, SDC. 

SDC. 

SDC. 

SDC. 

ACY, SDC. 

SDC. 

DUP. 

DUP. 

ACY. 

ACY. 

ACY. 

SDC. 

SDC. 

ACS. 

ACS. 

ACS. 

ACY. 

ACY, SDC. 

ACS, ACY, DUP, SDC. 

ACS, ACY, SDC. 

SDC. 

ACS, ACY, DUP, SDC. 

ACS, ACY, SDC. 

SDC. 

ACS. 

ACY, DUP. 

ACS, ACY. 

SDC. 

SDC. 

SDC. 



ACS. 
AAP, 
GAP, 
DUP. 
ACY, 
GAP, 
GAP. 
ICI. 
TRC. 
ACY. 
ATL. 
DUP, 
VPC. 
TRC. 
ACY. 
ACS, 



ACS, ATL, GAP, ICI, TRC, VPC. 
ICI. 

ATL, CMC, OAF, HST, ICI, VPC. 
HST, ICI. 



GAP. 



GAP, MAY, VPC. 



ACS, CMC, GAP, HST, ICI, TRC, VPC. 

GAP, HST, ICI. 

AAP, ACS, ACY, CMG, DUP, GAP, ICI, TRC. 

CMG, DUP, GAP, HST. 



108 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 8B. -- Benzenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer, 7567 --Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



VAT DYES--Continued 

*Vat orange dyes--Continued 

»Vat Orange <;, 6% 

»Vat Orange 5, 10^ 

»Solubilized Vat Orange 5, 30<f, 

Vat Orange 7, ll^t 

■»Vat Orange 9, 12/. 

Vat Orange 11, 6% 

»Vat Orange 15, 1054 

Vat Orange 23, 17-l/25t 

Vat Orange 2'i 

Other vat orange dyes 

»Vat red dyes : 

»Vat Red.l, 13% 

»Solubllized Vat Red 1, 37=!, 

Vat Red 10, l8«i 

Solubilized Vat Red 10, 31^4 

Vat Red 12, 8-1/2'^ 

»Vat Red 13, ll^t 

Vat Red U, lO^i 

»Vat Red 15, lO?!. 

Vat Red 16, lljt 

Vat Red 17, 10$ 

Vat Red 23 

Vat Red 29, 18$ 

*Vat Red 32, 20$ 

Vat Red 35, 12-1/2$ 

Vat Red -W, 17^ 

Vat Red 52, 10$ 

Vat Red 53, 12$ 

Vat Red 56, 15-1/2$ 

Vat Red 62 

Other vat red dyes 

»Vat violet dyes: 

*Vat Violet 1, 11$ 

Solubilized Vat Violet 1, 26$ 

»Vat Violet 2, 20$ 

Vat Violet 3, 15$ 

Solubilized Vat Violet 3, 0$ 

»Vat Violet 9, 12$ 

*Vat Violet 13, 6-l/<;$ 

Vat Violet W, 12-1/2$ 

Vat Violet 17, 12-1/2$ 

Vat Violet 21— 

Other vat violet dyes 

»Vat blue dyes: 

Vat Blue 1, 20$ 

Solubilized Vat Blue 1, 25$ 

Vat Blue A, 10$ 

Vat Blue 5, 16$ 

Solubilized Vat Blue 5, 38$ 

»Vat Blue 6, 8-1/3$ 

Solubilized Vat Blue 6, 17-1/2$ 

Vat Blue 7, 12-1/2$ 

Solubilized Vat Blue 9, 35$ 

Vat Blue 12, 6-1/2$ 

Vat Blue U, 8-1/3$ 

Vat Blue 16, 16-1/2$ 

Vat Blue 18, 13$ 

»Vat Blue 20, 1^$ 

Vat Blue 26, 24$ 

Vat Blue 29 

Vat Blue 35, 20$ 

Vat Blue 39, 12$ 

Vat Blue 42, 20$ 

Vat Blue 43 

Vat Blue 53, 20-1/2$ 

Vat Blue 60 

Other vat blue dyes 

*Vat green dyes : 

*Vat Green 1, 6$ 

Solubilized Vat Green 1, 12-1/2$ 



ACY, CMG, DUP. 

AAP, ACY, HST. 

GAF, HST, ICI. 

GAF, HST, TRC. 

AAP, ACS, ACY, CMG, DUP, GAF, ICI, TRC. 

ACS, DUP. 

AAP, ACS, GAF, ICI, TRC, VPC. 

ACY, DUP. 

DUP. 

GAF, SDC. 

AAP, ACY, HST, ICI. 

GAF, HST, ICI. 

ACS, GAF. 

GAF. 

DUP. 

DUP, GAF, TRC. 

GAF, HST. 

GAF, HST, TRC. 

DUP. 

GAF. 

DUP. 

GAF. 

ACS, DUP, GAF. 

ACS, TRC. 

TRC. 

DUP. 

DUP. 

ACY. 

DUP. 

GAF, TRC, VPC. 

ACS, ACY, DUP, GAF, ICI, MAY, TRC. 

GAF, ICI. 

ACY, GAF, HST, VPC. 

GAF, HST. 

GAF. 

DUP, GAF, ICI, TRC. 

ACS, DUP, GAF, ICI, TRC. 

ACS. 

DUP, GAF. 

VPC. 

GAF, MAY. 



ACS. 
GAF. 
ACY, 
ATL, 
GAF, 
AAP, 
GAF, 
ACS. 
GAF. 
DUP. 
ACS, 
ACS, 
AAP, 
AAP, 
GAF. 
GAF. 
HST. 
GAF. 
SDC. 
DUP, 
GAF. 
DUP. 
GAF, 



DUP, GAF. 

DUP, HST. 

HST. 

ACS, ACY, DUP, OAF, ICI, MAY, TRC. 

HST, ICI. 



DUP, GAF, TRC. 

ACY, DUP. 

ACS, ACY, ATL, DUP, GAF, ICI, MAY, TRC. 

ACY, ATL, DUP, GAF, ICI, MAY, SDC, TRC. 



SDC. 



VPC, X. 



AAP, ACY, ATL, DUP, GAF, ICI, MAY. 
GAF, HST, ICI. 



DYES 



109 



TABLE 8B. — Bemenoid dyes for which U.S. production or sales were reported, identified by 

manufacturer, 7 967- -Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 22) 



VAT DYES— Continued 

»Vat green dyes — Continued 

»Vat Green 3, 10$ 

Solubillzed Vat Green 3, 26% 

»Vat Green 8, 8-l/2i6 

•Vat Green 9, 12-l/2!t 

Vat Green 15, 17$ 

Vat Green 18, 8$ 

Vat Green 20, 6$ 

Other vat green dyes 

»Vat brovm dyes: 

»Vat Brown 1, 11$ 

Solubilized Vat Brown 1, 17$ 

»Vat Brown 3, 11$ 

»Vat Brown 5, 13$ 

Vat Brown 11, 12$ 

Vat Brown 12, 12-1/2$ 

Vat Brown 13, 17$ 

Vat Brown 20, 10-1/2$ 

Vat Brown 25, 11-1/2$ 

Vat Brown 28, 22$ 

Vat Brown 29, 13$ 

Vat Brown 31, 28$ 

Vat Brown 38, 20$ 

Vat Brown 40, l'i$ 

Vat Brown 53 

Vat Brown 57, 15$ 

Other vat brown dyes 

»Vat black dyes: 

•Solubilized Vat Black 1, 27-1/2$ 

•Vat Black 9, 16$— 

Vat Black 11, 17-1/2$ 

Vat Black 13, U$ 

Vat Black W, 11-1/2$ 

Vat Black 15 

Vat Black 18, 15-1/2$ 

Vat Black 21, 18-1/2$ 

Vat Black 22, 19$ 

•Vat Black 25, 12-1/2$ 

•Vat Black 27, 12-1/2$ 

Vat Black iU, 16$ 

Vat Black 37 

Vat Black 38, 20$ 

Vat Black 52, l8-l/2$ 

Other vat black dyes 

All other dyes 



AAP, 


ACS, 


ACY, 


ATL, 


DUP, 


GAF, 


ICI, 


MAY, 


TRC 


GAF, 


HST, 


ICI. 














ACS, 


ATI, 


DUP, 


GAF, 


ICI. 










ACS, 


ACY, 


ATL, 


DUP, 


GAF, 


MAY, 


SDC, 


TRC. 




ACS. 


















DUP. 


















DUP. 


















GAF, 


MAY, 


SDC. 














ACS, 


ACY, 


DUP, 


GAF, 


ICI, 


MAY, 


TRC. 






GAF, 


ICI. 
















AAP, 


ACS, 


ACY, 


DUP, 


GAF, 


ICI, 


MAY, 


TRC, 


VPC 


AAP, 


ACY, 


GAF, 


HST, 


VPC. 










DUP, 


MAY, 


TRC. 














ACS, 


DUP. 
















MAY. 


















ACS, 


GAF. 
















GAF. 


















ICI. 


















ACY. 


















AAP. 


















ICI. 


















DUP. 


















GAF. 


















GAF, 


HST, 


TRC. 














ACS, 


GAF, 


SDC, 


VPC. 












GAF, 


HST, 


ICI. 














ACS, 


ATL, 


GAF, 


MAY, 


TRC. 










ACY. 


















ACS, 


DUP. 
















DUP. 


















AAP. 


















ACS, 


GAF. 
















ACY. 


















ACY, 


TRC. 
















AAP, 


ACY, 


DUP, 


GAF, 


ICI, 


MAY, 


TRC. 






AAP, 


ACS, 


ACY, 


BDO, 


DUP, 


GAF, 


ICI, 


MAY, 


TRC 


ICI. 


















GAF. 


















GAF. 


















ACY. 


















DUP, 


GAF, 


SDC, 


TRC. 












ACY, 


DUP, 


PAT, 


SDC. 













110 



SYNTHETIC ORGANIC CHEMICALS, 1967 



Pigments 



TABLE ll'B.--Benzenoid pigments for which U.S. production or sales were reported, identified 

by manufacturer, 1967 

[Benzenoid pigments for which separate statistics are given in table llA are marked below with an asterisk («); 
products not so marked do not appear in table llA because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Pigment 



Manufacturers' identification codes 
(according to list in table 22) 



TONERS 

»Yellow toners: 
*Hansa yellows : 

»Pigment Yellow 1, C.I. 11 680 

^-Pigment Yellow 3, C.I. 11 710 

Pigment Yellow A, C.I. 11 665 

Pigment Yellow 5, C.I. 11 660 

Pigment Yellow 6, C.I. 11 670 

Pigment Yellow 9, C.I. 11 720 

Pigment Yellow 4.9, C.I. 11 765 

Pigment Yellow 65, C.I. 11 740 

*Pigment Yellow 73 

»Pigment Yellow 74, C.I. 11 741 

All other Hansa yellows 

^^Benzidine yellows : 

^Pigment Yellow 12, C.I. 21 090 

»Pigment Yellow 13, C.I. 21 100 

»Pigment Yellow 14, C.I. 21 095- 

*Pigment Yellow 17, C.I. 21 105 

Pigment Yellow 83 

All other benzidine yellows 

Pigment Yellow 10, C.I. 12 710 

Pigment Yellow 18, C.I. 49 005 

Pigment Yellow 19 

Pigment Yellow 60, C.I. 12 705 

(Basic Yellow 2), C.I. 4-1 000, fugitive 

(Vat Yellow l), C.I. 70 600 

All other 

*Orange toners : 

Pigment Orange 1, C.I. 11 725 

^-Pigment Orange 2, C.I. 12 060 

*Pigment Orange 5, C.I. 12 075 

^Pigment Orange 13, C.I. 21 110 

Pigment Orange 15, C.I. 21 130 

»Pigment Orange 16, C.I. 21 160 

Pigment Orange 30 

Pigment Orange 34, C.I. 21 115 

(Vat Orange 1), C.I. 59 105 

(Vat Orange 2), C.I. 59 705 

(Vat Orange 3), C.I. 59 300 

(Vat Orange 4), C.I. 59 710 

(Vat Orange 7), C.I. 71 105 

(Vat Orange 15), C.I. 69 025 

All other 

»Red toners : 

*Naphthol reds : 

^Pigment Red 2, C.I. 12 310 

«Pigment Red 5, C.I. 12 490 

Pigment Red 7, C.I. 12 420 

Pigment Red 9, C.I. 12 460 

Pigment Red 10, C.I. 12 440 

^Pigment Red 13, C.I. 12 395 

Pigment Red 14, C.I. 12 380 

Pigment Red 15, C.I. 12 465 

See note at end of table for definition of abbreviations. 



ACS, ACY, AMS, CPC, DUP, FCL, GAP, HSC, HSH, ICI, 

IMP, KON, PPG, S, SDH, SNA, SW. 
ACS, HSC, HSH, HST, IMP, KCW, PPG, S, SW. 
ACS, SNA. 
IMP. 
IMP. 
SNA. 
ICI. 
SW. 

ACS, SNA, SW, X. 
DUP, SDH, SW. 
HSC, KCW. 

ACS, ACY, AMS, CIK, DUP, FCL, GAP, HSC, HSH, HST, 

ICC, IMP, KON, LVY, S, SDH, SNA, SW. 
ACS, BUC, FCL, GAP, HSH, HST, ICC, IMP, RCM, SDH, 

SNA, SW. 
ACS, ACY, AMS, BUC, CIK, CPC, DUP, FCL, GAP, HSC, 

HSH, HST, ICC, IMP, KON, ROM, S, SDH, SNA, SW, x. 
ACY, AMS, BUC, FCL, HSC, HSH, HST, ICC, IMP, SDH, 

SNA, SW. 
HST. 

HSH, ICC, IMP, ROM, SW. 
SW. 
IMP. 
GAF. 
SW. 
MRX. 

ACS, TRC. 
ACY, ICC, IMP, S, SW. 

ACS, KCW. 

FCL, IMP, SDH, SW, UHL. 

ACY, HSC, IMP, SNA, SW. 

ACS, ACY, AMS, DUP, HSC, IMP, KON, S, SNA, SW. 

ACS, GAF. 

ACS, BUC, DUP, FCL, HSH, HST, ICC, IMP, RCM, SDH, 

SNA, SW. 
SNA. 

BUC, ICC. 
HST. 
GAF. 

ACS, TRC. 
ACS. 

GAF, HST. 
ACS, TRC. 
ICC, KON, ROM, SDH. 



ACS, GAF, HSC, HSH, IMP, KCW, KON, MRX, SDH, SW. 

DUP, GAF, HSH, HST, ICC, ICI, IMP, RCM, S, SDH, SW. 

ICI, S. 

IMP. 

KCW. 

ACS, IMP, KCW, SW. 

DUP. 

DUP. 



PIGMENTS 

TABLE WB.--Benzenoid pigments for which U.S. production or sales were reported, identified 

by manufacturer , iS67--Continued 



Pigment 



Manufacturers' identification codes 
(according to list in table 22) 



TONERS— Continued 

«Red toners--Continued 
*Naphthol reds--Contlnued 

♦Pigment Red 17, C.I. 12 390 

"Pigment Red 18, C.I. 12 350 

Pigment Red 19, C.I. 12 <iOO 

♦Pigment Red 22, C.I. 12 315 

♦Pigment Red 23, C.I. 12 355 

Pigment Red 31, C.I. 12 360 

All other naphthol reds 

♦Pigment Red 1, C.I. 12 070, dark 

♦Pigment Red 1, C.I. 12 070, light 

♦Pigment Red 3, C.I. 12 120 

♦Pigment Red ^, C.I. 12 085 

♦Pigment Red 6, C.I. 12 090 

♦Pigment Red 38, C.I. 21 120 

Pigment Red 41, C.I. 21 200 

♦Pigment Red ^S, C.I. 15 365 

Pigment Red 49, C.I. 15 630: 
♦Barium toner 

♦Calcium toner 

♦Sodium toner 

♦Pigment Red 52, C.I. 15 860 

♦Pigment Red 53, C.I. 15 585, barium toner-- 

Pigment Red 53, C.I. 15 585, sodium toner — 

♦Pigment Red 54, C.I. 14 830, calcium toner- 
Pigment Red 55, C.I. 15 820 

♦Pigment Red 57, C.I. 15 850, calcium toner- 
Pigment Red 58, C.I. 15 825 

♦Pigment Red 63, C.I. 15 880 

Pigment Red 64, C.I. 15 800 

Pigment Red 77, C.I. 15 826 

Pigment Red 79, PMA 

Pigment Red 81, C.I. 45 160, fugitive 

♦Pigment Red 81, C.I. 45 160, MA 

♦Pigment Red 81, C.I. 45 160, PTA 

Pigment Red 87, C.I. 73 310 

Pigment Red 88 

♦Pigment Red 90, C.I. 45 380 

Pigment Red 117, C.I. 15 603 

Pigment Red 122 

Pigment Red 123 

(Vat Red 1), C.I. 73 360 

(Vat Red 23), C.I. 71 130 

♦(Vat Red 29), C.I. 71 140 

All other 

♦Violet toners; 

Pigment Violet 1, C.I. 45 170, fugitive 

♦Pigment Violet 1, C.I. 45 170, PMA 

♦Pigment Violet 1, C.I. 45 170, PTA 

♦Pigment Violet 3, C.I. 42 535, fugitive 

♦Pigment Violet 3, C.I. 42 535, PMA 

♦Pigment Violet 3, C.I. 42 535, PTA 

Pigment Violet 19, C.I. 46 500 

♦Pigment Violet 23 

(Vat Violet 1), C.I. 60 010 

(Vat Violet 2), C.I. 73 385 

'Vat Violet 3), C.I. 73 395 

All other 



ACY, FCL, ICC, IMP, SNA, SW, UHL. 

ACS, IMP, SW. 

ACS. 

ACY, DUP, FCL, GAP, IMP, MRX, SNA, 

ACY, BUC, DUP, FCL, ICC, IMP, ROM, 

SNA. 

ICC, IMP, KCW, S, SDH, SW. 

ACY, AMS, HSC, HSH, IMP, KON, LVY, 

ACY, HSC, HSH, IMP, KON, PPG, SDH, 

ACS, ACY, CIK, DUP, FCL, HSC, HSH, 

PPG, SDH, SNA, SW, UHL. 

ACY, AMS, FCL, HSC, HSH, IMP, KON, MRX, SDH, SNA, 

SW, UHL. 

DUP, HSC, KCW, KON, SW. 

ACS, DUP, GAF, ICC, SNA, SW. 
ACS, GAF. 

ACS, ACY, AMS, DUP, FCL, GAF, HSC, HSH, ICC, IMP, 

KON, LVY, MRX, S, SNA, SW. 



SW. 

SDH, SNA, SW. 



SDH, SW. 
SNA, SW. 
IMP, KCW, KON, 



ACY, 


AMS, 


CIK, 


FCL, 


HSC, 


IMP, 


KON, 


LVY, 


PPG, 


SDH, 


SW 


, UHL 


















ACY, 


AMS, 


CIK, 


FCL, 


HSC, 


IMP, 


LVY, 


PPG, 


SDH, 


SW. 


ACY, 


AMS, 


FCL, 


HSC, 


SDH, 


SW. 










AMS, 


FCL, 


HSC, 


HSH, 


IMP, 


SNA, 


SW. 








ACY, 


AMS, 


CIK, 


FCL, 


HSC, 


IMP, 


KON, 


LVY, 


MGR, 


MRX, 


SDH, SNA, SW 
















KON. 




















HSH, 


IMP, 


MRX, 


SDH. 














ACS, 


DUP. 


















ACS, 


AMS, 


CIK, 


DUP, 


FCL, 


HSC, 


HSH, 


IMP, 


KON, 


LVY, 


MGR, SDH, SNA, SW 














DUP, 


GAF, 


IMP. 
















ACS, 


FCL, 


HSH, 


IMP, 


KON, 


SNA, 


SW. 








ACS. 




















SW. 




















GAF. 




















KCW, 


MGR. 


















CPC, 


DUP, 


FCL, 


GAF, 


IMP, 


KON, 


LVR, 


LVY, 


MGR, 


MRX, S, 


SNA. 


















ACY, 


AMS, 


DUP, 


FCL, 


GAF, 


HSC, 


IMP, 


KCW, 


KON, 


MGR, 


MRX, S, 


SDH, 


SNA. 














ACS. 




















ACS, 


SDH. 


















AMS, 


FCL, 


ICC, 


IMP, 


LVR, 


LVY, 


NYC, 


SDH, 


SNA. 




SW. 




















ACS. 




















ACS. 




















HST. 




















ACS. 




















ACS, 


GAF, 


HSC. 
















ACY, 


DUP, 


GAF, 


HAM, 


HSC, 


SW, 


TRC. 









UHL. 

GAF, IMP, LVR, MGR, MRX, S, SNA. 

ACY, AMS, DUP, FCL, GAF, HSC, IMP, MGR, MRX, SNA. 

ACY, AMS, HAM, HSC, IMP, KON, LVY, MGR, NYC, UHL. 

AMS, CIK, DUP, GAF, HSC, IMP, KON, LVR, LVY, MGR, 

MRX, PPG, SDH, SNA, SW, UHL. 

ACY, AMS, GAF, HSC, IMP, KON, MRX, SNA, SW. 

ACS, DUP, SNA. 

ACS, ACY, GAF, HST. 

ACS, DUP. 
ACS. 
ACS. 

BUC, ICC, IMP, ROM. 



See note at end of table for definition of abbreviations. 



112 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE IIB Benzenoid pigments for which U.S. production or sales were reported, identified 

by manufacturer, 1967 — Continued 



Pigment 



Manufacturers' identification codes 
(according to list in table 22) 



TONERS- -Continued 

»Blue toners; 

»Pigment Blue 1, C.I. -42 595, PMA 

•Pigment Blue 1, C.I. ^2 595, PTA 

Pigment Blue 2, C.I. ^ CK5, PMA- 

Pigment Blue 2, C.I. ^ 045, PTA 

Pigment Blue 5, C.I. 42 600 

Pigment Blue 9, C.I. 42 025, MA 

■"■Pigment Blue 9, C.I. 42 025, PTA 

Pigment Blue 10, C.I. 44 040, FMA 

Pigment Blue 10, C.I. 44 040, PTA 

-"Pigment Blue 14, C.I. 42 600, PMA 

Pigment- Blue 14, C.I. 42 600, PTA 

-•Pigment Blue 15, C.I. 74 160, alpha form 

•Pigment Blue 15, C.I. 74 160, beta form 

•Pigment Blue 19, C.I. 42 750A 

•Pigment Blue 22, C.I. 69 810 

•Pigment Blue 25, C.I. 21 180 

(Basic Blue 7), C.I. 42 595, PTA 

(Vat Blue 4), C.I. 69 800 

(Vat Blue 6), C.I. 69 825 

All other 

•Green toners ; 

Pigment Green 1, C.I. 42 040, FMA 

•Pigment Green 1, C.I. 42 040, PTA 

•Pigment Green 2, C.I. 42 040 and 49 005, FMA- 
•Pigment Green 2, C.I. 42 040 and 49 005, PTA- 

Pigment Green 4, C.I. 42 000, fugitive 

Pigment Green 4, C.I. 42 000, FMA 

•Pigment Green 4, C.I. 42 000, PTA 

•Pigment Green 7, C.I. 74 260 

•Pigment Green 8, C.I. 10 006 

Pigment Green 10, C.I. 12 775 

•Pigment Green 36, C.I. 74 265 

Pigment Green 38 

All other 

•Brown toners : 

Pigment Brown 1, C.I. 12 480 

Pigment Brown 2, C.I. 12 071 

Pigment Brown 3, C.I. 21 010, FMA 

•Pigment Brown 5, C.I. 15 800 

(Vat Brown 3), C.I. 69 015 

All other 

•Black toners : 

Pigment Black 1, C.I. 50 440 

Pigment Black 7, C.I. 77 266 

All other 

LAKES 

yellow lakes : 

(Acid Yellow l), C.I. 10 316 

(Acid Yellow 3), C.I. 47 005 

(Acid Yellow 23), C.I. 19 140 

Orange lakes : 

Pigment Orange 17, C.I. 15 510 

All other 

Red Lakes: 

•Pigment Red 60, C.I. 16 105 

•Pigment Red 83, C.I. 58 000 

(Acid Red 17), C.I. 16 180 

• (Acid Red 26), C.I. 16 150 -- 

(Natural Red 4), C.I. 75 470 

(Natural Red 24), C.I. 75 280 



DUP, GAP, IMP, KON, LVR, LVY, MGR, MRX, SDH, SNA, 

SW, UHL. 
ACS, AMS, GAP, IMP, KON, MGR, SNA, SW. 
GAF. 

GAP, HAM. 
GAF. 
MRX. 

GAF, IMP, MGR, MRX, SDH. 
IMP, SDH. 
IMP. 

DUP, GAF, IMP. 
DUP, 
ACS, ACY, DUP, FCL, GAF, HSC, ICI, IMP, MGR, SNA, 

SW, TMS, TRC. 
ACY, AMS, DUP, FCL, HSC, ICC, IMP, LVY, SNA, SW, 

TMS. 
ACY, AMS, HSC, NYC, SW. 
ACS, DUP, MP, TRC. 
ACS, DUP, GAP, ICC, S, SW. 
DUP. 
GAF. 

ICI, TRC. 
GAF, IMP, S, SDH. 

GAF, IMP, MRX, UHL. 

IMP, MGR, S. 

AMS, GAF, IMP, KON, LVY, MGR, MRX, UHL. 

ACY, DUP, GAF, IMP, KON, LVY, MRX, S, SDH, UHL. 

GAF. 

GAF, MGR. 

ACY, AMS, HAM, IMP, KON, MGR. 

ACS, ACY, CIK, DUP, FCL, GAF, HSC, ICC, IMP, SNA, 

SW, TMS, TRC. 

DUP, HSH, MP, KCW, SW. 

DUP, HSC, MP, SW. 

ACY, GAF, SNA. 
ACS, SNA. 
SW. 

ICI. 

SDH. 

KCW, KON. 

ACS, BUC, HSH, ICC, RCM, SNA. 

GAF, TRC. 

GAF, ICC, SDH, SW. 

SNA. 
GAF. 
DUP, GAF, UHL. 



MP. 








MP. 

KON, 


MRX. 






CPC, 
HAM. 


IMP, 


KCW. 




HSC, 


HSH, 


KON, 


MRX, SNA, SW 


HSH, 


MP, 


KON, 


MRX, SW, UHL 


MP, 


KCW. 






CPC, 


HAM, 


MP, 


KCW. 


KON. 








IMP. 









See note at end of table for definition of abbreviations. 



PIGMENTS 

TABLE IIB. --Bemenoid pigments for which U.S. production or sales were reported, identified 

by manufacturer, 7967— Continued 



113 



Pigment 


Manufacturers' identification codes 
(according to list in table 22) 


LAKES- -Continued 

Red Lakes--Continued 

(Natural Red 2-4), C.I. 75 280 

All other — 

Violet lakes: 

»Pigment Violet 5, C.I. 58 055 

Pigment Violet 20, C.I. 58 225 

All other 

Blue lakes: 

Pigment Blue 17, C.I. 74 180 

Pigment Blue 24, C.I. 42 090 

(Acid Blue 93), C.I. 42 780 

(Acid Blue 104), C.I. 42 735 

Brown lakes 

Black lakes : 

(Natural Black 3), C.I. 75 291 

All other 


IMP. 

HAM, IMP, SNA. 

ACS, DUP, HSH, IMP, KON, MRX, S, UHL. 

SW. 

HAM. 

CPC. 

AMS, ICC, KON, LVY, SDH. 

LVR. 

CPC, KCW. 

HAM, KON. 

CPC, KON. 
HAM. 



Note. — The C.I. (Colour Index) numbers shown in this report are the identifying codes given in the second edition of 

the Colour Index. 

When the name of a color is enclosed in parentheses, it indicates that this name is that of the dye from which the 
pigment can be made and that no name for the pigment itself is given in the Colour index. 

The abbreviations FMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic) 
acids, respectively. 



114 



SYNTHETIC ORGANIC CHEMICALS, 1967 



Medicinal Chemicals 



TABLE IZB.— Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1967 

[Jfedicinal chemicals for which separate statistics are given in table I3A are marked below with an asterisk 

(«); medicinal chemicals not so marked do not appear in table 13A because the reported data are accepted in con- 
fidence and ma^r not be published. Manufacturers' Identification codes shown below are taken from table 22. An x 
signifies that the manufacturer did not consent to his identification with the designated product] 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



*Antibiotlcs: 

*For medicinal use: 

^Antifungal and antitubercular antibiotics: 
Antifungal antibiotics: 

Amphotericin B 

Candicidin 

Nystatin 

Antitubercular antibiotics: 
Cycloserine- 



Dihydrostreptomycin 

Streptomy c in 

Viomycin — 

*Bacitracin 



*Penicillin G, potassium 

■Other antibiotics for medicinal use: 

Cephaloridine 

Cephalothin 

Chloramphenicol 

Ery thromyc in 

Fumagillin 

Oentamycin 

Gramicidin 

Kanamycin 

Lincomycin 

Neomycin 

Novob ioc in 

Oleandomycin 

Paromomycin 

Penicillins: 
Ampicillin- 



Cloxacillin, sodium 

Dicloxacillin, sodium 

Hetacillin 

Methicilltn, sodium 

Nafcillin, sodium 

Oxacillin, sodiujn 

Penicillin G, benzathine- 

Penicillin G, procaine 

Penicillin G, sodium 

Phenethioillin 



Phenethicillin, potassium 

Phenoxymethylpenicillin (Penicillin V)- 

Phenoxymethylpenicillin, benzathine 

Phenoxymethylpenicillin, hydrabamine — 

Phenoxymethylpenicillin, potasslujn'i 

Ftolymyxin B 

Spectinomycin 

Tetracyclines: 

Chlortetracycline- 



Deraethylchlortetracycline- 

Doxyoycline 

Methacy c 1 ine — 



Oxytetracyoline- 

Tetracycline 

Thiostrepton 

Troleandomyoin 

Tyrothr ic in 

Vancomycin 

*For other uses: 

*Bacitrao in 

Chlortetracycllne 

Cycloheximide-- 

Jfygronyoin B 

Neomyoin- 



Novobiocin- 



CMS. 

PEN. 
QMS. 

CCM. 
MRK, 
LIL, 
PFZ. 
CCM, 
LIL, 

LIL. 

LIL. 

PD. 

ABB, 

ABB. 

SCH. 

PEN. 

BRS. 

X. 

QMS, 
MRK, 
PFZ. 
MRK. 

BRS, 
BRS. 
BRS. 
BRS. 
BRS. 
WYT. 
BRS. 

wn. 

LIL, 
CMS. 
PFZ. 
BRS. 
LIL. 
WTT. 
ABB. 
ABB, 
PFZ. 
ABB. 

ACY, 
ACY. 
PFZ. 
PFZ. 
PFZ. 
ACY, 

Qie. 

PFZ. 
PEN. 
LIL. 

CCM, 
ACY. 
UPJ. 
LIL. 
PEN, 
UPJ. 



PFZ. 

MRK, QMS, PFZ. 

PEN, PFZ, MP. 

MRK, QMS, PFZ, WYT. 



LIL. 



PEN, PFZ, UPJ. 
UPJ. 



WYT. 



MRK, QMS, PRZ, WYT. 



LIL. 



RI^. 



BRS, PFZ, RLS. 



DLI, GPR, PEN, IMP. 



PFZ. 



MEDICINAL CHEMICALS 



115 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer , i567--Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



»Antitiotios — Continued 
*For other uses — Continued 

Oxytetracycline 

Penicillin G, benzathine 

Penicillin G, procaine 

Streptcunyoin 

Tylosin 

»AnticoagulantE : 

Ajuraonium heparin 

Anisindione 

Bishydroxycouraarin — 

Phenlndione — 

»Sodium heparin 

Sodium warfarin 

^Antihistamines : 
*Ant inau s eant s : 

Cyolizine hydrochloride 

Dlraerihydrinate 

Meclizine hydrochloride 

Trimethobenzamide hydrochloride 

Bromodiphenhydramine hydrochloride 

Brompheniramine maleate — 

Carbinoxamine — — 

Carbinoxamine D-tartrate 

Chlorcyclizine hydrochloride 

Chlorothen citrate _— __ 

^Chlorpheniramine maleate 

Cyproheptadine hydrochloride 

Dexbrompheniramine maleate 

Dexohlorpheniramine maleate 

Dimethindene maleate 

Diphenhydramine hydrochloride 

Doxylamine succinate ~ — 

Methapyrllene fumarate 

Methapyrilene hydrochloride ~ — 

Methapyrllene hybenzate 

Phenindamlne tartrate 

*Pheniramlne maleate 

Phenyl toloxamine c itrate 

I^rilamine maleate 

Pyrrobutamine phosphate 

Thenyldiamine hydrochloride — 

Thonzylamine hydrochloride— — - 

Tripelennamine — — 

Tripelennamine citrate 

Tripelennamine hydrochloride 

Triprolldine hydrochloride 

*Anti-inf ective agents ( except antibiotics) ; 
»Arsenic and bismuth compounds: 

Arsanlllo acid^ — __ ______ 

Bismuth dipropylacetate . .. ... 

Bismuth sodium triglycollamate 

Bismuth subsalicylate — _ 

Carbarsone 

Glycobiarsol 

Nltarsone 

Roxarsone _- _ __________ 

Roxarsone sodium 

Sodium arsanilate'- 

*Caprylates and undeoylenates ; 

Calcium undecylenate ~ ___ 

Sodium caprylate 

Sodium undecylenate — 

Undecylenic acid 

Zinc undecylenate 

Mercury compounds: 

Merbromln — . 

Mercuric salicylate ____ 

Nitromersol' -___ 

See footnotes at end of table. 



PFZ. 

WYT. 

LIL, MRK, CMS. 

LIL, MRK, PFZ. 

LIL. 

ABB, WIL. 

SCH. 

ABB, FIN. 

GAll. 

ABB, RIK, WIL. 

EN. 



BUR. 

SRL. 

PFZ. 

HOF. 

PD. 

SCH. 

SCH. 

SCH. 

ABB, BUR. 

ACY. 

HEX, LEM, SCH, SK, x. 

MRK. 

SCH. 

SCH. 

CBP. 

GAH, PD, Rl£. 

BKC. 

ABB. 

ABB. 

LIL. 

HOF. 

HEX, LEM, SCH, x. 

BRS. 

HEX, MRK, RSA. 

LIL. 

SDW. 

NEP. 

CBP. 

CBP. 

CBP, RI£. 

BUR. 



SAL, WHL. 

X. 

BPC. 

MAL, NOR, PEN. 

LIL, FYL, WHL. 

PYL, SDW. 

SAL. 

SAL. 

SAL. 

PYL, SAL. 

WTL. 

CFC, IMK. 

BAC. 

BAC. 

BAC, CFC, LEM, WIL. 

HYN. 
MRK. 
ABB. 



116 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i 967— Continued 



Chemical 



Mamif aoturers ' identification codes 
(according to list in table 22) 



*Anti-lnfective agents (except antibiotics) — Continued 
''Mercury compounds — Continued 

Phenylmercuric acetate 

Phenylmercuric benzoate 

Phenylmercuric borate 

Phenylmercuric chloride ~ 

Phenyljnercuric nitrate — — 

«Thimerosal 



♦Phenolic antiseptics and disinfectants: 

Betanaphthol^ 

Bithionol — 



Chlorothymol- 
Resorctnol-' — 



Resorcinol monoacetate^— 

Thymol 

Thymol iodide — — 

»Piperazlne base and salts: 
♦Piperazine-"-- 



Piperazine adipate 

Piperazine citrate 

Piperazine dihydroehloride- 
Piperazine dlthlocarbamate- 

Piperazine hexahydrate 

Piperazine hydrochloride 

Piperazine phosphate ~ 

Piperazine sulfate — — 

Piperazine tartrate- 



*Quinoline derivatives: 
Amodiaquin- 



Amodiaquin hydroohloride- 
Buquinolate — 



Chloroquine phosphate — — 

*Diiodohydroxyquin 

Ifydroxychloroquine sulfate — _- 

8-i^droxy-5-qulnolinesulfonic acid- 

lodochlorhydroxyquin- 

Oxolinic acid ■■ 

Oxyquinoline- 



Oxyqulnoline benzoate-— 

Oxyquinoline citrate — — 

i<Oxyquinoltne sulfate ■ 

Primaquine phosphate 

*Sul f onamldes : 

Acetyl sulfamethoxypyridazine- 

Acetyl sulflsoxazole 

Azosulf amide 

Dinsed — 



Mafenide acetate- 



Mafenide hydrochloride- 
Phthalylsulfacetamide — 
Phthalylsulfathiazole — 
Succinylsulfathiazole — 
Sulfabenz amide 



Sulfabenzamide, sodium- 



Sulfabromomethazine, sodium- 
Sulfacetamide — — 



Sulfacetamide, sodium- 



Sulfachloropyrazine, sodium- 
Sul fad iaz ine 



Sulfadiazine, sodium- 

Sulfadimethoxine 

Sulfaethidole 

Sulfaguanidine 

Sulfamerazine 



Sulfamerazine, sodium- 
Sul f amethaz ine 



Sulfamethazine, sodlmn- 

Sulfamethizole 

Sulfamethoxazole 



WRC. 

MRK, WRC. 

MRK, WRC. 

MRK. 

MRK, WRC. 

LIL, MED, PYL, SEL. 

ACY, FIN. 

SDH. 

OPC. 

LiM. 

KPT. 

GIV. 

MAL. 



DOW, 
JCC, 

BUR, 
DOW, 
SEL. 
JCC. 
DOW, 
BUR, 
JCC. 
PTL, 



FIM, JCC, UCC. 

PYL. 

JCC. 

FIW, JCC, SEL, WHL. 



JCC. 

JCC, pn,. 



SEL. 



Sulfamethoxypyridazlne- 



PD. 

PD. 

UOP. 

SDW. 

im, PYL, RSA, SRL. 

SDW. 

MRK. 

CBP, PYL. 

NEP. 

IMk, MRK. 

FIS, LEM, MRK. 

FIS. 

FIS, LIM, MRK, PYL. 

PD, SDW. 

ACY. 

HOF. 

SDW. 

SAL. 

SDW. 

SDW. 

LBJ, PYL. 

LEM, MRK, PYL. 

LiW, MRK. 

ACY. 

ACY. 

MRK. 

LFM. 

LEM. 

ACY. 

ACY, LFM. 

ACY. 

HOF. 

ACY. 

ACY, LEW. 

ACY, LEW. 

ACY. 

ACY, LEM. 

ACY. 

ACY. 

HOF. 

ACY. 



See footnotes at end of table. 



MEDICINAL CHEMICALS 



117 



TABLE 13B. — Medicinal chemicals for which U.S. production or sates were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



»Anti-infective agents (except antibiotics) 
*Sulfonamides — Continued 

Sulfanilamide 

Sulfanilanilide 

Sulfanitran 



-Continued 



Sulfapyridine 

Sulfapyridine, sodium 

Sulfaquinoxaline 

Sulfathiazole- 
Sulfathiazole, sodium- 
Sulfisoxazole 



Sulfisoxazole, sodium- 



*<Hher anti-infective agents: 

♦Anthelmintic and antifungal agents: 
Anthelmintic agents: 

Cadmimn anthranilate 



Diethylcarbamazine citrate- 
Gentian violet — _ 

Hexylresorcinol — 

Phenothlaz ine — — 



Pyrvinium pamoate- 
Thiabendazole 

Antifungal agents: 
Benzoic acid^ 



Fuchsin, basic— 
Salioylanilide^- 



*Antiprotozoan and antiviral agents: 
Antiprotozoan agents: 

Aklcmide — — 



Aminitrozole— — — 

2-Amino-5-nitrothiazole- 

Amprolium 

Chlorbetamide 



Cyologuanil pamoate- 
Furazolidone 

Metronidazole 

Nihydrazone — — — - 
Nithiazide 



Nitrophenide — 
Pyrimethamine- 
Antiviral agent: 



*Urinary antiseptics: 
Ammonium benzoate- 
Calcium mandelate- 



Amantadine hydrochloride- 



Ethoxazene hydrochloride- 

Mandelic acid 

Methenamine 



Methenamine hippurate- 
Methenamine mandelate- 

Methylene blue 

Nitrofurantoin 



Phenazopyridine hydrochloride- 
•All other: 

Acriflavine- 

Aminacrine 



MRK. 

LBJ. 

SAL. 

ACT, MRK. 

ACT. 

MRK. 

ACT, LEM, MRK. 

ACY, MRK. 

HOF. 

HOF. 



MAL. 
ACT. 

ACS, SDH. 
HEX, MRK. 
CLV. 

X. 

MRK. 

MON, PFZ. 

ACS. 

LHJ. 



SAL. 

ACT. 

ACT. 

MRK. 

SDW. 

PD. 

NOR. 

RDA. 

NOR. 

MRK. 

ACT. 

BUR. 

X. 

PEN. 

MAL. 

KON. 

MAL. 

HN. 

RIK. 

ARN, 

ACS, 

NOR. 

HOF, 



LEM, NEP, PYL, fiSA. 
ACT. 

KON, NEP. 



Aminacrine hydrochloride- 



Antileprotic and antitubercular agents: 
Aminosalicylic acid- 



Calcium aminosalioylate- 

Dapsone- — 

Isoniazid — — 



Potassium aminosalicylate- 
Pyrazinamide- 



Sodium aminosalioylate- 
Sodlum sulfoxone 



Benzalkonium chloride- 
Bromoform— — 



Camphor, monobromated 

Cetalkonium chloride 

Cetylpyridinium ohloride- 



ACS. 
SDW. 
SDW. 

MI^. 

MI^. 

SDW. 

RIL. 

MLS. 

MRK. 

MLS. 

ABB. 

SDH. 

DOW. 

MAL, PEN. 

FIN, SDW. 

FIN, HEX, NEP. 



See footnotes at end of table. 



118 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



*Anti-infective agents (except antibiotics) 
■sOther anti-infective agents — Continued 
*A11 other — Continued 

Chloramine T 



-Continued 



Chlorobutanol — 

Iodoform^ 

Nalidixic acid- 
Nifuraldezone — 



Nitrofurathiaz ide~ — — 

Nitrofurazone ~ 

Nitromide ~ 

Povidone - iodine oomplex- 



*Antineoplastic agents and local anesthetics: 
Antineoplastic agents: 

Meroaptopurine 

Urethane — 



Vinblastine sulfate 

Local anesthetics: 

Butacaine 

Butacaine hydrochloride — 

Butacaine sulfate 

Butamben picrate- 



Butyl aminobenzoate (ButarabenJ 

Dibuca ine — 



Dibucaine hydrochloride — 

Ethyl aminobenzoate (Benzooaine). 

Isobutyl aminobenzoate 

»Lidocaine 

Oxethazine 



Phenaoaine hydrochloride — 
Piperocaine hydrochloride- 

Pramoxine hydrochloride 

Procaine 



Procaine hydrochloride 

Proparacaine hydroohloride- 

Propoxycaine 

Tetracaine 



Tetracaine hydrochloride—— 

^■Autonomic drugs: 

*ParaEympatholytic ( anticholinergic) 
( except tropane derivatives) : 
■"Quaternary ammonium compounds: 

Ambutonium bromide 

Diphemanil methylsulfate- 



MON. 




BPC, 


PD. 


MAL, 


PEN. 


SDH. 




NOR. 




SCH. 




NOR. 




SAL. 




GAT. 




BUR. 




IMP. 




LIL. 




ABB. 




ABB. 




ABB. 




ABB. 




ABB, 


ICO. 


GBP. 




CBP, 


RSA. 


ABB, 


LEM. 


ICO. 




AST, 


LEM, RI^, SDW 


WYT. 




GAN, 


SDW. 


LIL. 




ABB. 




ABB. 




ABB, 


LM, PFZ. 


OK. 




SDW. 




SDW. 




RSA, 


SDW. 



agents 



Hexocyolium methylsulfate- 

Isopropamide iodide 

Mepenzolate bromide 

Methantheline bromide 

Pipenzolate bromide 

Pralidoxime chloride 

Propantheline bromide 

Thihexinol methylbromide — 

Tridihexethyl iodide 

*Tertiary amines: 



Adiphenine hydrochloride 

Caramiphen edisylate 

Dicyclomine hydrochloride 

Orphenadrine citrate 

Orphenadrine hydrochloride 

Oxyphencycllmine hydrochloride — 
Piperidolate hydrochloride-—— 
Thiphenamil hydrochloride 



Trihexyphenidyl hydrochloride- 



»Sympathomiraetio (adrenergic) agents: 
dl-Arterenal hydroohloride- 



Cinnamedrine hydrochloride ( Cinnamylephedrine 
hydrochloride) . 

Cyclopentamine hydrochloride — 

Epinephrine bltartrate (levo) 



ICO. 

SCH. 

ABB. 

SK. 

LKL. 

SRL. 

LKL. 

NEP. 

SRL. 

SCH. 

ACT. 

CBP. 

SK. 

BJL, BKC. 

RIK. 

RIK. 

PFZ. 

LKL. 

BJL, X. 

ACY, SDW. 

SDW. 
SDW. 

LIL. 
SDW. 



See footnotes at end of table. 



MEDIONAl CHEMICALS 



119 



TABLE 13B. --Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i567--Continued 



Chemical 



^Autonomic drugs — Continued 

*Sympathomime-tic (adrenergic) agents — Continued 
*Isoproterenol salts: 

Isoproterenol hydrochloride 

Isoproterenol sul fate 

Levarterenol bi tartrate 

dl-Metanephrine hydrochloride 

Methoxyphenajnine hydrochloride 

Naphazoline hydrochloride 

Nordefrin hydrochloride- 



dl-Normetanephrine hydrochloride- 

Hylidrin hydrochloride — — — 

Hienylephrine 



Phenylephrine hydrochloride 

^Phenylpropanolamine hydroohloride- 
Propylhexedrine- 



Protoliylol hydrochloride 

Pseudoephedrlne hydrochloride- 
Pseudoephedrine sulfate- 



Tetrahydrozoline hydrochloride 

Other autonomic drugs: 

Ganglionic blocking agent: Hexemethonium chloride. 
Parasympatholytic (anticholinergic) tropane 
derivatives: 

Anisotropine methylbromide 

Benztropine mesylate 

Homatropine- 



Homatropine hydrobromide- 



Manuf acturers ' identification codes 
(according to list in table 22) 



SDW. 



Homatroplne methylbromide -— 

Parasympathomimetic (cholinergic) agents: 

Acetylcholine chloride — 

Methacholine chloride 

Neostigmine bromide- 



Physostigmine salicylate- 
lyridostigmine bromide- 



Sympatholytic ( antiadrenergic) agent: 
maleate. 
»Cardiovascular agents: 
*Cardiao drugs: 

Calcium camphorsulfonate — 

Gitalin 



Ergonovine 



Procainamide hydrochloride- 

Quinidine gluconate 

Quinldine sulfate 



»Rauwolfia and veratrum alkaloids: 

Alkaverv ir — 

Alseroxylon 

Reserplne- 



Raunormine- 



Syros ingopine 

"Vasodilator s : 

Dioxyline phosphate- 
Ethyl nitrite 



Glyceryl trinitrate — 
Isosorbide dinitrate- 



Mannitol hexanitrate 

Nicotinyl alcohol tartrate- 



Pentaerythritol tetranitrate 

"Other cardiovascular agents: 

Antihypertensive agents (except rauwolfia and veratrum 
alkaloids) : 

Hydralazine hydrochloride 

Methyldopa- 



Pargyltne hydrochloride- 
Bioflavonoids: 
Hesperidin- 



Hesperidin methyl chalcone- 

Lemon bioflavonoid 

Naringin— — 

Rutin 



Sclerosing agent: Sodium morrhuate- 



GAN, 
ABB. 
SDW. 
SDW. 

X. 

CBP. 
SDW. 
SDW. 
BKL. 
GAW, 
CTN, 
BKL, 
HEX, 
LKL. 
BUR, 
GAN. 
PFZ. 

RSA. 



EH, X. 

X. 

CTN. 
CTN. 
CTN, HEX. 

MRK, RSA. 

MRK, RSA. 

HEX. 

PEN. 

HOF. 

LIL. 



FIN. 
PEN. 

LiM, QMS. 
HEX. 
HEX. 

PEN, RIK. 

RIK. 

PEN. 

PEN. 

CBP. 

LIL. 
MAL. 
APD. 
APD. 
APD. 
HOF. 
APD. 



CBP. 
MRK. 
ABB. 

SKG. 
SKG. 
SKG. 
SKG. 
PEN. 
MED. 



SDW. 

GAN, HEX, ORT, SDW. 

GAJJ, ICO, NEP, ORT. 

SK. 

GAN. 



120 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list In table 22) 



■>*Central depressants and stimulants: 
»Amphetamlnes : 

*Amphetaintne base and sulfate (raoemlc): 

Amphetamine ( racemic) 

Amphetamine sulfate (racemic) 

Dextroamphetamine 

Dextroamphetamine oarboxymethylcellulose- 

Dextroamphetamine hydrochloride 

Dextroamphetamine phosphate 

^Dextroamphetamine sulfate 

Dextroamphetamine tannate 

Levamphetamine succinate 

Methamphetamine ( dextro) 

Methamphetamine ( levo) 

Methamphetamine ( racemic) 

Methamphetamine hydrochloride ( dextro) 

Methamphetamine hydrochloride (racemic) — 
*Analgesics and antipyretics: 

p-Aminobenzoic acid and salts: 

Aminobenzoio acid 

Calcium aminobenzoate 

Magnesium aminobenzoate 

Potassium aminobenzoate 

Sodium aminobenzoate- 

Anileridine hydrochloride- 

Calcium succinate 

Colohic ine 



Ethoheptazine citrate 

Indomethacin 

Mefenamic acid 

Meperidine hydrochloride — 

Methadone hydrochloride 

Oxycodone hydrochloride 

Oxymorphone hydrochloride- 

Oxyphenbutazone 

Pentazoc ine 

Ehenacetin 



Phenylbutazone 

Ehenyramidol hydrochloride- 
Propoxyphene hydrochloride- 
»Salicylates: 

Aluminum aspirin 

»Aspirin- 



Ethyl salicylate carbonate- 
Magnesium salicylate 

Phenyl salicylate 

Potassium salicylate 

Salicylamide 

Salicylsalicylic acid 

Sodium salicylate 



Strontium salicylate- 
«Antidepressants : 
Amitriptyl ine- 



Desipramine hydrochloride — 

Imipramine hydrochloride 

Nialamide 



Nortriptyline- 



Phenelzine sulfate— — — — — -■■ 

Protriptyline 

^ffiarbiturates : 

5-Allyl-5-( 2-cyolopenten-l-yl) barbituric acid- 
Amobarbital 



Amobarbital, sodium- 
Barbital 



Barbital, sodium- 
Butabarbital 



**Butabarbital, sodium- 

Butalbital 

Butalbital, sodium 

Cyolobarbital- 



Cyolobarbltal, calciiim- 



HEX, ORT. 

ARN, HEX, SK. 

HEX. 

ARN. 

ARN, HEX. 

ARN, HEX. 

ARN, HEX, SK. 

ARN. 

ARN. 

HEX. 

ABB. 

HEX. 

ABB, ARN, GAN, HEX. 

ARN, HEX. 

ATP, MLS, NEP, PEN. 

LIM. 
GAN. 
LEM. 

GAN, LJM. 
GAN, Lai. 
MRK. 

um. 

PEN. 

WYT. 

MRK. 

PD. 

SDW, WYT. 

LIL. 

EN. 

EN. 

GGY. 

SDW. 

MON. 

GGY. 

ore. 

LIL. 



ABB, 

DOW, 

PD. 

MAL. 

DOW, 

HN, 

CFC, 

CFC. 

DOW, 

HFC. 



SCH. 

MLS, MON, NOR, SDG. 



MAL. 
PEN. 
PEN. 



HN. 



MRK. 

GGY, LKL. 
GGY. 

PFZ. 
LIL. 
NEP. 
MRK. 

GAN. 

LIL. 

GAN, LIL. 

GAN. 

GAN. 

ABB, GAN. 

ABB, BPC, GAN. 

GAN. 

GAN. 

SDW. 

SDW. 



MEDICINAL CHEMICALS 



121 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



^Central depressants and stimulants- 
»Barbiturates — Continued 

Hexobarb ital 



-Continued 



Hexobarbltal, sodium — 

Mephobarb ital 

Metharb ital 

Methohexital, sodium — 

Pentobarbital 

Pentobarbital, sodium- 
Phenobarbital —- 



»Phenobarbital, sodium- 

Seoobarbital 

Secobarbital, sodium — 

Talbutal 

Thiamylal, sodium 

Thiopental, sodium 

Vinbarbital- 



*Hypnotios and sedatives ( except barbiturates) ; 
Carbromal 



Ethchlorvynol- 

Ethinamate 

Glutethimide— 
Mecloqualone — 
Methyprylon- 



•'<Skeletal muscle relaxants: 
Carisoprodol- 



Chlorphenesin carbamate- 
Mephenesin- 



Mephenesin carbamate- 

Phenaglycodol 

Styramate- 



*<Succinylcholine chloride — 

Tubocurarine 

*TranquilizerE: 

Azacyclonol hydrochloride- 
Buclizine hydrochloride- 



Chlordiazepoxide hydrochloride- 

Ohlormezanone 

Chlorprothixene 

Diazepam- 



Ectylurea- 
ftydroxyphenamate- 



Hydroxyzine hydrochloride — 

Hydroxyzine pamoate — 

Mebutamate 

^iMeprobamate — 

Methaqualone 

Oxazepam- 



Phenothiazine derivatives: 
Acetophenazine maleate — 
Carphenazine maleate- 



Chlorpromazine hydrochloride- 
Fluphenazine enanthate- 



Fluphenazine hydrochloride- 
Perphenaz Ine- 



Prochlorperazine maleate- 
Promazine hydrochloride — 
Promethazine hydrochloride- 



Trifluoperazine hydrochloride- 

Triflupromazine hydrochloride- 

Tybamate- 



^*Other central depressants and stimulants: 
Anticonvulsants: 
Diphenylhydantoin- 



Diphenylhydantoin, sodium- 

Bthosuximide ■ 

Ethoto in-——— — 

Methsuximide— — 

Paramethadione ___— 

Phenacemlde 

Phensuximide — —— — 



GAN, SDW. 

SDW. 

SDW. 

ABB. 

LIL. 

ABB, GAN. 

ABB, GAN, PD. 

GAH, MAL. 

GAN, MAL, SDW. 

GAIJ. 

GAN, LIL. 

SDW. 

PD. 

ABB. 

X. 

PD. 

ABB. 

LIL. 

CBP. 

NEP. 

HOF. 

BKL. 

UPJ. 

BKL, HEX. 

QMS. 

LIL. 

ARP. 

ABB, BUR, SDW. 

ABB, QMS. 

BKC. 
PFZ. 
HOF. 
SDW. 
HOF. 
HOF. 

X. 

ARP. 

PFZ. 

PFZ. 

BKL. 

ABB, BKL, PEN. 

HEX. 

wn. 

SCH. 

WYT. 

SK. 

CMS. 

CMS, SCH. 

SCH. 

SK. 

WYT. 

wrr. 

SK. 

CMS. 

BKL. 



PD. 

PD. 

PD. 

ABB. 

PD. 

ABB. 

ABB. 

PD. 



122 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' Identification codes 
(according to list in table 22) 



^Central depressants and stimulants — Continued 

*Other central depressants and stimulants — Continued 
Antitussives: 

Benzonatate 

Carbetapentane citrate — 

Dextromethorphan hydrobromide 

Dimethoxanate hydrochloride 

Ethylmorphine hydrochloride 

Ifydrocodone b itartrate 

General anesthetics: 

Tribromoethanol 

Vinyl ether 

Stimulants : 

Benzphetamine hydrochloride 

Caffeine: 

Natural 

Synthetic 

Caffeine, citrated 

Caffeine sodium benzoate — 

Chlorphentermine hydrochloride- — ■ ■■ — — — 

Deanol acetamidobenzoate -— _ — 

Diethylpropion hydrochloride — — - 

Nikethamide-- ~ ~ — — 

Phendimetrazine tartrate — — — 

Phentermine ~ — — _— — _ 

Sodium succinate -— — ~ 

*Dermatological agents: 

Allantoin — — — 

Aluminum phenolsulfonate — — ~— — 

Ammonium phenolsulfonate — _— 

^isamith subgallate- — — — -— — _ . 

Dipropylene glycol salicylate 

Glycol salicylate 

Homomenthyl sal icylate 

p-Methoxycinnamic acid, 2-ethoxyethyl ester 

■'<Salicylie acid-*- — ~ 

Scarlet red 

Sodiura phenolsulfonate __—___- 

Zinc phenolsulfonate — — — 

^Expectorants and mucolytic agents: 

Ethylenediamlne diiiydriodide 

*Guaiaool and its derivatives: 

Glyceryl guaiacolate 

Guaiacol— _ — — — . — — 

Potassium guaiacolsulfonate — -— 

lodinated glycerol -. .. — — 

lodobrassid— ~— ___— — ___ 

Lobel ine sulfate — ~ _— 

Terpln hydrate — — -____ 

Thonzonlum bromide— — — — — — 

■••GaBtrointestinal agents: 

*Betalne base, hydrate, and hydrochloride: 

Betaine base— — — -_— — 

Betaine hydrate 

Betaine hydrochloride 

^Choleretics and hydrocholeretics: 

Bile acids, oxidized 

Dehydrocholic acid— . . 

Florantyrone — — — — — 

Iron bile salts 

Ox bile extract 

Sodium dehydrocholate _— 

Tocamphyl 

^Choline chloride ( all grades) : 

Feed grade -. . ... 

Medicinal grade — - 

Technical grade 

^^fethionlne and its hydroxy analogue: 

Methionine (feed grade) 

Methionine (medicinal grade) — — — _ 

See footnotes at end of table. 



CBP. 






EFZ. 






HOF. 






BKl. 






MAL, 


MRK, 


PEN. 


EN, 


MAL, 


MRK. 


SDW. 






MRK. 






X. 






GNF, 


MW. 




PFZ. 






MAL. 






MAL. 






NEP. 






RIK. 






BKC, 


GAN. 




CBP. 






X. 






HEX. 






LEM. 






FIN, 


HFT. 




MAL. 






SAL. 






BKC, 


MAL, 


PEN. 


SBC. 






RDA. 






ICO. 






GIV. 






DOW, 


HN, 


MON, SDH. 


ACS. 






MAL, 


SAL. 




MAL. 






CLV, 


WHL. 




GAJJ, 


PEN. 




MON. 






HK. 






X, X 






CBP. 






ABB. 






LM, 


PEN. 




NEP. 






HIT, 


MAL. 




HFT. 






CFC, 


HFT, 


LEM. 


SRL, 


WIL. 




WIL. 






SRL. 






LIL. 






ABB. 






WIL. 






X. 






CM, 


DA, 


DLI, HFT, TMH 


HIT. 






GAF, 


RH. 




DOW. 






DOW, 


LEM. 





MEDICINAL CHEMICALS 



123 



TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



^Gastrointestinal agents — Continued 

<41ethionine and its hydroxy analogue — Continued 
Methionine, hydroxy analogue, calcium salt — 
»Other gastrointestinal agents: 

Choline bicarbonate 

Choline bltartrate 

Choline citrate (Tricholine citrate) 

Choline dihydrogen citrate 

Dihydroxy aluminum aminoacetate- — — — — 

Magnesium citrate — — — — — 

Pectin 

Phenolphthalein 

Phenolphthaletn, yellow 

Podophyllum 

Polycarbophil 

Sitosterols — ~ -— 

Sodium carboxymethylcellulose 

Sodium tartrate — 

*Hormones and synthetic substitutes: 

Anabolic agents and androgens: 

Fluoxymesterone — — 

Testosterone cypionate 

Testosterone phenylacetate — — — — 

Antithyroid agents: 

lothiouraoil, sodium 

Methimazole — — . . . . — 

Thlouracil 

Corticosteroids : 

Betamethasone 

Betamethasone acetate — 

Betamethasone phosphate ____ 

Betamethasone valerate 

Cortisone 

Cortisone acetate _— __ 

Dexamethasone — 

Dexamethasone acetate — — . 

Dexamethasone phosphate 

Dichlorisone acetate 

Fludrocort isone acetate 

Fluorcmetholone — — — — — 

9-Fluoroprednlsolone acetate — — 

Fluprednisolone 

Hydrocortisone — — ■ — 

}^drocortisone acetate — — -— 

Ifydrocortisone phosphate- — 

Ifethylprednisolone 

Prednisolone — — 

Prednisolone acetate 

Presdnisolone pivalate — — 

Prednisone- — __— __ __ 

Triamcinolone — — — 

Estrogens : 

Chlorotrianisene 

Dienestrol diacetate 

Diethylstilbestrol 

Diethylstilbestrol dipropionate 

Natural estrogenic substances 

Plperazine estrone sulfate 

Progestogens: 

ll|i-Ifydroxy-6a-methyl progesterone 

Medroxyprogesterone acetate 

Progesterone _— _ , 

^Synthetic hypoglycemic agents: 

Acetohexamide — — . 

Chlorpropamide — _______ 

Phenformin hydrochloride_— — . 

Tolazamide -., ■ . ___. 

Tolbutamide 

*Other hormones; 

Corticotropin (ACTH) (pituitary) 

Insulin ( pancreas) —____— _ 



DUP, MON. 

COM. 

ACY, HFT. 

ACT, HFT. 

ACT, HFT. 

CHT. 

MAL. 

SKG. 

MON. 

WLI. 

ABB. 

WLI. 

UPJ. 

GBP. 

MAI. 



UPJ. 
UPJ. 
CBP. 

GBP. 
LIL. 
ACT. 

SCH. 

SGH. 

SGH. 

SCH. 

UPJ. 

MRK, SCH, UPJ. 

MRK, SCH. ■ 

SCH. 

MRK. 

SCH. 

UPJ. 

UPJ. 

UPJ. 

UPJ. 

MRK, UPJ. 

MRK, UPJ. 

MRK. 

UPJ. 

MRK, UPJ. 

SCH, UPJ. 

CBP. 

MRK, SCH, UPJ. 

ACY, QKB. 

BKG. 

SCH. 

CTN, LIL. 

CTN. 

ORG. 

ABB. 

UPJ. 



LIL. 
PF2. 
BKL. 

X. 

HST, X. 

ARP, ORG, WIL. 
ARP, LIL. 



124 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 13B.— Medicinal chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i567--Continued 



Chemical 



Maniifacturers ' Identification codes 
(according to list in table 22) 



*Renal-acting and edema-reducing agents: 
^Mercurial diuretics: 

Meralluride ~ 



Mersalyl acid 

Sodium mercaptoraerin- 
Sodium mercurophylline- 



*Theobromine and theophylline derivatives: 
Ambuphylltne- 



*Aminophy 11 ine 

Aminophylline sodium biphosphate- 

Oxtr iphy 11 ine 

Theobromine sodium salicylate 

Theophylline monoethanolamine 

Theophylline sodium glycinate- 



■lOther renal-acting and edema-reducing agents: 
AcetElzolamide — — 



Benzothiadiazine derivatives: 

Bendroflumethiazide 

Benz thiazide — — — — 



Chlorothiazide--—- 

Flumethiazide 

ftydrochlorothiazide- 

Methyclothiazide 

Polythiazide 

Trichlorme thiazide — 

Chlorthalidone 

Diohlorphenamide 

Ethacrynio acid 

Probenec id — 



Spironolactone- 
Triamterene 



^Therapeutic nutrients: 
*Amiiio acids and salts: 

Aminoacetlc acid (glycine) ^- 

Amino acid mirtures-— 

Arginine glutamate- 



Aspartic acid and salts: 

Aspartic acid 

Magnesium aspartate 

Potassium aspartate 

Beta-alanine 



Glutamic acid and salts: 
Ammonium glutamate 



Calcium glutamate— 
Glutamic acid- 



Glutamic acid hydrochloride- 

Potassium glutamate 

lysine (feed grade)-— -^— 

lysine hydrochloride-— 

Rienylalanlne- 



«Calcium gluconate— 

Other therapeutic nutrients: 
Calcium glucoheptonate 



Calcium lactophosphate- 
Calcium levulinate- 

Calcium phytate 

Copper gluconate 

Ferrcfus gluconate — 
Fructose -___ 



Liver concentrate 

Liver, desiccated 

Magnesium gluconate- 
Manganese gluconate- 
Potassium gluconate- 



Sodlum glycerophosphate 

Witamins: 

Witamin A alcohol and esters: 
Vitamin A acetate ( feed grade) - 



Vitamin A acetate (medicinal grade) 
Vitamin A alcohol 



See footnotes at end of table. 



LKL. 
SDW. 
WYT. 
FIN. 

GAU, LM. 

GAN, Lm, SRL. 

GAN. 

MEP. 

GLY. 

LIL. 

CUT. 

ACY. 

QMS. 

PFZ. 

MRK. 

QMS. 

ABB, CBP, MHK. 

ABB. 

FFZ. 

SCH. 

GGY. 

MRK. 

MRK. 

MRK. 

SRL. 

SK. 



BPC. 

ABB, CUT, STA. 

ABB. 

ACS, HEX. 
WYT. 
WYT. 
UA. 

BJC. 

Lm. 

Bic, Lm. 

IMC, Lm. 

mC, LM. 

MHK. 

MRK. 

SDW. 

MAL, PFZ, WHL. 

PFN. 

MAL. 

PYL. 

STA. 

PFZ. 

PFZ, SDW. 

DLL 

WIL. 

WIL. 

PFZ. 

PFZ. 

PFZ. 

SEL. 



HOF. 

HOF, PFZ. 
CW, HOF. 



MEDICINAL CHEMICALS 



125 



TABLE UB.— Medicinal chemicals for which U.S. production or sales were reported identified by 

manufacturer, 196 7- -Continued 



ChemlcEl 



Witamins — Continued 

«Vltamin A alcohol and esters- 
Vitamin A natural esters— - 



-Continued 



'A^'itamin A palmitate ( feed grade) - 



Vitamin A palmitate (medicinal grade) - 
Witamin B-complex: 
♦Niacin: 

Feed grade- 



Medicinal grade- 
*Niac inamide - 



♦Pantothenic acid and derivatives: 
Calcium pantothenate (dextro)- 



*Calcium pantothenate (racemic) (feed grade) 

Calcium pantothenate (racemic) (medicinal 

grade) . 
Calcium pantothenate (racemic) - calcium chloride 

complex. 
Derpanthenol- 



Panthenol ( racemic) - 
Sodium pantothenate- 
♦Riboflavin: 

Feed grade 

Medicinal grade 



♦Other B-complex vitamins: 
Biotin 



Cyanooobalamin: 

Feed grade 

Medicinal grade — — 
U.S. P. crystalline- 



Cyanocobalamin with intrinsic 

Folic acid 

Inositol 



factor concentrate — 



Magnesium nicotinate- 



Niaoinamide hydrochloride 

jyridoxine hydrochloride 

Riboflavin-5-phosphate, sodium- 
Sodium nicotinate — 



Thiamine hydrochloride- 
Thiamine mononitrate—— 
♦Vitamin C: 

♦Ascorbic acid- 



Calcium ascorbate- 
Sodium ascorbate- 



♦Vitamin D2 (Ergooalciferol)- 
♦Vitamin E: 

d-Alpha tocopherol- 



dl-Alpha tocopherol 

d-Alpha tocopheryl acetate- 
dl-Alpha tocopheryl aoetate- 



dl-Alpha tocopheryl acetate ( feed grade) - 
d-Alpha tocopheryl acid succinate 



dl-Alpha tocopheryl acid succinate 

Vitamin K: 
<4tenadione 



<4tenadione sodium bisulfite 

♦Other vitamins: 

Beta-carotene ( Provitamin A) — 
Cholecalciferol (Vitamin D3) — 

Phytonadione (Vitamin K^) 

'^tLscellaneous medicinal chemicals: 
Diagnostic agents: 

Ptoentgenographic contrast media: 
Acetrlzoate, sodium- 



Dlatrizoate, meglumlne- 

Diatrlzoate, sodium 

Dlprotrizoate, sodium — 
lodohippurate, sodium — 

lodopyracet — — — 

lopanoio acid 

lophendylate- 



lothalamate, meglumine- 



Manuf acturers ' identification codes 
(according to list in table 22) 



CW. 

EK, HOF, PF2. 

EK, HOF, PFZ. 



CKl, MRK, HEP, RIL. 
DA, MRK, RIL, SCR. 
MRK, MEP, PD, RIL, SCR. 



CKL, DA, 


DLI, 


HFT. 


DA. 






CKL, DA, 


HFT. 




HOF. 






HOF, PD. 






PD. 






CCM, GPR, 


HOF, 


MRK, PMP 


HOF, MRK. 






HOF. 






GPR, MRK, 


IMP. 




mC, MRK. 






MRK. 






WIL. 






ACT. 






STA. 






NEP. 






MEP. 






HOF, MRK. 






HOF. 






NEP. 






HOF, MRK. 






HOF, MRK. 






HOF, MRK, 


PFZ, 




PFZ. 






HOF, MRK, 


PFZ. 




DLI, PHF, 


SCR, 


vm. 


CW, EK. 






HOF. 






CW, EK. 






HOF. 






HOF. 






CW, EK. 






HOF. 






ABB, HET, 


HFT, 


WHL. 


ABB, DLI, 


HET, 


HFT, WHL. 


EK, HOF. 






DA, DLI, 


PHF. 




MHK. 






MAL. 






SDW. 






SDW. 






MAL. 






MAL. 






SDW. 






SDW. 







MAL. 



126 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 13B, 



--Medicinal chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



^Miscellaneous medicinal chemicals — Continued 
Diagnostic agents — Continued 

Roentgenographic contrast media—Continued 

lothalamate, sodium ~ 

Methiodal, sodium- 



Other diagnostic agents: 

Evans blue (Blood volume determination) — 
Indooyanine green ( cardiac output test) — - 

Metyrapone (pituitary function test) 

Hematological agents (except anticoagulants): 

Aminocaproic aold- 



Cellulose, oxidlzed- 



Dextran (plasma expander) - 
Smooth muscle relaxants: 
Alverine — 



Alverine oitrate- 



Alverine hydrochloride 

Papaverine hydroohloride- 
Sodium benzyl succinate- 



Unclassified medicinal chemicals: 
Allopurinol— — — — . 



Berberine hydrochloride- 
Hydrastine- 



Hydrastine hydrochloride- 



Penicillamine (copper chelating agent) - 



MAL. 

SDW. 

NEP. 

X. 

CBP 

ACY. 
EKT. 
PHR. 

CTN. 
CTN. 
CTN. 
LIL. 
LEM. 

BUR. 

ABB, PEN. 
PEN. 
PEN. 
MRK. 



See table 7B for producers of the technical grade. 
See table 2IB for producers of the technical grade. 



FLAVOR AND PERFUME MATERIALS 



127 



Flavor and Perfume Materials 



TABLE 14B. --Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer , 1967 

[ Flavor and perfume materials for which separate statistics are given in table KA are marked below with an asterisk 
(*); those not so marked do not appear in table lAA because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Material 



Manufacturers' identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIALS, CYCLIC 
Bfmenoid and Naphthalenoid 

2'-Acetonaphthone 

Acetophenone 

5-Acetyl-l,l,2,3,3,6-hexamethylindan 

p-Allylanisole 

i-Allyl-l,2-dimethoxybenzene (<i-Allylveratrole ) 

*4-Allyl-2-methoxyphenol (Eugenol) 

^-Allyl-2-methoxyphenol acetate (Eugenyl acetate) 

■"■A-Allyl-l, 2 -(methylenedioxy) -benzene (Safrole) 

Allyl phenoxy acetate 

*p-Anisaldehyde 

Anisole (Methyl phenyl ether) 

*Anisyl acetate 

Anisyl butyrate 

Anisyl formate 

Other anisyl esters 

*Benzophencne 

*Benzyl acetate 

Benzly acetoacetate 

»Benzyl alcohol 

Benzyl benzoate 

*Benzyl butyrate 

Benzyl cinnamate 

Benzyl ether : 

Benzyl formate 

»Benzyl glyceryl acetal 

Benzyl isopentyl ether 

l-(Benzyloxy)-2-methoxy-<i-propenylbenzene (Benzyl iso- 
eugenyl ether). 

*Benzyl phenylacetate 

*Benzyl propionate 

»Benzyl salicylate 

'i-tert-Butyl -2 ' , 6' -dimethyl -3 ' , 5 ' -dinitroacetophenone 

(Musk ketone). 
6-tert-Butyl-3-methyl-2,i-dinitroanisole (Musk ambrette)- 

p-tert-Butyl-a-methyl hydrocinnamaldehyde 

l-tert-Butyl-3,4,5-trimethyl-2,6-dinltrobenzene 

5-tert-Butyl-2,'i,6-trinitro-m-xylene (Musk xylol) 

Carvacrol 

Cinnamaldehyde 

Cinnamic acid 

»Cinnamyl acetate 

*Cinnamyl alcohol 

»Clnnamyl anthranilate 

»Cinnamyl propionate 

*Coumarin 

Dihydronordicyolopentadienyl acetate 

p-Dimethoxybenzene (Dimethylhydroquinone) 

l,2-Dimethoxy-<4-propenylbenzene ("i-Propenylveratrole) 

p-a-Dimethylbenzyl alcohol 

3,7-Dimethyl-l,6-octadien-3-yl benzoate (Llnalyl benzoate) 
3,7-Dimethyl-2,6-octadlenylphenylacetate (Geranyl phenyl- 
acetate). 

a,a-Dimethylphenethyl acetate 

a,a-Dimethylphenethyl alcohol 

Diphenylraethane (Benzylbenzene) 

l,3-Diphenyl-2-propanone (Dibenzyl ketone) 

6-Ethoxy-m-anol ( Propenylguaethol ) 

3-Ethoxy-'4-hydroxybenzaldehyde (Ethyl vanillin) 

2-Ethoxynaphthalene 



GIV, UOP. 






GIV. 






?m. 






GIV. 






GIV, ICO. 






FB, GIV, ICO, 


IFF, 


LUE, 


GIV. 






FB, GIV, OPC. 






GIV. 






GIV, OPC, UNG 


UOP 




GIV. 






GIV, RT, UOP. 






RT. 






RT. 






RT. 






GAF, GIV, NEC 


PD, 


UOP. 


GIV, OPC, SHL 


UOP 




RT. 






BPC, OPC, SHL 


UOP, 


VEL 


MON, OPC, PFZ 


UOP 


VEL 


FB, GIV, UOP. 






GIV, UOP. 






OPC, SHL. 






GIV, RT, UOP. 






GIV, RT, VLY. 






GIV. 






GIV, UOP. 






GIV, MYW, RT, 


UOP. 




FB, GIV, UOP. 






GIV, OPC, RT, 


UNG, 


UOP. 


GIV. 






GIV. 






GIV. 






GIV. 






GIV. 






GIV. 






FB, OPC, UOP. 






BPC. 






GIV, RT, UOP. 






FB, GIV, NEO, 


UOP. 




FEL, GIV, RT. 






GIV, RT, UOP. 






DOW, RDA, UOP. 






GIV. 






ICO. 






GIV, ICO. 






GIV, UOP. 






HOF. 






GIV. 






GIV, IFF. 






GIV, IFF. 






ARA. 






GIV. 






ICO, SHL. 






MON, RDA. 






GIV, UOP. 







m 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 14B. --Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer, i 567- -Continued 



Material 



Manufacturers' identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued 

Benzenoid and Naphthalenoid'-Continued 

Ethyl anisate (Ethyl p-methoxybenzoate) 

Ethyl anthranilate 

Ethyl cinnamate 

Ethyl a, p-epoxy-P-methyliiydroclnnamate 

2-Ethylhexyl salicylate 

«Ethyl phenylglycidate 

Ethyl salicylate 

3 '-Ethyl-5 ', 6 ', 7 ' , 8 ' -tetrahydro-5 ' , 5 ', 8 ', 8 ' , -tetramethyl- 
2 '-acetonaphthone. 

a-Hexyleinnamaldehyde 

Hydratropaldehyde 

■»Hydratropaldel^fde, dimethyl acetal 

**-HydroGoumarin 

Hydroxycitronellalmethyl anthranilate 

Indole 

Isoamyl phenylacetate 

Isobutyl cinnamate 

*Isobutyl phenylacetate 

2-Isobutylquinoline 

■»Isobutyl salicylate 

*Isopentyl salicylate 

p-Isopropylbenzaldehyde (Cumaldehyde) 

p-Isopropylbenzyl alcohol 

p-Isopropyl-a-me thy Ihydrocinnamaldehyde (Cyclamen aldehyde) 

6-Isopropylquinoline 

p-Mentha-1, 8-diene (Limonene) 

Menthyl anthranilate 

*<V'-Methoxyacetophenone (Acetanisole) 

p-Methoxybenzyl alcohol (Anisyl alcohol) 

o-Methoxyclnnamaldehyde 

2-Methoxynaphthalene 

l-(p-Methoxyphenyl)-l-pentene-3-one 

«2-Methoxy-4-propenylphenol (Isoeugenol) 

A'-Methylacetophenone 

Methyl anisate (Methyl p-methoxybenzoate) 

p-Methylanisole 

*Methyl anthranilate 

Methyl anthranilydene-p-isopropylmethyl hydrooinnamal- 

dehyde. 
Methyl benzoate 

»oi-Methylbenzyl acetate (Styralyl acetate) 

»c<-Methylcinnamaldehyde 

Methyl cinnamate 

• 6-Methylcoumarin 

l,2-(Methylenedioxy)-'4-propenylbenzene (isosafrole) 

p-Methylhydratropaldehydfe 

Methyl N-methylanthranilate 

Methyl phenylacetate 

*Methyl salicylate 

l,l,3,3,5-Pentamethyl-<i,6-dinltroindan 

»a-Pentyleinnamaldehyde 

»Phenethyl acetate 

Phenethylacetoaoetate 

Phenethyl alcohol 

Phenethyl benzoate 

Phenethyl butyrate 

Phenethyl formate 

»Phenethyl isobutyrate 

Phenethyl isovalerate 

»2-Phenethyl phenylacetate 

Phenethyl propionate , 

Phenethyl salicylate 

»2-Phenoxyethyl isobutyrate 

2-Phenoxyethyl propionate 

Phenylacetaldehyde 

Phenylacetaldehyde, dimethyl acetal 

o-Phenylanisole (2-Methoxybiphenyl ) 

'4-Phenyl-3-buten-2-one (Methyl styryl ketone) 



ICO. 




FB. 




GIV, 


UOP. 


GIV, 


PFW, RT. 


FEL, 


ICO. 


GIV, 


RT, UOP. 


FB, 


UOP. 


GIV, 


UOP. 


GIV, 


IFF, UOP. 


GIV, 


IFF, UOP. 


GIV, 


IFF, RT, UOP. 


GIV, 


ICO, UOP. 


GIV. 




GIV. 




GIV. 




RT. 




FB, 


GIV, OPC, RT, UOP. 


FMT. 




FB, 


GIV, UOP. 


FB, 


GIV, OPC, UOP. 


GIV. 




GIV. 




GIV, 


RDA. 


FMT. 




RT, 


SKG. 


PFW. 




GIV, 


ICO, OPC, UOP. 


GIV, 


UOP. 


x. 




GIV, 


UOP, .VLY. 


GIV. 




GIV, 


SHL, UOP, VLY. 


UOP. 




ICO. 




GIV, 


UOP. 


FB, 


GIV, MEE, OPC, SHL, UNG 


RDA. 




HN, 


VLY. 


GIV, 


UNG, UOP. 


FB, 


GIV, UOP, VLY. 


FB, 


ICO, UOP. 


GIV. 




GIV. 




GIV. 




GIV, 


OPC. 


GIV, 


UOP. 


CFC, 


DOW, HN, MON, PEN. 


GIV. 




GIV, 


IFF, RDA, UOP, VLY. 


GIV, 


IFF, NEO. 


RT. 




IFF. 




IFF. 




GIV. 




IFF, 


RT, UOP. 


GIV, 


IFF, RT, UOP. 


GIV, 


RT, UOP. 


GIV, 


IFF, RT, UOP. 


GIV, 


UOP. 


GIV, 


UOP. 


GIV, 


IFF, UOP. 


IFF. 




GIV, 


UOP. 


GIV, 


UOP. 


GIV. 




FB, 


RT, UOP. 



FLAVOR AND PERFUME MATERIALS 



129 



TABLE 14B. --Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer, i 967- -Continued 



Material 



Manufacturers' identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued 
Benzfnoid and Naphthalenoid--Cont\mjeii 

•3-Phenyl-l-propanol (Hydrocinnamic alcohol) 

3-Phenylpropyl acetate 

3-Phenylpropyl cinnamate 

«Piperonal (Heliotropin) 

»p-Propenylanisole (Anethole) 

p - Propy lani sole ( Dihydroane thole ) 

o-Propylphenylethyl alcohol 

^Sweeteners, synthetic: 

Cyclohexanesulfamic acid 

Cyclohexanesulfamic acid, calcium salt 

Cyclohexanesulfamic acid, sodium salt 

Saccharin (l,2-Benzisothiazolin-3-one, -1,1-dioxider-- 

Saccharin, calcium salt 

Saccharin, sodium salt 

p-Tolualdehyde 

p-Tolylacetaldehyde 

»p-Tolyl acetate 

p-Tolyl phenylacetate 

a-(Trichloromethyl)benzyl acetate (Rosetone) 

Vanillin ('4-Hydroxy-3-methoxybenzaldehyde) 

Verdyl propionate 

Terpenoid, He terocyc I ic , and Alicyclic 

Allyl cyclohexyl propionate 

Amyris acetate 

Bornyl acetate 

p-tert-Butylcyclohexanone 

p-tert-Butyloyclohexyl acetate 

p-Caryophyllene 

Cedrenol 

Cedrol 

»Cedryl acetate 

2-Cyclohexylcyclohexanone 

Cyclopentanone 

Dihydroterpinyl acetate 

Essential oils, chemically modified: 

Acetyl cedrene 

Cedarwood acetate ' 

Clove leaf oil terpenes 

Clove stem oil, acetylated 

trans -Decahydro-P-naphthol 

Ethyl oxyhydrate 

Ceranonitrile 

Guaiacwood acetate 

'i-('i-Hydroxy-'i-methylpentyl)-3-cyclohexene-10-carbox- 
aldehyde. 

Lavandin, acetylated 

t^rcenyl acetate 

Ocimenyl acetate 

Onega decenol 

Piperonal terpenes 

Rosemary oil, acetylated 

Sassafrass oil, hydrogenated 

Tetrahydro alloocimenol 

Ethylene brassylate 

Ethylene glycol trideoandiote 

a- Furfural mercaptan 

2-Heptylcyclopentanone 

Hexadecen-8-olide (Ambrettolide) 

16-Hydroxyhexadecanoic acid, o-laotone (Hexadecanolide) 
2-Hydroxy-3-methyl-2-cyclopenten-l-one (Methyl cyclo- 
pentanolone) . 

2-Hydroxy-3 -methyl -2 -cyclopenten-1 -one isovalerate 

3-Hydroxy-2-ethyl-A-pyrone (Ethyl maltol) 

3-Hydroxy-2-methyl-4-pyrone (Maltol) 

"i-Hydroxynonanoic acid, y-lactone (y-Nonalactone) 



FB, GIV, 


UOP. 








GIV, UOP. 










FB. 










GIV, SHL, 


UOP. 








ARZ, GLD, 


HNW, 


HPC, 


NCI. 




FB, GIV. 










GIV. 










ABB. 










ABB, DRW, 


MON, 


NRS, 


PBY, 


PFZ, UNS 


ABB, MON, 


NRS, 


PBY, 


PFZ, 


UNS. 


MEE, MON. 










MEE, MON, 


PBY. 








MEE, MON. 










GIV, HN. 










GIV. 










FB, GIV, 


ICO, 


UOP. 






GIV. 










ICQ, UOP. 










MON, SLV. 










GIV. 











IFF. 
VLY. 
GIV. 

IFF, UOP. 

IFF, NEO, UNG, UOP. 



GIV. 

GIV. 

FEL. 

DOW, 

IFF, 

FB, 

GIV. 

GIV, 

GIV, 

GIV. 

ARA. 

GIV. 



IFF. 

FB. 

SHL. 

FB. 

IFF. 

FEL, FLO, LUE, PFW, RT, VND. 

IFF. 

FB, GIV. 

IFF. 

GIV, UNG. 

IFF. 

IFF. 

IFF 

SHL. 

FEL. 

GIV. 

IFF. 

RDA, VLY. 

RDA. 

EVN, RT. 

IFF. 

IFF. 

IFF. 

DOW, RT. 



RT. 
PFZ. 

DOW, PFZ. 
GIV. 



130 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 14B. --Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer, 7967- -Continued 



Material 



Manufacturers' identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued 

Terpenoid, Heterocyclic, and Ali eye lie- -Continned 

4.-Hydroxyoctanoio acid, Y-la°"tone (Y-Octalactone) 

A-Hydrcxyundecanoic acid, Y-la^'tone (y-Undecalactone)--- 
»Ionones : 

a-Ionone 

P-Ionone 

lonone (ct- and P-) 

Isobomeol 

»Isobomyl acetate 

Isobornyl propionate 

Isomenthone 

2-Isopropylcyclohexanol 

Menthadiene-7-carbinol 

p-Mentha-6,8-dien-2-ol (Carveol) 

p-Mentha-6,8-dien-2-one (Carvone; Carvol) 

»p-Menthan-3-one (Menthone) 

p-Menth-8-en-3-ol (Isopulegol) 

p-Menth-l-en-8-ol butyrate (Terpinyl butyrate) 

p-Menth-4(8)-en-3-one (Pulegone) 

l,l-p-Menthen-6-yl-l-propanone 

*Menthol, synthetic; 

Tech 

U.S.P 

Menthyl acetate 

*Methylionones : 

6-Methyl-a-ionone 

Methylionone (o.- and P-) 

2-(2-Methyl-l-propenyl)-<i-inethyl-tetrahydropyTane (Rose 
oxide). 

Neryl acetate prime 

Nopyl acetate 

Santalol 

Santalyl acetate 

»Terpineols : 

a-Terpineol 

p-Terpineol 

Terpineol (a- and P-) 

Terpinol hydrate (terpin hydrate), tech 

»a-Terpinyl acetate 

C( -Terpinyl propionate 

3,5,5-Trimethylcyclohexanol (m-Homomenthol) 

l-(2,6,6-Trimethyl-2-cyolohexen-l-yl)-l,6-heptadien-3- 

one (Allyl-a-ionone) . 
'l-(2,6-Trimethyl-l-cyclohexen-l-yl)-3-methyl-3-buten-2- 
one (|3-Isomethylionone) . 

Vemaldehyde 

Vetivenol 

»Vetivenyl acetate 

FLAVOR AND PERFUME MATERIALS, ACYCLIC 

Ace tylbutyryl (2,3 -Hexanedione ) 

Acetyl valeryl (2,3-Heptanedione) 

Allyl cinnamate 

Allyl furcate 

Allyl hexadienoate 

»Allyl hexanoate 

Allyl isothlocyanate (Synthetic mustard oil) 

Allylmercaptan 

Allyl octanoate (Allyl caprylate) 

Allyl sulfide 

Amyl caprylate 

Amyl propionate 

Brazinol 

Butyl butyryl lactate 



GIV, RT. 
FB, GIV. 

GIV, HOF, IFF, MYW, UOP. 

HOF, MYW, UOP. 

GIV, LUE, MYW, UNO, UOP. 

RDA. 

FB, GIV, OPC, RDA, UNO, UOP. 

GIV. 

GIV, UOP. 

GIV. 

RT. 

FB. 

FB, FRM, OPC. 

GIV, HNW, NEC. 

GIV. 

RT. 

GIV. 

GIV. 

GIV, NEO. 

GIV, GLD, HNW, NEO. 

GIV. 

GIV, IFF, MYW. 

GIV, IFF, LUE, MYW, UNG, UOP. 

GIV. 

GIV. 

RT, SHL, VLY. 

GIV, IFF. 

GIV. 

GLD, HPC. 

HNW. 

GIV, NEO. 

HPC. 

GIV, IFF, NEO, RDA, UNG, UOP. 

GIV, UOP. 

ICO. 

GIV, IFF. 

HOF. 

GIV. 

GIV, UOP. 

FB, GIV, IFF, NEO, UOP. 



RT. 

RT. 

RT. 

RT. 

RT. 

FB, GIV, PFW. 

MRT. 

RT. 

RT. 

RT. 

VLY. 

GIV. 

RDA. 

ICO, RT. 



FLAVOR AND PERFUME MATERIALS 



131 



TABLE 14B. --Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer, 7 967- -Continued 



Material 



FLAVOR AND PERFUME MATERIALS, ACYCLIC--Continued 

Butyl 10-undeoylenate 

»Citral (Geranial and Neral) 

»Citronellyl acetate 

Citronellyl butyrate 

»Citronellyl formate 

»Citronellyl isobutyrate 

Citronellyl propionate 

Decanal (Capraldehyde) 

Diethyl sebacate 

Diethyl succinate 

l,l-Dimethoxy-3,7-dimethyl-2,6-octadiene 

2,6-Dimethyl-5-hepten-l-al 

3,7-Dimethyl-l,6-nonadien-3-ol 

3,7-Dimethyl-l,6-nonadien-3-ol, acetate 

3,7-Dimethyl-cis-2,6-octadien-l-ol (Nerol) 

»3 , 7-Dimethyl -trans -2 , 6-oc tadien-1-ol (Geraniol ) 

3,7-Dimethyl-l,6-octadien-3-ol (Linalyl alcohol) 

3,7-Diniethyl-l,6-octadien-3-ol, acetate (Linalyl acetate) 

3,7-Dimethyl-l,6-octadien-3-ol, cinnamate 

3,7-Dimethyl-l,6-octadien-3-yl anthranilate (Linalyl 

anthranilate). 
3,7-Dimethyl-l,6-octadien-3-yl isobutyrate (Linalyl 

isobutyrate) . 
3,7-Dimethyl-l,6-octadien-3-yl propionate (Linalyl 
propionate ) . 

3,7-Dimethyloctan-l-al 

3, 7-Dimethyl -1,7-octanediol (Hydroxycitronellol) 

3,7-Dimethyl-l-octanol (Dihydrocitronellol) 

3, 7-Dimethyl -3-octanol (Tetrahydrolinalool) 

3, 7-Dimethyl -6 -octen-1-al (Citronellal) 

*3,7-Dimetl^l-6-octen-l-ol (Citronellol) 

3,7-Diinethyl-6-octen-l-yl formate (Rhodinyl formate) 

Dimethyl succinate 

1,1-Dipropoxyethane (Propylacetal) 

Dodecyl laurate 

<Ethyl butyrate 

Ethyl formate 

Ethyl heptanoate 

»Ethyl hexanoate (Ethyl caproate) 

2-Ethyl-l-hexanol (3-Octanol) 

Ethyl isohexanoate 

Ethyl isovalerate 

Ethyl laurate 

Ethyl le^Allinate 

Ethyl myristate 

»Ethyl nonanoate 

Ethyl octanoate 

Ethyl propionate 

Ethyl valerate 

»Geranyl acetate 

Geranyl butyrate 

»Geranyl formate 

Geranyl isobutyrate 

•Glutamic acid, monosodium salt (Monosodium glutamate) 

Heptanal (Enanthaldehyde) 

Heptyl alcohol (l-Heptanol) 

2-Hexenal 

cis-3-Hexen-l-ol 

cis-3-Hexen-l-ol lactate 

3-Hydroxy-2-butanone (Acetoin) 

«7-Ftrdroxy-3,7-dimethyl-l-octanal (Hydroxyoitronellal) 

»7-Hydroxy-3,7-dimetl^l octanal, dimethyl aoetal (f^droxy- 
cltronellal, dimethyl acetal). 

Isobutyl acetate 

Isobutyl hexanoate 



Manufacturers' identification codes 
(according to list in table 22) 



GIV. 

FB, 

GIV, 

GIV, 

GIV, 

GIV, 

IFF, 

GIV, 

FEL, 

ICO, 

VLY. 

GIV. 

HOF. 

HOF. 

FB, 

FEL, 

FB, 

FB, 

HOF, 

Fm. 

HOF. 



FEL, GIV, HOF, IFF, LUE, RT, UNG, UOP, VLY. 
IFF, UOP, VLI. 
UOP. 

RT, UOP, VLY. 
RT, UOP. 
VLY. 
IFF. 
UOP. 
UCC, UOP. - 



GLD, IFF, UOP. 

GIV, GLD, IFF, NCI, NEO, UNG, UOP, VLY. 
FEL, GIV, GLD, HOF, LUE, SHL, UNG, VLY. 
GIV, GLD, HOF, SHL, UNG. 



GIV, HOF. 




HOF. 




GIV. 




GIV, VLY. 




GIV, HOF. 




FB, GIV, IFF, UOP. 




GIV, GLD, IFF, NEO, 


UOP, VLY 


GIV. 




ICO. 




GIV. 




RT. 




FB, NW, RT, UOP. 




FB, pra. 




FEL, RT, UOP. 




FB, NW, PFW, RT. 




GIV. 




PFW. 




FB, PFW. 




RT, UOP. 




FMT. 




PFW, RT. 




FEL, RT, UOP. 




RT. 




FB. 




PFW. 




FEL, GIV, IFF, UOP, 


VLY. 


GIV, UOP. 




GIV, RT, UOP, VLY. 




IFF. 




COM, GRW, D/IC, MRK. 




BAG. 




BAG, UCC, UOP. 




GIV, RT. 




X. 




RT. 




FMT. 




GIV, GLD, IFF, OPC, 


UOP, VLY. 


GIV, IFF, UOP. 




FB, UOP. 




GIV. 





132 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 14B. --Flavor and perfume materials for which U.S. production or sales were reported, identified by 

manufacturer, i967--Continued 



Material 



Manufacturers ' Identification codes 
(according to list in table 22) 



FLAVOR AND PERFUME MATERIALS, ACYCLIC— Continued 

Isodecanyl acetate 

■»Isopentyl butyrate 

»Isopentyl foimate 

Isopentyl heptoate 

Isopentyl isovalerate 

Lauraldehyde 

Methyl isobutyrate 

Methyl P-methylthiopropionate 

Methyl 2-nonenoate 

Methylol methyl hexyl ketone 

p-Methylthlopropionaldehyde 

2-Methylundecanal 

I^ristaldehyde 

Nonamethylene glycol diacetate 

Nonanal 

Nonane-l,3-diol monoacetate 

Nonanol 

Nonyl acetate 

Octanal 

3-Octanone (Ethyl amyl ketone) 

n-Octyl alcohol 

n-Octyl foimate 

2,3-Pentandione (Acetyl propinyl) 

»Rhodinol 

Rhodinyl acetate 

Tepyl acetate 

3,7,9-Trimethyl-l,6-decadien-3-ol 

Trimethyl hexanal, sodium bisulfite complex 

2,6,10-Trimethyl-9-undecen-l-al 

Undecanal 

9-Undecenal 

10-Undecen-l-ol 

Y-Valerolactone 

All other 



VLY 

ra, 

FEL, 

RT. 

FB, 

GIV, 

PFW. 

RT. 

GIV, 

GIV. 

RT. 

GIV, 

GIV, 

VLY. 

GIV. 

GIV. 

GIV. 

GIV. 

GIV, 

GIV. 

GIV. 

RT. 

FB. 

FB, 

GIV, 

IFF, 

HOF. 

SHL. 

GIV. 

GIV, 

GIV. 

GIV. 

GIV. 

GIV. 



GIV, NW, PFW, RT, UOP. 
GIV, RT, UOP. 

PFW, UOP. 
IFF. 



RT. 



UOP. 
IFF. 



IFF, UOP. 



FEL, GIV, IFF, LUE, NEO, SHL. 
IFF. 
UOP. 



IFF. 



PLASTICS AND RESIN MATERIALS 



133 



Plastics and Resin Materials 



TABLE 15B. — Plastics and resin materials for which U.S. production or sales were reported, identified by 

manufacturer, 1967 

[Plastics and resin materials for which separate statistics are given in table 15A are marked below with an 
asterisk (»); chemicals not so marked do not appear in table 15A because the reported data are accepted in 
confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. 
An X signifies that the manufacturer did not consent to his identification with the designated product ] 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



THERMOSETTING RESINS 



*Alkyd resins, domestic: 
»Phthalic anhydride type- 



*Polybasic acid type- 



»Coumarone-indene and petroleum polymer resins; 

»Floor tile 

*Rubber compounding 

»AH other uses (including export) 

Epoxy resins: 

*Unmodified: 

»Bonding and adhesives 

•Protective coatings 

•Reinforced plastics 

»A11 other uses (including export) 

•Modified 



•Polyester resins: 

Reinforced plastics: 
•Sheets, flat and corrugated 

•All other 

•Surface coatings 

•All other uses (including export) 

•Phenolic and other tar acid resins: 

•Molding materials 

Bonding and adhesive resins for: 
•Laminating 

•Coated and bonded abrasives 

•Friction materials 

•Thermal Insulation 

•Foundry or shell molding 

•Plywood 

•Fibrous and granulated wood 

•Protective coatings, unmodified and modified- 



ACP, ACY, APV, ASH, BAL, BEN, BOY, BRU, CEL, CIK, 
CM, COM, CPV, DAV, DEC, DSO, DUN, DUP, EW, FAR, 
FBR, FCD, FLW, FOC, FSH, GEI, GIL, GLD, GRG, GRV, 
HAN, HPC, HRS, ICF, JOB, JSC, JWL, KEL, KMC, KMF, 
KPS, KPT, KYN, MCC, MID, MMM, MNP, MR, NCl, NGN, 
NPV, NTL, OBC, ORO, QSB, PER, PFP, PPG, PRT, PRX, 
PTP, QCP, RCI, RED, REL, RH, SCN, SED, SHA, SIP, 
SM, SRR, SVC, SW, SYV, TV, TXT, x. 

ACP, ACY, APV, ASH, BEN, BRU, CGL, CM, COM, CPV, 
DEG, DSO, DUN, DUP, EW, FAR, FBR, FCD, FOC, GEI, 
GIL, GLD, GRV, HAN, HPC, HYC, ICF, KYN, MCC, MID, 
MMM, MOB, NCI, NON, NPV, ORO, QSB, PPG, RCI, RED, 
RH, SCN, SM, SRR, SW, TV. 

ACC, ACP, NEV, PAI, RCI, VEL. 

ACC, ACP, KPI, NEV, PAI, RCI, VEL. 

ACC, ACP, nSO, DUP, ENJ, MCA, NEV, ORO, PAI, PPG, RCI, 
VEL, VSV. 



CBA, CEL, DOW, RCI, SHC, UCC. 
CBA, CEL, DOW, RCI, SHC, UCC. 
CBA, CEL, DOW, RCI, SHC, UCC. 
CBA, CEL, DOW, RCI, SCH, UCC. 
ASH, CM, CPV, DA, EW, FOM, HAP, IOC, JOB, MID, MMM, 

MNP, MRB, NPV, ORO, QSB, PRX, PYR, REL, REZ, SCN, 

SED, SM. 



ACY, APD, DA, EW, GLD, HKD, ICF, LAS, MFG, ORO, PPG, 

RCI, RH, SIC, SW, USR. 
ACP, ACY, ASH, CPV, DA, DSO, GLD, GNT, GRV, GYR, HKD, 

ICF, IPC, KPS, LAS, MFG, MRO, PLU, PPG, RCI, SW, 

USR, UTR, VAL, x. 
ACP, ACY, APD, COM, CPV, DA, GLD, GYR, ORO, PPG, SW, 

USR. 
ACP, ACR, ACY, CAP, DA, DSO, DUP, EKT, EPC, EW, FMP, 

GEI, GLD, GNT, GRG, GYR, HKD, KPT, LAS, MMM, OCF, 

PFP, PLU, PPG, PTP, RCI, RH, SCN, SW, USR, UTR, x. 

FRL, GE, HER, HKD, HVG, MON, MRB, NPI, PLS, RCI, RGC, 
UCC, VSV. 

ACP, AMR, ASH, BOR, CBR, CD, ENJ, EW, FOM, GE, HKD, 

IRI, MON, NTC, NVF, PGU, PPL, PYZ, RCD, RCI, SCN, 

SPL, UCC. 
AMR, ASH, BME, BOR, CBM, CBR, HKD, MMM, MON, MRB, PPG, 

PYZ, RCI, SCN, UCC. 
ABS, ASH, BME, BOR, FRL, GE, HKD, MMM, MON, PYZ, RAB, 

RCI, SCN, SYV, UCC, VSV. 
ACP, AMR, ASH, HKD, MON, OCF, PYZ, RCI, UCC. 
ACP, ACR, AMR, ASH, BOR, GE, HKD, MON, PYZ, RCI, SCN, 

UCC, UNO. 
ASH, BOR, CBC, CBD, HPC, MON, PGU, PYZ, RCI, RH, SIM, 

WCA, WRD. 
AMR, BOR, CBC, CBD, HKD, MON, PYZ, RCI, SIM, UCC, UPL. 
ASH, BOR, CIK, CM, CPV, DSO, EW, FAR, FCD, GE, GEI, 
GRG, GRV, HAN, HER, HKD, ICF, INL, KMC, KRM, KYN, MID, 
MMM, MON, MRB, NCI, ORO, PRX, PYZ, RCI, REL, RH, SM, 
SNC, SW, TV, UCC, x. 



134 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 15B. --plastics and resin materials for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



THERMOSETTING RESINS— Continued 

^Phenolic and other tar acid resins — Continued 

»A11 other uses (Including export) 

»Polyurethane and dlisocyanate resins 

»Rosin modifications: 

»Rosin and rosin esters, unmodified (ester gums) 

*A11 other 

Silicone resins 

Styrene-alkyd polyesters 

»Urea and melamine resins: 

^Textile treating and coating resins 

»Paper treating and coating resins 

Molding materials 

Bonding and adhesive resins for: 
^Laminating 

»Plywood 

*Flbrous and granulated wood 

^Protective coatings 

*A11 other uses (including export) 

»A11 other thermosetting resins 

THERMOPLASTIC RESINS 
Acrylic resins 

»Cellulose plastics materials: 
Sheets, continuous: 
»Under 0.003 gage 

»0.003 gage and over 

»A11 other sheets, rods, and tubes 

♦Molding and extrusion materials 

Polyamide resins: 

»Nylon type 

Hon- nylon type 

Polyolefln plastics materials: 
Ethylene polymers and copolymers: 
Production : 
»High-pressure polyethylene 

«Low-pressure polyethylene 

"Ethylene copolymers 

"Polyethylene, density O.g^iO and below: 
"Sales and use: 

"Injection molding 

"Blow molding 

"Film and sheet 

"Extrusion coating on paper and other substrates- 
•Wlre and cable 



ACP, ACR, AMR, ASH, BME, BOH, CBR, DSO, EW, GE, GEI, 
ORG, HER, HKD, HVG, IOC, IRC, IRI, KND, KPT, MCA, 
MMM, MOW, MRB, NPI, PLS, PTP, PYE, PYZ, RAB, RCI, 
ROC, RH, RPC, SCN, SHA, SNC, TKL, UNO, USR, WCA. 

ACB, ARK, ASH, BFG, CBM^ DA, DCC, DSO, DUP, GPM, HAP, 
IPI, JWL, KMC, MCC, PEL, PFP, PTP, PYR, QUN, RCT, 
SCN, SKT, UPJ. 

ASH, CBY, DPP, FAR, FLW, FRP, KRM, MCC, NCI, QSB, PTP, 

RCI, SRR. 
ASH, CBY, DPP, EW, FAR, FRP, HN, KRM, NCI, OSB, PTP, 

RCI, RH, SCF, SHA. 
ACP, ASH, DCC, GLD, RCI, SPD. 
ASH, EW, FLW, MCC, PTP, USR. 

ACY, ASH, BRY, CBR, CIB, DAN, DEP, DUP, ECC, GAF, HNC, 
HHT, JSC, MON, MRA, ONX, PC, QCP, RCI, RH, RPC, S, 
SBC, SEY, SNW, STC, USO, VAl, WIC. 

ACY, AMR, BME, BOR, CBC, CBD, CBR, DUP, HPC, MMM, MON, 
RCI, RH, SIM, TXT, x. 

ACP, ACY, FMB, GDN, PMC, SFA. 

ACY, ASH, BOR, CBR, ENJ, FQM, GE, MON, NTC, OCF, PGU, 

PMC, PPL, RCI, STC. 
ACP, ACY, ASH, BOR, CBC, CBD, HPC, MON, NTC, PGU, RCI, 

REN, RH, SAC, SM, SOR, WRD. 
ACY, AMR, BOR, CBC, CBD, IPR, MON, PGU, RCI, SAC, SOR, 

SYV, UPL. 
ACP, ACY, CEL, CMP, CPV, DSO, DUP, GLD, GRV, HAN, KPS, 

MID, MON, NON, PPG, RCI, REL, RH, SCN, SW, TV. 
ACP, ACY, AMR, ASH, BOR, DUP, EFH, FMB, HPC, IRI, MON, 

RCI, RH, TV, UNO, VAL. 
ACP, ACY, HPC, HVG, MOB, MON, RPC, UNO, VSV, x. 



ACY, ASH, CEL, CIB, CMG, DUP, FLH, GLC, GLX, HRT, 
JOB, JSC, ORO, PPG, QUN, RH, RPC, SAR, SED, SEY, 
VPC, WIC, x, X. 



CEL, DUP, EKT, NIX. 

CEL, DOW, EKT, MON, MPFj NIX, PDJ, SPY. 

CEL, MPP, NIX, PDJ, RSB, SPY. 

CBN, CEL, DOW, EKT, MON, RSB. 

ALF, CEL, DUP, FG, GOC, POL. 

AMR, BCM, EMR, GNM, HN, KRM, SM, SNW. 



ACP, CBN, DOW, DUP, EKX, GOC, KPP, MON, PLC, RCC, 

UCC, USI. 

ACP, CEL, DOW, DUP, HPC, KPP, MON, PLC, UCC, USI. 

DUP, EKX, ENJ, UCC, USI. 



ACP, CBN, CEL, DOW, DUP, EKX, ENJ, GOC, KPP, MON, PLC, 

RCC, SHC, UCC, USI. 
ACP, CBN, DOW, DUP, EKX, KPP, MON, PLC, RCC, SHC, UCC, 

USI. 
ACP, CBH, CEL, DA, DOW, DUP, EKX, ENJ, GOC, KPP, MON, 

PLC, RCC, SHC, UCC, USI. 
CEL, DOW, DUP, EKX, GOC, MON, PLC, RCC, UCC, USI. 
DOW, DUP, EKX, KPP, MON, PLC, UCC, USI. 



PLASTICS AND RESIN MATERIALS 



135 



TABLE 15B. --Plastics ami resin materials for which U.S. production or sales were reported, identified by 

manufacturer, 7 967- -Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



THERMOPLASTIC RESINS— Continued 

Polyolefin plastics materials — Continued 
»Ftilyethylene, density 0.940 and below — Continued 
»Sales and use — Continued 

»Pipe and conduit 

»Other extruded products 

»A11 other uses (Including export) 

"Polyethylene, density over 0.940: 
»Sales and use; 

"Injection molding 

»Blow molding 

"Film and sheet 

• Bttrusion coating on paper and other substrates- 

"Wire and cable 

"Pipe and conduit 

"Other extruded products 

"All other uses (including export) 

"Polypropylene : 

"Production 

"Sales and use: 

"Injection and blow molding 

"Film and sheet 

"Fibers and filaments 

"Other extruded products 

"All other uses (including export) 

"Styrene type plastics materials: 
ABS and SAN resins: 
"Production 

"Sales and use: 

"Molding 

"Extrusion 

"All other uses (including export) 

Styrene and styrene copolymer resins: 
"Production: 

"Straight polystyrene 

Rubber-modi fled polystyrene 

Styrene-butadiene copolymer 

All other 

"Sales and use: 

"Molding 

"Textile and paper treating and coating 

"Emulsion paint 

"Extrusion 

Foam and foamable materials 

"All other uses (including export) 



Vinyl resins: 

Polyvlnylchloride and copolymers; 
"Production: 

Suspension homopolymers 

Suspension copolyioers 

Dispersions (paste) 



EKX, KPP, PLC, UCC, IBI. 

ACP, DOW, DUP, EKX, ENJ, KPP, PLC, UCC, USI. 

ACP, CEL, DOW, DSO, DUP, EKX, ENJ, GOC, KPP, MON, PLC, 
RCC, UCC, USI. 



ACP, CEL, DOW, 

USI. 
ACP, CEL, DOW, 

UCC, USI. 
ACP, CEL, DOW, 
DUP, EKX, PLC, 
ACP, CEL, DUP, 
ACP, CEL, DUP, 
ACP, CEL, DOW, 
ACP, CEL, DOW, 

UCC, USI. 



DUP, EKX, HPC, KPP, PLC, RCC, SHC, UCC, 
DUP, EKX, HPC, KPP, MON, PLC, RCC, SHC, 
KPP, PLC, SHC, UCC, USI. 



DUP, EKX, HPC, 

UCC, USI. 

EKX, HPC, MON, 

EKX, HPC, KPP, 

DUP, EKX, HPC, 

DSO, DUP, EKX, 



PLC, SHC, UCC, USI. 

PLC, SHC, UCC, USI. 

KPP, PLC, UCC, USI. 

HPC, KPP, MON, PLC, 



AV3, DA, DOW, EKX, ENJ, HPC, NVT, RCC, SHC. 

ACP, DOW, EKX, ENJ, HPC, NVT, PLC, RCC, SHC, UCC, 

USI, X. 
ACP, AVS, DA, EKX, ENJ, HPC, RCC, SHC, UCC. 
DA, EKX, ENJ, HPC, PLC, SHC, x. 
EKX, ENJ, HPC, PLC, RCC, SHC, UCC. 
ACP, AVS, DA, DOW, EKX, ENJ, HPC, NVT, PLC, RCC, SHC, 

UCC, USI. 



BFG, DOW, FBF, FIR, GRD, KPP, MCB, MON, RCC, SW, 
UCC, USR. 

BFG, DOW, FBF, KPP, MCB, MON, UCC, USR. 

BFG, DOW, MCB, MON, RCC, UCC, USR. 

BFG, DOW, FIR, GRD, KPP, MCB, MON, SW, UCC, USR. 



BPL, CBN, CSD, DOW, FBF, FG, KPP, MON, ONX, PLA, POL, 

PRX, RCC, SEK, SOL, SW, TIC, UBS, UCC. 
BOR, BPL, CSD, DOW, FG, GOR, KPP, MON, PLA, RCC, 

SHC, UCC. 
BFG, BOR, DOW, FIR, GNT, GRD, GIR, ILC, KPP, USR, WIC. 
ACC, BAS, BCN, BKC, DOW, DSO, DUP, GAF, GLD, GRD, IOC, 

JSC, KEL, MON, MRT, NLC, ORO, PAI, POL, PRX, PVI, 

RCC, RH, SEK, SM, SPT. 

BFG, BKC, BPL, CSD, DOW, FBF, FG, FIR, GOR, GYR, KPP, 
MON, PLA, RCC, SHC, SOL, TIC, UCC, USR. 

BFG, BOR, DOW, FIR, GNT, GRD, GYR, ILC, JSC, KPP, MON, 
MRT, ONX, PRX, USR, WIC. 

BOR, DOW, DSO, FIR, GLD, GNT, GRD, GYR, KPP, MON, USR. 

BFG, CBN, CSD, DOW, KPP, MON, RCC, SHC, UCC. 

BAS, CSD, DOW, FG, GYR, KPP, MON, RCC, SEK, SHC, USR. 

ACC, BAS, BCN, BFG, BOR, CSD, DOW, DSO, DUP, FG, GAF, 
GNT, GRD, GYR, IOC, JSC, KPP, MON, MRT, PAI, PRX, 
PVI, RCC, RH, SEK, SHC, SM, UBS, UCC, USR, x. 



ACP, AME, ATU, BFG, BOR, CRY, CUC, DA, DOW, ESC, FIR, 
GNT, GRA, GYR, MON, PNT, SFA, UCC, UBR. 

ACP, AME, BFG, BOR, CRY, CUC, DA, FIR, GNT, GYR, KYS, 
MON, NSC, ONX, PNT, SFA, THC, UCC. 

ACP, BFG, BOR, CRY, DA, FIR, GYR, MON, SFA, UCC, USR. 



136 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 15B. 



-Plastics andYesin materials for which U.S. production or sales were reported, identified by 
manufacturer, iS67— Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



THERMOPLASTIC RESINS— Continued 

Vinyl res ins --Continued 

Polyvinylohloride and copolymers — Continued 
*Sales and use: 

^Calendering, except flooring 

Flooring: 
^Calendered 

»Coated 

Paper and textile uses: 
*Coating 

»Other 

»Protective coatings and adhesives 

»Wire and cable 

*Extruded film and sheet 

»Other extruded products 

*Sound records 

♦Injection and blow molding 

■*Plastisol formulating and molding 

»A11 other uses (including export) 

Polyvinyl acetate: 
«Production: 

♦Latexes 

»Resins 

♦Sales and use: 

♦Emulsion paints 

♦Adhesives 

♦Paper treating 

♦Textile treating 

♦All other uses (including export) 

♦Polyvinyl alcohol 

♦Other vinyl resins 

♦All other thermoplastic resins 



AME, ATU, BFG, BOR, CRY, CUC, DA, DOW, ESC, FIR, GNT, 
GYR, MON, PNT, SFA, THC, UCC, USR. 

AME, ATU, BFG, BOR, CRY, CUC, DA, ESC, FJR, MON, PNT, 

SFA, THC, UCC. 
BFG, BOR, CRY, DA, FIR, GNT, GYR, MON, THC, UCC, USR. 

ATU, BFG, BOR, CRY, DA, FIR, MON, ONX, SFA, THC, UCC, 

USR. 
BFG, BOR, ESC, FIR, THC, UCC. 
BFG, BOR, DA, ESC, FIR, MON, NSC, UCC. 
AME, ATU, BFG, BOR, CRY, CUC, DA, DOW, FIR, MON, PNT, 

THC, UCC, USR. 
AME, BFG, BOR, CUC, DA, DOW, FIR, GYR, MON, PNT, SFA, 

THC, UCC, USR. 
ACP, AME, ATU, BFG, BOR, CRY, CUC, DA, DOW, ESC, FIR, 

GNT, GYR, MON, PNT, THC, UCC, USR. 
AME, BFG, BOR, CRY, CUC, DA, KYS, MON, PNT, SFA, THC, 

UCC, USR. 
ATU, BFG, BOR, CRY, DA, ESC, FIR, GYR, MON, PNT, SFA, 

THC, UCC, USR. 
BFG, BOR, CUC, DA, FIR, MON, PYR, SFA, THC, UCC, USR. 
BFG, BOR, CRY, CUC, DA, DOW, ESC, FIR, GRA, GYR, MON, 

PNT, SFA, THC, UCC, USR. 



AML, BEN, BOR, BOY, CEL, CUC, DSC, DUP, FLH, GLC, GRD, 
HAN, HNC, HRT, JOB, JSC, KMC, KMP, MCC, MMM, MON, MR, 
MRN, NCI, NPV, NSC, NTC, OBC, PFP, PII, PPG, PRX, PVI, 
QCP, REL, RFC, SED, SEY, SPC, UCC, WIC, x. 

ASH, BEN, BOR, CST, CUC, DAN, DAV, DUP, FAR, HNC, JOB, 
MON, MRN, NSC, OCF, PPG, RCI, SCO, SED, SH, UCC, x. 

AML, APV, ASH, BEN, BOR, CEL, CUC, DAV, DSO, DUP, FLH, 

GLC, GLD, GRD, HAN, JOB, KMC, KMP, MCC, MON, NCI, 

NPV, NSC, PFP, PPG, PRX, RCI, SED, SPC, UCC, WIC. 
AML, ASH, BOR, CEL, CUC, DUP, FLH, GLC, GRD, HNC, JSC, 

MMM, MON, MRN, NSC, NTC, PII, PPG, RCI, SH, UCC, x. 
AML, BOR, CEL, CUC, DUP, FLH, GLC, MON, NSC, PII, 

SEY, WIC. 
AML, BOR, CEL, CST, CUC, DAN, DUP, GLC, GRD, HRT, NSC, 

PII, SCO, SEY. 
BOR, CUC, DUP, GRD, MON, NSC, OCF, PII, PVI, QCP, RCI, 

SCO, UCC, X. 
BOR, CUC, DUP, MON, SEY, x. 
BAS, BOR, DOW, DUP, GRD, MON, SW, UCC. 
ACP, CBY, CEL, CIB, DEP, DUP, GE, GGY, JSC, KRM, MOB, 

ONX, PPG, RH, RPC, SCN, SNW, WIC, x. 



RUBBER-PROCESSING CHEMICALS 



137 



Rubber -Processing Chemicals 



TABLE 16B. -- Rubber-processing chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1967 

[Rubber-processing chemicals for which separate statistics are given in table 16A are marked below with an asterisk 
(*); chemicals not so marked do not appear in table 16A because the reported data are accepted in confidence and 
may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that 
the manufacturer did not consent to his identification with the designated product] 



Chemical 



Manufacturers' identification codes 
(according to list In table 22) 



RUBBER-PROCESSING CHIMICALS, CYCLIC 

^Accelerators, activators, and vulcanizing agents: 
»Aldehyde-amine reaction products: 

Aoetaldehyde-aniline condensate 

n-Butyraldehyde-aniline condensate 

Butyraldehyde-butylideneaniline condensate 

a-Ethyl-p-propylacrylanlllde 

Kept aldehyde- aniline condensate 

Triethyltrimethylenetriamine 

»Dithiocarbamic acid derivatives: 

Dlbenzyldlthiocarbandc acid, sodium salt 

Dlbenzyldithiocarbamlc acid, zinc salt 

Dlbutyldithlocarbamc acid, N, N-dlmethylcyclo- 

hexylamine salt. 
Dibutyldlthiocarbamlo acid, dlphenylguanidlne salt — 

2,4-Dinltrophenyl dlmethyldlthlooarbamate 

Plperidinecarbodithloio acid, piperldlnlujn-potassiujn 
salts, mixed. 
Guanidines ; 

Dicatechol borate, di-o-tolylguanidine salt 

1,3-Diphenylguanidine 

Dlphenylguanidlne phthalate 

1,3-Dl-o-tolylguanidlne 

1, 2,3-Trlphenylguanidine 

»Thlazole derivatives: 

2-Benzothiazyl-N, N-dletl-iylthiocarbamoyl sulfide 

l,3-Bls(2-benzothlazolylmercaptomethyl)urea 

N-tert-Butyl-2-benzothiazolesulfenamide 

»N-Cyolohexyl-2-benzothiazolesulf en amide 

N, N-Dlisopropyl-2-benzothlazolesulfenaiiude 

N-(2,6-Dimethylmorpholino)-2-benzothiazole- 
sulfenamlde. 

»2,2'-Dithiobls(benzothlazole) 

»2-Meroaptobenzothlazole 

2-Mercaptobenzothiazole, zinc chloride 

2-Mercaptobenzothlazole, zinc salt 

'*-Morpholinyl-2-benzothlazyl disulfide 

N-CKydiethylene.-2-benzothiazolesulfenajiilde 

Thlazoline-2-thlol 

All other cyclic accelerators, activators, and 
vulcanizing agents: 

p-Benzoquinonedioxime 

Bls(p-aminocyclohexyl)methane carbamate 

Bls(2,6-dlraethylmorpholinothiocarbonyl) sulfide 

Dibenzoyl-p-quinonedioxime 

Dlbenzylamine 

N, N'-Dicinnajnylidene-l,6-hexanediamine 

Di-N, N'-pentaraethylenethluram tetrasulf Ide 

4,4'-Dithiodiniorphollne 

2-Imidazoline-2-thlol 

Poly-p-dinltrosobenzene 

Styrene polysulf ide 

^Antioxidants, antlozonants, and stabilizers: 

♦Amino antioxidants, antlozonants, and stabilizers: 
Aldehyde- and acetone-amlne reaction products: 

Acetaldehyde-anillne hydrochloride condensate 

Aldol-a-naphthylamlne condensate 

Butyraldehyde-anlllne condensate 

Dlphenylamine-acetone condensate 

Phenyl-2-naphthylamlne-acetone condensate 

♦Substituted p-phenylenediamlnes: 

N, N '-Bis (l,"! -dime thy lpentyl)-p-phenylenedlamlne 

N, N'-Bls(l-ethyl-3-methylpentyl)-p-phenylenedlamlne- 



USR. 










DUP, 


MON, 


RCD, 


USR. 




MON. 










ceo. 










USR. 










USR. 










USR. 










USR. 










MON. 










ceo. 










USR. 










DUP. 










DUP. 










ACY. 










MON. 










ACY. 










ACS. 










PAS. 










MON. 










V.ON. 










ACY, 


BFG, 


MON, 


USR. 




ACY. 










MON. 










ACY, 


BFG, 


GYR, 


MON, 


USR 


ACY, 


BFG, 


GYR, 


MON, 


USR 


DUP. 










ACY, 


BFG, 


DUP, 


GYR, 


USR 


GYR. 










ACY, 


BFG, 


MON. 






ACY. 










CTA, 


DUP. 








DUP. 










DUP. 










CTA, 


USR. 








MLS, 


USR. 








DUP. 










DUP, 


VNC. 








MON. 










DUP, 


RBC. 








DUP. 










TKL. 










USR. 










BFO. 










DUP. 










ACY, 


BFG, 


USR. 






USR. 










EKT, 


USR. 


x. 






MON, 


UFM. 









138 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 16B. — Rubber-processing chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



RUBBER-PROCESSING CHEMICAI^, CYCLIC--Continued 

^Antioxidants, antiozonants, and stabilizers — Continued 
»Amlno antioxidants, antiozonants, and stabilizers — 
Continued 
^Substituted p-phenylenediamines-- Continued 

N, N'-Bis(l-methylheptyl)-p-phenylenediamine 

N-sec-Butyl-N'-phenyl-p-phenylenediamine 

N-Cyclohexyl-N'-phenyl-p-phenylenediaraine 

DiarylarylenediajTdnes, inixed 

N, N'-Di-sec-butyl-p-phenylenediajnine 

N-(l,3-Dimethylbutyl)-N'-phenyl-p-phenylenediaiiiine- 

N, N'-Di-2-naphthyl-p-phenylenediainine 

*N, N'-Diphenyl-p-phenylenediamine 

N-lsopropyl-N'-phenyl-p-phenylenediamine 

Nitroso-N-phenyl-p-phenylenediamine 

All other p-phenylenedlaraines 

Other amino antioxidants, antiozonants, and 
stabilizers: 

p-Anilinophenol 

l,2-Dihydro-5-dodecyl-2,2,'4-trlmethylquinoline 

l,2-Dihydro-6-ethoxy-2,2,'4-trlmethylquinoline 

l,2-Dihydro-2,2,4.-trimethylquinoline 

4,4-'-Diinethoxydiphenylainine 

4,4'-Dinonyldiphenylaiidne 

ij^'-Dioctyldiphenylamine 

N, N'-Diphenylethylenediamine 

N, N'-Diphenyl-l,3-propaiiediamine 

N, N'-Di-o-tolylethylenediamine 

p-Isopropoxydiphenylamlne 

4,'i'-Methylenedianiline 

*Ootyldiphenylamine 

Octyldiphenylajnine mixture {mono-, nonyl-, and di- 

N-Phenyl-l-naphthylamine 

*N-Phenyl-2-naphthylamine 

p-(p-Toluenesulfonaiiddo)diphenylamine 

All other 

*Phenolic and phosphite antioxidants and stabilizers: 
Phosphites: 

Nonyl phenyl phosphites, mixed 

Polyphenolio phosphite, polyalkylated 

*Polyphenolies (including bisphenols): 

Bisphenol, hindered 

'i,<V'-Butylidenebis(6-tert-butyl-m-cresol) 

2,5-Di-(l,l-dimethylpropyl)hydroquinone 

2,2'-Methylenebis(6-tert-butyl-p-cresol) 

2,2'-Methylenebis(6-tert-butyl-'4-ethylphenol) 

2,2'-Methylenebis(6-tert-octyl-p-cresol) 

4,4'-Thiobis(6-tert-15utyl-m-oresol) 

2,2'-Thiobis(4,6-di-sec-aii0flphenol) 

l,l,3-Tri(2-methyl-4-hydroxy-5-tert-butylphenyl) 
butane. 
Other phenolic antioxidants and stabilizers: 

p-Benzyloxyphenol 

o-Cresol, alkylated 

N-Lauroyl-p-ajninophenol 

wPhenol, alkylated 

Phenol, hindered 

Phenol, styrenated 

N-Stearoyl-p-aminophenol 

5!ylenol, alkylated 

^Blowing agents: 

N, N'-Dimethyl-N, N'-dinitrosoterephthalamide 

Dinitrosopentamethylenetetramine 

p,p'-Oxybis(benzenesulfonhydrazide) 

^Peptizers: 

Alkylated o-thiooresol 

Alkylated thiophenol, zinc salt 

Aryl raercaptans 

2-Benzamidothiophene, zinc salt 

2', 2' ' '-Dithiobis(benzanllide) 

Dixylyl disulfides, mixed 

2-Naphthalenethiol 



BFG, MON, UPM. 

USR. 

USR. 

GYR. 

USR. 

GYR. 

BFG. 

BFG, DUP, USR. 

MON, USR. 

USR. 

MON. 



BFG. 

MON. 

MON. 

BFG, MON. 

DUP. 

ACY. 

BFG. 

ceo, DA, X. 

ceo. 
ceo. 

BFG.. 

USR. 

ACY, NPl, PAS, USR. 

BFG. 

DUP, UCC. 

BFG, DUP, USR. 

USR. 

DUP. 



USR. 
BFG. 

GYR. 

MON. 

MON. 

ACY, ASH. 

ACY. 

ACY. 

MON. 

MON. 

ICI. 



BFG. 

PIT. 

MLS. 

ACY, BFG, CCO, GYR, PIT, USR. 

DUP, GYR, PIT. 

BFG, GYR, USR. 

MLS. 

PIT. 

DUP. 

DUP, NPI. 
USR. 

PIT. 
PIT. 
PIT. 
ACY. 
ACY. 
PIT. 
DUP. 



RUBBER-PROCESSING CHEMICALS 



139 



TABLE 16B. 



--Rubber-processing chemicals for which U.S. production or sales were reported, identified by 
manufacturer , 1967 — Continued 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



RUBBER-PROCESSING CHEMICALS, CYCLIC— Continued 

^peptizers — Continued 

Pentachlorobenzene thiol 

Pentachlorobenzenethiol, zinc salt 

Thiocresol 

Thiophenol (Benzenethiol) 

Xylenethiol 

Other cyclic rubber-processing chemicals: 

p-tert-Amylphenol sulfide (tackifier) 

Dioresyl disulfide 

N,«4-Dinitroso-N-raethylaniline (physical-property 

improver). 
Hindered aromatic polyamine 

N-Nltro$odiphenylamine (retarder) 

RUBBER- PROCESSING CHIMICALS, ACYCLIC 

»Accelerators, activators, and vulcanizing agents: 
*Dithiocarbamic acid derivatives : 

Dibutyldithiocarbamic acid, potassium salt 

*Dibutyldithiocarbamic acid, sodium salt 

»Dibutyldlthiocarbamic acid, zinc salt 

Diethyldithiocarbamic acid, selenium salt 

Diethyldithiocarbajnic acid, sodium salt 

Diethyldithiocarbamic acid, tellurium salt 

^Diethyldithiocarbamic acid, zinc salt 

Dimethyldithiocarbamic acid, bismuth salt 

Dimethyldithiocarbamic acid, copper salt 

Dimethyldithiocarbamic acid, lead salt 

Dimethyldithiocarbamic acid, selenium salt 

Dimethyldithiocarbamic acid, sodium salt and sodium 
polysulfide. 

^Dimethyldithiocarbamic acid, zinc salt 

All other 

*Thiurams : 

Bis(dibutylthiocarbamoyl ) sulfide 

■»Bis(diethylthiocarbamoyl) disulfide 

»Bis (dimethyl thiocarbamoyl) disulfide 

Bis(dimethylthiocarbamoyl ) disulfide and 
2-mercaptobenzothiazole, mixed. 

»Bis(dimethylthiocarbamoyl) sulfide 

Bis(ethylmethylthiocarbamoyl) sulfide 

Thiuram blend 

Xanthates and sulfides: 

Di-n-butylxantho disulfide 

Diisopropylxantho disulfide 

Zinc dibutyl xanthate 

Zinc isopropyl xanthate 

All other acyclic accelerators, activators, and 
vulcanizing agents: 

n-Butyraldehyde-butylamine condensate 

Di-n-butylammonium oleate 

3-Ethyl-l,l-dimethyl-2-thiourea 

Ethylenediamine carbamate 

1, l,3-Trimethyl-2-thiourea 

Blowing agents : 

Madified urea 

Urea-biuret mixture 

Conditioning and lubricating agents: 

Methyl stearyl-10-sulfonic acid, sodium salt 

Mono- and dialkyl acid phosphates, mixed 

Mono- and dialkyl phosphate ammonium salts, mixed 

Polymerization regulators: 

Alkyl mercaptans, mixed 

*Dodecyl mercaptans 

Tetradecyl mercaptan 

Shortstops : 

Dimethyldithiocarbamic acid, potassium salt 

»Dimethyldithlocarbamio acid, sodium salt 

Other acyclic rubber-processing chemicals: 

Zinc laurate (activator, physical-property Improver)-- 
All other 



DUP. 
DUP. 
PIT. 
PIT. 
DUP. 

PAS. 
USR. 
CTA, MON. 

USR. 

ACY, BFG, CTA, GYR, USR. 



VNC. 








ALC, 


DUP, PAS, 


USR, 


VNC. 


ALC, 


DUP, USR, 


VNC. 




VNC. 








ALC, 


PAS. 






™c. 








ALC, 


GYR, PAS, 


USR, 


VNC. 


VNC. 








VNC. 








VNC. 








VNC. 








BFG, 


GNT. 






ALC, 


DUP, FMN, 


GYR, 


PAS, RBCUSR, WRC 


PAS, 


VNC. 






USR. 








DUP, 


GYR, PAS. 






BFG, 


DUP, GYR, 


PAS, 


VNC. 


VNC. 








DUP, 


GYR, USR. 






PAS, 


VNC. 






DUP. 








USR. 








BFG. 








USR. 








VNC. 








DUP. 








DUP. 








VNC. 








DUP. 








VNC. 








DUP. 








SW. 








DUP. 








DUP. 








DUP. 








PAS, 


PLC. 






HK, PAS, PLC. 






PAS, 


PLC. 







GYR, PAS, USR. 

ALC, BFG, DUP, GYR, PAS, USR. 

USR. 
USR. 



140 



SYNTHETIC ORGANIC CHEMICALS. 1967 



Elastomers (Synthetic Rubbers) 

TABLE IIB.-- Elastomers (synthetic rubbers) for which U.S. production or sales were reported, identified by 

manufacturer, 1967 



[Elastomers (synthetic rubbers) for which separate statistics are given in table 17A are marked below with an as- 
terisk (»); products not so marked do not appear in table 17A because the reported data are accepted in confidence 
and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies 
that the manufacturer did not consent to his identification with the designated product] 



Product 


Manufacturers ' identification codes 
(according to list in table 22) 


ELASTOUERS, CYCLIC 


ASY. BFG CPY FIR FRS CiGC GMT C.YR TTP MCR 




PLC, RUB, SHC, TUS, URC, USR, WIC. 
BPG, FIR, FRS, GNT, GYR, USR. 




ACY, DUP, GNT, MOB, PRO, RUB, TKL, USR. 


ELASTOMERS, ACYCLIC 


ACY, BFG, TKL. 




PRC. TKT,. 




BFG, FRS, GYR, TKL, TUS. 




BFG, FRS, GYR, ILO, USR. 




DUP. 


»Polyisobuty lene - isoprene type ( Butyl ) 

Reaction products of natural rubber 


CBN, ENJ. 
GYR, HPC, ICI. 
DCC, SFA, SPD, UCC. 


»Stereo elastomers 

All other 


ASY, BAR, DUP, ENJ, FRS, GGC, GYR, PLC, SHC, TUS, USR. 
DUP, ENJ, X. 



PIASTICIZERS 



141 



Plasticizers 

TABLE 18B. --Plasticizers for which U.S. production or sales were reported, identified by 

manufacturer, 1967 

[Plasticizers for which separate statistics are given in table 18A are marked with an asterisk (*); products 
not so marked do not appear in table 18A because the reported data are accepted in confidence and may not be 
published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product.] 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



PLASTICIZERS, CYCLIC 

Coumarone-indene plasticizer 

N- Cyclohexyl-p-toluenesulf onamide 

Dibenzyl sebacate 

Diethylene glycol dibenzoate 

Di-tert-octyldlphenyl oxide 

Dipropanediol dibenzoate 

N- Ethyl -p-toluenesulfonamide 

Isopropylidenediphenoxypropanol 

Naphthalene, alkylated 

Phosphoric acid esters ; 

»Cresyl dlphenyl phosphate 

Dibutyl phenyl phosphate 

Diphenyl raono-o-xenyl phosphate 

Diphenyl octyl phosphate 

Methyl diphenyl phosphate 

»Tricresyl phosphate 

*Triphenyl phosphate 

All other phosphoric acid esters 

^Phthalic anhydride esters : 

Alkyl benzyl phthalates 

Bis(4-methyl-2-pentyl ) phthalate 

Butyl benzyl phthalate 

Butyl cyclohexyl phthalate 

n-Butyl n-decyl phthalate 

»Butyl 2-ethylhexyl phthalate 

»Butyl octyl phthalate 

Di(2-butoxy ethyl) phthalate 

»Dibutyl phthalate 

»Di cyclohexyl phthalate 

Diethyl Isophthalate 

»Di ethyl phthalate 

Dihexyl phthalate 

Di(isodecyl )-"i,5-epoxy phthalate 

Diisodecyl hydrophthalate 

»Diisodecyl phthalate 

«Di(2-methoxyethyl ) phthalate 

Dimethyl isophthalate 

»Dimethyl phthalate 

Dinonyl phthalate 

»Dioctyl phthalates: 

»Dicapryl phthalate 

*Di (2-ethylhexyl) isophthalate 

«Di (2-ethylhexyl) phthalate 

»Diiso-octyl phthalate 

•Di-n-octyl phthalate 

"Mixed dioctyl phthalate 

Diphenyl phthalate 

*Ditridecyl phthalate 

2-Ethylhexyl isodecyl phthalate 

"Glycolate phthalate esters : 

Butyl phthalyl butyl glycolate 

Ethyl (and methyl) phthalyl ethyl glycolate 

All other glycolate phthalate esters 

n-Hexyl n-decyl phthalate 

I^drogenated castor oil phthalate 

Isodecyl tridecyl phthalate 

Iso-octyl isodecyl phthalate 

«n-Octyl n-decyl phthalate 

All other phthalic anhydride esters 



NEV. 










MON. 










WTH. 










VEL. 










DOW. 










VEL. 










MON. 










DOW. 










ACC. 










FMP, 


MON, MTR, SFA, SM. 








MON. 










DOW. 










MON. 










FMP, 


MON. 








FMP, 


MON, MTR, SFA. 








EK, 


MON, MTR, SFA. 








SFA. 










x. 










GRH. 










GRH, 


MON, UCC. 








ACP. 










PCC. 










MON, 


UCC. 








GRH, 


PCC, RCI, RUB. 








ARC, 


FMP, WM, WTH. 








ACP, 


COM, DUP, EKT, ENJ, 


GRH, MON, PCC, 


PFZ, RCI, 


RUB 


sw 


, UCC. 








ACP, 


DUP, FMP, MON, PFZ. 








PFZ. 










DUP, 


EKT, KF, MON, PFZ. 








ACP, 


ENJ, GRH, TEK. 








UCC. 










UCC. 










ACP, 


BFG, EKT, ENJ, GRH, 


MON, PCC, RCI, 


RUB, TEK, 


UCC 


DUP, 


EKT, FWP, RCI, SFA, 


WTH. 






PFZ. 










EKT, 


KF, MON, PFZ, TCC. 








RCI. 











GRH, WTH. 

UCC. 

ACP, BFG. EKT, ENJ, GRH, MON, PCC, PFZ, RCI, RUB, 

TEK, UCC. 
ACP, H4J, GRH, MON, PCC, RCI, RUB, TEK, UCC. 
ASH. 
BFG. 
MON. 

ACP, ENJ, GRH, MON, PCC, PFZ, RCI, RUB, TEK, UCC. 
UCC. 

DA, MON. 

MON. 

ARG, HPC. 

ACP, GRH, UCC. 

DUP. 

TEK. 

ACP, RUB. 

ACP, GRH, MON, PCC, RCI, RUB, TEK, UCC. 

fWP, TEK, UCC, X. 



142 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 18B. --Plasticizers for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



PUSTICIZEBSj CYCLIC— Continued 

Polyethylene glycol dibenzoate 

Tetrahydrofurfuryl oleate 

Toluenesulfonamide, o-, p- mixtures 

»Trimellitio acid esters : 

n-Ootyl n-deoyl triraellitate 

Tri(2-ethylhexyl) triraellitate 

Triisodecyl triraellitate 

Triiso-octyl triraellitate 

*Trioctyl triraellitate 

All other trimellitio acid esters 

All other cyclic plasticizers 

PLASTICIZERS, ACYCLIC 

*Adipic acid esters: 

»Di(2-(2-butoxyethoxy )ethyl) adipate 

»Di(2-ethylhexyl) adipate 

Di-n-hexyl adipate 

Diisobutyl adipate 

*Diisodecyl adipate 

Diiso-ootyl adipate 

Diisopropyl adipate 

Dinonyl adipate 

Di-n-octyl adipate 

Di-n-propyl adipate 

n-Hexyl n-deoyl adipate 

Iso-octyl isodecyl adipate 

*n-Octyl n-decyl adipate 

Polyethylene glycol adipate 

All other adipic acid esters 

»Azelaic acid esters: 

Dicyclohexyl azelate 

Di(2-ethylbutyl) azelate 

Di (2-ethylhexyl ) azelate 

Diisobutyl azelate 

Diiso-ootyl azelate 

Di-n-ootyl azelate 

All other azelalo acid esters 

1,4-Butanediol dioaprylate 

Butoxyethyl pelargonate 

Citric and aoetylcitrio acid esters 

*Complex linear polyesters and polymeric plasticizers 

Di(butoxyethoxy-ethoxy)raethane 

Di(2-(2-butoxyethoxy )ethyl)methane 

Dibutyl tartrate 

Diethylene glycol dipelargonate (d onanoate) 

Diiso-ootyl diglyoolate 

*Epoxidized esters: 

Butyl epoxydioleate 

Butyl epoxystearate 

Butyl epoxytallate 

EJ)oxidized linseed oils 

*£t>oxidized soya oils 

IJ)oxidized tall oils 

»2-Ethylhexyl epoxytallates 

Octyl epoxystearates 

*Octyl epoxytallates 

All other epoxidized esters 

Glyceryl pelargonate 

Glyceiryl tributyrate and tripropionate 

Glycol pelargonate 

Isodecyl nonanoate (Isodecyl pelargonate) 

Laurie acid esters 

t^istic acid esters : 

Butyl nyristate 

»Isopropyl nyristate 

^Oleic acid esters: 

2-Butoxyethyl oleate 

■»Butyl oleate 



VEL. 

ccw, aiR. 

ACY, MON. 

GRH, PCC, RCI, TEK. 

PFZ, RCI. 

PFZ. 

RCI, RUB. 

GRH, PCC, RUB. 

PFZ, RUB. 

CCW, EKT, MON, NEV. 



FMP, 


RCI, TKL. 






DA, 


EKT, GRH, MON, 


PCC, RCI, 


RH, RUB, TEK, UCC, IVTH. 


ARC. 








FMP, 


GRH, HAL. 






AGP, 


EKT, GRH, MON, 


PCC, PFZ 


RCI, RH, RUB, TEK, UCC. 


PCC, 


RCI, RH, RUB. 






SBC, 


VND. 






TEK. 








ACP. 








ARC. 








ACP, 


PCC. 






GRH, 


RCI. 






ACP, 


GRH, MON, PCC, 


RCI, RH, 


RUB, TEK, TKL. 


PFZ. 








PFZ, 


RUB. 






PFZ. 








am. 








EKT, 


BAR, PCS, PFZ, 


RCI, RH, 


RUB. 


HAL. 








am. 








PFZ. 








ACP, 


MR. 






RUB. 








HAL. 








PFZ. 








ASH, 


EKT, am, HAL, 


MON, PFZ 


RCI, RH, RUB, TEK, UCC, 


WTH. 






TKL. 








GRD. 








ARC. 








MR. 








CCA, 


FMP. 






ASH. 








BAG. 








ASH, 


TEK. 






ASH, 


sm. 






ARG, 


ASH, BAG, RCI, 


RH, SWT, 


TEK, UCC. 


RCI. 








ASH, 


BAG, UCC. 






ARG. 








ARG, 


RH, TEK, UCC. 






FMH, 


RH. 






aiR. 








EKT. 








am. 








am. 








HAL, 


SBC. 







ARG. 

ARC, DA, DRW, ICI, PCS, PEN, SBC. 

ARC, HAL. 

ARC, CHL, DA, HAL, ICI, SWT, WM, WTH. 



PLASTICIZERS 



143 



TABLE 18B. --Plasticizers for which U.S. production or sales were reported, identified by 

manufacturer, i£>67— Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



PLASTICIZERS, ACYCLIC— Continued 

»01eio acid esters — Continued 

•Glyceryl triolate (Triolein) 

»Isopropyl oleate 

»Methyl oleate 

«n- Propyl oleate 

All other oleic acid esters 

Palmitic acid esters: 

Isobutyl palmitate 

Iso-ootyl palmitate 

*Isopropyl palmitate 

2-Methoxyethyl palmitate 

»Phosphorio acid esters : 

Tri(2-butoxyethyl) phosphate 

Tributyl phosphate 

Tri(2-chloroethyl ) phosphate 

Triethyl phosphate 

Trioctyl phosphate 

All other phosphoric acid esters 

Ricinoleic and aoetylricinoleic acid esters: 

n-Butyl aoetylrioinoleate 

*Butyl rioinoleate 

■>*Glyceryl monoricinoleate 

Glyceryl tri(acetylricinoleate) 

Methoxyethyl rioinoleate 

Methyl ricinoleate 

All other ricinoleic and aoetylricinoleic acid esters 
Sebaoic acid esters: 

Dibutoxyethyl sebaoate 

»Dibutyl sebaoate 

*Di(2-ethylhexyl ) sebaoate 

Diiso-octyl sebaoate 

All other sebacic acid esters 

^Stearic acid esters : 

Butoxyethyl stearate 

*n-Butyl stearate 

Dimethylammonium stearate 

2-Ethylhexyl stearate 

Glyceryl triacetyl stearate 

Hexadecyl stearate 

Isocetyl stearate 

Isopropyl stearate 

Methoxyethyl stearate 

Methyl dichlorostearate 

Methyl pentaohlorostearate 

Methyl stearate 

All other stearic acid esters 

Sucrose acetate isobutyrate 

Tetraethylene glycol di(2-ethylhexanoate) 

Triethylene glycol dioaprylate 

*Triethylene glycol di(oaprylate-caprate) 

Triethylene glycol di-2-ethylbutyrate 

Triethylene glycol di(2-ethylhexanoate) 

Triethylene glycol dipelargonate 

2,2,'4-Trimethyl-l, 3-pentanediol diisobutyrate 

All other acyclic plasticizers 



DRW, 


WS., 


PCS, 


SWT, WM. 


ma., 


ICI, 


SCP, 


WM. 


Bffi, 


ICI, 


SWT. 




CHL, 


aiR, 


SCP, 


WM. 


DRW, 


HAL, 


RH, 


VND. 


ARC, 


EKT, 


PEN. 




RUB. 








ARC, 


DRW, 


ICI, 


PCS, SBC 


EKT. 








FMP. 








MP. 








SFA, 


UCC. 






EKT. 








FWP, 


UCC. 






SM. 








BAC, 


WTH. 






BAG, 


DA, 


RCI. 




BAC, 


GLY, 


HAL. 




BAC. 








RCI. 








BAC. 








BAC, 


PFZ, 


RH. 





HAL, RCI. 

EKT, GRH, HAL, RCI, RH, WTH. 

GRH, HAL, RH, RCI, WTH. 

DA, RCI. 

DA, SBC. 



ARC, 

ARC, 

RH. 

FMP. 

BAC. 

SCP. 

WM. 

PEN, 

ARC. 

HK. 

HK. 

CHL. 

RCI, 

ARC, 

UCC. 

RUB. 

FOR, 

UCC. 

DA, 

RUB. 

EKX. 

ARC, 



WM. 

CHL, BAR, HAL, ICI, SCP, SWT, WTH. 



WM. 



WM, X. 

EKT. 



HAL, RUB, WM. 
EKT, UCC. 



CTA, MR, GLY, HAL, HPC, PFZ, RUB, SCP, TKL, WM. 



144 



SYNTHETIC ORGANIC CHEMICALS, 1967 



Surface -Active Agents 



TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer , 1967 

[ Surface-active agents for which separate statistics are given in table 19A are marked below with an asterisk (*); 
products not so marked do not appear in table 19A because the reported data are accepted in confidence and may not 
be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



Amphoteric Surface-Ac t ive Agents 

Acyclic: 

Alkylbetaine 

(l-Carboxyheptadecyl)trimethylammonium hydroxide, inner 

salt. 
rCarboxymethyl){ coconut oil alkyl)dimethylararaonium 

hydroxide, inner salt. 
(Carboxymethyl) [3- (coconut oil amido)propyl] dimethyl- 
ammonium chloride, sodium salt. 
(Carboxymethyl)[ 3- (coconut oil ajiiido)propyl] dimethyl- 
ammonium hydroxide, inner salt. 
(Carboxymethyl) dimethyl ^9-octadecenyl) ammonium hydroxide, 

inner salt. 
(Carboxymethyl)dodecyldimethylammonium hydroxide, inner 

salt. 
(l-Carboxyundecyl)trimethylammonium hydroxide, inner 

salt. 

N-(Coconut oil alkyl)-(j-alanine, sodium salt 

3-[(Coconut oil alkyl) amino] butyric acid sodium salt 

N-(2-Coconut oil amidoethyl)-N-(2-hydroxyethyl)glycine, 

sodiiim salt. 

N-Dodecyl-3-iminodipropionic acid 

N-Dodecyl-3-iminodipropionic acid, disodium salt 

N-(2-Hydroxyethyl)-N-(2-stearamidoethyl) glycine, sodium 

salt. 
Mixed acyclic primary amines, ethoxylated and sulfated, 

sodium salt. 

(Mixed alkyl )sulfobetaine 

Mixed fatty betaines 

Oleic acid - ethylenediamine condensate, propoxylated 

and sulfated, sodium salt. 

Polypeptide, ammonium salt 

Polypeptide, sodium salt 

N-(Tallow alkyl)-3-iminodiproplonlc acid, disodium salt — 

All other acyclic 

Cyclic: 
l,l-Bisi( carboxymethyl) -2-ujidecyl-2-imldazolinium hydrox- 
ide, disodium salt. 
l-Carboxymethyl-2-heptadecyl-l-(2-hydroxyethyl)-2- 

imidazollnium hydroxide, sodium derivative, sodium salt 
l-Carboxymethyl-l-(2-hydroxyethiyl)-2-nonyl-2-imidazo- 

linium chloride, sodium salt. 
l-Carboxymethyl-l-(2-Hydroxyethyl)-2-nonyl-2-imidazo- 

linium hydroxide, sodium derivative, sodium salt. 
l-Carboxymethyl-l-(2-hydroxyethyl)-2-undecyl-2-imldazo- 

linium hydroxide, sodium derivative, sodium salt. 
l-Carboxymethyl-l-('2-hydroxyethyl)-2-undecyl-2-imidazo- 

linium hydroxide, sodium salt. 
Heptadecylmethylbenzimldazolinesulfonlc acid, sodium 

salt. 
3-[2-(2-Mixed alkyl-2-imidazolln-l-yl)|etho:!y] propionic 

acid salt. 
3-[2-(2-Undecyl-2-imidazolin-l-yl)ethoxy] propanesulfonlc 

acid, sodium salt. 
3-[2-(2-Undecyl-2-imidazolin-l-yl)ethoxjr] propionic acid, 
sodium salt. 



DUP. 
DUP. 

CUL. 

JRG. 

UVC. 

DUP. 

TCC. 

DUP. 

GNM. 
ARC. 
TCC. 

GNM. 
GNM. 
GAF. 

RH. 

DDP, TXT. 

TXT. 
S. 

MYW. 
MCT. 
GNM. 
VAC. 

MIR. 

MIR. 

PCS, UVC. 

MIR. 

MIR, PCS. 

UVC. 

CIB. 

MOA. 

UVC. 

UVC. 



An 



tonic Surface-Ac t ive Agents 



»Carboxylic acids (and salts thereof): 

»Amine salts of fatty, rosin, and tall oil acids: 
Coconut oil acids, diethanolamine salt 



SEY. 



SURFACE-ACTIVE AGENTS 



145 



TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer , i967--Contlnued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



Anionic Surf ace-Act ive 4gcnls- -Continued 

»Carboxylio acids (and salts thereof) — Continued 
»Amine salts of fatty, rosin, and tall oil 

acids — Continued 

Coconut oil acids, ethanolamine salt 

Coconut oil acids, triethanolamine salt 

Oleic acid, butylamine salt 

Oleic acid, triethanolamine salt 

Stearic acid, morpholine salt 

Stearic acid, N,N,N',N'-tetrakis(2-hydroxyethyl)- 

ethylenediaraine salt. 

Stearic acid, triethanolamine salt 

Tall oil acids, diethanolamine salt 

Tallow acids, ethanolamine salt 

Tallow acids, triethanolamine salt 

»Carboxylic acids having amide, ester, or ether linkages: 

Butoxyethoxypropionic acid 

N-(Coconut oil acyl)polypeptide, ammonium salt 

N-(Coconut oil acyl)polypeptide, potassium salt 

N-(Coconut oil acyl)polypeptide, sodium salt 

N-(Coconut oil acyl)sarcosine 

N-(Coconut oil acyl)sarcosine, sodium salt 

Diisobutylene-maleic anhydride copolymer, ammonium and 

sodium salts. 

*N-Lauroylsarcosine, sodium salt 

N-(Mixed alkylsulfonyl)glycine, sodium salt 

Mixed linear alcohols, ethoxylated and carboxyalkylated, 

sodium salt. 

N-Oleoylpolypeptide, sodium salt 

N-Oleoylsarcosine, sodium salt 

Phthalic acid, octadecyl ester, potassium salt 

Stearolactolactic acid 

Stearolactolactic acid, calcium salt 

Stearolactolactic acid, sodium salt 

H-Stearoylsarcosine, sodium salt 

Tridecyloxypoly(ethyleneoxy) acetic acid, sodium salt — 

N-(Undecenoylpolypeptide), potassium salt 

Unspecified sarcosine derivatives 

*Potassium and sodium salts of fatty, rosin, and tall oil 

acids : 

Castor oil acids, potassium salt 

Castor oil acids, sodium salt 

Cocoa butter acids, sodium salt 

*Coconut oil acids, potassium and sodium salts: 

Potassium salt 

Sodium salt 

*Com oil acids, potassium salt 

*Com oil acids, sodium salt 

Laurie acid, potassium salt 

i<Mixed vegetable fatty acids, potassium salt 

^^ristic acid, potassium salt 

**01eic acid, potassium salt 

»01eic acid, sodium salt 

Olive oil acids, sodium salt 

Palm kernel oil acids, sodium salt 

Palm oil acids, sodium salt 

Peanut oil acids, potassixom salt 

Rosin acids, potassium salt 

Rosin acids, sodium salt 

Soybean oil acids, potassium salt 

Soybean oil acids, sodium salt 

"Stearic acid, potassium and sodium salts: 

Potassium salt 

Sodium salt 

*Tall oil aeids, potassium and sodium salts: 

•Potassium salt 

•Sodium salt 



SBP. 

EMR, SCP. 
DYS. 

DOM, HAL. 
CSB. 
ICI. 

GLY. 
SEY. 
SBP. 
SBP. 

uvc. 

MYW. 
MYW. 
MYW. 
GGY. 
HMP. 
RH. 

CP, GGY, HMP, ONX. 

GAF. 

SEY. 

LMI, MYW. 
GAF, GGY. 

CIB. 
GLY. 
GLY. 
GLY. 

GGY. 
UVC. 
MYW. 
HMP. 



ARL, BAC, SEA. 
HEW, MRV. 
HSY. 

ACE, AES, CSB, DYS, GAT, GRC, GRL, HEW, HNT, JRG, LUR, 

MCP, NMC, PCH, PG, SWT. 
AGP, CON, CP, GRC, HEW, JRG, LEV, NFR, PG, PRX. 
GRC, HNT, NMC. 
GRC, LUR, NMC. 
DA, DRW, VAL. 

AES, AML, DYS, GRC, GRL, PCH, SWT. 
AES. 
AES, AML, ARL, BSW, CCL, CPY, DA, DAN, GAF, GYR, HNT, 

QCP, S, SCP, SHP, USR, WBG. 
BSW, DA, GYR, LAK, LEV, LUR, MRV, NMC, SEA, SNW, SWT, 

WBG, WTC. 
HEW, HNT, LUR. 
HEW. 

HEW, LUH. 
KAL, SLC. 
ASY, GYR, USR, x. 
ASY, CRT, MRA, PLC, PRX, QCP, x. 
CON, DYS, HEW. 
HEW. 

GYR, HEW, VAL. 

DA, HEW, LEV, MAL, WTC. 

ACE, AES, CON, CSB, DRW, DSO, DYS, EFH, GAF, GRC, GYR, 

HNT, LUR, NMC, PNX, QCP, SOP, VAL, x. 
CPY, GRC, GYR, MRV, PRX, SOP, UNP, x. 



146 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 19B. 



-Surface-active agents for which U.S. production or sales were reported, identified by 
manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



Anionic Surf ace-Act ive 4gen(s • -Continued 

*Carboxylio acids (and salts thereof) — Continued 

^Potassium and sodium salts of fatty, rosin, and tall 
oil acids — Continued 

»Tallow acids, potassium salt 

»Tallow acids, sodium salt 

All other 

^Phosphoric and polyphosphoric acid esters (and salts 
thereof) : 
*Aloohols and phenols, ethoxylated and phosphated: 

Butyl alcohol, ethoxylated and phosphated 

p-tert-Butylphenol, ethoxylated and phosphated 

Dinonylphenol, ethoxylated and phosphated 

Dodecyl alcohol, ethoxylated and phosphated 

Dodecyl alcohol, ethoxylated and phosphated, barium 
salt. 

2-Ethylhexanol, ethoxylated and phosphated 

»Mixed linear alcohols, ethoxylated and phosphated 

»Nonylphenol, ethoxylated and phosphated 

9-Octadecenyl alcohol, ethoxylated and phosphated 

Octylphenol, ethoxylated and phosphated 

Octylphenol, ethoxylated and phosphated, magnesium 
salt. 

Phenol, ethoxylated and phosphated 

Polyhydric alcohol, ethoxylated and phosphated 

»Tridecyl alcohol, ethoxylated and phosphated 

All other 

*Alcohols, phosphated or polyphosphated : 

Decyl, dodecyl, and octyl phosphate, morpholine salt-- 

Decyl polyphosphate, triethanolamine salt 

2-Ethylhexyl phosphate 

■"■2-Ethylhexyl phosphate, sodium salt 

2-Ethylhexyl polyphosphate 

Hexyl polyphosphate, potassium salt 

Mixed alkyl phosphate 

Mixed alkyl phosphate, diethanolamine salt 

9-Octadeoenyl phosphate 

Octadecyl phosphate, triethanolamine salt 

»Ootyl phosphates: 

Octyl phosphate 

Octyl phosphate, alkylamine salt 

Octyl phosphate, potassium salt 

Octyl polyphosphate 

Octyl polyphosphate, potassium salt 

Octyl polyphosphate, sodium salt 

All other 

^Sulfonic acids (and salts thereof): 
»Alkylbenzenesulf onates : 

»Dodecylbenzenesulfonates : 

*Dodecylbenzenesulf onic acid 

Dodecylbenzenesulfonic acid, ammonium salt 

Dodecylbenzenesulfonic acid, butylamine salt 

^Dodecylbenzenesulfonic acid, calcium salt 

Dodecylbenzenesulfonic acid, diethanolamine salt-- 
Dodecylbenzenesulfonic acid, ethylenediamine salt-- 

^Dodecylbenzenesulfonic acid, isopropanolamine salt- 

^Dodecylbenzenesulfonic acid, isopropylamine salt-- 
Dodecylbenzenesulfonic acid, (mixed alkyl) amine 

salt. 
Dodecylbenzenesulfonic acid, potassium salt 

»Dodecylbenzenesulfonic acid, sodium salt 

Dodecylbenzenesulfonic acid, strontium salt 

wDodecylbenzenesulfonic acid, triethanolamine salt- 



ASY, CPY, NMC, PG, SWT. 

AGP, hSt, BSW, CON, CP, DA, DYS, GRC, GYR, HEW, JRG, 

LEV, LUR, NMC, NPR, PG, PLC, PRX, QCP, SCP, SWT. 
NMC. 



OAF. 
RTF. 
GAP. 

GAP, WIC. 
GAP. 

WAY. 

CHP, CRT, CST, GAP, SEY, WAY. 

GAP, HDG, NLC, RTP, SCP, TCC, TXT, VAC, WAY. 

GAP. 

RH. 



ARC, 


GAF. 








NLC. 










ARC, 


GAP, 


LUR, 


NLC, 


TCC, WAY 


GAP. 










DUP. 










RCD. 










WAY. 










SEY, 


TCI, 


UCC, 


UVC. 




TCC, 


TCI, 


UVC. 






DEX. 










CST, 


DUP, 


GAP, 


SFA, 


TCC. 


DUP. 










DUP. 










RCD. 










DUP. 










DUP, 


TXT. 








DUP. 










DEX, 


TXT. 








X. 










SFA. 










NLC. 











ACS, ARD, CO, CRT, CTL, EMK, HLI, LAK, LEV, MON, PIL, 

RCD, RTP, STP, TCI, TDC, TEN, TXT, WTC. 
AKS, ARL, PLX. 
SOP, WTC. 

APD, NLC, RCD, RH, RTF, STP, WTC, x. 
VAL. 

APD, RTF. 
CTL, RCD, X. 

APD, ARD, CTL, RCD, RTF, SNW, STP. 
VAL, WTC. 

RCD, SOP, VAL. 

AAC, ACS, AKS, APX, ARD, ARL, ATR, BLA, CO, CP, CRT, 

CTL, DA, DEP, ESO, EFH, HLI, HRT, LEV, MON, PEK, 

PG, PIL, PLX, PRX, RCD, RTF, STP, TEN, TXT, UNP, 

VAC, WTC. 
RTF. 
ACC, ACS, AML, ARD, ARL, ATR, CRT, CTL, DSO, DYS, 

HLI, PCS, PIL, RCD, RTF, SOS, STP, VAC. 



SURFACE-ACTIVE AGENTS 



147 



TABLE 19B. —Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer, i567--Continued 



Chemical 



Anionic Surface-Active .4gents - -Continued 

•Sulfonic acids (and salts thereof) — Continued 
»Alkylbenzenesulfonates — Continued 
»Other alkylbenzenesulfonates: 

D-3oylbenzenesulfonic acid, sodium salt 

Didodecylbenzenesulfonic acid 

Didodecylbenzenesulfonic acid, sodium salt 

(Mixed higher alkyl)benzenesulfonic acid 

(Mixed higher alkyl)benzenesulfonic acid, ammonium 
salt. 

Pentadecylbenzenesulfonic acid, potassium salt 

Pentylbenzenesulfonio acid, sodium salt 

»Tridecylbenzenesulfonic acid 

Tridecylbenzenesulfonic acid, sodium salt 

Tridecylbenzenesulfonic acid, triethanolamine salt- 

Undecylbenzenesulfonic acid 

Undecylbenzenesulfonic acid, ammonium salt 

Undecylbenzenesulfonic acid, sodium salt 

Undecylbenzenesulfonic acid, triethanolamine salt — 

All other 

•Benzene-, cumene-, toluene-, and xylenesulfonates: 

Benzenesulfonic acid, sodiirai salt 

Cumenesulfonic acid, ammonium salt 

a.-i-Dinitrobenezenesulfonic acid, sodium salt 

Toluenesulfonic acid 

Toluenesulfonic acid, potassium salt 

Toluenesulfonic acid, sodium salt 

Toluene- and xylenesulfonic acids, sodium salt 

»Xylenesulfonic acid, ammonium salt 

Xylenesulfonic acid, potassium salt 

•Xylenesulfonic acid, sodium salt 

•Ligninsulf onates : 

Ligninsulfonic acid, aluminum salt 

Ligninsulfonic acid, ammonium salt 

•Ligninsulfonic acid, calcium salt 

•Ligninsulfonic acid, chromiimi salt 

Ligninsulfonic acid, iron salt 

Ligninsulfonic acid, magnesium salt 

Ligninsulfonic acid, mixed salts 

•Ligninsulfonic acid, sodium salt 

•Naphthalenesulf onates : 

•Butylnaphthalenesulfonic acid, sodium salt 

Dibutylnaphthalenesulfonic acid 

Didodecylnaphthlenesulfonic acid, sodium salt 

•Diisopropylnaphthalenesulfonic acid and sodium salt: 

Diisopropylnaphthalenesulfonic acid 

Diisopropylnaphthalenesulfonic acid, sodium salt 

Dipentylnaphthalenesulfonic acid, ammonium salt 

Dipentylnaphthalenesulfonic acid, (mixed alkyl)amine 
salt. 

Dipentylnaphthalenesulfonic acid, sodium salt 

Isopropylnaphthalenesulfonic acid 

Isopropylnaphthalenesulfonic acid, ammonium salt 

Methylenebis(2-naphthalenesulfonic acid) 

6,6' -Methylenebis(2-naphthalenesulfonic acid ), 
calcium salt. 

Methylnaphthalenesulfonio acid, sodium salt 

Methylnonylnaphthalenesulfonic acid, sodium salt 

Tetrahydronaphthalenesulfonic acid 

•Sulfonic acids having amide linkages : 

N-(Coconut oil acyl)-N-methyltaurine, sodium salt 

N-Cyclohexyl-N-palmitoyltaurine, sodium salt 

•N-Methyl-N-oleoyltaurine, sodium salt 

N-Methyl-N-palmitoyltaurine, sodium salt 

N-Methyl-N-(tall oil acyl)taurine, sodium salt 

N-Methyl-N- ( tallow acyl)taurine, sodium salt 



Manufacturers' identification codes 
(according to list in table 22) 



MON 






CO. 






CO. 






TXT. 






RTF. 






STP. 






MON. 






KON, 


NPR, ROD, TXT. 




BLA, 


CP, NPR, RCD, WTC. 




PCS. 






TXT. 






TXT. 






TXT. 






TXT. 






USE. 






NES. 






STP. 






NES. 






NES, 


RCD. 




NES, 


RCD, STP, TXN. 




CO, 


NES, PIL, STP, WTC. 




CO. 






ATR, 


CO, HLI, NEX, RCD, STP, WTC. 




NES, 


STP, 




ATR, 


CO, HLI, JRG, NES, PIL, RCD, STP, TXN, WTC 


MAR. 






CPP, 


CRZ. 




CRZ, 


CWP, GLY, LKY, LPC, MAR, PSP. 




DCP, 


MAR, RAY. 




CRZ, 


WVA. 




LPC, 


MAR. 




PSP. 






CRZ, 


CWP, MAR, RAY, SNC, WVA. 




CLD, 


CMC, GGY, PFZ. 




GAT, 


S. 




PFZ. 






DDP, 


GAF. 




ACS, 


GAF, PFZ. 




NLC. 






NLC. 






OCT. 






DA, DUP, GRD, ONX. 




NLC. 






DUP. 






DUP. 






UDI. 






UDI. 






DUP. 






GAF, 


MCP, TNI. 




GAF. 






CRT, 


DA, DEP, DRW, GAF, HRT, MRA, PCI. 




GAF. 






GAF, 


WTC. 




GAF. 







148 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



Anionic Surface-Active /Agents- -Continued 

^Sulfonic acids (and salts thereof) — Continued 
»Sulfonic acids having amide linkages: 
»Sulfosuccinamic acid derivatives: 

N-(l,2-Dicarboxyethyl)-N-octadecylsulfosuccinaiiiic 

acid, tetrasodium salt. 
U_(2_Hydroxyethyl )-.!-( tallow alkyl)sulfosuccinamic 
acid, disodium salt. 

N-Octadeoylsulfosuccinamio acid, disodium salt 

N-(01eoyloxyisopropyl)sulfosuccinamic acid, 
disodium salt. 
Sulfosuccinic acid, alkanolamide ester, sodium salt-- 
Sulfosuccinic acid, 2-(Coconut oil amido)ethyl ester, 
disodium salt. 
»Sulfosuccinic acid esters : 

Sulfosuccinic acid, bis(2,6-dimethyl-';-heptyl) ester, 
sodium salt. 
^Sulfosuccinic acid, bis(2-ethylhexyl) ester, sodium 
salt. 
Sulfosuccinic acid, bis(tallow monoglyceride ) ester, 
sodium salt. 

Sulfosuccinic acid, dihexyl ester, sodium salt 

Sulfosuccinic acid, dioctyl ester, sodium salt 

Sulfosuccinic acid, dipentyl ester, sodium salt 

Sulfosuccinic acid, ditridecyl ester, sodium salt 

»A11 other sulfonic acids: 

Butylhydroxybiphenylsulfonic acid 

Coconut oil acids, 2-sulfoethyl ester, sodium salt — 

Dodecyldiphenyloxidedisulfonic acid, disodium salt 

Dodecyl sulfoacetate 

2-ljauroyloxy-l-propanesulfonic acid 

Methyl 2-sulfostearate 

Mixed alkanesulfonic acid, sodium salt 

Octylphenol, ethoxylated and sulfonated, sodium salt- 
Petroleumsulfonic acid, water soluble (acid layer), 
sodium salt. 

All other 

Sulfuric acid esters (and salts thereof): 
»Acids, amides, and esters, sulfated: 

»Coconut oil acids - ethanolamine condensate, sulfated 

potassium salt. 
»Esters of sulfated oleic acid: 

2-Butoxyethyl oleate, sulfated, sodium salt 

»Butyl oleate, sulfated, sodium salt 

Ethyl oleate, sulfated, sodium salt 

Glycerol trioleate, sulfated, sodium salt 

»Isopropyl oleate, sulfated, sodium salt 

Methyl oleate, sulfated, sodium salt 

»Propyl oleate, sulfated, sodium salt 

»01eic acid, sulfated, disodium salt 

*Tall oil, sulfated, sodium salt 

»Other acids, amides, and esters, sulfated: 

Butyl ricinoleate, sulfated, disodium salt 

Coconut oil acids - isopropanolamine condensate, 

sulfated, sodium salt. 
Glycerol monoester of coconut oil acids, sulfated, 

sodium salt. 
Neat's-foot oil acids - ethanolamine condensate, 

sulfated, ammonium salt. 

9-Octadecenyl acetate, sulfated, sodium salt 

Oleic acid - ethanolamine condensate, sulfated, 

sodium salt. 

Oleostearin, sulfated, sodium salt 

Propyl ricinoleate, sulfated, disodium salt 

Ricinoleic acid, sulfated, disodium salt 

All other 

»Alcohols and phenols, sulfated: 

»Coconut and sperm oil alkyl sulfate, sodium salt 



ACY. 
SCP. 



ACY, CTA. 
WTC. 



HDG. 
LAK. 



OAF, SCP. 

ACY, AKS, CRT, CST, DAN, EFH, EMK, GGY, HDG, HHT, ICI, 

MCP, MOA, PC, SBC, SCP, TCI. 
ACY. 

ACY, MCP, MOA, SNW. 

RH. 

ACY. 

ACY, MOA. 

RBC. 

GAF, LEV. 

DOW. 

ACS. 

cue, SDH. 

ARC. 

DUP, VPC. 

CRT, RH. 

SIN, VAL, WTC. 

STC. 



DEX, EMK, ONX. 



AKS, CHP, DA, ICI, MCP, ONX, PC. 

GAF. 

LEA, MRV, SCP. 

BRY, CRT, DEX, HRT, ICI, LEA, LUR, SCP. 

DA, ICI. 

ACY, CHP, EFH, GAF, MCP, MRV. 

ACT, ACY, CHP, CRT, DA, DRW, GAF, ICI, LEA, MRV, PCI, 

SCO, SCP, TEN, WHI, WHW. 
ACY, APX, BAO, DA, ICI, MRV, RTF, SEA, WHI. 

DA. 
APX. 

AAC, CP. 

APX. 



DUP. 
SCP. 

SEA. 
AKS. 
DA. 

EMR. 



DEP, DUP, SCP. 



SURFACE-ACTIVE AGENTS 



149 



TABLE 19B. -Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer, 75^7— Continued 



Chemieal 



Manufacturers' identification codes 
(according to list in table 22) 



Anionic Surface -Act ivf -4gcnts - -Continued 

Sulfuric acid esters (and salts thereof J — Continued 
"Alcohols and phenols, sulfated--Continued 
»Dodeoyl sulfate salts: 

2-Amino-2-methylpropanol salt 

»Ammonium salt 

Dlethanolamine salt 

N,N-Diethyloyclohexylaniine salt 

Isopropanolamine salt 

"Magnesium salt 

Potassium salt 

"Sodium salt 

"Triethanolamine salt 

•Hexadecyl sulfate, sodium salt 

•Mixed linear alcohol sulfate salts: 

Ammonium salt 

Polyamine salt 

Sodium salt 

"Octadecyl sulfate salts: 

Sodium salt 

Triethanolamine salt 

"Other alcohols and phenols, sulfated: 
Linear alcohols, sulfated: 

Decyl and octyl sulfate, sodium salt 

Decyl sulfate, sodium salt 

Decyl sulfate, triethanolamine salt 

Hexadecyl and 9-octadecenyl sulfate, sodium salt-- 

Hexyl sulfate, potassium salt 

Hexyl sulfate, sodium salt 

Nonyl sulfate, sodium salt 

Octyl sulfate, sodium salt 

Phenols and nonlinear alcohols, sulfated: 

Branched hexadecyl sulfate, sodium salt 

3-9-Diethyl-6-tridecyl sulfate, sodium salt 

2-Ethylhexyl sulfate, sodium salt 

7-Ethyl-2-methyl-'i-undecyl sulfate, sodium salt 

Trichlorophenol sulfate, ethanolamine salt 

Tridecyl sulfate, sodium salt 

"Ethers, sulfated: 

"Alkylphenols, ethoxylated and sulfated: 

Dodecylphenol, ethoxylated and sulfated, ammonium 
salt. 

(Mixed alkyl)phenol, ethoxylated and sulfated, 
ammonium salt. 

Nonylphenol, ethoxylated and sulfated, ammonium 
salt. 

Nonylphenol, ethoxylated and sulfated, sodium salt-- 

Nonylphenol, ethoxylated and sulfated, triethanol- 
amine salt. 

Octylphenol, ethoxylated and sulfated, sodium salt-- 
"Dodecyl alcohol, ethoxylated and sulfated, ammonium 

salt. 
•Dodecyl alcohol, ethoxylated and sulfated, sodium salt 
"Mixed linear alcohols, ethoxylated and sulfated, 

sodium salt. 
"Tridecyl alcohol, ethoxylated and sulfated, sodium 

salt. 
•Other sulfated ethers: 

Dodecyl and tetradecyl alcohols, ethoxylated and 
sulfated, ammonium salt. 

Hexyloxypropyl sulfated, sodium salt 

Mixed linear alcohols, ethoxylated and sulfated, 
ammonium salt. 

Mixed linear alcohols, ethoxylated and sulfated, 
potassium salt. 

Sperm oil alcohol, ethoxylated and sulfated, sodium 
salt. 

All other 



DUP. 

AAC, CTL, CUL, DUP, ONX, PCS, SOP, STP. 

CUL, DUP, HLI, JHG, SCP, STP, WTC. 

DUP. 

JRG, PCS. 

AAC, HLI, SCP, STP. 

HLI, PC. 

AAC, CTL, CUL, DUP, HLI, JRG, ONX, PCS, PG, RCD, STP. 

AAC, CTL, CUL, DUP, HLI, ONX, PCS, PG, RCD, SCP, STP, 

TXT. 
AAC, DUP, SCP. 



LAK, 


S, TXT. 




NLC. 








LAK, 


SCP, 


TXT. 




DUP, 


EMK, 


ONX, 


PG. 


DUP. 








PCS. 








CTL, 


DUP, 


ONX, 


PCS 


DUP. 








RCD. 








DEX. 








GAF. 








TEN. 








AAC, 


DUP. 






APX. 








UCC. 








AAC, 


SCP, 


UCC, 


WTC 


UCC. 








GAF. 








ACC, 


DUP, 


SCP. 




GAF. 








GAF. 








CIB, 


GAF, 


STP, 


TXT 


CRT, 


GAF. 






ARL. 









RH. 

AAC, CTL, HLI, ONX, PG, SCP. 

AAC, CTL, CUL, DUP, ONX, PCS, RCD, SCP, STP, TCI. 

CRT, GAF, LAK, NLC, RCD, RTF, SCP, TCI, TXT, UCC. 

AAC, ARL, ONX, RCD. 



LEV. 

S. 

CO, GAF, LAK, NLC, RCD, SCP, SHC, STP, TXT, UCC. 

CO, SHC, STP, TXT. 

DUP. 

APX, PG. 



150 SYNTHETIC ORGANIC CHEMICALS, 1967 

TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer, iS67— Continued 







Manufacturers' identification codes 


Chemical 




(according to list in table 22) 


Anionic Surface-Active :4gen(s--Coiitinued 






Sulfuric acid esters (and salts thereof) — Continued 






*Natural fats and oils, sulfated: 






wAnlraal (including fish) oils, sulfated: 






»Cod oil, sulfated, sodium salt 


ACT, 


BAO, CRT, DRW, MRD, S, SEA, WAW, WHI, WHW. 


Grease, other than wool, sulfated, sodium salt 


DA, 


SEA, WHI, WHW. 


Herring oil, sulfated, sodium salt 


WHI. 




Lard, sulfated, sodium salt 


WAW. 




^Aixed fish oils, sulfated, sodium salt 


AML, 


SCO, WHI. 


»Neat's-foot oil, sulfated, sodium salt 


ACT, 


BAO, CRT, DA, KAL, LUR, MRD, PC, SEA, WHW. 


»Sperm oil, sulfated, sodium salt 


ACT, 


AKS, BAO, CLD, CRT, DA, DRW, HRT, KAL, KNG, LEA, 




MRD, ONX, RTC, S, SEA, WHI, WHW. 


.,-, ,. ,, 


ACT, 
LH 


APY AKS RRY BSW DA DRW EFH. ICI KAL LEA. 


■*Tallow, sultated, soaium salt 


R, MCP, MRA, MRD, ONX, PC, PCI, SCP, SEY, SID, 




SNW, SOS, WHI. 


Whale oil, sulfated, sodium salt 


KNG. 




*Vegetable oils, sulfated: 






»Castor oil, sulfated, sodium salt 


AAE, 


ACT, ACY, _ AKS, AML, APX, BAO, BRY, BSW, CRT, DA, 




DEX, DRW, OAF, HRT, ICI, KAL, KNG, LEA, LUR, MCP, 




MRA, MRD, MRV, ONX, PC, S, SCO, SCP, SEA, SLC, WHI, 
WHW. 
ACY, BAO, DA, KNG, MRD, SEA, WHW. 


»Coconut oil, sulfated, sodium salt 


Cottonseed oil, sulfated, sodium salt 


DA, 


RTC. 


Mustard seed oil, sulfated, sodium salt 


DA, 


LUR. 


Peanut oil, sulfated, sodium salt 


ACY, 


DA, ICI, LEA, LUR, SCP, SLC. 


*Ricebran oil, sulfated, sodium salt 


DA, 


EFH, KNG, LUR. 


»Soy'bean oil, sulfated, sodium salt 


CRT, 


DA, DRW, HRT, KAL, LEA, MRD, ONX. 


Other anionic surface-active agents: 






Lignin (non-sulfonated) and salts thereof 


WVA. 




Mixed linear alcohols, ethoxylated and carbonated, 


S. 




sodium salt. 






Tridecyl alcohol, ethoxylated and carbonated sodium 


S. 




salt. 






Cationic Surface-Ac t ive Agents 






*Amine oxides and oxygen-containing amines (except those 






having amide linkages ) : 






»Acyclic: 






N,N-Bis(2-hydroxyethyl) (coconut oil al}cyl)amine oxide- 


ARC. 




fcT hi D.id-*^0 Vnf-^ -M^^ij-i rd^+Vnrl ^i-^/^/^^i^^ -tf~\ arTi "Tn^ ___^^_^^ 


CTL, 


FIN. 


N, N-Dis (, £^-nyaroxyeT-nyi jaoaecyiainine 




kJ M Dtj^TO Viirx-l-ni'-* ■v-iT*^+ VnrT Id^^+O/^O i^ ArT Qim T^d ^ ^ ^ ^ -^ -.^ '^ 4 — i— i— ^^^^^^ 


ARC, 


FIN. 


N,N-Dis ^ ,:;-nyaroxyetnyj.,;oG Lauccy xaiiLLiit; - 




N,N-Bis(2-hydroxyethyl)octadecylainine oxide 


ARC. 
ARC. 




N,N-Bis(2-hydroxyethylJ ^tallow aiisyijamine 




N,N-Bis(2-hydroxyethyl) (tallow alkyl)amine acetate 


PG. 




N,N-Bis(2-hydroxyethyl) (tallow alkyl)amine oxide 


ARC. 




\j //^„— .,.^fc--»4. ^^tT riT Ir^ tH InTnTr^di ^"t'Vi rw~\r T 0^"t:iH_— ^ — ^^^^^^^^^«*_^ 


AAC, 


APD, ARC, NLC, SDW, SNW, TCH, VAC. 


*^Ooconut oii aiKyijamine, eLnoxyxai^eu 


(Coconut oil all5yl)amine, ethoxylated, acetate 


RFC. 




(Coconut oil all<yl)amine, ethoxylated, maleate 


SDH. 
ARC. 




t^uoconub oil aiKyi;ajiiine, propoxyiuijeu 




t^ cy r\-^ ^.v+'Vm'T '7 Vt-Trd v^^--.\f"t Tt^j-^f^at-in-Y^t^ C^ F^y~\ct t'^'v'^ xr\a _^_^-^^_^__^ 


GNM. 




9,y-iJietny±- /-nyuroxyaoaecane-o-one oxime 




N,N-Dimethyl( coconut oil alkyl)amine oxide 


ARC. 




N,N-Dimethylhexadecylamine oxide 


ARC, 


ONX. 


/tt. ..>3i»..nr*^-.i»^A-i-.^^ 4-«^in^^*.v j-*ni*-*fT ^r^»wi»^*-i £i + Viz-^v^rT o "t" ^/^ ^^ 


CIB, 


TCH. 


(.jiyurogenatea taiiow aiKyijaimne, eiinoxyiabeu 


N- ( 2-Hydroxyethyl) -N, M ' , N '-tris ( 2-hydroxypropyl ) 


NLC. 




ethylenediamine . 








APD, 

GNM. 


rTR DA GAF RH. 


*t.Mixea aXKyijamine, eLnojcyiaxea 


\J A-LJ y Jh'JI % ^-A^\A. y il.i L a 


Mixed substituted oximes 


ARC. 




^y— UCTiauecenyi jainine , e uiioxy laucu- 






ARC, 


TCT TCH 


UcxaaeGyiainine, eonoxyiai-ea 


XVV.i.« ± \JIX U 




NLC. 




roiyetiiy ienepoiyaimne , aiKoxyiaLea 




M. r O ^^^fVt^^ #^*-t ^..^t"! r^ll*-»Tl \ r\-rt\A 'v^q j^ + V^ H'^\/-ir nQ + dH _ ^^^ ^^^.-*-^^ 


AAC, 


ARC HDG RTF. VAC. 


■*l,c)oyDean on aiKyi;ajnine, exnoxyiabeu 


J'l.X\,\J y I U.'^J y X\^ ^ y * Jt\j • 


^ /T'^iTT^mr ^»n 1^1. 1 1 nrm* r\i^ ti + Vi^^ virT 0't'QH__^^^_-._^^_^— — — ^^ — — — — — 


AAC, 


ARC, ASH, CIB, DUP. 


*( laiiow aXKyi jajnine, sLnoxyxai^eu — 




N-CTallow alkyljtriraethylenediamine, ethoxylated 


ARC, 


RTF. 


N,N,N', N'-Tetrakis(2-hydroxyethyl)ethylenediamine 


NLC. 




rl,N,N',N'-Tetrakis(2-hydroxypropyl)ethylenediamine, 


WYN. 




propoxylated and ethoxylated. 






All other 


GAP, 


X. 



SURFACE-ACTIVE AGENTS 



151 



TABLE 19B. —Surface-active agents for which U.S. production or sales mere reported identified by 

manufacturer, 7567— Continued 



Chemical 



Cationic Surface-Act ive Agents - -Continued 

tAmine oxides and oxygen-containing amines (except those 
having amide linkages) — Continued 
»Imidazoline and oxazoline derivatives: 

2-(8-Heptadeoenyl)-'V,'i-bls(hydroxymethyl)-2-oxa- 
zoline . 
»2-(8-Heptadecenyl)-l-(2-hydroxyethyl)-2-imidazoIine-- 
2-(8-Heptadecenyl)-'i-hydroxyinethyl-'4-methyl-2-oxa- 
zoline. 

»2-(Heptadeoyl)-l-(2-hydroxyethyl)-2-imadazoline 

l-(2-Hydroxyethyl)-2-nony 1-2- imidazoline 

l-(2-Hydroxyethyl)-2-nor(coconut oil alkyl)-2-imidazo 

line. 
l-(2-Hydroxyethyl)-2-nor(tall oil all(yl)-2-imidazo- 

line. 
l-(2-Hydroxyethyl)-2-tridecyl-2-imidazoline hydro- 
chloride. 

l-(2-Hydroxyethyl)-2-undecyl-2-imidazoline 

2-(ll-Hydroxy-8-heptadecenyl)-2-iinidazoline 

»Cyclic products (except imidazoline and oxazoline 
derivatives) : 

N-(Coconut oil alkyDmorphollne oxide 

N-Hexadecylmorpholine 

N- ( 2-Hydroxyethyl) -1, 2-dlphenylethylenediamlne 

Lignin amine 

Piperazine, ethoxylated 

»Rosin amine, ethoxylated 

N-(Soybean oil alkyl)morpholine 

•Amines and amine oxides having amide linkages : 

»Carboxylic acid - diamine and polyamlne condensates: 

Capryllc acid - tetraethylenepentamlne condensate 

*Coconut oil acids - diethylenetriamlne condensate 

*Coconut oil acids - N, N-dimethyltrimethylenediamlne 

condensate. 
Mixed fatty acids - polyalkylenepolyamlne condensate- 

Olelc acid - l-(2-ajiilnoethyl)plperazlne condensate 

Oleic acid - diethylenetriamlne condensate 

Oleic acid - N,N-dlmethyltrimethylenedlamlne con- 
densate. 
Pelargonic acid - tetraethylenepentamlne condensate--- 

•Stearic acid - diethylenetriamlne condensate 

Stearic acid - N,N-diethylethylenedlamlne condensate-- 

Stearic acid - dlpropylenetriamine condensate 

Stearic acid - tetraethylenepentamlne condensate 

Tall oil acids - diethylenetriamlne condensate 

Tall oil acids - polyalkylenepolyamlne condensate 

All other 

"Stearic acid - ethylenediamine condensate, mono- 

ethoxylated . 
•Other amines and amine oxides having amide linkages: 
H, N-Bis ( 2-hydroxyethyl ) -2- ( stearamldomethoxy ) ethy 1- 

amine. 
Coconut oil acids - diethylenetriamlne condensate, 

polyethoxylated . 
Coconut oil acids - ethylenediamine condensate, 
monoethoxy lated . 

3-Lauramldo-N,N,dlmethylpropylamlne oxide 

Oleic acid - ethylenediamine condensate, mono- 
ethoxy lated. 
Palm oil acids - ethylenediamine condensate, mono- 
ethoxy lated. 

Polypeptide, ethyl ester 

Stearic acid - N-(2-cyanoethyl)dlethylenetrlamlne 

condensate (amlne/acid ratlo=l/2). 
Stearic acid - diethylenetriamlne condensate, poly- 
ethoxylated. 
Stearic acid - ethylenediamine condensate j poly- 
ethoxylated. 



Manufacturers' Identification codes 
(according to list In table 22) 



COM, SWT, UVC. 



NLC, 


ONX, 


UVC, 


VAC. 


COM, 


UVC. 






GGY, 


MOA, 


PCS, 


UVC. 


UVC. 








GGY, 


UVC. 






CUL, 


NLC, 


UVC, 


VAC, X 


UVC, 


WTC. 






MOA, 


UVC. 






UVC. 








ARC. 








APD. 








APX, 


HDG. 






WVA. 








GAP. 








HPC, 


NLC, 


PCS, 


RTF. 


APD. 








ICI. 








APX, 


DA, 


TXT. 




JRG, 


PCS, 


RCD, 


TXT. 


GRD, 


NLC. 






TXT. 








APD, 


PCS, 


TXT. 




CCW, 


CIB, 


SNW. 




ICI. 








APX, 


CST, 


HRT, 


ONX, P 


CBP. 








JOR. 








ICI, 


ONX. 






NCW, 


NLC, 


RTF. 




UVC. 








TXT, 


VND. 






AML, 


CLD, 


CMG, 


CST, Dj 


CIB. 








TCC. 








Am, 


DA. 







SNW. 

CLD, DA, DEX, SOC, TNA. 

APX. 

MYW. 
CIB. 

TCC. 

APD. 



152 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 19B. Surface -active agents for which U.S. production or sales uiere reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



Cationic Surface-Active 4gen(s - -Continued 

»Anu.nes, not containing oxygen (and salts thereof): 
*Amine salts: 

(Coconut oil alkyl)amine acetate 

N- (Coconut oil all!yl)triinethylenediainine acetate 

N-(Coconut oil all!yl)trimethylenediamine adipate 

N-(Coconut oil all<yl)trimethylenediaiiiine dicaprylate- 

(Hydrogenated tallow alkyl)amine acetate 

(9-Octadecenyl) amine acetate 

Octadecylamine acetate 

Octylamine acetate 

(Soybean oil alkyl)amine acetate 

(Tallow all(yl)amine acetate 

N-(Tallow alkyl)trimethylenediamine acetate 

N- (Tallow alkyl)trimethylenediamine naphthenate 

N-(Tallow alkyl)trimethylenediamine oleate 

N- (Tallow alkyl)trimethylenediamlne tallate 

All other 

^Diamines and polyamines: 

l-(2-Aminoethyl)-2-(mixed all(yl)-2-imidazoline» 

l-[3-(2-aminoethyl)naphth-l-yl]-2-(8-heptadecenyl) 

-2-imidazoline. 
l-(2-Aminoethyl)-2-nor(tall oil alkyl)-2-imldazoline 

»N-(Coconut oil alkyl)trimethylenediamlne 

N-(Docosyl and eicosyl)trimethylenediamine 

N-Dodecyldiethylenetriamine 

2-Heptadecyl-2-imidazoline 

N- (Mixed alkyl)polyethylenepolyamine 

»N-(9-0ctadecenyl)trimethylenediamine 

N-(Soybean oil alkyDtrimethylenediamine 

N-(Tall oil allsyl)trimethylenediamine 

N- (Tallow alkyl)dipropylenetriamine 

»N-( Tallow alkyl)trimethylenediamine 

^*Primary monoamines : 

»(Coconut oil alkyl)amine 

(Cottonseed oil alkyl)amine 

Docosyl- and eicosylamine 

Dodecylaraine 

Hexadecylamine 

»( Hydrogenated tallow all<yl)amine 

(Mixed alkyl) amine 

(Mixed tert-alkyl) amine 

*9-0ctadecenylamine 

»Ootadecylamine 

Octylamine 

tert-Octylamine 

(Soybean oil alliyl)amine 

»(Tall oil alkyl)amine 

»( Tallow alkyl) amine 

Tetradecylamine 

^Secondary and tertiary monoamines: 

Bis(coconut oil alkyl)amine 

Bis (hydrogenated tallow alkyl)amlne 

»N,N-Dimethyl(coconut oil alkyl)amine 

N,N-Dimethyldodeoylamine 

N,N-Dimethylhexadecylamine 

N,N-Dlmethyl( hydrogenated tallow alkyljamine 

N,N-Dimethyl (mixed alkyl) amine 

N,N-Dlmethyl(9-octadecenyl) amine 

»N,N-Dimethyloctadecylamine 

N,N-Dimethyl(soybean oil alkyl)amine 

N,N-Dimethyltetradecylamine 

N-Methy Ibis (coconut oil alkyl)amlne 

*N-Methylbis(hydrogenated tallow alkyl)amine 

N-Methylbls (mixed alkyl) amine 

N-Methyldioctadecylamine 

Tridodecylamine 



ARC, 


ASH, 


FOR. 




ARC. 








ARC. 








ARC. 








ARC, 


ASH, 


FOR. 




ARC, 


GNM. 






ACY, 


ARC. 






ARC. 








ARC, 


ENO. 






ARC, 


ASH, 


FOR. 




ARC, 


FOR. 






APD, 


ARC, 


FOR. 




ARC, 


FOR. 






ARC. 








ASH. 








RTF. 








NLC. 








NLC, 


PCS, 


RTF, 


UVC. 


ARC, 


ENO, 


FOR, 


GNM. 


ENO. 








FIN. 








SCO. 








CCW. 








ARC, 


FOR, 


GNM. 




ARC, 


ENO. 






ARC. 








GNM. 








ARC, 


ENO, 


FOR, 


GNM. 


ARC, 


ASH, 


ENO, 


FOR, GNM 


FOR. 








ENO. 








ARC, 


ASH, 


ENO, 


FOR, GNM 


ARC, 


ASH, 


ENO, 


FOR. 


ARC, 


ASH, 


ENO, 


FOR, GNM 


ARC, 


GNM. 






RH. 








ARC, 


ENO, 


FOR, 


GNM. 


ARC, 


ENO, 


FOR, 


GNM. 


ARC. 








RH. 








ARC, 


ENO. 






ARC, 


FOR, 


GNM. 




ARC, 


ASH, 


ENO, 


FOR, GNM 


GNM. 








ARC, 


FOR. 






ARC, 


FOR, 


GNM. 




ARC, 


BRD, 


ENO, 


PG. 


ARC, 


BRD, 


ENO. 




ARC, 


BRD. 






ARC. 








BRD, 


RH. 






ARC. 








ARC, 


BRD, 


ENO, 


PG. 


ARC. 








ARC, 


BRD, 


ENO. 




ENO, 


FOR, 


GNM. 




ARC, 


ENO, 


FOR, 


GNM. 


PG. 








FOR. 








GNM. 









SURFACE-ACTIVE AGENTS 



153 



TABLE 19B. -Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 




Manufacturers' identification 


codes 




(according to list in table 


22) 


Cat ionic Surface-Active >^gen(s - -Continued 








^Amines, not containing oxygen (and salts thereof) -- 








Continued 








»Secondary and tertiary monoamines — Continued 








-PTiTr^/l+lf-lQITlinii _ _•_ ^__^^^^^^^^^^^^^.. 


GNM. 






irioGtyxamine 


GNM. 






iris ^nyurogenatcQ T^axxow ainyi^amiiie 




»Oxygen-containing quaternary ammonium salts (except those 








having amide linkages ) : 








»Acyclic : 








(2-Aminoethyl)ethyl(hydrogenated tallow alkyl)(2- 


ARC. 






hydroxyethyl )ammonium ethyl sulfate. 








Bis(hydrogenated tallow alkyl)(2-hydroxyethyl, ethoxy- 


ARC. 






lated)methylammonium chloride. 








Bis ( 2-hydroxyethyl , ethoxylated ) methyl ( 9-octadecenyl) 


ARC. 






ammonium chloride . 








Bis (2-hydroxyethyl, ethoxylated )methyloctadecyl- 


ARC. 






ammoniiffli chloride. 








(Coconut oil alkyl)bis(2-hydroxyethyl, ethoxylated) 


ARC, 


VAC. 




methylararaonium chloride . 








(Coconut oil alkyl)( 2-hydroxyethyl, ethoxylated) 


ARC. 






methyl(mixed alkyl) ammonium chloride. 








(Coconut oil alkyl) (2-hydroxyethyl, ethoxylated)methyl 


ARC. 






(mixed alkyl)ammonium methyl sulfate. 








2-Hydroxytrimethylenebis [(coconut oil alkyl) 


CIB. 






diraethylammoniura chloride] . 








Triethyl(octadecyloxymethyl) ammonium chloride 


DAN. 






All other 


DUP, 


TCC. 




»Cyclic: 








Benzyl (coconut oil alkyl) bis (2-hydroxyethyl) ammonium 


CIB, 


NIC. 




chloride. 








Benzyl (coconut oil alkyl, ethoxylated )dimethylammonium 


GAF. 






chloride . 








1-Benzy 1-2-heptadecyl-l- (2-hydroxyethyl ) -2-imidazo- 


PCS, 


UVC. 




linium chloride. 








l-Benzyl-l-(2-hydroxyethyl)-2-nor(tall oil alkyl)-2- 


HDG, 


NLC. 




imidazolinium chloride. 








(Ethoxybenzyl)dimethyl(octylphenoxy) ammonium chloride — 


RH. 






(Ethoxybenzyl)dimethyl(octyltolyloxy) ammonium 


RH. 






chloride. 








l-Ethyl-2- ( 8-heptadecenyl ) -1- ( 2-hydroxyethyl) -2- 


APD, 


UVC. 




imidazolinium ethyl sulfate. 








N-Ethyl-N-hexadecylmorpholinium ethyl sulfate 


APD. 






N-Ethyl-N-octadecylmorpholinium ethyl sulfate 


OAF. 






N-Ethyl-N- (soybean oil alkyl)morpholinium ethyl 


APD. 






sulfate. 








2(8-Heptadecenyl)-l,l-bis (2-hydroxyethyl) -2-imidazo- 


GGY. 






linium chloride. 








(Tridecylbenzyl)diethyl(2-hydroxyethyl) ammonium 


SNW. 






chloride. 








wQuatemajTy ammonium salts having amide linkages : 








Benzy Ibis ( 2-hydroxyethyl )( 2'-stearamidomethoxyethyl ) 


ARC, 


CIB. 




ammonium chloride. 








2-Heptadecyl-l-methyl-l-(2-stearamidoethyl)-2-imidazo- 


ARC, 


CUL. 




linium methyl sulfate. 








(2-Hydroxyethyl)dlmethyl(3-stearamidopropyl) ammonium 


ACY. 






dihydrogen phosphate. 








( 2-Hydroxyethyl ) dime thyl( 3-stearamidopropyl) ammonium 


ACY. 






nitrate. 








(2-Hydroxyethyl) dimethyl (3-tallow acyl amidopropyl) 


CUL. 






ammonium chloride. 








(3-Lauramidopropyl)trlmethylammoni\mi methyl sulfate 


ACY. 






Trimethyl(3-oleamidopropyl)ammonium methyl sulfate 


CIB, 


LUR. 




All other 


DUP, 


NLC. 




*KJuatemary ammonium salts, not containing oxygen: 








»Acyclic: 








»Bis(coconut oil alkyl )dimethylammonium chloride 


ARC, 


END, FOR, GNM, VAC. 




Bls(coconut oil alkyl)dimethylammonium nitrate 


ARC. 






»Bis(hydrogenated tallow alkyl)dimethylammonium 


ARC, 


ASH, ENO, FOR, GNM, VAC. 




chloride. 








»( Coconut oil alkyl )trimethylammonium chloride 


ARC, 


FOR, GNM. 




(Cottonseed oil alkyl)trimethylammonium chloride 


FOR. 







154 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 19B Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer , i967--Continued 







Manufacturers' identification codes 


Chemical 




(according to list in table 22) 


Cationic Surface-Active , Agents --Continued 






^Quaternary ammonium salts, not containing oxygen — 






Continued 






^^Acyclic- -Continued 






Didodecyldimethylammonium bromide 


ONX. 




Dimethy Ibis (mixed alkyl)- and trimethyl(raixed alkyl) 


GNM. 




aiimonium chloride . 






Dlmethylbis(9-octadecenyl) ammonium chloride 


GNM. 




Dimethy Ibis (soybean oil alliyl) ammonium chloride 


ARC. 




Dimethyldioctadecylammonium chloride 


FOR, 


ONX, PG. 


Dimethyldioctadecylaramonium methyl sulfate 


ONX. 




Dodecyltrimethylammonium bromide 


DUP. 




Dodecyltrimethylammonium chloride 


ARC, 


FOR, GNM. 


Ethyldimethyl (mixed alkyl) ammonium ethyl sulfate 


JOR, 


TCC. 


Ethyldimethyl(9-octadecenyl) ammonium bromide 


ONX. 




Ethyldimethyl (soybean oil alkyl) ammonium bromide 


ARC. 




EthyUiexadecyldimethylaramonium bromide 


FIN. 




^^Hexadecyltrimethylammonium salts: 






Hexadecyltrimethylammoniura bromide 


DUP, 


FIN, ICI. 


Hexadecyltrimethylammoniimi chloride 


ARC, 


BRD. 


Hexadecyltrimethylammoniura p-toluenesulfonate 


FIN. 




(Hydrogenated tallow alkyl )trimethylammonium ohloride- 


ARC, 


FOR. 


Methyltrioctylammonium chloride 


GNM. 




Methyltris (mixed alkyl) ammonium chloride 


ASH, 


VAC. 


N,N,N',N',N'-Pentamethyl-N-(tallow alkyl )trimethyl- 


ARC, 


GNM, ORO. 


enebis [ammonium chloride] . 






Triethyloctadecylammonium ethyl sulfate 


AKS. 




TrimethyloctadecylanHiionium chloride 


ARC. 




Trimethyl(soybean oil alkyl)ammonium chloride 


ARC, 


VAC. 


Trimethyl(tallow alkyl) ammonium chloride 


ARC, 


FOR, GNM. 


Trimethyl( tallow alkyl) ammonium dimethyl phosphate 


CUL. 




All other - 


GNM, 


STC, VAC. 


*Benzenoid: 






»Benzyl( coconut oil alkyDdimethylammonium chloride 


ARC, 


CRT, DEP, LUR, RTF, TXT. 


»Benzyldimethyl(mixed alkyl) ammonium chloride 


AAC, 


BRD, CUL, FIN, ONX, PG, RH, TXT, VAC, WSN. 


Benzyldimethyloctadecylammonium chloride 


APX, 


CUL, FIN, ONX, WSN. 


Benzyldimethyl( tallow alkyl) ammonium chloride 


END. 




Benzyldiraethyltetradecylammonium chloride 


SNW, 


WSN. 


Benzy Idodecyldimethylammonium chloride 


FIN, 


ONX, SDH, WSN. 


Benzyhexadecyldimethylammonium chloride 


ONX, 


RH. 


BenzyH hydrogenated- tallow alkyl)dimethylammonlura 


ENO. 




chloride. 






Benzyl(mixed alkyl)pyridinium chloride 


RTF. 




1-Benzylpyridinium chloride 


DEP. 




Benzyltrimethylammonium chloride 


BRD, 


TCC. 


»(3,<i-Diohlorobenzyl)dodecyldimethylammonium chloride — 


CUL, 


ONX, VAC, WSN. 


(Dodecylbenzyl)dimethyloctadecylammonium chloride 


ARC. 




(Dodecylbenzyl)triethylammonium chloride 


PC. 




( Dodecylbenzyl ) trimethylammonium chloride 


CUL, 


NLC, VAC, WTC. 


2-Dodecylisoquinolini\im bromide 


CUL, 


ONX. 


(Dodecylraethylbenzyl) trimethylammonium chloride 


RH. 




1-Dodecylpyridinium chloride 


HK. 




(Ethylbenzyl)dimethyl(mixed alkyl )ammonium chloride 


ONX. 




JVonionic Surface-Active Agents 






»Carboxyllc acid amides: 






»Carboxylic acid - alkanolamine condensates: 






»Diethanolamine condensates (amine/acid ratio=2/l) : 






■^Canri c acid - 


GGY, 
BAC, 


PCS, SCP, UVC. 
PCS, VAL. 


Castor oil acids 


*Coconi_i't nil npidci------ -- 


AKS, AML, ARD, BSW, CIB, CLI, CTL, DA, DEP, EFH, GAF, 
HLI, HRT, JOR, KNP, LUR, MCP, MOA, ONX, PC, PCS, 


'\J\J^^\JIX\J. \J \J ^. A^ ^^j^l^^^i— -•i^^*— — — ^^^^i_^^*.™^ — ___,__^__^^^_ ^ 




PNX, PUR, RCD, SBC, SCP, SEY, SOP, SOS, STP, SWT, 




TXC, UNN, UVC, VAC, VND, WTC. 


Coconut oil and tall oil acids 


CSB. 




^Coconut oil and tallow acids 


CLI, 


CRT, GAF, PG. 


^Laurie acid—- - -.-——- „„ 


CLI, 
HLI. 


DA, DRW, HLI, MCP, MOA, ONX, PG, RCD, WON, WTC. 


Laurie and myristic acids 


Linoleic acid - ----._-_..- -_- - 


VND. 
HLI. 




Mixed vegetable oil acids 





SURFACE-ACTIVE AGENTS 



155 



TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer, iser'-Contlnued 



Chemioal 



Manufacturers' identification codes 
(according to list in table 22) 



Nonionic Surface-Active >^gen(s--Cont,iiiue(I 

»Carboxylic acid amides — Continued 

»Carboxylic acid - alkanolamine condensates — Continued 
»Diethanolamine condensates (amine/acid ratio=2/l) — 
Continued 

»01eic acid 

Palmitic acid 

Palmitic and stearic acids 

Pelargonic acid 

»Stearic acid 

Tallow acids 

»TaH oil acids 

Unspecified mixed fatty acids 

*Diethanolamine condensates (other amine/acid ratios): 
»Coconut oil acids (1/1) 

Coconut oil acids ^l.Vl) 

Hydrogenated tallow acids (.1/1) 

»Lauric acid (l/l) 

Laurie and rayristic acids (l/l) 

Myristic acid (l/l) 

Oleic acid (l/l) 

Palmitic and stearic acids (l/l) 

Pelargonic acid (l/l) 

»Stearic acid (l/l) 

Tall oil acids (l/l) 

Tallow acids (l/l) 

Unspecified mixed fat^y acids (l/l) 

*Ethanolamine condensates: 
Amine/acid ratio=2/l: 

Coconut oil acids 

Hydrogenated castor oil acids 

Hydrogenated tallow acids 

»L£nirio acid 

Laurie and rayristic acids 

Stearic acid 

Amine/acid ratio=l/l: 

Coconut oil acids 

Laurie and myristic acids 

Oleic acid 

Stearic acid 

Amine/acid ratio = 1/2; Stearic acid 

*Isopropanolamine condensates : 

Coconut oil acids 

»Lauric acid 

Laurie and n^ristic acids 

Oleic acid 

*Carboxylic acid - alkanolamine condensates, ethoxylated 
Coconut oil acids - ethanolamine condensate, ethoxy- 
lated. 
Hydrogenated tallow acids - ethanolamine condensate, 
ethoxylated. 

Oleic acid - ethanolamine condensate, ethoxylated 

Tallow oil acids - ethanolamine condensate, ethoxy- 
lated (amine/acid ratio=l/2). 
»Carboxylic acid esters: 
»Anhydrosorbitol esters: 

Anhydrosorbitol dioleate 

Anhydrosorbitol ester of mixed fatty acids 

»Anhydrosorbitol monoester of tall oil acids 

Anhydrosorbitol monolaurate 

^Anhydrosorbitol mono-oleate 

Anhydrosorbitol monopalmitate 

»Anhydrosorbitol monostearate 

Anhydrosorbitol sesquioleate 

Anhydrosorbitol tetrastearate 

Anhydrosorbitol triester of tall oil acids 



CCW, CLI, SCP, SOS, STP, VAC, WTC. 

CMG. 

MOP. 

EMR. 

AML, CLI, DA, EMR, JOR, ONX, SCO, SCP, TXC, VAL. 

MCP. 

EFH, MRA, WTC. 

ROB. 

APX, ARD, CCL, CLI, CTL, DA, DRW, EMK, GGY, HLI, MOA, 
MRV, ONX, PCS, PEK, ftCP, RCD, RTF, SBC, SCO, SEY, 
STP, TCC, TXT, VAC. 

JRG. 

DA. 

CTL, CUL, DRW, HLI, LEV, MOA, ONX, PCS, PC, SBC, STP, 
TXN, TXT, VAC. 

CLI, TXT, RTF. 

HDG. 

DA, GGY, PCS, SBC, SWT, TCC, TXT. 

GAF, MRA. 

PCS. 

EMR, GAF, GGY, GLY, PCS, RPC, SEY, SWT, UVC. 

MRV. 

RPC. 

STP. 



CTL, 


MOA, 


PCS, RTF, STP, VND, WTC 


BAC, 


GLY. 




GLY. 






AES, 


ARC, 


CTL, WTC. 


TXN. 






ARC, 


CLI. 




APX, 


DSO, 


PG, STP, UVC. 


TXT. 






VPC. 






MOA, 


VND. 




GLY, 


WTC. 




MOA, 


STP, 


TXT. 


CLI, 


MOA, 


PCS, WTC. 


LEV, 


TXT. 




WTC. 






STP. 






ARC, 


DA. 




ARC, 


GAF. 




NLC. 







APD. 

GLY. 

APD, GLY, HDG, RTF, TCH. 

APD, GLY, DRW, HDG, PCS, TCH. 

AAC, APD, ARC, DRW, EMR, GLY, HDG, PCS, TCH. 

APD, GLY, HDG, PCS. 

AAC, APD, ARC, DRW, GLY, HDG, PCS. 

AAC, GLY. 

APD. 

TCH. 



156 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 19B.- -Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer, 7567- -Continued 



Chemioal 



Manufacturers' identification codes 
(according to list in table 22) 



/Vonionic Surface-Act ive 4gen(s- -Continued 

»Carboxylic acid esters — Continued 
»Aiihydrosorbitol esters — Continued 

»Anhydrosorbitol trioleate 

*Anliydrosorbitol tristearate 

*Ethoxylated anhydrosorbitol esters: 

Ethoxylated anhydrosorbitol monoester of tall oil 
acids. 

»Ethoxylated anhydrosorbitol monolaurate 

»Ethoxylated anhydrosorbitol mono-oleate 

»Ethoxylated anhydrosorbitol monopalmitate 

»Ethoxylated anhydrosorbitol monostearate 

Ethoxylated anhydrosorbitol triester of castor oil 

acids. 
Ethoxylated anhydrosorbitol triester of tall oil 
acids. 

^Ethoxylated anhydrosorbitol trioleate 

*Ethoxylated anhydrosorbitol tristearate 

»Ethylene glycol and diethylene glycol esters: 

Diethylene glycol dioleate 

Diethylene glycol distearate 

Diethylene glycol monoester of coconut oil acids 

Diethylene glycol monoester of tallow acids 

»Dlethylene glycol monolaurate 

»Diethylene glycol mono-oleate 

Diethylene glycol monoricinoleate 

^Diethylene glycol monostearate 

Diethylene glycol sesquiester of tall oil acids 

Diethylene glycol sesqullaurate 

Diethylene glycol sesqulstearate 

Ethylene glycol distearate 

*Ethylene glycol monostearate 

Ethylene glycol sesqulstearate 

All other 

♦Glycerol esters: 

♦Complex glycerol esters: 

Glycerol diacetyltartrate monostearate 

Glycerol lactate palmitate 

Glycerol lactate stearate 

Glycerol maleate mono-oleate 

Glycerol monoester of mixed fatty acids, acetylated- 

Glycerol mono-oleate, acetylated 

Glycerol monostearate, succinylated 

♦Clycerol esters of chemically defined acids: 

Glycerol dioleate 

Glycerol distearate 

Glycerol monocaprate 

Glycerol monocaprylate 

♦Glycerol monolaurate 

♦Glycerol mono-oleate 

Glycerol monoricinoleate 

♦Glycerol monostearate 

♦Glycerol esters of mixed acids : 

Glycerol diester of lard acids 

Glycerol ester of tall oil acids 

Glycerol monoester of coconut oil acids 

Glycerol monoester of com oil acids 

Glycerol monoester of cottonseed oil acids 

Glycerol monoester of hydrogenated cottonseed oil 

acids. 
♦Glycerol monoester of hydrogenated soybean oil 

acids. 

Glycerol monoester of lard acids 

Glycerol monoester of peanut oil acids 

Glycerol monoester of tallow acids 

Glycerol sesquiester of castor oil acids 



APD, GLY, PCS, TCH. 
APD, DRW, GLY, HDG, PCS. 

RTF, TCH. 

AAC, APD, ARC, DRW, GLY, HDG, PCS, TCH. 

AAC, APD, ARC, DRW, GLD, GLY, HDG, PCS, TCH. 

AAC, APD, GLY, HDG, PCS, TCH. 

AAC, APD, ARC, DRW, GLY, HDG, PCS, TCH. 

APD. 

APD. 

AAC, APD, GLY, HDG, TCH. 

AAC, APD, DRW, GLY, HDG, PCS, TCH. 

GLY. 

ARC, GLY. 

EMR. 

DRW. 

CCW, DA, GLY, HAL, HDG, WTC. 

ARC, DA, HAL, WTC. 

GLY. 

AML, ARC, CCW, CLI, DA, HAL, HDG, PCS, QCP, SEY, UVC, 

VAL, VND, WTC. 
eCP, WTC. 
ARC, GLY. 
MCP, WM. 

ARC, EMR, HAL, HDG, HUM. 

ARC, CCW, CLI, EFH, GLY, HAL, HDG, KNP, PCS, VND, WM. 
WM. 
EMR. 



DRW, PCS. 
ARC, DRW, GLD. 
APD, GLD. 
DA, WTC. 
EK, EFH. 

X. 

EK. 

ARC, HAL. 

APX, ARC. 

ARC. 

ARC, DRW. 

ARC, GLY, HAL. 

APD, ARC, CCW, DRW, EFH, EK, EMR, GLY, HAL, HDG, PCS, 

SWT, WM. 
CCW, HDG. 
ARC, CCW, CHL, CRT, DA, DRW, EK, GLY, GRO, HAL, HDG, 

JRG, LUR, MRA, NW, PCS, PG, SOS, SWT, TCC, VND, WM, 

WTC, X. 



PCS. 




DRW, 


GLY, SWT, WM. 


GLD. 




DRW, 


EK. 


GLD, 


LEV, PCS. 


DRW, 


EK, GLD. 


EK, 


GLD, PCS. 


DRW. 




PCS. 




HDG. 





SURFACE-ACTIVE AGENTS 



157 



TABLE 19B. -Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



I^onionic Surface-Active 4gen(s- -Continued 

»Carboxylio acid esters —Continued 
«Glycerol esters--Continued 

^Glycerol esters of mixed acids — Continued 

Glycerol sesquiester of mixed fatty acids 

All other 

»Natural fats and oils, ethoxylated: 

»Castor oil, ethoxylated 

Hydrogenated castor oil, ethoxylated 

»Lanolin, ethoxylated 

Tallow, ethoxylated 

"Polyethylene glycol esters: 

"Polyethylene glycol esters of chemically defined 
acids: 

"Polyethylene glycol dilaurate 

"Polyethylene glycol dioleate 

"Polyethylene glycol distearate 

Polyethylene glycol methylcarbitol maleate 

"Polyethylene glycol monolaurate 

"Polyethylene glycol mono-oleate 

Polyethylene glycol monopalmitate 

Polyethylene glycol monopelargonate 

Polyethylene glycol monoricinoleate 

"Polyethylene glycol monostearate 

Polyethylene glycol pelargonate 

Polyethylene glycol sesquioleate 

"Polyethylene glycol esters of rosin and tall oil 
acids : 

Polyethylene glycol diester of tall oil acids 

Polyethylene glycol monoester of rosin acids 

Polyethylene glycol monoester of tall oil acids 

Polyethylene glycol sesquiester of rosin acids 

"Polyethylene glycol sesquiester of tall oil acids 

"Polyethylene glycol esters of other mixed acids : 

Polyethylene glycol diester of trimerized castor oil 

acids. 
Polyethylene glycol monoester of coconut oil acids — 
Polyethylene glycol monoester of soybean oil acids — 
Polyethylene glycol sesquiester of castor oil acids- 
"Polyethylene glycol sesquiester of coconut oil 
acids. 

Polyethylene glycol sesquiester of tallow acids 

"Polyglycerol esters: 

Polyglycerol lactate oleate 

Polyglycerol mono-oleate 

Polyglycerol monostearate 

"Propanediol esters: 

1,2-Propanediol distearate 

1,3-Propanediol monoester of coconut oil acids 

1,3-Propanediol monoester of tallow acids 

1,2-Propanediol monolaurate 

1,2-Propanediol mono-oleate 

Propanediol monopalmitate 

"1,2-Propanediol monostearate 

"Other carboxylic acid esters: 

Anhydrosorbitol glycerol monolaurate 

Ethoxylated glycerol sesquiester of mixed fatty acids- 

Ethoxylated 1,2-propanediol monostearate 

Ethoxylated sorbitol beeswax ester 

Ethoxylated sorbitol hexaester of tall oil acids 

Ethoxylated sorbitol hexaoleate 

Ethoxylated sorbitol lanolin ester 

Ethoxylated sorbitol mono-oleate 

Ethoxylated sorbitol monostearate 



APD. 
EK, LEV. 

APD, BAC, DA, DRW, EMR, GAF, GLY, ICI, NLC, PCS, RTF, 

TCH, TMH, Win. 
APD, GAF, TCH, VAC. 
APD, CRD, PCS. 
DRW. 



ARC, DA, DRW, EFH, GLY, HAL, HDG, JOR, PCS, UVC, WM. 
ARC, CLD, DA, EFH, GGY, GLY, HAL, HDG, NLC, PCS, SM, 

UVC. 
ARC, GLY, HAL, HDG, PCS, QCP. 
CCA. 
AAC, ARC, CCA, DA, GAF, GGY, GLY, HAL, HDG, JOR, KNP, 

PCS, SYC, TCH, TXT, UVC. 
ARC, CCA, CLD, CRT, DA, DRW, EMR, GAF, GGY, GLY, HAL, 

HDG, ICI, ONX, PCS, SM, SOS, SWT, SYC, TCH, UVC, VAC, 

VND, VPC, WM, WTC. 
APD. 

EMR, PCS. 

BAC, DA, HAL, TCH. 
AAC, AKS, AML, APD, AEC, CHP, CRT, DA, DEP, DEX, DRW, 

GAF, GGY, GLY, HAL, HDG, ICI, KNP, ONX, PC, PCS, PD, 

RH, SCP, SEY, TCC, TCH, UVC, VND, WTC. 
SCP. 
PCS. 



GLY. 
NLC. 
GLY, 
APD, 
AML, 

GLY. 

EMR, 
SYC. 
ARC, 
ARC, 



TMH, UVC. 
HPC, QCP. 
APD, APX, AHC, DA, DRW, MON, OMC, RTF, TCH, WTC. 



GLY. 



GGY, WTC. 

AHL, DA, DRW, MCP, ONX, PG, SCP, SOS, VAC, VND. 



ONX, SQS. 



DRW. 
HDG, 
PCS. 

HAL, 
DRW. 
PCS. 
ARC, 
HAL. 
ARC, 
APD, 

APD. 
APD. 
APD. 
APD. 
APD, 
APD, 
APD. 
APD, 
MCP, 



PCS, VND, WTC. 



PCS. 



HAL, SBC, WM. 



HDG. 



ARC, CCW, EK, GLD, GLY, HAL, JRG, PCS, PG. 



RTF, TCH. 
TCH. 

HAL. 
SNW. 



158 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer, i567--Continued 



Chemioal 



Mamif aoturers ' identification codes 
(according to list in table 22) 



!^onionic Surface-Active Agents --Continued 

»Carboxylic acid esters — Continued 

»Other carboxyiio acid esters— Continued 

Ethoxylated sorbitol oleate, acetylated 

Ethoxylated sorbitol pentaester of tall oil acids 

Ethoxylated sorbitol pentalaurate 

Ethoxylated sorbitol tetraester of laurio and oleic 
acids. 

Ethoxylated sorbitol tetraester of tall oil acids 

Methoxy polyethylene glycol mono-oleate 

Methylglucoside laurate 

Methylglucoside oleate 

Pentaerythritol distearate 

Poly^lkylene glycol diglycolate 

Sucrose esters of fatty acids 

All other 

*Ethers : 

*Benzenoid ethers: 

Alkylphenol - formaldehyde condensates, alkoxylated: 

p-tert-Butylphenol - formaldehyde, alkoxylated 

(Mixed alkyDphenol - formaldehyde, alkoxylated 

Nonylphenol - formaldehyde, alkoxylated 

tert-Octylphenol - formaldeliyde, ethoxylated 

p-tert-Butylphenol, ethoxylated 

Diisobutylphenol, ethoxylated 

Dinonylphenol, ethoxylated 

»Dodecylphenol, ethoxylated 

»Iso-octylphenol, ethoxylated, 

(Mixed alkyl)phenol, ethoxylated 

(Mixed alkyDphenol, ethoxylated, butyl ether 

(Mixed alkyl)phenoxypoly(ethyleneoxj-)ethyl chloride-- 
»Nonylphenol, ethoxylated 

Nonylphenol, ethoxylated and propoxylated 

Nonylphenoxypoly(ethyleneoxy) ethyl iodide 

»Phenol, ethoxylated 

Tetradecylphenol, ethoxylated 

Tridecylphenol, ethoxylated 

Xylenol, ethoxylated 

All other 

»Nonbenzenoid ethers: 

»Linear alcohols, alkoxylated: 

Coconut oil alcohol, ethoxylated 

»Decyl alcohol, ethoxylated 

Deoyloxypoly(ethyleneoxy )ethyl chloride 

Decyl and octyl alcohols, ethoxylated 

»Dodecyl alcohol, ethoxylated 

»Hexadecyl alcohol, ethoxylated 

»Mixed linear alcohols, ethoxylated 

»Mixed linear alcohols, ethoxylated and propoxylated. 
itg-Octadecenyl alcohol, ethoxylated 

»Octadecyl alcohol, ethoxylated 

Sperm oil alcohol, ethoxylated 

Tallow alcohol, ethoxylated 

Tridecyl alcohol, ethoxylated 

All other 

»Other ethers and thioethers: 

tert-Dodecyl mercaptan, ethoxylated 

Glucose, ethoxylated 

Glycerol, alkoxylated 

Mixed alcohols, ethoxylated 

Poly(mixed ethylene, propylene) glycol 

Polypropylene glycol, ethoxylated 

Propoxylated thiourea 

Rosin alcohol, ethoxylated 

Sorbitol, ethoxylated 

2,'i,7,9-Tetramethyl-5-decyne-'i,7-diol, ethoxylated- 
»Tridecyl alcohol, ethoxylated 



APD. 




APD, 


RTF. 


APD. 




APD. 




APD. 




NLC. 




HDG. 




HDG. 




GLY, 


VAL. 


NLC, 


RTF. 


SUG. 




CCW, 


STC, TCC, WM. 


RTF. 




NLC, 


RTF. 


NLC, 


RTF. 


SDW. 




RTF. 




GAF, 


RH. 


GAF, 


PCS, RTF, STP, TMH. 


GAF, 


MON, PCS, TMH, UCC. 


APX, 


DA, DRW, OMC. 


GAF. 




RH. 




GAF. 




APD, 


CIB, CLY, DOW, DRW, GAF, HDG, HPC, JCC, MON, NLC, 


CMC, PCS, RH, RTF, STP, TCH, TMH, UCC. 


RTF. 




GAF. 




APD, 


DA, GAF, JCC, TCH, UCC. 


ORO, 


WTC. 


PCS. 




NLC. 




RH. 





PCS. 

GAT, ICI, PCS. 

GAF. 

GAF. 

AAC, APD, DRW, DUP, GAF, HDG, JCC, OMC, UCC. 

ACS, APD, ASH, CIB, GLY, ICI. 

AAC, ASH, CO, GAF, HDG, JCC, MON, NLC, RH, RTF, SHC, 

STP, TCH, UCC, VAC. 
GAF, JCC, STP, WYN. 
AAC, APD, ASH, CIB, CRD, DA, DUP, GAF, GLY, ICI, TCH, 

VPC. 
APD, CIB, DUP, HDG, VAC. 
DUP. 

AAC, ASH. 
DUP. 
RH, VPC. 

AAC, MON, RTF, UCC. 

RH. 

NLC. 

DRW. 

NLC, UCC. 

NLC, PCS, RTF, WYN. 

VAC. 

CIB, HPC. 

TCH. 

cue. 

AAC, APD, DRW, EFH, GAF, GLY, ICI, JCC, MON, NLC, OMC, 
PCS, RTF, TCH, UCC. 



SURFACE-ACTIVE AGENTS 



159 



TABLE 19B. -Surface-active agents for which U.S. production or sales were reported, identified by 

manufacturer, i567--Continued 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



^anionic Surface-Active ,4gen(s --Continued 

»Ethers — Continued 

*Nonbenzenoid ethers--Continued 

»Other ethers and thioethers — Continued 

Tridecyl alcohol, propoxylated and ethoxylated 

Trimethylnonyl alcohol, ethoxylated 

Trimethylolpropane, alkoxylated 

Woolwax alcohols, ethoxylated 

All other 

lOther nonionic surface-active agents: 

Bis(octadecenyloxypolyethylene glycol)ester of 1,6- 
hexamethylenedicarbamic acid. 

3,5-Dimethyl-l-hexyn-3-ol 

3,5-Dimethyl-'i-octyne-3,5-diol 

Dodecylbenzenesulfonic acid - diethanolamine condensate, 

fatty acid monoester. 
Glycerol sesquiester of hydrogenated castor oil acids, 
borated and ethoxylated. 

Octyl phosphate, ethoxylated 

Polyethylene - vinyl alcohol condensate, potassium salt- 

2,'4,7,9-Tetramethyl-5-decyne-';,7-diol 

Tri(castor oil alkyl) phosphate 

Tris(nonylphenyl) phosphite 

All other 



JCC. 

UCC. 

JCC, RTF, WYN. 

CRD. 

SNW. 

CIB. 

cue. 
cue. 

MAH. 
GLY. 



SFA. 



DUP, 
NLC. 

cue. 

GLY. 
GAF. 
CCW, CMG, SNW. 



160 



SYNTHETIC ORGANIC CHEMICALS, 1967 



Pesticides and Related Products 



TABLE 2QB. --Pesticides and related products for which U.S. production or sales were reported, identified 

by manufacturer, 1967 

[ Pesticides and related products for which separate statistics are given in table 20A are marked below with an 
asterisk (»); products not so marked do not appear in table 20A because the reported date are accepted in confidence 
and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies 
that the manufacturer did not consent to his identification with the designated product] 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



PESTICIDES AND RELATED PRODUCTS, CYCLIC 

■^Fungicides: 

2,6-Bis(dimethylaminomethyl)oyclohexanone 

5-Chloro-2-benzothiazolethiol, laurylpyridium salt 

2,4.-Dichloro-5-(o-chloroanilino)-s-triazine 

l,4-Dlchloro-2,5-dimethoxybenzene 

2,3-Dichloro-l,4-naphthoquinone (Dichlone ) 

2,6-Diohloro-<i-nitroaniline (DCNA) 

*3, 5-Dimethyl-l, 3, 5, 2H-tetrahydrothiadiazine-2- 
thione (DMTT) 

Diphenylajranoniuin propionate 

2-Heptadecyl-2-imidazoline (Glyodin) 

2-Meroaptobenzothiazole, monoethanolamine salt 

^Mercury fungicides: 

N-(Ethylmerouri)-p-toluene sulfonanilide 

Hydroxymercurichlorophenol 

^ydroxymercurinitrophenol 

Mercurial turf fungicides 

Methylinercury quinolinolate-^ 

2-(Phenylmercurlajidno)ethyl acetate 

*Phenylmercuric acetate (FMA) 

Phenyljnercuric ammoniuiQ acetate 

Phenylraerouric hydroxide 

Phenylmercuric lactate 

Phenylmercurio naphthenate 

Phenylmercuric oleate 

Phenylmercuric propionate 

N-Phenylmercuriformamide 

Tris(2-hydroxyethyl)(phenylmerouri )ammonium lactate 

2-(l-Methyl-n-heptyl)-'i,6-dinitrophenyl crotonate 

(Dinooap) 
3-(2-Methylpiperidino)propyl-3,4.-dichlorobenzoate 
( Piperalin). 

*Naphthenic acid, copper salt 

Pentachloronitrobenzene (PCNB) 

»Pentachlorophenol ( PCP) 

Pentachlorophenol, sodium salt 

»8-Qainolinol (8-ftydroxyquinoline), copper salt 

Tetraohloro-p-benzoquinone (Chloranil ) 

2,3,4,6-Tetrachlorophenol and sodium salt 

N-Trichloromethylthio-'i-oyolohexene-l,2-dloarboxiiiu.de 
( Captan ) . 

N-Trichloromethylthiophthalimide (Folpet) 

*2,<i, 5-Trichlorophenol 

*2,4,5-Trichlorophenol, ethanolamine salt 

»2,4,5-Triohlorophenol, sodium salt 

2,4,6-Trichlorophenol 

^Herbicides and plant hormones: 

'i-Amino-3,5,6-triohloropicolinio acid (Picloram) 

5-Bromo-3-sec-butyl-6-methyluracil (Bromacil) 

3-tert-Butyl-5-ohloro-6-raethyluracil 

N-Butyl-N-ethyl-a, a, a-trif luoro-2, 6-dinitro-p-toluidine 
(Benefin). 

2-Butynyl-4-chloro-ra-ohlorocarbanilate ( Barban ) 

2-Chloro-4,6-bis(ethylaraino)-s-triazine (Simazine) 

2-Chloro-<4, 6-bis ( isopropylamino )-s-triazine ( Propazine ) — 
2-Chloro-4-ethylamlno-6-isopropylainino-s-triazine 
(Atrazine). 

2-Chloro-N-isopropyl acetanilide 

3'-Chloro-2-methyl-p-valerotoluidide (Solan) 

N'-(4-Chlorophenoxy )phenyl N, N-dimethylurea (Chloroxuron) 

3-(p-Chlorophenyl)-l,l-diraethylurea (Monuron) 

3-(p-Chlorophenyl)-l,l-dimethylurea trichloroacetate 



MRK. 

VNC. 

CHG. 

DUP. 

USR. 

CWN, UP J. 

MRK, OTC, SF, WRC. 

MRK. 
UCC. 
VNC. 



DUP. 
DUP. 
DUP. 
MAL. 
MRK. 
CLY. 
BKM, 
TRO. 
MRK. 
WRC. 
MRK. 
CLY, 
MRK. 
VIN. 
CLY. 
RH. 

LIL. 



CLY, MRK, TRO, TOC. 



HNX, MRK, TRO. 



CCA, FER, HNX, MCI, MLD, SHP, SRR, TGL, TRO, WTC. 

QMC, OTC. 

BXT, DOW, FRO, MON, RCI, SFD. 

DOW, MON, RCI. 

FIS, HNX, MRK. 

USR. 

DOW. 

CHO. 

CHO. 

DA, DOW, HK, HPC. 

GAF. 

DOW. 

DOW, RBC. 

DOW. 
DUP. 
DUP. 
LIL. 

GOC. 
GGY. 
GGY. 
GGY. 

MON. 
FMN. 

CBA, NES. 
DUP. 
ACN. 



PESTICIDES AND RELATED PRODUCTS 161 

TABLE 20B. --Pesticides and related products for which U.S. production or sales were reported, identified 

by manufacturer, i967--Continued 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



PESTICIDES AND RELATED PRODUCTS, CYCLIC— Continued 

*Herbicides and plant hormones — Continued 

3-Cyclohexyl-5,5-trimethyleneuraoil 

2,6-Di-tert-butyl-p-tolylmethyIcarbamate 

2,5-Diohloro-3-aminobenzoio acid, aumonium salt 

3,6-Dichloro-o-anisic acid (Dicamba) 

2,4-Dichlorobenzyltrlbutylphosphonium chloride 

2-(2,'i-Diohlorophenoxy )ethyl sulfate, sodium salt 
(Sesone). 

3-(3,'i-Diohlorophenyl)-l,l-dimethylurea (Diuron) 

3-(3,4--Diohlorophenyl)-l-methoxy-l-methylurea (Linuron) 
3-(3,'4-Dichlorophenyl )-l-methyl-l-n-butylurea (Neburon) 

2,4-Diohlorophenyl-i4-nitrophenyl ether 

3 ',4' -Dichloropropionanilide (Propanil) 

l,2-Dihydropyridazine-3,6-dione (Maleic hydrazide) (MH) 
N-(beta-0, 0-Diisopropyl-dithiophosphorylethyl)-benzene 
sulfonamide (Bensulide). 

N, N-Dimethyl-2, 2-diphenylacetainide (Diphenamide) 

1, l-Dimethyl-3-phenylurea ( Fenuron ) 

1, l-Dimethyl-3-phenylurea trichloroacetate 

Dimethyl tetrachloroterephthalate 

Dinitrobutylphenol (DNBP) 

»Dinitrobutylphenol, ammonium salt 

Dinitrobutylphenol, triethanolamine salt 

Dinitrocresol (DNOC) 

Dinitrocresol, sodium salt 

Diphenylaoetonitrile (Diphenatrile) 

2-Ethylamino-4-isopropylamino-6-methylmercapto-s- 

triazine (Ametryne). 
S-Ethyl hexahydro-lH-azepine-l-carbothioate (Molinate)- 

Gibberellic acid 

3-(Hexahydro-'i,7-methanoindan-5-yl)-l,l-diraethylurea 
(Norea). 

3-Indolebutyric acid 

Isopropyl N-phenylcarbamate (IPC) 

Isopropyl N-(3-chlorophenyl)carbaraate (CIPC) 

l-(2-Methyloyolohexyl)-3-phenylurea (Siduron) 

2-Methylmeroapto-'4,5-bis-(isopropylaralno)-s-triazine 
( Prometryne ) . 

4-(Methylsulfonyl )-2,6-dinitro-N, N-dipropylaniline 

1-Naphthaleneacetic acid and derivatives: 

1-Naphthaleneacetamide 

«l-Naphthaleneacetio acid (NAA) 

»l-Naphthaleneaoetic acid, methyl ester 

*1-Naphthaleneacetic acid, sodium salt 

N-1-Naphthylphthalamic acid (NPA) 

7-Q>cabicyclo[2.2.l]heptane-2,3-dioarboxylic acid, 

disodium salt (Endothall). 
Phenoxyacetic acid derivatives; 

'♦-Chloro-2-methylphenoxyacetic acid (MCPA) 

4-Chloro-2-methylphenoxyacetio acid, potassium salt-- 

»2,4-Dichlorophenoxyaoetic acid (2,4-D) 

«2,4-Diohlorophenoxyacetic acid esters and salts: 

2,4-Dichlorophenoxyacetic acid, 2-butoxyethyl ester 
2,4- Dichlorophenoxyacetic acid, butoxypoly- 
propyleneglycol ester. 

■»2,4-Dichlorophenoxyacetic acid, n-butyl ester 

2,4-Dichlorophenoxyacetic acid, sec-butyl ester 

2,4-Diohlorophenoxyaoetic acid, dimethylamine salt- 
2,4-Dichlorophenoxyacetio acid, ethanolamine and 
isopropanolamine salt. 

2,4-Dichlorophenoxyacetic acid, ethyl ester 

2,4-Dichlorophenoxyacetic acid, 2-ethylhexyl ester- 

»2,4-Dichlorophenoxyacetic acid, iso-octyl ester 

•2,4-Dichlorophenoxyacetio acid, isopropyl ester 

2,4-Dichlorophenoxyaoetic acid, lithium salt 

»2,4,5-Trichlorophenoxyacetic acid (2,4, 5-T) 

»2,4, 5-Trichlorophenoxyacetic acid esters and salts: 

2,4,5-Triohlorophenoxyacetic acid, an^rl esters 

2,4,5-Trlohlorophenoxyaoetic acid, 2-butoxyethyl 

ester 
2,4,5-Trichlorophenoxyyacetio acid, butoxypoljrpropy 
leneglycol ester. 
»2,4,5-Trichlorophenoxyaoetic acid, n-butyl ester 



DUP. 






HPC. 






AMC, 


GAF. 




VEL. 






SM. 






GAF. 






DUP. 






DUP. 






DUP. 






RH. 






CIS, 


MON, RH. 




ACY, 


USR. 




SF. 






AHA, 


CWN, UP J. 




DUP. 






ACN. 






DA. 






CIS, 


DOW, FWN. 




CIS, 


DOW, FMN. 




CIS, 


DOW, FMN. 




CIS, 


MN. 




CIS, 


FMN. 




LIL. 






GGY. 






SF. 






ABB, 


MHK. 




HPC. 






ARA. 






PPG. 






PPG. 






DUP. 






GGY. 






SHC. 






AMC. 






AMC, 


COK, THM. 




AMC. 






AMC, 


BKL. 




USR. 






PAS. 






CHC, 


CLY, RIV. 




GTH. 






CHC, 


DA, DOW, HPC, MON, THM 


AMC. 






DOW. 







AMC, CHC, DA, DOW, HPC, MON, PBI, RIV. 

CHC, DOW, MON. 

ALC, AMC, CHC, DA, DOW, HPC, PBI, RIV, TVR. 

DOW. 

AMC. 

DA, HPC. 

CHC, DOW, MON, PBI, RIV. 

AMC, CHC, DA, DOW, HPC, MON. 

GTH, RIV. 

DA, DOW, HPC, MON, THM. 

HPC. 
AMC. 

DOW. 

DA, DOW, HPC, MON, PBI, RIV. 



162 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 20B. --Pesticides and related products for which U.S. production or sales were reported, identified 

by manufacturer, 1967 — Continued 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



PESTICIDES AND RELATED PRODUCTS, CYCLIC--Continued 

*Herbicldes and plant hormones — Continued 
Phenoxyacetio acid derivatives — Continued 
»2,'i,5-Trichlorophenoxyacetic acid esters and salts — 
Continued 
2,'4,5-Trichlorophenoxyacetic acid, 2-ethylhexyl 
ester. 
»2,'ij5-Trichlorophenoxyaoetic acid, iso-ootyl ester — 
2,4,5-Trichlorophenoxyacetio acid, triethylamlne 
salt. 
Polyohloro-tetrahydro-methanoindene ( Polychlorodioyclo- 
pentadiene) isomers, 

N-ra-Tolyl phthalamic acid 

2-(2,^,5-Trichlorophenoxy)propionic acid (Silvex) 

2-(2,'i,5-Trichlorophenoxy )propionio acid, 2-ethylhexyl 

ester. 
2-(2,4,5-Trichlorophenoxy)propionio acid, triethanol- 

amine salt). 
a,a,a-Trifluoro-2,6-dinitro-N, N-dipropyl-p-toluidine 

(Trifluralin). 
3- (m-Irif luoromethylphenyl )-l, 1- dime thy lurea 

( Fluometuron ) . 
Tris(2, <i-dichlorophenoxyethyl ) phosophite (2, '♦-DEP) — 
Insect attraotants and repellants: 

tert-Butyl •iCor 5)-chloro-2-methyloyclohexanecarboxylate 
(Trimedlure). 

N, N-Diethyltoluamide (DEET) 

Di-n-propyl isocinchomeronate 

^Insecticides: 

Allethrin (allyl homolog of Cinerin I) 

3-sec-Ajiylphenyl-N-methylcarbamate 

Benzyl thiocyanate 

2-seo-Butyl-4, 6-dinitrophenyl-3, 3-dimethylacrylate 

( Binapaoryl ) . 
Chlorinated insecticides: 
*Aldrin-toxaphene group : 

Heptachloro-tetrahydro-endo-raethanoindene 

( Heptachlor ) . 
Hexachloro-epoxy-ootahydro-endo-endo-dimethano- 

naphthalene ( Qidrin ) . 
Hexachloro-epoxy-octahydro-endo-exo-dimethano- 

naphthalene (Dieldrin). 
Hexachloro-hexahydro-endo-exo-dimethanonaphthalene 
(Aldrin). 

Octachloro-hexahydro-methanoindene (Chlordan) 

Terpene polychlorinates 

Toxaphene (Chlorinated caniphene) 

2,2-Bis(p-chlorophenyl)-l,l-dichloroethane (DDD) (TDE) 

1, l-Bis(p-ohlorophenyl)-2-nitrobutane 

1, l-Bis(p-chloroph6nyl)-2-nitropropane 

*<x-Bis(p-chlorophenyl )p, p,fi-triohloroethane (DDT) 

2-(p-tert-Butylphenoxy )isopropyl-2' -chloroethyl 
sulfite. 

Chlorobenzilate 

p-Chlorophenyl p-chlorobenzenesulfonate (Ovex) 

o-Chlorophenyl-N-methylcarbamate 

p- Chlorophenyl 2,4,5-trichlorophenyl sulfone 
(Tetradifon). 

6-Chloro-3,4-xylyl, methyloarbamate 

Decachlorooctahydro-l,3,4-metheno-2H-cyclobuta[cd]pen- 
talen-2-one. 

l,l-Dichloro-2,2-bis(p-ethylphenyl)ethane 

■4,4'-Dichloro-a-trichloromethylbenzhydrol (Dicofol) 

Dodecachlorooctahydro-l,3,4-metheno-2H-oyclobuta[cd] 
pentalene (Mirex). 

»Hexaohlorooyclohexane (Benzene hexachloride) (BHC) 

Hexachlorocyolohexane, 100^ Y-isomer (Lindane) 

Hexachloro-hexahydro-methano-benzodioxathiepin 

3-oxide (Endosulfan). 
1, 1, l-Trlohloro-2, 2-bis (p-methoxyphenyl )ethane 
(Methoxychlor ) . 

Isobornyl thiocyanoacetate 

N-(Fhenyl-2-nitropropyl )piperidine 

1-Naphthyl N-methylcarbamate (Carbaryl) 



DA, HPC. 

DA, DOW, MON, FBI, RIV, TMH. 
DOW, HPC. 

VEL. 

USR. 

DOW, HPC, RIV. 

HPC. 

BKL. 

LIL. 

CBA 

USR. 

UOP. 

HPC, PFZ. 
MGK. 

BPC. 
x. 

HK. 
FMN. 



VEL. 

VEL. 

SHC. 

SHC. 

VEL. 

HN. 

HPC, 

ACN, 

CCM. 

cm. 

ACN, 
USR. 



GGY. 

AMP, 
OTC. 

mm, 

UPJ. 
ACN. 

RH. 
RH. 
ACN. 

DA, 
HK. 
HK. 

CHE, 

CIS, 

MRK. 
UCC. 



SFD. 

RH. 



DA, LEB, MTO, CMC. 

DOW. 
FMP. 



HK, PPG. 

DUP. 
HPC. 



PESTICIDES AND RELATED PRODUCTS 



163 



TABLE 20B. --Pesticides and related products for which U.S. production or sales were reported, identified 

by manufacturer, i 967— Continued 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



PESTICIDES AND RELATED PRODUCTS, CYCLIC— Continued 

»Inseotioides — Continued 

«Qrganophosphorus insectidides : 

'4-tert-Butyl-2-chlorophenyl methyl methylphosphor- 

amldite. 
S-[[ (p-Chlorophenyl)thio] metliyl] 0,0-diethyl phos- 

phorodithioate ( Carbophenothion ) . 
2-Chloro-l- (2,4., 5-triohlorophenyl) vinyl dimethyl 

phosphate. 
0, 0-Diethyl 0-3-chloro-4-methyl-l-oxo-2H-l-benzopyran- 

7-yl phosphorothioate ( Coujnaphos ) . 
Diethyl l-(2,4-dichlorophenyl)-2-ohlorovinyl 

phosphate. 
0, 0-Diethyl-l- (2, 5-dichlorophenyl ) 0-2-chlorovinyl 

phosphate. 
0, 0-Diethyl 0-(2-isopropyl-4-methyl-6-pyriJin.dinyl) 

phosphorothioate (Diazinon). 
0, 0-Diethyl 0-p-(methylsulfinyl)phenyl phos- 
phorothioate. 
*0, 0-Diethyl O-p-nitrophenyl phosphorothioate 
(Parathion). 
0, 0-Dimethyl 0- [4- (methyl thio)-m-tolyl] phosphoro- 
thioate (Fenthion). 
*0, 0-Dimethyl O-p-nitrophenyl phosphorothioate (Methyl 
parathion ) . 
0, 0-Dimethyl S- [4-0x0- 1,2, 3-benzotriazin-3(4H)- 

ylmethyl] phosphorodithloate. 
0, 0-Dimethyl S-phthalimidomethyl phosphorodithloate — 
Dimethyl 2,4, 5-triohlorophenyl phosphorothionate 

(Ronnel). 
2,3-p-Dioxane S, S-bis(0, 0-diethylphosphorodithioate) 

(Dioxathion). 
0- Ethyl O-p-nitrophenyl phenylphosphonothioate (EPN). 
a-Methylbenzyl 3-(dimethoxyphosphinyloxy)-cis-croto- 

nate. 
0, 0, 0', O'-Tetramethyl 0, O'-thiodi-p-phenylene 
phosphorodithloate. 

Lampricide: 3-Trifluoromethyl-4-nitrophenol 

Nematooides: 

0,0-Diethyl 0-(2,4-dichlorophenyl) phosphorothioate 

0, 0-Diethyl 0-2-pyrazinyl phosphorothioate (Thionazin)- 
»Rodentlcides: 

3-(a-Acetonylbenzyl )-4-hydroxycoumarin (Warfarin) 

2-Diphenylacetyl-l-3-indandione (Diphacinone) 

2-Diphenylacetyl-l-3-indandione, sodium salt 

3-(l-Furyl-3-acetylethyl)-4-hydroxycoumarin 
( Coumaf uryl ) . 

2-Pivaloyl-l,3-indandione (Pindone) 

^mergists and adjuvants: 

a-[2-(2-n-Batoxyethoxy )-ethoxy] -4,5-methylene-dioxy-2- 
propyltoluene (Piperonyl butoxide). 

N, N-Di-n-butyl-p-chlorobenzenesulfonamide 

N-(2-Ethylhexyl)bicyclo(2.2.1)-5-heptene-2,3- 

dicarboximide. 
l,2-Methylenedioxy-4-[2-(octylsulfinyl )propyl] -benzene 

(Sulfoxide). 
Piperonal bis [2-(2-butoxyethoxy)ethyl] acetal 

PESTICIDES AND RELATED PRODUCTS, ACYCLIC 

♦Fungicides : 

Bis-l,4-bromoacetoxy-2-butene 

Cadmium succinate 

l-Chloro-2-nitropropane (Korax) 

Disodium cyanodithioimidocarbonate 

Dithiocarbamic acid fungicides: 

»Dimethyldithiocarbamic acid, ferric salt (Ferbam) 

Dimethyldithiocarbamic acid, manganese salt 

Ethylene bis (dithiocarbamic acid), diammoniura salt 

♦Ethylene bis (dithiocarbamic acid), disodium salt 
(Nabam). 
Ethylene bis(dithiocarbamic acid), manganese salt 
(Maneb). 



DOW. 

SF. 

SHC. 

CHG. 

SHC. 

SHC. 

GGY. 

CHG. 

AMP, MON, SF, SHC. 

CHG. 

AMP, MON, SF, SHC, VEL. 

CHG. 

SF. 
DOW. 

HPC. 

SF. 
SHC. 

ACY. 

MEE. 

SM. 
ACY. 

CIS, 

NES. 
NES. 
AMC. 

MOT, 

FMN, 

NES. 
MGK. 

PEN. 

MGK. 



MOT, PEN. 



PIC. 

FMP. 



VIN. 








MAL. 








FMN. 








BKM. 








DUP, 


FMN, 


VNC, 


WRC. 


FMN. 








CIS, 


RBC. 






CIS, 


DUP, 


FMN, 


RH. 


CIS, 


DUP, 


RH. 





164 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 20B. --Pesticides and related products for which U.S. production or sales were reported, identified 

by manufacturer, 1967 — Continued 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



PESTICIDES AND RELATED PRODUCTS, ACYCLIC— Continued 

»Fungicides — Continued 

Dithiocarbamio acid fungicides — Continued 
^Ethylene bis(dithiooarbamic acid), zinc salt 
tZineb) . 

Polyethylenethiuram disulfide (PETD) 

Other dithiocarbamic acid fungicides 

n-Dodecylguanidine acetate (Dodine) 

Mercury fungicides: 

Chloromethoxypropylmercuric acetate 

3-Methyl (mercurithio)-l,2-propanediol 

Methylmercuric hydroxide 

Methylmercury nitrile 

All other acyclic fungicides: 

Dimethyl thiocarbonyl disulfide 

2-Propene-l,l-diol diacetate 

^Herbicides and plant hormones: 

Cacodylic acid 

2-Chloroallyl diethyldithiocarbamate (CDEC) 

2-Chloro-N,N-diallylacetamide (CDAA) 

2,3-Dichloroallyl diisopropylthiolcarbamate 

(Diallate). 

2,2-Dichloropropionic acid, sodium salt (Dalapon) 

N-Dimethylaminosuccinamlc acid 

S-Ethyl di-N,N-propylthiocarbamate (EPTC) 

Ethyl xanthogen disulfide 

Methanearsonic acid, disodium salt (DSMA) 

Methanearsonic acid, dodecyl- and octylammonium 

salts. 

Methanearsonic acid, sodium salt (MSMA) 

S-Propyl butylethylthiocarbamate (Pebulate) 

S-Propyl dipropylthiocarbamate (Vernolate) 

S,S,S-Tributyl phosphorotrithioate 

Tributyl phosphorotrithioite 

Trichloroacetic acid, sodium salt (TCA) 

S-2 , 3 , 3-TrichloroaHyl N , N-diisopropylthiol 
carbamate (Tri-allate). 

Other acyclic herbicides 

^Insecticides: 

2-(2-Butoxyethoxy)ethyl thiocyanate 

Metaldehyde 

*Organophosphorus insecticides: 

S-[1,2-Bis (ethoxyoarbonyl) ethyl] 0,0-dijiiethyl 

phosphorodithioate (Malathion) . 
2-Carbomethoxy-l-propen-2-yl dimethyl phosphate--- 
l,2-Dibromo-2,2-dichloroethyl dimethyl phosphate 

(Naled) 
0,0-Diethyl S-2-(ethylthio)ethyl phosophorodi- 

thioate (Disulfoton) . 
0,0-Diethyl 0-2-(ethylthio)ethyl phosphorothioate 

(Demeton 0). 
0,0-Diethyl S-2-(ethylthio)ethyl phosphorothioate 

(Demeton S). 
0,0-Diethyl S-(ethylthio)methyl phosphorodithioate 

(Phorate). 
3-(Dimethoxyphosphinyloxy)-N,N-dimethyl-cis- 

crotonamide. 
0,0-Dimethyl 0-2,2-dichlorovinyl phosphate 

(DDVP). 
, O-Dimethyl S- ( N-methy Icarbamoylmethy 1 ) 

phosphorodithioate (Dimethoate) , 
Dimethyl phosphate of 3-hydroxy-N-methyl-cis- 

orotonamide . 
S-[2-(Ethylsulfinyl)ethyl] 0,0-dimethyl phos- 
phorothioate ( Oxydemetonmethyl ) . 
0,0,0',0'-Tetraethyl S,S' -methylene bis-phos- 
phorodithioate (Ethion). 

Tetraethyl pyrophosphate (TEPP) 

Tetra-n-propyl dithiopyrophosphate 

2-lThiooyanoethyl dodeoanoate — 

Other acyclic insecticides 



CIS, DUP, IMN, RH, WOD. 

FMN. 
VNC. 
ACY. 

TRO. 
DUP. 

MRT. 
WRC. 

CLY. 
SHC. 

ASL, VIN. 

MON. 

MON. 

MON. 

DOW. 

USR. 

SF. 

RBC. 

ASL, CLY. 

CLY, VIN. 

VIN. 

SF. 

SF. 

CHG. 

SM. 

DOW. 

MON. 

ACN. 

RH. 
COM. 

ACY, CIS. 

SHC. 
SHC. 

CHG. 

CHG. 

CHG. 

ACY. 

SHC. 

SHC. 

ACY. 

SHC. 

CHG. 

FMN, FMP. 

ALC, OTH. 
SF. 
RH. 
BFG. 



PESTICIDES AND RELATED PRODUCTS 



165 



TABLE 20B. 



-Pesticides and related products for which U.S. production or sales were reported, identified 
by manufacturer, 1967— Continued 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



PESTICIDES AND RELATED PRODUCTS, ACYCLIC— Continued 

»Rodentioides : Sodium fluoraoetate 

"Soil conditioners: Polyacrylonltrile, hydrol;yzed, sodium 

salt. 
»Soil fumigants: 

2-Aminobutane carbonate 

»l,2-Dibroiiio-3-chloropropane (DBCP) 

1,3-Dichloropropene 

1,3-Dichloropropene, 1, 2-dichloropropane 

•Methyl bromide ( Bromomethane) 

N-Methyldlthlocarbamic acid, sodium salt (Metham) 

Trichloronitromethane ( Chloropiorin) 

All other soil fumigants 



RBC. 






ACY. 






LIL. 






AMP, 


BST, 


DOW, SHC 


DOW. 






DOW, 


SHC. 




AMP, 


DOW, 


GIL, MCH 


CHF, 


DUP, 


RH, SF. 


DOW, 


IMC. 




SF. 







166 



SYNTHETIC ORGANIC CHEMICALS, 1967 



Miscellaneous Chemicals 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1967 

[Miscellaneous chemicals for which separate statistics are given in table 21A are marked with an asterisk (»); 

chemicals not so marked do not appear in table 21A because the reported data are accepted in confidence and may not 
be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Chemical 



Manufacturers' identification codes 
(according to list In table 22) 



MISCELLANEOUS CHMICAIS, CYCLIC 

6-Acetoxy-2,i-dimethyl-m-dioxane 

Adamantane and carboxylio acid 

Adenosine phosphates 

2-Arainobenzothiazole 

2-Amino-4,6-dimercapto-l,3,5-triazine 

l-(2-Aniinoethyl)piperazine 

l-(3-Aminopropyl)morpholine 

Anlsaldehyde bisulfite 

Arylalkyl phosphites 

Barium ootylphenate 

Benzoic acid salts : 

Ammonium benzoate 

»Sodium benzoate 

p-Benzoquinone (p-Quinone) 

Benzothiazole 

«Benzoyl peroxide 

Benzyltrimethylararaoniujn chloride 

Biological stains 

Bis(2,'i-dichlorobenzoyl) peroxide 

2,4-Bls(<i-hydroxy-3,5-di-tert-butyl-phenoxy)-6-(n- 

ootylthio)-l,3,5-triazine. 
2,A-Bis(n-octylthio)-6-(4'-hydroxy-3',5'-di-tert- 

butylanilino)-l,3,5-triazine. 
Boron fluoride-phenol complex 

»Butyl benzoate 

p-tert-Butylbenzoic acid, barium bis-salt 

2 (and 3)-tert-Butyl-<i-methoxyphenol 

p-tert-Butyl-;*-methyloinnamaldehyde 

tert-Butyl peroxybenzoate 

4--tert-Butylphenyl salicylate 

M-tert-Butylpyrooatechol 

Camphene 

Catecholsulfonic acid, sodium salt 

Centralite-1 (N, N'-Diethyl-N, N'-dlphenylurea) 

Chemical indicators 

Chemical reagents 

Chloramine B (Sodium derivative of N-ohlorobenzene- 

suLf onamide ) . 
l-(3-Chloroallyl)-3,5,7-triaza-l-azon iaadamantane 
chloride. 

o-Chlorobenzaraalononitrile 

5-Chloro-a, n-bis (3, 5-diohloro-2-hydroxyphenyl )-o- 
toluenesulf onic acid 

5-Chloro-2-hydroxybenzophenone 

Chlorophyllin, sodium-potassium-oopper 

Cobalt phthalocyaninedisulfonic acid 

Cumene hydroperoxide 

Cyanuric acid 

l,3-(and 1,4-- )Cyclohexadiene 

»Cyclohexanone peroxide 

cirolohexene-l,2-dicarboxylic acid (Tetrahydrophthalic 
acid) disubstituted, polyester salts: Barium and 
cadmium salts. 

Cyolohexenone and cyclopentanone 

1,4-Cyclohexylenedimethanol 

Cyclopropane 

Cytidine and derivatives 

Decahydronaphthalene (Decalin) 

Decyl diphenyl phosphite 

Dehydroacetic acid, and sodium salt 

Dlamlnohexanitrobiphenyl 

Diaminotrinitrobenzene 



GIV. 

ALD. 

PLB. 

FMT. 

ACY. 

JCC. 

JCC. 

GIV, SHL. 

WES. 

CCA. 

FIS. 

HK, HN, MON, PFZ, VEL. 

EKT. 

ACY. 

ARC, AZT, BKL, CAD, NOC, RCI, SDH, UPR, WTL. 

COM. 

ACS, EK. 

CAD, WTL. 

GGY. 

GGY. 



ACS. 










FRO, 


TCC, 


VEL. 






CCA. 










EKT. 










GIV. 










AZT, 


WTL. 








DOW. 










BKL, 


CTA, 


DOW. 






GLD, 


HPC. 








ICO. 










ACS, 


OTC, 


PAS. 






ACS, 


EK, 


LAM. 






ACS, 


CLB, 


EK, GFS, 


LAM, 


PIC 


NES. 











DOW. 

NCA. 
TRO. 

DOW. 
KCH. 
ACS. 
HPC, RCI. 

ram. 

ALD. 

AZT, CAD, NOC, WTL. 

RCI. 



ALD. 

EKT. 

OH, CMS, TAE. 

PLB. 

DUP. 

HK, X. 

GAN. 

NCA. 

NCA. 



MISCELLANEOUS CHEMICALS 



167 



TABLE 21B. —Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i9()7--Continued 



Chemical 



MISCELLANEOUS CHiMICAIS, CYCUC— Continued 

2j 5-Di-tert-ajiylhydroquinone 

l,5-Diazabioyclo(4.3.0.)-5-non-5-ene 

l,4-DiazabioyoloC2.2.2)ootane 

Diazodinitrophenol 

2,'i-Dibenzoylresorcinol 

2,6-Di-tert-butyl-p-cresol: 

»Food grade 

»Teoh 

2, 5-Di-tert-butylhydroquinone 

Di-tert-butyl peroxyphthalate 

l,3-Dichloro-5,5-dlraethylhydantoin 

Dichloro-s-triazine-2, 4, 6( IH, 3H, 5H)trione ( Dichloro- 
isocyanuric acid), potassium and sodium salts. 

'4,"i'-Diohloro-3-trifluoroinethylcarbonalide 

Dicyclohexylamnioniujii nitrite 

Didecyl phenyl phosphite 

Digitonin 

2,4-Dihydroxybenzophenone 

2,2'-Dihydroxy-4,4'-dimethoxybenzophenone 

2,6-Dihydroxyisonicotinic acid (2,5-Dihydroxy-4-oarboxy- 
pyridine). 

2,2'-Dihydroxy-'i-methoxybenzophenone 

2,2'-Dihydroxy-<i-(octadeoyloxy )benzophenone 

3, 5-Diiodosalicylic acid 

Diisopropylbenzene hydroperoxide 

Diisopropyl-m, p-cresols 

i'p-Dimethoxybenzene (Dimethyl ether of hydroquinone ) 

5, 6-Dimethylbenzinddazole 

2,5-Dimethyl-2,5-di(benzoylperoxy )hexane 

2, 6-Dimethyliiiorpholine 

4,4^-Dinitrocarbanilide-4, 6-dimethyl-2-pyrinu.dinol 

Di-n-octadecyl 3,5-di-tert-butyl-4-hydroxyphenyl phos- 
phonate . 

Dioxane (l^'i-Diethylene oxide) 

Dipropylene glycol salicylate 

Dithioamrailide, monoethanolamine salt 

'i-{Dodeoyloxy)-2-hydroxybenzophenone 

Bizymes : 
f^drolytic : 

An^ylases 

Proteases 

Other 

Nonhydrolytic 

l,2-^oxy-3-phenoxypropane (Glycidyl phenyl ether) 

Ethyl cellulose phthalate 

Ethylenedianiinedi(o-hydroxyphenylaoetic acid), ferric, 
sodium salt. 

2-Ethylethyleneimine 

4-Ethylmorpholine 

^Flotation reagents : 

Dioresylphosphorodithioio acid (Dicresylthiophcsphoric 
acid ) . 

Dicresylphosphorodithioic acid, ammonium salt 

Dicresylphosphorodithioio acid, sodium salt 

2,2'-Dimethylthiocarbanilide (Di-o-tolyl thiourea) 

Rosin amines 

Thiocarbanilide (Diphenylthiourea) 

Fluorinated benzenoid chemicals 

Furan derivatives : 

2-Furaldehyde (Furfural) 

Tetrahydrofurfuryl alcohol 

Gallic acid 

•Gasoline additives: 

N, N'-Bis(l,'i-dimethylpentyl)-p-phenylenedianiine 

2,6-Di-tert-butylphenol 

N, N-Di-sec-butyl-o-phenylenediamine 

*N, N'-Di-sec-butyl-p-phenylenediaraine 

N, N'-Diisopropyl-p-phenylenediamine 

*N, N'-Disalicylidene-l,2-propanediamine 



Manufacturers' identification codes 
(according to list in table 22) 



EKT. 
ALD. 
HOU. 
HPC. 

DOW. 

ASH, EKT, HPC, KPT, PRD, SHC. 

ASH, EKT, HPC, KPT, PRD, SHC. 

EKT. 

WTL. 

GLY. 

FMB, WON. 

GGY. 

CMC. 

HK. 

PEN. 

DUP. 

GAF. 

EK. 

ACY. 
ACY. 

MRT. 

HPC. 

GIV. 

ASL, EKT, GAF, ICO, UOP. 

ALD. 

iVTL. 

DOW. 

MRK. 

GGY. 

DOW, UCC. 
HAL. 
ACY. 
DUP, EKT. 



BAX, CRN, MLS, CMS, MP, RH, SBI, '«/BC. 

BAX, MLS, PFZ, ™p, RH, WBC. 

l^LS, RH, WBC. 

MLS, PLB, WBC. 

SHC. 

EK. 

GGY. 

ICO. 
BRD, JCC. 

ACY. 

ACY. 
KCU. 

DUP, RBC. 
HPC. 

ACS, ACY. 
PIC. 

QKO. 
QKO. 
MAL. 

EKT. 
SHC, TNA. 

X. 

DUP, EKT, U™. 

DUP, X. 

DUP, EKT, SM, TX, Uffl. 



168 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAI^, CYCLIC- -Continued 

^Gasoline additives — Continued 

Methylcyclopentadienylmanganese tricarbonyl 

4,^ '-Methylenebis(2,6-di-tert-butylphenol ) 

2,2 '-Thiobis[6-tert-butyl-4-methylphenol] 

Other 

Glyceryl p-ajrdnobenzoate 

Glyceryl tribenzoate 

Guanos ine phosphates 

*Hexajnethylenetetramine, tech 

Hexanitrostilbene 

Hydrindantin 

o-(2-H/droxy-p-anisoyl )benzoic acid 

p-t^j'droxybenzoic acid esters: 

Benzyl p-hydroxybenzoate 

Butyl p-hydroxybenzoate (Butylparaben) 

Ethyl p-hydroxybenzoate ( Ethylparaben ) 

n-Heptyl p-hydroxybenzoate (Heptylparaben) 

^Methyl p-hydroxybenzoate (Methylparaben) 

^Propyl p-hydroxybenzoate (Propylparaben) 

Other 

N-(2-Hydroxyethyl)gentisajnide 

Hydroxyethylpiperazine 

2-Itydroxy-4-methoxybenzophenone 

2-!^droxy-4-methoxy-5-sulfobenzophenone trihydrate 

Hydroxymethyl-5,5-dimethylhydantoin ■ 

2-(2'-Hydroxy-5 '-methylphenyl)benzotriazole 

2-Ifydroxy-'i-n-octoxybenzophenone 

Ptydroxyphenylbenzotriazole derivative 

2-^ydroxypropyl p-(N, N-bis-2-hydroxypropylamino) 
benzoate. 

l-f^droxy-2-pyridine (Oraadine) 

2-Imidazolidinethione (l,3-Ethylene-2-thiourea) 

1,2,3-Indantrione monohydrate (Ninliydrin) 

Inosine and phosphates 

Isoaji^l p-dimethylaminobenzoate 

Isooyanurio acid 

Isopropyl-o-oresol 

p-Isopropyl-a-methyloinnamaldehyde 

Ketene, dimer 

^Lubricating oil and grease additives: 

Chlorosulfurized and sulfurized compounds: 

Alicyclic compounds, sulfurized 

Heterocyclic compounds, sulfurized 

Tall oil ester, sulfurized 

Terpenes, sulfurized 

All other 

Oil-soluble petroleum sulfonates : 

Oil-soluble petroleum sulfonate, ammonium salt 

*Oil-soluble petroleum sulfonate, barium salt 

»Oil-soluble petroleum sulfonate, calcium salt 

Oil-soluble petroleum sulfonate, magnesium salt 

»Oil-soluble petroleum sulfonate, sodium salt 

All other 

Phenol salts: 

Bariujn salt of nonylphenol 

Calcium salt of octylphenol-formaldehyde 

Calcium salt of polypropylphenol 

All other phenol salts 

All other 

Maleic anhydride half esters, vinyl ether copolymers 

p-Menthane 

8-p-Menthyl hydroperoxide 

p-Methoxybenzylidenemalonic acid, dimethyl ester 

"i-Methoxyphenol 

2-Methylaziridine 

2,2'-Methylenebis[<-chlorophenol] (Dichlorophene ) 

Methylenebis[5,5-dimethylhydantoin] 

2,2' -Methy lenebis[ 3 , 4, 6- trichlorophenol ]( Hexaohlorophene) 
2,2'-Methylenedi-p-oresol (Bis(5-methyl-2-hydroxyphenyl) 
methane ). 



TNA. 
SHC. 
ASH. 
DUP, 
VND. 
VEL. 
PLB. 
BOR, 
NCA. 
HEX. 
ACY. 

Lai. 

HN, 

HN, 

WSN. 

HN, 

HN, 

HN. 

ICO. 

UCC. 

ACY, 

ACY. 

GLY. 

GGY. 

ACY. 

GGY. 

SHL. 



CMC. 

PAS. 

HEX, PIC. 

PLB. 

VND. 

MON. 

CP. 

GIV. 

EKT. 



EKT, TNA, U™. 



DUP, HKD, HMP, HN, PLS. 



ICO, LHH, WSN. 

LM, WSN. 

ICO, Lffl, FYL, SEL, WSN. 

ICO, LU/l, SEL, WSN. 



GAF. 



SOI. 
ORO. 
LUB. 
LUB. 
LUB. 

CO, SIN. 

CO, LUB, TX, X. 

CO, EN J, LUB, ORO, SHO, SOI, TX, WTC. 

CO. 

CO, DA, MOR, PAR, SHO, SOC, SOI, TX, WTC. 

LUB. 



CCA, 
SHC. 
ORO, 
ENJ, 
ENJ, 
GAF. 
HPC. 
HPC. 
ACY. 
ASL, 
ICO. 
GIV. 
GLY. 
GIV. 
GIV. 



ENJ. 



TX. 



LUB, MON, ORO, SIN, TX, x. 
LUB, MON, ORO, SIN, TNA, x. 



EKT. 



MISCELLANEOUS CHEMICALS 



169 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i 567— Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



^aSCELLANEOUS CHHCCAI^, CYCUC— Continued 

Methyl gallate 

Methylgluooside 

A-Methylmorpholine 

5-Methyl-5-norbornene-2,3-dicarboxylic anhydride 
(Methylbicyolo[2.2.1] hept-5-ene-2,3-dicarboxylic 
anhydride). 

Methyl phenyl phosphates 

l-Methyl-2-pyrrolidone, monomer 

Methyl vinyl ether-toluene polymer 

Methyl vinyl ether-xylene polymer 

ifMorpholine 

Jtorpholine salt of p-toluenesulfonio acid 

Naphthenamidoethylnaphthenylimidazolene 

*Napthenic acid salts: 

Aluminum naphthenate 

Barium naphthenate 

Cadmium naphthenate 

«Caloium naphthenate 

Cerium naphthenate 

Cobalt lead manganese naphthenate 

»Cobalt naphthenate 

»Iron naphthenate 

Lead manganese naphthenate 

»Lead naphthenate 

Lithium naphthenate 

^Manganese naphthenate 

Nickel naphthenate 

Rare earths naphthenate 

Sodium naphthenate 

Strontium naphthenate 

*Zinc naphthenate 

o-Nitrobenzoic acid and sodium salt 

5-Norbomen-2-ylraethyl acrylate (Bicyclo[2.2.l]-hept-5- 
ene-2-methylol acrylate). 

l-Octadecenyl-2-naphthenyltetrahydropyrimidine 

Octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)- 

propionate. 
Organic mercury compounds ; 

Phenyl mercuric borate 

Other 

Phenol thiosulfonic acid 

2-Phenoxyethanol (Ethylene glycol monophenyl ether) 

2-(2-Phenoxyethoxy)ethanol (Diethylene glycol phenyl 
ether ) . 

2,2' -(p-Phenylene)diethanol 

m-Phenylene isonaphthalamide 

Phenyl hydrogen phosphate 

5-Hiosphonylribose 1 -pyrophosphate, magnesium salt 

Photographic chemicals: 

N-(o-Acetamidophenethyl)-l-hydroxy-2-naphthamide 

2-(4-Amino-N-ethyl-m-toluidino)ethanol sulfate 

3-Amino-l,2,4-triazole 

Benzotriazole 

p-Benzylaminophenol hydrochloride 

Catechol ( lyrocatechin ) 

»3-Chloro-4-diethylaminobenzenediazonium (p-Diazo- 
2-chloro-N, N-diethylaniline) salts. 

Chlorohydroqulnone 

2,4-Diamlnophenol dihydrochloride (Amidol) 

2[N-(2,4-Di-tert-a]t(ylphenoxyacetyl) ainido]-4, 6- 
diohloro-5-raethylphenol. 

»2, S-Dibutoxy-i-morpholinobenzenediazonium salts 

*Z, 5-Diethoxy-4-morpholinobenzenediazonium salts 

»p-Diethylaminobenzenediazonium (p-Diazo-N, N- 
diethylaniline) salts. 



HSH. 
CRN. 

JCC, UCC. 
ICO. 



TNA. 

GAF. 

GAP. 

GAF. 

DOW, JCC, UCC. 

AMB. 

SM. 

HSH, WTC. 

CCA. 

CCA, X. 

CCA, CCC, PER, HNX, HSH, MCI, MLD, SHP, SM, SOC, SW, 

TRO, WTC. 
SHP. 

HNX, HSH. 
CCA, CCC, PER, HNX, HSH, MCI, MLD, SHP, SM, SOC, SW, 

TRO, WTC, X. 
CCA, CCC, HNX, MCI, MLD, OTC. 
CCA. 
CCA, CCC, CCW, FER, HNX, HSH, MCI, MLD, SHP, SM, SW, 

TRO, TX, WTC, X. 
CCA, MCI. 
CCA, CCC, FER, HNX, HSH, MCI, MLD, SHP, SM, SW, TRO, 

WTC. 
CCA. 

CCA, HNX. 
CCA. 
CCA. 
CCA, CCC, FER, HNX, HSH, MCI, MLD, SHP, SM, SOC, SW, 

TRO, WTC. 
WAY. 
ICO. 



SM. 




GGY. 




TRO. 




EK. 




GAF. 




DOW. 




DOW. 




EKT. 




X. 




HDG, SM. 




PLB. 




EKT. 




EKT. 




FMT. 




EK, FMT, 


MEE, MRT. 


EK. 




KPT. 




ESA, FMT, 


IDC. 


EK. 




VPC. 




IDC. 




ESA, FMT, 


IDC. 


ESA, FMT, 


GAF, IDC. 


ESA, PMT, 


GAF, IDC, MRT 



170 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i567--Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, CYCLIC--Continued 

Photographic chemicals — Continued 

p-Diethylaminobenzenediazonium (p-Diazo-N, N- 
diethylaniline) fluoroborate. 

N, N-Diethyl-p-phenylenediamine hydrochloride 

*N, N-Diethyltoluene-2, 5-diamine, monohydrochloride ■ 

2, 5-Dihydroxybenzenesulf onic acid 

2, 7-Dihydroxy-3, 6-naphthalene sulfonate 

p-Dimethylajninobenzenediazoniujn chloride (p-Diazo- 

N, N-dimethylaniline) - zinc chloride. 
'i-(2',6'-Dimethyliiiorpholinyl)benzenediazonium chloride - 
zinc chloride. 

p-Diphenylaminediazonium sulfate 

p-(N-Ethylbenzimido)benzenediazoniuin chloride (p-Diazo- 

N-benzyl-N-ethylaniline) - zinc chloride. 
p- [Ethyl(2-hydroxyethyl )ajnino]benzenediazoniujn chloride 
(p-Diazo-N-ethyl-N-hydroxyethylaniline) - zinc 
chloride. 

N-Ethyl-N-hydroxyethyl-p-phenylenediamine sulfate 

N-Ethyl-N-(p-methanesulf onamidoethyl )toluene-2, 5- 
diajnine sulfate. 

}fydroquinone ( ffydroquinol ) 

p-[ (2-Itydroxyethyl )methylajiu.no]benzenediazoniujii 

chloride (p-Diazo-N-hydroxyethyl-N-methylaniline) - 
zinc chloride. 
l-Hrdroxy-N-(2-hydroxyethyl)-2-naphthainide (2,3- 
Qxynaphthoic-mono-ethanolamide ) . 

l-(3-Ifydroxyphenyl)urea 

4-Methoxy-l-naphthol 

p-Methylajidnophenol sulfate 

5-Methylbenzotriazole 

2-Methylbenzoxazole 

4--Methyl-l-phenyl-3-pyrazolidinone 

4-Morpholinylbenzenediazoni\iin salts 

6-Nitrobenzimidazole 

Octylphenyl salicylate 

Phenyl-5-mercaptotetrazole 

l-Phenyl-3-pyTazolidinone 

•i-Phenylpyrocatechol 

Polyvinyl cinnamate 

2-Resoroylic monoethanolamide 

•i,'i'-Thiodiresorcinol (Diresorcyl sulfide) 

l-(2,4,6-Trichlorophenyl )-3-(4-nitroanilino)-2- 
pyrazolin-5-one. 

All other 

Phthalic acid, lead salt, dibasic 

Picric acid, sodium salt 

»Pinene (a- and (j-) 

Piperonal, sodium bisulfite complex 

Poly-<i-(2-acryloxy ethoxy )-2-hydroxybenzophenone 

Poly(dihydroxyphenylene) sulfide 

Polyethylene terephthalate 

Polyvinyl phthalate 

»Propyl gallate 

lyrogallol (pyrogallic acid) 

Resorcinol monobenzoate 

*Itosin acid salts: 

Aluminum resinate 

Calcium resinate 

Cobalt manganese resinate 

Copper resinate 

Iron resinate 

Lead resinate 

Manganese resinate 

Zinc resinate 

Salicylanilide 

Salicylic acid salts; 

Lead salicylate 

Strontium salicylate 

Sodium cresoxide (Cresylic acid, sodium salt) 

Sucrose benzoate 



IDC. 

EKT, EMT. 

EKT, FOT, IDC. 

EK. 

FMT. 

ESA, FMT, IDC. 

IDC. 



FMT, 


MET 


FMT, 


IDC 


IDC. 




EKT. 




EKT. 
FMT. 





FMT. 
FMT, IDC. 

X. 

EK. 
EK. 
FMT. 
WAY. 

FMT, IDC. 
EK, FMT. 
EKT. 

CFC, FMT. 
GGY, WAY. 

X. 

WAY. 
FMT. 
BKC. 
EKT. 

EK, EKT, FMT, IDC, VPC, WAY, x. 

NTL. 

NCA, 

ARZ, 

SHL. 

ACY. 

ACY. 

DUP, 

EK. 

EKT, 

HSH, 

EKT. 



SDC. 

CBY, GLD, HNW, HPC, NCI. 



EK. 



HN, HSH. 
MAL. 



JMS. 

JMS, SW. 
JMS. 
JMS. 

HSH, JMS. 
JMS. 

JMS, WVA. 
JMS, SW. 
DUP, PCW. 

NTL. 
CFC. 

DEX, GOC. 
VEL. 



MISCELLANEOUS CHEMICALS 



171 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i 567- -Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAIS, CYCLIC— Continued 

Sulfosalicylic acid 

Tall oil fatty acid chloride 

*Tall oil salts (linoleic-rosin acid salts); 

Barium zinc tallate 

Calcium manganese tallate 

»Caloium tallate 

■»Cobalt tallate 

Copper tallate 

Iron tallate 

Lead manganese tallate 

»Lead tallate 

*Manganese tallate 

Manganese zinc tallate 

Zinc tallate 

Tannic acid 

*Tanning materials, synthetic: 

ftydroxytoluenesulfonio acid, formaldehyde condensate 
( Cresol-f ormaldehyde sulfonate), sodium salt. 
*2-Naphthalenesulfonic acid, formaldehyde condensate and 

salts. 
*l-Phenol-2-sulfonic acid, formaldehyde condensate 
( Phenol-formaldehyde, sulfonated ) . 
Styrene maleic anhydride interpolymer, partial sodium 
salt. 

Sulfonyldiphenolsulfonic acid, formaldehyde condensate 

All other 

Tetra(n-butyl )ammoniujii piorate 

Tetrahydromethylthiophene-l,l-dioxide 

l,2,3,4--Tetraliydronaphthalene (Tetralin) 

Tetrahydrothiophene 

Tetrahydrothiophene-l,l-dioxide (Sulfolane) 

Tetrakis [methylene-3-(3 ', 5 '-dl-tert-butyl-"*' -hydroxyphenol ) 
propionate] methane . 

Tetranitrocarbazole 

Tetraphenyltin 

"Textile chemicals, other than surface-active agents: 
l,3-Bis(hydroxymethyl)-2-imidazolidone (Diraethylol 
ethylene urea), 

•4-Decyloxy-2-hydroxybenzophenone 

N^, N"'"-Diphenyl-l,2-propanediamine 

l-[ (Octadecyloxy)methyl]pyridinium chloride 

Phenol, sulfurated 

Tetrahydro-3, 5-bis(methoxyraethyl )-^H-l,3, 5-oxadlazine-4- 
one (l, 3-Bis(m.ethoxymethyl)uron). 

2,2',4,4-'-Tetrahydroxybenzophenone 

All other 

2,2'-Thiobis [4-chlorophenol] 

2,2'-Thiobis ['i,6-dlchlorophenol] 

[2,2'-Thiobis('i-octylphenolate)]-n-butylamine nickel 

Thiophene 

3-o-Tolyloxy-l,2-propanediol 

o-Tolylblguanide 

Trial lyl cyanurate 

Triaryl phosphites 

Tribenzylamine 

3,4',5-Tribromosalicylanilide 

3,4',5-Tribromosalicylanilide and dibromosalicyl- 
anilide mixtures. 

3,4,4' -Trichlorocarbanilide 

Trichloromelamine 

l,3,5-Trichloro-s-triazine-2,4,6(lH,3H,5H)trione 
(Trichloroisocyanuric acid). 

Trl-(m,p)-cresyl borate 

a, j.,a-Trifluoro-p-toluidine (p-Aminobenzotrifluoride) 

Trimethylaminoethylpiperazine 

3, 5, 5-Trimethyl-2-cyclohexen-l-one ( Isophorone ) 

2,4,6-Trinitroresorcinol, lead derivative 

s-Trioxane 

Triphenylphosphine 



MON, MRK. 
GAF. 



HSH. 
MCI. 
CCA, 
CCA, 
CCA, 
CCA, 
HSH, 
CCA, 
CCA, 
MCI. 
CCA, 
HSH, 

GGY. 



CCC, DYS, HNX, HSH, MCI, MID, SRfi, TRO, .VTC. 

CCC, FER, HNX, MCI, MLD, SHP, SRR, TRO, WTC. 

MCI, MLD, SHP. 

MCI, MLD, SHP, SRR, WTC. 

MCI. 

CCC, FER, HNX, HSH, MCI, MLD, SHP, SRR, TRO, WTC. 

CCC, FER, HNX, HSH, MCI, MLD, SHP, SRR, TRO, WTC. 

HSH, MCI. 
MAL. 



AKS, 


DA, GRD, 


NYC, RH 


ACS, 


DA, RH. 




DUP. 






GAF. 






AKS, 


GGY. 




PLC. 






DUP, 


UCC. 




ORO, 


PAS. 




PLC. 






GGY. 







SDC. 



ACY, AKS. 

GAF. 
SNW. 
DUP. 
GAF. 
DEX. 

GAF. 
X, x, 

GIV. 
SDH. 
ACY. 

PAS. 

ICO. 

MON. 

ACY. 

WES. 

BPC. 

DOW, FIN, MEE. 

FIN. 

MON. 
WTH. 
MON. 

USB. 
PIC. 
JCC. 
ENJ, UCC. 

X. 

CEL. 
CCW, X. 



172 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i967--Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELIANEOUS CHIMICAIS, CYCLIC— Continued 

Triphenyl phosphite 

Triphenyltin 

Triphenyltin chloride t 

Tris(l-aziridinyl)phosphine oxide 

Uridine derivatives 

l-Vinyl-2-pyrrolidinone - acrylaraide copolymer 

l-Vinyl-2-pyrrolidinone - ethyl - acrylamide copolymer- 

l-Vinyl-2-pyrrolidinone - olefin copolymers 

l-Vinyl-2-pyrrolidinone - vinyl acetate copolymer 

l-Vihyl-2-pyrrolidinone, monomer and polymer 

MISCELLANinUS CHiMICALS, ACYCLIC 
Cellulose Esters and Ethers 

»Cellulose esters : 

^Cellulose acetate 

Cellulose acetate butyrate 

Cellulose acetate propionate 

Cellulose propionate 

Nitrocellulose (Cellulose nitrate) 

»Cellulose ethers; 

Ethylcellulose 

Ethylhydroxyethylcellulose 

Hydroxy ethylcellulose 

Hydroxypropylcellulose 

Methylcellulose 

^Sodium carboxymethylcellulose, 100^ 

Sodium carboxymethylhydroxyethylcellulose 

l.ubrlcatini^ Oil Additlies 

Chlorosulfurized lard oil 

Chlorosulfurized sperm oil 

Oxidized hydrocarbons 

»Phosphorodithioates (Dithiophosphates ): 

Zinc di(butylhexyl) phosphorodithioate 

Zinc dihexyl phosphorodithioate 

All other 

Sulfurized butenes 

*Sulfurized lard oil 

Sulfurized sperm oil 

All other 

iVi tro^enous Compounds 

Acetamide 

Acetamidine hydrochloride 

Acetamidoethanol (n-Acetyl-ethanolaraine ) 

Aoetonitrile 

*Acrylonitrile 

Adiponitrile 

Allyl-sec-butylcyanoacetic acid, ethyl ester 

l-Allyl-3-(2-hydroxyethyl)-2-thiourea 

Allyl isocyanate 

Allyl isothiocyanate, non-perfume grade 

Allyl nitrile (Allyl cyanide) 

Amidinourea (Guanylurea) phosphate 

»Amines : 

Allylamines 

n-Butylaraines: 

*n-ButylajTdne, mono- 

»Di-n-butylajnine 

Tri-n-butylamine 

tert-Butylamine, mono- 

n-Butylethylajnine 

n-Butylmethylamine 

Diethylaminopropylandne 

Diethylenetriamine 

N, N-Diethylethylenediamine 

N-^, N-'-Diethyl-lj'V-pentanediamine (Novoldiamine) 

Dihexylamine 



HK, MON. 

X. 

X. 

DOW. 
PLB. 
GAF. 
GAF. 
GAF. 
GAF. 
GAF. 



AV, CEL, DUP, EKT. 

EKT. 

EKT. 

CEL. 

DUE, HPC. 

DOW, X. 
HPC. 
HPC, UCC. 

X. 

DOW. 

BUK, DUP, HPC, KON, WMP, WYN, UCC. 

HPC. 



CCW. 






ccw. 






ALX. 






ORO. 






MON, 


SIN. 




ENJ, 


LUB, 


MON, SIN, X. 


LUB. 






ccw, 


GOC, 


NLC, SIN, WBG. 


CCW, 


LUB, 


QCP, SIN. 


CCW, 


ENJ, 


HK, LUB, MON, ORO, PAS, SIN, SM, SOI, TX 


ACS. 






MRK. 






RBC. 






EKX, 


SOH, 


UCC. 


ACY, 


BFG, 


DUP, MON, SOH. 


DUP, 


MON. 




SDW. 






FMT, 


IDC. 




CWN. 






ICO. 






KF. 






ACY. 






SHC. 






EKT, 


PAS, 


UCC, VGC. 


PAS, 


UCC, 


VGC. 


PAS, 


VGC. 




MON, 


RH. 




PAS. 






PAS. 






UCC 






DOW, 


JCC, 


UCC. 


ALB, 


CBP. 




SDH. 






VGC. 







MISCEllANEOUS CHEMICALS 



173 



TABLE 21B. --Miscellaneous chemicals for wltich U.S. production or sales were reported, identified by 

manufacturer, i 967- -Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHBDCALS, ACYCLIC— Continued 

/Vi trogenctts Compounds- -Continued 

♦Amines — Continued 

N, N-Dimethyl-l,3-propanediamine 

Dimethylandnopropylamine 

Ethylajnines : 

»Diethylaniine 

Diethylamine hydrochloride 

»Ethylamine, mono- 

»Triethylamine 

Ethylenediamine 

Ethylenediamine sulfate 

(2-Ethylhexyl )ainine, mono- 

n-Heptylamine 

»1,6-Hexanediamine (Hexamethylenediamlne) 

n-Hexylamine 

3,3'-ljninohispropylamine 

Isobutylajrdnes ; 

Diisobutylamine 

Isobutylamine, mono- 

Isopropylamines : 

»Dilsopropylainine 

*Isopropylamine, mono- 

Methylamines : 

»Dimethylamine 

Dimethylamine hydrochloride 

Dimethylamine sulfate 

*Methylamlne, mono- 

Methylamine hydrochloride 

*Trimethylainine 

n-Octylamine, mono- 

Pentaethylenehexajnine 

Pentylamines ( Amylamlnes ) : 

Dipentylamine 

Pentylamine, mono- 

Tripentylamine 

1,2-Propanediamine (Propylenediamine) 

1,3-Propanedianiine (1,3-Diaminopropane) 

Propylamines : 

»Dipropylamine 

Propylamine^ mono- 

Tripropylamine 

Tetraethylenepentamine 

N, N, N', N'-Tetramethyl-l, 3-butanediamine 

Tetramethylethylenediamlne 

Triethylenetetramine 

Other amines 

2-Amino-l-butanol 

2-Aminoethanethiol (2-Mercaptoethylamine) hydrochloride-- 

1-Aminoethanol (Acetaldehyde ajnraonia) 

2-Aminoethanol (Monoethanolamine) hydrochloride 

2-Aminoethanol (Monoethanolamine) sulfite 

Aminoethoxyethanol 

2-(2-Amlnoethylainino)ethanol (Aminoethylethanolamine) 

2-Amlnoethyl mercaptoaoetate (Jtonoethanolamine 
thioglyoolate ) . 

2-Amino-2-ethyl-l,3-propanediol 

Aminoguanidine bicarbonate 

2-Amino-2-(hydroxymethyl)-l,3-propanediol ( Tris-( hydroxy - 
methyl )aminomethane ) . 

2-Amino-2-methyl-l,3-propanedlol 

2-Amino-2-methyl-l-propanol 

2-Amino-l-propanol 

3-Amino-l-propanol 

*l,l'-A2obisformamlde 

2,2'-Azobls[2-methylproplonitrlle] ( Azobislsobutyro- 

nitrile). 
l,3-Bis(hydroxymethyl)urea (Dimethylolurea) 



JCC. 








ARC, 


UCC. 






DUP, 


ESC, 


PAS, 


UCC, VGC 


CFC. 








ESC, 


PAS, 


UCC, 


VGC. 


ESC, 


PAS, 


UCC, 


VGC. 


DOW, 


JCC, 


UCC. 




ASH. 








VGC. 








ALB. 








CEL, 


DUP, 


ELP, 


MON. 


VGC. 








JCC, 


UCC. 






PAS. 








PAS. 









ESC, PAS, UCC, VGC. 

ESC, PAS, UCC, VGC. 

COM, DUP, ESC, GAF, PAS, RH. 

CFC, EK. 

RH. 

COM, DUP, ESC, GAF, PAS, RH. 

EK, RBC. 

COM, DUP, ESC, GAF, PAS, RH. 

VGC. 

DOW. 



ASH, 


PAS, 


VGC. 




EK, 


PAS. 






PAS. 








UCC. 








JCC. 








PAS, 


UCC, 


VGC. 




PAS, 


UCC, 


VGC. 




PAS. 








DOW, 


UCC. 






UCC . 








RH. 








DOW, 


UCC. 






ALB, 


ALD, 


DUP, 


EK, NLC, PIC, SDW, UCC 


ACY, 


CCW. 






EVN. 








PAS. 








WSN. 








EVN, 


SUM. 






JCC. 








DOW, 


HDG, 


JCC, 


UCC. 


EVN, 


HAB. 






cm. 








C(1A, 


TRJ. 






ccw. 








CCM. 








CCM. 








LIL. 








UCC. 








FMT, 


NPI, 


USR. 




DUP. 








CCW, 


GLY, 


x. 





>174 



SYNTHETIC ORGANIC CHEMICALS, )967 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer , 7967- -Continued 



Chemioal 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 
Nitrogenous Compoun(is--Continued 

N, 0-Bls(trlmetliylsilyl)acetajiiide 

Biuret 

N-Bromoacetamide 

N-Bromosuccinimide (Suocinibromimide ) 

2,3-Butanedione monoxime 

2-Butanone oxime 

l-Butyl-3-ethyl-2-thiourea 

2, 2 ' - ( Butylimino )diethanol ( N, N-Bis ( 2-hydroxyethyl ) - 
butylamlne). 

Butyl isocyanate 

Butyraldehyde oxime 

n-Butyronitrile 

*Caprolaotam (2-Oxohexamethylenimine ) 

Chloroacetamide 

Chloroaoetonitrile 

p-Chloroallyl-N-methylamine 

Chlorooholine chloride 

2-Chloro-N, N-dimethylethylamlne (Dimethylaminoethyl 
chloride) hydrochloride. 

2-Chloro-N, N-diethylethylamine hydrochloride 

3-Chloro-N, N-dimethylpropylamine 

2-Chloro-N, N-dimethylpropylamine hydrochloride 

3-Chloro-N, N-dimethylpropylamine hydrochloride 

2-Chloroethylamine hydrochloride 

N-Chlorosuccinimide (Succinichlorimide) 

Choline base 

Coco nitrile 

Coconut oil amide 

Cottonseed oil acids, ammoniujn salt 

Cottonseed oil nitrile 

Creatine and creatinine 

2-Cyanoacetaraide 

2-Cyanoacethydrazide 

Cyanoacetic acid 

cyanogen bromide 

3-Cyanopropylamine 

2-Dibutylaminoethanol 

l,3-Dibutyl-2-thiourea 

l,<+-Dioyanobutene 

Diethanolamine polyoxypropylene ether 

Diethyl acetamidoraalonate 

Diethylaminoethanethiol hydrochloride 

2-Diethylaitiinoethanol 

2-(2-Diethylaminoethoxy)ethanol 

2-Diethylaminoethyl methacrylate 

Diethyldithiocarbamic acid, sodium salt 

N,N-Diethyldodecan amide 

Diethylhydroxylamine 

l,3-Diethyl-2-thiourea 

Diisopropylaminoethanol 

Diisopropylaramoniujn nitrite •• — 

N, N-Dimethylacetamide 

2-Dimethylaminoethanethiol hydrochloride 

»2-Dimethylaminoethanol 

Dimethylaminoethyl methacrylate 

Dimethylami no-2-propanol 

3-DimethylaiDinopropionitrile 

Dimethylcarbamoyl chloride 

N, N-Dimethylformamide 

1,1-Dimethylhydrazine 

2, 5-Dithiobiurea 

Dithiooxamide 

»Eruoamide 

*Ethanolamines : 

»2-Aminoethanol (Monoethanolamine) 

*2,2'-Iminodiethanol (Diethanolamine) 

»2,2',2" -Nitrilotriethanol (Triethanolamine) 



PIC. 








sw. 








ARA. 








ARA, 


SDW. 






EK. 








ACS, 


CCA, 


MID. 




PAS. 








PAS. 








CWN, 


UP J. 






ACS. 








EKX. 








ACS, 


CNP, 


DBC, 


DUP. 


BPC. 








BPC. 








LIL. 








ACY. 








ABB, 


HEX, 


MCH, 


PAS. 


HEX. 








SK. 








MCH. 








MCH. 








NES. 








ACS, 


ARA. 






RH. 








FOR. 








ARC, 


PG. 






GLY. 








FOR. 








PFN. 








KF. 








KF. 








KF. 








EK. 








EKT. 








AAC, 


PAS. 






OMC, 


PAS, 


RBC. 




X. 








JCC. 








RSA, 


SDW. 






EVN. 








AAC, 


PAS, 


UCC. 




PAS. 








DUP. 








EK. 








EK. 








PAS. 








PAS, 


RBC. 






PAS, 


ucc. 






OMC. 








DUP. 








EVN. 








AAC, 


JCC, 


PAS, 


RH, UCC 


X. 








COM, 


PAS. 






ACY. 








CTN, 


OTC. 






DUP. 








FMP. 








ACY. 








MAL. 








ARC, 


ASH, 


FIN, 


HUM. 


ACP, 


DOW, 


JCC, 


UCC. 


ACP, 


DOW, 


JCC, 


UCC. 


ACP, 


DOW, 


JCC, 


UCC. 



MISCELLANEOUS CHEMICALS 



175 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 7967— Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHE^^CALS, ACYCLIC— Continued 
Nitrogenous Compounds — Continued 

Ethoxymethyleneraalononitrile 

3-Ethoxypropionitrile ; 

Ethyl acetamidocyanoacetate 

2-Ethylajninoethanol ( Ethylmonoethanolamine ) 

Ethyl carbamate 

Ethyl carbodiimide hydrochloride 

Ethyl cyanoacetate 

N, N'-Bthylenebis stearamide 

2-Ethylhexyl cyanoacetate 

5-(N-Ethyl-N-hydroxyethylamino)-2-pentanone 

N-Ethyl-N-hydroxyethyl-lj'i-pentanediamine 

Ethyl isocyanate 

Ethyl isothiocyanate 

Fish oil fatty acid amide 

Formamide 

Formamidine disulfide dihydroohloride 

Formamidine hydrochloride 

Glycine (Aminoaoetic acid), non-medicinal 

Glycine ethyl ester hydrochloride 

Glycine salts: Cuprio glycinate 

Glycolonitrile 

Guanidine hydrochloride 

Hexadecyl nitrile 

Hexamethyldiaminoisopropanol diiodide 

Hex amethylenedi ammonium adipate (Nylon salt) 

Hydracrylonitrile (Ethylene cyanohydrin) 

N-(2-Hydroxyethyl)chloracetamide 

2-(Hydroxymethyl)-2-nitro-l,3-propanediol ( Tris( hydroxy • 
methyl )nitroraethane ) . 

N-[fydroxyraethylstear amide 

3,3'-Iminodi-l,2-propanediol 

Isobutyl cyanoacetate 

Isobutyronitrile 

Isopropanolamines ; 

l-Araino-2-propanol (Vonoisopropanolamine) 

1, l'-Iminodi-2-propanol (Diisopropanolamine) 

1,1', 1" -Nitrilotri-2-propanol ('Briisopropanolamine)-- 

3-Isopropoxypropionitrile 

3-Isopropoxypropylamine 

2-Isopropylaminoethanol 

Isopropyl carbamate 

Isopropyl ethyl thionocarbamate 

Isopropyl isocyanate 

Lactonitrlle 

Lauronitrile (Dodecyl nitrile) 

Malononitrile 

Methacrylamide 

Methacrylonitrile 

Methoxyamine hydrochloride 

Me thoxyiminobis (propylamine) 

3-Methoxypropionitrile 

3-Methoxypropylamine 

N-Methylacetamide 

2-Methylaminoethanol (N-Methylethanolamine) 

Methylamino dimethyl acetal 

Methyl carbamate 

Methyl cyanoacetate 

Methyl a-oyanoacrylate 

N, N'-Methylenebis(acrylamide) 

N, N '-Me thy lenebis(octadecan amide) 

Methylenebls(thiooyanate) 

N-Methylglucamine 

2,2'-(Methylimino)diethanol (Methyldiethanolamine) 

Methyl isobutyl ketoxime 

Methyl isocyanate 

*2-Vjethyllactohitrile (Acetone cyanohydrin) 

2-Methyl-2-nitro-l,3-propanediol 



KF. 




ACY. 




SDW. 




PAS. 




FMP. 




OTC. 




KF. 




CTN. 




GAF, 


KF. 


SDW. 




SDW. 




OTC. 




CWN, 


EK. 


ASH, 


HUM. 


DUP. 




WAY. 




KF. 




BPC, 


CHT. 


BPC. 




BPC. 




ACY. 




ACY. 




FOR. 




RSA. 




CEL, 


DUP, MON 


UCC. 




KF. 




COM. 




ICI. 




DUP. 




KF. 




EKX, 


ESC. 


DOW, 


UCC. 


DOW, 


UCC. 


DOW, 


UCC. 


ACY, 


DUP. 


DUP. 




PAS. 




BKL. 




DOW. 




OTC. 




MON. 




ARC, 


FOR. 


KF, 


MTR. 


RH, 


X. 


SOH. 




EK. 




JCC. 




DUP. 




DUP, 


JCC. 


ACI, 


EK. 


UCC. 




LIL. 




BKL, 


FMP. 


KF. 




EKT. 




ACY. 




ARC. 




NLC. 




DUP. 




UCC. 




ALB. 




OTC. 


UCC. 


ACY, 


RH, X. 


COM. 





176 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i967 --Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAIS, ACYCLIC--Continued 
/Vifrogenous Compounds--Continued 

2-Methyl-2-nitro-l-propanol ' 

Methylpolyethanolamine 

N-Methyltaurine 

N-Methylurea 

Nitrated lard oil 

*Nitriloacids and salts: 

(Diethylenetrinitrilo)pentaacetlo acid 

(DietlTylenetrinitrilo)pentaacetic acid, mono-sodium 

hydrogen ferric salt. 
(Diethylenetrinltrilo)pentaacetic acid, pentasodium salt 

(Diethylenetrinitrilo)pentaacetic acid, sodium salt 

N, N-Dihydroxyethylglyoine, sodium salt 

Ethanoldiglyoine, disodiujn salt 

»(Ethylenedinitrilo)tetraacetic acid ( Ethylenediamine- 
tetraacetic acid), 
(Ethylenedinitrilo)tetraacetic acid, calcium disodium 
salt. 

{Ethylenedinitrilo)tetraacetio acid, disodium salt 

(Ethylenedlnitrilo)tetraaoetic acid, disodium copper 

salt, dihydrate. 
(Rhylenedinitrilo)tetraacetic acid, disodium zinc salt, 
dihydrate. 

(Ethylenedlnitrilo)tetraacetic acid, manganese salt 

( Ethylenedlnitrilo)tetraacetic acid, monosodium iron 

salt. 
(Ethylenedinitrilo)tetraacetio acid, tetrammonium salt-- 
{Ethylenedinitrilo)tetraacetio acid, tetrapotassiura salt 

»(Ethylenedlnitrilo)tetraacetic acid, tetrasodlum salt 

(Ethylenedinitrilo)tetraacetio acid, triammonlum salt 

»{Ethylenedinitrilo)tetraacetic acid, trlsodium salt 

(N-Hydroxyethylethylenedinltrilo)triacetic acid 

■x-(N-Hydroxyethylethylenedinitrilo)triacetic acid, tri- 
sodium salt. 

Nitrilotriacetic acid, trlsodium salt 

Other 

2-Nitro-l-butanol 

Nitroethane 

Nitromethane 

l-Nitropropane 

2-Nitropropane 

»Nylon, 6 and 6/6 polymer for fiber 

Octadecyl isocyanate 

Octadecyloxymethyltriethylammonium chloride 

Oleamide (Ootadecene amide) 

Oleonitrile (Octodecene nitrile) 

Oleoylhydroxamic acid 

Oleoylpalmltamide 

»Pentaerythrltol tetranitrate 

Pentyl nitrate (An^l nitrate) 

Polyacrylamide 

Polyacrylonitrile 

Polyesteramide 

n-Ftopyl carbamate 

Propyl isocyanate 

Propyl nitrate 

Quaternary ammonium compounds 

Ricinolamide 

»Sarcosine ( N-Methylaminoaoetic acid) 

Semicarbazide base 

Semicarbazide hydrochloride — 

Semioxamazide 

»Stearaiiiide (Ootadecane amide) 

Stearonitrile (Octadecanenitrlle) 

Succinimide 

Tallow amide, hydrogenated 

Tallow nitrile 

Tallow nitrile, hydrogenated 

N, N, N',N'-Tetrakis(2-hydroxypropyl)ethylenediamine 



COM. 

GAP. 

GAP. 

EK. 

SM. 

HMP. 
GGY. 

GGY, HMP. 

CWL, DOW, GGY, HMP, RFC, TCC. 

OWL, DOW, HMP. 

HMP. 

DOW, EK, GGY, HMP. 

DOW, GGY. 

DOW, EK, GGY, HMP, RPC. 
GGY. 

GGY, HMP. 

GGY. 
GGY, HMP. 

DOW. 

GGY. 

CRT, CWL, DOW, GGY, HMP, HRT, IBI, RPC, TCC. 

DOW. 

DA, GGY, MAP. 

GGY. 

CRT, CWL, DOW, GGY, HMP, IBI, RPC, TCC. 

DOW, GGY, HMP. 

HMP. 

COM. 

CCM. 

CCM. 

COM. 

COM. 

ACS, DBC, DUP, MON. 

cm, MOB. 

DAN. 

ARC, ASH, FIN, HUM. 

ARC, FOR. 

WAY, WOB. 

FIN. 

CCM, DUP, HPC, TRJ. 

TNA. 

ACY, HPC, NLC. 

DUP. 

ICI. 

BKL. 

CWN, OTC. 

TNA. 

EK, RSA, WAY. 

TKL. 

GAF, GGY, HMP. 

FMT. 

FMT. 

NOR. 

ARC, ASH, DUP, FIN, HUM. 

FOR, HUM. 

ACS. 

ARC, ASH. 

ASH, FOR. 

FOR. 

WYN. 



MISCELLANEOUS CHEMICALS 



\77 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i 967 --Continued 



Chemical 



Manufacturers' identification codes 
(aooording to list in table 22) 



MISCELLANEOUS CIOMICAIS, ACYCLIC--Continued 

Nitrogenous Compounds --Continued 

Tetramethylguanidine 

Thioacetamide 

3,3'-Thiodipropionitrile 

Thiosemicarbazide 

»Urea in compounds or mixtures, 100^ basis: 

»In feed compounds 

*In liquid fertilizer 

»In solid fertilizer 

In plastics 

All other 

Urea peroxide 

Urea - Urethane copolymer 

7-Valeronitrile 

All other nitrogenous compounds 

Acuis. Acid Anhydrides, and Acyl Halides 

"Acetic acid, synthetic, lOO^t 

»Acetic anhydride, 100^: 

From acetaldehyde 

From acetic acid, other than recovered, by the vapor- 
phase process. 
From acetic acid, recovered, by the vapor-phase prooess- 

From ethylene 

Aconitic acid ■ 

»Acrylio acid 

»Adipio acid 

Adipoyl chloride 

Azelaio acid 

Behenic acid 

a-Bromo(lauric-stearic) acid 

tert-Butylperoxymaleic acid 

Butylstannoic acid 

»Butyric acid 

Butyric anhydride 

Butyryl chloride 

Castor oil fatty acids, dehydrated 

»Chloroacetic acid, mono- 

Chloroacetyl chloride 

Chlorolevulinic acid 

Citric acid 

Crotonic acid (2-Butenoic acid) 

»Decanoyl chloride 

Diglycolic acid 

Dodeoenylsuccinio anhydride 

2-Ethylbutyric acid (Diethylacetic acid) 

2-Ethylhexanoic acid (d-Ethylcaproic acid) 

2-Ethylhexanoyl chloride 

»Formic acid, 90^ 

»Fuinaric acid 

"Gluconic acid, tech 

Glutaric anhydride 

Glycolic acid (}{ydroxyacetic acid) 

n-Hexadecenylsuocinic anhydride 

Hexafluoroglutario acid 

Isethionic acid (2-Hydroxyethanesulfonic acid) 

Isoasorbic acid 

Isobutyric acid 

Isobutyric anhydride 

Iso-octanoic acid 

Itaconic acid (Methylenesuccinio acid) 



ACY. 
EK. 
ACY. 
ACY, FMT. 

ACN, 1 ^.- DUP, GCC, JDC, KET, MON, MSC, SHC, SOH, 

TER, VLN, WC. 
ACN, AOY, BOR, CFA, CMC, COL, DUP, ESC, FCA, FTX, 

GCC, GOC, HKY, HPC, JDC, KET, MON, MSC, NIT, CMC, 

PLC, PPC, SHC, SNI, SOH, TER, VLN, WYC, x. 
ACN, ACY, DUP, GCC, GOC, HPC, JDC, MON, MSC, CMC, 

PPC, SHC, SNO, SOH, TER, VLN, WYC, x, x, x, x. 
DUP, MON. 

ACN, ACY, DUP, HPC, MON, SHC, SNO, SOH. 
FMB. 
DUP. 

EK, SEL. 
ACY, AID, ARC, DUP, EK, FIN, GAF, GLY, LIL, MOB, NCA, 

CMC, SM, VPC, WAY, lYYN, x, x. 



BOR, CEL, EKT, HPC, PUB, SNC, UCC. 

HPC. 

CEL, EKT, FMT. 



CEL. 

UCC. 

PCW. 

BFG, 

ACS, 

CFC, 

mR. 

ASH. 

DUP. 

WTL. 

CCW. 

CEL, 

ARC, 

HK. 

BAG. 

BUK, 

DOW. 

CHZ. 

MLS, 

EKT. 

CAD, 

DUP. 

ACS, 

UCC. 

EKT. 

UPR, 

DUP, 

ACS, 

CWL, 

UCC. 

DUP. 

HMY. 

PIC. 

GAF. 

MRK, 

EKT. 

EKT. 

SFA, 

PFZ. 



CEL, DBC, MMM, UCC. 
CEL, DUP, ELP, MON, RH. 
EK. 



EKT, UCC. 
EKT, UCC. 



DA, DOW, HPC, MON. 

PFZ. 

UPR, WTL. 

ARC, HMY, MON. 

UCC. 

WTL. 

HN, SFI, SNC, UCC. 

HN, MON, PCC, PFZ, PTT. 

DLI, IBI, PFZ. 



PFZ. 



UCC. 



178 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i567--Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

Aci-ds, Acid Anhydr ide 5 , and Acyl Hahdes-'Continued 

Lactic acid: 

Edible, lOO^t 

Technical, 100«(. 

»Lairroyl chloride 

Levulinio acid 

Maleio acid 

»Maleic anhydride 

Malic acid 

Malonic acid 

Mercaptoacetic acid (Thioglyoolio acid) 

P-Mercaptopropionic acid 

Mercaptosuccinio acid (Thiomalic acid) 

Methacrylio acid 

Methanesulfonio acid 

2-Methylvaleric acid (2-Methylpentanoio acid) 

Muoochloric acid (2,3-Dichloro-3-f ormylaorylic aoid)- 

Neodecanoic acid 

Neoheptanoic acid 

Neononanoic acid 

Neopentanoic acid 

Nonanolc acid (Pelargonio acid) 

Nonenylsuccinic anhydride 

Ootadecylphosphonic acid 

Ootanoyl chloride 

Octenylsuccinic anhydride 

Oleoyl chloride 

Oxalic acid 

*Palmitoyl chloride 

Pelargonyl chloride 

Perfluorobutyryl chloride 

Perfluoroglutaryl chloride 

Peroxyacetic acid 

Pivaloyl chloride 

Polyacrylic acid 

Polygalacturonic acid 

^Propionic acid 

Propionic anhydride 

Propionyl chloride 

Sebacic acid 

Sorbic acid (2,'i-Hexadienoic acid) 

Succinic acid 

Succinic anhydride 

d-Tartaric acid 

Tetrahydroxysuccinic acid (Dioxytartaric acid) 

Thioacetic acid 

3,3'-Thiodipropionic acid 

Thiodisuccinic acid 

Thiolactic acid 

Trichloroacetic acid 

Trichloroaoetyl chloride 

Trif luoroacetic anhydride 

Valeric acid 

All other 

Salts of Organic Acids 

*Acetic acid salts: 

Aluminum acetate 

Aluminum subacetate 

*Aiiimonium acetate 

Barium acetate 

Cadmium acetate 

Calcium acetate 

Chromium acetate 

Cobalt acetate 

Copper acetate 

Dibutyltin di acetate 



CLN, 


MON. 


CLN, 


MON. 


CAD, 


GAT, HK, ONX, THC, UPR, WTL 


QKO. 




ACS, 


PFN, PFZ. 


ACS, 


HN, KPS, MON, PCC, PTT, RCI 


ACS, 


EK. 


KF. 




EVN, 


HAB. 


EVN. 




EVN. 




DUP, 


RH. 


EK, 


PAS. 


UCC. 




EKT. 




ENJ. 




ENJ. 




ENJ. 




ENJ. 




mia, 


GIV. 


HMY. 




SM. 




HK. 




HMY. 




GAP. 




ACS, 


MAL, PFZ, SFI. 


GAP, 


OPC, PD. 


OTL. 




PIC. 




PIC. 




FMB, 


UCC. 


WTL. 




RH. 




SKG. 




CEL, 


CCW, EKT, UCC. 


EKT, 


UCC. 


ABB, 


EK. 


RH, 


WTH. 


UCC. 




ACS, 


BKC. 


ACS. 




BKC. 




ACY. 




EK, 


EVN. 


EVN. 




EVN. 




EVN. 




DOW. 




EK. 




EK, 


PIC. 


ARC, 


UCC. 


ABB, 


ALD, CCW, EK, KF, PD, PIC, 



ACY, UCC. 

MAL. 

ACS, BKC, MAL, WSN. 

ACS, BKC, MAL. 

MAL, SHP. 

ACS, BKC, ENJ, MAL. 

ACY. 

BKC, HSH, SHP. 

ACS, BKC, SHP, UCC. 

CCW, X. 



MISCEllANEOUS CHEMICALS 



179 



TABLE 21B. Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i 967- -Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAI£, ACYCLIC— Continued 
Salts of Organic Acids — Continued 

*Acetic acid salts — Continued 

Lead acetate 

Lead subaoetate 

Lead tetraacetate 

Magnesium acetate 

Manganese acetate 

Mercuric acetate 

Methylmercury acetate 

Nickel acetate 

Potassium acetate 

Silver acetate 

»Sodium acetate 

Sodium diacetate 

Strontium acetate 

Uranyl acetate 

»Zinc acetate 

*Zirconiura acetate 

Adipic acid, ammonium salt 

Chloroacetic acid, sodium salt 

Chlorohydroxylactic acid, aluminum, sodium salt 

Citric acid salts: 

Ammonium citrate 

Calcium citrate 

Ferric ammonium citrate 

Ferric citrate 

Ferrous calcium citrate 

Potassium citrate 

Sodium citrate 

Cottonseed oil acids, calcium salt 

»2-Ethylhexanoic acid (i-Ethylcaproic acid) salts: 

Aluminum 2-ethylhexanoate 

Barium 2-ethylhexanoate 

Cadmium 2-ethylhexanoate 

*Calcium 2-ethylhexanoate 

»Cobalt 2-ethylhexanoate 

Cobalt lead manganese 2-ethylhexanoate 

Copper 2-ethylhexanoate 

Dibutyltin di-2-ethylhexanoate 

Iron 2-ethylhexanoate 

*Lead 2-ethylhexanoate 

Lithium 2-ethylhexanoate 

<<Manganese 2-ethylhexanoate 

Nickel 2-ethylhexanoate 

Potassium 2-ethylhexanoate 

Rare earths 2-ethylhexanoate 

Stannous 2-ethylhexanoate 

Strontium 2-ethylhexanoate 

»Zinc 2-ethylhexanoate 

Zirconium 2-ethylhexanoate 

»Formic acid salts : 

Aluminum formate 

Ammonium formate 

Calcium formate 

Chromic formate 

Copper formate 

Lead formate 

Nickel formate 

Potassium formate 

Sodium formate, refined 

Sodium formate, tech 

Fumaric acid, lead salt 

Gluooheptonic acid salts: 

Sodium glucoheptonate 

Zinc glucoheptonate 

Gluconic acid salts: 

Ammonium gluconate 

»Sodium gluconate 



BKC, 
ACS, 
ARA, 
ACS, 
HSH, 
MAL. 
DUP. 
BKC, 
ACS, 
MAL. 
ACS, 
UCC. 
BKC. 
BKC. 
ACS, 
HSH, 
FIS. 
DOW. 
REH. 



MAL, PFZ. 
PFZ. 
PFZ. 
MAL. 

BKL, MAL. 
MLS, PFZ. 
MLS, PFZ. 
PD. 



MAI., SW. 
BKC, MAL. 
UCC. 
BKC. 
SHP. 



HSH, SHP. 

BKC, CWL, MAL, UCC, WSN. 

BKC, CEL, DAN, EKT, MAL, UCC, WSN. 



BKC, HSH, MAL, SHP, SNW, UCC. 
NTL, SNW, TZC. 



EK, 

CCA. 

CCA. 

CCA, 

CCA, 

MCI. 

CCA, 

X. 

CCA, 
CCA, 
SRR. 
CCA, 
MCI. 
CCA, 
CCA. 

tnc. 

CCA. 
CCA, 
CCA, 



WTC. 



CCC, FER, HNX, HSH, MCI, SRR, SW, WTC. 

CCC, FER, HNX, HSH, MCI, MLD, SRR, SW, TRO, WTC. 

SRR. 

MCI, SRR. 

CCC, HNX, HSH, MCI, SRR, SW, TRO, WTC. 

HNX, MCI, MLD, WTC. 

SRR. 



HNX, HSH, MCI, SRR. 
HNX, WTC. 



UCC, WSN. 

ACS, WSN. 

CCW, TRJ. 

GAF. 

CTN. 

NTL. 

HSH. 

CFC. 

ACS, BKC. 

CCW, HPC, TRJ. 

NTL. 

IBI. 
PFN. 

PFZ. 

CWL, DLI, IBI, PFZ, HIP. 



180 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 7967 --Continued 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 
Salts of Organic 4ci(is--Continued 

Glycolic acid salts: 

Alumnum glycolate 

Sodium glycolate 

9H-Hexadecafluorononanoio acid, ammonium salt 

Humic acids, sodium salts 

Isoascorbic acid, sodium salt 

Lactic acid salts; 

Aluminur. sodium lactate 

Ammonium lactate 

Calcium lactate 

Other 

Laurie acid, dibutyltin salt 

^Linoleic acid salts: 

Calcium linoleate 

Cobalt linoleate 

Copper linoleate 

Lead linoleate 

Lead manganese linoleate 

Manganese linoleate 

Male.TC acid salts: 

Dibutyltin maleate 

Lead (tribasic) maleate 

Malonic acid, calcium salt 

»Mercaptoacetic acid (Thioglyoolio acid) salts: 

Ammonium mercaptoacetate 

Antimony mercaptoacetate 

Calcium mercaptoacetate 

Dibutyltin mercaptoacetate 

Potassium mercaptoacetate ■ 

Sodium mercaptoacetate 

Mercaptopropionic acid, dibutyltin salt 

Methylsuccinic acid, disodium salt 

Myristic acid, lithium salt 

Neodecanoic acid salts: 

Cadmium neodecanoate 

Calcium neodecanoate 

Cobalt neodecanoate 

Lead neodecanoate 

Lithium neodecanoate 

Zinc neodecanoate 

Other 

Octanoic acid (Caprylic acid) salts: 

Aluminum octanoate 

Stannous octanoate 

Zinc octanoate 

»01eic acid salts: 

Aluminum oleate 

Ammonium oleate 

Barium zinc oleate 

Chromium oleate 

Copper oleate 

Lead oleate 

Stannous oleate 

Oxalic acid salts: 

Ammonium oxalate 

Copper oxalate 

Ferric ammonium oxalate 

Ferric oxalate 

Ferrous oxalate 

Potassium binoxalate 

Potassium oxalate 

Sodium oxalate 

Palmitic acid salts : 

* Aluminum palmitate 

Zinc palmitate 



CIB. 






CFC, 


MED. 




ARC, 


DUP. 




NLC. 






BAX, 


MRK, 


PFZ 


TZC. 






TCC. 






SHF. 






REH. 






CCA, 


X. 




CCA, 


SHP, 


SRR 


HSH, 


SHP, 


SRR 


SHP, 


WTC. 




SHP, 


SRR. 




SDH, 


aic. 




SHP. 






CCA, 


X. 




NTL. 






GIV. 






EVN, 


HAB, 


TNI 


CCA. 






EVN. 






CCA. 






EVN. 






EVN, 


MED. 




CCA. 






SDW. 






CCW. 






CCA. 






CCA, 


MCI. 




MCI. 






CCA, 


MCI. 




CCA, 
MCI. 


MCI. 




ARC, 


DA. 




CCW, 


X. 




BKC. 






WTC. 






BCN. 






WTC. 






SHP. 






MLD, 


SHP, 


WTC 


SHP. 






CCW, 


X. 




ACS, 


BKC, 


PFZ 


CFC. 






PFZ. 






PFZ. 






BKL. 






BKC. 






BKC, 


PFZ. 




BKC, 


MAL, 


SFI 


ACY, 


DA, 


WTC. 


ACY, 


DA, 


WTC. 



MISCELLANEOUS CHEMICALS 



181 



TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i567--Continued 



Chemical 



MISCELLANEOUS CHJMICA15, ACYCLIC— Continued 

Salts of Organic .4cids--Continue<i 

Phosphorodlthlolc add salts { Dithiophosphates ) : 

Potassium dihexyl phosphorodithioate 

Sodium di-seo-butyl diethyl phosphorodithioate 

Sodium di-seo-butyl phosphorodithioate 

Sodium diethyl phosphorodithioate 

Sodium dihexyl phosphorodithioate 

Sodium diisopropyl phosphorodithioate 

Other 

»Polyacrylic: acid salts: 

Anmionium polyaorylate 

Sodium polyaorylate 

Polymethaorylic acid, sodium salt 

Propionic acid salts ; 

*f Calcium propionate 

*Sodium propionate 

Zinc propionate 

Ricinoleic acid salts: 

Calcium ricinoleate 

Lithium ricinoleate 

Sodium ethyl oxalacetate 

Sodium polypectate 

Sodium sorbitol borate 

Sorbic acid salts: 

Potassium sorbate 

Sodium sorbate 

»Steario acid salts: 
^Aluminum stearates: 

"Aluminum distearate 

♦Aluminum mpnostearate 

♦Aluminum tristearate 

Ammonium stearate 

Barium stearate 

Cadmium stearate 

♦Calcium stearate 

Cobalt stearate 

Copper stearate 

Ferric stearate 

Ferrous stearate 

Lead stearate 

Lead stearate, dibasic 

♦Lithium stearate 

♦Magnesium stearate 

Manganese stearate 

Nickel stearate 

Strontium stearate 

♦Zinc stearate 

All other 

Succinic acid, sodium salt 

Sugar acids, sodium salt 

Tartaric acid salts: 

Antimony potassium tartrate 

Calcium tartrate 

Potassium bitartrate 

Potassium sodium tartrate 

Sodium bitartrate 

Valeric acid, ammonium salt 

Xanthio acid salts: 

Potassium ethylxanthate 

Potassium hexylxanthate 

Potassium isopropylxanthate 

Potassium pentyLxanthate 

Potassium seo-pentylxanthate 

Sodium n-butylxanthate 

Sodium sec-butylxanthate 

Sodium ethylxanthate 



Manufacturers' identification codes 
(according to list in table 22) 



ACY. 








ACY. 








ACY. 








ACY. 








ACY. 








ACY. 








ACY. 








BFG. 








ALC, 


BFG, GRD 


JOR 


RH. 


GRD. 








HFT, 


PFZ, UCC 


WSN 




HFT, 


PFZ, UCC 


WSN 




BKC. 








BAC. 








BAC. 








FMP. 








SKG. 








APD. 








UCC. 








UCC. 








ACY, 


DA, JTC, 


MAL, 


NOC, 


DA, 


JTC, MAL, 


NOC, 


WTC. 


ACY, 


DA, MAL, 


NOC, 


PIN, 


DA, 


WTC. 






DA, 


NOC, PEN, 


SYP. 




DA, 


NOC, PEN, 


SYP, 


WTC. 


ACY, 


DA, HNX, 


JTC, 


MAL, 


mc. 








NOC, 


WTC. 






NOG, 


WTC. 






WTC. 








DA, 


NTL, WTC. 






NTL. 








DA, 


PEN, SYP, 


WTC. 




ACY, 


DA, JTC, 


MAL, 


NOC, 


NOC. 








NOC, 


WTC. 






MAL. 








ACI, 


ACY, BCN, 


CCA, 


DA, 


WTC. 






APD, 


NOC. 






MAL. 








PFN. 








PFZ. 








CFC. 








ATC. 








PFZ. 








PFZ. 








RSA. 








ACY, 


DOW. 






DOW. 








DOW. 








ACY, 


DOW. 






DOW. 








KCC. 








ACY, 


DOW. 






ACY, 


DOW. 







PEN, SYP, WTC. 



SYP. 



NOC, P0), SYP, WTC. 



PEN, SYP, WTC. 



HNX, JTC, MAL, NOC, PEN, SYP, 



182 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported identified by 

manufacturer, i567-- Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAIS, ACYCLIC — Continued 
Salts of Organic 4cic/s--Continued 

Xanthio acid salts — Continued 

Sodium isobutylxanthate 

Sodium isopropylxanthate 

All other salts of organic acids 

Aldehydes and Ketones 

*Acetaldehyde 

^Acetone: 

From cumene 

*From isopropyl alcohol 

Crther 

Acrolein (Acrylaldehyde) 

Aldol (Acetaldol) 

»2-Butanone (Methyl ethyl ketone) 

Butyr aldehyde 

*Chloral (Trichloroaoetaldehyde) 

5-Chloro-2-pentanone 

l-Chloro-l-penten-3-one (p-Chlorovinyl ethyl ketone) 

Chloro-2-propanone ( Chloroaoetone ) 

Croton aldehyde 

Dichloroacetaldehyde 

Dihydropseudoionone 

l,3-Dihydroxy-2-propanone (Dihydroxyacetone ) 

2-Ethylbutyraldehyde 

2-Ethylhexanal (a-Ethyloaproaldehyde) 

Ethylpropylacrolein 

»Formaldehyde (37^ by weight) 

Glutar aldehyde 

Glyoxal 

2-Heptanone (Methyl anyl ketone) 

Heptyl methyl ketone 

Hex aldehyde 

2, 5-Hexanedione ( Acetonylaoetone ) 

2-t^droxy-2-methyl-3-butanone 

*«V-}fydroxy-4-methyl-2-pentanone (Diaoetone alcohol )-- 

Isobutyraldehyde 

Isodecaldehyde, mixed isomers 

Isovalerone (Diisobutyl ketone) 

Lac tide (3,6-Dimettiyl-2, 5-p-dioxanedione) 

'i-Methoxy-ii-methyl-2-pentanone 

5-Methyl-2-hexanone (Methyl isoamyl ketone) 

Methyl nonyl ketone 

«4-Methyl-2-pentanone (Methyl isobutyl ketone) 

4-Methyl-3-penten-2-one (Mesityl oxide) 

Methylpseudoionone 

2-Methylvaleraldehyde (2-Methylpentaldehyde ) 

3-Octanone {Jmyl ethyl ketone) 

Paraformaldehyde 

Paraldehyde (Paracetaldehyde) 

2,'4-Pentanedione ( Acetylacetone ) 

3-Pentanone (Diethyl ketone) 

Propionaldehyde 

Pseudoionone 

Tetrahydropseudoionone 

2,6, 8-Trimethyi-"4-nonanone (Isobutyl heptyl ketone )- 

Valeraldehyde 

All other 

Alcohols. Monohydnc, Unsubstituted 

»Alcohols Cg or lower, unmixed: 

Allyl alcohol 

Anjrl alcohols ; 

2-Methyl-l-butanol 

2-Methyl-2-butanol (tert-Anyl alcohol) 



DOW. 

ACY, DOW. 

CCW, EK, RSA, SYP, x. 



CEL, CCM, DUP, EKT, EKX, HPC, MON, PUB, SHC, UCC. 

ACP, CLK, HPC, MON, SHC, SKO, SOC, UCC. 

EKT, ENJ, SHC, UCC. 

CEL, DIX, HPC. 

SHC, UCC. 

UCC. 

CEL, DIX, ENJ, SHC, SPI, UCC. 

CEL, EKX, UCC. 

DA, FMB, GGY, MTO. 

SDW. 

ABB. 

EK. 

CEL, EKT, UCC. 

FMB. 

GIV. 

BAX. 

UCC. 

EKT, EKX, UCC. 

UCC. 

ACN, ACP, BOR, CBC, CEL, COM, DUP, GAF, GOC, HKD, 

HN, HPC, MON, RCI, RH, TRJ, UCC. 
UCC. 
UCC. 
UCC. 
ARC. 
GIV. 

ACI, RBC, UCC. 
LIL. 

CEL, SHC, UCC. 
EKX, UCC. 
UCC. 

EKT, UCC. 
CLN. 
SHC. 

EKT, UCC. 
ARC. 

EKT, ENJ, SHC, UCC. 
SHC, UCC. 
GIV. 
UCC. 
SHC. 

CEL, HN. 
ARC, UCC. 
UCC. 
DUP. 

EKX, UCC. 
GIV. 
GIV. 
UCC. 
UCC. 
CEL, CLE, EK, MLS, PIC, UCC. 



DOW, SHC. 

UCC. 
SHC. 



MISCELLANEOUS CHEMICALS 



183 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers ' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

Alcohols, \hnohydric, Unsubstltuted — Continued 

^Alcohols Cg or lower, unmixed — Continued 
An^l alcohols--Continued 

1-Pentanol 

2-Pentanol 

Butyl alcohols : 
Rrirnary: 

*Iso ( Isopropylcarbinol ) 

*Normal (n-Propyloarbinol) 

Secondary (Methylethylcarbinol ) 

Tertiary (Trimethylcarbinol) 

2, 6-Dimethyl-4-heptanol (Diisobutylcarbinol) 

»Ethyl alcohol, synthetic 

2-Ethyl-l-butanol 

»2-Ethyl-l-hexanol 

2-Ethyl-4-methyl-l-pentanol 

4-Etlorl-l-octyn-3-ol 

Heptyl alcohol 

»Hexyl alcohol 

*Hexynol 

»Iso-octyl alcohols 

»Isopropyl alcohol 

»Methanol, synthetic 

2-Methyl-3-buten-2-ol 

2-Methyl-3-butyn-2-ol 

'4--Wethyl-2-pentanol (l-Methylisobutylcarbinol) 

3-Methyl-l-pentyn-3-ol (Methylparafynol ) 

»1-Ootanol 

»2-0otanol (seo-Capryl alcohol) 

Octanols, other 

Propyl alcohol (Propanol) 

2-Propyn-l-ol 

All other 

*Alcohols Cio or higher, unmixed: 

»Decyl alcohols 

3,9-Diethyl-6-tridecanol 

Dodecyl alcohol (Lauryl alcohol) {95'f>j 

7-Ethyl-2-methyl-4-hendecanol 

»l-Hexadecanol (Cetyl alcohol) (955t) 

Hexadecyl alcohols 

1-Octadecanol (Stearyl alcohol) (95^) 

cis-9-Octadecen-l-ol (Oleyl alcohol) 

Tetradecyl alcohols 

1-Tridecanol 

2,6,3-Trimethyl-<i-nonanol 

^Mixtures of alcohols: 

»C9 and lower only: 

An^rl alcohols 

Other 

»Cio and higher only 

»C6 to Cj^j and others 

Pfilyhydric Alcohols and Their E'iters and Ethers 

»Polyhydric alcohols : 

l,4--Butanediol 

l,2(and l,3)-Butanediol ( Butylene glycol ) 

1,2,4-Butanetriol 

2-Butene-l,4-diol 

2-Butyne-l,"i-diol 

3-Chloro-l,2-propanediol (Glycerol a-chlorohydrin)- 

1,10-Decanediol 

2, 5-Dimethyl-2, 5-hexanediol 

2,5-Dimethyl-3-hexyne-2,5-diol 

2,2-Dimethyl-l,3-propanedlol (Neopentyl glycol) 

»Ethylene glycol 



UCC. 
UCC. 



DBC, EKX, ENJ, SHC, UCC. 

CEL, CO, DBC, EKX, ENJ, SHC, UCC. 

ENJ, SHC. 

SHC. 

UCC. 

CEL, DUP, EKX, ENJ, HPC, SHC, UCC, USI. 

UCC. 

CEL, EKX, ENJ, SHC, UCC. 

EKX. 

cue. 

EKX. 

CO, EKX, ENJ, PG, UCC. 
cue, LIL, X. 

ENJ, GOC, HOU, PCC, TID, UCC. 
ENJ, SHC, UCC. 

ACN, BOR, CEL, CCM, DUP, ENJ, ESC, GOC, HN, HPC, MON, 
RH, TCC, UCC. 

cue. 
cue. 

SHC, UCC. 

cue. 

CO, DUP. 

RH, WTH. 

EKX, IFF. 

CEL, EKX, UCC. 

GAF. 

cue, EK, GOC, GYR, LIL, UCC. 

CO, DUP, ENJ, GOC, HOU, PCC, TID, TNA, UCC. 

GOC, UCC. 

CO, DUP, PG, RH. 

UCC. 

ASH, CO, DUP, GIV, RH. 

ENJ, PG. 

ASH, CO, DUP, PG, RH. 

ASH, DUP. 

CO, PG. 

ENJ, HOU, TID. 

UCC. 



ENJ, PUB, UCC. 

CEL, EKX, ENJ, GOC. 

ASH, CO, ENJ, GOC, PG, RH, SHC, TNA, VPC. 

CO, EKX, GOC, PG, TNA. 



GAF. 
CEL. 
GAF, 
GAF. 
GAF. 
EVN, 
NEP. 

cue. 
cue. 

EKX. 
ACP, 
CMC, 



NEP. 



OTC. 



APD, CAU, CEL, DOW, DUP, EKX, GAF, HCH, JCC, 
, SHC, UCC, WYN. 



184 



SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, 1967 — Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



KaSCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Polyhydric Alcohols andTheir Esters and Ether s--Continued 

■»Polyhydric alcohols — Continued 

2-Ethyl-l,3-hexanediol 

2-Ethyl-2-(hydroxymethyl)-l, 3-propanediol (Trimethylol- 

propane ) . 

Glycerol, synthetic 

1, 6-Hexanediol 

2- ([t'droxyraethyl)-2-methyl-l, 3-propanediol (Trimethyl- 

olethane) . 

Mannitol 

3-Mercapto-l,2-propanediol (Thioglycerol ) 

Methylglycerol 

2-Methyl-2,'4-pentanediol (Hexylene glycol) 

2-Me thy 1-2-propyl-l, 3-propanediol 

1,9-Nonanediol 

»Pentaerythritol 

^Propylene glycol (1,2-Propanediol) 

^-Sorbitol 

2,2,'i-Trimethyl-l,3-pentanediol 

All other 

*Polyhydric alcohol esters : 

1,3-Butanediol dimethacrylate 

2-(2-Butoxyethoxy )ethyl acetate 

2-Butoxyethyl acetate 

Diethylene glycol chloroforraate 

2-(2-Ethoxyethoxy )ethyl acetate 

2-Ethoxyethyl acetate 

Ethylene glycol diacetate 

Ethylene glycol dimercaptoacetate 

Ethylene glycol dimethacrylate 

Ethylene glycol glycolate 

2-Ethyl-2(hydroxymethyl )-l, 3-propanediol trimethacrylate 

Glyceryl monoacetate (Monoacetin) 

Glyceryl triacetate (Triacetin) 

Glyceryl trioleate 

Glycol adipate 

Hexylene glycol diacetate 

Hydroxyethyl carbonate 

Hydroxyethyl methacrylate 

ftydroxypropyl methacrylate 

Hydroxypivalyl hydroxypivalate 

2-Kethoxyetl^l acetate 

Methoxytriethyleneglycol acetate 

Pentaerythritol caprylate 

Pentaerythritol pelargonate 

Polyethylene glycol dimethacrylate 

Sucrose octa-aoetate 

Tetraethylene glycol dimethacrylate 

Tri(hexylene glycol) biborate 

2,2,4-Trimethyl-l,3-pentanediol monoisobutyrate 

All other 

*Polyhydric alcohol ethers: 

3-( Allyloxy )-l,2-propanediol (Allyl glyceryl ether) 

Bis(2-butoxyethyl) ether (Diethylene glycol di-n-butyl 

ether ) . 
Bis(2-ethoxyethyl) ether (Diethylene glycol di- 
ethyl ether). 

Bis (hydroxyethyl) ether butynediol 

Bis[2-(2-methoxyethoxy)ethyl] ether (Tetraethylene 

glycol dimethyl ether). 
Bis(2-methoxyethyl) ether (Diethylene glycol dimethyl 

ether). 

»2-Butoxyethanol (Ethylene glycol monobutyl ether) 

2-(2-Biitoxyethoxy)ethanol (Diethylene glycol monobutyl 

ether ) . 
2-[2-(2-Butoxyethoxy )ethoxy]ethanol (Triethylene glycol 

monobutyl ether). 
l-Butoxyethoxy-2-propanol 



UCC. 
CEL. 

APD, DOW, SHC. 
CEL, UCC. 
COM, TRJ. 



APD. 
EVN. 
APD. 
CEL, 
ABB, 
ASH. 
CEL, 
APD, 
APD, 
EKX. 
GAF, 



SHC, UCC. 

BKl, ICO. 

COM, HN, HPC, RCI, TRJ. 

CEL, DOW, DUP, JCC, CMC, UCC, WYN. 

BRD, MRK, PFZ. 

PHR, UCC, x. 



SAR. 

EKT, UCC. 

UCC. 

PPG. 

EKT, UCC. 

DOW, EKT, EN J, UCC. 

EKT, UCC. 

EVN. 

SAR. 

CCA. 

SAR. 

HAL. 

EKT, UCC. 

GRO. 

X. 

UCC. 

JCC. 

AAC. 

JCC. 

EKX. 

UCC. 

RBC. 

DRW. 

DRW. 

SAR. 

PD. 

SAR. 

USB. 

EKX. 

EK, am, GLY, SAR. 

SHC. 
UCC. 

UCC. 



GAF. 
ASL. 

ASL, CMC. 

DOW, JCC, CMC, SHC, UCC. 
DOW, SHC, UCC. 

DOW, CMC, UCC. 

UCC. 



MISCELLANEOUS CHEMICALS 



185 



TABLE 21B. 



--Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, iS67--Continued 



Chemical 



Manufacturers' Identification codes 
(according to list in table 22) 



MISCELLANEOUS CHIMICA15, ACYCLIC— Continued 

Polyhydric Alcohols and Their Esters and Ethers —Continued 

«Polyhydric alcohol ethers — Continued 

»Dlethylene glycol 

Dimethoxyethane (Ethylene glycol dimethyl ether) 

»Dipropylene glycol 

»2-Ethoxyethanol (Ethylene glycol monoethyl ether) 

»2-(2-Ethoxyethoxy )ethanol (Diethylene glycol monoethyl 

ether ) . 
»2-[2-(2-Ethoxyethoxy)ethoxy]ethanol (Triethylene glycol 
monoethyl ether). 

2-[2-(Hexyloxy )ethoxy]ethanol 

Isobutoxyethanol 

l-Isobutoxy-2-propanol (Propylene glycol isobutyl 
ether ) . 

»2-Methoxyethanol (Ethylene glycol monomethyl ether) 

»2-(2-Methoxyethoxy)ethanol (Diethylene glycol mono- 
methyl ether). 
2-[ 2-(2-Methoxyethoxy )ethoxy]ethanol (Triethylene 

glycol monomethyl ether). 
2-(2-Methoxyethoxy )ethyl 2-methoxyethyl ether (Tri- 
ethylene glycol dimethyl ether). 

Methoxypolyethylene glycol 

l-Methoxy-2-propanol 

3-(3-Methoxypropoxy )propanol 

3-[3-(3-Methoxypropoxy )propoxy]propanol 

Polybutylene glycol 

Polyethoxyethylglycerol 

Polyethoxyethylsorbitol 

^Polyethylene glycol 

*Polypropoxy ethers : 

*Glycerol tri(polyoxypropylene) ether 

Other 

"Polypropylene glycol 

Polytetramethylene ether glycol 

Tetraethylene glycol 

1,1,3,3-Tetramethoxypropane 

2,2'-Thiodiethanol ( Thiodiglyool ) 

"Triethylene glycol 

Tripropylene glycol 

All other 

Esters of Monohydric Alcohols 

Allyl methacrylate 

An^yl acetates, 905t: 

Isopentyl acetate ( Isoan^l acetate) 

Mixed 

»Butyl acetates: 

Iso 

"Normal 

Secondary 

Mixed 

"Butyl acrylate 

Butyl chloroacetate 

Butyl formate 

Butyl lactate 

Butyl maleate, mono- 

tert-Butyl peroxyacetate 

tert-Butyl peroxy-2-ethylhexanoate 

tert-Butyl peroxyisobutyrate 

tert-Butyl peroxyisopropylcarbonate 

tert-Butyl peroxypivalate 

Cetyl lactate 

Diallyl maleate 

"Dibutyl fujuarate 

"Dibutyl maleate 



ACP, CAU, DOW, EKX, GAF, HCH, JCC, *IC, SHC, UCC, 

Win. 
ASL. 

CEL, DOW, JCC, CMC, UCC, WYN. 

DOW, JCC, CMC, UCC. 

DOW, JCC, CMC, UCC. 

DOW, JCC, CMC, UCC. 

UCC. 

UCC. 
DOW. 

DOW, HCH, JCC, CMC, UCC. 

DOW, JCC, CMC, UCC. 

DOW, CMC, UCC. 

ASL. 

UCC. 

DOW, UCC. 

DOW, UCC. 

DOW. 

NLC. 

GLY. 

APD, GLY, TCH. 

ACP, DOW, DUP, GAF, HDG, JCC, NLC, C*1C, UCC, WYN. 

JCC, QMC, UCC, WYN. 

ACS, APD, JCC, UCC, WYN. 

DOW, HDG, JCC, NLC, QMC, UCC, WYN. 

QKO, X. 

DOW, UCC. 

KF. 

PIC, UCC. 

ACP, CAU, DOW, GAF, HCH, JCC, CMC, UCC. 

DOW, UCC. 

DOW, EKX, NLC, UCC, 'VYN. 



SAR. 



NW. 










PFW, 


PUB, 


UCC. 






EKT, 


PUB, 


UCC. 






CEL, 


EKT, 


ENJ, PUB, 


SHC, 


UCC 


ENJ, 


HPC, 


PUB, SHC. 






CEL. 










CEL, 


DBC, 


RH, UCC. 






MON. 










BJL. 










COM. 










PCC. 










WTL. 










OTL. 










WTL. 










PPG, 


OTL. 








WTL. 










VND. 










FMP. 










MON, 


PFZ, 


RCI, RUB. 






cue. 


DUP, 


MON, PCC, 


RCI, 


RUB 



186 



SYNTHETIC ORGANIC CHEMICALS. 1967 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, J967--Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Esters of Monohydnc -1 / coho /s- -Cont itiued 

Diethyl sec-butylethylmalonate 

Diethyl butylmalonate 

Diethyl sec-butyljnalonate 

Diethyl carbonate (Ethyl carbonate) 

Diethyl diethylmalonate (Diethyl malonic ester) 

Diethyl (ethoxyiiiethylene)malonate 

Diethyl ethylisopentylmalonate 

Diethyl ethylmalonate (Ethyl malonic ester) 

Dietl^l etl^rl(l-methylbutyl)malonate (Ethyl 1-methyl 
butyl malonic ester). 

Diethyl ethyl (l-methylpropyl )malonate 

Di(2-ethyl-l-hexyl) fumarate 

Di(2-etl^l-l-hexyl) maleate 

Diethyl maleate 

Diethyl malonate (Malonic ester) 

Diethyl methoxymethylene malonate 

Diethyl (l-methylbutyl )malonate 

Diethyl methylmalonate 

Diethyl ( l-methylpropyl )malonate 

Diethyl oxalate (Ethyl oxalate) 

Diisobutyl maleate 

Di-iso-nonyl maleate 

Diisopropyl peroxydicarbonate (Isopropyl percarbonate)- 

*Dilauryl 3,3'-thiodipropionate 

Dimethyl aoetylenedicarboxylate 

2,5-Dimethylhexane 2, 5-diperoctoate 

Dimethyl maleate 

Dimethyl malonate 

Di(4-methyl-2-pentyl) maleate 

Dioctyl fumarate 

*Dioctyl maleate 

*Distearyl 3j3'-thiodipropionate 

Dithiobis(stearyl propionate) 

Ditridecyl maleate 

Di(tridecyl ) 3,3' -thiodipropionate 

*Ethyl acetate (85^) 

Ethyl acetoacetate 

*Ethyl acrylate 

*Ethyl chloroacetate 

Ethyl chloroformate 

Ethylene carbonate 

Ethyl formate 

2-Ethyl-l-hexyl acetate 

2-Ethyl-l-hexyl acrylate 

2-Ethyl-l-hexyl methaorylate 

Ethylidene diacetate 

Ethyl propionate 

Ethyl silicate (Tetraethoxysilane) 

Ethyl sulfate (Diethyl sulfate) 

Etl^l thioglycolate 

Fatty acid esters, not included with plasticizers or 
surface-active agents: 

Dimethyl brassylate 

Ethyl stearate 

Hexadecyl stearate 

Isopropyl linoleate 

Methyl esters of coconut oil 

Methyl esters of cottonseed oil 

^(Methyl esters of tallow 

Methyl 12-hydroxystearate 

Methyl laurate 

Methyl inyristate 

Methyl stearate 

^^istyl n^rristate 

All other 

Hexyl acetate 

n-Hexyl formate 

»Isobutyl acrylate 



ABB. 






BPC. 






ABB. 






CTN, 


FMP. 




BPC, 


LIL. 




KF. 






LIL. 






LIL. 






ABB. 






BPC. 






RUB. 






RUB. 






ACY, 


UCC. 




ABB, 


KF, LIL. 




KF. 






ABB. 






BPC. 






BPC. 






FMP. 






RUB. 






RUB. 






PPG, 


WTL. 




ACX, 


CCW, EVN, HAB. 




EK. 






UPR. 






AAC. 






KF. 






RUB. 






RCI. 






HRT, 


MON, PCC, RCI. 




ACY, 


CCW, EVN, HAB. 




EVN. 






RUB. 






ACY, 


EVN. 




CEL, 


EKT, ENJ, HPC, MON, 


PUB, UCC 


EKT, 


UCC. 




CEL, 


DBC, RH, UCC. 




DOW, 


KF, MON. 




CTN, 


FMP. 




JCC. 






CCM. 






EKT, 


UCC. 




CEL, 


DBC, UCC. 




X. 






CEL. 






NW. 






MTR. 






UCC. 






EVN. 






am. 






ICO. 






ICI. 






VND. 






PG. 






BFR. 






BFR, 


CHL, HUM. 




BAG, 


HUM. 




PG. 






PG. 






PG, 


SUG. 




VND. 






ftlR, 


ICI, SNW, SUG. 




ENJ. 






EK. 






DBC, 


RH, UCC. 





MISCELLANEOUS CHEMICALS 



187 



TABLE 21B. 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer , ;967--Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHENQCALS, ACYCLIC— Continued 

E&tfrs of Monohydnr 4 /co/io ?s--ront iniu'd 

Isobutyl isobutyrate 

Isodecyl aorylate 

*Iso-octyl meroaptoacetate 

Iso-octyl 3-mercaptopropionate 

»Isopropyl acetate 

Isopropyl chloroformate 

Lauryl lactate 

Kethallylidene diaoetate 

Methyl acetate 

Methyl acetoaoetate 

Methyl acrylate, monomer 

Methyl borate 

Methyl chloroacetate 

Methyl diohloroacetate 

Methyl formate 

*Methyl methacrylate, monomer 

'i-Methyl-2-pentyl acetate 

Methyl sulfate (Dimethyl sulfate) 

Methyl thloglycolate 

Methyl vinyl acetate 

Kyristyl lactate 

Octadecyl 3-raercaptopropionate 

^Phosphorus acid esters: 

Bis(2-ethylhexyl ) hydrogen phosphate 

Butyl phosphates 

Chloropropyl phosphorothioate 

Dlbutyl butylphosphonate 

Dibutyl hydrogen phosphite 

Didodecyl hydrogen phosphate 

Diethyl phosphorochloridothionate 

Dimethyl raethylphosphonate 

Dimethyl phosphorochloridothionate 

Iso-octyl phosphate 

Methyl phosphates 

Tributyl phosphate 

Tributyl phosphite 

Tridecyl phosphite 

Triethyl phosphite 

Triiso-octyl phosphite 

Trimethyl phosphate 

Trimethyl phosphite 

Trioctyl phosphite 

Tris(2-ohloroethyl) phosphite 

Trls(2,3-dibromopropyl) phosphate 

Tris(2-ethylhexyl) phosphite 

Tris( octadecyl) phosphite 

All other 

Propyl acetate 

Propylene carbonate 

Tetraoctyl orthosilicate 

Titanic acid esters: 

Tetrabutyl titanate 

Tetraisopropyl titanate 

Tetrakis(2-ethylhexyl) titanate 

Crther 

Triethyl borate 

Triethyl orthoacetate 

Triethyl orthoformate 

Triethyl orthopropionate 

Tri isodecyl orthoformate 

Trimethyl orthoformate 

»Vlnyl acetate, monomer 

All other— 

lialo^pnnt I'd hydrocarbons 

1-Bromobutane (n-Butyl bromide) 

2-Bromobutane (sec-Butyl bromide) 



EKX. 






UCC. 






CCW, 


EVN, HAB. 




EVN. 






EKT, 


ENJ, HPC, UCC. 




CTN, 


OTC, PPG. 




VND. 






UCC. 






EK, 


MON, UCC. 




EKT, 


UCC. 




CEL, 


DBC, RH. 




CAL, 


MHI, SFA. 




DOW, 


KF. 




KF, 


PD. 




DUP. 






ACY, 


DUP, RH. 




PUB, 


SHC, UCC. 




DUP. 






EVN. 






UCC. 






VND. 






EVN. 






SM, 


UCC. 




SM. 






TNA. 






SM. 






SM. 






DUP. 






SF. 






SM. 






SF. 






SM. 






HK, 


SM. 




COM. 






SFI, 


SM. 




HK. 






SM. 






SM. 






TNA. 






SM. 






HK. 






SM. 






MCH. 






SM. 






SM. 






DUP, 


EK, MON, SFA, SM. 




CEL, 


EKT, PUB, UCC. 




DOW, 


JCC. 




MON. 






DUP. 






DUP. 






DUP. 






DUP. 






USB. 






EK, 


KF. 




KF. 






KF. 






KF. 






KF. 






BOR, 


CEL, cue, DUP, MON, NSC, UCC. 




ALD, 


ARG, CEL, CTN, DUP, EK, FMP, PIC, PCC, 


RH, RSA, 


TNI, UCC, WTL. 




ABB, 


BPC, MCH. 




ABB, 


BPC, EK. 





SYNTHETIC ORGANIC CHEMICALS, 1967 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i 967- -Continued 



Chemical 



Manufacturers ' identification codes 

(according to list in table 22) 



MISCELLANEOUS CHIMICAI^, ACYCLIC— Continued 
Halogenated Hydrocarbons- -Continued 

Bromochloromethane 

l-Bromo-3-chloropropane (Trimethylenechlorobromide)-- 

2-Bronio-2-ohloro-l, 1, 1-trlf luoroethane 

1-Broraododecane 

Bromoethane (Ethyl bromide) 

l-Bromo-3-methylbutane ( Isoanyl bromide) 

1-Bromo-octadecane 

l-Bromopentane (n-Anyl bromide) 

*2-BroniDpentane (l-Methylbutyl bromide) 

l-Bromopropane (n-Propyl bromide) 

2-Broraopropane (Isopropyl bromide) 

3-Bromopropene (Allyl bromide) 

Bromotrlchlororaethane 

Bromotrifluorome thane 

»Carbon tetrachloride 

^Chlorinated paraffins : 

35^6456 chlorine 

65?t or more chlorine 

l-Chlorobutane (n-Butyl chloride) 

2-Chlorobutane (sec-Butyl chloride) 

l-Chloro-l,l-dif luoroethane 

^Chlorodif luoromethane 

*Chloroethane (Ethyl chloride) 

»Chloroform 

*Chloromethane (Methyl chloride) 

2-Chloro-2-methylpropane (tert-Butyl chloride) 

3-Chloro-2-methylpropene (Methallyl chloride) 

Chloropentaf luoroethane 

3-Chloropropene (Allyl chloride) 

Chlorotrifluoroethylene (Trif luorovinyl chloride) 

Chlorotrif luoroethylene, polymerized 

Chlorotrlfluorome thane 

l,2-Dibromo-l,l-dichloroethaiie 

Dibromodlfluorome thane 

1,2-Dibronioethane (Ethylene dibromide) 

Dibromoethane (Methylene bromide) 

1,4-Dibromopentane 

1,2-Dibromo- 1,1, 2, 2-tetraf luoroethane 

Dichlorobutadiene 

l,'+-Dichlorobutene 

*Dlchlorodlfluoromethane 

*1,2-Diohloroethane (Ethylene dichloride) 

*Dlchloromethane (Methylene chloride) 

*l,2-Dichloropropane (Propylene dichloride) 

2,3-Dichloropropene 

*Dlchlorotetraf luoroethane 

1, l-Dlf luoroethane 

Dif luorotetrachloroethane 

Diiodomethane (Methylene iodide) 

Hexachloroethane 

Hexaf luoropropylene, monomer 

lodoethane (Ethyl iodide), tech 

*Iodomethane (Methyl iodide) 

1-Iodoperfluorohexane 

Lauryl chlorides 

Octaf luorocyclobutane 

Tetrabromoethane 

1,1,2,2-Tetrabromoethane (Acetylene tetrabromlde ) 

1,1,2,2-Tetrachloroethane (Acetylene tetrachloride)-- 

»Tetrachloroethylene ( Perohloroethylene ) 

Tetraf luoroethylene, monomer 

Tetraf luoroethylene, polymer 

Tetraf luorome thane 

»l,l,l-Trichloroethane (Methyl chloroform) 

1, 1, 2-'rrichloroethaiie (Vinyl trichloride) 

»Triohloroethylene 



DOW. 






DOW, 


MCH. 




ICI. 






DUP, 


GAF. 




DOW, 


MCH. 




LIL. 






DUP, 


GAF. 




BPC. 






ABB, 


LIL, PD. 




BPC, 


EK. 




BPC. 






DOW. 






MCH. 






DUP. 






ACS, 


DA, DOW, FMB, FRO, PPG, SFI. 




CCH, 


DA, DVC, HK, HPC, ICI, KPS, NE7. 




DA, 


DVC, NEV. 




PUB, 


UCC. 




PLC, 


EK. 




ACS, 


DUP. 




ACS, 


DUP, KAI, PAS, UCC. 




AME, 


DOW, DUP, HPC, PPG, SHC, TNA. 




ACS, 


DA, DOW, DUP, FRO, SFI. 




ACS, 


ANM, CO, DCC, DOW, DUP, FRO, TNA, UCC. 




EK. 






FMP. 






DUP. 






DOW, 


SHC. 




ACQ, 


MMM. 




HK, 


MMM. 




DUP, 


PAS, UCC. 




DOW. 






DOW. 






DOW, 


EID, HCH, MCH. 




DOW. 






SDW. 






DUP. 






DUP. 






DUP. 






ACS, 


DUP, KAI, PAS, UCC. 




AME, 


BFG, DA, DOW, DUP, JCC, MON, CMC, PPG, TNA, UCC 


ACS, 


DA, DOW, DUP, FRO, SFI'. 




DOW, 


JCC, UCC. 




DOW, 


UCC. 




ACS, 


DUP, PAS, UCC. 




ACS, 


DUP. 




DUP, 


UCC. 




NTB, 


SDW. 




NES. 






DUP. 






CLB, 


EK, FMT. 




CLB, 


EK, FMT, RSA. 




BRD. 






DUP. 






DOW. 






DOW. 






DUP. 






DA, 


DOW, DUP, FRO, HK, PPG, SFI, TNA, TTX. 




DUP. 






DUP. 






DUP. 






DOW, 


PPG, TNA. 




DOW, 


TNA, UCC. 




DOW, 


DUP, HK, PPG, TNA, TTX. 





MISCELLANEOUS CHEMICALS 



189 



TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by 

manufacturer, i 567- -Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 

Ihlogena t ed Hydrocarbons- - Con H nued 

»Triohlorofluoromethane 

1,2,3-Trichloropropane 

1,2,3-Trlchloropropene 

Triohlorotrifluoroethane 

*Vinyl chloride, monomer ( Chloroethylene ) 

Vinyl fluoride 

Vinylidene chloride, monomer (1,1-Dlchloroethylene) 

Vinylidene fluoride 

All other 

AU Other Miscellaneous Acyclic Chemicals 

Acetyl peroxide 

Alkyl sulfides, mixed 

Aluminum isopropoxide (Aluminum isopropylate ) 

*2-Butanone peroxide 

tert-Butyl hydroperoxide 

»tert-Butyl peroxide (Di-tert-butyl peroxide) 

Butyrolactone 

Caprolactone 

»Carbon disulfide 

2-Chloroethaiiol (Ethylene chlorohydrin ) 

l-Chloro-2-propanol 

*Decanoyl peroxide 

Dialdehyde starch 

Dichlorcpropanol 

l,3-Dichloro-2-propanol 

2,4-Dihydroxy-3,3-dimethylbutyric acid, gairanalactone 
( Pantolaotone ) . 

2,5-Dimethyl-2,5-di(tert-butylperoxy )hexane 

2,5-Dimethyl-2,5-di(tert-butylperoxy)hexyne-3 

Qjoxides, ethers, and acetals: 

Acetone dimethylaoetal (2,2-Dimethoxypropane) 

l-(Allyloxy)-2,3-epoxypropane (Allyl glycidyl ether)- 

Bis(2-chloroethoxy)methane (Dichloroethylformal) 

Bis(2-Chloroethyl) ether (Dichlorodiethyl ether) 

Bis(2-ohloro-l-methylethyl) ether (Dichloroisopropyl 
ether ) . 

l-Butoxy-2,3-epoxypropane (Butyl glycidyl ether) 

Butylene oxide 

Butyl ether (Di-n-butyl ether) 

Butyl vinyl ether 

2-Chloro-l,l-dimethoxyethane (Dimethyl chloracetal) — 

2-Chloroethyl vinyl ether 

Chloromethyl methyl ether 

2,2-Dichloro-l, 1-difluoroethyl methyl ether 

Qjichlorohydrin 

^Ethylene oxide 

*Ethyl ether; 

Absolute 

Tech 

U.S.P 

Ethyl vinyl ether 

Glycidol {2,3-E^oxy-l-propanol) 

Isobutyl vinyl ether 

*Isopropyl ether 

Methylal ( Dimethoxymethane ) 

»Metl^l ether (Dimethyl ether) 

Methyl vinyl ether 

^Propylene oxide 

Other 

Ethan edithiol 

Ethanethiol 

2-(Ethyljiiercapto)ethanol 

Fats and oils, chemically modified 

Gluoono-delta-lactone 



ACS, 


DUP, KAI, PAS, 


UCC. 


DOW, 


SHC. 




DOW. 






ACS, 


DUP, PAS, UCC. 




ACS, 


AME, BFG, cue. 


DA, DOW, GNT, GYR, HN, MNO, WON, 


PPG, TNA, UCC. 




X. 






DOW, 


TNA. 




X. 






CLE, 


DUP, EK, RSA, 


SDW. 


AZT, 


WTL. 




ORG. 






CHT. 






AZT, 


CAD, NOC, RCI, 


WTL. 


AZT, 


CAD, WTL. 




ARC, 


AZT, CAD, NOC, 


SHC, nh. 


GAP. 






UCC. 






ACS, 


FMB, PAS, PPG, 


SFI. 


OMC, 


UCC. 




RSA. 






CAD, 


UPR, OTL. 




MLS. 






ICO. 






EK. 






CKL, 


PD. 




WTL. 






WTL. 






DOW. 






SHC. 






TKL. 






DOW, 


UCC. 




DOW. 






DOW, 


SHC. 




DOW. 






UCC. 






UCC. 






LIL. 






UCC. 






HK, 


RH. 




DOW. 






DOW, 


SHC. 




ACP, 


CAU, DOW, EKX, 


GAF, HCH, JCC, CMC, SNO, UCC, WY 


MAL. 






ENJ, 


HPC, UCC, USI. 




MAL, 


QMS. 




GAF, 


UCC. 




DIX, 


OTC. 




GAF. 






ENJ, 


SHC, UCC. 




CEL. 






CCM, 


DUP, UCC. 




GAF, 


UCC. 




CEL, 


DOW, JCC, CMC, 


UCC, WYN. 


EK, 


HDG, UCC. 




RBC. 






EK. 






PAS, 


PLC. 




ABB, 


CHL, DCM, RT. 




DLI, 


PFZ. 





190 



SYNTHETIC ORGANIC CHEMICALS. 1967 



TABLE 21B. 



-Miscellaneous chemicals for which U.S. production or sales were reported, identified by 
manufacturer, 7.967- -Continued 



Chemical 



Manufacturers' identification codes 
(according to list in table 22) 



MISCELLANEOUS CHEMICAI^, ACYCLIC— Continued 

All Other Miscellaneous Acyclic Chemicals — Continued 

Glucoheptonolactone 

Glutaraldehyde bis(sodiuiii bisulfite) 

Hexaohlorodimethyl sulfone 

n-Hexadecyl disulfide 

f^drocarbons : 

1-Butyne { Ethylacetylene ) 

n-Dodecane 

Ethylene, from ethyl alcohol, medicinal grade 

Hexadecane 

Ivtyrcene 

1-Octadecene 

n-Ootane 

Propyne (Methylacetylene) 

Other 

*Lauroyl peroxide 

Magnesium methylate 

Methanesulfanol 

Methyl disulfide 

Methyl sulfide (Dimethyl sulfide) 

Methyl sulfoxide 

1-Octanethiol (n-Octyl meroaptan) 

Organo-aluminum compounds ; 

Ethylaluminum chlorides 

Isobutylaluminum chlorides 

Methylalumnuin chlorides 

Other 

Organo-boron compounds 

Qrgano-lead compounds ; 

»Tetraethyllead 

»Tetramethyllead 

»Tetra(methyl-ethyl)lead 

Organo-lithium compounds 

Organo-magnesiujn compounds 

Organo-mercury compounds 

Organo-silicon compounds: 

Monomers 

»Polymers 

Organo-tin compounds : 

Bis(tributyltin ) oxide 

Dibutylmethoxytin (Dibutyltin methoxide) 

Dibutyltin dichloride 

Other 

Perchloromethanethiol ( Perchloromethyl mercaptan) 

Perlargonyl peroxide 

»Phosgene (Carbonyl chloride) 

Pine oil, synthetic 

i;-Propiolactone 

Propionyl peroxide 

Rare sugars 

Sodium ethoxide 

Sodium formaldehyde bisulfite 

*Sodium formaldehyde sulfoxylate 

*Sodium methoxide (Sodium methylate) 

Sodium octylate 

Succinyl peroxide 

Tetrakis(hydroxymethyl )phosphonium chloride 

Tributylphosphine 

Tridecyl mercaptan 

Trioctylphosphine oxide 

»Zino formaldehyde sulfoxylate 

Other 



PFN. 
IDC. 
SFA. 
PAS. 

cue. 

HMY. 

OH. 

HMY. 

IFF, 

HMY. 

HMY. 

cue. 

EK, HMY. 
ARG, AZT, 



NCI. 



CAD, UPR, WTL. 



MRT, 

PAS. 
CRZ. 
CRZ, 
CRZ. 
PAS. 

TNA, 
TNA, 
TNA, 
TNA, 
ACS, 

DUP, 
DUP, 
DUP, 
FTE. 
ARA, 
NTB. 

DCC, 
DCC, 



SFA. 



PAS. 



TSA. 
TSA. 
TSA. 
TSA. 
CAL, 

HCH, 
NLC, 
HCH, 



PIC, 
ORO, 



SFA. 

NLC, 
TNA. 
TNA. 



UCC. 
SFA, 



TNA. 



SPD, UCC. 



CTN, 
NCI. 



RSA. 



DUP, MOB, CMC, OTC, PPG, RUC, UCC, UPJ, VEM. 



CCW, X. 
CCA. 
CCW, X. 
CCA, CCW, X. 
CHO. 
WTL. 
ACS, 
CBY, 
CEL. 
WTL. 
PFN, 
FMP. 

EK, IDC. 
DA, RH, ROY. 

BFR, DA, DUP, KF, CMC, RBC, SFA 
DA. 
WTL. 
HK. 

CCW, X. 
PAS. 
EK. 

DA, RH, ROY. 

ALX, CAD, CCW, DUP, EK, GAF, 
SFA, SFI, UCC, WAY, WTL, x 



KF, 

X. 



NES, ORO, PLC, RSA, 



DIRECTORY OF MANUFACTURERS 



191 



Directory of Manufacturers 

The Directory of Manufacturers lists the companies that report their production of synthetic 
organic chemicals to the U.S. Tariff Commission. The name of each manufacturer is preceded by 
an alphabetical identification symbol. These identification symbols consist of not more than three 
capital letters, and usually bear a relation to the company name. 

For 1967, the Directory of Manufacturers lists approximately 819 primary manufacturers 
(see table 22). Some of the companies that report production of synthetic organic chemicals do not 
sell the materials, but consume their entire output in further manufacturing. 

The Directory of Manufacturers lists the reporting companies in two ways: Section 1 lists 
them in alphabetical order by identification symbols; section E lists the reporting companies in 
alphabetical order by company name, and gives the corresponding identification symbol and the 
company address. Company divisions are usually listed under the parent company's name. 

TABLE 22. — Synthetic organic chemicals: Directory of manufacturers , 1967 

SECTION 1. ALPHABETICAL DIRECTORY BY CODE 
[Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. Tariff Commission 
for 1967 are listed below in the order of their identification codes as used in tables in pt. III. Section 2 of 
this table lists these manufacturers alphabetically and gives their office addresses.] 



Code 




Code 




identi- 


Name of company 


identi- 


Name of company 


fication 




fication 




AAC 


Aloolac Chemical Corp. 


ARC 


Armour & Co. , Armour Industrial Chemical 


AAE 


American Aniline & Extract Co., Inc. 




Co. Div. 


AAP 


American Aniline Products, Inc. 


ARD 


Ardmore Chemical Co. 


ABB 


Abbott Laboratories 


ARG 


Argus Chemical Corp. 


ABS 


Abex Corp. , American Bra]£eblok Div. 


ARK 


Armstrong Cork Co. 


ACB 


Allied Chemical Corp. , Fabricated Products 


ARL 


Arol Chemical Products Co. 




Div. 


ARM 


Armour Agricultural Chemical Co. 


ACQ 


Amoco Chemicals Corp. 


ARM 


Arenol Chemical Corp. 


ACE 


Acme Chemical Co. 


ARP 


Armour Pharmaceutical Co. 


ACI 


Aceto Industrial Chemical Co. 


ARZ 


Arizona Chemical Co. 


ACN 


Allied Chemical Corp., Agricultural Div. 


ASH 


Ashland Oil & Refining Co.: 


ACP 


Allied Chemical Corp. , Plastics Div. 




Ashland Chemical Co. Div. 


ACR 


Corn Products Co. , Acme Resin Co. Div. 




Catalin Corp. Div. 


ACS 


Allied Chemical Corp., Specialty Chemicals 


ASL 


Ansul Chemical Co. 




Div. 


AST 


Astra Pharmaceutical Products, Inc. 


ACT 


Arthur C. Trask Co. 


ASY 


American Synthetic Rubber Corp. 


ACU 


Allied Chemical Corp., Union Texas 


ATC 


American Tartars Corp. 




Petroleum Div. 


ATL 


Atlantic Chemical Corp. 


ACY 


American Cyanamid Co. 


ATP 


Atoo Chemical-Industrial Products, Inc., 


AES 


Amerace-Esna Corp., Chemical Specialties Div. 




Fine Chemicals Div. 


AGP 


Armour & Co. , Armour Grocery Products Co. 


ATR 


Atlantic Richfield Co., ARCO Chemical Co. 




Div. 




Div. 


AGY 


Agway, Inc. 


ATU 


Atlantic Tubing & Rubber Co. 


AKS 


Arkansas Co., Inc. 


AV 


FMC Corp., American Viscose Div. 


AIB 


Ames Laboratories, Inc. 


AVS 


Avisun Corp. 


ALC 


Alco Chemical Corp. 


AZT 


Aztec Chemicals, Inc. 


AID 


Aldrioh Chemical Co. , Inc. 






ALF 


Allied Chemical Corp., Fibers Div. 


BAG 


Baker Castor Oil Co. 


ALL 


Alliance Color & Chemical Co. 


BAL 


Baltimore Paint & Chemical Corp. 


ALT 


Crompton & Knowles Corp. , Chemicals Group, 


BAO 


Bayoil Co., Inc. 




Althouse & Bates Div. 


BAR 


American Rubber & Chemical Co. 


ALX 


Alox Corp. 


BAS 


BASF Corp. 


AMB 


American Bio-Synthetics Corp. 


BAX 


Baxter Laboratories, Inc. 


AMC 


Amchem Products, Inc. 


BCM 


Belding Chemical Industries 


AMI 


American Chemical Corp. 


BCN 


Lehn Sc Fink Products Corp., Beacon Div. 


AML 


Amalgamated Chemical Corp. 


BDO 


Benzenoid Organics, Inc. 


AMD 


American Oil Co. (Texas) 


BEN 


Bennett ' s 


AMP 


American Potash & Chemical Corp. 


BPG 


B. F. Goodrich Co., B. F. Goodrich Chemical 


AMR 


Pacific Resins 6 Chemical Co. 




Co. Div. 


AMS 


Martin-Marietta Corp. , Ridgway Color & 


BFR 


Branchflower Co. 




Chemical Div. 


BJL 


Burdick & Jackson Laboratories, Inc. 


ANM 


Ancon Chemical Corp. 


BKC 


J. T. Baker Chemical Co. 


APD 


Atlas Chemical Industries, Inc. 


BKL 


Millmaster Onyx Corp. , Millmaster Chemical 


APR 


Atlas Processing Co. 




Div. , Berkeley Chemical Dept. 


APV 


Armstrong Paint & Varnish Works, Inc. 


BKM 


Buckman Laboratories, Inc. 


APX 


Apex Chemical Co. , Inc. 


BKS 


Tenneco Chemicals, Inc., Tenneco Colors Div. 


ARA 


Arapahoe Chemicals Div. of Syntex Corp. 


BL 


Belle Chemical Co., Inc. 



192 SYNTHETIC ORGANIC CHEMICALS, 1967 

TABLE 22. --Synthetic organic chemicals,- Directory of manufacturers , 1967 — Continued 



Code 
identi- 
fication 



Name of company 



Code 
identi- 
fication 



Name of company 



Astor Products, Blue Arrow Div. 

Beech-Nut Inc. 

Bendix Corp., Friction Materials Div. 

Borden Co. , Borden Chemical Co. Div. 

Walter N. Boysen Co. 

Cowles Chemical Co., Benzol Products Div. 

Brand Plastics Co. 

Baird Chemical Industries, Inc. 

Bristol -Meyers Co. , Bristol Laboratories Div. 

M. A. Bruder & Sons, Inc. 

Bryant Chemical Corp. 

Occidental Petroleum Corp. , Occidental 

Chemical Co. Div. 
Original Bradford Soap Works, Inc. 
Blackman-Uhler Chemical Co. 
Buckeye Cellulose Corp. 
Burroughs-Welloome & Co. (U.S.A.), Inc. 
J. H. Baxter & Co. 

Cadet Chemical Corp., a subsidiary of 

Chemetron Noury Corp. 
Gallery Chemical Co. 
Cap-Roc, Inc. 
Calcasieu Chemical Corp. 
Ciba Corp. : 

Ciba Argochemioal Co. 

Ciba Products Co. 
Georgia-Pacific Corp., Coos Bay Div. 
Chembond Corp. 

Carborundum Co. , Coated Abrasives Div. 
Columbian Carbon Co., Inc. and Chemicals Div. 
Ciba Corp., Ciba Pharmaceutical Co. Div. 
Colab Resin Corp. 
Samuel Cabot, Inc. 
Crosby Chemicals, Inc. 

Carlisle Chemical Works, Inc., Advance Div. 
Chase Chemical Corp. 
Pearsall Chemical Co. 
Charlotte Chemical Laboratories 
Chemioo, Inc. 

Crown Central Petroleum Corp. 
Carlisle Chemical Works, Inc. 
Budd Co., Polychem Div. 
Celanese Corp. of America: 

Celanese Chemical Co. Div. 

Celanese Coatings Co. 

Celanese Plastics Co. 

Fibers Co. Div. 
Cooperative Farm. Chemicals Association 
Sun Chemical Corp. Organic Chemical Dept. 
Cargill, Inc. 

Chipman Chemical Co., Inc. 
Chemical Formulators, Inc. 
Chemagro Corp. 
Chemol, Inc. 
Stauffer Chemical Co., Calhio Chemicals, Inc. 

Div. 
C. H. Patrick & Co. , Inc. 
Chattem Drug & Chemical Co. , Chattem Chemicals 

Div. 
Ciba Chemical & I>ye Co. 
Tenneco Chemicals, Inc., Cal/Ink Div. 
Chemical Insecticide Corp. 
Chemlek Laboratories, Inc. 
Columbia Organic Chemicals Co., Inc. 
Colloids, Inc. 
Clintwood Chemical Co. 
Clark Oil & Refining Corp. 
Standard Brands, Inc., Clinton Com Processing 

Co. Div. 
Clover Chemical Co. 



CLY 

CM 

CMC 

CMP 

CNC 

CNP 

CO 

COK 

COL 

CCM 

CON 

COP 

COR 

CP 

CPC 

CPD 

CPP 

CPV 

CPY 

CRD 

CRN 

CRS 

CRT 

CRY 

CRZ 

CSB 
CSD 
CSO 
CSP 
CST 
CTA 

CTL 

CTN 

cue 

CUL 
CUT 
CW 

CWL 
OWN 
CWP 

DA 

DAN 

DAY 

DBC 

DCC 

DCP 

DB3 

DEP 

DEX 

DIX 

DLH 

DLI 

DCM 

DOW 

DPP 

DRW 

DSC 

DSO 

DUN 

DUP 

D7C 

DXS 

DYS 

ECC 



Inc. 



W. A. Cleary Corp. 

Carpenter-Morton Co. 

Nyanza, Inc. 

Commercial Products Co., Inc. 

Columbia Nitrogen Corp. 

Coliimbia Nipro Corp. 

Continental Oil Co. 

Cockerille Chemicals, Inc. 

Collier Carbon & Chemical Corp. 

Commercial Solvents Corp. 

Concord Chemical Co., Inc. 

Coopers Creek Chemical Corp. 

Commonwealth Oil Refining Co. 

Colgate-Palmolive Co. 

Childs Pulp Colors, Inc. 

Chemical Products Corp. 

Charmin Paper Products Co. 

Cook Paint & Varnish Co. 

Copolymer RubberSc Chemical Corp. 

Croda, Inc. 

Corn Products Co. 

Carus Chemical Co., Inc. 

Crest Chemical Corp. 

Tenneco Manufacturing Co., Tenneco Plastics 

Div. 
Crown Zellerbach Corp., Chemical Products 

Div. 
Imoco Corp., Chemical Services Div. 
Cosden Oil & Chemical Co. 
Cities Service Oil Co. 
Coastal States Petrochemical Co. 
Charles S. Tanner Co. 
Chemetron Corp. , Chemetron Chemicals, Organic 

Chemical Dept. 
Continental Chemical Co. 
Chemetron Corp. , Chemetron Chemicals 

Organic Chemical Dept. 
Air Reduction Co., Inc., Airco Chemicals & 

Plastics 
Culver Chemical Co. 
Cutter Laboratories, 
General Mills, Inc., 
Cowles Chemical Co. 
Upjohn Co., Carwin Organic Chemicals 
Consolidated Papers, Inc. 

Diamond Shamrock Corp. 

Dan River Mills, Inc. 

Conchemco, Inc., H. B. Davis Co. Div. 

Dow Badische Co. 

Dow Coming Corp. 

Dixie Chemical Products, Inc. 

Degen Oil & Chemical Co. 

DeFfeul Chemical Co., Inc. 

Dexter Corp. 

Dixie Chemical Co. 

Hess Oil & Chemical Corp. 

Dawe's Laboratories, Inc. 

Dominion Products, Inc. 

Dow Chemical Co. 

Dixie Pine Products Co., Inc. 

Drew Chemical Corp. 

Dye Specialties, Inc. 

DeSoto, Inc. 

Frank W. Dunne Co. 

E. I. duPont de Nemours & Co., Inc. 

Dover Chemical Corp. 

Sunray DX Oil Co. 

Davies-Young Soap Co. 

Eastern Color & Chemical Co. 



Inc. 
Chemical Div. 



DIRECTORY OF MANUFACTURERS 193 

TABLE 22. --Synthetic organic chemicals: Directory of manufacturers , 1967 — Continued 



Code 




Code 




identi- 


Name of company 


identi- 


Name of company 


fication 




fication 




EFH 


E. F. Houghton & Co. 


GGC 


Goodrich-Gulf Chemicals, Inc. 


EK 


Eastman Kodak Co. 


GGY 


Geigy Chemical Corp. 


EIO" 


Eastman Kodak Co. , Tennessee Eastman Co. Div. 


GIL 


Gilman Paint & Varnish Co. 


EKX 


Eastman Kodak Co., Texas Eastman Co. Div. 


GIV 


Givaudan Corp. 


ELP 


El Paso Products Co. 


GLC 


General Latex & Chemical Corp. 


niK 


Bnkay Chemical Co. 


GLD 


SCM Corp., Glidden-Durkee Div. 


WR 


Bnery Industries, Inc. 


GLX 


Electro-Seal Glasflex Corp. 


EN 


Endo Laboratories, Inc. 


GLY 


Glyco Chemicals, Inc. 


ENJ 


Enjay Chemical Co. 


GNF 


General Foods Corp., Maxwell House Div. 


ENO 


Enenco, Inc. 


GNM 


General Mills, Inc. S: Chemical Div. 


EPC 


Epoxylite Corp. 


GNI 


General Tire 4 Rubber Co., Chemical Div. 


ESA 


East Shore Chemical Co. , Inc. 


GOC 


Gulf Oil Corp. 


ESC 


Escambia Chemical Corp. 


GOR 


Gordon Chemical Co., Inc. 


ETD 


Ethyl-Dow Chemical Co. 


GIM 


General Plastics Manufacturing Co. 


EVN 


Evans Chemetics, Inc. 


GPR 


Grain Processing Corp. 


EW 


Westinghouse Electric Corp. , Benolite Dept. 


GRA 


Great American Plastics Co. 






GRC 


W. R. Grace & Co., Dubois Chemicals Div. 


FAB 


Fabricolor Manufacturing Corp. 


GRD 


W. R. Grace & Co. , Dewey 8c Almy Chemical 


FAR 


Famow, Inc. 




Div. 


FB 


Fritzsche Bros., Inc. 


GRG 


P. D. George Co. 


IBF 


Hexall Chemical Co., Fiberfil Div. 


GRH 


W. R. Grace & Co., Hatoo Chemical Div. 


FBR 


Fibreboard Corp. 


GRL 


W. R. Grace & Co. , Vestal Laboratories Div. 


FC 


Franklin Chemical Co. 


GRO 


Mlllmaster Onyx Corp., A. Gross & Co. Div. 


FCA 


Farmers Chemical Association, Inc. 


GRS 


Pontiac Refining Corp. 


FCD 


France, Campbell S: Darling, Inc. 


GHV 


Guardsman Chemical Coatings, Inc. 


FCL 


Federal Color Laboratories, Inc. 


GRW 


Great Western Sugar Co. 


FEL 


Felton International, Inc. 


GTH 


Guth Chemical Co. 


FER 


Ferro Corp. , Ferro Chemical Div. 


GTL 


Great Lakes Chemical Corp. 


PG 


Foster Grant Co., Inc. 


GYR 


Goodyear Tire & Rubber Co. 


FH 


Foster-Heaton Co. 






FDJ 


Fine Organics, Inc. 


HAB 


Halby Products Co., Inc. 


Fin 


Firestone Tire & Rubber Co. , Firestone 


HAL 


C. P. Hall Co. of Illinois 




Plastics Co. Div. 


HAM 


Hampden Color & Chemical Co. 


FIS 


Fisher Chemicals Co., Inc. & Fisher Melamine 


HAN 


Hanna I^int Manufacturing Co., Inc. 




Corp. 


HAP 


Applied Plastics Co., Inc. 


FLU 


H. B. Fuller Co. 


HCH 


Houston Chemical Corp. 


Flii 


Fleming Laboratories, Inc. 


HCR 


Hercor Chemical Corp. 


FLO 


Florasynth, Inc . 


HDG 


Hodag Chemical Corp. 


FLW 


Fuller-O'Brien Corp. 


HER 


Heresite & Chemical Co. 


FMB 


FWC Corp., Inorganic Chemicals Div. & Organic 


HET 


Heterochemlcal Corp. 




Chemicals Div. 


HEW 


Hewitt Soap Co. 


FMN 


FMC Corp. , Niagara Chemical Div. 


HEX 


Hexagon Laboratories, Inc. 


IMP 


IMC Corp. , Organic Chemicals Div. & Nitro 


HIT 


Hoffman-Taff, Inc. 




Plant 


HK 


Hooker Chemical Corp. 


FMT 


Fairmount Chemical Co., Inc. 


HKD 


Hooker Chemical Corp., Darex Div. 


FOC 


Farac Oil & Chemical Co. , Div of Handschy 


HKY 


Hawkeye Chemical Co. 




Chemical Co. 


HLI 


Haag Laboratories, Inc. 


FQM 


Formica Corp. 


HMP 


W. R. Grace & Co. , Hampshire Chemical Div. 


FOR 


El Dorado Chemical Co. 


HMY 


Humphrey Chemical Co. 


FRE 


Freeman Chemical Corp. 


HN 


Tenneco Chemicals, Inc. 


FRL 


Firestone Tire Sc Rubber Co. , Firestone 


HNC 


H & N Chemical Co. 




Industrial Rubber Products Co. Div. 


HNT 


Huntington Laboratories, Inc. 


FRM 


Farmer's Chemical Co. 


HNW 


Tenneco Chemicals, Inc. , Newport Div. 


FRO 


Vulcan Materials Co., Chemicals Div. 


HNX 


Tenneco Chemicals, Inc. , Nuodex Div. 


FRP 


Filtered Rosin Products Co. 


HOF 


HofCmann-LaHoche, Inc. 


FHS 


Firestone Tire 4 Rubber Co. , Firestone 


HOU 


Air Products & Chemicals, Inc., Houdry 




Synthetic Rubber & Latex Co. Div. 




Process & Chemical Div. 


FSH 


Frisch ic Co., Inc. 


HPC 


Hercules, Inc. 


FST 


First Chemical Corp. 


HRS 


Grow Chemical Corp. , Harris Paint Co. Div. 


FTE 


Foote Mineral Co. 


HRT 


Hart Products Corp. 


FTX 


Central Farmers Fertilizer Co. , Fel-Tex Plai.t 


HSC 


Holland-Suco Color Co. 






HSH 


Harshaw Chemical Co., Div. of Kewanee Oil Co. 


GAF 


General Anllne & Film Corp. : 


HST 


American Hoechst Corp. 




riyestuff & Chemical Div. 


HSY 


Hershey Estates, Inc. 




Textile Finishes Dept., Textile Chemical Div. 


HUM 


National Dairy Products Corp., Humko Products 


GAN 


Gane's Chemical Works, Inc. 




Chemical Div. 


OCC 


W. R. Grace 4 Co. , Agricultural Products Div. 


HUS 


Husky Briquettlng, Inc. 


GE 


General Electric Co., & Chemical Materials 


HVG 


Haveg Industries, Inc. 




Dept. 


HYC 


Dexter Corp. , Hysol Co. Div. 


GEI 


General Eleotrio Co. , Insulating Materials 
Dept. 


HYN 


Ifynson, Westcott & IXuining, Inc. 


GKS 


G. Frederick Smith Chemical Co. 


IBI 


Industrial Bloohemloals, Inc. 



194 SYNTHETIC ORGANIC CHEMICALS, 1967 

TABLE 22. --Synthetic organic chemicals.- Directory of manufacturers , 1967— Contmued 



Code 




Code 




identi- 


Name of company 


identi- 


Name of company 


fication 




fication 




ICC 


Interchemical Corp., Color & Chemicals Div. 


LUR 


Laurel Products Corp. 


ICF 


Interohemical Corp., Finishes Div. 


LVR 


C. Lever Co., Inc. 


ICI 


I.e. I./Organios/Ino. 


LVY 


Fred'k H. Levey Co.; Inc. 


ICO 


Interchemical Corp., Organic Chemicals Dept. 






IDC 


Industrial Dyestuff Co. 


MAH 


Maher Color Sc Chemical Co. 


IFF 


International Flavors & Fragrances, Inc. 


MAL 


Mallinckrodt Chemical Works 


ILC 


International Latex & Chemical Corp. 


MAN 


Pickands Mather & Co. Manganese Chemical Co. 


IMC 


International Minerals & Chemical Corp. 




Div. 


IMP 


Hercules, Inc., Imperial Color & Chemical Dept. 


MAR 


American Can Co. , Marathon Products/ Chemical 


INL 


Inland Steel Co., Inland Steel Container Co. 


MAY 


Otto B. May, Inc. 




Div. 


MCA 


Masonlte Corp., Alpine Chemical Div. 


IOC 


Hitter Pfaudler Corp., lonao Chemical Co. Div. 


MCB 


Borg-Warner Corp., Marbon Chemical Div. 


IPC 


Interplastio Corp. , Commercial Resins Div. 


MCC 


MoCloskey Varnish Co. 


IPI 


Isocyanate Products, Inc. 


MCH 


Michigan Chemical Corp. 


IPR 


Inter-Pacific Resins, Inc. 


MCI 


Mooney Chemicals, Inc. 


IRC 


IRC, Inc. 


MCP 


Moretex Chemical Products, Inc. 


IRI 


Ironsides Resins, Inc. 


MED 


Medical Chemicals Corp. 






MEE 


Maumee Chemical Co. 


JCC 


Jefferson Chemical Co., Inc. 


MER 


Merichem Co. 


JDC 


Nipak, Inc. 


MET 


M & T Chemicals, Inc. 


JEN 


Jennison-Wright Corp. 


MFG 


Molded Fiber Glass Body Co. 


JMS 


J. Meyer & Sons, Inc. 


MGK 


McLaughlin Gormley King Co. 


JNS 


S. C. Johnson & Son, Inc. 


MGR 


Magruder Color Co., Inc. 


JOB 


Jones-Blair Paint Co. 


MHI 


Ventron Corp. 


JOR 


Jordan Chemical Co. 


MID 


Midland Industrial Finishes Co. 


JRG 


Andrew Jergens Co. 


MIR 


Miranol Chemical Co., Inc. 


JSC 


Jersey State Chemical Co. 


MLD 


Metalead Products Corp. 


JTC 


Joseph Turner & Co. 


MLS 


Miles Laboratories, Inc., Marschall Div. 


JWL 


Jewel Paint & Varnish Go. 


mm 


Minnesota Mining & Manufacturing Co. 






MNO 


Monochem, Inc. 


KAI 


Kaiser Aluminum & Chemical Corp. , Kaiser Chem- 


MNP 


Minnesota Paints, Inc. 




icals Div. 


MOA 


Mona Industries, Inc. 


KAL 


Kali Manufacturing Co. 


MOB 


Mobay Chemical Co. 


KCC 


Kennecott Copper Corp. , Chino Mines Div. 


MOC 


Marathon Oil Co. , Texas Refining Div. 


KCH 


Keystone Chemurgic Corp. 


MON 


Monsanto Co. 


KCU 


Kennecott Copper Corp. , Utah Copper Div. 


MOR 


Mineral Oil Refining Co. 


KCW 


Keystone Color Works, Inc. 


MOT 


Motomco, Inc. 


KEL 


Kelly-Pickering Chemical Corp. 


MR 


Benjamin Moore & Co. 


K£N 


Witco Chemical Co. Inc., Kendall Refining Div. 


MRA 


Metro-Atlantic, Inc. 


K£T 


Ketona Chemical Corp. 


MRB 


Marblette Co. Div. of Allied Products Corp. 


KF 


Kay-Fries Chemicals, Inc. 


MRD 


Marden-Wild Corp. 


KMC 


Kohler-McLister Paint Co. 


MRK 


Merck & Co., Inc. 


KM? 


Kelly-Moore Paint Co. 


MRN 


International Latex & Chemical Corp., Paisley 


KND 


Knoedler Chemical Co. 




Products Div. 


KNG 


Far- Best Corp., 0. L. King Div. 


MHO 


W. R. Grace & Co., Marco Chemical Div. 


KNP 


Knapp Products, Inc. 


MRT 


Morton Chemical Co. . 


KON 


H. Kohnstamm & Co., Inc. 


MRV 


Marlowe- Van Loan Corp. 


KPI 


Kenrich Petrochemicals, Inc. 


MRX 


Max Marx Color & Chemical Co. 


KPP 


Sinclair-Koppers Co. 


MSC 


Mississippi Chemical Corp. 


KPS 


Koppers Pittsburgh Co. 


MTO 


Montrose Chemical Corp. of California 


KPT 


Koppers Co., Inc., Organic Materials Div. 


MTR 


Baldwin-Montrose Chemical Co., Inc., Montrose 


KRM 


Lawter Chemicals, Inc., Krumbhaar Resin Div. 




Chemical Div. 


KYN 


Kyanize Paints, Inc. 


MYW 


Stepan Chemical Co. , Maywood Div. 


KYS 


Keysor Chemical Co. 










NCA 


Northrop Carolina, Inc. 


LAK 


Lakeway Chemical Co. 


NCI 


Union Camp Corp., Chemicals Div. 


LAM 


LaMotte Chemical Products Co. 


NCW 


Nostrip Chemical Works, Inc. 


LAS 


Lasco Industries, Inc. 


NEO 


Norda Essential Oil & Chemical Co. , Inc. 


LEA 


Leatex Chemical Co. 


NEP 


Nepera Chemical Co., Inc. 


LEB 


Lebanon Chemical Corp. 


NES 


Nease Chemical Co., Inc. 


LEM 


B. L. Lemke & Co., Inc. 


NEV 


Neville Chemical Co. 


LEN 


Leonard Refineries, Inc. 


NIL 


Nilok Chemicals, Inc. 


LEV 


Lever Brothers Co. 


NIT 


Nitrin, Inc. 


LIL 


Eli Lilly & Co. 


NLC 


Nalco Chemical Co. 


LKL 


Lakeside Laboratories, Div. of Colgate- 


NMC 


National Milling & Chemical Co., Inc. 




Palmolive Co. 


NOC 


Norac Co., Inc. & Mathe Chemical Co. Div. 


LKY 


Lake States, Div. of St. Regis. Paper Co. 


NON 


A. P. Nonweiler Co. 


LMI 


North American Chemical Co. 


NOR 


Norwich Pharmacal Co. 


LPC 


Lignln Products Co. 


NPC 


Northwest Petrochemical Corp. 


LUB 


Lubrizol Corp. 


NPI 


National Polifchemicals, Inc. 


LUE 


George Lueders & Co., Inc. 







DIRECTORY OF MANUFACTURERS 
TABLE 22 .-- Synthetic organic chemicals: Directory of manufacturers , 1967. — Continued 



195 



Code 




Code 




identi- 


Name of company 


identi- 


Name of company 


fication 




fication 




MV 


Enjay Chemical Co., Enjay Fibers & Laminates 


PLU 


Plumb Chemical Corp. 




Co. Div. 


PLX 


Plex Chemical Corp. 


NPR 


Safeway Stores, Inc., Newport PrSduots Co. 


PMC 


Plastics Manufacturing Co. 




Div. 


PMP 


Premier Malt Products, Inc. 


NPV 


Norris Paint &. Varnish Co. 


PNT 


Pantasote Co. of New York, Inc. 


NRS 


Norse Chemical Corp. 


PNX 


Phoenix Oil Co. 


NSC 


National Starch & Chemical Corp. 


POL 


Polymer Corp. 


NTB 


National Biochemical Co. 


PPC 


Premier Petrochemical Co. 


NTC 


National Casein Co. 


PPG 


Pittsburgh Plate Glass Co. 


NTL 


National Lead Co. 


PPL 


Pioneer Plastics Corp. , Chemical Div. 


NVF 


NVF Co. 


PRC 


Products Research & Chemical Corp. 


Nvr 


Novamont Corp., Neal Works 


PRD 


Productol Chemical Co., Inc. 


m 


Northwestern Chemical Co. 


PRT 


Pratt & Lambert, Inc. 


NYC 


Tenneco Chemicals, Inc., New York Color Div. 


PRX 


Purex Corp., Ltd. 






PSC 


Passaic Color & Chemical Co. 


OBC 


O'Brien Corp. 


PSP 


Georgia-Pacific Corp. , Bellingham Div. 


OCF 


Owens-Corning Fiberglas Corp. 


PTO 


Puerto Rico Chemical Co., Inc. 


OH 


Air Reduction Co., Inc., Ohio Medical 


PTP 


Preservative Paint Co. 




Products Div. 


PTT 


Petro-Tex Chemical Corp. 


QMG 


Olin Mathieson Chemical Corp. , & Agricultural 


PUB 


Publicker Industries, Inc. 




Div. 


PUR 


Puritan Chemical Co. 


QMS 


£. R. Squibb & Sons, Inc. 


PVI 


Polyvinyl Chemicals, Inc. 


ONX 


Millmaster Onyx Corp., Onyx Chemical Div. 


PYL 


Polychemical Laboratories, Inc. 


OPC 


Orbis Products Corp. 


PYR 


Poly Resins 


OHG 


Organics, Inc. 


PYZ 


Pol^frez Co., Inc. 


ORO 


Chevron Chemical Co. 






ORT 


Roehr Chemicals, Inc. 


QCP 


Quaker Chemical Corp. 


OSB 


C. J. Osborn Co. 


QKO 


Quaker Oats Co. 


OTA 


Ottawa Chemical Co. 


QUN 


K. J. Qulnn & Co., Inc. 


OTC 


Ott Chemical Co. 






OTH 


Chevron Chemical Co. 


RAB 


Raybestos-Manhattan, Inc., Raybestos Div. 






RAY 


ITT Rayonier, Inc. 


PAI 


Pennsylvania Industrial Chemical Corp. 


RBC 


Roberts Chemicals, Inc. 


PAN 


Pan American Petroleum Corp. 


RCC 


Rexall Chemical Co. 


PAR 


Pennsylvania Refining Co. 


RCD 


Richardson Co. 


PAS 


Pennsalt Chemicals Corp. 


RCI 


Reichhold Chemicals, Inc. 


PAT 


Patent Chemicals, Inc. 


RDA 


Rhodia, Inc. 


PBI 


Private Brands, Inc. 


RED 


Red Spot Paint Co., Inc. 


PBY 


Pillsbury Co. 


REH 


Reheis Chemical Co., Div. of Armour Pharma- 


PC 


Proctor Chemical Co., Inc. 




ceutical Co. 


PCC 


USS Chemicals, Div. of U.S. Steel Corp. 


REL 


Reliance Universal, Inc. & Rel-Rez Div. 


PCH 


Peerless Chemical Co. 


REM 


Remington Arms Co., Inc. 


PCI 


Pioneer Chemical Works, Inc. 


REN 


Renroh Resins 


PCR 


Princeton Chemical Research, Inc. 


REZ 


Rezolln, Inc. 


PCS 


Emery Industries, Inc., Western Div. 


RGC 


Rogers Corp. 


PCW 


Pfister Chemical, Inc. 


RH 


Rohm & Haas Co. 


PD 


Parke, Davis & Co. 


RIK 


Riker Laboratories, Div. of Rexall Drug & 


PDC 


Bernoolors-Poughkeepsie, Inc. 




Chemical Co. 


PDJ 


Joseph Davis Plastics Co. 


RIL 


Reilly Tar & Chemical Corp. 


PEK 


Peck's Products Co. 


RIV 


Riverdale Chemical Co. 


PEL 


PelTon Corp. 


RLS 


Rachelle Laboratories, Inc. 


PEN 


S. B. Penick & Co. 


ROB 


Robeco Chemicals, Inc. 


PER 


Perry & Derrick Co. 


ROC 


Rock Hill Printing & Finishing Co. 


PFN 


Pfanstiehl Laboratories, Inc. 


ROM 


United Merchants & Manufacturers, Inc., Roma 


PFP 


Phelan- Faust Paint Manufacturing Co., 




Chemical Div. 




Phelan's Resins & Plastics Div. 


ROY 


Royce Chemical Co. 


PP# 


Polak's Frutal Works 


RPC 


Refined Products Co. 


PFZ 


Chas. Pfizer & Co., Inc. 


RSA 


R.S.A. Corp. 


PG 


Procter & Gamble Co., Procter & Gamble 


RSB 


Rosenberg Bros. & Co. 




Manufacturing Co. 


RT 


F. Ritter & Co. 


PCKJ 


Gulf Oil Corp., Perkins Glue, Chemicals Dept. 


RTC 


Ritter Chemical Co., Inc. 


PHF 


Peter Hand Foundation, Inc. 


RTF 


Retzloff Chemical Co. 


PHR 


Pharmachem Corp. 


RUB 


Hooker Chemical Corp., Ruco Div. 


PIC 


Pierce Organics, Inc. 


RUC 


Rubicon Chemicals, Inc. 


PII 


Polymer Industries, Inc. 






PIL 


Pilot Chemical Co. 


S 


Sandoz, Inc. & Dyestuff & Chemical Div. 


PIT 


Pitt-Consol Chemical Co. 


SAC 


Southeastern Adhesives Co. 


PLA 


Richardson Co., Richardson Polymers Div. 


SAL 


Salsbury Laboratories 


PLB 


P-L Biochemicals, Inc. 


SAR 


Sartomer Resins, Inc. 


PLC 


Phillips Petroleum Co. 


SBC 


Scher Bros., Inc. 


PLS 


Plastics Engineering Co. 


SBI 


Southern Biochemical Corp. 



196 SYNTHETIC ORGANIC CHEMICALS, 1967 

TABLE 22. — Synthetic organic chemicals.- Directory of manufacturers , 1967 — Continued 



Code 




Code 




identi- 


Name of company 


identi- 


Name of company 


fication 




fication 




SEP 


Sugar Beet Products Co. 


SRL 


G. D. Searle & Co. 


sec 


Standard Chlorine Chemical Co., Inc. 


SRR 


Stresen-Reuter International, International 


SCF 


Schaefer Varnish Co. 




Minerals & Chemical Corp. 


SCH 


Schering Corp. 


STA 


A. E. Staley Manufacturing Co. 


SCN 


Schenectady Chemicals, Inc. 


STC 


Sou-Tex Chemical Co., Inc. 


SCO 


Scholler Bros., Inc. 


STG 


Stange Co. 


SCP 


Standard Chemical Products, Inc. 


STP 


Stepan Chemical Co. , Industrial Chemicals 


SCR 


R. P. Scherer Corp. 




Div., MlUsdale Works 


SDC 


Martin-Marietta Corp. , Southern Dyestuf f Co. 


SUG 


Colonial Sugars Co., Sucro-Chemical Div. 




Div. 


SUM 


Summit Chemical Products Corp. 


SDG 


Sterling Drug, Inc. , Glentrook Latoratories 


SUN 


Sun Oil Co. 




Div. 


SVC 


Sullivan Varnish Co. 


SDH 


Sterling Drug, Inc., Hilton-Davis Chemical Co. 


SVT 


Solvent Chemical Co., Inc. 




Div. 


SW 


Sherwin-Williams Co. 


SDW 


Sterling Drug, Inc., Winthrop Laboratories 


SWT 


Swift & Co. 




Div. 


SYC 


Synthetic Chemicals, Inc. 


SEA 


Seaboard Chemicals, Inc. 


SYP 


Synthetic Products Co. 


SED 


Conohemco, Inc., Seidlitz Paint Div. 


SYV 


Synvar Corp. 


SEK 


Plastic Systems Corp. 






SEL 


Selney Co., Inc. 


TAE 


Chemetron Corp. , National Cylinder Gas Div. 


SEY 


Seydel-Woolley & Co. 


TCC 


Tanatex Chemical Corp. 


SF 


Stauffer Chemical Co., Agricultural Div. 


TCH 


Trylon Chemical, Corp. 


SFA 


Stauffer Chemical Co., Specialty Chemical Div. 


TCI 


Norwich Pharmacal Co., Texize Chemicals, Inc. 


SFD 


Sonford Chemical Co. 




Div. 


SFI 


Stauffer Chemical Co., Industrial Div. 


TDC 


Diversey Corp. 


SH 


Stein, Hall & Co., Inc. 


TEK 


Teknor Apex Co. 


SHA 


Shanoo Plastics & Chemicals, Inc. 


TEN 


Tennessee Copper Co., Div. of Tennessee Corp. 


SHC 


Shell Oil Co., Shell Chemical Co. Div. 


TER 


Terra Chemicals International, Inc. 


SHF 


National Dairy Products Corp., Sheffield 


TGL 


Triangle Chemical Co. 




Chemical Div. 


THC 


Thompson Apex Co., Div. of Continental Oil Co. 


SHL 


Shulton, Inc. 


THM 


Wm. T. Thompson Co., Thompson Chemicals Div. 


SHO 


Shell Oil Co. 


TIC 


Ticonderoga Chemical Corp. 


SHP 


Shepherd Chemical Co. 


TID 


Getty. Oil Co. 


SIC 


Vistron Corp., Silmar Div. 


TKl 


Thiokol Chemical Corp. 


SID 


George F. Siddall Co., Inc. 


TMH 


Thompson-Hayward Chemical Co. 


SIM 


Simpson Timber Co. 


■ma 


Sterling Dmg, Inc., Thomasset Colors Div. 


SIN 


Sinclair Refining Co. 


INA 


Ethyl Corp. 


SIO 


Standard Oil Co. of Ohio 


TNI 


Gillette Chemical Co., Div. of Gillette Co. 


SIP 


James P. Sipe & Co. 


TOC 


Tenneco Oil Co. 


SK 


Smith, Kline & French Laboratories 


TRC 


Toms River Chemical Corp. 


SKC 


Sinclair-Koppers Chemical Co. 


TRJ 


Jeras Corp. 


SKG 


Sunkist Growers, Inc. 


TRO 


Troy Chemical Co. 


SKO 


Skelly Oil Co. 


TSA 


Texas Alkyls, Inc. 


SKT 


Textron, Inc., Spencer Kellogg Div. 


TTX 


Detrex Chemical Industries, Inc. 


SLC 


Soluol Chemical Co., Inc. 


TUS 


Texas-U.S. Chemical Co. 


SLV 


Sterling Drug, Inc., Salvo Chemical Div. 


TV 


Sun Chemical Corp., Industrial Coatings Div. 


SM 


Mobil Chemical Co. 


TX 


Texaco, Inc. 


SM 


Mobil Oil Corp. & 'Mobil Chemical Co. Div., 


TXC 


Tex Chem Co. 




Industrial Chemical Div. 


TXN 


Textilana-Nease, Inc. 


SMC 


Stamford Chemical Industries, Inc. 


TXT 


Textilana Corp. 


SNA 


Sun Chemical Corp., Pigments Div. 


TZC 


Tizon Chemical Corp. 


SNC 


Sonooo Products Co. 






SNI 


Kaiser Aluminum & Chemicals Corp. , Kaiser 


UBS 


A. E. Staley Manufacturing Co., UBS Chemi- 




Agricultural Chemicals Div. 




cal Co. Div. 


SNO 


SunOlin Chemical Co. 


UCC 


Union Carbide Corp. 


SNT 


Suntide Refining Co. 


UDI 


Petrochemicals Co., Inc. 


SNW 


Sun Chemical Corp. , Chemical Div. 


UHL 


Paul Uhlich & Co., Inc. 


SOC 


Standard Oil Co. of California, Chevron 


UNG 


Ungerer & Co. 




Chemical Co. 


UNN 


United Chemical Corp. of Norwood 


SOG 


Signal Oil & Gas Co. 


UNO 


United Oil Manufacturing Co. 


SOH 


Solar Nitrogen Chemicals, Inc. & Vistron Corp. 


UNP 


United Chemical Products Corp. 


SOI 


American Oil Co. (Maryland) 


UNS 


Union Starch & Refining Co., Inc. 


SOL 


Solar Chemical Corp. 


UOC 


Union Oil Co. of California 


SOP 


Southern Chemical Products Co. 


UOP 


Universal Oil Products Co., UOP Chemical Div. 


SOR 


Thomason Industries, Inc., Southern Resin Div. 


UPF 


United States Pipe & Foundry Co. 


SOS 


Southern Sizing Co. 


UPJ 


Upjohn Co. 


SPC 


Sinclair Paint Co. 


UPL 


United States Plywood-Champion Papers, Inc., 


SPD 


General Electric Co., Silicone Products Dept. 




California Div., Shasta Operations. 


SPI 


Sinclair Petrochemicals, Inc. 


UPM 


Universal Oil Products Co. 


SPL 


Spaulding Fibre Co., Inc. 


UPR 


Argus Chemical Corp., U.S. Peroxygen Div. 


SPY 


Standard Pyroxoloid Corp. 


URC 


United Carbon Co. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. — Synthetic organic chemicals.- Directory of manufacturers , 1967 — Continued 



197 



Code 




Code 




identi- 


Name of company 


identi- 


Name of company 


fication 




fication 




USB 


U.S. Borax Research Corp. 


WHC 


Whittaker Corp. , Research & Development/San 


USI 


National Distillers & Chemical Corp. : 




Diego 




National Petro Chemical Corp. Div. 


WHI 


White & Hodges, Inc. 




U.S. Industrial Chemicals Co. Div. 


WHL 


Whitmoyer Laboratories, Inc. 


uso 


U.S. Oil Co. 


WHW 


Whlttemore-Wright Co., Inc. 


USE 


Uniroyal, Inc., Chemical Div. 


WIC 


Wica Chemicals, Inc. 


UTR 


Utah Resin Co., Inc. 


WIL 


Wilson Fharmaceutical & Chemical Corp., 


UVC 


Universal Chemicals Corp. 




Wilson Laboratories Div. 






WJ 


Warner-Jenkinson Manufacturing Co. 


VAC 


Northern Petrochemical Co. , Varney Div. 


WLI 


White Laboratories, Inc. 


VAL 


Valchem 


WLM 


Wilmot & Cassidy, Inc. 


VB 


Vermi lye- Bell 


WM 


Wilson Pharmaceutical & Chemical Corp. 


VIM 


Van De Mark Chemical Co. 




Wilson-Martin Div. 


VEL' 


Velsicol Chemical Corp. 


WMP 


Warner Machine Products, Inc., Warner Chem- 


VGC 


Virginia Chemicals, Inc. 




ical Div. 


VIN 


Vineland Chemical Co. 


WOB 


Woburn Chemical Corp. 


VLN 


Valley Nitrogen Producers, Inc. 


WOD 


Woodbury Chemical Co. 


VLY 


Chem-Fleur, Inc. 


WON 


Woonsocket Color & Chemical Co. 


VNC 


Vanderbilt Chemical Corp. 


WHC 


Wood Ridge Chemical Corp. 


VND 


Van Dyk & Co., Inc. 


WRD 


Weyerhaeuser Co., Wood Products Div. 


VPC 


Verona-Pharma Chemical Corp. 


WSN 


Washine Chemical Corp. 


VPT 


Vickers Refining Co., Inc. 


WTC 


Witco Chemical Co., Inc. 


VSV 


Valentine Sugars, Inc. 


WTH 


Wallace & Tiernan, Inc., Harohem Div. 


VTM 


Vitamins, Inc. 


WTL 


Wallace & Tiernan, Inc., Lucidol Div. 






WVA 


West Virginia Pulp & Paper Co. : 


WAW 


W. A. Wood Co. 




Chemical Div., Tall Oil Dept. 


WAY 


Philip A. Hunt Chemical Corp. , Way land Chem- 




Polyohemicals Div. 




ical Div. 


WYC 


Wycon Chemical Co. 


WBC 


Worthington Biochemical Corp. 


WIN 


Wyandotte Chemicals Corp. 


WBG 


White & Bagley Co. 


wn 


Wyeth Laboratories, Inc., Div. of American 


WGA 


West Coast Adhesives Co. 




Home Products Corp. 


WCC 


Witfield Chemical Corp. 






WES 


Weston Chemical Co., Inc. 


lAW 


Young Aniline Works, Inc. 



198 



SYNTHETIC ORGANIC CHEMICALS, 1967 



Table 22. -- Synthetic organic chemicals; Directory of manufacturers , iS67 --Continued 

SECTION 2. ALPHABETICAL DIRECTORY BY CCWPANY 

[Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. Tariff Commission 
for 1967 are listed below alphabetically, together with their identification codes as used in tables in pt. III. 
Sec. 1 of this table lists these manufacturers in the order of their identification codes] 



Identi- 
fication 
code 



Name of company 



Office address 



Abbott Laboratories 

Abex Corp., American Brakeblok Div 

Aceto Industrial Chemical Co. 

Acme Chemical Co 

Agway, Inc. 

Air Products & Chemicals, Inc., Houndry Proc- 
ess & Chemical Div. 
Air Reduction Co., Inc.: 

Airco Chemicals & Plastics 

Ohio Medical Products Div 

Alco Chemical Corp 

Aloolac Chemical Corp 

Aldrich Chemical Co., Inc 

Alliance Color & Chemical Co 

Allied Chemical Corp. : 

Agricultural Div 

Fabricated Products Div 

Fibers Div 

Plastics Div 

Specialty Chemicals Div 

Union Texas Petroleum Div 

Alox Corp 

Amalgamated Chemical Corp 

Amchem Products, Inc 

Ameraoe-Esna Corp., Chemical Specialities 
Div. 

American Aniline & Extract Co., Inc 

American Aniline Products, Inc 

American Bio-Synthetics Corp 

American Can Co., Marathon Products/Chemioal- 

American Chemical Corp 

American Cyanaraid Co 

American Hoechst Corp 

American Oil Co. (Maryland) 

American Oil Co. (Texas) 

American Potash & Chemical Corp 

American Rubber & Chemical Co 

American Synthetic Rubber Corp 

American Tartars Corp 

Ames laboratories, Inc 

Amoco Chemicals Corp 

Ancon Chemical Corp 

Ansul Chemical Co 

Apex Chemical Co., Inc 

Applied Plastics Co., Inc 

Arapahoe Chemicals, Div. of Syntex Corp 

Ardmore Chemical Co 

Arenol Chemical Corp 

Argus Chemical Corp 

U.S. Peroxygen Div 

Arizona Chemical Co 

Arkansas Co., Inc 

Armour & Co. : 

Armour Grocery Products Co. Div 

Armour Industrial Chemical Co. Div 

Armour Agricultural Chemical Co 

Armour Pharmaceutical Co 

Armstrong Cork Co 

Armstrong Paint & Varnish Works, Inc 

Arol Chemical Products Co 

Ashland Oil & Refining Co 

Ashland Chemical Co. Div 

Catalin Corp. Div 



l-ith St. and Sheridan Rd., N. Chicago, IL 60664. 

900 W. Maple Rd., Troy, MI <;8084. 

126-02 Northern Blvd., Flushing, New York, NY 11368. 

2506 N. 32d St., Milwaukee, WI 532<i5. 

I4i6 Buffalo St., Olean, NY 10760. 

1339 Chestnut St., Philadelphia, PA 19107. 



150 E. 'i2d St., New York, NY 10017. 

liOO E. Washington Ave., Madison, WI 53701. 

Trenton Ave. and William St., Philadelphia, PA 19134. 

3440 Fairfield Rd., Baltimore, MD 21226. 

2371 N. 30th St., Milwaukee, WI 53210. 

P.O. Box 326, Ridgefield, NJ 07657. 

40 Rector St., New York, NY 10006. 

40 Rector St., New York, NY 10006. 

1450 Broadway, New York, NY 10018. 

P.O. Box 365, Morristown, NJ 07960. 

Columbia Rd. & Park Ave., Morristown, NJ 07960. 

P.O. Box 2120, Houston, TX 77001. 

3943 Buffalo Ave., Niagara Falls, NY 14302. 

Ontario and Rorer Sts., Philadelphia, PA 19134. 

Brookside Ave., Ambler, PA 19002. 

74 Hudson Ave., Tenafly, NJ 07670. 

Venango and F Sts., Philadelphia, PA 19134. 

P.O. Box 3063, Paterson, NJ 07509. 

710 W. National Ave., Milwaukee, WI 53204. 

708 3d Ave., New York, NY 10017. 

P.O. Box 9247, Long Beach, CA 90810. 

Wayne, NJ 07470. 

129 Quidnick St., Coventry, RI 02816. 
910 S. Michigan Ave., Chicago, IL 60680. 
910 S. Michigan Ave., Chicago, IL 60680. 
3000 W. 6th St., Los Angeles, CA 90005. 
P.O. Box 1034, Louisville, KY 40201. 

P.O. Box 360, 4500 Camp Ground Rd., Louisville, KY 40201. 
420 Lexington Ave., New York, NY 10017. 
200 Rock Lane, Mil ford, CT 06460. 

130 E. Randolph Dr., Chicago, IL 60601. 
1 Stanton St., Marinette, WI 54143. 

1 Stanton St., Marinette, WI 54143. 

200 S. 1st St., Elizabethport, NJ 07206. 

130 Penn St., El Segundo, CA 90246. 

2855 Walnut St., Boulder, CO 80302. 

840 Valley Brook Ave., I^/ndhurst, NJ 07071. 

40-33 23d St., Long Island City, NJ 11101. 

633 Court St., Brooklyn, NY 11231. 

840 Morton Ave., Richmond, CA 94804. 

Wayne, NJ 07470. 

185 Foundry St., Newark, NJ 07105. 

100 S. Wacker Dr., Chicago, IL 60606. 
401 N. Wabash Ave., Chicago, IL 60690. 
P.O. Box 1685, Atlanta, GA 30301. 
P.O. Box 511, Kankakee, IL 60901. 
Liberty and Charlotte Sts., Lancaster, PA 17604. 
1330 S. Kilboum Ave., Chicago, IL 60623. 
371 Wayne St., Jersey City, NJ 07302. 
1401 Winchester Ave., Ashland KY 41101. 
Henry St., Bethel, CT 06801 and P.O. Box 2458, Colum- 
bus, OH 43216. 
170 N. High St., Columbus, OH 43215. 



DIRECTORY OF MANUFACTURERS 199 

TABLE 22. --Synthetic organic chemicals: Directory of manufacturers , 796"--Contiiiued 



Name of company 



Astra Pharmaceutical Products, Ino 

Astor Products, Blue Arrow Div 

Atco Chemical-Industrial Products, Inc., Fine 
Chemical Div. 

Atlantic Chemical Corp 

Atlantic Richfield Co., ARCO Chemical Co. Div- 

Atlantic Tubing & Rubber Co 

Atlas Chemical Industries, Inc 

Atlas Processing Co 

Avisun Corp 

Aztec Chemicals, Inc 

BASF Corp 

Baird Chemical Industries, Inc 

Baker Castor Oil Co 

J. T. Baker Chemical Co 

Baldwin-Montrose Chemical Co., Inc., Montrose 
Chemical Div. 

Baltimore Paint & Chemical Corp" 

J. H. Baxter & Co 

Baxter Laboratories, Inc 

Bayoil Co., Inc 

Beech-Nut, Inc 

Belding Chemical Industries 

Belle Chemical Co., Inc 

Bendix Corp., Friction Materials Div 

Bennett's 

Benzenoid Organics, Inc 

Bemcolors-Poughkeepsie, Inc 

Blackman-Uhler Chemical Co 

Borden Co., Borden Chemical Co. Div 

Borg -Warner Corp. , Marbon Chemical Div 

Walter N. Boysen Co 

Branchf lower Co 

Brand Plastics Co 

Bristol -Meyers Co., Bristol laboratories Div-- 

M. A. Bruder & Sons, Inc 

Bryant Chemical Corp 

Buckeye Cellulose Corp 

Buckman Laboratories, Ino 

Budd Co., Polychem Div 

Burdick & Jackson laboratories, Ino 

Burroughs-Wellcome & Co. (U.S.A.), Ino 

Samuel Cabot, Inc 

Cadet Chemical Corp., Subsidiary of Chemetron 
Noury Corp. 

Calcasieu Chemical Corp 

Gallery Chemical Co 

Cap-Roc, Inc 

Carborundum Co., Coated Abrasives Div 

Cargill, Inc 

Carlisle Chemicals Works, Ino 

Advance Div 

Carpenter-Morton Co 

Carus Chemical Co., Ino 

Celanese Corp. of America: 

Celanese Chemical Co. Div 

Celanese Coatings Co 

Celanese Plastics Co 

Fibers Co. Div 

Central Farmers Fertilizer Co., Fel-Tex Plant- 
Charlotte Chemical Laboratories 

Charmin Paper Products Co 

Chase Chemical Corp 

Chattem Drug & Chemical Co., Chattem Chemicals 
Div. 

Chemagro Crop 

Chembond Corp 



Office address 



7-1/2 Neponset St., Worcester, MA 01606. 
5050 Edgewood Ct., Jacksonville, FL 32203. 
93 Main St., Franklin, NJ 07416. 

P.O. Box 216, Nutley, NJ 07110. 

260 S. Broad St., Philadelphia, PA 19101. 

Mill St., Cranston, RI 02905. 

Wilmington, DE 19899. 

P.O. Box 9188, 35<16 Midway St., Shreveport, LA 71109. 

P.O. Box 312, New Castle, DE 19720. 

P.O. Box 756, Elyria, OH -^035. 

866 3d St., New York, NY 10022. 

185 Madison Ave., New York, NY 10016. 

AO Avenue A, Bayonne, NJ 07002. 

222 Red School Lane, Phillipsburg, NJ 08865. 

100 Lister Ave., Newark, NJ 07105. 

2325 Rollins Ferry Rd., Baltimore, MD 21230. 

1700 South El Camino Real, San Mateo, CA 944-02. 

6301 N. Lincoln Ave., Morton Grove, IL 60053. 

2 Union St., Peabody, MA 01960. 

Church St., Canajoharie, NY 13317. 

1407 Broadway, New York, NY 10018. 

P.O. Box 848, Lowell, NC 28098. 

P.O. Box 238, Troy, NY 12180. 

65 W. 1st South St., Salt Lake City, UT 84110. 

P.O. Box 156, Bellingham, MA 02019. 

75 N. Water St., Poughkeepsie, NY 12601. 

P.O. Box 5627, Spartanburg, SC 29301. 

350 Madison Ave., New York, NY 10017. 

P.O. Box 68, Washington, WV 26181. 

1001 42d St., Oakland, CA 94608. 

4501 Shilshole Ave., NW., Seattle, WA 98101. 

130 E. Randolph Dr., Chicago, II 60601. 

P.O. Box 657, Syracuse, NY 13201. 

52d St. and Grays Ave., Philadelphia, PA 19143. 

6 North St., N. Quinoy, MA 02171. 

2899 Jackson Ave., Memphis, TN 38108. 

1256 N. McLean Blvd., Memphis, TN 38108. 

70 S. Chapel St., Newark, DE 19711. 

1953 S. Harvey St., Muskegon, MI 49442. 

1 Scarsdale Rd., Tuckahoe, NY 10707. 

246 Summer St., Boston, MA 02210. 

2153 Lookport-Oloott Rd., Burt, NY 14028. 

P.O. Box 1522, Lake Charles, LA 70601. 

Callery, PA 16024. 

300 State St., Rochester, MY 14614. 

P.O. Box 477, Niagara Falls, NY 14302. 

Room 2008, 3 Penn Center Plaza, Philadelphia, PA 19102. 

West St., Reading OH 45215. 

500 Jersey Ave., New Brunswick, NJ 08903. 

376 3d St., Everett, MA 02149. 

1375 8th St., LaSalle, IL 61301. 

245 Park Ave., New York, NY 10036. 
1481 S. 11th St., Louisville, KY 40208. 
550 Broad St., Newark, NJ 07102. 
P.O. Box 1414, Charlotte, NC 28201. 
P.O. Box 68, Fremont, NB 68025. 
P.O. Box 948, Charlotte, NC 28201. 
800 Hoberg St., Green Bay, WI 54305. 
3527 Smallman St., Pittsburgh, PA 15201. 
1715 W. 38th St., Chattanooga, TN 37409. 

P.O. Box 4913, Station "F", Kansas City, MO 64120. 
P.O. Box 270, Springfield, OR 97477. 



200 , SYNTHETIC ORGANIC CHEMICALS, 1967 

TABLE 22. --Synthetic organic chemicals: Directory of manufacturers , iS67- -Continued 



Identi- 
fication 
code 



Name of company 



DAN 
DYS 
PDJ 

DLI 



Cheraetron Corp. : 

Chemetron Chemicals, Organic Chemical Dept. 

National Cylinder Gas Div 

Chem-Fleur, Inc 

Chemical Formulators, Inc 

Chemical Insecticide Corp 

Chemical Products Corp 

Chemioo, Inc 

Chemlek Laboratories, Inc 

Chemol, Inc 

Chevron Chemical Co 

Childs Pulp Colors, Inc 

Chipman Chemical Co., Inc 

Ciba Chemical & Dye Co 

Ciba Corp. : 

Ciba Argochemioal Co 

Ciba Pharmaceutical Co. Div 

Ciba Products Co 

Cities Service Oil Co 

Clark Oil & Refining Corp 

W. A. Cleary Corp 

Clintwood Chemical Co 

Clover Chemical Co 

Coastal States Petrochemical Co 

Cockerille Chemicals, Inc 

Colab Resin Corp 

Colgate-Palmolive Co-« 

Collier Carbor & Chemical Corp 

Colloids, Inc 

Colonial Sugars Co., Suoro-Chemioal Div 

Columbia Nitrogen Corp 

Columbia Nipro Corp 

Columbia Organic Chemicals Co., Inc 

Columbian Carbon Co 

Chemicals Div 

Commercial Products Co., Inc 

Commercial Solvents Corp 

Commonwealth Oil Refining Co., Inc 

Cone heme o. Inc. : 

H.B. Davis Co. Div 

Seidlitz Paint Co. Div 

Concord Chemical Co., Inc 

Consolidated Papers, Inc 

Continental Chemical Co 

Continental Oil Co 

Cook Paint & Varnish Co 

Cooperative Farm Chemicals Association 

Coopers Creek Chemical Corp 

Copolymer Rubber & Chemical Corp 

Corn Products Co 

Acme Resin Co. Div 

Cosden Oil & Chemical Co 

Cowles Chemical Co 

Benzol Products Div 

Crest Chemical Corp 

Croda, Inc 

Crompton & Knowles Corp., Chemicals Group, 
Althouse & Bates Div. 

Crosby Chemicals, Inc 

Crown Central Petroleum Corp 

Crown Zellerbach Corp., Chemical Products Div. 

Culver Chemical Co 

Cutter Laboratories, Inc 

Dan River Mills, Inc 

Davles-Young Soap Co 

Joseph Davis Plastics Co 

Dawe's Laboratories, Inc 



Office address 



393 7th Ave., New York, NY and Wilmington Industrial 
Park, Wilmington, DE 19801. 

84.0 N. Michigan Ave., Chicago, IL 60611. 

200 Pulaski St., Newark, NJ 07105. 

P.O. Box 26, Nitre, WV 25U3. 

20 Whitman Ave., Metuchen, NJ 08840. 

P.O. Box AA9, Cartersville, GA 30120. 

2508 E. Bailey Rd., Cuyahoga Falls, OH 44221. 

4040 W. 123d St., Alsip, IL 60658. 

P.O. Box 20687, Greensboro, NC 27420. 

940 Hensley St., Richmond, CA 94801 and 200 Bush St., 

San Francisco, CA 94120. 
43 Summit St., Brooklyn, NY 11231. 
120 Jersey Ave., New Brunswick, NJ 08903. 
Route 208, Fair Lawn, NJ 07410. 

556 Morris Ave., Summit, NJ 07901. 

556 Morris Ave., Summit, NJ 07901. 

556 Morris Ave., Summit, NJ 07901. 

P.O. Box 300, Tulsa, OK 74101. 

131st St. and Kedzie Ave., Blue Island, IL 60406. 

P.O. Box 749, New Brunswick, NJ 08903. 

4342 S. Wolcoth Ave., Chicago, IL 60609. 

P.O. Box 146, Eighty Four, PA 15330. 

6th Fl., Lincoln Liberty Life Bldg., Houston, TX 77002. 

Greenwood, VA 22943. 

Main St., Tewksbury, MA 01876. 

300 Park Ave., New York, NY 10022. 

714 W. Olympic Blvd., Los Angeles, CA 90015. 

394 Frelinghuysen Ave., Newark, NJ 07114. 
Drawer G, Grameroy, LA 70052. 

P.O. Box 1483, Augusta, GA 30903. 
P.O. Box 1483, Augusta, GA 30903. 
912 Drake St., Columbia, SC 29205. 
380 Madison Ave., New York, NY 10017. 
P.O. Box 1522, Lake Charles, LA 70601. 
117 Ethel Ave., Hawthorne, NJ 07641. 
245 Park Ave., New York, NY 10017. 
G.P.O. Box 4065, San Juan, PR 00936. 

Bayard & Severn Sts., Baltimore, MD 21230. 

18th & Garfield Sts., Kansas City, MO 64127. 

205 S. 2d St., Camden, NJ 08103. 

P.O. Box 50, Wisconsin Rapids, WI 54494. 

270 Clifton Blvd., Clifton, iW 07015. 

9 Rockefeller Plaza, New York, NY 10020. 

1412 Knox, N. Kansas City, MO 64116. 

P.O. Box 308, Lawrence, KS 66044. 

River Rd., W. Conshohocken, PA 19428. 

P.O. Box 2591, Baton Rouge, LA 70821. 

717 5th Ave., New York, NY 10022. 

1401 S. Circle Ave., Forest Park, IL 60130. 

P.O. Box 1311, Big Spring, TX 79720. 

12000 Shaker Blvd., Cleveland, OH 44120. 

Mento Park Office Bldg., Edison, NJ 08817. 

225 Emmet St., Newark, NJ 07114. 

51 Madison Ave., New York, NY 10010. 

500 Pear St., Reading PA 19603. 

P.O. Drawer 32, DeRidder, LA 70634. 
P.O. Box 1168, Baltimore, MD 21203. 
Camas, WA 98607. 

1502 N. 25th St., Melrose Park, IL 60160. 
4th and Parker Sts., Berkeley, CA 94710. 

Danville, VA 24541. 

705 Albany St., Dayton, OH 45401. 

450 Schuyler Ave., Kearny, NJ 07032. 

4800 S. Richmond St., Chicago, I L 60632. 



DIRECTORY OF MANUFACTURERS 201 

TABLE 22. --Synthetic organic chemicals.- Directory of manufacturers, i567- -Continued 




Office address 



Degen Oil & Chemical Co 

DePaul Chemical Co., Inc 

DeSoto, Inc -^ — 

Detrex Chemical Industries, Inc 

Dexter Corp 

Hysol Co. Div - 

Diamond Shamrock Corp 

Diversey Corp 

Dixie Chemical Co 

Dixie Chemical Products, Inc 

Dixie Pine Products Co., Inc 

Dominion Products, Inc 

Dover Chemical Co 

Dow Badische Co 

Dow Chemical Co 

Dow Coming Corp 

Drew Chemical Corp 

Frank W. Dunne Co 

E. I. duPont de Nemours & Co., Inc 

Dye Specialties, Inc 

Eastern Color & Chemical Co 

Eastman Kodak Co 

Tennessee Eastman Co. Div 

Texas Eastman Co. Div 

East Shore Chemical Co., Inc 

El Dorado Chemical Co 

Electro-Seal Glasflex Corp 

El Paso Products Co 

Bnery Industries, Inc 

Western Div 

Bnkay Chemical Co 

Endo Laboratories, Inc 

Enenco, Inc 

Enjay Chemical Co 

Enjay Fibers & Laminates Co. Div 

Epoxylite Corp 

Escambia Chemical Corp 

Ethyl Corp 

Ethyl-Dow Chemical Co 

Evans Chemetics, Inc 

FMC Corp. : 

American Viscose Div 

Inorganic Chemicals Div 

Niagara Chemical Div 

Organic Chemicals Div 

Organic Chemicals Div 

Nitro Plant 

Fabricolor Manufacturing Corp 

Fairmount Chemical Co., Inc 

Farao Oil & Chemical Co., Div. of Handschy 
Chemical Co. 

Far-Best Corp., 0. L. King Div 

Fanners Chemical Association, Inc 

Farmer's Chemical Co 

Famow, Inc 

Federal Color laboratories, Inc 

Felton International, Inc 

Ferro Corp., Ferro Chemical Div 

Fibreboard Corp 

Filtered Rosin Products Co 

Fine Organics, Inc 

Firestone Tire Sc Rubber Co. : 

Firestone Industrial Rubber Products Div-— 

Firestone Plastics Co. Div 

Firestone Synthetic Rubber Sc Latex Co. Div- 
First Chemical Corp 



200 Kellogg St., Jersey City, NJ 07305. 
<i'i-27 Purvis St., Long Island City, NY 11101. 
1700 S. Mt. Prospect Ave., Des Plaines, IL 60018. 
1"4331 Woodrow Wilson, Detroit, MI 48232. 
845 Edgewater Rd., Bronx, NY 10474. 

211 Franklin St., Olean, NY 14760. 

300 Union Commerce Bldg., Cleveland, OH 44114. 

212 W. Monroe St., Chicago, IL 60606. 
P.O. Box 13410, Houston, TX 77019. 
P.O. Box 13410, Houston, TX 77019. 
P.O. Box 470, Hattiesburg, MS 39401. 
882 3d Ave., Brooklyn, NY 11232. 
15th and Davis Sts., Dover, OH 44622. 
Drawer D, Williamsburg, VA 23185. 
Hopkins Bldg., Midland, MI 48640. 
P.O. Box 582, Midland, MI 48640. 

416 Division St., Boonton, NJ 07005. 
1007 41st St., Oakland, CA 94608. 
DuPont Bldg., Wilmington, DE 19898. 
26 Journal Sq., Jersey City, NJ 07306. 

35 Livingston St., Providence, RI 02904. 

343 State St., Rochester, HY 14650. 

P.O. Box 511, Kingsport, TN 37662. 

P.O. Box 2068, Longview, TX 75601. 

1180 Michigan Ave., Muskegon, MI 49440. 

P.O. Box 599, Oakland, CA 94604. 

Stirling, NJ 07980. 

P.O. Box 3986, Odessa, TX 79760. 

4300 Carew Tower, Cincinnati, OH 45202. 

8733 S. Dice Rd., Santa Fe Springs, CA 90670. 

319 2d St., Elizabeth, NJ 07206. 

1000 Stewart Ave., Garden City, NY 11530. 

P.O. Box 398, Memphis, TN 38101. 

60 W. 49th St., New York, NY 10020. 

Odenton, MD 21113. 

P.O. Box 3397, 1428 N. Tyler Ave., S. El Monte, CA 91733. 

P.O. Box 467, Pensacola, FL 32502. 

330 S. 4th St., Richmond, VA 23217. 

Midland, MI 48640. 

250 E. 43d St., New York, NY 10017. 



1617 John F. Kennedy Blvd., Philadelphia, PA 19103. 

P.O. Box 8127, S. Charleston, WV 25303 and Sawyer Ave. & 

River Rd., Town of Tonawanda, NY 14150. 
100 Niagara St., Middleport, NY 14105. 
633 3rd Ave., New York, NY 10017. 
1701 Patapsco Dr., Baltimore, MD 21226. 
P.O. Box 547, Nitro, WV 25143. 
24-1/2 Van Houten St., Paterson, NJ 07505. 
117 Blanchard St., Newark, NJ 07105. 
147th St. and Indiana Ave., Chicago, I L 60627. 

640 Oilman St., Berkeley, CA 94710. 

P.O. Box 67, Tyner, TN 37392. 

P.O. Box 591, 3713 W. Main St., Kalamazoo, MI 49005. 

77 Jacobus Ave., S. Kearny, NJ 07032. 

4526 Chlckering Ave., Cincinnati, OH 45232. 

599 Johnson Ave., Brooklyn, NY 11237. 

P.O. Box 349, 7050 Krick Rd., Bedford, OH 44014. 

P.O. Box 4314, Oakland, CA 94623. 

P.O. Box 349, Baxley, GA 31513. 

205 Main St., Lodl, NJ 07644. 

P.O. Box 2290, Fall River, MA 02777. 
P.O. Box 699, Pottstown, PA 19464. 
381 W. Wllbeth Rd., Akron, OH 44301. 
P.O. Box 1427, Pascagoula, MS 39567. 



202 SYNTHETIC ORGANIC CHEMICALS, 1967 

TABLE 22. --Synthetic organic chemicals; Directory of manufacturers , i5'67--Continued 



Identi- 
fication 
code 



Name of conpany 



Office address 



Fisher Chemical Co., Inc 

Fisher Melamine Corp 

Fleming Laboratories, Inc 

Florasynth Laboratories, Inc 

Foote Mineral Co 

Formica Corp 

Foster Grant Co., Inc 

Foster-Heaton Co 

France, Campbell & Darling, Inc 

Franklin Chemical Co 

Freeman Chemical Corp 

Frisch & Co., Inc 

Fritzsche Bros., Inc 

H. B. Fuller Co 

Fuller-O'Brien Corp 

Cane's Chemical Works, Inc 

Geigy Chemical Corp 

General Aniline & Film Corp. ; 

Dyestuff & Chemical Div 

Textile Finishes Dept., Textile Chemical 
Div. 

General Electric Co. : 

Chemical Materials Dept 

Insulating Materials Dept 

Silicone Products Dept 

General Foods Corp., Maxwell House Div 

General Latex & Chemical Corp 

General Mills, Inc 

Chemical Div 

General Plastics Manufacturing Co 

General Tire & Rubber Co., Chemical Div 

P. D. George Co 

Georgia-Pacific Corp. : 

Bellingham Div 

Coos Bay Div 

Getty Oil Co 

Gillette Chemical Co., Div. of Gillette Co 

Gilman Paint & Varnish Co 

Givaudan Corp 

Glyco Chemicals, Inc 

B. F. Goodrich Co., B. F. Goodrich Chemical Co 
Div. 

Goodrich-Gulf Chemicals, Inc 

Goodyear Tire & Rubber Co 

Gordon Chemical Co., Inc 

W. R. Grace & Co. : 

Agricultural Products Div 

Dewey & Almy Chemical Div 

Dubois Chemicals Div 

Hampshire Chemical Div 

Hatoo Chemical Div 

Marco Chemical Div 

Vestal Laboratories Div 

Grain Processing Corp 

Great American Plastics Co 

Great Lakes Chemical Corp 

Great Western Sugar Co 

Grow Chemical Corp., Harris Paint Co. Div 

Guardsman Chemical Coatings, Inc 

Gulf Oil Corp 

Perkins Glue, Chemicals Dept 

Guth Chemical Co 

H & N Chemical Co 

Haag Laboratories, Inc 

Halby Products Co., Inc 

C. P. Hall Co. of Illinois 



580 Sylvian Ave., Englewood, NJ 07632. 

AlO Park Ave., New York, NY 10022. 

P.O. Box 10372, Charlotte, NC 28201. 

900 Van Nest Ave., Bronx, NY 10462. 

Route 100, Exton, PA 193';i . 

"ieW Spring Grove Ave., Cincinnati, OH -45232. 

289 N. Main St., Leominster, MA 01'i53. 

16 E. 5th St., Paterson, NJ 07524. 

N. Michigan Ave., Kenilworth, NJ 07033. 

2020 Bruck St., Columbus, OH 43207. 

222 E. Main St., Port Washington, WI 53074. 

88 E. 11th St., Paterson, NJ 07524. 

76 9th Ave., New York, NY 10011. 

1150 Eustic St., St. Paul, MN 55108. 

450 E. Grand Ave., S. San Francisco, CA 94080. 

535 5th Ave., New York, NY 10017. 

444 Saw Mill River Rd., Ardsley, NY 10502. 

P.O. Box 12, Linden, NJ 07036. 

1228 Chestnut St., Chattanooga, IN 37402. 



1 Plastics Ave., Coshocton, OH 43812, and 1 Plastics 

Ave., Pittsfield, MA 01203. 
1 River Rd., Schenectady, NY 12305. 
Mechanic ville Rd., Waterford, NY 12188. 
1125 Hudson St., Hoboken, NJ 07030. 
666 Main St., Cambridge, MA 02139. 
S. Kensington Rd., Kankakee, IL 60901. 
Quimby St., Ossining, NY 10562. 
3481 S. 35th St., Tacoma, WA 98409. 
1708 Englewood Ave., Akron, OH 44309. 
5200 N. 2d St., St. Louis, MO 63147. 

P.O. Box 1236, Bellingham, WA 98225. 

P.O. Box 869, Coos Bay, OR 97420. 

Delaware City, DE 19706. 

P.O. Box 362, N. Chicago, IL 60064. 

W. 8th and Pine Sts., Chattanooga, TN 37401. 

125 Delawanna Ave., Clifton, NJ 07014. 

417 5th Ave., New York, NY 10016. 

3135 Euclid Ave., Cleveland, OH 44137. 

1717 E. 9th St. , Cleveland, OH 44114. 
1144 E. Market St., Akron, OH 44316. 
88 Webster St., Worcester, MA 01603. 

P.O. Box 277, 147 Jefferson Ave., Memphis, TN 38101. 

62 Whittemore Ave., Cambridge, MA 02140. 

634 Broadway, Cincinnati, OH 45202. 

Poisson Ave., Nashua, NH 03060. 

629 Amboy St., Edison, NJ 08817. 

1711 W. Elizabeth Ave., Linden, NJ 07036. 

4963 Manchester Ave., St. Louis, MO 63110. 

1600 Oregon St., Muscatine, lA 52761. 

85 Water St., Fitohburg, MA 01420. 

P.O. Box 2200, West Lafayette, IN 47906. 

P.O. Box 5308, Terminal Annex, Denver, CO 80217. 

1010-26 N. 19th St., Tampa, FL 33601. 

1350 Steele Ave. SW., Grand Rapids, MI 49502. 

P.O. Box 2100, Houston, TX 77001. 

632 Cannon Ave., Lansdale, PA 19446. 

332 S. Center St., Hillside, IL 60162. 

90 Maltese Dr., Totowa, NJ 07512. 
14010 S. Seeley, Blue Island, IL 60406. 
P.O. Box 366, Wilmington, DE 19899. 
7300 S. Central Ave., Chicago, IL 60638. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. --Synthetic organic chemicals: Directory of manufacturers , i567--Continued 



203 



Name of company 



Office address 



Hampden Color & Chemical Co 

Hanna Paint Manufacturing Co., Inc 

Harshaw Chemical Co., Div. of Kewanee Oil Co- 
Hart Products Corp 

Haveg Industries, Inc 

Hawkeye Chemical Co 

Hercor Chemical Corp 

Hercules, Ino 

Imperial Color & Chemical Dept 

Heresite & Chemical Co 

Hershey Estates, Inc 

Hess Oil & Chemical Corp 

Heterochemical Corp 

Hewitt Soap Co 

Hexagon Laboratories, Inc 

Hodag Chemical Corp 

Hoffmann-LaRoche, Inc 

Hoffman-Taff, Inc 

Holland-Suco Color Co 

Hooker Chemical Corp 

Durez Div 

Ruco Div 

E. F. Houghton & Co 

Houston Chemical Corp 

Humphrey Chemical Co 

Philip A. Hunt Chemical Corp., Wayland Chemi- 
cal Div. 

Huntington Laboratories, Inc 

Husky Briquetting, Ino 

Hynson, Westcott & Dunning, Inc 

I.C.I./Organics/lnc 

IRC, Inc 

ITT Rayonier, Inc 

Imoco Corp., Chemical Services Div 

Industrial Bioohemicals, Inc 

Industrial Dyestuff Co 

Inland Steel Co. , Inland Steel Container Co-- 

Interchemical Corp. : 

Color & Chemicals Div 

Finishes Div 

Organic Chemicals Dept 

International Flavors & Fragrances, Inc 

International latex & Chemical Corp 

Paisley Products Div 

International Minerals & Chemical Corp 

Inter-Pacific Resins, Inc 

Interplastic Corp., Commercial Resins Div 

Ironsides Resins, Inc 

Isocyanate Products, Inc 

Jefferson Chemical Co., Inc 

Jennison -Wright Corp 

Jeras Corp 

Andrew Jergens Co 

Jersey State Chemical Co 

Jewel Paint & Varnish Co 

S. C. Johnson & Son, Inc 

Jones-Blair Paint Co 

Jordan Chemical Co 

Kaiser Aluminum & Chemical Corp. : 

Kaiser Agricultural Chemicals Div 

Kaiser Chemicals Div 

Kali Manufacturing Co 

Kay-Fries Chemicals, Inc 

Kelly-Moore Paint Co 

Kelly-Pickering Chemical Corp 

Kennecott Copper Corp. : 

Chino Mines Div 

Utah Copper Div 



5 Albany St., Springfield, MA 01101. 

P.O. Box 147, Columbus, OH "43216. 

19-15 E. 97th St., Cleveland, OH 4<H06. 

WAO Broadway, New York, NY 10018. 

900 Greenbank Rd., Wilmington, DE 19808. 

P.O. Box 899, Clinton, lA 52733. 

P.O. Box 4198, Ponce, PR 00731. 

Hercules Tower, 910 Market St., Wilmington, DE 19899. 

P.O. Box 231, Glens Falls, NY 12803. 

822 S. Uth St., Manitowoc, WI 54220. 

1 W. Chocolate Ave., Hershey, PA 17033. 

State St., Perth Amboy, NJ 08862. 

Ill E. Hawthorne Ave., Valley Stream, NY 11757. 

333 Linden Ave., Dayton, OH 45403. 

3536 Peartree Ave., Bronx, NY 10469. 

7247 N. Central Park Ave., Skokie, IL 60076. 

324 Klngsland Rd., Nutley, NJ 07110. 

P.O. Box 1246 S.S.S., Springfield, MO 65805. 

P.O. Box 2166, Huntington, WV 25722. 

Buffalo Ave. & 47th St. Niagara Falls, m 14302. 

Walck Rd., N. Tonawanda, NY 14121. 

New South Rd., Hicksville, L.I., NY 11802. 

303 W. Lehigh Ave., Philadelphia, PA 19133. 

1 Gateway Center, Pittsburgh, PA 15222. 

Devine St., North Haven, CT 06473. 

P.O. Box 0, Lincoln, RI 02865. 

P.O. Box 710, Huntington, IN 46750. 

P.O. Box 380, Cody, WY 82414. 

Charles and Chase Sts., Baltimore, }M) 21201. 

P.O. Box 1274, 151 South St., Stamford, CT 06904, 

401 N. Broad St., Philadelphia, PA 19108. 

161 E. 42d St., New York, NY 10017. 

Howard & West Sts., Baltimore, MD 21230- 

U.S. Highway #1, Edison, NJ 08817. 

P.O. Box 4249, E. Providence, RI 02914. 

4300 W. 130th St., Chicago, IL 60658. 

150 Wagaraw Rd., Hawthorne, NJ 07506. 

5935 Milford Ave., Detroit, MI 48210. 

Berry Ave. and Route 17, Carlstadt, NJ 07072. 

521 W. 57th St., New York, NY 10019. 

P.O. Drawer K, Playtex Park, Dover, DE 19901. 

1770 Canalport Ave., Chicago, IL 60616. 

5401 Old Orchard Rd., Skokie, IL 60078. 

P.O. Box 445, 1602 N. 18th Ave., Sweet Home, OR 97386. 

2015 NE. Broadway St., Minneapolis, MN 55413. 

270 W. Mound St., Columbus, OH 43216. 

900 Wilmington Rd., New Castle, DE 19720. 

P.O. Box 53300, Houston, TX 77052 

P.O. Box 691, Toledo, OH 43601. 

17 N. 7th St., Allentown, PA 18105. 

2535 Spring Grove Ave., Cincinnati, OH 45214. 

59 Lee Ave., Haledon, NJ 07508. 

345 N. Western Ave., Chicago, IL 60612. 

1525 Howe St., Racine, WI 53403. 

6969 Denton Dr., Dallas, TX 75235. 

325 Barclay Bldg.,- 1 Belmont Ave., Bala Cynwyd, PA 19004. 



P.O. Box 246, Savannah, GA 31402. 

P.O. Box 337, Grameroy, LA 70052. 

427 Moyer St., Philadelphia, PA 19125. 

360 Lexington Ave., New York, NY 10017. 

1015 Commercial St., San Carlos, CA 94070. 

956 Bransten Rd., San Carlos, CA 94070. 

Hurley, NM 88043. 

P.O. Box 11299, Salt Lake City, UT 84111. 



204 SYNTHETIC ORGANIC CHEMICALS, 1967 

TABLE 22. -Synthetic organic chemicals: Directory of manufacturers, i 567 --Continued 



Name of company 



Kenrioh Petrochemicals, Inc 

Ketona Chemical Corp 

Keysor Chemical Co 

Keystone Chemurglc Corp 

Keystone Color Works, Inc 

Knapp Products, Inc 

Knoedler Chemical Co 

Kohler-McLister Paint Co 

H. Kohnstamm & Co., Inc 

Koppers Co., Inc., Organic Materials Div 

Koppers Pittsburgh Co 

Kyanize Paints, Inc 

Lakeside Laboratories, Div. of Colgate- 
Palmolive Co. 

Lake States, Div. of St. Regis Paper Co 

Lakeway Chemical Co 

LaMotte Chemical Products Co 

Lasco Industries, Inc 

laurel Products Corp 

Lawter Chemicals, Inc., Krumbhaar Resin Div--- 

Leatex Chemical Co 

Lebanon Chemical Corp 

Lehn & Fink Products Corp., Beacon Div 

B. L. Lemke & Co., Inc 

Leonard Refineries, Inc 

Lever Brothers Co 

C. Lever Co., Inc 

Fred'k H. Levey Co., Inc 

Lignin Products Co 

Eli Lilly & Co 

Lubrizol Corp 

George Lueders & Co., Inc 

M & T Chemicals, Inc 

Magruder Color Co., Inc 

Maher Color & Chemical Co 

Mallinckrodt Chemical Works 

Marathon Oil Co., Texas Refining Div 

Marblette Co., Div. of Allied Products Corp 

Marden-Wild Corp 

Marlowe-Van Loan Corp 

Martin-Marietta Corp. : 

Ridgway Color & Chemical Div 

Southern Dyestuff Co. Div 

Max Marx Color & Chemical Co 

Masonite Corp., Alpine Chemical Div 

Ma the Chemical Co., Div. of Norac Co., Inc 

Maumee Chemical Co 

Otto B. May, .Inc 

McCloskey Varnish Co 

McLaughlin Gormley King Co 

Medical Chemicals Corp 

Merck & Co., Inc 

Merichem Co 

Metalead Products Corp 

Metro-Atlantic, Inc 

J. Meyer & Sons, Inc 

Michigan Chemical Corp 

Midland Industrial Finishes Co 

Miles Laboratories, Inc., Marschall Div 

Millmaster Onyx Corp. : 

Millmaster Chemical Div., Berkeley Chemical 
Dept. 

A. Gross & Co. Div 

Onyx Chemical Div 

Mineral Oil Refining Co 

Minnesota Mining & Manufacturing Co 

Minnesota Paints, Inc 

Miranol Chemical Co., Inc 



Office address 



Foot of E. 22d St., Bayonne, NJ 07002. 

P.O. Box 6565, Tarrant Branch, Birmingham, AL 35217. 

26000 Bouquet Canyon Rd., Saugus, CA 91350. 

R.D. 2, Bethlehem, PA 18017. 

151 W. Gay Ave., York, PA 17'i03. 

180 Hamilton Ave., Lodi, NJ 076^^. 

651 High St., Lancaster, PA 1760-4 . 

P.O. Box 54.6, Denver, CO 80201. 

161 Avenue of the Americas, New York, NY 10013. 

Koppers Bldg., Pittsburgh, PA 15219. 

Koppers Bldg., Pittsburgh, PA 15219. 

2d and Boston Sts., Everett, MA 02149. 

1707 E. North Ave., Milwaukee, WI 53201. 

603 W. Davenport St., Rhinelander, WI 54501. 

5025 Evanston Ave., Muskegon, MI 49443. 

Chestertown, MD 21620. 

1561 Chapin Rd., Montebello, CA 90640. 

2600 E. Tioga St., Philadelphia, PA 19134. 

3550 Touhy Ave., Chicago, IL 60645. 

2722 N. Hancock St., Philadelphia, PA 19133. 

P.O. Box 180, Lebanon, PA 17042. 

33 Richdale Ave., Cambridge, MA 02140. 

199 Main St., Lodi, NJ 07644. 

E. Superior St., Alma, Ml 48801. 

390 Park Ave., New York, NY 10022. 

Howard and Huntington Sts., Philadelphia, PA 19133. 

380 Madison Ave., New York, NY 10017. 

P.O. Box 960, Erie, PA 16512. 

740 S. Alabama St., Indianapolis, IN 46206. 

29400 Lakeland Blvd., Wickliffe, OH 44117. 

427 Washington St., New York, NY 10013. 

Woodbridge Rd. and Randolph Ave., Rahway, NJ 07065. 

1 Virginia St., Newark, NJ 07114. 

1700 N. Elston Ave., Chicago, IL 60622. 
3600 N. 2nd St., St. Louis, MO 63147. 
P.O. Box 1191, Texas City, TX 77590. 
37-31 30th St., Long Island City, NY 11101. 
500 Columbia St., Somerville, MA 02143. 
1511 Joshua Circle, High Point, NC 27260. 

75 Front St., Ridgway, PA 15853. 

P.O. Box 10098, Charlotte, NC 28201. 

192 Coit St., Irvington, NJ- 07111. 

P.O. Box 2392, Gulfport, MS 39503. 

169 Kennedy Dr., Lodi, NJ 07644. 

1310 Expressway Dr., Toledo, OH 43608. 

52 Amsterdam St., Newark, NJ 07105. 

7600 State Rd., Philadelphia, PA 19136. 

1715 SE. 5th St., Minneapolis, MN 55414. 

4541 W. Grand Ave., Chicago, IL 60639. 

126 E. Lincoln Ave., Rahway, NJ 07065. 

1914 Haden Rd., Houston, TX 77015. 

P.O. Box 11005, 2901 Park Blvd., Palo Alto, CA 94306. 

2027 Smith St., Centerdale, RI 02911. 

4321 N. 4th St., Philadelphia, PA 19140 

2 N. Riverside Plaza, Chicago, IL 60606. 
E. Water, St., Waukegan, IL 60086. 

Myrtle and McNaughton Sts., Elkhart, IN 46514. 

99 Park Ave., New York, NY 10016. 

295 Madison Ave., New York, NY 10017. 

Warren and Morris Sts., Jersey City, NJ 07302. 

4401 Park Ave., Dickinson, TX 77539. 

3M Center, St. Paul, MN 55101. 

1101 S. 3d St., Minneapolis, MN 55415. 

277 Coit St., Irvington, NJ 07111. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. --Synthetic organic chemicals.- Directory of manufacturers , 7967- -Continued 



205 



Name of oon^iany 



Office address 



Mississippi Chemical Corp 

Mobay Chemical Co 

Mobil Chemical Co 

htobil Oil Corp 

Mobil Chemical Co. Div., Industrial Chemical 
Div. 

Molded Fiber Glass Body Co 

Mona Industries, Inc 

Monochem, Inc 

Monsanto Co 

Bircham Bend Plant 

Chocolate Bayou Plant 

Gering Plastics Dept 

Plastics Div 

Textiles Div 

Western Div 

Montrose Chemical Corp. of California 

Mooney Chemicals, Inc 

Benjamin Moore & Co 

Moretex Chemical Products, Inc 

Morton Chemical Co 

Motomco, Inc 

NVF Co 

Nalco Chemical Co 

National Biochemical Co 

National Casein Co 

National Dairy Products Corp. ; 

Humko Products Chemical Div 

Sheffield Chemical Div 

National Distillers & Chemical Corp. : 

National Petro Chemical Corp. Div 

U.S. Industrial Chemicals Co. Div 

National Lead Co 

National Milling & Chemical Co., Inc 

National Polychemicals, Inc 

National Starch & Chemical Corp 

Nease Chemical Co., Inc 

Nepera Chemical Co., Inc 

Neville Chemical Co 

Nilok Chemicals, Inc 

Nipak, Inc 

Nitrin, Inc 

A. P. Nonweiler Co 

Norac Co., Inc 

Norda Essential Oil Sc Chemical Co., Inc 

Norris Paint & Varnish Co 

Norse Chemical Corp 

North American Chemical Co 

Northern Petrochemical Co., Varney Div 

Northrop Carolina, Inc 

Northwestern Chemical Co 

Northwest Petrochemical Corp 

Norwich Pharmacal Co 

Texlze Chemicals, Inc. Div 

Nostrip Chemical Works, Inc 

Novamont Corp., Neal Works 

Nyanza, Ino 

O'Brien Corp 

Occidental Petroleum Corp., Occidental Chemi- 
cal Co. Div. 

Olin Mathieson Chemical Corp 

Agricultural Div 



P.O. Box 388, Yazoo City, MS 39191. 

Penn Lincoln Parkway, W. Pittsburgh, PA 15205. 

P.O. Box 3868, Beaumont, TX 77704; 7301 Bessemer Ave., 
Cleveland, OH 'i'il27; 12815 Elmwood St., Cleveland, 
OH 4^111; P.O. Box 250, Edison, NJ 08817 and 1630 W. 
Hill St., Louisville, KY "40210. 

612 S. Flower St., Los Angeles, CA 90054. 

■401 E. Main St., Richmond, VA 23208. 

"4601 Benefit Ave., Ashtabula, OH ^^OO^. 

65 E. 23d St., Paterson, NJ 0752-4. 

P.O. Box "488, Geismar, LA 70734. 

800 N. Lindbergh Blvd., St. Louis, MO 63166. 

190 Grochmal Ave., Indian Orchard, MA 01051. 

P.O. Box 711, Alvin, TX 77511. 

200 N. 7th St., Kenilworth, NJ 07033. 

730 Worcester St., Springfield, MA 01101; 5100 W. 
Jefferson Ave., Trenton, MI 48183; River Rd., 
Addyston, OH 45001, and P.O. Box 1311, Texas City, 
TX 77591. 

800 N. Lindbergh Blvd., St. Louis, MO 63166. 

9229 E. Marginal Way S. , Seattle, WA 98108. 

500 S. Virgil Ave., Los Angeles, CA 90005. 

2301 Scranton Rd., Cleveland, OH 44113. 

548 5th Ave., New York, NY 10036. 

314 W. Henry St., P.O. Box 1799, Spartanburg, SC 29301. 

110 N. Wacker Dr., Chicago, IL 60606. 
89 Terminal Ave., Clark, NJ 07066. 

700 Maryland Ave., Wilmington, DE 19805. 
180 N. Michigan Ave., Chicago, IL 60601. 
3127 W. Lake St., Chicago, IL 60612. 
601 W. 80th St., Chicago, IL 60620. 

5050 Poplar Ave., Memphis, TN 38117. 
2400 Morris Ave., Union, NJ 07083. 

99 Park Ave., New York, NY 10016. 
99 Park Ave., New York, NY 10016. 

111 Broadway, New York, NY 10006. 

4601 Flat Rock Rd., Philadelphia, PA 19127. 

51 Fames St., Wilmington, MA 01887. 

750 3d Ave., New York, NY 10017. 

P.O. Box 221, State College, PA 16801. 

Route 17, Harrlman, NY 10926. 

Neville Island P.O., Pittsburgh, PA 15225. 

Mill St. and N. Transit Rd., Lockport, NY 14094. 

301 S. Harwood St., Dallas, TX 75221. 

P.O. Box 233, Cordova, IL 61242. 

P.O. Box 1007, Oshkosh, WI 54901. 

405 S. Motor Ave., Azusa, CA 91703. 

475 10th Ave., New York, NY 10001. 

P.O. Box 2023, Salem, OR 97308. 

2121 Norse Ave., Cudahy, WI 53110. 

19 S. Canal St., Lawrence, MA 01843. 

2001 Afton Rd., Janesville, WI 53545. 

P.O. Box 3049, Asheville, NC 28802. 

120 N. Aurora St., W. Chicago, IL 60185. 

P.O. Box 99, Anaoortes, WA 98221. 

17 Eaton Ave., Norwich, NY 13815. 

P.O. Box 368, Greenville, SC 29602. 

182 Liberty Ave., Jamaica, NY 11433. 

P.O. Box 189, Kenova, WV 25530. 

P.O. Box 349, Ashland, MA 01721. 

2001 W. Washington Ave., South Bend, IN 46621. 
P.O. Box 198, Lathrop, CA 95330. 

445 W. 59th St., New York, NY 10019. 
1120 Marshall St., Little Rock, AR 72203. 



206 SYNTHETIC ORGANIC CHEMICALS. 1967 

TABLE 22. --Synthetic organic chemicals.- Directory of manufacturers , i967--Continued 



Name of company 



Orbis Products Corp 

Organies, Inc 

Original Bradford Soap Works, Inc 

C. J. Osbom Co 

Ottawa Chemical Co 

Ott Chemical Co 

Owens-Coming Fiberglas Corp 

P-L Biochemicals, Inc 

Pacific Resins & Chemical Co 

Pan American Petroleum Corp 

Pantasote Co. of New York, Inc 

Parke, Davis & Co 

Passaic Color & Chemical Co 

Patent Chemicals, Inc 

C. H. Patrick & Co., Inc 

Pearsall Chemical Co 

Peck's Products Co 

Peerless Chemical Co 

Pelron Corp 

S. B. Penick & Co 

Pennsalt Chemicals Corp 

Pennsylvania Industrial Chemical Corp 

Pennsylvania Refining Co 

Perry & Derrick Co 

Peter Hand Foundation, Inc 

Petrochemicals Co., Inc 

Petro-Tex Chemical Corp 

Pfanstiehl laboratories, Inc 

Pfister Chemical, Inc 

Chas. Pf izer & Co., Inc 

Pharraachem Corp 

Phelan-Faust Paint Manufacturing Co., Phelan'i 

Resins & Plastics Div. 

Phillips Petroleum Co 

Phoenix Oil Co 

Pickands Mather & Co., Manganese Chemical Co. 

Div. 

Pierce Organies, Inc 

Pillsbury Co 

Pilot Chemical Co : 

Pioneer Chemical Works, Inc 

Pioneer Plastics Corp., Chemical Div 

Pitt-Consol Chemical Co 

Pittsburgh Plate Glass Co 

Plastics Engineering Co 

Plastics Manufacturing Co 

Plastic Systems Corp 

Plex Chemical Corp 

Plumb Chemical Corp 

Polak's Frutal Works 

Polychemical Laboratories, Inc 

Polymer Corp 

Polymer Industries, Inc 

Poly Resins 

Polyrez Co., Inc 

Polyvinyl Chemicals, Inc 

Pontiac Refining Corp 

Pratt & Lambert, Inc 

Premier Malt Products, Inc 

Premier Petrochemical Co 

Preservative Paint Co 

Princeton Chemical Research, Inc 

Private Brands, Inc 

Procter & Gamble Co., Procter & Gamble 

Manufacturing Co. 

Proctor Chemical Co., Inc 

Productol Chemical Co., Inc 

Products Research & Chemical Corp 

Publicker Industries, Inc 



Office address 



^75 10th Ave., New York, NY 10018. 
172-4 Greenleaf Ave., Chicago, IL 60628. 
200 Providence St., W. Warwick, RI 02893. 
1301 W. Blancke St., Linden, NJ 07036. 
700 N. Wheeling St., Toledo, OH 43605. 
500 Agard Rd., Muskegon, MI 499A5. 
P.O. Box 901, Toledo, OH <i361'4. 

1037 W. McKinley Ave., Milwaukee, WI 53205. 
3400 13th Ave. SW. , Seattle, WA 98134. 
P.O. Box 591, Tulsa, OK 74102. 
26 Jefferson St., Passaic, NJ 07056. 
Foot of Jos. Campau, Detroit, MI 48232. 
28-36 Paterson St., Paterson, NJ 07501. 
335 McLean Blvd., Paterson, NJ 07504. 
P.O. Box 2526, Greenville, SC 29602. 
P.O. Box 108, Phillipsburg, NJ 08865. 
610 E. Clarence Ave., St. Louis, MO 63147. 
3850 Oakman Blvd., Detroit, MI 48204. 
7847 W. 47th St., I^rons, IL 60534. 
100 Church St., New York, NY 10008. 
3 Penn Center, Philadelphia, PA 19102. 
120 State St., Clairton, PA 15025. 
Union Bank Bldg., Butler, PA 16001. 
2510 Highland Ave., Norwood, OH 45212. 
2 E. Madison St., Waukegan, IL 60085. 
1825 E. Spring St. , Long Beach, CA 90806. 
P.O. Box 2584, Houston, TX 77001. 
1219 Glen Rock Ave., Waukegan, IL 60085. 
Linden Ave., Ridgefield, NJ 07657. 
235 E. 42d St., New York, NY 10017. 
Broad and Wood Sts., Bethlehem, PA 18018. 
P.O. Box 189, Burlington, lA 52602. 

841 -A Adams Bldg., Bartlesville, OK 74003. 

9505 Cassius Ave., Cleveland, OH 44105. 

2000 Union Commerce Bldg., Cleveland, OH 44115. 

P.O. Box 98, Rockford, IL 61105. 

608 2nd Ave. S. , Minneapolis, MN 55402. 

11756 Burke St., Santa Fe Springs, CA 90670. 

P.O. Box 237, Maple Shade, NJ 08052. 

Pionite Rd., Auburn, ME 04210. 

191 Doremus Ave., Newark, NJ 07105. 

1 Gateway Center, Pittsburgh, PA 15222. 

1607 Geele Ave., Sheboygan; WI 53082. 

2700 S. Westmoreland, Dallas, TX 75224. 

666 Dietrich Ave., Hazelton, PA 18201. 

1205 Atlantic St., Union City, CA 94587. 

4837 James St., Philadelphia, PA 19137. 

33 Sprague Ave., Middletown, NY 10940. 

490 Hunts Point Ave., New York, NY 10059. 

2120 Fairmont Ave., Reading, PA 19603. 

Viaduct Rd., Springdale, CT 06879. 

11655 Wicks St., Sun Valley, CA 91352. 

P.O. Box 320, Woodbury, NJ 08096. 

730 Main St., Wilmington, MA 01887. 

1801 Nueces Bay Blvd., Corpus Christi, TX 78403. 

P.O. Box 22, Buffalo, NY 14240. 

917 W. Juneau Ave., Milwaukee, WI 53201. 

P.O. Box 100, Pasadena, TX 77501. 

5410 Airport Way, S., Seattle, WA 98108. 

P.O. Box 652, Princeton, NJ 08540. 

300 S. 3d St., Kansas City, KS 66118. 

Ivorydale Technical Ctr., RM. 2S22, Cincinnati, 

OH 45217. 
P.O. Box 399, Salisbury, NC 28144. 
615 S. Flower St., Los Angeles, CA 90017. 
2919 Empire Ave., Burbank, CA 91504. 
1429 Walnut St., Philadelphia, PA 19102. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. --Synthetic organic chemicals: Directory of manufacturers , iS6/-- Continued 



207 



Name of oorapany 



Puerto Rioo Chemical Co., Inc 

Purex Corp., Ltd 

Puritan Chemical Co 

Quaker Chemical Corp 

Quaker Oats Co 

K. J. Qulnn&Co., Inc 

R.S.A. Corp 

Rachelle Laboratories, Inc 

Raybestos-Manhattan, Inc., Raybestos Div 

Red Spot Paint Co., Inc 

Refined Products Co 

Reheis Chemical Co., Div. of Armour Pharmaceu- 
tical Co. 

Reiohhold Chemicals, Inc 

Reilly Tar & Chemical Corp 

Reliance Universal, Inc 

Rel-Rez Div 

Remington Arras Co., Inc 

Renroh Resins 

Retzloff Chemical Co 

Rexall Chemical Co 

Fiberfil Div 

Rezolin, Inc 

Rhodia, Inc 

Richardson Co 

Richardson Polymers Div 

Riker Laboratories, Div. of Rexall Drug & 
Chemical Co. 

F. Ritter & Co 

Ritter Chemical Co., Inc 

Ritter Pfaudler Corp., lonac Chemical Co. Div. 

Riverdale Chemical Co 

Robeco Chemicals, Inc 

Roberts Chemicals, Inc 

Rock Hill Printing & Finishing Co 

Roehr Chemicals, Inc 

Rogers Corp 

Rohm & Haas Co 

Rosenberg Bros. & Co 

Royce Chemical Co 

Rubicon Chemicals, Inc 

Salsbury Laboratories 

SCM Corp., Glldden-Durkee Div 

Safeway Stores, Inc., Newport Products Co. Div 

Sandoz, Inc 

Dyestuff & Chemical Div 

Sartomer Resins, Inc 

Schaefer Varnish Co. 

Schenectady Chemicals, Inc 

Scher Bros., Inc 

R. P. Scherer Corp 

Sobering Corp 

Scholler Bros., Inc 

Seaboard Chemicals, Inc 

G. D. Searle & Co 

Selney Co., Inc 

Seydel-Woolley & Co 

Shanco Plastics & Chemicals, Inc 

Shell Oil Co 

Shell Chemical Co. Div 

Shepherd Chemical Co 

Sherwin-Williams Co 

Shulton, Inc 

George F. Siddall Co., Inc 

Signal Oil & Gas Co 



Office address 



P.O. Box 157, Arecibo, PR 00612. 

5101 Clark Ave., Lakewood, CA 90712, and 2244 N. Elston 

Ave., Chicago, IL 60614. 
916 Ashby St., NW., Atlanta, GA 30318. 

lime, Elm and Sandy Sts., Conshohocken, PA 19428. 
345 Merchandise Mart Plaza, Chicago, IL 60654. 
195 Canal St., Maiden, MA 02148. 

690 Saw Mill River Rd., Ardsley, NY 10502. 

P.O. Box 9095, 700 Henry Ford Ave., Long Beach, CA 90810. 

75 E. Main St., Stratford, CT 06601. 

110 Main St., Evansville, IN 47708. 

624 Schuyler Ave., Lyndhurst, NJ 07071. 

325 Snyder Ave., Berkeley Heights, NJ 07922. 

525 N. Broadway, White Plains, NY 10602. 

11 S. Meridan St., Indianapolis, IN 46204. 

6901 Cavalcade, Houston, TX 77001. 

4730 Crittenden Dr., Louisville, KY 40221. 

939 Barnum Ave., Bridgeport, CT 06602. 

P.O. Box 1191, New Bern, NC 28560. 

P.O. Box 45296, Houston, TX 77045. 

P.O. Box 37, Paramus, NJ 07652. 

1701 N. Heidelbach Ave., Evansville, IN 47717. 

20701 Nordhoff St., Chatsworth, CA 91311. 

600 Madison Ave., New York, NY 10022. 

27th Ave. & Lake St., Melrose Park, IL 60160. 

425 Morgan Lane, West Haven, CT 06516. 

19901 Nordhoff St., Northridge, CA 91324. 

4001 Goodwin Ave., Los Angeles, CA 90039. 
403 W. Main St., Armsterdam, NY 12010. 
Birmingham, NJ 08011. 
220 E. 17th St., Chicago Heights, IL 60411. 

51 Madison Ave., New York, NY 10010. 
P.O. Box 546, Nitro, WV 25143. 

Rock Hill, SC 29730. 

52-20 37th St., Long Island City, NY 11101. 

Main St., Rogers, CT 06263. 

Independence Mall West, Philadelphia, PA 19105. 

100 Landing Ave., Smithtown, NY 11787. 

E. Rutherford P.O., E. Rutherford, NJ 07073. 
P.O. Box 517, Geismar, LA 70734. 

500 Gilbert St., Charles City, lA 50616. 

2333 W. Logan Blvd., Chicago, IL 60647, and 900 Union 

Commerce Bldg., Cleveland, OH 44115. 
1501 Mariposa St., San Francisco, CA 94107. 
P.O. Box 357, Fair Lawn, NJ 07410. 
Route No. 10, Hanover, NJ 07936. 
P.O. Box 56, Essington, PA 19029. 
1350 S. 15th St., Louisville, KY 40210. 
Congress St. and 10th Ave., Schenectady, NY 12301. 
P.O. Box 538, Allwood Station, Clifton, NJ 07012. 
9425 Grinnell Ave., Detroit, MI 48213. 
1011 Morris Ave., Union, NJ 07083. 

Collins and Westmoreland Sts., Philadelphia, PA 19134. 
30 Foster St., Salem, MA 01970. 
P.O. Box 5110, Chicago, IL 60680. 
7 Park Ave., New York, NY 10016. 
762 Marietta Blvd., NW. , Atlanta, GA 30318. 
Ill Wales St., Tonawanda, NY 14150. 

52 W. 52d St., New York, NY 10019. 
52 W. 52d St., New York, NY 10019. 
5000 Poplar St., Cincinnati, OH 45212. 

101 Prospect Ave. NW., Cleveland, OH 44101. 
697 Route 46, Clifton, NJ 07015. 

P.O. Box 925, Spartanburg, SC 29301. 
P.O. Box 5008, Houston, TX 77012. 



208 SYNTHETIC ORGANIC CHEMICALS, 1967 

TABLE 22. -Synthetic organic chemicals; Directory of manufacturers , 1967 — Continued 



Name of company 



SNW 

TV 

CFC 

SNA 

SKG 

SUN 

SNO 

DXS 

SNT 

SWT 

SYC 

SYP 

SYV 



Simpson Timber Co 

Sinolair-Koppers Chemical Co 

Sinolair-Koppers Co 

Sinclair Paint Co 

Sinclair Petrochemicals, Inc 

Sinclair Refining Co 

James B. Sipe & Co 

Skelly Oil Co 

G. Frederick Smith Chemical Co 

Smith, Kline & French Laboratories 

Solar Chemical Corp 

Solar Nitrogen Chemicals, Inc 

Soluol Chemical Co., Inc 

Solvent Chemical Co., Inc 

Sonford Chemical Co 

Sonoco Products Co 

Sou-Tex Chemical Co., Inc 

Southeastern Adhesives Co 

Southern Biochemical Corp 

Southern Chemical Products Co 

Southern Sizing Co 

Spaulding Fibre Co., Inc 

E. R. Squibb & Sons, Inc 

A. E. Staley Manufacturing Co 

UBS Chemical Co. Dlv 

Stamford Chemical Industries, Inc 

Standard Brands, Inc., Clinton Com Processing 
Co. Div. 

Standard Chemical Products, Inc 

Standard Chlorine Chemical Co. , Inc 

Standard Oil Co. of California, Chevron Chemi- 
cal Co. 

Standard Oil Co. of Ohio 

Standard Pyroxoloid Corp 

Stange Co 

Stauffer Chemical Co. : 

Agricultural Div 

Calhio Chemicals, Inc. Div 

Industrial Div 

Specialty Chemical Div 

Stein, Hall & Co., Inc 

Stepan Chemical Co. : 

Industrial Chemicals Div., Millsdale Works— 

Maywood Div 

Sterling Drug, Inc.: 

Glenbrook Laboratories Div 

Hilton-Davis Chemical Co. Div 

Salvo Chemical Div 

Thomasset Colors Div 

Winthrop Laboratories Div 

Stresen-Reuter International, International 
Minerals & Chemical Corp. 

Sugar Beet Products Co 

Sullivan Varnish Co 

Summit Chemical Products Corp 

Sun Chemical Corp. : 

Chemicals Div 

Industrial Coatings Div 

Organic Chemical Dept 

Pigments Div 

Sunkist Growers, Inc 

Sun Oil Co 

SunOlin Chemical Co 

Sunray DX Oil Co 

Suntide Refining Co 

Swift & Co 

Synthetic Chemicals, Inc 

Synthetic Products Co 

Synvar- Corp 



Office address 



2301 N. Columbia Blvd., Portland, OR 97217. 

9822 La Porte Freeway, Houston, TX 77012. 

900 Koppers Bldg., Pittsburgh, PA 15219. 

3960 E. Washington Blvd., Los Angeles, CA 90023. 

600 5th Ave., New York, NY 10020. 

600 5th Ave., New York, NY 10020. 

P.O. Box 13090, Pittsburgh, PA 152-13. 

P.O. Box 1650, Tulsa, OK 7<il02. 

867 McKinley Ave., Columbus, OH ■43223. 

1500 Spring Garden St., Philadelphia, PA 19101. 

Solar Park, Leominster, MA 01'453. 

W3-; Midland Bldg., Cleveland, OH 4-'ill5. 

Green Hill and Market Sts., W. Warwick, fil 02893. 

341 Commercial St., Maiden, MA 021'48. 
P.O. Box 127, Port Neches, TX 77651. 
Hartsville, SO 29550. 

E. Catawba Ave., Mount Holly, NC 28120. 

P.O. Box 791, Lenoir, NC 28645. 

P.O. Box 2526, Greenville, SC 29602. 

420 lower Boundary St., P.O. Box 205, Macon, GA 31202. 

3056 SE. Main St., East Point, GA 30344. 

310 Wheeler St., Tonawanda, NY 14150. 

460 Park Ave., New York, NY 10022. 

22d and Eldorado Sts., Decatur, IL 62525. 

491 Main St., Cambridge, MA 02142. 

P.O. Box 1131, Stamford, CT 06940. 

1251 Beaver Channel Parkway, Clinton, lA 52733. 

1301 Jefferson St., Hoboken, NJ 07030. 
1035 Belleville Turnpike, Kearny, NJ 07032. 
200 Bush St., San Francisco, CA 94120. 

Midland Bldg., Cleveland, OH 44115. 
85 Pleasant St., Leominster, MA 01453. 

342 N. Western Ave., Chicago, IL 60612. 

299 Park Ave., New York, NY 10017. 
299 Park Ave., New York, NY 10017. 
299 Park Ave., New York, NY 10017. 
299 Park Ave., New York, NY 10017. 
605 3d Ave., New York, NY 10016. 

Elwood, IL 60421. 

100 W. Hunter Ave., Maywood, NJ 07607. 

90 Park Ave., New York, NY 10018. 

2235 Langdon Farm Rd., Cincinnati, OH 45237. 

Military Rd., Rothschild, WI 54474. 

120 Lister Ave., Newark, NJ 07105. 

90 Park Ave., New York, NY 10016. 

400 W. Roosevelt Ave., Bensenville, IL 60106. 

302 Waller St., Saginaw, MI 48605. 
410 N. Hart St., Chicago, IL 60622. 
11 William St., Belleville, NJ 07109. 

Wood River Junction, RI 02894. 

135 W. Lake St. , North Lake, IL 60164. 

P.O. Box 153, Harrison, NJ 07029. 

441 Tompkins Ave., Staten Island, NY 10305. 

720 E. Sunkist St., Ontario, CA 91764. 

1608 Walnut St., Philadelphia, PA 19103. 

P.O. Box F, Claymont, DE 19703. 

P.O. Box 2039, Tulsa, OK 74102. 

P.O. Box 2608, Corpus Chrlsti, TX 78403. 

115 W. Jackson Blvd., Chicago, IL 60604. 

335 McLean Blvd., Paterson, NJ 07504. 

1636 Wayside Rd., Cleveland, OH 44112. 

917 Washington St., Wilmington, DE 19899. 



DIRECTORY OF MANUFACTURERS 
TABLE 22. -Synthetic organic chemicals: Directory of manufacturers, 1967 — Continued 



209 



Najne of company 



Office address 



Tanatex Chemical Corp 

Charles S. Tanner Co 

Tetoior Apex Co 

Tenneco Chemicals, Inc 

Cal/Ink Div 

Newport Div 

New York Color Div 

Nuodex Div 

Tenneco Colors Div 

Tenneco Manufacturing Co., Tenneco Plastics 
Div. 

Tenneco Oil Co 

Tennessee Copper Co., Div. of Tennessee Corp-- 

Terra Chemicals International, Inc 

Texaco, Inc 

Texas Aliyls, Inc 

Texas-U.S. Chemical Co 

Tex Chem Co 

Textilana Corp 

Textilana-Nease, Inc 

Textron, Inc., Spencer Kellogg Div 

Thiokol Chemical Corp 

Thomason Industries, Inc., Southern Resin Div- 
Thompson Apex Co. , Div. of Continental Oil Co- 
Wm. T. Thompson Co., Thompson Chemicals Div — 

Thompson-Hayward Chemical Co 

Ticonderoga Chemical Corp 

Tizon Chemical Corp 

Toms River Chemical Corp 

Arthur 0. Trask Co 

Triangle Chemical Co 

Troy Chemical Co 

Trylon Chemical Corp 

Joseph Turner & Co 

USS Chemicals, Div. of U.S. Steel Corp 

Paul Uhlich & Co., Inc 

Ungerer & Co 

Union Camp Corp., Chemicals Div 

Union Carbide Corp 

Union Oil Co. of California 

Union Starch St Refining Co., Inc 

Uniroyal, Inc., Chemical Div 

United Carbon Co 

United Chemical Corp. of Norwood 

United Chemical Products Corp 

United Merchants & Manufacturers, Inc., Roma 

Chemical Div. 

United Oil Manufacturing Co 

U.S. Borax Research Corp 

U.S. Oil Co - 

United States Pipe & Foundry Co 

United States Plywood -Champion Papers, Inc., 

California Div., Shasta Operations. 

Universal Chemicals Corp 

Universal Oil Products Co 

UOP Chemical Div 

Upjohn Co 

Carwin Organic Chemicals 

Utah Resin Co., Inc 

Valchem 

Valentine Sugars, Inc 

Valley Nitrogen Producers, Inc 

Van De Mark Chemical Co., Inc 

Vanderbilt Chemical Corp 

Van Dyk & Co., Inc 

Velsicol Chemical Corp 

Ventron Corp 



P.O. Box 388, lyndhurst, NJ 07071. 

^50 Furraan Hall Rd., Greenville, SC 29608. 

505 Central Ave., Pawtucket, RI 02662. 

300 E. ^2d St., New York, NY 10017. 

711 Caraelia St., Berkeley, CA 9<i710. 

P.O. Box 911, Pensacola, FL 32502. 

37-; Main St., Belleville, NJ 07109. 

P.O. Box 2, Piscataway, NJ 08854. 

11th & Bern Sts., Reading, PA 1960<i. 

P.O. Box 2, Piscataway, NJ 08854. 

P.O. Box 2511, Houston, TX 77001. 

Copperhill, TN 37317. 

Davidson Bldg., Sioux City, lA 51102. 

1111 Rush Ave., Houston, TX 77052. 

P.O. Box 600, Deer Park, TX 77536. 

P.O. Box 667, Port Neches, TX 77651. 

20-21 Wagaraw Rd., Fair Lawn, NJ 07410. 

12607 Cerise Ave., Hawthorne, CA 90250. 

2U0 S. 88th St., Edwardsville, KS 66022. 

120 Delaware Ave., Buffalo, NY 14240. 

P.O. Box 27, Bristol, PA 19007. 

P.O. Drawer 1600, Fayettevllle, NC 28302. 

505 Central Ave., Pawtucket, RI 02862. 

3028 Locust St., St. Louis, MO 63103. 

5200 Speaker Rd., Kansas City, KS 66110. 

Marguerite Ave., Leominster, MA 01453. 

Flemington, NJ 08822. 

P.O. Box 71, Toms River, NJ 08753. 

327 S. LaSalle St., Chicago, IL 60604. 

206 Lower Elm St., P.O. Box 4528, Macon, GA 31208. 

338 Wilson Ave., Newark, NJ 07105. 

P.O. Box 607, Mauldin, SC 29662. 

Pleasant View Terrace, Ridgefield, NJ 07451. 

Grant Bldg., Pittsburgh, PA 15219. 

90 West St., New York, NY 10006. 

161 Avenue of the Americas, New York, NY 10013. 

P.O. Box 6170, Jacksonville, FL 32205. 

270 Park Ave., New York, NY 10017. 

461 S. Boylston St., Los Angeles, CA 90017. 

900 19th St., Granite City, IL 62040. 

Naugatuck, CT 06771. 

P.O. Box 149, Baytown, TX 77520. 

Endioott St., Norwood, MA 02062. 

York and Colgate Sts., Jersey City, NJ 07302. 

749 Quequechan St., Fall River, MA 02721. 

2d and Cascade Sts., Erie, PA 16512. 
3075 Wilshire Blvd., Los Angeles, CA 90005. 
P.O. Box 4228, E. Providence, RI 02914. 
3300 1st Ave. N., Birmingham, AL 35202. ' 
P.O. Box 2317, Redding, CA 96002. 

1224 Mendon Rd., Ashton, RI 02864. 

30 Algonquin Rd., Des Plaines, IL 60018. 
State Highway 17, E. Rutherford, NJ 07073. 
7000 Portage Rd., Kalamazoo, MI 49001. 
Sackett Point Rd., North Haven, CT 06473. 
604-605 Keams Bldg., Salt Lake City, UT 84101. 

1407 Broadway, New York, NY 10018. 
726 Whitney Bldg., New Orleans, LA 70130. 
1221 Van Ness Ave., Fresno, CA 93721. 
N. Transit Rd., Lockport, NY 14094. 

31 Taylor Ave., Bethel, CT 06801. 

Main & William Sts., Belleville, NJ 07109. 
341 E. Ohio St., Chicago, IL 60611. 
Congress St., Beverly, M 01915. 



210 SYNTHETIC ORGANIC CHEMICALS, r?67 

TABLE 22. -Synthetic organic chemicals; Directory of manufacturers , iS67--Continued 



Identi- 
fication 
code 



Name of company- 



Office address 



Vermilye-Bell 

Verona-Pharma Chemical Corp 

Vickers Refining Co., Inc 

Vineland Chemical Co 

Virginia Chemicals, Inc 

Vistron Corp 

Silmar Div 

Vitamins, Inc 

Vulcan Materials Co., Chemicals Dlv 

Wallace & Tiernan, Inc . : 

Harchem Div 

Lucidol Div 

Wamer-Jenkinson Manufacturing Co 

Warner Machine Products, Inc., Warner Chemical 

Div. 

Washine Chemical Corp 

West Coast Adhesives Co 

Westinghouse Electric Corp., Benolite Dept 

Weston Chemical Co., Inc 

West Virginia Pulp & Paper Co. : 

Chemical Div., Tall Oil Dept 

Polychemicals Div 

Weyerhaeuser Co., Wood Products Div 

White & Bagley Co 

White & Hodges, Inc 

White Laboratories, Inc 

Whitmoyer Laboratories, Inc 

Whittaker Corp., Research & Development/San 

Diego. 

Whlttemore-Wright Co., Inc 

Wica Chemicals, Inc 

Wilmot & Cassidy, Inc 

Wilson Pharmaceutical & Chemical Corp. : 

Wilson Laboratories Div 

Wilson-Martin Div 

Witco Chemical Co., Inc 

Kendall Refining Co. Div 

Witfield Chemical Corp 

Woburn Chemical Corp 

Woodbury Chemical Co 

W. A. Wood Co 

Wood Ridge Chemical Corp 

Woonsocket Color & Chemical Co 

Worthington Biochemical Corp 

Wyandotte Chemicals Corp 

Wycon Chemical Co 

Wyeth Laboratories, Inc., Div. of American 

Home Products Corp. 

Young Aniline Works, Inc 



21707 Bothell Way, Bothell, WA 98011. 

lorio Ct., Union, NJ 07083. 

P.O. Box 22'iO, Wichita, KS 67201. 

W. Wheat Rd., Vineland, NJ 08360. 

Portsmouth, VA 23703. 

143-4- Midland Bldg., Cleveland, OH 4^115. 

12335 S. Van Ness Ave., Hawthorne, CA 90250. 

<i01 N. Michigan Ave., Suite 2730, Chicago, IL 60611. 

P.O. Box 545, Wichita, KS 67201. 



110 E. Hanover Ave., Cedar Knolls, NJ 07927. 
1740 Military Rd., Buffalo, NY 14240. 
2526 Baldwin St., St. Louis, MO 63106. 
1200 Rochester Ave., Muncie, IN 47302. 

165 Main St., Lodi, NJ 07644. 

11104 NW. Front Ave., Portland, OR 97231. 

Manor, PA 15665. 

104 E. 40th St., New York, NY 10016. 

P.O. Box 5207, N. Charleston, SC 29406. 
P.O. Box 5207, N. Charleston, SC 29406. 
115 S. Palmetto St., Marshfield, WI 54449. 
P.O. Box 1171, Worcester, MA 01601. 
576 Lawrence St., Lowell, MA 01852. 
Galloping Hill Rd., Kenilworth, NJ 07033. 
19 N. Railroad St., Myerstown, PA 17067. 
3540 Aero Ct., San Diego, CA 92123. 

62 Alford St., Boston, MA 02129. 
P.O. Box 506, Charlotte, NC 28201. 
108 Provost St., Brooklyn, NY 11222. 

4221 3. Western Blvd., Chicago, IL 60609. 

Jackson and Swanson Sts., Philadelphia, PA 19148. 

P.O. Box 305, Paramus, NJ 07652. 

77 N. Kendall Ave., Bradford, PA 16701. 

P.O. Box 1243, Wilmington, CA 90744. 

1200 Harrison Ave., Harrison, NJ 07029. 

P.O. Box 788, St. Joseph, MO 64502. 

108 Spring St., Everett, MA 02149. 

Park PI. E., Wood Ridge, NJ 07075. 

176 Sunnyside Ave., Woonsocket, RI 02895. 

Route 9, Freehold, NJ 07728. 

1609 Biddle Ave., Wyandotte; MI 48192. 

P.O. Box 1087, Colorado Springs, CO 80901. 

P.O. Box 8299, Paoli, PA 19101. 



2731 Boston St., Baltimore, MD 21224. 






APPENDIX 



U. So Imports of Benzenoid Intermediates 
and Finished Benzenoid Products 

Table 23 summarizes, for 1966 and 1967, U.S. imports of benzenoid chemicals and products 
entered under the Tariff Schedules of the United States (TSUS), schedule 4, part 1, subparts B 
and C. The data, which were obtained by analyzing invoices covering imports through U. S. 
customs districts, are given in detail in a separate report of the Tariff Commission. 

In 1967, general imports of benzenoid intermediates entered under part IB, comprised 617 
items with a total weight of 71.8 inillion pounds, and an invoice value of $28. 2 million, compared 
with 68. 9 million pounds, with an invoice value of $31.2 million, in 1966. Half of these inter- 
mediate products were declared to be "competitive" (duty based on "American selling price"). In 
terms of value, 47 percent of all the intermediates imported in 1967 came from West Germany; 
12 percent, from the United Kingdom; and 10 percent, from Japan. The remaining imports came 
mainly from Italy, Switzerland, Canada and France. Imports from West Germany in 1967 in- 
creased to $13. 2 million from $12. 1 million in 1966. In 1967, imports from Italy increased to 
$2.6 million, from $1.9 million in 1966. Imports in 1967 from Canada increased to $2. 3 million 
from $2. 1 million in 1966. Imports from Japan announted to $2.7 million in 1967, compared with 



TABLE 23. — Benzenoid intermediates and finished benzenoid products : 

classified by use, 1966 and 1967 



U.S. general imports. 



Product 



1966 



Quantity 



Invoice 
value 



1967 



Quantity 



Invoice 
value 



Intermediates^ 

Finished benzenoid products, total 

Dyes, total 

Acid 

Azoic dyes 

Azoic components: 

Fast color bases 

Fast color salts 

Naphthol AS and its derivatives — 

Basic 

Direct 

Disperse 

Fiber-reactive 

Fluorescent brightening agents 

Mordant 

Solvent 

Sulfur 

Vat 

All other 

Benzenoid pigments (toners and lakes )- 

Medicinals and pharmaceuticals 

Flavor and perfume materials 

All other 



t.OOO 
pounds 
68,919 

47,875 



13,715 
2,555 

M 

520 

269 

1,558 

1,136 

1,159 

2,494 

1,249 

247 

362 

265 

45 

1,761 

2 81 

1,010 

4,674 

2,564 

25,912 



1 . 000 
del lars 
31,217 

56,859 



1 . 000 
pounds 



25,817 



1,738 
10,855 

4,033 
14,416 



71,779 
45,907 



12,812 

2,163 

5 

648 

273 

749 

1,198 

794 

2,358 

1,188 

250 

367 

203 

89 

2,455 

^ 67 

1,485 

4,581 

1,740 

25,289 



1.000 
dollars 
28,-230 

54,340 



23,382 



2,944 
11,935 

2,758 
13,321 



■"■ Includes small quantities of rubber-processing oheraioals. 

2 Includes ingrain dyes. 

^ Includes organic pesticides and related products, plasticizers, surface-active agents, and textile assistant. 

Source: Coii5)iled from the records of the U.S. Bureau of Customs. 



1 Imports of Benzenoid Chemicals and Products, 1967 ^ TC Publication 264, 1968 [processed]. 



211 



212 SYNTHETIC ORGANIC CHEMICALS, 1967 

$4.3 million in 1966, while imports from Switzerland totaled $2.5 million, compared with $4.2 
million in 1966. 

In 1967, 10 chemicals accounted for approximately 67 percent of the quantity of imports of 
benzenoid intermediates. The large-volume intermediates innported in 1967 were styrene, poly- 
alkylbenzene, phenol, phthalic anhydride, N-isopropylaniline, 1 , 4-cyclohexanedimethanol, ace- 
toacetanilide, 4- (p-chlorophenoxy)phenyl isocyanate, anthraquinone, and cyclohexanone. In 1967, 
innports of styrene amounted to 16. 6 million pounds and came fronn Canada and Italy. Imports of 
polyalkylbenzene amounted to 14. 2 million pounds and all came from Italy. Imports of phenol in 
1967 totaled 4. 4 million pounds, compared with 8. 6 million pounds in 1966 and came from 
France and Italy. Imports of phthalic anhydride in 1967 amounted to 3. 3 million pounds and im- 
ports of N-isopropylaniline amounted to 2.4 million pounds. Phthalic anhydride came prin- 
cipally from Italy, Japan, and the United Kingdom; N-isopropylaniline all came fronn Canada. In 
1967, imports of 1 , 4-cyclohexanedimethanol, which came from West Gerinany, amounted to 2.4 
million pounds; acetoacetanilide, which came principally from the United Kingdom, Switzerland, 
and West Germany, amounted to 1.4 million pounds; 4- (p-chlorophenoxy)phenyl isocyanaie, which 
all came from West Germany, totaled 1.2 million pounds; anthraquinone, which came fronn Japan, 
the United Kingdonn, and West Germany, totaled 1.2 nnillion pounds; and imports of cyclohexanone, 
which canne fronn Italy and the United Kingdom, totaled 810,000 pounds. 

Imports in 1967 of all finished benzenoid products that are dutiable under part IC comprise 
2, 227 listed items, with a total weight of 45. 9 million pounds and an invoice value of $54. 3 mil- 
lion. In 1966, imports consisted of 2, 401 items, with a total weight of 47. 9 nnillion pounds and an 
invoice value of $56. 9 nnillion. The most innportant group of finished benzenoid products innported 
in 1967 was benzenoid dyes. Imports of dyes amounted to $23.4 million (invoice value), or 43.0 
percent of the value of all imports under part IC. In 1966, innports of dyes amounted to $25. 8 
million (invoice value), or 45.4 percent of the value of all innports under part IC. 

Imports of medicinals and pharmaceuticals, the next nnost important group of products 
entered under part IC in 1967, increased in 1967, compared with 1966. In 1967, imports of 
medicinals and pharnnaceuticals were valued at $11.9 million (invoice value), or 22. percent of 
the total value of imports under part IC. In 1966, imports of medicinals and pharnnaceuticals 
were valued at $10. 9 million, or 19. 1 percent of the total value of iinports under part IC. 

As in 1966, innports of benzenoid pigments increased in 1967. In 1967, imports of these 
products were valued at $2. 9 million, compared with $1.7 million in 1966. 

Imports of benzenoid flavor and perfume materials in 1967 ($2. 8 million) were 30 percent 
less than in 1966 ($4.0 nnillion). In 1967 innports of other benzenoid products entered under part 
IC (chiefly polyamide resins and pesticides) were valued at $13. 3 nnillion, compared with $14. 4 
million in 1966. 



rUS GOVERNMENT PRINTING OFFICE 1969 — 363-502 



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