BOSTON
PUBLIC
LIBRARY
13-
UNITED STATES TARIFF COMMISSION
SYNTHETIC
ORGANIC CHEMICALS
United States Production
and Sales, 1970
TC Publication 479
Boston Public Library
Superintendent of Documents
JUN14 1972
RECENT REPORTS OF THE UNITED STATES TARIFF COMMISSION ON
SYNTHETIC ORGANIC CHEMICALS
Synthetic Organic Chemicals, United States Production and Sales, 1965 (TC Publication 206,
1967), $1.00
Synthetic Organic Chemicals, United States Production and Sales, 1966 (TC Publication 248,
1968), $1.50
Synthetic Organic Chemicals, United States Production and Sales, 1967 (TC Publication 295,
1969), $2.00
Synthetic Organic Chemicals, United States Production and Sales, 1968 (TC Publication 327.
1970), $2.00
Synthetic Organic Chemicals, United States Production and Sales, 1969 (TC Publication 412.
1971), $2.00
NOTE.— The reports listed above may be purchased from the Superintendent of Documents, U.S. Governmen
Printing Office, Washington, D.C. 20402. All U.S. Tariff Commission reports reproduced by the Government Printin
Office may be consulted in the official depository libraries throughout the United States.
UNITED STATES TARIFF COMMISSION
SYNTHETIC
ORGANIC CHEMICALS
United States Production
and Sales, 1970
UNDER THE PROVISIONS OF
SECTION 332 OF THE TARIFF
ACT OF 1930, AS AMENDED
U.S. GOVERNMENT PRINTING OFFICE
WASHINGTON : 1972
TC Publication 479
UNITED STATES TARIFF COMMISSION
Catherine Bedell, Chairman
Joseph O. Parker, Vice Chairman
Glenn W. Sutton
Will E. Leonard, Jr.
George M. Moore
J. Banks Young
Kenneth R. Mason, Secretary
Address all communications
UNITED STATES TARIFF COMMISSION
Washington, D.C. 20436
4
For sale by the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402 - Price $2
Stok Number 4900-0030
CONTENTS
Page
Introduction 1
Summary 3
General 4
Tar and tar crudes 7
Crude products from petroleum and natural gas
for chemical conversion 13
Cyclic intermediates 21
Dyes 55
Organic pigments 91
Medicinal chemicals 101
Flavor and perfume materials 123
Plastics and resin materials 135
Rubber -processing chemicals 147
Elastomers 155
Plasticizers 159
Surface -active agents 167
Pesticides and related products 197
Miscellaneous chemicals 207
Appendix:
Directory of manufacturers 247
Uo So imports of benzenoid chemicals
and products 261
HI
Introduction
This is the fifty-fourth annual report of the U.S. Tariff Commission on domestic production and sales of
synthetic organic chemicals and the raw materials from which they are made. It is authorized under the provisions
of section 332 of the Tariff Act of 1930, as amended. The report consists of fourteen sections, each covering a
specified group (based principally on use) of organic chemicals as follows: tar and tar crudes; crude products from
petroleum and natural gas; intermediates; dyes; pigments; medicinal chemicals; flavor and perfume materials; plastics
and resin materials; rubber-processing chemicals; elastomers; plasticizers; surface-active agents; pesticides and
related products; and miscellaneous organic chemicals. Data have been supplied by more than 800 producers.
The first table in each section gives statistics on products and groups of products in as great detail as is
possible without revealing the operations of individual producers. Statistics for an individual chemical or group
of chemicals are given only when there are three or more producers, no one or two of which may be predominant. More-
over, even when there are three or more producers, statistics are not given if there is any possibility that their
publication would violate the statutory provisions relating to unlawful disclosure of information accepted in con-
fidence by the Commission. '
Data are reported by producers for only those items where the volume of production or sales exceeds 1,000 pounds
or the value of sales exceeds $1,000. They are usually given in terms of undiluted materials; however, products of
95 percent or more purity are considered to be 100 percent pure. Commercial concentrations are applied to dyes,
certain plastics and resins, and a few solvents; such concentrations are specifically noted.
The statistics given in this report include data from all known domestic producers of the items covered and in-
clude the total output of each company's plants, i.e., the quantities produced for consumption within the producing
plant, as well as the quantities produced for domestic and foreign sale. The quantities reported as produced, there-
fore, generally exceed the quantities reported as sold. Some of these differences, however, are attributable to
changes in inventory.
The second table in each section lists all items for which data on production or sales have been reported, by
primary manufacturers, identified by manufacturers' codes. Each code consists of not more than three capital letters
which is assigned on a permanent basis. The third table in each section is a directory, alphabetized by the codes
of the manufacturers reporting in that section. Table 1 of the Appendix is a directory, alphabetized by the names of
the manufacturers reporting in all sections and includes their office addresses.
Information on the synonymous names of the organic chemicals included in this report may be found in the SOCMA
Handbook: Commercial Organic Chemical Homes, published by the Chemical Abstracts Service of the American Chemical
Society, or the Colour Index (2d edition), published by the Society of Dyers and Colourists.
Table 2 of the Appendix summarizes and gives the competitive status of U.S. general imports in 1970 of benzenoid
intermediates and finished benzenoid products, entered under schedule 4, parts IB and IC, of the Tariff Schedules of
the United States.
As specified in the reporting instructions sent to manufacturers, production and sales (unless otherwise
specified) are defined as follows:
PRODUCTION is the total quantity of a commodity made available
by original manufacturers only. It is the sum — expressed in terms
of 100% active ingredient unless otherwise specified in the reporting
instructions — of the quantities:
Produced, separated, and consumed in the same plant or
establishment. A commodity is considered separated
when it is isolated from the reaction system and/or
when it is weighed, analyzed, or otherwise measured.
This includes byproducts and coproduats that are not
classifiable as waste materials;
Produced and transferred to other plants or establish-
ments of the same firm;
Produced and sold to other firms, including production
for another under a toll agreement {i.e., an agreement,
under which one firm furnishes the raw materials' and
pays the processing costs and the other firm prepares
the finished product and returns it to the first firm) .
Produced and held in stock.
' Title 18, U.S.C. 1905 and Title 44, U.S.C. 3508
I
INTRODUCTION
PRODUCTION EXCLUDES;
Purification of a commodity , unless inclusion of
such processing is specifically requested in
the reporting instructions for individual
sections;
Intermediate products which are formed in the
manufacturing process, but are not isolated
from the reaction system — that is, not
weighed, analyzed, or otherwise measured;
Materials that are used in the process but
which are recovered for re-use or sale;
Waste products having no economic significance.
SALES are actual quantities of commodities sold by ORIGINAL
MANUFACTURERS ONLY. Sales include the quantity and value of:
Shipments of a commodity for domestic use and
for export, or segregation in a warehouse
when title has passed to the purchaser in a
bona fide sale;
Shipments of a commodity produced by others under
toll agreements;
Shipments to subsidiary or affiliated companies.
SALES EXCLUDE:
All intra-company transfers within a corporate entity;
All sales of purchased commodities;
Alt shipments of a commodity produced for others
under toll agreements.
VALUE OF SALES is the net selling value f.o.b. plant or
warehouse, or delivered value, whichever represents the normal
industry practice.
Summary
Combined production of all synthetic organic chemicals, tars, tar crudes, and crude products from petro-
leum and natural gas in 1970 was 233,110 million pounds--an increase of 4.2 percent over the output in 1969
(see table 1). Sales of these materials in 1970, which totaled 128,478 million pounds, valued at $13,638 million,
were 5,6 percent larger than in 1969 in terms of quantity and 2.2 percent larger in terms of value. These figures
include data on production and sales of chemicals measured at several successive steps in the manufacturing pro-
cess, and therefore they necessarily reflect some duplication.
In 1970, production of all synthetic organic chemicals, including cyclic intermediates and finished chemical
products, totaled 138,322 million pounds, or 2.7 percent more than the output in 1969. Production increased for
only three subgroups of products, however: Medicinal chemicals C214 million pounds) was 7.2 percent more than in
1959; miscellaneous chemicals (79,257 million pounds) was 4.7 percent more; and plastics and resin materials
(19,210 million pounds) was 3.5 percent more. Production of subgroups which declined in 1970 compared with 1969
included flavor and perfume materials (100 million pounds) down 16.7 percent, organic pigments (57 million pounds)
down 7.4 percent, and pesticides and related materials (1,034 million pounds) down 6.4 percent.
TABLE 1. --Synthetic organic chemicals and their raw materials: U.S. production and sales, 1969 and 1970
decrease
(-), 1970
over
1969'
Quantity
decrease
(-), 1970
over
1969'
Increase
or
decrease
(-), 1970
over
1969'
Grand total^
Tar
Tar crudes
Crude products from petro-
leum and natural gas
Synthetic organic chemicals,
total^
Cyclic intermediates
Dyes
Organic pigments
Medicinal chemicals
Flavor and perfume mate-
rials
Plastics and resin mate-
rials
Rubber-processing chem-
icals
Elastomers (synthetic
rubbers)
Plasticizers
Surface-active agents
Pesticides and related
products
Miscellaneous chemicals
Million
pounds
223,684
7,688
9,996
71,315
134,685
28,571
240
61
200
120
18,557
303
4,524
1,382
3,901
1,104
75,720
Mi I lion
pounds
233,110
Percent
4.2
Million
pounds
121,616
Million
pounds
Percent
5.6
Million
dollco's
13,345
Million
dollars
13,638
7,609
9,300
138,322
-1.0
-7.0
2.7
3,772
6,644
71,961
3,712
6,533
74,794
-1.6
-1.7
141
1,001
12,166
132
1,061
12,409
28,257
235
57
214
100
19,210
4,438
1,336
3,886
1,034
79,257
-1.1
-2.4
-7.4
7.2
-16.7
3.5
-1.7
-1.9
-3.3
-.4
-6.4
4.7
12,398
221
51
145
104
3,918
1,275
1,988
929
34,782
12,976
223
47
155
92
17,074
228
3,820
1,239
2,061
881
35,998
4.7
1.1
-7.1
6.7
-11.6
7.2
-2.5
-2.8
3.7
-5.1
3.5
1,208
385
133
462
94
3,175
144
1,060
266
370
851
4,018
1,260
390
123
510
3,266
149
1,032
235
387
870
4,097
Percent
2.2
-2.0
-6.4
2.0
4.3
1.3
-7.6
10.4
-4.8
2.9
3.1
-2.6
-11.7
4.7
2.2
1.9
Percentages calculated from figures rounded
Because of rounding, figures may not add to
to thousands,
the totals shown.
SYNTHETIC ORGANIC CHEMICALS, 1970
General
In this report, synthetic organic chemicals are classified on the basis of their principal use as follows:
cyclic intermediates, dyes, organic pigments, medicinal chemicals, flavor and perfume materials, plastics and resin
materials, rubber-processing materials, elastomers, plasticizers, surface-active agents, pesticides and related
products, and miscellaneous chemicals (acyclic intermediates and acyclic and cyclic finished products). Most of
these groups are further subdivided either by use or by chemical composition. As intermediate chemicals are used
in the manufacture of finished products, aggregate figures that cover both intermediates and finished products nec-
essarily include considerable duplication.
Total production of synthetic organic chemicals (intermediates and finished products combined) in 1970 was
138, 322 million pounds, or 2.7 percent more than the output of 134,685 million pounds reported for 1969 and 32.1
percent more than the output of 104,711 million pounds reported for 1967 (see table 2). Sales of synthetic organic
chemicals in 1970 amounted to 74,794 million pounds, valued at $12,409 million, compared with 71,961 million pounds,
valued at $12,166 in 1969 and 55,177 million pounds, valued at $10,438 million in 1967. Production of all cyclic
products (intermediates and finished products combined) in 1970 totaled 43,245 million pounds, or 0.9 percent less
than the 43,656 million pounds reported for 1969 and 29.2 percent more than the 33,479 million pounds reported for
1967. Production of all acyclic products in 1970 totaled 95,077 million pounds, or 4.4 percent more than the
91,028 million pounds reported for 1969 and 33.5 percent more than the 71,232 million pounds reported for 1967.
TABLE 2. --Synthetic organic chemicals: Summary of U.S. production and sales of intermediates and
finished products, 1967, 1969 and 1970
[Production and sales in thousands of pounds; sales value in thousands of dollars]
Increase, or decrease (-)
1970 over
1967
1970 over
1969
Organic chemicals, cyclic and acyclic,
grand total :
Production
Sales
Sales value
Cyclic, total:
Production
Sales
Sales value
Acyclic, total:
Production
Sales
Sales value
1. Cyclic Intermediates
Production
Sales
Sales value
2. Dyes
Production
Sales
Sales value
Z. Organic Pigments
Production
Sales
Sales value
4. Medicinal Chemicals
Cyclic:
Production
Sales
Sales value
Acyclic:
Production
Sales
Sales value
See footnote at end of table.
,711,357
,176,823
,438,453
,479,469
,328,628
,610,293
,231,888
848,195
828,160
,793,132
,461,180
,000,359
206,240
198,592
332,049
53,322
42,867
108,354
110
129
70
120
348
873
69
941
56
804
36
402
134,684,910
71,960,615
12,166,311
43,656,481
23,927,329
5,393,830
91,028,429
48,033,286
6,772,481
28,570,871
12,398,249
1,208,447
240,208
220,886
385,301
61,011
50,794
133,149
126,418
88,113
425,235
73,616
56,689
36,585
138,322,426
74,793,892
12,409,252
43,245,465
24,571,197
5,470,865
95,076,961
50,222,695
6,938,387
28,257,042
12,976,217
1,260,395
234,526
223,218
390,429
56,524
47,166
122,965
132,190
87,308
465,354
82,281
67,206
44,705
32.1
35.6
18.9
29.2
27.1
18.7
10.0
13.5
17.6
18.3
22.8
2.7
3.9
-.9
2.7
4.6
2.4
-2.4
1.1
1.3
GENERAL
TABLE 2.— Synthetic organic chemicals: Summary of U. S. production and sales of intermediates and
finished products, 1967, 1969 and 1970-- Continued
[Production and sales in thousands of pounds; sales value in thousands of dollars]
Increase, or decrease (-)
1970 over
1967
5. Flavor and Perfume Materials
Cyclic:
Production
Sales
Sales value
Acyclic:
Production
Sales
Sales value
6. Plastics and Resin Materials
Cyclic:
Production
Sales
Sales value
Acyclic:
Production
Sales
Sales value
7. Rubber-Processing Chemicals
Cyclic:
Production
Sales
Sales value
Acyclic:
Product ion
Sales
Sales value
8. Elastomers (Synthetic Rubbers)
Cyclic:
Production
Sales
Sales value
Acyclic:
Production
Sales
Sales value
9. Plasticizers
Cyclic:
Production
Sales
Sales value
Acyclic:
Production
Sales
Sales value
57,978
47,285
52,866
53,558
49,311
40,495
5,033,497
4,224,121
1,036,940
8,759,452
7,753,242
1,635,690
220,139
169,970
116,318
43,994
30,878
15,477
2,297,637
1,940,099
439,580
1,524,908
1,321,945
434,657
929,871
865,084
167,827
332,908
296,767
93,142
61,353
48,721
52,873
59,037
54,843
40,753
6,435,204
5,386,791
1,238,301
12,122,045
10,535,093
1,936,452
254,792
194,012
127,268
48,687
35,480
17,208
2,591,720
2,172,843
520,141
1,932,337
1,744,740
539,365
1,022,941
946,984
164,709
359,290
327,618
101,161
52,543
42,916
52,045
47,778
48,587
37,057
6,799,570
5,793,962
1,298,725
12,410,349
11,280,347
1,967,356
255,477
196,485
133,534
42,814
31,376
15,425
2,454,462
1,998,632
485,092
1,983,114
1,821,293
547,236
998,475
937,504
143,736
337,601
301,612
91,100
-9.4
-9.2
-1.6
35.1
37.2
25.2
41.7
45.5
1.6
-.3
6.8
3.0
10.4
30.0
37.8
25.9
7.4
8.4
-14.4
1.4
1.6
-2.2
See footnote, at end of table.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Synthetic organic chemicals: Summary of U. S. production and sales of intermediates and
finished products, 1967, 1969 and 1970-- Continued
[Production and sales in thousands of pounds; sales value in thousands of dollars]
Increase, or decrease (-)
1970 over
1967
1970 over
1969
10, Supfaoe-Aative Agents
Cyclic:
Production
Sales
Sales value
Acyclic:
Production
Sales
Sales value
11. Pesticides and Related Produats
Cyclic:
Production
Sales
Sales value
Acyclic:
Production
Sales
Sales value
12. Miscellaneous Chemicals
Cyclic:
Production
Sales
Sales value
Acyclic:
Production
Sales
Sales value
1,418,444
852,238
95,810
2,060,851
897,786
220,877
823,158
681,532
627,742
226,505
215,831
159,301
1,535,922
775,540
283,575
58,159,771
25,225,631
3,192,119
1,566,958
894,017
116,271
2,334,063
1,094,098
253,504
819,436
666,038
697,167
284,945
262,625
153,999
1,905,569
859,881
324,968
73,814,409
33,922,100
3,693,454
1,572,505
916,922
106,662
2,313,681
1,144,535
280,539
727,133
601,755
701,558
306,942
279,159
168,756
1,705,018
749,112
310,370
77,552,401
35,248,580
3,786,213
7.6
11.3
12.3
27.5
27.0
-11.7
11.8
35.5
29.3
11.0
-3.4
2.6
-8.3
-.9
4.6
10.7
-11.3
-9.7
.6
7.7
6.3
9.6
-lO.S
-12.9
-4.5
5.1
3.9
2.5
' Standard reference base period for Federal Government general -purpose index numbers.
The following tabulation shows, by chemical groups, the number of companies that reported production in 1970 of
one or more of the chemicals included in the groups listed in table 2:
Number
of
companies
■- 211
47
Chemical group
Cyclic intermediates
Dyes
Organic pigments 35
Medicinal chemicals 104
Flavor and perfume materials 50
Plastics and resin materials 264
Chemical group
Rubber-processing chemicals
Elastomers (synthetic rubbers;) --
Plasticizers
Surface-active agents
Pesticides and related products-
Miscellaneous chemicals
Number
of _
companies
60
210
TAR AND TAR CRUDES
Tars
Coal tar is produced chiefly by the steel industry as a byproduct
of the manufacture of coke; water-gas tar and oil-gas tar are produced
by the fuel-gas industry. Production of coal tar, therefore, depends
on the demand for steel; production of water-gas tar and oil-gas tar
reflects the consumption of manufactured gas for industrial and house-
hold use. Water-gas and oil-gas tars have properties intermediate be-
tween those of petroleum asphalts and coal tars. Petroleum asphalts
are not usually considered to be raw materials for chemicals.
The quantity of tar produced in the United States in 1970 was al-
most entirely coal tar which amounted to 761 million gallons, or 1.0
percent less than the 769 million gallons produced in 1969 (see table l'^)
U.S. production of water-gas and oil-gas tars was not reported to the
Commission for 1969 or 1970; production of these tars amounted to 21 mil-
lion gallons in 1968, according to trade publications. Sales of coal tar
in 1970 amounted to 371 million gallons, valued at $36 million, compared
with 377 million gallons, valued at $37 million, in 1969.
Consumption of tar in 1970 amounted to 767 million gallons, of which
658 million gallons was consumed in distillation and (by tar distillers
only) in other uses. Tar used as fuel amounted to 108 million gallons.
A lesser amount, 1.6 million gallons, was consumed by coke-oven operators
in miscellaneous uses (see table lA) .
Tar Crudes
Tar crudes are obtained from coke-oven gas and by distilling coal
tar, water-gas tar, and oil-gas tar. The most important tar crudes are
benzene, toluene, xylene, naphthalene, creosote oil, and pitch of tar.
Some of these products are identical with those obtained from petroleum.
Data for materials derived from petroleum are included, for the most
part, with the statistics for like materials derived from coke-oven gas
and tars, and are shown in tables 1 and IB.
Domestic production of industrial and specification grades of
benzene reported by coke-oven operators and petroleum refinery operators"
in 1970 amounted to 1,134 million gallons--4.4 percent less than the
1,185 million gallons reported for 1969. These statistics include data
for benzene produced from light oil and petroleum. Sales of benzene by
coke-oven operators and petroleum operators in 1970 amounted to 654 mil-
^ See also table 2 of this section which lists the products in table 1
and identifies the manufacturers by code. These codes are given in
table 3.
2 Statistics on production and sales of benzene, toluene, and xylene
by tar distillers cannot be shown because publication would reveal the
operations of individual companies.
8 SYNTHETIC ORGANIC CHEMICALS, 1970
lion gallons, valued at $143 million, compared with 675 million gallons,
valued at $148 million, in 1969. In 1970 the output of toluene^ [in-
cluding material produced for use in blending in aviation fuel) amounted
to 830 million gallons--9.2 percent more than the 759 million gallons
reported for 1969. Sales of toluene in 1970 were 430 million gallons,
valued at $77 million, compared with 418 million gallons, valued at
$76 million, in 1969. The output of xylene^ in 1970 (including that
produced for blending in motor fuels) was 538 million gallons, com-
pared with 382 million gallons in 1969. About 99 percent of the 538
million gallons of xylene produced in 1970 was obtained from petroleum
sources .
Production of crude naphthalene in 1970 (including 291 million
pounds of petroleum-derived naphthalene) amounted to 719 million pounds,
compared with 854 million pounds in 1969. In 1970 the output of creosote
oil for wood preservation was 129 million gallons (100 percent creosote
basis), compared with 137 million gallons in 1969. Production of road
tar in 1970 was 53 million gallons, compared with 60 million gallons in
1969.
Some of the products obtained from tars and included in the
statistics in table 1 are derived from other products for which data
are also included in the table. The statistics, therefore, involve
considerable duplication, and for this reason no group totals or grand
totals are given. It is estimated, that, after duplication has been
eliminated insofar as possible, the net value of the output (from all
sources) of these products and of tar burned as fuel was $634 million
in 1970, compared with $640 million in 1969 and $574 million in 1968.
The total value of sales of those products derived from coke-oven gas
and tars shown in table 1 (exclusive of coal tar itself) , amounted to
$132 million in 1970, compared with $141 million in 1969.
TAR AND TAR CRUDES
TABLE 1. --Tar and tar crudes: U.S. production and sales, 1970 9
[Listed below are all tar crudes for which any reported data on production or sales may be published. (Leaders are
used where the reported data are accepted in confidence any may not be published or where no data were reported.)
Table 2 lists separately gll products for which data on production or sales were reported and identifies the manu-
facturers reporting to the U.S. Tariff Commission]
Sales
Quantity
Unit
value'
Tar : Coke-oven operators
Crude light oil:' Coke-oven operators
Intermediate light oil: Coke-oven operators
Light-oil distillates:
Benzene, specification and industrial grades,
total' ■* --
Coke-oven operators
Petroleum operators
Toluene, all grades, total' "*
Coke-oven operators
Petroleum operators
Xylene, all grades
Coke-oven operators
Petroleum operators
Solvent naphtha, total
Coke-oven operators
Tar distillers
Naphthalene, crude (tar distillers and coke-oven
operators), total
Solidifying at--
Less than 74° C
74° C. to less than 79° C
Crude tar-acid oils: ' Coke-oven operators-
Creosote oil (Dead oil) (tar distillers and coke-
oven operators) (100% creosote basis),
total'
Distillate as such (100% creosote basis)
Creosote content of coal-tar solution (100%
creosote basis) '
1
,000
gal
1
,000
gal
1
,000
gal
1
,000
gal
1
,000
gal
1
,000
gal
1
000
gal
1
000
gal
1
,000
gal
1
,000
gal
1
000
gal
1
,000
gal
1
000
gal
1
,000
gal
1
000
gal
1
000
Ib-
1
000
Ib-
1
000
Ib-
1
000
gal
1,000 gal-
1,000 gal-
1,000
All other distillates, total 1,000 gal'
Coke-oven operators, total 1,000 gal--
From light oil 1,000 gal--
Other° ! 1,000 gal--
Tar distillers' 1,000 gal--
Tar, road 1,000 gal-
Tar, refined, for other uses 1,000 gal--
Pitch of tar (tar distillers and coke-oven i
operators), total I 1,000 tons
1,000 tons
Soft (water softening point less than 110° F.)--
Medium (water softening point 110° F. to
160° F.)
Hard (water softening point over 160° F.)'°
1,000 tons
1,000 tons
760,926
244,107
5,066
1,133,520
93,492
1,040,028
829,607
17,041
812,566
537,637
4,501
533,136
4,539
3,707
832
428,086
19,364
408,722
90^038
7,956
4,693
3,263
82,082
53,005
9,712
371, -203
98,060
1,187
653,977
92,117
561,860
430,478
16,765
413,713
453,913
4,752
449,161
3,288
1,000
doVlars
35,804
11,888
102
143,331
19,793
123,538
3,093
74,285
75,794
945
74,849
536
18,804
22,686
15,892
'6,794
.855
6,227
3,019
3,208
54,628
53,785
9,565
284
12,620
7,289
2,263
46,401
203
767
C)
.14
.24
43.64
38.19
Unit value per gallon, pound, or ton, as specified.
Includes only data for coal tar reported to the Division of Fossil Fuels, U.S. Bureau of Mines. Data on U.S. pro-
duction of water-gas tar and oil-gas tar are not collected by the Tariff Commission, but according to trade publica-
tions, production of these tars amounted to 21 million gallons in 1968.
Data reported by tar distillers are not included because publication would disclose the operations of individual
Note. --Statistics for materials produced in coke and gas-retort ovens are compiled by the Division of Fossil Fuels,
U.S. Bureau of Mines, Department of the Interior. Statistics for materials produced in tar and petroleum refineries
are compiled by the U.S. Tariff Commission.
10 SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1.-- Tar and tar crudes: U.S. production and sales, 1970- -Continued
Footnotes foT table 1 — Continued
companies. Production of benzene, toluene, and xylene by tar distillers decreased in 1970, compared with 1969.
The annual production statistics for petroleum operators on benzene, toluene, and xylene are not comparable with
the combined monthly production figures, due to fiscal year revisions.
" Includes data for material produced for use in blending motor fuels.
^ Statistics represent combined data for the commercial grades of naphthalene. Because of conversion of naphtha-
lene from one grade to another, the figures may include some duplication.
' Statistics include data only for creosote oil sold for, or used in, wood preserving.
' In 1970, production of coal tar solution containing creosote (100% solution basis) amounted to 38,676 thousand
gallons; sales were 39,593 thousand gallons, valued at 6,794 thousand dollars, with a unit value of $0.17 per gallon.
° Includes data for crude sodium phenolate.
' Includes data for crude light oil, benzene, toluene, xylene, ethylbenzene, rubber-reclaiming oils, pyridine
crude bases, crude tar-acid oils, crude cresylic acid, methylnaphthalene, crude tar for other uses, and sales of
solvent naphtha and naphthalene solidifying at 74° C. to less than 79° C.
'" Includes hard pitch and pitch emulsion.
TABLE lA. --Tar: U.S. production and consumption, 1969 and 1970
(In thousands of gallons)
Product
1969
1970
PRODUCTION
768,766
760,926
CONSUMPTION
765,886
767,299
667,150
657,731
282,785
384,365
98,065
671
280,892
376,839
107,967
1,601
oven plants for roads and upkeep
Reported to the Division of Fossil Fuels, U.S. Bureau of Mines.
^ Reported to U.S. Tariff Commission. Represents tar purchased from companies operating coke ovens and gas-
retort plants and distilled by companies operating tar-distillation plants. Statistics also include tar
consumed other than by distillation or as fuel by tar distillers.
TAR AND TAR CRXIDES
TABLE IB. --Tar and tar crudes: Summary of U. S. production of specified products, 1967, 1969-1970
Unit
of
quantity
Increase, or decrease (-)
1970 over
1967
1970 over
1969
Tar
Benzene :
Coke-oven operators-
Petroleum operators-
Total
Toluene:
Coke-oven operators-
Petroleum operators-
Total
Xylene:
Coke-oven operators-
Petroleum operators-
Total
Naphthalene:
Crude ■
Petroleum naphthalene, all
grades
Total
Creosote oil (Dead oil) :
Distillate as such (100%
creosote basis)
Creosote content of coal-tar
solution (100% creosote
basis)
Total
1,000 gal--
1,000 gal--
1,000 gal--
1,000 gal--
1,000 gal-
1,000 gal-
1,000 gal-
1,000 gal-
1,000 gal-
1,000 gal-
1,000 Ib-
1,000 Ib-
1,000 gal—
1,000 gal-
1,000 gal-
90,642
878,704
101,695
1,083,653
760,926
93,492
1,040,028
Percent
-2.5
3.1
18.4
19,357
624,454
19,603
739,855
1,133,520
17,041
812,566
-12.0
30.1
643,811
5,246
"376,596
4,501
"533,136
-18.0
18.6
454,837
520,991
376,679
495,863
357,637
428,086
290,545
-17.8
-22.9
897,670
17,402
853,500
18,598
103,374
25,559
126,234
136,914
128,933
Peraent
-1.0
-13.1
9.8
-14.2
41.6
-13.7
-18.8
' Standard reference base period for Federal Government general-purpose index numbers.
^ Includes data for coal tar reported to the Division of Fossil Fuels, U.S. Bureau of Mines.
^ Data reported by tar distillers are not included because publication would disclose the operations of individual
companies .
'' Includes data for material produced for use in blending motor fuels. Statistics are not comparable with monthly
figures which included some o-xylene.
5 Naphthalene solidifying at less than 79° C. Figures include production by tar distillers and coke-oven operators
and represent combined data for the commercial grades of naphthalene to avoid disclosure of the operations of
individual companies. Because of conversion between grades, the figures may include some duplication. Statistics
on naphthalene refined from domestic crudes are reported in the section on cyclic intermediates.
^ Includes data for creosote oil produced by tar distillers and coke-oven operators and used only in wood preserving.
SYNTHETIC ORGANIC CHEMICALS, 1970
-Tar crudes for which U.S. production or sales were reported
identified by manufacturer, 1970
[Tar crudes for which separate statistics are given in table 1 are marked with an asterisk (*] ; products not so
marked do not appear in table 1 because the reported data are accepted in confidence and may not be published.
Manufacturers' identification codes shown below are taken from table 3. Table 3 identifies all U.S. producers of
tar crudes (except producers that report to the Division of Fossil Fuels, U.S. Bureau of Mines)]
Manufacturers' identification codes
(according to list in table 3)
*Crude light oil'
Light-oil distillates:
*Benzene, specification and industrial grades'
*Toluene, all grades'
*Xylene, all grades'
*Solvent naphtha '
*A11 other light-oil distillates'
Pyridine crude bases'
*Naphthalene, crude, solidifying at--
*Less than 74° C'
*74° C. to less than 79° C:'
74° C. to less than 76° C
76° C. to less than 79° C
Methy Inaphthal ene
*Crude tar-acid oils:'
Tar-acid content 5% to less than 24%
Tar-acid content 24% to 50%
Cresylic acid, crude
*Creosote oil (Dead oil) :
*Distillate as such'
*Creosote in coal-tar solution'
*A11 other distillate products'
*Tar, road
Tar for other uses:
Crude
♦Refined'
*Pitch of tar:
*Soft (water softening point less than 110° F.)'
*Medium (water softening point 110° F. to 160" F.)'
*Hard (water softening point above 160° F.)'
Pitch emulsion
CBT.
ACY, KPP.
ACY, KPP.
ACY.
ACY, NEV, PAI.
ACY, KPT. PAI.
ACP, KPT.
COP.
KPT.
ACP, KPT.
KPT.
ACP, KPT, RIL.
ACP, RIL, WTC.
ACP, KPT, PRD.
ACP, CBT, COP, HUS, KPT, RIL, IVTC.
ACP, KPT, RIL, WTC.
ACP, KPT.
ACP, KPT, RIL.
KPT.
ACP, KPT, RIL.
ACP, KPT, WTC.
ACP, CBT, COP, KPT, RIL, WTC.
ACP, HUS, KPT, RIL.
JEN.
1 Does not include manufacturers' identification codes for producers who report to the Division of Fossil Fuels,
U.S. Bureau of Mines. Those producers are listed in the U.S. Bureau of Mines Mineral Industry Survey, July 30,
1971, entitled "Coke Producers in the U.S. in 1970".
TABLE 3. --Tar and tar crudes: Directory of manufacturers, 1970
ALPHABETICAL DIRECTORY BY CODE
[Names of manufacturers that reported production or sales of tar and tar crudes to the U.S. Tariff Comniisson for
1970 are listed below in the order of their identification codes as used in table 21
Code
identi-
fication
Name of company
Code
identi-
fication
Name of company
ACP
ACY
Allied Chemical Corp., Plastics Div.
American Cyanamid Co.
KPT
Koppers Co ., Inc., Organic Materials Div.
CBT
COP
Samuel Cabot, Inc.
Coopers Creek Chemical Corp.
NEV
Neville Chemical Co.
HUS
Husky Briquetting, Inc.
PAI
PRD
Pennsylvania Industrial Chemical Corp.
Productol Chemical Co., Inc.
JEN
Jennison-Wright Corp.
RIL
Reilly Tar § Chemical Corp.
KPP
Sinclair- Koppers Co.
WTC
Witco Chemical Co., Inc.
Note. --For complete names and addresses of the above reporting companies, refer to table 1 in the Appendix.
CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS ^^
FOR CHEMICAL CONVERSION
Crude products that are derived from petroleum and natural gas^
are related to the intermediates and finished products made from such
crudes in much the same way that crude products derived from the dis-
tillation of coal tar are related to their intermediates and finished
products. Many of the crude products derived from petroleum are
identical with those derived from coal tar (e.g., benzene, toluene,
and xylene). Considerable duplication exists in the statistics on the
production and sales of petroleum crudes because some of these crude
chemicals are converted to other crude products derived from petroleum
and because data on some production and sales are reported at succes-
sive stages in the conversion process. Notwithstanding these duplica-
tions, the statistics are sufficiently accurate to indicate trends in
the industry and to serve as a basis for general comparison. Many of
the crude products for which data are included in the statistics may
be used either as fuel or as basic materials from which to derive other
chemicals, depending on prevailing economic conditions; but in this
report every effort has been made to exclude data on materials that are
used as fuel; however, data are included on toluene and xylene which are
used in blending aviation and motor fuel.
The output of crude products derived from petroleum and natural gas
as a group amounted to 77,879 million pounds in 1970, or 9.2 percent
more than the 71,315 million pounds reported for 1969 (table 1).^ The
larger output in 1970 is accounted for chiefly by increased production
of ethylene, propane, xylenes, and ethane. Sales of crude chemicals
from petroleum in 1970 amounted to 43,439 million pounds, valued at
$1,061 million, compared with 39,240 million pounds, valued at $1,001
million, in 1969.
The output of aromatic and naphthenic products irom petroleum
cunounted to 21,079 million pounds in 1970, compared with 19,134 million
poimds in 1969. Sales in 1970, which amounted to 13,571 million pounds,
valued at $323 million, were 1803 million pounds larger, and valued at
$22 million more, than those in 1969. The output of 1° and 2° benzene
from petroleum amounted to 7,675 million pounds in 1970--4.0 percent
less than the 7,997 million pounds produced in 1969. The output of
toluene in 1969 was 5,907 million pounds--9.8 percent more than the
5,379 million pounds produced in 1969. Production of xylene was 3,844
million pounds in 1970, compared with 2,715 million pounds in 1969.
These figures include toluene and xylene used in blends in aviation and
motor-grade gasolines. Production of naphthalene, 291 million pounds
in 1970 was 67,092 thousand pounds less than production in 1969. The
output of 24.7 million pounds of naphthenic acids in 1970 was 3.3 mil-
lion pounds less than that produced 1969.
"^ Statistics on aromatic chemicals from coal tar are reporterl in
"Tar and Tar Crudes".
^ See also table 2 which lists these products and identifies the manu-
facturers by codes. These codes are given in table 3.
462-669 O - 72 - 2
14 SYNTHETIC ORGANIC CHEMICALS, 1970
Production of all aliphatic hydrocarbons and derivatives from
petroleum and natural gas was 56,800 million pounds in 1970, compared,
with 52,182 million pounds in 1969. Sales of these products were
29,868 million pounds, valued at $738 million, in 1970 compared with
27,472 million pounds, valued at $701 million in 1969. The statistics
on production of acetylene include only acetylene produced from hydro-
carbons and used as raw material in the production of other chemicals.
Total production of acetylene for chemical synthesis is reported to
the U.S. Bureau of the Census. In 1970, production of acetylene from
hydrocarbon sources, amounted to 472 million pounds. Production of
ethylene was 18,089 million pounds in 1970--10.1 percent more than the
16,436 million pounds produced in 1969. The output of propylene and
propane-propylene mixture was 6,641 million pounds in 1970--8.2 per-
cent less than the 7,235 million pounds produced in 1969. Production
of 1,3-butadiene, one of the principal ingredients of S-type synthetic
rubber, was 3,101 million pounds in 1970, compared with the output of
3,123 million pounds in 1969, the largest on record.
The following tabulation shows the number of companies that re-
ported production of organic chemical crudes in 1970.
of
Chemical group companies
Tar crudes 13
Petroleum crudes 74
CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS FOR CHEMICAL CONVERSION
TABLE 1. — Crude products from petroleum and natural gas for chemical conversion: U.S. production
and sales, 1970
[Listed below are the crude products from petroleum and natural gas for chemical conversion for which any reported
data on production or sales may be published. (Leaders are used where the reported data are accepted in confi-
dence and may not be published or where no data were reported.) Table 2 lists separately all products from
petroleum and natural gas for chemical conversion for which data on production or sales were reported and identi-
fies the manufacturers of each]
Sales
Quantity
Grand total
AROMATICS AND NAPHTHENES^
Total
Benzene (1° and 2°)
Naphthalene, all grades
Naphthenic acid, total
Acid number less than 150
Acid number 150 and over
Toluene, all grades, total
Nitration grade, 1°
Pure commercial grade, 2°
All other*
Xylenes, mixed, total
Xylene, 3°
Xylene, 5°
All other'
All other aromatics and naphthenes*
ALIPHATIC HYDROCARBONS
Total
Cj hydrocarbons, total
Acetylene 5
Ethane
Ethylene
Cj and Cj hydrocarbons, mixed
Cj hydrocarbons, total
Propane
Propylene^
Ci, nydrocarbons, total
1,3-Butadiene, grade for rubbers (elastomers) -
Butadiene and butylene fractions
n- Butane
1-Butene
1-Butene and 2-butene mixtures'
Isobutane
Isobutylene
All other 8
C5 hydrocarbons, total
Isoprene (2-Methyl-l,3-butadiene)
Pentenes, mixed
All other'
See footnotes at end of table.
1,000
pounds
77,879,080
1,000
pounds
43,438,980
1,000
dollars
1,060,947
21,079,182
7,675,406
290,545
24,662
4,146,527
201,474
10,269
14,393
5,907,400
5,007,740
4,184,190
427,505
1,295,705
3,843,910
2,382,466
625,274
3,238,451
513,640
592,179
2,738,091
504,044
569,741
2,164,666
23,523,203
471;685
4,962,433
18,089,085
2,128,452
15,426,916
3,523,887
5,046,920
9,993,278
8,786,067
6,640,849
10,472,783
6,894,751
3,098,527
6,658,458
3,101,437
743,492
2,757,102
58,139
1,594,461
809,500
580,746
827,906
1,142,935
1,947,218
409,320
1,276,126
50,183
1,621,445
211,152
327,194
815,820
490,584
351,610
330,105
461,220
65,778
424,806
123,538
10,562
74,285
60,683
13,602
74,849
12,017
14,002
48,830
7 38,148
30,707
156,053
157,356
74,749
82,607
266,722
163,967
12,846
13,278
2,554
43,894
2,224
12,600
15,359
16,391
6,700
9,691
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. — Crude products from petroleum and natural gas for chemical conversion: U.S. production
and sales, 1970- -Continued
Production
Quantity
Unit
value'
ALIPHATIC HYDROCARBONS- -Continued
All other aliphatic hydrocarbons, derivatives, and mixtures,
total
Alpha olefins'"
Diisobutylene (Diisobutene)
Heptenes, mixed
Hexanes and other Cj hydrocarbons
Nonene (Tr ipropylene)
n- Paraffins, total
Carbon chain length, Cio-Cji,
Other
Polybutene'i
Tetrapropylene
Hydrocarbon derivatives ^^
All other"
1,000
pounds
4,105.609
1,000
pounds
1,000
do I lars
110.919
Per
pound
$0.027
185,055
36,032
138,640
275,863
323,782
1,015,611
508,199
507,412
155,338
371,866
117,091
1,486,331
129,662
72,889
230,173
224,411
520,960
520,960
145,877
180,226
113,775
2,537,055
8,105
2,396
7,394
8,429
16,997
16,997
9,678
6,213
9,096
42,611
.062
.033
.032
.038
.033
.033
.066
.034
.080
.017
' Calculated from rounded figures.
^ The chemical raw materials designated as aromatics are in some cases identical with those obtained from the
distillation of coal tar; however, the statistics given in the table above relate only to such materials as are
derived from petroleum and natural gas. Statistics on production or sales of benzene, toluene, xylene, and
naphthalene from all sources are given in tables 1 and IB of "Tar and Tar Crudes".
^ Includes toluene and xylene used as solvents, as well as that which is blended in aviation and motor gasolines.
Includes data for 90-percent benzene, crude cresylic acid, alkyl aromatics, distillates, solvents, and miscellaneous
cyclic hydrocarbons.
^ Production figures on acetylene from calcium carbide for chemical synthesis are collected by the U.S. Bureau of
the Census .
Includes data for propane-propylene mixture.
The statistics represent principally the butene content of crude refinery gases from which butadiene is
manufactured.
° Includes data for 2-butene, mixed butylenes, and mixed olefins.
Includes data for isopentane, pentenes, and C5 hydrocarbon mixtures.
'" Includes data for the following molecular weight ranges: Ce-C,; Cg-Cn,; Cn-CisJ C15-C20; and Cu-Cjj.
'•' Includes compounds having a molecular weight of 3,000 or less.
'^ Includes data for butyl, ethyl, methyl, and miscellaneous mercaptans .
Includes data for acetylene (sales only), ethane-ethylene mixture, heptane, methane, octanes, and hydrocarbon
mixtures .
CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS FOR CHEMICAL CONVERSION
TABLE 2.
-Crude products from petroleum and natural gas for chemical conversion for which U.S.
production or sales were reported, identified by manufacturer, 1970
[Crude products from petroleum and natural gas for chemical conversion for which separate statistics are given in
table 1 are marked below with an asterisk (*) ; products not so marked do not appear in table 1 because the re-
ported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below
are taken from table 3. An x signifies that the manufacturer did not consent to his identification with the
designated product]
Manufacturers' identification codes
(according to list in table 3)
AROMATICS AND NAPHTHENES
*Benzene (except motor grade) :
* Benzene, 1°
*Beniene, 2°
Cresylic acid, crude
*Naphthalene, all grades
*Naphthenic acids :
*Acid number lower than 150
Acid number 150-199
Acid number 200-224
Acid number 225-249
Sodium carbolate and phenate, crude
*Toluene:
♦Nitration grade, 1°
*Pure commercial grade, 2°
Solvent grade, 90%
All other
♦Xylenes, mixed:
Aviation grade
*3° grade
*5° grade
All other
All other aromatics, naphthenes, distillates and solvents
ALIPHATIC HYDROCARBONS
Ci hydrocarbon: Methane
'^2 hydrocarbons:
♦Acetylene
♦Ethane
♦Ethylene
♦C2 and C3 hydrocarbons, mixed
♦Ca hydrocarbons:
♦Propane
♦Propane-propylene mixture
♦Propylene
♦Ci, hydrocarbons:
♦1,3- Butadiene, grade for rubbers (elastomers)
♦Butadiene and butylene fractions
♦nT Butane
♦1-Butene
2-Butene
ACU, APR, ASH, ATR, CCP, CPI, CSD, CSC, CSP, DLH,
ENJ, GOC, GRS, HES, MOC, MON, PLC, PPR, SHC, SHO,
SKO, SM, SNT, SOG, SUN, TOC, TX, UCC, UOC, VPT.
DOW, SHO, SOC.
PRD.
ASH, COL, MON, SUN, TID.
ATR, SOC, SUN, TX.
ATR, PRD, SOC, SUN.
ATR, PRD, SOC.
SOC.
ATR.
ASH, ATR, CCP, CSD, CSP, DLH, ENJ, GOC, HES, MOC,
MON, PLC, PPR, SHC, SHO, SNT, SOG, SUN, TOC, TX,
UCC, UOC, VPT.
ATR, CPI, DOW, ENJ, LEN, MON, UCC.
CO, FG, SKO.
ACC, ATR, ELP, GRS, PLC, SM, SOC, SUN, TX.
CSD, CSO.
DLH, MOC, PPR, UOC.
ASH, HES, SOG, TX.
ATR, CCP, CPI, CSD, CSP, ENJ, HCR, LEN, MON, PPR,
SHC, SHO, SNT, SOC, STY, TOC, UCC, VPT.
ACC, ACU, ATR, CBN, CPI, CPX, DUP, ELP, ENJ, FG,
GOC, JCC, LEN, MOC, MON, OMC, PLC, PPR, SHC,
SOC, SOG, SOI, TX, USI, VPT.
CCP, MON.
DOW, DUP, MNO, MON, UCC, x.
ACU, ATR, CCP, ENJ, MON, PAN, PLC, SHO, SM, TX, USI.
ACU, ATR, BFG, CBN, CCP, CO, CPX, DOW, DUP, EKX, ELP,
ENJ, GOC, JCC, KPP, MON, OMC, PLC, SHC, SM, SNO,
UCC, USI.
ATR, CSO, ENJ, PLC.
AMO, APR, ASH, ATR, CCP, COR, CPI, CSD, CSO, CSP,
ENJ, GOC, GRS, JCC, MOC, OMC, PAN, PLC, SHC, SHO,
SM, SNT, SOG, SOI, SUN, TX, UOC, USI.
GOC.
ACU, AMO, ASH, ATR, BFG. CBN, CCP, CO, COR, CPX,
CSO, CSP, DOW, DUP, EKX, ELP, ENJ, GOC, JCC, KPP,
MOC, MON, PLC, SHO, SIO, SM, SNT, SOG, SOI, SUN,
TX, UCC, UOC.
APL, ATR, CBN, CPY, DOW, DUP, ELP, ENJ, FRS, MON,
PLC, PTT, SBI, SHC, SHO, SM, SOC, TID, TUS, UCC.
ACU, ATR, CO, CPX, DOW, EKX, GOC, GYR, KPP, PLC,
SHC, SHO, SOC, UCC.
ATR, COR, CPI, CSD, CSP, GRS, OMC, PAN, PLC, SHO,
SM, SNT, SOC, SOG, SUN, USI.
GOC, PLC, PTT.
MON, PLC.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Crude products from petroleum and natural gas for chemical conversion for which U.S.
production or sales were reported, identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
ALIPHATIC HYDROCARBONS--Continued
*Ci, hydrocarbons--Continued
*1-Butene and 2-butene mixture
*Isobutane
*Isobutylene
All other
*C5 hydrocarbons:
Isopentane (2-Methylbutane)
*Isoprene (2 -Me thy 1-1, 3 -butadiene)
nrPentane
*Pentenes, mixed
All other
*Cg hydrocarbons:
Hexane
Neohexane (2,2-Dimethylbutane)
All other
C 7 hydrocarbons :
n-Heptane
*Heptenes, mixed
All other
Cj hydrocarbons:
*Diisobutylene (Diisobutene) '
n-Octane
All other
Hydrocarbons, Cg and above:
*Nonene (Tripropy 1 ene)
*Polybutene
*Tetrapropylene
Tridecene concentrate
Triisobutylene
All other
*A11 other aliphatic hydrocarbons, derivatives and
mixtures :
Hydrocarbons:
*Alpha olefins--Molecular weight ranges:
C6-C7
Cs-Cio
C11-C15
All other
*n-Paraffins--Carbon chain length:
C5-C3
C9"Ci5
*Cio-Cii,
Cl0"Cl6
All other
*Hydrocarbon derivatives:
1-Butanethiol
tert-Butyl-mercaptan (2-Methyl-2-propanethiol)
Cyclohexyl mercaptan
Di-tert -butyl disulfide
Di-tert-nonylpolysulfide
Ethyl mercaptan (Ethanethiol)
Isopropyl mercaptan
Methyl mercaptan (Methanethiol)
tert-Nonyl mercaptan
n-Propyl mercaptan (I-Propanethiol)
All other
Mixtures, not elsewhere classified
ATR
ATR
APR
APR
APL
APR
ENJ
PLC
ENJ
PLC
APR
EKX
CSD
ENJ
ATR
SOG
ENJ
ATR
ACC
ATR
ENJ
ATR
ATR
ATR, CSO, ENJ, GOC, PLC, PTT, SHO, SOC, TX, UOC.
CSP, ELP, OMC, PAN, PLC, SHO, SUN, TX, USI .
ENJ, OCC, SHO, UOC.
BFG, ENJ, JCC, MON, PLC, SM, USI.
PAN, PLC, SHO, SM.
ENJ, GYR, MON, SHC .
PLC.
GYR, MON, TX.
UCC, USI.
PLC, SOG.
PLC, SWC, UOC.
PLC, SOG.
ENJ, GOC, HOU, SOI, TID.
HCR, PLC, TX, UCC. UOC.
ENJ, GOC, HOU, UOC.
CSD, SOC, SOI.
CO, COR, ENJ, GOC, SOC, SUN, TX, UOC.
CO, EKX, ENJ, GOC, HCR, HOU, KPP, PLC, SOC, SUN,
TID, UCC.
GOC, GYR, SOC.
GOC, SOC.
ENJ, GOC, SOC.
EKX, GOC, SOC.
SOG.
SOG.
ENJ, SOG, UCC.
CO.
ATR, UCC.
PAS, PLC.
PAS, PLC.
PAS.
PLC.
PAS.
PAS.
PAS.
ACC, PAS.
PAS.
PAS, PLC.
EKX, PAS, PLC, UCC.
GYR, MON.
CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS FOR CHEMICAL CONVERSION
TABLE 3, --Crude products from petroleum and natural gas for chemical conversion:
Directory of manufacturers, 1970
ALPHABETICAL DIRECTORY BY CODE
[Names of manufacturers that reported production or sales of crude products from petroleum and natural gas for
chemical conversion to the U.S. Tariff Commission for 1970 are listed below in the order of their identificatio
codes as used in table 2]
Code
Code
identi-
Name of company
identi-
Name of company
fication
fication
ACC
Amoco Chemicals Corp.
KPP
Sinclair- Koppers Co.
ACU
Allied Chemical Corp., Union Texas
Petroleum Div.
LEN
Leonard Refineries, Inc.
AMO
American Oil Co. (Texas 5
APL
Ameripol, Inc.
MNO
Monochem, Inc.
APR
Atlas Processing Co.
MOC
Marathon Oil Co., Texas Refining Div.
ASH
Ashland Oil, Inc.
MON
Monsanto Co.
ATR
Atlantic Richfield Co. , ARCO Chemical Co. Div.
OCC
Oxirane Chemical Co.
BFG
B. F. Goodrich Co. , B. F. Goodrich Chemical
Co. Div.
OMC
Olin Corp.
PAN
Amoco Production Co.
CBN
Cities Service Co., Petrochemical Div.
PAS
Pennwalt Corp.
CCP
Crown Central Petroleum Corp.
PLC
Phillips Petroleum Co.
CO
Continental Oil Co.
PPR
Phillips Puerto Rico Core, Inc.
COL
Collier Carbon § Chemical Corp.
PRD
Productol Chemical Co., Inc.
COR
Commonwealth Oil S Refining Co., Inc.
PTT
Petro-Tex Chemical Corp.
CPI
Commonwealth Petrochemicals, Inc.
CPX
Chemplex Co.
RH
Rohm § Haas Co.
CPY
Copolymer Rubber 5 Chemical Corp.
CSD
Cos den Oil S Chemical Co.
SBI
Standard Brands Chemical Industries, Inc.
CSO
Cities Service Oil Co.
SHC
Shell Oil Co., Shell Chemical Co. Div.
CSP
Coastal States Petrochemical Co.
SHO
Shell Oil Co.
SIO
Standard Oil Co. of Ohio
DLH
Amerada Hess Corp. , Hess Oil S Chemical Div.
SKO
Skelly Oil Co.
DOW
Dow Chemical Co.
SM
Mobil Chemical Co.
DUP
E. I. duPont de Nemours § Co., Inc.
SM
Mobil Oil Corp.
SNO
SunOlin Chemical Co.
EKX
Eastman Kodak Co., Texas Eastman Co. Div.
SNT
Suntide Refining Co.
ELP
El Paso Products Co.
SOC
Standard Oil Co. of California, Chevron
ENJ
En jay Chemical Co.
Chemical Co.
SOG
Charter International Oil Co.
FG
Foster Grant Co. , Inc.
SOI
American Oil Co. (Maryland)
FRS
Firestone Tire 5 Rubber Co. , Firestone
STY
Styrochem Corp.
Synthetic Rubber g Latex Co. Div.
SUN
Sun Oil Co.
SWC
Shell S Commonwealth Chemicals, Inc.
GOC
Gulf Oil Corp., Gulf Oil Chemicals
Co. - United States
TID
Getty Oil Co.
GRS
Chainplin Petroleum Co. , Corpus
TOC
Tenneco Oil Co.
Christi Refinery
TUS
Texas-U.S. Chemical Co.
GYR
Goodyear Tire 5 Rubber Co.
TX
Texaco, Inc.
HCR
Hercor Chemical Corp.
UCC
Union Carbide Corp.
HES
Hess Oil Virgin Islands Corp.
UOC
Union Oil Co. of California
HOU
Air Products § Chemical, Inc., Houdry
US I
National Distillers § Chemical Corp.,
Process 5 Chemical Co. Div.
U. S. Industrial Chemicals Co. Div.
JCC
Jefferson Chemical Co., Inc.
VPT
Vickers Refining Co., Inc.
refer to table 1 in the Appendix.
CYCLIC INTERMEDIATES 21
Cyclic intermediates are synthetic organic chemicals derived princi-
pally from petroleum and natural gas and from coal-tar crudes produced
by destructive distillation (pyrolysis) of coal. Most cyclic intermediates
are used in the manufacture of more advanced synthetic organic chemicals
and finished products, such as dyes, medicinal chemicals, elastomers
(synthetic rubbers), pesticides, and plastics and resin materials. Some
intermediates, however, are sold as end products without further proces-
sing. For example, refined naphthalene may be used as a raw material in
the manufacture of 2-naphthol or of other more advanced intermediates,
or it may be packaged and sold as a moth repellent or as a deodorant.
In 1970 almost half of the total output of cyclic intermediates was sold;
the rest was consumed chiefly by the producing plants in the manufacture
of more advanced intermediates and finished products .
Total production of cyclic intermediates (table 1) in 1970--28,257
million pounds--was 1.1 percent less than the output of 28,571 million
pounds reported for 1969, the largest output on record. The smaller
output of cyclic intermediates in 1970 reflects the decreased demand by
the chemical products industries, particularly those industries that pro-
duce plastics materials, dyes, pigments, and plasticizers. Sales of
cyclic intermediates in 1970 amounted to 12,976 million pounds, valued
at $1,260 million, compared with 12,398 million pounds, valued at $1,208
million, in 1969. In terms of quantity, sales of cyclic intermediates in
1970 were 4.7 percent larger than those in 1969 and in terms of value,
4.3 percent larger.
Production of ethylbenzene in 1970 was 4,827 million pounds, or
1.6 percent less than the 4,907 million pounds reported for 1969. Out-
put of styrene in 1970 was 4,335 million pounds, a decrease of 6.7 per-
cent from the 4,648 million pounds in 1969. Other intermediates whose
production exceeded 1 billion pounds in 1970 were cumene (1,983 million
pounds), cyclohexane (1,841 million pounds), phenol (1,755 million pounds),
p-xylene (1,590 million pounds), dimethyl terephthalate (1,447 million
pounds), and terephthalic acid (1,329 million pounds). The output of
other large-volume intermediates in 1970 compared with 1969 were: Ortho-
xylene, 799 million pounds (6.1 percent less than in 1969); phthalic
anhydride, 734 million pounds (3.4 percent less); cyclohexanone, 714
million pounds (1.5 percent larger); straight chain alkylbenzenes, 553
million pounds (4.5 percent larger); nitrobenzene, 548 million pounds
(13.1 percent larger); and isocyanates, 513 million pounds (21.7 per-
cent larger) . Production of chlorobenzene amounted to 485 million
pounds (19.4 percent less than in 1969), and production of aniline was
398 million pounds, an increase of 19.3 percent over 1969. The above
16 chemicals accounted for 84 percent of the total output of cyclic
intermediates in 1970.
^ See also table 2 of this section which lists these products alpha-
betically and identifies the manufacturers by codes. These codes are
given in table 3.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. --Cyclic intermediates: U.S. production and sales, 1970
[Listed below are all cyclic intermediates for which any reported data on production or sales may be published.
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data
were reported.) Table 2 lists alphabetically all cyclic intermediates for which data on production or sales were
reported and identifies the manufacturers of each]
Quantity
Unit
Value
1,000
pounds
Total
Acetanilide, tech
Acetoacetanilide
o-Acetoacetanisidide
o-Acetoacetotoluidide
Acetophenone, tech
Alkylbenzenes^
3'-Aminoacetanilide
4' -Aminoacetanilide (Acetyl -p-phenylenediamine)
5-Amino-2- (p-aminoanilino)benzenesulfonic acid
1-Aminoanthraquinone and salt
2-Aminoanthraquinone and salt
2-Amino-p-benzenedisulfonic acid [S03H=1]
l-Amino-2-bromo-4-hydroxyanthraquinoiie
l-Amino-2-bromo-4-p-toluidinoanthraquinone
l-Amino-5-chloroanthraquinone
l-Amino-2,4-dibromoanthraquinone
4-Amino-3-hydroxy-l-naphthalenesulfonic acid (1,2,4-Acid)
N- (4-Amino-3-methoxy-l-anthraquinonyl)-p-toluenesulfonamide
6-Amino-l,3-naphthalenedisulfonic acid (Amino I acid)
7-Amino-l,3-naphthalenedisulfonic acid (Amino G acid)
5(and 8)-Amino-2-naphthalenesulfonic acid (Cleve's acid, mixed)-
6-Amino-2-naphthalenesulfonic acid (Broenner's acid)
2-Amino-5-nitrobenzenesulfonic acid [S03H=1]
4-Amino-4'-nitro-2,2'-stilbenedisulfonic acid
.Aniline (Aniline oil)
7-Anilino-4-hydroxy-2-naphthalenesulfonic acid (Phenyl J acid)-
Anilinomethanesulfonic acid and salt
8-Anilino-l-naphthalenesulfonic acid (Phenyl peri acid)
o-Anisidine
Anisole, tech
l-Benzamido-5-chloroanthraquinone
7H-Benz[de]anthracen-7-one (Benzanthrone)
2-Benzothiazolethiol, sodium salt
[4,4'-Bi-7H-benz[de]anthracene]-7,7'-dione
l,4-Bis[l-anthraquinonylamino]anthraquinone
3-Bromo-7H-benz[de]anthracene-7-one (3-Bromobenzanthrone)
l-Brorao-4-(methylamino)anthraquinone
Campho sulfonic acid
l-Chloroanthraquinone
2-Chloroanthraquinone
Chlorobenzene, mono-
o- (p-Chlorobenzoyl)benzoic acid :
l-Chloro-2-methylanthraquinone
l-Chloro-4-nitrobenzene (Chloro-p-nitrobenzene)
4-Chloro-3-nitrobenzenesulfonamide
4-Chloro-3-nitrobenzenesulfonyl chloride
a-Chlorotoluene (Benzyl chloride)
Cresols, total — ■
o-Cresol
(ra,p)-Cresol
All other "*
Cresylic acid, refined^
Cumene
Cyclohexane '
1,000
pounds
12,976.217
1,000
dollars
1.260.395
Per
pound
4,221
4.006
644
839
814
553.166
13
187
10
955
536
435
498
497
376
264
398.362
34
522
129
1.845
298
45
1,881
32,477
681
24
271
127
531
484,914
523
266
88,854
431
426
75,131
91,414
23,110
41,007
27,297
98,334
1,983,349
1,841,052
317
3,917
686
937
1,200
1,795
1,659
677
507
See footnotes at end of table.
CYCLIC INTERMEDIATES
TABLE 1. --Cyclic intermediates: U.S. production and sales, 1970- -Continued
23
Quantity
Cyclohexanol
Cyclohexanone
1,4-Dianiinoanthraquinone
2,6-Diaininoanthraquinone
l,4-Diainino-2,3-dihydroanthraquinone
4, 4 '-Di amino- 2, 2 ' --stilbenedi sulfonic acid
4,S'-Dibenzainido-l,l'-iminodianthraquinone
1,5-Dichloroanthraquinone
o-Dichlorobenzene ■
p-Dichlorobenzene
3,3'-Dichlorobenzidine base and salts-
2,5-Dichloro-4-[3-methyl-5-oxo-2-pyTazolin-l-yl)benzenesulfonic
acid-
2,5-Dichlorosulfanilic acid
Dicyclopentadiene (includes cyclopentadiene)
p-(Diethylainino)benzaldehyde
N,N-Diethylaniline
9,10-Dihydro-l,4-dihydroxy-9,10-dioxo-2-anthracenesulfonic acid-
9,10-Dihydro-9,10-dioxo-l,5-anthracenedisulfonic acid, disodium
salt-
9,10-Dihydro-9,10-dioxo-l,8-anthracenedisulfonic acid, potassium
salt
9,10-Dihydro-9,10-dioxo-2,6-anthracenedisul£onic acid and salt
9,10-Dihydro-9,10-dioxo-l-anthracenesulfonic acid and salt (Gold
salt)-
1,4-Dihydroxyanthraquinone (Quinizarin)
1,5-Dihydroxyanthraquinone (Anthrarufin)
1 , 8-Dihydroxy-4 , 5-dinitroanthraquinone (4, S-DinitrochrysazinJ
16,17-Dihydroxyviolanthrone (Dihydroxydibenzanthrone)
N,N-Dimethylaniline
N,N-Dimethylbenzylamine
2,2-Dimethyl-l,l '-bianthraquinone
2,4-Dinitroaniline
4,4'-Dinitrostilbene-2,2'-disulfonic acid
2, 4 (and 2,65-Dinitrotoluene
Diphenylamine
1,4-Di-p-toluidinoanthraquinone
Divinylbenzene
p-Dodecylphenol
N-Ethylaniline, refined
Ethylbenzene^
N-Ethyl-N-phenylbenzylamine
Hippuric acid
Hydroquinone, tech
p-Hydroxybenzenesulfonic acid
4-Hydroxymetanilamide
3-Hydroxy-2-methylcinchoninic acid
3-Hydroxy-2,7-naphthalenedisulfonic acid, potassium 5 sodium salts-
7-Hydroxy-l,3-naphthalenedisulfonic acid and sodium salt
6-Hydroxy-2-naphthalenesulfonic acid and sodium salt
N-(7-Hydroxy-l-naphthyl5acetamide
1,1' -Iminobis[4-aminoanthraquinone]
1,1'- Iminobis [5-benzamidoanthraquinone]
7,7'-Iminobis[4-hydroxy-2-naphthalenesulfonic acid]
1 , 1 ' -Iminobis [4-nitroanthraquinone]
1 , 1 ' -Iminodianthraquinone (1,1' -Dianthrimide]
Isocyanic acid derivatives, total
Polymethylene polypheny lisocyanate
Toluene 2,4- and 2,6-diisocyanate (80/20 mixture^-
Other isocyanic acid derivatives
4,4' -Isopropylidenediphenol (Bisphenol Aj-
1,000
pounds
714,470
72
158
651
7,571
66,219
69,606
3,656
234
363
1,507
1,610
112
217
404
93
134
196
10,161
296,503
29,423
108
3,204
10,453
682
4,827,273
~" — 872
1,099
13,681
8,049
135
179
1,343
968
458
23
79
512,802
132,028
304,900
75,874
1,000
pounds
10,156
33,777
35,074
69,669
3,492
1,556
30
1,000
dollars
1,396
3,800
72,931
503
165
227
814
102
,581
,771
985
,144
924
,320
,107
,585
See footnotes at end of table.
24
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE l.--CycUc intermediates: U.S. production and sales, 1970- -Continued
Production
Quantity
Unit
value'
Leuco quinizarin (1,4,9, 10-Anthratetrol)
Melaraine
dl-p-Mentha-1 ,8-diene (Limonene)
Metanilic acid (m-Aminobenzenesulfonic acid)
p- (3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic acid
3-Methyl-l-phenyl-2-pyTazolin-5-one (Developer Z)
a-Methylstyrene
Naphthalene, solidifying at 79° C. or above (refined flake] (from
domestic crude)
3'-Nitroacetanilide
4'-Nitroacetanilide
Nitrobenzene
m-Nitrobenzenesulfonic acid and sodium salt
p-Nitrophenol and sodium salt
4'- (p-Nitrophenyl)acetophenone
5-Nitro-o-toluenesulfonic acid [SOjHsl]
5-Nitro-o-toluidine [NH2=1]
Nonylphenol
l-[ (7-0x0 -7H-benz[de]anthracene-3-yl) amino] anthraquinone
Phenol, grand total ^
Natural, from coal tar and petroleum
Synthetic, total
From cumene
Other synthetic
Phenylacetonitrile (a-Tolunitrile)
p-Phenylazoaniline (C.l. Solvent Yellow 1) and hydrochloride
Phthalic anhydride
Picolines, total ^
2 -Pi CO line (a-Picoline)
Other picolines
Sal icy! aldehyde
Salicylic acid, tech
Styrene, all grades
Terephthalic acid
Terephthalic acid, dimethyl ester
l,4,S,8-Tetrahydroxyanthraquinone, leuco derivative
3,3'-Thiobis[7H-benz[de]anthracen-7-one]
Toluene -2, 4 -diamine (4-m-Tolylenediamine)
o- (p-Toluoyl )benzoic acid
4-(o-Tolylazo)-o-toluidine (C.I. Solvent Yellow 3)
1,2,4-Trichlorobenzene
l,3,3-Trimethyl-A^,a-indolineacetaldehyde
l,3,3-Trimethyl-2-methyleneindoline (Trimethyl base)
7,7' -Ureylenebis[4-hydroxy-2-naphthalenesulfonic] (J acid Urea) —
Viol ant hrone (Dibenzanthrone)
m-Xylene
o-Xylene
p-Xylene
All other cyclic intermediates
103
68,477
7,956
1,202
176
81
19,063
IS
277
547,680
3,654
32,600
42
9,025
78,134
399
1,755,278
47,071
1,708,207
1,167,168
541,039
324
734,020
4,479
4,479
3,820
38,786
4,335,313
1,328,953
1,446,937
149
24
132,760
226
290
9,344
168
332
205
430
99,301
798,706
1,590,209
2,680,748
1,000 1,000
pounds dollars
12,737
1,786
2,165
19,312
95
32,138
769,010
28,685
740,325
542,220
198,105
572
440,846
2,839
852
1,987
2,668
7,543
2,013,221
777,145
1,293,937
1,629,380
Per
pound
789
161
803
6,429
120
3,564
53,998
2,503
51,495
37,387
14,108
292
40,126
997
298
699
2,677
3,097
130,311
103,734
23,069
81,971
365,424
Calculated from rounded figures.
^ Includes straight -chain dodecylbenzene, tridecylbenzene and other striaght-chain alkylbenzenes . Branched-chain
alkylbenzenes are included in "All other cyclic intermediates."
' Includes data for coke ovens and gas-retort ovens, reported to the Division of Fossil Fuels, U.S. Bureau of Mines,
and for tar and petroleum refineries and other producers, reported to the U.S. Tariff Commission.
"* Figures include (o,m,p)-cresol from coal tar and some m-cresol and p-cresol.
^ Does not include ethylbenzene produced and consumed in continuous-process styrene manufacture.
CYCLIC INTERMEDIATES
25
TABLE 2.
-Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970
[Cyclic intermediates for which separate statistics are given in table 1 are marked with an asterisk (*) ; cyclic
intermediates not so marked do not appear in table 1 because the reported data are accepted in confidence and may
not be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that
the manufacturer did not consent to his identification with the designated product]
Manufacturers' identification codes
(according to list in table 3J
5-Acetamido-2-aminobenzenesulfonic acid
3-[(2-Acetaiiiido-4-aminophenyl]azo] -l,S-naphthalenedi-
sulfonic acid.
2,2'- [(S-Acetamido-2-ethoxyphenyl) iminojdiethanol
2,2'-[(3-Acetamidophenyl)imino]diethanol
a-Acetamido-p-toluenesulfonamide
*Acetanilide, tech
Acetic acid, phenyl ester
*Acetoacetanilide
*o-Acetoacetanisidide
*o-Acetoacetotoluidide
2 ',4'-Acetoacetoxylidide
1 ' -Acetonaphthone
Acetone phenylhydrazone
*Acetophenone, tech
p-Acetotoluidide :
p-Acetylbenzenesulfonamide
p-Acetylbenzenesulfonic acid, sodium salt
p-Acetylbenzenesulfonylurethane
N-Acetylsulfanilyl chloride
Adenine
*Alkylbenzenes :
Dodecylbenzene (including tridecylbenzene) :
*Straight chain
Other
Alkylphenols, mixed
Alkylpiperazines, mixed
Alkylpyridines, mixed
a-dl-5-Allyl-6-imino l-methyl-5-(l-methyl-2-pentynyl)
barbituric acid.
a-dl-5-Allyl-5-(l-methyl-2-pentynyl) -1-methylbarbituric
acid.
*3'-Aminoacetanilide
*4'-Aminoacetanilide (Acetyl-p-phenylenediamine)
3'-Ainino-o-acetophenetidide -■
3 ' -Aminoacetophenone
4 ' -Aminoacetophenone
*S-Amino-2-(p-aminoanilino;)benzenesulfonic acid
l-Amino-4-(3-ajnino-4-sulfoanilino)-9,10-dihydro-9,10-
dioxo-2-anthracenesulfonic acid.
1 -Amino-4- (4-aiiiino-3-sulfoani lino) -9,10 -dihydro-9, 10-
dioxo-2-anthracenesulfonic acid.
2-(p-Aminoanilino) -5-nitrobenzenesulfonic acid
3-Amino-p-anisaiiiide
3-Amino-p-anisanilide
*l-Aminoanthraquinone and salt
*2-Aininoanthraquinone and salt
5(and 8)-Amino-l-anthraquinonesulfonic acid
N-(4-Amino-l-anthraquinonyl)anthranilic acid
N-(S-Ajnino-l-anthraquinonyl) anthranilic acid
4-Aminoantipyrine
6-Amino-3,4'-azodibenzenesulfonic acid (C.I. Acid
Yellow 9] .
Aminoazoxylene toluene homologues
p-Aminobenzamide
l-Ainino-4-benzamidoanthraquinone
GAF.
TRC.
AAP.
AAP.
SOW.
CTN, EKT, MRK, SAL.
UCC.
FMP, HST, UCC.
FMP, HST, UCC.
FMP, HST, UCC.
HST.
GIV.
DUP.
ACP, SKO, UCC.
EK.
LIL.
LIL.
LIL.
ACY, CTN, MRK, SAL.
KF.
BRP, CO, MON, UCC, WCC.
CO, SOC.
GAF, ORG.
HOU.
UCC.
LIL.
LIL.
AAP, GAF, TRC.
ACS, DUP, GAF, TRC.
AAP.
CTN, SDH.
EK.
GAF, TRC, YAW.
TRC.
TRC.
TRC.
PCW.
PCW.
AAP,
ACS,
ICI.
GAF.
DUP.
VPC.
ACY,
ACY, DUP, GAF, ICI, MAY, TRC.
ACY, GAF, TRC.
ACS.
SDH.
MAY, TRC.
26
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.
-Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
l-Amino-S-benzamidoanthraquinone
7- [p-(p-Aminobenzamido5benzaniido] -4-hydroxy-2-naphthalene-
sulfonic acid.
7- fp-Aminobenzaraido) -4-hydroxy-2-naphthalenesulfonic acid--
*2-Amino-p-benzenedisulfonic acid [SOaH^l]
o-Aminobenzenethiol
2 -Aminobenz imidazole
p-Aminobenzoic acid, tech
p-Aminobenzoic acid, 2-(dimethylainino)ethyl ester
4-Aminobenzophenone
2-Amino-6-benzothiazolecarboxylic acid
2-(m-Aininobenzoyl) -o-acetanisidide
2-Amino-l-bromo-3-chloroanthraquinone
l-Amino-4-bromo-9,10-dihydro-9,10-dioxo-2-anthracenesul-
fonic acid and sodium salt.
*l-Amino-2-bromo-4-hydroxyanthraquinone
l-Ainino-4-brorao-2-methylanthraquinone
*l-Amino-2-bromo-4-p-toluidinoanthraquinone
*l-Amino-5-chloroanthraquinone
l-Amino-8-chloroanthraquinone
2-Ainino-l-chloroanthraquinone
2-Amino-3-chloroanthraquinone
4-Amino-6-chloro-m-benzenedisulfonamide
4-Amino-6-chloro-m-benzenedisul£oamide hydrochloride
2-Aitiino-6-chlorobenzothiazole hydrochloride
o-(3-Ainino-4-chlorobenzoyl)benzoic acid
2-Ainino-5-chloro-4-ethylbenzene
l-Ainino-2-chloro-4-hydroxyanthraquinone
2-Amino-4-chlorophenol
2-Amino-6-chloropyrazine
3-Amino-6-chloropyridazine
2-Amino-5-chloro-p-toluenesulfonic acid [S03H=1]
6-Amino-4-chloro-m-toluenesulfonic acid [S03H=1]
*l-Ainino-2,4-dibromoanthraquinone '
5 (and 8)-Amino-6 , 8 (and 5,7) -dibromo-9 , lO-dihydro-9 , 10-
dioxo-1-anthracenesulfonic acid.
l-Amino-2,4-dichloroanthraquinone
2-Amino-5,6-dichlorobenzothiazole
6-Amino-2,4-dichloro-m-cresol
4'-Amino-2 'S'-diethoxybenzanilide
l-Ainino-9,10-dihydro-9, lO-dioxo-2-anthroic acid
l-Aiiiino-9,10-dihydro-9,10-dioxo-4-p-toluenesulfonamido-
2-anthracenesulfonic acid, sodium salt.
5-Amino-4,5 ' -dihydroxy-3,4 ' - [(2-methoxy-5-methyl-p-
phenylene)bis(azo)] -di-2,7-naphthalenedisulfonic acid,
5 ' -benzenesulfonate .
2-Amino-4-(a,a-dimethylbenzyl)phenol
3-Amino-9-ethylcarbazole
N-(2-Aminoethyl)-N-ethyl-ra-toluidine
3-Amino-a-ethylhydrocinnamic acid
N- [2-(4-Amino-N-ethyl-m-toluidino) ethyl]methanesulfonainide
hemisulfate.
N-Aminohexamethyleneimine
2-Amino-3-hydroxyanthraquinone
l-Ainino-4-hydroxy-2-methoxyanthraquinone
4-Amino-S-hydroxy-2, 7-naphthalenedisulfonic acid,
benzenesulfonate.
3-Amino-5-hydroxy-2, 7-naphthalenedisulfonic acid (2R acid)
monosodium salt.
4-Amino-5-hydroxy-2, 7-naphthalenedisulfonic acid (H acid),
monosodium salt.
ACY,
GAP,
ICI.
CMG,
TRC.
CMG,
GAP.
ACS,
DUP,
ICC.
FIS,
FMT.
EK.
DUP.
SOW.
DUP.
DUP.
GAP.
ICI.
ICl,
TRC.
AAP,
DUP,
TCD.
ICl.
ACS,
GAP,
ICI.
ACY,
DUP,
ICI, TRC
DUP.
DUP.
GAP,
ICI.
ABB,
MRK.
ABB.
DUP.
AAP,
ICI.
ACY.
TRC.
SW.
ACY.
ACY.
ACY,
HSC.
DUP,
HSC,
SW.
AAP,
DUP,
■ICI, TCD
ICI.
TRC.
SDC.
EK.
GAP.
DUP.
AAP,
DUP,
GAP.
TRC.
SDC.
WAY.
SDW.
WAY.
FMP.
ACS, GAP.
TRC.
TRC.
ACS.
ACS.
CYCLIC INTERMEDIATES
27
TABLE 2.-
-Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
*4-Aiiiino-3-hydroxy-l-naphthalenesulfonic acid (1,2,4-Acid)-
6-Amino-4-hydroxy-2-naphthalenesulfonic acid (Gamma acid),
sodium salt.
7-Amino-4-hydroxy-2-naphthalenesulfonic acid (J acid),
sodium salt
2-(2-Amino-5-hydroxy-7-sulfo-l-naphthylazo) -5-nitro-
benzoic acid.
l-(6-Amino-l-hydroxy-3-sulfo-2-naphthylazo) -6-nitro-2-
naphthol-4-sulfonic acid.
4-Amino-3-(3-iiiethanesulfonamidoethyl) -N,N-diethylaniline
hydrochloride.
*N-(4-Amino-3-methoxy-l-anthraquinonyl)-p-toluenesulfon-
amide.
5-Amino-6-methoxy-2-naphthalenesulfonic acid
m-[(4-Amino-3-methoxyphenyl)azo]benzenesulfonic acid
8-Amino-6-methoxyquinoline
4- [ (4-Amino-5-methoxy-o-tolyl) azo] -4-hydroxy-2, 7-naphtha-
lenedisulfonic acid, benzenesulfonate.
3-[(4-Amino-5-methoxy-o-tolyl)azo]-l,5-naphthalenedisul-
fonic acid.
7-[(4-Amino-S-methoxy-o-tolyl)azo] -1,3-naphthalenedisul-
fonic acid.
4'-Amino-N-methylacetanilide
1 - Amino- 2-methy 1 anthraquinone
4-Amino-4'-(3-methyl-5-oxo-2-pyrazolin-l-yl)-2,2 '-stil-
benedisulfonic acid.
2-Amino-3-methylpyridine
2-Amino-5-methylpyridine
2-Amino-6-methylpyridine
2-Amino-4-methylpyriraidine (2-Amino-4-methyl-l,3-diazine) ■
2-Amino-4-(methylsulfonyl) phenol
2-Amino-S-niethyl-l,3,4-thiadiazole-
l-Amino-2-methyl-4-p-toluidinoanthraquinone
4-Aminonaphth[2,3-c]acridan-5,8,14-trione
6-Aminonaphth[2,3-c]acridan-5,8,14-trione
2-Amino-l ,5-naphthalenedisulfonic acid
3-Amino-l,5-naphthalenedisulfonic acid (C acid)
3-Amino-2,7-naphthalenedisulfonic acid
4-Amino-l,6-naphthalenedisulfonic acid
*6-Amino-l,3-naphthalenedisulfonic acid (Amino 1 acid)
*7-Amino-l,3-naphthalenedisulfonic acid (Amino G acid)
l-Amino-2-naphthalenesulfonic acid (o-Naphthionic acid)--
2-Amino-o-naphthalenesulfonic acid (Tobias acid)
4-Amino-l-naphthalenesulfonic acid (Naphthionic acid)
4-Amino-l-naphthalenesulfonic acid, sodium salt
4(and 5)-Amino-l-naphthalenesulfonic acid
5-Amino-l-naphthalenesulfonic acid (Laurent's acid)
5-Amino-2-naphthalenesulfonic acid (1,6-Cleve's acid)
*5(and 8)-Amino-2-naphthalenesulfonic acid (Cleve's acid,
mixed) .
*6-Amino-2-naphthalenesulfonic acid (Broenner's acid)
8-Amino-l-naphthalenesulfonic acid (Peri acid)
8-Amino-2-naphthalenesulfonic acid (1,7-Cleve's acid)
7-Amino-l, 3,6-naphthalenetrisulfonic acid
8-Amino-l,3,6-naphthalenetrisulfonic acid (Koch's acid) —
5 (and 8)-Amino-2-naphthol
8-Amino-2-naphthol
l-Amino-2-naphthol hydrochloride
2-(4-Aiiiino-l-naphthylazo)-4-(l,l,3,3-tetramethylbutyl)-
phenol .
2-Amino-4-nitroacetanilide
ACS, GAF, TRC.
DUP, TCD, TRC.
TCD, TRC.
TRC.
EKT.
AAP,
DUP,
GAF.
TRC.
DUP,
TRC.
SDW.
TRC.
TRC.
ACS,
TRC.
ACS,
GAF.
ICl.
TRC.
RIL.
RIL.
RIL.
ACY.
ACS,
TRC.
ACY.
ICl.
DUP.
DUP.
ACY,
SDH.
GAF,
TCD,
TRC.
ACS,
TRC.
DUP.
ACS,
TCD,
TRC.
ACS,
ACY,
DUP, TCD, TRC
DUP.
ACY,
SW.
ACS,
ACY,
DUP.
ACY,
DUP.
TRC.
ACS,
TCD.
ACS.
ACS,
DUP,
TRC.
ACS,
SNA,
TRC.
ACS,
TCD,
TRC.
ACS.
DUP.
ACS.
GAF.
TRC.
EK.
GAF.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
3-Amino-5-(m-nitrobenzamide)-p-toluenesulfonic acid
*2-Ainino-5-nitrobenzenesul£onic acid [SOsH^l]
2-Aiiiino-6-nitrobenzothiazole
2-Amino-4-nitrophenol
4-Amino-2-nitrophenol
2 - Amino -(p-nitrophenylazo) naphthalene
d- 2 -Amino- 1- (p-nitrophenyl) -1, 3-propanediol
l-2-Amino-l-(p-nitrophenyl)-l,3-propanediol
*4-Amino-4' -nitro-2,2 '-stilbenedisulfonic acid
2-Amino-5-nitrothiazole
3' -Aminooxanilic acid
4'-Aminocxanilic acid
3-Ainino-2-oxazolidinone
5 -Amino- 2- [(2-oxo-5-benzimidazolinyl) amino] benzenesul-
fonic acid.
o-Aminophenol
p-Aminophenol
2-(p-Aminophenoxy)ethanol hydrochloride
(p-Aminophenyl) acetic acid
m- [ (p-Aminophenyl) azo]benzenesulfonic acid
p- [ (p-Aminophenyl) azojbenzenesulfonic acid
7-[(4-Aminophenyl)azo] -1 ,3-naphthalenedisul£onic acid
4- [ (p-Aminophenyl) azo] -1-naphthylamine
5- [ (p-Aminophenyl) azo] salicylic acid
5- [ (p-Aminophenyl)azo]salicylic acid, sodium salt
2,2 '-(ra-Aminophenylimino)diethanol, diacetate ester
2- (p-Aminophenyl) -6 -methylbenzothiazole
2- (p-Aminophenyl) -6-methyl-7-benzothiazolesul£onic acid
and salt.
1- (m-Aminophenyl) -5-oxo-2-pyrazoline-3-carboxylic acid —
S-(4-Aminophenyl)thiosulfuric acid, sodium salt
l-(Aminopropyl)cyclohexylamine
3-Aminopyrazole-4-carboxamide sulfate
2-Aminopyridine
3-Aminopyridine
4-Aminopyridine
2-Aminopyrimidine
3-Aminoquinoline
S -Aminosalicylic acid
2-Amino-4-(l,l,3,3-tetramethylbutyl)phenol hydrochloride-
2-Aminothiazole
3-Amino-p-toluamide
a-Amino-p-toluenesulfonamide
4-Amino-m-toluenesulfonic acid [S03H=1]
6-Amino-m-toluenesulfonic acid [SOsH^l]
5-Amino-2-p-toluidinobenzenesulfonic acid
m-(4-Amino-3-tolylazo)benzenesulfonic acid
3- [(4-Amino-o-tolyl)azo]-l,5-naphthalenedisulfonic acid--
7- [(4-Amino-o-tolyl)azo] -1,3-naphthalenedisulfonic acid--
16-Aminoviolanthrone
S-Amino-2,4-xylenesulfonic acid
*Aniline (Aniline oil)
Aniline hydrochloride
6-Anilino-4-hydroxy-2-naphthalenesulfonic acid (Phenyl
gamma acid) .
*7-Anilino-4-hydroxy-2-naphthalenesalfonic acid (Phenyl
J acid) .
•Anilinomethanesulfonic acid and salt
*8-Anilino-l-naphthalenesulfonic acid (Phenyl peri acid)--
GAF.
ACS, GAF, TRC.
ICC.
DUP.
ACY.
AAP.
PD.
PD.
ACS, GAF, TCD, TRC.
PCW.
CMC.
DUP.
NOR.
DUP.
SDC, TRC.
SDC.
GAF.
EK.
DUP, TRC.
ACS, ACY, DUP, TRC.
TRC.
ACS.
TRC.
ACS.
DUP.
DUP.
DUP, TRC.
TRC,
SDC.
ABB.
KF.
NEP,
NEP,
RIL.
ACY.
EK.
AAP,
GAF.
ACY,
SDH,
SDW.
ACY,
DUP,
DUP,
TRC.
TRC.
TRC.
ACY.
DUP.
ACS,
ACY.
DUP.
VPC.
RIL.
RIL.
TRC.
MRK.
DUP, GAF.
HSC, SNA.
TRC.
ACY, DUP, FST, MOB, RUC, USR.
CMC, DUP, TRC.
AAP, ACS, ACY, ATL, DUP, TRC, VPC.
ACS, DUP, EK, SDC, TCD.
CYCLIC INTERMEDIATES
29
TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 19 70- -Continued
Manufacturers' identification codes
(according to list in table 3)
8-Anilino-l-naphthalene sulfonic acid, magnesium salt —
p-Anilinophenol
o-Anisaldehyde
*o-Anisidine
p-Anisidine
o-Anisidinomethanesulfonic acid
*Anisole, tech
4-Co-Anisylazo)-o-anisidine
3-(o-Anisylazo)benzenesulfonic acid, sodium salt
Anthracene , refined
Anthranilic acid (o-Aminobenzoic acid)'
Anthra[l,9-cd]pyrazol-6(2H)-one (Pyrazoleanthrone)
Anthraquinone, 100%
1,1 '- [1,5 (and l,8)-Anthraquinonylenediamino]bis-
naphth [2 , 3-c] acridan-5 , 8, 14- trione .
N,N'-(l,5-Anthraquinonylene3dianthranilic acid
N,N'-(l,S-Anthraquinonylene)dioxamic acid
( 1 -Anthraquinony 1) - 1 , 2-hydrazinedisul f oni c acid ,
disodium salt.
Arsanilic acid and salt, tech
4' ,4' ' '-Azobis [4-biphenylcarboxylic acid]
3,3'-Azoxydianiline
Barbituric acid, sodium derivative
Benzaldehyde, tech
4-[(4-Benzamido-l-anthraquinonyl)amino]naphth-
[2, 3-c] acridan-5, 8, 14- trione.
N-(S-Benzamido-l-anthraquinonyl)-p-toluenesulfonamide--'
l-Benzamido-4-bromoanthraquinone
l-Benzajiiido-4-chloroanthraquinone
*l-Benzamido-5-chloroanthraquinone
l-(4-Benzamido-2,S-diethoxyphenyl3-3- [methyl-3-(2-sulfO'
ethyl) triazene] .
4-Benzamido-5-hydroxy-2, 7-naphthalenedisulfonic acid
7-Benzamido-4-hydrci3cy-2-naphthalenesulfonic acid
N- (4-Benzamido-6-methoxy-m-tolyl) -N- (methylazo) glycine-
Benzanilide
Benz (a) anthracene
Benz (a) anthracene- 7,1 2 -dione
*7H-Benz [de] anthracen-7-one (Benzanthrone)
m-Benzenedisulfonic acid
Benzenesulfinic acid, sodium salt
Benzenesulf on amide
Benzenesulfonic acid
Benzenesulfonic acid, methyl ester
Benzenesulfonyl chloride
l,2,4,S-Benzenetetracarboxylic-l,2:4,5-dianhydride
1,2,4-Benzenetricarboxylic acid
1,3,5-Benzenetricarboxylic acid (Trimesic acid)
1,2,4-Benzenetricarboxylic acid, 1,2-anhydride (Tri-
mellitic anhydride) .
1,3,5-Benzenetricarboxylic acid, triphenyl ester
Benzhydrol (Diphenylmethanol)
Benzidine hydrochloride and sulfate
2-Benzofuranacetonitrile
Benzoic acid, tech'
Benzoic anhydride
Benzoin
a-Benzoin oxime
Benzonitrile
Benzophenonetetracarboxylic dianhydride
*2-Benzothiazolethiol, sodium salt
SDC.
ASL.
AAP,
DUP,
MON.
DUP,
MON.
ATL,
GAP,
TRC,
VPC.
CTN,
DUP,
GIV,
LIL,
OPC, PIT
AAP.
ACS.
ACP.
ACS,
DUP,
SW.
DUP,
GAP,
TRC.
DUP,
TRC.
DUP.
GAP,
TRC.
GAP,
SW.
DUP.
ABB,
FLM.
DUP,
GAP,
TRC.
GAP.
ABB.
BPC,
HN,
VEL.
DUP.
ICI.
AAP.
GAP.
ACY,
GAP,
ICI,
MAY,
TRC.
GAP.
TRC.
TRC.
GAP.
DUP,
EK,
PCW.
EK.
EK.
AAP,
ACS,
ACY,
ATL,
DUP, GAP
KPT,
UPF.
GAP.
NES.
NES,
UPF.
EK.
NES.
DUP,
PCR.
EK.
ACC.
AGO.
BJL.
HEX,
UOP
ACS,
LAK
HN, MON, PFZ, VEL.
EK.
BPC.
RSA.
VEL.
GOG.
ACY, GYR, MON, USR.
See footnotes at end of table.
462-669 O - 72 ■
30
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers identification codes
(according to list in table 3)
IH-Benzotriazole
2H-3, l-Benzoxazine-2,4(lH}-dione
2-Benzoxazolinone-6-sulfonyl chloride
o-Benzoylbenzoic acid
Benzoyl chloride
2-Benzoyl-4-sulfobenzoic acid
N - Ben zylacet amide
Benzyl amine
4-(Benzylamino) -6-chloro-m-benzenedisulfonic acid
2- ( Benzyl amino) ethanol
p-(Benzylamino) phenol
4-Benzyl-6-chloro-3-keto-2-methyl-7-sulfamyl-l,2,4-benzyl-
thiadiazine-1, 1 -dioxide.
4- Benzyl -6- chloro-3-ket 0-7- sulf amy 1-1,2, 4-benzy Ithia-
diazine- 1,1 -dioxide.
1 -Benzyl -4, 5-dimethyl -6- (p-methoxybenzyl) -1,2,3, 6-tetra-
hydropyridine oxalate.
Benzyl disulfide
Benzyl ether (Dibenzyl ether)
5- (Benzylethylamino) -o-toluenesulfonic acid
N-Benzyl-N-ethyl-m-toluidine
3-Benzyl-l,2,3,4,5,6-hexahydro-8-hydroxy-cis-6,ll-
dimethyl-2,6-methano-3-benzazocine hydrobromide .
4,4'-Benzylidenedi-o-toluidine
4,4 ' -Benzylidinedi-2,5-xylidine
Benzylidene phthalide
p-(Benzyloxy) phenol
1 -Benzyl -4 -phenyl is onipecotic acid
l-Benzyl-4-phenylisonipecotonitrile
Benzyltrimethyl ammonium hydroxide.
Benzyltrimethyl ammonium methoxide
[3,3'-Bianthra[l,9-cd]pyrazole]-6,6'-(2H,2'H)dione
(Pyrazoleanthrone yellow) .
[3, 3 '-Bi-7H-benz[de] anthracene] -7,7'-dione
* [4, 4 '-Bi-7H-benz[de] anthracene] -7,7'-dione
[1,1 '-Binaphthalene] -8,8'-dicarboxylic acid
Biphenyl
2-Biphenylamine
3,3' ,4,4'-Biphenyltetramine
2,2 ' -Biquinoline
* 1,4- Bis [l-anthraquinonylamino]anthraquinone
1,4-Bis [l-anthraquinonylamino]anthraquinone and 1,4-Bis-
[5-chloro-l-anthraquinonylamino]anthraquinone Cmixed) .
1 ,5-Bis [l-anthraquinonylamino]anthraquinone
2,6-Bis(p-azidobenzylidene) -4-methylcyclohexanone
1 ,4-Bis [ (S-benzamido- 1-anthraquinonyl) amino] anthraquinone-
2,3-Bis(bromomethyl)quinoxaline
Bis (chlorosulfonyl)phthalocyaninedisulfonic acid, copper
derivative.
4, 4 '-Bis [diethyl amino] benzhydrol, 2,6-naphthalenedi-
sulfonate.
4,4-Bis(diethylamino)benzhydrol salt, 2, 7-naphthalenedi-
sulfonic acid mixture.
4,4'-Bis [diethylaminojbenzophenone (Ethyl ketone base)
4-Bis [(p-diethylaminophenyl) methyl] -2,7-naphthalenedi-
sulfonic acid, leuco form.
4,4'-Bis [dimethylamino]benzhydrol (Michler's hydrol)
4,4'-Bis[dimethylamino]benzophenone (Michler's ketone)
3'-[Bis(2-hydroxyethyl)amino]acetanilide
3'-[Bis(2-hydroxyethyl)amino]benzanilide, diacetate ester-
FMT, SW.
SW.
SDC.
ACY, DUP, GAP.
HK, VEL.
DUP.
SDW.
ARS, MLS.
ABB.
MLS.
EK.
ABB.
SDW.
CCW.
UOP.
ACS.
ACS, DUP.
SDW.
ACY.
ACS.
LIL.
EK.
SDW.
SDW.
MLS.
MLS.
DUP, GAP, TRC-.
DUP.
ACY, DUP, ICI, MAY.
ACS.
DOW, GOC, MON, SNT.
NES.
AAP.
EK.
ACY, DUP, GAP, MAY, TRC.
TRC.
DUP.
WAY.
ICI.
GAP.
TRC.
DSC, SDH.
TRC.
SDH.
DSC, DUP.
GAP.
DUP.
CYCLIC INTERMEDIATES
31
TABLE 2.-
-Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
3'-[Bis(2-hydroxyethyl)ainino]methanesulfonanilide, di-
acetate ester.
4,4 '-Bis [(p-hydroxyphenyl)azo]-2,2 '-stilbenedisulfonic
acid CC.I- Direct Yellow 4).
4,4-Bis (p-methoxyphenyl) -3-hexanone
1 ,4-Bis [2- (4-methyl-S-phenyloxazolyl) ]Iienzene (Dimethyl
POPOP) .
Bis (o-nitrophenyl) sulfide
1,4-Bis [2-(5-phenyloxazolyl] Jbenzene (POPOP)
2-Bronioacetophenone
m-Bromoaniline
p-Bromoaniline
m-Bromoanisole
p-Bromoanisole
*3-Broino-7H-benz [de] anthracen-7-one (3-Bromobenzanthrone)
Bromobenzene, mono-
p-Bromobenzenesulfonyl chloride
o-Bromobenzoic acid
Bromochlorobenzene
6-Bromo-5-chlorobenzoxazolone
2-Bromodibenzofuran
4-Bromo-l,2-dichlorobenzene
2-Bromo-4,6-dinitro aniline
Bromoethylbenzene-
2-Bromo-3'-hydroKyacetophenone benzoate
l-Bromo-4-iodobenzene
*l-Bromo-4- (methyl amino) anthraquinone
6-Bromo-3-methyl-7H-dibenz [f , ij ] isoquinoline-2, 7- (3H) -
dione.
3-(Bromomethyl)thiophene
1-Bromonaphthalene
2-Bromo-4'-nitroacetophenone
l-Bromo-2-nitrobenzene
N-(4-Bromopentyl)phthalimide
p-Bromophenol
(p-Bromophenyl)acetonitrile
p-Bromophenylhydrazine hydrochloride
2-Bromopyridine
4-Bromoresorcylic acid
a-Bromotoluene
o-Bromotoluene
p-Bromotoluene
2-Bromo-l,3,5-triethylbenzene
p-Butoxyphenol
4-[3(p-Butoxyphenoxy)propyl]morpholine
p-Butylaniline
2-tert-Butylanthraquinone
p-tert-Butylbenzaldehyde
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
p-tert-Butylbenzoic acid
o-(p-tert-Butylbenzoyl) benzoic acid
4-Butyl-o-cresol
2-tert -Butyl -p-cresol
6-tert-Butyl-m-cresol
(n-Butylcyclopentadienyl)cyclopentadienyliron
2 ' -tert-Butyl-4 ' ,6 ' -dimethylacetophenone
4-Butyl-a- (dimethylamino) -o-cresol
Butyl-p- (p-ethoxyphenoxycarbonyl)phenyl carbonate
DUP.
TRC.
LIL
ARA.
ARA.
EK.
EK.
EK.
EK.
OPC.
ACY, ATL, DUP, GAP, MAY, TRC.
DOW.
EK.
EK.
DOW.
SW.
GAP.
EK.
AAP, SDC, TCD, TRC.
RSA.
SDH.
EK.
AAP,
AAP,
ACS, DUP, ICI.
GAP, ICI.
SDW.
EK.
GAP.
EK.
SDW.
EK.
BPC
EK.
RIL.
PCW.
EK.
EK, RSA.
BPC, EK.
DUP.
ABB.
ABB.
DUP.
DUP,
GIV.
PLC.
PLC.
EK, PLC.
SHC.
DUP.
PRD.
ACY.
KPT, PRD.
ARA.
GIV.
RH.
EK.
32
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
2-tert-Butyl-4-ethylphenol
5-tert-Butylisophthalic acid
n' -Butyl -4-methoxyraetanilamide
2-tert-Butyl-S-methylanisole
o-sec-Butylphenol
p-sec-Butylphenol
o-tert-Butylphenol
p-tert-Butylphenol
Butylphenols, mixed
tert-Butylstyrene
p-tert -Butyl toluene
S-tert-Butyl-m-xylene
6-tert-Butyl-2,4-xylenol
Camphoric acid
Camphor i c anhydri de
*Camphosulfonic acid
Carbazole, refined
l-(4-Carbonyl-o-anisyl)-3-methyl-3-(2-sulfoethyl)triazene
N,N'-Carbonylbis [4-methoxymetanilic acid]
N,N ' -Carbonylbis [4-methoxy-6-nitrometanilic acid]
N- [ (3-Carboxy-4-chlorophenyl) sulfonyl] anthranilic acid —
3-Carboxy-3(and 4) -hydroxybenzenediazonium sulfate
4- (2-Carboxyphenylazo} -3-methyl-l-phenyl-2-pyrazolin-5-
one.
[(o-Carboxyphenyl)thio]ethylniercury
Cedrene
2 '-Chloroacetoacetanilide
2 '-Chloroacetophenone
4'-Chloroacetophenone
4' -(Chloroacetyl)acetanilide
m-Chloroaniline
o-Chloroaniline
p-Chloro aniline
3-(o-Chloroanilino)propionitrile
5-Chloro-o-anisidine [NH2=1] (4-Chloro-o-anisidine
r0CH3=l]) .
* 1 - Ch 1 oroanthraquinone
*2-Chloroanthraquinone
N-(5-Chloro-l-anthraquinonyl) -p-toluenesulfonamide
o-Chlorobenz aldehyde
p-Chlorobenzaldehyde
Chloro-7H-benz [de]anthracen-7-one (Chlorobenzathrone)
*Chlorobenzene, mono-
p-Chlorobenzenesulfinic acid
p-Chlorobenzenesulfonamide
p-Chlorobenzenesulfonic acid
o-Chlorobenzoic acid
7-Chlorobenzo[b]thiophen-3(2H)-one
5-Chloro-2-benzoxazolinone
•o-(p-Chlorobenzoyl) benzoic acid
p-Chlorobenzoyl chloride
4,4'-(o-Chlorobenzylidene)di-2,5-xylidine
a-(p-Chlorobenzyl) -a-phenyl-1-pyrrolidinepropanol hydro-
chloride.
Chloro(p-chlorophenyl)phenylmethane
Chlorocyclohexane
4-Chloro-2-cyclopentylphenol
l-Chloro-2, 5 -diethoxy-4 -nitrobenzene
2-Chloro-N,N-diethyl-4-nitroaniline
2-Chloro-3' ,4'-dihydroxyacetophenone
UCC.
ACY.
X.
ALL.
GIV.
DOW, TNA.
DOW.
TNA.
DOW, PRO, SCN
DOW.
DOW.
GIV, SHC.
GIV.
PRO.
FIN, SEL.
SEL.
KF, LIL, OTC, SEL
SDC.
GAF.
GAF.
GAF.
TRC.
GAF.
ACS.
LIL.
GIV.
FMP, UCC.
EK.
LIL.
DUP.
DUP, GAF.
DUP, MON.
DUP, MON.
DUP.
ALL.
DUP, GAF, ICI, MAY, TRC.
ACY, GAF, TRC.
TRC.
ACY,
ACS,
ICI.
HN,
HN.
ACY,
ACS,
TRC.
ACY.
MTR,
HN.
ACS.
SW.
ACS,
HN.
GAF.
LIL.
OPC.
ACY, ARA.
DOW.
GAF.
DUP.
SDW.
DOW, DVC, HK, HKD, MON, MTO, OMC, PPG, SCC.
ACY, DUP, ICI.
CYCLIC INTERMEDIATES
33
TABLE 2.
■Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970--Continued
Manufacturers' identification codes
(according to list in table 3)
2 -Ch loro- 1 , 4-dihydroxy anthraquinone
4'-Chloro-2 ' ,5 ' -dimethoxyacetoacetanilide
4-Chloro-2,5-dimethoxyaniline
4-Chloro-N,N-dimethyl-3-nitrobenzenesulfonamide
[(4-Chloro-2,5-dimethylphenyl)thio]acetic acid
l-Chloro-2,4-dinitrobenzene (DinitrochlorobenzeneJ
3-Chloro-4,6-dinitrobenzenesulfonic acid
4-Chloro-3,5-dinitrobenzenesulfonic acid, potassium salt-
3-Chlorodiphenylainine
Chlorodiphenylmethane
n- (2-Chloroethyl} -4- (2-chloro-4-nitrophenylazo} -N-ethyl-
aniline.
4- [(2-chloroethyl)ethylamino]-o-toluidine
p-[(2-Chloroethyl)niethylamino]benzaldehyde
Chloroformic acid, benzyl ester
Chloroformic acid, phenyl ester
l-Chloro-4-hydroxy anthraquinone
4-Chloro-5-hydroxy-2,7-naphthalenedisulfonic acid
5 ' -Chloro-3-hydroxy-2-naphth-o-anisidide
3-Chloro-4-hydroxyquinoline- 3, 4- carbonic acid
4-Chlorometanilic acid
5-Chlorometanilic acid
6-Chlorometanilic acid
5-Chloro-2-methoxybenzenediazonium chloride
N-[(5-Chloro-2-methoxyphenyl)azo]sarcosine
p-(Chloromethyl5anisole
*l-Chloro-2 -methyl anthraquinone
6-Chloro-4-methylbenzo[b]thiophene-2-ol
4-Chloro-7-methylbenzo[b] thiophen-3C2H)-one
4-(Chloromethyl)-l,2-dimethylbenzene
4-(Chloromethyl) -1,3-dimethylbenzene
1-CChloromethyl) naphthalene
4-Chloro-N-methyl-3-nitrobenzenesulfonamide
2 -Chloro-5-[N-methylsulfamoyl) sulfanilamide
S-Chloro-2-(N-methylsulfamyl]-4-sulfamyl-N-benzylaniline-
4 -Chloro-3-(methylsulfonyl) nitrobenzene
Chloronaphthalenes
2-Chloro-4-nitroaniline (o-Chloro-p-nitroanilineJ
4-Chloro-2-nitroaniline (p-Chloro-o-nitroaniline)
1-Chloro-S -nit ro anthraquinone
4-Q\loro-3-nitrobenzaldehyde
l-Chloro-2-nitrobenzene (Chloro-o-nitrobenzene)
l-Chloro-3-nitrobenzene (Chloro-m-nitrobenzene)
*l-Chloro-4-nitrobenzene (Chloro-p-nitrobenzene)
2-Chloro-5-nitrobenzenesulfinic acid
2-Chloro-5-nitrobenzenesulfonamide
*4-Chloro-3-nitrobenzenesulfonamide
2-Chloro-5-nitrobenzenesulfonic acid
2-Chloro-5-nitrobenzenesulfonic acid, sodium salt
4-Chloro-3-nitrobenzenesulfonic acid
*4-Chloro-3-nitrobenzenesulfonyl chloride
2-Chloro-4-nitrobenzoic acid
2-Qiloro-5-nitrobenzoic acid
4-Chloro-3-nitrobenzoic acid
o-(4-Chloro-3-nitrobenzoyl}benzoic acid
4-Chloro-3-nitrocinnamic acid
4-Chloro-3-nitrophenyl methyl sulfone
2-Chloro-4-nitrotoluene
HSH.
PCW.
PCW.
EKT.
ACS.
SDC.
TRC.
SDC.
SK.
OPC.
GAF.
AAP.
GAF,
CTN,
CTN,
ICl.
GAF.
PCW.
SDH.
DUP.
ACS.
AAP.
GAF.
ATL.
SDW.
ACS,
ACY.
ACS
BPC.
BPC.
BPC.
TRC.
ABB.
ABB
TRC.
KPS.
DUP,
DUP,
ACY,
GAF.
AAP,
DUP,
AAP,
TRC.
AAP.
AAP,
ACS,
DUP,
ACS,
AAP,
SAL.
TRC.
PCW.
AAP,
GAF.
TRC.
DUP.
TRC.
EK, RSA.
EK, OTC.
ACY, CMC, DUP, TRC.
SDC.
SDC.
DUP, TRC.
DUP, MON, UPM.
UPM.
DUP, MON, UPM.
DUP, EKT, GAF, ICC, TRC.
TRC.
GAF.
GAF, TRC.
DUP, EKT, SAL, SDC.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.
-Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
Caccording to list in table 3)
2-Chloro-6-nitrotoluene
4-Chloro-2-nitrotoluene
4-Chloro-3-nitrotoluene
a-Chloro-m-nitrotoluene
o-Chlorophenol
p-Ch 1 oropheno 1
2-Chlorophenothiazine
(p-Chlorophenoxy)acetic acid
(p-Chlorophenyl)acetonitrile
4-Chloro-o-phenylenediamine
(o-Chlorophenyl) hydrazine
3- (o-Chlorophenyl) -5-methyl-4-isoxazolecarbonyl chloride-
3- Co-Chlorophenyl)-5-methyl-4-isoxazole carboxylic acid--
1- (p-Chlorophenyl)-3-methyl-2-pyrazolin-S-one
p-Chlorophenyl methyl sulfone
2-Chloro-4-phenylphenol
1- [4- (p-Chlorophenyl)-3-phenyl-2-butenyl] pyrrolidine
hydrobromide.
4-Chlorophthalic acid
(3-Chloropropenyl)benzene (Cinnamyl chloride)
1- (3-Chloropropyl) -4-methylpiperazine
N - [6-Chloro-3-pyridazinyl)sulfanilamide
7-Chloro-4-quinolinol
4-Chlororesorcinol
5-Chlorosalicylic acid
Chlorostyrene, mono-
2-Chloro-5-sulfamoylbenzoic acid
2-Chlorothiophene
m-Chlorotoluene
o-Chlorotoluene
p-Chlorotoluene
*a-Chlorotoluene (Benzyl chloride) — 7
3-Chloro-o-toluidine [NH2=1]
3-Chloro-p-toluidine [NH2=1]
4-Chloro-o-toluidine [NHj^l] and hydrochloride
5-Chloro-o-toluidine [NH2=1] (4-Chloro-o-toluidine
[CH3=1]).
5-Chloro-o-toluidine hydrochloride [NH2=1]
N-[ (5-Chloro-o-tolyl)azo]sarcosine
[ (4-Chloro-o-tolyl)thio] acetic acid
[ (5-Chloro-o-tolyl)thio] acetic acid
4-Chloro-a,a,a-trifluoro-3-nitrotoluene
p-Chloro-a,a,a-trifluorotoluene
6-Chloro-a,a,a-trif luoro-m-toluidine
Chlorotriphenylmethane
a-Chloro-o-xylene
a-Chloro-p- xylene
2-Chloro-p-xylene
4-Chloro-2,5-xylenesulfonyl chloride
4-Chloro-3,5-xylenol
Cholesteryl nonanoate
Cholesteryl oleyl carbonate (Mesomorphic)
Cholestyramine resin
Cholic acid
Cinnamoyl chloride
*Cresols:^
m-Cresol
*o-Cresol :
From coal tar
From petrol etun
p-Cresol
DUP.
DUP.
BUC.
EK.
DOW,
X.
DOW,
MON.
SK.
EK.
ARS,
OPC.
FMT.
GAF.
ARS,
OTC.
TRC.
TRC.
DOW.
LIL.
SW.
SDW.
SK.
ACY.
SDW.
AAP,
GAF.
PCW.
DOW.
TRC.
FIS.
HK.
HN.
HN.
BPC,
HN, MQN, VEL.
DUP.
DUP.
BUC,
PCW.
DUP.
ATL,
SDH.
ATL.
ACY,
GAF.
ACS.
PCW.
HK.
PCW.
EK.
BPC.
BPC.
DUP.
OTA.
EK.
EK.
MRK.
WIL.
ARS,
X.
KPT,
PRD.
KPT,
PRD.
KPT,
MER, NPC, PRD, SW
HPC,
SW.
See footnotes at end of table.
CYCLIC INTERMEDIATES
35
TABLE 2. — Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table)
Cresols, mixed:
*C'''jP5-Cresol :
From coal tar
From petroleum
Co,m,p)-Cresol :
From coal tar
From petroleum
Other
*Cresylic acid, refined:
*From coal tar
*From petroleum
*Cumene
p-Cumylphenol
4-[ (2-Cyanoethyl)ethylamino]-o-tolualdehyde
p- [ [2-Cyanoethyl)methylaraino]benzaldehyde
*Cyclohexane
1,2-Cyclohexanedicarboxylic anhydride
1,3-Cyclohexanedione
Cyclohexane oxide
*Cyclohexanol
*Cyclohexanone
Cyclohexanone oxime
Cyclohexene
4-Cyclohexene-l-carboxaldehyde
4-Cyclohexene-l,2-dicarboximide
4-Cyclohexene-l,2-dicarboxylic anhydride
Cyclohexylamine
Cyclohexyl-2-propanone
N-Cyclohexyltaurine, sodium salt
Cyclopentadienyliron
Cyclopentamine base
Cyclopentanepropionic acid ■
Cyclopentanol
Cyclopentene
[2-Cyclopenten-l-yl)-2-propanone
p-Cymene
Decabromobiphenyl
Deoxycholic acid
Diacenaphthol[l,2-j :l,2-l]fluoranthene (Decacyclene)-
1,5 (and l,8)-Diacetamidoanthraquinone
3,5-Diacetamido-2,4,6-triiodobenzoic acid
3^- [gi (2-acetoxyethyl)amino] -p-acetophenetidide
N ,N -Diallylmelamine
*l,4-Diaminoanthraquinone
1,5-Diaminoanthraquinone
1,5 (and l,8)-Uiaminoanthraquinone
*2,6-Diaininoanthraquinone
3,3'-Diaminobenzanilide
3>4-Diaininobenzanilide
2,4-Diaminobenzeriesulfonic acid [SSjHsl]
2,5-Diaminobenzenesulfonic acid [S03H=1]
4,4'-Dianiino-l,l'-bianthraquinone-3,3'-disulfonic
acid.
4,4'-Diamino-2,2'-biphenyldisulfonic acid
1,3-Diaminocyclohexane
3 , 7-Dianiino-4 ,6-dibenzothiophenedisulfonic acid ,
5,5-dioxide, disodium salt.
1 , 5-Diamino-2 , 6-dibromo-4 , 8-di-p-toluidinoanthra-
quinone .
l,4-Diajiiino-2,3-dichloroanthraquinone
*l,4-Diamino-2,3-dihydroanthraquinone
ACP, KPT, PRD.
MER, NPC, PIT, PRD.
ACP, KPT.
NPC.
SW.
ACP, KPT, PRD.
MER, NPC, PIT, PRD.
ASH, CLK, CSP, DOW, GOC,
HPC
MOC, MON, PLC
SHC
SKO, SNT, SOC, TX.
PCW.
DUP, GAF.
DUP, GAF.
ASH, ATR, CO, CSD; ENJ,
GOC,
GRS, PLC, PPR,
SWC,
TX, UOC.
ACS.
PD.
USR.
ACP, GEL, CNP, DUP, EKT,
MON
ACP, CEL, CNP, DBC, DUP,
MON
ACP, ACS, CNP.
PLC, USR.
UCC.
CHO.
PTT.
ABB, MON, VGC.
GIV.
GAF.
ARA.
LIL.
ARA.
LIL.
ARA, PLC.
LIL.
ACS, HN, X.
MCH.
WIL.
SDC.
AAP.
SDW.
TRC.
ACY.
ACS, CMC, DUP, TRC.
GAF, TRC.
AAP, TRC.
AAP, GAF, ICI, TRC, VPC.
TRC.
SW.
ACS, DUP, TRC.
TRC.
TRC.
ACS, ACY.
DUP.
ACY.
ICI.
AAP, DUP.
AAP, ACY, ATL, CMG, DUP,
GAF,
HSH, ICC, ICI
MAY
See footnotes at end of table.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.-
- Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to 11.st in table 3)
4,8-Diamino-9,10-dihydro-l,5-dihydroxy-9,10-dioxo-2,6-
anthracenedisulfonic acid.
l,4-Diamino-9,10-dihydro-9,10-dioxo-2,3-anthracenedi-
carboximide.
l,5-Diamino-4,8-dihydroxyanthraquinone
4,S-Diamino-l,8-dihydroxyanthraquinone
2,7-Diainino-3,6-dinitrofluoren-9-one
2,4-Diamino-6-phenyl-s-triazine
2,6-Diaminopyridine
*4,4'-Diamino-2,2'-stilbenedisulfonic acid
3,5-Diaiiiino-p-toluenesulfonic acid [S03H=1]
4,6-Diamino-m-toluenesulfonic acid [S03H=1]
3,5-Diamino-2,4,6-triiodobenzoic acid
l,4:3,6-Dianhydroglucitol
l,5-Dianilino-9,10-dihydro-9, 10-aioxo-2,6-anthracenedi-
carboxylic acid.
2,5-Dianilinoterephthalic acid
Diarylguanidine
p-Diazo-N,N-diraethylaniline-l-amino-8-naphthol-3-sul-
fonate-6-sulfonic acid, sodium salt.
5(and 3)-Diazo-6-oxo-l,3(and l,4)-cyclohexadiene-l-car-
boxylic acid.
l.S-Dibenzamidoanthraquinone
6,ll-Dibenzainido-16H-dinaphtho[2,3-a,2' ,3'-i]carbazole-
5,10,15,17-tetrone.
*4,5'-Dibenzamido-l,l'-iminodianthraquinone
4"',5-Dibenzamido-4-methoxy-l,l '-iminodianthraquinone —
2-Dibenzofuranol
1,5-Dibenzoylnaphthalene
3'- (N,N-Dibenzyl)amino-p-acetanisidide
N,N' -Dibenzylethylenedi amine
N,N'-Dibenzylethylenediamine diacetate
3,4-Dibenzyloxybutyrophenone
N,N-Dibenzylsulfanilic acid
2,4 ' -Dibromoacetophenone
3,9-Dibromo-7H-benz[de]anthracen-7-one
ar-Dibromobenzene
m-Dibromobenzene
4,4'-Dibromobenzil
2,6-Dibrorao-4-nitroaniline
2,6-Dibromo-4-nitrophenol
a,a-Dibromo-p-nitrotoluene
5,13-Dibromo-8,16-pyranthrenedione
3,5-Dibromo-3'-trifluoromethylsalicylanilide
2,5-Dibutoxy-4-morpholinobenzenediazonium sulfate
2,6-Di-tert-butyl-p-benzoquinone
l,l'-Di-n-butyldicyclopentadienyliron
2,6-Di-tert-butyl-4-nonylphen0l
2,4-Di-tert-butylphenol
Dibutyltin bis(cyclohexylmaleate)
3' ,4'-Dichloroacetophenone
3,4-Dichloroaniline
2,5-Dichloroaniline and hydrochloride [NH2=1]
3- (2,4-Dichloroanilino)-l- (2,4,6-trichlorophenyl)-2-
pyrazolin-5-one .
*l,S-Dichloroanthraquinone
1 , 5 (and 1,8) -Dichloroanthraquinone
1,8-Dichloroanthraquinone
Dichlorobenzanthrone
m-Dichlorobenzene
*o-Dichlorobenzene
*p-Dichlorobenzene
o(and p)-Dichlorobenzene
2,S-Dichlorobenzenesulfonyl chloride
*3,3'-Dichlorobenzidine base and salts
2,2'-Dichlorobenzil
VEL.
RIL.
ACY, CGY, GAF, SDH, TRC, VPC .
VPC.
ICl.
BJL.
RH,
NEP,
ACS,
GAF.
ACS.
SDW.
APD.
ACS.
SDC.
DUP.
IDC.
GAF, TRC.
ICI.
ACY,
SDH.
GAF.
ACY,
SDC.
WYT.
WYT.
SDW.
ICl,
EK,
DUP,
DOW.
EK.
NES.
SDC.
SW.
DUP.
DUP,
PCW.
ALL.
NES.
ARA.
GAF.
DOW.
X.
EK.
DUP,
BUC,
EK.
ACS,
DUP.
GAF,
ACY.
EK,
ACS,
ACS,
DVC.
ACS.
ACS,
MTO.
GAF, ICI, MAY, TRC.
DUP, GAF, TRC, VPC.
NES.
MAY, TRC.
MON.
DUP.
DUP, GAF, ICI, TRC.
ICI.
DOW, DUP, HKD, MON, NEV, PPG, SCC, SVT.
DOW, DVC, MON, NEV, PPG, SCC, SVT.
CWN, LAK.
CYCLIC INTERMEDIATES
37
TABLE 2.
-Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970--Continued
Manufacturers' identification codes
(according to list in table 3)
2,4-Dichlorobenzoic acid
4,4'-Dichlorobenzophenone
4,7-Dichlorobenzo[b]thiophen-3(2H)one
2,4-Dichlorobenzoyl chloride
2,5-Dichlorobenzoyl chloride
Dichlorobenzyl chloride
4,4- (2,6-Dichlorobenzylidene)-di-2,6-xylidine
7,16-Dichloro-6,15-dihydro-S,9,14,18-anthrazinetetrone —
4,5-Dichloro-3,6-dioxo-l,4-cyclohexadiene-l,2-dicarbo-
nitrile.
Dichlorodiphenylsilane
2' ,7'-Dichlorof luorescein
2- (5, 8-Dich lore- 1 -hydroxy- 2-naph thy lazo)-l -phenol -4-
sulfonamide.
5,14-Dichloroisoviolanthrone
*2,5-Dichloro-4- (3-niethyl-5-oxo-2-pyrazolin-l-yl)benzene-
sulfonic acid.
Dichloromethylphenylsilane
2,6-Dichloro-4-nitroaniline
l,2-Dichloro-4-nitrobenzene
l,4-Dichloro-2-nitrobenzene (Nitro-p-dichlorobenzene)
2,S-Dichloro-3-nitrobenzoic acid
2,5-Dichloro-3-nitrobenzoic acid, ammonium salt
2,4-Dichlorophenol
3- (2 ',6' -0ichlorophenyl)-5-methyl-4-isoxazolecarbonyl
chloride.
[ (2,5-Dichlorophenyl)thio]acetic acid t--
2,6-Dichloropyrazine
3,6-Dichloropyridazine
4,7-Dichloroquinoline
*2,5-Dichlorosulfanilic acid [SQ3H=1]
2,5-Dichloro-4-sulfobenzenediazonium sulfate
2,6-Dichlorotoluene
m,a-Dichlorotoluene
p,a-Dichlorotoluene
Dichloroxylene
Dicyclohexyl amine
Dicyclohexylcarbodiimide
1,3-Dicyclohexy 1-2- thiourea
*Dicyclopentadiene (includes cyclopentadiene)
Dicyclopentadiene dioxide
Didodecylbenzene ■
p-Diethoxybenzene
2,5-Diethoxy-4-morpholinobenzenediazonium chloride, zinc
chloride.
*p- (Diethylamino)benzaldehyde
3'- [2- (Diethylamino)ethyl]-4'-hydroxyacetanilide
a- I (2-Diethylamino) ethyl] -a-phenylcyclohexanemethanol ,
hydrochloride.
7-Diethylamino-4-methylcoumarin
m-(Diethylamino) phenol (N,N-Diethyl-3-aminophenol)
3-[(4-N,N-Diethylamino)phenylazo]-lH-l,2,4-triazole
3- (DiBthylamino)propiophenone
4- (Diethylamino)-o-tolualdehyde
*N,N-Diethylaniline
N,N-Diethyl-m-anisidine
Diethylbenzene
l,l'-Diethyl-4,4'-carbocyanine iodide (Cryptocyanine)
N,N-Diethylcyclohexylainine
a,a'-Diethyl-4,4'-dimethoxystilbene
N,N-Diethvlmetanilic acid
N',N'-Diethyl-4-methoxymetanilamide
HN.
NES.
ACS.
HN.
GAP.
BPC.
DUP.
ICI.
ARA.
DCC.
ICI.
ACY, CMC, TRC, VPC.
DCC.
CWN, EKT, HSH, SW, TRC.
DUP, MON, SDC.
DUP, SDC, VPC.
GAP.
GAP.
DOW, MON.
APD, OTC.
ACS,
ACY,
ACY,
PD,
ACS,
TRC,
GAP.
BPC.
HN.
BPC.
SDW.
CMG, DUP, VPC.
GOC, MON, UCC, VEL.
CWN.
ABB.
EN J,
VEL.
CO.
GAP.
ALL.
ACS, DUP, GAP, TRC.
PD.
ACY.
GAP.
ACY,
TRC.
ACY.
DUP.
ACS,
DUP.
DOW,
EK.
DUP.
LIL.
DUP.
PCW.
ACY, DSC, DUP, SDH.
KPP.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
N,N-Diethyl-p-nitrosoaniline
N,N-Diethyl-4-nitroso-m-anisidine hydrochloride
N,N-Diethyl-4-nitroso-m-phenetidine
N.N-Diethyl-m-phenetidine
N.N-Diethyl-m-toluidine
N,N-Diethyl-p-toluidine
6,15-Dihydro-5,9,14,18-anthrazinetetrone
10,ll-Dihydro-5H-dibenzo[a,d]cyclohepten-5-one
*9,10-Dihydro-l,4-dihydroxy-9,10-dioxo-2-anthracenesul-
fonic acid-
9, 10-Dihydro-9,10-dioxo-l,5-anthracenedisulfonic acid —
*9,10-Dihydro-9,10-dioxo-l,5-anthracenedisulfonic acid,
disodium salt.
9,10-Dihydro-9,10-dioxo-l,5(and 1 ,8;)-anthracene-
disulfonic acid and salt.
*9, 10-Dihydro-9,10-dioxo-l,8-anthracenedisulfonic acid,
potassium salt.
*9, lO-Dihydro-9, 10-dioxo-2,6-anthracenedisulfonic acid
and salt.
*9, 10-Dihydro-9,10-dioxo-l-anthracenesulfonic acid and
salt (.Gold salt) .
9,10-Dihydro-9, lO-dioxo-2-anthracenesulfonic acid and
salt (Silver salt).
3,4-Dihydro-3,4-dioxo-l-naphthalenesulfonic acid,
sodium salt.
[Dihydrogen 3,3' ' -phthalocyaninedisulfonate (2-) ] copper--
10, ll-Dihydro-5-[3- (njethylaminopropyl)] -5H-dibenzo[a,d] -
cyclohepten-5-ol .
9,10-Dihydro-5-nitro-9, 10-dioxo-l-anthracenesulfonic
acid.
9,10-Dihydro-5(and 8) -nitro-9, 10-dioxo-l-anthracene-
sulfonic acid.
9, 10-Dihydro-l-nitro-9,10-dioxo-2-anthroic acid
l,4-Dihydro-4-oxo-2,6-pyTidinedicarboxylic acid
*l,4-Dihydroxyanthraquinone (Quinizarin)
* 1 , 5 -Dihydroxyanthraquinone (Anthraruf in)
1 , 5 (and 1,8) -D ihydroxyanthraquinone
1,8-Dihydroxyanthraquinone (Chrysazin)
2,6-Dihydroxyanthraquinone (Anthraf lavic acid)
2,4-Dihydroxybenzaldehyde
2,5-Dihydroxybenzenesulfonic acid, potassium salt
2,4-Dihydroxybenzophenone
l,S-Dihydroxy-4,8-dinitroanthraquinone
* 1 , 8-Dihydroxy-4 , 5-dinitroanthraquinone (4 , 5-Dinitro-
chrysazin) .
3,4-Dihydroxyhydrocinnamic acid, ethyl ester
4,5-Dihydroxy-2,7-naphthalenedisulfonic acid (Chromo-
tropic acid) .
6,7-Dihydroxy-2-naphthalenesulfonic acid
116,21-Dihydroxypregna-4,17(20)-cis-dien-3-one
4,5-Dihydroxy-3- (p-sulfophenylazo) -2,7-naphthalene-
disulfonic acid, trisodium salt.
*16,17-Dihydroxyviolanthrone (Dihydroxydibenzanthrone) --
m-Diiodobenzene
3,5-Diiodosalicylic acid
Diisopropylbenzene
N,N'-Diisopropyl-p-phenylenedi amine
2,5-Dimethoxyaniline
1 , 5 (and 1,8) -Dimethoxyanthraquinone
2,5-Dlmethoxybenzaldehyde
m-D imethoxyb enzene
p-Dimethoxybenzene
EK.
DUP.
GAF.
GAF.
DUP,
RSA.
RSA.
TRC.
LIL.
AAP,
ACS,
HSH,
PAT.
TRC.
DUP,
GAF,
ICI,
TRC.
DUP,
TRC.
GAF,
ICI,
TRC.
AAP,
GAF,
ICI,
TRC,
VPC.
AAP,
ACS,
ACY,
DUP,
GAF,
ICI,
MAY,
TRC
DUP,
TRC.
ICI.
LIL.
TRC.
ICI.
DUP,
SDW.
AAP,
ACS,
CMG,
GAF,
GAF,
EK.
NES.
DUP.
TRC,
DUP,
BJL.
ACS.
IDC.
UPJ.
EK.
GAF.
ACY, DUP, GAF, HSH, ICC, MAY, TRC.
GAF, TRC.
TRC.
TRC.
TRC.
VPC.
GAF, ICI.
ACY, DUP, GAF, ICI, MAY.
EK.
DOW.
DUP,
EKT,
TRC.
CWN.
ACY,
ASL.
USR.
PCW.
CYCLIC INTERMEDIATES
39
TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers ' identification codes
[according to list in table 3)
3,3'-Diniethoxybenzidine (o-Dianisidine)
3,3 ' -Dimethoxybenzidine hydrochloride
N,N '- [ (3, 3 ' -Dimethoxy-4,4 ' -biphenylylene)bis (azo) ]bis-
(N-methyltaurineJ .
2,5-r)imethoxy-g-methyl-B-nitrostvrene
2,S-Dimethoxy-a-methylphenethylamine hydrobromide
N- (3 , 4-Dimethoxy-a-niethy Iphenethy 1 ) - 2- (4- ethoxy- 3-
methoxyphenyl^acet amide.
l,4-Diniethoxy-2-nitrobenzene
2,5-Dimethoxy-4'-nitrostilbene
3,4-Dimethoxyphenethylamine (Homoveratrylamine)
4- (2' ,S'-Dimethoxyphenethyl)aniline hydrochloride
N- (3,4-Dimethoxyphenethyl)-2- C3,4-dimethoxyphenyl)-
acetamide.
(3, 4-Dimethoxyphenyl) acetic acid
C3,4-Dimethoxyphenyl)acetonitrile
1- (3,4'-Dimethoxyphenyl3-2-aiiiinDpropane
1- (3,4'-Dimethoxyphenyl)-2-nitropropene
2,5-Dimethoxytetrahydrofuran
16,17-Dimethoxyviolanthrone
1,5-Dimethylaminoanthraquinone
p- (Dimethylaminojbenzaldehyde
m-(Dimethylamino) benzoic acid
a-(Dimethylamino)-p-cresol
6-Diinethylamino-2-[2,5-dimethyl-l-phenyl-3-pyrryl)-
vinyl]-l-methyl-l-quinolinium methyl sulfate.
2- [ [2- (Dimethylamino) ethyl] -2-thenylamino] pyridine
(nonmedicinal grade) .
2-[ [2- (Dimethylamino) ethyl] -3-thenylamino] pyridine
5-Dimethylaminonaphthalenesulfonyl chloride
m- (Dimethylamino) phenol
*N,N-Dimethylaniline
7, 12-Dimethylbenz [a] anthracene
3,3'-Dimethylbenzidine (o-Tolidine)
3,3'-Dimethylbenzidine hydrochloride
*N,N-Dimethylbenzylamine
a,a-Dimethylbenzyl hydroperoxide
4-Ca,a-Dimethylbenzyl-2-phenylazophenol
*2 , 2 ' -Dimethyl- 1 , 1 ' -bianthraquinone
5,5-Dimethyl-l,3-cyclohexanedione
N,N-Dimethylcyclohexylamine
5,5-Dimethylhydantoin
2, 3-Dimethyl indole
2,5-Dimethyl-4(2)-morpholinylmethylphenol, hydro-
chloride.
N,N-Dimethyl-l-naphthylamine
N,N-Dimethyl-p-nitrosoaniline
6,6-Dimethyl-2-norpinene-2-ethanol
N,N-Dimethyl-p-phenylenediamine
N,N-Dimethyl-p-phenylenediamine hydrochloride
N,N-Dimethyl-p-phenylenediamine sulfate
1,4-Dimethylpiperazine
N,N-Dimethyl sulfanilamide
N,N-Dimethylsulfanilic acid
Dimethyl- 5- sulfoisophthalate
N,N-Dimethyl-p-toluidine
2,4-Dinitroacetanilide
*2,4-Dinitroaniline
p- (2, 4-Dinitroanilino) phenol
1,5 (and l,8)-Dinitroanthraquinone
N,N ' - (2 ,4-Dinitro- 1 , 5-anthraquinonylene) dioxamic acid-
3,3'-Dinitrobenzanilide
ALL, CWN, SDH.
ALL, CWN.
GAF.
LIL.
UPJ.
LIL.
LIL.
LIL.
LIL.
LIL.
HEX.
ICI, MAY.
AAP.
TRC.
NES, SDH.
TKL.
SOW.
EK.
ACY.
ACS,
ACY,
DSC
DUP.
EK.
ALL,
CWN.
CWN,
DUP,
EK.
ARS,
MLS,
RH,
SW.
CLK.
TRC.
ACS,
ACY,
DUP
GAF, ICI, TRC
AAP.
ABB,
DUP,
EKT
GLY.
DUP.
IDC.
EK.
ACY.
RDA.
EKT.
EK.
EK.
JCC.
PCW.
AAP,
GAF.
X.
EK,
RSA.
SDC.
AAP,
ACY,
SDC.
GAF,
SDC.
AAP,
TRC.
TRC.
TRC.
SYNTHETIC ORGANIC CHEMICALS, 1970
-Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
3' ,4-Dinitrobenzanilide
m-Dinitrobenzene
2,4-Dinitrobenzenesulfonic acid
2,4-Dinitrobenzenesulfonic acid, sodium salt
3,5-Dinitrobenzoic acid
3,5-Dinitrobenzoyl chloride
3,3'-Dinitro-4,4'-biacetanilide
10,10'-Dinitro[3,3'-bi-7H[de]anthracene]-7,7'-dione
Dinitrocaprylphenol
2,4-Dinitrocumene
3, 5 -Dinitro-N,N-dipropyl sulfanilamide
1- (3,5-Dinitro-2-hydroxyphenylazo)-2-naphthol
2,4-Dinitrophenol, tech
(2,4-Dinitrophenyl)hydrazine
3,5-Dinitrosalicylic acid
*4,4'-Dinitrostilbene-2,2'-disulfonic acid
2,4-Dinitrotoluene
* 2, 4 (and 2 ,6)-Dinitrotoluene
Dinonylphenol
2,4-Di-tert-pentylphenol
Di-tert-pentylphenoxyacetyl chloride
2- (2,4-Di-tert-pentylphenoxy)butyric acid
1 , 5 -D iphenoxy anthr aquinone
Diphenylacet aldehyde
Diphenylacetic acid
Diphenylacetonitrile, tech
*Diphenyl amine
2,8-Diphenylanthra[l,2-d:6,5-d']bisthiazole-6,12-dione-
2,5-Diphenyl-p-benzoquinone
Diphenylcarbamyl chloride
1,1-Diphenylethylene
N,N'-Diphenylethylenediamine
2,S-Diphenyloxazole
l,3-Diphenyl-l,3-propanedione
4,4 '-Dithiodiani line
2,2'-Dithiodibenzoic acid
*1 ,4-Di-p-toluidinoanthraquinone
l,S-Di-p-toluidinoanthraquinone
1,8-Di-p-toluidinoanthraquinone
2,5-Di-p-toluidinoterephthalic acid
*Divinylbenzene
p-Dodecylaniline
Dodecylbenzene. (See Alkylbenzenes . )
Dodecylbenzyl chloride
Dodecylmethylbenzyl chloride
*p-Dodecylphenol
Eos in (2 ' ,4' ,5' ,7 ' -Tetrabromof luorescein)
l,2-Epoxy-3- (2-biphenylyl) propane
o-Ethoxybenzoic acid
4-Ethoxy-3-methoxybenzaldehyde
4-Ethoxy-3-methoxybenzyl alcohol
1- (4-Ethoxy-3-methoxybenzyl)-6,7-dimethoxy-3-methyliso-
quinone .
(4-Ethoxy-3-methoxyphenyl) acetic acid
2-Ethoxy-l-naphthoyl chloride
4-Ethoxy-o-phenylenediamine
N'- (6- Ethoxy-3-pyridazinyl) sulfanilamide
3- (Ethy 1 amino) -p-cresol
*N- Ethyl aniline, refined
2-(N-Ethanilino)ethanol
[2- (N-Ethylanilino) ethyl] trimethylammonium chloride
a-(N-Ethylanilino)-m-toluenesulfonic acid
AAP.
DUP.
EK,
TRC.
EK.
SAL.
EK.
AAP.
DUP,
MAY.
RH.
DUP.
SDC.
TRC.
AAP,
SDC.
EK.
EK,
SAL.
ACY,
CGY,
DUP,
GAP,
SDH, TCD, TRC
ACS,
DUP,
RUC.
DUP,
MOB,
UCC.
GAP,
JCC.
PAS,
PRD.
EK.
EK.
VPC.
ARA.
ARA.
PIS.
ACY,
DUP,
FST,
ORO,
RUC, USR.
GAP,
ICI.
EK.
EK.
EK.
RPC
ARA
EK.
EK,
RSA.
SDC.
LIL
SW.
ACS
ATL,
GAP,
ICI,
TRC.
ICI
ICI
SDC
DOW
FG,
KPP.
MON
CO.
RH.
GAP
MON,
X,
ICC
NES
ACY
LIL
LIL
LIL
LIL
WYT
TRC
ACY
DUP
ACS
ACY
DUP,
SDH.
DUP
EKT
DUP
GAP
SDH
WJ.
CYCLIC INTERMEDIATES
41
TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
a- [N-Ethylanilino) -p-toluenesulfonic acid-
2 -Ethy lanthraquinone
*Ethylbenzene
Ethylbenzyl chloride
N-Ethyl-l-cyclohexen-l-ylamine
N- Ethy Icyclohexyl amine
3,3'-Ethylenedioxydiphenol
Ethylene glycol dibenzenesulfonate
2-[N-Ethyl-p-[ [6-methoxy-2-benzothiazolyl)azo] aniline] -
ethanol .
N-Ethyl-N-(2-methylsulfonamidoethyl]-m-toluidine
N-Ethyl-1-naphthylamine
*N-Ethyl-N-phcnylbenzylainine
9-Ethyl-3-nitrocarbazole
a-Ethyl-3-nitrocinnainic acid
N-[2-CN-Ethyl-4-nitroso-ni-toluidino(ethyl]methane-
sulfonamide.
p-Ethylphenol
Ethylphenylmalonic acid, diethyl ester
5-Ethyl-2-picoline (2-Methyl-5-ethylpyridine) (MEP)
1-Ethylpiperidine
2-Ethylpyridine
6-Ethyl- 1,2,3, 4-tetrahydro-l, 1,4, 4-tetramethyl-
naphthalene.
N-Ethyl-m-toluidine
N-Ethyl-o-toluidine
3-(N-Ethyl-ni-toluidino3propionitrile
a-(N-Ethyl-m-toluidino)-m-toluenesulfonic acid
1-Ethynyl-l-cyclohexanol
Fluoren-9-one
Fluorescein (3' ,6'-Dihydroxyfluoran)
l-Fluoro-2,4-dinitrobenzene
d- 2 - Form amido-l -phenyl -1,3 -propanediol
4-Formyl-m-benzenedisulfonic acid
o-Formylbenzenesulfonic acid (o-Sulfobenzaldehyde]
Furan-
Furfuryl alcohol
Furfurylamine
N-Glycolylarsanilic acid, sodium salt
Hexabromobenzene
Hexabromobiphenyl
Hexachlorocyclopentadiene
1,4,5,6,7, 7-Hexachloro-5-norbornene-2 , 3-dicarboxylic
acid,
1,4, 5 ,6 , 7, 7-Hexachloro-5-norbornene-2 , 3-dicarboxylic
anhydride .
Hexadecachlorophthalocyanine, copper complex
Hexafluorobenzene
l,2,3,4,5,6-Hexahydro-8-hydr JXy-cis-6,ll-dimethyl-2,6-
methano-2-benzazocine .
Hexahydro-1-methy 1-4 -phenyl -lH-azepine-4-carbonitrile--
Hexamethylenimine
*Hippuric acid
p-Hydrazinobenzenesulfonic acid
Hydrazobenzene
Hydroquinone, di(B-hydroxyethyl) ether
*Hydroquinone, tech
g-Hydroxy-p-acetophenetidide
3'-Hydroxyacetophenone
3'-Hydroxyacetophenone benzoate
p-Hydroxybenzaldehyde
*p-Hydroxybenzenesulfonic acid
ACS, TRC.
ACS, DUP.
ATR, CSD, CSP, DOW, ENJ, FG, KPP, MCB, MON, SHC.
SKC, SNT, SOG, STY, TOG, UCC.
BPC.
x.
ABB, PAS.
IDC.
NES.
TRG.
WAY.
DUP.
ACS, DUP, SDH.
SDC.
SDW.
WAY.
ACY.
BPC, MAL.
UCC.
RIL.
RIL.
GIV.
DUP.
DUP.
DUP, ICC.
GAF.
cue, EKT.
EK.
ICC.
EK.
PD.
GAF.
SDH.
QKO.
QKO.
MLS.
SDW.
MCH.
MCH.
HK, VEL.
HK.
VEL.
TRC.
WHC.
SDW.
WYT.
GEL,
DUP
BPC,
HEX,
NES.
GAF,
WJ.
HEX.
CTN.
CRS,
DA,
DUP, EKT.
GAF,
TRC,
CTN,
SDH.
SDH.
DOW.
DOW,
MON,
PRD, UPF.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
p-Hydroxybenzoic acid
Hydroxybenzoic acid, mixed
3 ' -Hydroxy- 2- (N-benzyl -N-methyl amino) acetophenone
4-Hydroxycouinarin
3-[N- (2-Hydroxyethyl)anilino]propionitrile
3- TN- (2-Hydroxyethyl)anilino]propionitrile, acetate
3_[jN- (2-Hydroxyethyl)anilino]propionitrile, benzoate
N-3-Hydroxyethyl-2,4-dihydroxybenzamide
N-3-Hydroxyethyl-3,5-dihydroxybenzainide
N- [7-Hydroxy-8- [2-hydroxy-5- (methylsulfamoylphenyl) azo] -
1-naphthyl] acet amide.
6 ' -Hydroxy-S ' - [ [2-hydroxy-5-nitrophenyl) azo] -m-aceto-
toluidide.
N-[7-Hydroxy-8-[ (2-hydroxy-5-nitrophenyl)azo] -1-
naphthyl ] acetamide .
7-Hydroxy-8- [ [4 ' - [ (p-hydroxyphenyl )azo] -4-biphenylyl] -
azo] - 1 , 3-naphthalenedisulf onic acid .
*4-Hydroxymetanilamide
4-Hydroxymetanilic acid
N- (4-Hydroxymetanilyl)anthranilic acid
3' -Hydroxy-2- (methylamino) acetophenone
4-Hydroxy-l-methylcarbostyrj.l
*3-Hydroxy-2-methylcinchoninic acid
4-Hydroxy-N -me thy Imet anil amide
4-Hydroxy-5-methyl-m-phenetidine hydrochloride
N-(Hydroxymethyl)phthalimide
3-Hydroxy-N- (3-N-morpholinopropyl)-2-naphthamide
*3-Hydroxy-2,7-naphthalenedisulfonic acid, dipotassium
salt.
*3-Hydroxy-2,7-naphthalenedisulfonic acid, disodium salt-
* 7- Hydroxy- 1, 3-naphthalenedisulf onic acid
7-Hydroxy-l,3-naphthalenedisulfonic acid, disodium salt-
4 -Hydroxy- 2-naph thai enesulfonamide
4 -Hydroxy- 1-naphthalenesulf onic acid
*6-Hydroxy-2-naphthalenesulfonic acid
*6-Hydroxy-2-naphthalenesulfonic acid, sodium salt
8-Hydroxy- 1-naphthalenesulf onic acid
4-Hydroxy-2-naphthalenesulfonic acid, benzenesulfonate
sodium salt.
l-Hydroxy-2-naphthalenesulfonic acid, potassium salt
3-Hydroxy-2-naphthanilide (Naphthol AS)
1 -Hydroxy- 2-naph thoic acid
3-Hydroxy-2-naphthoic acid (B.O.N.)
3-Hydroxy-2-naphthoic acid, methyl ester
l-Hydroxy-2-naphthoic acid, phenyl ester
3-Hydroxy-2-naphtho-o-toluidide
N- (2-Hydroxy-l-naphthyl) acet amide
*N- (7-Hydroxy-l-naphthyl) acet amide
1- (2-Hydroxy-l-naphthylazo) -6-nitro-2-naphthol-4-
sulfonic acid.
4-Hydroxy-7- (p-nitrobenzamido)-2-naphthalenesulfonic
acid.
2-Hydroxy-S-nitrometanilic acid
1- (2-Hydroxy-4-nitrophenyl azo) -2 -naphthol
2,2'- (2-Hydroxy-4-nitrophenylimino)diethanol
2-Hydroxy-4-n-octoxybenzophenone
2 - (m-Hydroxyphenoxy ) ethanol
0- [ (p-Hydroxyphenyl)azo]benzoic acid
3- [4- (4'-Hydroxvphenylazo)-2,5-dimethoxyphenylazo] -
benzenesulfamic acid.
3-Hyaroxy-4- (phenylazo)-2-naphthoic acid
lla-Hydroxyprogesterone
4-Hydroxypropiophenone .-,--.
2-Hydroxy-4-sulfo-l-naphthalenediazoniu7n hydroxide,
inner salt.
l-Hydroxy-4-p-toluidinoanthraquinone
SDW.
ABB.
DUP,
EKT.
DUP.
IDC.
PCW.
TRC.
TRC.
ACS,
GMG,
DUP,
TRC,
VPC
ACS,
CWN,
TRC.
TRC.
CTN.
ICC.
AAP,
DUP,
GAP,
ICC,
TRC
TRC.
UPJ.
ACY.
IDC.
TCD.
ACS,
ACY,
GAP,
TRC,
WJ.
DUP,
TCD,
TRC.
ACS,
ACY.
GAP.
ACS,
DUP.
ACS,
SNA,
TMS.
ACY,
TRC,
WJ.
VPC.
GAP.
EK.
ATL.
ACS.
BUC,
PCW.
PCW.
EK.
ATL,
PCW.
ACY.
CMC,
GAP,
TRC.
TRC.
GAP.
TRC.
TRC.
WAY.
CCW.
BJL.
EK.
TRC.
ICC.
UPJ.
MLS.
ACY.
CYCLIC INTERMEDIATES
43
TABLE 2.
-Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970-- Continued
2-Iniidazolidinone
2-Imidazolidinone modifications
*l,l''-Iminobis[4-aminoanthraquinone]
l,l'-Iininobis[4-ben2amidoanthraquinone]
*1 , 1 ' -Iminobis [5-benzamidoanthraquinone]
*7,7'-Iminobis[4-hydroxy-2-naphthalenesulfonic acid]
*!,!' -Iminobis [4-nitroanthraquinone]
*!,!'- Iminodianthraquinone (1,1' -Dianthrimide)
1-Indanone
Indole- 2, 3-dione
Indophenol, sodium salt
5-Iodoanthranilic acid
o-Iodobenzoic acid
Isobutylbenzene
*Isocyanic acid derivatives:
Bitolylene diisocyanate (TODI)
p-Chlorophenyl isocyanate
Cyclohexyl isocyanate
Dianisidine diisocyanate (DADI)
Dicyclohexylmethane-4,4-diisocyanate
Diphenylmethane-4,4' -diisocyanate (MDI)
p-Methoxypheny 1 isocyanate
Phenyl isocyanate
Polyisocyanates (complex)
*Polymethylene polyphenyl isocyanate
Toluene 2,4-diisocyanate
Toluene 2,4- and 2,6-diisocyanate (65/35 mixture) —
♦Toluene 2,4- and 2,6-diisocyanate (80/20 mixture) —
Other
Isonicotinic acid, methyl ester
Isonicotinonitrile
Isooctylphenol
Isophthalic acid (Benzene-l,3-dicarboxylic acid)
Isophthalic acid, diallyl ester
Isophthalic acid, dimethyl ester=
Isophthalic acid, diphenyl ester
Isophthaloyl chloride
4,4'-Isopropylidenebis[2,6-dibromophenol] (Tetrabromo-
bisphenol A) .
4,4'-Isopropylidenebis[2,6-dibroraophenol]diacetate
5,5' -Isopropylidenebis (2-hydroxy-m-xylene-a,a'-diol)--
*4,4'-Isopropylidenediphenol (Bisphenol A)
4,4'-Isopropylidenediphenol, ethoxylated
4,4'- I sopropy 1 idenedipheno 1, propoxylated
o-Isopropylphenol
p-Isopropylphenol
Isopropylphenols, mixed
4-Isopropyl-m-phenylenediaiiiine
Isoviolanthrone (Isodibenzanthrone)
*Leuco quinizarin (1,4,9,10-Anthratetrol)
2,4-Lutidine
2,6-Lutidine
3,4-Lutidine
Malonanilide
Mandelonitrile
*Melamine ■
*dl-p-Mentha-l,8-diene (Limonene)
p-Mentha-l,4(8)-diene
p-Menth-1-ene
o-Mercaptobenzoic acid (Thiosalicylic acid)
*Metanilic acid (m-Aminobenzenesulfonic acid)
5- (2 ' -Methoxybenzenesulfonamido) -2-benzoxazolinone
4-Methoxyiiietanilic acid
6-Methoxymetanilic acid
Manufacturers ' identification codes
(according to list in table 3)
VAL.
RH.
ACY,
ACY.
GAF,
ACS,
ACY,
ACY,
EK.
ACS.
EK.
SOW.
RSA.
PLC,
UPJ.
MOB.
OTC.
CIVN,
DUP.
ACS,
OTC.
MOB.
MOB.
KAI,
DUP,
DUP,
ACS,
DUP,
RIL.
RIL.
PRD.
ACC.
FMP.
MTR.
BJL.
DUP.
DOW.
MCH.
ARK.
DOW,
APD.
APD.
TNA.
PRD.
FMP.
DUP,
ACY,
AAP,
ACP,
RIL.
UCC.
KF, 1
KF.
ACN,
ARZ,
GIV.
GIV.
AMB,
ACY,
SDC.
GAF,
GAF.
DUP, GAF, ICI, TRC.
ICI, TRC.
CMG, DUP, TRC.
DUP, ICI, TRC.
DUP, GAF, ICI, MAY, TRC.
UPJ.
DUP, MOB, UPJ.
MOB, UPJ.
MOB, UCC.
MOB.
DUP, MOB,. OMC, RUG, UCC, WYN.
EK, MOB, UPJ.
GE, MON, SHC, UCC.
DUP, GAF, TRC.
ACS, ACY, EKT, HSH, ICC, TRC.
KPT, RIL.
ACY, ASH, PPC.
GIV, HN, NCI.
LIL, WAY.
DUP, TRC.
44
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.
-Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
4'-Methoxy-2- (p-methoxyphenyl)acetophenone
N- (2-Methox>'-l-naphthyl)acetainide
6-Methoxy-8-nitroquinoline
(p-Methoxyphenyl) acetic acid
5-[N- (2 '-Methoxy) phenyl] -2-aminophenol
4-Methoxy-m-phenylenediainine sulfate
6-Methoxy-2- (phenylthio)quinoline
4 ' -Methoxypropiophenone
1- (Methylaniino)anthraquinone
1- (Methylaniino)-4-p-toluidinoanthraquinone
N-Me thy 1 aniline
3- [N-Methylanilino)propionitrile
5-Methyl-o-anisidine [NH2=1]
m-Methylanisole
N-Methylanthranilic acid
2-Methvlanthraquinone
L-'t'.^cu/lDenzo[f Jquinoline
2-Methylbenzothiazole
N-Methylbenzylamine
Methylbenzyl ether
5- (l-Methylbutyl)barbituric acid
3-Methy 1 cholanthrene
Methyl eye lohexane
4-Methylcyclohexanone
Methylcyclopentadiene
N-Methyldicyclohexylamine
4-Methyl-a,a-diphenyl-l-piperazine ethanol, dihydro-
chloride.
N-Methyleneaniline '
4,4'-Methylenebis[2-chloroaniline]
4,4'-Methylenebis[N,N-diethylaniline]
.4,4'-Methylenebis[N,N-dimethylaniline] (Methane base)
4,4'-Methylenebis(3-hydroxy-2-naphthoic acid) , disodium
salt.
2,2'-Methylenebis (6-nonyl-p-cresol)
4,4'-Methylenedianiline
5,5'-Methylenedisalicylic acid
Methylhydroquinone
2-Methyl indole
2-Methylindole-3-carboxaldehyde
6-Methyl-2- (2-methyl-6-quinolyl) -7-benzothiazolesulfonic
acid.
N-Methyl-4'-nitroacetanilide
N-Methyl-p-nitroaniline
5-Methyl-4-nitro-o-anisidine
4-Methyl-2-nitroanisole
2-Methyl-l- n i t roanthr aquinone
2-Methyl -S-nitroimidazole
N-Methyl-N-nitroso-p-toluenesulfonamide
2-Methyl-S-norbornene-2 ,3-dicarboxylic anhydride
Methylnorbornene-2,3-dicarboxylic anhydride, isomers
m- (3-Methy 1-5-0X0- 2 -pyrazol in- l-yl)benzenesulfonamide
p- (3-Methy 1-5-0X0- 2 -pyrazol in- l-yl)benzenesulfonamide
*p- (3-Methy 1-S-oxo- 2 -pyrazol in- l-yl)benzenesulfonic
acid.
3- (3-Methy l-S-oxo-2-pyrazol in- l-yl)-l,5-naph thalene-
disulfonic acid,
4- (3-Methy l-S-oxo-2-pyrazolin-l-yl)-in-toluenesulfonic
acid [SOaH^l] .
2-Methyl -5-phenylbenzoxazole
1-Methyl-l-phenylhydrazine
l-Methyl-2-phenyl indole- 3- carboxaldehyde
l-Methyl-4-phenylisonipecotic acid
5-Methyl-3-phenyl-4-isoxazolecarboxylic acid
CTN.
TRC.
SDW.
UOP.
SDC.
WAY.
EK.
LIL.
MP, ACS, ACY, ICI.
GAP, ICI.
DUP.
DUP.
SDC.
GIV.
GIV, ICC.
ACS, ACY.
ACY.
FMT.
MLS, SDW.
UCC.
LIL.
EK.
PLC.
EK.
ENJ.
ABB.
ABB.
DUP.
DUP.
ACY, GAP, SDH, TRC.
ACY, DUP, SDH.
PD.
ACY.
ACS, DOW, DUP, MOB.
HN.
EKT.
TRC.
GAP.
DUP.
ACS, GAP.
PCW.
SDC.
GAP,
ICI.
RDA.
ALD,
EK.
VEL.
ACS.
CMG,
TRC,
VPC.
CMG.
AAP,
ACY,
GAP,
TRC,
VPC
CMG, VPC.
EK.
EK.
GAP.
SDW.
ARS.
CYCLIC INTERMEDIATES
45
TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
5-Methyl-3-phenyl-4-isoxazolecarboxylic acid hydro-
chloride.
*3-Methyl-l-phenyl-2-pyrazolin-5-one (Developer Z)
Methyl phenyl sulfide (Thioanisole)
4-Methyl-l-piperazineacetic acid, methyl ester
l-Methyl-4-piperidinol
3- (a-Methylpiperidine)propanol
Methylpvrazine
1-Methylpyrrole
8-Methylquinoline
*a-Methylstyrene
ar-Methylstyrene (Vinyl toluene)
2- (Methyl sulfonyl}-4-nitroani line
4- (Methylthio)-m-cresol
3-Methylthiophene
p-(Methylthio) phenol
3-Methyl-l- (thiosulfophenyl) -2-pyrazolin-5-one, sodium
salt.
3-Methyl-6-p-toluidino-7H-dibenz[f ,ij] isoquinoline-
2,7(3H)-dione.
1-Naphthaldehyde
♦Naphthalene, solidifying at 79° C. or above (refined
flake) (from domestic crude).
1,5-Naphthalenediol (1,5-Dihydroxynaphthalene)
2,7-Naphthalenedisulfonic acid
1-Naphthalenesulfonic acid
1-Naphthalenesulfonic acid, sodium salt -■
2-Naphthalenesulfonic acid
2-Naphthalenesulfonic acid, sodium salt
l-Naphthalenesul£onyl chloride
2-Naphthalenesuironyl chloride
1,4,5,8-Naphthalenetetracarboxylic acid
Naphthalimide
1-Naphthol (a-Naphthol)
2-Naphthol, tech. i.B-iiaphthol)
p-Naphtholbenzein
1,2-Naphthoquinone
Naphthostyril
Naphth[l,2-d] [1 ,2,3]oxadiazole-5-sul£onic acid
1-Naphthylamine (a-Naphthylamine)
1-Naphthylamine hydrochloride
p- (2-Naphthylamino)phenol (N- (p-Hydrophenyl)-2-
naphthylamine) .
N- (l-Naphthyl)ethylenediamine dihydrochloride
(2-Naphthyloxy) acetic acid
(2-Naphthyloxy) acetic acid, sodium salt
Nicotinonitrile (3-Cyanopyridine)
Nitroaceanthra[2,l-a]aceanthrylene-5,13-dione
*3'-Nitroacetanilidei
*4'-Nitroacetanilide
2'-Nitro-p-acetanisidide
4'-Nitro-o-acetanisidide
3'-Nitro-p-acetophenetidide
3'-Nitroacetophenone
m-Nitroaniline
o-Nitroanlline
p-Nitroaniline
2- (o-Nitroanilino)ethanol
2-Nitro-p-anisidine [NHz^l]
4-Nitro-o-anisidine [NH2=1]
5-Nitro-o-anisidine [NHz^l]
See footnotes at end of table.
ACY,
DUP,
GAP, SDH, VPC.
PIT.
ABB.
ARA.
LIL.
DUP.
DUP.
EK.
ACP,
CLK,
DOW, HPC, PCC, SKO
DOW.
TRC.
CRZ.
SDW.
CRZ.
SDC.
GAP,
ICI.
ELK.
KPT,
RIL,
WTC.
ACS.
ACS,
DUP,
TRC.
TRC.
TRC.
ACY,
EK,
NES.
ACY.
EK.
DUP.
TRC.
ACS.
UCC.
ACY,
DUP.
EK.
EK.
ACS.
ACS,
GAP,
TRC.
ACS,
DUP.
GAP.
SDC.
RSA.
APD.
APD.
NEP,
RIL.
ICI.
AAP,
GAP,
TRC.
GAP,
SAL,
TRC.
DUP.
DUP.
AAP
CTN,
SDH
ACY,
X.
AAP
MON
AAP
HON
SAL.
AAP
DUP.
DUP,
SDH
BUC.
462-669 O - 72
46
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers ' identification codes
(according to list in table 3)
o-Nitroanisole
p-Nitroanisole
5-Nitroanthranilic acid
1-Nitroanthraquinone
2- (4-Nitro-2-anthraquinonyl)anthra[2,3-d] -oxazole-5,10-
dione.
m-Nitrobenzaldehyde
3' -Nitrobenzanilide
*Nitrobenzene
*ni-Nitrobenzenesulfonic acid
*m-Nitrobenzenesulfonic acid, sodium salt
p-Nitrobenzenesulfonyl chloride
5-Nitro-2-benziinidazolinone
m-Nitrobenzoic acid
m-Nitrobenzoic acid, sodium salt
p-Nitr ©benzoic acid
2- (m-Nitrobenzoyl)-o-acetanisidide
m-Nitrobenzoyl chloride
p-Nitrobenzoyl chloride
p-Nitrobenzyl alcohol
4- (p-Nitrobenzyl) pyridine
4 ' -Nitro-4-biphenylcarboxylic acid
4-Nitro-sec-butylbenzene
2-Nitro-p-cresol
2-Nitro-p-cymene
Nitrodiphenylamine
5-Nitro-2-furanmethanediol, diacetate
5-Nitroisophthalic acid
1-Nitronaphthalene
3-Nitro-l,5-naphthalenedisulfonic acid
4-Nitronaphthalic anhydride
7(and 8)-Nitronaphth[l,2-d] [l,2,3]oxadiazole-s-sulfonic
acid.
4-Nitrooxanilic acid
p-Nitrophenethyl alcohol
o-Nitrophenol
*p-Nitrophenol
*p-Nitrophenol, sodium salt
*4' (p-Nitrophenyl)acetophenone
4-[ (p-Nitrophenyl)azo]-o-anisidine
2-Nitro-p-phenylenediamine
4-Nitro-o-phenylenedi amine
(p-Nitrophenyl) hydrazine
2,2'- [ (m-Nitrophenyl)imino]diethanol
2,2'- [ (m-Nitrophenyl)imino]diethanol, diacetate ester —
2- (p-NitrophenylJ-1-octadecyl-S-benzimidazolesulfonic
acid.
1- (m-Nitrophenyl)-5-oxo-pyrazoline-3-carboxylic acid
3-Nitrophthalic acid
3-Nitrophthalic anhydride
5-Nitrosalicylaldehyde
3(and S)-Nitrosalicyclic acid
l-Nitroso-2-naphthol
p-Nitrosophenol
4-Nitrostilbene
m-Nitrotoluene
o-Nitrotoluene
p-Nitrotoluene
Nitrotoluene mixtures
p-Nitrotoluenesulfonic acid
DUP,
MON.
DUP.
TRC.
ACY.
ACS,
GAP.
SDH.
AAP.
ACS,
ACY,
DUP,
FST,
MOB,
MON,
RUC
ACY,
DUP.
ACS,
GAP,
MON,
MRA.
EK.
DUP.
SAL,
SDH,
WAY.
SAL,
WAY.
DUP.
GAP.
ARS,
HK.
DUP,
TRC.
WAY.
SW.
EK.
ACY,
MON.
NOR.
PIS.
DUP.
GAP,
TRC.
ACS.
ACS,
GAP,
TRC.
DUP.
PCW.
MON.
DUP,
MON,
SDC, UPM
MON,
UPM.
DUP,
PIS,
GAP.
AAP.
WAY.
DUP,
PMT.
EK,
RSA.
DUP.
DUP.
GAP.
DUP,
VPC.
EK.
EK.
EK.
GAP.
EK.
ACY,
SDC.
GAP.
DUP,
PST.
DUP,
FST.
DUP,
FST.
DUP,
FST.
CGY.
CYCLIC INTERMEDIATES
47
TABLE 2. — Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers ' identification codes
(according to list in table 3)
3-Nitro-p-toluenesulfonic acid [S03H=1]
*5-Nitro-o-toluenesulfonic acid [S03H=1]
3-Nitro-p-toluic acid, methyl ester
2-Nitro-p-toluidine [NH2=1]
*5-Nitro-o-toluidine [NH2=1]
5-Nitro-2-p-toluidinobenzenesulfonic acid
16-Nitroviolanthrone
4-Nitro-in-xylene
*Nonylphenol
5-Norbornene-2,3-dicarboxylic anhydride
Octylphenol
p-Octylphenyl acid phosphate
Oxalacetic acid, diethyl ester, (p-sulfophenyl)-
hydrazone.
Oxanilide
*l-[7-Oxo-7H-benz[de]anthracene-3-yl)]anthraquinone
1 J 1 ' - [ C7-0xo-7H-benz [de] anthracen-3,9-xyleneldiiinino] -
dianthraquinone .
5-0x0-1- Cp-sulfophenyl)-2-pyrazoline-3-carboxylic acid
(Pyrazolone T) .
4,4'-Oxydianiline
Penicillin, N-ethylpiperidine salt
Pentachloropyridine
o,a,a,oi' ,01' -Pentachloro-o-xylene
l,l,3,3,S-Pentamethylindan
o-Pentylphenol (o-Amylphenol)
p-tert-Pentylphenol
3,4,9,10-Perylenetetracarboxylic acid
3,4,9,10-Perylenetetracarboxylic-3,4:9,10-di(3-aniino-
phenylimide) .
3., 4,9,10-Perylenetetracarboxylic-3,4:9,10-diiinide
Phenethylamine
a-Phenethylamine
Phenethylamine sulfate
o-Phenethylbenzoic acid
m-Phenetidine
o-Phenetidine
p-Phenetidine
*Phenol:
*Natural :
*Froin coal tar:
39° C, m.p
82%-84%
U.S.P--
All other
*From petroleum
* Synthetic:
By caustic fusion: U.S.P
From chlorobenzene by liquid-phase hydrolysis: U.SiP-
From chlorobenzene by vapor-phase hydrolysis: U.b.P--
*From cumene by oxidation: U.S.P
Phenolsulfonaphthalein
Phenolsulfonaphthalein, sodium salt
Phenolsulfonic acid, lithium salt
Phenoxyacetic acid, sodium salt
2-Phenoxypropanol
2-Phenoxypropionic acid
2-Phenoxypropionyl chloride
CMG,
TCD.
ACS,
ACY,
DUP,
GAF, SDH,
TRC
SDH.
ABB,
DUP,
SW.
BUG,
DUP,
PGW,
SDH.
TRC.
GAF,
ICl,
MAY.
DUP.
GAF,
JGC,
MON,
RH, STP.
VEL.
RH.
SM.
TRC.
ACY, DUP, GAF, ICI, MAY, TRC.
ACY, ICI, MAY, TRC.
MRK.
DOW.
GIV.
PAS.
PAS, PRD.
ACS, GAF.
SDC.
ACS, SDC.
MLS.
MLS.
MLS.
LIL.
EK.
MON.
MON.
KPT.
PRD.
ACP,
KPT.
MAL.
ACP,
KPT.
MER,
NPC,
PIT,
PRD
MON,
RCI.
DOW.
HKD,
UCC.
ACP,
CLK,
HPC,
MON
ARA, BPC.
ARS.
ARS.
ARS,
See footnotes at end of table.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
Phenylacetic acid (a-Toluic acid)
Phenylacetic acid, ethyl ester, tech
Phenylacetic acid, methyl ester
Phenylacetic acid, potassium salt
Phenylacetic acid, sodium salt
*Phenylacetonitrile (a-Tolunitrile)
4'-Phenylacetophenone
Phenylacetyl chloride
N-Phenylanthranilic acid
2-Phenylanthra[2,3-d]oxazole-5, 10-dione
Phenolarsine oxide
*p-Phenylazoaniline (C.l. Solvent Yellow 1) and hydro-
chloride.
4- (Phenylazo)diphenylamine
4- (Phenylazo)-l-naphthylamine
5- (Phenylazo)salicylic acid
l-Phenyl-l,3-butanedione
a- Phenyl -o-cresol
1-Phenylcyclopentanecarboxylic acid
N,N'-p-Phenylenebis[acetamide]
m-Phenylenediamine
o-Phenylenedi amine
p-Phenylenedi amine
d- Phenylephrine base
dl-Phenylephrine base
2-Phenylethenesulfonic acid, sodium salt
Phenyl ether (Diphenyl oxide)
d(-)Phenylglycine
d- (-)Phenylglycine, N-carboxy anhydride
Phenylglycine, sodium salt
d(-)Phenylglycl hydrochloride
5-Phenylhydantoin
Phenylhydrazine hydrochloride
2,2 ' - [ (Phenyl )imino]diethanol (N-Phenyldiethanolamine) -
3,3 ' - [ (Phenyl)imino]dipropionitrile
Phenylmalonic acid, diethyl ester
o-Phenylphenol
o-Phenylphenol , chlorinated
o-Phenylphenol, sodium salt
p-Phenylphenol
N-Phenyl-1-p-phenylenediamine
Phenylphosphinic acid
Phenylphosphonothioic dichloride
Phenylphosphorous dichloride
1-Phenylpiperazine
1-Phenyl-l ,2-propanedione, 2-oxime
Phenyl- 2-propanone
N-3-Phenylpropyl-p-toluidine
dl-Phenylsuccinic acid
Phenyl sulfide
Phenyl sulfone
1 -Phenyl -2- thiourea
Phenylundecanoic acid
Phloroglucinol
l(2H)-Phthalazinone
Phthalic acid
Phthalic acid, diallyl ester
Phthalic acid, monopotassium salt
* Phthalic anhydride
Phthalide
Phthalimide
Phthalimide, potassium salt
BPC, GIV, MAL.
BPC.
BPC.
BPC, OPC.
BPC, OPC.
BPC, OPC, SDW, UOP.
DUP, GAP, NES.
BJL.
SDW.
GAP.
EK.
ACS, ACY, GAP, TRC.
EK.
DUP.
TRC.
EK.
RBC.
SK.
ACY.
ACY,
DUP.
DUP,
SW, TRC.
ACY,
SDC.
SDW.
SDW.
SHL.
DOW.
BKL,
KF, OTC.
OTC.
ACS.
KF,
OTC.
ABB.
EK.
EKT.
DUP.
BPC.
DOW,
RCI.
DOW.
DOW.
DOW.
USR.
SPA.
SFI.
SFI.
RSA.
NEP,
ORT.
ORT,
SK.
EK.
MRT.
x.
EK,
SW.
FMP.
EK.
AGP,
GRH,
KPS,
KPT,
MON,
PCC,
PTO,
RCI,
SOC,
STP
SW
, UCC
ACS,
FMT.
DUP
SW.
EK,
SDW.
CYCLIC INTERMEDIATES
49
TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
[PhthalocyaninatoC2-)] copper
Phthalocyanine, copper complex, di-Cand tri)-chloro
methyl .
Phthaloyl chloride CPhthalyl chloride)
*Picolines:^
*2-PicoUne (a-Picoline)
3-Picoline C3-Picoline)
4-Picoline Cy-Picoline)
Picoline C3,4-iiiixture)
Picolinic acid
Picolinonitrile C2-Cyanopyridine)
3-Picolylamine
Picric acid (Trinitrophenol)
2-Pipecoline
2,5-Piperazinedione
Piper idine
3-Piper idinopropiophenone hydrochloride
Polychlorobiphenyl
PolyCmethylenephenylene) polyamine
Primuline base
Priraulinesulfonic acid
Propiophenone
2-Propy 1-4- amino- 5-methoxymethylpyrimidine amino
n-Propylbenzene sulfonate
8,16-Pyranthrenedione
Pyridine, refined:^
2° Pyridine
Other grades
Pyridine hydrochloride
3-Pyridinemethanol
Pyridine-N-oxide
2-Pyrimidinol
2 CIH) -pyrimidinone
2-Pyrrolidinone
3-(l-Pyrrolidinyl)propiophenone hydrochloride
Quinaldine
Quinoline:
1° and 2° Quinoline
Other grades
2,4-Quinolinediol
Quinophthalone (Quinoline yellow, base)
3-Quiniclidinol
Resorcinol, monoacetate (non-medicinal grade)
Resorcinol, tech
6-Resorcylaldehyde
g-Resorcylic acid
*Salicylaldehyde
Salicylaldehyde oxime
Salicylanilide
*Salicylic acid, tech
Salicylic acid, ammonium chromium complex
Salicylic acid, sodium-chromium complex
Salicylic acid, sodium salt (crude)
Salicylideneaminoguanidine oleate
*Styrene, all grades
Sulfaguanidine, tech
S-Sulfamoylanthranilic acid
Sulfanilamide, tech
Sulfanilic acid (p-Aminobenzenesulfonic acid) and salt-
S-Sulfoanthranilic acid
o-Sulfobenzoic acid, cyclic anhydride
Manufacturers' identification codes
(according to list in table 3)
GAF, ICI, TRC.
TRC.
DUP, MON.
ACP, KPT, NEP, RIL, UCC .
NEP, RIL.
NEP, RIL, UCC.
ACP, KPT.
NEP.
NEP, RIL.
RIL.
SDC.
LIL.
EK.
ABB, DUP, MRK, RIL.
ACY, SDW.
MON.
KAI.
DUP.
ATL.
ORT, UOP.
MRK.
NES.
ICI, TRC.
ACP, KPT, NEP, RIL.
KPT.
EK.
RIL.
RIL.
CGY.
VAL.
GAF.
LIL.
ACS, ACY.
ACP, KPT.
EK, KPT.
PCW.
ACS.
APD.
AAP.
KPT, UPF.
UPF.
ACY, KPT.
DOW, HN, MTR, RDA.
EK.
CFC.
CFC, DOW, HN, MON, SDH.
TRC.
TRC.
DOW.
DUP.
ACC, CSD, DOW, ELP, ENJ, FG,
KPP, MCB, MON, SHC
SKC, SNT, UCC.
SAL.
TRC.
SAL.
ACS, ACY, CTN.
ICI.
EK.
See footnotes at end of table
SYNTHETIC ORGAmC CHENHCALS, 1970
TABLE 2. — Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
la-Sulfobenzoic acid, monosodium salt
p-Sulfobenzoic acid, potassium salt
5-Sulfoisophthalic acid, 1 , 3-dimethyl ester, sodium
salt.
5-Sulfoisophthalic acid, sodium salt
Sulfor.ylbis[N-methylaniline]
4,4'-Sulfonyldianiline
N-S'-Sulfonyldianthranilic acid
4,4' -Sulfonyldiphenol (4,4' -Dihydroxydiphenylsulf one) -
Sulfonyldiphenol, mixed isomers
4-Sulfophthalic acid
"Terephthalic acid
*Terephthalic acid, dimethyl ester
Terephthalic acid, diphenyl ester
Terephthaloyldiacetic acid, diethyl ester
Terphenyl (Phenylbiphenyl)
Tetraaminobenzophenone
Tetraaminodiphenyl ether
1,2,4,5-Tetraaminobenzene tetrahydrochloride
[4,4' ,4' ' ,4' ' '-Tetraaminophthalocyaninato (2)] copper —
3' ,3' ' ,5' ,5' '-Tetrabromophenolphthalein, ethyl ester —
Tetrabromophthalic anhydride
Tetrabromo-8 , 16-p)Tanthrenedione
1,4,3,8-Tetrachloroanthraquinone
1,2,4,5-Tetrachlorobenzene
l,2,4,5-Tetrachloro-3-nitrobenzene
Tetrachlorophthalic anhydride
Tetrachloroviolanthrone
Tetrahydrofuran
Tetrahydrofurfury 1 methacry late
1,4,5,8-Tetrahydroxyanthraquinone
*l,4,5,8-Tetrahydroxyanthraquinone, leuco derivative
1,4,5, 8-Tetrakis (1 -anthraquinony lamino) anthraquinone
(Pentanthrimide) .
l,2,3,S-Tetramethylbenzene (Isodurene)
1,2,4,5-Tetramethylbenzene (Durene)
p- (l,l,3,3-Tetramethylbutyl)phenol
3,3' ,5,S'-Tetramethyldiphenoquinone
X , N, N ' , X ' -Tetramethyl -p-pheny 1 enediamine dihydro-
chloride.
[4,4'4' ',4'' '-Tetranitrophthalocyaninato (2)] copper
2-(2-ThenylaminoJp>Tidine
Thiobenzamide
*3,3'-Thiobis[7H-benz[de]anthracen-7-one]
l,l'-Thiobis[2-naphthol]
2,2'-Thiobis[5-nitrobenzenesulfonic acid]
4,4 '-Thiodiani line
6,6-Thiodiiiietanilic acid
2-Thiopheneacetyl chloride
2-Thiophenecarboxaldehyde
sym-Thymol
*Toluene-2,4-diamiTie (4-m-Tolylenediamine)
To luene-2, 5 -diamine sulfate
Toiuene-2,4-disulfonic acid
o-Toluenesulfonamide
p-Toluenesulfonamide
o(and p}-Toluenesulfonic acid
p-Toluenesulfonic acid
p-Toluenesulfonic acid, methyl ester
p-Toluenesulfonic acid, monohydrate
NES.
PCW.
PCW.
SDC.
RSA.
TRC.
MON,
UPF.
CIVX,
ACC,
ACC,
BJL.
PCW.
MON.
BJL.
BJL.
BJL.
SDC.
EK.
MCH.
ACS,
DUP,
DOW,
SDH.
MON.
C^F.
DUP,
S.AR.
ICC.
ACS,
GAP.
HSC.
DUP, EKT, SM.
DUP, EKT, HPC.
GAP.
GAP.
HK.
QKO.
GAP, ICC, TCD, TRC.
SNT.
SNT.
GAF, SCN.
DUP.
EK.
SDC.
DUP,
ACY.
GAP.
ACY.
ACS,
LIL.
ABB.
GIV,
ACS,
WAY.
GAP.
MON.
MON.
EK,
TEN
ICI
NES
GAP, MAY, TRC.
ACY, DUP, GAP, OMC, RUC, TRC, UCC.
MON, SW, UPF,
, UPF.
CYCLIC INTERMEDIATES
51
TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970— Continued
Manufacturers' identification codes
(according to list in table 3)
p-Toluenesulfonyl chloride
a-Toluenesulfonyl fluoride
m-Toluic acid
o-Toluic acid
p-Toluic acid
m-Toluidine
o-Toluidine
o-Toluidine hydrochloride
p-Toluidine
p-Toluidine hydrochloride
Toluidines, mixed
m-Toluidinomethanesulfonic acid
o-Toluidinomethanesulfonic acid
8-p-Toluidino-l-naphthalenesulfonic acid
*o- (p-Toluoyl)benzoic acid
N-(p-Tolylazo)sar cosine
*4-Co-Tolylazo)-o-toluidine (C.I. Solvent Yellow 3) —
4- (o-Tolylazo)-o-toluidine hydrochloride
1-p-Tolyldodecane
2,2 '-(m-Toly limine) diethanol
2,2'- (m-Tolylimino)diethanol, diacetate ester
p-Tolylmercuric chloride
Tolyltriazole
3,4' ,5-Tribromosalicylanilide
1,2, 3 (and l,2,4)-Trichlorobenzene
*l,2,4-Trichlorobenzene
N,2,6-Trichloro-p-benzoquinoneimine
1,2,4-Trichloro-S-nitrobenzene
Trichlorophenylsilane
a,a,a-Trichlorotoluene (Benzotrichloride)
a,2,4-Trichlorotoluene
a,3,4-Trichlorotoluene
2,4,6-Trichloro-s-triazine (Cyanuric chloride)
1,3,5-Triethylbenzene
2-(Trifluoroinethyl)phenothiazine
a,a,a-Trif luoTo-N-phenyl-m-toluidine (3- (Trif luoro-
methyl)diphenylaiiiine) .
a,a,a-Trifluorotoluene
a,a,a-Trifluoro-m-toluidine
a,a,a-Trifluoro-o-toluidine
1,2,4-TrihydToxyanthTaquinone
Trihydroxybiphenyl
1,2,3-Trimethylbenzene (Hemimellitine)
1,2,4-Trimethylbenzene (Pseudocumene)
1,3,5-Trimethylbenzene fMesitylene)
3,5,5-Trimethylcyclohexanol
2,3,3-Tri]iiethyl-3H-indole--^
*l,3,3-Trimethyl-V^,ci-indolineacetaldehyde
*l,3,3-Trimethyl-2-methyleneindoline (Trimethyl base)-
Trinethylphenylammonium iodide
a, a' ,2-Trimethyl-l,4-piperazinediethanol
2,4,6-Trimethylpyridine
1,3,5-Trinitrobenzene
2,4,6-Trinitrobenzenesulfonic acid
2,4,7-Trinitrofluoren-9-one
2,4,6-Trinitroresorcinol, lead derivative
Triphenyl amine
Triphenylmethane
Triphenylmethanol
a,a' ,a' ' -Tris (dimethylaminojmesitbl
Tris (2-methyl-l-aziridinyl)phosphine oxide
Tri-o-tolylphosphine
Tri-p-tolylphosphine
EK.
BPC,
CWL.
BPC,
CWL.
BPC,
CWL,
EK.
DUP.
DUP,
FST.
AAP,
ACY.
DUP.
EK.
DUP.
VPC.
GAP,
TRC,
VPC.
ACS.
ACS,
.ACY,
DUP.
BUC,
GAP.
ACY,
ALL,
DUP, GAP
aAF.
X.
EKT.
SDC.
EK.
SW.
PCW,
SW.
DVC,
PPG.
DOW
HK,
SVT.
EK.
PCW.
DCC
UCC.
HK,
VEL.
HN.
HN.
ACY
CGY
NIL.
DUP
GAP.
PCW.
S^JT.
PLC,
SNT.
SNT.
ARS.
GAP,
TRC.
ACS,
DUP,
GAF,
TRC,
VPC.
ACS,
DUP,
GAP,
TRC,
VPC.
EK.
WYN.
KPT,
RIL.
EK.
EK.
EK.
EK.
EK.
EK.
EK.
RH,
TKL.
ARS,
ICC.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Cyclic intermediates for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
Tropine
m-Ureidoaniline
*7)7'-Ureylenebis[4-hydroxy-2-naphthalenesulfonic acid]
(J Acid Urea).
Veratraldehyde (3,4-Dimethoxybenzaldehyde3
Veratryl alcohol (3,4-Dimethoxybenzyl alcohol)
p-Vinylbenzenesulfonic acid, sodium salt
2-Vinylcyclohexene
5-Vinyl-2-picoline (MVP)
2-Vinylpyridine
4-Vinylpyridine
Vinyl toluene
*Violanthrone (Dibenzanthrone)
Xanthene-9-carboxylic acid
*ni-Xylene
*o-Xylene
*p-Xylene
2,5-Xylenesulfonic acid
Xylenesulfonic acid, mixed isomers
Xylenol crystals
2,6-Xylenol
Xylenols :
Medium b.p
Not classified as to b.p
Xylidines :
2,4-Xylidine (m-4-Xylidine)
2,6-Xylidine
Original mixture
4- (2,4-Xylylazo}-o-toluidine
4- (2,5-Xylylazo)-o-toluidine
4-C2,4-Xylylazo)-2,5-xylidine
4- (Xylylazo)xylidines, mixed
All other cyclic intermediates
CTN.
ICI.
CMG, GAF, TCD, TRC, VPC.
GIV, LIL, SLV.
LIL.
DUP.
UCC.
PLC.
RIL.
RIL.
FG.
ACS, ACY, ATL, DUP, GAF, ICl, MAY, SDC, TRC.
MAL.
ATR, SNT, SOC.
ASH, ATR, CCP, CPI, CSD, CSO, CSP, DLH, ENJ, MON,
PPR, SNT. SOC, SUN, TOC.
ACC, ATR, CSD, CSC, ENJ, HCR, PPR, SHC, SHO, SNT,
SOC, SOC, TOC.
EK, NES.
NES.
ACP.
GE.
NPC.
KPT.
DUP.
DUP.
DUP.
ACS.
ACY.
ACS.
GAF.
AAP, ACY, ALL, ARA, CUC, CWN, DUP, EK, GAF, HMY, HN,
ICC, JCC, LIL, MON, MRK, OPC, PCW, PRD, RH, SCH,
SIV, UCC, VEL, IVTC, x, x, x.
Producers of medicinal grade are listed in "^^edicinal chemicals."
Does not include manufacturers' identification codes for producers that report to the Division of Fossil Fuels,
U.S. Bureau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey Coke Producers
in the United States in 1970, July 30, 1971.
CYCLIC INTERMEDIATES
53
TABLE 3. --Cyclic intermediates; Directory of manufacturers, 1970
ALPHABETICAL DIRECTORY BY CODE
[Names of manufacturers that reported production or sales of cyclic intermediates to the U.S. Tariff Commission for
1970 are listed below in the order of their identification codes as used in table 2]
Code
Code
identi-
Name of company
identi-
Name of company
fication
fication
AAP
American Aniline Products, Inc.
FG
Foster Grant Co., Inc.
ABB
Abbott Laboratories
FIN
Fine Organics. Inc.
ACC
Amoco Chemical Corp.
FIS
Fisher Chemical Co., Inc.
Allied Chemical Corp.:
FLM
Fleming Laboratories, Inc.
AC?
Plastics Div.
FMP
FMC Corp., Organic Chemicals Div.
ACS
Specialty Chemicals Div.
FMT
Fairmount Chemical Co., Inc.
ACY
American Cyanamid Co.
FST
First Chemical Corp.
ALD
Aldrich Chemical Co., Inc.
ALL
Alliance Chemical, Inc.
GAF
GAF Corp., Chemical Div.
ALT
Crompton § Knowles Corp., Althouse Div.
GE
General Electric Co.
AMB
American Bio-Synthetics Corp.
GIV
Givaudan Corp.
APD
Atlas Chemical Industries, Inc.
GLY
Glyco Chemicals, Inc.
ARA
Arapahoe Chemical Div. of Syntax Corp.
GOC
Gulf Oil Corp., Gulf Oil Co. Chemical Co
-
ARK
Armstrong Cork Co.
United States
ARS
Arsynco, Inc.
GRH
W. R. Grace 5 Co.. Hatco Chemical Div.
ARZ
Arizona Chemical Co.
GRS
Champlin Petroleum Co. Corpus Christi Refinery
ASH
Ashland Oil, Inc.
GYR
Goodyear Tire § Rubber Co.
ASL
Ansul Chemical Co.
ATL
Atlantic Chemical Corp.
HCR
Hercor Chemical Corp.
ATR
Atlantic Richfield Co., Arco Chemical Co.
HEX
Hexagon Laboratories, Inc.
Div.
HK
HKD
Hooker Chemical Corp.:
Durez Div.
BJL
Burdick 5 Jackson Laboratories, Inc.
HMY
Humphrey Chemical Co.
BKL
Millmaster Onyx Corp., Millmaster Chemical
HN
Tenneco Chemicals, Inc.
Div., Berkeley Chemical Dept.
HOU
Air Products § Chemicals, Inc., Houdry
BPC
Stauffer Chemical Co., Benzol Products Div.
Process § Chemical Div.
BRP
BP Oil Corp.
HPC
Hercules, Inc.
BUC
Blackman-Uhler Chemical Co.
HSC
Chemetron Corp., Pigments Div.
HSH
Harshaw Chemical Co. Div. of Kewanee Oil
Co.
CCP
Crown Central Petroleum Corp.
HST
American Hoechst Corp.
CCW
Cincinnati Milacron Chemicals, Inc.
CEL
Celanese Corp.
ICC
Inmont Corp.
CFC
Sun Chemical Corp.
ICI
ICI America, Inc.
CGY
Ciba-Geigy Corp.
IDC
Industrial Dyestuff Co.
CHO
Stauffer Chemical Co., Calhio Chemicals,
Inc. Div.
JCC
Jefferson Chemical Co., Inc.
CLK
Clark Oil § Refining Corp., Clark Chemical Co.
CMC
Nyanza, Inc.
KAI
Kaiser Aluminum § Chemical Corp., Kaiser
CNP
Columbia Nipro Corp.
Chemicals Div.
CO
Continental Oil Co.
KF
Kay-Fries Chemicals, Inc.
CPI
Commonwealth Petrochemicals, Inc.
KPP
Sinclair-Koppers Co.
CRS
Carus Chemical Co., Inc.
KPS
Koppers Pittsburgh Co.
CRZ
Crown Zellerbach Corp., Chemical Products Div>
KPT
Koppers Co.^ Inc., Organic Materials Div
CSD
Cosden Oil § Chemical Co.
CSC
Cities Service Oil Co.
LAK
Lakeway Chemical Co.
CSP
Coastal States Petrochemical Co.
LIL
Eli Lilly § Co. § Puerto Rico
CTN
Chemetron Corp., Organic Chemical Div.
cue
Air Reduction Co., Inc., Chemicals § Plastics
MAL
Mallinckrodt Chemical Works
Div.
MAY
Otto B. May, Inc.
CWL
Stauffer Chemical Co., Cowles Chemical Div.
MCB
Borg-Warner Corp., Marbon Chemical Div.
CWN
Upjohn Co., Carwin Organic Chemicals
MCH
MER
Michigan Chemical Corp.
Merichem Co.
DA
Diamond Shamrock Corp.
MET
M S T Chemicals, Inc.
DBC
Dow Badische Co.
MLS
Miles Laboratories, Inc., Marschall Div.
DCC
Dow Corning Corp.
MOB
Mobay Chemical Co.
DLH
Amerada Hess Corp., Hess Oil § Chemical Div.
MOC
Marathon Oil Co., Texas Refining Div.
DOW
Dow Chemical Co.
MON
Monsanto Co.
DSC
Dye Specialties, Inc.
MRA
Crown-Metro, Inc.
DUP
E. I. duPont de Nemours § Co., Inc.
MRK
Merck 5 Co. , Inc.
DVC
Dover Chemical Corp.
MRT
MTO
Morton Chemical Co.
Montrose Chemical Co.
EK
Eastman Kodak Co . :
MTR
Chris-Craft Industries, Inc., Montrose
EKT
Tennessee Eastman Co. Div.
Chemical Div.
ELP
El Paso Products Co.
ENJ
En jay Chemical Co.
NCI
Union Camp Corp., Chemicals Div.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 3. — Cyclic intermediates: Directory of manufacturers, 1970 — Continued
Code
Code
identi-
Name of company
identi-
Name of company
fication
fication
NEP
Nepera Chemical Co., Inc.
SHL
Nitine, Inc., Div. of Shulton, Inc.
NES
Nease Chemical Co., Inc.
SHO
Shell Oil Co.
NEV
Neville Chemical Co.
SK
Smith, Kline 5 French Laboratories
NIL
Nilok Chemicals, Inc.
SKC
Sinclair-Koppers Chemical Co.
NOR
Norwich Pharmacal Co.
SKO
Skelly Oil Co.
NPC
Northwest Petrochemical Corp.
SLV
Sterwin Chemicals, Inc.
SM
Mobil Chemical Co.
OMC
01 in Corp.
SM
Mobil Oil Corp., Mobil Chemical Co. Div.,
OPC
Orb is Products Corp.
Industrial Chemical Div.
ORO
Chevron Chemical Co.
SNA
Sun Chemical Corp., Ansbacher-Siegle Div.
ORT
Roehr Chemicals, Inc.
SNT
Suntide Refining Co.
OTA
Ferro Corp., Ottawa Chemical Div.
SOC
Standard Oil Co. of California, Chevron
OTC
Ott Chemical Co.
Chemical Co.
SOG
Charter International Oil Co.
PAS
Pennwalt Chemicals Corp.
STP
Stepan Chemical Co.
PAT
Morton International, Inc., Morton
STY
Styrochem Corp.
Chemical Co. Div.
SUN
Sun Oil Co.
PCC
USS Chemicals, Div. of U.S. Steel Corp.
SVT
Solvent Chemical Co., Inc.
PCR
Princeton Chemical Research, Inc.
SW
Sherwin-Williams Co.
PCW
Pfister Chemical, Inc.
SWC
Shell § Commonwealth Chemicals, Inc.
PD
Parke, Davis S Co.
PFZ
Pfizer, Inc.
TCD
Tenneco Chemicals, Inc., Tenneco Colors
PIT
Pitt-Consol Chemical Co.
TEN
Cities Service Co., Copperhill Operations
PLC
Phillips Petroleum Co.
TKL
Thiokol Chemical Corp.
PPC
Premier Petrochemical Co.
TMS
Sterling Drug, Inc., Thomasset Color Div.
PPG
PPG Industries, Inc.
TNA
Ethyl Corp.
PPR
Phillips Puerto Rico Core, Inc.
TOC
Tenneco Oil Co.
PRD
Productol Chemical Co., Inc.
TRC
Toms River Chemical Corp.
PTO
Puerto Rico Chemical Co., Inc.
TX
Texaco, Inc.
PTT
Petro-Tex Chemical Corp.
UCC
Union Carbide Corp.
QKO
Quaker Oats Co.
UOC
Union Oil Co. of California
UOP
Universal Oil Products Co., UOP Chemical
RBC
Roberts Chemicals, Div. of Security Chemicals,
Div.
Inc.
UPF
United States Pipe § Foundry Co.
RCI
Reichhold Chemicals, Inc.
UPJ
Upjohn Co.
RDA
Rhodia, Inc.
UPM
Universal Oil Products Co.
RH
Rohm 5 Haas Co.
USR
Uniroyal, Inc., Chemical Div.
RIL
Reilly Tar § Chemical Corp.
RPC
Millmaster Onyx Corp., Refined-Onyx
VAL
Valchem
Div.
VEL
Velsicol Chemical Corp.
RSA
R.S.A. Corp.
VGC
Virginia Chemicals, Inc.
RUC
Rubicon Chemicals, Inc.
VPC
Verona Corp.
SAL
Salsbury Laboratories
WAY
Philip A. Hunt Chemical Corp., Wayland
SAR
Sartomer Resins, Inc.
Chemical Div.
sec
Standard Chlorine of Delaware, Inc.
WCC
Witco Chemical Corp., Witfield Chemical
SCH
Schering Corp.
Div.
SCN
Schnectady Chemicals, Inc.
WHC
Whittaker Corp., Narmco Research §
SDC
Martin-Marietta Corp., Southern Dyestuff
Development Div.
Co. Div.
WIL
Wilson S Co., Inc., Wilson Laboratories
Sterling Drug, Inc.:
Div.
SDH
Hilton-Davis Chemical Co. Div.
WJ
Warner-Jenkison Manufacturing Co.
SDW
Winthrop Laboratories Div.
mc
Witco Chemical Co., Inc.
SEL
Selney Co. , Inc.
WYN
BASF - Wyandotte Corp.
Stauffer Chemical Co.:
WYT
Wyeth Laboratories, Inc., Wyeth Laboratories
SFA
Specialty Chemical Div.
Div. of American Home Products Corp.
SFI
Industrial Div.
SHC
Shell Oil Co., Shell Chemical Co. Div.
YAW
Young Aniline Works, Inc.
Note. --For complete names and addresses of the above reporting companies, refer to table 1 in the Appendix
DYES 55
Domestic synthetic dyes are derived in whole or in part from cyclic
intermediates. Approximately two-thirds of the dyes consumed in the
United States are used by the textile industry to dye natural and syn-
thetic fibers or fabrics; about one-sixth is used for coloring paper;
and the rest is used chiefly in the production of organic pigments
and in the dyeing of leather and plastics. Of the several thousand
different synthetic dyes that are known, more than one thousand are
manufactured by one or more domestic producers. The large number
of dyes results from the many different types of materials to which
dyes are applied, the different conditions of service for which dyes
are required, and the costs that a particular use can bear. Dyes are
sold as pastes, powders, lumps, and solutions; concentrations vary
from 6 percent to 100 percent. The concentration, form, and purity
of a dye are determined largely by the use for which it is intended.
Total domestic production of dyes in 1970 amounted to 235 million
pounds, or 2.4 percent less than the 240 million pounds produced in
1969 (table 1).^ Sales of dyes in 1970 amounted to 223 million pounds,
valued at $390 million, compared with 221 million pounds, valued at
$385 million, in 1969. In terms of quantity, sales of dyes in 1970
were 1.0 percent larger than in 1969 and in terms of value, 1.3 percent
larger. The average unit value of sales of all dyes in 1970 was $1.75
a pound, compared with $1.74 in 1969.
For many important dyes , production was larger in 1970 than in
1969. Acid Blue 9 production increased 75.9 percent, from 1,062,000
pounds in 1969 to 1,868,000 pounds in 1970; Basic Red 14 output in-
creased 45.9 percent, from 414,000 pounds in 1969 to 604,000 pounds
in 1970. Other important dyes whose output in 1970 was substantially
larger than in 1969 were Direct Yellow 44 (30.4 percent increase).
Disperse Blue 79 (22.1 percent increase), FD§C Red No. 2 (18.1 per-
cent increase). Vat Green 1 (17.3 percent increase), and Vat Yellow 2
(12.0 percent increase).
On the other hand, the output of several important dyes was
smaller in 1970 than in 1969. Production of Direct Yellow 106 was
983,000 pounds in 1970, or 48.5 percent less than the 1,909,000
pounds produced in 1969. Production of Direct Black 38 in 1970
was 4,125,000 pounds, or 32.5 percent less than the 6,112,000 pounds
produced in 1969. The output of Vat Yellow 4 was 59.1 percent
smaller in 1970 than in 1969; that of Disperse Yellow 3 was 28.3
percent smaller, that of Acid Yellow 151 was 25.0 percent smaller;
that of Vat Brown 3 was 19.1 percent smaller; and that of Direct
Blue 86 was 17.5 percent smaller.
^ See also table 2 of this report which lists these products and iden-
tifies the manufacturers by code; These codes are given in table 3.
56 SYNTHETIC ORGANIC CHEMICALS, 1970
Table lA summarizes production and sales of dyes in 1970 by class
of application. Five application classes of dyes accounted for approx-
imately three-fourths of all the dyes produced. Vat dyes accounted for
24.1 percent of the total; direct dyes, for 13.7 percent; fluorescent
brighteners , for 13.4 percent; disperse dyes, for 12.3 percent; and
acid dyes, for 9.8 percent. Of these five classes of dyes, the output
of fluorescent brighteners was 21.2 percent smaller in 1970 than in
1969; the output of direct dyes was 14.8 percent smaller; and the output
of acid dyes was 5.9 percent smaller. The output of vat dyes, however,
was 11.2 percent larger in 1970 than in 1969, and the output of dis-
perse dyes was 13.7 percent larger.
Of the remaining classes, the output of solvent dyes in 1970 was
2.4 percent more than the 1969 production; that of azoic compositions
was 2.5 percent larger in 1970 than in 1969; and that of food, drug,
and cosmetic colors was 2.1 percent larger in 1970. Production of
fiber-reactive dyes decreased 7.9 percent in 1970 from the 1969 output;
mordant dyes decreased 19.2 percent in 1970; and basic dye output in
1970 was 2.9 percent less than the 1969 output.
Table IB shows production and sales of dyes, by chemical class.
In 1970, three chemical classes of dyes accounted for about two-thirds
of all the dyes produced: Azo dyes accounted for 30.8 percent of the
total; anthraquinone dyes, for 22.2 percent; and stilbene dyes, for
13.6 percent. The output of the azo dyes was 4.5 percent smaller in
1970 than in 1969, that of the stilbene dyes was 22.1 percent smaller,
and that of the anthraquinone dyes, 0.2 percent larger. Of the remain-
ing chemical classes for which statistics are published, the output of
indigoid dyes was 43.8 percent larger in 1970 than in 1969; cyanine
dyes, 41.0 percent larger; oxazine dyes, 10.4 percent larger; methine
dyes, 8.0 percent larger; quinoline dyes, 7.6 percent larger; azoic
dyes and components, 7.6 percent larger; and triarylmethane dyes, 7.4
percent larger. On the other haiid, the output of thiazole dyes was
54.9 percent smaller in 1970 than in 1969; that of the nitro dyes was
22.7 percent smaller; that of the xanthene dyes was 20.0 percent
smaller; and that of the phthalocyanine dyes was 11.3 percent smaller.
57
Table 1. --Dyes: U.S. production and sales, 1970
[Listed below are all dyes for which any reported data on production or sales may be published. (Leaders are used
where the reported data are accepted in confidence and may not be published or where no data were reported.)
Table 2 lists all dyes for which data on production or sales were reported and identifies the manufacturers
of each]
Grand total
Total
Acid yellow dyes, total
Acid Yellow 11
Acid Yellow 17
Acid Yellow 23
Acid Yellow 34
Acid Yellow 36
Acid Yellow 40
Acid Yellow 42
Acid Yellow 44
Acid Yellow 54
Acid Yellow 76
Acid Yellow 99
Acid Yellow 124
Acid Yellow 151
Acid Yellow 159
All other
Acid orange dyes
Acid Orange 7
Acid Orange 8
Acid Orange 10
Acid Orange 24
Acid Orange 60
Acid Orange 74
Acid Orange 116
All other
Acid red dyes , total
Acid Red 1
Acid Red
Acid Red 14
Acid Red 18
Acid Red 26
Acid Red 37
Acid Red 73
Acid Red 85
Acid Red 88
Acid Red 89
Acid Red 99
Acid Red 114
Acid Red 115
Acid Red 119
Acid Red 137
Acid Red i51
Acid Red 182
Acid Red 186
All other —
Acid violet dyes, total
Acid Violet 1
Acid Violet 3
Acid Violet 7
See footnote
SYNTHETIC ORGANIC CHEMICALS, 1970
Table 1.-- Dyes: U.S. production and sales, 1970 — Continued
Dye
Quantity
ACID DYES--Continued
Acid violet dyes — Continued
Acid Violet 12
Acid Violet 49
All other
Acid blue dyes, total
Acid Blue 7
Acid Blue 9
Acid Blue 25
Acid Blue 27
Acid Blue 40
Acid Blue 41
Acid Blue 45
Acid Blue 62
Acid Blue 78
Acid Blue 113
Acid Blue 118
Acid Blue 120
Acid Blue 158 and 158A
Acid Blue 230
All other
Acid green dyes, total
Acid Green 1
Acid Green 3
Acid Green 9
Acid Green 16
Acid Green 20
Acid Green 25
All other
Acid brown dyes, total
Acid Brown 14
All other
Acid black dyes, total
Acid Black 1
Acid Black 24
Acid Black 48
Acid Black 52
Acid Black 60
Acid Black 107
All other
AZOIC DYES AND COMPONENTS
1,000
pounds
133
24
393
36
19
623
48
297
175
789
726
558
114
279
1,560
1,000
pounds
101
131
31
1,045
215
87
110
44
462
585
52
37
1,148
154
11
343
170
819
756
66
11
646
116
252
1,551
1,000
dollars
257
458
11,974
119
1,397
1,249
342
483
181
1,433
181
226
1,225
102
41
199
245
4,551
2,361
244
43
239
111
1,078
576
3,666
1,409
2,257
6,584
1,292
123
64
1,150
414
673
2,668
Azova Compositions
Total
Azoic Yellow 2
Azoic Orange 3
Azoic Red 1
Azoic Red 2
Azoic Red 6
Azoic Blue 3
Azoic Brown 9
Azoic black dyes
All other azoic compositions
2,632
120
479
77
213
263
266
725
440
1,874
201
198
710
737
41
365
320
1,412
1,565
See footnotes at end of table.
DYES
59
Table 1.-- Dyes: U.S. production and sales, 1970- -Continued
Dye
Quantity
Unit
Value'
AZOIC DYES AND COMPONENTS--Continued
Azoic Diazo Components , Bases,
(Fast Color Bases)
Total
Azoic Diazo Component 4, base
Azoic Diazo Component 10, baise
Azoic Diazo Component 12, base
Azoic Diazo Component 32, base
All other azoic diazo components, bases
Azoic Diazo Components, Salts
(Fast Color Salts)
1,000
Total-
Azoic Diazo Component 1, salt
Azoic Diazo Component 3, salt
Azoic Diazo Component 5, salt
Azoic Diazo Component 6, salt
Azoic Diazo Component 8, salt
Azoic Diazo Component 9, salt
Azoic Diazo Component 10, salt
Azoic Diazo Component 11, salt
Azoic Diazo Component 12, salt
Azoic Diazo Component 13, salt
Azoic Diazo Component 28, salt
Azoic Diazo Component 44, salt
Azoic Diazo Component 48, salt
Azoic Diazo Component 49, salt
All other azoic diazo components, salts-
Azoic Coupling Components
(Naphthol AS and Derivatives)
Total-
Azoic Coupling Component 4
Azoic Coupling Component 7
Azoic Coupling Component 8
Azoic Coupling Component 14
Azoic Coupling Component 18
Azoic Coupling Component 29
Azoic Coupling Component 34
Azoic Coupling Component 43
All other azoic coupling components-
BASIC DYES
Total-
Basic yellow dyes, total -
Basic Yellow 11
Basic Yellow 13
All other
Basic orange dyes, total-
Basic Orange 1
Basic Orange 2
Basic Orange 21
All other
1,389
281
294
703
60
177
315
294
178
2,206
23
653
1,278
3,657
1,096
121
2,440
225
393
838
136
1,000
pounds
221
207
417
2,531
43
544
108
247
30
26
386
326
191
1,522
376
9
13,931
3,406
1,032
97
2,277
1,678
276
449
788
165
1,000
dollars
254
329
680
2,616
348
134
87
165
440
231
173
271
615
60
27
1,730
10,102
3,792
248
6,062
3,770
380
673
2,116
601
Per
pound
$1.48
1.15
1.59
1.63
1.24
.95
.67
1.50
1.35
1.14
.71
.91
1.67
.83
2.77
1.46
2.00
3.33
1.15
2.17
1.88
2.70
2.13
1.50
2.69
3.64
See footnotes at end of table.
SYNTHETIC ORGANIC CHEMICALS, 1970
Table 1. — Dyes: U.S. production and sales, 1970- -Continued
Dye
Production
Quantity
Unit
value'
BASIC DYES--Continued
asic red dyes, total-
Basic Red 9
Basic Red 13
Basic Red 14
Basic Red 18
All other
Basic violet dyes, total-
Basic Violet 1
Basic Violet 4
Basic Violet 10
Basic Violet 16
All other
Basic blue dyes, total -
Basic Blue 1
Basic Blue 5
All other
Basic Green 1
Basic Green 4
Basic Brown 1
Basic Brown 4
All other basic dyes-
DIRECT DYES
Total-
Direct yellow dyes, total-
Direct Yellow 4
Direct Yellow 5
Direct Yellow 6
Direct Yellow 11
Direct Yellow 12
Direct Yellow 26
Direct Yellow 28
Direct Yellow 29
Direct Yellow 44
Direct Yellow SO
Direct Yellow 84
Direct Yellow 105
Direct Yellow 106
All other
Direct orange dyes, total-
Direct Orange 1
Direct Orange 8
Direct Orange IS
Direct Orange 26
Direct Orange 29
Direct Orange 34
Direct Orange 37
Direct Orange 39
Direct Orange 72
Direct Orange 73
Direct Orange 81
Direct Orange 102
All other
1,000
pounds
2,208
604
232
1,338
3,328
171
281
1,4S6
2,343
2,23S
176
469
S31
199
493
,614
210
1,219
369
1,019
983
2,869
2.067
1,499
2,970
207
2S3
1,399
2.285
152
648
156
482
87
32,577
10,685
25
144
181
34
174
417
102
218
411
486
222
479
2,582
230
10
189
66
1,193
397
1,007
241
1,088
2,495
1,978
138
202
160
394
112
87
248
300
1,000
dollars
63
137
1,388
4,971
973
798
3,385
368
103
6,833
564
1,698
238
691
214
19,044
960
637
844
2,815
763
28
395
161
2,175
842
1,753
550
1,897
5,224
4.950
63
230
257
116
343
243
84
362
875
481
242
698
956
Per
pound
3.71
3.04
2.74
4.70
3.15
2.42
3.79
6.06
3.15
3.71
2.62
1.53
1.43
2.46
1.78
1.98
2.87
1.76
1.09
3.32
2.80
2.09
2.44
1.82
2.12
1.74
2.28
1.74
1.67
1.27
2.33
2.26
See footnotes at end of table.
DYES
61
Table 1.-- Dyes: U.S. production and sales, 19 70- -Continued
Dye
Quantity
DIRECT DYES- -Continued
Direct red dyes, total
Direct Red 1
Direct Red 2
Direct Red 4
Direct Red 10
Direct Red 13
Direct Red 16
Direct Red 23
Direct Red 24
Direct Red 26
Direct Red 28
Direct Red 31
Direct Red 37
Direct Red 39
Direct Red 72
Direct Red 75
Direct Red 79
Direct Red 80
Direct Red 81
Direct Red 83
Direct Red 122
Direct Red 149
All other
Direct violet dyes, total -
Direct Violet 1
Direct Violet 7
Direct Violet 9
Direct Violet 51
All other
Direct blue dyes, total —
Direct Blue 1
Direct Blue 2
Direct Blue 6
Direct Blue 8
Direct Blue 15
Direct Blue 22
Direct Blue 24
Direct Blue 25
Direct Blue 67
Direct Blue 71
Direct Blue 76
Direct Blue 78
Direct Blue 80
Direct Blue 86
Direct Blue 98
Direct Blue 120 and 120A
Direct Blue 126
Direct Blue 218
All other
Direct green dyes, total--
Direct Green 1
Direct Green 6
All other
Direct brown dyes, total--
Direct Brown 1
Direct Brown lA
Direct Brown 2
Direct Brown 31
1,000
119
169
142
283
51
225
25
104
69
272
11
114
521
493
140
14
117
119
374
1,028
531
70
72
556
851
168
118
142
1,397
1,258
186
479
163
1,000
3,508
154
214
36
117
186
311
66
212
478
131
23
447
6,501
220
114
331
1,009
477
75
88
560
816
140
185
151
1,113
1,263
932
201
500
231
1,000
dollars
278
453
105
15
104
239
486
628
173
318
39
307
272
611
41
247
871
1,211
209
46
63
1,164
680
1,024
342
78
225
32
9
138
55
159
120
285
927
1,259
272
454
485
2,193
1,871
2,057
248
708
1,101
229
145
139
367
443
See footnotes at end of table.
SYNTHETIC ORGANIC CHEMICALS, 1970
Table 1. — Dyes: U.S. production and sales, 1970- -Continued
Dye
Production
DIRECT DYES--Continued
Direct brown dyes- -Continued
Direct Brown 74
Direct Brown 95
Direct Brown 111
Direct Brown 154
All other
Direct black dyes, total
Direct Black 4
Direct Black 9
Direct Black 22
Direct Black 38
Direct Black 51
Direct Black 80
All other
DISPERSE DYES
Total
Disperse yellow dyes, total
Disperse Yellow 3
Disperse Yellow 5
Disperse Yellow 23
Disperse Yellow 33
Disperse Yellow 34
Disperse Yellow 42
Disperse Yellow 54
All other
Disperse orange dyes, total
Disperse Orange 3
Disperse Orange 5
Disperse Orange 17
Disperse Orange 25
All other
Disperse red dyes, total
Disperse Red 1
Disperse Red 5
Disperse Red 11
Disperse Red 13
Disperse Red 15
Disperse Red 17
Disperse Red 55
Disperse Red 60
Disperse Red 65
All other
Disperse violet dyes, total
Disperse Violet 1
Disperse Violet 4
Disperse Violet 27
All other
Disperse blue dyes, total
Disperse Blue 1
Disperse Blue 3
Disperse Blue 7
Disperse Blue 64
Disperse Blue 79
All other
1,000
pounds
309
207
539
4,125
28,936
1,870
1,019
234
234
1,038
690
1,801
4,072
142
201
246
406
3,077
4,098
234
437
129
557
591
1,707
481
238
1,433
6,688
1,000
pounds
308
267
6,855
708
640
25,460
6,334
1,916
36
955
269
208
938
bll
1,335
3,114
142
182
205
323
,262
791
78
126
444
9,904
VIT
1,568
378
190
1,372
5,973
1,000
dollars
691
264
331
457
361
3,291
195
698
1,044
65.705
12,932
2,806
130
1,728
414
338
1,685
2,522
3,309
5,558
246
420
225
334
24
212
263
2,751
154
7,560
2,370
366
114
224
1,666
29,965
1,751
2,496
2,668
339
4,922
17,789
See footnotes at end of table.
DYES
63
Table 1.-- Dyes: U.S. production and sales, 1970- -Continued
Dye
DISPERSE DYES--Continued
Disperse black dyes, total
Disperse Black 1
All other
All other disperse dyes
FIBER-REACTIVE DYES
Fiber-reactive dyes, total
Reactive yellow dyes
Reactive blue dyes
Reactive black dyes
All other reactive dyes
FLUORESCENT BRIGHTENING AGENTS
Total
Fluorescent Brightening Agent 28
All other fluorescent brightening agents
FOOD, DRUG, AND COSMETIC COLORS
Total
Food, Drug, and Cosmetic Dyes
Total
FD5C Blue No. 1
FD§C Blue No. 2
FDSC Red No. 2
FD8C Red No. 3
FDSC Red No. 4
FD§C Violet No. 1
FD5C Yellow No. 5
FD§C Yellow No. 6
All other food, drug, and cosmetic dyes
Drug and Cosmetic and External Drug
and Cosmetic Dyes
Total
D§C Green dyes
D§C Red dyes, total
D§C Red No. 7
DSC Red No. 9
D§C Red No. 12
DSC Red No. 19
DSC Red No. 21
DSC Red No. 36
All other
DSC Yellow No. 5
All other drug S cosmetic and external drug S
cosmetic dyes
1,000
pounds
238
1,284
2,235
253
626
171
1,185
1,593
29,731
4,118
1,430
225
1,239
1,013
Quantity
1,000
pounds
1,401
237
1,164
340
2,683
171
1,303
1,417
29,880
4,200
3,969
1,347
200
1,207
1,005
42
30
134
1,000
do I lars
11,728
1,727
4,403
564
5,034
51,456
2,125
49,331
13,416
1,045
294
3,694
1,857
86
126
3,259
2,702
353
385
665
27
442
See footnotes at end of table.
SYNTHETIC ORGANIC CHEMICALS, 1970
Table 1.- -Dyes: U.S. production and sales, 1970- -Continued
Dye
Quantity
MORDANT DYES
Total
Mordant yellow dyes, total
Mordant Yellow 1
Mordant Yellow 8
All other
Mordant orange dyes
Mordant red dyes
Mordant brown dyes, total
Mordant Broim 1
Mordant Brown 33
Mordant Brown 40
All other
Mordant black dyes, total
Mordant Black 11
Mordant Black 17
All other
All other mordant dyes
SOLVENT DYES
Total
Solvent yellow dyes, total
Solvent Yellow 2
Solvent Yellow 3
Solvent Yellow 14
All other
Solvent orange dyes, total
Solvent Orange 3
Solvent Orange 7
All other
Solvent red dyes, total
Solvent Red 26
Solvent Red 49
All other
Solvent violet dyes
Solvent Blue 38
Solvent Green 3
Solvent Brown 12
All other solvent dyes
1,000
pounds
1,823
135
203
87
233
754
281
1,136
636
478
510
2,392
222
53
2,117
267
61
1,000
pounds
1,818
767
278
1,170
700
416
459
2.579
246
52
2,281
254
6,465
1,000
dollars
290
214
102
123
955
287
169
863
1,617
69
131
990
520
346
3,800
621
437
230
See footnotes at end of table.
DYES
Table 1.-- Dyes: U.S. production and sales , 1970- -Continued
65
Dye
Quantity
Unit
value'
1,000
Total
Vat yellow dyes, total--
Vat Yellow 2, S-1/2--
Vat Yellow 4, 12-1/2-
All other
Vat orange dyes, total--
Vat Orange 1, 20%
Vat Orange 2, 12%
Vat Orange 9, 12%
Vat Orange 15, 10%
All other
Vat red dyes, total
Vat Red 1, 13%
Vat Red 13, 11%
Vat Red 32, 20%
All other
Vat violet dyes, total--
Vat Violet 1, 11%
Vat Violet 9, 12%
Vat Violet 13, 6-1/4%-
All other
Vat blue dyes, total
Vat Blue 4, 10%
Vat Blue 6, 8-1/3%
Vat Blue 18, 13%
All other
Vat green dyes, total--
Vat Green 1, 6%
Vat Green 3, 10%
Vat Green 9, 12-1/2%-
All other
Vat brown dyes, total —
Vat Brown 1, 11%
Vat Brown 3, 11%
All other
Vat black dyes, total--
Vat Black 25, 12-1/2%
Vat Black 27, 12-1/2%
All other
All other dyes^
6,255
3,650
762
1,843
4,215
1,672
864
330
521
828
1.599
821
124
141
443
3,236
1,016
19,232
10,276
4,303
3,780
744
1,449
3.979
514
879
2,586
1,000
pounds
55,382
5.538
3,204
760
1,574
1,661
644
192
507
821
1,410
613
107
170
92
213
120
22,551
3,151
863
18,461
9,818
4,664
3,023
979
1,152
4,046
579
950
2,517
5,619
3,113
2,824
768
783
1,908
2,012
18,226
2^000
8,610
3,156
836
4,618
10,137
4,618
1,260
438
1,379
2,442
2,687
1,103
367
217
1,000
1,439
509
326
275
329
14,188
122
3,905
1,645
8,516
8,205
3,274
2,935
853
1,143
7,299
811
1,688
4,800
2,419
1,091
2,216
12,046
Per
pound
2.72
2.97
3.43
4.02
1.57
2.99
3.54
2.74
.63
2.18
1.24
1.91
.46
.97
.87
.99
1.80
1.40
1.78
1.91
1.02
1.39
1.10
Calculated from rounded figures.
^ Includes oxidation bases, ingrain dyes, sulfur dyes, and miscellaneous dyes. Statistics for these groups of
dyes may not be published separately because publication would disclose information received in confidence.
66
SYNTHETIC ORGANIC CHEMICALS, 1970
Table LA. — Dyes: U.S. production and sales, by class of application, 1970
Class of application
Quantity
Unit
value'
Total
Acid
Azoic dyes and components:
Azoic compositions
Azoic diazo components, bases (Fast color bases) —
Azoic diazo components, salts (Fast color salts) —
Azoic coupling components (Naphthol AS derivatives)
Basic
Direct
Disperse
Fiber-reactive
Fluorescent brightening agents
Food, drug, and cosmetic colors
Mordant
Solvent
Vat
All other^
1,000
■pounds
234.526
1,000
pounds
23,088
2,632
1,389
2,055
2,206
14,461
32,246
28,936
2,235
31,324
4,352
1,823
11,464
56,464
19,851
21,553
1,874
957
2,531
1,522
13,931
32,577
25,460
2,683
31,297
4,200
1,818
11,207
53,382
18,226
1,000
dollca's
50,752
3,703
1,421
2,616
2,959
38,115
54,035
65,705
11,728
51,456
14,926
2,853
19,823
58,291
12,046
Per
pound
2.35
1.98
1.48
1.03
1.94
2.74
1.66
2.58
4.37
1.64
3.55
1.57
1.77
1.09
.66
Calculated from rounded figures.
^ Includes oxidation bases, ingrain dyes, sulfur dyes, and miscellaneous dyes. Statistics for these groups of
dyes may not be published separately because publication would disclose information received in confidence.
Table IB. — Dyes: U.S. production and sales, by chemical class, 1970
Chemical class
Quantity
Unit
value
1,000
Total---
Anthraquinone —
Azo, total
Monazo
Disazo
Trisazo
Polyazo
Not specified-
Azoic
Cyanine
Indigoid
Methine
Nitro
Oxazine
Phthalocyanine--
Quinoline
Stilbene
Thiazole
Triarylmethane--
Xanthene
All other^
51,965
72.166
30,234
23,590
7,964
2,033
8,345
8,282
725
7,507
3,251
1,739
393
1,755
1,735
31,927
237
7,964
1,105
43,775
1,000
pounds
48,855
69,846
28,531
23,205
8,646
2,009
7,455
6,884
603
6,603
2,982
1,633
406
1,914
1,642
31,450
329
7,218
844
42,009
1,000
dollars
390,429
141,501
66,616
45,645
9,664
3,296
16,280
10,699
1,636
3,552
9,539
2,847
1,489
5,286
5,370
44,084
880
17,377
5,110
41,398
Per
pound
$1.75
2.04
2.03
2.33
1.97
1.12
1.64
2.18
1.55
2.71
.54
3.20
1.74
3.66
2.76
3.27
1.40
2.67
2.41
6.05
.99
' Calculated from rounded figures.
^ Includes production and sales of acridine, aminoketone, azine, coumarin, indophenol, ketone imine, nitroso,
oxazole, oxidation bases, sulfur, thiazine, and miscellaneous dyes. Statistics for these groups of dyes may not
be published separately because publication would disclose information received in confidence.
DYES
67
Table 2.-
-Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970
[Dyes for which separate statistics are given in table 1 are marked below with an asterisk (*;i ; dyes not so marked
do not appear in table 1 because the reported data are accepted in confidence and may not be published. Manu-
facturers' identification codes shown below are taken from table 3. An x signifies that the manufacturer did not
consent to his identification with the designated product]
Dye
Manufacturers ' identification codes
(according to list in table 3)
I
ACID DYES
*Acid yellow dyes:
Acid Yellow 1
Acid Yellow 3
Acid Yellow 4
*Acid Yellow 11
Acid Yellow 14
*Acid Yellow 17
*Acid Yellow 23
Acid Yellow 25
Acid Yellow 29
*Acid Yellow 34
*Acid Yellow 36
Acid Yellow 38
*Acid Yellow 40
*Acid Yellow 42
*Acid Yellow 44
Acid Yellow 49
*Acid Yellow 54
Acid Yellow 59
Acid Yellow 63
Acid Yellow 65
Acid Yellow 73
*Acid Yellow 76
Acid Yellow 79
*Acid Yellow 99
Acid Yellow 114
Acid Yellow 121
*Acid Yellow 124
Acid Yellow 127
Acid Yellow 128
Acid Yellow 129
Acid Yellow 135
*Acid Yellow 151
Acid Yellow 152
*Acid Yellow 159
Acid Yellow 174
Acid Yellow 175
Acid Yellow 181
Other acid yellow dyes
*Acid orange dyes :
Acid Orange 1
Acid Orange 2
Acid Orange 4
Acid Orange 6
*Acid Orange 7
*Acid Orange 8
*Acid Orange 10
Acid Orange 11
Acid Orange 12
Acid Orange 19
*Acid Orange 24
Acid Orange 31
Acid Orange 45
Acid Orange 51
Acid Orange 52
Acid Orange 56
*Acid Orange 60
Acid Orange 62
ACY.
ACS,
SDH.
ATL,
TRC.
ACS,
AAP,
GAP.
GAP,
ACS,
ACS,
ACS,
ALT,
AAP,
AAP,
VPC.
ACS,
VPC.
AAP,
ACS,
ACS,
ACS,
VPC.
ACS,
CMG,
GAP.
ACS,
TRC.
ALT,
TRC.
GAP.
ACY,
ACY.
ACS,
DUP.
DUP.
GAP.
ACY,
GAP,
ACS.
ACY.
ACS.
AAP,
ACS,
ACS,
SDH.
ACS.
GAP.
ACS,
AAP.
ACS,
CMG,
ACS,
GAP.
CMG,
TRC.
ACY.
EDO,
ACY,
ACS,
TRC.
ATL,
DUP,
GAP.
ATL,
ACY,
GAP,
ATL, EDO, CMG, DUP, PDC, SDH, TCD, TRC, VPC.
ACY, GAP, MRX, PDC, TRC, VPC, WJ, YAW.
PDC.
GAP, TRC.
DUP, TRC, VPC.
GAP, VPC.
VPC.
ACY, CMG, GAP, TCD, TRC, VPC.
ACS.
ALT,
DUP,
GAP,
CMG,
TRC.
ATL,
TRC.
PAE, TRC.
SDH.
TRC.
GAP, TRC, VPC.
DUP, TCD.
ATL, DUP, PAS, GAP, TCD, TRC, VPC.
ALT, FAB, GAP, TRC.
ALT, CMG, DUP, GAP, TRC, VPC.
TCD.
ACS, ACY, ATL, CPC, GAP, PDC, TCD, TRC, YAW.
ACY, ATL, DUP, GAP, TCD, TRC.
ACY, ATL, DUP, GAP, PDC, TRC, VPC, YAW.
ACY, DUP, GAP, TRC, YAW.
TRC.
DUP, TRC.
ATL.
DUP, GAP, TCD, TRC.
SYNTHETIC ORGANIC CHEMICALS, 1970
Table 2.
-Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
ACID DYES--Continued
*Acid orange dyes--Continued
Acid Orange 63
Acid Orange 64
Acid Orange 69
Acid Orange 72
*Acid Orange 74
Acid Orange 76
Acid Orange 85
Acid Orange 86
*Acid Orange 116
Acid Orange 119
Acid Orange 128
Acid Orange 132
Other acid orange dyes
*Acid red dyes :
*Acid Red 1
*Acid Red 4
*Acid Red 14
Acid Red 17
*Acid Red 18
.*Acid Red 26
Acid Red 27
Acid Red 32
Acid Red 33
Acid Red 35
*Acid Red 37
Acid Red 42
Acid Red 52
Acid Red 57
Acid Red 66
*Acid Red 73
Acid Red 80
*Acid Red 85
Acid Red 87
*Acid Red 88
*Acid Red 89
Acid Red 97
*Acid Red 99
Acid Red 100
Acid Red 104
Acid Red 106
Acid Red 111
*Acid Red 114
*Acid Red 115
*Acid Red 119
Acid Red 133
Acid Red 134
*Acid Red 137
Acid Red 138
*Acid Red 151
Acid Red 167
Acid Red 175
Acid Red 178
Acid Red 179
*Acid Red 182
Acid Red 183
*Acid Red 186
Acid Red 191
Acid Red 194
Acid Red 201
Acid Red 207
Acid Red 211
Acid Red 212
Acid Red 213
Acid Red 217
Acid Red 266
GAF
ACS
ACY
GAF
ACS
ACS
ACS
ACS
ACS
TRC
DUP
DUP
ALT
ACS
AAP
ACS
ACS
ACS
ACS
ACS
GAF
YAK
AAP
ATL
CMG
GAF
ATL
AAP
ACS
GAF
ACS
SDH
ACS
AAP
ATL
ATL
VPC
AAP
YAW
ATL
ACS
ACS
ACS
GAF
TRC
ACS
ALT
AAP
ACS
DUP
DUP
CMG
ACS
CMG
ATL
TRC
TRC
TRC
ACS
DUP
TRC
TRC
ALT
DUP
TRC.
ACY, DUP.
CMG, GAF, TRC.
TRC.
ALT, TRC.
ALT, FAB, GAF, TCD, TRC, YAW.
TRC, VPC.
ACY, ATL, BDO, DUP, GAF, SDH, TCD, TRC, VPC, YAW.
ATL, BDO, CMG, DUP, GAF, PDC, TRC, VPC, YAW.
ATL, GAF, PDC, YAW.
ATL, TRC.
ATL, BDO, GAF, PDC, TRC.
ACY, ATL, CPC.
GAF.
CMG, DUP, GAF, TCD, TRC.
GAF.
TRC.
ATL, YAW.
ACY, ATL, DUP, GAF, PSC, TRC, YAW.
ICI.
ACY, ATL, DUP, GAF, PDC, TCD, TRC, VPC, YAW.
ACY, ATL, DUP, GAF, TRC, SDH, YAW.
ATL, BDO, GAF, VPC.
GAF.
CMG, FAB, TCD, TRC, YAW.
ALT, ATL, DUP, GAF, PDC, TRC, VPC.
ATL, GAF.
ALT, ATL.
ATL, DUP, GAF, TRC.
ACY, ALT, ATL, DUP, TCD, TRC, VPC, YAW.
ATL, DUP, TRC.
ACY, BDO, CMG, DUP, GAF, TCD.
TRC.
CMG, GAF, VPC.
DYES
Table 2. --Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Dye
ACID DYES- -Continued
'^Acid red dyes--Continued
Acid Red 292
Acid Red 299
Acid Red 309
Acid Red 337
Other acid red dyes
*Acid violet dyes :
*Acid Violet 1
*Acid Violet 3
*Acid Violet 7
*Acid Violet 12
Acid Violet 17
Acid Violet 29
Acid Violet 34
Acid Violet 41
Acid Violet 43
*Acid Violet 49
Acid Violet 56
Acid Violet 76
Other acid violet dyes
*Acid blue dyes :
Acid Blue 1
*Acid Blue 7
*Acid Blue 9
Acid Blue 10
Acid Blue 15
Acid Blue 20
Acid Blue 23
*Acid Blue 25
*Acid Blue 27
Acid Blue 29
Acid Blue 34
*Acid Blue 40
*Acid Blue 41
Acid Blue 43
*Acid Blue 45
Acid Blue 47
Acid Blue 48
Acid Blue 58
*Acid Blue 62
Acid Blue 67 '
Acid Blue 69
Acid Blue 74
*Acid Blue 78
Acid Blue 80
Acid Blue 81
Acid Blue 83
Acid Blue 89
Acid Blue 90
Acid Blue 92
Acid Blue 93
Acid Blue 102
Acid Blue 104
*Acid Blue 113
*Acid Blue 118
*Acid Blue 120
Acid Blue 122
Acid Blue 145
*Acid Blue 158 and 158A
Acid Blue 165
Acid Blue 179
Acid Blue 198
Acid Blue 203
Acid Blue 221
*Acid Blue 230
Acid Blue 231
Manufacturers' identification codes
[according to list in table 3)
ACY.
ALT,
TRC.
DUP.
ALT,
CMC, DUP, GAP, TCD, TRC, VPC.
BDO
CMG
GAP
ACS
ACY
CMG
TRC
YAW
AAP
ACS
ATL
BDO
CMG
GAP
TRC
VPC.
BDO
CMG
DUP
GAP
DUP
GAP
SDH
HSH
DUP
ICI
CMC
HSH
ICI
ACS
ACY
SDH
TRC
CMC
GAP
ACS
TRC
ACS,
GAP
ACS
ACY
GAP,
SDH
ACS,
ACY
GAP,
SDH.
ACS.
GAP.
ACS.
ACS,
TRC.
ACS,
ATL,
BDO,
CMG,
DUP,
GAP,
TCD,
TRC, VPC.
ALT,
ATL,
BDO,
GAP.
YAW.
ACS.
ACS,
ALT,
ATL,
BDO,
DUP,
GAP,
ICI,
TRC.
ACS,
ATL,
BDO,
CMG,
GAP.
ACY,
TRC.
ACS,
ACY,
ATL,
CMG,
DUP,
GAP,
TCD,
TRC.
ICI.
HSC.
DUP.
ACS,
ALT,
BDO,
GAP,
VPC.
CMC.
GAP.
ACS,
DUP.
ACS,
ATL,
BDO,
DUP,
GAP,
ICI,
TRC.
ACS,
ATL,
TRC.
ICI.
GAP.
ACS.
TRC.
ACS,
YAW.
ACY,
HSC.
TRC.
ACS,
GAP.
ACS,
ALT,
TRC,
ATL,
YAW.
BDO,
CMG,
DUP,
PAB,
GAP, PDC, TCD
ACS,
ATL,
TCD.
ACS,
ATL,
GAP.
DUP.
ACS,
DUP.
ACS,
BDO,
GAP,
TCD,
TRC,
VPC.
DUP.
GAP.
VPC.
VPC.
VPC.
ACS,
DUP',
TRC.
TRC.
70
SYNTHETIC ORGANIC CHEMICAI5, 1970
Table 2. --Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Dyes
Manufacturers ' identification codes
(according to list in table 3)
ACID DYES--Continued
*Acid blue dyes — Continued
Acid Blue' 232
Acid Blue 255
Acid Blue 264
Other acid blue dyes
*Acid green dyes :
*Acid Green 1
*Acid Green 3
Acid Green 5
*Acid Green 9
Acid Green 12
*Acid Green 16
*Acid Green 20
Acid Green 22
*Acid Green 25
Acid Green 35
Acid Green 41
Acid Green 50
Acid Green 58
Acid Green 70
Acid Green 84
Other acid green dyes
*Acid brown dyes:
Acid Brown 1
Acid Brown 6
*Acid Brown 14
Acid Brown 19
Acid Brown 22
Acid Brown 28
Acid Brown 29
Acid Brown 31
Acid Brown 45
Acid Brown 96
Acid Brown 97
Acid Brown 98
Acid Brown 152
Acid Brown 158
Acid Brown 223
Acid Brown 243
Other acid brown dyes
*Acid black dyes:
*Acid Black 1
Acid Black 2
Acid Black 12
*Acid Black 24
Acid Black 26, 26A and 26B
Acid Black 29
*Acid Black 48
*Acid Black 52
Acid Black 58
*Acid Black 60
Acid Black 92
*Acid Black 107
Acid Black 108
Acid Black 138
Other acid black dyes
A201C DYES AND COMPONENTS
Azoia Compositions
Azoic yellow dyes:
Azoic Yellow 1
*Azoic Yellow 2
Azoic Yellow 3
ALT, ATL, CMC, GAP, TCD, TRC, VPC.
ACY, DUP.
ACY, GAP, TRC.
ACY, GAP.
GAP.
GAP, SDH, TRC.
ATL, EDO, GAP, PDC, TRC.
ALT, ATL, CMG, GAP, HSH, ICI, TRC, VPC.
VPC.
GAP.
VPC
DUP
VPC
ACY
ACS
ACS
GAP
ACS
ACS
ACS
ACS
GAP
ACS
TRC
ICI
ACY
TRC
TRC
VPC
ALT
GAP
GAP
AAP
TRC
DUP
TRC
DUP
GAP
TRC
ACY
ACY
ACY
GAP
GAP
GAP
GAP
ALT
AAP
ACS
ACS
ACS
ATL
GAP
ACY
ACS
DUP
BDO
ACY
ACS
GAP
VPC
ALT
ALL, ATL.
ATL, BUG,
ATL.
ACS, ACY, DUP, GAP, TRC, YAW.
CMG, DUP, GAP, VPC.
ACS, ACY, ATL, DUP, GAP, PDC, TCD, TRC, YAW.
ACY.
CMG, DUP, GAP.
DUP, TRC.
ICI, TRC.
ATL, DUP, GAP, TCD, TRC.
TRC.
OIG, TRC.
DUP, GAP, TRC.
DYES
71
Table 2. --Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970— Continued
AZOIC DYES AND COMPONENTS— Continued
Azoia Compositions — Continued
Azoic orange dyes :
*Azoic Orange 3
Azoic Orange 4
Azoic Orange 10
Azoic red dyes :
*Azoic Red 1
*Azoic Red 2
*Azoic Red 6
Azoic Red 12
Azoic Red 16
Azoic Red 73
Azoic Red 74
Other azoic red dyes
Azoic violet dyes:
Azoic Violet 1
Other azoic violet dyes
Azoic blue dyes :
Azoic Blue 2
*Azoic Blue 3
Azoic Blue 6
Azoic Blue 7
Azoic Blue 8
Other azoic blue dyes
Azoic green dyes:
Azoic Green 1
Other azoic green dyes
Azoic brown dyes :
Azoic Brown 3
Azoic Brown 7
*Azoic Brown 9
Azoic Brown 10
Azoic Brown 26
Other azoic brown dyes
*Azoic black dyes :
Azoic Black 1
Azoic Black 4
Azoic Black 15
Other azoic black dyes
Azoia Uiazo Components, Bases
(Fast Color Bases)
Azoic Diazo Component 2, base
Azoic Diazo Component 3, base
*Azoic Diazo Component 4, base
Azoic Diazo Component S, base
Azoic Diazo Component 8, base
Azoic Diazo Component 9, base
*Azoic Diazo Component 10, base
Azoic Diazo Component 11, base
*Azoic Diazo Component 12, base
Azoic Diazo Component 13, base
Azoic Diazo Component 14, base
Azoic Diazo Component 20, base —
Azoic Diazo Component 28, base
*Azoic Diazo Component 32, base
Azoic Diazo Component 42, base
Azoic Diazo Component 44, base
Azoic Diazo Component 46, base
Azoic Diazo Component 48, base
Manufacturers' identification codes
(according to list in table 3}
ALL
ATL
BUC
GAP
X.
GAP.
BUC.
ALL,
ATL
BUC,
X.
ALL,
ATL,
BUC,
GAP
X.
ALL,
ATL
BUC,
X.
ATL.
ATL.
GAP.
GAP.
ALL,
X.
ATL,
BUC,
GAP.
ALL.
ATL.
ALL,
ATL,
BUC,
GAP,
HST,
ATL,
GAP.
ATL,
GAP.
ALL
ALL.
ATL.
ALL,
BUC,
VPC.
X.
BUC.
ALL,
BUC,
GAP,
HST,
VPC,
BUC.
GAP.
ALL,
GAP,
VPC.
HST.
ATL,
BUC,
GAP.
GAP.
ALL,
GAP,
VPC.
ATL,
BUC.
ALL,
GAP.
SDH.
VPC.
ALL.
PCW.
BUC,
BUC.
AAP.
ALL,
ALL,
AAP,
PCW.
BUC.
ATL.
CWN,
BUC.
BUC, GAP, SDH.
BUC, GAP.
PCW, SDH.
GAP.
BUC.
ALL, ATL, BUC, DUP.
72
SYNTHETIC ORGANIC CHEMICALS, 1970
--Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
AZOIC DYES AND COMPONENTS- -Continued
Asoia Diazo Components, Salts
(Fast Color Salts)
*Azoic Diazo
Azoic Diazo
*Azoic Diazo
Azoic Diazo
*Azoic Diazo
*Azoic Diazo
*Azoic Diazo
*Azoic Diazo
*Azoic Diazo
*Azoic Diazo
* Azoic Diazo
*Azoic Diazo
Azoic Diazo
Azoic Diazo
*Azoic Diazo
Azoic Diazo
Azoic Diazo
Azoic Diazo
Azoic Diazo
Azoic Diazo
Azoic Diazo
Azoic Diazo
Azoic Diazo
*Azoic Diazo
*Azoic Diazo
*Azoic Diazo
Azoic Diazo
Azoic Diazo
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
Component
1, salt- —
2, salt — -
3, salt
4, salt---
5, salt---
6, salt— -
8, salt— -
9, salt— -
10, salt--
11, salt —
12, salt--
13, salt--
14, salt--
20, salt--
28, salt--
32, salt —
34, salt —
35, salt--
36, salt--
37, salt--
40, salt--
41, salt--
42, salt--
44, salt--
48, salt--
49, salt--
51, salt--
121, salt-
Azoia Coupling Components
(Naphthol AS and Derivatives )
Azoic
Azoic
* Azoic
Azoic
*Azoic
*Azoic
Azoic
Azoic
Azoic
Azoic
*Azoic
Azoic
Azoic
Azoic
*Azoic
Azoic
Azoic
Azoic
Azoic
Azoic
*Azoic
* Azoic
Azoic
Azoic
*Azoic
Azoic
Other
Coupling Component 2-
Coupl
Coupl
Coupl
Coupl
Coupling Component
Coupl
Coupl
Coupl
Coupl
Coupl
Coupl
Coupl
Coupl
Coupl
Coupl
Coupl
Coupl
ng Component 3-
ng Component 4-
ng Component 5-
ng Component 7-
ng Component 10-
ng Component li-
ng Component 12-
ng Component 13-
ng Component 14-
ng Component 15-
ing Component 16-
Coupling Component 17-
ing Component 18
ing Component 19-
ing Component 20-
ing Component 21-
ng Component 23-
Coupling Component 24
Coupling Component 29
Coupling Component 34
Coupling Component 35
Coupling Component 36
Coupling Component 43
Coupling Component 44
azoic coupling components-
AAP,
ALL,
GAP,
SDH
BUC,
GAP.
AAP,
ALL,
BUC,
GAP,
SDH
ALL,
BUC.
AAP,
ALL,
BUC,
GAP,
SDH
AAP,
BUC,
GAP.
AAP,
ALL,
BUC,
GAP.
AAP,
ALL,
BUC,
GAP,
SDH
ALL,
BUC,
GAP.
AAP,
ALL,
BUC,
GAP.
AAP,
ALL,
BUC,
GAP,
SDH
AAP,
ALL,
BUC,
GAP,
SDH
AAP.
ALL,
BUC.
ALL,
BUC,
GAP,
SDH.
ALL,
SDH.
ALL,
GAP.
BUC,
GAP.
AAP,
GAP.
GAP.
BUC.
ALL,
BUC,
GAP.
GAP.
ALL,
BUC,
GAP.
BUC,
GAP,
SDH.
AAP,
ALL,
BUC,
GAP.
GAP.
GAP.
ATL,
BUC,
GAP,
PCW.
BUC,
GAP,
PCW.
ATL,
BUC,
GAP,
PCW.
BUC.
AAP,
BUC,
PCW.
ATL,
BUC,
PCW.
ATL,
PCW.
BUC,
PCW.
BUC,
PCW.
GAP.
ATL,
BUC,
PCW.
BUC,
GAP.
BUC,
GAP.
ATL,
BUC,
PCW.
AAP,
ATL,
BUC,
GAP, PCW
BUC,
GAP,
PCW.
BUC,
GAP,
PCW.
ATL,
BUC,
PCW.
PCW.
GAP,
PCW.
ATL,
BUC,
PCW.
ATL,
BUC,
PCW.
BUC,
PCW.
GAP.
ATL,
BUC,
GAP.
PCW.
ATL,
GAP,
VPC.
73
Table 2. ■
-Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970-- Continued
Dye
BASIC DYES
*Basic yellow dyes:
Basic Yellow 1 ,
Basic Yellow 2
♦Basic Yellow 11
♦Basic Yellow 13
Basic Yellow 15
Basic Yellow 21
Basic Yellow 24
Basic Yellow 25
Basic Yellow 26
Basic Yellow 28
Basic Yellow 29
Basic Yellow 31
Basic Yellow 37
Basic Yellow 41
Other basic yellow dyes
*Basic orange dyes:
•Basic Orange 1
*Basic Orange 2
Basic Orange 14
Basic Orange 17
♦Basic Orange 21
Basic Orange 22
Basic Orange 24
Basic Orange 25
Basic Orange 26
Basic Orange 27
Basic Orange 31
Basic Orange 39
Other basic orange dyes
♦Basic red dyes :
Basic Red 1
Basic Red 2
♦Basic Red 9
Basic Red 12
♦Basic Red 13
♦Basic Red 14
Basic Red IS
Basic Red 16
Basic Red 17
♦Basic Red 18
Basic Red 19
Basic Red 22
Basic Red 23
Basic Red 29
Basic Red 30
Basic Red 47
Basic Red 48
Basic Red 49
Other basic red dyes
♦ Basic violet dyes:
♦Basic Violet 1
Basic Violet 2
Basic Violet 3
♦Basic Violet 4
Basic Violet 7
♦Basic Violet 10
Basic Violet 13
Basic Violet 14
Basic Violet 15
♦Basic Violet 16
Basic Violet 18
Basic Violet 24
Basic Violet 27
♦Basic blue dyes :
♦Basic Blue 1
Basic Blue 2
Basic Blue 3
♦Basic Blue 5
Manufacturers' identification codes
(according to list in table 3)
DUP.
ACS,
ACS,
ACS,
DUP.
VPC.
BAS.
BAS.
ACY.
VPC.
DUP,
DUP.
ACY.
ACY.
ATL,
ACS,
ACS,
GAP.
ACS.
ATL,
ACS,
DUP.
DUP.
DUP.
VPC.
ACY.
DUP.
VPC.
BAS,
ACS,
ACY,
DUP.
ACS,
ACS,
ATL,
DUP.
DUP.
DUP,
DUP.
ACY,
VPC.
BAS.
ACY.
DUP.
DUP.
DUP.
EKT,
ACS,
DSC.
ACS,
ACS,
GAP.
ACY,
DSC.
ACY,
DUP.
ATL,
ACY.
DUP.
ATL.
DSC,
DSC.
ACY,
DSC,
ACY, ALT, ATL, DUP, FAB, GAP, TRC, VPC.
ATL, DUP, GAP.
DUP, VPC.
ACY, DUP, GAP, PSC, TRC.
ACY, DSC, DUP, GAP, PSC, TRC.
ACS, DUP, FAB, GAF, VPC.
GAF.
DUP.
DUP.
DSC, HSC.
ATL, GAF, TRC, VPC.
ACY, ATL, DUP, GAF, VPC.
DUP, GAF.
GAF, VPC.
TRC.
TRC, VPC.
ACY, DSC, DUP, HSC, TCD.
DSC, DUP, SDH.
DSC, DUP.
DUP, GAF.
DSC.
DUP, FAB, GAF, TRC, VPC.
GAF, SDH, VPC.
DUP, GAF.
SDH, VPC.
74
SYNTHETIC ORGANIC CHEMICALS, 1970
Table 2.
-Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
BASIC DYES- -Continued
*Basic blue dyes--Continued
Basic Blue 6
Basic B:
Basic b:
Basic B:
Basic B:
Basil
Basic B]
Basic B:
Basic B]
Basic B:
Basic B]
Basic Bl
Basic B:
Basic B:
Basic Bl
Basic Bl
Basic Bl
Basic Bl
Basic B:
Basic B:
Basic B:
Bas:
Basic B:
ue 7-
ue 9-
lue 11
lue 21
lue 22
lue 25
lue 26
lue 35
lue 39
lue 41
lue 45
lue 47
lue 54
lue 60
lue 69
lue 75
lue 76
lue 77
lue 82
lue 87
lue 94
lue 97
Other basic blue dyes —
Basic green dyes:
*Basic Green 1
Basic Green 3
*Basic Green 4
Basic Green 7
Other basic green dyes-
Basic Brown dyes :
*Basic Brown 1
Basic Brown 2
♦Basic Brown 4
Basic Black dyes
DIRECT DYES
•Direct yellow dyes:
•Direct Yellow 4 —
•Direct Yellow 5
•Direct Yellow 6 —
Direct Yellow 7 —
Direct Yellow 8
Direct Yellow 9
•Direct Yellow 11--
•Direct Yellow 12--
Direct Yellow 20--
Direct Yellow 23--
•Direct Yellow 26--
Direct Yellow 27--
•Direct Yellow 28--
•Direct Yellow 29--
Direct Yellow 34--
Direct Yellow 39--
Direct Yellow 41--
•Direct Yellow 44--
•Direct Yellow 50--
Direct Yellow 59--
Direct Yellow 63--
Direct Yellow 81--
•Direct Yellow 84--
Direct Yellow 103-
•Direct Yellow 105-
•Direct Yellow 106-
Direct Yellow 107-
Direct Yellow 114-
ACS, ACY.
DSC, DUP, SDH.
ACS, ACY, DUP.
DSC, SDH.
DUP.
ACS, DUP.
VPC.
DUP, SDH.
DUP.
DUP.
TRC.
VPC.
VPC.
ACY, BAS.
GAP.
VPC.
EKT.
ACY.
DUP.
DUP, TRC.
DUP.
DUP.
DUP.
BAS, DUP, VPC.
ACS, ACY, DSC, DUP, SDH.
DUP.
ACS, ACY, DSC, DUP, SDH.
DSC.
VPC.
ACS, ACY, DUP, GAP, PSC, TRC.
GAP.
ACS, ACY, DSC, DUP, GAP, PSC, TRC.
ALT, DSC, VPC.
ACS,
ACS,
ACS,
ATL.
ACS,
ATL.
ACS,
ACS,
TRC.
DUP.
ALT,
GAP.
ACS,
ATL,
ALT,
TRC.
ATL.
ACS,
ACS,
ACS,
DUP.
ATL.
ACS,
ACS.
ALT,
ACS,
GAP.
ACY.
ACY, ATL, DUP, GAP, TCD, TRC, VPC.
ACY, GAP.
ACY, ATL, DUP, GAP, TRC.
ACY, ALT, DUP, GAP, TCD, TRC, VPC.
ATL, DUP, FAB, GAP, TRC.
ATL, DUP, GAP, PDC, TRC.
DUP, GAP.
GAP.
ATL, DUP, FAB, GAF, TCD, TRC, VPC.
ALT, ATL, DUP, FAB, GAF, HSH, TCD, TRC, VPC.
DUP.
ATL, DUP, FAB, TCD, TRC.
GAF, TCD, TRC.
ALT, PAB, GAF, TCD, TRC.
75
Table 2.
-Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
DIRECT DYES--Continued
♦Direct yellow dyes --Continued
Direct Yellow 117
Direct Yellow 118
Direct Yellow 119
Direct Yellow 120
Direct Yellow 121
Direct Yellow 123
Direct Yellow 125
Direct Yellow 127
Direct Yellow 131
Other direct yellow dyes
♦Direct orange dyes :
♦Direct Orange 1
Direct Orange 6
♦Direct Orange 8
Direct Orange 10
Direct Orange 11
♦Direct Orange IS
♦Direct Orange 26
♦Direct Orange 29
♦Direct Orange 34
♦Direct Orange 37
♦Direct Orange 39
Direct Orange 59
Direct Orange 61
Direct Orange 67
♦Direct Orange 72
♦Direct Orange 73
Direct Orange 74
Direct Orange 78
Direct Orange 79
Direct Orange 80
♦Direct Orange 81
Direct Orange 83
Direct Orange 88
♦Direct Orange 102
Direct Orange 110
Other direct orange dyes
♦Direct red dyes :
♦Direct Red 1
♦Direct Red 2
♦Direct Red 4
Direct Red 5
Direct Red 7
♦Direct Red 10
♦Direct Red 13
♦Direct Red 16
Direct Red 20
♦Direct Red 23
♦Direct Red 24
♦Direct Red 26
♦Direct Red 28
♦Direct Red 31
Direct Red 32
♦Direct Red 37
♦Direct Red 39
Direct Red 62
♦Direct Red 72
Direct Red 73
♦Direct Red 75
Direct Red 76
♦Direct Red 79
♦Direct Red 80
♦Direct Red 81
♦Direct Red 83
Direct Red 84
TRC.
TRC.
DUP.
DUP, TCD.
TRC.
DUP.
ACY.
DUP.
DUP.
AAP, ALT, ATL,
DUP,
GAF,
HSH,
TRC,
VPC.
AAP, ACS, ATL,
BDO,
CMG,
VPC.
ACS.
ACS, ATL, DUP,
GAP,
TRC,
YAW.
AAP.
GAP.
ACS, ACY, DUP,
GAP,
TRC.
ACS, ATL, CMC,
DUP,
GAF,
HSH,
TRC.
ATL, FAB, TCD,
TRC,
VPC.
ACS, ATL, CMC,
DUP,
GAF.
ACY, ATL, CMC,
DUP,
GAF.
ACY, ALT, ATL,
CMG,
DUP,
FAB,
GAP-,
TCD.
DUP, GAP.
TRC.
ACS, VPC.
ACS, ALT, ATL,
FAB,
HSH,
TCD,
TRC.
VPC.
DUP, GAP, TRC,
VPC.
DUP, HSH.
VPC.
DUP.
DUP, VPC.
DUP, GAP, VPC.
GAP.
DUP.
ACS, ACY, ATL,
DUP,
GAP.
TRC.
ALT, DUP, VPC.
ACS, ATL, DUP,
GAP,
TRC,
YAW.
ACS, ATL, DUP,
FAB,
TCD,
TRC.
ACS, ATL, TRC,
VPC.
ACS.
ATL.
AAP, ACS, ATL,
YAW.
ACS, ATL, DUP,
GAP,
TRC,
YAW.
ATL, DUP, TRC.
ACS, GAP.
ACS, ATL, CMG,
DUP
FAB
GAF,
TCD,
TRC, VPC.
AAP, ACS, ATL
FAB
HSH
TCD,
TRC,
VPC.
AAP, ACS, ATL
DUP
GAP
HSH,
TRC,
VPC.
ACS, ATL, DUP
FAB
TRC
YAW.
ACS, ATL, GAP
HSH
TRC
ACS, DUP.
ACS, ATL, DUP
GAP
TRC
YAW
ATL, DUP, GAP
TRC
YAW
ATL, TRC.
ACS, DUP, GAP
TRC
ACS, ATL.
ACS, CMG, DUP
GAP
GAP.
ATL, CMG, TCD
TRC
VPC
AAP, ACS, ALT
ATL
BDO
CMG
FAB
HSH, SDH, TCD
TRC, VPC.
AAP, ACS, ACY
ATL
BDO
CMG
DUP
GAF, HSH, TCD
TRC, VPC, YAW.
ACS, ALT, ATL
CMC
FAB
HSH
TCD
TRC, VPC.
ATL.
SYNTHETIC ORGANIC CHEMICALS, 1970
-Dyes for which U.S. production or sales were reported,
identified by manxifacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
DIRECT DYES--Continued
*Direct red dyes--Continued
Direct Red 95
Direct Red HI
Direct Red 117
Direct Red 118
♦Direct Red 122
Direct Red 123
Direct Red 127 and 127A
Direct Red 139
*Direct Red 149
Direct Red 152
Direct Red 153
Direct Red 209
Direct Red 212
Other direct red dyes
♦Direct violet dyes:
♦Direct Violet 1
♦Direct Violet 7
♦Direct Violet 9
Direct Violet 14
Direct Violet 22
Direct Violet 47
Direct Violet 48
♦Direct Violet 51
Direct Violet 62
Direct Violet 66
Direct Violet 67
Other direct violet dyes
♦Direct blue dyes:
♦Direct Blue 1
♦Direct Blue 2
♦Direct Blue 6
♦Direct Blue 8
Direct Blue 14
♦Direct Blue 15
♦Direct Blue 22
♦Direct Blue 24
♦Direct Blue 25
Direct Blue 26
♦Direct Blue 67
♦Direct Blue 71
Direct Blue 74
Direct Blue 75
♦Direct Blue 76
♦Direct Blue 78
♦Direct Blue 80
Direct Blue 81
♦Direct Blue 86
Direct Blue 87
Direct Blue 91
♦Direct Blue 98
Direct Blue 100
Direct Blue 104
♦Direct Blue 120, 120A
♦Direct Blue 126
Direct Blue 133
Direct Blue 136
Direct Blue 143
Direct Blue 151
Direct Blue 160
Direct Blue 189
Direct Blue 191
Direct Blue 199
♦Direct Blue 218
Direct Blue 224
Direct Blue 238
Direct Blue 263
^Hhei^^ec^^Ujedve^
VPC.
GAF.
DUP.
ATL.
ATL,
TRC,
VPC.
ATL,
GAF.
ATL.
ATL,
VPC.
ATL,
CMG,
DUP.
CMG,
DUP.
ATL.
TRC,
VPC.
VPC.
ALT,
ATL,
DUP,
GAF,
HSH,
TCD, TRC.
AAP,
ACS,
ATL.
ACS,
ATL,
GAF.
ACS,
ATL,
DUP,
GAF,
TCD,
TRC.
ACS,
ATL.
DUP.
GAF.
ACS.
ACS,
ATL,
DUP.
ACY.
ATL,
TRC.
DUP.
ALT.
ACS, ACY, ATL, DUP,
ACS, ATL, DUP, FAB,
AAP,
ACS,
ACY,
ATL,
DUP
ACS,
ATL,
DUP,
GAF.
ACS,
ATL,
TRC.
ACS,
ATL,
DUP,
GAF,
YAW
ACS,
ATL,
•QJIG.
ATL,
TCD,
YAW.
ACS,
ATL,
GAF,
TRC,
YAW
ATL.
ACS,
ATL,
DUP,
TRC.
ACS,
ATL,
GAF,
TRC.
DUP.
TRC.
ACS,
ALT,
ATL,
FAB,
GAF
ACS,
ATL,
CMG,
DUP,
TRC
ACS,
ALT,
ATL,
DUP,
FAB
ATL.
AAP,
ACS,
ACY,
ALT,
ATL
SDH, TCD, TRC, VPC.
ICI.
TRC.
ALT,
ATL,
GAF,
TRC,
VPC
ALT,
ATL,
TCD.
DUP.
ATL,
DUP,
TCD,
TRC.
ATL,
DUP,
HSH,
TRC,
VPC
GAF.
GAF.
DUP.
ATL,
TRC.
TRC.
TCD,
TRC.
AAP,
ALT,
GAF.
GAF.
ACS,
ALT,
ATL,
DUP,
FAB
ATL.
ACY.
DUP.
ALT
GAF
VPC.
GAF, HSH, TCD, TRC, VPC,
GAF, HSH, TCD, TRC, VPC,
GAF, HSH, TCD, TRC, YAW.
HSH, TCD, TRC, VPC, YAW.
GAF, HSH, TCD, TRC.
DUP, FAB, GAF, ICC, ICI,
GAF, TCD, TRC, VPC.
DYES
77
Table 2. — Dyes for which U.S. production or sales were reported,
identified by manufacturer, 19 70- -Continued
Dye
DIRECT DYES--Continued
*Direct green dyes :
'Direct Green 1
•Direct Green 6
Direct Green 8
Direct Green 12
Direct Green 15
Direct Green 26
Direct Green 27
Direct Green 28
Direct Green 38
Direct Green 39
Direct Green 45
Direct Green 47
Direct Green 51
Direct Green 69
Other direct green dyes
*Direct brown dyes :
*Direct Brown 1
*Direct Brown lA
*Direct Brown 2
Direct Brown 6
Direct Brown 27
*Direct Brown 31
Direct Brown 32
Direct Brown 33
Direct Brown 40
Direct Brown 44
Direct Brown 48
Direct Brown 59
*Direct Brown 74
'Direct Brown 95
Direct Brown 106
*Direct Brown 111
Direct Brown 112
'Direct Brown 154
Direct Brown 218
Other direct brown dyes
'Direct black dyes:
'Direct Black 4
Direct Black 8
'Direct Black 9
Direct Black 17—'
Direct Black 19
'Direct Black 22
Direct Black 36
Direct Black 37
'Direct Black 38
Direct Black 44
'Direct Black 51
Direct Black 56
Direct Black 71
Direct Black 75
Direct Black 78
'Direct Black 80
Direct Black 190
Other direct black dyes
DISPERSE DYES
'Disperse yellow dyes:
Disperse Yellow 1
Disperse Yellow 2
'Disperse Yellow 3
'Disperse Yellow 5
Disperse Yellow 8
'Disperse Yellow 23
Disperse Yellow 31 -■
Disperse Yellow 32
'Disperse Yellow 33
Manufacturers' identification codes
Caccording to list in table 3)
ACS, ACY, ATL, DUP, FAB, GAP, TCD, TRC, YAW.
ACS, ATL, FAB, GAF, TCD, TRC, YAW.
TRC.
TRC.
AAP,
AAP,
TRC.
TRC.
DUP.
DUP,
DUP,
TRC.
DUP,
GAF.
ATL,
ATL,
TRC.
TRC.
ACY, ALT, DUP.
VPC.
DUP, GAF.
ACY,
GAF,
AAP,
ACS,
ATL,
AAP,
GAF.
DUP.
AAP.
GAF,
AAP.
ACY,
AAP,
ACS,
GAF.
DUP,
ATL.
ACS,
ACS,
ALT,
ACS,
TRC,
ACS,
GAF.
ATL,
ALT,
AAP.
AAP.
AAP,
TRC.
AAP,
ACS,
ATL.
GAF.
ACS,
ACS,
TCD.
ACY,
ATL, TCD.
TRC, YAW.
ACS, ACY, ATL, DUP, GAF, HSH, TCD, TRC, YAW.
TRC, YAW.
GAF.
ACS, ATL, DUP, GAF, TRC, YAW.
YAW.
ACS, DUP.
ATL, DUP, FAB, GAF, HSH, TCD, TRC, YAW.
GAF, TRC, VPC.
DUP, FAB, TRC, YAW.
HSH.
VPC.
ATL, GAF, TCD, TRC, YAW.
YAW.
ATL, DUP, GAF, TCD.
ATL, DUP, GAF, TCD, TRC, VPC, YAW.
ACS, ACY, ATL, FAB, GAF, HSH, TCD, TRC, YAW.
ACS, DUP, GAF, TRC.
TRC.
ATL, FAB, HSH, TCD, TRC, VPC, YAW.
ALT, ATL, HSH, TRC, YAW.
GAF.
DUP.
AAP, ACS, ALT, DUP, GAF, HSH, ICC, TCD, TRC.
GAF, ICC, TCD.
EKT, TRC.
AAP, ALT, DUP, EKT, GAF, ICC, TCD, TRC.
GAF.
DUP.
AAP, EKT, GAF, ICC, TRC.
.ICO-CCQ r^ .■,■> _^
78
SYNTHETIC ORGANIC CHEMICALS, 1970
Table 2. — Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Dye
Manufacturers ' identification codes
(according to list in table 3)
DISPERSE DYES- -Continued
*Disperse yellow dyes --Continued
*Disperse Yellow 34
*Disperse Yellow 42
Disperse Yellow 50
♦Disperse Yellow 54
Disperse Yellow 67
Disperse Yellow 69
Disperse Yellow 77
Disperse Yellow 85
Disperse Yellow 86
Disperse Yellow 87
Disperse Yellow 88
Disperse Yellow 89
Disperse Yellow 93
Disperse Yellow 95
Disperse Yellow 96
Disperse Yellow 106
Disperse Yellow 125
Other disperse yellow dyes
♦Disperse orange dyes:
♦Disperse Orange 3
♦Disperse Orange 5
Disperse Orange 16
♦Disperse Orange 17
Disperse Orange 21
♦Disperse Orange 25
Disperse Orange 28
Disperse Orange 29
Disperse Orange 30
Disperse Orange 38
Disperse Orange 41
Disperse Orange 44
Disperse Orange 57
Disperse Orange 58
Disperse Orange 59
Disperse Orange 62
Disperse Orange 75
Other disperse orange dyes
♦Disperse red dyes :
♦Disperse Red 1
Disperse Red 4
♦Disperse Red 5
Disperse Red 7
Disperse Red 9
♦Disperse Red 11
♦Disperse Red 13
♦Disperse Red 15
♦Disperse Red 17
Disperse Red 21
Disperse Red 30
Disperse Red 31
Disperse Red 35
Disperse Red 54
"Disperse Red 55
Disperse Red 56
Disperse Red 59
♦Disperse Red 60
♦Disperse Red 65
Disperse Red 66
Disperse Red 73
Disperse Red 78
Disperse Red 86
Disperse Red 88
Disperse Red 96
Disperse Red 117
Disperse Red 136
Disperse Red 137
Disperse Red 138
AAP
AAP
TRC
AAP
DUP
ACY
VPC
EKT
AAP
EKT
EKT
EKT
VPC
VPC
VPC
GAP
SDC
AAP
AAP
AAP
AAP
AAP
DUP
DUP
AAP
AAP
ICC
TRC
DUP
DUP
EKT
AAP
EKT
DUP
DUP
AAP
AAP
GAP
AAP
AAP
ATL
AAP
DUP
GAP
AAP
EKT
EKT
ICC
EKT
ICC
AAP
DUP
ACY
AAP
DUP
AAP
TRC
ICC
EKT
EKT
ACY
EKT
EKT
EKT
EKT
EKT, ICC
ALT, DUP, EKT, GAP, ICC, MAY, TCD, TRC.
DUP, GAP, ICC, TRC.
ALT, DUP, EKT, MAY, SDC, TRC, VPC.
ALT, DUP, GAP, HSH, ICC, TCD, TRC.
EKT, GAP, SDC.
EKT, GAP, HSH, ICC, TCD.
TRC.
EKT, TRC.
GAP.
TRC.
EKT.
ICC.
ALT, DUP, EKT, GAP, ICC, MAY, SDC, TCD, TRC.
DUP, EKT, GAP, HSH, ICC, TCD, TRC.
ICC, TRC.
EKT, GAP, HSH, ICC, TCD.
GAP.
ICI.
DUP, GAP, ICC.
GAP, ICC, TCD.
HSH, TCD, TRC.
DUP, EKT, GAP, HSH, ICC, TCD, TRC.
TRC.
DUP, ICC, TCD, TRC.
DUP, GAP.
DUP, EKT, GAP, SDC, TCD, TRC, VPC.
EKT, ICC, TRC.
TRC.
GAP.
DYES
79
Table 2.
-Dyes for which U.S. production or sales were reported,
identified by maniifacturer, 1970- -Continued
Dye
DISPERSE DYES- -Continued
'Disperse red dyes --Continued
Disperse Red 140
Disperse Red 177
Disperse Red 178
Disperse Red 179
Disperse Red 180
Other disperse red dyes
♦Disperse violet dyes :
♦Disperse Violet 1
♦Disperse Violet 4
Disperse Violet 8
Disperse Violet 14
Disperse Violet 18
Disperse Violet 26
♦Disperse Violet 27
Disperse Violet 28
Disperse Violet 41
Disperse Violet 42
Disperse Violet 43
Disperse Violet 44
Other disperse violet dyes
♦Disperse blue dyes:
♦Disperse Blue 1
♦Disperse Blue 3
♦Disperse Blue 7
Disperse Blue 9
Disperse Blue 26
Disperse Blue 27
Disperse Blue 35
Disperse Blue 55
Disperse Blue 56
Disperse Blue 60
Disperse Blue 61
Disperse Blue 62
Disperse Blue 63
♦Disperse Blue 64
Disperse Blue 70
Disperse Blue 71
Disperse Blue 73
♦Disperse Blue 79
Disperse Blue 81
Disperse Blue 94
Disperse Blue 95
Disperse Blue 102
Disperse Blue 109
Disperse Blue 112
Disperse Blue 116
Disperse Blue 117
Disperse Blue 118
Disperse Blue 119
Disperse Blue 120
Disperse Blue 121
Disperse Blue 123
Disperse Blue 125
Disperse Blue 132
Disperse Blue 133
Disperse Blue 139
Disperse Blue 150
Disperse Blue 155
Disperse Blue 166
Other disperse blue dyes
Disperse green dyes
Disperse brown dyes:
Disperse Brown 1
Disperse Brown 2
Disperse Brown 7
Other disperse brown dyes
Manufacturers' identification codes
(according to list in table 3)
DUP.
ICC.
ICC.
ICC.
ICC.
AAP,
MP,
AAP,
GAF.
DUP.
DUP.
DUP.
AAP,
TRC.
EKT.
EKT.
EKT.
EKT.
DUP,
AAP,
AAP,
EKT,
DUP,
ICC.
DUP,
ICI.
TRC.
VPC.
DUP.
DUP.
DUP,
DUP.
DUP,
AAP.
VPC.
TRC.
AAP,
VPC.
BAS.
GAF.
EKT.
DUP.
EKT.
ACY.
EKT.
EKT.
EKT.
EKT.
EKT.
EKT.
TRC.
DUP.
DUP.
VPC.
DUP.
GAF,
ICI.
ALT,
GAF,
TRC.
DUP,
EKT.
AAP,
DUP, EKT, GAF, ICC, MAY, SDC , TRC, VPC.
GAF, HSH, ICC, TRC.
GAF, ICC.
ACY, DUP, EXT, GAF, ICC.
GAF, MAY, SDC.
BAS, GAF, ICC, TCD, TRC.
DUP, EKT, GAF, HSH, ICC, TCD, TRC.
GAF, HSH, ICC, TCD, TRC.
GAF, ICC.
EKT.
EKT, SDC.
EKT, GAF, TRC.
DUP, GAF. HSH, ICC, MAY, SDC, TRC, VPC.
VPC.
EKT, GAF.
GAF, ICC, SDC.
80
SYNTHETIC ORGANIC CHEMICALS, 1970
Table 2.
-Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Dye
Manufacturers ' identification codes
(according to list in table 3)
DISPERSE DYES--Continued
'Disperse black dyes:
'Disperse Black 1
Disperse Black 2
Disperse Black 9
Disperse Black 33
Disperse Black 34
Other disperse black dyes
FIBER-REACTIVE DYES
♦Reactive yellow dyes:
Reactive Yellow 1
Reactive Yellow 2
Reactive Yellow 3
Reactive Yellow 4
Reactive Yellow 6
Reactive Yellow 7
Reactive Yellow 8
Reactive Yellow 13
Reactive Yellow 14
Reactive Yellow IS
Reactive Yellow 17
Reactive Yellow 18
Reactive Yellow 22
Reactive Yellow 24
Reactive Yellow 25
Reactive Yellow 37
Reactive Yellow 60
Reactive Yellow 61
Reactive Yellow 62
Reactive orange dyes :
Reactive Orange 1
Reactive Orange 2
Reactive Orange 4
Reactive Orange 10
Reactive Orange 12
Reactive Orange 13
Reactive Orange 14
Reactive Orange 16
Reactive Orange 49
Reactive red dyes :
Reactive Red 1
Reactive Red 2
Reactive Red 3
Reactive Red 4
Reactive Red 5
Reactive Red 8
Reactive Red 11
Reactive Red 16
Reactive Red 21
Reactive Red 29
Reactive Red 31
Reactive Red 33
Reactive Red 40
Reactive Red 41
Reactive Red 92
Reactive Red 93
Reactive violet dyes:
Reactive Violet 1
Reactive Violet 2
Reactive Violet 4
Reactive Violet 5
Reactive Violet 14
'Reactive blue dyes:
Reactive Blue 1
Reactive Blue 2
Reactive Blue 3
Reactive Blue 4
AAP, DUP, GAP, TRC.
TRC.
AAP, EKT.
EKT.
EKT.
ALT, DUP, GAP, ICC, SDC, VPC.
ICI.
HST, TRC.
TRC.
ICI.
TRC.
ICI.
HST.
HST.
HST.
HST.
HST.
ICI.
ICI.
HST.
VPC.
HST.
ACY.
ACY.
ACY.
ICI.
TRC.
ICI.
HST.
ICI.
ICI.
ICI.
HST.
ACY.
ICI.
ICI.
ICI.
TRC.
ICI.
ICI.
ICI.
TRC.
HST.
ICI.
HST, ICI.
ICI.
VPC.
VPC.
ACY.
ACY.
ICI.
TRC.
HST.
HST.
HST.
ICI.
TRC.
ICI.
ICI.
DYES
81
Table 2. --Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Dye
FIBER-REACTIVE DYES- -Continued
*Reactive blue dyes--Continued
Reactive Blue 5
Reactive Blue 7
Reactive Blue 9
Reactive Blue 19
Reactive Blue 21
Reactive Blue 2S
Reactive Blue 27
Reactive Blue 29
Reactive Blue 30
Reactive Blue 86
Reactive Blue 87
Reactive Blue 88
Other reactive blue dyes
Reactive green dyes
Reactive brown dyes: Reactive Brown 10
*Reactive black dyes :
Reactive Black 1
Reactive Black 5
Reactive Black 9
FLUORESCENT BRIGHTENING AGENTS
Fluorescent Brightening Agent 6
Fluorescent Brightening Agent 8
Fluorescent Brightening Agent 9
Fluorescent Brightening Agent 22
Fluorescent Brightening Agent 24
Fluorescent Brightening Agent 2S
'Fluorescent Brightening Agent 28
Fluorescent Brightening Agent 30
Fluorescent Brightening Agent 33
Fluorescent Brightening Agent 34
Fluorescent Brightening Agent 45
Fluorescent Brightening Agent 46
Fluorescent Brightening Agent 49
Fluorescent Brightening Agent 52
Fluorescent Brightening Agent 54
Fluorescent Brightening Agent 59
Fluorescent Brightening Agent 61
Fluorescent Brightening Agent 68
Fluorescent Brightening Agent 71
Fluorescent Brightening Agent 75
Fluorescent Brightening Agent 102
Fluorescent Brightening Agent 108
Fluorescent Brightening Agent 109
Fluorescent Brightening Agent 113
Fluorescent Brightening Agent 114
Fluorescent Brightening Agent 125
Fluorescent Brightening Agent 126
Fluorescent Brightening Agent 128
Fluorescent Brightening Agent 130
Fluorescent Brightening Agent 134
Fluorescent Brightening Agent 135
Fluorescent Brightening Agent 158
Fluorescent Brightening Agent 159
Fluorescent Brightening Agent 184
Fluorescent Brightening Agent 189
Fluorescent Brightening Agent 190
Fluorescent Brightening Agent 205
Other fluorescent brightening agents
FOOD, DRUG, AND COSMETIC COLORS
Food, Drug, and Cosmetic Dyes
*FD§C Blue No. 1
*FD§C Blue No. 2
FD5C Green No. 3
Manufacturers' identification codes
(according to list in table 3)
TRC.
TRC.
ICI.
HST.
HST.
ICI.
HST.
VPC.
VPC.
ACY.
ACY.
ACY.
HST.
HST, ICI.
ICI.
TRC.
HST.
ICI.
ACY.
ACY.
ACY,
CGY.
CGY.
GAF.
ACY,
GAF.
GAF.
DUP.
TRC.
CGY.
S.
CCW, DUP, SDH.
CGY.
CGY.
ACY, CGY.
CCW, GAF.
ACY, GAF.
GAF.
DUP, VPC.
GAF.
GAF.
VPC.
VPC.
ACY.
SDH.
SDH.
SDH.
CGY.
CGY.
ACY.
ACY.
CGY.
CGY.
CGY.
VPC.
ACY, CCW, CGY, DUP, GAF, PCW, S, VPC.
ACS, ALT, KON, SDH, WJ.
ACS, KON, SDH, WJ.
82
SYNTHETIC ORGANIC CHEMICALS, 1970
Table 2. — Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Dye
Manufacturers ' identification codes
(according to list in table 3)
FOOD, DRUG, AND COSMETIC COLORS--Continued
Food, Drug, and Cosmetic Dyes — Continued
*FD§C Red No. 2
*FD§C Red No. 3
*FDSC Red No. 4
*FD5C Violet No. 1
*FD8C Yellow No. 5
*FD§C Yellow No. 6
Other food, drug, and cosmetic dyes
Dmg and Cosmetic Dyes
D5C Blue No. 6
D§C Green No. 5
D5C Green No. 6
D§C Green No. 7
DSC Green No. 8
D§C Orange No. 4
DSC Orange No. 5
DSC Orange No. 10
DSC Orange No. 17
DSC Red No. 2
DSC Red No. 3
DSC Red No. 6
*DSC Red No. 7
DSC Red No. 8
*DSC Red No. 9
DSC Red No. 10
DSC Red No. 11
*DSC Red No. 12
DSC Red No. 13
DSC Red No. 17
*DSC Red No. 19
*DSC Red No. 21
DSC Red No. 22
DSC Red No. 27
DSC Red No. 28
DSC Red No. 30
DSC Red No. 31
DSC Red No. 33
DSC Red No. 34
*DSC Red No. 36
DSC Red No. 37
*DSC Yellow No. 5
DSC Yellow No. 6
DSC Yellow No. 7
DSC Yellow No. 8
DSC Yellow No. 10
DSC Yellow No. 11
Drug and Cosmetic Dyes, External
Ext. DSC Green No. 1
Ext. DSC Yellow No. 1
Ext. DSC Yellow No. 7
INGRAIN DYES
Ingrain blue dyes:
Ingrain Blue 1--
Ingrain Blue 2--
ACS, ALT, KON, SDH, STG , WJ.
ACS, ALT, KON, SDH, STG, WJ.
KON, STG, WJ.
ACS, SDH, WJ.
ACS, ALT, KON, SDH, STG, WJ.
ACS, ALT, KON, SDH, STG, WJ.
ALT, STG.
KON.
ACS,
ALT,
KON.
ACS,
ALT,
KON.
ALT.
KON,
SDH.
KON,
SNA,
TMS.
SNA,
TMS.
TMS.
SNA.
KON.
KON,
TMS.
KON,
SNA,
TMS.
KON,
SNA,
TMS.
KON,
SNA.
KON,
SNA,
TMS.
KON,
SNA.
KON,
SNA.
KON,
SNA,
TMS.
SNA.
KON.
ACS,
KON,
SNA, TMS
KON,
SNA,
TMS.
KON,
SDH.
TMS.
ACS.
KON,
™s.
KON.
ACS,
KON.
KON.
ALT,
KON,
TMS.
ACS.
KON,
SNA,
TMS.
KON.
KON.
KON,
TMS.
KON.
KON.
MORDANT DYES
*Mordant yellow dyes:
♦Mordant Yellow 1
Mordant Yellow 3
Mordant Yellow 5
ACS, KON.
ACS, KON.
KON.
ICI.
ICI, VPC.
ATL, GAF, PDC.
ATL.
TRC.
DYES
83
Table 2. — Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Dye
MORDANT DYES--Continued
*Mordant yellow dyes --Continued
*Mordant Yellow 8
Mordant Yellow 14
Mordant Yellow 16
Mordant Yellow 20
Mordant Yellow 26
Mordant Yellow 29
Mordant Yellow 30
Mordant Yellow 36
*Mord2int orange dyes :
Mordant Orange 1
Mordant Orange 4
Mordant Orange 6
Mordant Orange 8
Mordant Orange 30
*Mordant red dyes :
Mordant Red 3
Mordant Red 5
Mordant Red 7
Mordant Red 9
Mordant Red 11
Mordant violet dyes:
Mordant Violet 5
Mordant Violet 11
Mordant Violet 20
Mordant blue dyes:
Mordant Blue 1
Mordant Blue 3
Mordant Blue 9
Mordant Blue 13
Mordant Blue 19
Mordant green dyes :
Mordant Green 36
*Mordant brown dyes :
*Mordant Brown 1
Mordant Brown 12
Mordant Brown 13
Mordant Brown 15
Mordant Brown 18
Mordant Brown 19
Mordant Brown 21
*Mordant Brown 33
'Mordant Brown 40
Mordant Brown 50
Mordant Brown 63
Mordant Brown 70
*Mordant black dyes:
Mordant Black 3
Mordant Black 7
Mordant Black 8
Mordant Black 9
*Mordant Black 11
Mordant Black 13
*Mordant Black 17
Mordant Black 19
Mordant Black 26
Mordant Black 38
OXIDATION BASES
Oxidation Base 8 and 8A
Oxidation Base 21
Oxidation Base 22
Oxidation Base 25
Other oxidation bases
Manufacturers' identification codes
(according to list in table 3)
ACS,
PDC,
VPC.
ACS,
PDC.
ACY.
ACS,
ATL.
VPC.
GAP.
TRC,
VPC.
PDC.
ACY,
GAP,
PDC,
TRC.
GAP,
PDC.
ATL,
GAP,
PDC,
TRC.
TRC.
ACS.
ACS,
ACY.
PDC.
ACS,
ACY,
ATL,
BDO, CMG, GAP, TRC, VPC
MRX.
ACY.
PDC.
GAP.
GAP.
GAP.
GAP.
GAP.
ACS.
CMG.
ACS,
CMG,
DUP
GAP,
PDC.
ACS.
GAP.
ACS,
DUP.
GAP.
GAP,
VPC.
ACS,
GAP,
PDC,
TRC.
ACS,
DUP,
GAP,
YAW.
TRC.
TRC.
DUP,
PDC.
ACS,
TRC.
GAP.
VPC.
ACS,
VPC.
ACS,
GAP,
TRC,
VPC.
HSH.
ACS,
ACY,
GAP,
TRC.
PDC.
TRC.
PDC.
ACY.
PDC.
ACY.
ACY.
ACY.
SYNTHETIC ORGANIC CHEMICALS, 1970
-Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Dye
Manufacturers' identification codes
(according to list in table 3)
SOLVENT DYES
♦Solvent yellow dyes:
Solvent Yellow 1
*Solvent Yellow 2
♦Solvent Yellow 3
Solvent Yellow 13
♦Solvent Yellow 14
Solvent Yellow 19
Solvent Yellow 29
Solvent Yellow 30
Solvent Yellow 33
Solvent Yellow 34
Solvent Yellow 40
Solvent Yellow 42
Solvent Yellow 43
Solvent Yellow 44
Solvent Yellow 45
Solvent Yellow 47
Solvent Yellow 56
Solvent Yellow 71
Solvent Yellow 72
Solvent Yellow 87
Other solvent yellow dyesr
♦Solvent orange dyes:
Solvent Orange 2
♦Solvent Orange 3
Solvent Orange 5
♦Solvent Orange 7
Solvent Orange 20
Solvent Orange 23
Solvent Orange 24
Solvent Orange 25
Solvent Orange 31
Solvent Orange 47
Solvent Orange 48
Solvent Orange 51
Other solvent orange dyes
♦Solvent red dyes:
Solvent Red 1
Solvent Red 8
Solvent Red 22
Solvent Red 24
♦Solvent Red 26
Solvent Red 27
Solvent Red 33
Solvent Red 35
Solvent Red 40
Solvent Red 41
♦Solvent Red 49
Solvent Red 52
Solvent Red 68
Solvent Red 69
Solvent Red 74
Solvent Red 75
Solvent Red 80
Solvent Red 105
Solvent Red 108
Solvent Red 111
Solvent Red 115
Solvent Red 126
Other solvent red dyes
♦Solvent violet dyes:
Solvent Violet 8
Solvent Violet 9
Solvent Violet 13
Solvent Violet 14
Solvent Violet 17
Other solvent violet dyes
AAP
MP
DUP,
FH,
GAF,
PSC.
ACS
DUP,
PSC
ACY
GAF.
AAP
ACS,
ACY
DUP
FH, GAF, PSC,
SDH
GAP
GAP
ACS
PSC.
ACS
ACY.
DSC
ACS
ACS
GAF
ACS
GAF.
ACS
ACY
DUP,
GAF.
ACS
ACY.
ACY
ACY
ACY
AAP
DSC,
PAT
AAP
PSC.
ACS
ACY,
DSC,
GAF
PSC.
GAF
ACS
ACY,
ATL
GAF
ACY
GAF.
ACS
DUP
ACY
DUP.
ACS
FH.
ACY
ACY
AAP
ACY,
DSC
DUP,
PAT.
ATL
PSC.
GAF
GAF
ACY
DUP,
FH,
GAF,
PAT, SDH.
AAP
ACS,
ACY,
PSC
ACS
DUP
GAF.
GAF
GAF
DSC
ACY
DSC,
DUP
GAF
AAP
GAF,
ICl
ACS
DSC
DUP.
ACS
ACS
ACS
ACY.
ACY
ACY
ACY
ACY
ACY
AAP
ACY,
ATL,
DSC
DUP, PAT.
ACS
ACY,
DSC
DUP
DSC
ATL
HSH,
ICI
AAP
ICI.
ACS
AAP
DSC,
PAT.
DYES
85
Table 2. — Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Dye
SOLVENT DYES--Continued
Solvent blue dyes;
Solvent Blue 3
Solvent Blue 4
Solvent Blue 5
Solvent Blue 6
Solvent Blue 7
Solvent Blue 9
Solvent Blue 11
Solvent Blue 12
Solvent Blue 16
Solvent Blue 36
Solvent Blue 37
♦Solvent Blue 38
Solvent Blue 43
Solvent Blue 58
Solvent Blue 59
Solvent Blue 60
Solvent Blue 74
Other solvent blue dyes
Solvent green dyes :
Solvent Green 1
Solvent Green 2
*Solvent Green 3
Other solvent green dyes
Solvent brown dyes :
Solvent Brown 11
♦Solvent Brown 12
Solvent Brown 19
Solvent Brown 20
Solvent Brown 22
Solvent Brown 38
Other solvent brown dyes
Solvent black dyes :
Solvent Black 3
Solvent Black 5
Solvent Black 7
Solvent Black 12
Solvent Black 13
Solvent Black 17
Solvent Black 26
Other solvent black dyes
SULFUR DYES
Sulfur yellow dyes:
Leuco Sulfur Yellow 1
Leuco Sulfur Yellow 2
Sulfur Yellow 4
Leuco Sulfur Yellow 4
Leuco Sulfur Yellow 9
Leuco Sulfur Yellow 15
Other Sulfur yellow dyes
Sulfur Orange 1
Sulfur red dyes :
Leuco Sulfur Red 5
Sulfur Red 6
Other sulfur red dyes
Sulfur blue dyes:
Sulfur Blue 5
Sulfur Blue 7
Leuco Sulfur Blue 7
Solubilized Sulfur Blue 7
Sulfur Blue 8
Leuco Sulfur Blue 8
Sulfur Blue 9
Leuco Sulfur Blue 13
Sulfur Blue 16
Other sulfur blue dyes
Manufacturers' identification codes
(according to list in table 3)
ACY,
SW.
DSC,
DUP
SDH.
DSC.
DSC.
ACY.
GAP.
BOO,
GAP,
ICl.
BDO.
ACS.
ACS,
DUP.
DUP.
ACS,
ACY
ATL,
DUP,
GAP.
ACS.
ACY.
ACY.
ACY.
ACS.
AAP,
ACY,
DSC,
GAP,
ICI, PAT, SDH
ACY,
DSC
SDH.
GAP.
AAP,
ACS,
ACY,
ATL,
GAP, HSH, ICI
ACY,
DSC,
GAP.
GAP.
ACY,
DSC,
GAP.
DUP.
ACY,
DUP.
DUP,
PH,
PSC.
ACY.
DSC.
ACS.
ACS,
ACY,
DSC,
DUP.
ACS,
ACY,
DSC,
PH.
ACS.
ACS.
DUP.
ACY.
DSC.
SDC.
ACY,
SDC.
SDC.
SDC.
STC.
ACY.
ACY,
SDC.
STC.
SDC.
SDC.
SDC.
ACY.
ACY,
SDC.
ACY,
SDC, STC
SDC.
SDC.
SDC.
ACY.
ACY,
SDC.
86
SYNTHETIC ORGANIC CHEMICALS, 1970
Table 2. — Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers ' identification codes
(according to list in table 3]
SULFUR DYES- -Continued
Sulfur green dyes :
Sulfur Green 2
Leuco Sulfur Green 2
Leuco Sulfur Green 3
Leuco Sulfur Green 9
Sulfur Green 14
Leuco Sulfur Green 16
Solubllized Sulfur Green 16
Other sulfur green dyes
Sulfur brown dyes :
Leuco Sulfur Brown 1
Solubilized Sulfur Brown 1
Leuco Sulfur Brown 3
Sulfur Brown 10
Leuco Sulfur Brown 10
Solubilized Sulfur Brown 10
Sulfur Brown 12
Sulfur Brown 14
Leuco Sulfur Brown 14
Leuco Sulfur Brown 20
Solubilized Sulfur Brown 21
Sulfur Brown 25
Leuco Sulfur Brown 26
Sulfur Brown 30
Leuco Sulfur Brown 37
Leuco Sulfur Brown 81
Leuco Sulfur Brown 82
Other sulfur brown dyes
Sulfur black dyes:
Sulfur Black 1
Leuco Sulfur Black 1
Solubilized Sulfur Black 1
Sulfur Black 2
Leuco Sulfur Black 2
Solubilized Sulfur Black 2
Leuco Sulfur Black 10
Sulfur Black 11
Leuco Sulfur Black 11
Other sulfur black dyes
VAT DYES
*Vat yellow dyes :
Vat Yellow 1, 12-1/2%
*Vat Yellow 2, 8-1/2%
Solubilized Vat Yellow 2, 25%
Vat Yellow 3, 12-1/2%
*Vat Yellow 4, 12-1/2%
Solubilized Vat Yellow 4, 37-1/2%—
Vat Yellow 10, 10%
Vat Yellow 14, 12-1/2%
Vat Yellow IS, 11-1/2%
Vat Yellow 21, 9-1/2%
Vat Yellow 22, 10%
Vat Yellow 33, 15%
Other vat yellow dyes
*Vat orange dyes :
*Vat Orange 1, 20%
Solubilized Vat Orange 1, 26%
*Vat Orange 2, 12%
Vat Orange 3, 13-1/2%
Vat Orange 4, 6%
Vat Orange 5, 10%
Solubilized Vat Orange 5, 30%
Vat Orange 7, 11%
*Vat Orange 9, 12%
SDC.
SDC.
SDC
STC.
DUP,
SDC.
SDC.
SDC.
ACY,
SDC.
STC.
STC.
SDC.
DUP,
SDC.
SDC.
SDC.
SDC.
SDC.
ACY,
SDC.
STC.
STC.
ACY.
STC.
ACY.
SDC.
ACY.
ACY.
ACY,
SDC.
ACY,
SDC.
ACY,
SDC, STC
SDC,
STC.
SDC.
ACY,
SDC.
SDC.
ACY.
SDC.
SDC.
SDC.
ACS.
AAP,
GAP.
DUP.
ATL,
GAP.
GAP.
TRC.
ACY,
ATL.
DUP.
TRC,
ACS,
ACS, GAP, HST, ICl, TRC, VPC.
CMG, GAP, HST, VPC.
DUP.
VPC.
GAP, MAY, VPC.
ACS, ACY, ATL, DUP, GAP, HST, ICl, TRC, VPC.
HST.
ACS, ACY, DUP, GAP, ICl, TRC.
CMG, DUP, GAP.
ACY, DUP.
ACY, HST.
HST.
GAP, HST, TRC.
ACY, DUP, GAP, ICl, TRC.
DYES
87
Table 2. --Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Dye
VAT DYES— Continued
*Vat orange dyes--Continued
Vat Orange 11, 6%
*Vat Orange 15, 10%
Vat Orange 24
Other vat orange dyes
*Vat red dyes :
*Vat Red 1, 13%
Solubilized Vat Red 1, 37%
Vat Red 10, 18%
Vat Red 12, 8-1/2
*Vat Red 13, 11%
Vat Red 14, 10%
Vat Red 15, 10%
Vat Red 16, 11%
Vat Red 23
*Vat Red 32, 20%
Vat Red 35, 12-1/2%
Vat Red 41, 20%
Vat Red 52, 10%
Vat Red 56, 15-1/2%
Vat Red 57
Other vat red dyes
*Vat violet dyes:
*Vat Violet 1, 11%
Vat Violet 2, 20%
Vat Violet 3, 15%
*Vat Violet 9, 12%
*Vat Violet 13, 6-1/4%
Vat Violet 14, 12-1/2%
Vat Violet 17, 12-1/2%
Vat Violet 21
Other vat violet dyes
*Vat blue dyes:
Vat Blue 1, 20%
Solubilized Vat Blue 1, 25%
Vat Blue 3, 16%
*Vat Blue 4, 10%
Vat Blue S, 16%
Solubilized Vat Blue 5, 38%
*Vat Blue 6, 8-1/3%
Solubilized Vat Blue 6, 17-1/2%
Solubilized Vat Blue 9, 35%
Vat Blue 12, 6-1/2%
Vat Blue 14, 8-1/3%
Vat Blue 16, 16-1/2%
*Vat Blue 18, 13%
Vat Blue 20, 14%
Vat Blue 26, 24%
Vat Blue 29
Vat Blue 39, 12%
Vat Blue 43 —
Vat Blue 53, 20-1/2%
Vat Blue 60
Other vat blue dyes.
*Vat green dyes :
*Vat Green 1, 6%
Solubilized Vat Green 1, 12-1/2%
*Vat Green 3, 10% —
Solubilized Vat Green 3, 26%
Vat Green 8, 8-1/2%
*Vat Green 9, 12-1/2%
Vat Green 20, 6%
Other vat green dyes
*Vat brown dyes :
*Vat Brown 1, 11%
Solubilized Vat Brown 1, 17%
*Vat Brown 3, 11%
Manufacturers' identification codes
(according to list in table 3)
DUP
MP
ACS
ACY
, GAF
, ICI
, TRC
, VPC
DUP
GAF
SDC
AAP
ACY
HST
TCI
GAF
HST
ACS
GAF
DUP
DUP
GAF
TRC
GAF
HST
GAF
HST
TRC
DUP
DUP
ACS
DUP
GAF
ACS
HST
DUP.
ACY
ACY.
GAF,
TRC.
ACY,
DUP,
GAF
ICI
TRC
ACY,
HST.
GAF,
HST.
DUP,
GAF,
ICI,
TRC
ACS,
DUP,
GAF,
ICI
TRC
ACS.
DUP.
VPC.
GAF,
MAY.
ACS.
GAF.
HST.
ACY,
DUP,
GAF.
ATL,
DUP,
HST.
GAF.
ACS,
ACY,
DUP,
GAF,
ICI,
TRC.
GAF,
HST.
GAF.
DUP.
DUP,
GAF,
TRC.
ACY,
DUP.
AAP,
ACY,
ATL,
DUP,
GAF,
ICI,
MAY,
TRC.
AAP,
ACY,
ATL,
DUP,
GAF,
MAY,
SDC,
TRC.
GAF.
GAF.
GAF.
SDC.
GAF.
DUP.
GAF,
MAY,
X.
ACS,
ACY,
ATL,
DUP,
GAF,
TCT,
MAY.
ICI.
AAP,
ACS,
ACY,
ATL,
DUP,
GAF,
ICI,
MAY, TRC
GAF,
ICI.
ACS,
ATL,
DUP,
GAF.
ACY,
ATL,
GAF,
MAY,
SDC,
TRC.
DUP.
GAF,
MAY,
SDC.
ACY,
DUP,
GAF,
MAY,
TRC,
VPC.
GAF.
AAP,
ACS,
ACY,
DUP,
GAF,
ICI,
MAY,
TRC, VPC
SYNTHETIC ORGANIC CHEMICALS, 1970
Table 2. — Dyes for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
VAT DYES --Continued
*Vat brown dyes — Continued
Vat Brown 5, 13%
Vat Brown 6, 17-1/2%
Vat Brown 11, 12%
Vat Brown 12, 12-1/2%
Vat Brown 13, 17%
Vat Brown 14, 12%
Vat Brown 20, 10-1/2%
Vat Brown 28, 22%
Vat Brown 29, 13%
Vat Brown 31, 28%
Vat Brown 38, 20%
Vat Brown 40, 14%
Vat Brown 57, 12.8%
Other vat brown dyes
*Vat black dyes :
Solubilized Vat Black 1, 27-1/2%
Vat Black 9, 16%
Vat Black 11, 17-1/2%
Vat Black 13, 14%
Vat Black 14, 11-1/2%
Vat Black 18, 15-1/2%
Vat Black 21, 18-1/2%
Vat Black 22, 19%
*Vat Black 25, 12-1/2%
*Vat Black 27, 12-1/2%
Vat Black 34, 16%
Vat Black 37
Vat Black 38, 20%
Vat Black 52, 18-1/2%
Other vat black dyes
All other dyes
ACY, HST, VPC.
AAP.
MAY, TRC.
DUP.
MAY.
HST.
ACS, GAP.
ICl.
ACY.
AAP.
ICl.
DUP.
TRC.
GAP, SDC, VPC.
HST.
GAP,
ACY.
DUP.
DUP.
GAP.
ACY.
ACY,
AAP,
ACY,
ICl.
GAP.
GAP.
ACY.
GAP,
ACY,
TRC.
ACY, DUP, GAP ,^ ICl, MAY, TRC.
BDO, DUP, GAP,' ICl, MAY, TRC.
SDC, TRC.
GAP, HSH, PAT, SDC.
DYES
89
Table 3. --Dyes: Directory of manufacturers, 1970
ALPHABETICAL DIRECTORY BY CODE
[Names of dye manufacturers that reported production or sales to the U.S. Tariff Commission for 1970 are listed below
in the order of their identification codes as used in table 2]
Code
Code
identi-
Name of company
identi-
Name of company
fication
fication
AAP
American Aniline Products, Inc.
ICC
Inmont Corp.
ACS
Allied Chemical Corp., Specialty Chemicals
Div.
American Cyanamid Co.
ICI
ICI America, Inc.
ACY
KON
H. Kohnstamm § Co., Inc.
ALL
Alliance Chemical, Inc.
ALT
Crompton 5 Knowles Corp., Althouse Div.
MAY
Otto B. May, Inc.
ATL
Atlantic Chemical Corp.
MRX
Max Marx Color § Chemical Co.
BAS
BASF Wyandotte Corp.
PAT
Morton International, Inc., Morton Chemical
BDO
Benzenoid Organics, Inc.
Co. Div.
BUC
Blackman-Dhler Chemical Co.
PCW
Pfister Chemical Works
PDC
Berncolors-Poughkeepsie, Inc.
CCW
Cincinnati Milacron Chemicals, Inc.
PSC
Passaic Color 5 Chemical Co.
CGY
Ciba-Geigy Corp.
CMC
Nyanza, Inc.
S
Sandoz, Inc., Sandoz Color 5 Chemicals Div.
CPC
Childs Pulp Colors, Inc.
SDC
Martin-Marietta Corp., Southern Dyestuff
CWN
Upjo'hn Co., Carwin Organic Chemicals
Co. Div.
SDH
Sterling Drug, Inc., Hilton-Davis Chemical
DSC
Dye Specialties, Inc.
Co. Div.
DUP
E . I . duPont de Nemours 5 Co . , Inc .
SNA
Sun Chemical Corp., Ansbacher-Siegle Div.
STC
Sou-Tex Chemical Co., Inc.
EKT
Eastman Kodak Co., Tennessee Eastman
STG
Stange Co.
Co. Div.
SW
Sherwin-Williams Co.
FAB
Fabricolor Manufacturing Corp.
TCD
Tenneco Chemicals, Inc., Tenneco Colors Div.
FH
Foster-Heaton Co.
TMS
Sterling Drug, Inc., Thomasset Colors Div.
TRC
Toms River Chemical Corp.
GAF
GAF Corp., Chemical Div.
VPC
Verona Corp.
HSC
Chemetron Corp., Pigments Div.
HSH
Harshaw Chemical Co. Div. of Kewanee
Oil Co.
WJ
Warner-Jenkinson Manufacturing Co.
HST
HP
American Hoechst Corp.
YAW
Young Aniline Works, Inc.
Note. — For complete
ss and addresses of the above reporting companies, refer to table 1 in the Appendix.
ORGANIC PIGMENTS 91
As the terms are used in this report, organic pigments are toners and
lakes derived in whole or in part from benzenoid chemicals and colors . They
are used in paints and related products, in printing inks, and in plastics
and resin materials.
Statistics on production and sales o£ all organic pigments in 1970 are
given in table 1. If Statistics on sales of a few selected pigments by com-
mercial forms (dry full-strength form, dry extended form, dry dispersions,
aqueous dispersions, and flushed colors) are given in table lA. Individiual
toners and lakes are identified in this report by the names used in the second
edition of the Colour Index.
Total production of organic pigments in 1970 was 56.5 million pounds--7.4
percent less than the 61.0 million pounds produced in 1969 and 5.2 percent
more than the 53.7 million pounds produced in 1968. Total sales of organic
pigments in 1970 amounted to 47.2 million pounds, valued at $123.0 million,
compared with 50.8 million pounds, valued at $133.1 million, in 1969 and 45.8
million pounds, valued at $119.9 million, in 1968. In terms of quantity,
sales of organic pigments in 1970 were 7.1 percent less than in 1969 and 3.0
percent greater than in 1968; in terms of value, sales in 1970 were 7.6 per-
cent less than in 1969 and 2.5 percent greater than in 1968.
Production of toners in 1970 amounted to 52.5 million pounds--8.3 percent
less than the 57.3 million pounds reported for 1969. Sales in 1970 were 43.8
million pounds, valued at $119.4 million, compared with 47.4 million pounds,
valued at $129.3 million, in 1969. Sales in 1970 were thus 7.6 percent less
than those in 1969 in terms of quantity, and 7.7 percent less in terms of
value. The individual toners listed in the report which were produced in the
largest quantities in 1970 were Pigment Yellow 12, 5.1 million pounds; Pigment
Blue 19, 4.6 million pounds; and Pigment Blue 15, beta form, 4.2 million pounds,
Production of lakes totaled 4.0 million pounds in 1970--7.5 percent more
than the 3.7 million pounds reported for 1969. Sales of lakes in 1970 amount-
ed to 3.4 million pounds, valued at $3.6 million, compared with sales in 1969
of 3.4 million pounds, valued at $3.8 million. Sales in 1970 were thus equal
to those in 1969 in terms of quantity, and 5.9 percent less in terms of value.
For each of 15 selected pigments, or groups of pigments, table lA gives
data on sales by commercial forms. Pigment Yellow 12, Pigment Red 90, and
Pigment Blue 19 were sold principally in the flushed form. The remaining 12
pigments, or groups of pigments, for which statistics are published were sold
principally in the dry full-strength form. Statistics on sales by commercial
forms could not be published for Pigment Red 49, sodium toner, without reveal-
ing the operations of individual companies .
1/ See also table 2 which lists these products and identifies the manu-
facturers by code. These codes are given in table 3.
92
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE L --Organic pigments: U.S. production and sales, 1970
[Listed below are all organic pigments for which any reported data on production or sales may be published. (Leaders
are used where the reported data are accepted in confidence and may not be published or where no data were reported.)
Table 2 lists all organic pigments for which data on production or sales were reported and identifies the manufac-
turers of each]
Pigment
Quantity
1,000
pounds
Grand total
TONERS
Total
Yellow toners, total
Acetoacetarylide yellows, total
Pigment Yellow 1, C.I. 11 680
Pigment Yellow 3, C.I. 11 710
Pigment Yellow 4, C.I. 11 665
Pigment Yellow 74, C.I. 11 741
Other acetoacetarylide yellows
Benzidine yellows, total
Pigment Yellow 12, C.I. 21 090
Pigment Yellow 13, C.I. 21 100
Pigment Yellow 14, C.I. 21 095
Pigment Yellow 17, C.I. 21 105
Other benzidine yellows
All other
Orange toners, total
Pigment Orange 5, C.I. 12 075
Pigment Orange 13, C.I. 21 110
Pigment Orange 16, C.I. 21 160
Pigment Orange 34, C.I. 21 115
All other
Red toners, total
Naphthol reds, total
Pigment Red 2, C.I. 12 310
Pigment Red 5, C.I. 12 490
Pigment Red 17, C.I. 12 390
Pigment Red 18, C.I. 12 350
Pigment Red 22, C.I. 12 315
Pigment Red 23, C.I. 12 355
Other naphthol reds
Pigment Red 1, C.I. 12 070, dark
Pigment Red 1, C.I. 12 070, light
Pigment Red 3, C.I. 12 120
Pigment Red 4, C.I. 12 085
Pigment Red 6, C.I. 12 090
Pigment Red 38, C.I. 21 120
Pigment Red 48, C.I. 15 865
Pigment Red 49, C.I. 15 630:
Barium toner
Calcium toner
Sodium toner
Pigment Red 52, C.I. 15 860
Pigment Red 53, C.I. 15 585, barium toner-
Pigment Red 54, C.I. 14 830, calcium toner
Pigment Red 57, C.I. 15 850, calcium toner
Pigment Red 63, C.I. 15 880
Pigment Red 81, C.I. 45 160, PMA
Pigment Red 81, C.I. 45 160, PTA
Pigment Red 90, C.I. 45 380
All other
Violet toners, total
Pigment Violet 1, C.I. 45 170, PMA
Pigment Violet 1, C.I. 45 170, PTA
Pigment Violet 3, C.I. 42 535, fugitive---
52,547
1,379
427
198
282
472
8,489
5,100
439
1,866
444
640
370
828
231
135
280
83
21,678
53
87
152
250
117
105
1,656
176
92
2,904
4,021
1,431
189
1,890
2,176
87
1,176
38
509
101
1,754
2,588
2,252
109
561
1,000
pounds
47,166
1,092
359
109
22
228
374
6,201
3,634
1,485
294
788
130
912
313
133
270
18,472
150
152
93
106
1,395
184
2,567
3,931
1,279
191
1,731
1,943
73
1,013
978
1,761
2,131
1,000
dollars
20,410
2,779
737
252
50
745
995
16,072
7,924
3,669
878
3,601
1,559
2,494
527
453
750
291
473
36,570
1,965
122
240
155
33
265
508
642
129
144
2,362
298
66
460
4,796
4,443
1,511
236
2,779
2,768
165
1,617
73
2,419
583
1,979
7,777
13,855
385
524
768
6.72
1.44
See footnotes at end of table.
ORGANIC PIGMENTS
93
TABLE I. --Organic pigments: U.S. production and sales, 1970- -Continued
Pigment
TONERS--Continued
Violet toners--Continued
Pigment Violet 3, C.I. 42 535, PMA
Pigment Violet 3, C.I. 42 535, PTA
Pigment Violet 23, C.I. 51 319
All other
Blue toners, total
Pigment Blue 1, C.I. 42 595, PMA
Pigment Blue 1, C.I. 42 595, PTA
Pigment Blue 14, C.I. 42 600, PMA
Pigment Blue 15, C.I. 74 160, alpha form
Pigment Blue IS, C.I. 74 160, beta form
Pigment Blue 19, C.I. 42 750A
Pigment Blue 22, C.I. 69 810
Pigment Blue 25, C.I. 21 180
All other
Green toners, total
Pigment Green 1, C.I. 42 040, PMA
Pigment Green 1, C.I. 42 040, PTA
Pigment Green 2, C.I. 42 040 and 49 005, PMA-
Pigment Green 2, C.I. 42 040 and 49 005, PTA-
Pigment Green 7, C.I. 74 260
Pigment Green 8, C.I. 10 006
Pigment Green 10, C.I. 12 775
Pigment Green 36, C.I. 74 265
All other
Brown toners, total
Pigment Brown 5, C.I. 15 800
All other
Black toners
LAKES
Total
Red lakes :
Pigment Red 60, C.I. 16 105
Pigment Red 83, C.I. 58 000
(Acid Red 26), C.I. 16 150
Violet lakes: Pigment Violet 5, C.I. 58 055---
All other lakes^
1,000
pounds
442
62
203
875
216
6
117
3,581
4,204
4,596
26
191
277
3,976
60
55
,143
153
205
348
3,977
277
49
223
102
3,326
Quantity
1,000
pounds
187
786
11.122
157
5
101
3,208
3,494
3,797
18
186
156
54
44
2,653
129
177
174
100
100
272
46
225
108
2,761
1,000
dollars
1,245
3,122
7,811
35,113
743
31
482
9,894
11,209
8,837
306
576
1,035
12,411
56
96
311
175
9,433
170
1,077
663
430
224
3,612
495
170
110
254
2,583
' Calculated from rounded figures.
Includes all black, blue, green, orange, yellow lakes, "all other" red, and "all other" violet lakes.
Note. --The C.I. (Colour Jndex^ numbers shown in this report are the identifying numbers given in the second
edition of the Colour Index.
The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic Cincluding phosphotungstomolybdic)
acids, respectively.
462-669 O - 72 - 7
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE lA.-
■U.S. sales of selected dry full-strength colors, dry extended colors, dry dispersions,^
aqueous dispersions, and flushed colors, 1970
Selected pigments by commercial forms
Quantity
Pigment Yellow 12, C.I. 21 090, total
Dry full-strength toner
Dry e.xtended toner, dry dispersions, and aqueous dispersions^ ''
Flushed color
Pigment Yellow 13, C.I. 21 100; Pigment Yellow 14, C.I. 21 095; Pigment Yellow 17
C.I. 21 105; and other benzidine yellows, total
Dry full-strength toner, dry e.xtended toner, and dry dispersions'"
Aqueous dispersions'
Flushed color
Pigment Red 3, C.I. 12 120, total
Dry full-strength toner and dry extended toner"
Aqueous dispersions^
Flushed color
Pigment Red 48, C.I. 15 865, total
Dry full-strength toner, dry extended toner, and dry dispersions'*
Aqueous dispersions'
Flushed color
Pigment Red 49, C.I. 15 630, barium toner, total
Dry full-strength toner
Dry dispersion and aqueous dispersion' *
Flushed color
Pigment Red 49, C.I. 15 630, calcium toner, total
Dry full-strength toner and dry dispersions'*
Aqueous dispersions' and flushed color'*
Pigment Red 49, C.I. 15 630, sodium toner"*
Pigment Red 53, C.I. 15 585, barium toner, total
Dry full-strength toner, dry extended toner, and dry dispersions"
Aqueous dispersions' and flushed color"
Pigment Red 90, C.I. 45 380, total
Dry full-strength toner, dry extended toner, and dry dispersions"
Flushed color
Pigment Violet 3, C.I. 42 535, fugitive, total
Dry full -strength toner
Dry extended toner and flushed color'
Pigment Violet 3, C.I. 42 535, PMA, total
Dry full-strength toner
Dry extended toner, dry dispersion and aqueous dispersions' "
Flushed color
Pigment Blue 15, C.I. 74 160, alpha form, total
Dry full-strength toner
Dry extended toner
Dry dispersions
Aqueous dispersions'
Flushed color
1,000
5,634
963
114
!,557
2,567
1,000
dollars
8,168
2,076
248
5,844
8.183
6,127
1,416
640
2,567
;,421
91
1,535
146
758
4,796
4,563
119
114
1,279
1,105
174
1,943
1,166
777
119
859
1,627
1,307
320
1,652
1,159
278
255
3,208
1,710
188
143
765
402
246
1,849
442
326
1,336
966
127
243
9,957
5,741
660
464
1,781
1,311
See footnotes at end of table.
ORGANIC PIGMENTS
95
TABLE IA.--U.S. sales of selected dry full- strength colors, dry extended colors, dry dispersions,
aqueous dispersions, and flushed colors, 1970- -Continued
Selected pigments by conmercial forms
Quantity'
Unit
value^
1,000
pounds
1,000
dollars
Pigment Blue IS, C.I. 74 160, beta form, total
Dry full-strength toner, dry extended toner and dry dispersions
Aqueous dispersions^
Flushed color
Pigment Blue 19, C.I. 42 750A, total
Dry full-strength toner
Aqueous dispersions'
Flushed color
Pigment Green 7, C.I. 74 260, total
Dry full-strength toner
Dry extended toner
Aqueous dispersions^
Dry dispersions and flushed color''
1,812
403
1,279
6,243
1,159
4,145
483
318
2,996
2,653
1,203
746
9,434
1,082
434
857
280
4,048
1,714
2,572
1,100
Per
pound
3.24
2.33
2.49
2.35
2.30
3.56
3.74
3. 95
3.00
3.93
^ Quantity of the various commercial forms is given in terms of dry full-strength toner (or dry lake) content.
^ Calculated from rounded figures .
' Includes presscake.
'* Separate data on these commercial forms may not be published without revealing the operations of individual
companies.
Note.— The C.I. (Colour Index) numbers shown in this report are the identifying numbers given in the second
edition of the Colour Index.
The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic [including phosphotungstomolybdic)
acids, respectively.
96
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Organic pigments for which U.S. production or sales were reported,
identified by manufacturer, 1970
[Organic pigments for which separate statistics are given in table 1 are marked below with an asterisk (*); products
not so marked do not appear in table 1 because the reported data are accepted in confidence and may not be pub-
lished. Manufacturers' identification codes shown below are taken from table 3. An x signifies that the manufac-
turer did not consent to his identification with the designated product]
Pigment
Manufacturers ' identification codes
(according to list in table 3)
TONERS
*Yellow toners:
*Acetoacetarylide yellows:
♦Pigment Yellow 1, C.I. 11 680
♦Pigment Yellow 3, C.l. 11 710
♦Pigment Yellow 4, C.l. 11 665
Pigment Yellow 5, C.l. 11 660
Pigment Yellow 6, C.I. 11 670
Pigment Yellow 9, C.I. 11 720
Pigment Yellow 49, C.I. 11 765
Pigment Yellow 73
♦Pigment Yellow 74, C.I. 11 741
Pigment Yellow 75
All other acetoacetarylide yellows---
♦Benzidine yellows:
♦Pigment Yellow 12, C.I. 21 090
♦Pigment Yellow 13, C.I. 21 100
♦Pigment Yellow 14, C.I. 21 095
♦Pigment Yellow 17, C.I. 21 105
Pigment Yellow 76
Pigment Yellow 83
Pigment Yellow 97
All other benzidine yellows
Pigment Yellow 10, C.I. 12 710
Pigment Yellow 11, C.I. 10 235
Pigment Yellow 18, C.I. 49 005
Pigment Yellow 19
Pigment Yellow 60, C.I. 12 705
Pigment Yellow 108, C.I. 68 420
Pigment Yellow 110
Pigment Yellow 112 C.I. 70 600
[Basic Yellow 2), C.I. 41 000 fugitive
All other
♦Orange toners :
Pigment Orange 1, C.I. 11 725
Pigment Orange 2, C.I. 12 060
Pigment Orange 4
♦Pigment Orange 5, C.I. 12 075
♦Pigment Orange 13, C.I. 21 110
Pigment Orange 15, C.I. 21 130
♦Pigment Orange 16, C.I. 21 160
♦Pigment Orange 34, C.I. 21 115
Pigment Orange 43, C.I. 71 105
CVat Orange 2), C.I. 59 705
(Vat Orange 4), C.I. 59 710
CVat Orange 15), C.I. 69 025
All other
♦Red toners :
♦Naphthol reds:
♦Pigment Red 2, C.I. 12 310
♦Pigment Red 5, C.I. 12 490
Pigment Red 9, C.I. 12 460
Pigment Red 10, C.I. 12 440
Pigment Red 13, C.I. 12 395
ACS, ACY, AMS, CPC, DUP, GAF , HSC, HSH, ICI, IMP,
KON, S, SDH, SNA, SW.
ACS, HSH, IMP, KCW, KON, PPG, S, SW.
ACS, HSC, SNA.
IMP.
CIK, IMP.
SNA.
ICI, IMP.
ACS, SNA, X.
DUP, HSC, IMP, SDH, SW.
IMP.
DUP, KCW.
ACS, ACY, AMS, APO, DUP, HSC, HSH, HST, ICC, IMP,'
KON, LVY, MRX, ROM, S, SDH, SNA, SW.
APO, BUC, GAF, HSC, HSH, HST, ICC, IMP, ROM, SDH,
SNA, SW.
ACS, ACY, AMS, BUC, CIK, CPC, DUP, GAF, HSC, HSH,
HST, ICC, IMP, KON, ROM, S, SDH, SNA, SW, x.
ACY, AMS, APO, BUC, GAF, HSC, HSH, ICC, IMP, ROM,
SDH, SNA, SW.
X.
ACS, HST.
HST.
HSH, ICC, ROM, S, SW.
SW.
LVR.
IMP.
GAF.
SW.
ACS.
ACS.
ACS.
LVR, MRX.
ACS, ACY, ICC, IMP, S, SW, TRC .
ACS.
IMP, SNA, SW, UHL.
SW.
ACY, HSC, IMP, SNA, SW.
ACS, ACY, AMS, IMP, KON, S, SNA, SW.
ACS.
ACS, DUP, GAF, HSC, HSH, HST, ICC, IMP, ROM, SDH,
SNA, SW.
BUC, ICC, ROM, SDH, SNA.
ACS, GAF.
GAF.
ACS.
ACS, TRC.
GAF, KON, SNA.
ACS, HSH, IMP, KCW, MRX, SW.
DUP, GAF, HSH, ICC, ICI, IMP, ROM, S, SDH, SW.
IMP.
KCW.
IMP, KCW, SW.
ORGANIC PIGMENTS
97
TABLE 2.
-Organic pigments for which U, S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Pigment
Manufacturers' identification codes
(according to list in table 3)
TONERS- -Continued
*Red toners --Continued
*Naphthol reds --Continued
Pigment Red IS, C.I. 12 465
♦Pigment Red 17, C.I. 12 390
♦Pigment Red 18, C.I. 12 350
♦Pigment Red 22, C.I. 12 315
♦Pigment Red 23, C.I. 12 355
Pigment Red 31, C.I. 12 360
Pigment Red 112, C.I. 12 370
All other naphthol reds
♦Pigment Red 1, C.I. 12 070, dark
♦Pigment Red 1, C.I. 12 070, light
♦Pigment Red 3, C.I. 12 120
♦Pigment Red 4, C.I. 12 085
♦Pigment Red 6, C.I. 12 090
♦Pigment Red 38, C.I. 21 120
Pigment Red 41, C.I. 21 200
♦Pigment Red 48, C.I. 15 865
Pigment Red 49, C.I. 15 630:
♦Barium toner
♦Calcium toner
♦Sodium toner
♦Pigment Red 52, C.I. 15 860
Pigment Red 53, C.I. 15 585:
♦Barium toner
Sodium toner
♦Pigment Red 54, C.I. 14 830, calcium toner-
Pigment Red 55, C.I. 15 820
♦Pigment Red 57, C.I. 15 850, calcium toner-
Pigment Red 58, C.I. 15 825
♦Pigment Red 63, C.I. 15 880
Pigment Red 64, C.I. 15 800
Pigment Red 77, C.I. 15 826
Pigment Red 79, PMA
Pigment Red 81, C.I. 45 160, fugitive
♦Pigment Red 81, C.I. 45 160, PMA
♦Pigment Red 81, C.I. 45 160, PTA
Pigment Red 87, C.I. 73 310
Pigment Red 88
♦Pigment Red 90, C.I. 45 380
Pigment Red 91
Pigment Red 92
Pigment Red 94
Pigment Red 122
Pigment Red 123, C.I. 71 145
Pigment Red 168, C.I. 59 300
Pigment Red 177
Pigment Red 179, C.I. 71 130-
Pigment Red 190, C.I. 71 140
(Basic Red 2), C.I. 50 240
All other
♦Violet toners:
Pigment Violet 1, C.I. 45 170, fugitive
♦Pigment Violet 1, C.I. 45 170, PMA
♦Pigment Violet 1, C.I. 45 170, PTA
♦Pigment Violet 3, C.I. 42 535, fugitive
♦Pigment Violet 3, C.I. 42 535, PMA
DUP.
ACY, ICC, IMP, SNA, SW, UHL.
ACS, IMP, SW.
ACY, DUP, GAP, IMP, MRX, ROM, SNA, SW.
ACS, ACY, BUC, DUP, IMP, ROM, SDH, SNA.
SNA.
IMP.
ICC, KCW, ROM, S, SDH, SNA, SW.
ACY, AMS, HSC, HSH, IMP, KON, LVY, SW.
ACY, HSC, HSH, IMP, PPG, SHD.
ACY, CIK, CPC, DUP, HSC, HSH, IMP, KCW, KON, PPG,
SDH, SNA, SW, UHL.
ACY, AMS, HSC, IMP, KON, MRX, SNA, UHL.
DUP, HSC, HSH, KCW, KON, SW.
ACS, DUP, GAP, ICC, SNA, SW.
ACS.
ACS, ACY, AMS, DUP, GAP, HSC, HSH, ICC, IMP, KON,
LVY, MRX, S, SNA, SW.
ACY, AMS, CIK, HSC, IMP, KON, LVY, SDH, SNA, SW,
UHL.
ACY, AMS, CIK, HSC, IMP, LVY, PPG, SDH, SNA, SW.
ACY, AMS, HSC, KON, SDH, SW.
AMS, HSC, HSH, IMP, SNA, SW.
ACY, AMS, CIK, HSC, IMP, KON, LVY, MGR, MRX, SDH,
SNA, SW.
KON.
HSH, IMP, SDH.
DUP, HSH.
AMS, CIK, DUP, HSC, IMP, KON, LVY, MGR, SDH, SNA,
SW.
DUP, GAP, IMP.
ACS, HSH, IMP, KON, SNA, SW.
ACS.
SW.
GAP.
SNA.
CPC, DUP, GAP, IMP, KON, LVR, LVY, MGR, MRX, S,
SNA, TCD, UHL.
ACY, AMS, DUP, GAP, HSC, IMP, KCW, KON, LVR, MGR,
MRX, S, SNA, UHL.
ACS, TCD.
ACS, SDH.
AMS, ICC, IMP, LVR, LVY, SDH, SNA, TCD.
TCD.
TCD.
TCD.
ACS, ACY, SNA.
ACS.
ACS, TRC.
TRC.
ACS.
ACS, GAP, HSC, SNA.
GAP.
ACS, DUP, HAM, HSC, SW, x.
UHL.
GAP, IMP, LVR, MGR, MRX, SNA, UHL.
ACY, AMS, DUP, GAP, HSC, IMP, MGR, MRX, SNA.
ACY, AMS, HSC, IMP, KON, LVY, MGR, UHL.
AMS, CIK, DUP, GAP, HSC, IMP, KON, LVR, LVY, MGR,
MRX, PPG, SDH, SNA, SW, UHL.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. --Organic pigments for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Pigment
Manufacturers' identification codes
Caccording to list in table 3)
TONERS--Continued
42 535, PTA-
*Violet toners --Continued
•Pigment Violet 3, C.I.
Pigment Violet 5, C.I. 58 055
Pigment Violet 19, C.I. 46 500
♦Pigment Violet 23, C.I
Pigment Violet 31, C.I
Pigment Violet 36, C.I
Pigment Violet 38, C.I
All other
*Blue toners:
♦Pigment Blue 1, C.I. 42 595, PMA-
*Pigment Blue 1, C.I. 42 595, PTA-
Pigment Blue 2, C.I. 44 045, PMA-
C.I. 42 025, PMA-
51 319-
60 010-
73 385-
73 395-
Pigment Blue 9
Pigment Blue 9
Pigment Blue 10
Pigment Blue 10
♦Pigment Blue 14
Pigment Blue 14
♦Pigment Blue 15
42 025,
. 44 040
. 44 040
. 42 600
PTA
PMA
PTA
PMA
42 600, PTA
74 160, alpha form-
*Pigment Blue 15, C.I. 74 160, beta form-
♦Pigment Blue 19, C.I. 42 750A
♦Pigment Blue 22, C.I. 69 810-
♦Pigment Blue 25, C.I. 21 180-
Pigment Blue 64, C.I. 69 825-
(Basic Blue 2)
All other
♦Green toners :
♦Pigment Green 1
♦Pigment Green 1
♦Pigment Green 2
♦Pigment Green 2
Pigment Green 4
Pigment Green 4, C.I
Pigment Green 4, C.I
♦Pigment Green 7, C.I
C.I.
C.I.
42 040, PMA
42 040, PTA
42 040 and 49 005, PMA-
42 040 and 49 005, PTA-
42 000, fugitive
42 000, PMA
42 000, PTA
74 260
♦Pigment Green 8, C.I. 10 006-
♦Pigment Green 10, C.I. 12 775
♦Pigment Green 36, C.I. 74 265
Pigment Green 38
'Brown toners :
Pigment Brown 1, C.I
Pigment Brown 2, C.I
Pigment Brown 3, C.I
Pigment Brown 3, C.I
♦Pigment Brown 5, C.I
Pigment Brown 28, C.I. 69 015
All other
♦Black toners:
Pigment Black 1, C.I. 50 440-
All other
12 480
12 071
21 010, fugitive-
21 010, PMA
15 800
LAKES
Yellow lakes:
(Acid Yellow 25^, C.I. 19 140 —
(Acid Yellow 73), C.I. 45 3S0--
Orange lakes:
Pigment Orange 7, C.I. 15 530--
Pigment Orange 17, C.I. 15 510-
All other
ACY, AMS, HSC, IMP, KON, MRX , SNA, SW, TCD.
S.
ACS, DUP, SNA.
ACS, ACY, BUC, GAP, HST, ROM, SDC, SNA.
DUP.
ACS.
ACS.
BUC, ICC, IMP, ROM.
DUP, GAP, IMP, KON, LVY, MGR, MRX, SNA, SW, TCD,
UHL.
AMS, GAP, IMP, KON, MGR, SNA.
GAP.
LVR, MRX.
GAP, IMP, MGR.
IMP, LVR, SDH.
IMP.
DUP, GAP, IMP, LVR.
DUP, GAP.
ACS, ACY, DUP, GAP, HSC, ICC, ICI, IMP, MGR, SNA,
SW, TMS, TRC.
ACS, ACY, AMS, BUC, DUP, GAP, HSC, ICC, IMP, LVY,
ROM, SNA, SW, TMS.
ACY, AMS, HSC, SW, TCD.
ACS, DUP, TCD, TRC.
ACS, DUP, GAP, ICC, S.
ICI, TRC.
IMP .
DUP, GAP, S, SDH, TNI.
GAP, IMP, MRX, S, UHL.
ACY, IMP, MGR.
GAP, IMP, KON, LVY, MGR, MRX, UHL.
AMS, DUP, IMP, KON, LVY, MRX, S, SDH.
GAP.
GAP, KON, MGR.
ACY, AMS, IMP, KON, MGR.
ACS, ACY, CIK, DUP, GAP, HSC, IMP, SNA, SW, TMS,
TRC.
HSH, IMP, KCW.-
DUP, HSC, IMP, SNA, SW.
ACY, GAP, SNA.
ACS, DUP.
ICI.
HSH.
KON.
KCW, KON.
ACS, BUC, HSH, ICC, ROM, SNA.
GAP, TRC.
GAP, ICC, SDH.
SNA.
DUP, GAP, UHL.
KON, MGR, MRX.
TCD.
CPC.
IMP, KCW, KCN.
HAM.
ORGANIC PIGMENTS
99
TABLE 2. — Organic pigments for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Pigment
Manufacturers' identification codes
(according to list in table 3)
LAKES— Continued
Red lakes:
^Pigment Red 60, C.I. 16 lOS
'Pigment Red 83, C.I. 58 000
(Acid Red 17), C.I. 16 180
*(Acid Red 26), C.I. 16 150
HSH, KON, MRX, SNA.
HSH, IMP, KON, MRX, UHL.
IMP.
CPC, HAM, IMP, KCW.
KON.
KON.
HAM, IMP.
ACS, DUP, HSH, IMP, KON, UHL.
SW.
HAM.
CPC, KCW.
AMS, KON, LVY, SDH.
LVR.
CPC, KCW.
IMP.
CPC, KON.
HAM.
(Natural Red 4), C.I. 75 470
Violet lakes:
'Pigment Violet 5, C.I. 58 055
Pigment Violet 20, C.I. 58 225
All other
Blue lakes:
Pigment Blue 17, C.I. 74 180
Pigment Blue 24, C.I. 42 090
(Acid Blue 93), C.I. 42 780
(Acid Blue 104), C.I. 42 735
Green lakes
Black lakes:
(Natural Black 3), C.I. 75 291
Note. --The C.I. (Colour Index) numbers shown in this report are the identifying codes given in the second edition of
the Colour Index.
When the name of a color is enclosed in parentheses, it indicates that this name is that of the dye from which the
pigment can be made and that no name for the pigment itself is given in the Colour' Index.
The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic)
acid, respectively.
100 SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 3. --Organic pigments: Directory of manufacturers, 1970
ALPHABETICAL DIRECTORY BY CODE
[Names of organic pigment manufacturers that reported production or sales to the U.S. Tariff Commission for 1970
are listed below in the order of their identification codes as used in table 2]
Code
Code
identi-
Name of company
identi-
Name of company
fication
fication
ACS
Allied Chemical Corp., Specialty Chemicals
Div.
KON
H. Kohnstamm § Co., Inc.
ACY
American Cyanamid Co.
LVR
C. Lever Co. , Inc.
AMS
Martin-Marietta Corp., Ridgway Color §
Chemical Div.
LVY
Cities Service Co., Levey Div.
APO
Apollo Colors, Inc.
MGR
Magruder Color Co., Inc.
MRX
Max Marx Color § Chemical Co.
BUC
Blackman-Uhler Chemical Co.
PPG
PPG Industries, Inc.
CIK
Tenneco Chemicals, Inc., Cal/Ink Div.
CPC
Childs Pulp Colors, Inc.
ROM
United Merchants 6 Manufacturers, Inc.,
Roma Chemical Div.
DUP
E. I. duPont de Nemours § Co., Inc.
S
Sandoz, Inc., Sandoz Color S Chemicals
GAF
GAF Corp., Chemical Div.
Div.
SDC
Martin-Marietta Corp., Southern Dyestuff
HAM
Hampden Color 6 Chemical Co.
Co. Div.
HSC
Chemetron Corp., Pigments Div.
SDH
Sterling Drug, Inc., Hilton-Davis
HSH
Harshaw Chemical Co. Div. of Kewanee
Chemical Co. Div.
Oil Co.
SNA
Sun Chemical Corp., Pigments Div.
HST
American Hoechst Corp.
SW
The Sherwin-Williams Co.
ICC
Inmont Corp .
TCD
Tenneco Chemicals, Inc., Tenneco Colors
ICI
ICI America, Inc.
Div.
IMP
Hercules, Inc., Imperial Color & Chemical
TMS
Sterling Drug, Inc., Thomasset Colors Div.
Dept .
TNI
Gillette Co., Chemical Division
TRC
Toms River Chemical Corp.
KCW
Keystone Color Works, Inc.
UHL
Paul Uhlick & Co., Inc.
Note. --For complete names and addresses of the above reporting companies, refer to table 1 in the Appendix.
MEDICINAL CHEMICALS 101
Medicinal chemicals include the medicinal and feed grades of all
organic chemicals having therapeutic value, whether obtained by chemical
synthesis, by fermentation, by extraction from naturally occurring
plant or animal substances, or by refining a technical grade product.
They include antibiotics and other anti- infective agents, antihistamines
autonomic drugs, cardiovascular agents, central nervous system depres-
sants and stimulants, hormones and synthetic substitutes, vitamins, and
other therapeutic agents for human or veterinary use and for animal feed
supplements.
Table 1 shows statistics for production and sales of medicinal
chemicals grouped by pharmacological class, while table 2 lists sepa-
rately each product for which data were reported and identifies the
manufacturers.^ The statistics shown in table 1 are for bulk chemicals
only; finished pharmaceutical preparations and products put up in pills,
capsules, tablets, or other measured doses are excluded. The difference
between production and sales reflects inventory changes, processing
losses, and captive consumption of medicinal chemicals processed into
ethical and proprietary pharmaceutical products by the primary manu-
facurer. In some instances, the difference may also include quantities
of medicinal grade products used as intermediates, e.g., penicillin G
salts used as intermediates in the manufacture of semisynthetic peni-
cillins. All quantities are given in terms of 100-percent content of
the pure bulk drug.
Total U.S. production of bulk medicinal chemicals in 1970 amounted
to 214 million pounds, or 7.2 percent more than the 200 million pounds
produced in 1969 and 21.0 percent more than the 177 million pounds pro-
duced in 1968. Total sales of bulk medicinal chemicals in 3 970 amounted
to 155 million pounds, valued at $510 million, compared with sales in
1969 of 145 million pounds, valued at $462 million, and sales in 1968
of 123 million pounds, valued at $415 million. In terms of quantity,
sales in 1970 were thus 6.7 percent larger than in 1969 and 26.1 per-
cent larger than in 1968. In terms of value, sales in 1970 were 10.4
percent larger than in 1969 and 22.9 percent larger than in 1968.
Production of the more important groups of medicinal chemicals in
1970 was as follows: Antibiotics, 16.9 million pounds (28.3 percent
larger than in 1969), of which 9.6 million pounds was for medicinal
"^ See table 3 for a list of manufacturers and their identification
codes .
2 Complementary statistics on the dollar value of manufacturers'
shipments of finished pharmaceutical preparations, except biologicals,
are published annually by the U.S. Department of Commerce, Bureau of
the Census, in Current Industrial Reports, Series MA-28G. Many pharma-
ceutical manufacturers who report to the Bureau of the Census are ex-
cluded from the Tariff Commission report because they are not primary
producers of medicinal chemicals, that is, they do not themselves pro-
duce the bulk drugs which go into their pharmaceutical products but
purchase their drug requirements from domestic or foreign producers.
102 SYNTHETIC ORGANIC CHEMICALS, 1970
use and 7.3 million pounds was for other uses; anti-infective agents
other than antibiotics, 34.0 million pounds (0.8 percent larger than
in 1969); central nervous system depressants and stimulants, 49.9 mil-
lion pounds (3.9 percent smaller); gastrointestinal agents, 62.5 million
pounds (7.1 percent larger); and vitamins, 22.9 million pounds (29.9
percent larger) . Production of some of the more important individiual
products listed in table 1 was as follows: Choline chloride, 39.6 million
pounds (6 percent smaller than in 1969); aspirin, 35.2 million pounds
(6 percent smaller); salicylic acid, 14.1 million pounds (3 percent
larger); ascorbic acid, 9.8 million pounds (41 percent larger);
piperazine base and salts, 7.8 million pounds (2 percent smaller);
anti-infective sulfonamides, 5.9 million pounds (21 percent larger);
penicillins (except semi-synthetic), 3,760 trillion units (53 percent
larger); tetracyclines, 2.3 million kilograms (13 percent larger);
vitamin A, 1,274 trillion units (7 percent larger); and vitamin E, 600
billion units (26 percent larger) .
MEDICINAL CHEMICALS
TABLE 1.- -Medicinal chemicals: U.S. production and sales, 1970
103
ft
[Listed below are all synthetic organic medicinal chemicals for which any reported data on production or sales may
be published. (Leaders are used where the reported data are accepted in confidence and may not be published or
where no data were reported.) Table 2 lists all medicinal chemicals for which data on production or sales were
reported and identifies the manufacturers of each]
Quantity
Grand total
Acyclic
Benzenoid'
Cyclic nonbenzenoid"*
Antibiotics, total ^
For medicinal use, total
Antifungal and antitubercular antibiotics
Bacitracin
Penicillin G, potassium^
Penicillins^ (semi-synthetic), total
Ampicillin
All other
Other antibiotics for medicinal use
For other uses, total
Bacitracin
All other
Antihistamines, total
Antinauseants
Chlorphenirajnine maleate
All other
Anti-infective agents (except antibiotics), total
Antimony, bismuth, and mercury compounds
Phenolic antiseptics and disinfectants
Piperazine base and salts, total
Piperazine
All other
Quinoline derivatives, total
Diiodohydroxyquin
Oxyquinoline benzoate
All other
Sulfonamides, total
Phthalylsulfacetamide
All other
Other anti-infective agents, total
Antibacterial agents and general antiseptics, total--
Antileprotic and antitubercular agents-r
Urinary antiseptics, total
Methenamine salts
All other
Other antibacterial agents and general antiseptics-
Ant ifungal agents
Antiprotozoan agents
All other'
Autonomic drugs, total
Parasympatholytic (anticholinergic) quaternary ammonium
compounds .
Parasympatholytic (anticholinergic) tertiary amines
1,000
pounds
214,471
82,281
111,440
20,750
9,638
954
15
2,166
883
684
199
5,620
7,301
420
6,881
363
33,984
288
450
7,849
3,817
4,032
377
16
3
358
5,943
16
5,927
19,077
2,682
222
599
499
100
1,861
8,962
7,433
1,000
pounds
1,000
dottars
510,059
67,206
73,438
13,870
7,216
44,705
351.113
114,241
,934
757
3,163
3,282
389
2,893
187
175
23,871
327
5,184
1,276
3,908
185
1,643
16,518
811
7,609
7,597
112,475
11,567
1,177
99,731
32,972
6,118
26,854
7,003
169
6,834
96,544
528
3,691
1,030
2,661
930
7,224
84,133
1,111
605
42,086
40,331
See footnotes at end of table.
104
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. --Medicinal chemicals: U.S. production and sales, 1970- -Continued
Production'
Quantity
Autonomic drugs--Continued
Sympathomimetic (adrenergic) agents, total
Epinephrine hydrochloride (racemic)
Phenylpropanolamine hydrochloride
All other
Other autonomic drugs
Cardiovascular agents, total
Vasodilators
Other cardiovascular agents
Central depressants and stimulants, total
Amphetamines, total
Amphetamine base and sulfate (racemic)
All other
Analgesics and antipyretics, total
Aspirin
Salicylates [except aspirin)
_:^-, All other
- Antidepressants
Barbiturates
Hydrocodone bitartrate
Hypnotics and sedatives (except barbiturates)
Skeletal muscle relaxants and tranquilizers, total
Meprobamate
All other
Other central depressants and stimulants'
Dermatological agents and local anesthetics, total--
Salicylic acid
All other
Diagnostic agents, total
Roentgenographic contrast media
All other
Expectorants and mucolytic agents, total
Ethylenediamine dihydr iodide
All other
Gastrointestinal agents, total
Choleretics and hydrocholeretics
Choline chloride (all grades)
All other
Hematological agents
Hormones and synthetic substitutes, total
Corticosteroids
Synthetic hypoglycemic agents
All other
Renal-acting and edema-reducing agents, total
Mercurial diuretics
Theophylline derivatives
All other
Therapeutic nutrients, total
Amino acids and salts
Calcium salts
Ferrous gluconate
Other therapeutic nutrients
1,000
pounds
292
230
1.391
121
1,270
49,943
34
44
43,457
35,170
2,741
5,546
159
1,003
')
562
1,206
1,206
3,478
14,126
1,478
2,617
1,224
1,393
124
39,563
22,793
1,511
1,269
192
1,463
79
1,384
3,626
2,159
741
591
135
1,000
pounds
302
154
20
56
27,294
2,511
24,783
t»)
767
561
206
2,783
14,438
13,710
728
2,481
1,111
1,370
53,307
67
74
2,497
1,230
763
1,000
dollars
6,104
83
1,842
4,179
1,573
483
49,047
2,536
46,511
2,394
267
4,948
1,414
3,534
19,864
7,014
5,447
1,567
4,599
2,206
2,393
22,289
16,551
1,087
15,464
19
270
4,661
3,031
1,984
498
MEDICINAL CHEMICALS 105
TABLE L --Medicinal chemicals: U.S. production and sales, 1970- -Continued
I
Production'
Quantity
Unit
value^
Vitamins, total
Vitamin A alcohol and esters, total"
Vitamin A palmitate (feed grade]
All other
Vitamin B-complex, total
Niacin (all grades)
Niacin (feed grade)
Niacinamide
Pantothenic acid and derivatives, total
Calcium pantothenate (racemic) (feed grade) -
All other
Other B-complex vitamins
Vitamin C, total
Ascorbic acid
All other
Vitamin d"
Vitamin E"
Vitamin K
1,000
pounds
22,915
1,000
pounds
17.055
1,428
990
458
8,079
2,555
1,559
2,159
1,424
755
2,228
12,059
9,832
2,227
13
1,105
251
Miscellaneous medicinal chemicals
970
684
286
6,284
1,257
1,428
1,456
761
675
2,165
893
70
1,139
1,000
dollars
84.065
21,222
11,660
9,562
51,455
1,552
2,448
5,855
1,650
2,205
25,798
15,426
1,129
16,541
492
32.461
Per
Dound
21.88
17.05
33.43
5.01
1.08
1.71
2.68
2.17
5.27
11.00
1.52
141.12
18.30
7.05
1 The data on production and sales are for bulk medicinal chemicals only; they exclude finished preparations
and dosage-form products, which are manufactured from bulk chemicals. All quantities are given in terms of
100% active ingredient.
2 Calculated from rounded figures .
3 The term "benzenoid," as used in this report, describes any cyclic medicinal chemical whose molecule con-
tains either a six-membered carbocylic ring with conjugated double bonds (e.g., the benzene ring or the quinone
ring) or a six-membered heterocyclic ring with 1 or 2 hetero atoms and conjugated double bonds, except the
pyrimidine ring (e.g., the pyridine ring or the pyrazine ring.)
"* Includes antibiotics of unknown structure.
5 With the exception of bacitracin, the penicillins (except semi-synthetic), and a few other antibiotics which
were reported in terms of U.S. P. units, all quantities for antibiocics were reported as grams of antibiotic base.
(Thus production of 480,900 grams of tetracycline hydrochloride, for example, would have been reported as 444.430
grams of tetracycline base.) For inclusion in the main statistical table, all quantities were converted from
grams of antibiotic base to pounds of antibiotic base (453.6 grams = 1 pound) or from U.S. P. units to pounds (22.7
million units of bacitracin, 458 million units of procaine penicillin G, 723 million units of potassium peni-
cillin G, etc. = 1 pound). The following tabulation shows statistics for all individually publishable antibiotics
in terms of kilograms of antibiotic base (Kg.) or billions of U.S. P. units (BU) :
Unit of
quantity
Production
Quantity
Unit
value
Bacitracin, total
For medicinal use-
For other uses---
Penicillins (except semi-synthetics). total-
Penicillin G, potassium, for medicinal use
Penicillin G. procaine, for all uses
All other, for all uses
Penicillins (semi-synthetic), total-
Ampicillin
All other
Tetracyclines, for all uses-
9,881
351
,530
3.760,210
1.566.158
2.194.052
400.662
510,555
90,309
2,318,826
9,135
1,000
dollars
7,295
515
8.822
1.522.253
1.177
6.118
28.667
3,760.38
693.49
787.301
734,952
15.174
15.495
19.27
18.56
735,456
106
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. --Medicinal chemicals: U.S. production and sales, 1970- -Continued
Footnotes for table l--Continued
^ Production of medicinal and feed grades of all penicillins (except semi-synthetics) amounted to 5,944,000 pounds;
sales amounted to 2,732,000 pounds, valued at $28,667,000.
' Includes production and sales of anthelmintic and antiviral agents, production of antifungal agents, sales of
all other antibacterial agents and general antiseptics, and sales of antimony, bismuth, and mercury compounds.
^ Production of hydrocodone bitartrate amounted to 975 pounds, and sales amounted to 667 pounds.
9 Includes production and sales of anticonvulsants, antitussives [except hydrocodone bitartrate} and stimulants;
also includes sales of antidepressants, and hypnotics and sedatives (except barbiturates).
10 Sales of mercurial diuretics amounted to 404 pounds.
11 All quantities for vitamin A, B12, D, and E were reported in terms of grams or units, but were converted to
pounds for inclusion in the main statistical table (1.317 billion units of vitamin A acetate, 0.824 billion units
of vitamin A palmitate, 453.6 grams of vitamins B12, 18.14 billion units of vitamin D, 617,000 units of d-alpha
tocopheryl acetate, 454,000 units of dl-alpha tocopheryl acetate, etc. = 1 pound). The following tabulation shows
statistics for these vitamins, except for B12, which was not separately publishable, in terms of million of inter-
national units (MU) or billion of U.S. P. units (BU) :
Production
Quantity
1,000
dollars
Vitamin A, total
Vitamin A palmitate (feed grade) -
All other
1,273,557
Vitamin D-
Vitamin E-
815,763
457,774
243,992
599,829
563,499
289,084
137,651
494.983
11,660
9,562
1,129
16,341
20.69
33.08
8.20
33.01
Includes production and sales of antineoplastic agents, smooth-muscle relaxants, and unclassified medicinal
nicals; also includes sales of cardiovascular agents, diagnostic agents, and hematological agents.
MEDICINAL CHEMICALS
107
TABLE 2. — Medicinal chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970
[Medicinal chemicals for which separate statistics are given in table 1 are marked below with an asterisk (*); medic-
inal chemicals not so marked do not appear in table 1 because the reported data are accepted in confidence and may
not be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that the
manufacturer did not consent to his identification with the designated product]
Manufacturers ' identification codes
(according to list in table 3)
* Antibiotics:
*For medicinal use:
*Antifungal and antitubercular antibiotics:
Antifungal antibiotics:
Amphotericin B
Candicidin
Nystatin
Antitubercular antibiotics:
Cycloserine
Dihydrostreptomycin
Streptomycin
Viomycin
* Bacitracin
*Penicillin G, potassium
*Penicillins (semi-synthetic) :
*Ampicillin
*Other semi-synthetic penicillins:
Ampicillin, sodium
Carbenicillin
Cloxacillin, sodium
Dicloxacillin, sodium
Hetacillin
Methicillin, sodium
Nafcillin, sodium
Oxacillin, sodium
Phenethicillin, potassium
*Other antibiotics for medicinal use:
Cephalexin
Cephaloglycin
Cephaloridine
Cephalothin
Chloramphenical — '
Clindamycin
Erythromycin
Fumagillin
Gentamycin
Gramicidin
Kanamycin
Lincomycin
Neomycin
Novobiocin
Oleandomycin
Paromomycin
Penicillin G, benzathine
Penicillin G, procaine
Penicillin G, sodium
Penicillin 0, sodium
Phenoxymethylpenicillin (Penicillin V)--'
Phenoxymethylpenicillin, benzathine
Phenoxymethy Ipeni ci 1 1 in , hydrab amine
Phenoxymethylpenicillin, potassium
Polymyxin B
Spectinomycin
Tetracyclines:
Chlortetracycline
Demeclocycline
Doxycycline
Methacycline
Oxytetracycline
Tetracycline
Thiostrepton
Troleandomycin
Tyrothricin
OMS.
PEN.
ACY,
OMS.
COM.
MRK,
PFZ.
MRK,
PFZ.
PFZ.
COM,
PEN.
PFZ. PMP
OMS,
PFZ,
WYT.
BEE,
BRS,
OMS, WYT
BEE,
OMS,
WYT.
BEE.
BEE,
BRS.
BEE,
BRS,
WYT.
BRS.
BRS.
WYT.
BEE,
BRS.
NRS,
PFZ.
LIL.
LIL.
LIL.
LIL.
PD,
RLS.
X.
ABB,
LIL,
UPJ.
ABB.
SCH.
PEN.
BRS.
X.
OMS,
PFZ,
UPJ.
MRK,
UPJ.
PFZ.
MRK.
WYT.
OMS,
PFZ,
WYT.
OMS.
PFZ.
ABB,
BRS,
LIL, OMS
WYT.
ABB.
ABB,
LIL.
PFZ.
ABB,
X
ACY,
RLS.
ACY.
PFZ.
PFZ.
PFZ,
RLS.
ACY,
BRS,
PFZ, RLS
OMS.
PFZ.
PEN.
108
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. --Medicinal chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970--Continued
Manufacturers' identification codes
(according to list in table 3)
* Antibiotics- -Continued
*For other uses:
* Bacitracin
Chlortetracycline
Cycloheximide
Hygr omy c in B
Neomycin
Novobiocin
Ny statin
Oxytetracycline
Penicillin G, benzathine
Penicillin G, procaine
Streptomycin
Tylosin
* Antihistamines :
*Antinauseants :
Cyclizine hydrochloride
Dimenhydrinat e
Meclizine hydrochloride
Trimethobenzamide hydrochloride
Bromodiphenhydramine hydrochloride
Brompheniramine maleate
Carbinoxamine
Chlorcyclizine hydrochloride
Chlorothen citrate
*Chlorpheniramine maleate
Cyproheptadine hydroch lor ide
Dexbrompheniramine maleate
Dexchlorphenlramine maleate
Dimethindene maleate
Diphenhydramine hydrochloride
Doxy 1 amine succinate
Methapyr i 1 ene f umar at e
Methapyrilene hybenzate
Methapyr ilene hydrochloride
Phenindamine tartrate
Pheniramine maleate
Phenyl toloxamine citrate
Pyrilamine maleate
Pyrilamine resin adsorbate
Pyrrobut amine phosphate
Thenyl diamine hydrochloride
Thonzylamine hydrochloride
Tripelennaraine
Tripe lennamine citrate
Tripelennamine hydrochloride
Triprolidine hydrochloride
* Anti-infective agents (except antibiotics) :
*Antimony, bismuth, and mercury compounds;
Bismuth dipropylacetate
Bismuth sodium triglycollamate
Bismuth subsalicylate
Glycobiarsol
Merbromin
Mercuric salicylate
Nitromersol
Phenylmer curie acetate
Phenylmercuric benzoate
Phenylmercuric borate
Phenylmercuric chloride
Phenylmercuric nitrate
Stibophen
Thimerosal
COM,
DLI,
GPR, PEN, PMP
ACY,
DLL
UPJ.
LIL.
PEN,
PFZ.
UPJ.
OMS.
PFZ.
WYT.
MRK,
OMS.
MRK,
PFZ.
COM,
LIL.
BUR.
HEX,
SRL.
PFZ.
HOP.
PD.
SCH.
SCH.
ABB,
BUR.
ACY.
HEX,
HFT,
SCH, SK.
SCH.
SCH.
CGY.
CAN,
PD.
BKC.
ABB,
PYL.
LIL.
ABB,
PYL.
HOF.
HEX,
HFT,
SCH.
BRS.
HEX,
MRK,
PYL.
LIL.
SDW.
NEP.
CGY.
CGY.
CGY.
BUR.
BPC.
MAL, NOR, PEN.
PYL, SDW.
HYN.
MRK.
ABB.
WRC.
MRK.
MRK, WRC.
WRC.
MRK, WRC.
SDW.
LIL, PYL, SEL.
MEDICINAL CHEMICALS
109
TABLE 2. --Medicinal chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
* Anti-infective agents (except antibiotics) --Continued
*Phenolic antiseptics and disinfectants:
Betanaphthol'
Bithionol
Resorcinol
Thymol
Thymol iodide
*Piperazine base and salts:
*PiperaEine
Piper az ine adipat e
Piperazine citrate
Piperazine dihydrochloride
Piperazine dithiocarbamate
Piperazine hexahydr at e
Piper a z ine hydroch loride
Piperazine phosphate
Piperazine sulfate
Piperazine tartrate
*Quinoline derivatives :
Amodiaquin
Amodiaquin hydrochloride
Buquinolate
Chloroquine phosphate
*Diiodohydroxyquin
Hydroxychloroquine sulfate
8-Hydroxy-5-quinolinesulfonic acid
1 odoch 1 orhydroxyquin
Oxolinic acid
Oxyquinoline
*Oxyquinoline benzoate
Oxyquinoline citrate
Oxyquinoline potassium sulfate
Oxyquinoline sulfate
Primaquine phosphate
*Sulfonamides:
Acetyl sulfamethoxypyridazine
Acetyl sulfisoxazole
Azosulf amide
Dinsed
Mafenide acetate
Mafenide hydrochloride
*Phthalylsulfacetamide
Phthalylsulfathiazole
Succinylsulfathiazole
Sulfabenzamide
Sulfabenzamide, sodium
Sulf abromomethazine , sodium
Sulfacetamide
Sulfacetamide, sodium
Sulfachloropyrazine, sodium
Sulf ach loropyridaz ine , sodium
Sulfadiazine
Sulfadiazine, sodium
Sulfadimethoxine
Sulfaethidole
Sulfaguanidine
Sulfamerazine
Sulfamerazine, sodium
Sulfamethazine
Sulfamethazine, sodium
Sulfamethizole
Sulfamethoxazole
Sulfamethoxypyridazine
KPT,
LEM.
GIV.
MAL.
DOW,
FLM,
JCC,
UCC
PYL.
BUR.
DOW,
FLM,
JCC,
WHL
SEL.
JCC.
DOW,
JCC,
SEL.
BUR,
JCC,
PYL,
SEL
JCC.
PYL.
UOP.
SDW.
CGY,
PCW,
PYL, SRL
SDW.
MRK.
CGY,
PYL.
NEP.
FIS,
MRK.
FIS,
LEM,
MRK.
FIS,
MRK.
LEM.
FIS,
MRK,
PYL.
PD,
SDW.
ACY.
HOF.
SDW.
SAL.
SDW.
SDW.
CTN,
LEM,
PYL.
MRK,
PYL.
MRK,
PYL.
ACY.
ACY.
MRK.
CTN,
LEM,
PYL.
CTN,
LEM.
ACY.
CGY.
ACY.
ACY.
HOF.
ACY.
ACY,
SAL.
ACY,
LEM.
ACY,
CTN.
ACY,
LEM.
ACY.
ACY,
CTN.
HOF.
ACY.
See footnotes at end of table.
462-669 O - 72 - 8
SYNTHETIC ORGANIC CHEMICALS, 1970
-Medicinal chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3J
*Anti-infective agents (except antibiotics) --Continued
*Sulfonamides- -Continued
Sulfanilamide
Sulf anitran
Sulfapyridine--
Sulfapyridine, sodium
Sul f aquinoxa line
Sulfathiazole
Sulfathiazole, sodiuin
Sulfisoxazole
Sulfisoxazole, sodium
*Other anti-infective agents:
Anthelmintic agents:
Cadmium anthrani lat e
2,2-Dichlorovinyl dimethyl phosphate
Diethylcarbamazine citrate
Gentian violet
Hexy Iresorcinol
Phenothiazine
Pyrvinium pamoate
Thiabendazole
*Antibacterial agents and general antiseptics:
*Antileprotic and antitubercular agents:
Aminosalicylic acid
Ethionamide
Isoniazid
Potassium aminosalicylate
Pyrazinamide
Sodium aminosalicylate
Sodium sulfoxone
*Urinary antiseptics:
Mandelic acid
Methenamine
*Methenamine salts:
Methenamine hippurate
Methenamine mandelate
Methenamine sul fosal icy late
Methylene blue
Nitrofurantoin
Phenazopyridine hydrochloride
*Other antibacterial agents and general
antiseptics :
Acriflavine
Aminacrine
Aminacrine hydrochloride
Benzalkonium chloride
Br omof orm
Camphor , monob r omat ed
Cetalkonium chloride
Cetylpyridinium chloride
Chlorobutanol
Furalt adone
Furamazone
Iodoform^
Magnes ium salicylate
Myristyl-y-picolinium chloride
Nalidixic acid
Nitrofurazone
Nitromide
Providone - iodine complex
*Antifungal agents:
Benzoic acid
Calcium undecylenate
Fuchsin, basic
SAL.
SAL.
ACY,
CTN, MRK
ACY,
CTN.
MRK.
ACY,
MRK.
ACY,
MRK.
HOF.
HOF.
MAL.
SHC.
ACY.
SDH.
HEX,
MRK.
ABR,
ISC.
MLS.
RDA.
RIL.
MLS.
MRK.
MLS.
RIK.
ARN,
NEP, PYL
x.
ACY,
NOR.
HOF,
NEP.
ACS.
SDW.
SDW.
SDH.
DOW.
MAL,
PEN.
FIN,
SDW.
FIN,
HEX.
BPC,
PD.
NOR.
NOR.
MAL.
MAL.
UPJ.
SDH.
NOR.
PEN,
SAL.
GAF.
MON.
IfTL.
ACS.
See footnotes at end of table.
MEDICINAL CHEMICALS
111
TABLE 2. --Medicinal chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970--Continued
Manufacturers' identification codes
(according to list in table 3)
*Anti-infective agents (except antibiotics) --Continued
*Other anti-infective agents--Continued
*Antifungal agents--Continued
Sodium caprylate
Sodium undecylenate
Undecylenic acid
Zinc undecylenate
*Antiprotozoan agents:
Aklomide
Aminitrozole
Amprolium
Arsanilic acid
Carbarsone
Dimetridazole
■3,S-£)initro-o-toluamide
Furazolidone
Metronidazole
Nifursol
Nihydrazone
Nitarsone
Nithiazide
Nitrophenide
Pyrimethamine ■
Roxarsone
Roxarsone, sodium
Sodium arsanilate
Antiviral agent: Amantadine hydrochloride
*Autonomic drugs :
Parasympatholytic (anticholinergic) agents (except
tropane derivatives) :
♦Quaternary ammonium compounds:
Diphemanil methylsulfate
Hexocyclium methylsulfate
Isopropamide iodide
Mepenzolate bromide
Methanthel ine bromide
Pipenzolate bromide
Propanthe line bromide
Tridihexethyl iodide
*Tertiary amines :
Adiphenine hydrochloride
Aminopent amide
Benactyzine
Cycrimine hydrochloride
Dicyclomine hydrochloride
Orphenadrine citrate
Orphenadrine hydrochloride
Oxyphencyclimine hydrochloride
Piper ido late hydrochloride
Thiophenamil hydrochloride
Trihexyphenidyl hydrochloride
♦sympathomimetic (adrenergic) agents:
Cinnamedrine hydrochloride
Cyclopentamine hydrochloride
Epinephrine bitartrate (levo)
♦Epinephrine hydrochloride (racemic)
Isoproterenol hydrochloride
Levarterenol bitartrate
Metaraminol bitartrate
Methoxyphenamine hydrochloride
Naphazoline hydrochloride
Nordefrin hydrochloride
Nylidrin hydrochloride
LEM.
NTL.
NTL.
CFC, NTL,
WTL.
SAL.
ACY.
MRK.
WHL.
LIL, PYL, RSA, SEL, WHL.
RDA.
DOW.
NOR.
RDA.
SAL.
NOR.
SAL.
MRK.
ACY.
BUR.
SAL.
SAL.
SAL.
DUP
SK.
LKL.
SRL.
LKL.
SRL.
ACY.
CGY.
BJL.
BKL.
LIL.
BKC.
RIK.
RIK.
PFZ.
LKL.
X.
ACY, SDW.
SDW.
LIL.
SDW.
ECL, VB, X.
SDW.
SDW.
SDW.
X.
CGY.
SDW.
BKL.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.-
-Medicinal chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3}
'Autonomic drugs --Continued
* Sympathomimetic (adrenergic) agents--Continued
Phenyl ephrine
Phenylephrine bi tart rate
Phenylephrine hydrochloride
*Phenylpropanolajiiine hydrochloride
Propylhexedrine
Protokylol hydrochloride
Pseudoephedrine hydrochloride
Pseudoephedrine sulfate
Tetrahydrozoline hydrochloride
*Other autonomic drugs :
Parasympatholytic tropane derivatives:
Anisotropine methylbromide
Benztropine mesylate
Homa t rop ine
Homatropine hydrobromide
Homatropine methylbromide
Parasympathomimetic (cholinergic) agents:
Acetylcholine chloride
Methacholine chloride
Neostigmine bromide
Physostigmine salicylate
Pyridostigmine bromide
Sympatholytic (antiadrenergic) agent; Ergonovine
maleate.
*Cardiovascular agents:
'Vasodilators:
Clonitrate
Cyclandelate
Dioxyline phosphate
Ethyl nitrite
Glyceryl trinitrate
Isosorbide dinitrate
Mannitol hexanitrate
Nicotinyl alcohol tartrate
Pentaerythritol tetranitrate
*Other cardiovascular agents :
Antihypertensive agents:
Guanethidine sulfate
Hydralazine hydrochloride
Methyldopa
Pargyline hydrochloride
Rauwolfia and veratrum alkaloids:
Alkavervir
Alseroxylon
Raunormine
Reserpine
Bioflavonoids:
Hesperidin
Hesperidin methyl chalcone
Lemon bioflavonoids
Naringin
Rutin
Cardiac drugs:
Procainamide hydrochloride
Quinidine sulfate
Colestipol hydrochloride
'Central depressants and stimulants:
'Amphetamines :
'Amphetamine base and sulfate (racemic) :
Amphetamine (racemic)
Amphetamine sulfate (racemic)
Dextroamphetamine
Dextroamphetamine carboxymethyl cellulose
Dextroamphetamine hydrochloride
Dextroamphetamine phosphate
GAN, SDW.
GAN.
CTN, GAN, HEX, ORT, SDW.
ARS, BKL, HEX, NEP, ORT.
HEX, SK.
LKL.
BUR, GAN.
GAN.
PFZ.
HEX.
HEX.
CTN, HEX.
MRK.
MRK, RSA.
HEX.
PEN.
HOP.
LIL.
APD.
IKYT.
HAL.
MAL.
APD.
APD.
APD.
HOP.
APD.
CGY.
CGY.
MRK.
ABB.
RIK.
RIK.
PEN.
PEN.
SKG.
SKG.
SKG.
SKG.
PEN.
QMS.
HEX.
HEX, ORT.
ARN, HEX, SK.
HEX.
ARN.
ARN, HEX.
ARN, HEX.
MEDICINAL CHEMICALS
113
TABLE 2. — Medicinal chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
•Central depressants and 5timulants--Continued
•Amphetamines- -Continued
Dextroamphetamine sulfate
Dextroamphetamine t annate
Levamphet amine
Levamphetamine succinate
Methamphet amine (dextrol )
Methamphetamine (levo)
Methamphetamine hydrochloride (dextro)
Methamphetamine hydrochloride (racemic) —
*Analgestics and antipyretics:
•Aspirin
•Salicylates (except aspirin] :
Aluminum aspirin
Phenyl salicylate
Potassium salicylate
Salicylamide
Salicylsalicylic acid
Sodium salicylate
Strontium salicylate
•Other analgesics and antipyretics:
Acetaminophen
p-Aminobenzoic acid and salts:
Aminobenzoic acid
Calcium aminobenzoate
Magnesium aminobenzoate
Potassium aminobenzoate
Sodium aminobenzoate
Anileridine hydrochloride
Calcium succinate
Colchicine
Dext ropropoxyph ene napsylate
Ethoheptazine citrate
Indomethacin
Mefenamic acid
Meperidine hydroch lor ide
Methadone hydroch lor ide-7
Oxycodone hydrochloride
Oxyphenbutazone
Pentazocine
Pentazocine hydrochloride
Phenacetin
Phenylbutazone
Propoxyphene hydrochloride
•Antidepressants :
Amitriptyline
Desipramine hydroch lor ide
Doxepin hydrochloride
Imipramine hydrochloride
Nialamide
Nortriptyline
Phenelzine sulfate
Protriptyline
•Barbiturates:
Allylbarbituric acid
Allylbarbituric acid, sodium
Amobarbital
Amobarbital, sodium
ARN,
HEX,
SK.
ARN.
HEX.
HEX.
HEX.
ARN,
ARN,
GAN,
HEX.
HEX
DOW, MLS, MON, NOR, SDG.
ABB,
SCH.
DOW.
HN.
CFC,
PEN.
CFC,
NES.
DOW,
HN.
CFC.
ATP,
NEP, PEN
LEM.
GAN.
LEM.
GAN,
LEM.
GAN.
MRK.
LEM.
PEN.
LIL.
WYT.
MRK.
PD.
PEN,
SDW, WYT
LIL.
EN.
CGY.
SDW.
SDW.
MON.
CGY.
LIL.
MRK.
LKL.
PFZ.
CGY.
PFZ.
LIL.
NEP.
MRK.
GAN.
GAN.
LIL.
GAN,
LIL.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.-
-Medicinal chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3]
*Central depressants and stimulants--Continued
* Barb i turat es - -Continued
Barbital
Barbital, sodium
Butabarbital
Butabarbital, sodium
Hexobarbital
Mephobarbital
Metharbital
Methohexital , sodium
Pentobarbital
Pentobarbital, sodium
Phenobarbital
Phenobarb ital , sodium
Secobarbital
Secobarbital, sodium
Talbutal
Thiamylal, sodium
Thiopental, sodium
Vinbarbital
*Hydrocodone bitartrate
*Hypnotics and sedatives (except barbiturates) :
Carbromal
Ethchlorvynol
Ethinamate
Glutethimide
Methyprylon
'Skeletal muscle relaxants and tranquilizers;
Skeletal muscle relaxants:
Carisoprodol
Chlorphenesin carbamate
Mephenesin
Mephenesin carbamate
Phenaglycodol
Succinylcholine chloride
Tubocurarine
Tranquilizers :
Buclizine hydrochloride
Chlordiazepoxide hydrochloride
Chlormezanone
Chlorprothixene
Diazepam
Ethomoxane hydrochloride
Hydroxy z ine hydroch loride
Hydroxy zine pamoate
Mebutamate
*Meprob amat e
Methaqualone
Methaqualone hydroch loride
Oxazepam
Phenothiazine derivatives:
Ch lorproraaz ine hydrochloride
Fluphenazine hydrochloride
Perphenazine
Prazepam
Prochlorperazine edisylate
Prochlorperazine maleate
GAN,
LIL.
GAN.
ABB,
GAN.
ABB,
GAN.
GAN,
SDW.
SDW.
ABB.
LIL.
ABB,
GAN.
ABB,
GAN, PD.
GAN,
MAL.
GAN,
MAL.
GAN.
GAN,
LIL.
SDW.
PD.
ABB.
X.
MAL,
MRK, PEN
PD.
ABB.
LIL.
CGY.
HOP.
BKL.
UPJ.
BLK,
HEX, OMS
OMS.
IJL.
ABB,
BUR.
ABB,
OMS.
PFZ.
HOP.
SDW.
HOP.
HOP.
LIL.
PFZ.
PFZ.
BKL.
ABB,
BKL, X.
HEX,
X.
SK.
SCH.
SCH.
NEP.
SK.
SK.
MEDICINAL CHEMICALS
115
TABLE 2. — Medicinal chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
*Central depressants and stimulants--Continued
*Skeletal muscle relaxants and tranquilizers--Continued
Tranquilizers- -Continued
Phenothiazine derivatives --Continued
Promazine hydrochloride
Promethazine hydrochloride
Thiothixene hydrochloride
Trifluoperazine hydrochloride
Tybamate
*Other central depressants and stimulants:
Anticonvulsants :
Diphenylhydantoin
Dipheny Ihydantoin , sodium
Ethosuximide
Ethotoin
Methsuximide
Phenacemide
Phensuximide
Antitussives:
Benzonatate
Caramiphen edisylate
Codeine
Dextromethorphan hydrobromide
Dimethoxanate hydrochloride
Ethylmorphine hydrochloride
Levopr opoxyphene napsy lat e
Thebaine
General anesthetic: Vinyl ether
Stimulants :
Benzphetamine hydrochloride
Caffeine:
Natural
Synthetic
Caffeine, citrated
Caffeine sodium benzoate
Chlorphentermine hydrochloride
Diethylpropion hydrochloride
Nikethamide
Phentermine
•Dermatological agents and local anesthetics :
* Salicylic acid
*Other dermatological agents and local anesthetics:
Dermatological agents:
Allantoin
Aluminum phenol sul f onat e
Ammonium phenol sulfonate
Bismuth subgallate
Glycol salicylate
Scarlet red
Sodium phenolsulfonate
Zinc phenolsulfonate
Local anesthetics:
Butacaine
Butacaine sulfate
Butamben picrate
Butyl aminobenzoate (Butajnben)
Dibucaine
WYT.
WYT.
PFZ.
SK.
BKL.
PD.
ABB.
PD.
CGY.
SK.
MRK.
HOP.
BKL.
MAL, MRK.
LIL.
MRK.
MRK.
GNF.
PFZ.
MAL, MRK.
GAN, MAL.
NEP.
BKC, X.
CGY.
HEX.
DOW, HN, HON, SDH.
FIN, HFT.
MAL, sal;
SAL.
MAL.
RDA.
ACS.
SAL.
MAL, SAL.
ABB
ABB
ABB
CGY
See footnotes at end of table.
116
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.
-Medicinal chemicals for which U.S.
identified by manufacturer,
production or sales were reported,
1970- -Continued
Manufacturers ' identification codes
(according to list in table 3)
•Dermatological agents and local anesthetics--Continued
*Other dermatological agents and local
anesthetics --Continued
Local anesthetics--Continued
Dibucaine hydrochloride
Lidocaine
Oxethazine
Piperocaine hydrochloride
Podophy Hum resin
Pramoxine hydroch loride
Procaine hydrochloride
Proparacaine hydrochloride
Tetracaine
Tetracaine hydrochloride
'Diagnostic agents:
*Roentgenographic contrast media:
Acetrizoate, sodium
Diatrizoate, meglumine
Diatrizoate, sodium
lodohippurate, sodium
lodopyracet
lopanoic acid
lophendylate
lothalamate, meglumine
lothalamate, sodium
Meglumine iodipamide
Methiodal, sodium
Sodium iodipamide
*Other diagnostic agents:
Betazole hydrochloride
Evans blue (blood volume determination)
Indocyanine green (cardiac output test)
Metyrapone (pituitary function test)
Phenolphthalein monophosphate dicyclohexylamine
•Expectorants and mucolytic agents:
*Ethylenediamine dihydr iodide
Guaiacol and its derivatives:
Glyceryl guaiacolate
Guaiacol
Potassium guaiacolsulfonate
lodinated glycerol
Lobe line sulfate
Terpin hydrate
Thonzonium bromide
•Gastrointestinal agents:
'Choleretics and hydrocholeretics :
Bile acids, oxidized
Dehydrocholic acid
Florantyrone
Iron bile salts
Ox bile extract
Sodium dehydrocholate
Tocamphyl
•Choline chloride (all grades):
Feed grade
Medicinal grade
Technical grade .■
CGY.
AST, LEM, RLS, SDW.
WYT.
LIL.
PEN.
ABB.
PFZ, UOP.
OMS.
SDW.
SDW.
MAL.
OMS, SDW.
OMS, SDW.
MAL.
SDW.
SDW.
x.
MAL.
MAL.
OMS.
SDW.
OMS.
LIL.
NEP.
CGY.
NEP.
ABR, HFT, ISC, MAL, WHL.
CAN,
HEX
X.
MON.
HN.
x.
ABB.
PEN.
NEP.
SRL,
WIL
WIL.
SRL.
LIL,
WIL
ABB,
LIL
WIL.
WIL.
X.
COM,
DA,
HFT, TMH
HFT.
MEDICINAL CHEMICALS
117
TABLE 2. — Medicinal chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers ' identification codes
(according to list in table 3)
*Gastro intestinal agents --Continued
*Other gastrointestinal agents:
Betaine base
Betaine hydrochloride
Choline bicarbonate
Choline bitartrate
Choline citrate (Tricholine citrate)
Choline dihydrogen citrate
Danthron
Dihydroxy aluminum aminoacetate
Magnesium citrate
Methionine (medicinal grade)
Methionine, hydroxy analogue, calcium salt
Oxyphenisatin acetate
Pectin
Phenolphthalein
Podophyllum
Sitosterols
Sodium tartrate
*Hemotological agents:
Anticoagulants :
Ammonium heparin
Anisindione
Bishydroxycoumarin
Sodium heparin
Sodium warfarin
Other hematological agents:
Aminocaproic acid
Cellulose, oxidized
Dextran
*Hormones and synthetic substitutes:
*Corticosteroids :
Betamethasone
Betamethasone acetate
Betamethasone phosphate
Betamethasone valerate
Cortisone
Cortisone acetate
Dexamethasone
Dexamethasone phosphate
Dichlorisone acetate
1,2-Dihydrotriamcinolone
17a, 21- Dihydroxy- 16a-methy 1-9 (11) -progesterone
21 acetate.
Fludrocortisone acetate
Fluorometholone
9-hluoroprednisolone acetate
Fluprednisolone
Hydrocortisone
Hydrocortisone acetate
Hydrocortisone phosphate
Medrysone
Methylprednisolone
Prednisolone
Prednisolone acetate
Prednisone
Triamcinolone
HFT,
MAL.
HFT.
COM.
ACY,
HFT.
ACY,
HFT.
ACY,
HFT.
GAF.
CHT.
MAL.
DOW.
DUP,
MON.
HEX.
SKG.
MON.
ABB.
LIL,
UPJ.
MAL.
ABB,
WIL.
SCH.
ABB.
ABB,
RIK, WIL
EN.
ACY.
EKT.
PHR.
SCH.
SCH.
SCH.
SCH.
MRK,
UPJ.
MRK,
UPJ.
MRL,
SCH.
MRK.
SCH.
UPJ.
UPJ.
UPJ.
UPJ.
UPJ.
UPJ.
MRK,
PFZ, UPJ
MRK,
UPJ.
MRK.
UPJ.
UPJ.
MRK,
UPJ.
UPJ.
UPJ.
ACY,
OMS.
118
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Medicinal chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
♦Hormones and synthetic substitutes--Continued
♦Synthetic hypoglycemic agents:
Acetohexamide
Chlorpropamide
Phenf ormin hydrochloride
Tolazamide
Tolbutamide
*Other hormones and synthetic substitutes:
Anabolic agents and androgens:
Fluoxymesterone
Testosterone cypionate
Antithyroid agents:
Methimazole
Propylthiouracil
2-Thiouracil
Estrogens:
Chlorotrianisene
Dienestrol di acetate
Diethylstilbestrol
Diethylstilbestrol diphosphate
Estrogenic substances, conjugated
Natural estrogenic substance
Piperazine estrone sulfate
Progestogens:
Medroxyprogesterone acetate
Norgestrel
Progesterone
Other hormones :
Corticotropin (ACTH) (pituitary)
Insulin (pancreas)
Thyroid
*Renal-acting and edema-reducing agents:
♦Mercurial diuretics:
Moral luride
Mersalyl acid
Sodium mercaptomerin
♦Theophylline derivatives:
Aminophylline
Oxtriphylline
Theophylline sodium glycinate
♦Other renal-acting and edema-reducing agents:
Acetazolamide
Benzothiadiazine derivatives :
Benzthiazide
Chlorothiazide
Cyclothiazide
Flumethiazide
Hydrochlorothiazide
Methyclothiazide—
Polythiazide
Trichlormethiazide
Chlorthalidone
Dichlorphenamide
Ethacrynic acid
LIL.
PFZ.
BKL.
UPJ.
UPJ.
LIL.
ACY, CTN.
ACY.
BKC, X.
SCH.
CTN, LIL.
X.
ORG.
ORG.
ABB.
ARP,
ORG
ARP,
LIL
LIL.
LKL.
SDW.
WYT.
GAN,
SRL
NEP.
CHT.
ACY.
PFZ.
MRK.
LIL.
QMS.
ABB, CGY, MRK.
ABB.
PFZ.
SCH.
CGY.
MRK.
MRK.
MEPICINAL CHEMICALS
119
TABLE 2. — Medicinal chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
*Renal-acting and edema-reducing agents--Continued
*Other renal-acting and edema-reducing agents--
Continued
Probenecid
Spironolactone
Triamterene
*Therapeutic nutrients:
*Amino acids and salts:
Amino acid mixtures
Aspartic acid and salts:
Aspartic acid
Potassium aspartate
Beta-alanine
Glutamic acid and salts:
Ammonium glutamate
L-Arginine-L-glutamate
Glutamic acid
Glutamic acid hydrochloride
Potassium glutamate
Lysine (feed grade}
Lysine hydrochloride
*Calcium salts:
Calcium glucoheptonate
Calcium gluconate
Calcium phytate
*Ferrous gluconate
*Other therapeutic nutrients:
Copper gluconate
Liver concentrate
Liver, desiccated
Magnesium gluconate
Manganese gluconate
Potassium gluconate
•Vitamins:
*Vitamin A alcohol and esters:
Beta-carotene (Provitamin A)
Vitamin A acetate (feed grade)
Vitamin A acetate (medicinal grade)
Vitamin A alcohol
*Vitamin A palmitate (feed grade)
Vitamin A palmitate (medicinal grade)
*Vitamin B-complex:
*Niacin (all grades) :
*Feed grade
Medicinal grade
•Niacinamide
•Pantothenic acid and derivatives:
Calcium pantothenate (dextrol)
Calcium pantothenate (racemic) - calcium chloride
complex.
•Calcium pantothenate (racemic) (feed grade)
Calcium pantothenate (racemic) (medicinal grade) --
Choline pantothenate
Dexpanthenol
Panthenol (racemic)
Sodium pantothenate
MRK.
SRL.
ACY,
SK.
ABB,
MDJ, STA.
HEX.
WYT.
DA,
HFT.
IMC.
ABB.
IMC,
LEM.
IMC,
LEM.
IMC,
LEM.
MRK.
MRK.
PFN.
DLI,
PFZ, WHL.
STA.
DLI,
PFZ, SDW.
PFZ.
WIL.
WIL.
PFZ.
PFZ.
DLI,
PFZ.
EKT,
HOF.
HOF,
PFZ.
HOF,
PFZ.
HOF,
PFZ.
EKT,
HOF, PFZ.
EKT,
HOF, PFZ.
DA,
MRK, RIL.
MRK,
SCR.
MRK,
NEP, PD, RIL, SCR
HFT.
CKL,
DA, HFT, PHF.
CKL,
DA, DLI, HFT, PHF
DA.
HFT.
DLL
HFT,
HOF.
HOF,
PD.
120
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.
-Medicinal chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
'Vitamins- -Continued
♦Vitamin B-coniplex--Continued
•Other B-complex vitamins:
Biotin
Cyanocobalamin :
Cyanocobalamin (feed grade)
Cyanocobalamin (medicinal grade)
Cyanocobalamin (U.S. P. crystalline)--
Cyanocobalamin with intrinsic factor
concentrate.
Folic acid '
Inositol
Niacinamide hydrochloride
Pyridoxine
Riboflavin (feed grade)
Riboflavin (medicinal grade)
Ribof lavin-5-phosphate, sodium
Thiamine hydrochloride
Thiamine mononitrate
*Vitamin C:
* As corbie acid
Calcium ascorbate
Sodium ascorbate
*Vitamin D:
Cholecalciferol (Vitamin D3)
7-Dehydrocholesterol (Provitamin D3)
Ergocalciferol (Vitamin D2)
*Vitamin E:
d- Alpha tocophero 1
dl-Alpha tocopherol
d-Alpha tocopheryl acetate
dl-Alpha tocopheryl acetate
dl-Alpha tocopheryl acetate (feed grade) -
d-Alpha tocopheryl acid succinate
•Vitamin K:
Menadione
Menadione sodium bisulfite
Phytonadione
•Miscellaneous medicinal chemicals:
Antineoplastic agents:
Azothioprine
Mer capt opur ine
Thioguanine
Vinblastine sulfate
Vincristine sulfate
Smooth muscle relaxants:
Alverine
Alverine citrate
Alverine hydrochloride
Papaverine hydrochloride
Sodium benzyl succinate
Unclassified medicinal chemicals:
All opur inol
Dopamine hydrochloride
Hydras tine hydrochloride
Penicillamine (copper chelating agent) —
GPR, MRK
PMP.
MRK.
MRK.
WIL.
ACY.
STA.
NEP.
HOP, MRK
DA, HOP,
MRK.
HOP, MRK
HOP.
HOP, MRK
HOP, MRK
HOP, MRK
PPZ.
PFZ.
HOP, MRK
PPZ.
DA, DLI,
PHP, VTM.
VTM.
PHP, SCR
VTM.
CW, EKT.
HOP.
CW, EKT.
HOP.
HOP.
CW, EKT.
ABB, HET
IVHL.
ABB, DA,
DLI, HET, IVHL
MRK.
BUR.
BUR.
BUR.
LIL.
LIL.
CTN.
LIL, MRK.
PIN.
BUR.
SDW.
PEN.
MRK.
1 Producers of technical grade are listed in "Cyclic intermediates."
2- Producers of technical grade are listed in "Miscellaneous chemicals.'
MEDICINAL CHEMICALS
TABLES. — Medicinal chemicals: Directory of manufacturers, 1970
121
ALPHABETICAL DIRECTORY BY CODE
[Names of manufacturers that reported production or sales of medicinal chemicals to the U.S. Tariff Commission for
1970 are listed below in the order of their identification codes as used in table 2]
Code
Code
identi-
Name of company
identi-
Name of company
fication
fication
ABB
Abbott Laboratories
HOF
Hoffmann-LaRoche, Inc.
ABR
West Agro-Chemicals, Inc.
HYN
Hynson, Westcott 6 Dunning, Inc.
ACS
Allied Chemical Corp., Specialty
Chemicals Div.
IMC
International Minerals S Chemical Corp.
ACY
American Cyanamid Co.
ISC
West Agro-Chemicals, Inc.
APD
Atlas Chemical Industries, Inc.
ARN
Arenol Chemical Corp.
JCC
Jefferson Chemical Co., Inc.
ARP
Armour Pharmaceutical Products Co.
ARS
Arsynco, Inc.
KPT
Koppers Co., Inc., Organic Materials Div.
AST
Astra Pharmaceutical Products, Inc.
ATP
Atco Chemical-Industrial Products, Inc.,
LEM
Lemke Chemicals, Inc.
Fine Chemicals Div.
LIL
Eli Lilly S Co.
LKL
Lakeside Laboratories Div. of Colgate-
BEE
Beecham, Inc.
Palmolive Co.
BJL
Burdick § Jackson Laboratories, Inc.
BKC
J. T. Baker Chemical Co.
MAL
Mallinckrodt Chemical Works
BKL
Millmaster Onyx Corp., Millmaster Chemical
HDJ
Mead Johnson § Co.
Div., Berkeley Chemical Dept.
MLS
Miles Laboratories, Inc., Marschall Div.
BPC
Stauffer Chemical Co., Benzol Products Div.
MON
Monsanto Co.
BRS
Bristol-Myers Co., Bristol Laboratories
Div.
Burroughs Wellcome Co.
MRK
Merck S Co., Inc.
BUR
NEP
Nepera Chemical Co., Inc.
NES
Nease Chemical Co., Inc.
CFC
Sun Chemical Corp .
NOR
Norwich Pharmacal Co.
CGY
Ciba-Geigy Corp., Ciba Pharmaceutical Co.
NTL
National Lead Co.
CHT
Chattam Drug § Chemical Co., Chattem
Chemicals Div.
OMS
E. R. Squibb § Sons, Inc.
CKL
Chemlek Laboratories, Inc.
ORG
Organics, Inc.
COM
Commerical Solvents Corp.
ORT
Roehr Chemicals, Inc.
CTN
Chemetron Corp., Organic Chemical Div.
CW
General Mills Chemicals, Inc.
PCW
Pfister Chemical, Inc.
PD
Parke, Davis 5 Co.
DA
Diamond Shamrock Corp.
PEN
CPC International, Inc., Penick Div.
DLl
Dawe's Laboratories, Inc.
PFN
Pfanstiehl Laboratories, Inc.
DOW
Dow Chemical Co.
PFZ
Pfizer, Inc.
DUP
E. I. duPont de Nemours § Co., Inc.
PHF
Peter Hand, Inc.
PHR
Pharmachem Corp.
ECL
Eastside Chemical Laboratory
PMP
Premier Malt Products, Inc.
EK
Eastman Kodak Co.:
PYL
Polychemical Laboratories, Inc.
EKT
Tennessee Eastman Co. Div.
EN
Endo Laboratories, Inc.
RDA
Rhodia, Inc.
RH
Rohm § Haas Co.
FIN
Fine Organics, Inc.
RIK
Riker Laboratories, Inc. Sub. of 3M Co.
FIS
Fisher Chemical Co., Inc.
RIL
Reilly Tar S Chemical Corp.
F.LM
Fleming Laboratories, Inc.
RLS
Rachelle Laboratories, Inc.
RSA
R.S.A. Corp.
GAF
GAF Corp., Chemical Div.
CAN
Gane's Chemical Works, Inc.
SAL
Salsbury Laboratories
GIV
Givaudan Corp.
SCH
Schering Corp.
GNF
General Foods Corp., Maxwell House Div.
SCR
R. P. Scherer Corp.
GPR
Grain Processing Corp.
Sterling Drug Corp.:
SDG
Glenbrook Laboratories Div.
HET
Heterochemical Corp.
SDH
Hilton-Davis Chemical Co. Div.
HEX
Hexagon Laboratories, Inc.
SOW
Winthrop Laboratories Div.
HFT
Hoffman-Taff, Inc.
SEL
Selney Co. , Inc.
HN
Tenneco Chemicals, Inc.
SHC
Shell Oil Co., Shell Chemical Co. Div.
122
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 3. — Medicinal chemicals: Directory of manufacturers, 1970 — Continued
Code
Code
identi-
Name of company
identi-
Name of company
fication
fication
SK
Smith, Kline 5 French Laboratories
UPJ
Upjohn Co.
SKG
Sunkist Growers, Inc.
SRL
G.D. Searle S Co.
VB
Vermilye-Bell
STA
A. E. Staley Manufacturing Co.
VTM
Vitamins, Inc.
TMH
Thompson-Hayward Chemical Co.
WHL
Whitmoyer Laboratories, Inc.
WIL
Wilson 5 Co., Inc., Wilson Laboratories Div.
UCC
Union Carbide Corp.
WRC
Ventron Corp.
UOP
Universal Oil Products Co.,
WTL
Pennwalt Corp., Lucidol Div.
UOP Chemical Div.
WYT
Wyeth Laboratories, Inc., Wyeth Laboratories
Div. of American Home Products Corp.
complete names and addresses of the above reporting companies, refer to table 1 in the Appendix
FLAVOR AND PERFUME MATERIALS 123
Flavor and perfume materials are organic chemicals used
to impart flavors and odors to foods, beverages, cosmetics
and soaps. These aromatic chemicals are also utilized to
neutralize or mask unpleasajit odors in industrial processes
and products as well as in consumer products.
Total domestic production of flavor and perfume
materials in 1970 amounted to 100.3 million pounds -- a
decrease by 16.7 percent from the 120.4 million pounds pro-
duced in 1969 (table I).'' Sales of these materials in 1970
amounted to 91.5 million pounds, valued at $89.1 million,
compared with 103.6 million pounds, valued at $93.6 million
in 1969.
Production of cyclic flavor and perfume materials in
1970 amounted to 52.5 million pounds; sales amounted to 42.9
million pounds, valued at $52.0 million. The individual
chemical in the cyclic group produced in the greatest volume
in 1970 again was benzyl alcohol (8.4 million pounds).
U.S. output of acyclic flavor and perfume materials in
1970 amounted to nearly 48 million pounds; sales of these
materials amounted to 48.6 million pounds, valued at $37.1
million. Monosodium glutamate was by far the most important
of the acyclic chemicals, and the individual flavor and per-
fume chemical produced in the greatest volume. Output of
this chemical in 1970 totaled 37.2 million potmds, compared
with 48.5 million pounds in 1969, a decrease by more than
23 percent .
See also table 2 which lists these materials and identi-
fies the manufacturers by codes . These codes are given in
table 3.
124
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. --Flavor and perfume materials: U.S. production and sales, 1970
fListed below are all synthetic organic flavor and perfume materials for which any reported data on production or
sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be
published or where no data were reported.) Table 2 lists all flavor and perfume materials for which data on pro-
duction or sales were reported and identifies the manufacturers of each]
Quantity
Grand total-
FLAVOR AND PERFUME MATERIALS, CYCLIC
Benzenoid and Naphthalenoid
Total-
4-Allyl-2-methoxyphenol (Eugenol)
4- Al lyl -1,2- (methylenedioxy) benzene (Saf rol e)
p-Anis aldehyde
Benzophenone^
Benzyl acetate
Benzyl alcohol^
Benzyl benzoate
Benzyl butyrate
Benzyl cinnamate
Benzyl salicylate
Cinnamaldehyde
Cinnamyl acetate
Cinnamyl alcohol
Cinnamyl anthranilate
Isobutyl phenyl acetate
Isobutyl salicylate
Isopentyl salicylate
2-Methoxy-4-propenylphenol CIsoeugenol)
4'-Methylacetophenone
p-Methylanisole
Methyl anthranilate
a-Methylbenzyl acetate (Styralyl acetate)
a-Methylcinnamaldehyde
Methyl phenylacetate
Methyl salicylate
Phenethyl acetate
2-Phenethyl phenylacetate
3-Phenyl-l-propanol (Hydrocinnamic alcohol)
p-Propenylanisole (Anethole)
All other benzenoid and naphthalenoid materials-
Terpenoid, Hetevocyalia, and Alioyclia
Total-
Cedryl acetate
Essential oils, chemically modified
4-Hydroxyundecanoic acid, y-lactone CT-Undecalactone)
a-Ionone
Isobomyl acetate
Menthol, synthetic, tech. 6 U.S.P
Methylionones
Terpineols
a-Terpinyl acetate
Vetivenyl acetate
All other terpenoid, heterocyclic and alicyclic materials-
See footnotes at end of table.
1^000
pounds
1UJ,321
52,543
41,109
435
277
1,446
357
1,530
8,389
316
13
241
1,510
767
100
5,396
2,363
17,374
213
214
96
1,148
399
580
3,349
482
41
4,912
1,000
pounds
71
126
1,554
9,101
469
7
6
257
1,135
646
115
28
5,274
79
2,326
12,983
107
126
8
56
980
431
398
,261
425
1,000
dollars
89,102
38,891
953
69
140
646
,858
217
11
24
317
846
412
450
1,354
27,026
13,154
265
471
34
266
357
1,675
1,748
1,211
273
559
6,295
FLAVOR AND PERFUME MATERIALS
TABLE 1. — Flavor and perfume materials: U.S. production and sales, 1970 — Continued
125
Sales
Quantity
Unit
value'
1,000
pounds
1,000
FLAVOR AND PERFUME MATERIALS, ACYCLIC
Total
Allyl hexanoate
Citronellyl acetate
3,7-Dimethyl-cis-2,6-octadien-l-ol (Nerol)
3,7-DLmethyl-trans-2,6-octadienal (Citral a; GeranialJ
3, 7-Dimethyl-trans-2,6-octadien-l-ol CGeraniol)
3,7-Dimethyl-6-octen-l-ol (Citronellol)
Ethyl butyrate
Ethyl heptanoate
Ethyl hexanoate (Ethyl caproate)
Ethyl nonanoate
Geranyl acetate
Geranyl formate
Glutamic acid, monosodium salt (Monosodium glutamate)
7-Hydroxy-3,7-dimethyl-l-octanal (Hydroxycitronellal)
Isopentyl butyrate
Isopentyl formate
Isopentyl isovalerate
Rhodinol
All other acyclic materials
48.587
81
3,144
958
422
7
17
2
100
12
37,210
533
147
27
10
5,065
2,234
839
421
1,000
dollars
37,057
48
41
304
2,245
1,400
263
13
16
2.488
58
276
29,651
per
pound
$0.76
2.53
1.99
2.41
3.71
1.01
1.67
.62
1.80
2.31
3.33
1.79
2.64
5.06
28.31
.67
' Calculated from the unrounded figures .
^ Includes some technical grade.
462-669 O - 72 - 9
126
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.
-Flavor and perfume materials for which U.S. production or sales were
reported, identified by manufacturer, 1970
[Flavor and perfume materials for which separate statistics are given in table 1 are marked below with an asterisk
(*) ; those not so marked do not appear in table 2 because the reported data are accepted in confidence and may
not be published. Manufacturers' identification codes are taken from table 3]
Manufacturers ' identification codes
(according to list in table 3)
FLAVOR AND PERFUME MATERIALS. CYCLIC
Benzenoid and Naphthalenoid
2'Acetonaphthone
Acet ophenone
5-Acetyl-l,l,2,3,3,6-hexajiiethylindan
p-Allylanisole
Allyl cinnamate
4-Allyl-l,2-dimethoxybenzene (4-Allylveratrole)
*4-Allyl-2-methoxyphenol (Eugenol)
4-Allyl-2-methoxyphenol acetate (Eugenyl acetate)
*4'-Ally 1-1, 2 -(methylenedioxy) benzene (Safrole)
Allyl phenoxyacetate
*p-Anisaldehyde
Anisole (Methyl phenyl ether)
Anisyl acetate
Anisyl butyrate
Anisyl formate
Benzaldehyde
*Benzophenone
*Benzyl acet ate
* Benzyl alcohol
*Benzyl benzoate
Benzyl butyl ether
*Benzyl butyrate
*Benzyl cinnamate
2-Benzyldioxolane
Benzyl ether
Benzyl formate
Benzyl glyceryl acetal
Benzyl isobutyrate
Benzyl isopentyl ether
l-(Benzyloxy) -2-methoxy-4-propenylbenzene (Benzyl
isoeugenyl ether) .
Benzyl phenyl acet ate
Benzyl propionate — ,
*Benzyl salicylate
4-tert-Buty 1-2 ' ,6 ' -dimethyl -3 ' ,5 ' -dinitroacetophenone
(Musk ketone) .
6-tert-Butyl-3-methyl-2,4-dinitroanisole (Musk
ambrette) .
p-tert-Butyl-a-methylhydrocinnamaldehyde
Butyl phenylacetate
l-tert-Butyl-3,4,5-trimethyl-2,6-dinitrobenzene
S-tert-Butyl-2,4,6-trinitro-m-xylene (Musk xylol)
Carvacrol
*Cinnamaldehyde
Cinnamic acid
*Cinnarayl acetate
*Cinnamy alcohol
*Cinnamyl anthranilate
Cinnamyl butyrate
Cinnamyl cinnamate
Cinnamyl propionate
Coumarin
o-Cresyl methyl ether
Cuminyl alcohol
trans -Decahydro-B-naphthol
Dihydrocoumarin (Melilotol)
l,2-Dimethoxy-4-propenylbenzene (4-Propenylveratrole)-
p-a-Dimethylbenzyl alcohol
GIV.
GIV. UOP.
PFW.
GIV.
RT.
GIV.
ARS, CI, FB, GIV, IFF, LUE, PEN, RT, UNG, UOP
GIV.
FB, GIV, OPC.
GIV.
GIV, OPC, UOP.
GIV.
ELN, GIV.
RT.
RT.
SHL.
GAF, GIV, NEO,
PD, UOP.
GIV, OPC, SHL,
UOP.
BPC, HN, OPC,
SHL, UOP, VEL.
MON, OPC, PFZ,
UOP, VEL.
SHL.
ELN, FB, GIV.
FB, GIV, UOP.
GIV.
SHL, VEL.
ELN, GIV, UOP.
CI, GIV.
GIV.
GIV.
GIV, UOP.
ELN, GIV.
ELN, FB, GIV.
ELN, GIV, OPC,
UNG; UOP.
GIV.
GIV.
GIV.
GIV.
GIV.
GIV.
GIV.
CI, FB, UOP.
BPC.
ELN, FB, GIV.
FB, GIV, NEO, UOP.
FEL, GIV, RT.
FB.
FB.
ELN, GIV, UOP.
DOW, RDA.
CI.
GIV.
IFF.
ARS.
GIV.
GIV.
FLAVOR AND PERFUME MATERIALS
127
TABLE 2. --Flavor and perfume materials for which U.S. production or sales were
reported, identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued
Bemenoid and Naphthalenoid- -Continued
3,7-Dimethyl-l,6-octadien-3-yl anthranilate (Linalyl
anthranilate) .
3,7-Dimethyl-l,6-octadien-3-ol, benzoate (Linalyl
benzoate).
3,7-Dimethyl-l,6-octadien-3-ol, cinnamate
3,7-Dimethyl-2,6-octadienyl phenylacetate (Geranyl
phenylacetate) .
a.a-Dimethylphenethyl acetate
a,a-Dimethylphenethyl alcohol
Diphenylmethane (Benzylbenzene)
l,3-Diphenyl-2-propanone (Dibenzyl ketone)
p-Ethoxy benzaldehyde
l-Ethoxy-2-hydroxy-4-propenylbenzene
3-Ethoxy-4-hydroxybenzaldehyde (Ethylvanillin)
2-Ethoxynaphthalene
Ethyl anthranilate
Ethyl benzoate
Ethyl cinnamate
Ethyl a,6-epoxy-6-methylhydrocinnamate
2-Ethylhexyl salicylate
Ethyl phenylacetate
Ethyl phenylglycidate
Ethyl salicylate
3 ' -Ethyl-5 ' , 6 ' , 7 ' , 8 ' -tetrahydro-5 ' , 5 ' , 8 ' , 8 ' -
tetramethyl-2 '-acetonaphthone.
a-Hexylcinnamaldehyde
Hydratropaldehyde
Hydratropaldehyde, dimethyl acetal
Hydrocoumarin
Hydroxycitronellalmethyl anthranilate
2-Hydroxy-3-ethoxybenzaldehyde (ortho Ethyl vanillin) --
4-(4-Hydroxy-3-methoxyphenyl)-2-butanone
Indole
Isoamyl phenylacetate
Isobutyl benzoate
p-Isobutyl d-ethoxybenzaldehyde (Rhodial)
*Isobutyl phenylacetate
*Isobutyl salicylate
Isopentyl benzoate
*Isopentyl salicylate
p-Isopropylbenzaldehyde (Cumaldehyde)
Isopropyl cinnamate
p-Isopropyl-a-methylhydrocinnamaldehyde (Cyclamen-
aldehyde) .
p-Mentha-l,8-diene (Limonene)
Menthyl anthranilate
4' -Methoxyacetophenone (Acetanisole) :
p-Methoxybenzyl alcohol (Anisyl alcohol)
o-Methoxycinnamaldehyde
2-Methoxynaphthalene
l-(p-Methoxyphenyl)-l-penten-3-one'-
*2-Methoxy-4-propenylphenol (Isoeugenol)
*4 ' -Methylacetophenone
*p-Methylanisole
*Methyl anthranilate
Methyl anthranilydene-p-isopropylmethylhydro-
cinnamaldehyde .
Methyl benzoate
*oi-Methylbenzyl acetate (Styralyl acetate)
*a-Methylcinnanialdehyde
Methyl cinnamate
6-Methylcoumarin
FMT.
HOF.
HOF.
GIV.
IFF.
IFF.
ARA.
GIV.
GIV.
SHL.
MON,
RDA,
SLV
GIV.
FB.
ELN.
GIV.
ELN.
FEL.
GIV.
GIV,
PFW
FB.
GIV,
UOP
CI,
IFF.
GIV,
IFF
GIV,
IFF
GIV,
UOP
GIV.
RDA
GIV.
GIV.
GIV.
ELN,
TCC
RDA.
ELN,
FB,
GIV,
OPC, RT.
FB,
GIV.
UOP.
GIV.
FB,
GIV,
OPC,
UOP.
GIV
RT.
GIV,
RDA
SKG
PFW
GIV.
GIV,
UOP
CI.
GIV
GIV
CI,
GIV,
SHL,
UOP.
ELN
GIV
OPC
, UOP.
GIV
OPC
UOP
FB,
OPC,
PFW,
SHL, SW, UNG
RDA
HN.
CI,
ELN,
FB,
GIV, UNG.
CI,
FB,
3IV.
FB,
UOP.
GIV
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2 -Flavor and perfume materials for which U.S. production or sales were
reported, identified by manufacturer, 1970-Contmued
FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued
Benzenoid and tlaphthalenoid- -Continued
l,2-(Methylenedioxy)-4-propenylbenzene (Isosafrole)
p-Methylhydratropaldehyde ""'"," V/l"/V'
l-Methyl-4-isohexyl-hexahydrobenzaldehyde (Vernaldehyde) —
Methyl N-methylanthranilate "
*Methyl phenyl acetate ""
*Methyl salicylate """ "■""
6-Oxa-l,l,2,3,3,8-hexamethyl-2,3,5,6,7,8-hexahydro IH-
benz[f)indene (Galaxolide) .
2-Oxa-4,5,5,8,8-pentamethyl-l,2,3,4,5,6,7,8-octahydro-
anthracene .
l,l,3,3,5-Pentamethyl-4,6-dinitroindan
a-Pentylcinnamaidehyde
*Phenethyl acetate "'"
Phenethyl alcohol '"_'_
Phenethyl benzoate "
Phenethyl n-butyrate
Phenethyl formate
Phenethyl isobutyrate """
Phenethyl isovalerate "
*2-Phenethyl phenylacetate
Phenethyl propionate """"
Phenethyl salicylate "
2-Phenoxyethyl isobutyrate -"""
Phenylacetaldehyde -----
Phenylacetaldehyde, dimethyl acetal ---
o-Phenylanisole (2-Methoxybiphenyl)
Phenylethyl acetal
Phenylethyl tiglate ---"
*3-Phenyl-l-propanol (Hydrocinnamic alcohol)
3-Phenylpropyl acetate """
3-Phenylpropyl cinnamate ""
Piperonal (Heliotropin) "_"
Piperonal terpenes ""
*p-Propenylanisole (Anethole)
p-Propylanisole (Dihydroanethole)
a-Propylphenylethyl alcohol
Sweeteners, synthetic:
Cyclohexanesulfamic acid
Cyclohexanesulfamic acid, calcium salt
Cyclohexanesulfamic acid, sodium salt -----
Saccharin [l,2-Benzisothiazolin-3-one, 1,1-dioxide)-
Saccharin, calcium salt
Saccharin, sodium salt """
p-Tolualdehyde
p-Tolylacet aldehyde
p-Tolyl acetate
p-Tolyl phenylacetate
a-(Trichloromethyl)benzyl acetate CRosetone)
Vanillin (;4-Hydroxy-3-niethoxybenzaldehyde)
Terpenoid, heteroayalic, and Alicyclio
Manufacturers' identification codes
(according to list in table 3)
GIV.
GIV.
GIV.
GIV. OPC.
ELN, GIV, OPC.
CFC, DOW, HN, MON, PEN.
IFF
IFF.
GIV.
CI, FB, GIV, UOP.
GIV, IFF, NEO.
IFF.
IFF.
IFF.
ELN, IFF.
GIV, IFF.
GIV, OPC.
CI, ELN, GIV, IFF, UOP.
GIV.
GIV.
ELN, GIV, IFF.
GIV.
GIV.
GIV.
GIV.
FB.
ELN, FB, GIV, UOP.
ELN, GIV.
FB.
GIV, SHL, UOP.
SHL.
ARZ, GLD, HPC, NCI, UOP.
FB. GIV.
GIV.
ABB.
MON, SW.
MON, SW.
LAK, MON.
GIV, HN, TCC.
GIV.
FB, GIV.
GIV.
ARS.
MON. SLV.
GIV.
IFF.
CI. IFF.
CI, GIV.
Allyl cyclohexyl propionate---- 'J"
p-tert-Butylcyclohexanone
p-tert-Butylcyclohexyl acetate
Cadinene
g-Caryophyllene
Caryophyllene alcohol """ I J,jy^
Cedrenol '_\'_\\\ ELN^ GIV,
Cedrol "" ELN, GIV,
*Cedryl acetate jPP_
Cedryl formate
IFF.
IFF, NEO, UNG.
FLAVOR AND PERFUME MATERIALS
129
TABLE 2. — Flavor and perfume materials for which U.S. production or sales were
reported, identified by manufacturer, 1970 — Continued
Manufacturers ' identification codes
(according to list in table 3]
FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued
Terpenoid, Heterocyolio, and Alicyclic--CQTitinued
2-Cyclohexylcyclohexanone
Cyclopentanone carboxylic acid
Dihydronordicyclopentadienyl acetate
Dihydronordicyclopentadienyl propionate
Dihydroterpinyl acetate
*Essential oils, chemically modified:
Acetyl cedrene
Amyris acetate s
Clove leaf oil terpenes^ ^
Ethyl oxyhydrate
Guaiacwood acetate
Guaiene
Lavandin, acetylated
Rose oxide
Sassafrass oil, hydrogenated
3-Hydroxy-2-ethyl-4-pyrone (Ethyl maltol)
16-Hydroxyhexadecanoic acid, o- lactone (Hexadeca-
nolide) .
4-(4-Hydroxy-4-methylpentyl3-3-cyclohexene-10-
carboxaldehyde .
3-Hydroxy-2-methyl-4-pyrone (Maltol)
4-Hydroxynonanoic acid, y-l^ctone (y-Nonalactone)
4-Hydroxyactanoic acid, y-l^ctone (y-Octalactone)
*4-Hydroxyundecanoic acid, y-l^'^tone (y-Undecalactone)
lonones :
*a-Ionone
S-Ionone
lonone (a-and g-)
Isobomeol
*Isobomyl acetate
Isobomyl propionate
Isojasmone
Isomenthone
2-Isopropylcyclohexanol
Jasmal
p-Mentha-6,8-dien-2-ol (Carveol)
p-Mentha-6,8-dien-2-one (Carvone; Carvol).
p-Menthan-3-one (Menthone)
prMenth-8-en-ol (Isopulegol)
p-Menth-l-en-3-one
p-Menth-4(8)-en-3-one (d-Pulegone)
l,l-p-Menthen-6-yl-l-propanone
*Menthol, synthetic:
Tech
U.S.P
Menthyl acetate
Methyl cyclohexyl propionate
*Methylionones :
6-Methyl-a-ionone
6-Methyl-6-ionone
Methylionone (a- and 8-)
y-Methylionone
Nopyl acetate
Santalol
Santalyl acetate
*Terpineols:
a-Terpineol
6-Terpineol
Terpineol (a- and g-)
GIV.
ARA.
GIV, IFF.
GIV, IFF.
GIV.
GIV, IFF.
GIV.
CI, SHL.
FEL, FLO, LUE
PFW, VND
ELN, FB, GIV.
FB.
FEL, GIV, UNG
FB.
GIV.
PFZ.
IFF.
IFF.
PFZ.
GIV.
GIV, RT.
ELN, FB, GIV.
GIV, HOF, IFF,
MYW.
HOF, MYW.
GIV, MYW, UNG
RDA.
FB, OPC, PFW,
RDA, UNG.
GIV, OPC.
FB.
GIV.
GIV.
IFF.
FB.
FB, FRM.
GIV, NED, OPC
GIV.
GIV.
GIV.
GIV.
GIV, NEO.
GIV, GLD, HN,
NEO.
GIV.
GIV.
GIV, MYW.
NEO.
GIV, IFF, MYW,
UNG.
GIV.
CI, FEL, SHL.
GIV, IFF.
GIV.
GLD, HPC, NCI
HN.
GIV, NEO.
130
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.
■Flavor and perfume materials for which U.S. production or sales were
reported, identified by manufacturer, 1970- -Continued
Manufacturers ' identification codes
(according to list in table 3)
FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued
Terpenoid, EeteTocyolia, and i4Hci/eZie- -Continued
Terpinol hydrate (Terpin hydratej , tech
*a-Terpinyl acetate
Terpinyl acetate (mixed a-6)
a-Terpinyl propionate
3,3,5-Trimethylcyclohexanol
l-(2,6,6-Trimethyl-2-cyclohexen-l-yl) -1,6-heptadien-
3-one (Allyl-a-ionone) .
Vetivenol
*Vetivenyl acetate
FLAVOR AND PERFUME MATERIALS, ACYCLIC
Acetylbutyryl (2,3-Hexanedione)
Acetyl propionyl
Acetylvaleryl (2,3-Heptanedione)
Ally! heptoate
*Allyl hexanoate
Allyl isothiocyanate (Synthetic mustard oil)
Allyl mercaptan
Allyl octanoate (Allyl caprylate)
Allyl sorbate
Allyl sulfide
Amyl propionate
Butyl butyrate
Butyl butyryl lactate
Butyl 10-undecylenate
Citral dimethyl acetal
*Citronellyl acetate
Citronellyl butyrate
Citronellyl ethyl ether
Citronellyl formate
Ci t rone 1 ly 1 i sobutyrat e
Citronellyl oxyacetaldehyde
Citronellyl propionate
Decanal (Capraldehyde)
Decyl acetate
Diethyl sebacate
Diethyl succinate
Dihydromyrcenol
Dihydromyrcenol and dihydromyrcenyl formate (Dimyrcetol)--
Dihydro s afro 1
2,6-Dimethyl-5-hepten-l-al
3,6-Dimethyl-S-hepten-2-oI and 7-Methyl-6-octen-3-ol
(Brazinol) .
3,7-Dimethyl-l,6-nonadien-3-ol
3,7-Dimethyl-l,6-nonadien-3-ol, acetate
3,7-Dimethyl-2,6-octadienal (Citral)
*3, 7 -Dimethyl -cis- 2, 6-octadien-l-ol (Nerol)
*3,7-Dimethyl-trans-2,6-octadienal (Citral a; Geranial)
3,7-DimethyI-trans-2,6-octadienal dimethyl acetal
*3, 7 -Dimethyl -trans -2, 6-octadien-l-ol (Geraniol)
3,7-Dimethyl-l,6-octadien-3-ol (Linalool; Linalyl alcohol)
3,7-Dimethyl-l,6-octadien-3-ol acetate (Linalyl
acetate) .
3,7-Dimethyl-l,6-octadien-3-yl isobutyrate (Linalyl
isobutyrate) .
3,7-Dimethyl-l,6-octadien-3-yl propionate (Linalyl
propionate) .
3,7-Dimethyloctan-l-al
3,7-Dimethyl-l,7-octanediol
3,7-Dimethyl-l-octanol (Dihydrocitronellol)
3,7-Dimethyl-3-octanoI (Tetrahydrolinalool)
3,7-Dimethyl-6-octen-l-al (Citronellal)
HPC.
GIV, NEO, PFW, UNG.
RDA.
ELN, GIV.
ARS.
GIV, IFF.
GIV, UOP.
CI, ELN, FB, GIV, IFF, NEO, UOP.
ELN,
FB,
GIV, PFW.
MRT.
RT.
RT.
RT.
RT.
GIV.
FB.
ARS.
GIV.
GIV.
ELN,
GIV
IFF, UOP
GIV.
IFF.
ELN,
GIV
IFF.
ELN,
GIV
IFF.
GIV,
IFF
GIV,
IFF
GIV.
ELN,
FEL
ELN,
UCC
IFF.
IFF.
CI.
GIV.
RDA.
HOF.
HOF.
HOF.
ELN, FB, GIV, GLD, IFF.
CI, FB, FEL, GIV, LUE, UOP.
CI.
CI, ELN, FB, FEL, GIV, GLD, IFF, NCI, NEO, UNG, UOP.
ELN, FB, FEL, GIV, GLD, HOF, LUE, SHL, UNG.
ELN, FB, GIV, GLD, HOF, SHL, UNG.
HOF.
HOF, NEO.
HOF.
GIV.
GIV.
HOF.
FB, GIV, IFF, UOP.
FLAVOR AND PERFUME MATERIALS
131
TABLE 2.
■ Flavor and perfume materials for which U.S. production or sales were
reported, identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
FLAVOR AND PERFUME MATERIALS , ACYCLIC— Continued
*3,7-Diraethyl-6-octen-l-ol (Citronellol)
3,7-Dimethyl-7-octenol and 6-octenol isomer
*Ethy 1 butyr at e
Ethyl caprate
Ethyl formate
*Ethyl heptanoate
*Ethyl hexanoate (Ethyl caproate)
Ethyl isohexanoate
Ethyl isovalerate
Ethyl laurate
Ethyl niyristate--r
*Ethyl nonanoate
Ethyl octanoate
Ethyl propionate
Ethyl valerate
Ethylene brassy late
Geranic acid
Geranonitrile
*Geranyl acetate
Geranyl butyrate
*Geranyl formate
Geranyl isobutyrate
Geranyl isovalerate
Geranyl neryl formate
*Glutaraic acid, monosodium salt (Monosodium glutamate)
Y-Heptalactone
Heptanal (Enanthaldehyde)
Heptyl alcohol (1-Heptanol)
2-Hexanal
Hexanoic acid (Caproic acid)
2-Hexanol
cis-3-Hexen-l-ol
cis-3-Hexen-l-ol lactate
3-Hydroxy-2-butanone (Acetoin)
*7-Hydroxy-3,7-dimethyl-l-octanal (Hydroxycitronellal)
7-Hydroxy-3, 7-dimethyl octanal, dimethyl acetal
(Hydroxycitronellal, dimethyl acetal).
Isoamyl geranate
Isobutyl acetate
Isodihydro lavandul aldehyde
Isodihydro lavandulol
Isodihydro lavandulyl acetate
*Isopentyl butyrate
*Isopentyl formate
*Isopentyl isovalerate
Lauraldehyde
Methyl amyl ketone
Methyl isobutyrate
Methyl isovalerate
Methyl -6 -methylthiopropionate
Methyl 2-nonenoate
Methylol methyl hexyl ketone
B-Methylthiopropionaldehyde
2-Methylundecanal
Muguol and tetrahydro muguol
Hyrcenyl acetate
Myristaldehyde
Neryl acetate
Nonanal
Nonane diacetate
Nonane-1 ,3-diol monoacetate
CI,
ELN,
FB,
GIV,
GLD, IFF, OPC.
GIV.
FB,
NW, RT, UOP.
FB.
FB,
PFW.
ELN,
FEL
RT.
ELN,
FB,
NW,
PFW,
RT.
PFW.
FB,
PFW.
ELN,
FB.
RT.
FB,
FEL,
GIV,
RT.
FB,
RT.
FB.
PFW.
RDA.
FB.
IFF.
CI,
ELN,
FEL,
GIV
IFF, UNG, UOP
CI,
GIV.
CI,
ELN,
GIV.
IFF.
FB.
IFF
COM,
GRW
IMC
FB.
NTL.
NTL
FB.
FB.
FB.
GIV
SW.
RT.
FMT
GIV
GLD
IFF
, OPC, UOP.
GIV
FB.
FB,
PFW.
FB.
FB.
FB.
FB,
GIV,
NW,
PFW,
UOP.
ELN
GIV
, RT
ELN
FB,
PFW
GIV
IFF
CI.
PFW
FB.
RT.
GIV
GIV
RT
GIV
IFF
IFF
GIV
GIV
GIV
CI.
GIV
, IFF
132
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. --Flavor and perfume materials for which U.S. production or sales were
reported, identified by manufacturer, 1970- -Continued
Manufacturers ' identification codes
(according to list in table 3)
FLAVOR AND PERFUME MATERIALS, ACYCLIC--Continued
Nonanol
Nonyl acetate
Ocimenol and acetate
Oct anal
3-Octanone (.Ethyl amyl ketone)
Octyl acetate
n-Octyl alcohol
n-Octyl formate
Omega decenol
Pseudo linalyl acetate
Pyrolysate ester
*Rhodinol
Rhodinyl acetate
Rhodinyl formate
Sodium allyl sulfonate
Tepyl acetate
3,7,ll-Trimethyl-l,6,10-dodecatriene-3-ol
3,5,5-Trimethylhexyl acetate
2,6,10-Trimethyl-9-undecen-l-al
3,6, 10-Trimethyl-9-undecen-2-one
Undecanal
9-Undecenal
10-Undecen-l-ol
Y-Valero lactone •
GIV
CI,
IFF.
GIV,
GIV.
FB.
GIV.
FB.
IFF.
IFF.
GIV.
FB,
GIV,
IFF.
SHL.
UOP.
HOF.
OPC.
GIV.
GIV.
GIV,
GIV.
GIV.
GIV.
GIV.
IFF.
FEL, GIV, IFF, LUE, NEO, SHL.
IFF.
FLAVOR AND PERFUME MATERIALS
TABLE 3. — Flavor and perfume materials: Directory of manufacturers, 1970
133
ALPHABETICAL DIRECTORY BY CODE
[Names o£ manufacturers that reported production or sales o£ flavor and perfume materials to the U.S. Tariff
Commission for 1970 are listed below in the order of their identification codes as used in table 2]
Code
Code
identi-
Name of Company
identi-
Name of Company
fication
fication
ABB
Abbott Laboratories
LUE
George Lueders S Co., Inc.
ARA
Arapahoe Chemicals Div. of Syntex Corp.
ARS
Arsynco, Inc.
ARZ
Arizona Chemical Co.
MON
MRT
MYW
Monsanto Co.
Morton Chemical Co.
Stepan Chemical Co.. Maywood Div.
BPC
Stauffer Chemical Co., Benzol Products
NCI
Union Camp Corp., Chemical Div.
CFC
Sun Chemical Corp.
NEC
Norda Essential Oil 5 Chemical Co.,
Inc.
CI
Chem-Pluer, Inc.
NTL
National Lead Co.
COM
Commercial Solvents Corp.
NW
Northwestern Chemical Co.
DOW
Dow Chemical Co.
OPC
Orbis Products Corp.
ELN
Elan Chemical Co.
PD
PEN
PFW
Parke, Davis S Co.
CPC International, Inc., Penick Div
Polak's Frutal Works, Inc.
FB
Pritzsche, Dodge & Olcott, Inc.
PPZ
Pfizer, Inc.
PEL
Felton International, Inc.
FLO
Florasynth, Inc.
FMT
Fairmount Chemical Co., Inc.
RDA
Rhodia, Inc.
FRM
Farmers' Chemical Co.
RT
F. Ritter 5 Co.
GAP
GAP Corp., Chemical Div.
SHL
Nitini, Inc. Div. of Shulton, Inc.
GIV
Givaudan Corp.
SKC
Sunkist Growers, Inc.
GLD
SCM Corp., Glidden-Durkee Div.
SLV
Sterwin Chemicals, Inc.
GRW
Great Western Sugar Co.
SW
Sherwin-Williams Co.
HN
Tenneco Chemicals, Inc.
TCC
Tanatex Chemical Corp.
HOP
Hoffman- LaRoche, Inc.
HPC
Hercules, Inc.
UCC
UNG
Union Carbide Corp.
Ungerer 5 Co.
IFF
International Flavor S Fragrances, Inc.
UOP
Universal Oil Products Co., UOP
IMC
International Minerals S Chemical Corp.
Chemical Div.
LAK
Lakeway Chemical Co.
VEL
VND
Velsicol Chemical Corp.
Van Dyk 5 Co., Inc.
Note. --For the complete names and addresses of the above reporting companies, refer to table 1 in the Appendix.
PLASTICS AND RESIN MATERIALS 135
Plastics and resin materials are high molecular weight polymers
which, at some stage in their manufacture, exist in such physical con-
dition that they can be shaped or otherwise processed by the application
of heat and pressure. Depending on the chemical composition, manufacturing
process or intended use, the commercial products may contain plasticizers,
fillers, extenders, stabilizers, coloring agents or other additives.
Plastics materials may be molded, cast or extruded into semifinished or
finished solid forms. Resin materials may be in the form of solutions,
pastes or emulsions for applications such as protective coatings,
adhesives, or paper and textile treatment.
Statistics on U.S. production and sales of synthetic plastics and
resin materials for 1970 are given in table 1.^ In general, the
statistics follow the outline of the Tariff Commission's monthly re-
port on the production and sales of synthetic plastics and resin materials
(S.O.C. Series P-70); however, the data given include some resins and
some companies which were not covered in the monthly reports and also
some adjusted figures supplied by the original reporting companies.
Consequently, many of the figures given in table 1 are reviSed from
those shown in the Commission's monthly release dated March 15, 1971,
containing 12-month cumulative totals for 1970. The end-use breakdowns
shown were developed with the advice of representatives of the plastics
industry, and the reported data reflect producers' determinations of
the use categories for their materials.
U.S. production of plastics and resin materials in 1970 totaled
19,210 million pounds--an increase of 4 percent from the revised total
of 18,557 million pounds produced in 1969. Sales in 1970 totaled 17,074
million pounds, valued at $3,266 million compared with 15,922 million
pounds, valued at $3,175 million in 1969.
Thermosetting materials are those which harden with a change in
composition in the final treatment so that they cannot again be softened
by heat or solvents. U.S. production of thermosetting materials totaled
3,525 million pounds in 1970 compared with the revised total of 3,544
million pounds in 1969. Production of the most important products in
1970 included phenolic resins (1,186 million pounds), urea and melamine
resins (746 million pounds), alkyd resins (636 million pounds), and
polyester resins (569 million pounds) .
Thermoplastic materials are those which can be repeatedly softened
by heat and shaped. U.S. production of thermoplastic materials totaled
15,685 million pounds in 1970 compared with the revised total of 15,013
million pounds in 1969. Production of the most important products in
1970 included polyethylene (5,844 million pounds), vinyl resins (3,756
million pounds), and styrene type materials (3,550 million pounds).
^ See also table 2 which lists these products and identifies the
manufacturers of each by codes. These codes are given in table 3.
136
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1.-- Plastics and resin materials: U.S. production and sales, 1970
[Quantities and values are given in terms of the total weight of the materials (dry basis). Listed below are all
plastics and resin materials for which any reported data on production or sales may be published. (Leaders are
used where the reported data are accepted in confidence and may not be published or where no data were reported.)
Table 2 lists all plastics and resin materials for which data on production or sales were reported and identifies
the manufacturers of each]
Kind and use
Production
Sales'
Quantity
Grand total
Plastics and resin materials, benzenoid'*
Plastics and resin materials, nonbenzenoid
THERMOSETTING RESINS
Total
Alkyd resins, total
Phthalic anhydride type
Polybasic acid type
Polyester resins, total^
Reinforced plastics sheets
All other reinforced plastics
Sur f ac e coatings
All other domestic uses
Export sales
Styrene-alkyd polyesters
Epoxy resins^:
Unmodified, total
Bonding and adhesives
Protective coatings
Reinforced plastics
All other domestic uses
Export sales
Modified'
Phenolic and other tar acid resins, total
Molding compounds
Bonding and adhesives resins for:
Laminating
Coated and bonded abrasives
Friction materials
Thermal insulation
Foundry or shell molding
Plywood
Fibrous and granulated wood
Protective coatings, unmodified and modified
All other uses
Export sales
Polyurethane and diisocyanate resins (excluding foam and
elastomers)
Polyurethane and polyester polyols^- ■
1,000
pounds
dpy basis^
19,209,919
6,799,570
12,410,349
5,524.691
559,615
75,992
569,251
3,886
165,125
(7,604)
1,185,910
337,984
128,078
29,648
47,436
132,822
94,873
199,233
58,110
37,949
119,777
126,301
63,477
1,000
pounds
17,074,309
1,000
do I lars
3,266,081
5,793,962
11,280,347
2,788,693
1,298,725
1,967,356
661,529
352,296
^1,290
271,577
60,719
505,950
76,237
15,053
62,492
364,259
7,757
60,531
10,951
3,624
158,189
16,928
69,157
33,223
19,917
18,984
(6,086)
°983,769
1,564
71,982
(5,291)
'195,494
504,968
83,620
21,642
4 3,286
64,929
80,669
182,981
48,205
22,627
112,150
18,692
99,015
18,869
59,430
4,126
See footnotes at end of table.
PLASTICS AND RESIN MATERIALS
137
TABLE 1.-- Plastics and resin materials: U.S. production and sales , 1970--Cbntinued
Kind and use
Production'
Quantity
THERMOSETTING RESINS--Continued
Urea and melamine resins, total
Textile treating and coating resins
Paper treating and coating resins
Bonding and adhesives resins for:
Laminating
Plywood
Fibrous and granulated wood
Protective coatings (straight and modified)
All other domestic uses (including molding)
Export sales
Dicyandiamide resins
All other thermosetting resins"
THERMOPLASTIC RESINS
Total
Acrylic resins'^ t--
Cellulosic plastics and resins'^
Polyamide resins, nylon type'^
Coumarone-indene and petroleum hydrocarbon resins, total -
Floor tile
Rubber compounding
All other uses
Export sales
Rosin modifications, total
Rosin and rosin esters, unmodified (ester gums)
All other
Polyethylene and copolymers, total
Density 0.940 and below: '^
Production and sales, total
Sales and use
Injection molding
Blow molding
Film and sheet
Extrusion coating
Wire and cable
Other extruded products except pipe and conduit
All other domestic uses
Export sales
Density over 0.940:
Production and sales, total —
Sales and use
Injection molding
Blow molding
Film and sheet
Extrusion coating
1,000
pounds
dry basis^
85,834
65,682
50,754
119,421
219,436
70,160
134,915
425
28,507
538,159
182,178
90,833
31,835
86,087
164,712
21,401
65,466
5,844,061
1,604,454
1,000
pounds
dry basis^
"661,738
1,000
dollars
°113,799
72,791
43,278
35,069
111,172
209,771
47,645
128,778
13,234
379
24,864
14,285,616
211
25,388
2,604,552
461,912
179,107
81,218
285,259
229,800
101,992
64,431
54,361
31,803
82,905
130,251
40,300
84,769
16,568
20,149
64,620
5,416,792
4,449
12,119
4,006,591
4,049,524
491,320
42,011
2,049,335
381,322
403,722
22,787
298,622
360,405
1,410,201
1,644,816
326,789
593,884
62,059
21,382
503,151
See footnotes at end of table,
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. — Plastics and resin materials: U.S. production and sales, 1970- -Continued
Kind and use
Production
Quantity
Unit
value^
1,000
pounds
dry basis^
THERMOPLASTICS RESINS--Continued
Polyethylene and copolyiiiers--Continued
Density over 0.940 — Continued
Production and sales--Continued
Wire and cable
Pipe and conduit
Other extruded products
All other domestic uses
Export sales
Polypropylene, production and sales, total
Sales and use
Injection molding
Film and sheet
Fibers and filaments
Other extruded products
All other domestic uses (including blow molding
extrusion, coating, wire and cable, and pipe
and conduit)
Export sales
Styrene plastics materials, total
ABS (acrylonitrile-butadiene-styrene) and SAN
(styrene-acrylonitrile) resins, total
Molding
Extrusion
All other domestic uses
Export sales
Styrene polymers and copolymers, other:
Production and sales, total
Straight polystyrene
Rubber-modified polystyrene
Styrene r-butadiene copolymer
All other styrene polymers
Sales and use
Molding
Textile and paper coating and treating
Emulsion paint
Extrusion
All other domestic uses (including foam and
foamable materials)
Export sales
Vinyl and vinylidene resins, total''*
Polyvinyl chloride and copolymers, production
and sales
Suspension homopolymer resins
Suspension copolymer resins
Dispersion (paste) resins and latexes
Polyvinyl chloride and copolymers, sales and
use, total
Calendering, except flooring
Flooring, calendered
Flooring , coated
Paper and textile uses
3,549,713
567,707
2,982,006
1,157,276
1,213,368
395,599
215,763
3.756,393
3,115,204
2,232,008
519,026
364,170
1,000
pounds
dry basis^
31,034
60,238
20,560
303,617
225,253
963.512
1,000
dollars
Per
pound
190.475
995,997
398,234
88,689
249,848
43,224
83,453
132,549
3,228,108
619,152
538,063
293,453
170,953
48,680
24,977
2,804,776
1,395,781
316,585
36,781
447,595
504,445
103,589
3,346,561
517,486
2,985,214
457,957
247,227
75,074
93,395
See footnotes at end of table.
PLASTICS AND RESIN MATERIALS ,
TABLE 1.— Plastics and resin materials: U.S. production and sales , 1970— Continued
139
Kind and use
Sales'
Production'
Quantity
Unit
value^
1,000
pounds
dry basis^
THERMOPLASTICS RES INS- -Continued
Vinyl and vinylidene resins --Continued
Polyvinyl chloride and copolymers, sales and
use--Continued
Protective coatings and adhesives
Wire and cable
Extruded film and sheet
Other extruded products
Sound records
Injection and flow molding
Plastisol formulating and molding
All other domestic uses
Export sales
Polyvinyl acetate:'"
Production and sales, total
Latexes
Resins
Sales and use, total
Emulsion paints
Adhesives
Paper- treating
Textile- treating
All other domestic uses
Export sales
Polyvinyl alcohol
Other vinyl and vinylidene resins
All other thermoplastic resins"
422,320
328,022
94,298
48,784
170,085
323,531
1,000
pounds
dry basis
85,399
408,726
193,620
492,429
140,580
113,365
113,054
376,394
187,994
365,259
382,506
134,848
123,973
22,754
17,215
79,934
3,782
39,571
94,730
238,378
1,000
dollars
12,734
36,646
Data for each specified end use are based on a percentage breakdown which includes captive consumption as well
as sales by original producers, unless otherwise specified. To avoid disclosures of individual company operations,
some totals are made equal to sales rather than sales-plus-use. Data for export sales include materials for all
uses and exclude fabricated and semi-fabricated forms.
^ Calculated from rounded figures.
^ Dry weight basis unless otherwise specified. Dry weight basis is the total weight of the material including
resin and coloring agents, extenders, fillers, plasticizers, and other additives, but excluding water and other
liquid diluents unless they are an integral part of the material.
'' Includes benzenoid plastics and resin materials as defined in part I of schedule 4 of the Tariff Schedules of
the United States .
^ Polyester resins are unsaturated alkyd resins, later to be copolymerized with a monomer (such as styrene or methyl
methacrylate) ; and polyallyl resins (such as diallyl phthalate and diglycol carbonate^ . Data are on an "as sold"
basis, including monomer if part of the resin system. Production and sales totals have been revised downward from
the monthly reports because some companies had reported incorrectly. The same revisions for the 1969 data would bring
those totals just below the 1970 totals.
^ Includes reactive diluents which are an integral part of the resin. Excludes the weight of hardeners sold in
association with the resin as part of a two-component system.
Data shown for modified epoxy resins are that part of the unmodified epoxy resins which is further processed.
° Data represent sales only.
Data represent polyether and polyester polyols which are intermediates for polyurethanes and are not themselves
used as plastics or resins. The data do not include isocyanates or other intermediates for polyurethanes. The data
here are incomplete because most of the polyurethane polyols are reported as polyhydric alcohol derivatives in the
Miscellaneous Chemicals section.
About 70 percent of production consisted of urea-formaldehyde type.
Includes silicone resins, furfuryl-type resins, toluenesulfonamide resins, acetone- formaldehyde resins, and other
thermosetting resins.
Does not include production or sales for fiber use.
Includes data for ethylene copolymers. Sales do not include sales by primary producers to other primary
producers; sales do include resales of purchased material by primary producers. Sales and use data are from
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. --Plastics and resin materials: U.S. production and sales , 1970-- Continued
Footnotes for table 1 — Continued
preliminary monthly reports which are not necessarily consistent with final annual data.
"* Data are on the basis of dry resin content, excluding the weight of plasticizers, extenders, fillers, coloring
agents, stabilizers or impact modifiers, unless otherwise noted.
Data for polyvinyl acetate produced and sold in latex form include the weight of any protective colloids which
are used as emulsion stabilizers and form an integral part of the resin system. Production does not include poly-
vinyl acetate used as a reactive intermediate for polyvinyl alcohol or other vinyl resins.
'^ Includes polyvinylidene chloride, polyvinyl butyral, polyvinyl formal, and other vinyl resins.
'' Includes acetal resins, polyester (mostly terephthalate) resins, polycarbonate resins, polyterpene resins,
non-nylon polyamide resins, a-methylstyrene resins, fluorocarbon resins, polybutylene-type resins, polyimide-type
resins, polyether Cnon-urethane) resins, and other thermoplastics.
PLASTICS AND RESIN MATERIALS
141
TABLE 2. --Plastics and resin materials for which U.S. production or sales were reported,
identified by manufacturer, 1970
[Plastics and resin materials for which separate statistics are given in table 1 are marked below with an
asterisk (*); chemicals not so marked to not appear in table 1 because the reported data are accepted in cc
fidence and may not be published. Manufacturers' identification codes shown below are taken from table 3.
X signifies that the manufacturer did not consent to his identification with the designated product]
Manufacturers' identification codes
(according to list in table 3)
THERMOSETTING RESINS
Acetone-formaldehyde resins-
*Alkyd resins, domestic:
*Phthalic anhydride type
*Polybasic acid type-
'Polyester resins-
Silicone resins
*Styrene-alkyd polyesters
Epoxy resins :
*Unmodified
*Modified
Furfuryl-type resins
*Phenolic and other tar acid resins-
*Polyurethane and diisocyanate resins-
*Polyurethane and polyester polyols
*Urea and melamine resins
*Dicyandiamide resins
All other thermosetting resins-
ACY, SNW.
ACY, APT, APV, ASH, ATR, BAL, BEN, BRU, CEL, CIK, CM,
COM, CPV, DEC. DSO, DUN, DUP, EW, FAR, FBR, FCD,
FLW, FOC, FRE, FSH, GEl, GIL, GLD, GRG, GRV, HAN,,
ICF, IPC, JOB, JSC, JWL, KMC, KMP, KPS, KPT, KYN,
MCC, MID, MMM, MNP, NCI, NPV, OBC, PER, PFP, PLS,
PPG, PRT, PRX, RCl, RED, REL, RH, SCN, SIP, SKT,
SM, SW, SYV, TV, X, X, x.
ACY, APV, ASH, BEN, CGL, CM, COM, DEC, DUN, DUP, EW,
FBR, FCD, FOC, GEl, GLD, GRV, HAN, HPC, HYC,
ICF, KMC, KYN, MCC, MID, MMM, MOB, NCI, NPV, PPG,
RCI, RED, RH, SCN, SKT, SM, SK, TV, x.
ACP, ACR, ACY, APD, ASH, CGL, CPV, DA, DEG, DSO, EPC,
EW, FMP, FRE, GEl, GLD, GNT, GRG, GRV, GYR, HKD,
ICF, IPC, KMC, KPS, KPT, MFG, MMM, MRO, OCF, ORO,
PLU, PPG, RCI, SCN, SED, SHA, SIC, SW, SYV, TXT,
VAL, X.
ASH, CGL, DCC, RCI, SPD, UCC .
ASH, CGL, EW, FLW, JOB, MCC.
CEL, CGY, DOW, RCI, RSY, SHC, UCC.
ASH, DSO, EW, FAR, FOM, HAP, IOC, JOB, MID, MMM, MNP,
MRB, MRT, NPV, OCF, PRX, RELj SCN, SED, SKT, x.
HVG, TXT, UNO.
ABS, ACR, AMR, ASH, BME, BOR, CBC, CBD, CBM, CD, CGL,
CLK, CPV, DSO, EW, FCD, FOM, FRE, FRL, GE, GEl, GRG,
GRV, HAN, HER, HKD, HPC, HVG, ICF, INL, IOC, IRl,
KPT, KYN, MCA, MID, MMM, MON, MRB, NCI, NPP, NTC,
OCF, PAI, PGU, PLS, PPG, PPL, PRX, PYZ, RAB, RCD,
RCI, REL, RGC, RH, RPC, SCN, SHA, SIM, SKT, SNC,
SPL, SW, SYV, UCC, UNO, UPL, VSV, WCA, WRD.
ASH, BFG, CEL, CGL, DA, DUP, EW, FAR, FRE, GPM, HAP,
HYC, ICI, JWL, KMC, MCC, MID, NPV, PEL, PFP, PFZ,
PRT, PVI, PYR, QUN, RCI, SCN, SKT, UPJ, WTC, x.
DUP, MOB, PFZ, RCI, SPD, WTC.
ACP, ACY, AMR, APX, ASH, BOR, CAP, CBC, CBD, CEL, CGL,
CLK, CMP, CPV, DAN, DSO, DUP, EFH, FOR, GAF, GLD,
GRV, HAN, HNC, HPC, HRT, IRI, JSC, KPS, MID, MMM,
MON, NPP, NTC, OCF, PC, PGU, PMC, PPG, PPL, QCP, RCI,
REL, RH, RPC, SAC, SBC, SED, SNW, SOR, STc| SW, SYV,
TXT, UNO, UPL, USO, VAL, WRD, x.
ECC, CGY, JSC, RPC, SBC, SNW, VAL, WIC.
EW, MON, RH, USR, VAL.
462-669 O - 72 - 10
142
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Plastics and resin materials for which U. S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
THERMOPLASTIC RESINS
Acetal resins
* Aery lie resins
*Cellulosic plastics and resins
Polyamide resins:
*Nylon type
Non-nylon type
*Coumarone-indene and petroleum hydrocarbon resins-
Fluorocarb on resins
*Rosin modifications:
*Rosin and rosin esters, unmodified (ester gums)-
*A11 other
•Polyethylene and copolymers:
•Density 0.940 and below
•Density over 0.940
•Ethylene copolymers
•Polypropylene resins
Polybutene and polyisobutylene resins
Polycarbonate resins
Polyester resins, saturated
Polyterpene resins
•Styrene type plastics materials:
•ABS and SAN resins
•Styrene and styrene copolymer resins other than
ABS and SAN.
a-Methylstyrene polymers
•Vinyl resins:
•Polyvinyl chloride and copolymer resins-
•Polyvinyl acetate resins
•Polyvinyl alcohol resins
Polyvinyl butyral resins
Polyvinylidene chloride resins
All other vinyl resins
All other thermoplastic resins
CEL, DUP.
ACY, ASH, BAS, CEL, DUP, EFH, FLH, GLC, GLX, HNC,
HRT, JNS, JOB, JSC, KMC, NPV, PCI, PVI , QUN, RH,
RPC, SAR, SED, SEY, UCC, VAL, VPC, WAY, WIC, x.
CEL, DOW, EKT, HN, HPC, MON, RSB, SKT, SPY.
ALF, BCM, CEL, DUP, FG, GNM, GOC, HN, MON, POL, SNW.
DUP, EMR, GNM, UCC.
ACC. ACP, DSO, DUP, ENJ, MID, NEV, PAI, PPG, RCI,
SKT, VEL, WTC.
DUP, ICl, MMM.
APV, ASH, CBY, DPP, FAR, FLW, FRP, MCC, NCI, SKT.
APV, ASH, CBY, DPP, EW, FAR, FRP, NCI, RH, SCF.
ACP, CBN, CEL, CPX, DOW, DUP, EKX, ENJ, GOC, KPP,
MON, RCC, SHC, UCC, USI .
ACP, CEL, CPX, DOW, DUP, EKX, GOC, HPC, KPP, MON, PLC,
UCC, USI, X.
DSO, DUP, ENJ, USI.
ACC, DA, EKX, ENJ, HPC, NVT, RCC, SHC.
ENJ, RH, SM.
GE, MOB.
DUP, EKT.
CBY, HPC, PAI, SCN.
BFG, DOW, FBF, FIR, GRD, KPP, MCB, MON, RCC, UCC, USR.
ACC, AEP, ATR, BAS, BCN, BFG, BOR, CSD, DOW, DPI, DSO.
DUP, FBF, FG, FIR, FLH, GAF, GLD, GNT, GOR, GRD, GYR,
HLM, IOC, JNS, JSC, KPP, MNV, MON, MRT, NLC, ONX, PAI,
PLA, POL, PRX, PVI, RCC, RH, RPC, SBI, SHC, SKT,
SOL, SPE, UBS, UCC, UOC, USR, WIC, x.
ACC, DOW.
ACP, AME, BFG, BOR, CPL, CUC, DA, DOW, ESC, FIR, GNT,
GRA, GYR, HN, KYS, MON, NSC, PNT, RUB, SFA, THC,
TNA, UCC, USR.
AML, ASH, BEN, BOR, CEL, CUC, DAN, DSO, DUP, FAR, FLH,
FSH, GLC, GLD, GRD, HAN, HNC, HRT, JOB, JSC, KMC,
KMP, MCC, MMM, MON, NPV, NSC, OBC, OCF, ONX, PII,
PPG, PRX, PVI, QCP, RCI, RPC, SBI, SCO, SED, SEY,
SPC, UCC, UOC, WIC, X. X. X.
BOR, CUC, DUP, MON, SEY.
DUP, MON, UCC.
BAS, DOW, DUP, GRD, MRT.
EW, MCC, MON, UCC, USR.
ACC, DUP, RPC, WTC, x.
PLASTICS AND RESESf MATERIALS
143
TABLE 3. --Plastics and resin materials: Directory of manufacturers, 1970
ALPHABETICAL DIRECTORY BY CODE
[Names of manufacturers that reported production or sales of plastics and resin materials to the U.S. Tariff
Commission for 1970 are listed below in the order of their identification codes as used in table 2]
Code
Code
identi-
Name of company
identi-
Name of company
fication
fication
ABS
Abex Corp., American Brakeblok Div
DUP
E. I. duPont de Nemours 6 Co., Inc.
ACC
Amoco Chemical Corp.
AGP
Allied Chemical Corp., Plastics Div.
ECC
Eastern Color f, Chemical Co.
ACR
CPC International, Inc., Acme Resin Div,
EFH
E. F. Houghton S Co.
ACY
American Cyanamid Co.
Eastman Kodak Co.:
AEP
A § E Plastics Pak Co., Inc.
EKT
Tennessee Eastman Co., Div.
ALF
Allied Chemical Corp., Fibers Div.
EKX
Texas Eastman Go. Div.
AME
American Chemical Corp.
EMR
Emery Industries, Inc.
AML
Amalgamated Chemical Corp.
ENJ
Enjay Chemical Co.
AMR
Pacific Resins S Chemical Co.
EPC
Epoxylite Com.
APD
Atlas Chemical Industries, Inc.
ESC
Air Products f, Chemicals, Inc. Escambia
APT
Whittaker Corp., Mol Rez Div.
Chemical Plant
APV
Armstrong Chemcon
EW
Westinghouse Electric Corp., Industrial
APX
Apex Chemical Co., Inc.
Plastics Div. , Chemical Products Plant
ASH
Ashland Oil, Inc., Ashland Chemical Co.
Div.
FAR
Farnow, Inc.
ATR
Atlantic Richfield Co., ARCO Chemical Co.
FBF
Dart Industries, Inc., Fiberfil Div.
Div.
FBR
Pabco Paint Corp.
FCD
France, Campbell § Darling, Inc.
BAL
Baltimore Paint § Chemical Corp.
FG
Foster Grant Co., Inc.
BAS
BASF-Wyandotte Corp.
FIR
Firestone Tire § Rubber Co., Firestone
BCM
Belding Chemical Industries
Plastics Co. Div.
BCN
Lehn S Fink Products Corp., Beacon Div.
FLH
H. B. Fuller Co.
BEN
Bennett ' s
FLW
Fuller-O'Brien Com.
BFG
B. F. Goodrich Co., B.F. Goodrich Chemical
FMC Corp . :
Co. Div.
FHP
Organic Chemicals Div.
BME
Bendix Corp., Friction Materials Div.
FOG
Farac Oil fi Chemical Co. Div of Handschy
BOR
Borden Co., Borden Chemical Co. Div.
Chemical Co.
BRU
M. A. Bruder 5 Sons, Inc.
FOM
Formica Corp.
FRE
Freeman Chemical Corp.
CAP
DuPlan Corp., Rochester Button Div.
FRL
Firestone Tire § Rubber Co., Firestone
CBC
Georgia-Pacific Corp., Coos Bay Div.
Foam Products Co.
CBD
Chembond Corp.
FRP
FRP Company
CBM
Carborundum Co., Coated Abrasives Div.
FSH
Frish § Go. , Inc.
CBN
Cities Service Co., Petrochemicals Group
CBY
Crosby Chemicals, Inc.
GAF
GAF Corp . :
CD
Budd Co., Polychem Div.
Chemical Div.
CEL
Celanese Corp. :
Textile Chemicals Div.
Celanese Coatings Co.
GE
General Electric Co.:
Celanese Plastics Co.
GEI
Insulating Materials Dept.
CGL
Cargill, Inc.
GIL
Gilman Paint § Varnish Co.
CGY
Giba-Geigy Corp. S Ciba Products Co. Div.
GLG
General Latex § Chemical Corp.
crfc
Tenneco Chemicals, Inc., Gal/Ink Div.
GLD
SCM Corp., Glidden-Durkee Div.
CLK
Clark Oil § Refining Corp., Clark Chemical
GLX
Electro-Seal Glasflex Corp.
Co.
GNM
General Mills, Chemical Inc.
CM
Carpenter-Morton Co.
GNT
General Tire S Rubber Co., Chemical Div.
CMP
Commercial Products Co., Inc.
GOG
Gulf Oil Corp., Gulf Oil Go.
COM
Commercial Solvents Corp.
Chemicals Dept. - United States
CPL
Conoco Plastics
GOR
Gordon Chemical Co., Inc.
CPV
Cook Paint 5 Varnish Co.
GPM
General Plastics Manufacturing Co.
CPX
Ghemplex Co.
GRA
Great American Chemical Corp.
CSD
Gosden Oil § Chemical Co.
GRD
W. R. Grace 5 Co., Polymers Chemicals Div.
cue
Air Reduction Co., Inc., Chemical
GRG
P. D. George Go.
S Plastics Div.
GRV
Guardsman Chemical Coatings, Inc.
GYR
Goodyear Tire § Rubber Go.
DA
Diamond Shamrock Corp.
DAN
Dan River Mills, Inc.
HAN
Hanna Chemical Coating Corp.
DAV
Conchemco, Inc., H. B. Davis Co. Div.
HAP
Applied Plastics Co., Inc.
DCC
Dow Coming Corp.
HER
Heresite 5 Chemical Co.
DEC
Degan Oil 5 Chemical Co.
HKD
Hooker Chemical Corp., Durez Div.
DOW
Dow Chemical Co.
HLM
U.S. Industries, Inc., E. Helman Go. Div.
DPI
Diamond Plastics, Inc.
HN
Tenneco Chemicals, Inc.
DPP
Dixie Pine Products Co., Inc.
HNC
H.§ N Chemical Co.
DSO
DeSoto, Inc.
HPC
Hercules, Inc.
DUN
Frank W. Dunne Co.
HRT
Hart Products Corp.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 3. --Plastics and resin materials: Directory of manufacturers, 1970— Continued
Name of company
Haveg Industries
Dexter Corp., Hysol Co. Div.
Inmont Corp.
I ICI America, Inc.
Inland Steel Co., Inland Steel Container
Co. Div.
lonac Chemical Co. Div of Sybron Corp.
Interplastic Corp., Commerical Resins Div.
Ironsides Resins, Inc.
S. C. Johnson S Son Inc.
Jones-Blair Paint Co.
Jersey State Chemical Co.
Jewel Paint f, Varnish Co.
Kohler-McLister Paint Co.
Kelly-Moore Paint Co.
Sinclair-Koppers Co.
Koppers Pittsburgh Co.
Koppers Co., Organic Materials Div.
Kyanize Paints, Inc.
Keysor Chemical Corp.
Masonite Corp., Alpine Div.
Borg-Warner Corp., Marbon Chemical Div.
McCloskey Varnish Co.
North American Rockwell Corp., Reinforced
Plastic Operations, Automotive Products Di\
Dexter Corp., Midland Div.
Minnesota Mining S Manufacturing Co.
Minnesota Paints, Inc.
Johns-Manville Corp.
Mobay Chemical Co.
Monsanto Co.
Marblette Co., Div. of Allied Products
Corp.
W. R. Grace 8 Co., Marco Chemical Div.
Morton Chemical Co.
Union Camp Corp., Chemical Div.
Neville Chemical Co.
Nalco Chemical Co.
Enjay Chemical Co., Enjay Fibers 5 Laminates
Co. Div.
Norris Paint S Varnish Co., Inc.
National Starch S Chemical Corp.
National Casein Co.
Novamont Corp., Neal Works
O'Brien Corp.
Owens-Coming Fiberglas Corp.
Millmaster Onyx Corp., Onyx Chemical Corp.
Chevron Chemical Co.
Pennsylvania Industrial Chemical Corp.
Proctor Chemical Co., Inc.
Pioneer Chemical Works, Inc.
Pelron Corp.
Perry S Derrick Co.
Midwest Manufacturing Corp.
Pfizer, Inc.
Gulf Oil Corp., Gulf Adhesives
Polymer Industries, Inc.
Richardson Co., Polymeric Div.
Phillips PetroleiM Co.
Plastics Engineering Co.
Code
identi-
fication
PLU
p^c
PNT
pni
PPG
PPL
PRT
PRX
PVI
PYR
PYZ
OCP
dlTN
RAB
RCC
RCD
RCI
RED
REL
RPC
RSB
RSY
RUB
SAC
SAR
SBC
SBI
SCF
SCN
SCO
SED
SEY
SFA
SHA
SHC
SIC
SIM
SIP
SKT
SM
SNC
SNW
SOL
SOR
SPC
SPD
SPE
SPL
SPY
STC
THC
TNA
Name of company
Plumb Chemical Corp.
Plastics Manufacturing Co.
Pantasote Co.
Polymer Corp.
PPG Industries, Inc.
Pioneer Plastics Corp.
Pratt § Lambert, Inc.
Purex Corp. , Ltd.
Polyvinyl Chemicals, Inc., Div of
Beatrice Foods Co.
Poly Resins
Polyrez Co. , Inc.
Quaker Chemical Com.
K. J. Quinn S Co. , Inc.
Raybestos-Manhattan, Inc., Raybestos Div.
Rexene Polymers Co .
Richardson Co.
Reichhold Chemicals, Inc.
Red Spot Paint Co., Inc.
Reliance Universal, Inc.
§ Rel Rez Div.
Rogers Corp.
Rohm 5 Haas Co.
Millmaster Onyx Corp., Refined-Onyx Div.
Rosenberg Bros, fj Co.
Resyn Corp.
Hooker Chemical Corp., Ruco Div.
Southeastern Adhesives Co.
Sartouier Resins, Inc.
Scher Bros . , Inc .
Standard Brands Chemical Industries, Inc.
Schaefer Varnish Co. , Inc.
Schenectady Chemicals, Inc.
Scholler Bros. , Inc.
Conchemco, Inc., Kansas City
Div.
Seydel-Woolley S Co., Inc.
Stauffer Chemicals Co., Specialty
Chemical Div.
Shanco Plastics 5 Chemicals, Inc.
Shell Oil Co., Shell Chemical Co. Div.
Vistron Corp., Silmax Div.
Simpson Timber Co.
Sipes Chemical Coatings Co.
Textron Inc., Spencer Kellogg Div.
Mobil Chemical Co.
Sonoco Products Co.
Sun Chemical Corp., Chemicals Div.
Solar Chemical Corp.
Thomason Industries, Inc., Southern Resin
Div.
Sinclair Paint Co.
General Electric Co., Silicone Products.
Dept.
Petrochemical Investment Corp.
Saulding Fibre Co., Inc.
Standard Pyroxoloid Corp.
Sou-Tex Chemical Co., Inc.
Sherwin-Williams Co.
Synvar Corp.
Olin Corp., Thompson Plastics
Ethyl Corp.
Sun Chemical Corp., General Printing Ink Div.
PLASTICS AND RESIN MATERIALS
TABLE 3. --Plastics and resin materials: Directory of manufacturers, 1970 — Continued
145
Code
Code
identi-
Name of company
identi-
Name of company
fication
fication
TXT
1 ■
Textilana Corp.
USR
Uniroyal, Inc., Chemical Div.
UBS
A. E. Staler Manufacturing Co., Staley
VAL
"Valchem
Chemicals Div.
VEL
"Veliscol Chemical Corp.
UCC
Union Carbide Corp.
VPC
Verona Corp.
UNO
United-Erie, Inc.
VSV
Valentine Sugars, Inc.
UOC
Union Oil Co. of California
UPJ
Upjohn Co.
WAY
Philip A. Hunt Chemical Corp.,
UPL
Champion Papers, Inc., U.S. Plywood Div.,
Wayland Chemical Div.
California Operations, Shasta Area
WCA
West Coast Adhesives Co,
USI
National Distillers § Chemical Corp.:
WIC
Wica Chemical Inc.
U.S. Industrial Chemicals Co. Div.
WTO
Weyerhaeuser Co., Wood Products
USI
National Petro Chemical Corp.
Div.
USO
U. S. Oil Co.
WTC
Witco Chemical Co. , Inc.
Note. --For complete names and addresses of the above reoorting companies, refer to table 1 in the Appendix.
RUBBER-PROCESSING CHEMICALS 147
Rubber-processing chemicals are organic compounds that are added
to natural and" synthetic rubbers to give them qualities necessary for
their conversion into finished rubber goods. In this report, statis-
tics are given for cyclic and acyclic compounds, by use--such as
accelerators, antioxidants, blowing agents, and peptizers. Data on
production and sales of rubber-processing chemicals in 1970 are given
in table 1. ^
Production of rubber-processing chemicals as a group in 1970
amounted to 298 million pounds, or 1.7 percent less than the 303 rail-
lion pounds reported for 1969. Sales of rubber-processing chemicals
in 1970 amounted to 228 million pounds, valued at $149 million, com-
pared with 229 million pounds, valued at $144 million, in 1969. The
decreased production and sales of rubber-processing chemicals in 1970
is attributable principally to the decreased production and sales of
acyclic compotmds, particularly the dithiocarbamic acid derivatives.
The output of cyclic rubber-processing chemicals in 1970 amounted
to 255 million poimds, or about the same amovmt that was reported for
1969. Sales in 1970 were 196 million pounds, valued at $134 million,
compared with 194 million pounds, valued at $127 million in 1969. Of
the total output of cyclic rubber-processing chemicals in 1970, accel-
erators accounted for 35.1 percent and antioxidants for 60.0 percent.
Production of antioxidants, which amounted to 153.2 million pounds in
1970, included 114.6 million pounds of amino compounds and 38.7 million
pounds of phenolic and phosphite compounds. Sales of amino antioxi-
dants in 1970 were 86.4 million pounds, valued at $60.7 million; sales
of phenolic and phosphite antioxidants were 29.4 million poimds, valued
at $22.1 million.
Production of acyclic rubber -processing chemicals in 1970 amounted
to 42.8 million pounds, a decrease of 12.1 percent from the 48.7 million
pounds reported for 1969. Sales in 1970 totaled 31.4 million potinds,
valued at $15.4 million, compared with 35.5 million pounds, valued at
$17.2 million, in 1969. Accelerators, principally dithiocarbamic acid
derivatives and tetramethylthiuram sulfides, accounted for 50.8 percent
of the output of acyclic rubber-processing chemicals for 1970. Dodecyl
mercaptans accounted for 31.2 percent. Blowing agents, modifiers,
shortstops, and lubricating and conditioning agents accounted for the
remainder of the output of acyclic compounds.
See also table 2 which lists these products and identifies the
manufacturers by code. These codes are given in table 3.
148
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. — Rubber-processing chemicals: U.S. production and sales, 1970
[Listed below are all rubber-processing chemicals for which any reported data on production or sales may be published.
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data were
reported.) Table 2 lists separately all rubber-processing chemicals for which data on production or sales were re-
ported and identifies the manufacturers of each]
Sales
Quantity
Unit
value
Grand total
RUBBER-PROCESSING CHEMICALS, CYCLIC
Total
Accelerators, activators, and vulcanizing agents, total
Aldehyde-amine reaction products
Dithiocarbamic acid derivatives
Thiazole derivatives, total
N-Cyclohexyl-2-benzothiazolesulfenamide
2,2'-Dithiobis(benzothiazole)
2-Mercaptobenzothiazole
2-Mercaptobenzothiazole, zinc salt
All other thiazole derivatives ■;
AH other accelerators, activators, and vulcanizing agents'
Antioxidants, antiozonants, and stabilizers, total
Amino compounds, total
Substituted p-phenylenediamines, total
N,N'-Bis(l,4-dimethylpentyl) -p-phenylenedi amine
N,N'-Diphenyl-p-phenylenediamine
All other substituted p-phenylenediamines
Octyldiphenylamine
N-Phenyl-2-naphthylamine
All other amino compounds'
Phenolic compounds, total
Polyphenolics (including bisphenols)
Phenol, alkylated
Phenol, styrenated
All other phenolic compounds
Phosphite compounds--.-,-- — '
Retarder: N-Nitrosodiphenyisjnine
All other cyclic rubber-processing chemicals
RUBBER-PROCESSING CHEMICALS, ACYCLIC
Total
Accelerators, activators, and vulcanizing agents, total
Dithiocarbamic acid derivatives, total^
Dibutyldithiocarbamic acid, zinc salt
Diethyldithiocarbamic acid, zinc salt
Dimethyldithiocarbamic acid, zinc salt
All other dithiocarbamic acid derivatives
1,000
1,740
271
77,268
5,903
23,202
6,923
4,867
36,373
10,286
153.245
114,561
60,303
5,337
1,757
53,209
3,130
4,348
46,780
23,619
13,546
7,131
1,444
1,498
15,065
1,528
11,139
21,765
8,196
2,525
2,483
1,456
1,732
1,000
227,861
196,485
69,627
1,323
212
58,389
4,680
11,029
5,250
4,086
33,344
9,703
115,817
86,397
41,066
1,472
39,594
1,946
43,385
19,484
12,243
4,612
1,272
1,357
9,936
830
10,211
15,768
7,039
2,386
2,176
1,386
1,091
1,000
dollars
148,959
40.364
1,415
506
30,783
3,605
5,887
2,111
2,104
17,076
7,660
82_,725
60,669
38,335
1,519
36,816
1.064
21,270
17,172
13,353
2,246
510
1,063
4,884
514
9,931
9.722
5,139
1,988
1,215
622
1,314
Per
pound
$0.65
1.07
2.39
.53
.77
.53
.40
.51
.51
.79
.71
.70
.93
1.09
.49
.40
.78
.49
.62
.97
.49
.62
.45
1.20
See footnotes on following page.
RUBBER-PROCESSING CHEMICALS
TABLE 1. — Rubber-processing chemicals: U.S. production and sales, 1970- -Continued
149
Production
Sales
Quantity
Unit
value^
RUBBER-PROCESSING CHEMICALS, ACYCLIC- -Continued
Accelerators, activators, and vulcanizing agents--Continued
Thiurams, total
Bisfdimethylthiocarbamoyl) disulfide
Bis(dimethylthiocarbamoyl) sulfide
All other thiurams
All other accelerators, activators, and vulcanizing agents--
Polymerization regulators: Dodecyl mercaptans
Shortstops: Dimethyldithiocarbami-c acid, sodium salt
All other acyclic rubber-processing chemicals'
1,000
pounds
13,243
8,613
2,130
2,500
326
13,358
3,882
3,809
1,000
pounds
8,511
5,942
1,800
769
218
11,474
1,253
2,881
1,000
do I lars
4,356
2,565
1,345
446
227
4,115
318
1,270
Per
pound
Calculated from rounded figures.
^ Includes guanidines.
^ Includes aldehyde- and acetone-amine reaction products .
" Includes blowing agents, peptizers and other uses not separately shown.
Data on dithiocarbamates included in this table are for materials used chiefly in the processing of natural
and synthetic rubbers. Data on dithiocarbamates which are used chiefly as fungicides are included in the section
"Pesticides and Related Products".
^ Includes data for small amounts of tetramethylthiuram sulfides for uses other than in the processing of natural
and synthetic rubbers.
Includes xanthates and disulfides.
Includes blowing agents, conditioning and lubricating agents, polymerization regulators, shortstops and
physical property improvers.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.
-Rubber-processing chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970
[Rubber-processing chemicals for which separate statistics are given in table 1 are marked below with an asterisk (*);
chemicals not so marked do not appear in table 1 because the reported data are accepted in confidence and may not
be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that the
manufacturer did not consent to his identification with the designated product]
Manufacturers' identification codes
(according to list in table 3)
RUBBER-PROCESSING CHEMICALS, CYCLIC
* Accelerators, activators, and vulcanizing agents:
*Aldehyde-amine reaction products:
Acet aldehyde-aniline condensate
n-Butyraldehyde- aniline condensate
Butyraldehyde-butylideneaniline condensate
a-Ethyl-6-propylacrylanilide
Hept aldehyde-aniline condensate
Triethy It rimethylenetri amine
*Dithiocarbamic acid derivatives:
nibenzyldithiocarbamic acid, sodium salt
Dibenzyldithiocarbamic acid, zinc salt
Dibutyldithiocarbamic acid, N,N-dimethylcyclohexyl-
amine salt.
Dibutyldithiocarbamic acid, diphenylguanidine salt —
2,4-Dinitrophenyl dimethyldithiocarbamate
Piperidinecarbodithioic acid, piperidinium-potassium
salts, mixed.
Guanidines :
Dicatechol borate, di-o-tolylguanidine salt
1,3-Diphenylguanidine
Diphenylguanidine phthalate
1,3-Di-o-tolylguanidine
Dodecyltetramethylguanidine
1,2,3-Triphenylguanidine
*Thiazole derivatives:
2-Benzothiazyl N,N-diethylthiocarbamoyl sulfide
l,3-Bis(2-benzothiazolylmercaptomethyl) urea
N-tert-Butyl-2-benzothiazolesulfenamide
*N-Cyclohexyl-2-benzothiazolesulfenamide
N,N-Dii5opropyl-2-benzothiazolesulfenamide
N-(2,6-Dimethylmorpholino)-2-benzothiazolesulfenamide
*2,2'-Dithiobis(benzothiazole}
*2-Mercaptobenzothiazole
2-Mercaptobenzothiazole, copper salt
2-Mercaptobenzothiazole, zinc chloride
*2-Mercaptobenzothiazole, zinc salt
4-Morpholinyl-2-benzothiazyl disulfide
N-Oxydiethylene-2-benzothiazolesulfenamide
Thiazoline-2-thiol
All other cyclic accelerators, activators, and vulcan-
izing agents:
p-Benzoquinonedioxime
Bis (p-aminocyclohexyl) methane carbamate
Bis(morpholinothiocarbonyl) disulfide
Dibenzoyl-p-quinonedioxime
Dib en zyl amine
N,N'-Dicinnamylidene-l,6-hexanediamine
Di-N,N'-pentamethylenethiuram tetrasulfide
4,4'-Dithiodimorpholine
2 -Imidazoline- 2 -thiol
m-Phenylenebismaleimide
Poly-p-dinitrosobenzene
All other
*Antioxidants, antiozonants, and stabilizers:
*Araino compounds :
Aldehyde- and acetone-amine reaction products:
Acetaldehyde-aniline hydrochloride condensate
Aldol-a-naph thy 1 amine condensate
Butyraldehyde-aniline condensate
USR.
DUP, MON, RCD, USR.
MON.
ceo.
USR.
USR.
USR.
USR.
MON. '
ceo.
USR.
DUP.
DUP.
ACY.
MON.
ACY.
DUP.
ACS.
PAS.
MON.
BFG,
ACY,
ACY.
MON.
ACY,
ACY,
ACY.
DUP.
ACY,
GYR.
ACY,
ACY.
MON.
BFG, MON, USR.
BFG, GYR, MON, USR.
BFG, GYR, MON, USR.
BFG, DUP, GYR, USR.
BFG, MON.
CTN, DUP.
DUP.
ACY.
CTN, USR.
MLS, USR.
DUP.
DUP, VNC.
MON, RBC, VNC.
DUP, RBC.
DUP.
DUP.
DUP.
USR.
BFG.
DUP.
RUBBER-PROCESSING CHEMICALS
151
TABLE 2. — Rubber- processing chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3 )
RUBBER-PROCESSING CHEMICALS, CYCLIC--Continued
* Antioxidants, antiozonants, and stabilizers--Continued
*Aiiiino coinpounds--Continued
Aldehyde- and acetone-amine reaction products--
Continued.
Diphenylamine-acetone condensate
Phenyl -2 -naphthylamine-acetone condensate
*Substituted p-phenylenediamines:
*N,N' -Bis (l,4-dimethylpentyl)-p-phenylenedi amine
N,N'-BisCl-ethyl-3-methylpentyl}-p-phenylenediamine-
N,N'-Bis(l-methylheptyl) -p-phenylenediajnine
N-sec-Butyl-N'-phenyl-p-phenylenediamine
N-Cyclohexyl-N'-phenyl-p-phenylenediaraine
Diarylarylenediamines, mixed
N-(1,3-Dimethylbutyl) -N '-phenyl -p-phenylenedi amine- ■
N- (1,4-Dimethylpentyl)-N '-phenyl -p-phenylenedi amine-
N,N'-Di-2-naphthyl-p-phenylenediamine
*N,N'-Diphenyl-p-phenylenedi amine
N-Isopropyl-N'-phenyl-p-phenylenediamine
Nitroso-N-phenylenedi amine
All other substituted p-phenylenediamines
Other amino compounds :
p-Anilinophenol
l,2-Dihydro-6-dodecyl-2,2,4-trimethylquinoline
l,2-Dihydro-6-ethoxy-2,2,4-trimethylquinoline
l,2-Dihydro-2,2,4-trimethylquinoline
4,4'-Dimethoxydiphenylamine
Dinonyldiphenylamine
4,4' -Dioctyldiphenylamine
N,N'-Diphenylethylenedi amine
N,N'-Diphenyl-l,3-propanediamine
N,N'-Di-o-tolylethylenediamine
p-lsopropoxydiphenylamine
4,4'-Methylenedianiline
*Octyldi phenyl amine
Octyldiphenylamine mixture (mono-, nonyl-, and di-J
N-Phenyl-1-naphthylamine
*N-Phenyl-2-naphthylamine
p-(p-Toluenesulfonamide)dipheny lamina
All other
*Phenolic compounds:
*Polyphenolics (including bisphenols) :
Bisphenol, hindered
4,4'-Butylidenebis(6-tert-butyl-m-cresol)
2,S-Di-sec-butyldecylhydroquinone
2 , 5-Di - [ 1 , 1 -dimethy Ipropy 1 ) hydroquinone
2,2'-Methylenebis(6-tert-butyl-p-cresol)
2,2' -Methylenebis (6-tert-butyl-4-ethylphenol)
2,2'-Methylenebis [6-(l-methylcyclohexyl5 -p-
cresol]
2, 2 '-Methylenebis (6 -tert-octyl-p-cresol3
2,2'-Thiobis(4,6-di-sec-amylphenol)
4,4'-Thiobis(6-tert-butyl-m-cresol3
Thiobisphenol, alkylated
l,l,3-TriC2-methyl-4-hydroxy-5-tert-butylphenyl)-
butane.
ACY,
BFG,
USR.
USR.
EKT,
MON,
USR.
MON,
UPM.
BFG,
MON,
UPM.
USR.
USR.
BFG,
GYR.
GYR,
USR.
USR.
BFG.
BFG,
DUP,
SDC, USR
MON,
USR.
USR.
MON.
BFG.
MON.
MON.
BFG,
MON.
DUP.
ACY.
BFG.
CCO,
DA,
x.
ceo.
CCO.
BFG.
USR.
ACY,
NPI,
PAS, USR
BFG.
DUP.
BFG,
DUP,
USR.
USR.
DUP.
GYR,
USR
MON.
USR.
MON.
ACY,
ASH
ACY.
ICl.
ACY.
MON.
MON.
USR.
ICI.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. --Rubber-processing chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3 )
RUBBER-PROCESSING CHEMICALS, CYCLIC--Continued
* Antioxidants , antiozonants, and stabilizers--Continued
*Phenolic compounds--Continued
•Other phenolic antioxidants and stabilizers:
o-Cresol, alkylated
N- Lauroy 1 -p- aminopheno 1
*Phenol, alkylated
Phenol, hindered
*Phenol, styrenated
N-Stearoyl-p-aminophenol
Xylene I, alkylated
*Phosphite compounds:
Diphenyldecyl phosphite
Nonyl phenyl phosphites, mixed
Phenyldidecyl phosphite
Polymeric phosphite
Blowing agents:
N,N'-Dimethyl-N,N'-dinitrosoterephthalamide
Dinitrosopentamethylenetetramine
p,p'-Oxybis(benzenesulfonhydrazide)
p-Toluenesulfonylhydrazide
p-Toluenesulfonylsemicarbazide
Peptizers:
Alkylated o-thiocresol
Alkylated thiophenol, zinc salt
Aryl raercaptans
2-Benzamidothiophene, zinc salt
Dicresyl disulfide
2' ,2 ' ' '-Dithlobis(benzanilide)
Dixylyl disulfides, mixed
2-NaphthalenethioI
Pentachlorobenzenethiol
Thiocresol
Thiophenol (Benzenethiol)
Xylenethiol
*Retarders : N-Nitrosodiphenylamine
Other cyclic rubber-processing chemicals:
p-tert-Amylphenol sulfide (tackifier)
4-Chloro-2,6-bis(2,4-dihydroxybenzyl3phenol
Phenol cyanurate complex
All other
RUBBER- PROCESSING CHEMICALS, ACYCLIC
•Accelerators, activators, and vulcanizing agents:
*Dithiocarbamic acid derivatives:
Dibutyldithiocarbamic acid, potassium salt
Dibutyldithiocarbamic acid, sodium salt
•Dibutyldithiocarbamic acid, zinc salt
Diethyldithiocarbamic acid, selenium salt
Diethyldithiocarbamic acid, sodium salt
Diethyldithiocarbamic acid, tellurium salt
•Diethyldithiocarbamic acid, zinc salt
Dimethyldithiocarbamic acid, bismuth salt
Dimethyldithiocarbamic acid, copper salt
Dimethyldithiocarbamic acid, lead salt
Dimethyldithiocarbamic acid, selenium salt
Dimethyldithiocarbamic acid, sodium salt and sodium
polysulfide.
•Dimethyldithiocarbamic acid, zinc salt
All other
PIT.
MLS.
ACY,
BFG,
ceo.
GYR,
NEV,
PIT
DUP,
GYR,
USR.
BFG,
GYR,
NEV,
USR.
MLS.
PIT.
HK.
NPI,
USR.
NPI.
DUP.
NPI.
USR.
USR.
USR.
PIT.
PIT.
PIT.
ACY.
USR.
ACY.
PIT.
DUP.
DUP, SDC.
PIT.
PIT.
DUP.
ACY, BFG, CTN, GYR, NPI, SAL, USR.
PAS.
ICI.
ICI.
DUP, USR, VNC.
DUP, PAS, USR, VNC.
DUP, PAS.
GYR, PAS, USR, VNC, WRC.
VNC.
ALC,
ALC,
VNC.
ALC,
VNC.
ALC,
VNC.
VNC.
VNC.
VNC.
BFG,
ALC, DUP, FMN, GYR, PAS, RBC, USR.
VNC.
RUBBER-PROCESSING CHEMICALS
153
TABLE 2. --Rubber-prooBssing chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers ' identification codes
(according to list in table 3 )
RUBBER-PROCESSING CHEMICALS, ACYCLIC--Continued
*Accelerators, activators, and vulcanizing agents--
Continued
*Thiurains :
Bis(dibutylthiocarbamoyl) sulfide
Bis (diethyl thiocarbamoyl) disulfide
*Bis (dimethyl thiocarbamoyl) disulfide
*Bis(dimethylthiocarbamoyl) sulfide
Bis (ethylmethyl thiocarbamoyl) sulfide
Thiuram blend
Xanthates and sulfides:
Di-n-butylxantho disulfide
Diisopropylxantho disulfide
Zinc dibutyl xanthate
Zinc diisopropyl xanthate
All other acyclic accelerators, activators, and vulca"-i
izing agents:
n-Butyraldehyde-butyl amine condensate
Di-n-butyl ammonium oleate
3-Ethy 1-1,1 -dimethyl- 2- thiourea
Ethylenediamine carbamate
Tetramethylthioui-ea
l,l,3-Trimethyl-2-thiourea .
Blowing agents: Modified urea
Conditioning and lubricating agents:
Methyl stearyl-10-sulfonic acid, sodium salt
Mono- and dialkyl acid phosphates, mixed
Mono- and dialkyl phosphate ammonium salts, mixed
Other
Polymerization regulators:
Alkyl mercaptans, mixed
*Dodecyl mercaptans
n-Octyl mercaptan
tert-Octyl mercaptan
Tridecyl mercaptan
Shortstops:
Dimethyldithiocarbamic acid, potassium salt
*Dimethyldithiocarbamic acid, sodium salt
Other acyclic rubber-processing chemicals: Zinc laurate
(activator, physical -property improver)
USR.
DUP, GYR, PAS.
DUP, GYR, PAS, VNC.
DUP, GYR, USR.
PAS.
DUP.
USR.
BFG.
USR.
VNC.
DUP.
DUP.
VNC.
DUP.
DUP.
VNC.
DUP.
DUP.
DUP.
DUP.
DUP.
PAS, PLC.
HK, PAS, PLC.
PAS.
PAS.
PAS.
GYR, USR.
ALC, DUP, GYR, PAS, USR.
I
154 SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 3. --Rubber-processing chemicals: Directory of manufacturers, 1970
ALPHABETICAL DIRECTORY BY CODE
[Names of rubber-processing chemical manufacturers that reported production or sales to the U.S. Tariff Commission
for 1970 are listed below in the order of their identification codes as used in table 21
Code
Code
identi-
Name of company
identi-
Name of company
fication
fication
ACS
Allied Chemical Corp., Specialty Chemicals
MLS
Miles Laboratories, Inc., Marshall Div.
Div.
MON
Monsanto Co.
ACY
American Cyanamid Co.
ALC
Alco Chemical Corp.
ASH
Ashland Oil, Inc., Ashland Chemical Co. Div.
NEV
Neville Chemical Co.
NPI
National Polychemicals, Inc.
BFG
B.F. Goodrich Co., B. F. Goodrich Chemical
Co. Div.
PAS
Pennwalt Chemicals Corp.
PIT
Pitt-Consol Chemical Co.
ceo
Reichhold Chemicals, Inc.
PLC
Phillips Petroleum Co.
CTN
Chemetron Corp., Organic Chemical Div.
RBC
Roberts Chemical Div. of Security Chemicals,
DA
Diamond Shamrock Corp.
Inc.
DUP
E. I. duPont de Nemours § Co., Inc.
RCD
Richardson Co.
EKT
Eastman Kodak Co., Tennessee Eastman
Co. Div.
SAL
Salsbury Laboratories
SDC
Martin-Marietta Corp., Southern Dyestuff
Co. Div.
FMN
FMC Corp., Niagara Chemical Div.
UPM
Universal Oil Products Co.
GNT
General Tire 5 Rubber Co., Chemical Div.
USR
Uniroyal, Inc., Chemical Div.
GYR
Goodyear Tire S Rubber Co.
HK
Hooker Chemical Corp.
VNC
Vanderbilt Chemical Corp.
ICl
ICI America, Inc.
WRC
Ventron Corp.
Note. --For complete names and addresses of the above reporting companies, refer to table 1 in the Appendix.
I
ELASTOMERS 155
Elastomers (synthetic rubbers) are high polymeric materials with
properties similar to those of natural rubber. The term "elastomer"
as used in this report, means a substance, whether in bale, crumb, powder,
latex, and other crude form, which can be vulcanized or similarly proc-
essed into a material that can be stretched to at least twice its original
length and, after having been so stretched and the stress removed, will
return with force to approximately its original length. U.S. production
and sales of elastomers in 1970 are shown in table 1.^
Total U.S. production of synthetic elastomers in 1970 was 4,438
million pounds, a decrease of 2 percent from that produced in 1969. The
sales of these elastomers amounted to 3,820 million pounds (valued at
$1,032 million) in 1970, a decrease of nearly 3 percent from 1969.
Styrene-butadiene rubber (SBR or S-type rubber) in 1970 continued
to be the synthetic elastomer produced in the greatest quantity as it
has been for more than 25 years. U.S. production of SBR, including 32
million pounds of its vinylpyridine sub-type, amounted to 2,423 million
pounds in 1970. Solution polymerized polybutadiene, a stereo type
elastomer, was produced domestically in 1970 in the next largest amount--
636 million pounds; production of polyisoprene and ethylene-propylene
rubbers, the other stereo types, amounted to 270 million and 143 mil-
lion pounds, respectively. Total U.S. production of these stereo type
elastomers amounted to 1,049 million pounds in 1970--an increase of 4
percent over 1969. Other principal types of synthetic elastomers for
which U.S. production and sales data are reported separately are polyiso-
butylene-isoprene (butyl) rubber, production of which was 265 million
pounds in 1970, and polybutadiene-acrylonitrile (N-type) rubber, pro-
duction of which was 149 million pounds.
U.S. production and sales data on synthetic organic chemicals are
reported in terms of cyclic and acyclic structured compounds for purposes
of better correlation with other statistical reporting systems. In
1970, U.S. production of cyclic elastomers amounted to 2,454 million
pounds, a decrease of 5 percent from 1969; sales of cyclic elastomers
amounted to 1,999 million pounds (valued at $485 million), a decrease
of 8 percent from 1969. U.S. production of acyclic elastomers in 1970
amounted to 1,983 million pounds, an increase of nearly 3 percent over
1969; sales of acyclic elastomers amounted to 1,821 million pounds
(valued at $547 million), an increase of 4 percent over the previous
year .
^ See also table 2 which lists these products and identifies the
manufacturers by code. These codes are given in table 3.
156 SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1: --Elastomers (synthetic rubbers):' U. S. production and sales, 1970
[Listed below are all elastomers (synthetic rubbers) for which reported data on production or sales may be published.
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data were
reported.) Table 2 lists all elastomers for which data on production or sales were reported and identifies the
manufacturers of each]
Production
Quantity
Unit
value^
1,000
pounds
Grand total
ELASTOMERS, CYCLIC
Total
Polybutadiene-styrene type (S-type)'
Polybutadiene-styrene-vinylpyridine type
Polyurethane type
ELASTOMERS, ACYCLIC
Total
Polybutadiene-acrylonitrile type (N-type) —
Polyisobutylene-isoprene type (Butyl)
Silicone elastomers
Stereo elastomers, total
Ethylene-propylene rubber
Stereo polybutadiene
Stereo polyisoprene
All other acyclic elastomers^
1,000
pounds
3.819,925
1,000
dotlccrs
Per
poicnd
2,454,462
2,390,751
32,367
31,344
1,983,114
'1,955,251
17,817
25,564
449,708
10,252
25,132
547,236
148,663
264,659
12,267
1,049,384
132,968
12,269
945,238
62,622
38,870
184,635
143,266
636,275
269,843
117,733
600,265
227,240
34,025
103,437
47,173
^ The term "elastomers" is defined as substances in bale, crumb, powder, latex, and other crude forms which can be
vulcanized or similarly processed into materials that can be stretched at 68° F. to at least twice their original
length and, after having been so stretched and the stress removed, will return with force to approximately their
original length.
2 Calculated from rounded figures.
^ Elastomer-content basis.
" Partly estimated.
5 Includes data for polyacrylate, polyalkalene sulfide, polychloroprene, polyisobutylene, all other elastomers, and
for sales of polyisobutylene-isoprene elastomers.
Note. --Statistics on the production of S-type, N-type, butyl, neoprene, and stereo elastomers were compiled in
cooperation with the U.S. Bureau of the Census.
ELASTOMERS
157
TABLE 2o — Elastomers (synthetic rubbers) for which U. S. production or sales were reported
identified by maniifacturer, 1970
[Elastomers (synthetic rubbers) for which separate statistics are given in table 1 are marked below with an asterisk
[*); products not so marked do not appear in table 1 because the reported data are accepted in confidence and may
not be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that the
manufacturer did not consent to his identification with the designated product]
Product
Manufacturers ' identification codes
(according to list in table 3)
ELASTOMERS, CYCLIC
APL, ASH, ASY, BFG, CPY, FIR, PRS, GNT, GYR, MCB,
PLC, RUB, SBI, SHC, TUS, USR, WIC .
BFG, FIR, FRS, GNT, GYR, USR.
ACY, BFG, DA, DNS, DUP, GNT, MOB, PFP, PRC, RUB, TKL,
USR, WTC.
ACY, BFG, DA, TKL.
PRC, TKL.
BFG, FRS, GYR, TKL, TUS.
BFG, CPY, FRS, GYR, SBI, USR.
DUP, PTT.
CBN, ENJ.
GYR, HPC, ICI.
DCC, SFA, SPD, UCC.
CPY, DUP, ENJ, USR.
APL, ASY, ATR, FRS, GNT, GYR, PLC, TUS.
APL, GYR, SHC.
ASY, DUP, ENJ, PLC, UCC, WAY, x.
*D°i^ " +1,^^"^+^ yrene vmy pyri me ype
ELASTOMERS, ACYCLIC
D 1^ 11,^1 If -J ^^
*P 1 h t H' 1 '1- '1 T fN 1- 1
p 1 hi T (N yp >■ yp J
*p 1^- h t^^ -^^ eoprenej
Reaction products of natural rubber
*Stereo elastomers:
*t;i-^'^^ ^ 1^ ■ ^^"®
■n, 1- 1
462-669 O - 72 .
158
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 3. — Elastomers (synthetic rubbers): Directory of mamifacturers, 1970
ALPHABETICAL DIRECTORY BY CODE
[Names of elastomers manufacturers that reported production or sales to the U.S. Tariff Commission for 1970 are
listed below in the order of their identification codes as used in table 2]
Code
Code
identi-
Name of comapny
identi-
Name of company
fication
fication
ACY
American Cyanamid Co.
ICI
I.C.I. America, Inc.
APL
Ameripol, Inc.
ASH
Ashland Chemical Co.
MCB
Borg-Wamer Corp., Marbon Chemical Div.
ASY
American Synthetic Rubber Corp.
MOB
Mobay Chemical Co.
ATR
Atlantic Richfield Co., ARCO Chemical Co.
Div.
PFP
Midwest Manufacturing Corp.
PLC
Phillips Petroleum Co.
BFG
B. F. Goodrich Co., B. F. Goodrich Chem-
PRC
Products Research S Chemical Corp.
ical Co. Div.
PTT
Petro-Tex Chemical Corp.
CBN
Cities Service Co., Petrochemical Group
RUB
Hooker Chemical Corp., Ruco Div.
CPY
Copolymer Rubber § Chemical Corp.
SBI
Standard Brands Chemical Industries, Inc.
DA
Diamond Shamrock Corp.
SFA
Stauffer Chemical Co., Specialty Chemical
DCC
Dow Coming Corp.
Div.
DNS
Dennis Chemical Co.
SHC
Shell Oil Co., Shell Chemical Co. Div.
DUP
E. I. duPont de Nemours 5 Co., Inc.
SPD
General Electric Co., Silicone Products
Dept.
ENJ
Enjay Chemical Co.
TKL
Thiokol Chemical Corp.
Firestone Tire S Rubber Co.:
TUS
Texas-U.S. Chemical Co.
FIR
Firestone Plastics Co. Div.
FRS
Firestone Synthetic Rubber S Latex
UCC
Union Carbide Corp.
Co. Div.
USR
Uniroyal, Inc., Chemical Div.
GNT
General Tire I, Rubber Co., Chemical Div.
WAY
Philip A. Hunt Chemical Coj-p., Wayland
GYR
Goodyear Tire S Rubber Co.
Chemical Div.
WIG
Wica Chemicals, Inc.
HPC
Hercules, Inc.
WTC
Witco Chemical Co., Inc.
Note. --For complete names and addresses of the above reporting companies, refer to table 1 in the Appendix.
PLASTICIZERS 159
Plasticizers are organic chemicals that are added to synthetic
plastics and resin materials to (1) improve workability during fabri-
cation, (2) extend or modify the natural properties of these materials,
or (3) develop new improved properties not present in the original
material. Table 1 presents statistics on U.S. production and sales of
plasticizers in as great detail as is possible without revealing the
operations of individual producers . ^
U.S. production of plasticizers totaled 1,336 million pounds in 1970,
a decrease of 3.3 percent from the 1,382 million pounds reported for 1969.
Sales of plasticizers totaled 1,239 million pounds, valued at $235 mil-
lion, in 1970, compared with 1,275 million pounds, valued at $266 million,
in 1969.
Production of cyclic plasticizers in 1970, which consisted chiefly
of the esters of phthalic anhydride and phosphoric acid, amounted to 998
million pounds, a decrease of 2.4 percent from the 1,023 million pounds
reported for 1969. Sales of cyclic plasticizers in 1970 totaled 938
million pounds, valued at $144 million, compared with 947 million pounds,
valued at $165 million, in 1969. The most important cyclic plasticizer
was di(2-ethylhexyl) phthalate, with production of 350 million pounds,
in 1970.
Production of acyclic plasticizers in 1970 totaled 338 million pounds,
a decrease of 5.8 percent from the 359 million pounds reported for 1969.
Sales of acyclic plasticizers totaled 302 million pounds, valued at $91
million, in 1970, compared with 328 million pounds, valued at $101 million,
in 1969. Epoxidized esters were the most important group in 1970 with
production of 95 million pounds.
^ See also table 2 which lists these products and identifies the
manufacturers by code. These codes are given in table 3.
160 SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1--Plasticizers:' U.S. production and sales, 1970
[Listed below are plasticizers for which any reported data on production or sales may be published. (Leaders are
used where the reported data are accepted in confidence and may not be published or where no data were reported.)
Table 2 lists all plasticizers for which data on production or sales were reported and identifies the manufac-
turers of each]
Quantity
Grand total
Benzenoid'
Nonbenzenoid
PLASTICIZERS, CYCLIC
Total
Phosphoric acid esters, total
Cresyl diphenyl phosphate
Tricresyl phosphate
Triphenyl phosphate
All other phosphoric acid esters
Phthalic anhydride esters, total
Butyl octyl phthalates (including butyl 2-ethylhexyl
phthalate and butyl iso-octyl phthalate)
Dibutyl phthalate
Dicyclohexyl phthalate
Diethyl phthalate
Diisodecyl phthalate
Dimethyl phthalate
Dioctyl phthalates:
Di (2-ethylhexyl) phthalate
Di iso-octyl phthalate
Di-tridecyl phthalate
n-Hexyl n-decyl phthalate
n-Octyl n-decyl phthalate
All other phthalic anhydride esters
Triraellitic acid esters, total
Triiso-octyl trimellitate
Tri-n-octyl n-decyl trimellitate
Trioctyl trimellitate
All other trimellitic acid esters
All other cyclic plasticizers"*
PLASTICIZERS, ACYCLIC
Total
Adipic acid esters, total
Di [2- (2-butoxyethoxy) ethyl] adipate
Di (2-ethylhexyl j adipate
Diisodecyl adipate
Diiso-octyl adipate
n-Hexyl n-decyl adipate
n-Octyl n-decyl adipate
All other adipic acid esters
Complex linear polyesters and polymeric plasticizers^--
Di (2-ethylhexyl) azelate
1,000
pounds
1.336.076
1,095,668
240,408
998.47.S
12,738
46,003
10,593
855,060
11,934
22,919
4,537
20,636
123,359
8,117
350,396
85,128
15,130
9,276
58,938
144,690
9.699
3,184
2,510
2,342
1,663
64,382
54,040
1,338
34,989
3,100
2,215
2,062
8,345
1,991
46,793
7,844
1,000
pounds
1,021,835
217,281
11,266
39,584
24,513
11,468
24,604
16,830
121,315
6,017
343,543
71,220
16,471
9,638
51,689
141,750
7.398
2,489
1,433
1,644
1,832
40,198
48,590
1,344
31,246
2,927
2,292
7,258
3,523
40,429
6,676
1,000
do I lavs
234.836
166,168
68,668
3,087
13,035
9,811
107.699
1,606
4,237
3,010
14,494
1,187
38,765
8,594
3,308
1,369
7,480
23,649
2.122
678
409
467
568
6,441
708
479
1,593
1,064
15,295
2,204
See footnotes at end of table.
PLASTICIZERS
161
TABLE l.--Plasticizers:' U.S. production and sales , 1970- -Continued
Production
Quantity
Unit
value^
1,000
pounds
1,000
PLASTICIZERS, ACYCLIC- -Continued
Epoxidized esters, total
Epoxidized soya oils
Octyl epoxytallates (including 2-ethylhexyl epoxytallates)-
All other epoxidized esters
90,190
Glyceryl monoricinoleate-
Isopropyl myristate
Isopropyl palmitate
69,300
23,105
2,735
419
4,825
2,017
63,924
21,934
4,332
363
4,056
1,563
Oleic acid esters, total
Butyl oleate
Methyl oleate
All other oleic acid esters-
Phosphoric acid esters
Sebacic acid esters:
Dibutyl sebacate
Di (2-ethylhexyl) sebacate-
2,932
3,001
6,313
19,955
5,184
3,821
Stearic acid esters, total
n-Butyl stearate
All other stearic acid esters-
2,062
2,395
5,894
16,748
3,927
3,412
9,345
Triethylene glycol di(caprylate-caprate) -
All other acyclic plasticizers^
5,011
4,233
2,377
73,696
5,049
4,296
2,267
63,695
1,000
dollars
13,997
5,331
1,773
145
1,922
594
600
445
1,563
7,785
2,349
1,935
1,287
1,257
760
20,955
Per
pound
Includes data for compounds used principally (but not exclusively) as primary plasticizers . Does not include
clearly defined extenders or secondary plasticizers.
^ Calculated from rounded figures.
' Includes benzenoid products as defined in part 1 of schedule 4 of the Tariff Schedules of the United States
Annotated.
'* Includes data for alkylated naphthalene, glycol dibenzoates, hydrogenated terphenyls, all other phosphate esters
(production only), toluenesulfonamides, tetrahydrofurfuryl oleate, and other cyclic plasticizers.
^ Adipic acid polyesters account for most of the production of complex linear polyesters and polymeric plastici-
zers .
^ Includes data for azelaic, citric and acetylcitric, lauric, myristic, palmitic, pelargonic, ricinoleic, and seb-
acic acid esters, glyceryl and glycol esters, and other acyclic plasticizers, not separately shown.
162
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. --Plasticizers for which U.S. production or sales were reported, identified by
manufacturer, 1970
[Plasticizers for which separate statistics are given in table 1 are marked below with an asterisk C*): products not
so marked do not appear in table 1 because the reported data are accepted in confidence and may not be published.
Manufacturers' identification codes shown below are taken from table 3. An x signifies that the manufacturer did
not consent to his identification with the designated product]
Manufacturers ' identification codes
(according to list in table 3}
PLASTICIZERS, CYCLIC
Coumarone-indene plasticizers
N-Cyclohexyl-p-toluenesulfonamide
Dibenzyl sebacate
Diethylene glycol dibenzoate
Di-tert-octylphenyl ether
Dipropanediol dibenzoate
N-Ethyl-p-toluenesulfonamide
Isopropylidenediphenoxypropanol
Naphthalene, alkylated
* Phosphoric acid esters:
*Cresyl diphenyl phosphate
Dibutyl phenyl phosphate
Diphenyl octyl phosphate
Methyl diphenyl phosphate
*Tricresyl phosphate
*Triphenyl phosphate
All other phosphoric acid esters
*Phthalic anhydride esters:
Alkyl benzyl phthalates
Bis (4-methyl-l,2-pentyl) phthalate
Butyl benzyl phthalate
Butyl cyclohexyl phthalate
*Butyl octyl phthalates:
Butyl 2-ethylhexvl phthalate
Butyl iso-octyl phthalate
Butyl n-octyl pnthaiate
Di(2-butoxyethyl) phthalate
*Dibutyl phthalate
*Dicyclohexyl phthalate
Diethyl isophthalate
*Diethyl phthalate
Dihexyl phthalate
*Diisodecyl phthalate
Diisononyl phthalate
Diiso-octyldecyl phthalate
Di(2-methoxy ethyl) phthalate
Dimethyl isophthalate
*Dimethyl phthalate
Dinonyl phthalate
Dioctyl phthalates:
Dicapryl phthalate
Di(2-ethylhexyl3 isophthalate
*Di(2-ethylhexyl) phthalate
*Diiso-octyl phthalate
Mixed dioctyl phthalates
Diphenyl phthalate
*Di-tridecyl phthalate
2- (Ethylhexyl)isodecyl phthalate
Glycol phthalate esters:
Butyl phthalyl butyl glycolate
Ethyl (and methyl) phthalyl ethyl glycolate-
Polypropylene glycol bis(amyl) phthalate
All other glycol phthalate esters
*n-Hexyl n-decyl phthalate
Hexyl isodecyl phthalate
Isodecyl tridecyl phthalate
Iso-octyl isodecyl phthalate
Iso-octyl tridecyl phthalate
*n-Octyl n-decyl phthalate
All other phthalic anhydride esters
NEV.
WTH.
DOW.
VEL.
MON.
DOW.
ACC.
FMP,
MON, MTR, SFA, SM.
MON,
ORO.
FMP,
MDN.
FMP,
MON, MTR, SFA.
EK,
MON, SFA.
SFA.
MON.
GRH.
MON.
ACP.
ACP,
GRH, TEK, UCC.
GRH.
RCI.
FMP.
ACP,
CGL, COM, DUP, EKT,
GRH,
MON,
PFZ,
RCI,
RUB,
SW
, UCC, WTC.
ACP,
DUP, FMP, MON, PFZ
PFZ.
DUP,
EKT, KF, MON, PFZ,
WTC.
ENJ.
ACP,
BFG, CPL, EKT, ENJ
GRH,
MON,
PCC,
RIC,
RUB,
TEK, UCC, WTC.
ENJ,
PFZ.
PCC.
EKT,
FMP, SFA.
PFZ.
EKT,
KF, MON, TCC, WTC.
ACP,
RCI.
WTH.
UCC.
ACP, BFG, CGL,. CPL, EKT, ENJ, GRH, MON, PCC, PFZ,
RCI, RUB, TEK, UCC, WTC.
ACP, CGL, CPL, ENJ, GRH, MON, PCC, RCI, RUB, TEK, UCC.
CPL, TEK.
MON.
ACP, CGL, CPL, ENJ, GRH, MON, PCC, RCI, RUB, TEK, UCC.
CGL, UCC.
MON.
MON.
UCC.
HPC, WTC.
ACP, GRH, TEK, UCC.
GRH.
TEK.
RUB.
RUB.
ACP, CPL, GRH, MON, PCC, RCI, RUB, TEK, UCC.
FMP, MON, PFZ.
PLASTICIZERS
163
TABLE 2,
-Plasticizers for which U.S. production or sales were reported, identified by
manufacturer, 1970--Continued
Manufacturers' identification codes
(according to list in table 33
PLASTICIZERS, CYCLIC— Continued
Polyethylene glycol dibenzoate
Tetrahydrofurfuryl oleate
Toluenesulfonamide o-, p- mixtures
*Trimellitic acid esters:
Tri-n-alkyl trimellitate
Tri(2-ethylhexyl) trimellitate
Triisodecyl trimellitate
*Triiso-octyl trimellitate
*Tri-n-octyl n-decyl trimellitate
*Trioctyl trimellitate
All other trimellitic acid esters
Trimethylpentanediol dibenzoate
Trimethylpentanediol monoisobutyrate monobenzoate
All other cyclic plasticizers
PLASTICIZERS, ACYCLIC
*Adipic acid esters:
*Di[2-C2-butoxyethoxy)ethyl] adipate
*Di(2-ethylhexyl) adipate
Di-n-hexyl adipate
Diisobutyl adipate
*Diisodecyl adipate
*Diiso-octyl adipate
Diisononyl adipate
Diisopropyl adipate ---
Di-n-octyl adipate
*n-Hexyl n-decyl adipate
Iso-octyl isodecyl adipate
*n-Octyl n-decyl adipate
All other adipic acid esters
Azelaic acid esters:
Dicyclohexyl azelate
*DiC2-ethylhexyl} azelate
Diisobutyl azelate
Diiso-octyl azelate
All other azelaic acid esters
1,4-Butanediol dicaprylate
Butoxyethyl pelargonate
Castor oil maleate
Citric and acetylcitric acid esters
*Complex linear polyesters and polymeric plasticizers
Di[ (butoxyethoxy)ethoxy]methane
Dibutyl tartrate
Diethylene glycol dipelargonate (Dinonanoate^
Diiso-octyl diglycolate
*Epoxidized esters:
Butyl epoxydioleate
Butyl epoxytallate
Epoxidized linseed oils
*Epoxidized soya oils
Epoxidized tall oils
*2-Ethylhexyl epoxytallates
Octyl epoxystearates :
*Octyl epoxytallates
All other epoxidized esters
Glyceryl tri-acetate (Triacetin)
Glyceryl tributyrate and tripropionate
Glycol pelargonate
Isodecyl nonanoate (Isodecyl pelargonate)
Laurie acid esters
Myristic acid esters: *Isopropyl myristate
*01eic acid esters:
2-Butoxyethyl oleate
*Butyl oleate
VEL.
CCW,
EMR.
ACY,
LAK,
MON.
RUB.
GRH,
PFZ,
RCI.
PFZ.
GRH,
PCC,
RCI,
RUB, TEK
GRH,
PFZ,
RUB,
TEK.
PCC,
RCI,
RUB,
TEK.
CPL,
ENJ,
X.
VEL.
EKT.
CCW,
KPI,
MON,
NEV.
FMP, RCI, TKL, WTH.
CPL, DA, EKT, GRH, HAL, MON, PCC, PFZ, RCI, RH,
TEK, UCC.
ARC.
FMP, GRH, HAL.
ACP, GRH, MON, PCC, PFZ, RCI, RH, RUB, TEK, UCC.
BFG, GRH, PCC, RH, RUB.
ENJ.
SBC, VND.
ACP, ENJ.
GRH, PCC, TEK.
GRH, PFZ.
ACP, GRH, MON, PCC, RCI, RH, RUB, TKL.
RUB, UCC.
PFZ.
EKT,
HAL.
EMR.
EMR.
RUB.
HAL.
RH.
ICI,
ASH,
TKL.
ARC.
EMR.
CCA.
ASH.
ASH.
ASH,
ASH,
RH.
ASH,
WTC.
RH,
EMR.
PFZ.
EKT.
EMR.
EMR.
HAL,
ARC,
EMR, PFZ, RCI, RUB, UCC.
EKT, EMR, HAL, MON, PFZ, RCI, RH, RUB, TEK, WTH-
TEK.
SWT.
CPL, FMP, NTL, RH, SWT, TEK, UCC, WTC.
NTL, SWT.
TEK, UCC, WTC.
SBC.
DRW, PCS, SEC.
ARC, HAL.
ARC, DA, HAL, ICI, SWT, WM, WTC, WTH.
164
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.
- Plasticizers for which U.S. production or sales were reported, identified by
manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
PLASTICIZERS, ACYCLIC- -Continued
*01eic acid esters--Continued
Decyl oleate
Glyceryl trioleate (Triolein)
Isobutyl oleate
Isopropyl oleate
*Methyl oleate
Propyl oleate
All other oleic acid esters
Palmitic acid esters;
Isobutyl palmitate
Iso-octyl palmitate
* Isopropyl palmitate
"Phosphoric acid esters;
Tri(2-butoxyethyl) phosphate
Tributyl phosphate
Tri(2-chloroothyl) phosphate
Tri ethyl phosphate
Trioctyl phosphate
All other phosphoric acid esters
Ricinoleic and acetylricinoleic acid esters;
n- Butyl acetylricinoleate
Butyl ricinoleate
*Glyceryl monoricinoleate
Glyceryl tri (acetylricinoleate)
Methyl ricinoleate
All other ricinoleic and acetylricinoleic acid esters
Sebacic acid esters;
Dibutoxyethyl sebacate
*Dibutyl sebacate
*Di(2-ethylhexyl) sebacate
Diiso-octyl sebacate
"Stearic acid esters;
Butoxyothyl stearate
*n- Butyl stearate
Dimethyl ammonium stearate
Dodecyl (lauryl) stearate
2-Ethylhexyl stearate
Glyceryl triacetyl stearate
Isobutyl stearate
Isocetyl stearate
Isopropyl stearate
Methyl dichlorostearate
Methyl pentachlorostearate
Methyl stearate
All other stearic acid esters
Sucrose acetate isobutyrate
Tetraethylene glycol di (2-ethyIhexanoate)
Triethylene glycol dicaprylate
*Triethylene glycol di (caprylate-caprate)
Triethylene glycol di-2-ethylbutyrate
Triethylene glycol di (2-ethylhexanoate)
Triethylene glycol dipelargonate
2,2,4-Trimethyl-l,3-pentanediol di isobutyrate
All other acyclic plasticizers
VND.
DRW,
EMR
SWT
WM.
DA.
EMR,
Wi.
CIIL,
DA,
EMR,
HUM, ICI, SWT
CHL,
EMR
WM.
RH.
DA.
RUB.
ARC,
DRW
PCS
SBC.
FMP
SM.
FMP.
SFA,
UCC
EKT.
UCC.
SCP,
SM.
NTL.
NTL,
RCI
DA,
GLY,
1-IAL,
NTL.
NTL.
NTL.
NTL.
UAL, RCI.
EKT, GRH, HAL, PFZ, RCI, RH, WTH.
GRH, HAL, PFZ, RCI, RH, WTH.
DA, RCI.
ARC, WM.
AAE, ARC, CHL, DA, DRW, EMR, GRO, ICI, PCS, RUB, SCP,
SWT, WTC, WTH.
RH.
RCI.
FMP.
NTL.
ARC, DA.
WM.
ARC, WM.
HK.
HK.
CHL, SWT.
DA, HAL, WM, x.
ARC, EKT.
UCC.
RUB.
ASH, DRW, HAL, RUB, WM.
UCC.
UCC.
RUB.
EKX.
ARC, EMR, HAL, HPC, RUB, SCP, TKL, WM.
PLASTICIZERS
TABLE 3.--Plasticizers: Directory of manufacturers, 1970
165
ALPHABETICAL DIRECTORY BY CODE
[Names of plasticizers manufacturers that reported production or sales to the U.S. Tariff Commission for 1970 are
listed below in the order of their identification codes as used in table 2]
Code
Code
identi-
Name of company
identi-
Name of company
fication
fication
AAE
American Aniline § Extract Co., Inc.
KPI
Kenrich Petrochemicals, Inc.
ACC
Amoco Chemicals Corp.
ACP
Allied Chemical Corp., Plastics Div.
LAK
Lakeway Chemicals, Inc.
ACY
American Cyanamid Co.
ARC
Armour f, Co., Armour Industrial Chemical
MON
Monsanto Co.
Co. Div.
MTR
Chris-Craft Industries, Inc., Montrose
ASH
Ashland Oil, Inc., Ashland Chemical Co. Div.
Chemical Div.
BFG
B. F. Goodrich Co., B. F. Goodrich Chemical
NEV
Neville Chemical Co.
Co. Div.
NTL
National Lead Co.
CCA §
Cincinnati Melacron Chemicals, Inc.
ORO
Chevron Chemical Co.
CCW
CGL
Cargill, Inc.
PCC
USS Chemicals Div. of U.S. Steel Corp.
CHL
Chemol, Inc.
PCS
Emery Industries, Inc.
COM
Commercial Solvents Corp.
PFZ
Pfizer, Inc.
CPL
Conoco Plastics
CTN
Chemetron Corp., Organic Chemical Div.
RCI
Reichhold Chemicals, Inc.
RH
Rohm S Haas Co.
DA
Diamond Shamrock Corp.
RUB
Hooker Chemical Corp., Ruco Div.
DOW
Dow Chemical Co.
DRW
Drew Chemical Corp.
SBC
Scher Brothers, Inc.
DUP
E. I. duPont de Nemours 6 Co., Inc.
SCP
Standard Chemical Products, Inc.
SFA
Stauffer Chemical Co., Specialty Chemical
EK
Eastman Kodak Co. :
Div.
EKT
Tennessee Eastman Co. Div.
SM
Mobil Chemicalr Co.
EKX
Texas Eastman Co. Div.
SM
Mobil Oil Corp., Mobil Chemical Co. Div.,
EMR
Emery Industries, Inc.
Industrial Chemical Div.
ENJ
En jay Chemical Co.
SW
Sherwin-Williams Co.
SWT
Swift 5 Co., Swift Chemical Co. Div.
FMP
FMC Corp., Organic Chemicals Div.
FOR
El Dorado Chemical Co.
TCC
Tanatex Chemical Corp.
GLY
Glyco Chemicals, Inc.
TEK
Teknor Apex Co.
GRH
W.R. Grace 5 Co., Hatco Chemical Div.
TKL
Thiokol Chemical Corp.
GRO
Millmaster Onyx Corp., A. Gross 5 Co. Div.
UCC
Union Carbide Corp.
HAL
C. P. Hall Co. of Illinois
HK
Hooker Chemical Corp.
VEL
Velsicol Chemical Corp.
HPC
Hercules, Inc.
VND
Van Dyk 6 Co., Inc.
HUM
Kraftco Corp., Humko Plastics Div.
WM
Wilson Pharmaceutical § Chemical Corp.
ICI
ICI America, Inc.
Wilson-Martin Div.
WTC
Witco Chemical Co., Inc.
KF
Kay-Fries Chemicals, Inc.
WTH
Union Camp Corp., Harchem Div.
Note. --For complete names and addresses of the above reporting companies, refer to table 1 in the Appendix.
SURFACE -ACTIVE AGENTS 167
The surface-active agents included in this report are organic chemi-
cals that reduce the surface tension of water or other solvents and are
used chiefly as detergents, dispersing agents, emulsifiers, foaming agents,
or wetting agents in either aqueous or nonaqueous systems . Waxes and
products used chiefly as plasticizers are excluded. Surface-active
agents are produced from natural fats and oils; from si Ivi chemicals such
as lignin, rosin, and tall oil; and from chemical intermediates derived
from coal tar and petroleum. A major part of the output of the bulk
chemicals shown in this report is consiomed in the form of packaged soaps
and detergents for household and industrial use. The remainder is used
in the processing of textiles and leather, in ore flotation and oil-dril-
ling operations, and in the manufacture of agricultural sprays, cosmetics,
elastomers, foods, lubricants, paints, pharmaceuticals, and many other
products .
Table 1 shows statistics for production and sales of surface-active
agents grouped by ionic class and by chemical class and subclass; table
2 lists these products and identifies the manufacturers.'^ All quantities
are reported in terms of 100-percent organic surface-active ingredient
and thus exclude all inorganic salts, water, and other diluents. Sales
statistics reflect sales of bulk surface-active agents only; sales of
formulated products are excluded.
Total U.S. production of surface-active agents in 1970 amounted to
3,886 million pounds, or 0.4 percent less than the 3,901 million pounds
reported for 1969. Sales of bulk surface-active agents in 1970 amounted
to 2,061 million pounds, valued at $387 million, compared with sales in
1969 of 1,988 million pounds, valued at $370 million. In terms of
quantity, sales in 1970 were thus 3.7 percent larger than in 1969; in
terms of value, sales in 1970 were 4.7 percent larger than in 1969.
Production of anionic surface-active agents in 1970 amounted to
2,728 million pounds, or 70.2 percent of the total output reported for
1970 and 0.9 percent less than the anionic output reported for 1969.
Sales of anionics in 1970 amounted to 1,163 million pounds, valued at
$169 million. Of the total anionic output, 924 million pounds consisted
of potassium and sodium salts of fatty, rosin, and tall oil acids, of
which 505 million pounds was the sodium salt of tallow acids and 121
million pounds was the sodium salt of coconut oil acids; 715 million
pounds consisted of alkylbenzenesulfonates, of which 401 million pounds
was sodium dodecylbenzenesulfonate, 139 million poimds was dodecylben-
zenesulfonic acid, and 138 million pounds was sodium tridecylbenzene-
sulfonate; 491 million pounds consisted of ligninsulfonates, of which 306
million pounds was the calcium salt; and 179 million pounds consisted of
sulfated ethers.
Production of nonionic surface-active agents in 1970 amounted to
922 million pounds, or 23.7 percent of the total output reported for 1970
^ See table 3 for a list of manufacturers and their codes.
168 SYNTHETIC ORGANIC CHEMICALS, 1970
and 5.0 percent less than the nonionic output reported for 1969. Sales
of nonionics in 1970 amounted to 736 million pounds, valued at $148 mil-
lion. Of the total nonionic output, 249 million pounds consisted of
alkylphenol ethoxylates and other benzenoid ethers, of which 142 million
pounds was nonylphenol ethoxylate; 379 million pounds consisted of alcohol
ethoxylates and other nonbenzenoid ethers, of which 296 million pounds was
mixed linear alcohol ethoxylate; 111 million pounds consisted of glycerol
esters; and 90 million pounds consisted of alkanolamides .
Production of cationic surface-active agents in 1970 amounted to 228
million pounds, or 5.9 percent of the total output reported for 1970 and
35.3 percent more than the cationic output reported for 1969. Sales of
cationics in 1970 amounted to 155 million pounds, valued at $64 million.
Of the total cationic output, 51 million pounds consisted of quaternary
ammonium salts not containing oxygen, and 51 million pounds consisted of
primary monoamines not containing oxygen.
Production of amphoteric surface-active agents in 1970 amounted to
7.6 million pounds, or 0.2 percent of the total output reported for 1970
and 10.1 percent less than the amphoteric output reported for 1969. Sales
of amphoterics in 1970 amounted to 7.5 million pounds, valued at $5.4
million.
The difference between production and sales reflects inventory changes
and captive consumption of soaps and surface-active agents by synthetic
rubber producers, and by manufacturers of cosmetics, packaged detergents,
bar soaps, and other formulated consiomer products. In some instances the
difference may also reflect quantities of surface-active agents used as
chemical intermediates, e.g., nonionic alcohol and alkylphenol ethoxylates
which may be converted to anionic surface-active agents by phosphation or
sulfation.
SURFACE -ACTIVE AGENTS
TABLE 1. --Surface-active agents: U.S. production and sales, 1970
[Listed below are all surface-active agents for which reported data on production or sales may be published.
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data
were reported. J Table 2 lists all surface^active agents for which data on production or sales were reported and
identifies the manufacturer of each]
Quantity'
I
Grand total
Benzenoid"*
Nonbenzenoid^
Amphoteric Surface-Active Agents
Total
Anionic Surface-Active Agents
Total
Carboxylic acids (and salts thereof), total
Amine salts of fatty rosin, and tall oil acids
Carboxylic acids having amide, ester, or ether linkages,
total
N-Lauroylsarcosine, sodium salt
All other
Potassium and sodium salts of fatty, rosin, and tall oil
acids, total
Castor oil acids, potassium salt
Coconut oil acids, potassium and sodium salts, total
Potassium salt
Sodium salt
Corn oil acids, potassium and sodium salts
Mixed vegetable fatty acids, potassium salt
Oleic acid, potassium salt
Oleic acid, sodium salt
Soybean oil acids, potassium and sodium salts
Stearic acid, potassium salt
Tall oil acids, potassium and sodium salts, total
Potassium salt
Sodium salt
Tallow acids, sodium salt
All other
Phosphoric and polyphosphoric acid esters (and salts thereof) ,
total
Alcohols and phenols, ethoxylated and phosphated, total
Dinonylphenol, ethoxylated and phosphated
Mixed linear alcohols, ethoxylated and phosphated
Nonylphenol, ethoxylated and phosphated
Tridecyl alcohol, ethoxylated and phosphated
All other
Alcohols, phosphated or polyphosphated, total
2-Ethylhexyl phosphate, sodium salt
All other
Sulfonic acids (and salts thereof), total
Alkylbenzenesulfonates, total
See footnotes at end of table.
1,000
pounds
5,886,186
1,000
1,081,178
2,805,008
937,520
12,494
5,291
7,203
924,100
27,189
20,213
953
1,343
11,075
1,185
5,657
6,976
143
6,833
1,331,043
1,000
dollars
387.201
492,607
1,568,850
90,666
296,535
169.204
8,492
1,597
6.895
5,721
1,114
4,607
132,945
3,548
1.279
11,944
121.001
771
754
304
3,212
3,993
742
196
1,281
558
138
306
398
33,316
19.852
4.074
21,167
12.149
504,955
242.877
16,003
3,089
10,544
896
1,045
3,486
5,117
5,459
141
5,318
700,502
4,726
353
334
1,246
2,793
3,363
66
3,297
69,513
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. — Surface-active agents: U.S. production and sales, 1970 — Continued
Production'
Quantity
Anionic Surface-Active /43ents--Continued
Sulfonic acids C^nd salts thereof) --Continued
Alky Ibenzenesulfonates- -Continued
Dodecylbenzenesulfonates, total
Dodecylbenzenesulfonic acid
Dodecylbenzenesulfonic acid, calcium salt
Dodecylbenzenesulfonic acid, isopropanolamine salt
Dodecylbenzenesulfonic acid, isopropylamine salt
Dodecylbenzenesulfonic acid, potassium salt
Dodecylbenzenesulfonic acid, sodium salt
Dodecylbenzenesulfonic acid, triethanolamine salt
All other
Other alky Ibenzenesulfonates, total
Tridecylbenzenesulfonic acid, sodium salt
All other
Benzene-, cumene-, toluene-, and xylenesulfonates, total
Cumenesulfonic acid, ammonium salt
Xylenesulfonic acid, ammonium salt
Xylenesulfonic acid, sodium salt
All other
Ligninsulfonates, total
Ligninsulfonic acid, calcium salt
Ligninsulfonic acid, chromium salt
Ligninsulfonic acid, sodium salt
All other
Naphthalenesulfonates, total
Butyl -and dibutylnaphthalenesulfonic acid and sodium salt-
All other
Sulfonic acids having amide linkages, total
Sulfosuccinic acid derivatives
Taurine derivatives, total
N-Methyl-N-oleoyltaurine, sodium salt
All other
Sulfonic acids having ester or ether linkages, total
Sulfosuccinic acid esters, total
Sulfosuccinic acid, bis(2-ethylhexyl) ester, sodium
salt
All other
Other sulfonic acids having ester or ether linkages
All other sulfonic acids
Sulfuric acid esters (and salts thereof), total
Acids, amides, and esters, sulfated, total
Coconut oil acids - ethanolamine condensate, sulfated,
potassium salt
Esters of sulfated oleic acid, total
Butyl oleate, sulfated, sodium salt
Glycerol trioleate, sulfated, sodium salt'
Isopropyl oleate, sulfated, sodium salt
Propyl oleate, sulfated, sodium salt
All other
Oleic acid, sulfated, disodium salt
Tall oil, sulfated, sodium salt
All other
1,000
pounds
561,436
138,828
9,785
60S
3,134
49
400,559
4,034
4,439
154,008
138,241
15,767
64,528
4,737
4,479
38,829
16,483
491,327
306,197
9,341
73,872
101,917
8,246
1,732
6,514
5,734
1,849
3,885
41,549
12,469
9,095
3,374
29,080
4,215
36
5,261
1,868
165
421
449
2,358
6,456
2,728
1,000
pounds
163,362
45,376
6,178
3,471
100,484
3,877
3,976
21,585
9,143
12,442
52,268
4,844
4,538
26,957
15,929
424,315
300,585
9,343
42,431
71,956
6,972
1,526
5,446
3,782
1,493
2,289
2,083
206
23,968
11,752
8,500
3,252
12,216
4,250
189,043
15,146
36
4,868
1,641
413
447
2,367
6,499
2,662
1,000
dollarit
23,668
5,881
2,259
12,778
822
899
2,908
1,108
1,800
4,786
527
369
2,303
1,587
15,996
7,852
834
3,757
3,553
2,675
548
2,127
2,550
1,103
1,447
1,144
303
15,374
6.384
4,757
1,627
8,990
1,556
43,118
1,414
433
116
86
779
1,453
320
470
See footnotes at end of table.
SURFACE -ACTIVE AGENTS
TABLE 1. — Surface-active agents: U.S. production and sales, 1970 — Continued
171
■ Production
Quantity'
Anionic Surface-Active 43ents--Continued
Sulfuric acid esters (and salts thereof^ --Continued
Alcohols, sulfated, total
Coconut and sperm oil alkyl sulfate, sodium salt
Dodecyl sulfate salts, total
Dodecyl sulfate, ammonium salt
Dodecyl sulfate, diethanolamine salt
Dodecyl sulfate, magnesium salt
Dodecyl sulfate, sodium salt
Dodecyl sulfate, triethanol amine salt
All other
Mixed linear alcohol sulfate, ammonium salt
Mixed linear alcohol sulfate, sodium salt
All other
Ethers, sulfated, total
Alkylphenols, ethoxylated and sulfated
Dodecyl alcohol, ethoxylated and sulfated, ammonium salt
Dodecyl alcohol, ethoxylated and sulfated, sodium salt
Mixed linear alcohols, ethoxylated and sulfated, sodium
salt
All other
Natural fats and oils, sulfated, total
Castor oil, sulfated, sodium salt
Coconut oil, sulfated, sodium salt
Cod oil, sulfated, sodium salt
Mixed fish oils, sulfated, sodium salt
Neat's-foot oil, sulfated, sodium salt
Soybean oil, sulfated, sodium salt
Sperm oil, sulfated, sodium salt
Tallow, sulfated, sodium salt
All other
Other anionic surface-active agents^
Cationio Surface-Active Agents
Total
Amine oxides and oxygen-containing amines (except those having
amine linkages), total
Acyclic, total
(Coconut oil alkyljamine, ethoxylated
(Tallow alkyl)amine, ethoxylated
All other
Cyclic (except imidazoline and oxazoline derivatives)
Imidazoline and oxazoline derivatives, total
2- (8-Heptadecenyl) - 1- (2-hydroxyethyl) -2-imidazoline
l-(2-Hydroxyethyl)-2-nor(tall oil alkyl)-2-imidazoline
All other
Amines and amine oxides having amide linkages, total
Carboxylic acid - diamine and polyamine condensates; total
Stearic acid - diethylenetriamine condensate
All other
Oleic acid - ethylenediamine condensate, monoethoxylated
Stearic acid - ethylenediamine condensate, monoethoxylated
Other amines and amine oxides having amide linkage
1,000
pounds
505
57,584
2,588
365
20,337
16,844
17,450
228,489
50,458
43,405
4,694
2,186
36,525
3,232
3,801
328
3,473
15,041
8,369
333
8,036
3,565
2,090
1,017
1,000
pounds
40,346
502
32,400
2,425
2,272
17,875
2,636
2,411
4,945
179,290
92,806
3,421
3,378
1,038
572
5,028
4,926
9,970
12,064
159,833
71,866
42,447
40,745
8,443
8,054
1,216
1,119
1,341
1,366
4,575
4,034
2,202
1,833
90
90
7,264
7,207
10,077
9,989
7,239
7,053
134,900
223,261
155,093
2,937
1,292
2,844
328
491
2,025
14,115
1,914
4,006
1,000
dollars
16,192
252
13,093
1,187
1,404
6,642
3,860
66
782
1,999
15,010
1,144
303
1,468
2,052
10,043
8,232
2,270
301
175
720
336
41
1,384
1,372
1,633
64,424
1,049
911
1,306
138
165
1,003
5,925
2,815
2,815
1,145
1,963
See footnotes at end of table.
172
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. — Surface-active agents: U.S. production and sales, 1970-- Continued
Production
Quantity
Cationia Surfaas-Active Agents — Continued
Amines, not containing oxygen (and salts thereof), total
.Amine salts
Diamines and polyamines, total
X- (Coconut oil alkyl^trimethylenediajnine
Imidazoline derivatives
N- (9-Octadecenyl) trimethylenedi amine
\- (Tal low alkyl) trimethylenediamine
All other
Primary monoamines, total
(Hydrogenated tallow alkyl)amine
9-Octadecenylamine
Octadecylaraine
(Tallow alkyl} amine
All other
Secondary and tertiary monoamines, total
N,N-Dimethyloctadecylamine
N-Methy Ibis (coconut oil alkyl)amine
N'-Methy Ibis (hydrogenated tallow alkyl)amine
All other
Oxygen-containing quaternary ammonium salts
Quaternary ammonium salts, not containing oxygen, total
Acyclic, total
Bis (coconut oil alkyl)diraethylammonium chloride
• Bis (hydrogenated tallow alkyljdimethylammonium chioride-r
Hexadecyltrimethylammonium salts
Trimethyl (tallow alkyl) ammonium chloride
.All other
Benzenoid, total
Benzyl (coconut oil alkyljdimethylammonium chloride
Eenzyldimethyl (mixed alkyl) ammonium chloride
Benzyldimethyloctadecylammonium chloride
Benzyltriraethylammonium chloride
All other
Groups listed above for which separate sales data may not be
shown
lanionia Surfase-Astivs Agents
Total
Carboxylic acid amides, total
Diethanolamine condensates (araine/acid ratio=2/lj, total
Capric acid
Coconut oil acids
Laurie acid
Oleic acid
Stearic acid
Tall oil acids
All other
1,000
pounds
91,868
5,658
18,516
904
2,467
1,688
6,859
6,598
50,856
5,123
47,733
18,838
1,112
865
16,861
51,415
58,753
5,004
24.486
610
1,397
7,238
12,680
436
5,510
1,446
5,288
89,984
38,158
83
18,406
3,252
962
736
424
14,295
1,000
pounds
54,698
2,416
15,387
725
976
1,223
4,668
5,795
24,026
3,207
1,198
606
7,434
11,581
14,869
796
736
3,532
9,805
44,480
35,045
2,782
22,762
476
957
6.066
11,437
424
5,502
96
5,415
58,274
26,288
118
18,071
581
522
159
6,837
1,000
dollars
19,888
895
4.009
367
331
541
1.329
1.441
8.208
806
473
271
2.068
4.590
6.776
423
299
1.010
5,044
20,861
12,471
1,244
6,242
480
442
4,063
8,390
343
4,124
41
17,327
7,322
49
5,144
177
220
47
1,685
See footnotes at end of table.
SURFACE -ACTIVE AGENTS
TABLE 1. — Surface-active agents: U.S. production and sales , 1970--Continued
173
Production"
Sales^
Quantity'
Nonionis Surfase-Active Agents — Continued
Carboxylic acid amides — Continued
Diethanolamine condensates (other amine/acid ratios) , total-
Coconut oil acids (amine/acid ratio=l/l)
Laurie acid (amine/acid ratio=l/l)
Oleic acid (amine/acid ratio=l/l)
Stearic acid (amine/acid ratio=l/l)
All other
Ethanolamine condensates, total
Coconut oil acids (amine/acid ratio=2/l)
All other
Laurie acid - isopropanol amine condensate
Other carboxylic acid amides
Carboxylic acid esters, total
Anhydrosorbitol esters, total
Anhydrosorbitol mono-oleate
Anhydrosorbitol monopalmitate
Anhydrosorbitol monostearate
Anhydrosorbitol tristearate
All other
Diethylene glycol esters, total
Diethylene glycol monolaurate
Diethylene glycol monostearate
All other
Ethoxylated anhydrosorbitol esters, total
Ethoxylated anhydrosorbitol monolaurate
Ethoxylated anhydrosorbitol mono-oleate
Ethoxylated anhydrosorbitol monostearate
Ethoxylated anhydrosorbitol tristearate
All other
Ethylene glycol esters
Glycerol esters, total
Complex glycerol esters
Glycerol esters of chemically defined acids, total
Glycerol distearate
Glycerol monolaurate
Glycerol mono-oleate
Glycerol monostearate
All other
Glycerol esters of mixed acids, total
Glycerol monoester of hydrogenated cottonseed oil acids-
Glycerol monoester of hydrogenated soybean oil acids
All other
Natural fats and oils, ethoxylated, total
Castor oil, ethoxylated
Lanolin, ethoxylated
All other
Polyethylene glycol esters, total
Polyethylene glycol esters of chemically defined acids,
total
Polyethylene glycol dilaurate
Polyethylene glycol dioleate =
Polyethylene glycol monolaurate
Polyethylene glycol mono-oleate
Polyethylene glycol monostearate
All other
pounds
31,087
16,608
10,650
384
577
2,868
15,832
1,164
14,668
37
4,870
205,570
18,523
6,950
972
4,988
5,615
1,948
94
491
1,363
20,466
4,390
8,306
5,165
980
1,627
3,575
111,080
3,705
35,561
647
2,955
28,486
3,473
71,814
4,210
17,012
50,592
5,192
3,981
520
691
27,145
19,398
1,331
3,860
2,520
2,878
6,091
2,718
1,000
pounds
25,083
15.798
337
659
8,289
5,243
5,243
45
1,615
155,973
15,525
4,648
114
8,763
1,722
79
440
1,203
18,617
4,262
7,011
4.746
2,598
3,366
83,129
3,239
14,017
594
62
1.863
8.462
3.036
65,873
15,392
50,481
4,534
3,639
253
642
18,492
13,261
1,059
725
2,151
2,578
4,665
2.085
1,000
dollars
7,S02
4.449
121
111
2,955
1,577
"i,577
35
591
4,771
1.663
37
3.071
621
26
138
457
7,479
1,647
2.840
2.001
991
990
23,559
1,325
4.511
295
27
662
2.450
1.077
17.723
3.786
15.937
1.442
1.070
152
220
6.227
4.810
358
243
723
919
1.801
766
See footnotes at end of table.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. — Surface-active agents: U.S. production and sales, 1970- -Continued
Production'
, Quantity'
Unit
Value^
Nonionio Surface-Active /ljents--Continued
Carboxylic acid esters--Continued
Polyethylene glycol esters--Continued
Polyethylene glycol esters of rosin and tall oil
acids J total
Polyethylene glycol monoester of tall oil acids
Polyethylene glycol sesquiester of tall oil acids
All other
Polyethylene glycol esters of other mixed acids, total-
Polyethylene glycol sesquiester of coconut oil acids-
All other
Polyglycerol esters
Propanediol esters, total
1,2-Propanediol monostearate
All other .
Other carboxylic acid esters' ^
Ethers, total
Benzenoid ethers, total
Dodecylphenol , ethoxylated
Nonylphenol, ethoxylated
Phenol, ethoxylated
All other
Nonbenzenoid ethers, total
Linear alcohols, alkoxylated, total
Decyl alcohol, ethoxylated
Dodecyl alcohol, ethoxylated
Hexadecyl alcohol, ethoxylated
Mixed linear alcohols, ethoxylated —
9-Octadecenyl alcohol, ethoxylated
Octadecyl alcohol, ethoxylated
All other
Other ethers and thioethers, total
Mixed alcohols, ethoxylated
Poly (ethylene and propylene) glycols-
Tridecyl alcohol, ethoxylated
All other
Other nonionic surface-active agents-
1,000
pounds
5,330
1,857
3,038
435
2,417
171
2,246
2,075
4,969
3,788
1,181
8,597
627,422
248,804
17,038
141,587
7,691
82,488
378,618
328,293
1,118
11,701
711
295,825
3,441
803
14,694
50,325
507
5,624
5,525
38,669
1,499
1,000
pounds
3,614
2,381
1,233
1,617
167
1,450
2,000
1,916
1,663
253
6,672
215,836
8,203
125,392
82,241
306,718
269,261
625
239,867
2,001
315
26,453
37,457
4,876
4,334
28,247
911
1,000
do I lars
558
293
566
87
479
776
595
510
),736
36,222
1,277
18,497
16,448
44,514
34,692
347
28,245
981
261
4,858
9,822
1,106
987
7,729
Per
pound
'All quantities are given in terms of 100 percent organic surface-active ingredient.
2 Sales include products sold as bulk surface-active agents only.
^ Calculated from rounded figures.
'' The term "benzenoid," as used in this report, describes any surface-active agent, except lignin derivatives,
whose molecular structure includes 1 or more 6-membered carbocyclic or heterocyclic rings with conjugated double
bonds (e.g., the benzene ring or the pyridine ring).
^ Includes ligninsulfonates.
^ Includes production of "all other" sulfated acids, amides, and esters and of "all other" sulfated alcohols; also
includes sales of "all other" potassium and sodium salts of fatty, rosin, and tall oil acids.
' Includes ethoxylated sorbitol esters and miscellaneous esters.
SURFACE -ACTIVE AGENTS
175
TABLE 2. — Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970
[Surface-active agents for which separate statistics are given in table 1 are marked below with an asterisk (*);
products not so marked do not appear in table 1 because the reported data are accepted in confidence and may
not be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that
the manufacturer did not consent to his identification with the designated product]
Manufacturers ' identification codes
(according to list in table 3)
Amphoteric Surface-Active Agents
Acyclic:
Alkylbetaine
(l-Carboxyheptadecyl)trimethylammonium hydroxide,
inner salt.
N- [2- (Carboxymethylamino) ethyl] -N-(2-hydroxyethyl)-
coconut oil amide, sodium salt.
(Carboxymethyl) [3- (coconut oil amido)propyl] dimethyl-
ammonium chloride, sodium salt.
(.Carboxymethyl) [3- (coconut oil amidojpropyl]di-
methylammonium hydroxide, inner salt.
(Carboxyme thy l)dodecyl dimethyl ammonium hydroxide,
inner salt.
(l-Carboxyundecyl5trimethylammonium hydroxide, inner
salt.
N- (Coconut oil alkyd)-g-alanine, sodium salt
N- (Coconut oil alkyl)-6-alanine, partial sodium
salt.
3- [ (Coconut oil alkyl)amino]butyric acid, sodium
salt.
N-(2-Coconut oil amidoethyl)-N-(2-hydroxyethyl)-
glycine, sodium salt.
N-(Dodecyl and tetradecyl)-B-alanine
N- (Dodecyl and tetradecyl)-6-alanine, triethanol-
amine.salt.
N-Dodecyl-3-iminodipropionic acid.
N-Dodecyl-3-iminodipropionic acid, disodium salt
N- (2-Hydroxyethyl3 -N- (2-laurainidoethyl) -6-alanine,
sodium salt.
N- (2-Hydroxyethyl)-N-(2-stearamidoethyl)glycine, sodium
salt.
Mixed acyclic primary amines, ethoxylated and
sulfated, sodium salt.
(Mixed alkyl)sulfobetaine
Mixed fatty betaines
Oleic acid - ethylenediamine condensate, propoxylated
and sulfated, sodium salt.
N- (Tallow alkyl)-3-iminodipropionic acid, disodium
salt.
All other acyclic
Cyclic:
l,l-Bis(carboxymethyl)-2-undecyl-2-imidazolinium
chloride, disodium salt.
1 , 1-Bis (carboxymethyl) -2-undecyl-2-imidazolinium
hydroxide, disodium salt.
1- [2- (2-Carboxyethoxy)ethyl] -1- (2-hydroxy-3-sulfo-;
propyl) -2- (mixed alkyl)-2-imidazolinium hydroxide,
disodium salt.
l-Carboxymethyl-2-heptadecyl-l- (2-hydroxyethyl)-2-
imidazolinium hydroxide, sodium derivative, sodium
salt.
l-Carboxymethyl-l-(2-hydroxyethyl)-2-nonyl-2-imid-
azolinium chloride, sodium salt.
1-Carboxymethyl-l- (2-hydroxyethyl)-2-nonyl-2-imid-
azolinium hydroxide, sodium derivative, sodium
salt.
DUP.
DUP.
UVC.
JRG.
UVC.
TCC.
DUP.
GNM.
GNM
ARC.
TCC.
GNM
GNM.
GNM.
GNM, UVC.
UVC, VAC.
DUP,
TXT
TXT.
S.
GNM.
VAC.
UVC.
MIR,
UVC
UVC.
MIR,
UVC
UVC.
MIR,
UVC
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.-
-Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
Amphoteric Surface-Active /l^ents--Continued
Cyclic- -Continued
1-Carboxymethyl-l- (2-hydroxyethyl)-2-undecyl-2-
imidazolinium hydroxide, sodium derivative,
sodium salt.
Heptadecylmethylbenzimidazolinesulfonic acid,
sodium salt.
3- [2- (2-Undecyl-2-imidazolin-l-yl)ethoxy] -
propionic acid, sodium salt.
All other cyclic
Anionic Surface- Active Agents
*Carboxylic acids (and salts thereof):
*Amine salts of fatty, rosin, and tall oil acids:
Coconut oil acids, diethanolamine salt
Coconut oil acids, ethanolamine salt
Oleic acid, n-butylamine salt
Oleic acid, triethanolamine salt
Stearic acid, N,N,N' ,N' -tetrakis(2-hydroxyethyl)-
ethylenediamine salt.
Stearic acid, triethanolamine salt
Tallow acids, ethanolamine salt
Tallow acids, triethanolamine salt
*Carboxylic acids having amxde, ester, or ether
linkages:
Butoxyethoxypropionic acid
N- (Coconut oil acyl)sarcosine, sodium salt
Diisobutylene - maleic anhydride copolymer,
ammonium and sodium salts.
*N-Lauroylsarcosine, sodium salt
N- (Mixed alkylsulfonyljglycine, sodium salt
N-Oleoylpolypeptide, sodium salt
N-Oleoylsarcosine, sodium salt
Phthalic acid, octadecyl ester, potassium salt —
Stearoyl-2-lactylic acid
Stearoyl-2-lactylic acid, calcium salt
Tridecyloxypoly(ethyleneoxy5acetic acid, sodium
salt.
Unspecified sarcosine derivatives
All other
*Potassium and sodium salts of fatty, rosin, and
tall oil acids:
*Castor oil acid, potassium salt
Castor oil acid, sodium salt
*Coconut oil acids, potassium and sodium salts:
•Potassium salt
*Sodium salt
Coconut oil and tallow acids, sodium salt
*Corn oil acids, potassium and sodium salts:
Potassium salt
Sodium salt
MIR, PCS, UVC.
CGY.
UVC
SEY.
SEY.
SBP.
DYS.
AML,
GLY
SBP.
SBP.
UVC.
HMP.
RH.
CGY,
CP,
HMP, ONX.
GAP.
LMI,
x.
CGY,
GAP
CGY.
GLY.
GLY.
U\'C.
HMP.
MYW.
ARL,
NTL,
PEK, SEA.
HEW,
MRV,
NTL.
ACE, AES, CON, DA, DYS. ESS, GAP, GRC, GRL, HEW, HNT, HRT.
JRG, LUR, MCP, NMC, PCH, PEK, PG, SOP, SIVT.
AGP, CON, CP, GRC, HEW, JRG, LEV, NMC, NPR, PG, PRX,
SWT, VAC.
BSW.
GRC, HNT, NMC.
GRC, NMC.
SURFACE -ACTIVE AGENTS
177
TABLE 2.
-Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 19 70- -Continued
Anionic Surface-Active Agents-'Contimied
*Carboxylic acids (and salts thereof] --Continued
*Potassium and sodium salts of fatty, rosin, and
tall oil acids--Continued
Grease, sodium salt
Laurie acid, potassium salt
*Mixed vegetable fatty acids, potassium salt
Mixed vegetable fatty acids, sodium salt
Myristic acid, potassium salt
*01eic acid, potassium salt
*01eic acid, sodium salt
Olive oil acids, sodium salt
Palm kernel oil acids, sodium salt
Palm oil acids, sodium salt
Peanut oil acids, potassium salt
Peanut oil acids, sodium salt
Rosin acids, potassium salt
Rosin acids, sodium salt
*Soybean oil acids, potassium and sodium salts:
Potassium salt
Sodium salt
*Stearic acid, potassium salt
Stearic acid, sodium salt
*Tall oil acids, potassium and sodium salts:
*Potassium salt
*Sodium salt
Tallow acids, potassium salt
*Tallow acids, sodium salt
All other
'Phosphoric and polyphosphoric acid esters (and salts
thereof) :
*Alcohols and phenols, ethoxylated and phosphated:
Butyl alcohol ethoxylated and phosphated
*Dinonylphenol, ethoxylated and phosphated
Dodecyl alcohol, ethoxylated and phosphated
Dodecylphenol, ethoxylated and phosphated
2-Ethylhexanol, ethoxylated and phosphated
Iso-pentyl alcohol, ethoxylated and phosphated
*Mixed linear alcohols, ethoxylated and phosphated--
*Nonylphenol, ethoxylated and phosphated
9-Octadecenyl alcohol, ethoxylated and phosphated--
9-Octadecenyl alcohol, ethoxylated and phosphated
ethanolamine salt.
Octylphenol, ethoxylated and phosphated
Octylphenol, ethoxylated and phosphated, magnesium
salt.
Phenol, ethoxylated and phosphated
Polyhydric alcohol, ethoxylated and phosphated
*Tridecyl alcohol, ethoxylated and phosphated
All other
Manufacturers ' identification codes
(according to list in table 3)
NMC.
VAL.
AES, AML, DYS, GRC, GRL, LUR, PCH, PEK, SWT.
HAL, SWT.
AES.
AES, ARL, CGY, CHP, DA, DYS, GYR, HNT, S, SHP, SWT,
USR, WBG.
BSW, DA, GYR, LEV, LUR, MRV, NMC, SIVT, USR, WBG, WTC.
HEW, HNT, LUR.
NMC.
HEW, LUR, PRX.
KAL, SLC.
NMC.
USR, X.
CRT, HRT, PRX, SLM, x.
CON, DYS, HEW, PEK.
HEW.
GYR. HEW, USR, WTC.
DA, HEW, LEV, MAL, MRV, WTC.
ACE, AES, ACY, CON, DYS, ESS, GAP, GRC, HNT, NMC,
PEK, PNX, SOP, VAL, x.
ASY, GRC, GYR, PRX, SNW, SOP, UNP, x.
AES, ASY, DYS, GYR, PG, SWT, USR.
AGP, ASY, BSW, CON, CP, DA, GRC, GYR, HEW, JRG, LEV,
LUR, NMC, NPR, PG, PRX, QCP, SWT.
ASY.
GAP.
GAP, RTF, TCH, TXT.
GAP, wic, wrc.
GAP.
WAY.
GAP.
CHP, CRT, GST, GAP, SEY, TCH, TXT, WTC, WYN.
GAP, HDG, NLC, RTP, SCP, SEY, TCC, TCI, TXN, TXT,
VAC, WAY, WTC.
GAP.
GAP.
DUP, RH, WAY.
GAP, WTC, X.
NLC.
GAP, LUR, NLC, SOP, TCC, WAY, WTC.
GAP, WTC.
178
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
Anionic Surfaae-Aative ;ljents--Continued
'Phosphoric and polyphosphoric acid esters (and salts
thereof) --Continued
*Alcohols, phosphated or polyphosphated:
Decyl, dodecyl, and octyl phosphate, morpholine
salt.
Decyl and octyl phosphate
Decyl polyphosphate, sodium salt
Decyl polyphosphate, triethanolamine salt
2-Ethylhexyl phosphate
*2-Ethylhexyl phosphate, sodium salt
2-Ethylhexyl polyphosphate
2-Ethylhexyl polyphosphate, sodium salt
Hexyl polyphosphate, potassium salt
Mixed alkyl ohosphate
Mixed alkyl phosphate, diethanelamine salt
9-Octadecenyl phosphate
Octadecyl phosphate, triethanolamine salt
Octyl phosphate
Octyl phosphate, alkylamine salt
Octyl phosphate, potassium salt
Octyl polyphosphate
Octyl polyphosphate, potassium salt
All other
'Sulfonic acids (and salts thereof) :
*Alkylbenzenesulfonates :
*Dodecy Ibenzenesulf onates ;
*Dodecylbenzenesulfonic acid
Dodecylbenzenesulfonic acid, ammonium salt
Dodecylbenzenesulfonic acid, butylamine salt
♦Dodecylbenzenesulfonic acid, calcium salt
Dodecylbenzenesulfonic acid, diethanolamine salt-
Dodecylbenzenesulfonic acid, dimethylamine salt--
Dodecy Ibenzenesulf onic acid, ethylenediamine
salt.
♦Dodecylbenzenesulfonic acid, isopropanolamine
salt.
♦Dodecylbenzenesulfonic acid, isopropylamine
salt.
Dodecylbenzenesulfonic acid, (mixed alkyl)amine
salt.
♦Dodecylbenzenesulfonic acid., potassium salt
♦Dodecylbenzenesulfonic acid, sodium salt
♦Dodecylbenzenesulfonic acid, triethanolamine
salt.
♦Other alkylbenzenesulfonates:
Decylbenzenesulfonic acid, sodium salt
Didodecy Ibenzenesulf onic acid
Didodecylbenzenesulfonic acid, sodium salt
Pentadecylbenzenesulfonic acid, potassium salt-
Pentylbenzenesulfonic acid, sodium salt
DUP, HDG.
DUP, TXN.
nrrc.
RCD.
WAY.
SEY, TCI, UCC, UVC.
SFA, TCC, TCI.
SPA.
DEX.
CST, DUP, SFA, TCC.
DUP.
DUP.
RCD.
TXT.
DUP, TXT.
DUP.
DEX.
x.
SFA, VAL.
ACS, ARD, ATR, CO, CRT, CTL, EMK, HLI , LAK, LEV, PIL,
PLX, PRX, RCD, RTF, STP, TCI, TEN, TXT.
AKS, ARL, ATR, TXN.
SOP, WTC.
APD, NLC, RCD, RH, RTF, STP, WTC.
SOP, VAL, WTC.
PIL.
APD.
CTL, RCD, X.
APD, CTL, RCD, SNW, STP, TCH.
ECC, NLC, PCS, OTC.
RCD, SOP, VAL.
AAC, ACS, AKS, APX, ARD, ARL, ATR, BLA, CO, CP, CRT,
CTL, DA, DEP, DSO, ECC, HLI, LEV, MON, PG, PIL,
PLX, PRX, RCD, STP, TEN, TXN, TXT, WTC.
AAC, ACS, ARD, ARL, CTL, ESS, HLI. PEK, PIL, RCD,
RTF, SOS, STP, TXN, VAC, IVTC, x.
LAK, MON.
CO.
ATR.
STP.
MON.
SURFACE -ACTIVE AGENTS
179
TABLE 2. — Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Anionic Surface-Active j43e?jts--Continued
'Sulfonic acids (and salts thereof) --Continued
*Alkylbenzenesulfonates- -Continued
*Other alky Ibenzenesulfonates- -Continued
Tridecylbenzenesulfonic acid
*Tridecylbenzenesulfonic acid, sodium salt
Tridecylbenzenesulfonic acid, triethanolamine
salt.
Undecylbenzenesulfonic acid
Undecylbenzenesulfonic acid, ammonium salt
Undecylbenzenesulfonic acid, sodium salt
Undecylbenzenesulfonic acid, triethanolamine
salt.
All other
*Benzene-, cumene-, toluene-, and xylenesulfonates :
Benz^^sulfonic acid, sodium salt
*Cumenesulfonic acid, ammonium salt
Cumenesulfonic acid, sodium salt
Toluenesulfonic acid
Toluenesulfonic acid, potassium salt
Toluenesulfonic acid, sodium salt
Xylenesulfonic acid
*Xylenesulfonic acid, ammonium salt
Xylenesulfonic acid, potassium salt
*Xylenesulfonic acid, sodium salt
*Ligninsulfonates :
Ligninsulfonic acid, aluminum salt
Ligninsulfonic acid, ammonium salt
*Ligninsulfonic acid, calcium salt
*Ligninsulfonic acid, chromium salt
Ligninsulfonic acid, iron salt -r
Ligninsulfonic acid, magnesium salt
Ligninsulfonic acid, mixed salts
*Ligninsulfonic acid, sodium salt
All other
*Naphthalenesulfonates :
Alkylnaphthalenesulfonic acid, sodium salt
*ButyJ- and dibutylnaphthalenesulfonic acid
and sodium salt :
Butylnaphthalenesulfonic acid, sodium salt
Dibutylnaphthalenesulfonic acid
Didodecylnaphthalenesulfonic acid, sodium salt
Diisopropylnaphthalenesulfonic acid, sodium salt
Dipentylnaphthalenesulfonic acid, ammonium salt
Dipentylnaphthalenesulfonic acid, (mixed alkyl)-
amine salt.
Dipentylnaphthalenesulfonic acid, sodium salt
Isopropylnaphthalenesulfonic acid
Isopropylnaphthalenesulfonic acid, ammonium salt
Methylenebis (2-naphthalenesulfonic acid)
Methylnaphthalenesulfonic acid, sodium salt
Methylnonylnaphthalenesulfonic acid, sodium salt
Tetrahydronaphthalenesulfonic acid
All other
Manufacturers ' identification codes
(according to list in table 3)
CO,
BLA,
PCS.
TXT.
TXT.
TXT.
TXT.
PIL, RCD.
CO, CP, NPR, PG, PIL, RCD, TXT, UTTC .
NES,
NES
NES,
NES,
NES
CO,
HLl,
CO,
NES.
ATR.
MAR.
CPP,
CRZ,
DCP,
CRZ,
WVA.
PSP.
CRZ,
WVA.
STP, WTC.
RCD, WTC.
RCD, STP, TXN.
NES, STP, WTC.
HLI, NES, RCD, STP, TXN, WTC.
CO, HLI, NES, PIL, RCD, SDC, STP, TXN, WTC.
CRZ, SPA.
CWP, GLY, LKY, MAR, PSP.
MAR, RAY.
WVA.
MAR, RAY, SNC, WVA.
CLD,
DA, ECC, PFZ
GAP,
S.
PFZ.
GAP,
PFZ.
NLC.
NLC.
CGY.
DUP,
GRD.
NLC.
DUP.
DA,
UDI.
UDI.
DUP.
TRC.
180
SYNTHETIC ORGANIC CHEMICALS, 1970
-Surface-active agents for which U.S. productibn or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
Anionio Surfaae-Aotive Agents — Continued
•Sulfonic acids (and salts thereof)--Continued
•Sulfonic acids having amide linkages:
*Sulfosuccinic acid derivatives:
N- (1 ,2-Dicarboxyethyl)-N-octadecylsulfosuccinamic
acid, tetrasodium salt.
N-(2-Hydroxyethyl)-N- (tallow alkyl)sulfo-
succinamic acid, disodium salt.
N-Octadecylsulfosuccinamic acid, disodium salt^
Sulfosuccinic acid, alkanolamide half ester,
sodium salt.
Sulfosuccinic acid, alkanolamide half ester, tri-
ethanolamine salt.
Sulfosuccinic acid, 2- (coconut oil amido)ethyl
ester, disodium salt.
•Taurine derivatives:
N- (Coconut oil acyl)-N-methyltaurine, sodium
salt.
N- (Cyclohexyl-N-palmitoyltaurine, sodium
salt.
*N-Methyl-N-oleoyltaurine, sodium salt
N-Methyl-N-palmitoyltaurine, sodium salt
N-Methyl-N- (tall oil acyl)taurine, sodium salt
N-Methyl-N- (tallow acyl)taurine, sodium salt
All other
•Sulfonic acids having ester or ether linkages:
•Sulfosuccinic acid esters:
Sulfosuccinic acid, bis(2,6-dimethyl-4-heptyl]
ester, sodium salt.
•Sulfosuccinic acid, bis(2-ethylhexyl) ester,
sodium salt.
Sulfosuccinic acid, bis (tallow monoglyceride)
ester, sodium salt.
Sulfosuccinic acid, dihexyl ester, sodium salt
Sulfosuccinic acid, diisobutyl ester, sodium
salt.
Sulfosuccinic acid, diisodecyl ester, sodium
salt.
Sulfosuccinic acid, diisooctyl ester, sodium
salt.
Sulfosuccinic acid, dipentyl ester, sodium
salt.
Sulfosuccinic acid, ditridecyl ester, sodium
salt.
•Other sulfonic acids having ester or ether
linkages:
Coconut oil acids, 2-sulfoethyl ester, sodium
salt.
Dodecyldiphenyloxidedisulfonic acid, disodium
salt.
Dodecyl sulfoacetate
Iso-octylphenol, ethoxylated and sulfonated,
sodium salt.
All other
ACY,
CTN,
MOA.
SCP.
ACY.
HDG,
SCP.
SCP.
LAK.
GAP,
LIL,
TNI.
GAP.
CRT, DA, DEP, GAP, HRT, MCP, SNW.
GAP, WTC.
DUP, GAP.
GAP.
GAP.
ACY, AKS, CGY, CHP, CRT, GST, DA, DAN, ECC, EMK, HDG,
HRT, ICl, MCP, MOA, PC, TCI, UVC.
ACY.
ACY,
MOA
MOA.
MCP.
RH.
ACY.
ACY,
MOA
GAP,
LEV,
X
DOW
ACS
CRT,
RH.
PG,
SLM.
SURFACE -ACTIVE AGENTS
181
TABLE 2. — Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers ' identification codes
(according to list in table 3)
Anionio Surfaae-Aative ,4g'ents--Continued
'Sulfonic acids (and salts thereof] — Continued
*A11 other sulfonic acids:
Butylhydroxybiphenylsulfonic acid
Mixed alkanesulfonic acid, sodium salt
Mixed fish oils, sulfonated
Petroleumsulfonic acid, water soluble
(acid layer), sodium salt.
All other
'Sulfuric acid esters (and salts thereof) :
*Acids, amides, and esters, sulfated:
'Coconut oil acids - ethanolamine condensate,
sulfated, potassium salt.
Glycerol monoester of coconut oil acids, sulfated,
sodium salt.
9-Octadecenyl acetate, sulfated, sodium salt
'Oleic acid esters, sulfated:
2-Butoxyethyl oleate, sulfated, sodium salt
'Butyl oleate, sulfated, sodium salt
2-Ethylhexyl oleate, sulfated, sodium salt
Ethyl oleate, sulfated, sodium salt
'Glycerol trioleate, sulfated, sodium salt
'Isopropyl oleate, sulfated, sodium salt
Methyl oleate, sulfated, sodium salt
Mixed esters of oleic acid, sulfated, sodium
salt.
'Propyl oleate, sulfated, sodium salt
'Oleic acid, sulfated, disodium salt
Oleic acid, sulfated, triethanolamine salt
Propyl ricinoleate, sulfated, disodium salt
'Tall oil, sulfated, sodium salt
All other
'Alcohols, sulfated:
'Coconut and sperm oil alkyl sulfate, sodium salt--
Decyl and octyl sulfate, sodium salt
Decyl sulfate, sodium salt
3,9-Diethyl-6-tridecyl sulfate, sodium salt
'Dodecyl sulfate salts:
2-Amino-2-methylpropanol salt
'Ammonium salt
'Diethanolamine salt
Diethylamine salt
N,N-Diethylcyclohexy lamina salt
Isopropanolamine salt
'Magnesium salt
Potassium salt
'Sodium salt
'Triethanolamine salt
2-Ethylhexyl sulfate, sodium salt
7-Ethyl-2-methyl-4-undecyl sulfate, sodium salt---
Hexadecyl and 9-octadecenyl sulfate, sodium salt--
RBC.
DUP, VPC.
SLM.
WTC.
STC.
DEX, EMK, ONX.
AAC, CP.
S.
AKS, EFH, ICl, MCP, ONX, PC.
MCP.
GAP.
LEA, MRV, SCP.
CRT, DEX, ECC, HRT, ICl, LEA, SCP.
DA, ICl.
EFH, MCP, SEY.
ACY, CHP, GAP, MRV, WTC.
ACT, ACY, CRT, DA, EFH, GAP, ICl, LEA, MRV, SCO,
TEN, WHW.
WAY.
AKS.
ACY, APX, BAO, CHP, DA, HRT, ICI, KAL, MRV, RTF,
SEA, WHI, WHW.
EMR. SLM.
DEP, DUP.
PCS.
CTL, DA, DUP.
UCC.
DUP.
AAC, CTL, HLI, JRG, ONX, PCS, RCD, SCP, STP, WTC.
DUP, HLI, JRG, ONX, SCP, STP, WTC.
AAC.
DUP.
JRG, PCS.
AAC, HLI, ONX, STP.
HLI, PC, RCD.
AAC, CTL, DUP, HLI, JRG, ONX, PCS, PC, RCD, RTF.
SCP, SEY, STP.
AAC, CTL, DUP, HLI, ONX, PCS, PG, RCD, SCP, SEY,
STP, TXT.
AAC, PCS, UCC.
UCC.
AAC, RCD.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. --Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970-- Continued
Manufacturers' identification codes
(according to list in table 3)
Anionic Surface-Active Agrents--Continued
^Sulfuric acid esters (and salts thereof) --Continued
♦Alcohols, sulfated--Continued
Hexadecyl sulfate, sodium salt
Hexyl sulfate, potassium salt
*Mixed linear alcohol sulfate, ammonium salt
*Mixed linear alcohol sulfate, sodium salt
Mixed linear alcohol sulfate, triethanolamine
salt.
Nonyl sulfate, sodium salt
Octadecyl sulfate, sodium salt
Octadecyl sulfate, triethanolamine salt
Octyl sulfate, sodium salt
Tridecyl sulfate, sodium salt
*Ethers, sulfated:
*Alkylphenols, ethoxylated and sulfated:
Iso-octylphenol, ethoxylated and sulfated,
sodium salt.
Nonylphenol, ethoxylated and sulfated, ammonium
salt.
Nonylphenol, ethoxylated and sulfated, sodium
salt.
Nonylphenol, ethoxylated and sulfated, tri-
ethanolamine salt.
*Dodecyl alcohol, ethoxylated and sulfated,
ammonium salt.
*Dodecyl alcohol, ethoxylated and sulfated,
sodium salt.
Dodecyl and tetradecyl alcohols, ethoxylated
and sulfated, ammonium salt.
2-Hexyloxypropyl sulfate, sodium salt
Mixed linear alcohols, ethoxylated and sulfated,
ammonium salt.
*Mixed linear alcohols, elhoxylated and sulfated,
sodium salt.
Sperm oil alcohol, ethoxylated and sulfated,
sodium salt.
Tridecyl alcohol, ethoxylated and sulfated,
sodium salt.
All other
•Natural fats and oils, sulfated:
*Castor oil, sulfated, sodium salt
*Coconut oil, sulfated, sodium salt
*Cod oil, sulfated, sodium salt
Grease, other than wool, sulfated, sodium salt
Herring oil, sulfated, sodium salt
Lard, sulfated, sodium salt
Mixed animal and vegetable oils, sulfated, sodium
salt.
*Mixed fish oils, sulfated, sodium salt
Mustard seed oil, sulfated, sodium salt
*Neat's-foot oil, sulfated, sodium salt
Peanut oil, sulfated, sodium salt
AAC, DUP, SCP.
DEX.
CP, LAK, S, SCP, TXT.
CP, LAK, SCP, TXT, VAC.
LAK.
TEN.
DUP, EMK, ONX, PG.
DUP.
AAC, DUP.
AAC.
RH.
CGY, GAP, STP, TXT, x.
CRT, GAP.
ARL.
AAC, CTL, HLI, TXT.
AAC, CTL, DUP, ONX, PCS, RCD, RTF, SCP, STP.
LEV, TXN.
S.
CO, LAK, NLC, PIL, RCD, SCP, SHC, STP, TXT, UCC.
CO, CRT, DA, GAP, LAK, PIL, RCD, SCP, SHC, STP, TCI,
TXT.
DUP, WAW.
AAC, ARL, RCD.
APX, PG.
ACT, ACY, AKS, AML, APX, BAO, BSW, CRT, DA, DEX,
EFH, GAP, HRT, ICl, KAL, KNG, LEA, LUR, MCP, MRD,
MRV, ONX, PC, S, SCO, SLC, SLM, SNW, WHl , WHW.
ACY, BAO, DA, KNG, LUR, MRD, SEA, WHW.
ACT, BAO, CRT, S, SEA, WAW, WHl, WHW.
SEA, WHl.
ACT, DA, WHl, WHW.
SLM, WAW.
SLM.
ACT, AML, DA, MRD, SCO, SLM.
DA, LUR.
ACT, BAO, CRT, DA, KAL, LUR, MRD, PC, SEA, SLM, WHW.
ACY, DA, LEA, LUR, SLC.
SURFACE -ACTIVE AGENTS
183
TABLE 2. — Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
Anionic Surface-Active /43ents--Continued
♦Sulfuric acid esters (and salts thereof) --Continued
♦Natural fats and oils, sulfated — Continued
Ricebran oil, sulfated, sodium salt
♦Soybean oil, sulfated, sodium salt
♦Sperm oil, sulfated, sodium salt
♦Tallow, sulfated, sodium salt
Whale oil, sulfated, sodium salt
Other anionic surface-active agents:
Lignin (non-sulfonated) and salts thereof
Mixed linear alcohols, ethoxylated and carbonated,
sodium salt.
Tridecyl alcohol, ethoxylated and carbonated,
sodium salt.
Cationic Surface-Active Agents
♦Amine oxides and oxygen-containing amines (except
those having amide linkages) :
*Acyclic:
N,N-Bis (2-hydroxyethyl)decylamine oxide
N,N-Bis (2-hydroxyethyl)dodecyl amine
N,N-Bis (2-hydroxyethyl)octadecylamine
N,N-Bis (2-hydroxyethyl) (tallow alkyl)amine
N,N-Bis (2-hydroxyethyl) (tallow alkyl)amine acetate-
♦(Coconut oil alkyl)amine, ethoxylated
(Coconut oil alkyl)amine, ethoxylated, acetate
(Coconut oil alkyl)amine, etho;yylated, maleate
N,N-Diethyldecylamine oxide
N,N-Dimethylhexadecylamine oxide
(Hydrogenated tallow alkyl)amine, ethoxylated
N- (2-Hydroxyethyl)-N,N' ,N'-tris (2-hydroxypropyl)-
ethylenediamine.
(Mixed alkyl)amine, ethoxylated
(Mixed alky l)poly(oxyethylene) amine
Mixed substituted oximes
(9-Octadecenyl) amine, ethoxylated
Octadecyl amine, ethoxylated
Polyethylenepolyamine, alkoxylated
(Soybean oil alkyl)amine, ethoxylated
♦(Tallow alkyl)amine, ethoxylated
Tallow alkyl amine sulfate, ethoxylated
N- (Tallow alkyl)trimethylenediamine, ethoxylated
N,N,N' ,N'-Tetrakis (2-hydroxyethyl) ethylenediamine--
N,N,N' ,N' -Tetrakis (2-hydroxypropyl)ethylenediamine,
propoxylated and ethoxylated.
All other
♦Cyclic (except imidazoline and oxazoline derivatives:
N-Hexadecylmorpholine
N- (2 -Hydroxyethy 1 ) - 1 , 2-dipheny lethy lenediamine
Lignin amine
Rosin amine, ethoxylated
N- (Soybean oil alkyl)morpholine
All other
DA, EFH, LUR.
CRT, HRT, KAL, LEA, MRD, ONX.
ACT, BAD, CLD, CRT, DA, HRT, KAL, KNG, LEA, MRD,
ONX, RTC, SEA, WHI , WHW.
ACT, ACY, BSW, DA, ECC, EFH, ICI, K.4L, LUR, MCP, MRD,
ONX, PC, PCI, QCP, SCP, SID, SLM, SOS, WHI.
KNG.
WVA.
S.
BRD.
CTL,
FIN.
ARC,
FIN,
TCH.
ARC.
PG.
AAC,
APD,
ARC, ASH, BRD, SDH, TCH, VAC, WYN
RPC.
SDH.
BRD.
ONX.
CGY,
TCH.
NLC.
APD,
CGY,
DA, GAF, NLC, RH.
GAP.
GNM.
ARC,
TCH.
ARC,
TCH.
NLC.
AAC,
ARC,
VAC.
AAC,
ARC,
CGY, DUP, TCH.
DUP.
ARC.
NLC.
ARC,
WYN.
ARC,
BRD,
X.
APD,
wrc.
APX,
WVA.
HPC,
NLC,
PCS, RTF, iirrc.
APD.
TCH.
184
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. --Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers
identification codes
Chemical
(according
to list in table 3)
Cationia Supface-Aotive Agents--Contirmed
*Amine oxides and oxygen-containing amines (except those
having amide linkages) — Continued
* Imidazoline and oxazoline derivates:
2-(8-Heptadecenyl)-4,4-bis(hydroxymethyl)-2-
COM,
SIVT,
UVC
oxazoline.
*2- (8-Heptadeceny 1) - 1- (2-hydroxyethyl )-2-
DA,
ONX,
UVC,
VAC.
imidazoline.
2- (S-Heptadecenyl) -4-hydroxymethyl-4-methyl-2-
CGY,
COM
UVC
oxazoline.
2- CHeptadecylH-C2-hydroxyethyl) -2- imidazoline
CGY.
MOA,
UVC
VAC.
UVC.
1- (2-Hydroxyethyl)-2-nor(coconut oil alkyl}-2-
CGY,
MOA,
PCS
UVC.
imidazoline.
*l-(2-Hydroxyethyl)-2-nor(tall oil alkyl)-2-
HDG,
MOA,
NLC
UVC.
imidazoline.
1- (2-Hydroxyethyl )-2-tridecyl-2-imidazoline
UVC,
WTC.
hydrochloride.
UVC.
2- f 1 1- Hydro xy-8-heptadecenvl) -2- imidazoline
UVC.
All other
EMR.
*Amines and amine oxides having amide linkages:
*Carboxylic acid - diamine and polyamine condensates:
Caprylic acid - tetraethylenepentamine condensate
ICI.
Coconut oil acids - diethylenetriamine condensate
AFX,
TXT.
Coconut oil acids - N,N-dimethyltrimethylene-
JRG,
TXT,
WTC
diamine condensate.
Mixed dicarboxylic acids - polyalkylenepolyamine
TXT.
condensate.
Mixed fatty acids - polyalkylenepolyamine
GRD,
NLC.
condensate.
Oleic acid - 1- (2raminoethyl)piperazine condensate--
TXT.
AFD,
TXT.
Oleic acid - N,N-dimethyltrimethylenediamine
CCtV.
condensate.
Pelargonic acid - tetraethylenepentamine
ICI.
condensate.
♦Stearic acid - diethylenetriamine condensate
CHP,
CST,
HRT,
ONX, S.
Stearic acid - N,N-diethylethylenediamine
CGY.
condensate.
Stearic acid - dipropylenetriamine condensate
JOR.
Stearic acid - tetraethylenepentamine condensate
DEX,
ICI,
ONX.
Tall oil acids - diethylenetriamine condensate
New,
NLC,
RTF.
Tall oil acids - polyalkylenepolyamine condensate
RTF.
All other
EFH.
VND.
Carboxylic acid - diamine and polyamine condensates.
alkoxylated:
Coconut oil acids - diethylenetriamine condensate
TCC.
polyethoxylated.
Coconut oil acids - ethylenediamine condensate.
ARL.
monoethoxylated.
*01eic acid - ethylenediamine condensate, mono-
CLD,
DA,
DEX,
SOC, TNA.
ethoxylated.
Palm oil acids - ethylenediamine condensate, mono-
APX.
ethoxylated.
SURFACE -ACTIVE AGENTS
185
TABLE 2. --Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
Cationio Surface-Active <4g'e?zts--Continued
'Amines and amine oxides having amide
linkages — Continued
Carboxylic acid - diamine and polyamine condensates,
alkoxylated- -Continued
'Stearic acid - ethylenediamine condensate, mono-
ethoxylated.
Stearic acid - diethylenetriamine condensate, poly-
ethoxylated.
Stearic acid - ethylenediamine condensate, poly-
ethoxylated.
3-Lauramido-N,N-dimethylpropylamine oxide
All other
* Amines, not containing oxygen (and salts thereof]:
*Amine salts:
(Coconut oil alkyl^amine acetate
N- (Coconut oil alkyl)trimethylenediamine acetate
(Hydrogenated tallow alkyl)amine acetate
(9-0ctadecenyl)amine acetate
Octadecyl amine acetate
Octylamine acetate
(Tallow alkyl)amine acetate
N- (Tallow alkyl)trimethylenediamine acetate
N- (Tallow alkyl)trimethylenediamine naphthenate
N- (Tallow alkyl)trimethylenediamine oleate
All other
♦Diamines and polyamines :
*N- (Coconut oil alkyl]trimethylenediamine
N-(Docosyl- and eicosyl)trimethylenediamine
*Imidazoline derivatives:
1- (2-Aminoethyl)-2-heptadecyl-2-imidazoline
1- (2-Aminoethyl)-2- (mixed alkyl)-2-imida2oline
1- [3- (2-Aminoethyl)naphth-l-yl] -2- (8-hepta-
decenyl)-2-imidazoline.
1- (2-Aminoethyl5-2-nor(tall oil alkyl)-2-
imidazoline.
2- (8-Heptadecenyl)-2-imidazoline
2-Heptadecyl-2-imidazoline
N- (Mixed alkyl)polyethylenepolyamine
*N- (9-0ctadecenyl)trimethylenediamine
Polybutene amine
N- (Soybean oil alkyl)trimethylenediamine
N-(Tall oil alkyljtrimethylenediamine
N- (Tallow alkyl)dipropylenetriamine
*N- (Tallow alkyl]trimethylenediamine
•Primary monoamines:
(Coconut oil alkyl^amine
(Cottonseed oil alkyl)amine
Dodecylamine
Docosyl- and eicosylamine
Hexadecylamine
* (Hydrogenated tallow alkyl]amine
(Mixed alky 1) amine
(Mixed tert-alkyl) amine
Myristylamine
*9-0ctadecenylamine
AML, CLD, CST, DA, DEX, ECC, ICI, MRA, S, SNW.
TCC.
APD.
SNW.
MYW,
UVC.
ARC,
IVTC.
ASH.
ARC,
ASH.
ARC,
GNM.
ACY,
ARC.
ARC.
ARC.
ARC,
ASH.
APD.
ARC,
ASH.
ARC.
ARC,
ENO,
GNM.
ENO.
UVC.
UVC.
NLC.
NLC,
RTF,
UVC.
PCS.
SCO.
CCW.
ARC,
ASH,
GNM.
ORO.
ENO.
ARC.
ARC,
GNM.
ARC,
ASH,
ENO, GNM
ARC,
ENO,
GNM.
ASH.
ARC,
ASH,
GNM.
ENO
ENO.
ARC,
ASH,
ENO, GNM
ARC,
GNM.
RH.
GNM.
ARC,
ASH,
ENO, GNM
186
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970--Continued
Manufacturers' identification codes
(according to list in table 3)
Cationio Surfaae-Aotive 4grents--Continued
•Amines, not containing oxygen (and salts thereof) --
Continued
♦Primary iiionoamines--Continued
*Octadecyl amine
Octylamine ■
tert-Octylamine
(Soybean oil alkyl)amine
(Tall oil alkyl)amine
* (Tallow alkyl) amine
♦Secondary and tertiary monoamines :
Bis(coconut oil alkyl)amine
Bis(hydrogenated tallow alkyl)amine
Bis (soybean oil alkyl)amine
N,N-Diethyloctylamine
N,N-Dimethyl (coconut oil alkyl)amine
N,N-Dimethyldecyl amine
N,N-Dimethyl (docosyl and eicosyl)amine
N,N-Dimethyldodecyl amine
N,N- Dime thy Ihexadecyl amine
N,N-Dimethyl (hydrogenated tallow alkyl)ajnine
N,N-Dimethyl (mixed alkyl)amine
*N, N-Dime thy loctadecyl amine
N,N-Dimethyl (soybean oil alkyl)amine
N, N-Dime thy Itetradecylamine
N,N-Dimethyltridecyl amine
*N-Methy Ibis (coconut oil alkyl)amine
*N-Methy Ibis (hydrogenated tallow alkyl]amine
N-Methylbis(mixed alkyl) amine
N-Methyldioctadecylamine
Tri octylamine
*Oxygen~containing quaternary ammonium salts:
Quaternary ammonium salts having amide linkages:
(2-Hydroxyethyl)dimethyl (3-stearai]iidopropyl) -
ammonium dihydrogen phosphate.
(2-Hydroxyethyl)dimethyl(3-stearajiiidopropyl)-
ammonium nitrate.
(3-Lauramidopropyl)trimethylammonium methyl
sulfate.
2- (2-Lauroyloxyethyl) carbamoyl- 1-methylpyridinium
chloride.
Stearic acid - diethanolamine condensate, methyl
sulfate.
Tall oil acid - polyalkylenepolyamine condensate,
quaternary sulfate.
Trimethyl (3-oleamidopropyl) ammonium methyl
sulfate.
All other
Other oxygen-containing quaternary ammonium salts;
(2-Aminoethyl)ethyl(hydrogenated tallow alkyl)2-
hydroxyethyl) ammonium ethyl sulfate.
Benzyl (coconut oil alkyl)bis (2-hydroxyethyl)-
aramonium chloride.
ARC,
ASH,
ENO,
GNM.
ARC.
RH.
ARC,
ENO.
ASH,
GNM.
ARC,
ASH,
ENO,
GNM, SNW
ARC.
ARC,
ASH,
ENO.
ARC.
BRD.
ARC,
ASH,
BRD,
ENO.
BRD.
ENO.
ARC,
BRD.
ARC,
BRD.
ARC,
ASH.
ARC,
BRD,
PG.
ARC,
ASH,
BRD,
ENO.
ARC,
ENO.
ARC,
BRD,
GNM.
BRD.
ARC,
ENO,
GNM.
ARC,
ASH,
ENO,
GNM.
PG.
ASH.
GNM.
ACY.
ACY.
ACY.
IVTC.
DUP.
NLC.
CGY.
ARC,
VAC.
LUR.
CGY,
NLC.
SURFACE -ACTIVE AGENTS
187
TABLE 2. --Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Chemical
Manufacturers
(according
identification codes
to list in table 3)
Caticnio Surface-Active Agents — Continued
•Oxygen-containing quaternary ammonium salts- -Continued
Other oxygen-containing quaternary ammonium
salts- -Continued
Benzyl (coconut oil alkyl, ethoxylated)dimethyl-
GAP.
ammonium chloride.
l-Benzyl-2-heptadecyl-l-(2-hydroxyethyl)-2-
UVC.
imidazolinium chloride.
l-Benzyl-l-C2-hydroxyethyl)-2-norCtall oil alkyl)-
NLC,
UVC.
2-imidazolinium chloride.
Bis C2-hydroxyethyl , ethoxy lated)methyl (9-octa-
ARC.
decenyl)ammonium chloride.
Bis (2-hydroxyethyl , ethoxylated)methyloctadecyl-
ARC.
ammonium chloride.
CCoconut oil alkyl)bis(2-hydroxyethyl, ethoxy-
ARC,
VAC.
latedjmethylammonium chloride.
(Ethoxybenzyl 3 dimethyl (octylphenoxy) ammonium
RH.
chloride.
(Ethoxybenzyl ) dimethyl (octyltolyloxy^ ammonium
RH.
chloride.
l-Ethyl-2-(8-heptadecenyl)-l-[2-hydroxyethyl)-2-
APD,
UVC.
imidazolinium ethyl sulfate.
N-Ethyl-N-hexadecylmorpholinium ethyl sulfate
APD,
BRD.
N-Ethyl-N- (soybean oil alkyljmorpholinium ethyl
APD,
sulfate.
2(8-Heptadecenyl)-l,l-bis(2-hydroxyethyl)-2-
CGY.
imidazolinium chloride.
N-C2-Hydroxyethyl)-N,N' ,N' -tris (2-hydroxypropyl) -
DUP.
ethylenediamine, distearate methyl sulfate.
2-Hydroxytrimethylenebis[ (Jcoconut oil alkyl)di-
CGY.
methylammonium chloride]
Octadecylamine, propoxylated and quaternarized
TCC.
N,N,N' ,N'-TetrakisC2-hydroxypropyl) ethylene-
DUP.
diamine, dioleate methyl sulfate.
(Tridecylbenzyl)diethyl(2-hydroxyethyl) ammonium
SNW.
chloride.
All other
APD,
ARC.
•Quaternary ammonium salts, not containing oxygen:
•Acyclic:
•Bis (coconut oil alkyl)dimethylammonium chloride
ARC,
ASH,
ENO, GNM, VAC.
Bis (coconut oil alkyl)dimethylammonium nitrate
ARC.
•Bis(hydrogenated tallow alkyl) dimethylammonium
ARC.
ASH,
ENO, GNM, VAC.
chloride.
(Coconut oil alkyl) trimethylammonium chloride
ARC,
ASH,
GNM.
Didecyldimethylammonium chloride
BRD.
Didodecyldimethylammonium bromide
ONX.
Dimethylb
s(9-octadecenyl) ammonium chloride
GNM.
Dimethylb
Ls(soybean oil alkyl) ammonium chloride
ARC.
Dimethyld
Loctadecylammonium chloride
ASH,
ONX,
PG.
Dimethyld
Loctadecylammonium methyl sulfate
ONX.
Dodecyltr
Lmethyl ammonium bromide
DUP.
ARC,
JOR,
GNM,
TCC.
WTC,
Ethyldimethyl (mixed alkyl) ammonium ethyl sulfate
Ethyldiraethyl(9-octadecenyl)ammonium bromide
ONX.
Ethylhexadecyldimethylammonium bromide
FIN.
•Hexadecyltrimethylammonium salts:
Hexadecyltrimethylammonium bromide
DUP,
FIN,
ICI.
Hexadecyltrimethylammonium chloride
ARC,
BRD.
Hexadec
rltrimethylammonium p-toluenesulfonate
FIN.
188
SYNTHETIC ORGANIC CHEMICALS, 1970
-Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
Cationi-o Surface-Active 4jents--Continued
*Quaternary aminonium salts, not containing oxygen--
Continued
* Acyclic --Continued
(Hydrogenated tallow alkyl)triiiiethylammonium
chloride.
Methyl tricctylammonium chloride
MethyltrisWixed alkyl)ammonium chloride
N,N,N' ,N',N'-Pentamethyl-N- (tallow alkyl)tri-
methylenebis [ammonium chloride].
Triethyloctadecylammonium ethyl sulfate
Trimethyl (mixed alkyl) ammonium chloride
Trime thy loctadecyl ammonium chloride
Trimethyl (soybean oil alkyljammonium chloride
*Trimethyl (tallow alkyl) ammonium chloride
Trimethyltetradecylammonium bromide
All other
*Benzenoid:
*Benzyl (coconut oil alkyl )dimethylammonium
chloride.
*Benzyldimethyl (mixed alkyl)ammonium chloride
*Benzyldimethyloctadecylammonium chloride
Benzyldimethyl (tallow alkyl) ammonium chloride
Benzyldimethyltetradecylammonium chloride
Ben zyldodecyl dimethyl ammonium chloride
Benzylhexadecyldimethylammonium chloride
Benzyl (hydrogenated tallow alkyl)dimethylammonium
chloride.
Benzyl (mixed alkyl)pyridinium chloride
l-Benzyl-2-picolinium bromide
1-Benzylpyridinium chloride
*Benzyltrimethylammonium chloride
(3, 4-Dichlorobenzyl)dodecyldimethyl ammonium
chloride.
(Dodecylbenzyl)triethylammonium chloride
(Dodecylbenzyl)trimethylammonium chloride
2-Dodecylisoquinolinium bromide
(Dode cylmethy lb en zyl) trimethyl ammonium chloride —
1-Dodecylpyridinium chloride
(Ethylbenzyl)dimethyl (mixed alkyl) ammonium
chloride.
l-Phenethyl-2-picolinium bromide
Nonionia Surfaae-Aative Agents
*Carboxylic acid amides:
*Diethanolamine condensates (amine/acid ratio=2/l);
*Capric acid
Castor oil acids
•Coconut oil acids
Coconut oil and tallow acids
* Laurie acid
Laurie and myristic acids
Linoleic acid
GNM.
ASH.
ARC,
GNM.
AKS.
NLC.
ARC.
ARC,
ENO,
VAC.
ARC,
ASH,
GNM,
VAC
FIN.
GNM,
STC.
ARC, CRT, DEP, LUR, RTF, TXT.
AAC,
ASY,
BRD,
FIN
ONX, RH, TXT, VAC
BRD,
FIN,
ONX,
RH,
TNI, WSN.
ENO.
BRD,
FIN,
SNW.
FIN,
ONX,
SDH.
ONX.
ENO,
FIN.
RTF.
FIN.
DEP.
CHP,
COM,
CRT,
TCC
WTC.
ONX,
VAC.
CHP,
PC.
NLC,
VAC,
WTC.
ONX.
RH.
BRD,
HK.
ONX.
CGY, PCS, SCP. UVC.
CLI, NTL.
AKS, AML, ARD, BSW, CGY, CLI, CTL, DA, DEP, DSO, EFH,
ESS, HLI, HRT, JOR, KNP, LUR, MCP, MOA, ONX, PC,
PCS, PG, PNX, RCD, RTF, SBC, SCP, SEY, SOP, SOS,
STP, SIVT, TXC, TXN, UNN, UVC, VAC, VAL, WTC. x.
CLI, CRT, ECC, MOA, PG, VND.
CLI, DA, DRW, HLI, ONX, PG, RCD, WON, x.
HLI, MOA, PG.
VND.
SURFACE -ACTIVE AGENTS
189
TABLE 2. — Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
Nonionia Surface-Active 4jents--Continued
*Carboxylic acid amides — Continued
*Diethanolamine condensates (amine/acid ratio=2/l) —
Continued
Mixed vegetable oil acids
Myristic acid
*01eic acid
Pelargonic acid
* Stearic acid
*Tall oil acids
Tallow acids
All other
*Diethanolainine condensates (other amine/acid
ratios) :
*Coconut oil acids (amine/acid ratio=l/l)
Coconut oil acids (amine acid ratio=1.4/l)
*Lauric acid {amine/acid ratio=l/l)
Laurie and myristic acids (amine/acid ratio=l/l)
Linoleic acid (aipine/acid ratio=l/l)
Myristic acid (amine/acid ratio=l/l)
*01eic acid (amine/acid ratio=l/l)
Palmitic and stearic acids (amine/acid ratio=l .3/1)-
*Stearic acid (amine/acid ratio=l/l)
Stearic acid (amine/acid ratio=2.7/l)
Tall oil acids (amine/acid ratio=2.7/l)
Tallow acids (amine/acid ratio=l/l)
Unspecified mixed fatty acids (amine/acid
ratio=l/l) .
All other
* Ethano 1 amine condens at es :
*Coconut oil acids (amine/acid ratio=2/l)
Coconut oil acids (amine/acid ratio=l/l)
Hydrogenated castor oil acids (amine/acid
ratio=2/l).
Hydrogenated tallow acids (amine/acid ratio=2/l)
Laurie acid (amine/acid ratio=2/l)
Laurie and myristic acids (amine/acid ratio=l/l)
Oleic acid (amine/acid ratio=l/l)
Oleic acid (amine/acid ratio=2/l)
Stearic acid (amine/acid ratio=2/l)
Stearic acid (amine/acid ratio=l/l)
Stearic acid (amine/acid ratio=l/2)
*Lauric acid - isopropanolamine condensate
*Other carboxylic acid amides:
Coconut oil acids - ethanolamine condensate,
ethoxylated.
Coconut oil acids - isopropanolamine condensate
Laurie and myristic acids - isopropanolamine
condensate.
Oleic acid - ethanolamine condensate, ethoxylated
Stearic acid - N,N'-diethylethylenediamine
condensate (amine/acid ratio=l/2).
Tallow acids - propanolamine condensate,
ethoxylated.
All other
HLI.
MRT.
CCW, CLI, EMR, STP, UVC, VAC.
EMR.
AML, CLI, DA, EMR, JOR, ONX, SCO, SOS, TXC, VAL.
EFH, MCP, MOA, MRA, SOS.
WTC.
GAP, ROB.
APX, ARD, CCL, CGY, CLI, CTL, DA, HLI, MOA, ONX, PCS,
PIL, RTF, SBC, SCP, SEY, STP, TCC, TXN, TXT, VAC.
JRG.
CTL, EML, HLI, LEV, MOA, ONX, PCS, PG, RTF, SBC, TXN,
VAC.
CLI, TXT.
MOA.
HDG.
CGY, ECC, SBC, SWT, TCC, TXT.
MCP.
CGY, EMR, GAF, GLY, RFC, SEY, UVC.
EFH.
EFH.
RFC.
STP.
EFH.
CTL, PCS, PEK, STP, VND, WTC.
MOA, PG, STP, UVC.
GLY, NTL.
GLY
ARC,
CTL.
MOA,
TXN
VPC.
ARD.
ARC,
CLI
ECC.
MOA,
VND.
GLY.
CLI,
MOA,
SNW.
DA,
GAF,
STP.
STP.
LEV,
TXT.
GAF.
SNW.
NLC.
ARC.
462-669 0-72-13
190
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. ■
-Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers ' identification codes
(according to list in table 3)
Nonionio Suvfaoe-Aative Agents — Continued
*Carboxylic acid esters:
*Anhydrosorbitol esters:
Anhydrosorbital ester of mixed fatty acids
Anhydrosorbitol dioleate
Anhydrosorbitol monoester of tall oil acids
Anhydrosorbitol monolaurate
* Anhydrosorbitol mono-oleate
*Aiihydrosorbitol monopalmitate
*Anhydrosorbitol monostearate
Anhydrosorbitol sesquioleate
Anhydrosorbitol triester of tall oil acids
Anhydrosorbitol trioleate
♦Anhydrosorbitol tristearate
*Diethylene glycol esters:
Diethylene glycol dioleate
Diethylene glycol distearate
Diethylene glycol monoester of coconut oil acids--
*Diethylene glycol monolaurate
Diethylene glycol mono-oleate
Diethylene glycol monoricinoleate
*Diethylene glycol monostearate
Diethylene glycol sesquiester of tall oil acids —
Diethylene glycol sesquilaurate
Diethylene glycol sesquistearate
*Ethoxylated anhydrosorbitol esters:
Ethoxylated anhydrosorbitol monoester of tall oil
acids.
*Ethoxylated anhydrosorbitol monolaurate
*Ethoxylated anhydrosorbitol mono-oleate
Ethoxylated anhydrosorbitol monopalmitate
■■*Ethoxylated anhydrosorbitol monostearate
Ethoxylated anhydrosorbitol triester of tall oil
acids.
Ethoxylated anhydrosorbitol trioleate
*Bthoxylated anhydrosorbitol tristearate
Ethoxylated sorbitol esters:
Ethoxylated sorbitol beeswax ester
Ethoxylated sorbitol distearate
Ethoxylated sorbitol heptaoleate
Ethoxylated sorbitol hexaester of tall oil acids--
Ethoxylated sorbitol hexaoleate
Ethoxylated sorbitol lanolin ester
Ethoxylated sorbitol mono-oleate
Ethoxylated sorbitol monostearate"
Ethoxylated sorbitol oleate, acetylated
Ethoxylated sorbitol pentaester of tall oil acids-
Ethoxylated sorbitol pentalaurate
Ethoxylated sorbitol pentaoleate
Ethoxylated sorbitol tetraester of lauric and
oleic acids.
Ethoxylated sorbitol tetraester of tall oil acids-
Ethoxylated sorbitol tetraoleate
♦Ethylene glycol esters:
Ethylene glycol distearate
Ethylene glycol ester of dimer acid
Ethylene glycol mono-oleate
Ethylene glycol monostearate
Ethylene glycol sesquistearate
GLY.
APD,
HDG.
APD,
GLY,
HDG,
TCH.
APD,
GLY,
HDG,
PCS,
TCH.
AAC,
APD,
ARC,
DRW,
GLY, HDG, PCS, TCH
APD,
GLY,
HDG,
PCS,
TCH.
APD,
DRW,
GLD,
GLY
PCS.
AAC,
GLY,
HDG.
TCH.
AAC,
APD,
GLY,
PCS,
TCH.
APD,
GLY,
PCS.
GLY.
ARC,
GLY.
DA.
CCW,
ECC,
GLY,
HAL,
HDG.
ARC,
EMR,
HAL.
GLY.
ARC,
CLl,
DA,
ECC,
HAL, HDG, MCP, PCS,
WM
, WTC
ECC,
WTC.
ARC,
GLY.
WM.
RTF.
AAC, APD, ARC, DRW, GLY, HDG, PCS, TCH.
AAC, APD, ARC, DRW, GLY, HDG, PCS, TCH.
AAC, APD, GLY, HDG, TCH.
AAC, APD, ARC, DRW, GLY, HDG, PCS.
APD, TCH.
AAC, APD, GLY, PCS, TCH.
AAC, APD, DRW, GLY, HDG, PCS, TCH.
APD.
APD.
APD.
APD, TCH.
APD.
APD.
APD.
SNW.
APD.
APD, RTF.
APD.
APD.
APD.
APD.
APD.
ARC, EMR, HUM.
EMR.
EFH, HAL.
ARC, CCW, CLl, GLY, HAL, KNP, PCS, VND, WM.
WM.
SURFACE -ACTIVE AGENTS
191
TABLE 2. --Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers ' identification codes
(according to list in table 3)
Non-tonic Surface-Active Agents --Continued
*Carboxylic acid esters--Continued
*Glycerol esters:
*Complex glycerol esters;
Glycerol ester ethoxylated
Glycerol lactate esters of fatty acids
Glycerol lactate stearate
Glycerol maleate mono-oleate
Glycerol mannitan laurate
Glycerol monoester of mixed fatty acids,
acetylated.
Glycerol mono-oleate, acetylated
Glycerol monostearate, ethoxylated
Glycerol monostearate, succinylated
*Glycerol esters of chemically defined acids:
Glycerol dioleate
*Glycerol distearate
Glycerol monocaprylate
*Glycerol monolaurate
* Glycerol mono-oleate
Glycerol monoricinoleate
'Glycerol monostearate
'Glycerol esters of mixed acids :
Glycerol diester of lard acids
Glycerol monoester of Coconut oil acids
Glycerol monoester of corn oil acids
Glycerol monoester of cottonseed oil acids
'Glycerol monoester of hydrogenated cottonseed
oil acids.
'Glycerol monoester of hydrogenated soybean oil
acids.
Glycerol monoester of hydrogenated tallow acids-
Glycerol monoester of lard acids
Glycerol monoester of peanut oil acids
Glycerol monoester of tall oil acids
All other
'Natural fats and oils, ethoxylated:
'Castor oil, ethoxylated
Corn oil, ethoxylated
Hydrogenated castor oil, ethoxylated
'Lanolin, ethoxylated
Tallow, ethoxylated
'Polyethylene glycol esters:
'Polyethylene glycol esters of chemically defined
acids:
'Polyethylene glycol dilaurate
'Polyethylene glycol dioleate
Polyethylene glycol distearate
Polyethylene glycol methylcarbitol maleate
Polyethylene glycol monocaprylate
'Polyethylene glycol monolaurate
'Polyethylene glycol mono-oleate
Polyethylene glycol mono-oleate, ethoxylated
GLY.
GLD.
APD, PCS.
DA.
GLY.
EKT, WTC.
TCH.
EKT.
ARC, HAL.
APD, APX, ARC, WTC.
ARC, DRW.
ARC, GLY, HAL.
APD, CCW, DRW, EFH, EKT, EMR, GLY, HAL, HDG, PCS,
SWT, WM, WTC.
CCW, CGY, DA, GLY, HDG.
ARC, ASH, CHL, CHP, CRT, DRW, EFH, EMR, GLY, GRO,
HAL, HRT, LUR, PCS, PG, SOS, SWT, TCC, VND, WM, WTC, x.
VND, WM.
DRW, SWT.
TCH.
EKT.
GLD, LEV, WM.
ASH, DRW, EKT, GLD, NW, PCS.
PCS, SCT.
EKT, GLD.
DRW.
ARC, EFH.
APD, CGY, EKT, GLD, LEV.
AAC, APD, DA, DRW, GAF, GLY, NLC, NTL, PCS, RTF,
TCH, TMH.
TCH.
APD, DA, TCH.
AAC, APD, CRD, PCS.
DRW.
ARC, DA, DEX, EFH, GLY, HAL, HDG, JOR, PCS, WM.
ARC, CLD, DA, EFH, GLY, HAL, HDG, NLC, PCS, UVC,
VND, WM.
AAC, EFH, GLY, HAL, HDG, PCS, QCP.
CCA.
ECC.
AAC, ARC, CCA, DA, DEX, GLY, HAL, HDG, KNP, MCP, PCS,
TCH, UVC.
APD, ARC, CCA, CGY, CLD, CRT, DA, DEX, DRW, EFH, GAF,
GLY, HAL, HDG, ICI, ONX, PCS, TCH, UVC, VAC, WTC.
APD.
192
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.
-Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
Non-ionic Surface-Active ^g'ents- -Continued
*Carboxylic acid esters--Continued
'Polyethylene glycol esters--Continued
•Polyethylene glycol esters of chemically defined
acids --Continued
Polyethylene glycol monopalmltate
Polyethylene glycol monopelargonate
Polyethylene glycol monoricinoleate
•Polyethylene glycol raonostearate
Polyethylene glycol sesquioleate
All other
•Polyethylene glycol esters of rosin and tall oil
acids :
Polyethylene glycol diester of tall oil acids
•Polyethylene glycol monoester of tall oil acids —
Polyethylene glycol sesquiester of rosin acids
•Polyethylene glycol sesquiester of tall oil
acids.
•Polyethylene glycol esters of other mixed acids:
Polyethylene glycol diester of trimerized castor
oil acids.
Polyethylene glycol ester of palmitic and stearic
acids.
Polyethylene glycol monoester of coconut oil
acids.
Polyethylene glycol monoester of coconut oil
acids, ethoxylated.
Polyethylene glycol sesquiester of castor oil
acids.
•Polyethylene glycol sesquiester of coconut oil
acids .
Polyethylene glycol sesquiester of tallow acids
All other
•Polyglycerol esters:
Polyglycerol laurate
Polyglycerol lactate oleate
Polyglycerol mono-oleate
Polyglycerol monostearate
•Propanediol esters:
1,2 -Propanediol dioleate
1,2- Propanediol distearate
1,2- Propanediol monolaurate
1,2 -Propanediol mono-oleate
•1, 2 -Propanediol monostearate
All other
Miscellaneous carboxylic acid esters:
Anhydrosorbitol glycerol monolaurate
Ethoxylated glycerol sesquiester of mixed fatty
acids.
Ethoxylated 1 ,2-propanediol monostearate
Laurie acid esters of glycerol and ethoxylated
nonylphenol.
Methylglucoside laurate
Miscellaneous esters of stearic acid
Oleic acid esters of ethoxylated nonylphenol
Pentaerythritol distearate
APD.
EMR, TCH.
HAL, NTL, TCH, UVC .
AAC, AKS, AML, APD, ARC, CHP, CRT, DA, DEP, DEX, DRW,
EFH, EMR, GLY, HAL, HDG, HRT, KNP, ONX, PC. PCS, RH,
TCC, TCH, VND, WM, WTC.
EMR, PCS.
GAP.
EFH,
EFH,
HPC,
AML,
GLY
NLC,
QCP.
APD,
RTF, SOS, TCH.
ARC, DA, MON, SLM, OTC.
GLY.
MCP.
GLY.
APD.
ARC.
ARL,
DA,
MRT, PG, SCP, UVC, VND, W
SOS.
ARC,
VAC.
VND.
DRW.
HDG,
ASH,
PCS,
PCS.
VND.
HAL,
ARC.
ARC,
EFH,
APD,
ARC,
x.
HAL,
HAL.
ARC,
GLD.
SBC.
CCW, EKT, GLD, GLY, HAL.
APD.
APD.
APD.
TCC.
HDG.
EMR.
EFH.
EMR,
GLY
VAL.
SURFACE -ACTIVE AGENTS
193
TABLE 2. --Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers ' identification codes
(according to list in table 3)
Nonionio Surface-Active Agents- -Conti.misi
*Carboxylic acid esters — Continued
Miscellaneous carboxylic acid esters — Continued
Pentaerythritol pelargonate
Polyalkylene glycol diglycolate
Polypropylene glycol mono-oleate
Polypropylene glycol mono-oleate, .propoxylated
Polypropylene glycol monostearate
Sucrose esters of fatty acids
All other
*Ethers:
*Benzenoid ethers:
Alkylphenol - formaldehyde condensates, alkoxylated:
p-tert-Butylphenol - formaldehyde condensate,
alkoxylated.
(Mixed alkyljphenol - formaldehyde, alkoxylated
Nonylphenol - formaldehyde, alkoxylated
tert-Octylphenol - formaldehyde condensate,
ethoxylated.
p-tert-Butylphenol , ethoxylated
Diisobutylphenol, ethoxylated
Dinonylphenol, ethoxylated
*Dodecylphenol, ethoxylated
Iso-octylphenol, ethoxylated
(Mixed alkyl5phenol, ethoxylated
(Mixed alkyl)phenoxypolyXethyleneoxy5 ethyl
chloride.
*Nonylphenol , ethoxylated
Nonylphenol, ethoxylated and propoxylated
Nonylphenoxypoly(ethyleneoxy) ethyl iodide
n-Octylphenol, ethoxylated
*Phenol, ethoxylated
Phenol, propoxylated
Tetradecylphenol, ethoxylated
Tridecylphenol, ethoxylated
Xylenol, ethoxylated
All other
*Nonbenzenoid ethers :
*Linear alcohols, alkoxylated:
*Decyl alcohol, ethoxylated
Decyl and octyl alcohols, ethoxylated
Decyl and octyl alcohols, ethoxylated and
propoxylated.
Decyloxypoly(ethyleneoxy) ethyl chloride
*Dodecyl alcohol, ethoxylated
Dodecyl alcohol, ethoxylated and propoxylated
*Hexadecyl alcohol, ethoxylated
*Mixed linear alcohols, ethoxylated
Mixed linear alcohols, ethoxylated, butyl ether —
Mixed linear alcohols, ethoxylated and
propoxylated.
*9-0ctadecenyl alcohol, ethoxylated
*Octadecyl alcohol, ethoxylated
Sperm oil alcohol, ethoxylated
EMR.
NLC.
HDG.
APD.
HDG.
sue.
CCW, STC, TCH, WM.
NLC.
NLC, RTF.
DA, SDW.
RTF.
GAF.
GAF, HDG, STP, TCH, VAC.
GAF, HON, PCS, TMH, UCC.
APX, DA, OMC, RH.
GAF.
GAF.
APD, CGY, CLY, DA, GAF, HDG, JCC, MON, NLC, OMC,
PCS, RH, RTF, STP, TCH, TMH, UCC, VAC.
RTF.
GAF.
TCH, TMH.
APD, DA, GAF, JCC, TCH, UCC.
ADP.
ORO.
PCS.
NLC.
DA, RH, VPC.
GAF, ICI, TCH.
GAF.
GAF.
GAF.
AAC, APD, DRW, GAF, HDG, OMC, RTF, SNW.
DUP.
AAC, APD, CGY, GLY, ICI.
AAC, CO, GAF, HDG, JCC, MON, NLC, RH, SEY, SHC, SNW,
STP, TCH, UCC, WTC.
TMH.
GAF, JCC, STP, WYN.
AAC, APD, ASH, CGY, DA, DUP, GAF, TCH, VPC.
APD, CGY, DA, DUP, GAF, HDG.
CRD, DUP.
194
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. --Surface-active agents for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers ' identification codes
(according to list in table 3)
Nonionia Surface-Active Agents - -Contir\nei
*Ethers- -Continued
*Nonbenzenoid ethers--Continued
*Linear alcohols, alkoxylated — Continued
Tallow alcohol, ethoxylated
Tetradecyl alcohol, ethoxylated
Tridecyl alcohol, ethoxylated
All other
*Other ethers and thioethers:
*Poly(ethylene and propylene) glycols :
PolyCmixed ethylene, propylene) glycol
Polypropylene glycol, ethoxylated
tert-Dodecyl mercaptan, ethoxylated
2-Ethylhexanol, ethoxylated
Glucose, ethoxylated
Glycerol, alkoxylated
Iso-octyl alcohol, ethoxylated
Methylglucoside, propoxylated
*Mixed alcohols, ethoxylated
Rosin, ethox)'lated
2,4,7,9-Tetramethyl-5-decyne-4,7-diol,
ethoxylated.
*Tridecyl alcohol, ethoxylated
Tridecyl alcohol, propoxylated and ethoxylated-
Trimethylheptanol, ethoxylated
Trimethylnonyl alcohol, ethoxylated
Trimethylolpropane, alkoxylated
All other
*Other nonionic surface-active agents:
3., 5 -Dimethyl- l-hexyn-3-ol
3,6-Dimethyl-4-octyne-4,7..diol
Dodecylbenzenesulfonic acid - diethanolamine
condensate, fatty acid monoester.
Glycerol sesquiester of hydrogenated castor oil
acids, borated and ethoxylated.
Octyl phosphate, ethoxylated
2,4,7,9-Tetramethyl-5-decyne-4,7-diol
Tri(castor oil alkyl)phosphate
Tr is (nonylphenyl) phosphite
All other
AAC,
JCC.
AAC.
AAC,
DUP.
RH.
NLC,
UCC,
VAC.
NLC,
RTF,
WYN.
AAC,
RTF,
UCC.
TCH.
RH.
NLC.
GAP.
STP.
DRW,
UCC,
VAC.
NLC.
cue.
AAC,
APD,
DRW, GAP,
GLY, ICI,
JCC,
MON,
NLC,
OMC, PCS
RTF, TCH, UCC.
JCC.
PCS.
HDG,
UCC.
HDC,
JFF,
RTF, WYN.
AAC,
NLC,
SNW.
cue.
cue.
ACT.
GLY.
DUP.
cue.
GLY.
GAP.
NLC.
SURFACE -ACTIVE AGENTS
195
TABLE 3. — Surface- active agents: Directory of manufacturers, 1970
ALPHABETICAL DIRECTORY BY CODE
[Names of manufacturers of surface-active agents that reported production or sales to the U.S. Tariff Commission for
1970 are listed below in the order of their identification codes as used in table 2]
Code
Code
identi-
Name of company
identi-
Name of company
fication
fication
AAC
Alcolac Chemical Corp.
EGG
Eastern Color 6 Chemical Co.
ACE
Acme Chemical Co.
EFH
E. F. Houghton § Co.
ACS
Allied Chemical Corp., Specialty Chemicals
EKT
Eastman Kodak Co., Tennessee Eastman Co. Div.
Div.
EMK
Eipkay Chemical Go.
ACT
Arthur C. Trask Co.
EMR
Emery Industries, Inc.
ACY
American Cyanamid Co.
ENO
Enenco, Inc.
AES
Amerace-Esna Corp., Chemical Specialties
Div.
Armour-Dial, Inc.
ESS
Essential Chemicals Corp.
AGP
FIN
Fine Organics, Inc.
AKS
Arkansas Co . , Inc .
AML
Amalgamated Chemical Corp.
GAP
GAF Corp . :
APD
Atlas Chemical Industries, Inc.
Chemical Div.
APX
Apex Chemical Co., Inc.
Textile Chemical Div.
ARC
Armour S Co., Armour Industrial Chemical
GLD
SCM Corp., Glidden-Durkee Div.
Go.
GLY
Glyco Chemicals, Inc.
ARD
Ardmore Chemical Co.
GNM
General Mills Chemicals, Inc.
ARL
Arol Chemical Products Go.
W.R. Grace 5 Co.:
ASH
Ashland Oil, Inc., Ashland Chemical Co. Div.
GRG
Dubois Chemicals Div.
ASY
American Synthetic Rubber Corp.
GRD
Polymer 6 Chemicals Div.
ATR
Atlantic Richfield Co., ARCO Chemical Co.
GRL
Vestal Laboratories Div.
Div.
GRO
Millmaster Onyx Corp., A. Gross 5 Go. Div.
GYR
Goodyear Tire S Rubber Co.
BAO
Bayoil Co. , Inc.
BLA
Astor Products, Inc., Blue Arrow Div.
HAL
G. P. Hall Co. of Illinois
BLS
Beech-nut, Inc.
HDG
Hodag Chemical Corp.
BRD
Baird Chemical Industries, Inc.
HEW
Hewitt Soap Co.
BSW
Original Bradford Soap Works, Inc.
HK
Hooker Chemical Corp.
HLI
Haag Laboratories, Inc.
CCA §
Cincinnati Melacron Chemicals, Inc.
HMP
W. R. Grace § Co.. Hampshire Chemical Div.
CCW
HNT
Huntington Laboratories, Inc.
CCL
A. E. Staley Manufacturing Co., Charlotte
HPC
Hercules, Inc.
Chemicals Labs., Textile Div.
HRT
Hart Products Corp.
CGY
Ciba-Geigy Corp. :
Giba Pharmaceutical Go.
HUM
Krafto Corp., Humko Products Div.
CHL
Ghemol, Inc.
IGI
ICI America, Inc.
CHP
C. H. Patrick § Co., Inc.
CLD
Colloids, Inc.
JCG
Jefferson Chemical Co., Inc.
CLl
Glintwood Chemical Co.
JOR
Jordan Chemical Co.
CLY
W. A. Cleary Corp.
JRG
Andrew Jergens Co.
CO
Continental Oil Go.
COM
Commercial Solvents Corp.
KAL
Kali Manufacturing Co.
CON
Concord Chemical Co., Inc.
KNG
Far-Best Corp., 0. L. King Div.
CP
Colgate-Palmolive Go.
KNP
Knapp Products, Inc.
CPP
Charmin Paper Products Co.
CRD
Croda, Inc.
LAK
Lakeway Chemical Co.
CRT
Crest Chemical Corp.
LEA
Leatex Chemical Co.
CRZ
Grown Zellerbach Corp., Chemical Products
LEV
Lever Brothers Go .
Div.
LIL
Eli Lilly § Go.
GST
Charles S. Tanner Co.
LKY
Lake State Div. of St. Regis Paper Co.
CTL
Continental Chemical Co.
LMI
North American Chemical Co.
CTN
Ghemetron Corp., Organic Chemical Div.
LUR
Laurel Products Corp.
cue
Air Reduction Co., Inc., Chemical §
Plastics Div.
MAL
Mallinckrodt Chemical Works
CWP
Consolidated Papers, Inc.
MAR
American Can Co.
MCP
Moretex Chemical Products, Inc.
DA
Diamond Shamrock Corp.
MIR
Miranol Chemical Co., Inc.
DAN
Dan River Mills, Inc.
MOA
Mona Industries, Inc.
DCP
Dixie Chemical Products, Inc.
MON
Monsanto Go.
DEP
DePaul Chemical Co., Inc.
MRA
Crown-Metro, Inc.
DEX
Dexter Chemical Corp.
MRD
Marden-Wild Corp.
DOW
Dow Chemical Go.
MRT
Morton Chemical Co.
DRW
Drew Chemical Corp.
MRV
Marlowe-Van Loan Corp.
DSO
DeSoto, Inc.
MYW
Stepan Chemical Co., Maywood Div.
DUP
E . I . duPont de Nemours 6 Co . , Inc .
DYS
Davies- Young Co.
196
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 3. --Surface-active agents: Directory of manufacturers, 1970— Continued
Name of company
Code
identi-
fication
Name of company
Nostrip Chemical Works, Inc.
Nease Chemical Co., Inc.
Nalco Chemical Co.
National Milling 8 Chemical Co., Inc.
Safeway Stores, Inc., Brookside Div.
National Lead Co.
Northwestern Chemical Co.
Olin Corp.
Millmaster Onyx Corp., Onyx Chemical Co.
Chevron Chemical Co.
Proctor Chemical Co., Inc.
Peerless Chemical Co.
Pioneer Chemical Works, Inc.
Emery Industries, Inc.
Peck's Products Co.
Pfizer, Inc.
Procter 5 Gamble Co.
Pilot Chemical Co.
Plex Chemical Corp.
Murphy-Phoenix Co.
Purex Corp. , Ltd.
Georgia-Pacific Corp., Bellingham Div.
Puritan Chemical Co.
Quaker Chemical Corp.
ITT Rayonier, Inc.
Roberts Chemical Div. of Security
Chemicals, Inc.
Richardson Co.
Rohm & Haas Co.
Robeco Chemicals, Inc.
Millmaster Or.yxCorp., Refined-Onyx
Div.
Ritter Chemical Co., Inc.
Retzloff Chemical Co.
SandoZjInc, Sandoz Colors S Chemical
Div.
Scher Bros. , Inc.
Sugar Beet Products Co.
Scholler Bros., Inc.
Standard Chemical Products, Inc.
Sucrist Corp.
Martin-Marietta Corp., Southern
Dyestuff Co. Div.
Sterling Drug, Inc. :
Hilton-Davis Chemical Co. Div.
Winthrop Laboratories Div.
Seaboard Chemicals, Inc.
Seydel-Woolley 8 Co.
Stauffer Chemical Co., Specialty
Chemical Div.
Shell Oil Co., Shell Chemical Co.
Div.
SHP
SID
SLC
SLM
SMC
SNC
SNW
SOC
SOP
SOS
SPA
STC
STP
SUG
SWT
TCC
TCH
TCI
TEN
TMH
TNA
TNI
TRC
TXC
TXN
TXT
UCC
UDI
UNN
UNP
USR
UVC
VAC
VAL
VND
VPC
WAW
WAY
WBG
WHI
WHW
WIC
WON
WSN
WTC
WVA
Shepherd Chemical Co.
George F. Siddall Co., Inc.
Soluol Chemical Co., Inc.
Salem Oil § Grease Co.
Stamford Chemical Industries, Inc.
Sonoco Products Co.
Sun Chemical Corp., Chemicals Div.
Standard Oil Co. of California,
Chevron Chemical Co.
Southern Chemical Products Co.
Southern Sizing Co.
Scott Paper Co.
Sou-Tex Chemical Co., Inc.
Stepan Chemical Co.
Colonial Sugars Co.^Sucro Chemical Div.
Swift 5 Co., Swift Chemical Co. Div.
Tanatex Chemical Corp.
Try Ion Chemical Corp.
Texize Chemicals, Inc.
Cities Service Co., Copperhill Operations
Thompson-Hayward Chemical Co.
Ethyl Corp.
Gillette Chemical Co. Div. of Gillette Co.
Toms River Chemical Corp.
Tex Chem Co.
Textilana-Nease, Inc.
Textilana Corp.
Union Carbide Corp.
Petrochemicals Co., Inc.
United Chemical Corp. of Norwood
United Chemical Products Corp.
Uniroyal, Inc., Chemical Div.
Universal Chemicals Corp.
Northern Petrochemical Co.
Valchem
Van Dyk § Co. , Inc.
Verona Corp.
W. A. Wood Co.
Philip A. Hunt Chemical Corp., Wayland
Chemical Div.
White 6 Bagley Co.
White 5 Hodges, Inc.
Whittemore-Wright Co., Inc.
Wica Chemicals, Inc.
Wilson Pharmaceutical S Chemical Corp.,
Wilson-Martin Div.
Woonsocket Color § Chemical Co.
Mallinckrodt Chemical Works, Washine Div.
Witco Chemical Co., Inc.
Westvaco Corp., Chemicals Div., Polychemicals
Dept.
BASF-Wyandotte Chemicals Corp.
Note. --For complete
3S and addresees of the above reporting companies, refer to table 1 in the Appendix.
PESTICIDES AND RELATED PRODUCTS 197
Pesticides and related products include fungicides, herbicides,
insecticides, rodenticides, and related products such as plant hormones,
seed disinfectants, soil conditioners, soil fumigants and synergists.
The data are given in terms of 100-percent active material; they thus
exclude such materials as diluents, emulsifiers, and wetting agents.
U.S. production of pesticides and related products in 1970 amounted
to 1,034 million pounds--6.4 percent less than the 1,104 million pounds
reported for 1969 (table 1)^. Sales in 1970 were 881 million pounds,
valued at $870 million, compared with 929 million pounds, valued at $851
million, in 1969.
The output of cyclic pesticides and related products amounted to
727 million pounds in 1970--about 11.3 percent less than the 819 mil-
lion poimds produced in 1969. Sales in 1970 were 602 million pounds,
valued at $702 million, compared with 666 million pounds, valued at
$697 million, in 1969. The output of DDT amounted to 59 million pounds
in 1970--the lowest since 1949. Production of acyclic pesticides and
related products, increased in 1970 amounting to 307 million pounds,
compared with the 285 million pounds reported for 1969. Sales in 1970
were 279 million pounds an increase of about 6.3 percent as compared
with 263 million pounds in 1969; the value of sales increased to $169
million in 1970, compared with $154 million in 1969--a gain of 9.6 per-
cent.
See also table 2 which lists these products and identifies the
manufacturers by code. These codes are given in table 3.
198
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. — Pesticides and related products: U.S. production and sales , 1970
[Listed below are all pesticides and related products for which any reported data on production or sales may be pub-
lished. (Leaders are used where the reported data are accepted in confidence and may not be published or where no
data were reported.) Table 2 lists all pesticides and related products for which data on production or sales were
reported and identifies the manufacturers of each]
Quantity
Grand total
Benzenoid
Nonbenzenoid
PESTICIDES AND RELATED PRODUCTS, CYCLIC
Total
Fungicides, total
3,S-Dimethyl-l,3,5-2H-tetrahydrothiadiazine-2-thione (DMTT)---
Mercury fungicides, total
Phenylmercuric acetate (PMA)
Other mercury fungicides
Naphthenic acid, copper salt
Pentachlorophenol (PCP)
8-Quinolinol (8-Hydroxyquinoline) , copper salt
All other cyclic fungicides^
Herbicides and plant hormones, total
l,2-Dihydropyridazine-3,6-dione (Maleic hydrazide) (MH)
Phenoxyacetic acid derivatives :
2,4-Dichlorophenoxyacetic acid (2,4-D)
2,4-Dichlorophenoxyacetic acid esters and salts, total
2,4-Dichlorophenoxyacetic acid, n-butyl ester
2,4-Dichlorophenoxyacetic acid, sec-butyl ester
2,4-Dichlorophenoxyacetic acid, dimethylamine salt
2,4-Dichlorophenoxyacetic acid, iso-octyl ester
2,4-Dichlorophenoxyacetic acid, isopropyl ester
All other (2,4-D) esters and salts
2,4,S-Trichlorophenoxyacetic acid, esters, and salts, total-
2,4,5-Trichlorophenoxyacetic acid, iso-octyl ester
All other C2,4,S7T) esters and salts
2-(2,4,5-Trichlorophenoxy)propionic acid (Silvex), and esters-
All other cyclic herbicides and plant hormones'
Insecticides and rodenticides, total
Aldrin-toxaphene group''
a-Bis (p-chlorophenyl)-B,6,6-trichloroethane (DDT)
Organophosphorus insecticides, total
0,0-Diethyl O-p-nitrophenyl phosphorothioate (Parathion)
0,0-Dimethyl O-p-nitrophenyl phosphorothioate (Methyl
parathion)
All other organophosphorus insecticides^
All other insecticides and rodenticides^
PESTICIDES AND RELATED PRODUCTS, ACYCLIC
Total
Fungicides , total
Dithiocarbamic acid salts'
All other acyclic fungicides'
Herbicides and plant hormones, total
Methanearsonic acid salts^
All other acyclic herbicides '°
1,000
pounds
1.034.075
579,414
454,661
727,133
95,762
1,218
1,571
457
1,114
1,730
47,170
71
44,002
3,271
43,576-
878
6,740
19,499
9,989
1,001
12,335
2,142
10,193
2,016
231,021
301,045
88,641
59,316
77,236
15,259
41,353
20,624
75,852
506,942
44,397
39,381
5,016
73,458
30,454
43,004
1,000
pounds
1,000
dollars
497,365
383,549
601,755
513,087
357,227
701,558
1,117
631
1,625
5,902
301
2,003
1,324
3,899
1,795
529
45,832
6,371
68
120
33,028
25,470
246,534
449,026
3,096
15,783
43,917
1,454
3,931
19,480
7,387
1,078
10,587
7,214
7,214
1,407
175,117
271,756
5,247
4,136
13,140
479
1,023
5,350
2,474
324
3,490
5,347
5,347
1,474
419,682
213,509
84,225
34,019
75,055
15,504
39,869
19,682
78,457
43,159
5,351
78,204
7,672
19,173
51,359
86,795
40,013
5,381
18,998
7,157
24,521
37,057
8,028
40,900
See footnotes at end of table.
PESTICIDES AND RELATED PRODUCTS
TABLE 1.-- Pesticides and related products: U.S. production and sales, 1970— Continued
199
Production
Quantity
Unit
value'
PESTICIDES AND RELATED PRODUCTS, ACYCLIC--Continued
Insecticides, rodenticides, and soil conditioners and
fumigants, total
Methyl bromide (Bromoethane)
Organophosphorus insecticides
All other acyclic insecticides (including sales of acyclic
organophosphorus insecticides), rodenticides, and soil
conditioners and fumigants'^ '^
1,000
pounds
189,087
1,000
1,000
dollars
Per
■pound
21,047
55,260
112,780
21,790
150,397
8,764
84,909
.56
' Calculated from rounded figures .
^ Includes benomyl, captafol, captan, dinocap, folpet, pentachloronitrobenzene, sodium pentachlorophenate, tri-
and tetra-chlOTophenols, (including 2,4,5-trichlorophenol and its salts) and others.
' Includes acetanilide compounds, amiben esters and salts, barban, benefin, bensulide, other 2,4-D esters and
salts (production only), dicaniba, dimethylurea compounds, dinitrophenol compounds, endothal, isopropyl phenylcarbamates
(IPC and CIPC), MCPA, mollinate, NPA, picloram, propanil, triazines, trifluralin, uracils, and others.
"* Includes aldrin, chlordan, dieldrin, endrin, heptachlor, and toxaphene.
Includes azinphosmethyl, carbophenothion, coumaphos, diazinon, dioxathion, fensulfothion, ronnel, and other
phosphorothioates and phosphorodithioates, and others.
Includes carbofuran, chlorobenzilate
late, dicofol, endosulfan, methoxychlor , and other chlorinated insecticides,
carbaryl, insect attractants, DEET and other insect repellents, lindane, small amounts of rodenticides, piperonyl
butoxide and other synergists , and others .
' Includes ferbam, maneb, metham, nabam, and zineb, plus the remaining dithiocarbamates which are used chiefly as
pesticides .
' Includes dodine, mercury compounds, PETD, and others.
' Includes the mono- and di-sodium salts, and the dodecyl- and octyl-ammonium salts of methanearsonic acid.
'" Includes cacodylic acid, CDAA, dalapon, thiocarbamate, thiolcarbamate, and organophosphorus herbicides, sodium
TCA, and others .
'' Includes DDVP, dimethoate, disulfoton, ethion, malathion, monocrotophos , naled, phorate, and other organophos-
phorus insecticides. Sales are included in the data for all other acyclic insecticides.
'^ Includes DBCP, soil conditioners and fumigants, metaldehyde (which is a molluscicide) , small quantities of
rodenticides, and others.
' Sales of acyclic organophosphorus insecticides are included with "All other acyclic insecticides" in order to
establish an all other acyclic insecticide total without disclosing the operations of individual companies.
Note. --In order to expedite the release of this report, it was necessary to estimate the data for two small pest-
icide producers and to partially estimate the data for one large producer. Therefore, minor revisions may be nec-
essary for the 1970 final report.
200
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. --Pesticides and related products for which U.S. production or sales were reported,
identified by manufacturer, 1970
[Pesticides and related products for which separate statistics are given in table 1 are marked below with an
asterisk (*); chemicals not so marked do not appear in table 1 because the reported data are accepted in
confidence and may not be published. Manufacturers' identification codes shown below are taken from table 3]
Manufacturers' identification codes
(according to list in table 3)
PESTICIDES AND RELATED PRODUCTS, CYCLIC
♦Fungicides :
2-Benzothiazolethiol , zinc salt
2, 6 -Bis (dime thy laminomethyl)cyclohexanone
2' -Bromo-4' -hydroxy acetophenone
5-Chloro-2-benzothiazolethiol, laurylpyridinium salt —
Cyanomethylthiobenzothiozole
2,4-Dichloro-6- (o-chloroanilino)-s-triazine
l,4-Dichloro-2,5-dimethoxybenzene (Chloroneb)
2,6-Dichloro-4-nitroaniline (DCNA)
*3,S-Diraethyl-l,3,5,2H-tetrahydrothiadiazine-2-thione
(DMTT)
Diphenyl ammonium propionate
2-Heptadecy 1-2 -imidazoline (Glyodin)
2-Mercaptobenzothiazole, monoethanolamine salt
*Mercury fungicides:
N- (Ethylmercuri)-p-toluene sulfonanilide
Hydroxymercur i ch loropheno 1
Methylmercury quino lino late
2- (Phenylmercuriamino)ethyl acetate
*Phenylmercuric acetate (PMA)
Phenylmercuric ammonium acetate
Phenylmer curie dimethyldithiocarbamate
Phenylmercuric hydroxide .
Phenylmercuric lactate
Phenylmercuric naphthonate
Phenylmercuric oleate
Pheny Imercur i c propionate
Tris (2-hydroxyethyl) (phenylmercuri) ammonium lactate--
All other mercury fungicides
Methyl -N-benzimidazol-2-yl-N-(butylcarbonioyl J car-
bamate (Benomyl)
2- (l-Methyl-n-heptyl)-4,6-dinitrophenyl crotonate
(Dinocap)
3- (2-Methylpiperidino)propyl-3,4-dichlorobenzoate
(Piperalin)
*Naphthenic acid, copper salt
Pentachloronitrobenzene (PCNB)
* Pent ach loropheno 1 (PCP)
Pentach loropheno 1, sodium salt
*8-Quinolinol (8-Hydroxyquinoline) , copper salt
N-(l ,1 ,2,2-Tetrachloro-ethylsulfenyl)-cis-A-4-cyclo-
hexene-l,2-dicarboximide (Captafol)
2,4,5,6-TetrachloroisophthD-lonitrile
2,3,4,6-Tetrachlorophenol
N-Trichloromethylthio-4-cyclohexene-l ,2-dicarboximide
(Captan)
N-Trichloromethylthiophthalimide (Folpet)
2,4,5-Trichlorophenol acid and salts:
2 , 4 , 5-Tri ch loropheno 1
2,4,S-Trichlorophenol, ethanolamine salt
2,4,S-Trichlorophenol, sodium salt
2, 4, 6-Trich loropheno 1
'Herbicides and plant hormones:
4-Amino-3,S,6-trichloropicolinic acid (Picloram)
5-Bromo-3-sec-butyl-6-methyluracil (Bromacil)
3-tert-Butyl-5-chloro-6-methyluracil
N-Butyl-N-ethyl-a,a,a-trif luoro-2,6-dinitro-p-toluidine
(Benefin)
2-Butynyl-4-chloro-m-chlorocarbanilate (Barban)
2-Chloro-4,6-bis(ethylamino)-s-triazine (Simazine)
2-Chloro-4,6-bis (isopropylamino)-s-triazine (Propazine)
VNC.
MRK.
BKM.
VNC.
BKM.
CHG.
DUP.
UPJ.
MRK, OTC, SF, WRC.
MRK.
UCC.
VNC.
DUP.
DUP.
MRK.
CLY.
BKM,
MAL,
WRC.
MRK.
MRK,
MRK.
CLY,
MRK.
CLY.
MAL.
CLY, MRK, TRO, WRC.
TRO.
UCC.
HNX, TRO, IVRC.
DUP.
RH.
LIL.
CCA, PER, HNX, MCI, SHP , TRO, WTC.
OMC,
DOW, FRO, MON, RCI, SFD.
DOW, MON, RCI.
FIS, HNX, MRK.
ORG.
DA.
DOW.
SF.
DOW, HK, HPC.
GAF.
DOW.
DOW.
DOW.
DUP.
DUP.
LIL.
GOC.
CGY.
CGY.
PESTICIDES AND RELATED PRODUCTS
201
TABLE 2.-
- Pesticides and related products for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers ' identification codes
(according to list in table 3)
PESTICIDES AND RELATED PRODUCTS, CYCLIC--Continued
*Herbicides and plant hormones --Continued
2-Chloro-2 ' ,6 ' -diethyl-N- Cra-butoxymethy 1) acetanilide
2-Chloro-2' ,6 '-diethyl-N- (methoxymethylj acetanilide
(Alachlor)
2-Chloro-4-ethylainino-6-isopropylainino-s-triazine
CAtrazine)
2-Chloro-N-isopropyl acetanilide (Propachlor)
N'-(4-Chlorophenoxy)phenyl N,N-diinethylurea
(Chloroxuron)
3-Cp-Chlorophenyl3-l,l-dimethylurea (Monuron)
3-{p-Chlorophenyl)-l,l-diiiiethylurea trichloroacetate
3-Cyclohexyl-5,6-trimethyleneuracil
2,6-Di-tert-butyl-p-tolylmethylcarbamate
2,S-Dichloro-3-ajninobenzoic acid, ammonium salt
2,5-Dichloro-3-aminobenzoic acid, iminodi-2,2 '_
ethanol
2,5-Dichloro-3-aminobenzoic acid, methyl ester
3,6-Dichloro-2-anisic acid (Dicamba)
2,4-Dichlorobenzyltributylphosphonium chloride
2,5-Dichloro-3-nitrobenzoic acid
2,5-Dichloro-3-nitrobenzoic acid, ammonium hydroxide
2,5-Dichloro-3-nitrobenzoic acid, ethyl ester
2,5-Dichloro-3-nitrobenzoic acid, methylainine salt
3- (3,4-Dichlorophenyl)-l ,1-dimethylurea (Diuron)
3- (3,4-Dichlorophenyl5 -1-methoxy-l-methylurea (Linuron}
2,4-Dichlorophenyl-4-nitrophenyl ether
3' ,4'-Dichloropropionanilide (Propanil)
*l,2-Dihydropyridazine-3,6-dione (Maleic hydrazide) (MH)
N- (beta-0,0-Diisopropyl-dithiophosphorylethyl) -benzene
sulfonamide CBensulide)
N,N-Dimethyl-2,2-diphenylacetamide (Diphenamid)
l,l-Dimethyl-3-phenylurea (Fenuron)
Dimethyl-2,3,5,6-tetrachloroterephthalate (DCPA)
Dinitrobutylphenol (DNBP)
Dinitrobutylphenol, ammonium salt
Dinitrobutyl phenol, triethanolamine salt
Dinitrocresol, sodium salt
2,4' -Dinitro-4-trif luoromethyl-diphenyl ether
(Fluorodifen)-T
2-Ethylamino-4-isopropylaniino-6-methylmercapto-s-
triazine (Aroetryne)
S-Ethyl cyclohexylethylthiocarbamate
S-Ethyl hexahydro-lH-azepine-1-carbothioate (Molinate)-
Gibberellic acid
3-(Hexahydro-4,7-methanoindan-5-yl5-l,l-dimethylurea
CNoreaJ
3-Indolebutyric acid
Isopropyl N- (3-chlorophenyl3 carbamate (CIPC)
Isopropyl N-phenylcarbamate CIPC)
1- C2-Methylcyclohexyl)-3-phenylurea (Siduron)
2-Methylmercapto-4,6-bis (isopropylamino)-s-triazine
(Prometryne)
■4-CMethylsulfonyl)-2,6-dinitro-N,N-dipropylaniline
(Nitralin)
1-Naphthaieneacetic acid and derivatives :
1-Naphthaleneacet amide
1-Naphthaleneacetic acid (NAA)
1-Naphthaleneacetic acid, sodium salt
N-1-Naphthylphthalamic acid (NPA)
7-Oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid, di-
sodium salt CEndothall^
Phenoxyacetic acid derivatives:
4-Chloro-2-methylphenoxyacetic acid (MCPA)
4-Chloro-2-methylphenoxyacetic acid, potassium salt —
*2,4-Dichlorophenoxyacetic acid (2,4-D]
CGY.
MON.
CGY.
DUP.
ACN.
DUP.
HPC.
AMC, GAP.
GAP.
GAP.
VEL.
SM.
GAP.
GAP.
GAP.
GAP.
DUP.
DUP.
RH.
MON, RH.
ACY, ASL, CHP, PMT, USR.
SP.
ARA, CWN, UPJ.
DUP.
DA.
DOW, PMN.
DOW, PMN.
DOW, PMN.
PMN.
CGY.
SP.
ABB, MRK.
HPC.
ARA.
PPG.
PPG.
DUP.
CGY.
SHC.
AMC.
AMC, THM.
AMC, BKL.
USR.
PAS.
CLY, RDA.
GTH.
DOW, HPC, MON, RDA.
302
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Pesticides and related products for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
PESTICIDES AND RELATED PRODUCTS, CYCLIC- -Continued
*Herbicides and plant hormones — Continued
Phenoxyacetic acid derivatives--Continued
*2,4-Dichlorophenoxyacetic acid esters and salts:
2,4-Dichlorophenoxyacetic acid, 2-butoxyethyl ester
2,4-Dichlorophenoxyacetic acid, butoxyrjolypropylene'
glycol ester
*2,4-Dichlorophenoxyacetic acid, n-butyl ester
*2,4-Dichlorophenoxyacetic acid, sec-butyl ester
*2,4-Dichlorophenoxyacetic acid, dimethylamine salt-
2,4-Dichlorophenoxyacetic acid, ethanolamine and
isoprop and amine salt
2,4-Dichlorophenoxyacetic acid, ethyl ester
2,4-Dichlorophenoxyacetic acid, 2-ethylhexyl ester-
*2,4-Dichlorophenoxyacetic acid, iso-octyl ester
*2 ,4-Dichlorophenoxyacetic acid, isopropyl ester
2,4-Dichlorophenoxyacetic acid, lithium salt
2,4-Dichlorophenoxyacetic acid, sodium salt
*2,4,5-Trichlorophenoxyacetic acid (2,4,5-T3
*2,4,5-Trichlorophenoxyacetic acid esters and salts:
2,4,S-Trichlorophenoxyacetic acid, amyl esters
2,4,S-Trichlorophenoxyacetic acid, 2-butoxyethyl
ester
2,4,5-Trichlorophenoxyacetic acid, butoxypoly-
propyleneglycol ester
2,4,5-Trichlorophenoxyacetic acid, n-butyl ester
2,4,5-Trichlorophenoxyacetic acid, sec-butyl ester-
2,4,5-Trichlorophenoxyacetic acid, 2-ethylhexyl
ester
*2,4,5-Trichlorophenoxyacetic acid, iso-octyl ester-
2,4,5-Trichlorophenoxyacetic acid, triethylamine
salt
Polychloro-tetrahydro-methanoindene CPolychlorodicyclo-
pentadiene) isomers
•2-(2,4,5-Trichlorophenoxy)propionic acid (Silvex^
*2- (2,4,5-Trichlorophenoxy)propionic acid esters and
salts:
2-(2,4,5-Trichlorophenoxy)propionic acid, 2-ethyl-
hexyl ester
2-(2,4,5-Trichlorophenoxy5propionic acid isooctyl
ester
a,a,a-Trif luoro-2 ,6-dinitro-N,N-dipropyl-p-toluidine
(Trifluralin)
3-Cm-Trif luoromethylphenyl)-l,l-dimethylurea
(Fluometuron)
Tris- (2,4-dichlorophenoxyethyl)phosphite (2,4-DEP)
Insect attractants and repel lants:
tert-Butyl 4 (or 5)-chloro-2-methylcyclohexanecarboxy-
late (Trimedlure)
N,N-Diethyltoluamide (DEET)
Di-n-propyl isocinchomeronate
*Insecticides :
3-sec-Amylphenyl-N-methylcarbamate (m-(l-Methylbutyl)-
phenyl methyl carbamate)
Bacillus thuringiensis
2-sec-Butyl-4,6-dinitrophenyl 3,3-dimethylacrylate
(Binapacryl)
2- (p-tert-Butylphenoxy)cyclohexyl-2 ' -propynyl sulfite--
Chlorinated insecticides:
*Aldrin-toxaphene group:
Heptachloro-tetrahydro-endo-methanoindene
(Heptachlor)
Hexachloro-epoxy-octahydro-endo-endo-dimethano-
naphthalene (Endrin)
Hexachloro-epoxy-octahydro-endo-oxo-diraethano-
naphthalene (Dieldrin)
AMC,
DOW,
RIV.
DOW.
AMC,
HPC,
MON,
PBI,
RIV,
DOW,
MON,
RDA.
AMC,
DOW,
HPC,
PBI,
RDA,
RIV,
TWH
DOW.
AMC.
HPC.
AMC,
DOW,
MON,
PBI,
RDA,
RIV.
TMH
AMC,
DOW,
HPC,
MON,
RIV.
GTH.
DOW.
DOW,
HPC,
MON.
HPC.
AMC,
DOW.
DOW.
HPC,
MON,
PBI,
RIV.
DOW.
HPC.
DOW,
MON,
PBI,
RIV,
TMH.
DOW, HPC, RIV.
VEL.
DOW,
HPC, TMH.
HPC.
RIV.
LIL.
CGY.
USR.
UOP.
HPC, PFZ.
MGK.
ORO, OTC.
ABB.
FMN .
USR.
VEL.
VEL.
SHC.
PESTICIDES AND RELATED PRODUCTS
203
TABLE 2. — Pesticides and related products for which U.S. production or sales were reported,
identified by manufacturer, 1970-- Continued
Manufacturers' identification codes
Caccordlng to list in table 3)
PESTICIDES AND RELATED PRODUCTS. CYCLIC--Continued
'Insecticides — Continued
Chlorinated insecticides --Continued
*Aldrin-toxaphene group- -Continued
Hexachloro-hexahydro-endo-exo-diraethanonaphthalene
(Aldrin)
Oct ach loro-hexahydro-methanoindene (Chlordan)
Toxaphene (Chlorinated camphene)
2,2-Bis(p-chlorophenyl)-l,l-dichloroethane (DDD) CTDE)
1,1- Bis Cp-chlorophenyl)-2-nitrobutane
1,1 -Bis (p-chlorophenyl)-2-nitropropane
*a-Bis(p-chlorophenyl)-6,6,S-trichloroethane (DDT)
2- {p-teTt-Butylphenoxy)i'sopropyl-2 '-chloroethyl
sulfite
p-Chlorophenyl 2,4,5-trichlorophenyl sulfone
(Tetradifoh;i
Decachlorooctahydro-l,3,4-metheno-2H-cyclobuta[cd]-
pentalene-2-one
l,l-Dichloro-2,2-bis(p-ethylphenyl5ethane
4,4'-Dichloro-a-trichloroinethylbenzhydrol (Dicofol)
2,6-Dimethyl-3,5-dichloro-4-pyridinol
Dodecachlorooctahydro-1 ,3,4-metheno-2H-cyclobuta[cd]-
pentalene (Mirex)
Ethyl 4,4'-dichlorobenzilate (Chlorobenzilate)
Hexachlorocyclohexane (Benzene hexachloride) (BHC)
Hexachlorocyclohexane, 100% ■y-isomer (Lindane)
L^Hexachloro-hexahydro-methano-benzodioxathiepin
3-oxide (Endosulfan)
Isopropyl 4,4'-dichlorobenzilate (Chloropropylate)
1,1,1 -Tr ich loro-2 , 2 -bi s (p-raethoxypheny 1 ) ethane
(Methoxy ch lor)
2,3-Dihydro-2,2-dimethyl-7-benzofuranyl me thy 1-
carbamate (Carbofuran)
m- (l-Ethylpropyl)phenyl methylcarbaniate
Isobomyl thiocyanoacetate
0-Isopropylphenyl N-methylcarbamate
1-Naphthyl N-raethylcarbamate (Carbaryl)
*Organophosphorus insecticides :
4-tert-Butyl-2-chlorophenylmethyl methylphos-
phoramidite fCruf ornate)
S-[[ (p-Chlorophenyl)thio]methyl] 0,0-diethyl phosphoro
dithioate (Carbophenothion)
2-Chloro-l-(2,4,5-trichlorophenyl)vinyldiinethyl
phosphate
0,0-Diethyl 0-3-chloro-4-methyl-l-oxo-2H-l-benzopyran-
7-yl-phosphorothioate (Coumaphos)
0,0-Diethyl 0- (2-isopropyl-4-methyl-6-pyrimidinyl)
phosphorothioate (Diazinon)
0,0-Diethyl 0-p-(methylsulfinyl)phenyl phosphoro-
thioate (Fensulfothion)
*0,0-Diethyl 0-p-nitrophenyl phosphorothioate
(Parathion)
0,0-Diethyl 0-3,5,6-trichloro-2 pyridyl phosphoro-
thioate
0,0-Dimethyl 0-[4- (methylthio)-ni-tolyl] phosphoro-
thioate (Fenthion)
*0,0-Dimethyl 0-p-nitrophenyl phosphorothioate (Methyl
parathion)
0,0-Dimethyl S-[4-oxo-l,2,3-benzotriazin-3(4H)-
ylmethyl] phosphorodithioate (Azinphosmethyl)
0,0-Dimethyl S-phthalimidomethyl phosphorodithioate
Dimethyl 2,4,5-trichlorophenyl phosphorothionate
(Ronnel)
2,3-p-Dioxane S,S-bis(0,0-diethylphosphorodithioate)
(Dioxathion)
a-Methylbenzyl 3- (dimethoxyphosphinyloxy)-cis-
crotonate
0,0,0' ,0'-Tetramethyl O,0'-thiodi-p-phenylene phos-
phorothioate
SHC.
VEL.
HN, HPC, SFD.
ACN, RH.
COM.
COM.
ACN, DA, LEB, MTO, OMC .
USR.
FMN, FMP.
ACN.
RH.
RH.
DOW.
ACN.
CGY.
CGY.
CHF, DUP, NES.
FMN.
ORO.
HPC.
OTC.
UCC.
DOW.
SF.
SHC.
CHG.
CGY.
CHG.
AMP, MON, SF, SHC.
DOW.
CHG.
AMP, MON, SF, SHC, VEL.
CHG.
SF.
DOW.
HPC.
SHC.
ACY.
204
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. --Pesticides and related products for which U.S. production or sales were reported,
identified by manufacturer, 1970-- Continued
Chemical
Manufacturers' identification codes
(according to list in table 3)
PESTICIDES AND RELATED PRODUCTS, CYCLIC--Continued
* Insecticides --Continued
N-(Pheny 1-2 -nitropropyl) piper idine
m-Tolyl-N-methyl carbamate
Nematocides :
0,0-Diethyl 0- (2,4-dichlorophenyl) phosphorothioate
(Dichlofenthion)
0,0-Diethyl 0-2-pyrazinyl phosphorothioate (Thionazin) —
*Rodenticides :
3- (a-Acetonylben2yl)-4-hydroxycoumarin (Warfarin)
2-Diphenylacetyl-l ,3-indandione (Diphacinone)
S- (a-Hydroxy-a-2-pyridylbenzyl) -7- (a-2-pyridylbenzyl-
idene)-4-norbomene-2,3-dicarboxiiiiide (Norbormide)
2-Pivaloyl-l,3-indandione (Pindone)
Synergists and adjuvants:
a- [2- (2-ra-Butoxyethoxy)ethoxy]-4,5-methylenedioxy-2-
propyltoluene (Piperonyl butoxide)
N- C2-Ethylhexyl)-5-norbornene-2,3-dicarboximide
l,2-Methylenedioxy-4-[2-octylsulfinyl)propyl] benzene
Piperonal bis [2- (2 '-n-butoxyethoxy)ethyl]acetal
(Heliotropin acetal)
PESTICIDES AND RELATED PRODUCTS, ACYCLIC
*Fungicides :
2-Aininobutane carbonate
Bis-l,4-bromoacetoxy-2-butene
Cadmium succinate
l-Chloro-2-nitropropane (Korax)
Dimethylthiocarbonyl disulfide
Di sodium cyanodithioimidocarbonate
*Dithiocarbamic acid fungicides:
Dimethyldithiocarbamic acid, ferric salt (Ferbam)
Dimethyldithiocarbamic acid, manganese salt
Dimethyldithiocarbamic acid, potassium salt
Ethylene bis (dithiocarbaraic acid), diammonium salt
Ethylene bis (dithiocarbaraic acid) , disodium salt
(Nab am)
Ethylene bis (dithiocarbamic acid), manganese salt
(Maneb)
Ethylene bis (dithiocarbamic acid), zinc salt (Zineb) —
N-Methyldithiocarbamic acid, sodium salt (SMDC)
n-Dodecylguanidine acetate (Dodine)
2-Hydroxypropylmethanethio sulfonate
Mercury fungicides :
Chloromethoxypropylmercuric acetate
3-Methy 1 - (mercuri thi o) - 1 , 2 -propanedio 1
Methy Imercur i c hydroxide
Polyethylenethiuram disulfide (PETD)
'Herbicides and plant hormones:
2-Chloroallyl diethyldithiocarbamate (CDEC)
2-Chloro-N,N-diallyacetaraide (CDAA)
S-2,3-Dichloroallyl N,N-diisopropylthiol carbamate
(Dial late)
2,2-Dichloropropionic acid, sodium salt (Dalapon)
N-Dimethylamino succinaraic acid (DMSA)
Dimethylarsinic acid (Cacodylic acid)
Ethyl -N,N-diisobutyl thiol carbamate
Ethyl N,N-dipropylthiolcarbamate (EPTC)
Ethyl xanthogen disulfide (EXD)
*Methanearsonic acid salts:
Methanearsonic acid, disodium salt (DSMA)
Methanearsonic acid, dodecyl- and octyl- ammonium salts
Methanearsonic acid, monosodium salt (MSMA)
S-Propyl dipropylthiocarbamate (Vernolate)
S,S,S-Tributyl phosphorotrithioate
Tributyl phosphorotrithioite
MRK.
OTC.
MOT, PEN.
NES.
PM.
MOT, PIC.
ALP, BKL, FMN, FMP.
MGK.
PEN.
LIL.
VIN.
MAL.
FMN.
CLY.
BKM.
DUP,
FMN,
VNC, WRC
FMN.
BKM.
RBC.
FMN,
RH,
USR.
ALC,
DUP
RH.
DUP,
FMN
RH.
SF.
ACY.
BKM.
TRO.
DUP.
MRT.
FMN.
MON.
MON.
MON.
DOW.
USR.
ASL.
SF.
SF.
RBC.
ASL,
CLY
DA, VIN.
CLY,
VIN
ASL,
DA.
PESTICIDES AND RELATED PRODUCTS
205
TABLE 2.
--Pesticides and related products for which U. S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
PESTICIDES AND RELATED PRODUCTS, ACYCLIC- -Continued
♦Herbicides and plant hormones — Continued
Trichloroacetic acid, sodium salt (TCA)
S-2,3,-Trichloroallyl N,N-diisopropylthiolcarbamate
(Tri-allate)
* Insecticides :
2-(2-Butoxyethoxy)ethyl thiocyanate
Metaldehyde '
S-Methyl-N- [ (methylcarbamoyl)oxy]thioacetimidate
(Methomy 1 )
*Organophosphorus insecticides:
S-[1,2-Bis (ethoxycarbonyl)ethyl] 0,0-dimethyl phos-
phor odithioate (Malathion)
2-Carbomethoxy-l-propen-2yl dimethyl phosphate
(Mevinphos)
l-Chloro-diethylcarbamoyl-l-propen-2yl-dimethyl
phosphate (Phosphamidon)
l,2-Dibromo-2,2-dichloroethyl dimethyl phosphate
(Naled) ^-
0,0-Diethyl S-2- (ethylthio;) ethyl phosphorodithioate
(Disulfoton]
0,0-Diethyl S- Cethylthio^methyl phosphorodithioate
CPhorate}
3- (Dimathoxyphosphinyloxy)-N,N-dimethyl-cis-
crotonamide CDicrotophos)
0,0-Dimethyl 2,2-dichlorovinyl phosphate
(Dichlervos)
0,0-Dimethyl S-[2- (ethylsulfinyljethyllphosphoro-
thioate (Oxydemetonmethyl^
0,0-Dimethyl Cl-hydroxy-2 ,2,2-t^ichloroethyl5phos-
phonate CTrichlorfon)
0,0-Dimethyl S- (N-methylcarbamoylmethyl) phosphoro-
dithioate (Dimothoate]
Dimethyl phosphate of 3-hydroxy-N-methyl-cis-
crotonamide (Konocrotophos)
0,0,0' ,0'-Tetraethyl S,S'-methlene bisphosphoro-
dithioate (Ethion)
Tetraethyl pyrophosphate CTEPP)
Tetra-n-propyl dithiopyrophosphate
2-Thiocyanoethyl dodecanoate
All other
Nematocides :
0-Ethyl S,S-dipropyl phosphorodithioate
2-Methyl-2 (methylthiojpropionaldehyde 0- (methylcarba-
moyl)oxime (Aldicarb)
*Rodenticides : Sodium f luoroacetate
*Soil conditioners: Polyacrylonitrile, hydrolyzed,
sodium salt
*Soil fumigants:
l,2-Dibromo-3-chloropropane (DBCP)
1,3-Dichloropropene
1,3-Dichloropropene, 1,2-dichloropropane
♦Methyl bromide (Bromomethane)
Trichloronitromethane (Chloropicrin)
All other acyclic pesticides and related products
DOW.
MON.
RH.
COM.
DUP.
ACY.
SHC.
CGY, SM.
SHC.
CHG.
ACY.
SHC.
SHC.
CHG.
CHG.
ACY.
SHC.
FMN, FMP.
AMP.
SF.
RH.
BFG.
SM.
ucc.
RBC.
ACY.
AMP, BST, DOW, SHC.
DOW.
DOW, SHC.
AMP, DOW, GTL, MCH.
DOW, IMC.
GAF.
462-669 0-72-14
206
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 3. — Pesticides and related products: Directory of manufacturers, 1970
ALPHABETICAL DIRECTORY BY CODE
[Names of pesticides and related products manufacturers that reported production or sales to the U.S. Tariff
Commission for 1970 are listed below in the order of their identification codes as used in table 2]
Code
Code
identi-
Name of company
identi-
Name of company
fication
fication
ABB
Abbott Laboratories
MAL
Mallinckrodt Chemical Works
ACN
Allied Chemical Corp., Agricultural Div.
MCH
Michigan Chemical Corp.
ACY
American Cyanamid Co.
MCI
Mooney Chemical Corp.
ALC
Alco Chemical Corp.
MGK
McLaughlin, Gormley 5 King Co.
ALP
Alpha Laboratories, Inc.
MON
Monsanto Co.
AMC
Amchem Products, Inc.
MOT
Motomco, Inc.
AMP
Kerr-McGee Corp.
MRK
Merck § Co. , Inc.
ARA
Arapahoe Chemical Div. of Syntex Corp.
MRT
Morton Chemical Co.
ASL
Ansul Chemical Co.
MTO
Montrose Chemical Corp. of Calif.
BFG
B. F. Goodrich Co., B. F. Goodrich
Chemical Co. Div.
NES
Nease Chemical Co., Inc.
BKL
Millmaster Onyx Corp., Millmaster Chem-
ical Co. Div., Berkeley Chemical Dept .
OMC
Olin Mathieson Chemical Corp. and
Agricultural Div.
BKM
Buckman Labs . , Inc .
ORO
Chevron Chemical Co.
EST
Occidental Chemical Co.
OTC
Ott Chemical Co.
CCA
CGY
CHF
CHG
CIS
CLY
Cincinnati Milacron Chemicals, Inc.
Ciba-Geigy Corp. and
Ciba Agricultural Co.
Chemical Formulators, Inc.
Chemagro Corp.
Chemical Insecticide Corp.
W. A. Cleary Corp.
PAS
PBI
PEN
PFZ
PIC
PM
PPG
Pennwalt Chemicals Corp.
Gordon Corp.
CPC International, Inc., Penick Div.
Pfizer, Inc.
Pierce Organics, Inc.
Pitman-Moore, Inc.
PPG Industries, Inc.
COM
Commercial Solvents Corp.
RBC
Roberts Chemicals, Div. of Security Chemical,
CWN
Upjohn Co., Carwin Organic Chemicals
RCI
Inc.
Reichhold Chemicals, Inc.
DA
Diamond Shamrock Corp.
RDA
Rhodia, Inc.
DOW
Dow Chemical ''o.
RH
Rohm § Haas Co.
DUP
E. I. duPont de Nemours S Co. , Inc.
RIV
Riverdal? Chemical Co.
PER
Ferro Corp., Ferro Chemical Div.
SF
Stauffer Chemical Co., Agricultural Div.
PIS
Fisher Chemical Co., Inc.
SFD
Sonford Chemical Co.
FMC Corp . :
SHC
Shell Oil Co., Shell Chemical Co. Div.
FMN
Niagara Chemical Div.
SHP
Shepherd Chemical Co-
FMP
Organic Chemicals Div.
SM
Mobil Oil Corp., Mobil Chemical Co. Div.
,
FMr
Fairmount Chemical Co.
Industrial Chemical Div.
FRO
Vulcan Materials Co., Chemical Div.
THM
WM. T. Thompson Co., Thompson Chemicals
Div.
GAP
GAF Corp., Chemical Div.
TMH
Thompson-Hayward Chemical Co.
GOC
Gulf Oil Corp., Gulf Oil
Chemical Co. -United States
TRO
Troy Chemical Co.
GTH
Guth Chemical Co.
UCC
Union Carbide Corp.
GTL
Great Lakes Chemical Corp.
UOP
Universal Oil Products Co., UOP Chemical
Div.
Upjohn Co.
HK
Hooker Chemical Corp.
UPJ
HN
Tenneco Chemicals, Inc.:
USB
U.S. Borax Research Corp.
HNX
Nuodex Div.
USR
Uniroyal, Inc., Chemical Div.
HPC
Hercules, Inc.
VEL
Velsicol Chemical Corp.
IMC
International Minerals & Chemical Corp.
VIN
VNC
Vineland Chemical Co.
Vanderbilt Chemical Corp.
LEB
Lebanon Chemical Corp.
LIL
Eli Lilly S Co.
WRC
WTC
Wood Ridge Chemical Corp.
Witco Chemical Co., Inc.
For complete names and addresses of the above reporting companies, refer to table 1 in the Appendix.
MISCELLANEOUS CHEMICALS 207
The term miscellaneous chemicals comprises those synthetic organic
products that are not included in the use groups covered by the other
preliminary reports in the 1970 series. They include products that are
employed in a great variety of uses. The number of chemicals used ex-
clusively for only one purpose is not large. Among the products
covered are those used for gasoline and lubricating oil additives, paint
driers, photographic chemicals, tanning materials, flotation reagents,
refrigerants, textile polymers, sequestering agents, organic fertilizers,
antifreeze chemicals, solvents, and acyclic intermediates. Table 1 pre-
sents statistics on U.S. production and sales of miscellaneous chemicals
in as great detail as is possible without revealing the operations of
individual producers . ^
Production of miscellaneous cyclic and acyclic chemicals in 1970
totaled 79.3 bi?llion pounds, or 4.7 percent more than the output of
75.7 billion pounds reported for 1969. Sales of miscellaneous chemicals
in 1970 amounted to 36.0 billion pounds, valued at $4.1 billion, com-
pared with 34.8 billion pounds, valued at $4.0 billion, in 1969.
The total output of miscellaneous cyclic chemicals in 1970 was 1.7
billion pounds, or 10.5 percent less than the output of 1.9 billion pounds
reported for 1969. Sales in 1970 totaled 749 million pounds, valued at
$310 million, compared with 860 million pounds, valued at $325 million,
in 1969. In 1970 the most important groups of cyclic compounds were the
lubricating oil additives, the output of which was 380 million pounds, and
synthetic tanning materials, the output of which was 43 million pounds.
Total production of miscellaneous acyclic chemicals in 1970 was
77.6 billion pounds, or 5.1 percent more than the output of 73.8 billion
pounds reported for 1969. Sales in 1970 totaled 35.2 billion pounds,
valued at $3.8 billion, compared with 33.9 billion pounds, valued at
$3.7 billion, in 1969. The statistics for acyclic chemicals are grouped
primarily by chemical function. The order of precedence of these func-
tional groups is generally that used in naming and indexing chemical
compounds by Chemical Abstracts, but other important considerations are
comparability with other statistics and the need for groupings that will
not reveal the operations of individual producers.
In 1970, the most important groups of acyclic chemicals were the
halogenated hydrocarbons, the nitrogenous compounds, monohydric alcohols,
and aldehydes and ketones. Production of halogenated hydrocarbons, which
are used as solvents, intermediates, refrigerants, and aerosol propel lants,
totaled 18.7 billion pounds. The most important chemicals in this group
were dichloroethane (production of 7.5 billion pounds in 1970 compared with
^ See also table 2 which lists these products and identifies the
manufacturers by code. These codes are given in table 3.
208 SYNTHETIC ORGANIC CHEMICALS, 1970
6.0 billion pounds in 1969) and vinyl chloride (4.0 billion pounds
compared with 3.7 billion pounds). Output of nitrogenous compounds
totaled 12.7 billion pounds. The most important chemical in this group
was urea (used principally in fertilizers and as a feed additive), produc-
tion of which was 6.2 billion pounds in 1970, compared with 5.9 billion
pounds in 1969.
Monohydric alcohols, which are used largely as solvents and inter-
mediates, were the third largest group in 1970, with production of 11.4
billion pounds. The most important items in the group in terms of pro-
duction were synthetic methanol (4.9 billion pounds in 1970, compared
with 4.2 billion pounds in 1969), synthetic ethyl alcohol (2.0 billion
pounds in 1970, compared with 2.4 billion pounds in 1969) and isopropyl
alcohol (1.9 billion pounds in 1970, compared with 2.0 billion pounds in
1969). Aldehydes and ketones, which are also used largely as solvents
and intermediates, were the next largest group with production of 10.0
billion pounds. The most important items in this group in 1970 were
formaldehyde (4.4 billion pounds), acetaldehyde (1.6 billion pounds),
and acetone (1.6 billion pounds).
MISCELLANEOUS CHEMICALS
209
TABLE 1. --Miscellaneous chemicals: U.S. production and sales, 1970
[Listed below are all miscellaneous chemicals for which any reported data on production or sales may be published.
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data
were reported-) Table 2 lists all miscellaneous chemicals for which data on production or sales were reported
and identifies the manufacturer of each]
Quantity
Grand total
MISCELLANEOUS CHEMICALS, CYCLIC
Total
Benzoic acid, sodium salt
Benzoyl peroxide
Butyl benzoate
2,6-Di-tert-butyl-p-cresol :
Food grade
Tech
P"Dimethoxybenzene (Dimethyl ether of hydroquinone)
Enzymes
Flotation reagents
Gasoline additives^
Hexamethylenetetramine, tech
p-Hydroxybenzoic acid esters :
Methyl p-hydroxybenzoate (Methylparaben^
Propyl p-hydroxybenzoate (Propylparaben)
Lubricating oil and grease additives, total
Oil-soluble petroleum sulfonate, barium salt
Oil-soluble petroleum sulfonate, calcium salt
Oil-soluble petroleum sulfonate, sodium salt
All other
Morpholine
Naphthenic acid salts, total"* ^
Calcium naphthenate
Cobalt naphthenate
Lead naphthenate
Manganese naphthenate
Zinc naphthenate
All other
Photographic chemicals:
p-Diethylaminobenzenediazonium (p-Diazo-N,N-diethyl-
aniline), zinc chloride salt
p- [Ethyl (2-hydroxyethyl)amino]benzenediazonium
chloride
Pinene, (a- and B-)
Tall oil salts, total"*
Calcium tallate
Cobalt tallate
Iron tallate
Lead tallate
Manganese tallate
All other
Tanning materials, synthetic, total
2-Naphthalenesulfonic acid, formaldehyde condensate
and salts
All other
Textile chemicals
All other miscellaneous cyclic chemicals
1,000
pounds
79,257,419
1,705,018
11,876
6,311
3,140
7,192
18,841
163
(2)
6,779
30,299
76,625
840
312
380,025
16,894
167,116
58,376
137,639
21,204
25,272
1,820
3,412
14,363
1,958
1,192
2,527
8,273
684
2,145
188
4,162
815
279
43,272
39,873
3,399
2,494
980,704
1,000
pounds
35.997.692
1,000
dollars
4.096,583
749,112
11,422
6,232
2,156
6,932
16,842
25,043
36,890
820
292
213,961
30,978
182,983
19,855
21,103
1,774
3,485
10,504
1,759
3,581
57,624
8,300
717
2,198
160
4,022
849
354
40,501
1,591
279,448
3,379
5,717
460
3,624
8,573
17,037
5,639
1,258
559
5,647
45,290
6,434
5,710
509
1,716
2,020
474
991
8,007
183
965
35
767
204
911
1,462
150,552
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. — Miscellaneous chemicals: U.S. production and sales, 1970- -Continued
Sales
Quantity
1,000
MISCELLANEOUS CHEMICALS, ACYCLIC
Total
Cellulose Esters and Ethers
Total
Cellulose esters, total
Cellulose acetate
All other
Cellulose ethers, total
Sodium carboxymethylcellulose, 100%
All other^
Lubricating Oil Additives
Total
Phosphorodithioates (Dithiophosphates)
All other
Nitrogenous Compounds
Total'
Aery lonit rile
Amines, total
Butylamines, total
n-Butylamine, mono-
Di-n-butylamine
All other
Diethylenetriamine
Ethylamines:
Diethylamine
Ethylaraine, mono-
Triethyl amine
Ethylenediainine
1,6-Hexanediamine (Hexamethylenediamine)
Methylamines:
Dimethylamine
Methylamine, mono-
Trioethylamine
Propylamines:
Diisopropyl amine
Di-n-propylamine
Triethylenetetramine
All other
2- (2-Ajiiinoethy laraino) ethanol (Aminoethy lethanolamine) -
1, l'-Azobis£ormamide
2-Diraethylaminoethanol
Eruc amide
1,000
pounds
35,248,580
1,000
dollars
3,786, 213
1,107,530
989,421
820,392
169,029
117,909
64,876
53,033
436,864
98,796
338,068
12,708,990
1,039,257
975,289
17,213
2,073
2,662
12,478
8,795
28,069
62,062
613,439
78,283
28,676
25,454
1,237
7,674
13,159
91,228
8,710
3,147
2,473
207,649
207,649
112,431
65,235
47,196
25,723
135,475
7,475,514
547,124
275, 769
9,571
1,710
2,027
5,834
23,749
4,575
24,175
6,527
46,906
36,535
23,452
19,687
1,154
8,804
9,537
61,097
6,694
3,517
2,135
2,562
28,230
35,350
8,282
21,786
59,812
58,770
2,911
575
628
1,708
7,640
1,026
3,249
2,022
9,306
3,638
2,106
1,938
262
2,188
3,549
18,935
2,603
4,207
965
2,396
See footnotes at end of table.
MISCELLANEOUS CHEMICALS
TABLE 1.- -Miscellaneous chemicals: U.S. production and sales , 1970--Continued
211
Quantity
MISCELLANEOUS CHEMICALS, ACYCLIC— Continued
Nitrogenous Compounds--Continued
Ethanolamines, total
2-Aminoethanol (Monoethanolamine)
2,2'-Iminodiethanol (DiethanolamineJ
2,2' ,2' '-Nitrilotriethanol (Triethanolamine)
Nitriloacids and salts, total
(Diethylenetrinitrilojpentaacetic acid, potassium
salt
CEthylenedinitrilo)tetraacetic acid
(Ethylenedinitrilo)tetraacetic acid, disodium zinc
salt, dihydrate --
(Ethylenedinitrilo^tetraacetic acid, tetrasodium salt-
(N-Hydroxyethylethylenedinitrilo)triacetic acid, tri-
sodium salt
All other
Oleamide COct^decene amide)
Pentaerythritol tetranitrate
Stearamide
Stearic acid - ethylenediamine condensate (amine/acid
ratio-1/2)
Urea in compounds or mixtures (100% basis), total
In feed compounds
In liquid fertilizer
In solid fertilizer
All other
All other nitrogenous compounds
Acids, Aoyl Halides and Anhydrides
Total
Acetic acid, synthetic, 100%
Acetic anhydride, 100%
Acrylic acid
Adipic acid
Butyric acid
Dodecenylsuccinic anhydride
Fumaric acid
Lauroyl chloride
Maleic anhydride
Palmitoyl chloride
Polyacrylic acid
Propionic acid
All other acids, acyl halides and anhydrides
1,000
pounds
264,540
1,000
87
167
93
279
83
894
158
263
S
006
4
287
1
686
36
955
S
820
106
509
m.
3,644
20,614
6,238,357
671,901
2,818,562
2,403,260
344,634
3,994,896
5.992.209
1,932,285
1,589,047
100,418
1,081,995
53,202
4,617
215,122
330
890
49,601
964,702
1,000
dollars
23,557
63,352
65,688
78,642
6,951
6,633
9,973
2,550
1,339
1,694
24,795
4,488
104,306
4,410
3,085
745
13,358
5,456,122
738
727
684
6,712
1,742
15,325
1,922
2,546
326
584,803
2,438,170
2,212,700
220,449
813,139
1.258.061
4,210
f9-) 157,364
16,820
67,722
66,036
6,786
340,210
185,251
389,146
160,703
23,805
127,081
2,569
2,290
45,488
150,972
864
28,661
326,482
22,873
13,929
5,155
19,861
572
933
9,287
23,963
548
2,457
85,673
See footnotes at end of table.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. — Miscellaneous chemicals: U.S. production and sales , 1970- -Continued
Production
MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued
Salts of Organic Aaids
Total
Acetic acid salts, total
Copper acetate
Potassium acetate
Sodium acetate
Zinc acetate
Zirconium acetate
All other
2-Ethylhexanoic acid (a-Ethylcaproic acid) salts:
Calcium 2-ethylhexanoate
Cobalt 2-ethylhexanoate
Lead 2-ethylhexanoate
Manganese 2-ethylhexanoate
Zinc 2-ethylhexanoate
Zirconium 2-ethylhexanoate
Gluconic acid, sodium salt
Lactic acid salts
Mercaptoacetic (Thioglycolic) acid, salts
Octanoic (Caprylic) acid, salts
Oleic acid salts
Polyacrylic acid salts
Propionic acid salts:
Calcium propionate
Sodium propionate
Stearic acid salts, total'"
Aluminum stearates, total
Aluminum distearate
Aluminum monostearate and tristearate
Cadmium stearate
Calcium stearate
Lithium stearate
Magnesium stearate
Zinc stearate
All other
All other salts of organic acids
Aldehydes and Ketones
Total
Acetaldehyde
Acetone, total
From cumene
All other
2-Butanone (Methyl ethyl ketone)
See footnotes at end of table.
1,000
pounds
29,658
263
2,983
20,859
356
188
5,009
1,169
1,517
940
196
681
14,241
1,819
3,133
1,199
578
4,743
20,295
4,792
46,181
3,208
2,519
689
109
23,339
497
3,632
11,221
4,175
151,359
1,611,352
1.615,248
723,620
891,628
1,000
pounds
243,671
34,454
184
2,414
13,014
371
131
18,340
302
1,150
793
188
635
1,031
14,097
1,587
2,984
908
480
5,159
16,253
3,870
43,405
3,090
2,324
766
112
23,000
478
3,394
10,674
2,657
116,375
559,097
564,454
427,218
1,000
dollars
6,407
164
750
2,255
147
51
3,040
116
844
343
60
320
544
3,575
664
4,562
994
325
5,795
3,534
857
1,231
909
322
86
8,049
254
1,351
3,905
993
39,275
44,815
22,692
22,123
MISCELLANEOUS CHEMICALS
TABLE I. — Miscellaneous chemicals: U.S. production and sales, 1970 — Continued
Production
Quantity
1,000
dollars
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Aldehydes and Ketones--Conti.mxed
Formaldehyde (37% by weight)
4-Hydroxy-4-methyl-2-pentanone (Diacetone alcohol)
4-Methyl-2-pentanone (Methyl isobutyl ketone!)
All other aldehydes and ketones
Alcohols, Monohydric, Unsubstituted
Total
Alcohols, Cs or lower, unmixed, total
Butyl alcohols:
n-Butyl alcohol (n-Propylcarbinol)
Isobutyl alcohol (Isopropylcarbinol)
Ethyl alcohol, synthetic"
2-Ethyl-l-hexanol
Hexyl alcohol
Iso-octyl alcohols
Isopropyl alcohol
Methanol, synthetic
1- (and 2-)0ctanol
Propyl alcohol (Propanol)
All other
Alcohols, Cio and higher, unmixed, total
Decyl alcohols
1-Hexadecanol and other hexadecyl alcohols
Stearyl and other octadecyl alcohols
All other
Mixtures of alcohols, total
C9 and lower, only
Cio and higher, only
Ce to Ci2 and others
Polyhydric Alcohols and Their Esters and Ethers
Total' ^
Polyhydric alcohols, total
Ethylene glycol
Glycerol, synthetic only
Pentaerythritol
Propylene glycol (1,2-Propanediol)
Sorbitol
All other
Polyhydric alcohol esters
See footnotes at end of table.
1,000
pounds
4,426,931
199,043
1,692,804
10,531,342
467,808
91,746
1,956,597
456,997
16,656
99,833
1,919,206
4,931,682
60,320
530,497
127,307
534,675
49,574
394,681
90,420
6,200,071
4.265.579
,037,501
190,809
85,189
428,181
105,091
418,808
186,680
1,000
pounds
,381,029
33,049
37,493
4,830
166,948
19,425
815,446
64,726
318,030
4,609.154
243,390
278,163
77,771
1,060,607
228,612
3,744
76,271
861,215
1,723
5,518
57,245
98,285
130,182
1,
22,140
4,214
66,841
18,942
383
7,075
49,183
53,344
1,074
6,093
14,101
19,636
57,812
5,671
7,168
59,531
419,183
5,466
1,533
1,509
11,128
55,004
35,068
294,519
89,596
4,484.158
3.829
40.146
11.029
279.101
.209,675
176,129
67,572
395,459
88,183
131,514
178,258
146,205
32,637
15,501
36,419
17,444
30,895
36,218
214
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. — Miscellaneous chemicals: U.S. production and sales, 1970 — Continued
1,000
Quantity
1,000
pounds
1,257,568
1,0UU
dollars
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Polyhydrio Aloohols and Their Esters and Ethers — Continued
Polyhydric alcohol ethers, total
2-Butoxyethanol (Ethylene glycol monobutyl ether)
2- (2-Butoxyethoxy)ethanol (Disthylene glycol monobutyl
ether)
2-[2- (2-Butoxyethoxy)ethoxy]ethanol (Trlethylene glycol
monobutyl ether)
Diethylene glycol
Dipropylene glycol
2-Ethoxyethanol (Ethylene glycol monoethyl ether)
2-(2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl
ether)
2-Methoxyethanol (Ethylene glycol monomethyl ether)
2- (2-Methoxyethoxy)ethanol (Diethylene glycol monomethyl
ether)
2- [2- (2-Methoxyethoxy)ethoxy]ethanol (Triethylene
glycol monomethyl ether)
Polyethylene glycol
Polypropoxy ethers, total
Glycerol tri(polyoxypropylene) ether
All other
Polypropylene glycol
Triethylene glycol
All other ethers of polyhydric alcohols
Esters of Monohydrio Aloohols
Total
n-Butyl acetate, unmixed
Butyl aery late
Dibutyl maleate
Diethyl carbonate (Ethyl carbonate)
Dilauryl 3,3'-thiodipropionate
Dioctyl maleate
Distearyl 3,3 5-thiodipropionate
Ethyl acetate, 85%
Ethyl aery late
Ethyl chloroacetate
2-Ethyl-l-hexyl aery late
Methyl esters of tallow
Methyl methacrylate
Phosphorus acid esters, not elsewhere specified
Propyl acetate
Vinyl acetate
All other
1,747,812
106,915
15,080
341,407
44,142
136,316
35,842
97,029
13,375
24,801
42,098
388,023
192,103
195,920
212,886
89,312
200,586
2,447,970
74,322
84,429
9,686
1,759
993
4,529
850
161,360
207,269
45,360
269
445,053
17,791
23,532
803,224
567,544
10,295
2,007
196,613
34,874
59,174
30,760
75,375
40,653
301,711
164,761
136,950
187,016
70,178
131,516
64,268
45,835
9,546
1,328
4,092
791
138,834
68,202
182
32,660
269
17,482
22,071
348,875
425,160
13,385
1,778
398
13,325
3,862
7,795
4,260
8,415
9,163
49,208
24,253
24,955
28,131
9,246
28,589
188,778
7,204
8,125
1,743
515
838
692
11,034
11,464
91
6,975
38
14,480
2,660
29,698
93,221
See footnotes at end of table.
MISCELLANEOUS CHEMICALS
TABLE 1. --Miscellaneous chemicals: U.S. production and sales , 1970-- Continued
215
Quantity
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Halogenated Hydroaarbons
Total
Carbon tetrachloride
Chlorinated paraffins, total
35-64% chlorine
Other
Chlorodifluoromethane
Chloroethane (Ethyl chloride)
Chloroform
Chloromethane (Methyl chloride)
1,2-Dibromoethane .(Ethylene dibromide) —
Dichlorodif luoromethane
1,2-Dichloroethane. (Ethylene dichloride)
Dichloromethane (Methylene chloride)
1,2-Dichloropropane (Propylene dichloride)
lodomethane (Methyl iodide) :
Tetrachloroethylene (Perchloroethylene)
1,1,1-Trichloroethane (Methylchloroform)
Trichloroethylene
Trichlorof luoromethane
Vinyl chloride, monomer (Chloroethylene)
All other halogenat'ed hydrocarbons
All Other Miscellaneous Aoyolio Chemicals
Total
2-Butanone peroxide
tert- Butyl hydroperoxide
tert-Butyl peroxide (Di-tert-butyl peroxide)
Carbon disulfide
Epoxides, ethers, and acetals:
Ethylene oxide
Isopropyl ether
Propylene oxide
Lauroyl peroxide
Organo-silicon polymers
Phosgene (Carbonyl chloride)
Sodium formaldehyde sulfoxylate
Sodium methoxide (Sodium methylate)
Tetraethyllead
Tetra(methyl-;ethyl) leads
Zinc formaldehyde sulfoxylate
All other
1,000
pounds
18,695,628
1,000
pounds
1,011,191
58,371
35,393
22,978
678,034
239,893
422,678
296,826
375,406
7,459,824
402,190
20
706,896
366,330
610,778
244,472
4,040,234
1,782,485
8,304,545
3,164
2, '166
1,610
720,851
3,864,767
1,179,216
1,589
91,872
617,471
4,631
5,757
324,757
504,215
628
981,851
1,000
dollars
708,305
841,188
56,913
44,093
7,560
34,612
22,301
72,613
272,741
174,903
175,961
145,626
356,040
1,313,995
358,160
21,778
10
640,192
327,387
568,860
236,580
2,720,196
285,249
4,051
3,509
37.031
17,135
10,686
9,750
26,139
91,603
38,292
28,757
596
36
44,835
32,084
40,490
43,772
107,037
128,409
754,672
2,986
787
1,512
465,990
411,232
7,511
172,134
1,611
83,916
4,216
325,593
484,364
612
485,243
3,215
579
1,372
19,427
28,641
766
14,667
1,294
104,077
1,098
172,539
280,880
285
125,832
' Calculated from rounded figures.
2 Not available.
3 Statistics exclude production and sales of tricresyl phosphate. Statistics on tricresyl phosphate
with "Plasticizers".
'* Quantities are given on the basis of solid naphthenate, tallate, or linoleate content.
5 Statistics exclude production and sales of copper naphthenate.
Statistics on copper naphthenate are included
216 SYNTHETIC ORGANIC CHEMICALS, 19 VO
TABLE 1. --Miscellaneous chemicals: U.S. production and sales, 1970- -Continued
Footnotes for table ^--Continued
with "Pesticides and Related Products".
*' Ethylcellulose which was formerly included with cellulose ethers is now included with cellulosic plastics
materials .
^ Statistics exclude production and sales of fatty amines. Statistics on fatty amines are given with "Surface-
Active Agents."
® Production of urea in primary solution totaled 6.500,046 thousand pounds.
' Includes estimated values for sales of urea in nitrogen compounds.
'" Statistics exclude production and sales of potassium and sodium stearates. Statistics on these stearates are
included with "Surface-Active Agents."
" Statistics on production of ethyl alcohol from natural sources by fermentation are issued by the Alcohol Tax
Unit, U.S. Internal Revenue Service.
'^ Of the total production, about 60% consisted of alcohols lower than Cm and about 40% consisted of alcohols
higher than Cj q .
Some polyols which are used as intermediates for urethanes have been included with "Plastics and Resin Materials.
MISCELLANEOUS CHEMICALS
217
TABLE 2. — Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970
[Miscellaneous chemicals for which separate statistics are given in table 1 are marked with an asterisk (*5;
chemicals not so marked do not appear in table 1 because the reported data are accepted in confidence and may not
be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that the
manufacturer did not consent to his identification with the designated product]
Manufacturers ' identification codes
(according to list in table 3]
MISCELLANEOUS CHEMICALS, CYCLIC
Acetylcyclohexanesulfonyl peroxide
1-Adamantanamine
Adenosine and derivatives
2-Aminobenzothiazole
2-Amino-5-dichloro-2-propylbenzophenone
2-Amino-4,6-dimercapto-l,3,S-triazine
1- C2-Ajninoethyl)piperazine
1- (3rAminopropyl)morpholine
Amyl p-dimethylaminobenzoate
Anisaldehyde bisulfite
Arylalkyl phosphites
*Benzoic acid, sodium salt
p-Benzoquinone (p-Quinone)
Benzothiazole
* Benzoyl peroxide
Biological stains
Bis-aminopropylpiperazine
BisC2,4-dichlorobenzoyl) peroxide
2,4-BisC4-hydroxy-3,S-di-tert-butylphenoxy)-6- (n-octyl-
thio)-l,3,5-triazine.
Bis(2-hydroxypropoxyphenyl)methane
2,4-Bis(n-octylthio3-6-(4'-hydroxy-3' ,5 '-di-tert -butyl-
anil ino)- 1,3, 5-triazine.
Boron fluoride-phenol complex
* Butyl benzoate
p-tert-Butylbenzoic acid, barium bis-salt
2 (and 3)-tert-Butyl-4-methoxyphenol
tert- Butyl peroxybenzoate
4-tert-Butylphenyl salicylate
4-tert-Butylpyrocatechol
Camphene
Cellulose acetate phthalate
Central ite-1 (N,N'-Diethyl-N,N'-diphenylurea)
Chemical indicators and reagents
Chloramine B (Sodium derivative of N-chlorobenzenesulfon-
amide) .
1- (3-Chlorallyl)-3,5,7-triaza-l-azoniaadamantane
chloride.
o-Chlorobenzamalononitrile
p-Chlorophenylalanine
Chlorophyllin, sodium-potassium-copper
Cholesteryl chloride ■
Cobalt phthalocyaninedisulfonate
Cumene hydroperoxide
Cyanuric and isocyanuric acid
1,3 (and 1 ,4)-Cyclohexadiene
Cyclohexanone peroxide
Cyclohexene-l,2-dicarboxylic acid (Tetrahydrophthalic
acid) disubstituted, polyester salts: Barium and
cadmium salts.
Cyclohexene
Cyclohexenone and cyclopentenone
1,4-Cyclohexylenedimethanol
l-Cyclohexyl-2-pyrrolidinone
Cyclohexyl p-toluenesulfonate
Cyclopropane
Cytidine and derivatives
SHL.
MON, PFZ, VEL, WSN.
NOC, RCI, WTC, WTL, x.
EK.
WTL.
ALD.
PLB.
FMT.
ALD.
ACY.
JCC,
JCC.
VND.
GIV,
WES.
HN,
EKT
ACY
CAD
ACS,
JCC.
CAD,
CGY.
JCC.
CGY.
ACS.
PFZ,
CCA.
EKT.
NOC,
DOW.
BKL,
GLD,
X.
OTC.
ACS,
NES.
DOW.
NCA.
ALD.
KCH.
ALD.
ACS.
ACP, HPC, RCI.
FMB, MON.
ALD.
NOC, WTL.
RCI.
EK.
ALD.
EKT.
GAF.
ARS.
OH, OMS, TAE.
PLB.
TCC, VAL, VEL.
DOW.
HN, HPC.
EK, FIN, GFS, LAM.
218
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.-
-Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, CYCLIC--Continued
Decahydronaphthalene (Decalin)
Diaminohexanitrobiphenyl
Diaminotrinitrobenzene
2,S-Di-tert-amylhydroquinone
l,4-Diazobicyclo(2.2.2)octane
Diazodinitrophenol
2,5-Di(benzoylperoxy)-2,5-dimethylhexane
Dibenzyl azodicarboxylate
Dibromodimethylhydantoin
2,6-Di-tert-butyl-p-cresol :
*Food grade
*Tech
2,5-Di-tert-butylhydroquinone
Di-tert-butyl diperoxyphthalate
l,3-Dichloro-5,5-dimethylhydantoin
Dichloro-s-triazine-2,4,6(lH,3H,5H)trione [Dichloroiso-
cyanuric acid), and salts.
4,4'-Dichloro-3-trif luoromethylcarbonalide
Dicyclohexylanraionium nitrite
Digit onin
2,5-Dihydrothiophene-l,l-dioxide (Sulfolene)
2,4-Dihydroxybenzophenone
2,2'-Dihydroxy-4,4'-dimethoxybenzophenone
3,S-Dihydroxy-3,5-dimethyl-l,2-peroxycyclopentane
2,6-Dihydroxyisonicotinic acid (2,6-Dihydroxy-4-carboxy-
pyridine) .
2,2'-Dihydroxy-4-methoxybenzophenone
2,2'-Dihydroxy-4- (octadecyloxy}benzophenone
Diisopropylbenzene hydroperoxide
Diisopropyl-m.p-cresols
•p-Dimethoxybenzene (Dimethyl ether of hydroquinone)
2,6-DimethylraorphoIine
2,4-Dinitrobenzenesulfonic acid, sodium salt
4,4-Dinitrocarbanilide-4,6-dimethyl-2-pyrimidinol
Di-n-octadecyl-3,5-di-tert-butyl-4-hydroxyphenyl phospho-
nate.
l,2-Dioctylcyclobutane-3,4-bis(octamethylene isocyanate)-
Dioxane (1,4-Diethylene oxide)
Dioxin
Dipropylene glycol salicylate
Dithioammilide, monoethanolamine salt
4- (Dodecyloxy) -2-hydroxybenzophenone
* Enzymes:
Hydrolytic:
Amylases
Proteases
Other
Nonhydro lytic
Ethyl cellulose phthalate
Ethylenediaminedi(o-hydroxyphenylacetic acid), ferric
sodium salt.
4-Ethylmorpholine
*Flotation reagents:
Dicresylphosphorodithioic acid (Dicresylthiophosphoric
acid) .
Dicresylphosphorodithioic acid, ammonium salt
Dicresylphosphorodithioic acid, sodium salt
2,2' -Dimethyl thiocarbanilide (Di-o-tolyl thiourea)
Rosin amines
Thiocarbanilide (Diphenylthiourea)
Fluorinated benzenoid chemicals
Furan derivatives:
2-Furaldehyde (Furfural)
Tetrahydrof urf ury 1 al cohol
Gallic acid
"Gasoline additives:
N,N'-Bis(l,4-dimethylpentyl)-p-phenylenediamine
6-tert-Butyl-o-cresol
DUP.
NCA.
NCA.
CTN, EKT.
HOU.
HPC.
WTC, WTL.
WTL.
ARA.
ASH, HPC, KPT, PRD, SHC .
ASH, HPC, KPT, PRD, SHC, USR.
EKT.
WTL.
GLY.
FMB, MON.
CGY.
OMC.
PEN.
PLC.
DUP.
GAF.
WTL.
EK.
ACY.
ACY.
HPC.
GIV.
EKT, GAF, UOP.
DOW.
NES.
MRK.
CGY.
OTC.
DOW, UCC.
GIV.
SBC.
ACY.
DUP, EKT.
BAX, CRN, GRP, MLS, OMS, PMP, RH, WBC.
BAX, CHH, COM, DOL, ENZ, GRP, MLS, PD, PFZ, PMP,
SPR, WBC.
BAX, JFR, MLS, OMS, RH, WBC.
MLS, PLB, WBC.
EK.
CGY.
BRD, JCC.
ACY.
ACY.
KCU.
DUP, RBC.
HPC.
ACS, ACY.
PIC.
QKO.
QKO.
MAL.
EKT.
TNA.
MISCELLANEOUS CHEMICALS
219
TABLE 2. — Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
[according to list in table 3}
MISCELLANEOUS CHEMICALS, CYCLIC--Continued
*Gasoline additives --Continued
2,5-Di-tert-butylphenol
N,N'-Di-?ec-butyI-p-phenylenediamine
2,6-Di-tert-butyl-a-diniethyIaniiho-p-cresoI
2,6-Diethylaniline
N,N'-Diisopropyl-p-phenylenediamine
N,N'-Disalicylidene-l,2-propanediainine
4,4'-Methylenebis(2,6-di-tert-butylphenol)
4,4'-Thiobis[6-tert-butyI-o-cresoI)
2,2'-Thiobis(6-tert-butyl-p-cresoI)
I,3,5-Tris(;3,5-di-tert-butyl-4-hydroxybenzyI)-
mesitylene.
Other
Glyceryl p-aminobenzoate
Guanosine and derivatives
*HexainethyIenetetramine, tech
Hexanitrobenzene
Hexanitrostilbene
Homomenthyl salicylate
Hydrindantin
Hydrocinnamic acid •
o- (2-Hydroxy-p-anisoyl}benzoic acid
p-Hydroxybenzoic acid esters:
Benzyl p-hydroxybenzoat e
Butyl p-hydroxybenzoate (Butylparaben)
Ethyl p-hydroxybenzoate (Ethylparaben)
n-Heptyl p-hydroxybenzoate (Heptylparaben)
*MethyI p-hydroxybenzoate (Methylparaben)
*PropyI p-hydroxybenzoate [Propylparaben)
Other
Hydroxymethyl-5,5-dimethyIhydantoin
2-Hydroxy-4-methoxybenzophenone
2-Hydroxy-4-methoxy-5-sulfobenzophenone trihydrate--
2-HydroxyniethyI-5-norbornene aery late
2-Hydroxy-4-n-octoxybenzophenone
2-[2-Hydroxy-5-tert-octylphenyl)benzotriazole
2-HydroxypropyI p-[N,N-bis-2-hydroxypropyl amino )-
benzoate.
l-Hydroxy-2 -pyridine [Omadine)
2-Imidazolidinethione [I, 3-Ethylene- 2- thiourea)
1,2,3-Indantrione monohydrate [Ninhydrin)
Inosine and derivatives
2-(p-IodophenyI)-3- [p-nitrophenyl)-5-phenyl-2H-
tetrazolium chloride.
Isobutyl vinyl ether - toluene, xylene polymers
Isopropyl-o-cresols
Isopropylmorpholine
*Lubricating oil and grease additives:
Chlorosulfurized and sulfurized compounds:
Heterocyclic compounds, sulfurized
Other
Oil-soluble petroleum sulfonates:
Oil-soluble petroleum sulfonate, ammonium salt--
*Oil-soIuble petroleiun sulfonate, barium salt
*OiI-soluble petroleum sulfonate, calcium salt
Oil-soluble petroleum sulfonate, magnesium salt-
*Oil-soluble petroleum sulfonate, sodium salt
Phenol salts:
Barium salt of nonylphenol
Calcium salt of octylphenol-formaldehyde
Other
All other
TNA.
DUP, EKT, USR.
TNA.
TNA.
EKT.
DUP, TX.
TNA.
TNA.
ASH.
TNA.
EKT, TNA, UPM.
VND.
PLB.
DUP, HKD, HMP, HN, PLS, UCC .
NCA.
NCA.
ARS.
HEX.
ARS.
ACY.
RSA.
HN, LEM, WSN.
HN, LEM, WSN.
WSN.
ARS, HN, LEM, WSN.
ARS, HN, LEM, WSN.
WSN.
GLY.
ACY, GAP.
ACY.
ARS.
ACY.
ACY.
SHE.
OMC.
PAS.
HEX.
PLB.
EK.
GAP.
CP.
JCC.
ORO.
LUB, SOI.
CO.
CO, LUB, TX.
CO, ENJ, LUB, ORO, SHO,
CO.
CO, ENJ, MOR, PAR, SHO, SOC, SOI.
ENJ, CCA.
SHC.
ENJ, GOG, HOG. LUB, ORO, SHC, SIN, TX, x.
ENJ, GOC, LUB, ORO, SIN, SM, x.
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, CYCLlC--Continued
p-Menthane
8-p-Menthy 1 hydroperoxide
p-MethoxyDenzylidenemalonic acid, diethyl and
dimethyl esters.
4-Methoxyphenol
Methylaziridine
2,2'-Methylenebis(4-chlorophenol) (Dichlorophene)
Methylenebis[dimethylhydantoin]
2,2'-Methylenebis (3,4,6-trichlorophenol) (Hexachloro-
phene) .
Methyl gal late
Methylglucoside
4-Methylmorpholine
Methyl phenyl phosphates
1-Methyl- 2 -pyrro 1 idone , monomer
*Morpholine
Morpholine salt of p-toluenesulfonic acid
*Naphthenic acid salts:
Aluminum naphthenate
Barium naphthenate
Cadmium naphthenate
*Calcium naphthenate
Cerium naphthenate
Cobalt lead manganese naphthenate
*Cobalt naphthenate
Iron naphthenate
Lead manganese naphthenate
* Lead naph thenat e —
Lith ium naphthenate
*Manganese naphthenate
Nickel naphthenate
Rare earths naphthenate
Sodium naphthenate
Stront ium naphthenate
*Zinc naphthenate
o-Nitrobenzoic acid and sodium salt
Octadecyl 3- (3,S-di-tert-butyl-4-hydroxyphenyl)-
propionate.
Organic mercury compounds: Phenylmercuric borate
Oxanilide
2-Phenoxyethanol (Ethylene glycol monophenyl ether)--
2- (2-Phenoxyethoxy}ethanol (Diethylene glycol phenyl
ether) .
2 - Ph enoxypropano 1
2,2'- (p-Phenylene)diethanol
m-Phenylene isonaph thai amide
Phenyl hydrogen phosphate
2- (Phenylthio)quinoline
S-Phosphonylribose-1 -pyrophosphate
Photographic chemicals:
N- (o-Acetamidophenethyl) -l-hydroxy-2-naphthamide--'
2- (4-Ainino-N-ethyl-m-toluidino)ethyl sulfate
3-Amino-l,2,4-triazole
Benzotriazole
p-Benzylaminophenol hydrochloride
2-Chloro-N,N-diethyl-p-phenylenediamine hydro-
chloride.
3-Chloro-4-diethylaminobenzenediazonium salts (p-
Diazo-2-chloro-N,N-diethylaniline salts) .
Chlorohydroquinone
2 ,4-Diajninophenol dihydrochloride (Amidol)
2,5-Diethoxy-4-morpholinobenzenediazonium salts
HPC.
HPC, VND.
ACY.
ASL, EKT.
ARS.
GIV.
GLY.
GIV.
HSH.
CRN.
JCC, UCC.
TNA.
GAP.
DOW, JCC, UCC.
AMB.
HSH, WTC.
CCA.
CCA.
CCA, CCC, PER, HNX, HSH, MCI, SHP, SRR, SW, IRQ, WTC.
SHP.
HNX, HSH.
CCA, CCC, PER, HNX, HSH, MCI, SHP, SRR, SW, TRO, WTC.
CCA, CCC, HNX, HSH, MCI, WTC.
CCA.
CCA, CCC, PER, HNX, HSH, MCI, SHP, SRR, SW, TRO, TX,
WTC.
CCA, MCI.
CCA, PER, HNX, HSH, MCI, SHP, SRR, SW, WTC.
CCA.
CCA.
CCA.
CCA.
CCA, CCC, PER, HNX, HSH, MCI, SHP, SW, TRO, WTC.
WAY.
CGY.
TRO.
FIN.
DOW, JCC.
DOW.
JCC.
EKT.
DUP.
HDG, SM.
EK.
PLB.
EKT.
EKT.
FMT.
EK, FMT, MRT, SW.
EK.
IDC.
FMT.
EK.
VPC.
PMT, GAP.
MISCELLANEOUS CHEMICALS
221
TABLE 2.
-Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers ' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, CYCLIC--Continued
Photographic chemicals- -Continued
2,5-Diethoxy-!4-thiocresoldiazonium salts
*p-DiethyIaminobenzenediazonium (p-Diazo-N,N-diethyl-
aniline) , zinc chloride salt.
NjN-Diethyl-p-phenylenediamine hydrochloride
N,N-Diethyltoluene-2, 5 -diamine, monohydrochloride
2,5-Dihydroxy-p-benzenedisulfonic acid salts
2,5-Dihydroxybenzenesulfonic acid
p-Dimethylaminobenzenediazonium chloride (p-Diazo-N,N-
dimethylaniline] - zinc chloride.
4- (2' ,6'-Dimethvlmort)holinyl)benzenediazoniuni
chloride - zinc chloride.
p-Dipnenyiaminediazonium sulfate
p- (N-Ethylbenzimido)benzenediazonium chloride (p-
Diazo-N-benzyl-N-ethylaniline5 - zinc chloride.
*p- [Ethyl C2-hydroxyethyl)amino]benzenediazonium
chloride.
N-Ethyl-N-hydroxyethyl-p-phenylenediamine sulfate
N-Ethyl-N-Cg-methanesulfonamidoethyl) toluene- 2, 5-di-
amine sulfate.
Hydr oquinone (Hydroquinol )
p-((2-Hydroxyethyl3methylamino)benzenediazonium
chloride (p-Diazo-N-hydroxyethyl-N-methylaniline) -
zinc chloride.
4-Methoxy-l-naphthol
p-Methylaminophenol sulfate
S-Methylbenzotriazole
4-Methyl-l-phenyl-3-pyrazolidinone
4-Morpholinylbenzenediazonium salts
6-Nitrobenziinidazole ■■
Octylphenyl salicylate
1- Phenyl- 3-pyrazolidinone
4-Phenylpyrocatechol
Polyvinyl cinnamate
2-Resorcylic monoethanolamide
1- (2,4,6-Trichlorophenyl)-3- C4-nitroanilino]-2-
pyrazolin-5-one.
All other
Phthalic acid, lead salt, dibasic
Picramic acid, sodium salt
*Pinene (a- and g-)
Piperazine, ethoxylated
Piperonal, sodium bisulfite complex
Poly-4- (2-acryloxyethoxy)-2-hydroxybenzophenone
Polyethylene terephthalate
Polyvinyl phthalate
Propyl gal late
Pyrogallol (Pyrogallic acid]
Resorcinol monobenzoate
Rosin acid salts:
Calcium resinate
Copper resinate
Iron resinate
Lead resinate
Manganese resinate
Zinc resinate
Salicylanilide
Salicylic acid, lead salt
Sodium cresoxide (Cresylic acid, sodium salt)
Sucrose benzoate
Sulfosalicylic acid
FMT.
FMT,
MRT,
EKT,
FMT.
EKT,
IDC.
x.
EK.
FMT,
IDC.
FMT.
MRT.
FMT,
IDC, X
FMT,
IDC.
EKT.
EKT.
FMI,
IDC.
EK.
EK,
FMT.
WAY.
FMT,
IDC.
EK,
FMT.
EKT.
CGY,
WAY.
X.
WAY.
FMT.
EKT.
EK,
EKT, FMI,
IDC,
VPC, X.
NTL.
SDC.
ARZ,
CBY, GLD,
HN,
HPC, NCI
GAF.
SHL.
ACY.
DUP,
EK.
EK.
EKT,
HSH.
HSH,
MAL.
EKT.
JMS,
SW.
JMS.
JMS.
JMS.
JMS.
HN,
JMS, SW.
DUP,
FIN, PCW
NTL.
DEX,
GOC.
VEL.
LEM,
MON, MRK
462-669 O - 72 - 15
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manu£a<:turers ' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, CYCLIC--Continued
*TaII oil salts (Linoleic-rosin acid salts) :
Calcium manganese tallate
*Calciijm tallate ■
*Cobalt tallate
Copper tallate
*Iron tallate
Lead manganese tallate
*Lead tallate
*Manganese tallate
Zinc tallate
Tannic acid
*Tanning materials, synthetic:
*2-Naphthalenesulfonic acid, formaldehyde condensate
and salts.
l-Phenol-2-sulfonic acid, formaldehyde condensate
(Phenol-formaldehyde, sulfonated) .
Styrene maleic anhydride interpolymer, partial sodium
salt.
Sulfonyldiphenolsulfonic acid, formaldehyde
condensate.
All other
Te tr abr omob isphenol A
2,3,5,6-Tetrachloro-4- (methylsulfonyl) pyridine
1,2,3 , 4-Tetrahydronaphthal ene (Tetral in)
Te t r ahydroth ioph ene
Tetrahydrothioph ene- 1,1 -dioxide (Sulfolane)
Tetrakis [methylene-3- (3' , 5 ' -di-tert-butyl-4 ' -hydroxy-
phenol)propionate]methane.
1,3,6,8-Tetranitrocarbazole
Tetraphenyltin
*Tex':ile chemicals, other than surface-active agents:
N ,N -Diphenyl-l,2-propanediamine
1- ((Octadecyloxy)methyl)pyridinium chloride
Phenol, sulfurated
Tetrahydro-3 ,5-bis (methoxymethyl) -4H- 1 , 3, 5-oxadiazin-
4-one (l,3-Bis(methoxymethyl)uron) .
2 , 2 ' , 4 , 4 ' -Tetrahydroxybenzophenone
All other
2,2'-Thiobis (4-chlorophenol)
2,2'-Thiobis(4,6-dichlorophenol)
(2,2' -Thiobis (4-octylphenolate))-n-butylamine nickel
Thiophene-
o-Toluidine formaldehyde hydrochloride
o-Tolylbiguanide
Trial lyl cyanurate
Triaryl phosphites
3,4' ,5-Tribromosalicylanilide
3,4' ,5-Tribromosalicylanilide and 4,5-Dibromo-
salicylanilide mixtures.
3,4,4'-Trichlorocarbanilide
Trichloromelamine
l,3,5-Trichloro-s-triazine-2,4,6(lH,3H,5H)trione (Tri-
chloroisocyanuric acid) .
Tri- (m,p)-cresyl borate
Trimethylaminoethylpiperazine
3,5,S-Trimethyl-2-cyclohexen-2-one (Isophorone)
2,4,6-Trinitroresorcinol and lead derivative
s-Trioxane
Triphenylphosphine
Triphenyl phosphite
Triphenyl sulfonium chloride
Triphenyl tin
Uridine derivatives
l-Vinyl-2-pyrrolidinone, monomer and polymer
l-Vinyl-2-pyrrolidinone - acrylic copolymers
l-Vinyl-2-pyrrolidinone - vinyl acetate copolymer
l-Vinyl-2-pyrrolidinone - other copolymers
MCI.
CCA,
CCA,
CCA,
CCA,
HSH,
CCA,
CCA,
HSH,
MAL.
CCC, HNX, HSH, MCI, SRR, TRO, WTC .
CCC, FER, HNX, MCI, SHP, SRR, TRO, WTC.
MCI, SHP.
MCI, SHP, SRR, WTC.
MCI.
CCC, FER, HNX, HSH, MCI, SHP, SRR, TRO, WTC.
CCC, FER, HNX, HSH, MCI, SHP, TRO, WTC.
MCI.
AKS, DA, GRD, RH, TCD.
DUP.
GAP.
AKS,
GTL.
DOW.
DUP,
PAS.
PLC.
CGY.
SNW.
DUP.
GAP.
GAP.
GAP, x, X.
GIV.
X.
ACY.
PAS.
RBC.
MON.
ACY.
WES.
FIN.
FIN.
MON.
AMB, GAP, NES, WTH.
MON.
USB.
JCC.
ENJ, UCC.
REM.
CEL.
HK, MON.
FIS.
X.
PLB.
GAP.
GAP.
GAP.
GAP.
MISCELLANEOUS CHEMICALS
223
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers ' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC
Cellulose Esters and Ethers
*Cellulose esters:
*CelIulose acetate
Cellulose acetate butyrate
Cellulose acetate propionate
Cellulose propionate
Nitrocellulose (Cellulose nitrate)
*Cellulose ethers:
Ethylhydroxyethylcellulose
Hydroxyethylcellulose
Hydroxypropylcellulose
Methyl cellulose :
*Sodiuin carboxymethylcellulose, 100%
All other
Lubricating Oil Additives
*Phosphorodithioates (Dithiophosphates) :
Zinc di(butylhexyl) phosphorodithioate
Zinc dihexyl phosphorodithioate
All other
Sulfurized lard oil
Sulfurized sperm oil
All other
Nitrogenous Compounds
Acetamide
Acetamidine hydrochloride
Acetamidoethanol (N-Acetyl-ethanolamine)
Acetonitrile
*Acrylonitrile
Adiponitrile
l-Allyl-3-di(2-hydroxyethyl5 thiourea
l-Allyl-3-(2-hydroxyethyl3-2-thiourea
Allyl isothiocyanate, non-flavor grade
* Amines:
Allylamines
2-Amino-octane
*Butylamines:
*n-Butylaiiiine, mono-
*Di-n-butylamine
Diisobutylamine
sec-Butylamine, mono-
tert-Butylamine, mono-
Tri-n-butylamine
n-Butylethylamine
n-Butylmethylamine
Diethylaminoethylamine
*Diethylenetriamine
N.N-Diethylethylenediamine
N ,N -Diethyl-!, 4-pentanediamine (Novoldiamine)-
Diethylarainopropylamine
Dimethylaminopropylamine
1,3-Dimethylbutylajnine
Dipropylenetriamine
Ethylamines:
*Diethyl amine
Diethylamine hydrochloride
*Ethylamine, mono-
*Triethylamine
*Ethylenediamine
AV, CEL, DUP, EKT.
EKT.
EKT.
CEL.
DUP, HPC.
BUK, DUP, HPC, KON, WMP, WYN.
UCC.
ORO.
MON.
ENJ, LUB, SOI, x.
CCW, NLC, WBG.
CCW.
ALX', CCW, ENJ, GOC, HK, LUB, MON, NLC, ORO,
SOI, TX.
ACS.
MRK.
RBC.
EKX,
SOH.
ACY,
BFG,
DUP,
MON, SOH
DUP,
MON.
IDC.
FMT,
IDC.
ARS.
SHC.
PAS.
PAS,
UCC,
VGC.
PAS,
UCC,
VGC.
ESC,
VGC.
VGC.
MON,
RH.
PAS,
UCC,
VGC.
PAS.
UCC.
PD.
DOW,
JCC,
UCC.
ALB,
CGY.
SDH.
UCC.
JCC,
UCC.
PAS.
UCC.
DUP,
ESC,
PAS,
UCC, VGC.
BKL.
ESC,
PAS,
UCC,
VGC.
ESC,
PAS,
UCC,
VGC.
DOW,
JCC,
UCC.
224
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.-
-Mlscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 19 70- -Continued
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued
Nitrogenous Compounds--Continued
•Amines- -Continue''
Ethyl enediamine salts
(2-Ethylhexyl)aniine, mono-
*1,6-Hexanediamine (Hexamethyl enediamine)
n-Hexylamine
3,3' -Iminobispropyl amine
Isopropylamines :
*Diisopropylamine
Isopropylamines, mono
Methylamines:
•Dimethylamine
Dimethylamine hydrochloride
Dimethylamine sulfate
*Methylamine, mono-
Methylamine hydrochloride
*Trimethylamine
n-Octylamine, mono-
Pentaethylenehexamine
Pentylamines (Amylamines) :
Dipenty lamina
Pentylamine, mono-
Polyalkylene polyamines
Polyethyleneimine
1,2-Propanediajiiine (Propylenediamine)
1,3-Propanediamine (1,3-Diaminopropane)
Propylamines:
*Dipropylamine
Propylamine, mono-
Tripropylamine
Tetraethylenepent amine
N,N,N'-N'-Tetramethyl-l,3-butanediaraine
Tetramethylethylenediamine
*Triethylenetetramine
Other amines
2-Aiiiino-l-butanol
2-Aminoethanethiol C2-Mercaptoethylamine) hydro-
chloride.
2-Aininoethanol (Monoethanolamine) hydrochloride
2-Aminoethanol (Monoethanolamine) sulfite
Aminoethoxyethanol
*2- (2-Aminoethylamino)ethanol (Arainoethylethanolamine)-
2-Aminoethyl mercaptoacetate (Monoethanolamine thio-
glycolate) .
2-Amino-2-ethyl-l,3-propanediol
Aminoguanidine bicarbonate
2-Amino-2- (hydroxymethyl)-l,3-propanediol (Tris-
(hydroxymethyl)aminomethane) .
2-Amino-2-methyI-l,3-propanediol
2-Amino-2-methyl-l-propanol
2-Amino-l-propanol
3-Amino-l-propanol
3-Aminopropionitrile (3-Cyanopropylamine)
3-Amino-l-propylaminoethanol (N-Hydroxyethylpropanedi-
amine) .
*1,1 '-Azobisformamide
2,2'-Azobis[2-methylpropionitriIe] (Azobisisobutyro-
nitrile) .
Bilirubin
Bis[dimethylaminoethyl] etljer
EK, NES.
VGC.
CRL, DUP,
ELP,
MON.
VGC.
JCC.
ESC, PAS,
UCC,
VGC.
ESC, PAS,
UCC,
VGC.
COM, DUP,
ESC,
GAP.
CFC, EK.
RH.
COM, DUP,
ESC,
GAP.
EK, RBC.
COM, DUP,
ESC,
GAP.
VGC.
DOW, JCC.
PAS, VGC.
PAS.
NLC.
SNW.
UCC.
JCC, NTL.
ESC, PAS,
UCC,
VGC.
PAS, UCC,
VGC.
PAS, VGC.
DOW, JCC,
UCC.
UCC.
RH.
DOW, JCC,
UCC.
ALB, ALD,
DUP,
EK, JCC, NTL,
ONX, UCC
ACY, COM.
EVN.
WSN.
EVN, VND.
JCC.
DOW, HDG,
JCC,
UCC.
EVN, HAB.
COM.
COM.
COM.
COM.
COM.
ALB, LIL.
UCC.
EKT.
JCC.
FMT, NPl,
USR.
DUP.
PFN.
UCC.
MISCELLANEOUS CHEMICALS
225
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 19 70- -Continued
Manufacturers ' identification codes
, [according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued
Nitrogenous Compounds --Continued
1,3- Bis (hydroxymethyl) urea (Dimethylolurea)
BisCtrimethyIsilyl)acetamide
N-Bromoacetamide
N- Bromosuccinimide (Succinibromimide)
2,3-Butanedione monoxime
2-Butanone oxime
l-Butyl-3-ethyl-2-thiourea
Butyl isocyanate
Butryaldehyde oxime
n- Butyronit r i le
Caprolactam (2-Oxohexamethyleniniine)
Chlorocholine chloride
2-Chloro-N,N-dimethylethylajnine (Dimethylarainoethyl
chloride.
3-Chloro-N,N-dimethylpropylamine
2-Chloro-N,N-dimethylpropylamine and hydrochloride
3-Chloro-N,N-dimethylpropylamine hydrochloride
2"- Chloro-l,l-dimethyltriethylamine C2-Diisopropylainino-
ethyl chloride) hydrochloride.
2-Chloroethylamine hydrochloride
g-Chloroallyl-N-methylainine
Chloro-N- (2-hydroxyethyl)acetamide
N-Chlorosuccinimide (Succinichlorimide)
2-ChIoro-N, N-diethylethylamine hydrochloride
Choline base
Choline bisulfite
Coco nitrile
Coconut oil acids - airanonium condensate
Coconut oil amide
Cottonseed oil nitrile
Creatine and creatinine
2-Cyanoacetamide
Cyanoacetic acid
Cyanoacetic acid, 2-ethylhexyl ester
Cyanogen bromide
2-Dibutylaminoethanol
l,3-Dibutyl-2-thiourea
1,4-Dicyanobutene
Diethanolamine polyoxypropylene ether
Diethoxyethylamine
2-Diethylaminoethanol
2-C2-Diethylaminoethoxy)ethanol
2-Diethylajiiinoethyl methacrylate
Diethylcarbamoyl chloride
Diethyldithiocarbamic acid, sodium salt
N,N-Diethyldodecan amide
Diethylhydroxy lamina
l,3-Diethyl-2-thiourea
Diisopropylaminoethanol
2-Diisopropylaniinoethyl methacrylate
Diisopropylammonium nitrite
N,N-Dimethylacetamide
*2-Dimethylaminoethanol
3-Dimethylaminopropionitrile
Dimethylarainoethyl methacrylate
Dimethylamino-2-propanol
Dimethylcarbamyl chloride
N,N-Dimethylformamide
CLV,
X.
PIC,
WTC.
ARA.
ARA,
SW.
EK.
ACP,
ALB.
PAS.
OTC,
UPJ.
ACP.
EKX.
ACP,
CNP, DEC, UCC.
ACY.
HEX,
MCH, MRK, NES.
SK.
LIL,
MCH.
MCH,
NES.
MCH.
NHS.
LIL.
KF.
ARA.
HEX,
MCH.
RH.
WAY.
ARC,
ASH.
PC.
ARC.
ASH.
PFN.
AAC,
PAS.
PAS,
RBC.
X.
JCC.
WYN.
AAC,
PAS, UCC
PAS.
DUP.
FIS.
EK.
EK.
PAS.
PAS,
RBC.
PAS,
UCC.
DUP.
OMC.
DUP.
AAC,
DUP, PAS
ACY.
X.
COM,
PAS.
CTN,
OTC.
DUP.
226
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.
-Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers ' identification codes
(according to list in table 3]
MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued
Nitrogenous Compounds --Covitirmei
1 , 1 - D imethy Ihydr az ine
Dithiooxamide
2,5-Dithiobiurea
*Erucainide
*Ethanolamines:
*2-Aminoethanol (Monoethanolamine)
*2i2'-Iminodiethanol (Diethanol amine)
*2,2',2' '-Nitrilotriethanol (Triethanolamine)
Ethoxymethoxypropyl amine
3-Ethoxypropionitrile
Ethyl acetamidocyanoacetate
Ethyl allyl (l-methyl-2-pentynyl)cyanoacetate
2-Ethylaminoethanol (Ethylmonoethanolamine)
Ethyl carbamate
Ethyl carbodiimide hydrochloride
Ethyl cyanoacetate
N,N' -Ethylenebis-stearajnide
Ethyl eneimine, monomer
Ethyl eneimine, polymer
N-Ethyl-N-hydroxyethyl-l,4-pentanediamine
5- (N- Ethyl-N-hydroxyethyl amino) -2-pentanone
Ethyl isocyanate
Fish oil fatty acid amide
Form amide
Formamidine disulfide dihydrochloride
Glycine (Aminoacetic acid)
Glycine ethyl ester hydrochloride
Glycolonitrile
Guanidine hydrochloride
4-Guanyl-l-nitrosoguanyl-l-tetrazine
Hexamethylenediammonium adipate (Nylon salt)
Hydracrylonitrile (Ethylene cyanohydrin)
Hydroxy ethyl carb amate
2- (Hydroxymethyl)-2-nitro-l,3-propanediol (Tris-
(hydroxymethyl)nitromethane) .
N-Hydroxymethy Is tear amide
Hydroxypropy 1 carb amat e
3,3 '-Iminodi-1,2 -propanediol
Isobutyl cyanoacetate
Isobutyronitrile
Isopropanolamines :
l-Amino-2-propanol (Monoisopropanol amine)
1 , 1 ' -Iminodi-2-propanol (Diisopropanolamine)
1, 1 ' ,1' '-Nitrilotri-2-propanol (Tri isopropanol amine) -
3-Isopropoxypropionitrile
3- Isopropoxypropy lamine
2-Isopropylaminoethanol
Isopropyl ethyl thionocarbamate
Lactonitrile
Lauronitrile (Dodecyl nitrile)
Lysine diisocyanate methyl ester
Malononitrile
Methacryl amide
Methacrylonitrile
Methoxyamine hydrochloride
3-Methoxypropy lamine
N-Methylacetamide
FMP.
MAL.
ACY.
ARC, ASH, FIN, HUM.
DOW,
DOW,
DOW,
JCC.
ACY.
SOW.
LIL.
PAS.
FMP.
OTC.
KF.
CTN.
DOW.
AAC,
SDW.
SOW.
OTC.
ASH,
DUP.
WAY.
CHT.
BPC.
ACY.
ACY.
REM.
CEL,
AAE,
JCC.
COM.
JCC, MAT, OMC, SHC, UCC.
JCC, MAT, OMC, SHC, UCC.
JCC, MAT, OMC, SHC, UCC.
DUP, MON.
UCC.
ICI.
JCC.
DUP.
KF.
EKX, ESC.
DOW, UCC.
DOW, UCC.
DOW, UCC.
DUP.
DUP.
PAS.
DOW.
MON.
ASH.
MRK.
KF, MTR.
X,
SOH.
EK .
JCC.
EK.
MISCELLANEOUS CHEMICALS
227
TABLE 2. — Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Nitrogenous Compounds--Continued
2-Methylajninoethanol (N-Methylethanolamine)
Methyl carbamate
Methyl cyanoacetate
Methyl a-cyanoacrylate
N,N'-MethylenebisCacrylainide)
N,N'-Methylenebis(octadecanainide)
Methylenebis(thiocyanate)
N-Methylglucamine
Methyl isocyanate
2,2'- (Methylimino)diethanol (Methyldiethanolamine)
2-Methyllactonitrile (Acetone cyanohydrin)
2-Methyl-2-nitro-l,3-propanediol
2-Methyl-2-nitro-l-propanol
Methylpolyethanolamine
N-Methyl taurine
*Nitriloacids and salts:
(Diethylenetrinitrilo)pentaacetic acid
(Diethylenetrinitrilo)pentaacetic acid, monosodium
hydrogen ferric salt .
*(Diethylenetrinitrilo)pentaacetic acid, pentasodium
salt.
(Diethylenetrinitrilo)pentaacetic acid, sodium salt
N,N-Dihydroxyethylglycine, sodium salt
Ethanoldiglycine, disodium salt
* (Ethylenedinitrilo)tetraacetic acid (Ethylenediamine-
tetraacetic acid) .
(Ethylenedinitrilo)tetraacetic acid, calcium di-
sodium salt.
(Ethylenedinitrilo)tetraacetic acid, disodium salt
(Ethylenedinitrilo)tetraacetic acid, disodium copper
salt, dihydrate.
* (Ethylenedinitrilojtetraacetic acid, disodium zinc
salt, dihydrate.
(Ethylenedinitrilo)tetraacetic acid, manganese salt
(Ethylenedinitrilo)tetraacetic acid, monosodium iron
salt.
(Ethylenedinitrilo)tetraacetic acid, tetraammonium
salt.
(Ethylenedinitrilo)tetraacetic acid, tetrapotassium
salt.
* (Ethylenedinitrilo)tetraacetic acid, tetrasodium salt-
(Ethylenedinitrilo)tetraacetic acid, trisodium salt
(N-Hydroxyethylethylenedinitrilo)triacetic acid, iron
salt.
* (N-Hydroxyethylethylenedinitrilo)triacetic acid,
trisodium salt.
Nitrilotriacetic acid
Nitrilotriacetic acid, trisodium salt
Nitrilotriacetic acid, zinc salt
Other
2-Nitro-l-butanol
Nitroethane .
Nitromethane
1-Nitropropane
2-Nitropropane
UCC.
BKL, FMP.
KF.
EKT.
ACY, SOH.
NLC.
OTC, UCC.
PAS, UCC.
RH, X.
COM.
COM.
GAF.
GAF.
HMP.
CGY.
CGY, DOW,
HMP.
CGY, RPC.
DOW, HMP.
HMP.
CGY, DOW,
HMP.
CGY, DOW.
CGY, DOW,
EK, HMP, RPC
CGY, HMP.
CGY, DOW,
HMP.
CGY, HMP.
CGY, HMP.
CGY
CGY
HMP
HMP
CGY
HMP
ALD
COM
COM
COM
COM
COM
CRT, DOW, HMP, HRT, RPC.
HMP.
CRT, DOW, HMP. RPC.
DOW, HMP, MON.
EK, CGY, HMP, WAY.
228
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970--Continued
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Nitrogenous Compounds --CorAimiei
Nylon, 6 and 6/6 polymer for fiber
Octadecyl isocyanate
Octadecyloxymethyltriethylammonium chloride
Oleamide (Octadecene amide)
Oleic acid, amine condensates
Oleonitrile (Octadecene nitrile)
Oleoylpalmitamide
*Pentaerythritol tetranitrate
Pentyl nitrate (Amyl nitrate)
Poly aery lamide
Polyacrylonitrile
Polyoxyalkylene amines
n- Propyl carbamate
Propyl isocyanate
Propyl nitrate
Quaternary ammonium compounds
Ricinolamide
*Sarcosine (N-Methylaminoacetic acid)
Semicarbazide base
Semicarbazide hydrochloride
*Stearamide (Octadecane amide)
'Stearic acid - ethylenediamine condensate (amine/aci
ratio=l/2).
Stearonitrile (Octadecanenitrile)
Stearylerucamide
Succinimide
Tallow amide, hydrogenated
Tallow nitrile
Tallow nitrile, hydrogenated
Tetracyanoethylene
N,N,N' ,N'-Tetrakis(2-hydroxypropyl)ethylenediamine--
Tetramethylguanidine
3,3'-Thiodipropionitrile
Thiosemicarbazide --
*Urea in compounds or mixtures, 100% basis:
*In feed compounds
*In liquid fertilizer
*In solid fertilizer
In plastics
All other
Urea - urethane copolymer
All other nitrogenous compounds
Acids, Acid Anhydrides, and Acyl Halides
*Acetic acid, synthetic, 100%
*Acetic anhydride, 100%:
From ace t aldehyde
From acetic acid
From ethylene
* Aery lie acid
ALF,
DEC,
DUP,
MON.
CWN,
MOB,
UPJ.
DAN.
ARC,
ASH,
FIN,
HUM.
CCW,
GAF,
GLY.
ARC,
ASH.
FIN.
COM,
DUP,
HPC.
TNA.
ACY,
HPC,
NLC.
DUP.
JCC,
NLC,
UCC.
BKL.
OTC.
TNA.
EK,
RSA,
WAY.
TKL.
CGY,
GAF,
HMP.
FMT.
FMT.
ARC,
ASH,
FIN,
HUM.
CCW,
DA,
GLY,
HUM, ICI
ASH.
FIN.
ASH.
ARC,
HUM.
ARC,
ASH.
ARC,
ASH.
KF,
NCA.
WYN.
ACY.
HAB.
ACY,
FMT.
ACN, ACY, AGY, DUP, FTX, GCC, JDC, MSC, PPC, SHC,
SOH, TER, TRI, VLN, WYC .
ACN, AGY, AKL, APD, ARM, BOR, CFA, CHN, CNC, DUP,
ESC, FCA, FTX, GCC, GDC, HKY, HPC, JDC, MSC, OMC,
PLC, PPC, SHC, SM, SNI, SOH, TER, TRI, VLN, WYC'
ACN, ACY, AGY, AKL, COL, DUP, GCC, GOC, HPC, JDC,
MON, MSC, OMC, PPC, SHC, SNO, SOH, TER, TRI, VLN,
WYC.
ACN, DUP, MON.
ACN, BOR, CNC, DUP, HPC, MSC, SHC, SNO,
TER, WYC.
DUP.
AAC, ABB, ACY, ALD, ARC, BKL, DUP, EK, EVN, JCC, GAF,
GNM, IDC, KF, LIL, MOB, MRK, NLC, OTC, PCW, PFZ,
PIC, RSA, S, SNW, UCC, USB, x, x.
BOR, GEL, EKT, FI4P, HPC, MON, PUB, UCC.
HPC.
GEL, EKT, FMP.
UCC.
BFG, CEL, DBG, UCC.
MISCELLANEOUS CHEMICALS
229
TABLE 2. — Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC— Continued
Acids, Acid Anhydrides, and Acyl HaZides--Continued
*Adipic acid
Azelaic acid
Behenic acid
BroDiinated fatty acids
Bromoacetic acid
Bromobutyric acid
tert-Butylacetyl chloride
tert-Butylperoxymaleic acid
Butylstannoic acid
* Butyric acid
Butyric anhydride
Butyryl chloride
Castor oil fatty acids, dehydrated
Chloroacetic acid, mono-
Chloroacetyl chloride
Citric acid
Crotonic acid (2-Butenoic acid)
Decanoyl chloride
Di-n-propylacetic acid and chloride--
Dipropylmalonic acid
Dodecanedioic acid
Dodecenylsuccinic acid
*Dodecenylsuccinic anhydride
Dodecylsuccinic anhydride
2-Ethylbutyric acid (Diethylacetic acid)
2-Ethylhexanoic acid (c-Ethylcaproic acid)
2-Ethylhexanoyl chloride
Formic acid, 90%
*Fumaric acid
Gluconic acid, tech
Glutaric anhydride
Glycolic acid (Hydroxyacetic acid)
n-Hexadecenylsuccinic anhydride
Isethionic acid C2-Hydroxyethanesulfonic acid)
Isoascorbic acid
Isobutyric acid
Isobutyric anhydride
Isobutyl chloride
Iso-octanoic acid
Itaconic acid (Methylenesuccinic acid)
2-Keto-D-gluconic acid
Lactic acid
*Lauroyl chloride
Levulinic acid
Maleic acid
*Maleic anhydride
Malic acid
Malonic acid
Mercaptoacetic acid (Thioglycolic acid)
3-Mercaptopropionic acid
Mercaptosuccinic acid CThiomalic acid)
Methacrylic acid
Methanesulfonic acid
2-Methylvaleric acid C2-Methylpentanoic acid)
Neodecanoic acid
Neodecanoyl chloride
Neopentanoic acid
Nonanoic acid [Pelargonic acid)
Nonenylsuccinic anhydride
Octadecylphosphonic acid
ACP,
EMR.
ASH.
DUP.
MCH.
GTL.
ALD.
WTL.
CCW.
CEL,
EKT,
CEL, DBC, DUP, ELP, MON, RH.
BUK,
DOW,
MLS,
EKT.
WTC,
CTN.
CTN.
X.
HMY.
ACS,
HN.
UCC.
EKT,
WTC,
DUP,
ACS,
DLI,
UCC.
DUP,
HMY.
GAP.
MRK,
EKT.
EKT.
WTL.
UCC.
PFZ.
MRK.
CLN,
CAD,
QKO.
ACS,
ACS,
ACS,
KF.
EVN,
EVN.
EVN.
DUP,
EK,
UCC.
ENJ.
WTC.
ENJ.
EMR,
HMY.
SM.
EKT, UCC.
UCC.
NTL.
, DOW, HPC, MON.
WTC.
, PFZ, WTC.
WTL.
HMY, MON.
UCC.
WTL.
UCC.
HN, MON, NTL, PCC, PFZ;
PFZ.
SNW.
MON.
GAF, HK, PFN, TEK^ UOP, WTC, WTL, x.
PFN, PFZ.
HN, KPS, MON, PCC, PTT, RCI.
BK.
RH.
PAS.
230
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.
-Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLlC--Continued
Aoids, Acid Anhydrides, and Aayl Halides- -Continued
Octanoyl chloride
Octenylsuccinic anhydride r--
Oleoyl chloride
Oxalic acid
Oxalyl chloride
*Palmitoyl chloride
Peroxyacetic acid
Pivaloyl chloride
*Polyacrylic acid
Polygalacturonic acid
* Propionic acid '
Propionic anhydride
Propionyl chloride
Sebacic acid
Sorbic acid (2,4-Hexadienoic acid)
Succinic acid
Succinic anhydride
d-Tartaric acid
Tetrahydroxysuccinic acid (Dioxytartaric acid)
Thioacetic acid
Thiolactic acid
3,3'-Thiodiprooionic acid
Trichloroacetic acid
Valeric acid
All other
Salts of Organic Acids
* Acetic acid salts:
Aluminum acetate
Ammonium acetate
Ammonium titanyl acetate
Barium acetate
Butyltin acetates
Cadmium acetate
Calcium acetate
Chromium acetate
Cobalt acetate
* Copper acetate
Lead acetate
Lead subacetate
Lead tetraacetate
Magnesium acetate
Manganese acetate
Mercuric acetate
Nickel acetate
* Potassium acetate
Silver acetate
* Sodium acetate
Sodium diacetate
Strontium acetate
*Zinc acetate
* Zirconium acetate
Other
Acrylic acid, sodium salt
Adipic acid, ammonium salt
Allylsulfonic acid, sodium salt
HK.
HMY.
GAP , HRT , UOP .
ACS, MAL, PFZ.
ALD.
GAP, OPC, PD, UOP.
FMB, UCC.
WTC, OTL.
AAE, DA, RH.
SKG.
CEL, COM, EKT, UCC.
EKT, UCC.
EK, UOP.
RH, WTH.
UCC.
ACS, BKC.
ACS.
BKC.
ACY.
EK, EVN.
EVN.
CCW, EVN, HAB.
DOW.
UCC.
ABB, ACY, ALD, DUP, EK, ENJ, GAP, HMY, PIC, RH, UCC,
WTC, X, X.
ACY,
UCC,
WTC.
ACS,
BKC,
MAL.
DUP.
ACS,
BKC.
CCW,
X.
MAL,
SHP.
ACS,
MAL.
ACY.
BKC,
HSH,
SHP.
ACS,
BKC,
SHP,
UCC.
BKC,
MAL.
ACS,
BKC,
MAL.
ARA.
ACS,
BKC.
HSH,
SHP.
MAL.
BKC,
HSH,
SHP.
ACS,
BKC,
CWL,
MAL,
UCC.
MAL.
ACS,
BKC,
CEL,
DAN,
EKT, MAL
UCC.
BKC.
ACS,
BKC,
HSH,
MAL,
SHP, UCC
HSH,
NTL,
TZC.
CCA,
CCW,
X.
AAE.
FIS.
NES.
MISCELLANEOUS CHEMICALS
231
TABLE 2.
-Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Salts of Organic 4ei<is--Gdntinued
Chloroacetic acid, sodium salt
Citric acid salts:
Ammonium citrate
Calcium citrate
Ferric ammonium citrate
Ferric citrate
Potassium citrate
Sodium citrate
Di-n-propylacetic acid, sodium salt
2-Ethylhexanoic acid (a-Ethylcaproic acid) salts:
Aluminum 2-ethylhexanoate
Barium 2-ethylhexanoate
Cadmium 2-ethylhexanoate
*Calcium 2-ethylhexanoate
*Cobalt 2-ethylhexanoate
Copper 2-ethylhexanoate
Iron 2-ethylhexanoate
*Lead 2-ethylhexanoate
*Manganese 2-ethylhexanoate
Nickel 2-ethylhexanoate
Potassium 2-ethylhexanoate
Rare earths 2-ethylhexanoate
Strontium 2-ethylhexanoate
*Zinc 2-ethylhexanoate
*Zirconium 2-ethylhexanoate
Other
Formic acid salts:
Aluminum formate
Ammonium f ormat e
Calcium formate
Chromic formate
Copper formate
Lead formate
Sodium formate, refined
Sodium formate, tech
Glucoheptonic acid salts:
Sodium glucoheptonate
Zinc glucoheptonate
Gluconic acid salts:
Ammonium gluconate
* Sodium gluconate
Glycolic acid, aluminum salt
9H-Hexadecaf luorononanoic acid, ammonium salt
Humic acids, sodium salts
Isoascorbic acid, sodium salt
►Lactic acid salts:
Ammonium lactate
Calcium lactate
Other
Laurie acid salts:
Barium cadmium laurate
Dibutyltin dilaurate
Zinc laurate
Linoleic acid salts:
Calcium linoleate
Cobalt linoleate
Copper linoleate
Lead linoleate
Manganese linoleate
DOW.
MAL, PFZ.
PFZ.
MAL, PFZ.
MAL.
MLS, PFZ.
DAN, MLS, NES, PFZ, SNW.
CTN.
PFZ,
CCA,
CCA,
cca;
CCA,
CCA,
CCA,
CCA,
CCA,
MCI.
CCA.
CCA.
CCA.
CCA,
cca;
EK,
WTC.
PFZ.
PFZ.
ccc, fer; hnx, hsh," mci; sw,' tro!
CGC; fer; hnx,' hsh; mci; srr; sw,' otc.
srr.
mci.
ccc; hnx, hsh, mci', ntl) srr. wtc.
hnx, mci, wtc.
hnx, hsh, mci, srr, wpc.
ccc, hnx, tro, wtc.
WTC, X.
WSN.
ACS, RSA.
COM.
GAF.
CTN.
NTL.
ACS, BKC,
COM, HPC.
PFN.
PFN.
PFZ.
CWL, DLI, PFZ, PMP.
CIB.
DUP.
NLC.
MRK.
TCC.
SHF.
EK, PFN, REH, WTC.
CCA, X.
CCA, X.
SNW.
CCA, SHP.
HSH, SHP.
SHP.
SHP.
SDH, SHP.
232
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS,. ACYCLIC--Continued
Salts of Organic ;4ei(is--Continued
Maleic acid salts:
Dibutyltin maleate
Lead (tribasic) maleate
Malonic acid, calcium salt
*Mercaptoacetic acid (Thioglycolic acid) salts:
Ammonium mercaptoacetate
Ant imony mercaptoacetate
Calcium mercaptoacetate
Dibutyltin mercaptoacetate
Potassium mercaptoacetate
Sodium mercaptoacetate
Mercaptopropionic acid, dibutyltin salt
Methacrylic acid, sodium salt
Methylsuccinic acid, disodium salt
Neodecanoic acid salts:
Cadmium neodecanoate
Calcium neodecanoate
Cobalt neodecanoate
Copper neodecanoate
Lead neodecanoate
Lithium neodecanoate
Manganese neodecanoate
Zinc neodecanoate
Zirconium neodecanoate
*Octanoic acid (Caprylic acid) salts:
Aluminum octanoate
Barium cadmium octanoate
Stannous octanoate
Zinc octanoate
Other
*01eic acid salts:
Aluminum oleate
Ammonium oleate
Barium zinc oleate
Chromium oleate
Copper oleate
Lead oleate
Stannous oleate
Oxalic acid salts:
Ammonium oxalate
Ferric ammonium oxalate
Ferric oxalate
Ferric sodium oxalate
Potassiumbinoxalate
Potassium oxalate
Sodium oxalate
Palmitic acid salts:
Aluminum palmitate
Zinc palmitate
Other
Phosphorodithioic acid salts (Dithiophosphates) :
Sodium di-sec-butyl diethyl phosphorodithioate
Sodium di-sec-butyl phosphorodithioate
Sodium diethyl phosphorodithioate
Sodium dihexyl phosphorodithioate
Sodium diisopropyl phosphorodithioate
Other
*Polyacrylic acid salts:
Ammonium polyacrylate
Potassium polyacrylate
Sodium polyacrylate
CCA,
x.
NTL.
GIV.
EVN,
HAB, TNI.
CCA.
EVN.
CCA.
EVN.
EVN.
CCA,
X.
AAE.
SDW.
CCA.
CCA,
MCI.
MCI.
MCI.
MCI.
MCI.
MCI.
CCA,
MCI.
MCI.
DA.
CCA.
CCW,
X.
BKC.
DA.
WTC.
MCI.
m-c.
SHP.
SHP,
WTC.
SHP.
CCW,
X.
ACS,
PFZ.
PFZ.
BKL,
PFZ.
PFZ.
BKC.
BKC,
PFZ.
BKC,
MAL.
DA,
WTC.
ACY,
DA, WTC.
DA.
ACY.
ACY.
ACY.
ACY.
ACY.
ACY.
BFG.
BFG.
ALC,
BFG, DA,
MISCELLANEOUS CHEMICALS
233
TABLE 2. — Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Salts of Organic 4ctds--Continued
Polymethacrylic acid, sodium salt
Propionic acid salts:
*CaIcium propionate
* Sodium propionate
Zinc propionate
Ricinoleic acid salts:
Calcium ricinoleate
Lithium ricinoleate
Sodium ethyl oxalacetate
Sodium polypectate
Sodium sorbitol borate
Sorbic acid salts:
Potassium sorbate
*Stearic acid salts:
'Aluminum stearates:
*Aluminum distearate
*Aluminum monostearate
*Aluminum tristearate
Ammonium stearate
Barium stearate
*Cadmium stearate
*Calciura stearate
Copper stearate
Ferric stearate
Ferrous stearate
Lead stearate
'Lithium stearate
'Magnesium stearate
Manganese stearate
Nickel stearate
Strontium stearate
*Zinc stearate '■
All other
Succinic acid, sodium salt
Tartaric acid salts:
Antimony potassium tartrate
Potassium bitartrate
Potassium sodium tartrate
Sodium bitartrate
Vinylsulfonic acid, sodium salt
Xanthic acid salts:
Potassium ethylxanthate
Potassium hexylxanthate
Potassium isopropylxanthate
Potassium pentylxanthate
Sodium n-butylxanthate
Sodium sec-butylxanthate
Sodium ethylxanthate
Sodium isobutylxanthate
Sodium isopropylxanthate
All other ,-.
All other salts of organic acids
Aldehydes and Ketones
*Acetaldehyde
'Acetone:
'From cumene
From isopropyl alcohol
Other
HFT, PFZ, UCC, WSN.
HFT, PFZ, UCC, WSN.
BKC.
NTL.
NTL.
FMP.
SKG.
APD.
UCC.
ACY, DA, JTC,
MAL,
NOC
SYP
WTC.
DA, MAL, SYP,
WTC
DA, MAL, NOC,
SYP.
DA, MCI, NOC,
WTC.
DA, NOC, SYP.
DA, NOC, SYP,
WTC.
acy; da; hnx.
JTC,
MAL
NOC
SYP; WTC
NOC.
MCI.
NOC, WTC.
DA, MCI, NOC,
WTC.
DA, NOC, SYP,
wrc.
ACY, DA,' JTC,
MAL,
NOC
SYP
WTC.
NOC.
nrrc.
MAL.
ACY, CCA, DA,
HNX,
JTC
MAL'
NOC, SYP
APD; DA', NOC,
SYP,
WTC.
MAL.
PFZ.
ACY.
PFZ.
PFZ.
X.
ACY, DOW.
DOW.
DOW.
ACY, DOW.
KCC, USR.
ACY, DOW.
ACY, DOW.
DOW.
DOW.
ACY.
CCW,' DA", EK,
FIN,
KCH,
NTL,
PD., , RSA .
CEL, DUP, EKT, EKX, MON, PUB, SHC, UCC.
ACP, CLK, HPC, MON, PCC, SHC, SKO, SOC, UCC.
EKT, ENJ, SHC, UCC. '
CEL, DIX; HPC.
234
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.
-Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers ' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Aldehydes and Xetones--Continued
Acetone, crude
Acrolein (Acrylaldehyde)
Aldol (Acetaldol)
*2-Butanone (Methyl ethyl ketone)
But yr a Idehyde
e-Caprolactone
Chloral (Trichloroacet aldehyde)
5-Chloro-2-pentanone
l-Chloro-l-penten-3-one (B-Chlorovinyl ethyl ketone) -
Chloro-2-propanone (Chloroacetone)
Crotonaldehyde
l,4-Dihydroxy-2-butanone
l,3-Dihydroxy-2-propanone (Dihydroxyacetone)
Diisopropyl ketone (2,4-Diniethyl-3-pentanone)
2 -Ethylbutyr aldehyde
2-Ethylhexanal (a-Ethylcaproaldehyde)
2-Ethyl-2-hexen-l-al (2-Ethyl-3-propylacrolein)
Ethyl ideneacetone
*Formaldehyde (37% by weight)
Glutaraldehyde
Glyoxal
2-Heptanone (Methyl amyl ketone)
3-Heptanone (Ethyl butyl ketone)
Hexadienal
Hexaldehyde
2 , 5-Hexanedi one (Acetony lacetone)
2 -Hydroxy- 2-iiiethyl-3-butanone
*4-Hydroxy-4-methyl-2-pentanone (Diacetone alcohol)---
Isobutyraldehyde
Isopentaldehyde, mixed isomers
Isovalerone (Diisobutyl ketone)
Methacrylaldehyde (Methacrolein)
4-Methoxy-4-methy 1-2 -pent anone
2 -Met hylbutyra Idehyde
5-Methyl-2-hexanone (Methyl isoarayl ketone)
Methyl hexenone
*4-Methyl-2-pentanone (Methyl isobutyl ketone)
Methy Ipent enal ,-
4-Methyl-3-penten-2-one (Mesityl oxide)
Methy Ipseudoionone
2-Methylvaleraldehyde (2 -Methy Ipent aldehyde)
Paraformaldehyde
Paraldehyde (Paracetaldehyde)
2,4-Pentanedione (Acety lacetone)
2-Pentanone (Methyl propyl ketone)
Propionaldehyde
Pseudoionone
Tetrahydropseudoionone
2,6,8-Trimethyl-4-nonanone (Isobutyl heptyl ketone)--
Valeraldehyde
All other
Alcohols, Monohydpio, Unsubstituted
*Alcohols Cg or lower, unmixed:
Allyl alcohol
Amyl alcohols:
2-Methyl-l-butanol
2-Methyl-2-butanol (tert-Amyl alcohol)
1-Pentanol
2-Pentanol
OCC.
SHC, UCC.
UCC.
ATR, CEL,' Dix; EKTJ ENJ,' SHC,' UCC.'
CEL, EKX, UCC.
UCC.
DA, FMB, MTO.
SDW.
X.
EK.
CEL, EKT, UCC.
GAP.
BAX.
EKX.
UCC.
EKX, UCC.
UCC.
UCC. ,
ACN,' BOR; CBC, CBD] CEL', COM, DUP', GAP, GOC, HKD,
hn; hpc; mon, rci; rh,' ucc,' wcl.
UCC.
UCC.
LCI, UCC.
UCC.
UCC.
GIV.
RBC, UCC.
LIL.
CEL, SHC, UCC.
EKX, UCC.
UCC.
EKT, UCC.
UCC.
SHC.
UCC.
EKT, UCC.
UCC.
EKT, ENJ, SHC, UCC,
UCC.
SHC, UCC.
GIV.
UCC.
CEL, HN.
UCC.
UCC.
UCC.
EKX, UCC.
GIV.
GIV.
UCC.
UCC.
ALD, ARC, CEL, EK, HEX.
DOW, FMP, SHC.
UCC.
SHC.
UCC.
UCC.
MISCELLANEOUS CHEMICALS
235
TABLE 2.
-Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers ' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Alcohols, Monohydria, Unsubstituted
*Alcohols Cg or lower, unmixed--Continued
Butyl alcohols:
Primary:
*Iso (Isopropylcarbinol)
*Normal (n- Propylcarbinol)
Secondary (Methylethylcarbinol)
Tertiary (Trimethylcarbinol)
2,6-Dimethyl-4-heptanol (Diisobutylcarbinol)
*Ethyl alcohol, synthetic
*2-Ethyl-l-hexanol
2-Ethyl-4-methyl-l-pentanol
Heptyl alcohol
*Hexyl alcohol
Hexynol
*Iso-octyl alcohols
*Isopropyl alcohol
*Methanol, synthetic
2-Methyl-3-butyn-2-ol
4-Methyl-2-pentanol (1-Methylisobutylcarbinol)
3-Methyl-l-pentyn-3-ol (Methylparafynol)
*1-Octanol
*2-0ctanol (sec-Capryl alcohol)
Octanols, other
*Propyl alcohol (Propanol)
2-Propyn-l-ol
All other
*Alcohols Ciu or higher, unmixed:
*Decyl alcohols
3,9-Diethyl-6-tridecanol
3,6-Diinethyl-3-octanol
Dodecyl alcohol (Lauryl alcohol) (95%)
4-Ethyl-l-octyn-3-ol
*l-Hexadecanol (Cetyl alcohol) (95%)
*Hexadecyl alcohols, other
*1-Octadecanol (Stearyl alcohol) (95%)
cis-9-Octadecen-l-ol (Oleyl alcohol) --
Tetradecyl alcohols
1-Tridecanol
2,6,8-Trimethyl-4-nonanol
All other
*Mixtures of alcohols:
*C9 and lower only:
Amyl alcohols
Other
*Cio and higher only
•Cs to Ci2 and others
Polyhydrio Aloohols and Their Esters and Ethers
*Polyhydric alcohols:
1,3-Butanediol
1,4-Butanediol
1,2,4-Butanetriol -
2-Butene-l,4-diol
2-Butyne-l,4-diol
3-Chloro-l,2-propanediol (Glycerol a-chlorohydrin)-
2,5-Dimethyl-2,5-hexanediol
2,5-Dimethyl-3-hexyne-2,5-diol
2,2-Diinethyl-l,3-propanediol (Neopentyl glycol)
dbc, ekx, shc, ucc.
cel; co; dbc; ekx; enj,' shc,' tna, ucC
ENJ, SHC.
SHC, x.
UCC .
cel; EKX, ENJ, HPC; PUBj SHC, UCC, USI.
CEL, DBC, EKX, ENJ, SHC, UCC.
EKX.
EKX.
CO, EKX, ENJ, PC, TNA, UCC.
cue.
ENJ, HOU, PCC, TID, UCC.
ENJ, SHC, UCC.
acn; bor, cel; com,' dup; ESC, Goc; m', HPc; mon;
rh; ucc
cue.
SHC.
cue.
CO, OTH.
RH.
EKX
GOC, iff; pg;
CEL
EKX, UCC.
GAF
cue.
EK, GYR, ucc;
CO,"
ENJ, HOU, PCC, PG,
TID,
UCC.
cue
CO.
cue
ASH
CO, GIV, PG.
ENJ
ASH
CO, PG.
ASH
DUP.
CO,
ENJ, PG, UCC.
ENJ,
GOC, TID.
UCC.
GOC.
gEL,
ENJ, PUB, UCC.
CEL,
EKX.
ASH,
CO,' ENj; PG, SHC;
tna;
CO,-
EKx; Goc; pg; tna:
GAF, x.
GAF.
GAF.
GAF, x.
EVN.
cue.
cue.
EKX.
236
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.
-Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers ' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued
PolyhydFia Alcohols and Tifeir Esters
and Ethers — Continued
Polyhydric alcohols--Continued
*Ethylene glycol
2-Ethyl-l,3-hexanediol
2-Ethyl-2- Chydroxymethyl)-l,3-propanediol (Tri-
methylol propane J .
*Glycerol, synthetic
1,2,5-Hexanetriol
2- (Hydroxymethyl)-2-methyl-l,3-propanediol (Tri-
methylolethane) .
Mannitol
3-Mercapto-l,2-propanediol (Thioglycerol)
2-Methyl-2,4-pentanediol (Hexylene glycol)
2-Methyl-2-propyl-l,3-propanediol
*Pentaerythritol
♦Propylene glycol (1,2-Propanediol)
'Sorbitol
2,2,4-Trimethyl-l,3-pentanediol
All other
*Polyhydric alcohol esters:
1,3-Butanediol dimethacrylate
2- (2-Butoxyethoxy)ethyl acetate
2-Butoxyethyl acetate
Diethylene glycol chloroformate
2- (2-Ethoxyethoxy) ethyl acetate
2-Ethoxyethyl acetate
Ethylene glycol diacetate
Ethylene glycol dimercaptoacetate
Ethylene glycol dimethacrylate
Ethylene glycol hydroxyacetate
2-Ethyl-2- Chydroxyinethyl)-l,3-propanediol triacrylate
(Trimethylol propane triacrylate) .
2-Ethyl-2- (hydroxymethyl)-l,3-propanediol trimethacry-
late.
Glyceryl monoacetate (Monoacetin)
Glyceryl triacetate (Triacetin)
Glyceryl trioleate
Glycol adipate
2-Methoxyethyl acetate
Methoxytriethyleneglycol acetate
Pentaerythritol caprylate
Pentaerythritol pelargonate
Polyethylene glycol dimethacrylate
Sucrose oct a- acetate
Tetraethylene glycol diacrylate
Tetraethylene glycol dimethacrylate
Triethylene glycol diacrylate
Triethylene glycol dimethacrylate
2,2,4-Triniethyl-l,3-pentanediol monoisobutyrate
All other
*Polyhydric alcohol ethers:
Allyloxypolyethylene glycol
3-(Allyloxy)-l,2-propanediol (Allyl glyceryl ether) —
Bis(2-butoxyethyl) ether (Diethylene glycol di-n-
butyl ether) .
Bis(2-ethoxyethyl) ether (Diethylene glycol diethyl
ether.
CAU, CEL, DOW, DUP, EKX, GAP, HCH, JCC, MAT, OMC,
SHC, UCC; WYN.'
UCC.
CEL.
APD,
DOW,
FMP, SHC
CEL.
COM.
APD.
EVN.
CEL,
SHC,
UCC.
ABB,
BKL.
CEL,
COM,
HN, HPC,
RCI.
CEL,
DOW,
JCC, OCC
OMC
UCC, WYN.
APD,
BRD,
MRK, PFZ
EKX.
APD,
BKL,
cue, PHR
PIC
UCC.
SAR.
EKT,
UCC.
EKT,
UCC.
PPG.
EKT.
DOW,
UCC,
X.
EKT,
UCC.
EVN.
SAR.
CCA.
AAE.
SAR.
ARC,
HAL.
ARC,
EKT,
UCC.
GRO.
X.
UCC.
RBC.
DRW.
DRW.
SAR.
HPT,
PD.
AAE.
SAR.
AAE.
SAR.
EKX.
ARC,
EK,
EKX, EVN,
GLY,
SAR, USB, UCC, X
UCC.
SHC.
UCC.
UCC.
MISCELLANEOUS CHEMICALS
237
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Polyhydrio Alcohols and Their Esters
and fftfcers--Continued
*PoIyhydric alcohol ethers — Continued
Bis (hydroxyethyl) ether butynediol
Bis[2-(2-methoxyethoxy)ethyl] ether (Tetraethylene
glycol dimethyl ether) .
Bis (2-jiiethoxyethyl) ether (Diethylene glycol dimethyl
etherJ ■
l,4-Bis(vinyloxy3butane (1,4-Butanediol, divinyl
ether) .
*2-Butoxyethanol (Ethylene glycol monobutyl ether)
*2-(2-Butoxyethoxy)ethanol (Diethylene glycol mono-
butyl ether) .
*2-[2-(2-Butoxyethoxy)ethoxy]ethanol (Triethylene glycol
glycol monobutyl ether) .
l-Butoxyethoxy-2-propanol
*Diethylene glycol
Diethoxytetraglycol
Dimethoxyethane (Ethylene glycol dimethyl ether)
*Dipropylene glycol
*2-Ethoxyethanol (Ethylene glycol monoethyl ether)
*2- (2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl
ether) .
2-[2-(2-Ethoxyethoxy)ethoxy]ethanol (Triethylene
glycol monoethyl ether) .
2-Hexyloxyethanol
2- [2- (Hexyloxy)ethoxy]ethanol
2-Isobutoxyethanol
l-IsobutoXy-2-propanol (Propylene glycol isobutyl
ether) .
*2-Methoxyethanol (Ethylene glycol monomethyl ether)
*2-(2-Methoxyethoxy)ethanol (Diethylene glycol mono-
methyl ether) .
*2-[2- (2-Methoxyethoxy)ethoxy]ethanol (Triethylene glycol
monomethyl ether) .
2-(2-Methoxyethoxy)ethyl 2-methoxyethyl ether (Tri-
ethylene glycol dimethyl ether) .
Methoxypolyethylene glycol
l-Methoxy-2-propanol
3- (3-Methoxypropoxy)propanol
3- [3- (3-Methoxypropoxy)propoxyl]propanol
Methyl butynoxyethanol
Polybutylene glycol
Polyethoxyethyl glycerol
Polyethoxyethylsorbitol
* Polyethylene glycol
*Polypropoxy ethets:
*Glycerol tri(polyoxypropylene) ether
*Other
*Polypropylene glycol
Polytetramethylene ether glycol
Tetraethylene glycol
1,1,3,3-Tetramethoxypropane
2,2'-Thiodiethanol (Thiodiglycol)
*Triethylene glycol
Tripropylene glycol
All other
GAF.
ASL.
ASL, OMC.
GAF.
DOW, EKX, OMC, SHC, UCC.
DOW, EKX, OMC, SHC, UCC.
DOW, OMC, UCC.
CAU,
CEL,
DOW,
EKX,
GAF,
hch;
JCC,
MAT,
OMC,
SHC
UCC; WYN.'
UCC.
ASL,
WYN.
DOW,
JCC,
OCC,
OMC,
UCC.
DOW,
EKX,
JCC,
OMC,
UCC.
DOW,
EKX,
JCC,
OMC,
UCC.
DOW,
OMC,
UCC.
UCC.
UCC.
EKX,
UCC.
DOW.
CBN, CO, DOW, EKX, JCC,' HCH; OMC, UCC,
DOw; EKx; JCC,' hch; omc; ucC
DOW, OMC, UCC.
ASL.
JCC, UCC.
DOW, JCC, UCC.
DOW, UCC.
DOW.
cue.
NLC.
GLY.
APD, GLY, TCH.
DA,' DOW,' DUP; GAp; HDCi JCC," MAT, NLC, OMC, PCS,'
UCC; WYN."
JCC, OMC, UCC, WYN.
APD, DA," DOW," JCC, UCC,' WYN.'
DOW," Jcc; hdg; NLC,' omc; ucc; wyn."
QKO, X.
DOW, EKX, UCC
KF, UCC.
HAB, UCC.
CAU, CEL, DOW, EKX,' GAF, HCH, JCC, MAT, OMC,' SHC,
UCC.'
DOW, HDG, UCC.
DOW," EKX," GAF, UCC,' UPJ.
462-669 O - 72 - 16
238
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2; --Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Esters of Monohydrio Alcohols
Allyl methacrylate
Amy I acetates, 90%:
Isopentyl acetate (Isoamyl acetate)
n-Pentyl acetate
Mixed
Butyl acetates:
ISO --
*Normal
Secondary
Tertiary
•Butyl aery late
n-Butyl 4,4-bis [tert-butylperoxy)valerate
Butyl butyl lacetate
Butyl chloroacetate
sec- Butyl chlorof ormat e
Butyl lactate
Butyl maleate, mono-
tert- Butyl peroxyacetate
tert- Butyl peroxy-2-ethylhexanoate
tert- Butyl peroxyisobutyrate
tert- Butyl peroxyisononanoate
tert- Butyl peroxyisopropy I carbonate
tert -Butyl peroxypivalate
Cetyl lactate ^
Chloromethyl pivalate
Diallyl maleate
Di (sec-butyl) chlorof ormat e
D ibut y 1 f umarat e
*Dibutyl maleate
Di (sec-butyl) peroxydicarbonate
Diethyl sec-butyl ethylmalonate
Diethyl butylmalonate
Diethyl sec-butylmalonate
♦Diethyl carbonate [Ethyl carbonate)
Diethyl diethylmalonate (Diethyl malonic ester)
Diethyl (ethoxymethylene)malonate
Diethyl ethylmalonate (Ethyl malonic ester)
Diethyl ethyl (l-methylbutyl)malonate (Ethyl-1-methyl-
butyl malonic ester) .
Di (2-ethylhexyl) chloroformate
Di(2-ethyl-l-hexyl) f umarat e
Di(2-ethyl-l-hexyl) maleate
Di (2-ethyl-l-hexyl) peroxydicarbonate
Diethyl maleate
Diethyl malonate (Malonic ester)
Diethyl (1-methylbutyl) malonate
Diethyl oxalate (Ethyl oxalate)
Diisobutyl maleate
Di-iso-nonyl maleate
Diisopropyl peroxydicarbonate (Isopropyl percarbonate)-
Dilauryl maleate
*Dilauryl 3,3' -thiodipropionate
Dimethyl carb onate
2,5-Dimethylhexane 2,5-diperoctoate
Dimethyl maleate
Dimethyl malonate
Dimethyl methoxymethylene malonate--
Di(4-methyl-2-pentyl) maleate
Dimyristyl 3, 3 '-thiodipropionate
*Dioctyl maleate
*Distearyl 3, 3' -thiodipropionate
Dithiobis (stearyl propionate)
NW,
ucc.
PFW.
PUB.
EKT,
EKX,
ENJ,
UCC.
CEL,
EKT,
ENJ
PUB,
SHC,
UCC
EKT,
ENJ,
HPC
PUB,
SHC.
EK.
CEL,
DBC,
RH,
UCC.
WTL.
RT.
MON.
CTN.
COM.
PCC.
WTL.
WTC,
WTL.
nrrc,
WTL.
WTL.
PPG,
WTL.
WTC,
WTL.
VND.
BJL.
FMP.
WTL.
MON,
PFZ,
RCI
RUB.
cue,
Dup;
MON
pcc;
RCI,
RUB
IVTL.
CTN,
FMP,
OTC.
BPC,
LIL.
KF.
LIL.
ABB.
WTL.
RUB.
HRT,
RUB.
WTL.
ACY,
UCC.
ABB,
KF,
LIL.
ABB,
LIL.
FMP.
RUB.
RUB.
PPG.
EFH.
ACY,
CCW
EVN, HAB.
CTN.
WTC.
AAC.
KF.
KF.
RUB.
CCW.
MON,
PCC
RCI.
ACY,
CCW
EVN, HAB.
EVN.
MISCELLANEOUS CHEMICALS
239
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued
Esters of Monohydrio Alcohols --Continued
Ditridecyl maleate
DiCtridecyl) 3,3'-thiodipropionate
*Ethyl acetate (85%)
Ethyl acetoacetate
*Ethyl aery late
*Ethyl chloroacetate
Ethyl ch 1 or of ormat e
Ethylene carbonate
2-Ethyl-l-hexyl acetate
*2-Ethyl-l-hexyl aery late
2-Ethyl-l-hexyl methacrylate
Ethyl propionate
Ethyl silicate (Tetraethoxysilane)
Ethyl sulfate (Diethyl sulfate)
Fatty acid esters, not included with plasticizers or
surface-active agents;
Butyl palmitate
Dimethyl brassylate
Ethyl stearate
Hexadeeyl stearate
Isopropyl linoleate
Methyl esters of coconut oil
*Methyl esters of tallow
Methyl 12-hydroxystearate---!
Methyl myristate
Methyl stearate
Myristyl myristate
All other
Glycidyl aery late
Glyeidyl methacrylate
Hexyl acetate
Isobutyl aery late
Isobutyl ehlor of ormat e
Isobutyl isobutyrate
Isodeeyl aery late
Iso-oetyl mereaptoacetate
Iso-octyl 3-mereaptopropionate
Isopropyl acetate
Isopropyl chloroformate
Lauryl lactate
Lauryl stearyl thiodipropionate
Maleic esters and copolymers
Methallylidene diacetate
Methyl acetate
Methyl acetoacetate
Methyl acrylate, monomer
Methyl borate
Methyl chloroacetate
Methyl chloroformate
Methyl diehloroacetate
Methyl formate
*Methyl methacrylate, monomer
4-Methyl-2-pentyl acetate
Methyl sulfate (Dimethyl sulfate)
Methyl vinyl acetate
Myristyl lactate
Octadecyl 3-mercaptopropionate
*Phosphorus acid esters :
Bis(2-ethylhexyl) hydrogen phosphate
Bis(2-ethylhexyl) hydrogen phosphite
Butyl hydrogen phosphates
Dibutyl butylphosphonate
Dibutyl hydrogen phosphite
RUB
EVN
HAB.
CEL-
EKT,' EKX'
ENj; mon; pub; ucc
EKT
UCC.
CEL
DBC, RH,
SNW, UCC
DOW,
KF, MON.
CTN
FMP, OTC
JCC
EKT
UCC.
CEL
DBC, UCC
X.
NW.
SFA.
UCC.
AAE
DA.
EMR.
ARS.
ICI.
VND.
PG.
BFR,
CHL, HUM.
HUM,
NTL.
PG.
DA.
VND.
BFR,
CCA, HUM.
AAE.
AAE.
ENJ.
DBC,
RH, UCC.
OTC.
EKX.
UCC.
CCW,
EVN, HAB.
EVN.
EKT,
ENJ, HPC,
UCC.
CTN,
PPG.
VND.
EVN.
GAF.
UCC.
EK,
HON, UCC.
EKT,
UCC.
CEL,
DBC, RH.
MHI,
SFA.
DOW,
KF.
CTN,
FMP.
PD.
CEL,
DUP.
ACY,
DUP, RH.
SHC,
UCC.
DUP.
UCC.
VND.
EVN.
SM, UCC.
SM.
SM.
SM.
SM.
240
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.-
-Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Esters of Monohydria Alcohols - -Continued
'Phosphorus acid esters — Continued
Didodecyl hydrogen phosphate
Dimethyl hydrogen phosphite
Dimethyl methylphosphonate
Dioleyl hydrogen phosphite
Iso-octyl hydrogen phosphate
Methyl hydrogen phosphates
Oleyl hydrogen phosphate
Tributyl phosphate
Tributyl phosphite
Tridecyl phosphite
Triethyl phosphite
Tri iso-octyl phosphite
Triisopropyl phosphite
Trimethyl phosphate
Trimethyl phosphite
Tris(2-chloroethyl) phosphite
Tris (chloroisopropyl) thionophosphate
Tr is C2 , 3-dibromopropy 1 ) phosphate
Tris (2-ethylhexyl) phosphite
TrisCoctadecyl) phosphite
All other
*Propyl acetate
Propylene carbonate
Tetraoctyl orthosilicate
Titanic acid esters:
Tetrabuty 1 t itanat e
Tetraisopropyl titanate
Tetrakis(2-ethylhexyl) titanate
Other
Triethyl orthoacetate
Triethyl orthoformate
Triethyl orthopropionate
Triisodecyl orthoformate
Trimethyl orthoformate
*Vinyl acetate, monomer
All other
Halogenated Hydroaarbons
1-Bromobutane (n-Butyl bromide)
2-Bromobutane (sec-Butyl bromide)
Bromochloromethane
l-Bromo-3-chloropropane (Trimethylenechlorobromide)-
2-Bromo-2-chloro-l,l, 1-trif luoroethane
Bromoethane (Ethyl bromide)
l-Bromo-3-methylbutane (Isoamyl bromide)
l-Bromo-3-methyl-2-butene
1 - Bromo- Oct adecane
1-Bromo-octane (n-Octyl bromide)
2-Bromopentane (1-Methylbutyl bromide)
1-Bromopropane (n-Propyl bromide)
2-Bromopropane (Isopropyl bromide)
Bromotrichloromethane
Bromotrifluoromethane
*Carbon tetrachloride
'Chlorinated paraffins:
Less than 35% chlorine
*35%-64% chlorine
65% or more chlorine
2-Chloro-l,3-butadiene
DUP.
SM.
SM.
SM.
SM.
HK.
SM.
COM.
SFI, SM.
HK.
SM.
SM.
SM.
TNA.
TNA.
MCH.
SM.
SM.
DUP, MON, SM, WES.
CEL, EKT, PUB, UCC.
DOW, JCC.
MON.
DUP.
DUP.
DUP.
DUP.
EK, KF.
KF.
KF.
KF.
KF.
BOR, CEL, cue, DUP, MON, NSC, UCC.
ald; cel; ctn,' dup; bfh, ek; ekx; emr; evn; fmp;
gaf, lil, pcc; pub, rh,' tni', ucc; vnd', wtl.
ABB
BPC
ABB
EK,
MCH.
DOW
MCH
ICl
DOW
GTL
MCH.
LIL.
SDW
DUP
GAF
MCH.
ABB,
LIL
PD.
BPC,
EK.
BPC.
MCH.
DUP.
ACS,
DA,
DOW, FMB, FRO, PPG, SFI, TN;
DA,
DVC.
CCH,
DA,
DVC, HK, HPC, ICI, KPS, NEV
DA,
DVC,
NEV.
DUP
MISCELLANEOUS CHEMICALS
241
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers ' identification codes
(according to list in table 3}
MISCELUNEOUS CHEMICALS, ACYCLIC--Continued
Halogenated Hydrocarbons — Continued
l-Chlorobutane (n-Butyl chloride)
2-Chlorobutane (sec-Butyl chloride)
l-Chloro-l,l-difluoroethane
*Chlorodifluoromethane
*Chloroethane (Ethyl chloride)
*Chloroform
*Chloromethane (Methyl chloride)
2-Chloro-2-methylpropane (tert-Butyl chloride)
3-Chloro-2-methylpropene (Methallyl chloride)
Chloropentafluoroethane
3-Chloropropene (Allyl chloride)
Chlorotrifluoroethylene (Trifluorovinyl chloride) --
Chlorotrifluoroethylene, polymerized
Chlorotrifluoromethane
Dibromodifluorome thane
*l,2-Dibromoethane (Ethylene dibromide)
Dibromomethane (Methylene bromide)
1,4-Dibromopentane
1,3-Dibromopropane
l,2-Dibromo-l,l,2,2-tetrafluoroethane
Dichlorobutadiene
l,3-Dichloro-2-butene
1,4-Dichlorobutene
*Dichlorodifluoromethane
*l,2-Dichloroethane (Ethylene dichloride)
*Dichloroniethane (Methylene chloride)
*l,2-Dichloropropane (Propylene dichloride)
2,3-Dichloropropene
Dichlorotetrafluoroethane
1,1-Difluoroethane
Difluorotetrachloroethane
Diiodomethane (Methylene iodide)
Hexafluoropropylene, monomer
lodoethane (Ethyl iodide), tech
*Iodomethane (Methyl iodide) ;
1-Iodoperf luorohexane
Octafluorocyclobutane
1,1,2,2-Tetrabromoethane (Acetylene tetrabromide) —
l,l,2,2-Tetrachloro?thane (Acetylene tetrachloride) -
*Tetrachloroethylene (Perchloroethylene)
Tetrafluoroethylene, monomer
Tetrafluoroethylene, polymer
Tetrafluoromethane
*l,l,l-Trichloroethane (Methyl chloroform)
1,1,2-Trichloroethane (Vinyl trichloride)
*Trichloroethylene
*Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,3-Trichloropropene
Trichlorotrifluoroethane
Vinyl bromide (Bromoethylene)
*Vinyl chloride, monomer (Chloroethylene)
Vinyl fluoride
Vinylidene chloride, monomer (1,1-Dichloroethylene)-
Vinylidene fluoride
All other
PUB
EK,
ACS
ACS,
AME,
ACS,
ACS,
EK.
FMP.
DUP.
DOW,
ACS,
MMM.
DUP,
DOW.
DOW,
DOW,
SDW.
MCH.
DUP,
DUP.
DUP.
DUP.
ACS,
ACS,
ACS,
DOW,
DOW.
ACS,
ACS,
DUP.
NTH,
DUP.
EK,
EK,
TKL,
DUP.
DOW.
DUP.
da;
DUP,
ACP,
DUP.
DOW,
DOW,
DA,"
ACS,
DOW,
DOW.
ACS,
DOW.
Acs;
DUP.
DOW,
DUP.
ald;
UCC.
PLC.
DUP, PAS.
DUP, KAl, PAS.
Dow; DUP," Hpc," ppg; shc; tna".
da; DOW," DUp; fro; sfi:
anm; dcc,' dow," dup," fro; tna; ucc'
shc.
MMM.
gtl, hch, mch, tna.
ucc.
dup, kai, pas, ucc.
ame; bfg; co; da; dow; fro; jcc; ppg; tna", ucc.
DA," DOW,' dup; fro; sfi.'
jcc, ucc.
DUP.
DUP.
FMT, RSA.
FMT, NTB, RSA.
dow; dup; fro," hk; ppg; sfi, tna; ttx;
PAS, TKL.
DUP, PAS, TKL.
FRO, PPG, TNA.
UCC.
Dow.'Dup; hk; ppg; tna', ttx."
DUP,' KAi; PAS; UCC.
SHC, UCC.
DUP, UCC.
ame; bfg; CO,' da; dow; hn; mno,' ppg," tna.
FRO.
DUp; ek; gaf; hmy; mch, tkl.
462-669 O - 72 - 17
242
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2. — Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970 — Continued
Manufacturers ' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Alt Other Miscellaneous Acyclic Chemicals
Acetyl peroxide
Aluminum isoproDnxide (Aluminum isopropylate)
* 2-Butanone peroxide-
*tert- Butyl hydroperoxide
*tert-Butyl peroxide (Di-tert-butyl peroxide)
But yro lactone
*Carbon disulfide
2-Chloroethanol (Ethylene chlorohydrin)
Decanoyl peroxide
Di aldehyde starch
2 , 3-D ibromopropanol
Diketene
2,5-Dimethyl-2,S-bis (2-ethyl-l-hexanoylperoxy)hexane --
2,S-Dimethyl-2,S-di (tert-butylperoxy)hexane
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexyne-3
2 ,5 -Dimethyl- 2, 5-dihydroperoxyhexane
Epoxides, ethers, and acetals:
Acetone dimethylacetal (2,2-Dimethoxypropane)
I-(Allyloxy)-2,3-epoxypropane (Allyl glycidyl ether)-
Bis (2-chloroethoxy)methane (Dichloroethylformal)
Bis(2-chloroethyI) ether (Dichlorodiethyl ether)
Bis(2-chloro-l-methylethyl) ether (Dichloroisopropyl
ether) .
l-Butoxy-2,3-epoxypropane (Butyl glycidyl ether)
Butyl ene oxide
Butyl ether (Di-n-butyl ether)
Butyl vinyl ether
2-Chloroethyl vinyl ether
Chloromethyl methyl ether
2,2-DichIoro-l, 1-dif luoroethyl methyl ether
Dimercaptodiethyl ether
Epichlorohydrin
*Ethylene oxide
*Ethyl ether:
Absolute
Tech
U.S.P
Ethyl vinyl ether
Glycidol (2,3-Epoxy-l-propanol)
Isobutyl vinyl ether
*Isopropyl ether
Methyl ether (Dimethyl ether)
Methyl vinyl ether
Octadecyl vinyl ether
* Propylene oxide
Other
Ethanedithiol
Ethanethiol .
2- (Ethylmercapto)ethanol
Fats and oils, chemically modified
Glucono-delta-lactone
WTL.
CHT,
KCH.
CAD
NOC, RCI, WTC, IVTL,
x.
CAD
NOG, OCC, WTC, IVTL.
CAD
NOC, SHC, WTC, WTL,
x.
GAP.
ACS,
PMB, PAS, PPG, SFI.
UCC.
WTC,
WTL.
MLS.
MCH.
ALD,
EKT, FMP.
WTL.
OTL.
WTL.
IVTC.
DOW.
AAC,
DOW, SHC.
TKL.
DOW.
DOW,
OMC.
DOW.
DOW.
PUB,
UCC.
GAP,
UCC.
UCC.
HK,
RH.
DOW.
EVN,
USR.
DOW,
SHC.
CAU,
CEL, DOw; EKX, GAP,
HCH; JCC, MAT,
NWP, OMC
SHC,' SNO, UCC, WYN.-
MAL.
ENJ,
HPC, UCC, USI.
MAL,
OMS.
GAP,
UCC.
DIX.
GAP.
ENJ,
SHC, UCC.
COM,
DUP, UCC.
GAP.
GAP.
GEL,
DOW, JGC, occ; oMc;
UCC, wyn;
ek; gap, ici', UCC.
CHL, DOM, SDW.
PPZ.
MISCELLANEOUS CHEMICALS
243
TABLE 2.
-Miscellaneous chemicals for which U.S. production or sales were reported,
identified by manufacturer, 1970- -Continued
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Atl Other Miscellaneous Acyolio Chemioals - -Continued
Glutaraldehyde bisCsodium bisulfite)
Hexachlorodimethyl sulfone
n-Hexadecyl disulfide
Hydrocarbons :
1-Butyne (Ethylacetylene)
n-Decane
n-Dodecane
Ethylene, from ethyl alcohol, medicinal grade
Hexadecane
Myrcene
1-Octadecene
n-Octane
Propyne CMethylacetylene)
Other
*Lauroyl peroxide
Magnesium methylate
Methanesulfanol
Methyl sulfide (Dimethyl sulfide)
Methyl sulfoxide
Organo-aluminum compounds:
Diethylaluminum chloride
Diethylaluminum iodide
Ethyl aluminum chlorides
Isobutylaluminum chlorides
Methyl aluminum chlorides
Triethylaluminum
Triisobutylaluminum
Other
Or gano -boron compounds
Organo-lead compounds;
*Tetraethyllead
Tetramethyllead
*Tetra (methyl-ethyl) lead
Organo- lithium compounds
Organo-magnesium halides
Organo-mercury compounds
Organo-silicon compounds:
Monomers
* Polymers
Organo-tin compounds:
Bis(tributyltin) oxide
Dibutyltin dichloride
Dibutylmethoxytin (Dibutyl tin methoxide)
Other
Organo- zinc compounds
Organo- zirconium compounds
Perchloromethanethiol (Perchloromethyl mercaptan)
*Phosgene (Carbonyl chloride)
Pine oil, synthetic
S-Propiolactone
Propionyl peroxide
Rare sugars
Sodium ethoxide
Sodium formaldehyde bisulfite
*Sodium formaldehyde sulfoxylate
*Sodium methoxide (Sodium methylate)
Sodium vinyl sulfonate
Succinyl peroxide
Tetrakis (hydroxymethyl)phosphonium chloride
Thallous ethoxide
Tributylphosphine
Trioctylphosphine oxide
*Zinc formaldehyde sulfoxylate
Other
IDC
SFA
PAS
cue
HMY
PLC.
HMY,
PLC.
OH.
HMY.
IFF,
NCI.
HMY.
HMY,
PLC.
cue.
HMY.
CAD,
TEK,
WTC, WTL, X.
MRT.
PAS.
CRZ.
CRZ.
TNA
TSA.
TSA.
TNA
TSA.
TNA,
TSA.
TNA.
TNA,
TSA.
TNA,
TSA.
TNA,
TSA.
ACS,
SFA,
TSA.
DUP,
HCH,
NLC, TNA.
DUP,
NLC,
TNA.
DUP,
HCH,
TNA.
FTE.
ARA.
EK,
NTB.
DCC,
UCC.
DCC,
ORO,
SFA, SPD, UCC.
CCW,
x.
CCW,
X.
CCA.
CCA,
CCW,
PCW, X.'
TSA.
LCI.
CHO.
ACS,
CTN,
DUP, MOB, OTC, PPG, RUC, UCC, UPJ, VDM x
CBY,
NCI.
CEL.
WTL.
PFN,
RSA.
FMP.
EK,
IDC.
DA,
RH, ROY.
DA,
DUP,
OMC, SFA, X.
cue.
IVTL.
HK.
ALD.
CCW.
DA, RH, ROY.
ald; alx; da, ek,' gaf, gnmI nes,' rsa] sdw,' sfa, tna,'
ucc,' wtl, x,' x.'
244
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 3. --Miscellaneous chemicals: Directory of manufacturers, 1970
ALPHABETICAL DIRECTORY BY CODE
[Names of miscellaneous chemical manufacturers that reported production or sales to the U.S. Tariff Commission for
1970 are listed below in the order of their identification codes as used in table 2]
Code
Code
identi-
Name of company
identi-
Name of company
fication
fication
AAC
Alcolac Chemical Corp.
CFA
Cooperative Farm Chemicals Association
AAE
American Aniline S Extract Co., Inc.
CFC
Sun Chemical Corp.
ABB
Abbott Laboratories
CGY
Ciba-Geigy Corp. :
Allied Chemical Corp.:
Ciba Pharmaceutical Co.
ACN
Agricultural Div.
CHH
Charles Hansen's Laboratory, Inc.
ACP
Plastics Div.
CHO
Stauffer Chemical Co., Calhio Chemicals,
ACS
Specialty Chemicals Div.
Inc. Div.
ACY
American Cyanamid Co.
CHN
Cherokee Nitrogen Co.
AGY
Agway, Inc., Nitrogen Div.
CHT
Chattem Drug § Chemical Co., Chattem
AKL
Arkla Chemical Corp.
Chemicals Div.
AKS
Arkansas Co., Inc.
CLK
Clark Oil 5 Refining Corp., Clark Chemical
ALB
Ames Laboratories, Inc.
Co.
ALC
Alco Chemical Corp.
CLN
Standard Brands, Inc., Clinton Com
ALD
Aldrich Chemical Co., Inc.
Processing Co. Div.
ALF
Allied Chemical Corp., Fibers Div.
CNC
Columbia Nitrogen Corp.
ALX
Alox Corp.
CNP
Columbia Nipro Co.
AMB
American Bio-Synthetic Corp.
CO
Continental Oil Co.
AME
American Chemical Corp.
COL
Collier Carbon § Chemical Corp.
ANM
Ancon Chemical Corp.
COM
Commercial Solvents Corp.
APD
Atlas Chemical Industries, Inc.
CP
Colgate-Palmolive Co.
ARA
Arapahoe Chemicals Div. of Syntex Corp.
CRN
CPC International, Inc.
ARC
Armour Industrial Chemical Co.
CRT
Crest Chemical Corp.
ARM
USS Agri-Chemicals, Div. of U.S. Steel Corp.
CRZ
Crown Zellerbach Corp., Chemical Products
ARS
Arsynco, Inc.
Div.
ARZ
Arizona Chemical Co.
CTN
Chemetron Corp., Organic Chemical Div.
ASH
Ashland Oil, Inc., Ashland Chemical Co. Div.
cue
Air Reduction Co., Inc., Chemicals §
ASL
Ansul Chemical Co.
Plastics Div.
ATR
Atlantic Richfield Co., ARCO Div.
CWL
Stauffer Chemical Co., Cowles Chemical Div.
AV
FMC Corp., American Viscose Div.
CWN
Upjohn Co., Carwin Organic Chemicals
AZT
Dart Industries, Inc., Aztec Chemicals Div.
DA
Diamond Shamrock Corp.
BAX
Baxter Laboratories, Inc.
DAN
Dan River Mills, Inc.
BFG
B. F. Goodrich Co., B. F. Goodrich Chemical
DBC
Dow Badische Co.
Co. Div.
DCC
Dow Coming Corp.
BFR
Pace National Corp.
DEX
Dexter Chemical Corp.
BJL
Burdick 5 Jackson Labs., Inc.
DIX
Dixie Chemical Co.
BKC
J. T. Baker Chemical Co.
DLl
Dawe's Laboratories, Inc.
BKL
Millmaster Onyx Corp., Millmaster Chemical
DOL
Dole Co., Div. of Castle 5 Cook, Inc.
Co. Div., Berkeley Chemical Dept.
DOM
Dominion Products, Inc.
BOR
Borden Co., borden Chemical Co. Div.
DOW
Dow Chemical Co.
BPC
Stauffer Chemical Co., Benzol Products Div.
DRW
Drew Chemical Corp.
BRD
Baird Chemical Industries, Inc.
DUP
E. I. duPont de Nemours § Co., Inc.
BUK
Buckeye Cellulose Corp.
DVC
Dover Chemical Corp.
CAD
Noury Chemical Corp.
EFH
E. F. Houghton 5 Co.
CAU
Calcasieu Chemical Corp.
EK
Eastman Kodak Co. :
CBC
Georgia-Pacific Corp.. Coos Bay Div.
EKT
Tennessee Eastman Co. Div.
CBD
Chembond Corp.
EKX
Texas Eastman Co. Div.
CBN
Cities Service Co.
ELP
El Paso Products Co.
CBY
Crosby Chemicals, Inc.
EMR
Emery Industries, Inc.
CCA
Cincinnati Milacron Chemicals, Inc.
ENJ
En jay Chemical Co.
CCC
Chase Chemical Corp.
ENZ
Enzyme Development Corp.
CCH
Pearsall Chemical Co.
ESA
East Shore Chemical Co., Inc.
ecu
Cincinnati Milacron Chemicals, Inc.
ESC
Air Products 6 Chemicals, Inc., Escambia
CEL
Celanese Corp. :
Plant
Celanese Chemical Co.
EVN
Evans Chemetics, Inc.
Celanese Fibers Co.
Celanese Plastics Co.
MISCELLANEOUS CHEMICALS
245
TABLE 3. — Miscellaneous chemicals: Directory of manufacturers, 1970 — Continued
Name of company
Code
identi-
fication
Name of Company
Farmers Chemical Association, Inc.
Ferro Corp., Ferro Chemical Div.
Fine Organics, Inc.
Fisher Chemical Co., Inc.
FMC Corp . :
Inorganic Chemicals Div.
Organic Chemicals Div.
Fairmount Chemical Co., Inc.
Vulcan Materials Co., Chemicals Div.
Foote Mineral Co.
CF Industries, Inc., Fel-Tex Plant
GAF Corp., Chemical Div.
Gane's Chemical Works, Inc.
W. R. Grace § Co., Agricultural Chemical Group
G. Frederick Smith Chemical Co.
Givaudan Corp.
SCM Corp. Glidden-Durkee Div.
Glyco Chemicals, Inc.
General Mills Chemicals, Inc.
Gulf Oil Corp., Gulf Oil Chemicals Co. -
llniteH States
Grain Processing Corp.
W. R. Grace § Co., Polymers § Chemicals Div.
Millmaster Onyx Corp., A. Gross § Co. Div.
Great Lakes Chemical Corp.
Goodyear Tire 5 Rubber Co.
Halby Products Co., Inc.
C. P. Hall Co. of Illinois
Houston Chemical Corp.
Hodag Chemical Corp.
Hexagon Laboratories, Inc.
Hoffman-Taff, Inc.
Hooker Chemical Corp.:
Durez Plastics Div.
Hawk eye Chemical Co.
W. R. Grace 8 Co., Hampshire Chemical Div.
Humphrey Chemical Co.
Tenneco Chemicals, Inc.:
Nuodex Div.
Air Products 5 Chemicals, Inc., Houdry
Process § Chemical Div.
Hercules, Inc.
Hart Products Corp.
Harshaw Chemical Co., Div. of Kewanee Oil
Co.
Kraftco Corp., Humko Products Chemical Div.
ICI America, Inc.
Industrial Dyestuff Co.
International Flavors 5 Fragrances, Inc.
Jefferson Chemical Co., Inc.
Nipak, Inc.
George A. Jeffrey's S Co., Inc.
J . Meyer § Sons , Inc .
Joseph Turner 8 Co.
Kaiser Aluminum § Chemical Corp., Kaiser
Chemicals Div.
Kennecott Copper Corp., Chino Mines Div.
Keystone Chemurgic Corp.
Kennecott Copper Corp., Utah Copper Div.
Kay-Fries Chemicals, Inc.
KON
KPS
KPT
LAM
LCI
LEM
LIL
LUB
MAL
MAT
MCH
MCI
MET
MHI
MLS
MMM
MNO
MOB
MON
MOR
MRK
MRT
MSC
MTO
MTR
NCA
NCI
NES
NEV
NLC
NOC
NOR
NPI
NSC
NTB
NTL
OMC
OMS
ONX
OPC
ORG
OTC
PAR
PAS
PCC
PCS
PCW
PD
PEN
PFN
PFW
PFZ
H. Kohnstamm S Co., Inc.
Koppers Pittsburgh Co.
Koppers Co., Inc., Organic Materials Div.
LaMotte Chemical Products Co.
Lachat Chemicals, Inc.
Lerake Chemicals, Inc.
Eli Lilly 5 Co. , Inc.
Lubrizol Corp.
Mallinckrodt Chemical Works
Matador Chemical Co., Inc.
Michigan Chemical Corp.
Mooney Chemicals, Inc.
M 5 T Chemicals, Inc.
Ventron Corp., Chemicals Div.
Miles Laboratories, Inc., Marschall Div.
Minnesota Mining § Manufacturing Co.
Monochem, Inc.
Mobay Chemical Co.
Monsanto Co.
Mineral Oil Refining Co.
Merck 6 Co. , Inc.
Morton Chemical Co.
Mississippi Chemical Corp.
Montrose Chemical Corp. of California
Chris-Craft Industries, Inc., Montrose
Chemical Div.
Northrop Carolina, Inc.
Union Camp Corp., Chemical Div.
Nease Chemical Co., Inc.
Neville Chemical Co.
Nalco Chemical Co.
Norac Co., Inc. and Mathe Chemical Co. Div.
Norwich Pharmacal Co.
National Polychemicals, Inc.
National Starch § Chemical Corp.
National Biochemical Co.
National Lead Co.
Northwestern Chemical Co.
Northern Petrochemicals Co.
Oxirane Chemical Co.
Air Reduction Co., Inc., Ohio Medical
Products Div .
Olin Corp.
E. R. Squibb 6 Sons, Inc.
Millmaster Onyx Corp., Onyx Chemical Co.
Orbis Products Corp .
Chevron Chemical Co.
Ott Chemical Co.
Pennsylvania Refining Co.
Pennwalt Corp.
USS Chemicals Div. of U.S. Steel Corp.
Emery Industries, Inc.
Pfister Chemical Works
Parke, Davis 5 Co.
CPC International, Inc., Penick Div.
Pfanstiehl Laboratories, Inc.
Polak's Frutal Works, Inc.
Pfizer, Inc.
Procter & Gamble Co.
Pharmachem Corp.
246 SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 3. — Miscellaneous chemicals: Directory of manufacturers, 1970 — Continued
Code
Code
identi-
Name of company
identi-
Name of company
fication
fication
PIC
Pierce Organics, Inc.
SPD
General Electric Co., Silicone Products
PLB
P-L Bicchemicals, Inc.
Dept.
PLC
Phillips Petroleum Co. 5 Phillips Pacific
SPR
Scientific Protein Laboratories
Chemical Co.
SRR
Stresen-Reuter International, International
FLS
Plastics Engineering Co.
Minerals § Chemical Corp.
PMP
Premier Malt Products, Inc.
SW
Sherwin-Williams Co.
PPC
Premier Petrochemical Co.
SYP
Synthetic Products Co.
PPG
Pittsburgh Plate Glass Co.
PRD
Productol Chemical Co., Inc.
TAB
Chemetron Corp., National Cylinder Gas Div.
PIT
Petro-Tex Chemical
TCC
Tanatex Chemical Corp.
PUB
Publicker Industries, Inc.
TCD
Tenneco Chemical, Inc., Tenneco Colors Div.
TCH
Trylon Chemicals, Inc.
QKO
Quaker Oats Co.
TEK
Teknor Apex Co .
TER
Terra Chemicals International, Inc.
RBC
Roberts Chemicals Div. of Security
TID
Getty Oil Co.
Chemicals, Inc.
TKL
Thiokol Chemical Corp.
RCI
Reichhold Chemicals, Inc.
TNA
Ethyl Corp.
REH
Reheis Chemical Co. Div. of Armour
TNI
Gillette Chemical Co., Div. of Gillette Co.
Pharmaceutical Co.
TCC
Tanatex Chemical Corp.
REM
Remington Arms Co., Inc.
TRI
Triad Chemicals
RH
Rohm 5 Haas Co.
TRO
Troy Chemical Co.
ROY
Royce Chemical Co.
TSA
Texas Alkyls, Inc.
RPC
Millraaster Onyx Corp., Refined-Onyx Div.
TTX
Detrex Chemical Industries, Inc.
RSA
R.S.A. Corp.
TX
Texaco, Inc.
RT
F. Ritter § Co.
TZC
Tizon Chemical Corp.
RUB
Hooker Chemical Corp., Ruco Div.
RUC
Rubicon Chemicals, Inc.
UCC
Union Carbide Corp.
UOP
Universal Oil products Co., UOP Chemical Div.
S
Sandoz, Inc., Sandoz Colors S Chemical
UPJ
Upjohn Co.
Div.
UPM
Universal Oil Products Co.
SAR
Sartomer Resins, Inc.
UPR
Witco Chemical Corp., U.S. Peroxygen Div.
SBC
Scher Bros .
USB
U.S. Borax Research Corp.
SDC
Martin-Marietta Corp., Southern Dyestuff
US I
National Distillers § Chemical Corp., U.S.
Co. Div.
Industrial Chemicals Co. Div.
Sterling Drug, Inc.:
USR
Uniroyal, Inc., Chemical Div.
SDH
Hilton-Davis Chemical Co. Div.
1
SDW
Winthrop Laboratories Div.
VDM
Van De Mark Chemical Co.
Stauffer Chemical Co.:
VEL
Velsicol Chemical Corp., Inc.
SFA
Specialty Chemical Div.
VGC
Virginia Chemicals, Inc.
SFI
Industrial Div.
VLN
Valley Nitrogen Producers, Inc.
SHC
Shell Oil Co., Shell Chemical Co. Div.
VND
Van Dyk 6 Co . , Inc .
SHF
Kraftco Corp., Sheffield Qiemical Co. Div.
VPC
Verona Corp.
SHL
Nitine, Inc. Div. of Shulton, Inc.
SHO
Shell Oil Co.
Way
Phillip A. Hunt Chemical Corp., Wayland
SHP
Shepherd Chemical Co.
Chemical Div.
SK
Smith, Kline 5 French Laboratories
WBC
Worthington Biochemical Corp.
SKG
Sunkist Growers, Inc.
WBG
White § Bagley Co.
SKO
Skelly Oil Co.
WES
Weston Chemical Corp.
SM
Mobil Oil Corp., Mobil Chemical Co. Div.
WM
Wilson Pharmaceutical S Chemical Corp.,
Industrial Chemical Div.
Wilson-Martin Div.
SNI
Kaiser Aluminum S Chemical Corp., Kaiser
WMP
Essex International, Inc.. Electro-
Agricultural Chemicals Div.
Mechanical Div.
SNO
SunOlin Chemical Co.
WSN
Mallinckrodt Chemical Works, Washine Div.
SNW
Sun Chemical Corp., Chemical Div.
WTC
Witco Chemical Co., Inc.
SOC
Standard Oil Co. of California, Chevron
WTH
Union Camp Corp., Harchem Div.
Chemical Co.
WTL
Pennwalt Corp., Lucidal Div.
SOH
Vistron Corp.
WYC
Wycon Chemical Co.
SOI
American Oil Co. (Maryland)
WYN
Wyandotte Chemicals Corp.
Note. --For complete names and addresses of the above reporting companies, refer to table 1 in the Appendix.
APPENDIX
DIRECTORY OF MANUFACTURERS 247
TABLE 1. --Synthetic organic chemicals: Alphabetical directory of manufacturers, by company, 1970
[Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. Tariff Conimission
for 1970 are listed below alphabetically, together with their identification codes as used in table 2 of the 14
individual sections of this report]
Name of company
Office address
A 5 E Plastik Pak Co., Inc
Abbott Laboratories
Abex Corp., American Brakelok Div
Acme Chemical Co
Agway, Inc., Nitrogen Div
Air Products § Chemicals, Inc.:
Escambia Plant
Houndry Process 5 Chemical Div
Air Reduction Co., Inc.:
> Chemicals 5 Plastics Div
Ohio Medical Products Div
Alco Chemical Corp
Alcolac Chemical Corp
Aldrich Chemical Co. , Inc
Alliance Chemical Co., Inc
Allied Chemical Corp.:
Agricultural Div
Fibers Div
Plastics Div
Specialty Chemicals Div
Union Texas Petroleum Div
Alox Corp
Alpha Laboratories, Inc
Amalgamated Chemical Corp
Amchem Products Inc
Amerace-Esna Corp., Chemical Specialties —
Div.
Amerada Hess Corp, Hess Oil § Chemical Div-
American Aniline 6 Extract Co., Inc
American Aniline Products, Inc
American Bio-Synthetics Corp
American Can Co
American Chemical Corp
American Cyanamid Co
American Hoechst Corp
American Oil Co. [Maryland)
American Oil Co. (Texas)
American Synthetic Rubber Corp
Ameripol, Inc
Ames Laboratories, Inc
Amoco Chemical Corp
Amoco Production Co
Ancon Chemical Corp
Ansul Chemical Co ■
Apex Chemical Co., Inc
Apollo Colors, Inc
Applied Plastics Cot
Arapahoe Chemicals Div. of Syntex Corp
Ardmore Chemical Co., Inc
Arenol Chemical Corp
Arizona Chemical Co
Arkansas Co., Inc
Arkla Chemical Corp
Armour-Dial, Inc
Armour Industrial Chemical Co
14505 Proctor, Industry, CA 91747.
14th St. and Sheridan Rd., N. Chicago, IL 60664.
2401 S. Loudoun (Paper Mill Rd.), Winchester, VA 22601.
2506 N. 32d St., Milwaukee, WI 53245.
1446 Buffalo St., Clean, NY 10760.
P. 0. Box 467, Pensacola, FL 32702.
1339 Chestnut Street, Philadelphia, Pa 19107.
150 E. 42nd St., New York, NY 10017.
3030 Airco Dr., P. 0. Box 1319, Madison, WI 53701.
Trenton Ave. and William St., Philadephia, PA 19134.
3440 Fairfield Rd., Baltimore, MD 21226.
940 W. St. Paul Ave., Milwaukee, WI 53233.
33 Avenue P, Newark, NJ 07105.
P. 0. Box 2061R, Morristown, NJ 07960.
1 Times Square, New York, NY" 10036.
P. 0. Box 365, Morristown, NJ 07960.
Columbia Rd. S Park Ave., Morristown, NJ 07960.
P. 0. Box 2120, Houston, TX 77001.
3943 Buffalo Ave., Niagara Falls, NY 14302.
1685 S. Fairfax St., Denver, CO 80222.
Ontario and Rorer Sts., Philadelphia, PA 19134.
Brookside Ave., Ambler, PA 19002.
74 Hudson Ave., Tanafly, NJ 07670.
1 Hess Plaza, Woolridge, NJ 07095.
Venango and F Sts., Philadelphia, PA 19134.
P. 0. Box 3063, Paterson, NJ 07509.
710 W. National Ave., Milwaukee, WI 53204.
American Lane, Greenwich, CT 06830.
2112 E. 223d St., Long Beach, CA 90810.
Wayne, NJ 07470.
129 Quidnick St., Coventry, RI 02816.
910 S. Michigan Ave., Chicago, IL 60680.
910 S. Michigan Ave., Chicago, IL 60680.
P. 0. Box 360, Louisville, KY 40201.
3135 Euclid Ave., Cleveland, OH 4411S.
200 Rock Lane, Milford, CT 06460.
130 E. Randolph Dr., Chicago, IL 60601.
P. 0. Box 591, Tulsa, OK 74102.
1 Stanton St., Marinette, WI 54143.
1 Stanton St., Marinette, WI 54143.
200 S. 1st St., Elizabethport, NJ 07206.
899 Skokie Blvd., Northbrook, IL 60062.
130 Penn St., El Segundo, CA 90245.
2855 Walnut St., Boulder, CO 80302.
840 Valley Brook Ave., Lyndhurst, NJ 07071.
40-33 23d St., Long Island City, NJ 11101.
Wayne, NJ 07470.
185 Foundry St., Newark, NJ 07105.
P. 0. Box 825, Helena, AK 72342.
Ill E. Wacker Dr., Chicago, IL 60601.
Ill E. Wacker Dr., Chicago, IL 60601.
248 SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. — Synthetic organic chemicals: Alphabetical directory of manufacturers, by company, 1970 — Continued
Name of company
Office address
Armour Pharmaceutical Co
Armstrong Chemco, Inc
Armstrong Cork Co
Arol Chemical Products Co
Arsynco, Inc
Ashland Oil, Inc
Ashland Chemical Co. Div
Astor Products, Inc., Blue Arrow Div
Astra Pharamaceutical Products, Inc^ — •-
Atco Chemical Industrial Products, Inc.,
Fine Chemicals Div.
Atlantic Chemical Corp
Atlantic Richfield Co., ARCO Chemical Co.
Div.
Atlas Chemical Industries, Inc
Atlas Processing Co
BASF Wyandotte Corp
BP Oil Corp
Baird Chemical Industries
J. T. Baker Chemical Co
Baltimore Paint 5 Chemical Corp
Baxter Laboratories, Inc
Bayoil Co., Inc
Beecham, Inc
Beech-Nut, Inc ■
Belding Chemical Industries
Bendix Corp. , Friction Materials Div
Bennett's . —
Benzenoid Organics, Inc--
Berncolors-Poughkeepsie, In.c
Blackman-llhler Chemical Co — -
Borden, Inc., Borden Chemical Div--
Borg-Warner Corp., Marbon Chemical Div---
Bristol-Meyers Co., Bristol Laboratories Div
M. A. Bruder (j Sons, Inc
Buckeye Cellulose Corp
Buckman Laboratories, Inc- ^ --
Budd Co., Polychem Div-- --.
Burdick 5 uTackson Laboratories, Inc. —
Burroughs Wellcome Co.
CF Industries, Inc., Fel-Tex Plant-
CPC International, Inc
Acme Resin Co. Div- — -- — .
Penick Div---
Samuel Cabot, Inc . .
Calcasieu Chemical Corp-. —
Carborundum Co., Coated Abrasives Div
Cargill, Inc
Carpenter-Morton Co -.
Carus Chemical Co., Inc-
Celanese Corp. of America-^ — ^ — -—
Celanese Coatings Co- ^--. ---. — --—
Champlin Petroleimi Co., Corpus Christ!
Refinery
Charmin Paper Products Co
Charter International Oil Co ---
Chase Chemical Corn
Chattem Drug 5 Chemical Co., Chattem
Chemicals Div
Chemagro Com .
Chembond Com
Chemetron Corp.:
National Cylinder Gas Div
Organic Chemical Div
Pigments Div
P. 0. Box 511, Kankakee, IL 60901.
1330 S. Kolbourn Ave., Chicago, IL 60623.
Liberty and Charlotte Sts., Lancaster, PA 17604.
371 Wayne St., Jersey City, NJ 07072.
P. 0. Box 8, Carlstadt, NJ 07072.
1401 Winchester Ave., Ashland, KY 41101.
1701 N. High St., Columbus, OH 43215 and P. 0. Box 149,
Baytown, TX 77520.
P. 0. Box B, Jacksonville, FL 32203.
7-1/2 Neponset St., Worcester, MA 01606.
93 Main St., Franklin, NJ 07416.
10 Kingsland Rd., Nutley, NJ 07110.
260 S. Broad St., Philadelphia, PA 19101.
Wilmington, DE 19899 and P. 0. Box 87, Joplin, MO 64801.
P. 0. Box 9188, 3S46 Midway St., Shreveport, LA 71109.
100 Cherry Hill Rd. , Parsippany, NJ 07054
and 1609 Biddle Ave., Wyandotte, MI 48192.
Midland Bldg., Cleveland. OH 44115.
22-10 Route 208, Fair Lawn, NJ 07410.
222 Red School Lane, Philipsburg, NJ 08865.
2325 Hollins Ferry Rd., Baltimore, md 21230.
6301 Lincoln Ave., Morton Grove, IL 60053.
2 Union St., Peabody, MA 01960.
65 Industrial S., Clifton, NJ 07012.
Church St., Canaioharie, NY 13317.
1439 Broadway, New York, NY 10018.
P. 0. Box 238, Troy, NY 12180.
65 W. Ist S. St., Salt Lake City, IIT 84110.
P. n. Box 157, Bellingham, MA 02019.
75 N. Water St., Poughkeepsie, NY 12602.
P. 0. Box 5627, Spartanburg, SC 29301.
350 Madison Ave., New York, NY 10017.
P. 0. Box 68, Washington, W\' 26181.
19 Mony Plaza, E. Syracuse, NY 13201.
52d St. and Grays Ave., Philadelphia, "A 19143.
2899 Jackson Ave., Memphis, TN 38108.
12S6 N. McLean Blvd., Memphis, TN 38108.
70 S. Chapel St., Newark, DE 19711.
1953 S. Harvey St., Muskegon, MI 49442.
3030 CoTOwalles Rd. Research Triangle Park, NC 27709.
P. 0. Box 68, Fremont, NB 68025.
International Plaza, Englewood Cliffs, NJ 07632.
1401 Circle Ave., Forest Park, IL 60130.
100 Church St., New York, NY 10008.
One Union St., Boston, MA 02108.
P. 0. Box 1522, Lake Charles, LA 70601.
Walmore, Rd., P. 0. Box 477, Niagara Falls, NY 14304.
Cargill Bldg., Miimeanolis, m 55402.
376 3d St., Everett, MA 02149.
1375 8th St., LaSalle, IL 61301.
522 5th Ave., New York, NY 10036.
1495 S. 11th St., Louisville, KY 40208.
P. 0, Box 9176, Corpus Christi, TX 78408.
800 Hoberg St., Green Bay, WI 54305.
P. 0. Box 5008, Houston, TX 77012.
3527 Smallman St., Pittsburgh, PA 15201.
1715 W. 38th St., Chattanooga, TN 37409.
P. 0. Box 4913, Station "F", Kansas City, md 64120.
P. o. Box 270, Springfield, OR 97477.
840 N. Michigan Ave., Chicago, IL 60611.
P. 0. Box 480, Newport, TN 37821.
491 Columbia Ave., Holland, MI 49423.
DIRECTORY OF MANUFACTURERS 249
-Synthetic organic chemicals: Alphabetical directory of manirfacturers, by company, 1970--Continued
Name of company
Office address
Chem-Fleur, Inc
Chemical Formulators, Inc
Chemlek Laboratories, Inc
Chemol, Inc
Chemplex Co
Cherokee Nitrogen Co
Chevron Chemical Co
Childs Pulp Colors, Inc
Chri-Hansen' s Laboratory, Incr
Chris-Craft Industries, Inc., Montrose
Chemical Div.
Ciba-Geigy Corp
Ciba Agrochemical Co
Ciba Pharmaceutical Co
Ciba Products Div
Cincinnati Milacron Chemicals, Inc
Cities Service Co.:
Copperhill Operations
Levey Div
Petrochemicals Div., Chemicals Div
Petrochemicals Group
Cities Service Oil Co
Clark Oil S Refining Corp., Clark Chemical
Co
W. A. Cleary Corp
Clintwood Chemical Co-
Coastal States Petrochemical Co
Colgate-Palmolive Co ^
Collier Carbon S Chemical Corp
Colloids, Inc
Colonial Sugars Co., Sucro-Chemical Div
Columbia Nipro Corp
Columbia Nitrogen Corp
Commercial Products Co., Inc
Commercial Solvents Corp
Commonwealth Oil Refining Co., Inc
Commonwealth Petrochemicals, Inc., Sub. of
Commonwealth Oil Refining Co., Inc.
Concord Chemical Co., Inc
Conoco Plastics
Consolidated Papers, Inc
Contijiental Chemical Co
Continental Oil Co
Cook Paint 5 Varnish Co-
Cooperative Farm Chemicals Association
Coopers Creek Chemical Corp
Copolymer Rubber 5 Chemical Corp
Cosden Oil § Chemical Co
Crest Chemical Corp
Croda:, Inc
Crompton § Knowles Corp., Althouse Div
Crosby Chemicals, Inc
Crown Central Petroleum Corp
Crown Metro, Inc
Croivn Zellerbach Corp., Chemical Products
Div.
Dan River Mills, Inc
Dart Industries, Inc.:
Azetec Chemicals Div
Fiberfil Div
Davies-Young Co^
Dawe's Laboratories, Inc
Degen Oil § Chemical Co
200 Pulaski St., Newark, NJ 07105.
P. 0. Box 26, Nitro, WV 25143.
4040 W. 123d St., Alsip, IL 60658.
P. 0. Box' 20687, Greensboro, NC 27420.
3100 Golf Rd., Rolling Meadows, IL 60008.
P. 0. Box 429, Pryor, OK 74361.
200 Bush St., San Francisco, CA 94120.
43 Summit St., Brooklyn, NY 11231.
9015 W. Maple St., Milwaukee, WI S3214.
100 Lister Ave., Newark, NJ 07105.
444 Saw Mill River Rd. , Ardsley, NY 10502.
556 Morris Ave., Summit, NJ 07901.
556 Morris Ave., Summit, NJ 07901.
556 Morris Ave., Summit, NJ 07901.
500 Jersey Ave., New Brunswick, NJ 08903.
and West St., Reading, OH 45215.
Copperhill, TN 37317.
630 Glendale-Milford Rd., Cincinnati, OH 45215.
P. 0. Box 1522, Lake Charles, LA 70601.
60 Wall St., New York, NY 10005.
P. 0. Box 300, Tulsa, OK 74101.
131st St. § Kedzie Ave., Blue Island, IL 60406.
P. 0. Box 749, New Brunswick, NJ 08903.
4342 S. Wolcoth Ave., Chicago, IL 60609.
P. 0. Drawer, Corpus Christi, TX 78403.
300 Park Ave., New York, NY 10022.
461 S. Boyston, Los Angeles, CA 90017.
394 Frelinghuysen Ave., Newark, NJ 07114.
Gramercy, LA 70052.
P. 0. Box 1483, Augusta, GA 3D903.
P. 0. Box 1483, Augusta, GA 30903.
117 Ethel Ave., Hawthorne, NJ 07641.
245 Park Ave., New York, NY 10017.
P. 0. Box 3623, Ponce, PR 00731.
P. 0. Box 3623, Ponce, PR 00731.
17th 5 Federal Sts., Camden, NJ 08105.
P. 0. Box 236, Wilton, CT 06897.
Wisconsin Rapids, WI 54494.
270 Clifton Blvd., Clifton, NJ 07015.
Park-Eighty Plaza East, Saddle Brook, NJ 07662.
P. 0. Box 389, Kansas City, MO 64141.
P. 0. Box 308, Lawrence, KS 66044.
River Rd., W. Conshohocken, PA 19428.
P. 0. Box 2591, Baton Rouge, LA 70821.
P. 0. Box 1311, Big Spring, TX 79720.
225 Emmet St., Newark, NJ 07114.
51 Madison Ave., New York, NY 10010.
500 Pear St., Reading, PA 19603.
P. '0. Box 460, DeRidder, LA 70634.
P. 0. Box 1168, Baltimore, MD 21203.
12 Dudley St., Providence, RI 02905.
Camas, WA 98607.
Danville, VA 24541.
P. 0. Box 756, Elyria, OH 44035.
1701 N. Heidelbach Ave., Evansville, IL 47717.
705 Albany St., Dayton, OH 45401.
450 State St., Chicago, IL 60430.
200 Kellogg St., Jersey City, NJ 07305.
250 SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. --Synthetic organic chemicals: Alphabetical directory of manufacturers, by company, 1970--Continued
Name of company
Office address
Dennis Chemical Co
DePaul Chemical Co., Inc
DeSoto, Inc
Detrex Chemical Industries, Inc
Dexter Chemical Corp
Hysol Div
Midland Div
Diamond Plastics, Inc
Diamond Shamrock Corp
Dixie Chemical Co
Dixie Chemical Products, Inc
Dixie Pine Products Co., Inc
Dole Co. Div. of Castle 5 Cook, Inc
Dominion Products, Inc
Dover Chemical Co
Dow Badische Chemical Co
Dow Chemical Co
Dow Corning Corp
Drew Chemical Corp
Frank W. Dunne Co
DuPlan Corp. , Rochester Button Div
E. I. duPont de Nemours § Co., Inc
Dye Specialties, Inc
Eastern Color § Chemical Co-
Eastman Kodak Co
Tennessee Eastman Co. Div
Texas Eastman Co. Div
East Shore Chem.ical Co., Inc
Eastside Chemical Laboratory
Elan Chemical Co
Electro-Seal Glasflex Corp
El Paso Products Co
Emery Industries, Inc
Emkay Chemical Co
Endo Laboratories, Inc
Enenco, Inc
Enjay Chemical Co
En jay Fibers § Laminates Co. Div
Enzyme Development Corp
Epoxylite Corp
Essential Chemicals Corp
Essex International, Inc., Electro-
Mechanical Div.
Ethyl Corp
Evans Chemetics, Inc
FMC <;orp . :
American Viscose Div
Inorganic Chemicals Div
Niagara Chemical Div
Organic Chemicals Div
Nitro Plant--
FRP Co
Fabricolor Manufacturing Corp
Fairmont Chemical Go., Inc
Farac Oil 5 Chemical Co. Div of Handschy
Chemical Co.
Far-Best Corp., 0. L. King Div
Farmers Chemical Association, Inc
Farmer'.s Chemical Co
Farnow, Inc
2701 Papin St., St. Louis, MO 63103.
44-27 Purvis St., Long Island City, NY 11101.
1700 S. Mt. Prospect Ave., Des Plaines, IL 60018.
14331 Woodrow Wilson, Detroit MI 48232.
845 Edgewater Rd., Bronx, NY 10474.
211 Franklin St., Olean, NY 14760.
E. Water St., P. 0. Box 620, Waukegan, IL 60085.
P. 0..BOX 666, Paramount, CA 90723.
300 Union Commerce Bldg,, Cleveland, OH 44114.
3635 W. Dallas Ave., Houston, TX 77019.
3635 W. Dallas Ave., Houston, TX 77019;
P. 0. Box 470, Hattiesburg, MS 39401.
P. 0. Box 3380, Honolulu, HI 96801
882 3d Ave., Brooklyn, NY 11232.
W. 15th and Davis Sts., Dover, OH 44622.
P. 0. Drawer "D", Williamsburg, VA 23605.
Hopkins Bldg., Midland, MI 48640.
P. 0. Box 1592, Midland, MI 48640.
416 Division St., Boonton, NJ 07005.
1007 41st.. Oakland, CA 94608.
300 State St., Bochester, NY 14614.
DuPont Bldg., Wilmington, DE 19898.
26 Journal Sq., Jersey City, NJ 07306.
35 Livingston St., Providence, RI 02904.
343 State St., Rochester, NY 14650.
P. 0. Box 511, Kingsport, IN 37662.
P. 0. Box 7444, Longview, TX 75601.
1221 Barney Ave., Muskegon, MI 49443.
12880 NE Bellerae-Richmond Rd., Bellevue, WA 98005.
268 Doremus Ave., Newark, NJ 07105.
Plainfield, Stirling, NJ 07980.
P. 0. Box 3986, Odessa, TX 79760.
4300 Carew Tower, Cincinnati, OH 45202 and
8733 S. Dice Rd., Santa Fe Springs, CA 90670.
319 2d St., Elizabeth, NJ 07206.
1000 Stewart Ave., Garden City, NY 11530.
P. 0. Box 398, Memphis, TN 38101.
P. 0. Box 201, Florham Park, NJ 07932.
Odenton, MD 21113.
2 Penn Plaza, New York, NY 10001.
1428 Santa Anita, S. El Monte, CA 91733.
28391 Essential Rd., Merton, WI 53056,
1200 Rochester Ave., Muncie, IN 47302.
330 S. 4th St., Richmond, VA 23217.
90 Tokeneke Rd., Darien, CT 06820.
1617 John F. Kennedy Blvd., Philadelphia, PA 19103.
633 3d Ave., New York, NY 10017 and Sawyer Ave. 5
River Rd., Town of Tonawanda, NY 14150.
100 Niagara St., Middleport, NY 14105.
633 3d Ave., New York, NY 10017.
633 3d Ave., New York, NY 10017.
P. 0. Box 349,-Baxley, GA 31S13.
24-1/2 Van Houten St. , Paterson, NJ 07505.
117 Blanchard St., Newark, NJ 07105.
13601 S. Ashland Ave., Riverdale, IL 60627.
640 Oilman St., Berkeley, CA 94710.
P. 0. Box 87, Harrison, TN 37341.
P. 0. Box 591, 3713 W. Main St., Kalamazoo, MI 490
77 Jacobus Ave., S. Kearny, NJ 07032.
DIRECTORY OF MANUFACTURERS 251
TABLE 1. --Synthetic organic chemicals: Alphabetical directory of manufacturers, by company, 1970--Continued
Name of company
Office address
Felton International, Inc
Ferro Corp. :
Ferro Chemical Div
Ottawa Chemical Div
Fine Organics, Inc
Firestone Tire § Rubber Co.:
Firestone Foam Products Co
Firestone Plastics Co. Div
Firestone Synthetic Rubber 6 Latex Co. Di'
First Chemical Corp
Fisher Chemical Co., Inc
Fleming Laboratories, Inc
Florasynth Laboratories, Inc
Foote Mineral Co
Formica Corp
Foster Grant Co., Inc
Foster-Heaton Co
France, Campbell § Darling, Inc
Freeman Chemical Corp
Frisch 5 Co. , Inc
Fritzsche Dodge § Olcott, Inc
H. B. Fuller Co
Fuller-O'Brien Corp
GAF Corp:
Chemical Div
Textile Chemical Div
Cane's Chemical Works, Inc '
General Electric Co
Insulating Materials Dept
Silicone Products Dept
General Foods Corp., Maxwell House Div
General Latex § Chemical Corp
General Mills Chemicals, Inc
General Plastics Manufacturing Co
General Tire § Rubber Co., Chemical Div
P. D. George Co
George A. .Jeffreys 5 Co
Georgia-Pacific Corp. :
Bellingham Div
Coos Bay Div
Getty Oil Co
Gillette Chemical Co. Div. of Gillette Co-
Gilman Paint 5 Varnish Co
Givaudan Corp
Glyco Chemicals, Inc
B. F. Goodrich Co., B. F. Goodrich Chemical
Co. Div.
Goodyear Tire § Rubber Co
Gordon Corp
Gordon Chemical Co., Inc
W. R. Grace § Co. :
Agricultural Chemical Group
Dubois Chemicals Div
Hampshire Chemical Div
Hatco Chemical Div
Marco Chemical Div
Polymers 6. Chemicals 'Div-
Vestal Laboratories Div
Grain Processing Corp
Great American Chemical Corp
Great Lakes Chemical Corp
Great Western Sugar Co-
599 Johnson Ave., Brooklyn, NY 11237.
P. 0. Box 349, 7050 Kreck Rd., Bedford, OH 44146.
700 N. Wheeling St., Toledo, OH 43605.
205 Main St., Lodi, NJ 07644.
P. 0. Box 2290, Fall River, MA 02777.
P. 0. Box 699, Pottstown, PA 19464.
381 W. Wilbeth Rd., Akron, OH 44301.
P. 0. Box 1427, Pascagoula, MS 39567.
5200 Paul G. Blazer Memorial Pkwy. , Columbus, OH 43216.
P. 0. Box 10373, Charlotte, NC 28201.
900 Van Nest Ave., Bronx, NY 10462.
Route 100, Exton, PA 19341.
Formica Bldg., 120 E. 4th St., Cincinnati, OH 45202.
289 N. Main St., Leominster, MA 01453.
16 E. 5th St., Paterson, NJ 07524.
N. Michigan Ave., Kenilworth, NJ 07033.
222 E. Main St., Port Washington, WI 53074.
88 E. 11th St., Paterson, NJ 07524.
76 9th Ave., New York, NY 10011.
2400 Kasota Ave., St. Paul, MN 55108.
450 E. Grand Ave., S. San Francisco, CA 94080.
P. 0. Box 12, Linden, NJ 07036.
1228 Chestnut St., Chattanooga, TN 37402.
535 Sth Ave., New York, NY 10017.
1 Plastics Ave., Pittsfield, MA 01201 and
1 Plastics Ave., Coshocton, OH 43812.
1 River Rd.,:"> Schenectady, NY 12305.
Waterford, NY 12188.
1125 Hudson St., Hoboken, NJ 07030.
666 Main St., Cambridge, MA 02139.
4620 W. 77th St., Mann, MN 55435 and
So. Kensington Rd., Kankakee, IL 60901.
3481 S. 35th St., Tacoma, WA 98409.
1 General St., Akron, OH 44309.
5200 N. 2d St., St. Louis, MO 63147.
528 Chapman St., P. 0. Box 709, Salem, VA 24153.
P. 0. Box 1236, Bellingham, WA 98225.
P. 0. Box 869, Coos Bay, OR 97420.
Delaware City, DE 19706.
P. 0. Box 362, N. Chicago, IL 60064.
W. 8th and Pine Sts. , Chattanooga, TN 37401.
125 Delawanna Ave., Clifton, NJ 07014.
Greenwich, CT 06830.
3135 Euclid Ave., Cleveland, OH 44137.
1144 E. Market St., Akron, OH 44313.
300 S. 3d St., Kansas City, KS 66118.
88 Webster St., Worcester, MA 01603.
P. 0. Box 277, Memphis, TN 38101.
Dubois Tower, Cincinnati, OH 45202.
Poisson Ave., Nashua, NH. 03060.
629 Amboy St., Edison, NJ 08817.
1711 W. Elizabeth Ave., Linden, NJ 07036.
62 Whittemore Ave., Cambridge, MA 02140.
4963 Manchester Ave., St. Louis, MO 63110.
1600 Oregon St., Muscatine, LA 52761.
650 Water St., Fitchburg, MA 01420.
P. 0. Box 2200, West Lafayette, IN 47906.
P. 0. Box 5308, Terminal Annex, Denver, CO 80217.
TABLE 1.-
SYNTHETIC ORGANIC CHEMICALS, 1970
-Synthetic organic chemicals: Alphabetical directory of manufacturers, by company, 1970--Continued
Name of company
Office address
Guardsman Chemical Coatings, Inc
Gulf Oil Corp.:
Gulf Adhesives
Gulf Oil Chemicals Co. - United States---
Guth Corp
H S N Chemical Co
Haag Laboratories, Inc
Halby Products Co., Inc
C. P. Hall Co. of Illinois
Hampden Color § Chemical Co
Hanna Chemical Coatings Corp
Harshaw Chemical Co. Div. of Kewanee Oil Co
Hart Products Corp
Haveg Industries, Incr
Hawkeye Chemical Co
Hercor Chemical Corp
Hercules, Inc
Imperial Color 5 Chemical Dept
Heresite 5 Chemical Co
Hess Oil Virgin Islands Corp
Heterochemical Corp
Hewitt Soap Co., Inc
Hexagon Laboratories, Inc
Hodag Chemical Corp
Hoffmann- LaRoche , Inc
Hoffman-Taff, Inc
Hooker Chemical Corp
Durex Div
Ruco Div
E. F. Houghton & Co-
Houston Chemical Corp
Humphrey Chemical Co
Philip A. Hunt Chemical Corp., Wayland
Chemical Div.
Huntington Laboratories, Inc
Husky Briquetting, Inc
Hynson, Kestcott 5 Dunning, Inc
ICI America, Inc
ITT Rayonier, Inc
Industrial Dyestuff Co
Inland Steel Co., Inland Steel Container Co
Inmont Corp
International Flavors § Fragrances, Inc
International Minerals § Chemical Corp
Interplastic Corp. , Commercial Resins Div--
lonac Chemical Co. Div. of Sybron Corp
Ironsides Resins, Inc
Jefferson Chemical Co., Inc
Jennison-Wright Corp
Andrew Jergens Co
Jersey State Chemical Co
Jewel Paint § Varnish Co
Johns-Manville Corp
S. C. Johnson 5 Son, Inc
Jones-Blair Paint Co
Jordan Chemical Co
Kaiser Aluminum 5 Chemical Corp.:
Kaiser Agricultural Chemicals Div
Kaiser Chemical Div
Kali Manufacturing Co
Kay-Fries Chemicals, Inc
1350 Steele Ave., SW. , Grand Rapids, MI 49502.
632 No. Cannon Ave., Lansdale, PA 19446.
P. 0. Box 2100, Houston,. TX 77001.
332 S.' Center St., Hillside, IL 60162.
90 Maltese Dr., Totowa, NJ 07512.
14010 S. Seeley Ave., Blue Island, IL 60406.
600 Terminal Ave., New Castle, DE 19720.
7300 S. Central Ave., Chicago, IL 60638.
126 Memorial Dr., Springfield, MA 01101.
P. 0. Box 147, Columbus, OH 43216.
1945 E. 97th St., Cleveland, OH 44106.
1440 Broadway, New York, NY 10018.
900 Greenbank Rd., Wilmington, DE 19808.
P. 0. Box 899, Clinton, LA 52733.
P. 0. Box 3623, Ponce, PR 00731.
910 Market St., Wilmington, DE 19899.
P. 0. Box 231, Glen Falls, NY 12803.
822 S. 14th St., Manitowoc, WI 54220.
Kingshell, P. 0. Box 127, St Croix, USVI 00850.
Ill E. Hawthorne Ave., Valley Stream, NY 11580.
333 Linden Ave., Dayton, OH 45403.
3536 Peartree Ave., Bronx, NY 10469.
7247 N. Central Park Ave., Skokie., IL 60076.
324 Kingsland St., Nutley, NJ 07110.
P. 0. Box 1246 S.S.S., Springfield, MO 65805.
Buffalo Ave. § 47th St., Niagara Falls, NY 14302.
Walck Rd., N. Tonawanda, NY 14121.
New South Rd., Hicksville, NY 11802.
303 W. Lehigh Ave.,' Philadelphia, PA 19133.
1 Gateway Center., Pittsburgh, PA 15222.
Devine St., North Haven, CT 06473.
P. 0. Box 0, Lincoln, RI 02865.
P. U. Box 710, Huntington, IN 46750.
P. 0. Box 380, Cody, WY 82414.
Charles and Chase Sts., Baltimore, MD 21201.
151 South St., Stamford, CT 06904.
161 E. 42d St., New York, NY 10017.
P. 0. Box 4249, E. Providence, RI 02914.
4300 W. 130th St., Chicago, IL 60658.
1133 Avenue of the Americas, New York, NY 10036.
521 W. 57th St., New York, NY 10019.
5401 Old Orchard Rd., Skokie, IL 60078.
2015 NE. Broadway St., Minneapolis, MN 55413.
Birmingham, NJ 08011.
270 W. Mound St., Columbus, OH 43216.
P. 0. Box 53300, Houston, TX 77052.
P. 0. Box 691, Toledo, OH 43601.
2535 Spring Grove Ave., Cincinnati, OH 45214.
59 Lee Ave., Haledon, NJ 07508.
345 N. Western Ave., Chicago, IL 60612.
22 E. 40th St., New York, NY 10016.
1525 Howe St., Racine, WI 53403.
6969 Denton Dr., Dallas, TX 75235.
1830 Columbia Ave., Folcraft, PA 19032.
P. 0. Box 246, Savannah, GA 31402.
P. 0. Box 337, Gramercy, LA 70052.
427 Moyer St., Philadelphia, PA 19125.
360 Lexington Ave.. New York, NY 10017.
DIRECTORY OF MANUFACTURERS 253
TABLE 1. --Synthetic organic chemicals: Alphabetical directory of manufacturers, by company, 1970-- Continued
Name of company
Office address
Kelly-Moore Paint Co
Kennecott Copper Corp.:
Chino Mines Div — ' »_„-.-, — , ,
Utah Copner Div —
Kenrich Petrochemicals, Inc
Kerr-McGee Corp
Keysor Chemical Corp
Keystone Chemurgic Com
Keystone Color Works, InC'
Knapp Products, Inc ^
Kohler-McLister Paint Co
H. Kohnstamm 5 Co. , Inc — -^ '
Koppers Co., Inc., Organic Materials Div
Koppers Pittsburgh Co ■
Kraftco Corp. :
Humko Products Div ■■
Sheffield Chemicals Div-
Kyanize Paints, Inc —
Lachat Chemicals, Inc
Lakeside Laboratories Div. of Colgate-
Palmolive Co.
Lake States Div. of St. Regis Pacer Co
Lakeway Chemical Co
LaMotte Chemical Products Co
Laurel Products Corp
Leatex Chemical Co
Lebanon Chemical Corn
Lehn § Fink Products, Inc., Beacon Div
Lemke Chemicals, Inc
Leonard Refineries, Inc
Lever Brothers Co
C. Lever Co
Eli Lilly f, Co-
Lubrizol Corp
George Lueders fi Co., Inc-
M § T Chemicals, Inc
Magruder Color Co., Inc
Mallinckrodt Chemical Works
Washine Div
Marathon Oil Co., Texas Refining Div
Marblette Co. Div. of Allied Products Corp
Marden-Wild Corp
Marlowe-Van Loan Corp
Martin-Marietta Corp.:
Ridgway Color S Chemical Div
South'em Dyestuff Co. Div
Max Marx Color § Chemical Co
Masonite Corp., Alpine Chemical Div
Matador Chemical Co., Inc
Mathe Chemical Co. Div. of Norac Co., Inc-
Otto B. May, Inc
McCloskey Varnish Co ■
McLaughlin Gormley King Co
Mead Johnson fi Co
Merck S Co., Inc
Merichera Co
J. Meyer § Sons, Inc
Michigan Chemical Corp
Midwest Manufacturing Corp
Miles Laboratories, Inc., Marschall Div
1015 Commercial St., San Carlos, CA 94070.
Hurley, MN 88043.
P. 0. Box 11299 Salt Lake City, UT 84111.
Foot of E. 22d St., Bayonne, NJ 07002.
Robert S. Kerr Ave., Oklahoma City, OK 73102.
26000 Snringfield Rd., Saugus, CA 91350.
P. D. 2\ Bethlehem, Pa 18017.
151 W. Gay Ave, York, PA 17403.
180 Hamilton Ave., Lodi, NJ 07644.
1201 Osage St., Denver, CO 80201.
161 Avenue of the Americas, New York, NY 10013.
Kopners Bldg., Pittsburgh, PA 15219.
Konners Bldg., Pittsburgh, PA 15219.
P. 0. Box 398, Memphis, TN 38101.
2400 Morris Ave., Union, NJ 07083.
2d and Boston Sts., Everett, MA 02149.
20200 Ashland Ave., Chicago Heights, IL 60411.
1707 E. North Ave., Milwaukee, WI 53201.
603 W. Davenport St., Rhinelander, WI 54501.
5025 Evanston Ave., Muskegon. MI 49443.
Chestertown, MD 21620.
2600 E. Tioga St., Philadelphia, PA 19134.
2722 N. Hancock St., Philadelphia, PA^ 19133.
P. 0. Box 180, Lebanon, PA 17042.
33 Richdale Ave., Cambridge, MA 02140.
195-203 Main St., Lodi, NJ 07644.
E. Superior St., Alma, mi 48801.
390 Park Ave., New York, NY 10022.
Howard and Huntington Sts., Philadelphia, PA 19133.
307 E. McCarty St., Indianapolis, IN 46206 and G.P.O.
Box 4388, San Juan, PR 00936.
29400 Lakeland Blvd., Wickliffe, OH 44092.
427 Washington St., New York, NY 10013.
Woodridge Rd. fi Randolph Ave., P. 0. Box 1104,
Pahway, NJ 07065.
1 Virginia St., Newark, NJ 07114.
3600 N. 2d St., St. Louis, MO 63147.
165 Kain^St., Lodi, NJ 07644.
P. 0. Box 1191, Texas City, TX 77590.
37-31 30th St., Long Island City, NY 11101.
500 Columbia St., Somerville, MA 02143.
1511 Joshua Circle, Hieh Point, NC 27260.
75 Front St., Ridgway., PA 15853.
P. 0. Box 10098, Charlotte, NC 28201.
192 Coit St., Irvington, NJ 07111.
P. 0. Box 2392, Gulfport, ^«S 39503.
P. O. Box 2256, Wichita, KS 67201.
169 Kennedy Dr., Lodi, NJ 07644.
52 Amsterdam St., Newark, NJ 07105.
7600 State Rd., Philadelphia, PA 19136.
1715 SE. 5th St., Minneapolis, MN 55414.
2404 W. Penna. St. , Evansville, IN 47721.
126 E. Lincoln Ave., Rahway, NJ 07065.
1914 Haden Rd., Houston, TX 77015.
4321 N. 4th St., Philadelphia, PA 19140.
351 E. Ohio St., Chicago, IL 60611.
Oak St. and Bluff Rd., Burlington, lA 52601.
Myrtle 6 McNaughton Sts., Elkhart, IN 46514.
254 SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. --Synthetic organic chemicals: Alphabetical directory of manufacturers, by company, 1970 — Continued
Name of company
Office address
Millmaster Onyx Corp.:
A. Gross § Co. Div
Millmaster Chemical Div., Berkely
Chemical Dept.
Onyx Chemical Co. Div
Refined-Onyx Div
Mineral Oil Refining Co
Minnesota Mining & Maufacturing Co
Minnesota Paints, Inc
Miranol Chemical Co., Inc
Mississippi Chemical Corp
Mobay Chemical Co
Mobil Chemical Co
Mobil Oil Corp
Mobil Chemical Co., Industrial Chemical
Div.
Mona Industries, Inc
Monochem, Inc
Monsanto Co
Bircham Bend Plant
Chocolate Bayou Plant
Plastics Div
Textiles Div
Montrose Chemical Corp. of California
Mooney Chemicals, Inc
Moretex Chemical Products, Inc
Morton Chemical Co
Morton International, Inc.,
Morton Chemical Co. Div.
Motomco, Incr--
Murphy-Phoenix Co
Nalco Chemical Co
National Biochemical Co
National Casein Co
National Distillers 5 Chemical Corp., U.S
Industrial Chemicals Co. Div.
National Lead Co
National Milling 5 Chemical Co
National Petro Chemical Corp
National Polychemicals, Inc
National Starch 8 Chemical Corp
Nease Chemical Co., Inc
Nepera Chemical Co., Inc
Neville Chemical Co
Nilok Chemicals, Inc., Hilton-Davis
Chemical Co.
Nipak, Inc
Nitini, Inc. Div. of Shulton, Inc
Norac Co., Inc
Norda Essential Oil § Chemical Co., Inc —
Norris Paint § Varnish Co
North American Chemical Co
North American Rockwell Corp., Re-
inforced Plastics Operations, Automotive
Products Div.
Northern Petrochemical Co
Northrop Carolina, Inc
99 Park Ave., New York; NY 10016.
99 Park Ave., New York, NY 10016.
190 Warren St., Jersey City, NJ 07302.
624 Schuyler Ave., Lyndhurst, NJ 07071.
P. 0. Drawer C, Dickinson, TX 77539.
3M Center, St. Paul, MN 55101.
1101 S. 3d St., Minneapolis, MN 55415
277 Coit St., Irvington, NJ 07111.
P. 0. Box 388, Yazoo City, MS 39194.
Penn Lincoln Parkway, W. Pittsburgh, PA 15205.
P. 0. Box 3868, Beaumont, TX 77704; 7301 Bessemer Ave.,
Cleveland, OH 44127 and P.O. Box 250, Edison, NJ
08817.
P. 0. Box 900, Dallas, TX 75221.
801 E. Main St., Richmond, VA 23219.
65 E. 23d St., Paterson, NJ 07524.
P. 0. Box 488, Geismar, LA 70734.
P. 0. Box 120, Santa Clara, CA 95052 and 800 N.
Lindergh Blvd., St. Louis, MO 63166.
190 Grochmal Ave., Indian Orchard, MA 01051.
P. 0. Box 711, Alvin, TX 77511.
730 Worcester St., Indian Orchard, MA 01101;
5100 W. Jefferson Ave., Trenton, MI 48183;
River Rd., Addyston, OH 45001 and P. 0. Box 1311,
Texas City, TX 77591.
800 N. Linbergh Blvd., St. Louis, MO 63166 and P. 0.
Box 1507, Pensacola, Fl 32503.
500- S. Virgil Ave., Los: Angeles, CA 90005.
2301 Scranton Rd., Cleveland, OH 44113.
314 W. Henry St., P. 0. Box 1799, Spartanbury, SC 29301.
110 N. Wacker Dr., Chicago, IL 60606.
110 N. Wacker Dr., Chicago, IL 60606.
89 Terminal Ave. ,
9505 Cassius Ave.
Clark, NJ 07066.
, Cleveland, OH 44105.
180 N. Michigan Ave., Chicago, IL 60601.
3127 W. Lake St., Chicago, IL 60612.
601 W. 80th St., Chicago, IL 60620.
99 Park Ave., New York, NY 10016.
Ill Broadway, New York, NY 10006.
4601 Flat Rock Rd., Philadelphia, PA 19127.
99 Park Ave., New York NY 10016.
51 Eames St., Wilmington, MA 01887.
750 3d Ave., New York, NY 10017.
P. 0. Box 221, State College, PA 16801.
Route 17, Harriman, NY 10926.
Neville Island P.O., Pittsburgh, PA 15225.
2235 Langdon Farm Rd., Cincinnati, OH 45230.
301 S. Harwood St., Dallas, TX 75221.
697 Rt. 46, Clifton, NJ 07015.
405 S. Motor Ave., Azusa, CA 91703.
475 10th Ave., New York, NY 10001.
P. 0. Box 2023, Salem, OR 97308.
19 Chestnut St., Cambridge, MA 02139.
4601 Benefit Ave., Ashtabula, OH 44004.
2200 E. Devon Ave., Des Plaines, IL 60018.
P. 0. Box 3049, Asheville, NC 28802.
DIRECTORY OF MANUFACTURERS 255
TABLE 1. --Synthetic organic chemicals: Alphabetical directory of manufacturers, by company, 1970- -Continued
Name of company
Office address
Northwestern Chemical Co ---
Northwest Petrochemical Corp-- ■
Norwich Pharmacal Co ■
Nostrip Chemical Works, Inc
Noury Chemical Corp
Novamont Corp., Neal Works
Nyanza, Inc
O'Brien Corp --'
Occidental Chemical Co
Clin Corp ■ ---
Agricultural Chemicals Div
Thompson Plastics
Orbis Products Corp
Organics, Inc
Original Bradford Soap Works, Inc
Ott Chemical Co
Owens-Corning Fiberglas Corp
Oxirane Chemical Co- -■ ■
P-L Biochemicals, Inc
PPG Industries, Inc
Pabco Paint Corp
Pace National Corp
Pacific Resins § Chemical Co
Pantasote Co. of New York, Inc
Parke Davis § Co
Passaic Color 5 Chemical Co
C. H. Patrick § Co., Inc
Pears all Co
Peck's Products Co
Peerless Chemical Co -^-^--- -—
Pelron Corp
Pennsylvania Industrial Chemical Corp
Pennsylvania Refining Co
Pennwalt Corp
Lucidol Div
Perry § Derrick Co., Inc
Peter Hand, Inc
Petrochemicals Co., Inc
Petrochemical Investment Corp
Petro-Tex Chemical Corp
Pfanstiehl Laboratories, Inc
Pfister Chemical, Inc
Pfizer, Inc '
Pharmachem Corp
Phillips Petroleum Co
Phillips Pacific Chemical Co
Phillips Puerto Rico Core, Inc
Pierce Chemical Co
Pilot Chemical Co
Pioneer Chemical Works, Inc--
Pioneer Plastics Corp
Pitman-Moore, Inc
Pitt-Consol Chemical Co
Plastics Engineering Co ^--,-, —
Plastics Manufacturing Co-^ ^ —
Plex Chemical Corp
Plumb Chemical Corp
Polak's Frutal Works, Inc--
Polychemical Laboratories, Inc —
Polymer Corp
Polymer Industries, Inc •
Poly Resins
Polyrez Co., Inc —
Polyvinyl Chemicals, Inc. Div. of
Beatrice Foods Co.
120 N. Aurora St., W. Chicago, IL 60185.
P. 0. Box 99, Anacortes, WA 98221.
17 Eaton Ave., Norwich, NY 13815.
P. 0. Box 160, Pedrichtown, NJ 08067.
2153 Lockuort-Olcott Rd. , Burt, NY 14028.
P. 0. Box 189, Kenova, W 25530.
Maguno Rd. , Ashland, MA 01721.
2001 W. Washington Ave., South Bend, IN 46621.
P. 0. Box 198, Lathrop, CA 95330.
120 Long Ridge Rd. , Stamford, CT 06904.
1120 ^%rshall St., P. 0. Box 991, Little "ock, AR 72203.
238 S. i^iain St., Assonet, m 02702.
475 10th Ave, New York, NY 10018.
1724 W. Greenleaf Ave., Chicago, IL 60628.
200 Providence St., W. Warwick, RI 02893.
500 Agard Rd. , ?'uskegon, MI 49945.
P. 0. Box 901, Toledo, OH 43601.
10801 Choate Rd., Houston, TX 77062.
1037 W. McKinley Ave., Milwaukee, WI 53205.
1 Gateway Center, Pittsburgh, PA 15222.
P. 0. Box 8502, Emeryville, CA 94608.
4501 Shilshole Ave., N.W., Seattle, WA 98107.
3400 13th Ave., SW. , Seattle, WA 98134.
26 Jefferson St., Passaic, NJ 07055.
Jos. Campau at the River, Detroit, MI 48207.
28-36 Paterson St., Paterson, NJ 07501.
P. 0. Box 2526, Greensville, SC 29602.
P. 0. Box 108, Phillipsburg, NJ 08865.
610 E. Clarence Ave., St. Louis, MO 63147.
12416 Cloverdale, Detroit, MI 48204.
7847 W. 47th St., Lyons, PL 60534.
120 State St., Clairton, PA 15025.
Union Bank Bldg. , Butler, PA 16001.
Three Penn Center, Philadelphia, PA 19102.
1740 Military Rd., Buffalo, NY 14240.
2510 Highland Ave., Norwood, OH 45212.
2 E. Madison St., Waukegan, IL 60085.
P. n. Box 2199, Fort Worth, TX 76101.
P. 0. Drawer F, Channelview, TX 77530.
P. 0. Box 2584, Houston, TX 77001.
1219 Glen Rock Ave., Waukegan, IL 60085.
P. 0. Box 15, Ridgefield, NJ 07657.
235 E. 42d St., New York, NY 10017.
Broad and Wood Sts., Bethlehem, PA 18018.
4440 Frank Phillips Bldg., Bartlesville, OK 74003.
P. 0. Box 6008, Kennewich, WA 99336.
GPO Box 4129, San Juan, PR 00936.
P. O. Box 117 Rockford, IL 61105.
11756 Burke St., Santa Fe .Springs, CA 90670.
P. 0. Box 237, Route 73, Manle Shade, NJ 08052.
Pionite Rd. , Auburn, me 04210.
Fort Washington, PA 19034.
191 Doremus Ave., Newark, NJ 07105.
1607 Geele Ave., Sheboygan, WI 53081.
2700 S. Westmoreland Ave., Dallas, TX 75224.
1205 Atlantic St., Union City, CA 94487.
4837 James St., Philadelphia, PA 19137.
33 Snrague Ave., »!iddletown, NY 10940.
490 Hunts Point Ave., Bronx, NY 10474.
2120 Fairmont Ave., Reading, PA 19603.
Viaduct Rd., Springdale, CT 06879.
11655 Wicks St"., Sun Valley, CA 91352.
P. 0. Box 320, Woodbury, NJ 08096.
730 Main St., Wilmington, MA 01887.
256 SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 1. --Synthetic organic chemicals: Alphabetical directory of manufacturers, by company, 1970 — Continued
Name of company
Office address
Pratt § Lambert, Inc
Premier Malt Products, Inc
Premier Petrochemical Co
Princeton Chemical Research, Inc
Procter § Gamble Co
Proctor Chemical Co. , Inc
Productol Chemical Co., Inc
Products Research § Chemical Corp
Publicker Industries, Inc
Puerto Rico Chemical Co., Inc
Pur ex Corp . , Ltd
Puritan Chemical Co
Quaker Chemical Corp
Quaker Oats Co
K. J. Quinn § Co., Inc
R.S.A. Corp
Rachelle Laboratories, Inc
Raybestos-Manhattan, Inc., Raybestos Div--
Red Spot Paint § Varnish Co., Inc
Reheis Chemical Co. Div. of Armour
Pharmaceutical Co.
Reichhold Chemicals, Inc
Reilly Tar § Chemical Corp
Reliance Universal, Inc, of Texas
Rel-Rez Div
Remington Arms Co. , Inc
Resyn Corp
Retzloff Chemical Co
Rexene Polymers Co
Rhodia, Inc
Richardson Co
Polymeric Div
Riker Laboratories, Inc., Sub. of 3M Co —
F. Ritter § Co
Ritter Chemical Co., Inc
Riverdale Chemical Co
Robeco Chemicals, Inc
Roberts Chemicals Div. of Security
Chemicals, Inc.
Roehr Chemicals, Inc
Rogers Corp
Rohm S Haas Co
Rosenberg Bros. 5 Co
Royce Chemical Co
Rubicon Chemicals, Inc
SCM Corp. and Glidden-Durkee Div
Safeway Stores, Inc., Brookside Div
Salem Oil § Grease Co
Salsbury Laboratories
Sandoz, Inc., Sandoz Color § Chemical Div-
Sartomer Resins, Inc
Schaefer Varnish Co., Inc
Schenectady Chemicals, Inc
Scher Bros., Inc
R. P. Scherer Corp
Sobering Corp
Scholler Bros., Inc
Scientific Protein Labs
P. 0. Box 22, Buffalo, NY 14240.
917 W. Juneau Ave., Milwaukee, WI S3201.
P. 0. Box 100, Pasadena, TX 77501
P. 0. Box 651, Princeton, NJ 08540.
Ivorydale Technical Ctr., Cincinnati, OH 45217.
P. 0. Box 399, Salisbury, NC 28144.
13215 E. Penn St., Whittier, CA 90602.
2919 Empire Ave., Burbank, CA 91504.
1429 Walnut St., Philadelphia, PA 19102.
P. 0. Box 496, Arecibo, PR 00613.
5101 Clark Ave., Lakewood, CA 90712 and
2244 N. Elston Ave., Chicago, IL 60614.
916 Ashby St., NW. , Atlanta, GA 30318.
Lime 5 Elm Sts., Conshohocken, PA 19428.
345 Merchandise Mart Plaza, Chicago, IL 60654.
195 Canal St., Maiden, MA 02148.
690 Sawmill River Rd. , Ardsley, NY 10502.
700 Henry Ford Ave., Long Beach, CA 90810.
74 E. Main St., Strafford, CT 06497.
966 E. Columbia St., Evansville, IN 47708.
325 Snyder Ave., Berkeley Heights, NJ 07922.
525 N. Broadway, White Plains, NY 10602 and
2508 E. Bailey Rd., Cviyahoga Falls, OH 44221.
1615 Merchants Bank,; Indianapolis, IN 46204.
6901 Cavalcade St., Houston, TX 77001.
4730 Crittenden Dr., Louisville, KY 40221.
939 Barnum Ave., Bridgeport, CT 06602.
1401 W. Blancke St., Linden, NJ 07036.
P. 0. Box 45296, Houston, TX 77045.
P. 0. Box 37, Paramus, NJ 07652.
600 Madison Ave., New York, NY 10022.
2708 Lake St., Melrose Park, IL 60160.
425 Morgan Lane, West Haven, CT 065] fi.
19901 Nordhoff St., Northridge, CA 91324.
4001 Goodwin Ave., Los Angeles, CA 90039.
403 W. Main St. , Amsterdam, NY 12010.
220 E. 17th St., Chicago Heights, IL 60411.
51 Madison Ave., New York, NY 10010.
P. 0. Box 546, Nitro, W 25143.
52-20 37th St., Long Island City, NY 11101.
Main St., Rogers, CT 06263.
Independence Mall West, Philadelphia, PA 19105.
100 Landing Ave., Smithtoim, NY 11787.
P. 0. Box 237, E, Rutherford, NJ 07073
P. 0. Box 517, Geismar, LA 70734.
900 Union Commerce Bldg., Cleveland, OH 44115 and
2333 W. Logan Blvd., Chicago, IL 60647.
1111 Marina Blvd., San Leandro, CA 94577.
60 Grove St., Salem, MA 01970.
2000 Rockford Rd. , Charles City, lA 50616.
P. 0. Box 357, Fair Lawn, NJ 07410 and Route No. 10,
Hanover, NJ 07936.
P. 0. Box 56, Essington, PA 19029.
1350 S. 15th St., Louisville, KY 40210.
Congress St. and 10th Ave., Schenectady, NY 12301.
P. 0. Box 538, Allwood Station, Clifton, NJ 07012.
9425 Grinnell Ave., Detroit, MI 48213.
1011 Morris Ave., Union, NJ 07083.
Collins and Westmoreland Sts., Philadelphia, PA 19134.
P. 0. Box 1409, Madison WI 53701.
TABLE 1.
DIRECTORY OF MANUFACTURERS 257
-Synthetic organic chemicals: Alphabetical directory of manufacturers, by company, 19 70- -Continued
Name of company
Seaboard Chemicals, Inc
G. D. Searle § Co
Selney Co., Inc
Seydel -Wool ley S Co., Inc
Shanco Plastics 5 Chemicals, Inc
Shell § Commonwealth Chemicals, Inc
Shell Oil Co
Shell Chemical Co. Div
Shepherd Chemical Co
Sherwin-Williams Co
George F. Siddall Co., Inc
Simpson Timber Co
Sinclair-Koppers Co
Sinclair-Koppers Chemical Co
Sinclair Paint Co
Sipes Chemical Coatings Co
Skelly Oil Co
G. Frederick Smith Chemical Co
Smith, Kline § French Laboratories
Solar Chemical Corp
Soluol Chemical Co., Inc
Solvent Chemical Co., Inc
Sonford Chemical Co-
Sonoco Products Co
Sou-Tex Chemical Co., Inc
Southeastern Adhesives Co
Southern Chemical Products Co
Southern Sizing Co
Spaulding Fibre Co., Inc
E. R. Squibb § Sons, Inc
A. E. Staley Manufacturing Co
Charlotte Chemicals Labs. Div
Staley Chemicals Div
Stamford Chemical Industries
Standard Brands, Inc., Clinton Corn
Processing Co. Div
Standard Brands Chemical Industries, Inc-
Standard Chemical Products, Inc
Standard Chlorine of Delaware, Inc
Standard Oil Co. of California, Chevron
Chemical Co.
Standard Oil Co. of Ohio
Standard Pyroxoloid Corp
Stange Co
Stauffer Chemical Co.:
Benzol Products Div
Calhio Chemicals, Inc
Cowles Chemical Div
Industrial Div
Specialty Chemical Div
Stepan Chemical Co
Maywood Div
Sterling Drug, Inc.:
Glenbrook Laboratories Div
Hilton-Davis Chemical Co. Div
Thomasset Colors Div
Winthrop Laboratories Div
Sterwin Chemicals, Inc
Stresen-Reuter International,
International Minerals 5 Chemical Corp,
Styrochem Corp. Sub. of Commonwealth
Oil Refining Co., Inc.
Sucrest Corp
Sugar Beet Products Co
Office address
30 Foster St., Salem, MA 01970.
P. 0. Box SllO, Chicago, IL 60680.
185 Court St., Brooklyn, NY 11201.
762 Marietta Blvd., NW. , Atlanta, GA 30318.
Ill Wales St., Tonawanda, NY 14150.
P. 0. Box 3623, Ponce, PR 00731.
P. 0. Box 2463, Houston, TX 77001.
52 W. 52d St., New York, NY 10020.
4900 Beech St., Cincinnati, OH 45212.
101 Prospect Ave., NW Cleveland, OH 44101.
P. 0. Box 925, Spartanburg, SC 29301.
2301 N. Columbia Blvd., Portland, OR 97217.
900 Koppers Bldg., Pittsburgh, PA 15219.
9822 La Porte Freeway, .Houston, TX 77012.
3960 E. Washington Blvd., Los Angeles, CA 90023.
P. 0. Box 13090, Pittsburgh, PA 15243.
P. 0. Box 1650, Tulsa, OK 74102.
867 McKinley Ave., Columbus, OH 43223.
1500 Spring Garden St., Philadelphia, PA 19101,
P. 0. Box 90, Leominster, MA 01453.
Green Hill and Market Sts., W. Warwick, RI 02893.
335-341 Commercial St., Maiden, MA 02148.
P. 0. Box 127, Port Neches, TX 77651.
2d St., Hartsville, SC 29550.
E. Catawba Ave., Mount Holly, NC 28120.
P. 0. Box 791, Lenoir, NC 28645.
420 Lower Boundary St., P. 0. Box 205, Macon, GA 31202.
P. 0. Box 90987, East Point, GA 30344.
310 Wheeler St., Tonawanda, NY 14150.
Georges Rd., Brunswich, NJ 08903.
22nd S Elorado Sts., Decatur, IL 62525.
P. 0. Box 948, Charlotte, NC 28201.
320 Schuyler Ave., Kearny, NJ 07032.
P. 0. Box 1131, Stamford, CT 06940.
1251 Beaver Channel Parkway, Clinton, lA 52733.
P. 0. Drawer K, Dover, DE 19901.
1301 Jefferson St., Hoboken, NJ 07030.
1035 Belleville Turnpike, Kearny, NJ 07032.
200 Bush St., San Francisco, CA 94120.
Midland Bldg., Cleveland, OH 44115.
85 Pleasant St., Leominster, MA 01453.
342 N. Western Ave., Chicago, IL 60612.
Menlo Park Office Bldg., Edison, NJ 08817.
636 California St., San Francisco, CA 94119.
12000 Shaker Blvd., Cleveland, OH 44120.
San Francisco, CA 24119.
San Francisco, CA 24119.
60421.
Maywood, NJ 07607.
636 California St.,
536 California St.,
R.R. #1, Elwood, IL
100 W. Hunter Ave.,
90 Park Ave., New York, NY 10016.
2235 Langdon Farm Rd., Cincinnati, OH 45237.
120 Lister Ave., Newark, NJ 07105.
90 Park Ave., New York, NY 10016.
Military Rd., Rothschild, WI 54474.
400 W. Roosevelt Ave., Bensenville, IL 60106.
P. 0. Box 3623, Ponce, PR 00731.
120 Wall St., New York, NY 10005.
302 Waller St., Saginaw, MI 48605.
258 SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE L --Synthetic organic chemicals; Alphabetical directory of manufacturers, by company, 19 70- -Continued
Name of company
Office address
Sun Chemical Corp
Ansbacher-Siegle Div
Chemicals Div
General Printing Ink Div
Sunkist Growers, Inc
Sun Oil Co., Sunoco Div
SunOlin Chemical Co
Suntide Refining Co
Swift § Co., Swift Chemical Co. Div
Synthetic Products Co
Synvar Corp
Tanatex Chemical Corp
Charles S. Tanner Co
Teknor Apex Co
Tenneco Chemicals, Inc
Cal/InkDiv
Nuodex Div
Tenneco Colors Div
Tenneco Oil Co., Refining § Marketing
Accounting.
Terra Chemicals International, Inc
Texaco, Inc
Texas Alkyls, Inc
Texas-U.S. Chemical Co
Tex Chem Co., Inc
Texize Chemicals, Inc
Textilana-Nease, Inc
Textron, Inc., Spencer Kellogg Div
Thiokol Chemical Corp
Thomason Industries, Inc., Southern Resin
Div.
Wm. T. Thompson Co., Thompson Chemical Div-
Thompson-Hayward Chemical Co
Tizon Chemical Corp
Toms River Chemical Corp
Arthur C. Trask Co
Triad Chemical
Troy Chemical Co
Trylon Chemicals, Inc
Joseph Turner 5 Co
USS Agri-Chemicals Div of U.S. Steel Corp--
USS Chemicals Div. of U.S. Steel Corp
Paul Uhlich § Co., Inc
Ungerer 5 Co
Union-Camp Corp
Harchem Div
Union Carbide Corp
Union Oil Co. of California
Uniroyal , Inc., Chemical Div
United Chemical Corp., of Norwood
United Chemical Products Corp
United-Erie, Incv
United Merchants 5 Manufacturers, Inc., Roma
Chemical Div.
U.S. Borax Research Corp
U.S. Industries, Inc., E. Helman Co. Div —
U.S. Oil Co
U.S. Pipe § Foundry Co
U.S. Plywood, California Operations,
Shasta Div.
Universal Chemicals Corp
Universal Oil Products Co
UOP Chemical Div
441 Tompkins Ave., Rosebank, NJ 10305.
441 Tompkins Ave., Rosebank, NJ 1030S.
Route 91, Wood River Junction, RI 02894.
135 W. Lake St., North Lake, IL 60164.
720 E. Sunkist St., Ontario, CA 91764.
1608 Walnut St., Philadelphia, PA 19103.
P. 0. Box F, Claymount, DE 19703.
P. 0. Box 2608, Corpus Christ i, TX 78403.
1211 W. 22d St., Oak Brook, IL 60521.
1636 Wayside Rd., Cleveland, OH 44112.
917 Washington St., Wilmington, DE 19899.
P. 0. Box 388, Lyndhurst, NJ 07071.
450 Furman Hall Rd., Greensville, SC 29608.
505 Central Ave., Pawtucket, RI 02662.
280 Park Ave., New York, NY 10017.
711 Camelia St., Berkeley, CA 94710.
P. 0. Box 2, Piscataway, NJ 08854.
1729 N. 11th St., Reading, PA 19604.
P. 0. Box 2511, Houston, TX 77001.
507 6t,h St., Sioux City, lA 51121.
135 E. 42d St., New York, NY 10017.
P. 0. Box 600, Deer Park, TX 77536.
P. 0. Box 667, Port Neches, TX 77651.
20-21 Wagaraw Rd., Fair Lawn, NJ 07410.
P. 0. Box 368, Greenville, SC 29602.
12607 Cerise Ave., Hawthorne, CA 90250.
120 Delaware Ave., Buffalo, NY 14240.
P. 0. Box 27, Bristol, PA 19007.
P. 0. Drawer 1600, Fayetteville, NC 29302.
23529 So. Figueroa St., Carson, CA 90745.
5200 Speaker Rd., Kansas City, KS 66110.
Flemington, NJ 08822.
P. 0. Box 71, Toms River, NJ 08753.
327 S. LaSalle St., Chicago, IL 60604.
P. 0. Box 310, Donaldsonville, LA 70346.
One Avenue L, Newark, NJ 07105.
P. 0. Box 628, Mauldin, SC 29662.
Pleasant View Terrace, P.O. Box 88, Ridgefield,
NJ 07451.
P. 0. Box 1684, Atlanta, GA 30301.
Grant Bldg. , Pittsburgh, PA 15219.
90 West St., New York, NY 10006.
161 Avenue of the Americas, New York, NY 10013.
P. 0. Box 6170, Jacksonville, FL 32205.
P. 0. Box 220, Dover, NJ 44622.
270 Park Ave., New York, .NY 10017.
Union Oil Center, Los Angeles, CA 90017.
Emic Bldg., Naugatuck, CT 06770.
P. 0. Box 367, Endicott St., Norwood, MA 02062.
York and Colgate Sts., Jersey City, NJ 07302.
438 Huron SE., Erie, PA 16512.
749 Quequechan St., Fall River, MA 02721.
3075 Wilshire Blvd., Los Angeles, CA 90005.
P. 0. Box 5129, Akron, OH 44313.
P. 0. Box 4228, E. Providence, RI 02914.
3300 1st Ave. N. , Birmingham, AL 35202.
P. 0. Box 2713, Redding, CA 96002.
1224 Mendon Rd., Ashton, RI 02864.
30 Algonquin Rd., Des Plaines, IL 60018.
State Highway 17, E. Rutherford, NJ 07073.
DIRECTORY OF MANUFACTURERS 259
TABLE 1. --Synthetic organic chemicals: Alphabetical directory of manufacturers, by company, 1970- -Continued
Name of company
Office address
Upjohn Co
Carwin Organic Chemicals
Valchem
Valentine Sugars, Inc
Valley Nitrogen Producers, Inc
Van De Mark Chemical Co., Inc
Vanderbilt Chemical Corp
Van Dyk 5 Co., Inc
Velsicol Chemical Corp
Ventron Corp
Chemicals Div
Vermi lye- Bell
Verona Corp
Vickers Refining Co., Inc
Vineland Chemical Co
Virginia Chemicals, Inc
Vistron Corp
Silmar Div
Vitamins, Inc
Vulcan Materials Co., Chemicals Div
Warner-Jenkinson Manufacturing Co
West Agro-Chemicals, Inc
West Coast Adhesives Co
Westinghouse Electric Corp., Industrial
Plastics Div., Chemical Products Plant.
Weston Chemical Co., Inc
Westvaco Corp., Chemical Div., Polychemicals
Dept.
Weyerhaeuser Co
White § Bagley Co
White § Hodges, Inc
Wliitmoyer Laboratories, Inc
Whittaker Corp. ;
Mol Rez Div
Research § Development
Whittemore-Wright Co., Inc
Wica Chemicals, Inc
Wilson Pharmaceutical 5 Chemical Corp. :
Wilson Laboratories Div
Wilson-Martin Div
Witco Chemical Co., Inc
Witfield Chemical Div
W. A. Wood Co
Woonsocket Color § Chemical Co
Worthington Biochemical Corp
Wycon Chemical Co
Wyeth Laboratories, Inc., Wyeth Laboratories
Div of American Home Products Corp.
J. S. Young Co., Young Aniline Works Div
7000 Portage Rd,, Kalamazoo, Ml 49001.
Sackett Point Rd., North Haven, CT 06473
1407 Broadway, New York, NY 10018.
726 Whitney Bldg., New Orleans, LA 70130.
1221 Van Ness Ave., Fresno, CA 93721.
N. Transit Rd., Lockport, NY 14094.
33 Winfield St., Norwalk, CT 06801.
Main § Williams Sts., Belleville, NJ 07109.
341 E. Ohio St., Chicago, IL 60611.
Park Place E., Wood Ridge, NJ 07075.
1224 Congress St., Beverly, MA 01915.
21707 Bothell Way, Bothell, WA 98011.
lorio Ct., P. 0. Box 385, Union, NJ 07083.
P. 0. Box 2240, Wichita, KS 67201.
W. Wheat Rd., Vineland, NJ 08360.
3340 W. Norfolk Rd. , Portsmouth, VA 23703.
Midland Bldg., Cleveland, OH 44115.
12335 S. Van Ness Ave., Hawthorne, CA 90250.
401 N. Michigan Ave., Suite 2730, Chicago, IL 60611.
P. 0. Box 545, Wichita, KS 67201.
2526 Baldwin St., St. Louis, MO 63106.
501 Santa Fe, Kansas City, MO 64105.
11104 NW. Front Ave
Manor, PA 15665.
Portland, OR 97231.
103 Spring Valley Rd., Montvale, NJ 07645.
P. 0. Box 5207, N. Charleston, SC 29406.
115 S. Palmetto Ave., Marshfield, WI 54449.
P. 0. Box 706, Worcester, MA 01613.
576 Lawrence St., Lowell, MA 01852.
19 N. Railroad, St. , Myerstoivn, PA 17067.
3134 California St., NE, Minneapolis, MN 55426.
3540 Aero Ct., San Diego, CA 92123.
62 Alford St., Boston, MA 02129.
P. 0. Box 506, Charlotte, NC 28201.
4221 S. Western Blvd. Chicago, IL 60609.
Jackson and Swanson Sts., Philadelphia, PA 19148.
P. 0. Box 305, Paramus, NJ 07652.
P. 0. Box 1243, Wilmington, CA 90744.
108 Spring St., Everett, MA 02149.
176 Sunnyside Ave., Woonsocket, RI 02895.
Halls Mills Rd., Freehold, NJ 07728.
P. 0. Box 1087, Colorado Springs, CO 80901.
P. 0. Box 8299, Paoli, PA 19101.
2731 Boston St., Baltimore, MD 21224.
U. S. IMPORTS OF BENZENOID CHEMICALS AND PRODUCTS 261
U.S. general imports of benzenoid chemicals and products entered
under the Tariff Schedules of the United States (TSUS) , schedule 4,
part 1, subparts B and C are analyzed by the Tariff Commission annually
and published in detail in a separate report. General imports of
benzenoid items entered in parts IB and IC totaled 193.7 million pounds
with a foreign invoice value of $135.2 million in 1970 compared with
152.4 million pounds with a foreign invoice value of $118.7 million
in 1969.
Benzenoid products that are "competitive" with similar domestic
products, because they accomplish results substantially equal to those
accomplished by the similar domestic product when used in substantially
the same manner, are subject to a special basis of valuation for customs
purposes known as the "American selling price." If "noncompetitive,"
the benzenoid products are valued for customs purposes on the basis of
the "United States value." The essential difference between these two
values is that "American selling price" is based on the wholesale price
in the United States of the "competitive" domestic product, whereas
"United States value" is based on the wholesale price in the United
States of the imported product less most of the expenses incurred in
bringing the product to the United States and selling it. When neither
of these two valuation bases applies, then the "export value," "foreign
value," or "constructed value" is used as the valuation basis under
section 402 or 402a, Tariff Act of 1930, as amended. The competitive
status of benzenoid imports in 1970 is shown in table 2.
Industrial organic chemicals that are entered under part IB consist
chiefly of benzenoid intermediates and small quantities of acyclic
compounds which are derived in whole or in part from benzenoid compounds,
Also included are mixtures and small quantities of finished products not
specially provided for in part IC (e.g., rubber-processing chemicals).
In terms of value, 41.6 percent of all the benzenoid imports under
part IB in 1970 came from West Germany; 25.5 percent, from Japan; 10.5
percent, from Italy; and 9.2 percent from Switzerland.
Finished organic chemical products entered under part IC include
dyes, pigments, medicinals, flavor and perfume materials, pesticides,
plastics materials, and certain other specified products. In terms of
vaiue, 35.4 percent of all finished benzenoid imports under part IC
in 1970 came from West Germany; 24.1 percent, from Switzerland; 11.2
percent, from Japan; and 10.6 percent from the United Kingdom.
^Imports of Benzenoid Chemicals and Fvoducts, 1970^ TC Publication
413, 1971 [processed].
SYNTHETIC ORGANIC CHEMICALS, 1970
TABLE 2.--Benzenoid chemicals and products: Summary of U.S. general imports entered under Schedule 4,
Parts IB and IC of the TSUS, and analysis by competitive status, 1970
Part and competitive status
Number
of
items
Quantity
Percent
of total
quantity
Foreign
invoice
value
Percent of
foreign
value
Unit
foreign
value
Schedule 4, Part IE
Total'
Competitive:
Duty based on ASP
Noncompetitive;
Duty based on U.S. value
Duty based on export value
Competitive status not available
Schedule 4, Part IC
Total'
Competitive:
Duty based on ASP^
Noncompetitive :
Duty based on U.S. value
Duty based on export value
Competitive status not available
Summary (Schedule 4, Parts IE and IC)
Total'
Competitive:
Duty based on ASP^
Noncompetitive :
Duty based on U.S. value
Duty based on export value
Competitive status not available
2,067
1,405
164
1,000
1,000
dollars
8,012
13,571
6.5
10.9
9,400
3,306
22,615
6,432
32.5
9.0
33,556
43,343
9,035
193,703
30,627
20,003
4,275
15.8
10.3
66,881
52,743
12,341
20.0
7.0
49.2
10.3
39.0
9.1
Per
pound
$0.38
1.17
.24
1.92
1.40
1.72
.62
' Detail may not add to total due to rounding.
^ American selling price.
Source: Compiled by the U.S. Tariff Commission from records of the U.S. Bureau of Customs.
Note. --The totals shown in this table differ from those given in the official statistics of the U.S. Department
of Commerce chiefly because of differences in coverage and in the methods used in compiling the data. In general,
the statistical coverage in 1970 varies from a low of 75 percent for drugs to almost complete coverage for inter-
mediates, drugs, and pigments.
U. S. GOVERNMENT PRINTING OFFICE : 1972 O - 469-
I
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